diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..58e9a075588b4eb498bbc1c4c8d7b76353a7393d
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_postprocess.srt
@@ -0,0 +1,2216 @@
+1
+00:00:21,350 --> 00:00:25,870
+بسم الله الرحمن الرحيم نستأنف اليوم في موضوع ال
+
+2
+00:00:25,870 --> 00:00:30,470
+alkanes و ال cycloalkanes زي ما بتعرفوا المرة
+
+3
+00:00:30,470 --> 00:00:37,030
+الماضية أعطينا فكرة عن ال alkanes من ناحية التسمية
+
+4
+00:00:37,030 --> 00:00:41,330
+و من ناحية بعض الخواص الفيزيائية و من ناحية
+
+5
+00:00:41,330 --> 00:00:51,110
+تركيبها بمعنى عدد ذرات ال carbon و ال hydrogenو
+
+6
+00:00:51,110 --> 00:00:57,310
+الصيغة العامة ربما بتذكروا حكينا للالكينز CNN H2N
+
+7
+00:00:57,310 --> 00:01:02,560
+Plus Twoالان من انواع ال hydrocarbons اللى بنقول
+
+8
+00:01:02,560 --> 00:01:07,080
+عنها مشبعة saturated ال cycle alkenes عشان ناخد
+
+9
+00:01:07,080 --> 00:01:12,600
+cycle alkenes او حتى بعد هيك alkenes بننطلق احنا
+
+10
+00:01:12,600 --> 00:01:17,220
+من ال alkenes يعني اتخيلوا هذا المركب اللى امامكم
+
+11
+00:01:17,220 --> 00:01:26,060
+هذا عبارة عن بروبين C3H8 واضح؟لو بدى انا اجعل هذا
+
+12
+00:01:26,060 --> 00:01:32,700
+المركب اشيل ذرتين هيدروجين و احط بدالهم رابطة يعني
+
+13
+00:01:32,700 --> 00:01:37,400
+هى ذرة هيدروجين و من جنبها تماما يعني عندك ذرتين
+
+14
+00:01:37,400 --> 00:01:41,240
+كربون متجاورات شيلت ذرة هيدروجين و حطيت رابطة
+
+15
+00:01:41,240 --> 00:01:48,270
+مكانهم بيصير عندى ال keenبصير عندى الكين اللى فيه
+
+16
+00:01:48,270 --> 00:01:52,210
+double bond لبروبيل الان لو سألت ال الكين ايش
+
+17
+00:01:52,210 --> 00:01:59,970
+الصيغة العامة له لاحظوا معاه C3H6
+
+18
+00:02:01,060 --> 00:02:09,040
+C3H6 معنا ذلك الصيغة العامة للالكينز CNNH2N واضح
+
+19
+00:02:09,040 --> 00:02:15,540
+نقص كم هيدروجينة تنتين الان لو جربنا نشيل كمان
+
+20
+00:02:15,540 --> 00:02:19,180
+هيدروجين تان من جنب بعض و نحط رابطة مكانهم يعني
+
+21
+00:02:19,180 --> 00:02:24,060
+هاي كمان هيدروجين شيلتها و كمان هيدروجين و حطيت
+
+22
+00:02:24,060 --> 00:02:32,960
+رابطة صار عندى رابطةثلاثية ال kind صار عندي ال
+
+23
+00:02:32,960 --> 00:02:39,660
+kind هذا ال ال kind الصيغة العامة إيه له CNH2N-2
+
+24
+00:02:39,660 --> 00:02:44,940
+يعني لما أقول C3H326
+
+25
+00:02:44,940 --> 00:02:50,830
+-2 أربعة شايفين الأربعةفهذه الصيغة العامة لل
+
+26
+00:02:50,830 --> 00:02:56,690
+الkins لل الkinds لل الkins الآن خلّينا نرجع مرة
+
+27
+00:02:56,690 --> 00:03:01,890
+تانية لل الkins ونشوف طيب إيش الصيغة العامة لل
+
+28
+00:03:01,890 --> 00:03:06,370
+cycloalkins اللي الآن بدهم يمروا علينا ال
+
+29
+00:03:06,370 --> 00:03:11,050
+cycloalkins يعني لو بدي أعمل حلقة و كل الروابط
+
+30
+00:03:11,050 --> 00:03:17,770
+تبعت هذه الحلقة روابط إيش أحديةعشان اعمل حلقة
+
+31
+00:03:17,770 --> 00:03:24,250
+المفروض ان اشيل ذرتين هيدروجين لكن بشيلهم مش من
+
+32
+00:03:24,250 --> 00:03:28,810
+جنب بعض في هذه الحالة مثلا بشيلهم من الأطراف هشيلت
+
+33
+00:03:28,810 --> 00:03:33,990
+ذرة هيدروجين من هنا و ذرة هيدروجين تانية من
+
+34
+00:03:33,990 --> 00:03:41,210
+الأطراف و حطيت مكانها رابطة صار
+
+35
+00:03:41,210 --> 00:03:47,060
+عند مركب حلقهcycloalkane لأنه إجا من تلت كربونات
+
+36
+00:03:47,060 --> 00:03:53,100
+بروبيل، شو صرت أسميه؟ Cyclopropane طيب، الآن طالما
+
+37
+00:03:53,100 --> 00:03:58,100
+أنا شيلت هيدروجين تان، والواقع أيضا بأيد هالكلام
+
+38
+00:03:58,100 --> 00:04:00,400
+C3H
+
+39
+00:04:01,190 --> 00:04:08,670
+Six إذا ما الصيغة العامة للـ Cycloalkynes CNH2N
+
+40
+00:04:08,670 --> 00:04:15,810
+CNH2N لاحظوا معناه إن ال الكينز و ال Cycloalkynes
+
+41
+00:04:15,810 --> 00:04:19,990
+بينشأوا عنفق الذرتين هيدروجين ولذلك الطرفين اللي
+
+42
+00:04:19,990 --> 00:04:26,110
+همنفس الصيغة العامة لكن لو فقدوا ذرات الهيدروجين
+
+43
+00:04:26,110 --> 00:04:31,050
+من جانب بعض اعملنا رابطة مكانهم صار عند ال الكين
+
+44
+00:04:31,050 --> 00:04:35,450
+لو فقدوا من اماكن بعيدة و اعملنا رابطة صار عند
+
+45
+00:04:35,450 --> 00:04:40,370
+Cycloalkyn و لذلك ال Cycloalkyn و ال الكين هما
+
+46
+00:04:40,370 --> 00:04:46,750
+يمتلون نفس الفورمولة CNH2N
+
+47
+00:04:46,750 --> 00:04:52,900
+هذه النقطة الأولى اللى بدى احكيها في الموضوعالان
+
+48
+00:04:52,900 --> 00:04:57,960
+لو اتطلعنا اكثر على الـ Cyclopropane بدنا معلومات
+
+49
+00:04:57,960 --> 00:05:03,040
+اكثر عنه، لاحظوا ان تلت ذرات الكربون تبعون الـ
+
+50
+00:05:03,040 --> 00:05:09,830
+Cyclopropane في مستوى واحد، واضح؟و أي تلت ذرات في
+
+51
+00:05:09,830 --> 00:05:13,470
+الدنيا بالمناسبة بيكونوا في مستوى واحد يعني مش
+
+52
+00:05:13,470 --> 00:05:17,130
+ممكن تلاتة إلا يكونوا في مستوى واحد واحد اتنين
+
+53
+00:05:17,130 --> 00:05:22,070
+حطوا التالتة هذا في مستوى واحد ولذلك لو سألنا عن
+
+54
+00:05:22,070 --> 00:05:27,370
+الـcyclopropane إيش الشكل تبعه بدنا نقول planner
+
+55
+00:05:27,370 --> 00:05:34,230
+planner يعني في مستوى واحد مش بتلت أبعاد يعني لو
+
+56
+00:05:34,230 --> 00:05:39,070
+كنا بنحكي عن XY هذا في ال XYواضحة الفكرة؟ هذه
+
+57
+00:05:39,070 --> 00:05:41,870
+النقطة الثانية اللى بدنا ننبهها بالنسبة للـ
+
+58
+00:05:41,870 --> 00:05:48,610
+Cyclopropane الان نقطة تالتة كتير مهمة جدا عندنا
+
+59
+00:05:48,610 --> 00:05:55,510
+دائما في أي مركب نعرف أنواع ذرات الهيدروجيلعشان
+
+60
+00:05:55,510 --> 00:05:59,570
+لما بنعمل التفاعلات النواتج تتمد كم نوع ذرات
+
+61
+00:05:59,570 --> 00:06:04,410
+هيدروجين عندك يعني ربما المركب الأصلي اللى قبل ما
+
+62
+00:06:04,410 --> 00:06:08,230
+يكون Cyclopropane اللى هو البروبين لما حكينا المرة
+
+63
+00:06:08,230 --> 00:06:18,590
+الماضية CH3 CH2 CH3 كم نوع من ذرات الهيدروجين فيه
+
+64
+00:06:18,590 --> 00:06:24,250
+نوعين هدولة الستة زي بعض و هدولة التنتين زي بعض و
+
+65
+00:06:24,250 --> 00:06:27,630
+عشان ايه بعد شوية لو بدي اعمل عليه تفاعلات اقول طب
+
+66
+00:06:27,630 --> 00:06:32,530
+نشيل هيدروجينة نحط مركانها كلور لو شيلت من هان
+
+67
+00:06:32,530 --> 00:06:37,610
+بطلع عنده مركب بسميه one chlorobrobil لو شيلت من
+
+68
+00:06:37,610 --> 00:06:43,220
+هانبطلع مركّب تاني بسميه 2-chloropropane فبناء على
+
+69
+00:06:43,220 --> 00:06:47,240
+عدد أنواع الهيدروجين انا بقدر اعرف ايش اللي بيصير
+
+70
+00:06:47,240 --> 00:06:51,340
+عندى بالتفاعل طيب يا تورا لو مسكت ال cyclopropane
+
+71
+00:06:51,340 --> 00:06:59,720
+و سألت هدولة 6 ذرات هيدروجين كام نوع؟نوع واحد
+
+72
+00:06:59,720 --> 00:07:04,400
+بمعنى لو انا امسكت ذرة كلور خلّينا نفترض هذه لمخ
+
+73
+00:07:04,400 --> 00:07:08,520
+اللون الأخضر بدي اشيل اي هيدروجين و احط مكانها
+
+74
+00:07:08,520 --> 00:07:14,180
+كلور مش هذا تفاعل ابدال بدلنا هيدروجين بكلور الان
+
+75
+00:07:14,180 --> 00:07:20,460
+لو شيلت هذه و حطيت كلور هيطلع عندى مركببس بيصير
+
+76
+00:07:20,460 --> 00:07:25,920
+اسمه اكلورو سايكلو بروبين طب لو كنت بده احك مكان
+
+77
+00:07:25,920 --> 00:07:33,120
+هادي نفس الاشي واضح مكان هادي مكان هادي ف ست ذرات
+
+78
+00:07:33,120 --> 00:07:38,520
+الهيدروجين في هذا المركب they are equivalent يعني
+
+79
+00:07:38,520 --> 00:07:43,560
+لو كنا بنسألكم the six hydrogens of cyclopropane
+
+80
+00:07:43,560 --> 00:07:50,880
+areequivalent متكافئات واضحة الفكرة وعشان هيك
+
+81
+00:07:50,880 --> 00:07:56,440
+بنقدر نتبع هالكلام جملة تانية monochlorination of
+
+82
+00:07:56,440 --> 00:07:59,600
+cyclopropane معناه monochlorination إن أنا أبدل
+
+83
+00:07:59,600 --> 00:08:05,680
+هيدروجين واحدة بكلور واحدة شو بسمي العملية؟ mono
+
+84
+00:08:05,680 --> 00:08:11,120
+يعني أحادي monochlorination
+
+85
+00:08:11,120 --> 00:08:18,080
+إيش يعني chlorination؟تفاعل مع الكلور تفاعل الـ
+
+86
+00:08:18,080 --> 00:08:21,340
+Cyclopropane مع الكلور إبدال بذرة واحدة
+
+87
+00:08:21,340 --> 00:08:27,820
+Monochlorination of Cyclopropane produces only one
+
+88
+00:08:27,820 --> 00:08:34,880
+product بيطلع فقط ناتج واحد، شو سميته أنا؟
+
+89
+00:08:34,880 --> 00:08:40,900
+Chlorocyclopropane واضح؟
+
+90
+00:08:41,270 --> 00:08:48,910
+الان اذا بنستمر بنفس هذه الفكرة وبنقول ان انسان
+
+91
+00:08:48,910 --> 00:08:54,850
+عمل هذا التفاعل وصار عنده chlorocyclopropane وفكر
+
+92
+00:08:54,850 --> 00:09:00,570
+انه بده يعمل تفاعل تاني على ال cyclopropane ابدل
+
+93
+00:09:00,570 --> 00:09:06,850
+كمان هيدروجين لازم يكون عارف كم نوع من الهيدروجين
+
+94
+00:09:06,850 --> 00:09:15,380
+عنده في هذا المركب الانلا أكيد لا الان احنا بحاجة
+
+95
+00:09:15,380 --> 00:09:24,980
+إلى عمق في التفكير و في النظر الأمر مش سهل اكثر
+
+96
+00:09:24,980 --> 00:09:31,580
+من نوع يعني هذا لما بضحط chlorine تانية كان مركب
+
+97
+00:09:31,580 --> 00:09:38,640
+بينتج عندى فيه واضح؟في الحقيقة هنكتشف انهم اللي
+
+98
+00:09:38,640 --> 00:09:45,540
+بينتجوا تلت مركبات معناه ذلك عندنا تلت أنواع من
+
+99
+00:09:45,540 --> 00:09:49,220
+الهيدروجيل بنعملهم بال model و بعدين بنكتبهم
+
+100
+00:09:49,220 --> 00:09:53,680
+معادلة حتى نأكد المعلومة الآن لو إجت طالبة منكم
+
+101
+00:09:53,680 --> 00:09:59,240
+قالت بدي أشيل هذه الهيدروجيل اللي على نفس الكاربون
+
+102
+00:09:59,240 --> 00:10:05,020
+اللي حامله كلور و أحط محالها كلورطلعت مركّب حامل
+
+103
+00:10:05,020 --> 00:10:08,840
+ذرتين كلور على نفس الكربون هذا
+
+104
+00:10:08,840 --> 00:10:13,180
+Dichlorocyclopropane لكن التسمية بتشترط اني لازم
+
+105
+00:10:13,180 --> 00:10:17,680
+احدد الان مواقعهم وين موجودة هذه عن امر واحد و هذه
+
+106
+00:10:17,680 --> 00:10:23,680
+ع واحد اذا هذا لو كنت بدى اسميه هسميه one one
+
+107
+00:10:23,680 --> 00:10:28,540
+مرتين لازم اقول one يعني ذرة على one والتانية على
+
+108
+00:10:28,540 --> 00:10:32,600
+one one one dichlorocyclopropane
+
+109
+00:10:33,600 --> 00:10:39,640
+هذا مُركّب إجى مكان ذرّة الهيدروجين اللي هنا الان
+
+110
+00:10:39,640 --> 00:10:47,020
+لو إجيت طلعت على هدول الذرات نسبتهم لهذه واحد تنين
+
+111
+00:10:47,020 --> 00:10:56,580
+او واحد تنين واضح؟ الان لو شيلت هذه حطيت مكانها
+
+112
+00:10:56,580 --> 00:11:04,460
+اكلور هيطلع عند مُركّب جديدDichlorocyclopropane
+
+113
+00:11:04,460 --> 00:11:09,300
+قدرتين لكلور على موقعين متجاورين عشانك بقول one
+
+114
+00:11:09,300 --> 00:11:13,520
+two dichlorocyclopropane
+
+115
+00:11:13,520 --> 00:11:19,240
+one two dichlorocyclopropane هاي مركب تاني الان
+
+116
+00:11:19,240 --> 00:11:25,060
+ممكن واحدة منكم تفكر تقول طب خلينا نشيل هذه الذرعة
+
+117
+00:11:25,060 --> 00:11:30,880
+مش من نفس الجهة اللي هنا من الجهة المعاكسة ونحط
+
+118
+00:11:34,790 --> 00:11:40,130
+one two dichlorocyclopropane الان السؤال هل يا ترى
+
+119
+00:11:40,130 --> 00:11:44,950
+المركب اللى فى ذرتين لكلور على جهة واحدة زى اللى
+
+120
+00:11:44,950 --> 00:11:49,070
+فى ذرتين لكلور متعاكسة ممكن البعض يقول طب احنا
+
+121
+00:11:49,070 --> 00:11:54,190
+بنلف حوالين الرابط لو جربنا اللفتذكروا أن الدوران
+
+122
+00:11:54,190 --> 00:12:00,050
+ممنوع حول الحلقة مافيش إمكانية إذا هدول مركبين طيب
+
+123
+00:12:00,050 --> 00:12:04,210
+هذا اسمه one two و اللي كان ع جهة واحدة برضه اسمه
+
+124
+00:12:04,210 --> 00:12:07,510
+one two dichlorocyclopropane لو بدي أميزهم أكثر
+
+125
+00:12:07,510 --> 00:12:11,890
+بقول اه في عندي one two اللي على جهة واحدة و one
+
+126
+00:12:11,890 --> 00:12:19,170
+two اللي على جهتين متعاكستين هنا بدأنا نتكلم في ال
+
+127
+00:12:19,170 --> 00:12:24,460
+stereo chemistryانه صحيح الذرات موجودين على موقع
+
+128
+00:12:24,460 --> 00:12:28,440
+واحد و اتنين يعني same bonding لكن هنا على واحد و
+
+129
+00:12:28,440 --> 00:12:32,480
+اتنين على جهة واحدة و على واحد و اتنين على جهتين
+
+130
+00:12:32,480 --> 00:12:37,660
+متعاكستين الاسم في الحالتين one two
+
+131
+00:12:37,660 --> 00:12:42,770
+dichlorocyclopropane لكن بدي اضيف عليه مرة معو مرة
+
+132
+00:12:42,770 --> 00:12:49,450
+ضد لو كنا بنكتب بالعربي فعلا بيستعملوا مع كلمتين
+
+133
+00:12:49,450 --> 00:12:55,110
+مع على جهة واحدة و ضد على جهتين متعاكستين الآن
+
+134
+00:12:55,110 --> 00:12:58,550
+بالإنقليزي بيروحوا بيحطوا prefix ال prefix يعني
+
+135
+00:12:58,550 --> 00:13:03,690
+اشي في أول الكلام بادئة توضح هذا الكلام بيروحوا
+
+136
+00:13:03,690 --> 00:13:08,910
+بيضيفوا cis بمعنى على جهة واحدة و trans بمعنى على
+
+137
+00:13:08,910 --> 00:13:16,000
+جهتينSex و Trans يعني على جهة واحدة وعلى جهتين
+
+138
+00:13:16,000 --> 00:13:24,840
+خلينا هذا الكلام إذا بتسمحوا نتخيله بمعادلة ليش
+
+139
+00:13:24,840 --> 00:13:29,660
+لأنه دائما إنتوا لو بدكوا تكتبوا هتكتبوا معادلات
+
+140
+00:13:29,660 --> 00:13:31,780
+بمعنى هاي في عند أنا
+
+141
+00:13:36,020 --> 00:13:41,100
+Cyclopropane هذا Cyclopropane كام هيدروجين فيه؟
+
+142
+00:13:41,100 --> 00:13:46,860
+ستة لو قلت بدي أعمل إيه له؟ إكلورينايشن CL2 في
+
+143
+00:13:46,860 --> 00:13:51,460
+البداية بدي أعمل مونوكلورينايشن أبدل ذرة واحدة شو
+
+144
+00:13:51,460 --> 00:13:57,400
+هينشاء عندى؟ إكلورو سايكلوبروبين على أي موقع ابنه
+
+145
+00:13:57,400 --> 00:14:03,840
+كتوبة ماعنداش مشكلة إكلورو سايكلوبروبين
+
+146
+00:14:03,840 --> 00:14:07,900
+هيك حاجة أسميهالان لو افترضت هذا ال
+
+147
+00:14:07,900 --> 00:14:14,440
+chlorocyclopropane بدي اعمله كمان chlorination
+
+148
+00:14:14,440 --> 00:14:20,000
+حيصير بالمجمل كم ذرة ال chlor أبدلت تنتين اه كمان
+
+149
+00:14:20,000 --> 00:14:25,720
+مرة chlorination حيصير عندي عدة احتمالات هذا
+
+150
+00:14:25,720 --> 00:14:29,140
+الاحتمال ان ذرة ال chlor تيجي على نفس الذرة اللي
+
+151
+00:14:29,140 --> 00:14:35,700
+حملة ال chlor الأولى ايش سمناهالأ اللي عملناه في
+
+152
+00:14:35,700 --> 00:14:42,520
+الأولى ال chlorine ال chlorine على نفس الذرة one
+
+153
+00:14:42,520 --> 00:14:45,880
+one one one one one one one one one one one one
+
+154
+00:14:45,880 --> 00:14:46,040
+one one one one one one one one one one one one
+
+155
+00:14:46,040 --> 00:14:46,060
+one one one one one one one one one one one one
+
+156
+00:14:46,060 --> 00:14:53,560
+one one one one one one one one one one one one
+
+157
+00:14:53,560 --> 00:14:53,820
+one one one one one one one one one one one one
+
+158
+00:14:53,820 --> 00:14:54,180
+one one one one one one one one one one one one
+
+159
+00:14:54,180 --> 00:14:54,200
+one one one one one one one one one one one one
+
+160
+00:14:54,200 --> 00:14:54,300
+one one one one one one one one one one one one
+
+161
+00:15:10,380 --> 00:15:18,060
+الان يا تورا لو كنا بدنا نحط ذرة الكلور على الموقع
+
+162
+00:15:18,060 --> 00:15:24,020
+اتنين خلينا نحط واحد و اتنين هنا بهذا الشكل ممكن
+
+163
+00:15:24,020 --> 00:15:30,380
+يكون عنده ذرتين كلور على جهة واحدة او ذرتين كلور
+
+164
+00:15:30,380 --> 00:15:33,920
+على جهتين متعاكسات
+
+165
+00:15:35,440 --> 00:15:40,600
+واضح؟ الان هاي واحد اتنين تلاتة واحد اتنين تلاتة
+
+166
+00:15:40,600 --> 00:15:45,240
+اذا كل مركب من هدوله ايش اسمه one two
+
+167
+00:15:45,240 --> 00:15:56,340
+dichlorocyclopropane one two dichlorocyclopropane
+
+168
+00:15:56,340 --> 00:15:58,800
+لكن
+
+169
+00:16:05,080 --> 00:16:10,380
+لكن لما بدي اميز هدول المركبات هنا الديكلورو جايين
+
+170
+00:16:10,380 --> 00:16:16,680
+على جهة واحدة فهذا الاسم الكامل له شو حيصير SES
+
+171
+00:16:16,680 --> 00:16:22,200
+شرطة one two dichlorocyclopropane يعني لما بدي
+
+172
+00:16:22,200 --> 00:16:27,540
+اجيب هذا في الامتحان سموه هتكتبوا SES شرطة one two
+
+173
+00:16:27,540 --> 00:16:33,430
+dichlorocyclopropane لو كنت بدي اسمي هذاالترانس
+
+174
+00:16:33,430 --> 00:16:37,190
+شرطة one two dichlorocyclopropane طبعا اكيد الذره
+
+175
+00:16:37,190 --> 00:16:44,010
+التاني اللي هي ذره ايش ال hydrogenواضح؟ لاحظوا ان
+
+176
+00:16:44,010 --> 00:16:49,010
+هدول المركبين .. هدول المركبين من ناحية ال bonding
+
+177
+00:16:49,010 --> 00:16:53,170
+.. من ناحية ال bonding they have the same bonding
+
+178
+00:16:53,170 --> 00:16:57,230
+من أي ناحية؟ ان ذرة كلورة على موقع واحد و التاني
+
+179
+00:16:57,230 --> 00:17:00,690
+على موقع التاني على واحد على اتنين .. على واحد على
+
+180
+00:17:00,690 --> 00:17:06,310
+اتنين the same bonding لكن اين الاختلاف؟ بالشكل ..
+
+181
+00:17:06,310 --> 00:17:10,930
+بالشكل الفراغي they have the same bondingbut
+
+182
+00:17:10,930 --> 00:17:15,470
+different arrangement in space شكلهم بالفراغ مختلف
+
+183
+00:17:15,470 --> 00:17:19,010
+ان هدول الذرتين ع جهة واحدة و هدول الذرتين ع جهات
+
+184
+00:17:19,010 --> 00:17:22,850
+متعاكسة بس اتنين ع واحد اتنين هذا النوع اللي احنا
+
+185
+00:17:22,850 --> 00:17:29,250
+ايش سمنا stereo isomersهذا النوع اللي سمناه stereo
+
+186
+00:17:29,250 --> 00:17:32,910
+isomers لما حكينا على ال isomerism قلنا ال stereo
+
+187
+00:17:32,910 --> 00:17:37,630
+isomers they have the same bonding يعني لما أجي
+
+188
+00:17:37,630 --> 00:17:41,670
+أقول الكلور وين؟ ع واحد و التانية ع اتنين في
+
+189
+00:17:41,670 --> 00:17:45,870
+التاني الكلور وين؟ ع واحد و التانية ع اتنين اذا
+
+190
+00:17:45,870 --> 00:17:50,310
+they have the same bonding طب وين اختلفوا؟بشكل
+
+191
+00:17:50,310 --> 00:17:54,390
+برفرات اه هدول ع واحد و اتنين ع جهة واحدة على واحد
+
+192
+00:17:54,390 --> 00:17:57,630
+و اتنين ع جهتين مختلفتين هذه بنسميها different
+
+193
+00:17:57,630 --> 00:18:03,710
+arrangement in space اذا العلاقة بين هذا ال cis و
+
+194
+00:18:03,710 --> 00:18:12,070
+ال trans they are stereo isomers لاحظوا
+
+195
+00:18:12,070 --> 00:18:16,930
+لو قلتلكوا ما العلاقة بين هذا المركب و هذا المركب
+
+196
+00:18:16,930 --> 00:18:22,870
+في ال isomersهنا they have different bonding و
+
+197
+00:18:22,870 --> 00:18:29,140
+different namesذرتين الكلور على واحد و واحد وعشان
+
+198
+00:18:29,140 --> 00:18:33,980
+هيك سميته one one dichlorocyclopropane هنا ذرتين
+
+199
+00:18:33,980 --> 00:18:36,600
+الكلور على واحد و اتنين هذا ال same bonding ولا
+
+200
+00:18:36,600 --> 00:18:40,020
+different bonding different bonding ال different
+
+201
+00:18:40,020 --> 00:18:45,220
+bonding أدى إلى different names أنا لما حددت مواقع
+
+202
+00:18:45,220 --> 00:18:49,620
+الكلور قلت one one هنا قلت one two إذا هذا المركب
+
+203
+00:18:49,620 --> 00:18:50,860
+و هذا المركب
+
+204
+00:18:53,140 --> 00:18:58,280
+صحيح مكونين من نفس الذرات لكن فيهم different
+
+205
+00:18:58,280 --> 00:19:01,860
+bonding و different names فالعلاقة بين ال 11
+
+206
+00:19:01,860 --> 00:19:06,420
+-dichlorocyclopropane و ال 12-dichlorocyclopropane
+
+207
+00:19:06,420 --> 00:19:11,480
+they are structural isomers و كذلك العلاقة بين هذا
+
+208
+00:19:11,480 --> 00:19:15,140
+و هذا لكن لو قلت العلاقة بين ال cis و ال trans
+
+209
+00:19:15,140 --> 00:19:19,120
+they are stereo isomers
+
+210
+00:19:21,810 --> 00:19:26,210
+Same bonding but different arrangement in space هي
+
+211
+00:19:26,210 --> 00:19:30,550
+تعريف الـ Stereoisomers نفس الإرتباط ولكن يختلف
+
+212
+00:19:30,550 --> 00:19:33,610
+فيه الشكل بالفراغ
+
+213
+00:19:37,910 --> 00:19:43,110
+لما قلنا لـ Stereoisomers قلنا نوعين نوع منهم
+
+214
+00:19:43,110 --> 00:19:48,150
+بنسميه Diastereomers هنتعلمه و نوع منهم بنسميه
+
+215
+00:19:48,150 --> 00:19:54,330
+Enantiomers الآن هدولة المركبين مثال لأحد أنواع
+
+216
+00:19:54,330 --> 00:19:59,290
+الـ Stereoisomers الاتنين مثال للـ Diastereomers
+
+217
+00:19:59,290 --> 00:20:02,050
+Diastereomers
+
+218
+00:20:03,170 --> 00:20:06,650
+يعني لما ناخد الاستيريو ايزو مارز ونقول يقسموا إلى
+
+219
+00:20:06,650 --> 00:20:12,590
+نوعين داياستيريو مارز وانانشو مارز الانانشو مارز
+
+220
+00:20:12,590 --> 00:20:17,370
+هندرسهم بأي فصل بالفصل الخامس الداياستيريو مارز
+
+221
+00:20:17,370 --> 00:20:22,520
+الآن بيمروا عليناطيب لو واحدة بده تيجي تقول طب إيش
+
+222
+00:20:22,520 --> 00:20:26,660
+يعني بالظبط diastereomers؟ إيش يعني بالظبط
+
+223
+00:20:26,660 --> 00:20:31,540
+diastereomers؟ بنقول ببساطة التعريف العام التعريف
+
+224
+00:20:31,540 --> 00:20:35,780
+العام ل diastereomers ال diastereomers they are
+
+225
+00:20:35,780 --> 00:20:41,360
+non mirror image stereoisomers يعني stereoisomers
+
+226
+00:20:41,360 --> 00:20:47,140
+ولكن مش صورة بعض في المرآة يعني لو تخيلت أنا أنه
+
+227
+00:20:47,140 --> 00:20:52,280
+بين واحد والتانيفي بينهم مرايا، هل الواحد منهم
+
+228
+00:20:52,280 --> 00:20:57,060
+صورة التالف في المرآة ولا لأ؟ يعني تخيلوا أن أنا
+
+229
+00:20:57,060 --> 00:21:03,800
+هنا حطيت مرآة، دائما و أبدا، أمام المرآة كل جسم له
+
+230
+00:21:03,800 --> 00:21:11,800
+صورة، والصورة في المرآة دائما معاكسة تماما لصورة
+
+231
+00:21:11,800 --> 00:21:16,740
+الجسميعني لو أنا وقفت زي المرأة .. أمام المرأة
+
+232
+00:21:16,740 --> 00:21:22,720
+بهذا الشكل كل النظر تبعي باتجاهكم الآن الصورة اللي
+
+233
+00:21:22,720 --> 00:21:28,960
+في المرأة بكل أبعادها يجب أن تكون معاكسة لصورة
+
+234
+00:21:28,960 --> 00:21:35,380
+الجسم دائما صورة المرأة معاكسة لصورة الجسم بكل
+
+235
+00:21:35,380 --> 00:21:41,560
+مكوناتهاالان لو اتيت يا تورا اتسألت هل هدولة من
+
+236
+00:21:41,560 --> 00:21:47,360
+الاساس صورة مرآه ولا مش صورة مرآه؟ لاحظوا يمكن هنا
+
+237
+00:21:47,360 --> 00:21:50,600
+تلاقي كلور متجه باتجاه هذه عكسها وهذه الهيدروجين
+
+238
+00:21:50,600 --> 00:21:55,600
+باتجاه هذه عكسها يعني لحد هذه النقطةمعاكسات لكن
+
+239
+00:21:55,600 --> 00:22:01,280
+هنا في chlorine إقبالها hydrogen تحت هنا في
+
+240
+00:22:01,280 --> 00:22:05,140
+chlorine إقبالها hydrogen هل هدولة بيصيروا صورة
+
+241
+00:22:05,140 --> 00:22:11,730
+مرآة إذا بطلوا صورة مرآةشرط صورة المرآة أن كل جزء
+
+242
+00:22:11,730 --> 00:22:16,930
+من الجزيئات هيكون بعكس الجثة الآخر هدولة فيهم
+
+243
+00:22:16,930 --> 00:22:19,910
+أشياء أساسا مش اقبال .. مش .. يعني هذه لا فوق،
+
+244
+00:22:19,910 --> 00:22:25,650
+كلور اقبالها هيدروجين، إذا هدولة الشكلين الcess
+
+245
+00:22:25,650 --> 00:22:30,730
+والترانس لما أنا بدي أحكي عنهم بقول they are non
+
+246
+00:22:30,730 --> 00:22:38,720
+mirrorimages، إيش يعني non-mirror images؟ مش صورة
+
+247
+00:22:38,720 --> 00:22:42,120
+بعض في المرأة، الأشياء اللي بتكون مش صورة بعض في
+
+248
+00:22:42,120 --> 00:22:47,960
+المرأة هي اللي تعرف ان اسمها diastereomers، وهذا
+
+249
+00:22:47,960 --> 00:22:53,760
+مثال عليها، ف ال cicatrans، isomers، they are
+
+250
+00:22:53,760 --> 00:22:55,720
+diastereomers
+
+251
+00:22:57,420 --> 00:23:00,580
+They are non-mirror image stereoisomers, so they
+
+252
+00:23:00,580 --> 00:23:06,520
+are diastereomers فكتصنيف من أنواع الاستيريو ايزو
+
+253
+00:23:06,520 --> 00:23:10,460
+مارز، they are diastereomers واضح؟ ولذلك لو
+
+254
+00:23:10,460 --> 00:23:14,080
+جيبنالكم سؤال صح و غلط Sistransisomers are
+
+255
+00:23:14,080 --> 00:23:21,360
+stereoisomers صحالان لو بدى اسأل اكثر عمقًا
+
+256
+00:23:21,360 --> 00:23:26,640
+Sistransisomers are diastereomers برضه صح ما هي
+
+257
+00:23:26,640 --> 00:23:31,080
+diastereomers نوع لكن لو قلنا Sistransisomers are
+
+258
+00:23:31,080 --> 00:23:36,000
+enantiomers لأ و هنتعلم ال enantiomers مستقبلا لو
+
+259
+00:23:36,000 --> 00:23:42,280
+قلنا Sistransisomers are structural isomersبرضه
+
+260
+00:23:42,280 --> 00:23:47,080
+غلط لأ مش structural .. ال structural بيختلفوا في
+
+261
+00:23:47,080 --> 00:23:49,580
+ال bonding هدولة they have the same bonding ع واحد
+
+262
+00:23:49,580 --> 00:23:56,120
+و اتنين ع واحد و اتنين واضح؟ لكن هذا المركب و هذا
+
+263
+00:23:56,120 --> 00:24:00,180
+they are structural isomers بس ال cis trans
+
+264
+00:24:00,180 --> 00:24:04,400
+isomers are stereoisomers أي نوع من ال
+
+265
+00:24:04,400 --> 00:24:10,050
+stereoisomers تحديدا ده يا stereomersتطلعوا معي
+
+266
+00:24:10,050 --> 00:24:14,650
+مرة تانية نرسم أحد هدولة أو نعمل model لأحد هدولة
+
+267
+00:24:14,650 --> 00:24:18,950
+المركبات اللي هم ال sis, trans, isomers واضح؟ هذا
+
+268
+00:24:18,950 --> 00:24:25,810
+أي مركب فيهم؟ ال sis والتاني لترانس متى توجد عندنا
+
+269
+00:24:25,810 --> 00:24:29,840
+ظاهرة ال sis و الترانس؟يعني في ناس بيقولوا وقتش
+
+270
+00:24:29,840 --> 00:24:33,660
+بدأ اقول ان في عندى cis و trans او لأ بنقول القاتل
+
+271
+00:24:33,660 --> 00:24:38,740
+ظاهرة ال cis و ال trans توجد في مكانين اما في
+
+272
+00:24:38,740 --> 00:24:45,400
+الحلقات او المكان التاني حول الروابط الزوجية صار
+
+273
+00:24:45,400 --> 00:24:50,320
+عندى نقطة كتير مهمة ناس بدهم يفهموا كل موضوع
+
+274
+00:24:53,400 --> 00:24:58,400
+كل موضوع ال sis و ال trans وين عمره يمر علي كلمة
+
+275
+00:24:58,400 --> 00:25:07,120
+sis و ال trans بنقول ال sis و ال trans هتشوفهم
+
+276
+00:25:07,120 --> 00:25:18,180
+بمكانين sis و ال trans اما في ال cycles او في ال
+
+277
+00:25:18,180 --> 00:25:23,160
+alkenesالالكينز اللي فيها روابط الزوجين هذا المكان
+
+278
+00:25:23,160 --> 00:25:29,940
+اللي بتشوفه فيه كلمة sis و trans في ال cycles مثل
+
+279
+00:25:29,940 --> 00:25:35,680
+المثال اللي احنا رسمنا زي ما قولنا هذا مثلا بهذا
+
+280
+00:25:35,680 --> 00:25:43,400
+الشكل sis و بهذا الشكل ال trans هاي بال cycle اللي
+
+281
+00:25:43,400 --> 00:25:48,970
+اتعرفنا عليه طيب حوالين ال double bondنفس الاشي لو
+
+282
+00:25:48,970 --> 00:25:52,810
+تخيل انه عندنا carbon double bond carbon حطينا
+
+283
+00:25:52,810 --> 00:25:59,310
+زرتين كلور بهذا الشكل وهنا carbon double bond
+
+284
+00:25:59,310 --> 00:26:07,670
+carbon حطينا زرتين كلور بهذا الشكل هذا
+
+285
+00:26:07,670 --> 00:26:12,890
+إثالين وهذا إثالين هذولة زرتين كلور على واحد
+
+286
+00:26:12,890 --> 00:26:20,030
+واتنين على جهة واحدةانا على واحد و اتنين و اتنين
+
+287
+00:26:20,030 --> 00:26:24,370
+على جهتين مختلفتين اذا الاتنين اسمه one two
+
+288
+00:26:24,370 --> 00:26:33,450
+dichloroethane طب كيف بدي اميزهم هدوله sis و هدوله
+
+289
+00:26:33,450 --> 00:26:38,010
+ال trans هدوله ال sis و هدوله ال trans فدائرة ال
+
+290
+00:26:38,010 --> 00:26:42,570
+sis و ال trans مكان وجودها في الدنيا مكانين ال
+
+291
+00:26:42,570 --> 00:26:44,790
+cycloalkenes و
+
+292
+00:26:46,730 --> 00:26:51,230
+الالكايز الالكينز عفوا ليش هذا الكلام بيتم لأنه
+
+293
+00:26:51,230 --> 00:26:56,390
+انا لو جربت في cycle الكل بدي ألوف هذا هيك أخلي
+
+294
+00:26:56,390 --> 00:27:00,470
+هدول يصيروا عكس بعض يعني ال 6 يصير ال trans لاحظوا
+
+295
+00:27:00,470 --> 00:27:05,210
+لأنه مربوط بالحلقة الدوران حول الحلقة ممنوع
+
+296
+00:27:05,210 --> 00:27:11,210
+الدوران حول الحلقة ممنوع الان طيب لو اتخيلتوا ان
+
+297
+00:27:11,210 --> 00:27:19,360
+انا في عندهالكين وهي مُركّب الـ CIS مش هذا
+
+298
+00:27:19,360 --> 00:27:25,900
+المُركّب اللي مرسوم CIS 1,2-dichloroethane الأن
+
+299
+00:27:25,900 --> 00:27:31,860
+لاحظوا لو بدى ألف و أخلي هدولة يصيروا عكس بعضبرضه
+
+300
+00:27:31,860 --> 00:27:35,500
+لأن الرابطة الزوجية رابطة قوية الدوران حولها
+
+301
+00:27:35,500 --> 00:27:43,500
+ممنوعة إذا العامل المشترك في هذا الموضوع ما بين
+
+302
+00:27:43,500 --> 00:27:51,800
+الحلقة و ما بين الألكين أنه في الحالتين الدوران
+
+303
+00:27:51,800 --> 00:27:57,040
+ممنوعة لذلك مقدرش أنا أعمل دوران أحول واحد للتاني
+
+304
+00:27:59,010 --> 00:28:05,410
+فكل واحد منهم بيصير مركّب منفصل بخواص منفصلة بمعنى
+
+305
+00:28:05,410 --> 00:28:10,150
+لو واحدة راحت تشتري مركّب كيميائي جالت بدّي one
+
+306
+00:28:10,150 --> 00:28:15,030
+two dichlorocyclopropane البياحة يقولها مافيش
+
+307
+00:28:15,030 --> 00:28:20,230
+عندى، في عندى؟two bottles مرتبانين واحد بكتب عليه
+
+308
+00:28:20,230 --> 00:28:26,170
+sis والتاني trans واضح الفكرة زي لما الواحدة
+
+309
+00:28:26,170 --> 00:28:31,510
+بيجيها مولود مافيش يكون عشوائي يا ولد يا بنت لو
+
+310
+00:28:31,510 --> 00:28:37,030
+قلنا مثلا one two dichloroethaneروحنا نشتريه،
+
+311
+00:28:37,030 --> 00:28:42,930
+مافيش، هتلاقوا عند البائع two bottles مرتبان CES 1
+
+312
+00:28:42,930 --> 00:28:49,270
+,2-dichloroethane بقواص معينة و بظائف معينة في
+
+313
+00:28:49,270 --> 00:28:54,590
+الحياة و هتلاقوا مركب تاني مختلف ال Trans و زي ما
+
+314
+00:28:54,590 --> 00:28:59,520
+قلنا العلاقة بين هدولة VRDiastereomers they are
+
+315
+00:28:59,520 --> 00:29:04,740
+non mirror images كلام سليم ولا لأ؟ مش صورة بعض في
+
+316
+00:29:04,740 --> 00:29:10,720
+المرأة في الخصائص
+
+317
+00:29:10,720 --> 00:29:16,420
+الفيزيائية أكيد و الكيميائية بيختلفوا في كل شيء
+
+318
+00:29:16,420 --> 00:29:21,910
+صاروا مركبينواضح مركبين they have different
+
+319
+00:29:21,910 --> 00:29:24,810
+physical properties، واحد من نقطة غليانه مثلا
+
+320
+00:29:24,810 --> 00:29:29,970
+سبعين، التانه نقطة غليانه تسعين، يختلفوا، واضح
+
+321
+00:29:29,970 --> 00:29:37,080
+الفكرة؟الان البعض احيانا بيقول طيب وكتش انا ممكن
+
+322
+00:29:37,080 --> 00:29:42,040
+يكون عندى ظاهرة ال sesual trance وانتبه لها اكثر و
+
+323
+00:29:42,040 --> 00:29:47,880
+وكتش لأ يعني لما أخدنا هذا المركب اللى حطينا فيه
+
+324
+00:29:47,880 --> 00:29:53,180
+chlorine و chlorine هنا طبعا اكيد هنا في hydrogen
+
+325
+00:29:53,180 --> 00:29:59,760
+ماجيبناش سيرة sesual tranceجيبناه إيش صيرت Sis &
+
+326
+00:29:59,760 --> 00:30:05,580
+Trans؟ وسمناها one-one-dichlorocyclo
+
+327
+00:30:05,580 --> 00:30:11,080
+-propane كذلك الحالة لو أنا انطلقت من الاثيليل
+
+328
+00:30:11,080 --> 00:30:16,540
+وحطيت ذرتين كلور على ال carbon الأولى يعني كان
+
+329
+00:30:16,540 --> 00:30:19,600
+عندى هذا المركب carbon double bond carbon ..
+
+330
+00:30:22,850 --> 00:30:26,870
+لو كان عندى هذا المركب carbon double bond carbon
+
+331
+00:30:26,870 --> 00:30:32,450
+وحطيت ذرتين كلور على الموقع الأول وقلنا إيش هذا
+
+332
+00:30:32,450 --> 00:30:39,880
+بدنا نسميهone one dichloroethane one one
+
+333
+00:30:39,880 --> 00:30:44,680
+dichloroethane مظبوط ولا لأ الان جيبنا هانة صيرت
+
+334
+00:30:44,680 --> 00:30:50,740
+cis و trans هان اه هان اه طيب بيصير سؤال وكتش
+
+335
+00:30:50,740 --> 00:30:54,360
+بيكون عندى ظاهرة ال cis و ال trans كلها موجودة
+
+336
+00:30:54,360 --> 00:31:00,220
+وكتش لأ الجواب بسيطبطلّع على الطرفين اللي بيحملوا
+
+337
+00:31:00,220 --> 00:31:03,920
+الذرات اللي هم الطرفين ال double bond أو الطرفين
+
+338
+00:31:03,920 --> 00:31:08,760
+اللي هنا إذا كانت كل ذرة تحمل مجموعتين مختلفتين
+
+339
+00:31:08,760 --> 00:31:11,760
+بيكون عند السيس و ترانس يعني هاي ال double bond
+
+340
+00:31:11,760 --> 00:31:19,200
+هادي غير هادي إذا هدوله مختلفتان ولا لأ هادي غير
+
+341
+00:31:19,200 --> 00:31:24,910
+هادي هدول مختلفتان و هدول مختلفتانإذا في عندي أكيد
+
+342
+00:31:24,910 --> 00:31:28,970
+من هذا المركب sis و trans هذا ال sis كيف بدي أجيب
+
+343
+00:31:28,970 --> 00:31:36,230
+لل trans؟ بال rotation؟ خليني أقول لو جيبنا لكوا
+
+344
+00:31:36,230 --> 00:31:42,070
+سؤال كيف نحول مركب ال sis إلى ال trans؟ أو نقول
+
+345
+00:31:42,070 --> 00:31:46,070
+sis compounds can be converted to trans by
+
+346
+00:31:46,070 --> 00:31:50,810
+rotation هاي الدوران جادر يلوف؟ لأ طب لو بدي أخلي
+
+347
+00:31:50,810 --> 00:31:58,660
+هذا ال sis transbond breaking bond formation اذا
+
+348
+00:31:58,660 --> 00:32:03,740
+انا كيف بحول السسلة ل Trans بال bond breaking و
+
+349
+00:32:03,740 --> 00:32:07,220
+bond formation بكسر الروابط و بحطها من اول و جديد
+
+350
+00:32:07,220 --> 00:32:11,150
+بس الدوران لا يؤدي الى هذا الكلامهنا صرت ما أعطيكم
+
+351
+00:32:11,150 --> 00:32:15,190
+كمان معلومتين إضافيتين عن ظاهرة الـ sexual trance
+
+352
+00:32:15,190 --> 00:32:20,110
+عشان توجد كظاهرة لابد كل carbon من أطراف الـ
+
+353
+00:32:20,110 --> 00:32:26,170
+double bond تحمل مجموعتين مختلفتينواضح؟ و لو بدى
+
+354
+00:32:26,170 --> 00:32:32,790
+احول ال 6 والترانس لازم اعمل
+
+355
+00:32:32,790 --> 00:32:36,870
+bond breaking و bond formation هذا الكلام بينطبق
+
+356
+00:32:36,870 --> 00:32:40,550
+على ال alkenes اللي فيهم ظاهرة ال 6 والترانس و
+
+357
+00:32:40,550 --> 00:32:46,810
+بينطبق أيضا على ال cycloalkenes كل هذه مفاهيم
+
+358
+00:32:46,810 --> 00:32:54,970
+أساسية و مهمة جدا في فعلنا لهذه الظاهرةالـ
+
+359
+00:32:54,970 --> 00:32:58,130
+Stereoisomers أو الـ Diastereomers اللي هي ظاهرة
+
+360
+00:32:58,130 --> 00:33:02,910
+الـ cis والترانس مكان وجودها الـ Cycloalkynes و
+
+361
+00:33:02,910 --> 00:33:09,230
+الـ Alkenes شرط وجودها ان كل طرف من الأطراف تبعت
+
+362
+00:33:09,230 --> 00:33:14,670
+ال carbons المكونة للـ double bond بتحمل مجموعتين
+
+363
+00:33:14,670 --> 00:33:17,890
+مختلفتين عشان ايك لو حد انا بدي احكي عن ال cis
+
+364
+00:33:17,890 --> 00:33:22,420
+والترانس هذه ال carbon شو بتحمل؟نفس المجموعات، هذا
+
+365
+00:33:22,420 --> 00:33:26,000
+ال carbo شو بتحمل؟ هذا شو بتحمل؟ أنا مافيش عنده ال
+
+366
+00:33:26,000 --> 00:33:31,060
+cis و ال trans، خلاص هو مركّب واحد، واضح؟ شرط فكرة
+
+367
+00:33:31,060 --> 00:33:37,870
+ال cis و ال trans أنه يكون عندهع كل طرف من أطراف
+
+368
+00:33:37,870 --> 00:33:41,250
+ال carbon سواء في الحلقة أو في ال double bond
+
+369
+00:33:41,250 --> 00:33:45,510
+مجموعات مختلفة ولذلك لو سألنا مثلا يا ترى هذا
+
+370
+00:33:45,510 --> 00:33:49,210
+المركب ال carbon double bond carbon وحطين هنا CL و
+
+371
+00:33:49,210 --> 00:33:54,690
+هنا CL و هنا H و هنا CL هل هذا في منه cis و trans؟
+
+372
+00:33:54,690 --> 00:34:02,790
+لأ هذا فقط مركب واحد لأن هنا HCL مختلفة لكن نفس
+
+373
+00:34:02,790 --> 00:34:12,160
+الشيءو شرط ال sis و ال trans مختلفة مختلفة غير هيك
+
+374
+00:34:12,160 --> 00:34:18,320
+ما بنتكلمش عن sis و trans سواء كنا بنحكي في ال ال
+
+375
+00:34:18,320 --> 00:34:25,600
+keys أو كنا بنحكي في الحلقات ال cyclo ال keys
+
+376
+00:34:30,680 --> 00:34:36,320
+أتعمقنا كثير في الـ Cyclopropane لكن أخدنا معلومات
+
+377
+00:34:36,320 --> 00:34:42,820
+كثير مهمة بخصوص ظاهرة بتتكرر معنا سواء الآن أو في
+
+378
+00:34:42,820 --> 00:34:48,060
+المستقبل لما ندرس ال الكينز الآن لو إجيت لمركب
+
+379
+00:34:48,060 --> 00:34:50,380
+الـcyclobutane
+
+380
+00:34:53,020 --> 00:34:57,300
+كم هيدروجين فيه؟ أربع كربونات كل كربون تو
+
+381
+00:34:57,300 --> 00:35:03,960
+هيدروجين؟ تمانية التمانية they are equivalent يعني
+
+382
+00:35:03,960 --> 00:35:09,020
+لو كنت أعمل عليه monochlorination بطلع بس مركب
+
+383
+00:35:09,020 --> 00:35:14,340
+واحد لكن لو قلنا نبدأ بالcyclobutane ونعمل
+
+384
+00:35:14,340 --> 00:35:20,260
+dichlorination هيطلع عندنا أكيد عدد أكبر من
+
+385
+00:35:20,260 --> 00:35:24,940
+المركباتواضح؟ يعني انتوا تخيلوا مش كل شي بدنا
+
+386
+00:35:24,940 --> 00:35:28,500
+نفصله بدنا نسيب شي انتوا تجربوه في البيت يعني هي
+
+387
+00:35:28,500 --> 00:35:33,360
+عندى ذرة الكلور الأولى و هنا فيه H لو بدى أحط كلور
+
+388
+00:35:33,360 --> 00:35:41,880
+تانية ممكن أحطها على الموقع الأول اعمل one one
+
+389
+00:35:41,880 --> 00:35:46,200
+dichlorocyclopropane صحيه ولا لأ؟ ممكن أحطها على
+
+390
+00:35:46,200 --> 00:35:53,330
+الموقع التانيأو Trans ممكن احطه على الموقع التالت
+
+391
+00:35:53,330 --> 00:35:59,030
+ايضا SIS او Trans بمعنى في الحلقة مش ضروري مش
+
+392
+00:35:59,030 --> 00:36:02,830
+ضروري ان ال SIS و ال Trans يكونوا جانب بعض يعني
+
+393
+00:36:02,830 --> 00:36:09,910
+هاي تخيلوا هذا Cyclobutane تجاوزا هاي ذرتين لكلور
+
+394
+00:36:09,910 --> 00:36:15,960
+خلينا نتخيلهم باللون الأحمر هذا المركب اي مركبone
+
+395
+00:36:15,960 --> 00:36:22,040
+one-dichlorocyclobutane، الآن هذا المركّب one two
+
+396
+00:36:22,040 --> 00:36:30,660
+-cis، هذا one two-trans، هذا one three-cis، هذا
+
+397
+00:36:30,660 --> 00:36:36,200
+one three-transواضح؟ يعني مش ضروري ان ال sis و ال
+
+398
+00:36:36,200 --> 00:36:39,360
+trans في الحلقة انهم يكونوا جانب بعض ممكن يكونوا
+
+399
+00:36:39,360 --> 00:36:42,480
+على واحد اتنين او على واحد تلات في الحلقات الأكبر
+
+400
+00:36:42,480 --> 00:36:47,980
+ممكن يكونوا أبعد كمان واضح؟ بتظهر نقطة الحقيقة في
+
+401
+00:36:47,980 --> 00:36:54,020
+موضوع ال cyclobutane ان هل يا ترى ال cyclobutane
+
+402
+00:36:54,020 --> 00:37:00,440
+بلانربهذا الشكل؟ الجواب لو كنا بنطلع على الزوايا
+
+403
+00:37:00,440 --> 00:37:04,940
+تبعته بشكل دقيق هو مش planner هو شوية بيقول عنه
+
+404
+00:37:04,940 --> 00:37:09,500
+puckered يعني مثني شوية لجوا الان بيشبه ايش بهذا
+
+405
+00:37:09,500 --> 00:37:16,000
+الشكل الفراشة ال butterflyواضح؟ فالـ cyclobutane
+
+406
+00:37:16,000 --> 00:37:21,580
+is not a planar molecule مش موجود بهذا الشكل في
+
+407
+00:37:21,580 --> 00:37:27,640
+مستوى واحد لأ من ثاني شوية للداخل عامل زي الفراشة
+
+408
+00:37:27,640 --> 00:37:34,760
+بتعرفوا أنتوا كيف عادة بترسموا الفراشة؟ فأنا لو
+
+409
+00:37:34,760 --> 00:37:39,140
+بدأ أرسم ال cyclobutane بهذا الشكل بارسمه واحد
+
+410
+00:37:39,140 --> 00:37:41,840
+اتنين تلاتة أربع هذه الأربع كربونات
+
+411
+00:37:44,220 --> 00:37:51,580
+cyclobutane is not a planar molecule الان تقريبا
+
+412
+00:37:51,580 --> 00:37:58,240
+المعلومات بتصير تتكرر هنا قولنا زي الاش زي ال
+
+413
+00:37:58,240 --> 00:38:03,900
+butter fly اللي هي الفراشة طب لو بدى احكي عن
+
+414
+00:38:03,900 --> 00:38:08,000
+الcyclobutane معلومات ال cis و ال trans و ال
+
+415
+00:38:08,000 --> 00:38:13,160
+substitution نفس الشيءممكن تعملوا على اكثر من موقع
+
+416
+00:38:13,160 --> 00:38:19,400
+لكن لو كنت بده احط اول كلور العشرة هيدروجين هم
+
+417
+00:38:19,400 --> 00:38:24,800
+اكويفلانت عشان ايه لما بده اعمل monochlorination
+
+418
+00:38:24,800 --> 00:38:28,960
+يعني بس one كلور بده يطلع عندى مركب بعدين لما بده
+
+419
+00:38:28,960 --> 00:38:32,740
+اعمل dichlorination بطلع عندى اكثر من مركب
+
+420
+00:38:32,740 --> 00:38:36,900
+بإمكانكوا تحسبوهم و تجمعوهم طب يا تورا لو حكيت عن
+
+421
+00:38:36,900 --> 00:38:42,220
+الشكل تبعه هل هو planner؟الجواب لأ مش planner طب
+
+422
+00:38:42,220 --> 00:38:45,920
+هى زى إيش بيعمل الآن تخيلوا هى الحلقة الخماسية
+
+423
+00:38:45,920 --> 00:38:50,420
+شايفينها هى دى اللى أمامكوا حلقة خماسية ولا لأ؟
+
+424
+00:38:50,420 --> 00:38:57,600
+واحد تانين تلاتة أربعة خمسة هيك بتكون planner لكن
+
+425
+00:38:57,600 --> 00:39:03,100
+هى عاملة بهذا الشكل الآن هذا الشكل لو كنا نعطيه
+
+426
+00:39:03,100 --> 00:39:09,040
+اسمبنقول عنه non planner أكيد لكن إله اسم أمركوا
+
+427
+00:39:09,040 --> 00:39:17,720
+شفتوا ضرف مغلف رسالة مفتوح it is like an open
+
+428
+00:39:17,720 --> 00:39:23,380
+envelope فهذا الشكل لو قلنا لكوا عنه planner لأ
+
+429
+00:39:23,380 --> 00:39:29,640
+هتقولوا it is like an open envelope اللي هو ضرف
+
+430
+00:39:29,640 --> 00:39:37,370
+رسالة مفتوح لو كنتوا بتكونوا ترسموهبشكل فراغي open
+
+431
+00:39:37,370 --> 00:39:41,350
+envelope مش envelope ال .. الظرف تبع الرسالة و
+
+432
+00:39:41,350 --> 00:39:45,050
+الموضوع it is like an open envelope لو بدي ارسمه
+
+433
+00:39:45,050 --> 00:39:49,990
+بهذا الشكل بارسمه فال Cyclopropane is a planar
+
+434
+00:39:49,990 --> 00:39:56,970
+Cyclobutane لأ Cyclopentane لأ الان لو انتقلنا بعد
+
+435
+00:39:56,970 --> 00:40:00,980
+هيك لل Cyclohexaneلاحظوا ال Cyclohexane الكلام
+
+436
+00:40:00,980 --> 00:40:04,100
+اللي موجود عليه في الدنيا كتير جدا احنا بنعطيه
+
+437
+00:40:04,100 --> 00:40:09,880
+مختصر للمختصر عليه ليش؟ لأن عليه كلام كتير لو كان
+
+438
+00:40:09,880 --> 00:40:15,340
+بهذا الشكل بيكون planner هي حلقة سدسية شايفينها
+
+439
+00:40:15,340 --> 00:40:19,780
+الواقع ان ال Cyclohexane مش زي هيك لما نتعلم في
+
+440
+00:40:19,780 --> 00:40:25,100
+chapter 4 عن البنزين البنزين زي هيك plannerالبنزين
+
+441
+00:40:25,100 --> 00:40:33,820
+C6H6 بلانر لكن الـCyclohexane ليس مليكيوم بلانر مش
+
+442
+00:40:33,820 --> 00:40:38,520
+بلانر طب ها كيف بينوجد؟ ممكن ينوجد على أكثر من
+
+443
+00:40:38,520 --> 00:40:42,860
+هيئة هيئة بيقول عنها confirmation confirmation
+
+444
+00:40:42,860 --> 00:40:47,820
+هيئة بمعنى ممكن نمسكه بهذا الشكل لاحظوا نفس الحلقة
+
+445
+00:40:47,820 --> 00:40:52,200
+شايفين كيف أنا مسكها؟الان هذا الشكل اللي انا ماسكه
+
+446
+00:40:52,200 --> 00:40:59,000
+يشبه ماذا؟ القارب او الزورق بسمي انا هيئة القارب
+
+447
+00:40:59,000 --> 00:41:04,740
+boat confirmation boat confirmation موجود عندكم
+
+448
+00:41:04,740 --> 00:41:13,520
+ربما بهذا المكان شايفينه؟
+
+449
+00:41:14,650 --> 00:41:19,050
+بهذا الشكل بيرسم بسهولة boat conformation يمكن أن
+
+450
+00:41:19,050 --> 00:41:26,830
+يكون على هيئة القارب بهذا الشكل و يمكن أن يكون على
+
+451
+00:41:26,830 --> 00:41:34,270
+هيئة الكرسي لو تخيلته زي هيك هي كأنه هذا كرسي هي
+
+452
+00:41:34,270 --> 00:41:37,910
+الرجلين وهي القاعدة اللي الناس بيجلس عليها وهي
+
+453
+00:41:37,910 --> 00:41:42,100
+الظهرطبعا هذا ال chair confirmation و ال boat
+
+454
+00:41:42,100 --> 00:41:46,020
+confirmation بيجلبه يعني هذا الشكل زي ما بتكون
+
+455
+00:41:46,020 --> 00:41:51,040
+تماما معاكم الشمسية ال umbrella في يوم عاصف كيف
+
+456
+00:41:51,040 --> 00:41:56,960
+بتكون؟ بتجلب للأمام و للخلف؟ هاد العملية بسميها
+
+457
+00:41:56,960 --> 00:42:03,200
+عشان flipping الشكل لما بيصير يجلب بهذا الشكل لفوق
+
+458
+00:42:03,200 --> 00:42:06,940
+لتحت زي الشمسية ما بتعمل بسمي العملية عشان
+
+459
+00:42:06,940 --> 00:42:07,540
+flipping
+
+460
+00:42:10,670 --> 00:42:17,390
+flipping الآن ممكن الـcyclohexane يكون بلحظة boat
+
+461
+00:42:17,390 --> 00:42:22,970
+هذه تجلب لتحت صار chair لحظة هذا ال chair هيظهر
+
+462
+00:42:22,970 --> 00:42:26,790
+للخلف و الأرجل للأمام ممكن تجلب هذه الأرجل تصير
+
+463
+00:42:26,790 --> 00:42:31,830
+بهذا الشكل و بهذا الشكل هو في حالة تقلب دائم يعني
+
+464
+00:42:31,830 --> 00:42:37,390
+الذرات في حالة تقلب دائما تماما مثل مثل إيش شمسية
+
+465
+00:42:37,390 --> 00:42:41,930
+في مهب الريحمثل مثل ال umbrella أو الشمسية في ماب
+
+466
+00:42:41,930 --> 00:42:47,450
+بالريح إذا هو يمكن أن يوجد على هيئة القارب ويمكن
+
+467
+00:42:47,450 --> 00:42:54,680
+أن يوجد على هيئةالكرسي لـ Chair Conformation أو
+
+468
+00:42:54,680 --> 00:43:00,120
+Boat Conformation واضح؟ زي ما حكيت، كثير فيه
+
+469
+00:43:00,120 --> 00:43:04,080
+تفاصيل للهيدروجينات و التركيبة لكن احنا بنتجاوز
+
+470
+00:43:04,080 --> 00:43:08,780
+هذا الكلام، بنقف ان الـCyclohexane ممكن يكون على
+
+471
+00:43:08,780 --> 00:43:12,500
+شكل الـChair Conformation وبيعمل flipping، بيقلب
+
+472
+00:43:13,380 --> 00:43:19,880
+مرة تانية انا اكد عادى الظاهر هيه بهذا الشكل بيكون
+
+473
+00:43:19,880 --> 00:43:23,500
+share و بيصير boat و بيرجع ت share و ت share بهذا
+
+474
+00:43:23,500 --> 00:43:27,040
+الشكل و ت share بهذا الشكل هو في حالة تقلب ايش
+
+475
+00:43:27,040 --> 00:43:32,860
+دائم الان اي الأشكال اثبت معنى اثبت هنا انه بيقضي
+
+476
+00:43:32,860 --> 00:43:37,380
+في وقت كتير ال share ولا ال boat ال share بنقول
+
+477
+00:43:37,380 --> 00:43:43,580
+عنه is more stable than the boatmore stable معناه
+
+478
+00:43:43,580 --> 00:43:48,360
+more stable أنه أنا لو بتطلع عليه و هو بيجلب هو
+
+479
+00:43:48,360 --> 00:43:53,440
+يتقلب بين هذه الأشكال لكن يبقى لفترة أطول على هيئة
+
+480
+00:43:53,440 --> 00:43:58,580
+إيش الكرسي يبقى لفترة أطول على هيئة الكرسي الآن
+
+481
+00:43:58,580 --> 00:44:04,040
+عملية أنهليش لفترة أطول على هيئة الكرسي؟ ليش هذا
+
+482
+00:44:04,040 --> 00:44:08,140
+أثبت؟ ما إلى ذلك؟ هذا الكلام لطلبة مختصين في
+
+483
+00:44:08,140 --> 00:44:12,600
+الكيميا فيه تفصيل كتير، يعني اللي الآن بنحكيه بخمس
+
+484
+00:44:12,600 --> 00:44:17,480
+دقائق، بنعمله فصل كامل لطالب الكيميا يتعمق فيه
+
+485
+00:44:17,480 --> 00:44:20,140
+بالcyclohexane، لكن احنا الآن اللي بنايعه
+
+486
+00:44:20,140 --> 00:44:25,480
+الcyclohexaneكلام بسيط ان هو non planar molecule
+
+487
+00:44:25,480 --> 00:44:30,700
+يوجد فيه اكتر من conformation هيئة منها ال boat
+
+488
+00:44:30,700 --> 00:44:35,420
+conformation و ال chair conformation واضح ال boat
+
+489
+00:44:35,420 --> 00:44:39,120
+conformation و ال chair conformation اكتر من هيك
+
+490
+00:44:39,120 --> 00:44:45,770
+مابدناش نتكلم عن هذا الموضوعطبعا الكلام اللي هو
+
+491
+00:44:45,770 --> 00:44:50,290
+حكيناه عن الـcis و الـtrans في الحلقات الخماسية
+
+492
+00:44:50,290 --> 00:44:54,790
+والسوداسية والسبعية والربعية والثلاثية كله موجود
+
+493
+00:44:54,790 --> 00:45:00,910
+واضح؟ كله موجود أخر شغلة بدنا نتكلمها اليوم إن شاء
+
+494
+00:45:00,910 --> 00:45:09,660
+الله تفاعلات الالكانز تفاعلات الالكانزقليلة جدا،
+
+495
+00:45:09,660 --> 00:45:12,880
+عشانيك احنا بنقول الالكينز they are generally
+
+496
+00:45:12,880 --> 00:45:17,220
+inert، ايش يعني inert؟ يعني قليلة التفاعلات،
+
+497
+00:45:17,220 --> 00:45:21,540
+عشانيك كل اشي inert يستعمل ك solvent، يعني يستعمل
+
+498
+00:45:21,540 --> 00:45:25,680
+كمثيب عضوي، لأن الأشياء بتكون في قلبه و بتفعلش
+
+499
+00:45:25,680 --> 00:45:32,220
+معها، في تفاعل مشهور جدا للالكينز، ان الالكينز لو
+
+500
+00:45:32,220 --> 00:45:36,840
+حرقناهم في وجود الأكسجين، بيعطونا ثانو أكسيد كربون
+
+501
+00:45:36,840 --> 00:45:42,940
+وماءوهذا التفاعل هو تفاعل حرق الغاز المنزلي لما
+
+502
+00:45:42,940 --> 00:45:47,660
+احنا بنشعل الغاز هو تفاعل حرق على سبيل المثال
+
+503
+00:45:47,660 --> 00:45:53,220
+الوقود البنزين والديزل في السيارات كله الكان
+
+504
+00:45:53,220 --> 00:45:58,180
+بنحرقه في وجود ال oxygen بنسمي العملية combustion
+
+505
+00:45:58,180 --> 00:46:03,200
+إيش يعني combustion burning in the presence of
+
+506
+00:46:03,200 --> 00:46:09,540
+oxygen burning يعني burningin the presence of
+
+507
+00:46:09,540 --> 00:46:17,980
+oxygen ايش بيعطيني؟ ثاني أكسيد كربون وماء بدون ما
+
+508
+00:46:17,980 --> 00:46:21,480
+ندخل بتفاصيل الأرقام كيف توزن المعادلة مش الموضوع
+
+509
+00:46:21,480 --> 00:46:26,400
+احنا بهمنا الآن النتيجة ان الالكينز بصير التفاعل
+
+510
+00:46:26,400 --> 00:46:32,700
+مع الأكسجين تعطيتانو أكسيد كربون و ماء زائد و ربما
+
+511
+00:46:32,700 --> 00:46:37,880
+أهم من الشغلتين بالنسبة لنا ال heat الحرارة عشان
+
+512
+00:46:37,880 --> 00:46:41,380
+هيك حرق الغاز و حرق البنزين اللي بيعطيني حرارة
+
+513
+00:46:41,380 --> 00:46:45,700
+بشغل عليها موقد الغاز بمشي عليها السيارة كل هذه
+
+514
+00:46:45,700 --> 00:46:50,130
+الأشياءالشغل التاني أو التفاعل التاني ال
+
+515
+00:46:50,130 --> 00:46:54,270
+halogenation هو التفاعل مع ال halogens الكلور و
+
+516
+00:46:54,270 --> 00:46:58,690
+البرومي بشكل أساسي عادة يتم هذا التفاعل في وجود
+
+517
+00:46:58,690 --> 00:47:01,210
+الحرارة أو الضوء
+
+518
+00:47:17,340 --> 00:47:22,460
+كم عدد النواتج اللي بتطلع؟ يعتمد على أنواع
+
+519
+00:47:22,460 --> 00:47:27,240
+الهيدروجين يعني لو كان المركب اللي عندكم هو
+
+520
+00:47:27,240 --> 00:47:32,340
+البروبين زي ما احنا حكينا وين
+
+521
+00:47:32,340 --> 00:47:38,040
+هيحط ال chlorine؟ يا ع موقع واحد و ال chlorine و
+
+522
+00:47:38,040 --> 00:47:40,400
+البروبين يا ع موقع اتنين اتنين اتنين اتنين اتنين
+
+523
+00:47:40,400 --> 00:47:40,820
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+524
+00:47:40,820 --> 00:47:41,480
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+525
+00:47:41,480 --> 00:47:41,500
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+526
+00:47:41,500 --> 00:47:46,500
+اتنين اتنين اتنين اتنين اتنين اتنين ااو ايزوبروبل
+
+527
+00:47:46,500 --> 00:47:49,900
+اكلورايد لو نفس المراكب بيقولنا بيعمله
+
+528
+00:47:49,900 --> 00:47:56,090
+دايكلوريلاشينوين ممكن احض دارتين لكلور؟ يا على
+
+529
+00:47:56,090 --> 00:47:59,750
+نمرة واحد واحد بيصير one one dichlorobropane يا
+
+530
+00:47:59,750 --> 00:48:07,150
+على واحد واثنين يا ع اتنين واثنين او ع واحد واثنين
+
+531
+00:48:07,150 --> 00:48:11,170
+او ع واحد تلاتة اذا لو انا قلتلكم dichlorination
+
+532
+00:48:11,170 --> 00:48:16,210
+of a propane produces come isomers كي بتكون تعمله
+
+533
+00:48:16,210 --> 00:48:22,960
+و تجربه بالورقة و الجلمتستفيدوا من كل المعلومات
+
+534
+00:48:22,960 --> 00:48:28,720
+اللي حكيناها بمعنى لو كان السؤال عندكم عن cycle
+
+535
+00:48:28,720 --> 00:48:33,000
+بتعرفوا تجاوبوه احنا اليوم جاوبناها لـcyclopropane
+
+536
+00:48:33,000 --> 00:48:37,220
+قولنا الـ monochlorination بيعطينا كام مركب؟ واحد
+
+537
+00:48:37,220 --> 00:48:43,300
+ال-dichlorination بيعطينا كام مركب؟ تلاتةسمناهم
+
+538
+00:48:43,300 --> 00:48:48,640
+one one و one two six و one two .. Trans مظبوط ولا
+
+539
+00:48:48,640 --> 00:48:53,860
+لأ؟ و هكذا دائما ممكن يجيكم أسئلة و ممكن الأن
+
+540
+00:48:53,860 --> 00:48:58,540
+ماعطيكم سؤالين أنتوا تحلوهم لوحدكم تتدربوا عليهم و
+
+541
+00:48:58,540 --> 00:49:03,980
+بننهي فيهم المحاضرة لو مثلا قلنالكوا اعملونا لمركب
+
+542
+00:49:03,980 --> 00:49:11,980
+لبيوتينمونو إكلورينايشن ودايكلورينايشن تعملوه و
+
+543
+00:49:11,980 --> 00:49:16,400
+تسلمونا إياه و لهذا المُركّب لو تخيلتوا إنه في
+
+544
+00:49:16,400 --> 00:49:23,000
+عندكم مثل سايكلوبروبين شايفينه
+
+545
+00:49:23,000 --> 00:49:29,160
+المُركّب؟ إيش اسمه؟ مثل سايكلوبروبين اعملوله مونو
+
+546
+00:49:29,160 --> 00:49:34,510
+إكلورينايشنوDichlorination وشوفوا كم ناتج بيطلع
+
+547
+00:49:34,510 --> 00:49:38,230
+عندكم طبعا بتكونوا تنتبهوا ان الchlorination ممكن
+
+548
+00:49:38,230 --> 00:49:43,330
+يجي على المثل او على الحلقة بدي كل النواتج الممكنة
+
+549
+00:49:43,330 --> 00:49:47,830
+وهنا كل النواتج الممكنة هذا بحاجة انكوا تتدربوا
+
+550
+00:49:47,830 --> 00:49:52,700
+بشكل جيدو تعرفوا أنواع الهيدروجينز اللي موجودة و
+
+551
+00:49:52,700 --> 00:49:56,040
+تحددوا كام ناتج بيطلع عندهم من ال monochlorination
+
+552
+00:49:56,040 --> 00:50:00,340
+و ال dichlorination ترسموهم بعد ما ترسموهم انتبهوا
+
+553
+00:50:00,340 --> 00:50:05,180
+إذا في أشكال متشابهة انه ما تكرروهاش وبهيك بننهي
+
+554
+00:50:05,180 --> 00:50:06,040
+اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..27db1b25fd229653382ea829fa02b2ffef46e294
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4909, "start": 21.35, "end": 49.09, "text": "بسم الله الرحمن الرحيم نستأنف اليوم في موضوع ال alkanes و ال cycloalkanes زي ما بتعرفوا المرة الماضية أعطينا فكرة عن ال alkanes من ناحية التسمية و من ناحية بعض الخواص الفيزيائية و من ناحية تركيبها بمعنى عدد ذرات ال carbon و ال hydrogen", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 8717, 14851, 33456, 5172, 45595, 20498, 8978, 3714, 2407, 11242, 45367, 2423, 419, 5225, 279, 4032, 2423, 38154, 752, 667, 12779, 30767, 1829, 19446, 39894, 3615, 28480, 14407, 9673, 25720, 9673, 46958, 10632, 5551, 3615, 9566, 1829, 8315, 6156, 4117, 25720, 18871, 2423, 419, 5225, 279, 9154, 8717, 39319, 10632, 16712, 38251, 10632, 4032, 9154, 8717, 39319, 10632, 45030, 11242, 33962, 2407, 33546, 27188, 1829, 11622, 1829, 16373, 10632, 4032, 9154, 8717, 39319, 10632, 6055, 31747, 1829, 3555, 11296, 4724, 2304, 3615, 1863, 7578, 6225, 3215, 3215, 29910, 2288, 9307, 2423, 5954, 4032, 2423, 12697], 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"probability": 0.875}], "temperature": 1.0}, {"id": 19, "seek": 43892, "start": 416.2, "end": 438.92, "text": "نوع واحد بمعنى لو انا امسكت ذرة كلور خلّينا نفترض هذه لمخ اللون الأخضر بدي اشيل اي هيدروجين و احط مكانها كلور مش هذا تفاعل ابدال بدلنا هيدروجين بكلور الان لو شيلت هذه و حطيت كلور هيطلع عندى مركب", "tokens": [1863, 45367, 36764, 24401, 4724, 2304, 3615, 1863, 7578, 45164, 1975, 8315, 1975, 2304, 3794, 4117, 2655, 29910, 25720, 28242, 13063, 16490, 1211, 11703, 9957, 995, 8717, 5172, 2655, 43042, 29538, 32767, 9778, 13672, 11536, 16247, 9778, 11242, 2288, 4724, 16254, 1975, 8592, 26895, 1975, 1829, 8032, 25708, 2288, 29245, 9957, 4032, 1975, 5016, 9566, 3714, 41361, 11296, 28242, 13063, 37893, 23758, 6055, 5172, 995, 30241, 1975, 44510, 6027, 47525, 1211, 8315, 8032, 25708, 2288, 29245, 9957, 4724, 28820, 13063, 2423, 7649, 45164, 13412, 26895, 2655, 29538, 4032, 11331, 9566, 36081, 28242, 13063, 39896, 9566, 1211, 3615, 43242, 7578, 3714, 31747, 3555], "avg_logprob": 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0.71728515625}, {"start": 424.08, "end": 424.4, "word": " لمخ", "probability": 0.846435546875}, {"start": 424.4, "end": 424.78, "word": " اللون", "probability": 0.6484375}, {"start": 424.78, "end": 425.36, "word": " الأخضر", "probability": 0.9886474609375}, {"start": 425.36, "end": 425.94, "word": " بدي", "probability": 0.7322998046875}, {"start": 425.94, "end": 426.32, "word": " اشيل", "probability": 0.8197428385416666}, {"start": 426.32, "end": 426.6, "word": " اي", "probability": 0.7666015625}, {"start": 426.6, "end": 427.34, "word": " هيدروجين", "probability": 0.875}, {"start": 427.34, "end": 427.52, "word": " و", "probability": 0.71044921875}, {"start": 427.52, "end": 427.8, "word": " احط", "probability": 0.85888671875}, {"start": 427.8, "end": 428.52, "word": " مكانها", "probability": 0.9874674479166666}, {"start": 428.52, "end": 429.36, "word": " كلور", "probability": 0.86572265625}, {"start": 429.36, "end": 429.74, "word": " مش", "probability": 0.89306640625}, {"start": 429.74, 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"probability": 0.9899088541666666}, {"start": 468.42, "end": 469.38, "word": " وعشان", "probability": 0.75347900390625}, {"start": 469.38, "end": 470.88, "word": " هيك", "probability": 0.957275390625}, {"start": 470.88, "end": 471.7, "word": " بنقدر", "probability": 0.86279296875}, {"start": 471.7, "end": 472.2, "word": " نتبع", "probability": 0.9676513671875}, {"start": 472.2, "end": 472.98, "word": " هالكلام", "probability": 0.8323974609375}, {"start": 472.98, "end": 473.84, "word": " جملة", "probability": 0.9554036458333334}, {"start": 473.84, "end": 474.4, "word": " تانية", "probability": 0.97412109375}, {"start": 474.4, "end": 476.18, "word": " monochlorination", "probability": 0.7393798828125}, {"start": 476.18, "end": 476.44, "word": " of", "probability": 0.9462890625}, {"start": 476.44, "end": 477.34, "word": " cyclopropane", "probability": 0.81298828125}, {"start": 477.34, "end": 477.8, "word": " معناه", "probability": 0.841796875}, {"start": 477.8, "end": 478.8, "word": " monochlorination", "probability": 0.8150634765625}, {"start": 478.8, "end": 478.98, "word": " إن", "probability": 0.21044921875}, {"start": 478.98, "end": 479.1, "word": " أنا", "probability": 0.77001953125}, {"start": 479.1, "end": 479.6, "word": " أبدل", "probability": 0.9073893229166666}, {"start": 479.6, "end": 480.34, "word": " هيدروجين", "probability": 0.839697265625}, {"start": 480.34, "end": 481.2, "word": " واحدة", "probability": 0.966796875}, {"start": 481.2, "end": 481.92, "word": " بكلور", "probability": 0.869140625}, {"start": 481.92, "end": 482.3, "word": " واحدة", "probability": 0.98046875}, {"start": 482.3, "end": 482.46, "word": " شو", "probability": 0.747802734375}, {"start": 482.46, "end": 482.9, "word": " بسمي", "probability": 0.9591471354166666}, {"start": 482.9, "end": 484.38, "word": " العملية؟", "probability": 0.8255615234375}, {"start": 484.38, "end": 485.68, "word": " mono", "probability": 0.51123046875}, {"start": 485.68, "end": 486.92, "word": " يعني", "probability": 0.8720703125}, {"start": 486.92, "end": 487.6, "word": " أحادي", "probability": 0.7562255859375}, {"start": 487.6, "end": 491.12, "word": " monochlorination", "probability": 0.675750732421875}, {"start": 491.12, "end": 491.82, "word": " إيش", "probability": 0.83837890625}, {"start": 491.82, "end": 492.02, "word": " يعني", "probability": 0.9736328125}, {"start": 492.02, "end": 493.3, "word": " chlorination؟", "probability": 0.8995768229166666}], "temperature": 1.0}, {"id": 22, "seek": 52090, "start": 494.82, "end": 520.9, "text": "تفاعل مع الكلور تفاعل الـ Cyclopropane مع الكلور إبدال بذرة واحدة Monochlorination of Cyclopropane produces only one product بيطلع فقط ناتج واحد، شو سميته أنا؟ Chlorocyclopropane واضح؟", "tokens": [2655, 5172, 995, 30241, 20449, 33251, 1211, 13063, 6055, 5172, 995, 30241, 2423, 39184, 49173, 404, 1513, 1929, 20449, 33251, 1211, 13063, 11933, 44510, 6027, 4724, 8848, 25720, 36764, 24401, 3660, 4713, 8997, 6746, 2486, 295, 49173, 404, 1513, 1929, 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"probability": 0.91748046875}, {"start": 1022.31, "end": 1022.95, "word": " bonding", "probability": 0.92333984375}, {"start": 1022.95, "end": 1024.03, "word": " لكن", "probability": 0.8642578125}, {"start": 1024.03, "end": 1024.45, "word": " اين", "probability": 0.8271484375}, {"start": 1024.45, "end": 1025.69, "word": " الاختلاف؟", "probability": 0.9412434895833334}, {"start": 1025.69, "end": 1026.19, "word": " بالشكل", "probability": 0.8914388020833334}, {"start": 1026.19, "end": 1026.31, "word": " ..", "probability": 0.470703125}, {"start": 1026.31, "end": 1026.97, "word": " بالشكل", "probability": 0.9832356770833334}, {"start": 1026.97, "end": 1027.93, "word": " الفراغي", "probability": 0.9572265625}, {"start": 1027.93, "end": 1028.39, "word": " they", "probability": 0.90869140625}, {"start": 1028.39, "end": 1028.67, "word": " have", "probability": 0.96826171875}, {"start": 1028.67, "end": 1028.97, "word": " the", "probability": 0.94775390625}, {"start": 1028.97, "end": 1029.29, "word": " same", "probability": 0.92333984375}, {"start": 1029.29, "end": 1029.87, "word": " bonding", "probability": 0.912109375}], "temperature": 1.0}, {"id": 42, "seek": 104633, "start": 1030.57, "end": 1046.33, "text": "but different arrangement in space شكلهم بالفراغ مختلف ان هدول الذرتين ع جهة واحدة و هدول الذرتين ع جهات متعاكسة بس اتنين ع واحد اتنين هذا النوع اللي احنا ايش سمنا stereo isomers", "tokens": [5955, 819, 17620, 294, 1901, 13412, 28820, 16095, 20666, 5172, 2288, 5718, 118, 3714, 46456, 46538, 16472, 8032, 3215, 12610, 32545, 2288, 2655, 9957, 6225, 10874, 3224, 3660, 36764, 24401, 3660, 4032, 8032, 3215, 12610, 32545, 43500, 9957, 6225, 10874, 3224, 9307, 44650, 3615, 995, 4117, 3794, 3660, 4724, 3794, 1975, 2655, 1863, 9957, 6225, 36764, 24401, 1975, 2655, 1863, 9957, 23758, 28239, 45367, 13672, 1829, 1975, 5016, 8315, 1975, 1829, 8592, 8608, 2304, 8315, 29029, 307, 298, 433], "avg_logprob": -0.22851562071591616, "compression_ratio": 1.6337209302325582, 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"end": 1036.65, "word": " ع", "probability": 0.77001953125}, {"start": 1036.65, "end": 1036.91, "word": " جهة", "probability": 0.8271484375}, {"start": 1036.91, "end": 1037.61, "word": " واحدة", "probability": 0.95068359375}, {"start": 1037.61, "end": 1037.89, "word": " و", "probability": 0.60888671875}, {"start": 1037.89, "end": 1038.11, "word": " هدول", "probability": 0.9449869791666666}, {"start": 1038.11, "end": 1038.59, "word": " الذرتين", "probability": 0.8297526041666666}, {"start": 1038.59, "end": 1038.71, "word": " ع", "probability": 0.962890625}, {"start": 1038.71, "end": 1039.01, "word": " جهات", "probability": 0.9156901041666666}, {"start": 1039.01, "end": 1039.91, "word": " متعاكسة", "probability": 0.9178059895833334}, {"start": 1039.91, "end": 1040.33, "word": " بس", "probability": 0.837158203125}, {"start": 1040.33, "end": 1040.69, "word": " اتنين", "probability": 0.75091552734375}, {"start": 1040.69, "end": 1040.83, "word": " ع", "probability": 0.7421875}, {"start": 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قلنا ال stereo isomers they have the same bonding يعني لما أجي أقول الكلور وين؟ ع واحد و التانية ع اتنين في التاني الكلور وين؟ ع واحد و التانية ع اتنين اذا they have the same bonding طب وين اختلفوا؟", "tokens": [3224, 15730, 28239, 45367, 13672, 1829, 8608, 2304, 8315, 3224, 29029, 307, 298, 433, 5296, 15042, 11331, 4117, 1829, 8315, 15844, 2423, 307, 14301, 1434, 12174, 1211, 8315, 2423, 29029, 307, 298, 433, 436, 362, 264, 912, 28824, 37495, 22653, 5296, 15042, 5551, 7435, 1829, 5551, 39648, 33251, 1211, 13063, 4032, 9957, 22807, 6225, 36764, 24401, 4032, 16712, 7649, 10632, 6225, 1975, 2655, 1863, 9957, 8978, 16712, 7649, 1829, 33251, 1211, 13063, 4032, 9957, 22807, 6225, 36764, 24401, 4032, 16712, 7649, 10632, 6225, 1975, 2655, 1863, 9957, 1975, 15730, 436, 362, 264, 912, 28824, 23032, 3555, 4032, 9957, 1975, 46456, 46538, 14407, 22807], "avg_logprob": -0.15256911157988584, "compression_ratio": 1.9748743718592965, "no_speech_prob": 0.0, "words": [{"start": 1047.01, "end": 1047.49, 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{"start": 1057.95, "end": 1058.69, "word": " الكلور", "probability": 0.7347005208333334}, {"start": 1058.69, "end": 1059.01, "word": " وين؟", "probability": 0.8857421875}, {"start": 1059.01, "end": 1059.09, "word": " ع", "probability": 0.75732421875}, {"start": 1059.09, "end": 1059.55, "word": " واحد", "probability": 0.9248046875}, {"start": 1059.55, "end": 1059.69, "word": " و", "probability": 0.5}, {"start": 1059.69, "end": 1060.27, "word": " التانية", "probability": 0.869140625}, {"start": 1060.27, "end": 1060.69, "word": " ع", "probability": 0.8359375}, {"start": 1060.69, "end": 1061.09, "word": " اتنين", "probability": 0.8831787109375}, {"start": 1061.09, "end": 1061.67, "word": " في", "probability": 0.52978515625}, {"start": 1061.67, "end": 1062.07, "word": " التاني", "probability": 0.919921875}, {"start": 1062.07, "end": 1062.49, "word": " الكلور", "probability": 0.94189453125}, {"start": 1062.49, "end": 1062.97, "word": " وين؟", "probability": 0.98388671875}, {"start": 1062.97, "end": 1063.13, "word": " ع", "probability": 0.96728515625}, {"start": 1063.13, "end": 1063.95, "word": " واحد", "probability": 0.978271484375}, {"start": 1063.95, "end": 1064.11, "word": " و", "probability": 0.9580078125}, {"start": 1064.11, "end": 1064.63, "word": " التانية", "probability": 0.9803059895833334}, {"start": 1064.63, "end": 1065.31, "word": " ع", "probability": 0.9091796875}, {"start": 1065.31, "end": 1065.63, "word": " اتنين", "probability": 0.9495849609375}, {"start": 1065.63, "end": 1065.87, "word": " اذا", "probability": 0.6214599609375}, {"start": 1065.87, "end": 1066.05, "word": " they", "probability": 0.93115234375}, {"start": 1066.05, "end": 1066.31, "word": " have", "probability": 0.97216796875}, {"start": 1066.31, "end": 1066.47, "word": " the", "probability": 0.93994140625}, {"start": 1066.47, "end": 1066.75, "word": " same", "probability": 0.919921875}, {"start": 1066.75, "end": 1067.29, "word": " bonding", "probability": 0.90771484375}, {"start": 1067.29, "end": 1067.79, "word": " طب", "probability": 0.902099609375}, {"start": 1067.79, "end": 1067.97, "word": " وين", "probability": 0.988525390625}, {"start": 1067.97, "end": 1068.81, "word": " اختلفوا؟", "probability": 0.97451171875}], "temperature": 1.0}, {"id": 44, "seek": 109821, "start": 1069.67, "end": 1098.21, "text": "بشكل برفرات اه هدول ع واحد و اتنين ع جهة واحدة على واحد و اتنين ع جهتين مختلفتين هذه بنسميها different arrangement in space اذا العلاقة بين هذا ال cis و ال trans they are stereo isomers لاحظوا لو قلتلكوا ما العلاقة بين هذا المركب و هذا المركب في ال isomers", "tokens": [3555, 8592, 28820, 4724, 2288, 5172, 2288, 9307, 1975, 3224, 8032, 3215, 12610, 6225, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 6225, 10874, 3224, 3660, 36764, 24401, 3660, 15844, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 6225, 10874, 3224, 2655, 9957, 3714, 46456, 46538, 2655, 9957, 29538, 44945, 38251, 1829, 11296, 819, 17620, 294, 1901, 1975, 15730, 18863, 15040, 28671, 49374, 23758, 2423, 37847, 4032, 2423, 1145, 436, 366, 29029, 307, 298, 433, 20193, 5016, 19913, 14407, 45164, 12174, 1211, 2655, 23275, 14407, 19446, 18863, 15040, 28671, 49374, 23758, 9673, 31747, 3555, 4032, 23758, 9673, 31747, 3555, 8978, 2423, 307, 298, 433], "avg_logprob": -0.1903822835787986, "compression_ratio": 1.8957345971563981, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1069.67, "end": 1070.31, "word": "بشكل", "probability": 0.7825520833333334}, {"start": 1070.31, "end": 1070.87, "word": " برفرات", "probability": 0.77451171875}, {"start": 1070.87, "end": 1071.21, "word": " اه", "probability": 0.5272216796875}, {"start": 1071.21, "end": 1071.51, "word": " هدول", "probability": 0.8868815104166666}, {"start": 1071.51, "end": 1071.63, "word": " ع", "probability": 0.6865234375}, {"start": 1071.63, "end": 1071.93, "word": " واحد", "probability": 0.7841796875}, {"start": 1071.93, "end": 1072.09, "word": " و", "probability": 0.95263671875}, {"start": 1072.09, "end": 1072.35, "word": " اتنين", "probability": 0.930419921875}, {"start": 1072.35, "end": 1072.55, "word": " ع", "probability": 0.82373046875}, {"start": 1072.55, "end": 1072.73, "word": " جهة", "probability": 0.88134765625}, {"start": 1072.73, "end": 1073.47, "word": " واحدة", "probability": 0.9435221354166666}, {"start": 1073.47, "end": 1074.09, "word": " على", "probability": 0.308837890625}, {"start": 1074.09, "end": 1074.39, "word": " واحد", "probability": 0.97900390625}, {"start": 1074.39, "end": 1074.53, "word": " و", "probability": 0.95361328125}, {"start": 1074.53, "end": 1074.73, "word": " اتنين", "probability": 0.9683837890625}, {"start": 1074.73, "end": 1074.89, "word": " ع", "probability": 0.8427734375}, {"start": 1074.89, "end": 1075.29, "word": " جهتين", "probability": 0.95166015625}, {"start": 1075.29, "end": 1076.23, "word": " مختلفتين", "probability": 0.97578125}, {"start": 1076.23, "end": 1076.61, "word": " هذه", "probability": 0.322021484375}, {"start": 1076.61, "end": 1077.25, "word": " بنسميها", "probability": 0.9002685546875}, {"start": 1077.25, "end": 1077.63, "word": " different", "probability": 0.7822265625}, {"start": 1077.63, "end": 1078.65, "word": " arrangement", "probability": 0.7919921875}, {"start": 1078.65, "end": 1079.09, "word": " in", "probability": 0.95068359375}, {"start": 1079.09, "end": 1080.29, "word": " space", "probability": 0.90625}, {"start": 1080.29, "end": 1080.99, "word": " اذا", "probability": 0.64306640625}, {"start": 1080.99, "end": 1081.91, "word": " العلاقة", "probability": 0.9619140625}, {"start": 1081.91, "end": 1082.17, "word": " بين", "probability": 0.9677734375}, {"start": 1082.17, "end": 1082.65, "word": " هذا", "probability": 0.87060546875}, {"start": 1082.65, "end": 1082.99, "word": " ال", "probability": 0.88037109375}, {"start": 1082.99, "end": 1083.33, "word": " cis", "probability": 0.383056640625}, {"start": 1083.33, "end": 1083.71, "word": " و", "probability": 0.62353515625}, {"start": 1083.71, "end": 1083.79, "word": " ال", "probability": 0.47314453125}, {"start": 1083.79, "end": 1084.49, "word": " trans", "probability": 0.67724609375}, {"start": 1084.49, "end": 1085.05, "word": " they", "probability": 0.78662109375}, {"start": 1085.05, "end": 1085.69, "word": " are", "probability": 0.966796875}, {"start": 1085.69, "end": 1087.85, "word": " stereo", "probability": 0.468017578125}, {"start": 1087.85, "end": 1088.89, "word": " isomers", "probability": 0.9158528645833334}, {"start": 1088.89, "end": 1092.07, "word": " لاحظوا", "probability": 0.81121826171875}, {"start": 1092.07, "end": 1092.45, "word": " لو", "probability": 0.9384765625}, {"start": 1092.45, "end": 1092.95, "word": " قلتلكوا", "probability": 0.93720703125}, {"start": 1092.95, "end": 1093.03, "word": " ما", "probability": 0.79345703125}, {"start": 1093.03, "end": 1093.65, "word": " العلاقة", "probability": 0.9588216145833334}, {"start": 1093.65, "end": 1093.95, "word": " بين", "probability": 0.84521484375}, {"start": 1093.95, "end": 1094.39, "word": " هذا", "probability": 0.95751953125}, {"start": 1094.39, "end": 1095.09, "word": " المركب", "probability": 0.9069010416666666}, {"start": 1095.09, "end": 1095.19, "word": " و", "probability": 0.88720703125}, {"start": 1095.19, "end": 1095.47, "word": " هذا", "probability": 0.95166015625}, {"start": 1095.47, "end": 1096.93, "word": " المركب", "probability": 0.9860026041666666}, {"start": 1096.93, "end": 1097.35, "word": " في", "probability": 0.89013671875}, {"start": 1097.35, "end": 1097.47, "word": " ال", "probability": 0.884765625}, {"start": 1097.47, "end": 1098.21, "word": " isomers", "probability": 0.9640299479166666}], "temperature": 1.0}, {"id": 45, "seek": 110397, "start": 1099.61, "end": 1103.97, "text": "هنا they have different bonding و different names", "tokens": [3224, 8315, 436, 362, 819, 28824, 4032, 819, 5288], "avg_logprob": -0.35117186307907106, "compression_ratio": 1.0192307692307692, "no_speech_prob": 0.0, "words": [{"start": 1099.61, "end": 1100.09, "word": "هنا", "probability": 0.737548828125}, {"start": 1100.09, "end": 1100.35, "word": " they", "probability": 0.306884765625}, {"start": 1100.35, "end": 1100.65, "word": " have", "probability": 0.96044921875}, {"start": 1100.65, "end": 1101.19, "word": " different", "probability": 0.95068359375}, {"start": 1101.19, "end": 1101.73, "word": " bonding", "probability": 0.7197265625}, {"start": 1101.73, "end": 1102.87, "word": " و", "probability": 0.8505859375}, {"start": 1102.87, "end": 1103.27, "word": " different", "probability": 0.84814453125}, {"start": 1103.27, "end": 1103.97, "word": " names", "probability": 0.89599609375}], "temperature": 1.0}, {"id": 46, "seek": 113085, "start": 1105.94, "end": 1130.86, "text": "ذرتين الكلور على واحد و واحد وعشان هيك سميته one one dichlorocyclopropane هنا ذرتين الكلور على واحد و اتنين هذا ال same bonding ولا different bonding different bonding ال different bonding أدى إلى different names أنا لما حددت مواقع الكلور قلت one one هنا قلت one two إذا هذا المركب و هذا المركب", "tokens": [8848, 43500, 9957, 33251, 1211, 13063, 15844, 36764, 24401, 4032, 36764, 24401, 4032, 3615, 8592, 7649, 39896, 4117, 8608, 2304, 36081, 3224, 472, 472, 10390, 6746, 31078, 3474, 404, 1513, 1929, 34105, 29910, 43500, 9957, 33251, 1211, 13063, 15844, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 23758, 2423, 912, 28824, 49429, 819, 28824, 819, 28824, 2423, 819, 28824, 5551, 3215, 7578, 30731, 819, 5288, 41850, 5296, 15042, 11331, 3215, 3215, 2655, 3714, 14407, 4587, 3615, 33251, 1211, 13063, 12174, 1211, 2655, 472, 472, 34105, 12174, 1211, 2655, 472, 732, 11933, 15730, 23758, 9673, 31747, 3555, 4032, 23758, 9673, 31747, 3555], "avg_logprob": -0.23746906530739056, "compression_ratio": 2.0531400966183573, "no_speech_prob": 0.0, "words": [{"start": 1105.94, "end": 1106.58, "word": "ذرتين", "probability": 0.6253255208333334}, {"start": 1106.58, "end": 1107.02, "word": " الكلور", "probability": 0.7620442708333334}, {"start": 1107.02, "end": 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1129.8, "word": " و", "probability": 0.73291015625}, {"start": 1129.8, "end": 1130.1, "word": " هذا", "probability": 0.93798828125}, {"start": 1130.1, "end": 1130.86, "word": " المركب", "probability": 0.9856770833333334}], "temperature": 1.0}, {"id": 47, "seek": 115911, "start": 1133.14, "end": 1159.12, "text": "صحيح مكونين من نفس الذرات لكن فيهم different bonding و different names فالعلاقة بين ال 11-dichlorocyclopropane و ال 12-dichlorocyclopropane they are structural isomers و كذلك العلاقة بين هذا و هذا لكن لو قلت العلاقة بين ال cis و ال trans they are stereo isomers", "tokens": [9381, 5016, 1829, 5016, 3714, 30544, 9957, 9154, 8717, 36178, 32545, 2288, 9307, 44381, 8978, 16095, 819, 28824, 4032, 819, 5288, 6156, 6027, 3615, 15040, 28671, 49374, 2423, 2975, 12, 67, 480, 6746, 31078, 3474, 404, 1513, 1929, 4032, 2423, 2272, 12, 67, 480, 6746, 31078, 3474, 404, 1513, 1929, 436, 366, 15067, 307, 298, 433, 4032, 9122, 8848, 23275, 18863, 15040, 28671, 49374, 23758, 4032, 23758, 44381, 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"-dichlorocyclopropane", "probability": 0.9656575520833334}, {"start": 1146.42, "end": 1146.64, "word": " they", "probability": 0.28173828125}, {"start": 1146.64, "end": 1147.16, "word": " are", "probability": 0.96337890625}, {"start": 1147.16, "end": 1148.5, "word": " structural", "probability": 0.78466796875}, {"start": 1148.5, "end": 1149.52, "word": " isomers", "probability": 0.9651692708333334}, {"start": 1149.52, "end": 1149.92, "word": " و", "probability": 0.92626953125}, {"start": 1149.92, "end": 1150.38, "word": " كذلك", "probability": 0.9562174479166666}, {"start": 1150.38, "end": 1150.92, "word": " العلاقة", "probability": 0.9830729166666666}, {"start": 1150.92, "end": 1151.18, "word": " بين", "probability": 0.97021484375}, {"start": 1151.18, "end": 1151.48, "word": " هذا", "probability": 0.794921875}, {"start": 1151.48, "end": 1151.64, "word": " و", "probability": 0.7451171875}, {"start": 1151.64, "end": 1151.9, "word": " هذا", "probability": 0.94384765625}, {"start": 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"word": " stereo", "probability": 0.71875}, {"start": 1158.0, "end": 1159.12, "word": " isomers", "probability": 0.95947265625}], "temperature": 1.0}, {"id": 48, "seek": 117360, "start": 1161.81, "end": 1173.61, "text": "Same bonding but different arrangement in space هي تعريف الـ Stereoisomers نفس الإرتباط ولكن يختلف فيه الشكل بالفراغ", "tokens": [50, 529, 28824, 457, 819, 17620, 294, 1901, 39896, 37279, 16572, 5172, 2423, 39184, 745, 323, 7376, 298, 433, 8717, 36178, 33688, 43500, 3555, 41193, 35525, 19452, 7251, 46456, 46538, 8978, 3224, 25124, 28820, 20666, 5172, 2288, 5718, 118], "avg_logprob": -0.3025390639901161, "compression_ratio": 1.1666666666666667, "no_speech_prob": 0.0, "words": [{"start": 1161.81, "end": 1162.49, "word": "Same", "probability": 0.57391357421875}, {"start": 1162.49, "end": 1163.37, "word": " bonding", "probability": 0.845703125}, {"start": 1163.37, "end": 1164.01, "word": " but", "probability": 0.481201171875}, {"start": 1164.01, "end": 1164.71, "word": " different", "probability": 0.80908203125}, {"start": 1164.71, "end": 1165.43, "word": " arrangement", "probability": 0.6201171875}, {"start": 1165.43, "end": 1165.69, "word": " in", "probability": 0.91845703125}, {"start": 1165.69, "end": 1166.07, "word": " space", "probability": 0.86962890625}, {"start": 1166.07, "end": 1166.21, "word": " هي", "probability": 0.1185302734375}, {"start": 1166.21, "end": 1166.63, "word": " تعريف", "probability": 0.9830729166666666}, {"start": 1166.63, "end": 1166.83, "word": " الـ", "probability": 0.5621337890625}, {"start": 1166.83, "end": 1167.79, "word": " Stereoisomers", "probability": 0.792431640625}, {"start": 1167.79, "end": 1168.81, "word": " نفس", "probability": 0.94873046875}, {"start": 1168.81, "end": 1169.59, "word": " الإرتباط", "probability": 0.89111328125}, {"start": 1169.59, "end": 1170.01, "word": " ولكن", "probability": 0.88134765625}, {"start": 1170.01, "end": 1170.55, "word": " يختلف", "probability": 0.9855143229166666}, {"start": 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1184.59, "end": 1185.71, "word": " Diastereomers", "probability": 0.72158203125}, {"start": 1185.71, "end": 1186.67, "word": " هنتعلمه", "probability": 0.8330078125}, {"start": 1186.67, "end": 1187.05, "word": " و", "probability": 0.85107421875}, {"start": 1187.05, "end": 1187.27, "word": " نوع", "probability": 0.9150390625}, {"start": 1187.27, "end": 1187.53, "word": " منهم", "probability": 0.990234375}, {"start": 1187.53, "end": 1188.15, "word": " بنسميه", "probability": 0.938720703125}, {"start": 1188.15, "end": 1188.83, "word": " Enantiomers", "probability": 0.79083251953125}, {"start": 1188.83, "end": 1189.67, "word": " الآن", "probability": 0.593994140625}, {"start": 1189.67, "end": 1190.59, "word": " هدولة", "probability": 0.7301025390625}, {"start": 1190.59, "end": 1191.71, "word": " المركبين", "probability": 0.916015625}, {"start": 1191.71, "end": 1192.93, "word": " مثال", "probability": 0.9912109375}, {"start": 1192.93, "end": 1193.77, "word": " لأحد", "probability": 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9307, 7435, 40294, 29538, 6225, 4117, 3794, 11296, 37037, 24192, 2423, 3224, 25708, 2288, 29245, 9957, 4724, 9307, 7435, 40294, 29538, 6225, 4117, 3794, 11296, 37495, 22653, 5296, 24401, 29538, 28239, 47432, 3660], "avg_logprob": -0.22639973709980646, "compression_ratio": 1.910179640718563, "no_speech_prob": 0.0, "words": [{"start": 1297.28, "end": 1297.86, "word": "الان", "probability": 0.866455078125}, {"start": 1297.86, "end": 1298.32, "word": " لو", "probability": 0.85888671875}, {"start": 1298.32, "end": 1298.72, "word": " اتيت", "probability": 0.69873046875}, {"start": 1298.72, "end": 1298.86, "word": " يا", "probability": 0.6943359375}, {"start": 1298.86, "end": 1299.22, "word": " تورا", "probability": 0.8128255208333334}, {"start": 1299.22, "end": 1300.48, "word": " اتسألت", "probability": 0.79034423828125}, {"start": 1300.48, "end": 1300.86, "word": " هل", "probability": 0.894287109375}, {"start": 1300.86, "end": 1301.4, "word": " هدولة", "probability": 0.6912841796875}, {"start": 1301.4, "end": 1301.56, "word": " من", "probability": 0.97705078125}, {"start": 1301.56, "end": 1302.44, "word": " الاساس", "probability": 0.8211263020833334}, {"start": 1302.44, "end": 1303.26, "word": " صورة", "probability": 0.9900716145833334}, {"start": 1303.26, "end": 1303.8, "word": " مرآه", "probability": 0.77919921875}, {"start": 1303.8, "end": 1303.94, "word": " ولا", "probability": 0.82421875}, {"start": 1303.94, "end": 1304.18, "word": " مش", "probability": 0.9248046875}, {"start": 1304.18, "end": 1304.58, "word": " صورة", "probability": 0.9806315104166666}, {"start": 1304.58, "end": 1305.24, "word": " مرآه؟", "probability": 0.8777262369791666}, {"start": 1305.24, "end": 1306.6, "word": " لاحظوا", "probability": 0.8853759765625}, {"start": 1306.6, "end": 1307.14, "word": " يمكن", "probability": 0.88623046875}, {"start": 1307.14, "end": 1307.36, "word": " هنا", "probability": 0.81494140625}, {"start": 1307.36, "end": 1307.78, "word": " تلاقي", "probability": 0.84521484375}, {"start": 1307.78, "end": 1308.26, "word": " كلور", "probability": 0.7285970052083334}, {"start": 1308.26, "end": 1308.78, "word": " متجه", "probability": 0.92626953125}, {"start": 1308.78, "end": 1309.24, "word": " باتجاه", "probability": 0.8282470703125}, {"start": 1309.24, "end": 1309.48, "word": " هذه", "probability": 0.51904296875}, {"start": 1309.48, "end": 1309.9, "word": " عكسها", "probability": 0.9508056640625}, {"start": 1309.9, "end": 1310.12, "word": " وهذه", "probability": 0.328857421875}, {"start": 1310.12, "end": 1310.6, "word": " الهيدروجين", "probability": 0.8495279947916666}, {"start": 1310.6, "end": 1310.96, "word": " باتجاه", "probability": 0.822509765625}, {"start": 1310.96, "end": 1311.08, "word": " هذه", "probability": 0.8876953125}, {"start": 1311.08, "end": 1311.4, "word": " عكسها", "probability": 0.989501953125}, {"start": 1311.4, "end": 1311.8, "word": " يعني", "probability": 0.825927734375}, {"start": 1311.8, "end": 1312.18, "word": " لحد", "probability": 0.906982421875}, {"start": 1312.18, "end": 1312.4, "word": " هذه", "probability": 0.67626953125}, {"start": 1312.4, "end": 1313.06, "word": " النقطة", "probability": 0.982421875}], "temperature": 1.0}, {"id": 55, "seek": 132822, "start": 1314.14, "end": 1328.22, "text": "معاكسات لكن هنا في chlorine إقبالها hydrogen تحت هنا في chlorine إقبالها hydrogen هل هدولة بيصيروا صورة مرآة إذا بطلوا صورة مرآة", "tokens": [2304, 3615, 995, 4117, 3794, 9307, 44381, 34105, 8978, 39888, 11933, 4587, 3555, 6027, 11296, 12697, 6055, 33753, 34105, 8978, 39888, 11933, 4587, 3555, 6027, 11296, 12697, 8032, 1211, 8032, 3215, 12610, 3660, 4724, 1829, 9381, 13546, 14407, 20328, 13063, 3660, 3714, 2288, 148, 95, 3660, 11933, 15730, 4724, 9566, 1211, 14407, 20328, 13063, 3660, 3714, 2288, 148, 95, 3660], "avg_logprob": -0.15112704429470125, "compression_ratio": 1.5984251968503937, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1314.14, "end": 1315.14, "word": "معاكسات", "probability": 0.9659016927083334}, {"start": 1315.14, "end": 1315.6, "word": " لكن", "probability": 0.4873046875}, {"start": 1315.6, "end": 1316.12, "word": " هنا", "probability": 0.98486328125}, {"start": 1316.12, "end": 1316.46, "word": " في", "probability": 0.9423828125}, {"start": 1316.46, "end": 1317.0, "word": " chlorine", "probability": 0.279052734375}, {"start": 1317.0, "end": 1318.46, "word": " إقبالها", "probability": 0.855712890625}, {"start": 1318.46, "end": 1319.76, "word": " hydrogen", "probability": 0.421142578125}, {"start": 1319.76, "end": 1320.76, "word": " تحت", "probability": 0.839111328125}, {"start": 1320.76, "end": 1320.98, "word": " هنا", "probability": 0.94970703125}, {"start": 1320.98, "end": 1321.28, "word": " في", "probability": 0.91552734375}, {"start": 1321.28, "end": 1322.16, "word": " chlorine", "probability": 0.67138671875}, {"start": 1322.16, "end": 1322.68, "word": " إقبالها", "probability": 0.963671875}, {"start": 1322.68, "end": 1322.98, "word": " hydrogen", "probability": 0.60546875}, {"start": 1322.98, "end": 1323.42, "word": " هل", "probability": 0.926025390625}, {"start": 1323.42, "end": 1323.8, "word": " هدولة", "probability": 0.8343505859375}, {"start": 1323.8, "end": 1324.56, "word": " بيصيروا", "probability": 0.9607421875}, {"start": 1324.56, "end": 1325.14, "word": " صورة", "probability": 0.9763997395833334}, {"start": 1325.14, "end": 1326.36, "word": " مرآة", "probability": 0.82841796875}, {"start": 1326.36, "end": 1326.64, "word": " إذا", "probability": 0.730224609375}, {"start": 1326.64, "end": 1327.18, "word": " بطلوا", "probability": 0.9476318359375}, {"start": 1327.18, "end": 1327.58, "word": " صورة", "probability": 0.9938151041666666}, {"start": 1327.58, "end": 1328.22, "word": " مرآة", "probability": 0.9859375}], "temperature": 1.0}, {"id": 56, "seek": 135187, "start": 1329.11, "end": 1351.87, "text": "شرط صورة المرآة أن كل جزء من الجزيئات هيكون بعكس الجثة الآخر هدولة فيهم أشياء أساسا مش اقبال .. مش .. يعني هذه لا فوق، كلور اقبالها هيدروجين، إذا هدولة الشكلين الcess والترانس لما أنا بدي أحكي عنهم بقول they are non mirror", "tokens": [46309, 9566, 20328, 13063, 3660, 9673, 2288, 148, 95, 3660, 14739, 28242, 10874, 11622, 38207, 9154, 25724, 11622, 1829, 19986, 9307, 39896, 30544, 45030, 4117, 3794, 25724, 12984, 3660, 6024, 95, 34740, 8032, 3215, 12610, 3660, 8978, 16095, 5551, 8592, 1829, 16606, 5551, 3794, 32277, 995, 37893, 1975, 4587, 3555, 6027, 4386, 37893, 4386, 37495, 22653, 29538, 20193, 6156, 30543, 12399, 9122, 1211, 13063, 1975, 4587, 3555, 6027, 11296, 8032, 25708, 2288, 29245, 9957, 12399, 11933, 15730, 8032, 3215, 12610, 3660, 25124, 28820, 9957, 2423, 780, 16070, 2655, 2288, 7649, 3794, 5296, 15042, 41850, 4724, 16254, 5551, 5016, 4117, 1829, 18871, 16095, 4724, 39648, 436, 366, 2107, 8013], "avg_logprob": -0.3047591633752945, "compression_ratio": 1.6363636363636365, "no_speech_prob": 0.0, "words": [{"start": 1329.11, "end": 1329.61, "word": "شرط", "probability": 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"probability": 0.5481363932291666}, {"start": 1339.91, "end": 1340.45, "word": " كلور", "probability": 0.677734375}, {"start": 1340.45, "end": 1341.45, "word": " اقبالها", "probability": 0.863330078125}, {"start": 1341.45, "end": 1342.99, "word": " هيدروجين،", "probability": 0.7574869791666666}, {"start": 1342.99, "end": 1343.29, "word": " إذا", "probability": 0.70263671875}, {"start": 1343.29, "end": 1344.13, "word": " هدولة", "probability": 0.8848876953125}, {"start": 1344.13, "end": 1344.97, "word": " الشكلين", "probability": 0.86181640625}, {"start": 1344.97, "end": 1345.65, "word": " الcess", "probability": 0.436767578125}, {"start": 1345.65, "end": 1346.61, "word": " والترانس", "probability": 0.803125}, {"start": 1346.61, "end": 1347.05, "word": " لما", "probability": 0.890625}, {"start": 1347.05, "end": 1347.33, "word": " أنا", "probability": 0.69091796875}, {"start": 1347.33, "end": 1347.77, "word": " بدي", "probability": 0.758544921875}, {"start": 1347.77, "end": 1348.19, "word": " أحكي", "probability": 0.963623046875}, {"start": 1348.19, "end": 1348.49, "word": " عنهم", "probability": 0.990478515625}, {"start": 1348.49, "end": 1348.95, "word": " بقول", "probability": 0.957275390625}, {"start": 1348.95, "end": 1349.41, "word": " they", "probability": 0.76416015625}, {"start": 1349.41, "end": 1350.03, "word": " are", "probability": 0.9609375}, {"start": 1350.03, "end": 1350.73, "word": " non", "probability": 0.80419921875}, {"start": 1350.73, "end": 1351.87, "word": " mirror", "probability": 0.481201171875}], "temperature": 1.0}, {"id": 57, "seek": 137572, "start": 1353.72, "end": 1375.72, "text": "images، إيش يعني non-mirror images؟ مش صورة بعض في المرأة، الأشياء اللي بتكون مش صورة بعض في المرأة هي اللي تعرف ان اسمها diastereomers، وهذا مثال عليها، ف ال cicatrans، isomers، they are diastereomers", "tokens": [332, 1660, 12399, 11933, 1829, 8592, 37495, 22653, 2107, 12, 19834, 2874, 5267, 22807, 37893, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 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{"start": 1362.12, "end": 1362.58, "word": " المرأة", "probability": 0.95361328125}, {"start": 1362.58, "end": 1362.96, "word": " هي", "probability": 0.6376953125}, {"start": 1362.96, "end": 1363.18, "word": " اللي", "probability": 0.977783203125}, {"start": 1363.18, "end": 1363.88, "word": " تعرف", "probability": 0.968017578125}, {"start": 1363.88, "end": 1365.36, "word": " ان", "probability": 0.33935546875}, {"start": 1365.36, "end": 1366.36, "word": " اسمها", "probability": 0.9641927083333334}, {"start": 1366.36, "end": 1367.6, "word": " diastereomers،", "probability": 0.61358642578125}, {"start": 1367.6, "end": 1367.96, "word": " وهذا", "probability": 0.885009765625}, {"start": 1367.96, "end": 1368.46, "word": " مثال", "probability": 0.973876953125}, {"start": 1368.46, "end": 1369.54, "word": " عليها،", "probability": 0.7962239583333334}, {"start": 1369.54, "end": 1369.7, "word": " ف", "probability": 0.953125}, {"start": 1369.7, "end": 1369.86, "word": " ال", "probability": 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1447.16, "word": " ده", "probability": 0.5748291015625}, {"start": 1447.16, "end": 1447.3, "word": " يا", "probability": 0.42724609375}, {"start": 1447.3, "end": 1447.94, "word": " stereomers", "probability": 0.8937174479166666}], "temperature": 1.0}, {"id": 61, "seek": 146803, "start": 1449.09, "end": 1468.03, "text": "تطلعوا معي مرة تانية نرسم أحد هدولة أو نعمل model لأحد هدولة المركبات اللي هم ال sis, trans, isomers واضح؟ هذا أي مركب فيهم؟ ال sis والتاني لترانس متى توجد عندنا ظاهرة ال sis و الترانس؟", "tokens": [2655, 9566, 1211, 3615, 14407, 20449, 1829, 3714, 25720, 6055, 7649, 10632, 8717, 2288, 38251, 5551, 24401, 8032, 3215, 12610, 3660, 34051, 8717, 25957, 1211, 2316, 5296, 10721, 24401, 8032, 3215, 12610, 3660, 9673, 31747, 3555, 9307, 13672, 1829, 8032, 2304, 2423, 26288, 11, 1145, 11, 307, 298, 433, 4032, 46958, 5016, 22807, 23758, 36632, 3714, 31747, 3555, 8978, 16095, 22807, 2423, 26288, 16070, 2655, 7649, 1829, 5296, 2655, 2288, 7649, 3794, 44650, 7578, 33427, 7435, 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trans هاي بال cycle اللي اتعرفنا عليه طيب حوالين ال double bond", "tokens": [6027, 6027, 4117, 9957, 11622, 13672, 1829, 8978, 11296, 12602, 14407, 3555, 9566, 6024, 110, 29245, 9957, 23758, 9673, 41361, 13672, 1829, 39894, 8592, 38688, 3224, 8978, 3224, 9122, 19528, 3660, 26288, 4032, 1145, 8978, 2423, 17796, 50113, 1211, 9673, 12984, 6027, 13672, 1829, 1975, 5016, 8315, 12602, 38251, 8315, 30767, 1829, 19446, 12174, 12610, 8315, 23758, 50113, 15040, 39627, 15730, 25124, 28820, 26288, 4032, 39627, 15730, 25124, 28820, 2423, 1145, 8032, 47302, 20666, 6586, 13672, 1829, 1975, 2655, 3615, 28480, 8315, 47356, 23032, 1829, 3555, 11331, 2407, 6027, 9957, 2423, 3834, 6086], "avg_logprob": -0.18650265862333013, "compression_ratio": 1.854368932038835, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1520.1, "end": 1520.86, "word": "الالكينز", "probability": 0.70673828125}, {"start": 1520.86, "end": 1520.96, "word": " اللي", "probability": 0.791259765625}, {"start": 1520.96, "end": 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بيتم لأنه انا لو جربت في cycle الكل بدي ألوف هذا هيك أخلي هدول يصيروا عكس بعض يعني ال 6 يصير ال trans لاحظوا لأنه مربوط بالحلقة الدوران حول الحلقة ممنوع الدوران حول الحلقة ممنوع الان طيب لو اتخيلتوا ان انا في عنده", "tokens": [6027, 6027, 4117, 47302, 11622, 2423, 6027, 4117, 9957, 11622, 6225, 5172, 14407, 32239, 8592, 23758, 2423, 28820, 10943, 4724, 36081, 2304, 5296, 33456, 3224, 1975, 8315, 45164, 10874, 25513, 2655, 8978, 6586, 2423, 28820, 4724, 16254, 5551, 1211, 38688, 23758, 39896, 4117, 5551, 9778, 20292, 8032, 3215, 12610, 7251, 9381, 13546, 14407, 6225, 4117, 3794, 45030, 11242, 37495, 22653, 2423, 1386, 7251, 9381, 13546, 2423, 1145, 20193, 5016, 19913, 14407, 5296, 33456, 3224, 3714, 25513, 2407, 9566, 20666, 5016, 1211, 28671, 32748, 13063, 7649, 11331, 12610, 21542, 1211, 28671, 3714, 27842, 45367, 32748, 13063, 7649, 11331, 12610, 21542, 1211, 28671, 3714, 27842, 45367, 2423, 7649, 23032, 1829, 3555, 45164, 1975, 2655, 9778, 26895, 2655, 14407, 16472, 1975, 8315, 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{"start": 1703.63, "end": 1704.15, "word": " الفكرة", "probability": 0.9207356770833334}, {"start": 1704.15, "end": 1704.95, "word": " زي", "probability": 0.64501953125}, {"start": 1704.95, "end": 1705.47, "word": " لما", "probability": 0.9091796875}, {"start": 1705.47, "end": 1706.17, "word": " الواحدة", "probability": 0.9349365234375}, {"start": 1706.17, "end": 1706.55, "word": " بيجيها", "probability": 0.98681640625}, {"start": 1706.55, "end": 1707.19, "word": " مولود", "probability": 0.9908854166666666}, {"start": 1707.19, "end": 1708.05, "word": " مافيش", "probability": 0.7647298177083334}, {"start": 1708.05, "end": 1708.35, "word": " يكون", "probability": 0.912353515625}, {"start": 1708.35, "end": 1709.05, "word": " عشوائي", "probability": 0.9857421875}, {"start": 1709.05, "end": 1709.37, "word": " يا", "probability": 0.75244140625}, {"start": 1709.37, "end": 1709.85, "word": " ولد", "probability": 0.7305908203125}, {"start": 1709.85, "end": 1710.77, "word": " يا", "probability": 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بظائف", "probability": 0.8232421875}, {"start": 1728.57, "end": 1729.15, "word": " معينة", "probability": 0.9944661458333334}, {"start": 1729.15, "end": 1729.27, "word": " في", "probability": 0.8876953125}, {"start": 1729.27, "end": 1729.79, "word": " الحياة", "probability": 0.9934895833333334}, {"start": 1729.79, "end": 1730.07, "word": " و", "probability": 0.5634765625}, {"start": 1730.07, "end": 1730.55, "word": " هتلاقوا", "probability": 0.96689453125}, {"start": 1730.55, "end": 1731.15, "word": " مركب", "probability": 0.8126627604166666}, {"start": 1731.15, "end": 1731.79, "word": " تاني", "probability": 0.9762369791666666}, {"start": 1731.79, "end": 1732.79, "word": " مختلف", "probability": 0.978515625}, {"start": 1732.79, "end": 1733.21, "word": " ال", "probability": 0.548828125}, {"start": 1733.21, "end": 1733.89, "word": " Trans", "probability": 0.46435546875}, {"start": 1733.89, "end": 1734.31, "word": " و", "probability": 0.85595703125}, {"start": 1734.31, "end": 1734.51, "word": " زي", "probability": 0.8916015625}, {"start": 1734.51, "end": 1734.59, "word": " ما", "probability": 0.98779296875}, {"start": 1734.59, "end": 1734.83, "word": " قلنا", "probability": 0.8816731770833334}, {"start": 1734.83, "end": 1735.31, "word": " العلاقة", "probability": 0.9484049479166666}, {"start": 1735.31, "end": 1735.55, "word": " بين", "probability": 0.98388671875}, {"start": 1735.55, "end": 1736.21, "word": " هدولة", "probability": 0.78118896484375}, {"start": 1736.21, "end": 1736.61, "word": " VR", "probability": 0.64453125}], "temperature": 1.0}, {"id": 73, "seek": 175780, "start": 1737.72, "end": 1757.8, "text": "Diastereomers they are non mirror images كلام سليم ولا لأ؟ مش صورة بعض في المرأة في الخصائص الفيزيائية أكيد و الكيميائية بيختلفوا في كل شيء صاروا مركبين", "tokens": [35, 72, 525, 323, 298, 433, 436, 366, 2107, 8013, 5267, 28242, 10943, 8608, 20292, 2304, 49429, 5296, 10721, 22807, 37893, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 10721, 3660, 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"end": 2203.42, "word": " يكونوا", "probability": 0.9903971354166666}, {"start": 2203.42, "end": 2203.84, "word": " أبعد", "probability": 0.8860677083333334}, {"start": 2203.84, "end": 2204.3, "word": " كمان", "probability": 0.9765625}, {"start": 2204.3, "end": 2205.56, "word": " واضح؟", "probability": 0.7987060546875}, {"start": 2205.56, "end": 2205.98, "word": " بتظهر", "probability": 0.74658203125}, {"start": 2205.98, "end": 2206.38, "word": " نقطة", "probability": 0.96435546875}, {"start": 2206.38, "end": 2207.0, "word": " الحقيقة", "probability": 0.9669596354166666}, {"start": 2207.0, "end": 2207.98, "word": " في", "probability": 0.9658203125}, {"start": 2207.98, "end": 2208.42, "word": " موضوع", "probability": 0.9940185546875}, {"start": 2208.42, "end": 2208.62, "word": " ال", "probability": 0.89306640625}, {"start": 2208.62, "end": 2210.86, "word": " cyclobutane", "probability": 0.6790313720703125}, {"start": 2210.86, "end": 2211.36, "word": " ان", "probability": 0.576171875}, {"start": 2211.36, "end": 2211.64, "word": " هل", "probability": 0.7186279296875}, {"start": 2211.64, "end": 2211.82, "word": " يا", "probability": 0.62451171875}, {"start": 2211.82, "end": 2212.4, "word": " ترى", "probability": 0.8821614583333334}, {"start": 2212.4, "end": 2212.66, "word": " ال", "probability": 0.78955078125}, {"start": 2212.66, "end": 2214.02, "word": " cyclobutane", "probability": 0.8883056640625}, {"start": 2214.02, "end": 2214.98, "word": " بلانر", "probability": 0.61956787109375}], "temperature": 1.0}, {"id": 94, "seek": 223258, "start": 2215.96, "end": 2232.58, "text": "بهذا الشكل؟ الجواب لو كنا بنطلع على الزوايا تبعته بشكل دقيق هو مش planner هو شوية بيقول عنه puckered يعني مثني شوية لجوا الان بيشبه ايش بهذا الشكل الفراشة ال butterfly", "tokens": [3555, 3224, 15730, 25124, 28820, 22807, 25724, 14407, 3555, 45164, 9122, 8315, 44945, 9566, 1211, 3615, 15844, 6024, 110, 14407, 25528, 6055, 3555, 34268, 3224, 4724, 8592, 28820, 11778, 38436, 4587, 31439, 37893, 31268, 31439, 13412, 2407, 10632, 4724, 1829, 39648, 18871, 3224, 47181, 323, 67, 37495, 22653, 50113, 22653, 13412, 2407, 10632, 5296, 7435, 14407, 2423, 7649, 4724, 1829, 8592, 3555, 3224, 1975, 1829, 8592, 39627, 15730, 25124, 28820, 27188, 2288, 33599, 3660, 2423, 22140], "avg_logprob": -0.2102272796940494, "compression_ratio": 1.5730337078651686, "no_speech_prob": 1.8477439880371094e-06, "words": [{"start": 2215.96, "end": 2216.44, "word": "بهذا", "probability": 0.8404947916666666}, {"start": 2216.44, "end": 2217.14, "word": " الشكل؟", "probability": 0.8600260416666666}, {"start": 2217.14, "end": 2218.64, "word": " الجواب", "probability": 0.8831380208333334}, {"start": 2218.64, "end": 2218.96, "word": " لو", "probability": 0.87646484375}, {"start": 2218.96, "end": 2219.24, "word": " كنا", "probability": 0.9912109375}, {"start": 2219.24, "end": 2219.78, "word": " بنطلع", "probability": 0.8458251953125}, {"start": 2219.78, "end": 2219.96, "word": " على", "probability": 0.857421875}, {"start": 2219.96, "end": 2220.44, "word": " الزوايا", "probability": 0.916259765625}, {"start": 2220.44, "end": 2220.92, "word": " تبعته", "probability": 0.83734130859375}, {"start": 2220.92, "end": 2221.34, "word": " بشكل", "probability": 0.9866536458333334}, {"start": 2221.34, "end": 2221.88, "word": " دقيق", "probability": 0.9944661458333334}, {"start": 2221.88, "end": 2222.34, "word": " هو", "probability": 0.9150390625}, {"start": 2222.34, "end": 2222.74, "word": " مش", "probability": 0.98681640625}, {"start": 2222.74, "end": 2223.22, "word": " planner", "probability": 0.78173828125}, {"start": 2223.22, "end": 2223.78, "word": " هو", "probability": 0.89697265625}, {"start": 2223.78, "end": 2224.24, "word": " شوية", "probability": 0.8943684895833334}, {"start": 2224.24, "end": 2224.58, "word": " بيقول", "probability": 0.652587890625}, {"start": 2224.58, "end": 2224.94, "word": " عنه", "probability": 0.96240234375}, {"start": 2224.94, "end": 2225.46, "word": " puckered", 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"word": " butterfly", "probability": 0.9296875}], "temperature": 1.0}, {"id": 95, "seek": 226184, "start": 2233.64, "end": 2261.84, "text": "واضح؟ فالـ cyclobutane is not a planar molecule مش موجود بهذا الشكل في مستوى واحد لأ من ثاني شوية للداخل عامل زي الفراشة بتعرفوا أنتوا كيف عادة بترسموا الفراشة؟ فأنا لو بدأ أرسم ال cyclobutane بهذا الشكل بارسمه واحد اتنين تلاتة أربع هذه الأربع كربونات", "tokens": [2407, 46958, 5016, 22807, 6156, 6027, 39184, 19474, 996, 325, 1929, 307, 406, 257, 1393, 289, 15582, 37893, 3714, 29245, 23328, 39627, 15730, 25124, 28820, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 5296, 10721, 9154, 38637, 7649, 1829, 13412, 2407, 10632, 24976, 3215, 47283, 1211, 6225, 10943, 1211, 30767, 1829, 27188, 2288, 33599, 3660, 39894, 3615, 28480, 14407, 14739, 2655, 14407, 9122, 33911, 6225, 18513, 3660, 39894, 2288, 38251, 14407, 27188, 2288, 33599, 3660, 22807, 6156, 10721, 8315, 45164, 47525, 10721, 5551, 2288, 38251, 2423, 19474, 996, 325, 1929, 39627, 15730, 25124, 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"word": " عامل", "probability": 0.9957682291666666}, {"start": 2246.78, "end": 2247.1, "word": " زي", "probability": 0.910888671875}, {"start": 2247.1, "end": 2247.64, "word": " الفراشة", "probability": 0.9100341796875}, {"start": 2247.64, "end": 2248.06, "word": " بتعرفوا", "probability": 0.93359375}, {"start": 2248.06, "end": 2248.28, "word": " أنتوا", "probability": 0.614013671875}, {"start": 2248.28, "end": 2248.48, "word": " كيف", "probability": 0.97021484375}, {"start": 2248.48, "end": 2248.84, "word": " عادة", "probability": 0.9864908854166666}, {"start": 2248.84, "end": 2249.48, "word": " بترسموا", "probability": 0.95458984375}, {"start": 2249.48, "end": 2252.14, "word": " الفراشة؟", "probability": 0.864990234375}, {"start": 2252.14, "end": 2254.6, "word": " فأنا", "probability": 0.7967936197916666}, {"start": 2254.6, "end": 2254.76, "word": " لو", "probability": 0.98681640625}, {"start": 2254.76, "end": 2255.0, "word": " بدأ", "probability": 0.596923828125}, {"start": 2255.0, "end": 2255.32, "word": " أرسم", "probability": 0.8800455729166666}, {"start": 2255.32, "end": 2255.5, "word": " ال", "probability": 0.92578125}, {"start": 2255.5, "end": 2256.54, "word": " cyclobutane", "probability": 0.83892822265625}, {"start": 2256.54, "end": 2257.26, "word": " بهذا", "probability": 0.94873046875}, {"start": 2257.26, "end": 2257.6, "word": " الشكل", "probability": 0.9892578125}, {"start": 2257.6, "end": 2258.36, "word": " بارسمه", "probability": 0.815185546875}, {"start": 2258.36, "end": 2259.14, "word": " واحد", "probability": 0.759033203125}, {"start": 2259.14, "end": 2259.58, "word": " اتنين", "probability": 0.895263671875}, {"start": 2259.58, "end": 2260.18, "word": " تلاتة", "probability": 0.923583984375}, {"start": 2260.18, "end": 2260.52, "word": " أربع", "probability": 0.70068359375}, {"start": 2260.52, "end": 2260.7, "word": " هذه", "probability": 0.2183837890625}, {"start": 2260.7, "end": 2261.12, "word": " الأربع", "probability": 0.93212890625}, {"start": 2261.12, "end": 2261.84, "word": " كربونات", "probability": 0.85546875}], "temperature": 1.0}, {"id": 96, "seek": 229010, "start": 2264.22, "end": 2290.1, "text": "cyclobutane is not a planar molecule الان تقريبا المعلومات بتصير تتكرر هنا قولنا زي الاش زي ال butter fly اللي هي الفراشة طب لو بدى احكي عن الcyclobutane معلومات ال cis و ال trans و ال substitution نفس الشيء", "tokens": [1344, 66, 752, 5955, 1929, 307, 406, 257, 1393, 289, 15582, 2423, 7649, 6055, 4587, 16572, 3555, 995, 9673, 30241, 20498, 9307, 39894, 9381, 13546, 6055, 2655, 37983, 2288, 34105, 12174, 12610, 8315, 30767, 1829, 2423, 33599, 30767, 1829, 2423, 5517, 3603, 13672, 1829, 39896, 27188, 2288, 33599, 3660, 23032, 3555, 45164, 47525, 7578, 1975, 5016, 4117, 1829, 18871, 2423, 1344, 66, 752, 5955, 1929, 20449, 1211, 20498, 9307, 2423, 37847, 4032, 2423, 1145, 4032, 2423, 35827, 8717, 36178, 25124, 1829, 38207], "avg_logprob": -0.26694276677556783, "compression_ratio": 1.5561224489795917, "no_speech_prob": 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"probability": 0.16796875}, {"start": 2275.94, "end": 2276.28, "word": " قولنا", "probability": 0.8201497395833334}, {"start": 2276.28, "end": 2276.54, "word": " زي", "probability": 0.88232421875}, {"start": 2276.54, "end": 2277.0, "word": " الاش", "probability": 0.461669921875}, {"start": 2277.0, "end": 2278.1, "word": " زي", "probability": 0.770751953125}, {"start": 2278.1, "end": 2278.24, "word": " ال", "probability": 0.798828125}, {"start": 2278.24, "end": 2278.6, "word": " butter", "probability": 0.80712890625}, {"start": 2278.6, "end": 2280.44, "word": " fly", "probability": 0.275146484375}, {"start": 2280.44, "end": 2280.62, "word": " اللي", "probability": 0.634033203125}, {"start": 2280.62, "end": 2281.04, "word": " هي", "probability": 0.830078125}, {"start": 2281.04, "end": 2282.76, "word": " الفراشة", "probability": 0.958251953125}, {"start": 2282.76, "end": 2283.16, "word": " طب", "probability": 0.892333984375}, {"start": 2283.16, "end": 2283.26, "word": " لو", "probability": 0.98486328125}, {"start": 2283.26, "end": 2283.46, "word": " بدى", "probability": 0.572265625}, {"start": 2283.46, "end": 2283.74, "word": " احكي", "probability": 0.9019775390625}, {"start": 2283.74, "end": 2283.9, "word": " عن", "probability": 0.98876953125}, {"start": 2283.9, "end": 2285.1, "word": " الcyclobutane", "probability": 0.7373046875}, {"start": 2285.1, "end": 2286.48, "word": " معلومات", "probability": 0.9114990234375}, {"start": 2286.48, "end": 2286.7, "word": " ال", "probability": 0.93798828125}, {"start": 2286.7, "end": 2286.92, "word": " cis", "probability": 0.358642578125}, {"start": 2286.92, "end": 2287.12, "word": " و", "probability": 0.439208984375}, {"start": 2287.12, "end": 2287.24, "word": " ال", "probability": 0.76806640625}, {"start": 2287.24, "end": 2287.72, "word": " trans", "probability": 0.591796875}, {"start": 2287.72, "end": 2287.88, "word": " و", "probability": 0.8798828125}, {"start": 2287.88, "end": 2288.0, "word": " ال", "probability": 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اكثر", "probability": 0.8338216145833334}, {"start": 2292.34, "end": 2292.56, "word": " من", "probability": 0.97607421875}, {"start": 2292.56, "end": 2293.16, "word": " موقع", "probability": 0.9900716145833334}, {"start": 2293.16, "end": 2294.34, "word": " لكن", "probability": 0.79345703125}, {"start": 2294.34, "end": 2295.2, "word": " لو", "probability": 0.85693359375}, {"start": 2295.2, "end": 2295.44, "word": " كنت", "probability": 0.9755859375}, {"start": 2295.44, "end": 2295.66, "word": " بده", "probability": 0.509033203125}, {"start": 2295.66, "end": 2295.88, "word": " احط", "probability": 0.8447265625}, {"start": 2295.88, "end": 2296.26, "word": " اول", "probability": 0.862060546875}, {"start": 2296.26, "end": 2296.86, "word": " كلور", "probability": 0.681884765625}, {"start": 2296.86, "end": 2297.9, "word": " العشرة", "probability": 0.6857096354166666}, {"start": 2297.9, "end": 2298.68, "word": " هيدروجين", "probability": 0.77548828125}, {"start": 2298.68, "end": 2299.4, 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0.9332682291666666}, {"start": 2312.06, "end": 2312.26, "word": " من", "probability": 0.970703125}, {"start": 2312.26, "end": 2312.74, "word": " مركب", "probability": 0.9767252604166666}, {"start": 2312.74, "end": 2313.56, "word": " بإمكانكوا", "probability": 0.8960774739583334}, {"start": 2313.56, "end": 2314.24, "word": " تحسبوهم", "probability": 0.87529296875}, {"start": 2314.24, "end": 2314.36, "word": " و", "probability": 0.61962890625}, {"start": 2314.36, "end": 2314.9, "word": " تجمعوهم", "probability": 0.9376627604166666}, {"start": 2314.9, "end": 2315.36, "word": " طب", "probability": 0.807861328125}, {"start": 2315.36, "end": 2315.5, "word": " يا", "probability": 0.94482421875}, {"start": 2315.5, "end": 2315.86, "word": " تورا", "probability": 0.7686360677083334}, {"start": 2315.86, "end": 2316.28, "word": " لو", "probability": 0.97705078125}, {"start": 2316.28, "end": 2316.7, "word": " حكيت", "probability": 0.9884440104166666}, {"start": 2316.7, "end": 2316.9, "word": " عن", "probability": 0.9833984375}, {"start": 2316.9, "end": 2317.3, "word": " الشكل", "probability": 0.950439453125}, {"start": 2317.3, "end": 2317.68, "word": " تبعه", "probability": 0.8907470703125}, {"start": 2317.68, "end": 2317.86, "word": " هل", "probability": 0.946533203125}, {"start": 2317.86, "end": 2318.02, "word": " هو", "probability": 0.9912109375}, {"start": 2318.02, "end": 2318.6, "word": " planner؟", "probability": 0.759521484375}], "temperature": 1.0}, {"id": 98, "seek": 234354, "start": 2319.3, "end": 2343.54, "text": "الجواب لأ مش planner طب هى زى إيش بيعمل الآن تخيلوا هى الحلقة الخماسية شايفينها هى دى اللى أمامكوا حلقة خماسية ولا لأ؟ واحد تانين تلاتة أربعة خمسة هيك بتكون planner لكن هى عاملة بهذا الشكل الآن هذا الشكل لو كنا نعطيه اسم", "tokens": [6027, 7435, 14407, 3555, 5296, 10721, 37893, 31268, 23032, 3555, 8032, 7578, 30767, 7578, 11933, 1829, 8592, 4724, 1829, 25957, 1211, 6024, 48506, 6055, 9778, 26895, 14407, 8032, 7578, 21542, 1211, 28671, 33962, 15042, 3794, 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"probability": 0.88330078125}, {"start": 2322.22, "end": 2322.6, "word": " هى", "probability": 0.6392822265625}, {"start": 2322.6, "end": 2322.9, "word": " زى", "probability": 0.929443359375}, {"start": 2322.9, "end": 2323.14, "word": " إيش", "probability": 0.7635904947916666}, {"start": 2323.14, "end": 2323.6, "word": " بيعمل", "probability": 0.9151611328125}, {"start": 2323.6, "end": 2324.12, "word": " الآن", "probability": 0.560546875}, {"start": 2324.12, "end": 2324.6, "word": " تخيلوا", "probability": 0.976806640625}, {"start": 2324.6, "end": 2324.74, "word": " هى", "probability": 0.755859375}, {"start": 2324.74, "end": 2325.18, "word": " الحلقة", "probability": 0.98388671875}, {"start": 2325.18, "end": 2325.92, "word": " الخماسية", "probability": 0.878662109375}, {"start": 2325.92, "end": 2326.64, "word": " شايفينها", "probability": 0.9552734375}, {"start": 2326.64, "end": 2327.6, "word": " هى", "probability": 0.377197265625}, {"start": 2327.6, "end": 2327.72, "word": " دى", "probability": 0.883056640625}, {"start": 2327.72, "end": 2327.82, "word": " اللى", "probability": 0.990478515625}, {"start": 2327.82, "end": 2328.3, "word": " أمامكوا", "probability": 0.89248046875}, {"start": 2328.3, "end": 2328.64, "word": " حلقة", "probability": 0.9568684895833334}, {"start": 2328.64, "end": 2329.34, "word": " خماسية", "probability": 0.93017578125}, {"start": 2329.34, "end": 2329.54, "word": " ولا", "probability": 0.74267578125}, {"start": 2329.54, "end": 2330.42, "word": " لأ؟", "probability": 0.7853190104166666}, {"start": 2330.42, "end": 2331.02, "word": " واحد", "probability": 0.835205078125}, {"start": 2331.02, "end": 2331.92, "word": " تانين", "probability": 0.6533203125}, {"start": 2331.92, "end": 2332.9, "word": " تلاتة", "probability": 0.92822265625}, {"start": 2332.9, "end": 2333.8, "word": " أربعة", "probability": 0.8670247395833334}, {"start": 2333.8, "end": 2334.72, "word": " خمسة", "probability": 0.9722900390625}, {"start": 2334.72, "end": 2335.38, "word": " هيك", "probability": 0.9140625}, {"start": 2335.38, "end": 2335.98, "word": " بتكون", "probability": 0.983642578125}, {"start": 2335.98, "end": 2336.96, "word": " planner", "probability": 0.8623046875}, {"start": 2336.96, "end": 2337.6, "word": " لكن", "probability": 0.8125}, {"start": 2337.6, "end": 2337.88, "word": " هى", "probability": 0.802001953125}, {"start": 2337.88, "end": 2338.4, "word": " عاملة", "probability": 0.9920247395833334}, {"start": 2338.4, "end": 2339.04, "word": " بهذا", "probability": 0.94921875}, {"start": 2339.04, "end": 2339.58, "word": " الشكل", "probability": 0.990234375}, {"start": 2339.58, "end": 2341.64, "word": " الآن", "probability": 0.6500244140625}, {"start": 2341.64, "end": 2341.9, "word": " هذا", "probability": 0.8720703125}, {"start": 2341.9, "end": 2342.26, "word": " الشكل", "probability": 0.986328125}, {"start": 2342.26, "end": 2342.42, "word": " لو", "probability": 0.97900390625}, {"start": 2342.42, "end": 2342.62, "word": " كنا", "probability": 0.625}, {"start": 2342.62, "end": 2343.1, "word": " نعطيه", "probability": 0.953125}, {"start": 2343.1, "end": 2343.54, "word": " اسم", "probability": 0.879638671875}], "temperature": 1.0}, {"id": 99, "seek": 237214, "start": 2344.36, "end": 2372.14, "text": "بنقول عنه non planner أكيد لكن إله اسم أمركوا شفتوا ضرف مغلف رسالة مفتوح it is like an open envelope فهذا الشكل لو قلنا لكوا عنه planner لأ هتقولوا it is like an open envelope اللي هو ضرف رسالة مفتوح لو كنتوا بتكونوا ترسموه", "tokens": [3555, 1863, 39648, 18871, 3224, 2107, 31268, 5551, 4117, 25708, 44381, 11933, 43761, 24525, 2304, 5551, 29973, 4117, 14407, 13412, 5172, 2655, 14407, 48812, 28480, 3714, 17082, 46538, 12602, 3794, 6027, 3660, 3714, 5172, 2655, 2407, 5016, 309, 307, 411, 364, 1269, 19989, 6156, 3224, 15730, 25124, 28820, 45164, 12174, 1211, 8315, 5296, 4117, 14407, 18871, 3224, 31268, 5296, 10721, 8032, 2655, 39648, 14407, 309, 307, 411, 364, 1269, 19989, 13672, 1829, 31439, 48812, 28480, 12602, 3794, 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2349.04, "end": 2349.52, "word": " شفتوا", "probability": 0.7474365234375}, {"start": 2349.52, "end": 2350.12, "word": " ضرف", "probability": 0.6279296875}, {"start": 2350.12, "end": 2351.6, "word": " مغلف", "probability": 0.93603515625}, {"start": 2351.6, "end": 2352.2, "word": " رسالة", "probability": 0.9674072265625}, {"start": 2352.2, "end": 2352.86, "word": " مفتوح", "probability": 0.9966796875}, {"start": 2352.86, "end": 2354.34, "word": " it", "probability": 0.63525390625}, {"start": 2354.34, "end": 2355.6, "word": " is", "probability": 0.92578125}, {"start": 2355.6, "end": 2356.12, "word": " like", "probability": 0.9580078125}, {"start": 2356.12, "end": 2356.86, "word": " an", "probability": 0.826171875}, {"start": 2356.86, "end": 2357.72, "word": " open", "probability": 0.9326171875}, {"start": 2357.72, "end": 2358.48, "word": " envelope", "probability": 0.84521484375}, {"start": 2358.48, "end": 2360.68, "word": " فهذا", "probability": 0.9654947916666666}, {"start": 2360.68, 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2366.24, "word": " open", "probability": 0.87939453125}, {"start": 2366.24, "end": 2367.98, "word": " envelope", "probability": 0.884765625}, {"start": 2367.98, "end": 2369.02, "word": " اللي", "probability": 0.8994140625}, {"start": 2369.02, "end": 2369.26, "word": " هو", "probability": 0.98291015625}, {"start": 2369.26, "end": 2369.64, "word": " ضرف", "probability": 0.929931640625}, {"start": 2369.64, "end": 2370.1, "word": " رسالة", "probability": 0.9954833984375}, {"start": 2370.1, "end": 2370.38, "word": " مفتوح", "probability": 0.9970703125}, {"start": 2370.38, "end": 2370.76, "word": " لو", "probability": 0.8544921875}, {"start": 2370.76, "end": 2371.08, "word": " كنتوا", "probability": 0.9943033854166666}, {"start": 2371.08, "end": 2371.32, "word": " بتكونوا", "probability": 0.7888997395833334}, {"start": 2371.32, "end": 2372.14, "word": " ترسموه", "probability": 0.9744140625}], "temperature": 1.0}, {"id": 100, "seek": 239839, "start": 2372.91, "end": 2398.39, "text": "بشكل فراغي open envelope مش envelope ال .. الظرف تبع الرسالة و الموضوع it is like an open envelope لو بدي ارسمه بهذا الشكل بارسمه فال Cyclopropane is a planar Cyclobutane لأ Cyclopentane لأ الان لو انتقلنا بعد هيك لل Cyclohexane", "tokens": [3555, 8592, 28820, 6156, 2288, 5718, 118, 1829, 1269, 19989, 37893, 19989, 2423, 4386, 6024, 116, 28480, 6055, 3555, 3615, 34892, 3794, 6027, 3660, 4032, 9673, 2407, 11242, 45367, 309, 307, 411, 364, 1269, 19989, 45164, 4724, 16254, 1975, 2288, 38251, 3224, 39627, 15730, 25124, 28820, 4724, 9640, 38251, 3224, 6156, 6027, 10295, 3474, 404, 1513, 1929, 307, 257, 1393, 289, 10295, 66, 752, 5955, 1929, 5296, 10721, 10295, 3474, 404, 317, 1929, 5296, 10721, 2423, 7649, 45164, 16472, 2655, 4587, 1211, 8315, 39182, 39896, 4117, 24976, 10295, 66, 752, 675, 87, 1929], "avg_logprob": -0.2774268477521044, "compression_ratio": 1.601010101010101, "no_speech_prob": 0.0, "words": [{"start": 2372.91, "end": 2373.45, "word": "بشكل", "probability": 0.90283203125}, 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{"start": 2381.63, "end": 2382.07, "word": " it", "probability": 0.70361328125}, {"start": 2382.07, "end": 2382.27, "word": " is", "probability": 0.90966796875}, {"start": 2382.27, "end": 2382.55, "word": " like", "probability": 0.95361328125}, {"start": 2382.55, "end": 2382.81, "word": " an", "probability": 0.8271484375}, {"start": 2382.81, "end": 2383.33, "word": " open", "probability": 0.94140625}, {"start": 2383.33, "end": 2384.01, "word": " envelope", "probability": 0.89208984375}, {"start": 2384.01, "end": 2384.39, "word": " لو", "probability": 0.94921875}, {"start": 2384.39, "end": 2384.55, "word": " بدي", "probability": 0.740234375}, {"start": 2384.55, "end": 2385.05, "word": " ارسمه", "probability": 0.84149169921875}, {"start": 2385.05, "end": 2385.51, "word": " بهذا", "probability": 0.924560546875}, {"start": 2385.51, "end": 2385.93, "word": " الشكل", "probability": 0.991943359375}, {"start": 2385.93, "end": 2386.77, "word": " بارسمه", "probability": 0.9044189453125}, 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لاحظوا نفس الحلقة شايفين كيف أنا مسكها؟", "tokens": [6027, 3555, 1863, 11622, 9957, 383, 21, 39, 21, 4724, 1211, 7649, 2288, 44381, 2423, 39184, 34, 88, 66, 752, 675, 87, 1929, 32239, 3794, 3714, 20292, 4117, 1829, 20498, 4724, 1211, 7649, 2288, 37893, 4724, 1211, 7649, 2288, 23032, 3555, 8032, 995, 9122, 33911, 4724, 1829, 1863, 29245, 3215, 22807, 3714, 43020, 7251, 1863, 29245, 3215, 15844, 5551, 4117, 49115, 9154, 39896, 19986, 3660, 39896, 19986, 3660, 4724, 1829, 39648, 18871, 11296, 21871, 21871, 39896, 19986, 3660, 4724, 2304, 3615, 1863, 7578, 3714, 43020, 8717, 2304, 3794, 4117, 3224, 39627, 15730, 25124, 28820, 20193, 5016, 19913, 14407, 8717, 36178, 21542, 1211, 28671, 13412, 995, 33911, 9957, 9122, 33911, 41850, 47524, 4117, 11296, 22807], "avg_logprob": -0.22160325750060703, "compression_ratio": 1.7235023041474655, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2424.28, "end": 2425.1, "word": "البنزين", "probability": 0.91455078125}, {"start": 2425.1, "end": 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أنا", "probability": 0.767578125}, {"start": 2448.62, "end": 2449.48, "word": " مسكها؟", "probability": 0.8665771484375}], "temperature": 1.0}, {"id": 103, "seek": 247352, "start": 2450.0, "end": 2473.52, "text": "الان هذا الشكل اللي انا ماسكه يشبه ماذا؟ القارب او الزورق بسمي انا هيئة القارب boat confirmation boat confirmation موجود عندكم ربما بهذا المكان شايفينه؟", "tokens": [6027, 7649, 23758, 25124, 28820, 13672, 1829, 1975, 8315, 19446, 3794, 4117, 3224, 7251, 8592, 3555, 3224, 3714, 45636, 995, 22807, 25062, 9640, 3555, 1975, 2407, 6024, 110, 13063, 4587, 4724, 38251, 1829, 1975, 8315, 39896, 19986, 3660, 25062, 9640, 3555, 6582, 21871, 6582, 21871, 3714, 29245, 23328, 43242, 24793, 12602, 3555, 15042, 39627, 15730, 9673, 41361, 13412, 995, 33911, 9957, 3224, 22807], "avg_logprob": -0.13012695545330644, "compression_ratio": 1.6, "no_speech_prob": 0.0, "words": [{"start": 2450.0, "end": 2450.44, "word": "الان", "probability": 0.8037109375}, {"start": 2450.44, "end": 2450.96, 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شايفينه", "probability": 0.923828125}, {"start": 2963.0, "end": 2964.28, "word": " المُركّب؟", "probability": 0.8729248046875}, {"start": 2964.28, "end": 2964.4, "word": " إيش", "probability": 0.8050130208333334}, {"start": 2964.4, "end": 2965.6, "word": " اسمه؟", "probability": 0.9100341796875}, {"start": 2965.6, "end": 2966.04, "word": " مثل", "probability": 0.9931640625}, {"start": 2966.04, "end": 2967.08, "word": " سايكلوبروبين", "probability": 0.8897705078125}, {"start": 2967.08, "end": 2968.3, "word": " اعملوله", "probability": 0.8814453125}, {"start": 2968.3, "end": 2969.16, "word": " مونو", "probability": 0.8562825520833334}, {"start": 2969.16, "end": 2970.18, "word": " إكلورينايشن", "probability": 0.9128146701388888}], "temperature": 1.0}, {"id": 125, "seek": 298893, "start": 2971.47, "end": 2988.93, "text": "وDichlorination وشوفوا كم ناتج بيطلع عندكم طبعا بتكونوا تنتبهوا ان الchlorination ممكن يجي على المثل او على الحلقة بدي كل النواتج الممكنة وهنا كل النواتج الممكنة هذا بحاجة انكوا تتدربوا بشكل جيد", "tokens": [2407, 35, 480, 6746, 2486, 4032, 8592, 38688, 14407, 9122, 2304, 8717, 9307, 7435, 4724, 1829, 9566, 1211, 3615, 43242, 24793, 23032, 3555, 3615, 995, 39894, 30544, 14407, 6055, 29399, 3555, 3224, 14407, 16472, 2423, 11439, 284, 2486, 3714, 43020, 7251, 7435, 1829, 15844, 9673, 12984, 1211, 1975, 2407, 15844, 21542, 1211, 28671, 4724, 16254, 28242, 28239, 2407, 9307, 7435, 9673, 43020, 3660, 37037, 8315, 28242, 28239, 2407, 9307, 7435, 9673, 43020, 3660, 23758, 4724, 5016, 26108, 3660, 16472, 4117, 14407, 6055, 2655, 3215, 25513, 14407, 4724, 8592, 28820, 10874, 25708], "avg_logprob": -0.2455842410740645, "compression_ratio": 1.8186813186813187, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2971.47, "end": 2972.47, "word": "وDichlorination", "probability": 0.552685546875}, {"start": 2972.47, "end": 2972.97, "word": " وشوفوا", "probability": 0.810302734375}, {"start": 2972.97, "end": 2973.21, "word": " كم", "probability": 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المثل", "probability": 0.7413736979166666}, {"start": 2979.15, "end": 2979.71, "word": " او", "probability": 0.8212890625}, {"start": 2979.71, "end": 2980.09, "word": " على", "probability": 0.8896484375}, {"start": 2980.09, "end": 2981.51, "word": " الحلقة", "probability": 0.97900390625}, {"start": 2981.51, "end": 2981.75, "word": " بدي", "probability": 0.61767578125}, {"start": 2981.75, "end": 2982.01, "word": " كل", "probability": 0.432861328125}, {"start": 2982.01, "end": 2982.65, "word": " النواتج", "probability": 0.875732421875}, {"start": 2982.65, "end": 2983.33, "word": " الممكنة", "probability": 0.9420572916666666}, {"start": 2983.33, "end": 2984.37, "word": " وهنا", "probability": 0.47613525390625}, {"start": 2984.37, "end": 2984.57, "word": " كل", "probability": 0.970703125}, {"start": 2984.57, "end": 2985.03, "word": " النواتج", "probability": 0.9432373046875}, {"start": 2985.03, "end": 2985.53, "word": " الممكنة", "probability": 0.9803059895833334}, {"start": 2985.53, "end": 2986.03, "word": " هذا", "probability": 0.78076171875}, {"start": 2986.03, "end": 2986.75, "word": " بحاجة", "probability": 0.9920654296875}, {"start": 2986.75, "end": 2987.23, "word": " انكوا", "probability": 0.8098958333333334}, {"start": 2987.23, "end": 2987.83, "word": " تتدربوا", "probability": 0.91494140625}, {"start": 2987.83, "end": 2988.31, "word": " بشكل", "probability": 0.9934895833333334}, {"start": 2988.31, "end": 2988.93, "word": " جيد", "probability": 0.987060546875}], "temperature": 1.0}, {"id": 126, "seek": 300604, "start": 2989.62, "end": 3006.04, "text": "و تعرفوا أنواع الهيدروجينز اللي موجودة و تحددوا كام ناتج بيطلع عندهم من ال monochlorination و ال dichlorination ترسموهم بعد ما ترسموهم انتبهوا إذا في أشكال متشابهة انه ما تكرروهاش وبهيك بننهي اليوم ان شاء الله", "tokens": [2407, 37279, 28480, 14407, 14739, 14407, 3615, 2423, 3224, 25708, 2288, 29245, 9957, 11622, 13672, 1829, 3714, 29245, 23328, 3660, 4032, 6055, 24401, 3215, 14407, 9122, 10943, 8717, 9307, 7435, 4724, 1829, 9566, 1211, 3615, 43242, 16095, 9154, 2423, 1108, 8997, 6746, 2486, 4032, 2423, 10390, 6746, 2486, 6055, 2288, 38251, 2407, 16095, 39182, 19446, 6055, 2288, 38251, 2407, 16095, 16472, 2655, 3555, 3224, 14407, 11933, 15730, 8978, 5551, 8592, 4117, 6027, 44650, 8592, 16758, 3224, 3660, 16472, 3224, 19446, 6055, 37983, 2288, 2407, 11296, 8592, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984], "avg_logprob": -0.20173267267718173, "compression_ratio": 1.6971153846153846, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2989.62, "end": 2989.82, "word": "و", "probability": 0.35693359375}, {"start": 2989.82, "end": 2990.32, "word": " تعرفوا", "probability": 0.87939453125}, {"start": 2990.32, "end": 2990.68, "word": " أنواع", "probability": 0.9345703125}, {"start": 2990.68, "end": 2991.44, "word": " الهيدروجينز", "probability": 0.7777622767857143}, {"start": 2991.44, "end": 2991.58, "word": " اللي", "probability": 0.643798828125}, {"start": 2991.58, "end": 2992.32, "word": " موجودة", "probability": 0.9873046875}, {"start": 2992.32, "end": 2992.7, "word": " و", "probability": 0.64599609375}, {"start": 2992.7, "end": 2993.44, "word": " تحددوا", "probability": 0.8753662109375}, {"start": 2993.44, "end": 2994.0, "word": " كام", "probability": 0.7275390625}, {"start": 2994.0, "end": 2994.36, "word": " ناتج", "probability": 0.9871419270833334}, {"start": 2994.36, "end": 2994.72, "word": " بيطلع", "probability": 0.90146484375}, {"start": 2994.72, "end": 2994.98, "word": " عندهم", "probability": 0.6868896484375}, {"start": 2994.98, "end": 2995.12, "word": " من", "probability": 0.939453125}, {"start": 2995.12, "end": 2995.22, "word": " ال", "probability": 0.9609375}, {"start": 2995.22, "end": 2996.04, "word": " monochlorination", "probability": 0.65142822265625}, {"start": 2996.04, "end": 2996.2, "word": " و", "probability": 0.93701171875}, {"start": 2996.2, "end": 2996.26, "word": " ال", "probability": 0.80517578125}, {"start": 2996.26, "end": 2997.0, "word": " dichlorination", "probability": 0.7526041666666666}, {"start": 2997.0, "end": 2997.8, "word": " ترسموهم", "probability": 0.9169921875}, {"start": 2997.8, "end": 2998.36, "word": " بعد", "probability": 0.70947265625}, {"start": 2998.36, "end": 2998.52, "word": " ما", "probability": 0.916015625}, {"start": 2998.52, "end": 2999.44, "word": " ترسموهم", "probability": 0.9890625}, {"start": 2999.44, "end": 3000.34, "word": " انتبهوا", "probability": 0.9478515625}, {"start": 3000.34, "end": 3000.56, "word": " إذا", "probability": 0.768310546875}, {"start": 3000.56, "end": 3000.72, "word": " في", "probability": 0.83251953125}, {"start": 3000.72, "end": 3001.16, "word": " أشكال", "probability": 0.9620361328125}, {"start": 3001.16, "end": 3002.18, "word": " متشابهة", "probability": 0.963671875}, {"start": 3002.18, "end": 3002.64, "word": " انه", "probability": 0.534423828125}, {"start": 3002.64, "end": 3002.7, "word": " ما", "probability": 0.6611328125}, {"start": 3002.7, "end": 3003.66, "word": " تكرروهاش", "probability": 0.8272298177083334}, {"start": 3003.66, "end": 3004.7, "word": " وبهيك", "probability": 0.7799072265625}, {"start": 3004.7, "end": 3005.18, "word": " بننهي", "probability": 0.906982421875}, {"start": 3005.18, "end": 3005.5, "word": " اليوم", "probability": 0.967041015625}, {"start": 3005.5, "end": 3005.72, "word": " ان", "probability": 0.473876953125}, {"start": 3005.72, "end": 3005.98, "word": " شاء", "probability": 0.970703125}, {"start": 3005.98, "end": 3006.04, "word": " الله", "probability": 0.94873046875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3006.89125, "duration_after_vad": 2895.673749999989}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..40707ebba23a54f23c6a92f790882b54af569394
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8.srt
@@ -0,0 +1,1566 @@
+
+1
+00:00:18,780 --> 00:00:24,830
+بسم الله الرحمن الرحيم بعد ما اتكلمنا المرة الماضية 
+
+2
+00:00:24,830 --> 00:00:29,410
+عن السكريات المنفردة اتعرفنا عليها ال mono
+
+3
+00:00:29,410 --> 00:00:34,750
+-saccharides الان بدنا نتكلم عن ال di-saccharides 
+
+4
+00:00:34,750 --> 00:00:39,930
+طبعا اللي بنقصده احنا ب di-saccharides انه جزيئين 
+
+5
+00:00:39,930 --> 00:00:43,910
+من ال mono-saccharides يتحدوا مع بعض و بيعملوا 
+
+6
+00:00:43,910 --> 00:00:51,360
+ايش؟ di-saccharide الان مش دائما مش دائمامش دائما 
+
+7
+00:00:51,360 --> 00:00:54,820
+هدول الجزيئين اللي بدهم يتحدوا مع بعض بيكونوا زي
+
+8
+00:00:54,820 --> 00:01:00,140
+بعض يعني يوم بدأ احكي انا عن دايسا كرايد ممكن اجيب 
+
+9
+00:01:00,140 --> 00:01:06,260
+نفس الجزيئين تماما بكل محتوياتهم طبعا بالتأكيد ال
+
+10
+00:01:06,260 --> 00:01:09,680
+stereo chemistry تكون نفس الشيء تماما و يعملوا 
+
+11
+00:01:09,680 --> 00:01:14,040
+دايسا كرايد و ممكن اجيب جزيئين مختلفين و يعملوا
+
+12
+00:01:14,040 --> 00:01:19,820
+دايسا كرايد فمش ضروريمش ضروري ان الـ disaccharide 
+
+13
+00:01:19,820 --> 00:01:26,240
+يكون مكوّن من الجزيئين نفسهم تماما، واضح؟ يعني 
+
+14
+00:01:26,240 --> 00:01:30,560
+ممكن يكون فعلا من نفس الجزيئين مكوّن disaccharide 
+
+15
+00:01:30,560 --> 00:01:36,920
+وممكن يكون من جزيئين مختلفين وهذا اللي هنشوفه لما 
+
+16
+00:01:36,920 --> 00:01:45,550
+نستعرض بعض الـ disaccharides بشكل عام ويعني جداأول 
+
+17
+00:01:45,550 --> 00:01:51,710
+دايسا كارايد بدنا نستعرضه المالتوز، واضح؟
+
+18
+00:01:51,710 --> 00:01:57,970
+المالتوز، الآن هذا الديسا كارايد مكون من سكرين
+
+19
+00:01:57,970 --> 00:02:03,070
+جولوكوز، لكن فيهم اختلاف في ال stereo chemistry 
+
+20
+00:02:03,470 --> 00:02:08,830
+فيهم اختلاف في ال stereo chemistry واحد منهم واحد
+
+21
+00:02:08,830 --> 00:02:14,730
+منهم alpha glucose والتاني منهم beta glucose الآن 
+
+22
+00:02:14,730 --> 00:02:19,390
+اللي بتذكروا معنا قولنا احنا ان ال alpha و ال beta
+
+23
+00:02:19,390 --> 00:02:24,930
+sugars بصيروا لما نسكر اخر carbon اللي سمناها ال
+
+24
+00:02:24,930 --> 00:02:29,300
+anomeric carbon و نعملفي حالة السكريات هذه الميزات
+
+25
+00:02:29,300 --> 00:02:35,240
+الكربونات ال fifth chiral center فإذا ال OH كانت 
+
+26
+00:02:35,240 --> 00:02:40,020
+للأسفل على هذا الكربون تحديدا بنقول هذا السكر 
+
+27
+00:02:40,020 --> 00:02:46,120
+Alpha وإذا كانت للأعلى Beta الآن هذا ال maltose لو 
+
+28
+00:02:46,120 --> 00:02:50,760
+بتطلع عليه أنا هيمكون من سكر متصل في ال anomeric
+
+29
+00:02:50,760 --> 00:02:54,560
+carbon لاحظوا أنا تركيزي على أي كربون ال anomeric 
+
+30
+00:02:54,560 --> 00:02:59,820
+carbon نكون معلمينها إلى أساساهذه السكرين المتحدين
+
+31
+00:02:59,820 --> 00:03:07,180
+الآن اتطلعوا على واحد منهم ال oxygen فيه alpha
+
+32
+00:03:07,180 --> 00:03:18,840
+واضح التاني منهم ال oxygen فيه betaواضح فالملتوز
+
+33
+00:03:18,840 --> 00:03:24,740
+بيكون في هذه الحالة امكون من Alpha-Glucose مع Beta
+
+34
+00:03:24,740 --> 00:03:29,660
+-Glucose هى دول اتنين قبل ما يتصلوا مع بعض هذا 
+
+35
+00:03:29,660 --> 00:03:35,440
+بهذا الشكل كان OH كان Alpha-Glucose هذا كان Beta
+
+36
+00:03:35,440 --> 00:03:41,320
+-Glucose فاتنين اتصلوا مع بعض من خلال موقع اربعة 
+
+37
+00:03:41,320 --> 00:03:45,060
+لما ناخد الترقيم واحد اتنين تلاتة اربعة هذا الموقع
+
+38
+00:03:46,020 --> 00:03:49,540
+أربعة اتحدوا من خلال هذه ال Oxygenة اللي في موقع 
+
+39
+00:03:49,540 --> 00:03:55,920
+أربعة عملوا رابطة واضح فصار عند المركب مكوّن من 
+
+40
+00:03:55,920 --> 00:04:03,040
+Alpha و من Dبيتا جولوكوز وعشان هيك لما بدنا نسميه 
+
+41
+00:04:03,040 --> 00:04:09,900
+ممكن انه نقرأ الاسم تبعه هتحسوا انه مش صعب هو ممكن
+
+42
+00:04:09,900 --> 00:04:15,120
+تتخيلوا مركب بيتا جولوكوز لو حطيت ع موقع اربعة مثل 
+
+43
+00:04:15,120 --> 00:04:19,960
+شو كنتوا هتسموه four مثل بيتا جولوكوز
+
+44
+00:04:23,450 --> 00:04:29,690
+الاسم الـ Beta في آخر الكلام Beta-D-Glucobiranose
+
+45
+00:04:29,690 --> 00:04:35,170
+مش سمناه لأن جولوكوزم سكرة حلقة سداسية
+
+46
+00:04:35,170 --> 00:04:40,030
+Glucobiranose وD و Beta لأن هذه موجودة في الوضع 
+
+47
+00:04:40,030 --> 00:04:45,410
+Beta الآن هذا على موقع أربعة هي على موقع أربعة من 
+
+48
+00:04:45,410 --> 00:04:50,950
+خلال ال Oxygen متحد بإيش ب Alpha-D-Glucobiranose 
+
+49
+00:04:51,620 --> 00:04:57,800
+واضح الفكرة؟ فيذكر الاسم العام على موقع أربعة من 
+
+50
+00:04:57,800 --> 00:05:05,690
+هذا السكر، إيش موجود عنده على موقع أربعة؟الفا دي 
+
+51
+00:05:05,690 --> 00:05:08,890
+جلوكو بايرانوس طبعا اتصاله من خلال ال O عشان هيك 
+
+52
+00:05:08,890 --> 00:05:13,490
+كتبنا O فاللي بده يفهم الاسم الاسم مش صعب انه هاي 
+
+53
+00:05:13,490 --> 00:05:18,290
+المركب اللي عندى بيتا جلوكو بايرانوس على موقع
+
+54
+00:05:18,290 --> 00:05:22,650
+اربعة منه ايش ايجا نعتبرها بين قوسينAlpha
+
+55
+00:05:22,650 --> 00:05:28,230
+Glucobiranose فهذا سكر الملتوز ببساطة هذه الأشياء 
+
+56
+00:05:28,230 --> 00:05:34,030
+بيبقى تفهموا فيها الأفكار العامة فالملتوز من سكرين 
+
+57
+00:05:34,030 --> 00:05:38,350
+جولوكوز لكن اتنين مش Alpha Alpha ولا Beta Beta
+
+58
+00:05:38,350 --> 00:05:46,590
+Alpha مع Betaالان بيجيني سكر تاني السيلو بيوز
+
+59
+00:05:46,590 --> 00:05:55,730
+السيلو بيوز متحد من سكرين متفقين تماما بيتا جلوكو 
+
+60
+00:05:55,730 --> 00:06:00,550
+بيرانوز مع بيتا جلوكو بيرانوز واضح؟ ولذلك لو انا 
+
+61
+00:06:00,550 --> 00:06:07,550
+بدأ اطلع على هذا السكر هذا بيتا ولا لا؟ بيتا وعلى 
+
+62
+00:06:07,550 --> 00:06:14,780
+هذا السكرهذه أيضًا Beta فلما بنسميه نسبة لهذا Beta 
+
+63
+00:06:14,780 --> 00:06:20,740
+D Glucopyranose متحد من موقع أربعةواحد اتنين تلاتة
+
+64
+00:06:20,740 --> 00:06:25,880
+اربعة متحد من موقع اربعة من خلال ال oxygen ال beta
+
+65
+00:06:25,880 --> 00:06:31,160
+D-glucobiranose واضح يعني هذا كأننا بنقول beta D
+
+66
+00:06:31,160 --> 00:06:36,660
+-glucobiranose يحمل على موقع اربعة beta D
+
+67
+00:06:36,660 --> 00:06:42,100
+-glucobiranose واضح الفكرة فال cellobiose بيكون من 
+
+68
+00:06:42,100 --> 00:06:50,330
+سكرين متماثلينتماما، لاحظوا قداش نسبة الخلاف اللي 
+
+69
+00:06:50,330 --> 00:06:56,450
+بتعمل يعني مركبات مختلفة، يعني انا بحكي عن 
+
+70
+00:06:56,450 --> 00:07:02,330
+Glucopyranose و Glucopyranose و بحكي عن هذا Beta
+
+71
+00:07:02,330 --> 00:07:06,870
+في الحالتين، بس التاني مرة Beta و مرة ايش Alpha 
+
+72
+00:07:07,710 --> 00:07:14,870
+خلاف بسيط جدا بس كايرال سنتر واحد، الآن بعد شوية
+
+73
+00:07:14,870 --> 00:07:19,770
+هتكتشفوا ان هذا الخلاف البسيط جدا في كايرال سنتر
+
+74
+00:07:19,770 --> 00:07:26,510
+الوحيد بيتبع خلاف كبير جدا جدا جدا في الخواص بعد
+
+75
+00:07:26,510 --> 00:07:31,760
+ذلك للمراكباتيعني لما ييجيوا الجزيئات الـ
+
+76
+00:07:31,760 --> 00:07:35,200
+disaccharides بدهم يعملوا polysaccharides هاي
+
+77
+00:07:35,200 --> 00:07:38,540
+disaccharide و خلّينا نعتبر هاي كمان disaccharide
+
+78
+00:07:38,540 --> 00:07:43,120
+هذا كان من Beta و Beta و هذا كان من Beta و Alpha
+
+79
+00:07:43,120 --> 00:07:47,660
+الان اللي كان من Alpha و Beta الملتوز بيعمل جزئ 
+
+80
+00:07:47,660 --> 00:07:56,080
+كبير اسمه نشا او glycogenاللي هي تخزين أو أماكن 
+
+81
+00:07:56,080 --> 00:07:59,380
+تخزين ال carbohydrates سواء في النبات أو في
+
+82
+00:07:59,380 --> 00:08:03,400
+الحيوان وهذه بتدوب في الميه وبيقدر البني آدم 
+
+83
+00:08:03,400 --> 00:08:07,000
+يهضمها يعني البني آدم لما بياكل النشويات بيقدر 
+
+84
+00:08:07,000 --> 00:08:12,180
+بسهولة يحللها للسكريات الأولية بتاعتها أكيد الآن 
+
+85
+00:08:12,180 --> 00:08:16,060
+اللي مكوّن من ال beta و ال beta هيجي يعمل ال 
+
+86
+00:08:16,060 --> 00:08:20,600
+cellulose هيعمل الخشب البني آدم بيقدرش يهضم الخشب
+
+87
+00:08:20,600 --> 00:08:27,570
+الآن هتيجي تقوله شو الفرق؟بين أساس الخشب و أساس
+
+88
+00:08:27,570 --> 00:08:33,270
+النشا أساس الخشب cellobiose و اتحد و أعطاني 
+
+89
+00:08:33,270 --> 00:08:39,110
+cellulose و أساس النشا الملتوز و أعطاني starch
+
+90
+00:08:39,110 --> 00:08:46,230
+واضح فقط مختلفين هدول الاتنين بواحد من السكريات
+
+91
+00:08:46,230 --> 00:08:49,770
+جولوكوز جولوكوز صح جولوكوز جولوكوز بس هذا beta و
+
+92
+00:08:49,770 --> 00:08:55,240
+beta هذا beta و alphaمخيلوا كيف اختلاف بسيط في ال
+
+93
+00:08:55,240 --> 00:09:00,740
+stereochemistry بيقدر الاختلاف كبير بعد هيك في 
+
+94
+00:09:00,740 --> 00:09:05,480
+الخواص و في الاستفادة من المركبات بيجينا سكر 
+
+95
+00:09:05,480 --> 00:09:15,960
+الحليب ال lactoseاللاكتوز أيضا في جولوكوز لكن في
+
+96
+00:09:15,960 --> 00:09:20,900
+جالاكتوز يعني هدولا ال stereo chemical centers
+
+97
+00:09:20,900 --> 00:09:26,320
+اتغير فيهم اكتر كل الفروقات بينهم هي فروقات ايش 
+
+98
+00:09:26,320 --> 00:09:30,500
+لحتى لها ال stereo chemistry يعني هذه الوحدة مش
+
+99
+00:09:30,500 --> 00:09:36,340
+بيتا جولوكوز في هذه الحالة الفا جولوكوز متحد مع
+
+100
+00:09:36,340 --> 00:09:42,300
+بيتا جالاكتوزعشانك لو ذكرنا الاسم العام هتلاحظوا
+
+101
+00:09:42,300 --> 00:09:47,260
+في الآخر Alpha D Glucopyranose هي ال Alpha D 
+
+102
+00:09:47,260 --> 00:09:54,480
+Glucopyranose وشايفين أنها Alpha الآن متحد من موقع 
+
+103
+00:09:54,480 --> 00:10:01,340
+أربعة ال Beta D Galactopyranose طبعا بنكتب Beta D
+
+104
+00:10:01,340 --> 00:10:07,450
+Galactopyranoseال YL اللي هي بصفته أصبح مجموعة زي 
+
+105
+00:10:07,450 --> 00:10:14,330
+ما بقول مثل اثل بروبل ال YL لأنه أصبح مجموعة واضحة 
+
+106
+00:10:14,330 --> 00:10:20,630
+الفكرة؟ هذا ال lactose طبعا بيجي صاحبنا، مين
+
+107
+00:10:20,630 --> 00:10:27,330
+صاحبنا؟السكاروز ماحدش اقول عن السكاروز العدو
+
+108
+00:10:27,330 --> 00:10:33,030
+تبعنا، يعني في ناس دائما متطرفين في الحكم على اللي 
+
+109
+00:10:33,030 --> 00:10:37,090
+هي هذه الأشياء، كل هذه السكريات و كل حتى الدهون 
+
+110
+00:10:37,090 --> 00:10:40,730
+بتلزم للإنسان، بس المشكلة مش أن الإنسان ياخد 
+
+111
+00:10:40,730 --> 00:10:45,340
+سكريات و ياخد دهونالمشكلة أنه ياخدها بإفراط يعني 
+
+112
+00:10:45,340 --> 00:10:49,160
+الإنسان بحاجة للسكريات، بحاجة للدهون بالتأكيد، 
+
+113
+00:10:49,160 --> 00:10:53,940
+بحاجة للكلسترول، بحاجة لكل إشي لكن الإفراط في أي 
+
+114
+00:10:53,940 --> 00:10:58,840
+شغل هو اللي بيعمل عندنا إيش المشكلة الآن لو إجينا 
+
+115
+00:10:58,840 --> 00:11:02,640
+اتطلعنا على السكروز اللي هو السكر اللي إحنا
+
+116
+00:11:02,640 --> 00:11:07,540
+بنستعمله هتلاحظوا مرة تانية في عندى Alpha 
+
+117
+00:11:07,540 --> 00:11:11,680
+-Glucopyranose هاي Alpha هذه شايفينها؟ 
+
+118
+00:11:14,950 --> 00:11:19,930
+طالما لا أسفل إذا هذه إيش؟ Alpha لكن المرة هذه
+
+119
+00:11:19,930 --> 00:11:27,030
+الاتحاد تبعه مش من موقع أربعة هو متحد ب fractose
+
+120
+00:11:27,030 --> 00:11:33,390
+واضح؟ هو متحد ب fractose و ال fractose keto sugar
+
+121
+00:11:33,390 --> 00:11:38,370
+لما أخدنا السكريات قلنا إن في عندنا ال doses من ال
+
+122
+00:11:38,370 --> 00:11:43,920
+aldehydesو Ketosis لفراكتوز كيتو شوجار و لما بيسكر
+
+123
+00:11:43,920 --> 00:11:50,240
+بيسكر على السكر خماسي السكر الخماسي فيورانوز و من 
+
+124
+00:11:50,240 --> 00:11:56,020
+الفيورانوز متحد من موقع ايش؟ واحد واضح؟ الان هذا
+
+125
+00:11:56,020 --> 00:12:04,630
+الفيورانوز لما بتطلع فيهبيتا واضح؟ اذا هذا بيتا
+
+126
+00:12:04,630 --> 00:12:09,270
+عشانك هتلاقوا الاسم تبعه اعتبروا ان هذا هو الأصل
+
+127
+00:12:09,270 --> 00:12:14,010
+وهذه هي الاش المجموعة اللي جاية على الأصل واضح؟
+
+128
+00:12:14,010 --> 00:12:19,950
+فهتلاحظوا بيتا دي فراكتو فيورانوزيل طبعا
+
+129
+00:12:19,950 --> 00:12:26,210
+فيورانوزيل لأنه جاي ايش؟ مجموعة متحدة مع الف دي 
+
+130
+00:12:26,210 --> 00:12:33,150
+غلوكوما كتبش هنا by rhinos، كتب by rhinocide، ليش؟ 
+
+131
+00:12:33,150 --> 00:12:37,790
+لأن الاتحاد تم هنا من موقع واحد، لاحظوا في 
+
+132
+00:12:37,790 --> 00:12:41,270
+السكريات اللي قبل شوية، لما كنا نيجع هذا السكر، 
+
+133
+00:12:41,270 --> 00:12:45,150
+الاتحاد تم من أي موقع؟ أربعة، هنا الاتحاد تم من 
+
+134
+00:12:45,150 --> 00:12:53,080
+موقع واحد، فإذا هذه الرابطة بطلت OH صارت O-Carbon
+
+135
+00:12:53,080 --> 00:12:58,340
+معنا ذلك هذه الرابطة ايش بدها تكون؟ Glycosidic
+
+136
+00:12:58,340 --> 00:13:02,280
+bond واضح؟ عشان Glycosidic bond عشان تكون 
+
+137
+00:13:02,280 --> 00:13:08,400
+Glycoside هنحط ايش؟ Glucoburanoside لاحظته هنا 
+
+138
+00:13:08,400 --> 00:13:12,640
+كلمة؟ Buranoside لو رجعتوا على الأسماء اللي قبل
+
+139
+00:13:12,640 --> 00:13:19,240
+كان حط Glucoburanose لأن هذه كانت تكون OHفي كل
+
+140
+00:13:19,240 --> 00:13:23,280
+اللي قبل هذه كانت OH غلوكو باي رانوس سواء كان 
+
+141
+00:13:23,280 --> 00:13:28,860
+Alpha أو Beta لكن هنا بطلت OH صار الاتحاد من عندها
+
+142
+00:13:28,860 --> 00:13:33,420
+و عشان هيك صارت هذه الرابطة Glycosidic bond فقال 
+
+143
+00:13:33,420 --> 00:13:38,300
+غلوكو باي رانوسايد غلوكو باي رانوسايد فالحقيقة
+
+144
+00:13:40,010 --> 00:13:46,150
+السكر اللى فيه two glycosidic bonds هو سكر ايش 
+
+145
+00:13:46,150 --> 00:13:50,210
+السكروز انتبهوا لو كانوا بيسألكوا multiple choice 
+
+146
+00:13:50,210 --> 00:13:58,670
+الان هذه الرابطة carbon و carbon هذى glycosidic 
+
+147
+00:13:58,670 --> 00:14:04,230
+bond ولا لأ و هذا الرابطة glycosidic bond فلما 
+
+148
+00:14:04,230 --> 00:14:10,320
+نيجي نطلع احنا حقيقة على السكروزكم جليكوسايدك بوند 
+
+149
+00:14:10,320 --> 00:14:18,940
+فيه؟ تنتين لو رجعنا اتطلعنا على السكريات 
+
+150
+00:14:18,940 --> 00:14:25,100
+اللي قبل هنا كم جليكوسايدك بوند؟ واحدة ماحدش يقول
+
+151
+00:14:25,100 --> 00:14:29,520
+هذه جليكوسايدك بوند ليش؟ لأن الجليكوسايدك بوند 
+
+152
+00:14:29,520 --> 00:14:34,700
+اللي بتتكون على الكايرال سنتر الأخير على هذه مش 
+
+153
+00:14:34,700 --> 00:14:40,650
+على هذا الموقع أربعةواضح؟ يعني مش اي او كربون
+
+154
+00:14:40,650 --> 00:14:47,850
+glycosidic bond ال glycosidic bond مرتبطة بأي بأي
+
+155
+00:14:47,850 --> 00:14:52,630
+كربون بال anomeric carbon اللي كانت أساسا الديهايد
+
+156
+00:14:52,630 --> 00:14:56,350
+واضح؟ ولذلك هذه glycosidic bond بس هذه مش 
+
+157
+00:14:56,350 --> 00:15:01,390
+glycosidic bond واضح؟ فلو أنا اجيت على ال lactose
+
+158
+00:15:01,390 --> 00:15:08,540
+في one glycosidic bond لو رجعتعلى السيلو بيوز على 
+
+159
+00:15:08,540 --> 00:15:13,640
+سبيل المثال برضه أي واحدة anomeric carbon كل سكر 
+
+160
+00:15:13,640 --> 00:15:17,780
+فيه two anomeric carbon مظبوط ولا لأ هذه فيها 
+
+161
+00:15:17,780 --> 00:15:24,200
+glycosidic bond هذه فيها لذلك في السيلو بيوز في 
+
+162
+00:15:24,200 --> 00:15:30,950
+عنده one glycosidic bond هذه لأواضحة الفكرة؟ يعني 
+
+163
+00:15:30,950 --> 00:15:34,970
+انا عندي two anomeric carbons مين فيهم glycosidic
+
+164
+00:15:34,970 --> 00:15:40,630
+bond؟ هذي ال O H glycosidic، هذي، اه واضحة الفكرة؟ 
+
+165
+00:15:40,630 --> 00:15:44,950
+فدائما لما بدنا نعرف كام glycosidic bond، نرجع على 
+
+166
+00:15:44,950 --> 00:15:53,670
+الملتوز مثلا، هذي ال anomeric carbons الآن لو
+
+167
+00:15:53,670 --> 00:15:57,690
+إجينا سألنا هذي glycosidic bond؟ O H، هذي
+
+168
+00:15:59,540 --> 00:16:07,100
+Glycosidic bond فالملتوز والسيلوبيوز واللاكتوز 
+
+169
+00:16:07,100 --> 00:16:11,380
+هدولة فيهم و one glycosidic bond و التانية عادية
+
+170
+00:16:11,380 --> 00:16:16,740
+عشان ايه كنتوا تلاقوا؟ Glucopyranose عادي لكن لما
+
+171
+00:16:16,740 --> 00:16:23,340
+وصلنا للسكروز لو اجينا سألنا وين ال anomeric
+
+172
+00:16:23,340 --> 00:16:24,180
+carbons؟
+
+17
+
+223
+00:20:43,810 --> 00:20:47,710
+قلنا عنه بيتا و بيتا يعني خلينا نركز احنا على
+
+224
+00:20:47,710 --> 00:20:52,810
+الملتوز الملتوز كان من ألفة و بيتا جولوكوز مكون
+
+225
+00:20:52,810 --> 00:20:57,790
+واضح؟ و السيلو بيوز من بيتا و بيتا جولوكوز الآن
+
+226
+00:20:57,790 --> 00:21:02,470
+هدولة لما بيجوا بيعملوا بوليمار كبير لما بيعملوا
+
+227
+00:21:02,470 --> 00:21:06,750
+بوليمار كبير بيكون هم الوحدة الأساسية المتكررة في
+
+228
+00:21:06,750 --> 00:21:12,930
+البوليمار بيعطوناالـ starch أو النشا في حالة ما
+
+229
+00:21:12,930 --> 00:21:18,570
+نتكلم عن إيش؟ عن الملتوز، في حالة ما نتكلم عن
+
+230
+00:21:18,570 --> 00:21:22,990
+السيلوبايوز، بيعطينا السيليلوز، واضح؟ فالملتوز
+
+231
+00:21:22,990 --> 00:21:29,130
+بيعطيني إيش؟ النشا، starch، السيلوبايوز بيعطيني
+
+232
+00:21:29,130 --> 00:21:36,470
+السيليلوز، الخشب، واضح؟ بولمار كبير طبعاًلاحظوا
+
+233
+00:21:36,470 --> 00:21:40,990
+عاد حسب ال polymer اللي بتكون يعني يوم ما نحكي عن
+
+234
+00:21:40,990 --> 00:21:45,550
+polymer يعني عدد كبير من الشغلات هتلاحظوا في علم
+
+235
+00:21:45,550 --> 00:21:50,250
+ال polymerization هذا العدد ممكن يكون 300 وحدة
+
+236
+00:21:50,250 --> 00:21:56,200
+ممكن يكون الف ممكن يكون تلت تلافتمام؟ حسب طريقة
+
+237
+00:21:56,200 --> 00:21:59,420
+الارتباط اللى موجودة في هذا العدد وحسب عدد
+
+238
+00:21:59,420 --> 00:22:03,760
+الجزيئات او الوحدات المكونة له الآن وحدة ال stars
+
+239
+00:22:03,760 --> 00:22:08,300
+هي ايش؟ ال maltose هذه الوحدة اللى مكونة من سكرين
+
+240
+00:22:08,300 --> 00:22:13,160
+حسب كمية الأشياء المتصلة بيصير عند نوع ال polymer
+
+241
+00:22:13,160 --> 00:22:16,340
+عشانك انتوا بال plastic بتلاحظوا في عندكوا أنواع
+
+242
+00:22:16,340 --> 00:22:21,460
+كتيرةفي النيلون في عندكم أنواع كتيرة هذا بيصير
+
+243
+00:22:21,460 --> 00:22:25,860
+يدخل فيه جانب الصناعة انه قداش العدد اللي خلناه
+
+244
+00:22:25,860 --> 00:22:31,640
+يتحد تقريبا يعمل polymer هالخليه 300 جزء و وحدة ال
+
+245
+00:22:31,640 --> 00:22:37,640
+polymer 3000 2000 واضح الفكرة؟ الآن نفس الفكرة من
+
+246
+00:22:37,640 --> 00:22:43,350
+الملتوز هلاحظ ان في انهاالـ starch لو حللته
+
+247
+00:22:43,350 --> 00:22:47,990
+بيعطيني ملتوز، الملتوز لو حللته بيعطيني جولوكوز،
+
+248
+00:22:47,990 --> 00:22:52,830
+لكن جولوكوز Alpha
+
+249
+00:22:53,990 --> 00:22:58,410
+وبيتاجولوكوز لكن هذه الوحدة المتكررة وحدة الملتوز
+
+250
+00:22:58,410 --> 00:23:03,350
+اعملوا منها عدد كبير الان لاحظوا ان النشا مكون من
+
+251
+00:23:03,350 --> 00:23:08,230
+شغلتين من اميلوز بنسبة 20% والباقي تقريبا
+
+252
+00:23:08,230 --> 00:23:15,200
+اميلوبكتل ايش بيفرقوا هدولة الشغلتين؟بعدد الجزيئات
+
+253
+00:23:15,200 --> 00:23:19,980
+المكونة له بطريقة الاتحاد يعني ال amylose في
+
+254
+00:23:19,980 --> 00:23:25,840
+جولوكوز units عادة بيكون عددها ما يقارب بين خمسين
+
+255
+00:23:25,840 --> 00:23:30,260
+لتلتمية جولوكوز unit لكن أهم شيء بيميزها أن هي
+
+256
+00:23:30,260 --> 00:23:37,970
+موجودة في إيش؟بسلاسل بدون تفرعات، واضح؟ سلاسل بهذا
+
+257
+00:23:37,970 --> 00:23:42,830
+الشكل بدون ما يصير فيها تفرعات، العدد تبع ال
+
+258
+00:23:42,830 --> 00:23:47,410
+geolocose units بيكون ما بين خمسين إلى تلتمية
+
+259
+00:23:47,410 --> 00:23:52,770
+geolocose unit والاتحاد زي ما انتوا عارفين نمر
+
+260
+00:23:52,770 --> 00:23:58,270
+أربعة من هان وبتحد من واحد مع الجزء التانييعني
+
+261
+00:23:58,270 --> 00:24:02,190
+احنا لما كنا نتكلم عن ال مالتوز، كنا هنا في عنا
+
+262
+00:24:02,190 --> 00:24:07,550
+الاتحاد مع أربعة أو سابين واحد، أوقتش، الآن لما
+
+263
+00:24:07,550 --> 00:24:11,150
+بتعمل polymer، بيجيب التحد منها، يعني لو انتوا
+
+264
+00:24:11,150 --> 00:24:16,630
+تذكرتوا المالتوز، مش كانت هذه تكون فيهقواتش لما
+
+265
+00:24:16,630 --> 00:24:20,930
+نحكي عن الملتوز لوحده الآن بيصير يتحد من هذه
+
+266
+00:24:20,930 --> 00:24:23,690
+القواتش عشان يعمل ال polymer يعني القواتش اللي
+
+267
+00:24:23,690 --> 00:24:28,610
+كانت ماتروكة فاضية بيصير يتحد من خلالها مع موقع
+
+268
+00:24:28,610 --> 00:24:33,130
+أربعة من وحدة ملتوز تانية بطلع عنده جزء كبير
+
+269
+00:24:33,130 --> 00:24:34,210
+بنسميه إيش
+
+270
+00:24:37,020 --> 00:24:43,020
+الاميلوز الاميلوز هذا احد مكونات النشا الان النشا
+
+271
+00:24:43,020 --> 00:24:49,260
+في مكون تاني الاميلوبكتين الاميلوبكتين في ما بين
+
+272
+00:24:49,260 --> 00:24:53,460
+تلتمية الى خمستلاف جولوكوز units يعني الجولوكوز
+
+273
+00:24:53,460 --> 00:24:59,860
+units اللى في عددها اكبر لكن اهم شغل فيه is
+
+274
+00:24:59,860 --> 00:25:06,920
+هايلبراجد واضح يعني الاميلوز سلسلةالـ amylobectin
+
+275
+00:25:06,920 --> 00:25:13,440
+في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300
+
+276
+00:25:13,440 --> 00:25:17,220
+إلى 5000 جولوكوز units is a highly branched
+
+277
+00:25:17,220 --> 00:25:21,660
+molecule او highly branched molecule chains with
+
+278
+00:25:21,660 --> 00:25:24,360
+consecutive one four links شوفنا كيف one four
+
+279
+00:25:24,360 --> 00:25:28,520
+links الارتباط ال average يعني كل مجموعة حوالي
+
+280
+00:25:28,520 --> 00:25:35,070
+خمسة وعشرين لتلاتين وحدةو بعدين بيجي تفرع 25 ل 30
+
+281
+00:25:35,070 --> 00:25:41,110
+و تفرع بيصير الجزء أشماله highly branched واضح
+
+282
+00:25:41,110 --> 00:25:48,470
+فواضح أن جزء ال amylobectin أكبر من ال amylose و
+
+283
+00:25:48,470 --> 00:25:55,150
+بنفس الوقت اللي بيميزه التفرعات واضح فال amylose
+
+284
+00:25:55,150 --> 00:26:02,220
+is a chain moleculeالـ amylobectin هو جزئ عالي جزئ
+
+285
+00:26:02,220 --> 00:26:11,520
+فيه تفرعات كتيرة طبعا هذه كل أشكال تقريبية بتوضح
+
+286
+00:26:11,520 --> 00:26:20,720
+لنا كيف بيتكونوا هذول الجزيئات الأن لو جينا من ال
+
+287
+00:26:20,720 --> 00:26:30,470
+amylose أيضاغير النشق بمكوينه يعني من الملتوز كان
+
+288
+00:26:30,470 --> 00:26:35,130
+في عنده ال starch اللي هو مكوّن من amylose و
+
+289
+00:26:35,130 --> 00:26:40,470
+mylobectin أيضًا من الملتوز في عنده الجليكوجين ال
+
+290
+00:26:40,470 --> 00:26:45,470
+starch ما كان تخزين ال carbohydratesفي النبات
+
+291
+00:26:45,470 --> 00:26:49,410
+الجليكوجين مكان تخزين ال carbohydrates في
+
+292
+00:26:49,410 --> 00:26:55,750
+الحيوانات برضه هو فيه جولوكوز units لكن حوالي مائة
+
+293
+00:26:55,750 --> 00:27:00,590
+ألف جولوكوز unit لاحظوا العدد في الجليكوجين
+
+294
+00:27:00,590 --> 00:27:06,810
+جليكوجين بيزيد بشكل كبير وبرنشد يعني كل ما بين كل
+
+295
+00:27:06,810 --> 00:27:11,010
+تمانية ل 12 جولوكوز unit خلينا هيك نتخيل هتلاحظوا
+
+296
+00:27:11,010 --> 00:27:17,930
+ان في عندكم إيشالجزء هذا الجليكوجين بيكون أيضا
+
+297
+00:27:17,930 --> 00:27:24,090
+highly branched الآن الجليكوجين بيجي من الجلوكوز
+
+298
+00:27:24,090 --> 00:27:30,130
+اللي بيمتص من أمعاء produced from glucose that is
+
+299
+00:27:30,130 --> 00:27:35,930
+absorbed from intestines into the blood الآن إيش
+
+300
+00:27:35,930 --> 00:27:41,060
+وظيفته هذا الجليكوجين؟ يمكن مار عليكمبيولوجيا اللي
+
+301
+00:27:41,060 --> 00:27:45,260
+هو توازن السكر helps maintain the glucose balance
+
+302
+00:27:45,260 --> 00:27:49,660
+واضح يعني إذا في عندي جولوكوز ازيادة بيجي و بتخزن
+
+303
+00:27:49,660 --> 00:27:54,340
+وين في الجليكوجين بدخل ضمن البوليمار الآن إذا
+
+304
+00:27:54,340 --> 00:28:00,770
+الجسم نقص عليه الجولوكوزبصير هذا نفسه يفرز أو يعطي
+
+305
+00:28:00,770 --> 00:28:07,930
+الجسم وحدات جولوكوز واضح الفكرة؟ يعني هو كأنه هاي
+
+306
+00:28:07,930 --> 00:28:12,450
+جزيئات الجولوكوز بتقدروا تتخيلوها بتمطس من المعدة
+
+307
+00:28:12,450 --> 00:28:16,030
+المفروض لازم لحرق الأكل الناس اللي بياكلوا كتير
+
+308
+00:28:16,030 --> 00:28:21,510
+okay بنجمع هذه الجزيئات هيعملنا إيش؟جلايكوجين
+
+309
+00:28:21,510 --> 00:28:25,790
+وخزانة الان بعد هيك صار البني ادم عنده ناقص في
+
+310
+00:28:25,790 --> 00:28:31,010
+السكر جد ما فيه ناقص بيصير يطلع له جولوكوز واضح؟
+
+311
+00:28:31,010 --> 00:28:36,090
+واضحة الفكرة العامة خليني اقول العامة جدا
+
+312
+00:28:36,090 --> 00:28:42,890
+لجلايكوجين الان لو طلعنا على ال cellulose ال
+
+313
+00:28:42,890 --> 00:28:48,830
+cellulose هو ال polymerاللي جاي من الـ cellobiose
+
+314
+00:28:48,830 --> 00:28:55,010
+اللي بيعمل الخشب يعني النشا والجليكوجين جايين من
+
+315
+00:28:55,010 --> 00:29:01,430
+وين؟ من الملتوز من الملتوز لكن ال cellulose جاي من
+
+316
+00:29:01,430 --> 00:29:03,410
+ال cellobiose
+
+317
+00:29:05,410 --> 00:29:11,210
+بيتا وبيتا sugar فالcellulose is an unbranched
+
+318
+00:29:11,210 --> 00:29:16,210
+polymer مستقيم مافيش فيه branches of glucose
+
+319
+00:29:16,210 --> 00:29:20,110
+joined by one four beta glycosidic bonds كل
+
+320
+00:29:20,110 --> 00:29:29,390
+هالكلام شفناه لاحظوا معي كيف فرق في الأساس بسيط
+
+321
+00:29:29,390 --> 00:29:37,500
+جدا انه هذا منسيلو بيوز هذا من مالتوز السيلو بيوز
+
+322
+00:29:37,500 --> 00:29:42,260
+و المالتوز متحدين في beta غلوكوز لكن السكر التاني
+
+323
+00:29:42,260 --> 00:29:46,820
+في كل واحدة واحد منهم واحد alpha واحد beta يعني
+
+324
+00:29:46,820 --> 00:29:51,120
+خلينا نقول هنا في عند بيتا و بيتا نفس الاشي في
+
+325
+00:29:51,120 --> 00:29:57,340
+السكرين الآن في المالتوز هذا alpha في السيلو بيوز
+
+326
+00:29:58,430 --> 00:30:03,590
+هذا beta فهذا alpha beta هذا beta beta الآن هذا
+
+327
+00:30:03,590 --> 00:30:07,690
+بيصير ملتوز و بيعملني نشا و glycogen هذا بيصير
+
+328
+00:30:07,690 --> 00:30:12,970
+cellulose و cellobiose و بيعمله ال cellulose الان
+
+329
+00:30:12,970 --> 00:30:16,990
+البني آدم بيقدر يهضم النشا بيقدر يهضم ال glycogen
+
+330
+00:30:16,990 --> 00:30:22,670
+بيقدرش يهضم ال cellulose ال cellulose واضح فال
+
+331
+00:30:22,670 --> 00:30:26,830
+humans and other animals they digest starch and
+
+332
+00:30:26,830 --> 00:30:32,880
+glycogenبيقدروا يهضموا النشق والجليكوجين، الآن
+
+333
+00:30:32,880 --> 00:30:37,360
+الحيوانات
+
+334
+00:30:37,360 --> 00:30:42,610
+والنمليمكن تقولوا النمل صار أقوى من البني آدم يعني
+
+335
+00:30:42,610 --> 00:30:46,550
+هو النمل بيقدر يخضم الخشب و البني آدم مابيقدرش
+
+336
+00:30:46,550 --> 00:30:52,030
+معنا ذلك النمل أقوى من البني آدم هي المشكلة انه
+
+337
+00:30:52,030 --> 00:30:57,150
+كمان مش النمل اللي بيخضم او مش الحيوانات المجترة
+
+338
+00:30:57,150 --> 00:31:01,570
+اللي بتخضم لأ بكتيريا موجودة جوا أمعاها هذه
+
+339
+00:31:01,570 --> 00:31:05,050
+البكتيريا اللي جوا أمعاها بتفرز اللي هو
+
+340
+00:31:08,560 --> 00:31:14,060
+الانزيمات اللى هى ال beta glycosidase اللى بتساعد
+
+341
+00:31:14,060 --> 00:31:19,960
+على عملية ايش ان تقدر تهضم الخشب وتستفيد منه واضح
+
+342
+00:31:19,960 --> 00:31:27,760
+فماني بكتيريا contain beta glycosidase دايما اذا
+
+343
+00:31:27,760 --> 00:31:33,510
+شفتوا هذه النهاية ايش هذاالنزيم Oxidase و
+
+344
+00:31:33,510 --> 00:31:37,870
+Redactase و glycosidase and they can hydrolyze
+
+345
+00:31:37,870 --> 00:31:42,810
+يعني يفككوا ال cellulose فلو احنا قلنالكم ان ال
+
+346
+00:31:42,810 --> 00:31:46,090
+humans can hydrolyze cellulose
+
+347
+00:31:48,210 --> 00:31:52,250
+واضح؟ لكن في بكتيريا كتير بتقدر تعمل هذا الكلام
+
+348
+00:31:52,250 --> 00:31:55,990
+هذه موجودة في ال termites اللي هو النمل الأبيض و
+
+349
+00:31:55,990 --> 00:31:59,510
+ال ruminants اللي هي الحيوانات المجترة اللي
+
+350
+00:31:59,510 --> 00:32:03,050
+بتلاقوها مستعدة تاكل ال .. إيش؟ زي الجمل و زي ..
