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+{"segments": [{"id": 1, "seek": 3484, "start": 20.82, "end": 34.84, "text": "بسم الله الرحمن الرحيم اذا الله رغب اليوم بنكمل في ال chapter اللي بتحدث عن ال chemical thermodynamics طلعنا في الحصة الماضية على ال second law of thermodynamics والthird law of thermodynamics", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 1975, 15730, 21984, 12602, 17082, 3555, 45595, 20498, 44945, 24793, 1211, 8978, 2423, 7187, 13672, 1829, 39894, 24401, 12984, 18871, 2423, 7313, 8810, 35483, 23032, 1211, 3615, 8315, 8978, 21542, 9381, 3660, 9673, 46958, 10632, 15844, 2423, 1150, 2101, 295, 8810, 35483, 16070, 25095, 2101, 295, 8810, 35483], "avg_logprob": -0.1732219809602047, "compression_ratio": 1.6467065868263473, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 20.82, "end": 21.12, "word": "بسم", "probability": 0.897705078125}, {"start": 21.12, "end": 21.32, "word": " الله", "probability": 0.96728515625}, {"start": 21.32, "end": 21.6, "word": " الرحمن", 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"probability": 0.9686279296875}, {"start": 118.17, "end": 119.57, "word": " القراءات", "probability": 0.84002685546875}, {"start": 119.57, "end": 119.75, "word": " أو", "probability": 0.83935546875}, {"start": 119.75, "end": 120.33, "word": " النتائج", "probability": 0.9486083984375}, {"start": 120.33, "end": 120.43, "word": " اللي", "probability": 0.747314453125}, {"start": 120.43, "end": 120.71, "word": " بنحصل", "probability": 0.8997395833333334}, {"start": 120.71, "end": 121.07, "word": " عليها", "probability": 0.99560546875}, {"start": 121.07, "end": 121.31, "word": " من", "probability": 0.9892578125}, {"start": 121.31, "end": 122.31, "word": " ال", "probability": 0.8232421875}, {"start": 122.31, "end": 122.95, "word": " other", "probability": 0.39111328125}, {"start": 122.95, "end": 124.19, "word": " thermodynamic", "probability": 0.93505859375}, {"start": 124.19, "end": 124.91, "word": " quantities", "probability": 0.919921875}, {"start": 124.91, "end": 125.43, "word": " علشان", "probability": 0.9191080729166666}, {"start": 125.43, "end": 126.07, "word": " نحسب", "probability": 0.9943033854166666}, {"start": 126.07, "end": 127.13, "word": " ال", "probability": 0.7763671875}, {"start": 127.13, "end": 128.35, "word": " أنتروبي", "probability": 0.852783203125}, {"start": 128.35, "end": 128.89, "word": " لل", "probability": 0.86376953125}, {"start": 128.89, "end": 129.95, "word": " system", "probability": 0.841796875}, {"start": 129.95, "end": 130.41, "word": " entropy", "probability": 0.62109375}, {"start": 130.41, "end": 130.91, "word": " change", "probability": 0.79736328125}, {"start": 130.91, "end": 131.11, "word": " على", "probability": 0.8017578125}, {"start": 131.11, "end": 131.47, "word": " سبيل", "probability": 0.9754231770833334}, {"start": 131.47, "end": 131.95, "word": " المثال", "probability": 0.9947916666666666}], "temperature": 1.0}, {"id": 6, "seek": 15946, "start": 132.52, "end": 159.46, "text": "فبنقول تماما كما كنا نحسب ال delta H فبنقول والله ال delta S at standard conditions بتساوي summation N ال entropy standard entropy لل products minus summation M ال standard entropy لل reactants انه M هي عبارة عن stoichiometric coefficients من المعادلة اللي هي عدد الملات يعني", "tokens": [5172, 3555, 1863, 39648, 46811, 10943, 995, 9122, 15042, 9122, 8315, 8717, 5016, 35457, 2423, 8289, 389, 6156, 3555, 1863, 39648, 16070, 43761, 2423, 8289, 318, 412, 3832, 4487, 39894, 3794, 995, 45865, 28811, 426, 2423, 30867, 3832, 30867, 24976, 3383, 3175, 28811, 376, 2423, 3832, 30867, 24976, 4515, 1719, 16472, 3224, 376, 39896, 6225, 3555, 9640, 3660, 18871, 22784, 18543, 29470, 31994, 9154, 9673, 3615, 18513, 37977, 13672, 1829, 39896, 6225, 3215, 3215, 9673, 1211, 9307, 37495, 22653], "avg_logprob": -0.23203124497085809, "compression_ratio": 1.6486486486486487, "no_speech_prob": 0.0, "words": [{"start": 132.52, "end": 133.82, "word": "فبنقول", "probability": 0.76318359375}, {"start": 133.82, "end": 135.16, "word": " تماما", "probability": 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stoichiometric", "probability": 0.8776041666666666}, {"start": 154.22, "end": 155.84, "word": " coefficients", "probability": 0.9072265625}, {"start": 155.84, "end": 157.04, "word": " من", "probability": 0.97265625}, {"start": 157.04, "end": 157.72, "word": " المعادلة", "probability": 0.9754638671875}, {"start": 157.72, "end": 158.22, "word": " اللي", "probability": 0.618896484375}, {"start": 158.22, "end": 158.32, "word": " ��ي", "probability": 0.89404296875}, {"start": 158.32, "end": 158.58, "word": " عدد", "probability": 0.9752604166666666}, {"start": 158.58, "end": 159.14, "word": " الملات", "probability": 0.9049479166666666}, {"start": 159.14, "end": 159.46, "word": " يعني", "probability": 