+
+351
+00:32:03,050 --> 00:32:08,250
+أه اللي بتاكل الخشب فبكتيريا في معدتها بتقدر تدخل
+
+352
+00:32:08,250 --> 00:32:13,450
+على هذا الخشب و تحلله لوحدات السكر بحيث أنه النمل
+
+353
+00:32:13,450 --> 00:32:18,430
+الأبيض أو الحيوانات هذه المجترة تقدر تستفيد منهأو
+
+354
+00:32:18,430 --> 00:32:22,310
+من السكر اللي موجود فيه لكن البني آدم مابيقدرش
+
+355
+00:32:22,310 --> 00:32:26,730
+يخدمه أخر
+
+356
+00:32:26,730 --> 00:32:33,090
+شغلة أخر شغلة بنحكيها بالنسبة لهذا الجزء أنه في
+
+357
+00:32:33,090 --> 00:32:37,870
+عندى بعض ال sugars يمكن أن ينزع منها أكسجين هذه
+
+358
+00:32:37,870 --> 00:32:42,850
+بتفيدنا لما بدنا ندرس ال nuclear acid اللي هي
+
+359
+00:32:42,850 --> 00:32:49,090
+الأحماض النووية ومنهابصير اسمها deoxy sugars يعني
+
+360
+00:32:49,090 --> 00:32:53,470
+لاحظوا هذا ال sugar لما يكون فيه ال oxygen و سكر
+
+361
+00:32:53,470 --> 00:32:58,610
+من خمس كربونات tripose تمام لما نشيل منه oxygen
+
+362
+00:32:58,610 --> 00:33:02,870
+منها يعني في الأصل كان في عنده OH لو شيلنا منه
+
+363
+00:33:02,870 --> 00:33:09,490
+oxygen ايش بيصير اسمه؟ deoxy، deoxy يعني منزوعأه
+
+364
+00:33:09,490 --> 00:33:14,570
+لحظة ميزه .. ميزه رجاء في الكلمات، عشانك احنا
+
+365
+00:33:14,570 --> 00:33:22,080
+بنقول اتعبوا شوية، يعني لو اتينا قولنالكم ضايقزيدا
+
+366
+00:33:22,080 --> 00:33:27,800
+يعني اتنين اه لكن دي منزوعة زي ما كنا نقول
+
+367
+00:33:27,800 --> 00:33:31,760
+hydrogenation, dehydrogenation, hydration,
+
+368
+00:33:32,600 --> 00:33:38,260
+dehydrogenation, halogenation, dehydrogenation فال
+
+369
+00:33:38,260 --> 00:33:43,820
+دي بتاعنا اللي هو العكس فهذا ال beta دي دي
+
+370
+00:33:43,820 --> 00:33:48,860
+oxyribofuranose طب علشه فيورانوز لأنهمن حلقاء
+
+371
+00:33:48,860 --> 00:33:53,520
+خماسية هو ال sugar تبع ال DNA هو عبارة عن Ribose
+
+372
+00:33:53,520 --> 00:33:58,720
+نزعت منه ال Oxygen و لو كان ال Ribose اللي في ال
+
+373
+00:33:58,720 --> 00:34:05,400
+Oxygen بيعملنا ال RNA Ribonucleic Acid لما يكون ال
+
+374
+00:34:05,400 --> 00:34:09,800
+DNA Deoxyribonucleic Acid واضح؟
+
+375
+00:34:12,560 --> 00:34:19,700
+الكلام عام عن اللي هي ال dice carats و عن ال
+
+376
+00:34:19,700 --> 00:34:26,210
+polymers اللي بتكونوا منهم خلينا يعني نبدأنعطي
+
+377
+00:34:26,210 --> 00:34:31,310
+فكرة عامة ليش أنا محتاجها الآن مقارنة مع
+
+378
+00:34:31,310 --> 00:34:37,050
+البروتينات اللي بدنا ناخدها في الفصل الأخير ان شاء
+
+379
+00:34:37,050 --> 00:34:41,910
+الله اللي هو ال amino acids و ال peptides و ال
+
+380
+00:34:41,910 --> 00:34:48,210
+proteins زي ما لاحظته يمكن أهم شغلة في ال
+
+381
+00:34:48,210 --> 00:34:52,290
+polysaccharides أهم شغلة في ال polysaccharides أن
+
+382
+00:34:52,290 --> 00:34:57,650
+هم polymersماذا يعني polymers؟ يعني لما أقول
+
+383
+00:34:57,650 --> 00:35:04,150
+النشا، إيش الوحدة تبعته؟ هتقولولي مالتوز
+
+384
+00:35:04,150 --> 00:35:10,390
+البيسكريدي المالتوز، تمام؟ لو قولت مثلا السيللوز،
+
+385
+00:35:10,390 --> 00:35:15,870
+بوليمر كبير، إيش الوحدة تبعته؟ السيلوبيوز، ولذلك
+
+386
+00:35:15,870 --> 00:35:23,490
+ال polysaccharidesيمكن التعامل معها يكون أسهل كتير
+
+387
+00:35:23,490 --> 00:35:28,790
+من التعامل مع البروتينات ليش؟ لأن ال
+
+388
+00:35:28,790 --> 00:35:32,930
+polysaccharides عندي وحدة و بتتكرر يعني كأن
+
+389
+00:35:32,930 --> 00:35:37,110
+الإنسان بيقدر يقول عنهم ان they are real polymers
+
+390
+00:35:37,110 --> 00:35:43,710
+واضح؟ ال polymers مكون من إيش؟مونومارز تتحد تصير
+
+391
+00:35:43,710 --> 00:35:47,910
+دايمارز، ترايمارز، تترامارز، في الآخر إيش؟
+
+392
+00:35:47,910 --> 00:35:55,190
+بوليمارز، فالبوليمار من ناحية المبدأ وحدة متكررة،
+
+393
+00:35:55,190 --> 00:36:00,390
+البوليمار وحدة إيش مالها؟ متكررة، فلمّا أجي أقول
+
+394
+00:36:00,390 --> 00:36:05,990
+starch polymer ما وحدته المتكررة؟ الملتوز، انتهى
+
+395
+00:36:06,580 --> 00:36:13,060
+واضح؟ الآن لما بدي اجي .. لما
+
+445
+00:41:01,570 --> 00:41:07,910
+glycine, alanine, tryptophan, cysteine كذا كذا
+
+446
+00:41:07,910 --> 00:41:14,270
+هتلاحظوا أنه مطلوب منناانحدد الترتيب تبع ال amino
+
+447
+00:41:14,270 --> 00:41:17,690
+acids ولذلك ال proteins لو الإنسان بده يستعمل
+
+448
+00:41:17,690 --> 00:41:23,010
+الكلام بدقة أكثر they are macro molecules جزيئات
+
+449
+00:41:23,010 --> 00:41:30,490
+كبيرة macro molecules جزيئات كبيرة أكثر منهم إيش
+
+450
+00:41:30,490 --> 00:41:39,610
+polymers they are macro molecules أكثر منهمبولمار
+
+451
+00:41:39,610 --> 00:41:46,310
+طبعا فيهم نوعا ما شيء مشترك بيخلي بعض الناس يقولوا
+
+452
+00:41:46,310 --> 00:41:54,670
+ممكن تجاوزا نعتبر ال protein بولمار ليش؟ لأنه لو
+
+453
+00:41:54,670 --> 00:42:00,010
+أنا اتطلعت على الهيكل تبعه اللي بتكرر هلاحظ ان هو
+
+454
+00:42:00,010 --> 00:42:05,960
+عبارة عن NCEالان هذه الوحدة بتتكرر في البروتين
+
+455
+00:42:05,960 --> 00:42:12,760
+بعدها N C C double bond O بعدها N C C double bond
+
+456
+00:42:12,760 --> 00:42:19,220
+O هتقولولي مش ناقص غير ايش تكتب هذولة to the N طب
+
+457
+00:42:19,220 --> 00:42:25,870
+ليش مش قادر اكتبهم؟لأن كل amino acid فيها R group
+
+458
+00:42:25,870 --> 00:42:33,210
+مختلفة يعني هذه مرة H هذه مرة CH3 هذه مرة CH2SH
+
+459
+00:42:33,210 --> 00:42:40,430
+فلو بتطلع على الهيكل الأساسي للذرات لبروتين NCC
+
+460
+00:42:40,430 --> 00:42:45,870
+double bond O هو مكرر لكن لو طلعت على هذه المجموعة
+
+461
+00:42:46,670 --> 00:42:51,530
+مش مكررة بناء على ذلك لو هذا مثلا كان بيبتايد هذا
+
+462
+00:42:51,530 --> 00:42:55,810
+بيبتايد مكون من كام amino acid من تلاتة هتعلم أن
+
+463
+00:42:55,810 --> 00:43:00,570
+هذا اسمه إجليسين هذا اسمه ألانين هذا اسمه سيستين
+
+464
+00:43:00,570 --> 00:43:05,450
+حصير أقول هذاEglicin, Alanine, Cysteine هيكون بفرق
+
+465
+00:43:05,450 --> 00:43:08,390
+عن Alanine, Eglicin, Cysteine من نفس التلاتة
+
+466
+00:43:08,390 --> 00:43:14,810
+فانفعلكوا لما نصيح نحكي عن تلاتمية فالبروتين بوجهة
+
+467
+00:43:14,810 --> 00:43:19,870
+النظر اللي بده يتطلع الهيكل الأساسي هو كأنه بوليمر
+
+468
+00:43:19,870 --> 00:43:25,170
+امكرر في N, C, C double bond O N, C, C double bond
+
+469
+00:43:25,170 --> 00:43:28,950
+O لكن لما نيجي نلاحظ أن هذه المجموعة اللي هنا
+
+470
+00:43:28,950 --> 00:43:36,740
+اختلفتبطل polymer ولذلك ال polymer مابنعدش ال 300
+
+471
+00:43:36,740 --> 00:43:40,680
+وحدة ولا ال 5000 وحدة تبعته بس ال protein بدي
+
+472
+00:43:40,680 --> 00:43:45,860
+أجهزة و بدي علم يوم أقول هذا protein كذا يذكر لل
+
+473
+00:43:45,860 --> 00:43:54,170
+5000 وحدة مرتبين و نفس الاشي هيتكرر معاكم مهمفي ال
+
+474
+00:43:54,170 --> 00:43:58,670
+nucleic acids عشان هيك في الشفرة الوراثية وغيرها
+
+475
+00:43:58,670 --> 00:44:02,570
+وغيراتها هتلاحظوا ان البني ادم بيختلف عن التاني و
+
+476
+00:44:02,570 --> 00:44:07,270
+الشغل بتختلف عن التاني انه بدي اذكر الأشياء مرتبة
+
+477
+00:44:08,550 --> 00:44:18,550
+كذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+478
+00:44:18,550 --> 00:44:19,230
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+479
+00:44:19,230 --> 00:44:19,250
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+480
+00:44:19,250 --> 00:44:19,450
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+481
+00:44:19,450 --> 00:44:22,470
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+482
+00:44:22,470 --> 00:44:25,070
+وكذا
+
+483
+00:44:25,690 --> 00:44:30,730
+جزيئات كبيرة اكثر من ان نسميها Polymers و نقدر
+
+484
+00:44:30,730 --> 00:44:35,170
+نكتب شغلته دي انا الان حيصير درسنا القادم سهل اللي
+
+485
+00:44:35,170 --> 00:44:39,730
+بده يدرس ال proteins ايش أساسهم اذا اول شئ بدنا
+
+486
+00:44:39,730 --> 00:44:45,310
+نتعلم على ال amino acids بعدين ال amino acids بتحد
+
+487
+00:44:45,310 --> 00:44:48,890
+و بيعملوا ال protein نتعلم كيف نوجد ال sequence و
+
+488
+00:44:48,890 --> 00:44:53,390
+كيف نحضر ال protein لو بدنايالكن حيكون ان شاء الله
+
+489
+00:44:53,390 --> 00:44:58,410
+درسنا القادم على الوحدة المكونة للبروتين اللي هي
+
+490
+00:44:58,410 --> 00:45:00,370
+عبارة عن ايش؟ الامام 
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..3ac3e3633704cdcd6730373a7adc2e64ee2ff88c
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2007, "start": 18.78, "end": 20.08, "text": "بسم الله الرحمن الرحيم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640], "avg_logprob": -0.03093261569738388, "compression_ratio": 1.0789473684210527, "no_speech_prob": 0.0, "words": [{"start": 18.78, "end": 19.08, "word": "بسم", "probability": 0.92578125}, {"start": 19.08, "end": 19.24, "word": " الله", "probability": 0.97021484375}, {"start": 19.24, "end": 19.62, "word": " الرحمن", "probability": 0.9874674479166666}, {"start": 19.62, "end": 20.08, "word": " الرحيم", "probability": 0.9952799479166666}], "temperature": 1.0}, {"id": 2, "seek": 4939, "start": 21.19, "end": 49.39, "text": "بعد ما اتكلمنا المرة الماضية عن السكريات المنفردة اتعرفنا عليها ال mono-saccharides الان بدنا نتكلم عن ال di-saccharides طبعا اللي بنقصده احنا ب di-saccharides انه جزيئين من ال mono-saccharides يتحدوا مع بعض و بيعملوا ايش؟ di-saccharide الان مش دائما مش دائما", "tokens": [3555, 22488, 19446, 1975, 2655, 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بطلت OH صار الاتحاد من عندها و عشان هيك صارت هذه الرابطة Glycosidic bond فقال غلوكو باي رانوسايد غلوكو باي رانوسايد فالحقيقة", "tokens": [41185, 28242, 13672, 1829, 12174, 36150, 29538, 25961, 2655, 13931, 32771, 1211, 2407, 4117, 2407, 4724, 47302, 12602, 7649, 41779, 8608, 2407, 16606, 25961, 20588, 34051, 33286, 44381, 34105, 4724, 9566, 1211, 2655, 13931, 20328, 9640, 2423, 9307, 5016, 18513, 9154, 43242, 11296, 4032, 6225, 8592, 7649, 39896, 4117, 20328, 9640, 2655, 29538, 34892, 16758, 9566, 3660, 460, 356, 6877, 327, 299, 6086, 6156, 4587, 6027, 32771, 1211, 2407, 4117, 2407, 4724, 47302, 12602, 7649, 41779, 995, 25708, 32771, 1211, 2407, 4117, 2407, 4724, 47302, 12602, 7649, 41779, 995, 25708, 6156, 6027, 5016, 38436, 28671], "avg_logprob": -0.22021484716484943, "compression_ratio": 1.6802030456852792, "no_speech_prob": 0.0, "words": [{"start": 798.74, "end": 798.98, "word": "في", "probability": 0.482421875}, {"start": 798.98, "end": 799.24, "word": " كل", "probability": 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بيجوا بيعملوا بوليمار كبير لما بيعملوا بوليمار كبير بيكون هم الوحدة الأساسية المتكررة في البوليمار بيعطونا", "tokens": [6027, 3794, 26895, 2407, 4724, 1829, 2407, 11622, 13672, 1829, 12174, 1211, 8315, 18871, 3224, 4724, 36081, 995, 4032, 4724, 36081, 995, 37495, 22653, 16490, 1211, 9957, 995, 8717, 31747, 11622, 1975, 5016, 8315, 15844, 9673, 1211, 2655, 2407, 11622, 9673, 1211, 2655, 2407, 11622, 25961, 9154, 5551, 46538, 3660, 4032, 4724, 36081, 995, 10874, 12610, 2407, 4117, 2407, 11622, 3714, 30544, 4032, 46958, 5016, 22807, 4032, 21136, 26895, 2407, 4724, 1829, 2407, 11622, 9154, 4724, 36081, 995, 4032, 4724, 36081, 995, 10874, 12610, 2407, 4117, 2407, 11622, 6024, 48506, 8032, 3215, 12610, 3660, 5296, 15042, 4724, 1829, 7435, 14407, 4724, 1829, 25957, 1211, 14407, 4724, 12610, 32640, 9640, 9122, 3555, 13546, 5296, 15042, 4724, 1829, 25957, 1211, 14407, 4724, 12610, 32640, 9640, 9122, 3555, 13546, 4724, 1829, 30544, 8032, 2304, 2423, 2407, 24401, 3660, 16247, 3794, 32277, 10632, 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1466.79, "end": 1467.01, "word": " من", "probability": 0.99658203125}, {"start": 1467.01, "end": 1467.67, "word": " خلالها", "probability": 0.9959716796875}, {"start": 1467.67, "end": 1468.15, "word": " مع", "probability": 0.97265625}, {"start": 1468.15, "end": 1468.61, "word": " موقع", "probability": 0.9459635416666666}, {"start": 1468.61, "end": 1469.07, "word": " أربعة", "probability": 0.8138020833333334}, {"start": 1469.07, "end": 1469.25, "word": " من", "probability": 0.990234375}, {"start": 1469.25, "end": 1469.65, "word": " وحدة", "probability": 0.9090169270833334}, {"start": 1469.65, "end": 1470.23, "word": " ملتوز", "probability": 0.96171875}, {"start": 1470.23, "end": 1470.67, "word": " تانية", "probability": 0.9334309895833334}, {"start": 1470.67, "end": 1471.37, "word": " بطلع", "probability": 0.7576904296875}, {"start": 1471.37, "end": 1472.03, "word": " عنده", "probability": 0.6016845703125}, {"start": 1472.03, "end": 1472.57, "word": " جزء", "probability": 0.8727213541666666}, {"start": 1472.57, "end": 1473.13, "word": " كبير", "probability": 0.99658203125}, {"start": 1473.13, "end": 1473.89, "word": " بنسميه", "probability": 0.9354248046875}, {"start": 1473.89, "end": 1474.21, "word": " إيش", "probability": 0.8466796875}], "temperature": 1.0}, {"id": 63, "seek": 150480, "start": 1477.02, "end": 1504.8, "text": "الاميلوز الاميلوز هذا احد مكونات النشا الان النشا في مكون تاني الاميلوبكتين الاميلوبكتين في ما بين تلتمية الى خمستلاف جولوكوز units يعني الجولوكوز units اللى في عددها اكبر لكن اهم شغل فيه is هايلبراجد واضح يعني الاميلوز سلسلة", "tokens": [6027, 10943, 26895, 2407, 11622, 2423, 10943, 26895, 2407, 11622, 23758, 1975, 24401, 3714, 30544, 9307, 28239, 8592, 995, 2423, 7649, 28239, 8592, 995, 8978, 3714, 30544, 6055, 7649, 1829, 2423, 10943, 26895, 37746, 4117, 2655, 9957, 2423, 10943, 26895, 37746, 4117, 2655, 9957, 8978, 19446, 49374, 6055, 1211, 2655, 2304, 10632, 2423, 7578, 16490, 2304, 14851, 15040, 5172, 10874, 12610, 2407, 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"end": 1491.32, "word": " خمستلاف", "probability": 0.826123046875}, {"start": 1491.32, "end": 1491.9, "word": " جولوكوز", "probability": 0.8601888020833334}, {"start": 1491.9, "end": 1492.3, "word": " units", "probability": 0.5771484375}, {"start": 1492.3, "end": 1492.84, "word": " يعني", "probability": 0.883544921875}, {"start": 1492.84, "end": 1493.46, "word": " الجولوكوز", "probability": 0.9373372395833334}, {"start": 1493.46, "end": 1493.88, "word": " units", "probability": 0.9228515625}, {"start": 1493.88, "end": 1494.26, "word": " اللى", "probability": 0.861083984375}, {"start": 1494.26, "end": 1494.46, "word": " في", "probability": 0.7919921875}, {"start": 1494.46, "end": 1495.16, "word": " عددها", "probability": 0.88330078125}, {"start": 1495.16, "end": 1495.94, "word": " اكبر", "probability": 0.8914388020833334}, {"start": 1495.94, "end": 1496.6, "word": " لكن", "probability": 0.8525390625}, {"start": 1496.6, "end": 1497.06, "word": " اهم", "probability": 0.957763671875}, {"start": 1497.06, "end": 1497.56, "word": " شغل", "probability": 0.7736002604166666}, {"start": 1497.56, "end": 1498.18, "word": " فيه", "probability": 0.723388671875}, {"start": 1498.18, "end": 1499.86, "word": " is", "probability": 0.55029296875}, {"start": 1499.86, "end": 1500.94, "word": " هايلبراجد", "probability": 0.5816243489583334}, {"start": 1500.94, "end": 1501.68, "word": " واضح", "probability": 0.8636067708333334}, {"start": 1501.68, "end": 1502.46, "word": " يعني", "probability": 0.693115234375}, {"start": 1502.46, "end": 1503.54, "word": " الاميلوز", "probability": 0.97587890625}, {"start": 1503.54, "end": 1504.8, "word": " سلسلة", "probability": 0.9918212890625}], "temperature": 1.0}, {"id": 64, "seek": 153058, "start": 1505.64, "end": 1530.58, "text": "الـ amylobectin في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300 إلى 5000 جولوكوز units is a highly branched molecule او highly branched molecule chains with consecutive one four links شوفنا كيف one four links الارتباط ال average يعني كل مجموعة حوالي خمسة وعشرين لتلاتين وحدة", "tokens": [6027, 39184, 669, 5088, 996, 557, 259, 8978, 6055, 5172, 2288, 3615, 9307, 37495, 22653, 6055, 4587, 16572, 3555, 995, 20193, 5016, 19913, 14407, 2423, 39184, 669, 5088, 541, 49374, 6641, 30731, 23777, 10874, 12610, 2407, 4117, 2407, 11622, 6815, 307, 257, 5405, 9819, 292, 15582, 1975, 2407, 5405, 9819, 292, 15582, 12626, 365, 30497, 472, 1451, 6123, 13412, 38688, 8315, 9122, 33911, 472, 1451, 6123, 2423, 9640, 2655, 3555, 41193, 2423, 4274, 37495, 22653, 28242, 3714, 7435, 2304, 2407, 27884, 11331, 2407, 6027, 1829, 16490, 2304, 3794, 3660, 4032, 3615, 46309, 9957, 5296, 2655, 1211, 9307, 9957, 4032, 24401, 3660], "avg_logprob": -0.2553615052910412, "compression_ratio": 1.5222672064777327, "no_speech_prob": 0.0, "words": [{"start": 1505.64, "end": 1505.94, "word": "الـ", "probability": 0.4827880859375}, {"start": 1505.94, "end": 1506.92, "word": " amylobectin", "probability": 0.76015625}, {"start": 1506.92, "end": 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1527.14, "word": " يعني", "probability": 0.985595703125}, {"start": 1527.14, "end": 1527.38, "word": " كل", "probability": 0.9609375}, {"start": 1527.38, "end": 1528.04, "word": " مجموعة", "probability": 0.94873046875}, {"start": 1528.04, "end": 1528.52, "word": " حوالي", "probability": 0.96630859375}, {"start": 1528.52, "end": 1528.84, "word": " خمسة", "probability": 0.7772216796875}, {"start": 1528.84, "end": 1529.32, "word": " وعشرين", "probability": 0.8521728515625}, {"start": 1529.32, "end": 1530.0, "word": " لتلاتين", "probability": 0.88154296875}, {"start": 1530.0, "end": 1530.58, "word": " وحدة", "probability": 0.8484700520833334}], "temperature": 1.0}, {"id": 65, "seek": 155705, "start": 1532.37, "end": 1557.05, "text": "و بعدين بيجي تفرع 25 ل 30 و تفرع بيصير الجزء أشماله highly branched واضح فواضح أن جزء ال amylobectin أكبر من ال amylose و بنفس الوقت اللي بيميزه التفرعات واضح فال amylose is a chain molecule", "tokens": [2407, 39182, 9957, 4724, 1829, 7435, 1829, 6055, 5172, 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"probability": 0.463134765625}, {"start": 1543.37, "end": 1543.89, "word": " جزء", "probability": 0.9052734375}, {"start": 1543.89, "end": 1544.05, "word": " ال", "probability": 0.8408203125}, {"start": 1544.05, "end": 1545.19, "word": " amylobectin", "probability": 0.74677734375}, {"start": 1545.19, "end": 1546.21, "word": " أكبر", "probability": 0.9571940104166666}, {"start": 1546.21, "end": 1547.23, "word": " من", "probability": 0.98583984375}, {"start": 1547.23, "end": 1547.49, "word": " ال", "probability": 0.927734375}, {"start": 1547.49, "end": 1548.17, "word": " amylose", "probability": 0.8771158854166666}, {"start": 1548.17, "end": 1548.47, "word": " و", "probability": 0.8310546875}, {"start": 1548.47, "end": 1548.85, "word": " بنفس", "probability": 0.7275390625}, {"start": 1548.85, "end": 1549.51, "word": " الوقت", "probability": 0.9814453125}, {"start": 1549.51, "end": 1550.47, "word": " اللي", "probability": 0.885498046875}, {"start": 1550.47, "end": 1551.25, "word": " 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polymers", "probability": 0.939697265625}, {"start": 2060.28, "end": 2060.52, "word": " اللي", "probability": 0.968994140625}, {"start": 2060.52, "end": 2061.1, "word": " بتكونوا", "probability": 0.7464192708333334}, {"start": 2061.1, "end": 2061.52, "word": " منهم", "probability": 0.98095703125}, {"start": 2061.52, "end": 2062.94, "word": " خلينا", "probability": 0.75390625}, {"start": 2062.94, "end": 2063.6, "word": " يعني", "probability": 0.862548828125}, {"start": 2063.6, "end": 2064.14, "word": " نبدأ", "probability": 0.9894205729166666}], "temperature": 1.0}, {"id": 88, "seek": 209371, "start": 2065.65, "end": 2093.71, "text": "نعطي فكرة عامة ليش أنا محتاجها الآن مقارنة مع البروتينات اللي بدنا ناخدها في الفصل الأخير ان شاء الله اللي هو ال amino acids و ال peptides و ال proteins زي ما لاحظته يمكن أهم شغلة في ال polysaccharides أهم شغلة في ال polysaccharides أن هم polymers", "tokens": [1863, 3615, 9566, 1829, 6156, 4117, 25720, 6225, 10943, 3660, 32239, 8592, 41850, 3714, 33753, 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"end": 2342.28, "word": " هذا", "probability": 0.88671875}, {"start": 2342.28, "end": 2342.86, "word": " بيسموه", "probability": 0.9251953125}, {"start": 2342.86, "end": 2343.64, "word": " ايش؟", "probability": 0.72564697265625}, {"start": 2343.64, "end": 2344.2, "word": " sequence", "probability": 0.84814453125}, {"start": 2344.2, "end": 2345.6, "word": " يعني", "probability": 0.7880859375}, {"start": 2345.6, "end": 2345.86, "word": " كيف", "probability": 0.974365234375}, {"start": 2345.86, "end": 2346.18, "word": " هدول", "probability": 0.9368489583333334}, {"start": 2346.18, "end": 2347.02, "word": " مرتبين", "probability": 0.8465576171875}], "temperature": 1.0}, {"id": 100, "seek": 236173, "start": 2348.81, "end": 2361.73, "text": "أعمل التسلسل تبعه، الآن فكرة ال sequence أو التسلسل غير موجودة في ال polysaccharides، ال polysaccharides نفس الشغلة to the N", "tokens": [10721, 25957, 1211, 16712, 3794, 1211, 3794, 1211, 6055, 3555, 3615, 3224, 12399, 6024, 48506, 6156, 4117, 25720, 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2393.14, "end": 2420.34, "text": "لابد من ال sequence هم اكيد هم اكيد عشرين amino acid تقريبا اللي موجودين في ال proteins لكن هدول العشرين لما بدي اخد منهم protein من تلاتمية amino acid كيف هيكونوا؟ هيكونوا مختلفين مافيش ان احك مثلا glycine to the N", "tokens": [1211, 16758, 3215, 9154, 2423, 8310, 8032, 2304, 1975, 4117, 25708, 8032, 2304, 1975, 4117, 25708, 6225, 46309, 9957, 24674, 8258, 6055, 4587, 16572, 3555, 995, 13672, 1829, 3714, 29245, 23328, 9957, 8978, 2423, 15577, 44381, 8032, 3215, 12610, 18863, 46309, 9957, 5296, 15042, 4724, 16254, 1975, 9778, 3215, 9154, 16095, 7944, 9154, 6055, 1211, 9307, 2304, 10632, 24674, 8258, 9122, 33911, 39896, 30544, 14407, 22807, 39896, 30544, 14407, 3714, 46456, 46538, 9957, 19446, 41185, 8592, 16472, 1975, 5016, 4117, 50113, 15040, 22633, 66, 533, 281, 264, 426], "avg_logprob": -0.17652738228272857, "compression_ratio": 1.671641791044776, "no_speech_prob": 0.0, "words": [{"start": 2393.14, "end": 2393.62, "word": "لابد", "probability": 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"انحدد الترتيب تبع ال amino acids ولذلك ال proteins لو الإنسان بده يستعمل الكلام بدقة أكثر they are macro molecules جزيئات كبيرة macro molecules جزيئات كبيرة أكثر منهم إيش polymers they are macro molecules أكثر منهم", "tokens": [7649, 24401, 3215, 16712, 2288, 31371, 3555, 6055, 3555, 3615, 2423, 24674, 21667, 35525, 8848, 23275, 2423, 15577, 45164, 33688, 1863, 3794, 7649, 47525, 3224, 7251, 14851, 25957, 1211, 2423, 28820, 10943, 47525, 28671, 5551, 4117, 49115, 436, 366, 18887, 13093, 10874, 11622, 1829, 19986, 9307, 9122, 3555, 48923, 18887, 13093, 10874, 11622, 1829, 19986, 9307, 9122, 3555, 48923, 5551, 4117, 49115, 9154, 16095, 11933, 1829, 8592, 6754, 18552, 436, 366, 18887, 13093, 5551, 4117, 49115, 9154, 16095], "avg_logprob": -0.1799841821193695, "compression_ratio": 1.718232044198895, "no_speech_prob": 0.0, "words": [{"start": 2471.97, "end": 2472.71, "word": "انحدد", "probability": 0.8234049479166666}, {"start": 2472.71, "end": 2473.43, "word": " الترتيب", "probability": 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شيء مشترك بيخلي بعض الناس يقولوا ممكن تجاوزا نعتبر ال protein بولمار ليش؟ لأنه لو أنا اتطلعت على الهيكل تبعه اللي بتكرر هلاحظ ان هو عبارة عن NCE", "tokens": [3555, 12610, 2304, 9640, 23032, 3555, 3615, 995, 8978, 16095, 8717, 45367, 995, 19446, 44049, 38207, 37893, 2655, 31747, 4724, 1829, 9778, 20292, 45030, 11242, 2423, 8315, 3794, 7251, 39648, 14407, 3714, 43020, 6055, 7435, 995, 2407, 11622, 995, 8717, 34268, 26890, 2423, 7944, 4724, 12610, 2304, 9640, 32239, 8592, 22807, 5296, 33456, 3224, 45164, 41850, 1975, 2655, 9566, 1211, 34268, 15844, 2423, 3224, 1829, 28820, 6055, 3555, 3615, 3224, 13672, 1829, 39894, 37983, 2288, 8032, 15040, 5016, 19913, 16472, 31439, 6225, 3555, 9640, 3660, 18871, 426, 4969], "avg_logprob": -0.1883778116676245, "compression_ratio": 1.5578947368421052, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2499.03, "end": 2499.61, "word": "بولمار", "probability": 0.5931396484375}, {"start": 2499.61, "end": 2500.61, "word": " طبعا", "probability": 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بعدها", "probability": 0.821533203125}, {"start": 2526.6, "end": 2526.9, "word": " N", "probability": 0.32080078125}, {"start": 2526.9, "end": 2527.88, "word": " C", "probability": 0.529296875}, {"start": 2527.88, "end": 2529.04, "word": " C", "probability": 0.76513671875}, {"start": 2529.04, "end": 2529.24, "word": " double", "probability": 0.476806640625}, {"start": 2529.24, "end": 2529.58, "word": " bond", "probability": 0.7939453125}, {"start": 2529.58, "end": 2529.88, "word": " O", "probability": 0.92236328125}, {"start": 2529.88, "end": 2530.46, "word": " بعدها", "probability": 0.8095703125}, {"start": 2530.46, "end": 2530.72, "word": " N", "probability": 0.90234375}, {"start": 2530.72, "end": 2531.3, "word": " C", "probability": 0.97314453125}, {"start": 2531.3, "end": 2532.26, "word": " C", "probability": 0.95458984375}, {"start": 2532.26, "end": 2532.48, "word": " double", "probability": 0.8701171875}, {"start": 2532.48, "end": 2532.76, "word": " bond", "probability": 0.9716796875}, {"start": 2532.76, "end": 2532.98, "word": " O", "probability": 0.97900390625}, {"start": 2532.98, "end": 2533.8, "word": " هتقولولي", "probability": 0.89619140625}, {"start": 2533.8, "end": 2534.06, "word": " مش", "probability": 0.923828125}, {"start": 2534.06, "end": 2534.42, "word": " ناقص", "probability": 0.87060546875}, {"start": 2534.42, "end": 2534.66, "word": " غير", "probability": 0.988037109375}, {"start": 2534.66, "end": 2535.08, "word": " ايش", "probability": 0.7862141927083334}, {"start": 2535.08, "end": 2536.98, "word": " تكتب", "probability": 0.923583984375}, {"start": 2536.98, "end": 2537.46, "word": " هذولة", "probability": 0.67523193359375}, {"start": 2537.46, "end": 2537.6, "word": " to", "probability": 0.70751953125}, {"start": 2537.6, "end": 2537.78, "word": " the", "probability": 0.84912109375}, {"start": 2537.78, "end": 2538.58, "word": " N", "probability": 0.67236328125}, {"start": 2538.58, "end": 2539.22, "word": " طب", "probability": 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طلعت", "probability": 0.7884928385416666}, {"start": 2564.27, "end": 2564.51, "word": " على", "probability": 0.81201171875}, {"start": 2564.51, "end": 2564.99, "word": " هذه", "probability": 0.93896484375}, {"start": 2564.99, "end": 2565.87, "word": " المجموعة", "probability": 0.96201171875}], "temperature": 1.0}, {"id": 109, "seek": 258189, "start": 2566.67, "end": 2581.89, "text": "مش مكررة بناء على ذلك لو هذا مثلا كان بيبتايد هذا بيبتايد مكون من كام amino acid من تلاتة هتعلم أن هذا اسمه إجليسين هذا اسمه ألانين هذا اسمه سيستين حصير أقول هذا", "tokens": [2304, 8592, 3714, 37983, 25720, 44945, 16606, 15844, 29910, 23275, 45164, 23758, 50113, 15040, 25961, 4724, 1829, 3555, 2655, 995, 25708, 23758, 4724, 1829, 3555, 2655, 995, 25708, 3714, 30544, 9154, 9122, 10943, 24674, 8258, 9154, 6055, 1211, 9307, 3660, 8032, 2655, 3615, 19528, 14739, 23758, 24525, 2304, 3224, 11933, 7435, 20292, 3794, 9957, 23758, 24525, 2304, 3224, 5551, 1211, 7649, 9957, 23758, 24525, 2304, 3224, 8608, 1829, 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"word": " انا", "probability": 0.49658203125}, {"start": 2671.91, "end": 2672.73, "word": " الان", "probability": 0.616943359375}, {"start": 2672.73, "end": 2673.27, "word": " حيصير", "probability": 0.80682373046875}, {"start": 2673.27, "end": 2673.77, "word": " درسنا", "probability": 0.9676513671875}, {"start": 2673.77, "end": 2674.23, "word": " القادم", "probability": 0.9812825520833334}, {"start": 2674.23, "end": 2674.67, "word": " سهل", "probability": 0.9962565104166666}, {"start": 2674.67, "end": 2675.17, "word": " اللي", "probability": 0.74609375}, {"start": 2675.17, "end": 2675.39, "word": " بده", "probability": 0.60498046875}, {"start": 2675.39, "end": 2675.79, "word": " يدرس", "probability": 0.99609375}, {"start": 2675.79, "end": 2675.93, "word": " ال", "probability": 0.580078125}, {"start": 2675.93, "end": 2676.51, "word": " proteins", "probability": 0.8564453125}, {"start": 2676.51, "end": 2676.91, "word": " ايش", "probability": 0.8880208333333334}, {"start": 2676.91, "end": 2677.69, "word": " أساسهم", "probability": 0.9315185546875}, {"start": 2677.69, "end": 2678.93, "word": " اذا", "probability": 0.5347900390625}, {"start": 2678.93, "end": 2679.31, "word": " اول", "probability": 0.876708984375}, {"start": 2679.31, "end": 2679.53, "word": " شئ", "probability": 0.6142578125}, {"start": 2679.53, "end": 2679.73, "word": " بدنا", "probability": 0.77099609375}, {"start": 2679.73, "end": 2680.23, "word": " نتعلم", "probability": 0.9918212890625}, {"start": 2680.23, "end": 2680.51, "word": " على", "probability": 0.72900390625}, {"start": 2680.51, "end": 2680.63, "word": " ال", "probability": 0.9697265625}, {"start": 2680.63, "end": 2681.01, "word": " amino", "probability": 0.8544921875}, {"start": 2681.01, "end": 2681.57, "word": " acids", "probability": 0.828125}, {"start": 2681.57, "end": 2683.57, "word": " بعدين", "probability": 0.867919921875}, {"start": 2683.57, "end": 2684.11, "word": " ال", "probability": 0.97119140625}, {"start": 2684.11, "end": 2684.47, "word": " amino", "probability": 0.98779296875}, {"start": 2684.47, "end": 2684.85, "word": " acids", "probability": 0.86669921875}, {"start": 2684.85, "end": 2685.31, "word": " بتحد", "probability": 0.545166015625}, {"start": 2685.31, "end": 2685.41, "word": " و", "probability": 0.41162109375}, {"start": 2685.41, "end": 2685.83, "word": " بيعملوا", "probability": 0.9142578125}, {"start": 2685.83, "end": 2685.93, "word": " ال", "probability": 0.7734375}, {"start": 2685.93, "end": 2686.31, "word": " protein", "probability": 0.8486328125}, {"start": 2686.31, "end": 2686.81, "word": " نتعلم", "probability": 0.9034423828125}, {"start": 2686.81, "end": 2687.09, "word": " كيف", "probability": 0.977783203125}, {"start": 2687.09, "end": 2687.49, "word": " نوجد", "probability": 0.9794921875}, {"start": 2687.49, "end": 2687.67, "word": " ال", "probability": 0.81201171875}, {"start": 2687.67, "end": 2688.31, "word": " sequence", "probability": 0.98193359375}, {"start": 2688.31, "end": 2688.89, "word": " و", "probability": 0.97314453125}, {"start": 2688.89, "end": 2689.21, "word": " كيف", "probability": 0.909423828125}, {"start": 2689.21, "end": 2689.87, "word": " نحضر", "probability": 0.985595703125}, {"start": 2689.87, "end": 2690.01, "word": " ال", "probability": 0.9912109375}, {"start": 2690.01, "end": 2690.51, "word": " protein", "probability": 0.9736328125}, {"start": 2690.51, "end": 2690.75, "word": " لو", "probability": 0.9931640625}, {"start": 2690.75, "end": 2691.35, "word": " بدنايا", "probability": 0.8733723958333334}], "temperature": 1.0}, {"id": 115, "seek": 270037, "start": 2692.19, "end": 2700.37, "text": "لكن حيكون ان شاء الله درسنا القادم على الوحدة المكونة للبروتين اللي هي عبارة عن ايش؟ الامام", "tokens": [1211, 19452, 11331, 1829, 30544, 16472, 13412, 16606, 21984, 11778, 2288, 3794, 8315, 25062, 18513, 2304, 15844, 2423, 2407, 24401, 3660, 9673, 30544, 3660, 24976, 26890, 35473, 9957, 13672, 1829, 39896, 6225, 3555, 9640, 3660, 18871, 1975, 1829, 8592, 22807, 2423, 10943, 10943], "avg_logprob": -0.2484020015055483, "compression_ratio": 1.537037037037037, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2692.19, "end": 2692.65, "word": "لكن", "probability": 0.7919921875}, {"start": 2692.65, "end": 2693.05, "word": " حيكون", "probability": 0.7298177083333334}, {"start": 2693.05, "end": 2693.15, "word": " ان", "probability": 0.5673828125}, {"start": 2693.15, "end": 2693.33, "word": " شاء", "probability": 0.949462890625}, {"start": 2693.33, "end": 2693.39, "word": " الله", "probability": 0.96435546875}, {"start": 2693.39, "end": 2693.91, "word": " درسنا", "probability": 0.9119873046875}, {"start": 2693.91, "end": 2694.57, "word": " القادم", "probability": 0.99462890625}, {"start": 2694.57, "end": 2695.79, "word": " على", "probability": 0.71044921875}, {"start": 2695.79, "end": 2696.67, "word": " الوحدة", "probability": 0.97607421875}, {"start": 2696.67, "end": 2697.35, "word": " المكونة", "probability": 0.8138020833333334}, {"start": 2697.35, "end": 2698.09, "word": " للبروتين", "probability": 0.8984375}, {"start": 2698.09, "end": 2698.23, "word": " اللي", "probability": 0.68505859375}, {"start": 2698.23, "end": 2698.41, "word": " هي", "probability": 0.85009765625}, {"start": 2698.41, "end": 2698.79, "word": " عبارة", "probability": 0.9921875}, {"start": 2698.79, "end": 2699.01, "word": " عن", "probability": 0.9814453125}, {"start": 2699.01, "end": 2700.09, "word": " ايش؟", "probability": 0.6593017578125}, {"start": 2700.09, "end": 2700.37, "word": " الامام", "probability": 0.4725341796875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2700.89875, "duration_after_vad": 2612.6406249999914}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..82a5200cf7ab9e0e4c85df14d592edc3c2b33801
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_raw.srt
@@ -0,0 +1,1960 @@
+1
+00:00:18,780 --> 00:00:24,830
+بسم الله الرحمن الرحيمبعد ما اتكلمنا المرة الماضية
+
+2
+00:00:24,830 --> 00:00:29,410
+عن السكريات المنفردة اتعرفنا عليها ال mono
+
+3
+00:00:29,410 --> 00:00:34,750
+-saccharides الان بدنا نتكلم عن ال di-saccharides
+
+4
+00:00:34,750 --> 00:00:39,930
+طبعا اللي بنقصده احنا ب di-saccharides انه جزيئين
+
+5
+00:00:39,930 --> 00:00:43,910
+من ال mono-saccharides يتحدوا مع بعض و بيعملوا
+
+6
+00:00:43,910 --> 00:00:51,360
+ايش؟ di-saccharide الان مش دائما مش دائمامش دائما
+
+7
+00:00:51,360 --> 00:00:54,820
+هدول الجزيئين اللي بدهم يتحدوا مع بعض بيكونوا زي
+
+8
+00:00:54,820 --> 00:01:00,140
+بعض يعني يوم بدأ احكي انا عن دايسا كرايد ممكن اجيب
+
+9
+00:01:00,140 --> 00:01:06,260
+نفس الجزيئين تماما بكل محتوياتهم طبعا بالتأكيد ال
+
+10
+00:01:06,260 --> 00:01:09,680
+stereo chemistry تكون نفس الشيء تماما و يعملوا
+
+11
+00:01:09,680 --> 00:01:14,040
+دايسا كرايد و ممكن اجيب جزيئين مختلفين و يعملوا
+
+12
+00:01:14,040 --> 00:01:19,820
+دايسا كرايد فمش ضروريمش ضروري ان الـ disaccharide
+
+13
+00:01:19,820 --> 00:01:26,240
+يكون مكوّن من الجزيئين نفسهم تماما، واضح؟ يعني
+
+14
+00:01:26,240 --> 00:01:30,560
+ممكن يكون فعلا من نفس الجزيئين مكوّن disaccharide
+
+15
+00:01:30,560 --> 00:01:36,920
+وممكن يكون من جزيئين مختلفين وهذا اللي هنشوفه لما
+
+16
+00:01:36,920 --> 00:01:45,550
+نستعرض بعض الـ disaccharides بشكل عام ويعني جداأول
+
+17
+00:01:45,550 --> 00:01:51,710
+دايسا كارايد بدنا نستعرضه المالتوز، واضح؟
+
+18
+00:01:51,710 --> 00:01:57,970
+المالتوز، الآن هذا الديسا كارايد مكون من سكرين
+
+19
+00:01:57,970 --> 00:02:03,070
+جولوكوز، لكن فيهم اختلاف في ال stereo chemistry
+
+20
+00:02:03,470 --> 00:02:08,830
+فيهم اختلاف في ال stereo chemistry واحد منهم واحد
+
+21
+00:02:08,830 --> 00:02:14,730
+منهم alpha glucose والتاني منهم beta glucose الآن
+
+22
+00:02:14,730 --> 00:02:19,390
+اللي بتذكروا معنا قولنا احنا ان ال alpha و ال beta
+
+23
+00:02:19,390 --> 00:02:24,930
+sugars بصيروا لما نسكر اخر carbon اللي سمناها ال
+
+24
+00:02:24,930 --> 00:02:29,300
+anomeric carbon و نعملفي حالة السكريات هذه الميزات
+
+25
+00:02:29,300 --> 00:02:35,240
+الكربونات ال fifth chiral center فإذا ال OH كانت
+
+26
+00:02:35,240 --> 00:02:40,020
+للأسفل على هذا الكربون تحديدا بنقول هذا السكر
+
+27
+00:02:40,020 --> 00:02:46,120
+Alpha وإذا كانت للأعلى Beta الآن هذا ال maltose لو
+
+28
+00:02:46,120 --> 00:02:50,760
+بتطلع عليه أنا هيمكون من سكر متصل في ال anomeric
+
+29
+00:02:50,760 --> 00:02:54,560
+carbon لاحظوا أنا تركيزي على أي كربون ال anomeric
+
+30
+00:02:54,560 --> 00:02:59,820
+carbon نكون معلمينها إلى أساساهذه السكرين المتحدين
+
+31
+00:02:59,820 --> 00:03:07,180
+الآن اتطلعوا على واحد منهم ال oxygen فيه alpha
+
+32
+00:03:07,180 --> 00:03:18,840
+واضح التاني منهم ال oxygen فيه betaواضح فالملتوز
+
+33
+00:03:18,840 --> 00:03:24,740
+بيكون في هذه الحالة امكون من Alpha-Glucose مع Beta
+
+34
+00:03:24,740 --> 00:03:29,660
+-Glucose هى دول اتنين قبل ما يتصلوا مع بعض هذا
+
+35
+00:03:29,660 --> 00:03:35,440
+بهذا الشكل كان OH كان Alpha-Glucose هذا كان Beta
+
+36
+00:03:35,440 --> 00:03:41,320
+-Glucose فاتنين اتصلوا مع بعض من خلال موقع اربعة
+
+37
+00:03:41,320 --> 00:03:45,060
+لما ناخد الترقيم واحد اتنين تلاتة اربعة هذا الموقع
+
+38
+00:03:46,020 --> 00:03:49,540
+أربعة اتحدوا من خلال هذه ال Oxygenة اللي في موقع
+
+39
+00:03:49,540 --> 00:03:55,920
+أربعة عملوا رابطة واضح فصار عند المركب مكوّن من
+
+40
+00:03:55,920 --> 00:04:03,040
+Alpha و من Dبيتا جولوكوز وعشان هيك لما بدنا نسميه
+
+41
+00:04:03,040 --> 00:04:09,900
+ممكن انه نقرأ الاسم تبعه هتحسوا انه مش صعب هو ممكن
+
+42
+00:04:09,900 --> 00:04:15,120
+تتخيلوا مركب بيتا جولوكوز لو حطيت ع موقع اربعة مثل
+
+43
+00:04:15,120 --> 00:04:19,960
+شو كنتوا هتسموه four مثل بيتا جولوكوز
+
+44
+00:04:23,450 --> 00:04:29,690
+الاسم الـ Beta في آخر الكلام Beta-D-Glucobiranose
+
+45
+00:04:29,690 --> 00:04:35,170
+مش سمناه لأن جولوكوزم سكرة حلقة سداسية
+
+46
+00:04:35,170 --> 00:04:40,030
+Glucobiranose وD و Beta لأن هذه موجودة في الوضع
+
+47
+00:04:40,030 --> 00:04:45,410
+Beta الآن هذا على موقع أربعة هي على موقع أربعة من
+
+48
+00:04:45,410 --> 00:04:50,950
+خلال ال Oxygen متحد بإيش ب Alpha-D-Glucobiranose
+
+49
+00:04:51,620 --> 00:04:57,800
+واضح الفكرة؟ فيذكر الاسم العام على موقع أربعة من
+
+50
+00:04:57,800 --> 00:05:05,690
+هذا السكر، إيش موجود عنده على موقع أربعة؟الفا دي
+
+51
+00:05:05,690 --> 00:05:08,890
+جلوكو بايرانوس طبعا اتصاله من خلال ال O عشان هيك
+
+52
+00:05:08,890 --> 00:05:13,490
+كتبنا O فاللي بده يفهم الاسم الاسم مش صعب انه هاي
+
+53
+00:05:13,490 --> 00:05:18,290
+المركب اللي عندى بيتا جلوكو بايرانوس على موقع
+
+54
+00:05:18,290 --> 00:05:22,650
+اربعة منه ايش ايجا نعتبرها بين قوسينAlpha
+
+55
+00:05:22,650 --> 00:05:28,230
+Glucobiranose فهذا سكر الملتوز ببساطة هذه الأشياء
+
+56
+00:05:28,230 --> 00:05:34,030
+بيبقى تفهموا فيها الأفكار العامة فالملتوز من سكرين
+
+57
+00:05:34,030 --> 00:05:38,350
+جولوكوز لكن اتنين مش Alpha Alpha ولا Beta Beta
+
+58
+00:05:38,350 --> 00:05:46,590
+Alpha مع Betaالان بيجيني سكر تاني السيلو بيوز
+
+59
+00:05:46,590 --> 00:05:55,730
+السيلو بيوز متحد من سكرين متفقين تماما بيتا جلوكو
+
+60
+00:05:55,730 --> 00:06:00,550
+بيرانوز مع بيتا جلوكو بيرانوز واضح؟ ولذلك لو انا
+
+61
+00:06:00,550 --> 00:06:07,550
+بدأ اطلع على هذا السكر هذا بيتا ولا لا؟ بيتا وعلى
+
+62
+00:06:07,550 --> 00:06:14,780
+هذا السكرهذه أيضًا Beta فلما بنسميه نسبة لهذا Beta
+
+63
+00:06:14,780 --> 00:06:20,740
+D Glucopyranose متحد من موقع أربعةواحد اتنين تلاتة
+
+64
+00:06:20,740 --> 00:06:25,880
+اربعة متحد من موقع اربعة من خلال ال oxygen ال beta
+
+65
+00:06:25,880 --> 00:06:31,160
+D-glucobiranose واضح يعني هذا كأننا بنقول beta D
+
+66
+00:06:31,160 --> 00:06:36,660
+-glucobiranose يحمل على موقع اربعة beta D
+
+67
+00:06:36,660 --> 00:06:42,100
+-glucobiranose واضح الفكرة فال cellobiose بيكون من
+
+68
+00:06:42,100 --> 00:06:50,330
+سكرين متماثلينتماما، لاحظوا قداش نسبة الخلاف اللي
+
+69
+00:06:50,330 --> 00:06:56,450
+بتعمل يعني مركبات مختلفة، يعني انا بحكي عن
+
+70
+00:06:56,450 --> 00:07:02,330
+Glucopyranose و Glucopyranose و بحكي عن هذا Beta
+
+71
+00:07:02,330 --> 00:07:06,870
+في الحالتين، بس التاني مرة Beta و مرة ايش Alpha
+
+72
+00:07:07,710 --> 00:07:14,870
+خلاف بسيط جدا بس كايرال سنتر واحد، الآن بعد شوية
+
+73
+00:07:14,870 --> 00:07:19,770
+هتكتشفوا ان هذا الخلاف البسيط جدا في كايرال سنتر
+
+74
+00:07:19,770 --> 00:07:26,510
+الوحيد بيتبع خلاف كبير جدا جدا جدا في الخواص بعد
+
+75
+00:07:26,510 --> 00:07:31,760
+ذلك للمراكباتيعني لما ييجيوا الجزيئات الـ
+
+76
+00:07:31,760 --> 00:07:35,200
+disaccharides بدهم يعملوا polysaccharides هاي
+
+77
+00:07:35,200 --> 00:07:38,540
+disaccharide و خلّينا نعتبر هاي كمان disaccharide
+
+78
+00:07:38,540 --> 00:07:43,120
+هذا كان من Beta و Beta و هذا كان من Beta و Alpha
+
+79
+00:07:43,120 --> 00:07:47,660
+الان اللي كان من Alpha و Beta الملتوز بيعمل جزئ
+
+80
+00:07:47,660 --> 00:07:56,080
+كبير اسمه نشا او glycogenاللي هي تخزين أو أماكن
+
+81
+00:07:56,080 --> 00:07:59,380
+تخزين ال carbohydrates سواء في النبات أو في
+
+82
+00:07:59,380 --> 00:08:03,400
+الحيوان وهذه بتدوب في الميه وبيقدر البني آدم
+
+83
+00:08:03,400 --> 00:08:07,000
+يهضمها يعني البني آدم لما بياكل النشويات بيقدر
+
+84
+00:08:07,000 --> 00:08:12,180
+بسهولة يحللها للسكريات الأولية بتاعتها أكيد الآن
+
+85
+00:08:12,180 --> 00:08:16,060
+اللي مكوّن من ال beta و ال beta هيجي يعمل ال
+
+86
+00:08:16,060 --> 00:08:20,600
+cellulose هيعمل الخشب البني آدم بيقدرش يهضم الخشب
+
+87
+00:08:20,600 --> 00:08:27,570
+الآن هتيجي تقوله شو الفرق؟بين أساس الخشب و أساس
+
+88
+00:08:27,570 --> 00:08:33,270
+النشا أساس الخشب cellobiose و اتحد و أعطاني
+
+89
+00:08:33,270 --> 00:08:39,110
+cellulose و أساس النشا الملتوز و أعطاني starch
+
+90
+00:08:39,110 --> 00:08:46,230
+واضح فقط مختلفين هدول الاتنين بواحد من السكريات
+
+91
+00:08:46,230 --> 00:08:49,770
+جولوكوز جولوكوز صح جولوكوز جولوكوز بس هذا beta و
+
+92
+00:08:49,770 --> 00:08:55,240
+beta هذا beta و alphaمخيلوا كيف اختلاف بسيط في ال
+
+93
+00:08:55,240 --> 00:09:00,740
+stereochemistry بيقدر الاختلاف كبير بعد هيك في
+
+94
+00:09:00,740 --> 00:09:05,480
+الخواص و في الاستفادة من المركبات بيجينا سكر
+
+95
+00:09:05,480 --> 00:09:15,960
+الحليب ال lactoseاللاكتوز أيضا في جولوكوز لكن في
+
+96
+00:09:15,960 --> 00:09:20,900
+جالاكتوز يعني هدولا ال stereo chemical centers
+
+97
+00:09:20,900 --> 00:09:26,320
+اتغير فيهم اكتر كل الفروقات بينهم هي فروقات ايش
+
+98
+00:09:26,320 --> 00:09:30,500
+لحتى لها ال stereo chemistry يعني هذه الوحدة مش
+
+99
+00:09:30,500 --> 00:09:36,340
+بيتا جولوكوز في هذه الحالة الفا جولوكوز متحد مع
+
+100
+00:09:36,340 --> 00:09:42,300
+بيتا جالاكتوزعشانك لو ذكرنا الاسم العام هتلاحظوا
+
+101
+00:09:42,300 --> 00:09:47,260
+في الآخر Alpha D Glucopyranose هي ال Alpha D
+
+102
+00:09:47,260 --> 00:09:54,480
+Glucopyranose وشايفين أنها Alpha الآن متحد من موقع
+
+103
+00:09:54,480 --> 00:10:01,340
+أربعة ال Beta D Galactopyranose طبعا بنكتب Beta D
+
+104
+00:10:01,340 --> 00:10:07,450
+Galactopyranoseال YL اللي هي بصفته أصبح مجموعة زي
+
+105
+00:10:07,450 --> 00:10:14,330
+ما بقول مثل اثل بروبل ال YL لأنه أصبح مجموعة واضحة
+
+106
+00:10:14,330 --> 00:10:20,630
+الفكرة؟ هذا ال lactose طبعا بيجي صاحبنا، مين
+
+107
+00:10:20,630 --> 00:10:27,330
+صاحبنا؟السكاروز ماحدش اقول عن السكاروز العدو
+
+108
+00:10:27,330 --> 00:10:33,030
+تبعنا، يعني في ناس دائما متطرفين في الحكم على اللي
+
+109
+00:10:33,030 --> 00:10:37,090
+هي هذه الأشياء، كل هذه السكريات و كل حتى الدهون
+
+110
+00:10:37,090 --> 00:10:40,730
+بتلزم للإنسان، بس المشكلة مش أن الإنسان ياخد
+
+111
+00:10:40,730 --> 00:10:45,340
+سكريات و ياخد دهونالمشكلة أنه ياخدها بإفراط يعني
+
+112
+00:10:45,340 --> 00:10:49,160
+الإنسان بحاجة للسكريات، بحاجة للدهون بالتأكيد،
+
+113
+00:10:49,160 --> 00:10:53,940
+بحاجة للكلسترول، بحاجة لكل إشي لكن الإفراط في أي
+
+114
+00:10:53,940 --> 00:10:58,840
+شغل هو اللي بيعمل عندنا إيش المشكلة الآن لو إجينا
+
+115
+00:10:58,840 --> 00:11:02,640
+اتطلعنا على السكروز اللي هو السكر اللي إحنا
+
+116
+00:11:02,640 --> 00:11:07,540
+بنستعمله هتلاحظوا مرة تانية في عندى Alpha
+
+117
+00:11:07,540 --> 00:11:11,680
+-Glucopyranose هاي Alpha هذه شايفينها؟
+
+118
+00:11:14,950 --> 00:11:19,930
+طالما لا أسفل إذا هذه إيش؟ Alpha لكن المرة هذه
+
+119
+00:11:19,930 --> 00:11:27,030
+الاتحاد تبعه مش من موقع أربعة هو متحد ب fractose
+
+120
+00:11:27,030 --> 00:11:33,390
+واضح؟ هو متحد ب fractose و ال fractose keto sugar
+
+121
+00:11:33,390 --> 00:11:38,370
+لما أخدنا السكريات قلنا إن في عندنا ال doses من ال
+
+122
+00:11:38,370 --> 00:11:43,920
+aldehydesو Ketosis لفراكتوز كيتو شوجار و لما بيسكر
+
+123
+00:11:43,920 --> 00:11:50,240
+بيسكر على السكر خماسي السكر الخماسي فيورانوز و من
+
+124
+00:11:50,240 --> 00:11:56,020
+الفيورانوز متحد من موقع ايش؟ واحد واضح؟ الان هذا
+
+125
+00:11:56,020 --> 00:12:04,630
+الفيورانوز لما بتطلع فيهبيتا واضح؟ اذا هذا بيتا
+
+126
+00:12:04,630 --> 00:12:09,270
+عشانك هتلاقوا الاسم تبعه اعتبروا ان هذا هو الأصل
+
+127
+00:12:09,270 --> 00:12:14,010
+وهذه هي الاش المجموعة اللي جاية على الأصل واضح؟
+
+128
+00:12:14,010 --> 00:12:19,950
+فهتلاحظوا بيتا دي فراكتو فيورانوزيل طبعا
+
+129
+00:12:19,950 --> 00:12:26,210
+فيورانوزيل لأنه جاي ايش؟ مجموعة متحدة مع الف دي
+
+130
+00:12:26,210 --> 00:12:33,150
+غلوكوما كتبش هنا by rhinos، كتب by rhinocide، ليش؟
+
+131
+00:12:33,150 --> 00:12:37,790
+لأن الاتحاد تم هنا من موقع واحد، لاحظوا في
+
+132
+00:12:37,790 --> 00:12:41,270
+السكريات اللي قبل شوية، لما كنا نيجع هذا السكر،
+
+133
+00:12:41,270 --> 00:12:45,150
+الاتحاد تم من أي موقع؟ أربعة، هنا الاتحاد تم من
+
+134
+00:12:45,150 --> 00:12:53,080
+موقع واحد، فإذا هذه الرابطة بطلت OH صارت O-Carbon
+
+135
+00:12:53,080 --> 00:12:58,340
+معنا ذلك هذه الرابطة ايش بدها تكون؟ Glycosidic
+
+136
+00:12:58,340 --> 00:13:02,280
+bond واضح؟ عشان Glycosidic bond عشان تكون
+
+137
+00:13:02,280 --> 00:13:08,400
+Glycoside هنحط ايش؟ Glucoburanoside لاحظته هنا
+
+138
+00:13:08,400 --> 00:13:12,640
+كلمة؟ Buranoside لو رجعتوا على الأسماء اللي قبل
+
+139
+00:13:12,640 --> 00:13:19,240
+كان حط Glucoburanose لأن هذه كانت تكون OHفي كل
+
+140
+00:13:19,240 --> 00:13:23,280
+اللي قبل هذه كانت OH غلوكو باي رانوس سواء كان
+
+141
+00:13:23,280 --> 00:13:28,860
+Alpha أو Beta لكن هنا بطلت OH صار الاتحاد من عندها
+
+142
+00:13:28,860 --> 00:13:33,420
+و عشان هيك صارت هذه الرابطة Glycosidic bond فقال
+
+143
+00:13:33,420 --> 00:13:38,300
+غلوكو باي رانوسايد غلوكو باي رانوسايد فالحقيقة
+
+144
+00:13:40,010 --> 00:13:46,150
+السكر اللى فيه two glycosidic bonds هو سكر ايش
+
+145
+00:13:46,150 --> 00:13:50,210
+السكروز انتبهوا لو كانوا بيسألكوا multiple choice
+
+146
+00:13:50,210 --> 00:13:58,670
+الان هذه الرابطة carbon و carbon هذى glycosidic
+
+147
+00:13:58,670 --> 00:14:04,230
+bond ولا لأ و هذا الرابطة glycosidic bond فلما
+
+148
+00:14:04,230 --> 00:14:10,320
+نيجي نطلع احنا حقيقة على السكروزكم جليكوسايدك بوند
+
+149
+00:14:10,320 --> 00:14:18,940
+فيه؟ تنتين لو رجعنا اتطلعنا على السكريات
+
+150
+00:14:18,940 --> 00:14:25,100
+اللي قبل هنا كم جليكوسايدك بوند؟ واحدة ماحدش يقول
+
+151
+00:14:25,100 --> 00:14:29,520
+هذه جليكوسايدك بوند ليش؟ لأن الجليكوسايدك بوند
+
+152
+00:14:29,520 --> 00:14:34,700
+اللي بتتكون على الكايرال سنتر الأخير على هذه مش
+
+153
+00:14:34,700 --> 00:14:40,650
+على هذا الموقع أربعةواضح؟ يعني مش اي او كربون
+
+154
+00:14:40,650 --> 00:14:47,850
+glycosidic bond ال glycosidic bond مرتبطة بأي بأي
+
+155
+00:14:47,850 --> 00:14:52,630
+كربون بال anomeric carbon اللي كانت أساسا الديهايد
+
+156
+00:14:52,630 --> 00:14:56,350
+واضح؟ ولذلك هذه glycosidic bond بس هذه مش
+
+157
+00:14:56,350 --> 00:15:01,390
+glycosidic bond واضح؟ فلو أنا اجيت على ال lactose
+
+158
+00:15:01,390 --> 00:15:08,540
+في one glycosidic bond لو رجعتعلى السيلو بيوز على
+
+159
+00:15:08,540 --> 00:15:13,640
+سبيل المثال برضه أي واحدة anomeric carbon كل سكر
+
+160
+00:15:13,640 --> 00:15:17,780
+فيه two anomeric carbon مظبوط ولا لأ هذه فيها
+
+161
+00:15:17,780 --> 00:15:24,200
+glycosidic bond هذه فيها لذلك في السيلو بيوز في
+
+162
+00:15:24,200 --> 00:15:30,950
+عنده one glycosidic bond هذه لأواضحة الفكرة؟ يعني
+
+163
+00:15:30,950 --> 00:15:34,970
+انا عندي two anomeric carbons مين فيهم glycosidic
+
+164
+00:15:34,970 --> 00:15:40,630
+bond؟ هذي ال O H glycosidic، هذي، اه واضحة الفكرة؟
+
+165
+00:15:40,630 --> 00:15:44,950
+فدائما لما بدنا نعرف كام glycosidic bond، نرجع على
+
+166
+00:15:44,950 --> 00:15:53,670
+الملتوز مثلا، هذي ال anomeric carbons الآن لو
+
+167
+00:15:53,670 --> 00:15:57,690
+إجينا سألنا هذي glycosidic bond؟ O H، هذي
+
+168
+00:15:59,540 --> 00:16:07,100
+Glycosidic bond فالملتوز والسيلوبيوز واللاكتوز
+
+169
+00:16:07,100 --> 00:16:11,380
+هدولة فيهم و one glycosidic bond و التانية عادية
+
+170
+00:16:11,380 --> 00:16:16,740
+عشان ايه كنتوا تلاقوا؟ Glucopyranose عادي لكن لما
+
+171
+00:16:16,740 --> 00:16:23,340
+وصلنا للسكروز لو اجينا سألنا وين ال anomeric
+
+172
+00:16:23,340 --> 00:16:24,180
+carbons؟
+
+173
+00:16:26,580 --> 00:16:31,440
+هي الانوميرك كاربونز الان هنا في جليكوسايدك بوند
+
+174
+00:16:31,440 --> 00:16:36,640
+فيه هنا في جليكوسايدك بوند فيه تنتين جليكوسايدك
+
+175
+00:16:36,640 --> 00:16:42,920
+بوند واضح؟ وعشان هيك هذا لما أنهينا اسمه أنهينا ب
+
+176
+00:16:42,920 --> 00:16:49,480
+side اللي هو alpha D-glucopyranoside زي ما اتعلمنا
+
+177
+00:16:49,480 --> 00:16:53,160
+لما أخدنا الجليكوسايدك بوند وقلنا بننهي بإيش؟
+
+178
+00:16:53,160 --> 00:16:54,360
+جليكوسايد
+
+179
+00:16:57,360 --> 00:17:03,560
+هذا بالنسبة لبعض السكريات اللي هي بنستفيد منها ل
+
+180
+00:17:03,560 --> 00:17:08,700
+ال die saccharides الكلام يمكن يجيب بعضه أن القاسم
+
+181
+00:17:08,700 --> 00:17:16,810
+المشترك ربما في الأشياء المحلية طعم الحلوواضح؟
+
+182
+00:17:16,810 --> 00:17:20,550
+يعني الإنسان بيفتش في النهاية عن إيش؟ الطعم كذلك
+
+183
+00:17:20,550 --> 00:17:24,450
+الحال يمكن تلاحظوه في العطور يعني مار علينا و إحنا
+
+184
+00:17:24,450 --> 00:17:31,410
+بنشرح بعض العطور العطور لا يوجد خليني أقول مجموعة
+
+185
+00:17:31,410 --> 00:17:35,810
+كيميائية تكون قاسم مشترك ما بين العطور ما القاسم
+
+186
+00:17:35,810 --> 00:17:41,920
+المشترك؟الرائحة الذكية، الرائحة الجيدة الآن العطر
+
+187
+00:17:41,920 --> 00:17:46,360
+ممكن مرة يكون Easter ممكن مرة يكون الديهيد ممكن
+
+188
+00:17:46,360 --> 00:17:50,440
+مرة يكون كيتون شوفنا الياسمون مثلا شوفنا ..
+
+189
+00:17:50,440 --> 00:17:53,940
+متذكرين الياسمين كان كيتون شوفنا ال Easter's قولنا
+
+190
+00:17:53,940 --> 00:17:58,040
+عنها مواد عطرية مافيش قاسم كيميائي مشترك القاسم
+
+191
+00:17:58,040 --> 00:18:03,310
+الكيميائي ما بين العطورهو الرائحة الجيدة الآن
+
+192
+00:18:03,310 --> 00:18:07,290
+القاسم الكيميائي ما بين ال sweeteners المحليات و
+
+193
+00:18:07,290 --> 00:18:12,970
+منها السكر هو الطعم الاش؟ الحلو ولذلك الآن في
+
+194
+00:18:12,970 --> 00:18:17,490
+سكريات اللي هي السكريات هذه الصناعية اللي بياخدوها
+
+195
+00:18:17,490 --> 00:18:21,430
+الناس اللي عندهم سكر و ما إلى ذلك لو اطلعت على
+
+196
+00:18:21,430 --> 00:18:25,590
+أنواعها المختلفة مش هتلاقيوا شيء مشترك في الشكل
+
+197
+00:18:25,590 --> 00:18:32,500
+بينها لكن هالمراكبات لما حضروهالاحظوا انه طعمها
+
+198
+00:18:32,500 --> 00:18:37,440
+حلو وبشكل عام آمن يعني كتير في مركبات طعمها حلو
+
+199
+00:18:37,440 --> 00:18:40,980
+لكن خطيرة جدا بيقدرش الإنسان يتعامل معايا
+
+200
+00:18:40,980 --> 00:18:45,440
+الكلوروفورم طعمه حلو لكن سامه carcinogenic لكن هذا
+
+201
+00:18:45,440 --> 00:18:50,040
+المركب مثلا بدون ما ناخد طرق تحضيره هو السكارين
+
+202
+00:18:50,040 --> 00:18:54,720
+سواء وجد ع شكل السكارين أو عشان يدوب بيسحبوا القدش
+
+203
+00:18:54,720 --> 00:18:58,580
+بيعملوا ال salt تبعه طبعا دائما لما نقول salt ال
+
+204
+00:18:58,580 --> 00:19:03,300
+salt ليش بنعمله احناعشان الذائبية تكون أعلى في
+
+205
+00:19:03,300 --> 00:19:08,740
+الميه فلو اطلعنا احنا هذا ال sodium سكارين اللي هو
+
+206
+00:19:08,740 --> 00:19:12,740
+اللي بنستعمله و بنحطه على الشاي مافيش علاقة بين
+
+207
+00:19:12,740 --> 00:19:20,080
+شكله وبين شكل السكاروز لكن يوضع بديل للسكاروز،
+
+208
+00:19:20,080 --> 00:19:25,780
+مظبوط ولا لأ؟ ليش يوضع بديل للسكاروز؟ بسبب الطعم
+
+209
+00:19:25,780 --> 00:19:30,730
+الحلو، الآن في سكريات تانية غير السكاروزالسكارين
+
+210
+00:19:30,730 --> 00:19:36,150
+تستعمل منها مثلا ال Aspartame و ال Cyclamates لو
+
+211
+00:19:36,150 --> 00:19:42,110
+فتشته Cyclamates لو فتشته على شكل ال Aspartame و
+
+212
+00:19:42,110 --> 00:19:46,030
+ال Cyclamate و السكارين هتلاقي كل واحد يمثل شكل
+
+213
+00:19:46,030 --> 00:19:52,410
+معين مافيش قاسم مشترك بينهم القاسم المشترك هو إيش؟
+
+214
+00:19:52,410 --> 00:19:57,510
+الطعم الحلو القاسم المشترك هو الطعم الحلو يعني هاي
+
+215
+00:19:57,510 --> 00:20:02,700
+ال Aspartameطلعوا هذا شكل و هذا شكل بتلاحظوا فيه
+
+216
+00:20:02,700 --> 00:20:07,740
+شيء مشترك مع السكرين طب العسل بس زي محلق و بطعم
+
+217
+00:20:07,740 --> 00:20:12,060
+حلو؟ ايه هو؟ العسل؟ ما هو العسل فيه سكريات كتيرة
+
+218
+00:20:12,060 --> 00:20:17,120
+لأ لأ مش من هدولة من السكريات العادية اللي أخدناها
+
+219
+00:20:17,120 --> 00:20:23,000
+بس تركيبته عاد كبيرة في سكريات و فيتامينات و إشي
+
+220
+00:20:23,000 --> 00:20:31,540
+أكثر من شغلها الآنهذه الـ Disaccharides سواء كانت
+
+221
+00:20:31,540 --> 00:20:37,740
+سكريات مختلفة زي الملتوز اللي احنا قلنا عنه Alpha
+
+222
+00:20:37,740 --> 00:20:43,810
+و Beta الجلوكوز متحدين مع بعض أوالسيلو بيوز اللي
+
+223
+00:20:43,810 --> 00:20:47,710
+قلنا عنه بيتا و بيتا يعني خلينا نركز احنا على
+
+224
+00:20:47,710 --> 00:20:52,810
+الملتوز الملتوز كان من ألفة و بيتا جولوكوز مكون
+
+225
+00:20:52,810 --> 00:20:57,790
+واضح؟ و السيلو بيوز من بيتا و بيتا جولوكوز الآن
+
+226
+00:20:57,790 --> 00:21:02,470
+هدولة لما بيجوا بيعملوا بوليمار كبير لما بيعملوا
+
+227
+00:21:02,470 --> 00:21:06,750
+بوليمار كبير بيكون هم الوحدة الأساسية المتكررة في
+
+228
+00:21:06,750 --> 00:21:12,930
+البوليمار بيعطوناالـ starch أو النشا في حالة ما
+
+229
+00:21:12,930 --> 00:21:18,570
+نتكلم عن إيش؟ عن الملتوز، في حالة ما نتكلم عن
+
+230
+00:21:18,570 --> 00:21:22,990
+السيلوبايوز، بيعطينا السيليلوز، واضح؟ فالملتوز
+
+231
+00:21:22,990 --> 00:21:29,130
+بيعطيني إيش؟ النشا، starch، السيلوبايوز بيعطيني
+
+232
+00:21:29,130 --> 00:21:36,470
+السيليلوز، الخشب، واضح؟ بولمار كبير طبعاًلاحظوا
+
+233
+00:21:36,470 --> 00:21:40,990
+عاد حسب ال polymer اللي بتكون يعني يوم ما نحكي عن
+
+234
+00:21:40,990 --> 00:21:45,550
+polymer يعني عدد كبير من الشغلات هتلاحظوا في علم
+
+235
+00:21:45,550 --> 00:21:50,250
+ال polymerization هذا العدد ممكن يكون 300 وحدة
+
+236
+00:21:50,250 --> 00:21:56,200
+ممكن يكون الف ممكن يكون تلت تلافتمام؟ حسب طريقة
+
+237
+00:21:56,200 --> 00:21:59,420
+الارتباط اللى موجودة في هذا العدد وحسب عدد
+
+238
+00:21:59,420 --> 00:22:03,760
+الجزيئات او الوحدات المكونة له الآن وحدة ال stars
+
+239
+00:22:03,760 --> 00:22:08,300
+هي ايش؟ ال maltose هذه الوحدة اللى مكونة من سكرين
+
+240
+00:22:08,300 --> 00:22:13,160
+حسب كمية الأشياء المتصلة بيصير عند نوع ال polymer
+
+241
+00:22:13,160 --> 00:22:16,340
+عشانك انتوا بال plastic بتلاحظوا في عندكوا أنواع
+
+242
+00:22:16,340 --> 00:22:21,460
+كتيرةفي النيلون في عندكم أنواع كتيرة هذا بيصير
+
+243
+00:22:21,460 --> 00:22:25,860
+يدخل فيه جانب الصناعة انه قداش العدد اللي خلناه
+
+244
+00:22:25,860 --> 00:22:31,640
+يتحد تقريبا يعمل polymer هالخليه 300 جزء و وحدة ال
+
+245
+00:22:31,640 --> 00:22:37,640
+polymer 3000 2000 واضح الفكرة؟ الآن نفس الفكرة من
+
+246
+00:22:37,640 --> 00:22:43,350
+الملتوز هلاحظ ان في انهاالـ starch لو حللته
+
+247
+00:22:43,350 --> 00:22:47,990
+بيعطيني ملتوز، الملتوز لو حللته بيعطيني جولوكوز،
+
+248
+00:22:47,990 --> 00:22:52,830
+لكن جولوكوز Alpha
+
+249
+00:22:53,990 --> 00:22:58,410
+وبيتاجولوكوز لكن هذه الوحدة المتكررة وحدة الملتوز
+
+250
+00:22:58,410 --> 00:23:03,350
+اعملوا منها عدد كبير الان لاحظوا ان النشا مكون من
+
+251
+00:23:03,350 --> 00:23:08,230
+شغلتين من اميلوز بنسبة 20% والباقي تقريبا
+
+252
+00:23:08,230 --> 00:23:15,200
+اميلوبكتل ايش بيفرقوا هدولة الشغلتين؟بعدد الجزيئات
+
+253
+00:23:15,200 --> 00:23:19,980
+المكونة له بطريقة الاتحاد يعني ال amylose في
+
+254
+00:23:19,980 --> 00:23:25,840
+جولوكوز units عادة بيكون عددها ما يقارب بين خمسين
+
+255
+00:23:25,840 --> 00:23:30,260
+لتلتمية جولوكوز unit لكن أهم شيء بيميزها أن هي
+
+256
+00:23:30,260 --> 00:23:37,970
+موجودة في إيش؟بسلاسل بدون تفرعات، واضح؟ سلاسل بهذا
+
+257
+00:23:37,970 --> 00:23:42,830
+الشكل بدون ما يصير فيها تفرعات، العدد تبع ال
+
+258
+00:23:42,830 --> 00:23:47,410
+geolocose units بيكون ما بين خمسين إلى تلتمية
+
+259
+00:23:47,410 --> 00:23:52,770
+geolocose unit والاتحاد زي ما انتوا عارفين نمر
+
+260
+00:23:52,770 --> 00:23:58,270
+أربعة من هان وبتحد من واحد مع الجزء التانييعني
+
+261
+00:23:58,270 --> 00:24:02,190
+احنا لما كنا نتكلم عن ال مالتوز، كنا هنا في عنا
+
+262
+00:24:02,190 --> 00:24:07,550
+الاتحاد مع أربعة أو سابين واحد، أوقتش، الآن لما
+
+263
+00:24:07,550 --> 00:24:11,150
+بتعمل polymer، بيجيب التحد منها، يعني لو انتوا
+
+264
+00:24:11,150 --> 00:24:16,630
+تذكرتوا المالتوز، مش كانت هذه تكون فيهقواتش لما
+
+265
+00:24:16,630 --> 00:24:20,930
+نحكي عن الملتوز لوحده الآن بيصير يتحد من هذه
+
+266
+00:24:20,930 --> 00:24:23,690
+القواتش عشان يعمل ال polymer يعني القواتش اللي
+
+267
+00:24:23,690 --> 00:24:28,610
+كانت ماتروكة فاضية بيصير يتحد من خلالها مع موقع
+
+268
+00:24:28,610 --> 00:24:33,130
+أربعة من وحدة ملتوز تانية بطلع عنده جزء كبير
+
+269
+00:24:33,130 --> 00:24:34,210
+بنسميه إيش
+
+270
+00:24:37,020 --> 00:24:43,020
+الاميلوز الاميلوز هذا احد مكونات النشا الان النشا
+
+271
+00:24:43,020 --> 00:24:49,260
+في مكون تاني الاميلوبكتين الاميلوبكتين في ما بين
+
+272
+00:24:49,260 --> 00:24:53,460
+تلتمية الى خمستلاف جولوكوز units يعني الجولوكوز
+
+273
+00:24:53,460 --> 00:24:59,860
+units اللى في عددها اكبر لكن اهم شغل فيه is
+
+274
+00:24:59,860 --> 00:25:06,920
+هايلبراجد واضح يعني الاميلوز سلسلةالـ amylobectin
+
+275
+00:25:06,920 --> 00:25:13,440
+في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300
+
+276
+00:25:13,440 --> 00:25:17,220
+إلى 5000 جولوكوز units is a highly branched
+
+277
+00:25:17,220 --> 00:25:21,660
+molecule او highly branched molecule chains with
+
+278
+00:25:21,660 --> 00:25:24,360
+consecutive one four links شوفنا كيف one four
+
+279
+00:25:24,360 --> 00:25:28,520
+links الارتباط ال average يعني كل مجموعة حوالي
+
+280
+00:25:28,520 --> 00:25:35,070
+خمسة وعشرين لتلاتين وحدةو بعدين بيجي تفرع 25 ل 30
+
+281
+00:25:35,070 --> 00:25:41,110
+و تفرع بيصير الجزء أشماله highly branched واضح
+
+282
+00:25:41,110 --> 00:25:48,470
+فواضح أن جزء ال amylobectin أكبر من ال amylose و
+
+283
+00:25:48,470 --> 00:25:55,150
+بنفس الوقت اللي بيميزه التفرعات واضح فال amylose
+
+284
+00:25:55,150 --> 00:26:02,220
+is a chain moleculeالـ amylobectin هو جزئ عالي جزئ
+
+285
+00:26:02,220 --> 00:26:11,520
+فيه تفرعات كتيرة طبعا هذه كل أشكال تقريبية بتوضح
+
+286
+00:26:11,520 --> 00:26:20,720
+لنا كيف بيتكونوا هذول الجزيئات الأن لو جينا من ال
+
+287
+00:26:20,720 --> 00:26:30,470
+amylose أيضاغير النشق بمكوينه يعني من الملتوز كان
+
+288
+00:26:30,470 --> 00:26:35,130
+في عنده ال starch اللي هو مكوّن من amylose و
+
+289
+00:26:35,130 --> 00:26:40,470
+mylobectin أيضًا من الملتوز في عنده الجليكوجين ال
+
+290
+00:26:40,470 --> 00:26:45,470
+starch ما كان تخزين ال carbohydratesفي النبات
+
+291
+00:26:45,470 --> 00:26:49,410
+الجليكوجين مكان تخزين ال carbohydrates في
+
+292
+00:26:49,410 --> 00:26:55,750
+الحيوانات برضه هو فيه جولوكوز units لكن حوالي مائة
+
+293
+00:26:55,750 --> 00:27:00,590
+ألف جولوكوز unit لاحظوا العدد في الجليكوجين
+
+294
+00:27:00,590 --> 00:27:06,810
+جليكوجين بيزيد بشكل كبير وبرنشد يعني كل ما بين كل
+
+295
+00:27:06,810 --> 00:27:11,010
+تمانية ل 12 جولوكوز unit خلينا هيك نتخيل هتلاحظوا
+
+296
+00:27:11,010 --> 00:27:17,930
+ان في عندكم إيشالجزء هذا الجليكوجين بيكون أيضا
+
+297
+00:27:17,930 --> 00:27:24,090
+highly branched الآن الجليكوجين بيجي من الجلوكوز
+
+298
+00:27:24,090 --> 00:27:30,130
+اللي بيمتص من أمعاء produced from glucose that is
+
+299
+00:27:30,130 --> 00:27:35,930
+absorbed from intestines into the blood الآن إيش
+
+300
+00:27:35,930 --> 00:27:41,060
+وظيفته هذا الجليكوجين؟ يمكن مار عليكمبيولوجيا اللي
+
+301
+00:27:41,060 --> 00:27:45,260
+هو توازن السكر helps maintain the glucose balance
+
+302
+00:27:45,260 --> 00:27:49,660
+واضح يعني إذا في عندي جولوكوز ازيادة بيجي و بتخزن
+
+303
+00:27:49,660 --> 00:27:54,340
+وين في الجليكوجين بدخل ضمن البوليمار الآن إذا
+
+304
+00:27:54,340 --> 00:28:00,770
+الجسم نقص عليه الجولوكوزبصير هذا نفسه يفرز أو يعطي
+
+305
+00:28:00,770 --> 00:28:07,930
+الجسم وحدات جولوكوز واضح الفكرة؟ يعني هو كأنه هاي
+
+306
+00:28:07,930 --> 00:28:12,450
+جزيئات الجولوكوز بتقدروا تتخيلوها بتمطس من المعدة
+
+307
+00:28:12,450 --> 00:28:16,030
+المفروض لازم لحرق الأكل الناس اللي بياكلوا كتير
+
+308
+00:28:16,030 --> 00:28:21,510
+okay بنجمع هذه الجزيئات هيعملنا إيش؟جلايكوجين
+
+309
+00:28:21,510 --> 00:28:25,790
+وخزانة الان بعد هيك صار البني ادم عنده ناقص في
+
+310
+00:28:25,790 --> 00:28:31,010
+السكر جد ما فيه ناقص بيصير يطلع له جولوكوز واضح؟
+
+311
+00:28:31,010 --> 00:28:36,090
+واضحة الفكرة العامة خليني اقول العامة جدا
+
+312
+00:28:36,090 --> 00:28:42,890
+لجلايكوجين الان لو طلعنا على ال cellulose ال
+
+313
+00:28:42,890 --> 00:28:48,830
+cellulose هو ال polymerاللي جاي من الـ cellobiose
+
+314
+00:28:48,830 --> 00:28:55,010
+اللي بيعمل الخشب يعني النشا والجليكوجين جايين من
+
+315
+00:28:55,010 --> 00:29:01,430
+وين؟ من الملتوز من الملتوز لكن ال cellulose جاي من
+
+316
+00:29:01,430 --> 00:29:03,410
+ال cellobiose
+
+317
+00:29:05,410 --> 00:29:11,210
+بيتا وبيتا sugar فالcellulose is an unbranched
+
+318
+00:29:11,210 --> 00:29:16,210
+polymer مستقيم مافيش فيه branches of glucose
+
+319
+00:29:16,210 --> 00:29:20,110
+joined by one four beta glycosidic bonds كل
+
+320
+00:29:20,110 --> 00:29:29,390
+هالكلام شفناه لاحظوا معي كيف فرق في الأساس بسيط
+
+321
+00:29:29,390 --> 00:29:37,500
+جدا انه هذا منسيلو بيوز هذا من مالتوز السيلو بيوز
+
+322
+00:29:37,500 --> 00:29:42,260
+و المالتوز متحدين في beta غلوكوز لكن السكر التاني
+
+323
+00:29:42,260 --> 00:29:46,820
+في كل واحدة واحد منهم واحد alpha واحد beta يعني
+
+324
+00:29:46,820 --> 00:29:51,120
+خلينا نقول هنا في عند بيتا و بيتا نفس الاشي في
+
+325
+00:29:51,120 --> 00:29:57,340
+السكرين الآن في المالتوز هذا alpha في السيلو بيوز
+
+326
+00:29:58,430 --> 00:30:03,590
+هذا beta فهذا alpha beta هذا beta beta الآن هذا
+
+327
+00:30:03,590 --> 00:30:07,690
+بيصير ملتوز و بيعملني نشا و glycogen هذا بيصير
+
+328
+00:30:07,690 --> 00:30:12,970
+cellulose و cellobiose و بيعمله ال cellulose الان
+
+329
+00:30:12,970 --> 00:30:16,990
+البني آدم بيقدر يهضم النشا بيقدر يهضم ال glycogen
+
+330
+00:30:16,990 --> 00:30:22,670
+بيقدرش يهضم ال cellulose ال cellulose واضح فال
+
+331
+00:30:22,670 --> 00:30:26,830
+humans and other animals they digest starch and
+
+332
+00:30:26,830 --> 00:30:32,880
+glycogenبيقدروا يهضموا النشق والجليكوجين، الآن
+
+333
+00:30:32,880 --> 00:30:37,360
+الحيوانات
+
+334
+00:30:37,360 --> 00:30:42,610
+والنمليمكن تقولوا النمل صار أقوى من البني آدم يعني
+
+335
+00:30:42,610 --> 00:30:46,550
+هو النمل بيقدر يخضم الخشب و البني آدم مابيقدرش
+
+336
+00:30:46,550 --> 00:30:52,030
+معنا ذلك النمل أقوى من البني آدم هي المشكلة انه
+
+337
+00:30:52,030 --> 00:30:57,150
+كمان مش النمل اللي بيخضم او مش الحيوانات المجترة
+
+338
+00:30:57,150 --> 00:31:01,570
+اللي بتخضم لأ بكتيريا موجودة جوا أمعاها هذه
+
+339
+00:31:01,570 --> 00:31:05,050
+البكتيريا اللي جوا أمعاها بتفرز اللي هو
+
+340
+00:31:08,560 --> 00:31:14,060
+الانزيمات اللى هى ال beta glycosidase اللى بتساعد
+
+341
+00:31:14,060 --> 00:31:19,960
+على عملية ايش ان تقدر تهضم الخشب وتستفيد منه واضح
+
+342
+00:31:19,960 --> 00:31:27,760
+فماني بكتيريا contain beta glycosidase دايما اذا
+
+343
+00:31:27,760 --> 00:31:33,510
+شفتوا هذه النهاية ايش هذاالنزيم Oxidase و
+
+344
+00:31:33,510 --> 00:31:37,870
+Redactase و glycosidase and they can hydrolyze
+
+345
+00:31:37,870 --> 00:31:42,810
+يعني يفككوا ال cellulose فلو احنا قلنالكم ان ال
+
+346
+00:31:42,810 --> 00:31:46,090
+humans can hydrolyze cellulose
+
+347
+00:31:48,210 --> 00:31:52,250
+واضح؟ لكن في بكتيريا كتير بتقدر تعمل هذا الكلام
+
+348
+00:31:52,250 --> 00:31:55,990
+هذه موجودة في ال termites اللي هو النمل الأبيض و
+
+349
+00:31:55,990 --> 00:31:59,510
+ال ruminants اللي هي الحيوانات المجترة اللي
+
+350
+00:31:59,510 --> 00:32:03,050
+بتلاقوها مستعدة تاكل ال .. إيش؟ زي الجمل و زي ..
+
+351
+00:32:03,050 --> 00:32:08,250
+أه اللي بتاكل الخشب فبكتيريا في معدتها بتقدر تدخل
+
+352
+00:32:08,250 --> 00:32:13,450
+على هذا الخشب و تحلله لوحدات السكر بحيث أنه النمل
+
+353
+00:32:13,450 --> 00:32:18,430
+الأبيض أو الحيوانات هذه المجترة تقدر تستفيد منهأو
+
+354
+00:32:18,430 --> 00:32:22,310
+من السكر اللي موجود فيه لكن البني آدم مابيقدرش
+
+355
+00:32:22,310 --> 00:32:26,730
+يخدمه أخر
+
+356
+00:32:26,730 --> 00:32:33,090
+شغلة أخر شغلة بنحكيها بالنسبة لهذا الجزء أنه في
+
+357
+00:32:33,090 --> 00:32:37,870
+عندى بعض ال sugars يمكن أن ينزع منها أكسجين هذه
+
+358
+00:32:37,870 --> 00:32:42,850
+بتفيدنا لما بدنا ندرس ال nuclear acid اللي هي
+
+359
+00:32:42,850 --> 00:32:49,090
+الأحماض النووية ومنهابصير اسمها deoxy sugars يعني
+
+360
+00:32:49,090 --> 00:32:53,470
+لاحظوا هذا ال sugar لما يكون فيه ال oxygen و سكر
+
+361
+00:32:53,470 --> 00:32:58,610
+من خمس كربونات tripose تمام لما نشيل منه oxygen
+
+362
+00:32:58,610 --> 00:33:02,870
+منها يعني في الأصل كان في عنده OH لو شيلنا منه
+
+363
+00:33:02,870 --> 00:33:09,490
+oxygen ايش بيصير اسمه؟ deoxy، deoxy يعني منزوعأه
+
+364
+00:33:09,490 --> 00:33:14,570
+لحظة ميزه .. ميزه رجاء في الكلمات، عشانك احنا
+
+365
+00:33:14,570 --> 00:33:22,080
+بنقول اتعبوا شوية، يعني لو اتينا قولنالكم ضايقزيدا
+
+366
+00:33:22,080 --> 00:33:27,800
+يعني اتنين اه لكن دي منزوعة زي ما كنا نقول
+
+367
+00:33:27,800 --> 00:33:31,760
+hydrogenation, dehydrogenation, hydration,
+
+368
+00:33:32,600 --> 00:33:38,260
+dehydrogenation, halogenation, dehydrogenation فال
+
+369
+00:33:38,260 --> 00:33:43,820
+دي بتاعنا اللي هو العكس فهذا ال beta دي دي
+
+370
+00:33:43,820 --> 00:33:48,860
+oxyribofuranose طب علشه فيورانوز لأنهمن حلقاء
+
+371
+00:33:48,860 --> 00:33:53,520
+خماسية هو ال sugar تبع ال DNA هو عبارة عن Ribose
+
+372
+00:33:53,520 --> 00:33:58,720
+نزعت منه ال Oxygen و لو كان ال Ribose اللي في ال
+
+373
+00:33:58,720 --> 00:34:05,400
+Oxygen بيعملنا ال RNA Ribonucleic Acid لما يكون ال
+
+374
+00:34:05,400 --> 00:34:09,800
+DNA Deoxyribonucleic Acid واضح؟
+
+375
+00:34:12,560 --> 00:34:19,700
+الكلام عام عن اللي هي ال dice carats و عن ال
+
+376
+00:34:19,700 --> 00:34:26,210
+polymers اللي بتكونوا منهم خلينا يعني نبدأنعطي
+
+377
+00:34:26,210 --> 00:34:31,310
+فكرة عامة ليش أنا محتاجها الآن مقارنة مع
+
+378
+00:34:31,310 --> 00:34:37,050
+البروتينات اللي بدنا ناخدها في الفصل الأخير ان شاء
+
+379
+00:34:37,050 --> 00:34:41,910
+الله اللي هو ال amino acids و ال peptides و ال
+
+380
+00:34:41,910 --> 00:34:48,210
+proteins زي ما لاحظته يمكن أهم شغلة في ال
+
+381
+00:34:48,210 --> 00:34:52,290
+polysaccharides أهم شغلة في ال polysaccharides أن
+
+382
+00:34:52,290 --> 00:34:57,650
+هم polymersماذا يعني polymers؟ يعني لما أقول
+
+383
+00:34:57,650 --> 00:35:04,150
+النشا، إيش الوحدة تبعته؟ هتقولولي مالتوز
+
+384
+00:35:04,150 --> 00:35:10,390
+البيسكريدي المالتوز، تمام؟ لو قولت مثلا السيللوز،
+
+385
+00:35:10,390 --> 00:35:15,870
+بوليمر كبير، إيش الوحدة تبعته؟ السيلوبيوز، ولذلك
+
+386
+00:35:15,870 --> 00:35:23,490
+ال polysaccharidesيمكن التعامل معها يكون أسهل كتير
+
+387
+00:35:23,490 --> 00:35:28,790
+من التعامل مع البروتينات ليش؟ لأن ال
+
+388
+00:35:28,790 --> 00:35:32,930
+polysaccharides عندي وحدة و بتتكرر يعني كأن
+
+389
+00:35:32,930 --> 00:35:37,110
+الإنسان بيقدر يقول عنهم ان they are real polymers
+
+390
+00:35:37,110 --> 00:35:43,710
+واضح؟ ال polymers مكون من إيش؟مونومارز تتحد تصير
+
+391
+00:35:43,710 --> 00:35:47,910
+دايمارز، ترايمارز، تترامارز، في الآخر إيش؟
+
+392
+00:35:47,910 --> 00:35:55,190
+بوليمارز، فالبوليمار من ناحية المبدأ وحدة متكررة،
+
+393
+00:35:55,190 --> 00:36:00,390
+البوليمار وحدة إيش مالها؟ متكررة، فلمّا أجي أقول
+
+394
+00:36:00,390 --> 00:36:05,990
+starch polymer ما وحدته المتكررة؟ الملتوز، انتهى
+
+395
+00:36:06,580 --> 00:36:13,060
+واضح؟ الآن لما بدي اجي .. لما بدي اجي اتكلم عن ال
+
+396
+00:36:13,060 --> 00:36:18,900
+proteins هلاحظ ان في عندي اختلاف أساسي ال proteins
+
+397
+00:36:18,900 --> 00:36:26,580
+عبارة عن amino acids وال amino acids مختلفين
+
+398
+00:36:27,350 --> 00:36:33,110
+واضح ال amino acids مختلفين ولذلك انا لما بدي اجي
+
+399
+00:36:33,110 --> 00:36:38,050
+اعمل مثلا نشا بقدر اقول بقدر اقول في حالة النشا او
+
+400
+00:36:38,050 --> 00:36:44,630
+ال amylose مالتوز تلاتين
+
+401
+00:36:44,630 --> 00:36:50,320
+وحدة مثلا او تلاتميت وحدةملتوز 300 وحدة واضح؟
+
+402
+00:36:50,320 --> 00:36:56,520
+الملتوز مكرر كده؟ 300 مرة هاي صرت عامل مثلا اميلوز
+
+403
+00:36:56,520 --> 00:37:01,240
+لكن لو جيت بدي اعمل البروتين او الأصغر من البروتين
+
+404
+00:37:01,240 --> 00:37:04,720
+ال بيبتايد اللي هيمر علينا بعد شوية مابقدرش اعمل
+
+405
+00:37:04,720 --> 00:37:09,460
+مثل هذه المعادلة واضح؟ يعني هذه المعادلة ان اقول
+
+406
+00:37:09,460 --> 00:37:15,860
+انه is a real polymerاللي هي ال polysaccharides
+
+407
+00:37:15,860 --> 00:37:21,480
+مالتوز منه تلاتمية وحدة او منه مائة الف وحدة في ال
+
+408
+00:37:21,480 --> 00:37:26,640
+glycogen على سبيل المثال او ما إلى ذلك هي وحدة و
+
+409
+00:37:26,640 --> 00:37:32,680
+متكررة لما بدي اجي احكي عن ال protein
+
+410
+00:37:36,730 --> 00:37:43,590
+هلاحظ ان البروتين عبارة عن amino acids عدد كبير من
+
+411
+00:37:43,590 --> 00:37:49,190
+ال amino acids الان كل amino acid من ناحية المبدأ
+
+412
+00:37:49,190 --> 00:37:56,730
+بختلف عن التاني يعني خليني اتخيل ان هذا حقيقة بمثل
+
+413
+00:37:56,730 --> 00:38:03,490
+البروتين الان هذا بقدر احط عليه كذا to the N لأ طب
+
+414
+00:38:03,490 --> 00:38:10,740
+ايش المطلوب اعمله؟أعمله إيش التسلسل تبعه، يعني لو
+
+415
+00:38:10,740 --> 00:38:14,600
+اتخيلت أنا أن هذا بروتين صغير، يعني بيبتايد، بقول
+
+416
+00:38:14,600 --> 00:38:19,700
+لحظة معايا إيش التسلسل تبعه من amino acids، أسود،
+
+417
+00:38:19,700 --> 00:38:27,230
+أخضر، أحمر، أسود، أزرقتمام؟ الآن كل واحد شكل من
+
+418
+00:38:27,230 --> 00:38:29,870
+هدول، يعني هذا في الـ amino acids ممكن يكون
+
+419
+00:38:29,870 --> 00:38:36,990
+إجليسين، ألانين، سيستين، تريبتوفان، كذا، فما بقدرش
+
+420
+00:38:36,990 --> 00:38:38,830
+أصيغه بصيغة
+
+421
+00:38:41,480 --> 00:38:45,080
+amino acid و بعدين اقول عنه to the end فالان
+
+422
+00:38:45,080 --> 00:38:51,640
+تخيلوا لو كان في عندي مثلا protein من 300 amino
+
+423
+00:38:51,640 --> 00:38:58,780
+acid عشان اعرفه جيدا ايش المطلوب مني اعمل احدد ال
+
+424
+00:38:58,780 --> 00:39:04,200
+300 amino acid مرتبين هذا بيسموه ايش؟ sequence
+
+425
+00:39:04,200 --> 00:39:11,930
+يعني كيف هدول مرتبينأعمل التسلسل تبعه، الآن فكرة
+
+426
+00:39:11,930 --> 00:39:16,490
+ال sequence أو التسلسل غير موجودة في ال
+
+427
+00:39:16,490 --> 00:39:21,170
+polysaccharides، ال polysaccharides نفس الشغلة to
+
+428
+00:39:21,170 --> 00:39:28,380
+the Nمالتوز to the M خلصت واضح بينما في ال
+
+429
+00:39:28,380 --> 00:39:33,100
+proteins هتواجهنا صعوبة ان ال proteins وحدتهم
+
+430
+00:39:33,100 --> 00:39:37,660
+الأساسية amino acids ال amino acids عادة اللي
+
+431
+00:39:37,660 --> 00:39:41,720
+موجودين في ال protein عشرين amino acid الان لما
+
+432
+00:39:41,720 --> 00:39:50,400
+يكون عندى protein من تلتمية amino acid كويس
+
+433
+00:39:50,400 --> 00:39:56,960
+في أشياء مكررة لكنلابد من ال sequence هم اكيد هم
+
+434
+00:39:56,960 --> 00:40:00,580
+اكيد عشرين amino acid تقريبا اللي موجودين في ال
+
+435
+00:40:00,580 --> 00:40:07,180
+proteins لكن هدول العشرين لما بدي اخد منهم protein
+
+436
+00:40:07,180 --> 00:40:15,700
+من تلاتمية amino acid كيف هيكونوا؟ هيكونوا
+
+437
+00:40:15,700 --> 00:40:22,050
+مختلفين مافيش ان احك مثلا glycine to the Nعشان
+
+438
+00:40:22,050 --> 00:40:28,290
+اميز اي protein عن التاني لازم اعد ال 300 ولذلك ال
+
+439
+00:40:28,290 --> 00:40:32,950
+protein لو انا بدى اتكلم عنه انه هل هو real
+
+440
+00:40:32,950 --> 00:40:40,870
+polymer يعني حقيقي بمعنى الكلمة الجواب لأ ال real
+
+441
+00:40:40,870 --> 00:40:48,390
+polymer حقيقة ايش هو؟ monomerto the end زي ما
+
+442
+00:40:48,390 --> 00:40:52,770
+شوفنا ال polyethylene و ال PVC و حتى كمان ال
+
+443
+00:40:52,770 --> 00:40:57,750
+polysaccharides مونومر مكرر لكن هنا لما بدي أجي
+
+444
+00:40:57,750 --> 00:41:01,570
+أحكي عن ال protein هصير أجيب ال amino acids أقول
+
+445
+00:41:01,570 --> 00:41:07,910
+glycine, alanine, tryptophan, cysteine كذا كذا
+
+446
+00:41:07,910 --> 00:41:14,270
+هتلاحظوا أنه مطلوب منناانحدد الترتيب تبع ال amino
+
+447
+00:41:14,270 --> 00:41:17,690
+acids ولذلك ال proteins لو الإنسان بده يستعمل
+
+448
+00:41:17,690 --> 00:41:23,010
+الكلام بدقة أكثر they are macro molecules جزيئات
+
+449
+00:41:23,010 --> 00:41:30,490
+كبيرة macro molecules جزيئات كبيرة أكثر منهم إيش
+
+450
+00:41:30,490 --> 00:41:39,610
+polymers they are macro molecules أكثر منهمبولمار
+
+451
+00:41:39,610 --> 00:41:46,310
+طبعا فيهم نوعا ما شيء مشترك بيخلي بعض الناس يقولوا
+
+452
+00:41:46,310 --> 00:41:54,670
+ممكن تجاوزا نعتبر ال protein بولمار ليش؟ لأنه لو
+
+453
+00:41:54,670 --> 00:42:00,010
+أنا اتطلعت على الهيكل تبعه اللي بتكرر هلاحظ ان هو
+
+454
+00:42:00,010 --> 00:42:05,960
+عبارة عن NCEالان هذه الوحدة بتتكرر في البروتين
+
+455
+00:42:05,960 --> 00:42:12,760
+بعدها N C C double bond O بعدها N C C double bond
+
+456
+00:42:12,760 --> 00:42:19,220
+O هتقولولي مش ناقص غير ايش تكتب هذولة to the N طب
+
+457
+00:42:19,220 --> 00:42:25,870
+ليش مش قادر اكتبهم؟لأن كل amino acid فيها R group
+
+458
+00:42:25,870 --> 00:42:33,210
+مختلفة يعني هذه مرة H هذه مرة CH3 هذه مرة CH2SH
+
+459
+00:42:33,210 --> 00:42:40,430
+فلو بتطلع على الهيكل الأساسي للذرات لبروتين NCC
+
+460
+00:42:40,430 --> 00:42:45,870
+double bond O هو مكرر لكن لو طلعت على هذه المجموعة
+
+461
+00:42:46,670 --> 00:42:51,530
+مش مكررة بناء على ذلك لو هذا مثلا كان بيبتايد هذا
+
+462
+00:42:51,530 --> 00:42:55,810
+بيبتايد مكون من كام amino acid من تلاتة هتعلم أن
+
+463
+00:42:55,810 --> 00:43:00,570
+هذا اسمه إجليسين هذا اسمه ألانين هذا اسمه سيستين
+
+464
+00:43:00,570 --> 00:43:05,450
+حصير أقول هذاEglicin, Alanine, Cysteine هيكون بفرق
+
+465
+00:43:05,450 --> 00:43:08,390
+عن Alanine, Eglicin, Cysteine من نفس التلاتة
+
+466
+00:43:08,390 --> 00:43:14,810
+فانفعلكوا لما نصيح نحكي عن تلاتمية فالبروتين بوجهة
+
+467
+00:43:14,810 --> 00:43:19,870
+النظر اللي بده يتطلع الهيكل الأساسي هو كأنه بوليمر
+
+468
+00:43:19,870 --> 00:43:25,170
+امكرر في N, C, C double bond O N, C, C double bond
+
+469
+00:43:25,170 --> 00:43:28,950
+O لكن لما نيجي نلاحظ أن هذه المجموعة اللي هنا
+
+470
+00:43:28,950 --> 00:43:36,740
+اختلفتبطل polymer ولذلك ال polymer مابنعدش ال 300
+
+471
+00:43:36,740 --> 00:43:40,680
+وحدة ولا ال 5000 وحدة تبعته بس ال protein بدي
+
+472
+00:43:40,680 --> 00:43:45,860
+أجهزة و بدي علم يوم أقول هذا protein كذا يذكر لل
+
+473
+00:43:45,860 --> 00:43:54,170
+5000 وحدة مرتبين و نفس الاشي هيتكرر معاكم مهمفي ال
+
+474
+00:43:54,170 --> 00:43:58,670
+nucleic acids عشان هيك في الشفرة الوراثية وغيرها
+
+475
+00:43:58,670 --> 00:44:02,570
+وغيراتها هتلاحظوا ان البني ادم بيختلف عن التاني و
+
+476
+00:44:02,570 --> 00:44:07,270
+الشغل بتختلف عن التاني انه بدي اذكر الأشياء مرتبة
+
+477
+00:44:08,550 --> 00:44:18,550
+كذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+478
+00:44:18,550 --> 00:44:19,230
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+479
+00:44:19,230 --> 00:44:19,250
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+480
+00:44:19,250 --> 00:44:19,450
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+481
+00:44:19,450 --> 00:44:22,470
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+482
+00:44:22,470 --> 00:44:25,070
+وكذا
+
+483
+00:44:25,690 --> 00:44:30,730
+جزيئات كبيرة اكثر من ان نسميها Polymers و نقدر
+
+484
+00:44:30,730 --> 00:44:35,170
+نكتب شغلته دي انا الان حيصير درسنا القادم سهل اللي
+
+485
+00:44:35,170 --> 00:44:39,730
+بده يدرس ال proteins ايش أساسهم اذا اول شئ بدنا
+
+486
+00:44:39,730 --> 00:44:45,310
+نتعلم على ال amino acids بعدين ال amino acids بتحد
+
+487
+00:44:45,310 --> 00:44:48,890
+و بيعملوا ال protein نتعلم كيف نوجد ال sequence و
+
+488
+00:44:48,890 --> 00:44:53,390
+كيف نحضر ال protein لو بدنايالكن حيكون ان شاء الله
+
+489
+00:44:53,390 --> 00:44:58,410
+درسنا القادم على الوحدة المكونة للبروتين اللي هي
+
+490
+00:44:58,410 --> 00:45:00,370
+عبارة عن ايش؟ الامام
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..d0f068143bbccb8c183919fb88088fb2f701e1e2
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_raw.json
@@ -0,0 +1 @@
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Aromatic Substitution ولذلك لو إحنا بنيجي بنسألكم مثلا aromatic compounds undergo addition reactions غلط", "tokens": [5016, 9566, 36081, 2423, 1783, 9673, 29245, 49401, 29538, 3714, 5016, 36520, 3660, 16712, 5172, 995, 30241, 11933, 15730, 16712, 5172, 995, 30241, 11933, 1829, 8592, 4724, 1829, 9381, 13546, 24525, 2304, 3224, 12575, 11741, 388, 299, 1587, 13143, 42090, 6518, 35525, 8848, 23275, 45164, 11933, 5016, 8315, 44945, 1829, 7435, 1829, 44945, 3794, 10721, 23275, 2304, 50113, 15040, 45831, 21810, 26426, 4500, 12215, 32771, 1211, 9566], "avg_logprob": -0.24379595982677796, "compression_ratio": 1.3523316062176165, "no_speech_prob": 0.0, "words": [{"start": 738.16, "end": 738.7, "word": "حطيت", "probability": 0.6922200520833334}, {"start": 738.7, "end": 738.82, "word": " ال", "probability": 0.8173828125}, {"start": 738.82, "end": 739.08, "word": " X", "probability": 0.32421875}, {"start": 739.08, "end": 739.8, "word": " الموجبة", "probability": 0.9026692708333334}, {"start": 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0.9517822265625}, {"start": 775.01, "end": 775.59, "word": " التوظيف", "probability": 0.861572265625}, {"start": 775.59, "end": 775.79, "word": " لما", "probability": 0.78173828125}, {"start": 775.79, "end": 776.05, "word": " الواحد", "probability": 0.97265625}, {"start": 776.05, "end": 776.67, "word": " بيسأل", "probability": 0.98076171875}, {"start": 776.67, "end": 777.45, "word": " بهمش", "probability": 0.5625}, {"start": 777.45, "end": 777.89, "word": " يخلي", "probability": 0.66796875}, {"start": 777.89, "end": 778.25, "word": " الطالب", "probability": 0.9910481770833334}, {"start": 778.25, "end": 778.51, "word": " يعيد", "probability": 0.75732421875}, {"start": 778.51, "end": 778.71, "word": " كل", "probability": 0.943359375}, {"start": 778.71, "end": 779.13, "word": " العلم", "probability": 0.993896484375}, {"start": 779.13, "end": 779.69, "word": " بس", "probability": 0.95654296875}, {"start": 779.69, "end": 780.03, "word": " ممكن", "probability": 0.959228515625}, {"start": 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46, "seek": 108195, "start": 1061.17, "end": 1081.95, "text": "هذا التفاعل مختلف، يتفاعل على الـ aliphatic carbon لما كنا نقول مثان CH4 و بعدين Cl2 في وجود الضوء اللي بنعبر عليه frequency يعني اللي هو تعبير عن الضوء، plant constant في التردد، هذا طاقة الضوء أو heat", "tokens": [3224, 15730, 16712, 5172, 995, 30241, 3714, 46456, 46538, 12399, 7251, 2655, 5172, 995, 30241, 15844, 2423, 39184, 419, 24595, 2399, 5954, 5296, 15042, 9122, 8315, 8717, 39648, 50113, 7649, 5995, 19, 4032, 39182, 9957, 2033, 17, 8978, 49610, 23328, 6024, 114, 2407, 38207, 13672, 1829, 44945, 3615, 26890, 47356, 7893, 37495, 22653, 13672, 1829, 31439, 37279, 3555, 13546, 18871, 6024, 114, 2407, 38207, 12399, 3709, 5754, 8978, 16712, 2288, 3215, 3215, 12399, 23758, 23032, 995, 28671, 6024, 114, 2407, 38207, 34051, 3738], "avg_logprob": -0.30822173115752993, "compression_ratio": 1.509433962264151, "no_speech_prob": 0.0, "words": [{"start": 1061.17, "end": 1061.49, "word": "هذا", "probability": 0.884033203125}, 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بيعطيني", "probability": 0.771435546875}, {"start": 1088.05, "end": 1089.39, "word": " CH3Cl", "probability": 0.8919270833333334}, {"start": 1089.39, "end": 1090.31, "word": " هذا", "probability": 0.85107421875}, {"start": 1090.31, "end": 1090.71, "word": " ابدال", "probability": 0.59033203125}, {"start": 1090.71, "end": 1090.87, "word": " على", "probability": 0.79638671875}, {"start": 1090.87, "end": 1090.97, "word": " ال", "probability": 0.96484375}, {"start": 1090.97, "end": 1091.43, "word": " aliphatic", "probability": 0.6488444010416666}, {"start": 1091.43, "end": 1092.03, "word": " compounds", "probability": 0.84716796875}, {"start": 1092.03, "end": 1092.55, "word": " لان", "probability": 0.4833984375}, {"start": 1092.55, "end": 1092.73, "word": " لو", "probability": 0.97607421875}, {"start": 1092.73, "end": 1093.05, "word": " هذا", "probability": 0.92236328125}, {"start": 1093.05, "end": 1093.67, "word": " الكلام", "probability": 0.9650065104166666}, {"start": 1093.67, "end": 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حطيت عليه جزء aromatic يعني ممكن يعمل ادالة على الحلقة و كتبت هنا CH2 CH3 و بدى اعمله halogenation اه بيصير اذا قلتلكم فعلوا مع CL2 في وجود FECL3 اذا بتكون حطوا CL على الحلقة", "tokens": [3555, 3224, 15730, 25124, 28820, 16472, 3224, 1975, 8315, 45164, 10874, 3555, 2655, 9673, 31747, 3555, 8717, 36178, 3224, 45164, 10874, 3555, 2655, 9673, 31747, 3555, 8717, 36178, 3224, 4032, 11331, 9566, 36081, 47356, 10874, 11622, 38207, 45831, 37495, 22653, 3714, 43020, 7251, 25957, 1211, 1975, 3215, 6027, 3660, 15844, 21542, 1211, 28671, 4032, 9122, 2655, 3555, 2655, 34105, 5995, 17, 5995, 18, 4032, 47525, 7578, 1975, 25957, 43761, 7523, 8799, 399, 1975, 3224, 4724, 1829, 9381, 13546, 1975, 15730, 12174, 1211, 2655, 23275, 2304, 6156, 30241, 14407, 20449, 12855, 17, 8978, 49610, 23328, 479, 8140, 43, 18, 1975, 15730, 39894, 30544, 11331, 9566, 14407, 12855, 15844, 21542, 1211, 28671], "avg_logprob": -0.18046171681301013, "compression_ratio": 1.6946902654867257, "no_speech_prob": 0.0, "words": 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"probability": 0.97119140625}, {"start": 2793.83, "end": 2794.39, "word": " حصن", "probability": 0.760498046875}, {"start": 2794.39, "end": 2795.23, "word": " باسمنا", "probability": 0.67919921875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2795.404, "duration_after_vad": 2679.683124999987}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..cb91c76f3bef52f8e11c70062c5254867c337a0d
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_postprocess.srt
@@ -0,0 +1,2048 @@
+1
+00:00:19,570 --> 00:00:24,470
+بسم الله الرحمن الرحيم اليوم ان شاء الله بنشرح
+
+2
+00:00:24,470 --> 00:00:31,450
+معلومات ايضا مختصرة على موضوع ال carbohydrates جزء
+
+3
+00:00:31,450 --> 00:00:39,870
+من ال biochemistry طبعا ال carbohydrates هم اكثر
+
+4
+00:00:40,850 --> 00:00:46,930
+جزيئات يمكن موجودة في الطبيعة من الجزيئات الحيوية
+
+5
+00:00:46,930 --> 00:00:51,770
+يمكن البعض يستغرب لكن لما تفكروا بس قداش في
+
+6
+00:00:51,770 --> 00:00:57,810
+بالدنيا نباتات و النباتات بشكل أساسي cellulose و
+
+7
+00:00:57,810 --> 00:01:03,430
+ال cellulose هو عبارة عن carbohydrates هذا الكلام
+
+8
+00:01:03,430 --> 00:01:09,890
+يمكن يعطيكم إيش فكرةبشكل عام ال carbohydrates
+
+9
+00:01:09,890 --> 00:01:16,010
+الصيغة تبعتهم هي عبارة عن carbon مع مية مكررين
+
+10
+00:01:16,010 --> 00:01:21,890
+يعني CH2O to the N فمن هنا إجت فكرة carbohydrates
+
+11
+00:01:21,890 --> 00:01:29,250
+يعني ال carbons وبعدين الميةCarbons وميّه واضح
+
+12
+00:01:29,250 --> 00:01:34,130
+فعلى سبيل المثال يعني لو بدكوا تاخدوا أنتوا أبسط
+
+13
+00:01:34,130 --> 00:01:42,510
+سكر .. أبسط سكر اللي هو C6H12O6
+
+14
+00:01:42,510 --> 00:01:51,010
+الآن بنقدر نقول هذا عبارة عن 6 في C وH2O
+
+15
+00:01:51,010 --> 00:01:58,700
+فهو مضاعف لل Carbon و الميّهواضح؟ C6H12O6
+
+16
+00:01:58,700 --> 00:02:04,900
+واضح الفكرة؟ ومن هنا إجا الاسم carbohydrate لأنه
+
+17
+00:02:04,900 --> 00:02:11,740
+بشكل أساسي الصيغة البسيطة تبعته هي عبارة عن carbon
+
+18
+00:02:11,740 --> 00:02:17,700
+وميه واضح هذه الفكرة؟ يعني لما نيجي نسألكم أن ال
+
+19
+00:02:17,700 --> 00:02:20,660
+carbohydrates الصيغة الأساسية بتاعتهم carbon و
+
+20
+00:02:20,660 --> 00:02:25,540
+oxygen carbon و hydrogenلأ لو كربون و هيدروجين كال
+
+21
+00:02:25,540 --> 00:02:30,800
+سمناها hydrocarbon لكن carbohydrate يعني كربون و
+
+22
+00:02:30,800 --> 00:02:35,840
+مياه الآن ال carbohydrates ببساطة احنا بنقدر
+
+23
+00:02:35,840 --> 00:02:41,260
+نتخيلها اذا بنفهمها بالشكل القاتل هي عبارة عن
+
+24
+00:02:41,260 --> 00:02:47,540
+جزيئات في الغالب كبيرة يعني ممكن نتخيل ان هذا جزيئ
+
+25
+00:02:48,170 --> 00:02:55,070
+كبير أشبه ما تكون بوليمار تمام الآن هذه الجزيئات
+
+26
+00:02:55,070 --> 00:02:59,650
+الكبيرة بنسميها احنا polysaccharides يعني سكريات
+
+27
+00:02:59,650 --> 00:03:05,720
+اشمالها عديدة لو عملنا لها hydrolysisفي وجود حمض
+
+28
+00:03:05,720 --> 00:03:12,200
+ميه بتتكسر الى جزيئات اصغر من وحدتين او تلاتة هذه
+
+29
+00:03:12,200 --> 00:03:16,980
+الجزيئات الاصغر بنسميها oligosaccharides يعني هي
+
+30
+00:03:16,980 --> 00:03:21,780
+كانت الكبيرة polysaccharide اتكسرت الى
+
+31
+00:03:21,780 --> 00:03:26,720
+oligosaccharides سكريات بسيطة زى السكريات الثنائية
+
+32
+00:03:26,720 --> 00:03:31,770
+هتمر علينا الان لو كسرناها اكتربصير عندى
+
+33
+00:03:31,770 --> 00:03:37,150
+monosaccharides اللى هو السكر المنفرد فإحنا لما
+
+34
+00:03:37,150 --> 00:03:41,750
+بدنا ندرس الآن بهذا الفصل و نتعرف على السكريات
+
+35
+00:03:41,750 --> 00:03:47,110
+هيكون المحور تبعنا بسيط جدا هنبدأ نقول إيش والله
+
+36
+00:03:47,110 --> 00:03:53,090
+ال monosaccharidesالمنفرد بعد هيك من اكثر من
+
+37
+00:03:53,090 --> 00:03:57,690
+monosaccharide هنعمل disaccharide اللي هو نوع من
+
+38
+00:03:57,690 --> 00:04:01,970
+ال oligosaccharide هيطلع عند السكاروز والملتوز
+
+39
+00:04:01,970 --> 00:04:06,430
+والاشياء هذه اللي هيواضح؟ الآن من ال
+
+40
+00:04:06,430 --> 00:04:11,950
+oligosaccharides هنعمل الجزيئات الكبيرة بشكل أساسي
+
+41
+00:04:11,950 --> 00:04:17,870
+النشا ال starch و ال cellulose واضح؟ فاحنا هنمشي
+
+42
+00:04:17,870 --> 00:04:22,110
+بهذا التدريج أن نتعرف في البداية شو هي ال
+
+43
+00:04:22,110 --> 00:04:27,120
+monosaccharides شو معناه sugarمنفرد لوحده الآن بعد
+
+44
+00:04:27,120 --> 00:04:32,160
+هيك اتنين من الشجر المنفرد هيعملولي Dysaccharide
+
+45
+00:04:32,160 --> 00:04:36,280
+اللي هو يعتبر نوع من ال Oligosaccharides و بعدين
+
+46
+00:04:36,280 --> 00:04:41,180
+لو اتحدوا ال Dysaccharides بشكل كبير عدد كبير منهم
+
+47
+00:04:41,180 --> 00:04:46,140
+بيعطينا ال إيش ال polysaccharides على سبيل المثال
+
+48
+00:04:46,140 --> 00:04:52,890
+النشا polysaccharideالنشط بولي ساكرايد لو عملنا له
+
+49
+00:04:52,890 --> 00:04:58,510
+هيدروليسيز بيعطينا داي ساكرايد اللي هو الملتوز
+
+50
+00:04:58,510 --> 00:05:03,950
+فالملتوز أوليغو ساكرايد أو داي ساكرايد ما هو الداي
+
+51
+00:05:03,950 --> 00:05:08,910
+أحد أنواع الأوليغو ساكرايد الآن لو الملتوز كسرناه
+
+52
+00:05:08,910 --> 00:05:16,240
+للوحدات الأساسية هو مكون من وحدتين جولوكوزالملتوز
+
+53
+00:05:16,240 --> 00:05:21,220
+من وحدتين جولوكوز واضح الفكرة فالجولوكوز مونو
+
+54
+00:05:21,220 --> 00:05:27,760
+ساكرايد الملتوز داي ساكرايد الاسترش بوني ساكرايد
+
+55
+00:05:27,760 --> 00:05:34,260
+واضح طبعا اللي بده يبتدى الان يتعرف ايش هم المونو
+
+56
+00:05:34,260 --> 00:05:37,300
+ساكرايد ايش هم المونو ساكرايد
+
+57
+00:05:40,150 --> 00:05:45,650
+ال sugar بنعرفهم انهم polyhydroxyaldehydes او
+
+58
+00:05:45,650 --> 00:05:49,670
+polyhydroxyketones ال polyhydroxyaldehydes بنسميهم
+
+59
+00:05:49,670 --> 00:05:54,130
+ال doses و ال polyhydroxyketones كيتوزز بمعنى
+
+60
+00:05:54,130 --> 00:06:01,070
+الشجر لازم يكون فيه يا aldehyde يا كيتون مع
+
+61
+00:06:01,070 --> 00:06:09,170
+مجموعات OH كتيرة اكثر من مجموعة OHولذلك لو احنا
+
+62
+00:06:09,170 --> 00:06:13,850
+اتطلعنا مثلا على المركب اللى موجود عندنا هنا اللى
+
+63
+00:06:13,850 --> 00:06:19,570
+هو الجليسرال ديهايد هل يترى هذا يمكن انه يتصنف
+
+64
+00:06:19,570 --> 00:06:27,510
+بمنطق الكيميا ك sugar فى عندي هنا الديهايد وفى
+
+65
+00:06:27,510 --> 00:06:35,050
+عندي هنا مجموعاتOH إذا هذا بولي هيدروكسي الديهايد
+
+66
+00:06:35,050 --> 00:06:39,330
+يعني عديد هيدروكسي ال الديهايد ولذلك هذا بنقول عنه
+
+67
+00:06:39,330 --> 00:06:45,550
+إيش ال dose ال dose يعني sugar من ال الديهايد طيب
+
+68
+00:06:45,550 --> 00:06:50,570
+ال dye هيدروكسي أسيتون بتعرفوا ال أسيتون CH3C
+
+69
+00:06:50,570 --> 00:06:55,130
+double bond O CH3 شيلت H حطيت مكان هنا OH وكمان
+
+70
+00:06:55,130 --> 00:07:01,270
+هنا OH صارDihydroxy-13-Dihydroxyacetone الآن هذا
+
+71
+00:07:01,270 --> 00:07:08,050
+الـDihydroxyacetone فيه كيتون وفيه
+
+72
+00:07:08,050 --> 00:07:14,870
+مجموعات OH إذا هذا عبارة عن بوليهيدروكس كيتون
+
+73
+00:07:14,870 --> 00:07:20,010
+بوليهيدروكس كيتون إذا هذا sugar كيتوز
+
+74
+00:07:21,950 --> 00:07:27,190
+ليش؟ لأنه جاي من كيتون، الدوز من ال الديهايد، واضح
+
+75
+00:07:27,190 --> 00:07:34,110
+الفكرة؟ الآن لو اتطلعت على ال glycerol، ال
+
+76
+00:07:34,110 --> 00:07:37,950
+glycerol او ال glycerin، فيه بس ال O H's، مافيه
+
+77
+00:07:37,950 --> 00:07:43,190
+الديهايد او كيتون، فهل ال glycerin بنصنفه انه
+
+78
+00:07:43,190 --> 00:07:46,930
+sugar كيميائيا؟ لأواضحة الفكرة؟ يعني لما نيجي
+
+79
+00:07:46,930 --> 00:07:51,410
+نقولكم glycerol can be classified as a sugar او is
+
+80
+00:07:51,410 --> 00:07:54,630
+classified as a sugar، لأ، لو قلنالكوا
+
+81
+00:07:54,630 --> 00:08:01,810
+dihydroxyacetone is an aldose، فهمته؟ او لو
+
+82
+00:08:01,810 --> 00:08:07,390
+قلنالكوا glyceraldehyde is equitoseglial aldehyde
+
+83
+00:08:07,390 --> 00:08:11,630
+is an aldose, dihydroxyacetone is a ketose تفهمنا
+
+84
+00:08:11,630 --> 00:08:15,710
+بالظبط إذا إيش معنى sugar، إيش معنى aldose، إيش
+
+85
+00:08:15,710 --> 00:08:20,550
+معنى ketose، واضحة الفكرة؟ والشجر لازم ينوجد فيه
+
+86
+00:08:20,550 --> 00:08:26,790
+كام شغلة؟ شغلتين، يا الديهيد، يا كيتون، ومجموعات
+
+87
+00:08:26,790 --> 00:08:35,230
+الـOH، هذا اللي بدنا نصنفه sugarلو بدنا ننطلق من
+
+88
+00:08:35,230 --> 00:08:40,850
+ال glyceraldehyde، ال glyceraldehyde كم carbon كان
+
+89
+00:08:40,850 --> 00:08:47,710
+فيه؟ تلاتة، تلاتة، احنا بدنا نعلمكوا العد، تلاتة،
+
+90
+00:08:47,710 --> 00:08:49,670
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+91
+00:08:49,670 --> 00:08:51,370
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+92
+00:08:51,370 --> 00:08:58,720
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تهي الديهيد و
+
+93
+00:08:58,720 --> 00:09:02,360
+أكتر من جمعة أواتش هذا بنقول عنه تيتروز تيتروز
+
+94
+00:09:02,360 --> 00:09:09,430
+يعني سكر إيش من أربع كربونات طب لو كانوا خمسةبنتوز
+
+95
+00:09:09,430 --> 00:09:14,530
+لو كانوا ستة هكسوز طبعا هذه كلها اللي موجودة عندنا
+
+96
+00:09:14,530 --> 00:09:20,150
+لأن الجزء الأول فيها الديهيد they are all doses طب
+
+97
+00:09:20,150 --> 00:09:25,830
+لو كان فيها كيتون برضه هذا تتروز وبنتوز وهكسوز لكن
+
+98
+00:09:25,830 --> 00:09:31,590
+هذه ايش كيتوز واضح؟ الان كل واحد هياخد اسم تفصيلي
+
+99
+00:09:31,590 --> 00:09:36,490
+بس بشكل عام ممكن السكر يكون من تلات ذرات من أربعة
+
+100
+00:09:36,490 --> 00:09:41,610
+من خمسة من ستةيعني هدولة خلينا نقول الاش المشهورين
+
+101
+00:09:41,610 --> 00:09:48,410
+الآن لو بدنا نتطلع في ال sugars و اتطلعنا على أبسط
+
+102
+00:09:48,410 --> 00:09:54,770
+واحد فيهم ال glyceraldehyde ع طول هنلاحظ أن هذا ال
+
+103
+00:09:54,770 --> 00:10:00,310
+glyceraldehyde فيه chiral center يعني لو اتطلعنا
+
+104
+00:10:00,310 --> 00:10:03,210
+ال C double bond OH اللي هو جزء ال aldehyde هذا
+
+105
+00:10:03,210 --> 00:10:06,090
+مافيش فيه chiral center ال chiral center أربع
+
+106
+00:10:06,090 --> 00:10:12,980
+مجموعاتمختلفة، الآن ال CH2OH الأخيرة مافيها chiral
+
+107
+00:10:12,980 --> 00:10:19,460
+center، الكاربون الوسطني هاديفيها chiral center
+
+108
+00:10:19,460 --> 00:10:22,940
+الكربون الوسطاني اللي موجود عندنا فيها chiral
+
+109
+00:10:22,940 --> 00:10:28,920
+center الآن لاحظوا معي انه في ال sugars في ال
+
+110
+00:10:28,920 --> 00:10:34,760
+sugars هذه جزيئات شوية كبيرة وكل واحد ممكن يرسمها
+
+111
+00:10:34,760 --> 00:10:38,880
+بطريقة معينة يعني واحد ممكن يرسم واقف نايم مائل
+
+112
+00:10:38,880 --> 00:10:45,000
+عشان يسهلوا تبعون ال biochemistry على بعض المتابعة
+
+113
+00:10:45,000 --> 00:10:52,080
+اتفقواإنه يوحدوا طريقة الرسم، يعني ليش أضلني أتعب
+
+114
+00:10:52,080 --> 00:10:55,680
+الطالب مرة أحط مجموعة الالديهايد يمين، مرة شمال،
+
+115
+00:10:55,680 --> 00:10:59,820
+مرة فوق، مرة تحت، بره أرسم الجزء مائل، في كل لحظة
+
+116
+00:10:59,820 --> 00:11:04,670
+هو بيصير بحاجة إلىمزيد من التفكير و من الوقت عشان
+
+117
+00:11:04,670 --> 00:11:10,530
+يفهم إيش شكل الجزء فقالوا إيش المانع؟ إيش المانع؟
+
+118
+00:11:10,530 --> 00:11:15,910
+إن نوحد طريقة الرسم لما نرسم ال sugars بدل ما كل
+
+119
+00:11:15,910 --> 00:11:18,650
+واحد يرسمه بطريقة معينة و نقعد نقول وين ال
+
+120
+00:11:18,650 --> 00:11:22,350
+aldehyde وين ال OHS وين ال chiral center ليش ما
+
+121
+00:11:22,350 --> 00:11:29,310
+نرسم بطريقة موحدة؟بنسهل على الناس تمام؟ طيب إيش
+
+122
+00:11:29,310 --> 00:11:33,910
+فكرة الرسم بالطريقة الموحدة؟ جال خلّي المجموعة
+
+123
+00:11:33,910 --> 00:11:37,210
+اللي هي الكبيرة ال carbon اللي حاملة أعلى إشي اللي
+
+124
+00:11:37,210 --> 00:11:42,630
+هي ال aldehyde تكون لفوق و ارسم بهذا الشكل العمودي
+
+125
+00:11:42,630 --> 00:11:46,950
+واضح؟ يعني نخلي مجموعة ال aldehyde أو ال keto اللي
+
+126
+00:11:46,950 --> 00:11:54,970
+وجدت لأعلى و بنرسم بشكل عموديطبعا اخر شئ هنا هيكون
+
+127
+00:11:54,970 --> 00:12:03,090
+عندى CH2OH الان ايش ضال عندى على الوسط OH OH ضال
+
+128
+00:12:03,090 --> 00:12:09,030
+عندى في الوسط OH OH هذه ال OH OH بالتأكيد طالما
+
+129
+00:12:09,030 --> 00:12:14,830
+هذا chiral center هيكون فيه الجزئ و صورتهفى
+
+130
+00:12:14,830 --> 00:12:18,490
+المراية حيكون عند الجزء و صورته فى المراية لو
+
+131
+00:12:18,490 --> 00:12:22,630
+جربنا ان نشوف ال configuration إيه لو جربنا نشوف
+
+132
+00:12:22,630 --> 00:12:29,390
+ال configuration إيه هتتذكروا ان هذه أقل مجموعة و
+
+133
+00:12:29,390 --> 00:12:33,570
+ال oxygen أعلى مجموعة بعدين الكاربون اللى متصل
+
+134
+00:12:33,570 --> 00:12:37,490
+مرتين بال oxygen بعدها بعدين الكاربون اللى متصل
+
+135
+00:12:37,490 --> 00:12:41,830
+مرة بال oxygen وبناء على ذلك لو أنا بدي أمشي هى
+
+136
+00:12:41,830 --> 00:12:50,270
+نمره واحدنمرة اتنين، نمرة تلاتة، مبينة كإنها S،
+
+137
+00:12:50,270 --> 00:12:54,830
+لكن لأن هذه المجموعة الصغيرة للأمام، بنعكس ال
+
+138
+00:12:54,830 --> 00:13:01,270
+configuration، إذن هذا Rوبالتجربة ال R طلع بلس
+
+139
+00:13:01,270 --> 00:13:04,390
+بتذكرين لما قولنا ال plus و ال minus هذا من قصة
+
+140
+00:13:04,390 --> 00:13:09,330
+بالتجربة بال بولاريمتر الآن هذا بالتأكيد ال
+
+141
+00:13:09,330 --> 00:13:13,490
+enantiomer التاني هو ال S فبناء على ذلك ال
+
+142
+00:13:13,490 --> 00:13:19,650
+glyceraldehyde طالما في one chiral center إذا في
+
+143
+00:13:19,650 --> 00:13:27,060
+منه كام مركب اتنين R و Sالان تابعون ال
+
+144
+00:13:27,060 --> 00:13:32,020
+biochemistry قالوا احنا بنحب الخصوصية مش حابين
+
+145
+00:13:32,020 --> 00:13:36,580
+نظلنا مربوطين في جماعة الكيميا طب ليش يا عم
+
+146
+00:13:36,580 --> 00:13:41,800
+بتزيدوا غلبتنا قال بهمش الطلاب بتحملونا ايش اللي
+
+147
+00:13:41,800 --> 00:13:48,740
+بدكمياه قال بدل ما نستعمل ال R و ال S نستعمل D و L
+
+148
+00:13:50,330 --> 00:13:54,210
+هما لو ضالوا على ال R و ال S العلم بيمشي لكن قرروا
+
+149
+00:13:54,210 --> 00:13:59,650
+انهم بيستعملوا D و L الآن ضمن هذا الشكل اللي رسمنا
+
+150
+00:13:59,650 --> 00:14:02,450
+فيه يعني المجموعة هذه ال الدياد أو ال keto اللي
+
+151
+00:14:02,450 --> 00:14:07,630
+فوق قالوا إذا كانت ال OH على ال carbon اللي هي قبل
+
+152
+00:14:07,630 --> 00:14:10,770
+الأخيرة منها يعني هي أخر carbon من تحتها دي اللي
+
+153
+00:14:10,770 --> 00:14:16,010
+قبلها إذا كانت ال OH على اليمين بنعطي للمركب الرمز
+
+154
+00:14:16,500 --> 00:14:22,460
+وإذا كانت الـ OH على الشمال بنعطي المركب الرمز L
+
+155
+00:14:22,460 --> 00:14:27,540
+فصيرنا نقول هذا دي إجليسرال ديهيد وهال و هذا
+
+156
+00:14:27,540 --> 00:14:33,000
+الإجليسرال ديهيد الآن هم ركزوا على أي كاربون
+
+157
+00:14:33,000 --> 00:14:38,980
+تحديدا حاملة الـ OHالـ OH اللي جابلي الأخيرة، ليش؟
+
+158
+00:14:38,980 --> 00:14:42,820
+لأنه بعد شوية .. بعد شوية حيصير عندى أكثر من
+
+159
+00:14:42,820 --> 00:14:47,580
+Carbon بتحمل OH OH OH OH و أكثر من chiral center
+
+160
+00:14:47,580 --> 00:14:52,680
+مين فيهم اللي بدي أوصفه أنه D أو L؟ وين بدي أطلع؟
+
+161
+00:14:52,680 --> 00:14:56,940
+بدي أطلع مش على آخر Carbon، آخر Carbon مش chiral
+
+162
+00:14:56,940 --> 00:15:02,660
+أول Carbon chiral من تحت، اللي هي نمرة 2، لأن هو
+
+163
+00:15:02,660 --> 00:15:08,570
+اللي مش chiralواضح فلما انا بدي بعد شوية اصير اطلع
+
+164
+00:15:08,570 --> 00:15:15,310
+هيك على شكله و اقول هذا D ولا L بدي اطلع وين من
+
+165
+00:15:15,310 --> 00:15:23,190
+التحت طبعا هنا في عندي scheme كيف ببدأ انا ازيد في
+
+166
+00:15:23,190 --> 00:15:28,070
+مجموعات ال OH يعني اول ما بدأت تلاتة بعد هيك ببدأ
+
+167
+00:15:28,070 --> 00:15:34,930
+ازيد واضح انه هذا ال scheme يمكناضعيف جدا و لذلك
+
+168
+00:15:34,930 --> 00:15:41,230
+انا حاولت ان اجزء هذا ال scheme لأشياء لعلها تكون
+
+169
+00:15:41,230 --> 00:15:47,490
+أوضح لاحظوا معي بالنسبة لل glyceral dehyd هي ال OH
+
+170
+00:15:47,490 --> 00:15:52,200
+هنا على اليمين اذا انا جيبت بس منه ايش؟الـ D
+
+171
+00:15:52,200 --> 00:15:57,540
+-Glyceraldehyde الان يا ترى لو بدى ازيد كربون تانى
+
+172
+00:15:57,540 --> 00:16:03,280
+على ال D-Glyceraldehyde وين بدى اجي احطها؟ بهذا
+
+173
+00:16:03,280 --> 00:16:14,060
+الموقع واضح؟ هذه الكربون حاملةوح وح وح
+
+174
+00:16:14,060 --> 00:16:16,620
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+175
+00:16:16,620 --> 00:16:16,900
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+176
+00:16:16,900 --> 00:16:21,200
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+177
+00:16:21,200 --> 00:16:25,800
+وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+178
+00:16:25,800 --> 00:16:25,920
+وح وح وح وح وح وح وح وح وح وح وح
+
+179
+00:16:36,210 --> 00:16:40,270
+D لكن انا ال carbon اللي زيدتها في الوسط اللي الآن
+
+180
+00:16:40,270 --> 00:16:43,350
+بعلم عليها بالأحمر اللي هو ال chiral center التاني
+
+181
+00:16:43,350 --> 00:16:49,430
+مرة حطيت فيه ال OH علي اليمين و مرة حطيت فيه ال OH
+
+182
+00:16:49,430 --> 00:16:54,990
+علي الشمال بناء على ذلك لما انا زيدت من تلت ذرات
+
+183
+00:16:54,990 --> 00:17:01,630
+لاربع ذرات من ال D اعملت كام مركب اتنين طب لو
+
+184
+00:17:01,630 --> 00:17:07,900
+أخدنا الجزء التاني اللي هو ال Lهتكون ال OH هذه على
+
+185
+00:17:07,900 --> 00:17:11,820
+اليسار و هزيد واحدة مرة يمين و مرة شمال برضه هعمل
+
+186
+00:17:11,820 --> 00:17:19,400
+ايش؟ اتنين واضح؟ اذا كام مركب صار عندي من الاربع
+
+187
+00:17:19,400 --> 00:17:23,280
+ذرات كربون اللي هو two chiral centers؟ اربع احنا
+
+188
+00:17:23,280 --> 00:17:30,700
+أخدنا انهعدد الـ Stereoisomers 2 to the N فلما كان
+
+189
+00:17:30,700 --> 00:17:35,300
+عندي one chiral center كان عندي مركبين اللي هو الـ
+
+190
+00:17:35,300 --> 00:17:39,740
+D-glyceraldehyde و الـ L-glyceraldehyde طب الآن
+
+191
+00:17:39,740 --> 00:17:42,680
+لما زيدت كمان chiral center، one chiral center و
+
+192
+00:17:42,680 --> 00:17:47,170
+one chiral centerصار عندى كام مُركّب؟ أربعة شومة
+
+193
+00:17:47,170 --> 00:17:51,770
+الأربعة في عندى هذا المُركّب لأن هذه الـ OH أول
+
+194
+00:17:51,770 --> 00:17:57,210
+واحدة كيرال من تحت على اليمين دي بسميه D-erythrose
+
+195
+00:17:58,950 --> 00:18:03,570
+تمام؟ و لأن الـ OH هذه على الشمال بيصير مركّب تاني
+
+196
+00:18:03,570 --> 00:18:09,070
+طبعا هذه طالما علي اليمين هتعطيني كلمة إيش؟ D دي
+
+197
+00:18:09,070 --> 00:18:14,070
+هذا بسميه Ethreose فصار في عندي مركّب اسمه D
+
+198
+00:18:14,070 --> 00:18:20,410
+-Erythrose و مركّب اسمه D-Ethreose ال Erythrose زي
+
+199
+00:18:20,410 --> 00:18:24,570
+ما بتلاحظوا اللي موجودة فيه الـ OH التاني على
+
+200
+00:18:25,670 --> 00:18:31,110
+اليمين والثريوز اللي موجودة فيه هذه على اليسار طب
+
+201
+00:18:31,110 --> 00:18:36,720
+الأن وين المركبين التانيين؟الـ L اللي هم الـ L لما
+
+202
+00:18:36,720 --> 00:18:40,320
+بدي الـ L شو بدي أعمل بهدي؟ بدي أعكسها يعني أنا
+
+203
+00:18:40,320 --> 00:18:45,060
+هنا جايب نص الصورة جايب ال D زي ما فيه D بتاخدوا
+
+204
+00:18:45,060 --> 00:18:49,880
+نفس الجزيه تماما و بس بنعكس منه إيش الـ OH الـ OH
+
+205
+00:18:49,880 --> 00:18:55,720
+الخضرة أول واحدة كايرال من تحت طبعا هي بتكون تاني
+
+206
+00:18:55,720 --> 00:18:59,780
+واحدة لإن هذه مش كايرال هي أول واحدة كايرال من تحت
+
+207
+00:19:01,360 --> 00:19:06,880
+واضح الفكرة؟ الآن اتخيلوا من هدول الاتنين لو بدى
+
+208
+00:19:06,880 --> 00:19:12,040
+ازيد كمان ذرة carbon يعني اخليهم بدل اربعة خمسة
+
+209
+00:19:12,040 --> 00:19:20,280
+وين هازيد ذرة ال carbon هادي؟ هنا الان من هذه لما
+
+210
+00:19:20,280 --> 00:19:26,720
+بدى ازيد واحدة هنا وين هتيجي؟يا يمين، يا شمال، يا
+
+211
+00:19:26,720 --> 00:19:29,980
+شمال،
+
+212
+00:19:29,980 --> 00:19:37,580
+يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا
+
+213
+00:19:37,580 --> 00:19:42,640
+شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا شمال،
+
+214
+00:19:42,640 --> 00:19:45,500
+يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا
+
+215
+00:19:45,500 --> 00:19:46,080
+شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا شمال،
+
+216
+00:19:46,080 --> 00:19:52,290
+شمال، يا شمالتمانية اتنين اقصد تلاتة تمانية الان
+
+217
+00:19:52,290 --> 00:19:56,950
+لو بدنا نتعرف عليهم نتعرف على نصهم اللي هم جايين
+
+218
+00:19:56,950 --> 00:20:02,710
+من وين من ال D هاي المركب ال D اللي توي رسمناه
+
+219
+00:20:02,710 --> 00:20:09,850
+طالما هذي على اليمين اذا هذا D صحيح الان بدي ازيد
+
+220
+00:20:09,850 --> 00:20:17,330
+كمان هذا الرباعي لأ هذا صار الخماسي حط هذه وين مرة
+
+221
+00:20:18,610 --> 00:20:25,130
+يمين مرة شمال، الآن هذول أعطاهم أسماء، شو أعطاهم؟
+
+222
+00:20:25,130 --> 00:20:31,490
+دي رايبوز وهذا دي أرابينوز، ليش دي؟ لأنه هذي
+
+223
+00:20:31,490 --> 00:20:36,690
+عاليمين، الآن بنصير نقول شو هو الرايبوز؟ الرايبوز
+
+224
+00:20:36,690 --> 00:20:40,790
+السكر الخماسي اللي تلت مجموعات ال OH في جين ع جهة
+
+225
+00:20:40,790 --> 00:20:46,690
+واحدةالان الارابينوز الشو هو السكر الخماسي اللى
+
+226
+00:20:46,690 --> 00:20:50,930
+هدولة بتنتنع جهة وادي على جهة تانية لحظوا قاعدة
+
+227
+00:20:50,930 --> 00:20:57,170
+بتكتر المراكبات عندى هذا خمس درات كربون واحد اتنين
+
+228
+00:20:57,170 --> 00:21:02,690
+تلاتة اربعة خمسة بكم chiral center تلاتة طالما
+
+229
+00:21:02,690 --> 00:21:07,410
+عندى تلاتة chiral center اذا كم مركب تمانية وين
+
+230
+00:21:07,410 --> 00:21:16,070
+التمانية4D و 4R بالظبط واضحة؟
+
+231
+00:21:16,070 --> 00:21:22,770
+انا هنا بس أخدت الاريثروز و جسمته يتبعوا معاك هذا
+
+232
+00:21:22,770 --> 00:21:28,590
+بس اللي نتج من الاريثروز لما أجسم للثريوز بيعطيني
+
+233
+00:21:28,590 --> 00:21:35,410
+كمان اتنين اتنين و اتنين اربع اربع و هكذا واضح؟
+
+234
+00:21:35,410 --> 00:21:36,430
+هاي للثريوز
+
+235
+00:21:40,860 --> 00:21:44,360
+خلّينا هذا اللي اتعودنا نقول عنه دي نخليه باللون
+
+236
+00:21:44,360 --> 00:21:48,780
+الأخضر هذا السكر التالي الاثريوز مش احنا قولنا
+
+237
+00:21:48,780 --> 00:21:57,060
+الاريثروز و الاثريوز الاريثروز بيقسم لاتنين هايهم
+
+238
+00:21:57,060 --> 00:22:01,760
+و الاثريوز بيقسم لاتنين تانين الان الاتنين اللي
+
+239
+00:22:01,760 --> 00:22:05,820
+بيقسملهم الاثريوز بياخدوا اسم اكزايلوز و لاكزوز
+
+240
+00:22:07,610 --> 00:22:13,030
+فصار المجموع من الخماسي اربعة D و اربعة L كده؟
+
+241
+00:22:13,030 --> 00:22:19,030
+تمانية لو جينا اي واحد من هدولة بدنا نزيد له
+
+242
+00:22:19,030 --> 00:22:25,250
+chiral center هيقسم لإيش؟ لاتنين طالما وما تمانية
+
+243
+00:22:25,250 --> 00:22:29,290
+كل واحد يقسم لاتنين هيصير المجموع ستة عشر كلام
+
+244
+00:22:29,290 --> 00:22:32,650
+منطقي ليش؟ لأنه لما يصير عند اربعة chiral centers
+
+245
+00:22:32,650 --> 00:22:39,090
+اتنين اقص اربعة16 16 اتنين اقصى اربعة ستة عشر فلما
+
+246
+00:22:39,090 --> 00:22:43,230
+نيجي نتعرف عليهم لما نيجي نتعرف عليهم لو أخدنا
+
+247
+00:22:43,230 --> 00:22:49,250
+مثلا الريبوز هاي ال O H هذه العملة دي و زيدنا
+
+248
+00:22:49,250 --> 00:22:53,690
+كايرة ال center وين هنا
+
+249
+00:22:53,690 --> 00:23:01,730
+هذا هيعمل O H مرة يمين و مرة شمال
+
+250
+00:23:03,120 --> 00:23:07,240
+لو أخدنا الأرابينوز برضه وين بدنا نزيد الـ OH؟
+
+251
+00:23:07,240 --> 00:23:14,580
+هنا، هتيجي مرة يمين و مرة شمال، الآن هدولة بنبدأ
+
+252
+00:23:14,580 --> 00:23:19,980
+نعطيهم أسماء اللي كلهم جايين زي بعض سموه ألوز، هذا
+
+253
+00:23:19,980 --> 00:23:25,360
+تلاتة و بعدين واحدة زي بعض ألتروز، هذا الجولوكوز
+
+254
+00:23:25,360 --> 00:23:31,300
+صاحبنا، اللي بدأ تحفظ الجولوكوزيعني منهم كلهم بدنا
+
+255
+00:23:31,300 --> 00:23:34,860
+نقولكوا بس احفظوا الجولوكوز كيف ترتيب مجموعاته
+
+256
+00:23:34,860 --> 00:23:39,960
+طبعا اللي بدها تحفظ الجولوكوز بدها تقولوا one and
+
+257
+00:23:39,960 --> 00:23:44,440
+six carbonate صحيح؟ الآن الـC double bond OH
+
+258
+00:23:44,440 --> 00:23:51,400
+الالديهيد هذه لفوق أكيد مافيها نقاش والـCH2OH هذه
+
+259
+00:23:51,400 --> 00:23:59,040
+لتحت أكيد ولا فيها نقاش؟ الآن لو قلنا Dجولوكوز،
+
+260
+00:23:59,040 --> 00:24:03,900
+إيش معناه دي؟ إنه هذه لازم تكون على اليمين، الآن
+
+261
+00:24:03,900 --> 00:24:08,080
+في دي جولوكوز، بعد ما نحط هذه على اليمين، ضال عنده
+
+262
+00:24:08,080 --> 00:24:16,960
+يمين شمال يمين، ولو كنا جايلين الجولوكوز، هتخلوا
+
+263
+00:24:16,960 --> 00:24:22,200
+هذه تيجي هنا والباقي زي ما هوواضح؟ يعني اللي بيغير
+
+264
+00:24:22,200 --> 00:24:25,660
+دي و قل هذه المجموعة، هذه يمين دي، لو قلتلكوا بدي
+
+265
+00:24:25,660 --> 00:24:31,560
+القل جولوكوز، خدوا هذا الـD و غيروا بس هذه، إذا
+
+266
+00:24:31,560 --> 00:24:36,520
+كانت هذه يمين، دي جولوكوزة، الآن الخلاصة بهذا
+
+267
+00:24:36,520 --> 00:24:44,240
+الشكل، كم sugar طلع عنده؟16 16 sugar و الكلام
+
+268
+00:24:44,240 --> 00:24:49,740
+منطقي ليش من ال 6 كربونات لأن ال 6 كربونات فيهم 4
+
+269
+00:24:49,740 --> 00:24:55,760
+chiral centers و المركب مش symmetric 2 أس 4 16
+
+270
+00:24:55,760 --> 00:25:02,220
+الان لو بدنا هدولا ال 16 ناخد أسماءهم هاي أربعة
+
+271
+00:25:02,220 --> 00:25:06,020
+منهم الألوز و الألتروز و الجولوكوز و المانوز و لو
+
+272
+00:25:06,020 --> 00:25:12,140
+أخدنا الأربعة التانين اللي في الأساس جوا منالثريوز
+
+273
+00:25:12,140 --> 00:25:16,660
+الجولوز والأيدوز والجالاكتوز والتالوز الآن هذول
+
+274
+00:25:16,660 --> 00:25:21,460
+تمانية ايش التمانية التانية كل هذول التمانية دي
+
+275
+00:25:21,460 --> 00:25:30,640
+التمانية التانية ال ال واضح فبصف عندى ست عشر مركب
+
+276
+00:25:30,640 --> 00:25:37,340
+لل C6 لاحظوا معايا هذول الست عشر مركباخذين بعين
+
+277
+00:25:37,340 --> 00:25:42,040
+الاعتبار ان الجولوكوز بهذا الشكل موجود على شكل
+
+278
+00:25:42,040 --> 00:25:48,300
+فاتح مش مسكّر بعد شوية هانيجي نعمل ال cyclic sugar
+
+279
+00:25:48,300 --> 00:25:51,940
+يعني نخليه يسكّر على بعضه كيف بده يسكّر على بعضه
+
+280
+00:25:51,940 --> 00:25:55,340
+احنا لما شرحنا ال aldehyde قولنا لكم في عندي OH
+
+281
+00:25:55,340 --> 00:25:59,980
+وفي عندي aldehyde الكحول بتفعل مع ال aldehyde
+
+282
+00:25:59,980 --> 00:26:04,790
+يعطيني hemiacetalأخدناها كمثال فبنخلّي هذه تسكّر
+
+283
+00:26:04,790 --> 00:26:10,310
+هنا لو هذه سكّرت هنا هنعمل ال Cairo Center الخامس
+
+284
+00:26:10,310 --> 00:26:14,930
+وقت كام ايزومار حيصير عندى اذا صاروا خمس Cairo
+
+285
+00:26:14,930 --> 00:26:22,010
+Centers اتنين اص خمسة ايش اتنين اص خمسة اتنين
+
+286
+00:26:22,010 --> 00:26:28,310
+وتلاتين ايزومار واضح اتنين وتلاتين ايزومار هيكون
+
+287
+00:26:28,310 --> 00:26:39,230
+عندكم من ال C6من 6 ذرات كربون لاحظوا كم هو استيريو
+
+288
+00:26:39,230 --> 00:26:42,870
+كيميستر مهم يعني حد ما درسش استيريو كيميستر عمره
+
+289
+00:26:42,870 --> 00:26:48,360
+ممكن يستوعب موضوعالـ sugars مستحيل وهذا الكلام
+
+290
+00:26:48,360 --> 00:26:51,940
+اللي تقريبا احنا كنا حاطينه في ال scheme العام كنا
+
+291
+00:26:51,940 --> 00:26:57,380
+حاطين لكم كيف الزيادة one chiral center تمام
+
+292
+00:26:57,380 --> 00:27:01,660
+بيكونوا تنين أخدت واحد منهم اعملتله زيادة chiral
+
+293
+00:27:01,660 --> 00:27:06,150
+صاروايعني هن واحد و في واحد تاني موجود يعني لو حد
+
+294
+00:27:06,150 --> 00:27:09,690
+بده يحط ال scheme كاملا بده يجد هذا ال scheme و
+
+295
+00:27:09,690 --> 00:27:12,310
+يحط واحد تاني ليش؟ لأنه انا هن بدت بال D
+
+296
+00:27:12,310 --> 00:27:17,870
+-Glyceraldehyde فيه زيه ال glyceraldehyde و بيقسم
+
+297
+00:27:17,870 --> 00:27:24,430
+بنفس الشكل و بياخد نفس الأسماء طبعا لاحظوا معي أن
+
+298
+00:27:24,430 --> 00:27:29,740
+الأسماء الأساسية الأسماء الأساسية كام اسمتمانية
+
+299
+00:27:29,740 --> 00:27:36,860
+الأسماء الأساسية تمانية اللي هي موجودين
+
+300
+00:27:36,860 --> 00:27:40,560
+عندكم الالوز والألتروز والجولوكوز والمانوز وكذا
+
+301
+00:27:40,560 --> 00:27:47,020
+كذا الآن كيف التمانية بيصيروا الست عاشر طبعا
+
+302
+00:27:47,020 --> 00:27:51,120
+هذا الكلام بإمكانكم أنتم تجلسوا تتدربوا عليه
+
+303
+00:27:51,120 --> 00:27:58,200
+تقرؤوا زي ما قلنا مش ضروري أننا بدنا نحفظهالان لسه
+
+304
+00:27:58,200 --> 00:28:03,880
+الكيميائيين ما شبعوش يعني وصلوكوا ل 16 مركب و بدهم
+
+305
+00:28:03,880 --> 00:28:11,550
+ايش؟وبدهم اكتر قالوا طالما ان السكر فيه OH وفيه
+
+306
+00:28:11,550 --> 00:28:16,050
+الديهايد يعني الكحول و الديهايد نرجع لكيمية ال
+
+307
+00:28:16,050 --> 00:28:20,790
+الديهايد ماش كنا نقول ان ال الديهايد بيعمل تفاعل
+
+308
+00:28:20,790 --> 00:28:26,050
+addition مع الكحولات وبيعطيني hemiacetal ال OH
+
+309
+00:28:26,050 --> 00:28:32,420
+بتهاجم علىالـ C double bond O تبعت ال الديهايد
+
+310
+00:28:32,420 --> 00:28:39,080
+بتخليها OH متذكرينه التفاعل ولا نذكر فيه الناس
+
+311
+00:28:39,080 --> 00:28:43,340
+اللي مش متذكرينه التفاعل نكتبها لما كنا نقول مثلا
+
+312
+00:28:43,340 --> 00:28:51,840
+Methanol مثل OH هي نرسمه بالأسود زائد CH3C double
+
+313
+00:28:51,840 --> 00:29:00,510
+bond OH هي الكحول وهي إيش؟الالديهيد هذه الكحول
+
+314
+00:29:00,510 --> 00:29:05,190
+وهذه الالديهيد لو قلنا لكوا في الامتحان اكمل هذه
+
+315
+00:29:05,190 --> 00:29:08,910
+المعادلة كيف بتفعل الكحول و الالديهيد مش هذا
+
+316
+00:29:08,910 --> 00:29:14,550
+نيوكليوفاين بيعمل addition بيجي بها جمهان وهذا
+
+317
+00:29:14,550 --> 00:29:22,690
+بتصير OH وبناء على ذلك هيكون الناتج CH3C
+
+318
+00:29:22,690 --> 00:29:29,250
+هذا صفية OH وهذا ال H الأصلية وإيجي عندنا من هناو
+
+319
+00:29:29,250 --> 00:29:34,870
+مثل هذا شو سمنا Himacetal Himacetal Himacetal
+
+320
+00:29:34,870 --> 00:29:39,790
+Himacetal
+
+321
+00:29:39,790 --> 00:29:44,810
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+322
+00:29:44,810 --> 00:29:45,610
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+323
+00:29:45,610 --> 00:29:45,770
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+324
+00:29:45,770 --> 00:29:45,810
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+325
+00:29:45,810 --> 00:29:45,890
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+326
+00:29:45,890 --> 00:29:47,790
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+327
+00:29:47,790 --> 00:29:55,530
+Himacetal Himacetal Himacetal
+
+328
+00:29:55,530 --> 00:30:07,430
+Himacetal HimacetHemiacetal OR و OR أسيتال، الآن
+
+329
+00:30:07,430 --> 00:30:12,770
+السكر فيه OH و فيه الديهايد، إيش المانع إنهم
+
+330
+00:30:12,770 --> 00:30:19,560
+يسكروا على بعض؟فيش مانع، وعشان هيك بيصير بيعمل
+
+331
+00:30:19,560 --> 00:30:23,580
+الشكل الحلقي، بنفس منطقة هذا التفاعل، يعني هذا
+
+332
+00:30:23,580 --> 00:30:28,440
+تفاعل تذكير كيف كان الكحول يتفاعل مع إيش؟ مع ال
+
+333
+00:30:28,440 --> 00:30:35,450
+الديهيد، الآن بدنا نرجع لهمفي السكر بدا نرجع للسكر
+
+334
+00:30:35,450 --> 00:30:41,710
+و نشوف كيف بتم هذا التفاعل هاي السكر بنرسمه بشكل
+
+335
+00:30:41,710 --> 00:30:46,070
+ملتوى خليكوا تطلعوا معنا هاي ال الديهايد C double
+
+336
+00:30:46,070 --> 00:30:50,430
+bond O و بعدين carbon حاملة OH و carbon حاملة OH و
+
+337
+00:30:50,430 --> 00:30:56,150
+carbon حاملة OH و هذه اللي هي ال carbon اللي كانت
+
+338
+00:30:56,150 --> 00:31:00,710
+معطية ال D اللي هي القبل الأخيرة
+
+339
+00:31:06,670 --> 00:31:14,590
+الان من ناحية المبدأ كل OH من هدوله ممكن تسكر على
+
+340
+00:31:14,590 --> 00:31:19,780
+ال الديهايديعني نظرياً هذه الـ OH ممكن تسكر على ال
+
+341
+00:31:19,780 --> 00:31:23,320
+الديهاد تعطينا حلقة ثلاثية، هذه ممكن تسكر على ال
+
+342
+00:31:23,320 --> 00:31:26,600
+الديهاد تعطينا حلقة رباعية، هذه ممكن تسكر على
+
+343
+00:31:26,600 --> 00:31:30,260
+الديهاد تعطينا حلقات خماسية، هذه ممكن تسكر تعطينا
+
+344
+00:31:30,260 --> 00:31:35,020
+حلقة سداسية، هذه ممكن تسكرتعطي حلقة سباعية لكن
+
+345
+00:31:35,020 --> 00:31:41,200
+أشهر إغلاق اللي بيعطي الحلقة السداسية فال OH اللي
+
+346
+00:31:41,200 --> 00:31:45,600
+بتسكر في حالة الجولوكوز هي ال OH اللي كانت تتحدد
+
+347
+00:31:45,600 --> 00:31:50,620
+ال D والL ال OH هذه اللي جاب للاخيرة الآن هذه بدأ
+
+348
+00:31:50,620 --> 00:31:56,400
+تيجي تسكر هناهيصير عندى كايرال سنتر جديد يعنى هذه
+
+349
+00:31:56,400 --> 00:32:01,420
+ال carbon هتعمل ايش كايرال سنتر جديد طب انا فى
+
+350
+00:32:01,420 --> 00:32:08,060
+الأساس كام كايرال سنتر عندى هى واحد اتنين تلاتة
+
+351
+00:32:08,060 --> 00:32:14,440
+اربعة ولمّا اجى اعمل هنا الإغلاق هيصيروا ايش خمسة
+
+352
+00:32:15,390 --> 00:32:20,530
+هيصيروا خمسة chiral centers وبناء على ذلك لاحظوا
+
+353
+00:32:20,530 --> 00:32:25,890
+معاه ان هدولة اللي هم ابعد عن التفاعل بيظلوا زي ما
+
+354
+00:32:25,890 --> 00:32:29,730
+هم لكن انا بدي اعمل generation لل chiral center
+
+355
+00:32:29,730 --> 00:32:33,830
+على هذا الكربون تحديدا بناء على ذلك لما بعمل
+
+356
+00:32:33,830 --> 00:32:37,490
+generation لل chiral center على هذا الكربون ايش
+
+357
+00:32:37,490 --> 00:32:43,330
+بيصير عندى؟ two enantiomersمظبوط ولا لأ؟ الان
+
+358
+00:32:43,330 --> 00:32:48,470
+هدولة لما بدهم يتموه طبعا مش two enantiomers أقفل
+
+359
+00:32:48,470 --> 00:32:51,450
+two diastereomers ليش؟ لأن أنا مش generation of
+
+360
+00:32:51,450 --> 00:32:55,860
+the first chiral centerاحنا قولنا two enantiomars
+
+361
+00:32:55,860 --> 00:33:00,960
+in equal ratios لو كان ايش؟ اول chiral center بس
+
+362
+00:33:00,960 --> 00:33:04,700
+هل هذا هو اول chiral center ولا نمرخمسة؟ نمرخمسة
+
+363
+00:33:04,700 --> 00:33:09,580
+نمرخمسة لما بنعمل chiral center اشديد second,
+
+364
+00:33:09,940 --> 00:33:13,600
+third, fourth, fifth chiral center شو كان يطلع
+
+365
+00:33:13,600 --> 00:33:18,860
+عندنا؟ اللي جيبناها سؤال في الامتحان unequal
+
+366
+00:33:18,860 --> 00:33:24,720
+mixture of diastereomersمتذكرينه؟ generation of a
+
+367
+00:33:24,720 --> 00:33:28,400
+second chiral center of a third of a fourth chiral
+
+368
+00:33:28,400 --> 00:33:31,640
+center produces an equal mixture of diastereomers
+
+369
+00:33:31,640 --> 00:33:35,320
+الألم هنا بدنا نشوف كيف هذا بده يصير chiral center
+
+370
+00:33:35,320 --> 00:33:41,720
+الـC ضبط هو بده تصير OH هذه الـOH مرة هتكون للأعلى
+
+371
+00:33:41,720 --> 00:33:50,080
+و مرة هتكون للأسفل هم
+
+372
+00:33:50,080 --> 00:33:54,910
+لاحظين؟هي ال chiral center مرة لفوق و مرة لتحت
+
+373
+00:33:54,910 --> 00:34:03,250
+واضح الفكرة؟ الآن في هذا الجزء صار عنده اللي هو ال
+
+374
+00:34:03,250 --> 00:34:07,930
+chiral center الخامس لحظة أنا بدأت بأي سكر؟ ال
+
+375
+00:34:07,930 --> 00:34:11,590
+جولوكوز ال D جولوكوز الآن ال D جولوكوز أعطاني كم
+
+376
+00:34:11,590 --> 00:34:18,270
+مركب؟ اتنين طب أنا كل السكريات اللي اتعرفت عليهم
+
+377
+00:34:18,270 --> 00:34:25,650
+قداش كانواكانوا ستة عشر تمانية D و تمانية L إذا ال
+
+378
+00:34:25,650 --> 00:34:30,410
+D جولوكوز أعطى اتنين الستة عشر كل واحد فيهم هيعطي
+
+379
+00:34:30,410 --> 00:34:34,950
+اتنين اتنين اتنين اتنين اتنين اتنين بستة عشر اتنين
+
+380
+00:34:34,950 --> 00:34:39,280
+و تلاتين هي الاتنين و التلاتين I زمرواضح؟ الان
+
+381
+00:34:39,280 --> 00:34:42,660
+هدولة اللي جدوا عندنا اجداد جايين من الجولوكوز و
+
+382
+00:34:42,660 --> 00:34:46,860
+جايين تحديدا من اي جولوكوز؟ من ال D جولوكوز لما
+
+383
+00:34:46,860 --> 00:34:50,280
+بدنا نميزهم عن بعض انتوا بتقدروا تميزهم تقولوا
+
+384
+00:34:50,280 --> 00:34:57,260
+واحد في ال OH لفوق واحد في ال OH لتحت الان بلغة
+
+385
+00:34:57,260 --> 00:35:01,880
+الكيميا بنقول اللي بيطلع بهذا الشكل و ال OH لفوق
+
+386
+00:35:01,880 --> 00:35:08,090
+بنسميه beta و بنحط الاسم القديممن وين هذا جاي؟ من
+
+387
+00:35:08,090 --> 00:35:12,070
+D جولوكوز، فصار ده Beta D جولوكوز، يعني ال Beta
+
+388
+00:35:12,070 --> 00:35:21,490
+اللي هي لفوق، اه، وإذا كانت لتحت؟ Alpha D جولوكوز،
+
+389
+00:35:21,490 --> 00:35:27,460
+واضح؟الان مرة تانية عشان تبعون ال biochemistry
+
+390
+00:35:27,460 --> 00:35:33,080
+اسهلوا على نفسهم هذه الحلقة السوداسية يمكن ان ترسم
+
+391
+00:35:33,080 --> 00:35:37,660
+بإيش بطرق كتير مختلفة يعني ممكن تخلوا ال oxygen
+
+392
+00:35:37,660 --> 00:35:42,380
+هان هان هان اعتادوا انهم يرسموها بهذا الشكل اللي
+
+393
+00:35:42,380 --> 00:35:47,920
+موجود أمامكم يعني بدكوا ترسموها حلقة سوداسية بهذا
+
+394
+00:35:47,920 --> 00:35:52,680
+الشكل وتجددوا انكوا تحطوا ال oxygen وين؟ع هذا
+
+395
+00:35:52,680 --> 00:35:58,660
+الموقع وبناء على ذلك واجتها بنقول ان الكاربون اللي
+
+396
+00:35:58,660 --> 00:36:03,320
+ماكنتش كايرال سنتر وصارت كايرال سنتر هي اي كاربون؟
+
+397
+00:36:03,320 --> 00:36:09,600
+هذه عشان الناس مايتخربطوش بطريقة الرسم ترسم الحلقة
+
+398
+00:36:09,600 --> 00:36:14,140
+السوداسية عادة في ال biochemistry بهذا الشكل ال
+
+399
+00:36:14,140 --> 00:36:19,640
+oxygen اللي سكرت هي هان هذه الكاربون اللي كانت
+
+400
+00:36:20,700 --> 00:36:28,460
+الديهايد ماكنتش كايرال سنتر صارت كايرال سنتر واضح؟
+
+401
+00:36:28,460 --> 00:36:33,560
+هيهانة قبل ما يسكركانت كايران ولا لأ؟ لأ كان
+
+402
+00:36:33,560 --> 00:36:37,960
+المركب .. كم كايرال سنتر فيه؟ كانوا أربعة و هذه
+
+403
+00:36:37,960 --> 00:36:41,940
+زادت .. هايهم الكايرال سنتر الأربعة و هذه زادت
+
+404
+00:36:41,940 --> 00:36:47,260
+صاروا كدهش؟ خمسة واضح؟ الآن هذه الكاربون اللي
+
+405
+00:36:47,260 --> 00:36:52,440
+ماكنتش كايرال سنتر كانت الديهايد و صارت كايرال
+
+406
+00:36:52,440 --> 00:36:57,560
+سنتر إلها اسم بنسميها Anomeric Carbon
+
+407
+00:36:59,780 --> 00:37:05,500
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+408
+00:37:05,500 --> 00:37:07,800
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+409
+00:37:07,800 --> 00:37:08,020
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+410
+00:37:08,020 --> 00:37:10,440
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+411
+00:37:10,440 --> 00:37:12,440
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+412
+00:37:12,440 --> 00:37:12,540
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+413
+00:37:12,540 --> 00:37:16,080
+انوميرك كاربونالكاربون اللي عملت الكايرال سنتر
+
+414
+00:37:16,080 --> 00:37:20,660
+الجديد كانوا أربعة صاروا إيش؟ خمسة، مين اللي عملت
+
+415
+00:37:20,660 --> 00:37:24,960
+الكايرال سنتر الجديد؟ هذه تبعت ال الديهايد بسميها
+
+416
+00:37:24,960 --> 00:37:30,100
+Anomeric Carbon، الآن إذا الكايرال سنتر هذا الجديد
+
+417
+00:37:30,730 --> 00:37:36,350
+أجت فيه مجموعة الـ OH لأعلى بقول هذا Beta Sugar
+
+418
+00:37:36,350 --> 00:37:41,070
+وإذا أجت لأسفل Alpha Alpha بيضلوا ماخد نفس الاسم
+
+419
+00:37:41,070 --> 00:37:45,630
+اللي هو الـ D والجولوكوز اللي هو يعبر عن كل
+
+420
+00:37:45,630 --> 00:37:52,230
+الترتيبات هذه واضح؟ الآن طالما كانوا 16 وكل واحد
+
+421
+00:37:52,230 --> 00:37:59,750
+بدأ أعمل منهAlpha و Beta قداش حيصيروا 32 طبعا
+
+422
+00:37:59,750 --> 00:38:04,570
+بتكونوا منتبهين أن الأسماء الأساسية في ال sugars
+
+423
+00:38:04,570 --> 00:38:11,990
+قداش تمانية واضحة الفكرة الأسماء الأساسية اللي هي
+
+424
+00:38:11,990 --> 00:38:16,330
+جولوكوز و جولاكتوز و ألوز و ما إلى ذلك كام اسم
+
+425
+00:38:16,330 --> 00:38:20,750
+تمان أسماء يعني خليني أوضحلكوا الصورة مرة أخيرة
+
+426
+00:38:24,310 --> 00:38:29,390
+تمان أسماء أساسية الان هدولة تمان أسماء أساسية كل
+
+427
+00:38:29,390 --> 00:38:35,690
+اسم فيه منه D و L و بعد هيك كل اسم بيصير ايش فيه
+
+428
+00:38:35,690 --> 00:38:44,130
+منه Alpha هذا بيكون Alpha D و Beta D و هذا بيصير
+
+429
+00:38:44,130 --> 00:38:51,510
+منه Alpha L و Beta L واضح؟ هي هذا كده صفة منه؟
+
+430
+00:38:51,510 --> 00:38:58,660
+أربعةيعني لو قولنا من الجولوكوز الجولوكوز
+
+431
+00:38:58,660 --> 00:39:02,800
+واحد منهم في Alpha D جولوكوز و Beta D جولوكوز
+
+432
+00:39:02,800 --> 00:39:09,440
+Alpha L جولوكوز و Beta L جولوكوز و من كل واحد
+
+433
+00:39:09,440 --> 00:39:14,200
+موجودة نفسها للتقسيمة طالما تمان أسماء أساسية في
+
+434
+00:39:14,200 --> 00:39:23,300
+أربعرموز صفر العدد لكل جداش 32 سكر في حالة ما كان
+
+435
+00:39:23,300 --> 00:39:30,020
+السكر إيه اشماله؟ Cyclic لكن لو كان acyclic بس
+
+436
+00:39:30,020 --> 00:39:34,620
+بنصفة ال 16 لأنه ماعملناش ال chiral center الخامس
+
+437
+00:39:34,620 --> 00:39:39,100
+اللي هو ماهيكون جولوكوز D و L جلاكتوز D و L مانوز
+
+438
+00:39:39,100 --> 00:39:47,570
+D و L و هكذا إذا كان acyclicالسكر السداسي بيكون
+
+439
+00:39:47,570 --> 00:39:53,750
+العدد الكلي 16 وإذا كان Cyclic بيكون العدد الكلي
+
+440
+00:39:53,750 --> 00:40:00,490
+32 الآن في ال A Cyclic تمان أسماء كل واحد بيقسم D
+
+441
+00:40:00,490 --> 00:40:08,530
+و L في ال Cyclic كل D و كل L بتقسم إلى ألفة و بيتا
+
+442
+00:40:08,530 --> 00:40:12,550
+الان
+
+443
+00:40:12,550 --> 00:40:18,700
+انتبهوا معيقلنا احنا انه لما يتكون هذا الدياستيريو
+
+444
+00:40:18,700 --> 00:40:23,460
+مارس بيكونوا ب equal ratios ولا unequal ratios؟
+
+445
+00:40:23,460 --> 00:40:30,200
+unequal ratios الان اللي طلع عندنا حقيقة ان ال
+
+446
+00:40:30,200 --> 00:40:37,520
+beta بيطلع بنسبة 64% و ال alpha من الجولوكوس بيطلع
+
+447
+00:40:37,520 --> 00:40:45,380
+بنسبة 36% واضح؟طبعا ال beta لحاله له زاوية دوران
+
+448
+00:40:45,380 --> 00:40:51,420
+plus 19 و ال alpha لحاله لو فصلوا له زاوية دوران
+
+449
+00:40:51,420 --> 00:40:59,120
+112 الان لو حطيت الخليط تبعهم بطلع زاوية بين
+
+450
+00:40:59,120 --> 00:41:02,700
+التنتين ماخدة نسبة بعين الاعتبار الخليط بطلع
+
+451
+00:41:02,700 --> 00:41:10,450
+زاويته حقيقة 52لاحظوا معي، الآن هذا كله اتزان، هذا
+
+452
+00:41:10,450 --> 00:41:15,750
+كله ايش؟ اتزان، بمعنى، لو أنا بدأت في هذا الـA
+
+453
+00:41:15,750 --> 00:41:21,390
+Cyclic و سبته في المحلول، بعد يوم، ايش هلاجيك؟ في
+
+454
+00:41:21,390 --> 00:41:27,090
+نسبة جليلة من الـCyclic ضايلة، سكر لهذا و لهذا، و
+
+455
+00:41:27,090 --> 00:41:34,670
+بنسبة 64% إلى 36%، و بخليط الزاوية تبعتهنتأكد منها
+
+456
+00:41:34,670 --> 00:41:47,210
+بالظبط قداش 52 52 اللي هو الاش ال mixture الخليط
+
+457
+00:41:47,210 --> 00:41:51,460
+اللي من هذا و من هذاالـ A Cyclic له زاوية تانية
+
+458
+00:41:51,460 --> 00:41:55,920
+مالنا و ماله بحكي عن الـ mixture اللي من هذا و من
+
+459
+00:41:55,920 --> 00:42:03,260
+هذا بيكون زاوية و قداش 52 طيب يا تورا لو حطينا الـ
+
+460
+00:42:03,260 --> 00:42:10,040
+A Cyclic هيسكر لإيش؟ لهدولة بنسبة 64 ل 36 طب لو
+
+461
+00:42:10,040 --> 00:42:16,880
+جيبنا هذا نقي و حطيناه لحاله و غيبنا عنه يوم إيش
+
+462
+00:42:16,880 --> 00:42:24,640
+بيعمل؟لا بيعمل اشي هذا في حالة اتزان مع الفاتح
+
+463
+00:42:24,640 --> 00:42:32,760
+الان نتيجة الاتزان بيفتح لما بيفتح بيسكر من اول و
+
+464
+00:42:32,760 --> 00:42:38,520
+جديد بالجهتين وبناء على ذلك لو اجينا حاطينا هذا
+
+465
+00:42:38,520 --> 00:42:43,480
+المسكر و سبناه يوم هو في اتزان مع الفاتح فتح سكر
+
+466
+00:42:43,480 --> 00:42:46,920
+اشمال يمين اشمال يمين بعد يوم بنلاقي ايش الناس
+
+467
+00:42:46,920 --> 00:42:53,530
+بصفيتوجود الاتنين ال alpha و ال beta بنفس النسبة
+
+468
+00:42:53,530 --> 00:43:01,190
+اللي هي ال 64 ل 36 طب لو جيبنا هذا المسكر و
+
+469
+00:43:01,190 --> 00:43:08,250
+دوّبناه في المحلول و سيبناه يوم يومين هذا هيفتح ل
+
+470
+00:43:08,250 --> 00:43:13,940
+ال a cyclic ال a cyclic هيسكر من أول و جديدشمال
+
+471
+00:43:13,940 --> 00:43:19,640
+ويمين شمال ويمين الى ان يصل الى الاتزان 64% الى 36
+
+472
+00:43:19,640 --> 00:43:25,120
+% فسواء بدأت بال A cyclic و سبته في المحلول او
+
+473
+00:43:25,120 --> 00:43:27,880
+بدأت بهذا و سبته في المحلول او بدأت بهذا و سبته في
+
+474
+00:43:27,880 --> 00:43:33,760
+المحلول اصل لنفس الخليط نفس النتيجة هذه العملية
+
+475
+00:43:33,760 --> 00:43:39,670
+الحقيقة بيسموها mutarotationلحظة الميوتا روتيشن هي
+
+476
+00:43:39,670 --> 00:43:44,070
+التغيير في الروتيشن الأبطالي بسبب تغيير الانو مارس
+
+477
+00:43:44,070 --> 00:43:53,290
+هدولة .. هدولة التنين الجداد بنسميهم احنا ايش؟ انو
+
+478
+00:43:53,290 --> 00:43:58,300
+مارساللي جايين من ال anomeric carbon اللي اختلفوا
+
+479
+00:43:58,300 --> 00:44:03,420
+في one chiral center واضح؟ يعني ال anomer beta
+
+480
+00:44:03,420 --> 00:44:07,860
+بيصير ال anomer alpha و ال anomer alpha بيصير ال
+
+481
+00:44:07,860 --> 00:44:12,560
+anomer beta لو حطيت ال alpha بصف على اتزان من
+
+482
+00:44:12,560 --> 00:44:17,120
+alpha و betaو لو حطيت ال beta بصف على اتزان من
+
+483
+00:44:17,120 --> 00:44:21,080
+alpha و beta و بنفس النسبة هذه العملية اللي احنا
+
+484
+00:44:21,080 --> 00:44:24,420
+بنسميها ايش ال mutation rotation لما احط ال alpha
+
+485
+00:44:24,420 --> 00:44:27,300
+و اكون جسد في ال polarimeter راح لاحظ ان الزاوية
+
+486
+00:44:27,300 --> 00:44:32,680
+في أولها 146 بعد شوية بتجل بتجل بتجل اخر مابتصف
+
+487
+00:44:32,680 --> 00:44:40,550
+يداش 52 لو حطيت ال betaالزاوية 19 بضلني اديس معي
+
+488
+00:44:40,550 --> 00:44:46,990
+الزمن بتضل ازيد ازيد ازيد اخر ما بتصفح 52 هذا
+
+489
+00:44:46,990 --> 00:44:52,390
+التغير في ال rotation إلى أن يصل 52 يعني إذا بدأت
+
+490
+00:44:52,390 --> 00:44:57,960
+من هنا ستصل ل 52 وإذا بدأت من هنا ستصل ل 52هذا ايش
+
+491
+00:44:57,960 --> 00:45:03,260
+بنسميه احنا ميوتا روتيشن اللي هو نشوف ايش تعريفه
+
+492
+00:45:03,260 --> 00:45:06,920
+is the change in optical rotation التغيير في ال
+
+493
+00:45:06,920 --> 00:45:09,780
+optical rotation due to inter conversion of
+
+494
+00:45:09,780 --> 00:45:13,360
+animals ان ال alpha بتصير a cyclic و بترجع تصير
+
+495
+00:45:13,360 --> 00:45:17,540
+alpha و beta in solution it is explained by the
+
+496
+00:45:17,540 --> 00:45:22,980
+equilibriumبالفسيرة بإيش أنه في اتزان أنه ال beta
+
+497
+00:45:22,980 --> 00:45:26,080
+بيفتح و بسكر alpha و beta ال alpha بيفتح و بسكر
+
+498
+00:45:26,080 --> 00:45:31,560
+alpha و beta و بنفس إيش الإتزان طبعا بإمكانهم
+
+499
+00:45:31,560 --> 00:45:34,680
+يعملوا حسابات احنا مش موضوعنا الحسابات احنا
+
+500
+00:45:34,680 --> 00:45:38,840
+موضوعنا ببساطة الآن أنه في عندنا سواء بدأت ب alpha
+
+501
+00:45:38,840 --> 00:45:44,980
+أو beta بالمحلول هاصل إلى إيش إلى الاتزان هذا
+
+502
+00:45:44,980 --> 00:45:53,110
+الاتزان 64%Beta و 36% Alpha ايش معناه؟ معناه ان ال
+
+503
+00:45:53,110 --> 00:45:57,810
+.. which is more stable ال Beta ولا ال Alpha؟ ال
+
+504
+00:45:57,810 --> 00:46:03,190
+Beta طبعا هم بيفسروا على انه لو رسمنا السكر على
+
+505
+00:46:03,190 --> 00:46:08,310
+شكل الكرسي مش السكر Cyclohexane في النهاية بتكون
+
+506
+00:46:08,310 --> 00:46:14,250
+ال OH في ال Beta equatorial يعني غير مزدحمة واضح؟
+
+507
+00:46:14,250 --> 00:46:18,690
+هذه ال OH لا تعاني ازدحام، لاحظوا هذه ال OHnot
+
+508
+00:46:18,690 --> 00:46:24,830
+crowded غير مزحمة الان هذه ال اواتش اللي طلع عليها
+
+509
+00:46:24,830 --> 00:46:33,450
+crowded مزحمة عشان هيك هو بفضل يكون في ال beta ولا
+
+510
+00:46:33,450 --> 00:46:39,170
+في ال alpha بالنسبة أعلى في ال beta بهيك بننهي
+
+511
+00:46:39,170 --> 00:46:43,430
+اليوم هذا الجزء و المرة اللي جاي ان شاء الله
+
+512
+00:46:43,430 --> 00:46:44,510
+بنستكمل
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds.srt
new file mode 100644
index 0000000000000000000000000000000000000000..17faa8b9412d5e2a828afdacc39488370d5f8925
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds.srt
@@ -0,0 +1,1691 @@
+
+1
+00:00:20,690 --> 00:00:24,750
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry 
+
+2
+00:00:24,750 --> 00:00:29,730
+ربما المرة الماضية نوّهنا من خلال أنفلة تطبيقية من
+
+3
+00:00:29,730 --> 00:00:36,970
+خلال أهمية فهم ال stereo isomers في الحياة العملية 
+
+4
+00:00:36,970 --> 00:00:42,990
+أن هذا موضوع مهم ولذلك شوية بنظل نتوسع فيه بعد ما 
+
+5
+00:00:42,990 --> 00:00:46,830
+أخدنا المركبات اللي فيها one chiral center قولنا 
+
+6
+00:00:46,830 --> 00:00:51,610
+ال one chiral center بيعتق فقط two isomers بعد ذلك
+
+7
+00:00:51,610 --> 00:00:56,690
+إذا زاد العدد بيبدأوا يزيدوا ال isomers طبعا بيحكم
+
+8
+00:00:56,690 --> 00:01:00,890
+الأمر المعادلة two to the n لكن ال two to the n 
+
+9
+00:01:00,890 --> 00:01:05,230
+هذا أقصى عدد ممكن من ال isomers في كل الأحوال ممكن
+
+10
+00:01:05,230 --> 00:01:10,290
+يكون العدد أقل من هيك وقلنا هنعطي مثال على العدد 
+
+11
+00:01:10,290 --> 00:01:15,330
+الأقصى ومثال على وانتش العدد بيصير أقل في حالة ما
+
+12
+00:01:15,330 --> 00:01:20,620
+عندنا two chiral centers بدأنا في مثال كنا عادة
+
+13
+00:01:20,620 --> 00:01:25,140
+ناخده على أنه مثال بسيط يعني الفكره مركب واحد لما 
+
+14
+00:01:25,140 --> 00:01:29,620
+نيجي نقول two three dichloro بنتين بالفكره مركب
+
+15
+00:01:29,620 --> 00:01:33,640
+واحد لكن لما بنيجي نتطلع على موقع اتنين وعلى موقع
+
+16
+00:01:33,640 --> 00:01:39,410
+تلاتة بنلاحظ ان الاتنين they are chiral centers 
+
+17
+00:01:39,410 --> 00:01:42,750
+وبناء على ذلك بنبدأ نتوقع انه كام مركبة بيصير 
+
+18
+00:01:42,750 --> 00:01:48,890
+عندنا اربع مركبات جربنا نرسمهم من خلال انه نتخيل
+
+19
+00:01:48,890 --> 00:01:52,010
+مثلا بدنا ناخد السلسلة الكربونية بهذا الشكل يعني
+
+20
+00:01:52,010 --> 00:01:56,970
+الخمس كربونات واحد اتنين تلاتة و الاثلاربعة خمسة
+
+21
+00:01:56,970 --> 00:02:01,390
+CH2 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+22
+00:02:01,390 --> 00:02:06,770
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 
+
+23
+00:02:06,770 --> 00:02:08,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+24
+00:02:08,170 --> 00:02:08,950
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 
+
+25
+00:02:08,950 --> 00:02:09,750
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 
+
+26
+00:02:09,750 --> 00:02:10,270
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 
+
+27
+00:02:10,270 --> 00:02:11,790
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+28
+00:02:11,790 --> 00:02:13,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+29
+00:02:13,190 --> 00:02:23,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+30
+00:02:23,190 --> 00:02:27,670
+CH3 CH يعني ال R عكسة S ال R عكسة S كلام منطقي الان 
+
+31
+00:02:27,670 --> 00:02:32,110
+لو جينا نطلع على المركب الثاني two R three S هذا
+
+32
+00:02:32,110 --> 00:02:37,870
+عكسه ال R اقبلها S ال S اقبلها R لأنه دائما صورة
+
+33
+00:02:37,870 --> 00:02:43,590
+بعض في المرأة بتعني التعاكس التام فلو احنا سألنا 
+
+34
+00:02:43,590 --> 00:02:48,170
+ايش العلاقة بين واحد و اتنين they are enantiomers و
+
+35
+00:02:48,170 --> 00:02:52,290
+بيصير مفهوم عندنا ان اي مركبة لما نقول عنهم in 
+
+36
+00:02:52,290 --> 00:02:58,650
+anchors بدتكون اشاراتهم عكس بعض الان طبعا انتوا
+
+37
+00:02:58,650 --> 00:03:02,390
+بالنظر بتقولوا صورة بعض في المرأة غير متطابقة لكن 
+
+38
+00:03:02,390 --> 00:03:08,390
+ماتنسوش شغلة ان انا بإمكاني ارسم 
+
+39
+00:03:09,150 --> 00:03:13,850
+المُركّب بطرق مختلفة بحيث أنه انتوا بمجرد النظر
+
+40
+00:03:13,850 --> 00:03:18,430
+البسيط ما تقدروش تتاخدوا قرار من النظر وجهة القرار 
+
+41
+00:03:18,430 --> 00:03:21,750
+الأكيد بتقدروا تتاخدوا من إيش في علاقة بين
+
+42
+00:03:21,750 --> 00:03:29,110
+المُركّبين من قيم A و S خليني أؤكد الفكرة هذه لو
+
+43
+00:03:29,110 --> 00:03:34,310
+فقط أنا بدي أشغل معكم على مُركّب في one chiral
+
+44
+00:03:34,310 --> 00:03:40,470
+center لو رسمت منه شكلين شو الاحتمالات المتوقعين
+
+45
+00:03:40,470 --> 00:03:43,610
+لما يكون عندي one chiral center؟ يا بده يكون
+
+46
+00:03:43,610 --> 00:03:48,910
+المركب نفسه رسمه بطريقتين مختلفة يا بده يكون in
+
+47
+00:03:48,910 --> 00:03:51,410
+anchormers ماعندي احتمال تاني
+
+48
+00:03:53,870 --> 00:04:01,450
+أخذ بسرعة عشوائيا هاي مركّب CH3CLPR وهي مركّب كتبت
+
+49
+00:04:01,450 --> 00:04:08,010
+هنا ال PR وهنا ال H وهنا ال CL وهنا ال CH3 لاحظوا 
+
+50
+00:04:08,010 --> 00:04:12,610
+هدول المركّبين لو سألتكم ما العلاقة بينهما اللي
+
+51
+00:04:12,610 --> 00:04:16,030
+بده تيجي تتطلع تشوف أي شيء بالنظر و المرايا و
+
+52
+00:04:16,030 --> 00:04:22,100
+بنطبقه و مابنطبقوش حتىمش هتقدر، لأنه أنا أرسمهم 
+
+53
+00:04:22,100 --> 00:04:25,640
+بطرق مختلفة، ماحدش بيمنعني أرسمهم بطرق مختلفة،
+
+54
+00:04:25,640 --> 00:04:31,700
+الآن أسهل شيء أن أحدد لكل مركب R أو S، الآن إذا
+
+55
+00:04:31,700 --> 00:04:35,500
+هذا طلع R و هذا R، معنى ذلك نفس المركب مرسوم بطرق
+
+56
+00:04:35,500 --> 00:04:40,800
+مختلفة، S و S نفس المركب إذا هذا R و هذا S, they 
+
+57
+00:04:40,800 --> 00:04:44,140
+are enantiomers إذا هذا S و هذا R, they are
+
+58
+00:04:44,140 --> 00:04:48,260
+enantiomers هيكا بيكون أسهل طريقة أن أعملهم ولذلك 
+
+59
+00:04:48,260 --> 00:04:54,380
+لو بدي أجي أطلع لهذا أقل مجموع ال H ب RCLCH3 من
+
+60
+00:04:54,380 --> 00:05:00,660
+بين R S لأن هذا ال H للأمام الآن لو بدي أطلع 
+
+61
+00:05:00,660 --> 00:05:12,780
+المركب الثاني ب R CL SCH3 بين R مرة تانية وبنخليها 
+
+62
+00:05:12,780 --> 00:05:18,100
+R لأن ال H للخلف هدول الانشو مارس طالما واحد قسي
+
+63
+00:05:18,100 --> 00:05:21,380
+التاني R إذا we are in ancho mars فالانشو مارس
+
+64
+00:05:21,380 --> 00:05:25,040
+دايما عكس بعض الان لو عندكوا خمسة كايرة ال centers 
+
+65
+00:05:25,040 --> 00:05:29,520
+مش واحدإيش بتكون في الخمسة يكونوا عشان يكونوا 
+
+66
+00:05:29,520 --> 00:05:35,300
+مركبين انانشومارز؟ كل واحد عكس التاني زي أنا باجف 
+
+67
+00:05:35,300 --> 00:05:38,420
+قدام المرايا، الإيدين عكس بعض، الوش عكس بعض، البطن
+
+68
+00:05:38,420 --> 00:05:42,060
+عكس بعض، الرجلين عكس بعض، كل شيء بيكون عكس التاني،
+
+69
+00:05:42,060 --> 00:05:45,120
+يعني لو عندي ان شاء الله عشرين Cairo Center في 
+
+70
+00:05:45,120 --> 00:05:49,600
+مركب، الانانشومارز تبعه، العشرين المقابلات بيكونوا 
+
+71
+00:05:49,600 --> 00:05:56,300
+عكسهم، لو واحدة منهم اختلتببطلوا in anchormers على 
+
+72
+00:05:56,300 --> 00:05:59,840
+طول ببطلوا صورة بعض في المرآة إذا بطلوا صورة بعض 
+
+73
+00:05:59,840 --> 00:06:04,700
+في المرآة، شو بدوا يصيروا؟ ديستيريومارز، تنسوش إن
+
+74
+00:06:04,700 --> 00:06:08,740
+احنا عرفنا الديستيريومارز، they are non-mirror 
+
+75
+00:06:08,740 --> 00:06:12,580
+image in anchormers ولذلك لو أنا سألت العلاقة بين
+
+76
+00:06:12,580 --> 00:06:20,780
+هدول، خلّينا نوضحها باسم RS عكس بعضعكس بعض اذا
+
+77
+00:06:20,780 --> 00:06:24,580
+they are enansimals واضح؟ الان لو سئلت هدول 
+
+78
+00:06:24,580 --> 00:06:33,560
+الاتنين RS SR عكس طلع عليهم R اقبلها S S اقبلها R 
+
+79
+00:06:33,560 --> 00:06:39,320
+عكس بعض they are enansimals الان لو اجيت اخدت مثلا 
+
+80
+00:06:39,320 --> 00:06:49,160
+المركب واحد مع تلاتة اتطلعوا R وR هدولا متل بعض و
+
+81
+00:06:49,160 --> 00:06:56,860
+are و us عكس بعض هل هدولا عكس بعض بالكامل؟ لأ
+
+82
+00:06:56,860 --> 00:07:01,500
+هدولا متل بعض بالكامل؟ لأ مالو كانوا عكس بعض
+
+83
+00:07:01,500 --> 00:07:04,560
+بالكامل يعني كل نقطة عكس التانية they are
+
+84
+00:07:04,560 --> 00:07:10,000
+enantiomers الان لو كل نقطة زي التانية they are
+
+85
+00:07:10,000 --> 00:07:14,600
+the same compound لو كل نقطة زي التانية هو نفس 
+
+86
+00:07:14,600 --> 00:07:20,760
+المُركّب الـ R إيش زي بعض و إيش عكس بعض بطلوا صورة
+
+87
+00:07:20,760 --> 00:07:24,400
+بعض في المرأة أو بطلوا نفس المُركّب إيش هيصفه؟ ده
+
+88
+00:07:24,400 --> 00:07:28,180
+الـ Stereomers إذا لما بنيجي نتطلع إنه بدنا نفهم
+
+89
+00:07:28,180 --> 00:07:32,260
+العلاقة بين مُركّبين من خلال الرموز هنقول إنه
+
+90
+00:07:32,260 --> 00:07:36,260
+عندنا تلت احتمالات في حالة ما عندي أكتر من chiral 
+
+91
+00:07:36,260 --> 00:07:40,600
+center لحظة لما كان عندي one chiral center بدون ما
+
+92
+00:07:40,600 --> 00:07:44,080
+أعمل R و S بقولكوا عندي احتمالين يا بدهم يكونوا
+
+93
+00:07:44,080 --> 00:07:50,120
+نفس المركب R R S S يا بدهم يكونوا Enansi و Mars S
+
+94
+00:07:50,120 --> 00:07:54,840
+R أو R S الان لو كان عندي more than one chiral 
+
+95
+00:07:54,840 --> 00:07:57,960
+center عندي تلت احتمالات الاحتمال الاول بدهم
+
+96
+00:07:57,960 --> 00:08:03,440
+يكونوا Enansi و Mars كل شيء عكس بعض الاحتمال
+
+97
+00:08:03,440 --> 00:08:09,150
+التاني انهم يكونوا نفس المركب كل شيء نفسهزي بعض طب 
+
+98
+00:08:09,150 --> 00:08:12,950
+لو طلع شيء عكس و شيء زي بعض وجدت دي R ده يستيريو 
+
+99
+00:08:12,950 --> 00:08:18,370
+مارس لحظوا الآن لو اجيت على واحد و تلاتة R و S عكس 
+
+100
+00:08:18,370 --> 00:08:23,670
+بعض R و R زي بعض اذا هدولة صورت بعض في المرقاة لأ 
+
+101
+00:08:23,670 --> 00:08:28,530
+نفس المركب لأ ر ده يستيريو مارس اذا واحد و تلاتة
+
+102
+00:08:28,530 --> 00:08:31,970
+ده يستيريو مارس لو طبقته مرة تانية على واحد و 
+
+103
+00:08:31,970 --> 00:08:39,700
+أربعة مثلا ما العلاقة بينهم R و S عكس بعض، هم 
+
+104
+00:08:39,700 --> 00:08:47,540
+لاحظين؟ R و R نفس بعض، they are diastereomers لو
+
+105
+00:08:47,540 --> 00:08:52,720
+إجينا اتطلعنا على اتنين و تلاتة،
+
+106
+00:08:52,720 --> 00:09:02,010
+لاحظوا؟ S و R عكس بعض السؤاس زي بعض كذلك الحال لو
+
+107
+00:09:02,010 --> 00:09:08,070
+اتطلعت اتنين اربع السؤاس نفس الاشي السؤاد عكس بعض
+
+108
+00:09:08,070 --> 00:09:13,230
+they are diastereomers واضح؟صار عندى نوع تانى من 
+
+109
+00:09:13,230 --> 00:09:17,590
+الدياستيريو مارز جاي من وين جاي من المركبات فيها
+
+110
+00:09:17,590 --> 00:09:20,910
+chiral centers يعني احنا اول ما أخدنا تعريف
+
+111
+00:09:20,910 --> 00:09:25,270
+الدياستيريو مارز قولنا كل شيء مش صورة بعض في 
+
+112
+00:09:25,270 --> 00:09:29,500
+المرقاة they are diastereomars الأمثلة الكيميائية
+
+113
+00:09:29,500 --> 00:09:33,820
+الأولى اللى أخدناها شو هي الـ Cis والـ Trans أو
+
+114
+00:09:33,820 --> 00:09:37,300
+الـ Z والـ E they are diastereomers الآن بيجينا
+
+115
+00:09:37,300 --> 00:09:40,900
+أمثلة تانية لما يكون عندى more than one chiral 
+
+116
+00:09:40,900 --> 00:09:45,160
+center هذه الأمثلة بتقول القاتل انه لو كان في عندى
+
+117
+00:09:45,160 --> 00:09:51,530
+مركبين في الإشارات تبعتهممش زي بعض تماما، مش نفس
+
+118
+00:09:51,530 --> 00:09:54,650
+المُركّب، ولا Inansiomers و they are 
+
+119
+00:09:54,650 --> 00:10:00,010
+stereoisomers، إيش هيصفهم؟ ديستيريو مارس، واضح؟ 
+
+120
+00:10:00,010 --> 00:10:05,270
+وبهيك أخدنا إن الديستيريو مارس بكم ما كان، بنشوفهم 
+
+121
+00:10:05,270 --> 00:10:11,460
+بالكيميامكالين بال CC trans او ZE و بال chiral 
+
+122
+00:10:11,460 --> 00:10:15,680
+compounds او بال stereo chemistry لما يكون عندى
+
+123
+00:10:15,680 --> 00:10:21,440
+اكتر من chiral center بشرط انه ننتبه ل ROS
+
+124
+00:10:21,440 --> 00:10:27,760
+بالطريقة اللى اتكلمنا فيها الان طالما ان هدولة الهم
+
+125
+00:10:27,760 --> 00:10:31,760
+إشارات مختلفة فى كام مركب عندى لتو ثري دايكلورو 
+
+126
+00:10:31,760 --> 00:10:36,180
+بنتين أربعة هى رموزهم اللى بدى تروح تشتريهم من 
+
+127
+00:10:36,180 --> 00:10:39,800
+السوق هتلاقيهم أربعة مركبات الآن احنا قولنا ممكن 
+
+128
+00:10:39,800 --> 00:10:46,760
+يكون العدد أقل ناخد مثالهذا المثال 2,3
+
+129
+00:10:46,760 --> 00:10:51,800
+-dichlorobutane قال ذرة كربون واحدة يعني لو انا
+
+130
+00:10:51,800 --> 00:10:56,080
+رسمت هاي كربون تنتين تلاتة اربعة اذا المركب اللي
+
+131
+00:10:56,080 --> 00:11:02,100
+عندى ايش بيوتين واضح لاحظوا ايش بيفرق يعني كتير
+
+132
+00:11:02,100 --> 00:11:09,120
+لبيوتين عن البنتين لو انا مجرد ان كتبت كتابة مثل 
+
+133
+00:11:09,120 --> 00:11:17,800
+CH3 CHCl CHCl CH3 عارفين شو بيفرق؟ لو انا اتيت بين
+
+134
+00:11:17,800 --> 00:11:20,840
+هدولة الـ chiral centers التنين الكاربونز اللي
+
+135
+00:11:20,840 --> 00:11:26,760
+حاملة كلور و جسمت المركب من النصتطلعوا هنا إيش
+
+136
+00:11:26,760 --> 00:11:33,460
+اللي موجود Carbon حاملة HCl و بعدها CH3 و هنا 
+
+137
+00:11:33,460 --> 00:11:39,240
+Carbon حاملة HCl و بعدها CH3 إذا هذا المركب صار
+
+138
+00:11:39,240 --> 00:11:44,460
+مركب متماثل قبل شوية لما كنت .. أو من هنا على هذا
+
+139
+00:11:44,460 --> 00:11:49,800
+الشكل أجسم زي هيك تطلعوا كأعداد ذرات ماذا عندكم
+
+140
+00:11:49,800 --> 00:11:54,980
+هنا؟ كاربون حاملة HCl و CH3 وهنا كاربون حاملة HCl
+
+141
+00:11:54,980 --> 00:12:01,860
+و CH3 فعدد الذرات اللي بهذا الاتجاه هو نفسه عدد
+
+142
+00:12:01,860 --> 00:12:05,760
+الذرات اللي بهذا الاتجاه فهذا الكاربون بيحمل نوع
+
+143
+00:12:05,760 --> 00:12:10,380
+من التماثل هذا الكلام في المثال السابق ماكانش لما 
+
+144
+00:12:10,380 --> 00:12:16,160
+كنتوا تحطوا خط هنابين ال two chiral centers عدولي
+
+145
+00:12:16,160 --> 00:12:22,780
+كل الذرات اللي هتشومها C و H و CL و CH3 و هنا CH و CL
+
+146
+00:12:22,780 --> 00:12:29,460
+و بعدها CH2 CH3 إذا هل هذا النص زي هذا النص لأ في 
+
+147
+00:12:29,460 --> 00:12:34,910
+حالة البيوتينأ لبيوتين في تماثل داخلي بين ال two
+
+148
+00:12:34,910 --> 00:12:39,790
+chiral centers يعني المركب سيماتريك الآن لو إجينا
+
+149
+00:12:39,790 --> 00:12:44,310
+جربنا نرسم ال isomers بنفس الطريقة اللي اتعلمناها
+
+150
+00:12:44,310 --> 00:12:51,270
+سابقا يعني أجي أحط تنتين كلور عكس بعض و صورتهم في
+
+151
+00:12:51,270 --> 00:12:54,810
+المرأة و تنتين كلور على جهة واحدة و صورتهم في
+
+152
+00:12:54,810 --> 00:13:02,210
+المرأة و بعدين أحدد R و S لاحظوا هذه الرسمة تماما
+
+153
+00:13:02,210 --> 00:13:06,510
+هي نسخ و لصق من الرسمة السابقة بس بدل ما كنا 
+
+154
+00:13:06,510 --> 00:13:12,890
+كاتبين هنا اثل كتبنا مثل واضح؟ و لذلك انتوا الان 
+
+155
+00:13:12,890 --> 00:13:20,310
+كام مركب بتشوفه؟ مازالتوا بتشوفوا أربع مركبات
+
+156
+00:13:20,310 --> 00:13:26,150
+للوهلة الأولى لكن لو نظرنا بعمق لهدولة الأربع
+
+157
+00:13:26,150 --> 00:13:32,130
+مركبات هلاحظ ان هذا 2R3R و هذا 2S3S
+
+158
+00:13:34,300 --> 00:13:40,660
+عكس بعض هتيجوا تستنتجوا انهم انانشومارز فش اننا
+
+159
+00:13:40,660 --> 00:13:45,160
+خلاف الآن لما بتيجوا تطلع على المركبين التانيين
+
+160
+00:13:45,160 --> 00:13:49,140
+وخلونا نقول .. نقولنا الترقيم واحد اتنين تلاتة
+
+161
+00:13:49,140 --> 00:13:55,720
+اربعة واحد اتنين تلاتة اربعة و هيناخد واحدة بس
+
+162
+00:13:55,720 --> 00:14:01,560
+نأكد هي ال CL نمرة واحد وهذه ال carbon الحاملة Cl2
+
+163
+00:14:01,560 --> 00:14:09,860
+و CH3 بين S كتبناها R وهذه لو بدنا نتطلع عليها 1 2
+
+164
+00:14:09,860 --> 00:14:16,300
+Cl بعدين carbon حاملة Cl بعدين CH3 Cl بعدين carbon
+
+165
+00:14:16,300 --> 00:14:21,100
+حاملة Cl بعدين CH3 بين R كتبنا S إذا هيك مظبوطين
+
+166
+00:14:21,100 --> 00:14:25,900
+هدولة two R three S لو اعملنا المركب التاني لجبانو 
+
+167
+00:14:25,900 --> 00:14:30,260
+بين two as three are اي حد هيتطلع بهذا الشكل 
+
+168
+00:14:30,260 --> 00:14:33,800
+البصير شو هيقول هدول العلاقة بينهم they are
+
+169
+00:14:33,800 --> 00:1
+
+223
+00:18:52,420 --> 00:18:56,880
+اللي بعده المتماثل لو أنا رقمته زي ما أنتوا شايفين
+
+224
+00:18:56,880 --> 00:19:06,100
+بالأزرق صح و لو أنا رقمته بالأحمر صح طيب اللي رقمت
+
+225
+00:19:06,100 --> 00:19:12,660
+بالأزرق كتبت المركب 2R3S23Diclorobutane
+
+226
+00:19:12,660 --> 00:19:17,390
+طب و اللي بده ترقم بالأحمر شو هتكتب؟ الـ 2 ما إحنا 
+
+227
+00:19:17,390 --> 00:19:21,950
+عارفين أن هذه R و هذه S بغض النظر عن الترقيم هتكتب
+
+228
+00:19:21,950 --> 00:19:25,270
+2S3R
+
+229
+00:19:25,270 --> 00:19:30,930
+الآن أي جواب اللي بدنا نعتبره صح الجوابين صح هذا
+
+230
+00:19:30,930 --> 00:19:36,610
+إله اسمين هذا إله اسمين لأنه متماثل وعشانك المدرس
+
+231
+00:19:36,610 --> 00:19:40,250
+اللي بده يصلح بيجيبلكوا هذا المركب ويقولكوا أعطوه
+
+232
+00:19:40,250 --> 00:19:45,680
+اسمهذا الجواب يبدو يعتبره صح وهذا الجواب يبدو
+
+233
+00:19:45,680 --> 00:19:49,600
+يعتبره صح لسبب بسيط أنه مافيه فارق نهائي بين إنكوا
+
+234
+00:19:49,600 --> 00:19:54,280
+ترقموه من هنا أو من هنا الآن نفس الشيء في المركب
+
+235
+00:19:54,280 --> 00:19:58,900
+التاني لما رقمناه بالأزرق واحد اتنين تلاتة اربعة 
+
+236
+00:19:58,900 --> 00:20:05,140
+طب لو واحدة عملت له ترقيم ثاني بالأحمر ايش هتكتبوه؟
+
+237
+00:20:05,140 --> 00:20:11,040
+two R three S الآن اتطلعوا هذا أحد أسماء two S
+
+238
+00:20:11,040 --> 00:20:19,770
+three R هذا أحد أسمائه 2R3S
+
+239
+00:20:19,770 --> 00:20:28,590
+و هذا 2R3S لأن الجزء ببساطة متماثل لأن هذا الجزء
+
+240
+00:20:28,590 --> 00:20:33,490
+ببساطة متماثل بياخد اسمين و هدول الشكلين بيكونوا
+
+241
+00:20:33,490 --> 00:20:38,710
+مركب واحد مش مركبينواضح؟ مركّب واحد وبتسمى
+
+242
+00:20:38,710 --> 00:20:42,110
+بطريقتين، الآن إذا اتفقنا إن هدولة they are the 
+
+243
+00:20:42,110 --> 00:20:46,250
+same compound، بأكتر من طريقة فرجيتكم، اللي بدأ من
+
+244
+00:20:46,250 --> 00:20:49,710
+خلال الإشارات، إنه يلهم نفس الإشارات، أيه؟ يلهم 
+
+245
+00:20:49,710 --> 00:20:56,750
+نفس الإشارات ولا لأ؟ 2R 3S .. 2S 3R .. 2S 3R .. 2S
+
+246
+00:20:56,750 --> 00:21:04,650
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 
+
+247
+00:21:04,650 --> 00:21:05,570
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R 
+
+248
+00:21:05,570 --> 00:21:05,730
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+249
+00:21:05,730 --> 00:21:05,930
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 
+
+250
+00:21:05,930 --> 00:21:06,830
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+251
+00:21:06,830 --> 00:21:14,070
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 
+
+252
+00:21:14,070 --> 00:21:21,840
+2S 3R .. 2S 3R وغيرهم سواء سمّته 2R3S أو 2S3R هو نفس
+
+253
+00:21:21,840 --> 00:21:26,100
+المركب له اسميننفس المركب له اسمين شو اللي عمله 
+
+254
+00:21:26,100 --> 00:21:31,660
+الاسمين التماثل إذا لو أنا بجاجي أسأل ببساطة لو 
+
+255
+00:21:31,660 --> 00:21:35,480
+واحدة على طول بده تعرف إنه عندها أربع مركبات ولا 
+
+256
+00:21:35,480 --> 00:21:40,320
+تلاتة ايش اول ما بده تطلع عليه في الجزء إنه هل يا
+
+257
+00:21:40,320 --> 00:21:44,460
+ترى هذا الجزء اللي عنده فيه تماثل ولا لا اذا فيه
+
+258
+00:21:44,460 --> 00:21:49,620
+تماثل على طول بده تحكي عن كام مركبعن تلاتة مافيش
+
+259
+00:21:49,620 --> 00:21:53,820
+تماثل بده تحكي عن أربع يعني لو مثلاً سألكوا هذا
+
+260
+00:21:53,820 --> 00:22:05,280
+السؤال CH3 CHBR CHCL CH3 كام Cairo Center فيه؟ هن و 
+
+261
+00:22:05,280 --> 00:22:09,200
+هن قبل ما ارسم ايزو مارزو اتعب كام ايزو مارزو 
+
+262
+00:22:09,200 --> 00:22:14,480
+تتوقعوا له أربعة على طول أربعة ليش لانه أنا لو جسمت
+
+263
+00:22:14,480 --> 00:22:18,260
+بين هدولة two chiral centers هذي الذرات مش هي هذي
+
+264
+00:22:18,260 --> 00:22:25,060
+الذرات هنا عندكم H و CL هنا H .. خلاص انتهى واضح؟
+
+265
+00:22:25,060 --> 00:22:31,600
+و هكذاواضح، الان هذا المركب اللي فيه تماثل داخلي، 
+
+266
+00:22:31,600 --> 00:22:37,860
+لو أنتوا بتأمّلوا فيه بعمق شوية، بتحسوا أنه اللي
+
+267
+00:22:37,860 --> 00:22:44,250
+خلّاه يصيرنفس المركب و أقدر أفهم أنه أنا لو إني 
+
+268
+00:22:44,250 --> 00:22:48,650
+اتخيلت مرايا في نص المركب هذا النص اللي فوق صورة 
+
+269
+00:22:48,650 --> 00:22:52,770
+النص اللي تحت في المرأة ولا لأ طلعوا معاك هي ال CL 
+
+270
+00:22:52,770 --> 00:23:00,790
+اقبالها CL ال H H ال مثل مثل اذا one half of the
+
+271
+00:23:00,790 --> 00:23:04,170
+molecule is the mirror image of the other half ولا 
+
+272
+00:23:04,170 --> 00:23:10,660
+لأ هذا النص هو صورة هذا النص في المرأةواضح الكلام؟ 
+
+273
+00:23:10,660 --> 00:23:14,420
+زي الناس اللي بتطلعوا على كروت الشدة إذا عمركوا
+
+274
+00:23:14,420 --> 00:23:18,780
+شفتوها بتشوفوا الرسومات اللي فيها البني آدم هيك او 
+
+275
+00:23:18,780 --> 00:23:24,620
+بصر هيك بعدين هذا 
+
+276
+00:23:24,620 --> 00:23:29,540
+زيه بالظبط .. هذا زيه بالظبط أنه النص هذا .. صورة 
+
+277
+00:23:29,540 --> 00:23:37,180
+النص هذا في المرأةواضح؟ الآن هذا المركب كأنه حقيقة 
+
+278
+00:23:37,180 --> 00:23:42,380
+يحتوي على مركبين كأنه هذا مركب بإمكانكوا تتخيلوه و 
+
+279
+00:23:42,380 --> 00:23:47,540
+هذا مركب ثاني و هاي هم بس متصلين في بعض و من بعض
+
+280
+00:23:47,540 --> 00:23:52,760
+لو اجيت بديت أفكر بعمق شوية هذا لو إنه حطناه لوحده
+
+281
+00:23:52,760 --> 00:23:59,810
+في المرآة بيطلع كايران و إلهrotation وهذا لو حطيته
+
+282
+00:23:59,810 --> 00:24:04,450
+لوحده في المرأة كايرة له rotation طيب لو أخذت
+
+283
+00:24:04,450 --> 00:24:09,530
+مليون جزء من المركب الكلي كده يكون من هذا النص
+
+284
+00:24:09,530 --> 00:24:15,370
+مليون و من هذا النص مليون و المليونين عكس بعض صار
+
+285
+00:24:15,370 --> 00:24:21,750
+هذا بنفسه يشبه إيش؟ Racemic mixture اللي أخدناه 
+
+286
+00:24:21,750 --> 00:24:25,510
+المرة الماضية لما كنا نقولكوا لو كان عندي خليط
+
+287
+00:24:25,510 --> 00:24:31,050
+متساوي من two isomers شو سمّناه؟ Racemic mixture
+
+288
+00:24:31,050 --> 00:24:35,850
+واحد منهم بيلف يمين الثاني شمال قداش بيكون 
+
+289
+00:24:35,850 --> 00:24:41,240
+بالمجمل ال rotation له؟ صفرالـ Racemic mixture
+
+290
+00:24:41,240 --> 00:24:45,460
+بيكون optically active ولا inactive؟ optically 
+
+291
+00:24:45,460 --> 00:24:48,880
+inactive ليش optically inactive؟ لأنه فيه عدد 
+
+292
+00:24:48,880 --> 00:24:54,240
+متساوي من ال enantiomers بيلغوا بعض الآن هذا تمامًا 
+
+293
+00:24:54,240 --> 00:24:58,700
+يشبه الracemic mixture كأنه هاي نص و هاي نص هدول
+
+294
+00:24:58,700 --> 00:25:04,040
+عكس بعض ولا لا؟ واحد R و واحد S الجزء الكبير لو 
+
+295
+00:25:04,040 --> 00:25:09,210
+منه مليون كدهش فيه من هذا؟ و من هذا؟أذا هذا 
+
+296
+00:25:09,210 --> 00:25:13,330
+racemic mixture كأنه بامتياز بس موجود في مركب واحد
+
+297
+00:25:13,330 --> 00:25:17,550
+فهذا المركب بالمجمل بيكون optically active ولا
+
+298
+00:25:17,550 --> 00:25:24,070
+inactive هالمركب العجيب هذا المتماثل اللي موجود ال
+
+299
+00:25:24,070 --> 00:25:28,390
+configuration فيه لنصه عكس التاني اللي نصه صورة 
+
+300
+00:25:28,390 --> 00:25:32,270
+بعض أو صورة نص الثاني في المرآة أخد اسم في ال
+
+301
+00:25:32,270 --> 00:25:36,910
+stereo chemistry بيسميه meso compound أو
+
+302
+00:25:36,910 --> 00:25:42,570
+mesostructureلحظة الآن لو بدنا نقرأ ايش تعريف ال
+
+303
+00:25:42,570 --> 00:25:47,170
+meso compound كل الكلام هذا معرف هنا كل اللي حكينا
+
+304
+00:25:47,170 --> 00:25:53,050
+ال meso compound is an achiral diastereomer of the 
+
+305
+00:25:53,050 --> 00:25:56,450
+compound achiral يعني optically inactive شفنا ليش 
+
+306
+00:25:56,450 --> 00:26:02,470
+أنه achiral و ليش أنه optically inactive رغم أنه في
+
+307
+00:26:02,470 --> 00:26:06,750
+مركز استيريوجينيك كم مركز استيريوجينيك فيه؟ اثنين
+
+308
+00:26:06,750 --> 00:26:11,630
+لكن هو بالمحصلة كايرال ولا اكايرال؟ اكايرال
+
+309
+00:26:11,630 --> 00:26:14,190
+optical and active although it contains 
+
+310
+00:26:14,190 --> 00:26:18,030
+stereogenic centers الان its stereogenic centers 
+
+311
+00:26:18,030 --> 00:26:23,190
+have opposite configurations يعني لازم واحد R
+
+312
+00:26:23,190 --> 00:26:26,970
+والتاني S هذا اللي بيكون ال mesocompound أو نفس 
+
+313
+00:26:26,970 --> 00:26:32,470
+المركب one half of the molecule is The mirror image
+
+314
+00:26:32,470 --> 00:26:37,330
+of the other half اللي في هذه المواصفات بنقول أنه 
+
+315
+00:26:37,330 --> 00:26:43,520
+ميزو كومباوند بيكون مركب واحد مش مش مركبين
+
+316
+00:26:43,520 --> 00:26:46,160
+optically inactive يعني لو جينا سئلناكوا في 
+
+317
+00:26:46,160 --> 00:26:49,360
+الامتحان ميزو كومباوند is optically active or
+
+318
+00:26:49,360 --> 00:26:55,260
+inactive؟ inactive الميزو كومباوند if مركب متماثل
+
+319
+00:26:55,260 --> 00:26:58,680
+لما اجي ارسم عندي two R three R two S three S و
+
+320
+00:26:58,680 --> 00:27:02,880
+two R three S أو الثانية من اللي فيهم بتكون ميزو؟
+
+321
+00:27:02,880 --> 00:27:09,000
+اللي فيها هدول عكس بعض يعني اللي بتكون RR أو SS كل 
+
+322
+00:27:09,000 --> 00:27:13,630
+واحدة منهم فردة in andيعني هذه لو أخذتها لحالها 
+
+323
+00:27:13,630 --> 00:27:19,130
+optically active لو
+
+324
+00:27:19,130 --> 00:27:23,650
+عملت خليط متساوي من هدول الاثنين بيصير عند راسمك 
+
+325
+00:27:24,520 --> 00:27:28,120
+mixture بيصير optical inactive لو أخذت من واحدة 
+
+326
+00:27:28,120 --> 00:27:33,360
+اكتر من الثانية زي ما اتعلمنا بيصير النتج نتاج 
+
+327
+00:27:33,360 --> 00:27:38,600
+التنتين لكن هذا المركب هذا المركب اللي بيميزه أنه
+
+328
+00:27:38,600 --> 00:27:43,100
+واحدة منه R والثانية S اذا أنا لما بتعرف ال mezzo
+
+329
+00:27:43,100 --> 00:27:47,380
+compound في المركب المتماثل اللي بيكون منه واحدة R
+
+330
+00:27:47,380 --> 00:27:53,360
+والثانية S هذا ال mezzo compound والمجموع بيطلع
+
+331
+00:27:54,340 --> 00:27:59,240
+تلات مركبات في النهاية الان لو أتيت سألة طيب يا
+
+332
+00:27:59,240 --> 00:28:02,700
+تورا قولنا احنا اكيد بين هذا و هذا العلاقة they 
+
+333
+00:28:02,700 --> 00:28:06,720
+are enantiomers طب لو أي واحد من هذول ال 
+
+334
+00:28:06,720 --> 00:28:11,520
+enantiomers قرنته بال meso compound اه طلعوا two
+
+335
+00:28:11,520 --> 00:28:18,320
+are نفس الاشي هدوله واضح نفس الشي و three are 
+
+336
+00:28:18,320 --> 00:28:24,870
+three as عكس بعض، إشي نفسه، إشي عكسه، فين VR؟ ده 
+
+337
+00:28:24,870 --> 00:28:30,950
+يستيريو مارسي، فين VR؟ ده يستيريو مارسي بتايع ليه؟
+
+338
+00:28:30,950 --> 00:28:35,490
+بيكفي على موضوع ال two chiral centers الآن في
+
+339
+00:28:35,490 --> 00:28:41,850
+عندكم مجموعة من الأسئلة كيف توجدوا العلاقة بين
+
+340
+00:28:41,850 --> 00:28:47,080
+المركبين حتى لو رسمناهم بطرق مختلفة لاحظوا هذه 
+
+341
+00:28:47,080 --> 00:28:50,980
+المُركّبات مرسومة بطرق مختلفة تماما مرة الـH لفوق
+
+342
+00:28:50,980 --> 00:28:54,820
+و مرة الـH على الجانب لكنهم نفس المُركّب بالمناسبة
+
+343
+00:28:54,820 --> 00:29:00,060
+يعني من ناحية structure أو روابط يعني كاربون
+
+344
+00:29:00,060 --> 00:29:04,280
+الأولى حملة PR و CL و بعدين CH3 و هاي الكاربون 
+
+345
+00:29:04,280 --> 00:29:07,680
+اللي هو حملة PR و CL و بعدين CH3 يعني لو هذا و هذا 
+
+346
+00:29:07,680 --> 00:29:13,090
+كنت بدأ أسميهم one-bromo one-chloro-ethaneمرة
+
+347
+00:29:13,090 --> 00:29:18,290
+ثانية هاي carbon واحد هاي اثنين شو هتسموه وان 
+
+348
+00:29:18,290 --> 00:29:25,500
+برومو وان كلورو إيثان الار هدول الاثنين اللي
+
+349
+00:29:25,500 --> 00:29:29,680
+مرسومين بيدي العلاقة بينهم مش مرسومين بطريقة اللي 
+
+350
+00:29:29,680 --> 00:29:33,180
+بالعين المجردة أشوف أنهم بينيهم مرسومين زي بعض أو 
+
+351
+00:29:33,180 --> 00:29:37,000
+كل واحدة عكس الثانية مرسومين بطرق مختلفة اذا على 
+
+352
+00:29:37,000 --> 00:29:42,200
+طول ماليش حل إلا أحدد ال configuration أحددهم بضوء 
+
+353
+00:29:42,200 --> 00:29:46,880
+هذا طلع R و هذا R then they are the same compound 
+
+354
+00:29:46,880 --> 00:29:53,920
+واضح؟ الآن جيبنالكم مركبين ثانيينكم carbon هذا لو 
+
+355
+00:29:53,920 --> 00:29:59,540
+بدكوا تسموه المركب هذا أطول سلسلة فيه قداش أربعة 
+
+356
+00:29:59,540 --> 00:30:09,160
+واحد اتنين اعلم على أطول سلسلة CH3CCCH3
+
+357
+00:30:09,160 --> 00:30:17,440
+إذا هذا المركب اللي عندي بيوتين شو بيحمل بيوتين؟ ع
+
+358
+00:30:17,440 --> 00:30:21,920
+نمره 2 برومه ع نمره 3 كلور ترقيب واحد عندي عشان 
+
+359
+00:30:21,920 --> 00:30:26,340
+اخلي البروم اقل ما يمكن اتنين برومه ثلاثة ثلاثة 
+
+360
+00:30:26,340 --> 00:30:27,620
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+361
+00:30:27,620 --> 00:30:29,600
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+362
+00:30:29,600 --> 00:30:36,300
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة 
+
+363
+00:30:36,300 --> 00:30:44,220
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة 
+
+364
+00:30:44,220 --> 00:30:50,050
+ثلاثة ثأحدد R و S لما اعملهم بهدوء بتعملهم في
+
+365
+00:30:50,050 --> 00:30:56,550
+البيت هنا two S and two R انبينين عكس بعض three S 
+
+366
+00:30:56,550 --> 00:31:01,850
+and three R the same then they are diastereomers 
+
+367
+00:31:01,850 --> 00:31:05,730
+كذلك 
+
+368
+00:31:05,730 --> 00:31:11,930
+الحال هذا المركب هي أطول سلسلة فيهنطلع عليها واحد
+
+369
+00:31:11,930 --> 00:31:15,810
+اتنين تلاتة اربعة ع تنين برم وع تلاتة كلور وهذه 
+
+370
+00:31:15,810 --> 00:31:20,350
+أطول السلسلة واحد اتنين تلاتة اربعة ع تنين برم وع 
+
+371
+00:31:20,350 --> 00:31:28,710
+تلاتة كلور نحدد له R وS two S two R three S three 
+
+372
+00:31:28,710 --> 00:31:37,170
+R الترقيم من هناك كل شيء عكس بعضين VR انانشومارز
+
+373
+00:31:37,170 --> 00:31:41,670
+اللي بعده نفس الشيء لو عملته بهدوء the same
+
+374
+00:31:41,670 --> 00:31:46,270
+compound واضح؟ the same compound طبعاً انتوا بدكوا
+
+375
+00:31:46,270 --> 00:31:51,970
+تحذروا بس بحالة واحدة لما يكون المركب متماثل و 
+
+376
+00:31:51,970 --> 00:31:57,010
+يطلع عندكم 2R 3S و التالية 2S 3R بدكوا ترجعوا 
+
+377
+00:31:57,010 --> 00:32:00,770
+تفكروا بالإيش بال meso compound اللي هو the same 
+
+378
+00:32:00,770 --> 00:32:04,910
+compoundلو كان المركب متماثل الامثل هذا اللي
+
+379
+00:32:04,910 --> 00:32:09,350
+قدامكم مش متماثل لأنه على جهة بروم و على جهة كلور
+
+380
+00:32:09,350 --> 00:32:15,150
+دائمًا التفكير وين بده يكون قف و أفكر لما يكون فيه
+
+381
+00:32:15,150 --> 00:32:19,490
+تماثل داخلي اذا في تماثل داخلي و طلع عندكم ال
+
+382
+00:32:19,490 --> 00:32:26,150
+configurations في المتماثل إذا طلع عندكم R و S و 
+
+383
+00:32:26,150 --> 00:32:31,390
+جبالها S و R they are the same compound هذا الحكي
+
+384
+00:32:31,390 --> 00:32:37,610
+وين بيكون في المركبات المتماثلة بيكون المركب فعلا
+
+385
+00:32:37,610 --> 00:32:44,630
+ميزو لما أحكي عن مركبين ر أس و أس و ر طلعوا معاكم
+
+386
+00:32:44,630 --> 00:32:51,270
+if مركب فيه تماثل داخلي بنقول عنهم they are the 
+
+387
+00:32:51,270 --> 00:32:56,130
+same compound أو بنقول this is a mezzo compound 
+
+388
+00:32:56,130 --> 00:33:01,530
+وبيكون طبعًا opticallyinactive بيكون optically 
+
+389
+00:33:01,530 --> 00:33:05,810
+inactive الان
+
+390
+00:33:05,810 --> 00:33:13,230
+لو اجينا لتفاعلات أو التفاعلات المرتبطة بال stereo
+
+445
+00:37:55,590 --> 00:38:00,410
+بترتفع في ذرة هيدروجين بيصيروا هدولة التلاتة
+
+446
+00:38:00,410 --> 00:38:06,520
+planar في مستوى واحد يعني لو انا بدي اجي اتخيلليش
+
+447
+00:38:06,520 --> 00:38:10,780
+تم التفاعل على الجهتين؟ لما تم التفاعل على
+
+448
+00:38:10,780 --> 00:38:18,200
+الجهتين؟ ممكن ايه بسرعة اريكم باستعمال ال models و
+
+449
+00:38:18,200 --> 00:38:27,360
+بأمل انها ال models بتخدمنا اتخيلوا
+
+450
+00:38:27,360 --> 00:38:33,500
+معنا لو اتخيلنا ان في عندنا CH3 ال CH3 نتخيلهاذرة
+
+451
+00:38:33,500 --> 00:38:39,550
+كربون صمرة CH3 تمام؟ لما أشيل H بيبقى عندى كام
+
+452
+00:38:39,550 --> 00:38:44,650
+هيدروجين؟ واحدة و إيش بيبقى عندى؟ مجموعة ال إفل
+
+453
+00:38:44,650 --> 00:38:48,770
+لسه ماجيبتش ال chlorine أنا بدي بهذا كيف بعمل
+
+454
+00:38:48,770 --> 00:38:52,830
+الإبدال؟ بشيل الهيدروجينة في الأول و بعدين بحط
+
+455
+00:38:52,830 --> 00:38:57,250
+بدالها chlorine فدولة كام رابطة حوالين الكربون؟
+
+456
+00:38:57,250 --> 00:38:58,910
+أربعة أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+457
+00:38:58,910 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+458
+00:38:59,790 --> 00:39:06,750
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة
+
+459
+00:39:07,360 --> 00:39:13,760
+بمشي الحال هاي هذا صار بهذا الشكل بالظبط طلعوا في
+
+460
+00:39:13,760 --> 00:39:20,740
+مجموعة مثل و H و إثل و ال H الأخيرة شيلناها
+
+461
+00:39:20,740 --> 00:39:24,240
+رفعناها الآن بدنا نجيب ال chlorine تتفاعل
+
+462
+00:39:26,450 --> 00:39:29,650
+هذه الـ Intermediate للحظة برفعت الـ H الأولى
+
+463
+00:39:29,650 --> 00:39:33,330
+planar في مستوى واحد الكلور بإمكانها تيجي تهاجم
+
+464
+00:39:33,330 --> 00:39:37,470
+عليها من هنا و هدولا بتعجوا حلو ميك او من هنا
+
+465
+00:39:37,470 --> 00:39:43,910
+طالما انها planar في فرق ان الكلور هي جاية من بعيد
+
+466
+00:39:43,910 --> 00:39:49,130
+بفرق عندها انها تمشي من هنا او من هنا اطلع معي
+
+467
+00:39:49,130 --> 00:39:52,670
+شايفين هدول الممرين اللي في القاعة لو انا بدي اروح
+
+468
+00:39:52,670 --> 00:39:59,700
+لاخر نقطةبإمكاني أمشي من هنا و من هنا بشكل متساوي
+
+469
+00:39:59,700 --> 00:40:04,520
+ولا لأ؟ ماعندي مشكلة، بدي أروح لآخر نقطة وهي عندي
+
+470
+00:40:04,520 --> 00:40:08,240
+مصارين متكافئت كذلك الحال، هذا planar بدي تيجي
+
+471
+00:40:08,240 --> 00:40:12,200
+اكلور من برا تتفاعل عليه، ترد تعمل المجموعة
+
+472
+00:40:12,200 --> 00:40:16,180
+الرابعة إذا أتيت من هنا عملة انانشومر و إذا أتيت من
+
+473
+00:40:16,180 --> 00:40:20,660
+هنا عملة التاني الان من ناحية الاحتمالات متساوية
+
+474
+00:40:20,660 --> 00:40:25,440
+تماما و لذلك يظهر عندي راسيمك ميكسشر يعني يظهر
+
+475
+00:40:25,440 --> 00:40:30,220
+الاتنين و يظهرون بنسب متساوية يظهر الاتنين و
+
+476
+00:40:30,220 --> 00:40:34,100
+يظهرون بنسب متساوية فبصير المحصلة ان ال generation
+
+477
+00:40:34,100 --> 00:40:42,710
+of a chiral center produces راسيمك ميكسشرواضح؟ ال
+
+478
+00:40:42,710 --> 00:40:46,690
+generation of a chiral center produces a racemic
+
+479
+00:40:46,690 --> 00:40:53,110
+mixture الان لو قلنا بدل racemic mixture equal
+
+480
+00:40:53,110 --> 00:40:59,740
+number of enantiomers أكيد صح .. أكيد صح generation
+
+481
+00:40:59,740 --> 00:41:02,520
+of a chiral center produces racemic mixtures
+
+482
+00:41:02,520 --> 00:41:10,660
+لاحظوا هذه الجملة بالنسبة للكيميا ما بين الكيميا
+
+483
+00:41:10,660 --> 00:41:15,480
+اللي بيصنعوها البشر و ما بين خلق الله سبحانه
+
+484
+00:41:15,480 --> 00:41:21,070
+وتعالى بتعمل فرق كبير جدااليوم لما انا باجي في
+
+485
+00:41:21,070 --> 00:41:26,450
+المختبر بده احضر مركب و اعمل chiral center انا
+
+486
+00:41:26,450 --> 00:41:31,290
+مابتحكمش في الاحتمالات بطلع عندى خليط متساوي و
+
+487
+00:41:31,290 --> 00:41:36,090
+بعدين اتعب و افصله و هذا السبب ربما في انه في دوة
+
+488
+00:41:36,090 --> 00:41:41,360
+مثل الثاليدواميد كان بيطلع الخليطالمتساوي ال R و
+
+489
+00:41:41,360 --> 00:41:45,860
+ال S لمنهم واحد مفيد و واحد ضار و عمل مشاكل كتير
+
+490
+00:41:45,860 --> 00:41:50,160
+كل ما بشغل في المختبر المختبر بطلعلي خليط من
+
+491
+00:41:50,160 --> 00:41:52,940
+المركبين اذا مش عندى chiral center انا بدي اعمله
+
+492
+00:41:52,940 --> 00:41:57,460
+بطلعلي .. بطلعلي ايش؟ racemic mixture الان في
+
+493
+00:41:57,460 --> 00:42:02,570
+الطبيعة فيه انزيماتالانزيمات كأنها بتاخد بإيدي
+
+494
+00:42:02,570 --> 00:42:05,850
+المجموعة اللي جاية بالظبط بداخلها من جهة واحدة
+
+495
+00:42:05,850 --> 00:42:10,030
+ولذلك المنتجات الطبيعية بيطلع منها بس one in a
+
+496
+00:42:10,030 --> 00:42:16,750
+number هذا خلقههذا خلق الله يعني انا لما شغلة كون
+
+497
+00:42:16,750 --> 00:42:21,210
+بتحضرها الانزيمات و بتتحضر جوا الجسم بتلاقوا بيطلع
+
+498
+00:42:21,210 --> 00:42:26,330
+منها بس واحد لما اجي انا اعيد التفاعل بالمختبر و
+
+499
+00:42:26,330 --> 00:42:30,110
+بدون انزيمات و بكذا بيطلع عندى خليط متساوي من
+
+500
+00:42:30,110 --> 00:42:34,830
+التنين ولذلك اللى بده مركبات نقية يعني بده one in
+
+501
+00:42:34,830 --> 00:42:39,750
+one شمر ايش اسهل طريقة يعملها؟ ياخدها من مصادرها
+
+502
+00:42:39,750 --> 00:42:44,590
+الطبيعية اذا كانت تحضر في الطبيعةطبعا إذا كانت لا
+
+503
+00:42:44,590 --> 00:42:51,850
+تحضر في الطبيعة بده يجعب هذه المشكلة و يطلع عنده
+
+504
+00:42:51,850 --> 00:42:56,450
+خليط من التنين عشان ايه كده في الكيميا بيسموه ايش
+
+505
+00:42:56,450 --> 00:43:02,990
+Symmetric Synthesis Symmetric Synthesis ايش معنى
+
+506
+00:43:02,990 --> 00:43:08,350
+Symmetric انه بيطلع خليط متمافل من التنين جد بعض و
+
+507
+00:43:08,350 --> 00:43:15,290
+بعدين يقعد ايش يعمليفصل فيهم الآن بدأوا من جديد
+
+508
+00:43:15,290 --> 00:43:21,030
+يستعملوا طرق حديثة في ال synthesis و يضيفوا عوامل
+
+509
+00:43:21,030 --> 00:43:25,330
+حفازة اللي تخلى واحد من هدول يطلع بنسبة اكتر من
+
+510
+00:43:25,330 --> 00:43:30,490
+التانية او يكاد يكون يطلع نقي وجدتها اذا طلعوا مش
+
+511
+00:43:30,490 --> 00:43:35,790
+متساويات شو بدى اسم ال synthesis Asymmetric
+
+512
+00:43:35,790 --> 00:43:40,010
+synthesis واضح؟ يعني الـ symmetric synthesis بتطلع
+
+513
+00:43:40,010 --> 00:43:44,810
+الخليط متساوي الآن إذا صرت أضيف عوامل حفازة بطرق
+
+514
+00:43:44,810 --> 00:43:49,290
+معينة بتحذيرات بصير أشتغل ايش؟ asymmetric
+
+515
+00:43:49,290 --> 00:43:52,910
+synthesis اليوم اللي منكم بده تدرس كيميا وبعدين
+
+516
+00:43:52,910 --> 00:43:57,120
+تقول أنا بدي أخد جائزة نوبل في الكيمياBye Bye
+
+517
+00:43:57,120 --> 00:44:01,260
+Asymmetric Synthesis بدا تشتغل على ايش؟ Asymmetric
+
+518
+00:44:01,260 --> 00:44:05,420
+Synthesis تصير تتعلم كتير تضيف عوامل حفازة
+
+519
+00:44:05,420 --> 00:44:12,040
+بمواصفات معينة تخلي التفاعل تطلع واحدمايطلعش
+
+520
+00:44:12,040 --> 00:44:16,200
+التاني او طلع واحد مثلا بنسبة 90% و التاني بنسبة
+
+521
+00:44:16,200 --> 00:44:20,800
+10% على سبيل المثال و كل ما جدت تطلع واحد تماما و
+
+522
+00:44:20,800 --> 00:44:26,500
+تلغي التاني كل ما كانت تمثل ايش نجاح كبير في الشغل
+
+523
+00:44:26,500 --> 00:44:31,720
+افهمنا اذا المشكلة ما بين الطبيعة و ما بين المختبر
+
+524
+00:44:31,720 --> 00:44:36,380
+المختبر هو وضع الطبيعيبطلّع لي خليط الطبيعة بوضعها
+
+525
+00:44:36,380 --> 00:44:42,120
+الطبيعي بطلّع واحد الان العالم بيسعوا نحو ايش؟ ان
+
+526
+00:44:42,120 --> 00:44:45,960
+يقتربوا من الطبيعة انهم يقدروا يطلعوا واحد و لو
+
+527
+00:44:45,960 --> 00:44:51,120
+بنسبة كبيرة في ما يسمى بالعلم ايش؟ asymmetric
+
+528
+00:44:51,120 --> 00:44:55,620
+synthesis بس بالتأكيد هذا الموضوع كتير متطور
+
+529
+00:44:55,620 --> 00:44:59,860
+بالنسبة لطالب organic يعني ما لم تتخصصوا كيميا مش
+
+530
+00:44:59,860 --> 00:45:02,460
+هتشتغلوا فيه بنكمل ان شاء الله في مرات 
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4753652e2218d0884eeb33c0ae73abc7219b9989
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_postprocess.srt
@@ -0,0 +1,2120 @@
+1