0.627197265625}], "temperature": 1.0}, {"id": 7, "seek": 17501, "start": 159.99, "end": 175.01, "text": "هنتقل على كيف نستخدم هذه العلاقة لحساب delta S لأي reaction وبالتالي نتوقع بدأة هل التفاعل اللي عندي هيكون spontaneous", "tokens": [3224, 1863, 2655, 4587, 1211, 15844, 9122, 33911, 8717, 14851, 9778, 40448, 29538, 18863, 15040, 28671, 5296, 5016, 3794, 16758, 8289, 318, 5296, 10721, 1829, 5480, 46599, 6027, 2655, 6027, 1829, 8717, 2655, 30543, 3615, 47525, 10721, 3660, 8032, 1211, 16712, 5172, 995, 30241, 13672, 1829, 18871, 16254, 8032, 1829, 30544, 32744], "avg_logprob": -0.3511202920157954, "compression_ratio": 1.2972972972972974, "no_speech_prob": 0.0, "words": [{"start": 159.99, "end": 160.71, "word": "هنتقل", "probability": 0.4054443359375}, {"start": 160.71, "end": 161.03, "word": " على", "probability": 0.33203125}, {"start": 161.03, "end": 161.49, "word": " كيف", "probability": 0.885986328125}, {"start": 161.49, "end": 162.39, "word": " نستخدم", "probability": 0.884033203125}, {"start": 162.39, "end": 162.67, "word": " هذه", "probability": 0.5654296875}, {"start": 162.67, "end": 163.11, "word": " العلاقة", "probability": 0.9656575520833334}, {"start": 163.11, "end": 163.83, "word": " لحساب", "probability": 0.939208984375}, {"start": 163.83, "end": 164.77, 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175.01, "word": " spontaneous", "probability": 0.9091796875}], "temperature": 1.0}, {"id": 8, "seek": 20066, "start": 176.22, "end": 200.66, "text": "بمعنى اخر ان ال delta S هتكون positive او non spontaneous بمعنى اخر ال delta S بتكون negative فحنحاول نتوقع هذا الكلام qualitatively وبعدين نحاول نحسب جداش طيب بيزيد ال entropy او جداش بيجل ال entropy جداش بالظبط ال delta S لأي chemical reaction", "tokens": [3555, 2304, 3615, 1863, 7578, 1975, 34740, 16472, 2423, 8289, 318, 8032, 2655, 30544, 3353, 1975, 2407, 2107, 32744, 4724, 2304, 3615, 1863, 7578, 1975, 34740, 2423, 8289, 318, 39894, 30544, 3671, 6156, 5016, 1863, 5016, 995, 12610, 8717, 2655, 30543, 3615, 23758, 2423, 28820, 10943, 31312, 356, 46599, 22488, 9957, 8717, 5016, 995, 12610, 8717, 5016, 35457, 10874, 3215, 33599, 23032, 1829, 3555, 4724, 1829, 11622, 25708, 2423, 30867, 1975, 2407, 10874, 3215, 33599, 4724, 1829, 7435, 1211, 2423, 30867, 10874, 3215, 33599, 20666, 19913, 3555, 9566, 2423, 8289, 318, 5296, 10721, 1829, 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{"start": 194.46, "end": 194.86, "word": " entropy", "probability": 0.95166015625}, {"start": 194.86, "end": 195.32, "word": " جداش", "probability": 0.9168294270833334}, {"start": 195.32, "end": 195.78, "word": " بالظبط", "probability": 0.983642578125}, {"start": 195.78, "end": 195.92, "word": " ال", "probability": 0.91259765625}, {"start": 195.92, "end": 196.18, "word": " delta", "probability": 0.951171875}, {"start": 196.18, "end": 196.56, "word": " S", "probability": 0.95751953125}, {"start": 196.56, "end": 197.56, "word": " لأي", "probability": 0.7408854166666666}, {"start": 197.56, "end": 199.56, "word": " chemical", "probability": 0.97802734375}, {"start": 199.56, "end": 200.66, "word": " reaction", "probability": 0.91943359375}], "temperature": 1.0}, {"id": 9, "seek": 21977, "start": 202.33, "end": 219.77, "text": "على سبيل المثال بقول calculate the standard entropy change for the following reaction aluminum oxide مع طبعا solid لازم نقول الحالة مهم كتير تلاتة H2O gas اتنين aluminum solid زائد تلاتة H2O gas", "tokens": [3615, 23942, 8608, 21292, 1211, 9673, 12984, 6027, 4724, 39648, 8873, 264, 3832, 30867, 1319, 337, 264, 3480, 5480, 15656, 28421, 20449, 23032, 3555, 3615, 995, 5100, 5296, 31377, 2304, 8717, 39648, 21542, 6027, 3660, 3714, 16095, 9122, 2655, 13546, 6055, 1211, 9307, 3660, 389, 17, 46, 4211, 1975, 2655, 1863, 9957, 15656, 5100, 30767, 16373, 3215, 6055, 1211, 9307, 3660, 389, 17, 46, 4211], "avg_logprob": -0.21650095103365002, "compression_ratio": 1.3670212765957446, "no_speech_prob": 0.0, "words": [{"start": 202.33, "end": 202.79, "word": "على", "probability": 0.78466796875}, {"start": 202.79, "end": 203.19, "word": " سبيل", "probability": 0.9866536458333334}, {"start": 203.19, "end": 203.75, "word": " المثال", "probability": 0.9923502604166666}, {"start": 203.75, "end": 205.27, "word": " بقول", "probability": 0.609619140625}, {"start": 205.27, "end": 205.77, "word": " calculate", "probability": 0.76806640625}, {"start": 205.77, "end": 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"end": 749.99, "text": "الـ Delta S قيمة سالبة لأنه بتحول من غازات إلى liquid فواضح أنه ال Delta S لازم تقل تفاعل شبيه فيه بقول calculate Delta S not for the reaction of liquid iso-octane with oxygen على تفاعل الاحتراق to give CO2 and H2O gas at 298 Kelvin", "tokens": [6027, 39184, 18183, 318, 12174, 32640, 3660, 8608, 6027, 49401, 5296, 33456, 3224, 39894, 5016, 12610, 9154, 32771, 31377, 9307, 30731, 6553, 6156, 2407, 46958, 5016, 14739, 3224, 2423, 18183, 318, 5296, 31377, 2304, 6055, 4587, 1211, 6055, 5172, 995, 30241, 13412, 21292, 3224, 8978, 3224, 4724, 39648, 8873, 18183, 318, 406, 337, 264, 5480, 295, 6553, 307, 78, 12, 78, 349, 1929, 365, 9169, 15844, 6055, 5172, 995, 30241, 42963, 33753, 23557, 4587, 281, 976, 3002, 17, 293, 389, 17, 46, 4211, 412, 9413, 23, 36955], "avg_logprob": -0.25142044946551323, "compression_ratio": 1.3390557939914163, "no_speech_prob": 0.0, "words": [{"start": 723.31, "end": 723.91, "word": "الـ", "probability": 0.72509765625}, {"start": 723.91, 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ان والله يعني", "tokens": [5172, 3555, 39648, 8032, 47302, 2423, 25042, 12, 46, 349, 1929, 38943, 3552, 15844, 568, 37495, 22653, 2272, 13, 20, 3714, 12610, 9154, 2423, 422, 17, 4032, 5296, 5016, 19913, 3660, 4724, 40228, 9566, 9957, 1829, 3282, 3714, 12610, 9154, 25724, 31377, 11622, 37495, 22653, 23758, 10874, 31377, 20328, 5016, 1829, 5016, 44381, 4724, 40228, 9566, 9957, 1829, 8032, 7649, 3282, 3714, 12610, 9154, 25724, 31377, 11622, 23758, 5551, 12610, 8717, 47432, 3660, 28239, 47432, 3660, 16712, 7649, 10632, 28239, 47432, 3660, 16712, 7649, 10632, 16472, 16070, 43761, 37495, 22653], "avg_logprob": -0.28914835099335556, "compression_ratio": 1.8555555555555556, "no_speech_prob": 0.0, "words": [{"start": 750.61, "end": 751.11, "word": "فبقول", "probability": 0.5780436197916666}, {"start": 751.11, "end": 751.57, "word": " هاي", "probability": 0.48583984375}, {"start": 751.57, "end": 751.97, "word": " ال", "probability": 0.8876953125}, {"start": 751.97, "end": 752.69, "word": " ISO", 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{"start": 757.75, "end": 758.19, "word": " و", "probability": 0.4931640625}, {"start": 758.19, "end": 758.49, "word": " لحظة", "probability": 0.765045166015625}, {"start": 758.49, "end": 759.11, "word": " بيعطيني", "probability": 0.674072265625}, {"start": 759.11, "end": 759.55, "word": " 17", "probability": 0.9423828125}, {"start": 759.55, "end": 760.15, "word": " مول", "probability": 0.951416015625}, {"start": 760.15, "end": 760.35, "word": " من", "probability": 0.98388671875}, {"start": 760.35, "end": 760.81, "word": " الجازز", "probability": 0.532958984375}, {"start": 760.81, "end": 761.19, "word": " يعني", "probability": 0.747802734375}, {"start": 761.19, "end": 761.41, "word": " هذا", "probability": 0.84326171875}, {"start": 761.41, "end": 761.67, "word": " جاز", "probability": 0.872314453125}, {"start": 761.67, "end": 762.09, "word": " صحيح", "probability": 0.924560546875}, {"start": 762.09, "end": 762.35, "word": " لكن", "probability": 0.666015625}, {"start": 762.35, "end": 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"الـ delta H not F هي اللي صفر، وحنشوف كمان ان الـ delta G not F اللي هي الـ free energy of formation هتكون يعني صفر at standard state آه، لكن ال S not لأ، ال S not فقط", "tokens": [6027, 39184, 8289, 389, 406, 479, 39896, 13672, 1829, 20328, 5172, 2288, 12399, 4032, 5016, 1863, 8592, 38688, 9122, 2304, 7649, 16472, 2423, 39184, 8289, 460, 406, 479, 13672, 1829, 39896, 2423, 39184, 1737, 2281, 295, 11723, 8032, 2655, 30544, 37495, 22653, 20328, 5172, 2288, 412, 3832, 1785, 19753, 3224, 12399, 44381, 2423, 318, 406, 5296, 10721, 12399, 2423, 318, 406, 6156, 47432], "avg_logprob": -0.30712890811264515, "compression_ratio": 1.4409937888198758, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 953.0, "end": 953.32, "word": "الـ", "probability": 0.65234375}, {"start": 953.32, "end": 953.5, "word": " delta", "probability": 0.28662109375}, {"start": 953.5, "end": 953.78, "word": " H", "probability": 0.68017578125}, {"start": 953.78, "end": 954.04, "word": " not", "probability": 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نصفر نهائيا Delta S0 بتساوى 2S0 للأمونا يقولنا هذا الكلام لو عوضنا يطلع عندى سالب 198.3 J per Kelvin هل هذا كلام منطقي يطلع عندى سالب الانتروبي؟", "tokens": [18684, 1958, 36955, 5296, 15042, 8717, 30544, 43242, 7578, 6239, 31924, 533, 12961, 6156, 3555, 3215, 8315, 8717, 2655, 8848, 37983, 23758, 2423, 28820, 10943, 3714, 7649, 3615, 2407, 11242, 3224, 6225, 8592, 7649, 8717, 9381, 5172, 2288, 8717, 3224, 16373, 25528, 18183, 318, 15, 39894, 3794, 995, 2407, 7578, 568, 50, 15, 24976, 10721, 2304, 2407, 8315, 7251, 39648, 8315, 23758, 2423, 28820, 10943, 45164, 6225, 2407, 11242, 8315, 7251, 9566, 1211, 3615, 43242, 7578, 8608, 6027, 3555, 6375, 13, 18, 508, 680, 36955, 8032, 1211, 23758, 28242, 10943, 9154, 9566, 38436, 7251, 9566, 1211, 3615, 43242, 7578, 8608, 6027, 3555, 2423, 7649, 2655, 32887, 21292, 22807], "avg_logprob": -0.3371559764267108, "compression_ratio": 1.5630252100840336, "no_speech_prob": 0.0, "words": [{"start": 968.82, "end": 969.24, "word": "At", "probability": 