+00:00:20,690 --> 00:00:24,750
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry
+
+2
+00:00:24,750 --> 00:00:29,730
+ربما المرة الماضية نوّهنا من خلال أنفلة تطبيقية من
+
+3
+00:00:29,730 --> 00:00:36,970
+خلال أهمية فهم ال stereo isomers في الحياة العملية
+
+4
+00:00:36,970 --> 00:00:42,990
+أن هذا موضوع مهم ولذلك شوية بنظل نتوسع فيه بعد ما
+
+5
+00:00:42,990 --> 00:00:46,830
+أخدنا المركبات اللي فيها one chiral center قولنا
+
+6
+00:00:46,830 --> 00:00:51,610
+ال one chiral center بيعتق فقطtwo isomers بعد ذلك
+
+7
+00:00:51,610 --> 00:00:56,690
+إذا زاد العدد بيبدأوا يزيدوا ال isomers طبعا بيحكم
+
+8
+00:00:56,690 --> 00:01:00,890
+الأمر المعادلة two to the n لكن ال two to the n
+
+9
+00:01:00,890 --> 00:01:05,230
+هذا أقصى عدد ممكن من ال isomers في كل الأحوال ممكن
+
+10
+00:01:05,230 --> 00:01:10,290
+يكون العدد أقل من هيك وقلنا هنعطي مثال على العدد
+
+11
+00:01:10,290 --> 00:01:15,330
+الأقصى ومثال على وانتش العدد بيصير أقل في حالة ما
+
+12
+00:01:15,330 --> 00:01:20,620
+عندنا two chiral centersبدأنا في مثال كنا عادة
+
+13
+00:01:20,620 --> 00:01:25,140
+ناخده على أنه مثال بسيط يعني الفكره مركب واحد لما
+
+14
+00:01:25,140 --> 00:01:29,620
+نيجي نقول two three dichloro بنتين بالفكره مركب
+
+15
+00:01:29,620 --> 00:01:33,640
+واحد لكن لما بنيجي نتطلع على موقع اتنين وعلى موقع
+
+16
+00:01:33,640 --> 00:01:39,410
+تلاتةبنلاحظ ان الاتنين they are chiral centers
+
+17
+00:01:39,410 --> 00:01:42,750
+وبناء على ذلك بنبدأ نتوقع انه كام مركبة بيصير
+
+18
+00:01:42,750 --> 00:01:48,890
+عندنا اربع مركبات جربنا نرسمهم من خلال انه نتخيل
+
+19
+00:01:48,890 --> 00:01:52,010
+مثلا بدنا ناخد السلسلة الكربونية بهذا الشكل يعني
+
+20
+00:01:52,010 --> 00:01:56,970
+الخمس كربونات واحد اتنين تلاتة و الاثلاربعة خمسة
+
+21
+00:01:56,970 --> 00:02:01,390
+CH2 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+22
+00:02:01,390 --> 00:02:06,770
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+23
+00:02:06,770 --> 00:02:08,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+24
+00:02:08,170 --> 00:02:08,950
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+25
+00:02:08,950 --> 00:02:09,750
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+26
+00:02:09,750 --> 00:02:10,270
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+27
+00:02:10,270 --> 00:02:11,790
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+28
+00:02:11,790 --> 00:02:13,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+29
+00:02:13,190 --> 00:02:23,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+30
+00:02:23,190 --> 00:02:27,670
+CH3 CHيعني ال R عكسة S ال R عكسة S كلام منطقي الان
+
+31
+00:02:27,670 --> 00:02:32,110
+لو جينا نطلع على المركب الثاني two R three S هذا
+
+32
+00:02:32,110 --> 00:02:37,870
+عكسه ال R اقبلها S ال S اقبلها R لأنه دائما صورة
+
+33
+00:02:37,870 --> 00:02:43,590
+بعض في المرأة بتعني التعاكس التام فلو احنا سألنا
+
+34
+00:02:43,590 --> 00:02:48,170
+ايش العلاقة بين واحد و اتنين they are enantiomersو
+
+35
+00:02:48,170 --> 00:02:52,290
+بيصير مفهوم عندنا ان اي مركبة لما نقول عنهم in
+
+36
+00:02:52,290 --> 00:02:58,650
+anchors بدتكون اشاراتهم عكس بعض الان طبعا انتوا
+
+37
+00:02:58,650 --> 00:03:02,390
+بالنظر بتقولوا صورة بعض في المرأة غير متطابقة لكن
+
+38
+00:03:02,390 --> 00:03:08,390
+ماتنسوش شغلة ان انا بإمكاني ارسم
+
+39
+00:03:09,150 --> 00:03:13,850
+المُركّب بطرق مختلفة بحيث أنه انتوا بمجرد النظر
+
+40
+00:03:13,850 --> 00:03:18,430
+البسيط ما تقدروش تتاخدوا قرار من النظر وجهة القرار
+
+41
+00:03:18,430 --> 00:03:21,750
+الأكيد بتقدروا تتاخدوا من إيش في علاقة بين
+
+42
+00:03:21,750 --> 00:03:29,110
+المُركّبين من قيم A و S خليني أؤكد الفكرة هذه لو
+
+43
+00:03:29,110 --> 00:03:34,310
+فقط أنا بدي أشغل معكم على مُركّب في one chiral
+
+44
+00:03:34,310 --> 00:03:40,470
+centerلو رسمت منه شكلين شو الاحتمالات المتوقعين
+
+45
+00:03:40,470 --> 00:03:43,610
+لما يكون عندي one chiral center؟ يا بده يكون
+
+46
+00:03:43,610 --> 00:03:48,910
+المركب نفسه رسمه بطريقتين مختلفة يا بده يكون in
+
+47
+00:03:48,910 --> 00:03:51,410
+anchormers ماعندي احتمال تاني
+
+48
+00:03:53,870 --> 00:04:01,450
+أخذ بسرعة عشوائيا هاي مركّب CH3CLPR وهي مركّب كتبت
+
+49
+00:04:01,450 --> 00:04:08,010
+هنا ال PR وهنا ال H وهنا ال CL وهنا ال CH3 لاحظوا
+
+50
+00:04:08,010 --> 00:04:12,610
+هدول المركّبين لو سألتكم ما العلاقة بينهما اللي
+
+51
+00:04:12,610 --> 00:04:16,030
+بده تيجي تتطلع تشوف أي شيء بالنظر و المرايا و
+
+52
+00:04:16,030 --> 00:04:22,100
+بنطبقه و مابنطبقوش حتىمش هتقدر، لأنه أنا أرسمهم
+
+53
+00:04:22,100 --> 00:04:25,640
+بطرق مختلفة، ماحدش بيمنعني أرسمهم بطرق مختلفة،
+
+54
+00:04:25,640 --> 00:04:31,700
+الآن أسهل شيء أن أحدد لكل مركب R أو S، الآن إذا
+
+55
+00:04:31,700 --> 00:04:35,500
+هذا طلع R و هذا R، معنى ذلك نفس المركب مرسوم بطرق
+
+56
+00:04:35,500 --> 00:04:40,800
+مختلفة، S و S نفس المركبإذا هذا R و هذا S, they
+
+57
+00:04:40,800 --> 00:04:44,140
+are enantiomers إذا هذا S و هذا R, they are
+
+58
+00:04:44,140 --> 00:04:48,260
+enantiomers هيكا بيكون أسهل طريقة أن أعملهم ولذلك
+
+59
+00:04:48,260 --> 00:04:54,380
+لو بدي أجي أطلع لهذا أقل مجموع ال H ب RCLCH3 من
+
+60
+00:04:54,380 --> 00:05:00,660
+بين R S لأن هذا ال H للأمام الآن لو بدي أطلع
+
+61
+00:05:00,660 --> 00:05:12,780
+المركب الثاني ب R CL SCH3 بين R مرة تانية وبنخليها
+
+62
+00:05:12,780 --> 00:05:18,100
+R لأن ال H للخلف هدول الانشو مارس طالما واحد قسي
+
+63
+00:05:18,100 --> 00:05:21,380
+التاني R إذا we are in ancho mars فالانشو مارس
+
+64
+00:05:21,380 --> 00:05:25,040
+دايما عكس بعض الان لو عندكوا خمسة كايرة ال centers
+
+65
+00:05:25,040 --> 00:05:29,520
+مش واحدإيش بتكون في الخمسة يكونوا عشان يكونوا
+
+66
+00:05:29,520 --> 00:05:35,300
+مركبين انانشومارز؟ كل واحد عكس التاني زي أنا باجف
+
+67
+00:05:35,300 --> 00:05:38,420
+قدام المرايا، الإيدين عكس بعض، الوش عكس بعض، البطن
+
+68
+00:05:38,420 --> 00:05:42,060
+عكس بعض، الرجلين عكس بعض، كل شيء بيكون عكس التاني،
+
+69
+00:05:42,060 --> 00:05:45,120
+يعني لو عندي ان شاء الله عشرين Cairo Center في
+
+70
+00:05:45,120 --> 00:05:49,600
+مركب، الانانشومارز تبعه، العشرين المقابلات بيكونوا
+
+71
+00:05:49,600 --> 00:05:56,300
+عكسهم، لو واحدة منهم اختلتببطلوا in anchormers على
+
+72
+00:05:56,300 --> 00:05:59,840
+طول ببطلوا صورة بعض في المرآة إذا بطلوا صورة بعض
+
+73
+00:05:59,840 --> 00:06:04,700
+في المرآة، شو بدوا يصيروا؟ ديستيريومارز، تنسوش إن
+
+74
+00:06:04,700 --> 00:06:08,740
+احنا عرفنا الديستيريومارز، they are non-mirror
+
+75
+00:06:08,740 --> 00:06:12,580
+image in anchormers ولذلك لو أنا سألت العلاقة بين
+
+76
+00:06:12,580 --> 00:06:20,780
+هدول، خلّينا نوضحها باسم RS عكس بعضعكس بعض اذا
+
+77
+00:06:20,780 --> 00:06:24,580
+they are enansimals واضح؟ الان لو سئلت هدول
+
+78
+00:06:24,580 --> 00:06:33,560
+الاتنين RS SR عكس طلع عليهم R اقبلها S S اقبلها R
+
+79
+00:06:33,560 --> 00:06:39,320
+عكس بعض they are enansimals الان لو اجيت اخدت مثلا
+
+80
+00:06:39,320 --> 00:06:49,160
+المركب واحد مع تلاتة اتطلعوا R وRهدولا متل بعض و
+
+81
+00:06:49,160 --> 00:06:56,860
+are و us عكس بعض هل هدولا عكس بعض بالكامل؟ لأ
+
+82
+00:06:56,860 --> 00:07:01,500
+هدولا متل بعض بالكامل؟ لأ مالو كانوا عكس بعض
+
+83
+00:07:01,500 --> 00:07:04,560
+بالكامل يعني كل نقطة عكس التانية they are
+
+84
+00:07:04,560 --> 00:07:10,000
+enantiomers الان لو كل نقطة زي التانية they are
+
+85
+00:07:10,000 --> 00:07:14,600
+the same compoundلو كل نقطة زي التانية هو نفس
+
+86
+00:07:14,600 --> 00:07:20,760
+المُركّب الـ R إيش زي بعض و إيش عكس بعض بطلوا صورة
+
+87
+00:07:20,760 --> 00:07:24,400
+بعض في المرأة أو بطلوا نفس المُركّب إيش هيصفه؟ ده
+
+88
+00:07:24,400 --> 00:07:28,180
+الـ Stereomers إذا لما بنيجي نتطلع إنه بدنا نفهم
+
+89
+00:07:28,180 --> 00:07:32,260
+العلاقة بين مُركّبين من خلال الرموز هنقول إنه
+
+90
+00:07:32,260 --> 00:07:36,260
+عندنا تلت احتمالات في حالة ما عندي أكتر من chiral
+
+91
+00:07:36,260 --> 00:07:40,600
+center لحظة لما كان عندي one chiral centerبدون ما
+
+92
+00:07:40,600 --> 00:07:44,080
+أعمل R و S بقولكوا عندي احتمالين يا بدهم يكونوا
+
+93
+00:07:44,080 --> 00:07:50,120
+نفس المركب R R S S يا بدهم يكونوا Enansi و Mars S
+
+94
+00:07:50,120 --> 00:07:54,840
+R أو R S الان لو كان عندي more than one chiral
+
+95
+00:07:54,840 --> 00:07:57,960
+center عندي تلت احتمالات الاحتمال الاول بدهم
+
+96
+00:07:57,960 --> 00:08:03,440
+يكونوا Enansi و Mars كل شيء عكس بعض الاحتمال
+
+97
+00:08:03,440 --> 00:08:09,150
+التاني انهم يكونوا نفس المركب كل شيء نفسهزي بعض طب
+
+98
+00:08:09,150 --> 00:08:12,950
+لو طلع شيء عكس و شيء زي بعض وجدت دي R ده يستيريو
+
+99
+00:08:12,950 --> 00:08:18,370
+مارس لحظوا الآن لو اجيت على واحد و تلاتة R و S عكس
+
+100
+00:08:18,370 --> 00:08:23,670
+بعض R و R زي بعض اذا هدولة صورت بعض في المرقاة لأ
+
+101
+00:08:23,670 --> 00:08:28,530
+نفس المركب لأ ر ده يستيريو مارس اذا واحد و تلاتة
+
+102
+00:08:28,530 --> 00:08:31,970
+ده يستيريو مارس لو طبقته مرة تانية على واحد و
+
+103
+00:08:31,970 --> 00:08:39,700
+أربعة مثلا ما العلاقة بينهم Rو S عكس بعض، هم
+
+104
+00:08:39,700 --> 00:08:47,540
+لاحظين؟ R و R نفس بعض، they are diastereomers لو
+
+105
+00:08:47,540 --> 00:08:52,720
+إجينا اتطلعنا على اتنين و تلاتة،
+
+106
+00:08:52,720 --> 00:09:02,010
+لاحظوا؟ S و Rعكس بعض السؤاس زي بعض كذلك الحال لو
+
+107
+00:09:02,010 --> 00:09:08,070
+اتطلعت اتنين اربع السؤاس نفس الاشي السؤاد عكس بعض
+
+108
+00:09:08,070 --> 00:09:13,230
+they are diastereomers واضح؟صار عندى نوع تانى من
+
+109
+00:09:13,230 --> 00:09:17,590
+الدياستيريو مارز جاي من وين جاي من المركبات فيها
+
+110
+00:09:17,590 --> 00:09:20,910
+chiral centers يعني احنا اول ما أخدنا تعريف
+
+111
+00:09:20,910 --> 00:09:25,270
+الدياستيريو مارز قولنا كل شيء مش صورة بعض في
+
+112
+00:09:25,270 --> 00:09:29,500
+المرقاة they are diastereomarsالأمثلة الكيميائية
+
+113
+00:09:29,500 --> 00:09:33,820
+الأولى اللى أخدناها شو هي الـ Cis والـ Trans أو
+
+114
+00:09:33,820 --> 00:09:37,300
+الـ Z والـ E they are diastereomers الآن بيجينا
+
+115
+00:09:37,300 --> 00:09:40,900
+أمثلة تانية لما يكون عندى more than one chiral
+
+116
+00:09:40,900 --> 00:09:45,160
+center هذه الأمثلة بتقول القاتل انه لو كان في عندى
+
+117
+00:09:45,160 --> 00:09:51,530
+مركبين في الإشارات تبعتهممش زي بعض تماما، مش نفس
+
+118
+00:09:51,530 --> 00:09:54,650
+المُركّب، ولا Inansiomers و they are
+
+119
+00:09:54,650 --> 00:10:00,010
+stereoisomers، إيش هيصفهم؟ ديستيريو مارس، واضح؟
+
+120
+00:10:00,010 --> 00:10:05,270
+وبهيك أخدنا إن الديستيريو مارس بكم ما كان، بنشوفهم
+
+121
+00:10:05,270 --> 00:10:11,460
+بالكيميامكالين بال CC trans او ZE و بال chiral
+
+122
+00:10:11,460 --> 00:10:15,680
+compounds او بال stereo chemistry لما يكون عندى
+
+123
+00:10:15,680 --> 00:10:21,440
+اكتر من chiral center بشرط انه ننتبه ل ROS
+
+124
+00:10:21,440 --> 00:10:27,760
+بالطريقة اللى اتكلمنا فيها الان طالما ان هدولةالهم
+
+125
+00:10:27,760 --> 00:10:31,760
+إشارات مختلفة فى كام مركب عندى لتو ثري دايكلورو
+
+126
+00:10:31,760 --> 00:10:36,180
+بنتين أربعة هى رموزهم اللى بدى تروح تشتريهم من
+
+127
+00:10:36,180 --> 00:10:39,800
+السوق هتلاقيهم أربعة مركبات الآن احنا قولنا ممكن
+
+128
+00:10:39,800 --> 00:10:46,760
+يكون العدد أقل ناخد مثالهذا المثال 2,3
+
+129
+00:10:46,760 --> 00:10:51,800
+-dichlorobutane قال ذرة كربون واحدة يعني لو انا
+
+130
+00:10:51,800 --> 00:10:56,080
+رسمت هاي كربون تنتين تلاتة اربعة اذا المركب اللي
+
+131
+00:10:56,080 --> 00:11:02,100
+عندى ايش بيوتين واضح لاحظوا ايش بيفرق يعني كتير
+
+132
+00:11:02,100 --> 00:11:09,120
+لبيوتين عنالبنتين لو انا مجرد ان كتبت كتابة مثل
+
+133
+00:11:09,120 --> 00:11:17,800
+CH3 CHCl CHCl CH3 عارفين شو بيفرق؟ لو انا اتيت بين
+
+134
+00:11:17,800 --> 00:11:20,840
+هدولة الـ chiral centers التنين الكاربونز اللي
+
+135
+00:11:20,840 --> 00:11:26,760
+حاملة كلور و جسمت المركب من النصتطلعوا هنا إيش
+
+136
+00:11:26,760 --> 00:11:33,460
+اللي موجود Carbon حاملة HCl و بعدها CH3 و هنا
+
+137
+00:11:33,460 --> 00:11:39,240
+Carbon حاملة HCl و بعدها CH3 إذا هذا المركب صار
+
+138
+00:11:39,240 --> 00:11:44,460
+مركب متماثل قبل شوية لما كنت .. أو من هنا على هذا
+
+139
+00:11:44,460 --> 00:11:49,800
+الشكل أجسم زي هيك تطلعوا كأعداد ذراتماذا عندكم
+
+140
+00:11:49,800 --> 00:11:54,980
+هنا؟ كاربون حاملة HCl وCH3 وهنا كاربون حاملة HCl
+
+141
+00:11:54,980 --> 00:12:01,860
+وCH3 فعدد الذرات اللي بهذا الاتجاه هو نفسه عدد
+
+142
+00:12:01,860 --> 00:12:05,760
+الذرات اللي بهذا الاتجاه فهذا الكاربون بيحمل نوع
+
+143
+00:12:05,760 --> 00:12:10,380
+من التماثل هذا الكلام في المثال السابق ماكانش لما
+
+144
+00:12:10,380 --> 00:12:16,160
+كنتوا تحطوا خط هنابين ال two chiral centers عدولي
+
+145
+00:12:16,160 --> 00:12:22,780
+كل الذرات اللي هتشومها C وH وCL و CH3 و هنا CH وCL
+
+146
+00:12:22,780 --> 00:12:29,460
+و بعدها CH2 CH3 إذا هل هذا النص زي هذا النص لأ في
+
+147
+00:12:29,460 --> 00:12:34,910
+حالة البيوتينأ لبيوتين في تماثل داخلي بين ال two
+
+148
+00:12:34,910 --> 00:12:39,790
+chiral centers يعني المركب سيماتريك الآن لو إجينا
+
+149
+00:12:39,790 --> 00:12:44,310
+جربنا نرسم ال isomers بنفس الطريقة اللي اتعلمناها
+
+150
+00:12:44,310 --> 00:12:51,270
+سابقا يعني أجي أحط تنتين كلور عكس بعض و صورتهم في
+
+151
+00:12:51,270 --> 00:12:54,810
+المرأة و تنتين كلور على جهة واحدة و صورتهم في
+
+152
+00:12:54,810 --> 00:13:02,210
+المرأة و بعدين أحدد R و Sلاحظوا هذه الرسمة تماما
+
+153
+00:13:02,210 --> 00:13:06,510
+هي نسخ و لصق من الرسمة السابقة بس بدل ما كنا
+
+154
+00:13:06,510 --> 00:13:12,890
+كاتبين هنا اثل كتبنا مثل واضح؟ و لذلك انتوا الان
+
+155
+00:13:12,890 --> 00:13:20,310
+كام مركب بتشوفه؟مازالتوا بتشوفوا أربع مركبات
+
+156
+00:13:20,310 --> 00:13:26,150
+للوهلة الأولى لكن لو نظرنا بعمق لهدولة الأربع
+
+157
+00:13:26,150 --> 00:13:32,130
+مركبات هلاحظ ان هذا 2R3R و هذا 2S3S
+
+158
+00:13:34,300 --> 00:13:40,660
+عكس بعض هتيجوا تستنتجوا انهم انانشومارز فش اننا
+
+159
+00:13:40,660 --> 00:13:45,160
+خلاف الآن لما بتيجوا تطلع على المركبين التانيين
+
+160
+00:13:45,160 --> 00:13:49,140
+وخلونا نقول .. نقولنا الترقيم واحد اتنين تلاتة
+
+161
+00:13:49,140 --> 00:13:55,720
+اربعة واحد اتنين تلاتة اربعة و هيناخد واحدة بس
+
+162
+00:13:55,720 --> 00:14:01,560
+نأكد هي ال CL نمرة واحدوهذه ال carbon الحاملة Cl2
+
+163
+00:14:01,560 --> 00:14:09,860
+و CH3 بين S كتبناها R وهذه لو بدنا نتطلع عليها 1 2
+
+164
+00:14:09,860 --> 00:14:16,300
+Cl بعدين carbon حاملة Cl بعدين CH3 Cl بعدين carbon
+
+165
+00:14:16,300 --> 00:14:21,100
+حاملة Cl بعدين CH3 بين R كتبنا S إذا هيك مظبوطين
+
+166
+00:14:21,100 --> 00:14:25,900
+هدولة two R three Sلو اعملنا المركب التاني لجبانو
+
+167
+00:14:25,900 --> 00:14:30,260
+بين two as three are اي حد هيتطلع بهذا الشكل
+
+168
+00:14:30,260 --> 00:14:33,800
+البصير شو هيقول هدول العلاقة بينهم they are
+
+169
+00:14:33,800 --> 00:14:36,760
+enantiomers الان بنقول لأ they are the same
+
+170
+00:14:36,760 --> 00:14:42,420
+compound هتبدو يصير عندكم مشكلة ليش لأنه هتقولوا
+
+171
+00:14:42,420 --> 00:14:47,540
+انت لسه توت و التصوير شاهد علينا كمان بتقول انه
+
+172
+00:14:47,540 --> 00:14:55,020
+اذا كل شيء عكس بعضهthey are enantiomers هاي مثال و
+
+173
+00:14:55,020 --> 00:14:59,320
+فيها دول عكس بعض لكن أنا قاعد بقول عنهم they are
+
+174
+00:14:59,320 --> 00:15:05,060
+the same compound كيف هذا الكلام بيصير؟ هل يا ترى
+
+175
+00:15:05,060 --> 00:15:09,520
+الإنسان بناقض في الحكي ولا لأ؟ الحقيقة في سبب و
+
+176
+00:15:09,520 --> 00:15:15,240
+الأمر هنابحاجة إلى نظرة شوية متعمقة .. بحاجة إلى
+
+177
+00:15:15,240 --> 00:15:19,380
+نظرة شوية متعمقة بين هدول الصورتين تحديدا لو
+
+178
+00:15:19,380 --> 00:15:23,140
+اتخيلتوا انتوا .. لو اتخيلتوا ان انتوا حاطيتوا
+
+179
+00:15:23,140 --> 00:15:26,660
+دبوس هنا مسيكتوا هذا المركب بعدين لفتوه بهذا الشكل
+
+180
+00:15:26,660 --> 00:15:30,980
+طلعوا معايا مرة تانية كأنه هنا فيه محور و الف
+
+181
+00:15:30,980 --> 00:15:35,640
+المركب بهذا الشكل وين هتيجي هذه ال CH3 وين هتطلع
+
+182
+00:15:35,640 --> 00:15:41,720
+هذه ال CL تنتين وين هييجوا ال Hهيصيروا نفس هذا
+
+183
+00:15:41,720 --> 00:15:48,580
+المُركّب ولا لأ؟ نفس المُركّب واضح؟ بهذا الشكل
+
+184
+00:15:48,580 --> 00:15:54,420
+لفوه هاي الـ CLE جوهان و الـ H3 و الـ CH3 انعكسوا
+
+185
+00:15:54,420 --> 00:16:00,660
+ممكن واحدة تيجي تقولي ما كان لفت اللي قبله خليني
+
+186
+00:16:00,660 --> 00:16:05,680
+أرجع للي قبله اللي قبله ماكانش متمثل يعني لما ألف
+
+187
+00:16:05,680 --> 00:16:12,140
+شو بده ينزل هنا CH3 شو بده يطلع هنا؟صح لما انا هاد
+
+188
+00:16:12,140 --> 00:16:15,140
+و بدى ألف و هيك ال CL's و ال H's بيجوا مكان بعض
+
+189
+00:16:15,140 --> 00:16:19,940
+لكن محل ال Ethel شو بتيجي؟ محل ال Ethel مثل هذه
+
+190
+00:16:20,690 --> 00:16:26,010
+املاحظين يعني هذا لو لفته بينطبق على هذا لأ بينما
+
+191
+00:16:26,010 --> 00:16:30,910
+اللي بعده بينطبق ماسبب الانطباق في الحالة التالية
+
+192
+00:16:30,910 --> 00:16:34,390
+و عدم الانطباق في الحالة الأولى انه هذا في الحالة
+
+193
+00:16:34,390 --> 00:16:39,970
+هذه غير متماثل داخليا يعني هذه CH3 هذه اتل مش هذا
+
+194
+00:16:39,970 --> 00:16:47,410
+النص زي هذا بينما في المركب اللي بعده هذا متماثل
+
+195
+00:16:48,570 --> 00:16:51,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+196
+00:16:51,090 --> 00:16:58,750
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+197
+00:16:58,750 --> 00:16:59,530
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+198
+00:16:59,530 --> 00:17:00,070
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+199
+00:17:00,070 --> 00:17:00,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+200
+00:17:00,090 --> 00:17:00,210
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+201
+00:17:00,210 --> 00:17:00,910
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+202
+00:17:00,910 --> 00:17:00,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+203
+00:17:00,950 --> 00:17:01,730
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+204
+00:17:01,730 --> 00:17:13,310
+مثل مثل
+
+205
+00:17:13,310 --> 00:17:17,470
+مثل مثالـR و الـS اللي مبينين عكس بعض كيف بدنا نحل
+
+206
+00:17:17,470 --> 00:17:23,450
+مشكلتهم لأن احنا قلنا إذا كل شي عكس بعض لازم نصنف
+
+207
+00:17:23,450 --> 00:17:28,970
+المراكبات in anchors طب هي مبينين عكس بعض آه مديش
+
+208
+00:17:28,970 --> 00:17:33,990
+تنسوا شغلة هذا المراكب لو أنا جبته لكم في الامتحان
+
+209
+00:17:33,990 --> 00:17:39,610
+و قلتلكم سموهو إجت واحدة منكم اتطلعت فيه و حطت
+
+210
+00:17:39,610 --> 00:17:46,850
+ترقيم 1234 صار هذا موقع 2 و عملته لجته 2R هذا موقع
+
+211
+00:17:46,850 --> 00:17:53,050
+3 و عملته لجته 3S طيب لو واحدة تانية إجت و قالت
+
+212
+00:17:53,050 --> 00:18:00,930
+خليني أرقم من تحت ما هو متمثل هاي 1234 ع 23 أيضا
+
+213
+00:18:01,530 --> 00:18:06,510
+Echlor, إذا هذا بترقم من كام جهة؟ من الجهتين نفس
+
+214
+00:18:06,510 --> 00:18:11,230
+الشيء هذا بترقم من الجهتين نفس الشيء المركب اللي
+
+215
+00:18:11,230 --> 00:18:16,230
+جابي اللي بقدرش أعمل فيه هذا الكلام بدي أكو أتضالك
+
+216
+00:18:16,230 --> 00:18:22,490
+و أتقرره لو كنت بده أرقم من هنا هذه CH2 CH3 لحظة
+
+217
+00:18:22,490 --> 00:18:28,720
+واحد اتنين هيصيروا ال Echlorتلاتة اربعة واحد اتنين
+
+218
+00:18:28,720 --> 00:18:34,200
+تلاتة اذا هذا كام ترقيم يحتمل واحد فقط واحد اتنين
+
+219
+00:18:34,200 --> 00:18:37,920
+تلاتة عشان ال glory يكونوا اقل ترقيم من هنا واحد
+
+220
+00:18:37,920 --> 00:18:41,140
+اتنين تلاتة اربعة خمسة بيكون اتنين تلاتة من هنا
+
+221
+00:18:41,140 --> 00:18:45,640
+واحد اتنين تلاتة اربعة خمسة بيصير تلاتة اربعة اذا
+
+222
+00:18:45,640 --> 00:18:52,420
+هذا كام ترقيم يحتمليحتمل ترقيم واحد فقط لكن المركب
+
+223
+00:18:52,420 --> 00:18:56,880
+اللي بعده المتماثل لو انا رقمته زي ما انتوا شايفين
+
+224
+00:18:56,880 --> 00:19:06,100
+بالازرق صح و لو انا رقمته بالاحمر صح طيب اللي رقمت
+
+225
+00:19:06,100 --> 00:19:12,660
+بالازرق كتبت المركب 2R3S23Diclorobutane
+
+226
+00:19:12,660 --> 00:19:17,390
+طب و اللي بده ترقم بالاحمر شو هتكتب؟الـ 2 ما احنا
+
+227
+00:19:17,390 --> 00:19:21,950
+عارفين ان هذه R و هذه S بغض النظر عن الترقيم هتكتب
+
+228
+00:19:21,950 --> 00:19:25,270
+2S3R
+
+229
+00:19:25,270 --> 00:19:30,930
+الآن اي جواب اللي بدنا نعتبره صح الجوابين صح هذا
+
+230
+00:19:30,930 --> 00:19:36,610
+إله اسمين هذا إله اسمين لأنه متماثل وعشانك المدرس
+
+231
+00:19:36,610 --> 00:19:40,250
+اللي بده يصلح بيجيبلكوا هذا المركب ويقولكوا اعطوه
+
+232
+00:19:40,250 --> 00:19:45,680
+اسمهذا الجواب يبدو يعتبره صح وهذا الجواب يبدو
+
+233
+00:19:45,680 --> 00:19:49,600
+يعتبره صح لسبب بسيط انه مافيه فارق نهائي بين انكوا
+
+234
+00:19:49,600 --> 00:19:54,280
+ترقموه من هنا او من هنا الان نفس الشيء في المركب
+
+235
+00:19:54,280 --> 00:19:58,900
+التاني لما رقمناه بالازرق واحد اتنين تلاتة اربعة
+
+236
+00:19:58,900 --> 00:20:05,140
+طب لو واحدة عملتله ترقيم تاني بالاحمر ايش هتكتبوه؟
+
+237
+00:20:05,140 --> 00:20:11,040
+two R three S الان اتطلعوا هذا أحد أسماء two S
+
+238
+00:20:11,040 --> 00:20:19,770
+three Rهذا أحد أسمائه 2R3S
+
+239
+00:20:19,770 --> 00:20:28,590
+و هذا 2R3S لأن الجزء ببساطة متماثل لأن هذا الجزء
+
+240
+00:20:28,590 --> 00:20:33,490
+ببساطة متماثل بياخد اسمين و هدول الشكلين بيكونوا
+
+241
+00:20:33,490 --> 00:20:38,710
+مركب واحد مش مركبينواضح؟ مركّب واحد وبتسمى
+
+242
+00:20:38,710 --> 00:20:42,110
+بطريقتين، الآن إذا اتفقنا إن هدولة they are the
+
+243
+00:20:42,110 --> 00:20:46,250
+same compound، بأكتر من طريقة فرجيتكم، اللي بدأ من
+
+244
+00:20:46,250 --> 00:20:49,710
+خلال الإشارات، إنه يلهم نفس الإشارات، أيه؟ يلهم
+
+245
+00:20:49,710 --> 00:20:56,750
+نفس الإشارات ولا لأ؟2R 3S .. 2S 3R .. 2S 3R .. 2S
+
+246
+00:20:56,750 --> 00:21:04,650
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+247
+00:21:04,650 --> 00:21:05,570
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+248
+00:21:05,570 --> 00:21:05,730
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+249
+00:21:05,730 --> 00:21:05,930
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+250
+00:21:05,930 --> 00:21:06,830
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+251
+00:21:06,830 --> 00:21:14,070
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+252
+00:21:14,070 --> 00:21:21,840
+2S 3R .. 2S 3Rوغيرهم سواء سمته 2R3S او 2S3R هو نفس
+
+253
+00:21:21,840 --> 00:21:26,100
+المركب له اسميننفس المركب له اسمين شو اللي عمله
+
+254
+00:21:26,100 --> 00:21:31,660
+الاسمين التماثل اذا لو انا بجاجي اسأل ببساطة لو
+
+255
+00:21:31,660 --> 00:21:35,480
+واحدة ع طول بده تعرف انه عندها اربع مركبات ولا
+
+256
+00:21:35,480 --> 00:21:40,320
+تلاتة ايش اول ما بده تطلع عليه في الجزء انه هل يا
+
+257
+00:21:40,320 --> 00:21:44,460
+ترى هذا الجزء اللي عنده فيه تماثل ولا لا اذا فيه
+
+258
+00:21:44,460 --> 00:21:49,620
+تماثل ع طول بده تحكي عن كام مركبعن تلاتة مافيش
+
+259
+00:21:49,620 --> 00:21:53,820
+تماثل بده تحكي عن أربع يعني لو مثلا سألكوا هذا
+
+260
+00:21:53,820 --> 00:22:05,280
+السؤال CH3 CHBR CHCL CH3 كام Cairo Center فيه؟هن و
+
+261
+00:22:05,280 --> 00:22:09,200
+هن قبل ما ارسم ايزو مارزو اتعب كام ايزو مارزو
+
+262
+00:22:09,200 --> 00:22:14,480
+تتوقعوا له اربعة عطول اربعة ليش لانه انا لو جسمت
+
+263
+00:22:14,480 --> 00:22:18,260
+بين هدولة two chiral centers هذي الظرات مش هى هذي
+
+264
+00:22:18,260 --> 00:22:25,060
+الظرات هنا عندكم H و CL هنا H .. خلاص انتهى واضح؟
+
+265
+00:22:25,060 --> 00:22:31,600
+و هكذاواضح، الان هذا المركب اللي فيه تماثل داخلي،
+
+266
+00:22:31,600 --> 00:22:37,860
+لو انتوا بتتأملوا فيه بعمق شوية، بتحسوا انه اللي
+
+267
+00:22:37,860 --> 00:22:44,250
+خلّاه يصيرنفس المركب و اقدر الفه انه انا لو اني
+
+268
+00:22:44,250 --> 00:22:48,650
+اتخيلت مرايا في نص المركب هذا النص اللى فوق صورة
+
+269
+00:22:48,650 --> 00:22:52,770
+النص اللى تحت فى المرأة ولا لأ طلعوا معاك هى ال CL
+
+270
+00:22:52,770 --> 00:23:00,790
+اقبالها CL ال H H ال مثل مثل اذا one half of the
+
+271
+00:23:00,790 --> 00:23:04,170
+molecule is the mirror image of the other half ولا
+
+272
+00:23:04,170 --> 00:23:10,660
+لأ هذا النص هو صورة هذا النص فى المرأةواضح الكلام؟
+
+273
+00:23:10,660 --> 00:23:14,420
+زي الناس اللي بتطلعوا على كروت الشدة إذا عمركوا
+
+274
+00:23:14,420 --> 00:23:18,780
+شفتوها بتشوفوا الرسومات اللي فيها البني آدم هيك او
+
+275
+00:23:18,780 --> 00:23:24,620
+بصر هيك بعدين هذا
+
+276
+00:23:24,620 --> 00:23:29,540
+زيه بالظبط .. هذا زيه بالظبط أنه النص هذا .. صورة
+
+277
+00:23:29,540 --> 00:23:37,180
+النص هذا في المرأةواضح؟ الان هذا المركب كأنه حقيقة
+
+278
+00:23:37,180 --> 00:23:42,380
+يحتوي على مركبين كأنه هذا مركب بإمكانكوا تتخيلوه و
+
+279
+00:23:42,380 --> 00:23:47,540
+هذا مركب تاني و هاي هم بس متصلين في بعض و من البعض
+
+280
+00:23:47,540 --> 00:23:52,760
+لو إجيت بديت أفكر بعمق شوية هذا لو إنه حطناه لوحده
+
+281
+00:23:52,760 --> 00:23:59,810
+في المرآة بيطلع كايران و إلهrotation وهذا لو حطيته
+
+282
+00:23:59,810 --> 00:24:04,450
+لوحده في المرأة كايرة له rotation طيب لو أخدت
+
+283
+00:24:04,450 --> 00:24:09,530
+مليون جزء من المركب الكلي كده يكون من هذا النص
+
+284
+00:24:09,530 --> 00:24:15,370
+مليون و من هذا النص مليون و المليونين عكس بعض صار
+
+285
+00:24:15,370 --> 00:24:21,750
+هذا بنفسه يشبه إيش؟Racemic mixture اللى أخدناه
+
+286
+00:24:21,750 --> 00:24:25,510
+المرة الماضية لما كنا نقولكوا لو كان عندى خليط
+
+287
+00:24:25,510 --> 00:24:31,050
+متساوي من two isomers شو سمناه؟ Racemic mixture
+
+288
+00:24:31,050 --> 00:24:35,850
+واحد منهم بيلف يمين التانى اشمال قداش بيكون
+
+289
+00:24:35,850 --> 00:24:41,240
+بالمجمل ال rotation له؟ سفرالـ Racemic mixture
+
+290
+00:24:41,240 --> 00:24:45,460
+بيكون optically active ولا inactive؟ optically
+
+291
+00:24:45,460 --> 00:24:48,880
+inactive ليش optically inactive؟ لأنه فيه عدد
+
+292
+00:24:48,880 --> 00:24:54,240
+متساوي من ال enantiomers بيلغوا بعض الان هذا تماما
+
+293
+00:24:54,240 --> 00:24:58,700
+يشبه الracemic mixture كأنه هاي نص و هاي نص هدول
+
+294
+00:24:58,700 --> 00:25:04,040
+عكس بعض ولا لا؟ واحد R و واحد S الجزء الكبير لو
+
+295
+00:25:04,040 --> 00:25:09,210
+منه مليون كدهش فيه من هذا؟ و من هذا؟أذا هذا
+
+296
+00:25:09,210 --> 00:25:13,330
+racemic mixture كأنه بامتياز بس موجود في مركب واحد
+
+297
+00:25:13,330 --> 00:25:17,550
+فهذا المركب بالمجمل بيكون optically active ولا
+
+298
+00:25:17,550 --> 00:25:24,070
+inactive هالمركب العجيب هذا المتماثل اللي موجود ال
+
+299
+00:25:24,070 --> 00:25:28,390
+configuration فيه لنصه عكس التاني اللي نصه صورة
+
+300
+00:25:28,390 --> 00:25:32,270
+بعض أو صورة نص التاني في المرآة أخد اسم في ال
+
+301
+00:25:32,270 --> 00:25:36,910
+stereo chemistry بيسميه meso compound أو
+
+302
+00:25:36,910 --> 00:25:42,570
+mesostructureلحظة الان لو بدنا نقرأ ايش تعريف ال
+
+303
+00:25:42,570 --> 00:25:47,170
+meso compound كل الكلام هذا معرف هنا كل اللي حكينا
+
+304
+00:25:47,170 --> 00:25:53,050
+ال meso compound is an achiral diastereomer of the
+
+305
+00:25:53,050 --> 00:25:56,450
+compound achiral يعني optically inactive شوفنا ليش
+
+306
+00:25:56,450 --> 00:26:02,470
+انه achiral و ليش انه optically inactiveرغم أنه في
+
+307
+00:26:02,470 --> 00:26:06,750
+مركز استيريوجينيك كم مركز استيريوجينيك فيه؟ اتنين
+
+308
+00:26:06,750 --> 00:26:11,630
+لكن هو بالمحصلة كايرال ولا اكايرال؟ اكايرال
+
+309
+00:26:11,630 --> 00:26:14,190
+optical and active although it contains
+
+310
+00:26:14,190 --> 00:26:18,030
+stereogenic centers الان its stereogenic centers
+
+311
+00:26:18,030 --> 00:26:23,190
+have opposite configurations يعني لازم واحد R
+
+312
+00:26:23,190 --> 00:26:26,970
+والتاني S هذا اللي بيكون ال mesocompound او نفس
+
+313
+00:26:26,970 --> 00:26:32,470
+المركب one half of the molecule isThe mirror image
+
+314
+00:26:32,470 --> 00:26:37,330
+of the other half اللي في هذه المواصفات بنقول انه
+
+315
+00:26:37,330 --> 00:26:43,520
+ميزو كومباوند بيكون مركب واحد مشمش مركبين
+
+316
+00:26:43,520 --> 00:26:46,160
+optically inactive يعني لو جينا سئلناكوا في
+
+317
+00:26:46,160 --> 00:26:49,360
+الامتحان ميزو كومباوند is optically active or
+
+318
+00:26:49,360 --> 00:26:55,260
+inactive؟ inactive الميزو كومباوند if مركب متماثل
+
+319
+00:26:55,260 --> 00:26:58,680
+لما اجي ارسم عندى two R three R two S three S و
+
+320
+00:26:58,680 --> 00:27:02,880
+two R three S او التانية من اللي فيهم بتكون ميزو؟
+
+321
+00:27:02,880 --> 00:27:09,000
+اللي فيها هدول عكس بعض يعني اللي بتكون RR او SS كل
+
+322
+00:27:09,000 --> 00:27:13,630
+واحدة منهم فردة in andيعني هذه لو أخدتها لحالها
+
+323
+00:27:13,630 --> 00:27:19,130
+optically active لو
+
+324
+00:27:19,130 --> 00:27:23,650
+عملت خليط متساوي من هدول الاتنين بيصير عند راسمك
+
+325
+00:27:24,520 --> 00:27:28,120
+mixture بيصير optical inactive لو أخدت من واحدة
+
+326
+00:27:28,120 --> 00:27:33,360
+اكتر من التانية زي ما اتعلمنا بيصير النتج نتاج
+
+327
+00:27:33,360 --> 00:27:38,600
+التنتين لكن هذا المركب هذا المركب اللي بيميزه انه
+
+328
+00:27:38,600 --> 00:27:43,100
+واحدة منه R والتانية S اذا انا لما بتعرف ال mezzo
+
+329
+00:27:43,100 --> 00:27:47,380
+compound في المركب المتماثل اللي بيكون منه واحدة R
+
+330
+00:27:47,380 --> 00:27:53,360
+والتانية S هذا ال mezzo compound والمجموع بيطلع
+
+331
+00:27:54,340 --> 00:27:59,240
+تلات مركبات في النهاية الان لو اتيت سألة طيب يا
+
+332
+00:27:59,240 --> 00:28:02,700
+تورا قولنا احنا اكيد بين هذا و هذا العلاقة they
+
+333
+00:28:02,700 --> 00:28:06,720
+are enantiomers طب لو اي واحد من هذول ال
+
+334
+00:28:06,720 --> 00:28:11,520
+enantiomers قرنته بال meso compound اه طلعوا two
+
+335
+00:28:11,520 --> 00:28:18,320
+are نفس الاشي هدوله واضح نفس الشي و three are
+
+336
+00:28:18,320 --> 00:28:24,870
+three asعكس بعض، اشي نفسه، اشي عكسه، فين VR؟ ده
+
+337
+00:28:24,870 --> 00:28:30,950
+يستيريو مارسي، فين VR؟ ده يستيريو مارسي بتايع ليه؟
+
+338
+00:28:30,950 --> 00:28:35,490
+بيكفي على موضوع ال two chiral centers الآن في
+
+339
+00:28:35,490 --> 00:28:41,850
+عندكم مجموعة من الأسئلة كيف توجدوا العلاقة بين
+
+340
+00:28:41,850 --> 00:28:47,080
+المركبين حتى لو رسمناهم بطرق مختلفةلاحظوا هذه
+
+341
+00:28:47,080 --> 00:28:50,980
+المُركّبات مرسومة بطرق مختلفة تماما مرة الـH لفوق
+
+342
+00:28:50,980 --> 00:28:54,820
+و مرة الـH على الجانب لكنهم نفس المُركّب بالمناسبة
+
+343
+00:28:54,820 --> 00:29:00,060
+يعني من ناحية structure أو روابط يعني كاربون
+
+344
+00:29:00,060 --> 00:29:04,280
+الأولى حملة PR و CL و بعدين CH3 و هاي الكاربون
+
+345
+00:29:04,280 --> 00:29:07,680
+اللي هو حملة PR و CL و بعدين CH3 يعني لو هذا و هذا
+
+346
+00:29:07,680 --> 00:29:13,090
+كنت بدأ أسميهم one-bromo one-chloro-ethaneمرة
+
+347
+00:29:13,090 --> 00:29:18,290
+تانية هاي carbon واحد هاي اتنين شو هتسموه وان
+
+348
+00:29:18,290 --> 00:29:25,500
+برومو وان كلوروإيه ثاني الار هدول الاتنين اللي
+
+349
+00:29:25,500 --> 00:29:29,680
+مرسومين بيدي العلاقة بينهم مش مرسومين بطريقة اللي
+
+350
+00:29:29,680 --> 00:29:33,180
+بالعين المجردة أشوف أنهم بينيهم مرسومين زي بعض أو
+
+351
+00:29:33,180 --> 00:29:37,000
+كل واحدة عكس التانية مرسومين بطرق مختلفة إذا على
+
+352
+00:29:37,000 --> 00:29:42,200
+طول ماليش حل إلا أحدد ال configuration أحددهم بضوء
+
+353
+00:29:42,200 --> 00:29:46,880
+هذا طلع R و هذا R then they are the same compound
+
+354
+00:29:46,880 --> 00:29:53,920
+واضح؟ الآن جيبنالكم مركبين تانينكم carbon هذا لو
+
+355
+00:29:53,920 --> 00:29:59,540
+بدكوا تسموه المركب هذا أطول سلسلة فيه قداش أربعة
+
+356
+00:29:59,540 --> 00:30:09,160
+واحد اتنين اعلم على أطول سلسلة CH3CCCH3
+
+357
+00:30:09,160 --> 00:30:17,440
+إذا هذا المركب اللي عندى بيوتين شو بيحمل بيوتين؟ع
+
+358
+00:30:17,440 --> 00:30:21,920
+نمره 2 برومه ع نمره 3 كلور ترقيب واحد عندي عشان
+
+359
+00:30:21,920 --> 00:30:26,340
+اخلي البروم اقل ما يمكن اتنين برومه ثلاثة ثلاثة
+
+360
+00:30:26,340 --> 00:30:27,620
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+361
+00:30:27,620 --> 00:30:29,600
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+362
+00:30:29,600 --> 00:30:36,300
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+363
+00:30:36,300 --> 00:30:44,220
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+364
+00:30:44,220 --> 00:30:50,050
+ثلاثة ثأحدد R و S لما أعملهم بهدوء بتعملهم في
+
+365
+00:30:50,050 --> 00:30:56,550
+البيت هنا two S and two R انبينين عكس بعض three S
+
+366
+00:30:56,550 --> 00:31:01,850
+and three R the same then they are diastereomers
+
+367
+00:31:01,850 --> 00:31:05,730
+كذلك
+
+368
+00:31:05,730 --> 00:31:11,930
+الحال هذا المركب هي أطول سلسلة فيهنطلع عليها واحد
+
+369
+00:31:11,930 --> 00:31:15,810
+اتنين تلاتة اربعة ع تنين برم وع تلاتة كلور وهذه
+
+370
+00:31:15,810 --> 00:31:20,350
+أطول السلسلة واحد اتنين تلاتة اربعة ع تنين برم وع
+
+371
+00:31:20,350 --> 00:31:28,710
+تلاتة كلور نحدد له R وS two S two R three S three
+
+372
+00:31:28,710 --> 00:31:37,170
+R الترقيم من هناك كل شيء عكس بعضين VR انانشومارز
+
+373
+00:31:37,170 --> 00:31:41,670
+اللي بعده نفس الشيء لو عملته بهدوءthe same
+
+374
+00:31:41,670 --> 00:31:46,270
+compound واضح؟ the same compound طبعا انتوا بدكوا
+
+375
+00:31:46,270 --> 00:31:51,970
+تحذروا بس بحالة واحدة لما يكون المركب متماثل و
+
+376
+00:31:51,970 --> 00:31:57,010
+يطلع عندكم 2R 3S و التالية 2S 3R بدكوا ترجعوا
+
+377
+00:31:57,010 --> 00:32:00,770
+تفكروا بالإيش بال meso compound اللي هو the same
+
+378
+00:32:00,770 --> 00:32:04,910
+compoundلو كان المراكب متماثل الأمثل هذا اللي
+
+379
+00:32:04,910 --> 00:32:09,350
+قدامكم مش متماثل لأنه على جهة بروم و على جهة كلور
+
+380
+00:32:09,350 --> 00:32:15,150
+دائما التفكير وين بده يكون قف و أفكر لما يكون فيه
+
+381
+00:32:15,150 --> 00:32:19,490
+تماثل داخلي إذا في تماثل داخلي و طلع عندكم ال
+
+382
+00:32:19,490 --> 00:32:26,150
+configurations في المتماثل إذا طلع عندكم R و S و
+
+383
+00:32:26,150 --> 00:32:31,390
+جبالها S و Rthey are the same compound هذا الحكي
+
+384
+00:32:31,390 --> 00:32:37,610
+وين بيكون في المركبات المتماثلة بيكون المركب فعلا
+
+385
+00:32:37,610 --> 00:32:44,630
+ميزو لما أحكي عن مركبين ر أس و أس و ر طلعوا معاكم
+
+386
+00:32:44,630 --> 00:32:51,270
+if مركب فيه تماثل داخلي بنقول عنهم they are the
+
+387
+00:32:51,270 --> 00:32:56,130
+same compound أو بنقول this is a mezzo compound
+
+388
+00:32:56,130 --> 00:33:01,530
+وبيكون طبعا opticallyinactive بيكون optically
+
+389
+00:33:01,530 --> 00:33:05,810
+inactive الان
+
+390
+00:33:05,810 --> 00:33:13,230
+لو اجينا لتفاعلات او التفاعلات المرتبطة بال stereo
+
+391
+00:33:13,230 --> 00:33:17,590
+chemistry في ال stereo chemistry في عندى اكتر من
+
+392
+00:33:17,590 --> 00:33:21,520
+نوع من التفاعلاتأحد هذه التفاعلات بنسميه
+
+393
+00:33:21,520 --> 00:33:25,720
+generation of a chiral center يعني انتوا بدأتوا
+
+394
+00:33:25,720 --> 00:33:30,320
+بمركب مش فيه ولا chiral center اعملتوا chiral
+
+395
+00:33:30,320 --> 00:33:35,740
+center خلينا ناخد مثال بسيط لو قلنا لكوا بدنا نعمل
+
+396
+00:33:35,740 --> 00:33:44,340
+chlorination للبيوتين بتذكرين البيوتين CH3 CH2 CH2
+
+397
+00:33:45,570 --> 00:33:50,510
+CH3 هل يترى هذا في أي كايرال سنتر؟ لا في كربون
+
+398
+00:33:50,510 --> 00:33:55,770
+بتحمل أربع مجموعات الآن بدنا نشيل هيدروجين يا من
+
+399
+00:33:55,770 --> 00:34:00,590
+موقع واحد يا من موقع اتنين يعني انا لما بعمل ال
+
+400
+00:34:00,590 --> 00:34:04,370
+chlorineation على البيوتين كام ناتج كنا متوقعين
+
+401
+00:34:04,370 --> 00:34:08,630
+اللي بيطلع عندنا اتنين المركب الأول اللي بيجيب ال
+
+402
+00:34:08,630 --> 00:34:13,150
+chlorine على موقع واحد هل صار في كايرال سنتر؟ لا
+
+403
+00:34:14,270 --> 00:34:18,910
+تخيلوا لو بدأ أضع الكلور على موقع واحد CH2CL
+
+404
+00:34:43,960 --> 00:34:47,500
+فى كل الأحوال بيصير عندى carol center يعني تخيل لو
+
+405
+00:34:47,500 --> 00:34:50,320
+أنا حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+406
+00:34:50,320 --> 00:34:55,040
+و لو حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+407
+00:34:55,040 --> 00:34:59,820
+اتطلعوا بينهم سواء كعلاقة أو لو حسبتولهم R و S
+
+408
+00:34:59,820 --> 00:35:07,910
+هتلاحظوا ان هدول الاتنين عكس بعض Rانانشو مارزي
+
+409
+00:35:07,910 --> 00:35:13,250
+يعني هاي ال H نفترض CL و بعدين اثلو مثل مبينة R
+
+410
+00:35:13,250 --> 00:35:18,650
+this is S وهي هذي ال H بنشطبها CL مبينة S هاي ال
+
+411
+00:35:18,650 --> 00:35:23,970
+configuration لهدول اذا انا وين اعملت chiral
+
+412
+00:35:23,970 --> 00:35:27,830
+center ع موقع واحد ولا ع موقع اتنين ع موقع اتنين
+
+413
+00:35:27,830 --> 00:35:31,870
+وين بعمل chiral center بطلع عندى خليط من two
+
+414
+00:35:31,870 --> 00:35:36,810
+انانشو مارزيبطلع عندى خليط من two enansimers اذا
+
+415
+00:35:36,810 --> 00:35:40,270
+لو اجيت انا سألتكوا الان سؤال بالمجمل
+
+416
+00:35:40,270 --> 00:35:46,110
+لchlorination of butane كم مركب بيعطينى تلاتة
+
+417
+00:35:46,110 --> 00:35:50,130
+تلاتة تنسوش انه انا في شغل مش كاتبة لأنه خارج
+
+418
+00:35:50,130 --> 00:35:57,190
+الإطار تبعنا انه لو فعلنا على هذا بيعطينا CH2CL
+
+419
+00:35:57,190 --> 00:36:00,450
+اللى هو ال one chlorobutane هذا مافيه chiral
+
+420
+00:36:00,450 --> 00:36:08,390
+centersهذا يبدو يجي الكلورة ع موقع واحد او ع موقع
+
+421
+00:36:08,390 --> 00:36:12,530
+اتنين ع موقع واحد عمل كايرال سنتر اذا هو مركب واحد
+
+422
+00:36:12,530 --> 00:36:16,490
+ع موقع اتنين عمل كايرال سنتر و ايه اللي بيصير
+
+423
+00:36:16,490 --> 00:36:20,790
+كايرال سنتر بيطلع عندى كام مركب اتنين اذا مجموع
+
+424
+00:36:20,790 --> 00:36:25,310
+المركبات قداشر تلاتة طب لو قولتلى واحدة سميلي
+
+425
+00:36:25,310 --> 00:36:27,890
+التلات نواتج اللى بيطلعوا من ال chlorineation و ال
+
+426
+00:36:27,890 --> 00:36:32,010
+butane شو هتقرأواحد كلورو بيوتين واحد كلورو بيوتين
+
+427
+00:36:32,010 --> 00:36:35,930
+ممتازة ارتو
+
+428
+00:36:35,930 --> 00:36:40,970
+كلورو بيوتين و استو كلورو بيوتين فبال total كام
+
+429
+00:36:40,970 --> 00:36:45,810
+مركب طلعوا تلاتة لكن لو كان السؤال كام structural
+
+430
+00:36:45,810 --> 00:36:50,610
+isomer بيطلع عنده من ال chlorineation اتنين لأن
+
+431
+00:36:50,610 --> 00:36:54,710
+معنى structural isomer مواقع الارتباط لكلور يا
+
+432
+00:36:54,710 --> 00:37:00,470
+بترتبط ع واحد يا بترتبط ع اتنينهدولة اتنين stereo
+
+433
+00:37:00,470 --> 00:37:05,390
+isomers ال R2 كلورو بيوتين و ال S2 كلورو بيوتين
+
+434
+00:37:05,390 --> 00:37:09,670
+they have the same bonding الارتباط فيه مع موقع
+
+435
+00:37:09,670 --> 00:37:13,870
+ايش اتنين but different arrangement in space هدولة
+
+436
+00:37:13,870 --> 00:37:18,010
+stereo isomers فبدكوا تنتبهوا لما بنسألكوا في
+
+437
+00:37:18,010 --> 00:37:21,550
+المنطقة لما نيجي نقولكم ال chlorineation في بيوتين
+
+438
+00:37:21,550 --> 00:37:26,670
+producesتو Structural Isomers، الـ Structural
+
+439
+00:37:26,670 --> 00:37:30,770
+مواقع، يا بتيجي الكلور على واحد، يا على اتنين،
+
+440
+00:37:30,770 --> 00:37:35,590
+الآن اللي على اتنين، في منها اتنين Stereoisomers،
+
+441
+00:37:35,590 --> 00:37:43,130
+اللي هم الـR والـS، واضح؟العلى اتنين في منها two
+
+442
+00:37:43,130 --> 00:37:47,750
+stereoisomers الار والاسم طبعا عادة بفسروا هذا
+
+443
+00:37:47,750 --> 00:37:50,870
+الكلام احنا مش اتنين ركزنا على ال mechanism of
+
+444
+00:37:50,870 --> 00:37:55,590
+reaction بفسروا انه هذا التفاعل اول ما بيبدأ
+
+445
+00:37:55,590 --> 00:38:00,410
+بترتفع في ذرة هيدروجين بيصيروا هدولة التلاتة
+
+446
+00:38:00,410 --> 00:38:06,520
+planner في مستوى واحد يعني لو انا بدي اجي اتخيلليش
+
+447
+00:38:06,520 --> 00:38:10,780
+تم التفاعل على الجهتين؟ لما تم التفاعل على
+
+448
+00:38:10,780 --> 00:38:18,200
+الجهتين؟ ممكن ايه بسرعة اريكم باستعمال ال models و
+
+449
+00:38:18,200 --> 00:38:27,360
+بأمل انها ال models بتخدمنا اتخيلوا
+
+450
+00:38:27,360 --> 00:38:33,500
+معنا لو اتخيلنا ان في عندنا CH3 ال CH3 نتخيلهاذرة
+
+451
+00:38:33,500 --> 00:38:39,550
+كربون صمرة CH3تمام؟ لما أشيل H بيبقى عندى كام
+
+452
+00:38:39,550 --> 00:38:44,650
+هيدروجين؟ واحدة و إيش بيبقى عندى؟ مجموعة ال إفل
+
+453
+00:38:44,650 --> 00:38:48,770
+لسه ماجيبتش ال chlorine أنا بدي بهذا كيف بعمل
+
+454
+00:38:48,770 --> 00:38:52,830
+الإبدال؟ بشيل الهيدروجينة في الأول و بعدين بحط
+
+455
+00:38:52,830 --> 00:38:57,250
+بدالها chlorine فدولة كام رابطة حوالين الكربون؟
+
+456
+00:38:57,250 --> 00:38:58,910
+أربعة أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+457
+00:38:58,910 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+458
+00:38:59,790 --> 00:39:06,750
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة
+
+459
+00:39:07,360 --> 00:39:13,760
+بمشي الحال هاي هذا صار بهذا الشكل بالظبط طلعوا في
+
+460
+00:39:13,760 --> 00:39:20,740
+مجموعة مثل و H و إثل و ال H الأخيرة شيلناها
+
+461
+00:39:20,740 --> 00:39:24,240
+رفعناها الآن بدنا نجيب ال chlorine تتفاعل
+
+462
+00:39:26,450 --> 00:39:29,650
+هذه الـ Intermediate للحظة برفعت الـ H الأولى
+
+463
+00:39:29,650 --> 00:39:33,330
+بلانر في مستوى واحد الكلور بإمكانها تيجي تهاجم
+
+464
+00:39:33,330 --> 00:39:37,470
+عليها من هنا و هدولا بتعجوا حلو ميك او من هنا
+
+465
+00:39:37,470 --> 00:39:43,910
+طالما انها بلانر في فرق ان الكلور هي جاية من بعيد
+
+466
+00:39:43,910 --> 00:39:49,130
+بفرق عندها انها تمشي من هنا او من هنا اطلع معي
+
+467
+00:39:49,130 --> 00:39:52,670
+شايفين هدول الممرين اللي في القاعة لو انا بدي اروح
+
+468
+00:39:52,670 --> 00:39:59,700
+لاخر نقطةبإمكاني أمشي من هنا و من هنا بشكل متساوي
+
+469
+00:39:59,700 --> 00:40:04,520
+ولا لأ؟ ماعندي مشكلة، بدي أروح لآخر نقطة وهي عندي
+
+470
+00:40:04,520 --> 00:40:08,240
+مصارين متكافئت كذلك الحال، هذا planner بدي تيجي
+
+471
+00:40:08,240 --> 00:40:12,200
+اكلور من برا تتفاعل عليه، ترد تعمل المجموعة
+
+472
+00:40:12,200 --> 00:40:16,180
+الرابعةإذا أتيت من هنا عملة انانشومر و إذا أتيت من
+
+473
+00:40:16,180 --> 00:40:20,660
+هنا عملة التاني الان من ناحية الاحتمالات متساوية
+
+474
+00:40:20,660 --> 00:40:25,440
+تماما و لذلك يظهر عندي راسيمك ميكسشر يعني يظهر
+
+475
+00:40:25,440 --> 00:40:30,220
+الاتنين و يظهرون بنسب متساوية يظهر الاتنين و
+
+476
+00:40:30,220 --> 00:40:34,100
+يظهرون بنسب متساوية فبصير المحصلة ان ال generation
+
+477
+00:40:34,100 --> 00:40:42,710
+of a chiral center produces راسيمك ميكسشرواضح؟ ال
+
+478
+00:40:42,710 --> 00:40:46,690
+generation of a chiral center produces a racemic
+
+479
+00:40:46,690 --> 00:40:53,110
+mixture الان لو قلنا بدل racemic mixture equal
+
+480
+00:40:53,110 --> 00:40:59,740
+number of enantiomers أكيد صح .. أكيد صحgeneration
+
+481
+00:40:59,740 --> 00:41:02,520
+of a chiral center produces racemic mixtures
+
+482
+00:41:02,520 --> 00:41:10,660
+لاحظوا هذه الجملة بالنسبة للكيميا ما بين الكيميا
+
+483
+00:41:10,660 --> 00:41:15,480
+اللي بيصنعوها البشر و ما بين خلق الله سبحانه
+
+484
+00:41:15,480 --> 00:41:21,070
+وتعالى بتعمل فرق كبير جدااليوم لما انا باجي في
+
+485
+00:41:21,070 --> 00:41:26,450
+المختبر بده احضر مركب و اعمل chiral center انا
+
+486
+00:41:26,450 --> 00:41:31,290
+مابتحكمش في الاحتمالات بطلع عندى خليط متساوي و
+
+487
+00:41:31,290 --> 00:41:36,090
+بعدين اتعب و افصله و هذا السبب ربما في انه في دوة
+
+488
+00:41:36,090 --> 00:41:41,360
+مثل الثاليدواميد كان بيطلع الخليطالمتساوي ال R و
+
+489
+00:41:41,360 --> 00:41:45,860
+ال S لمنهم واحد مفيد و واحد ضار و عمل مشاكل كتير
+
+490
+00:41:45,860 --> 00:41:50,160
+كل ما بشغل في المختبر المختبر بطلعلي خليط من
+
+491
+00:41:50,160 --> 00:41:52,940
+المركبين اذا مش عندى chiral center انا بدي اعمله
+
+492
+00:41:52,940 --> 00:41:57,460
+بطلعلي .. بطلعلي ايش؟ racemic mixture الان في
+
+493
+00:41:57,460 --> 00:42:02,570
+الطبيعة فيه انزيماتالانزيمات كأنها بتاخد بإيدي
+
+494
+00:42:02,570 --> 00:42:05,850
+المجموعة اللي جاية بالظبط بداخلها من جهة واحدة
+
+495
+00:42:05,850 --> 00:42:10,030
+ولذلك المنتجات الطبيعية بيطلع منها بس one in a
+
+496
+00:42:10,030 --> 00:42:16,750
+number هذا خلقههذا خلق الله يعني انا لما شغلة كون
+
+497
+00:42:16,750 --> 00:42:21,210
+بتحضرها الانزيمات و بتتحضر جوا الجسم بتلاقوا بيطلع
+
+498
+00:42:21,210 --> 00:42:26,330
+منها بس واحد لما اجي انا اعيد التفاعل بالمختبر و
+
+499
+00:42:26,330 --> 00:42:30,110
+بدون انزيمات و بكذا بيطلع عندى خليط متساوي من
+
+500
+00:42:30,110 --> 00:42:34,830
+التنين ولذلك اللى بده مركبات نقية يعني بده one in
+
+501
+00:42:34,830 --> 00:42:39,750
+one شمر ايش اسهل طريقة يعملها؟ ياخدها من مصادرها
+
+502
+00:42:39,750 --> 00:42:44,590
+الطبيعية اذا كانت تحضر في الطبيعةطبعا إذا كانت لا
+
+503
+00:42:44,590 --> 00:42:51,850
+تحضر في الطبيعة بده يجعب هذه المشكلة و يطلع عنده
+
+504
+00:42:51,850 --> 00:42:56,450
+خليط من التنين عشان ايه كده في الكيميا بيسموه ايش
+
+505
+00:42:56,450 --> 00:43:02,990
+Symmetric Synthesis Symmetric Synthesis ايش معنى
+
+506
+00:43:02,990 --> 00:43:08,350
+Symmetric انه بيطلع خليط متمافل من التنين جد بعض و
+
+507
+00:43:08,350 --> 00:43:15,290
+بعدين يقعد ايش يعمليفصل فيهم الآن بدأوا من جديد
+
+508
+00:43:15,290 --> 00:43:21,030
+يستعملوا طرق حديثة في ال synthesis و يضيفوا عوامل
+
+509
+00:43:21,030 --> 00:43:25,330
+حفازة اللي تخلى واحد من هدول يطلع بنسبة اكتر من
+
+510
+00:43:25,330 --> 00:43:30,490
+التانية او يكاد يكون يطلع نقي وجدتها اذا طلعوا مش
+
+511
+00:43:30,490 --> 00:43:35,790
+متساويات شو بدى اسم ال synthesis Asymmetric
+
+512
+00:43:35,790 --> 00:43:40,010
+synthesisواضح؟ يعني الـ symmetric synthesis بتطلع
+
+513
+00:43:40,010 --> 00:43:44,810
+الخليط متساوي الآن إذا صرت أضيف عوامل حفازة بطرق
+
+514
+00:43:44,810 --> 00:43:49,290
+معينة بتحذيرات بصير أشتغل ايش؟ asymmetric
+
+515
+00:43:49,290 --> 00:43:52,910
+synthesis اليوم اللي منكم بده تدرس كيميا وبعدين
+
+516
+00:43:52,910 --> 00:43:57,120
+تقول أنا بدي أخد جائزة نوبل في الكيمياBye Bye
+
+517
+00:43:57,120 --> 00:44:01,260
+Asymmetric Synthesis بدا تشتغل على ايش؟ Asymmetric
+
+518
+00:44:01,260 --> 00:44:05,420
+Synthesis تصير تتعلم كتير تضيف عوامل حفازة
+
+519
+00:44:05,420 --> 00:44:12,040
+بمواصفات معينة تخلي التفاعل تطلع واحدمايطلعش
+
+520
+00:44:12,040 --> 00:44:16,200
+التاني او طلع واحد مثلا بنسبة 90% و التاني بنسبة
+
+521
+00:44:16,200 --> 00:44:20,800
+10% على سبيل المثال و كل ما جدت تطلع واحد تماما و
+
+522
+00:44:20,800 --> 00:44:26,500
+تلغي التاني كل ما كانت تمثل ايش نجاح كبير في الشغل
+
+523
+00:44:26,500 --> 00:44:31,720
+افهمنا اذا المشكلة ما بين الطبيعة و ما بين المختبر
+
+524
+00:44:31,720 --> 00:44:36,380
+المختبر هو وضع الطبيعيبطلّع لي خليط الطبيعة بوضعها
+
+525
+00:44:36,380 --> 00:44:42,120
+الطبيعي بطلّع واحد الان العالم بيسعوا نحو ايش؟ ان
+
+526
+00:44:42,120 --> 00:44:45,960
+يقتربوا من الطبيعة انهم يقدروا يطلعوا واحد و لو
+
+527
+00:44:45,960 --> 00:44:51,120
+بنسبة كبيرة في ما يسمى بالعلم ايش؟ asymmetric
+
+528
+00:44:51,120 --> 00:44:55,620
+synthesis بس بالتأكيد هذا الموضوع كتير متطور
+
+529
+00:44:55,620 --> 00:44:59,860
+بالنسبة لطالب organic يعني ما لم تتخصصوا كيميا مش
+
+530
+00:44:59,860 --> 00:45:02,460
+هتشتغلوا فيه بنكمل ان شاء الله في مرات
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..864b835533104ec7e59ec3855116960bf3f85565
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_raw.srt
@@ -0,0 +1,2128 @@
+1
+00:00:20,690 --> 00:00:24,750
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry
+
+2
+00:00:24,750 --> 00:00:29,730
+ربما المرة الماضية نوّهنا من خلال أنفلة تطبيقية من
+
+3
+00:00:29,730 --> 00:00:36,970
+خلال أهمية فهم ال stereo isomers في الحياة العملية
+
+4
+00:00:36,970 --> 00:00:42,990
+أن هذا موضوع مهم ولذلك شوية بنظل نتوسع فيه بعد ما
+
+5
+00:00:42,990 --> 00:00:46,830
+أخدنا المركبات اللي فيها one chiral center قولنا
+
+6
+00:00:46,830 --> 00:00:51,610
+ال one chiral center بيعتق فقطtwo isomers بعد ذلك
+
+7
+00:00:51,610 --> 00:00:56,690
+إذا زاد العدد بيبدأوا يزيدوا ال isomers طبعا بيحكم
+
+8
+00:00:56,690 --> 00:01:00,890
+الأمر المعادلة two to the n لكن ال two to the n
+
+9
+00:01:00,890 --> 00:01:05,230
+هذا أقصى عدد ممكن من ال isomers في كل الأحوال ممكن
+
+10
+00:01:05,230 --> 00:01:10,290
+يكون العدد أقل من هيك وقلنا هنعطي مثال على العدد
+
+11
+00:01:10,290 --> 00:01:15,330
+الأقصى ومثال على وانتش العدد بيصير أقل في حالة ما
+
+12
+00:01:15,330 --> 00:01:20,620
+عندنا two chiral centersبدأنا في مثال كنا عادة
+
+13
+00:01:20,620 --> 00:01:25,140
+ناخده على أنه مثال بسيط يعني الفكره مركب واحد لما
+
+14
+00:01:25,140 --> 00:01:29,620
+نيجي نقول two three dichloro بنتين بالفكره مركب
+
+15
+00:01:29,620 --> 00:01:33,640
+واحد لكن لما بنيجي نتطلع على موقع اتنين وعلى موقع
+
+16
+00:01:33,640 --> 00:01:39,410
+تلاتةبنلاحظ ان الاتنين they are chiral centers
+
+17
+00:01:39,410 --> 00:01:42,750
+وبناء على ذلك بنبدأ نتوقع انه كام مركبة بيصير
+
+18
+00:01:42,750 --> 00:01:48,890
+عندنا اربع مركبات جربنا نرسمهم من خلال انه نتخيل
+
+19
+00:01:48,890 --> 00:01:52,010
+مثلا بدنا ناخد السلسلة الكربونية بهذا الشكل يعني
+
+20
+00:01:52,010 --> 00:01:56,970
+الخمس كربونات واحد اتنين تلاتة و الاثلاربعة خمسة
+
+21
+00:01:56,970 --> 00:02:01,390
+CH2 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+22
+00:02:01,390 --> 00:02:06,770
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+23
+00:02:06,770 --> 00:02:08,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+24
+00:02:08,170 --> 00:02:08,950
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+25
+00:02:08,950 --> 00:02:09,750
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+26
+00:02:09,750 --> 00:02:10,270
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+27
+00:02:10,270 --> 00:02:11,790
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+28
+00:02:11,790 --> 00:02:13,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+29
+00:02:13,190 --> 00:02:23,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+30
+00:02:23,190 --> 00:02:27,670
+CH3 CHيعني ال R عكسة S ال R عكسة S كلام منطقي الان
+
+31
+00:02:27,670 --> 00:02:32,110
+لو جينا نطلع على المركب الثاني two R three S هذا
+
+32
+00:02:32,110 --> 00:02:37,870
+عكسه ال R اقبلها S ال S اقبلها R لأنه دائما صورة
+
+33
+00:02:37,870 --> 00:02:43,590
+بعض في المرأة بتعني التعاكس التام فلو احنا سألنا
+
+34
+00:02:43,590 --> 00:02:48,170
+ايش العلاقة بين واحد و اتنين they are enantiomersو
+
+35
+00:02:48,170 --> 00:02:52,290
+بيصير مفهوم عندنا ان اي مركبة لما نقول عنهم in
+
+36
+00:02:52,290 --> 00:02:58,650
+anchors بدتكون اشاراتهم عكس بعض الان طبعا انتوا
+
+37
+00:02:58,650 --> 00:03:02,390
+بالنظر بتقولوا صورة بعض في المرأة غير متطابقة لكن
+
+38
+00:03:02,390 --> 00:03:08,390
+ماتنسوش شغلة ان انا بإمكاني ارسم
+
+39
+00:03:09,150 --> 00:03:13,850
+المُركّب بطرق مختلفة بحيث أنه انتوا بمجرد النظر
+
+40
+00:03:13,850 --> 00:03:18,430
+البسيط ما تقدروش تتاخدوا قرار من النظر وجهة القرار
+
+41
+00:03:18,430 --> 00:03:21,750
+الأكيد بتقدروا تتاخدوا من إيش في علاقة بين
+
+42
+00:03:21,750 --> 00:03:29,110
+المُركّبين من قيم A و S خليني أؤكد الفكرة هذه لو
+
+43
+00:03:29,110 --> 00:03:34,310
+فقط أنا بدي أشغل معكم على مُركّب في one chiral
+
+44
+00:03:34,310 --> 00:03:40,470
+centerلو رسمت منه شكلين شو الاحتمالات المتوقعين
+
+45
+00:03:40,470 --> 00:03:43,610
+لما يكون عندي one chiral center؟ يا بده يكون
+
+46
+00:03:43,610 --> 00:03:48,910
+المركب نفسه رسمه بطريقتين مختلفة يا بده يكون in
+
+47
+00:03:48,910 --> 00:03:51,410
+anchormers ماعندي احتمال تاني
+
+48
+00:03:53,870 --> 00:04:01,450
+أخذ بسرعة عشوائيا هاي مركّب CH3CLPR وهي مركّب كتبت
+
+49
+00:04:01,450 --> 00:04:08,010
+هنا ال PR وهنا ال H وهنا ال CL وهنا ال CH3 لاحظوا
+
+50
+00:04:08,010 --> 00:04:12,610
+هدول المركّبين لو سألتكم ما العلاقة بينهما اللي
+
+51
+00:04:12,610 --> 00:04:16,030
+بده تيجي تتطلع تشوف أي شيء بالنظر و المرايا و
+
+52
+00:04:16,030 --> 00:04:22,100
+بنطبقه و مابنطبقوش حتىمش هتقدر، لأنه أنا أرسمهم
+
+53
+00:04:22,100 --> 00:04:25,640
+بطرق مختلفة، ماحدش بيمنعني أرسمهم بطرق مختلفة،
+
+54
+00:04:25,640 --> 00:04:31,700
+الآن أسهل شيء أن أحدد لكل مركب R أو S، الآن إذا
+
+55
+00:04:31,700 --> 00:04:35,500
+هذا طلع R و هذا R، معنى ذلك نفس المركب مرسوم بطرق
+
+56
+00:04:35,500 --> 00:04:40,800
+مختلفة، S و S نفس المركبإذا هذا R و هذا S, they
+
+57
+00:04:40,800 --> 00:04:44,140
+are enantiomers إذا هذا S و هذا R, they are
+
+58
+00:04:44,140 --> 00:04:48,260
+enantiomers هيكا بيكون أسهل طريقة أن أعملهم ولذلك
+
+59
+00:04:48,260 --> 00:04:54,380
+لو بدي أجي أطلع لهذا أقل مجموع ال H ب RCLCH3 من
+
+60
+00:04:54,380 --> 00:05:00,660
+بين R S لأن هذا ال H للأمام الآن لو بدي أطلع
+
+61
+00:05:00,660 --> 00:05:12,780
+المركب الثاني ب R CL SCH3 بين R مرة تانية وبنخليها
+
+62
+00:05:12,780 --> 00:05:18,100
+R لأن ال H للخلف هدول الانشو مارس طالما واحد قسي
+
+63
+00:05:18,100 --> 00:05:21,380
+التاني R إذا we are in ancho mars فالانشو مارس
+
+64
+00:05:21,380 --> 00:05:25,040
+دايما عكس بعض الان لو عندكوا خمسة كايرة ال centers
+
+65
+00:05:25,040 --> 00:05:29,520
+مش واحدإيش بتكون في الخمسة يكونوا عشان يكونوا
+
+66
+00:05:29,520 --> 00:05:35,300
+مركبين انانشومارز؟ كل واحد عكس التاني زي أنا باجف
+
+67
+00:05:35,300 --> 00:05:38,420
+قدام المرايا، الإيدين عكس بعض، الوش عكس بعض، البطن
+
+68
+00:05:38,420 --> 00:05:42,060
+عكس بعض، الرجلين عكس بعض، كل شيء بيكون عكس التاني،
+
+69
+00:05:42,060 --> 00:05:45,120
+يعني لو عندي ان شاء الله عشرين Cairo Center في
+
+70
+00:05:45,120 --> 00:05:49,600
+مركب، الانانشومارز تبعه، العشرين المقابلات بيكونوا
+
+71
+00:05:49,600 --> 00:05:56,300
+عكسهم، لو واحدة منهم اختلتببطلوا in anchormers على
+
+72
+00:05:56,300 --> 00:05:59,840
+طول ببطلوا صورة بعض في المرآة إذا بطلوا صورة بعض
+
+73
+00:05:59,840 --> 00:06:04,700
+في المرآة، شو بدوا يصيروا؟ ديستيريومارز، تنسوش إن
+
+74
+00:06:04,700 --> 00:06:08,740
+احنا عرفنا الديستيريومارز، they are non-mirror
+
+75
+00:06:08,740 --> 00:06:12,580
+image in anchormers ولذلك لو أنا سألت العلاقة بين
+
+76
+00:06:12,580 --> 00:06:20,780
+هدول، خلّينا نوضحها باسم RS عكس بعضعكس بعض اذا
+
+77
+00:06:20,780 --> 00:06:24,580
+they are enansimals واضح؟ الان لو سئلت هدول
+
+78
+00:06:24,580 --> 00:06:33,560
+الاتنين RS SR عكس طلع عليهم R اقبلها S S اقبلها R
+
+79
+00:06:33,560 --> 00:06:39,320
+عكس بعض they are enansimals الان لو اجيت اخدت مثلا
+
+80
+00:06:39,320 --> 00:06:49,160
+المركب واحد مع تلاتة اتطلعوا R وRهدولا متل بعض و
+
+81
+00:06:49,160 --> 00:06:56,860
+are و us عكس بعض هل هدولا عكس بعض بالكامل؟ لأ
+
+82
+00:06:56,860 --> 00:07:01,500
+هدولا متل بعض بالكامل؟ لأ مالو كانوا عكس بعض
+
+83
+00:07:01,500 --> 00:07:04,560
+بالكامل يعني كل نقطة عكس التانية they are
+
+84
+00:07:04,560 --> 00:07:10,000
+enantiomers الان لو كل نقطة زي التانية they are
+
+85
+00:07:10,000 --> 00:07:14,600
+the same compoundلو كل نقطة زي التانية هو نفس
+
+86
+00:07:14,600 --> 00:07:20,760
+المُركّب الـ R إيش زي بعض و إيش عكس بعض بطلوا صورة
+
+87
+00:07:20,760 --> 00:07:24,400
+بعض في المرأة أو بطلوا نفس المُركّب إيش هيصفه؟ ده
+
+88
+00:07:24,400 --> 00:07:28,180
+الـ Stereomers إذا لما بنيجي نتطلع إنه بدنا نفهم
+
+89
+00:07:28,180 --> 00:07:32,260
+العلاقة بين مُركّبين من خلال الرموز هنقول إنه
+
+90
+00:07:32,260 --> 00:07:36,260
+عندنا تلت احتمالات في حالة ما عندي أكتر من chiral
+
+91
+00:07:36,260 --> 00:07:40,600
+center لحظة لما كان عندي one chiral centerبدون ما
+
+92
+00:07:40,600 --> 00:07:44,080
+أعمل R و S بقولكوا عندي احتمالين يا بدهم يكونوا
+
+93
+00:07:44,080 --> 00:07:50,120
+نفس المركب R R S S يا بدهم يكونوا Enansi و Mars S
+
+94
+00:07:50,120 --> 00:07:54,840
+R أو R S الان لو كان عندي more than one chiral
+
+95
+00:07:54,840 --> 00:07:57,960
+center عندي تلت احتمالات الاحتمال الاول بدهم
+
+96
+00:07:57,960 --> 00:08:03,440
+يكونوا Enansi و Mars كل شيء عكس بعض الاحتمال
+
+97
+00:08:03,440 --> 00:08:09,150
+التاني انهم يكونوا نفس المركب كل شيء نفسهزي بعض طب
+
+98
+00:08:09,150 --> 00:08:12,950
+لو طلع شيء عكس و شيء زي بعض وجدت دي R ده يستيريو
+
+99
+00:08:12,950 --> 00:08:18,370
+مارس لحظوا الآن لو اجيت على واحد و تلاتة R و S عكس
+
+100
+00:08:18,370 --> 00:08:23,670
+بعض R و R زي بعض اذا هدولة صورت بعض في المرقاة لأ
+
+101
+00:08:23,670 --> 00:08:28,530
+نفس المركب لأ ر ده يستيريو مارس اذا واحد و تلاتة
+
+102
+00:08:28,530 --> 00:08:31,970
+ده يستيريو مارس لو طبقته مرة تانية على واحد و
+
+103
+00:08:31,970 --> 00:08:39,700
+أربعة مثلا ما العلاقة بينهم Rو S عكس بعض، هم
+
+104
+00:08:39,700 --> 00:08:47,540
+لاحظين؟ R و R نفس بعض، they are diastereomers لو
+
+105
+00:08:47,540 --> 00:08:52,720
+إجينا اتطلعنا على اتنين و تلاتة،
+
+106
+00:08:52,720 --> 00:09:02,010
+لاحظوا؟ S و Rعكس بعض السؤاس زي بعض كذلك الحال لو
+
+107
+00:09:02,010 --> 00:09:08,070
+اتطلعت اتنين اربع السؤاس نفس الاشي السؤاد عكس بعض
+
+108
+00:09:08,070 --> 00:09:13,230
+they are diastereomers واضح؟صار عندى نوع تانى من
+
+109
+00:09:13,230 --> 00:09:17,590
+الدياستيريو مارز جاي من وين جاي من المركبات فيها
+
+110
+00:09:17,590 --> 00:09:20,910
+chiral centers يعني احنا اول ما أخدنا تعريف
+
+111
+00:09:20,910 --> 00:09:25,270
+الدياستيريو مارز قولنا كل شيء مش صورة بعض في
+
+112
+00:09:25,270 --> 00:09:29,500
+المرقاة they are diastereomarsالأمثلة الكيميائية
+
+113
+00:09:29,500 --> 00:09:33,820
+الأولى اللى أخدناها شو هي الـ Cis والـ Trans أو
+
+114
+00:09:33,820 --> 00:09:37,300
+الـ Z والـ E they are diastereomers الآن بيجينا
+
+115
+00:09:37,300 --> 00:09:40,900
+أمثلة تانية لما يكون عندى more than one chiral
+
+116
+00:09:40,900 --> 00:09:45,160
+center هذه الأمثلة بتقول القاتل انه لو كان في عندى
+
+117
+00:09:45,160 --> 00:09:51,530
+مركبين في الإشارات تبعتهممش زي بعض تماما، مش نفس
+
+118
+00:09:51,530 --> 00:09:54,650
+المُركّب، ولا Inansiomers و they are
+
+119
+00:09:54,650 --> 00:10:00,010
+stereoisomers، إيش هيصفهم؟ ديستيريو مارس، واضح؟
+
+120
+00:10:00,010 --> 00:10:05,270
+وبهيك أخدنا إن الديستيريو مارس بكم ما كان، بنشوفهم
+
+121
+00:10:05,270 --> 00:10:11,460
+بالكيميامكالين بال CC trans او ZE و بال chiral
+
+122
+00:10:11,460 --> 00:10:15,680
+compounds او بال stereo chemistry لما يكون عندى
+
+123
+00:10:15,680 --> 00:10:21,440
+اكتر من chiral center بشرط انه ننتبه ل ROS
+
+124
+00:10:21,440 --> 00:10:27,760
+بالطريقة اللى اتكلمنا فيها الان طالما ان هدولةالهم
+
+125
+00:10:27,760 --> 00:10:31,760
+إشارات مختلفة فى كام مركب عندى لتو ثري دايكلورو
+
+126
+00:10:31,760 --> 00:10:36,180
+بنتين أربعة هى رموزهم اللى بدى تروح تشتريهم من
+
+127
+00:10:36,180 --> 00:10:39,800
+السوق هتلاقيهم أربعة مركبات الآن احنا قولنا ممكن
+
+128
+00:10:39,800 --> 00:10:46,760
+يكون العدد أقل ناخد مثالهذا المثال 2,3
+
+129
+00:10:46,760 --> 00:10:51,800
+-dichlorobutane قال ذرة كربون واحدة يعني لو انا
+
+130
+00:10:51,800 --> 00:10:56,080
+رسمت هاي كربون تنتين تلاتة اربعة اذا المركب اللي
+
+131
+00:10:56,080 --> 00:11:02,100
+عندى ايش بيوتين واضح لاحظوا ايش بيفرق يعني كتير
+
+132
+00:11:02,100 --> 00:11:09,120
+لبيوتين عنالبنتين لو انا مجرد ان كتبت كتابة مثل
+
+133
+00:11:09,120 --> 00:11:17,800
+CH3 CHCl CHCl CH3 عارفين شو بيفرق؟ لو انا اتيت بين
+
+134
+00:11:17,800 --> 00:11:20,840
+هدولة الـ chiral centers التنين الكاربونز اللي
+
+135
+00:11:20,840 --> 00:11:26,760
+حاملة كلور و جسمت المركب من النصتطلعوا هنا إيش
+
+136
+00:11:26,760 --> 00:11:33,460
+اللي موجود Carbon حاملة HCl و بعدها CH3 و هنا
+
+137
+00:11:33,460 --> 00:11:39,240
+Carbon حاملة HCl و بعدها CH3 إذا هذا المركب صار
+
+138
+00:11:39,240 --> 00:11:44,460
+مركب متماثل قبل شوية لما كنت .. أو من هنا على هذا
+
+139
+00:11:44,460 --> 00:11:49,800
+الشكل أجسم زي هيك تطلعوا كأعداد ذراتماذا عندكم
+
+140
+00:11:49,800 --> 00:11:54,980
+هنا؟ كاربون حاملة HCl وCH3 وهنا كاربون حاملة HCl
+
+141
+00:11:54,980 --> 00:12:01,860
+وCH3 فعدد الذرات اللي بهذا الاتجاه هو نفسه عدد
+
+142
+00:12:01,860 --> 00:12:05,760
+الذرات اللي بهذا الاتجاه فهذا الكاربون بيحمل نوع
+
+143
+00:12:05,760 --> 00:12:10,380
+من التماثل هذا الكلام في المثال السابق ماكانش لما
+
+144
+00:12:10,380 --> 00:12:16,160
+كنتوا تحطوا خط هنابين ال two chiral centers عدولي
+
+145
+00:12:16,160 --> 00:12:22,780
+كل الذرات اللي هتشومها C وH وCL و CH3 و هنا CH وCL
+
+146
+00:12:22,780 --> 00:12:29,460
+و بعدها CH2 CH3 إذا هل هذا النص زي هذا النص لأ في
+
+147
+00:12:29,460 --> 00:12:34,910
+حالة البيوتينأ لبيوتين في تماثل داخلي بين ال two
+
+148
+00:12:34,910 --> 00:12:39,790
+chiral centers يعني المركب سيماتريك الآن لو إجينا
+
+149
+00:12:39,790 --> 00:12:44,310
+جربنا نرسم ال isomers بنفس الطريقة اللي اتعلمناها
+
+150
+00:12:44,310 --> 00:12:51,270
+سابقا يعني أجي أحط تنتين كلور عكس بعض و صورتهم في
+
+151
+00:12:51,270 --> 00:12:54,810
+المرأة و تنتين كلور على جهة واحدة و صورتهم في
+
+152
+00:12:54,810 --> 00:13:02,210
+المرأة و بعدين أحدد R و Sلاحظوا هذه الرسمة تماما
+
+153
+00:13:02,210 --> 00:13:06,510
+هي نسخ و لصق من الرسمة السابقة بس بدل ما كنا
+
+154
+00:13:06,510 --> 00:13:12,890
+كاتبين هنا اثل كتبنا مثل واضح؟ و لذلك انتوا الان
+
+155
+00:13:12,890 --> 00:13:20,310
+كام مركب بتشوفه؟مازالتوا بتشوفوا أربع مركبات
+
+156
+00:13:20,310 --> 00:13:26,150
+للوهلة الأولى لكن لو نظرنا بعمق لهدولة الأربع
+
+157
+00:13:26,150 --> 00:13:32,130
+مركبات هلاحظ ان هذا 2R3R و هذا 2S3S
+
+158
+00:13:34,300 --> 00:13:40,660
+عكس بعض هتيجوا تستنتجوا انهم انانشومارز فش اننا
+
+159
+00:13:40,660 --> 00:13:45,160
+خلاف الآن لما بتيجوا تطلع على المركبين التانيين
+
+160
+00:13:45,160 --> 00:13:49,140
+وخلونا نقول .. نقولنا الترقيم واحد اتنين تلاتة
+
+161
+00:13:49,140 --> 00:13:55,720
+اربعة واحد اتنين تلاتة اربعة و هيناخد واحدة بس
+
+162
+00:13:55,720 --> 00:14:01,560
+نأكد هي ال CL نمرة واحدوهذه ال carbon الحاملة Cl2
+
+163
+00:14:01,560 --> 00:14:09,860
+و CH3 بين S كتبناها R وهذه لو بدنا نتطلع عليها 1 2
+
+164
+00:14:09,860 --> 00:14:16,300
+Cl بعدين carbon حاملة Cl بعدين CH3 Cl بعدين carbon
+
+165
+00:14:16,300 --> 00:14:21,100
+حاملة Cl بعدين CH3 بين R كتبنا S إذا هيك مظبوطين
+
+166
+00:14:21,100 --> 00:14:25,900
+هدولة two R three Sلو اعملنا المركب التاني لجبانو
+
+167
+00:14:25,900 --> 00:14:30,260
+بين two as three are اي حد هيتطلع بهذا الشكل
+
+168
+00:14:30,260 --> 00:14:33,800
+البصير شو هيقول هدول العلاقة بينهم they are
+
+169
+00:14:33,800 --> 00:14:36,760
+enantiomers الان بنقول لأ they are the same
+
+170
+00:14:36,760 --> 00:14:42,420
+compound هتبدو يصير عندكم مشكلة ليش لأنه هتقولوا
+
+171
+00:14:42,420 --> 00:14:47,540
+انت لسه توت و التصوير شاهد علينا كمان بتقول انه
+
+172
+00:14:47,540 --> 00:14:55,020
+اذا كل شيء عكس بعضهthey are enantiomers هاي مثال و
+
+173
+00:14:55,020 --> 00:14:59,320
+فيها دول عكس بعض لكن أنا قاعد بقول عنهم they are
+
+174
+00:14:59,320 --> 00:15:05,060
+the same compound كيف هذا الكلام بيصير؟ هل يا ترى
+
+175
+00:15:05,060 --> 00:15:09,520
+الإنسان بناقض في الحكي ولا لأ؟ الحقيقة في سبب و
+
+176
+00:15:09,520 --> 00:15:15,240
+الأمر هنابحاجة إلى نظرة شوية متعمقة .. بحاجة إلى
+
+177
+00:15:15,240 --> 00:15:19,380
+نظرة شوية متعمقة بين هدول الصورتين تحديدا لو
+
+178
+00:15:19,380 --> 00:15:23,140
+اتخيلتوا انتوا .. لو اتخيلتوا ان انتوا حاطيتوا
+
+179
+00:15:23,140 --> 00:15:26,660
+دبوس هنا مسيكتوا هذا المركب بعدين لفتوه بهذا الشكل
+
+180
+00:15:26,660 --> 00:15:30,980
+طلعوا معايا مرة تانية كأنه هنا فيه محور و الف
+
+181
+00:15:30,980 --> 00:15:35,640
+المركب بهذا الشكل وين هتيجي هذه ال CH3 وين هتطلع
+
+182
+00:15:35,640 --> 00:15:41,720
+هذه ال CL تنتين وين هييجوا ال Hهيصيروا نفس هذا
+
+183
+00:15:41,720 --> 00:15:48,580
+المُركّب ولا لأ؟ نفس المُركّب واضح؟ بهذا الشكل
+
+184
+00:15:48,580 --> 00:15:54,420
+لفوه هاي الـ CLE جوهان و الـ H3 و الـ CH3 انعكسوا
+
+185
+00:15:54,420 --> 00:16:00,660
+ممكن واحدة تيجي تقولي ما كان لفت اللي قبله خليني
+
+186
+00:16:00,660 --> 00:16:05,680
+أرجع للي قبله اللي قبله ماكانش متمثل يعني لما ألف
+
+187
+00:16:05,680 --> 00:16:12,140
+شو بده ينزل هنا CH3 شو بده يطلع هنا؟صح لما انا هاد
+
+188
+00:16:12,140 --> 00:16:15,140
+و بدى ألف و هيك ال CL's و ال H's بيجوا مكان بعض
+
+189
+00:16:15,140 --> 00:16:19,940
+لكن محل ال Ethel شو بتيجي؟ محل ال Ethel مثل هذه
+
+190
+00:16:20,690 --> 00:16:26,010
+املاحظين يعني هذا لو لفته بينطبق على هذا لأ بينما
+
+191
+00:16:26,010 --> 00:16:30,910
+اللي بعده بينطبق ماسبب الانطباق في الحالة التالية
+
+192
+00:16:30,910 --> 00:16:34,390
+و عدم الانطباق في الحالة الأولى انه هذا في الحالة
+
+193
+00:16:34,390 --> 00:16:39,970
+هذه غير متماثل داخليا يعني هذه CH3 هذه اتل مش هذا
+
+194
+00:16:39,970 --> 00:16:47,410
+النص زي هذا بينما في المركب اللي بعده هذا متماثل
+
+195
+00:16:48,570 --> 00:16:51,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+196
+00:16:51,090 --> 00:16:58,750
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+197
+00:16:58,750 --> 00:16:59,530
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+198
+00:16:59,530 --> 00:17:00,070
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+199
+00:17:00,070 --> 00:17:00,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+200
+00:17:00,090 --> 00:17:00,210
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+201
+00:17:00,210 --> 00:17:00,910
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+202
+00:17:00,910 --> 00:17:00,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+203
+00:17:00,950 --> 00:17:01,730
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+204
+00:17:01,730 --> 00:17:13,310
+مثل مثل
+
+205
+00:17:13,310 --> 00:17:17,470
+مثل مثالـR و الـS اللي مبينين عكس بعض كيف بدنا نحل
+
+206
+00:17:17,470 --> 00:17:23,450
+مشكلتهم لأن احنا قلنا إذا كل شي عكس بعض لازم نصنف
+
+207
+00:17:23,450 --> 00:17:28,970
+المراكبات in anchors طب هي مبينين عكس بعض آه مديش
+
+208
+00:17:28,970 --> 00:17:33,990
+تنسوا شغلة هذا المراكب لو أنا جبته لكم في الامتحان
+
+209
+00:17:33,990 --> 00:17:39,610
+و قلتلكم سموهو إجت واحدة منكم اتطلعت فيه و حطت
+
+210
+00:17:39,610 --> 00:17:46,850
+ترقيم 1234 صار هذا موقع 2 و عملته لجته 2R هذا موقع
+
+211
+00:17:46,850 --> 00:17:53,050
+3 و عملته لجته 3S طيب لو واحدة تانية إجت و قالت
+
+212
+00:17:53,050 --> 00:18:00,930
+خليني أرقم من تحت ما هو متمثل هاي 1234 ع 23 أيضا
+
+213
+00:18:01,530 --> 00:18:06,510
+Echlor, إذا هذا بترقم من كام جهة؟ من الجهتين نفس
+
+214
+00:18:06,510 --> 00:18:11,230
+الشيء هذا بترقم من الجهتين نفس الشيء المركب اللي
+
+215
+00:18:11,230 --> 00:18:16,230
+جابي اللي بقدرش أعمل فيه هذا الكلام بدي أكو أتضالك
+
+216
+00:18:16,230 --> 00:18:22,490
+و أتقرره لو كنت بده أرقم من هنا هذه CH2 CH3 لحظة
+
+217
+00:18:22,490 --> 00:18:28,720
+واحد اتنين هيصيروا ال Echlorتلاتة اربعة واحد اتنين
+
+218
+00:18:28,720 --> 00:18:34,200
+تلاتة اذا هذا كام ترقيم يحتمل واحد فقط واحد اتنين
+
+219
+00:18:34,200 --> 00:18:37,920
+تلاتة عشان ال glory يكونوا اقل ترقيم من هنا واحد
+
+220
+00:18:37,920 --> 00:18:41,140
+اتنين تلاتة اربعة خمسة بيكون اتنين تلاتة من هنا
+
+221
+00:18:41,140 --> 00:18:45,640
+واحد اتنين تلاتة اربعة خمسة بيصير تلاتة اربعة اذا
+
+222
+00:18:45,640 --> 00:18:52,420
+هذا كام ترقيم يحتمليحتمل ترقيم واحد فقط لكن المركب
+
+223
+00:18:52,420 --> 00:18:56,880
+اللي بعده المتماثل لو انا رقمته زي ما انتوا شايفين
+
+224
+00:18:56,880 --> 00:19:06,100
+بالازرق صح و لو انا رقمته بالاحمر صح طيب اللي رقمت
+
+225
+00:19:06,100 --> 00:19:12,660
+بالازرق كتبت المركب 2R3S23Diclorobutane
+
+226
+00:19:12,660 --> 00:19:17,390
+طب و اللي بده ترقم بالاحمر شو هتكتب؟الـ 2 ما احنا
+
+227
+00:19:17,390 --> 00:19:21,950
+عارفين ان هذه R و هذه S بغض النظر عن الترقيم هتكتب
+
+228
+00:19:21,950 --> 00:19:25,270
+2S3R
+
+229
+00:19:25,270 --> 00:19:30,930
+الآن اي جواب اللي بدنا نعتبره صح الجوابين صح هذا
+
+230
+00:19:30,930 --> 00:19:36,610
+إله اسمين هذا إله اسمين لأنه متماثل وعشانك المدرس
+
+231
+00:19:36,610 --> 00:19:40,250
+اللي بده يصلح بيجيبلكوا هذا المركب ويقولكوا اعطوه
+
+232
+00:19:40,250 --> 00:19:45,680
+اسمهذا الجواب يبدو يعتبره صح وهذا الجواب يبدو
+
+233
+00:19:45,680 --> 00:19:49,600
+يعتبره صح لسبب بسيط انه مافيه فارق نهائي بين انكوا
+
+234
+00:19:49,600 --> 00:19:54,280
+ترقموه من هنا او من هنا الان نفس الشيء في المركب
+
+235
+00:19:54,280 --> 00:19:58,900
+التاني لما رقمناه بالازرق واحد اتنين تلاتة اربعة
+
+236
+00:19:58,900 --> 00:20:05,140
+طب لو واحدة عملتله ترقيم تاني بالاحمر ايش هتكتبوه؟
+
+237
+00:20:05,140 --> 00:20:11,040
+two R three S الان اتطلعوا هذا أحد أسماء two S
+
+238
+00:20:11,040 --> 00:20:19,770
+three Rهذا أحد أسمائه 2R3S
+
+239
+00:20:19,770 --> 00:20:28,590
+و هذا 2R3S لأن الجزء ببساطة متماثل لأن هذا الجزء
+
+240
+00:20:28,590 --> 00:20:33,490
+ببساطة متماثل بياخد اسمين و هدول الشكلين بيكونوا
+
+241
+00:20:33,490 --> 00:20:38,710
+مركب واحد مش مركبينواضح؟ مركّب واحد وبتسمى
+
+242
+00:20:38,710 --> 00:20:42,110
+بطريقتين، الآن إذا اتفقنا إن هدولة they are the
+
+243
+00:20:42,110 --> 00:20:46,250
+same compound، بأكتر من طريقة فرجيتكم، اللي بدأ من
+
+244
+00:20:46,250 --> 00:20:49,710
+خلال الإشارات، إنه يلهم نفس الإشارات، أيه؟ يلهم
+
+245
+00:20:49,710 --> 00:20:56,750
+نفس الإشارات ولا لأ؟2R 3S .. 2S 3R .. 2S 3R .. 2S
+
+246
+00:20:56,750 --> 00:21:04,650
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+247
+00:21:04,650 --> 00:21:05,570
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+248
+00:21:05,570 --> 00:21:05,730
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+249
+00:21:05,730 --> 00:21:05,930
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+250
+00:21:05,930 --> 00:21:06,830
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+251
+00:21:06,830 --> 00:21:06,830
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+252
+00:21:06,830 --> 00:21:14,070
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+253
+00:21:14,070 --> 00:21:21,840
+2S 3R .. 2S 3Rوغيرهم سواء سمته 2R3S او 2S3R هو نفس
+
+254
+00:21:21,840 --> 00:21:26,100
+المركب له اسميننفس المركب له اسمين شو اللي عمله
+
+255
+00:21:26,100 --> 00:21:31,660
+الاسمين التماثل اذا لو انا بجاجي اسأل ببساطة لو
+
+256
+00:21:31,660 --> 00:21:35,480
+واحدة ع طول بده تعرف انه عندها اربع مركبات ولا
+
+257
+00:21:35,480 --> 00:21:40,320
+تلاتة ايش اول ما بده تطلع عليه في الجزء انه هل يا
+
+258
+00:21:40,320 --> 00:21:44,460
+ترى هذا الجزء اللي عنده فيه تماثل ولا لا اذا فيه
+
+259
+00:21:44,460 --> 00:21:49,620
+تماثل ع طول بده تحكي عن كام مركبعن تلاتة مافيش
+
+260
+00:21:49,620 --> 00:21:53,820
+تماثل بده تحكي عن أربع يعني لو مثلا سألكوا هذا
+
+261
+00:21:53,820 --> 00:22:05,280
+السؤال CH3 CHBR CHCL CH3 كام Cairo Center فيه؟هن و
+
+262
+00:22:05,280 --> 00:22:09,200
+هن قبل ما ارسم ايزو مارزو اتعب كام ايزو مارزو
+
+263
+00:22:09,200 --> 00:22:14,480
+تتوقعوا له اربعة عطول اربعة ليش لانه انا لو جسمت
+
+264
+00:22:14,480 --> 00:22:18,260
+بين هدولة two chiral centers هذي الظرات مش هى هذي
+
+265
+00:22:18,260 --> 00:22:25,060
+الظرات هنا عندكم H و CL هنا H .. خلاص انتهى واضح؟
+
+266
+00:22:25,060 --> 00:22:31,600
+و هكذاواضح، الان هذا المركب اللي فيه تماثل داخلي،
+
+267
+00:22:31,600 --> 00:22:37,860
+لو انتوا بتتأملوا فيه بعمق شوية، بتحسوا انه اللي
+
+268
+00:22:37,860 --> 00:22:44,250
+خلّاه يصيرنفس المركب و اقدر الفه انه انا لو اني
+
+269
+00:22:44,250 --> 00:22:48,650
+اتخيلت مرايا في نص المركب هذا النص اللى فوق صورة
+
+270
+00:22:48,650 --> 00:22:52,770
+النص اللى تحت فى المرأة ولا لأ طلعوا معاك هى ال CL
+
+271
+00:22:52,770 --> 00:23:00,790
+اقبالها CL ال H H ال مثل مثل اذا one half of the
+
+272
+00:23:00,790 --> 00:23:04,170
+molecule is the mirror image of the other half ولا
+
+273
+00:23:04,170 --> 00:23:10,660
+لأ هذا النص هو صورة هذا النص فى المرأةواضح الكلام؟
+
+274
+00:23:10,660 --> 00:23:14,420
+زي الناس اللي بتطلعوا على كروت الشدة إذا عمركوا
+
+275
+00:23:14,420 --> 00:23:18,780
+شفتوها بتشوفوا الرسومات اللي فيها البني آدم هيك او
+
+276
+00:23:18,780 --> 00:23:24,620
+بصر هيك بعدين هذا
+
+277
+00:23:24,620 --> 00:23:29,540
+زيه بالظبط .. هذا زيه بالظبط أنه النص هذا .. صورة
+
+278
+00:23:29,540 --> 00:23:37,180
+النص هذا في المرأةواضح؟ الان هذا المركب كأنه حقيقة
+
+279
+00:23:37,180 --> 00:23:42,380
+يحتوي على مركبين كأنه هذا مركب بإمكانكوا تتخيلوه و
+
+280
+00:23:42,380 --> 00:23:47,540
+هذا مركب تاني و هاي هم بس متصلين في بعض و من البعض
+
+281
+00:23:47,540 --> 00:23:52,760
+لو إجيت بديت أفكر بعمق شوية هذا لو إنه حطناه لوحده
+
+282
+00:23:52,760 --> 00:23:59,810
+في المرآة بيطلع كايران و إلهrotation وهذا لو حطيته
+
+283
+00:23:59,810 --> 00:24:04,450
+لوحده في المرأة كايرة له rotation طيب لو أخدت
+
+284
+00:24:04,450 --> 00:24:09,530
+مليون جزء من المركب الكلي كده يكون من هذا النص
+
+285
+00:24:09,530 --> 00:24:15,370
+مليون و من هذا النص مليون و المليونين عكس بعض صار
+
+286
+00:24:15,370 --> 00:24:21,750
+هذا بنفسه يشبه إيش؟Racemic mixture اللى أخدناه
+
+287
+00:24:21,750 --> 00:24:25,510
+المرة الماضية لما كنا نقولكوا لو كان عندى خليط
+
+288
+00:24:25,510 --> 00:24:31,050
+متساوي من two isomers شو سمناه؟ Racemic mixture
+
+289
+00:24:31,050 --> 00:24:35,850
+واحد منهم بيلف يمين التانى اشمال قداش بيكون
+
+290
+00:24:35,850 --> 00:24:41,240
+بالمجمل ال rotation له؟ سفرالـ Racemic mixture
+
+291
+00:24:41,240 --> 00:24:45,460
+بيكون optically active ولا inactive؟ optically
+
+292
+00:24:45,460 --> 00:24:48,880
+inactive ليش optically inactive؟ لأنه فيه عدد
+
+293
+00:24:48,880 --> 00:24:54,240
+متساوي من ال enantiomers بيلغوا بعض الان هذا تماما
+
+294
+00:24:54,240 --> 00:24:58,700
+يشبه الracemic mixture كأنه هاي نص و هاي نص هدول
+
+295
+00:24:58,700 --> 00:25:04,040
+عكس بعض ولا لا؟ واحد R و واحد S الجزء الكبير لو
+
+296
+00:25:04,040 --> 00:25:09,210
+منه مليون كدهش فيه من هذا؟ و من هذا؟أذا هذا
+
+297
+00:25:09,210 --> 00:25:13,330
+racemic mixture كأنه بامتياز بس موجود في مركب واحد
+
+298
+00:25:13,330 --> 00:25:17,550
+فهذا المركب بالمجمل بيكون optically active ولا
+
+299
+00:25:17,550 --> 00:25:24,070
+inactive هالمركب العجيب هذا المتماثل اللي موجود ال
+
+300
+00:25:24,070 --> 00:25:28,390
+configuration فيه لنصه عكس التاني اللي نصه صورة
+
+301
+00:25:28,390 --> 00:25:32,270
+بعض أو صورة نص التاني في المرآة أخد اسم في ال
+
+302
+00:25:32,270 --> 00:25:36,910
+stereo chemistry بيسميه meso compound أو
+
+303
+00:25:36,910 --> 00:25:42,570
+mesostructureلحظة الان لو بدنا نقرأ ايش تعريف ال
+
+304
+00:25:42,570 --> 00:25:47,170
+meso compound كل الكلام هذا معرف هنا كل اللي حكينا
+
+305
+00:25:47,170 --> 00:25:53,050
+ال meso compound is an achiral diastereomer of the
+
+306
+00:25:53,050 --> 00:25:56,450
+compound achiral يعني optically inactive شوفنا ليش
+
+307
+00:25:56,450 --> 00:26:02,470
+انه achiral و ليش انه optically inactiveرغم أنه في
+
+308
+00:26:02,470 --> 00:26:06,750
+مركز استيريوجينيك كم مركز استيريوجينيك فيه؟ اتنين
+
+309
+00:26:06,750 --> 00:26:11,630
+لكن هو بالمحصلة كايرال ولا اكايرال؟ اكايرال
+
+310
+00:26:11,630 --> 00:26:14,190
+optical and active although it contains
+
+311
+00:26:14,190 --> 00:26:18,030
+stereogenic centers الان its stereogenic centers
+
+312
+00:26:18,030 --> 00:26:23,190
+have opposite configurations يعني لازم واحد R
+
+313
+00:26:23,190 --> 00:26:26,970
+والتاني S هذا اللي بيكون ال mesocompound او نفس
+
+314
+00:26:26,970 --> 00:26:32,470
+المركب one half of the molecule isThe mirror image
+
+315
+00:26:32,470 --> 00:26:37,330
+of the other half اللي في هذه المواصفات بنقول انه
+
+316
+00:26:37,330 --> 00:26:43,520
+ميزو كومباوند بيكون مركب واحد مشمش مركبين
+
+317
+00:26:43,520 --> 00:26:46,160
+optically inactive يعني لو جينا سئلناكوا في
+
+318
+00:26:46,160 --> 00:26:49,360
+الامتحان ميزو كومباوند is optically active or
+
+319
+00:26:49,360 --> 00:26:55,260
+inactive؟ inactive الميزو كومباوند if مركب متماثل
+
+320
+00:26:55,260 --> 00:26:58,680
+لما اجي ارسم عندى two R three R two S three S و
+
+321
+00:26:58,680 --> 00:27:02,880
+two R three S او التانية من اللي فيهم بتكون ميزو؟
+
+322
+00:27:02,880 --> 00:27:09,000
+اللي فيها هدول عكس بعض يعني اللي بتكون RR او SS كل
+
+323
+00:27:09,000 --> 00:27:13,630
+واحدة منهم فردة in andيعني هذه لو أخدتها لحالها
+
+324
+00:27:13,630 --> 00:27:19,130
+optically active لو
+
+325
+00:27:19,130 --> 00:27:23,650
+عملت خليط متساوي من هدول الاتنين بيصير عند راسمك
+
+326
+00:27:24,520 --> 00:27:28,120
+mixture بيصير optical inactive لو أخدت من واحدة
+
+327
+00:27:28,120 --> 00:27:33,360
+اكتر من التانية زي ما اتعلمنا بيصير النتج نتاج
+
+328
+00:27:33,360 --> 00:27:38,600
+التنتين لكن هذا المركب هذا المركب اللي بيميزه انه
+
+329
+00:27:38,600 --> 00:27:43,100
+واحدة منه R والتانية S اذا انا لما بتعرف ال mezzo
+
+330
+00:27:43,100 --> 00:27:47,380
+compound في المركب المتماثل اللي بيكون منه واحدة R
+
+331
+00:27:47,380 --> 00:27:53,360
+والتانية S هذا ال mezzo compound والمجموع بيطلع
+
+332
+00:27:54,340 --> 00:27:59,240
+تلات مركبات في النهاية الان لو اتيت سألة طيب يا
+
+333
+00:27:59,240 --> 00:28:02,700
+تورا قولنا احنا اكيد بين هذا و هذا العلاقة they
+
+334
+00:28:02,700 --> 00:28:06,720
+are enantiomers طب لو اي واحد من هذول ال
+
+335
+00:28:06,720 --> 00:28:11,520
+enantiomers قرنته بال meso compound اه طلعوا two
+
+336
+00:28:11,520 --> 00:28:18,320
+are نفس الاشي هدوله واضح نفس الشي و three are
+
+337
+00:28:18,320 --> 00:28:24,870
+three asعكس بعض، اشي نفسه، اشي عكسه، فين VR؟ ده
+
+338
+00:28:24,870 --> 00:28:30,950
+يستيريو مارسي، فين VR؟ ده يستيريو مارسي بتايع ليه؟
+
+339
+00:28:30,950 --> 00:28:35,490
+بيكفي على موضوع ال two chiral centers الآن في
+
+340
+00:28:35,490 --> 00:28:41,850
+عندكم مجموعة من الأسئلة كيف توجدوا العلاقة بين
+
+341
+00:28:41,850 --> 00:28:47,080
+المركبين حتى لو رسمناهم بطرق مختلفةلاحظوا هذه
+
+342
+00:28:47,080 --> 00:28:50,980
+المُركّبات مرسومة بطرق مختلفة تماما مرة الـH لفوق
+
+343
+00:28:50,980 --> 00:28:54,820
+و مرة الـH على الجانب لكنهم نفس المُركّب بالمناسبة
+
+344
+00:28:54,820 --> 00:29:00,060
+يعني من ناحية structure أو روابط يعني كاربون
+
+345
+00:29:00,060 --> 00:29:04,280
+الأولى حملة PR و CL و بعدين CH3 و هاي الكاربون
+
+346
+00:29:04,280 --> 00:29:07,680
+اللي هو حملة PR و CL و بعدين CH3 يعني لو هذا و هذا
+
+347
+00:29:07,680 --> 00:29:13,090
+كنت بدأ أسميهم one-bromo one-chloro-ethaneمرة
+
+348
+00:29:13,090 --> 00:29:18,290
+تانية هاي carbon واحد هاي اتنين شو هتسموه وان
+
+349
+00:29:18,290 --> 00:29:25,500
+برومو وان كلوروإيه ثاني الار هدول الاتنين اللي
+
+350
+00:29:25,500 --> 00:29:29,680
+مرسومين بيدي العلاقة بينهم مش مرسومين بطريقة اللي
+
+351
+00:29:29,680 --> 00:29:33,180
+بالعين المجردة أشوف أنهم بينيهم مرسومين زي بعض أو
+
+352
+00:29:33,180 --> 00:29:37,000
+كل واحدة عكس التانية مرسومين بطرق مختلفة إذا على
+
+353
+00:29:37,000 --> 00:29:42,200
+طول ماليش حل إلا أحدد ال configuration أحددهم بضوء
+
+354
+00:29:42,200 --> 00:29:46,880
+هذا طلع R و هذا R then they are the same compound
+
+355
+00:29:46,880 --> 00:29:53,920
+واضح؟ الآن جيبنالكم مركبين تانينكم carbon هذا لو
+
+356
+00:29:53,920 --> 00:29:59,540
+بدكوا تسموه المركب هذا أطول سلسلة فيه قداش أربعة
+
+357
+00:29:59,540 --> 00:30:09,160
+واحد اتنين اعلم على أطول سلسلة CH3CCCH3
+
+358
+00:30:09,160 --> 00:30:17,440
+إذا هذا المركب اللي عندى بيوتين شو بيحمل بيوتين؟ع
+
+359
+00:30:17,440 --> 00:30:21,920
+نمره 2 برومه ع نمره 3 كلور ترقيب واحد عندي عشان
+
+360
+00:30:21,920 --> 00:30:26,340
+اخلي البروم اقل ما يمكن اتنين برومه ثلاثة ثلاثة
+
+361
+00:30:26,340 --> 00:30:27,620
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+362
+00:30:27,620 --> 00:30:29,600
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+363
+00:30:29,600 --> 00:30:36,300
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+364
+00:30:36,300 --> 00:30:44,220
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+365
+00:30:44,220 --> 00:30:50,050
+ثلاثة ثأحدد R و S لما أعملهم بهدوء بتعملهم في
+
+366
+00:30:50,050 --> 00:30:56,550
+البيت هنا two S and two R انبينين عكس بعض three S
+
+367
+00:30:56,550 --> 00:31:01,850
+and three R the same then they are diastereomers
+
+368
+00:31:01,850 --> 00:31:05,730
+كذلك
+
+369
+00:31:05,730 --> 00:31:11,930
+الحال هذا المركب هي أطول سلسلة فيهنطلع عليها واحد
+
+370
+00:31:11,930 --> 00:31:15,810
+اتنين تلاتة اربعة ع تنين برم وع تلاتة كلور وهذه
+
+371
+00:31:15,810 --> 00:31:20,350
+أطول السلسلة واحد اتنين تلاتة اربعة ع تنين برم وع
+
+372
+00:31:20,350 --> 00:31:28,710
+تلاتة كلور نحدد له R وS two S two R three S three
+
+373
+00:31:28,710 --> 00:31:37,170
+R الترقيم من هناك كل شيء عكس بعضين VR انانشومارز
+
+374
+00:31:37,170 --> 00:31:41,670
+اللي بعده نفس الشيء لو عملته بهدوءthe same
+
+375
+00:31:41,670 --> 00:31:46,270
+compound واضح؟ the same compound طبعا انتوا بدكوا
+
+376
+00:31:46,270 --> 00:31:51,970
+تحذروا بس بحالة واحدة لما يكون المركب متماثل و
+
+377
+00:31:51,970 --> 00:31:57,010
+يطلع عندكم 2R 3S و التالية 2S 3R بدكوا ترجعوا
+
+378
+00:31:57,010 --> 00:32:00,770
+تفكروا بالإيش بال meso compound اللي هو the same
+
+379
+00:32:00,770 --> 00:32:04,910
+compoundلو كان المراكب متماثل الأمثل هذا اللي
+
+380
+00:32:04,910 --> 00:32:09,350
+قدامكم مش متماثل لأنه على جهة بروم و على جهة كلور
+
+381
+00:32:09,350 --> 00:32:15,150
+دائما التفكير وين بده يكون قف و أفكر لما يكون فيه
+
+382
+00:32:15,150 --> 00:32:19,490
+تماثل داخلي إذا في تماثل داخلي و طلع عندكم ال
+
+383
+00:32:19,490 --> 00:32:26,150
+configurations في المتماثل إذا طلع عندكم R و S و
+
+384
+00:32:26,150 --> 00:32:31,390
+جبالها S و Rthey are the same compound هذا الحكي
+
+385
+00:32:31,390 --> 00:32:37,610
+وين بيكون في المركبات المتماثلة بيكون المركب فعلا
+
+386
+00:32:37,610 --> 00:32:44,630
+ميزو لما أحكي عن مركبين ر أس و أس و ر طلعوا معاكم
+
+387
+00:32:44,630 --> 00:32:51,270
+if مركب فيه تماثل داخلي بنقول عنهم they are the
+
+388
+00:32:51,270 --> 00:32:56,130
+same compound أو بنقول this is a mezzo compound
+
+389
+00:32:56,130 --> 00:33:01,530
+وبيكون طبعا opticallyinactive بيكون optically
+
+390
+00:33:01,530 --> 00:33:05,810
+inactive الان
+
+391
+00:33:05,810 --> 00:33:13,230
+لو اجينا لتفاعلات او التفاعلات المرتبطة بال stereo
+
+392
+00:33:13,230 --> 00:33:17,590
+chemistry في ال stereo chemistry في عندى اكتر من
+
+393
+00:33:17,590 --> 00:33:21,520
+نوع من التفاعلاتأحد هذه التفاعلات بنسميه
+
+394
+00:33:21,520 --> 00:33:25,720
+generation of a chiral center يعني انتوا بدأتوا
+
+395
+00:33:25,720 --> 00:33:30,320
+بمركب مش فيه ولا chiral center اعملتوا chiral
+
+396
+00:33:30,320 --> 00:33:35,740
+center خلينا ناخد مثال بسيط لو قلنا لكوا بدنا نعمل
+
+397
+00:33:35,740 --> 00:33:44,340
+chlorination للبيوتين بتذكرين البيوتين CH3 CH2 CH2
+
+398
+00:33:45,570 --> 00:33:50,510
+CH3 هل يترى هذا في أي كايرال سنتر؟ لا في كربون
+
+399
+00:33:50,510 --> 00:33:55,770
+بتحمل أربع مجموعات الآن بدنا نشيل هيدروجين يا من
+
+400
+00:33:55,770 --> 00:34:00,590
+موقع واحد يا من موقع اتنين يعني انا لما بعمل ال
+
+401
+00:34:00,590 --> 00:34:04,370
+chlorineation على البيوتين كام ناتج كنا متوقعين
+
+402
+00:34:04,370 --> 00:34:08,630
+اللي بيطلع عندنا اتنين المركب الأول اللي بيجيب ال
+
+403
+00:34:08,630 --> 00:34:13,150
+chlorine على موقع واحد هل صار في كايرال سنتر؟ لا
+
+404
+00:34:14,270 --> 00:34:18,910
+تخيلوا لو بدأ أضع الكلور على موقع واحد CH2CL
+
+405
+00:34:43,960 --> 00:34:47,500
+فى كل الأحوال بيصير عندى carol center يعني تخيل لو
+
+406
+00:34:47,500 --> 00:34:50,320
+أنا حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+407
+00:34:50,320 --> 00:34:55,040
+و لو حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+408
+00:34:55,040 --> 00:34:59,820
+اتطلعوا بينهم سواء كعلاقة أو لو حسبتولهم R و S
+
+409
+00:34:59,820 --> 00:35:07,910
+هتلاحظوا ان هدول الاتنين عكس بعض Rانانشو مارزي
+
+410
+00:35:07,910 --> 00:35:13,250
+يعني هاي ال H نفترض CL و بعدين اثلو مثل مبينة R
+
+411
+00:35:13,250 --> 00:35:18,650
+this is S وهي هذي ال H بنشطبها CL مبينة S هاي ال
+
+412
+00:35:18,650 --> 00:35:23,970
+configuration لهدول اذا انا وين اعملت chiral
+
+413
+00:35:23,970 --> 00:35:27,830
+center ع موقع واحد ولا ع موقع اتنين ع موقع اتنين
+
+414
+00:35:27,830 --> 00:35:31,870
+وين بعمل chiral center بطلع عندى خليط من two
+
+415
+00:35:31,870 --> 00:35:36,810
+انانشو مارزيبطلع عندى خليط من two enansimers اذا
+
+416
+00:35:36,810 --> 00:35:40,270
+لو اجيت انا سألتكوا الان سؤال بالمجمل
+
+417
+00:35:40,270 --> 00:35:46,110
+لchlorination of butane كم مركب بيعطينى تلاتة
+
+418
+00:35:46,110 --> 00:35:50,130
+تلاتة تنسوش انه انا في شغل مش كاتبة لأنه خارج
+
+419
+00:35:50,130 --> 00:35:57,190
+الإطار تبعنا انه لو فعلنا على هذا بيعطينا CH2CL
+
+420
+00:35:57,190 --> 00:36:00,450
+اللى هو ال one chlorobutane هذا مافيه chiral
+
+421
+00:36:00,450 --> 00:36:08,390
+centersهذا يبدو يجي الكلورة ع موقع واحد او ع موقع
+
+422
+00:36:08,390 --> 00:36:12,530
+اتنين ع موقع واحد عمل كايرال سنتر اذا هو مركب واحد
+
+423
+00:36:12,530 --> 00:36:16,490
+ع موقع اتنين عمل كايرال سنتر و ايه اللي بيصير
+
+424
+00:36:16,490 --> 00:36:20,790
+كايرال سنتر بيطلع عندى كام مركب اتنين اذا مجموع
+
+425
+00:36:20,790 --> 00:36:25,310
+المركبات قداشر تلاتة طب لو قولتلى واحدة سميلي
+
+426
+00:36:25,310 --> 00:36:27,890
+التلات نواتج اللى بيطلعوا من ال chlorineation و ال
+
+427
+00:36:27,890 --> 00:36:32,010
+butane شو هتقرأواحد كلورو بيوتين واحد كلورو بيوتين
+
+428
+00:36:32,010 --> 00:36:35,930
+ممتازة ارتو
+
+429
+00:36:35,930 --> 00:36:40,970
+كلورو بيوتين و استو كلورو بيوتين فبال total كام
+
+430
+00:36:40,970 --> 00:36:45,810
+مركب طلعوا تلاتة لكن لو كان السؤال كام structural
+
+431
+00:36:45,810 --> 00:36:50,610
+isomer بيطلع عنده من ال chlorineation اتنين لأن
+
+432
+00:36:50,610 --> 00:36:54,710
+معنى structural isomer مواقع الارتباط لكلور يا
+
+433
+00:36:54,710 --> 00:37:00,470
+بترتبط ع واحد يا بترتبط ع اتنينهدولة اتنين stereo
+
+434
+00:37:00,470 --> 00:37:05,390
+isomers ال R2 كلورو بيوتين و ال S2 كلورو بيوتين
+
+435
+00:37:05,390 --> 00:37:09,670
+they have the same bonding الارتباط فيه مع موقع
+
+436
+00:37:09,670 --> 00:37:13,870
+ايش اتنين but different arrangement in space هدولة
+
+437
+00:37:13,870 --> 00:37:18,010
+stereo isomers فبدكوا تنتبهوا لما بنسألكوا في
+
+438
+00:37:18,010 --> 00:37:21,550
+المنطقة لما نيجي نقولكم ال chlorineation في بيوتين
+
+439
+00:37:21,550 --> 00:37:26,670
+producesتو Structural Isomers، الـ Structural
+
+440
+00:37:26,670 --> 00:37:30,770
+مواقع، يا بتيجي الكلور على واحد، يا على اتنين،
+
+441
+00:37:30,770 --> 00:37:35,590
+الآن اللي على اتنين، في منها اتنين Stereoisomers،
+
+442
+00:37:35,590 --> 00:37:43,130
+اللي هم الـR والـS، واضح؟العلى اتنين في منها two
+
+443
+00:37:43,130 --> 00:37:47,750
+stereoisomers الار والاسم طبعا عادة بفسروا هذا
+
+444
+00:37:47,750 --> 00:37:50,870
+الكلام احنا مش اتنين ركزنا على ال mechanism of
+
+445
+00:37:50,870 --> 00:37:55,590
+reaction بفسروا انه هذا التفاعل اول ما بيبدأ
+
+446
+00:37:55,590 --> 00:38:00,410
+بترتفع في ذرة هيدروجين بيصيروا هدولة التلاتة
+
+447
+00:38:00,410 --> 00:38:06,520
+planner في مستوى واحد يعني لو انا بدي اجي اتخيلليش
+
+448
+00:38:06,520 --> 00:38:10,780
+تم التفاعل على الجهتين؟ لما تم التفاعل على
+
+449
+00:38:10,780 --> 00:38:18,200
+الجهتين؟ ممكن ايه بسرعة اريكم باستعمال ال models و
+
+450
+00:38:18,200 --> 00:38:27,360
+بأمل انها ال models بتخدمنا اتخيلوا
+
+451
+00:38:27,360 --> 00:38:33,500
+معنا لو اتخيلنا ان في عندنا CH3 ال CH3 نتخيلهاذرة
+
+452
+00:38:33,500 --> 00:38:39,550
+كربون صمرة CH3تمام؟ لما أشيل H بيبقى عندى كام
+
+453
+00:38:39,550 --> 00:38:44,650
+هيدروجين؟ واحدة و إيش بيبقى عندى؟ مجموعة ال إفل
+
+454
+00:38:44,650 --> 00:38:48,770
+لسه ماجيبتش ال chlorine أنا بدي بهذا كيف بعمل
+
+455
+00:38:48,770 --> 00:38:52,830
+الإبدال؟ بشيل الهيدروجينة في الأول و بعدين بحط
+
+456
+00:38:52,830 --> 00:38:57,250
+بدالها chlorine فدولة كام رابطة حوالين الكربون؟
+
+457
+00:38:57,250 --> 00:38:58,910
+أربعة أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+458
+00:38:58,910 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+459
+00:38:59,790 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+460
+00:38:59,790 --> 00:39:06,750
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة
+
+461
+00:39:07,360 --> 00:39:13,760
+بمشي الحال هاي هذا صار بهذا الشكل بالظبط طلعوا في
+
+462
+00:39:13,760 --> 00:39:20,740
+مجموعة مثل و H و إثل و ال H الأخيرة شيلناها
+
+463
+00:39:20,740 --> 00:39:24,240
+رفعناها الآن بدنا نجيب ال chlorine تتفاعل
+
+464
+00:39:26,450 --> 00:39:29,650
+هذه الـ Intermediate للحظة برفعت الـ H الأولى
+
+465
+00:39:29,650 --> 00:39:33,330
+بلانر في مستوى واحد الكلور بإمكانها تيجي تهاجم
+
+466
+00:39:33,330 --> 00:39:37,470
+عليها من هنا و هدولا بتعجوا حلو ميك او من هنا
+
+467
+00:39:37,470 --> 00:39:43,910
+طالما انها بلانر في فرق ان الكلور هي جاية من بعيد
+
+468
+00:39:43,910 --> 00:39:49,130
+بفرق عندها انها تمشي من هنا او من هنا اطلع معي
+
+469
+00:39:49,130 --> 00:39:52,670
+شايفين هدول الممرين اللي في القاعة لو انا بدي اروح
+
+470
+00:39:52,670 --> 00:39:59,700
+لاخر نقطةبإمكاني أمشي من هنا و من هنا بشكل متساوي
+
+471
+00:39:59,700 --> 00:40:04,520
+ولا لأ؟ ماعندي مشكلة، بدي أروح لآخر نقطة وهي عندي
+
+472
+00:40:04,520 --> 00:40:08,240
+مصارين متكافئت كذلك الحال، هذا planner بدي تيجي
+
+473
+00:40:08,240 --> 00:40:12,200
+اكلور من برا تتفاعل عليه، ترد تعمل المجموعة
+
+474
+00:40:12,200 --> 00:40:16,180
+الرابعةإذا أتيت من هنا عملة انانشومر و إذا أتيت من
+
+475
+00:40:16,180 --> 00:40:20,660
+هنا عملة التاني الان من ناحية الاحتمالات متساوية
+
+476
+00:40:20,660 --> 00:40:25,440
+تماما و لذلك يظهر عندي راسيمك ميكسشر يعني يظهر
+
+477
+00:40:25,440 --> 00:40:30,220
+الاتنين و يظهرون بنسب متساوية يظهر الاتنين و
+
+478
+00:40:30,220 --> 00:40:34,100
+يظهرون بنسب متساوية فبصير المحصلة ان ال generation
+
+479
+00:40:34,100 --> 00:40:42,710
+of a chiral center produces راسيمك ميكسشرواضح؟ ال
+
+480
+00:40:42,710 --> 00:40:46,690
+generation of a chiral center produces a racemic
+
+481
+00:40:46,690 --> 00:40:53,110
+mixture الان لو قلنا بدل racemic mixture equal
+
+482
+00:40:53,110 --> 00:40:59,740
+number of enantiomers أكيد صح .. أكيد صحgeneration
+
+483
+00:40:59,740 --> 00:41:02,520
+of a chiral center produces racemic mixtures
+
+484
+00:41:02,520 --> 00:41:10,660
+لاحظوا هذه الجملة بالنسبة للكيميا ما بين الكيميا
+
+485
+00:41:10,660 --> 00:41:15,480
+اللي بيصنعوها البشر و ما بين خلق الله سبحانه
+
+486
+00:41:15,480 --> 00:41:21,070
+وتعالى بتعمل فرق كبير جدااليوم لما انا باجي في
+
+487
+00:41:21,070 --> 00:41:26,450
+المختبر بده احضر مركب و اعمل chiral center انا
+
+488
+00:41:26,450 --> 00:41:31,290
+مابتحكمش في الاحتمالات بطلع عندى خليط متساوي و
+
+489
+00:41:31,290 --> 00:41:36,090
+بعدين اتعب و افصله و هذا السبب ربما في انه في دوة
+
+490
+00:41:36,090 --> 00:41:41,360
+مثل الثاليدواميد كان بيطلع الخليطالمتساوي ال R و
+
+491
+00:41:41,360 --> 00:41:45,860
+ال S لمنهم واحد مفيد و واحد ضار و عمل مشاكل كتير
+
+492
+00:41:45,860 --> 00:41:50,160
+كل ما بشغل في المختبر المختبر بطلعلي خليط من
+
+493
+00:41:50,160 --> 00:41:52,940
+المركبين اذا مش عندى chiral center انا بدي اعمله
+
+494
+00:41:52,940 --> 00:41:57,460
+بطلعلي .. بطلعلي ايش؟ racemic mixture الان في
+
+495
+00:41:57,460 --> 00:42:02,570
+الطبيعة فيه انزيماتالانزيمات كأنها بتاخد بإيدي
+
+496
+00:42:02,570 --> 00:42:05,850
+المجموعة اللي جاية بالظبط بداخلها من جهة واحدة
+
+497
+00:42:05,850 --> 00:42:10,030
+ولذلك المنتجات الطبيعية بيطلع منها بس one in a
+
+498
+00:42:10,030 --> 00:42:16,750
+number هذا خلقههذا خلق الله يعني انا لما شغلة كون
+
+499
+00:42:16,750 --> 00:42:21,210
+بتحضرها الانزيمات و بتتحضر جوا الجسم بتلاقوا بيطلع
+
+500
+00:42:21,210 --> 00:42:26,330
+منها بس واحد لما اجي انا اعيد التفاعل بالمختبر و
+
+501
+00:42:26,330 --> 00:42:30,110
+بدون انزيمات و بكذا بيطلع عندى خليط متساوي من
+
+502
+00:42:30,110 --> 00:42:34,830
+التنين ولذلك اللى بده مركبات نقية يعني بده one in
+
+503
+00:42:34,830 --> 00:42:39,750
+one شمر ايش اسهل طريقة يعملها؟ ياخدها من مصادرها
+
+504
+00:42:39,750 --> 00:42:44,590
+الطبيعية اذا كانت تحضر في الطبيعةطبعا إذا كانت لا
+
+505
+00:42:44,590 --> 00:42:51,850
+تحضر في الطبيعة بده يجعب هذه المشكلة و يطلع عنده
+
+506
+00:42:51,850 --> 00:42:56,450
+خليط من التنين عشان ايه كده في الكيميا بيسموه ايش
+
+507
+00:42:56,450 --> 00:43:02,990
+Symmetric Synthesis Symmetric Synthesis ايش معنى
+
+508
+00:43:02,990 --> 00:43:08,350
+Symmetric انه بيطلع خليط متمافل من التنين جد بعض و
+
+509
+00:43:08,350 --> 00:43:15,290
+بعدين يقعد ايش يعمليفصل فيهم الآن بدأوا من جديد
+
+510
+00:43:15,290 --> 00:43:21,030
+يستعملوا طرق حديثة في ال synthesis و يضيفوا عوامل
+
+511
+00:43:21,030 --> 00:43:25,330
+حفازة اللي تخلى واحد من هدول يطلع بنسبة اكتر من
+
+512
+00:43:25,330 --> 00:43:30,490
+التانية او يكاد يكون يطلع نقي وجدتها اذا طلعوا مش
+
+513
+00:43:30,490 --> 00:43:35,790
+متساويات شو بدى اسم ال synthesis Asymmetric
+
+514
+00:43:35,790 --> 00:43:40,010
+synthesisواضح؟ يعني الـ symmetric synthesis بتطلع
+
+515
+00:43:40,010 --> 00:43:44,810
+الخليط متساوي الآن إذا صرت أضيف عوامل حفازة بطرق
+
+516
+00:43:44,810 --> 00:43:49,290
+معينة بتحذيرات بصير أشتغل ايش؟ asymmetric
+
+517
+00:43:49,290 --> 00:43:52,910
+synthesis اليوم اللي منكم بده تدرس كيميا وبعدين
+
+518
+00:43:52,910 --> 00:43:57,120
+تقول أنا بدي أخد جائزة نوبل في الكيمياBye Bye
+
+519
+00:43:57,120 --> 00:44:01,260
+Asymmetric Synthesis بدا تشتغل على ايش؟ Asymmetric
+
+520
+00:44:01,260 --> 00:44:05,420
+Synthesis تصير تتعلم كتير تضيف عوامل حفازة
+
+521
+00:44:05,420 --> 00:44:12,040
+بمواصفات معينة تخلي التفاعل تطلع واحدمايطلعش
+
+522
+00:44:12,040 --> 00:44:16,200
+التاني او طلع واحد مثلا بنسبة 90% و التاني بنسبة
+
+523
+00:44:16,200 --> 00:44:20,800
+10% على سبيل المثال و كل ما جدت تطلع واحد تماما و
+
+524
+00:44:20,800 --> 00:44:26,500
+تلغي التاني كل ما كانت تمثل ايش نجاح كبير في الشغل
+
+525
+00:44:26,500 --> 00:44:31,720
+افهمنا اذا المشكلة ما بين الطبيعة و ما بين المختبر
+
+526
+00:44:31,720 --> 00:44:36,380
+المختبر هو وضع الطبيعيبطلّع لي خليط الطبيعة بوضعها
+
+527
+00:44:36,380 --> 00:44:42,120
+الطبيعي بطلّع واحد الان العالم بيسعوا نحو ايش؟ ان
+
+528
+00:44:42,120 --> 00:44:45,960
+يقتربوا من الطبيعة انهم يقدروا يطلعوا واحد و لو
+
+529
+00:44:45,960 --> 00:44:51,120
+بنسبة كبيرة في ما يسمى بالعلم ايش؟ asymmetric
+
+530
+00:44:51,120 --> 00:44:55,620
+synthesis بس بالتأكيد هذا الموضوع كتير متطور
+
+531
+00:44:55,620 --> 00:44:59,860
+بالنسبة لطالب organic يعني ما لم تتخصصوا كيميا مش
+
+532
+00:44:59,860 --> 00:45:02,460
+هتشتغلوا فيه بنكمل ان شاء الله في مرات
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6a0086bdc8f9d20c17f508d3310c58f34b63a4b0
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y.srt
@@ -0,0 +1,1487 @@
+
+1
+00:00:19,520 --> 00:00:23,540
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في 
+
+2
+00:00:23,540 --> 00:00:28,820
+موضوع ال acidity و عرفنا بالظبط ايش معنى الأحماض و
+
+3
+00:00:28,820 --> 00:00:35,360
+وضحنا انه مهم جدا نعرف ايش معنى ال acidity 
+
+4
+00:00:35,360 --> 00:00:39,820
+constant و قولنا كل ما ال PKA قلّت كل ما الحامض
+
+5
+00:00:39,820 --> 00:00:45,000
+بيكون ايش أقوى بعد هي طرحنا سؤال و أعطينا عليه 
+
+6
+00:00:45,000 --> 00:00:49,940
+إجابة عامة بدون ما ندخل بإنّفلة تفصيلية كان السؤال
+
+7
+00:00:49,940 --> 00:00:54,540
+لما بدأ نقارن حامض مع حامض تاني من الأقوى و من 
+
+8
+00:00:54,540 --> 00:00:59,250
+الأقل بدأ نعتمد على ايش لما بنقارن الأحماض في قوتها
+
+9
+00:00:59,250 --> 00:01:05,270
+بدي أنظر لل أيون السالب اللي بتكون نتيجة اللي هو 
+
+10
+00:01:05,270 --> 00:01:10,430
+تحلل الحمض بالماء هذا ال أيون السالب بدي الشحنة
+
+11
+00:01:10,430 --> 00:01:14,110
+تبعته تكون أقل ما يمكن هذا اللي بنسميه إيش احنا ال
+
+12
+00:01:14,110 --> 00:01:18,470
+stability ل ال negative أيون معنى ال stability أن
+
+13
+00:01:18,470 --> 00:01:21,710
+الشحنة تكون أقل ما يمكن الآن إيش اللي بيقلل
+
+14
+00:01:21,710 --> 00:01:27,060
+الشحنة؟ تلات تأثيرات ممكن الحجم اللي بيحمل الشحنة
+
+15
+00:01:27,060 --> 00:01:30,920
+و ممكن شيء نسميه ال inductive effect اللي هو تأثير
+
+16
+00:01:30,920 --> 00:01:36,180
+المساعدة و ممكن شيء نسميه ال resonance effect
+
+17
+00:01:36,180 --> 00:01:42,660
+أعطينا بعض الأمثلة لكن خلينا نأكد الآن مثلاً لو
+
+18
+00:01:42,660 --> 00:01:48,420
+أجينا نقارن ال phenols مع الالكوهولز العادية
+
+19
+00:01:48,420 --> 00:01:54,480
+الاليفاتك الالكوهولز بمعنى انا بدي اقارن ROH مع 
+
+20
+00:01:54,480 --> 00:01:59,320
+فنل OH لاحظوا المقطة الأولى انه لما يجي يعمل
+
+21
+00:01:59,320 --> 00:02:04,680
+المقارنة ويفهم المقارنة سابه هو من الحامض ايش كتب؟
+
+22
+00:02:04,680 --> 00:02:10,760
+الايون السالب يعني كتب انا R O minus وفنل O minus 
+
+23
+00:02:10,760 --> 00:02:17,990
+فالحكم هو ال Ion السالب الان هذا ال RO- الشحن
+
+24
+00:02:17,990 --> 00:02:22,450
+اللي موجود عليه ثابت على ال oxygen ما فيش فيها حركة
+
+25
+00:02:22,450 --> 00:02:25,970
+ما فيش فيها resonance ال oxygen ذرة صغيرة يعني
+
+26
+00:02:25,970 --> 00:02:29,710
+بيقول it cannot carry the negative charge صعب
+
+27
+00:02:29,710 --> 00:02:33,250
+عليها تحمل ال negative charge ولذلك ال Ion كله
+
+28
+00:02:33,250 --> 00:02:37,050
+بيكون unstable فلاحظوا الكلام ان ال charge is 
+
+29
+00:02:37,050 --> 00:02:43,570
+localized يعني محمولة على موقع واحد مش عملتها تتنجل 
+
+30
+00:02:43,570 --> 00:02:48,730
+localized متموضعة محمولة في موضع واحد عكسها ايش؟
+
+31
+00:02:48,730 --> 00:02:53,410
+delocalized فبيصير عندي كلمتين localized شيء على
+
+32
+00:02:53,410 --> 00:02:57,550
+موضع واحد delocalized زي ما انا اجي احمل هذا هيك 
+
+33
+00:02:57,550 --> 00:03:01,550
+بس عن ايد هذه و فقط لا غير هيك بيكون هذا الحمل 
+
+34
+00:03:01,550 --> 00:03:07,590
+localized الآن لو كنت بنجله بيكون De-localized واضح 
+
+35
+00:03:07,590 --> 00:03:13,210
+فإذا بنلاحظ انه بالفينول الشحنة السالبة في أحد ال 
+
+36
+00:03:13,210 --> 00:03:16,350
+resonance structures على ال oxygen لكن لو عملنا
+
+37
+00:03:16,350 --> 00:03:20,450
+حركة إلكترونات زوج من الإلكترونات بهذا الشكل و
+
+38
+00:03:20,450 --> 00:03:23,710
+حركنا ال bond هنلاحظ انها ممكن تصير على ال carbon 
+
+39
+00:03:23,710 --> 00:03:26,510
+اللي موجودة هنا بحركة تانية على ال carbon اللي
+
+40
+00:03:26,510 --> 00:03:29,750
+موجودة هنا بحركة تالتة على ال carbon لاحظوا انه 
+
+41
+00:03:29,750 --> 00:03:34,460
+بطّلت الشحنة محمولة على مكان واحد بطّلت localized
+
+42
+00:03:34,460 --> 00:03:39,000
+صارت delocalized هذا resonance واضح أو
+
+43
+00:03:39,000 --> 00:03:42,400
+delocalization يعني بيستعملوا كلمة resonance أو 
+
+44
+00:03:42,400 --> 00:03:46,900
+delocalization بنفس المعنى واضح ف because of the 
+
+45
+00:03:46,900 --> 00:03:52,360
+delocalization of the charge in phenoxide and ion
+
+46
+00:03:52,360 --> 00:03:56,540
+or anion لحظوا ال phenyl O minus شو بنسميه 
+
+47
+00:03:58,860 --> 00:04:02,960
+فينوكسايد أنا يعني يمكن سابقا حكينالكم هي اللي لو 
+
+48
+00:04:02,960 --> 00:04:09,300
+كانت هذه مثل O minus مثوكسايد مثل O minus إثوكسايد
+
+49
+00:04:09,300 --> 00:04:16,880
+HO minusHydroxide هيدروكسايد هيدروكسايد 
+
+50
+00:04:16,880 --> 00:04:17,360
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+51
+00:04:17,360 --> 00:04:20,000
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد 
+
+52
+00:04:20,000 --> 00:04:20,660
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+53
+00:04:20,660 --> 00:04:22,780
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+54
+00:04:22,780 --> 00:04:27,020
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+55
+00:04:27,020 --> 00:04:30,260
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد 
+
+56
+00:04:30,260 --> 00:04:37,420
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+57
+00:04:37,420 --> 00:04:43,720
+هيدروكسايد هيدروحوالي ستّ عشرة، خمس عشرة و نصّ و خمس
+
+58
+00:04:43,720 --> 00:04:47,340
+عشر و تسعة فلما نيجي نسأل ليش ال phenols are more
+
+59
+00:04:47,340 --> 00:04:51,140
+acidic than alcohols الجواب because of resonance 
+
+60
+00:04:51,140 --> 00:04:56,460
+or because of delocalization of its charge طبعا لو
+
+61
+00:04:56,460 --> 00:05:02,800
+صار عندي Nitrophenol ال delocalization بزيد يعني
+
+62
+00:05:02,800 --> 00:05:07,600
+الشحنة السالبة بالاضافة لإنها ممكن تنوجد على مواضع 
+
+63
+00:05:07,600 --> 00:05:12,500
+كثيرة كمان بيصير بإمكانها تنوجد على ذرات ال oxygen
+
+64
+00:05:12,500 --> 00:05:15,260
+بتاعون ال Nitro فبيصير 
+
+65
+00:05:17,450 --> 00:05:22,290
+ال Delocalization لل negative charge ايش ماله 
+
+66
+00:05:22,290 --> 00:05:27,270
+اكتر بيصير عندي more delocalization يعني الشحنة 
+
+67
+00:05:27,270 --> 00:05:31,350
+موزعة زي حمل بيحملوا اتنين اتريحوا شوية طب لو 
+
+68
+00:05:31,350 --> 00:05:36,630
+حملوا تلاتة افضل لو حملوا اربعة أسهل واضح الفكرة
+
+69
+00:05:36,630 --> 00:05:42,650
+فبالنيتروفينول عندي more delocalization ولذلك نزل 
+
+70
+00:05:42,650 --> 00:05:48,190
+النيتروفينول لقداش لسبعة و اتنين من عشرة ال PKA اذا
+
+71
+00:05:48,190 --> 00:05:52,510
+which is more acidic ال Nitrophenol is more acidic 
+
+72
+00:05:52,510 --> 00:05:57,290
+لانه فيه more resonance طب لو صارت Trinitrophenol
+
+73
+00:05:57,290 --> 00:06:02,970
+more and more فهيصل ل point two five وبناء على ذلك
+
+74
+00:06:02,970 --> 00:06:08,670
+سمّينا إيش احنا بكريك اسد ل Trinitrophenol هذه كلها
+
+75
+00:06:08,670 --> 00:06:12,850
+أمثلة على ال Resonance Effect الآن لو كنت بدي 
+
+76
+00:06:12,850 --> 00:06:17,290
+أمثلة على ال Inductive Effect لو بدأت بالإيثانول 
+
+77
+00:06:17,290 --> 00:06:24,150
+فيه تلت مجموعات هيدروجين CH2OH CH3 طيب لو حطيت
+
+78
+00:06:24,150 --> 00:06:28,830
+واحدة من الهيدروجين زي كلور بتبدأ هذه الكلور تسحب
+
+79
+00:06:28,830 --> 00:06:30,210
+جزء من الشحنة 
+
+80
+00:06:32,900 --> 00:06:36,200
+افترضوا ان كلهم فيهم شحنة سالبة قلّلت الشحنة
+
+81
+00:06:36,200 --> 00:06:41,580
+السالبة هذا ال effect سحب الشحنة with drawing of 
+
+82
+00:06:41,580 --> 00:06:47,930
+the charge أو إعطاء شحنة ايش بنسميه احنا Inductive
+
+83
+00:06:47,930 --> 00:06:51,050
+Effect فال Inductive Effect هو سحب الشحنة أو
+
+84
+00:06:51,050 --> 00:06:55,470
+إعطائها مش نقلها لأ الشحنة موجودة هنا لكن افترض
+
+85
+00:06:55,470 --> 00:07:00,090
+الشحنة هنا عشر وحدات سحبنا منها واحدتين ال CL اللي
+
+86
+00:07:00,090 --> 00:07:05,050
+انا بتحب السالب سحبت واحدتين جديش صفية بدل عشرة
+
+87
+00:07:05,050 --> 00:07:11,820
+ثمانيه واضح؟ الآن لو حطيت انتين CL صار عندي more
+
+88
+00:07:11,820 --> 00:07:17,220
+and more with the drawing لو حطيت تلاتة CL كلهم 
+
+89
+00:07:17,220 --> 00:07:22,160
+بيسحبوا الشحنة السالبة بناء على ذلك ال effect هنا 
+
+90
+00:07:22,160 --> 00:07:25,480
+لما انا بقول ان ال trichloroethanol is more acidic
+
+91
+00:07:25,480 --> 00:07:28,240
+than dichloroethanol than chloroethanol than
+
+92
+00:07:28,240 --> 00:07:32,340
+ethanol هذا ايش اللي بنسميه احنا inductive effect
+
+93
+00:07:32,340 --> 00:07:39,750
+واضح؟ لمّا قررنا ال RSH و ال ROH مين اللي قلنا
+
+94
+00:07:39,750 --> 00:07:45,010
+فيهم أقوى كقواعد؟ RSH طب الآن بنقول ال RSH أقوى من 
+
+95
+00:07:45,010 --> 00:07:51,310
+ال ROH why because of the size إذن هاي نعرفه
+
+96
+00:07:51,310 --> 00:08:00,410
+طيب لو بدأ اجي اقول ال ARSH مع ال ROH مين أقوى؟ 
+
+97
+00:08:02,130 --> 00:08:06,990
+because of the size لحظوا ال AR هنا و ال AR هنا
+
+98
+00:08:06,990 --> 00:08:11,890
+فيهم resonance فبطل ال resonance هو السبب يعني ال 
+
+99
+00:08:11,890 --> 00:08:16,150
+aromatic او البنزينة هنا و البنزينة هنا فينول و
+
+100
+00:08:16,150 --> 00:08:22,040
+ثيوفينول ال AR عامل مشترك اللي بيعمل resonance بناء
+
+101
+00:08:22,040 --> 00:08:25,900
+على ذلك لو حد .. لو بدنا نجيب سؤال arsh is more
+
+102
+00:08:25,900 --> 00:08:30,240
+acidic than aroh due to resonance غلط لأنه هنا فيه
+
+103
+00:08:30,240 --> 00:08:33,680
+resonance و هنا فيه resonance طب هاش المختلف
+
+104
+00:08:33,680 --> 00:08:41,950
+sulfur و oxygen اذا because of the size لكن لو اجيت
+
+105
+00:08:41,950 --> 00:08:49,470
+قلت لكم بدأ أقارن ARSH و RSH لاحظوا ال sulphur
+
+106
+00:08:49,470 --> 00:08:53,990
+sulphur the same size إذا وين صار الفرق؟ AR ولا
+
+107
+00:08:53,990 --> 00:09:00,310
+R إذا why because of resonance
+
+108
+00:09:04,470 --> 00:09:11,150
+لو كنت بدأ أقارن A R O H مع R O H ال O و ال O نفس 
+
+109
+00:09:11,150 --> 00:09:16,870
+ال size اللي اتغير R و A R إذا مين أعلى؟ A R 
+
+110
+00:09:16,870 --> 00:09:23,650
+because of resonance بضحك الفكرة لما بنعمل مقارنة 
+
+111
+00:09:23,650 --> 00:09:29,630
+الآن لو إجيت على هدولة كلهم و قولت بدأ أستطب كل
+
+112
+00:09:29,630 --> 00:09:37,500
+الكلام وبلغة عربية بسيطة جدا بدي اقول من الأقوى و من 
+
+113
+00:09:37,500 --> 00:09:44,240
+الأضعف في الأربعة ال ARSH هو أقوى حاجة ال ARSH
+
+114
+00:09:44,240 --> 00:09:51,560
+هو الأقوى the strongest وال ROH هو الأضعف 
+
+115
+00:09:54,370 --> 00:10:00,150
+يعني لو بنقارن ال alcohols و ال thyols و ال phenols
+
+116
+00:10:00,150 --> 00:10:04,330
+و ال thyophenols أقوى واحد فيهم ال thyophenol و
+
+117
+00:10:04,330 --> 00:10:08,710
+أضعف واحد فيهم بالحمضية اللي هو ايش ال alcohol هذا 
+
+118
+00:10:08,710 --> 00:10:14,970
+الكلام بينعكس على التفاعلات الكيميائية هذا الكلام 
+
+119
+00:10:14,970 --> 00:10:19,170
+الآن إنّ هذا الأضعف بنعكس على التفاعلات الكيميائية
+
+120
+00:10:19,170 --> 00:10:22,990
+وين بنعكس على التفاعلات الكيميائية مش احنا قاعدين
+
+121
+00:10:22,990 --> 00:10:28,010
+نقول هدولة أحماط مظبوط ولا لا طول عمرنا بنعرف
+
+122
+00:10:28,010 --> 00:10:35,170
+الجملة الشهيرة حمض زاد قاعدة ملح زاد ماء بناء على
+
+123
+00:10:35,170 --> 00:10:40,570
+ذلك لو اجيت أفاعل هدولة مثلا مع قاعدة قوية زي ال N
+
+124
+00:10:40,570 --> 00:10:53,890
+A O H زائد NaOH كلهم مش هم زائد قاعدة اه هلاحظ انّ 
+
+125
+00:10:53,890 --> 00:10:57,670
+تلاتة منهم بتفاعل و بيعطوا ملح زائد ماء واحد
+
+126
+00:10:57,670 --> 00:11:05,990
+مابتفعلش الا مابتفعلش هذا هذا بتفعل هذا بتفعل هذا
+
+127
+00:11:05,990 --> 00:11:11,040
+بتفعل واضح؟ طبعا لو قلنا لكم اكتبوا المعادلة،
+
+128
+00:11:11,040 --> 00:11:17,080
+عندنا مثال، لو أخدنا هذا ال ROH زي NAOH، إيش
+
+129
+00:11:17,080 --> 00:11:24,600
+كتبنا؟ No reaction لكن لو قلنا RSH زي NAOH،
+
+130
+00:11:24,600 --> 00:11:29,770
+ال H مع ال O H ايش بيعملوا؟ ميّه طول عمره و ال RS 
+
+131
+00:11:29,770 --> 00:11:36,350
+minus مع ال NA NA plus RS minus و بنفس الطريقة 
+
+132
+00:11:36,350 --> 00:11:45,830
+بإمكانكم تكتبوا ايش كل الأشياء RSH
+
+133
+00:11:45,830 --> 00:11:46,050
+مع 
+
+134
+00:11:57,410 --> 00:12:03,230
+فاهم الآن دائمًا إذا وجد عندك مش سؤال مش سؤالك هذا
+
+135
+00:12:03,230 --> 00:12:08,170
+ال specific مش سؤالك هذا ال specific لأ إذا أي
+
+136
+00:12:08,170 --> 00:12:15,110
+شغلة حطيت فيها متغيرين معناه ذلك مش هيكون عندك ثقة
+
+137
+00:12:15,110 --> 00:12:20,110
+كاملة انك بتقدر تاخد الجواب مباشرة إلا من التجربة 
+
+138
+00:12:20,110 --> 00:12:27,210
+و من قيمة ايش بتطلع التجربة ال PKA اذا صار عندك
+
+139
+00:12:27,210 --> 00:12:31,910
+متغيرين سؤالك انا بعتبره جيد انّه انت غيرتي هنا ال 
+
+140
+00:12:31,910 --> 00:12:37,970
+ar و r و هنا ال o و ال s و سألت مين الأقوى فيهم
+
+141
+00:12:37,970 --> 00:12:44,250
+كم متغير عندك اتنين الحل انك تبحثي تعمل التجربة و 
+
+142
+00:12:44,250 --> 00:12:48,550
+تشوف ال PKA لهذا و ال PKA لهذا و تعمل المقارنة
+
+143
+00:12:48,550 --> 00:12:54,180
+ولذلك في العلم دائمًا لما بتعملوا المقارنة بتثبتوا
+
+144
+00:12:54,180 --> 00:12:59,600
+جميع المتغيرات ما عدا متغير واحد بيصير بإمكانكم
+
+145
+00:12:59,600 --> 00:13:03,420
+تعملوله مقارنة و تعملوله قوانين يمكن هذا الكلام
+
+146
+00:13:03,420 --> 00:13:08,780
+أكثر شيء مر عليكم في منطقة الغازات ليش؟ لأن
+
+147
+00:13:08,780 --> 00:13:13,500
+الغازات لها أكتر من متغير الضغط و الحجم و عدد 
+
+148
+00:13:13,500 --> 00:13:19,790
+المولات و درجة الحرارة أربع متغيرات في الغازات واضح؟
+
+149
+00:13:19,790 --> 00:13:23,810
+الآن الغازات في النهاية كانت بتنجمع بمعادلة P في V
+
+150
+00:13:23,810 --> 00:13:28,570
+بساوي N في R في T pressure في volume بساوي number
+
+151
+00:13:28,570 --> 00:13:32,610
+of moles في R تابع الغازات في ال temperature الآن
+
+152
+00:13:32,610 --> 00:13:36,770
+لما كنت قادر اقول بدي أقارن ال volume مع ال 
+
+153
+00:13:36,770 --> 00:13:43,210
+temperature كنت أحط لنفس الكمية من الغاز عند نفس
+
+154
+00:13:43,210 --> 00:13:49,550
+الضغط واضح بعد ذلك تصبح المقارنة أصعب تعمل تجربة
+
+155
+00:13:49,550 --> 00:13:55,930
+الان هنا ال O و O مشتركات ال R و AR مختلفات سهل 
+
+156
+00:13:55,930 --> 00:14:01,650
+علي أعطي جواب واضح الفكرة؟ لكن هنا ال S أفضل من ال
+
+157
+00:14:01,650 --> 00:14:07,940
+O و ال AR أفضل من ال R ايش النتيجة؟ التجربة
+
+158
+00:14:07,940 --> 00:14:14,040
+المجموعة التجربة واضح؟ يعني ما فيش عندك جواب هذي
+
+159
+00:14:14,040 --> 00:14:16,880
+أفضل من هذي و هذي أفضل من هذي طب هذي أفضل من هذي 
+
+160
+00:14:16,880 --> 00:14:20,440
+بقدش و هذي أفضل من هذي بقدش عشان يطلع عندي جواب؟
+
+161
+00:14:20,440 --> 00:14:29,160
+لا بدّك تعمل التجربة واضح؟ سؤال جيد الآن لاحظوا معي
+
+162
+00:14:29,160 --> 00:14:32,340
+هل يا ترى الكيميائي 
+
+163
+00:14:33,600 --> 00:14:38,120
+بيستسلم؟ لا يعني سبحان الله زي ما بتقول آية كريمة 
+
+164
+00:14:38,120 --> 00:14:44,820
+و فوق كل ذي علم عليم واضح؟ يعني احنا قلنا الكحول 
+
+165
+00:14:44,820 --> 00:14:52,580
+هذا زائد NAOH لا يتفاعل طب ال NAOH كان تصنيف
+
+166
+00:14:52,580 --> 00:15:00,380
+strong base قاعدة قوية الان ال NAOH is a strong 
+
+167
+00:15:00,380 --> 00:15:05,360
+base مركب ايوني و قاعدة قوية طب حبيل غصب عنه
+
+168
+00:15:05,360 --> 00:15:11,000
+الكحول الفاعله ايش بنعمله بنجيبله very strong base
+
+169
+00:15:11,000 --> 00:15:16,460
+يعني بنجيبله قاعدة تكون اقوى من ال NAOH موجود
+
+170
+00:15:16,460 --> 00:15:20,860
+يعني بدل ما اجي افعله مع ال NAOH اللي strong 
+
+171
+00:15:20,860 --> 00:15:26,490
+base ممكن افعله مع NAH هذا المركب اسمه Sodium
+
+172
+00:15:26,490 --> 00:15:33,110
+Hydride الجزء القاعد فيه ايون H- الهيدرايد H-
+
+173
+00:15:33,110 --> 00:15:40,510
+واضح؟ ايش بنسمي هذا Sodium Hydride لاحظوا ال I
+
+
+
+223
+00:20:12,940 --> 00:20:18,520
+كنت على البروبين اضيف الماء في وجود H بلس وين كنت
+
+224
+00:20:18,520 --> 00:20:23,700
+احط الهيدروجين هان ال O-H هان اطلع البروبان to all
+
+225
+00:20:23,700 --> 00:20:27,780
+او to probanol او ايزو برو بالالكول ماكانش يطلع
+
+226
+00:20:27,780 --> 00:20:34,200
+هذا طب لو بدنا هذا شو كنا نعمل Antimarkovnikov
+
+227
+00:20:36,400 --> 00:20:40,420
+كنا نستعمل طريقة ال boron ال bh3 و توابعها
+
+228
+00:20:40,420 --> 00:20:46,540
+بترجعوها واضح؟ إذا الكحولات يمكن أن تحضر و أخدنا
+
+229
+00:20:46,540 --> 00:20:51,000
+هذا الكلام بالتفصيل من خلال إضافة الماء على ال
+
+230
+00:20:51,000 --> 00:20:56,860
+alkyls برضه طريقة تانية أخدناها لتحضير الكحولات
+
+231
+00:20:56,860 --> 00:20:59,440
+مين اتذكرنا فيها؟
+
+232
+00:21:04,290 --> 00:21:10,270
+الـ RX زائد الماء أو الـ OH ماينوس مش كنا ناخد هذه
+
+233
+00:21:10,270 --> 00:21:18,110
+المعادلة RX زائد H2O in general R OH لنيوكليوفيليك
+
+234
+00:21:18,110 --> 00:21:23,710
+سبستيوشن على ال الكلهيلايت شبتر ستة سواء كنا نفعله
+
+235
+00:21:23,710 --> 00:21:27,940
+مع نيوترال نيوكليوفايل او معit charged the
+
+236
+00:21:27,940 --> 00:21:32,680
+nucleophile واضح ال substitution إذا الطرق العامة
+
+237
+00:21:32,680 --> 00:21:38,340
+لتحضير الكحولات يا إما من ال RX بالإبدال يا إما من
+
+238
+00:21:38,340 --> 00:21:45,840
+ال alkenes بتفاعل إيش بنسميه الإضافة ما هو مع
+
+239
+00:21:45,840 --> 00:21:53,100
+الميه تفاعل إضافة addition reaction واضح الآن لو
+
+240
+00:21:53,100 --> 00:22:00,470
+إجينا بعد هيك على تفاعلاتالكحولات تفاعلات الكحولات
+
+241
+00:22:00,470 --> 00:22:05,210
+طبعا في زميلة لكم بس عشان يعني ما نغمطهاش حقها ان
+
+242
+00:22:05,210 --> 00:22:10,530
+هي منتبهة جالت من ال evoxides كلامها سليم يعني لما
+
+243
+00:22:10,530 --> 00:22:14,950
+كان يكون عندكم الالكين و اضيف عليه ال oxygen أعمل
+
+244
+00:22:14,950 --> 00:22:22,050
+منه evoxide و بعد هيك لو عملنا ring opening
+
+245
+00:22:22,050 --> 00:22:28,320
+باستعمال ال nucleophile كنا نقول CCOH و يجي
+
+246
+00:22:28,320 --> 00:22:32,640
+لنكليوفايل this is an alcohol كلامها سليم ماكنش
+
+247
+00:22:32,640 --> 00:22:39,500
+فيه غلط واضح لكن منطلقوا ايش الالكين برضه منطلقنا
+
+248
+00:22:39,500 --> 00:22:43,860
+الالكين اعملنا ابوكسايد و عملنا ring opening هذا
+
+249
+00:22:43,860 --> 00:22:48,780
+الكلام ماكن ان شاء الله الان لو اجينا على موضوع ال
+
+250
+00:22:48,780 --> 00:22:56,650
+reactions of alcoholsمن تفاعلات ال alcohols تفاعل
+
+251
+00:22:56,650 --> 00:23:01,390
+ال dehydration معنى ال dehydration او acidic
+
+252
+00:23:01,390 --> 00:23:08,500
+dehydration نزع الماء في وجود الحامضنزع الماء في
+
+253
+00:23:08,500 --> 00:23:12,660
+وجود الحامض هذا ايش اسمه dehydration حدف الماء في
+
+254
+00:23:12,660 --> 00:23:17,280
+وجود الحامض الآن بدنا ننتبه هنا لنقطة انه احنا
+
+255
+00:23:17,280 --> 00:23:22,940
+ممكن نعمل هذا التفاعل بطريقتين تؤدي الى ناتجين
+
+256
+00:23:22,940 --> 00:23:28,280
+مختلفين ممكن من نفس الكحول يعني لو أخدنا الاثانول
+
+257
+00:23:28,280 --> 00:23:31,240
+كمثال ننزع من هنا OH
+
+258
+00:23:34,460 --> 00:23:40,300
+OH من carbon مجاورة هنا رفعنا ايش؟ مية لما بنشيل
+
+259
+00:23:40,300 --> 00:23:48,100
+OH مع اتش شو ممكن نعمل؟ الالكين الحد في عكس ايش؟
+
+260
+00:23:48,100 --> 00:23:53,400
+الاضافة اضافة الماء على الالكين بتاعة الالكول حد
+
+261
+00:23:53,400 --> 00:23:58,520
+في ال ..إضافة الماء على الالكين تعطي الالكول وحذف
+
+262
+00:23:58,520 --> 00:24:03,620
+الماء من الالكول ممكن يعطي الالكين هذا أحد النواتج
+
+263
+00:24:03,620 --> 00:24:09,120
+الناتج التاني انه يتفاعلوا جزيئين من الالكول مع
+
+264
+00:24:09,120 --> 00:24:15,040
+بعضواضح؟ يعملول ال ether يعني هذا ال ethanol مع
+
+265
+00:24:15,040 --> 00:24:19,740
+ethanol تاني CH3CH2OH
+
+266
+00:24:19,740 --> 00:24:24,020
+يعني طبعا من و ال ethanol التاني ما انا حاطط ال
+
+267
+00:24:24,020 --> 00:24:29,380
+ethanol ملايين الجزيئات فجزيئ بتفاعل ايش؟ مع جزيئ
+
+268
+00:24:29,380 --> 00:24:35,200
+لاحظوا لما يعمل ال ether CH3CH2OCH2CH3
+
+269
+00:24:35,200 --> 00:24:41,990
+ايش حُدف من هدول الجزيئين؟مية O H من واحد O H من
+
+270
+00:24:41,990 --> 00:24:46,490
+واحد يعني كأنه بالظبط اللي بده يصير هنا أن هذه ال
+
+271
+00:24:46,490 --> 00:24:51,630
+O بدها تهاجم هنا على الكربون وتترد ال O H الآن و
+
+272
+00:24:51,630 --> 00:24:53,230
+هذه ال O شو هتخسر؟
+
+273
+00:24:57,940 --> 00:25:01,920
+هي لما هذه هاجمت من خلال الـ Oxygen كان يوكليوفايل
+
+274
+00:25:01,920 --> 00:25:06,880
+طردت الـ OH والنيوترال يوكليوفايل دايما بيخسر ايش؟
+
+275
+00:25:06,880 --> 00:25:11,740
+H اتفقنا على هذا الكلام هذه خسرت الـ H والـ OH ايش
+
+276
+00:25:11,740 --> 00:25:19,280
+عملوه؟ H2O يعني هنا زائد H2O وهنا زائد H2O لكن هنا
+
+277
+00:25:19,280 --> 00:25:23,780
+ما حُدفت من جزء واحد اعطت الالكين لو حُدفت من
+
+278
+00:25:23,780 --> 00:25:31,820
+التفاعل بين جزيئين بتعطي ايش؟الـ Ether الـ ROR هو
+
+279
+00:25:31,820 --> 00:25:36,780
+الـ Ether طبعاً بيصير السؤال يا ترى أي التفاعلات
+
+280
+00:25:36,780 --> 00:25:42,640
+بيمشي بيعتمد على عدة عوامل من أهمها درجة الحرارة
+
+281
+00:25:42,640 --> 00:25:47,580
+زائد العوامل الحفازة اللي بيستعملوها للتفاعل خلينا
+
+282
+00:25:47,580 --> 00:25:51,260
+نكون مركزين على درجة الحرارة لو هذا التفاعل عملناه
+
+283
+00:25:51,260 --> 00:25:56,280
+عند 140 درجة مئوية هيعطينا بشكل أساس الـ Etherو لو
+
+284
+00:25:56,280 --> 00:26:00,740
+عملناها عند 180 درجة مئوية هيعطينا بشكل أساسي
+
+285
+00:26:00,740 --> 00:26:06,220
+الالكيد لكن بقولكوا أن التفاعل صناعيا له شغلات
+
+286
+00:26:06,220 --> 00:26:11,300
+تانية و بيستعمله catalyst معينة اللي مع الحرارة
+
+287
+00:26:11,300 --> 00:26:16,960
+تفضل هذا أو هذا يعني بعض العوامل الحفازة مع حرارة
+
+288
+00:26:16,960 --> 00:26:21,760
+أعلى من 180 ع 250 ممكن تخلي التفاعل يعطي بس ال
+
+289
+00:26:21,760 --> 00:26:27,030
+الكيد و بعض العوامل الحفازةعلى مية و اربعين، مية و
+
+290
+00:26:27,030 --> 00:26:34,050
+خمسين، ممكن تخليه يعطي بس إيش؟الإيثر الآن بدناش
+
+291
+00:26:34,050 --> 00:26:37,510
+ندخل في التفصيل الممل احنا بنقول انه تسخين
+
+292
+00:26:37,510 --> 00:26:42,030
+الاثانول في وجود الحامض 140 هيعطيني ال ether و 180
+
+293
+00:26:42,030 --> 00:26:47,950
+هيعطيني ال alkene و القمر لما يصير في الصناعة اكيد
+
+294
+00:26:47,950 --> 00:26:52,310
+اللي بيشتغلوا فيه يعني عندهم انتباه لأشياء إضافية
+
+295
+00:26:52,310 --> 00:26:56,290
+و لعوامل حفازة اللي يتحكموا ايش الناتج اللي بيطلع
+
+296
+00:26:56,290 --> 00:26:56,670
+عندهم
+
+297
+00:26:59,310 --> 00:27:04,610
+الان لو أخدنا مثال تاني لو أخدنا ال tertiary butyl
+
+298
+00:27:04,610 --> 00:27:08,770
+alcohol عارفينه ال tertiary butyl alcohol اللي هو
+
+299
+00:27:08,770 --> 00:27:12,470
+ال carbon اللي حامله تلت مجموعات مثل يعني لو رسمته
+
+300
+00:27:12,470 --> 00:27:22,330
+انا OH CH3 CH3 CH3 و سخناه في وجود حامض بالتأكيد
+
+301
+00:27:22,330 --> 00:27:31,490
+هيفقدالـ OH و هيفقد معها H من كاربون مجاورة الآن
+
+302
+00:27:31,490 --> 00:27:35,770
+التلت ذرات اللي هنا متكافئات ولا لأ؟ والتسع
+
+303
+00:27:35,770 --> 00:27:39,150
+هيدروجينات متكافئات عشان ايه؟ لو بدأ أقولكوا هذا
+
+304
+00:27:39,150 --> 00:27:42,990
+الحذف أو هذا ال dehydrationيعني جيكوا اك سؤال
+
+305
+00:27:42,990 --> 00:27:46,930
+dehydration of tertiary-butanol او tertiary-butyl
+
+306
+00:27:46,930 --> 00:27:51,770
+alcohol produces how many products؟ one يعني لو
+
+307
+00:27:51,770 --> 00:27:55,970
+شال H من هان زي هان زي هان بدون ما ندخل في
+
+308
+00:27:55,970 --> 00:27:59,250
+الميكانيزم لو رسمتوا double bond هان او رسمتوها
+
+309
+00:27:59,250 --> 00:28:03,230
+هان او رسمتوها هان هو ايش؟ نفس المركب هنا مثلا
+
+310
+00:28:03,230 --> 00:28:09,230
+رسمنا الـOH هذه مع H من هدولة هي الناتج ايش اسمه؟
+
+311
+00:28:09,230 --> 00:28:15,840
+ISOبيوتين مار عليكم ايزو بيوتين او لو بتكوينها بال
+
+312
+00:28:15,840 --> 00:28:22,300
+ايوبك one two three وعنمرة اتنين حامل ايش مثل اذا
+
+313
+00:28:22,300 --> 00:28:27,660
+two مثل بروبين two مثل بروبين هو نفس ال ايزو
+
+314
+00:28:27,660 --> 00:28:32,300
+بيوتين الان لاحظوا معايا ان انتوا صارت عندكم
+
+315
+00:28:32,300 --> 00:28:39,490
+الفكرة انه بتحذف OHو Hydrogen مجاورة لحسن الحظ في
+
+316
+00:28:39,490 --> 00:28:43,830
+ال tertiary butanol التلاتة زي بعض طلع بيطلع عندى
+
+317
+00:28:43,830 --> 00:28:49,330
+كام ناتج طب لو التلاتة مختلفات هيعطينى كام ناتج
+
+318
+00:28:49,330 --> 00:28:55,080
+اعملتوا مثال شبيه جدا بس لما كنتوا تحلفوا ايشمش ال
+
+319
+00:28:55,080 --> 00:29:01,400
+H O H ال H C L و سلمتوه homeware الحد في الميه زي
+
+320
+00:29:01,400 --> 00:29:06,420
+حد في ال H C L طب حد في ال H C L متذاكرين قاعدة
+
+321
+00:29:06,420 --> 00:29:14,280
+أخدتوها عشان اتقولكوا أي نواتج أفضل ال more
+
+322
+00:29:14,280 --> 00:29:18,740
+substituted زي سفرول ولذلك لو مثلا أخدتوا ال two
+
+323
+00:29:18,740 --> 00:29:25,870
+butanol أكيد بدنا نحدفالـ OH لكن يا تراب نحذف H من
+
+324
+00:29:25,870 --> 00:29:32,670
+هنا و لا H من هنا إذا حذفنا هذه ال H بنطلع هذا و
+
+325
+00:29:32,670 --> 00:29:36,350
+إذا حذفنا هذه ال H بنطلع هذا which is more
+
+326
+00:29:36,350 --> 00:29:41,780
+substitutedفي حد في ال alkalites زيها تماما ال
+
+327
+00:29:41,780 --> 00:29:45,020
+alcohols هذا more substituted بيكون ال major
+
+328
+00:29:45,020 --> 00:29:50,780
+product ال less substituted ال minor product واضح؟
+
+329
+00:29:50,780 --> 00:29:56,640
+كذلك الحالة بهذا المثال هيبدأ احذف ال OH تأكيد مش
+
+330
+00:29:56,640 --> 00:30:03,450
+فيها نقاش بس بدي Hمجاورة هنا في اتش وهذا المثل
+
+331
+00:30:03,450 --> 00:30:08,030
+كمان فيها اتش لو حذفت هذا الاتش اللي هنا بيطلع
+
+332
+00:30:08,030 --> 00:30:12,110
+الناتج التاني و لو حذفت الاتش من هنا او اتش او اتش
+
+333
+00:30:12,110 --> 00:30:17,050
+بيطلع هذا نتطلع عليهم which is more substituted
+
+334
+00:30:17,050 --> 00:30:21,470
+اكيد هذا more substituted ال major ال minor نفس
+
+335
+00:30:21,470 --> 00:30:24,610
+الكلام كنا نجيب السؤال بس بدل ما نكون كاتبين OH
+
+336
+00:30:24,610 --> 00:30:31,410
+نكون كاتبين CL او PRاللي عملناه لما كان دا يكون CL
+
+337
+00:30:31,410 --> 00:30:35,170
+او PR في chapter ال elimination في ال alkalites هو
+
+338
+00:30:35,170 --> 00:30:40,270
+نفسه بنطبقه على ال alcohol ف ال dehydration of
+
+339
+00:30:40,270 --> 00:30:46,530
+alcohol بيعطي نتائج موازية تماما ل ال
+
+340
+00:30:46,530 --> 00:30:51,100
+dehydrohalogenation of alcoholAlkyl Halides لاحظوا
+
+341
+00:30:51,100 --> 00:30:55,720
+في ال alcohols شو سمينا العملية؟ dehydration نزع
+
+342
+00:30:55,720 --> 00:31:00,780
+الماء OH وH طب لو كانت هذه بيه R او halogen X وH
+
+343
+00:31:00,780 --> 00:31:05,380
+ايش قولنا عنها؟ dehydrohalogenation
+
+344
+00:31:05,380 --> 00:31:11,600
+واضح؟ يعني لو هذه كانت X, hydro و halogen فصارت
+
+345
+00:31:11,600 --> 00:31:15,280
+dehydrohalogenation
+
+346
+00:31:15,280 --> 00:31:22,830
+لما H و OHdehydration و سبق أن وضحت لكم إيش معناه
+
+347
+00:31:22,830 --> 00:31:26,710
+الإضافات و النزع hydrogenation, dehydrogenation,
+
+348
+00:31:26,850 --> 00:31:30,290
+hydration, dehydration, hydrogenation,
+
+349
+00:31:30,410 --> 00:31:36,990
+dehydrogenation هذه المصطلحات لازم تكون واضحة لازم
+
+350
+00:31:36,990 --> 00:31:44,750
+تكون واضحة عندكم من تفاعلات ال alcohols التفاعل مع
+
+351
+00:31:44,750 --> 00:31:49,670
+ال hydrogen halidesالان هذا التفاعل سبق اننا
+
+352
+00:31:49,670 --> 00:31:54,870
+شرحناه لكن بنعيد نأكد عليه مرة ثانية ال alcohol مع
+
+353
+00:31:54,870 --> 00:32:00,370
+ال hydrogen halide بيبدل ال OH ب X بيعطيني RX زائد
+
+354
+00:32:00,370 --> 00:32:06,290
+H2O الان لو اتيت انا اتطلعت على ال alcohol ايش
+
+355
+00:32:06,290 --> 00:32:10,900
+ممكن يكون ال alcohol ممكن يكون tertiaryو secondary
+
+356
+00:32:10,900 --> 00:32:14,800
+و primary افضل اش هيتفاعل مع ال tertiary ال
+
+357
+00:32:14,800 --> 00:32:24,040
+hydrogen halides ممكن تكون يود و بروم و كلور واضح؟
+
+358
+00:32:25,040 --> 00:32:28,740
+الـ hydrogen halides يا يود يا بروم يا كلور، مين
+
+359
+00:32:28,740 --> 00:32:32,420
+أحسن واحدة بتتفعل؟ أفضل من البروم، أفضل من الكلور
+
+360
+00:32:32,420 --> 00:32:36,580
+والالكهول تيرتشري أفضل من سكندريا، أفضل من إيش؟ ال
+
+361
+00:32:36,580 --> 00:32:41,280
+primary بناء على ذلك، لو أنا أجي اتفعلت أي ألكهول
+
+362
+00:32:41,280 --> 00:32:47,660
+من هدولة مع يود أو بروم، يعني مع HI أو HPR، هيتفعل
+
+363
+00:32:47,660 --> 00:32:53,360
+بدون مشاكل ويعمل إبدالهتصير المشكلة وين؟ لو بدأ
+
+364
+00:32:53,360 --> 00:32:59,060
+ضقة فاعل، الأضعف هان مع الأضعف هان، بتمشي التفاعل
+
+365
+00:33:00,250 --> 00:33:05,650
+بشكل عام يعني لو أخدت ال primary alkyl halide مع
+
+366
+00:33:05,650 --> 00:33:10,450
+HCl مش هيعمل إبدال يعني لو أخدت ال ethanol مع ال
+
+367
+00:33:10,450 --> 00:33:16,090
+HCl إيثانول مع HCl بيعمل إبدال إيثانول primary HCl
+
+368
+00:33:16,090 --> 00:33:20,250
+للأضعف بيعملش إبدال بعد ذلك خدوا على سبيل المثال
+
+369
+00:33:20,250 --> 00:33:25,890
+high tertiary alkyl halide ملاحظين انتوا؟ مع HCl
+
+370
+00:33:25,890 --> 00:33:29,070
+عمل
+
+371
+00:33:29,070 --> 00:33:34,250
+إبدالTertiary Alkylide مع HCl عمل إبدالة اللي ما
+
+372
+00:33:34,250 --> 00:33:42,010
+بيعملش أي واحد ال primary مع ال HCl يمكن هنا مرات
+
+373
+00:33:42,010 --> 00:33:45,270
+التفاعل بيكون إيش قوي زي التانين يعني حطوله
+
+374
+00:33:45,270 --> 00:33:50,670
+catalyst zinc chloride ما بضرش مش مشكلة بس بيمشي
+
+375
+00:33:50,670 --> 00:33:57,220
+في الآخر واضح؟ بيمشيحتى لو أخدت secondary alcohol
+
+376
+00:33:57,220 --> 00:34:01,200
+ماقعدش CL في وجود ذنك كلورادي و شوية تسخين بمشي
+
+377
+00:34:01,200 --> 00:34:06,560
+لكن مين اللي فيه المشكلة ال primary؟ اه مع ال FCL
+
+378
+00:34:06,560 --> 00:34:12,580
+لاحظوا هنا عشان هيك بنلاقي حلول بديلة لما يصير عند
+
+379
+00:34:12,580 --> 00:34:17,340
+primary لو قلتلكوا ماقعدش CL إيش الجواب؟ نوريا
+
+380
+00:34:20,520 --> 00:34:24,140
+بدّو البني آدم هيك هيك لازم يحوّل الـ OH لـCl
+
+381
+00:34:24,140 --> 00:34:28,180
+بيغير ال reagent يعني لو استعمل ال primary مع ال
+
+382
+00:34:28,180 --> 00:34:35,080
+BCL3 فوسفوراس الـ Trichloride بيعمل تفاعل واضح؟
+
+383
+00:34:35,080 --> 00:34:38,780
+يعني ال primary الكهول مع فوسفوراس ال Trichloride
+
+384
+00:34:38,780 --> 00:34:43,080
+بتفاعل بيبدّي ال OH بCL لكن مع ال HCL لأ بتفاعل
+
+385
+00:34:43,080 --> 00:34:47,320
+وغير الفوسفوراس ال Trichloride أخدنا كمان reagent
+
+386
+00:34:47,320 --> 00:34:56,800
+SOCL2 هذا مشهور بيسميه ثيونيليكلورايد واضح؟ برضه
+
+387
+00:34:56,800 --> 00:35:02,920
+هذا ايش بيعمل؟ بتفاعل و بيبدل ال OH ل ال primary
+
+388
+00:35:02,920 --> 00:35:08,880
+بCL فسواء استعملت الفوسفوراس ال trichloride او
+
+389
+00:35:08,880 --> 00:35:12,380
+الثيونيليكلورايد بقدر اعمل التفاعل لكن لو استعملت
+
+390
+00:35:12,380 --> 00:35:19,650
+ال HCl بمشيش التفاعلطبعا ما عدا ذلك مع اليود و مع
+
+391
+00:35:19,650 --> 00:35:23,730
+البروم بيمشي مع كله تيرتشاري .. سكندر .. برايماري
+
+392
+00:35:23,730 --> 00:35:29,370
+.. يعني المشكلة حقيقة بين ال primary و ال hcl في
+
+393
+00:35:29,370 --> 00:35:32,150
+
+
+445
+00:40:22,090 --> 00:40:25,130
+من الـ OH هيدروجينة و من الكربون اللي حامله 
+
+446
+00:40:25,130 --> 00:40:27,850
+هيدروجينة طب الكربون اللي حامله مش حامله هيدروجينة
+
+447
+00:40:28,820 --> 00:40:33,540
+إذا الأكسدة لا تتم مع إيش؟ مع الـ tertiary 
+
+448
+00:40:33,540 --> 00:40:37,860
+alcohols، الآن مع الـ primary والـ secondary؟ بالتم،
+
+449
+00:40:37,860 --> 00:40:44,160
+شو بدها تعطيني؟الديهايد او كيتون وقت ايش بتعطي
+
+450
+00:40:44,160 --> 00:40:49,760
+الديهايد و وقت ايش بتعطي كيتون الـ primary ببساطة
+
+451
+00:40:49,760 --> 00:40:55,480
+بيعطي الديهايد و الـ secondary بيعطي كيتون واضح؟
+
+452
+00:40:55,480 --> 00:40:59,380
+إذا كأنه لو الانسان بده يلخص الكلام ان الـ alcohol 
+
+453
+00:40:59,380 --> 00:41:03,920
+في كام نوع؟ primary secondary و tertiary الـ
+
+454
+00:41:03,920 --> 00:41:11,080
+tertiaryكفى الله المؤمنين القتال ..مش فيها كلمة شر
+
+455
+00:41:11,080 --> 00:41:17,300
+..وكفى الله المؤمنين القتال الـ tertiary بتأكسدش الـ
+
+456
+00:41:17,300 --> 00:41:22,400
+primary لما يتأكسد شو هيعطيني الـ dihyde الـ
+
+457
+00:41:22,400 --> 00:41:28,130
+secondary لما يتأكسد شو هيعطيني كيتونلحظته هيك 
+
+458
+00:41:28,130 --> 00:41:34,290
+بيصير العلم ايش ماله؟ سهل انه الـ alcohols تلاتة الـ
+
+459
+00:41:34,290 --> 00:41:38,630
+primary او الـ secondary او الـ tertiary الـ primary
+
+460
+00:41:38,630 --> 00:41:44,560
+هيعطيني aldehyde الـ secondary كيتون الـ tertiaryمش
+
+461
+00:41:44,560 --> 00:41:50,320
+حيت أكسد الان المرة الجاية بتجيجتين هنوضح ايش 
+
+462
+00:41:50,320 --> 00:41:54,440
+العامل المؤكسد اللي بتتم فيه العملية يعني نبدأ من 
+
+463
+00:41:54,440 --> 00:41:58,820
+هذه بنشرحها بتجيجتين وننتبه ان الـ الديهايد ممكن 
+
+464
+00:41:58,820 --> 00:42:06,400
+بعدين يعمل تفاعل تاني يصير أسد هذه زيادة واضح؟ لكن
+
+465
+00:42:06,400 --> 00:42:12,560
+الأكسد الأساسية الأولى الـ primary شو بيصير؟الـ 
+
+466
+00:42:12,560 --> 00:42:17,640
+secondary الـ tertiary لا يتأكسد الان الـ primary 
+
+467
+00:42:17,640 --> 00:42:22,200
+بعد ما يصير الديهاي ممكن لو العامل المؤكسد قوي 
+
+468
+00:42:22,200 --> 00:42:28,660
+يمشي كمان مرحلة يصير أسد لو ضعيف بيظل زي ما هو إذا
+
+469
+00:42:28,660 --> 00:42:32,340
+بتصير قصتنا إيش العامل المؤكسد اللي استعملنا هان و
+
+470
+00:42:32,340 --> 00:42:37,340
+هان هان من الأساس مافيش أكسدة من هذه المقطة ان شاء
+
+471
+00:42:37,340 --> 00:42:40,120
+الله بنبدأ المرة الجاية 
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..fb6d6837eba461ceaaca22b71b32343165a6d781
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_postprocess.srt
@@ -0,0 +1,1884 @@
+1
+00:00:19,520 --> 00:00:23,540
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:23,540 --> 00:00:28,820
+موضوع ال acidity و عرفنا بالظبط ايش معنى الأحمار و
+
+3
+00:00:28,820 --> 00:00:35,360
+وضحنا انه مهم جدا نعرف ايش معنى ال BKAال acidity
+
+4
+00:00:35,360 --> 00:00:39,820
+constant و قولنا كل ما ال PKA قلة كل ما الحامض
+
+5
+00:00:39,820 --> 00:00:45,000
+بيكون ايش اقوى بعد هي طرحنا سؤال و أعطينا عليه
+
+6
+00:00:45,000 --> 00:00:49,940
+إجابة عامة بدون ما ندخل بأنفلة تفصيلية كان السؤال
+
+7
+00:00:49,940 --> 00:00:54,540
+لما بدأ قارن حامض مع حامض تاني من الأقوى و من
+
+8
+00:00:54,540 --> 00:00:59,250
+الأقل بدأ اعتمد على ايشلما بقارن الأحماض في قوتها
+
+9
+00:00:59,250 --> 00:01:05,270
+بدي أنظر لل أيون السالب اللي بتكون نتيجة اللي هو
+
+10
+00:01:05,270 --> 00:01:10,430
+تحلل الحمض بالماء هذا ال أيون السالب بدي الشحنة
+
+11
+00:01:10,430 --> 00:01:14,110
+تبعته تكون أقل ما يمكن هذا اللي بنسميه إيش احنا ال
+
+12
+00:01:14,110 --> 00:01:18,470
+stability ل ال negative أيون معنى ال stability أن
+
+13
+00:01:18,470 --> 00:01:21,710
+الشحنة تكون أقل ما يمكن الآن إيش اللي بيقلل
+
+14
+00:01:21,710 --> 00:01:27,060
+الشحنة؟تلات تأثيرات ممكن الحجم اللي بيحمل الشحنة
+
+15
+00:01:27,060 --> 00:01:30,920
+وممكن شيء نسميه ال inductive effect اللي هو تأثير
+
+16
+00:01:30,920 --> 00:01:36,180
+المساعدة وممكن شيء نسميه ال resonance effect
+
+17
+00:01:36,180 --> 00:01:42,660
+أعطينا بعض الأمثلة لكن خلينا نأكد الآن مثلا لو
+
+18
+00:01:42,660 --> 00:01:48,420
+أجينا نقارن ال phenolsمع الالكوهولز العادية
+
+19
+00:01:48,420 --> 00:01:54,480
+الاليفاتك الالكوهولز بمعنى انا بدي اقارن ROH مع
+
+20
+00:01:54,480 --> 00:01:59,320
+فنل OH لاحظوا المقطة الأولى انه لما ايجي يعمل
+
+21
+00:01:59,320 --> 00:02:04,680
+المقارنة ويفهم المقارنة سابه هو من الحامض ايش كتب؟
+
+22
+00:02:04,680 --> 00:02:10,760
+الايون السالد يعني كتب أنا R O minus وفنل O minus
+
+23
+00:02:10,760 --> 00:02:17,990
+فالحكم هوالـ Ion السالب الان هذا الـ RO- الشحن
+
+24
+00:02:17,990 --> 00:02:22,450
+اللي موجود عليه ثابت على ال oxygen مافيش فيها حركة
+
+25
+00:02:22,450 --> 00:02:25,970
+مافيش فيها resonance ال oxygen ذرة صغيرة يعني
+
+26
+00:02:25,970 --> 00:02:29,710
+بيقول it cannot carry the negative charge صعب
+
+27
+00:02:29,710 --> 00:02:33,250
+عليها تحمل ال negative charge ولذلك ال Ion كله
+
+28
+00:02:33,250 --> 00:02:37,050
+بيكون unstable فلاحظوا الكلام ان ال charge is
+
+29
+00:02:37,050 --> 00:02:43,570
+localized يعني محمولة على موقع واحد مش عملهاتتنجل
+
+30
+00:02:43,570 --> 00:02:48,730
+localized متموضعة محمولة في موضع واحد عكسها ايش؟
+
+31
+00:02:48,730 --> 00:02:53,410
+delocalized فبصير عندي كلمتين localized اشي على
+
+32
+00:02:53,410 --> 00:02:57,550
+موضع واحد delocalized زي ما انا اجي احمل هذا هيك
+
+33
+00:02:57,550 --> 00:03:01,550
+بس عن ايد هذه و فقط لا غير هيك بيكون هذا الحمل
+
+34
+00:03:01,550 --> 00:03:07,590
+localized الآن لو كنت بنجلهبيكون De-localized واضح
+
+35
+00:03:07,590 --> 00:03:13,210
+فإذا بنلاحظ أنه بالفينول الشحنة السالبة في أحد ال
+
+36
+00:03:13,210 --> 00:03:16,350
+resonance structures على ال oxygen لكن لو عملنا
+
+37
+00:03:16,350 --> 00:03:20,450
+حركة إلكترونات زوج من الإلكترونات بهذا الشكل و
+
+38
+00:03:20,450 --> 00:03:23,710
+حركنا ال bond هنلاحظ أنها ممكن تصير على ال carbon
+
+39
+00:03:23,710 --> 00:03:26,510
+اللي موجودة هنا بحركة تانية على ال carbon اللي
+
+40
+00:03:26,510 --> 00:03:29,750
+موجودة هنا بحركة تالتة على ال carbon لاحظوا أنه
+
+41
+00:03:29,750 --> 00:03:34,460
+بطلت الشحنةمحمولة على مكان واحد بطلت localized
+
+42
+00:03:34,460 --> 00:03:39,000
+صارت delocalized هذا resonance واضح او
+
+43
+00:03:39,000 --> 00:03:42,400
+delocalization يعني بيستعملوا كلمة resonance او
+
+44
+00:03:42,400 --> 00:03:46,900
+delocalization بنفس المعنى واضح ف because of the
+
+45
+00:03:46,900 --> 00:03:52,360
+delocalization of the charge in phenoxide and ion
+
+46
+00:03:52,360 --> 00:03:56,540
+or anion لحظوا ال phenyl O minus شو بنسميه
+
+47
+00:03:58,860 --> 00:04:02,960
+فينوكسايد انا يعني يمكن سابقا حكينالكم هي اللي لو
+
+48
+00:04:02,960 --> 00:04:09,300
+كانت هذه مثل O minus مثوكسايد مثل O minus إثوكسايد
+
+49
+00:04:09,300 --> 00:04:16,880
+HO minusHydroxide هيدروكسايد هيدروكسايد
+
+50
+00:04:16,880 --> 00:04:17,360
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+51
+00:04:17,360 --> 00:04:20,000
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+52
+00:04:20,000 --> 00:04:20,660
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+53
+00:04:20,660 --> 00:04:22,780
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+54
+00:04:22,780 --> 00:04:27,020
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+55
+00:04:27,020 --> 00:04:30,260
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+56
+00:04:30,260 --> 00:04:37,420
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+57
+00:04:37,420 --> 00:04:43,720
+هيدروكسايد هيدروحوالي ست عشر، خمس عشر و نص و خمس
+
+58
+00:04:43,720 --> 00:04:47,340
+عشر و تسعة فلما نيجي نسأل ليش ال phenols are more
+
+59
+00:04:47,340 --> 00:04:51,140
+acidic than alcohols الجواب because of resonance
+
+60
+00:04:51,140 --> 00:04:56,460
+or because of delocalization of its chargeطبعا لو
+
+61
+00:04:56,460 --> 00:05:02,800
+صار عندى Nitrophenol ال delocalization بزيد يعني
+
+62
+00:05:02,800 --> 00:05:07,600
+الشحنة السالبة بالاضافة لإنها ممكن تنوجد على مواضع
+
+63
+00:05:07,600 --> 00:05:12,500
+كثيرة كمان بصير بإمكانها تنوجد على ذرات ال oxygen
+
+64
+00:05:12,500 --> 00:05:15,260
+بتاعون ال Nitro فبصير
+
+65
+00:05:17,450 --> 00:05:22,290
+الـ Delocalization للـ negative charge ايش ماله
+
+66
+00:05:22,290 --> 00:05:27,270
+اكتر بيصير عندي more delocalization يعني الشحنة
+
+67
+00:05:27,270 --> 00:05:31,350
+موزعة زي حمل بيحملوا اتنين اتريحوا شوية طب لو
+
+68
+00:05:31,350 --> 00:05:36,630
+حملوا تلاتة افضل لو حملوا اربعة أسهل واضح الفكرة
+
+69
+00:05:36,630 --> 00:05:42,650
+فبالنيتروفينول عندي more delocalization ولذلك نزل
+
+70
+00:05:42,650 --> 00:05:48,190
+النيتروفينول لقداشلسبعة و اتنين من عشرة ال BKA اذا
+
+71
+00:05:48,190 --> 00:05:52,510
+which is more acidic ال Nitrophenol is more acidic
+
+72
+00:05:52,510 --> 00:05:57,290
+لانه فيه more resonance طب لو صارت Trinitrophenol
+
+73
+00:05:57,290 --> 00:06:02,970
+more and more فهيصل ل point two five وبناء على ذلك
+
+74
+00:06:02,970 --> 00:06:08,670
+سمنا ايش احنا بكريك اسد ل Trinitrophenolهذه كلها
+
+75
+00:06:08,670 --> 00:06:12,850
+أمثلة على الـ Resonance Effect الآن لو كنت بدي
+
+76
+00:06:12,850 --> 00:06:17,290
+أمثلة على ال Inductive Effect لو بدأت بالإيثانول
+
+77
+00:06:17,290 --> 00:06:24,150
+فيه تلت مجموعات هيدروجين CH2OH CH3 طيب لو حطيت
+
+78
+00:06:24,150 --> 00:06:28,830
+واحدة من الهيدروجين زي كلور بتبدأ هذه الكلور تسحب
+
+79
+00:06:28,830 --> 00:06:30,210
+جزء من الشحنة
+
+80
+00:06:32,900 --> 00:06:36,200
+افترضوا ان كلهم فيهم شحنة سالبة قللت الشحنة
+
+81
+00:06:36,200 --> 00:06:41,580
+السالبة هذا ال effect سحب الشحنة with drawing of
+
+82
+00:06:41,580 --> 00:06:47,930
+the chargeأو إعطاء شحنة إيش بنسميه إحنا Inductive
+
+83
+00:06:47,930 --> 00:06:51,050
+Effect فال Inductive Effect هو سحب الشحنة أو
+
+84
+00:06:51,050 --> 00:06:55,470
+إعطائها مش نقلها لأ الشحنة موجودة هنا لكن افترض
+
+85
+00:06:55,470 --> 00:07:00,090
+الشحنة هنا عشر وحدات سحبنا منها واحدتين ال CL اللي
+
+86
+00:07:00,090 --> 00:07:05,050
+أنا بتحب السالب سحبت واحدتين جديش صفية بدل عشرة
+
+87
+00:07:05,050 --> 00:07:11,820
+تمانية واضح؟ الآن لو حطيت انتين CLصار عندى more
+
+88
+00:07:11,820 --> 00:07:17,220
+and more with the drawing لو حطيت تلاتة CL كلهم
+
+89
+00:07:17,220 --> 00:07:22,160
+بيسحبوا الشحنة السالبة بناء على ذلك ال effect هنا
+
+90
+00:07:22,160 --> 00:07:25,480
+لما انا بقول ان ال trichloroethanol is more acidic
+
+91
+00:07:25,480 --> 00:07:28,240
+than dichloroethanol than chloroethanol than
+
+92
+00:07:28,240 --> 00:07:32,340
+ethanol هذا ايش اللي بنسميه احنا inductive effect
+
+93
+00:07:32,340 --> 00:07:39,750
+واضح؟لمّا قررنا الـ RSH و الـ ROH مين اللي قلنا
+
+94
+00:07:39,750 --> 00:07:45,010
+فيهم أقوى كأسس؟ RSH طب الآن بنقول الـ RSH أقوى من
+
+95
+00:07:45,010 --> 00:07:51,310
+الـ ROH، why؟ because of the size، إذن هاي نعرفه
+
+96
+00:07:51,310 --> 00:08:00,410
+طيب، لو بدأجي أقول الـ ARSH مع الـ ROH، مين أقوى؟
+
+97
+00:08:02,130 --> 00:08:06,990
+because of the size لحظوا ال AR هنا و ال AR هنا
+
+98
+00:08:06,990 --> 00:08:11,890
+فيهم resonance فبطل ال resonance هو السبب يعني ال
+
+99
+00:08:11,890 --> 00:08:16,150
+aromatic او البنزينة هنا و البنزينة هنا فينول و
+
+100
+00:08:16,150 --> 00:08:22,040
+ثيوفينول ال AR عامل مشتركاللي بيعمل resonance بناء
+
+101
+00:08:22,040 --> 00:08:25,900
+على ذلك لو حد .. لو بدنا نجيب سؤال arsh is more
+
+102
+00:08:25,900 --> 00:08:30,240
+acidic than aroh due to resonance غلط لأنه هنا فيه
+
+103
+00:08:30,240 --> 00:08:33,680
+resonance و هنا فيه resonance طب هاش المختلف
+
+104
+00:08:33,680 --> 00:08:41,950
+sulfur و oxygen اذا because of the sizeلكن لو اجيت
+
+105
+00:08:41,950 --> 00:08:49,470
+قلتلكم بدأ اقارن ARSH و RSH، لاحظوا ال sulphur،
+
+106
+00:08:49,470 --> 00:08:53,990
+sulphur the same size، اذا وين صار الفرق؟ AR ولا
+
+107
+00:08:53,990 --> 00:09:00,310
+R؟ اذا why؟ because of resonance
+
+108
+00:09:04,470 --> 00:09:11,150
+لو كنت بدأ اقارن A R O H مع R O H ال O و ال O نفس
+
+109
+00:09:11,150 --> 00:09:16,870
+ال size اللي اتغير R و A R إذا مين أعلى؟ A R
+
+110
+00:09:16,870 --> 00:09:23,650
+because of resonance بضحك الفكرة لما بنعمل مقارنة
+
+111
+00:09:23,650 --> 00:09:29,630
+الآن لو إجيت على هدولة كلهم و قولت بدأ أسطب كل
+
+112
+00:09:29,630 --> 00:09:37,500
+الكلاموبلغة عربية بسيطة جدا بدي أقول من الأقوى ومن
+
+113
+00:09:37,500 --> 00:09:44,240
+الأضعف في الأربعة ال A R S H هو أقوى حاجة ال A R S
+
+114
+00:09:44,240 --> 00:09:51,560
+H هو الأقوى the strongest وال R O H هو الأضعف
+
+115
+00:09:54,370 --> 00:10:00,150
+يعني لو بقارن ال alcohols و ال thyols و ال phenols
+
+116
+00:10:00,150 --> 00:10:04,330
+و ال thyophenols أقوى واحد فيهم ال thyophenol و
+
+117
+00:10:04,330 --> 00:10:08,710
+أضعف واحد فيهم بالحمضية اللي هو إيش ال alcohol هذا
+
+118
+00:10:08,710 --> 00:10:14,970
+الكلام بينعكس على التفاعلات الكيميائيةهذا الكلام
+
+119
+00:10:14,970 --> 00:10:19,170
+الآن ان هذا الأضعف بنعكس على التفاعلات الكيميائية
+
+120
+00:10:19,170 --> 00:10:22,990
+وين بنعكس على التفاعلات الكيميائية مش احنا قاعدين
+
+121
+00:10:22,990 --> 00:10:28,010
+نقول هدولة أحماط مظبوط ولا لأ طول عمرنا بنعرف
+
+122
+00:10:28,010 --> 00:10:35,170
+الجملة الشهيرة حمض زاد قاعدة ملح زاد ماء بناء على
+
+123
+00:10:35,170 --> 00:10:40,570
+ذلك لو اجيت أفاعل هدولة مثلا مع قاعدة قوية زي ال N
+
+124
+00:10:40,570 --> 00:10:53,890
+A O Hزائد NaOH كلهم مش هم زائد قاعدة اه هلاحظ ان
+
+125
+00:10:53,890 --> 00:10:57,670
+تلاتة منهم بتفاعل وبيعطوا ملح زائد ماء واحد
+
+126
+00:10:57,670 --> 00:11:05,990
+مابتفعلش الا مابتفعلش هذا هذا بتفعل هذا بتفعل هذا
+
+127
+00:11:05,990 --> 00:11:11,040
+بتفعلواضح؟ طبعا لو قولنا لكم اكتبوا المعادلة،
+
+128
+00:11:11,040 --> 00:11:17,080
+عندنا مثال، لو أخدنا هذا ال R O H زي N A O H، إيش
+
+129
+00:11:17,080 --> 00:11:24,600
+كتبنا؟ No reaction لكن لو قولنا R S H زي N A O H،
+
+130
+00:11:24,600 --> 00:11:29,770
+ال H مع ال O H، إيش بيعملوا؟ ميّهطول عمره و ال RS
+
+131
+00:11:29,770 --> 00:11:36,350
+minus مع ال NA NA plus RS minus و بنفس الطريقة
+
+132
+00:11:36,350 --> 00:11:45,830
+بإمكانكم تكتبوا إيش كل الأشياء RSH
+
+133
+00:11:45,830 --> 00:11:46,050
+مع
+
+134
+00:11:57,410 --> 00:12:03,230
+فاهم الان دائما اذا وجد عندك مش سؤال مش سؤالك هذا
+
+135
+00:12:03,230 --> 00:12:08,170
+ال specific مش سؤالك هذا ال specific لأ اذا اي
+
+136
+00:12:08,170 --> 00:12:15,110
+شغلة حطيت فيها متغيرين معناه ذلك مش هيكون عندك ثقة
+
+137
+00:12:15,110 --> 00:12:20,110
+كاملة انك بتقدر تاخد الجواب مباشرة الا من التجربة
+
+138
+00:12:20,110 --> 00:12:27,210
+و من قيمة اش بتطلع التجربة ال BKAإذا صار عندك
+
+139
+00:12:27,210 --> 00:12:31,910
+متغيرين سؤالك انا بعتبره جيد انه انت غيرتي هنا ال
+
+140
+00:12:31,910 --> 00:12:37,970
+ar و r و هنا ال o و ال s و سألت مين الأقوى فيهم
+
+141
+00:12:37,970 --> 00:12:44,250
+كام متغير عندك اتنين الحل انك تبحثي تعمل التجربة و
+
+142
+00:12:44,250 --> 00:12:48,550
+تشوف ال bk ايه لهذا و ال bk لهذا و تعمل المقارنة
+
+143
+00:12:48,550 --> 00:12:54,180
+ولذلك في العلم دائما لما بتعملوا المقارنةبتثبتوا
+
+144
+00:12:54,180 --> 00:12:59,600
+جميع المتغيرات ما عدا متغير واحد بيصير بإمكانكوا
+
+145
+00:12:59,600 --> 00:13:03,420
+تعملوله مقارنة و تعملوله قوانين يمكن هذا الكلام
+
+146
+00:13:03,420 --> 00:13:08,780
+أكثر شيء مر عليكم في منطقة الغازات ليش؟ لأن
+
+147
+00:13:08,780 --> 00:13:13,500
+الغازات لها أكتر من متغير الضغط والحجم وعدد
+
+148
+00:13:13,500 --> 00:13:19,790
+المولات ودرجة الحرارةأربع متغيرات في الغازات واضح؟
+
+149
+00:13:19,790 --> 00:13:23,810
+الآن الغازات في النهاية كانت بتنجمع بمعادلة B في V
+
+150
+00:13:23,810 --> 00:13:28,570
+بساوي N في R في T pressure في volume بساوي number
+
+151
+00:13:28,570 --> 00:13:32,610
+of moles في R تابع الغازات في ال temperature الآن
+
+152
+00:13:32,610 --> 00:13:36,770
+لما كنت قادش أقول بدي أقارن ال volume مع ال
+
+153
+00:13:36,770 --> 00:13:43,210
+temperature كنت أحط لنفس الكمية من الغاز عندنفس
+
+154
+00:13:43,210 --> 00:13:49,550
+الضغط واضح بعد ذلك تصبح المقارنة أصعب تعمل تجربة
+
+155
+00:13:49,550 --> 00:13:55,930
+الان هنا ال O و O مشتركات ال R و AR مختلفات سهل
+
+156
+00:13:55,930 --> 00:14:01,650
+علي أعطي جواب واضح الفكرة؟ لكن هنا ال S أفضل من ال
+
+157
+00:14:01,650 --> 00:14:07,940
+O و ال AR أفضل من ال Rإيش النتيجة؟ التجربة
+
+158
+00:14:07,940 --> 00:14:14,040
+المجموعة التجربة واضح؟ يعني مافيش عندك جواب هذي
+
+159
+00:14:14,040 --> 00:14:16,880
+أفضل من هذي و هذي أفضل من هذي طب هذي أفضل من هذي
+
+160
+00:14:16,880 --> 00:14:20,440
+بقدش و هذي أفضل من هذي بقدش عشان يطلع عندي جواب؟
+
+161
+00:14:20,440 --> 00:14:29,160
+لأ بدك تعمل التجربة واضح؟ سؤال جيد الآن لاحظوا معي
+
+162
+00:14:29,160 --> 00:14:32,340
+هل يا ترى الكيميائي
+
+163
+00:14:33,600 --> 00:14:38,120
+بيستسلم؟ لأ، يعني سبحان الله زي ما بتقول آية كريمة
+
+164
+00:14:38,120 --> 00:14:44,820
+وفوق كل ذي علم عليم واضح؟ يعني احنا قولنا الكحول
+
+165
+00:14:44,820 --> 00:14:52,580
+هذا زائد N A O H لا يتفاعل طب ال N A O H كان تصنيف
+
+166
+00:14:52,580 --> 00:15:00,380
+strong baseقاعدة قوية الان ال N A O H is a strong
+
+167
+00:15:00,380 --> 00:15:05,360
+base مركب ايوني و قاعدة قوية طب حبيل غصب عنه
+
+168
+00:15:05,360 --> 00:15:11,000
+الكحول الفاعله ايش بنعمله بنجيبله very strong base
+
+169
+00:15:11,000 --> 00:15:16,460
+يعني بنجيبله قاعدة تكون اقوى من ال N A O H موجود
+
+170
+00:15:16,460 --> 00:15:20,860
+يعني بدل ما اجي افعله مع ال N A O H اللي strong
+
+171
+00:15:20,860 --> 00:15:26,490
+base ممكن افعله مع N A Hهذا المركب اسمه Sodium
+
+172
+00:15:26,490 --> 00:15:33,110
+Hydride الجزء القاعد فيه ايون H- الهيدرايد H-
+
+173
+00:15:33,110 --> 00:15:40,510
+واضح؟ ايش بنسمي هذا Sodium Hydride لاحظوا ال I
+
+174
+00:15:40,510 --> 00:15:47,390
+نهاية ايون سالف يعني هذا NA plus H- ويمكن كلكم
+
+175
+00:15:47,390 --> 00:15:54,470
+بتعرفوا او سبق مر عليكم ان ال H لهاتلت حلق ال H
+
+176
+00:15:54,470 --> 00:15:58,910
+ممكن تتخيلوها بتلت حلق ال H لحالها اللي فيها
+
+177
+00:15:58,910 --> 00:16:04,010
+إلكترون و ال H اللي فقدت الإلكترون و ال H لو
+
+178
+00:16:04,010 --> 00:16:09,010
+اكتسبت كمان إلكترون يعني ذرة الهيدروجين هي الذرة
+
+179
+00:16:09,010 --> 00:16:12,430
+اللي فيها إلكترون و بروتون فهذا ال H اللي فيها
+
+180
+00:16:12,430 --> 00:16:17,810
+إلكترون و بروتون هيدروجين أتم الآن لو فقدت
+
+181
+00:16:18,700 --> 00:16:25,900
+الإلكترون شو بنسميها بروتون بروتون ما انتوا تخيلوا
+
+182
+00:16:25,900 --> 00:16:31,020
+الذرة اتخيلوها بالذرة مش عندى نواة موجبة في كل
+
+183
+00:16:31,020 --> 00:16:38,060
+الأحوال و هالنواة الموجبة حواليهاالألكترون صارت
+
+184
+00:16:38,060 --> 00:16:41,660
+هيدروجين أتم الهيدروجين أتم نوال موجبة حوالها
+
+185
+00:16:41,660 --> 00:16:47,140
+إلكترون طيب لو صارت هيك وشيلنا الإلكترون شو الصفة
+
+186
+00:16:47,140 --> 00:16:55,280
+عندي النوال موجبة بس لبروتون واضح؟ الآن لو اكتسبت
+
+187
+00:16:55,280 --> 00:17:00,620
+كمان إلكترون تاني بتصير هيدرايد أنيون فهذه
+
+188
+00:17:00,620 --> 00:17:09,330
+هيدروجين أتمهذا البروتون وهذا الهيدرايد أنيون ال H
+
+189
+00:17:09,330 --> 00:17:14,810
+minus هيدرايد أنيون كتبنا هناك هيدرايد هذا دايما
+
+190
+00:17:14,810 --> 00:17:20,320
+البروتون اش بنسمي احنا او ال H plusبروتون ال H بلس
+
+191
+00:17:20,320 --> 00:17:25,400
+بروتون ولذلك الأحماض لما بنوصفها مثلا بنقول ال
+
+192
+00:17:25,400 --> 00:17:31,020
+HNO3 بنقول عنه في بروتون واحد monobrotic acid ال
+
+193
+00:17:31,020 --> 00:17:38,640
+H2SO4 بنقول dibrotic acid ال H3BO4 بنقول عنه
+
+194
+00:17:38,640 --> 00:17:43,100
+tribrotic acid واضح؟ اللي جابنا عن هالكلام كلمة
+
+195
+00:17:43,100 --> 00:17:51,800
+إيش؟السوديوم هايدرايد هو مصدر
+
+196
+00:17:51,800 --> 00:17:57,080
+قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى
+
+197
+00:17:57,080 --> 00:17:57,100
+قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى
+
+198
+00:17:57,100 --> 00:18:01,200
+قوى قوى قوى قوى قوى قوى قوى
+
+199
+00:18:02,990 --> 00:18:06,750
+اللي هو لو كنا بناخده مع الاثانول مثلا Sodium
+
+200
+00:18:06,750 --> 00:18:11,870
+Ethoxide كذلك الحال لو فعلنا مع ال metal نفسه NA
+
+201
+00:18:11,870 --> 00:18:19,010
+Sodium Metal Sodium Metal كmetal لوحده أقوى كقاعدة
+
+202
+00:18:19,010 --> 00:18:24,350
+من ال NAOH يعني بإمكانه يتفاعل ال ROH مع ال NA
+
+203
+00:18:24,350 --> 00:18:29,290
+ويعطينا RO minus في الحالتين ال بيكتمل التفاعل انه
+
+204
+00:18:29,290 --> 00:18:35,630
+بيطلع غاز هيدروجينفصحيح ان ال R O H بتفعلش مع ال N
+
+205
+00:18:35,630 --> 00:18:40,290
+A O H ولكنه يتفاعل مع ال sodium hydrate او ال
+
+206
+00:18:40,290 --> 00:18:46,090
+sodium metal وبيعطينا ال R O minus N A plus واضح
+
+207
+00:18:46,090 --> 00:18:54,450
+هذه الفكرة لان هذه تعتبر كقواعد اقوى من ال N A O H
+
+208
+00:18:56,180 --> 00:19:01,080
+بهيك بيكفي في موضوع ال acidity لو اجينا على ال
+
+209
+00:19:01,080 --> 00:19:07,040
+preparation of alcohol الحقيقة هتلاحظ انه بشكل عام
+
+210
+00:19:07,040 --> 00:19:14,260
+ال preparation of alcohol مر معنا طب وين مر معنا؟
+
+211
+00:19:14,260 --> 00:19:21,040
+في مكانين المكان الأول لما كنا ناخد double bond و
+
+212
+00:19:21,040 --> 00:19:24,440
+نعمل عليها addition of water in presence of acid
+
+213
+00:19:25,200 --> 00:19:31,800
+إيش كانت الضيف؟ H و OH إذا إنها تيش كحول، واضح؟
+
+214
+00:19:31,800 --> 00:19:37,680
+فإضافة الماء للالكينز هذه الطريقة ولذلك الإثانول
+
+215
+00:19:37,680 --> 00:19:42,800
+مثلا بنحضره بإضافة الماء للإثيلين
+
+216
+00:19:44,070 --> 00:19:48,550
+طبعا إله شغل عملي و ال yield جليل لكن بيعيدوا
+
+217
+00:19:48,550 --> 00:19:51,810
+التفاعل أكتر من مرة لحد ما يمشوا التفاعل يعني
+
+218
+00:19:51,810 --> 00:19:57,110
+الفكرة العلمية أنه بتفاعل و بيضيف واضح صناعيا أكيد
+
+219
+00:19:57,110 --> 00:20:01,690
+إله أجهزة أو إله متابعة صناعية كذلك الحال اللي
+
+220
+00:20:01,690 --> 00:20:06,230
+بتذكر ال alkenes و إضافة الميه لازم يظلوا متذكر
+
+221
+00:20:06,230 --> 00:20:06,710
+إيش
+
+222
+00:20:09,640 --> 00:20:12,940
+Markovnikov وAntimarkovnikov addition يعني انا لما
+
+223
+00:20:12,940 --> 00:20:18,520
+كنت على البروبين اضيف الماء في وجود H بلس وين كنت
+
+224
+00:20:18,520 --> 00:20:23,700
+احط الهيدروجين هان ال O-H هان اطلع البروبان to all
+
+225
+00:20:23,700 --> 00:20:27,780
+او to probanol او ايزو برو بالالكول ماكانش يطلع
+
+226
+00:20:27,780 --> 00:20:34,200
+هذا طب لو بدنا هذا شو كنا نعمل Antimarkovnikov
+
+227
+00:20:36,400 --> 00:20:40,420
+كنا نستعمل طريقة ال boron ال bh3 و توابعها
+
+228
+00:20:40,420 --> 00:20:46,540
+بترجعوها واضح؟ إذا الكحولات يمكن أن تحضر و أخدنا
+
+229
+00:20:46,540 --> 00:20:51,000
+هذا الكلام بالتفصيل من خلال إضافة الماء على ال
+
+230
+00:20:51,000 --> 00:20:56,860
+alkyls برضه طريقة تانية أخدناها لتحضير الكحولات
+
+231
+00:20:56,860 --> 00:20:59,440
+مين اتذكرنا فيها؟
+
+232
+00:21:04,290 --> 00:21:10,270
+الـ RX زائد الماء أو الـ OH ماينوس مش كنا ناخد هذه
+
+233
+00:21:10,270 --> 00:21:18,110
+المعادلة RX زائد H2O in general R OH لنيوكليوفيليك
+
+234
+00:21:18,110 --> 00:21:23,710
+سبستيوشن على ال الكلهيلايت شبتر ستة سواء كنا نفعله
+
+235
+00:21:23,710 --> 00:21:27,940
+مع نيوترال نيوكليوفايل او معit charged the
+
+236
+00:21:27,940 --> 00:21:32,680
+nucleophile واضح ال substitution إذا الطرق العامة
+
+237
+00:21:32,680 --> 00:21:38,340
+لتحضير الكحولات يا إما من ال RX بالإبدال يا إما من
+
+238
+00:21:38,340 --> 00:21:45,840
+ال alkenes بتفاعل إيش بنسميه الإضافة ما هو مع
+
+239
+00:21:45,840 --> 00:21:53,100
+الميه تفاعل إضافة addition reaction واضح الآن لو
+
+240
+00:21:53,100 --> 00:22:00,470
+إجينا بعد هيك على تفاعلاتالكحولات تفاعلات الكحولات
+
+241
+00:22:00,470 --> 00:22:05,210
+طبعا في زميلة لكم بس عشان يعني ما نغمطهاش حقها ان
+
+242
+00:22:05,210 --> 00:22:10,530
+هي منتبهة جالت من ال evoxides كلامها سليم يعني لما
+
+243
+00:22:10,530 --> 00:22:14,950
+كان يكون عندكم الالكين و اضيف عليه ال oxygen أعمل
+
+244
+00:22:14,950 --> 00:22:22,050
+منه evoxide و بعد هيك لو عملنا ring opening
+
+245
+00:22:22,050 --> 00:22:28,320
+باستعمال ال nucleophile كنا نقول CCOH و يجي
+
+246
+00:22:28,320 --> 00:22:32,640
+لنكليوفايل this is an alcohol كلامها سليم ماكنش
+
+247
+00:22:32,640 --> 00:22:39,500
+فيه غلط واضح لكن منطلقوا ايش الالكين برضه منطلقنا
+
+248
+00:22:39,500 --> 00:22:43,860
+الالكين اعملنا ابوكسايد و عملنا ring opening هذا
+
+249
+00:22:43,860 --> 00:22:48,780
+الكلام ماكن ان شاء الله الان لو اجينا على موضوع ال
+
+250
+00:22:48,780 --> 00:22:56,650
+reactions of alcoholsمن تفاعلات ال alcohols تفاعل
+
+251
+00:22:56,650 --> 00:23:01,390
+ال dehydration معنى ال dehydration او acidic
+
+252
+00:23:01,390 --> 00:23:08,500
+dehydration نزع الماء في وجود الحامضنزع الماء في
+
+253
+00:23:08,500 --> 00:23:12,660
+وجود الحامض هذا ايش اسمه dehydration حدف الماء في
+
+254
+00:23:12,660 --> 00:23:17,280
+وجود الحامض الآن بدنا ننتبه هنا لنقطة انه احنا
+
+255
+00:23:17,280 --> 00:23:22,940
+ممكن نعمل هذا التفاعل بطريقتين تؤدي الى ناتجين
+
+256
+00:23:22,940 --> 00:23:28,280
+مختلفين ممكن من نفس الكحول يعني لو أخدنا الاثانول
+
+257
+00:23:28,280 --> 00:23:31,240
+كمثال ننزع من هنا OH
+
+258
+00:23:34,460 --> 00:23:40,300
+OH من carbon مجاورة هنا رفعنا ايش؟ مية لما بنشيل
+
+259
+00:23:40,300 --> 00:23:48,100
+OH مع اتش شو ممكن نعمل؟ الالكين الحد في عكس ايش؟
+
+260
+00:23:48,100 --> 00:23:53,400
+الاضافة اضافة الماء على الالكين بتاعة الالكول حد
+
+261
+00:23:53,400 --> 00:23:58,520
+في ال ..إضافة الماء على الالكين تعطي الالكول وحذف
+
+262
+00:23:58,520 --> 00:24:03,620
+الماء من الالكول ممكن يعطي الالكين هذا أحد النواتج
+
+263
+00:24:03,620 --> 00:24:09,120
+الناتج التاني انه يتفاعلوا جزيئين من الالكول مع
+
+264
+00:24:09,120 --> 00:24:15,040
+بعضواضح؟ يعملول ال ether يعني هذا ال ethanol مع
+
+265
+00:24:15,040 --> 00:24:19,740
+ethanol تاني CH3CH2OH
+
+266
+00:24:19,740 --> 00:24:24,020
+يعني طبعا من و ال ethanol التاني ما انا حاطط ال
+
+267
+00:24:24,020 --> 00:24:29,380
+ethanol ملايين الجزيئات فجزيئ بتفاعل ايش؟ مع جزيئ
+
+268
+00:24:29,380 --> 00:24:35,200
+لاحظوا لما يعمل ال ether CH3CH2OCH2CH3
+
+269
+00:24:35,200 --> 00:24:41,990
+ايش حُدف من هدول الجزيئين؟مية O H من واحد O H من
+
+270
+00:24:41,990 --> 00:24:46,490
+واحد يعني كأنه بالظبط اللي بده يصير هنا أن هذه ال
+
+271
+00:24:46,490 --> 00:24:51,630
+O بدها تهاجم هنا على الكربون وتترد ال O H الآن و
+
+272
+00:24:51,630 --> 00:24:53,230
+هذه ال O شو هتخسر؟
+
+273
+00:24:57,940 --> 00:25:01,920
+هي لما هذه هاجمت من خلال الـ Oxygen كان يوكليوفايل
+
+274
+00:25:01,920 --> 00:25:06,880
+طردت الـ OH والنيوترال يوكليوفايل دايما بيخسر ايش؟
+
+275
+00:25:06,880 --> 00:25:11,740
+H اتفقنا على هذا الكلام هذه خسرت الـ H والـ OH ايش
+
+276
+00:25:11,740 --> 00:25:19,280
+عملوه؟ H2O يعني هنا زائد H2O وهنا زائد H2O لكن هنا
+
+277
+00:25:19,280 --> 00:25:23,780
+ما حُدفت من جزء واحد اعطت الالكين لو حُدفت من
+
+278
+00:25:23,780 --> 00:25:31,820
+التفاعل بين جزيين بتعطي ايش؟الـ Ether الـ ROR هو
+
+279
+00:25:31,820 --> 00:25:36,780
+الـ Ether طبعاً بيصير السؤال يا ترى أي التفاعلات
+
+280
+00:25:36,780 --> 00:25:42,640
+بيمشي بيعتمد على عدة عوامل من أهمها درجة الحرارة
+
+281
+00:25:42,640 --> 00:25:47,580
+زائد العوامل الحفازة اللي بيستعملوها للتفاعل خلينا
+
+282
+00:25:47,580 --> 00:25:51,260
+نكون مركزين على درجة الحرارة لو هذا التفاعل عملناه
+
+283
+00:25:51,260 --> 00:25:56,280
+عند 140 درجة مئوية هيعطينا بشكل أساس الـ Etherو لو
+
+284
+00:25:56,280 --> 00:26:00,740
+عملناها عند 180 درجة مئوية هيعطينا بشكل أساسي
+
+285
+00:26:00,740 --> 00:26:06,220
+الالكيد لكن بقولكوا أن التفاعل صناعيا له شغلات
+
+286
+00:26:06,220 --> 00:26:11,300
+تانية و بيستعمله catalyst معينة اللي مع الحرارة
+
+287
+00:26:11,300 --> 00:26:16,960
+تفضل هذا أو هذا يعني بعض العوامل الحفازة مع حرارة
+
+288
+00:26:16,960 --> 00:26:21,760
+أعلى من 180 ع 250 ممكن تخلي التفاعل يعطي بس ال
+
+289
+00:26:21,760 --> 00:26:27,030
+الكيد و بعض العوامل الحفازةعلى مية و اربعين، مية و
+
+290
+00:26:27,030 --> 00:26:34,050
+خمسين، ممكن تخليه يعطي بس إيش؟الإيثر الآن بدناش
+
+291
+00:26:34,050 --> 00:26:37,510
+ندخل في التفصيل الممل احنا بنقول انه تسخين
+
+292
+00:26:37,510 --> 00:26:42,030
+الاثانول في وجود الحامض 140 هيعطيني ال ether و 180
+
+293
+00:26:42,030 --> 00:26:47,950
+هيعطيني ال alkene و القمر لما يصير في الصناعة اكيد
+
+294
+00:26:47,950 --> 00:26:52,310
+اللي بيشتغلوا فيه يعني عندهم انتباه لأشياء إضافية
+
+295
+00:26:52,310 --> 00:26:56,290
+و لعوامل حفازة اللي يتحكموا ايش الناتج اللي بيطلع
+
+296
+00:26:56,290 --> 00:26:56,670
+عندهم
+
+297
+00:26:59,310 --> 00:27:04,610
+الان لو أخدنا مثال تاني لو أخدنا ال tertiary butyl
+
+298
+00:27:04,610 --> 00:27:08,770
+alcohol عارفينه ال tertiary butyl alcohol اللي هو
+
+299
+00:27:08,770 --> 00:27:12,470
+ال carbon اللي حامله تلت مجموعات مثل يعني لو رسمته
+
+300
+00:27:12,470 --> 00:27:22,330
+انا OH CH3 CH3 CH3 و سخناه في وجود حامض بالتأكيد
+
+301
+00:27:22,330 --> 00:27:31,490
+هيفقدالـ OH و هيفقد معها H من كاربون مجاورة الآن
+
+302
+00:27:31,490 --> 00:27:35,770
+التلت ذرات اللي هنا متكافئات ولا لأ؟ والتسع
+
+303
+00:27:35,770 --> 00:27:39,150
+هيدروجينات متكافئات عشان ايه؟ لو بدأ أقولكوا هذا
+
+304
+00:27:39,150 --> 00:27:42,990
+الحذف أو هذا ال dehydrationيعني جيكوا اك سؤال
+
+305
+00:27:42,990 --> 00:27:46,930
+dehydration of tertiary-butanol او tertiary-butyl
+
+306
+00:27:46,930 --> 00:27:51,770
+alcohol produces how many products؟ one يعني لو
+
+307
+00:27:51,770 --> 00:27:55,970
+شال H من هان زي هان زي هان بدون ما ندخل في
+
+308
+00:27:55,970 --> 00:27:59,250
+الميكانيزم لو رسمتوا double bond هان او رسمتوها
+
+309
+00:27:59,250 --> 00:28:03,230
+هان او رسمتوها هان هو ايش؟ نفس المركب هنا مثلا
+
+310
+00:28:03,230 --> 00:28:09,230
+رسمنا الـOH هذه مع H من هدولة هي الناتج ايش اسمه؟
+
+311
+00:28:09,230 --> 00:28:15,840
+ISOبيوتين مار عليكم ايزو بيوتين او لو بتكوينها بال
+
+312
+00:28:15,840 --> 00:28:22,300
+ايوبك one two three وعنمرة اتنين حامل ايش مثل اذا
+
+313
+00:28:22,300 --> 00:28:27,660
+two مثل بروبين two مثل بروبين هو نفس ال ايزو
+
+314
+00:28:27,660 --> 00:28:32,300
+بيوتين الان لاحظوا معايا ان انتوا صارت عندكم
+
+315
+00:28:32,300 --> 00:28:39,490
+الفكرة انه بتحذف OHو Hydrogen مجاورة لحسن الحظ في
+
+316
+00:28:39,490 --> 00:28:43,830
+ال tertiary butanol التلاتة زي بعض طلع بيطلع عندى
+
+317
+00:28:43,830 --> 00:28:49,330
+كام ناتج طب لو التلاتة مختلفات هيعطينى كام ناتج
+
+318
+00:28:49,330 --> 00:28:55,080
+اعملتوا مثال شبيه جدا بس لما كنتوا تحلفوا ايشمش ال
+
+319
+00:28:55,080 --> 00:29:01,400
+H O H ال H C L و سلمتوه homeware الحد في الميه زي
+
+320
+00:29:01,400 --> 00:29:06,420
+حد في ال H C L طب حد في ال H C L متذاكرين قاعدة
+
+321
+00:29:06,420 --> 00:29:14,280
+أخدتوها عشان اتقولكوا أي نواتج أفضل ال more
+
+322
+00:29:14,280 --> 00:29:18,740
+substituted زي سفرول ولذلك لو مثلا أخدتوا ال two
+
+323
+00:29:18,740 --> 00:29:25,870
+butanol أكيد بدنا نحدفالـ OH لكن يا تراب نحذف H من
+
+324
+00:29:25,870 --> 00:29:32,670
+هنا و لا H من هنا إذا حذفنا هذه ال H بنطلع هذا و
+
+325
+00:29:32,670 --> 00:29:36,350
+إذا حذفنا هذه ال H بنطلع هذا which is more
+
+326
+00:29:36,350 --> 00:29:41,780
+substitutedفي حد في ال alkalites زيها تماما ال
+
+327
+00:29:41,780 --> 00:29:45,020
+alcohols هذا more substituted بيكون ال major
+
+328
+00:29:45,020 --> 00:29:50,780
+product ال less substituted ال minor product واضح؟
+
+329
+00:29:50,780 --> 00:29:56,640
+كذلك الحالة بهذا المثال هيبدأ احذف ال OH تأكيد مش
+
+330
+00:29:56,640 --> 00:30:03,450
+فيها نقاش بس بدي Hمجاورة هنا في اتش وهذا المثل
+
+331
+00:30:03,450 --> 00:30:08,030
+كمان فيها اتش لو حذفت هذا الاتش اللي هنا بيطلع
+
+332
+00:30:08,030 --> 00:30:12,110
+الناتج التاني و لو حذفت الاتش من هنا او اتش او اتش
+
+333
+00:30:12,110 --> 00:30:17,050
+بيطلع هذا نتطلع عليهم which is more substituted
+
+334
+00:30:17,050 --> 00:30:21,470
+اكيد هذا more substituted ال major ال minor نفس
+
+335
+00:30:21,470 --> 00:30:24,610
+الكلام كنا نجيب السؤال بس بدل ما نكون كاتبين OH
+
+336
+00:30:24,610 --> 00:30:31,410
+نكون كاتبين CL او PRاللي عملناه لما كان دا يكون CL
+
+337
+00:30:31,410 --> 00:30:35,170
+او PR في chapter ال elimination في ال alkalites هو
+
+338
+00:30:35,170 --> 00:30:40,270
+نفسه بنطبقه على ال alcohol ف ال dehydration of
+
+339
+00:30:40,270 --> 00:30:46,530
+alcohol بيعطي نتائج موازية تماما ل ال
+
+340
+00:30:46,530 --> 00:30:51,100
+dehydrohalogenation of alcoholAlkyl Halides لاحظوا
+
+341
+00:30:51,100 --> 00:30:55,720
+في ال alcohols شو سمينا العملية؟ dehydration نزع
+
+342
+00:30:55,720 --> 00:31:00,780
+الماء OH وH طب لو كانت هذه بيه R او halogen X وH
+
+343
+00:31:00,780 --> 00:31:05,380
+ايش قولنا عنها؟ dehydrohalogenation
+
+344
+00:31:05,380 --> 00:31:11,600
+واضح؟ يعني لو هذه كانت X, hydro و halogen فصارت
+
+345
+00:31:11,600 --> 00:31:15,280
+dehydrohalogenation
+
+346
+00:31:15,280 --> 00:31:22,830
+لما H و OHdehydration و سبق أن وضحت لكم إيش معناه
+
+347
+00:31:22,830 --> 00:31:26,710
+الإضافات و النزع hydrogenation, dehydrogenation,
+
+348
+00:31:26,850 --> 00:31:30,290
+hydration, dehydration, hydrogenation,
+
+349
+00:31:30,410 --> 00:31:36,990
+dehydrogenation هذه المصطلحات لازم تكون واضحة لازم
+
+350
+00:31:36,990 --> 00:31:44,750
+تكون واضحة عندكم من تفاعلات ال alcohols التفاعل مع
+
+351
+00:31:44,750 --> 00:31:49,670
+ال hydrogen halidesالان هذا التفاعل سبق اننا
+
+352
+00:31:49,670 --> 00:31:54,870
+شرحناه لكن بنعيد نأكد عليه مرة ثانية ال alcohol مع
+
+353
+00:31:54,870 --> 00:32:00,370
+ال hydrogen halide بيبدل ال OH ب X بيعطيني RX زائد
+
+354
+00:32:00,370 --> 00:32:06,290
+H2O الان لو اتيت انا اتطلعت على ال alcohol ايش
+
+355
+00:32:06,290 --> 00:32:10,900
+ممكن يكون ال alcohol ممكن يكون tertiaryو secondary
+
+356
+00:32:10,900 --> 00:32:14,800
+و primary افضل اش هيتفاعل مع ال tertiary ال
+
+357
+00:32:14,800 --> 00:32:24,040
+hydrogen halides ممكن تكون يود و بروم و كلور واضح؟
+
+358
+00:32:25,040 --> 00:32:28,740
+الـ hydrogen halides يا يود يا بروم يا كلور، مين
+
+359
+00:32:28,740 --> 00:32:32,420
+أحسن واحدة بتتفعل؟ أفضل من البروم، أفضل من الكلور
+
+360
+00:32:32,420 --> 00:32:36,580
+والالكهول تيرتشري أفضل من سكندريا، أفضل من إيش؟ ال
+
+361
+00:32:36,580 --> 00:32:41,280
+primary بناء على ذلك، لو أنا أجي اتفعلت أي ألكهول
+
+362
+00:32:41,280 --> 00:32:47,660
+من هدولة مع يود أو بروم، يعني مع HI أو HPR، هيتفعل
+
+363
+00:32:47,660 --> 00:32:53,360
+بدون مشاكل ويعمل إبدالهتصير المشكلة وين؟ لو بدأ
+
+364
+00:32:53,360 --> 00:32:59,060
+ضقة فاعل، الأضعف هان مع الأضعف هان، بتمشي التفاعل
+
+365
+00:33:00,250 --> 00:33:05,650
+بشكل عام يعني لو أخدت ال primary alkyl halide مع
+
+366
+00:33:05,650 --> 00:33:10,450
+HCl مش هيعمل إبدال يعني لو أخدت ال ethanol مع ال
+
+367
+00:33:10,450 --> 00:33:16,090
+HCl إيثانول مع HCl بيعمل إبدال إيثانول primary HCl
+
+368
+00:33:16,090 --> 00:33:20,250
+للأضعف بيعملش إبدال بعد ذلك خدوا على سبيل المثال
+
+369
+00:33:20,250 --> 00:33:25,890
+high tertiary alkyl halide ملاحظين انتوا؟ مع HCl
+
+370
+00:33:25,890 --> 00:33:29,070
+عمل
+
+371
+00:33:29,070 --> 00:33:34,250
+إبدالTertiary Alkylide مع HCl عمل إبدالة اللي ما
+
+372
+00:33:34,250 --> 00:33:42,010
+بيعملش أي واحد ال primary مع ال HCl يمكن هنا مرات
+
+373
+00:33:42,010 --> 00:33:45,270
+التفاعل بيكون إيش قوي زي التانين يعني حطوله
+
+374
+00:33:45,270 --> 00:33:50,670
+catalyst zinc chloride ما بضرش مش مشكلة بس بيمشي
+
+375
+00:33:50,670 --> 00:33:57,220
+في الآخر واضح؟ بيمشيحتى لو أخدت secondary alcohol
+
+376
+00:33:57,220 --> 00:34:01,200
+ماقعدش CL في وجود ذنك كلورادي و شوية تسخين بمشي
+
+377
+00:34:01,200 --> 00:34:06,560
+لكن مين اللي فيه المشكلة ال primary؟ اه مع ال FCL
+
+378
+00:34:06,560 --> 00:34:12,580
+لاحظوا هنا عشان هيك بنلاقي حلول بديلة لما يصير عند
+
+379
+00:34:12,580 --> 00:34:17,340
+primary لو قلتلكوا ماقعدش CL إيش الجواب؟ نوريا
+
+380
+00:34:20,520 --> 00:34:24,140
+بدّو البني آدم هيك هيك لازم يحوّل الـ OH لـCl
+
+381
+00:34:24,140 --> 00:34:28,180
+بيغير ال reagent يعني لو استعمل ال primary مع ال
+
+382
+00:34:28,180 --> 00:34:35,080
+BCL3 فوسفوراس الـ Trichloride بيعمل تفاعل واضح؟
+
+383
+00:34:35,080 --> 00:34:38,780
+يعني ال primary الكهول مع فوسفوراس ال Trichloride
+
+384
+00:34:38,780 --> 00:34:43,080
+بتفاعل بيبدّي ال OH بCL لكن مع ال HCL لأ بتفاعل
+
+385
+00:34:43,080 --> 00:34:47,320
+وغير الفوسفوراس ال Trichloride أخدنا كمان reagent
+
+386
+00:34:47,320 --> 00:34:56,800
+SOCL2 هذا مشهور بيسميه ثيونيليكلورايد واضح؟ برضه
+
+387
+00:34:56,800 --> 00:35:02,920
+هذا ايش بيعمل؟ بتفاعل و بيبدل ال OH ل ال primary
+
+388
+00:35:02,920 --> 00:35:08,880
+بCL فسواء استعملت الفوسفوراس ال trichloride او
+
+389
+00:35:08,880 --> 00:35:12,380
+الثيونيليكلورايد بقدر اعمل التفاعل لكن لو استعملت
+
+390
+00:35:12,380 --> 00:35:19,650
+ال HCl بمشيش التفاعلطبعا ما عدا ذلك مع اليود و مع
+
+391
+00:35:19,650 --> 00:35:23,730
+البروم بيمشي مع كله تيرتشاري .. سكندر .. برايماري
+
+392
+00:35:23,730 --> 00:35:29,370
+.. يعني المشكلة حقيقة بين ال primary و ال hcl في
+
+393
+00:35:29,370 --> 00:35:32,150
+حلول بديلة ولا لأ؟ كم حل؟
+
+394
+00:35:40,460 --> 00:35:46,160
+هي هنا على سبيل المثال ال primary مع ال SOCl2
+
+395
+00:35:46,160 --> 00:35:51,480
+بتفاعل مية في المية الان لاحظوا ان هذا التفاعل
+
+396
+00:35:51,480 --> 00:35:57,100
+تفاعل إبدال ال OH ب X خاص بال alcohol يعني ال
+
+397
+00:35:57,100 --> 00:36:03,950
+phenols لا يتم عليها إبداليعني لو قلنا لكوا ال A R
+
+398
+00:36:03,950 --> 00:36:16,610
+O H مع HBR مع HCL مع BCL3 مع SOCL2 بكل لغات الأرض
+
+399
+00:36:16,610 --> 00:36:25,460
+لا تتفاعل مافيش إبدال علىالاروماتيك كومباونز لإيش؟
+
+400
+00:36:25,460 --> 00:36:29,400
+لأنه أنا هنا بدي أجيب سالب الـ nucleophile سالب و
+
+401
+00:36:29,400 --> 00:36:32,740
+أخليه يهاجم على البنزينة و احنا من البداية اتفقنا
+
+402
+00:36:32,740 --> 00:36:36,080
+انه الإبدال اللي على البنزين Electrophilic
+
+403
+00:36:36,080 --> 00:36:39,460
+Substitution in general واضح؟ يعني انا لو اجيت
+
+404
+00:36:39,460 --> 00:36:43,740
+افعل مع هدولة في النهاية هاجيب PR minus او I minus
+
+405
+00:36:43,740 --> 00:36:47,960
+minus على minus بيصير و لذلك الإبدالات اللي هنا
+
+406
+00:36:47,960 --> 00:36:53,940
+كلها اللي أخدناها هي متعلقةبالكحولات بال R O H لكن
+
+407
+00:36:53,940 --> 00:36:58,440
+لو صارت A R O H بنزينة أو حملة O H و قلتلكوا
+
+408
+00:36:58,440 --> 00:37:03,740
+بدلوها ب C L و ب R لأواضح؟ هنا مافيش substitution
+
+409
+00:37:03,740 --> 00:37:07,840
+في ال aromatic compounds ال substitution في إيش؟
+
+410
+00:37:07,840 --> 00:37:12,200
+في ال aliphatic compounds تبوا هذا الكلام ممكن
+
+411
+00:37:12,200 --> 00:37:16,440
+نسألكوا يا صح و غلط aromatic alcohols undergo
+
+412
+00:37:16,440 --> 00:37:22,540
+substitution in uneasy manner مثلا ولا .. no they
+
+413
+00:37:22,540 --> 00:37:26,320
+don't undergo substitution
+
+414
+00:37:30,300 --> 00:37:34,040
+ما هو الـ Electrophilic Substitution بيبطل في هذه
+
+415
+00:37:34,040 --> 00:37:38,420
+الحالة للـ OH بيصير في مكان تاني على البنزينة
+
+416
+00:37:38,420 --> 00:37:44,520
+بيختلف التفاعل يعني زي ما تجيب فينول و بدك تعمل
+
+417
+00:37:44,520 --> 00:37:50,200
+مثلا مع الchlor FeCl3 على سبيل المثال أو تاخد O
+
+418
+00:37:50,200 --> 00:37:57,880
+Methyl بتصير تبدل هنا بتبدل Hydrogens مش بتبدلطبعا
+
+419
+00:37:57,880 --> 00:38:01,320
+المشكلة ان الفينول نفسه بعارض مع ال FEC الاتنين
+
+420
+00:38:01,320 --> 00:38:05,420
+افترض او مثل مثلا بتبدليش ال او مثل بتبدلي ايش
+
+421
+00:38:05,420 --> 00:38:11,540
+بتبدلي على الحلقة هيدروجينات بتبدلي هيدروجينات على
+
+422
+00:38:11,540 --> 00:38:20,140
+الحلقة الان ال alcohol من تفاعلاتها الشهيرة تفاعل
+
+423
+00:38:20,140 --> 00:38:25,720
+ال oxidation خليني اقول ايش معنى ال oxidationال
+
+424
+00:38:25,720 --> 00:38:29,920
+Oxidation بلغة الكيميا ما انا عارف ترجمتها انه
+
+425
+00:38:29,920 --> 00:38:34,900
+افقد ال H تبعت ال OH يعني لو انا اطلعت على المركب
+
+426
+00:38:34,900 --> 00:38:41,420
+CHOH زي هيك و ايش ما كان يكون عندى هنا ان افقد
+
+427
+00:38:41,420 --> 00:38:47,910
+جزئها هيدروجينأفقد الـ H اللي على الأكسجين و H على
+
+428
+00:38:47,910 --> 00:38:52,310
+الكربون المتسقة بها الأكسجين مباشرة الآن هدولة لو
+
+429
+00:38:52,310 --> 00:38:56,550
+فقدوا زي هيك على شكل جزء هيدروجين هذه إيش بنتيجة
+
+430
+00:38:56,550 --> 00:39:02,950
+تعمل هنا double bond طالما عملت double bond شو
+
+431
+00:39:02,950 --> 00:39:09,330
+هيصير النتج الديهايد أو كيتونباعتمد على هدول
+
+432
+00:39:09,330 --> 00:39:13,130
+المجموعتين خلّينا نكون في البداية فاهمين قصة
+
+433
+00:39:13,130 --> 00:39:18,950
+الأكسدة الأكسدة معناها ان ال COH بيصير C double
+
+434
+00:39:18,950 --> 00:39:24,090
+bond O طالما C double bond O صارت اذا صارت الجهاي
+
+435
+00:39:24,090 --> 00:39:29,870
+او كيتون هتفقد ال H تعطي ال OH OH عن الكربون اللي
+
+436
+00:39:29,870 --> 00:39:35,790
+هنا اول سؤال هيجيكم طب يا ترى لو فيش هنا H
+
+437
+00:39:38,560 --> 00:39:43,880
+يعني لو هذه كانت R و R و R فى عندي OH مستعدة تفقد
+
+438
+00:39:43,880 --> 00:39:48,860
+ال H بس فىش هنا H يعني صار إيش نوع ال alcohol?