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formation يعني delta H0 if for the following reaction at 298 Kelvin provided that the standard enthalpy of formation of ammonia", "tokens": [3615, 23942, 45030, 11242, 16247, 2304, 12984, 37977, 13672, 1829, 39894, 14851, 9778, 40448, 29538, 18863, 15040, 4587, 9307, 4032, 3615, 15040, 4587, 9307, 9122, 8315, 1975, 2655, 4117, 19528, 8315, 18871, 11296, 8608, 16758, 4587, 995, 6156, 3555, 39648, 8873, 264, 3832, 48869, 295, 11723, 37495, 22653, 8289, 389, 15, 498, 337, 264, 3480, 5480, 412, 9413, 23, 36955, 5649, 300, 264, 3832, 48869, 295, 11723, 295, 46833], "avg_logprob": -0.13995536416769028, "compression_ratio": 1.4880382775119618, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1313.06, "end": 1313.54, "word": "على", "probability": 0.740234375}, {"start": 1313.54, "end": 1314.02, "word": " بعض", "probability": 0.93896484375}, {"start": 1314.02, "end": 1314.48, "word": " الأمثلة", "probability": 0.9859619140625}, {"start": 1314.48, "end": 1314.66, "word": " اللي", 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"seek": 135602, "start": 1335.94, "end": 1356.02, "text": "-46.19 in which direction is the reaction spontaneous بيسألني بيقول لي scan هه بيعطيني كمان ال delta S نوت لل system بيقول لي هيحققنا تفاعل N2 جاز زائد تلاتة H2 جاز بيعطينا أمونيا نفهم مع بعض إيش اللي بدويا بيقول بيحسب ال delta H not F", "tokens": [12, 16169, 13, 3405, 294, 597, 3513, 307, 264, 5480, 32744, 4724, 1829, 3794, 10721, 1211, 22653, 4724, 1829, 39648, 32239, 11049, 8032, 3224, 4724, 40228, 9566, 1829, 22653, 9122, 2304, 7649, 2423, 8289, 318, 8717, 35473, 24976, 1185, 4724, 1829, 39648, 32239, 8032, 1829, 5016, 4587, 4587, 8315, 6055, 5172, 995, 30241, 426, 17, 10874, 31377, 30767, 16373, 3215, 6055, 1211, 9307, 3660, 389, 17, 10874, 31377, 4724, 40228, 9566, 1829, 8315, 5551, 2304, 11536, 25528, 8717, 5172, 16095, 20449, 45030, 11242, 11933, 1829, 8592, 13672, 1829, 47525, 2407, 25528, 4724, 1829, 39648, 4724, 1829, 5016, 35457, 2423, 8289, 389, 406, 479], "avg_logprob": -0.32211539407189077, "compression_ratio": 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"seek": 223715, "start": 2219.97, "end": 2237.15, "text": "و طبعا فيه tendency عالية جدا انه البنزين يحترق و يعطيني لأنها عالية كتير ففيه very high tendency for بنزين to form combustion products ال CO2 و ال H2O فالتفاعل بيتم بشكل ممتاز", "tokens": [2407, 23032, 3555, 3615, 995, 8978, 3224, 18187, 6225, 6027, 10632, 10874, 28259, 16472, 3224, 29739, 1863, 11622, 9957, 7251, 33753, 2288, 4587, 4032, 37495, 9566, 9957, 1829, 5296, 33456, 11296, 6225, 6027, 10632, 9122, 2655, 13546, 6156, 41185, 3224, 588, 1090, 18187, 337, 44945, 11622, 9957, 281, 1254, 28121, 3383, 2423, 3002, 17, 4032, 2423, 389, 17, 46, 6156, 6027, 2655, 5172, 995, 30241, 4724, 36081, 2304, 4724, 8592, 28820, 3714, 2304, 2655, 31377], "avg_logprob": -0.15409127564022415, "compression_ratio": 1.4371584699453552, "no_speech_prob": 0.0, "words": [{"start": 2219.97, "end": 2220.29, "word": "و", "probability": 0.79638671875}, {"start": 2220.29, "end": 2220.65, "word": " طبعا", "probability": 0.9033203125}, {"start": 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0.8968098958333334}, {"start": 2225.83, "end": 2226.51, "word": " ففيه", "probability": 0.8274739583333334}, {"start": 2226.51, "end": 2226.69, "word": " very", "probability": 0.7958984375}, {"start": 2226.69, "end": 2226.95, "word": " high", "probability": 0.92529296875}, {"start": 2226.95, "end": 2227.59, "word": " tendency", "probability": 0.9501953125}, {"start": 2227.59, "end": 2228.23, "word": " for", "probability": 0.9365234375}, {"start": 2228.23, "end": 2228.83, "word": " بنزين", "probability": 0.8468424479166666}, {"start": 2228.83, "end": 2229.21, "word": " to", "probability": 0.92431640625}, {"start": 2229.21, "end": 2231.23, "word": " form", "probability": 0.91259765625}, {"start": 2231.23, "end": 2231.77, "word": " combustion", "probability": 0.86474609375}, {"start": 2231.77, "end": 2232.45, "word": " products", "probability": 0.73095703125}, {"start": 2232.45, "end": 2233.85, "word": " ال", "probability": 0.378662109375}, {"start": 2233.85, "end": 2234.39, "word": " 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للأمونيا", "probability": 0.75634765625}, {"start": 2251.62, "end": 2252.4, "word": " سالب", "probability": 0.9099934895833334}, {"start": 2252.4, "end": 2253.0, "word": " 16", "probability": 0.75244140625}, {"start": 2253.0, "end": 2253.18, "word": " و", "probability": 0.6953125}, {"start": 2253.18, "end": 2253.56, "word": " 6", "probability": 0.72412109375}, {"start": 2253.56, "end": 2254.38, "word": " و", "probability": 0.9501953125}, {"start": 2254.38, "end": 2254.76, "word": " 60", "probability": 0.8720703125}, {"start": 2254.76, "end": 2255.36, "word": " حلو", "probability": 0.9488932291666666}, {"start": 2255.36, "end": 2255.68, "word": " كتير", "probability": 0.96435546875}], "temperature": 1.0}, {"id": 101, "seek": 228557, "start": 2256.59, "end": 2285.57, "text": "طيب، إيش الـ ΔG0 للـ reaction؟ بقول الله الـ ΔG0 للأمونيا في 2 minus .. أه، هذا صفر وهذا صفر، هذا صفر وهذا صفر، إذن، بدها تساوي سارب 33.3 كيلو جول، طبعا ال .. ال .. ال mitrogen صفر، لأنه element في ال standard 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{"start": 2283.55, "end": 2283.93, "word": " G0", "probability": 0.886962890625}, {"start": 2283.93, "end": 2284.19, "word": " F", "probability": 0.458984375}, {"start": 2284.19, "end": 2284.39, "word": " له", "probability": 0.623046875}, {"start": 2284.39, "end": 2284.73, "word": " صفر،", "probability": 0.8411865234375}, {"start": 2284.73, "end": 2284.79, "word": " و", "probability": 0.787109375}, {"start": 2284.79, "end": 2285.03, "word": " Delta", "probability": 0.47314453125}, {"start": 2285.03, "end": 2285.57, "word": " H0", "probability": 0.7841796875}], "temperature": 1.0}, {"id": 102, "seek": 229891, "start": 2285.97, "end": 2298.91, "text": "الـ F له برضه كمان صفر دلتا جي نوت ال reaction is negative value هذا الكلام بيقترح علي ان ال process is spontaneous to the right to produce more products", "tokens": [6027, 39184, 479, 46740, 4724, 43042, 3224, 9122, 2304, 7649, 20328, 5172, 2288, 11778, 1211, 2655, 995, 10874, 1829, 8717, 35473, 2423, 5480, 307, 3671, 2158, 23758, 2423, 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القيمة وبيعتمد عليها يوجد Delta G راح تتغير بتغير الـ A الحرارة فممكن بعض التفاعلات اللي بتكون spontaneous وحرجوا على التفاعل الأمونيا كمان مرة بعض التفاعلات اللي بتكون spontaneous ويصير مان ال spontaneous إذا كان غيرنا الـ A الحرارة اللي عندي", "tokens": [9381, 5016, 2423, 39184, 27556, 39, 6055, 2655, 17082, 13546, 4724, 2655, 17082, 13546, 21542, 2288, 9640, 3660, 12174, 20292, 15040, 44381, 2423, 39184, 18183, 318, 34051, 2423, 39184, 3951, 27514, 6564, 76, 3714, 11242, 2288, 20498, 8978, 21542, 2288, 9640, 3660, 37495, 22653, 39896, 2655, 10721, 49115, 9122, 2655, 13546, 39627, 24192, 25062, 32640, 3660, 4032, 21292, 34268, 2304, 3215, 25894, 11296, 7251, 29245, 3215, 18183, 460, 12602, 39319, 6055, 2655, 17082, 13546, 39894, 17082, 13546, 2423, 39184, 316, 21542, 2288, 9640, 3660, 6156, 2304, 43020, 45030, 11242, 16712, 5172, 995, 30241, 9307, 13672, 1829, 39894, 30544, 32744, 4032, 5016, 47341, 14407, 15844, 16712, 5172, 995, 30241, 16247, 2304, 11536, 25528, 9122, 2304, 7649, 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"probability": 0.82373046875}, {"start": 2688.66, "end": 2692.9, "word": " هذا", "probability": 0.54248046875}, {"start": 2692.9, "end": 2693.32, "word": " مافيه", "probability": 0.7685546875}, {"start": 2693.32, "end": 2693.94, "word": " خلاف", "probability": 0.953125}, {"start": 2693.94, "end": 2694.74, "word": " مافيه", "probability": 0.806640625}, {"start": 2694.74, "end": 2694.86, "word": " خلاف", "probability": 0.9620768229166666}, {"start": 2694.86, "end": 2695.08, "word": " ان", "probability": 0.578125}, {"start": 2695.08, "end": 2695.2, "word": " انت", "probability": 0.768798828125}, {"start": 2695.2, "end": 2695.42, "word": " عارف", "probability": 0.9083658854166666}, {"start": 2695.42, "end": 2695.82, "word": " تطلع", "probability": 0.78961181640625}, {"start": 2695.82, "end": 2696.16, "word": " الآن", "probability": 0.58636474609375}, {"start": 2696.16, "end": 2696.74, "word": " ان", "probability": 0.748046875}, {"start": 2696.74, "end": 2697.04, "word": " عند", 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طبقات high temperature لو تكون هذه very high هتكون اكبر من الـ Delta H ممكن تكون اكبر من ال Delta H بالسالب معناته ال Delta H هي اللي negligible و ال T Delta S will dominate و التفاعل بده يكون spontaneous ناخد حالة تانية هذا مثال على الكلام اللي ذكرنا ناخد حالة تانية", "tokens": [6027, 39184, 27556, 38, 8032, 2655, 30544, 3714, 29245, 3660, 4724, 4587, 7578, 16712, 5172, 995, 30241, 2107, 32744, 23032, 3555, 4587, 9307, 1090, 4292, 45164, 6055, 30544, 29538, 588, 1090, 8032, 2655, 30544, 1975, 4117, 26890, 9154, 2423, 39184, 18183, 389, 3714, 43020, 6055, 30544, 1975, 4117, 26890, 9154, 2423, 18183, 389, 20666, 3794, 6027, 3555, 20449, 8315, 47395, 2423, 18183, 389, 39896, 13672, 1829, 32570, 964, 4032, 2423, 314, 18183, 318, 486, 28246, 4032, 16712, 5172, 995, 30241, 47525, 3224, 7251, 30544, 32744, 8717, 47283, 3215, 11331, 6027, 3660, 6055, 7649, 10632, 23758, 50113, 6027, 15844, 2423, 28820, 10943, 13672, 1829, 29910, 37983, 8315, 8717, 47283, 3215, 11331, 6027, 3660, 6055, 7649, 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0.712890625}, {"start": 2992.28, "end": 2992.72, "word": " التنتين", "probability": 0.9654947916666666}, {"start": 2992.72, "end": 