+
+439
+00:39:50,620 --> 00:39:55,800
+tertiary واضحة؟ يعني افترضوا هذه كانت C وهذه C
+
+440
+00:39:55,800 --> 00:40:02,370
+وهذه C CH3 CH3 CH3 هنا فى H هنا مافيش Hبدوا يتم
+
+441
+00:40:02,370 --> 00:40:07,270
+الأكسدة؟ إذا على طول هنطلع قاعدة أن الـ tertiary
+
+442
+00:40:07,270 --> 00:40:11,070
+alcohols اللي مافيش عليهم هيدروجينة هنا بتأكسدوش
+
+443
+00:40:11,070 --> 00:40:17,150
+إذا التأكسد خاص بماذا؟ ال primary و ال secondary
+
+444
+00:40:17,150 --> 00:40:22,090
+التيرتشاري مابصله أكسدة ليش؟ لأن الأكسد بدأ أفقد
+
+445
+00:40:22,090 --> 00:40:25,130
+من ال OH هيدروجينة و من الكربون اللي حامله
+
+446
+00:40:25,130 --> 00:40:27,850
+هيدروجينة طب الكربون اللي حامله مش حامله هيدروجينة
+
+447
+00:40:28,820 --> 00:40:33,540
+إذا الأكسدة لا تتم مع إيش؟ مع ال tertiary
+
+448
+00:40:33,540 --> 00:40:37,860
+alcohols، الآن مع ال primary وال secondary؟ بالتم،
+
+449
+00:40:37,860 --> 00:40:44,160
+شو بدها تعطيني؟الديهايد او كيتون وقت ايش بتعطي
+
+450
+00:40:44,160 --> 00:40:49,760
+الديهايد و وقت ايش بتعطي كيتون ال primary ببساطة
+
+451
+00:40:49,760 --> 00:40:55,480
+بيعطي الديهايد و ال secondary بيعطي كيتون واضح؟
+
+452
+00:40:55,480 --> 00:40:59,380
+اذا كأنه لو الانسان بده يلخص الكلام ان ال alcohol
+
+453
+00:40:59,380 --> 00:41:03,920
+في كام نوع؟ primary secondary و tertiary ال
+
+454
+00:41:03,920 --> 00:41:11,080
+tertiaryكفى الله المؤمنين القتال ..مش فيها كلمة شر
+
+455
+00:41:11,080 --> 00:41:17,300
+..وكفى الله المؤمنين القتال ال tertiary بتأكسدش ال
+
+456
+00:41:17,300 --> 00:41:22,400
+primary لما يتأكسد شو هيعطيني ال dihyde ال
+
+457
+00:41:22,400 --> 00:41:28,130
+secondary لما يتأكسد شو هيعطيني كيتونلحظته هيك
+
+458
+00:41:28,130 --> 00:41:34,290
+بيصير العلم ايش ماله؟ سهل انه ال alcohols تلاتة ال
+
+459
+00:41:34,290 --> 00:41:38,630
+primary او ال secondary او ال tertiary ال primary
+
+460
+00:41:38,630 --> 00:41:44,560
+هيعطيني aldehyde ال secondary كيتون ال tertiaryمش
+
+461
+00:41:44,560 --> 00:41:50,320
+حيت أكسد الان المرة الجاية بتجيجتين هنوضح ايش
+
+462
+00:41:50,320 --> 00:41:54,440
+العامل المؤكسد اللي بتتم فيه العملية يعني نبدأ من
+
+463
+00:41:54,440 --> 00:41:58,820
+هذه بنشرحها بتجيجتين وننتبه ان ال الديهايد ممكن
+
+464
+00:41:58,820 --> 00:42:06,400
+بعدين يعمل تفاعل تاني يصير أسد هذه زيادة واضح؟ لكن
+
+465
+00:42:06,400 --> 00:42:12,560
+الأكسد الأساسية الأولى ال primary شو بيصير؟الـ
+
+466
+00:42:12,560 --> 00:42:17,640
+secondary الـ tertiary لا يتأكسد الان ال primary
+
+467
+00:42:17,640 --> 00:42:22,200
+بعد ما يصير الديهاي ممكن لو العامل المؤكسد قوي
+
+468
+00:42:22,200 --> 00:42:28,660
+يمشي كمان مرحلة يصير أسد لو ضعيف بيظل زي ما هو إذا
+
+469
+00:42:28,660 --> 00:42:32,340
+بتصير قصتنا إيش العامل المؤكسد اللي استعملنا هان و
+
+470
+00:42:32,340 --> 00:42:37,340
+هان هان من الأساس مافيش أكسدة من هذه المقطة ان شاء
+
+471
+00:42:37,340 --> 00:42:40,120
+الله بنبدأ المرة الجاية
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..6ae450446c2170e5564f2dbcfff8d6b0d1cb84a8
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.json
@@ -0,0 +1 @@
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"probability": 0.91259765625}, {"start": 577.5, "end": 578.34, "word": " الأضعف", "probability": 0.9964599609375}, {"start": 578.34, "end": 578.56, "word": " في", "probability": 0.84228515625}, {"start": 578.56, "end": 579.38, "word": " الأربعة", "probability": 0.9381510416666666}, {"start": 579.38, "end": 581.16, "word": " ال", "probability": 0.2291259765625}, {"start": 581.16, "end": 581.76, "word": " A", "probability": 0.35791015625}, {"start": 581.76, "end": 581.96, "word": " R", "probability": 0.2454833984375}, {"start": 581.96, "end": 582.26, "word": " S", "probability": 0.98291015625}, {"start": 582.26, "end": 582.48, "word": " H", "probability": 0.900390625}, {"start": 582.48, "end": 582.68, "word": " هو", "probability": 0.81201171875}, {"start": 582.68, "end": 583.02, "word": " أقوى", "probability": 0.84576416015625}, {"start": 583.02, "end": 583.2, "word": " حاجة", "probability": 0.6792805989583334}, {"start": 583.2, "end": 583.56, "word": " ال", "probability": 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"end": 2209.3, "word": " أخدناها", "probability": 0.9638671875}, {"start": 2209.3, "end": 2209.72, "word": " هي", "probability": 0.861328125}, {"start": 2209.72, "end": 2210.64, "word": " متعلقة", "probability": 0.9806315104166666}], "temperature": 1.0}, {"id": 93, "seek": 222036, "start": 2211.92, "end": 2220.36, "text": "بالكحولات بال R O H لكن لو صارت A R O H بنزينة أو حملة O H و قلتلكوا بدلوها ب C L و ب R لأ", "tokens": [3555, 6027, 4117, 5016, 12610, 9307, 20666, 497, 422, 389, 44381, 45164, 20328, 9640, 2655, 316, 497, 422, 389, 44945, 11622, 9957, 3660, 34051, 11331, 2304, 37977, 422, 389, 4032, 12174, 1211, 2655, 23275, 14407, 47525, 1211, 2407, 11296, 4724, 383, 441, 4032, 4724, 497, 5296, 10721], "avg_logprob": -0.1974283792078495, "compression_ratio": 1.3271028037383177, "no_speech_prob": 0.0, "words": [{"start": 2211.92, "end": 2212.4, "word": "بالكحولات", "probability": 0.939697265625}, {"start": 2212.4, "end": 2212.64, "word": " بال", "probability": 0.41259765625}, {"start": 2212.64, "end": 2213.18, "word": " R", "probability": 0.52099609375}, {"start": 2213.18, "end": 2213.46, "word": " O", "probability": 0.368408203125}, {"start": 2213.46, "end": 2213.7, "word": " H", "probability": 0.9853515625}, {"start": 2213.7, "end": 2213.94, "word": " لكن", "probability": 0.724609375}, {"start": 2213.94, "end": 2214.18, "word": " لو", "probability": 0.98828125}, {"start": 2214.18, "end": 2214.66, "word": " صارت", "probability": 0.9677734375}, {"start": 2214.66, "end": 2214.9, "word": " A", "probability": 0.75244140625}, {"start": 2214.9, "end": 2215.4, "word": " R", "probability": 0.9091796875}, {"start": 2215.4, "end": 2215.66, "word": " O", "probability": 0.99365234375}, {"start": 2215.66, "end": 2216.12, "word": " H", "probability": 0.99462890625}, {"start": 2216.12, "end": 2217.16, "word": " بنزينة", "probability": 0.8310546875}, {"start": 2217.16, "end": 2217.26, "word": " أو", "probability": 0.5107421875}, {"start": 2217.26, "end": 2217.52, "word": " حملة", "probability": 0.9015299479166666}, {"start": 2217.52, "end": 2217.7, "word": " O", "probability": 0.796875}, {"start": 2217.7, "end": 2217.92, "word": " H", "probability": 0.966796875}, {"start": 2217.92, "end": 2218.02, "word": " و", "probability": 0.82763671875}, {"start": 2218.02, "end": 2218.44, "word": " قلتلكوا", "probability": 0.80126953125}, {"start": 2218.44, "end": 2218.84, "word": " بدلوها", "probability": 0.951904296875}, {"start": 2218.84, "end": 2218.94, "word": " ب", "probability": 0.9384765625}, {"start": 2218.94, "end": 2219.12, "word": " C", "probability": 0.69287109375}, {"start": 2219.12, "end": 2219.26, "word": " L", "probability": 0.91015625}, {"start": 2219.26, "end": 2219.38, "word": " و", "probability": 0.9267578125}, {"start": 2219.38, "end": 2219.5, "word": " ب", "probability": 0.8505859375}, {"start": 2219.5, "end": 2219.78, "word": " R", "probability": 0.50732421875}, {"start": 2219.78, "end": 2220.36, "word": " لأ", "probability": 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2222.08, "word": " هنا", "probability": 0.92529296875}, {"start": 2222.08, "end": 2222.72, "word": " مافيش", "probability": 0.9142252604166666}, {"start": 2222.72, "end": 2223.74, "word": " substitution", "probability": 0.9453125}, {"start": 2223.74, "end": 2224.36, "word": " في", "probability": 0.962890625}, {"start": 2224.36, "end": 2224.5, "word": " ال", "probability": 0.9443359375}, {"start": 2224.5, "end": 2225.0, "word": " aromatic", "probability": 0.94287109375}, {"start": 2225.0, "end": 2225.64, "word": " compounds", "probability": 0.95947265625}, {"start": 2225.64, "end": 2225.8, "word": " ال", "probability": 0.59716796875}, {"start": 2225.8, "end": 2226.38, "word": " substitution", "probability": 0.94677734375}, {"start": 2226.38, "end": 2226.68, "word": " في", "probability": 0.96142578125}, {"start": 2226.68, "end": 2227.84, "word": " إيش؟", "probability": 0.869873046875}, {"start": 2227.84, "end": 2228.04, "word": " في", "probability": 0.9453125}, {"start": 2228.04, "end": 2228.2, "word": " ال", "probability": 0.984375}, {"start": 2228.2, "end": 2228.9, "word": " aliphatic", "probability": 0.7069498697916666}, {"start": 2228.9, "end": 2229.72, "word": " compounds", "probability": 0.947265625}, {"start": 2229.72, "end": 2230.76, "word": " تبوا", "probability": 0.8356119791666666}, {"start": 2230.76, "end": 2230.94, "word": " هذا", "probability": 0.9228515625}, {"start": 2230.94, "end": 2231.42, "word": " الكلام", "probability": 0.9519856770833334}, {"start": 2231.42, "end": 2232.2, "word": " ممكن", "probability": 0.893310546875}, {"start": 2232.2, "end": 2232.72, "word": " نسألكوا", "probability": 0.96494140625}, {"start": 2232.72, "end": 2232.86, "word": " يا", "probability": 0.640625}, {"start": 2232.86, "end": 2233.1, "word": " صح", "probability": 0.865478515625}, {"start": 2233.1, "end": 2233.22, "word": " و", "probability": 0.98583984375}, {"start": 2233.22, "end": 2233.56, "word": " غلط", "probability": 0.9493815104166666}, {"start": 2233.56, "end": 2234.32, "word": " aromatic", "probability": 0.6591796875}, {"start": 2234.32, "end": 2235.82, "word": " alcohols", "probability": 0.90478515625}, {"start": 2235.82, "end": 2236.44, "word": " undergo", "probability": 0.94287109375}, {"start": 2236.44, "end": 2237.6, "word": " substitution", "probability": 0.96875}, {"start": 2237.6, "end": 2239.48, "word": " in", "probability": 0.95166015625}, {"start": 2239.48, "end": 2239.88, "word": " uneasy", "probability": 0.669921875}, {"start": 2239.88, "end": 2240.32, "word": " manner", "probability": 0.9033203125}, {"start": 2240.32, "end": 2240.82, "word": " مثلا", "probability": 0.97314453125}, {"start": 2240.82, "end": 2241.06, "word": " ولا", "probability": 0.85546875}, {"start": 2241.06, "end": 2242.02, "word": " ..", "probability": 0.72998046875}, {"start": 2242.02, "end": 2242.3, "word": " no", "probability": 0.537109375}, {"start": 2242.3, "end": 2242.54, "word": " they", "probability": 0.74658203125}, {"start": 2242.54, "end": 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حامله هيدروجينة طب الكربون اللي حامله مش حامله هيدروجينة", "tokens": [44510, 14407, 7251, 39237, 16247, 4117, 3794, 41891, 22807, 11933, 15730, 15844, 23032, 12610, 8032, 1863, 9566, 1211, 3615, 12174, 995, 22488, 3660, 14739, 2423, 39184, 38726, 29104, 7658, 82, 13672, 1829, 19446, 41185, 8592, 25894, 16095, 8032, 25708, 2288, 29245, 9957, 3660, 34105, 39894, 10721, 4117, 3794, 3215, 2407, 8592, 11933, 15730, 16712, 10721, 4117, 3794, 3215, 16490, 33546, 4724, 2304, 45636, 995, 22807, 2423, 6194, 4032, 2423, 11396, 16712, 13546, 2655, 8592, 9640, 1829, 19446, 3555, 9381, 43761, 5551, 4117, 3794, 41891, 32239, 8592, 22807, 5296, 33456, 16247, 4117, 3794, 3215, 47525, 10721, 5551, 5172, 28543, 9154, 2423, 13931, 8032, 25708, 2288, 29245, 9957, 3660, 4032, 9154, 33251, 25513, 11536, 13672, 1829, 11331, 10943, 43761, 8032, 25708, 2288, 29245, 9957, 3660, 23032, 3555, 33251, 25513, 11536, 13672, 1829, 11331, 10943, 43761, 37893, 11331, 10943, 43761, 8032, 25708, 2288, 29245, 9957, 3660], 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2544.0, "word": " مرحلة", "probability": 0.9730224609375}, {"start": 2544.0, "end": 2544.3, "word": " يصير", "probability": 0.9189453125}, {"start": 2544.3, "end": 2544.66, "word": " أسد", "probability": 0.62060546875}, {"start": 2544.66, "end": 2545.04, "word": " لو", "probability": 0.90771484375}, {"start": 2545.04, "end": 2545.64, "word": " ضعيف", "probability": 0.9871419270833334}, {"start": 2545.64, "end": 2547.48, "word": " بيظل", "probability": 0.67840576171875}, {"start": 2547.48, "end": 2547.78, "word": " زي", "probability": 0.912841796875}, {"start": 2547.78, "end": 2547.86, "word": " ما", "probability": 0.94482421875}, {"start": 2547.86, "end": 2548.12, "word": " هو", "probability": 0.99658203125}, {"start": 2548.12, "end": 2548.66, "word": " إذا", "probability": 0.69091796875}, {"start": 2548.66, "end": 2549.08, "word": " بتصير", "probability": 0.9593098958333334}, {"start": 2549.08, "end": 2549.7, "word": " قصتنا", "probability": 0.9954833984375}, {"start": 2549.7, "end": 2550.18, "word": " إيش", "probability": 0.82958984375}, {"start": 2550.18, "end": 2550.62, "word": " العامل", "probability": 0.99072265625}, {"start": 2550.62, "end": 2551.18, "word": " المؤكسد", "probability": 0.99365234375}, {"start": 2551.18, "end": 2551.3, "word": " اللي", "probability": 0.841064453125}, {"start": 2551.3, "end": 2551.82, "word": " استعملنا", "probability": 0.90625}, {"start": 2551.82, "end": 2552.14, "word": " هان", "probability": 0.5582275390625}, {"start": 2552.14, "end": 2552.34, "word": " و", "probability": 0.61865234375}, {"start": 2552.34, "end": 2552.66, "word": " هان", "probability": 0.84765625}, {"start": 2552.66, "end": 2553.12, "word": " هان", "probability": 0.6961669921875}, {"start": 2553.12, "end": 2553.28, "word": " من", "probability": 0.60791015625}, {"start": 2553.28, "end": 2553.88, "word": " الأساس", "probability": 0.98046875}, {"start": 2553.88, "end": 2555.28, "word": " مافيش", "probability": 0.9251302083333334}, {"start": 2555.28, "end": 2555.98, "word": " أكسدة", "probability": 0.713671875}, {"start": 2555.98, "end": 2556.36, "word": " من", "probability": 0.90966796875}, {"start": 2556.36, "end": 2556.6, "word": " هذه", "probability": 0.92822265625}, {"start": 2556.6, "end": 2557.0, "word": " المقطة", "probability": 0.771728515625}, {"start": 2557.0, "end": 2557.16, "word": " ان", "probability": 0.66455078125}, {"start": 2557.16, "end": 2557.34, "word": " شاء", "probability": 0.95654296875}, {"start": 2557.34, "end": 2557.44, "word": " الله", "probability": 0.9580078125}, {"start": 2557.44, "end": 2558.08, "word": " بنبدأ", "probability": 0.8997395833333334}, {"start": 2558.08, "end": 2558.54, "word": " المرة", "probability": 0.97509765625}, {"start": 2558.54, "end": 2560.12, "word": " الجاية", "probability": 0.7242838541666666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2560.92875, "duration_after_vad": 2451.335624999991}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..7be7452f0f81323e1dd5a708258e82498d9b65cb
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_postprocess.srt
@@ -0,0 +1,1992 @@
+1
+00:00:20,330 --> 00:00:25,410
+بسم الله الرحمن الرحيم اليوم ان شاء الله درسنا مش
+
+2
+00:00:25,410 --> 00:00:30,670
+في موضوع معين لأ هو مراجعة شاملة من خلال حل
+
+3
+00:00:30,670 --> 00:00:36,320
+الامتحانات السابقة استعدادا للامتحانالنصفي ربما
+
+4
+00:00:36,320 --> 00:00:40,320
+أحيانا اتلاحظوا بعض الأسئلة لامتحان النصفي كان
+
+5
+00:00:40,320 --> 00:00:44,380
+للفصل السابع المرة هذه طلبنا منكوا للفصل السادس
+
+6
+00:00:44,380 --> 00:00:49,160
+فمش مشكلة يعني الإنسان بيقدر يعرف الأسئلة هتلاحظوا
+
+7
+00:00:49,160 --> 00:00:54,980
+ان في عندنا أسئلة متنوعة بشكل عام دائما ننصح
+
+8
+00:00:54,980 --> 00:01:01,250
+الطلاب انه يهتموابالأفكار الأساسية العامة يكونوا
+
+9
+00:01:01,250 --> 00:01:06,030
+فاهمينها بنسبة أكبر هذا بمنعش أنه في أشياء متخصصة
+
+10
+00:01:06,030 --> 00:01:09,730
+لكن دائما الطالب أول شيء يجب أن يكون عنده يعني
+
+11
+00:01:09,730 --> 00:01:14,190
+قناع أن هو فاهم الاشي الأفكار العامة ولذلك ربما
+
+12
+00:01:14,190 --> 00:01:19,110
+تلاحظوا أنه يعني لو أنا بدأ أصنف الأسئلة مش في هذا
+
+13
+00:01:19,110 --> 00:01:24,450
+الامتحان في معظم الامتحانات هنكتشف أنه هي عنوين
+
+14
+00:01:25,470 --> 00:01:30,250
+يعني هي عنوين لأشياء احنا درسناها خلينا نشوف هذا
+
+15
+00:01:30,250 --> 00:01:35,710
+الكلام من خلال التطبيق الآن في هذا الامتحان اللي
+
+16
+00:01:35,710 --> 00:01:41,350
+أمامنا في عندنا مجموعة من الجمال هذه المجموعة من
+
+17
+00:01:41,350 --> 00:01:46,450
+الجمال بدنا نكمل الفراغ فيها complete the
+
+18
+00:01:46,450 --> 00:01:50,450
+following السؤال أول مثلا بيسألنا الدياستيريو
+
+19
+00:01:50,450 --> 00:01:55,210
+مارزهاف و بيحكي عن ال physical propertiesالان كان
+
+20
+00:01:55,210 --> 00:01:58,970
+واضح تماما ان ال بيستيريو مارز هيف different
+
+21
+00:01:58,970 --> 00:02:02,390
+physical
+
+22
+00:02:02,390 --> 00:02:10,670
+properties واضح الان السؤال التاني addition of HBr
+
+23
+00:02:10,670 --> 00:02:17,410
+H plus to isobutene produces لاحظوا هنا السؤال هذا
+
+24
+00:02:17,410 --> 00:02:22,070
+في فكرتين ان الطالب لازم في الأول يعرف ايش هو ال
+
+25
+00:02:22,070 --> 00:02:28,970
+isobuteneهذا ال isobutene واضح بعد هيك إضافة ال
+
+26
+00:02:28,970 --> 00:02:35,930
+HBR H plus معناه ذلك هذه إضافة حسب Markov-Nikov
+
+27
+00:02:35,930 --> 00:02:40,670
+addition يعني هذه بدها تروح يجي عند هنا H و يجي
+
+28
+00:02:40,670 --> 00:02:44,070
+عند هنا CL او PR و بنحكي عن PR
+
+29
+00:02:47,350 --> 00:02:53,650
+الان هذا المركب اللى طلع عندى carbon حاملة CH3 CH3
+
+30
+00:02:53,650 --> 00:03:01,230
+CH3Br هذه مجموعة لها اسم ولا لأ تيرتشاري بيوتل
+
+31
+00:03:01,230 --> 00:03:09,310
+إبرومايد produces tertiary butyl bromide من تسمية
+
+32
+00:03:09,310 --> 00:03:16,810
+المجموعات produces tertiary butyl bromideالان فكرة
+
+33
+00:03:16,810 --> 00:03:20,890
+عامة قلنا ال branched alkanes اللي هم ال boiling
+
+34
+00:03:20,890 --> 00:03:23,930
+point و ال melting point lower than ال chain
+
+35
+00:03:23,930 --> 00:03:28,390
+alkanes الان ال branched alkanes هم اكيد هنا هتكون
+
+36
+00:03:28,390 --> 00:03:32,110
+higher او lower boiling point than the
+
+37
+00:03:32,110 --> 00:03:37,890
+corresponding chain lower ال
+
+38
+00:03:37,890 --> 00:03:44,850
+curved arrows قلنا عنهمالهم رأسين are used to
+
+39
+00:03:44,850 --> 00:03:53,830
+indicate the movement of two electrons ممتاز ال
+
+40
+00:03:53,830 --> 00:04:00,350
+reaction المهم من البنزين هو أي تحديد تحديد
+
+41
+00:04:00,350 --> 00:04:07,070
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+42
+00:04:07,070 --> 00:04:10,130
+الهواتف الهواتف
+
+43
+00:04:10,130 --> 00:04:10,910
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+44
+00:04:10,910 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+45
+00:04:11,810 --> 00:04:24,490
+الكلهيليتز اليوكليوفيليك اليوكليوفيليك
+
+46
+00:04:28,790 --> 00:04:33,570
+Dipromination of a Neopentane gives a total of ..
+
+47
+00:04:33,570 --> 00:04:38,110
+لاحظوا معي تكونوا عارفين لـ Neopentane يعني أنا
+
+48
+00:04:38,110 --> 00:04:41,950
+هنا باختبركم أن تكونوا عارفين هذا المُركّب لـ
+
+49
+00:04:41,950 --> 00:04:45,470
+Neopentane اللي هي الكربون اللي حاملة كام مثل؟
+
+50
+00:04:45,470 --> 00:04:49,910
+أربعة الأربعة الأربعة دي دي Dipromination
+
+51
+00:04:51,580 --> 00:04:57,320
+يعني احض ذرتين abroad كم ناتج بتوقع التنتين ممكن
+
+52
+00:04:57,320 --> 00:05:00,880
+ييجوا على نفس الذرع اذا اجوا تنتين هان زي هان زي
+
+53
+00:05:00,880 --> 00:05:08,060
+هان و ممكن ييجوا علىدرتين مختلفتين يعني ايه ييجي
+
+54
+00:05:08,060 --> 00:05:12,460
+هان و هان لحظوا هان و هان زي هذه و هذه زي هذه و
+
+55
+00:05:12,460 --> 00:05:15,860
+هذه زي هذه و هذه لأن المجموعات كلها ماخدة
+
+56
+00:05:15,860 --> 00:05:19,140
+tetrahedral arrangement متذكرين لما كنا نقول مافيش
+
+57
+00:05:19,140 --> 00:05:23,100
+اشي اسمه مجموعتين جان بعض و اشي اسمه مجموعتين قبال
+
+58
+00:05:23,100 --> 00:05:27,280
+بعض يعني تيجي طالبة تقول حط ال .. البروم هان و هان
+
+59
+00:05:27,280 --> 00:05:30,860
+بتختلف عن البروم هان و هان لأ هذه الزاوية PR, CPR
+
+60
+00:05:30,860 --> 00:05:37,280
+قداش مقدارهامية و تسعة و نص كربون حملة PR كربون كم
+
+61
+00:05:37,280 --> 00:05:40,640
+.. كربون حملة PR كدهش مقدارها؟ مية و تسعة و نص إذا
+
+62
+00:05:40,640 --> 00:05:45,260
+كم ناتج هنا؟ أربعة ليش أربعة؟ مش هو two bromine
+
+63
+00:05:45,260 --> 00:05:50,800
+atoms طيب انا .. انا حطيت two bromine atoms أو
+
+64
+00:05:50,800 --> 00:05:53,720
+حطيت وحدها وحدها هاي معناه die bromination طيب و
+
+65
+00:05:53,720 --> 00:05:57,100
+لو حطنا على ال carbon نفل نص ال carbon نفل نص
+
+66
+00:05:57,100 --> 00:05:58,540
+بيصير على خمس روابط؟
+
+67
+00:06:01,850 --> 00:06:05,670
+يا التنتين على هذه الذرة، يا التنتين كل واحدة على
+
+68
+00:06:05,670 --> 00:06:11,690
+ذرة، سواء كانت هان أو هان أو هان، إذا كان مركب two
+
+69
+00:06:11,690 --> 00:06:15,910
+isomers، structural isomers of course
+
+70
+00:06:18,990 --> 00:06:24,790
+The IUPAC name of allyl chloride لاحظوا كام سؤال
+
+71
+00:06:24,790 --> 00:06:28,970
+صار جايكم اؤكد انكوا تكونوا عارفين المجموعات
+
+72
+00:06:28,970 --> 00:06:32,150
+والمركبات الأساسية اللي أخدناها جيبنا ال tertiary
+
+73
+00:06:32,150 --> 00:06:38,430
+butyl هاي جيبنا ال allyl اللي هي CH2 CH double
+
+74
+00:06:38,430 --> 00:06:44,770
+bond CH2 Hanachlor وقولنا سابقا ان هذا بدو يتسمى
+
+75
+00:06:44,770 --> 00:06:53,810
+واحد اتنينتلاتة اذا three chloro one
+
+76
+00:06:53,810 --> 00:07:04,450
+propene three chloro one propene واضح؟
+
+77
+00:07:04,450 --> 00:07:09,150
+فحفظ المجموعات بين القليل ايزو بروبيل ايزو بيوتل
+
+78
+00:07:09,150 --> 00:07:13,250
+اساسي جداgeneration of the second chiral center
+
+79
+00:07:13,250 --> 00:07:19,290
+produces unequal mixture of diastereomers هذا أكمل
+
+80
+00:07:19,290 --> 00:07:26,470
+الجواب، هيك العنوان صح ولا لأ؟ unequal mixture of
+
+81
+00:07:26,470 --> 00:07:32,470
+diastereomers والfirst
+
+82
+00:07:32,470 --> 00:07:36,350
+chiral center شو كان بيعمل؟ racemic mixture of
+
+83
+00:07:36,350 --> 00:07:42,090
+enantiomers the meso compound is opticallyinactive
+
+84
+00:07:42,090 --> 00:07:47,630
+كان عنوان meso compounds are optically inactive
+
+85
+00:07:47,630 --> 00:07:54,790
+واضح هي دي مراجعة شاملة خلينا نقوله بعتقد جميلة
+
+86
+00:07:54,790 --> 00:07:59,930
+لمفاهيم أساسية أخدناها واضحة
+
+87
+00:08:12,680 --> 00:08:18,980
+الان بعد هيك ارسمولنا أشكال بعض المركبات
+
+88
+00:08:18,980 --> 00:08:22,000
+Cyclobentane
+
+89
+00:08:22,000 --> 00:08:26,500
+مين ما بيعرفوا ال Cyclobentane؟ هاي ال
+
+90
+00:08:26,500 --> 00:08:30,500
+Cyclobentane أسس على نمرة واحد و تلت يعني لو قولنا
+
+91
+00:08:30,500 --> 00:08:38,230
+هنا مثلا خلينا نحط إبروم للأمام وهنابروم هاي واحد
+
+92
+00:08:38,230 --> 00:08:43,990
+اتنين تلاتة وستعملنا
+
+93
+00:08:43,990 --> 00:08:51,070
+الشكل الفراغي عشان نبين انه مجموعتين للامام الان
+
+94
+00:08:51,070 --> 00:08:58,450
+Cyclohexane نعرف ال Cyclohexane هاي Cyclohexane
+
+95
+00:08:58,450 --> 00:09:03,980
+والترقيم بيكون واحدتنين و نستمر نمر عبر ال double
+
+96
+00:09:03,980 --> 00:09:09,280
+bond صح ولا لأ يعني واحد اتنين تلاتة اربعة خمسة
+
+97
+00:09:09,280 --> 00:09:12,280
+ستة الان على نمرة اتنين ايش في اندي في ال
+
+98
+00:09:12,280 --> 00:09:24,860
+Cyclohexane بروم وعلى نمرة تلاتة isopropyl for
+
+99
+00:09:24,860 --> 00:09:32,020
+nitroicumin اخدنا الاكيومين انه ال isopropylبنزين
+
+100
+00:09:32,020 --> 00:09:38,360
+قلنا ايزوبروب البنزين is كيومين لما بتحط على
+
+101
+00:09:38,360 --> 00:09:49,060
+الأربعة ن او اتو for نيترو كيومين الان المركب هذا
+
+102
+00:09:49,060 --> 00:09:54,420
+بدنا نسميه اين و اين ضايقين
+
+103
+00:09:55,420 --> 00:10:01,040
+لما بدنا ننتبه من وين بدنا نعمل الترقيم يعني واحد
+
+104
+00:10:01,040 --> 00:10:06,460
+اتنين تلاتة اربعة خمسة و هنا في كمان carbon ستة
+
+105
+00:10:06,460 --> 00:10:10,840
+طبعا لاحظوا انه انا لو برقم من هنا بيكون double
+
+106
+00:10:10,840 --> 00:10:16,120
+points عند اتنينوخمسة لو برقم هنا عند واحد اتنين
+
+107
+00:10:16,120 --> 00:10:19,860
+واحد واربعة لازم اسعى ان ال double poles يكونوا
+
+108
+00:10:19,860 --> 00:10:25,160
+اقل ترقيم اذا هذا هقول واحد اتنين تلاتة اربعة خمسة
+
+109
+00:10:25,160 --> 00:10:33,960
+ستة فهذا المركب هيكون one four hexadien
+
+110
+00:10:33,960 --> 00:10:41,370
+ايش بيحمل على نمرة تلاتة وعلى نمرة اربعةأه إذا هذا
+
+111
+00:10:41,370 --> 00:10:49,490
+كمان بدو ييجي عليه three four diapromo one four
+
+112
+00:10:49,490 --> 00:10:55,660
+الآن هذا double bondمافيش عليها مجموعات مختلفان و
+
+113
+00:10:55,660 --> 00:10:58,500
+.. يعني مافيش فيها ظاهرة ال sexual trance بس هذا
+
+114
+00:10:58,500 --> 00:11:02,700
+ال double bond فيها .. يعني هنا في عندى مثل و أتش،
+
+115
+00:11:02,700 --> 00:11:07,040
+لاحظوا كل رأس زي هذا يعتبر مثل، انتبهوله في العد و
+
+116
+00:11:07,040 --> 00:11:12,110
+انتبهوله لما تشتغلوا، المثل أعلى من الأتشالمثل
+
+117
+00:11:12,110 --> 00:11:17,350
+أعلى من الـ H هنا PR و Carbon أنا باطلع فقط على
+
+118
+00:11:17,350 --> 00:11:20,470
+الذرة الأولى و الأولى هذه PR وهذه Carbon الآن
+
+119
+00:11:20,470 --> 00:11:25,410
+هذولا المجمعتين على جهة واحدة إذا هذا المركب Z
+
+120
+00:11:25,410 --> 00:11:31,610
+فلما بدي تسمية كاملة Z three four dibromo one four
+
+121
+00:11:31,610 --> 00:11:33,050
+hexadien
+
+122
+00:11:35,670 --> 00:11:38,790
+واضح؟ ال double bond التانية مافيش فيها أي شيء
+
+123
+00:11:38,790 --> 00:11:42,490
+طبعا واضح أنه هنا في chiral center لكن طالما أنا
+
+124
+00:11:42,490 --> 00:11:47,010
+ماحطتوش على شكل صليب معناه ذلك أنا مش مركز أني
+
+125
+00:11:47,010 --> 00:11:54,470
+اتحددولي IR أو استركتو مفتوح هذا المركب مثلا في
+
+126
+00:11:54,470 --> 00:11:58,330
+chiral center وموضح أنه أنا طالب ال chiral center
+
+127
+00:11:58,330 --> 00:12:06,270
+هنا واضح؟ لو أتيت طلعت أطول سلسلةانعلمها بالاحمر
+
+128
+00:12:06,270 --> 00:12:14,430
+واحد اتنين تلاتة اربعة اذا هذا بيوتين ايش بيحمل
+
+129
+00:12:14,430 --> 00:12:19,450
+هذا البيوتين على البيوتين واحد اتنين تلاتة اربعة
+
+130
+00:12:19,450 --> 00:12:26,870
+على نمرة واحد اكلور وعلى نمرة تلاتة فنل والترقيم
+
+131
+00:12:26,870 --> 00:12:29,770
+منها لان لو رقمتي منها هيصيروا على اتنين واربعة
+
+132
+00:12:29,770 --> 00:12:38,510
+بدي ال lower numbering اذا هذاone chloro three
+
+133
+00:12:38,510 --> 00:12:47,330
+phenyl بيوتين الان في chiral center ال chiral
+
+134
+00:12:47,330 --> 00:12:53,370
+center هنا ال H أقل مجموعة أكيد البنزينة نمرة واحد
+
+135
+00:12:53,370 --> 00:13:00,310
+الكاربون هذه نمرة اتنين وال CH3 نمرة تلاتةواحد
+
+136
+00:13:00,310 --> 00:13:06,870
+اتنين تلاتة وهذه موجودة اذا هذا اس one chlorine
+
+137
+00:13:06,870 --> 00:13:08,750
+three phenyl butane
+
+138
+00:13:15,300 --> 00:13:19,960
+المُركّب اللي بعده aromatic فيه مجموعتين، معنا ذلك
+
+139
+00:13:19,960 --> 00:13:24,020
+السؤال إنه مين أعلى في الأولوية عشان أسمه إيه؟ ال
+
+140
+00:13:24,020 --> 00:13:27,600
+ketone ولا ال alcohol؟ ال ketone، الآن هذا
+
+141
+00:13:27,600 --> 00:13:32,320
+المُركّب إيش اسمه؟ أسيتوفينون، نكتب small letter
+
+142
+00:13:34,690 --> 00:13:40,030
+acetophenon ال O H بترجع على أصلها ال three one
+
+143
+00:13:40,030 --> 00:13:45,710
+two three ال three أو ميتا هيدروكسي الشغلتين صح ال
+
+144
+00:13:45,710 --> 00:13:50,470
+three هيدروكسي أسيتوفينون كلمة واحدة واضح ال three
+
+145
+00:13:50,470 --> 00:13:57,030
+هيدروكسي أسيتوفينون بتيعني كل هذه من ضمن الأفكار
+
+146
+00:13:57,030 --> 00:14:01,610
+العامة الأساسية اللي احنا درسناكم
+
+147
+00:14:18,380 --> 00:14:25,580
+الان بعد ذلك عندى اكمال معادلات هذا المركب مثل
+
+148
+00:14:25,580 --> 00:14:32,160
+Cyclopropane مثل Cyclopropane وحطينا لكوا بدنا
+
+149
+00:14:32,160 --> 00:14:37,020
+نشوف all structural isomers يعني مش مركز انا على
+
+150
+00:14:37,020 --> 00:14:40,720
+ال stereo isomers او اعمله monochlorination يعني
+
+151
+00:14:40,720 --> 00:14:46,860
+احط one chlorine atomواضح؟ وين بده احط هذه ال
+
+152
+00:14:46,860 --> 00:14:55,400
+chlorine طبعا هنبدأ نرسم اكثر من شكل مش عارف تلاتة
+
+153
+00:14:55,400 --> 00:14:59,900
+اربعة بنجرب احنا الان اكيد ال chlorine بإمكانها
+
+154
+00:14:59,900 --> 00:15:06,810
+تيجي هنا على المثلوأكيد ال chlorine بإمكانها تيجي
+
+155
+00:15:06,810 --> 00:15:11,250
+على هذا الموقع وأكيد ال chlorine بإمكانها تيجي على
+
+156
+00:15:11,250 --> 00:15:15,510
+هذا الموقع لأن هذا و هذا زي بعض، ضال عندكم إشي
+
+157
+00:15:15,510 --> 00:15:21,170
+تاني؟ خلاص وكل
+
+158
+00:15:21,170 --> 00:15:23,210
+واحد فيهم أكيد إله اسم مختلف
+
+159
+00:15:29,980 --> 00:15:35,600
+الان لاحظوا معي هذا المركب فيه double bond بنقول
+
+160
+00:15:35,600 --> 00:15:40,880
+في نمر واحد بدنا نضيف عليه pear acid ايش معناه
+
+161
+00:15:40,880 --> 00:15:48,260
+pear acid انه بده يلغي هذه و يعملي حلقة لكن انا
+
+162
+00:15:48,260 --> 00:15:53,160
+كمان بعد ما عملت هذه الحلقة بده اعمل ring opening
+
+163
+00:15:53,160 --> 00:15:59,920
+ضيفت ميهواضحة الفكرة؟ كيف هذي بتعمل ring opening؟
+
+164
+00:15:59,920 --> 00:16:07,240
+بيكونوا سن ولا أنتي؟ مجموعات ال OHS ال
+
+165
+00:16:07,240 --> 00:16:10,360
+ring opening من البرأس الانتي
+
+166
+00:16:12,610 --> 00:16:17,550
+هي الميه من وين بتيجي عكس هذه اللي كان يعمل sin
+
+167
+00:16:17,550 --> 00:16:22,350
+addition لمجموعتين OH الكيامان O4 والأزوميوم O4
+
+168
+00:16:22,350 --> 00:16:27,590
+أخدناهم بيعملوا sin addition لمجموعتين OH لكن بهذه
+
+169
+00:16:27,590 --> 00:16:31,890
+الطريقة بنطلع ال Anti product اللي كان واضح تماما
+
+170
+00:16:31,890 --> 00:16:37,350
+يعني بدكوا تحطوا OH على جهة و OH على الجهة التانية
+
+171
+00:16:37,350 --> 00:16:42,720
+بالتأكيد هنا هتكون هذه المجموعة هيكهيأجوا اشمالهم
+
+172
+00:16:42,720 --> 00:16:47,880
+انتي طبعا
+
+173
+00:16:47,880 --> 00:16:51,600
+اي واحدة متذاكرة جيدا مش ضروري تفكر تعمل زي هيك
+
+174
+00:16:51,600 --> 00:16:54,900
+خلاص هو ال bare acid و بعدين نعمل ring opening في
+
+175
+00:16:54,900 --> 00:17:00,660
+الميه هذا محصلته في الدماغ بيحط مجمعتين OH انتي
+
+176
+00:17:00,660 --> 00:17:09,120
+انتي طبعا الان لما نضيف H2 في وجود platinum
+
+177
+00:17:20,030 --> 00:17:25,790
+هذا المُركّب اللي فيه ال PR لحظة انا هنا حاططلكم
+
+178
+00:17:25,790 --> 00:17:29,290
+KOH و جايلكم ان انا بدي ال major elimination
+
+179
+00:17:29,290 --> 00:17:33,950
+product كأني بقول انو حطوا double bond هان او هان
+
+180
+00:17:33,950 --> 00:17:39,750
+واضح انه كتير ركزنا معاكم انه the more substituted
+
+181
+00:17:39,750 --> 00:17:44,710
+ال keenوالـ Form حسب قاعدة Zaitsev إذا هنا بدو
+
+182
+00:17:44,710 --> 00:17:52,170
+ييجي ال الـ K واضح؟ مش هتيجي ال PR مع هذه ال H لأن
+
+183
+00:17:52,170 --> 00:17:56,530
+هذا less substituted ال K هذا ال more substituted
+
+184
+00:17:56,530 --> 00:18:00,890
+الآن بعد هيك هذا المركب بدنا نضيف عليه ميا في وجود
+
+185
+00:18:00,890 --> 00:18:06,590
+H plus هذا إضافة Markovnikov لحظة هنا في carbon
+
+186
+00:18:06,590 --> 00:18:12,190
+تحمل H و هذه ال carbon لأ تحملش H إذالو حطينا
+
+187
+00:18:12,190 --> 00:18:19,390
+الشكل العام بس بتكون المشكلة وين أحط ال H وين أحط
+
+188
+00:18:19,390 --> 00:18:30,150
+ال OH حسب
+
+189
+00:18:30,150 --> 00:18:36,430
+قاعدة Markovnikov لأنه في الأساس هنا في عندكم H
+
+190
+00:18:36,430 --> 00:18:38,650
+اللي كانت متروكة فاضية
+
+191
+00:18:56,340 --> 00:19:03,760
+الان هنا بدنا نضيف HPR في وجود البروكسايد اذا هنا
+
+192
+00:19:03,760 --> 00:19:09,600
+الإضافة مع ولا عكس قاعدة Markovnikov عكس قاعدة
+
+193
+00:19:09,600 --> 00:19:15,520
+Markovnikov لاحظوا لما انا هنا بد اضيف H على هذه
+
+194
+00:19:15,520 --> 00:19:21,870
+الجهة و ال PR على اللي بتحمل Hانتبهوا معي ال H هنا
+
+195
+00:19:21,870 --> 00:19:26,350
+طالما عندكم مثل و مثل ماعملتش chiral center هنا
+
+196
+00:19:26,350 --> 00:19:30,390
+لأن هدول المجموعتين زي بعض يعني مافيش اد اربع
+
+197
+00:19:30,390 --> 00:19:35,850
+مجموعات مختلفة لكن هنا بدي يكون عندكم مثل و H و
+
+198
+00:19:35,850 --> 00:19:44,410
+هتيجيها ب Rهي مثل وهي H و إيش هيجي عندك PR في هذه
+
+199
+00:19:44,410 --> 00:19:50,450
+الحالة حيصير في كايرال سنتر على هذا الكربون الان
+
+200
+00:19:50,450 --> 00:19:56,410
+ال generation و في كايرال سنتر شو بيطلعلك رسمك
+
+201
+00:19:56,410 --> 00:20:01,550
+mixture كان هذا عنوان إذا انا لما بدي أجي أشتغل
+
+202
+00:20:01,550 --> 00:20:07,250
+الأصل بدي أشتغل بهذا الشكلهدولة بأي طريقة تكتبوها
+
+203
+00:20:07,250 --> 00:20:10,370
+مافيش فيها مشكلة إطلاقا لأنه مش chiral center في
+
+204
+00:20:10,370 --> 00:20:14,410
+النهاية يعني
+
+205
+00:20:14,410 --> 00:20:19,050
+لو كتبيه بأي طريقة مش مشكلة لكن هنا بدي أجي مثلا
+
+206
+00:20:19,050 --> 00:20:25,470
+أقول ال PR هان ال PR عكسها ممكن نكتب ال H و ال H و
+
+207
+00:20:25,470 --> 00:20:30,710
+نكتبالـ CH3 والـ CH3 أهم شيء نعمله .. أهم شيء
+
+208
+00:20:30,710 --> 00:20:38,610
+نعمله أن هذه المنطقة يكونوا هذولة أشملهم عكس بعض و
+
+209
+00:20:38,610 --> 00:20:42,330
+هذولة بيطلعوا ال 50 50 ratio
+
+210
+00:20:44,190 --> 00:20:47,510
+الان بأي طريقة تكتبوها مافيش مشكلة مش هيكون خلاف
+
+211
+00:20:47,510 --> 00:20:51,270
+يعني واحدة كتبت هنا PR و هنا CH3 و هنا H و عملت
+
+212
+00:20:51,270 --> 00:20:54,770
+صورتها مش مشكلة واحدة كتبت هنا CH3 و هنا H و هنا
+
+213
+00:20:54,770 --> 00:21:01,330
+PR مافيش مشكلة اهم يعني ارسموا التلاتة بأي شكل
+
+214
+00:21:01,330 --> 00:21:06,150
+بدكم إياه بس حطوا صورتهم في المرايا لو احنا نفس
+
+215
+00:21:06,150 --> 00:21:08,930
+الشكل بس شيلنا لابتا ثنائية و حاطينا ال PR هيك و
+
+216
+00:21:08,930 --> 00:21:10,770
+هيك وين تحط ال PR؟
+
+217
+00:21:25,670 --> 00:21:29,510
+الان السؤال اللي بعده draw all the possible
+
+218
+00:21:29,510 --> 00:21:34,870
+isomers having the formula C3H4
+
+219
+00:21:35,800 --> 00:21:41,180
+الان عندما تفكر في هذا الكلام تفكر في صيغة العامة
+
+220
+00:21:41,180 --> 00:21:52,320
+للمركبات الوضع الطبيعي ال C3 بتاخد HS في
+
+221
+00:21:52,320 --> 00:21:59,470
+الألكال اللي كله single bonds يعني ال C3H8 في
+
+222
+00:21:59,470 --> 00:22:07,170
+الالكينز صح؟ الان اذا شيلت منها هيدروجينتين صارت
+
+223
+00:22:07,170 --> 00:22:12,870
+C3H6 مقابل ان شيلتم يا عملت bubble bond يا حلقة
+
+224
+00:22:12,870 --> 00:22:17,910
+الان لسه انا مش بس هيدروجنتين بده اشيل كمان تنتين
+
+225
+00:22:17,910 --> 00:22:22,690
+يعني شيلت هيدروجنتين وكمان هيدروجنتين معنى ذلك
+
+226
+00:22:22,690 --> 00:22:27,870
+التفكير اللي بده يكون عندكم اما تنتين bubble bonds
+
+227
+00:22:28,750 --> 00:22:35,290
+أو تنتين حلقات او حلقة و double bond واضح؟ لأن كل
+
+228
+00:22:35,290 --> 00:22:39,130
+هيدروجينتين معناهم ان انت شيلتوا ايش؟ يا عملتوا
+
+229
+00:22:39,130 --> 00:22:42,810
+double bond يا عملتوا حلقة واضح؟ فانا شيلت
+
+230
+00:22:42,810 --> 00:22:46,310
+هيدروجين مرتين بين التمانية والاربعة اربع
+
+231
+00:22:46,310 --> 00:22:50,750
+هيدروجينات تنتين و تنتين الآن بدكوا تقولوا يا
+
+232
+00:22:50,750 --> 00:22:54,790
+تنتين double bonds يا تنتين حلقات يا double bond
+
+233
+00:22:54,790 --> 00:23:01,040
+وحلقة طبعا ال C3H4 ما بتحتملتلتين حلقات يعني كلها
+
+234
+00:23:01,040 --> 00:23:05,860
+كم ذرة هي تلاتة بناء على ذلك لو أنا فكرت أني بدأ
+
+235
+00:23:05,860 --> 00:23:10,220
+أعمل منهم حلقة حلقة واحدة لازم ألاحقها بكمان ايش
+
+236
+00:23:10,220 --> 00:23:14,760
+double bond لاحظوا لو هنا اتيتوا تكملوا ال
+
+237
+00:23:14,760 --> 00:23:20,420
+hydrogens هتطلع الفورموله صح اتش اتش اتش اتش اتش
+
+238
+00:23:20,420 --> 00:23:23,500
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+239
+00:23:26,930 --> 00:23:32,270
+هذا الاحتمال اللى فيه حلقات الان بعد هيك ممكن اعمل
+
+240
+00:23:32,270 --> 00:23:37,870
+التنتين bubble bonds اعتبرهم ال kind triple bond
+
+241
+00:23:37,870 --> 00:23:48,130
+يعني احط C triple bond C و هنا CH3 CH3
+
+242
+00:23:48,130 --> 00:23:55,510
+و هذه H هدولة بمثابة تنتين bubble bonds هاي CH3
+
+243
+00:23:57,130 --> 00:24:02,770
+ممكن احط تنتين double bonds جانب بعض carbon double
+
+244
+00:24:02,770 --> 00:24:07,490
+bond carbon double bond carbon وهنا بدو يكون عندكم
+
+245
+00:24:07,490 --> 00:24:14,490
+CH2 CH2
+
+246
+00:24:14,490 --> 00:24:15,910
+في غير هيك؟
+
+247
+00:24:19,310 --> 00:24:23,910
+أهم شيء اللى بنى عليها هذا السؤال انه نفهم احنا ان
+
+248
+00:24:23,910 --> 00:24:31,610
+الصيغة المشبعة تماما لل C3 هي H8 الان مقابل كل
+
+249
+00:24:31,610 --> 00:24:35,990
+هيدروجينتين بخصومهم بدي اعمل double bond او حلقة
+
+250
+00:24:35,990 --> 00:24:41,170
+واضح فخصمت هيدروجنتين على كام مرة امرتين اربعة
+
+251
+00:24:41,170 --> 00:24:44,730
+تقسيم اتنين اتنين فهنا عملت حلقة و double bond هنا
+
+252
+00:24:44,730 --> 00:24:47,370
+عملت تنتين by bonds هنا عملت تنتين double bonds
+
+253
+00:24:49,120 --> 00:24:53,720
+ولما تكملوا الشكل كيميائيا شكل سليم 100% ولا لأ؟
+
+254
+00:25:08,560 --> 00:25:13,280
+الان هذا السؤال نمشي أسرع على تفاعل ال الكاينز
+
+255
+00:25:13,280 --> 00:25:17,380
+قلنا ال terminal الكاينز are acidic يعني هذا شو
+
+256
+00:25:17,380 --> 00:25:23,400
+بده يعطينا فنل C triple bond C minus الان إذا
+
+257
+00:25:23,400 --> 00:25:31,440
+فعلتوا مع إيثالبروميد CH3 CH2Br بده يعمل عليها ال
+
+258
+00:25:31,440 --> 00:25:36,890
+eucleophilic substitution هذه الكربون اتهاجمهاتطرد
+
+259
+00:25:36,890 --> 00:25:43,610
+ال PR ما هو ذا نيوكليو 5 إذا النتيجة فينيل C
+
+260
+00:25:43,610 --> 00:25:55,130
+triple bond C وهنا هياتحدت مع CH2 CH3 طردت ال PR
+
+261
+00:25:55,130 --> 00:26:02,330
+إبدالي نيوكليو فينيل الان هذا المركب مع ال lithium
+
+262
+00:26:02,330 --> 00:26:07,730
+و ال ammonia شو بيعمل؟Double bond هو اكيد بيضيف
+
+263
+00:26:07,730 --> 00:26:16,630
+الهيدروجين عكس بعض لكن مافيش فارق بالنتيجة هايو
+
+264
+00:26:16,630 --> 00:26:20,910
+الهيدروجين اللي ضفته كيف اجوا عكس بعض لكن المراكب
+
+265
+00:26:20,910 --> 00:26:26,810
+لا فيه cis ولا trans لأن هدوله زي بعض الان بعد هيك
+
+266
+00:26:26,810 --> 00:26:30,450
+هذا المراكب بتعمله اوزونوليسيز شو ال اوزونوليسيز
+
+267
+00:26:30,450 --> 00:26:35,130
+نكسر ال double bond لتنتين
+
+268
+00:26:36,290 --> 00:26:42,030
+C double bond O إذا
+
+269
+00:26:42,030 --> 00:26:47,130
+انكوّننا الألكين وبعدين كسرنا لتنتين C double bond
+
+270
+00:26:47,130 --> 00:26:48,830
+O هذا ال ozoneolysis
+
+271
+00:27:03,880 --> 00:27:10,080
+بعد هيك السؤال كيف ممكن نحضر المراكبات الآتية سيس
+
+272
+00:27:10,080 --> 00:27:15,900
+وانتو سايكلو بنتين دايول يعني
+
+273
+00:27:15,900 --> 00:27:26,420
+هنا سايكلو بنتين و OH و OH على جهة واحدة الآن أي
+
+274
+00:27:26,420 --> 00:27:32,140
+واحدة فيكوا شاطرة هتقول السيس كيف كنت أجيبه ترجع
+
+275
+00:27:32,140 --> 00:27:41,640
+برجوعالألكين مع الكيامان او فور في ال basic medium
+
+276
+00:27:41,640 --> 00:27:48,440
+او اوزميام او فور الان انا كنت حاكي هنا مابديش
+
+277
+00:27:48,440 --> 00:27:51,820
+ابدأ من ال cyclopentane مابدي ابدأ من ال promo
+
+278
+00:27:51,820 --> 00:27:58,240
+cyclopentane يعني هنا في عند بي ار الان يا تورا
+
+279
+00:27:58,240 --> 00:28:06,550
+هذه ال بي ار فيش جنب هاتشها اكيدبقدر استعمل KOH
+
+280
+00:28:06,550 --> 00:28:20,150
+بتصير ألكيل والألكيل بضيف عليه الميه starting
+
+281
+00:28:20,150 --> 00:28:29,490
+from بنزين برا نيترو كيومين هيلي
+
+282
+00:28:29,490 --> 00:28:35,410
+كيومين وحملة نيترواللي متذكرة هذي بتودي على الميتا
+
+283
+00:28:35,410 --> 00:28:39,790
+هذي Orthobara ال الكلي جروبز كلهم ال R Orthobara
+
+284
+00:28:39,790 --> 00:28:44,610
+الآن الوضع اللي موجود عندك اذا اول اشي انا بدي
+
+285
+00:28:44,610 --> 00:28:54,250
+اعمله اني بدي احضر هذا المركب وبعدين اه الان بيضل
+
+286
+00:28:54,250 --> 00:28:56,350
+ايش ال reagents ايزوبروبليكلورايد
+
+287
+00:28:56,350 --> 00:29:02,740
+ايزوبروبليكلورايد معالألمنيوميكلورايد او whatever
+
+288
+00:29:02,740 --> 00:29:11,080
+وبعدين هنا بدي اعمل نيتريشن بيطلع
+
+289
+00:29:11,080 --> 00:29:19,680
+ال ortho زائد البارا product واضح؟
+
+290
+00:29:21,290 --> 00:29:26,590
+هي الامتحان كامل مع الشريح والتفصيل الممل اعملناه
+
+291
+00:29:26,590 --> 00:29:29,350
+معاكم بطول الساعة اكيد لما يجيكوا انتوا كطلاب
+
+292
+00:29:29,350 --> 00:29:34,430
+هتاخدوا عليه ساعة لكن السؤال في حرف منه خارج عن
+
+293
+00:29:34,430 --> 00:29:37,590
+اللي درسته؟ الحمد لله ربنا
+
+294
+00:29:48,970 --> 00:29:54,650
+خلّينا نكسب الوقت و نحل امتحان من باب المراجعة
+
+295
+00:29:54,650 --> 00:29:58,030
+الشاملة
+
+296
+00:29:58,030 --> 00:30:16,490
+هذا
+
+297
+00:30:16,490 --> 00:30:27,530
+الامتحانالنمط تبعه في سؤال صح و غلط خلينا
+
+298
+00:30:27,530 --> 00:30:31,930
+نشوفه there are four types of hydrogen and
+
+299
+00:30:31,930 --> 00:30:37,170
+isobentane هذا بيستلزم ان انا اعرف ايش ال
+
+300
+00:30:37,170 --> 00:30:43,070
+isobentaneالان هاي ال eyes وبينتين كام نوع عندى من
+
+301
+00:30:43,070 --> 00:30:49,890
+ال hydrogens خلينا نقول هدول ال hydrogens زى بعض و
+
+302
+00:30:49,890 --> 00:30:59,490
+هدى و هدى و هدى نفس ايش؟ كيف؟
+
+303
+00:31:01,530 --> 00:31:06,390
+رجاءً لما بجيبلكوا سؤال ما تفكروش أنه أنواع ال
+
+304
+00:31:06,390 --> 00:31:10,970
+hydrogens أنه primary و secondary و tertiary مش
+
+305
+00:31:10,970 --> 00:31:14,590
+هذا اللي علمتكوا إياه إطلاقا، يعني من ال primary
+
+306
+00:31:14,590 --> 00:31:20,200
+ممكن يكون عندهكذا مجموعة برايمر لكن كل واحدة تمثل
+
+307
+00:31:20,200 --> 00:31:25,060
+نوع في الهيدروجينز واضح؟ عمره ماكان السؤال حددولي
+
+308
+00:31:25,060 --> 00:31:28,540
+كام نوع هيدروجينز انكوا تفكروا بكلمة برايمر و
+
+309
+00:31:28,540 --> 00:31:31,700
+سكندر و تيرتشل ولا هذا اللي علمناكم إياه يعني على
+
+310
+00:31:31,700 --> 00:31:36,520
+سبيل المثال على سبيل المثال حتى نأكد المعلومة الآن
+
+311
+00:31:36,520 --> 00:31:45,540
+لو حطيت هذا المركب هي هذه CH3 وهي هذه CH3 هذه زي
+
+312
+00:31:45,540 --> 00:31:51,700
+هذه؟لو حطيت هنا كلور بدل H من هنا زي ما حطي بدل H
+
+313
+00:31:51,700 --> 00:31:57,120
+من هنا مش كل CH3 بدي أقول عنها زي بعض ولا كل CH2
+
+314
+00:31:57,120 --> 00:32:04,380
+زي بعض لأ واضح؟ ولذلك هذا المركب الآن كام هيدروجين
+
+315
+00:32:04,380 --> 00:32:08,580
+فيه هدول المجمعتين زي بعض هي كمان نوع هي كمان نوع
+
+316
+00:32:08,580 --> 00:32:15,260
+هي كمان نوع أربع أنواع من الهيدروجين واضح؟طيب
+
+317
+00:32:15,260 --> 00:32:20,480
+احبطت شوية اتجاوزجالبة تقولي في هذا كام نوع من
+
+318
+00:32:20,480 --> 00:32:26,860
+الهيدروجين عندك؟ يعني لو قولنا لكوا برائث التلوين
+
+319
+00:32:26,860 --> 00:32:34,280
+كام نوع من الهيدروجين؟ واحد هدولة تنتين زي بعض،
+
+320
+00:32:34,280 --> 00:32:41,860
+هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول زي
+
+321
+00:32:41,860 --> 00:32:43,760
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول
+
+322
+00:32:43,760 --> 00:32:45,480
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعهتنسيش ان
+
+323
+00:32:45,480 --> 00:32:52,860
+هذه double bond ان هذه الدويرة اصلا و هدولة مافيش
+
+324
+00:32:52,860 --> 00:32:58,000
+عليهم غير مجموعة واحدة يعني انا واحد اتنين تلاتة
+
+325
+00:32:58,000 --> 00:33:02,100
+اربعة مافيش انا hydrogen فلما نكون راسمين دائرة
+
+326
+00:33:02,100 --> 00:33:05,840
+ماحدش يفكر ان هوان و هوان فيها hydrogen واضحة
+
+327
+00:33:05,840 --> 00:33:09,240
+الفكرة؟ هي اللي بيوجع الانسان في الغلط ان انا مش
+
+328
+00:33:09,240 --> 00:33:13,220
+راسم ال double bonds ان انا عامل هيك بس هذه لها
+
+329
+00:33:13,220 --> 00:33:17,180
+معنى في الكيميافما تفكروش ان هنا وهنا يوجد
+
+330
+00:33:17,180 --> 00:33:23,500
+هيدروجينز في الشكل يا
+
+331
+00:33:23,500 --> 00:33:28,780
+ريتما ماحطتش الامتحان كان جيبتي الكويزمة اه there
+
+332
+00:33:28,780 --> 00:33:33,460
+are three possible stereoisomers of 1,2
+
+333
+00:33:33,460 --> 00:33:39,460
+-dichlorobrobane الان لاحظوا بالكتورث مش شكل
+
+334
+00:33:39,460 --> 00:33:46,160
+البروبين كام كاربونتلاتة على نمرة واحد و اتنين في
+
+335
+00:33:46,160 --> 00:33:50,120
+عندى chlorine يعني هذه حملة chlorine و هذه حملة
+
+336
+00:33:50,120 --> 00:33:54,780
+chlorine لو كملنا ال hydrogens الان هنا CH2 هنا
+
+337
+00:33:54,780 --> 00:34:04,140
+CH3 الان من هذا المركب كم isomer عندى اه
+
+338
+00:34:04,140 --> 00:34:09,580
+بديش انسى ان في عندى chiral center هنا مافيش هنا
+
+339
+00:34:09,580 --> 00:34:13,940
+في chiral centerطالما عندي chiral center إذا
+
+340
+00:34:13,940 --> 00:34:23,740
+المركب و صورته إذا كام stereo isomer عند هنا الصح؟
+
+341
+00:34:23,740 --> 00:34:30,220
+نان .. نان هذا واحد اللي موجود عندكم حقيقة هو ال S
+
+342
+00:34:30,220 --> 00:34:35,900
+بتقدر ترسم صورته في المرايا ال R اللي موجود هو ال
+
+343
+00:34:35,900 --> 00:34:40,200
+S بتقدر ترسم ال R إذا هذه الجملة غلط
+
+344
+00:34:46,280 --> 00:34:53,080
+Addition of HBr Peroxide to styrene produces two
+
+345
+00:34:53,080 --> 00:34:59,040
+stereoisomers طبعا اللي مش عارف ال styrene زنبها ع
+
+346
+00:34:59,040 --> 00:35:08,500
+جنبها CH double bond CH2 لاحظوا هذا سؤال جميل لو
+
+347
+00:35:08,500 --> 00:35:13,060
+انا كنت باضيف HBr في وجود H plus هضيفه حسب قاعدة
+
+348
+00:35:13,060 --> 00:35:18,780
+Markovnikov هحط هنا ال Hوهنا ال PR وجدت في هذه
+
+349
+00:35:18,780 --> 00:35:24,080
+الحالة هعمل chiral center هنا هيطلع عندى ناتجين لو
+
+350
+00:35:24,080 --> 00:35:28,460
+أنا بضيف ال HPR في وجود H Plus هنا ال H هنا ال PR
+
+351
+00:35:28,460 --> 00:35:32,920
+إذا انا عملت chiral center لأن لما بضيف في وجود ال
+
+352
+00:35:32,920 --> 00:35:37,780
+peroxide Anti Markovnikov's addition يعني بدي ألغى
+
+353
+00:35:37,780 --> 00:35:45,050
+هذا ال double bond و أحط هنا H و هنا PRبر فيها انا
+
+354
+00:35:45,050 --> 00:35:50,050
+كايرال سنتر فيها انا كايرال سنتر اذا الكم ايزو مار
+
+355
+00:35:50,050 --> 00:35:57,430
+طلع عني واحد مش اتنين لو كنا بنضيف hbr في وجود h
+
+356
+00:35:57,430 --> 00:35:58,550
+plus بطلع اتنين
+
+357
+00:36:08,270 --> 00:36:11,910
+هذا السؤال MAI reacts with ethyl chloride
+
+358
+00:36:11,910 --> 00:36:16,410
+producing ethyl iodide لاحظوا هنا إبدال أن اليود
+
+359
+00:36:16,410 --> 00:36:23,670
+بيحل محل كلور هذه المعلومة أخدناها ولا لأ اليود
+
+360
+00:36:23,670 --> 00:36:32,630
+بيحل محل كلور و العكس مش صحيح Cyclohexanol بتكون
+
+361
+00:36:32,630 --> 00:36:37,730
+تتذكروا بمخكوا ع طول ال Cyclohexanolركزنا عليه في
+
+362
+00:36:37,730 --> 00:36:43,130
+الرسم ولا لأ؟ اللي متصل ب OH لو عملتله أكسدة شو
+
+363
+00:36:43,130 --> 00:36:52,690
+هيعمل؟ هيحذف ال H و ال H هاي الأكسدة تبعته، هاي
+
+364
+00:36:52,690 --> 00:36:57,360
+أكسدته، إيش أعطاني؟عطاني كيتون أساسا
+
+365
+00:36:57,360 --> 00:37:00,680
+الـcyclohexanol is secondary alcohol secondary
+
+366
+00:37:00,680 --> 00:37:05,420
+alcohols are oxidized to ketones وهي بالرسمة بيعطي
+
+367
+00:37:05,420 --> 00:37:13,660
+كيتون أنا كاتبلكم غلط مش الديهيد كيتون dehydration
+
+368
+00:37:13,660 --> 00:37:18,180
+of secondary butyl alcohol مرة تانية رجعنا تكونوا
+
+369
+00:37:18,180 --> 00:37:23,060
+حافظين أسماء إيش المجموعات ال secondary butyl اللي
+
+370
+00:37:23,060 --> 00:37:30,120
+حاملة هناعلى هذا الموقع وهذا لما يحمل OH سكندر
+
+371
+00:37:30,120 --> 00:37:35,020
+بيوت الالكهول طبعا ال dehydration يا ال OH من هنا
+
+372
+00:37:35,020 --> 00:37:42,620
+او من هنا اخدنا انه حسب قاعدة زي سف الحذف و more
+
+373
+00:37:42,620 --> 00:37:47,320
+substituted product will form اذا ال one butane
+
+374
+00:37:47,320 --> 00:37:51,260
+ولا ال two butane انا كاتبينلكم بشكل أساسي one
+
+375
+00:37:51,260 --> 00:37:52,820
+butane اذا خطأ
+
+376
+00:38:10,810 --> 00:38:15,070
+dichlorination of cyclobutane gives a total of
+
+377
+00:38:15,070 --> 00:38:19,310
+لحظوا ال cyclobutane بهذا الشكل بدي أضع عليه
+
+378
+00:38:19,310 --> 00:38:25,830
+مجموعتين كلور كيف ممكن أضعهم على واحد و واحد أو
+
+379
+00:38:25,830 --> 00:38:29,150
+على واحد و اتنين على واحد و اتنين بيجي ال ces و ال
+
+380
+00:38:29,150 --> 00:38:29,810
+trans
+
+381
+00:38:39,260 --> 00:38:45,180
+cyclobutane ..cyclobutane ..انا متأسف okay ..الان
+
+382
+00:38:45,180 --> 00:38:48,500
+ال ..cyclobutane ..حطوا مجموعتين كلور على واحد
+
+383
+00:38:48,500 --> 00:38:53,980
+واحد ..هذا مركب ..بعدين ع واحد و اتنين .. six و
+
+384
+00:38:53,980 --> 00:38:57,860
+trance .. بعدين ع واحد و تلاتة .. six و trance ..
+
+385
+00:38:57,860 --> 00:39:02,300
+اذا قداش المجموعة؟ خمسة ..هي نفس فكرة ال
+
+386
+00:39:02,300 --> 00:39:07,200
+..cyclobrote .. بس على أوصةThe common name of two
+
+387
+00:39:07,200 --> 00:39:19,360
+propene one all يعني هاي CH2OH CH double bond CH2
+
+388
+00:39:19,360 --> 00:39:26,160
+لحظوا هذا two propene واحد اتنين تلاتة one all هنا
+
+389
+00:39:26,160 --> 00:39:30,340
+فسرناه الآن الناس اللي متذكرة شكل المجموعة شو هي
+
+390
+00:39:30,340 --> 00:39:32,400
+الالكول
+
+391
+00:39:34,300 --> 00:39:40,940
+قلل ألكول قلل ألكول إذا كان شوكارو مستعمل لإيصال
+
+392
+00:39:40,940 --> 00:39:45,440
+حركة محركة واحدة إلكترون واحدة إلكترون فالمثال لـ
+
+393
+00:39:45,440 --> 00:39:51,880
+Cyclic Alkenes هو CNH2N-2 لاحظوا الـ Cyclic بدأ
+
+394
+00:39:51,880 --> 00:39:55,660
+أقسم جبالها اتنين من الفورمولة الأصلية والـ E بدأ
+
+395
+00:39:55,660 --> 00:40:00,400
+أقسم اتنين إذا صارت زي formula of الكائنات يعني
+
+396
+00:40:00,400 --> 00:40:08,300
+CNHتو ان ماينوس تو وبتاعة اللي عملناها مركبة زيها
+
+397
+00:40:08,300 --> 00:40:14,260
+اوزونوليسيس او سيس اوري ترانس تو بيوتين خليني
+
+398
+00:40:14,260 --> 00:40:19,860
+اخد ال سيس تو بيوتين ارسمه هان هاي ال سيس تو
+
+399
+00:40:19,860 --> 00:40:23,880
+بيوتين بدي اكسره من هان C double bond O وهذه H
+
+400
+00:40:23,880 --> 00:40:30,660
+بالتأكيدهذا C double bond OH CH3 Acetaldehyde هذا
+
+401
+00:40:30,660 --> 00:40:38,400
+C double bond OH CH3 Acetaldehyde و لل Trans هاي
+
+402
+00:40:38,400 --> 00:40:47,640
+CH3H و هنا CH3H الان اكسروا هذا من هنا و اكسروا
+
+403
+00:40:47,640 --> 00:40:53,400
+هذا من هنا و حطوا ايش Oxygen Oxygen Oxygen Oxygen
+
+404
+00:40:53,980 --> 00:40:59,480
+كل النواتج ايش؟ أسيتلديهيد بيعطي نفس الناتج
+
+405
+00:40:59,480 --> 00:41:07,000
+produces only أسيتلديهيد أو إيثانال أسيتلديهيد
+
+406
+00:41:07,000 --> 00:41:14,960
+CH3SH is more acidic than CH3OH due to size
+
+407
+00:41:17,520 --> 00:41:22,560
+سلفر مع اكسجين ايش العامل المحدد في ال acidity ال
+
+408
+00:41:22,560 --> 00:41:27,820
+size ال due to size
+
+409
+00:41:27,820 --> 00:41:34,740
+الان
+
+410
+00:41:34,740 --> 00:41:40,660
+ارسموا المراكبات التالية بدي بيوتينيعني carbon
+
+411
+00:41:40,660 --> 00:41:46,820
+تنتين تلاتة أربعة على لمرة اتنين ايش موجود عندكم؟
+
+412
+00:41:46,820 --> 00:41:56,900
+فينوكسي يعني O phenyl OH OHANA CH3 CH2 CH3 الآن
+
+413
+00:41:56,900 --> 00:42:01,120
+انا برسم المركب بعدين بشوفه اذا طلع R كان بيها
+
+414
+00:42:01,120 --> 00:42:06,970
+ماطلعش Rبعكس اي مجموع تاني الا لو جيت تطلعت عليه
+
+415
+00:42:06,970 --> 00:42:11,890
+كيف مبين هذي واحد هذي اتنين هذي تلاتة مبين اس و
+
+416
+00:42:11,890 --> 00:42:18,590
+هذي على الجانب اذا هذا فعلا الار ايزو مار عندي
+
+417
+00:42:18,590 --> 00:42:24,770
+سايكلو بنتين هاي السايكلو بنتين خليني ارسمه بهذا
+
+418
+00:42:24,770 --> 00:42:30,530
+الشكلcyclopentane واحد اتنين تلاتة اربعة خمسة على
+
+419
+00:42:30,530 --> 00:42:38,950
+نمرة تلاتة واربعة شو بدي احط كلور وكلور بالزويك
+
+420
+00:42:38,950 --> 00:42:47,010
+أسد C double bond O OH وهنا ال formal C double
+
+421
+00:42:47,010 --> 00:42:57,620
+bond OH هذا ميتاميتا أو بارا هذا موضوع بسيط هذا
+
+422
+00:42:57,620 --> 00:43:01,020
+المركب
+
+423
+00:43:01,020 --> 00:43:10,120
+Cyclopentane شو هذه المجموعة؟ Isobutyl Isobutyl
+
+424
+00:43:10,120 --> 00:43:15,680
+Cyclopentane هذا
+
+425
+00:43:15,680 --> 00:43:22,160
+كحول ألكين من وين الترقيم؟ من عند الكحول يعني هذا
+
+426
+00:43:25,670 --> 00:43:36,290
+بيوتين بيوت two in one all و إيش بيحمل بعد هى two
+
+427
+00:43:36,290 --> 00:43:43,710
+bromo فيه زده E لحظوا هنا ال brom و هنا الميثل ال
+
+428
+00:43:43,710 --> 00:43:47,270
+brom أعلى من الكربون و الميثل أعلى من ال H إذا هذا
+
+429
+00:43:47,270 --> 00:43:51,750
+E هذا أسيتوفينون
+
+430
+00:44:14,250 --> 00:44:18,730
+مش كتير معنا وقت ان شاء الله بخمس دقائق نمشي أسرع
+
+431
+00:44:18,730 --> 00:44:21,270
+بدنا خمس دقائق نمشي أسرع شوية
+
+432
+00:44:24,120 --> 00:44:30,000
+هحاول امشي بشكل سريع الان هنا في ال HBr Peroxide
+
+433
+00:44:30,000 --> 00:44:35,140
+الفكرة الأساسية اللى بتكون تعمله شو هي انت
+
+434
+00:44:35,140 --> 00:44:43,000
+Markovnikov واضح فلو انتوا جيتوا واشتغلتوا H CH3
+
+435
+00:44:43,000 --> 00:44:51,740
+CH2 هنا H هنا H وين هتحطوا ال Br وهنا
+
+436
+00:44:51,740 --> 00:44:56,880
+ال Hهي الـ Antimark of Nikon واضح؟ الان هذا لو
+
+437
+00:44:56,880 --> 00:45:00,320
+فعلته مع ال Oethel minus Can you clear your file؟
+
+438
+00:45:00,320 --> 00:45:08,700
+شو بتعمل؟ بتحيل محل لبروم يعني بتحط كل الجزيء و
+
+439
+00:45:08,700 --> 00:45:18,540
+تكتبوا هنا Oethel و لو فعلته مع ال SH minus بدنا
+
+440
+00:45:18,540 --> 00:45:26,810
+نحط كل الجزيء مرة تانيةوبنحط هنا sh ابدال يعني هذا
+
+441
+00:45:26,810 --> 00:45:30,870
+البروم بتبدل هذا عنوان chapter 6 انه البروم بتبدل
+
+442
+00:45:30,870 --> 00:45:36,310
+بال او اثل او بال sh هنا بالكئمن او فور مع ال o h
+
+443
+00:45:36,310 --> 00:45:44,090
+minus شو بدها تحط مجمعتين o h على جهة واحدة بال
+
+444
+00:45:44,090 --> 00:45:50,730
+ozonolysis بدوا يعمل تلتين c double point o بتكمل
+
+445
+00:45:50,730 --> 00:45:58,340
+الجزيةبالميه هذه بتضيف حسب قاعدة Markovnikov
+
+446
+00:45:58,340 --> 00:46:03,220
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+447
+00:46:03,220 --> 00:46:07,800
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+448
+00:46:07,800 --> 00:46:07,980
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+449
+00:46:07,980 --> 00:46:09,020
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+450
+00:46:09,020 --> 00:46:09,960
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+451
+00:46:09,960 --> 00:46:20,320
+اتش اتش اتش اتش اتش اتش اتش اتش
+
+452
+00:46:20,320 --> 00:46:22,320
+ات
+
+453
+00:46:33,790 --> 00:46:41,490
+أخر شغلة الأفكار الأساسية هنا إضافة ميه وبعدين
+
+454
+00:46:41,490 --> 00:46:47,110
+توتوميرزم متذاكرينها ال
+
+455
+00:46:47,110 --> 00:46:54,030
+ISOبنتين هي ال ISOبنتين اعملولها إكلوريناشن توي
+
+456
+00:46:54,030 --> 00:47:01,240
+حكينا كام موقع فيها؟واحد اتنين تلاتة اربعة لما
+
+457
+00:47:01,240 --> 00:47:05,440
+احطولكوا all possible monochlorination products
+
+458
+00:47:05,440 --> 00:47:10,700
+انتبهوا معي لما احط كلور هان و هان هذا ناتج و اذا
+
+459
+00:47:10,700 --> 00:47:13,740
+حطيت هان هذا ناتج هذا فيش فيه chiral center هذا
+
+460
+00:47:13,740 --> 00:47:17,500
+فيش فيه chiral center لو حطيت هان CH2Cl فيش فيه
+
+461
+00:47:17,500 --> 00:47:23,210
+chiral center لو حطيت هانأتش و CL في كايرالسنتر
+
+462
+00:47:23,210 --> 00:47:27,430
+هدا بده يطلع منه كام واحد اتنين اذا المجموع كده؟
+
+463
+00:47:27,430 --> 00:47:32,890
+خمسة product لما ادخل ال stereo isomers هذه النقطة
+
+464
+00:47:32,890 --> 00:47:38,510
+تحديدا بحط فيها ال H و ال CL يعني الناتجين اللي
+
+465
+00:47:38,510 --> 00:47:44,450
+بدهم يكونوا هنا لو رسمت الناتج و صورته في المرايا
+
+466
+00:47:44,450 --> 00:47:52,680
+بدكوا تكونوا حاطين هنا مثلاH و CH3 و CL وهنا تحطوا
+
+467
+00:47:52,680 --> 00:48:02,100
+CL و H و CH3 الناتج و صورته في المرأة واضح
+
+468
+00:48:02,100 --> 00:48:06,300
+الناتج و صورته في المرأة هذوله اتنين و بعدين
+
+469
+00:48:06,300 --> 00:48:09,920
+بتحطوا هن واحد و هن واحد و هن واحد المجموع كده؟
+
+470
+00:48:09,920 --> 00:48:17,300
+خمسة خمسة بقى لعنا اتنين صغار كتير
+
+471
+00:48:25,790 --> 00:48:29,490
+isopropylacetophenon الفكرة فقط انكوا تعرفوا مين
+
+472
+00:48:29,490 --> 00:48:34,550
+بده احطها في الأول انهي المجموعة اللي بتلحط نمرا
+
+473
+00:48:34,550 --> 00:48:42,090
+واحد ال isopropyl ال isopropyl orthopara ال
+
+474
+00:48:42,090 --> 00:48:46,290
+isopropyl orthopara directing و بعدين ال
+
+475
+00:48:46,290 --> 00:48:47,270
+acetophenon
+
+476
+00:48:49,330 --> 00:48:54,330
+Cl ألمنيوم كلورايد و هنا ايزو بروبل كلورايد
+
+477
+00:48:54,330 --> 00:49:02,530
+ألمنيوم كلورايد أخر سؤال سيث ثريهكسيني من ون
+
+478
+00:49:02,530 --> 00:49:07,430
+بيوتايل لاحظوا هذا ال ون بيوتايل بهذا الشكل CH3
+
+479
+00:49:07,430 --> 00:49:15,670
+CH2 C triple bond CH من أربعة بده أحضر ستة
+
+480
+00:49:15,670 --> 00:49:17,890
+ملاحظين؟
+
+481
+00:49:18,690 --> 00:49:24,670
+من الأربعة شو بده احضر؟ ستة كيف بده اعمل هذا
+
+482
+00:49:24,670 --> 00:49:31,470
+الكلام؟ اول اشي بده ازيد ذاتين carbon فانا لو فعلت
+
+483
+00:49:31,470 --> 00:49:38,380
+مع ال NANH2 نمرة واحد خلت هذه minusو بعدين نمرة
+
+484
+00:49:38,380 --> 00:49:44,540
+اتنين فعلتها مع إثيل بروميد CH3 CH2Br ال minus
+
+485
+00:49:44,540 --> 00:49:48,760
+اللي بيحجم على ال PR و أجتها بيصير عندي هذا ال
+
+486
+00:49:48,760 --> 00:49:56,140
+كائن CH3 CH2 C triple bond C وهي ال إثيل اللي أنا
+
+487
+00:49:56,140 --> 00:50:04,950
+حطيتها CH2 CH3 الان من هذه بدي أخليهاالكين
+
+488
+00:50:04,950 --> 00:50:09,090
+والالكين يكون إيش؟ SES كيف بحول ال triple bond
+
+489
+00:50:09,090 --> 00:50:18,610
+لالكين SES؟ H2 Lendlers Catalyst Lendlers Catalyst
+
+490
+00:50:18,610 --> 00:50:24,350
+إذا هذا السؤال فيه فكرتين أساسيات الفكرة الأولى أن
+
+491
+00:50:24,350 --> 00:50:28,010
+ال terminal alkyl بيصير نيوكليوفايل ممكن يعمل
+
+492
+00:50:28,010 --> 00:50:34,070
+إبدال علىالكالهلايد كبرت السلسلة و بعدين ل triple
+
+493
+00:50:34,070 --> 00:50:38,010
+bond ان اخليها cis او trans اخدته قولت انا ل
+
+494
+00:50:38,010 --> 00:50:43,470
+triple bond يا بخليها الكن يا cis الكن يا trans
+
+495
+00:50:43,470 --> 00:50:48,590
+الكن كل واحدة في إلها شروط معينة ابقى اك تقريبا
+
+496
+00:50:48,590 --> 00:50:53,810
+بنكون غطينا يعني باسئلة مختلفة معظم الأشياء اللي
+
+497
+00:50:53,810 --> 00:50:57,490
+درسناها و بنتمنالكوا ان شاء الله النجاح و التوفيق
+
+498
+00:50:57,490 --> 00:50:59,050
+في الامتحان اللي بدكنوا تقدموه
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..67527dfe5d9af8d0812dc642f87d8cc31dcf062e
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3340, "start": 20.33, "end": 33.41, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله درسنا مش في موضوع معين لأ هو مراجعة شاملة من خلال حل الامتحانات السابقة استعدادا للامتحان", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 11778, 2288, 3794, 8315, 37893, 8978, 3714, 2407, 11242, 45367, 20449, 9957, 5296, 10721, 31439, 3714, 2288, 26108, 27884, 13412, 10943, 37977, 9154, 16490, 1211, 6027, 11331, 1211, 2423, 10943, 2655, 5016, 7649, 9307, 21136, 16758, 28671, 44713, 22488, 18513, 995, 24976, 10943, 2655, 5016, 7649], "avg_logprob": -0.08108618723288659, "compression_ratio": 1.7050359712230216, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 20.33, "end": 20.65, "word": "بسم", "probability": 0.871337890625}, {"start": 20.65, "end": 20.85, "word": " الله", "probability": 0.96923828125}, {"start": 20.85, "end": 21.31, "word": " الرحمن", "probability": 0.9736328125}, {"start": 21.31, "end": 21.87, "word": " الرحيم", "probability": 0.9949544270833334}, {"start": 21.87, "end": 23.33, "word": " اليوم", "probability": 0.751953125}, {"start": 23.33, "end": 23.47, "word": " ان", "probability": 0.68212890625}, {"start": 23.47, "end": 23.71, "word": " شاء", "probability": 0.982666015625}, {"start": 23.71, "end": 23.89, "word": " الله", "probability": 0.9638671875}, {"start": 23.89, "end": 25.29, "word": " درسنا", "probability": 0.9769287109375}, {"start": 25.29, "end": 25.41, "word": " مش", "probability": 0.98876953125}, {"start": 25.41, "end": 25.59, "word": " في", "probability": 0.8642578125}, {"start": 25.59, "end": 26.03, "word": " موضوع", "probability": 0.9952392578125}, {"start": 26.03, "end": 26.53, "word": " معين", "probability": 0.991943359375}, {"start": 26.53, "end": 26.75, "word": " لأ", "probability": 0.73291015625}, {"start": 26.75, "end": 27.03, "word": " هو", "probability": 0.92138671875}, {"start": 27.03, "end": 28.33, "word": " مراجعة", 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"probability": 0.318115234375}, {"start": 49.24, "end": 49.44, "word": " في", "probability": 0.90380859375}, {"start": 49.44, "end": 49.96, "word": " عندنا", "probability": 0.99365234375}, {"start": 49.96, "end": 50.6, "word": " أسئلة", "probability": 0.9677734375}, {"start": 50.6, "end": 51.48, "word": " متنوعة", "probability": 0.9656982421875}, {"start": 51.48, "end": 52.62, "word": " بشكل", "probability": 0.970703125}, {"start": 52.62, "end": 53.1, "word": " عام", "probability": 0.998779296875}, {"start": 53.1, "end": 54.28, "word": " دائما", "probability": 0.94775390625}, {"start": 54.28, "end": 54.98, "word": " ننصح", "probability": 0.948974609375}, {"start": 54.98, "end": 55.6, "word": " الطلاب", "probability": 0.97314453125}, {"start": 55.6, "end": 55.84, "word": " انه", "probability": 0.603515625}, {"start": 55.84, "end": 56.52, "word": " يهتموا", "probability": 0.9591064453125}], "temperature": 1.0}, {"id": 3, "seek": 8445, "start": 57.05, "end": 84.45, "text": "بالأفكار الأساسية العامة يكونوا فاهمينها بنسبة أكبر هذا بمنعش أنه في أشياء متخصصة لكن دائما الطالب أول شيء يجب أن يكون عنده يعني قناع أن هو فاهم الاشي الأفكار العامة ولذلك ربما تلاحظوا أنه يعني لو أنا بدأ أصنف الأسئلة مش في هذا الامتحان في معظم الامتحانات هنكتشف أنه هي عنوين", "tokens": [3555, 6027, 10721, 5172, 4117, 9640, 16247, 3794, 32277, 10632, 18863, 10943, 3660, 7251, 30544, 14407, 6156, 995, 16095, 9957, 11296, 44945, 35457, 3660, 5551, 4117, 26890, 23758, 4724, 27842, 3615, 8592, 14739, 3224, 8978, 5551, 8592, 1829, 16606, 44650, 9778, 9381, 9381, 3660, 44381, 11778, 16373, 15042, 41950, 6027, 3555, 5551, 12610, 44049, 38207, 7251, 7435, 3555, 14739, 7251, 30544, 43242, 3224, 37495, 22653, 12174, 8315, 3615, 14739, 31439, 6156, 995, 16095, 2423, 33599, 1829, 16247, 5172, 4117, 9640, 18863, 10943, 3660, 35525, 8848, 23275, 12602, 3555, 15042, 6055, 15040, 5016, 19913, 14407, 14739, 3224, 37495, 22653, 45164, 41850, 47525, 10721, 5551, 9381, 1863, 5172, 16247, 3794, 19986, 37977, 37893, 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{"start": 74.77, "end": 75.35, "word": " أنه", "probability": 0.863037109375}, {"start": 75.35, "end": 75.85, "word": " يعني", "probability": 0.980712890625}, {"start": 75.85, "end": 76.55, "word": " لو", "probability": 0.97265625}, {"start": 76.55, "end": 76.73, "word": " أنا", "probability": 0.720703125}, {"start": 76.73, "end": 76.97, "word": " بدأ", "probability": 0.7269287109375}, {"start": 76.97, "end": 77.65, "word": " أصنف", "probability": 0.954345703125}, {"start": 77.65, "end": 78.49, "word": " الأسئلة", "probability": 0.995849609375}, {"start": 78.49, "end": 78.71, "word": " مش", "probability": 0.9150390625}, {"start": 78.71, "end": 78.89, "word": " في", "probability": 0.94287109375}, {"start": 78.89, "end": 79.11, "word": " هذا", "probability": 0.95947265625}, {"start": 79.11, "end": 79.75, "word": " الامتحان", "probability": 0.962109375}, {"start": 79.75, "end": 80.17, "word": " في", "probability": 0.82373046875}, {"start": 80.17, "end": 80.63, "word": " معظم", "probability": 0.9871419270833334}, {"start": 80.63, "end": 81.65, "word": " الامتحانات", "probability": 0.9720865885416666}, {"start": 81.65, "end": 82.85, "word": " هنكتشف", "probability": 0.947265625}, {"start": 82.85, "end": 83.39, "word": " أنه", "probability": 0.833740234375}, {"start": 83.39, "end": 83.75, "word": " هي", "probability": 0.89453125}, {"start": 83.75, "end": 84.45, "word": " عنوين", "probability": 0.9423828125}], "temperature": 1.0}, {"id": 4, "seek": 11295, "start": 85.47, "end": 112.95, "text": "يعني هي عنوين لأشياء احنا درسناها خلينا نشوف هذا الكلام من خلال التطبيق الآن في هذا الامتحان اللي أمامنا في عندنا مجموعة من الجمال هذه المجموعة من الجمال بدنا نكمل الفراغ فيها complete the following السؤال أول مثلا بيسألنا الدياستيريو مارزهاف و بيحكي عن ال physical properties", "tokens": [40228, 22653, 39896, 18871, 2407, 9957, 5296, 10721, 8592, 1829, 16606, 1975, 5016, 8315, 11778, 2288, 3794, 8315, 11296, 16490, 1211, 9957, 995, 8717, 8592, 38688, 23758, 2423, 28820, 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"probability": 0.931640625}, {"start": 87.19, "end": 87.55, "word": " احنا", "probability": 0.8640950520833334}, {"start": 87.55, "end": 88.31, "word": " درسناها", "probability": 0.96259765625}, {"start": 88.31, "end": 89.49, "word": " خلينا", "probability": 0.8192138671875}, {"start": 89.49, "end": 90.03, "word": " نشوف", "probability": 0.99169921875}, {"start": 90.03, "end": 90.25, "word": " هذا", "probability": 0.97265625}, {"start": 90.25, "end": 90.73, "word": " الكلام", "probability": 0.9615885416666666}, {"start": 90.73, "end": 90.87, "word": " من", "probability": 0.9970703125}, {"start": 90.87, "end": 91.39, "word": " خلال", "probability": 0.9947916666666666}, {"start": 91.39, "end": 92.35, "word": " التطبيق", "probability": 0.980224609375}, {"start": 92.35, "end": 93.45, "word": " الآن", "probability": 0.6680908203125}, {"start": 93.45, "end": 94.47, "word": " في", "probability": 0.921875}, {"start": 94.47, "end": 94.79, "word": " هذا", "probability": 0.95556640625}, {"start": 94.79, "end": 95.51, "word": " الامتحان", "probability": 0.97373046875}, {"start": 95.51, "end": 95.71, "word": " اللي", "probability": 0.93798828125}, {"start": 95.71, "end": 96.43, "word": " أمامنا", "probability": 0.9483642578125}, {"start": 96.43, "end": 97.25, "word": " في", "probability": 0.57861328125}, {"start": 97.25, "end": 97.67, "word": " عندنا", "probability": 0.959716796875}, {"start": 97.67, "end": 98.33, "word": " مجموعة", "probability": 0.9568359375}, {"start": 98.33, "end": 98.69, "word": " من", "probability": 0.9892578125}, {"start": 98.69, "end": 99.83, "word": " الجمال", "probability": 0.7607421875}, {"start": 99.83, "end": 100.61, "word": " هذه", "probability": 0.65234375}, {"start": 100.61, "end": 101.19, "word": " المجموعة", "probability": 0.89345703125}, {"start": 101.19, "end": 101.35, "word": " من", "probability": 0.984375}, {"start": 101.35, "end": 101.87, "word": " الجمال", "probability": 0.9088541666666666}, {"start": 101.87, "end": 102.33, "word": " بدنا", "probability": 0.9365234375}, {"start": 102.33, "end": 103.05, "word": " نكمل", "probability": 0.9957682291666666}, {"start": 103.05, "end": 103.71, "word": " الفراغ", "probability": 0.985107421875}, {"start": 103.71, "end": 104.27, "word": " فيها", "probability": 0.9931640625}, {"start": 104.27, "end": 105.67, "word": " complete", "probability": 0.546875}, {"start": 105.67, "end": 106.45, "word": " the", "probability": 0.9130859375}, {"start": 106.45, "end": 107.15, "word": " following", "probability": 0.900390625}, {"start": 107.15, "end": 108.65, "word": " السؤال", "probability": 0.9835611979166666}, {"start": 108.65, "end": 108.91, "word": " أول", "probability": 0.806396484375}, {"start": 108.91, "end": 109.21, "word": " مثلا", "probability": 0.9794921875}, {"start": 109.21, "end": 109.67, "word": " بيسألنا", "probability": 0.956298828125}, {"start": 109.67, "end": 110.45, "word": " الدياستيريو", "probability": 0.7172502790178571}, {"start": 110.45, "end": 111.23, "word": " مارزهاف", "probability": 0.6673828125}, {"start": 111.23, "end": 111.41, "word": " و", "probability": 0.56201171875}, {"start": 111.41, "end": 111.73, "word": " بيحكي", "probability": 0.857958984375}, {"start": 111.73, "end": 111.87, "word": " عن", "probability": 0.98828125}, {"start": 111.87, "end": 111.97, "word": " ال", "probability": 0.935546875}, {"start": 111.97, "end": 112.29, "word": " physical", "probability": 0.8466796875}, {"start": 112.29, "end": 112.95, "word": " properties", "probability": 0.143798828125}], "temperature": 1.0}, {"id": 5, "seek": 14309, "start": 114.07, "end": 143.09, "text": "الان كان واضح تماما ان ال بيستيريو مارز هيف different physical properties واضح الان السؤال التاني addition of HBr H plus to isobutene produces لاحظوا هنا السؤال هذا في فكرتين ان الطالب لازم في الأول يعرف ايش هو ال isobutene", "tokens": [6027, 7649, 25961, 4032, 46958, 5016, 46811, 10943, 995, 16472, 2423, 4724, 1829, 14851, 13546, 1829, 2407, 3714, 9640, 11622, 8032, 33911, 819, 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"word": " بيستيريو", "probability": 0.6562906901041666}, {"start": 117.05, "end": 117.33, "word": " مارز", "probability": 0.806640625}, {"start": 117.33, "end": 117.91, "word": " هيف", "probability": 0.16851806640625}, {"start": 117.91, "end": 118.97, "word": " different", "probability": 0.318359375}, {"start": 118.97, "end": 122.39, "word": " physical", "probability": 0.38134765625}, {"start": 122.39, "end": 123.07, "word": " properties", "probability": 0.81689453125}, {"start": 123.07, "end": 124.43, "word": " واضح", "probability": 0.7909342447916666}, {"start": 124.43, "end": 127.39, "word": " الان", "probability": 0.6256103515625}, {"start": 127.39, "end": 128.23, "word": " السؤال", "probability": 0.9890950520833334}, {"start": 128.23, "end": 128.77, "word": " التاني", "probability": 0.9269205729166666}, {"start": 128.77, "end": 129.21, "word": " addition", "probability": 0.60009765625}, {"start": 129.21, "end": 129.55, "word": " of", "probability": 0.9794921875}, {"start": 129.55, 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"word": " ان", "probability": 0.6201171875}, {"start": 138.83, "end": 139.31, "word": " الطالب", "probability": 0.9853515625}, {"start": 139.31, "end": 139.67, "word": " لازم", "probability": 0.94873046875}, {"start": 139.67, "end": 139.79, "word": " في", "probability": 0.89794921875}, {"start": 139.79, "end": 140.09, "word": " الأول", "probability": 0.8466796875}, {"start": 140.09, "end": 140.85, "word": " يعرف", "probability": 0.770263671875}, {"start": 140.85, "end": 141.37, "word": " ايش", "probability": 0.7532552083333334}, {"start": 141.37, "end": 141.73, "word": " هو", "probability": 0.93310546875}, {"start": 141.73, "end": 142.07, "word": " ال", "probability": 0.79150390625}, {"start": 142.07, "end": 143.09, "word": " isobutene", "probability": 0.9185791015625}], "temperature": 1.0}, {"id": 6, "seek": 16407, "start": 144.57, "end": 164.07, "text": "هذا ال isobutene واضح بعد هيك إضافة ال HBR H plus معناه ذلك هذه إضافة حسب Markov-Nikov addition يعني هذه بدها تروح يجي عند هنا H و 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"seek": 90354, "start": 884.4, "end": 903.54, "text": "واضح؟ وين بده احط هذه ال chlorine طبعا هنبدأ نرسم اكثر من شكل مش عارف تلاتة اربعة بنجرب احنا الان اكيد ال chlorine بإمكانها تيجي هنا على المثل", "tokens": [2407, 46958, 5016, 22807, 4032, 9957, 47525, 3224, 1975, 5016, 9566, 29538, 2423, 39888, 23032, 3555, 3615, 995, 8032, 1863, 44510, 10721, 8717, 2288, 38251, 1975, 4117, 49115, 9154, 13412, 28820, 37893, 6225, 9640, 5172, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 44945, 7435, 25513, 1975, 5016, 8315, 2423, 7649, 1975, 4117, 25708, 2423, 39888, 4724, 28814, 2304, 41361, 11296, 6055, 1829, 7435, 1829, 34105, 15844, 9673, 12984, 1211], "avg_logprob": -0.17812499425240924, "compression_ratio": 1.5157232704402517, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 884.4, "end": 885.26, "word": "واضح؟", "probability": 0.8828125}, {"start": 885.26, "end": 885.5, "word": " وين", "probability": 0.907470703125}, {"start": 885.5, "end": 885.72, "word": " بده", "probability": 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الحلقة بده اعمل ring opening ضيفت ميه", "tokens": [6027, 7649, 20193, 5016, 19913, 14407, 20449, 1829, 23758, 9673, 31747, 3555, 8978, 3224, 3834, 6086, 44945, 39648, 8978, 8717, 29973, 36764, 24401, 47525, 8315, 8717, 11242, 33911, 47356, 37320, 8258, 1975, 1829, 8592, 20449, 8315, 3224, 37320, 8258, 16472, 3224, 47525, 3224, 7251, 1211, 17082, 1829, 29538, 4032, 7251, 25957, 20292, 11331, 1211, 28671, 44381, 1975, 8315, 9122, 2304, 7649, 39182, 19446, 6225, 42213, 2655, 29538, 21542, 1211, 28671, 47525, 3224, 1975, 25957, 1211, 4875, 5193, 48812, 33911, 2655, 3714, 1829, 3224], "avg_logprob": -0.18210564855308758, "compression_ratio": 1.6804123711340206, "no_speech_prob": 0.0, "words": [{"start": 929.98, "end": 930.68, "word": "الان", "probability": 0.788330078125}, {"start": 930.68, "end": 931.7, "word": " لاحظوا", "probability": 0.9635009765625}, {"start": 931.7, "end": 932.08, "word": " معي", "probability": 0.80517578125}, {"start": 932.08, "end": 932.7, "word": " هذا", 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"seek": 148737, "start": 1459.31, "end": 1487.37, "text": "أهم شيء اللى بنى عليها هذا السؤال انه نفهم احنا ان الصيغة المشبعة تماما لل C3 هي H8 الان مقابل كل هيدروجينتين بخصومهم بدي اعمل double bond او حلقة واضح فخصمت هيدروجنتين على كام مرة امرتين اربعة تقسيم اتنين اتنين فهنا عملت حلقة و double bond هنا عملت تنتين by bonds هنا عملت تنتين double bonds", "tokens": [10721, 16095, 44049, 38207, 13672, 7578, 44945, 7578, 25894, 11296, 23758, 21136, 33604, 6027, 16472, 3224, 8717, 5172, 16095, 1975, 5016, 8315, 16472, 31767, 1829, 17082, 3660, 9673, 8592, 3555, 27884, 46811, 10943, 995, 24976, 383, 18, 39896, 389, 23, 2423, 7649, 3714, 4587, 16758, 1211, 28242, 8032, 25708, 2288, 29245, 9957, 2655, 9957, 4724, 9778, 9381, 20498, 16095, 4724, 16254, 1975, 25957, 1211, 3834, 6086, 1975, 2407, 11331, 1211, 28671, 4032, 46958, 5016, 6156, 9778, 9381, 2304, 2655, 8032, 25708, 2288, 29245, 29399, 9957, 15844, 9122, 10943, 3714, 25720, 1975, 29973, 2655, 9957, 1975, 25513, 27884, 6055, 4587, 3794, 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"end": 1527.28, "word": " CH3", "probability": 0.935791015625}, {"start": 1527.28, "end": 1529.06, "word": " CH2Br", "probability": 0.640869140625}, {"start": 1529.06, "end": 1530.02, "word": " بده", "probability": 0.798095703125}, {"start": 1530.02, "end": 1530.34, "word": " يعمل", "probability": 0.9513346354166666}, {"start": 1530.34, "end": 1530.92, "word": " عليها", "probability": 0.98681640625}, {"start": 1530.92, "end": 1531.44, "word": " ال", "probability": 0.751953125}, {"start": 1531.44, "end": 1532.24, "word": " eucleophilic", "probability": 0.7880045572916666}, {"start": 1532.24, "end": 1532.9, "word": " substitution", "probability": 0.8779296875}, {"start": 1532.9, "end": 1533.2, "word": " هذه", "probability": 0.333251953125}, {"start": 1533.2, "end": 1533.76, "word": " الكربون", "probability": 0.8175455729166666}, {"start": 1533.76, "end": 1534.66, "word": " اتهاجمها", "probability": 0.82158203125}], "temperature": 1.0}, {"id": 61, "seek": 156459, "start": 1536.35, "end": 1564.59, "text": "تطرد ال PR ما هو ذا نيوكليو 5 إذا النتيجة فينيل C triple bond C وهنا هياتحدت مع CH2 CH3 طردت ال PR إبدالي نيوكليو فينيل الان هذا المركب مع ال lithium و ال ammonia شو بيعمل؟", "tokens": [2655, 9566, 2288, 3215, 2423, 11568, 19446, 31439, 29910, 995, 8717, 1829, 2407, 28820, 1829, 2407, 1025, 11933, 15730, 28239, 31371, 7435, 3660, 8978, 22653, 1211, 383, 15508, 6086, 383, 37037, 8315, 39896, 9307, 24401, 2655, 20449, 5995, 17, 5995, 18, 23032, 2288, 3215, 2655, 2423, 11568, 11933, 44510, 6027, 1829, 8717, 1829, 2407, 28820, 1829, 2407, 8978, 22653, 1211, 2423, 7649, 23758, 9673, 31747, 3555, 20449, 2423, 32180, 4032, 2423, 46833, 13412, 2407, 4724, 1829, 25957, 1211, 22807], "avg_logprob": -0.39824219793081284, "compression_ratio": 1.4728260869565217, "no_speech_prob": 0.0, "words": [{"start": 1536.35, "end": 1536.89, "word": "تطرد", "probability": 0.69158935546875}, {"start": 1536.89, "end": 1537.57, "word": " ال", "probability": 0.43408203125}, {"start": 1537.57, 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"text": "Double bond هو اكيد بيضيف الهيدروجين عكس بعض لكن مافيش فارق بالنتيجة هايو الهيدروجين اللي ضفته كيف اجوا عكس بعض لكن المراكب لا فيه cis ولا trans لأن هدوله زي بعض الان بعد هيك هذا المراكب بتعمله اوزونوليسيز شو ال اوزونوليسيز نكسر ال double bond لتنتين", "tokens": [35, 33147, 6086, 31439, 1975, 4117, 25708, 4724, 1829, 11242, 33911, 2423, 3224, 25708, 2288, 29245, 9957, 6225, 4117, 3794, 45030, 11242, 44381, 19446, 41185, 8592, 6156, 9640, 4587, 20666, 29399, 1829, 7435, 3660, 8032, 995, 1829, 2407, 2423, 3224, 25708, 2288, 29245, 9957, 13672, 1829, 48812, 5172, 47395, 9122, 33911, 1975, 7435, 14407, 6225, 4117, 3794, 45030, 11242, 44381, 9673, 23557, 4117, 3555, 20193, 8978, 3224, 37847, 49429, 1145, 5296, 33456, 8032, 3215, 12610, 3224, 30767, 1829, 45030, 11242, 2423, 7649, 39182, 39896, 4117, 23758, 9673, 23557, 4117, 3555, 39894, 25957, 43761, 1975, 2407, 11622, 11536, 12610, 1829, 3794, 1829, 11622, 13412, 2407, 2423, 1975, 2407, 11622, 11536, 12610, 1829, 3794, 1829, 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هاي ال eyes وبينتين كام نوع عندى من ال hydrogens خلينا نقول هدول ال hydrogens زى بعض و هدى و هدى و هدى نفس ايش؟ كيف؟", "tokens": [6027, 7649, 8032, 47302, 2423, 2575, 46599, 9957, 2655, 9957, 9122, 10943, 8717, 45367, 43242, 7578, 9154, 2423, 5796, 6675, 694, 16490, 1211, 9957, 995, 8717, 39648, 8032, 3215, 12610, 2423, 5796, 6675, 694, 30767, 7578, 45030, 11242, 4032, 8032, 3215, 7578, 4032, 8032, 3215, 7578, 4032, 8032, 3215, 7578, 8717, 36178, 1975, 1829, 8592, 22807, 9122, 33911, 22807], "avg_logprob": -0.31666668007771176, "compression_ratio": 1.503875968992248, "no_speech_prob": 0.0, "words": [{"start": 1839.91, "end": 1840.37, "word": "الان", "probability": 0.769287109375}, {"start": 1840.37, "end": 1840.61, "word": " هاي", "probability": 0.55224609375}, {"start": 1840.61, "end": 1840.73, "word": " ال", "probability": 0.951171875}, {"start": 1840.73, "end": 1841.03, "word": " eyes", "probability": 0.251220703125}, {"start": 1841.03, "end": 1841.73, "word": " وبينتين", 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stereoisomers", "probability": 0.92431640625}, {"start": 2094.2, "end": 2094.98, "word": " طبعا", "probability": 0.927001953125}, {"start": 2094.98, "end": 2095.12, "word": " اللي", "probability": 0.71728515625}, {"start": 2095.12, "end": 2095.32, "word": " مش", "probability": 0.982421875}, {"start": 2095.32, "end": 2095.68, "word": " عارف", "probability": 0.9861653645833334}, {"start": 2095.68, "end": 2095.84, "word": " ال", "probability": 0.27587890625}, {"start": 2095.84, "end": 2096.66, "word": " styrene", "probability": 0.5850830078125}, {"start": 2096.66, "end": 2098.9, "word": " زنبها", "probability": 0.75238037109375}, {"start": 2098.9, "end": 2099.04, "word": " ع", "probability": 0.69384765625}, {"start": 2099.04, "end": 2099.6, "word": " جنبها", "probability": 0.9779052734375}, {"start": 2099.6, "end": 2101.9, "word": " CH", "probability": 0.82958984375}, {"start": 2101.9, "end": 2102.82, "word": " double", "probability": 0.31787109375}, {"start": 2102.82, "end": 2103.4, "word": " bond", "probability": 0.93505859375}, {"start": 2103.4, "end": 2105.4, "word": " CH2", "probability": 0.86767578125}, {"start": 2105.4, "end": 2106.36, "word": " لاحظوا", "probability": 0.809814453125}, {"start": 2106.36, "end": 2106.58, "word": " هذا", "probability": 0.80859375}, {"start": 2106.58, "end": 2107.22, "word": " سؤال", "probability": 0.8776041666666666}, {"start": 2107.22, "end": 2107.78, "word": " جميل", "probability": 0.9939778645833334}, {"start": 2107.78, "end": 2108.5, "word": " لو", "probability": 0.91845703125}, {"start": 2108.5, "end": 2108.92, "word": " انا", "probability": 0.716796875}, {"start": 2108.92, "end": 2109.48, "word": " كنت", "probability": 0.99072265625}, {"start": 2109.48, "end": 2110.0, "word": " باضيف", "probability": 0.819580078125}, {"start": 2110.0, "end": 2110.8, "word": " HBr", "probability": 0.879150390625}, {"start": 2110.8, "end": 2110.98, "word": " في", "probability": 0.94482421875}, {"start": 2110.98, "end": 2111.24, "word": " وجود", "probability": 0.9580078125}, {"start": 2111.24, "end": 2111.5, "word": " H", "probability": 0.95703125}, {"start": 2111.5, "end": 2111.82, "word": " plus", "probability": 0.125732421875}, {"start": 2111.82, "end": 2112.26, "word": " هضيفه", "probability": 0.8612060546875}, {"start": 2112.26, "end": 2112.58, "word": " حسب", "probability": 0.97412109375}, {"start": 2112.58, "end": 2113.06, "word": " قاعدة", "probability": 0.9708251953125}, {"start": 2113.06, "end": 2113.92, "word": " Markovnikov", "probability": 0.8685302734375}, {"start": 2113.92, "end": 2114.54, "word": " هحط", "probability": 0.9381510416666666}, {"start": 2114.54, "end": 2114.8, "word": " هنا", "probability": 0.9453125}, {"start": 2114.8, "end": 2115.04, "word": " ال", "probability": 0.919921875}, {"start": 2115.04, "end": 2115.34, "word": " H", "probability": 0.625}], "temperature": 1.0}, {"id": 82, "seek": 214330, "start": 2116.14, "end": 2143.3, "text": "وهنا ال PR وجدت في هذه الحالة هعمل chiral center هنا هيطلع عندى ناتجين لو أنا بضيف ال HPR في وجود H Plus هنا ال H هنا ال PR إذا انا عملت chiral center لأن لما بضيف في وجود ال peroxide Anti Markovnikov's addition يعني بدي ألغى هذا ال double bond و أحط هنا H و هنا PR", "tokens": [2407, 3224, 8315, 2423, 11568, 49610, 3215, 2655, 8978, 29538, 21542, 6027, 3660, 8032, 25957, 1211, 23782, 304, 3056, 34105, 8032, 1829, 9566, 1211, 3615, 43242, 7578, 8717, 9307, 7435, 9957, 45164, 41850, 4724, 11242, 33911, 2423, 12557, 49, 8978, 49610, 23328, 389, 7721, 34105, 2423, 389, 34105, 2423, 11568, 11933, 15730, 1975, 8315, 6225, 42213, 2655, 23782, 304, 3056, 5296, 33456, 5296, 15042, 4724, 11242, 33911, 8978, 49610, 23328, 2423, 4768, 34454, 27757, 3934, 5179, 13123, 5179, 311, 4500, 37495, 22653, 4724, 16254, 5551, 1211, 17082, 7578, 23758, 2423, 3834, 6086, 4032, 5551, 5016, 9566, 34105, 389, 4032, 34105, 11568], "avg_logprob": -0.30606618669687535, "compression_ratio": 1.6317991631799162, "no_speech_prob": 0.0, "words": [{"start": 2116.14, "end": 2116.66, "word": "وهنا", "probability": 0.5440266927083334}, {"start": 2116.66, "end": 2116.84, "word": " ال", "probability": 0.87890625}, {"start": 2116.84, "end": 2117.34, "word": " PR", "probability": 0.441650390625}, {"start": 2117.34, "end": 2118.52, "word": " وجدت", "probability": 0.6077473958333334}, {"start": 2118.52, "end": 2118.6, "word": " في", "probability": 0.7060546875}, {"start": 2118.6, "end": 2118.78, "word": " هذه", "probability": 0.93505859375}, {"start": 2118.78, "end": 2119.14, "word": " الحالة", "probability": 0.9698893229166666}, {"start": 2119.14, "end": 2119.56, "word": " هعمل", "probability": 0.8566080729166666}, {"start": 2119.56, "end": 2120.06, "word": " chiral", "probability": 0.6256103515625}, {"start": 2120.06, "end": 2120.54, "word": " center", "probability": 0.69775390625}, {"start": 2120.54, "end": 2120.74, "word": " هنا", "probability": 0.5078125}, {"start": 2120.74, "end": 2121.14, "word": " هيطلع", "probability": 0.70625}, {"start": 2121.14, "end": 2121.46, "word": " عندى", "probability": 0.595458984375}, {"start": 2121.46, "end": 2122.14, "word": " ناتجين", "probability": 0.95947265625}, {"start": 2122.14, "end": 2124.08, "word": " لو", "probability": 0.8095703125}, {"start": 2124.08, "end": 2124.3, "word": " أنا", "probability": 0.5625}, {"start": 2124.3, "end": 2124.66, "word": " بضيف", "probability": 0.8865559895833334}, {"start": 2124.66, "end": 2124.82, "word": " ال", "probability": 0.90771484375}, {"start": 2124.82, "end": 2125.38, "word": " HPR", "probability": 0.623779296875}, {"start": 2125.38, "end": 2125.52, "word": " في", "probability": 0.8232421875}, {"start": 2125.52, "end": 2125.78, "word": " وجود", "probability": 0.981201171875}, {"start": 2125.78, "end": 2126.02, "word": " H", "probability": 0.8388671875}, {"start": 2126.02, "end": 2126.46, "word": " Plus", "probability": 0.140625}, {"start": 2126.46, "end": 2127.0, "word": " هنا", "probability": 0.6162109375}, {"start": 2127.0, "end": 2127.18, "word": " ال", "probability": 0.94384765625}, {"start": 2127.18, "end": 2127.46, "word": " H", "probability": 0.93359375}, {"start": 2127.46, "end": 2127.9, "word": " هنا", "probability": 0.65576171875}, {"start": 2127.9, "end": 2128.08, "word": " ال", "probability": 0.97265625}, {"start": 2128.08, "end": 2128.46, "word": " PR", "probability": 0.97509765625}, {"start": 2128.46, "end": 2128.72, "word": " إذا", "probability": 0.731201171875}, {"start": 2128.72, "end": 2128.86, "word": " انا", "probability": 0.522705078125}, {"start": 2128.86, "end": 2129.16, "word": " عملت", "probability": 0.9806315104166666}, {"start": 2129.16, "end": 2129.52, "word": " chiral", "probability": 0.93896484375}, {"start": 2129.52, "end": 2129.94, "word": " center", "probability": 0.8916015625}, {"start": 2129.94, "end": 2130.52, "word": " لأن", "probability": 0.53759765625}, {"start": 2130.52, "end": 2130.7, "word": " لما", "probability": 0.7880859375}, {"start": 2130.7, "end": 2131.34, "word": " بضيف", "probability": 0.9007161458333334}, {"start": 2131.34, "end": 2132.3, "word": " في", "probability": 0.82080078125}, {"start": 2132.3, "end": 2132.76, "word": " وجود", "probability": 0.983154296875}, {"start": 2132.76, "end": 2132.92, "word": " ال", "probability": 0.93359375}, {"start": 2132.92, "end": 2133.7, "word": " peroxide", "probability": 0.72705078125}, {"start": 2133.7, "end": 2134.76, "word": " Anti", "probability": 0.21826171875}, {"start": 2134.76, "end": 2136.02, "word": " Markovnikov's", "probability": 0.81279296875}, {"start": 2136.02, "end": 2136.64, "word": " addition", "probability": 0.8271484375}, {"start": 2136.64, "end": 2137.14, "word": " يعني", "probability": 0.897705078125}, {"start": 2137.14, "end": 2137.34, "word": " بدي", "probability": 0.755615234375}, {"start": 2137.34, "end": 2137.78, "word": " ألغى", "probability": 0.9078369140625}, {"start": 2137.78, "end": 2138.08, "word": " هذا", "probability": 0.38427734375}, {"start": 2138.08, "end": 2138.2, "word": " ال", "probability": 0.7958984375}, {"start": 2138.2, "end": 2138.4, "word": " double", "probability": 0.84765625}, {"start": 2138.4, "end": 2138.94, "word": " bond", "probability": 0.962890625}, {"start": 2138.94, "end": 2139.54, "word": " و", "probability": 0.4765625}, {"start": 2139.54, "end": 2139.96, "word": " أحط", "probability": 0.8795572916666666}, {"start": 2139.96, "end": 2140.46, "word": " هنا", "probability": 0.97314453125}, {"start": 2140.46, "end": 2141.92, "word": " H", "probability": 0.9404296875}, {"start": 2141.92, "end": 2142.36, "word": " و", "probability": 0.71630859375}, {"start": 2142.36, "end": 2142.7, "word": " هنا", "probability": 0.92724609375}, {"start": 2142.7, "end": 2143.3, "word": " PR", "probability": 0.79296875}], "temperature": 1.0}, {"id": 83, "seek": 215855, "start": 2143.65, "end": 2158.55, "text": "بر فيها انا كايرال سنتر فيها انا كايرال سنتر اذا الكم ايزو مار طلع عني واحد مش اتنين لو كنا بنضيف hbr في وجود h plus بطلع اتنين", "tokens": [26890, 8978, 11296, 1975, 8315, 9122, 995, 13546, 6027, 8608, 29399, 2288, 8978, 11296, 1975, 8315, 9122, 995, 13546, 6027, 8608, 29399, 2288, 1975, 15730, 2423, 24793, 1975, 1829, 11622, 2407, 3714, 9640, 23032, 1211, 3615, 18871, 1829, 36764, 24401, 37893, 1975, 2655, 1863, 9957, 45164, 9122, 8315, 44945, 11242, 33911, 276, 1443, 8978, 49610, 23328, 276, 1804, 4724, 9566, 1211, 3615, 1975, 2655, 1863, 9957], "avg_logprob": -0.3393190218441522, "compression_ratio": 1.6846153846153846, "no_speech_prob": 0.0, "words": [{"start": 2143.65, "end": 2144.17, "word": "بر", "probability": 0.155029296875}, {"start": 2144.17, "end": 2144.85, "word": " فيها", "probability": 0.4710693359375}, {"start": 2144.85, "end": 2145.05, "word": " انا", "probability": 0.5621337890625}, {"start": 2145.05, "end": 2145.49, "word": " كايرال", "probability": 0.710205078125}, {"start": 2145.49, "end": 2146.11, "word": " سنتر", "probability": 0.6466471354166666}, {"start": 2146.11, "end": 2146.95, "word": " فيها", "probability": 0.568359375}, {"start": 2146.95, "end": 2147.11, "word": " انا", "probability": 0.930908203125}, {"start": 2147.11, "end": 2147.53, "word": " كايرال", "probability": 0.9683837890625}, {"start": 2147.53, "end": 2148.21, "word": " سنتر", "probability": 0.9733072916666666}, {"start": 2148.21, "end": 2149.09, "word": " اذا", "probability": 0.62255859375}, {"start": 2149.09, "end": 2149.41, "word": " الكم", "probability": 0.7509765625}, {"start": 2149.41, "end": 2149.87, "word": " ايزو", "probability": 0.50433349609375}, {"start": 2149.87, "end": 2150.05, "word": " مار", "probability": 0.7529296875}, {"start": 2150.05, "end": 2150.35, "word": " طلع", "probability": 0.7685546875}, {"start": 2150.35, "end": 2150.67, "word": " عني", "probability": 0.51593017578125}, {"start": 2150.67, "end": 2151.73, "word": " واحد", "probability": 0.796875}, {"start": 2151.73, "end": 2153.57, "word": " مش", "probability": 0.716796875}, {"start": 2153.57, "end": 2154.09, "word": " اتنين", "probability": 0.9622802734375}, {"start": 2154.09, "end": 2155.19, "word": " لو", "probability": 0.86474609375}, {"start": 2155.19, "end": 2155.43, "word": " كنا", "probability": 0.974365234375}, {"start": 2155.43, "end": 2155.99, "word": " بنضيف", "probability": 0.9661458333333334}, {"start": 2155.99, "end": 2156.81, "word": " hbr", "probability": 0.3773193359375}, {"start": 2156.81, "end": 2156.95, "word": " في", "probability": 0.9677734375}, {"start": 2156.95, "end": 2157.21, "word": " وجود", "probability": 0.972900390625}, {"start": 2157.21, "end": 2157.43, "word": " h", "probability": 0.8603515625}, {"start": 2157.43, "end": 2157.73, "word": " plus", "probability": 0.33935546875}, {"start": 2157.73, "end": 2158.11, "word": " بطلع", "probability": 0.8350830078125}, {"start": 2158.11, "end": 2158.55, "word": " اتنين", "probability": 0.9898681640625}], "temperature": 1.0}, {"id": 84, "seek": 219546, "start": 2168.27, "end": 2195.47, "text": "هذا السؤال MAI reacts with ethyl chloride producing ethyl iodide لاحظوا هنا إبدال أن اليود بيحل محل كلور هذه المعلومة أخدناها ولا لأ اليود بيحل محل كلور و العكس مش صحيح Cyclohexanol بتكون تتذكروا بمخكوا ع طول ال Cyclohexanol", "tokens": [3224, 15730, 21136, 33604, 6027, 376, 48698, 33305, 365, 1030, 3495, 75, 35434, 10501, 1030, 3495, 75, 44422, 482, 20193, 5016, 19913, 14407, 34105, 11933, 44510, 6027, 14739, 45595, 23328, 4724, 1829, 5016, 1211, 3714, 5016, 1211, 9122, 1211, 13063, 29538, 9673, 30241, 20498, 3660, 5551, 9778, 3215, 8315, 11296, 49429, 5296, 10721, 45595, 23328, 4724, 1829, 5016, 1211, 3714, 5016, 1211, 9122, 1211, 13063, 4032, 18863, 4117, 3794, 37893, 20328, 5016, 1829, 5016, 10295, 66, 752, 675, 87, 282, 401, 39894, 30544, 6055, 2655, 8848, 37983, 14407, 4724, 2304, 9778, 4117, 14407, 6225, 23032, 12610, 2423, 10295, 66, 752, 675, 87, 282, 401], "avg_logprob": -0.19657738549368722, "compression_ratio": 1.588785046728972, "no_speech_prob": 0.0, "words": [{"start": 2168.27, "end": 2168.71, "word": "هذا", "probability": 0.89892578125}, {"start": 2168.71, "end": 2169.33, "word": " السؤال", "probability": 0.99365234375}, {"start": 2169.33, "end": 2170.29, "word": " MAI", "probability": 0.424468994140625}, {"start": 2170.29, "end": 2170.83, "word": " reacts", "probability": 0.52001953125}, {"start": 2170.83, "end": 2171.11, "word": " with", "probability": 0.9033203125}, {"start": 2171.11, "end": 2171.49, "word": " ethyl", "probability": 0.908203125}, {"start": 2171.49, "end": 2171.91, "word": " chloride", "probability": 0.93701171875}, {"start": 2171.91, "end": 2172.67, "word": " producing", "probability": 0.6025390625}, {"start": 2172.67, "end": 2173.11, "word": " ethyl", "probability": 0.8805338541666666}, {"start": 2173.11, "end": 2173.77, "word": " iodide", "probability": 0.97705078125}, {"start": 2173.77, "end": 2174.41, "word": " لاحظوا", "probability": 0.8074951171875}, {"start": 2174.41, "end": 2174.61, "word": " هنا", "probability": 0.8154296875}, {"start": 2174.61, "end": 2175.11, "word": " إبدال", "probability": 0.70068359375}, {"start": 2175.11, "end": 2175.77, "word": " أن", "probability": 0.418701171875}, {"start": 2175.77, "end": 2176.41, "word": " اليود", "probability": 0.84423828125}, {"start": 2176.41, "end": 2177.01, "word": " بيحل", "probability": 0.76617431640625}, {"start": 2177.01, "end": 2177.45, "word": " محل", "probability": 0.89697265625}, {"start": 2177.45, "end": 2178.05, "word": " كلور", "probability": 0.8323567708333334}, {"start": 2178.05, "end": 2178.67, "word": " هذه", "probability": 0.615234375}, {"start": 2178.67, "end": 2179.25, "word": " المعلومة", "probability": 0.9912109375}, {"start": 2179.25, "end": 2179.87, "word": " أخدناها", "probability": 0.9578125}, {"start": 2179.87, "end": 2180.09, "word": " ولا", "probability": 0.7265625}, {"start": 2180.09, "end": 2180.53, "word": " لأ", "probability": 0.88525390625}, {"start": 2180.53, "end": 2183.67, "word": " اليود", "probability": 0.80859375}, {"start": 2183.67, "end": 2184.01, "word": " بيحل", "probability": 0.9925537109375}, {"start": 2184.01, "end": 2184.33, "word": " محل", "probability": 0.9903971354166666}, {"start": 2184.33, "end": 2184.65, "word": " كلور", "probability": 0.9563802083333334}, {"start": 2184.65, "end": 2184.75, "word": " و", "probability": 0.62548828125}, {"start": 2184.75, "end": 2185.05, "word": " العكس", "probability": 0.89599609375}, {"start": 2185.05, "end": 2185.19, "word": " مش", "probability": 0.953125}, {"start": 2185.19, "end": 2186.29, "word": " صحيح", "probability": 0.9954833984375}, {"start": 2186.29, "end": 2188.57, "word": " Cyclohexanol", "probability": 0.90576171875}, {"start": 2188.57, "end": 2192.63, "word": " بتكون", "probability": 0.5001220703125}, {"start": 2192.63, "end": 2193.29, "word": " تتذكروا", "probability": 0.92021484375}, {"start": 2193.29, "end": 2193.79, "word": " بمخكوا", "probability": 0.809423828125}, {"start": 2193.79, "end": 2193.93, "word": " ع", "probability": 0.412841796875}, {"start": 2193.93, "end": 2194.13, "word": " طول", "probability": 0.81640625}, {"start": 2194.13, "end": 2194.33, "word": " ال", "probability": 0.62548828125}, {"start": 2194.33, "end": 2195.47, "word": " Cyclohexanol", "probability": 0.9090401785714286}], "temperature": 1.0}, {"id": 85, "seek": 221467, "start": 2196.45, "end": 2214.67, "text": "ركزنا عليه في الرسم ولا لأ؟ اللي متصل ب OH لو عملتله أكسدة شو هيعمل؟ هيحذف ال H و ال H هاي الأكسدة تبعته، هاي أكسدته، إيش أعطاني؟", "tokens": [31747, 11622, 8315, 47356, 8978, 34892, 38251, 49429, 5296, 10721, 22807, 13672, 1829, 44650, 36520, 4724, 13931, 45164, 6225, 42213, 2655, 43761, 5551, 4117, 3794, 41891, 13412, 2407, 39896, 25957, 1211, 22807, 39896, 5016, 8848, 5172, 2423, 389, 4032, 2423, 389, 8032, 47302, 16247, 4117, 3794, 41891, 6055, 3555, 34268, 3224, 12399, 8032, 47302, 5551, 4117, 3794, 3215, 47395, 12399, 11933, 1829, 8592, 5551, 3615, 9566, 7649, 1829, 22807], "avg_logprob": -0.15424107504742487, "compression_ratio": 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"probability": 0.34259033203125}, {"start": 2403.22, "end": 2403.5, "word": " ان", "probability": 0.2294921875}, {"start": 2403.5, "end": 2404.22, "word": " ماينوس", "probability": 0.6892903645833334}, {"start": 2404.22, "end": 2404.96, "word": " تو", "probability": 0.3931884765625}, {"start": 2404.96, "end": 2406.78, "word": " وبتاعة", "probability": 0.4161865234375}, {"start": 2406.78, "end": 2406.94, "word": " اللي", "probability": 0.657470703125}, {"start": 2406.94, "end": 2407.2, "word": " عملناها", "probability": 0.93798828125}, {"start": 2407.2, "end": 2407.62, "word": " مركبة", "probability": 0.6865234375}, {"start": 2407.62, "end": 2408.3, "word": " زيها", "probability": 0.90087890625}, {"start": 2408.3, "end": 2409.28, "word": " اوزونوليسيس", "probability": 0.6244574652777778}, {"start": 2409.28, "end": 2409.46, "word": " او", "probability": 0.518310546875}, {"start": 2409.46, "end": 2409.74, "word": " سيس", "probability": 0.7381998697916666}, {"start": 2409.74, "end": 2410.04, "word": " اوري", "probability": 0.5952962239583334}, {"start": 2410.04, "end": 2410.42, "word": " ترانس", "probability": 0.8260498046875}, {"start": 2410.42, "end": 2410.62, "word": " تو", "probability": 0.572265625}, {"start": 2410.62, "end": 2411.24, "word": " بيوتين", "probability": 0.9364013671875}, {"start": 2411.24, "end": 2414.26, "word": " خليني", "probability": 0.582733154296875}, {"start": 2414.26, "end": 2414.66, "word": " اخد", "probability": 0.7508138020833334}, {"start": 2414.66, "end": 2414.84, "word": " ال", "probability": 0.810546875}, {"start": 2414.84, "end": 2415.14, "word": " سيس", "probability": 0.6696573893229166}, {"start": 2415.14, "end": 2415.38, "word": " تو", "probability": 0.7734375}, {"start": 2415.38, "end": 2415.98, "word": " بيوتين", "probability": 0.983642578125}, {"start": 2415.98, "end": 2417.9, "word": " ارسمه", "probability": 0.762939453125}, {"start": 2417.9, "end": 2418.28, "word": " هان", "probability": 0.66455078125}, {"start": 2418.28, "end": 2419.28, "word": " هاي", "probability": 0.5850830078125}, {"start": 2419.28, "end": 2419.44, "word": " ال", "probability": 0.85546875}, {"start": 2419.44, "end": 2419.62, "word": " سيس", "probability": 0.8143717447916666}, {"start": 2419.62, "end": 2419.86, "word": " تو", "probability": 0.90185546875}, {"start": 2419.86, "end": 2420.28, "word": " بيوتين", "probability": 0.990478515625}, {"start": 2420.28, "end": 2420.48, "word": " بدي", "probability": 0.613037109375}, {"start": 2420.48, "end": 2420.98, "word": " اكسره", "probability": 0.8626953125}, {"start": 2420.98, "end": 2421.12, "word": " من", "probability": 0.986328125}, {"start": 2421.12, "end": 2421.5, "word": " هان", "probability": 0.766845703125}, {"start": 2421.5, "end": 2422.16, "word": " C", "probability": 0.285888671875}, {"start": 2422.16, "end": 2422.36, "word": " double", "probability": 0.3046875}, {"start": 2422.36, "end": 2422.72, "word": " bond", "probability": 0.92626953125}, {"start": 2422.72, "end": 2423.08, "word": " O", "probability": 0.87255859375}, {"start": 2423.08, "end": 2423.56, "word": " وهذه", "probability": 0.4080810546875}, {"start": 2423.56, "end": 2423.88, "word": " H", "probability": 0.68701171875}, {"start": 2423.88, "end": 2424.64, "word": " بالتأكيد", "probability": 0.92607421875}], "temperature": 1.0}, {"id": 93, "seek": 245340, "start": 2426.66, "end": 2453.4, "text": "هذا C double bond OH CH3 Acetaldehyde هذا C double bond OH CH3 Acetaldehyde و لل Trans هاي CH3H و هنا CH3H الان اكسروا هذا من هنا و اكسروا هذا من هنا و حطوا ايش Oxygen Oxygen Oxygen Oxygen", "tokens": [3224, 15730, 383, 3834, 6086, 13931, 5995, 18, 5097, 302, 304, 1479, 3495, 1479, 23758, 383, 3834, 6086, 13931, 5995, 18, 5097, 302, 304, 1479, 3495, 1479, 4032, 24976, 6531, 8032, 47302, 5995, 18, 39, 4032, 34105, 5995, 18, 39, 2423, 7649, 1975, 4117, 3794, 2288, 14407, 23758, 9154, 34105, 4032, 1975, 4117, 3794, 2288, 14407, 23758, 9154, 34105, 4032, 11331, 9566, 14407, 1975, 1829, 8592, 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2431.56, "end": 2431.88, "word": " bond", "probability": 0.97021484375}, {"start": 2431.88, "end": 2432.3, "word": " OH", "probability": 0.96875}, {"start": 2432.3, "end": 2433.22, "word": " CH3", "probability": 0.971923828125}, {"start": 2433.22, "end": 2434.14, "word": " Acetaldehyde", "probability": 0.9671223958333334}, {"start": 2434.14, "end": 2434.5, "word": " و", "probability": 0.560546875}, {"start": 2434.5, "end": 2434.68, "word": " لل", "probability": 0.354736328125}, {"start": 2434.68, "end": 2435.22, "word": " Trans", "probability": 0.345947265625}, {"start": 2435.22, "end": 2438.4, "word": " هاي", "probability": 0.653564453125}, {"start": 2438.4, "end": 2439.94, "word": " CH3H", "probability": 0.9697265625}, {"start": 2439.94, "end": 2440.78, "word": " و", "probability": 0.78076171875}, {"start": 2440.78, "end": 2441.06, "word": " هنا", "probability": 0.77734375}, {"start": 2441.06, "end": 2443.38, "word": " CH3H", "probability": 0.9918619791666666}, {"start": 2443.38, "end": 2444.32, "word": " الان", "probability": 0.61572265625}, {"start": 2444.32, "end": 2445.04, "word": " اكسروا", "probability": 0.95634765625}, {"start": 2445.04, "end": 2445.32, "word": " هذا", "probability": 0.916015625}, {"start": 2445.32, "end": 2445.56, "word": " من", "probability": 0.9873046875}, {"start": 2445.56, "end": 2445.9, "word": " هنا", "probability": 0.93212890625}, {"start": 2445.9, "end": 2447.16, "word": " و", "probability": 0.55810546875}, {"start": 2447.16, "end": 2447.64, "word": " اكسروا", "probability": 0.9751953125}, {"start": 2447.64, "end": 2447.88, "word": " هذا", "probability": 0.9833984375}, {"start": 2447.88, "end": 2448.14, "word": " من", "probability": 0.9892578125}, {"start": 2448.14, "end": 2448.5, "word": " هنا", "probability": 0.9658203125}, {"start": 2448.5, "end": 2448.78, "word": " و", "probability": 0.9794921875}, {"start": 2448.78, "end": 2449.18, "word": " حطوا", "probability": 0.8522135416666666}, {"start": 2449.18, "end": 2449.52, "word": " ايش", "probability": 0.8619791666666666}, {"start": 2449.52, "end": 2451.12, "word": " Oxygen", "probability": 0.720703125}, {"start": 2451.12, "end": 2451.96, "word": " Oxygen", "probability": 0.81591796875}, {"start": 2451.96, "end": 2452.74, "word": " Oxygen", "probability": 0.95361328125}, {"start": 2452.74, "end": 2453.4, "word": " Oxygen", "probability": 0.972412109375}], "temperature": 1.0}, {"id": 94, "seek": 247496, "start": 2453.98, "end": 2474.96, "text": "كل النواتج ايش؟ أسيتلديهيد بيعطي نفس الناتج produces only أسيتلديهيد أو إيثانال أسيتلديهيد CH3SH is more acidic than CH3OH due to size", "tokens": [28820, 28239, 2407, 9307, 7435, 1975, 1829, 8592, 22807, 5551, 3794, 36081, 1211, 16254, 3224, 25708, 4724, 40228, 9566, 1829, 8717, 36178, 28239, 9307, 7435, 14725, 787, 5551, 3794, 36081, 1211, 16254, 3224, 25708, 34051, 11933, 1829, 12984, 7649, 6027, 5551, 3794, 36081, 1211, 16254, 3224, 25708, 5995, 18, 17308, 307, 544, 39514, 813, 5995, 18, 31187, 3462, 281, 2744], "avg_logprob": -0.25909324161341935, "compression_ratio": 1.3513513513513513, "no_speech_prob": 0.0, "words": [{"start": 2453.98, "end": 2454.34, "word": "كل", "probability": 0.771484375}, {"start": 2454.34, "end": 2455.02, "word": " النواتج", "probability": 0.8031005859375}, {"start": 2455.02, "end": 2455.5, "word": " ايش؟", "probability": 0.706787109375}, {"start": 2455.5, "end": 2457.06, "word": " أسيتلديهيد", "probability": 0.6798270089285714}, {"start": 2457.06, "end": 2458.52, "word": " بيعطي", "probability": 0.78363037109375}, {"start": 2458.52, "end": 2458.8, "word": " نفس", "probability": 0.989990234375}, {"start": 2458.8, "end": 2459.48, "word": " الناتج", "probability": 0.9140625}, {"start": 2459.48, "end": 2460.38, "word": " produces", "probability": 0.2047119140625}, {"start": 2460.38, "end": 2461.22, "word": " only", "probability": 0.83349609375}, {"start": 2461.22, "end": 2463.4, "word": " أسيتلديهيد", "probability": 0.9464285714285714}, {"start": 2463.4, "end": 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"seek": 249844, "start": 2477.52, "end": 2498.44, "text": "سلفر مع اكسجين ايش العامل المحدد في ال acidity ال size ال due to size الان ارسموا المراكبات التالية بدي بيوتين", "tokens": [3794, 46538, 2288, 20449, 1975, 4117, 3794, 7435, 9957, 1975, 1829, 8592, 18863, 10943, 1211, 9673, 24401, 3215, 8978, 2423, 8258, 507, 2423, 2744, 2423, 3462, 281, 2744, 2423, 7649, 1975, 2288, 38251, 14407, 9673, 23557, 4117, 3555, 9307, 16712, 6027, 10632, 4724, 16254, 4724, 1829, 35473, 9957], "avg_logprob": -0.35299744897959184, "compression_ratio": 1.3953488372093024, "no_speech_prob": 0.0, "words": [{"start": 2477.52, "end": 2478.28, "word": "سلفر", "probability": 0.5266520182291666}, {"start": 2478.28, "end": 2478.46, "word": " مع", "probability": 0.9072265625}, {"start": 2478.46, "end": 2479.22, "word": " اكسجين", "probability": 0.784765625}, {"start": 2479.22, "end": 2479.92, "word": " ايش", "probability": 0.456787109375}, {"start": 2479.92, "end": 2480.32, "word": " العامل", "probability": 0.8824869791666666}, {"start": 2480.32, "end": 2480.92, "word": " المحدد", "probability": 0.9825846354166666}, {"start": 2480.92, "end": 2481.04, "word": " في", "probability": 0.86865234375}, {"start": 2481.04, "end": 2481.14, "word": " ال", "probability": 0.89990234375}, {"start": 2481.14, "end": 2481.84, "word": " acidity", "probability": 0.7132568359375}, {"start": 2481.84, "end": 2482.56, "word": " ال", "probability": 0.333984375}, {"start": 2482.56, "end": 2483.04, "word": " size", "probability": 0.29345703125}, {"start": 2483.04, "end": 2483.74, "word": " ال", "probability": 0.5029296875}, {"start": 2483.74, "end": 2483.96, "word": " due", "probability": 0.54296875}, {"start": 2483.96, "end": 2484.24, "word": " to", "probability": 0.94580078125}, {"start": 2484.24, "end": 2487.82, "word": " size", "probability": 0.5068359375}, {"start": 2487.82, "end": 2494.74, "word": " الان", "probability": 0.684326171875}, {"start": 2494.74, "end": 2495.44, "word": " ارسموا", "probability": 0.841796875}, {"start": 2495.44, "end": 2496.3, "word": " المراكبات", "probability": 0.90615234375}, {"start": 2496.3, "end": 2497.0, "word": " التالية", "probability": 0.9913736979166666}, {"start": 2497.0, "end": 2497.54, "word": " بدي", "probability": 0.6263427734375}, {"start": 2497.54, "end": 2498.44, "word": " بيوتين", "probability": 0.939208984375}], "temperature": 1.0}, {"id": 96, "seek": 252202, "start": 2499.56, "end": 2522.02, "text": "يعني carbon تنتين تلاتة أربعة على لمرة اتنين ايش موجود عندكم؟ فينوكسي يعني O phenyl OH OHANA CH3 CH2 CH3 الآن انا برسم المركب بعدين بشوفه اذا طلع R كان بيها ماطلعش R", "tokens": [40228, 22653, 5954, 6055, 29399, 9957, 6055, 1211, 9307, 3660, 5551, 25513, 27884, 15844, 32767, 25720, 1975, 2655, 1863, 9957, 1975, 1829, 8592, 3714, 29245, 23328, 43242, 24793, 22807, 8978, 1863, 2407, 4117, 3794, 1829, 37495, 22653, 422, 7279, 5088, 13931, 13931, 21429, 5995, 18, 5995, 17, 5995, 18, 6024, 48506, 1975, 8315, 4724, 2288, 38251, 9673, 31747, 3555, 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بنتين", "probability": 0.9261067708333334}, {"start": 2543.43, "end": 2543.81, "word": " خليني", "probability": 0.8211669921875}, {"start": 2543.81, "end": 2544.31, "word": " ارسمه", "probability": 0.8828125}, {"start": 2544.31, "end": 2544.77, "word": " بهذا", "probability": 0.96826171875}, {"start": 2544.77, "end": 2545.29, "word": " الشكل", "probability": 0.989990234375}], "temperature": 1.0}, {"id": 98, "seek": 257217, "start": 2546.13, "end": 2572.17, "text": "cyclopentane واحد اتنين تلاتة اربعة خمسة على نمرة تلاتة واربعة شو بدي احط كلور وكلور بالزويك أسد C double bond O OH وهنا ال formal C double bond OH هذا ميتا", "tokens": [1344, 66, 752, 22786, 1929, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 15844, 8717, 2304, 25720, 6055, 1211, 9307, 3660, 4032, 9640, 3555, 27884, 13412, 2407, 4724, 16254, 1975, 5016, 9566, 9122, 1211, 13063, 4032, 28820, 13063, 20666, 11622, 45865, 4117, 5551, 3794, 3215, 383, 3834, 6086, 422, 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"word": " واربعة", "probability": 0.791748046875}, {"start": 2551.85, "end": 2552.03, "word": " شو", "probability": 0.877685546875}, {"start": 2552.03, "end": 2552.21, "word": " بدي", "probability": 0.7281494140625}, {"start": 2552.21, "end": 2552.63, "word": " احط", "probability": 0.9226888020833334}, {"start": 2552.63, "end": 2554.27, "word": " كلور", "probability": 0.6844889322916666}, {"start": 2554.27, "end": 2554.93, "word": " وكلور", "probability": 0.742919921875}, {"start": 2554.93, "end": 2558.95, "word": " بالزويك", "probability": 0.649169921875}, {"start": 2558.95, "end": 2559.91, "word": " أسد", "probability": 0.7569986979166666}, {"start": 2559.91, "end": 2562.09, "word": " C", "probability": 0.293701171875}, {"start": 2562.09, "end": 2562.35, "word": " double", "probability": 0.31201171875}, {"start": 2562.35, "end": 2562.69, "word": " bond", "probability": 0.92041015625}, {"start": 2562.69, "end": 2563.23, "word": " O", "probability": 0.88671875}, {"start": 2563.23, 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كحول ألكين من وين الترقيم؟ من عند الكحول يعني هذا", "tokens": [2304, 36081, 995, 34051, 4724, 9640, 995, 23758, 3714, 2407, 11242, 45367, 4724, 3794, 1829, 9566, 23758, 9673, 31747, 3555, 49173, 404, 317, 1929, 13412, 2407, 29538, 9673, 7435, 2304, 2407, 27884, 22807, 286, 539, 5955, 5088, 286, 539, 5955, 5088, 49173, 404, 317, 1929, 23758, 9122, 5016, 12610, 5551, 1211, 4117, 9957, 9154, 4032, 9957, 16712, 2288, 4587, 32640, 22807, 9154, 43242, 33251, 5016, 12610, 37495, 22653, 23758], "avg_logprob": -0.24575893240315574, "compression_ratio": 1.50625, "no_speech_prob": 0.0, "words": [{"start": 2573.4, "end": 2573.98, "word": "ميتا", "probability": 0.6168619791666666}, {"start": 2573.98, "end": 2574.14, "word": " أو", "probability": 0.76025390625}, {"start": 2574.14, "end": 2574.4, "word": " بارا", "probability": 0.9529622395833334}, {"start": 2574.4, "end": 2574.62, "word": " هذا", "probability": 0.74560546875}, {"start": 2574.62, "end": 2575.02, "word": " موضوع", "probability": 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"من الأربعة شو بده احضر؟ ستة كيف بده اعمل هذا الكلام؟ اول اشي بده ازيد ذاتين carbon فانا لو فعلت مع ال NANH2 نمرة واحد خلت هذه minus", "tokens": [27842, 16247, 25513, 27884, 13412, 2407, 47525, 3224, 1975, 5016, 11242, 2288, 22807, 8608, 2655, 3660, 9122, 33911, 47525, 3224, 1975, 25957, 1211, 23758, 2423, 28820, 10943, 22807, 1975, 12610, 1975, 8592, 1829, 47525, 3224, 1975, 11622, 25708, 29910, 9307, 9957, 5954, 6156, 7649, 995, 45164, 6156, 30241, 2655, 20449, 2423, 426, 1770, 39, 17, 8717, 2304, 25720, 36764, 24401, 16490, 1211, 2655, 29538, 3175], "avg_logprob": -0.2447916612480626, "compression_ratio": 1.36875, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2958.69, "end": 2958.97, "word": "من", "probability": 0.495361328125}, {"start": 2958.97, "end": 2959.45, "word": " الأربعة", "probability": 0.80908203125}, {"start": 2959.45, "end": 2959.61, "word": " شو", "probability": 0.647705078125}, {"start": 2959.61, "end": 2959.79, "word": " بده", "probability": 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"compression_ratio": 1.8591549295774648, "no_speech_prob": 7.748603820800781e-07, "words": [{"start": 3030.1299999999997, "end": 3031.0499999999997, "word": "الكالهلايد", "probability": 0.6587320963541666}, {"start": 3031.0499999999997, "end": 3031.97, "word": " كبرت", "probability": 0.82080078125}, {"start": 3031.97, "end": 3032.69, "word": " السلسلة", "probability": 0.9853515625}, {"start": 3032.69, "end": 3033.19, "word": " و", "probability": 0.5224609375}, {"start": 3033.19, "end": 3033.63, "word": " بعدين", "probability": 0.93994140625}, {"start": 3033.63, "end": 3033.73, "word": " ل", "probability": 0.38134765625}, {"start": 3033.73, "end": 3034.07, "word": " triple", "probability": 0.38037109375}, {"start": 3034.07, "end": 3034.45, "word": " bond", "probability": 0.91259765625}, {"start": 3034.45, "end": 3034.63, "word": " ان", "probability": 0.467529296875}, {"start": 3034.63, "end": 3035.05, "word": " اخليها", "probability": 0.812744140625}, {"start": 3035.05, "end": 3035.25, 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"word": " يا", "probability": 0.7392578125}, {"start": 3040.69, "end": 3041.11, "word": " cis", "probability": 0.86865234375}, {"start": 3041.11, "end": 3041.79, "word": " الكن", "probability": 0.896728515625}, {"start": 3041.79, "end": 3042.49, "word": " يا", "probability": 0.75048828125}, {"start": 3042.49, "end": 3043.47, "word": " trans", "probability": 0.8115234375}, {"start": 3043.47, "end": 3043.91, "word": " الكن", "probability": 0.96923828125}, {"start": 3043.91, "end": 3044.11, "word": " كل", "probability": 0.63232421875}, {"start": 3044.11, "end": 3044.45, "word": " واحدة", "probability": 0.94775390625}, {"start": 3044.45, "end": 3044.55, "word": " في", "probability": 0.89892578125}, {"start": 3044.55, "end": 3044.97, "word": " إلها", "probability": 0.6528727213541666}, {"start": 3044.97, "end": 3046.23, "word": " شروط", "probability": 0.9524739583333334}, {"start": 3046.23, "end": 3047.27, "word": " معينة", "probability": 0.9889322916666666}, {"start": 3047.27, "end": 3047.83, "word": " ابقى", "probability": 0.4733072916666667}, {"start": 3047.83, "end": 3047.95, "word": " اك", "probability": 0.5146484375}, {"start": 3047.95, "end": 3048.59, "word": " تقريبا", "probability": 0.98447265625}, {"start": 3048.59, "end": 3049.05, "word": " بنكون", "probability": 0.897216796875}, {"start": 3049.05, "end": 3049.73, "word": " غطينا", "probability": 0.9752197265625}, {"start": 3049.73, "end": 3050.69, "word": " يعني", "probability": 0.885009765625}, {"start": 3050.69, "end": 3051.31, "word": " باسئلة", "probability": 0.9498291015625}, {"start": 3051.31, "end": 3051.93, "word": " مختلفة", "probability": 0.9923095703125}, {"start": 3051.93, "end": 3052.33, "word": " معظم", "probability": 0.9803059895833334}, {"start": 3052.33, "end": 3053.13, "word": " الأشياء", "probability": 0.983642578125}, {"start": 3053.13, "end": 3053.81, "word": " اللي", "probability": 0.808837890625}, {"start": 3053.81, "end": 3054.73, "word": " درسناها", "probability": 0.9521484375}, {"start": 3054.73, "end": 3054.89, "word": " و", "probability": 0.8740234375}, {"start": 3054.89, "end": 3055.79, "word": " بنتمنالكوا", "probability": 0.677587890625}, {"start": 3055.79, "end": 3055.89, "word": " ان", "probability": 0.81103515625}, {"start": 3055.89, "end": 3056.07, "word": " شاء", "probability": 0.941162109375}, {"start": 3056.07, "end": 3056.17, "word": " الله", "probability": 0.94775390625}, {"start": 3056.17, "end": 3056.87, "word": " النجاح", "probability": 0.9656575520833334}, {"start": 3056.87, "end": 3057.01, "word": " و", "probability": 0.61474609375}, {"start": 3057.01, "end": 3057.49, "word": " التوفيق", "probability": 0.979736328125}, {"start": 3057.49, "end": 3057.63, "word": " في", "probability": 0.9033203125}, {"start": 3057.63, "end": 3058.11, "word": " الامتحان", "probability": 0.975}, {"start": 3058.11, "end": 3058.23, "word": " اللي", "probability": 0.8857421875}, {"start": 3058.23, "end": 3058.51, "word": " بدكنوا", "probability": 0.5111490885416666}, {"start": 3058.51, "end": 3059.05, "word": " تقدموه", "probability": 0.959765625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3059.972, "duration_after_vad": 2821.7949999999896}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e5bf93dcb8a75119f849750f6e18ea73977c01cd
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_postprocess.srt
@@ -0,0 +1,1440 @@
+1
+00:00:21,240 --> 00:00:26,260
+بسم الله الرحمن الرحيم موضوعنا اليوم عن ال
+
+2
+00:00:26,260 --> 00:00:31,560
+stereochemistry ربما يعني انتوا اتشوقتوا اليها لان
+
+3
+00:00:31,560 --> 00:00:37,220
+احنا من اول محاضرة لما اتكلمنا عن المتشكلات او ال
+
+4
+00:00:37,220 --> 00:00:43,960
+isomers قسمناهم وقلنا هم نوعين اساسيين structural
+
+5
+00:00:43,960 --> 00:00:48,920
+isomers او constitutional isomers سمناهم و stereo
+
+6
+00:00:48,920 --> 00:00:54,250
+isomersالان هذا التصنيف اللى بنشوفه باللوحة
+
+7
+00:00:54,250 --> 00:01:01,030
+التصنيف العام ل .. خلينا نقول ال isomers أخدنا جزء
+
+8
+00:01:01,030 --> 00:01:06,510
+منه اللى هو إيش معنى isomers بشكل عام المركبات
+
+9
+00:01:06,510 --> 00:01:10,750
+اللى لها نفس الصيغة الجزائية ولكن بتختلف في الشكل
+
+10
+00:01:10,750 --> 00:01:16,070
+الان قسمت إلى نوعين النوع الأول ال structural
+
+11
+00:01:16,070 --> 00:01:21,770
+isomers المركباتاللي بتختلف في مواقع ارتباط الذرات
+
+12
+00:01:21,770 --> 00:01:25,310
+يعني فيها different bonding وقولنا هذا different
+
+13
+00:01:25,310 --> 00:01:29,350
+bonding بيقدر إلى انه يكون لها different names ولو
+
+14
+00:01:29,350 --> 00:01:33,430
+على اقل تقدير في الرقم اللي بيحدد مثلا Substituent
+
+15
+00:01:33,430 --> 00:01:37,470
+يعني على سبيل المثال لما نقول بروبين امكون من تلت
+
+16
+00:01:37,470 --> 00:01:41,750
+ذرات الآن على الموقع الأول Clor أو على الموقع
+
+17
+00:01:41,750 --> 00:01:45,430
+التاني Clorهذا صار different bonding يعني أي حد
+
+18
+00:01:45,430 --> 00:01:49,670
+يقول هدولة شو بيفرقوا على البعض، هيقول هذا بروبين
+
+19
+00:01:49,670 --> 00:01:52,990
+تلت ذرات على الموقع الأول كلور صار اسمه one
+
+20
+00:01:52,990 --> 00:01:57,190
+chloroborbine التاني على الموقع اتنين two
+
+21
+00:01:57,190 --> 00:02:03,100
+chloroborbine هدولة اسمين مختلفينالان الشيء التاني
+
+22
+00:02:03,100 --> 00:02:07,900
+في ال isomers اللى حتى ايضا بدنا فيه اللى هو ال
+
+23
+00:02:07,900 --> 00:02:12,900
+stereo isomers المركبات اللى بتكون لها نفس
+
+24
+00:02:12,900 --> 00:02:17,840
+الارتباط ولكن اختلاف في شكلها بالفراغ ولذلك احنا
+
+25
+00:02:17,840 --> 00:02:21,400
+قولنا ال stereo isomers ال atoms they have the
+
+26
+00:02:21,400 --> 00:02:26,970
+same constitutiondifferent arrangement in space
+
+27
+00:02:26,970 --> 00:02:31,590
+بدأنا فيهم الحقيقة لما احنا أخدنا مراكبات ال sis
+
+28
+00:02:31,590 --> 00:02:36,990
+والترانس يعني مثلا عندنا اثين على موقع واحد كلور
+
+29
+00:02:36,990 --> 00:02:40,890
+هاي اثين جزئي ب double bond على موقع واحد كلور
+
+30
+00:02:40,890 --> 00:02:45,030
+وعلى موقع اتنين كلور وبناء على ذلك شو هيصير اسمه
+
+31
+00:02:45,030 --> 00:02:51,130
+one two dichloro ethaneSame bondage الآن يا تورا
+
+32
+00:02:51,130 --> 00:02:57,650
+هدولة ذرتين لchlor جايين على جهة واحدة ولا جايين
+
+33
+00:02:57,650 --> 00:03:01,770
+على جهتين متعاكستين صيرنا نضيف ال prefix أو
+
+34
+00:03:01,770 --> 00:03:08,130
+البادئة اللي هي cis وtrans فالcis وtrans هنا ما
+
+35
+00:03:08,130 --> 00:03:13,470
+بتعني مواقع الذرات مواقع الذرات حدد one two ع ذرة
+
+36
+00:03:13,470 --> 00:03:18,420
+واحد وع ذرة اتنينSame bonding, same name المركب
+
+37
+00:03:18,420 --> 00:03:22,420
+اسمه one two dichloroethane لكن الفرق ال
+
+38
+00:03:22,420 --> 00:03:28,600
+arrangement in space مع بعض و لا ضد بعض و عرفنا ان
+
+39
+00:03:28,600 --> 00:03:34,040
+احنا بنستعمل كلمة cess او الأعام منها z للتعبير عن
+
+40
+00:03:34,040 --> 00:03:40,260
+معنى مع بعض و ال transاو ايه؟ ضد بعض واضح هذا
+
+41
+00:03:40,260 --> 00:03:43,860
+الكلام؟ الان لما أخذنا ال sis و ال trans قولنا
+
+42
+00:03:43,860 --> 00:03:47,840
+هدوله نوع او احد انواع ال stereo isomers اللي
+
+43
+00:03:47,840 --> 00:03:52,700
+سمناهم ايش؟ they are stereomersالان شو يعني
+
+44
+00:03:52,700 --> 00:03:56,980
+diastereomers ال diastereomers ببساطة قلنا عنهم
+
+45
+00:03:56,980 --> 00:04:00,660
+non mirror image stereoisomers يعني stereoisomers
+
+46
+00:04:00,660 --> 00:04:04,820
+لو حطيت واحد جبال التاني و تخيلت انه في امرأة
+
+47
+00:04:04,820 --> 00:04:09,460
+بينهم بيكونوا مش صورة بعض في المرأة non mirror
+
+48
+00:04:09,460 --> 00:04:14,500
+image stereoisomers الان موضوعنا في هذا الفصل على
+
+49
+00:04:14,500 --> 00:04:19,930
+النوع التاني يعني كل الكلام اللي اتكلمتهمقدمة لكن
+
+50
+00:04:19,930 --> 00:04:24,570
+موضوعنا على النوع التاني اللي اسمه enantiomers
+
+51
+00:04:24,570 --> 00:04:28,750
+النوع التاني اللي اسمه enantiomers ال enantiomers
+
+52
+00:04:28,750 --> 00:04:34,970
+قبل ما تكون ظاهرة موجودة في الكيميا و في ال stereo
+
+53
+00:04:34,970 --> 00:04:40,530
+isomers هي ظاهرة موجودة في الحياة ربما من تبهينها
+
+54
+00:04:40,530 --> 00:04:46,580
+الناس او لأالله أعلم لكن لما نذكرها و نفهمها
+
+55
+00:04:46,580 --> 00:04:51,200
+بالحياة بعد هيك بنقدر نفهمها بالكيميا يعني اللي
+
+56
+00:04:51,200 --> 00:04:56,280
+بده يفهم إيش معناه in and sumars بدوش يظن أن هذه
+
+57
+00:04:56,280 --> 00:05:00,840
+الكلمة هي كلمة كيميائية لأ كلمة in and sumars هي
+
+58
+00:05:00,840 --> 00:05:06,840
+كلمة حياتية يعني ممكن في الامتحان أرسمه to in and
+
+59
+00:05:06,840 --> 00:05:12,620
+sumarsمن الحياة لا بد يبين فيها روابط ولا بد يبين
+
+60
+00:05:12,620 --> 00:05:17,300
+فيها ذرات ولا جزيئات ولا ما يحزنون ال enantiomers
+
+61
+00:05:17,300 --> 00:05:22,700
+ظاهرة حياتية ايش اصل هذه الظاهرة اصل هذه الظاهرة
+
+62
+00:05:22,700 --> 00:05:29,710
+تنطلق من الإيدينلحظوا الإيد اليمين والإيد الشمال،
+
+63
+00:05:29,710 --> 00:05:34,930
+لو أنا حطيت هدول الاتين بهذا الشكل أقبال بعض،
+
+64
+00:05:34,930 --> 00:05:40,900
+هلاحظ أن هدول الاتين صورت بعض في المرقاةواضح؟ يعني
+
+65
+00:05:40,900 --> 00:05:44,920
+لو هنا في مراية بدل الإيد الشمال، إيش اللي هيبين
+
+66
+00:05:44,920 --> 00:05:49,960
+فيها؟ نفس هذه، لو كنت حاطط لشمال، لو في مراية، إيش
+
+67
+00:05:49,960 --> 00:05:54,160
+هيبين فيها نفس هذه؟ الآن صورة المرأة اللي احنا
+
+68
+00:05:54,160 --> 00:06:01,510
+سمناها mirror image سابقاإيش بتمتاز؟ إن كل نقطة
+
+69
+00:06:01,510 --> 00:06:06,910
+فيها عكس التاني عكس الأصل يعني أنا لما بحط الإيد
+
+70
+00:06:06,910 --> 00:06:12,290
+اتطلع على الكف اللي موجود عنده بأي اتجاه؟ بهذا
+
+71
+00:06:12,290 --> 00:06:17,830
+الاتجاه واضح؟ الآن هذا صورته في المرأة لوين؟
+
+72
+00:06:17,830 --> 00:06:21,710
+بالاتجاه المعاكس ولذلك لما الإنسان نفسه كمان بيقف
+
+73
+00:06:21,710 --> 00:06:27,710
+قدام المراية بشوف صورتهمعنى ذلك إن كل ما في المرأة
+
+74
+00:06:27,710 --> 00:06:32,450
+عكس الوضع اللي هو واقف الإنسان فيه، واضح؟ الآن إنه
+
+75
+00:06:32,450 --> 00:06:36,330
+ملقتين mirror image هذا أمر طبيعي، لأ وأمر طبيعي
+
+76
+00:06:36,330 --> 00:06:41,770
+أكثر إن كل شيء في الدنيا كل شيء في الدنيا له
+
+77
+00:06:41,770 --> 00:06:45,850
+mirror image، يعني هذا مش موضوع خلافي إطلاقا، يعني
+
+78
+00:06:45,850 --> 00:06:52,470
+لو جيبنا قدام المرايا حجرأو كرة أو أرنب أو بني آدم
+
+79
+00:06:52,470 --> 00:06:58,710
+أو ملك أو فقير وقفناه قدام المراية له mirror image
+
+80
+00:06:58,710 --> 00:07:03,470
+يعني بنقدر نصيغي الكلام for every object there is
+
+81
+00:07:03,470 --> 00:07:07,530
+a mirror imageكل جسم في الدنيا له mirror image
+
+82
+00:07:07,530 --> 00:07:11,890
+تمام؟ إذا بيصير وين الجديد؟ إذا كل إشي في الدنيا
+
+83
+00:07:11,890 --> 00:07:16,770
+له mirror image الآن بيجي الشيء الجديد اللي بينبني
+
+84
+00:07:16,770 --> 00:07:21,670
+عليه فهمنا لهذا ال chapter هل يا تورا الصورة في
+
+85
+00:07:21,670 --> 00:07:27,490
+المرآة تنطبق على الأصل ولا لأ؟يعني لو أنا إجيت
+
+86
+00:07:27,490 --> 00:07:32,170
+قولت ال .. ال tail هدولة they are mirror images هل
+
+87
+00:07:32,170 --> 00:07:37,430
+يا ترى هذه الإيد بتنطبق على هذه الإيد ولا لأ؟ معنى
+
+88
+00:07:37,430 --> 00:07:45,030
+تنطبق على super imposible super imposible
+
+89
+00:07:46,690 --> 00:07:51,710
+واضح؟ هل يا تورا الإيد اليمين و الإيد الشمال
+
+90
+00:07:51,710 --> 00:07:56,250
+بينطبقوا على بعض من بعض ولا لأ؟ إيش إنتوا رأيكم من
+
+91
+00:07:56,250 --> 00:08:03,770
+خبرتكوا الحياتية؟ كويس، الآن لاحظوا الشعب
+
+92
+00:08:03,770 --> 00:08:12,170
+الفلسطيني لأنه عاش طفولة صعبةلم يقدر له أن يستمتع
+
+93
+00:08:12,170 --> 00:08:19,410
+بطفولته ولذلك لم يستطع أن يجيب على سؤال بسيط مثل
+
+94
+00:08:19,410 --> 00:08:29,270
+هذا السؤال لو استمتعتنا بطفولتي كنا لعرفتنا إيش
+
+95
+00:08:29,270 --> 00:08:34,350
+أنه لما بنيجي نركب العروسة الصغيرة إلها التين
+
+96
+00:08:34,350 --> 00:08:40,380
+ماقدرش أحط هذه محل هذهالعروسة الصغيرة معمولة بتنفك
+
+97
+00:08:40,380 --> 00:08:44,940
+الاتين والرجلتين ولا لأ؟ لما بتيجوا تركبوها هذه
+
+98
+00:08:44,940 --> 00:08:48,220
+العروسة الصغيرة جسم اللي بيلعبوا فيها الأطفال
+
+99
+00:08:48,220 --> 00:08:53,900
+ويلها إيد وإيد ورجل ورجل هل يا تورا عمركوا جربتوا
+
+100
+00:08:53,900 --> 00:08:58,300
+وهي مفكوكة تركبوها تاني؟ هل بتيجي الإيد لشمال محل
+
+101
+00:08:58,300 --> 00:09:03,130
+اليمين؟ لأبالتأكيد لأ بنعكس الأصبع الآن تخيلوا أن
+
+102
+00:09:03,130 --> 00:09:06,950
+هذه الإيد اللي عندى اليمين لو أنا بدأ أحط الشمال
+
+103
+00:09:06,950 --> 00:09:10,790
+مكانها تماما و الكف لجوه بده يكون هاي بدأ أجيب
+
+104
+00:09:10,790 --> 00:09:15,270
+الشمال لحظوا هذا الأصبع وين رايح هذا الأصبع وين
+
+105
+00:09:15,270 --> 00:09:20,310
+رايح ولذلك لا يمكن لو إجيتوا تركبوا الرجلين محال
+
+106
+00:09:20,310 --> 00:09:26,130
+بعض هتلاحظوا أن رجل للأمام و رجل للخلف فالاتين
+
+107
+00:09:27,470 --> 00:09:31,670
+و كل كوا عندكم لسه ما زال من بقايا الطفولة شيء على
+
+108
+00:09:31,670 --> 00:09:38,280
+أرض الواقع أو في الذاكرة فجربوا .. فجربواالان ..
+
+109
+00:09:38,280 --> 00:09:43,500
+هذه الان بتصبح أساس لظاهرة .. بتصبح أساس لظاهرة
+
+110
+00:09:43,500 --> 00:09:50,020
+أنه في أحيانا الصورة في المرأة و الأصل يكونوا غير
+
+111
+00:09:50,020 --> 00:09:54,020
+متطابقين طبعا ممكن الصورة و الأصل تكون متطابقة
+
+112
+00:09:54,020 --> 00:10:00,380
+يعني لو إنسان مثلا جاب هذا القلمحطه هنا الصورة
+
+113
+00:10:00,380 --> 00:10:05,560
+تبعته جلم تاني هذه صورة هذا أصل ينطبق على بعض لو
+
+114
+00:10:05,560 --> 00:10:12,020
+الإنسان جاب كرةأيه كويس؟ حطها أمام المرآة، شو
+
+115
+00:10:12,020 --> 00:10:16,820
+هيشوف؟ كرة، الكورتين ينطبقوا مكان بعض، بمعنى آخر
+
+116
+00:10:16,820 --> 00:10:21,020
+لو كان فيه قالب محطوطة في الكورة هذه و قالب محطوطة
+
+117
+00:10:21,020 --> 00:10:23,800
+في الكورة الثانية، بقدر أحط هذه محل هذه و بقدر أحط
+
+118
+00:10:23,800 --> 00:10:29,000
+هذه محل هذه، لكن تخيلوا معي لو كان الإنسان بيشتري
+
+119
+00:10:29,000 --> 00:10:33,660
+عروسة صغيرة اللي بيلعبوا فيها، والاتنين محطوطين في
+
+120
+00:10:33,660 --> 00:10:39,730
+الجالب الكلكل المفحورهذه للإيد اليمين مفحورة جوا،
+
+121
+00:10:39,730 --> 00:10:44,410
+هذه للإيد التانية أرفع هذه الإيد، بيقدر يحط هذه
+
+122
+00:10:44,410 --> 00:10:48,690
+مكانها؟ مش ممكن، لحظوا هذه الفحر وين الأصبع جاي
+
+123
+00:10:48,690 --> 00:10:52,810
+فيها؟ بهذا الاتجاه، طبعا ما تحطوهاش بالعكس، معنى
+
+124
+00:10:52,810 --> 00:10:57,630
+التطابق أن كل نقطة تنطبق محل إيش؟ التانية، واضح؟
+
+125
+00:10:57,630 --> 00:11:02,060
+هل بنقدر نحط هذه محل هذه؟بنقدرش نحطهم محال بعض
+
+126
+00:11:02,060 --> 00:11:08,400
+الان هذه الظاهرة .. هذه الظاهرة لأنها أساس لأشياء
+
+127
+00:11:08,400 --> 00:11:12,980
+كتيرة أعطوها اسم في الكيميا سموها ظاهرة ايش ال
+
+128
+00:11:12,980 --> 00:11:21,380
+handedness ظاهرة ال handedness ظاهرة ال handedness
+
+129
+00:11:21,380 --> 00:11:28,200
+اللي هي عدم تطابق الأصل مع الصورة الان لو بدنا
+
+130
+00:11:28,200 --> 00:11:35,620
+أنصيهاباللغة الإنقليزية بدنا نقول بيكون عند non
+
+131
+00:11:35,620 --> 00:11:40,020
+-superimposable mirror image stereoisomers لاحظوا
+
+132
+00:11:40,020 --> 00:11:44,500
+معي non-superimposable غير متطابق non
+
+133
+00:11:44,500 --> 00:11:47,720
+-superimposable mirror image stereoisomers يعني
+
+134
+00:11:47,720 --> 00:11:53,760
+صور في المرأة غير متطابقة الأصل والصورة ايش ماله
+
+135
+00:11:53,760 --> 00:11:57,520
+غير متطابق non-superimposable غير متطابق mirror
+
+136
+00:11:57,520 --> 00:12:04,920
+imageصورة مع الأصل واضح الصورة لا تنطبق على الأصل
+
+137
+00:12:04,920 --> 00:12:12,060
+الان كل ما كان مثل الإيدين بنطبق عليه الظاهرة الان
+
+138
+00:12:12,060 --> 00:12:16,500
+كل شغلتين مثل الإيدين اعطوهم اسم سموهم enantiomers
+
+139
+00:12:16,500 --> 00:12:23,690
+فالاتين enantiomersواضح؟ فعلاقة الانانشومارز بلغة
+
+140
+00:12:23,690 --> 00:12:29,710
+بسيطة هي أصل وصورة في المرآة ولكنهم غير متطابقين
+
+141
+00:12:29,710 --> 00:12:33,790
+non superimposable mirror images أو mirror images
+
+142
+00:12:33,790 --> 00:12:40,350
+stereo isomers الآن أعطوني عد أمثلة من الحياة غير
+
+143
+00:12:40,350 --> 00:12:49,130
+الإتين الرجلتين صح الرجلتين برضه مش متطابقين وكمان
+
+144
+00:12:50,730 --> 00:12:54,870
+ابواب السيارة، لاحظوا لما بيخرب مثلا الباب الأمامي
+
+145
+00:12:54,870 --> 00:12:58,150
+في السيارة، الواحد بيروح باشتري باب، أول سؤال
+
+146
+00:12:58,150 --> 00:13:04,330
+بينسأله من البيبيع، بدك الباب شمال ولا يمين؟
+
+147
+00:13:04,330 --> 00:13:09,790
+كمان، إمريتين السيارة، الإمريات اللي على الجانب،
+
+148
+00:13:09,790 --> 00:13:12,870
+بيركبوا، في واحدة شمال، في واحدة يمين، مابيجيوش
+
+149
+00:13:12,870 --> 00:13:17,150
+التنتين محال بعض، كمان، لودان
+
+150
+00:13:18,370 --> 00:13:24,490
+واضح؟ كمان إذا شلحت هذه النضارة تخيلوا لو انت جزء
+
+151
+00:13:24,490 --> 00:13:29,200
+منكم درس بصريات طبية انت علوم صحة الآن صح؟هذه
+
+152
+00:13:29,200 --> 00:13:36,180
+النضارة مفكوكة هيكون عنده إيد و إيد و عدسة و عدسة
+
+153
+00:13:36,180 --> 00:13:41,000
+و هذا الجسم الصغير إله اسم انتعون النضارات تمام لو
+
+154
+00:13:41,000 --> 00:13:45,820
+فكتوهم و إجيتوا تركبوهم يعني بس بمفك صغير اشتغلتوا
+
+155
+00:13:45,820 --> 00:13:49,160
+على هذه النضارة هيصير عندكم من هذه قطعتين من هذه
+
+156
+00:13:49,160 --> 00:13:54,780
+قطعتين من هذه قطعتين تعالوا ركبوهم لو جربتوا تحطوا
+
+157
+00:13:54,780 --> 00:14:01,140
+هذه محل هذه و تركبوهم صح تطلع هذه لفوقواضح؟ و هاد
+
+158
+00:14:01,140 --> 00:14:04,600
+هتطلع على فوق، مش هيظبطه، لو جربتوا تحطوا العدسة
+
+159
+00:14:04,600 --> 00:14:08,580
+محل العدسة، مش هيظبط، لو جربتوا هاد محل هاد، مش
+
+160
+00:14:08,580 --> 00:14:13,400
+هيظبط، إذا كل هدولة، رغم إن أنا لو حطيت مرقابي هذا
+
+161
+00:14:13,400 --> 00:14:19,480
+الشكل، هذا الجزء و هذا الجزء، إيش معلهم؟صورة بعض
+
+162
+00:14:19,480 --> 00:14:23,660
+في المرأة صحيح صورة بعض في المرأة ولكنها غير
+
+163
+00:14:23,660 --> 00:14:28,820
+متطابقة إذا كل مكونات النضارة بيخضعوا لظاهرة إيش
+
+164
+00:14:28,820 --> 00:14:32,500
+ال handedness ال handedness كل مكونات النضارة in
+
+165
+00:14:32,500 --> 00:14:36,300
+anchomers يعني لو أنا جبتلكوا في الامتحان صورة إيد
+
+166
+00:14:36,300 --> 00:14:39,240
+النضارة هذه والإيد التانية وقلتلكوا ما العلاقة
+
+167
+00:14:39,240 --> 00:14:43,750
+بينهم بتقولولي they are anchomersواضح؟ they are
+
+168
+00:14:43,750 --> 00:14:49,850
+enantiomers الأحذية شو رأيكم فيهم؟ لاحظوا فكرة
+
+169
+00:14:49,850 --> 00:14:53,750
+الأحذية فكرة يعني مهمة عارفين ليش؟ لأن ال
+
+170
+00:14:53,750 --> 00:14:58,670
+enantiomers ببساطة للوهلة الأولى صعب أنكم تتميزوهم
+
+171
+00:14:58,670 --> 00:15:01,630
+وممكن تغلطوا فيهم أول ما بدنا أن تغلطوا في
+
+172
+00:15:01,630 --> 00:15:07,430
+الإيدين، مظبوط ولا لأ؟ الآن في المستقبل سواء
+
+173
+00:15:07,430 --> 00:15:10,750
+قابلته أو قابته
+
+174
+00:15:12,820 --> 00:15:17,720
+هتلاحظوا انه عشان الطفل الصغير اول ما بيبدأ يستعمل
+
+175
+00:15:17,720 --> 00:15:22,320
+الحذاء يفهم هذه الظاهرة بتضله حوالي اربع خمس ست
+
+176
+00:15:22,320 --> 00:15:24,540
+سنين لما هو بيجي يلبس الحذاء و انتوا قاعدينه
+
+177
+00:15:24,540 --> 00:15:28,600
+تقولوله شماله يمين طب هم اذا كانوا نفس الاشي ليش
+
+178
+00:15:28,600 --> 00:15:31,940
+مغلبين حالكوا و منشفين ريجها الطفل الصغير و
+
+179
+00:15:31,940 --> 00:15:39,080
+بتقولوله شماله يمين مؤمن الغلطان الطفل ولا انتوا
+
+180
+00:15:41,020 --> 00:15:45,120
+احنا بدنا نفهم الطفل لما بيجي بيلبس الحذاء مش ليه
+
+181
+00:15:45,120 --> 00:15:48,400
+لنهار الأب و الأم لأ هذي شمال، هذي يمين أول ما
+
+182
+00:15:48,400 --> 00:15:54,440
+بيبدأ؟ إذا عندكم قناعة أنه هذي و هذي مابيجوش مع
+
+183
+00:15:54,440 --> 00:16:02,740
+بعض، واضح؟ إذا الأحذية انان شمارز، الأحذية انان
+
+184
+00:16:02,740 --> 00:16:08,160
+شمارز أيضا، والجوارب انان شمارز، والشاطر اللي
+
+185
+00:16:08,160 --> 00:16:15,450
+بيعرف إيشيلبسهم صحي الظاهرة اشمالها كبيرة لاحظوا
+
+186
+00:16:15,450 --> 00:16:21,210
+معي وين بيبين اكثر اشي وين بيبين اكثر اشي ال
+
+187
+00:16:21,210 --> 00:16:26,970
+enantiomers عارفين وين لما ييجوا ال enantiomers
+
+188
+00:16:26,970 --> 00:16:31,430
+يتعاملوا مع enantiomers تاني وهذه فكرة كتير اساسية
+
+189
+00:16:31,430 --> 00:16:36,720
+في الكيميا يعني انتوا قلتوا القدمينEnhance
+
+190
+00:16:36,720 --> 00:16:40,440
+Shoemers يعني القدم اليمين و القدم الشمال صورة بعض
+
+191
+00:16:40,440 --> 00:16:44,960
+في المرأة ولكنها غير متطابقة صح ولا لأ؟ و الحذائن
+
+192
+00:16:44,960 --> 00:16:50,580
+Enhance Shoemers الآن أن الحذائن ممكن يستعملوا
+
+193
+00:16:50,580 --> 00:16:56,460
+استعمالات كتيرة مايفرجوش نهائيا يعني لو افترضنا
+
+194
+00:16:56,460 --> 00:17:01,100
+إنسان مثلا بيشتري خردة على الميزان بلاستيك عشان
+
+195
+00:17:01,100 --> 00:17:06,100
+يعملوا recyclingبيفرج معه إن هذا شمال ولا هذا
+
+196
+00:17:06,100 --> 00:17:13,800
+يمين؟ لأ، مظبوط ولا لأ؟ لو افترضنا إن إنسان بده
+
+197
+00:17:13,800 --> 00:17:20,440
+يستعمل الحذاء ليضرب به أعداء الله، صارت في
+
+198
+00:17:20,440 --> 00:17:25,440
+التاريخ، بيفرج معه إنه شمال ولا يمين؟ ولا جنب
+
+199
+00:17:25,440 --> 00:17:31,260
+الواجب؟جانب الواجب طيب السؤال عاد لو افترضنا انه
+
+200
+00:17:31,260 --> 00:17:36,480
+انسان بده يحط الرجلتين في الحذائل بيفرق معه ولا
+
+201
+00:17:36,480 --> 00:17:42,120
+لأ؟ وين افرقت؟ لما جبت انان شومارز مع انان شومارز
+
+202
+00:17:42,120 --> 00:17:45,960
+هذا الكلام بعد شوية وين هيجي يفرق معكم؟ لما ابدأ
+
+203
+00:17:45,960 --> 00:17:53,100
+انا اقول ان الجسم في أشياء مواد مستقبلات موجود
+
+204
+00:17:53,100 --> 00:17:59,210
+منها اتنينو الدواء موجود منه اتنين الان اذا اللي
+
+205
+00:17:59,210 --> 00:18:02,510
+في الجسم واحد هيجي على التنين اللي في الدواء اللي
+
+206
+00:18:02,510 --> 00:18:08,570
+هيتفق مع واحد و يختلف مع التاني هيكون اكثر تطبيق
+
+207
+00:18:08,570 --> 00:18:14,470
+لهذه المنطقة في ال biological system في الجسم لانه
+
+208
+00:18:14,470 --> 00:18:18,570
+هتبدو تلاحظوا ان الجزيئات الانزمات الكذا في منها
+
+209
+00:18:18,570 --> 00:18:23,390
+اتنينإنانشومارز والأدوية في منها إنانشومارز الآن
+
+210
+00:18:23,390 --> 00:18:28,790
+أي إنانشومارز أعطيه عشان يتفق مع اللي في الجسم هنا
+
+211
+00:18:28,790 --> 00:18:35,610
+بيصير إيش؟ بيصير الانتباه وأول ما الناس بتبدأ تغلط
+
+212
+00:18:35,610 --> 00:18:44,340
+مباشرة بتعمل إيش؟ مشكلة وصارت مشاكلضخمة جدا بل
+
+213
+00:18:44,340 --> 00:18:51,440
+مقاسي خليني في الأول أفرجيكم خلال فترة صغيرة كيف
+
+214
+00:18:51,440 --> 00:18:54,160
+هذه الظاهرة نفسها اللي قلنا ربع ساعة بنحكي عنها في
+
+215
+00:18:54,160 --> 00:18:57,900
+الحياة يمكن أن توجد في الكيميا وبعدين بنفرجيكم
+
+216
+00:18:57,900 --> 00:19:02,360
+المقاسي اللي موجودة من الخطأ في هذه الظاهرة في
+
+217
+00:19:02,360 --> 00:19:07,550
+المجال الطبي وغيرهالان هذه الظاهرة في الكيميا
+
+218
+00:19:07,550 --> 00:19:14,470
+بتوجد إذا كان في عندي جزيء في ذرة carbon تحمل أربع
+
+219
+00:19:14,470 --> 00:19:20,190
+مجموعات مختلفة واضح؟ يعني شرطها أن توجد carbon،
+
+220
+00:19:20,190 --> 00:19:25,730
+هاي ال carbon عندي تحمل كام مجموعة مختلفة؟ تحمل
+
+221
+00:19:25,730 --> 00:19:30,790
+أربع مجموعات مختلفة إذا وجدت، بعمل جزيء و صورته
+
+222
+00:19:30,790 --> 00:19:36,140
+خليني أتخيل، هاي carbonوبدي اعمل تحمل اربع مجموعات
+
+223
+00:19:36,140 --> 00:19:41,300
+مختلفة الان شايفينها بالالوان ولا لأ عشان نسهل على
+
+224
+00:19:41,300 --> 00:19:45,720
+حالنا و نفهم الموضوع ببساطة خليني اتخيل ان هذا
+
+225
+00:19:45,720 --> 00:19:52,200
+الكربون بتحمل يود ايش لون اليود في الدنيا ازرق و
+
+226
+00:19:52,200 --> 00:20:00,660
+كلور اخضر اخضر مصفر مظبوط ولا لأ و برومأحمر
+
+227
+00:20:00,660 --> 00:20:06,780
+بورتقالي أحمر بورتقالي إذا هذا الأزرق يود والأخضر
+
+228
+00:20:06,780 --> 00:20:11,920
+أكلور والأحمر إبروم اتخيلنا كأنا جزء الآن وهذا
+
+229
+00:20:11,920 --> 00:20:17,620
+هيدروجين طب الآن لو قلت لواحدة لو سمحت سمينا
+
+230
+00:20:17,620 --> 00:20:25,820
+المركب هذا اللي أنا ماسكه بإيدي شو هتسميه ذرد
+
+231
+00:20:25,820 --> 00:20:33,810
+كاربون واحدة بسرعةميتين؟ شو بتحمل؟مافيش غير الواحد
+
+232
+00:20:33,810 --> 00:20:41,350
+ما تقولوهوش إبرومو كلورو أيودو ميثيل و بنذكرهم
+
+233
+00:20:41,350 --> 00:20:45,530
+alphabetical مش هذي الف باقي التسمية يعني هذا
+
+234
+00:20:45,530 --> 00:20:50,690
+الجزيء لما تجيب الكياشو اسمه إبرومو كلورو أيودو
+
+235
+00:20:50,690 --> 00:20:55,550
+ميثيل في مشكلة لحد الآن؟ الآن لو عملت صورته في
+
+236
+00:20:55,550 --> 00:21:00,330
+المرقاة يعني مسكته زي هيك و جيبت كمان إبرومو
+
+237
+00:21:00,330 --> 00:21:01,170
+هيدروجيل
+
+238
+00:21:04,280 --> 00:21:09,440
+وعملت انتبهوا معي هدول التنين تماما صورة بعض في
+
+239
+00:21:09,440 --> 00:21:16,020
+المرأة ولا لأ واضح صورة بعض في المرأة مية في المية
+
+240
+00:21:16,020 --> 00:21:20,260
+طب لو قولنا له ده سميناها ده ده سميناها انت سميها
+
+241
+00:21:20,260 --> 00:21:21,320
+ده
+
+242
+00:21:26,260 --> 00:21:29,560
+برومو، كلورو، ايود وميثين برومو، كلورو، ايود
+
+243
+00:21:29,560 --> 00:21:33,660
+وميثين لاحظوا معي إجت الجملة العامة في تعريف ال
+
+244
+00:21:33,660 --> 00:21:36,900
+stereo isomers they have the same bonding يعني لو
+
+245
+00:21:36,900 --> 00:21:39,800
+واحدة هنا بتوصف هذا الجزء و واحدة هنا بتوصف هذا
+
+246
+00:21:39,800 --> 00:21:43,880
+الجزء هتقول carbon متصل في برومو، كلورو، يودو،
+
+247
+00:21:43,880 --> 00:21:48,490
+هيدروجين و اللي هناcarbon متصل فيه برومو كلورو
+
+248
+00:21:48,490 --> 00:21:53,250
+يودو هيدروجين اذا same bonding ولا لأ الان يا تورا
+
+249
+00:21:53,250 --> 00:21:57,550
+لو سألنا نفسنا السؤال هدول بينطبقوا على بعض ولا لأ
+
+250
+00:22:01,090 --> 00:22:08,270
+الخمسة درّات بدهم يجوا فوق بعض، الخمسة و لا في جنس
+
+251
+00:22:08,270 --> 00:22:11,130
+ال resonance، هذا وين ال resonance اللي فيه؟ ال
+
+252
+00:22:11,130 --> 00:22:15,270
+resonance حركة إلكترونات مافي أي resonance إطلاقا
+
+253
+00:22:16,410 --> 00:22:21,330
+الان معناه الانطباق انهم الخمس ذرات يجوا على بعض
+
+254
+00:22:21,330 --> 00:22:25,870
+خليني اجرب بده احط الكربون على الكربون زي هيك
+
+255
+00:22:25,870 --> 00:22:29,770
+خليني اجرب الان لاحظوا هاي الكربون اجت على الكربون
+
+256
+00:22:29,770 --> 00:22:39,510
+الكلور الهيدروجين اليو دولبروم شمالهم بالعكس اذا
+
+257
+00:22:39,510 --> 00:22:43,530
+لان مشكلتي باليو دولبروم بصلحها خليني اظبط اليو
+
+258
+00:22:43,530 --> 00:22:51,020
+دولبرومهيدروجين و هيدروجين هدولة
+
+259
+00:22:51,020 --> 00:22:54,220
+انطبقوا على بعض هدولة انطبقوا على بعض هدولة
+
+260
+00:22:54,220 --> 00:22:58,400
+انطبقوا على بعض صح؟ الان هدولة تنتيل كلورو
+
+261
+00:22:58,400 --> 00:23:06,920
+هيدروجين كلورو هيدروجين بينطبقوا؟ لا بينطبقواتمام؟
+
+262
+00:23:06,920 --> 00:23:11,060
+لو أعطناكم ياهم homework في البيت، هدول الجزيئين،
+
+263
+00:23:11,060 --> 00:23:15,780
+ضلينا نقولكوا معاكم عشر سنين، خليهم ينطبقوا على
+
+264
+00:23:15,780 --> 00:23:22,450
+بعض، لا ينطبقواواضح؟ إذا بدأت أكسر رابطتين و
+
+265
+00:23:22,450 --> 00:23:26,490
+أبدلهم هيصيروا نفس الجزء، هيبطلوا صورة بعض في
+
+266
+00:23:26,490 --> 00:23:31,370
+المرآة، هيصيروا نفس الجزء، واضح؟ لكن طالما هم صورة
+
+267
+00:23:31,370 --> 00:23:36,330
+بعض في المرآة، فغير متطابقين، إذا هذول أول مثال في
+
+268
+00:23:36,330 --> 00:23:40,110
+الكيميا على ال enantiomers و ال enantiomers بتوجد
+
+269
+00:23:40,110 --> 00:23:45,670
+لما يكون عند ذرة carbon تحمل أربع مجموعات مختلفة
+
+270
+00:23:46,540 --> 00:23:51,900
+واضح؟ إذا متى تصبح هذه الظاهرة موجودة في الكيمياء؟
+
+271
+00:23:51,900 --> 00:23:55,460
+إذا وجد عندي ذرّة كاربون تحمل أربع مجموعات مختلفة
+
+272
+00:23:55,460 --> 00:24:01,160
+الآن هذه الكاربون بنسميها كايرالكاربون إيش
+
+273
+00:24:01,160 --> 00:24:12,080
+بنسميها؟ كايرالكاربون أو stereogenic center أو
+
+274
+00:24:12,080 --> 00:24:19,630
+أحيانا كايرالسنتريعني هو يا مركز المشكلة أو مركز
+
+275
+00:24:19,630 --> 00:24:23,410
+الـ Stereochemistry بأي من هذه الأسماء شفتوها سواء
+
+276
+00:24:23,410 --> 00:24:26,910
+شفتوها chiral carbon أو chiral center أو
+
+277
+00:24:26,910 --> 00:24:33,290
+stereogenic center الفكرة فيها أن الكربون تحمل
+
+278
+00:24:33,290 --> 00:24:39,000
+أربع مجموعات مختلفةلحظة أنا بحبش أني أتعبكم في
+
+279
+00:24:39,000 --> 00:24:42,180
+صياغات لغوية the carbon carries four different
+
+280
+00:24:42,180 --> 00:24:46,780
+groups البفروض بس تفهموا كلمة إيش أربعة و بعدين زي
+
+281
+00:24:46,780 --> 00:24:51,340
+ما بيقول الشاعر و بكل لغات الأرض عبروا عنها المهم
+
+282
+00:24:51,340 --> 00:24:57,180
+إيش ذرة الكربون تحمل أربع مجموعات مختلفة فبصير
+
+283
+00:24:57,180 --> 00:25:02,620
+الشكل و صورته في المرأة غير متطابقين في هذه الحالة
+
+284
+00:25:02,620 --> 00:25:11,710
+صاروا إيشانانشومارز بدنا نميزهم عن بعض الان كل شيء
+
+285
+00:25:11,710 --> 00:25:18,910
+غير متطابق بلزم اننا ايش نميزه عن بعض بالمناسبة لو
+
+286
+00:25:18,910 --> 00:25:26,300
+انا سألت هذه ايش هتقولولي يدصح؟ وهذه يد، الان اليد
+
+287
+00:25:26,300 --> 00:25:33,880
+و اليد غير متطابقات، ايش ضفتلهم؟ كلمة يمنا و يسرا،
+
+288
+00:25:33,880 --> 00:25:40,110
+هذه عشان توضحهم بالفراغكيف بيجوا الان هذول
+
+289
+00:25:40,110 --> 00:25:47,090
+المركبين غير متطابقين اذا انا بحاجة لان اميزهم عن
+
+290
+00:25:47,090 --> 00:25:51,650
+بعضهم البعض يعني لو مجرد ان انا خربطته مع بعض كنت
+
+291
+00:25:51,650 --> 00:25:56,090
+حامل هذا المركب و خربطته مع بعض قلتلكوا اي مركب
+
+292
+00:25:56,090 --> 00:26:01,820
+كنت حامله باليمين و اي واحد بالاشمالهتعرفوه؟ اذا
+
+293
+00:26:01,820 --> 00:26:06,840
+لابد من طريقة لتمييزهم الان كيف بيميزوهم كيميائيا؟
+
+294
+00:26:06,840 --> 00:26:10,840
+بيقولوا تذكروا القواعد اللي أخدناها للأولويات في
+
+295
+00:26:10,840 --> 00:26:14,340
+المجموعات اللي أخدناها بالسلسة ال Trans ال يكان
+
+296
+00:26:14,340 --> 00:26:18,480
+انجلد بريلوج رولز اللي بتعتمد على ال atomic number
+
+297
+00:26:18,480 --> 00:26:21,500
+لما كنا نقول عند ال double bond مين أعلى؟ هذه ولا
+
+298
+00:26:21,500 --> 00:26:28,280
+هذه؟واضح الفكرة؟ الان صنف المجموعات اللى موجودة
+
+299
+00:26:28,280 --> 00:26:33,300
+حسب هذه القواعد من الأعلى للأقل في ال atomic
+
+300
+00:26:33,300 --> 00:26:39,320
+numbers الان تذكروا اللى عندي هيدروجين و كلور و
+
+301
+00:26:39,320 --> 00:26:45,440
+بروميود من أعلى واحدة؟بعدها البروم وبعدها الكلور
+
+302
+00:26:45,440 --> 00:26:49,400
+وبعدها الهيدروجين كلكوا متذكرين انه كان عنده ال
+
+303
+00:26:49,400 --> 00:26:53,300
+floriclor, البروم, اليود و الهيدروجين هان في
+
+304
+00:26:53,300 --> 00:26:55,880
+الجدول الدوري اذا اليود اعلى من البروم اعلى من
+
+305
+00:26:55,880 --> 00:27:00,760
+الكلور اعلى من الهيدروجين هذا في خلاف ولا لأ؟ لأ
+
+306
+00:27:00,760 --> 00:27:06,160
+الان بمسك الجزء بهذا الشكل بخلي المجموعة الأقل
+
+307
+00:27:06,160 --> 00:27:11,680
+الخلفالان انا هنا خلّيت المجموع الأقل للخلف منكم و
+
+308
+00:27:11,680 --> 00:27:16,840
+مني كمان ايش المجموع الأقل الهيدروجين خلوها للخلف
+
+309
+00:27:16,840 --> 00:27:28,460
+و اتحركوا من الأعلى للأقل للأقل واحدة تتحرك كيف
+
+310
+00:27:28,460 --> 00:27:35,820
+تكون الحركة مع قرب الساعة clockwise طب لو عملت
+
+311
+00:27:35,820 --> 00:27:41,800
+الكلام في الجزء التانييعني خلّيت أقل مجموعة
+
+312
+00:27:41,800 --> 00:27:49,780
+الهيدروجين للخلف و تحركوا يود .. عكس عقارة عكس
+
+313
+00:27:49,780 --> 00:27:58,660
+عقارة بالساعة صار في فرق بين التلات كيف؟
+
+314
+00:28:03,590 --> 00:28:11,830
+الان صار المطلوب يهدى ان هذا الجزء ابرومو كلورو
+
+315
+00:28:11,830 --> 00:28:17,630
+ايودو ميثين اللى معه قريب الساعةاتبهي معاك و هذا
+
+316
+00:28:17,630 --> 00:28:23,730
+الجزء برومو كلورو ايودو ميثين اللي ضد عقارب الساعة
+
+317
+00:28:23,730 --> 00:28:28,010
+الان شوف الكيميائيين جداش لطيفين و محترمين و سهلين
+
+318
+00:28:28,010 --> 00:28:32,910
+بدل ما ييجي يقولك كبشة كلامها الجد اجبال الاسم
+
+319
+00:28:32,910 --> 00:28:39,230
+اللي مع عقارب الساعة كام كلمة اربعة استبدالهم بحرف
+
+320
+00:28:39,230 --> 00:28:40,810
+جال اكتبله R
+
+321
+00:28:44,120 --> 00:28:50,200
+و هذا اللي ضد عقارب الساعة استبدله بحرف جال و
+
+322
+00:28:50,200 --> 00:28:54,280
+اكتبله S R
+
+323
+00:28:54,280 --> 00:29:03,400
+capital R و capital ايش S صار عندي R و S ال R
+
+324
+00:29:03,400 --> 00:29:10,200
+معناها clockwise و ال S counter clockwise
+
+325
+00:29:14,800 --> 00:29:20,020
+يعني مع و ضد عقارب الساعة هدول جايين من اللاتيني
+
+326
+00:29:20,020 --> 00:29:26,520
+rectus و sinister يعني أصل ال R من rectus
+
+327
+00:29:26,520 --> 00:29:31,380
+اللاتينية يعني يمين هيك مع عقارب و هذه sinister
+
+328
+00:29:31,380 --> 00:29:39,520
+يعني أصل الكلمة من إيش من اللاتيني الآن صار الإسم
+
+329
+00:29:39,520 --> 00:29:43,260
+الكامل لهذا لو جبته في الامتحان الإسم الكامل
+
+330
+00:29:43,260 --> 00:29:48,720
+الصحيحأي واحد في يوميك أخلطهم أخلطهم أنتوا مش
+
+331
+00:29:48,720 --> 00:29:52,640
+شايفين إشي و بعد ما خلطت و اتعبت قولتلها واحدة
+
+332
+00:29:52,640 --> 00:29:59,780
+سميلي هذا المركب طبعا هي عشان تاخد الأربع علامات
+
+333
+00:29:59,780 --> 00:30:02,460
+من خمسة في الأول بتجيب اسم الكيميا العادى
+
+334
+00:30:06,770 --> 00:30:09,690
+Ibromochloroiodomethane الان اخدت اربعة او تلاتة
+
+335
+00:30:09,690 --> 00:30:14,150
+من خمسة بعدين اربع مجموعات مختلفة اذا يجب مباشرة
+
+336
+00:30:14,150 --> 00:30:19,190
+انها تتحول على ال R و ال S اتطلع عليه سكنه اليود
+
+337
+00:30:19,190 --> 00:30:26,970
+Ibromichlor عكس اذا هذا صار اسمه الكامل S Ibrom و
+
+338
+00:30:26,970 --> 00:30:32,960
+هذا صار اسمه الكامل R فال S و ال Rهي بادئة لتوضيح
+
+339
+00:30:32,960 --> 00:30:37,800
+إيش؟ الشكل الفراغي تماما زي ما كان عندى في
+
+340
+00:30:37,800 --> 00:30:42,940
+الدياستيريو مارز إيش ال sis و ال trans و ال z و ال
+
+341
+00:30:42,940 --> 00:30:47,320
+E متذكرين لما احنا كنا نقول one two dichloroethane
+
+342
+00:30:47,320 --> 00:30:51,340
+و التاني نفس الاسم بدي أميزهم في الدياستيريو مارز
+
+343
+00:30:51,340 --> 00:31:00,320
+شو كنت بستعمل؟Sis و Trans او Z و E هذه البادئات
+
+344
+00:31:00,320 --> 00:31:07,340
+ايش بتوضح ليه؟ شكل فراغي الان في الانانشو مارز ROS
+
+345
+00:31:07,340 --> 00:31:14,980
+واضح؟ في الانانشو مارز ROS شوية في ال biochemistry
+
+346
+00:31:14,980 --> 00:31:18,900
+هيستعملوا مصطلحات تانية مبنية على نفس الفكرة
+
+347
+00:31:18,900 --> 00:31:21,180
+هتصيروا تشوفوا DOL
+
+348
+00:31:23,400 --> 00:31:28,660
+لما ابتصلوا لل biochemistry للبروتينات و الأشياء
+
+349
+00:31:28,660 --> 00:31:33,200
+اللي زي هيك هتلاحظوا و ال sugars بستعملوا D و L
+
+350
+00:31:33,200 --> 00:31:37,440
+بديل عن R و S تاريخيا لكن نفس الفكرة في حينه
+
+351
+00:31:37,440 --> 00:31:42,380
+بتدرسوها ف ال D و L أو ال R و ال S طبعا الأساس
+
+352
+00:31:42,380 --> 00:31:46,990
+الأعم و الأشمل و الأصل في الكيميا اللي هو إيش؟الـR
+
+353
+00:31:46,990 --> 00:31:49,170
+والـS يعني دي والأول استعمالات شويه في ال
+
+354
+00:31:49,170 --> 00:31:53,710
+biochemistry الـR والـS يستعملوا لتمييز ال
+
+355
+00:31:53,710 --> 00:31:57,910
+enantiomers عن بعضها البعض والعملية البسيطة
+
+356
+00:31:57,910 --> 00:32:04,900
+المجموعة الأقل أين توجدللخلف المجموع الأقل للخلف
+
+357
+00:32:04,900 --> 00:32:10,660
+وباقي المجموعات بنتحرك فيها من الأعلى للأقل حسب
+
+358
+00:32:10,660 --> 00:32:14,420
+قواعد الأولويات اللي أخدناها لإي اسمها Ken Ingold
+
+359
+00:32:14,420 --> 00:32:19,760
+Prelog Rules وبالتالي يحدد المركب هل هو R أو هو
+
+360
+00:32:19,760 --> 00:32:25,260
+إيش S وإلى لقاء آخر
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s.srt
new file mode 100644
index 0000000000000000000000000000000000000000..40b1fc11085db0d4903981a73ca1836e272b89c8
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s.srt
@@ -0,0 +1,1546 @@
+
+1
+00:00:19,640 --> 00:00:24,180
+بسم الله الرحمن الرحيم موضوعنا اليوم عن عائلة 
+
+2
+00:00:24,180 --> 00:00:28,620
+كيميائية جديدة مجموعة وظيفية جديدة اللي هي ال 
+
+3
+00:00:28,620 --> 00:00:34,460
+ethers طبعا على طول عدد كبير منكم هيتذكر ان ال
+
+4
+00:00:34,460 --> 00:00:40,460
+ethers اللي هم الصيغة العامة ROR يعني Oxygen 
+
+5
+00:00:40,460 --> 00:00:47,150
+محصورة بين ذرتين أو Oxygen بين مجموعتين R وكلكم 
+
+6
+00:00:47,150 --> 00:00:53,550
+اتذكرين ان ال Oxygen رابطتين وزوجين إيش؟ إلكترونات
+
+7
+00:00:53,550 --> 00:00:59,950
+ولذلك احنا غير ال ethers مر علينا شغلتين أبسط من 
+
+8
+00:00:59,950 --> 00:01:04,390
+ال ethers مر علينا شغلتين أبسط من ال ethers شو هم 
+
+9
+00:01:04,390 --> 00:01:11,100
+الآن؟ مين يذكرنا فيهم؟ الماء والكحول الان الماء
+
+10
+00:01:11,100 --> 00:01:16,260
+أكسوجينة أيضًا و الكحول أكسوجينة و ال ether برضه
+
+11
+00:01:16,260 --> 00:01:21,080
+ذرة أكسوجين و زوجين الإلكترونات هدوله مافيش مفار 
+
+12
+00:01:21,080 --> 00:01:31,320
+منهم لكن الميه كانت H H الكحول R و H يعني مازال 
+
+13
+00:01:31,320 --> 00:01:37,840
+فيه H ال ether R و R الان لاحظوا بمنطق ال hydrogen
+
+14
+00:01:37,840 --> 00:01:43,740
+bonding الان الميه تنتين hydrogen bonding الكحول 
+
+15
+00:01:43,740 --> 00:01:48,080
+من جهة واحدة بتقدر تعمل hydrogen bonding ال ether 
+
+16
+00:01:48,080 --> 00:01:52,660
+مافيش hydrogen bonding و بناء على ذلك الان لو بدنا 
+
+17
+00:01:52,660 --> 00:01:57,660
+نحكي بمنطق ال polarity من أعلى polarity فيهم الميه 
+
+18
+00:01:57,660 --> 00:02:02,080
+بعدها الكحول بعدها ال ether الان ال polarity 
+
+19
+00:02:02,080 --> 00:02:07,340
+مباشرة بتنعكس على إيش على أي خاصية فيزيائية؟ على 
+
+20
+00:02:07,340 --> 00:02:11,460
+درجة الغليان ولذلك على الضغط العادى الميه درجة 
+
+21
+00:02:11,460 --> 00:02:17,640
+غليانها 100 الكحول 78 ال ether لو افترضنا اثل و 
+
+22
+00:02:17,640 --> 00:02:22,080
+اثل حوالي 37 
+
+23
+00:02:23,430 --> 00:02:30,190
+لاحظوا كيف تناسب نقاط الغليان مع القطبية و لو كان 
+
+24
+00:02:30,190 --> 00:02:33,950
+ال ether die مثل ether يعني مثل أو مثل بيصير غاز
+
+25
+00:02:33,950 --> 00:02:38,930
+يعني درجة غليانه أقل بكتير ولذلك على حرارة الغرفة 
+
+26
+00:02:38,930 --> 00:02:45,510
+غلي و خلص و صار إيش موجود على شكل غاز الآن ربما من 
+
+27
+00:02:45,510 --> 00:02:48,790
+أشهر ال ether هذا ال ether ال ethyl o ethyl اللي 
+
+28
+00:02:48,790 --> 00:02:53,670
+هو ال diethyl ether واضح؟ ليش هذا يستعمل ك solvent 
+
+29
+00:02:53,670 --> 00:02:58,670
+مدير سابقا استعمل في التخدير لما كانوا مثلا 
+
+30
+00:02:58,670 --> 00:03:01,850
+بيخدروا حيوانات صغيرة بيعملوا تجارب في المختبرات 
+
+31
+00:03:01,850 --> 00:03:06,930
+فال ether they have been used as anesthetics الآن 
+
+32
+00:03:06,930 --> 00:03:11,720
+لو بدنا ننسى هدول الأشياء اللي احنا سبق اننا 
+
+33
+00:03:11,720 --> 00:03:17,820
+أخذناهم و نضلنا امركزين حالنا في ال ethers و هي
+
+34
+00:03:17,820 --> 00:03:22,980
+المثال عنهم اللي هو diethyl ether و ممكن نسميه
+
+35
+00:03:22,980 --> 00:03:26,540
+ethyl ether يعني لو لغينا كلمة ethyl، die، بمشي 
+
+36
+00:03:26,540 --> 00:03:32,140
+يعني diethyl ether و ethyl ether نفس الشيء لحظوا 
+
+37
+00:03:32,140 --> 00:03:36,440
+لما بنقول من خواصه much less polar than alcohols
+
+38
+00:03:37,210 --> 00:03:40,210
+الكلام صحيح ولا لأ؟ مافيش فيه hydrogen bonding
+
+39
+00:03:40,210 --> 00:03:44,130
+بالمرة لما نقول من خواصه not soluble in water
+
+40
+00:03:44,130 --> 00:03:49,430
+مافيش فيه solubility لأن هذه are groups كلها مافيش 
+
+41
+00:03:49,430 --> 00:03:52,510
+فيه hydrogen bonding اللي يصير polar و like، 
+
+42
+00:03:52,510 --> 00:03:56,730
+dissolves، like، له lower melting point و boiling
+
+43
+00:03:56,730 --> 00:04:01,130
+point أو boiling temperatures than alcohol أكيد صح 
+
+44
+00:04:03,220 --> 00:04:08,200
+كمان بضيف عليه شغلة chemically inert يعني خامل 
+
+45
+00:04:08,200 --> 00:04:14,940
+كيميائيا تفاعلاته قليلة جدا ولذلك ان شاء الله بأمل
+
+46
+00:04:14,940 --> 00:04:18,900
+كل أمل ان نخلص كل ال chapter اليوم لانه لما نحكي
+
+47
+00:04:18,900 --> 00:04:21,560
+عن ال kings و ال quills بنحكي على عشرين تفاعل على
+
+48
+00:04:21,560 --> 00:04:28,180
+ال ethers بنحكي على تفاعل واحد واضح؟لأنه مافيش من 
+
+49
+00:04:28,180 --> 00:04:32,340
+خلال MH و لا OH و لا C double bond O و لا double
+
+50
+00:04:32,340 --> 00:04:35,760
+bond هذي المجموعات اللي بنسميها active groups اللي
+
+51
+00:04:35,760 --> 00:04:39,460
+بتيم عليها تفاعلات كتيرة هذا الكلام مش متوفر وين
+
+52
+00:04:39,460 --> 00:04:44,380
+في ال ethers يضاف إلى ذلك all are very flammable 
+
+53
+00:04:45,250 --> 00:04:50,010
+يعني باشتعلوا بشكل سريع جدا زي بنزين السيارات و
+
+54
+00:04:50,010 --> 00:04:54,950
+وقود السيارات أو ربما كمان أكثر ولذلك ادمجوا
+
+55
+00:04:54,950 --> 00:05:00,090
+الشغلتين مع بعض ان هو له نقطة غليان منخفضة يعني 
+
+56
+00:05:00,090 --> 00:05:07,230
+بتبخر بسهولة و قابل للاشتعال بشكل كبير واضح؟ ولذلك
+
+57
+00:05:07,230 --> 00:05:11,770
+يمثل خطر في المختبر يعني نفترض ان حد عنده بنزين
+
+58
+00:05:11,770 --> 00:05:15,630
+burner مولعة هنا و قاعد بيشتغل و هنا فيه وعاء فيه 
+
+59
+00:05:15,630 --> 00:05:19,610
+ether مفتوح ال ether نفسه بتبخر سبعة و تلاتين احنا 
+
+60
+00:05:19,610 --> 00:05:23,170
+مرات في غزة الحرارة سبعة و تلاتين طبعا هو بتبخر 
+
+61
+00:05:23,170 --> 00:05:27,030
+على كل الدرجات و كل ما ارتفعت الحرارة بتزيد التبخر 
+
+62
+00:05:27,030 --> 00:05:32,020
+ولذلك ممكن و ال ether هنا و فيناعرف مكان تاني it
+
+63
+00:05:32,020 --> 00:05:36,000
+can catch fire زي ما بيسموه يعني ممكن يشتعل و يعمل
+
+64
+00:05:36,000 --> 00:05:41,060
+حريق فالتعامل مع ال ether بحاجة إلى حذر لأن هو 
+
+65
+00:05:41,060 --> 00:05:46,440
+very flammable و له نقطة غليان منخفضة يعني بينوجد
+
+66
+00:05:46,440 --> 00:05:51,500
+.. بيتبخر واضح؟ تماما زي التعامل مع وقود السيارات
+
+67
+00:05:51,500 --> 00:05:56,240
+أو مع التنر هذه المركبات الكيميائية بحاجة إلى نوع 
+
+68
+00:05:56,240 --> 00:06:04,050
+من الحذر الشديد الآن كيف بنسمي ال ethers؟ في إنا 
+
+69
+00:06:04,050 --> 00:06:08,670
+نظامين للتسمية نظام الشائع ال common nomenclature 
+
+70
+00:06:08,670 --> 00:06:12,710
+إن أنا أذكر المجموعات و دائما المجموعة بتاخد 
+
+71
+00:06:12,710 --> 00:06:17,990
+النهاية YL مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+72
+00:06:17,990 --> 00:06:20,470
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+73
+00:06:20,470 --> 00:06:26,330
+مثل مثل مثل مثل مثل مثل
+
+74
+00:06:26,330 --> 00:06:26,970
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل 
+
+75
+00:06:26,970 --> 00:06:30,750
+مثل مثل مثل مثل مثل بقول die ethyl ether و ممكن
+
+76
+00:06:30,750 --> 00:06:35,210
+تلاقوها ethyl ether يعني تختصر ال die مثل و مثل، 
+
+77
+00:06:35,210 --> 00:06:41,030
+die مثل ether فنل و فنل، die فنل ether الان طب لو 
+
+78
+00:06:41,030 --> 00:06:44,450
+كان هذا ال ether اللاحظه اللي زي بعض المجموعتين
+
+79
+00:06:44,450 --> 00:06:48,110
+يعني نتخيله زي هيك هي هذه ال oxygena وهنا
+
+80
+00:06:48,110 --> 00:06:53,920
+المجموعتين زي بعض هذا بنسميه Symmetric Ether متماثل
+
+81
+00:06:53,920 --> 00:06:59,700
+طب لو يختلفوا Unsymmetric Ether الآن واجهت أذكر
+
+82
+00:06:59,700 --> 00:07:04,840
+المجموعتين alphabetically يعني Ether فيه إثل و مثل
+
+83
+00:07:04,840 --> 00:07:13,080
+إيش هسميه إثل مثل إثر إبروبل مثلا و تيرتشار بيوتل 
+
+84
+00:07:14,280 --> 00:07:27,560
+ترتشير بيوتل بروبل إيثار ترتشير
+
+85
+00:07:27,560 --> 00:07:28,240
+بيوتل بروبل إيثار ترتشير بيوتل بروبل إيثار ترتشير
+
+86
+00:07:28,240 --> 00:07:33,600
+بيوتل بروبل إيثار ترتشير بيوتل بروبل إيثار
+
+87
+00:07:39,540 --> 00:07:45,680
+بتكونش تعجزوا ال ether معناه ذرة أكسوجين طالع
+
+88
+00:07:45,680 --> 00:07:49,940
+منها رابطة تل لكن الشطارة في اللي بيكون حفظ 
+
+89
+00:07:49,940 --> 00:07:57,840
+المجفوعات الآن ال tertiary butylcarbon عليها تلاتة
+
+90
+00:07:57,840 --> 00:08:04,700
+مثل أخذناها وال isopropyl carbon CH متصلة باتنين 
+
+91
+00:08:04,700 --> 00:08:11,280
+مثل زي هيك المحافظة على هذه الشغلة من الأول هذا 
+
+92
+00:08:11,280 --> 00:08:18,320
+دلبو واضح فهي tertiary butyl isopropyl ether احنا
+
+93
+00:08:18,320 --> 00:08:22,560
+قلنا تيرتشاري بيوتل بنعملها على حرف ال بي هذا لما
+
+94
+00:08:22,560 --> 00:08:27,140
+شرحنا المجموعات اذا شفنا كيف بنعمل ال ethers كذلك
+
+95
+00:08:27,140 --> 00:08:31,380
+الحالة لو قلنا الكوفينيل مثلا إيش بدنا نحط البنزين
+
+96
+00:08:31,380 --> 00:08:32,300
+المخصوم منها 
+
+97
+00:08:42,010 --> 00:08:47,110
+وهاي هذه أمثلة die methyl ether اثل مثل اثر زي ما
+
+98
+00:08:47,110 --> 00:08:50,810
+قولت مرات بيحطهم مش مرتبين alphabetical لكن الأصح
+
+99
+00:08:50,810 --> 00:08:55,090
+تحطهم alphabetical يعني زي هذا الأصح تكتبوه اثل
+
+100
+00:08:55,090 --> 00:09:00,110
+مثل اثر خلو ال E قبل ال M هذا ال ether هذه ال
+
+101
+00:09:00,110 --> 00:09:07,410
+CH2Cl اسمها كلوروميثل CH2Cl كلوروميثل وهنا اثل اثل
+
+102
+00:09:07,410 --> 00:09:15,930
+اثل Ether وهكذا هذه التسمية هي ال common 
+
+103
+00:09:15,930 --> 00:09:21,070
+nomenclature الان لاحظوا معاك شرط هذه التسمية شرط
+
+104
+00:09:21,070 --> 00:09:24,730
+هذه التسمية ان المجموع اللي هان و اللي هان يكون 
+
+105
+00:09:24,730 --> 00:09:28,010
+لهم اسماء معروفة بالنسبة لنا و المجموعات اللي
+
+106
+00:09:28,010 --> 00:09:31,810
+أخذناها ايجليلا مثل إيثل بروبل ايزوبروبل تيرتشر
+
+107
+00:09:31,810 --> 00:09:38,800
+بيوتل لحجناها انا بكلورو مثل .. بنل مثلا ب ..أقل 
+
+108
+00:09:38,800 --> 00:09:46,290
+ال ether لو قلنا لكم اعملوه يعني شغلات إيش معروفة
+
+109
+00:09:46,290 --> 00:09:51,030
+طيب الان لو المركب كبر وفي ايثر ايثر معناه
+
+110
+00:09:51,030 --> 00:09:55,610
+أكسوجينة بين كربونتين واجيتها بدي ارجع اسم المركب
+
+111
+00:09:55,610 --> 00:10:02,770
+كأنه ال cane عادي ابحث عن اطول سلسلة اطول سلسلة 
+
+112
+00:10:02,770 --> 00:10:08,310
+تلاتة مركبة بروبين اربعة بيوتين خمسة بنتين و هكذا 
+
+113
+00:10:08,310 --> 00:10:13,780
+طيب بعد ما اطول اطول سلسلة يعني هاي هذا مركب لاحظوا 
+
+114
+00:10:13,780 --> 00:10:17,180
+هنا في carbon تنتين تلاتة لبروبل و هنا carbon 
+
+115
+00:10:17,180 --> 00:10:21,920
+واحدة إيش أطول السلسلة لبروبل الآن تخيل لو هذا 
+
+116
+00:10:21,920 --> 00:10:26,580
+الأزرق اللي هنا كانت Cl لكلور اللي على موقع واحد 
+
+117
+00:10:26,580 --> 00:10:33,420
+إيش هتسموه المركب و إن كلورو بروبل بدكوا تحددوا
+
+118
+00:10:33,420 --> 00:10:38,620
+الرقم الان اللي على موقع واحد مش كلور او مثل ال أو 
+
+119
+00:10:38,620 --> 00:10:40,780
+مثل اللي لها اسم مثوكسي 
+
+120
+00:10:43,660 --> 00:10:52,760
+مثل ا ا مثوكسي طب لو كانت ا اثل اثوكسي لو كانت ا 
+
+121
+00:10:52,760 --> 00:10:57,660
+فنل مثوكسي
+
+122
+00:10:57,660 --> 00:11:04,080
+مثل ا اثوكسي اثل
+
+123
+00:11:04,080 --> 00:11:10,420
+افنوكسي فنل افروبوكسي 
+
+124
+00:11:13,650 --> 00:11:22,270
+هيبروبيل او ابيوتكسي ابيوتل او and so on واضح
+
+125
+00:11:22,270 --> 00:11:27,350
+فبنطول أطول سلسلة وبعدين المجموعات بنسميها يعني
+
+126
+00:11:27,350 --> 00:11:31,190
+مثلا هذا المركب هاي كاربون تنتين أطول سلسلة إذا 
+
+127
+00:11:31,190 --> 00:11:37,540
+المركب إيش إيثان على نمرة واحد إيش عليه؟أو مثل 
+
+128
+00:11:37,540 --> 00:11:43,040
+مثوكسي و إيش عليه كمان اكلور إذا هذا one chloro
+
+129
+00:11:43,040 --> 00:11:49,840
+one methoxy اثان هاي هذا المركب carbon 234 بيوتين 
+
+130
+00:11:49,840 --> 00:11:56,560
+على نمره اتنين إيش عليه تلت ذرات معه بروبوكسي 
+
+131
+00:11:56,560 --> 00:12:02,810
+بروبوكسي تلت ذرات معه هذا المركب لاحظوا إيثانول ال
+
+132
+00:12:02,810 --> 00:12:07,230
+alcohol أقوى من ال ether هنقول عنه واحد اتنين 
+
+133
+00:12:07,230 --> 00:12:12,330
+تلاتة اربعة إذا هذا أي مركب واند يوتانول ضال على 
+
+134
+00:12:12,330 --> 00:12:17,990
+نمره تلاتة شو المجموعة اللي حملها؟مش اتوكسي كلور و
+
+135
+00:12:17,990 --> 00:12:23,730
+اتوكسي تمام حملة كلور الان الكلور هذه محمولة على
+
+136
+00:12:23,730 --> 00:12:27,510
+الكربون هذه ولا هذه تعون ال organic بيحطوها بين 
+
+137
+00:12:27,510 --> 00:12:31,550
+جسين و بيقولوا الكلور على الكربون رقم اتنين لاحظوا
+
+138
+00:12:31,550 --> 00:12:36,490
+اتنين يعني كأنه كل هذه انحطت إيش بين جسين صار كام 
+
+139
+00:12:36,490 --> 00:12:40,410
+نظام ترقيم عندي نظامين النظام الاصلي واحد اتنين 
+
+140
+00:12:40,410 --> 00:12:43,890
+تلاتة اربعة و هنا الكلور لو اجتها انا بدي اقول one
+
+141
+00:12:43,890 --> 00:12:49,570
+prime إكلورو إيثوكس لو إجت هنا two prime إكلورو
+
+142
+00:12:49,570 --> 00:12:52,890
+إيثوكس و مرات بتلاحظون ممكن يختصروا ال prime لكن 
+
+143
+00:12:52,890 --> 00:12:59,190
+الأحسن إذا الإنسان استعمل أكثر من نظام ترقيم أنه
+
+144
+00:12:59,190 --> 00:13:05,070
+يحط إيش ل prime واضح هذه الفكرة بدي أركز معاكوا 
+
+145
+00:13:05,070 --> 00:13:12,140
+عليها فكرة أن الإنسان يستعمل أكثر من نظام ترقيم في 
+
+146
+00:13:12,140 --> 00:13:15,980
+نفس المُركّب خلّيني أعطيكوا عليها مثالين عند 
+
+147
+00:13:15,980 --> 00:13:20,460
+اللزوم ممكن مثال من موضوعنا الـ Ethers و مثال من 
+
+148
+00:13:20,460 --> 00:13:27,920
+موضوع الـ H تاني يعني الترقيم ممكن نستعمل أكثر من 
+
+149
+00:13:27,920 --> 00:13:35,300
+نظام ترقيم لو يا تورا أعطيتكم المُركّب هذا و 
+
+150
+00:13:35,300 --> 00:13:44,270
+كتبت هنا OH و كتبت هنا Z و حطينا هنا PR نفترض هذا 
+
+151
+00:13:44,270 --> 00:13:50,710
+المركب جاينا سمى المركب التالي الآن هذا أفضل شيء
+
+152
+00:13:50,710 --> 00:13:57,590
+أسميه كالكين واضح؟ أطول سلسلة و أطول سلسلة حاملة 
+
+153
+00:13:57,590 --> 00:14:06,330
+OH إذا هكسانول الان ال all عشان تكون أقل ترقيم 1,2
+
+154
+00:14:06,330 --> 00:14:12,190
+,3,4,5,6 إذا هذا لو ماكنش عليه هذه الإضافة اللي
+
+155
+00:14:12,190 --> 00:14:20,110
+موجودة هنا إيش هتسموه two hexanol واضح؟ الآن ال
+
+156
+00:14:20,110 --> 00:14:27,310
+two تاب على ترقيم إيش؟ طب على ترقيم السلسلة لو هذه 
+
+157
+00:14:27,310 --> 00:14:33,870
+إجت بنزينة كان كل كشاطرين four phenyl two hexanol 
+
+158
+00:14:33,870 --> 00:14:39,030
+مش هتتغلبوا فيها لو هذه بنزينة هي four phenyl two
+
+159
+00:14:39,030 --> 00:14:45,010
+hexanol الآن إجت عليها بروم طبعا هذه موجودة وين؟
+
+160
+00:14:45,010 --> 00:14:48,150
+على four و هي ال four هذا اللي هو الرقم اللي هنا 
+
+161
+00:14:48,150 --> 00:14:57,370
+لكن هي بالظبطاه اعملوا ترقيم تاني three 
+
+162
+00:14:57,370 --> 00:15:03,090
+bromophenyl صارت واضحة الفكرة؟ اه three
+
+163
+00:15:03,090 --> 00:15:06,270
+bromophenyl
+
+164
+00:15:06,270 --> 00:15:09,470
+three
+
+165
+00:15:09,470 --> 00:15:14,580
+bromophenyl two hexanol الان بهذا المثال كم نظام
+
+166
+00:15:14,580 --> 00:15:18,780
+ترقيم استعملت حتى ممكن بالألوان تشايفينهم كيف 
+
+167
+00:15:18,780 --> 00:15:22,820
+صاروا واضحين هذا ال four تبقى لهان ان المجموعة
+
+168
+00:15:22,820 --> 00:15:26,300
+اللي بين القوسين موجودة على الموقع أربعة على 
+
+169
+00:15:26,300 --> 00:15:32,460
+السنسلة لكن هذا ترقيم تاني عشان هيك الأنسب لهذا 
+
+170
+00:15:32,460 --> 00:15:37,000
+الترقيم التاني اللي كنت كاتبه بالأزرق إن أحطله إيش
+
+171
+00:15:37,000 --> 00:15:44,720
+الـ prime طبعا هذا بيمنعش أنه بزام فيه تاني ممكن 
+
+172
+00:15:44,720 --> 00:15:50,520
+يصير كمان تالت و باجيتها ممكن أحطله double prime
+
+173
+00:15:50,520 --> 00:15:56,720
+وارد بتصير الأمور أصعب لكن المبدأ بأمل أنه صار إيش 
+
+174
+00:15:56,720 --> 00:15:58,440
+واضح عندكم
+
+175
+00:16:04,790 --> 00:16:11,250
+
+
+223
+00:21:04,730 --> 00:21:09,810
+الان بالنسبة لل ethers استعملوا سابقا كمواد مخدرة 
+
+224
+00:21:09,810 --> 00:21:14,670
+anesthetics والان بعض المشتقات منها زي هذا المركب 
+
+225
+00:21:14,670 --> 00:21:17,450
+اللي فيه ذرات floro و chloro بناهاش نحفظه اسمه 
+
+226
+00:21:17,450 --> 00:21:20,790
+penanthrene او هذا اللي فيه floro و chloro
+
+227
+00:21:20,790 --> 00:21:25,810
+enanthrene تستعمل في التخدير الطبي ال halogenated 
+
+228
+00:21:25,810 --> 00:21:28,970
+ethers they are common anesthetics anesthetics 
+
+229
+00:21:28,970 --> 00:21:33,650
+يعني مواد تستخدم في التخدير الطبي بدنا ننتبه لنقطة 
+
+230
+00:21:33,650 --> 00:21:37,830
+كتير مهمة مش هنفصل فيها لكن الآن بنحكيها اللي ال
+
+231
+00:21:37,830 --> 00:21:42,410
+ether إذا خزنا لفترة طويلة بالذات بعد ما نفتح ال
+
+232
+00:21:42,410 --> 00:21:49,650
+bottle و يتعرض لل oxygen بيعمل مادة متفجرة peroxide 
+
+233
+00:21:49,650 --> 00:21:54,530
+وبالتالي ممكن الشخص يجي يسخله طبعا مش عليها مباشرة 
+
+234
+00:21:54,530 --> 00:21:59,950
+على سخان كهربائي مغلق اللي بنسميه tablet يكون فيه
+
+235
+00:21:59,950 --> 00:22:04,380
+المواد المتفجرة يروح ينفجر فيه الان هذه المواد 
+
+236
+00:22:04,380 --> 00:22:08,320
+المتفجرة أشهر إيثر عادة بيستخدم اللي هو الـ 
+
+237
+00:22:08,320 --> 00:22:13,800
+Diethyl Ether الان هذا لو انخزن لفترة طويلة بتفعل
+
+238
+00:22:13,800 --> 00:22:18,600
+مع الأكسجين بيعمله مركب زي هذا بيروكسايد هذا
+
+239
+00:22:18,600 --> 00:22:23,680
+البروكسايد ايش ماله؟ Explosive الآن حسب كمية 
+
+240
+00:22:23,680 --> 00:22:28,280
+الخزانة لو اتخزن كتير في جو سيء ممكن يعمل peroxide 
+
+241
+00:22:28,280 --> 00:22:32,640
+ويترسب و تشوفوا بعينكم ان في قلب البوتل ال ether
+
+242
+00:22:32,640 --> 00:22:37,260
+مادة صلبة لو كانت بكمية صغيرة ممكن تكون دايب وما
+
+243
+00:22:37,260 --> 00:22:41,610
+تشوفوش بالعينين في كل الأحوال لما بتحولوا لجزء عملي 
+
+244
+00:22:41,610 --> 00:22:44,650
+او بتاخدوا في يوم من الأيام جزء عملي المفروض 
+
+245
+00:22:44,650 --> 00:22:48,530
+تفاصيل كيف نفحص ال ether كيف نتأكد منه قبل ما 
+
+246
+00:22:48,530 --> 00:22:53,690
+نشتغل عليه هذا الأمر بتتعلموه الان لو في المستقبل 
+
+247
+00:22:54,160 --> 00:22:58,620
+أشتغلت بكالوريوس، ماجستير، باحث في إيثر تسخين، في
+
+248
+00:22:58,620 --> 00:23:02,740
+هذه اللحظة خدوا كلمة واحدة إن الإيثر في منه خطر أن 
+
+249
+00:23:02,740 --> 00:23:06,820
+يكون مواد متفجرة يوم ما يطلب منكوا حقيقة تشتغلوا و
+
+250
+00:23:06,820 --> 00:23:10,820
+تسخنوا بالإيثر ارجعوا لهذه المعلومة في كل كتب 
+
+251
+00:23:10,820 --> 00:23:16,130
+العمل بدلكم بتفاصيل أكتر كيف تتأكدوا إنه هالمادة
+
+252
+00:23:16,130 --> 00:23:19,850
+موجودة ولا لأ و لو موجودة كيف تتخلصوا منها و كل 
+
+253
+00:23:19,850 --> 00:23:23,350
+الأشياء التفصيلية هذه لكن خلوا في ذهنكوا ان ال
+
+254
+00:23:23,350 --> 00:23:27,950
+ether مع سوق التخزين و في وجود ال oxygen بيعمل إيش 
+
+255
+00:23:27,950 --> 00:23:36,090
+explosive materials الان كيف بنحضر ال ethers أخدنا
+
+256
+00:23:36,090 --> 00:23:42,310
+احنا تحضير لل ethers لما درسنا ال alkenes و ال
+
+257
+00:23:42,310 --> 00:23:48,250
+alcohols قولنا ان ال alcohol لو سخناه عند 180 درجة
+
+258
+00:23:48,250 --> 00:23:54,460
+مئوية كان يعمل حذف للميه و يعطينا الالكين و عند 140 
+
+259
+00:23:54,460 --> 00:23:59,520
+درجة مئوية بيعطينا ال ether متذكرين هذه المعادلة
+
+260
+00:23:59,520 --> 00:24:03,300
+في كيمية ال alcohols اذا ال ethers they can be
+
+261
+00:24:03,300 --> 00:24:07,000
+prepared from alcohols طبعا انا لما بحكي عن ether 
+
+262
+00:24:07,000 --> 00:24:11,450
+هنا بحكي عن ال symmetrical ethers ماذا؟ إن إيثانول
+
+263
+00:24:11,450 --> 00:24:15,450
+يهاجم على إيثانول ويفقد ميّه وهذه المعادلة سابق
+
+264
+00:24:15,450 --> 00:24:20,190
+وضحتها إيها إيثانول زي إيثانول يخص منهم ميّه يعني 
+
+265
+00:24:20,190 --> 00:24:24,770
+هذه المعادلة لو أريدها موزنة، ماذا أكتب هنا؟ H2O 
+
+266
+00:24:24,770 --> 00:24:29,110
+واضح؟ جزء يهاجم على التانى ويطلع ميّه ويكون له 
+
+267
+00:24:29,110 --> 00:24:34,880
+إيثر الان هذا الـ symmetrical ether ان الاثانول 
+
+268
+00:24:34,880 --> 00:24:39,720
+اتفعل مع نفسه طيب يا تورا الان بيجيني السؤال لو
+
+269
+00:24:39,720 --> 00:24:45,320
+بدي un symmetrical ether يعني بدي ether في اثل و 
+
+270
+00:24:45,320 --> 00:24:51,400
+مثل ايش اول شيء ممكن يخطر ع بالكم يعني لو بدي انا 
+
+271
+00:24:51,400 --> 00:24:56,000
+دايم في ال ether شو اللي بسخنه مع الحامض؟ ميثانول
+
+272
+00:24:56,000 --> 00:24:59,760
+لو بدى داي إثل إيثار شو اللى بسخنه مع الحامض 
+
+273
+00:24:59,760 --> 00:25:05,540
+إثانول طيب لو بدى مثل إثل إيثار شو بدى أسخن مع 
+
+274
+00:25:05,540 --> 00:25:09,500
+الحامض واضحة 
+
+275
+00:25:09,500 --> 00:25:17,160
+الفكرة لو بدى مثل إثل إيثار او إثل مثل إيثار الان
+
+276
+00:25:17,160 --> 00:25:22,520
+انتبهوا معي أي واحدة ممكن تبدأ التفكير في مثل إثل 
+
+277
+00:25:22,520 --> 00:25:28,400
+إيثار تقول باخد ال two alcohols يعني باخد مثل OH 
+
+278
+00:25:28,400 --> 00:25:40,120
+زائد إثل OH بده يطلع لمثل OH إيش رأيكوا بهذا
+
+279
+00:25:40,120 --> 00:25:40,780
+الكلام؟
+
+280
+00:25:43,190 --> 00:25:47,830
+بطلع لكن هنا في مشكلة انه انا لما بخلط بخلطش جزئ و
+
+281
+00:25:47,830 --> 00:25:52,030
+جزئ بخلط عدد كبير يعني لو خلطت mall و mall يعني
+
+282
+00:25:52,030 --> 00:25:55,990
+انا خلطت 6 في 10 او 23 من هذا مع 6 في 10 او 23 من 
+
+283
+00:25:55,990 --> 00:26:00,290
+هذا الان كلهم موجودين خليني اعملها على النطاق
+
+284
+00:26:00,290 --> 00:26:06,110
+البسيط لو على نطاق جزيئين هذا ال ethanol و هذا ال
+
+285
+00:26:06,110 --> 00:26:09,600
+methanol و خلطتهم و قلتلهم يلا اتفاعلوا ايش
+
+286
+00:26:09,600 --> 00:26:13,600
+الاحتمالات؟ هم بتفعلوا، سمعين؟ الان ممكن يلتقي
+
+287
+00:26:13,600 --> 00:26:20,260
+الاثل مع الاثل بي اثل اثر ممكن يلتقي المثل مع
+
+288
+00:26:20,260 --> 00:26:27,420
+المثل بي مثل اثر ممكن يلتقي الاثل مع المثل اثر مثل 
+
+289
+00:26:27,420 --> 00:26:35,740
+اثر اذا هنا كم ناتج نتوقع؟ تلاتة مثل او مثل اثل او 
+
+290
+00:26:35,740 --> 00:26:41,970
+اثل أو إثل أو ميثل بيطلع لكن مع اتنين تانين يعني
+
+291
+00:26:41,970 --> 00:26:46,310
+بيطلع خليط من تلت مراكبات و هات وفصلهم هل هذا
+
+292
+00:26:46,310 --> 00:26:51,890
+الكلام الكيميائي بيحبه؟ اطلاقا لا ولذلك اي حد
+
+293
+00:26:51,890 --> 00:26:56,590
+بيقول انه تحضير الإثل مثل إيثر بخلط الكحولين وهي 
+
+294
+00:26:56,590 --> 00:27:00,530
+طلع الجواب بنقوله غلط لأنك طلعت تلت نواتج وبعدين
+
+295
+00:27:00,530 --> 00:27:05,170
+بدنا نشتغل نعمل انفصل وتقطير، هذه عملية إيش مالها؟ 
+
+296
+00:27:05,170 --> 00:27:09,610
+متعبة ولذلك بنحول على طريقة تانية في تحضير الـ 
+
+297
+00:27:09,610 --> 00:27:15,160
+Unsymmetrical ethers أيضا بنبتدأ فيها من وين؟ من
+
+298
+00:27:15,160 --> 00:27:20,340
+الكحولات الان الكحولات واحد منهم وبشكل عام اللي
+
+299
+00:27:20,340 --> 00:27:25,520
+بيكون primary بنخليه يصير chloride يعني هذا لو
+
+300
+00:27:25,520 --> 00:27:32,900
+فعلناه مع ال BCl3 إيش هيصير CH3 CH2 بدل ما هو OH
+
+301
+00:27:32,900 --> 00:27:39,020
+Cl حولته ل chloride والتالي بحوله ل O minus كيف
+
+302
+00:27:39,020 --> 00:27:43,010
+الكحول بيصير O minus؟ بالتفاعل مع السوديوم
+
+303
+00:27:43,010 --> 00:27:48,290
+هيدروكسايد؟ قلنا لأ بالتفاعل مع السوديوم أو
+
+304
+00:27:48,290 --> 00:27:51,890
+السوديوم هيدرايد هدولة التنين اللي بيصيروا يعني 
+
+305
+00:27:51,890 --> 00:27:57,750
+هذا لو فعلته مع السوديوم بيصير مثل O minus and A
+
+306
+00:27:57,750 --> 00:28:04,840
+plus هيو ب فلاسك لحاله و هذا ب فلاسك لحاله لسه 
+
+307
+00:28:04,840 --> 00:28:09,360
+ماخلطتهمش يعني إيجي إنسان أعطاكم هاي إيثانول و هاي 
+
+308
+00:28:09,360 --> 00:28:13,420
+ميثانول هذا بالفلاسك واحد منهم بخليه ايش O minus
+
+309
+00:28:13,420 --> 00:28:19,900
+والتاني اكلورايد بعدين بضيف التانين على بعض بعدين
+
+310
+00:28:19,900 --> 00:28:23,600
+بضيف ايش التانين على بعض لو بضيف هذا على هذا هذا 
+
+311
+00:28:23,600 --> 00:28:30,490
+ال O وين هتهاجم؟ و إيش هتطرد؟ ال CL تفاعل الإقدال 
+
+312
+00:28:30,490 --> 00:28:37,590
+اللي أخدناه ب chapter 6 لاحظوا إيش الناتج CH3 CH2O
+
+313
+00:28:37,590 --> 00:28:45,960
+مثل أو CH3 بس مركب واحد اذا أنا لما بدي ال un
+
+314
+00:28:45,960 --> 00:28:51,060
+symmetrical ethers لأخلط الكحولين مع بعض لأ واحد
+
+315
+00:28:51,060 --> 00:28:56,240
+منهم بحاوله ل O minus و واحد منهم بحاوله الى 
+
+316
+00:28:56,240 --> 00:29:00,000
+chloride او bromide و بعدين بضيفهم مع بعض بطلعولي
+
+317
+00:29:00,000 --> 00:29:04,780
+فقط ناتج واحد هذه الطريقة في التحضير اسمها طريقة
+
+318
+00:29:04,780 --> 00:29:10,230
+السيد William Sun William Sun's synthesis William
+
+319
+00:29:10,230 --> 00:29:14,410
+Sun's synthesis موجودة عندكم في ال slides وهين
+
+320
+00:29:14,410 --> 00:29:18,770
+وضحت بطريقة تانية انه مانخلطش الكحولين مع بعض 
+
+321
+00:29:18,770 --> 00:29:24,090
+اطلاقا اطلاقا هذا الكلام مابيصيرش واضح الفكرة؟
+
+322
+00:29:30,200 --> 00:29:34,580
+نشوف مرة تانية الـ Williamson's synthesis هاي مثلا
+
+323
+00:29:34,580 --> 00:29:40,500
+ROH مع ن إيه؟ شو أعطاني؟ R O minus هذا الـ charged
+
+324
+00:29:40,500 --> 00:29:45,300
+nucleophile و R X كوّنتها أساسا من الكحول لما أضيف
+
+325
+00:29:45,300 --> 00:29:50,800
+الـ R O minus على الـ R X أي تفاعل بعمل؟ الإبدال
+
+326
+00:29:50,800 --> 00:29:53,380
+ROR 
+
+327
+00:29:54,350 --> 00:29:59,510
+الان اتخيلوا لو اتيكم how can you prepare this
+
+328
+00:29:59,510 --> 00:30:09,870
+ether فنل O CH2 CH3 الفكرة ان واحد منهم بدي اخليه
+
+329
+00:30:09,870 --> 00:30:15,330
+يعني انا بدي ابدأ من فنل OH و F OH لكن مين منهم بدي 
+
+330
+00:30:15,330 --> 00:30:20,830
+أخليه O- ومين منهم بدي أخليه CL الان أنا قولت اللي
+
+331
+00:30:20,830 --> 00:30:25,610
+باخليه CL ال primary أو ال مثل إذا وجدت ما هو ال
+
+332
+00:30:25,610 --> 00:30:28,790
+مثل أفضل من ال primary يا ال primary يا المثل 
+
+333
+00:30:28,790 --> 00:30:34,720
+وبناء على ذلك الفن ال OH هذا بخليه ايش مع ال sodium
+
+334
+00:30:34,720 --> 00:30:37,980
+او مع ال sodium hydroxide بيمشي اساسا لان الفينول
+
+335
+00:30:37,980 --> 00:30:41,800
+بتفاعل مع ال sodium hydroxide بيصير فينيل O minus
+
+336
+00:30:41,800 --> 00:30:48,620
+هي ال nucleophile فينيل O minus وهذا ال ethanol 
+
+337
+00:30:48,620 --> 00:30:55,540
+بقدر انا اخليه من خلال التفاعل مع ال BCL3 CH3
+
+338
+00:30:55,540 --> 00:31:03,380
+CH2CL اكيد الان لو فعلت هذا ال phenoxide هنا بيطرد 
+
+339
+00:31:03,380 --> 00:31:09,330
+ال X و بيعطينا المركب المطلوب ولا لأ؟ واضح؟ فالفكرة 
+
+340
+00:31:09,330 --> 00:31:13,150
+في هذا النوع .. الفكرة في هذا النوع من الأسئلة لما
+
+341
+00:31:13,150 --> 00:31:17,150
+أجيبلكوا ether معين و أقولكوا كيف تحضروه أنكم
+
+342
+00:31:17,150 --> 00:31:20,450
+تعرفوا مين اللي بدي أخليه منه O minus مين اللي بدي
+
+343
+00:31:20,450 --> 00:31:24,270
+أخليه chloride الآن اللي بدي أخليه ال chloride يا 
+
+344
+00:31:24,270 --> 00:31:29,630
+ال methyl يا ال primary هاي مسألة هنا شايفينها
+
+345
+00:31:29,630 --> 00:31:37,760
+تيرتشاريب بيوتلبروبل إيثار كيف يمكنك تجهيزه بدأ من 
+
+346
+00:31:37,760 --> 00:31:44,680
+الكحول ارسم الانتوا الكحول احفظوا انتوا ايش
+
+347
+00:31:44,680 --> 00:31:52,260
+المطلوب تيرتشار بيوتل بروبل إيثار يعني كأنه عندكم 
+
+348
+00:31:52,260 --> 00:32:01,200
+انتوا معطى هاي ال تيرتشار بيوتل وهاي البروبانول
+
+349
+00:32:01,200 --> 00:32:06,700
+هاي الانتوا الكحول الان ما طريقة التحضير واحد منهم 
+
+350
+00:32:06,700 --> 00:32:15,000
+O- والتاني CL مين اللي بدي أخليه CL ال primary هذا 
+
+351
+00:32:15,000 --> 00:32:20,300
+ال alcohol tertiary هذا ال alcohol ال primary اذا 
+
+352
+00:32:20,300 --> 00:32:27,880
+هذا بعمله مع ال BCL3 هيوصار CL وهذا بعمله مع ال NA
+
+353
+00:32:27,880 --> 00:32:36,510
+هيوصار O- الان اخلطوا هادولا التانين مع بعض ايش 
+
+354
+00:32:36,510 --> 00:32:40,910
+النتيجة؟ 
+
+355
+00:32:40,910 --> 00:32:47,640
+هادي هتهاجم هان و تطرد الـ CL المركب المطلوب مرات 
+
+356
+00:32:47,640 --> 00:32:51,860
+لما يقولوا المركب المطلوب بيحطوا رمز TM مر عليكم 
+
+357
+00:32:51,860 --> 00:32:55,620
+إيش يعني الـ TM؟ زي ما في الهندس لما بتخلصوا الشغلة
+
+358
+00:32:55,620 --> 00:33:00,020
+بتقولوا هو المطلوب إثباته الآن TM يعني ال target
+
+359
+00:33:00,020 --> 00:33:05,020
+molecule يعني الجزء المطلوب target إيش target؟
+
+360
+00:33:05,020 --> 00:33:11,520
+molecule الجزء المطلوب يعني يعني الـ TM بلغة الكيميا
+
+361
+00:33:11,520 --> 00:33:15,820
+وهو المطلوب طبعاً هيكون زي هيك O وهي واحد، اتنين،
+
+362
+00:33:15,820 --> 00:33:21,100
+تلاتة واضحات؟ 
+
+363
+00:33:21,100 --> 00:33:24,580
+الان لو واحدة عكست عملت هذا ال chloride وهذا الـ O
+
+364
+00:33:24,580 --> 00:33:29,760
+minus بطلعش عندها يعني لو السؤال عليه عشر علامات 
+
+365
+00:33:29,760 --> 00:33:35,900
+مجاملة نحط لها تلاتة او تنين لأنه
+
+366
+00:33:35,900 --> 00:33:42,040
+عملياً ما بصيرش واضح؟ عملياً ما بيصيرش افهمنا هذه
+
+367
+00:33:42,040 --> 00:33:59,680
+الفكرة بوليام سانس سينتيسيز الان 
+
+368
+00:33:59,680 --> 00:34:06,640
+ال ethers اتكونت طيب يا تورا ممكن تنكسب ممكن تتفاعل 
+
+369
+00:34:06,640 --> 00:34:10,900
+إلا بس تفاعل واحد فقط اللي هو الـ cleavage of
+
+370
+00:34:10,900 --> 00:34:16,020
+ether يعني ممكن ينكسر نص سيلة كيف بتم ال cleavage 
+
+371
+00:34:16,020 --> 00:34:23,220
+of ether باستعمال الحامض القوي HI الـ HI بيهاجم
+
+372
+00:34:23,220 --> 00:34:30,020
+عادة في اليود وهذا هيو ماشي وين بده يروح الـ W مع
+
+373
+00:34:30,020 --> 00:34:33,200
+.. لأ على الـ Carbon اللي جنب الـ O الـ U السالب 
+
+374
+00:34:33,200 --> 00:34:36,080
+.. الـ O السالب على الـ Carbon من بين الموجبات الـ 
+
+375
+00:34:36,080 --> 00:34:39,360
+principal يعني هنا هذه الـ Carbon الموجبة و هذه 
+
+376
+00:34:39,360 --> 00:34:43,860
+الموجبة هذه السالبة جزئياً لما بده يروح .. وين بده
+
+377
+00:34:43,860 --> 00:34:47,880
+يروح؟ على الموجب .. الآن لاحظوا معي لما بده يروح 
+
+378
+00:34:47,880 --> 00:34:52,820
+على الموجب هيو ماشي ورايح على الموجب اليمين و لا
+
+379
+00:34:52,820 --> 00:34:58,480
+الموجب الشمالي افهمتوا وين السؤال؟ الآن على الـ 
+
+380
+00:34:58,480 --> 00:35:05,900
+Primary هذا المحور الان وين ال primary هان؟ وين ال
+
+381
+00:35:05,900 --> 00:35:12,420
+primary هان؟ ولذلك لما تطلع النتيجة هذا الجزء اللي
+
+382
+00:35:12,420 --> 00:35:18,340
+بيبقى معه ال O هياخد ال H هيصير فين ال O؟ H هياخد
+
+383
+00:35:18,340 --> 00:35:25,180
+ال H وهذا الجزء CH3 CH2 هيصير ايش؟ Iodide شوفنا كيف
+
+384
+00:35:25,180 --> 00:35:29,780
+الـ cleavage الان هذا ماشي هنا ايه هنا؟ هيعطيني 
+
+385
+00:35:29,780 --> 00:35:37,660
+CH3 CH2 CH2 I هذا معلوم CH3 CH2 CH2 I و هذا اللي
+
+386
+00:35:37,660 --> 00:35:43,380
+ضلت معه ال O شو هيصير OH هذا اللي هو ال cleavage 
+
+387
+00:35:43,380 --> 00:35:50,680
+of ether هذا اللي هو ال cleavage of ether 
+
+388
+00:35:52,990 --> 00:35:58,330
+باستعمال الـ HI غير هيك مش مشهور تفاعلات لل إيثارز 
+
+389
+00:35:58,330 --> 00:36:03,310
+يعني هو تفاعل واحد الـ cleavage الكسر الآن في
+
+390
+00:36:03,310 --> 00:36:08,450
+إيثارز حلقية اسمها الـ Epoxides أخدتها بالتفصيل هي
+
+391
+00:36:08,450 --> 00:36:12,990
+و تفاعلاتها ولا لأ لما أخدنا تفاعلات الالكين و
+
+392
+
+445
+00:40:53,590 --> 00:40:58,650
+معين بيدخل ب cavity معينة Ion معين بيدخل بcavity
+
+446
+00:40:58,650 --> 00:41:03,730
+معينة يعني مثلا هذا المركب ال 18 crown 6 لما جاسوا
+
+447
+00:41:03,730 --> 00:41:08,230
+حجم ال cavity تبعته بين اتنين و ستة من عشرة لتلاتة
+
+448
+00:41:08,230 --> 00:41:12,030
+و اتنين من عشرة أنجسترون طب حجم ايون الصوديوم واحد
+
+449
+00:41:12,030 --> 00:41:15,510
+و تسعة واحد و تسعة لو حطناه من هنا إيش بيعمل
+
+450
+00:41:15,510 --> 00:41:21,490
+الفتحة كبيرة عليه بيجع منها ال cesium تلاتة و 
+
+451
+00:41:21,490 --> 00:41:27,550
+تلاتة أكبر من الفتحة بيدخلش مين اللي بتناسب معها
+
+452
+00:41:27,550 --> 00:41:31,990
+اتنين و ستة و ستين وهذه اتنين و ستة لتلاتة و اتنين 
+
+453
+00:41:32,930 --> 00:41:37,910
+البوتاسيوم إذا لو حطينا ال crown الآن و جيبنا
+
+454
+00:41:37,910 --> 00:41:42,650
+التلت أيونات معادن هو فيه cavity الان ال cavity
+
+455
+00:41:42,650 --> 00:41:50,330
+واحد صغير بيدخل منها بيوقع والتاني كبير ما بيجيش
+
+456
+00:41:50,330 --> 00:41:54,970
+والتالت المتناسب مين اللي هيقعد في قلب ال cavity؟ 
+
+457
+00:41:55,610 --> 00:42:01,130
+البوتاسيوم اذا هذا ال crown صار لو حطناله التلاتة
+
+458
+00:42:01,130 --> 00:42:05,390
+صاد منهم البوتاسيوم و ساب التانين التانين عارفين 
+
+459
+00:42:05,390 --> 00:42:09,990
+الفكرة زي ايش؟ زي الشبكة تبعت صيادين السمك صياد
+
+460
+00:42:09,990 --> 00:42:13,530
+السمك عنده اكتر من شبكة لكل موسم كل شبكة فيها حجم
+
+461
+00:42:13,530 --> 00:42:19,110
+اليوم لما بدو يصيد البوري عنده حجم معين بيمسك سمكة
+
+462
+00:42:19,110 --> 00:42:24,200
+البوري طب و السردين؟في شبكة البوري بيدخل و بيطلع
+
+463
+00:42:24,200 --> 00:42:27,320
+قدامه هو مش ناوي يصيده بيدخل و بيطلع أو السمك
+
+464
+00:42:27,320 --> 00:42:30,460
+الصغير لما بديه يصيد السردين شو بديه يستعمل إلها؟
+
+465
+00:42:30,460 --> 00:42:35,000
+شبكة أصغر أفهمتوا إيش الفكرة هنا في ال host و ال
+
+466
+00:42:35,000 --> 00:42:39,840
+guest؟ إنه ال guest الضيف اللي بديه ييجي هنا اللي
+
+467
+00:42:39,840 --> 00:42:44,560
+هو المثل هذا ال guest لازم يكون حجمه متناسب مع 
+
+468
+00:42:44,560 --> 00:42:51,240
+إيش؟ مع ال cavity وهذا الكلام له حتى تطبيقات في
+
+469
+00:42:51,240 --> 00:42:56,940
+وين؟في المجال الطبي في الأدوية يعني آخر slide الآن
+
+470
+00:42:56,940 --> 00:43:03,220
+عندنا هاي هذا المركب في نفس الفكرة بطريقة أو باخره 
+
+471
+00:43:03,220 --> 00:43:10,380
+و في cavity هنا high cavity هذه الكفتي تبعته افتسع
+
+472
+00:43:10,380 --> 00:43:16,300
+البوتاسيوم يعني لما يكون فيه نا بلس وبوتاسيوم بلس
+
+473
+00:43:16,300 --> 00:43:20,980
+في جسم الإنسان من اللي بيدخل في الكفتي البوتاسيوم 
+
+474
+00:43:20,980 --> 00:43:25,940
+الآن هذا المضاد الحيوي بدخل جوا الخلية لما يدخل 
+
+475
+00:43:25,940 --> 00:43:31,500
+بدخل بما حمل إذا إيش جدر يدخل جوا الخلية؟ 
+
+476
+00:43:32,150 --> 00:43:37,190
+البوتاسيوم ايش صاب برا الخلية الصوديوم بنسمي هذه 
+
+477
+00:43:37,190 --> 00:43:43,630
+العملية ايش selective transport يعني هو دخل واحد
+
+478
+00:43:43,630 --> 00:43:50,770
+من اتنين هي الخلية هي جدارها هذه هي الخلية المضاد
+
+479
+00:43:50,770 --> 00:43:55,560
+بيقدر يدخل في جلب الخليةو بيقدر يحمل واحد من
+
+480
+00:43:55,560 --> 00:43:58,620
+الاتنين، مين اللي بيقدر يحمله؟ ال potassium
+
+481
+00:43:58,620 --> 00:44:01,920
+المتناسب مع حجم ال cavity بناء على ذلك هو في الأول 
+
+482
+00:44:01,920 --> 00:44:05,500
+بيحمل ال potassium، بعدين هو بما حمله بيدخل جوا 
+
+483
+00:44:05,500 --> 00:44:11,000
+الخلية بزامو دخل، نجل ال potassium من برا لجوا 
+
+484
+00:44:11,700 --> 00:44:15,900
+فاهمتوا أين الجمال بفكرة crown ethers يعني بسرها
+
+485
+00:44:15,900 --> 00:44:21,900
+انعكاس على واقع التطبيق الطبي بهك بنكون أنهينا هذا
+
+486
+00:44:21,900 --> 00:44:24,140
+ال chapter اللي اسمه ال ethers
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3bed0200f45e90bb165e6da87325547b7cef2042
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s_postprocess.srt
@@ -0,0 +1,1944 @@
+1
+00:00:19,640 --> 00:00:24,180
+بسم الله الرحمن الرحيم موضوعنا اليوم عن عائلة
+
+2
+00:00:24,180 --> 00:00:28,620
+كيميائية جديدة مجموعة وظيفية جديدة اللي هي ال
+
+3
+00:00:28,620 --> 00:00:34,460
+aethers طبعا على طول عدد كبير منكم هيتذكر ان ال
+
+4
+00:00:34,460 --> 00:00:40,460
+aethers اللي هم الصيغة العامة ROR يعني Oxygen
+
+5
+00:00:40,460 --> 00:00:47,150
+محصورة بين ذرتينأو Oxygen بين مجموعتين R وكلكم
+
+6
+00:00:47,150 --> 00:00:53,550
+اتذكرين ان ال Oxygen رابطتين وزوجين إيش؟ إلكترونات
+
+7
+00:00:53,550 --> 00:00:59,950
+ولذلك احنا غير ال ethers مر علينا شغلتين أبسط من
+
+8
+00:00:59,950 --> 00:01:04,390
+ال ethers مر علينا شغلتين أبسط من ال ethers شو هم
+
+9
+00:01:04,390 --> 00:01:11,100
+الآن؟ مين يذكرنا فيهم؟ الماءوالكحول الان الماء
+
+10
+00:01:11,100 --> 00:01:16,260
+اكسوجينة ايضا و الكحول اكسوجينة و ال ether برضه
+
+11
+00:01:16,260 --> 00:01:21,080
+ذرة اكسوجين و زوجين الالكترونات هدوله مافيش مفار
+
+12
+00:01:21,080 --> 00:01:31,320
+منهم لكن الميه كانت H H H الكحول R و H يعني مازال
+
+13
+00:01:31,320 --> 00:01:37,840
+فيه H ال ether R و Rالان لاحظوا بمنطق ال hydrogen
+
+14
+00:01:37,840 --> 00:01:43,740
+bonding الان الميه تنتين hydrogen bonding الكحول
+
+15
+00:01:43,740 --> 00:01:48,080
+من جهة واحدة بتقدر تعمل hydrogen bonding ال ether
+
+16
+00:01:48,080 --> 00:01:52,660
+مافيش hydrogen bonding وبناء على ذلك الان لو بدنا
+
+17
+00:01:52,660 --> 00:01:57,660
+نحكي بمنطق ال polarity من اعلى polarity فيهم الميه
+
+18
+00:01:57,660 --> 00:02:02,080
+بعدها الكحول بعدها ال ether الان ال polarity
+
+19
+00:02:02,080 --> 00:02:07,340
+مباشرة بتنعكس على ايشعلى أي خاصية فيزيائية؟ على
+
+20
+00:02:07,340 --> 00:02:11,460
+درجة الغليان ولذلك على الضغط العادى الميه درجة
+
+21
+00:02:11,460 --> 00:02:17,640
+غليانها 100 الكحول 78 ال ether لو افترضنا اثل و
+
+22
+00:02:17,640 --> 00:02:22,080
+اثل حوالي 37
+
+23
+00:02:23,430 --> 00:02:30,190
+لاحظوا كيف تناسب نقاط الغليان مع القطبية و لو كان
+
+24
+00:02:30,190 --> 00:02:33,950
+ال ether die مثل ether يعني مثل او مثل بيصير غاز
+
+25
+00:02:33,950 --> 00:02:38,930
+يعني درجة غليانه أقل بكتير ولذلك على حرارة الغرفة
+
+26
+00:02:38,930 --> 00:02:45,510
+غلي و خلص وصار ايش موجود على شكلغاز الآن ربما من
+
+27
+00:02:45,510 --> 00:02:48,790
+أشهر ال ether هذا ال ether ال ethyl o ethyl اللي
+
+28
+00:02:48,790 --> 00:02:53,670
+هو ال diethyl ether واضح؟ ليش هذا يستعمل ك solvent
+
+29
+00:02:53,670 --> 00:02:58,670
+مدير سابقا استعمل في التخدير لما كانوا مثلا
+
+30
+00:02:58,670 --> 00:03:01,850
+بيخدروا حيوانات صغيرة بيعملوا تجارب في المختبرات
+
+31
+00:03:01,850 --> 00:03:06,930
+فال ether they have been used as anesthetics الآن
+
+32
+00:03:06,930 --> 00:03:11,720
+لوبدنا ننسى هدول الأشياء اللى احنا سبق اننا
+
+33
+00:03:11,720 --> 00:03:17,820
+أخدناهم ونضلنا امركزين حالنا في ال aethers وهى
+
+34
+00:03:17,820 --> 00:03:22,980
+المثال عنهم اللى هو diethyl ether وممكن نسميه
+
+35
+00:03:22,980 --> 00:03:26,540
+ethyl ether يعني لو لغينا كلمة ethyl، die، بمشي
+
+36
+00:03:26,540 --> 00:03:32,140
+يعني diethyl ether وethyl ether نفس الاشي لحظوا
+
+37
+00:03:32,140 --> 00:03:36,440
+لما بنقول من خواصه much less polar than alcohols
+
+38
+00:03:37,210 --> 00:03:40,210
+الكلام صحيح ولا لأ؟ مافيش فيه hydrogen bonding
+
+39
+00:03:40,210 --> 00:03:44,130
+بالمرة لما نقول من خواصه not soluble in water
+
+40
+00:03:44,130 --> 00:03:49,430
+مافيش فيه solubility لأن هذه are groups كلها مافيش
+
+41
+00:03:49,430 --> 00:03:52,510
+فيه hydrogen bonding اللي يصير polar و like،
+
+42
+00:03:52,510 --> 00:03:56,730
+dissolves، like، له lower melting point و boiling
+
+43
+00:03:56,730 --> 00:04:01,130
+point أو boiling temperatures than alcohol اكيد صح
+
+44
+00:04:03,220 --> 00:04:08,200
+كمان بضيف عليه شغلة chemically inert يعني خامل
+
+45
+00:04:08,200 --> 00:04:14,940
+كيميائيا تفاعلاته قليلة جدا ولذلك ان شاء الله بأمل
+
+46
+00:04:14,940 --> 00:04:18,900
+كل أمل ان نخلص كل ال chapter اليوم لانه لما نحكي
+
+47
+00:04:18,900 --> 00:04:21,560
+عن ال kings و ال quills بنحكي على عشرين تفاعل على
+
+48
+00:04:21,560 --> 00:04:28,180
+ال ethers بنحكي على تفاعل واحد واضح؟لأنه مافيش من
+
+49
+00:04:28,180 --> 00:04:32,340
+خلال MH و لا OH و لا C double bond O و لا double
+
+50
+00:04:32,340 --> 00:04:35,760
+bond هذي المجموعات اللي بنسميها active groups اللي
+
+51
+00:04:35,760 --> 00:04:39,460
+بتيم عليها تفاعلات كتيرة هذا الكلام مش متوفر وين
+
+52
+00:04:39,460 --> 00:04:44,380
+في الethers يضاف إلى ذلك all are very flammable
+
+53
+00:04:45,250 --> 00:04:50,010
+يعني باشتعلوا بشكل سريع جدا زي بنزين السيارات و
+
+54
+00:04:50,010 --> 00:04:54,950
+وقود السيارات أو ربما كمان اكثر ولذلك ادمجوا
+
+55
+00:04:54,950 --> 00:05:00,090
+الشغلتين مع بعض ان هو له نقطة غليان منخفضة يعني
+
+56
+00:05:00,090 --> 00:05:07,230
+بتبخر بسهولة و قابل الاشتعال بشكل كبيرواضح؟ و لذلك
+
+57
+00:05:07,230 --> 00:05:11,770
+يمثل خطر في المختبر يعني نفترض ان حد عنده بنزين
+
+58
+00:05:11,770 --> 00:05:15,630
+burner مولعه هنا و قاعد بيشتغل و هنا فيه وعاء فيه
+
+59
+00:05:15,630 --> 00:05:19,610
+ether مفتوح ال ether نفسه بتبخر سبعة و تلاتين احنا
+
+60
+00:05:19,610 --> 00:05:23,170
+مرات في غزة الحرارة سبعة و تلاتين طبعا هو بتبخر
+
+61
+00:05:23,170 --> 00:05:27,030
+على كل الدرجات و كل ما ارتفعت الحرارة بتزيد التبخر
+
+62
+00:05:27,030 --> 00:05:32,020
+و لذلك ممكن و ال ether هنا و فيناعرف مكان تانيit
+
+63
+00:05:32,020 --> 00:05:36,000
+can catch fire زي ما بيسموه يعني ممكن يشتعل و يعمل
+
+64
+00:05:36,000 --> 00:05:41,060
+حريقة فالتعامل مع ال ether بحاجة إلى حذر لأن هو
+
+65
+00:05:41,060 --> 00:05:46,440
+very flammable و له نقطة غليان منخفضة يعني بينوجد
+
+66
+00:05:46,440 --> 00:05:51,500
+.. بيتبخر واضح؟ تماما زي التعامل مع وقود السيارات
+
+67
+00:05:51,500 --> 00:05:56,240
+أو مع التنر هذه المراكبات الكيميائية بحاجة إلى نوع
+
+68
+00:05:56,240 --> 00:06:04,050
+من الحذر الشديدالان كيف بنسمي ال ethers؟ في إنا
+
+69
+00:06:04,050 --> 00:06:08,670
+نظامين للتسمية نظام الشائع ال common nomenclature
+
+70
+00:06:08,670 --> 00:06:12,710
+إن أنا أذكر المجموعات و دائما المجموعة بتاخد
+
+71
+00:06:12,710 --> 00:06:17,990
+النهاية YL مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+72
+00:06:17,990 --> 00:06:20,470
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+73
+00:06:20,470 --> 00:06:26,330
+مثل مثل مثل مثل مثل مثل
+
+74
+00:06:26,330 --> 00:06:26,970
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+75
+00:06:26,970 --> 00:06:30,750
+مثل مثل مثل مثل مثل مثبقول die ethyl ether وممكن
+
+76
+00:06:30,750 --> 00:06:35,210
+تلاقوها ethyl ether يعني تختصر ال die مثل و مثل،
+
+77
+00:06:35,210 --> 00:06:41,030
+die مثل ether فنل و فنل، die فنل ether الان طب لو
+
+78
+00:06:41,030 --> 00:06:44,450
+كان هذا ال ether اللاحظه اللي زي بعض المجموعتين
+
+79
+00:06:44,450 --> 00:06:48,110
+يعني نتخيله زي هيك هي هذه ال oxygena وهنا
+
+80
+00:06:48,110 --> 00:06:53,920
+المجموعتين زي بعضهذا بنسميه Symmetric Ether متماثل
+
+81
+00:06:53,920 --> 00:06:59,700
+طب لو يختلفوا Unsymmetric Ether الأن واجهت أذكر
+
+82
+00:06:59,700 --> 00:07:04,840
+المجموعتين alphabetically يعني Ether فيه إثل و مثل
+
+83
+00:07:04,840 --> 00:07:13,080
+إيش هسميه إثل مثل إثر إبروبل مثلا و تيرتشار بيوتل
+
+84
+00:07:14,280 --> 00:07:27,560
+ترتشير بيوتل بروبل إيثار ترتشير
+
+85
+00:07:27,560 --> 00:07:28,240
+بيوتل بروبل إيثار ترتشير بيوتل بروبل إيثار ترتشير
+
+86
+00:07:28,240 --> 00:07:33,600
+بيوتل بروبل إيثار ترتشير بيوتل بروبل إيثار
+
+87
+00:07:39,540 --> 00:07:45,680
+بتكونش تعجزوا ال ether معناه ذرّة أكسوجين طالع
+
+88
+00:07:45,680 --> 00:07:49,940
+منها رابطة تل لكن الشطارة في اللي بيكون حفظ
+
+89
+00:07:49,940 --> 00:07:57,840
+المجفوعات الآن ال tertiary butylcarbon عليها تلاتة
+
+90
+00:07:57,840 --> 00:08:04,700
+مثل أخذناها وال isopropyl carbon CH متصلة باتنين
+
+91
+00:08:04,700 --> 00:08:11,280
+مثل زي هيكالمحافظة على هذه الشغلة من الأول هذا
+
+92
+00:08:11,280 --> 00:08:18,320
+دلبو واضح فهي tertiary butyl isopropyl ether احنا
+
+93
+00:08:18,320 --> 00:08:22,560
+قلنا تيرتشاري بيوتل بنعملها على حرف ال بي هذا لما
+
+94
+00:08:22,560 --> 00:08:27,140
+شرحنا المجموعات اذا شفنا كيف بنعمل ال ethers كذلك
+
+95
+00:08:27,140 --> 00:08:31,380
+الحالة لو قلنا الكوفينيل مثلا ايش بدنا نحط البنزين
+
+96
+00:08:31,380 --> 00:08:32,300
+المخصوم منها
+
+97
+00:08:42,010 --> 00:08:47,110
+وهاي هذه أمثلة die methyl ether اثل مثل اثر زي ما
+
+98
+00:08:47,110 --> 00:08:50,810
+قولت مرات بيحطهم مش مرتبين alphabetical لكن الأصح
+
+99
+00:08:50,810 --> 00:08:55,090
+تحطهم alphabetical يعني زي هذا الأصح تكتبوه اثل
+
+100
+00:08:55,090 --> 00:09:00,110
+مثل اثر خلو ال E قبل ال M هذا ال ether هذه ال
+
+101
+00:09:00,110 --> 00:09:07,410
+CH2Cl اسمها كلوروميثل CH2Cl كلوروميثل وهنا اثل اثل
+
+102
+00:09:07,410 --> 00:09:15,930
+اثلEther وهكذا هذه التسمية هي ال common
+
+103
+00:09:15,930 --> 00:09:21,070
+nomenclature الان لاحظوا معاك شرط هذه التسمية شرط
+
+104
+00:09:21,070 --> 00:09:24,730
+هذه التسمية ان المجموع اللي هان و اللي هان يكون
+
+105
+00:09:24,730 --> 00:09:28,010
+لهم اسماء معروفة بالنسبة لنا و المجموعات اللي
+
+106
+00:09:28,010 --> 00:09:31,810
+أخدناها ايجليلا مثل ايثلبروبل ايزوبروبل تيرتشر
+
+107
+00:09:31,810 --> 00:09:38,800
+بيوتل لحجناها انا بكلورو مثل .. بنل مثلا ب ..أقل
+
+108
+00:09:38,800 --> 00:09:46,290
+ال ether لو قلنا لكم اعملوه يعني شغلات ايشمعروفة
+
+109
+00:09:46,290 --> 00:09:51,030
+طيب الان لو المركب كبر وفي ايثر ايثر معناه
+
+110
+00:09:51,030 --> 00:09:55,610
+اكسوجينة بين كربونتين واجيتها بدي ارجع اسم المركب
+
+111
+00:09:55,610 --> 00:10:02,770
+كأنه ال cane عادي ابحث عن اطول سلسلة اطول سلسلة
+
+112
+00:10:02,770 --> 00:10:08,310
+تلاتة مركبة بروبين اربعة بيوتين خمسة بنتين و هكذا
+
+113
+00:10:08,310 --> 00:10:13,780
+طيب بعد ما اطول اطول سلسلة يعني هاي هذا مركبلاحظوا
+
+114
+00:10:13,780 --> 00:10:17,180
+هنا في carbon تنتين تلاتة لبروبل و هنا carbon
+
+115
+00:10:17,180 --> 00:10:21,920
+واحدة ايش أطول السلسلة لبروبل الآن تخيل لو هذا
+
+116
+00:10:21,920 --> 00:10:26,580
+الأزرق اللي هنا كانت Cl لكلور اللي على موقع واحد
+
+117
+00:10:26,580 --> 00:10:33,420
+ايش هتسموه المركب وان كلورو بروبل بدكوا تحددوا
+
+118
+00:10:33,420 --> 00:10:38,620
+الرقم الان اللي على موقع واحد مش كلور او مثل ال او
+
+119
+00:10:38,620 --> 00:10:40,780
+مثل اللي لها اسم مثوكسي
+
+120
+00:10:43,660 --> 00:10:52,760
+مثل ا ا مثوكسي طب لو كانت ا اثل اثوكسي لو كانت ا
+
+121
+00:10:52,760 --> 00:10:57,660
+فنل مثوكسي
+
+122
+00:10:57,660 --> 00:11:04,080
+مثل ا اثوكسي اثل
+
+123
+00:11:04,080 --> 00:11:10,420
+افنوكسي فنل افروبوكسي
+
+124
+00:11:13,650 --> 00:11:22,270
+هيبروبيل او ابيوتكسي ابيوتل او and so on واضح
+
+125
+00:11:22,270 --> 00:11:27,350
+فبنطول أطول سلسلة وبعدين المجموعات بنسميها يعني
+
+126
+00:11:27,350 --> 00:11:31,190
+مثلا هذا المركب هاي كاربون تنتين أطول سلسلة إذا
+
+127
+00:11:31,190 --> 00:11:37,540
+المركب إيش إيثان على نمرة واحد إيش عليه؟أو مثل
+
+128
+00:11:37,540 --> 00:11:43,040
+مثوكسي و إيش عليه كمان اكلور إذا هذا one chloro
+
+129
+00:11:43,040 --> 00:11:49,840
+one methoxy اثان هاي هذا المركب carbon 234 بيوتين
+
+130
+00:11:49,840 --> 00:11:56,560
+على نمره اتنين إيش عليه تلت ذرات معه بروبوكسي
+
+131
+00:11:56,560 --> 00:12:02,810
+بروبوكسي تلت ذرات معه هذا المركبلاحظوا إيثانول ال
+
+132
+00:12:02,810 --> 00:12:07,230
+alcohol أقوى من ال ether هنقول عنه واحد اتنين
+
+133
+00:12:07,230 --> 00:12:12,330
+تلاتة أربعة إذا هذا أي مركب واند يوتانول ضال على
+
+134
+00:12:12,330 --> 00:12:17,990
+نمرة تلاتة شو المجموعة اللي حملها؟مش اتوكسي كلور و
+
+135
+00:12:17,990 --> 00:12:23,730
+اتوكسي تمام حملة كلور الان الكلور هذه محمولة على
+
+136
+00:12:23,730 --> 00:12:27,510
+الكربون هذه ولا هذه تعون ال organic بيحطوها بين
+
+137
+00:12:27,510 --> 00:12:31,550
+جسين و بيقولوا الكلور على الكربون رقم اتنين لاحظوا
+
+138
+00:12:31,550 --> 00:12:36,490
+اتنين يعني كأنه كل هذه انحطت ايش بين جسين صار كام
+
+139
+00:12:36,490 --> 00:12:40,410
+نظام ترقيم عندى نظامين النظام الاصلي واحد اتنين
+
+140
+00:12:40,410 --> 00:12:43,890
+تلاتة اربعة و هنا الكلور لو اجتها انا بدي اقول one
+
+141
+00:12:43,890 --> 00:12:49,570
+primeإكلورو إيثوكس لو إجت هنا two prime إكلورو
+
+142
+00:12:49,570 --> 00:12:52,890
+إيثوكس و مرات بتلاحظون ممكن يختصروا ال prime لكن
+
+143
+00:12:52,890 --> 00:12:59,190
+الأحسن إذا الإنسان استعمل أكثر من نظام ترقيم أنه
+
+144
+00:12:59,190 --> 00:13:05,070
+يحط إيش ل prime واضح هذه الفكرة بدي أركز معاكوا
+
+145
+00:13:05,070 --> 00:13:12,140
+عليها فكرة أن الإنسان يستعملأكثر من نظام ترقيم في
+
+146
+00:13:12,140 --> 00:13:15,980
+نفس المُركّب خلّيني أعطيكوا عليها مثالين عند
+
+147
+00:13:15,980 --> 00:13:20,460
+اللزوم ممكن مثال من موضوعنا الـEthers ومثال من
+
+148
+00:13:20,460 --> 00:13:27,920
+موضوع الـH تاني يعني الترقيم ممكن نستعمل أكثر من
+
+149
+00:13:27,920 --> 00:13:35,300
+نظام ترقيم لو يا تورا أعطيتكم المُركّب هذا و
+
+150
+00:13:35,300 --> 00:13:44,270
+كتبت هنا OH و كتبت هنا Zوحطينا هنا PR نفترض هذا
+
+151
+00:13:44,270 --> 00:13:50,710
+المركب جاينا سمى المركب التالي الآن هذا أفضل شيء
+
+152
+00:13:50,710 --> 00:13:57,590
+أسميه كالكين واضح؟ أطول سلسلة و أطول سلسلة حاملة
+
+153
+00:13:57,590 --> 00:14:06,330
+OHإذا هكسانول الان ال all عشان تكون أقل ترقيم 1,2
+
+154
+00:14:06,330 --> 00:14:12,190
+,3,4,5,6 إذا هذا لو ماكنش عليه هذه الإضافة اللي
+
+155
+00:14:12,190 --> 00:14:20,110
+موجودة هنا إيش هتسموه two hexanol واضح؟ الآن ال
+
+156
+00:14:20,110 --> 00:14:27,310
+two تاب على ترقيم إيش؟طب على ترقيم السلسلة لو هذه
+
+157
+00:14:27,310 --> 00:14:33,870
+إجت بنزينة كان كل كشاطرين four phenyl two hexanol
+
+158
+00:14:33,870 --> 00:14:39,030
+مش هتتغلبوا فيها لو هذه بنزينة هي four phenyl two
+
+159
+00:14:39,030 --> 00:14:45,010
+hexanol الآن إجت عليها بروم طبعا هذه موجودة وين؟
+
+160
+00:14:45,010 --> 00:14:48,150
+على four وهي ال four هذا اللي هو الرقم اللي هنا
+
+161
+00:14:48,150 --> 00:14:57,370
+لكن هي بالظبطاه اعملوا ترقيم تاني three
+
+162
+00:14:57,370 --> 00:15:03,090
+bromophenyl صارت واضحة الفكرة؟ اه three
+
+163
+00:15:03,090 --> 00:15:06,270
+bromophenyl
+
+164
+00:15:06,270 --> 00:15:09,470
+three
+
+165
+00:15:09,470 --> 00:15:14,580
+bromophenyl two hexanolالان بهذا المثال كم نظام
+
+166
+00:15:14,580 --> 00:15:18,780
+ترقيم استعملت حتى ممكن بالألوان تشايفينهم كيف
+
+167
+00:15:18,780 --> 00:15:22,820
+صاروا واضحين هذا ال four تبقى لهان ان المجموعة
+
+168
+00:15:22,820 --> 00:15:26,300
+اللتي بين القوسين موجودة على الموقع أربعة على
+
+169
+00:15:26,300 --> 00:15:32,460
+السنسلة لكن هذا ترقيم تاني عشان هيك الأنسب لهذا
+
+170
+00:15:32,460 --> 00:15:37,000
+الترقيم التاني اللي كنت كاتبه بالأزرقإن أحطله إيش
+
+171
+00:15:37,000 --> 00:15:44,720
+الـ prime طبعا هذا بيمنعش أنه بزام فيه تاني ممكن
+
+172
+00:15:44,720 --> 00:15:50,520
+يصير كمان تالت و باجيتها ممكن أحطله double prime
+
+173
+00:15:50,520 --> 00:15:56,720
+وارد بتصير الأمور أصعب لكن المبدأ بأمل أنه صار إيش
+
+174
+00:15:56,720 --> 00:15:58,440
+واضح عندكم
+
+175
+00:16:04,790 --> 00:16:11,250
+لو طلبنا منكم تسمولنا
+
+176
+00:16:11,250 --> 00:16:27,510
+هذا المركب على سبيل المثال جاكوا
+
+177
+00:16:27,510 --> 00:16:32,870
+هذا في الامتحان هو زيكك BJ الآن
+
+178
+00:16:32,870 --> 00:16:37,720
+هتفكروا بإيش؟بأطول سلسلة ما تشوفوش تفكروا بال إيثا
+
+179
+00:16:37,720 --> 00:16:41,220
+لإن لو قلت هذه مثل طب وش كلها المجموعة التانية؟
+
+180
+00:16:41,220 --> 00:16:44,320
+مالهاش اسم و لو قلت هذه فنل شو المجموعة التانية؟
+
+181
+00:16:44,320 --> 00:16:50,400
+مالهاش اسم لكن ان نقول في سلسلة و هذه يا مسهلها
+
+182
+00:16:50,400 --> 00:16:57,960
+مثوكسي و في سلسلة و هذه يا مسهلها فينوكسي القمر
+
+183
+00:16:57,960 --> 00:17:04,070
+بيكون إيش؟سهل الان اطول سلسلة فيها double bond اذا
+
+184
+00:17:04,070 --> 00:17:09,690
+المركبة ال keen ال keen واحد اتنين تلاتة اربعة
+
+185
+00:17:09,690 --> 00:17:19,310
+خمسة ستة سبعة two heptane واضح two heptane الان
+
+186
+00:17:19,310 --> 00:17:26,250
+عليه ع موقع تلاتة methoxy وع موقع ستة phenoxy
+
+187
+00:17:26,250 --> 00:17:34,940
+بالترتيبthree methoxy six phenoxy
+
+188
+00:17:34,940 --> 00:17:42,280
+two heptane وكفى
+
+189
+00:17:42,280 --> 00:17:45,740
+الله المؤمنين القتال بس اللى بتسمى زيك بنحطله
+
+190
+00:17:45,740 --> 00:17:54,320
+تمانية من عشرة لسه موصلناش للعشرة من عشرة ليش ضايل
+
+191
+00:17:54,320 --> 00:18:00,650
+في التسمية ماجيبتهوشDouble bond اول ما نشوف double
+
+192
+00:18:00,650 --> 00:18:05,370
+bond فاكره ب Z و E و S و Trans و اول ما نشوف
+
+193
+00:18:05,370 --> 00:18:08,890
+chiral center فاكره بال R و S الان ايه double bond
+
+194
+00:18:08,890 --> 00:18:13,350
+ايش عليها اتشوميثل مختلفتان و هذا ال double bond
+
+195
+00:18:13,350 --> 00:18:19,250
+ايش عليها اوميثل و carbon مختلفتان اذا هذا المركب
+
+196
+00:18:19,250 --> 00:18:23,310
+منه واحد ولا اتنين اتنين اتنين لو قلتلكوا ارسموا
+
+197
+00:18:23,310 --> 00:18:27,810
+العيزو مرة تانية ايش أسهل طريقةلأ خدوه نحط ال اتش
+
+198
+00:18:27,810 --> 00:18:34,190
+تحت و الميثل فوق الان اتش و ميثل من الأعلى الميثل
+
+199
+00:18:34,190 --> 00:18:38,770
+الميثل لحظه هذه اللي ماتروه كهيك ميثل مش اتش انا
+
+200
+00:18:38,770 --> 00:18:43,030
+متعمد اتروه كهيك عشان أبقوا منتبهين لها ميثل اه هي
+
+201
+00:18:43,030 --> 00:18:51,270
+هذه الأعلى O و Carbon من الأعلى الان الأعلى على
+
+202
+00:18:51,270 --> 00:19:00,660
+جهة واحدة اذا هذا المركب Zهذا الاسم الكامل هذا دخل
+
+203
+00:19:00,660 --> 00:19:04,640
+فيه جزء من ال الكينز وجزء من ال الكينز وجزء من ال
+
+204
+00:19:04,640 --> 00:19:09,660
+ethers وهكذا العلم يصبح تجميعي لكل شيء درسناه
+
+205
+00:19:09,660 --> 00:19:15,960
+واتعلمناه اذا Z ثريميثوكسي سيكس فينوكسي توهيبتين
+
+206
+00:19:15,960 --> 00:19:18,140
+بهذا الشكل بنسمي المركب
+
+207
+00:19:22,520 --> 00:19:25,900
+طبعا ممكن تكون chiral center على طول بلاحظ R ولا S
+
+208
+00:19:25,900 --> 00:19:30,640
+هنا في chiral center لكن انا مش مركز عليه دايما
+
+209
+00:19:30,640 --> 00:19:34,340
+يعني ال chiral center اذا رسمته زي هيك معناه ذلك
+
+210
+00:19:34,340 --> 00:19:40,300
+انا طالبه منكم بس هنا بالتأكيد في chiral center لو
+
+211
+00:19:40,300 --> 00:19:43,800
+بدى افترض ان هدول بهذا الشكل المبينين وجهته بتكون
+
+212
+00:19:43,800 --> 00:19:49,150
+حددهدائما الكايرال سنتر إذا رسمناه كيا زي الصليب
+
+213
+00:19:49,150 --> 00:19:53,210
+معنا ذلك إحنا مركزين عليه مع ذلك تركينه بس هو أكيد
+
+214
+00:19:53,210 --> 00:19:59,350
+يا R يا S بس معرفين كوا ان كوا اتجاوبوا واضحة
+
+215
+00:19:59,350 --> 00:20:03,270
+الفكرة يعني يوم ما بدي الكايرال سنتر لو كنت بدي
+
+216
+00:20:03,270 --> 00:20:07,690
+بالتأكيد الكايرال سنتر هنا هتلاقوني رسمت الكيا زي
+
+217
+00:20:07,690 --> 00:20:17,330
+هيك O فنل CH3 H ال Aهنا بالتأكيد في عندكم chiral
+
+218
+00:20:17,330 --> 00:20:20,990
+center و المفروض تقدروا تعملوه و تقدروا تقولوا انه
+
+219
+00:20:20,990 --> 00:20:26,570
+أقل حاجة ال H ال O أعلى اشي بعدين الكربون المتصلة
+
+220
+00:20:26,570 --> 00:20:33,990
+بكربونات بعدين هذه S إذا chiral center واحد بلزمش
+
+221
+00:20:33,990 --> 00:20:40,170
+أحط له رقم إذا أكثر ممكن أحدد وين موقعه واضح؟ كل
+
+222
+00:20:40,170 --> 00:20:42,210
+شيء ممكن أدخله في الاسم
+
+223
+00:21:04,730 --> 00:21:09,810
+الان بالنسبة لل ethers استعملوا سابقا كمواد مخدرة
+
+224
+00:21:09,810 --> 00:21:14,670
+anesthetics والان بعض المشتقات منها زي هذا المركب
+
+225
+00:21:14,670 --> 00:21:17,450
+اللي فيه ذرات floro و chloro بناهاش نحفظه اسمه
+
+226
+00:21:17,450 --> 00:21:20,790
+penanthrene او هذا اللي فيه floro و chloro
+
+227
+00:21:20,790 --> 00:21:25,810
+enanthrene تستعمل في التخدير الطبي ال halogenated
+
+228
+00:21:25,810 --> 00:21:28,970
+ethers they are common anesthetics anesthetics
+
+229
+00:21:28,970 --> 00:21:33,650
+يعني مواد تستخدم في التخدير الطبيبدنا ننتبه لنقطة
+
+230
+00:21:33,650 --> 00:21:37,830
+كتير مهمة مش هنفصل فيها لكن الآن بنحكيها اللي ال
+
+231
+00:21:37,830 --> 00:21:42,410
+ether إذا خزنا لفترة طويلة بالذات بعد ما نفتح ال
+
+232
+00:21:42,410 --> 00:21:49,650
+bottle و يتعرض لل oxygenبيعمل مادة متفجرة peroxide
+
+233
+00:21:49,650 --> 00:21:54,530
+وبالتالي ممكن الشخص يجي يسخله طبعا مش عليها مباشرة
+
+234
+00:21:54,530 --> 00:21:59,950
+على سخان كهربائي مغلق اللي بنسميه tablet يكون فيه
+
+235
+00:21:59,950 --> 00:22:04,380
+المواد المتفجرة يروح ينفجر فيهالان هذه المواد
+
+236
+00:22:04,380 --> 00:22:08,320
+المتفجرة أشهر إيثر عادة بيستخدم اللي هو الـ
+
+237
+00:22:08,320 --> 00:22:13,800
+Diethyl Ether الان هذا لو انخزن لفترة طويلة بتفعل
+
+238
+00:22:13,800 --> 00:22:18,600
+مع الأكسجين بيعمله مركب زي هذا بيروكسايد هذا
+
+239
+00:22:18,600 --> 00:22:23,680
+البروكسايد ايش ماله؟Explosive الآن حسب كمية
+
+240
+00:22:23,680 --> 00:22:28,280
+الخزانة لو اتخزن كتير في جو سيء ممكن يعمل peroxide
+
+241
+00:22:28,280 --> 00:22:32,640
+ويترسب و تشوفوا بعينكم ان في قلب البوتل ال ether
+
+242
+00:22:32,640 --> 00:22:37,260
+مادة صلبة لو كانت بكمية صغيرة ممكن تكون دايب وما
+
+243
+00:22:37,260 --> 00:22:41,610
+تشوفوش بالعينينفي كل الأحوال لما بتحولوا لجزء عملي
+
+244
+00:22:41,610 --> 00:22:44,650
+أو بتاخدوا في يوم من الأيام جزء عملي المفروض
+
+245
+00:22:44,650 --> 00:22:48,530
+تفاصيل كيف نفحص ال ether كيف نتأكد منه قبل ما
+
+246
+00:22:48,530 --> 00:22:53,690
+نشتغل عليه هذا الأمر بتتعلموه الان لو في المستقبل
+
+247
+00:22:54,160 --> 00:22:58,620
+أشتغلت بكالوريوس، ماجستير، باحث في إيثر تسخين، في
+
+248
+00:22:58,620 --> 00:23:02,740
+هذه اللحظة خدوا كلمة واحدة إن الإيثر في منه خطر أن
+
+249
+00:23:02,740 --> 00:23:06,820
+يكون مواد متفجرة يوم ما يطلب منكوا حقيقة تشتغلوا و
+
+250
+00:23:06,820 --> 00:23:10,820
+تسخنوا بالإيثر ارجعوا لهذه المعلومة في كل كتب
+
+251
+00:23:10,820 --> 00:23:16,130
+العمل بدلكم بتفاصيل أكتر كيف تتأكدواإنه هالمادة
+
+252
+00:23:16,130 --> 00:23:19,850
+موجودة ولا لأ و لو موجودة كيف تتخلصوا منها و كل
+
+253
+00:23:19,850 --> 00:23:23,350
+الأشياء التفصيلية هذه لكن خلوا في ذهنكوا ان ال
+
+254
+00:23:23,350 --> 00:23:27,950
+ether مع سوق التخزين و في وجود ال oxygen بيعمل إيش
+
+255
+00:23:27,950 --> 00:23:36,090
+explosivematerials الان كيف بنحضر ال ethers اخدنا
+
+256
+00:23:36,090 --> 00:23:42,310
+احنا تحضير لل ethers لما درسنا ال alkenes و ال
+
+257
+00:23:42,310 --> 00:23:48,250
+alcohols قولنا ان ال alcohol لو سخناه عند 180 درجة
+
+258
+00:23:48,250 --> 00:23:54,460
+مئوية كان يعمل حذف للميه و يعطيناالالكين و عند 140
+
+259
+00:23:54,460 --> 00:23:59,520
+درجة مئوية بيعطينا ال ether متذكرين هذه المعادلة
+
+260
+00:23:59,520 --> 00:24:03,300
+في كيمية ال alcohols اذا ال ethers they can be
+
+261
+00:24:03,300 --> 00:24:07,000
+prepared from alcohols طبعا انا لما بحكي عن ether
+
+262
+00:24:07,000 --> 00:24:11,450
+هنا بحكي عن ال symmetrical ethersماذا؟ إن إيثانول
+
+263
+00:24:11,450 --> 00:24:15,450
+يهاجم على إيثانول ويفقد ميّه وهذه المعادلة سابق
+
+264
+00:24:15,450 --> 00:24:20,190
+وضحتها إيها إيثانول زي إيثانول يخص منهم ميّه يعني
+
+265
+00:24:20,190 --> 00:24:24,770
+هذه المعادلة لو أريدها موزنة، ماذا أكتب هنا؟ H2O
+
+266
+00:24:24,770 --> 00:24:29,110
+واضح؟ جزء يهاجم على التانى ويطلع ميّه ويكون له
+
+267
+00:24:29,110 --> 00:24:34,880
+إيثرالان هذا الـ symmetrical ether ان الاثانول
+
+268
+00:24:34,880 --> 00:24:39,720
+اتفعل مع نفسه طيب يا تورا الان بيجيني السؤال لو
+
+269
+00:24:39,720 --> 00:24:45,320
+بدي un symmetrical ether يعني بدي ether في اثل و
+
+270
+00:24:45,320 --> 00:24:51,400
+مثل ايش اول شيء ممكن يخطر ع بالكم يعني لو بدي انا
+
+271
+00:24:51,400 --> 00:24:56,000
+دايم في ال ether شو اللي بسخنه مع الحامض؟ميثانول
+
+272
+00:24:56,000 --> 00:24:59,760
+لو بدى داي إثل إيثار شو اللى بسخنه مع الحامض
+
+273
+00:24:59,760 --> 00:25:05,540
+إثانول طيب لو بدى مثل إثل إيثار شو بدى أسخن مع
+
+274
+00:25:05,540 --> 00:25:09,500
+الحامض واضحة
+
+275
+00:25:09,500 --> 00:25:17,160
+الفكرة لو بدى مثل إثل إيثارأو إثل مثل إيثار الأن
+
+276
+00:25:17,160 --> 00:25:22,520
+انتبهوا معي أي واحدة ممكن تبدأ التفكير في مثل إثل
+
+277
+00:25:22,520 --> 00:25:28,400
+إيثار تقول باخد ال two alcohols يعني باخد مثل OH
+
+278
+00:25:28,400 --> 00:25:40,120
+زائد إثل OH بده يطلع لمثل OH إيش رأيكوا بهذا
+
+279
+00:25:40,120 --> 00:25:40,780
+الكلام؟
+
+280
+00:25:43,190 --> 00:25:47,830
+بطلع لكن هنا في مشكلة انه انا لما بخلط بخلطش جزئ و
+
+281
+00:25:47,830 --> 00:25:52,030
+جزئ بخلط عدد كبير يعني لو خلطت mall و mall يعني
+
+282
+00:25:52,030 --> 00:25:55,990
+انا خلطت 6 في 10 او 23 من هذا مع 6 في 10 او 23 من
+
+283
+00:25:55,990 --> 00:26:00,290
+هذا الان كلهم موجودين خليني اعملها على النطاق
+
+284
+00:26:00,290 --> 00:26:06,110
+البسيط لو على نطاق جزيئين هذا ال ethanol و هذا ال
+
+285
+00:26:06,110 --> 00:26:09,600
+methanol و خلطتهم و قلتلهم يلا اتفاعلواأيش
+
+286
+00:26:09,600 --> 00:26:13,600
+الاحتمالات؟ هم بتفعلوا، سمعين؟ الان ممكن يلتقي
+
+287
+00:26:13,600 --> 00:26:20,260
+الاثل مع الاثل بي اثل اثر ممكن يلتقي المثل مع
+
+288
+00:26:20,260 --> 00:26:27,420
+المثل بي مثل اثر ممكن يلتقي الاثل مع المثل اثر مثل
+
+289
+00:26:27,420 --> 00:26:35,740
+اثر اذا هنا كم ناتج نتوقع؟ تلاتة مثل او مثل اثل او
+
+290
+00:26:35,740 --> 00:26:41,970
+اثلأو إثل أو ميثل بيطلع لكن مع اتنين تانين يعني
+
+291
+00:26:41,970 --> 00:26:46,310
+بيطلع خليط من تلت مراكبات و هات وفصلهم هل هذا
+
+292
+00:26:46,310 --> 00:26:51,890
+الكلام الكيميائي بيحبه؟ اطلاقا لا ولذلك اي حد
+
+293
+00:26:51,890 --> 00:26:56,590
+بيقول انه تحضير الإثل مثل إيثر بخلط الكحولينوهي
+
+294
+00:26:56,590 --> 00:27:00,530
+طلع الجواب بنقوله غلط لأنك طلعت تلت نواتج وبعدين
+
+295
+00:27:00,530 --> 00:27:05,170
+بدنا نشتغل نعمل انفصل وتقطير، هذه عملية إيش مالها؟
+
+296
+00:27:05,170 --> 00:27:09,610
+متعبة ولذلك بنحول على طريقة تانية في تحضير الـ
+
+297
+00:27:09,610 --> 00:27:15,160
+Unsymmetrical ethos أيضا بنبتدأ فيها من وين؟من
+
+298
+00:27:15,160 --> 00:27:20,340
+الكحولات الان الكحولات واحد منهم وبشكل عام اللي
+
+299
+00:27:20,340 --> 00:27:25,520
+بيكون primary بنخليه يصير chloride يعني هذا لو
+
+300
+00:27:25,520 --> 00:27:32,900
+فعلناه مع ال BCl3 ايش هيصير CH3 CH2 بدل ما هو OH
+
+301
+00:27:32,900 --> 00:27:39,020
+Cl حولته ل chloride والتالي بحوله ل O minus كيف
+
+302
+00:27:39,020 --> 00:27:43,010
+الكحول بيصير O minus؟بالتفاعل مع السوديوم
+
+303
+00:27:43,010 --> 00:27:48,290
+هيدروكسايد؟ قلنا لأ بالتفاعل مع السوديوم أو
+
+304
+00:27:48,290 --> 00:27:51,890
+السوديوم هيدرايد هدولة التنين اللي بيصيروا يعني
+
+305
+00:27:51,890 --> 00:27:57,750
+هذا لو فعلته مع السوديوم بيصير مثل O minus and A
+
+306
+00:27:57,750 --> 00:28:04,840
+plusهيو ب فلاسك لحاله و هذا ب فلاسك لحاله لسه
+
+307
+00:28:04,840 --> 00:28:09,360
+ماخلطتهمش يعني إيجي إنسان أعطاكم هاي إيثانول و هاي
+
+308
+00:28:09,360 --> 00:28:13,420
+ميثانول هذا بالفلاسك واحد منهم بخليه ايش O minus
+
+309
+00:28:13,420 --> 00:28:19,900
+والتاني اكلورايد بعدين بضيف التانين على بعض بعدين
+
+310
+00:28:19,900 --> 00:28:23,600
+بضيف ايش التانين على بعض لو بضيف هذا على هذا هذا
+
+311
+00:28:23,600 --> 00:28:30,490
+ال O وين هتهاجم؟و إيش هتطرد؟ ال CL تفاعل الإقدال
+
+312
+00:28:30,490 --> 00:28:37,590
+اللي أخدناه ب chapter 6 لاحظوا إيش الناتج CH3 CH2O
+
+313
+00:28:37,590 --> 00:28:45,960
+مثل أو CH3 بس مركب واحدإذا أنا لما بدي ال un
+
+314
+00:28:45,960 --> 00:28:51,060
+symmetrical ethers لأخلط الكحولين مع بعض لأ واحد
+
+315
+00:28:51,060 --> 00:28:56,240
+منهم بحاوله ل O minus و واحد منهم بحاوله الى
+
+316
+00:28:56,240 --> 00:29:00,000
+chloride او bromide و بعدين بضيفهم مع بعض بطلعولي
+
+317
+00:29:00,000 --> 00:29:04,780
+فقط ناتج واحد هذه الطريقة في التحضير اسمها طريقة
+
+318
+00:29:04,780 --> 00:29:10,230
+السيد William Sun William Sun's synthesisWilliam
+
+319
+00:29:10,230 --> 00:29:14,410
+Sun's synthesis موجودة عندكم في ال slides وهين
+
+320
+00:29:14,410 --> 00:29:18,770
+وضحت بطريقة تانية انه مانخلطش الكحولين مع بعض
+
+321
+00:29:18,770 --> 00:29:24,090
+اطلاقا اطلاقا هذا الكلام مابيصيرش واضح الفكرة؟
+
+322
+00:29:30,200 --> 00:29:34,580
+نشوف مرة تانية الـ Williamson's synthesis هاي مثلا
+
+323
+00:29:34,580 --> 00:29:40,500
+ROH مع ن إيه؟ شو أعطاني؟ R O minus هذا الـ charged
+
+324
+00:29:40,500 --> 00:29:45,300
+nucleophile و R X كوّنتها أساسا من الكحول لما أضيف
+
+325
+00:29:45,300 --> 00:29:50,800
+الـ R O minus على الـ R X أي تفاعل بعمل؟ الإبدال
+
+326
+00:29:50,800 --> 00:29:53,380
+ROR
+
+327
+00:29:54,350 --> 00:29:59,510
+الان اتخيلوا لو اتيكم how can you prepare this
+
+328
+00:29:59,510 --> 00:30:09,870
+ether فنل O CH2 CH3 الفكرة ان واحد منهم بدي اخليه
+
+329
+00:30:09,870 --> 00:30:15,330
+يعني انا بدي ابدأ من فنل OH و F OHلكن مين منهم بدي
+
+330
+00:30:15,330 --> 00:30:20,830
+أخليه O- ومين منهم بدي أخليه CL الان أنا قولت اللي
+
+331
+00:30:20,830 --> 00:30:25,610
+باخليه CL ال primary أو ال مثل إذا وجدت ما هو ال
+
+332
+00:30:25,610 --> 00:30:28,790
+مثل أفضل من ال primary يا ال primary يا المثل
+
+333
+00:30:28,790 --> 00:30:34,720
+وبناء على ذلك الفن ال OHهذا بخليه ايش مع ال sodium
+
+334
+00:30:34,720 --> 00:30:37,980
+او مع ال sodium hydroxide بيمشي اساسا لان الفينول
+
+335
+00:30:37,980 --> 00:30:41,800
+بتفاعل مع ال sodium hydroxide بيصير فينيل O minus
+
+336
+00:30:41,800 --> 00:30:48,620
+هي ال nucleophile فينيل O minus وهذا ال ethanol
+
+337
+00:30:48,620 --> 00:30:55,540
+بقدر انا اخليه من خلال التفاعل مع ال BCL3 CH3
+
+338
+00:30:55,540 --> 00:31:03,380
+CH2CL اكيدالان لو فعلت هذا ال phenoxide هنا بيطرد
+
+339
+00:31:03,380 --> 00:31:09,330
+ال X و بيعطينا المركب المطلوب ولا لأ؟واضح؟ فالفكرة
+
+340
+00:31:09,330 --> 00:31:13,150
+في هذا النوع .. الفكرة في هذا النوع من الأسئلة لما
+
+341
+00:31:13,150 --> 00:31:17,150
+أجيبلكوا ether معين و أقولكوا كيف تحضروه أنكم
+
+342
+00:31:17,150 --> 00:31:20,450
+تعرفوا مين اللي بدي أخليه منه O minus مين اللي بدي
+
+343
+00:31:20,450 --> 00:31:24,270
+أخليه chloride الآن اللي بدي أخليه ال chloride يا
+
+344
+00:31:24,270 --> 00:31:29,630
+ال methyl يا ال primary هاي مسألة هنا شايفينها
+
+345
+00:31:29,630 --> 00:31:37,760
+تيرتشاريب بيوتلبروبل إيثار كيف يمكنك تجهيزه بدأ من
+
+346
+00:31:37,760 --> 00:31:44,680
+الكحول ارسم الانتوا الكحول احفظوا انتوا ايش
+
+347
+00:31:44,680 --> 00:31:52,260
+المطلوب تيرتشار بيوتل بروبل إيثار يعني كأنه عندكم
+
+348
+00:31:52,260 --> 00:32:01,200
+انتوا معطى هاي ال تيرتشار بيوتل وهاي البروبانول
+
+349
+00:32:01,200 --> 00:32:06,700
+هاي الانتوا الكحولالان ما طريقة التحضير واحد منهم
+
+350
+00:32:06,700 --> 00:32:15,000
+O- والتاني CL مين اللي بدي أخليه CL ال primary هذا
+
+351
+00:32:15,000 --> 00:32:20,300
+ال alcohol tertiary هذا ال alcohol ال primary إذا
+
+352
+00:32:20,300 --> 00:32:27,880
+هذا بعمله مع ال BCL3 هيوصار CL وهذا بعمله مع ال NA
+
+353
+00:32:27,880 --> 00:32:36,510
+هيوصار O-الان اخلطوا هادولا التانين مع بعض ايش
+
+354
+00:32:36,510 --> 00:32:40,910
+النتيجة؟
+
+355
+00:32:40,910 --> 00:32:47,640
+هادي هتهاجم هان و تطردالـ CL المُركّب المطلوب مرات
+
+356
+00:32:47,640 --> 00:32:51,860
+لما يقولوا المُركّب المطلوب بيحطوا رمز TM مر عليكم
+
+357
+00:32:51,860 --> 00:32:55,620
+إيش يعني الـTM؟ زي ما في الهندس لما بتخلصوا الشغلة
+
+358
+00:32:55,620 --> 00:33:00,020
+بتقولوا هو المطلوب إثباته الآن TM يعني ال target
+
+359
+00:33:00,020 --> 00:33:05,020
+molecule يعني الجزء المطلوب target إيش target؟
+
+360
+00:33:05,020 --> 00:33:11,520
+molecule الجزء المطلوب يعنييعني الـTM بلغة الكيميا
+
+361
+00:33:11,520 --> 00:33:15,820
+وهو المطلوب طبعاً هيكون زي هيك O وهي واحد، اتنين،
+
+362
+00:33:15,820 --> 00:33:21,100
+تلاتة واضحات؟
+
+363
+00:33:21,100 --> 00:33:24,580
+الان لو واحدة عكست عملت هذا ال chloride وهذا الـO
+
+364
+00:33:24,580 --> 00:33:29,760
+minus بطلعش عندها يعني لو السؤال عليه عشر علامات
+
+365
+00:33:29,760 --> 00:33:35,900
+مجاملة نحط لها تلاتة او تنين لأنه
+
+366
+00:33:35,900 --> 00:33:42,040
+عملياً مابصيرشواضح؟ عملياً ما بيصيرش افهمنا هذه
+
+367
+00:33:42,040 --> 00:33:59,680
+الفكرة بوليام سانس سينتيسيز الان
+
+368
+00:33:59,680 --> 00:34:06,640
+ال ethers اتكونت طيب يا تورا ممكن تنكسبممكن تتفاعل
+
+369
+00:34:06,640 --> 00:34:10,900
+إلا بس تفاعل واحد فقط اللي هو الـ cleavage of
+
+370
+00:34:10,900 --> 00:34:16,020
+ether يعني ممكن ينكسر نص سيلة كيف بتم ال cleavage
+
+371
+00:34:16,020 --> 00:34:23,220
+of ether باستعمال الحامض القوي HI الـ HI بيهاجم
+
+372
+00:34:23,220 --> 00:34:30,020
+عادة في اليود وهذا هيو ماشي وين بده يروحالـ W مع
+
+373
+00:34:30,020 --> 00:34:33,200
+.. لأ على الـ Carbon اللي جنب الـ O الـ U السالب
+
+374
+00:34:33,200 --> 00:34:36,080
+.. الـ O السالب على الـ Carbon من بين الموجبات الـ
+
+375
+00:34:36,080 --> 00:34:39,360
+principal يعني هنا هذه الـ Carbon الموجبة و هذه
+
+376
+00:34:39,360 --> 00:34:43,860
+الموجبة هذه السالبة جزئياً لما بده يروح .. وين بده
+
+377
+00:34:43,860 --> 00:34:47,880
+يروح؟ على الموجب .. الآن لاحظوا معي لما بده يروح
+
+378
+00:34:47,880 --> 00:34:52,820
+على الموجب هيو ماشي ورايح على الموجب اليمين و لا
+
+379
+00:34:52,820 --> 00:34:58,480
+الموجب الشمالي افهمتوا وين السؤال؟ الآن على الـ
+
+380
+00:34:58,480 --> 00:35:05,900
+Primaryهذا المحور الان وين ال primary هان؟ وين ال
+
+381
+00:35:05,900 --> 00:35:12,420
+primary هان؟ ولذلك لما تطلع النتيجة هذا الجزء اللي
+
+382
+00:35:12,420 --> 00:35:18,340
+بيبقى معه ال O هياخد ال H هيصير فين ال O؟ H هياخد
+
+383
+00:35:18,340 --> 00:35:25,180
+ال H وهذا الجزء CH3 CH2 هيصير ايش؟Iodide شوفنا كيف
+
+384
+00:35:25,180 --> 00:35:29,780
+الـ cleavage الان هذا ماشي هنا ايه هنا؟ هيعطيني
+
+385
+00:35:29,780 --> 00:35:37,660
+CH3 CH2 CH2 I هذا معلوم CH3 CH2 CH2 I و هذا اللي
+
+386
+00:35:37,660 --> 00:35:43,380
+ضلت معه ال O شو هيصير OH هذا اللي هو ال cleavage
+
+387
+00:35:43,380 --> 00:35:50,680
+of ether هذا اللي هو ال cleavage of ether
+
+388
+00:35:52,990 --> 00:35:58,330
+باستعمال الـ HI غير هيك مش مشهور تفاعلات لل إيثارز
+
+389
+00:35:58,330 --> 00:36:03,310
+يعني هو تفاعل واحد الـ cleavage الكسر الآن في
+
+390
+00:36:03,310 --> 00:36:08,450
+إيثارز حلقية اسمها الـ Epoxides أخدتها بالتفصيل هي
+
+391
+00:36:08,450 --> 00:36:12,990
+و تفاعلاتها ولا لأ لما أخدنا تفاعلات الالكين و
+
+392
+00:36:12,990 --> 00:36:16,990
+قلنا الكين مع pear acid Epoxides وأخدتوا كمان
+
+393
+00:36:16,990 --> 00:36:21,670
+الحلقة بتفتح هنا واضحة
+
+394
+00:36:21,670 --> 00:36:26,890
+الفكرةأخدتوا كيف الحلقة بتفتح و كل هذا الكلام كل
+
+395
+00:36:26,890 --> 00:36:32,530
+هذه ال slides نفسها أخدناها الآن بيجينا آخر slide
+
+396
+00:36:32,530 --> 00:36:37,090
+اليوم عندنا هل ال cyclic ethers بس الحلقات
+
+397
+00:36:37,090 --> 00:36:43,430
+الثلاثية لأ طبعا في cyclic ethers حلقات أكبر يعني
+
+398
+00:36:43,430 --> 00:36:49,540
+مثلا الحلقة الخماسية هذا ether ORRcyclic ether
+
+399
+00:36:49,540 --> 00:36:54,820
+اسمه tetrahydrofuran باختصار THF هذا solvent مشهور
+
+400
+00:36:54,820 --> 00:37:02,360
+طب هذه الحلقة اسمها tetrahydropyrene هذا في ether
+
+401
+00:37:02,360 --> 00:37:08,060
+و ether دي ether ORR و ORR اسمه ديوكسين مركب
+
+402
+00:37:08,060 --> 00:37:14,300
+كارسينوجينيك مركب كارسينوجينيك وسام في مركبات حلوة
+
+403
+00:37:14,300 --> 00:37:19,260
+طلع عليها منظرها حلو ولا لأو دايما الاشي المنظرة
+
+404
+00:37:19,260 --> 00:37:23,980
+حلو بيحاولوا يعطوا اسم ايش اسم حلو يعني العلماء
+
+405
+00:37:23,980 --> 00:37:28,160
+لما بيعملوا اختراع لشغل مرات بيعملوا مسابق مين
+
+406
+00:37:28,160 --> 00:37:32,640
+يخترعلها اسم حلو و لو بتفتشوا مثلا لما اكتشفوا
+
+407
+00:37:32,640 --> 00:37:39,640
+نايلون كشيء جميل ليش في النهاية سموه نايلون؟اسم
+
+408
+00:37:39,640 --> 00:37:44,360
+حلو عملوا مسابقات لحد ما حد اخترع لهم اسم جميل زي
+
+409
+00:37:44,360 --> 00:37:47,520
+اللي بده يفتح بوتيك ولا اشي مش بيحاول يلاجيله اسم
+
+410
+00:37:47,520 --> 00:37:52,380
+حلو هدول عشانهم حلوين شو صموهم ال crown ethers
+
+411
+00:37:52,380 --> 00:37:58,020
+هدول اكتشفوهم مش زمان يعني بعد ال 1980 تقريبا
+
+412
+00:37:58,020 --> 00:38:02,460
+واللي اكتشفوهم أخدوا عليهم جائزة نوبل في الكيميا
+
+413
+00:38:02,460 --> 00:38:09,600
+بال 1987 اسمهم ايش ال crown ethersإيش قصته ما دول
+
+414
+00:38:09,600 --> 00:38:15,220
+ال crown ethers؟ أكسجين بعدين CH2 CH2 بعدين أكسجين
+
+415
+00:38:15,220 --> 00:38:19,980
+CH2 CH2 بعدين أكسجين هم لاحظين أكثر من ether في
+
+416
+00:38:19,980 --> 00:38:23,820
+بعض طب لما بدهم يسموهم قالوا كيف بدنا نسميهم؟ هاي
+
+417
+00:38:23,820 --> 00:38:29,780
+واحدة و هادي أكبر و هادي أكبر قال بسيطة استعملوا
+
+418
+00:38:29,780 --> 00:38:34,140
+اسم ال crown okay crown قالوا قبل ال crown عدوا كل
+
+419
+00:38:34,140 --> 00:38:39,130
+الذرات المحيطة يعني لو بديت أعد من هنا واحدأتنين
+
+420
+00:38:39,130 --> 00:38:43,550
+تلاتة أربعة خمسة لفتهم كلهم بلاحظ انه العدد الكل
+
+421
+00:38:43,550 --> 00:38:48,390
+اتنائش فبروح بكتب ال twelve يعني العدد الكل قداش
+
+422
+00:38:48,390 --> 00:38:53,730
+اتنائش ال crown كام اكسوجينة عندكم اربعة twelve
+
+423
+00:38:53,730 --> 00:38:59,930
+crown four الان هذا العدد الكل خمس عشر خمس
+
+424
+00:38:59,930 --> 00:39:05,790
+اكسوجينات شو حيصير fifteen crown five هذا
+
+425
+00:39:10,900 --> 00:39:17,000
+واضح؟طيب فى ناس لسه مقتنعوش بيقولوا يعنى ليش أخدوا
+
+426
+00:39:17,000 --> 00:39:21,760
+جائزة نوبل على شغل زى هذه يعنى سويانا الان لاحظوا
+
+427
+00:39:21,760 --> 00:39:26,100
+هدولة فى اللهم تجويف هنا عارفين التجويف شو بيسموه
+
+428
+00:39:26,100 --> 00:39:31,160
+بالإنقليزي cavity ممتازين جدا اللهم cavity ال
+
+429
+00:39:31,160 --> 00:39:34,520
+cavity هذه ممكن يدخل ضيف عليها يعنى هم يكونوا
+
+430
+00:39:34,520 --> 00:39:40,390
+المضيف ايش معناه المضيف hostممكن ييجي guest يدخل
+
+431
+00:39:40,390 --> 00:39:44,290
+جوا زي ما البني آدم عنده قوضة لضيوف و بيجي ضيف
+
+432
+00:39:44,290 --> 00:39:48,010
+يدخل فيها طب لو بدنا نجيب ضيف يدخل هنا، إيش بده
+
+433
+00:39:48,010 --> 00:39:53,650
+يكون هذا الضيف؟ اطلعولي إن ال oxygen يحمل أزواج
+
+434
+00:39:53,650 --> 00:39:54,850
+إلكترونات
+
+435
+00:39:57,510 --> 00:40:00,990
+و بدو يجي يضيفي بوسط هالسحابة الإلكترونية، شو بدو
+
+436
+00:40:00,990 --> 00:40:07,330
+يكون؟ موجب، ايش أشهر الموجب؟ الـmetal ions، Sodium
+
+437
+00:40:07,330 --> 00:40:13,330
+Plus, Potassium Plus, Cesium Plus و هكذا، اذا هنا
+
+438
+00:40:13,330 --> 00:40:19,440
+لما بدو يدخل، ايش هيدخل؟ Metal Plusلأن الجو العام
+
+439
+00:40:19,440 --> 00:40:25,160
+كله سالب اللي بدو يجي يدخل إيش؟ معدن موجب طب الآن
+
+440
+00:40:25,160 --> 00:40:29,000
+اتطلعولي على ال cavities ال cavities هذه إلها
+
+441
+00:40:29,000 --> 00:40:33,320
+أحجام ولا كلها نفس الحجم؟ أحجام طب و آيونات
+
+442
+00:40:33,320 --> 00:40:40,860
+المعادن مش في الجدول الدوري عندكم ن إيه؟ بوتاسيوم؟
+
+443
+00:40:40,860 --> 00:40:47,450
+سيزيوم؟الان هذا حجمه صغير، هذا أكبر، هذا أكبر، إذا
+
+444
+00:40:47,450 --> 00:40:53,590
+هل كل Ion بيجي على كل cavity ولا فيه تناسو؟ Ion
+
+445
+00:40:53,590 --> 00:40:58,650
+معين بيدخل ب cavity معينة Ion معين بيدخل بcavity
+
+446
+00:40:58,650 --> 00:41:03,730
+معينة يعني مثلا هذا المركب ال 18 crown 6 لما جاسوا
+
+447
+00:41:03,730 --> 00:41:08,230
+حجم ال cavity تبعتهبين اتنين و ستة من عشرة لتلاتة
+
+448
+00:41:08,230 --> 00:41:12,030
+و اتنين من عشرة أنجسترون طب حجم ايون الصوديوم واحد
+
+449
+00:41:12,030 --> 00:41:15,510
+و تسعة واحد و تسعة لو حطناه من هنا إيش بيعمل
+
+450
+00:41:15,510 --> 00:41:21,490
+الفتحة كبيرة عليه بيجع منها ال cesium تلاتة و
+
+451
+00:41:21,490 --> 00:41:27,550
+تلاتة أكبر من الفتحة بيدخلش مين اللي بتناسب معها
+
+452
+00:41:27,550 --> 00:41:31,990
+اتنين و ستة و ستين وهذه اتنين و ستة لتلاتة و اتنين
+
+453
+00:41:32,930 --> 00:41:37,910
+البوتاسيوم إذا لو حطينا ال crown الآن و جيبنا
+
+454
+00:41:37,910 --> 00:41:42,650
+التلت أيونات معادن هو فيه cavity الان ال cavity
+
+455
+00:41:42,650 --> 00:41:50,330
+واحد صغير بيدخل منها بيوقع والتاني كبير ما بيجيش
+
+456
+00:41:50,330 --> 00:41:54,970
+والتالت المتناسب مين اللي هيقعد في قلب ال cavity؟
+
+457
+00:41:55,610 --> 00:42:01,130
+البوتاسيوم اذا هذا ال crown صار لو حطناله التلاتة
+
+458
+00:42:01,130 --> 00:42:05,390
+صاد منهم البوتاسيوم و ساب التانين التانين عارفين
+
+459
+00:42:05,390 --> 00:42:09,990
+الفكرة زي ايش؟ زي الشبكة تبعت صيادين السمك صياد
+
+460
+00:42:09,990 --> 00:42:13,530
+السمك عنده اكتر من شبكة لكل موسم كل شبكة فيها حجم
+
+461
+00:42:13,530 --> 00:42:19,110
+اليوم لما بدو يصيد البوري عنده حجم معين بيمسك سمكة
+
+462
+00:42:19,110 --> 00:42:24,200
+البوري طب و السردين؟في شبكة البوري بيدخل و بيطلع
+
+463
+00:42:24,200 --> 00:42:27,320
+قدامه هو مش ناوي يصيده بيدخل و بيطلع أو السمك
+
+464
+00:42:27,320 --> 00:42:30,460
+الصغير لما بديه يصيد السردين شو بديه يستعمل إلها؟
+
+465
+00:42:30,460 --> 00:42:35,000
+شبكة أصغر أفهمتوا إيش الفكرة هنا في ال host و ال
+
+466
+00:42:35,000 --> 00:42:39,840
+guest؟ إنه ال guest الضيف اللي بديه ييجي هنا اللي
+
+467
+00:42:39,840 --> 00:42:44,560
+هو المثل هذا ال guest لازم يكون حجمه متناسب مع
+
+468
+00:42:44,560 --> 00:42:51,240
+إيش؟ مع ال cavity وهذا الكلام له حتى تطبيقات في
+
+469
+00:42:51,240 --> 00:42:56,940
+وين؟في المجال الطبي في الأدوية يعني آخر slide الآن
+
+470
+00:42:56,940 --> 00:43:03,220
+عندنا هاي هذا المركب في نفس الفكرة بطريقة أو باخره
+
+471
+00:43:03,220 --> 00:43:10,380
+و في cavity هناhigh cavity هذه الكفتي تبعته افتسع
+
+472
+00:43:10,380 --> 00:43:16,300
+البوتاسيوم يعني لما يكون فيه نا بلس وبوتاسيوم بلس
+
+473
+00:43:16,300 --> 00:43:20,980
+في جسم الإنسان من اللي بيدخل في الكفتي البوتاسيوم
+
+474
+00:43:20,980 --> 00:43:25,940
+الآن هذا المضاد الحيوي بدخل جوا الخلية لما يدخل
+
+475
+00:43:25,940 --> 00:43:31,500
+بدخل بما حمل إذا إيش جدر يدخل جوا الخلية؟
+
+476
+00:43:32,150 --> 00:43:37,190
+البوتاسيوم ايش صاب برا الخلية الصوديوم بنسمي هذه
+
+477
+00:43:37,190 --> 00:43:43,630
+العملية ايش selective transport يعني هو دخل واحد
+
+478
+00:43:43,630 --> 00:43:50,770
+من اتنين هي الخلية هي جدارها هذه هي الخلية المضاد
+
+479
+00:43:50,770 --> 00:43:55,560
+بيقدر يدخل في جلب الخليةو بيقدر يحمل واحد من
+
+480
+00:43:55,560 --> 00:43:58,620
+الاتنين، مين اللي بيقدر يحمله؟ ال potassium
+
+481
+00:43:58,620 --> 00:44:01,920
+المتناسب مع حجم ال cavity بناء على ذلك هو في الأول
+
+482
+00:44:01,920 --> 00:44:05,500
+بيحمل ال potassium، بعدين هو بما حمله بيدخل جوا
+
+483
+00:44:05,500 --> 00:44:11,000
+الخلية بزامو دخل، نجل ال potassium من برا لجوا
+
+484
+00:44:11,700 --> 00:44:15,900
+فاهمتوا أين الجمال بفكرة crown ethers يعني بسرها
+
+485
+00:44:15,900 --> 00:44:21,900
+انعكاس على واقع التطبيق الطبي بهك بنكون أنهينا هذا
+
+486
+00:44:21,900 --> 00:44:24,140
+ال chapter اللي اسمه ال ethers
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..945958f6bb3e43700e703f3c6e821501612c9e3c
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_postprocess.srt
@@ -0,0 +1,1832 @@
+1
+00:00:21,210 --> 00:00:26,340
+بسم الله الرحمن الرحيمباقي عندنا في موضوع
+
+2
+00:00:26,340 --> 00:00:30,340
+التفاعلات او التفاعلات المرتبطة بال
+
+3
+00:00:30,340 --> 00:00:34,940
+stereochemistry شغلتين بسيطات احنا اتكلمنا في
+
+4
+00:00:34,940 --> 00:00:38,600
+الاول على نقطة كتير مهمة او على تفاعل كتير مهم
+
+5
+00:00:38,600 --> 00:00:43,740
+قولنا دائما في المختبر بالوضع الطبيعي لما نعمل
+
+6
+00:00:43,740 --> 00:00:47,560
+generation of a chiral center بيطلع عندى racemic
+
+7
+00:00:47,560 --> 00:00:50,400
+mixture equal mixture of enantiomers و هذا بده
+
+8
+00:00:50,400 --> 00:00:54,830
+غلبة و بده فصل و ما إلى ذلكوالان بيحاولوا انهم
+
+9
+00:00:54,830 --> 00:00:59,250
+يتغلبوا على هذا الكلام من خلال تقنيات حديثة في
+
+10
+00:00:59,250 --> 00:01:04,390
+التحضير بيسموها asymmetric synthesis هذا التفاعل
+
+11
+00:01:04,390 --> 00:01:10,030
+الأولالتفاعل التاني، لو أنا يا تورا بعمل تفاعل
+
+12
+00:01:10,030 --> 00:01:15,450
+بعيدا عن ال chiral center، الآن إيش معنى بعيدا عن
+
+13
+00:01:15,450 --> 00:01:21,310
+ال chiral center؟ بمعنى لأكسر رابطة متصلة بال
+
+14
+00:01:21,310 --> 00:01:25,330
+chiral center، يعني الأربع روابط المتصلين بال
+
+15
+00:01:25,330 --> 00:01:30,950
+chiral center بكسرهم مشكل ما بعد ذلك يعتبر ايش؟
+
+16
+00:01:30,950 --> 00:01:35,230
+تفاعل بعيد عن الـ Chiral Center واضح الفكرة؟ يعني
+
+17
+00:01:35,230 --> 00:01:39,110
+مثلا في هذا المركب، عندي هنا أنا Chiral Center
+
+18
+00:01:39,110 --> 00:01:45,010
+متصل بـ Methyl و بـ Ethyl و COH و بH، الآن هذا الـ
+
+19
+00:01:45,010 --> 00:01:50,240
+Chiral Center عليه كام رابطةأربع روابط لو أنا بدي
+
+20
+00:01:50,240 --> 00:01:55,460
+أبدل مجموعة ال O H هنا اللي هي ال acidic O H
+
+21
+00:01:55,460 --> 00:02:01,200
+مجموعة ال O H الحامضية هذه كلها بمجموعة O Ethyl
+
+22
+00:02:01,200 --> 00:02:06,420
+بمعنى في الكيميا هذا التفاعل هنتعلمه بنبدل فيه ال
+
+23
+00:02:06,420 --> 00:02:12,340
+acid ل E starباستعمال التفاعل مع الكحول شيلت الـ
+
+24
+00:02:12,340 --> 00:02:19,240
+OH و خلتها ايش؟ O Ethan الان هذه الأربع رواضة كسرت
+
+25
+00:02:19,240 --> 00:02:25,380
+جزء منها؟ لأ وبناء على ذلكالجيومتري حوالين
+
+26
+00:02:25,380 --> 00:02:28,640
+الكايرال كاربون الشكل اللذس حوالين الكايرال كاربون
+
+27
+00:02:28,640 --> 00:02:33,620
+بيضل زي ما هو فأنا كأن بعمل عملية ايش نسخ و لصق
+
+28
+00:02:33,620 --> 00:02:38,960
+بلغة الكمبيوتر يعني باجي بعمل نسخ لهذا بكل موابط و
+
+29
+00:02:38,960 --> 00:02:43,740
+لاحظوا ال H باتجاه ال CO باتجاه ال CH3 ال إثل بحطه
+
+30
+00:02:43,740 --> 00:02:48,120
+هنا و بعمل التغيير اللي عندهو بناء على ذلك بنقول
+
+31
+00:02:48,120 --> 00:02:52,740
+انه تم عنده retention of configuration يعني الشكل
+
+32
+00:02:52,740 --> 00:02:58,360
+ضل زي ما هو اتجاه الاربع روابط اللي محيطين بال
+
+33
+00:02:58,360 --> 00:03:03,440
+chiral center ضالهم ايش زي ما هو لو انا بدي اعطيكم
+
+34
+00:03:03,440 --> 00:03:07,700
+مثال يعني تخيلوا مثلا انا بهذا الشكل هينعمل chiral
+
+35
+00:03:07,700 --> 00:03:12,260
+center من اربع شغلاتوأتيت أعمل التفاعل هنا كان
+
+36
+00:03:12,260 --> 00:03:15,900
+مافيش في إيدي جلم امسكت جلم هل غيرت في اتجاه
+
+37
+00:03:15,900 --> 00:03:19,480
+الأربع روابط ولا في عند retention of configuration
+
+38
+00:03:19,480 --> 00:03:23,760
+في عند retention of configuration إذا التفاعل
+
+39
+00:03:23,760 --> 00:03:28,720
+بعيدا عن ال chiral center بتم في retention of
+
+40
+00:03:28,720 --> 00:03:31,660
+configuration معنى retention of configuration أن
+
+41
+00:03:31,660 --> 00:03:36,600
+اتجاهات الروابط الأربع تبقى كما هي لم نكسر شيء
+
+42
+00:03:36,600 --> 00:03:42,300
+حولهاكذلك الحال هنا احنا حاطين مثال تاني لو فعلنا
+
+43
+00:03:42,300 --> 00:03:47,740
+هذا المركب يعلن الكايرال سنتر بدلنا هذه ال O H
+
+44
+00:03:47,740 --> 00:03:51,740
+خلناها C double bond O باستعمال اكسدة ابعام
+
+45
+00:03:51,740 --> 00:03:53,620
+المؤكسل عادة بنسميه
+
+46
+00:03:56,470 --> 00:04:01,290
+الان هذول الاربع روابط صار عندهم تغيير و لا تغيير
+
+47
+00:04:01,290 --> 00:04:06,390
+بعد الكايرالسينفاق بعد اذا كل الاتجاهات تبقى كما
+
+48
+00:04:06,390 --> 00:04:13,840
+هي CLH CH2 CH3 الـC هادىالتغير بعدها ما كسرت روابط
+
+49
+00:04:13,840 --> 00:04:16,660
+بالتصيلة بال chiral center مرة تانية في عندي
+
+50
+00:04:16,660 --> 00:04:20,280
+retention of configuration إذا ال reaction away
+
+51
+00:04:20,280 --> 00:04:23,160
+from a chiral center results in retention of
+
+52
+00:04:23,160 --> 00:04:30,000
+configuration الآن بهمني أعطي بس ملاحظة خفيفةالـ
+
+53
+00:04:30,000 --> 00:04:34,600
+retention of configuration معناه أن الأربع روابط
+
+54
+00:04:34,600 --> 00:04:39,720
+تبقى في اتجاهاتها ليس له علاقة .. ليس له علاقة
+
+55
+00:04:39,720 --> 00:04:46,100
+بكلمة R و S أنا هنا و أنا بشتغل كتبت R ولا S ولا
+
+56
+00:04:46,100 --> 00:04:50,380
+شفت أن ال R دلت R ولا ال S دلت S؟ ماجبتش سيرة
+
+57
+00:04:50,380 --> 00:04:55,100
+هالكلام، ليش؟ لأنه أنا لما بغير مجموعة هنا أو هنا
+
+58
+00:04:55,100 --> 00:05:02,890
+ممكن الأولويات تتغير؟ أكيدأكيد حتى لو غيرت مجموعة
+
+59
+00:05:02,890 --> 00:05:06,790
+بعيد ممكن يصير فيه تغيير بالأولويات و لذلك ممكن R
+
+60
+00:05:06,790 --> 00:05:11,430
+عند الضل R ممكن R تصير S ممكن S تصير R ممكن S تظل
+
+61
+00:05:11,430 --> 00:05:16,370
+S أو تتقلب إلى R هذا موضوع ما درسته انا اطلاقا انا
+
+62
+00:05:16,370 --> 00:05:21,650
+بدرس الأربع روابط في اتجاهاتهم فيهم تغيير ولا لأ
+
+63
+00:05:21,650 --> 00:05:26,020
+هى معناه retention of configuration الان R و Sمن
+
+64
+00:05:26,020 --> 00:05:31,160
+أول و جديد في عندكم اشي اسمه قواعد ترتيب المجموعات
+
+65
+00:05:31,160 --> 00:05:36,320
+حسب الأولويات واحد اتنين تلاتة اربعة بنرتبهم ضلت
+
+66
+00:05:36,320 --> 00:05:41,460
+الارار صارت اسم مش مشيء بالنسبة الي واضح الفكرة
+
+67
+00:05:41,460 --> 00:05:47,200
+فكلمة retention of configurationلا تعني اطلاقا ..
+
+68
+00:05:47,200 --> 00:05:52,700
+لا تعني اطلاقا ان ال R دلت R او ال S دلت S لأ تعني
+
+69
+00:05:52,700 --> 00:05:58,520
+ان الأربع روابط ضالهم باتجاههم ال R و ال S اولويات
+
+70
+00:05:58,520 --> 00:06:01,420
+اللي بيحسب اولويات يشوف حسب المثال اللي عنده
+
+71
+00:06:01,420 --> 00:06:05,480
+هتلاقوا مثال بتم فيه تغيير مثال بتم مش فيه تغيير
+
+72
+00:06:05,480 --> 00:06:09,460
+حسب هالمجموعة اللي طلعت و المجموعة اللي اجت هذا
+
+73
+00:06:09,460 --> 00:06:15,200
+موضوع تاني واضح الفكرة؟وهذا كثير بنسألكم بمعناه
+
+74
+00:06:15,200 --> 00:06:19,280
+انه هالمعنى كلمة retention of configuration means
+
+75
+00:06:19,280 --> 00:06:24,420
+are must be are in the product لأ مش ضروري ممكن
+
+76
+00:06:24,420 --> 00:06:29,400
+تظل ممكن تتغير هذا موضوع و هذا موضوع تاني
+
+77
+00:06:33,710 --> 00:06:39,030
+هذه تفاعلات بناخدها بعدين بس بنعطيها كأمثلة يعني
+
+78
+00:06:39,030 --> 00:06:43,710
+هذا تأكسد كحول إلى aldehyde لما ندرس chapter
+
+79
+00:06:43,710 --> 00:06:49,410
+الكحولات ب chapter 7 بنشرحه الآن بديش أنا أسمي لا
+
+80
+00:06:49,410 --> 00:06:52,750
+كحول ولا aldehyde أنا قلت ال Canada دي CO single
+
+81
+00:06:52,750 --> 00:06:57,840
+bond صارت CO double bond غيرت هان ولا لأ؟تستعجلوش
+
+82
+00:06:57,840 --> 00:07:02,880
+العلم هذا تحول حامض إلى Easter بدلت ال OH ب Oethel
+
+83
+00:07:02,880 --> 00:07:08,140
+بدرسه ب Chapter 10 مش هو موضوعي غيرت بدي ألغي كل
+
+84
+00:07:08,140 --> 00:07:13,060
+اللي كاتبه و أكتب XY عشان اترايحيني أعصابي خلت XY
+
+85
+00:07:13,060 --> 00:07:14,980
+واضح؟
+
+86
+00:07:16,500 --> 00:07:21,120
+دائما تتعبوش أنفسكم في الفكرة غير الأساسية بدلت X
+
+87
+00:07:21,120 --> 00:07:26,760
+بY إيش التفاعل مش مشكلة مش X صارت Y تفاعل general
+
+88
+00:07:26,760 --> 00:07:31,520
+بدلته بعيدا عن ال chiral center إيش بيظل عنده
+
+89
+00:07:31,520 --> 00:07:37,960
+retention إنما هدولا التفاعلين كتفصيل بناخدهم في
+
+90
+00:07:37,960 --> 00:07:43,160
+chapter 7 أو chapter 10 لكن استعانا فيهم كأمثلة
+
+91
+00:07:45,090 --> 00:07:50,130
+التفاعل التالت generation of a second chiral
+
+92
+00:07:50,130 --> 00:07:54,370
+center يعني لاحظوا احنا اول مرة قولنا ماكنش لنا
+
+93
+00:07:54,370 --> 00:07:57,390
+chiral center نهائي و عملنا له generation، شو طلع
+
+94
+00:07:57,390 --> 00:08:04,840
+عندى؟ رسمic mixtureتاني تفاعل لما اعملت تفاعل بعيد
+
+95
+00:08:04,840 --> 00:08:08,320
+عن الكايرال سنتر شو صار عندى retention of
+
+96
+00:08:08,320 --> 00:08:13,880
+configuration طيب الآن لو كان في عندى كايرال سنتر
+
+97
+00:08:13,880 --> 00:08:19,160
+اول و بدى اعمل كايرال سنتر تاني شو بده يصير عندى؟
+
+98
+00:08:19,160 --> 00:08:25,120
+خلّينا نشوف مثال هذه مثال لو طلعنا على هذا المركب
+
+99
+00:08:25,120 --> 00:08:29,880
+الآن هذه الكاربون اللى موجودة هنا بتحمل مثل
+
+100
+00:08:29,880 --> 00:08:33,970
+وchloro Hو المجموعة اللي فيها double bond كايرال
+
+101
+00:08:33,970 --> 00:08:39,290
+سنتر ولا لأ كايرال سنتر انا مش موضوعي اطلاقا هذه
+
+102
+00:08:39,290 --> 00:08:42,770
+ال carbon بدي اعمل التفاعل على ال double bond يعني
+
+103
+00:08:42,770 --> 00:08:48,160
+على ال double bond بدي اجي اضيف hbr في وجودH plus
+
+104
+00:08:48,160 --> 00:08:53,940
+هذه أخدناها إضافة Markovnikov يعني بدأ أحط ال H
+
+105
+00:08:53,940 --> 00:09:00,080
+هنا في الأول أبدأ تفاعل بإضافة ال H هنا وبعدين
+
+106
+00:09:00,080 --> 00:09:06,260
+أكمل ال PR على هذا الموقع لاحظوا إيش اللي بدو يصير
+
+107
+00:09:06,260 --> 00:09:12,060
+عندي لما أضيف ال H على هذا الموقع كام رابط هيظل
+
+108
+00:09:12,060 --> 00:09:20,250
+على هذه النقطة تلت روابط تلت روابطحاولوا تستحضروا
+
+109
+00:09:20,250 --> 00:09:24,510
+الشكل مع الهيدروجين المحذوف مع الهيدروجين المحذوف
+
+110
+00:09:24,510 --> 00:09:30,210
+أعطيكم H هاي
+
+111
+00:09:30,210 --> 00:09:35,830
+الشكل الكامل واضح؟ لما أضيف هنا H هذا الكربون بدل
+
+112
+00:09:35,830 --> 00:09:41,630
+ما يكون CH2 ماذا سيحصل؟ CH3 سيحصل CH3 و ال double
+
+113
+00:09:41,630 --> 00:09:48,850
+bond هذه ستذهب علىأساس أنه هيجي يخجم عندي هنا PR
+
+114
+00:09:48,850 --> 00:09:53,270
+في الخطوة التالية الآن لاحظوا معي لو اتطلعنا على
+
+115
+00:09:53,270 --> 00:09:58,450
+هذا الجزء هذا الجزء يا ترى هل احنا بنشتغل قريب عنه
+
+116
+00:09:58,450 --> 00:10:04,430
+ولا بالنسبة له بنشتغل reaction away from a chiral
+
+117
+00:10:04,430 --> 00:10:08,290
+center away from a chiral center وعشانك بنحطه زي
+
+118
+00:10:08,290 --> 00:10:10,630
+ما هو لاحظوا إيش معناه retention of configuration
+
+119
+00:10:10,630 --> 00:10:14,750
+المثل اللي فوق ال CL على اليمين ال H على الشمالهذا
+
+120
+00:10:14,750 --> 00:10:19,010
+retention of configuration ولا لأ؟ الآن هذه النقطة
+
+121
+00:10:19,010 --> 00:10:27,690
+هي النقطة اللي هنا ال CH2 شو صارت؟ CH3 و هذه ما
+
+122
+00:10:27,690 --> 00:10:35,090
+زالت H و الآن أنا بانتظار ال PR لما نيجي نطلع
+
+123
+00:10:35,090 --> 00:10:38,130
+حوالين هذه ال carbon ايش الشكل؟
+
+124
+00:10:40,850 --> 00:10:46,950
+بناء على ذلك بنتوقع ان ال PR بإمكانها تهجم من
+
+125
+00:10:46,950 --> 00:10:51,010
+الجهتين زي ما أخذنا في أول مرة لما درسنا ال
+
+126
+00:10:51,010 --> 00:10:53,950
+generation of a chiral center بمعنى ال PR ممكن
+
+127
+00:10:53,950 --> 00:10:58,830
+تيجي من هنا و ال PR ممكن تيجي تهاجي من هنا إذا كام
+
+128
+00:10:58,830 --> 00:11:03,070
+ناتج بدو يطلع عندى هى ال PR إذا إجت من هذا الاتجاه
+
+129
+00:11:03,070 --> 00:11:09,380
+و هى ال PR إذا إجت من الاتجاه التالفزي لما درسنا
+
+130
+00:11:09,380 --> 00:11:12,600
+اول مرة الـ Chiral Center تقولنا عندنا بلانر
+
+131
+00:11:12,600 --> 00:11:18,100
+انترميديت تم التفاعل من ايه؟ من الجهتين الان هنا
+
+132
+00:11:18,100 --> 00:11:22,180
+في عند بلانر انترميديت اتكونت نتيجة انه ضفت اتش
+
+133
+00:11:22,180 --> 00:11:29,780
+لغية ال bubble bond التفاعل بإمكانه تم من الجهتينو
+
+134
+00:11:29,780 --> 00:11:35,340
+بناء على ذلك كام ناتج يطلع عنده؟ اتنين بيفرق عن
+
+135
+00:11:35,340 --> 00:11:40,880
+المثال الأول بشغل واحدة انه هل يترى الاحتمالات
+
+136
+00:11:40,880 --> 00:11:44,860
+متساوية ان هذا ييجي عن اليمين او عن الشمال في
+
+137
+00:11:44,860 --> 00:11:48,960
+generation of a first chiral center كنا نقول
+
+138
+00:11:48,960 --> 00:11:54,000
+الاحتمالات بتكون متساوية و بناء على ذلك يطلع عنده
+
+139
+00:11:55,740 --> 00:12:01,120
+الان بسبب وجود الكايرال سنتر الاول اللى بيخل
+
+140
+00:12:01,120 --> 00:12:06,400
+الفراغات حوالين هذا الكاربون غير متساوية مابيكونوش
+
+141
+00:12:06,400 --> 00:12:13,720
+الاحتمالين بنفس المقدار فبتم صحيح هجوم من الجهتين
+
+142
+00:12:13,720 --> 00:12:20,570
+ولكن ليسبنسب متساوية يعني مابيجيش 50% من التفاعل
+
+143
+00:12:20,570 --> 00:12:24,430
+من هنا و 50% من التفاعل من هنا ليش هذا الكلام
+
+144
+00:12:24,430 --> 00:12:30,240
+امتنع؟بسبب وجود ال chiral center اللي بيخلي جهة
+
+145
+00:12:30,240 --> 00:12:35,240
+أحيانا مغلقة أكتر من الجهة التانية بيصير فيه فرق
+
+146
+00:12:35,240 --> 00:12:40,180
+بالوسع زي إنسان كان عنده مسارين متساويين تماما
+
+147
+00:12:40,180 --> 00:12:44,520
+بيمكنه يمشي من هنا و من هنا الآن إجا شيء سكر جزء
+
+148
+00:12:44,520 --> 00:12:50,520
+من مسار معين بيضلوا يمشي بنفس النسبة ولا غالبا
+
+149
+00:12:50,520 --> 00:12:55,530
+بيروح على المسار الأكتر يعني ساعة و فراغواضح
+
+150
+00:12:55,530 --> 00:13:00,610
+الفكرة؟ الآن شو اللي خلّى عدم التساوي؟ الكايرال
+
+151
+00:13:00,610 --> 00:13:04,450
+سنتر الأول الكايرال سنتر الأول بيخلّى عدم تساوي
+
+152
+00:13:04,450 --> 00:13:08,890
+إذا لو أنا اتطلعت الآن على هدول الناتجين اللي
+
+153
+00:13:08,890 --> 00:13:13,610
+طلعوا بنسب متساوي ولا غير متساوية؟ غير متساوية غير
+
+154
+00:13:13,610 --> 00:13:17,690
+متساوية in unequal amounts وسألت يا تورا ما
+
+155
+00:13:17,690 --> 00:13:24,530
+العلاقة بين هدول المركبين اللي طلعوا عندهم؟لاحظوا
+
+156
+00:13:24,530 --> 00:13:30,570
+هذا الجزء و هذا الجزء ايش مالهم صورة بعض في المرأة
+
+157
+00:13:30,570 --> 00:13:36,450
+و متعاكسة طب و هذا و هذا نفس الشيء إذا المركب كله
+
+158
+00:13:36,450 --> 00:13:42,110
+صورة بعض و لا لأ إذا بدكم تعملوا باستعمال الرموز
+
+159
+00:13:42,110 --> 00:13:49,370
+بإمكانكم تعملوا R و S بمعنى نلغي هذه ال edge هعندي
+
+160
+00:13:49,370 --> 00:13:55,180
+واحد اتنين تلاتة هذه البيانة Rهذه S الانهان ما
+
+161
+00:13:55,180 --> 00:14:00,540
+اتغيرت ضلت زي ما هي هالكلور و بعدين كربون حملة
+
+162
+00:14:00,540 --> 00:14:06,460
+برون بعدين اذا هذه ايش S طيب لو اتيت و طلعت هنا
+
+163
+00:14:06,460 --> 00:14:09,900
+واحد
+
+164
+00:14:09,900 --> 00:14:14,640
+اتنين R
+
+165
+00:14:14,640 --> 00:14:21,860
+S هذه واحد اتنين R S
+
+166
+00:14:24,660 --> 00:14:31,600
+مكتوبها R رجعوهم بهدوء ال R شيء متعاكس وشيء متساوي
+
+167
+00:14:31,600 --> 00:14:37,740
+اذا هدوله ايش ديستريو مارس ف ال generation of a
+
+168
+00:14:37,740 --> 00:14:42,920
+second chiral center المحاصلة تبعته it results in
+
+169
+00:14:42,920 --> 00:14:46,560
+diastereomeric products at different rates بسرعة
+
+170
+00:14:46,560 --> 00:14:53,300
+مختلفة الأهم منها and inunequal amounts يعني لو
+
+171
+00:14:53,300 --> 00:14:56,520
+أنا باسألكوا سؤال صح و غلط generation of a second
+
+172
+00:14:56,520 --> 00:15:00,580
+chiral center results in the stereomeric mixture
+
+173
+00:15:00,580 --> 00:15:06,440
+or products in equal amounts and unequal amounts
+
+174
+00:15:06,590 --> 00:15:10,050
+طبعا ليش صار الـ unequal amount؟ because of the
+
+175
+00:15:10,050 --> 00:15:14,750
+presence of the first chiral center وجود ال chiral
+
+176
+00:15:14,750 --> 00:15:19,390
+center الأول خلّى احتمالات الهجوم من الجهتين غير
+
+177
+00:15:19,390 --> 00:15:22,770
+متساوي يعني الوسع اللي موجود من الجهة بختلف عن
+
+178
+00:15:22,770 --> 00:15:25,370
+الوسع اللي موجود من الجهة التانية الآن ذرة بدأت
+
+179
+00:15:25,370 --> 00:15:29,370
+تتفاعل التفاعل هو هجوم، ذرة ماشية و بدأت تيجي الآن
+
+180
+00:15:29,370 --> 00:15:31,850
+دايما اللي بدو يروح، يروح من المنطقة الواسعة ولا
+
+181
+00:15:31,850 --> 00:15:39,690
+الديقة؟ من المنطقة الواسعة، واضح؟هذا المحصلة
+
+182
+00:15:39,690 --> 00:15:44,370
+بالنسبة لعملية generation of a chiral center وزي
+
+183
+00:15:44,370 --> 00:15:48,650
+ما لاحظته ان هذا التفاعل بيدمج التفاعلين السابقين
+
+184
+00:15:48,650 --> 00:15:53,490
+يعني بالنسبة لهذا هو تفاعل بعيد عنه ولذلك هذا
+
+185
+00:15:53,490 --> 00:15:58,870
+الجزء ايش ماله؟ ضال في retention of configuration
+
+186
+00:15:58,870 --> 00:16:04,250
+وال generation of a chiral center تمهن ولكن بنسبة
+
+187
+00:16:04,250 --> 00:16:05,990
+غير متساوية
+
+188
+00:16:07,980 --> 00:16:11,920
+بهيك احنا بننتهي من chapter ال stereochemistry في
+
+189
+00:16:11,920 --> 00:16:15,120
+عندكم slide عن resolution of enantiomers اتكلمنا
+
+190
+00:16:15,120 --> 00:16:19,500
+عنها اللي هي فصل ال enantiomers لو حضرناهم كخليط
+
+191
+00:16:19,500 --> 00:16:24,060
+متساوي وقولنا ان هذه العملية بكل الأحوال مش عملية
+
+192
+00:16:24,060 --> 00:16:30,580
+سهلة يمكن ان تعمل بعدة طرق فنية في المختبرات لكن
+
+193
+00:16:30,580 --> 00:16:36,120
+بتاخد وقت ومش عملية سهلة والافضل من resolution of
+
+194
+00:16:36,120 --> 00:16:42,550
+enantiomersأما أن أخد المركب نقي من الطبيعة أو
+
+195
+00:16:42,550 --> 00:16:46,930
+الاحتمال التاني لو و لابد في المختبر ان اعمل
+
+196
+00:16:46,930 --> 00:16:51,710
+asymmetric synthesis انتبهوا معي لو بدأ اقول ايش
+
+197
+00:16:51,710 --> 00:16:58,110
+افضل اشي للوصول للمركبات النقية نمرة واحد من ال
+
+198
+00:16:58,110 --> 00:17:04,230
+nature الطبيعة بتعطينا مركبات نقية نمرة اتنين ان
+
+199
+00:17:04,230 --> 00:17:10,070
+اعملasymmetric synthesis يعني أعمل synthesis
+
+200
+00:17:10,070 --> 00:17:18,670
+يعطيني واحد أكتر من التاني نمرة تلاتة أن أعمل ال
+
+201
+00:17:18,670 --> 00:17:21,950
+synthesis اللي حكينا اللي بيطلعوا التنين متساويات
+
+202
+00:17:21,950 --> 00:17:26,890
+في اللي إيش اسمه symmetric synthesis لكن ال
+
+203
+00:17:26,890 --> 00:17:31,650
+symmetric synthesis إيش بدوا يتبعوه؟Symmetric
+
+204
+00:17:31,650 --> 00:17:36,050
+Synthesis هذا يجب ان يتبع Resolution لان افصلهم
+
+205
+00:17:36,050 --> 00:17:41,430
+بتجارب صعبة الانزيمات
+
+206
+00:17:41,430 --> 00:17:48,760
+في ال nature ال catalystsبمواصفات معينة عادة كيرال
+
+207
+00:17:48,760 --> 00:17:53,500
+كتاليست في الطريقة التانية يعني اللي بيساعد على ان
+
+208
+00:17:53,500 --> 00:17:57,920
+انا احصل على المركب النقي في ال nature اللي هو ال
+
+209
+00:17:57,920 --> 00:18:02,820
+enzymes الان اللي بيساعد على ان احصل على ال
+
+210
+00:18:02,820 --> 00:18:05,880
+asymmetric synthesis يعني يطلعوا مش بنسبة متساوية
+
+211
+00:18:05,880 --> 00:18:09,280
+واحد اكثر من التاني الى درجة اقترب من النقاوة
+
+212
+00:18:09,280 --> 00:18:14,360
+احيانا ان انا باستعملكتاليست والكتاليست بيكون
+
+213
+00:18:14,360 --> 00:18:21,260
+كايرة الكتاليست عادة واضح؟ الان هذه طرق وقاية ليش
+
+214
+00:18:21,260 --> 00:18:25,000
+بعملها؟ عشان ما اجعش انه طلع عندى خليطه اتغلب
+
+215
+00:18:25,000 --> 00:18:28,640
+بفاصله لو مامشيش بهذه الطريقة او بهذه الطريقة
+
+216
+00:18:28,640 --> 00:18:33,220
+اعملت symmetric synthesis خليط متساوي من الاتنين و
+
+217
+00:18:33,220 --> 00:18:37,980
+اجت بدأ اجع في مشكلة ايش؟فصل الخليط يعني الخليط
+
+218
+00:18:37,980 --> 00:18:42,560
+اللى عندى نفترض R و S بدأ ادخل على عملية الفصل شو
+
+219
+00:18:42,560 --> 00:18:47,640
+بنسميها الفصل resolution هذه يمكن أن تتم باكثر من
+
+220
+00:18:47,640 --> 00:18:52,720
+طريقة كيميائية لكن بكل الأوقات ما تفكروش أنها
+
+221
+00:18:52,720 --> 00:18:57,080
+طريقة سهلة طريقة صعبة يعني أحيانا انتوا بيكونوا
+
+222
+00:18:57,080 --> 00:19:02,860
+التخيل عندكمانه شغلة صعبة يعني بدي اخد مختبر بدل
+
+223
+00:19:02,860 --> 00:19:07,300
+ما يكون ساعتين يكون تلت ساعات وانتهي ان انا فصلت
+
+224
+00:19:07,300 --> 00:19:11,020
+المادة لأ لما انا بقول ال resolution of
+
+225
+00:19:11,020 --> 00:19:15,520
+enhancements عملية صعبة يعني واحد باحث بيشتغل وطلع
+
+226
+00:19:15,520 --> 00:19:20,340
+عنده mix chart و بده يبدأ يفصل فيه ممكن الأمور معه
+
+227
+00:19:20,340 --> 00:19:23,640
+اذا بدأ من نقطة الصفر وماعندهش اي فكرة على الموضوع
+
+228
+00:19:23,640 --> 00:19:28,770
+يبدأ تجارب تاخد سنةمش بحكي عن ساعتين و تلاتة و
+
+229
+00:19:28,770 --> 00:19:34,410
+أربعة لأ بحكي عن سنة و أكتر كمان من سنة ليست عملية
+
+230
+00:19:34,410 --> 00:19:50,430
+سهلة في الوضع الطبيعي ابهيك
+
+231
+00:19:50,430 --> 00:19:54,930
+بنكون طبعا خلصنا هذا ال chapter اللي اسمه
+
+232
+00:19:58,800 --> 00:20:04,620
+استيريو كيميستري وبننتقل
+
+233
+00:20:04,620 --> 00:20:11,960
+مباشرة الى فصل اخر هذا الفصل الاخر بدنا ناخده نوعا
+
+234
+00:20:11,960 --> 00:20:19,910
+ما باختصار .. نوعا ما باختصار عنوانه الكلهيلايزو
+
+235
+00:20:19,910 --> 00:20:24,950
+طبعا ال الكلهليتز المجموعة هذه من المركبات لها
+
+236
+00:20:24,950 --> 00:20:30,870
+تفاعلين substitution and elimination تفاعل الإبدال
+
+237
+00:20:30,870 --> 00:20:37,980
+وتفاعل الحدث بالنسبة ل الكلاعرفنا إيش يعني الكل؟
+
+238
+00:20:37,980 --> 00:20:44,860
+مجموعة الكل مثل و إثل و بربل و كل شيء مأخوذ من ال
+
+239
+00:20:44,860 --> 00:20:50,260
+الكلس سواء له اسم و لا مالوش اسم و الهيليدز متصل
+
+240
+00:20:50,260 --> 00:20:57,300
+بهالوجين كلور بروم يود فلور أحيانا فال الكلهيليدز
+
+241
+00:20:57,300 --> 00:21:03,750
+ببساطة هم ال الكلس المتصلين بهالوجينيعني لو اجينا
+
+242
+00:21:03,750 --> 00:21:08,130
+و قولنا هذا المركب يا تورا و كتبنا هنا PR عبارة عن
+
+243
+00:21:08,130 --> 00:21:14,170
+إيش الكل هيلايد لأن هذا الجزء الكن و هذا الجزء
+
+244
+00:21:14,170 --> 00:21:18,250
+الهالوجين و عشان ذلك مرات بيسموها أي معنى الكل
+
+245
+00:21:18,250 --> 00:21:22,030
+هيلايد في جزء الكن و جزء الهالوجين عشان ذلك مرات
+
+246
+00:21:22,030 --> 00:21:28,870
+بيسموهم الهالوجينو الكنز الكل هيلايد او الهالوجينو
+
+247
+00:21:28,870 --> 00:21:32,490
+الكنز نفس الفكرة تماما
+
+248
+00:21:38,950 --> 00:21:43,570
+الان زي ما حكيت ال الكلهيلايتز بيسموهم مرات
+
+249
+00:21:43,570 --> 00:21:48,410
+الهالوجينوالكينز او هالوالكينز فسواء قرأنا العنوان
+
+250
+00:21:48,410 --> 00:21:53,170
+الكلهيلايتز او هالوجينوالكينز او هالوالكينز هو ال
+
+251
+00:21:53,170 --> 00:21:58,300
+cane حاملالهالوجين البساطة مش مشكلة كبيرة فال
+
+252
+00:21:58,300 --> 00:22:02,040
+الهالوجين محتوى الهالوجين اتوم و الهالوجين اتوم
+
+253
+00:22:02,040 --> 00:22:06,020
+معروفين بالنسبة لنا فلورين و كلورين و برومين و
+
+254
+00:22:06,020 --> 00:22:08,620
+ايودين متصلين ب الهالوجروم
+
+255
+00:22:11,830 --> 00:22:16,410
+الالكالهيلايتز ممكن ان نصنفهم احنا الى primary و
+
+256
+00:22:16,410 --> 00:22:19,890
+secondary و tertiary الكلهيلايتز هذا المصطلح
+
+257
+00:22:19,890 --> 00:22:23,770
+بيفيدنا اثناء ما بنشرح عن الموضوع ايش بنقصد احنا
+
+258
+00:22:23,770 --> 00:22:27,490
+بال primary و ال secondary و ال tertiary او باللغة
+
+259
+00:22:27,490 --> 00:22:32,170
+العربية اولي و ثانوي و ثالثي ال primary و ال
+
+260
+00:22:32,170 --> 00:22:35,790
+secondary و ال tertiary الكلهيلايتز باجي انا على
+
+261
+00:22:35,790 --> 00:22:39,430
+ذرة الكربون اللى حاملة ال halogen يعني هذا الكربون
+
+262
+00:22:39,430 --> 00:22:45,830
+اللى حاملة ال halogenمتصلة بكم كاربون؟ اذا متصلة
+
+263
+00:22:45,830 --> 00:22:50,610
+بكاربون واحدة بقول عنها primary لحظة ايه الكاربون
+
+264
+00:22:50,610 --> 00:22:54,950
+اللي حاملة الهالوجين متصلة بكم كاربون واحدة اذا
+
+265
+00:22:54,950 --> 00:22:58,170
+بقول عنها primary طبعا الناس الشاطرين بيصيروا
+
+266
+00:22:58,170 --> 00:23:02,530
+يفهموها يعني بشكل سهل بيقولوا لو الكاربون اللي
+
+267
+00:23:02,530 --> 00:23:08,540
+حاملة الهالوجين كانت CH2لاحظوا CH2 و ال PR هي تلات
+
+268
+00:23:08,540 --> 00:23:13,000
+روابط إذا كده يظل متصلة مع واحدة هذا ال primary
+
+269
+00:23:13,000 --> 00:23:19,140
+فاللي بيميز ال primary وجود ال CH2 هالوجينالان ال
+
+270
+00:23:19,140 --> 00:23:24,540
+secondary الكربون اللى حامله ال halogen هى هى هذه
+
+271
+00:23:24,540 --> 00:23:27,380
+الكربون اللى حامله ال halogen متصلة بكم كربون؟
+
+272
+00:23:27,380 --> 00:23:31,000
+تنتين تنتين بقول عنها ال secondary الان ايش بيكون
+
+273
+00:23:31,000 --> 00:23:36,600
+موجود فيها؟ CH يعني كأنه ال primary CH2 halogen ال
+
+274
+00:23:36,600 --> 00:23:43,960
+secondary CH halogen لو اجيت على ال tertiaryC
+
+275
+00:23:43,960 --> 00:23:49,220
+متصلة بالهالوجين طب و التلاتة روابط التانية متصلين
+
+276
+00:23:49,220 --> 00:23:54,600
+بالكاربون هاي C متصلة بالهالوجين و بعد هيك رابطة
+
+277
+00:23:54,600 --> 00:23:58,120
+تنتين تلاتة متصلة بالكاربون هذا النوع من ال
+
+278
+00:23:58,120 --> 00:24:02,340
+الكلهيلايتش شو بسمي انا tertiary alkyl halides
+
+279
+00:24:02,340 --> 00:24:06,040
+فإذا قلنا او رسمنا اي الكلهيلايت و قلنا عنه
+
+280
+00:24:06,040 --> 00:24:09,400
+primary او secondary او tertiary بفترض ان هذه
+
+281
+00:24:09,400 --> 00:24:17,540
+الشغلة تكون واضحةعشان نفهم الـ Alkyl Halides محور
+
+282
+00:24:17,540 --> 00:24:22,220
+الـ Alkyl Halides هو رابطة الـ Carbon-Halogen يعني
+
+283
+00:24:22,220 --> 00:24:27,180
+بين الـ Carbon والـ X الـ Halogen في عنده رابطة
+
+284
+00:24:28,310 --> 00:24:32,150
+الان بدي افهم هذه الرابطة جيدا لان التفاعلات
+
+285
+00:24:32,150 --> 00:24:37,330
+هيعتمد على هذه الرابطة ال carbon halogen bond جزء
+
+286
+00:24:37,330 --> 00:24:41,990
+من فهم هذا الموضوع ان اشوف فرق السالبية هنا هل
+
+287
+00:24:41,990 --> 00:24:47,310
+يترى هذه الرابطة polar ولا non polar عشان اشوف
+
+288
+00:24:47,310 --> 00:24:53,550
+الرابطة جيدا بدي اشوف ايش السالبية للكربون الكربون
+
+289
+00:24:53,550 --> 00:24:58,350
+سالبيته اتنين ونصال carbon ايش السالبية تبعته
+
+290
+00:24:58,350 --> 00:25:05,330
+اتنين و نص الان ال halogens كم واحد اه لاحظوا
+
+291
+00:25:05,330 --> 00:25:16,670
+floor سالبيته قداش اربعة و بروم تلاتة floor
+
+292
+00:25:16,670 --> 00:25:19,750
+تلاتة
+
+293
+00:25:19,750 --> 00:25:21,590
+بروم
+
+294
+00:25:23,000 --> 00:25:29,680
+2.8 و اليود 2.5 لاحظوا اليود و الكربون فيهم فرق
+
+295
+00:25:29,680 --> 00:25:34,620
+سالبية إذا الرابطة بشكل عام non polar مافيش فرق
+
+296
+00:25:34,620 --> 00:25:40,320
+سالبية الكربون 2.5 و اليود 2.5 لكن بعد ذلك مع
+
+297
+00:25:40,320 --> 00:25:45,140
+البروم و الكلور و الفلور في فرق سالبية لمصلحة
+
+298
+00:25:45,140 --> 00:25:50,080
+الهالوجين إذا بشكل عام مع هذول الذرات كيف بنتوقع
+
+299
+00:25:50,080 --> 00:25:57,150
+ال polarity للرابطة تكونإن الكربون تكون موجبة
+
+300
+00:25:57,150 --> 00:26:05,090
+والهالوجين سالبة واضح؟ أكبر فرق وين موجود؟ مع ال
+
+301
+00:26:05,090 --> 00:26:11,910
+floor أقل فرق العدم مع اليود الأن لاحظوا معي كل ما
+
+302
+00:26:11,910 --> 00:26:16,390
+كان الفرق كبير كل ما جربت الرابط تشبه الرابط
+
+303
+00:26:16,390 --> 00:26:20,890
+الأيونية بمعنى أخر بتصير أقوىو بناء على ذلك لو انا
+
+304
+00:26:20,890 --> 00:26:25,270
+بدى اشوف قوة هذه الروابط اللى هى مع ال flour و ال
+
+305
+00:26:25,270 --> 00:26:29,330
+brom و ال chlor و ال iod هلاحظ انه و اقارنها بقوة
+
+306
+00:26:29,330 --> 00:26:32,750
+رابطة ال carbon-H اللى هى تعتبر بلغة الكيميا رابطة
+
+307
+00:26:32,750 --> 00:26:38,930
+قوية و مش سائل تنقصت ال carbon-H 413 كيلوجول لكل
+
+308
+00:26:38,930 --> 00:26:42,910
+مول بدى عشان اكسر هذه الرابطة الان ال carbon-flour
+
+309
+00:26:42,910 --> 00:26:48,150
+اقوى منهاليش؟ لأن فرق ال polarity عالي صارت تشبه
+
+310
+00:26:48,150 --> 00:26:52,990
+رابطة ايونية قوية ال carboniclor 346 ال
+
+311
+00:26:52,990 --> 00:26:59,910
+carboniclor 290 ال carboniclor 228 أقوى واحدة فيهم
+
+312
+00:26:59,910 --> 00:27:06,670
+مين؟ مع ال fluor الآن جزء أساسي في بناء الكيميا
+
+313
+00:27:06,670 --> 00:27:09,850
+تبع ال alkyl halides ان انا بدي أكسر الرابطة هذه
+
+314
+00:27:09,850 --> 00:27:15,000
+اللي بين ال carbon و ال halogenيعني سواء في تفاعل
+
+315
+00:27:15,000 --> 00:27:20,020
+الإبدال أو الحذف، هذه الرابطة بدها تنكسر طيب ال
+
+316
+00:27:20,020 --> 00:27:23,480
+floor رابطته قوية؟ صعب، صعب، صعب، صعب، صعب، صعب،
+
+317
+00:27:23,480 --> 00:27:24,200
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+318
+00:27:24,200 --> 00:27:24,620
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+319
+00:27:24,620 --> 00:27:24,820
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+320
+00:27:24,820 --> 00:27:33,340
+صعب، صعب، صعب، صعب، صعب، صعب،
+
+321
+00:27:33,340 --> 00:27:41,060
+صعب، صعب، صعب،
+
+322
+00:27:41,060 --> 00:27:45,880
+صوبناء على ذلك عندما أعمل إبدال و أخد أمثلة على
+
+323
+00:27:45,880 --> 00:27:50,360
+الإبدال و أعمل حذف و في التفاعلين الإبدال و الحذف
+
+324
+00:27:50,360 --> 00:27:56,800
+تكسر فيه رابطة الأمثلة اللي هشوفها كلور بروم يود
+
+325
+00:27:56,800 --> 00:28:01,880
+مش هشوف أمثلة على ال floor لأن ال floor رابطة قوية
+
+326
+00:28:01,880 --> 00:28:06,380
+صعب كسرها وبناء على ذلك تفاعلات الإبدال و الحذف
+
+327
+00:28:06,380 --> 00:28:11,010
+مرتبطة بدول التلاتة ال floor برا الموضوعواضح
+
+328
+00:28:11,010 --> 00:28:17,150
+الفكرة؟ الآن
+
+329
+00:28:17,150 --> 00:28:22,890
+طالما احنا بنقول بدنا نكسر الرابط مع ال halogen
+
+330
+00:28:22,890 --> 00:28:28,230
+أني أضعف رابط فيهم اليود بناء على ذلك لو انا بعمل
+
+331
+00:28:28,230 --> 00:28:33,530
+تفاعل مع اليود بيكون سهل ولا صعب؟ سهل جداالبروم
+
+332
+00:28:33,530 --> 00:28:37,350
+بقعده في السهولة الكلور بقعده وعشان هيك لو انا بدى
+
+333
+00:28:37,350 --> 00:28:40,990
+اشوف ال rate of reaction لو كنت بفعل يود وبروم
+
+334
+00:28:40,990 --> 00:28:46,270
+وكلور مقارنة بعض و بالبعض أسرع تفاعل مع اليود أسرع
+
+335
+00:28:46,270 --> 00:28:51,580
+من البروم أسرع من الكلورلكلور والسبب قوة الرابطة
+
+336
+00:28:51,580 --> 00:28:56,100
+لأن هنا في رابطة ضعيفة بتنكسر بسهولة واضح الرابطة
+
+337
+00:28:56,100 --> 00:29:00,340
+مع اليود رابطة ضعيفة بتنكسر بسهولة يمكن هذا الكلام
+
+338
+00:29:00,340 --> 00:29:04,100
+حتى في الحياة العملية بتلاحظوا حتى في الحياة
+
+339
+00:29:04,100 --> 00:29:09,320
+العملية بتلاحظوا كثير من الأدوية مثلا موجود مكون
+
+340
+00:29:09,320 --> 00:29:15,660
+أساسي منها اليود هذه الأدوية لو اتعرضت لشوية حرارة
+
+341
+00:29:15,660 --> 00:29:20,980
+بسيطة أو لضوء الشمسبتنكسر الرابطة اللي معاليه طبعا
+
+342
+00:29:20,980 --> 00:29:24,240
+كنا انكسرت الرابطة إذا الدواء كله إيش صار فيه؟ خير
+
+343
+00:29:24,240 --> 00:29:28,680
+وعشان هيك هنلاحظ أن هذا النوع من الأدوية بيحطوه في
+
+344
+00:29:28,680 --> 00:29:33,800
+جزايز غامقة لونها بني وغالبا بيحفظوه بعيدا عن
+
+345
+00:29:33,800 --> 00:29:38,930
+الضوء و الحرارة و أحيانا في حرارة باردةيعني شوف
+
+346
+00:29:38,930 --> 00:29:43,690
+كيف لما مراتب تقرأ على شيء معين يحفظ بعيدا عن
+
+347
+00:29:43,690 --> 00:29:46,730
+الضوء و الحرارة ليش؟ بيكون هذا الشيء المعين فيه
+
+348
+00:29:46,730 --> 00:29:52,790
+روابط ضعيفة حتى حرارة الجو حتى على ضو الشمس ممكن
+
+349
+00:29:52,790 --> 00:29:58,410
+تتكسر فبنصير نحط مثلا جزاز بن يمنع أنه يدخل الضوء
+
+350
+00:29:58,410 --> 00:30:02,030
+بشكل كبير بنقبل حطه بعيد عن الضوء و عن الحرارة
+
+351
+00:30:02,030 --> 00:30:06,870
+ممكن يحتفظ فيهبالتلاجة على سبيل المثال كل هذا
+
+352
+00:30:06,870 --> 00:30:12,670
+نتيجة فهم قوة الروابط الكيميائية و دائما انتوا
+
+353
+00:30:12,670 --> 00:30:16,630
+يعني جزء منكوا في علوم الصحة و جزء في غيرها لحتى
+
+354
+00:30:16,630 --> 00:30:20,190
+تتعاملوا مع أدوى او اشياء اول ما بدكوا تمسكوا اي
+
+355
+00:30:20,190 --> 00:30:28,090
+عبو الدواء شغلتين الشيء الاول صحتكماقرأوا الكلام
+
+356
+00:30:28,090 --> 00:30:33,550
+اللي عليها، ضار، سام، يجوز أن نشمه، لا يجوز، كل
+
+357
+00:30:33,550 --> 00:30:38,050
+هذا الكلام مكتوب على العبوة ويله إشارات معينة،
+
+358
+00:30:38,050 --> 00:30:42,230
+بيحرق كوروسف مثلا زي أحماض إذا انكبت على الإيد
+
+359
+00:30:42,230 --> 00:30:46,200
+بتحرقها، إذا انكبت على الملابس بتحرقهامنفعش
+
+360
+00:30:46,200 --> 00:30:49,400
+الإنسان يتعامل مع أشياء و هو مش عارفها يكون
+
+361
+00:30:49,400 --> 00:30:55,240
+بيتعامل مع سم و بيسيبه ينكب على إيده و مابيغسلش و
+
+362
+00:30:55,240 --> 00:31:00,040
+مابياخدش احتياطات ولا بيلبس gloves ولا أي شيء و
+
+363
+00:31:00,040 --> 00:31:06,940
+شغلت تانية بيكون مكتوب عندكم كلمة storeاحفظه وانت
+
+364
+00:31:06,940 --> 00:31:12,160
+احفظه طبعا شغل اضافية بيكون عندكوا expire date انه
+
+365
+00:31:12,160 --> 00:31:16,120
+هذا بعد فترة معينة ما تفتحوه بيخرب بالذات كتير
+
+366
+00:31:16,120 --> 00:31:20,800
+مركبات بيكون مسكر عليها بشكل محكم لكن لما تفتحوها
+
+367
+00:31:20,800 --> 00:31:26,970
+تتفعل مع oxygen الهواءممكن تتفاعل مع الهوى نفسه أو
+
+368
+00:31:26,970 --> 00:31:31,370
+تمتص رطوبة من الهوى وبناء على ذلك تخرب فهتلاحظوا
+
+369
+00:31:31,370 --> 00:31:35,990
+بعض المراكبات مكتوب عليها لا يستعمل بعد أسبوع أو
+
+370
+00:31:35,990 --> 00:31:41,050
+أسبوعين من فتح العبوة كل إنسان بدي يتعامل بأدوية
+
+371
+00:31:41,050 --> 00:31:45,050
+أو pre agents بدي يكون منتبه لهذه الأمور وإلا
+
+372
+00:31:45,050 --> 00:31:47,470
+بيجعل بإيش؟ بالغلط
+
+373
+00:31:51,720 --> 00:31:57,640
+الان لو اجينا على التفاعلات تبعت ال alkyl halides
+
+374
+00:31:57,640 --> 00:32:04,320
+ممكن البعض يقول طب احنا ما أعطيناش التسمية مشعلة
+
+375
+00:32:04,320 --> 00:32:09,760
+جديدة مرت عليكم لما أخدنا ال alkenes يعني لو انا
+
+376
+00:32:09,760 --> 00:32:15,600
+جبتلكوا هذا المركب هذا
+
+377
+00:32:15,600 --> 00:32:22,830
+ال alkyl halide مين تسميه؟احد اتنين تلاتة اربعة
+
+378
+00:32:22,830 --> 00:32:30,340
+خمسة بنتين اثنان كلورو اثنان مثل بنتينأخدنا
+
+379
+00:32:30,340 --> 00:32:36,180
+التسمية ولا لأ؟ أخدنا التسمية طيب واحدة بتقول ماشي
+
+380
+00:32:36,180 --> 00:32:40,800
+التسمية أخدناها طيب و ال preparation التحضير هو
+
+381
+00:32:40,800 --> 00:32:45,220
+احنا عادة لما بندرس عائلة كيميائية اول اشي بنتعرف
+
+382
+00:32:45,220 --> 00:32:49,420
+على العائلة بعدين بناخد ال nomenclature التسمية
+
+383
+00:32:49,420 --> 00:32:54,500
+بعدين التحضير بعدين التفاعلات احنا عمال جاعدين
+
+384
+00:32:54,500 --> 00:33:00,060
+بنفض جزءالتسمية وشوفنا أننا أخدناها طب و جزء
+
+385
+00:33:00,060 --> 00:33:04,800
+التحضير أخدناها
+
+386
+00:33:04,800 --> 00:33:09,420
+من أكثر من طريقة أخدناها بأكثر من طريقة لما كنا
+
+387
+00:33:09,420 --> 00:33:13,220
+نيجي نقولكم مثلا ابرو بيل و اعملوله chlorination
+
+388
+00:33:13,220 --> 00:33:20,960
+شو كنتوا تطلعوا؟One Chloro, Two Chloro مش هذي
+
+389
+00:33:20,960 --> 00:33:25,680
+Alkyl Halides إذا ال Direct Halogenation طريقة من
+
+390
+00:33:25,680 --> 00:33:30,500
+طرق التحضير ولا لأ و حلينا عليها أمثلة تأكيد ..