2993.44, "word": " سالبات", "probability": 0.9915771484375}, {"start": 2993.44, "end": 2994.44, "word": " قال", "probability": 0.65673828125}, {"start": 2994.44, "end": 2994.76, "word": " برضه", "probability": 0.9939778645833334}, {"start": 2994.76, "end": 2994.86, "word": " ال", "probability": 0.83154296875}, {"start": 2994.86, "end": 2995.24, "word": " temperature", "probability": 0.9482421875}, {"start": 2995.24, "end": 2995.58, "word": " will", "probability": 0.9111328125}, {"start": 2995.58, "end": 2996.06, "word": " dictate", "probability": 0.97998046875}, {"start": 2996.06, "end": 2996.72, "word": " outcome", "probability": 0.9306640625}, {"start": 2996.72, "end": 2997.0, "word": " of", "probability": 0.9736328125}, {"start": 2997.0, "end": 2997.26, "word": " Delta", "probability": 0.91943359375}, {"start": 2997.26, "end": 2997.52, "word": " G", 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3045.16, "end": 3045.68, "word": " سيكون", "probability": 0.8279622395833334}, {"start": 3045.68, "end": 3046.5, "word": " موجب", "probability": 0.9827473958333334}, {"start": 3046.5, "end": 3047.08, "word": " ننتبه", "probability": 0.7833251953125}, {"start": 3047.08, "end": 3047.52, "word": " لهذه", "probability": 0.94970703125}, {"start": 3047.52, "end": 3049.3, "word": " الأمور", "probability": 0.9793294270833334}, {"start": 3049.3, "end": 3049.78, "word": " لأنه", "probability": 0.8564453125}, {"start": 3049.78, "end": 3050.18, "word": " ممكن", "probability": 0.72509765625}, {"start": 3050.18, "end": 3052.06, "word": " نسأل", "probability": 0.7845458984375}, {"start": 3052.06, "end": 3052.4, "word": " عنها", "probability": 0.98681640625}, {"start": 3052.4, "end": 3052.76, "word": " يعني", "probability": 0.751953125}], "temperature": 1.0}, {"id": 134, "seek": 307014, "start": 3053.98, "end": 3070.14, "text": "أقولها لما تكون الـ delta H سالبة و ال delta S موجبة فهي دائما عند spontaneous reaction و العكس لو التنتين واحدة اللي هو ال delta H موجبة و ال delta S سالبة فهيكون دائما non spontaneous reaction", "tokens": [10721, 39648, 11296, 5296, 15042, 6055, 30544, 2423, 39184, 8289, 389, 8608, 6027, 49401, 4032, 2423, 8289, 318, 3714, 29245, 49401, 6156, 3224, 1829, 11778, 16373, 15042, 43242, 32744, 5480, 4032, 18863, 4117, 3794, 45164, 16712, 29399, 9957, 36764, 24401, 3660, 13672, 1829, 31439, 2423, 8289, 389, 3714, 29245, 49401, 4032, 2423, 8289, 318, 8608, 6027, 49401, 6156, 3224, 1829, 30544, 11778, 16373, 15042, 2107, 32744, 5480], "avg_logprob": -0.32835477152291465, "compression_ratio": 1.7439024390243902, "no_speech_prob": 0.0, "words": [{"start": 3053.98, "end": 3054.54, "word": "أقولها", "probability": 0.3709309895833333}, {"start": 3054.54, "end": 3054.68, "word": " لما", "probability": 0.716796875}, {"start": 3054.68, "end": 3055.22, "word": " تكون", "probability": 0.70068359375}, {"start": 3055.22, "end": 3055.94, "word": " الـ", "probability": 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temperatures spontaneous at all temperatures يعني ال delta", "tokens": [1211, 15042, 8717, 39648, 23758, 16712, 5172, 995, 30241, 32744, 412, 439, 12633, 32744, 412, 439, 12633, 37495, 22653, 2423, 8289], "avg_logprob": -0.2649147862737829, "compression_ratio": 1.3296703296703296, "no_speech_prob": 0.0, "words": [{"start": 3078.67, "end": 3078.99, "word": "لما", "probability": 0.69140625}, {"start": 3078.99, "end": 3079.31, "word": " نقول", "probability": 0.8876953125}, {"start": 3079.31, "end": 3079.83, "word": " هذا", "probability": 0.689453125}, {"start": 3079.83, "end": 3080.53, "word": " التفاعل", "probability": 0.9366455078125}, {"start": 3080.53, "end": 3081.59, "word": " spontaneous", "probability": 0.7998046875}, {"start": 3081.59, "end": 3082.55, "word": " at", "probability": 0.97119140625}, {"start": 3082.55, "end": 3082.89, "word": " all", "probability": 0.95361328125}, {"start": 3082.89, "end": 3083.71, "word": " temperatures", "probability": 0.8671875}, {"start": 3083.71, "end": 3085.55, "word": " spontaneous", "probability": 0.2225341796875}, {"start": 3085.55, "end": 3086.07, "word": " at", "probability": 0.9833984375}, {"start": 3086.07, "end": 3086.29, "word": " all", "probability": 0.953125}, {"start": 3086.29, "end": 3087.01, "word": " temperatures", "probability": 0.89111328125}, {"start": 3087.01, "end": 3088.99, "word": " يعني", "probability": 0.878662109375}, {"start": 3088.99, "end": 3089.43, "word": " ال", "probability": 0.794921875}, {"start": 3089.43, "end": 3090.21, "word": " delta", "probability": 0.65185546875}], "temperature": 1.0}, {"id": 136, "seek": 311189, "start": 3093.11, "end": 3111.89, "text": "معناته هذه سالبة وهذه موجبة مادة مجلة spontaneous at all يعني الحرارة لا تؤثر و اكتش لا تؤثر وهو spontaneous معناته لما نكون ال delta H موجبة و ال delta H سالبة و ال delta S موجبة لأن محصلتهم دائما