+
+391
+00:33:30,500 --> 00:33:36,120
+تأكيد لما كنا .. هاي أول طريقة ال Halogenation طب
+
+392
+00:33:36,120 --> 00:33:42,440
+لو أعطيناكوا هذا المركب و قولنا لكم ضيفوا عليه HBR
+
+393
+00:33:46,050 --> 00:33:50,770
+هتقولولي مع Markovnikov ولا أنت Markovnikov؟ إذا
+
+394
+00:33:50,770 --> 00:33:55,510
+Markovnikov بيجي H و PR to Bromo وإذا أنت
+
+395
+00:33:55,510 --> 00:34:01,390
+Markovnikov H و PR و لا Bromo هذه المركبات مش ال
+
+396
+00:34:01,390 --> 00:34:06,230
+الهيليتز اللي نتجت الطريقة إذا أخدناها فإيش طروب
+
+397
+00:34:06,230 --> 00:34:12,210
+تحضير ال الهيليتز؟ نمرة واحد ال halogenation of
+
+398
+00:34:12,210 --> 00:34:20,960
+alkenesالـ Halogenation طب نمره اتنين ال addition
+
+399
+00:34:20,960 --> 00:34:29,660
+of HX to الكيين أو الكايين كمان لما كنا نضيف على
+
+400
+00:34:29,660 --> 00:34:37,360
+الكاين مرتين واضح؟ في طرق تالتة أخدناها في طريق
+
+401
+00:34:37,360 --> 00:34:42,920
+تالت لو هنا إجينا ضفنا على نفس هذا المركب PR2
+
+402
+00:34:46,320 --> 00:34:50,940
+أيش كان يعطيني؟ كان يعمل لي إضافة two PR atoms
+
+403
+00:34:50,940 --> 00:34:56,800
+بسين ولا ب Anti-addition؟ Anti-addition هيعمل لي
+
+404
+00:34:56,800 --> 00:35:03,020
+dihalo compound هذه طريقة الإبوكسايد رينج لو
+
+405
+00:35:03,020 --> 00:35:07,020
+فتحناها برضه بتصير طريقة إذا إحنا أخدنا الحقيقة
+
+406
+00:35:07,020 --> 00:35:14,730
+أكثر من طريقة لتحضيرالـ Halo Compounds في طريقة
+
+407
+00:35:14,730 --> 00:35:17,890
+إضافية
+
+408
+00:35:17,890 --> 00:35:23,610
+غير التلات طرق هدول اللي هم ال ال ال ال ال ال ال
+
+409
+00:35:23,610 --> 00:35:24,970
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+410
+00:35:24,970 --> 00:35:25,010
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+411
+00:35:25,010 --> 00:35:28,170
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+412
+00:35:28,170 --> 00:35:28,990
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+413
+00:35:28,990 --> 00:35:29,570
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+414
+00:35:29,570 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+415
+00:35:29,610 --> 00:35:33,550
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+416
+00:35:39,410 --> 00:35:46,970
+بتفاعلها ما عدش X أخليها RX يعني تحويل الكحول إلى
+
+417
+00:35:46,970 --> 00:35:51,810
+الكلهلايت هذه الطريقة لها تفاصيل كتير لما ندرس
+
+418
+00:35:51,810 --> 00:35:55,630
+chapter الكحولات بندرس كتفاعل على الكحول يعني
+
+419
+00:35:55,630 --> 00:36:00,290
+بإمكاننا ندرسها الأن كطريقة للتحضير و بإمكاننا
+
+420
+00:36:00,290 --> 00:36:05,900
+ندرسها في chapter الكحولات كتفاعل على الكحولواضح؟
+
+421
+00:36:05,900 --> 00:36:10,640
+هذا كحول، هذا الكلهلايت، بالنسبة للكحول هي تفاعل،
+
+422
+00:36:10,640 --> 00:36:14,980
+بالنسبة لالكلهلايت هي طريقة تحضير، لما ندرس
+
+423
+00:36:14,980 --> 00:36:19,720
+الكحولات و تفاعلاتها، هيكون عندنا تفاعل أساسي
+
+424
+00:36:19,720 --> 00:36:27,560
+تحويلالكحول إلى ال alkyl halides بمجموعة من
+
+425
+00:36:27,560 --> 00:36:31,440
+التفاصيل بندرسها بوقته، هاي بتصير كمان طريقة
+
+426
+00:36:31,440 --> 00:36:39,390
+إضافية لتحضير ال alkyl halidesكام طريقة؟ اربعة مين
+
+427
+00:36:39,390 --> 00:36:44,790
+تقول اليوم باختصار اتفضلي ال direct halogenation
+
+428
+00:36:44,790 --> 00:36:48,330
+في وجود الضوء او الحرارة لل ال alkenes اضافة ال X2
+
+429
+00:36:48,330 --> 00:36:56,190
+لل ال alkenes او اضافة ال HX
+
+430
+00:36:56,190 --> 00:37:01,620
+لل ال alkenes او لل ال alkynesو بعدين من الكحولات
+
+431
+00:37:01,620 --> 00:37:05,900
+في وجود HX او reagents تانية بندرسها في chapter
+
+432
+00:37:05,900 --> 00:37:10,860
+الكحولات هيصيرنا ذاكرينكوا كم طريقة اربع طرق
+
+433
+00:37:10,860 --> 00:37:15,380
+لتحضير ال alkyl halides تلاتة أخدتهم و طريقة
+
+434
+00:37:15,380 --> 00:37:24,180
+بندرسها في chapter الكحولات الآن التفاعل الأساسي
+
+435
+00:37:24,180 --> 00:37:30,380
+لل alkyl halides هو تفاعلالإبدال التفاعل الأساسي
+
+436
+00:37:30,380 --> 00:37:34,860
+لـ alkalites هو تفاعل الإبدال لو أنا أتي أتطلع طيب
+
+437
+00:37:34,860 --> 00:37:38,920
+إيش اللي بده أبدله؟ وكيف بده يتم الإبدال اللي
+
+438
+00:37:38,920 --> 00:37:44,480
+عندي؟ اتطلعوا هاي عندي carbon حاملة نفترض PR وهنا
+
+439
+00:37:44,480 --> 00:37:49,400
+في تلت روابط، بلاش نركز عليهم شو هما الآن إيش
+
+440
+00:37:49,400 --> 00:37:55,520
+اتفقنا على الرابط اللي موجود هنا؟قول لعنها بولا
+
+441
+00:37:55,520 --> 00:38:02,180
+يعني هذه موجبة وهذه سالبة بناء على ذلك هلاحظ أن
+
+442
+00:38:02,180 --> 00:38:06,720
+التفاعل الأساسي عندنا لما بناجي المرة الجاية اللي
+
+443
+00:38:06,720 --> 00:38:10,500
+اتكلم أنه بيجي نيوكليوفايل لإن نيوكليوفايل حامل
+
+444
+00:38:10,500 --> 00:38:15,840
+إلكترونات وين بيهاجم؟ على الكاربون الموجب يعني هذا
+
+445
+00:38:15,840 --> 00:38:22,560
+سالب للنيوكليوفايل سالب بيجي إيش بيطلعك باله؟ سالب
+
+446
+00:38:23,370 --> 00:38:27,830
+السالب هاجم على الكربون الموجب، طرد سالب إجا سالب،
+
+447
+00:38:27,830 --> 00:38:33,550
+طرد سالب، إجا موجب، طرد موجب أخدنا في البنزين
+
+448
+00:38:33,550 --> 00:38:38,190
+الإبدال إيش كان؟ موجب مكان موجب، سميناها
+
+449
+00:38:38,190 --> 00:38:41,950
+Electrophilic Substitution الآن هنا بدو ييجي سالب
+
+450
+00:38:41,950 --> 00:38:47,030
+مكان سالب، يعني إيش اللي بدو يطرد؟ ال X مع
+
+451
+00:38:47,030 --> 00:38:52,340
+إلكتروناته، شو اللي بدو يهاجم؟لنيوكليوفايل و بناء
+
+452
+00:38:52,340 --> 00:38:56,880
+على ذلك بيصير المفروض فينا نتذكر ايش معنى
+
+453
+00:38:56,880 --> 00:39:01,040
+النيوكليوفايل اللي بدو يهاجم هنا و يحل محل ال X
+
+454
+00:39:01,040 --> 00:39:06,220
+ولذلك المرة القادمة هنبدأ من كلمة ايش الـ
+
+455
+00:39:06,220 --> 00:39:11,190
+Eucleophilic Substitution يعني نبدأ نتعرف علىللـ
+
+456
+00:39:11,190 --> 00:39:14,950
+nucleophile اللي بده يهاجم ويبدأ التفاعل لأن الـ
+
+457
+00:39:14,950 --> 00:39:18,790
+nucleophile هو السالب اللي بده يهاجم ويحل محل
+
+458
+00:39:18,790 --> 00:39:23,630
+الهالوجين السالبة يعمل عملية الإبدال شكرا
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..54b2147223cfbe17d3c5218f6b768d83532d41d9
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_raw.srt
@@ -0,0 +1,1852 @@
+1
+00:00:21,210 --> 00:00:26,340
+بسم الله الرحمن الرحيمباقي عندنا في موضوع
+
+2
+00:00:26,340 --> 00:00:30,340
+التفاعلات او التفاعلات المرتبطة بال
+
+3
+00:00:30,340 --> 00:00:34,940
+stereochemistry شغلتين بسيطات احنا اتكلمنا في
+
+4
+00:00:34,940 --> 00:00:38,600
+الاول على نقطة كتير مهمة او على تفاعل كتير مهم
+
+5
+00:00:38,600 --> 00:00:43,740
+قولنا دائما في المختبر بالوضع الطبيعي لما نعمل
+
+6
+00:00:43,740 --> 00:00:47,560
+generation of a chiral center بيطلع عندى racemic
+
+7
+00:00:47,560 --> 00:00:50,400
+mixture equal mixture of enantiomers و هذا بده
+
+8
+00:00:50,400 --> 00:00:54,830
+غلبة و بده فصل و ما إلى ذلكوالان بيحاولوا انهم
+
+9
+00:00:54,830 --> 00:00:59,250
+يتغلبوا على هذا الكلام من خلال تقنيات حديثة في
+
+10
+00:00:59,250 --> 00:01:04,390
+التحضير بيسموها asymmetric synthesis هذا التفاعل
+
+11
+00:01:04,390 --> 00:01:10,030
+الأولالتفاعل التاني، لو أنا يا تورا بعمل تفاعل
+
+12
+00:01:10,030 --> 00:01:15,450
+بعيدا عن ال chiral center، الآن إيش معنى بعيدا عن
+
+13
+00:01:15,450 --> 00:01:21,310
+ال chiral center؟ بمعنى لأكسر رابطة متصلة بال
+
+14
+00:01:21,310 --> 00:01:25,330
+chiral center، يعني الأربع روابط المتصلين بال
+
+15
+00:01:25,330 --> 00:01:30,950
+chiral center بكسرهم مشكل ما بعد ذلك يعتبر ايش؟
+
+16
+00:01:30,950 --> 00:01:35,230
+تفاعل بعيد عن الـ Chiral Center واضح الفكرة؟ يعني
+
+17
+00:01:35,230 --> 00:01:39,110
+مثلا في هذا المركب، عندي هنا أنا Chiral Center
+
+18
+00:01:39,110 --> 00:01:45,010
+متصل بـ Methyl و بـ Ethyl و COH و بH، الآن هذا الـ
+
+19
+00:01:45,010 --> 00:01:50,240
+Chiral Center عليه كام رابطةأربع روابط لو أنا بدي
+
+20
+00:01:50,240 --> 00:01:55,460
+أبدل مجموعة ال O H هنا اللي هي ال acidic O H
+
+21
+00:01:55,460 --> 00:02:01,200
+مجموعة ال O H الحامضية هذه كلها بمجموعة O Ethyl
+
+22
+00:02:01,200 --> 00:02:06,420
+بمعنى في الكيميا هذا التفاعل هنتعلمه بنبدل فيه ال
+
+23
+00:02:06,420 --> 00:02:12,340
+acid ل E starباستعمال التفاعل مع الكحول شيلت الـ
+
+24
+00:02:12,340 --> 00:02:19,240
+OH و خلتها ايش؟ O Ethan الان هذه الأربع رواضة كسرت
+
+25
+00:02:19,240 --> 00:02:25,380
+جزء منها؟ لأ وبناء على ذلكالجيومتري حوالين
+
+26
+00:02:25,380 --> 00:02:28,640
+الكايرال كاربون الشكل اللذس حوالين الكايرال كاربون
+
+27
+00:02:28,640 --> 00:02:33,620
+بيضل زي ما هو فأنا كأن بعمل عملية ايش نسخ و لصق
+
+28
+00:02:33,620 --> 00:02:38,960
+بلغة الكمبيوتر يعني باجي بعمل نسخ لهذا بكل موابط و
+
+29
+00:02:38,960 --> 00:02:43,740
+لاحظوا ال H باتجاه ال CO باتجاه ال CH3 ال إثل بحطه
+
+30
+00:02:43,740 --> 00:02:48,120
+هنا و بعمل التغيير اللي عندهو بناء على ذلك بنقول
+
+31
+00:02:48,120 --> 00:02:52,740
+انه تم عنده retention of configuration يعني الشكل
+
+32
+00:02:52,740 --> 00:02:58,360
+ضل زي ما هو اتجاه الاربع روابط اللي محيطين بال
+
+33
+00:02:58,360 --> 00:03:03,440
+chiral center ضالهم ايش زي ما هو لو انا بدي اعطيكم
+
+34
+00:03:03,440 --> 00:03:07,700
+مثال يعني تخيلوا مثلا انا بهذا الشكل هينعمل chiral
+
+35
+00:03:07,700 --> 00:03:12,260
+center من اربع شغلاتوأتيت أعمل التفاعل هنا كان
+
+36
+00:03:12,260 --> 00:03:15,900
+مافيش في إيدي جلم امسكت جلم هل غيرت في اتجاه
+
+37
+00:03:15,900 --> 00:03:19,480
+الأربع روابط ولا في عند retention of configuration
+
+38
+00:03:19,480 --> 00:03:23,760
+في عند retention of configuration إذا التفاعل
+
+39
+00:03:23,760 --> 00:03:28,720
+بعيدا عن ال chiral center بتم في retention of
+
+40
+00:03:28,720 --> 00:03:31,660
+configuration معنى retention of configuration أن
+
+41
+00:03:31,660 --> 00:03:36,600
+اتجاهات الروابط الأربع تبقى كما هي لم نكسر شيء
+
+42
+00:03:36,600 --> 00:03:42,300
+حولهاكذلك الحال هنا احنا حاطين مثال تاني لو فعلنا
+
+43
+00:03:42,300 --> 00:03:47,740
+هذا المركب يعلن الكايرال سنتر بدلنا هذه ال O H
+
+44
+00:03:47,740 --> 00:03:51,740
+خلناها C double bond O باستعمال اكسدة ابعام
+
+45
+00:03:51,740 --> 00:03:53,620
+المؤكسل عادة بنسميه
+
+46
+00:03:56,470 --> 00:04:01,290
+الان هذول الاربع روابط صار عندهم تغيير و لا تغيير
+
+47
+00:04:01,290 --> 00:04:06,390
+بعد الكايرالسينفاق بعد اذا كل الاتجاهات تبقى كما
+
+48
+00:04:06,390 --> 00:04:13,840
+هي CLH CH2 CH3 الـC هادىالتغير بعدها ما كسرت روابط
+
+49
+00:04:13,840 --> 00:04:16,660
+بالتصيلة بال chiral center مرة تانية في عندي
+
+50
+00:04:16,660 --> 00:04:20,280
+retention of configuration إذا ال reaction away
+
+51
+00:04:20,280 --> 00:04:23,160
+from a chiral center results in retention of
+
+52
+00:04:23,160 --> 00:04:30,000
+configuration الآن بهمني أعطي بس ملاحظة خفيفةالـ
+
+53
+00:04:30,000 --> 00:04:34,600
+retention of configuration معناه أن الأربع روابط
+
+54
+00:04:34,600 --> 00:04:39,720
+تبقى في اتجاهاتها ليس له علاقة .. ليس له علاقة
+
+55
+00:04:39,720 --> 00:04:46,100
+بكلمة R و S أنا هنا و أنا بشتغل كتبت R ولا S ولا
+
+56
+00:04:46,100 --> 00:04:50,380
+شفت أن ال R دلت R ولا ال S دلت S؟ ماجبتش سيرة
+
+57
+00:04:50,380 --> 00:04:55,100
+هالكلام، ليش؟ لأنه أنا لما بغير مجموعة هنا أو هنا
+
+58
+00:04:55,100 --> 00:05:02,890
+ممكن الأولويات تتغير؟ أكيدأكيد حتى لو غيرت مجموعة
+
+59
+00:05:02,890 --> 00:05:06,790
+بعيد ممكن يصير فيه تغيير بالأولويات و لذلك ممكن R
+
+60
+00:05:06,790 --> 00:05:11,430
+عند الضل R ممكن R تصير S ممكن S تصير R ممكن S تظل
+
+61
+00:05:11,430 --> 00:05:16,370
+S أو تتقلب إلى R هذا موضوع ما درسته انا اطلاقا انا
+
+62
+00:05:16,370 --> 00:05:21,650
+بدرس الأربع روابط في اتجاهاتهم فيهم تغيير ولا لأ
+
+63
+00:05:21,650 --> 00:05:26,020
+هى معناه retention of configuration الان R و Sمن
+
+64
+00:05:26,020 --> 00:05:31,160
+أول و جديد في عندكم اشي اسمه قواعد ترتيب المجموعات
+
+65
+00:05:31,160 --> 00:05:36,320
+حسب الأولويات واحد اتنين تلاتة اربعة بنرتبهم ضلت
+
+66
+00:05:36,320 --> 00:05:41,460
+الارار صارت اسم مش مشيء بالنسبة الي واضح الفكرة
+
+67
+00:05:41,460 --> 00:05:47,200
+فكلمة retention of configurationلا تعني اطلاقا ..
+
+68
+00:05:47,200 --> 00:05:52,700
+لا تعني اطلاقا ان ال R دلت R او ال S دلت S لأ تعني
+
+69
+00:05:52,700 --> 00:05:58,520
+ان الأربع روابط ضالهم باتجاههم ال R و ال S اولويات
+
+70
+00:05:58,520 --> 00:06:01,420
+اللي بيحسب اولويات يشوف حسب المثال اللي عنده
+
+71
+00:06:01,420 --> 00:06:05,480
+هتلاقوا مثال بتم فيه تغيير مثال بتم مش فيه تغيير
+
+72
+00:06:05,480 --> 00:06:09,460
+حسب هالمجموعة اللي طلعت و المجموعة اللي اجت هذا
+
+73
+00:06:09,460 --> 00:06:15,200
+موضوع تاني واضح الفكرة؟وهذا كثير بنسألكم بمعناه
+
+74
+00:06:15,200 --> 00:06:19,280
+انه هالمعنى كلمة retention of configuration means
+
+75
+00:06:19,280 --> 00:06:24,420
+are must be are in the product لأ مش ضروري ممكن
+
+76
+00:06:24,420 --> 00:06:29,400
+تظل ممكن تتغير هذا موضوع و هذا موضوع تاني
+
+77
+00:06:33,710 --> 00:06:39,030
+هذه تفاعلات بناخدها بعدين بس بنعطيها كأمثلة يعني
+
+78
+00:06:39,030 --> 00:06:43,710
+هذا تأكسد كحول إلى aldehyde لما ندرس chapter
+
+79
+00:06:43,710 --> 00:06:49,410
+الكحولات ب chapter 7 بنشرحه الآن بديش أنا أسمي لا
+
+80
+00:06:49,410 --> 00:06:52,750
+كحول ولا aldehyde أنا قلت ال Canada دي CO single
+
+81
+00:06:52,750 --> 00:06:57,840
+bond صارت CO double bond غيرت هان ولا لأ؟تستعجلوش
+
+82
+00:06:57,840 --> 00:07:02,880
+العلم هذا تحول حامض إلى Easter بدلت ال OH ب Oethel
+
+83
+00:07:02,880 --> 00:07:08,140
+بدرسه ب Chapter 10 مش هو موضوعي غيرت بدي ألغي كل
+
+84
+00:07:08,140 --> 00:07:13,060
+اللي كاتبه و أكتب XY عشان اترايحيني أعصابي خلت XY
+
+85
+00:07:13,060 --> 00:07:14,980
+واضح؟
+
+86
+00:07:16,500 --> 00:07:21,120
+دائما تتعبوش أنفسكم في الفكرة غير الأساسية بدلت X
+
+87
+00:07:21,120 --> 00:07:26,760
+بY إيش التفاعل مش مشكلة مش X صارت Y تفاعل general
+
+88
+00:07:26,760 --> 00:07:31,520
+بدلته بعيدا عن ال chiral center إيش بيظل عنده
+
+89
+00:07:31,520 --> 00:07:37,960
+retention إنما هدولا التفاعلين كتفصيل بناخدهم في
+
+90
+00:07:37,960 --> 00:07:43,160
+chapter 7 أو chapter 10 لكن استعانا فيهم كأمثلة
+
+91
+00:07:45,090 --> 00:07:50,130
+التفاعل التالت generation of a second chiral
+
+92
+00:07:50,130 --> 00:07:54,370
+center يعني لاحظوا احنا اول مرة قولنا ماكنش لنا
+
+93
+00:07:54,370 --> 00:07:57,390
+chiral center نهائي و عملنا له generation، شو طلع
+
+94
+00:07:57,390 --> 00:08:04,840
+عندى؟ رسمic mixtureتاني تفاعل لما اعملت تفاعل بعيد
+
+95
+00:08:04,840 --> 00:08:08,320
+عن الكايرال سنتر شو صار عندى retention of
+
+96
+00:08:08,320 --> 00:08:13,880
+configuration طيب الآن لو كان في عندى كايرال سنتر
+
+97
+00:08:13,880 --> 00:08:19,160
+اول و بدى اعمل كايرال سنتر تاني شو بده يصير عندى؟
+
+98
+00:08:19,160 --> 00:08:25,120
+خلّينا نشوف مثال هذه مثال لو طلعنا على هذا المركب
+
+99
+00:08:25,120 --> 00:08:29,880
+الآن هذه الكاربون اللى موجودة هنا بتحمل مثل
+
+100
+00:08:29,880 --> 00:08:33,970
+وchloro Hو المجموعة اللي فيها double bond كايرال
+
+101
+00:08:33,970 --> 00:08:39,290
+سنتر ولا لأ كايرال سنتر انا مش موضوعي اطلاقا هذه
+
+102
+00:08:39,290 --> 00:08:42,770
+ال carbon بدي اعمل التفاعل على ال double bond يعني
+
+103
+00:08:42,770 --> 00:08:48,160
+على ال double bond بدي اجي اضيف hbr في وجودH plus
+
+104
+00:08:48,160 --> 00:08:53,940
+هذه أخدناها إضافة Markovnikov يعني بدأ أحط ال H
+
+105
+00:08:53,940 --> 00:09:00,080
+هنا في الأول أبدأ تفاعل بإضافة ال H هنا وبعدين
+
+106
+00:09:00,080 --> 00:09:06,260
+أكمل ال PR على هذا الموقع لاحظوا إيش اللي بدو يصير
+
+107
+00:09:06,260 --> 00:09:12,060
+عندي لما أضيف ال H على هذا الموقع كام رابط هيظل
+
+108
+00:09:12,060 --> 00:09:20,250
+على هذه النقطة تلت روابط تلت روابطحاولوا تستحضروا
+
+109
+00:09:20,250 --> 00:09:24,510
+الشكل مع الهيدروجين المحذوف مع الهيدروجين المحذوف
+
+110
+00:09:24,510 --> 00:09:30,210
+أعطيكم H هاي
+
+111
+00:09:30,210 --> 00:09:35,830
+الشكل الكامل واضح؟ لما أضيف هنا H هذا الكربون بدل
+
+112
+00:09:35,830 --> 00:09:41,630
+ما يكون CH2 ماذا سيحصل؟ CH3 سيحصل CH3 و ال double
+
+113
+00:09:41,630 --> 00:09:48,850
+bond هذه ستذهب علىأساس أنه هيجي يخجم عندي هنا PR
+
+114
+00:09:48,850 --> 00:09:53,270
+في الخطوة التالية الآن لاحظوا معي لو اتطلعنا على
+
+115
+00:09:53,270 --> 00:09:58,450
+هذا الجزء هذا الجزء يا ترى هل احنا بنشتغل قريب عنه
+
+116
+00:09:58,450 --> 00:10:04,430
+ولا بالنسبة له بنشتغل reaction away from a chiral
+
+117
+00:10:04,430 --> 00:10:08,290
+center away from a chiral center وعشانك بنحطه زي
+
+118
+00:10:08,290 --> 00:10:10,630
+ما هو لاحظوا إيش معناه retention of configuration
+
+119
+00:10:10,630 --> 00:10:14,750
+المثل اللي فوق ال CL على اليمين ال H على الشمالهذا
+
+120
+00:10:14,750 --> 00:10:19,010
+retention of configuration ولا لأ؟ الآن هذه النقطة
+
+121
+00:10:19,010 --> 00:10:27,690
+هي النقطة اللي هنا ال CH2 شو صارت؟ CH3 و هذه ما
+
+122
+00:10:27,690 --> 00:10:35,090
+زالت H و الآن أنا بانتظار ال PR لما نيجي نطلع
+
+123
+00:10:35,090 --> 00:10:38,130
+حوالين هذه ال carbon ايش الشكل؟
+
+124
+00:10:40,850 --> 00:10:46,950
+بناء على ذلك بنتوقع ان ال PR بإمكانها تهجم من
+
+125
+00:10:46,950 --> 00:10:51,010
+الجهتين زي ما أخذنا في أول مرة لما درسنا ال
+
+126
+00:10:51,010 --> 00:10:53,950
+generation of a chiral center بمعنى ال PR ممكن
+
+127
+00:10:53,950 --> 00:10:58,830
+تيجي من هنا و ال PR ممكن تيجي تهاجي من هنا إذا كام
+
+128
+00:10:58,830 --> 00:11:03,070
+ناتج بدو يطلع عندى هى ال PR إذا إجت من هذا الاتجاه
+
+129
+00:11:03,070 --> 00:11:09,380
+و هى ال PR إذا إجت من الاتجاه التالفزي لما درسنا
+
+130
+00:11:09,380 --> 00:11:12,600
+اول مرة الـ Chiral Center تقولنا عندنا بلانر
+
+131
+00:11:12,600 --> 00:11:18,100
+انترميديت تم التفاعل من ايه؟ من الجهتين الان هنا
+
+132
+00:11:18,100 --> 00:11:22,180
+في عند بلانر انترميديت اتكونت نتيجة انه ضفت اتش
+
+133
+00:11:22,180 --> 00:11:29,780
+لغية ال bubble bond التفاعل بإمكانه تم من الجهتينو
+
+134
+00:11:29,780 --> 00:11:35,340
+بناء على ذلك كام ناتج يطلع عنده؟ اتنين بيفرق عن
+
+135
+00:11:35,340 --> 00:11:40,880
+المثال الأول بشغل واحدة انه هل يترى الاحتمالات
+
+136
+00:11:40,880 --> 00:11:44,860
+متساوية ان هذا ييجي عن اليمين او عن الشمال في
+
+137
+00:11:44,860 --> 00:11:48,960
+generation of a first chiral center كنا نقول
+
+138
+00:11:48,960 --> 00:11:54,000
+الاحتمالات بتكون متساوية و بناء على ذلك يطلع عنده
+
+139
+00:11:55,740 --> 00:12:01,120
+الان بسبب وجود الكايرال سنتر الاول اللى بيخل
+
+140
+00:12:01,120 --> 00:12:06,400
+الفراغات حوالين هذا الكاربون غير متساوية مابيكونوش
+
+141
+00:12:06,400 --> 00:12:13,720
+الاحتمالين بنفس المقدار فبتم صحيح هجوم من الجهتين
+
+142
+00:12:13,720 --> 00:12:20,570
+ولكن ليسبنسب متساوية يعني مابيجيش 50% من التفاعل
+
+143
+00:12:20,570 --> 00:12:24,430
+من هنا و 50% من التفاعل من هنا ليش هذا الكلام
+
+144
+00:12:24,430 --> 00:12:30,240
+امتنع؟بسبب وجود ال chiral center اللي بيخلي جهة
+
+145
+00:12:30,240 --> 00:12:35,240
+أحيانا مغلقة أكتر من الجهة التانية بيصير فيه فرق
+
+146
+00:12:35,240 --> 00:12:40,180
+بالوسع زي إنسان كان عنده مسارين متساويين تماما
+
+147
+00:12:40,180 --> 00:12:44,520
+بيمكنه يمشي من هنا و من هنا الآن إجا شيء سكر جزء
+
+148
+00:12:44,520 --> 00:12:50,520
+من مسار معين بيضلوا يمشي بنفس النسبة ولا غالبا
+
+149
+00:12:50,520 --> 00:12:55,530
+بيروح على المسار الأكتر يعني ساعة و فراغواضح
+
+150
+00:12:55,530 --> 00:13:00,610
+الفكرة؟ الآن شو اللي خلّى عدم التساوي؟ الكايرال
+
+151
+00:13:00,610 --> 00:13:04,450
+سنتر الأول الكايرال سنتر الأول بيخلّى عدم تساوي
+
+152
+00:13:04,450 --> 00:13:08,890
+إذا لو أنا اتطلعت الآن على هدول الناتجين اللي
+
+153
+00:13:08,890 --> 00:13:13,610
+طلعوا بنسب متساوي ولا غير متساوية؟ غير متساوية غير
+
+154
+00:13:13,610 --> 00:13:17,690
+متساوية in unequal amounts وسألت يا تورا ما
+
+155
+00:13:17,690 --> 00:13:24,530
+العلاقة بين هدول المركبين اللي طلعوا عندهم؟لاحظوا
+
+156
+00:13:24,530 --> 00:13:30,570
+هذا الجزء و هذا الجزء ايش مالهم صورة بعض في المرأة
+
+157
+00:13:30,570 --> 00:13:36,450
+و متعاكسة طب و هذا و هذا نفس الشيء إذا المركب كله
+
+158
+00:13:36,450 --> 00:13:42,110
+صورة بعض و لا لأ إذا بدكم تعملوا باستعمال الرموز
+
+159
+00:13:42,110 --> 00:13:49,370
+بإمكانكم تعملوا R و S بمعنى نلغي هذه ال edge هعندي
+
+160
+00:13:49,370 --> 00:13:55,180
+واحد اتنين تلاتة هذه البيانة Rهذه S الانهان ما
+
+161
+00:13:55,180 --> 00:14:00,540
+اتغيرت ضلت زي ما هي هالكلور و بعدين كربون حملة
+
+162
+00:14:00,540 --> 00:14:06,460
+برون بعدين اذا هذه ايش S طيب لو اتيت و طلعت هنا
+
+163
+00:14:06,460 --> 00:14:09,900
+واحد
+
+164
+00:14:09,900 --> 00:14:14,640
+اتنين R
+
+165
+00:14:14,640 --> 00:14:21,860
+S هذه واحد اتنين R S
+
+166
+00:14:24,660 --> 00:14:31,600
+مكتوبها R رجعوهم بهدوء ال R شيء متعاكس وشيء متساوي
+
+167
+00:14:31,600 --> 00:14:37,740
+اذا هدوله ايش ديستريو مارس ف ال generation of a
+
+168
+00:14:37,740 --> 00:14:42,920
+second chiral center المحاصلة تبعته it results in
+
+169
+00:14:42,920 --> 00:14:46,560
+diastereomeric products at different rates بسرعة
+
+170
+00:14:46,560 --> 00:14:53,300
+مختلفة الأهم منها and inunequal amounts يعني لو
+
+171
+00:14:53,300 --> 00:14:56,520
+أنا باسألكوا سؤال صح و غلط generation of a second
+
+172
+00:14:56,520 --> 00:15:00,580
+chiral center results in the stereomeric mixture
+
+173
+00:15:00,580 --> 00:15:06,440
+or products in equal amounts and unequal amounts
+
+174
+00:15:06,590 --> 00:15:10,050
+طبعا ليش صار الـ unequal amount؟ because of the
+
+175
+00:15:10,050 --> 00:15:14,750
+presence of the first chiral center وجود ال chiral
+
+176
+00:15:14,750 --> 00:15:19,390
+center الأول خلّى احتمالات الهجوم من الجهتين غير
+
+177
+00:15:19,390 --> 00:15:22,770
+متساوي يعني الوسع اللي موجود من الجهة بختلف عن
+
+178
+00:15:22,770 --> 00:15:25,370
+الوسع اللي موجود من الجهة التانية الآن ذرة بدأت
+
+179
+00:15:25,370 --> 00:15:29,370
+تتفاعل التفاعل هو هجوم، ذرة ماشية و بدأت تيجي الآن
+
+180
+00:15:29,370 --> 00:15:31,850
+دايما اللي بدو يروح، يروح من المنطقة الواسعة ولا
+
+181
+00:15:31,850 --> 00:15:39,690
+الديقة؟ من المنطقة الواسعة، واضح؟هذا المحصلة
+
+182
+00:15:39,690 --> 00:15:44,370
+بالنسبة لعملية generation of a chiral center وزي
+
+183
+00:15:44,370 --> 00:15:48,650
+ما لاحظته ان هذا التفاعل بيدمج التفاعلين السابقين
+
+184
+00:15:48,650 --> 00:15:53,490
+يعني بالنسبة لهذا هو تفاعل بعيد عنه ولذلك هذا
+
+185
+00:15:53,490 --> 00:15:58,870
+الجزء ايش ماله؟ ضال في retention of configuration
+
+186
+00:15:58,870 --> 00:16:04,250
+وال generation of a chiral center تمهن ولكن بنسبة
+
+187
+00:16:04,250 --> 00:16:05,990
+غير متساوية
+
+188
+00:16:07,980 --> 00:16:11,920
+بهيك احنا بننتهي من chapter ال stereochemistry في
+
+189
+00:16:11,920 --> 00:16:15,120
+عندكم slide عن resolution of enantiomers اتكلمنا
+
+190
+00:16:15,120 --> 00:16:19,500
+عنها اللي هي فصل ال enantiomers لو حضرناهم كخليط
+
+191
+00:16:19,500 --> 00:16:24,060
+متساوي وقولنا ان هذه العملية بكل الأحوال مش عملية
+
+192
+00:16:24,060 --> 00:16:30,580
+سهلة يمكن ان تعمل بعدة طرق فنية في المختبرات لكن
+
+193
+00:16:30,580 --> 00:16:36,120
+بتاخد وقت ومش عملية سهلة والافضل من resolution of
+
+194
+00:16:36,120 --> 00:16:42,550
+enantiomersأما أن أخد المركب نقي من الطبيعة أو
+
+195
+00:16:42,550 --> 00:16:46,930
+الاحتمال التاني لو و لابد في المختبر ان اعمل
+
+196
+00:16:46,930 --> 00:16:51,710
+asymmetric synthesis انتبهوا معي لو بدأ اقول ايش
+
+197
+00:16:51,710 --> 00:16:58,110
+افضل اشي للوصول للمركبات النقية نمرة واحد من ال
+
+198
+00:16:58,110 --> 00:17:04,230
+nature الطبيعة بتعطينا مركبات نقية نمرة اتنين ان
+
+199
+00:17:04,230 --> 00:17:10,070
+اعملasymmetric synthesis يعني أعمل synthesis
+
+200
+00:17:10,070 --> 00:17:18,670
+يعطيني واحد أكتر من التاني نمرة تلاتة أن أعمل ال
+
+201
+00:17:18,670 --> 00:17:21,950
+synthesis اللي حكينا اللي بيطلعوا التنين متساويات
+
+202
+00:17:21,950 --> 00:17:26,890
+في اللي إيش اسمه symmetric synthesis لكن ال
+
+203
+00:17:26,890 --> 00:17:31,650
+symmetric synthesis إيش بدوا يتبعوه؟Symmetric
+
+204
+00:17:31,650 --> 00:17:36,050
+Synthesis هذا يجب ان يتبع Resolution لان افصلهم
+
+205
+00:17:36,050 --> 00:17:41,430
+بتجارب صعبة الانزيمات
+
+206
+00:17:41,430 --> 00:17:48,760
+في ال nature ال catalystsبمواصفات معينة عادة كيرال
+
+207
+00:17:48,760 --> 00:17:53,500
+كتاليست في الطريقة التانية يعني اللي بيساعد على ان
+
+208
+00:17:53,500 --> 00:17:57,920
+انا احصل على المركب النقي في ال nature اللي هو ال
+
+209
+00:17:57,920 --> 00:18:02,820
+enzymes الان اللي بيساعد على ان احصل على ال
+
+210
+00:18:02,820 --> 00:18:05,880
+asymmetric synthesis يعني يطلعوا مش بنسبة متساوية
+
+211
+00:18:05,880 --> 00:18:09,280
+واحد اكثر من التاني الى درجة اقترب من النقاوة
+
+212
+00:18:09,280 --> 00:18:14,360
+احيانا ان انا باستعملكتاليست والكتاليست بيكون
+
+213
+00:18:14,360 --> 00:18:21,260
+كايرة الكتاليست عادة واضح؟ الان هذه طرق وقاية ليش
+
+214
+00:18:21,260 --> 00:18:25,000
+بعملها؟ عشان ما اجعش انه طلع عندى خليطه اتغلب
+
+215
+00:18:25,000 --> 00:18:28,640
+بفاصله لو مامشيش بهذه الطريقة او بهذه الطريقة
+
+216
+00:18:28,640 --> 00:18:33,220
+اعملت symmetric synthesis خليط متساوي من الاتنين و
+
+217
+00:18:33,220 --> 00:18:37,980
+اجت بدأ اجع في مشكلة ايش؟فصل الخليط يعني الخليط
+
+218
+00:18:37,980 --> 00:18:42,560
+اللى عندى نفترض R و S بدأ ادخل على عملية الفصل شو
+
+219
+00:18:42,560 --> 00:18:47,640
+بنسميها الفصل resolution هذه يمكن أن تتم باكثر من
+
+220
+00:18:47,640 --> 00:18:52,720
+طريقة كيميائية لكن بكل الأوقات ما تفكروش أنها
+
+221
+00:18:52,720 --> 00:18:57,080
+طريقة سهلة طريقة صعبة يعني أحيانا انتوا بيكونوا
+
+222
+00:18:57,080 --> 00:19:02,860
+التخيل عندكمانه شغلة صعبة يعني بدي اخد مختبر بدل
+
+223
+00:19:02,860 --> 00:19:07,300
+ما يكون ساعتين يكون تلت ساعات وانتهي ان انا فصلت
+
+224
+00:19:07,300 --> 00:19:11,020
+المادة لأ لما انا بقول ال resolution of
+
+225
+00:19:11,020 --> 00:19:15,520
+enhancements عملية صعبة يعني واحد باحث بيشتغل وطلع
+
+226
+00:19:15,520 --> 00:19:20,340
+عنده mix chart و بده يبدأ يفصل فيه ممكن الأمور معه
+
+227
+00:19:20,340 --> 00:19:23,640
+اذا بدأ من نقطة الصفر وماعندهش اي فكرة على الموضوع
+
+228
+00:19:23,640 --> 00:19:28,770
+يبدأ تجارب تاخد سنةمش بحكي عن ساعتين و تلاتة و
+
+229
+00:19:28,770 --> 00:19:34,410
+أربعة لأ بحكي عن سنة و أكتر كمان من سنة ليست عملية
+
+230
+00:19:34,410 --> 00:19:50,430
+سهلة في الوضع الطبيعي ابهيك
+
+231
+00:19:50,430 --> 00:19:54,930
+بنكون طبعا خلصنا هذا ال chapter اللي اسمه
+
+232
+00:19:58,800 --> 00:20:04,620
+استيريو كيميستري وبننتقل
+
+233
+00:20:04,620 --> 00:20:11,960
+مباشرة الى فصل اخر هذا الفصل الاخر بدنا ناخده نوعا
+
+234
+00:20:11,960 --> 00:20:19,910
+ما باختصار .. نوعا ما باختصار عنوانه الكلهيلايزو
+
+235
+00:20:19,910 --> 00:20:24,950
+طبعا ال الكلهليتز المجموعة هذه من المركبات لها
+
+236
+00:20:24,950 --> 00:20:30,870
+تفاعلين substitution and elimination تفاعل الإبدال
+
+237
+00:20:30,870 --> 00:20:37,980
+وتفاعل الحدث بالنسبة ل الكلاعرفنا إيش يعني الكل؟
+
+238
+00:20:37,980 --> 00:20:44,860
+مجموعة الكل مثل و إثل و بربل و كل شيء مأخوذ من ال
+
+239
+00:20:44,860 --> 00:20:50,260
+الكلس سواء له اسم و لا مالوش اسم و الهيليدز متصل
+
+240
+00:20:50,260 --> 00:20:57,300
+بهالوجين كلور بروم يود فلور أحيانا فال الكلهيليدز
+
+241
+00:20:57,300 --> 00:21:03,750
+ببساطة هم ال الكلس المتصلين بهالوجينيعني لو اجينا
+
+242
+00:21:03,750 --> 00:21:08,130
+و قولنا هذا المركب يا تورا و كتبنا هنا PR عبارة عن
+
+243
+00:21:08,130 --> 00:21:14,170
+إيش الكل هيلايد لأن هذا الجزء الكن و هذا الجزء
+
+244
+00:21:14,170 --> 00:21:18,250
+الهالوجين و عشان ذلك مرات بيسموها أي معنى الكل
+
+245
+00:21:18,250 --> 00:21:22,030
+هيلايد في جزء الكن و جزء الهالوجين عشان ذلك مرات
+
+246
+00:21:22,030 --> 00:21:28,870
+بيسموهم الهالوجينو الكنز الكل هيلايد او الهالوجينو
+
+247
+00:21:28,870 --> 00:21:32,490
+الكنز نفس الفكرة تماما
+
+248
+00:21:38,950 --> 00:21:43,570
+الان زي ما حكيت ال الكلهيلايتز بيسموهم مرات
+
+249
+00:21:43,570 --> 00:21:48,410
+الهالوجينوالكينز او هالوالكينز فسواء قرأنا العنوان
+
+250
+00:21:48,410 --> 00:21:53,170
+الكلهيلايتز او هالوجينوالكينز او هالوالكينز هو ال
+
+251
+00:21:53,170 --> 00:21:58,300
+cane حاملالهالوجين البساطة مش مشكلة كبيرة فال
+
+252
+00:21:58,300 --> 00:22:02,040
+الهالوجين محتوى الهالوجين اتوم و الهالوجين اتوم
+
+253
+00:22:02,040 --> 00:22:06,020
+معروفين بالنسبة لنا فلورين و كلورين و برومين و
+
+254
+00:22:06,020 --> 00:22:08,620
+ايودين متصلين ب الهالوجروم
+
+255
+00:22:11,830 --> 00:22:16,410
+الالكالهيلايتز ممكن ان نصنفهم احنا الى primary و
+
+256
+00:22:16,410 --> 00:22:19,890
+secondary و tertiary الكلهيلايتز هذا المصطلح
+
+257
+00:22:19,890 --> 00:22:23,770
+بيفيدنا اثناء ما بنشرح عن الموضوع ايش بنقصد احنا
+
+258
+00:22:23,770 --> 00:22:27,490
+بال primary و ال secondary و ال tertiary او باللغة
+
+259
+00:22:27,490 --> 00:22:32,170
+العربية اولي و ثانوي و ثالثي ال primary و ال
+
+260
+00:22:32,170 --> 00:22:35,790
+secondary و ال tertiary الكلهيلايتز باجي انا على
+
+261
+00:22:35,790 --> 00:22:39,430
+ذرة الكربون اللى حاملة ال halogen يعني هذا الكربون
+
+262
+00:22:39,430 --> 00:22:45,830
+اللى حاملة ال halogenمتصلة بكم كاربون؟ اذا متصلة
+
+263
+00:22:45,830 --> 00:22:50,610
+بكاربون واحدة بقول عنها primary لحظة ايه الكاربون
+
+264
+00:22:50,610 --> 00:22:54,950
+اللي حاملة الهالوجين متصلة بكم كاربون واحدة اذا
+
+265
+00:22:54,950 --> 00:22:58,170
+بقول عنها primary طبعا الناس الشاطرين بيصيروا
+
+266
+00:22:58,170 --> 00:23:02,530
+يفهموها يعني بشكل سهل بيقولوا لو الكاربون اللي
+
+267
+00:23:02,530 --> 00:23:08,540
+حاملة الهالوجين كانت CH2لاحظوا CH2 و ال PR هي تلات
+
+268
+00:23:08,540 --> 00:23:13,000
+روابط إذا كده يظل متصلة مع واحدة هذا ال primary
+
+269
+00:23:13,000 --> 00:23:19,140
+فاللي بيميز ال primary وجود ال CH2 هالوجينالان ال
+
+270
+00:23:19,140 --> 00:23:24,540
+secondary الكربون اللى حامله ال halogen هى هى هذه
+
+271
+00:23:24,540 --> 00:23:27,380
+الكربون اللى حامله ال halogen متصلة بكم كربون؟
+
+272
+00:23:27,380 --> 00:23:31,000
+تنتين تنتين بقول عنها ال secondary الان ايش بيكون
+
+273
+00:23:31,000 --> 00:23:36,600
+موجود فيها؟ CH يعني كأنه ال primary CH2 halogen ال
+
+274
+00:23:36,600 --> 00:23:43,960
+secondary CH halogen لو اجيت على ال tertiaryC
+
+275
+00:23:43,960 --> 00:23:49,220
+متصلة بالهالوجين طب و التلاتة روابط التانية متصلين
+
+276
+00:23:49,220 --> 00:23:54,600
+بالكاربون هاي C متصلة بالهالوجين و بعد هيك رابطة
+
+277
+00:23:54,600 --> 00:23:58,120
+تنتين تلاتة متصلة بالكاربون هذا النوع من ال
+
+278
+00:23:58,120 --> 00:24:02,340
+الكلهيلايتش شو بسمي انا tertiary alkyl halides
+
+279
+00:24:02,340 --> 00:24:06,040
+فإذا قلنا او رسمنا اي الكلهيلايت و قلنا عنه
+
+280
+00:24:06,040 --> 00:24:09,400
+primary او secondary او tertiary بفترض ان هذه
+
+281
+00:24:09,400 --> 00:24:17,540
+الشغلة تكون واضحةعشان نفهم الـ Alkyl Halides محور
+
+282
+00:24:17,540 --> 00:24:22,220
+الـ Alkyl Halides هو رابطة الـ Carbon-Halogen يعني
+
+283
+00:24:22,220 --> 00:24:27,180
+بين الـ Carbon والـ X الـ Halogen في عنده رابطة
+
+284
+00:24:28,310 --> 00:24:32,150
+الان بدي افهم هذه الرابطة جيدا لان التفاعلات
+
+285
+00:24:32,150 --> 00:24:37,330
+هيعتمد على هذه الرابطة ال carbon halogen bond جزء
+
+286
+00:24:37,330 --> 00:24:41,990
+من فهم هذا الموضوع ان اشوف فرق السالبية هنا هل
+
+287
+00:24:41,990 --> 00:24:47,310
+يترى هذه الرابطة polar ولا non polar عشان اشوف
+
+288
+00:24:47,310 --> 00:24:53,550
+الرابطة جيدا بدي اشوف ايش السالبية للكربون الكربون
+
+289
+00:24:53,550 --> 00:24:58,350
+سالبيته اتنين ونصال carbon ايش السالبية تبعته
+
+290
+00:24:58,350 --> 00:25:05,330
+اتنين و نص الان ال halogens كم واحد اه لاحظوا
+
+291
+00:25:05,330 --> 00:25:16,670
+floor سالبيته قداش اربعة و بروم تلاتة floor
+
+292
+00:25:16,670 --> 00:25:19,750
+تلاتة
+
+293
+00:25:19,750 --> 00:25:21,590
+بروم
+
+294
+00:25:23,000 --> 00:25:29,680
+2.8 و اليود 2.5 لاحظوا اليود و الكربون فيهم فرق
+
+295
+00:25:29,680 --> 00:25:34,620
+سالبية إذا الرابطة بشكل عام non polar مافيش فرق
+
+296
+00:25:34,620 --> 00:25:40,320
+سالبية الكربون 2.5 و اليود 2.5 لكن بعد ذلك مع
+
+297
+00:25:40,320 --> 00:25:45,140
+البروم و الكلور و الفلور في فرق سالبية لمصلحة
+
+298
+00:25:45,140 --> 00:25:50,080
+الهالوجين إذا بشكل عام مع هذول الذرات كيف بنتوقع
+
+299
+00:25:50,080 --> 00:25:57,150
+ال polarity للرابطة تكونإن الكربون تكون موجبة
+
+300
+00:25:57,150 --> 00:26:05,090
+والهالوجين سالبة واضح؟ أكبر فرق وين موجود؟ مع ال
+
+301
+00:26:05,090 --> 00:26:11,910
+floor أقل فرق العدم مع اليود الأن لاحظوا معي كل ما
+
+302
+00:26:11,910 --> 00:26:16,390
+كان الفرق كبير كل ما جربت الرابط تشبه الرابط
+
+303
+00:26:16,390 --> 00:26:20,890
+الأيونية بمعنى أخر بتصير أقوىو بناء على ذلك لو انا
+
+304
+00:26:20,890 --> 00:26:25,270
+بدى اشوف قوة هذه الروابط اللى هى مع ال flour و ال
+
+305
+00:26:25,270 --> 00:26:29,330
+brom و ال chlor و ال iod هلاحظ انه و اقارنها بقوة
+
+306
+00:26:29,330 --> 00:26:32,750
+رابطة ال carbon-H اللى هى تعتبر بلغة الكيميا رابطة
+
+307
+00:26:32,750 --> 00:26:38,930
+قوية و مش سائل تنقصت ال carbon-H 413 كيلوجول لكل
+
+308
+00:26:38,930 --> 00:26:42,910
+مول بدى عشان اكسر هذه الرابطة الان ال carbon-flour
+
+309
+00:26:42,910 --> 00:26:48,150
+اقوى منهاليش؟ لأن فرق ال polarity عالي صارت تشبه
+
+310
+00:26:48,150 --> 00:26:52,990
+رابطة ايونية قوية ال carboniclor 346 ال
+
+311
+00:26:52,990 --> 00:26:59,910
+carboniclor 290 ال carboniclor 228 أقوى واحدة فيهم
+
+312
+00:26:59,910 --> 00:27:06,670
+مين؟ مع ال fluor الآن جزء أساسي في بناء الكيميا
+
+313
+00:27:06,670 --> 00:27:09,850
+تبع ال alkyl halides ان انا بدي أكسر الرابطة هذه
+
+314
+00:27:09,850 --> 00:27:15,000
+اللي بين ال carbon و ال halogenيعني سواء في تفاعل
+
+315
+00:27:15,000 --> 00:27:20,020
+الإبدال أو الحذف، هذه الرابطة بدها تنكسر طيب ال
+
+316
+00:27:20,020 --> 00:27:23,480
+floor رابطته قوية؟ صعب، صعب، صعب، صعب، صعب، صعب،
+
+317
+00:27:23,480 --> 00:27:24,200
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+318
+00:27:24,200 --> 00:27:24,620
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+319
+00:27:24,620 --> 00:27:24,820
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+320
+00:27:24,820 --> 00:27:33,340
+صعب، صعب، صعب، صعب، صعب، صعب،
+
+321
+00:27:33,340 --> 00:27:41,060
+صعب، صعب، صعب،
+
+322
+00:27:41,060 --> 00:27:45,880
+صوبناء على ذلك عندما أعمل إبدال و أخد أمثلة على
+
+323
+00:27:45,880 --> 00:27:50,360
+الإبدال و أعمل حذف و في التفاعلين الإبدال و الحذف
+
+324
+00:27:50,360 --> 00:27:56,800
+تكسر فيه رابطة الأمثلة اللي هشوفها كلور بروم يود
+
+325
+00:27:56,800 --> 00:28:01,880
+مش هشوف أمثلة على ال floor لأن ال floor رابطة قوية
+
+326
+00:28:01,880 --> 00:28:06,380
+صعب كسرها وبناء على ذلك تفاعلات الإبدال و الحذف
+
+327
+00:28:06,380 --> 00:28:11,010
+مرتبطة بدول التلاتة ال floor برا الموضوعواضح
+
+328
+00:28:11,010 --> 00:28:17,150
+الفكرة؟ الآن
+
+329
+00:28:17,150 --> 00:28:22,890
+طالما احنا بنقول بدنا نكسر الرابط مع ال halogen
+
+330
+00:28:22,890 --> 00:28:28,230
+أني أضعف رابط فيهم اليود بناء على ذلك لو انا بعمل
+
+331
+00:28:28,230 --> 00:28:33,530
+تفاعل مع اليود بيكون سهل ولا صعب؟ سهل جداالبروم
+
+332
+00:28:33,530 --> 00:28:37,350
+بقعده في السهولة الكلور بقعده وعشان هيك لو انا بدى
+
+333
+00:28:37,350 --> 00:28:40,990
+اشوف ال rate of reaction لو كنت بفعل يود وبروم
+
+334
+00:28:40,990 --> 00:28:46,270
+وكلور مقارنة بعض و بالبعض أسرع تفاعل مع اليود أسرع
+
+335
+00:28:46,270 --> 00:28:51,580
+من البروم أسرع من الكلورلكلور والسبب قوة الرابطة
+
+336
+00:28:51,580 --> 00:28:56,100
+لأن هنا في رابطة ضعيفة بتنكسر بسهولة واضح الرابطة
+
+337
+00:28:56,100 --> 00:29:00,340
+مع اليود رابطة ضعيفة بتنكسر بسهولة يمكن هذا الكلام
+
+338
+00:29:00,340 --> 00:29:04,100
+حتى في الحياة العملية بتلاحظوا حتى في الحياة
+
+339
+00:29:04,100 --> 00:29:09,320
+العملية بتلاحظوا كثير من الأدوية مثلا موجود مكون
+
+340
+00:29:09,320 --> 00:29:15,660
+أساسي منها اليود هذه الأدوية لو اتعرضت لشوية حرارة
+
+341
+00:29:15,660 --> 00:29:20,980
+بسيطة أو لضوء الشمسبتنكسر الرابطة اللي معاليه طبعا
+
+342
+00:29:20,980 --> 00:29:24,240
+كنا انكسرت الرابطة إذا الدواء كله إيش صار فيه؟ خير
+
+343
+00:29:24,240 --> 00:29:28,680
+وعشان هيك هنلاحظ أن هذا النوع من الأدوية بيحطوه في
+
+344
+00:29:28,680 --> 00:29:33,800
+جزايز غامقة لونها بني وغالبا بيحفظوه بعيدا عن
+
+345
+00:29:33,800 --> 00:29:38,930
+الضوء و الحرارة و أحيانا في حرارة باردةيعني شوف
+
+346
+00:29:38,930 --> 00:29:43,690
+كيف لما مراتب تقرأ على شيء معين يحفظ بعيدا عن
+
+347
+00:29:43,690 --> 00:29:46,730
+الضوء و الحرارة ليش؟ بيكون هذا الشيء المعين فيه
+
+348
+00:29:46,730 --> 00:29:52,790
+روابط ضعيفة حتى حرارة الجو حتى على ضو الشمس ممكن
+
+349
+00:29:52,790 --> 00:29:58,410
+تتكسر فبنصير نحط مثلا جزاز بن يمنع أنه يدخل الضوء
+
+350
+00:29:58,410 --> 00:30:02,030
+بشكل كبير بنقبل حطه بعيد عن الضوء و عن الحرارة
+
+351
+00:30:02,030 --> 00:30:06,870
+ممكن يحتفظ فيهبالتلاجة على سبيل المثال كل هذا
+
+352
+00:30:06,870 --> 00:30:12,670
+نتيجة فهم قوة الروابط الكيميائية و دائما انتوا
+
+353
+00:30:12,670 --> 00:30:16,630
+يعني جزء منكوا في علوم الصحة و جزء في غيرها لحتى
+
+354
+00:30:16,630 --> 00:30:20,190
+تتعاملوا مع أدوى او اشياء اول ما بدكوا تمسكوا اي
+
+355
+00:30:20,190 --> 00:30:28,090
+عبو الدواء شغلتين الشيء الاول صحتكماقرأوا الكلام
+
+356
+00:30:28,090 --> 00:30:33,550
+اللي عليها، ضار، سام، يجوز أن نشمه، لا يجوز، كل
+
+357
+00:30:33,550 --> 00:30:38,050
+هذا الكلام مكتوب على العبوة ويله إشارات معينة،
+
+358
+00:30:38,050 --> 00:30:42,230
+بيحرق كوروسف مثلا زي أحماض إذا انكبت على الإيد
+
+359
+00:30:42,230 --> 00:30:46,200
+بتحرقها، إذا انكبت على الملابس بتحرقهامنفعش
+
+360
+00:30:46,200 --> 00:30:49,400
+الإنسان يتعامل مع أشياء و هو مش عارفها يكون
+
+361
+00:30:49,400 --> 00:30:55,240
+بيتعامل مع سم و بيسيبه ينكب على إيده و مابيغسلش و
+
+362
+00:30:55,240 --> 00:31:00,040
+مابياخدش احتياطات ولا بيلبس gloves ولا أي شيء و
+
+363
+00:31:00,040 --> 00:31:06,940
+شغلت تانية بيكون مكتوب عندكم كلمة storeاحفظه وانت
+
+364
+00:31:06,940 --> 00:31:12,160
+احفظه طبعا شغل اضافية بيكون عندكوا expire date انه
+
+365
+00:31:12,160 --> 00:31:16,120
+هذا بعد فترة معينة ما تفتحوه بيخرب بالذات كتير
+
+366
+00:31:16,120 --> 00:31:20,800
+مركبات بيكون مسكر عليها بشكل محكم لكن لما تفتحوها
+
+367
+00:31:20,800 --> 00:31:26,970
+تتفعل مع oxygen الهواءممكن تتفاعل مع الهوى نفسه أو
+
+368
+00:31:26,970 --> 00:31:31,370
+تمتص رطوبة من الهوى وبناء على ذلك تخرب فهتلاحظوا
+
+369
+00:31:31,370 --> 00:31:35,990
+بعض المراكبات مكتوب عليها لا يستعمل بعد أسبوع أو
+
+370
+00:31:35,990 --> 00:31:41,050
+أسبوعين من فتح العبوة كل إنسان بدي يتعامل بأدوية
+
+371
+00:31:41,050 --> 00:31:45,050
+أو pre agents بدي يكون منتبه لهذه الأمور وإلا
+
+372
+00:31:45,050 --> 00:31:47,470
+بيجعل بإيش؟ بالغلط
+
+373
+00:31:51,720 --> 00:31:57,640
+الان لو اجينا على التفاعلات تبعت ال alkyl halides
+
+374
+00:31:57,640 --> 00:32:04,320
+ممكن البعض يقول طب احنا ما أعطيناش التسمية مشعلة
+
+375
+00:32:04,320 --> 00:32:09,760
+جديدة مرت عليكم لما أخدنا ال alkenes يعني لو انا
+
+376
+00:32:09,760 --> 00:32:15,600
+جبتلكوا هذا المركب هذا
+
+377
+00:32:15,600 --> 00:32:22,830
+ال alkyl halide مين تسميه؟احد اتنين تلاتة اربعة
+
+378
+00:32:22,830 --> 00:32:30,340
+خمسة بنتين اثنان كلورو اثنان مثل بنتينأخدنا
+
+379
+00:32:30,340 --> 00:32:36,180
+التسمية ولا لأ؟ أخدنا التسمية طيب واحدة بتقول ماشي
+
+380
+00:32:36,180 --> 00:32:40,800
+التسمية أخدناها طيب و ال preparation التحضير هو
+
+381
+00:32:40,800 --> 00:32:45,220
+احنا عادة لما بندرس عائلة كيميائية اول اشي بنتعرف
+
+382
+00:32:45,220 --> 00:32:49,420
+على العائلة بعدين بناخد ال nomenclature التسمية
+
+383
+00:32:49,420 --> 00:32:54,500
+بعدين التحضير بعدين التفاعلات احنا عمال جاعدين
+
+384
+00:32:54,500 --> 00:33:00,060
+بنفض جزءالتسمية وشوفنا أننا أخدناها طب و جزء
+
+385
+00:33:00,060 --> 00:33:04,800
+التحضير أخدناها
+
+386
+00:33:04,800 --> 00:33:09,420
+من أكثر من طريقة أخدناها بأكثر من طريقة لما كنا
+
+387
+00:33:09,420 --> 00:33:13,220
+نيجي نقولكم مثلا ابرو بيل و اعملوله chlorination
+
+388
+00:33:13,220 --> 00:33:20,960
+شو كنتوا تطلعوا؟One Chloro, Two Chloro مش هذي
+
+389
+00:33:20,960 --> 00:33:25,680
+Alkyl Halides إذا ال Direct Halogenation طريقة من
+
+390
+00:33:25,680 --> 00:33:30,500
+طرق التحضير ولا لأ و حلينا عليها أمثلة تأكيد ..
+
+391
+00:33:30,500 --> 00:33:36,120
+تأكيد لما كنا .. هاي أول طريقة ال Halogenation طب
+
+392
+00:33:36,120 --> 00:33:42,440
+لو أعطيناكوا هذا المركب و قولنا لكم ضيفوا عليه HBR
+
+393
+00:33:46,050 --> 00:33:50,770
+هتقولولي مع Markovnikov ولا أنت Markovnikov؟ إذا
+
+394
+00:33:50,770 --> 00:33:55,510
+Markovnikov بيجي H و PR to Bromo وإذا أنت
+
+395
+00:33:55,510 --> 00:34:01,390
+Markovnikov H و PR و لا Bromo هذه المركبات مش ال
+
+396
+00:34:01,390 --> 00:34:06,230
+الهيليتز اللي نتجت الطريقة إذا أخدناها فإيش طروب
+
+397
+00:34:06,230 --> 00:34:12,210
+تحضير ال الهيليتز؟ نمرة واحد ال halogenation of
+
+398
+00:34:12,210 --> 00:34:20,960
+alkenesالـ Halogenation طب نمره اتنين ال addition
+
+399
+00:34:20,960 --> 00:34:29,660
+of HX to الكيين أو الكايين كمان لما كنا نضيف على
+
+400
+00:34:29,660 --> 00:34:37,360
+الكاين مرتين واضح؟ في طرق تالتة أخدناها في طريق
+
+401
+00:34:37,360 --> 00:34:42,920
+تالت لو هنا إجينا ضفنا على نفس هذا المركب PR2
+
+402
+00:34:46,320 --> 00:34:50,940
+أيش كان يعطيني؟ كان يعمل لي إضافة two PR atoms
+
+403
+00:34:50,940 --> 00:34:56,800
+بسين ولا ب Anti-addition؟ Anti-addition هيعمل لي
+
+404
+00:34:56,800 --> 00:35:03,020
+dihalo compound هذه طريقة الإبوكسايد رينج لو
+
+405
+00:35:03,020 --> 00:35:07,020
+فتحناها برضه بتصير طريقة إذا إحنا أخدنا الحقيقة
+
+406
+00:35:07,020 --> 00:35:14,730
+أكثر من طريقة لتحضيرالـ Halo Compounds في طريقة
+
+407
+00:35:14,730 --> 00:35:17,890
+إضافية
+
+408
+00:35:17,890 --> 00:35:23,610
+غير التلات طرق هدول اللي هم ال ال ال ال ال ال ال
+
+409
+00:35:23,610 --> 00:35:24,970
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+410
+00:35:24,970 --> 00:35:25,010
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+411
+00:35:25,010 --> 00:35:28,170
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+412
+00:35:28,170 --> 00:35:28,990
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+413
+00:35:28,990 --> 00:35:29,570
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+414
+00:35:29,570 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+415
+00:35:29,610 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+416
+00:35:29,610 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+417
+00:35:29,610 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+418
+00:35:29,610 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+419
+00:35:29,610 --> 00:35:33,550
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+420
+00:35:33,550 --> 00:35:33,550
+ال ال
+
+421
+00:35:39,410 --> 00:35:46,970
+بتفاعلها ما عدش X أخليها RX يعني تحويل الكحول إلى
+
+422
+00:35:46,970 --> 00:35:51,810
+الكلهلايت هذه الطريقة لها تفاصيل كتير لما ندرس
+
+423
+00:35:51,810 --> 00:35:55,630
+chapter الكحولات بندرس كتفاعل على الكحول يعني
+
+424
+00:35:55,630 --> 00:36:00,290
+بإمكاننا ندرسها الأن كطريقة للتحضير و بإمكاننا
+
+425
+00:36:00,290 --> 00:36:05,900
+ندرسها في chapter الكحولات كتفاعل على الكحولواضح؟
+
+426
+00:36:05,900 --> 00:36:10,640
+هذا كحول، هذا الكلهلايت، بالنسبة للكحول هي تفاعل،
+
+427
+00:36:10,640 --> 00:36:14,980
+بالنسبة لالكلهلايت هي طريقة تحضير، لما ندرس
+
+428
+00:36:14,980 --> 00:36:19,720
+الكحولات و تفاعلاتها، هيكون عندنا تفاعل أساسي
+
+429
+00:36:19,720 --> 00:36:27,560
+تحويلالكحول إلى ال alkyl halides بمجموعة من
+
+430
+00:36:27,560 --> 00:36:31,440
+التفاصيل بندرسها بوقته، هاي بتصير كمان طريقة
+
+431
+00:36:31,440 --> 00:36:39,390
+إضافية لتحضير ال alkyl halidesكام طريقة؟ اربعة مين
+
+432
+00:36:39,390 --> 00:36:44,790
+تقول اليوم باختصار اتفضلي ال direct halogenation
+
+433
+00:36:44,790 --> 00:36:48,330
+في وجود الضوء او الحرارة لل ال alkenes اضافة ال X2
+
+434
+00:36:48,330 --> 00:36:56,190
+لل ال alkenes او اضافة ال HX
+
+435
+00:36:56,190 --> 00:37:01,620
+لل ال alkenes او لل ال alkynesو بعدين من الكحولات
+
+436
+00:37:01,620 --> 00:37:05,900
+في وجود HX او reagents تانية بندرسها في chapter
+
+437
+00:37:05,900 --> 00:37:10,860
+الكحولات هيصيرنا ذاكرينكوا كم طريقة اربع طرق
+
+438
+00:37:10,860 --> 00:37:15,380
+لتحضير ال alkyl halides تلاتة أخدتهم و طريقة
+
+439
+00:37:15,380 --> 00:37:24,180
+بندرسها في chapter الكحولات الآن التفاعل الأساسي
+
+440
+00:37:24,180 --> 00:37:30,380
+لل alkyl halides هو تفاعلالإبدال التفاعل الأساسي
+
+441
+00:37:30,380 --> 00:37:34,860
+لـ alkalites هو تفاعل الإبدال لو أنا أتي أتطلع طيب
+
+442
+00:37:34,860 --> 00:37:38,920
+إيش اللي بده أبدله؟ وكيف بده يتم الإبدال اللي
+
+443
+00:37:38,920 --> 00:37:44,480
+عندي؟ اتطلعوا هاي عندي carbon حاملة نفترض PR وهنا
+
+444
+00:37:44,480 --> 00:37:49,400
+في تلت روابط، بلاش نركز عليهم شو هما الآن إيش
+
+445
+00:37:49,400 --> 00:37:55,520
+اتفقنا على الرابط اللي موجود هنا؟قول لعنها بولا
+
+446
+00:37:55,520 --> 00:38:02,180
+يعني هذه موجبة وهذه سالبة بناء على ذلك هلاحظ أن
+
+447
+00:38:02,180 --> 00:38:06,720
+التفاعل الأساسي عندنا لما بناجي المرة الجاية اللي
+
+448
+00:38:06,720 --> 00:38:10,500
+اتكلم أنه بيجي نيوكليوفايل لإن نيوكليوفايل حامل
+
+449
+00:38:10,500 --> 00:38:15,840
+إلكترونات وين بيهاجم؟ على الكاربون الموجب يعني هذا
+
+450
+00:38:15,840 --> 00:38:22,560
+سالب للنيوكليوفايل سالب بيجي إيش بيطلعك باله؟ سالب
+
+451
+00:38:23,370 --> 00:38:27,830
+السالب هاجم على الكربون الموجب، طرد سالب إجا سالب،
+
+452
+00:38:27,830 --> 00:38:33,550
+طرد سالب، إجا موجب، طرد موجب أخدنا في البنزين
+
+453
+00:38:33,550 --> 00:38:38,190
+الإبدال إيش كان؟ موجب مكان موجب، سميناها
+
+454
+00:38:38,190 --> 00:38:41,950
+Electrophilic Substitution الآن هنا بدو ييجي سالب
+
+455
+00:38:41,950 --> 00:38:47,030
+مكان سالب، يعني إيش اللي بدو يطرد؟ ال X مع
+
+456
+00:38:47,030 --> 00:38:52,340
+إلكتروناته، شو اللي بدو يهاجم؟لنيوكليوفايل و بناء
+
+457
+00:38:52,340 --> 00:38:56,880
+على ذلك بيصير المفروض فينا نتذكر ايش معنى
+
+458
+00:38:56,880 --> 00:39:01,040
+النيوكليوفايل اللي بدو يهاجم هنا و يحل محل ال X
+
+459
+00:39:01,040 --> 00:39:06,220
+ولذلك المرة القادمة هنبدأ من كلمة ايش الـ
+
+460
+00:39:06,220 --> 00:39:11,190
+Eucleophilic Substitution يعني نبدأ نتعرف علىللـ
+
+461
+00:39:11,190 --> 00:39:14,950
+nucleophile اللي بده يهاجم ويبدأ التفاعل لأن الـ
+
+462
+00:39:14,950 --> 00:39:18,790
+nucleophile هو السالب اللي بده يهاجم ويحل محل
+
+463
+00:39:18,790 --> 00:39:23,630
+الهالوجين السالبة يعمل عملية الإبدال شكرا
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4bf39b1db011da894261ebc4a8aa5e7acc88bb80
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs_postprocess.srt
@@ -0,0 +1,2140 @@
+1
+00:00:21,410 --> 00:00:26,010
+بسم الله الرحمن الرحيم بدأنا احنا في محاضرات ماضية
+
+2
+00:00:26,010 --> 00:00:31,390
+في تفاعلات ال alkanes ويمكن لاحظنا ان الأمر في هذه
+
+3
+00:00:31,390 --> 00:00:36,690
+المنطقة هو أمر سهل جدا مافيش فيه مشاكل الرابطة
+
+4
+00:00:36,690 --> 00:00:41,450
+الزوجية من خلال تفاعل الإضافة بتصير رابطة أحدية
+
+5
+00:00:42,020 --> 00:00:45,740
+الاشياء المتعلقة بهذا التفاعل اللى اتكلمنا عنها
+
+6
+00:00:45,740 --> 00:00:50,220
+كانت طبيعة ال الكين و طبيعة ال reagent هل ال الكين
+
+7
+00:00:50,220 --> 00:00:54,400
+symmetric هل ال reagent symmetric و هذا الكلام أدى
+
+8
+00:00:54,400 --> 00:00:58,140
+إلى انه مرات بيكون في عندنا اضافات حسب قاعدة
+
+9
+00:00:58,140 --> 00:01:01,760
+Markovnikov او عكس قاعدة Markovnikov حسب طبيعة
+
+10
+00:01:02,350 --> 00:01:05,850
+التفاعل اللى بنعمله اخر شغل انتهينا عنده في
+
+11
+00:01:05,850 --> 00:01:11,030
+المحاضرة الماضية انه احنا ايضا ممكن نضيف oxygen
+
+12
+00:01:11,030 --> 00:01:16,050
+على ال double bond من خلال تفاعل ال alkenes مع ال
+
+13
+00:01:16,050 --> 00:01:20,030
+bare acids بيعطونا ال epoxides اللى هى الحلقات
+
+14
+00:01:20,030 --> 00:01:25,510
+الثلاثية اتعلمنا تسميتها بطريقتين سواء ان نسميها
+
+15
+00:01:25,510 --> 00:01:30,300
+من خلال ان نقولالكين اكسايد نذكر اسم الالكين
+
+16
+00:01:30,300 --> 00:01:34,720
+الأصلي اللى نتجت منه او من خلال اننا نعتبر ال
+
+17
+00:01:34,720 --> 00:01:37,360
+parent ring يعني الحلقة الأساسية اللى كلها
+
+18
+00:01:37,360 --> 00:01:43,720
+هيدروجين اسمها oxirane و الرقم من عند ال oxygen و
+
+19
+00:01:43,720 --> 00:01:51,200
+نذكر أسماء ال substituents اللى موجودةأيضا ركزنا
+
+20
+00:01:51,200 --> 00:01:55,660
+على نقطة أن هذه الحلقة الثلاثية هي حلقة مضغوطة is
+
+21
+00:01:55,660 --> 00:02:00,560
+a strained ring ليش؟ لأن الزوايا فيها ضغطت إلى
+
+22
+00:02:00,560 --> 00:02:04,720
+الستين الوضع المريح لزاوية ال carbon carbon carbon
+
+23
+00:02:04,720 --> 00:02:10,020
+او ما شابه مية وتسعة و نص ولذلك أسهل تفاعل فيها
+
+24
+00:02:10,020 --> 00:02:14,440
+اللي هو تفاعل ال ring opening فاحنا صح بنكون
+
+25
+00:02:14,440 --> 00:02:20,350
+الحلقةلكن الحلقة strain فلما تتجه تعمل ring
+
+26
+00:02:20,350 --> 00:02:26,250
+-opening فكرة ال ring-opening كانت مبنية على انه
+
+27
+00:02:26,250 --> 00:02:31,670
+اذا اتذكرنا احنا ان الاكسجين electronegative اكثر
+
+28
+00:02:31,670 --> 00:02:35,830
+من الكربون يعني الاكسجين partially negative ال two
+
+29
+00:02:35,830 --> 00:02:42,210
+carbons هيكونوابارشالة positive فانا لو جبت اي شيء
+
+30
+00:02:42,210 --> 00:02:46,250
+بده يتفاعل مع الموجب والاصل يكون سالم سمينا
+
+31
+00:02:46,250 --> 00:02:51,230
+نيوكليوفايل هاجم هنا النتيجة انه هيكسر هذه الرابطة
+
+32
+00:02:51,230 --> 00:02:55,970
+مش هيصير عنده خمس روابط فلما ييجي اي نيوكليوفايل
+
+33
+00:02:57,150 --> 00:03:02,150
+هاجم على هذا الكرمون هتنكسر الرابط أزواج
+
+34
+00:03:02,150 --> 00:03:08,050
+الألكترونات هيكون مع الـ O O minus بياخد H غالبا
+
+35
+00:03:08,050 --> 00:03:12,890
+الـ H هذه بتكون مع الـ nucleophile فهيصف ايش O H
+
+36
+00:03:12,890 --> 00:03:17,230
+او احنا بنعمل catalysis للتفاعل بـ H plus يعني
+
+37
+00:03:17,230 --> 00:03:22,690
+مثلا الميه فيها جزء ايه لو تشوفوا محصلة التفاعل O
+
+38
+00:03:22,690 --> 00:03:31,120
+H اللي هي تمثللنكليوفاي و في اتش فهذا لنكليوفاي لو
+
+39
+00:03:31,120 --> 00:03:38,130
+اتفعل من هنا وصف في الآخر انه حط OHL شو ضال عندكH
+
+40
+00:03:38,130 --> 00:03:42,870
+هتيجي وين؟ على هذه الـ O أو لو أنا كنت عامل acid
+
+41
+00:03:42,870 --> 00:03:47,530
+catalysis الـ H تبعت ال acid في الأساس هي اللي
+
+42
+00:03:47,530 --> 00:03:52,410
+بتيجي و بيطلع بدلها H plus لكن كمحصلة كمعادلة
+
+43
+00:03:52,410 --> 00:03:57,370
+موزونة كمعادلة موزونة لو بتتطلع على هذا المركب لو
+
+44
+00:03:57,370 --> 00:04:02,580
+بتتطلع على هذا المركباللي أنا بادى فيه وهذا المركب
+
+45
+00:04:02,580 --> 00:04:07,140
+اللى طلع عندى هتلاحظوا هى ال OH اللى اجت من الميه
+
+46
+00:04:07,140 --> 00:04:12,700
+وهىالـ H هيصل في ميّه إذا المعادلة بهذا الشكل
+
+47
+00:04:12,700 --> 00:04:17,460
+موصولة ولا لأ تماما كاربون كاربون أكسوجين وإيجي
+
+48
+00:04:17,460 --> 00:04:23,800
+عنده من الميّه الـ OH والـ H في كل الأحوال تفاعل
+
+49
+00:04:23,800 --> 00:04:28,500
+ال ring opening سهل جدا أن نطبقه بدنا نقول أن هذه
+
+50
+00:04:28,500 --> 00:04:35,720
+الحلقة بدأ تصير CCOH بما تحملهيعني لو كانت هنا
+
+51
+00:04:35,720 --> 00:04:40,080
+بتحمل H2 وهنا H2، بيظلوا زي ما هما، H و مثل وهنا
+
+52
+00:04:40,080 --> 00:04:43,820
+H2، بيظلوا زي ما هما، إيش ما بتحمل هنا، هدولة مش
+
+53
+00:04:43,820 --> 00:04:47,760
+موقع تفاعل، ما بتغيروش، أيًا كانوا، إيش ما
+
+54
+00:04:47,760 --> 00:04:51,200
+بيكونوا، هدول المجموعات بتغيروش، اللي بيصير عنده C
+
+55
+00:04:53,120 --> 00:04:58,840
+OH وهنا بدو ييجي عنده لنيوكليوفايل طبعا إذا كان
+
+56
+00:04:58,840 --> 00:05:05,100
+المتفاعل الماء لنيوكليوفايل OH طب إذا المتفاعل HX
+
+57
+00:05:05,100 --> 00:05:13,240
+لنيوكليوفايل X إذا المتفاعل RO- هيكون RO وبتيجي H
+
+58
+00:05:13,240 --> 00:05:18,020
+من هنا بهذا الشكل إذا الشيء المشترك هنا الشيء
+
+59
+00:05:18,020 --> 00:05:22,580
+المشترك هنا أنه هتشوفوا هذه القطعة
+
+60
+00:05:25,740 --> 00:05:37,660
+CCOH CCOH CCOH CCOH CCOH
+
+61
+00:05:37,660 --> 00:05:44,900
+CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH
+
+62
+00:05:44,900 --> 00:05:49,920
+CCOHأي مجموعات كانت موجودة عليهم اصلا يعني لو كنت
+
+63
+00:05:49,920 --> 00:05:53,760
+بدي انا في ال parent compound يعني هذه CH2 CH2
+
+64
+00:05:53,760 --> 00:06:01,540
+هتكون النتيجة OH CH2 CH2 OH لو هدولة C مثل 2 مثل 2
+
+65
+00:06:01,540 --> 00:06:09,100
+هيكون OH C مثل 2 C مثل 2 و هكذا واضح؟ بهذا الشكل
+
+66
+00:06:09,100 --> 00:06:15,230
+بتم التفاعد ولذلك مرات كتير لما بنشوف عندنالما
+
+67
+00:06:15,230 --> 00:06:20,510
+بنشوف إنه في تفاعلات موجود CH2 CH2 OH ممكن نفكر إن
+
+68
+00:06:20,510 --> 00:06:27,150
+هدولة إجوا من حلقة إيش Oxirane حلقة Oxirane CH2
+
+69
+00:06:27,150 --> 00:06:31,190
+CH2 OH اتفاعلت مع نيوكليوفايل بيضطر نيوكليوفايل
+
+70
+00:06:31,190 --> 00:06:39,600
+CH2 CH2واضح؟ طبعا في حالات ممكن المجموعات اللى
+
+71
+00:06:39,600 --> 00:06:43,480
+موجودة على ال carbon في هدولة النقطين تكون مختلفة
+
+72
+00:06:43,480 --> 00:06:49,780
+يعني ممكن مثلا تلاحظوا ان هذه تكونسي أتش تو وهنا
+
+73
+00:06:49,780 --> 00:06:53,700
+سي أتش و سي أتش ثري و بتكون تيجي تفعله الماء
+
+74
+00:06:53,700 --> 00:06:57,560
+لاحظوا هتصيروا متحيرين هل يا ترى النيوكليوفايل
+
+75
+00:06:57,560 --> 00:07:01,540
+هتخلوه يتفعل على هذا الكربون و لا على هذا الكربون
+
+76
+00:07:01,540 --> 00:07:04,600
+من ناحية المبدأ هذا موجبة و هذا موجبة دائما
+
+77
+00:07:04,600 --> 00:07:08,560
+النيوكليوفايل هتفعل على الكربون اللي بتحمل الكربون
+
+78
+00:07:08,560 --> 00:07:14,230
+أكثرتعرفوا تصنيفات ال carbon primary و secondary و
+
+79
+00:07:14,230 --> 00:07:18,090
+tertiary حسب ما بيحمل carbons فالتفاعل على ال
+
+80
+00:07:18,090 --> 00:07:21,930
+carbon اللي بتحمي ال carbons أكثر بيكون مفضل يعني
+
+81
+00:07:21,930 --> 00:07:25,090
+في هذه الحالة لو كنا بنفعل ميه هل يا ترى ال O
+
+82
+00:07:25,090 --> 00:07:28,550
+هتيجي تهاجم على هذا ال carbon ولا هذا ال carbon و
+
+83
+00:07:28,550 --> 00:07:35,650
+هنا هيصير أن ال O أتش هذا لو مر علينامثال بهذا
+
+84
+00:07:35,650 --> 00:07:41,150
+الشكل طبعا في كل الأحوال لأن هذه حلقة لأن هذه حلقة
+
+85
+00:07:41,150 --> 00:07:46,430
+هنلاحظ ان النيوكليوفايل هيجي من جهة و ال OH هتكون
+
+86
+00:07:46,430 --> 00:07:51,390
+من الجهة المعاكزة واضح ان هذا بيأثر على النواتج او
+
+87
+00:07:51,390 --> 00:07:56,510
+لا هذا موضوع ثاني لكن الإضافة هنا بتكون sin ولا
+
+88
+00:07:56,510 --> 00:08:02,550
+anti additionبتكون Anti-Addition الإضافة هنا بتكون
+
+89
+00:08:02,550 --> 00:08:05,750
+Anti-Addition يعني الـ Nucleophile بيجي من الجهة
+
+90
+00:08:05,750 --> 00:08:10,270
+المعاكسة لجهة تكوّن الـ OH ملاحظين منهم Anti
+
+91
+00:08:10,270 --> 00:08:13,690
+-Addition؟
+
+92
+00:08:13,690 --> 00:08:19,970
+الآن لاحظوا لو فكرنا مثلا أنه بدنا نضيف مجمعتين OH
+
+93
+00:08:21,270 --> 00:08:26,050
+من جهة واحدة يعني هذه الطريقة انه حولنا الالكين ل
+
+94
+00:08:26,050 --> 00:08:32,730
+ابوكسايد وفتحنا الحلقة اعطتنا مجموعتين OHمن جهتين
+
+95
+00:08:32,730 --> 00:08:37,370
+متعاكستين طب لو فكرنا انه بدنا نضيف المجموعتين من
+
+96
+00:08:37,370 --> 00:08:42,710
+جهة واحدة في عندنا تفاعل تاني ممكن نعمله مباشرة
+
+97
+00:08:42,710 --> 00:08:48,130
+على ال الكين و بضيف مجموعتين OH من جهة واحدة هذا
+
+98
+00:08:48,130 --> 00:08:54,170
+التفاعل ان نفعل ال الكين سواء مع مركب ال Osmium O4
+
+99
+00:08:54,170 --> 00:08:59,340
+في وجود هذه الأشياءكتاليست او مع مركب كيامان O4
+
+100
+00:08:59,340 --> 00:09:03,540
+بيرمانجانات البوتاسيوم سواء قلنا أزوميام الأزوميام
+
+101
+00:09:03,540 --> 00:09:08,320
+عنصر معدن ثقيل تقريبا هو أثقل العناصر يعني كثافته
+
+102
+00:09:08,320 --> 00:09:14,300
+أعلى حتى من الدهب واشي فوق العشرين جرام لكل سنتمتر
+
+103
+00:09:14,300 --> 00:09:21,180
+مكعبواضح؟ سواء قلنا Osmium O4 او KMnO4 انا بحكي عن
+
+104
+00:09:21,180 --> 00:09:27,520
+معدل مثل ال مثل Osmium او مانجانيز وهذا متصل بكم
+
+105
+00:09:27,520 --> 00:09:32,990
+مجموعة Oهيبقى أربعة، الآن لما بديجي يتفاعل مع
+
+106
+00:09:32,990 --> 00:09:36,310
+double bond لما بديجي يتفاعل مع double bond هي
+
+107
+00:09:36,310 --> 00:09:40,650
+double bond أكيد هيتفاعل من خلال أكسجنتين موجودات
+
+108
+00:09:40,650 --> 00:09:45,630
+على جهة واحدة و بعد هيك تنكسر هذه الرابطة مع
+
+109
+00:09:45,630 --> 00:09:51,530
+المعدنتم التفاعل بهذا الشكل هذي هتاخد من مجمل
+
+110
+00:09:51,530 --> 00:09:58,130
+التفاعل HOOH أكيد أجه من جهة واحدة فالتفاعل هذا
+
+111
+00:09:58,130 --> 00:10:02,150
+بتتم من جهة واحدة لأنه بإمكانكوا ببساطة تتخيلوا
+
+112
+00:10:02,150 --> 00:10:08,050
+الكيامان O4 زي هيك هاي .. هاي الأربع ذرات أكسوجين
+
+113
+00:10:08,050 --> 00:10:12,680
+اللي موجودين فيه الآن بدو يهاجم ع double bondبيقدر
+
+114
+00:10:12,680 --> 00:10:17,060
+يهاجم من جهتين؟ لأ بالتاكيد هيهاجم من هنا و من هنا
+
+115
+00:10:17,060 --> 00:10:22,500
+حذرتين أكسجين من جهة واحدة فإضافة مجموعات ال OH
+
+116
+00:10:22,500 --> 00:10:28,220
+باستعمال ال Osmium O4 أو الكيامان O4 في وجود طبعا
+
+117
+00:10:28,220 --> 00:10:32,000
+ما basic medium كل الأشياء اللي أمامكم هو عبارة عن
+
+118
+00:10:32,000 --> 00:10:37,040
+sin ولا anti addition؟ sin addition ابهيك بنذكر
+
+119
+00:10:37,040 --> 00:10:40,580
+إيش الأشياء اللي بتصيروا ماخدينها sin addition؟
+
+120
+00:10:42,290 --> 00:10:49,270
+إضافة الـ hydrogen و إضافة مجموعات ال OH باستعمال
+
+121
+00:10:49,270 --> 00:10:54,710
+ال Osmium O4 أو الكيامان O4 لما أخدنا إضافة ال PR2
+
+122
+00:10:54,710 --> 00:11:00,150
+أخدناها Anti addition لما أخدنا إضافة ال PR2
+
+123
+00:11:00,150 --> 00:11:06,290
+أخدناها Anti addition مش Sin addition واضح؟ ولذلك
+
+124
+00:11:06,290 --> 00:11:12,720
+لو مثلا جيبنا لكم مركب زي هذاخلنا ناخد مثال
+
+125
+00:11:12,720 --> 00:11:17,540
+Cyclopentane
+
+126
+00:11:17,540 --> 00:11:26,060
+طبعا ك Cyclopentane شو عليها؟H وH وسألناكم سؤال
+
+127
+00:11:26,060 --> 00:11:31,280
+قلنا لكم كيف ممكن تحضروا من هذا Cyclobentane
+
+128
+00:11:31,280 --> 00:11:37,540
+Cyclobentadiol يعني Cyclobentane شيلنا منه ال
+
+129
+00:11:37,540 --> 00:11:40,900
+double bond و حاطينا مجموعتين OH يعني بدل ال
+
+130
+00:11:40,900 --> 00:11:44,780
+double bond مجموعتين OH مرة يكونوا ال cis و مرة
+
+131
+00:11:44,780 --> 00:11:49,600
+يكونوا ال trans كأنه بيصير السؤال انه كيف بدي احضر
+
+132
+00:11:49,600 --> 00:11:59,490
+منههذا المُركّب اللي فيه مجموعتين الـ OH على جهة
+
+133
+00:11:59,490 --> 00:12:06,270
+واحدة و بدي أحضر منه أيضا المُركّب اللي فيه
+
+134
+00:12:06,270 --> 00:12:11,930
+مجموعتين الـ OH على جهتين متعاكستين اللي هم الـ
+
+135
+00:12:11,930 --> 00:12:13,330
+CIS والـ Trans
+
+136
+00:12:18,820 --> 00:12:21,820
+واضح؟ how can you prepare this is and
+
+137
+00:12:21,820 --> 00:12:27,060
+transcyclobentane diol starting from cyclobentene
+
+138
+00:12:27,060 --> 00:12:32,960
+الان في الحالة الأولى الجواب مباشر في الحالة
+
+139
+00:12:32,960 --> 00:12:37,040
+الأولى الجواب مباشر بدى استعمل اما طريقة ال
+
+140
+00:12:37,040 --> 00:12:41,760
+ozomium o4 او ال camon o4 نفس الشيء خلنا نقول مثلا
+
+141
+00:12:41,760 --> 00:12:49,610
+camon o4 فيباسيك ميديام في وجود الماء ألاحظوا
+
+142
+00:12:49,610 --> 00:12:54,210
+انتبهوا جيدا لو سمحتوا الكيامان اوفور عشان تعمل
+
+143
+00:12:54,210 --> 00:12:57,910
+هذا التفاعل و تضيف من جهتين بدا تكون في basic
+
+144
+00:12:57,910 --> 00:13:02,550
+medium في وجود OH- هذه بديكوا تركزوا عليها لسبب
+
+145
+00:13:02,550 --> 00:13:06,590
+بسيط انه في تفاعلات تانية سواء درسناها او
+
+146
+00:13:06,590 --> 00:13:10,850
+مادرسناهاش تفاعل الكيامان اوفور في acidic medium
+
+147
+00:13:10,850 --> 00:13:16,780
+بيعطيني أشياء تانيةواضح فركزوا ان هذا التفاعل بتم
+
+148
+00:13:16,780 --> 00:13:22,320
+في basic و medium الان لو قولنا المركب التاني كيف
+
+149
+00:13:22,320 --> 00:13:30,080
+بدنا نحضره على خطوتين اذا
+
+150
+00:13:30,080 --> 00:13:34,740
+انا في الاول بدي اجي اقول bare acid مثلا فينيل
+
+151
+00:13:34,740 --> 00:13:39,580
+COOOH و
+
+152
+00:13:39,580 --> 00:13:44,720
+استعمل و يعطيني ال ابوكسايدو بعدين بوجود ال ..
+
+153
+00:13:44,720 --> 00:13:49,480
+بساط حمضي مع .. هاي ال Evoxide واضح؟ أخدنا هذا
+
+154
+00:13:49,480 --> 00:13:54,440
+التفاعل بيصير Cyclopentene
+
+155
+00:13:54,440 --> 00:14:01,080
+Oxide و بعد هيك لما أجي أفعله مع ال H2O H plus
+
+156
+00:14:01,080 --> 00:14:05,300
+بيعمل ring opening O H بتيجي من هنا O Hواحدة من
+
+157
+00:14:05,300 --> 00:14:08,600
+التحت وواحدة من الفوق إذا هذا التفاعل بتتم على
+
+158
+00:14:08,600 --> 00:14:12,860
+خطوة ولا على خطوة إيه؟ على خطوة إيه؟ هذا التفاعل
+
+159
+00:14:12,860 --> 00:14:24,220
+على خطوة واحدة واضح
+
+160
+00:14:24,220 --> 00:14:24,960
+المثال؟
+
+161
+00:14:48,060 --> 00:14:52,220
+من التفاعلات اللى بدنا ندرسها ايضا لل Alkanes
+
+162
+00:14:52,220 --> 00:14:59,040
+تفاعل جديد الان مش تفاعل اضافة تفاعل bond cleavage
+
+163
+00:14:59,040 --> 00:15:03,480
+بمعنى بيكسر ال double bond نصين يعني اتطلعوا معاه
+
+164
+00:15:03,480 --> 00:15:07,000
+هذي ال double bond التفاعل اللى بدنا ندرسه الان
+
+165
+00:15:07,000 --> 00:15:11,800
+بدوش يضيف حوله من double ل single كل ما درسناه كان
+
+166
+00:15:11,800 --> 00:15:16,180
+addition reactions لحد الان كل ما درسناه كان
+
+167
+00:15:16,180 --> 00:15:19,970
+addition double bondتصير single bond الآن بدنا
+
+168
+00:15:19,970 --> 00:15:23,590
+ناخد نوع تاني من تفاعلات ال double bond اللي هو
+
+169
+00:15:23,590 --> 00:15:27,030
+cleavage reaction ان اجعل double bond و اكسرها
+
+170
+00:15:27,030 --> 00:15:32,950
+نصين هذا التفاعل بنسميه ozonolysis of alkenes وزي
+
+171
+00:15:32,950 --> 00:15:38,750
+ما قلت هو تفاعل ايشCleavage تفاعل كسر بيكسر ال
+
+172
+00:15:38,750 --> 00:15:43,010
+double bond نصين بتم هذا التفاعل من خلال التفاعل
+
+173
+00:15:43,010 --> 00:15:48,210
+مع ال ozone بتعرفوا ال ozone الأكسجل في الطبيعة O2
+
+174
+00:15:48,210 --> 00:15:52,810
+وإله ألوتروب بنسميها أو صورة تقاصلية تانية يعني
+
+175
+00:15:52,810 --> 00:15:58,070
+صورة فيزيائية تانية اسمها ايش ozone زي ما الكربون
+
+176
+00:15:58,070 --> 00:16:02,960
+في الطبيعة بنوجد على شكلGraphite و Diamond و
+
+177
+00:16:02,960 --> 00:16:09,080
+Carbon-60 او زي ما الفوسفور مثلا في الطبيعة فوسفور
+
+178
+00:16:09,080 --> 00:16:13,220
+أبيض فوسفور أحمد هذه صورة فيزيائية للمادة لنفس
+
+179
+00:16:13,220 --> 00:16:17,840
+المادة الآن ال Oxygen في الطبيعة ممكن ينوجد على
+
+180
+00:16:17,840 --> 00:16:22,860
+شكل Oxygen عادي O2 و ممكن ينوجد على شكل Ozone اللي
+
+181
+00:16:22,860 --> 00:16:27,540
+عادة موجود في الاطسفير في طبقات الجو العليا و
+
+182
+00:16:27,540 --> 00:16:33,380
+بعدينبتعرف مشكلة الأوزون لو فعلنا هذا المُركّب مع
+
+183
+00:16:33,380 --> 00:16:39,220
+الأوزون بداية وبعدين مع زنك في وجود حامض بيكوّنلنا
+
+184
+00:16:39,220 --> 00:16:42,440
+مُركّب وسيط مش كثير محتم أننا نحفظه أوزونويت
+
+185
+00:16:42,440 --> 00:16:48,260
+بنسميه هذه الأوزون التلاتة وبعد هيك بتكسر الرابطة
+
+186
+00:16:48,260 --> 00:16:53,710
+اللي هي بين الكاربون والكاربون هذهDouble bond
+
+187
+00:16:53,710 --> 00:16:57,470
+بتصير هنا C double bond O وهذه بتصير C double bond
+
+188
+00:16:57,470 --> 00:17:04,250
+O يعني الكسر من وين هيتملما نجي نفذ الناتج مش كل
+
+189
+00:17:04,250 --> 00:17:07,350
+مرة بدنا نكون عارفين ال intermediate ناخدها لمرة
+
+190
+00:17:07,350 --> 00:17:11,650
+واحدة لكن أنا بدي أنفذ أكتب الناتج بدي أجي أتخيل
+
+191
+00:17:11,650 --> 00:17:16,290
+أنه معي مساحة كسرت الرابطة من هنا هذه هتصير C
+
+192
+00:17:16,290 --> 00:17:22,690
+double bond O وهذه هتصير C double bond O هيعطيني
+
+193
+00:17:22,690 --> 00:17:25,570
+تنتين C double bond O لاحظوا الناتج هنا هذه
+
+194
+00:17:25,570 --> 00:17:32,150
+البنزينة وحملة CH وإيش صارتC double bond O وهنا
+
+195
+00:17:32,150 --> 00:17:38,270
+عندكم CH2 إيش صارت كمان C double bond O ولو مش
+
+196
+00:17:38,270 --> 00:17:45,930
+واضحين الروابط فببساطة تفاعل مع الأوزون و بعده
+
+197
+00:17:45,930 --> 00:17:51,830
+زنكمية هو حقيقة بيحول لل carbon carbon double bond
+
+198
+00:17:51,830 --> 00:17:57,800
+لتنتين C double bond O يعني بديكوا تتخيلوابهذا
+
+199
+00:17:57,800 --> 00:18:02,640
+الشكل كان عندكم carbons بغض النظر إيش موجود عندي
+
+200
+00:18:02,640 --> 00:18:08,460
+هنا ممكن اتش اتش اتش مثل فلل إيش مكان يكون بتخلوه
+
+201
+00:18:08,460 --> 00:18:12,400
+زي ما هو مش موضوعكم افترضوا قلنالكوا بدنا ناتج ال
+
+202
+00:18:12,400 --> 00:18:16,860
+ozonolesis لهذا التفاعل إيش أسهل طريقة عشان تنفذوا
+
+203
+00:18:16,860 --> 00:18:24,160
+الجواب تتخيلوا أنه كسرنا هذه الرابطة واضح؟ و هنا
+
+204
+00:18:24,160 --> 00:18:28,590
+حطينا O و هناأو نتيجة
+
+205
+00:18:31,420 --> 00:18:37,520
+هك انا بعمل ناتج ال ozoneolysis الان انه اكون عندى
+
+206
+00:18:37,520 --> 00:18:41,560
+اى مجموعة هنا مابفرقش عندى لكن بكل الاحوال لو
+
+207
+00:18:41,560 --> 00:18:45,920
+افترضت عندى carbon و carbon هيطلع عندى كيتون لو
+
+208
+00:18:45,920 --> 00:18:49,580
+افترضت عندى carbon و hydrogen او تنتين هيدروجين
+
+209
+00:18:49,580 --> 00:18:54,000
+هيطلع عندى الديهيد اذا هذا تفاعل ال ozoneolysis في
+
+210
+00:18:54,000 --> 00:18:59,340
+النهاية لو بدأ اقولكوا شو احتمالات نواتجهالديهيد
+
+211
+00:18:59,340 --> 00:19:04,280
+او كيتون او
+
+212
+00:19:04,280 --> 00:19:10,200
+كيتون
+
+213
+00:19:10,200 --> 00:19:12,040
+او كيتون او كيتون او كيتون او كيتون او كيتون او
+
+214
+00:19:12,040 --> 00:19:12,140
+او كيتون او كيتون او كيتون او كيتون او كيتون او
+
+215
+00:19:12,140 --> 00:19:12,600
+كيتون او كيتون او كيتون او كيتون او كيتون او كيتون
+
+216
+00:19:12,600 --> 00:19:13,180
+او كيتون او كيتون او كيتون او كيتون او كيتون او
+
+217
+00:19:13,180 --> 00:19:13,220
+كيتون او كيتون او كيتون او كيتون او كيتون او كيتون
+
+218
+00:19:13,220 --> 00:19:15,260
+او كيتون او كيتون او كيتون او كيتون او كيتون او
+
+219
+00:19:15,260 --> 00:19:21,580
+كيتون او كيتون او كيتون او كيتونأيضا الديهايد
+
+220
+00:19:21,580 --> 00:19:25,860
+الديهايد يعرف ب H واحدة و أبسط الديهايد في الدنيا
+
+221
+00:19:25,860 --> 00:19:29,660
+ال form الديهايد اللي فيه H و H تنتيل فوجود H
+
+222
+00:19:29,660 --> 00:19:34,320
+واحدة بيخل المركب إيش اسمه الديهايد الآن التانية
+
+223
+00:19:34,320 --> 00:19:38,120
+تكون H بيكون أبسط الديهايد التانية تكون مثل إثل
+
+224
+00:19:38,120 --> 00:19:43,820
+فنل بروبل أي مجموعة بيظلواالديهيد ايضا فنتج ال
+
+225
+00:19:43,820 --> 00:19:49,580
+اوزونوليسيس بيعطي الديهيد او كيتون باستخدام
+
+226
+00:19:49,580 --> 00:19:55,380
+الاشتراكات على الدبل بوند اعتمادا على الاشتراكات
+
+227
+00:19:55,380 --> 00:19:58,600
+على الدبل بوند الان هي هذا على طول لما واحدة بتطلع
+
+228
+00:19:58,600 --> 00:20:03,500
+هتلاحظ ايش اعطانا هنا الديهيد اكيد لان الدبل بوند
+
+229
+00:20:03,500 --> 00:20:08,910
+عليها اتش وهنا نور على نور الدبل بوند عليهاتنتين H
+
+230
+00:20:08,910 --> 00:20:13,670
+إذا أيضا بالتأكيد الديهايد وإن كان أبسط الديهايد
+
+231
+00:20:13,670 --> 00:20:17,890
+لكن لو أي طرف عليه تنتين كاربون من عند هذا الطرف
+
+232
+00:20:17,890 --> 00:20:25,070
+هيعطيه كيتون هاي أمثلة عندنا تطلع عليها في كل
+
+233
+00:20:25,070 --> 00:20:32,450
+الأحوال من أين ستكسر الرابط من
+
+234
+00:20:32,450 --> 00:20:38,340
+النص الرابط بنكسرها من النصبدون ما نتطلع على
+
+235
+00:20:38,340 --> 00:20:41,860
+الجواب لو إجينا سألنا هذا الناتج بيعطي إيش
+
+236
+00:20:41,860 --> 00:20:46,840
+الديهايد الكربون هذي حملة H at least و هذا
+
+237
+00:20:46,840 --> 00:20:53,920
+الديهايد و الديهايد هنا T ليش المخفي شو هو؟ بديش
+
+238
+00:20:53,920 --> 00:21:01,300
+أبقى أتعب معكم كل ما لم يكتب فهو H طيب إذا من هذه
+
+239
+00:21:01,300 --> 00:21:07,430
+الجهة شو بيعطيه؟ و من هذه الجهةكيتون هذه كل رأس
+
+240
+00:21:07,430 --> 00:21:12,850
+يعتبر carbon الان هذه بنكسرها ايضا من النص بتصير
+
+241
+00:21:12,850 --> 00:21:17,590
+هنا C double bond O وهنا C double bond O اكيد هذه
+
+242
+00:21:17,590 --> 00:21:23,170
+كيتون وهنا فيه H مخفية كيتون
+
+243
+00:21:23,170 --> 00:21:27,250
+والدايت لاحظوا هذا ماعطاش جزي ايه لكن كسر الرابط
+
+244
+00:21:27,250 --> 00:21:34,720
+بنفس المنطق هذا نفس الشي تماما لاحظوا هنا فيهأتش و
+
+245
+00:21:34,720 --> 00:21:38,160
+هنا فيه اتش خلو ادي سيضه بالبندقه و ادي سيضه
+
+246
+00:21:38,160 --> 00:21:42,200
+بالبندقه بس هو بعد هيك بدل ما الجزيئ يكتبوا عامل
+
+247
+00:21:42,200 --> 00:21:51,680
+زي هيك فرضه اعطاه نفس حرام يعني هذا بمش هو احنا
+
+248
+00:21:51,680 --> 00:21:54,940
+ليش بنعلمكوا ان الجزيئات بتتغير زي ما البني ادم
+
+249
+00:21:54,940 --> 00:21:58,340
+بياخد ميت صورة يعني هذا لو كان بدوا يكتبوا
+
+250
+00:21:58,340 --> 00:22:00,420
+بالطريقة اللي انتوا فاهمينها
+
+251
+00:22:03,590 --> 00:22:09,470
+عمل هيك و هيك زي هيك مبين سهل و اين كسرت الرابطة
+
+252
+00:22:09,470 --> 00:22:16,030
+الان بعد هيك انفرض زي ما الجنيل بيكون متكور في بطن
+
+253
+00:22:16,030 --> 00:22:25,570
+امه هذا هو هداك هذا المركب هو هذا المركب اليوم
+
+254
+00:22:25,570 --> 00:22:30,250
+انا باعطي ناتج تفاعل طالما الديهايد او كيتون موطعه
+
+255
+00:22:30,250 --> 00:22:35,750
+شبتر 9عشان أسميهم، مش اليوم، واضح؟ في طريقة
+
+256
+00:22:35,750 --> 00:22:44,970
+لتسميتهم ما سُكِت عنه يُصبر عليه، واضح؟
+
+257
+00:22:44,970 --> 00:22:51,710
+الآن
+
+258
+00:22:51,710 --> 00:22:58,890
+من أمثلة ومن تفاعلاتالالكينز أيضا تفاعل مهم جدا في
+
+259
+00:22:58,890 --> 00:23:02,110
+الحياة التطبيقية العملية وفي الحياة الصناعية
+
+260
+00:23:02,110 --> 00:23:06,190
+بنسميه احنا free radical polymerization of
+
+261
+00:23:06,190 --> 00:23:10,290
+ethylene ايش احنا اللي بنقصده في polymerization
+
+262
+00:23:10,290 --> 00:23:16,030
+بتعرف بيكون عندنا جزء واحد من المادة هذا الجزء
+
+263
+00:23:16,030 --> 00:23:23,180
+الواحد من المادة ممكن نسميه احنا monomerمونومر جزء
+
+264
+00:23:23,180 --> 00:23:29,500
+واحد الان لو عملت اتنين بيصير دايمر اتنين دايمر
+
+265
+00:23:29,500 --> 00:23:37,760
+تلاتة اترايمر اربعة تترامر تلت اربع مية تلت اربع
+
+266
+00:23:37,760 --> 00:23:45,410
+تلاف وقتها بوليمرطب مش من أولها polymer لأ إذا
+
+267
+00:23:45,410 --> 00:23:50,130
+إحنا لو كنا بنقول الجزء الواحد إيش بنقوله؟ monomer
+
+268
+00:23:50,130 --> 00:23:58,750
+اتنين دايمر تلاتة ترايمر أربعة تترامر
+
+269
+00:24:02,660 --> 00:24:08,120
+بوليمر يعني البوليمر بيكون تلت اربعميت جزيء خمسمية
+
+270
+00:24:08,120 --> 00:24:11,960
+احيانا تلت تلاف احيانا حسب طبيعة المواد خمسين الف
+
+271
+00:24:11,960 --> 00:24:15,680
+ميت الف بيكونوا كلهم مار بعض هذا اللي بنسميه
+
+272
+00:24:15,680 --> 00:24:20,420
+بوليمر مش تلاتة واربعة واضح فالواحد والاتنين
+
+273
+00:24:20,420 --> 00:24:24,770
+والتلاتة دول علهم أسماء لكن لما بيكون كبيربصير
+
+274
+00:24:24,770 --> 00:24:30,390
+عنده الـ Polymer الان إذا تخيلتوا ان هذا جزء
+
+275
+00:24:30,390 --> 00:24:36,310
+إيثالين إيثالين والإيثالين غاز و إجينا على هذا
+
+276
+00:24:36,310 --> 00:24:45,400
+الإيثالين و حطناه معبروكسايد تحت ضغط مرتفع جدا جدا
+
+277
+00:24:45,400 --> 00:24:51,160
+جدا الف أتمسفير عشان تخافوا من كلمة الف أتمسفير
+
+278
+00:24:51,160 --> 00:24:56,300
+يعني تقدروا تتخيلوا شوها الضغط الكبير بس تذكروا أن
+
+279
+00:24:56,300 --> 00:25:00,400
+طنجرة الضغط اللي بتطبخوا فيها و اللي بتكون تصفروا
+
+280
+00:25:00,400 --> 00:25:06,620
+و بتخوف الضغط فيها اتنين أتمسفير فقط
+
+281
+00:25:07,930 --> 00:25:12,510
+الضغط فيها دي طنجرة الضغط اتنين atmosphere فانا
+
+282
+00:25:12,510 --> 00:25:16,650
+لما بحكي عن الف atmosphere بيمكنكم تخيلوا الضغط
+
+283
+00:25:16,650 --> 00:25:21,410
+طبعا اكيد هذا التفاعل مابنعملش بجزاز ولا بحديد
+
+284
+00:25:21,410 --> 00:25:25,050
+بسيط بيكون عندكوا اوعية stainless steel الوعاء
+
+285
+00:25:25,050 --> 00:25:28,450
+يمكن عرضه اتنين تلاتة سانت stainless steel ومكابس
+
+286
+00:25:28,450 --> 00:25:34,820
+هيدروليكية هذا شغل صناعةمش شغل مختبر، الآن بيجيبوا
+
+287
+00:25:34,820 --> 00:25:42,310
+الغاز، بنحطه غاز، بنحط عليه ال ..البروكسايتز هذه
+
+288
+00:25:42,310 --> 00:25:46,030
+عند ألف أتمسفير وبنسخن عند مئة درجة مئوية بنضغط
+
+289
+00:25:46,030 --> 00:25:50,210
+الغاز بندخل جزيئات الغاز، لاحظوا غاز، بندخل
+
+290
+00:25:50,210 --> 00:25:55,970
+جزيئاته في بعضها طالما كبر المركب، هيتحول لإيش؟
+
+291
+00:25:55,970 --> 00:26:00,110
+لصلب، مش بزيادة ال molecular weight كنا نتحول من
+
+292
+00:26:00,110 --> 00:26:03,930
+غاز لسائل لصلب، هيتحول ل polymer، هذا ال polymer
+
+293
+00:26:03,930 --> 00:26:08,470
+هو plasticهو نوع من ال plastic اللي احنا بنستعمله
+
+294
+00:26:08,470 --> 00:26:14,410
+بنسميه polyethylene فال ethylene بكل هذه الشروط
+
+295
+00:26:14,410 --> 00:26:18,450
+بيصير CH2 CH2 to the N لحظة لغية ال double bond
+
+296
+00:26:18,450 --> 00:26:23,570
+خلتها single bond لغية ال double bond و خلتها
+
+297
+00:26:23,570 --> 00:26:30,530
+single bond في هذه الحالة صارالإيثالين بولي
+
+298
+00:26:30,530 --> 00:26:34,570
+إيثالين طبعا في ميكانيزم للتفاعل مش كتير بتفرج
+
+299
+00:26:34,570 --> 00:26:38,910
+عنده البولي إيثالين هو البلاستيك الأبيض إذا دخلتوا
+
+300
+00:26:38,910 --> 00:26:42,050
+على المختبرات بتلاحظوا في عندكم جلانات بنعب فيها
+
+301
+00:26:42,050 --> 00:26:46,330
+ميا ديستيلد ووتر wash bottles أشياء كل هذه عبارة
+
+302
+00:26:46,330 --> 00:26:49,490
+عن بولي إيثالين الأوعية اللى بنحط فيها هيدروكسيد
+
+303
+00:26:49,490 --> 00:26:53,050
+الصوديوم بتشوفوا ال .. ال bottle اللى بنكون معبينه
+
+304
+00:26:53,050 --> 00:27:00,100
+محلولا كل هذه عبارة عن إيش بولي إيثالينالان بنفس
+
+305
+00:27:00,100 --> 00:27:03,820
+المنطق، شوفوا كيف العلم بتطور، يعني أول ما بدأنا
+
+306
+00:27:03,820 --> 00:27:07,280
+عملنا Polymer عملنا إيش؟ الـ Ethylene و عملنا له
+
+307
+00:27:07,280 --> 00:27:12,200
+Polymerization إلى Polyethylene طيب هم قالوا لازم
+
+308
+00:27:12,200 --> 00:27:16,400
+هدول الأربعة يكونوا Hydrogen و Hydrogen يعني CH2
+
+309
+00:27:16,400 --> 00:27:22,400
+CH2 لو يا ترى بدلنا واحدة منهمبكلور هنا هنا شيلنا
+
+310
+00:27:22,400 --> 00:27:28,860
+واحدة بالغلط صار CH CH2CL وكان double bond وعملنا
+
+311
+00:27:28,860 --> 00:27:33,800
+منه ال polymer هتصير single bond طب هذا المركب
+
+312
+00:27:33,800 --> 00:27:42,680
+الأصلي CH2 double bond CHCL أخدنا اسمه vinyl
+
+313
+00:27:42,680 --> 00:27:47,480
+chloride هذه مجموعة ال vinylVinyl chloride اللي
+
+314
+00:27:47,480 --> 00:27:51,760
+قال لو اعملت منه بوليمار بنفس المنطق تبع الاثيلين
+
+315
+00:27:51,760 --> 00:27:58,640
+الغط بابل بوند و اكتبه to the end طالما هذا Vinyl
+
+316
+00:27:58,640 --> 00:28:03,960
+chloride Vinyl chloride شو هيصير البوليمار تبعه
+
+317
+00:28:03,960 --> 00:28:08,320
+بولي و Vinyl chloride اتخيلوا لو بدنا نختصر اسم
+
+318
+00:28:08,320 --> 00:28:14,300
+البوليمار تبعه BVC
+
+319
+00:28:15,850 --> 00:28:23,430
+مين ما بعرفش ال PVC؟ كل شناتكم PVC، كل بلاستيك
+
+320
+00:28:23,430 --> 00:28:27,310
+المحووتكم PVC، كل المواسير اللي بتشوفوها اللي
+
+321
+00:28:27,310 --> 00:28:30,810
+بنستعملها لتمديدات الصرف الصحي، المواسير
+
+322
+00:28:30,810 --> 00:28:35,750
+البردجانية والسكنية، لو جربت عليها، مكتوب عليها
+
+323
+00:28:35,750 --> 00:28:36,230
+PVC
+
+324
+00:28:39,480 --> 00:28:43,960
+Polyvinyl chloride اللي بيعملوها أرضيات أحيانا
+
+325
+00:28:43,960 --> 00:28:48,820
+بيغطوا فيها البلاط ممكن تشوفوها أحيانا في صالونات
+
+326
+00:28:48,820 --> 00:28:53,200
+لحلاجة في المستشفى أرضية بلاستيك و بيلزجوها فوق كل
+
+327
+00:28:53,200 --> 00:28:59,900
+بلاط الغرفة هذه PVC فال PVC موجود وبشكل كبير في
+
+328
+00:28:59,900 --> 00:29:05,640
+الحياة التطبيقيةزي وزي البولي إيثالين الآن لاحظوا
+
+329
+00:29:05,640 --> 00:29:09,540
+إذا صارت القصة إن أغير واحدة من الهيدروجين وحطيت
+
+330
+00:29:09,540 --> 00:29:14,960
+كلور لما كانت هيدروجين بولي إيثالين لما كانت كلور
+
+331
+00:29:14,960 --> 00:29:21,020
+PVC أو بولي فينيلي كلورايت طب لو خلناها بنزينة
+
+332
+00:29:22,360 --> 00:29:28,720
+المُركّب الأصلي سيكون CH2 double bond CH حملة
+
+333
+00:29:28,720 --> 00:29:34,920
+بنزينة أو phenyl اسمه styrene اسمه styrene لما
+
+334
+00:29:34,920 --> 00:29:41,130
+أعمل منه polymerإيش بده يصير؟ Polystyrene لما أعمل
+
+335
+00:29:41,130 --> 00:29:45,690
+منه polymer هيصير polystyrene إذا التفاعل مش بس
+
+336
+00:29:45,690 --> 00:29:50,390
+خاص بال إيثيلين لأ اتطور على مواد تانية و كل هذه
+
+337
+00:29:50,390 --> 00:29:54,310
+عبارة عن أنواع من ال plastic موجودة في السوق و
+
+338
+00:29:54,310 --> 00:29:59,950
+بتلباع و بتعامل فيها الناس و أفرجناكوا تطبيقيا وين
+
+339
+00:29:59,950 --> 00:30:02,430
+بتستعمل واضحة هذه الفكرة؟
+
+340
+00:30:05,100 --> 00:30:09,380
+إذا هاي كمان تفاعل تاني لل ال keys يعني كأنها
+
+341
+00:30:09,380 --> 00:30:14,560
+بنصير كتفاعلات أساسية أخدنا الإضافة أخدنا ال
+
+342
+00:30:14,560 --> 00:30:18,340
+cleavage اللي هو ال ozoneolysis و أخدنا ال
+
+343
+00:30:18,340 --> 00:30:24,690
+polymerization أنه بيعمل polymer كبيرطبعا الله
+
+344
+00:30:24,690 --> 00:30:29,510
+يعطيكوا العافية بالنسباله ال Alkenes طب لو انتقلنا
+
+345
+00:30:29,510 --> 00:30:35,130
+لل Alkynes هتلاحظوا أنه بشكل أساسي تفاعلات شبيهة
+
+346
+00:30:35,130 --> 00:30:41,710
+الأساس فيها الإضافة ولكن لاحظوا معي لما أبدأ أحكي
+
+347
+00:30:41,710 --> 00:30:47,590
+عن ال Alkynes ال Alkynes تلت روابط carbon ال
+
+348
+00:30:47,590 --> 00:30:52,230
+triple bond carbon إذا لو بده يبدأ يضيف إيش
+
+349
+00:30:52,230 --> 00:30:56,740
+هيتحول؟لـ carbon double bond carbon وكمان خطوة
+
+350
+00:30:56,740 --> 00:31:02,560
+carbon single bond carbon إذا الإضافة هنا يمكن أن
+
+351
+00:31:02,560 --> 00:31:07,820
+تتم على مراحل يعني ال triple bond تصير double bond
+
+352
+00:31:07,820 --> 00:31:12,020
+تصير single bond مرات حسب شروط التفاعل وهذا اللي
+
+353
+00:31:12,020 --> 00:31:15,820
+بتكون تنتبهوله ممكن نخل التفاعل يجف لهنا بنص
+
+354
+00:31:15,820 --> 00:31:19,700
+الطريق يعني ال triple تصير double و يجف التفاعل
+
+355
+00:31:19,700 --> 00:31:26,830
+مرات بيستمرمرات ما بنقدرش نفصل المركب اللي بالوسط
+
+356
+00:31:26,830 --> 00:31:31,150
+يعني مجرد ما نحط عليه المادة التانية بيصير double
+
+357
+00:31:31,150 --> 00:31:36,450
+bond و بسرعة كبيرة بيظلوا محول لإيش ل single bond
+
+358
+00:31:36,450 --> 00:31:40,070
+بعمل إضافة تانية طبعا هنا كام إضافة بيصير لو قلت
+
+359
+00:31:40,070 --> 00:31:46,750
+من triple ل single bond إضافتين إضافتين يعني لو
+
+360
+00:31:46,750 --> 00:31:53,720
+قعد بضيف HCl مش لغاية double bond شو حطيت؟ Hطب
+
+361
+00:31:53,720 --> 00:31:56,880
+هدولة كيف بدي أضيفهم؟ حسب قاعدة Markov Nikov ولا
+
+362
+00:31:56,880 --> 00:32:00,720
+ضد؟ إذا كانوا مع ال H Plus حسب قاعدة Markov Nikov
+
+363
+00:32:00,720 --> 00:32:06,340
+يعني اتخيلتوا هذه H وهذه CH3 وين هتيجي ال H؟ على
+
+364
+00:32:06,340 --> 00:32:13,940
+الحاملة ال H أكتر وين هتيجي التانية؟ واضح؟ أه بعد
+
+365
+00:32:13,940 --> 00:32:18,780
+هيك لو بدي أضيف كمان مرة سرادة ال K أخدنا كيف بضيف
+
+366
+00:32:18,780 --> 00:32:24,780
+ال K على هذا؟ هتيجي ال H هنا؟و ال CL هنا وجدت كأنه
+
+367
+00:32:24,780 --> 00:32:30,020
+ضفت التنتين هيدروجين على نفس الكربون وهي
+
+368
+00:32:30,020 --> 00:32:36,120
+الهيدروجين الأصلية والتنتين CL على نفس الكربون وهي
+
+369
+00:32:36,120 --> 00:32:42,660
+CH3 خلّينا الطول الأصلية إذا التفاعل هنا تم على
+
+370
+00:32:42,660 --> 00:32:48,600
+مرحلة ولا مرحلتين؟ ع مرحلتين كل مرحلة منهم تمت حسب
+
+371
+00:32:48,600 --> 00:32:54,750
+قاعدة Markov-Nikov لما أضيف HCL في وجودالـ H plus
+
+372
+00:32:54,750 --> 00:33:00,150
+واضح؟ كل مرحلة منهم بتتم حسب قاعدة ماركو بيه
+
+373
+00:33:00,150 --> 00:33:05,190
+خلّينا نشوف هذا الكلام بالتفصيل بعض الإضافات بعض
+
+374
+00:33:05,190 --> 00:33:09,850
+تفاؤلات الإضافة للالكينز لاحظوا هاي أول مثال
+
+375
+00:33:09,850 --> 00:33:18,490
+addition of HX to alkynes هاي عندي كاربون بتحمل H
+
+376
+00:33:18,490 --> 00:33:25,510
+وكاربون بتحمل إيش H وضفت ال HClضعفين كيف هيكون
+
+377
+00:33:25,510 --> 00:33:30,630
+الناتج الأخير انه هضيف مرتين ال H هنا و هنا و
+
+378
+00:33:30,630 --> 00:33:33,590
+مرتين ال CL هنا و هنا هذه الناتج الأخيرة بس
+
+379
+00:33:33,590 --> 00:33:39,030
+بالتأكيد اول ما بيبدأ اضيف الإضافة الأولى إجت هنا
+
+380
+00:33:39,030 --> 00:33:44,270
+H و إجت هنا CL و الإضافة التانية إجت هنا كمان H و
+
+381
+00:33:44,270 --> 00:33:52,640
+هنا كمان CL واضح فمرتين حسب قاعدةماركوف نيكوف
+
+382
+00:33:52,640 --> 00:33:56,380
+اديشن الان
+
+383
+00:33:56,380 --> 00:34:04,360
+لو كنت بدى اضيف لبروم لبروم بضيف Anti addition
+
+384
+00:34:04,360 --> 00:34:11,540
+المرة الأولى هين اضفت PR و PR عكس بعضه اعطانى
+
+385
+00:34:11,540 --> 00:34:18,660
+الالكيل كمان مرة يعني كأنه هى ال PR 2 الأول وهىالـ
+
+386
+00:34:18,660 --> 00:34:23,020
+PR2 التالي كمان مرة حديث من هنا و من هنا صار عندى
+
+387
+00:34:23,020 --> 00:34:27,420
+أربع ذرات إبروم فلاحظوا لو أنا كنت كاتب زيكوا و
+
+388
+00:34:27,420 --> 00:34:34,380
+كاتبلكوا 2PR2 شو ناتج النهاية اللى بدى أكتبه ال
+
+389
+00:34:34,380 --> 00:34:39,700
+كان أو ال كان ال كان ال كان بالإنجليزي ال كان
+
+390
+00:34:39,700 --> 00:34:45,890
+بالعربي ال كان بالإنجليزي ماختلفناهاش كتيرالان من
+
+391
+00:34:45,890 --> 00:34:52,230
+التفاعلات المهمة ايضا تفاعل اضافة الميه بس اضافة
+
+392
+00:34:52,230 --> 00:35:02,070
+الميه شوية في فكرة جديدة لو انا اجيت وضفت الميهH2O
+
+393
+00:35:02,070 --> 00:35:06,210
+في وجود H بلس يعني كأني بقول H3O plus و عادة
+
+394
+00:35:06,210 --> 00:35:14,230
+بنستعمل catalyst الذئبق ايون ذئبق HG2 plus فلما
+
+395
+00:35:14,230 --> 00:35:19,610
+بنعمل هذا الكلام بتضيف الميه حسب قاعدة Markovnikov
+
+396
+00:35:19,610 --> 00:35:24,210
+بمعنى هنا بدأ تيجي ال H وهنا بدأ تيجي ال OH هاي
+
+397
+00:35:24,210 --> 00:35:29,360
+الميه اللي ضفناهاهذه إضافة حسب قاعدة ماركوف نيكوف
+
+398
+00:35:29,360 --> 00:35:33,960
+و لا لأ الآن لاحظوا لو اتطلعت على المركب اللي
+
+399
+00:35:33,960 --> 00:35:39,880
+اتكون عندى هذا مركب يحتوي على مجموعتين وظيفيتين
+
+400
+00:35:39,880 --> 00:35:44,040
+المجموعة الوظيفة الوظيفية الأولى ال ال keen
+
+401
+00:35:45,140 --> 00:35:51,700
+والتانية ال alcohol all فهذا فيه in و فيه all
+
+402
+00:35:51,700 --> 00:35:55,920
+شايفينهم هذه ال double bond مش بتاخد نهاية in و
+
+403
+00:35:55,920 --> 00:36:02,620
+هذه all فهذا المركب بنسميه in all لأنه متكون من
+
+404
+00:36:02,620 --> 00:36:08,420
+هدول الشغلتين in all ال OH متصلة مباشرة جنب ال
+
+405
+00:36:08,420 --> 00:36:13,950
+double bond هذه المركباتللأسف الشديد انه في الوضع
+
+406
+00:36:13,950 --> 00:36:18,530
+الطبيعي في الاليفاتيك كومباونز they are unstable
+
+407
+00:36:18,530 --> 00:36:25,690
+مركبات غير ثابتة بتعمل تحول بتتحول هذه المركبات شو
+
+408
+00:36:25,690 --> 00:36:29,390
+التحول اللي بتعمله بتخلي ال double bond هذي تيجي
+
+409
+00:36:29,390 --> 00:36:33,030
+هنا تصير هذي C double bond O و ال H تنتقل هنا
+
+410
+00:36:33,030 --> 00:36:38,650
+لاحظوا تغيرين اللي بيصير فيها انتقال إلكترونات و
+
+411
+00:36:38,650 --> 00:36:46,940
+انتقالزرات لما نعمل هذا الكلام هذه ال C شو صارت؟ C
+
+412
+00:36:46,940 --> 00:36:54,740
+double bond O و هذه ال CH2 شو صارت؟ CH3 إذا إيش
+
+413
+00:36:54,740 --> 00:37:00,160
+انتقل عنده؟ فقط إلكترونات ولا إلكترونات و ذرات؟
+
+414
+00:37:00,160 --> 00:37:04,040
+إلكترونات و ذرات و الذرة تحديدا ذرة الهيدروجين هذه
+
+415
+00:37:04,040 --> 00:37:09,070
+العمليةاللي بتتم فيها انتقال إلكترونات و ذرات
+
+416
+00:37:09,070 --> 00:37:13,930
+بتختلف عن عملية ال resonance اللي كانت فقط انتقال
+
+417
+00:37:13,930 --> 00:37:20,310
+إلكترونات متذاكرين ال resonance؟ ال resonance لما
+
+418
+00:37:20,310 --> 00:37:26,150
+اتكلمنا عنه و أعطيناه أي سهم ال double headed
+
+419
+00:37:26,150 --> 00:37:29,930
+straight arrow كان ال resonance movement
+
+420
+00:37:33,520 --> 00:37:39,820
+movement of electrons only طب لو صارت ال movement
+
+421
+00:37:39,820 --> 00:37:47,940
+electrons زائد H هذه العملية بسميها Tautomerism
+
+422
+00:37:47,940 --> 00:37:54,620
+تختلف عن ال resonance بسميها Tautomerismالتوتو
+
+423
+00:37:54,620 --> 00:38:00,440
+ميريزم ليست فقط حركة إلكترونات حركة إلكترونات و
+
+424
+00:38:00,440 --> 00:38:04,040
+ذرات و الذرة تحديدا أو غالبا اللي هي ذرة ال إيش
+
+425
+00:38:04,040 --> 00:38:07,960
+الهيدروجين بيصير عندي توتو ميريزم الآن البعض هيقول
+
+426
+00:38:07,960 --> 00:38:13,660
+لي شو سهم التوتو ميريزم بنقول سهم التوتو ميريزم
+
+427
+00:38:13,660 --> 00:38:19,500
+سهم التوتو ميريزم هو سهم الإتزان بهذا الشكلانسى
+
+428
+00:38:19,500 --> 00:38:23,560
+السهم المرسوم هذا هو الشكل السليم سهم التوتوميرزم
+
+429
+00:38:23,560 --> 00:38:28,540
+هو سهم الاتزام اذا احنا بنقدر نقول الان لو كنا
+
+430
+00:38:28,540 --> 00:38:33,320
+بنسألكوا صح و غلط توتوميرزم is an equilibrium
+
+431
+00:38:33,320 --> 00:38:37,720
+reaction صح طالما equilibrium reaction في ال
+
+432
+00:38:37,720 --> 00:38:43,980
+equilibrium reaction ايش بينوجد الشغلتين بنسب
+
+433
+00:38:43,980 --> 00:38:51,040
+معينة الان هذا الشكل اللى اتكون كيتونهذا E0 عشان
+
+434
+00:38:51,040 --> 00:38:56,400
+هيك هذا التوتمريزم يسمونه كيتو E0 التوتمريزم
+
+435
+00:38:56,400 --> 00:39:00,660
+التنقل بين التنين لكن مين اللي ينجد بنسبة أكبر
+
+436
+00:39:00,660 --> 00:39:06,440
+الكيتو يعني لو افترضنا ان هذا كان 99.9% هذا بيكون
+
+437
+00:39:06,440 --> 00:39:13,050
+بس بنسبة 1.10%يعني في هذا التوتوميريزم ال keto
+
+438
+00:39:13,050 --> 00:39:17,090
+-enol توتوميريزم ال predominant عارفين كلمة
+
+439
+00:39:17,090 --> 00:39:23,690
+predominant؟ ال predominant
+
+440
+00:39:23,690 --> 00:39:27,610
+مين فيها؟ بيكون ال ketone ولا ال enol؟ ال ketone
+
+441
+00:39:27,610 --> 00:39:31,330
+هو اللي موجود بنسبة كبيرة و ال enol بيكون بنسبة
+
+442
+00:39:31,330 --> 00:39:35,930
+قليلة طبعا هذا في الaliphatic compoundsلما نيجي
+
+443
+00:39:35,930 --> 00:39:42,610
+نتعلم في ال aromatic compounds هتلاحظوا العكس في
+
+444
+00:39:42,610 --> 00:39:49,570
+ال aromatic اللي بينوجد بنسبة أكبر ال enol وعشان
+
+445
+00:39:49,570 --> 00:39:53,670
+هيك كل كلانة بتقدروا تتذكروا و تشوفوا كيف أصل
+
+446
+00:39:53,670 --> 00:39:59,190
+الإسم لو اطلعتوا على هذا المركب مين تسمينا إياه؟
+
+447
+00:39:59,190 --> 00:40:09,580
+Phenolفينول أنا بدي أسميه زي هيك في إين أول تطلعوا
+
+448
+00:40:09,580 --> 00:40:15,020
+معاه الفي لأنه عندي بنزينة الفنل الفنل البنزينة و
+
+449
+00:40:15,020 --> 00:40:20,880
+إين هي الإين و all هي
+
+450
+00:40:20,880 --> 00:40:25,980
+ال all هذا الشكل الثابت منه و بنقدر نعطيكوا
+
+451
+00:40:25,980 --> 00:40:29,240
+homework ان جولكوا ارسمونا ال ketone تبعه
+
+452
+00:40:42,070 --> 00:40:47,610
+ما هو الشكل الثابت في الاروماتيك كومباوتز الموجودة
+
+453
+00:40:47,610 --> 00:40:52,520
+بالنسبة أعلى؟الـ Enol في الالفاتيك كومباونز اللي
+
+454
+00:40:52,520 --> 00:40:57,200
+موجود بنسبة أعلى الـ Ketone وهذه التوتوماريزم زي
+
+455
+00:40:57,200 --> 00:41:01,320
+ما اتفقنا هي عبارة عن عملية equilibrium فالسهم
+
+456
+00:41:01,320 --> 00:41:08,350
+اللي بيستعمللهاأي سهم؟ الـ straight arrow او two
+
+457
+00:41:08,350 --> 00:41:12,270
+straight arrows with half heads اللي هو السهمين
+
+458
+00:41:12,270 --> 00:41:16,070
+اللي موجودين كل واحد بنصف رأس زي ما انتوا شايفينه
+
+459
+00:41:16,070 --> 00:41:20,610
+هنا واللي اتفقنا ان هذا يستعمل الاتزان وعملية
+
+460
+00:41:20,610 --> 00:41:25,830
+التوتوماريزم هي حقيقة عملية اتزان عملية
+
+461
+00:41:25,830 --> 00:41:29,490
+التوتوماريزم هي حقيقة عملية اتزان
+
+462
+00:41:34,870 --> 00:41:39,810
+التفاعلات أيضا لو كنت أنا بضيف الميه عكس قاعدة
+
+463
+00:41:39,810 --> 00:41:45,070
+Markov Nikov باستعمال ال boron لاحظوا هنا في عندكم
+
+464
+00:41:45,070 --> 00:41:50,310
+H هذا نفس المثال السابق بس في اللحظة الأولى اللي
+
+465
+00:41:50,310 --> 00:41:54,510
+حطيت فيها H و OH طالما بضيف باستعمال ال boron هل
+
+466
+00:41:54,510 --> 00:41:59,110
+هضيف حسب قاعدة Markov Nikov ولا عكسها عكسها بناء
+
+467
+00:41:59,110 --> 00:42:04,860
+على ذلك حطيت ال H على اللي حامله H أقلو ال O H على
+
+468
+00:42:04,860 --> 00:42:08,900
+اللي حامله H هذا إضافة عكس Markovnikov مرة تانية
+
+469
+00:42:08,900 --> 00:42:18,180
+صار عندى in all هذا ال in all بحوله إلى ال keto
+
+470
+00:42:18,180 --> 00:42:23,560
+form بمعنى هذا ال double bond تيجي هنا و ال H
+
+471
+00:42:23,560 --> 00:42:29,500
+تنتقل مكان ما إجت ال double bondكل هذا الكلام
+
+472
+00:42:29,500 --> 00:42:33,320
+طبقوا بإيدكم عشان تتدربوا عليه، إذا نفس
+
+473
+00:42:33,320 --> 00:42:37,380
+التوتوميرزم، لكن في هذه الحالة بدل ما أحصل على
+
+474
+00:42:37,380 --> 00:42:42,560
+كيتون حصلت على الديهايد، في المرة الأولى، ليش حصلت
+
+475
+00:42:42,560 --> 00:42:48,100
+على كيتون؟ لأن ال OH إجت على الكاربون الداخليةفلما
+
+476
+00:42:48,100 --> 00:42:51,380
+صارت C double bond O صفية متصلة بكاربون و بكاربون
+
+477
+00:42:51,380 --> 00:42:55,480
+كيتون في المرة التانية لما أضيف عكس قاعدة
+
+478
+00:42:55,480 --> 00:42:58,800
+Markovnikov و أعمل التوتوميرزم ال OH جت على
+
+479
+00:42:58,800 --> 00:43:04,720
+الكاربون الطرفية ولذلك حصلت على الديهيد اذا انا
+
+480
+00:43:04,720 --> 00:43:10,100
+ممكن احصل من هذا التفاعل على الديهيد او كيتون
+
+481
+00:43:10,100 --> 00:43:13,840
+اعتمادا على الطريقة اللي انا ببدأ فيها اذا ضفت
+
+482
+00:43:13,840 --> 00:43:19,760
+الماء بقاعدة Markovnikovبحصل على كيتون وإذا ضيفت
+
+483
+00:43:19,760 --> 00:43:24,300
+الماء عنتي ماركوفنيكوف بحصل على الديهايد وهذا
+
+484
+00:43:24,300 --> 00:43:27,360
+الكلام لما انتوا تتدربوا و تطبقوا بيدكم هتلاحظوا
+
+485
+00:43:27,360 --> 00:43:32,900
+انه بيطلع بشكل تلقائي النتيجة هذه تطلع معاكم بشكل
+
+486
+00:43:32,900 --> 00:43:42,700
+تلقائي تقريبا الشغلة الأخيرة في هذا الموضوع إضافة
+
+487
+00:43:42,700 --> 00:43:43,680
+الهيدروجين
+
+488
+00:43:45,820 --> 00:43:52,880
+أخرناها كثير إضافة الهيدروجين للـ triple bond لها
+
+489
+00:43:52,880 --> 00:43:57,780
+عدة حالاتإذا ضيفت الهيدروجين في وجود معدن زي
+
+490
+00:43:57,780 --> 00:44:02,380
+البلاديم والكربون أو مثلا ال nickel أو ال platinum
+
+491
+00:44:02,380 --> 00:44:08,060
+أي واحد من هدول بلاديم نيكل platinum عادة معدن
+
+492
+00:44:08,060 --> 00:44:13,680
+البلاديم بيكون مخلوط بكربون بودرة تمام فبتتحول لل
+
+493
+00:44:13,680 --> 00:44:18,820
+triple bond إلى single bond مباشرة بدون مأمورأو
+
+494
+00:44:18,820 --> 00:44:20,940
+بمر في الـ double bond بدون ما أفصل الـ double
+
+495
+00:44:20,940 --> 00:44:26,760
+bond يعني بضيف هيدروجين و كمان هيدروجين فالالكاين
+
+496
+00:44:26,760 --> 00:44:31,760
+إذا فعلنا مع الهيدروجين في وجود متل بيصير الكين
+
+497
+00:44:31,760 --> 00:44:35,340
+يعني لما نيجي نقولكم reaction of alkynes with
+
+498
+00:44:35,340 --> 00:44:40,270
+hydrogen in presence of metals شو بيعطيناالكينز
+
+499
+00:44:40,270 --> 00:44:46,010
+الان طيب لو جيبت الكاين زي هذا وفعلته مع هيدروجين
+
+500
+00:44:46,010 --> 00:44:51,030
+في وجود مادة اسمها لند لارز كتاليست يمكن بالكتابة
+
+501
+00:44:51,030 --> 00:44:55,170
+ناقص حرف ال L لند لارز كتاليست لند لارز كتاليست
+
+502
+00:44:55,170 --> 00:44:57,530
+لند لارز كتاليست لند لارز كتاليست لند لارز كتاليست
+
+503
+00:44:57,530 --> 00:45:02,890
+لند لارز كتاليست بضيف بهذه الحالة الهيدروجين من
+
+504
+00:45:02,890 --> 00:45:10,320
+جهة واحدة وبيعطينيالالكين بيجي في نص الطريق بس إيش
+
+505
+00:45:10,320 --> 00:45:17,260
+نوع إضافة الهيدروجين في وجود الليندلار
+
+506
+00:45:17,260 --> 00:45:18,700
+كاتاليست الهيدروجين الهيدروجين الهيدروجين
+
+507
+00:45:18,700 --> 00:45:20,760
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+508
+00:45:20,760 --> 00:45:21,100
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+509
+00:45:21,100 --> 00:45:21,420
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+510
+00:45:21,420 --> 00:45:21,440
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+511
+00:45:21,440 --> 00:45:24,080
+الهيدروجين الهيدروجين الهيدروجينسيس كومباوند في
+
+512
+00:45:24,080 --> 00:45:26,840
+حالة تانية ممكن لأ يعني لو كانت هذه قدش و قدش مش
+
+513
+00:45:26,840 --> 00:45:30,900
+هيقد لسيس كومباوند أهم شيء عندنا ان الهيدروجين
+
+514
+00:45:30,900 --> 00:45:36,100
+بيضيف بسين اديشن اذا كانت اضافته في وجود لندلار
+
+515
+00:45:36,100 --> 00:45:39,320
+كتاليست و بيقف عن نص الطريق بيقف في وين؟ عند
+
+516
+00:45:39,320 --> 00:45:44,500
+الألكيد طب يا تورا هل ممكن نضيف الهيدروجين انت
+
+517
+00:45:44,500 --> 00:45:51,300
+اديشن يعني على نفس هذا المركب و نطلعالهيدروجين
+
+518
+00:45:51,300 --> 00:45:55,020
+Anti-addition بمعنى إيصير عندي double bond أخلي
+
+519
+00:45:55,020 --> 00:46:03,960
+البنزنتين على جهتين والهيدروجين على جهتين هذا Anti
+
+520
+00:46:03,960 --> 00:46:09,880
+-addition واضح؟ ممكن لو أعملنا التفاعل في وجود
+
+521
+00:46:09,880 --> 00:46:19,310
+ليثيان مع liquid ammoniaواضح؟ اذا انا بإمكاني اضيف
+
+522
+00:46:19,310 --> 00:46:24,470
+الهيدروجين بطريقة معينة يعملي sin addition و
+
+523
+00:46:24,470 --> 00:46:29,630
+بطريقة تانية يعملي anti addition و ممكن اضيفه على
+
+524
+00:46:29,630 --> 00:46:36,970
+مرتين في وجود الهيدروجين و البلاديم او ال nickel
+
+525
+00:46:36,970 --> 00:46:41,990
+او ال platinum ثانية
+
+526
+00:46:41,990 --> 00:46:46,060
+بس لو سمحتواLindlar's catalyst هو عبارة عن خليط من
+
+527
+00:46:46,060 --> 00:46:49,800
+البلاديم مع الكالسيوم كربونيت مع ليد أسيتيت مع
+
+528
+00:46:49,800 --> 00:46:54,360
+كوينولين بهمنيش نحفظ شكله ماخد اسم، إيش اسمه؟
+
+529
+00:46:54,360 --> 00:46:57,000
+Lindlar's catalyst
+
+530
+00:47:00,060 --> 00:47:04,660
+في عندكم طبعا عدة أمثلة عشان انتوا تدرسوها هي
+
+531
+00:47:04,660 --> 00:47:10,100
+تطبيق مباشر على هذا الموضوع بيظل عندنا للمرة
+
+532
+00:47:10,100 --> 00:47:14,100
+الجاية فقط slide واحدة بنحكيها بدقيقتين في موضوع
+
+533
+00:47:14,100 --> 00:47:17,920
+ال kinds و بننتقل لل chapter الرابع اللي هو
+
+534
+00:47:17,920 --> 00:47:23,020
+chapter ال aromatic compounds يعني فقط ضايل عندنا
+
+535
+00:47:23,020 --> 00:47:26,780
+slide واحدة ان شاء الله المرة القادمة بنشرح
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..35d1952504d76508b27c9af3437cc98bdbdbcfd4
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3965, "start": 19.76, "end": 39.66, "text": "بسم الله الرحمن الرحيم نستمر اليوم في موضوع ال carboxylic acids and their derivatives ربما المرة الأخيرة اتكلمنا على تحضير ال acid anhydrides وصنفناهم ل symmetrical anhydride و unsymmetrical anhydride", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 8717, 14851, 29973, 45595, 20498, 8978, 3714, 2407, 11242, 45367, 2423, 1032, 4995, 88, 1050, 21667, 293, 641, 33733, 12602, 3555, 15042, 9673, 25720, 16247, 9778, 48923, 1975, 2655, 4117, 19528, 8315, 15844, 6055, 5016, 11242, 13546, 2423, 8258, 18931, 6655, 81, 1875, 4032, 9381, 1863, 5172, 8315, 16095, 5296, 40360, 18931, 6655, 25502, 4032, 2693, 32497, 32283, 18931, 6655, 25502], "avg_logprob": -0.1626320477102844, "compression_ratio": 1.53551912568306, "no_speech_prob": 0.0, "words": [{"start": 19.76, "end": 20.04, "word": "بسم", "probability": 0.887939453125}, {"start": 20.04, "end": 20.22, "word": " الله", "probability": 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{"start": 100.22, "end": 101.24, "word": " هيصير", "probability": 0.8878580729166666}, {"start": 101.24, "end": 101.84, "word": " amine", "probability": 0.6943359375}], "temperature": 1.0}, {"id": 5, "seek": 12881, "start": 102.09, "end": 128.81, "text": "ان اتش تو مثلا او ان اتش ار هيصير امين وهذا بيطلع على شكل حامض فزي ما بتلاحظوا انه دائما في عندى جزء معين بيطلع على شكل حامض وهذا الجزء اللى هجم عليه النيكليوفايل من الميه لنيكليوفايل OH من الكحول لنيكليوفايل OR من الأمونيا لنيكليوفايل NH2 وبالتالي ممكن ارجع", "tokens": [7649, 1975, 2655, 8592, 33427, 50113, 15040, 1975, 2407, 16472, 1975, 2655, 8592, 1975, 2288, 8032, 1829, 9381, 13546, 1975, 2304, 9957, 37037, 15730, 4724, 1829, 9566, 1211, 3615, 15844, 13412, 28820, 11331, 10943, 11242, 6156, 11622, 1829, 19446, 39894, 15040, 5016, 19913, 14407, 16472, 3224, 11778, 16373, 15042, 8978, 43242, 7578, 10874, 11622, 38207, 20449, 9957, 4724, 1829, 9566, 1211, 3615, 15844, 13412, 28820, 11331, 10943, 11242, 37037, 15730, 25724, 11622, 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123.97, "word": " من", "probability": 0.96435546875}, {"start": 123.97, "end": 124.55, "word": " الأمونيا", "probability": 0.72320556640625}, {"start": 124.55, "end": 125.55, "word": " لنيكليوفايل", "probability": 0.9824916294642857}, {"start": 125.55, "end": 126.43, "word": " NH2", "probability": 0.85107421875}, {"start": 126.43, "end": 127.75, "word": " وبالتالي", "probability": 0.898046875}, {"start": 127.75, "end": 128.23, "word": " ممكن", "probability": 0.990966796875}, {"start": 128.23, "end": 128.81, "word": " ارجع", "probability": 0.94140625}], "temperature": 1.0}, {"id": 6, "seek": 14901, "start": 129.39, "end": 149.01, "text": "لل acid ل ال E star ل الأمد و هكذا هذا مثال تطبيقي اللي موجود عندنا هنا كيف نحضر الأسبيرين واضح؟ كيف نحضر الأسبيرين ربما سبق مار معنا ان احنا بننطلق من ال salicylic acid", "tokens": [1211, 1211, 8258, 5296, 2423, 462, 3543, 5296, 16247, 2304, 3215, 4032, 8032, 4117, 15730, 23758, 50113, 6027, 6055, 9566, 21292, 38436, 13672, 1829, 3714, 29245, 23328, 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"end": 140.85, "word": " الأسبيرين", "probability": 0.73468017578125}, {"start": 140.85, "end": 141.83, "word": " واضح؟", "probability": 0.86767578125}, {"start": 141.83, "end": 142.05, "word": " كيف", "probability": 0.837890625}, {"start": 142.05, "end": 142.49, "word": " نحضر", "probability": 0.996826171875}, {"start": 142.49, "end": 143.45, "word": " الأسبيرين", "probability": 0.986572265625}, {"start": 143.45, "end": 144.65, "word": " ربما", "probability": 0.955078125}, {"start": 144.65, "end": 145.21, "word": " سبق", "probability": 0.9903971354166666}, {"start": 145.21, "end": 145.49, "word": " مار", "probability": 0.7294921875}, {"start": 145.49, "end": 145.89, "word": " معنا", "probability": 0.8955078125}, {"start": 145.89, "end": 146.49, "word": " ان", "probability": 0.25048828125}, {"start": 146.49, "end": 146.79, "word": " احنا", "probability": 0.88671875}, {"start": 146.79, "end": 147.47, "word": " بننطلق", "probability": 0.87294921875}, {"start": 147.47, "end": 147.69, "word": " من", "probability": 0.99560546875}, {"start": 147.69, "end": 147.85, "word": " ال", "probability": 0.84326171875}, {"start": 147.85, "end": 148.63, "word": " salicylic", "probability": 0.9108072916666666}, {"start": 148.63, "end": 149.01, "word": " acid", "probability": 0.9609375}], "temperature": 1.0}, {"id": 7, "seek": 17501, "start": 149.75, "end": 175.01, "text": "الساليسليك أسد اللى هو الحامض ال بنزويك أسد اللى على موقع ألفا منه OH فهو على موقع أورثو منه OH فهو أورثو هيدروكسي بنزويك أسد واسمه ساليسليك أسد وزي ما اتفقنا لازم تكونوا عارفينه سواء قولنا أورثو هيدروكسي بنزويك أسد", "tokens": [6027, 3794, 6027, 1829, 3794, 20292, 4117, 5551, 3794, 3215, 13672, 7578, 31439, 21542, 10943, 11242, 2423, 44945, 11622, 45865, 4117, 5551, 3794, 3215, 13672, 7578, 15844, 3714, 30543, 3615, 5551, 46538, 995, 9154, 3224, 13931, 6156, 3224, 2407, 15844, 3714, 30543, 3615, 34051, 2288, 12984, 2407, 9154, 3224, 13931, 6156, 3224, 2407, 34051, 2288, 12984, 2407, 8032, 25708, 32887, 4117, 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ال common name تبعه ايش salicylic acid الان هذا فيه OH اللي هي تعتبر الكهور من ناحية المبدأ هذا ال OH لما اتهاجل على ال acid anhydride عادة بيفعله مع ال acetic anhydride فهتكسر من هنا الحامض", "tokens": [3224, 15730, 2423, 1315, 1975, 1829, 37746, 4117, 2423, 7649, 45164, 47525, 24793, 2423, 2689, 1315, 6055, 3555, 3615, 3224, 1975, 1829, 8592, 1845, 2632, 1050, 8258, 2423, 7649, 23758, 8978, 3224, 13931, 13672, 1829, 39896, 6055, 34268, 26890, 33251, 3224, 13063, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 23758, 2423, 13931, 5296, 15042, 1975, 47395, 26108, 1211, 15844, 2423, 8258, 18931, 6655, 25502, 6225, 18513, 3660, 4724, 33911, 30241, 3224, 20449, 2423, 696, 3532, 18931, 6655, 25502, 6156, 3224, 2655, 4117, 3794, 2288, 9154, 34105, 21542, 10943, 11242], "avg_logprob": -0.2878472199042638, "compression_ratio": 1.642512077294686, "no_speech_prob": 0.0, "words": [{"start": 176.36, "end": 176.82, "word": "هذا", "probability": 0.940673828125}, {"start": 176.82, "end": 177.08, 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بس بيحاولوا يخففوا من مشاكل تأثيره على المعدة من خلال أنه بيكون مخلوط بنظام ال buffer هو مشكلة الأسبيرين حقيقة أنه الجزء الفعال فيه اللي هو ال salicylic acid نفسه لكن ال salicylic acid نفسه يعني شديد على المعدة", "tokens": [1211, 10721, 31439, 4724, 3794, 4724, 1829, 5016, 995, 12610, 14407, 7251, 9778, 5172, 5172, 14407, 9154, 37893, 995, 28820, 6055, 10721, 12984, 13546, 3224, 15844, 9673, 22488, 3660, 9154, 16490, 1211, 6027, 14739, 3224, 4724, 1829, 30544, 3714, 9778, 1211, 2407, 9566, 44945, 19913, 10943, 2423, 21762, 31439, 37893, 28820, 3660, 16247, 35457, 13546, 9957, 11331, 38436, 28671, 14739, 3224, 25724, 11622, 38207, 27188, 3615, 6027, 8978, 3224, 13672, 1829, 31439, 2423, 1845, 2632, 1050, 8258, 8717, 36178, 3224, 44381, 2423, 1845, 2632, 1050, 8258, 8717, 36178, 3224, 37495, 22653, 13412, 16254, 3215, 15844, 9673, 22488, 3660], "avg_logprob": -0.10314078343034995, "compression_ratio": 1.7647058823529411, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 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بـ Carbon و بـ Carbon و هنا الطبيعة الحالي بـ Carbon هتكون ايش؟ Tertiary بناء على ذلك الأمد بيصير تلت أنواع", "tokens": [2407, 6027, 39184, 37942, 7747, 45164, 25961, 2655, 44650, 36520, 3660, 4724, 39184, 497, 4032, 4724, 39184, 497, 4386, 4724, 39184, 31453, 4032, 4724, 39184, 31453, 4032, 34105, 41950, 21292, 27884, 21542, 6027, 1829, 4724, 39184, 31453, 8032, 2655, 30544, 1975, 1829, 8592, 22807, 6564, 7317, 822, 44945, 16606, 15844, 29910, 23275, 16247, 2304, 3215, 4724, 1829, 9381, 13546, 6055, 1211, 2655, 14739, 14407, 3615], "avg_logprob": -0.26065340547850635, "compression_ratio": 1.391566265060241, "no_speech_prob": 0.0, "words": [{"start": 495.85, "end": 496.41, "word": "والـ", "probability": 0.6417643229166666}, {"start": 496.41, "end": 496.99, "word": " Nitrogen", "probability": 0.646240234375}, {"start": 496.99, "end": 497.45, "word": " لو", "probability": 0.9775390625}, {"start": 497.45, "end": 497.87, "word": " كانت", "probability": 0.971923828125}, {"start": 497.87, 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0.51318359375}, {"start": 503.83, "end": 504.03, "word": " هنا", "probability": 0.53076171875}, {"start": 504.03, "end": 504.55, "word": " الطبيعة", "probability": 0.93603515625}, {"start": 504.55, "end": 504.95, "word": " الحالي", "probability": 0.81298828125}, {"start": 504.95, "end": 505.13, "word": " بـ", "probability": 0.85498046875}, {"start": 505.13, "end": 505.47, "word": " Carbon", "probability": 0.9228515625}, {"start": 505.47, "end": 506.17, "word": " هتكون", "probability": 0.8790690104166666}, {"start": 506.17, "end": 506.83, "word": " ايش؟", "probability": 0.7850341796875}, {"start": 506.83, "end": 507.51, "word": " Tertiary", "probability": 0.6359049479166666}, {"start": 507.51, "end": 508.21, "word": " بناء", "probability": 0.778564453125}, {"start": 508.21, "end": 508.49, "word": " على", "probability": 0.7138671875}, {"start": 508.49, "end": 509.07, "word": " ذلك", "probability": 0.992919921875}, {"start": 509.07, "end": 509.89, "word": " الأمد", "probability": 0.7555338541666666}, {"start": 509.89, "end": 510.47, "word": " بيصير", "probability": 0.942138671875}, {"start": 510.47, "end": 511.05, "word": " تلت", "probability": 0.794921875}, {"start": 511.05, "end": 511.67, "word": " أنواع", "probability": 0.93798828125}], "temperature": 1.0}, {"id": 23, "seek": 53989, "start": 512.49, "end": 539.89, "text": "والأمد بيصير تعريفه العام C double bond O متصلة بإيش؟ بنيتروجين هالنيتروجين هذه تكون NH2 primary أمد NHR secondary أمد NR2 tertiary أمد واضح هذه الفكرة؟ الآن هذه الفكرة طالما احنا وقفنا عندها هتجيبنا لنقطة كتير مهمة", "tokens": [2407, 6027, 10721, 2304, 3215, 4724, 1829, 9381, 13546, 37279, 16572, 5172, 3224, 18863, 10943, 383, 3834, 6086, 422, 44650, 36520, 3660, 4724, 28814, 1829, 8592, 22807, 44945, 36081, 2288, 29245, 9957, 8032, 6027, 22653, 2655, 2288, 29245, 9957, 29538, 6055, 30544, 31118, 17, 6194, 5551, 2304, 3215, 31118, 49, 11396, 5551, 2304, 3215, 38399, 17, 38726, 29104, 5551, 2304, 3215, 4032, 46958, 5016, 29538, 27188, 4117, 25720, 22807, 6024, 48506, 29538, 27188, 4117, 25720, 23032, 6027, 15042, 1975, 5016, 8315, 4032, 4587, 5172, 8315, 43242, 11296, 8032, 2655, 7435, 1829, 3555, 8315, 5296, 1863, 47432, 3660, 9122, 2655, 13546, 3714, 16095, 3660], "avg_logprob": -0.24338941992475435, "compression_ratio": 1.5936073059360731, "no_speech_prob": 0.0, "words": [{"start": 512.49, "end": 513.19, "word": "والأمد", "probability": 0.719677734375}, {"start": 513.19, "end": 513.91, "word": " بيصير", "probability": 0.8560791015625}, {"start": 513.91, "end": 514.53, "word": " تعريفه", "probability": 0.9832763671875}, {"start": 514.53, "end": 515.03, "word": " العام", "probability": 0.88427734375}, {"start": 515.03, "end": 515.75, "word": " C", "probability": 0.5615234375}, {"start": 515.75, "end": 516.15, "word": " double", "probability": 0.2489013671875}, {"start": 516.15, "end": 516.63, "word": " bond", "probability": 0.9267578125}, {"start": 516.63, "end": 517.17, "word": " O", "probability": 0.81787109375}, {"start": 517.17, "end": 518.09, "word": " متصلة", "probability": 0.5978190104166666}, {"start": 518.09, "end": 518.69, "word": " بإيش؟", "probability": 0.75068359375}, {"start": 518.69, "end": 520.17, "word": " بنيتروجين", "probability": 0.7569580078125}, {"start": 520.17, "end": 521.19, "word": " هالنيتروجين", "probability": 0.7462855747767857}, {"start": 521.19, "end": 521.47, "word": " هذه", "probability": 0.368408203125}, {"start": 521.47, "end": 522.19, "word": " تكون", "probability": 0.871826171875}, {"start": 522.19, "end": 523.11, "word": " NH2", "probability": 0.77001953125}, {"start": 523.11, "end": 524.53, "word": " primary", "probability": 0.6767578125}, {"start": 524.53, "end": 524.93, "word": " أمد", "probability": 0.8046061197916666}, {"start": 524.93, "end": 526.13, "word": " NHR", "probability": 0.716064453125}, {"start": 526.13, "end": 527.35, "word": " secondary", "probability": 0.179931640625}, {"start": 527.35, "end": 527.69, "word": " أمد", "probability": 0.9137369791666666}, {"start": 527.69, "end": 528.87, "word": " NR2", "probability": 0.6392822265625}, {"start": 528.87, "end": 530.03, "word": " tertiary", "probability": 0.948974609375}, {"start": 530.03, "end": 530.65, "word": " أمد", "probability": 0.9404296875}, {"start": 530.65, "end": 530.93, "word": " واضح", "probability": 0.96728515625}, {"start": 530.93, "end": 531.15, "word": " هذه", "probability": 0.296875}, {"start": 531.15, "end": 532.97, "word": " الفكرة؟", "probability": 0.9107666015625}, {"start": 532.97, "end": 533.43, "word": " الآن", "probability": 0.7626953125}, {"start": 533.43, "end": 534.11, "word": " هذه", "probability": 0.87890625}, {"start": 534.11, "end": 534.63, "word": " الفكرة", "probability": 0.9954427083333334}, {"start": 534.63, "end": 535.13, "word": " طالما", "probability": 0.9840494791666666}, {"start": 535.13, "end": 535.63, "word": " احنا", "probability": 0.83642578125}, {"start": 535.63, "end": 536.07, "word": " وقفنا", "probability": 0.95703125}, {"start": 536.07, "end": 536.71, "word": " عندها", "probability": 0.9970703125}, {"start": 536.71, "end": 538.41, "word": " هتجيبنا", "probability": 0.9032389322916666}, {"start": 538.41, "end": 538.97, "word": " لنقطة", "probability": 0.961181640625}, {"start": 538.97, "end": 539.29, "word": " كتير", "probability": 0.9381510416666666}, {"start": 539.29, "end": 539.89, "word": " مهمة", "probability": 0.9951171875}], "temperature": 1.0}, {"id": 24, "seek": 56779, "start": 541.11, "end": 567.79, "text": "العمل ممكن يعمل hydrogen bonding وممكن مايعملش وممكن يعمل بشكل كبير وممكن يعمل بشكل اقل عارفين انتوا ال hydrogen bonding بيصير لما يكون عندى hydrogen متطابط يا بنيتروجين يا باكسوجين يا بفلورين الان لو اجيت على المركب اللى هو ال primary amine فيه MH", "tokens": [6027, 25957, 1211, 3714, 43020, 7251, 25957, 1211, 12697, 28824, 4032, 2304, 43020, 19446, 1829, 25957, 1211, 8592, 4032, 2304, 43020, 7251, 25957, 1211, 4724, 8592, 28820, 9122, 3555, 13546, 4032, 2304, 43020, 7251, 25957, 1211, 4724, 8592, 28820, 1975, 4587, 1211, 6225, 9640, 5172, 9957, 16472, 2655, 14407, 2423, 12697, 28824, 4724, 1829, 9381, 13546, 5296, 15042, 7251, 30544, 43242, 7578, 12697, 44650, 9566, 16758, 9566, 35186, 44945, 36081, 2288, 29245, 9957, 35186, 4724, 995, 4117, 3794, 29245, 9957, 35186, 4724, 5172, 1211, 13063, 9957, 2423, 7649, 45164, 1975, 7435, 36081, 15844, 9673, 31747, 3555, 13672, 7578, 31439, 2423, 6194, 669, 533, 8978, 3224, 34796], "avg_logprob": -0.2521904350441193, "compression_ratio": 1.9371980676328502, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 541.11, "end": 542.11, "word": "العمل", "probability": 0.6084798177083334}, {"start": 542.11, "end": 543.11, "word": " ممكن", "probability": 0.7283935546875}, {"start": 543.11, "end": 543.81, "word": " يعمل", "probability": 0.9749348958333334}, {"start": 543.81, "end": 544.89, "word": " hydrogen", "probability": 0.12384033203125}, {"start": 544.89, "end": 545.55, "word": " bonding", "probability": 0.92431640625}, {"start": 545.55, "end": 546.69, "word": " وممكن", "probability": 0.7965494791666666}, {"start": 546.69, "end": 548.87, "word": " مايعملش", "probability": 0.723828125}, {"start": 548.87, "end": 549.25, "word": " وممكن", "probability": 0.7495930989583334}, {"start": 549.25, "end": 549.59, "word": " يعمل", "probability": 0.9523111979166666}, {"start": 549.59, "end": 550.01, "word": " بشكل", "probability": 0.98046875}, {"start": 550.01, "end": 550.51, "word": " كبير", "probability": 0.9921875}, {"start": 550.51, "end": 551.21, "word": " وممكن", "probability": 0.93798828125}, {"start": 551.21, "end": 551.53, "word": " يعمل", "probability": 0.9724934895833334}, {"start": 551.53, "end": 551.93, "word": " بشكل", "probability": 0.9856770833333334}, {"start": 551.93, "end": 552.27, "word": " اقل", "probability": 0.7964680989583334}, {"start": 552.27, "end": 552.73, "word": " عارفين", "probability": 0.913330078125}, {"start": 552.73, "end": 552.97, "word": " انتوا", "probability": 0.7685546875}, {"start": 552.97, "end": 553.05, "word": " ال", "probability": 0.873046875}, {"start": 553.05, "end": 553.41, "word": " hydrogen", "probability": 0.74951171875}, {"start": 553.41, "end": 553.83, "word": " bonding", "probability": 0.95263671875}, {"start": 553.83, "end": 554.43, "word": " بيصير", "probability": 0.9171142578125}, {"start": 554.43, "end": 554.95, "word": " لما", "probability": 0.935302734375}, {"start": 554.95, "end": 555.19, "word": " يكون", "probability": 0.98046875}, {"start": 555.19, "end": 555.47, "word": " عندى", "probability": 0.823486328125}, {"start": 555.47, "end": 555.99, "word": " hydrogen", "probability": 0.6396484375}, {"start": 555.99, "end": 556.85, "word": " متطابط", "probability": 0.65985107421875}, {"start": 556.85, "end": 557.59, "word": " يا", "probability": 0.50341796875}, {"start": 557.59, "end": 558.37, "word": " بنيتروجين", "probability": 0.74775390625}, {"start": 558.37, "end": 558.55, "word": " يا", "probability": 0.80126953125}, {"start": 558.55, "end": 559.17, "word": " باكسوجين", "probability": 0.7635091145833334}, {"start": 559.17, "end": 559.45, "word": " يا", "probability": 0.9091796875}, {"start": 559.45, "end": 560.13, "word": " بفلورين", "probability": 0.96943359375}, {"start": 560.13, "end": 561.05, "word": " الان", "probability": 0.69775390625}, {"start": 561.05, "end": 561.49, "word": " لو", "probability": 0.9814453125}, {"start": 561.49, "end": 561.99, "word": " اجيت", "probability": 0.8299153645833334}, {"start": 561.99, "end": 562.37, "word": " على", "probability": 0.81494140625}, {"start": 562.37, "end": 563.73, "word": " المركب", "probability": 0.9254557291666666}, {"start": 563.73, "end": 563.87, "word": " اللى", "probability": 0.862548828125}, {"start": 563.87, "end": 564.05, "word": " هو", "probability": 0.89404296875}, {"start": 564.05, "end": 564.23, "word": " ال", "probability": 0.9453125}, {"start": 564.23, "end": 564.97, "word": " primary", "probability": 0.90234375}, {"start": 564.97, "end": 565.57, "word": " amine", "probability": 0.4388427734375}, {"start": 565.57, "end": 567.41, "word": " فيه", "probability": 0.649658203125}, {"start": 567.41, "end": 567.79, "word": " MH", "probability": 0.417236328125}], "temperature": 1.0}, {"id": 25, "seek": 59349, "start": 569.61, "end": 593.49, "text": "و تنتين مش واحدة تمام اذا ال primary amide ممكن يعمل hydrogen bonding ولا لأ و ممكن يعمل كام hydrogen bonding طالما فيه تنتين hydrogen ممكن يعمل two hydrogen bonding الان لو اجيت على ال secondary amide في كام هيدروجينة", "tokens": [2407, 6055, 29399, 9957, 37893, 36764, 24401, 3660, 46811, 10943, 1975, 15730, 2423, 6194, 669, 482, 3714, 43020, 7251, 25957, 1211, 12697, 28824, 49429, 5296, 10721, 4032, 3714, 43020, 7251, 25957, 1211, 9122, 10943, 12697, 28824, 23032, 6027, 15042, 8978, 3224, 6055, 29399, 9957, 12697, 3714, 43020, 7251, 25957, 1211, 732, 12697, 28824, 2423, 7649, 45164, 1975, 7435, 36081, 15844, 2423, 11396, 669, 482, 8978, 9122, 10943, 8032, 25708, 2288, 29245, 9957, 3660], "avg_logprob": -0.21072635598279335, "compression_ratio": 1.7796610169491525, "no_speech_prob": 0.0, "words": [{"start": 569.61, "end": 569.97, "word": "و", "probability": 0.53369140625}, {"start": 569.97, "end": 570.73, "word": " تنتين", "probability": 0.706787109375}, {"start": 570.73, "end": 570.95, "word": " مش", "probability": 0.55615234375}, {"start": 570.95, "end": 571.51, "word": " واحدة", "probability": 0.9397786458333334}, {"start": 571.51, "end": 572.41, "word": " تمام", "probability": 0.6875}, {"start": 572.41, "end": 573.15, "word": " اذا", "probability": 0.59442138671875}, {"start": 573.15, "end": 573.63, "word": " ال", "probability": 0.9345703125}, {"start": 573.63, "end": 574.27, "word": " primary", "probability": 0.82470703125}, {"start": 574.27, "end": 574.69, "word": " amide", "probability": 0.681640625}, {"start": 574.69, "end": 575.15, "word": " ممكن", "probability": 0.97216796875}, {"start": 575.15, "end": 575.77, "word": " يعمل", "probability": 0.9724934895833334}, {"start": 575.77, "end": 576.35, "word": " hydrogen", "probability": 0.84423828125}, {"start": 576.35, "end": 576.89, "word": " bonding", "probability": 0.95849609375}, {"start": 576.89, "end": 577.15, "word": " ولا", "probability": 0.7177734375}, {"start": 577.15, "end": 577.59, "word": " لأ", "probability": 0.84033203125}, {"start": 577.59, "end": 578.35, "word": " و", "probability": 0.43798828125}, {"start": 578.35, "end": 578.69, "word": " ممكن", "probability": 0.827392578125}, {"start": 578.69, "end": 579.07, "word": " يعمل", "probability": 0.9903971354166666}, {"start": 579.07, "end": 579.35, "word": " كام", "probability": 0.825927734375}, {"start": 579.35, "end": 579.87, "word": " hydrogen", "probability": 0.896484375}, {"start": 579.87, "end": 580.43, "word": " bonding", "probability": 0.96630859375}, {"start": 580.43, "end": 581.43, "word": " طالما", "probability": 0.96533203125}, {"start": 581.43, "end": 581.71, "word": " فيه", "probability": 0.6116943359375}, {"start": 581.71, "end": 582.11, "word": " تنتين", "probability": 0.98779296875}, {"start": 582.11, "end": 582.63, "word": " hydrogen", "probability": 0.6708984375}, {"start": 582.63, "end": 583.47, "word": " ممكن", "probability": 0.940185546875}, {"start": 583.47, "end": 583.85, "word": " يعمل", "probability": 0.9930013020833334}, {"start": 583.85, "end": 584.09, "word": " two", "probability": 0.8525390625}, {"start": 584.09, "end": 584.73, "word": " hydrogen", "probability": 0.94970703125}, {"start": 584.73, "end": 585.37, "word": " bonding", "probability": 0.96435546875}, {"start": 585.37, "end": 587.73, "word": " الان", "probability": 0.6328125}, {"start": 587.73, "end": 588.17, "word": " لو", "probability": 0.97705078125}, {"start": 588.17, "end": 588.59, "word": " اجيت", "probability": 0.8439127604166666}, {"start": 588.59, "end": 588.93, "word": " على", "probability": 0.8408203125}, {"start": 588.93, "end": 589.31, "word": " ال", "probability": 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خاصية على ال boiling point بناء على ذلك لما انا بدي اجي احكي عن ال boiling point مين هيكون اعلى boiling point ال primary اعلى من ال secondary اعلى من ال tertiary", "tokens": [3555, 22488, 3224, 38726, 29104, 6225, 23032, 12610, 3714, 3555, 33599, 25720, 2423, 12697, 28824, 44945, 3615, 4117, 3794, 15844, 36632, 16490, 33546, 10632, 15844, 2423, 16208, 935, 44945, 16606, 15844, 29910, 23275, 5296, 15042, 1975, 8315, 4724, 16254, 1975, 7435, 1829, 1975, 5016, 4117, 1829, 18871, 2423, 16208, 935, 3714, 9957, 39896, 30544, 1975, 3615, 23942, 16208, 935, 2423, 6194, 1975, 3615, 23942, 9154, 2423, 11396, 1975, 3615, 23942, 9154, 2423, 38726, 29104], "avg_logprob": -0.170625003973643, "compression_ratio": 1.7135135135135136, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 618.45, "end": 619.65, "word": "بعده", "probability": 0.7799479166666666}, {"start": 619.65, "end": 621.03, "word": " tertiary", "probability": 0.6678466796875}, {"start": 621.03, "end": 621.51, "word": " ع", 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احنا قلنا تقريبا تلت اسابيع اربعة بس بندرس ال Carbonyl groups ال C double bond O في ال aldehydes في ال ketones في ال acids في ال E stars very reactive واضح؟", "tokens": [2407, 2741, 65, 2526, 75, 383, 3834, 6086, 422, 2423, 7649, 20193, 5016, 19913, 14407, 20449, 995, 25528, 28242, 36764, 24401, 3660, 9154, 16095, 9154, 5172, 2288, 41891, 588, 28897, 37495, 22653, 2423, 2741, 65, 2526, 75, 1594, 45164, 24401, 11296, 588, 28897, 4032, 1975, 5016, 8315, 12174, 1211, 8315, 6055, 4587, 16572, 3555, 995, 6055, 1211, 2655, 24525, 16758, 40228, 1975, 25513, 27884, 4724, 3794, 44945, 3215, 2288, 3794, 2423, 2741, 65, 2526, 75, 3935, 2423, 383, 3834, 6086, 422, 8978, 2423, 16798, 68, 3495, 14792, 8978, 2423, 14979, 2213, 8978, 2423, 21667, 8978, 2423, 462, 6105, 588, 28897, 4032, 46958, 5016, 22807], "avg_logprob": -0.2385416689373198, "compression_ratio": 1.7880184331797235, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1154.1, "end": 1154.32, "word": "و", "probability": 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double", "probability": 0.85009765625}, {"start": 1174.16, "end": 1174.5, "word": " bond", "probability": 0.96044921875}, {"start": 1174.5, "end": 1174.74, "word": " O", "probability": 0.9765625}, {"start": 1174.74, "end": 1174.9, "word": " في", "probability": 0.7705078125}, {"start": 1174.9, "end": 1174.98, "word": " ال", "probability": 0.919921875}, {"start": 1174.98, "end": 1175.72, "word": " aldehydes", "probability": 0.65228271484375}, {"start": 1175.72, "end": 1175.9, "word": " في", "probability": 0.7841796875}, {"start": 1175.9, "end": 1175.96, "word": " ال", "probability": 0.779296875}, {"start": 1175.96, "end": 1176.46, "word": " ketones", "probability": 0.77099609375}, {"start": 1176.46, "end": 1176.62, "word": " في", "probability": 0.9521484375}, {"start": 1176.62, "end": 1176.74, "word": " ال", "probability": 0.94921875}, {"start": 1176.74, "end": 1177.12, "word": " acids", "probability": 0.783203125}, {"start": 1177.12, "end": 1177.3, "word": " في", "probability": 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ال reactivity تفاعل مع الخارج تمام", "tokens": [409, 265, 12596, 44381, 13672, 1829, 4724, 33911, 16095, 32748, 22653, 995, 4724, 1829, 28543, 2288, 7251, 5172, 16095, 23758, 16247, 29973, 10874, 25708, 995, 13672, 1829, 4724, 33911, 16095, 32748, 22653, 995, 4724, 1829, 28543, 2288, 7251, 5172, 16095, 23758, 16247, 29973, 10874, 25708, 995, 2423, 4515, 4253, 2423, 4515, 4253, 20449, 8315, 11296, 6055, 5172, 995, 30241, 20449, 33962, 9640, 7435, 2423, 4515, 4253, 6055, 5172, 995, 30241, 20449, 33962, 9640, 7435, 46811, 10943], "avg_logprob": -0.10998376584672309, "compression_ratio": 2.3282442748091605, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1251.5900000000001, "end": 1252.91, "word": "unreactive", "probability": 0.7569986979166666}, {"start": 1252.91, "end": 1254.23, "word": " لكن", "probability": 0.58154296875}, {"start": 1254.23, "end": 1254.69, "word": " اللي", "probability": 0.916015625}, {"start": 1254.69, "end": 1255.31, "word": " بيفهم", "probability": 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"end": 1275.38, "word": " الأمة", "probability": 0.8818359375}, {"start": 1275.38, "end": 1276.42, "word": " العربية", "probability": 0.9793294270833334}, {"start": 1276.42, "end": 1276.56, "word": " ..", "probability": 0.443603515625}, {"start": 1276.56, "end": 1277.22, "word": " الأمة", "probability": 0.894287109375}, {"start": 1277.22, "end": 1278.12, "word": " العربية", "probability": 0.9903971354166666}, {"start": 1278.12, "end": 1278.82, "word": " كان", "probability": 0.9677734375}, {"start": 1278.82, "end": 1279.56, "word": " ممكن", "probability": 0.95751953125}, {"start": 1279.56, "end": 1280.1, "word": " تكون", "probability": 0.995849609375}, {"start": 1280.1, "end": 1280.9, "word": " reactive", "probability": 0.87060546875}, {"start": 1280.9, "end": 1281.76, "word": " بس", "probability": 0.823974609375}, {"start": 1281.76, "end": 1282.26, "word": " بشرط", "probability": 0.9119466145833334}, {"start": 1282.26, "end": 1282.94, "word": " reactive", "probability": 0.73193359375}, 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" نيجي", "probability": 0.96435546875}, {"start": 2208.49, "end": 2208.85, "word": " نقول", "probability": 0.992431640625}, {"start": 2208.85, "end": 2209.91, "word": " تحضير", "probability": 0.9290771484375}, {"start": 2209.91, "end": 2210.77, "word": " الأمين", "probability": 0.9576822916666666}], "temperature": 1.0}, {"id": 98, "seek": 223779, "start": 2212.89, "end": 2237.79, "text": "بالـ reduction of amides شبيه بهذا التفاعل عشان تعملوا المقارنة انه كان ال Easter ال R سيضا بالبند OOR بالليثيام ألومنوم هيدرايد بال reduction شو كان يعطيني ال primary alcohol كان يعطيني RCH2OH لاحظوا المعادلتين هدولة", "tokens": [3555, 6027, 39184, 11004, 295, 669, 1875, 13412, 21292, 3224, 39627, 15730, 16712, 5172, 995, 30241, 6225, 8592, 7649, 6055, 25957, 1211, 14407, 9673, 4587, 9640, 1863, 3660, 16472, 3224, 25961, 2423, 9403, 2423, 497, 8608, 1829, 11242, 995, 20666, 3555, 41260, 422, 2483, 20666, 20292, 12984, 1829, 10943, 5551, 1211, 20498, 1863, 20498, 8032, 25708, 23557, 25708, 20666, 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"word": "طبعاً", "probability": 0.84755859375}, {"start": 2519.02, "end": 2519.1, "word": " في", "probability": 0.87060546875}, {"start": 2519.1, "end": 2519.56, "word": " أشياء", "probability": 0.938232421875}, {"start": 2519.56, "end": 2519.96, "word": " تانية", "probability": 0.9910481770833334}, {"start": 2519.96, "end": 2520.7, "word": " فرمونات", "probability": 0.7783203125}, {"start": 2520.7, "end": 2521.16, "word": " بنسميها", "probability": 0.930908203125}, {"start": 2521.16, "end": 2521.44, "word": " برضه", "probability": 0.7591959635416666}, {"start": 2521.44, "end": 2521.82, "word": " أشياء", "probability": 0.9576416015625}, {"start": 2521.82, "end": 2522.48, "word": " تطبيقية", "probability": 0.9779296875}, {"start": 2522.48, "end": 2522.86, "word": " على", "probability": 0.86572265625}, {"start": 2522.86, "end": 2523.52, "word": " ال", "probability": 0.91650390625}, {"start": 2523.52, "end": 2523.68, "word": " e", "probability": 0.2301025390625}, {"start": 2523.68, "end": 2523.98, "word": "-stars", "probability": 0.665771484375}, {"start": 2523.98, "end": 2524.18, "word": " و", "probability": 0.74853515625}, {"start": 2524.18, "end": 2524.26, "word": " ال", "probability": 0.908203125}, {"start": 2524.26, "end": 2524.64, "word": " emits", "probability": 0.37353515625}, {"start": 2524.64, "end": 2525.62, "word": " بهيك", "probability": 0.7246907552083334}, {"start": 2525.62, "end": 2526.72, "word": " بننهي", "probability": 0.935791015625}, {"start": 2526.72, "end": 2527.04, "word": " اليوم", "probability": 0.978271484375}, {"start": 2527.04, "end": 2527.18, "word": " و", "probability": 0.6171875}, {"start": 2527.18, "end": 2527.18, "word": " ان", "probability": 0.634765625}, {"start": 2527.18, "end": 2527.38, "word": " شاء", "probability": 0.98681640625}, {"start": 2527.38, "end": 2527.44, "word": " الله", "probability": 0.94384765625}, {"start": 2527.44, "end": 2527.76, "word": " المرة", "probability": 0.960205078125}, {"start": 2527.76, "end": 2528.22, "word": " القادمة", "probability": 0.98681640625}, {"start": 2528.22, "end": 2528.7, "word": " بنبدأ", "probability": 0.94677734375}, {"start": 2528.7, "end": 2528.84, "word": " في", "probability": 0.8212890625}, {"start": 2528.84, "end": 2529.3, "word": " chapter", "probability": 0.88330078125}, {"start": 2529.3, "end": 2531.6, "word": " ال", "probability": 0.83544921875}, {"start": 2531.6, "end": 2532.28, "word": " emits", "probability": 0.866943359375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2533.20425, "duration_after_vad": 2446.1212499999906}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d95dd93f77dde0b3faa58bc5545f755e70b8649f
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_postprocess.srt
@@ -0,0 +1,1504 @@
+1
+00:00:19,940 --> 00:00:25,100
+بسم الله الرحمن الرحيم اليوم بنبتدأ في الفصل
+
+2
+00:00:25,100 --> 00:00:29,820
+المكمل خلينا نقول للالديهيدس والكيتونز اللي هو ال
+
+3
+00:00:29,820 --> 00:00:33,940
+carboxylic acids and their derivatives طبعا ليش
+
+4
+00:00:33,940 --> 00:00:38,900
+احنا قولنا الفصل المكمل لأن كل هذه المجموعة من
+
+5
+00:00:38,900 --> 00:00:42,240
+المركبات هي ال carbonyl containing compounds
+
+6
+00:00:42,240 --> 00:00:46,980
+المركبات يعني اللي فيها مجموعة السيضة بال bond O
+
+7
+00:00:47,750 --> 00:00:51,810
+صنفنا ال الديهيدز والكيتونز لوحدنا وقلنا هدولة
+
+8
+00:00:51,810 --> 00:00:56,810
+جماعة ال addition او الإضافة الآن بيجي عند
+
+9
+00:00:56,810 --> 00:01:01,330
+الكاربوكسيليك أسدوبنقول عن المراكبات التانية
+
+10
+00:01:01,330 --> 00:01:04,290
+derivatives of carboxylic acids مشتقة من ال
+
+11
+00:01:04,290 --> 00:01:08,770
+carboxylic acids بمعنى تبدل فيها مجموعة ال OH
+
+12
+00:01:08,770 --> 00:01:14,770
+بمجموعة تانية فإذا أبدلت ب OR بيصير Easter إذا
+
+13
+00:01:14,770 --> 00:01:20,190
+أبدلت ب NH2 و لا NHR بيصير Amid إذا أبدلت بCL أو
+
+14
+00:01:20,190 --> 00:01:24,310
+بR بيصير Acid Halide Acid chloride or bromide إذا
+
+15
+00:01:24,310 --> 00:01:27,490
+أبدلت بOC double bond O بيصير Acid anhydride
+
+16
+00:01:27,490 --> 00:01:34,570
+فبنقول إحناCarboxylic Acids and their derivatives
+
+17
+00:01:34,570 --> 00:01:40,630
+و لذلك لو أتينا مثلا سألناكوا السؤال E stars are
+
+18
+00:01:40,630 --> 00:01:45,450
+Carboxylic Acid derivatives صح Acid chlorides are
+
+19
+00:01:45,450 --> 00:01:48,070
+Carboxylic Acid derivatives صح لكن لو مثلا
+
+20
+00:01:48,070 --> 00:01:51,870
+قلنالكوا E stars are Carboxylic Acid derivatives
+
+21
+00:01:51,870 --> 00:01:57,050
+no aldehydes or ketones or alcohol واضح فاللي
+
+22
+00:01:57,050 --> 00:02:04,490
+بنقصده بال derivative كم نوعأربعة أستر أمد أسد
+
+23
+00:02:04,490 --> 00:02:12,370
+كلورايد و أسد أنهايدرايد الأسد
+
+24
+00:02:12,370 --> 00:02:15,950
+أنهايدرايد الأسد أنهايدرايد ماخد الصيغة العامة
+
+25
+00:02:15,950 --> 00:02:18,730
+الاتية R C double bond O
+
+26
+00:02:34,410 --> 00:02:35,810
+وووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو
+
+27
+00:02:50,150 --> 00:02:56,550
+طبعا دائما اول ما بنبدأ بنبدأ باش بتسمية العائلات
+
+28
+00:02:56,550 --> 00:03:01,890
+و احنا اتفقنا ان التسمية في النظام ال IUPAC تسمية
+
+29
+00:03:01,890 --> 00:03:07,630
+سهلة اهم فيها معرفة اطول سلسلة و نعرف ايش العائلة
+
+30
+00:03:07,630 --> 00:03:11,410
+بناء على الترتيبات اللي اتعلمناها سابقا الان لما
+
+31
+00:03:11,410 --> 00:03:17,230
+تكون العائلة الأحماض بنحط النهاية oic acid واضح
+
+32
+00:03:17,230 --> 00:03:22,830
+فالنهاية اللي بدنا نضيفها شو هيoic acid يعني لو
+
+33
+00:03:22,830 --> 00:03:29,270
+كان مع carbon واحدة إيش هنقول المركب مثال oic acid
+
+34
+00:03:29,270 --> 00:03:34,930
+carbon 2 إيثانويك أسد بروبانويك أسد بيوتانويك أسد
+
+35
+00:03:34,930 --> 00:03:39,730
+and so on ولذلك هذا المركب مثلا و العاد دائما
+
+36
+00:03:39,730 --> 00:03:43,730
+بيكون من عند ال acid ال acid دائما موجود على نمرة
+
+37
+00:03:43,730 --> 00:03:48,670
+واحد ولذلك مابنكتبش one oic acid لأ بس acid يعني
+
+38
+00:03:48,670 --> 00:03:54,420
+مثلا هذا المركبواحد، اتنين، تلاتة، اربعة، خمسة،
+
+39
+00:03:54,420 --> 00:03:58,900
+ستة دائما الحاجة اللي مكتوبة بين قسيل معناه انه
+
+40
+00:03:58,900 --> 00:04:03,860
+هذه معلجة واضح؟ يعني لما انا اكون هنا كاتب CH بين
+
+41
+00:04:03,860 --> 00:04:10,990
+قسيل CH3 معناه ذلك هذه ال CH3 معلجة هناواضح ايش
+
+42
+00:04:10,990 --> 00:04:14,050
+تفسيرها لما بكتبها بين قوسين بس لإن انا بكتب على
+
+43
+00:04:14,050 --> 00:04:19,410
+السطر بقدرش ا في برنامج الطباعة اطلع خط زي هيك و
+
+44
+00:04:19,410 --> 00:04:24,430
+ارسم زي هيك فبحط بين قوسين و بكتب CH3 فاللي موجودة
+
+45
+00:04:24,430 --> 00:04:27,910
+في داخل السلسلة بين قوسين يعني معلجة على المجموعة
+
+46
+00:04:27,910 --> 00:04:34,350
+اللي قبلها الان هذا المركب اكيد hexanoic acid على
+
+47
+00:04:34,350 --> 00:04:40,340
+نمرة تلاتة ال hexanoic acid شو بيحمل؟مثل فبصير
+
+48
+00:04:40,340 --> 00:04:44,040
+three methyl hexanoic acid
+
+49
+00:04:49,490 --> 00:04:54,850
+زي ما اتفقنا احنا ان الأحماض بالتدريج هتمشي مثانوك
+
+50
+00:04:54,850 --> 00:04:58,770
+ايثانوك بروبانوك بيوتانوك بنتانوك هكسانوك هبتانوك
+
+51
+00:04:58,770 --> 00:05:05,670
+اكتانوك نونا نوك ديكانوك ديكان يعني عشرة الان هذه
+
+52
+00:05:05,670 --> 00:05:10,910
+الأحماض لها أسماء شهرة هذه الأحماض لها أسماء شهرة
+
+53
+00:05:10,910 --> 00:05:15,890
+أقل تقدير نسمع فيها لمرة و نعرف أبسط اتنين او
+
+54
+00:05:15,890 --> 00:05:21,470
+تلاتة منهاالحمض اللي من كاربون واحدة formic acid
+
+55
+00:05:21,470 --> 00:05:27,310
+واضح؟ اللي من تنتين acidic acid اللي في مجموعة ال
+
+56
+00:05:27,310 --> 00:05:32,390
+acid اللي أخدناها تلاتة probionic بنقولش probionic
+
+57
+00:05:32,390 --> 00:05:38,470
+بروبانوك الاربعة بيوتانوك بيوتاريكبيوتاريك أسد
+
+58
+00:05:38,470 --> 00:05:42,390
+بعدين بيجي الخامسة Valeric و بعدين Caproic,
+
+59
+00:05:42,510 --> 00:05:46,950
+Enanthic, Caprylic, Pelargonic, Capric طبعا مش
+
+60
+00:05:46,950 --> 00:05:50,870
+ضرور نحفظها الأسماء لكن أقل تقدير يكون اسمعناها
+
+61
+00:05:50,870 --> 00:05:54,650
+مرة يعني لو في يوم من الأيام لجينا انه اخلط ال
+
+62
+00:05:54,650 --> 00:05:59,070
+Valeric acidنجي نتذكر شو ال valeric acid نفتح
+
+63
+00:05:59,070 --> 00:06:02,830
+الكتاب أو ال net نتذكر أن ال valeric acid هو ال
+
+64
+00:06:02,830 --> 00:06:06,730
+pentanoic acid واضح؟ بس أكيد أقل تقدير لما نقول
+
+65
+00:06:06,730 --> 00:06:11,850
+ethanoic acid هو ال acetic acid, methanoic acid هو
+
+66
+00:06:11,850 --> 00:06:15,630
+ال formic acid اللي أساسا جاي من وين ال formic
+
+67
+00:06:15,630 --> 00:06:20,930
+acid؟ من ال antsاللي هي باللاتيني formica يعني من
+
+68
+00:06:20,930 --> 00:06:25,770
+النمل هو الحمب اللي النملة لما بتجرس بتحطه بالإيد
+
+69
+00:06:25,770 --> 00:06:31,150
+عشان هيك القرص بيكون مؤلم واضح؟ يعني النملة لما
+
+70
+00:06:31,150 --> 00:06:37,170
+بتعمل قرص للبني آدم بتبخ شوية formic acid هذا اللي
+
+71
+00:06:37,170 --> 00:06:43,630
+بيسبب القلم عند الإنسان واضح؟
+
+72
+00:06:45,960 --> 00:06:49,860
+هذه أمثلة إضافية على تسمية ال assets واضح أنه
+
+73
+00:06:49,860 --> 00:06:53,960
+الأساس البحث عن أطول سلسة و الترقيم من عند ال c
+
+74
+00:06:53,960 --> 00:06:57,640
+double bond o يعني نمرة واحد هي إيش ال c double
+
+75
+00:06:57,640 --> 00:07:03,020
+bond o الآن انتبهوا لخطأ شائع بصره الطلاب جد ما
+
+76
+00:07:03,020 --> 00:07:06,420
+بتعد معهم إنهم يخطئوا فيه إنه أول ما يشوفوا c
+
+77
+00:07:06,420 --> 00:07:11,700
+double bond oبياخدوا هذا الجزء و بيقولوا CWO على
+
+78
+00:07:11,700 --> 00:07:16,040
+الطرف إذا هذا الديهايد و الديهايد على نمر واحد
+
+79
+00:07:16,040 --> 00:07:19,600
+حامل مجموعة هيدروكسي فبيجوا يقولون one
+
+80
+00:07:19,600 --> 00:07:26,660
+hydroxybutanol طبعا إذا التقت ال CWO مع ال OH خلاص
+
+81
+00:07:26,660 --> 00:07:33,030
+أصبحت المجموعة الوظيفية هي هذه كاملةو كلها كاملة
+
+82
+00:07:33,030 --> 00:07:37,170
+بتعطي نهاية ايش اوك اسد لما اجي اقول واحد اتنين
+
+83
+00:07:37,170 --> 00:07:40,250
+تلاتة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+84
+00:07:40,250 --> 00:07:46,130
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+85
+00:07:46,130 --> 00:07:51,210
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+86
+00:07:51,210 --> 00:07:52,450
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+87
+00:07:52,450 --> 00:07:53,030
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+88
+00:07:53,030 --> 00:07:53,550
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+89
+00:07:53,550 --> 00:07:56,910
+اربعة اربعة اربعة اربعة اربعة اربعة اربEthyl to
+
+90
+00:07:56,910 --> 00:08:02,530
+Ethyl butanoic acid هنا مثلا بالزويك أسد حامل
+
+91
+00:08:02,530 --> 00:08:07,890
+الكلور علىال بارا position أو ال four position مر
+
+92
+00:08:07,890 --> 00:08:12,870
+علينا مثل هذا المركب لحظو هنا عندنا مجموعة وظيفية
+
+93
+00:08:12,870 --> 00:08:18,110
+واحدة اللي هي مجموعة الاش ال acid لكن لو انتقل ال
+
+94
+00:08:18,110 --> 00:08:21,430
+acid مع ال الديهايد او ال كيتون او كذا مين اللي
+
+95
+00:08:21,430 --> 00:08:25,630
+الاولوية ال acid اعلى من ال الديهايد اعلى من ال
+
+96
+00:08:25,630 --> 00:08:31,430
+كيتون اعلى من ال alcohol كل شيء هينسبلهالان لو يا
+
+97
+00:08:31,430 --> 00:08:37,270
+ترى كان عندى اكثر من acid لو كان عندى اكثر من acid
+
+98
+00:08:37,270 --> 00:08:41,790
+ممكن على السلسلة على الطرفين يكون على هذا الطرف
+
+99
+00:08:41,790 --> 00:08:46,230
+مجموعة acid وعلى هذا الطرف مجموعة acid واضح؟ ممكن
+
+100
+00:08:46,230 --> 00:08:52,770
+يكون اكثر من مجموعتين كمان اكيد لو كان عندى تفرعات
+
+101
+00:08:52,770 --> 00:08:57,590
+يعني لو كان عندى مثل هذا مثل هذه السلسلة ممكن
+
+102
+00:08:57,590 --> 00:09:04,870
+احطها لمجموعة acidc double bond o o h ممكن احط هنا
+
+103
+00:09:04,870 --> 00:09:11,170
+مجموعة acid ممكن احط هنا مجموعة acid واضح يعني
+
+104
+00:09:11,170 --> 00:09:16,150
+ممكن مجموعة مجموعتين تلاتة اربعة لو صار عندى
+
+105
+00:09:16,150 --> 00:09:20,550
+تفارعات كله وارد طب الآن لما بيصير عندى اكثر من
+
+106
+00:09:20,550 --> 00:09:26,750
+مجموعة ايش بدي اسمه بدل ما بدي اقول awake لما
+
+107
+00:09:26,750 --> 00:09:35,110
+يصيروا تنتين die awakeDioic acid فهنا لما يكونوا
+
+108
+00:09:35,110 --> 00:09:38,510
+carbon 2 هل ممكن ع carbon واحدة نحط two acids
+
+109
+00:09:38,510 --> 00:09:46,230
+مستحيل فأبسط حامض diacid هو اللي ع carbon 2 بيكون
+
+110
+00:09:46,230 --> 00:09:52,250
+اسمه ethanedioic acid ethanedioic acid هذا ماخد
+
+111
+00:09:52,250 --> 00:09:58,230
+اسم الشهرة oxalic acid لو صاروا تلاتةيعني هي ع
+
+112
+00:09:58,230 --> 00:10:03,710
+الطرف وع الطرف مجموعة حامض بيصير إيش بروبان ديويك
+
+113
+00:10:03,710 --> 00:10:08,690
+أسد ماخد اسم شورا مالونك أسد بعدين بيوتان ديويك
+
+114
+00:10:08,690 --> 00:10:14,940
+أسد ساكسينك بنتان هكسان هبتينDioic acid، glutaric،
+
+115
+00:10:14,940 --> 00:10:19,920
+adibic بملك، أسماء شهراء كثيرة موجودة، أقل تقدير
+
+116
+00:10:19,920 --> 00:10:23,980
+خلّينا نعرف ال aiobacnine، ال aiobacnine بستعمل
+
+117
+00:10:23,980 --> 00:10:30,960
+كلمة إيش؟ Dioic acid، بستعمل كلمة Dioic acid، و
+
+118
+00:10:30,960 --> 00:10:35,470
+أبسط Dioic acid زي ما قولنا إيش؟ال oxalic acid ..