سالبة", "tokens": [2304, 3615, 8315, 47395, 29538, 8608, 6027, 49401, 37037, 24192, 3714, 29245, 49401, 3714, 18513, 3660, 3714, 7435, 37977, 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" مادة", "probability": 0.2708740234375}, {"start": 3095.75, "end": 3096.79, "word": " مجلة", "probability": 0.91943359375}, {"start": 3096.79, "end": 3097.91, "word": " spontaneous", "probability": 0.422119140625}, {"start": 3097.91, "end": 3098.23, "word": " at", "probability": 0.8935546875}, {"start": 3098.23, "end": 3098.49, "word": " all", "probability": 0.8291015625}, {"start": 3098.49, "end": 3098.83, "word": " يعني", "probability": 0.734375}, {"start": 3098.83, "end": 3099.13, "word": " الحرارة", "probability": 0.8695068359375}, {"start": 3099.13, "end": 3099.23, "word": " لا", "probability": 0.57666015625}, {"start": 3099.23, "end": 3100.13, "word": " تؤثر", "probability": 0.92578125}, {"start": 3100.13, "end": 3100.53, "word": " و", "probability": 0.54443359375}, {"start": 3100.53, "end": 3100.79, "word": " اكتش", "probability": 0.5538177490234375}, {"start": 3100.79, "end": 3100.93, "word": " لا", "probability": 0.65185546875}, {"start": 3100.93, "end": 3101.37, "word": " تؤثر", "probability": 0.9752604166666666}, {"start": 3101.37, "end": 3101.81, "word": " وهو", "probability": 0.76025390625}, {"start": 3101.81, "end": 3102.37, "word": " spontaneous", "probability": 0.9443359375}, {"start": 3102.37, "end": 3103.19, "word": " معناته", "probability": 0.9013671875}, {"start": 3103.19, "end": 3103.39, "word": " لما", "probability": 0.857177734375}, {"start": 3103.39, "end": 3103.67, "word": " نكون", "probability": 0.896240234375}, {"start": 3103.67, "end": 3103.77, "word": " ال", "probability": 0.8544921875}, {"start": 3103.77, "end": 3103.99, "word": " delta", "probability": 0.56103515625}, {"start": 3103.99, "end": 3104.35, "word": " H", "probability": 0.751953125}, {"start": 3104.35, "end": 3105.17, "word": " موجبة", "probability": 0.9757486979166666}, {"start": 3105.17, "end": 3105.33, "word": " و", "probability": 0.64208984375}, {"start": 3105.33, "end": 3105.41, "word": " ال", "probability": 0.77392578125}, {"start": 3105.41, "end": 3105.63, "word": 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314208, "start": 3112.86, "end": 3142.08, "text": "لأن دلتا G بسووة دلتا H minus T دلتا S فالمحصر يكون سالب دائما يبقى اه طب non spontaneous at all temperatures قال هد موجبه هد سالب spontaneous at low temperature non spontaneous at high temperature ايش اشارة دلتا H ودلتا S spontaneous at low temperature", "tokens": [1211, 33456, 11778, 1211, 2655, 995, 460, 4724, 3794, 2407, 2407, 3660, 11778, 1211, 2655, 995, 389, 3175, 314, 11778, 1211, 2655, 995, 318, 6156, 45340, 5016, 9381, 2288, 7251, 30544, 8608, 6027, 3555, 11778, 16373, 15042, 7251, 3555, 4587, 7578, 1975, 3224, 23032, 3555, 2107, 32744, 412, 439, 12633, 50239, 8032, 3215, 3714, 29245, 3555, 3224, 8032, 3215, 8608, 6027, 3555, 32744, 412, 2295, 4292, 2107, 32744, 412, 1090, 4292, 1975, 1829, 8592, 1975, 8592, 9640, 3660, 11778, 1211, 2655, 995, 389, 4032, 3215, 1211, 2655, 995, 318, 32744, 412, 2295, 4292], "avg_logprob": -0.339095745631989, "compression_ratio": 1.8054054054054054, "no_speech_prob": 0.0, "words": [{"start": 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بده احط ال delta H سالبة صحيح ال delta H سالبة وهدي موجبة وهدي سالبة وهدي سالبة طب spontaneous at high temperatures non spontaneous at low temperatures اذا التنتين", "tokens": [267, 2295, 4292, 4724, 3794, 32744, 412, 2295, 4292, 1975, 1829, 8592, 47525, 3224, 1975, 5016, 9566, 2423, 8289, 389, 8608, 6027, 49401, 20328, 5016, 1829, 5016, 2423, 8289, 389, 8608, 6027, 49401, 37037, 16254, 3714, 29245, 49401, 37037, 16254, 8608, 6027, 49401, 37037, 16254, 8608, 6027, 49401, 23032, 3555, 32744, 412, 1090, 12633, 2107, 32744, 412, 2295, 12633, 1975, 15730, 16712, 29399, 9957], "avg_logprob": -0.22355769230769232, "compression_ratio": 1.9726027397260273, "no_speech_prob": 0.0, "words": [{"start": 3143.36, "end": 3143.66, "word": "at", "probability": 0.39501953125}, {"start": 3143.66, "end": 3144.06, "word": " low", "probability": 0.97119140625}, {"start": 3144.06, "end": 3144.78, "word": " temperature", "probability": 0.79345703125}, {"start": 3144.78, "end": 3145.22, "word": " بس", 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فاحنا بنقدر نتوقع هذا بالنسبة لل Delta G هل بنقدر .. Delta .. طب ال Delta .. Delta H عرفناها ال Delta S برضه عرفناها في كل حالة فممكن بسهولة أنه نطلع على التفعل و نشوف هل هو spontaneous at all temperatures non spontaneous at all temperatures spontaneous at مثلا low temperatures و non spontaneous at height أو العكس", "tokens": [3555, 2304, 29245, 3660, 4724, 4587, 36081, 6156, 39319, 8315, 44945, 28543, 2288, 8717, 2655, 30543, 3615, 23758, 20666, 1863, 35457, 3660, 24976, 