+
+119
+00:10:35,470 --> 00:10:40,250
+ال oxalic acid كويس تعرفوه يعني طالما .. طالما
+
+120
+00:10:40,250 --> 00:10:47,010
+انتوا تحاليل طبية لما تبدأوا تدرسوا في ال urine في
+
+121
+00:10:47,010 --> 00:10:52,530
+ال bowl الأملاح وبعد هيك الأملاح هذه بدأت تعمل
+
+122
+00:10:52,530 --> 00:10:58,110
+حصوات في الكيليةهتلاحظوا ان جزء أساسي ان الحصوات
+
+123
+00:10:58,110 --> 00:11:03,550
+اما بده تكون صلبة جدا من ال oxalic acids او من ال
+
+124
+00:11:03,550 --> 00:11:08,850
+oxalic acid salts او من ال phosphates واضح فلما
+
+125
+00:11:08,850 --> 00:11:14,950
+نيجي نقول حصوات من ال oxalic acids او من ال salts
+
+126
+00:11:14,950 --> 00:11:21,180
+طبعا ال salt هيكون O minusالان هذه ال salts جزء من
+
+127
+00:11:21,180 --> 00:11:24,780
+أبيعمال حصواته و لذلك هتصيروا تقولوا oxalic acid
+
+128
+00:11:24,780 --> 00:11:29,760
+salts أملاح ال oxalic acid بتشوفوا بلوراتها تحت
+
+129
+00:11:29,760 --> 00:11:33,320
+الميكروسكوب فلما تكونوا تسمعوا oxalic acid و أنتوا
+
+130
+00:11:33,320 --> 00:11:37,160
+قاعدين بتحلله و بتحددوا شنوع الأملاح اللي عاملة
+
+131
+00:11:37,160 --> 00:11:42,100
+الحصوات و إشي أقل تقدير يضالوا في بالكوا انه مار
+
+132
+00:11:42,100 --> 00:11:49,980
+عليكم ال oxalic acid is a dyeواضح؟ من كم كربون؟ من
+
+133
+00:11:49,980 --> 00:11:56,060
+كربون تاني هنا
+
+134
+00:11:56,060 --> 00:12:01,260
+زى ما قلنا بيوتين ديويك أسد طيب لو صار عندى ال
+
+135
+00:12:01,260 --> 00:12:06,920
+triple bondلاحظوا هنا أصبح أكتر من مجموعة وظيفية
+
+136
+00:12:06,920 --> 00:12:12,120
+اويك أسد فى عندى منه تانين و triple bond اذا هنا
+
+137
+00:12:12,120 --> 00:12:17,640
+هنعد العدد لكل واحد اتنين تلاتة اربعة بيوتاين
+
+138
+00:12:17,640 --> 00:12:21,940
+دايويك أسد لاحظوا ان ال triple bond عبّرت عنها
+
+139
+00:12:21,940 --> 00:12:29,020
+بإيش ب I بيوتاين دايويك أسد طبعا لما بيكون عندى
+
+140
+00:12:29,020 --> 00:12:35,180
+triple bond مافيش عندى قصة إيشالسيس والترانس لانقص
+
+141
+00:12:35,180 --> 00:12:38,780
+السيس والترانس موجودة في ال double bonds او في
+
+142
+00:12:38,780 --> 00:12:44,740
+الحلقات وبناء على ذلك لو اتيت على بيوتين ديويك اسد
+
+143
+00:12:44,740 --> 00:12:50,120
+high carbon تنتين تلاتة اربعة اذا حطيت مجموعتين ال
+
+144
+00:12:50,120 --> 00:12:56,920
+acid على جهة واحدة هذا السيس واحد اتنين تلاتة
+
+145
+00:12:56,920 --> 00:13:02,180
+اربعة اتو بيوتين ديويك اسد ماخد اسم malic acid
+
+146
+00:13:02,830 --> 00:13:07,910
+ماليك لاحظوا ما بنقرأش مالك لأنه الملك أسد حامض
+
+147
+00:13:07,910 --> 00:13:19,010
+تاني بدون ال E ماليك هذه ال E تبعت ال الكيل ماليك
+
+148
+00:13:19,670 --> 00:13:24,190
+الـ E تبعت الالكيد الان لو هذول المجمعتين في ال
+
+149
+00:13:24,190 --> 00:13:28,790
+بيوتينويك أسد اجوا عكس بعض ال trans يعني كان
+
+150
+00:13:28,790 --> 00:13:31,830
+المركب واحد اتنين تلات اربع ال trans to
+
+151
+00:13:31,830 --> 00:13:37,370
+بيوتيندايويك أسد و اجت ايش بنسميه فيوماريك أسد
+
+152
+00:13:37,370 --> 00:13:41,890
+فيوماريك أسد هذه أحماض مشهورة المفروض تحفظوها يعني
+
+153
+00:13:41,890 --> 00:13:46,530
+لو قلنالكم ماليك أسد و فيوماريك أسد المفروض تكونوا
+
+154
+00:13:46,530 --> 00:13:51,620
+عارفين من فيهم السس الماليكمن ال Trans الفيومارك
+
+155
+00:13:51,620 --> 00:13:55,240
+واحد منهم بيجيبوه من التفاح والتاني بيجيبوه من
+
+156
+00:13:55,240 --> 00:14:01,140
+الحيوانات من الأغنام ويمكن عشان هيك لو بتطلعوا على
+
+157
+00:14:01,140 --> 00:14:07,080
+غلاف الكتاب غلاف كتاب heart بتلاحظوا في صورة تفاحة
+
+158
+00:14:07,080 --> 00:14:13,160
+خضرة اذا بعض الناس انتبهوا للغلاف هذا واحد من
+
+159
+00:14:13,160 --> 00:14:16,500
+الأحماض انسيت المليك او الفيومارك من التفاح
+
+160
+00:14:16,500 --> 00:14:22,180
+بتقولوا واضح؟الان لو يا ترى البنزينة كان عليها
+
+161
+00:14:22,180 --> 00:14:26,820
+اكثر من ascent يعني
+
+162
+00:14:26,820 --> 00:14:32,240
+die ascent كام احتمال ممكن يكون ممكن اتنين يكونوا
+
+163
+00:14:32,240 --> 00:14:36,460
+جانب بعض يعني one two die substituted بنزين ممكن
+
+164
+00:14:36,460 --> 00:14:39,820
+يكونوا واحد اتنين تلاتة وممكن يكونوا واحد اتنين
+
+165
+00:14:39,820 --> 00:14:44,200
+تلاتة اربعة اذا المجموعتين حامض على البنزينة ممكن
+
+166
+00:14:44,200 --> 00:14:49,390
+تكون علاقة بينهم one twoاو one three او one four
+
+167
+00:14:49,390 --> 00:14:54,970
+الان كل واحد من هدوله له اسم ال one two بنسميه
+
+168
+00:14:54,970 --> 00:14:59,450
+ifthalic acid و ال one three isophthalic acid و ال
+
+169
+00:14:59,450 --> 00:15:04,470
+one four teraphthalic acid اقل تقدير بدكوا تحفظه
+
+170
+00:15:04,470 --> 00:15:09,790
+لانه يعود يتكرر معنا ال ifthalic acidواضح؟ لأنه
+
+171
+00:15:09,790 --> 00:15:13,250
+منه هنعمل phthalic anhydride المليك أسد منه هنعمل
+
+172
+00:15:13,250 --> 00:15:17,530
+مليك أنهيدريد يعني هيعود مر معنى لما ندرس
+
+173
+00:15:17,530 --> 00:15:21,810
+الانهيدريد مليك أنهيدريد و phthalic anhydride
+
+174
+00:15:21,810 --> 00:15:26,570
+فالمليك أسد الأربعة اللي فيهم دابل بوند و سيس
+
+175
+00:15:26,570 --> 00:15:32,270
+الفثالك أسد داي أسد على البنزين أورثو جايين
+
+176
+00:15:32,270 --> 00:15:35,630
+المجموعتين to each other يعني العلاقة بينهم one
+
+177
+00:15:35,630 --> 00:15:42,670
+twoالان ال physical properties of carboxylic acids
+
+178
+00:15:42,670 --> 00:15:50,310
+الكلام يشبه الكحولات لكن خلنا نقول يعني في
+
+179
+00:15:50,310 --> 00:15:53,990
+hydrogen bonding في ال acids ال hydrogen bonding
+
+180
+00:15:53,990 --> 00:15:57,990
+في ال acids بيعمل solubility in water لكن بيضل
+
+181
+00:15:57,990 --> 00:16:05,090
+بشكل عام ان الحامض هو عبارة عن R وC double bond O
+
+182
+00:16:06,090 --> 00:16:12,950
+OH بمعنى زي ما كان الكحول ايش كان الكحول خلينا
+
+183
+00:16:12,950 --> 00:16:19,170
+نقول CH2OH الآن في الكحول اتفقنا انه في جزء polar
+
+184
+00:16:19,170 --> 00:16:24,990
+و في جزء non polar الآن الحامض نفس الاشي جزء polar
+
+185
+00:16:24,990 --> 00:16:31,760
+و جزء non polarnon-polar اللي هي ال R و لذلك لو
+
+186
+00:16:31,760 --> 00:16:35,600
+اجيلا نحكي عن ال solubility in water ال solubility
+
+187
+00:16:35,600 --> 00:16:39,160
+in water بنقول ان ال low alcohols are water
+
+188
+00:16:39,160 --> 00:16:43,260
+soluble كل ما ال R كبرت بتقلل ال solubility الان
+
+189
+00:16:43,260 --> 00:16:48,700
+نفس الجملة بنكررها ال low acids are water soluble
+
+190
+00:16:48,700 --> 00:16:51,620
+معناه low acids يعني اللي فيهم ال R صغيرة كربونا
+
+191
+00:16:51,620 --> 00:16:55,380
+تنتين تلاتة هدول بيدوبوا في الميه يعني مثلا ال
+
+192
+00:16:55,380 --> 00:17:00,290
+acetic acid كام كربونا بالمجملتلتين ال .. ال
+
+193
+00:17:00,290 --> 00:17:05,290
+acetic acid الخل بدوب في الميه عمرا واحد عملة مخلل
+
+194
+00:17:05,290 --> 00:17:11,310
+مش بتحطوا شوية خل عليها هو ال acetic acid حتى الخل
+
+195
+00:17:11,310 --> 00:17:14,870
+اللي بتشتريوه من السوق هو عبارة عن ال acetic acid
+
+196
+00:17:14,870 --> 00:17:20,710
+مدوب في الميه بنسبة بسيطة 4-5% واضح؟ فبنقول احنا
+
+197
+00:17:20,710 --> 00:17:25,610
+ان ال acids و ال alcohols both are polarو بناء على
+
+198
+00:17:25,610 --> 00:17:28,770
+ذلك الـ low acids and low alcohols are water
+
+199
+00:17:28,770 --> 00:17:32,850
+soluble كلما ال chain كبرت كلما ال solubility
+
+200
+00:17:32,850 --> 00:17:38,710
+اشمالها بتقل الان وجود ال OH بتعمل hydrogen
+
+201
+00:17:38,710 --> 00:17:43,630
+bonding وبناء على ذلك الأحماض والكحولات بشكل عام
+
+202
+00:17:43,630 --> 00:17:48,630
+نقاط غليانهم اشمالها مرتفعة لأن هان و هان في عنده
+
+203
+00:17:49,330 --> 00:17:53,990
+hydrogen bonding يعني تطلعوا انتوا مثلا ال acetic
+
+204
+00:17:53,990 --> 00:17:59,490
+acid كربونتين ال boiling point تبعته كده؟ مية و
+
+205
+00:17:59,490 --> 00:18:05,030
+تمانتاش عالية جدا ال ethanol كان تمانية و سبعين ال
+
+206
+00:18:05,030 --> 00:18:07,750
+probionic acid مية و واحد و اربعين ال butanoic
+
+207
+00:18:07,750 --> 00:18:11,290
+acid مية و اربعة و ستين بعد هيك الأحماض بتبدأ
+
+208
+00:18:11,290 --> 00:18:17,410
+تقترب تصير solidواضح الفكرة فالارتفاع في ال
+
+209
+00:18:17,410 --> 00:18:21,230
+boiling point النسبي و اكيد في ال melting point هو
+
+210
+00:18:21,230 --> 00:18:28,130
+سببه ال hydrogen bonding الان بتجينا صفة تانية
+
+211
+00:18:28,130 --> 00:18:34,050
+اللي هي ال acidity ال acidity متعلقة بإيش؟بال اتش
+
+212
+00:18:34,050 --> 00:18:38,190
+الموجودة على ال oxygen يعني هذه الاتش انها تفقد
+
+213
+00:18:38,190 --> 00:18:42,150
+ويتكون هنا عندي ايون سالم او تفقد هنا ويتكون عندي
+
+214
+00:18:42,150 --> 00:18:46,350
+هنا ايون سالم قلنا احنا ان ال alcohols they are in
+
+215
+00:18:46,350 --> 00:18:52,150
+general acidic و ال carboxylic acid acidic لكن جدش
+
+216
+00:18:52,150 --> 00:18:56,850
+ال bk ايه لل alcohol اذا انتم متذكرين تقريبا ال
+
+217
+00:18:56,850 --> 00:19:01,970
+alcohols العادية مثانول اثانولكانت خمس طائش، ست
+
+218
+00:19:01,970 --> 00:19:07,790
+طائش، الآن ال carboxylic acids أقوى كتير ال BKA
+
+219
+00:19:07,790 --> 00:19:12,770
+تبعتهم حوالي أربع على خمسة مين أقوى كتير ال
+
+220
+00:19:12,770 --> 00:19:16,430
+carboxylic acids ولا الكحولات المناظرة أو الكحولات
+
+221
+00:19:16,430 --> 00:19:22,410
+بشكل عام؟ ال carboxylic acids، إيش السبب؟ حكيناها
+
+222
+00:19:25,810 --> 00:19:29,770
+الـ H فقدت الله يرحمها، ضال الايون السالب لما
+
+223
+00:19:29,770 --> 00:19:33,710
+اتكلمنا عن ال acidity of acids قلنا بدنا ننظر
+
+224
+00:19:33,710 --> 00:19:39,510
+لثبات الايون السالب ال resonance هنا في resonance
+
+225
+00:19:39,510 --> 00:19:45,620
+مش هذا السالب ممكن يكون هناأه إذا ال acids they
+
+226
+00:19:45,620 --> 00:19:49,820
+are more acidic than alcohols or they have a lower
+
+227
+00:19:49,820 --> 00:19:55,460
+pka because of resonance ال charge in alcohol is
+
+228
+00:19:55,460 --> 00:20:01,940
+ايش وصفناها ثابتة في محلها مابتتنقلش حد يقوللي شو
+
+229
+00:20:01,940 --> 00:20:04,720
+الكلمة اللي استعملناها لهذه الشحنة اللي ثابتة في
+
+230
+00:20:04,720 --> 00:20:09,640
+محلها مابتتنقل لاحظوا اللي مابدرسوش مابحفظوش
+
+231
+00:20:09,640 --> 00:20:15,140
+المصطلحات localizedin its location ايش يعني
+
+232
+00:20:15,140 --> 00:20:20,420
+location في موقعها localized يعني ثابتة بموقعها
+
+233
+00:20:20,420 --> 00:20:26,470
+متمركزة localizedجاعدة بمحلة الانهاد اللي جاعدة
+
+234
+00:20:26,470 --> 00:20:31,970
+بتتنجل مرة هان و مرة هان و يعملالها resonance إيش
+
+235
+00:20:31,970 --> 00:20:39,450
+بنسميها؟ delocalized مرة هان و مرة هان و مرة هان و
+
+236
+00:20:39,450 --> 00:20:44,570
+مرة هان واضح؟ إذا وين ال charge localized و وين ال
+
+237
+00:20:44,570 --> 00:20:49,330
+delocalized؟localized في ال alcohols لأن مافيش
+
+238
+00:20:49,330 --> 00:20:53,570
+فيهم resonance delocalized قاعدة بتنقل شمال ويمين
+
+239
+00:20:53,570 --> 00:20:58,350
+في ال carboxylic acids لأن في جنبها C double bond
+
+240
+00:20:58,350 --> 00:21:04,130
+O فممكن يتم انتقال ال bond و الشحنة مرة بتكون هنا
+
+241
+00:21:04,130 --> 00:21:07,890
+و مرة بتكون هنا انا بتقول كل هذا ال resonance سبق
+
+242
+00:21:07,890 --> 00:21:12,130
+ان اوضحناه بشكل كامل لما حكينا ال alcohol بحاجة
+
+243
+00:21:12,130 --> 00:21:17,400
+لإنكم تتبعوه فال resonance هو سببالحمضية الزايدة
+
+244
+00:21:17,400 --> 00:21:22,700
+للاسدس ولذلك الكربوكسليك اسدس الآن بنقدرش نسيبهم
+
+245
+00:21:22,700 --> 00:21:27,920
+ينكبوا على أيدنا يعني الكحولات ال BKA بتاعتهم 15
+
+246
+00:21:27,920 --> 00:21:31,280
+-16 زي الميه مش مشكلة لو اجوا على أيدنا و غسلنا
+
+247
+00:21:31,280 --> 00:21:36,100
+فيهم و بيوتلوا البكتيريا بس ماحدش عمره يجرب يغسل
+
+248
+00:21:36,100 --> 00:21:41,160
+بمحلول حتى كربوكسليك اسدس و لو بنسميها weakيعني في
+
+249
+00:21:41,160 --> 00:21:46,200
+نهاية أحمار ضعيفة بالنسبة لل HCl وبالنسبة لل H2SO4
+
+250
+00:21:46,200 --> 00:21:52,120
+لكن بتظهر أقوى كتير من الكحولات وبتظهر تحرق
+
+251
+00:21:52,120 --> 00:21:57,700
+الإيدين واضح؟ طيب
+
+252
+00:22:04,580 --> 00:22:08,520
+كل موضوع ال acidity و كتاب الثابت ال acidity و ما
+
+253
+00:22:08,520 --> 00:22:12,800
+إلى ذلك اتعلمناه و اننا نتطلع على ال BKA لاحظوا
+
+254
+00:22:12,800 --> 00:22:17,100
+لما نتطلع على ال BKA اتطلعوا مثلا ال formic acid
+
+255
+00:22:17,100 --> 00:22:20,560
+تلاتة و ستة ال acetic acid اربعة و سبعة ال
+
+256
+00:22:20,560 --> 00:22:24,480
+probionic acid اربعة و تمانية زي ما حكينا تقريبا
+
+257
+00:22:24,480 --> 00:22:29,740
+معظم هدول ال acids في منطقة ال ايش التلاتة اربعة
+
+258
+00:22:29,740 --> 00:22:35,390
+خمسةواضح؟ معظم هدول ال acid في 3,4,5 لاحظوا ال
+
+259
+00:22:35,390 --> 00:22:41,950
+alcohol عمل مقارنة هنا هاي كل ال acid تتطلع عليها
+
+260
+00:22:41,950 --> 00:22:49,750
+ال PKA تعتها قليلة 3,4 لكن ال phenol عشرة واخدنا
+
+261
+00:22:49,750 --> 00:22:53,790
+ليش ال phenol كانت ال acidity شوية مرتفعة تبعته
+
+262
+00:22:53,790 --> 00:22:59,460
+بسبب ال resonanceيا ريتنا خلناه في الامتحان
+
+263
+00:22:59,460 --> 00:23:05,440
+chapter 7 سبب ال resonance ال ethanol والميه
+
+264
+00:23:05,440 --> 00:23:14,240
+تقريبا ال BKA تبعهم زي بعض 16 15.5 منخفض الان في
+
+265
+00:23:14,240 --> 00:23:18,820
+جوا الأحماض او في جوا الكحولات لما نيجي نقول حامض
+
+266
+00:23:18,820 --> 00:23:25,950
+اقوى من حامضوقلنا بنفتش على السبب كام سبب طرحناهم
+
+267
+00:23:25,950 --> 00:23:32,650
+تلاتة يا ال resonance يا ال size يا ال inductive
+
+268
+00:23:32,650 --> 00:23:36,030
+effect الان تطلعوا هنا بتلاقوا هاي حامض سبحان الله
+
+269
+00:23:36,030 --> 00:23:42,590
+صار إيش ماله قوى أقوى كتير وهذا مشتاق من ال acetic
+
+270
+00:23:42,590 --> 00:23:50,360
+acid خلينا نرسمه هناسي دبل بوند او اتش اتراي كلور
+
+271
+00:23:50,360 --> 00:23:55,800
+و أسيتك أسل اه هذا أسيتك أسل حامل تلت مجموعات كلور
+
+272
+00:23:55,800 --> 00:23:59,440
+تخيلوا
+
+273
+00:23:59,440 --> 00:24:06,870
+انه لما بيصير ال ionization بتصير هذه O minusماذا
+
+274
+00:24:06,870 --> 00:24:11,930
+يحدث لدي هنا اي effect؟ Inductive effect ان هذه
+
+275
+00:24:11,930 --> 00:24:16,930
+الكلور تسحب جزء من الشحنة السالبة وهذه تسحب جزء من
+
+276
+00:24:16,930 --> 00:24:18,610
+الشحنة السالبة وهذه تسحب جزء من الشحنة السالبة هذا
+
+277
+00:24:18,610 --> 00:24:23,090
+ال effect Inductive فال Trichloroacetic acid is
+
+278
+00:24:23,090 --> 00:24:28,830
+stronger than اكيد ال Dichloro لاحظوا ال Dichloro
+
+279
+00:24:28,830 --> 00:24:37,560
+في تن تل بيسحبوا ال Trichloro الكلور واحدةالاسيتك
+
+280
+00:24:37,560 --> 00:24:43,220
+أسد مفيش عشان هيك شوفوا التدريج الاسيتك أسد ال PKA
+
+281
+00:24:43,220 --> 00:24:51,480
+74% لو حطينا له وان كلورين صار كداش 82 لو حطينا
+
+282
+00:24:51,480 --> 00:24:56,870
+تنتينواحد و تلاتة من عشرة لو حطينا تلاتة point
+
+283
+00:24:56,870 --> 00:25:01,030
+seven الكلام منطقي ولا لأ inductive effect بيزيد
+
+284
+00:25:01,030 --> 00:25:04,930
+اعلى اشي بيصير لما يكونوا تلاتة اقل لو كانوا تلتين
+
+285
+00:25:04,930 --> 00:25:09,470
+اقل لو كانوا واحدة كل هذا الكلام في تفصيل ال
+
+286
+00:25:09,470 --> 00:25:14,050
+acidity الحقيقة موازي تماما للكلام اللي انا اخدناه
+
+287
+00:25:14,680 --> 00:25:18,540
+في الكحولات موازي تماما للكلام اللي أخدناه في
+
+288
+00:25:18,540 --> 00:25:22,480
+الكحولات ال resonance effect و ال inductive effect
+
+289
+00:25:22,480 --> 00:25:28,800
+و طبعا لأن ال BKA عالية في نهاية الأحماض بتتفاعل
+
+290
+00:25:28,800 --> 00:25:37,130
+مع ال NiOH حمض زي قاعدة ملح زي دماغ واضح؟هي الحامض
+
+291
+00:25:37,130 --> 00:25:41,090
+زاد الاني و اتش ال او اتش مع ال اتش هتعمل H2O و
+
+292
+00:25:41,090 --> 00:25:46,130
+هيصير عندى ملح الحامض و اتعلمنا الاصل كيف بنسميهم
+
+293
+00:25:46,130 --> 00:25:53,310
+يعني لو بدنا ناخد كمثال حقيقي ال acetic acid لو
+
+294
+00:25:53,310 --> 00:25:57,510
+بدنا ناخد كمثال حقيقي اللى عادة بتعملوله titration
+
+295
+00:25:57,510 --> 00:26:06,280
+فى التجارب العملية اللى هوC H 3 C O O H زائد N A O
+
+296
+00:26:06,280 --> 00:26:13,580
+H مين اتنجلنا شو بدي اكتب المعادلة وقتها C H 3 C O
+
+297
+00:26:13,580 --> 00:26:25,460
+O O خلينا نقول هيك N A Plus زائد H 2 O الآن هذا
+
+298
+00:26:25,460 --> 00:26:27,900
+الناتج لما بدي اسميه كيف بسميه
+
+299
+00:26:33,060 --> 00:26:38,000
+صوديوم والمجموع اللى جاى من ال acetic acid اذا من
+
+300
+00:26:38,000 --> 00:26:43,560
+ال formic acid فورميت اذا من ال probionic acid
+
+301
+00:26:43,560 --> 00:26:48,220
+بروبانويت من ال butanoic acid بيوتانويت اذا
+
+302
+00:26:48,220 --> 00:26:52,360
+النهاية ات زى ما كنتوا تقولوا صلفيت و كربونيت و
+
+303
+00:26:52,360 --> 00:26:59,010
+نيتريت نهاية ات هي نهاية ال acid اذا صوديومacetate
+
+304
+00:26:59,010 --> 00:27:05,770
+فانا شيلت ال اك او ال او اك اسد و حطيت بدلها ايش
+
+305
+00:27:05,770 --> 00:27:11,880
+ات فال ات هذهنهاية الايون السالب Sodium Acetate
+
+306
+00:27:11,880 --> 00:27:16,340
+وسبق ان وضحنا لكم ايش معنى ال Acetyl group و ال
+
+307
+00:27:16,340 --> 00:27:20,180
+Acetate group و ال Acetic Acid قولنا لكم ان هذه
+
+308
+00:27:20,180 --> 00:27:25,700
+المجموعة لحالة شو اسمها AC Acetate لو حطينا لل O
+
+309
+00:27:25,700 --> 00:27:32,030
+صارت Acetate لو حطينا لل Hأسيتك أسد فالأسيتك أسد
+
+310
+00:27:32,030 --> 00:27:41,030
+اختصارا a-c-o-h واضح أسيتل أسيتيت مع الأكسجين
+
+311
+00:27:41,030 --> 00:27:42,330
+أسيتك أسد
+
+312
+00:28:02,030 --> 00:28:03,610
+اشمع له الجهاز
+
+313
+00:28:28,050 --> 00:28:34,830
+كيف بنحضر ال carboxylic acids زي ما بتلاحظوا في
+
+314
+00:28:34,830 --> 00:28:40,830
+عندنا مجموعة كبيرة من الطرق لتحضير ال carboxylic
+
+315
+00:28:40,830 --> 00:28:46,910
+acids ممكن نبدأ نستعرض بعضها الحقيقة البعض منها مر
+
+316
+00:28:46,910 --> 00:28:53,000
+علينا البعض منها مر علينا وبعضهاعبارة عن أشياء
+
+317
+00:28:53,000 --> 00:28:57,720
+جديدة اليوم احنا بناخد الشغلتين الخفاف اللي مروا
+
+318
+00:28:57,720 --> 00:29:02,000
+علينا و الأشياء الجديدة بنسيبهم للمرة القادمة
+
+319
+00:29:02,000 --> 00:29:06,780
+الشغلتين اللي مروا علينا لما أخدنا أكسدة ال
+
+320
+00:29:06,780 --> 00:29:13,540
+primary alcohols مين تذكرني إياها بجملة بسيطة جدا؟
+
+321
+00:29:13,540 --> 00:29:19,870
+إيش حكينا في أكسدة ال primary alcohols؟قلنا اكسدت
+
+322
+00:29:19,870 --> 00:29:24,790
+ال primary alcohol بعمل مؤكسد خفيف بتعطيني ال
+
+323
+00:29:24,790 --> 00:29:30,330
+aldehyde واضح شو العمل المؤكسد الخفيف اللي بيحول
+
+324
+00:29:30,330 --> 00:29:36,310
+ال primary alcohol ل aldehyde بي سي سي الان طيب لو
+
+325
+00:29:36,310 --> 00:29:45,200
+ال primary alcohol استعملتله عامل مؤكسد قويبتحول ل
+
+326
+00:29:45,200 --> 00:29:48,540
+الديهايد و بيضلوا ماشي عدل ل ايش ل carboxylic
+
+327
+00:29:48,540 --> 00:29:52,420
+acids اذا ممكن انا اتحرك من ال primary alcohol ل
+
+328
+00:29:52,420 --> 00:29:57,960
+carboxylic acid باستعمال اي عامل مؤكسد كيامان او
+
+329
+00:29:57,960 --> 00:30:00,300
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+330
+00:30:00,300 --> 00:30:00,880
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+331
+00:30:00,880 --> 00:30:01,180
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+332
+00:30:01,180 --> 00:30:01,660
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+333
+00:30:01,660 --> 00:30:08,120
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+334
+00:30:08,120 --> 00:30:14,380
+فور و كيامان او فور و كيامان ابيصيروا alcohol
+
+335
+00:30:14,380 --> 00:30:18,360
+مباشرة طبعا اكيد مرورا بال الديهيدز الان في شبطر
+
+336
+00:30:18,360 --> 00:30:23,960
+ال الديهيدز و ال ketones اخدنا ان ال الديهيدز ايضا
+
+337
+00:30:23,960 --> 00:30:32,190
+بتأكسد لاش ل acids و ال ketones بتأكسدوشواضح؟
+
+338
+00:30:32,190 --> 00:30:37,030
+لاحظوا الخطأ الشائع بهمش .. خلّي كل العالم يسمع
+
+339
+00:30:37,030 --> 00:30:40,930
+الخطأ الشائع عند الطلاب أنه يوما بلتهيوا بامتحان
+
+340
+00:30:40,930 --> 00:30:44,950
+بنسوا المواد التانية و لذلك بنصير إحنا نحكي معهم و
+
+341
+00:30:44,950 --> 00:30:49,970
+هم خارج ال rhythm تماما يعني أكسدت ال aldehydes ل
+
+342
+00:30:49,970 --> 00:30:53,010
+carboxylic acids في المحاضرة السابقة هذه من
+
+343
+00:30:53,010 --> 00:30:56,110
+الأخطاء الشائعة اللي بيرتكبوها الطلاب أنه بيضالوا
+
+344
+00:30:56,110 --> 00:31:01,240
+يحطوا شغلة بدل شغلة مافيش عندهم اتزانفي الدراسة من
+
+345
+00:31:01,240 --> 00:31:06,060
+البداية يعني بيموتوا مادة او مادتيلة مدة اسبوعين و
+
+346
+00:31:06,060 --> 00:31:09,920
+بيغيبوا عن محاضراتها و بيلتهيوا لمادة الامتحان
+
+347
+00:31:09,920 --> 00:31:13,300
+عملوها بيجوا بيلاجوا عندهم مشكلة في المادة التانية
+
+348
+00:31:13,300 --> 00:31:18,720
+و هكذا دائما حافظوا على انه تظلوا متزينين في جميع
+
+349
+00:31:18,720 --> 00:31:22,900
+المواد يعني بيزعل المدرس لما ييجي يحكيلكوا انه
+
+350
+00:31:22,900 --> 00:31:26,080
+اكسدت ال primary alcohols ل acids و اكسدت ال
+
+351
+00:31:26,080 --> 00:31:30,660
+aldehydes ل acidsو تعب كتير في الكلام و يلاقي أنكم
+
+352
+00:31:30,660 --> 00:31:35,760
+مش متفاعلين طبعا ليش أنا نوّهت لهذا الكلام لأن
+
+353
+00:31:35,760 --> 00:31:39,720
+انتوا في النهاية لسه سنة أولى طبيعة الحياة أنه
+
+354
+00:31:39,720 --> 00:31:46,960
+هيطلب منكم عشر شغلات في يوم واحد الآن مش ممكن أن
+
+355
+00:31:46,960 --> 00:31:52,430
+البني آدم يعيش و هو بيموت شغلة على حساب شغلةلازم
+
+356
+00:31:52,430 --> 00:31:56,590
+يعمل كل شيء يعني طبيعة الحياة بعد شوية أنه بده
+
+357
+00:31:56,590 --> 00:32:02,630
+يكون عندكم عمل بدكم تعمله طفل بدكم اتربيه بيت بدكم
+
+358
+00:32:02,630 --> 00:32:06,570
+تديروا بالك عليه زوج بدكم تديروا بالك عليه الآن
+
+359
+00:32:06,570 --> 00:32:10,550
+اتخيلوا لو واحدة من هذه الأربعة طغت على التانية
+
+360
+00:32:10,550 --> 00:32:14,370
+فقط فكرتوا بالعمل الولد الصغير بيسخن و بيموت و
+
+361
+00:32:14,370 --> 00:32:18,330
+أنتم مش دارين على حالكم فقط فكرتوا بالولد الصغير
+
+362
+00:32:19,120 --> 00:32:23,340
+الجوز بيبطل عنكوا وانتوا مش دارين عن حالكوا ولذلك
+
+363
+00:32:23,340 --> 00:32:28,320
+لما تكتر الأعمال عند الإنسان من الأخطاء الشائعة
+
+364
+00:32:28,320 --> 00:32:34,910
+جدا انه يقوم بعمل ويهمل تلت أعمالاليوم في الحياة
+
+365
+00:32:34,910 --> 00:32:40,870
+العملية الجواب لأ لازم تجوم بكل الأعمال و تقسم
+
+366
+00:32:40,870 --> 00:32:45,570
+وقتك على كل الأعمال و كذلك انتوا كطلاب لازم تدرسوا
+
+367
+00:32:45,570 --> 00:32:49,730
+لكل المواد مش اذا اجاكوا امتحان اتحدد بعد أسبوعين
+
+368
+00:32:49,730 --> 00:32:53,590
+ع مدى الأسبوعين بندرس للامتحان و بنغيب عن المواد و
+
+369
+00:32:53,590 --> 00:33:00,740
+مابنفتحاش و بتضل ايشيصير عندكم التراكم هذه نصيحة
+
+370
+00:33:00,740 --> 00:33:05,180
+جيد مش بس انتوا تسمعوها وكمان الناس اللي بيحضروا
+
+371
+00:33:05,180 --> 00:33:10,300
+المحاضرات حتى لو كانوا من خارج الجامعة يسمعوا هذا
+
+372
+00:33:10,300 --> 00:33:15,540
+الكلام انه الإنسان أعماله كثيرة لازم يوازن بين
+
+373
+00:33:15,540 --> 00:33:21,600
+أعماله بس مش صح اطلاقا انه يعمل عمل على حساب عمل
+
+374
+00:33:21,600 --> 00:33:27,400
+ابهيك بنكون أخدنا طريقتين لتحضيرالاحماد من
+
+375
+00:33:27,400 --> 00:33:30,980
+الكحولات و من ال الدي هايتز في طرق ثانية ان شاء
+
+376
+00:33:30,980 --> 00:33:34,840
+الله المرة القادمة بنكمل فيها و بننهي لحد ذلك
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..24f87d661cfc52e7037ffd82aaf3ae6e0264bcb8
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4056, "start": 18.36, "end": 40.56, "text": "بسم الله الرحمن الرحيم المرة الماضية بدنا نتكلم في موضوع البروتينات وكان الأساس ان نتعرف على الأحماض الأمينية ال amino acids اتعرفنا عليهم و اتعرفنا طبعا كيف بيكونوا بالوسط الحامض أو القاعدى كيف بتتأثر الشحنة تبعتهم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 8315, 8717, 2655, 4117, 19528, 8978, 3714, 2407, 11242, 45367, 2423, 26890, 35473, 9957, 9307, 4032, 41361, 16247, 3794, 32277, 16472, 8717, 2655, 3615, 28480, 15844, 16247, 35571, 46958, 16247, 2304, 9957, 10632, 2423, 24674, 21667, 1975, 2655, 3615, 28480, 8315, 25894, 16095, 4032, 1975, 2655, 3615, 28480, 8315, 23032, 3555, 3615, 995, 9122, 33911, 4724, 1829, 30544, 14407, 20666, 41779, 9566, 21542, 10943, 11242, 34051, 25062, 995, 22488, 7578, 9122, 33911, 39894, 2655, 10721, 49115, 25124, 5016, 1863, 3660, 6055, 3555, 34268, 16095], "avg_logprob": -0.09726562812924384, 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25.2, "end": 26.48, "word": " وكان", "probability": 0.82421875}, {"start": 26.48, "end": 27.28, "word": " الأساس", "probability": 0.9339192708333334}, {"start": 27.28, "end": 28.1, "word": " ان", "probability": 0.43212890625}, {"start": 28.1, "end": 28.72, "word": " نتعرف", "probability": 0.8919677734375}, {"start": 28.72, "end": 29.04, "word": " على", "probability": 0.88623046875}, {"start": 29.04, "end": 29.78, "word": " الأحماض", "probability": 0.927734375}, {"start": 29.78, "end": 30.38, "word": " الأمينية", "probability": 0.9447021484375}, {"start": 30.38, "end": 30.5, "word": " ال", "probability": 0.93359375}, {"start": 30.5, "end": 30.84, "word": " amino", "probability": 0.828125}, {"start": 30.84, "end": 31.46, "word": " acids", "probability": 0.86962890625}, {"start": 31.46, "end": 32.7, "word": " اتعرفنا", "probability": 0.91640625}, {"start": 32.7, "end": 33.24, "word": " عليهم", "probability": 0.785888671875}, {"start": 33.24, "end": 33.58, "word": " و", "probability": 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"probability": 0.9236653645833334}], "temperature": 1.0}, {"id": 14, "seek": 35832, "start": 330.38, "end": 358.32, "text": "واضح فلما نقول ال peptide bond هي حقيقة ال amide bond واضح لكن لأنه انا لما بفعل two amino acids او three amino acids بكون ايش؟ peptide و لو كبروا كتير بصيروا ايش؟ protein واضح فال peptides و ال proteins فيهم ال amide bond واضح او بنسميها في هذه الحالة تخصيصا", "tokens": [2407, 46958, 5016, 6156, 1211, 15042, 8717, 39648, 2423, 41781, 482, 6086, 39896, 11331, 38436, 28671, 2423, 669, 482, 6086, 4032, 46958, 5016, 44381, 5296, 33456, 3224, 1975, 8315, 5296, 15042, 4724, 5172, 30241, 732, 24674, 21667, 1975, 2407, 1045, 24674, 21667, 4724, 30544, 1975, 1829, 8592, 22807, 41781, 482, 4032, 45164, 9122, 26890, 14407, 9122, 2655, 13546, 4724, 9381, 13546, 14407, 1975, 1829, 8592, 22807, 7944, 4032, 46958, 5016, 6156, 6027, 41781, 1875, 4032, 2423, 15577, 8978, 16095, 2423, 669, 482, 6086, 4032, 46958, 5016, 1975, 2407, 44945, 38251, 1829, 11296, 8978, 29538, 21542, 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0.87158203125}, {"start": 350.18, "end": 351.16, "word": " فال", "probability": 0.855224609375}, {"start": 351.16, "end": 351.78, "word": " peptides", "probability": 0.885986328125}, {"start": 351.78, "end": 352.0, "word": " و", "probability": 0.8212890625}, {"start": 352.0, "end": 352.08, "word": " ال", "probability": 0.93798828125}, {"start": 352.08, "end": 352.66, "word": " proteins", "probability": 0.96923828125}, {"start": 352.66, "end": 353.04, "word": " فيهم", "probability": 0.959716796875}, {"start": 353.04, "end": 353.2, "word": " ال", "probability": 0.923828125}, {"start": 353.2, "end": 353.58, "word": " amide", "probability": 0.90185546875}, {"start": 353.58, "end": 354.06, "word": " bond", "probability": 0.923828125}, {"start": 354.06, "end": 354.96, "word": " واضح", "probability": 0.8811848958333334}, {"start": 354.96, "end": 355.88, "word": " او", "probability": 0.864013671875}, {"start": 355.88, "end": 356.72, "word": " بنسميها", "probability": 0.967041015625}, {"start": 356.72, "end": 356.88, "word": " في", "probability": 0.8671875}, {"start": 356.88, "end": 357.06, "word": " هذه", "probability": 0.947265625}, {"start": 357.06, "end": 357.46, "word": " الحالة", "probability": 0.9890950520833334}, {"start": 357.46, "end": 358.32, "word": " تخصيصا", "probability": 0.9881184895833334}], "temperature": 1.0}, {"id": 15, "seek": 38717, "start": 359.05, "end": 387.17, "text": "ببتايت بوند فلو قلنا مثلا سؤال ببتايت بوند is an amide bond طبعا هي امد see double bond O and H طبعا هيكون فيها كل خواص الامدز انه هتكون هذه المنطقة كامد reactive ولا unreactive unreactive احنا قلنا الكلمة الأساسية المميزة للامدز they are unreactive", "tokens": [3555, 3555, 2655, 995, 36081, 4724, 11536, 3215, 6156, 1211, 2407, 12174, 1211, 8315, 50113, 15040, 8608, 33604, 6027, 4724, 3555, 2655, 995, 36081, 4724, 11536, 3215, 307, 364, 669, 482, 6086, 23032, 3555, 3615, 995, 39896, 1975, 2304, 3215, 536, 3834, 6086, 422, 293, 389, 23032, 3555, 3615, 995, 39896, 30544, 8978, 11296, 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"probability": 0.87216796875}, {"start": 362.47, "end": 362.91, "word": " بوند", "probability": 0.9435221354166666}, {"start": 362.91, "end": 363.23, "word": " is", "probability": 0.7919921875}, {"start": 363.23, "end": 363.61, "word": " an", "probability": 0.869140625}, {"start": 363.61, "end": 363.97, "word": " amide", "probability": 0.72705078125}, {"start": 363.97, "end": 364.37, "word": " bond", "probability": 0.93603515625}, {"start": 364.37, "end": 365.13, "word": " طبعا", "probability": 0.93896484375}, {"start": 365.13, "end": 365.29, "word": " هي", "probability": 0.76220703125}, {"start": 365.29, "end": 365.61, "word": " امد", "probability": 0.6809895833333334}, {"start": 365.61, "end": 365.81, "word": " see", "probability": 0.1768798828125}, {"start": 365.81, "end": 366.01, "word": " double", "probability": 0.437744140625}, {"start": 366.01, "end": 366.33, "word": " bond", "probability": 0.875}, {"start": 366.33, "end": 366.69, "word": " O", "probability": 0.331298828125}, {"start": 366.69, "end": 367.53, "word": " and", "probability": 0.55908203125}, {"start": 367.53, "end": 367.83, "word": " H", "probability": 0.447509765625}, {"start": 367.83, "end": 368.55, "word": " طبعا", "probability": 0.9649658203125}, {"start": 368.55, "end": 369.29, "word": " هيكون", "probability": 0.6929931640625}, {"start": 369.29, "end": 369.77, "word": " فيها", "probability": 0.978515625}, {"start": 369.77, "end": 370.19, "word": " كل", "probability": 0.9833984375}, {"start": 370.19, "end": 370.95, "word": " خواص", "probability": 0.84326171875}, {"start": 370.95, "end": 372.11, "word": " الامدز", "probability": 0.818359375}, {"start": 372.11, "end": 372.57, "word": " انه", "probability": 0.689697265625}, {"start": 372.57, "end": 373.09, "word": " هتكون", "probability": 0.91162109375}, {"start": 373.09, "end": 373.53, "word": " هذه", "probability": 0.61669921875}, {"start": 373.53, "end": 375.19, "word": " المنطقة", "probability": 0.80145263671875}, {"start": 375.19, "end": 375.77, "word": " كامد", "probability": 0.9404296875}, {"start": 375.77, "end": 376.99, "word": " reactive", "probability": 0.1517333984375}, {"start": 376.99, "end": 377.41, "word": " ولا", "probability": 0.88818359375}, {"start": 377.41, "end": 378.49, "word": " unreactive", "probability": 0.952880859375}, {"start": 378.49, "end": 380.53, "word": " unreactive", "probability": 0.59619140625}, {"start": 380.53, "end": 381.27, "word": " احنا", "probability": 0.9241536458333334}, {"start": 381.27, "end": 381.63, "word": " قلنا", "probability": 0.9676106770833334}, {"start": 381.63, "end": 382.13, "word": " الكلمة", "probability": 0.9044596354166666}, {"start": 382.13, "end": 382.89, "word": " الأساسية", "probability": 0.9368896484375}, {"start": 382.89, "end": 383.85, "word": " المميزة", "probability": 0.989453125}, {"start": 383.85, "end": 384.77, "word": " للامدز", "probability": 0.9527587890625}, {"start": 384.77, "end": 385.33, "word": " they", "probability": 0.875}, {"start": 385.33, "end": 385.91, "word": " are", "probability": 0.96630859375}, {"start": 385.91, "end": 387.17, "word": " unreactive", "probability": 0.9521484375}], "temperature": 1.0}, {"id": 16, "seek": 39257, "start": 387.95, "end": 392.57, "text": "و بناء على ذلك حتى ال hydrolysis تبعهم بيكون سهل ولا صعب", "tokens": [2407, 44945, 16606, 15844, 29910, 23275, 11331, 49975, 2423, 15435, 356, 17122, 6055, 3555, 3615, 16095, 4724, 1829, 30544, 8608, 3224, 1211, 49429, 20328, 3615, 3555], "avg_logprob": -0.17939814373298926, "compression_ratio": 1.0224719101123596, "no_speech_prob": 0.0, "words": [{"start": 387.95, "end": 388.17, "word": "و", "probability": 0.428955078125}, {"start": 388.17, "end": 388.53, "word": " بناء", "probability": 0.9091796875}, {"start": 388.53, "end": 388.79, "word": " على", "probability": 0.67822265625}, {"start": 388.79, "end": 389.23, "word": " ذلك", "probability": 0.992431640625}, {"start": 389.23, "end": 389.57, "word": " حتى", "probability": 0.8466796875}, 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المتكررة", "tokens": [2407, 3224, 15730, 25724, 11622, 38207, 16247, 9778, 13546, 4724, 1829, 30544, 1975, 1829, 14709, 2423, 5954, 14709, 6156, 7649, 995, 5296, 15042, 4724, 16254, 1975, 25957, 1211, 41781, 482, 8608, 2407, 16606, 3714, 30544, 9154, 36764, 24401, 1975, 2407, 1975, 2655, 1863, 9957, 1975, 2407, 6055, 1211, 9307, 3660, 1975, 2407, 1975, 25513, 27884, 1975, 2407, 16490, 2304, 3794, 3660, 24674, 21667, 8608, 3224, 1211, 10874, 28259, 11203, 25528, 4724, 16254, 1975, 25957, 1211, 426, 14709, 4032, 4724, 16254, 1975, 25957, 1211, 383, 14709, 2423, 7649, 19446, 2423, 2407, 24401, 3660, 9673, 2655, 37983, 25720], "avg_logprob": -0.18218427835051546, "compression_ratio": 1.7227722772277227, "no_speech_prob": 0.0, "words": [{"start": 504.22, "end": 504.9, "word": "وهذا", "probability": 0.7513020833333334}, {"start": 504.9, "end": 505.36, "word": " الجزء", "probability": 0.9718424479166666}, {"start": 505.36, "end": 505.86, "word": " الأخير", "probability": 0.81982421875}, 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{"start": 677.23, "end": 677.99, "word": " CH،", "probability": 0.9228515625}, {"start": 677.99, "end": 678.13, "word": " إنه", "probability": 0.947265625}, {"start": 678.13, "end": 678.33, "word": " هذه", "probability": 0.93408203125}, {"start": 678.33, "end": 680.01, "word": " NH،", "probability": 0.916015625}, {"start": 680.01, "end": 680.27, "word": " هذه", "probability": 0.446533203125}, {"start": 680.27, "end": 680.89, "word": " CH", "probability": 0.970703125}], "temperature": 1.0}, {"id": 29, "seek": 68576, "start": 681.26, "end": 685.76, "text": "عشان يكتمل الشكل العام بتاع الـ OH", "tokens": [3615, 8592, 7649, 7251, 4117, 39237, 1211, 25124, 28820, 18863, 10943, 39894, 45761, 2423, 39184, 13931], "avg_logprob": -0.35546875, "compression_ratio": 1.0169491525423728, "no_speech_prob": 0.0, "words": [{"start": 681.26, "end": 681.72, "word": "عشان", "probability": 0.9217122395833334}, {"start": 681.72, "end": 682.98, "word": " يكتمل", "probability": 0.8670654296875}, {"start": 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إيش ال sequence لهم لابد من معرفة ال sequence إيش تسلسلهم الآن لو إجيت جبتلكوا سؤال مثلا قلتلكوا والله هذا ال peptide يجلسين قلانين سستين فين القلانين؟", "tokens": [3555, 6027, 497, 3935, 23032, 3555, 3615, 995, 23758, 2423, 47283, 2655, 15040, 5172, 4724, 1829, 9778, 20292, 2423, 41781, 1875, 4032, 2423, 15577, 19446, 1829, 30544, 2407, 8592, 6754, 18552, 11331, 38436, 38436, 9957, 5296, 16758, 3215, 9154, 20449, 28480, 3660, 11933, 1829, 8592, 2423, 8310, 5296, 16095, 5296, 16758, 3215, 9154, 20449, 28480, 3660, 2423, 8310, 11933, 1829, 8592, 6055, 3794, 1211, 3794, 1211, 16095, 6024, 48506, 45164, 11933, 7435, 36081, 10874, 3555, 2655, 23275, 14407, 8608, 33604, 6027, 50113, 15040, 12174, 1211, 2655, 23275, 14407, 16070, 43761, 23758, 2423, 41781, 482, 7251, 7435, 1211, 3794, 9957, 12174, 1211, 7649, 9957, 8608, 14851, 9957, 8978, 1863, 25062, 1211, 7649, 9957, 22807], "avg_logprob": -0.2150493367460736, "compression_ratio": 1.7521367521367521, "no_speech_prob": 0.0, "words": 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"word": " والله", "probability": 0.66845703125}, {"start": 738.25, "end": 738.67, "word": " هذا", "probability": 0.947265625}, {"start": 738.67, "end": 738.83, "word": " ال", "probability": 0.9853515625}, {"start": 738.83, "end": 739.29, "word": " peptide", "probability": 0.931640625}, {"start": 739.29, "end": 740.07, "word": " يجلسين", "probability": 0.57213134765625}, {"start": 740.07, "end": 740.57, "word": " قلانين", "probability": 0.71966552734375}, {"start": 740.57, "end": 741.13, "word": " سستين", "probability": 0.79052734375}, {"start": 741.13, "end": 741.93, "word": " فين", "probability": 0.85107421875}, {"start": 741.93, "end": 742.77, "word": " القلانين؟", "probability": 0.8896484375}], "temperature": 1.0}, {"id": 32, "seek": 76717, "start": 743.81, "end": 767.17, "text": "مع هذا الـpeptide جلبت أي شيء فيه ألانين إيجليسين سيستين فين الألانين؟ غيرت أي شيء ما العلاقة بينهم؟ they are structural isomers اختلفوا في مواقع الارتباط كانت هنا مثلا اللي فيها المثل أعلى تاني وحدة صارت اللي فيها المثل على الأولى و اللي فيها الأتش على التانية", "tokens": [2304, 3615, 23758, 2423, 39184, 494, 662, 482, 10874, 46152, 2655, 36632, 44049, 38207, 8978, 3224, 5551, 1211, 7649, 9957, 11933, 1829, 7435, 20292, 3794, 9957, 8608, 1829, 14851, 9957, 8978, 1863, 16247, 1211, 7649, 9957, 22807, 32771, 13546, 2655, 36632, 44049, 38207, 19446, 18863, 15040, 28671, 49374, 16095, 22807, 436, 366, 15067, 307, 298, 433, 1975, 46456, 46538, 14407, 8978, 3714, 14407, 4587, 3615, 2423, 9640, 2655, 3555, 41193, 25961, 2655, 34105, 50113, 15040, 13672, 1829, 8978, 11296, 9673, 12984, 1211, 5551, 3615, 23942, 6055, 7649, 1829, 4032, 24401, 3660, 20328, 9640, 2655, 13672, 1829, 8978, 11296, 9673, 12984, 1211, 15844, 16247, 12610, 7578, 4032, 13672, 1829, 8978, 11296, 16247, 2655, 8592, 15844, 16712, 7649, 10632], "avg_logprob": -0.20934851278187866, "compression_ratio": 1.8855932203389831, "no_speech_prob": 0.0, "words": [{"start": 743.81, "end": 744.33, "word": "مع", "probability": 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they are structural isomers هذه الـ N-terminal وهذه الـ C-terminal", "tokens": [3224, 15730, 6055, 17082, 13546, 8978, 2423, 9640, 2655, 3555, 41193, 49429, 5296, 10721, 22807, 1975, 15730, 436, 366, 15067, 307, 298, 433, 4032, 46958, 5016, 22807, 436, 366, 15067, 307, 298, 433, 29538, 2423, 39184, 426, 12, 7039, 2071, 37037, 24192, 2423, 39184, 383, 12, 7039, 2071], "avg_logprob": -0.3164859791191257, "compression_ratio": 1.416, "no_speech_prob": 0.0, "words": [{"start": 767.95, "end": 768.25, "word": "هذا", "probability": 0.83642578125}, {"start": 768.25, "end": 768.67, "word": " تغير", "probability": 0.9287109375}, {"start": 768.67, "end": 768.85, "word": " في", "probability": 0.9501953125}, {"start": 768.85, "end": 769.45, "word": " الارتباط", "probability": 0.9201171875}, {"start": 769.45, "end": 769.65, "word": " ولا", "probability": 0.6240234375}, {"start": 769.65, "end": 770.49, "word": " لأ؟", "probability": 0.67919921875}, {"start": 770.49, "end": 770.73, "word": " اذا", 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ether و تبعت ال anhydride symmetrical بفرق اش معها تيجي اي مجموعة على اليمين و على الاشمال يعني خلينا نشوف ال ether لو بده احط مثل و اثل", "tokens": [8592, 38688, 14407, 9673, 7435, 2304, 2407, 27884, 2423, 2407, 19913, 33911, 10632, 9673, 7435, 2304, 2407, 27884, 2423, 2407, 19913, 33911, 10632, 6055, 3555, 34268, 2423, 37096, 6055, 3555, 34268, 2423, 37096, 4032, 6055, 3555, 34268, 2423, 18931, 6655, 25502, 40360, 4724, 5172, 2288, 4587, 1975, 8592, 20449, 11296, 6055, 1829, 7435, 1829, 1975, 1829, 3714, 7435, 2304, 2407, 27884, 15844, 2423, 32640, 9957, 4032, 15844, 2423, 33599, 2304, 6027, 37495, 22653, 16490, 1211, 9957, 995, 8717, 8592, 38688, 2423, 37096, 45164, 47525, 3224, 1975, 5016, 9566, 50113, 1211, 4032, 1975, 12984, 1211], "avg_logprob": -0.21924341979779696, "compression_ratio": 1.8531073446327684, "no_speech_prob": 0.0, "words": [{"start": 1100.42, "end": 1101.48, "word": "شوفوا", "probability": 0.712890625}, {"start": 1101.48, "end": 1102.44, "word": " المجموعة", 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"probability": 0.9847005208333334}, {"start": 2285.53, "end": 2286.05, "word": " انه", "probability": 0.90869140625}, {"start": 2286.05, "end": 2286.59, "word": " صعب", "probability": 0.9908854166666666}, {"start": 2286.59, "end": 2286.75, "word": " في", "probability": 0.8720703125}, {"start": 2286.75, "end": 2287.09, "word": " نهاية", "probability": 0.9757486979166666}, {"start": 2287.09, "end": 2287.83, "word": " المحاضرة", "probability": 0.9814453125}, {"start": 2287.83, "end": 2288.45, "word": " ان", "probability": 0.7919921875}, {"start": 2288.45, "end": 2289.13, "word": " نبدأ", "probability": 0.85693359375}, {"start": 2289.13, "end": 2290.91, "word": " نحكي", "probability": 0.9771728515625}, {"start": 2290.91, "end": 2291.21, "word": " عن", "probability": 0.99169921875}, {"start": 2291.21, "end": 2291.83, "word": " ال", "probability": 0.96337890625}, {"start": 2291.83, "end": 2292.33, "word": " protein", "probability": 0.6005859375}, {"start": 2292.33, "end": 2292.85, "word": " وكيف", "probability": 0.8733723958333334}, {"start": 2292.85, "end": 2293.29, "word": " نعمل", "probability": 0.9890950520833334}, {"start": 2293.29, "end": 2293.51, "word": " ال", "probability": 0.9638671875}, {"start": 2293.51, "end": 2294.17, "word": " sequence", "probability": 0.9794921875}, {"start": 2294.17, "end": 2294.91, "word": " هيلزمنا", "probability": 0.83330078125}, {"start": 2294.91, "end": 2295.07, "word": " ان", "probability": 0.87353515625}, {"start": 2295.07, "end": 2295.27, "word": " شاء", "probability": 0.969482421875}, {"start": 2295.27, "end": 2295.37, "word": " الله", "probability": 0.93994140625}, {"start": 2295.37, "end": 2296.51, "word": " محاضرة", "probability": 0.9901123046875}, {"start": 2296.51, "end": 2297.47, "word": " إضافية", "probability": 0.90087890625}, {"start": 2297.47, "end": 2298.03, "word": " نحكي", "probability": 0.9771728515625}, {"start": 2298.03, "end": 2298.47, "word": " فيها", "probability": 0.989990234375}, {"start": 2298.47, "end": 2299.03, "word": " كيف", "probability": 0.962158203125}, {"start": 2299.03, "end": 2299.71, "word": " نتعرف", "probability": 0.989013671875}, {"start": 2299.71, "end": 2300.09, "word": " على", "probability": 0.89501953125}, {"start": 2300.09, "end": 2300.97, "word": " ال", "probability": 0.98388671875}, {"start": 2300.97, "end": 2301.71, "word": " sequence", "probability": 0.99267578125}, {"start": 2301.71, "end": 2302.57, "word": " لل", "probability": 0.87548828125}, {"start": 2302.57, "end": 2302.99, "word": " amino", "probability": 0.9404296875}, {"start": 2302.99, "end": 2303.57, "word": " acids", "probability": 0.76953125}, {"start": 2303.57, "end": 2303.91, "word": " وإذا", "probability": 0.833984375}, {"start": 2303.91, "end": 2304.25, "word": " عرفنا", "probability": 0.9933268229166666}, {"start": 2304.25, "end": 2304.39, "word": " ال", "probability": 0.9833984375}, {"start": 2304.39, "end": 2304.83, "word": " sequence", "probability": 0.9931640625}, {"start": 2304.83, "end": 2305.21, "word": " شوفنا", "probability": 0.9168294270833334}, {"start": 2305.21, "end": 2305.45, "word": " كيف", "probability": 0.96923828125}, {"start": 2305.45, "end": 2305.69, "word": " الآن", "probability": 0.71435546875}, {"start": 2305.69, "end": 2306.57, "word": " بنحضرهم", "probability": 0.98359375}, {"start": 2306.57, "end": 2307.17, "word": " بعد", "probability": 0.7998046875}, {"start": 2307.17, "end": 2307.81, "word": " هيك", "probability": 0.78759765625}, {"start": 2307.81, "end": 2308.49, "word": " أشكال", "probability": 0.9591064453125}, {"start": 2308.49, "end": 2308.81, "word": " ال", "probability": 0.98486328125}, {"start": 2308.81, "end": 2309.25, "word": " protein", "probability": 0.9736328125}, {"start": 2309.25, "end": 2310.17, "word": " المختلفة", "probability": 0.9945068359375}, {"start": 2310.17, "end": 2310.65, "word": " فان", "probability": 0.709228515625}, {"start": 2310.65, "end": 2310.77, "word": " شاء", "probability": 0.981689453125}, {"start": 2310.77, "end": 2310.85, "word": " الله", "probability": 0.93701171875}, {"start": 2310.85, "end": 2311.09, "word": " إلى", "probability": 0.865234375}, {"start": 2311.09, "end": 2311.53, "word": " لقاء", "probability": 0.9265950520833334}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2312.336, "duration_after_vad": 2219.2037499999915}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d511c99f10a77c80d1cca130c0dc60fbeb25b456
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk.srt
@@ -0,0 +1,957 @@
+
+1
+00:00:19,460 --> 00:00:24,620
+بسم الله الرحمن الرحيم بدأنا احنا المرة الماضية في
+
+2
+00:00:24,620 --> 00:00:28,220
+موضوع الأحماض الكربوكسيلية الـ carboxylic acids
+
+3
+00:00:28,220 --> 00:00:35,460
+واستعرضنا طبعا تسميتها و الحامضية لها و بدأنا في
+
+4
+00:00:35,460 --> 00:00:40,840
+موضوع تحضير الـ carboxylic acids قلنا طبعا ان في
+
+5
+00:00:40,840 --> 00:00:47,130
+عندنا اكثر من طريقة لتحضير الـ carboxylic acids لو
+
+6
+00:00:47,130 --> 00:00:53,190
+بدنا احنا نيجي ببساطة نتخيل هالطرق هذه لتحضير ال
+
+7
+00:00:53,190 --> 00:00:59,430
+carboxylic acids بإمكانكوا تنظروا ل الأقلام اللي
+
+8
+00:00:59,430 --> 00:01:04,590
+أنا حاملهم هدولة كام قلم؟ تلاتة .. تلاتة .. تلاتة
+
+9
+00:01:04,590 --> 00:01:05,090
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+10
+00:01:05,090 --> 00:01:06,070
+تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+11
+00:01:06,070 --> 00:01:06,150
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+12
+00:01:06,150 --> 00:01:12,410
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+13
+00:01:12,410 --> 00:01:19,640
+.. تلاتة .. تيعني أبدأ بتلات ذرات عند اللزوم كحول
+
+14
+00:01:19,640 --> 00:01:24,020
+أو aldehyde و يطلع عندى حامض من تلات ذرات يعني
+
+15
+00:01:24,020 --> 00:01:28,520
+أبدأ بتلاته و يطلع عندى تلاته و كان هذه الطريقة
+
+16
+00:01:28,520 --> 00:01:32,480
+طريقة التساوي هي الطريقة الأولى اللى بدأنا نشرحها
+
+17
+00:01:32,480 --> 00:01:36,180
+لما اتكلمنا المرة الماضية عن الكحولات و عن ال
+
+18
+00:01:36,180 --> 00:01:40,550
+aldehydesلما اتكلمنا المرة الماضية عن الكحولات و
+
+19
+00:01:40,550 --> 00:01:45,950
+عن ال aldehydes هذه الطريقة طريقة ايش تساوي يعني
+
+20
+00:01:45,950 --> 00:01:52,330
+قداش في عندى عدد كربونات في الكحول او في ال
+
+21
+00:01:52,330 --> 00:01:56,290
+aldehyde قداش بيكونوا في ال essence يعني لو الكحول
+
+22
+00:01:56,290 --> 00:02:03,000
+كانوا تلاتة معنى ذلك هيكون اسم تبعه فيه propaneأو
+
+23
+00:02:03,000 --> 00:02:06,880
+ال الديهايد كانوا تلاتة الاسم تبعه برضه هيكون فيه
+
+24
+00:02:06,880 --> 00:02:12,760
+بروفان تلاتة الآن ال acid اللي هيطلع برضه هيكون
+
+25
+00:02:12,760 --> 00:02:19,560
+تلاتة لا هيزيد ولا هينقص خلينا نشوف هذا الكلام
+
+26
+00:02:19,560 --> 00:02:24,120
+يعني مثلا لو أخدنا CH3 CH2
+
+27
+00:02:26,930 --> 00:02:35,710
+هذا ايش؟ كحول من كام كربونة؟ ثلاثة اسمه بروبان
+
+28
+00:02:35,710 --> 00:02:41,810
+البروبان بتعبر عن العدد all الان لو بدنا اكسدة
+
+29
+00:02:41,810 --> 00:02:49,430
+بسيطة في ال BCC عند اللزوم حيصير CH3 CH2 C double
+
+30
+00:02:49,430 --> 00:02:59,080
+bond OH كام ذرة؟تلاتة هذا اللي اتكون شو اسمه?
+
+31
+00:03:02,720 --> 00:03:08,000
+Ibrobanol إذا هل تغير عدد الذرات؟ لأ لو امشينا في
+
+32
+00:03:08,000 --> 00:03:12,020
+الأكسدة بالكيامان O4 عند اللزوم أو من البداية
+
+33
+00:03:12,020 --> 00:03:20,960
+بدينا بالكيامان O4 CH3 CH2 Cضم البند O OH كم ذرة
+
+34
+00:03:20,960 --> 00:03:25,500
+كربون؟ اه هذا إيش بدو يصير؟ Ibrobanol
+
+35
+00:03:28,860 --> 00:03:35,200
+وبهيك بيصير واضح معاه أن الأفكار المتعلقة بالأكسد،
+
+36
+00:03:35,200 --> 00:03:40,920
+أكسدة الكحول، الالدهاي، الاسد، لتغير عدد درات
+
+37
+00:03:40,920 --> 00:03:46,350
+الكربونواضح الفكرة؟ ولذلك هذه الطريقة .. طريقة إيش
+
+38
+00:03:46,350 --> 00:03:51,930
+بنسميها؟ طريقة تساوي .. إنه أنا عندي تلت ذرات
+
+39
+00:03:51,930 --> 00:03:56,030
+carbon .. إنه أنا عندي تلت ذرات carbon .. هدولة
+
+40
+00:03:56,030 --> 00:03:58,570
+تلت ذرات carbon .. كانوا تلاتة .. ضالوا تلاتة ..
+
+41
+00:03:58,570 --> 00:04:04,070
+ضالوا تلاتة .. واضح الفكرة؟ طبعا للناس اللي بيحبوا
+
+42
+00:04:04,070 --> 00:04:07,890
+انزيد شوية في الكلام و في المعلومات .. أنا ممكن
+
+43
+00:04:07,890 --> 00:04:12,990
+أبدأ من التلاتةبطريقة شوية صغيرة مختلفة يعني
+
+44
+00:04:12,990 --> 00:04:20,290
+مابداش بالكحول مابداش بالكحول يا ترى لو مثلا بدأت
+
+45
+00:04:20,290 --> 00:04:27,810
+بهذا المركب لو بدأت بهذا المركب CH3 CH double bond
+
+46
+00:04:27,810 --> 00:04:35,520
+CH2جبتلكم سؤال كيف من الابروب برضه ابروب ملاحظين
+
+47
+00:04:35,520 --> 00:04:40,880
+تلاتة ابروبين how can you prepare aerobic acid
+
+48
+00:04:40,880 --> 00:04:46,340
+starting from aerobin تلاتة تلاتة تلاتة تلاتة اه
+
+49
+00:04:46,340 --> 00:04:51,720
+هتيجي واحدة تتذكر ان انا هنا بدي اضيف الميه مع ولا
+
+50
+00:04:51,720 --> 00:04:56,220
+عكس قاعدة Markovnikov طبعا عكس عكس
+
+51
+00:05:05,320 --> 00:05:10,460
+واضح الفكرة فتلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+52
+00:05:10,460 --> 00:05:11,320
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+53
+00:05:11,320 --> 00:05:11,500
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+54
+00:05:11,500 --> 00:05:13,440
+زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا
+
+55
+00:05:13,440 --> 00:05:15,280
+تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+56
+00:05:15,280 --> 00:05:19,440
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+57
+00:05:19,440 --> 00:05:28,330
+زالوا تلاتة ما زالوا تبصير acid واضح؟ الأن في هذه
+
+58
+00:05:28,330 --> 00:05:33,990
+الحالة مافيش عندى تغير في عدد ذرات الكربون فالطرق
+
+59
+00:05:33,990 --> 00:05:39,310
+المنطلقة من الأكسة ده مافيش فيها تغير بيكون بيوتان
+
+60
+00:05:39,310 --> 00:05:44,910
+بيوتانوك بيوتانول بيوتانال لكن عدد ذرات الكربون
+
+61
+00:05:44,910 --> 00:05:48,430
+إيش ماله؟ ثابت حتى لو قلت بيوتين كمان
+
+62
+00:05:55,150 --> 00:06:03,190
+الان في طرق تانية .. في طرق تانية ممكن أنه نتعامل
+
+63
+00:06:03,190 --> 00:06:09,570
+معها .. ممكن نشتغل على طريقة اسمها طريقة النقص ..
+
+64
+00:06:09,570 --> 00:06:16,000
+يعني أبدأ بتلاتةو أكسر من التلاتة هدولة و أجد
+
+65
+00:06:16,000 --> 00:06:21,820
+أبطلع بإيش نفترض ب 2 و ب 1 أكسر التلاتة أو أبدأ ب
+
+66
+00:06:21,820 --> 00:06:28,140
+4 و أكسر الأربعة ل 2 و 2 أو ل 3 و 1 هذه طريقة إيش
+
+67
+00:06:28,140 --> 00:06:33,400
+نقص أنه أنا يكون عند السلسلة الكلية السلسلة الكلية
+
+68
+00:06:33,400 --> 00:06:39,040
+أربع كربونات أطول منها 3 أو 2 أو 1 يعني أقل من إيش
+
+69
+00:06:39,560 --> 00:06:44,440
+أقل من الأربعة صارت هذه الطريقة طريقة ايش نقص طبعا
+
+70
+00:06:44,440 --> 00:06:48,660
+ايش بيظل عندنا انه ممكن تكون طريقة زيادة يعني
+
+71
+00:06:48,660 --> 00:06:53,920
+افترضوا انه سلسلة عندى أربعة وطلبت
+
+72
+00:06:53,920 --> 00:06:56,600
+منكوا تحضروا لي حمض بخمس كربونات
+
+73
+00:07:01,280 --> 00:07:08,760
+أنا قلت لكم ببساطة مبتدئا من البيوتانول البيوتانول
+
+74
+00:07:08,760 --> 00:07:14,680
+كام كربونا؟ أربعة حضرولي بنتانوك أسد الآن إذا
+
+75
+00:07:14,680 --> 00:07:19,720
+واحدة مش منتبهة تقول all oic acid تروح تعمل أكسدة
+
+76
+00:07:19,720 --> 00:07:26,520
+أه بس البيوتانول بيصير بيوتانوك أسدبزيدش Carbona
+
+77
+00:07:26,520 --> 00:07:30,960
+الان لو كنت بداجي اسألكم والله من ال Butanol
+
+78
+00:07:30,960 --> 00:07:37,890
+حضرولي Pentanoic acid زدتوا Carbonaإذا أنا بحاجة
+
+79
+00:07:37,890 --> 00:07:43,030
+إلى طريقة وبناء على ذلك للي بدوا يفهم طرق تحضير
+
+80
+00:07:43,030 --> 00:07:47,130
+الأحماض بشكل عام بنقول أن طرق تحضير الأحماض بدكوا
+
+81
+00:07:47,130 --> 00:07:51,870
+تنتبهوا تماما ممكن تكون طريقة التساوي وهذه موجودة
+
+82
+00:07:51,870 --> 00:07:55,130
+في شغل الأكسد أو الكلام اللي شرحنا الآن ممكن تكون
+
+83
+00:07:55,130 --> 00:08:01,250
+طريقة تكسير أو نقص وممكن تكون طريقة إيش؟ زيادة
+
+84
+00:08:01,250 --> 00:08:09,000
+واضحة الفكرة؟ الآن خلينا نيجيلاطرق التكثير خلّينا
+
+85
+00:08:09,000 --> 00:08:15,340
+نيجي لطرق التكثير بشكل عام نسبة من طرق التكثير مرت
+
+86
+00:08:15,340 --> 00:08:19,980
+معنا بطريقة أو باخرى ليش؟ لأنه احنا أخدنا ال
+
+87
+00:08:19,980 --> 00:08:27,460
+ozoneolysis ال ozoneolysis عادة بيكسر المركب لإيش؟
+
+88
+00:08:28,390 --> 00:08:33,650
+لأldehyde او كيتون ايه كويس الال بعد ما
+
+89
+00:08:33,650 --> 00:08:38,370
+الأوزونوليس يعني هيك انا بده اقول الكين والالكاين
+
+90
+00:08:38,370 --> 00:08:46,370
+زي الالكين بالمناسبة الكين ممكن يعطيني ايش كيتون
+
+91
+00:08:49,540 --> 00:08:53,540
+الديهايد هذا الكلام اتعلمناه ولا لأ ان الالكين
+
+92
+00:08:53,540 --> 00:08:57,600
+بيصير كيتون او الديهايد الان الكيتون اتعلمناه انه
+
+93
+00:08:57,600 --> 00:09:05,060
+لا يتأكسد اكسدة اضافية لكن ال الديهايد بتأكسد ولا
+
+94
+00:09:05,060 --> 00:09:09,860
+لأ ال الديهايد بتأكسد اكسدة اضافية بيصير ايش acid
+
+95
+00:09:09,860 --> 00:09:14,440
+الان بكل الأحوال هذا ال الديهايد هيكون اصغر من ال
+
+96
+00:09:14,440 --> 00:09:20,010
+الكين او من ال الكاين ولا لأبالتأكيد هنا هيلزمني
+
+97
+00:09:20,010 --> 00:09:25,750
+كام عملية يتموا ورا بعض عمليتين العملية الأولى ال
+
+98
+00:09:25,750 --> 00:09:31,630
+ozoneolysis و العملية التانية ال oxidation خلّيني
+
+99
+00:09:31,630 --> 00:09:35,990
+أعبّر عنها ب O بين جثين Oxidation عملية أكسدة عادة
+
+100
+00:09:35,990 --> 00:09:41,430
+بيستعملونها H2O2 الهيدروجين بيروكسايد هذه كمان
+
+101
+00:09:41,430 --> 00:09:49,310
+خلّوها H2O2أذن اوزونوليسيز followed by H2O2 يمكن
+
+102
+00:09:49,310 --> 00:09:55,050
+أن يؤدي إلى أحماض لكن أكيد هتكون أصغر من إيش؟ أصغر
+
+103
+00:09:55,050 --> 00:10:02,090
+من الألكين اللي أنا ابتدأت فيه الآن خلينا ناخد
+
+104
+00:10:02,090 --> 00:10:06,910
+مثال حقيقي ناخد مثال حقيقي لو يا ترى أخدنا هذا
+
+105
+00:10:06,910 --> 00:10:16,980
+الألكينسواء قلنا عنه CES و لا TRANS CH3 CH3H
+
+106
+00:10:16,980 --> 00:10:26,200
+CH3H و قلنا اكمل نمر واحد O3 Ozonolysis و نمر
+
+107
+00:10:26,200 --> 00:10:31,060
+اتنين H2O2 H2O2 Hydrogen Peroxide هو العامل
+
+108
+00:10:31,060 --> 00:10:39,210
+المؤكسد الان بدنا لما ننفذ نفهم الشغل الاولىكسر
+
+109
+00:10:39,210 --> 00:10:47,350
+يعني C double bond O H و CH3 زائد C double bond OH
+
+110
+00:10:47,350 --> 00:10:55,750
+و CH3 هذا ال ozonolases طب و ال acid هذا إيش؟
+
+111
+00:10:55,750 --> 00:11:00,830
+الديهايد الآن هذا ال الديهايد بال H2O2 اللي ضفناها
+
+112
+00:11:00,830 --> 00:11:08,760
+إيش حيصير؟ C double bond O OHCH3 وجدت حصلنا على
+
+113
+00:11:08,760 --> 00:11:14,980
+الاسيتك أسد الاسيتك أسد كده؟ كربون 2 يعني كأنه انا
+
+114
+00:11:14,980 --> 00:11:18,820
+بال اوزونوليسيز اتيت كصرت الأربعة هدولة اتنين و
+
+115
+00:11:18,820 --> 00:11:23,400
+اتنين طلعوا عندي ألديهيد الآن كملت أكسدت الألديهيد
+
+116
+00:11:23,400 --> 00:11:29,060
+صار اسيتك أسد فمن الأربعة حصلت على حامض من كام
+
+117
+00:11:29,060 --> 00:11:37,890
+كربون؟ تنتين واضحة الفكرة؟ طبعا الآناللي ممكن
+
+118
+00:11:37,890 --> 00:11:44,390
+يفكروا انه نتعمق معهم بمثل هذه الفكرة ممكن نيجي
+
+119
+00:11:44,390 --> 00:11:49,910
+نسألهم، مانقول هم مش مبتدئان من ال 2 بيوتين، لو
+
+120
+00:11:49,910 --> 00:11:55,930
+بدأت من ال one بيوتين، هيطلع عند أحمد واحد و تلاتة
+
+121
+00:11:56,580 --> 00:12:00,520
+لأن هذه هتكسر كربونا و هدول يكونوا تلاتة لكن لو
+
+122
+00:12:00,520 --> 00:12:07,080
+انا اجيت و قولتلكم والله من مركب زي هذا CH3 CH2 CH
+
+123
+00:12:07,080 --> 00:12:15,560
+سواء حطيت هنا CL او OH اتخيلوا ان انا اجي اقولكم
+
+124
+00:12:15,560 --> 00:12:23,720
+من two chlorobutane حضروا لي acidic acid واضح او
+
+125
+00:12:23,720 --> 00:12:28,880
+من two butanolبتكون تعملوا elimination الان ال CL
+
+126
+00:12:28,880 --> 00:12:32,320
+و ال H بيروحوا و بيعطينا ال more substituted
+
+127
+00:12:32,320 --> 00:12:37,280
+باستعمال ايش طلعت
+
+128
+00:12:37,280 --> 00:12:44,240
+انا ال alkyd و بعدين كسرت ال alkyd هذه الطرق و مع
+
+129
+00:12:44,240 --> 00:12:47,020
+ال triple bond نفس الاشي زي ال double bond هذه
+
+130
+00:12:47,020 --> 00:12:52,180
+الطرق تعتبر طرق ايشانقاس يعني كان عندى اربع
+
+131
+00:12:52,180 --> 00:12:56,720
+كربونات اعملت حامض من كربونتين اعملت حامض من تلات
+
+132
+00:12:56,720 --> 00:13:02,840
+كربونات حسب موقع ايش ال bubble bond بس بشرط انه
+
+133
+00:13:02,840 --> 00:13:06,660
+يكون من نتائج ال ozonosis انه بتكون aldehyde ليش؟
+
+134
+00:13:06,660 --> 00:13:10,820
+لأن اللى بيكمل وبيتأكسد ال aldehyde الكيتون بقولنا
+
+135
+00:13:10,820 --> 00:13:16,140
+فيه إله أكسدة إضافية؟ لأ واضحة الفكرة؟ اللى بيكمل
+
+136
+00:13:16,140 --> 00:13:21,210
+وبيتأكسد هو مين؟الالديهايد وهذا الكلام أخدناه في
+
+137
+00:13:21,210 --> 00:13:24,090
+أكسدة الالديهايد والكيتونز قلنا الالديهايد بتصير
+
+138
+00:13:24,090 --> 00:13:30,430
+أحمار الكيتونز لاتت أكسد أكسدة إضافية واضحة الفكرة
+
+139
+00:13:30,430 --> 00:13:37,150
+طيب
+
+140
+00:13:37,150 --> 00:13:45,300
+إذا عرفنا طريقة المساواة وطريقةالنقص ايش ضال
+
+141
+00:13:45,300 --> 00:13:51,140
+عندنا؟ طريقة الزيادة بمعنى لو انا اجيت وقلتلكم لو
+
+142
+00:13:51,140 --> 00:13:56,240
+سمحتوا من تلت كربونات بدي احضر حامض من اربع
+
+143
+00:13:56,240 --> 00:14:03,000
+كربونات عادة الزيادة اللي احنا بنعملها زيادة سهلة
+
+144
+00:14:03,480 --> 00:14:07,900
+ليه؟ كربونة واحدة هي اللي بتتم بسهولة يعني التلاتة
+
+145
+00:14:07,900 --> 00:14:13,160
+يصيروا أربعة، الأربعة يصيروا خمسة، الخمسة يصيروا
+
+146
+00:14:13,160 --> 00:14:17,680
+ستة كيف هذا الكلام .. كيف هذا الكلام بتم؟ هذا
+
+147
+00:14:17,680 --> 00:14:26,500
+الكلام عادة بتتممنطلقين فيه من ال الكل هلاي من ال
+
+148
+00:14:26,500 --> 00:14:33,040
+one chloro compound واضح يعني بدي مركب سلسلة يكون
+
+149
+00:14:33,040 --> 00:14:39,300
+على موقع واحد فيها إيش إكلور بدي سلسلة على موقع
+
+150
+00:14:39,300 --> 00:14:47,340
+واحد فيها إكلور يعني مثلا زي ما اقول CH3 CH2 CH2
+
+151
+00:14:47,340 --> 00:14:56,390
+CLالان الكلور هانا وين؟ على موقع واحد هذا الكلور
+
+152
+00:14:56,390 --> 00:15:00,050
+مكانه بدي ازيد كربونا اللي هي بده تكون حاملة
+
+153
+00:15:00,050 --> 00:15:06,320
+مجموعة الاسم عدد الكربونات الكل يعني قداشتلاتة بدي
+
+154
+00:15:06,320 --> 00:15:11,720
+أحضر من هذا butanoic acid يعني كام كربونا؟ أربعة
+
+155
+00:15:11,720 --> 00:15:16,640
+في عندى طريقتين ممكنين في عندى طريقتين ممكنين
+
+156
+00:15:16,640 --> 00:15:22,920
+الطريقة الأولى أنه أنا هذا أجي أفعله مع CN minus
+
+157
+00:15:22,920 --> 00:15:28,140
+والطريقة التانية أنه أنا هذا أفعله مع green yard
+
+158
+00:15:28,140 --> 00:15:34,560
+reagentمار عليكم المغنيسيا من اللي بيعطي RMGX طيب
+
+159
+00:15:34,560 --> 00:15:38,720
+لو فعلنا مع ال cyanide شو بده يصير هذا؟ بده يصير
+
+160
+00:15:38,720 --> 00:15:49,220
+CH3 CH2 CH2 و هنا بده تيجي مجموعة ال CN لاحظوا هنا
+
+161
+00:15:49,220 --> 00:15:54,120
+بينت الكربون الرابعة ولا لأ هيصاروا كام كربونة؟
+
+162
+00:15:55,060 --> 00:16:02,160
+أربعة بدل تلاتة الان ال cyanide بشكل عام لو عملتله
+
+163
+00:16:02,160 --> 00:16:11,340
+hydrolysis يا إما ب H3O plus بيمشي الحال أو ب N-A
+
+164
+00:16:11,340 --> 00:16:15,840
+-O-H و بعدين H plus يعني يا إما بهذا ال reagent يا
+
+165
+00:16:15,840 --> 00:16:20,100
+إما بهذا ال reagent بأي واحد منهم بيمشي بصير أسلوب
+
+166
+00:16:20,870 --> 00:16:24,310
+يعني ال cyanide بيعملها hydrolysis ال acid و بعدها
+
+167
+00:16:24,310 --> 00:16:34,310
+شو هيصير CH3 CH2 CH2 و هذه ال C هي اللي ضالت هتصير
+
+168
+00:16:34,310 --> 00:16:41,610
+C double bond O OH اذا انا ال chlorine
+
+223
+00:22:02,490 --> 00:22:05,670
+صح؟
+
+224
+00:22:05,670 --> 00:22:13,890
+CH3 إيش ممكن كمان؟ الـ F البنزين CH2 CH3 إيش كمان
+
+225
+00:22:13,890 --> 00:22:26,110
+ممكن؟ الـ كيومين CH CH3 CH3 كل هدول بيحملوه الـ كلي 
+
+226
+00:22:26,110 --> 00:22:29,950
+جروبز ممكن حد يفكر كمان بالـ تيرتشار بيوت البنزين 
+
+227
+00:22:29,950 --> 00:22:36,610
+ممكن حد يفكر بالـ تيرتشار بيوت البنزين الآن بنقول
+
+228
+00:22:36,610 --> 00:22:43,230
+الـ قاتل لو استعملنا عام المؤكسد بشكل عام الـ KMnO4
+
+229
+00:22:43,230 --> 00:22:48,710
+برمجانات البوتاسيوم مع أي ألكل بنزين مع أي ألكل
+
+230
+00:22:48,710 --> 00:22:54,480
+بنزين بس بشرط الـ كربون المتصل على البنزين مباشرة
+
+231
+00:22:54,480 --> 00:22:59,040
+تحتوي على ذرة هيدروجين على أقل تقدير الآن هذه 
+
+232
+00:22:59,040 --> 00:23:03,540
+الـ كربون .. كم هيدروجين بتحمل؟ تلاتة .. هذه .. هذه
+
+233
+00:23:03,540 --> 00:23:08,000
+.. هذه .. ولا واحدة .. اذا هدول الـ تلاتة بيمشي 
+
+234
+00:23:08,000 --> 00:23:14,540
+حالهمأى واحدة من هدول بالأكسدة بكامان of four
+
+235
+00:23:14,540 --> 00:23:18,820
+بتعطينا بنزويك أسل الآن انتبهوا معي لنقطة كتير
+
+236
+00:23:18,820 --> 00:23:26,100
+مهمة انه بغض النظر عن طول السلسلة هنطلع بس بنزويك
+
+237
+00:23:26,100 --> 00:23:30,960
+أسل يعني لو كان هنا مثل او اثل او بروبل او بيوتل
+
+238
+00:23:30,960 --> 00:23:34,760
+كربونة او تنتين او تلاتة او اربعة او خمسة او عشرة 
+
+239
+00:23:35,740 --> 00:23:40,220
+بس هطلعوا إيش الـ benzoic acid مرات كتير لما بنيجي
+
+240
+00:23:40,220 --> 00:23:44,620
+بنسأل الطلاب بنقولهم الله أعملونا أكسدة بنزين حامل
+
+241
+00:23:44,620 --> 00:23:47,340
+تلت كربونات بيروحوا بيخلوا الـ كربونتين و بيعملوا
+
+242
+00:23:47,340 --> 00:23:51,640
+الـ أكسدة على الـ تالتة افهمتوا الـ غلطة اللي بحكيها ولا
+
+243
+00:23:51,640 --> 00:24:00,600
+أوضحها أكتر لما أجي أرسملهم مركب زي هذا CH2 CH2
+
+244
+00:24:00,600 --> 00:24:07,120
+CH3 و أقولهم بالـ كمام O4الآن الـ غلطة اللي بيعملوه 
+
+245
+00:24:07,120 --> 00:24:11,900
+بيعملوا الـ acid هانا و بيخلوها دولة الـ جواب الصحيح
+
+246
+00:24:11,900 --> 00:24:15,620
+انه سواء كانوا دول واحدة او تنتين او تلاتة او 
+
+247
+00:24:15,620 --> 00:24:20,720
+اربعة او عشرة بس بتكون عند هانا مجموعة الـ acid
+
+248
+00:24:20,720 --> 00:24:27,240
+COOHبمعنى أنا بشرحش ميكانيزم متفق انه بدنيش ادخل
+
+249
+00:24:27,240 --> 00:24:31,180
+كتير بتفاصيل يعني خليني في الـ نتائج بمعنى لو انا
+
+250
+00:24:31,180 --> 00:24:38,120
+اجيت سألتكم و قولتلكم انه تفاعل الـ طلوين و الـ اكيومين
+
+251
+00:24:38,120 --> 00:24:42,120
+اه انتبهوا معاك الـ طلوين و الـ اكيومين مع الـ كيامة الـ
+
+252
+00:24:42,120 --> 00:24:47,990
+O4 both produces benzoic acid صحبينما لو كان
+
+253
+00:24:47,990 --> 00:24:52,390
+الـ سؤال تفاعل الـ طلوين و الـ tertiary بيوت البنزين
+
+254
+00:24:52,390 --> 00:24:56,490
+هذا لأ لأن هذا مافيش عليه هيدروجينة على الـ كربون
+
+255
+00:24:56,490 --> 00:25:03,190
+الـ متصلة مباشرة بالبنزينة واضحة الـ فكرة؟ فعشان اتم
+
+256
+00:25:03,190 --> 00:25:06,810
+هذا النوع من الـ أكسدة هذا بنسميه oxidation of the
+
+257
+00:25:06,810 --> 00:25:12,290
+aliphatic sided chain مش هذه سلسلة معلقة على
+
+258
+00:25:12,290 --> 00:25:18,730
+الـ بنزينولذلك هذا الـ تفاعل اسمه أكسدت الـ سلسلة 
+
+259
+00:25:18,730 --> 00:25:24,110
+الـ معلقة على الـ بنزين، مهما كبرت ومهما عظمت، ايش
+
+260
+00:25:24,110 --> 00:25:31,750
+بتعطيني؟ acid، بس، بغض النظر عن طولهاواضح؟
+
+261
+00:25:31,750 --> 00:25:36,530
+Oxidation of the aliphatic sided chain attached to
+
+262
+00:25:36,530 --> 00:25:41,330
+benzene واضحة الـ فكرة؟ هذه طريقة لتحضير الـ benzoic
+
+263
+00:25:41,330 --> 00:25:46,570
+acid طبعا احنا جيبنا طريقة تانية باستعمال إيش؟ الـ
+
+264
+00:25:46,570 --> 00:25:54,040
+CN إذا هي كام طريقة صيرنا ذاكرين لكم؟طريقة السيانة 
+
+265
+00:25:54,040 --> 00:26:00,060
+جيبناها ولا لأ؟ طيب خلينا نمحا كل هالكلام ونقول لو 
+
+266
+00:26:00,060 --> 00:26:05,320
+إجاكم الـ سؤال في الـ امتحان ابتلى الطرق حضرولي الـ 
+
+267
+00:26:05,320 --> 00:26:08,440
+benzoic acid هتقولوا الـ aliphatic side chain هذه 
+
+268
+00:26:08,440 --> 00:26:12,620
+كلها طريقة حتى لو من الـ بنزين بقول بنزين طلوين
+
+269
+00:26:13,730 --> 00:26:17,930
+بنزويك أسد واضح؟ لما أقولكوا بدي بنزويك أسد من 
+
+270
+00:26:17,930 --> 00:26:23,090
+الـ بنزين، شو هانمشي؟ بنزين طول وين؟ بنزويك أسد 
+
+271
+00:26:23,090 --> 00:26:28,750
+صعبة؟ من الـ سيان و بنزين؟ ابنعملها طب لو قولنا بدنا 
+
+272
+00:26:28,750 --> 00:26:33,090
+طريقة تالتة من الـ بنزين
+
+273
+00:26:39,040 --> 00:26:48,920
+طريقة تالتة بد بنزويك أسد من الـ بنزين واضحة 
+
+274
+00:26:48,920 --> 00:26:58,260
+الـ فكرة هي بنزين بد يصير بنزويك أسد حسب ما اتعلمنا
+
+275
+00:26:58,260 --> 00:27:03,900
+لاحظوا ما بين الـ بنزين
+
+276
+00:27:03,900 --> 00:27:09,650
+و بنزويك أسد زيادة كربونةولذلك .. و لذلك احنا قلنا
+
+277
+00:27:09,650 --> 00:27:17,870
+بطريقة ما هذه لما صارت سيانو اقدرنا 
+
+278
+00:27:17,870 --> 00:27:21,330
+نحولها لـ acid بس مااخدناش الـ طريقة اللي بتخليها 
+
+279
+00:27:21,330 --> 00:27:24,970
+سيانو لحتى الآن الآن ما طريقة الـ زيادة الـ تانية 
+
+280
+00:27:24,970 --> 00:27:34,830
+اللتي تعلمناها اغرينيا اذا هذا يصير اكلوروبنزين
+
+281
+00:27:34,830 --> 00:27:40,590
+هذه تعلمناها ولا لأ الـ كلورو بنزين لو فعلناه معي
+
+282
+00:27:40,590 --> 00:27:47,050
+green yard مع Mg شو بيصير؟
+
+283
+00:27:47,050 --> 00:27:56,270
+MgCl الـ MgCl بإيش بيزيد كربونا؟ بتاني أكسيد 
+
+284
+00:27:56,270 --> 00:28:03,890
+الـ كربون وحمد إذا بنزين كلورو بنزين طبعا كلكوا 
+
+285
+00:28:03,890 --> 00:28:06,470
+عارفين الـ reaction اللي هو Cl2
+
+286
+00:28:13,200 --> 00:28:26,560
+بنزين بيصير بنزويك أسد بنزين بيصير
+
+287
+00:28:26,560 --> 00:28:30,080
+طلوين 
+
+288
+00:28:30,080 --> 00:28:36,360
+بنزويك أسدو بعدين كيامان افور بالـ كيامان افور اذا
+
+289
+00:28:36,360 --> 00:28:40,460
+هي الـ بنزويك اسد بتلات طرق اللى بده يحفظهم اول شى 
+
+290
+00:28:40,460 --> 00:28:47,160
+يقول بنزين طلوين بنزويك اسد بنزين سيانو بنزين
+
+291
+00:28:47,160 --> 00:28:52,720
+بنزويك اسد بنزين كلورو بنزين بنزين جرينيارد بنزويك 
+
+292
+00:28:52,720 --> 00:28:57,180
+اسد كل هذه طرق لتحضير البنزويك اسد ولا لأ كان 
+
+293
+00:28:57,180 --> 00:29:02,480
+طريقة تلاتة واضح وبهيك بننهي الـ يوم 
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..428486a9f8fb99bdcb2377917d9f4e20ac18b1a3
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_postprocess.srt
@@ -0,0 +1,1172 @@
+1
+00:00:19,460 --> 00:00:24,620
+بسم الله الرحمن الرحيم بدأنا احنا المرة الماضية في
+
+2
+00:00:24,620 --> 00:00:28,220
+موضوع الأحماض الكربوكسيلية الـ carboxylic acids
+
+3
+00:00:28,220 --> 00:00:35,460
+واستعرضنا طبعا تسميتها و الحامضية لها و بدأنا في
+
+4
+00:00:35,460 --> 00:00:40,840
+موضوع تحضير الـ carboxylic acids قلنا طبعا ان في
+
+5
+00:00:40,840 --> 00:00:47,130
+عندنا اكثر من طريقة لتحضير الـ carboxylic acidsلو
+
+6
+00:00:47,130 --> 00:00:53,190
+بدنا احنا نيجي ببساطة نتخيل هالطرق هذه لتحضير ال
+
+7
+00:00:53,190 --> 00:00:59,430
+carboxylic acids بإمكانكوا تنظروا ل الأقلام اللي
+
+8
+00:00:59,430 --> 00:01:04,590
+أنا حاملهم هدولة كام قلم؟ تلاتة .. تلاتة .. تلاتة
+
+9
+00:01:04,590 --> 00:01:05,090
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+10
+00:01:05,090 --> 00:01:06,070
+تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+11
+00:01:06,070 --> 00:01:06,150
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+12
+00:01:06,150 --> 00:01:12,410
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+13
+00:01:12,410 --> 00:01:19,640
+.. تلاتة .. تيعني أبدأ بتلات ذرات عند اللزوم كحول
+
+14
+00:01:19,640 --> 00:01:24,020
+أو aldehyde و يطلع عندى حامض من تلات ذرات يعني
+
+15
+00:01:24,020 --> 00:01:28,520
+أبدأ بتلاته و يطلع عندى تلاته و كان هذه الطريقة
+
+16
+00:01:28,520 --> 00:01:32,480
+طريقة التساوي هي الطريقة الأولى اللى بدأنا نشرحها
+
+17
+00:01:32,480 --> 00:01:36,180
+لما اتكلمنا المرة الماضية عن الكحولات و عن ال
+
+18
+00:01:36,180 --> 00:01:40,550
+aldehydesلما اتكلمنا المرة الماضية عن الكحولات و
+
+19
+00:01:40,550 --> 00:01:45,950
+عن ال aldehydes هذه الطريقة طريقة ايش تساوي يعني
+
+20
+00:01:45,950 --> 00:01:52,330
+قداش في عندى عدد كربونات في الكحول او في ال
+
+21
+00:01:52,330 --> 00:01:56,290
+aldehyde قداش بيكونوا في ال essence يعني لو الكحول
+
+22
+00:01:56,290 --> 00:02:03,000
+كانوا تلاتة معنى ذلك هيكون اسم تبعه فيه propaneأو
+
+23
+00:02:03,000 --> 00:02:06,880
+ال الديهايد كانوا تلاتة الاسم تبعه برضه هيكون فيه
+
+24
+00:02:06,880 --> 00:02:12,760
+بروفان تلاتة الآن ال acid اللي هيطلع برضه هيكون
+
+25
+00:02:12,760 --> 00:02:19,560
+تلاتة لا هيزيد ولا هينقص خلينا نشوف هذا الكلام
+
+26
+00:02:19,560 --> 00:02:24,120
+يعني مثلا لو أخدنا CH3 CH2
+
+27
+00:02:26,930 --> 00:02:35,710
+هذا ايش؟ كحول من كام كربونة؟ ثلاثة اسمه بروبان
+
+28
+00:02:35,710 --> 00:02:41,810
+البروبان بتعبر عن العدد all الان لو بدنا اكسدة
+
+29
+00:02:41,810 --> 00:02:49,430
+بسيطة في ال BCC عند اللزوم حيصير CH3 CH2 C double
+
+30
+00:02:49,430 --> 00:02:59,080
+bond OH كام ذرة؟تلاتة هذا اللي اتكون شو اسمه?
+
+31
+00:03:02,720 --> 00:03:08,000
+Ibrobanol إذا هل تغير عدد الذرات؟ لأ لو امشينا في
+
+32
+00:03:08,000 --> 00:03:12,020
+الأكسدة بالكيامان O4 عند اللزوم أو من البداية
+
+33
+00:03:12,020 --> 00:03:20,960
+بدينا بالكيامان O4 CH3 CH2 Cضم البند O OH كم ذرة
+
+34
+00:03:20,960 --> 00:03:25,500
+كربون؟ اه هذا إيش بدو يصير؟ Ibrobanol
+
+35
+00:03:28,860 --> 00:03:35,200
+وبهيك بيصير واضح معاه أن الأفكار المتعلقة بالأكسد،
+
+36
+00:03:35,200 --> 00:03:40,920
+أكسدة الكحول، الالدهاي، الاسد، لتغير عدد درات
+
+37
+00:03:40,920 --> 00:03:46,350
+الكربونواضح الفكرة؟ ولذلك هذه الطريقة .. طريقة إيش
+
+38
+00:03:46,350 --> 00:03:51,930
+بنسميها؟ طريقة تساوي .. إنه أنا عندي تلت ذرات
+
+39
+00:03:51,930 --> 00:03:56,030
+carbon .. إنه أنا عندي تلت ذرات carbon .. هدولة
+
+40
+00:03:56,030 --> 00:03:58,570
+تلت ذرات carbon .. كانوا تلاتة .. ضالوا تلاتة ..
+
+41
+00:03:58,570 --> 00:04:04,070
+ضالوا تلاتة .. واضح الفكرة؟ طبعا للناس اللي بيحبوا
+
+42
+00:04:04,070 --> 00:04:07,890
+انزيد شوية في الكلام و في المعلومات .. أنا ممكن
+
+43
+00:04:07,890 --> 00:04:12,990
+أبدأ من التلاتةبطريقة شوية صغيرة مختلفة يعني
+
+44
+00:04:12,990 --> 00:04:20,290
+مابداش بالكحول مابداش بالكحول يا ترى لو مثلا بدأت
+
+45
+00:04:20,290 --> 00:04:27,810
+بهذا المركب لو بدأت بهذا المركب CH3 CH double bond
+
+46
+00:04:27,810 --> 00:04:35,520
+CH2جبتلكم سؤال كيف من الابروب برضه ابروب ملاحظين
+
+47
+00:04:35,520 --> 00:04:40,880
+تلاتة ابروبين how can you prepare aerobic acid
+
+48
+00:04:40,880 --> 00:04:46,340
+starting from aerobin تلاتة تلاتة تلاتة تلاتة اه
+
+49
+00:04:46,340 --> 00:04:51,720
+هتيجي واحدة تتذكر ان انا هنا بدي اضيف الميه مع ولا
+
+50
+00:04:51,720 --> 00:04:56,220
+عكس قاعدة Markovnikov طبعا عكس عكس
+
+51
+00:05:05,320 --> 00:05:10,460
+واضح الفكرة فتلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+52
+00:05:10,460 --> 00:05:11,320
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+53
+00:05:11,320 --> 00:05:11,500
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+54
+00:05:11,500 --> 00:05:13,440
+زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا
+
+55
+00:05:13,440 --> 00:05:15,280
+تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+56
+00:05:15,280 --> 00:05:19,440
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+57
+00:05:19,440 --> 00:05:28,330
+زالوا تلاتة ما زالوا تبصير acid واضح؟ الأن في هذه
+
+58
+00:05:28,330 --> 00:05:33,990
+الحالة مافيش عندى تغير في عدد ذرات الكربون فالطرق
+
+59
+00:05:33,990 --> 00:05:39,310
+المنطلقة من الأكسة ده مافيش فيها تغير بيكون بيوتان
+
+60
+00:05:39,310 --> 00:05:44,910
+بيوتانوك بيوتانول بيوتانال لكن عدد ذرات الكربون
+
+61
+00:05:44,910 --> 00:05:48,430
+إيش ماله؟ ثابت حتى لو قلت بيوتين كمان
+
+62
+00:05:55,150 --> 00:06:03,190
+الان في طرق تانية .. في طرق تانية ممكن أنه نتعامل
+
+63
+00:06:03,190 --> 00:06:09,570
+معها .. ممكن نشتغل على طريقة اسمها طريقة النقص ..
+
+64
+00:06:09,570 --> 00:06:16,000
+يعني أبدأ بتلاتةو أكسر من التلاتة هدولة و أجد
+
+65
+00:06:16,000 --> 00:06:21,820
+أبطلع بإيش نفترض ب 2 و ب 1 أكسر التلاتة أو أبدأ ب
+
+66
+00:06:21,820 --> 00:06:28,140
+4 و أكسر الأربعة ل 2 و 2 أو ل 3 و 1 هذه طريقة إيش
+
+67
+00:06:28,140 --> 00:06:33,400
+نقص أنه أنا يكون عند السلسلة الكلية السلسلة الكلية
+
+68
+00:06:33,400 --> 00:06:39,040
+أربع كربونات أطول منها 3 أو 2 أو 1 يعني أقل من إيش
+
+69
+00:06:39,560 --> 00:06:44,440
+أقل من الأربعة صارت هذه الطريقة طريقة ايش نقص طبعا
+
+70
+00:06:44,440 --> 00:06:48,660
+ايش بيظل عندنا انه ممكن تكون طريقة زيادة يعني
+
+71
+00:06:48,660 --> 00:06:53,920
+افترضوا انه سلسلة عندى أربعة وطلبت
+
+72
+00:06:53,920 --> 00:06:56,600
+منكوا تحضروا لي حمض بخمس كربونات
+
+73
+00:07:01,280 --> 00:07:08,760
+أنا قلت لكم ببساطة مبتدئا من البيوتانول البيوتانول
+
+74
+00:07:08,760 --> 00:07:14,680
+كام كربونا؟ أربعة حضرولي بنتانوك أسد الآن إذا
+
+75
+00:07:14,680 --> 00:07:19,720
+واحدة مش منتبهة تقول all oic acid تروح تعمل أكسدة
+
+76
+00:07:19,720 --> 00:07:26,520
+أه بس البيوتانول بيصير بيوتانوك أسدبزيدش Carbona
+
+77
+00:07:26,520 --> 00:07:30,960
+الان لو كنت بداجي اسألكم والله من ال Butanol
+
+78
+00:07:30,960 --> 00:07:37,890
+حضرولي Pentanoic acid زدتوا Carbonaإذا أنا بحاجة
+
+79
+00:07:37,890 --> 00:07:43,030
+إلى طريقة وبناء على ذلك للي بدوا يفهم طرق تحضير
+
+80
+00:07:43,030 --> 00:07:47,130
+الأحماض بشكل عام بنقول أن طرق تحضير الأحماض بدكوا
+
+81
+00:07:47,130 --> 00:07:51,870
+تنتبهوا تماما ممكن تكون طريقة التساوي وهذه موجودة
+
+82
+00:07:51,870 --> 00:07:55,130
+في شغل الأكسد أو الكلام اللي شرحنا الآن ممكن تكون
+
+83
+00:07:55,130 --> 00:08:01,250
+طريقة تكسير أو نقص وممكن تكون طريقة إيش؟ زيادة
+
+84
+00:08:01,250 --> 00:08:09,000
+واضحة الفكرة؟ الآن خلينا نيجيلاطرق التكثير خلّينا
+
+85
+00:08:09,000 --> 00:08:15,340
+نيجي لطرق التكثير بشكل عام نسبة من طرق التكثير مرت
+
+86
+00:08:15,340 --> 00:08:19,980
+معنا بطريقة أو باخرى ليش؟ لأنه احنا أخدنا ال
+
+87
+00:08:19,980 --> 00:08:27,460
+ozoneolysis ال ozoneolysis عادة بيكسر المركب لإيش؟
+
+88
+00:08:28,390 --> 00:08:33,650
+لأldehyde او كيتون ايه كويس الال بعد ما
+
+89
+00:08:33,650 --> 00:08:38,370
+الأوزونوليس يعني هيك انا بده اقول الكين والالكاين
+
+90
+00:08:38,370 --> 00:08:46,370
+زي الالكين بالمناسبة الكين ممكن يعطيني ايش كيتون
+
+91
+00:08:49,540 --> 00:08:53,540
+الديهايد هذا الكلام اتعلمناه ولا لأ ان الالكين
+
+92
+00:08:53,540 --> 00:08:57,600
+بيصير كيتون او الديهايد الان الكيتون اتعلمناه انه
+
+93
+00:08:57,600 --> 00:09:05,060
+لا يتأكسد اكسدة اضافية لكن ال الديهايد بتأكسد ولا
+
+94
+00:09:05,060 --> 00:09:09,860
+لأ ال الديهايد بتأكسد اكسدة اضافية بيصير ايش acid
+
+95
+00:09:09,860 --> 00:09:14,440
+الان بكل الأحوال هذا ال الديهايد هيكون اصغر من ال
+
+96
+00:09:14,440 --> 00:09:20,010
+الكين او من ال الكاين ولا لأبالتأكيد هنا هيلزمني
+
+97
+00:09:20,010 --> 00:09:25,750
+كام عملية يتموا ورا بعض عمليتين العملية الأولى ال
+
+98
+00:09:25,750 --> 00:09:31,630
+ozoneolysis و العملية التانية ال oxidation خلّيني
+
+99
+00:09:31,630 --> 00:09:35,990
+أعبّر عنها ب O بين جثين Oxidation عملية أكسدة عادة
+
+100
+00:09:35,990 --> 00:09:41,430
+بيستعملونها H2O2 الهيدروجين بيروكسايد هذه كمان
+
+101
+00:09:41,430 --> 00:09:49,310
+خلّوها H2O2أذن اوزونوليسيز followed by H2O2 يمكن
+
+102
+00:09:49,310 --> 00:09:55,050
+أن يؤدي إلى أحماض لكن أكيد هتكون أصغر من إيش؟ أصغر
+
+103
+00:09:55,050 --> 00:10:02,090
+من الألكين اللي أنا ابتدأت فيه الآن خلينا ناخد
+
+104
+00:10:02,090 --> 00:10:06,910
+مثال حقيقي ناخد مثال حقيقي لو يا ترى أخدنا هذا
+
+105
+00:10:06,910 --> 00:10:16,980
+الألكينسواء قلنا عنه CES و لا TRANS CH3 CH3H
+
+106
+00:10:16,980 --> 00:10:26,200
+CH3H و قلنا اكمل نمر واحد O3 Ozonolysis و نمر
+
+107
+00:10:26,200 --> 00:10:31,060
+اتنين H2O2 H2O2 Hydrogen Peroxide هو العامل
+
+108
+00:10:31,060 --> 00:10:39,210
+المؤكسد الان بدنا لما ننفذ نفهم الشغل الاولىكسر
+
+109
+00:10:39,210 --> 00:10:47,350
+يعني C double bond O H و CH3 زائد C double bond OH
+
+110
+00:10:47,350 --> 00:10:55,750
+و CH3 هذا ال ozonolases طب و ال acid هذا إيش؟
+
+111
+00:10:55,750 --> 00:11:00,830
+الديهايد الآن هذا ال الديهايد بال H2O2 اللي ضفناها
+
+112
+00:11:00,830 --> 00:11:08,760
+إيش حيصير؟ C double bond O OHCH3 وجدت حصلنا على
+
+113
+00:11:08,760 --> 00:11:14,980
+الاسيتك أسد الاسيتك أسد كده؟ كربون 2 يعني كأنه انا
+
+114
+00:11:14,980 --> 00:11:18,820
+بال اوزونوليسيز اتيت كصرت الأربعة هدولة اتنين و
+
+115
+00:11:18,820 --> 00:11:23,400
+اتنين طلعوا عندي ألديهيد الآن كملت أكسدت الألديهيد
+
+116
+00:11:23,400 --> 00:11:29,060
+صار اسيتك أسد فمن الأربعة حصلت على حامض من كام
+
+117
+00:11:29,060 --> 00:11:37,890
+كربون؟ تنتين واضحة الفكرة؟ طبعا الآناللي ممكن
+
+118
+00:11:37,890 --> 00:11:44,390
+يفكروا انه نتعمق معهم بمثل هذه الفكرة ممكن نيجي
+
+119
+00:11:44,390 --> 00:11:49,910
+نسألهم، مانقول هم مش مبتدئان من ال 2 بيوتين، لو
+
+120
+00:11:49,910 --> 00:11:55,930
+بدأت من ال one بيوتين، هيطلع عند أحمد واحد و تلاتة
+
+121
+00:11:56,580 --> 00:12:00,520
+لأن هذه هتكسر كربونا و هدول يكونوا تلاتة لكن لو
+
+122
+00:12:00,520 --> 00:12:07,080
+انا اجيت و قولتلكم والله من مركب زي هذا CH3 CH2 CH
+
+123
+00:12:07,080 --> 00:12:15,560
+سواء حطيت هنا CL او OH اتخيلوا ان انا اجي اقولكم
+
+124
+00:12:15,560 --> 00:12:23,720
+من two chlorobutane حضروا لي acidic acid واضح او
+
+125
+00:12:23,720 --> 00:12:28,880
+من two butanolبتكون تعملوا elimination الان ال CL
+
+126
+00:12:28,880 --> 00:12:32,320
+و ال H بيروحوا و بيعطينا ال more substituted
+
+127
+00:12:32,320 --> 00:12:37,280
+باستعمال ايش طلعت
+
+128
+00:12:37,280 --> 00:12:44,240
+انا ال alkyd و بعدين كسرت ال alkyd هذه الطرق و مع
+
+129
+00:12:44,240 --> 00:12:47,020
+ال triple bond نفس الاشي زي ال double bond هذه
+
+130
+00:12:47,020 --> 00:12:52,180
+الطرق تعتبر طرق ايشانقاس يعني كان عندى اربع
+
+131
+00:12:52,180 --> 00:12:56,720
+كربونات اعملت حامض من كربونتين اعملت حامض من تلات
+
+132
+00:12:56,720 --> 00:13:02,840
+كربونات حسب موقع ايش ال bubble bond بس بشرط انه
+
+133
+00:13:02,840 --> 00:13:06,660
+يكون من نتائج ال ozonosis انه بتكون aldehyde ليش؟
+
+134
+00:13:06,660 --> 00:13:10,820
+لأن اللى بيكمل وبيتأكسد ال aldehyde الكيتون بقولنا
+
+135
+00:13:10,820 --> 00:13:16,140
+فيه إله أكسدة إضافية؟ لأ واضحة الفكرة؟ اللى بيكمل
+
+136
+00:13:16,140 --> 00:13:21,210
+وبيتأكسد هو مين؟الالديهايد وهذا الكلام أخدناه في
+
+137
+00:13:21,210 --> 00:13:24,090
+أكسدة الالديهايد والكيتونز قلنا الالديهايد بتصير
+
+138
+00:13:24,090 --> 00:13:30,430
+أحمار الكيتونز لاتت أكسد أكسدة إضافية واضحة الفكرة
+
+139
+00:13:30,430 --> 00:13:37,150
+طيب
+
+140
+00:13:37,150 --> 00:13:45,300
+إذا عرفنا طريقة المساواة وطريقةالنقص ايش ضال
+
+141
+00:13:45,300 --> 00:13:51,140
+عندنا؟ طريقة الزيادة بمعنى لو انا اجيت وقلتلكم لو
+
+142
+00:13:51,140 --> 00:13:56,240
+سمحتوا من تلت كربونات بدي احضر حامض من اربع
+
+143
+00:13:56,240 --> 00:14:03,000
+كربونات عادة الزيادة اللي احنا بنعملها زيادة سهلة
+
+144
+00:14:03,480 --> 00:14:07,900
+ليه؟ كربونة واحدة هي اللي بتتم بسهولة يعني التلاتة
+
+145
+00:14:07,900 --> 00:14:13,160
+يصيروا أربعة، الأربعة يصيروا خمسة، الخمسة يصيروا
+
+146
+00:14:13,160 --> 00:14:17,680
+ستة كيف هذا الكلام .. كيف هذا الكلام بتم؟ هذا
+
+147
+00:14:17,680 --> 00:14:26,500
+الكلام عادة بتتممنطلقين فيه من ال الكل هلاي من ال
+
+148
+00:14:26,500 --> 00:14:33,040
+one chloro compound واضح يعني بدي مركب سلسلة يكون
+
+149
+00:14:33,040 --> 00:14:39,300
+على موقع واحد فيها إيش إكلور بدي سلسلة على موقع
+
+150
+00:14:39,300 --> 00:14:47,340
+واحد فيها إكلور يعني مثلا زي ما اقول CH3 CH2 CH2
+
+151
+00:14:47,340 --> 00:14:56,390
+CLالان الكلور هانا وين؟ على موقع واحد هذا الكلور
+
+152
+00:14:56,390 --> 00:15:00,050
+مكانه بدي ازيد كربونا اللي هي بده تكون حاملة
+
+153
+00:15:00,050 --> 00:15:06,320
+مجموعة الاسم عدد الكربونات الكل يعني قداشتلاتة بدي
+
+154
+00:15:06,320 --> 00:15:11,720
+أحضر من هذا butanoic acid يعني كام كربونا؟ أربعة
+
+155
+00:15:11,720 --> 00:15:16,640
+في عندى طريقتين ممكنين في عندى طريقتين ممكنين
+
+156
+00:15:16,640 --> 00:15:22,920
+الطريقة الأولى أنه أنا هذا أجي أفعله مع CN minus
+
+157
+00:15:22,920 --> 00:15:28,140
+والطريقة التانية أنه أنا هذا أفعله مع green yard
+
+158
+00:15:28,140 --> 00:15:34,560
+reagentمار عليكم المغنيسيا من اللي بيعطي RMGX طيب
+
+159
+00:15:34,560 --> 00:15:38,720
+لو فعلنا مع ال cyanide شو بده يصير هذا؟ بده يصير
+
+160
+00:15:38,720 --> 00:15:49,220
+CH3 CH2 CH2 و هنا بده تيجي مجموعة ال CN لاحظوا هنا
+
+161
+00:15:49,220 --> 00:15:54,120
+بينت الكربون الرابعة ولا لأ هيصاروا كام كربونة؟
+
+162
+00:15:55,060 --> 00:16:02,160
+أربعة بدل تلاتة الان ال cyanide بشكل عام لو عملتله
+
+163
+00:16:02,160 --> 00:16:11,340
+hydrolysis يا إما ب H3O plus بيمشي الحال أو ب N-A
+
+164
+00:16:11,340 --> 00:16:15,840
+-O-H و بعدين H plus يعني يا إما بهذا ال reagent يا
+
+165
+00:16:15,840 --> 00:16:20,100
+إما بهذا ال reagent بأي واحد منهم بيمشي بصير أسلوب
+
+166
+00:16:20,870 --> 00:16:24,310
+يعني ال cyanide بيعملها hydrolysis ال acid و بعدها
+
+167
+00:16:24,310 --> 00:16:34,310
+شو هيصير CH3 CH2 CH2 و هذه ال C هي اللي ضالت هتصير
+
+168
+00:16:34,310 --> 00:16:41,610
+C double bond O OH اذا انا ال chlorine حولتها ل CN
+
+169
+00:16:41,610 --> 00:16:48,530
+و ال CN ع طول بتصير COOHهذه طريقة معروفة وجيدة
+
+170
+00:16:48,530 --> 00:16:53,750
+لعمل هذا المُركّب طيب الطريقة التانية .. بدأ أزيد
+
+171
+00:16:53,750 --> 00:16:58,310
+كربونا لسه .. أنا لو فعلت مع المغنيسيوم .. هذا إيش
+
+172
+00:16:58,310 --> 00:17:04,750
+هيعطيني؟ الـ Grignard Reagent .. كلكم اتذكرينه؟CH3
+
+173
+00:17:04,750 --> 00:17:13,470
+CH2 CH2 وقلنا هذه اهم اشي فيها MgCl هاي Green Yard
+
+174
+00:17:13,470 --> 00:17:18,630
+Ray Agent إبروبيل مغنيسيا ميكلورايد صح؟ الآن هذا
+
+175
+00:17:18,630 --> 00:17:25,330
+ال Green Yard Ray Agent بفعله مع نمرة واحد CO2
+
+176
+00:17:25,330 --> 00:17:28,250
+لاحظوا هاي ال C double bond O double bond O ثاني
+
+177
+00:17:28,250 --> 00:17:29,030
+أكسيد كربون
+
+178
+00:17:31,920 --> 00:17:38,840
+واضح؟ ونمر اتنين خليني ال CO2 ارسمه بالاحمر بفعله
+
+179
+00:17:38,840 --> 00:17:43,220
+مع ال CO2 يعني C double bond O double bond O ونمر
+
+180
+00:17:43,220 --> 00:17:49,000
+اتنين مع H بلس بيعطيني الحامض اللي هتقولولي من وين
+
+181
+00:17:49,000 --> 00:17:54,710
+اجت الكربونة؟هي من الـ CO2 مش الـ C حاملة انتن
+
+182
+00:17:54,710 --> 00:17:59,370
+أكسجين وهنا إيش زاد عندي؟ C double bond O OH
+
+183
+00:17:59,370 --> 00:18:06,590
+ببساطة هذا نيوكليوفايل بيهاجم هنا بيهاجم على
+
+184
+00:18:06,590 --> 00:18:09,990
+الكربون الموجبة مش الكربون بتاع تاني أكسيد الكربون
+
+185
+00:18:09,990 --> 00:18:15,050
+الموجبة لأنه جنبها مجموعتين سالبات لما يهاجم هذا
+
+186
+00:18:15,050 --> 00:18:20,250
+بتصير O minus ومن ال H plus بتاخد H إيش بتصير؟ OH
+
+187
+00:18:21,350 --> 00:18:27,040
+إذا هنا مصدر الكربونة الجديدة إيش بيكون؟الـ CO2
+
+188
+00:18:27,040 --> 00:18:31,720
+إذا أنا لما بدي أعمل الزيادة بدي مصدر للكربونة
+
+189
+00:18:31,720 --> 00:18:36,540
+الجديدة مصدر الكربونة الجديدة يا بدي يكون ال CN و
+
+190
+00:18:36,540 --> 00:18:39,340
+بعدين أعمل ال hydrolysis يا بعمل ال green yard
+
+191
+00:18:39,340 --> 00:18:43,280
+reagent و الكربونة الجديدة بجيبها من وين؟ من ال
+
+192
+00:18:43,280 --> 00:18:50,340
+CO2 واضح الفكرة؟ الآن مرة تانية مش ضروري تكون نقطة
+
+193
+00:18:50,340 --> 00:18:57,860
+البداية اللي عندى هي هذا المركب الكلوريممكن تكون
+
+194
+00:18:57,860 --> 00:19:02,180
+نقطة البداية الكحول الان الكحول بقدر اخليك low
+
+195
+00:19:02,180 --> 00:19:07,140
+right في الخطوة الأولى بالإبدال كحول مع O H minus
+
+196
+00:19:07,140 --> 00:19:17,960
+بيعمل إبدال ممكن تكون نقطة البداية الالكين هذه
+
+197
+00:19:17,960 --> 00:19:19,900
+الالكين بتلت كربونات
+
+198
+00:19:29,710 --> 00:19:35,570
+واضحة الفكرة فهذه
+
+199
+00:19:35,570 --> 00:19:41,830
+طرق الزيادة اللى عادة بنستعملها من خلال ال CN أو
+
+200
+00:19:41,830 --> 00:19:42,630
+ال CO2
+
+201
+00:19:52,800 --> 00:19:54,940
+هنا على السلسلة هذه
+
+202
+00:20:03,960 --> 00:20:08,640
+لأ لأ لأ لأ لأ ال chlorineation ال chlorineation
+
+203
+00:20:08,640 --> 00:20:13,260
+على السلسلة أخدناها ب CL2 في وجود ضوء أو حرارة أو
+
+204
+00:20:13,260 --> 00:20:16,560
+من خلال الإضافة ع ال double bond يعني ال chlorine
+
+205
+00:20:16,560 --> 00:20:20,600
+مع ال FeCl3 هذا على ال aromatic compounds هذا على
+
+206
+00:20:20,600 --> 00:20:28,580
+ال aromatic compounds تمام بضل في عندى ال benzoic
+
+207
+00:20:28,580 --> 00:20:35,710
+acidعارفين البنزويك أسد؟ كيف ممكن نحضر البنزويك
+
+208
+00:20:35,710 --> 00:20:40,970
+أسد؟ و مرات ممكن نسأل كيف ممكن تحضروا البنزويك أسد
+
+209
+00:20:40,970 --> 00:20:44,370
+من البنزين هاي البنزويك أسد
+
+210
+00:20:53,780 --> 00:20:59,240
+سهلة ان لو انا عندى cyanobenzene بصير benzoic acid
+
+211
+00:20:59,240 --> 00:21:05,480
+هذه الطريقة خلينى نقول ايش مالها سهلة CN اذا عندى
+
+212
+00:21:05,480 --> 00:21:11,740
+cyanobenzene في وجود H plus او NaOH نمرة واحد و
+
+213
+00:21:11,740 --> 00:21:15,320
+نمرة اتنين H plus زى ما حكينا قبل شوية ال
+
+214
+00:21:15,320 --> 00:21:21,420
+cyanobenzene بصير acid فيها مشكلةطبعا هيصير السؤال
+
+215
+00:21:21,420 --> 00:21:26,080
+كيف يتحضر السيانو بنزين .. سيانو بنزين في شبطر 11
+
+216
+00:21:26,080 --> 00:21:31,510
+بنتعلم تحضيرهبيجيش مباشر بقتش CN لأ اللي طريقة
+
+217
+00:21:31,510 --> 00:21:37,250
+التفافية ال CN و البنزين بيجيش بشكل مباشر بتحضرش
+
+218
+00:21:37,250 --> 00:21:41,630
+بشكل مباشر انه بنزين ماقتش CN ليش؟ لإن ال CN minus
+
+219
+00:21:41,630 --> 00:21:45,590
+و البنزين حاملة إلكترونات بيهاجمش minus على minus
+
+220
+00:21:45,590 --> 00:21:51,270
+طمام الطريقة التانية انه لو احنا أخدنا .. نخلص من
+
+221
+00:21:51,270 --> 00:21:56,770
+هذه الطريقة و نمحاها لو احنا أخدنا أي بنزين بيحمل
+
+222
+00:21:56,770 --> 00:22:02,490
+ال kilogramإيش في بنزين بيحمل الكل جروب؟ الطلوين
+
+223
+00:22:02,490 --> 00:22:05,670
+صح؟
+
+224
+00:22:05,670 --> 00:22:13,890
+CH3 إيش ممكن كمان؟ ال F البنزين CH2 CH3 إيش كمان
+
+225
+00:22:13,890 --> 00:22:26,110
+ممكن؟ القيومين CH CH3 CH3 كل هدولة بيحملوهالكلي
+
+226
+00:22:26,110 --> 00:22:29,950
+جروبز ممكن حد يفكر كمان بال تيرتشار بيوت البنزين
+
+227
+00:22:29,950 --> 00:22:36,610
+ممكن حد يفكر بال تيرتشار بيوت البنزين الآن بنقول
+
+228
+00:22:36,610 --> 00:22:43,230
+القاتل لو استعملنا عام المؤكسد بشكل عام ال KMnO4
+
+229
+00:22:43,230 --> 00:22:48,710
+برمجانات البوتاسيوم مع أي ألكل بنزين مع أي ألكل
+
+230
+00:22:48,710 --> 00:22:54,480
+بنزين بس بشرطالكربون المتصل على البنزين مباشرة
+
+231
+00:22:54,480 --> 00:22:59,040
+تحتوي على ذرة هيدروجين على اقل تقدير الان هذه
+
+232
+00:22:59,040 --> 00:23:03,540
+الكربون .. كم هيدروجين بتحمل؟ تلاتة .. هذه .. هذه
+
+233
+00:23:03,540 --> 00:23:08,000
+.. هذه .. ولا واحدة .. اذا هدولة التلاتة بيمشي
+
+234
+00:23:08,000 --> 00:23:14,540
+حالهمأى واحدة من هدول بالأكسدة بكامان of four
+
+235
+00:23:14,540 --> 00:23:18,820
+بتعطينا بنزويك أسل الان انتبهوا معي لنقطة كتير
+
+236
+00:23:18,820 --> 00:23:26,100
+مهمة انه بغض النظر عن طول السلسلة هنطلع بس بنزويك
+
+237
+00:23:26,100 --> 00:23:30,960
+أسل يعني لو كان هنا مثل او اثل او بروبل او بيوتل
+
+238
+00:23:30,960 --> 00:23:34,760
+كربونة او تنتين او تلاتة او اربعة او خمسة او عشرة
+
+239
+00:23:35,740 --> 00:23:40,220
+بس هطلعوا إيش ال benzoic acid مرات كتير لما بنيجي
+
+240
+00:23:40,220 --> 00:23:44,620
+بنسأل الطلاب بنقولهم الله أعملونا أكسدة بنزين حامل
+
+241
+00:23:44,620 --> 00:23:47,340
+تلت كربونات بيروحوا بيخلوا الكربونتين و بيعملوا
+
+242
+00:23:47,340 --> 00:23:51,640
+الأكسدة على التالتة افهمتوا الغلطة اللي بحكيها ولا
+
+243
+00:23:51,640 --> 00:24:00,600
+أوضحها أكتر لما أجي أرسملهم مركب زي هذا CH2 CH2
+
+244
+00:24:00,600 --> 00:24:07,120
+CH3 و أقولهم بالكمان O4الآن الغلطة اللي بيعملوه
+
+245
+00:24:07,120 --> 00:24:11,900
+بيعملوا ال acid هانا و بيخلوها دولة الجواب الصحيح
+
+246
+00:24:11,900 --> 00:24:15,620
+انه سواء كانوا دول واحدة او تنتين او تلاتة او
+
+247
+00:24:15,620 --> 00:24:20,720
+اربعة او عشرة بس بتكون عند هانا مجموعة ال acid
+
+248
+00:24:20,720 --> 00:24:27,240
+COOHبمعنى أنا بشرحش ميكانيزم متفق انه بدنيش ادخل
+
+249
+00:24:27,240 --> 00:24:31,180
+كتير بتفاصيل يعني خليني في النتائج بمعنى لو انا
+
+250
+00:24:31,180 --> 00:24:38,120
+اجيت سألتكم و قولتلكم انه تفاعل الطلوين والاكيومين
+
+251
+00:24:38,120 --> 00:24:42,120
+اه انتبهوا معاك الطلوين والاكيومين مع الكيامة ال
+
+252
+00:24:42,120 --> 00:24:47,990
+O4 both produces benzoic acid صحبينما لو كان
+
+253
+00:24:47,990 --> 00:24:52,390
+السؤال تفاعل الطلوين والـ tertiary بيوت البنزين
+
+254
+00:24:52,390 --> 00:24:56,490
+هذا لأ لأن هذا مافيش عليه هيدروجينة على الكاربون
+
+255
+00:24:56,490 --> 00:25:03,190
+المتصلة مباشرة بالبنزينة واضحة الفكرة؟ فعشان اتم
+
+256
+00:25:03,190 --> 00:25:06,810
+هذا النوع من الأكسدة هذا بنسميه oxidation of the
+
+257
+00:25:06,810 --> 00:25:12,290
+aliphatic sided chain مش هذه سلسلة معلقة على
+
+258
+00:25:12,290 --> 00:25:18,730
+البنزينولذلك هذا التفاعل اسمه أكسدت السلسلة
+
+259
+00:25:18,730 --> 00:25:24,110
+المعلقة على البنزين، مهما كبرت ومهما عظمت، ايش
+
+260
+00:25:24,110 --> 00:25:31,750
+بتعطيني؟ acid، بس، بغض النظر عن طولهاواضح؟
+
+261
+00:25:31,750 --> 00:25:36,530
+Oxidation of the aliphatic sided chain attached to
+
+262
+00:25:36,530 --> 00:25:41,330
+benzene واضحة الفكرة؟ هذه طريقة لتحضير ال benzoic
+
+263
+00:25:41,330 --> 00:25:46,570
+acid طبعا احنا جيبنا طريقة تانية باستعمال إيش؟ ال
+
+264
+00:25:46,570 --> 00:25:54,040
+CN إذا هي كام طريقة صيرنا ذاكرين لكم؟طريقة السيانة
+
+265
+00:25:54,040 --> 00:26:00,060
+جيبناها ولا لأ؟ طيب خلينا نمحا كل هالكلام ونقول لو
+
+266
+00:26:00,060 --> 00:26:05,320
+إجاكم السؤال في الامتحان ابتلى الطرق حضرولي ال
+
+267
+00:26:05,320 --> 00:26:08,440
+benzoic acid هتقولوا ال aliphatic side chain هذه
+
+268
+00:26:08,440 --> 00:26:12,620
+كلها طريقة حتى لو من البنزين بقول بنزين طلوين
+
+269
+00:26:13,730 --> 00:26:17,930
+بنزويك أسد واضح؟ لما أقولكوا بدي بنزويك أسد من
+
+270
+00:26:17,930 --> 00:26:23,090
+البنزين، شو هانمشي؟ بنزين طول وين؟ بنزويك أسد
+
+271
+00:26:23,090 --> 00:26:28,750
+صعبة؟ من السيان و بنزين؟ ابنعملها طب لو قولنا بدنا
+
+272
+00:26:28,750 --> 00:26:33,090
+طريقة تالتة من البنزين
+
+273
+00:26:39,040 --> 00:26:48,920
+طريقة تالتة بد بنزويك أسد من البنزين واضحة
+
+274
+00:26:48,920 --> 00:26:58,260
+الفكرة هي بنزين بد يصير بنزويك أسد حسب ما اتعلمنا
+
+275
+00:26:58,260 --> 00:27:03,900
+لاحظوا ما بين البنزين
+
+276
+00:27:03,900 --> 00:27:09,650
+و بنزويك أسد زيادة كربونةولذلك .. و لذلك احنا قلنا
+
+277
+00:27:09,650 --> 00:27:17,870
+بطريقة ما هذه لما صارت سيانو اقدرنا
+
+278
+00:27:17,870 --> 00:27:21,330
+نحولها ل acid بس مااخدناش الطريقة اللي بتخليها
+
+279
+00:27:21,330 --> 00:27:24,970
+سيانو لحتى الان الان ما طريقة الزيادة التانية
+
+280
+00:27:24,970 --> 00:27:34,830
+اللتي تعلمناها اغرينيا اذا هذا يصير اكلوروبنزين
+
+281
+00:27:34,830 --> 00:27:40,590
+هذه تعلمناها ولا لأالكلورو بنزين لو فعلناه معي
+
+282
+00:27:40,590 --> 00:27:47,050
+green yard مع Mg شو بيصير؟
+
+283
+00:27:47,050 --> 00:27:56,270
+MgCl ال MgCl بإيش بيزيد كربونا؟ بتاني أكسيد
+
+284
+00:27:56,270 --> 00:28:03,890
+الكربون وحمد إذا بنزين كلورو بنزين طبعا كلكوا
+
+285
+00:28:03,890 --> 00:28:06,470
+عارفين ال reaction اللي هو Cl2
+
+286
+00:28:13,200 --> 00:28:26,560
+بنزين بيصير بنزويك أسد بنزين بيصير
+
+287
+00:28:26,560 --> 00:28:30,080
+طلوين
+
+288
+00:28:30,080 --> 00:28:36,360
+بنزويك أسدو بعدين كيامان افور بالكيامان افور اذا
+
+289
+00:28:36,360 --> 00:28:40,460
+هى البنزويك اسد بتلات طرق اللى بده يحفظهم اول شى
+
+290
+00:28:40,460 --> 00:28:47,160
+يقول بنزين طلوين بنزويك اسد بنزين سيانو بنزين
+
+291
+00:28:47,160 --> 00:28:52,720
+بنزويك اسد بنزين كلورو بنزين بنزين جرينيارد بنزويك
+
+292
+00:28:52,720 --> 00:28:57,180
+اسد كل هذه طرق لتحضير البنزويك اسد ولا لأ كان
+
+293
+00:28:57,180 --> 00:29:02,480
+طريقة تلاتة واضح وبهيك بننهي اليوم
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..0c00532793b4d58cbd314874e035a70b891b579b
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4506, "start": 19.46, "end": 45.06, "text": "بسم الله الرحمن الرحيم بدأنا احنا المرة الماضية في موضوع الأحماض الكربوكسيلية الـ carboxylic acids واستعرضنا طبعا تسميتها و الحامضية لها و بدأنا في موضوع تحضير الـ carboxylic acids قلنا طبعا ان في عندنا اكثر من طريقة لتحضير الـ carboxylic acids", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 47525, 10721, 8315, 1975, 5016, 8315, 9673, 25720, 9673, 46958, 10632, 8978, 3714, 2407, 11242, 45367, 16247, 35571, 46958, 33251, 25513, 2407, 4117, 3794, 26895, 10632, 2423, 39184, 1032, 4995, 88, 1050, 21667, 36764, 14851, 3615, 43042, 8315, 23032, 3555, 3615, 995, 6055, 38251, 36081, 11296, 4032, 21542, 10943, 11242, 10632, 5296, 11296, 4032, 47525, 10721, 8315, 8978, 3714, 2407, 11242, 45367, 6055, 5016, 11242, 13546, 2423, 39184, 1032, 4995, 88, 1050, 21667, 12174, 1211, 8315, 23032, 3555, 3615, 995, 16472, 8978, 43242, 8315, 1975, 4117, 49115, 9154, 23032, 16572, 28671, 5296, 2655, 5016, 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0.84716796875}], "temperature": 1.0}, {"id": 4, "seek": 12137, "start": 97.53, "end": 121.37, "text": "لما اتكلمنا المرة الماضية عن الكحولات و عن ال aldehydes هذه الطريقة طريقة ايش تساوي يعني قداش في عندى عدد كربونات في الكحول او في ال aldehyde قداش بيكونوا في ال essence يعني لو الكحول كانوا تلاتة معنى ذلك هيكون اسم تبعه فيه propane", "tokens": [1211, 15042, 1975, 2655, 4117, 19528, 8315, 9673, 25720, 9673, 46958, 10632, 18871, 33251, 5016, 12610, 9307, 4032, 18871, 2423, 16798, 68, 3495, 14792, 29538, 41950, 16572, 28671, 23032, 16572, 28671, 1975, 1829, 8592, 6055, 3794, 995, 45865, 37495, 22653, 12174, 3215, 33599, 8978, 43242, 7578, 6225, 3215, 3215, 9122, 25513, 2407, 8315, 2655, 8978, 33251, 5016, 12610, 1975, 2407, 8978, 2423, 16798, 68, 3495, 1479, 12174, 3215, 33599, 4724, 1829, 30544, 14407, 8978, 2423, 12801, 37495, 22653, 45164, 33251, 5016, 12610, 25961, 14407, 6055, 1211, 9307, 3660, 20449, 1863, 7578, 29910, 23275, 39896, 30544, 24525, 2304, 6055, 3555, 3615, 3224, 8978, 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acid يعني كام كربونا؟ أربعة في عندى طريقتين ممكنين في عندى طريقتين ممكنين الطريقة الأولى أنه أنا هذا أجي أفعله مع CN minus والطريقة التانية أنه أنا هذا أفعله مع green yard reagent", "tokens": [2655, 1211, 9307, 3660, 4724, 16254, 5551, 5016, 11242, 2288, 9154, 23758, 457, 3730, 299, 8258, 37495, 22653, 9122, 10943, 9122, 25513, 2407, 8315, 22807, 5551, 25513, 27884, 8978, 43242, 7578, 23032, 16572, 38149, 9957, 3714, 43020, 9957, 8978, 43242, 7578, 23032, 16572, 38149, 9957, 3714, 43020, 9957, 41950, 16572, 28671, 16247, 12610, 7578, 14739, 3224, 41850, 23758, 5551, 7435, 1829, 5551, 5172, 30241, 3224, 20449, 14589, 3175, 16070, 9566, 16572, 28671, 16712, 7649, 10632, 14739, 3224, 41850, 23758, 5551, 5172, 30241, 3224, 20449, 3092, 11682, 26949, 317], "avg_logprob": -0.2438553384180819, "compression_ratio": 1.788659793814433, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 905.12, "end": 905.88, "word": "تلاتة", "probability": 0.8184814453125}, {"start": 905.88, "end": 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طريقتين", "probability": 0.9866943359375}, {"start": 913.88, "end": 914.7, "word": " ممكنين", "probability": 0.9710286458333334}, {"start": 914.7, "end": 915.06, "word": " في", "probability": 0.2188720703125}, {"start": 915.06, "end": 915.34, "word": " عندى", "probability": 0.97265625}, {"start": 915.34, "end": 915.88, "word": " طريقتين", "probability": 0.9957275390625}, {"start": 915.88, "end": 916.64, "word": " ممكنين", "probability": 0.9930013020833334}, {"start": 916.64, "end": 917.78, "word": " الطريقة", "probability": 0.9739583333333334}, {"start": 917.78, "end": 919.06, "word": " الأولى", "probability": 0.9767252604166666}, {"start": 919.06, "end": 919.38, "word": " أنه", "probability": 0.4873046875}, {"start": 919.38, "end": 919.7, "word": " أنا", "probability": 0.818359375}, {"start": 919.7, "end": 920.1, "word": " هذا", "probability": 0.88916015625}, {"start": 920.1, "end": 920.52, "word": " أجي", "probability": 0.5641276041666666}, {"start": 920.52, "end": 921.26, "word": " أفعله", "probability": 0.9854736328125}, {"start": 921.26, "end": 921.8, "word": " مع", "probability": 0.98828125}, {"start": 921.8, "end": 922.2, "word": " CN", "probability": 0.258056640625}, {"start": 922.2, "end": 922.92, "word": " minus", "probability": 0.42431640625}, {"start": 922.92, "end": 924.66, "word": " والطريقة", "probability": 0.8660888671875}, {"start": 924.66, "end": 925.32, "word": " التانية", "probability": 0.9705403645833334}, {"start": 925.32, "end": 925.94, "word": " أنه", "probability": 0.9091796875}, {"start": 925.94, "end": 926.18, "word": " أنا", "probability": 0.88427734375}, {"start": 926.18, "end": 926.44, "word": " هذا", "probability": 0.96923828125}, {"start": 926.44, "end": 927.0, "word": " أفعله", "probability": 0.9825439453125}, {"start": 927.0, "end": 927.24, "word": " مع", "probability": 0.98828125}, {"start": 927.24, "end": 927.78, "word": " green", "probability": 0.493896484375}, {"start": 927.78, "end": 928.14, "word": " yard", "probability": 0.44287109375}, {"start": 928.14, "end": 928.86, "word": " reagent", "probability": 0.879638671875}], "temperature": 1.0}, {"id": 38, "seek": 95412, "start": 929.9, "end": 954.12, "text": "مار عليكم المغنيسيا من اللي بيعطي RMGX طيب لو فعلنا مع ال cyanide شو بده يصير هذا؟ بده يصير CH3 CH2 CH2 و هنا بده تيجي مجموعة ال CN لاحظوا هنا بينت الكربون الرابعة ولا لأ هيصاروا كام كربونة؟", "tokens": [2304, 9640, 25894, 24793, 9673, 17082, 22653, 3794, 25528, 9154, 13672, 1829, 4724, 40228, 9566, 1829, 23790, 38, 55, 23032, 1829, 3555, 45164, 6156, 30241, 8315, 20449, 2423, 47463, 482, 13412, 2407, 47525, 3224, 7251, 9381, 13546, 23758, 22807, 47525, 3224, 7251, 9381, 13546, 5995, 18, 5995, 17, 5995, 17, 4032, 34105, 47525, 3224, 6055, 1829, 7435, 1829, 3714, 7435, 2304, 2407, 27884, 2423, 14589, 20193, 5016, 19913, 14407, 34105, 4724, 9957, 2655, 33251, 25513, 11536, 34892, 16758, 27884, 49429, 5296, 10721, 8032, 1829, 9381, 9640, 14407, 9122, 10943, 9122, 25513, 11536, 3660, 22807], 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944.24, "word": " هنا", "probability": 0.478759765625}, {"start": 944.24, "end": 944.5, "word": " بده", "probability": 0.8427734375}, {"start": 944.5, "end": 944.74, "word": " تيجي", "probability": 0.9783935546875}, {"start": 944.74, "end": 945.54, "word": " مجموعة", "probability": 0.96416015625}, {"start": 945.54, "end": 946.96, "word": " ال", "probability": 0.79248046875}, {"start": 946.96, "end": 947.52, "word": " CN", "probability": 0.65869140625}, {"start": 947.52, "end": 948.82, "word": " لاحظوا", "probability": 0.943603515625}, {"start": 948.82, "end": 949.22, "word": " هنا", "probability": 0.982421875}, {"start": 949.22, "end": 950.06, "word": " بينت", "probability": 0.6886393229166666}, {"start": 950.06, "end": 950.7, "word": " الكربون", "probability": 0.84814453125}, {"start": 950.7, "end": 951.2, "word": " الرابعة", "probability": 0.8621419270833334}, {"start": 951.2, "end": 951.46, "word": " ولا", "probability": 0.81298828125}, {"start": 951.46, "end": 951.96, "word": " لأ", "probability": 0.858642578125}, {"start": 951.96, "end": 953.1, "word": " هيصاروا", "probability": 0.8142578125}, {"start": 953.1, "end": 953.28, "word": " كام", "probability": 0.864990234375}, {"start": 953.28, "end": 954.12, "word": " كربونة؟", "probability": 0.88359375}], "temperature": 1.0}, {"id": 39, "seek": 98010, "start": 955.06, "end": 980.1, "text": "أربعة بدل تلاتة الان ال cyanide بشكل عام لو عملتله hydrolysis يا إما ب H3O plus بيمشي الحال أو ب N-A-O-H و بعدين H plus يعني يا إما بهذا ال reagent يا إما بهذا ال reagent بأي واحد منهم بيمشي بصير أسلوب", "tokens": [10721, 25513, 27884, 47525, 1211, 6055, 1211, 9307, 3660, 2423, 7649, 2423, 47463, 482, 4724, 8592, 28820, 6225, 10943, 45164, 6225, 42213, 2655, 43761, 15435, 356, 17122, 35186, 11933, 15042, 4724, 389, 18, 46, 1804, 4724, 32640, 8592, 1829, 21542, 6027, 34051, 4724, 426, 12, 32, 12, 46, 12, 39, 4032, 39182, 9957, 389, 1804, 37495, 22653, 35186, 11933, 15042, 39627, 15730, 2423, 26949, 317, 35186, 11933, 15042, 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ال cyanide بيعملها hydrolysis ال acid و بعدها شو هيصير CH3 CH2 CH2 و هذه ال C هي اللي ضالت هتصير C double bond O OH اذا انا ال chlorine حولتها ل CN و ال CN ع طول بتصير COOH", "tokens": [40228, 22653, 2423, 47463, 482, 4724, 1829, 25957, 1211, 11296, 15435, 356, 17122, 2423, 8258, 4032, 39182, 11296, 13412, 2407, 39896, 9381, 13546, 5995, 18, 5995, 17, 5995, 17, 4032, 29538, 2423, 383, 39896, 13672, 1829, 48812, 6027, 2655, 8032, 2655, 9381, 13546, 383, 3834, 6086, 422, 13931, 1975, 15730, 1975, 8315, 2423, 39888, 11331, 12610, 2655, 11296, 5296, 14589, 4032, 2423, 14589, 6225, 23032, 12610, 39894, 9381, 13546, 3002, 31187], "avg_logprob": -0.2894965298473835, "compression_ratio": 1.4457142857142857, "no_speech_prob": 0.0, "words": [{"start": 980.87, "end": 981.23, "word": "يعني", "probability": 0.852294921875}, {"start": 981.23, "end": 981.37, "word": " ال", "probability": 0.611328125}, {"start": 981.37, "end": 982.01, "word": " cyanide", "probability": 0.6546630859375}, {"start": 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متفق انه بدنيش ادخل كتير بتفاصيل يعني خليني في النتائج بمعنى لو انا اجيت سألتكم و قولتلكم انه تفاعل الطلوين والاكيومين اه انتبهوا معاك الطلوين والاكيومين مع الكيامة ال O4 both produces benzoic acid صح", "tokens": [3555, 2304, 3615, 1863, 7578, 41850, 4724, 46309, 5016, 8592, 3714, 1829, 41361, 1829, 11622, 2304, 44650, 5172, 4587, 16472, 3224, 47525, 22653, 8592, 1975, 3215, 9778, 1211, 9122, 2655, 13546, 39894, 5172, 33546, 26895, 37495, 22653, 16490, 1211, 9957, 1829, 8978, 28239, 2655, 16373, 7435, 4724, 2304, 3615, 1863, 7578, 45164, 1975, 8315, 1975, 7435, 36081, 8608, 10721, 1211, 2655, 24793, 4032, 12174, 12610, 2655, 23275, 2304, 16472, 3224, 6055, 5172, 995, 30241, 41950, 1211, 2407, 9957, 16070, 995, 4117, 1829, 20498, 9957, 1975, 3224, 16472, 2655, 3555, 3224, 14407, 20449, 995, 4117, 41950, 1211, 2407, 9957, 16070, 995, 4117, 1829, 20498, 9957, 20449, 33251, 1829, 10943, 3660, 2423, 422, 19, 1293, 14725, 44335, 78, 299, 8258, 20328, 5016], "avg_logprob": 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"word": " هذه", "probability": 0.2822265625}, {"start": 1509.25, "end": 1510.71, "word": " سلسلة", "probability": 0.9940185546875}, {"start": 1510.71, "end": 1511.87, "word": " معلقة", "probability": 0.9222005208333334}, {"start": 1511.87, "end": 1512.29, "word": " على", "probability": 0.9033203125}, {"start": 1512.29, "end": 1513.41, "word": " البنزين", "probability": 0.9908447265625}], "temperature": 1.0}, {"id": 63, "seek": 152995, "start": 1514.41, "end": 1529.95, "text": "ولذلك هذا التفاعل اسمه أكسدت السلسلة المعلقة على البنزين، مهما كبرت ومهما عظمت، ايش بتعطيني؟ acid، بس، بغض النظر عن طولها", "tokens": [12610, 8848, 23275, 23758, 16712, 5172, 995, 30241, 24525, 2304, 3224, 5551, 4117, 3794, 3215, 2655, 21136, 1211, 3794, 37977, 9673, 30241, 28671, 15844, 29739, 1863, 11622, 9957, 12399, 3714, 3224, 15042, 9122, 26890, 2655, 4032, 2304, 3224, 15042, 6225, 19913, 2304, 2655, 12399, 1975, 1829, 8592, 39894, 3615, 9566, 9957, 1829, 22807, 8258, 12399, 4724, 3794, 12399, 4724, 17082, 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{"id": 64, "seek": 155209, "start": 1531.05, "end": 1552.09, "text": "واضح؟ Oxidation of the aliphatic sided chain attached to benzene واضحة الفكرة؟ هذه طريقة لتحضير ال benzoic acid طبعا احنا جيبنا طريقة تانية باستعمال إيش؟ ال CN إذا هي كام طريقة صيرنا ذاكرين لكم؟", "tokens": [2407, 46958, 5016, 22807, 16489, 327, 399, 295, 264, 419, 24595, 2399, 41651, 5021, 8570, 281, 44335, 1450, 4032, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 29538, 23032, 16572, 28671, 5296, 2655, 5016, 11242, 13546, 2423, 44335, 78, 299, 8258, 23032, 3555, 3615, 995, 1975, 5016, 8315, 10874, 1829, 3555, 8315, 23032, 16572, 28671, 6055, 7649, 10632, 4724, 995, 14851, 25957, 6027, 11933, 1829, 8592, 22807, 2423, 14589, 11933, 15730, 39896, 9122, 10943, 23032, 16572, 28671, 20328, 13546, 8315, 29910, 995, 37983, 9957, 5296, 24793, 22807], "avg_logprob": -0.22808907874699297, "compression_ratio": 1.4313725490196079, "no_speech_prob": 0.0, "words": [{"start": 1531.05, "end": 1531.75, "word": "واضح؟", 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اكلوروبنزين", "probability": 0.771820068359375}, {"start": 1654.83, "end": 1655.51, "word": " هذه", "probability": 0.4345703125}, {"start": 1655.51, "end": 1656.11, "word": " تعلمناها", "probability": 0.9044189453125}, {"start": 1656.11, "end": 1656.27, "word": " ولا", "probability": 0.91845703125}, {"start": 1656.27, "end": 1656.59, "word": " لأ", "probability": 0.754638671875}], "temperature": 1.0}, {"id": 69, "seek": 168647, "start": 1657.29, "end": 1686.47, "text": "الكلورو بنزين لو فعلناه معي green yard مع Mg شو بيصير؟ MgCl ال MgCl بإيش بيزيد كربونا؟ بتاني أكسيد الكربون وحمد إذا بنزين كلورو بنزين طبعا كلكوا عارفين ال reaction اللي هو Cl2", "tokens": [6027, 4117, 1211, 13063, 2407, 44945, 11622, 9957, 45164, 6156, 30241, 8315, 3224, 20449, 1829, 3092, 11682, 20449, 376, 70, 13412, 2407, 4724, 1829, 9381, 13546, 22807, 376, 70, 9966, 2423, 376, 70, 9966, 4724, 28814, 1829, 8592, 4724, 1829, 11622, 25708, 9122, 25513, 2407, 8315, 22807, 4724, 2655, 7649, 1829, 5551, 4117, 3794, 25708, 33251, 25513, 11536, 4032, 35571, 3215, 11933, 15730, 44945, 11622, 9957, 9122, 1211, 13063, 2407, 44945, 11622, 9957, 23032, 3555, 3615, 995, 28242, 4117, 14407, 6225, 9640, 5172, 9957, 2423, 5480, 13672, 1829, 31439, 2033, 17], "avg_logprob": -0.2948369610568751, "compression_ratio": 1.5567567567567568, "no_speech_prob": 0.0, "words": [{"start": 1657.29, "end": 1658.13, "word": "الكلورو", "probability": 0.70382080078125}, {"start": 1658.13, "end": 1658.89, "word": " بنزين", "probability": 0.9591471354166666}, {"start": 1658.89, "end": 1659.59, "word": " لو", "probability": 0.84033203125}, {"start": 1659.59, "end": 1660.29, "word": " فعلناه", "probability": 0.8873291015625}, {"start": 1660.29, "end": 1660.59, "word": " معي", "probability": 0.55804443359375}, {"start": 1660.59, "end": 1660.79, "word": " green", "probability": 0.26611328125}, {"start": 1660.79, "end": 1661.39, "word": " yard", "probability": 0.7841796875}, {"start": 1661.39, "end": 1661.83, "word": " مع", "probability": 0.578125}, {"start": 1661.83, "end": 1662.37, "word": " Mg", "probability": 0.5423583984375}, {"start": 1662.37, "end": 1663.73, "word": " شو", "probability": 0.574951171875}, {"start": 1663.73, "end": 1667.05, "word": " بيصير؟", "probability": 0.807763671875}, {"start": 1667.05, "end": 1669.21, "word": " MgCl", "probability": 0.763671875}, {"start": 1669.21, "end": 1669.71, "word": " ال", "probability": 0.145263671875}, {"start": 1669.71, "end": 1670.83, "word": " MgCl", "probability": 0.8470052083333334}, {"start": 1670.83, "end": 1672.61, "word": " بإيش", "probability": 0.8314208984375}, {"start": 1672.61, "end": 1673.07, "word": " بيزيد", "probability": 0.972412109375}, {"start": 1673.07, "end": 1674.57, "word": " كربونا؟", "probability": 0.82021484375}, {"start": 1674.57, "end": 1675.87, "word": " بتاني", "probability": 0.704345703125}, {"start": 1675.87, "end": 1676.27, "word": " أكسيد", "probability": 0.88720703125}, {"start": 1676.27, "end": 1677.19, "word": " الكربون", "probability": 0.9752604166666666}, {"start": 1677.19, "end": 1679.95, "word": " وحمد", "probability": 0.6328125}, {"start": 1679.95, "end": 1680.99, "word": " إذا", "probability": 0.60107421875}, {"start": 1680.99, "end": 1682.11, "word": " بنزين", "probability": 0.93505859375}, {"start": 1682.11, "end": 1682.77, "word": " كلورو", "probability": 0.82855224609375}, {"start": 1682.77, "end": 1683.19, "word": " بنزين", "probability": 0.9923502604166666}, {"start": 1683.19, "end": 1683.55, "word": " طبعا", "probability": 0.9537353515625}, {"start": 1683.55, "end": 1683.89, "word": " كلكوا", "probability": 0.7298177083333334}, {"start": 1683.89, "end": 1684.31, "word": " عارفين", "probability": 0.9912109375}, {"start": 1684.31, "end": 1684.43, "word": " ال", "probability": 0.96875}, {"start": 1684.43, "end": 1684.85, "word": " reaction", "probability": 0.440185546875}, {"start": 1684.85, "end": 1685.45, "word": " اللي", "probability": 0.891845703125}, {"start": 1685.45, "end": 1685.69, "word": " هو", "probability": 0.97607421875}, {"start": 1685.69, "end": 1686.47, "word": " Cl2", "probability": 0.820068359375}], "temperature": 1.0}, {"id": 70, "seek": 171058, "start": 1693.2, "end": 1710.58, "text": "بنزين بيصير بنزويك أسد بنزين بيصير طلوين بنزويك أسد", "tokens": [3555, 1863, 11622, 9957, 4724, 1829, 9381, 13546, 44945, 11622, 45865, 4117, 5551, 3794, 3215, 44945, 11622, 9957, 4724, 1829, 9381, 13546, 23032, 1211, 2407, 9957, 44945, 11622, 45865, 4117, 5551, 3794, 3215], "avg_logprob": -0.4218750026296167, "compression_ratio": 1.6491228070175439, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1693.1999999999998, "end": 1694.6, "word": "بنزين", "probability": 0.684906005859375}, {"start": 1694.6, "end": 1696.0, "word": " بيصير", "probability": 0.57659912109375}, {"start": 1696.0, "end": 1696.56, "word": " بنزويك", "probability": 0.74359130859375}, {"start": 1696.56, "end": 1697.04, "word": " أسد", "probability": 0.77880859375}, {"start": 1697.04, "end": 1698.68, "word": " بنزين", "probability": 0.8055013020833334}, {"start": 1698.68, "end": 1706.56, "word": " بيصير", "probability": 0.7291259765625}, {"start": 1706.56, "end": 1710.08, "word": " طلوين", "probability": 0.7620849609375}, {"start": 1710.08, "end": 1710.58, "word": " بنزويك", "probability": 0.8675537109375}, {"start": 1710.58, "end": 1710.58, "word": " أسد", "probability": 0.9679361979166666}], "temperature": 1.0}, {"id": 71, "seek": 174248, "start": 1712.74, "end": 1742.48, "text": "و بعدين كيامان افور بالكيامان افور اذا هى البنزويك اسد بتلات طرق اللى بده يحفظهم اول شى يقول بنزين طلوين بنزويك اسد بنزين سيانو بنزين بنزويك اسد بنزين كلورو بنزين بنزين جرينيارد بنزويك اسد كل هذه طرق لتحضير البنزويك اسد ولا لأ كان طريقة تلاتة واضح وبهيك بننهي اليوم", "tokens": [2407, 39182, 9957, 9122, 1829, 10943, 7649, 1975, 5172, 13063, 20666, 4117, 1829, 10943, 7649, 1975, 5172, 13063, 1975, 15730, 8032, 7578, 29739, 1863, 11622, 45865, 4117, 1975, 3794, 3215, 39894, 1211, 9307, 23032, 2288, 4587, 13672, 7578, 47525, 3224, 7251, 5016, 5172, 19913, 16095, 1975, 12610, 13412, 7578, 7251, 39648, 44945, 11622, 9957, 23032, 1211, 2407, 9957, 44945, 11622, 45865, 4117, 1975, 3794, 3215, 44945, 11622, 9957, 8608, 1829, 7649, 2407, 44945, 11622, 9957, 44945, 11622, 45865, 4117, 1975, 3794, 3215, 44945, 11622, 9957, 9122, 1211, 13063, 2407, 44945, 11622, 9957, 44945, 11622, 9957, 10874, 2288, 9957, 1829, 9640, 3215, 44945, 11622, 45865, 4117, 1975, 3794, 3215, 28242, 29538, 23032, 2288, 4587, 5296, 2655, 5016, 11242, 13546, 29739, 1863, 11622, 45865, 4117, 1975, 3794, 3215, 49429, 5296, 10721, 25961, 23032, 16572, 28671, 6055, 1211, 9307, 3660, 4032, 46958, 5016, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498], "avg_logprob": -0.20157284787948557, "compression_ratio": 2.3173076923076925, "no_speech_prob": 2.086162567138672e-06, "words": [{"start": 1712.74, "end": 1712.98, "word": "و", "probability": 0.673828125}, {"start": 1712.98, "end": 1713.54, "word": " بعدين", "probability": 0.87158203125}, {"start": 1713.54, "end": 1714.16, "word": " كيامان", "probability": 0.6718597412109375}, {"start": 1714.16, "end": 1714.42, "word": " افور", "probability": 0.6837565104166666}, {"start": 1714.42, "end": 1715.14, "word": " بالكيامان", "probability": 0.828173828125}, {"start": 1715.14, "end": 1715.72, "word": " افور", "probability": 0.96142578125}, {"start": 1715.72, "end": 1716.36, "word": " اذا", "probability": 0.6888427734375}, {"start": 1716.36, "end": 1716.58, "word": " هى", "probability": 0.404541015625}, {"start": 1716.58, "end": 1717.12, "word": " البنزويك", "probability": 0.773828125}, {"start": 1717.12, "end": 1717.42, "word": " اسد", "probability": 0.6758626302083334}, {"start": 1717.42, "end": 1717.9, "word": " بتلات", "probability": 0.775390625}, {"start": 1717.9, "end": 1718.3, "word": " طرق", "probability": 0.943359375}, {"start": 1718.3, "end": 1719.22, "word": " اللى", "probability": 0.947998046875}, {"start": 1719.22, "end": 1719.42, "word": " بده", "probability": 0.82958984375}, {"start": 1719.42, "end": 1719.94, "word": " يحفظهم", "probability": 0.87294921875}, {"start": 1719.94, "end": 1720.24, "word": " اول", "probability": 0.58251953125}, {"start": 1720.24, "end": 1720.46, "word": " شى", "probability": 0.44183349609375}, {"start": 1720.46, "end": 1720.86, "word": " يقول", "probability": 0.779296875}, {"start": 1720.86, "end": 1722.48, "word": " بنزين", "probability": 0.9358723958333334}, {"start": 1722.48, "end": 1723.14, "word": " طلوين", "probability": 0.81219482421875}, {"start": 1723.14, "end": 1724.76, "word": " بنزويك", "probability": 0.97119140625}, {"start": 1724.76, "end": 1725.18, "word": " اسد", "probability": 0.7816569010416666}, {"start": 1725.18, "end": 1726.0, "word": " بنزين", "probability": 0.962890625}, {"start": 1726.0, "end": 1726.5, "word": " سيانو", "probability": 0.9013671875}, {"start": 1726.5, "end": 1727.16, "word": " بنزين", "probability": 0.9755859375}, {"start": 1727.16, "end": 1728.54, "word": " بنزويك", "probability": 0.9837646484375}, {"start": 1728.54, "end": 1728.92, "word": " اسد", "probability": 0.8642578125}, {"start": 1728.92, "end": 1729.58, "word": " بنزين", "probability": 0.9822591145833334}, {"start": 1729.58, "end": 1730.0, "word": " كلورو", "probability": 0.8541259765625}, {"start": 1730.0, "end": 1730.44, "word": " بنزين", "probability": 0.97509765625}, {"start": 1730.44, "end": 1730.96, "word": " بنزين", "probability": 0.8070475260416666}, {"start": 1730.96, "end": 1731.9, "word": " جرينيارد", "probability": 0.801513671875}, {"start": 1731.9, "end": 1732.72, "word": " بنزويك", "probability": 0.9842529296875}, {"start": 1732.72, "end": 1733.1, "word": " اسد", "probability": 0.8470052083333334}, {"start": 1733.1, "end": 1733.42, "word": " كل", "probability": 0.8798828125}, {"start": 1733.42, "end": 1733.62, "word": " هذه", "probability": 0.6982421875}, {"start": 1733.62, "end": 1734.02, "word": " طرق", "probability": 0.9109700520833334}, {"start": 1734.02, "end": 1734.86, "word": " لتحضير", "probability": 0.97138671875}, {"start": 1734.86, "end": 1735.42, "word": " البنزويك", "probability": 0.96865234375}, {"start": 1735.42, "end": 1735.72, "word": " اسد", "probability": 0.8688151041666666}, {"start": 1735.72, "end": 1735.9, "word": " ولا", "probability": 0.8134765625}, {"start": 1735.9, "end": 1736.38, "word": " لأ", "probability": 0.90087890625}, {"start": 1736.38, "end": 1737.18, "word": " كان", "probability": 0.384521484375}, {"start": 1737.18, "end": 1737.86, "word": " طريقة", "probability": 0.9195963541666666}, {"start": 1737.86, "end": 1739.32, "word": " تلاتة", "probability": 0.9237060546875}, {"start": 1739.32, "end": 1739.88, "word": " واضح", "probability": 0.9405924479166666}, {"start": 1739.88, "end": 1740.92, "word": " وبهيك", "probability": 0.74310302734375}, {"start": 1740.92, "end": 1741.68, "word": " بننهي", "probability": 0.947021484375}, {"start": 1741.68, "end": 1742.48, "word": " اليوم", "probability": 0.94921875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 1742.680875, "duration_after_vad": 1658.0512499999968}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..5a45e0f04000a7e67d6378c275e089dfdfedf37f
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.srt
@@ -0,0 +1,1184 @@
+1
+00:00:19,460 --> 00:00:24,620
+بسم الله الرحمن الرحيم بدأنا احنا المرة الماضية في
+
+2
+00:00:24,620 --> 00:00:28,220
+موضوع الأحماض الكربوكسيلية الـ carboxylic acids
+
+3
+00:00:28,220 --> 00:00:35,460
+واستعرضنا طبعا تسميتها و الحامضية لها و بدأنا في
+
+4
+00:00:35,460 --> 00:00:40,840
+موضوع تحضير الـ carboxylic acids قلنا طبعا ان في
+
+5
+00:00:40,840 --> 00:00:47,130
+عندنا اكثر من طريقة لتحضير الـ carboxylic acidsلو
+
+6
+00:00:47,130 --> 00:00:53,190
+بدنا احنا نيجي ببساطة نتخيل هالطرق هذه لتحضير ال
+
+7
+00:00:53,190 --> 00:00:59,430
+carboxylic acids بإمكانكوا تنظروا ل الأقلام اللي
+
+8
+00:00:59,430 --> 00:01:04,590
+أنا حاملهم هدولة كام قلم؟ تلاتة .. تلاتة .. تلاتة
+
+9
+00:01:04,590 --> 00:01:05,090
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+10
+00:01:05,090 --> 00:01:06,070
+تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+11
+00:01:06,070 --> 00:01:06,150
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+12
+00:01:06,150 --> 00:01:06,150
+تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+13
+00:01:06,150 --> 00:01:12,410
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+14
+00:01:12,410 --> 00:01:19,640
+.. تلاتة .. تيعني أبدأ بتلات ذرات عند اللزوم كحول
+
+15
+00:01:19,640 --> 00:01:24,020
+أو aldehyde و يطلع عندى حامض من تلات ذرات يعني
+
+16
+00:01:24,020 --> 00:01:28,520
+أبدأ بتلاته و يطلع عندى تلاته و كان هذه الطريقة
+
+17
+00:01:28,520 --> 00:01:32,480
+طريقة التساوي هي الطريقة الأولى اللى بدأنا نشرحها
+
+18
+00:01:32,480 --> 00:01:36,180
+لما اتكلمنا المرة الماضية عن الكحولات و عن ال
+
+19
+00:01:36,180 --> 00:01:40,550
+aldehydesلما اتكلمنا المرة الماضية عن الكحولات و
+
+20
+00:01:40,550 --> 00:01:45,950
+عن ال aldehydes هذه الطريقة طريقة ايش تساوي يعني
+
+21
+00:01:45,950 --> 00:01:52,330
+قداش في عندى عدد كربونات في الكحول او في ال
+
+22
+00:01:52,330 --> 00:01:56,290
+aldehyde قداش بيكونوا في ال essence يعني لو الكحول
+
+23
+00:01:56,290 --> 00:02:03,000
+كانوا تلاتة معنى ذلك هيكون اسم تبعه فيه propaneأو
+
+24
+00:02:03,000 --> 00:02:06,880
+ال الديهايد كانوا تلاتة الاسم تبعه برضه هيكون فيه
+
+25
+00:02:06,880 --> 00:02:12,760
+بروفان تلاتة الآن ال acid اللي هيطلع برضه هيكون
+
+26
+00:02:12,760 --> 00:02:19,560
+تلاتة لا هيزيد ولا هينقص خلينا نشوف هذا الكلام
+
+27
+00:02:19,560 --> 00:02:24,120
+يعني مثلا لو أخدنا CH3 CH2
+
+28
+00:02:26,930 --> 00:02:35,710
+هذا ايش؟ كحول من كام كربونة؟ ثلاثة اسمه بروبان
+
+29
+00:02:35,710 --> 00:02:41,810
+البروبان بتعبر عن العدد all الان لو بدنا اكسدة
+
+30
+00:02:41,810 --> 00:02:49,430
+بسيطة في ال BCC عند اللزوم حيصير CH3 CH2 C double
+
+31
+00:02:49,430 --> 00:02:59,080
+bond OH كام ذرة؟تلاتة هذا اللي اتكون شو اسمه?
+
+32
+00:03:02,720 --> 00:03:08,000
+Ibrobanol إذا هل تغير عدد الذرات؟ لأ لو امشينا في
+
+33
+00:03:08,000 --> 00:03:12,020
+الأكسدة بالكيامان O4 عند اللزوم أو من البداية
+
+34
+00:03:12,020 --> 00:03:20,960
+بدينا بالكيامان O4 CH3 CH2 Cضم البند O OH كم ذرة
+
+35
+00:03:20,960 --> 00:03:25,500
+كربون؟ اه هذا إيش بدو يصير؟ Ibrobanol
+
+36
+00:03:28,860 --> 00:03:35,200
+وبهيك بيصير واضح معاه أن الأفكار المتعلقة بالأكسد،
+
+37
+00:03:35,200 --> 00:03:40,920
+أكسدة الكحول، الالدهاي، الاسد، لتغير عدد درات
+
+38
+00:03:40,920 --> 00:03:46,350
+الكربونواضح الفكرة؟ ولذلك هذه الطريقة .. طريقة إيش
+
+39
+00:03:46,350 --> 00:03:51,930
+بنسميها؟ طريقة تساوي .. إنه أنا عندي تلت ذرات
+
+40
+00:03:51,930 --> 00:03:56,030
+carbon .. إنه أنا عندي تلت ذرات carbon .. هدولة
+
+41
+00:03:56,030 --> 00:03:58,570
+تلت ذرات carbon .. كانوا تلاتة .. ضالوا تلاتة ..
+
+42
+00:03:58,570 --> 00:04:04,070
+ضالوا تلاتة .. واضح الفكرة؟ طبعا للناس اللي بيحبوا
+
+43
+00:04:04,070 --> 00:04:07,890
+انزيد شوية في الكلام و في المعلومات .. أنا ممكن
+
+44
+00:04:07,890 --> 00:04:12,990
+أبدأ من التلاتةبطريقة شوية صغيرة مختلفة يعني
+
+45
+00:04:12,990 --> 00:04:20,290
+مابداش بالكحول مابداش بالكحول يا ترى لو مثلا بدأت
+
+46
+00:04:20,290 --> 00:04:27,810
+بهذا المركب لو بدأت بهذا المركب CH3 CH double bond
+
+47
+00:04:27,810 --> 00:04:35,520
+CH2جبتلكم سؤال كيف من الابروب برضه ابروب ملاحظين
+
+48
+00:04:35,520 --> 00:04:40,880
+تلاتة ابروبين how can you prepare aerobic acid
+
+49
+00:04:40,880 --> 00:04:46,340
+starting from aerobin تلاتة تلاتة تلاتة تلاتة اه
+
+50
+00:04:46,340 --> 00:04:51,720
+هتيجي واحدة تتذكر ان انا هنا بدي اضيف الميه مع ولا
+
+51
+00:04:51,720 --> 00:04:56,220
+عكس قاعدة Markovnikov طبعا عكس عكس
+
+52
+00:05:05,320 --> 00:05:10,460
+واضح الفكرة فتلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+53
+00:05:10,460 --> 00:05:11,320
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+54
+00:05:11,320 --> 00:05:11,320
+زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا
+
+55
+00:05:11,320 --> 00:05:11,320
+تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+56
+00:05:11,320 --> 00:05:11,500
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+57
+00:05:11,500 --> 00:05:13,440
+زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا
+
+58
+00:05:13,440 --> 00:05:15,280
+تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+59
+00:05:15,280 --> 00:05:19,440
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+60
+00:05:19,440 --> 00:05:28,330
+زالوا تلاتة ما زالوا تبصير acid واضح؟ الأن في هذه
+
+61
+00:05:28,330 --> 00:05:33,990
+الحالة مافيش عندى تغير في عدد ذرات الكربون فالطرق
+
+62
+00:05:33,990 --> 00:05:39,310
+المنطلقة من الأكسة ده مافيش فيها تغير بيكون بيوتان
+
+63
+00:05:39,310 --> 00:05:44,910
+بيوتانوك بيوتانول بيوتانال لكن عدد ذرات الكربون
+
+64
+00:05:44,910 --> 00:05:48,430
+إيش ماله؟ ثابت حتى لو قلت بيوتين كمان
+
+65
+00:05:55,150 --> 00:06:03,190
+الان في طرق تانية .. في طرق تانية ممكن أنه نتعامل
+
+66
+00:06:03,190 --> 00:06:09,570
+معها .. ممكن نشتغل على طريقة اسمها طريقة النقص ..