18183, 460, 8032, 1211, 44945, 28543, 2288, 4386, 18183, 4386, 23032, 3555, 2423, 18183, 4386, 18183, 389, 6225, 28480, 8315, 11296, 2423, 18183, 318, 4724, 43042, 3224, 6225, 28480, 8315, 11296, 8978, 28242, 11331, 6027, 3660, 6156, 2304, 43020, 4724, 3794, 3224, 12610, 3660, 14739, 3224, 8717, 9566, 1211, 3615, 15844, 16712, 5172, 30241, 4032, 8717, 8592, 38688, 8032, 1211, 31439, 32744, 412, 439, 12633, 2107, 32744, 412, 439, 12633, 32744, 412, 50113, 15040, 2295, 12633, 4032, 2107, 32744, 412, 6681, 34051, 18863, 4117, 3794], "avg_logprob": -0.2141628391152128, "compression_ratio": 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height", "probability": 0.205322265625}, {"start": 3199.35, "end": 3199.49, "word": " أو", "probability": 0.67529296875}, {"start": 3199.49, "end": 3199.99, "word": " العكس", "probability": 0.97216796875}], "temperature": 1.0}, {"id": 140, "seek": 320971, "start": 3200.37, "end": 3209.71, "text": "ممكن نتعرف على إشارة Delta S و Delta H", "tokens": [2304, 43020, 8717, 2655, 3615, 28480, 15844, 11933, 8592, 9640, 3660, 18183, 318, 4032, 18183, 389], "avg_logprob": -0.3915441176470588, "compression_ratio": 0.9032258064516129, "no_speech_prob": 0.0, "words": [{"start": 3200.37, "end": 3200.79, "word": "ممكن", "probability": 0.60369873046875}, {"start": 3200.79, "end": 3201.29, "word": " نتعرف", "probability": 0.86181640625}, {"start": 3201.29, "end": 3201.61, "word": " على", "probability": 0.71875}, {"start": 3201.61, "end": 3205.97, "word": " إشارة", "probability": 0.811767578125}, {"start": 3205.97, "end": 3206.27, "word": " Delta", "probability": 0.40576171875}, {"start": 3206.27, 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جول per mole per Kelvin", "tokens": [12587, 264, 11723, 295, 3002, 17, 11331, 1211, 2407, 9122, 12984, 13546, 4724, 39648, 16070, 43761, 18183, 318, 406, 479, 28811, 426, 318, 406, 479, 24976, 3383, 3175, 376, 318, 406, 479, 24976, 4515, 1719, 37037, 24192, 23032, 3555, 3615, 995, 45030, 9566, 9957, 1829, 12174, 32640, 11296, 4724, 7435, 1829, 3555, 18183, 318, 406, 479, 4724, 9566, 1211, 3615, 1975, 2655, 1863, 9957, 34683, 3794, 27884, 10874, 12610, 680, 6353, 680, 36955], "avg_logprob": -0.27111485962932175, "compression_ratio": 1.3789473684210527, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3336.56, "end": 3336.96, "word": "For", "probability": 0.08892822265625}, {"start": 3336.96, "end": 3337.12, "word": " the", "probability": 0.71923828125}, {"start": 3337.12, "end": 3337.5, "word": " formation", "probability": 0.9052734375}, {"start": 3337.5, "end": 3337.72, "word": " of", "probability": 0.98095703125}, {"start": 3337.72, "end": 3338.36, "word": " CO2", 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"temperature": 1.0}, {"id": 172, "seek": 392761, "start": 3902.01, "end": 3927.61, "text": "التفاعل لـ Propane مع O2 وهو تفاعل احتراق عادي بيعطيني الـ CO2 H2O الـ Delta H نوت ماينس الفين و متين و عشرين كيلو جول كويس مين بتوقعلي ال Delta S تكون موجبة ولا سالبة؟ تطلع السالبة", "tokens": [6027, 2655, 5172, 995, 30241, 5296, 39184, 21944, 1929, 20449, 422, 17, 37037, 2407, 6055, 5172, 995, 30241, 1975, 33753, 23557, 4587, 6225, 995, 16254, 4724, 40228, 9566, 9957, 1829, 2423, 39184, 3002, 17, 389, 17, 46, 2423, 39184, 18183, 389, 8717, 35473, 19446, 9957, 3794, 27188, 9957, 4032, 44650, 9957, 4032, 6225, 46309, 9957, 9122, 26895, 2407, 10874, 12610, 9122, 45865, 3794, 3714, 9957, 39894, 30543, 3615, 20292, 2423, 18183, 318, 6055, 30544, 3714, 29245, 49401, 49429, 8608, 6027, 49401, 22807, 6055, 9566, 1211, 3615, 21136, 6027, 49401], "avg_logprob": -0.3326388832595613, "compression_ratio": 1.5736842105263158, "no_speech_prob": 0.0, "words": [{"start": 3902.0099999999998, "end": 3902.77, 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at 300 degrees c delta g naught إيش يعني؟ يعني at standard state at 298 Kelvin at 25 degrees c و بده delta g at 300 degrees c كويس؟", "tokens": [41185, 3224, 37495, 22653, 5551, 5016, 1211, 9673, 3794, 10721, 37977, 37893, 4724, 7435, 3215, 8592, 16070, 43761, 544, 3671, 23032, 1829, 3555, 29538, 47524, 10721, 37977, 9122, 45865, 3794, 3660, 4724, 39648, 8873, 257, 8289, 290, 13138, 293, 272, 8289, 290, 412, 6641, 5310, 269, 8289, 290, 13138, 11933, 1829, 8592, 37495, 22653, 22807, 37495, 22653, 412, 3832, 1785, 412, 9413, 23, 36955, 412, 3552, 5310, 269, 4032, 47525, 3224, 8289, 290, 412, 6641, 5310, 269, 9122, 45865, 3794, 22807], "avg_logprob": -0.3172637162412085, "compression_ratio": 1.5829145728643217, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 4199.83, "end": 4200.19, "word": "فيه", "probability": 0.24884033203125}, {"start": 4200.19, "end": 4200.47, "word": " يعني", "probability": 0.891845703125}, {"start": 4200.47, "end": 4201.11, "word": " أحل", 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