+
+67
+00:06:09,570 --> 00:06:16,000
+يعني أبدأ بتلاتةو أكسر من التلاتة هدولة و أجد
+
+68
+00:06:16,000 --> 00:06:21,820
+أبطلع بإيش نفترض ب 2 و ب 1 أكسر التلاتة أو أبدأ ب
+
+69
+00:06:21,820 --> 00:06:28,140
+4 و أكسر الأربعة ل 2 و 2 أو ل 3 و 1 هذه طريقة إيش
+
+70
+00:06:28,140 --> 00:06:33,400
+نقص أنه أنا يكون عند السلسلة الكلية السلسلة الكلية
+
+71
+00:06:33,400 --> 00:06:39,040
+أربع كربونات أطول منها 3 أو 2 أو 1 يعني أقل من إيش
+
+72
+00:06:39,560 --> 00:06:44,440
+أقل من الأربعة صارت هذه الطريقة طريقة ايش نقص طبعا
+
+73
+00:06:44,440 --> 00:06:48,660
+ايش بيظل عندنا انه ممكن تكون طريقة زيادة يعني
+
+74
+00:06:48,660 --> 00:06:53,920
+افترضوا انه سلسلة عندى أربعة وطلبت
+
+75
+00:06:53,920 --> 00:06:56,600
+منكوا تحضروا لي حمض بخمس كربونات
+
+76
+00:07:01,280 --> 00:07:08,760
+أنا قلت لكم ببساطة مبتدئا من البيوتانول البيوتانول
+
+77
+00:07:08,760 --> 00:07:14,680
+كام كربونا؟ أربعة حضرولي بنتانوك أسد الآن إذا
+
+78
+00:07:14,680 --> 00:07:19,720
+واحدة مش منتبهة تقول all oic acid تروح تعمل أكسدة
+
+79
+00:07:19,720 --> 00:07:26,520
+أه بس البيوتانول بيصير بيوتانوك أسدبزيدش Carbona
+
+80
+00:07:26,520 --> 00:07:30,960
+الان لو كنت بداجي اسألكم والله من ال Butanol
+
+81
+00:07:30,960 --> 00:07:37,890
+حضرولي Pentanoic acid زدتوا Carbonaإذا أنا بحاجة
+
+82
+00:07:37,890 --> 00:07:43,030
+إلى طريقة وبناء على ذلك للي بدوا يفهم طرق تحضير
+
+83
+00:07:43,030 --> 00:07:47,130
+الأحماض بشكل عام بنقول أن طرق تحضير الأحماض بدكوا
+
+84
+00:07:47,130 --> 00:07:51,870
+تنتبهوا تماما ممكن تكون طريقة التساوي وهذه موجودة
+
+85
+00:07:51,870 --> 00:07:55,130
+في شغل الأكسد أو الكلام اللي شرحنا الآن ممكن تكون
+
+86
+00:07:55,130 --> 00:08:01,250
+طريقة تكسير أو نقص وممكن تكون طريقة إيش؟ زيادة
+
+87
+00:08:01,250 --> 00:08:09,000
+واضحة الفكرة؟ الآن خلينا نيجيلاطرق التكثير خلّينا
+
+88
+00:08:09,000 --> 00:08:15,340
+نيجي لطرق التكثير بشكل عام نسبة من طرق التكثير مرت
+
+89
+00:08:15,340 --> 00:08:19,980
+معنا بطريقة أو باخرى ليش؟ لأنه احنا أخدنا ال
+
+90
+00:08:19,980 --> 00:08:27,460
+ozoneolysis ال ozoneolysis عادة بيكسر المركب لإيش؟
+
+91
+00:08:28,390 --> 00:08:33,650
+لأldehyde او كيتون ايه كويس الال بعد ما
+
+92
+00:08:33,650 --> 00:08:38,370
+الأوزونوليس يعني هيك انا بده اقول الكين والالكاين
+
+93
+00:08:38,370 --> 00:08:46,370
+زي الالكين بالمناسبة الكين ممكن يعطيني ايش كيتون
+
+94
+00:08:49,540 --> 00:08:53,540
+الديهايد هذا الكلام اتعلمناه ولا لأ ان الالكين
+
+95
+00:08:53,540 --> 00:08:57,600
+بيصير كيتون او الديهايد الان الكيتون اتعلمناه انه
+
+96
+00:08:57,600 --> 00:09:05,060
+لا يتأكسد اكسدة اضافية لكن ال الديهايد بتأكسد ولا
+
+97
+00:09:05,060 --> 00:09:09,860
+لأ ال الديهايد بتأكسد اكسدة اضافية بيصير ايش acid
+
+98
+00:09:09,860 --> 00:09:14,440
+الان بكل الأحوال هذا ال الديهايد هيكون اصغر من ال
+
+99
+00:09:14,440 --> 00:09:20,010
+الكين او من ال الكاين ولا لأبالتأكيد هنا هيلزمني
+
+100
+00:09:20,010 --> 00:09:25,750
+كام عملية يتموا ورا بعض عمليتين العملية الأولى ال
+
+101
+00:09:25,750 --> 00:09:31,630
+ozoneolysis و العملية التانية ال oxidation خلّيني
+
+102
+00:09:31,630 --> 00:09:35,990
+أعبّر عنها ب O بين جثين Oxidation عملية أكسدة عادة
+
+103
+00:09:35,990 --> 00:09:41,430
+بيستعملونها H2O2 الهيدروجين بيروكسايد هذه كمان
+
+104
+00:09:41,430 --> 00:09:49,310
+خلّوها H2O2أذن اوزونوليسيز followed by H2O2 يمكن
+
+105
+00:09:49,310 --> 00:09:55,050
+أن يؤدي إلى أحماض لكن أكيد هتكون أصغر من إيش؟ أصغر
+
+106
+00:09:55,050 --> 00:10:02,090
+من الألكين اللي أنا ابتدأت فيه الآن خلينا ناخد
+
+107
+00:10:02,090 --> 00:10:06,910
+مثال حقيقي ناخد مثال حقيقي لو يا ترى أخدنا هذا
+
+108
+00:10:06,910 --> 00:10:16,980
+الألكينسواء قلنا عنه CES و لا TRANS CH3 CH3H
+
+109
+00:10:16,980 --> 00:10:26,200
+CH3H و قلنا اكمل نمر واحد O3 Ozonolysis و نمر
+
+110
+00:10:26,200 --> 00:10:31,060
+اتنين H2O2 H2O2 Hydrogen Peroxide هو العامل
+
+111
+00:10:31,060 --> 00:10:39,210
+المؤكسد الان بدنا لما ننفذ نفهم الشغل الاولىكسر
+
+112
+00:10:39,210 --> 00:10:47,350
+يعني C double bond O H و CH3 زائد C double bond OH
+
+113
+00:10:47,350 --> 00:10:55,750
+و CH3 هذا ال ozonolases طب و ال acid هذا إيش؟
+
+114
+00:10:55,750 --> 00:11:00,830
+الديهايد الآن هذا ال الديهايد بال H2O2 اللي ضفناها
+
+115
+00:11:00,830 --> 00:11:08,760
+إيش حيصير؟ C double bond O OHCH3 وجدت حصلنا على
+
+116
+00:11:08,760 --> 00:11:14,980
+الاسيتك أسد الاسيتك أسد كده؟ كربون 2 يعني كأنه انا
+
+117
+00:11:14,980 --> 00:11:18,820
+بال اوزونوليسيز اتيت كصرت الأربعة هدولة اتنين و
+
+118
+00:11:18,820 --> 00:11:23,400
+اتنين طلعوا عندي ألديهيد الآن كملت أكسدت الألديهيد
+
+119
+00:11:23,400 --> 00:11:29,060
+صار اسيتك أسد فمن الأربعة حصلت على حامض من كام
+
+120
+00:11:29,060 --> 00:11:37,890
+كربون؟ تنتين واضحة الفكرة؟ طبعا الآناللي ممكن
+
+121
+00:11:37,890 --> 00:11:44,390
+يفكروا انه نتعمق معهم بمثل هذه الفكرة ممكن نيجي
+
+122
+00:11:44,390 --> 00:11:49,910
+نسألهم، مانقول هم مش مبتدئان من ال 2 بيوتين، لو
+
+123
+00:11:49,910 --> 00:11:55,930
+بدأت من ال one بيوتين، هيطلع عند أحمد واحد و تلاتة
+
+124
+00:11:56,580 --> 00:12:00,520
+لأن هذه هتكسر كربونا و هدول يكونوا تلاتة لكن لو
+
+125
+00:12:00,520 --> 00:12:07,080
+انا اجيت و قولتلكم والله من مركب زي هذا CH3 CH2 CH
+
+126
+00:12:07,080 --> 00:12:15,560
+سواء حطيت هنا CL او OH اتخيلوا ان انا اجي اقولكم
+
+127
+00:12:15,560 --> 00:12:23,720
+من two chlorobutane حضروا لي acidic acid واضح او
+
+128
+00:12:23,720 --> 00:12:28,880
+من two butanolبتكون تعملوا elimination الان ال CL
+
+129
+00:12:28,880 --> 00:12:32,320
+و ال H بيروحوا و بيعطينا ال more substituted
+
+130
+00:12:32,320 --> 00:12:37,280
+باستعمال ايش طلعت
+
+131
+00:12:37,280 --> 00:12:44,240
+انا ال alkyd و بعدين كسرت ال alkyd هذه الطرق و مع
+
+132
+00:12:44,240 --> 00:12:47,020
+ال triple bond نفس الاشي زي ال double bond هذه
+
+133
+00:12:47,020 --> 00:12:52,180
+الطرق تعتبر طرق ايشانقاس يعني كان عندى اربع
+
+134
+00:12:52,180 --> 00:12:56,720
+كربونات اعملت حامض من كربونتين اعملت حامض من تلات
+
+135
+00:12:56,720 --> 00:13:02,840
+كربونات حسب موقع ايش ال bubble bond بس بشرط انه
+
+136
+00:13:02,840 --> 00:13:06,660
+يكون من نتائج ال ozonosis انه بتكون aldehyde ليش؟
+
+137
+00:13:06,660 --> 00:13:10,820
+لأن اللى بيكمل وبيتأكسد ال aldehyde الكيتون بقولنا
+
+138
+00:13:10,820 --> 00:13:16,140
+فيه إله أكسدة إضافية؟ لأ واضحة الفكرة؟ اللى بيكمل
+
+139
+00:13:16,140 --> 00:13:21,210
+وبيتأكسد هو مين؟الالديهايد وهذا الكلام أخدناه في
+
+140
+00:13:21,210 --> 00:13:24,090
+أكسدة الالديهايد والكيتونز قلنا الالديهايد بتصير
+
+141
+00:13:24,090 --> 00:13:30,430
+أحمار الكيتونز لاتت أكسد أكسدة إضافية واضحة الفكرة
+
+142
+00:13:30,430 --> 00:13:37,150
+طيب
+
+143
+00:13:37,150 --> 00:13:45,300
+إذا عرفنا طريقة المساواة وطريقةالنقص ايش ضال
+
+144
+00:13:45,300 --> 00:13:51,140
+عندنا؟ طريقة الزيادة بمعنى لو انا اجيت وقلتلكم لو
+
+145
+00:13:51,140 --> 00:13:56,240
+سمحتوا من تلت كربونات بدي احضر حامض من اربع
+
+146
+00:13:56,240 --> 00:14:03,000
+كربونات عادة الزيادة اللي احنا بنعملها زيادة سهلة
+
+147
+00:14:03,480 --> 00:14:07,900
+ليه؟ كربونة واحدة هي اللي بتتم بسهولة يعني التلاتة
+
+148
+00:14:07,900 --> 00:14:13,160
+يصيروا أربعة، الأربعة يصيروا خمسة، الخمسة يصيروا
+
+149
+00:14:13,160 --> 00:14:17,680
+ستة كيف هذا الكلام .. كيف هذا الكلام بتم؟ هذا
+
+150
+00:14:17,680 --> 00:14:26,500
+الكلام عادة بتتممنطلقين فيه من ال الكل هلاي من ال
+
+151
+00:14:26,500 --> 00:14:33,040
+one chloro compound واضح يعني بدي مركب سلسلة يكون
+
+152
+00:14:33,040 --> 00:14:39,300
+على موقع واحد فيها إيش إكلور بدي سلسلة على موقع
+
+153
+00:14:39,300 --> 00:14:47,340
+واحد فيها إكلور يعني مثلا زي ما اقول CH3 CH2 CH2
+
+154
+00:14:47,340 --> 00:14:56,390
+CLالان الكلور هانا وين؟ على موقع واحد هذا الكلور
+
+155
+00:14:56,390 --> 00:15:00,050
+مكانه بدي ازيد كربونا اللي هي بده تكون حاملة
+
+156
+00:15:00,050 --> 00:15:06,320
+مجموعة الاسم عدد الكربونات الكل يعني قداشتلاتة بدي
+
+157
+00:15:06,320 --> 00:15:11,720
+أحضر من هذا butanoic acid يعني كام كربونا؟ أربعة
+
+158
+00:15:11,720 --> 00:15:16,640
+في عندى طريقتين ممكنين في عندى طريقتين ممكنين
+
+159
+00:15:16,640 --> 00:15:22,920
+الطريقة الأولى أنه أنا هذا أجي أفعله مع CN minus
+
+160
+00:15:22,920 --> 00:15:28,140
+والطريقة التانية أنه أنا هذا أفعله مع green yard
+
+161
+00:15:28,140 --> 00:15:34,560
+reagentمار عليكم المغنيسيا من اللي بيعطي RMGX طيب
+
+162
+00:15:34,560 --> 00:15:38,720
+لو فعلنا مع ال cyanide شو بده يصير هذا؟ بده يصير
+
+163
+00:15:38,720 --> 00:15:49,220
+CH3 CH2 CH2 و هنا بده تيجي مجموعة ال CN لاحظوا هنا
+
+164
+00:15:49,220 --> 00:15:54,120
+بينت الكربون الرابعة ولا لأ هيصاروا كام كربونة؟
+
+165
+00:15:55,060 --> 00:16:02,160
+أربعة بدل تلاتة الان ال cyanide بشكل عام لو عملتله
+
+166
+00:16:02,160 --> 00:16:11,340
+hydrolysis يا إما ب H3O plus بيمشي الحال أو ب N-A
+
+167
+00:16:11,340 --> 00:16:15,840
+-O-H و بعدين H plus يعني يا إما بهذا ال reagent يا
+
+168
+00:16:15,840 --> 00:16:20,100
+إما بهذا ال reagent بأي واحد منهم بيمشي بصير أسلوب
+
+169
+00:16:20,870 --> 00:16:24,310
+يعني ال cyanide بيعملها hydrolysis ال acid و بعدها
+
+170
+00:16:24,310 --> 00:16:34,310
+شو هيصير CH3 CH2 CH2 و هذه ال C هي اللي ضالت هتصير
+
+171
+00:16:34,310 --> 00:16:41,610
+C double bond O OH اذا انا ال chlorine حولتها ل CN
+
+172
+00:16:41,610 --> 00:16:48,530
+و ال CN ع طول بتصير COOHهذه طريقة معروفة وجيدة
+
+173
+00:16:48,530 --> 00:16:53,750
+لعمل هذا المُركّب طيب الطريقة التانية .. بدأ أزيد
+
+174
+00:16:53,750 --> 00:16:58,310
+كربونا لسه .. أنا لو فعلت مع المغنيسيوم .. هذا إيش
+
+175
+00:16:58,310 --> 00:17:04,750
+هيعطيني؟ الـ Grignard Reagent .. كلكم اتذكرينه؟CH3
+
+176
+00:17:04,750 --> 00:17:13,470
+CH2 CH2 وقلنا هذه اهم اشي فيها MgCl هاي Green Yard
+
+177
+00:17:13,470 --> 00:17:18,630
+Ray Agent إبروبيل مغنيسيا ميكلورايد صح؟ الآن هذا
+
+178
+00:17:18,630 --> 00:17:25,330
+ال Green Yard Ray Agent بفعله مع نمرة واحد CO2
+
+179
+00:17:25,330 --> 00:17:28,250
+لاحظوا هاي ال C double bond O double bond O ثاني
+
+180
+00:17:28,250 --> 00:17:29,030
+أكسيد كربون
+
+181
+00:17:31,920 --> 00:17:38,840
+واضح؟ ونمر اتنين خليني ال CO2 ارسمه بالاحمر بفعله
+
+182
+00:17:38,840 --> 00:17:43,220
+مع ال CO2 يعني C double bond O double bond O ونمر
+
+183
+00:17:43,220 --> 00:17:49,000
+اتنين مع H بلس بيعطيني الحامض اللي هتقولولي من وين
+
+184
+00:17:49,000 --> 00:17:54,710
+اجت الكربونة؟هي من الـ CO2 مش الـ C حاملة انتن
+
+185
+00:17:54,710 --> 00:17:59,370
+أكسجين وهنا إيش زاد عندي؟ C double bond O OH
+
+186
+00:17:59,370 --> 00:18:06,590
+ببساطة هذا نيوكليوفايل بيهاجم هنا بيهاجم على
+
+187
+00:18:06,590 --> 00:18:09,990
+الكربون الموجبة مش الكربون بتاع تاني أكسيد الكربون
+
+188
+00:18:09,990 --> 00:18:15,050
+الموجبة لأنه جنبها مجموعتين سالبات لما يهاجم هذا
+
+189
+00:18:15,050 --> 00:18:20,250
+بتصير O minus ومن ال H plus بتاخد H إيش بتصير؟ OH
+
+190
+00:18:21,350 --> 00:18:27,040
+إذا هنا مصدر الكربونة الجديدة إيش بيكون؟الـ CO2
+
+191
+00:18:27,040 --> 00:18:31,720
+إذا أنا لما بدي أعمل الزيادة بدي مصدر للكربونة
+
+192
+00:18:31,720 --> 00:18:36,540
+الجديدة مصدر الكربونة الجديدة يا بدي يكون ال CN و
+
+193
+00:18:36,540 --> 00:18:39,340
+بعدين أعمل ال hydrolysis يا بعمل ال green yard
+
+194
+00:18:39,340 --> 00:18:43,280
+reagent و الكربونة الجديدة بجيبها من وين؟ من ال
+
+195
+00:18:43,280 --> 00:18:50,340
+CO2 واضح الفكرة؟ الآن مرة تانية مش ضروري تكون نقطة
+
+196
+00:18:50,340 --> 00:18:57,860
+البداية اللي عندى هي هذا المركب الكلوريممكن تكون
+
+197
+00:18:57,860 --> 00:19:02,180
+نقطة البداية الكحول الان الكحول بقدر اخليك low
+
+198
+00:19:02,180 --> 00:19:07,140
+right في الخطوة الأولى بالإبدال كحول مع O H minus
+
+199
+00:19:07,140 --> 00:19:17,960
+بيعمل إبدال ممكن تكون نقطة البداية الالكين هذه
+
+200
+00:19:17,960 --> 00:19:19,900
+الالكين بتلت كربونات
+
+201
+00:19:29,710 --> 00:19:35,570
+واضحة الفكرة فهذه
+
+202
+00:19:35,570 --> 00:19:41,830
+طرق الزيادة اللى عادة بنستعملها من خلال ال CN أو
+
+203
+00:19:41,830 --> 00:19:42,630
+ال CO2
+
+204
+00:19:52,800 --> 00:19:54,940
+هنا على السلسلة هذه
+
+205
+00:20:03,960 --> 00:20:08,640
+لأ لأ لأ لأ لأ ال chlorineation ال chlorineation
+
+206
+00:20:08,640 --> 00:20:13,260
+على السلسلة أخدناها ب CL2 في وجود ضوء أو حرارة أو
+
+207
+00:20:13,260 --> 00:20:16,560
+من خلال الإضافة ع ال double bond يعني ال chlorine
+
+208
+00:20:16,560 --> 00:20:20,600
+مع ال FeCl3 هذا على ال aromatic compounds هذا على
+
+209
+00:20:20,600 --> 00:20:28,580
+ال aromatic compounds تمام بضل في عندى ال benzoic
+
+210
+00:20:28,580 --> 00:20:35,710
+acidعارفين البنزويك أسد؟ كيف ممكن نحضر البنزويك
+
+211
+00:20:35,710 --> 00:20:40,970
+أسد؟ و مرات ممكن نسأل كيف ممكن تحضروا البنزويك أسد
+
+212
+00:20:40,970 --> 00:20:44,370
+من البنزين هاي البنزويك أسد
+
+213
+00:20:53,780 --> 00:20:59,240
+سهلة ان لو انا عندى cyanobenzene بصير benzoic acid
+
+214
+00:20:59,240 --> 00:21:05,480
+هذه الطريقة خلينى نقول ايش مالها سهلة CN اذا عندى
+
+215
+00:21:05,480 --> 00:21:11,740
+cyanobenzene في وجود H plus او NaOH نمرة واحد و
+
+216
+00:21:11,740 --> 00:21:15,320
+نمرة اتنين H plus زى ما حكينا قبل شوية ال
+
+217
+00:21:15,320 --> 00:21:21,420
+cyanobenzene بصير acid فيها مشكلةطبعا هيصير السؤال
+
+218
+00:21:21,420 --> 00:21:26,080
+كيف يتحضر السيانو بنزين .. سيانو بنزين في شبطر 11
+
+219
+00:21:26,080 --> 00:21:31,510
+بنتعلم تحضيرهبيجيش مباشر بقتش CN لأ اللي طريقة
+
+220
+00:21:31,510 --> 00:21:37,250
+التفافية ال CN و البنزين بيجيش بشكل مباشر بتحضرش
+
+221
+00:21:37,250 --> 00:21:41,630
+بشكل مباشر انه بنزين ماقتش CN ليش؟ لإن ال CN minus
+
+222
+00:21:41,630 --> 00:21:45,590
+و البنزين حاملة إلكترونات بيهاجمش minus على minus
+
+223
+00:21:45,590 --> 00:21:51,270
+طمام الطريقة التانية انه لو احنا أخدنا .. نخلص من
+
+224
+00:21:51,270 --> 00:21:56,770
+هذه الطريقة و نمحاها لو احنا أخدنا أي بنزين بيحمل
+
+225
+00:21:56,770 --> 00:22:02,490
+ال kilogramإيش في بنزين بيحمل الكل جروب؟ الطلوين
+
+226
+00:22:02,490 --> 00:22:05,670
+صح؟
+
+227
+00:22:05,670 --> 00:22:13,890
+CH3 إيش ممكن كمان؟ ال F البنزين CH2 CH3 إيش كمان
+
+228
+00:22:13,890 --> 00:22:26,110
+ممكن؟ القيومين CH CH3 CH3 كل هدولة بيحملوهالكلي
+
+229
+00:22:26,110 --> 00:22:29,950
+جروبز ممكن حد يفكر كمان بال تيرتشار بيوت البنزين
+
+230
+00:22:29,950 --> 00:22:36,610
+ممكن حد يفكر بال تيرتشار بيوت البنزين الآن بنقول
+
+231
+00:22:36,610 --> 00:22:43,230
+القاتل لو استعملنا عام المؤكسد بشكل عام ال KMnO4
+
+232
+00:22:43,230 --> 00:22:48,710
+برمجانات البوتاسيوم مع أي ألكل بنزين مع أي ألكل
+
+233
+00:22:48,710 --> 00:22:54,480
+بنزين بس بشرطالكربون المتصل على البنزين مباشرة
+
+234
+00:22:54,480 --> 00:22:59,040
+تحتوي على ذرة هيدروجين على اقل تقدير الان هذه
+
+235
+00:22:59,040 --> 00:23:03,540
+الكربون .. كم هيدروجين بتحمل؟ تلاتة .. هذه .. هذه
+
+236
+00:23:03,540 --> 00:23:08,000
+.. هذه .. ولا واحدة .. اذا هدولة التلاتة بيمشي
+
+237
+00:23:08,000 --> 00:23:14,540
+حالهمأى واحدة من هدول بالأكسدة بكامان of four
+
+238
+00:23:14,540 --> 00:23:18,820
+بتعطينا بنزويك أسل الان انتبهوا معي لنقطة كتير
+
+239
+00:23:18,820 --> 00:23:26,100
+مهمة انه بغض النظر عن طول السلسلة هنطلع بس بنزويك
+
+240
+00:23:26,100 --> 00:23:30,960
+أسل يعني لو كان هنا مثل او اثل او بروبل او بيوتل
+
+241
+00:23:30,960 --> 00:23:34,760
+كربونة او تنتين او تلاتة او اربعة او خمسة او عشرة
+
+242
+00:23:35,740 --> 00:23:40,220
+بس هطلعوا إيش ال benzoic acid مرات كتير لما بنيجي
+
+243
+00:23:40,220 --> 00:23:44,620
+بنسأل الطلاب بنقولهم الله أعملونا أكسدة بنزين حامل
+
+244
+00:23:44,620 --> 00:23:47,340
+تلت كربونات بيروحوا بيخلوا الكربونتين و بيعملوا
+
+245
+00:23:47,340 --> 00:23:51,640
+الأكسدة على التالتة افهمتوا الغلطة اللي بحكيها ولا
+
+246
+00:23:51,640 --> 00:24:00,600
+أوضحها أكتر لما أجي أرسملهم مركب زي هذا CH2 CH2
+
+247
+00:24:00,600 --> 00:24:07,120
+CH3 و أقولهم بالكمان O4الآن الغلطة اللي بيعملوه
+
+248
+00:24:07,120 --> 00:24:11,900
+بيعملوا ال acid هانا و بيخلوها دولة الجواب الصحيح
+
+249
+00:24:11,900 --> 00:24:15,620
+انه سواء كانوا دول واحدة او تنتين او تلاتة او
+
+250
+00:24:15,620 --> 00:24:20,720
+اربعة او عشرة بس بتكون عند هانا مجموعة ال acid
+
+251
+00:24:20,720 --> 00:24:27,240
+COOHبمعنى أنا بشرحش ميكانيزم متفق انه بدنيش ادخل
+
+252
+00:24:27,240 --> 00:24:31,180
+كتير بتفاصيل يعني خليني في النتائج بمعنى لو انا
+
+253
+00:24:31,180 --> 00:24:38,120
+اجيت سألتكم و قولتلكم انه تفاعل الطلوين والاكيومين
+
+254
+00:24:38,120 --> 00:24:42,120
+اه انتبهوا معاك الطلوين والاكيومين مع الكيامة ال
+
+255
+00:24:42,120 --> 00:24:47,990
+O4 both produces benzoic acid صحبينما لو كان
+
+256
+00:24:47,990 --> 00:24:52,390
+السؤال تفاعل الطلوين والـ tertiary بيوت البنزين
+
+257
+00:24:52,390 --> 00:24:56,490
+هذا لأ لأن هذا مافيش عليه هيدروجينة على الكاربون
+
+258
+00:24:56,490 --> 00:25:03,190
+المتصلة مباشرة بالبنزينة واضحة الفكرة؟ فعشان اتم
+
+259
+00:25:03,190 --> 00:25:06,810
+هذا النوع من الأكسدة هذا بنسميه oxidation of the
+
+260
+00:25:06,810 --> 00:25:12,290
+aliphatic sided chain مش هذه سلسلة معلقة على
+
+261
+00:25:12,290 --> 00:25:18,730
+البنزينولذلك هذا التفاعل اسمه أكسدت السلسلة
+
+262
+00:25:18,730 --> 00:25:24,110
+المعلقة على البنزين، مهما كبرت ومهما عظمت، ايش
+
+263
+00:25:24,110 --> 00:25:31,750
+بتعطيني؟ acid، بس، بغض النظر عن طولهاواضح؟
+
+264
+00:25:31,750 --> 00:25:36,530
+Oxidation of the aliphatic sided chain attached to
+
+265
+00:25:36,530 --> 00:25:41,330
+benzene واضحة الفكرة؟ هذه طريقة لتحضير ال benzoic
+
+266
+00:25:41,330 --> 00:25:46,570
+acid طبعا احنا جيبنا طريقة تانية باستعمال إيش؟ ال
+
+267
+00:25:46,570 --> 00:25:54,040
+CN إذا هي كام طريقة صيرنا ذاكرين لكم؟طريقة السيانة
+
+268
+00:25:54,040 --> 00:26:00,060
+جيبناها ولا لأ؟ طيب خلينا نمحا كل هالكلام ونقول لو
+
+269
+00:26:00,060 --> 00:26:05,320
+إجاكم السؤال في الامتحان ابتلى الطرق حضرولي ال
+
+270
+00:26:05,320 --> 00:26:08,440
+benzoic acid هتقولوا ال aliphatic side chain هذه
+
+271
+00:26:08,440 --> 00:26:12,620
+كلها طريقة حتى لو من البنزين بقول بنزين طلوين
+
+272
+00:26:13,730 --> 00:26:17,930
+بنزويك أسد واضح؟ لما أقولكوا بدي بنزويك أسد من
+
+273
+00:26:17,930 --> 00:26:23,090
+البنزين، شو هانمشي؟ بنزين طول وين؟ بنزويك أسد
+
+274
+00:26:23,090 --> 00:26:28,750
+صعبة؟ من السيان و بنزين؟ ابنعملها طب لو قولنا بدنا
+
+275
+00:26:28,750 --> 00:26:33,090
+طريقة تالتة من البنزين
+
+276
+00:26:39,040 --> 00:26:48,920
+طريقة تالتة بد بنزويك أسد من البنزين واضحة
+
+277
+00:26:48,920 --> 00:26:58,260
+الفكرة هي بنزين بد يصير بنزويك أسد حسب ما اتعلمنا
+
+278
+00:26:58,260 --> 00:27:03,900
+لاحظوا ما بين البنزين
+
+279
+00:27:03,900 --> 00:27:09,650
+و بنزويك أسد زيادة كربونةولذلك .. و لذلك احنا قلنا
+
+280
+00:27:09,650 --> 00:27:17,870
+بطريقة ما هذه لما صارت سيانو اقدرنا
+
+281
+00:27:17,870 --> 00:27:21,330
+نحولها ل acid بس مااخدناش الطريقة اللي بتخليها
+
+282
+00:27:21,330 --> 00:27:24,970
+سيانو لحتى الان الان ما طريقة الزيادة التانية
+
+283
+00:27:24,970 --> 00:27:34,830
+اللتي تعلمناها اغرينيا اذا هذا يصير اكلوروبنزين
+
+284
+00:27:34,830 --> 00:27:40,590
+هذه تعلمناها ولا لأالكلورو بنزين لو فعلناه معي
+
+285
+00:27:40,590 --> 00:27:47,050
+green yard مع Mg شو بيصير؟
+
+286
+00:27:47,050 --> 00:27:56,270
+MgCl ال MgCl بإيش بيزيد كربونا؟ بتاني أكسيد
+
+287
+00:27:56,270 --> 00:28:03,890
+الكربون وحمد إذا بنزين كلورو بنزين طبعا كلكوا
+
+288
+00:28:03,890 --> 00:28:06,470
+عارفين ال reaction اللي هو Cl2
+
+289
+00:28:13,200 --> 00:28:26,560
+بنزين بيصير بنزويك أسد بنزين بيصير
+
+290
+00:28:26,560 --> 00:28:30,080
+طلوين
+
+291
+00:28:30,080 --> 00:28:36,360
+بنزويك أسدو بعدين كيامان افور بالكيامان افور اذا
+
+292
+00:28:36,360 --> 00:28:40,460
+هى البنزويك اسد بتلات طرق اللى بده يحفظهم اول شى
+
+293
+00:28:40,460 --> 00:28:47,160
+يقول بنزين طلوين بنزويك اسد بنزين سيانو بنزين
+
+294
+00:28:47,160 --> 00:28:52,720
+بنزويك اسد بنزين كلورو بنزين بنزين جرينيارد بنزويك
+
+295
+00:28:52,720 --> 00:28:57,180
+اسد كل هذه طرق لتحضير البنزويك اسد ولا لأ كان
+
+296
+00:28:57,180 --> 00:29:02,480
+طريقة تلاتة واضح وبهيك بننهي اليوم
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d1090a3474a98c8683203dd61caabc5e96ad64d8
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_postprocess.srt
@@ -0,0 +1,1904 @@
+1
+00:00:20,210 --> 00:00:23,950
+بسم الله الرحمن الرحيم بنبدأ اليوم بالفصل السابع
+
+2
+00:00:23,950 --> 00:00:30,470
+هتلاحظوا أنه يعني هنركز كعائلة أساسية فيه على
+
+3
+00:00:30,470 --> 00:00:35,650
+مركبات ال alcohols اللي بنسميها بالعربي الكحولات
+
+4
+00:00:35,650 --> 00:00:42,850
+الآن بعض الكتب اللي بتدرس باللغة العربية هتلاقوها
+
+5
+00:00:42,850 --> 00:00:49,720
+موجودة باسم الأغوالإذا مرت عليكم هذه الكلمة يعني
+
+6
+00:00:49,720 --> 00:00:52,920
+الناس اللي جاي من السعودية بدهم يدرسوا عن ال
+
+7
+00:00:52,920 --> 00:00:57,020
+alcohols الكحولات بدل ما يقولوا الكحولات بيقولوا
+
+8
+00:00:57,020 --> 00:01:03,200
+إيش الأغوال جامع غول و بيستندوا للنص القرآن لا
+
+9
+00:01:03,200 --> 00:01:08,760
+فيها غولولهم عنها ينزفون واضح الفكرة فإذا قرأتها
+
+10
+00:01:08,760 --> 00:01:14,800
+بكتاب عربي باسم الأغوال فهي الكحولات، الآن ككيميا
+
+11
+00:01:14,800 --> 00:01:23,080
+الكحولات هي المركبات اللي ماخدة صيغة Rواضح الان
+
+12
+00:01:23,080 --> 00:01:30,020
+بيجي معها ال phenols إذا كانت ال OH متصلة بحلقة
+
+13
+00:01:30,020 --> 00:01:35,020
+أروماتية البنزين حالة خاصة بيكون نفس ال phenol لكن
+
+14
+00:01:35,020 --> 00:01:42,920
+المجموعة العامة AR بشكل عام ال AR OH يعني كل
+
+15
+00:01:42,920 --> 00:01:47,580
+المركبات الأروماتية إذا اتصلت ب OH they are
+
+16
+00:01:47,580 --> 00:01:55,420
+phenolsموازي لل alcohols لكن بإبدال ال oxygen هادى
+
+17
+00:01:55,420 --> 00:02:01,200
+ب Sulphur بيصير المركب ثيول بيصير المركب ثيول يعني
+
+18
+00:02:01,200 --> 00:02:08,060
+ماخد الصيغة العامة R RSH ثيولز ماخد الصيغة العامة
+
+19
+00:02:08,060 --> 00:02:15,060
+RSH طبعا اكيد هتقولوا طيب في موازي لل phenol بمعنى
+
+20
+00:02:15,060 --> 00:02:16,580
+اخر ايش بدى يكون ماخد AR
+
+21
+00:02:19,820 --> 00:02:25,320
+SH موجود أيضا بنسميه Theophenol
+
+22
+00:02:27,210 --> 00:02:33,170
+واضح؟ فهذه العائلات اللي طبعا الأساس فيها عائلة
+
+23
+00:02:33,170 --> 00:02:37,390
+الكحولات يعني هيكون التركيز الأكبر على الكحولات
+
+24
+00:02:37,390 --> 00:02:41,030
+اللي هي المركبات اللي ماخدة الصيغة العامة ROH من
+
+25
+00:02:41,030 --> 00:02:47,210
+الطرق بشكل خفيف للphenols للthiols للthiophenols
+
+26
+00:02:47,210 --> 00:02:53,270
+كل هذه الأشياء ان شاء الله بنقشها في هذا الفصل
+
+27
+00:02:56,090 --> 00:03:00,990
+إذا بدأنا بالكحولات .. إذا بدأنا بالكحولات و أول
+
+28
+00:03:00,990 --> 00:03:06,430
+شغلة دايما بنبدأ فيها كيف نسمي المركبات عادة بنسمي
+
+29
+00:03:06,430 --> 00:03:12,190
+الكحولات بإضافة النهاية all لاحظوا أن نظام التسمية
+
+30
+00:03:12,190 --> 00:03:15,910
+.. نظام التسمية في ال organ chemistry للناس اللي
+
+31
+00:03:15,910 --> 00:03:22,120
+بيتقنوه هو نظامبسيط جدا يعني مئات إذا ما قلناش
+
+32
+00:03:22,120 --> 00:03:27,540
+ملايين المراكبات الإنسان بتعلم قواعد بسيطة جدا
+
+33
+00:03:27,540 --> 00:03:32,840
+للتسمية وبيقدر يسيطر عليها الآن المفروض مع هذا
+
+34
+00:03:32,840 --> 00:03:37,440
+الوقت أنه صار نظام التسمية بالنسبة لناواضح في
+
+35
+00:03:37,440 --> 00:03:42,560
+عندنا سلسلة كربونية بدنا ناخد العدد تبعها بالنهاية
+
+36
+00:03:42,560 --> 00:03:48,980
+ميثين إيثين بروبين بيوتين بيوتين هكسين هبتين هدوله
+
+37
+00:03:48,980 --> 00:03:53,300
+صرنا حافظينهم الآن هذا الكلام إذا كانت السلسلة
+
+38
+00:03:53,300 --> 00:03:56,840
+كلها روابط أحدية وقلنا الkins الآن إذا صرنا في
+
+39
+00:03:56,840 --> 00:04:02,900
+الروابط الثنائية بنغير بنحط in بدل ال in في
+
+40
+00:04:02,900 --> 00:04:09,610
+الروابط الثلاثيةI الآن في الكحولات بنحط نهاية all
+
+41
+00:04:09,610 --> 00:04:14,450
+بعد شوية هنتعلم في ال aldehydes بنحط نهاية L في ال
+
+42
+00:04:14,450 --> 00:04:19,430
+ketone بنحط نهاية on في الأحماض الكربوكسيلية بنحط
+
+43
+00:04:19,430 --> 00:04:24,390
+نهاية oic acid بمعنى لو أنا رسمت خمس درات كربون
+
+44
+00:04:24,390 --> 00:04:29,690
+بقدر اقول ان المركبات اللي منهم عند اللزوم مثيل
+
+45
+00:04:30,860 --> 00:04:39,680
+للألكين ميثين اعفوا بنتين I mean بنتين بنتين بنتين
+
+46
+00:04:39,680 --> 00:04:42,860
+طبعا بحدد وين موقع ال double bond ده قصة بسيطة
+
+47
+00:04:42,860 --> 00:04:50,580
+بنتاي بنتانول بنتانال لل الديهايد بنتانون لل كيتون
+
+48
+00:04:50,580 --> 00:04:56,970
+بنتانوك أسد فصارت القصة فقط هي نهايةبتتغير في
+
+49
+00:04:56,970 --> 00:05:01,750
+نهاية الاسم و بنقدر نسمي المراكبات انتبهوا جيدا ان
+
+50
+00:05:01,750 --> 00:05:05,870
+ال all اللي بنستعمله انه نهاية الكحولات مافيش فيها
+
+51
+00:05:05,870 --> 00:05:13,330
+E في الآخر يعني OL بدون E ليش هتوجهنا المراكبات
+
+52
+00:05:13,770 --> 00:05:20,050
+بتنتهي ب OLE هذه مركبات حلقية تحتوي على حلقات
+
+53
+00:05:20,050 --> 00:05:24,430
+خماسية خارج موضوع دراستنا زي لما تسمعوا عن بعض
+
+54
+00:05:24,430 --> 00:05:29,870
+الأدوية مثلا المضادة للفطريات الدكتازول
+
+55
+00:05:29,870 --> 00:05:33,690
+والفلوكانازول الناس اللي عندهم فطريات أحيانا بين
+
+56
+00:05:33,690 --> 00:05:39,560
+أصابع رجليهم بيشتريوامضاد للفطريات دكتازول مشهور
+
+57
+00:05:39,560 --> 00:05:45,040
+كتير في البلد flucanazole هدولة هتلاحظوا اسمهم OLE
+
+58
+00:05:45,040 --> 00:05:50,580
+OLE هذه عائلة ثانية عائلة مركبات بحلقات يشمالها
+
+59
+00:05:50,580 --> 00:05:56,980
+خماسية فالكحولات اللي عندنا نهايتهم all الان لو
+
+60
+00:05:56,980 --> 00:06:03,680
+اجينا بدنا نسمي ب carbon واحد هنقول مثان allو هكذا
+
+61
+00:06:03,680 --> 00:06:08,060
+الان لاحظوا ال common nomenclature و مرات كتير
+
+62
+00:06:08,060 --> 00:06:12,920
+بنقولكوا ايش الاسم الشائع للمركب ايضا لها بشكل عام
+
+63
+00:06:12,920 --> 00:06:19,800
+قاعدة القاعدة تبعتها ذكر المجموعة ال alkyl group و
+
+64
+00:06:19,800 --> 00:06:25,300
+بعدين بنحط نهاية يعني لو كان هذا المركب CH3Cl كنت
+
+65
+00:06:25,300 --> 00:06:28,800
+اقول ال common nomenclature له مثل ال chloride
+
+66
+00:06:28,800 --> 00:06:35,950
+الان لما بيصير CH3OHمثل و ال OH عائلة الألكوهول
+
+67
+00:06:35,950 --> 00:06:40,250
+فبصير مثل ألكوهول و هكذا ف ال common nomenclature
+
+68
+00:06:40,250 --> 00:06:48,750
+بشكل عام بتيجي بذكر المجموعة و بعدها العائلة واضح؟
+
+69
+00:06:48,750 --> 00:06:52,590
+نفس الاشي هتلاحظوا مثلا في ال aldehydes
+
+70
+00:06:52,590 --> 00:07:00,950
+بروبلالديهيد مثلا بروبل المجموعة الديهيدالعائلة و
+
+71
+00:07:00,950 --> 00:07:06,830
+بال كيتون و بال أسد و بال كلورايتس و بالبرومايتس
+
+72
+00:07:08,520 --> 00:07:13,980
+توجه عام الان لو اتيت هنا اتطلعت هذا إيثانول طبعا
+
+73
+00:07:13,980 --> 00:07:19,200
+المجموعة إيثل بناء على ذلك بيكون إيثل ألكول هذا
+
+74
+00:07:19,200 --> 00:07:23,700
+البروبانول الان لاحظوا البروبانول الالكول ممكن
+
+75
+00:07:23,700 --> 00:07:26,580
+تكون ال OH على الكاربون الأولى أو على الكاربون
+
+76
+00:07:26,580 --> 00:07:30,880
+الثانية ولذلك بلزم نوضح بالترقيم فبنقول one
+
+77
+00:07:30,880 --> 00:07:36,890
+probanol و two probanolواضح؟ ال alcohol من
+
+78
+00:07:36,890 --> 00:07:41,470
+المركبات زيها زي ال alkenes اللي مرات كتير لازم
+
+79
+00:07:41,470 --> 00:07:45,870
+نوضح موقع المجموعة الوظيفية باستعمال ايش؟ أرقام
+
+80
+00:07:45,870 --> 00:07:50,290
+طبعا هنا لما قلنا one probanol لو كنا بدنا نسميه
+
+81
+00:07:50,290 --> 00:07:54,070
+بالاسم الشائع ال common name المجموعة هذه probel
+
+82
+00:07:54,070 --> 00:08:00,370
+.. probel alcohol الآن هذا two probanolأيزو برو
+
+83
+00:08:00,370 --> 00:08:01,430
+بالالكهول
+
+84
+00:08:15,670 --> 00:08:19,770
+CH حملة تنتين CH3 و كمان كربونة يعني العدد الكلي
+
+85
+00:08:19,770 --> 00:08:25,310
+أربعة إذا هذا شو بدي أسميه Isobutyl يمكن ال I
+
+86
+00:08:25,310 --> 00:08:30,290
+رايحة Isobutyl alcohol طبعا لو بدي أسميه أيوبكنومي
+
+87
+00:08:30,290 --> 00:08:35,990
+كليتشار بدي أسميه بالترقيم و ال OH بدي أكون ماخدة
+
+88
+00:08:35,990 --> 00:08:40,290
+أقل ترقيم يعني بدي أقول واحد اتنين تلاتة إذا هذا
+
+89
+00:08:40,290 --> 00:08:45,440
+one-probanolوانبروبانول على نمر اتنين شو بيحمل
+
+90
+00:08:45,440 --> 00:08:51,200
+الوانبروبانول مثل هاي أطول سلسلة واحد اتنين تلاتة
+
+91
+00:08:51,200 --> 00:08:57,520
+two مثل وانبروبانول فلازم احدد موقع ال ايش ال OH
+
+92
+00:08:57,520 --> 00:09:02,800
+two مثل وانبروبانوللو بننظر لهذا المركب على سبيل
+
+93
+00:09:02,800 --> 00:09:06,460
+المثال كمجموعة لو كنت بدي ال common nomenclature
+
+94
+00:09:06,460 --> 00:09:11,080
+له كمجموعة معروفة tertiary butyl اذا tertiary
+
+95
+00:09:11,080 --> 00:09:14,640
+butyl alcohol طب لو بدي اسميه بال iubac
+
+96
+00:09:14,640 --> 00:09:18,360
+nomenclature مرة تانية بدي اطول سلسلة خليني افترض
+
+97
+00:09:18,360 --> 00:09:24,700
+هي اطول سلسلة واحد اتنين تلاتة اذا هذا a-probanol
+
+98
+00:09:25,770 --> 00:09:31,010
+تو بروبانول لأن ال OH طالعة من موقع اتنين و على
+
+99
+00:09:31,010 --> 00:09:34,730
+اتنين ايضا ايش في عندكم مثل اذا two methyl two
+
+100
+00:09:34,730 --> 00:09:37,370
+probanol is tertiary butyl alcohol
+
+101
+00:09:45,170 --> 00:09:48,790
+الـ Common Nomenclature هو الـ tertiary butyl
+
+102
+00:09:48,790 --> 00:09:52,950
+alcohol في الـ Common Nomenclature الآن هذا
+
+103
+00:09:52,950 --> 00:09:57,150
+المُركّب لو بدأ أطلع على المجموعة اللي فيه لما
+
+104
+00:09:57,150 --> 00:10:02,690
+درفنا ال الكينز أخدنا مجموعتين أخدنا الفينل والألل
+
+105
+00:10:02,690 --> 00:10:06,870
+قلنا الألل اللي هو البروبين اللي بنخص منه هيدروجين
+
+106
+00:10:06,870 --> 00:10:10,780
+من هذا الموقعكل هذا الكلام السكوت اللي بلاحظه على
+
+107
+00:10:10,780 --> 00:10:15,740
+بعض الوجوه اللي أنا مارجعتش كتير هذه مشكلتها واضح؟
+
+108
+00:10:15,740 --> 00:10:20,700
+بدكوا تكونوا متذاكرين هذه المجموعة أخدناها بهذا
+
+109
+00:10:20,700 --> 00:10:25,380
+الشكل اسمها إيش؟ ألل الآن إذا إجي عليها chlorine
+
+110
+00:10:26,360 --> 00:10:30,580
+ألل كلورايت إذا إتي عليها بروم ألل برومايت إذا إتي
+
+111
+00:10:30,580 --> 00:10:36,960
+عليها OH ألل Alcohol فمن ناحية ال Alcohol اعرفنا
+
+112
+00:10:36,960 --> 00:10:42,520
+الآن لو كنا هذا ال ال alcohol بدنا نسميه بال Iopac
+
+113
+00:10:42,520 --> 00:10:48,840
+Nomenclature هنلاحظ إن في عندنا مجمعتين وظيفيتين
+
+114
+00:10:48,840 --> 00:10:53,280
+بدنا ننتبهالان التقاء المجموعات الوظيفية في
+
+115
+00:10:53,280 --> 00:10:58,520
+المركبات هذه تماما زى التقاء المجموعات الوظيفية
+
+116
+00:10:58,520 --> 00:11:02,660
+لما درسنا ال aromatic compounds متذكرين؟ اه قولنا
+
+117
+00:11:02,660 --> 00:11:07,420
+أبسط إشي ال alkanes بعدين ال alkenes و ال alkynes
+
+118
+00:11:07,420 --> 00:11:13,460
+بعدين مثلا ال OH بعدين ال ketone بعدين ال aldehyde
+
+119
+00:11:13,460 --> 00:11:19,890
+بعدين ال acidOkay فلو أنا بدي أجي أطلع أنه عندي OH
+
+120
+00:11:19,890 --> 00:11:27,370
+وعندي ال keen مين بده تكون العائلة ال OH وبناء على
+
+121
+00:11:27,370 --> 00:11:33,050
+ذلك المركب اللي عنده لازم ياخد النهاية all لأن
+
+122
+00:11:33,050 --> 00:11:37,950
+الشيء بتسمى باسم عائلته بياخد النهاية all طبعا هذا
+
+123
+00:11:37,950 --> 00:11:41,490
+لو بدي أطلع عليه واحد و الترقيم من وين هيكون؟
+
+124
+00:11:41,710 --> 00:11:46,310
+بنعندى الالكول واحد اتنين تلاتة طبعا بينا نسميه
+
+125
+00:11:46,310 --> 00:11:51,950
+بروبان all هو فيه double bond فبدل ال a بروبين
+
+126
+00:11:51,950 --> 00:11:58,050
+بيصير بروبين ال يعني لو مافيش عند انا هذا double
+
+127
+00:11:58,050 --> 00:12:02,910
+bond ايش كنت استعمل حرف ال a الآن صار double bond
+
+128
+00:12:02,910 --> 00:12:10,150
+ال الكن صار الكن صار بروبين all واضح بروبين all
+
+129
+00:12:10,150 --> 00:12:18,000
+لاحظواالعائلة إيش؟ all و هو فيه ألكين، الآن ال all
+
+130
+00:12:18,000 --> 00:12:24,470
+لازم نحدد موقعها و ال ألكين لازم نحدد موقعهابتدخل
+
+131
+00:12:24,470 --> 00:12:29,550
+الأرقام ال all على أي موقع جاية على واحد فبنكتب
+
+132
+00:12:29,550 --> 00:12:34,830
+two prob in one all بمعنى أن ال in موجودة على موقع
+
+133
+00:12:34,830 --> 00:12:39,890
+اتنين وال all على موقع واحد مرات هذا ممكن تشوفوه
+
+134
+00:12:39,890 --> 00:12:45,670
+بطريقة تانية يعني يكتبوه a prob و بعدين in و بعدين
+
+135
+00:12:45,670 --> 00:12:52,100
+all و يحددوا أن ال in على أي موقع اتنينع اتنين و
+
+136
+00:12:52,100 --> 00:12:56,080
+ال all على اي موقع لاحظوا اختلاف بسيط هنا في
+
+137
+00:12:56,080 --> 00:13:00,160
+الكتاب يعني عملنا تقطيع في الاسم حددنا وين ال in و
+
+138
+00:13:00,160 --> 00:13:05,100
+وين ال all هنا نفس الاشي و فهمنا ضمنا ان اتنين
+
+139
+00:13:05,100 --> 00:13:11,180
+اللي كتبت برا هي تعنيموقع ال in و ال all جنبها ف
+
+140
+00:13:11,180 --> 00:13:16,000
+two probine one all او prob two in one all هو نفس
+
+141
+00:13:16,000 --> 00:13:20,560
+الاسم يعني طريقتين لكتابة نفس الاسم في كتير طلاب
+
+142
+00:13:20,560 --> 00:13:25,320
+بيحبوا يقولوا في الأول هذا كله probine all جنب ال
+
+143
+00:13:25,320 --> 00:13:30,140
+in بالظبط بيحطوا الرقم جنب ال all بالظبط بيحطوا
+
+144
+00:13:30,140 --> 00:13:32,140
+الرقم تبعها
+
+145
+00:13:35,230 --> 00:13:39,650
+فهذه الطريقة اللي احنا بنستعملها لما بلتقى عندنا
+
+146
+00:13:39,650 --> 00:13:44,370
+اكثر من مجموعة وظيفية لاحظوا بدي اجي مباشرة على
+
+147
+00:13:44,370 --> 00:13:50,650
+هذا المثال لانه على نفس الفكرة طلع هذا المثال ايش
+
+148
+00:13:50,650 --> 00:13:58,180
+العائلات اللي موجودة فيه؟ال all و ال I ال ال مين
+
+149
+00:13:58,180 --> 00:14:04,120
+أعلى في الأولوية ال all إذا لو عديت العدد لكل واحد
+
+150
+00:14:04,120 --> 00:14:11,880
+اتنين تلاتة أربعة خمسة إيش هيكون كمركب؟ بين two
+
+151
+00:14:11,880 --> 00:14:17,960
+all بين two all هيني ذكرت المجموعتين لما أنا أقول
+
+152
+00:14:17,960 --> 00:14:21,240
+بين I
+
+153
+00:14:22,480 --> 00:14:29,500
+all هذه المجموعتين في I و في all الآن بلزم أن احدد
+
+154
+00:14:29,500 --> 00:14:36,960
+موقعهم ال all على اي موقع و ال I على تلاتة بنت
+
+155
+00:14:36,960 --> 00:14:42,140
+اثري I one all او لو كتبت اثري بنتين بتفهم ان ال
+
+156
+00:14:42,140 --> 00:14:47,160
+three هذي بتحدد موقع ال I اثري بنتين one all او
+
+157
+00:14:47,160 --> 00:14:52,500
+بنت اثري I one all نفس الفكرة تماماواضح؟ نفس
+
+158
+00:14:52,500 --> 00:14:57,360
+المُركّب فهذا الكلام اللي بيصير عندنا لما بلتقي
+
+159
+00:14:57,360 --> 00:15:05,380
+أكثر من مجموعة وظيفية الان ممكن يكون عندي alcohol
+
+160
+00:15:05,380 --> 00:15:13,120
+على حلقات ال alcohol على الحلقة .. الحلقة مش زي
+
+161
+00:15:13,120 --> 00:15:18,620
+السلسلةالحلقة ما لهاش بداية و نهاية يعني لما يكون
+
+162
+00:15:18,620 --> 00:15:24,200
+عندي انا خمس درات كربون كسلسلة باجي بقول بضحوط ال
+
+163
+00:15:24,200 --> 00:15:31,460
+OH هنا بسميه one بنتانول هنا two بنتانول three
+
+164
+00:15:31,460 --> 00:15:35,760
+بنتانول برجع طبعا two بنتانول اذا في عندي في
+
+165
+00:15:35,760 --> 00:15:40,150
+السلسلةone pentanol و two pentanol و three
+
+166
+00:15:40,150 --> 00:15:46,600
+pentanol لكن لو هذه السلسلة صارت حلقة خماسيةالان
+
+167
+00:15:46,600 --> 00:15:50,420
+سواء كتبة ال او اتش هان او هان او هان او هان او
+
+168
+00:15:50,420 --> 00:15:54,220
+هان جميع المواقع متكافئة مافيش فيها موقع واحد يعني
+
+169
+00:15:54,220 --> 00:15:58,800
+مابيقدرش الإنسان الحلقة يقول وين بدايتها ولذلك هذا
+
+170
+00:15:58,800 --> 00:16:04,200
+بتسمى cyclopentanol بدون ما نحطله one أو two لأن
+
+171
+00:16:04,200 --> 00:16:11,240
+كل المواقع واحد واضح؟ cyclopentanol لكن وقتش بيلزم
+
+172
+00:16:11,240 --> 00:16:16,930
+ترقيملو كان عندى اكتر من مجموعة عشان اشوف انه هذه
+
+173
+00:16:16,930 --> 00:16:23,610
+المجموعات انه هذه المجموعات هل يا ترى واحد اتنين
+
+174
+00:16:23,610 --> 00:16:27,250
+ولا واحد تلاتة ايش العلاقة بينها يعني لو كان
+
+175
+00:16:27,250 --> 00:16:31,030
+المركب بهذا الشكل والمجموعتين على جهة واحدة هذا
+
+176
+00:16:31,030 --> 00:16:38,930
+ايش هسميه one two cyclopentane by all all و all
+
+177
+00:16:39,860 --> 00:16:44,680
+Diol واضح؟ one two cycle وبنتين ديول وحنقول إيش
+
+178
+00:16:44,680 --> 00:16:52,140
+مالهم؟ sis طبعا ممكن نتخيل مركب بهذا الشكل لو
+
+179
+00:16:52,140 --> 00:16:58,860
+افترضنا هنا في عندنا OH وهنا في عندنا CL وإيجا
+
+180
+00:16:58,860 --> 00:17:05,680
+بدنا نسميه الآن أكيد ال alcohol أساس أقوى من ال CL
+
+181
+00:17:05,680 --> 00:17:12,110
+إذا المركب إيش هيكون؟cyclopentanol بتخيلوا من وين
+
+182
+00:17:12,110 --> 00:17:17,070
+بيبدأ الترقيم؟ و
+
+183
+00:17:17,070 --> 00:17:23,270
+بناء على ذلك مثل هذا المركب هيصير three .. فيش
+
+184
+00:17:23,270 --> 00:17:31,050
+ميتة ميتة في البنزينة خلصنا منها بس في البنزينة مش
+
+185
+00:17:31,050 --> 00:17:37,190
+في الحلقات إذا هذا three chloro cyclopentanol
+
+186
+00:17:37,370 --> 00:17:44,590
+بنتانول مش بنتين Cyclopentanol خلاص مابنكتبش one
+
+187
+00:17:44,590 --> 00:17:48,150
+لأنه يفهم ضمنا أن الترقيم بدأ من عندها يعني
+
+188
+00:17:48,150 --> 00:17:52,770
+مابنكتبش three chloro cyclopentane one all أو one
+
+189
+00:17:52,770 --> 00:17:57,310
+cyclopentanol لأ three chloro cyclopentanol و هكذا
+
+190
+00:17:57,310 --> 00:17:58,110
+واضح؟
+
+191
+00:18:00,740 --> 00:18:06,080
+الان احيانا بلتقي عندى الجزء ال aliphatic مع ال
+
+192
+00:18:06,080 --> 00:18:10,320
+aromatic وسبق احنا لما أخدنا ال aromatic compounds
+
+193
+00:18:10,320 --> 00:18:16,020
+نوّهنا لهذه النقطة قولنا انه ممكن نسمي المركب بأحد
+
+194
+00:18:16,020 --> 00:18:21,560
+طريقين اما ان نعتبر الأساس بنزين و اكتشف نعتبر
+
+195
+00:18:21,560 --> 00:18:26,600
+الأساس بنزينإذا هذه المجموعة اللي موجودة سهلة ولها
+
+196
+00:18:26,600 --> 00:18:31,460
+اسم بسيط عارفينه طب إذا مش مجموعة سهلة وملاش اسم
+
+197
+00:18:31,460 --> 00:18:39,480
+بسيط بعتبر نفسي بتعامل مع المركب كالكين بتعامل مع
+
+198
+00:18:39,480 --> 00:18:45,620
+المركب كالكين هذا الالكين هيطول سلسلة فيه في نمرة
+
+199
+00:18:45,620 --> 00:18:50,780
+واحد اتنين ويحمل مجموعة ايش اسم هذه المجموعة فنل
+
+200
+00:18:51,570 --> 00:18:56,330
+البنزينة اللى خصمنا منها H كمجموعة شو بنسميها؟ فنل
+
+201
+00:18:56,330 --> 00:18:59,970
+طبعا لاحظوا المركب اللى فيه ذرتين كربون هو اي
+
+202
+00:18:59,970 --> 00:19:06,470
+مركب؟ الاثانول اذا هذا لو كنا بنسميه شو هنسميه؟
+
+203
+00:19:06,470 --> 00:19:08,790
+two phenyl اثانول
+
+204
+00:19:11,950 --> 00:19:16,070
+يفهم على طول مباشرة طالما كتبنا two أن الـ O على
+
+205
+00:19:16,070 --> 00:19:22,430
+واحد و هذا على اتنين لاحظوا لو مثلا جبنا مركب شبيه
+
+206
+00:19:22,430 --> 00:19:29,390
+فيه بهذا الشكل هاي ذارتين كربون و حطينا الـ OH هنا
+
+207
+00:19:29,390 --> 00:19:30,970
+و البنزينة هنا
+
+208
+00:19:35,020 --> 00:19:39,080
+لاحظوا هذا isomer .. structural isomer كربون تنتين
+
+209
+00:19:39,080 --> 00:19:42,140
+كانت ال O H على الكربون الأولى و البنزينة على
+
+210
+00:19:42,140 --> 00:19:45,080
+التانية حطينا ال O H على الأولى و البنزينة على
+
+211
+00:19:45,080 --> 00:19:53,120
+الأولى فلو بدنا نيجي نقول بدنا نسمي هذا one phenyl
+
+212
+00:19:53,120 --> 00:20:00,180
+one ethanol مواد هيك إيثانول
+
+213
+00:20:03,690 --> 00:20:10,650
+عشان نضع رقم وان فينيل وان إيثانول واضح؟ وان فينيل
+
+214
+00:20:10,650 --> 00:20:14,350
+وان إيثانول عشان التوضيح يعني دائما في موضوع
+
+215
+00:20:14,350 --> 00:20:19,430
+الأرقام إذا حسيت أن في شيء confusing لازمة أرقام
+
+216
+00:20:19,430 --> 00:20:25,250
+إضافية نضعها مش لازمة أرقام إضافية مافيش داعي أن
+
+217
+00:20:25,250 --> 00:20:29,470
+نضع الأرقام مايتضح بدون أرقام لا نستعمل له الأرقام
+
+218
+00:20:29,470 --> 00:20:35,310
+يعني هنابتمشي بدون أرقام بيبطل فيه لزوم ان اكتب
+
+219
+00:20:35,310 --> 00:20:39,490
+one على سبيل المثال one cyclopentanol خلاص
+
+220
+00:20:39,490 --> 00:20:45,030
+فالأرقام عندها غرض ايش الغرض تبعها التوضيح لما
+
+221
+00:20:45,030 --> 00:20:49,350
+بيصير في لبس معين بحتاج ان نحط الأرقام عشان نوضح
+
+222
+00:20:49,350 --> 00:20:56,350
+بنستعملها طبعا ال aromatic alcohol انجاز التعبير
+
+223
+00:20:56,350 --> 00:21:03,280
+الأساس فيهمالفينول مر علينا تسميته وقلنا لو ال OH
+
+224
+00:21:03,280 --> 00:21:08,480
+مع ال نيترو مين الأساس الفينول إذا هذا para-nitro
+
+225
+00:21:08,480 --> 00:21:14,260
+أو four-nitroفينول لكن بدكوا تنتبهوا لنقطة أن نفس
+
+226
+00:21:14,260 --> 00:21:21,020
+هذه الفينول لو انوجدت مع مجموعات أعلى منها هترجع
+
+227
+00:21:21,020 --> 00:21:26,620
+لأصلها يعني هذه حامض C double bond O OH acidو
+
+228
+00:21:26,620 --> 00:21:31,380
+Alcohol من الأعلى؟ ال acid ولذلك هذا المُركّب
+
+229
+00:21:31,380 --> 00:21:35,620
+Benzoic acid على موقع Ortho، إيش عندكم؟
+
+230
+00:21:39,360 --> 00:21:44,420
+Orthohydroxy benzoic acid أو two hydroxy benzoic
+
+231
+00:21:44,420 --> 00:21:51,020
+acid طبعا هذا ماخد اسم شهرة salicylic acid ماخد
+
+232
+00:21:51,020 --> 00:21:54,720
+اسم شهرة ايش؟ salicylic acid ال salicylic acid هو
+
+233
+00:21:54,720 --> 00:21:59,760
+الحامض اللي بيطلو عادة من شجر الصفصاف وهو أساس
+
+234
+00:21:59,760 --> 00:22:05,680
+تحضير الأسبيرين هو أساس تحضير الأسبيرينيعني
+
+235
+00:22:05,680 --> 00:22:11,960
+الأسبيرين عادة بيشتقوا من هذا الحامض بيبدلوا ال H
+
+236
+00:22:11,960 --> 00:22:16,400
+اللي موجودة هنا على ال OH شايفين هذه ال OH هذه ال
+
+237
+00:22:16,400 --> 00:22:20,140
+H بنبدلها و بنحط مكانها هذه المجموعة
+
+238
+00:22:23,720 --> 00:22:26,920
+الناس اللي حفظوا معنا هذه المجموعة أخدناها لجامن
+
+239
+00:22:26,920 --> 00:22:32,840
+الـ acetic acid أسيتل فبصير المركب بدل salicylic
+
+240
+00:22:32,840 --> 00:22:35,140
+acid أسيتو
+
+241
+00:22:37,400 --> 00:22:42,540
+acetosalicylic acid هو الاسبيرين واضح فالاسبيرين
+
+242
+00:22:42,540 --> 00:22:47,480
+هو ال salicylic acid لكن انا شيلت منه ال H وحطيت
+
+243
+00:22:47,480 --> 00:22:52,940
+مكانها C double bond O CH3 فبصير الاسم المشهور
+
+244
+00:22:52,940 --> 00:23:00,080
+للاسبيرين ايش acetosalicylic acidacetosalicylic
+
+245
+00:23:00,080 --> 00:23:04,860
+acid المثال الأخير اللي موجود في هذا ال slide هو
+
+246
+00:23:04,860 --> 00:23:10,280
+التقاء الديهايد مع الكهول لحظة متذكرين لما قلنا
+
+247
+00:23:10,280 --> 00:23:16,280
+الكهول الديهايدي ماكتبوش COH CHO وهذا لو كنا
+
+248
+00:23:16,280 --> 00:23:21,960
+بنفسرها بال structure كيف بنفسرها بنفسرها C double
+
+249
+00:23:21,960 --> 00:23:29,730
+bond OHهذه تفاصيلها C double bond OH لما بنكتبها
+
+250
+00:23:29,730 --> 00:23:34,750
+كتابة كيف بنكتبها CHO فهذه مجموعة ال الديهايد الان
+
+251
+00:23:34,750 --> 00:23:39,350
+ال الديهايد أعلى من الألكوهول ولذلك المركب اللي
+
+252
+00:23:39,350 --> 00:23:46,490
+عندي هنا بنز الديهايد على موقع متا هيدروكسي
+
+253
+00:23:46,490 --> 00:23:50,050
+متا هيدروكسي بنز الديهايد
+
+254
+00:23:54,320 --> 00:23:59,120
+هذا بشكل عام بالنسبة لتسمية الكحولات و ال phenols
+
+255
+00:23:59,120 --> 00:24:04,180
+لما نصل لل thyols اللي فيهم SH بناخد تسميتهم بشكل
+
+256
+00:24:04,180 --> 00:24:05,240
+منفصل
+
+257
+00:24:07,650 --> 00:24:14,410
+الان كنا عارفين شغلة ان الكحولات طالما فيهم OH إذا
+
+258
+00:24:14,410 --> 00:24:19,550
+اللي بيعملوا إيش هيدروجين bonding بيعملوا هيدروجين
+
+259
+00:24:19,550 --> 00:24:23,530
+bonding اللي مقصود بالهيدروجين bonding أن ذرة
+
+260
+00:24:23,530 --> 00:24:27,330
+الهيدروجين في الكحولات تحديدا بتكون محصورة بين
+
+261
+00:24:27,330 --> 00:24:32,400
+ذرتين أكسجينوبشكل عام إذا إنتوا متذكرين من المدارس
+
+262
+00:24:32,400 --> 00:24:37,380
+الـ hydrogen bonding بيكون إذا حصرت الهيدروجين بين
+
+263
+00:24:37,380 --> 00:24:43,440
+electronegative atoms محددة تلت ذرات شو هما؟
+
+264
+00:24:43,440 --> 00:24:48,680
+Oxygen و Nitrogen و Fluor سواء كان على اليمين أو
+
+265
+00:24:48,680 --> 00:24:52,360
+الشمال يعني بين تنتين Oxygen، بين تنتين Nitrogen،
+
+266
+00:24:52,360 --> 00:24:55,260
+بين تنتين Fluor، بين Oxygen وNitrogen، Oxygen و
+
+267
+00:24:55,260 --> 00:25:00,810
+Fluor الهيدروجين لما بتحصربين ذرتين
+
+268
+00:25:00,810 --> 00:25:05,130
+electronegative بهذا الشكل بتكون رابطة أساسية
+
+269
+00:25:05,130 --> 00:25:10,270
+رابطة أساسية مع ذرة و رابطة هيدروجينية مع الذرة
+
+270
+00:25:10,270 --> 00:25:15,130
+التانية يعني لو كنا بدنا نوضح بالظبط ال hydrogen
+
+271
+00:25:15,130 --> 00:25:20,670
+bonding في الألكوهول حتى ما نتغلب هيكون بهذا الشكل
+
+272
+00:25:20,670 --> 00:25:23,350
+ال hydrogen bonding في الألكوهول تخيلوا مثلا
+
+273
+00:25:23,350 --> 00:25:27,990
+الميثانول CH3O
+
+274
+00:25:29,040 --> 00:25:34,620
+H هذا الجزء و في كم زوج إلكتروناتها اتنين الان لو
+
+275
+00:25:34,620 --> 00:25:43,280
+بدى اجيب انا جزء كحول تاني CH3 OH وهي كمان زوجين
+
+276
+00:25:43,280 --> 00:25:53,130
+إلكترونات الان هذا جزء و هذاهذه الروابط الـ OH
+
+277
+00:25:53,130 --> 00:25:57,370
+اللي هنا رابطة أصلية Intramolecular bond و الـ OH
+
+278
+00:25:57,370 --> 00:26:01,510
+اللي هنا Intramolecular bond لو أنا إجيت أعملت بين
+
+279
+00:26:01,510 --> 00:26:07,070
+هذه الـ H و هذا زوج الإلكترونات رابطة هذا الرابطة
+
+280
+00:26:07,070 --> 00:26:13,230
+الهيدروجينية هذا الـ hydrogen bondهذا الهيدروجين
+
+281
+00:26:13,230 --> 00:26:18,630
+بوند الان لاحظوا معي ان الهيدروجين بوند ولا بحال
+
+282
+00:26:18,630 --> 00:26:23,090
+من الأحوال قوتها بتصل لقوة هذه الرابطة الأساسية
+
+283
+00:26:23,090 --> 00:26:27,450
+يعني هذه الهيدروجين بوند اللي بين الجزيئين قوتها
+
+284
+00:26:27,450 --> 00:26:32,070
+تقريبا بين خمسة لعشرة في المية من قوة الرابطة
+
+285
+00:26:32,070 --> 00:26:38,900
+الأصلية اللي هنا يعني هذه مقارنة بهذه خمسةالى 10%
+
+286
+00:26:38,900 --> 00:26:43,280
+من قوة الرابط الاصلية لهنا بناء على ذلك لو احنا
+
+287
+00:26:43,280 --> 00:26:49,460
+بدنا نعمل عملية تسخين او غليان نكسر روابط بالطاقة
+
+288
+00:26:49,460 --> 00:26:55,080
+اى رابط اللى بدأت نكسر هادي وبطير هذا الكحول لوحده
+
+289
+00:26:55,080 --> 00:26:59,840
+وبطير بتبخر هذا الكحول لوحدهبس ماحد بيقول اللي
+
+290
+00:26:59,840 --> 00:27:05,680
+بنكسر هذه الرابطة بالغليان، الغليان بيكسر الروابط
+
+291
+00:27:05,680 --> 00:27:10,040
+الـ Intermolecular forces، الروابط بين الجزيئات،
+
+292
+00:27:10,040 --> 00:27:14,080
+هذا جزيء و هذا جزيء بينهم رابطة ضعيفة هي اللي
+
+293
+00:27:14,080 --> 00:27:19,070
+بتتفكك و بتنكسر، بس بالتأكيدمش ال intramolecular
+
+294
+00:27:19,070 --> 00:27:22,330
+force الرابطة الأصلية اللي بتنكسر، لأ ال
+
+295
+00:27:22,330 --> 00:27:26,110
+intermolecular force يعني لو سخننا مثلا و بدنا
+
+296
+00:27:26,110 --> 00:27:30,110
+نعمل غليان أو كان بتبخر حتى مع ارتفاع الحرارة أي
+
+297
+00:27:30,110 --> 00:27:35,190
+رابطة اللي بتنكسر، هذه الرابطة بيصير كل جزء ينفصل
+
+298
+00:27:35,190 --> 00:27:41,000
+لإيش؟ لوحده، واضح؟طبعا انتبهوا معي وجود ال
+
+299
+00:27:41,000 --> 00:27:47,460
+hydrogen bond هادي بتخلي الكحول جزيئاته مترابطة
+
+300
+00:27:47,460 --> 00:27:52,040
+اذا نقطة غليانه نسبيا ايش بتكون عالية يعني هذا
+
+301
+00:27:52,040 --> 00:27:56,580
+الميثانول على سبيل المثال نقطة غليانه 65 درجة
+
+302
+00:27:56,580 --> 00:28:02,190
+مئويةمقارنة بمركبات مش فيها hydrogen bonding زي ال
+
+303
+00:28:02,190 --> 00:28:07,630
+الكنز تعتبر نقطة غليان عالية طيب لو قلنا بدنا
+
+304
+00:28:07,630 --> 00:28:13,610
+نقارن هذا الميثانول بالمية طب ليش؟ مع العلم أن
+
+305
+00:28:13,610 --> 00:28:20,130
+وزنها الجزائي أقل و
+
+306
+00:28:20,130 --> 00:28:24,800
+أنا هيدروجينيةعندى تلتين رابطين زى ما .. الميه
+
+307
+00:28:24,800 --> 00:28:29,020
+عندها الإمكانية بالظبط تعمل رابطتين هيدروجينيتين
+
+308
+00:28:29,020 --> 00:28:34,140
+مش رابط يعني الجزيئات بتترابط بشكل أقوى لما انتوا
+
+309
+00:28:34,140 --> 00:28:40,860
+بدكم تقولوا فى عندكم OHH نفترض الآن هذا الجزيئ لو
+
+310
+00:28:40,860 --> 00:28:47,560
+بدى أجيبله جزيئ تانى بهذا الشكل OHH وهنا كمان OHH
+
+311
+00:28:47,560 --> 00:28:49,740
+هى تلت جزيئات نفترض
+
+312
+00:28:52,840 --> 00:28:57,600
+الان هنا في عندي أزواج إلكترونات بيصير رابطة
+
+313
+00:28:57,600 --> 00:29:02,380
+هيدروجينية من هنا إذا أنا لو هذا بدي أفكه كام
+
+314
+00:29:02,380 --> 00:29:07,300
+رابطة هيدروجينية بدي أكسر؟ تنتين مش واحدة فالمي
+
+315
+00:29:07,300 --> 00:29:14,220
+لأنها H2 بيكون فيها روابط هيدروجينية إيش؟ أكتر من
+
+316
+00:29:14,220 --> 00:29:20,840
+الكحولاتلاحظوا يعني لو الإنسان بده يحكي شوية بمنطق
+
+317
+00:29:20,840 --> 00:29:27,440
+الفلسفة .. بمنطق الفلسفة الميه
+
+318
+00:29:27,440 --> 00:29:36,700
+يمكن مشروب لذيذ و أحل الحلال تمام؟ و الكحولات
+
+319
+00:29:36,700 --> 00:29:43,800
+بعضهاسام وبعضها خمر وبعضها مفيد يعني الكحولات
+
+320
+00:29:43,800 --> 00:29:50,300
+ماحدش يستعمل المصطلح الحديث إنه الكحولات بشكل عام
+
+321
+00:29:50,300 --> 00:29:57,460
+ضارة أو الكحولات محرمة لأ الكحولات عائلة عائلة
+
+322
+00:29:57,460 --> 00:30:04,440
+كبيرة هذه العائلة في منها مواد سامة في منها مواد
+
+323
+00:30:04,440 --> 00:30:11,100
+مسكرة في منها مواد مفيدةواضح؟ في منها مواد سامة
+
+324
+00:30:11,100 --> 00:30:16,420
+وفي مسكر وفي مفيد حسب طبيعة ال ايش ال R أو
+
+325
+00:30:16,420 --> 00:30:21,960
+المجموعة الان لو انا بدأ اتخيل ان الكحولات بنائها
+
+326
+00:30:21,960 --> 00:30:26,460
+الأساسي ال O H و اجي اقول أبسط الكحولات .. أبسط
+
+327
+00:30:26,460 --> 00:30:34,300
+الكحولات يعني هي عندي O H .. O H .. O H الان خليني
+
+328
+00:30:34,300 --> 00:30:43,510
+اجي احط هناقبل ال CH3 H أحط هنا CH3 و أحط هنا CH2
+
+329
+00:30:43,510 --> 00:30:51,780
+CH3لاحظوا أبسط مركّب هيكون الميّه طبعا الميّه ما
+
+330
+00:30:51,780 --> 00:30:55,980
+بنصنفهاش احنا مركّب عضوي لسبب بسيط ان مافيش فيها
+
+331
+00:30:55,980 --> 00:31:00,200
+carbon المركّب العضوي فيه carbon لكن لو الإنسان
+
+332
+00:31:00,200 --> 00:31:06,300
+بتأمل من ناحية الخواص الميّه كتير في خواصها بتشبه
+
+333
+00:31:06,300 --> 00:31:10,450
+الكحولاتكخواص كيميائية يعني لو بدأت أتكلم عن نقطة
+
+334
+00:31:10,450 --> 00:31:14,770
+غليان مرتفعة لو بدأ أتكلم عن تفاعل مع السوديوم لو
+
+335
+00:31:14,770 --> 00:31:19,490
+بدأ أتكلم بعد شوية لما أخد الحامضية هلاحظ أن
+
+336
+00:31:19,490 --> 00:31:24,310
+حامضية الماء زي حامضية الكحولات بالظبط يعني نفس
+
+337
+00:31:24,310 --> 00:31:29,630
+القوة الحامضية عشان هيك بنقول للبني آدم غسل بالمية
+
+338
+00:31:29,630 --> 00:31:34,350
+إيدك بنضره ولا لأ؟ بندرهش كلنا بنغسل بالمية طب
+
+339
+00:31:34,350 --> 00:31:39,160
+الكحولات؟بعد شوية لما تصيروا تعملوا مزارع بكتيريا
+
+340
+00:31:39,160 --> 00:31:41,840
+اللي بتخصصوا تحاليل طبية و إشي بعد ما يشتغلوا
+
+341
+00:31:41,840 --> 00:31:44,860
+بالبكتيريا بدهم يطهروا إيديهم بإيش بيغسلوا
+
+342
+00:31:44,860 --> 00:31:50,960
+بالإيثانول بالإيثانول اللي هو الكحول نفسه تبع
+
+343
+00:31:50,960 --> 00:31:56,420
+الخمر بيغسله فيه واضح؟ الآن لاحظوا أن الماء شراط
+
+344
+00:31:56,420 --> 00:32:04,660
+الميثانول poisonous الإيثانول
+
+345
+00:32:05,860 --> 00:32:10,060
+اللي هو الخمرة الاثانول
+
+346
+00:32:10,060 --> 00:32:13,760
+المكون الأساسي هو اللي بيسبب الاسكار في الخمر
+
+347
+00:32:13,760 --> 00:32:21,200
+والميه اللي هي أبسط مشروب فيهم الميه
+
+348
+00:32:21,200 --> 00:32:27,540
+مشروب جيد وممتاز هيجيكم كمان فكرة طالما ذكرنا هذا
+
+349
+00:32:27,540 --> 00:32:36,600
+الكلام هيجيكم كمان فكرة ان الاثانول في مشكلةإن هو
+
+350
+00:32:36,600 --> 00:32:42,540
+من أفضل المذيبات لإجراء التفاعلات الكيميائية ومطهر
+
+351
+00:32:42,540 --> 00:32:47,280
+يعني أنا بدي إياه يكون متوفر وبسعر رخيص يعني ال
+
+352
+00:32:47,280 --> 00:32:53,180
+letter يكون مثلا بتلاتة أربعة shekel بدولار واضح؟
+
+353
+00:32:58,850 --> 00:33:06,070
+بنغسل الأوان الذجاجية بالإيثانول بالإيثانول
+
+354
+00:33:06,070 --> 00:33:07,350
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+355
+00:33:07,350 --> 00:33:07,510
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+356
+00:33:07,510 --> 00:33:08,990
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+357
+00:33:08,990 --> 00:33:11,110
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+358
+00:33:11,110 --> 00:33:14,620
+بالإيثانول بالإصناعة الخمور هذه بحث ذاتها علم يعني
+
+359
+00:33:14,620 --> 00:33:19,560
+ملايين الفدانات بتكون مزروعة عنب اللي بيعملوا منه
+
+360
+00:33:19,560 --> 00:33:23,440
+الخمر و بدهوا مياه تكون بسعر غالي و زجاجة النبيذ
+
+361
+00:33:23,440 --> 00:33:27,100
+بسعر معين طب هى الاساس اللى فيها اللى بيعمل كل
+
+362
+00:33:27,100 --> 00:33:32,400
+المشاكل مين ال Ethanol اذا ال Ethanol صار مطلوب
+
+363
+00:33:32,400 --> 00:33:36,380
+عند العلماء و عند الكيميائين و عند الصناعة انه
+
+364
+00:33:36,380 --> 00:33:42,680
+ينباع رخيصو ممكن يتحضروا ينباع رخيص ومطلوب عند
+
+365
+00:33:42,680 --> 00:33:49,920
+الناس اللي بيصنعوا الخمر انه ينباع ايش؟ غالب لأنه
+
+366
+00:33:49,920 --> 00:33:54,300
+هذه صناعة في العالم الغربي و بدها تربح طب ايش
+
+367
+00:33:54,300 --> 00:33:57,940
+الحل؟ العالم والكيميائي بيقول بدي ايه ايه ايه ايه
+
+368
+00:33:57,940 --> 00:33:58,840
+ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه
+
+369
+00:33:58,840 --> 00:34:06,690
+ايه ايه ايه ايه ايه ايه ايه ايه ايهجالوا بسيطة
+
+370
+00:34:06,690 --> 00:34:14,050
+للكيميائيين جالولهم بنبيعكم إيثانول رخيص بس بشرط
+
+371
+00:34:14,050 --> 00:34:21,280
+عارفين إيش الشرط انسموا اللي ما تشربوهوشيعني هم
+
+372
+00:34:21,280 --> 00:34:24,220
+بدوا ميثاق أنه اللي بده يشرب إيثانول و اللي بده
+
+373
+00:34:24,220 --> 00:34:28,180
+يشرب خمره بده يدفع كتير طب ييجي بني آدم بده يلحق
+
+374
+00:34:28,180 --> 00:34:32,340
+عليهم بالله بيعوني إيثانول أنا بدي أستعمله للصناعة
+
+375
+00:34:32,340 --> 00:34:38,000
+و يروح يشربه برخيص خسروا الجماعة فقالوا بنبيعكيا
+
+376
+00:34:38,000 --> 00:34:44,900
+للصناعة بس ما تشربوش في ثقة متبادلة أنه يلتزم طب
+
+377
+00:34:44,900 --> 00:34:51,240
+إيش عملوه؟ قالوا بنحط فيه شوية سماللي لو شربته
+
+378
+00:34:51,240 --> 00:34:56,780
+تموت، تبقوا معاه، يعني لو الواحد شرب الاثانول بتاع
+
+379
+00:34:56,780 --> 00:35:03,800
+المختبر، بده يموت، إذا الإنسان شرب اثانول المختبر،
+
+380
+00:35:03,800 --> 00:35:07,240
+شو بده يصير فيه؟ بده يموت، طب إيش السم اللي بدكوا
+
+381
+00:35:07,240 --> 00:35:11,920
+تحطوه في الاثانول؟ جالي شوية ميثانول صغيرة،
+
+382
+00:35:11,920 --> 00:35:18,250
+الميثانول سام، يا بيموت يا بيعمىواضح؟ فال Ethanol
+
+383
+00:35:18,250 --> 00:35:21,330
+اللي في المختبر .. ال Ethanol اللي في المختبر
+
+384
+00:35:21,330 --> 00:35:26,570
+مسموم ممنوع أن البني أدم يشربه مخلوط بشوية إيش؟
+
+385
+00:35:26,570 --> 00:35:31,470
+Methanol. الآن إذا إجا لا سمح الله واحد جاهل بده
+
+386
+00:35:31,470 --> 00:35:35,510
+يحضر خمرة للغلابة و الفجرة و جاب منها ال Ethanol
+
+387
+00:35:35,510 --> 00:35:40,090
+الارخيص و حط في جزايز و باع و يلا اشربه شو بده
+
+388
+00:35:40,090 --> 00:35:48,340
+يصير فيهم؟ بدهم يموتواواضح؟ شو بده يصير فيهم؟ بدهم
+
+389
+00:35:48,340 --> 00:36:00,480
+يموتوا ويعيادوا بالله على أي حال، هذا الحادث مش
+
+390
+00:36:00,480 --> 00:36:06,270
+زمان صارجابل سنتين بس في ال 2013 عملها واحد
+
+391
+00:36:06,270 --> 00:36:10,750
+بالليبيا اول ما الدنيا صارت فوضى هناك راح اعمل هذا
+
+392
+00:36:10,750 --> 00:36:15,830
+الكلام و اقرأ التقرير لان انا بفرجيكوا تقرير من
+
+393
+00:36:15,830 --> 00:36:25,630
+تقرير حديث يعني لو بتطلع التاريخ 13.03.2003 2013
+
+394
+00:36:25,630 --> 00:36:26,950
+بالظبط
+
+395
+00:36:28,750 --> 00:36:34,410
+قدرين تقرأوا العنوان؟ ارتفاع عدد الموتى بسبب الخمر
+
+396
+00:36:34,410 --> 00:36:41,610
+المغشوشة لستين و هذا الكلام بتلت عشر تلاتة تداولته
+
+397
+00:36:41,610 --> 00:36:47,510
+وكلات الأنباء و ليش وصلوا لستين حالة و أكتر من
+
+398
+00:36:47,510 --> 00:36:52,310
+سبعميت حالة تسمم لأنهم
+
+399
+00:36:53,460 --> 00:36:58,040
+التسمم نجب عن مادة نجمة عن مادة مشروب كحول محل
+
+400
+00:36:58,040 --> 00:37:03,500
+الصناع والميثانول الذي يستخدم ايضا كوقود يضاف
+
+401
+00:37:03,500 --> 00:37:05,420
+احيانا بكميات صغيرة
+
+402
+00:37:13,840 --> 00:37:18,100
+يضاف أحيانا بكميات صغيرة في المشروبات الكحولية
+
+403
+00:37:18,100 --> 00:37:23,820
+التي تنتج سرا هو مش لزيادة المفعول يضاف يضاف أساسا
+
+404
+00:37:23,820 --> 00:37:29,800
+كتسميم لإيش لل إيثانول عشان الناس مايشربوش، الآن
+
+405
+00:37:29,800 --> 00:37:34,880
+هذا جاب إيثانول من تبع الكيمويات حطه عم الخمرة
+
+406
+00:37:36,080 --> 00:37:40,080
+ماتوا الناس اللي شربوا بالإضافة للناس اللي اتسمموا
+
+407
+00:37:40,080 --> 00:37:44,540
+و اللي أصيبوا بالإيش؟ بالعمى .. بالعمى و لذلك حتى
+
+408
+00:37:44,540 --> 00:37:48,240
+و أنتم تشتغلوا في المختبر نفترض أنكم كنتوا بتسخنوا
+
+409
+00:37:48,240 --> 00:37:53,060
+شغلة فيها إيثانول ما تعرضوش أنفسكم كتير لبخار
+
+410
+00:37:53,060 --> 00:37:58,680
+الإيثانولاللي تتنفسوا إيثانول يدخل لجسمكم من خلال
+
+411
+00:37:58,680 --> 00:38:03,660
+الجهاز التنفسي و يصل لعينيكم واضح؟ مثل هذه التجارب
+
+412
+00:38:03,660 --> 00:38:08,060
+و الأشياء لازم كيف تنشغل بخزانة أبخرة تشفطها مش
+
+413
+00:38:08,060 --> 00:38:13,300
+بني آدم بيعمل تجربة و بيسخن إيثانول و بيشتغل بدون
+
+414
+00:38:13,300 --> 00:38:17,040
+ما يعرف اللي بيشتغل كيميا هذه الكيميائيات بيتعامل
+
+415
+00:38:17,040 --> 00:38:22,520
+معاها كيف؟بأسلوب ضمن التحذيرات قبل ما بيمسك المادة
+
+416
+00:38:22,520 --> 00:38:27,600
+الإنسان بيكون فهمها و قرأ التحذيرات اللي عليها طيب
+
+417
+00:38:27,600 --> 00:38:33,020
+كيف يأتي السام يعني و بغسك يديه ممكن طبعا يعني؟ هو
+
+418
+00:38:33,020 --> 00:38:38,550
+ما بيأثرش في التغسيلفي التغسيل بأثرش لما يتناول من
+
+419
+00:38:38,550 --> 00:38:42,190
+الفم و يمتص جوا الجسم يعني مابتصيرش نسبة
+
+420
+00:38:42,190 --> 00:38:46,030
+absorption كبيرة اللى يدخل على الجسم بالذات اللى
+
+421
+00:38:46,030 --> 00:38:50,510
+هو بنسبة جليلة لكن لما بيتاخد كمشروب كلها النسبة
+
+422
+00:38:50,510 --> 00:38:55,430
+الجليلة بتيجي بتدخل الجسم طبعا أفضل كتير لو كنا
+
+423
+00:38:55,430 --> 00:39:01,010
+كمان بنغسل بإيثانول ناقي اللى مايصيرشنسبة ال
+
+424
+00:39:01,010 --> 00:39:04,270
+absorption الخفيفة لكن الواقع اللي موجود ان ال
+
+425
+00:39:04,270 --> 00:39:10,730
+ethanol الطبي بالذات ال ethanol المختبرة و عشان
+
+426
+00:39:10,730 --> 00:39:15,550
+هيك لما مرات بيجيبوا ethanol معين لصناعة الأدويات
+
+427
+00:39:16,370 --> 00:39:20,230
+بيكتبوا ان هذا إيثانول بنفع لصناعة الأدوية بيكون
+
+428
+00:39:20,230 --> 00:39:24,630
+مش فيه سموم ممكن يدوبوا فيه أدوية والموضوع خلاف في
+
+429
+00:39:24,630 --> 00:39:28,350
+موضوع انه يجوز استعماله او لا وقدر الإمكان الإنسان
+
+430
+00:39:28,350 --> 00:39:33,330
+لازم يتجنب الدواء اللي مدوب بإيثانول ما لم يكن
+
+431
+00:39:33,330 --> 00:39:39,130
+هناك يعني ضرورة يعني شديدة جدا و البدائل كتيرة في
+
+432
+00:39:39,130 --> 00:39:41,550
+كل الأحوال واضح الفكرة؟
+
+433
+00:39:49,990 --> 00:39:54,530
+الان في موضوع الـ hydrogen bonding قولنا بيخلي
+
+434
+00:39:54,530 --> 00:39:58,250
+نقاط الغليان مرتفعة يعني لو انا بدأ اطلع على
+
+435
+00:39:58,250 --> 00:40:04,330
+الميثانول 65 زادت كربونا الإيثانول بيصير 78
+
+436
+00:40:04,330 --> 00:40:10,030
+البروبانول 97 طبعا هذا كلام منطقي كل ما بتكبر
+
+437
+00:40:10,030 --> 00:40:14,970
+السلسلة شو بيصيرها نقطة الغليان؟بتزيد الان لو
+
+438
+00:40:14,970 --> 00:40:20,210
+اجينا نقارن الموضوع بذائبية هذه المراكبات في الميه
+
+439
+00:40:20,210 --> 00:40:24,690
+هذه المراكبات تمتاز انها مكونا من جزئين الجزء
+
+440
+00:40:24,690 --> 00:40:29,610
+الاول ال O H خلينا نعلمها بالاحمر في كل المراكبات
+
+441
+00:40:29,610 --> 00:40:36,030
+هذا جزء ال O H جزء ايش بنقول عنه احنا polar الان
+
+442
+00:40:36,030 --> 00:40:37,650
+الجزء التاني
+
+443
+00:40:47,350 --> 00:40:52,590
+السلسلة طولت فانجزوا اللي بيزيد قاعد ال non polar
+
+444
+00:40:56,610 --> 00:41:02,210
+ربما نستطيع ان نقول ان هذا الجزء polar يعني الجزء
+
+445
+00:41:02,210 --> 00:41:06,450
+ال polar فيه متغلب لكن لما تكبر السلسلة كتير الجزء
+
+446
+00:41:06,450 --> 00:41:12,330
+بالمجمل شو بنعمله؟ non polar بناء على ذلك الميه ال
+
+447
+00:41:12,330 --> 00:41:19,850
+H2O polar رجاء نقوله polar مش بولر مش بنانا،
+
+448
+00:41:19,850 --> 00:41:22,930
+pencil اه polar
+
+449
+00:41:25,090 --> 00:41:31,840
+لاحظوا القاعدة ايش بتقول Likedissolves like الان
+
+450
+00:41:31,840 --> 00:41:36,080
+هذا اعتبرنا polar بدوب في الميه هذا زيه هذا زيه
+
+451
+00:41:36,080 --> 00:41:41,100
+هذا اعتبرنا ايش non polar بدوب في الميه لأ و بناء
+
+452
+00:41:41,100 --> 00:41:45,280
+على ذلك بنصير قادرين نتخيل ليش ال methanol و ال
+
+453
+00:41:45,280 --> 00:41:48,460
+ethanol و ال probanol اللي هي الكحولات الصغيرة
+
+454
+00:41:48,460 --> 00:41:52,900
+بتدوب في الميه هذه الكحولات اللي في أول السلسلة
+
+455
+00:41:52,900 --> 00:41:58,820
+بنسميها احنا ايش lower alcohol يعني الكحولات الاش
+
+456
+00:41:59,790 --> 00:42:05,010
+لصغيرة و هذه الكحولات اللى تحت شو بنسميها higher
+
+457
+00:42:05,010 --> 00:42:09,750
+alcohols الان مين اللى بيدوبوا في الميه ال lower
+
+458
+00:42:09,750 --> 00:42:13,930
+alcohols ولا ال higher alcohols ال lower alcohols
+
+459
+00:42:13,930 --> 00:42:18,330
+are water soluble because they are considered to
+
+460
+00:42:18,330 --> 00:42:25,460
+be polar however higher alcohols arenon-polar and
+
+461
+00:42:25,460 --> 00:42:30,540
+so they are water insoluble الان بيستعملوا بدل
+
+462
+00:42:30,540 --> 00:42:33,520
+soluble و insoluble كلمة تانية عارفين شو بيسموها
+
+463
+00:42:33,520 --> 00:42:39,120
+missable missable لما نحط سائلين مع بعض و ينخلطوا
+
+464
+00:42:39,120 --> 00:42:44,140
+مع بعض بنستعملها بين السوائلفلما نقول completely
+
+465
+00:42:44,140 --> 00:42:49,780
+miscible يعني زي سائلين نحطهم في بعض و يخلطوا 100%
+
+466
+00:42:49,780 --> 00:42:54,220
+مثلا لو عمنا حطينا الاسيتون مع الميه الاسيتون
+
+467
+00:42:54,220 --> 00:42:57,340
+بيدوب في الميه الاثانول مع الميه الميثانول مع
+
+468
+00:42:57,340 --> 00:43:02,190
+الميه they are miscible لكن لو حطينا ال oilمع
+
+469
+00:43:02,190 --> 00:43:08,190
+الميّه بيكونوا immiscible أو non miscible يعني ما
+
+470
+00:43:08,190 --> 00:43:11,850
+بيدوبوش في بعض ف miscible تستعمل التعبير عن
+
+471
+00:43:11,850 --> 00:43:16,410
+السوائل اللي بتخلق مع بعضها البعض واضح؟ زي
+
+472
+00:43:16,410 --> 00:43:22,650
+soluble, miscibleالـ Hydrogen Bonding حكيناه
+
+473
+00:43:22,650 --> 00:43:25,970
+ووضحناه الآن ال acidity of alcohols الحقيقة موضوع
+
+474
+00:43:25,970 --> 00:43:30,630
+كبير يعني ربما يحتاج محاضرة كاملة بنبدأ فيه المرة
+
+475
+00:43:30,630 --> 00:43:35,090
+القادمة حمضية الكحولات إذا كان بإمكانك تراجعوا
+
+476
+00:43:35,090 --> 00:43:39,530
+مفهوم الحمضية مما تعلمته سابقا بيكون جيد
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..cd9a7f815ca6f68d3936894f12a8434e2ec2fdab
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4637, "start": 19.47, "end": 46.37, "text": "بسم الله الرحمن الرحيم بدأنا من محاضرة او محاضرتين في موضوع ال الديهيدس والكيتونز اتعرفنا عليهم ليش اتصنفوا مع بعض تسمية ال الديهيدس والكيتونز طرق صناعية لتحضير اشهر ال الديهيدس والكيتونز كان اخر شيء اتكلمنا عنه الان في المختبر الطرق العامة لتحضير ال الديهيدس والكيتونز", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 47525, 10721, 8315, 9154, 3714, 5016, 46958, 25720, 1975, 2407, 3714, 5016, 46958, 43500, 9957, 8978, 3714, 2407, 11242, 45367, 2423, 2423, 16254, 3224, 25708, 3794, 16070, 4117, 36081, 11536, 11622, 1975, 2655, 3615, 28480, 8315, 25894, 16095, 32239, 8592, 1975, 2655, 9381, 1863, 5172, 14407, 20449, 45030, 11242, 6055, 38251, 10632, 2423, 2423, 16254, 3224, 25708, 3794, 16070, 4117, 36081, 11536, 11622, 23032, 2288, 4587, 20328, 8315, 3615, 10632, 5296, 2655, 5016, 11242, 13546, 1975, 8592, 3224, 2288, 2423, 2423, 16254, 3224, 25708, 3794, 16070, 4117, 36081, 11536, 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1.0}, {"id": 12, "seek": 30252, "start": 285.2, "end": 302.52, "text": "بالاختصار هيرجع ايش؟ هيرجع لالكول وسبق احنا انه وضحنا معنى الأكسادة ان هي في النهاية اما انها زيادة في المحتوى الاكسوجيني او نقص في محتوى الهيدروجيني", "tokens": [3555, 6027, 47283, 2655, 9381, 9640, 8032, 13546, 7435, 3615, 1975, 1829, 8592, 22807, 8032, 13546, 7435, 3615, 5296, 6027, 4117, 12610, 4032, 35457, 4587, 1975, 5016, 8315, 16472, 3224, 4032, 11242, 5016, 8315, 20449, 1863, 7578, 16247, 4117, 3794, 18513, 3660, 16472, 39896, 8978, 28239, 11296, 10632, 1975, 15042, 16472, 11296, 30767, 1829, 18513, 3660, 8978, 9673, 33753, 2407, 7578, 42963, 4117, 3794, 29245, 9957, 1829, 1975, 2407, 8717, 4587, 9381, 8978, 3714, 33753, 2407, 7578, 2423, 3224, 25708, 2288, 29245, 9957, 1829], "avg_logprob": -0.21783087604186113, "compression_ratio": 1.832214765100671, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 285.2, "end": 286.16, "word": "بالاختصار", "probability": 0.8638509114583334}, {"start": 286.16, "end": 287.56, "word": " هيرجع", "probability": 0.787261962890625}, {"start": 287.56, "end": 288.0, "word": " ايش؟", "probability": 0.649627685546875}, {"start": 288.0, "end": 288.84, "word": " هيرجع", "probability": 0.94873046875}, {"start": 288.84, "end": 290.02, "word": " لالكول", "probability": 0.6729736328125}, {"start": 290.02, "end": 290.82, "word": " وسبق", "probability": 0.8030598958333334}, {"start": 290.82, "end": 291.16, "word": " احنا", "probability": 0.9306640625}, {"start": 291.16, "end": 291.74, "word": " انه", "probability": 0.70458984375}, {"start": 291.74, "end": 292.24, "word": " وضحنا", "probability": 0.970458984375}, {"start": 292.24, "end": 292.6, "word": " معنى", "probability": 0.9422200520833334}, {"start": 292.6, "end": 293.42, "word": " الأكسادة", "probability": 0.6673583984375}, {"start": 293.42, "end": 293.74, "word": " ان", "probability": 0.86083984375}, {"start": 293.74, "end": 293.94, "word": " هي", "probability": 0.2464599609375}, {"start": 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cinnamon cinnamon يعني جرفة", "tokens": [2407, 46958, 5016, 22807, 8978, 30767, 36081, 37893, 3224, 13063, 24525, 2304, 3224, 30767, 36081, 13672, 2407, 11622, 45164, 5551, 3794, 2288, 8315, 13672, 2407, 11622, 4724, 1829, 9566, 1211, 3615, 9154, 3224, 30767, 36081, 13672, 1829, 31439, 2423, 44335, 16798, 68, 3495, 1479, 23758, 2423, 16798, 68, 3495, 1479, 13672, 1829, 13412, 995, 33911, 9957, 3224, 383, 3834, 6086, 13931, 20449, 11331, 1211, 28671, 44945, 11622, 9957, 4032, 3834, 6086, 23758, 3714, 31747, 3555, 9122, 10943, 1211, 23758, 24525, 2304, 3224, 6539, 5378, 304, 1479, 3495, 1479, 6539, 5378, 304, 1479, 3495, 1479, 10874, 995, 10632, 9154, 2423, 6539, 5378, 266, 6539, 5378, 266, 37495, 22653, 10874, 28480, 3660], "avg_logprob": -0.16905967850942868, "compression_ratio": 1.7677725118483412, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 336.32, "end": 337.0, "word": "واضح؟", "probability": 0.6759033203125}, {"start": 337.0, "end": 337.24, "word": " في", 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32277, 1829, 13672, 1829, 4724, 40228, 9566, 1829, 25724, 28480, 3660, 2423, 16572, 5016, 3660, 6055, 3555, 34268, 11296, 5296, 33456, 25724, 28480, 3660, 24525, 2304, 11296, 22969, 31439, 8608, 2304, 2407, 3224, 11933, 1829, 8592, 22807], "avg_logprob": -0.14554687678813935, "compression_ratio": 1.3916666666666666, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 361.48, "end": 362.74, "word": "واضح؟", "probability": 0.8936767578125}, {"start": 362.74, "end": 363.56, "word": " فهو", "probability": 0.95361328125}, {"start": 363.56, "end": 364.68, "word": " المركب", "probability": 0.833984375}, {"start": 364.68, "end": 365.64, "word": " الأساسي", "probability": 0.97216796875}, {"start": 365.64, "end": 365.88, "word": " اللي", "probability": 0.829833984375}, {"start": 365.88, "end": 366.36, "word": " بيعطي", "probability": 0.9271240234375}, {"start": 366.36, "end": 367.02, "word": " الجرفة", "probability": 0.8831380208333334}, {"start": 367.02, "end": 368.3, "word": " الريحة", "probability": 0.9078369140625}, {"start": 368.3, "end": 368.98, "word": " تبعتها", "probability": 0.96435546875}, {"start": 368.98, "end": 369.48, "word": " لأن", "probability": 0.615966796875}, {"start": 369.48, "end": 369.96, "word": " الجرفة", "probability": 0.95556640625}, {"start": 369.96, "end": 370.36, "word": " اسمها", "probability": 0.9658203125}, {"start": 370.36, "end": 370.98, "word": " cinnamon", "probability": 0.329833984375}, {"start": 370.98, "end": 371.78, "word": " هو", "probability": 0.63671875}, {"start": 371.78, "end": 372.24, "word": " سموه", "probability": 0.8697509765625}, {"start": 372.24, "end": 373.1, "word": " إيش؟", "probability": 0.8765869140625}], "temperature": 1.0}, {"id": 17, "seek": 40060, "start": 373.48, "end": 400.6, "text": "cinnamaldehyde مثلا بالالماني الجرفة اسمها zimt فبيسموه zimt aldehyde واضح zimt aldehyde هنا cinnamon cinnamaldehyde واضح فهذه الجرفة اللي احنا بنتناولها في النهاية هي aldehyde مر علينا سابقا ان الفانيلة هي عبارة عن aromatic aldehyde عليه مجموعة هيدروكسي وميثوكسي الفانيلين", "tokens": [20021, 5378, 304, 1479, 3495, 1479, 50113, 15040, 20666, 45340, 7649, 1829, 25724, 28480, 3660, 24525, 2304, 11296, 710, 332, 83, 6156, 21292, 38251, 2407, 3224, 710, 332, 83, 16798, 68, 3495, 1479, 4032, 46958, 5016, 710, 332, 83, 16798, 68, 3495, 1479, 34105, 6539, 5378, 266, 6539, 5378, 304, 1479, 3495, 1479, 4032, 46958, 5016, 6156, 3224, 24192, 25724, 28480, 3660, 13672, 1829, 1975, 5016, 8315, 44945, 2655, 8315, 12610, 11296, 8978, 28239, 11296, 10632, 39896, 16798, 68, 3495, 1479, 3714, 2288, 25894, 8315, 8608, 16758, 4587, 995, 16472, 27188, 7649, 26895, 3660, 39896, 6225, 3555, 9640, 3660, 18871, 45831, 16798, 68, 3495, 1479, 47356, 3714, 7435, 2304, 2407, 27884, 8032, 25708, 32887, 4117, 3794, 1829, 4032, 2304, 1829, 12984, 2407, 4117, 3794, 1829, 27188, 7649, 26895, 9957], "avg_logprob": -0.22199518726422238, "compression_ratio": 1.91324200913242, "no_speech_prob": 5.364418029785156e-07, "words": 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الان احنا اتفقنا لما بدى يعمل hydrate هدول المجمعتين مافيش فيهم تغيير طب ها شو بدى يصير ال C double bond O بتصير O H والمية بتضيف O H هذا بتصير benz aldehyde hydrate", "tokens": [3224, 1829, 2423, 44335, 16798, 68, 3495, 1479, 383, 3834, 6086, 422, 389, 2423, 7649, 1975, 5016, 8315, 1975, 2655, 5172, 4587, 8315, 5296, 15042, 47525, 7578, 7251, 25957, 1211, 5796, 4404, 8032, 3215, 12610, 9673, 7435, 2304, 34268, 9957, 19446, 41185, 8592, 8978, 16095, 6055, 17082, 1829, 13546, 23032, 3555, 8032, 995, 13412, 2407, 47525, 7578, 7251, 9381, 13546, 2423, 383, 3834, 6086, 422, 39894, 9381, 13546, 422, 389, 16070, 2304, 10632, 39894, 11242, 33911, 422, 389, 23758, 39894, 9381, 13546, 44335, 16798, 68, 3495, 1479, 5796, 4404], "avg_logprob": -0.2678819358348846, "compression_ratio": 1.6054054054054054, "no_speech_prob": 0.0, "words": [{"start": 1058.13, "end": 1058.51, "word": "هي", "probability": 0.56866455078125}, {"start": 1058.51, "end": 1058.63, "word": " ال", "probability": 0.71484375}, 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"temperature": 1.0}, {"id": 48, "seek": 113604, "start": 1110.9, "end": 1136.04, "text": "و لذلك هذا التفاعل بيصير نوعا ما تفاعل نظري مش تفاعل عملي يعني بيكون هذا ال الديهيد او ال ketone موجود بالنسبة 99.9% و هذا موجود بالنسبة قليلة جدا و لذلك معظم ال الديهيد و ال ketones بيكون ال position of equilibrium اتجاه الاتزان فيها هل هو باتجاه ال hydrate و لا باتجاه ال الديهيد او ال ketone", "tokens": [2407, 5296, 8848, 23275, 23758, 16712, 5172, 995, 30241, 4724, 1829, 9381, 13546, 8717, 45367, 995, 19446, 6055, 5172, 995, 30241, 8717, 19913, 16572, 37893, 6055, 5172, 995, 30241, 6225, 2304, 20292, 37495, 22653, 4724, 1829, 30544, 23758, 2423, 2423, 16254, 3224, 25708, 1975, 2407, 2423, 14979, 546, 3714, 29245, 23328, 20666, 1863, 35457, 3660, 11803, 13, 24, 4, 4032, 23758, 3714, 29245, 23328, 20666, 1863, 35457, 3660, 12174, 20292, 37977, 10874, 28259, 4032, 5296, 8848, 23275, 20449, 19913, 2304, 2423, 2423, 16254, 3224, 25708, 4032, 2423, 14979, 2213, 4724, 1829, 30544, 2423, 2535, 295, 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لأ؟ أكيد لأن high carbon حاملة OH", "tokens": [31187, 1975, 5016, 8315, 12174, 1211, 8315, 8978, 28242, 16247, 5016, 2407, 6027, 11778, 16373, 15042, 2423, 383, 3834, 6086, 422, 39894, 9381, 13546, 13931, 7251, 43020, 8978, 28242, 16247, 2304, 12984, 37977, 21136, 16758, 28671, 12602, 38251, 8315, 11296, 20666, 10721, 9778, 11242, 2288, 4032, 2423, 14962, 49242, 8032, 26108, 2304, 39627, 15730, 25124, 28820, 6024, 48506, 23758, 9673, 31747, 3555, 13672, 1829, 44650, 30544, 43242, 3224, 36632, 11242, 995, 8636, 326, 302, 304, 49429, 5296, 10721, 22807, 5551, 4117, 25708, 5296, 33456, 1090, 5954, 11331, 10943, 37977, 13931], "avg_logprob": -0.2529189580089443, "compression_ratio": 1.5304347826086957, "no_speech_prob": 0.0, "words": [{"start": 1633.01, "end": 1633.57, "word": "OH", "probability": 0.1492919921875}, {"start": 1633.57, "end": 1633.95, "word": " احنا", "probability": 0.7135416666666666}, {"start": 1633.95, "end": 1634.21, "word": " قلنا", "probability": 0.89453125}, {"start": 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"هذا", "probability": 0.876953125}, {"start": 1661.7, "end": 1663.26, "word": " Hemacetal", "probability": 0.627227783203125}, {"start": 1663.26, "end": 1663.78, "word": " لكن", "probability": 0.591796875}, {"start": 1663.78, "end": 1664.52, "word": " التفاعل", "probability": 0.93505859375}, {"start": 1664.52, "end": 1664.96, "word": " بهذه", "probability": 0.613525390625}, {"start": 1664.96, "end": 1665.56, "word": " الحالة", "probability": 0.9720052083333334}, {"start": 1665.56, "end": 1667.54, "word": " Intramolecular", "probability": 0.7440185546875}, {"start": 1667.54, "end": 1668.3, "word": " reaction", "probability": 0.63525390625}, {"start": 1668.3, "end": 1669.28, "word": " الان", "probability": 0.54010009765625}, {"start": 1669.28, "end": 1669.94, "word": " هذا", "probability": 0.85693359375}, {"start": 1669.94, "end": 1670.84, "word": " التفاعل", "probability": 0.9708251953125}, {"start": 1670.84, "end": 1671.8, "word": " جزء", "probability": 0.97119140625}, {"start": 1671.8, "end": 1672.0, "word": " من", "probability": 0.99169921875}, {"start": 1672.0, "end": 1672.98, "word": " أهميته", "probability": 0.923828125}, {"start": 1672.98, "end": 1673.84, "word": " انه", "probability": 0.5780029296875}, {"start": 1673.84, "end": 1673.94, "word": " في", "probability": 0.9404296875}, {"start": 1673.94, "end": 1674.08, "word": " ال", "probability": 0.904296875}, {"start": 1674.08, "end": 1675.04, "word": " biochemistry", "probability": 0.872802734375}], "temperature": 1.0}, {"id": 70, "seek": 170253, "start": 1676.87, "end": 1702.53, "text": "إذا عندكم فكرة خفيفة أو هيمر عليكم لما بناخد السكريات ال sugars احنا قولنا ال sugars they are polyhydroxy aldehydes او كيتون هى عبارة عن الديهيد او كيتون مع مجموعات اوقاتش كبيرة الديهيد لحاله بيعملش sugar ومجموعات اوقاتش كتيرة لحالها بتعملش ايش sugar فال sugar عبارة عن ايش", "tokens": [28814, 15730, 43242, 24793, 6156, 4117, 25720, 16490, 5172, 33911, 3660, 34051, 39896, 29973, 25894, 24793, 5296, 15042, 44945, 47283, 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فكرة", "probability": 0.9949544270833334}, {"start": 1677.87, "end": 1678.39, "word": " خفيفة", "probability": 0.9837646484375}, {"start": 1678.39, "end": 1678.57, "word": " أو", "probability": 0.779296875}, {"start": 1678.57, "end": 1679.13, "word": " هيمر", "probability": 0.639404296875}, {"start": 1679.13, "end": 1679.87, "word": " عليكم", "probability": 0.968994140625}, {"start": 1679.87, "end": 1680.49, "word": " لما", "probability": 0.880615234375}, {"start": 1680.49, "end": 1680.95, "word": " بناخد", "probability": 0.96875}, {"start": 1680.95, "end": 1682.07, "word": " السكريات", "probability": 0.946044921875}, {"start": 1682.07, "end": 1682.23, "word": " ال", "probability": 0.462890625}, {"start": 1682.23, "end": 1682.73, "word": " sugars", "probability": 0.7275390625}, {"start": 1682.73, "end": 1683.19, "word": " احنا", "probability": 0.8678385416666666}, {"start": 1683.19, "end": 1683.49, "word": " قولنا", "probability": 0.8509114583333334}, {"start": 1683.49, "end": 1683.61, "word": " ال", "probability": 0.59814453125}, {"start": 1683.61, "end": 1684.11, "word": " sugars", "probability": 0.97216796875}, {"start": 1684.11, "end": 1684.71, "word": " they", "probability": 0.60400390625}, {"start": 1684.71, "end": 1685.33, "word": " are", "probability": 0.95751953125}, {"start": 1685.33, "end": 1687.07, "word": " polyhydroxy", "probability": 0.72607421875}, {"start": 1687.07, "end": 1687.89, "word": " aldehydes", "probability": 0.805419921875}, {"start": 1687.89, "end": 1688.15, "word": " او", "probability": 0.80224609375}, {"start": 1688.15, "end": 1688.67, "word": " كيتون", "probability": 0.7600911458333334}, {"start": 1688.67, "end": 1689.29, "word": " هى", "probability": 0.621337890625}, {"start": 1689.29, "end": 1689.73, "word": " عبارة", "probability": 0.989501953125}, {"start": 1689.73, "end": 1689.95, "word": " عن", "probability": 0.99462890625}, {"start": 1689.95, "end": 1690.85, "word": " الديهيد", "probability": 0.62445068359375}, {"start": 1690.85, "end": 1691.37, "word": " او", "probability": 0.97265625}, {"start": 1691.37, "end": 1691.83, "word": " كيتون", "probability": 0.9658203125}, {"start": 1691.83, "end": 1692.05, "word": " مع", "probability": 0.98681640625}, {"start": 1692.05, "end": 1692.89, "word": " مجموعات", "probability": 0.97685546875}, {"start": 1692.89, "end": 1693.79, "word": " اوقاتش", "probability": 0.70843505859375}, {"start": 1693.79, "end": 1694.19, "word": " كبيرة", "probability": 0.98828125}, {"start": 1694.19, "end": 1694.67, "word": " الديهيد", "probability": 0.89599609375}, {"start": 1694.67, "end": 1695.09, "word": " لحاله", "probability": 0.9761962890625}, {"start": 1695.09, "end": 1695.61, "word": " بيعملش", "probability": 0.87646484375}, {"start": 1695.61, "end": 1696.03, "word": " sugar", "probability": 0.71044921875}, {"start": 1696.03, "end": 1697.51, "word": " ومجموعات", "probability": 0.8773600260416666}, {"start": 1697.51, "end": 1698.01, "word": " اوقاتش", "probability": 0.9383544921875}, {"start": 1698.01, "end": 1698.37, "word": " كتيرة", "probability": 0.9264322916666666}, {"start": 1698.37, "end": 1698.85, "word": " لحالها", "probability": 0.9884033203125}, {"start": 1698.85, "end": 1699.53, "word": " بتعملش", "probability": 0.952392578125}, {"start": 1699.53, "end": 1699.89, "word": " ايش", "probability": 0.7294108072916666}, {"start": 1699.89, "end": 1700.67, "word": " sugar", "probability": 0.289794921875}, {"start": 1700.67, "end": 1701.23, "word": " فال", "probability": 0.84228515625}, {"start": 1701.23, "end": 1701.49, "word": " sugar", "probability": 0.92919921875}, {"start": 1701.49, "end": 1701.93, "word": " عبارة", "probability": 0.996826171875}, {"start": 1701.93, "end": 1702.13, "word": " عن", "probability": 0.984375}, {"start": 1702.13, "end": 1702.53, "word": " ايش", "probability": 0.9484049479166666}], "temperature": 1.0}, {"id": 71, "seek": 171583, "start": 1703.75, "end": 1715.83, "text": "موجود فيه يا الديهايد يا كيتون ومجموعات OH's الآن طالما وجد فيه على جهة معينة الديهايد او كيتون هي C double bond او نتخيل هيك وع الجهة التانية", "tokens": [2304, 29245, 23328, 8978, 3224, 7251, 995, 2423, 16254, 11296, 25708, 35186, 9122, 36081, 11536, 4032, 2304, 7435, 2304, 45367, 9307, 13931, 311, 6024, 48506, 23032, 6027, 15042, 49610, 3215, 8978, 3224, 15844, 10874, 3224, 3660, 20449, 9957, 3660, 2423, 16254, 11296, 25708, 1975, 2407, 9122, 36081, 11536, 39896, 383, 3834, 6086, 1975, 2407, 8717, 2655, 9778, 26895, 39896, 4117, 4032, 3615, 25724, 3224, 3660, 16712, 7649, 10632], "avg_logprob": -0.3453351328338402, "compression_ratio": 1.5816993464052287, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1703.75, "end": 1704.37, "word": "موجود", "probability": 0.7300211588541666}, {"start": 1704.37, "end": 1704.73, "word": " فيه", "probability": 0.6978759765625}, {"start": 1704.73, "end": 1704.85, "word": " يا", "probability": 0.30157470703125}, {"start": 1704.85, "end": 1705.41, "word": " الديهايد", "probability": 0.724853515625}, {"start": 1705.41, "end": 1705.59, "word": " يا", "probability": 0.257080078125}, {"start": 1705.59, "end": 1706.13, "word": " كيتون", "probability": 0.8232421875}, {"start": 1706.13, "end": 1707.03, "word": " ومجموعات", "probability": 0.930419921875}, {"start": 1707.03, "end": 1707.95, "word": " OH's", "probability": 0.375244140625}, {"start": 1707.95, "end": 1708.47, "word": " الآن", "probability": 0.55535888671875}, {"start": 1708.47, "end": 1709.01, "word": " طالما", "probability": 0.962890625}, {"start": 1709.01, "end": 1709.45, "word": " وجد", "probability": 0.6591796875}, {"start": 1709.45, "end": 1709.99, "word": " فيه", "probability": 0.902099609375}, {"start": 1709.99, "end": 1710.17, "word": " على", "probability": 0.8173828125}, {"start": 1710.17, "end": 1710.55, "word": " جهة", "probability": 0.9866536458333334}, {"start": 1710.55, "end": 1711.29, "word": " معينة", "probability": 0.9754231770833334}, {"start": 1711.29, "end": 1711.97, "word": " الديهايد", "probability": 0.94775390625}, {"start": 1711.97, "end": 1712.23, "word": " او", "probability": 0.84033203125}, {"start": 1712.23, "end": 1712.63, "word": " كيتون", "probability": 0.9376627604166666}, {"start": 1712.63, "end": 1712.81, "word": " هي", "probability": 0.1904296875}, {"start": 1712.81, "end": 1713.03, "word": " C", "probability": 0.464111328125}, {"start": 1713.03, "end": 1713.25, "word": " double", "probability": 0.211181640625}, {"start": 1713.25, "end": 1713.59, "word": " bond", "probability": 0.93505859375}, {"start": 1713.59, "end": 1713.77, "word": " او", "probability": 0.5384521484375}, {"start": 1713.77, "end": 1714.19, "word": " نتخيل", "probability": 0.89990234375}, {"start": 1714.19, "end": 1714.49, "word": " هيك", "probability": 0.880615234375}, {"start": 1714.49, "end": 1714.95, "word": " وع", "probability": 0.806884765625}, {"start": 1714.95, "end": 1715.33, "word": " الجهة", "probability": 0.7226155598958334}, {"start": 1715.33, "end": 1715.83, "word": " التانية", "probability": 0.9876302083333334}], "temperature": 1.0}, {"id": 72, "seek": 173896, "start": 1717.06, "end": 1738.96, "text": "أو أتشز ممكن هذه ال أو أتشز تسكر على ال الديهايد أو ال كيتون أكيد بتعمل في هذه الحالة hemeacetal بس لما تسكر بدل ما ال sugar كان عامل سلسلة بهذا الشكل ال chain بيصير إيش in the cyclic form كل كمار عليكوا أن السكر بيكون في ال chain form", "tokens": [10721, 2407, 5551, 2655, 8592, 11622, 3714, 43020, 29538, 2423, 34051, 5551, 2655, 8592, 11622, 6055, 3794, 37983, 15844, 2423, 2423, 16254, 11296, 25708, 34051, 2423, 9122, 36081, 11536, 5551, 4117, 25708, 39894, 25957, 1211, 8978, 29538, 21542, 6027, 3660, 415, 1398, 326, 302, 304, 4724, 3794, 5296, 15042, 6055, 3794, 37983, 47525, 1211, 19446, 2423, 5076, 25961, 6225, 10943, 1211, 8608, 1211, 3794, 37977, 39627, 15730, 25124, 28820, 2423, 5021, 4724, 1829, 9381, 13546, 11933, 1829, 8592, 294, 264, 38154, 1050, 1254, 28242, 9122, 2304, 9640, 25894, 4117, 14407, 14739, 21136, 37983, 4724, 1829, 30544, 8978, 2423, 5021, 1254], "avg_logprob": -0.26779083332212844, "compression_ratio": 1.7453703703703705, "no_speech_prob": 0.0, "words": [{"start": 1717.06, "end": 1717.4, "word": "أو", "probability": 0.4790802001953125}, {"start": 1717.4, "end": 1718.04, "word": " أتشز", "probability": 0.72125244140625}, {"start": 1718.04, "end": 1718.7, "word": " ممكن", "probability": 0.720947265625}, {"start": 1718.7, "end": 1719.06, "word": " هذه", "probability": 0.744140625}, {"start": 1719.06, "end": 1719.24, "word": " ال", "probability": 0.7255859375}, {"start": 1719.24, "end": 1719.38, "word": " أو", "probability": 0.1678466796875}, {"start": 1719.38, "end": 1719.88, "word": " أتشز", "probability": 0.9578857421875}, {"start": 1719.88, "end": 1720.48, "word": " تسكر", "probability": 0.7117513020833334}, {"start": 1720.48, "end": 1720.98, "word": " على", "probability": 0.7900390625}, {"start": 1720.98, "end": 1721.12, "word": " ال", "probability": 0.76171875}, {"start": 1721.12, "end": 1721.58, "word": " الديهايد", "probability": 0.6976318359375}, {"start": 1721.58, "end": 1721.76, "word": " أو", "probability": 0.59228515625}, {"start": 1721.76, "end": 1721.92, "word": " ال", "probability": 0.55419921875}, {"start": 1721.92, "end": 1722.42, "word": " كيتون", "probability": 0.8084309895833334}, {"start": 1722.42, "end": 1723.62, "word": " أكيد", "probability": 0.7836100260416666}, {"start": 1723.62, "end": 1724.4, "word": " بتعمل", "probability": 0.8699544270833334}, {"start": 1724.4, "end": 1724.52, "word": " في", "probability": 0.85546875}, {"start": 1724.52, "end": 1724.74, "word": " هذه", "probability": 0.8896484375}, {"start": 1724.74, "end": 1725.6, "word": " الحالة", "probability": 0.984375}, {"start": 1725.6, "end": 1726.64, "word": " hemeacetal", "probability": 0.6638916015625}, {"start": 1726.64, "end": 1727.14, "word": " بس", "probability": 0.917236328125}, {"start": 1727.14, "end": 1727.34, "word": " لما", "probability": 0.961669921875}, {"start": 1727.34, "end": 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Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone", "tokens": [34, 6277, 1445, 292, 2044, 45164, 6225, 42213, 39237, 20449, 2423, 39184, 10295, 66, 752, 675, 87, 282, 546, 8032, 8848, 1829, 2423, 39184, 383, 3834, 6086, 422, 11933, 1829, 8592, 8032, 2655, 9381, 13546, 22807, 13931, 37037, 1829, 2423, 39184, 2033, 13412, 2407, 8032, 38251, 1829, 3224, 22807, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 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{"start": 2243.53, "end": 2243.65, "word": " Cyclohexanone", "probability": 0.9896065848214286}, {"start": 2243.65, "end": 2243.81, "word": " Cyclohexanone", "probability": 0.9905133928571429}, {"start": 2243.81, "end": 2243.81, "word": " Cyclohexanone", "probability": 0.9911411830357143}, {"start": 2243.81, "end": 2244.51, "word": " Cyclohexanone", "probability": 0.9917689732142857}, {"start": 2244.51, "end": 2244.51, "word": " Cyclohexanone", "probability": 0.9921875}, {"start": 2244.51, "end": 2245.03, "word": " Cyclohexanone", "probability": 0.9924665178571429}, {"start": 2245.03, "end": 2246.93, "word": " Cyclohexanone", "probability": 0.9928152901785714}, {"start": 2246.93, "end": 2246.93, "word": " Cyclohexanone", "probability": 0.9930943080357143}, {"start": 2246.93, "end": 2246.93, "word": " Cyclohexanone", "probability": 0.9933733258928571}, {"start": 2246.93, "end": 2246.93, "word": " Cyclohexanone", "probability": 0.9937220982142857}, {"start": 2246.93, "end": 2246.93, 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"probability": 0.86572265625}, {"start": 2281.86, "end": 2282.1, "word": " صح", "probability": 0.987548828125}, {"start": 2282.1, "end": 2282.3, "word": " ولا", "probability": 0.953125}, {"start": 2282.3, "end": 2282.6, "word": " لأ", "probability": 0.90283203125}], "temperature": 1.0}, {"id": 96, "seek": 231333, "start": 2284.59, "end": 2313.33, "text": "لازم في الأصل تكون عارفة الـ Benzaldehyde مجرد ما نقولها سيانو هيدرين الـ C بابل بوند O OH OHIJNQCN مش عملية صعبة Benzaldehyde cyanohydrin واضح الفكرة؟ لاحظوا أنا كاتب له common name نفس الـ Benzaldehyde cyanohydrin له common name Manbilonitride", "tokens": [1211, 31377, 2304, 8978, 16247, 36520, 6055, 30544, 6225, 9640, 5172, 3660, 2423, 39184, 3964, 89, 304, 1479, 3495, 1479, 3714, 7435, 2288, 3215, 19446, 8717, 39648, 11296, 8608, 1829, 7649, 2407, 8032, 25708, 2288, 9957, 2423, 39184, 383, 4724, 16758, 1211, 4724, 11536, 3215, 422, 13931, 13931, 40, 41, 45, 48, 34, 45, 37893, 6225, 42213, 10632, 20328, 3615, 49401, 3964, 89, 304, 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قولنا oil of almond اللوز بالانجليزي بالالماني mandel ومن هنا استعمل mandilo nitral mandel من اللوز يعني كتير من ال common name علاقة في إيش", "tokens": [22396, 10720, 7411, 338, 20666, 45340, 7649, 1829, 37495, 22653, 5296, 2407, 11622, 16472, 2655, 14407, 39894, 15730, 37983, 9957, 12174, 36150, 13412, 2407, 10632, 5296, 15042, 5551, 9778, 3215, 8315, 2423, 44335, 304, 1479, 3495, 1479, 12174, 12610, 8315, 3184, 295, 29506, 2423, 1211, 2407, 11622, 20666, 7649, 7435, 20292, 11622, 1829, 20666, 45340, 7649, 1829, 7411, 338, 4032, 27842, 34105, 44713, 25957, 1211, 7411, 10720, 10900, 2155, 7411, 338, 9154, 13672, 2407, 11622, 37495, 22653, 9122, 2655, 13546, 9154, 2423, 2689, 1315, 11203, 995, 28671, 8978, 11933, 1829, 8592], "avg_logprob": -0.26222826734833093, "compression_ratio": 1.6748768472906403, "no_speech_prob": 0.0, "words": [{"start": 2314.29, "end": 2315.15, "word": "mandilo", "probability": 0.3641357421875}, {"start": 2315.15, "end": 2316.23, "word": " mandel", 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"word": " قولنا", "probability": 0.8030598958333334}, {"start": 2325.79, "end": 2326.19, "word": " oil", "probability": 0.8525390625}, {"start": 2326.19, "end": 2326.75, "word": " of", "probability": 0.96728515625}, {"start": 2326.75, "end": 2327.45, "word": " almond", "probability": 0.72412109375}, {"start": 2327.45, "end": 2329.99, "word": " اللوز", "probability": 0.68499755859375}, {"start": 2329.99, "end": 2330.83, "word": " بالانجليزي", "probability": 0.9318033854166666}, {"start": 2330.83, "end": 2331.87, "word": " بالالماني", "probability": 0.950439453125}, {"start": 2331.87, "end": 2333.35, "word": " mandel", "probability": 0.828857421875}, {"start": 2333.35, "end": 2333.91, "word": " ومن", "probability": 0.774658203125}, {"start": 2333.91, "end": 2334.17, "word": " هنا", "probability": 0.98291015625}, {"start": 2334.17, "end": 2334.83, "word": " استعمل", "probability": 0.9378255208333334}, {"start": 2334.83, "end": 2335.53, "word": " mandilo", "probability": 0.72900390625}, 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"start": 2655.36, "end": 2671.48, "text": "الومينوم هايدرايد يعني نفسه ممكن تلاقوه تحت اسم ليثيام ألومينوم هايدرايد أو ليثيام تيترا هايدرايد و ألومينيت وهذا بيسموه صوديوم بورو هايدرايد مش بورون", "tokens": [6027, 20498, 9957, 20498, 8032, 995, 25708, 23557, 25708, 37495, 22653, 8717, 36178, 3224, 3714, 43020, 6055, 15040, 4587, 2407, 3224, 6055, 33753, 24525, 2304, 32239, 12984, 1829, 10943, 5551, 1211, 20498, 9957, 20498, 8032, 995, 25708, 23557, 25708, 34051, 32239, 12984, 1829, 10943, 6055, 36081, 23557, 8032, 995, 25708, 23557, 25708, 4032, 5551, 1211, 20498, 9957, 36081, 37037, 15730, 4724, 1829, 38251, 2407, 3224, 20328, 2407, 16254, 20498, 4724, 13063, 2407, 8032, 995, 25708, 23557, 25708, 37893, 4724, 13063, 11536], "avg_logprob": -0.2627667570259513, "compression_ratio": 2.036764705882353, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 2655.36, "end": 2656.14, "word": "الومينوم", "probability": 0.55133056640625}, {"start": 2656.14, "end": 2657.66, "word": " 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تيترا", "probability": 0.79248046875}, {"start": 2664.84, "end": 2665.44, "word": " هايدرايد", "probability": 0.95185546875}, {"start": 2665.44, "end": 2665.54, "word": " و", "probability": 0.615234375}, {"start": 2665.54, "end": 2666.08, "word": " ألومينيت", "probability": 0.73291015625}, {"start": 2666.08, "end": 2666.7, "word": " وهذا", "probability": 0.81103515625}, {"start": 2666.7, "end": 2667.34, "word": " بيسموه", "probability": 0.933984375}, {"start": 2667.34, "end": 2668.14, "word": " صوديوم", "probability": 0.7750244140625}, {"start": 2668.14, "end": 2669.26, "word": " بورو", "probability": 0.9134114583333334}, {"start": 2669.26, "end": 2670.08, "word": " هايدرايد", "probability": 0.861865234375}, {"start": 2670.08, "end": 2671.08, "word": " مش", "probability": 0.8359375}, {"start": 2671.08, "end": 2671.48, "word": " بورون", "probability": 0.79296875}], "temperature": 1.0}, {"id": 112, "seek": 269731, "start": 2672.57, "end": 2697.31, "text": "Borohydride فإذا سمعتوا Sodium Borohydride أو Sodium Tetrahydride و Borate نفس الاسم Lithium Tetrahydride و Aluminate أو Lithium Aluminum Hydride نفس الاسم و مرات كتير حتى الاسم هذا Sodium Borohydride و عادة مش هيكونوا عاملينه زيك هتلاعظوا على السهم مكتوب عندكم NABH4", "tokens": [33, 284, 1445, 6655, 25502, 6156, 28814, 15730, 8608, 2304, 34268, 14407, 42059, 2197, 13739, 1445, 6655, 25502, 34051, 42059, 2197, 31580, 15688, 6655, 25502, 4032, 13739, 473, 8717, 36178, 2423, 32277, 2304, 32577, 2197, 31580, 15688, 6655, 25502, 4032, 967, 7112, 473, 34051, 32577, 2197, 967, 7112, 449, 24231, 25502, 8717, 36178, 2423, 32277, 2304, 4032, 3714, 2288, 9307, 9122, 2655, 13546, 11331, 49975, 2423, 32277, 2304, 23758, 42059, 2197, 13739, 1445, 6655, 25502, 4032, 6225, 18513, 3660, 37893, 39896, 30544, 14407, 6225, 10943, 1211, 9957, 3224, 30767, 1829, 4117, 8032, 2655, 15040, 3615, 19913, 14407, 15844, 21136, 16095, 3714, 4117, 2655, 37746, 43242, 24793, 426, 13868, 39, 19], "avg_logprob": -0.19214527161271722, 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2678.77, "word": " نفس", "probability": 0.9765625}, {"start": 2678.77, "end": 2679.25, "word": " الاسم", "probability": 0.783203125}, {"start": 2679.25, "end": 2681.01, "word": " Lithium", "probability": 0.785400390625}, {"start": 2681.01, "end": 2681.97, "word": " Tetrahydride", "probability": 0.8717041015625}, {"start": 2681.97, "end": 2682.05, "word": " و", "probability": 0.3291015625}, {"start": 2682.05, "end": 2682.67, "word": " Aluminate", "probability": 0.8507486979166666}, {"start": 2682.67, "end": 2682.85, "word": " أو", "probability": 0.7509765625}, {"start": 2682.85, "end": 2683.33, "word": " Lithium", "probability": 0.9267578125}, {"start": 2683.33, "end": 2683.87, "word": " Aluminum", "probability": 0.8507486979166666}, {"start": 2683.87, "end": 2684.47, "word": " Hydride", "probability": 0.65869140625}, {"start": 2684.47, "end": 2684.77, "word": " نفس", "probability": 0.97314453125}, {"start": 2684.77, "end": 2685.85, "word": " الاسم", "probability": 0.9015299479166666}, 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اه اذا هل جيتها بنصير نكتب reduction عشان تكون واضحة الأمور معاكم قبل الديهايدs produces primary alcohol", "tokens": [27375, 822, 7658, 1975, 15730, 16472, 2655, 3555, 3224, 14407, 20449, 1829, 10874, 25708, 995, 16472, 3224, 5296, 15042, 2423, 3224, 7435, 20498, 46811, 15844, 2423, 2423, 16254, 11296, 25708, 6225, 995, 16254, 1975, 2655, 4117, 12610, 1975, 3224, 1975, 15730, 8032, 1211, 10874, 36081, 11296, 44945, 9381, 13546, 8717, 4117, 2655, 3555, 11004, 6225, 8592, 7649, 6055, 30544, 4032, 46958, 5016, 3660, 16247, 2304, 13063, 20449, 995, 24793, 12174, 36150, 2423, 16254, 11296, 25708, 82, 14725, 6194, 7658], "avg_logprob": -0.24843748658895493, "compression_ratio": 1.5797872340425532, "no_speech_prob": 0.0, "words": [{"start": 2751.01, "end": 2751.83, "word": "secondary", "probability": 0.76318359375}, {"start": 2751.83, "end": 2752.37, "word": " alcohol", "probability": 0.869140625}, {"start": 2752.37, "end": 2752.87, "word": " اذا", "probability": 0.581787109375}, {"start": 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"end": 2800.24, "word": " ال", "probability": 0.7021484375}, {"start": 2800.24, "end": 2801.04, "word": " الديهايد", "probability": 0.603515625}, {"start": 2801.04, "end": 2801.28, "word": " لما", "probability": 0.7283935546875}, {"start": 2801.28, "end": 2801.8, "word": " بنعمله", "probability": 0.95849609375}, {"start": 2801.8, "end": 2802.44, "word": " reduction", "probability": 0.9208984375}, {"start": 2802.44, "end": 2804.76, "word": " بالهيدرايد", "probability": 0.627587890625}, {"start": 2804.76, "end": 2805.04, "word": " بده", "probability": 0.4464111328125}, {"start": 2805.04, "end": 2805.24, "word": " يصير", "probability": 0.9274088541666666}, {"start": 2805.24, "end": 2805.8, "word": " عنده", "probability": 0.98291015625}, {"start": 2805.8, "end": 2807.26, "word": " primary", "probability": 0.51220703125}, {"start": 2807.26, "end": 2807.96, "word": " alcohol", "probability": 0.88232421875}, {"start": 2807.96, "end": 2808.46, "word": " و", "probability": 0.642578125}, {"start": 2808.46, "end": 2808.68, "word": " ال", "probability": 0.625}, {"start": 2808.68, "end": 2809.28, "word": " ketone", "probability": 0.56146240234375}, {"start": 2809.28, "end": 2809.56, "word": " لما", "probability": 0.98388671875}, {"start": 2809.56, "end": 2810.08, "word": " بنعمله", "probability": 0.9759114583333334}, {"start": 2810.08, "end": 2810.6, "word": " reduction", "probability": 0.98876953125}, {"start": 2810.6, "end": 2810.9, "word": " بال", "probability": 0.966796875}, {"start": 2810.9, "end": 2811.62, "word": " الديهايد", "probability": 0.9195556640625}, {"start": 2811.62, "end": 2812.46, "word": " بده", "probability": 0.824951171875}, {"start": 2812.46, "end": 2812.64, "word": " يصير", "probability": 0.9869791666666666}, {"start": 2812.64, "end": 2813.34, "word": " عنده", "probability": 0.9755859375}, {"start": 2813.34, "end": 2814.24, "word": " secondary", "probability": 0.9501953125}, {"start": 2814.24, "end": 2815.06, "word": " alcohol", "probability": 0.900390625}, {"start": 2815.06, "end": 2815.92, "word": " لاحظوا", "probability": 0.8857421875}, {"start": 2815.92, "end": 2816.08, "word": " هذا", "probability": 0.935546875}, {"start": 2816.08, "end": 2816.68, "word": " الكلام", "probability": 0.9632161458333334}, {"start": 2816.68, "end": 2817.66, "word": " بفيدكم", "probability": 0.884521484375}, {"start": 2817.66, "end": 2818.02, "word": " سواء", "probability": 0.9640299479166666}, {"start": 2818.02, "end": 2818.48, "word": " بجمل", "probability": 0.6729329427083334}, {"start": 2818.48, "end": 2818.8, "word": " صح", "probability": 0.9921875}, {"start": 2818.8, "end": 2818.94, "word": " و", "probability": 0.63427734375}, {"start": 2818.94, "end": 2819.34, "word": " غلط", "probability": 0.9580078125}, {"start": 2819.34, "end": 2819.96, "word": " بأكمل", "probability": 0.818115234375}, {"start": 2819.96, "end": 2820.56, "word": " معادلة", "probability": 0.9825846354166666}, {"start": 2820.56, "end": 2821.08, "word": " او", "probability": 0.773681640625}, {"start": 2821.08, "end": 2821.6, "word": " حتى", "probability": 0.871337890625}, {"start": 2821.6, "end": 2822.06, "word": " لو", "probability": 0.96435546875}, {"start": 2822.06, "end": 2822.32, "word": " احنا", "probability": 0.91259765625}, {"start": 2822.32, "end": 2822.96, "word": " سألناكوا", "probability": 0.8898111979166666}, {"start": 2822.96, "end": 2823.4, "word": " سؤال", "probability": 0.978515625}, {"start": 2823.4, "end": 2823.82, "word": " how", "probability": 0.7421875}, {"start": 2823.82, "end": 2824.16, "word": " can", "probability": 0.9130859375}, {"start": 2824.16, "end": 2824.4, "word": " you", "probability": 0.9560546875}, {"start": 2824.4, "end": 2824.94, "word": " prepare", "probability": 0.943359375}, {"start": 2824.94, "end": 2825.22, "word": " the", "probability": 0.93212890625}, {"start": 2825.22, "end": 2825.76, "word": " following", "probability": 0.88037109375}, {"start": 2825.76, "end": 2826.74, "word": " compound", "probability": 0.947265625}], "temperature": 1.0}, {"id": 118, "seek": 285669, "start": 2828.25, "end": 2856.69, "text": "واضح؟ لما تشوفوا أن الناتج اللي عندكم primary alcohol إذا بتقدروا تفكروا أنه ممكن يكون إيجا من وين لما تشوفوا الناتج اللي عندكم secondary alcohol إذا ممكن يكون إيجا من وين من كيتون واضح الفكرة؟ بنقف عند هذه النقطة المرة القادمة إن شاء الله بنحكي عن تفاعل الديهيدس والكيتون مع متفاعل اسمه green yard reagent عمرنا حكينا عنه؟", "tokens": [2407, 46958, 5016, 22807, 5296, 15042, 6055, 8592, 38688, 14407, 14739, 28239, 9307, 7435, 13672, 1829, 43242, 24793, 6194, 7658, 11933, 15730, 39894, 28543, 2288, 14407, 6055, 5172, 37983, 14407, 14739, 3224, 3714, 43020, 7251, 30544, 11933, 1829, 7435, 995, 9154, 4032, 9957, 5296, 15042, 6055, 8592, 38688, 14407, 28239, 9307, 7435, 13672, 1829, 43242, 24793, 11396, 7658, 11933, 15730, 3714, 43020, 7251, 30544, 11933, 1829, 7435, 995, 9154, 4032, 9957, 9154, 9122, 36081, 11536, 4032, 46958, 5016, 27188, 4117, 25720, 22807, 44945, 4587, 5172, 43242, 29538, 28239, 47432, 3660, 9673, 25720, 25062, 18513, 46007, 36145, 13412, 16606, 21984, 44945, 5016, 4117, 1829, 18871, 6055, 5172, 995, 30241, 2423, 16254, 3224, 25708, 3794, 16070, 4117, 36081, 11536, 20449, 44650, 5172, 995, 30241, 24525, 2304, 3224, 3092, 11682, 26949, 317, 6225, 29973, 8315, 11331, 4117, 1829, 8315, 18871, 3224, 22807], "avg_logprob": -0.1834821442408221, "compression_ratio": 2.0185873605947955, "no_speech_prob": 0.0, "words": [{"start": 2828.25, "end": 2828.99, "word": "واضح؟", "probability": 0.7799072265625}, {"start": 2828.99, "end": 2829.21, "word": " لما", "probability": 0.857666015625}, {"start": 2829.21, "end": 2829.63, "word": " تشوفوا", "probability": 0.966064453125}, {"start": 2829.63, "end": 2829.71, "word": " أن", "probability": 0.38037109375}, {"start": 2829.71, "end": 2830.19, "word": " الناتج", "probability": 0.7259928385416666}, {"start": 2830.19, "end": 2830.35, "word": " اللي", "probability": 0.8193359375}, {"start": 2830.35, "end": 2830.63, "word": " عندكم", "probability": 0.955078125}, {"start": 2830.63, "end": 2831.15, "word": " primary", "probability": 0.492431640625}, {"start": 2831.15, "end": 2831.97, "word": " alcohol", "probability": 0.83837890625}, {"start": 2831.97, "end": 2832.61, "word": " إذا", "probability": 0.69189453125}, {"start": 2832.61, "end": 2833.17, "word": " بتقدروا", "probability": 0.9326171875}, {"start": 2833.17, "end": 2833.67, "word": " تفكروا", "probability": 0.95654296875}, {"start": 2833.67, "end": 2833.89, "word": " أنه", "probability": 0.802490234375}, {"start": 2833.89, "end": 2834.19, "word": " ممكن", "probability": 0.931640625}, {"start": 2834.19, "end": 2834.47, "word": " يكون", "probability": 0.85888671875}, {"start": 2834.47, "end": 2834.77, "word": " إيجا", "probability": 0.7686767578125}, {"start": 2834.77, "end": 2834.89, "word": " من", "probability": 0.99169921875}, {"start": 2834.89, "end": 2835.21, "word": " وين", "probability": 0.922119140625}, {"start": 2835.21, "end": 2836.53, "word": " لما", "probability": 0.5748291015625}, {"start": 2836.53, "end": 2836.85, "word": " تشوفوا", "probability": 0.98876953125}, {"start": 2836.85, "end": 2837.21, "word": " الناتج", "probability": 0.8981119791666666}, {"start": 2837.21, "end": 2837.35, "word": " اللي", "probability": 0.991943359375}, {"start": 2837.35, "end": 2837.77, "word": " عندكم", "probability": 0.987060546875}, {"start": 2837.77, "end": 2838.59, "word": " secondary", "probability": 0.91748046875}, {"start": 2838.59, "end": 2839.43, "word": " alcohol", "probability": 0.86962890625}, {"start": 2839.43, "end": 2839.93, "word": " إذا", "probability": 0.96435546875}, {"start": 2839.93, "end": 2840.31, "word": " ممكن", "probability": 0.97998046875}, {"start": 2840.31, "end": 2840.55, "word": " يكون", "probability": 0.98291015625}, {"start": 2840.55, "end": 2840.85, "word": " إيجا", "probability": 0.976318359375}, {"start": 2840.85, "end": 2841.01, "word": " من", "probability": 0.9931640625}, {"start": 2841.01, "end": 2841.33, "word": " وين", "probability": 0.897216796875}, {"start": 2841.33, "end": 2842.47, "word": " من", "probability": 0.62744140625}, {"start": 2842.47, "end": 2843.11, "word": " كيتون", "probability": 0.695068359375}, {"start": 2843.11, "end": 2843.95, "word": " واضح", "probability": 0.9069010416666666}, {"start": 2843.95, "end": 2844.97, "word": " الفكرة؟", "probability": 0.8421630859375}, {"start": 2844.97, "end": 2845.43, "word": " بنقف", "probability": 0.80517578125}, {"start": 2845.43, "end": 2845.65, "word": " عند", "probability": 0.98291015625}, {"start": 2845.65, "end": 2845.87, "word": " هذه", "probability": 0.76318359375}, {"start": 2845.87, "end": 2846.33, "word": " النقطة", "probability": 0.984375}, {"start": 2846.33, "end": 2846.65, "word": " المرة", "probability": 0.892822265625}, {"start": 2846.65, "end": 2847.61, "word": " القادمة", "probability": 0.9892578125}, {"start": 2847.61, "end": 2847.79, "word": " إن", "probability": 0.432861328125}, {"start": 2847.79, "end": 2847.95, "word": " شاء", "probability": 0.96630859375}, {"start": 2847.95, "end": 2848.11, "word": " الله", "probability": 0.95751953125}, {"start": 2848.11, "end": 2849.21, "word": " بنحكي", "probability": 0.91943359375}, {"start": 2849.21, "end": 2849.51, "word": " عن", "probability": 0.98779296875}, {"start": 2849.51, "end": 2850.19, "word": " تفاعل", "probability": 0.9427490234375}, {"start": 2850.19, "end": 2850.83, "word": " الديهيدس", "probability": 0.658349609375}, {"start": 2850.83, "end": 2851.57, "word": " والكيتون", "probability": 0.8038330078125}, {"start": 2851.57, "end": 2852.23, "word": " مع", "probability": 0.759765625}, {"start": 2852.23, "end": 2853.23, "word": " متفاعل", "probability": 0.886474609375}, {"start": 2853.23, "end": 2853.87, "word": " اسمه", "probability": 0.9244791666666666}, {"start": 2853.87, "end": 2854.31, "word": " green", "probability": 0.364990234375}, {"start": 2854.31, "end": 2854.69, "word": " yard", "probability": 0.335693359375}, {"start": 2854.69, "end": 2855.27, "word": " reagent", "probability": 0.878662109375}, {"start": 2855.27, "end": 2855.67, "word": " عمرنا", "probability": 0.939453125}, {"start": 2855.67, "end": 2856.11, "word": " حكينا", "probability": 0.98974609375}, {"start": 2856.11, "end": 2856.69, "word": " عنه؟", "probability": 0.94287109375}], "temperature": 1.0}, {"id": 119, "seek": 286622, "start": 2857.32, "end": 2866.22, "text": "بنعرفه المرة الجاية وبنشوف كيف بتفاعل ال الديهيد والكيتون مع ال green yard reagent شكرا", "tokens": [3555, 1863, 3615, 28480, 3224, 9673, 25720, 25724, 995, 10632, 46599, 1863, 8592, 38688, 9122, 33911, 39894, 5172, 995, 30241, 2423, 2423, 16254, 3224, 25708, 16070, 4117, 36081, 11536, 20449, 2423, 3092, 11682, 26949, 317, 13412, 4117, 23557], "avg_logprob": -0.20592948565116295, "compression_ratio": 1.2743362831858407, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2857.32, "end": 2858.04, "word": "بنعرفه", "probability": 0.9056640625}, {"start": 2858.04, "end": 2858.34, "word": " المرة", "probability": 0.928466796875}, {"start": 2858.34, "end": 2858.92, "word": " الجاية", "probability": 0.94140625}, {"start": 2858.92, "end": 2859.74, "word": " وبنشوف", "probability": 0.84423828125}, {"start": 2859.74, "end": 2860.0, "word": " كيف", "probability": 0.96826171875}, {"start": 2860.0, "end": 2860.74, "word": " بتفاعل", "probability": 0.81536865234375}, {"start": 2860.74, "end": 2861.26, "word": " ال", "probability": 0.8857421875}, {"start": 2861.26, "end": 2861.86, "word": " الديهيد", "probability": 0.71221923828125}, {"start": 2861.86, "end": 2862.66, "word": " والكيتون", "probability": 0.7459716796875}, {"start": 2862.66, "end": 2863.3, "word": " مع", "probability": 0.93017578125}, {"start": 2863.3, "end": 2863.68, "word": " ال", "probability": 0.859375}, {"start": 2863.68, "end": 2864.04, "word": " green", "probability": 0.45703125}, {"start": 2864.04, "end": 2864.44, "word": " yard", "probability": 0.73681640625}, {"start": 2864.44, "end": 2865.48, "word": " reagent", "probability": 0.8505859375}, {"start": 2865.48, "end": 2866.22, "word": " شكرا", "probability": 0.92578125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2867.01425, "duration_after_vad": 2750.2293749999894}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..2d2500e2cf61da81dd0b1492154023e34a6e6059
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_postprocess.srt
@@ -0,0 +1,2056 @@
+1
+00:00:20,280 --> 00:00:26,570
+بسم الله الرحمن الرحيمفي موضوع ال alcohols اللى
+
+2
+00:00:26,570 --> 00:00:29,970
+بدأنا فيه المرة الماضية موضوع ال acidity of
+
+3
+00:00:29,970 --> 00:00:37,870
+alcohols او حمضية الكحولات هو موضوع مهم جدا الان
+
+4
+00:00:37,870 --> 00:00:43,130
+يمكن موضوع ال acidity كمان يمر علينا باكثر من موقع
+
+5
+00:00:43,130 --> 00:00:48,110
+في ال organ chemistry ربما بشكل أساسي في ال
+
+6
+00:00:48,110 --> 00:00:53,030
+carboxylic acids يمر علينا موضوع ال acidityربما
+
+7
+00:00:53,030 --> 00:00:57,330
+المشكلة اللى بتتواجهنا أكثر شيء في الموضوع إذا
+
+8
+00:00:57,330 --> 00:01:02,410
+الطلاب من الأساس .. إذا الطلاب من الأساس ماعندهمش
+
+9
+00:01:02,410 --> 00:01:08,670
+فكرة صحيحة وسليمة عن إيش معنى الحامضية بناء على
+
+10
+00:01:08,670 --> 00:01:13,010
+ذلك أي مفهوم متطور في الموضوع بده البني أدم يحكي
+
+11
+00:01:13,010 --> 00:01:20,150
+فيه بدون وجود الأصل عند الطالب هيكون بيمثلمشكلة
+
+12
+00:01:20,150 --> 00:01:25,570
+لأنه ماعندوش أصل يبني عليه ولذلك شوية بدأ أتجاوز
+
+13
+00:01:25,570 --> 00:01:32,170
+هذا ال slide أعطي نوعا ما مقدمة صغيرة تذكيرية في
+
+14
+00:01:32,170 --> 00:01:37,730
+الجزء المهم بالنسبة لنا في موضوع الحمضية في الجزء
+
+15
+00:01:37,730 --> 00:01:43,500
+المهم بالنسبة لنا في موضوع الحمضيةالنقطة الأولى
+
+16
+00:01:43,500 --> 00:01:48,380
+يمكن اللى بتواجهكم في موضوع الأحماض أنه مر عليكم
+
+17
+00:01:48,380 --> 00:01:55,770
+أكثرمن تعريف مار عليكم أكتر من تعريف للحمض شو هو
+
+18
+00:01:55,770 --> 00:02:01,510
+الحمض و شو القلوي ربما حسب التدرج اللي اتعلمته في
+
+19
+00:02:01,510 --> 00:02:05,830
+المدارس أول ما بيمر على الناس ال Arrhenius
+
+20
+00:02:05,830 --> 00:02:10,250
+definition تعريف Arrhenius للحمض و القلوي خلنا
+
+21
+00:02:10,250 --> 00:02:16,730
+نشوفه ال Arrhenius definition من خلال مثال
+
+22
+00:02:17,780 --> 00:02:23,240
+المثال المشهور جدا لو انا كنت باخد ال HCL زائد ال
+
+23
+00:02:23,240 --> 00:02:31,120
+NAOH و متعودين تكملوا المعادلة NACL
+
+24
+00:02:31,120 --> 00:02:37,240
+زائدH2O الآن ضمن هذا التعريف كان أرهينياس بيقول
+
+25
+00:02:37,240 --> 00:02:42,180
+الحامض ببساطة هو المادة اللي بتتأين و بتعطي H plus
+
+26
+00:02:42,180 --> 00:02:49,000
+والقاعدة هي المادة اللي بتتأين و بتعطي OH minus
+
+27
+00:02:49,000 --> 00:02:53,820
+واضح؟ هذه أول تعريف، إذا الحامض المادة اللي بتتأين
+
+28
+00:02:53,820 --> 00:02:57,000
+في الميّه بيبقى تعطيني H plus والقاعدة بيبقى
+
+29
+00:02:57,000 --> 00:03:04,640
+تعطيني OH minus هذا التعريف تعريف أرهينياسالان اجى
+
+30
+00:03:04,640 --> 00:03:13,060
+لوري برونستيد نظر للموضوع شوية من زاوية تانية يعني
+
+31
+00:03:13,060 --> 00:03:17,820
+لاحظوا هنا الحامض ايش بيطلع كل ال HCL القاعدة شو
+
+32
+00:03:17,820 --> 00:03:25,980
+بتطلع كل ال NaOH اذا خليني اعمل الحامض حسب تعريف
+
+33
+00:03:25,980 --> 00:03:32,200
+Arrhenius هحوطه بالازرع هي الحامض القاعدةهي
+
+34
+00:03:32,200 --> 00:03:38,160
+القاعدة الان لوري برونستيد نظر وممكن لنفس المعادلة
+
+35
+00:03:38,160 --> 00:03:45,060
+نظرة شوية فيها تخصص بمعنى وين المركز الفاعل وين
+
+36
+00:03:45,060 --> 00:03:50,580
+المركز الفاعل اللي موجود لكن للأسف يمكن نظر
+
+37
+00:03:50,580 --> 00:03:55,640
+للقاعدة فقط مانظرش للحمض فخلى تعريف الحامض خلى
+
+38
+00:03:55,640 --> 00:04:03,220
+تعريف الحامض هاي التعريف التاني لوري برونستيدخلّى
+
+39
+00:04:03,220 --> 00:04:07,960
+تعريف الحامض زى ما هو اللى بيعطى H بلس فى التأيون
+
+40
+00:04:07,960 --> 00:04:12,440
+واضح فالحامض عند لوري برويستن شو بيعطينى H بلس
+
+41
+00:04:12,440 --> 00:04:17,600
+وبناء على ذلك وين بده يكون الحمض الـHCl كله عنده
+
+42
+00:04:17,600 --> 00:04:23,820
+حامضالـ HCl كله عند لوري برونستيد ما زال حامض،
+
+43
+00:04:23,820 --> 00:04:29,520
+الآن إجا للقاعدة، قال هي القاعدة سرها في الـ NaOH
+
+44
+00:04:29,520 --> 00:04:33,740
+يعني لو افترضنا أنها كانت KOH مثلا، بوتاسيوم
+
+45
+00:04:33,740 --> 00:04:37,930
+هيدروكسايدأو كالسيوم هيدروكسايد أو ألمنيوم
+
+46
+00:04:37,930 --> 00:04:43,670
+هيدروكسايد إفراج كتير؟ لأ إذا سير قوة القاعدة مش
+
+47
+00:04:43,670 --> 00:04:48,950
+فيها كلها لأ في ال O H و بناء على ذلك خلى القاعدة
+
+48
+00:04:48,950 --> 00:04:54,910
+هي ال O H minus مش ال N A O H شوفتوا القاعدة إيش
+
+49
+00:04:54,910 --> 00:05:00,770
+صار فيها؟ اختلفت و قال الحامض بيعطي H plus القاعدة
+
+50
+00:05:00,770 --> 00:05:07,010
+بتكتسب H plusهذه لما بدأت اكتسب الـ OH-, الـ H بلس
+
+51
+00:05:07,010 --> 00:05:11,550
+اللي فقدت هنا هي اللي هتعطيني الميه طبعا الايونات
+
+52
+00:05:11,550 --> 00:05:16,910
+المرافقة بيبقى مرافقة فصار عندي شوية اختلاف في
+
+53
+00:05:16,910 --> 00:05:25,350
+التعريف صار بيعطي H بلس بيكتسبH plus و بناء على
+
+54
+00:05:25,350 --> 00:05:31,770
+ذلك سرنا أي مادة .. سرنا أي مادة يمكن أن تكتسب H
+
+55
+00:05:31,770 --> 00:05:36,930
+plus نقدر نعتبرها قاعدة يعني بطلت القاعدة بس بال O
+
+56
+00:05:36,930 --> 00:05:41,350
+H بال hydroxides يعني بمعنى لو انا اجيت فعلت مع ال
+
+57
+00:05:41,350 --> 00:05:44,530
+ammonia ما هي ال ammonia بتكتسب H plus بتعطينا
+
+58
+00:05:44,530 --> 00:05:49,240
+ايون ال ammonium برضه تعتبر baseفكل ما يكتسب ال H
+
+59
+00:05:49,240 --> 00:05:54,140
+plus يعتبره قاعدة و كل ما يعطي ال H plus يعتبره
+
+60
+00:05:54,140 --> 00:06:00,860
+base الان لاحظوا ان هو نظر هنا نظر هنا على ال N E
+
+61
+00:06:00,860 --> 00:06:04,880
+O H و جال مركز قوتها ايش ال O H ماله و مالي الان
+
+62
+00:06:04,880 --> 00:06:10,490
+ايه فصارت ال base عنده ال O H او اي شيء يكتسبH
+
+63
+00:06:10,490 --> 00:06:15,370
+Plus لكن ما إجهاش تطلع هنا بنظرة تفصيلية طب يا
+
+64
+00:06:15,370 --> 00:06:22,530
+تورا لو كان هذا مش HCL لو كان هذا HPR بيفرق ولا HI
+
+65
+00:06:22,530 --> 00:06:28,670
+إذا لو أنا بدأ أطلع كمان بنظرة تفصيلية أكتر وين
+
+66
+00:06:28,670 --> 00:06:34,610
+مركز القوة حقيقة في ال HCL هو ال H Plus وعشان هيك
+
+67
+00:06:34,610 --> 00:06:41,220
+إجى Lewis في تعريفهزي ما أتيت هنا وأخدت مركز القوة
+
+68
+00:06:41,220 --> 00:06:44,920
+هذا تعالي ناخد مركز القوة الـ H Plus
+
+69
+00:06:49,960 --> 00:06:55,420
+الـ OH- فكأنه أخلت من هذا الجزء الأساسي فيه ومن
+
+70
+00:06:55,420 --> 00:06:59,180
+هذا الجزء الأساسي فيه اللي هي حقيقة الـ net ionic
+
+71
+00:06:59,180 --> 00:07:02,220
+equation يعني هذه لو عملت لها net ionic equation
+
+72
+00:07:02,220 --> 00:07:06,120
+الـ Na والـ Cl كلهم من شطبه هي عبارة عن H بلس زائد
+
+73
+00:07:06,120 --> 00:07:13,860
+OH- بتعطينا H2O وبناء على ذلك ال acid عند Lewis هو
+
+74
+00:07:13,860 --> 00:07:20,530
+H بلسو الـ base عنده الـ OH- الان نظر طب ايش اللي
+
+75
+00:07:20,530 --> 00:07:26,290
+بيميز هدوله قال اه هو كل التفاعل انه هذه ال OH- لو
+
+76
+00:07:26,290 --> 00:07:32,710
+انا اعملتلها توزيع إلكتروني عليها هنا تلت أزواج من
+
+77
+00:07:32,710 --> 00:07:35,630
+الإلكترونات عشان هيك صارت minus هدفش عليه
+
+78
+00:07:35,630 --> 00:07:42,560
+إلكترونات هذا موجب و هذهسالبة الموجة بدي تفعل مع
+
+79
+00:07:42,560 --> 00:07:46,920
+السالب هذا بدي يعطي إلكترونات هنا وبناء على ذلك
+
+80
+00:07:46,920 --> 00:07:52,860
+جانب ال acid electron acceptor بده إلكترونات وال
+
+81
+00:07:52,860 --> 00:08:00,240
+base electron donorوصار هذا تعريف عام الآن أن أي
+
+82
+00:08:00,240 --> 00:08:06,440
+إش بيعطي إلكترونات base و أي إش بيكتسب إلكترونات
+
+83
+00:08:06,440 --> 00:08:11,100
+acid إذا صار حسب تعريف Lewis الموضوع مش متطلع إيش
+
+84
+00:08:11,100 --> 00:08:14,580
+تكون هذه و إيش تكون هذه يعني لو كتبت الآن بعيدا عن
+
+85
+00:08:14,580 --> 00:08:20,200
+ال H plus وعن ال OH minus لو كتبت A plus زائد مثلا
+
+86
+00:08:20,200 --> 00:08:21,580
+X minus
+
+87
+00:08:23,870 --> 00:08:26,950
+هذا بيعطي إلكترونات إذا هذا بيحصل هذا بيكتسب
+
+88
+00:08:26,950 --> 00:08:33,530
+إلكترونات إذا هذا أسد واضح و لذلك إذا بتذكروا لما
+
+89
+00:08:33,530 --> 00:08:37,390
+أخدنا على سبيل المثال في chapter ال aromatic
+
+90
+00:08:37,390 --> 00:08:43,950
+compounds مركب زي ال FECL3 قلنا إن ال FECL3 كام
+
+91
+00:08:43,950 --> 00:08:50,420
+إلكترون كان حوله6 electron sextant الوضع الطبيعي
+
+92
+00:08:50,420 --> 00:08:57,760
+كم يكون 8 و بناء على ذلك اعتبرنا Lewis acid فلما
+
+93
+00:08:57,760 --> 00:09:00,820
+نيجي نقول له ال aromatic compounds كيف كانوا
+
+94
+00:09:00,820 --> 00:09:07,760
+يتفاعلوا من خلال انه ييجي على سبيل المثال ال CL2
+
+95
+00:09:07,760 --> 00:09:12,530
+يتفاعل مع هذا الآن ال CL2 كان يعطيسيال مع
+
+96
+00:09:12,530 --> 00:09:16,930
+إلكتروناتها كأنه هذه ال base هو بيكتسب السيال مع
+
+97
+00:09:16,930 --> 00:09:21,290
+إلكتروناتها بيصير تمان إلكترونات حوله بدل ستة فهذا
+
+98
+00:09:21,290 --> 00:09:26,770
+acid وهذا الجزء كأنه تعامل ك base وعشان تقولنا أن
+
+99
+00:09:26,770 --> 00:09:31,270
+ال aromatic reactionsبتم في وجود ال FECL3 أو
+
+100
+00:09:31,270 --> 00:09:35,130
+الألمنيوم الكلوريد الآن الإنسان مابدوش يكتب FECL3
+
+101
+00:09:35,130 --> 00:09:38,870
+أو الألمنيوم الكلوريد بيقول ببساطة the
+
+102
+00:09:38,870 --> 00:09:43,230
+chlorination of aromatic compounds occurs by using
+
+103
+00:09:43,230 --> 00:09:49,770
+Cl2 with a Lewis acidسواء قولنا FECL3 ألمنيوم CL3
+
+104
+00:09:49,770 --> 00:09:54,590
+واطفر هو في النهاية Lewis acid يعني مش الفكرة فيه
+
+105
+00:09:54,590 --> 00:10:00,270
+بمسماك مركب لأ هي الفكرة فيه بمسماء النوعي أن هو
+
+106
+00:10:00,270 --> 00:10:08,350
+Lewis acid فصار كل شيء electron donor هو عبارة عن
+
+107
+00:10:08,350 --> 00:10:14,020
+base وكل شيء electron acceptorهو عبارة عن ايش؟
+
+108
+00:10:14,020 --> 00:10:21,680
+acid الان لاحظوا انا نفس المركبات طبقت عليها
+
+109
+00:10:21,680 --> 00:10:28,460
+التلات تعريفات ولكن هي نظرة اكثر تخصصية يعني هنا
+
+110
+00:10:28,460 --> 00:10:33,860
+كنت اطلع على المركب كلهأطلع على المُركّب كله و
+
+111
+00:10:33,860 --> 00:10:38,600
+أقول والله هذا المُركّب كله هو الحامض، الآن إجا
+
+112
+00:10:38,600 --> 00:10:42,000
+لوري برونز تدعم نفس الطريق، قالوا طب وين مركز
+
+113
+00:10:42,000 --> 00:10:45,980
+القوة في القاعدة؟ الـ OH خلّال الـ OH القاعدة، لكن
+
+114
+00:10:45,980 --> 00:10:50,320
+ماتطلعش على مركز القوة وين؟في الحمض ايه جالي ويس؟
+
+115
+00:10:50,320 --> 00:10:53,200
+جلطب هو مركز القوة زي ما انت شوفت انه هو مركز
+
+116
+00:10:53,200 --> 00:10:57,700
+القوة الـ OH شوف انه هو مركز القوة الـ H plus و
+
+117
+00:10:57,700 --> 00:11:01,380
+اعمل تعريفك عليه و بعدين نظرله من ناحية
+
+118
+00:11:01,380 --> 00:11:05,580
+الإلكترونات نظرله من ناحية الإلكترونات فواضح ان
+
+119
+00:11:05,580 --> 00:11:11,070
+التلات تعريف ليست متناقضةالتلات تعريف ليست متناقضة
+
+120
+00:11:11,070 --> 00:11:18,710
+ولكنها تمثل نظرة اكثر تخصصية نظرة اكثر ايش؟ تخصصية
+
+121
+00:11:18,710 --> 00:11:24,390
+واضح؟ هذا بالنسبة لتعريف الأحمد الآن لما انا بدي
+
+122
+00:11:24,390 --> 00:11:29,970
+اجي على قوة الحامض في المحليل اللي عندنا احنا عادة
+
+123
+00:11:29,970 --> 00:11:35,630
+بنستعملفي ال alcohols تحديدا و ال acids بنفضل
+
+124
+00:11:35,630 --> 00:11:38,590
+نستعمل اللوري برونس لدفنيشي لاحظوا الناس بيستعملوا
+
+125
+00:11:38,590 --> 00:11:44,370
+اي تعريف بما يخدم الغرض تبعهم الان لما بدي اجي
+
+126
+00:11:44,370 --> 00:11:48,570
+اقول ان انا بدي اتعرف على حامض كيف بيتأين و كيف
+
+127
+00:11:48,570 --> 00:11:54,200
+بيعطي ال ايونات خلينا نتخيل ان الحامض اللي عندناH
+
+128
+00:11:54,200 --> 00:12:00,500
+A هذا الـ H A عادة تأيّن كيف بتم في الميّه زائد H
+
+129
+00:12:00,500 --> 00:12:07,380
+2 O كلكم عارفين المعادلة H 3 O plus مثلا زائد A
+
+130
+00:12:07,380 --> 00:12:13,020
+minus لأن هذه المعادلة العامة و كل ما بيزيد
+
+131
+00:12:13,020 --> 00:12:16,660
+التأيّن الحامض أقوى لأن هذه المعادلة لها ثابت
+
+132
+00:12:16,660 --> 00:12:23,410
+اتزان لو احنا بدنا ثابت الاتزان تبعها ال Kهي ساوي
+
+133
+00:12:23,410 --> 00:12:34,730
+الـ H3O Plus في الـ A Minus على الـ HA في تركيز
+
+134
+00:12:34,730 --> 00:12:39,750
+الميّه النواتج
+
+135
+00:12:39,750 --> 00:12:43,070
+على
+
+136
+00:12:43,070 --> 00:12:50,300
+المتفائلات الان اعتادوا الناس ان اي تركيز ثابتما
+
+137
+00:12:50,300 --> 00:12:55,000
+يخلّوهاش شيء فالماء تركيزه ثابت الماء تركيزه ثابت
+
+138
+00:12:55,000 --> 00:13:00,760
+و لو أخدنا احنا جديش عادة في اللتر ميه الف جرام
+
+139
+00:13:00,760 --> 00:13:05,000
+قسمناه على ال molecular weight تبع ال .. تبع الميه
+
+140
+00:13:05,000 --> 00:13:08,240
+تمانتعش الف على تمانتعش بطلع لنا حوالي خمسة و
+
+141
+00:13:08,240 --> 00:13:12,100
+خمسين و كسر هذا موجود في اللتر و بناء على ذلك
+
+142
+00:13:12,100 --> 00:13:16,100
+التركيز الثابت للميه حوالي خمسة و خمسين و كسر الآن
+
+143
+00:13:16,100 --> 00:13:21,700
+طالما هذا التركيز ثابت و هذا ثابتبنضرب الثابتين في
+
+144
+00:13:21,700 --> 00:13:25,800
+بعضهم البعض بنضرب الثابتين في بعضهم البعض فبصير
+
+145
+00:13:25,800 --> 00:13:32,520
+عند K مضروب في تركيز ال H2O هدولة بعمللهم تعريف
+
+146
+00:13:32,520 --> 00:13:38,300
+جديد بقول هدولة سميهم K A فال K A مش هو ثابت
+
+147
+00:13:38,300 --> 00:13:43,620
+الإتزان واضح؟ ال K A شيء و ثابت الإتزان شيء هذا ال
+
+148
+00:13:43,620 --> 00:13:48,740
+K equilibrium constant هذا ال K A acidity constant
+
+149
+00:13:50,110 --> 00:13:53,330
+لحظوا ميزوا بينهم equilibrium constant is
+
+150
+00:13:53,330 --> 00:13:56,650
+something and acidity constant is another thing ال
+
+151
+00:13:56,650 --> 00:14:01,630
+K a هذه هي عبارة عن ثابت الاتزان مضروب في تركيز ال
+
+152
+00:14:01,630 --> 00:14:06,910
+H2O اللي ثابت الان لو اتيت على ال K a هيصير ربما
+
+153
+00:14:06,910 --> 00:14:12,250
+التعبير اللي حضرتكم بتعرفوه H3O plus في A minus
+
+154
+00:14:12,250 --> 00:14:22,130
+علىهذا تعبير إيش ال K A اللي بنسميه احنا acidity
+
+155
+00:14:22,130 --> 00:14:30,050
+constant يعني ثابت الحامض الآن ال acidity constant
+
+156
+00:14:31,960 --> 00:14:37,420
+و كل مكان أعلى كل مكان الحامض بتأيين أكثر والحامض
+
+157
+00:14:37,420 --> 00:14:41,740
+اللي بتأيين أكثر بالتعريف والحامض الاش الأقوى بناء
+
+158
+00:14:41,740 --> 00:14:46,780
+على ذلك لو أنا بدي أعمل مقارنة لحامضين مين اللي
+
+159
+00:14:46,780 --> 00:14:54,730
+بدي يكون أقوى اللي له K A أعلىإذا القاعدة بتقول as
+
+160
+00:14:54,730 --> 00:15:01,970
+KA increases as KA increases the acidity increases
+
+161
+00:15:01,970 --> 00:15:08,840
+كل ما زادت ال KA كل ما كان الحامض اشماله أقوىكل ما
+
+162
+00:15:08,840 --> 00:15:13,280
+الـ Ka بتكون أعلى في القيمة كل ما الحامض بيكون
+
+163
+00:15:13,280 --> 00:15:17,480
+أقوى فأنا لو أعطيتكم مثلا حامضين هي Ka لهذا وKa
+
+164
+00:15:17,480 --> 00:15:21,440
+لهذا بتقدروا على طول تقولولي مين الحامض الأقوى
+
+165
+00:15:21,440 --> 00:15:27,400
+فيهم اللي إله ال Ka أعلى خلينا نجرب نعمل هذا
+
+166
+00:15:27,400 --> 00:15:31,900
+الكلام خلينا نجرب نعمل هذا الكلام لو إجينا
+
+167
+00:15:31,900 --> 00:15:40,990
+أعطيناكم حامض HAو حامض HB وهي حامضين و خلّيني أقول
+
+168
+00:15:40,990 --> 00:15:48,170
+ال K A لهدول الحامضين يعني K A H A نفترض هنا 1.8
+
+169
+00:15:48,170 --> 00:15:55,910
+في 10 أقص ناقص خمسة و نفترض هنا 1.3 في 10 أقص ناقص
+
+170
+00:15:55,910 --> 00:16:04,140
+تلاتةمن الأقوى ال HB، ليش؟ لأن هذا المقدار أكبر من
+
+171
+00:16:04,140 --> 00:16:09,060
+هذا المقدار، إذا احنا هنا اتفقنا أن هذا الأقوى،
+
+172
+00:16:09,060 --> 00:16:13,360
+الآن لما اتفقنا أن هذا الأقوى، لو سألنا طالب، ليش
+
+173
+00:16:13,360 --> 00:16:20,180
+هذا أقوى؟هنتعبها مجرد .. مجرد الأمر تجميلي و ليس
+
+174
+00:16:20,180 --> 00:16:24,900
+أكثر هنتعبها في الحكي هتيجي تحكي و تفكر و تطلع
+
+175
+00:16:24,900 --> 00:16:28,460
+تاخدلها ثانيتين تفكير احنا بنختصر عليها ثانية بس
+
+176
+00:16:28,460 --> 00:16:32,900
+هتقول ال one point three في عشر أقص ناقص تلاتة
+
+177
+00:16:32,900 --> 00:16:36,900
+أكبر من ال one point eight في عشر أقص ناقص خمسة
+
+178
+00:16:36,900 --> 00:16:41,680
+وبناء على ذلك هذا كحمض أقوىأقولكوا أعطيتوا الجواب
+
+179
+00:16:41,680 --> 00:16:46,340
+الصحيح كلامكوا سليم 100% لكن أخذ منكم ثانية أو
+
+180
+00:16:46,340 --> 00:16:50,380
+ثانيتين تفكير الآن العلماء قالوا بنقدر نوفر على
+
+181
+00:16:50,380 --> 00:16:55,400
+طلابنا ثانية تفكير يعني لو الأمر بياخد منهم
+
+182
+00:16:55,400 --> 00:17:00,240
+ثانيتين تفكير عشان يقارنوا يتطلعوا على رقم كبير
+
+183
+00:17:00,240 --> 00:17:03,120
+مجرد معانكوا تكملوا جراية هذا و جراية هذا بتاخد
+
+184
+00:17:03,120 --> 00:17:07,200
+ثانيتين فالعلماء قالوا يا تورا بنقدر نختصر على
+
+185
+00:17:07,200 --> 00:17:13,080
+الطلاب ثانية من التفكيرقال و ممكن كيف؟ قال بدل ما
+
+186
+00:17:13,080 --> 00:17:17,640
+نتعامل مع الأرقام اللي مش حلوة خلينا نتعامل مع
+
+187
+00:17:17,640 --> 00:17:24,960
+أشياء أحلى نعرف مقدار جديد نقوله PKA و نقول ال PKA
+
+188
+00:17:24,960 --> 00:17:31,240
+بتساوي minus logarithm ال KA minus logarithm ال KA
+
+189
+00:17:32,640 --> 00:17:36,920
+الان لو انا جيبت ال calculator بدل ما تغلبوني قولت
+
+190
+00:17:36,920 --> 00:17:39,820
+one point eight في عشر أقص خمسة بال minus وال
+
+191
+00:17:39,820 --> 00:17:43,780
+logarithm تبعها لاحظ ناقص اربعة و سبعة اذا ال BKA
+
+192
+00:17:43,780 --> 00:17:51,660
+هنقاش اربعة و سبعة طيب لو اجيت اعملت للتاني قولت
+
+193
+00:17:51,660 --> 00:17:55,100
+one point three في عشر أقص تلاتة بال minus وال
+
+194
+00:17:55,100 --> 00:17:57,660
+logarithm تبعها اتنين وتسعة
+
+195
+00:18:02,040 --> 00:18:06,980
+أتنين وتسعة الان لاحظوا انا عارف الأقوى اللي اتيان
+
+196
+00:18:06,980 --> 00:18:11,940
+اكثر هذا طيب من ناحية ال BKA الحامض الأقوى شو
+
+197
+00:18:11,940 --> 00:18:18,820
+بتلاحظوا عليه اللي له BKA أقلواضح؟ اللي إله PKA
+
+198
+00:18:18,820 --> 00:18:23,700
+أقل إذا بدي أنا دائما .. الآن أنا هو أسهل للإنسان
+
+199
+00:18:23,700 --> 00:18:28,560
+لما يصير حافظ لغرض مقارنة الأحماط الأقل أقوى و
+
+200
+00:18:28,560 --> 00:18:33,060
+دائما أعطي قيم PKA جداش بياخد منكم .. لما أفرجيكم
+
+201
+00:18:33,060 --> 00:18:37,810
+رقمين زي هيك أقولكم مين الأقوىثانية لما أفرجيكوا
+
+202
+00:18:37,810 --> 00:18:42,110
+يفهموا زيكي بياخد ثانيتين إذا هذا ال BKA كل فكرتها
+
+203
+00:18:42,110 --> 00:18:48,530
+هي فكرة تجميلية لتسهيل النظر والتفكير بالنتيجة
+
+204
+00:18:48,530 --> 00:18:53,660
+والمقارنة لا تحمل معنى علمي جديدومدلها تماما
+
+205
+00:18:53,660 --> 00:18:58,860
+بالمناسبة الـ pH اللى بتتعرف minus logarithm تركيز
+
+206
+00:18:58,860 --> 00:19:01,700
+ال H plus طب هو لو الناس أخدوا تركيز ال H plus
+
+207
+00:19:01,700 --> 00:19:06,280
+وقارنوا بيقدروا يعني لو أنه في العلم ماعملوش
+
+208
+00:19:06,280 --> 00:19:12,100
+نهائيا تعريف ال pH و تعريف ال PKA كانوا بيقدروا
+
+209
+00:19:12,100 --> 00:19:16,180
+برضه يشرحوا كل العلم بدون مشاكل لإيش؟ بيقارنوا
+
+210
+00:19:16,180 --> 00:19:19,100
+اعتمادا على ال PA بس لما بيقارنوا بذكروا أرقام
+
+211
+00:19:19,100 --> 00:19:25,820
+شوية غلسةواضح؟ فكل فكرة ال BKA فلسفيا خلّيني أقول
+
+212
+00:19:25,820 --> 00:19:33,140
+على أقل تقدير هي تسهيل النظر للأرقام الآن لما باجي
+
+213
+00:19:33,140 --> 00:19:38,760
+انا بعطيكم جدول في قوة لكذا حامض اقولكوا من الأقوى
+
+214
+00:19:38,760 --> 00:19:43,460
+انتوا خلال الدقيقة راح تتطلعوا أقل واحد أقل BKA
+
+215
+00:19:46,600 --> 00:19:53,160
+أو لو أعطيتكواها بال .. بال Ka أعلى Ka هي الأقوى
+
+216
+00:19:53,160 --> 00:19:56,540
+لكن هنا عشان تشوفوا الأعلى عملية بتكون تطلع على
+
+217
+00:19:56,540 --> 00:20:03,500
+الكسر و على الأسل هنا بتبين ايش أسهل كتير هذه
+
+218
+00:20:03,500 --> 00:20:09,580
+العملية واضح فقط لغاية طبعا هنا هتيجيكوا مقارنة
+
+219
+00:20:09,580 --> 00:20:13,720
+دائما ضالكوا متذاكروها متذاكرينها ان ال strength
+
+220
+00:20:13,720 --> 00:20:21,750
+of acidلو سؤلنا عنه من ناحية ال K A و من ناحية ال
+
+221
+00:20:21,750 --> 00:20:29,350
+BKA من ناحية ال BK .. ال K A ال higher كل ما كانت
+
+222
+00:20:29,350 --> 00:20:34,230
+K A أعلى كل ما الحامض أقوى من ناحية ال BKA ال
+
+223
+00:20:34,230 --> 00:20:40,410
+lower كل ما كانت ال BKA أقل كل ما كان الحامض أقوى
+
+224
+00:20:40,410 --> 00:20:48,680
+واضح هذه المفاهيم؟الان هذه تقريبا مقدمة خلنا نقول
+
+225
+00:20:48,680 --> 00:20:55,520
+تذكير بشكل عام في مفاهيم الأحماض الان لما نيجي
+
+226
+00:20:55,520 --> 00:21:01,100
+نتكلم عن ال alcohols هل يا ترى الكحول ممكن يكون
+
+227
+00:21:01,100 --> 00:21:09,370
+حامض ولا لأ؟زي و زي الميه انا لما بدي اجي اقول رو
+
+228
+00:21:09,370 --> 00:21:14,410
+اتش عنده امكانية يفقد هذه الاتش المتصلة بالاكسجين
+
+229
+00:21:14,410 --> 00:21:19,850
+يعني نقول زائد اتش to او باتزان رو ماينوس
+
+230
+00:21:22,320 --> 00:21:29,240
+زائد H3O plus إذا هو يمكن أن يفقد هذه ال H وبناء
+
+231
+00:21:29,240 --> 00:21:34,940
+على ذلك ممكن أنه يكون حامض هي الميه نفسها ممكن
+
+232
+00:21:34,940 --> 00:21:40,140
+تكون حامض طبعا الميه لما كنا نقول عنها كحامض هي
+
+233
+00:21:40,140 --> 00:21:46,470
+مجرد HOHيعني لو أخدت نفس هذه المعادلة المية كحمض H
+
+234
+00:21:46,470 --> 00:21:50,410
+O H لاحظوا لما المرة الماضية قلتلكوا أن المية
+
+235
+00:21:50,410 --> 00:21:56,890
+فلسفيا ممكن اعتبرها كأن أبسط كحول هنا قلت H O R
+
+236
+00:21:56,890 --> 00:22:03,490
+وهنا H O H يعني كأن ال R هذه H عشان هي أبسط إيش
+
+237
+00:22:04,620 --> 00:22:10,680
+أبسط الكحولات فلسفيا زائد H2O هيعطينا HO minus
+
+238
+00:22:10,680 --> 00:22:20,720
+زائد H3O plus وهذا تفاعل اتزار معروف بالنسبة لنا
+
+239
+00:22:20,720 --> 00:22:25,260
+في كتب الكيميا اذا H2O كأن واحد منها اتعمل كحمض
+
+240
+00:22:25,260 --> 00:22:31,740
+فقد H plus التاني اتعمل ك base اكتسب H plus واضح
+
+241
+00:22:31,740 --> 00:22:36,400
+الفكرة؟و عشان هيك بنقول الميه حامض و الكحول حامض،
+
+242
+00:22:36,400 --> 00:22:41,660
+الآن طيب لو بدي أجي أقول مين أقوى كحامضية؟ هاد
+
+243
+00:22:41,660 --> 00:22:45,180
+السؤال كتير مهم، الكحول ولا الميه؟ لأنه بعد شوية
+
+244
+00:22:45,180 --> 00:22:52,040
+لما بنيجي نقول أن الكحول مطهربدنا نغسل إيدينا فيه
+
+245
+00:22:52,040 --> 00:22:56,520
+هل يا تورا إذا غسلنا إيدينا في الكحول بدهم ينشعتوا
+
+246
+00:22:56,520 --> 00:23:01,720
+وينحرجوا بالإيثانول ولا لأ الآن هذا الجواب بنشوفه
+
+247
+00:23:01,720 --> 00:23:07,520
+من وين احنا من قيم ال BKA اتطلعوا انتوا على الماء
+
+248
+00:23:07,520 --> 00:23:12,900
+كحمض ال BKA له خمس طعش وسبعة اتطلعوا على الميثانول
+
+249
+00:23:12,900 --> 00:23:17,700
+خمس طعش وخمسة اتطلعوا على الإيثانول خمس طعش وتسعة
+
+250
+00:23:18,410 --> 00:23:25,030
+الان كل هذه القيم من ناحية المبدأ تكاد تكون
+
+251
+00:23:25,030 --> 00:23:31,650
+متساوية اذا حمضية الكحول مثل حمضية الميه والميه
+
+252
+00:23:31,650 --> 00:23:35,810
+متعودين نقول عنها weak acid عشان هيك لما بتعملوا
+
+253
+00:23:35,810 --> 00:23:39,130
+في المستقبل مزرعة بكتيريا وصار على إيديكوا جراثيم
+
+254
+00:23:39,130 --> 00:23:44,910
+و بعدها بدكوا تغسلوا تطهروا إيديكم بالكحولاللي
+
+255
+00:23:44,910 --> 00:23:48,250
+موجود واتوكلوا على الله مش هيعمل فيكوا إشي ولا
+
+256
+00:23:48,250 --> 00:23:53,230
+تفكروا إنه هيحرجلكوا إيديكوا من ناحية ال acidity
+
+257
+00:23:53,230 --> 00:23:59,430
+ال ethanol زي و زي الميه الآن اتخيلوا لو كنتوا
+
+258
+00:23:59,430 --> 00:24:04,030
+بتتعاملوا مع phenol اللي هو ال aromatic alcohol
+
+259
+00:24:04,030 --> 00:24:12,340
+نزل لعشرات إذا صارحامض اكتر عشان هيك الفينول اذا
+
+260
+00:24:12,340 --> 00:24:20,000
+كب ع اديكو هيعلم هيعمل لون هيحرق الايد واضح طبعا
+
+261
+00:24:20,000 --> 00:24:24,420
+لو بدي اجي على مركب زي ال Nitro Phenol سبعة و
+
+262
+00:24:24,420 --> 00:24:29,900
+اتنين اقوى و اقوى طب لو اجيتلى مركب زي ال Tri
+
+263
+00:24:29,900 --> 00:24:36,320
+Nitro Phenol point two fiveقوي جدا لدرجة انه
+
+264
+00:24:36,320 --> 00:24:40,240
+بيغيروا اسمه بدل ما يسموه phenol اعطوه اسم acid
+
+265
+00:24:40,240 --> 00:24:45,260
+بيكريك أسد حامض أصفر غامق بيكريك أسد مرات
+
+266
+00:24:45,260 --> 00:24:49,040
+بتستعملوه في بعض التحاليل لاحظوا شو اللي خلاهم رغم
+
+267
+00:24:49,040 --> 00:24:52,900
+انه في مجموعة ال O H يعني من ناحية اللي متعودين
+
+268
+00:24:52,900 --> 00:24:57,820
+على ال acids بال organ ال chemistry C double bond
+
+269
+00:24:57,820 --> 00:25:04,020
+OOHمش بس هم ال acids هم لما بيفقدوا ال H plus
+
+270
+00:25:04,020 --> 00:25:07,320
+بيكونوا acids بالعكس ال acetic acid .. ال acetic
+
+271
+00:25:07,320 --> 00:25:13,880
+acid لو بتكن تتطلع عليه CH3COOOH
+
+272
+00:25:13,880 --> 00:25:20,530
+هذا ال BKA له أربعة وسبعة بالعشرةيعني اللي احنا
+
+273
+00:25:20,530 --> 00:25:24,750
+ماعطينه اسم acid أربعة أو سبعة من عشرة الآن لما
+
+274
+00:25:24,750 --> 00:25:27,850
+تقوله هذا أربعة أو سبعة من عشرة مقارنة ب point two
+
+275
+00:25:27,850 --> 00:25:32,510
+five لل بيكريك أسد مين أقوى ميت مرة و بيحرق الجلد
+
+276
+00:25:32,510 --> 00:25:37,990
+ميت مرة ال بيكريك أسد رغم أنه هذا alcohol in
+
+277
+00:25:37,990 --> 00:25:41,870
+principle أو فينول واضح؟ رغم أن هذا alcohol أو
+
+278
+00:25:41,870 --> 00:25:47,210
+فينول فالفكرة بقيم ال BKA مش في النهاية حتى بال
+
+279
+00:25:47,210 --> 00:25:52,610
+structure الكيميائيطبعا بيصير السؤال يا تورا لحظه
+
+280
+00:25:52,610 --> 00:25:55,550
+انا مثلا لو جينا اتطلعنا على مركب two two two
+
+281
+00:25:55,550 --> 00:26:00,790
+trifluoroethanol جداش ال acidity تبعته؟ ماعشه
+
+282
+00:26:00,790 --> 00:26:05,630
+اربعة اذا لو انا بالاثانول بدال ال تلت هيدروجينات
+
+283
+00:26:05,630 --> 00:26:12,440
+لflour الحمضية بتزيد ولا بتجيل؟ بتزيدبصير السؤال
+
+284
+00:26:12,440 --> 00:26:17,060
+عاد .. بصير السؤال اللي بدنا نفهمه ليش يا تورا ..
+
+285
+00:26:17,060 --> 00:26:23,600
+ليش يا تورا الفينول كحمض أقوى من الإيثانول؟ ليش يا
+
+286
+00:26:23,600 --> 00:26:28,980
+تورا ال acetic acid أقوى من الإيثانول بكتير؟ يعني
+
+287
+00:26:28,980 --> 00:26:33,260
+ال acetic acid لو حطيناه على إيدنا، بده يحرج إيدنا
+
+288
+00:26:34,380 --> 00:26:38,400
+واضح؟ احنا مراتب بنستعمل الخل و بنشرب، لكن هذا خل
+
+289
+00:26:38,400 --> 00:26:43,260
+مخفف بنسبة أقل من خمسة في المية، خفيف كتير، لكن لو
+
+290
+00:26:43,260 --> 00:26:49,130
+حد بده يحط الخل النقيالصافي مش المدوّب في الميّه
+
+291
+00:26:49,130 --> 00:26:53,430
+اللي بنباع في السوق ال vinegar هذا خل أقل من 5%
+
+292
+00:26:53,430 --> 00:26:57,490
+ممكن تفوته على السلطة ممكن تشرب معلجة منه أو تخففه
+
+293
+00:26:57,490 --> 00:27:01,150
+بميه و تشرب معلجة منه لكن الخل نفسه لو بده أخده
+
+294
+00:27:01,150 --> 00:27:05,530
+كحامق بدون ما يكون مخفف بالميه هيحرج الإيدانواضح؟
+
+295
+00:27:05,530 --> 00:27:09,070
+ليش الخل اقوى من الاثانول؟ ليش ال try
+
+296
+00:27:09,070 --> 00:27:13,150
+fluoroethanol اقوى من الاثانول؟ ليش الفينول اقوى
+
+297
+00:27:13,150 --> 00:27:17,690
+من الاثانول؟ ليش ال nitrophenol اقوى من الفينول؟
+
+298
+00:27:17,690 --> 00:27:22,290
+ليش ال try nitrophenol اقوى من ال nitrophenol؟
+
+299
+00:27:22,290 --> 00:27:29,730
+الان كل هذه دراساتمقارنة يعني لما بدأ اقارن حامضين
+
+300
+00:27:29,730 --> 00:27:34,610
+لما بدأ اقارن حامضين و اجي اقول ان في عندى حامض
+
+301
+00:27:34,610 --> 00:27:42,270
+اقوى من حامض السؤال ليش تمام خلينا نفهم الأمور
+
+302
+00:27:42,270 --> 00:27:50,470
+شوية بهدوء و بشكل خلينا اقول منطقي اللي يخدمني لكل
+
+303
+00:27:50,470 --> 00:27:55,430
+الحالات اللي موجودة كل حالة بالمناسبة لها سببيعني
+
+304
+00:27:55,430 --> 00:28:00,950
+هنا مش سبب واحد اللي موجود لأ هي أكتر من سبب فرعي
+
+305
+00:28:00,950 --> 00:28:05,390
+لكن اللي بديه يفهم الموضوع ناخد الموضوع بشكل عام
+
+306
+00:28:05,390 --> 00:28:09,790
+لو بدنا نحكي على مقارنة حامضين خليني أجي أتخيل أني
+
+307
+00:28:09,790 --> 00:28:18,080
+بدي أقارن ال HCL و ال HBRكأحمار تمام و اقول انا
+
+308
+00:28:18,080 --> 00:28:23,700
+انه hcl و استعمل aq عارفين aq؟ aqs يعني بمية هذا
+
+309
+00:28:23,700 --> 00:28:28,540
+الكلام بيصير عشان ما نتغلبش h plus aqs يعني كأنها
+
+310
+00:28:28,540 --> 00:28:36,160
+h3o زائد cl minus و لو انا اجيت قولت hbr aqs برضه
+
+311
+00:28:36,160 --> 00:28:45,330
+h plus aqs زائد br minus كل هذا الكلام ايش؟في
+
+312
+00:28:45,330 --> 00:28:51,270
+محلول معين كل هذا الكلام محلول معين الان ال HBR
+
+313
+00:28:51,270 --> 00:28:56,030
+بالتجربة اقوى من ال HCL ال HBR بالتجربة اقوى من ال
+
+314
+00:28:56,030 --> 00:29:00,750
+HCL لو انا بدي اجي اقول يا تورا ايش السبب لاحظوا
+
+315
+00:29:00,750 --> 00:29:06,270
+لو فكرنا بمنطقة ال H plus لو فكرنا بمنطقة ال H
+
+316
+00:29:06,270 --> 00:29:11,610
+plus هذا بيعطي H plus وهذا بيعطي H plus اذا الحكم
+
+317
+00:29:11,610 --> 00:29:17,570
+مش ال H plusالحكم مش الـ H plus المشترك عمره ما
+
+318
+00:29:17,570 --> 00:29:22,470
+بيفرق شغلتين اللي بيفرق هو إيش؟ المختلف بناء على
+
+319
+00:29:22,470 --> 00:29:30,020
+ذلك ال PR minus وال CL minus هم السبب هم السببفي
+
+320
+00:29:30,020 --> 00:29:34,300
+انه حامض اقوى من حامض هم السبب في انه حامض اقوى من
+
+321
+00:29:34,300 --> 00:29:39,240
+حامض الان احنا بنقول الايون السالب النظر اليه هو
+
+322
+00:29:39,240 --> 00:29:42,220
+محور التفكير يوم افدياليس اللي اش حامض اقوى من
+
+323
+00:29:42,220 --> 00:29:46,100
+حامض على ايش بدأ اطلع على الايون السالب لان كله
+
+324
+00:29:46,100 --> 00:29:52,360
+هياطلق اتش بلس بنقول كل ما كان الايون السالب اثبت
+
+325
+00:29:52,360 --> 00:29:58,140
+كل ما كان الحامض اقوى واضح؟يعني كل ما هذا الايون
+
+326
+00:29:58,140 --> 00:30:02,940
+السالب أثبت الحامض أقوى و ربما هذا الكلام يكون
+
+327
+00:30:02,940 --> 00:30:08,260
+بحاجة شوية إلى تفسير شو يعني ان الايون السالب أثبت
+
+328
+00:30:08,260 --> 00:30:18,910
+المقصود بالثبات أن يحمل شحنة أقلالثبات كلما زادت
+
+329
+00:30:18,910 --> 00:30:25,410
+الشحنة قل الثبات و كلما قلت الشحنة زاد الثبات إذا
+
+330
+00:30:25,410 --> 00:30:30,190
+الثبات مرتبط بإيش؟ بالشحنة لما بتزيد بيبطل فيه
+
+331
+00:30:30,190 --> 00:30:34,250
+ثبات لما بتقل بيصير فيه ثبات فاللي بده يثبت أي شغل
+
+332
+00:30:34,250 --> 00:30:38,650
+بده يقل شحنتها لاحظوا هذا الكلام مش خاص في الأحماط
+
+333
+00:30:38,650 --> 00:30:43,630
+بس حتى في البشر يعني على سبيل المثال الغضب ..
+
+334
+00:30:43,630 --> 00:30:51,830
+الغضب إيش تعريفه؟الغضب شُحنة وهذه الشُحنة تظهر حتى
+
+335
+00:30:51,830 --> 00:30:56,430
+على الطاقة ال energy تظهر حتى على وش الإنسان وعلى
+
+336
+00:30:56,430 --> 00:31:00,650
+خدوده تشوف كيف عينيه يطلعوا لبرا الإنسان الغضبان
+
+337
+00:31:00,650 --> 00:31:04,370
+وخدوده حمر الرسول عليه الصلاة والسلام ايش بيقول
+
+338
+00:31:04,370 --> 00:31:11,460
+أما رأيتم إلى انتفاخ أوداجه وحمرار عينيهليش؟ لأنه
+
+339
+00:31:11,460 --> 00:31:16,120
+بيحمل شحنة غضب كتيرة هذا الغضبان كتير بيكون stable
+
+340
+00:31:16,120 --> 00:31:20,740
+ولا unstable؟ بيكون unstable اليوم لاحظوا لما أنا
+
+341
+00:31:20,740 --> 00:31:25,020
+بدي أضيع الغضب منه عند اللزوم بغسله بالمية مش ممكن
+
+342
+00:31:25,020 --> 00:31:29,700
+جد ما يكون الإنسان غضبان مولّع نار لو حاطيته تحت
+
+343
+00:31:29,700 --> 00:31:36,160
+دوش مية هي energy طاقة المية الباردة هذه هتسحب ال
+
+344
+00:31:36,160 --> 00:31:43,300
+energy منه هيقلل الغضبكل ما قلت الشحنة كل ما اش
+
+345
+00:31:43,300 --> 00:31:47,860
+عندى صار زادى الثبات اذا انا لما بدى اقارن شغلة
+
+346
+00:31:47,860 --> 00:31:52,380
+اثبت من شغلة بدى اطلع على الشحنة السالبة و اشوف
+
+347
+00:31:52,380 --> 00:31:58,800
+ايش اللى بيخليها اقل بدى يصير الان سؤالنا ايش طرق
+
+348
+00:31:58,800 --> 00:32:05,620
+تقليل الشحنة السالبة كيف ممكن الشحنة السالبة تكون
+
+349
+00:32:05,620 --> 00:32:15,250
+ايش اقلواضح؟ كيف ممكن أقلل أنا الشحنة؟ بشكل عام،
+
+350
+00:32:15,250 --> 00:32:23,890
+الشحنة حمل إمصيبة، عدم ثبات، كيف بدي أقللها؟ أنا
+
+351
+00:32:23,890 --> 00:32:29,060
+بحبش الكيمياأنا الكيميا دي مابحبهاش بالمرة أنا بحب
+
+352
+00:32:29,060 --> 00:32:34,820
+نفهم الموضوع من الحياة نفهم الموضوع كيف من الحياة
+
+353
+00:32:34,820 --> 00:32:39,080
+انتبهوا معايا لو اتخيلتوا الآن لو اتخيلتوا الآن
+
+354
+00:32:39,080 --> 00:32:45,440
+انسان راح على السوقو حمل اشترى خمسة كيلو من شغلة
+
+355
+00:32:45,440 --> 00:32:51,460
+معينة هدول يمثلوا شحنة ولا حمل ولا لأ؟ و حملهم هذا
+
+356
+00:32:51,460 --> 00:32:56,400
+الإنسان حمل خمسة كيلو بمثله ثقل عليه وعدم ثبات ولا
+
+357
+00:32:56,400 --> 00:33:02,940
+لأ؟ الآن بدنا نساعد هذا البني آدم نقلل الحمل اللي
+
+358
+00:33:02,940 --> 00:33:08,670
+عليهفي عندى اكثر من طريقة الطريقة الاولى تخيلوا لو
+
+359
+00:33:08,670 --> 00:33:14,310
+الخمسة كيلو دولة حملهم طفل صغير عمره اربع سنين ولا
+
+360
+00:33:14,310 --> 00:33:19,410
+حملهم شاب عمره عشرين سنة مين بيكون اثبت ومتريح
+
+361
+00:33:19,410 --> 00:33:26,050
+اكتر اذا كل ما بيزيد الحجملما أحط عليه حمل معين،
+
+362
+00:33:26,050 --> 00:33:30,330
+نفس الحمل، الخمسة كيلو على ابن أربع سنين لصغير ولا
+
+363
+00:33:30,330 --> 00:33:34,770
+على ابن عشرين سنة، مين اللي بيحمل أكثر؟ إذا صار
+
+364
+00:33:34,770 --> 00:33:39,630
+عند أول تأثير ممكن نفكر فيه تأثير إيش؟ الحجم، إنه
+
+365
+00:33:39,630 --> 00:33:45,070
+كل ما الحجم كبر، الإش بنحمل أسهل وعشان هيك الشاب
+
+366
+00:33:45,070 --> 00:33:50,860
+الكبير بيحمل الخمسة كيلو أسهل من إشمن الولد الصغير
+
+367
+00:33:50,860 --> 00:33:56,060
+طب لو إجينا لشاب كبير و قولنا له هدولة الخمسة كيلو
+
+368
+00:33:56,060 --> 00:34:02,340
+كيف ممكن كمان أقلل الحمل عنده بييجي شخص تاني
+
+369
+00:34:02,340 --> 00:34:05,960
+بيقوله أساعد معاك الان لما الشخص التاني بيقوله
+
+370
+00:34:05,960 --> 00:34:10,900
+أساعد معاك نفترض أن هدولة الخمسة كيلو هاي هذا ماسك
+
+371
+00:34:10,900 --> 00:34:15,880
+من هنا والتاني ماسك معاه صار الحمل محمول من إيش؟
+
+372
+00:34:15,880 --> 00:34:24,270
+من طرفيناتوزع الحمل واضح؟ صار في شخص مساعد هذا
+
+373
+00:34:24,270 --> 00:34:28,570
+الكلام نفسه ممكن يتكرر في الكيميا بنسميه إيش احنا؟
+
+374
+00:34:28,570 --> 00:34:32,890
+inductive effect يعني تأثير المساعدة من شيء قريب
+
+375
+00:34:32,890 --> 00:34:37,770
+إنه حد يساعد معاك طيب نفترض في طريقه مافيش ولا حد
+
+376
+00:34:37,770 --> 00:34:44,930
+يساعد هذا الإنسان هو حامل الخمسة كيلو إيش هيعمل؟
+
+377
+00:34:45,770 --> 00:34:48,850
+هذه الإيد بتتعب بتلاحظوا لو صورته
+
+378
+00:34:52,190 --> 00:34:57,270
+بصير يعمل تبديل هذا التبديل إيش بنسميه resonance
+
+379
+00:34:57,270 --> 00:35:02,710
+إذا هو خفف عن نفسه الحمل بإيش بال resonance لحظو
+
+380
+00:35:02,710 --> 00:35:08,250
+كام طريقة الأن صرت أنا حاكي لتخفيف الحمل تلت طرق
+
+381
+00:35:08,250 --> 00:35:14,350
+الطريقة الأولى زيادة الحجم الطريقة التانية طريقة
+
+382
+00:35:14,350 --> 00:35:17,930
+ال inductive effect ليه المساعدة و الطريقة التالتة
+
+383
+00:35:17,930 --> 00:35:21,930
+طريقة ال resonanceهذه الطرق اللي من خلالها انا
+
+384
+00:35:21,930 --> 00:35:26,970
+ممكن اقلل الشحنة الان لو بدأنا نتطلع على زيادة
+
+385
+00:35:26,970 --> 00:35:33,010
+الحجم حسب الجدول الدوري مين اكبر لبروم ولا لكلور؟
+
+386
+00:35:33,010 --> 00:35:39,250
+لبروم اتطلع معنا لبروم تحت في الجدول الدوري يعني
+
+387
+00:35:39,250 --> 00:35:44,390
+كأنه هاي لبروم و كأنه هاي لكلور الان عليهم نفس
+
+388
+00:35:44,390 --> 00:35:50,320
+الحمل شحنة سالبة و شحنة سالبةمين اقدر على حمل
+
+389
+00:35:50,320 --> 00:35:54,640
+الشحنة السالبة؟ الحجم الكبير طبعا لو بدأ اقارن
+
+390
+00:35:54,640 --> 00:36:00,460
+اليود اكبر منهم كلهم الان عليهم نفس الشحنة السالبة
+
+391
+00:36:00,460 --> 00:36:05,400
+من الاقدر على حمل الشحنة؟ اليود وبناء على ذلك لما
+
+392
+00:36:05,400 --> 00:36:13,100
+انا بدأ اجي افسر ليش ال hi اقوى من ال hbr اقوى من
+
+393
+00:36:13,100 --> 00:36:20,720
+ال hcl بدأ اقول السبب هو ايش ال sizeالـ Sizeبكلمة
+
+394
+00:36:20,720 --> 00:36:24,460
+واحدة ال size انه الحجم الكبير بيقدر يحمل نفس
+
+395
+00:36:24,460 --> 00:36:30,300
+الشحنة السالبة واضح السبب هو ايش ال size الان هاي
+
+396
+00:36:30,300 --> 00:36:34,500
+فهمنا التأثير الاول طب نجيبله مثال من الأشياء اللي
+
+397
+00:36:34,500 --> 00:36:39,520
+بدنا ندرسها متذكرين ان احنا شبترنا ال alcohols و
+
+398
+00:36:39,520 --> 00:36:43,220
+الthiols و متذكرين اللي هو ال oxygen و ال sulfur
+
+399
+00:36:43,220 --> 00:36:51,610
+تحت بعض طب لو بدي اجي اقول roh ولا rshالاتنين
+
+400
+00:36:51,610 --> 00:36:57,370
+هيفقدوا ايش ال H أنا قولت بدها تطلع على السالب
+
+401
+00:36:57,370 --> 00:37:02,170
+اللي بده يقارن حمضية بده يطلع على السالب هذا فقد و
+
+402
+00:37:02,170 --> 00:37:07,150
+هيحمل سالب وهذا فقد و يحمل سالب هو مين أكبر ال O
+
+403
+00:37:07,150 --> 00:37:13,750
+ولا ال S؟ ال S وبناء على ذلك بيصير ال RSH أقوى من
+
+404
+00:37:13,750 --> 00:37:19,980
+ال R O attributeSize و كذلك الحالة لو كنت أقولكم
+
+405
+00:37:19,980 --> 00:37:28,600
+ARSH و AROH من الأقوى؟ ال ARSH يعني طالما أنا موحد
+
+406
+00:37:28,600 --> 00:37:31,840
+كل إشي بس مفرج ال sulfur و ال oxygen طب ما هي ال
+
+407
+00:37:31,840 --> 00:37:40,410
+sulfur؟أكبر من ال Oxygen فهي أكبر على حمل الشحنة
+
+408
+00:37:40,410 --> 00:37:46,110
+السلبية إذا هذا ال size فصّال لي ليش ال RSH أقوى
+
+409
+00:37:46,110 --> 00:37:56,410
+من ال ROH و ليش ال ARSH أقوى من ال AROH ال size
+
+410
+00:37:56,410 --> 00:38:01,560
+اللي فصّال ليها الحجمالحجم الكبير أقدر على حمل
+
+411
+00:38:01,560 --> 00:38:09,620
+الشحنة الحجم الكبير أقدر على حمل الشحنة الآن خليني
+
+412
+00:38:09,620 --> 00:38:14,500
+أجي لل resonance و بدي أقارن أنا الاثانول مع حمض
+
+413
+00:38:14,500 --> 00:38:24,010
+الخلق لاحظوا الاثانول إيش صيبته؟CH3 CH2 OH وحمض
+
+414
+00:38:24,010 --> 00:38:33,550
+الخلب CH3 C O OH الآن اتفقنا انه لما بدنا نقارن ال
+
+415
+00:38:33,550 --> 00:38:39,690
+H Plus مش لازماني بدي اشيلها و بده اقارن ال Ion
+
+416
+00:38:39,690 --> 00:38:45,650
+السالب و Ion السالب واضح؟
+
+417
+00:38:46,870 --> 00:38:51,470
+الان هتلاحظوا هنا ال ايون السالب هذا موجود على ال
+
+418
+00:38:51,470 --> 00:38:55,430
+oxygen مش قادر يتحرك يعني هذا أشبه البني ادم معه
+
+419
+00:38:55,430 --> 00:39:00,170
+حمل بس إيده التانية مقطوعة طول الطريق هيضله إيش؟
+
+420
+00:39:00,170 --> 00:39:05,670
+حامل الشحن السالب على هذا ال oxygen هذا لأ له اتين
+
+421
+00:39:06,690 --> 00:39:10,570
+بناء على ذلك هذا ممكن يعمل resonance بمعنى أن هذه
+
+422
+00:39:10,570 --> 00:39:15,050
+تتحرك هنا وهذه تيجي هنا لاحظوا هذا ال resonance
+
+423
+00:39:15,050 --> 00:39:21,670
+حركة الإلكترونات متذكرين لما أخدناها CH3 سيصبح CH3
+
+424
+00:39:21,670 --> 00:39:26,150
+وهذه تصبح double bond O وهنا ال O minus إذا ال
+
+425
+00:39:26,150 --> 00:39:31,850
+minus أين صارت محمولة مرة على ال oxygen هذه ومرة
+
+426
+00:39:31,850 --> 00:39:36,350
+على هذهعملة resonance وعشان هيك مرات بتلاقوهم
+
+427
+00:39:36,350 --> 00:39:43,950
+كتبوها بهذا الشكل للأيون CH3COO وعملوا
+
+428
+00:39:43,950 --> 00:39:48,310
+ال minus مشترك بينهم جاعت بتنجل هذا تأثير ايش
+
+429
+00:39:48,310 --> 00:39:53,510
+resonance هذا تأثير resonance عشان هيك ال acetic
+
+430
+00:39:53,510 --> 00:39:57,490
+acid لو بتكون قارنوه بالإيثانول اربعة وسبعة ال BKA
+
+431
+00:39:57,490 --> 00:40:03,880
+مقارنة بخمستاعش تسعةالملاحظين قديش ال acetic acid
+
+432
+00:40:03,880 --> 00:40:09,580
+أقوى من ال ethanol كتير جدا مافيش مقارنة بينهم و
+
+433
+00:40:09,580 --> 00:40:13,720
+السبب لما نقول ال acetic acid is stronger than
+
+434
+00:40:13,720 --> 00:40:19,990
+ethanol الجواب يوتوresonance due to resonance بعد
+
+435
+00:40:19,990 --> 00:40:24,470
+شوية هتلاحظوا انه لما اجي اقارن الفينول بالاثانول
+
+436
+00:40:24,470 --> 00:40:29,330
+تاومت زكريه لما قولنا الفينول عشرة والاثانول خمساش
+
+437
+00:40:29,330 --> 00:40:32,930
+ستاش هتلاحظوا ان الفينول بعمل resonance للاثانول
+
+438
+00:40:32,930 --> 00:40:33,270
+لأ
+
+439
+00:40:37,470 --> 00:40:43,210
+الفكرة العامة وصلت انه هذا التأثير هو تأثير ايش؟
+
+440
+00:40:43,210 --> 00:40:47,110
+resonance نيجي للتأثير التالت ال inductive effect
+
+441
+00:40:47,110 --> 00:40:51,190
+انه ييجي حد يساعد يقول خليني اساعد معاك يعني
+
+442
+00:40:51,190 --> 00:40:55,490
+الشحنة مكانها زي الحمل ما زال باليد هادى مانتجلش
+
+443
+00:40:55,490 --> 00:41:01,550
+لكن بيجي حد ايش؟ بساعد اضافى لو انا اجيت اطلعت على
+
+444
+00:41:01,550 --> 00:41:07,470
+ال ethanol مرة تانيةCH3 CH2 بدي أخد منه على طول بس
+
+445
+00:41:07,470 --> 00:41:12,110
+ال ion السالب هيو مسكين حامل شحنة سالبة متغلب فيها
+
+446
+00:41:12,110 --> 00:41:17,310
+ولا لأ؟ متغلب جدا عارفين ليش؟ لأن ال oxygen صغيرة
+
+447
+00:41:17,310 --> 00:41:21,670
+مش قدرت تحمل شحنة سالبة ال oxygen مش قادرة تحمل
+
+448
+00:41:21,670 --> 00:41:25,550
+الشحنة السالبة الآن هذا يا تورا لو كنت بدي أقارنه
+
+449
+00:41:25,550 --> 00:41:29,110
+بالمركب اللي فيه تلت ذرات floor بسم الله ما شاء
+
+450
+00:41:29,110 --> 00:41:29,330
+الله
+
+451
+00:41:32,590 --> 00:41:38,790
+و هاي ال O و هاي عليها ال minus لاحظوا
+
+452
+00:41:38,790 --> 00:41:43,910
+ال floor ايش ماله ال electronegative ال
+
+453
+00:41:43,910 --> 00:41:48,090
+electronegative شو بعمل في الشحنة السالبة بسحب جزء
+
+454
+00:41:48,090 --> 00:41:53,030
+منها بحمل جزء منها بناء على ذلك هذه الشحنة السالبة
+
+455
+00:41:53,030 --> 00:41:59,650
+فى ناس مساعدين يساعدوا بحملها لأ الآن هنا هاي ال
+
+456
+00:41:59,650 --> 00:42:05,290
+floorElectronegative بيسحق جزء و ال floor التاني
+
+457
+00:42:05,290 --> 00:42:09,510
+كمان جزء و ال floor التالت يعني كأنه حمل أكم واحد
+
+458
+00:42:09,510 --> 00:42:14,050
+إيجي يساعد بحمله كمان تلاتة زي ناس حاملين شغلة
+
+459
+00:42:14,050 --> 00:42:18,790
+كبيرة و إجوا كمان تلاتة يساعدوا بحملها مش بتحمل
+
+460
+00:42:18,790 --> 00:42:24,270
+أسهل لو إجوا اتنينأصعب شوية لو إيجي واحد إذا .. لو
+
+461
+00:42:24,270 --> 00:42:27,770
+أنا بدي أقارن مركّب عليه تلت ذرات floor مع مركّب
+
+462
+00:42:27,770 --> 00:42:30,930
+عليه تنتين مع مركّب عليه واحدة مين بدي يكون فيهم
+
+463
+00:42:30,930 --> 00:42:34,270
+الحامض الأقوى؟ اللي تلاتة لأن في تلاتة جاعدين
+
+464
+00:42:34,270 --> 00:42:39,610
+بيساعدوا بحمل الشحنة السالبة واضح؟ لحظوا هذه أفكار
+
+465
+00:42:39,610 --> 00:42:43,290
+.. هذا هو ال inductive effect هذا ال effect هو إيش
+
+466
+00:42:43,290 --> 00:42:46,890
+بنسميه إحنا؟ ال inductive effect يعني تأثير
+
+467
+00:42:46,890 --> 00:42:55,350
+المساعدةمن خلال مجموعات ساحبة للإلكترونات طبعا هذا
+
+468
+00:42:55,350 --> 00:42:59,930
+ممكن يصير بالنسبة لي سؤال بالصح والغلط أنه يا ترى
+
+469
+00:42:59,930 --> 00:43:04,810
+المجموعة الساحبة للإلكترونات ماذا تعمل بالشحنة
+
+470
+00:43:04,810 --> 00:43:10,690
+السالبة تنقصها إذا تزيد الثبات وتزيد الحامضية طب
+
+471
+00:43:10,690 --> 00:43:16,710
+تخيلوا بقدرة جادر لو بني آدم زي ما بيقول المثل إيه
+
+472
+00:43:16,710 --> 00:43:23,500
+جاي كحلهاعماها بدل ما يحط تلت مجموعات مساعدة تحمل
+
+473
+00:43:23,500 --> 00:43:28,100
+حط تلاتة تزيد الحمل عارفين زي إيش؟ زي الأم الصغيرة
+
+474
+00:43:28,100 --> 00:43:30,780
+اللي شارية شغلة من السوق الأم اللي شارية شغلة من
+
+475
+00:43:30,780 --> 00:43:34,380
+السوق وتعبانة بحملها ومعها تلت ولادة وكل ولد بيحط
+
+476
+00:43:34,380 --> 00:43:41,320
+تجله على إيدها بتصير مش جارة الشغلة الشغلة و التلت
+
+477
+00:43:41,320 --> 00:43:45,480
+ولادة بتشوفوا كيف مهدودة وجه تسار التأثير إيش
+
+478
+00:43:45,480 --> 00:43:52,360
+ماله؟ عكسييعني لو هذه المجموعة بطلت ساحبة صارت
+
+479
+00:43:52,360 --> 00:43:57,060
+مجموعة معطية للإلكترونات وجدت إيش بدها تعمل
+
+480
+00:43:57,060 --> 00:44:00,400
+بالشحنة السالبة؟ بدها تزيدها، شو بتتوقع يصير في
+
+481
+00:44:00,400 --> 00:44:05,420
+الحامضية؟ اتقل، عشان هيك لو اطلعت مثلا هذا المثال
+
+482
+00:44:05,420 --> 00:44:06,680
+اللي فيه CH3
+
+483
+00:44:09,570 --> 00:44:13,210
+CH3O- اللي جاي من ال tertiary butyl alcohol
+
+484
+00:44:13,210 --> 00:44:16,690
+اتطلعوا في الجدول كداش ال tertiary butyl alcohol
+
+485
+00:44:16,690 --> 00:44:27,270
+عندكم محتوى 18 اقل اقل في الحمضية ولا لأ ايش السبب
+
+486
+00:44:27,270 --> 00:44:34,680
+ان هذه المجموعاتبتعطي إلكترونات electron donating
+
+487
+00:44:34,680 --> 00:44:40,080
+مش electron with a drawing الكلور بسبب سليبيته
+
+488
+00:44:40,080 --> 00:44:48,280
+بيسحب إلكترونات واضح المثل بيعطي إلكترونات وعشان
+
+489
+00:44:48,280 --> 00:44:52,640
+هيك هذا المركب يعني خلينا نعمل مرجعيتنا الاثانول
+
+490
+00:44:52,640 --> 00:45:02,070
+مشجولة حوالي 15.9 هذا المركب 18 أضعف هذا المركب12
+
+491
+00:45:02,070 --> 00:45:09,070
+أقوى واضح كيف التأثير انه انا لو اجيت اقارن هذه
+
+492
+00:45:09,070 --> 00:45:13,630
+المركبات المتشابهة هنا عندي تقليل الشحنة السالبة
+
+493
+00:45:13,630 --> 00:45:19,650
+معناها زيادة حمضية هنا عندي تركيز او intensifying
+
+494
+00:45:19,650 --> 00:45:25,720
+او زيادة الشحنة السالبة معناهاتقليل حمضية هذا ال
+
+495
+00:45:25,720 --> 00:45:28,920
+inductive effect بوجهينه ما هو ايه؟ في ناس
+
+496
+00:45:28,920 --> 00:45:33,820
+بيساعدوا بالموجب و في ناس بيساعدوا بالسالب واضح؟
+
+497
+00:45:33,820 --> 00:45:36,320
+تماما زي المثال الحكيناه، ناس بيجوا بيساعدوه و
+
+498
+00:45:36,320 --> 00:45:40,760
+بيحملوا مع البني آدم و ناس .. جيبناك يا عبد المعين
+
+499
+00:45:40,760 --> 00:45:47,160
+اتعين لجناك بدك؟ معين واضح؟ هنا التأثير سلبي، هنا
+
+500
+00:45:47,160 --> 00:45:54,420
+التأثير إيجابيواضح الفكرة؟ اذا اخر شيء باختم اليوم
+
+501
+00:45:54,420 --> 00:45:57,660
+بعدك بتصير الأمثلة كل اللي في ال slides اللي
+
+502
+00:45:57,660 --> 00:46:02,960
+بنحكيه بتجيجتين خلاص فينا المبادئ مفهوم الحامضية
+
+503
+00:46:02,960 --> 00:46:06,600
+مرتبط بالشحنة السالبة إنها تجل الشحنة السالبة اللي
+
+504
+00:46:06,600 --> 00:46:12,500
+بيجللها تلت أشياء ال size الأكبر ال resonance
+
+505
+00:46:12,500 --> 00:46:19,240
+الأكتر وال inductive effect الساحبلاحظوا عند كلمة
+
+506
+00:46:19,240 --> 00:46:24,260
+ال inductive effect ال inductive effect نوعين فى
+
+507
+00:46:24,260 --> 00:46:28,200
+inductive effect ساحب و inductive effect معطى ال
+
+508
+00:46:28,200 --> 00:46:33,100
+inductive effect الساحب هو اللى بيزيد الحامضية ال
+
+509
+00:46:33,100 --> 00:46:37,760
+inductive effect المعطى هو اللى بيقلل الحامضية إذا
+
+510
+00:46:37,760 --> 00:46:42,040
+صار عندى electron إيش معنى ساحب بالإنقليزة with a
+
+511
+00:46:42,040 --> 00:46:49,840
+drawing يسحب و إيش معنى معطىdonating donation
+
+512
+00:46:49,840 --> 00:46:56,080
+اعطار أو releasing electron donating electron
+
+513
+00:46:56,080 --> 00:47:00,240
+releasing هذا بيقلل الحمضية electron withdrawing
+
+514
+00:47:00,240 --> 00:47:04,740
+بيزيد الحمضية بنختم عند هذه اللحظة
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..a06edd19fb44e491212b9dcf2d41eae9c2b33efe
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_raw.json
@@ -0,0 +1 @@
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ربما حسب التدرج اللي اتعلمته في المدارس أول ما بيمر على الناس ال Arrhenius definition تعريف Arrhenius للحمض و القلوي خلنا نشوفه ال Arrhenius definition من خلال مثال", "tokens": [27842, 37279, 16572, 5172, 3714, 9640, 25894, 24793, 5551, 4117, 2655, 2288, 9154, 37279, 16572, 5172, 24976, 35571, 11242, 13412, 2407, 31439, 21542, 2304, 11242, 4032, 13412, 2407, 25062, 1211, 45865, 12602, 3555, 15042, 11331, 35457, 16712, 3215, 47341, 13672, 1829, 1975, 2655, 3615, 19528, 47395, 8978, 9673, 3215, 9640, 3794, 5551, 12610, 19446, 4724, 1829, 29973, 15844, 2423, 8315, 3794, 2423, 1587, 81, 2932, 4872, 7123, 37279, 16572, 5172, 1587, 81, 2932, 4872, 24976, 35571, 11242, 4032, 25062, 1211, 45865, 16490, 1211, 8315, 8717, 8592, 38688, 3224, 2423, 1587, 81, 2932, 4872, 7123, 9154, 16490, 1211, 6027, 50113, 6027], "avg_logprob": -0.13551980552106802, "compression_ratio": 1.8865979381443299, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 110.85, "end": 111.15, "word": "من", 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"start": 242.8, "end": 258.02, "text": "خلّى تعريف الحامض زى ما هو اللى بيعطى H بلس فى التأيون واضح فالحامض عند لوري برويستن شو بيعطينى H بلس وبناء على ذلك وين بده يكون الحمض الـHCl كله عنده حامض", "tokens": [9778, 1211, 11703, 7578, 37279, 16572, 5172, 21542, 10943, 11242, 30767, 7578, 19446, 31439, 13672, 7578, 4724, 40228, 9566, 7578, 389, 4724, 1211, 3794, 6156, 7578, 16712, 10721, 1829, 11536, 4032, 46958, 5016, 6156, 6027, 5016, 10943, 11242, 43242, 5296, 13063, 1829, 4724, 32887, 1829, 14851, 1863, 13412, 2407, 4724, 1829, 3615, 9566, 9957, 7578, 389, 4724, 1211, 3794, 46599, 1863, 16606, 15844, 29910, 23275, 4032, 9957, 47525, 3224, 7251, 30544, 21542, 2304, 11242, 2423, 39184, 39, 9966, 28242, 3224, 43242, 3224, 11331, 10943, 11242], "avg_logprob": -0.23219477385282516, "compression_ratio": 1.6606060606060606, "no_speech_prob": 0.0, "words": [{"start": 242.8, "end": 243.22, "word": "خلّى", "probability": 0.8565673828125}, {"start": 243.22, "end": 243.6, "word": " تعريف", 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"text": "زي ما أتيت هنا وأخدت مركز القوة هذا تعالي ناخد مركز القوة الـ H Plus", "tokens": [11622, 1829, 19446, 5551, 31371, 2655, 34105, 36725, 9778, 3215, 2655, 3714, 31747, 11622, 25062, 2407, 3660, 23758, 37279, 6027, 1829, 8717, 47283, 3215, 3714, 31747, 11622, 25062, 2407, 3660, 2423, 39184, 389, 7721], "avg_logprob": -0.3888392874172756, "compression_ratio": 1.2857142857142858, "no_speech_prob": 0.0, "words": [{"start": 397.76, "end": 398.74, "word": "زي", "probability": 0.621826171875}, {"start": 398.74, "end": 398.86, "word": " ما", "probability": 0.82080078125}, {"start": 398.86, "end": 399.34, "word": " أتيت", "probability": 0.589599609375}, {"start": 399.34, "end": 399.56, "word": " هنا", "probability": 0.7333984375}, {"start": 399.56, "end": 400.14, "word": " وأخدت", "probability": 0.7818603515625}, {"start": 400.14, "end": 400.66, "word": " مركز", "probability": 0.9484049479166666}, {"start": 400.66, "end": 401.22, "word": " القوة", "probability": 0.9742838541666666}, 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Lewis هو H بلس", "tokens": [6027, 39184, 13931, 12, 6156, 4117, 33456, 3224, 5551, 9778, 1211, 2655, 9154, 23758, 25724, 11622, 38207, 16247, 3794, 32277, 1829, 8978, 3224, 4032, 27842, 23758, 25724, 11622, 38207, 16247, 3794, 32277, 1829, 8978, 3224, 13672, 1829, 39896, 11331, 38436, 28671, 2423, 39184, 2533, 17437, 299, 5367, 37495, 22653, 29538, 45164, 6225, 42213, 2655, 5296, 11296, 2533, 17437, 299, 5367, 2423, 39184, 6056, 16070, 39184, 2033, 28242, 16095, 9154, 13412, 9566, 3555, 3224, 39896, 6225, 3555, 9640, 3660, 18871, 389, 4724, 1211, 3794, 30767, 16373, 3215, 13931, 12, 39894, 3615, 9566, 1829, 8315, 389, 17, 46, 46599, 1863, 16606, 15844, 29910, 23275, 2423, 8258, 43242, 17412, 31439, 389, 4724, 1211, 3794], "avg_logprob": -0.21372767670878343, "compression_ratio": 1.6722689075630253, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 409.96, "end": 410.28, "word": "الـ", "probability": 0.52587890625}, {"start": 410.28, "end": 410.44, "word": " OH", 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كتبت", "probability": 0.9959716796875}, {"start": 497.7, "end": 498.04, "word": " A", "probability": 0.8017578125}, {"start": 498.04, "end": 498.66, "word": " plus", "probability": 0.91748046875}, {"start": 498.66, "end": 499.74, "word": " زائد", "probability": 0.8351236979166666}, {"start": 499.74, "end": 500.2, "word": " مثلا", "probability": 0.984130859375}, {"start": 500.2, "end": 500.72, "word": " X", "probability": 0.9599609375}, {"start": 500.72, "end": 501.58, "word": " minus", "probability": 0.98828125}], "temperature": 1.0}, {"id": 23, "seek": 52529, "start": 503.87, "end": 525.29, "text": "هذا بيعطي إلكترونات إذا هذا بيحصل هذا بيكتسب إلكترونات إذا هذا أسد واضح و لذلك إذا بتذكروا لما أخدنا على سبيل المثال في chapter ال aromatic compounds مركب زي ال FECL3 قلنا إن ال FECL3 كام إلكترون كان حوله", "tokens": [3224, 15730, 4724, 1829, 3615, 9566, 1829, 11933, 23275, 2655, 2288, 11536, 9307, 11933, 15730, 23758, 4724, 1829, 5016, 36520, 23758, 4724, 1829, 4117, 2655, 35457, 11933, 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519.17, "word": " ال", "probability": 0.68310546875}, {"start": 519.17, "end": 520.53, "word": " FECL3", "probability": 0.81591796875}, {"start": 520.53, "end": 521.81, "word": " قلنا", "probability": 0.6890462239583334}, {"start": 521.81, "end": 521.97, "word": " إن", "probability": 0.32080078125}, {"start": 521.97, "end": 522.11, "word": " ال", "probability": 0.6357421875}, {"start": 522.11, "end": 523.65, "word": " FECL3", "probability": 0.9674072265625}, {"start": 523.65, "end": 523.95, "word": " كام", "probability": 0.67333984375}, {"start": 523.95, "end": 524.53, "word": " إلكترون", "probability": 0.99052734375}, {"start": 524.53, "end": 524.79, "word": " كان", "probability": 0.943359375}, {"start": 524.79, "end": 525.29, "word": " حوله", "probability": 0.966796875}], "temperature": 1.0}, {"id": 24, "seek": 55102, "start": 527.04, "end": 551.02, "text": "6 electron sextant الوضع الطبيعي كم يكون 8 و بناء على ذلك اعتبرنا Lewis acid فلما نيجي نقول له ال aromatic compounds كيف كانوا 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"probability": 0.9384765625}, {"start": 550.22, "end": 550.54, "word": " كان", "probability": 0.9814453125}, {"start": 550.54, "end": 551.02, "word": " يعطي", "probability": 0.9801432291666666}], "temperature": 1.0}, {"id": 25, "seek": 56803, "start": 551.81, "end": 568.03, "text": "سيال مع إلكتروناتها كأنه هذه ال base هو بيكتسب السيال مع إلكتروناتها بيصير تمان إلكترونات حوله بدل ستة فهذا acid وهذا الجزء كأنه تعامل ك base وعشان تقولنا أن ال aromatic reactions", "tokens": [3794, 1829, 6027, 20449, 11933, 23275, 2655, 2288, 11536, 9307, 11296, 9122, 33456, 3224, 29538, 2423, 3096, 31439, 4724, 1829, 4117, 2655, 35457, 21136, 1829, 6027, 20449, 11933, 23275, 2655, 2288, 11536, 9307, 11296, 4724, 1829, 9381, 13546, 46811, 7649, 11933, 23275, 2655, 2288, 11536, 9307, 11331, 12610, 3224, 47525, 1211, 8608, 2655, 3660, 6156, 3224, 15730, 8258, 37037, 15730, 25724, 11622, 38207, 9122, 33456, 3224, 37279, 10943, 1211, 9122, 3096, 4032, 3615, 8592, 7649, 6055, 39648, 8315, 14739, 2423, 45831, 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"word": " كأنه", "probability": 0.8387044270833334}, {"start": 563.61, "end": 564.29, "word": " تعامل", "probability": 0.8233235677083334}, {"start": 564.29, "end": 564.81, "word": " ك", "probability": 0.990234375}, {"start": 564.81, "end": 565.27, "word": " base", "probability": 0.76904296875}, {"start": 565.27, "end": 566.25, "word": " وعشان", "probability": 0.9066162109375}, {"start": 566.25, "end": 566.63, "word": " تقولنا", "probability": 0.7349853515625}, {"start": 566.63, "end": 566.77, "word": " أن", "probability": 0.466552734375}, {"start": 566.77, "end": 566.87, "word": " ال", "probability": 0.89111328125}, {"start": 566.87, "end": 567.21, "word": " aromatic", "probability": 0.86376953125}, {"start": 567.21, "end": 568.03, "word": " reactions", "probability": 0.8271484375}], "temperature": 1.0}, {"id": 26, "seek": 58589, "start": 568.23, "end": 585.89, "text": "بتم في وجود ال FECL3 أو الألمنيوم الكلوريد الآن الإنسان مابدوش يكتب FECL3 أو الألمنيوم الكلوريد بيقول ببساطة the chlorination of aromatic compounds occurs by using Cl2 with a Lewis acid", "tokens": [3555, 39237, 8978, 49610, 23328, 2423, 479, 8140, 43, 18, 34051, 16247, 19528, 22653, 20498, 33251, 1211, 13063, 25708, 6024, 48506, 33688, 1863, 3794, 7649, 3714, 16758, 3215, 2407, 8592, 7251, 4117, 2655, 3555, 479, 8140, 43, 18, 34051, 16247, 19528, 22653, 20498, 33251, 1211, 13063, 25708, 4724, 1829, 39648, 4724, 3555, 3794, 41193, 3660, 264, 18178, 2486, 295, 45831, 21810, 11843, 538, 1228, 2033, 17, 365, 257, 17412, 8258], "avg_logprob": -0.2845510462640037, "compression_ratio": 1.4615384615384615, "no_speech_prob": 0.0, "words": [{"start": 568.23, "end": 568.67, "word": "بتم", "probability": 0.5018310546875}, {"start": 568.67, "end": 568.85, "word": " في", "probability": 0.90283203125}, {"start": 568.85, "end": 569.27, "word": " وجود", "probability": 0.986083984375}, {"start": 569.27, "end": 569.41, "word": " ال", "probability": 0.481201171875}, {"start": 569.41, "end": 570.67, "word": " FECL3", "probability": 0.60321044921875}, {"start": 570.67, "end": 571.27, "word": " أو", "probability": 0.6455078125}, {"start": 571.27, "end": 571.99, "word": " الألمنيوم", "probability": 0.656768798828125}, {"start": 571.99, "end": 572.63, "word": " الكلوريد", "probability": 0.7586669921875}, {"start": 572.63, "end": 573.23, "word": " الآن", "probability": 0.5635986328125}, {"start": 573.23, "end": 573.69, "word": " الإنسان", "probability": 0.85980224609375}, {"start": 573.69, "end": 574.05, "word": " مابدوش", "probability": 0.7447265625}, {"start": 574.05, "end": 574.29, "word": " يكتب", "probability": 0.9705810546875}, {"start": 574.29, "end": 575.13, "word": " FECL3", "probability": 0.907958984375}, {"start": 575.13, "end": 575.27, "word": " أو", "probability": 0.69970703125}, {"start": 575.27, "end": 575.69, "word": " الألمنيوم", "probability": 0.8280029296875}, {"start": 575.69, "end": 576.25, "word": " الكلوريد", "probability": 0.9315185546875}, {"start": 576.25, "end": 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"probability": 0.64697265625}, {"start": 834.19, "end": 834.79, "word": " acidity", "probability": 0.53466796875}, {"start": 834.79, "end": 835.29, "word": " constant", "probability": 0.95849609375}, {"start": 835.29, "end": 835.59, "word": " is", "probability": 0.93310546875}, {"start": 835.59, "end": 835.91, "word": " another", "probability": 0.9130859375}, {"start": 835.91, "end": 836.27, "word": " thing", "probability": 0.93408203125}, {"start": 836.27, "end": 836.65, "word": " ال", "probability": 0.54345703125}, {"start": 836.65, "end": 836.91, "word": " K", "probability": 0.301513671875}, {"start": 836.91, "end": 837.15, "word": " a", "probability": 0.267822265625}, {"start": 837.15, "end": 837.69, "word": " هذه", "probability": 0.50048828125}, {"start": 837.69, "end": 838.23, "word": " هي", "probability": 0.88134765625}, {"start": 838.23, "end": 838.65, "word": " عبارة", "probability": 0.9869384765625}, {"start": 838.65, "end": 838.89, "word": " عن", "probability": 0.9951171875}, {"start": 838.89, "end": 839.27, "word": " ثابت", "probability": 0.9939778645833334}, {"start": 839.27, "end": 839.83, "word": " الاتزان", "probability": 0.853515625}, {"start": 839.83, "end": 840.25, "word": " مضروب", "probability": 0.861328125}, {"start": 840.25, "end": 840.37, "word": " في", "probability": 0.9208984375}, {"start": 840.37, "end": 840.99, "word": " تركيز", "probability": 0.9022216796875}, {"start": 840.99, "end": 841.63, "word": " ال", "probability": 0.92578125}, {"start": 841.63, "end": 842.41, "word": " H2O", "probability": 0.8837890625}, {"start": 842.41, "end": 842.73, "word": " اللي", "probability": 0.8466796875}, {"start": 842.73, "end": 843.15, "word": " ثابت", "probability": 0.99560546875}, {"start": 843.15, "end": 843.69, "word": " الان", "probability": 0.6734619140625}, {"start": 843.69, "end": 843.87, "word": " لو", "probability": 0.98193359375}, {"start": 843.87, "end": 844.25, "word": " اتيت", "probability": 0.6985677083333334}, {"start": 844.25, "end": 844.45, "word": " على", "probability": 0.73095703125}, {"start": 844.45, "end": 844.65, "word": " ال", "probability": 0.7646484375}, {"start": 844.65, "end": 844.83, "word": " K", "probability": 0.9541015625}, {"start": 844.83, "end": 845.01, "word": " a", "probability": 0.88134765625}, {"start": 845.01, "end": 845.73, "word": " هيصير", "probability": 0.736083984375}, {"start": 845.73, "end": 846.91, "word": " ربما", "probability": 0.9676106770833334}, {"start": 846.91, "end": 847.43, "word": " التعبير", "probability": 0.9625244140625}, {"start": 847.43, "end": 847.57, "word": " اللي", "probability": 0.9189453125}, {"start": 847.57, "end": 848.05, "word": " حضرتكم", "probability": 0.654052734375}, {"start": 848.05, "end": 848.83, "word": " بتعرفوه", "probability": 0.8908203125}, {"start": 848.83, "end": 849.65, "word": " H3O", "probability": 0.8873697916666666}, {"start": 849.65, "end": 850.11, "word": " plus", "probability": 0.2203369140625}, {"start": 850.11, "end": 851.33, "word": " في", "probability": 0.78369140625}, {"start": 851.33, "end": 851.57, "word": " A", "probability": 0.5146484375}, {"start": 851.57, "end": 852.25, "word": " minus", "probability": 0.87158203125}, {"start": 852.25, "end": 852.85, "word": " على", "probability": 0.763671875}], "temperature": 1.0}, {"id": 38, "seek": 87005, "start": 854.55, "end": 870.05, "text": "هذا تعبير إيش ال K A اللي بنسميه احنا acidity constant يعني ثابت الحامض الآن ال acidity constant", "tokens": [3224, 15730, 37279, 3555, 13546, 11933, 1829, 8592, 2423, 591, 316, 13672, 1829, 44945, 38251, 1829, 3224, 1975, 5016, 8315, 8258, 507, 5754, 37495, 22653, 38637, 16758, 2655, 21542, 10943, 11242, 6024, 48506, 2423, 8258, 507, 5754], "avg_logprob": -0.24568257441646174, "compression_ratio": 1.2654867256637168, "no_speech_prob": 0.0, "words": [{"start": 854.55, "end": 855.77, "word": "هذا", "probability": 0.6431884765625}, {"start": 855.77, "end": 856.85, "word": " تعبير", "probability": 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0.9111328125}, {"start": 865.73, "end": 867.65, "word": " الآن", "probability": 0.65478515625}, {"start": 867.65, "end": 868.37, "word": " ال", "probability": 0.8330078125}, {"start": 868.37, "end": 869.19, "word": " acidity", "probability": 0.991943359375}, {"start": 869.19, "end": 870.05, "word": " constant", "probability": 0.96826171875}], "temperature": 1.0}, {"id": 39, "seek": 89206, "start": 871.96, "end": 892.06, "text": "و كل مكان أعلى كل مكان الحامض بتأيين أكثر والحامض اللي بتأيين أكثر بالتعريف والحامض الاش الأقوى بناء على ذلك لو أنا بدي أعمل مقارنة لحامضين مين اللي بدي يكون أقوى اللي له K A أعلى", "tokens": [2407, 28242, 3714, 41361, 5551, 3615, 23942, 28242, 3714, 41361, 21542, 10943, 11242, 39894, 10721, 1829, 9957, 5551, 4117, 49115, 16070, 5016, 10943, 11242, 13672, 1829, 39894, 10721, 1829, 9957, 5551, 4117, 49115, 20666, 2655, 3615, 16572, 5172, 16070, 5016, 10943, 11242, 2423, 33599, 16247, 4587, 2407, 7578, 44945, 16606, 15844, 29910, 23275, 45164, 41850, 4724, 16254, 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"word": " أكثر", "probability": 0.9069010416666666}, {"start": 876.88, "end": 877.42, "word": " والحامض", "probability": 0.715087890625}, {"start": 877.42, "end": 877.54, "word": " اللي", "probability": 0.85400390625}, {"start": 877.54, "end": 878.02, "word": " بتأيين", "probability": 0.9581298828125}, {"start": 878.02, "end": 878.42, "word": " أكثر", "probability": 0.9015299479166666}, {"start": 878.42, "end": 879.06, "word": " بالتعريف", "probability": 0.9197265625}, {"start": 879.06, "end": 879.64, "word": " والحامض", "probability": 0.819091796875}, {"start": 879.64, "end": 880.14, "word": " الاش", "probability": 0.552001953125}, {"start": 880.14, "end": 881.08, "word": " الأقوى", "probability": 0.883056640625}, {"start": 881.08, "end": 881.74, "word": " بناء", "probability": 0.804931640625}, {"start": 881.74, "end": 882.0, "word": " على", "probability": 0.828125}, {"start": 882.0, "end": 882.5, "word": " ذلك", "probability": 0.9931640625}, {"start": 882.5, "end": 882.9, "word": " لو", "probability": 0.8818359375}, {"start": 882.9, "end": 883.12, "word": " أنا", "probability": 0.6337890625}, {"start": 883.12, "end": 883.32, "word": " بدي", "probability": 0.684814453125}, {"start": 883.32, "end": 883.68, "word": " أعمل", "probability": 0.9495442708333334}, {"start": 883.68, "end": 884.48, "word": " مقارنة", "probability": 0.99140625}, {"start": 884.48, "end": 885.56, "word": " لحامضين", "probability": 0.93974609375}, {"start": 885.56, "end": 886.64, "word": " مين", "probability": 0.91162109375}, {"start": 886.64, "end": 886.78, "word": " اللي", "probability": 0.96826171875}, {"start": 886.78, "end": 887.0, "word": " بدي", "probability": 0.799560546875}, {"start": 887.0, "end": 887.34, "word": " يكون", "probability": 0.94921875}, {"start": 887.34, "end": 888.16, "word": " أقوى", "probability": 0.9716796875}, {"start": 888.16, "end": 889.54, "word": " اللي", "probability": 0.818359375}, {"start": 889.54, "end": 889.94, "word": " له", "probability": 0.46337890625}, 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هذا الكلام لو إجينا أعطيناكم حامض HA", "tokens": [28820, 19446, 2423, 39184, 10988, 39894, 30544, 5551, 3615, 23942, 8978, 25062, 32640, 3660, 28242, 19446, 21542, 10943, 11242, 4724, 1829, 30544, 5551, 4587, 2407, 7578, 6156, 10721, 8315, 45164, 5551, 3615, 9566, 36081, 24793, 50113, 15040, 11331, 10943, 11242, 9957, 39896, 10988, 46740, 15730, 4032, 42, 64, 46740, 15730, 39894, 28543, 2288, 14407, 15844, 23032, 12610, 6055, 39648, 12610, 1829, 3714, 9957, 21542, 10943, 11242, 16247, 4587, 2407, 7578, 8978, 16095, 13672, 1829, 11933, 43761, 2423, 10988, 5551, 3615, 23942, 16490, 1211, 9957, 995, 8717, 7435, 25513, 8717, 25957, 1211, 23758, 2423, 28820, 10943, 16490, 1211, 9957, 995, 8717, 7435, 25513, 8717, 25957, 1211, 23758, 2423, 28820, 10943, 45164, 11933, 7435, 1829, 8315, 5551, 3615, 9566, 1829, 8315, 24793, 11331, 10943, 11242, 11979], "avg_logprob": -0.15737500143051147, "compression_ratio": 2.1658536585365855, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 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"text": "الان هذه تقريبا مقدمة خلنا نقول تذكير بشكل عام في مفاهيم الأحماض الان لما نيجي نتكلم عن ال alcohols هل يا ترى الكحول ممكن يكون حامض ولا لأ؟", "tokens": [6027, 7649, 29538, 6055, 4587, 16572, 3555, 995, 3714, 28543, 46007, 16490, 1211, 8315, 8717, 39648, 6055, 8848, 4117, 13546, 4724, 8592, 28820, 6225, 10943, 8978, 3714, 5172, 40294, 32640, 16247, 35571, 46958, 2423, 7649, 5296, 15042, 8717, 1829, 7435, 1829, 8717, 2655, 4117, 19528, 18871, 2423, 7658, 82, 8032, 1211, 35186, 6055, 2288, 7578, 33251, 5016, 12610, 3714, 43020, 7251, 30544, 11331, 10943, 11242, 49429, 5296, 10721, 22807], "avg_logprob": -0.13783481610672815, "compression_ratio": 1.5093167701863355, "no_speech_prob": 0.0, "words": [{"start": 1244.56, "end": 1245.1, "word": "الان", "probability": 0.8134765625}, {"start": 1245.1, "end": 1245.64, "word": " هذه", "probability": 0.63623046875}, {"start": 1245.64, "end": 1246.44, "word": " تقريبا", "probability": 0.99208984375}, {"start": 1246.44, "end": 1247.88, 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ممكن اعتبرها كأن أبسط كحول هنا قلت H O R وهنا H O H يعني كأن ال R هذه H عشان هي أبسط إيش", "tokens": [40228, 22653, 45164, 5551, 9778, 3215, 2655, 8717, 36178, 29538, 9673, 3615, 18513, 37977, 9673, 10632, 9122, 35571, 11242, 389, 422, 389, 20193, 5016, 19913, 14407, 5296, 15042, 9673, 25720, 9673, 46958, 10632, 12174, 1211, 2655, 23275, 14407, 14739, 9673, 10632, 6156, 1211, 3794, 5172, 25528, 3714, 43020, 1975, 34268, 26890, 11296, 9122, 33456, 5551, 3555, 3794, 9566, 9122, 5016, 12610, 34105, 12174, 1211, 2655, 389, 422, 497, 37037, 8315, 389, 422, 389, 37495, 22653, 9122, 33456, 2423, 497, 29538, 389, 6225, 8592, 7649, 39896, 5551, 3555, 3794, 9566, 11933, 1829, 8592], "avg_logprob": -0.20010080388797227, "compression_ratio": 1.8, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1302.43, "end": 1302.83, "word": "يعني", "probability": 0.9208984375}, {"start": 1302.83, "end": 1302.93, "word": " لو", "probability": 0.6865234375}, {"start": 1302.93, "end": 1303.27, "word": 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"probability": 0.7605794270833334}, {"start": 2249.08, "end": 2249.3, "word": " بس", "probability": 0.9140625}, {"start": 2249.3, "end": 2249.66, "word": " مفرج", "probability": 0.8981119791666666}, {"start": 2249.66, "end": 2249.84, "word": " ال", "probability": 0.7265625}, {"start": 2249.84, "end": 2250.16, "word": " sulfur", "probability": 0.50048828125}, {"start": 2250.16, "end": 2250.36, "word": " و", "probability": 0.71240234375}, {"start": 2250.36, "end": 2250.48, "word": " ال", "probability": 0.88916015625}, {"start": 2250.48, "end": 2250.96, "word": " oxygen", "probability": 0.791015625}, {"start": 2250.96, "end": 2251.44, "word": " طب", "probability": 0.861328125}, {"start": 2251.44, "end": 2251.5, "word": " ما", "probability": 0.88525390625}, {"start": 2251.5, "end": 2251.64, "word": " هي", "probability": 0.86865234375}, {"start": 2251.64, "end": 2251.84, "word": " ال", "probability": 0.8544921875}, {"start": 2251.84, "end": 2252.84, "word": " sulfur؟", "probability": 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"probability": 0.7294921875}, {"start": 2262.55, "end": 2263.29, "word": " فصّال", "probability": 0.63983154296875}, {"start": 2263.29, "end": 2263.45, "word": " لي", "probability": 0.73779296875}, {"start": 2263.45, "end": 2263.73, "word": " ليش", "probability": 0.7978515625}, {"start": 2263.73, "end": 2263.91, "word": " ال", "probability": 0.732421875}, {"start": 2263.91, "end": 2265.19, "word": " RSH", "probability": 0.618896484375}, {"start": 2265.19, "end": 2266.11, "word": " أقوى", "probability": 0.9576416015625}, {"start": 2266.11, "end": 2266.41, "word": " من", "probability": 0.9921875}, {"start": 2266.41, "end": 2266.77, "word": " ال", "probability": 0.791015625}, {"start": 2266.77, "end": 2268.85, "word": " ROH", "probability": 0.3931884765625}, {"start": 2268.85, "end": 2269.25, "word": " و", "probability": 0.66748046875}, {"start": 2269.25, "end": 2269.57, "word": " ليش", "probability": 0.8193359375}, {"start": 2269.57, "end": 2269.79, "word": " ال", "probability": 0.9375}, {"start": 2269.79, "end": 2272.01, "word": " ARSH", "probability": 0.783447265625}, {"start": 2272.01, "end": 2272.57, "word": " أقوى", "probability": 0.9798583984375}, {"start": 2272.57, "end": 2272.81, "word": " من", "probability": 0.99609375}, {"start": 2272.81, "end": 2273.05, "word": " ال", "probability": 0.90869140625}, {"start": 2273.05, "end": 2275.13, "word": " AROH", "probability": 0.8671875}, {"start": 2275.13, "end": 2276.09, "word": " ال", "probability": 0.396728515625}, {"start": 2276.09, "end": 2276.41, "word": " size", "probability": 0.8486328125}, {"start": 2276.41, "end": 2276.59, "word": " اللي", "probability": 0.8544921875}, {"start": 2276.59, "end": 2277.01, "word": " فصّال", "probability": 0.8763427734375}, {"start": 2277.01, "end": 2277.43, "word": " ليها", "probability": 0.790283203125}, {"start": 2277.43, "end": 2278.57, "word": " الحجم", "probability": 0.9298502604166666}], "temperature": 1.0}, {"id": 100, "seek": 229786, "start": 2279.42, "end": 2297.86, "text": "الحجم الكبير أقدر على حمل الشحنة الحجم الكبير أقدر على حمل الشحنة الآن خليني أجي لل resonance و بدي أقارن أنا الاثانول مع حمض الخلق لاحظوا الاثانول إيش صيبته؟", "tokens": [6027, 5016, 7435, 2304, 33251, 3555, 13546, 5551, 28543, 2288, 15844, 11331, 42213, 25124, 5016, 1863, 3660, 21542, 7435, 2304, 33251, 3555, 13546, 5551, 28543, 2288, 15844, 11331, 42213, 25124, 5016, 1863, 3660, 6024, 48506, 16490, 1211, 9957, 1829, 5551, 7435, 1829, 24976, 30944, 4032, 4724, 16254, 5551, 4587, 9640, 1863, 41850, 2423, 5718, 104, 7649, 12610, 20449, 11331, 2304, 11242, 33962, 1211, 4587, 20193, 5016, 19913, 14407, 2423, 5718, 104, 7649, 12610, 11933, 1829, 8592, 20328, 1829, 3555, 47395, 22807], "avg_logprob": -0.19588413998121168, "compression_ratio": 1.8355263157894737, "no_speech_prob": 0.0, "words": [{"start": 2279.42, "end": 2280.0, "word": "الحجم", "probability": 0.974365234375}, {"start": 2280.0, "end": 2280.54, "word": " الكبير", "probability": 0.9860026041666666}, {"start": 2280.54, "end": 2281.02, "word": " أقدر", "probability": 0.8955078125}, {"start": 2281.02, "end": 2281.22, "word": " على", "probability": 0.90283203125}, {"start": 2281.22, "end": 2281.56, "word": " حمل", "probability": 0.866455078125}, {"start": 2281.56, "end": 2283.42, "word": " الشحنة", "probability": 0.9051513671875}, {"start": 2283.42, "end": 2284.2, "word": " الحجم", "probability": 0.75341796875}, {"start": 2284.2, "end": 2284.6, "word": " الكبير", "probability": 0.9820963541666666}, {"start": 2284.6, "end": 2285.02, "word": " أقدر", "probability": 0.9853515625}, {"start": 2285.02, "end": 2285.22, "word": " على", "probability": 0.91259765625}, {"start": 2285.22, "end": 2285.62, "word": " حمل", "probability": 0.9638671875}, {"start": 2285.62, "end": 2287.66, "word": " الشحنة", "probability": 0.984130859375}, {"start": 2287.66, "end": 2288.94, "word": " الآن", "probability": 0.6409912109375}, {"start": 2288.94, "end": 2289.62, "word": " خليني", "probability": 0.8291015625}, {"start": 2289.62, "end": 2290.06, "word": " أجي", "probability": 0.8321940104166666}, {"start": 2290.06, "end": 2290.4, "word": " لل", "probability": 0.89794921875}, {"start": 2290.4, "end": 2291.06, "word": " resonance", "probability": 0.740234375}, {"start": 2291.06, "end": 2292.28, "word": " و", "probability": 0.580078125}, {"start": 2292.28, "end": 2292.5, "word": " بدي", "probability": 0.5706787109375}, {"start": 2292.5, "end": 2293.04, "word": " أقارن", "probability": 0.9600830078125}, {"start": 2293.04, "end": 2293.3, "word": " أنا", "probability": 0.418212890625}, {"start": 2293.3, "end": 2293.96, "word": " الاثانول", "probability": 0.733056640625}, {"start": 2293.96, "end": 2294.22, "word": " مع", "probability": 0.372314453125}, {"start": 2294.22, "end": 2294.5, "word": " حمض", "probability": 0.88330078125}, {"start": 2294.5, "end": 2295.52, "word": " الخلق", "probability": 0.8802083333333334}, {"start": 2295.52, "end": 2296.26, "word": " لاحظوا", "probability": 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"compression_ratio": 1.5067567567567568, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2298.53, "end": 2299.77, "word": "CH3", "probability": 0.695068359375}, {"start": 2299.77, "end": 2301.55, "word": " CH2", "probability": 0.7470703125}, {"start": 2301.55, "end": 2303.17, "word": " OH", "probability": 0.890625}, {"start": 2303.17, "end": 2304.01, "word": " وحمض", "probability": 0.56396484375}, {"start": 2304.01, "end": 2304.51, "word": " الخلب", "probability": 0.7149658203125}, {"start": 2304.51, "end": 2306.49, "word": " CH3", "probability": 0.96240234375}, {"start": 2306.49, "end": 2307.29, "word": " C", "probability": 0.630859375}, {"start": 2307.29, "end": 2307.93, "word": " O", "probability": 0.047149658203125}, {"start": 2307.93, "end": 2309.97, "word": " OH", "probability": 0.51025390625}, {"start": 2309.97, "end": 2310.75, "word": " الآن", "probability": 0.5819091796875}, {"start": 2310.75, "end": 2311.63, "word": " اتفقنا", "probability": 0.93154296875}, {"start": 2311.63, "end": 2311.93, "word": " انه", "probability": 0.705810546875}, {"start": 2311.93, "end": 2312.09, "word": " لما", "probability": 0.929443359375}, {"start": 2312.09, "end": 2312.39, "word": " بدنا", "probability": 0.81591796875}, {"start": 2312.39, "end": 2312.97, "word": " نقارن", "probability": 0.9940185546875}, {"start": 2312.97, "end": 2313.55, "word": " ال", "probability": 0.76513671875}, {"start": 2313.55, "end": 2313.75, "word": " H", "probability": 0.90234375}, {"start": 2313.75, "end": 2314.27, "word": " Plus", "probability": 0.1453857421875}, {"start": 2314.27, "end": 2315.47, "word": " مش", "probability": 0.85205078125}, {"start": 2315.47, "end": 2316.29, "word": " لازماني", "probability": 0.84873046875}, {"start": 2316.29, "end": 2317.13, "word": " بدي", "probability": 0.59637451171875}, {"start": 2317.13, "end": 2317.85, "word": " اشيلها", "probability": 0.86456298828125}, {"start": 2317.85, "end": 2318.13, "word": " و", "probability": 0.73193359375}, 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الشحن السالب على هذا ال oxygen هذا لأ له اتين", "tokens": [6027, 7649, 8032, 2655, 15040, 5016, 19913, 14407, 34105, 2423, 1975, 1829, 11536, 21136, 6027, 3555, 23758, 3714, 29245, 23328, 15844, 2423, 9169, 37893, 12174, 18513, 2288, 7251, 2655, 5016, 31747, 37495, 22653, 23758, 5551, 8592, 3555, 3224, 29739, 22653, 1975, 40448, 20449, 3224, 11331, 42213, 4724, 3794, 11933, 25708, 3224, 16712, 7649, 10632, 3714, 47432, 2407, 27884, 23032, 12610, 41950, 16572, 4587, 39896, 11242, 1211, 3224, 11933, 1829, 8592, 22807, 11331, 10943, 1211, 25124, 5016, 1863, 21136, 6027, 3555, 15844, 23758, 2423, 9169, 23758, 5296, 10721, 46740, 1975, 2655, 9957], "avg_logprob": -0.2131453870755175, "compression_ratio": 1.7692307692307692, "no_speech_prob": 0.0, "words": [{"start": 2326.8699999999994, "end": 2327.6299999999997, "word": "الان", "probability": 0.791015625}, {"start": 2327.6299999999997, "end": 2328.39, "word": " هتلاحظوا", "probability": 0.8361409505208334}, {"start": 2328.39, "end": 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" معطى", "probability": 0.9093424479166666}, {"start": 2787.78, "end": 2788.2, "word": " ال", "probability": 0.84521484375}, {"start": 2788.2, "end": 2788.74, "word": " inductive", "probability": 0.878173828125}, {"start": 2788.74, "end": 2789.16, "word": " effect", "probability": 0.93359375}, {"start": 2789.16, "end": 2790.26, "word": " الساحب", "probability": 0.9874674479166666}, {"start": 2790.26, "end": 2790.84, "word": " هو", "probability": 0.96337890625}, {"start": 2790.84, "end": 2791.26, "word": " اللى", "probability": 0.94580078125}, {"start": 2791.26, "end": 2791.9, "word": " بيزيد", "probability": 0.8797607421875}, {"start": 2791.9, "end": 2792.7, "word": " الحامضية", "probability": 0.9127197265625}, {"start": 2792.7, "end": 2793.1, "word": " ال", "probability": 0.896484375}, {"start": 2793.1, "end": 2793.6, "word": " inductive", "probability": 0.927978515625}, {"start": 2793.6, "end": 2793.98, "word": " effect", "probability": 0.923828125}, {"start": 2793.98, "end": 2794.92, "word": " المعطى", "probability": 0.9573974609375}, {"start": 2794.92, "end": 2795.44, "word": " هو", "probability": 0.96630859375}, {"start": 2795.44, "end": 2795.66, "word": " اللى", "probability": 0.979736328125}, {"start": 2795.66, "end": 2796.32, "word": " بيقلل", "probability": 0.89462890625}, {"start": 2796.32, "end": 2797.18, "word": " الحامضية", "probability": 0.98974609375}, {"start": 2797.18, "end": 2797.76, "word": " إذا", "probability": 0.722412109375}, {"start": 2797.76, "end": 2798.08, "word": " صار", "probability": 0.93505859375}, {"start": 2798.08, "end": 2798.54, "word": " عندى", "probability": 0.867919921875}, {"start": 2798.54, "end": 2799.26, "word": " electron", "probability": 0.80322265625}, {"start": 2799.26, "end": 2799.56, "word": " إيش", "probability": 0.77978515625}, {"start": 2799.56, "end": 2799.88, "word": " معنى", "probability": 0.8880208333333334}, {"start": 2799.88, "end": 2800.24, "word": " ساحب", "probability": 0.98681640625}, {"start": 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[13966, 990, 19724, 1975, 3615, 9566, 9640, 34051, 16327, 6084, 36686, 6084, 16327, 23758, 4724, 1829, 4587, 1211, 1211, 21542, 2304, 11242, 10632, 6084, 14999, 278, 4724, 1829, 11622, 25708, 21542, 2304, 11242, 10632, 44945, 9778, 39237, 43242, 29538, 13672, 5016, 19913, 3660], "avg_logprob": -0.2666903442957185, "compression_ratio": 1.4558823529411764, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2807.24, "end": 2808.36, "word": "donating", "probability": 0.3900146484375}, {"start": 2808.36, "end": 2809.84, "word": " donation", "probability": 0.1771240234375}, {"start": 2809.84, "end": 2810.76, "word": " اعطار", "probability": 0.80316162109375}, {"start": 2810.76, "end": 2812.9, "word": " أو", "probability": 0.359130859375}, {"start": 2812.9, "end": 2813.68, "word": " releasing", "probability": 0.78759765625}, {"start": 2813.68, "end": 2814.9, "word": " electron", "probability": 0.62548828125}, {"start": 2814.9, "end": 2815.56, "word": " donating", "probability": 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..ceb55e18286175388f27d17e343d2fabc5771085
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_postprocess.srt
@@ -0,0 +1,1836 @@
+1
+00:00:19,620 --> 00:00:25,000
+بسم الله الرحمن الرحيممازلنا احنا بنتكلم في موضوع
+
+2
+00:00:25,000 --> 00:00:28,880
+الأحماض ومشتقاتها المرة الماضية اتكلمنا عن ال E
+
+3
+00:00:28,880 --> 00:00:34,940
+-stars وطرق تحضيرهم وبدأنا في موضوع تفاعلات ال E
+
+4
+00:00:34,940 --> 00:00:40,040
+-stars قولنا أول شيء أن التفاعل الأساسي اللي
+
+5
+00:00:40,040 --> 00:00:44,520
+هيتكرر معنا في كل هذا الفصل للأحماض وجميع مشتقاتها
+
+6
+00:00:44,520 --> 00:00:49,020
+وتفاعل الإجدال فكان أول تفاعل أخدناه عن ال E-stars
+
+7
+00:00:49,020 --> 00:00:54,430
+ال ammonolysis يعني أن نبدل ال ORب نيتروجين
+
+8
+00:00:54,430 --> 00:01:00,210
+وبالتالي بيطلع عندنا أمد وشوفنا كيف مثلا اتكون ال
+
+9
+00:01:00,210 --> 00:01:03,870
+بنز أمد الأسيتامد ما إلى ذلك في نهاية
+
+10
+00:01:03,870 --> 00:01:09,210
+اليوكليوفيليك substitution الآن من التفاعلات
+
+11
+00:01:09,210 --> 00:01:15,190
+التانية من التفاعلات التانية لل E starsالريدكشن
+
+12
+00:01:15,190 --> 00:01:20,230
+الريدكشن بالليثيوم الومنوم هايدرايد سبق احنا
+
+13
+00:01:20,230 --> 00:01:24,810
+اتعرفنا حقيقة على الليثيوم الومنوم هايدرايد قولنا
+
+14
+00:01:24,810 --> 00:01:30,980
+الاساس اللي فيه الاساس اللي فيه هو ال H-يعني انا
+
+15
+00:01:30,980 --> 00:01:35,320
+اللى بدى استفيده من ال high drive H minus الان
+
+16
+00:01:35,320 --> 00:01:41,260
+بدكوا تتخيلوا ان ال H minus بدها تهاجم على هذا ال
+
+17
+00:01:41,260 --> 00:01:45,120
+Easter بدها تهاجم على هذا ال Easter شو بدها تعمل
+
+18
+00:01:45,120 --> 00:01:51,680
+ابدا مكان ال OR بناء على ذلك الناتج اللى بده يطلع
+
+19
+00:01:51,680 --> 00:01:57,460
+عندكم بالدرجة الأولى R C double bond O H
+
+20
+00:02:00,330 --> 00:02:06,850
+واضح؟ شيلنا ال OR و حطينا ال H طبعا إذا بتلاحظوا
+
+21
+00:02:06,850 --> 00:02:12,330
+هذا ال ناتج اللي اتكون عندى هو عبارة عن ال الديهيد
+
+22
+00:02:12,330 --> 00:02:17,570
+احنا أخدنا في chapter ال الديهيد و ال ketones ان
+
+23
+00:02:17,570 --> 00:02:22,310
+ال الديهيد و ال ketones بيتفاعلوا مع ال hydride
+
+24
+00:02:22,890 --> 00:02:27,170
+الالديهيدز بتعطيني ال primary alcohol و ال ketone
+
+25
+00:02:27,170 --> 00:02:30,890
+ال secondary alcohol بناء على ذلك هذا ال الديهيدز
+
+26
+00:02:30,890 --> 00:02:36,670
+اللي اتكون هنا مرة تانية لو اجت فاعل مع ال H minus
+
+27
+00:02:36,670 --> 00:02:42,290
+الان هذا كان E star ال E star ايش تفاعله المميز
+
+28
+00:02:42,290 --> 00:02:44,250
+Substitution
+
+29
+00:02:46,570 --> 00:02:50,930
+لما عملت substitution صار ال الديهايد ال الديهايد
+
+30
+00:02:50,930 --> 00:02:56,990
+شو تفاعله addition هم الكلمتين تحكوليش غيرهم فقط
+
+31
+00:02:56,990 --> 00:03:01,890
+بسمع هنا substitution وهنا بسمع addition طالما هذا
+
+32
+00:03:01,890 --> 00:03:06,770
+الديهايد addition طبعا هتيجي H و سيضة بال bond O
+
+33
+00:03:06,770 --> 00:03:11,090
+شو تصير O H هذا التفاعل سبق أخدنا الديهايد مع ال
+
+34
+00:03:11,090 --> 00:03:16,990
+hydride بيعمل addition والنتيجة هتكون إيشprimary
+
+35
+00:03:16,990 --> 00:03:22,810
+alcohol إذا لو أنا أخدت التفاعل بالمجمل تفاعل ال
+
+36
+00:03:22,810 --> 00:03:28,750
+eastern مع ال hydride بينتهي في النهاية ب primary
+
+37
+00:03:28,750 --> 00:03:33,090
+alcohol لكن ننتبه أنه مرورا بال aldehyde الآن هذا
+
+38
+00:03:33,090 --> 00:03:38,110
+ال aldehyde لا يفصلواضح؟ يعني بنفعل بتكون ال
+
+39
+00:03:38,110 --> 00:03:41,990
+الديهايد ع طول بلاجة اتش تانية يتفعل معاها بيصفى
+
+40
+00:03:41,990 --> 00:03:46,650
+primary alcohol عشان هيك هذا الكلام حتى نكون
+
+41
+00:03:46,650 --> 00:03:50,910
+فاهمين بالظبط إيش اللي صار معنا لكن بدل المرة ألف
+
+42
+00:03:50,910 --> 00:03:55,410
+بقول لو قلتلكوا أكمل المعادلة أكمل الفراغ بدي
+
+43
+00:03:55,410 --> 00:04:00,640
+Easterمع hydride في النهاية انا بده اشوف ال
+
+44
+00:04:00,640 --> 00:04:03,620
+primary alcohol ربما لهذا السبب انتوا شايفين
+
+45
+00:04:03,620 --> 00:04:07,580
+المعادلة في نهايتها ايش؟ primary alcohol لكن هي في
+
+46
+00:04:07,580 --> 00:04:13,440
+تفصيلها كام خطوة؟ خطوتين هي في تفصيلها خطوتين
+
+47
+00:04:13,440 --> 00:04:18,980
+إبدال كون ال aldehyde و بعدين إضافة كونت ال
+
+48
+00:04:18,980 --> 00:04:25,150
+primary alcohol واضحة الفكرة؟الان زى هذا التفاعل
+
+49
+00:04:25,150 --> 00:04:31,970
+تماما زى هذا التفاعل تماما لو يا تورا اجينا فعلنا
+
+50
+00:04:31,970 --> 00:04:35,890
+و هذا مش مكتوب عندكوا لكن بنضيفه عليكم لو اجينا
+
+51
+00:04:35,890 --> 00:04:42,590
+فعلنا ال Easter مش مع H minus مع R minus طبعا اللى
+
+52
+00:04:42,590 --> 00:04:47,890
+بنقصده في R بهدى الحالة ايش ال green yard reagent
+
+53
+00:04:47,890 --> 00:04:59,080
+ال Rمجي اكس مصدر لل R مينوس مظبوط ولا لأ هيحط R
+
+54
+00:04:59,080 --> 00:05:05,220
+مرتين فى المرة الأولى شو هيحط هنا R كوّن لك
+
+55
+00:05:05,220 --> 00:05:13,140
+الكيتون الان كمان مرة R تانية نشيل هدول ال chain
+
+56
+00:05:13,140 --> 00:05:18,820
+اللى كانوا من ال high drive نحط R وR
+
+57
+00:05:20,670 --> 00:05:26,770
+إذا في هذه الحالة التفاعل مع جرينيارد شو بيعطيني
+
+58
+00:05:26,770 --> 00:05:32,210
+تيرتشاري ألكول لأن R كانت أصلا من ال Easter وتنتين
+
+59
+00:05:32,210 --> 00:05:35,210
+متشابهات اتجوا من الجرينيارد يعني لو افترضنا مثلا
+
+60
+00:05:35,210 --> 00:05:39,990
+أن هذه كانت فنل وفعلت
+
+61
+00:05:39,990 --> 00:05:44,130
+مع إيثل ماجنيسيا مبروماي على مرتين أول مرة هيحق
+
+62
+00:05:44,130 --> 00:05:51,170
+إيثل و تاني مرة كمان إيثل إذا ال Easterفي المحصلة
+
+63
+00:05:51,170 --> 00:05:59,510
+مع الـ Greenyard reagent بدوا يعطيني تيرتشاريه
+
+64
+00:05:59,510 --> 00:06:05,710
+الكهول تماما نفس التفاعل اللي مع الهيدرايد لكن بدل
+
+65
+00:06:05,710 --> 00:06:10,210
+ما كنت بضيف H- مرتين يعني مرة بالإبدال و مرة
+
+66
+00:06:10,210 --> 00:06:21,410
+بالإضافة بحط R- مرتين واضح بحط ال R- مرتينلاحظوا
+
+67
+00:06:21,410 --> 00:06:27,030
+معي للناس اللي بيحاولوا يفهموا الأمور بصورتها
+
+68
+00:06:27,030 --> 00:06:31,730
+الكلية للناس اللي بيحاولوا يفهموا الأمور بصورتها
+
+69
+00:06:31,730 --> 00:06:38,410
+الكلية السهلة مش بالمسميات الضيقة الآن هذا Easter
+
+70
+00:06:38,410 --> 00:06:43,130
+اعملتله انا تفاعلين و اتعمت لما عرفتهم التفاعل
+
+71
+00:06:43,130 --> 00:06:43,670
+الأول
+
+72
+00:06:47,190 --> 00:06:51,550
+الـ Hydrides و أعطاني Primary Alcohols و التفاعل
+
+73
+00:06:51,550 --> 00:06:54,790
+التالي معي Green Yard Reagent و أعطاني Tertiary
+
+74
+00:06:54,790 --> 00:06:59,530
+Alcohol مرورا بالكيتون في هذه الحالة الآن هذه
+
+75
+00:06:59,530 --> 00:07:07,070
+المجموعة الـ OR مجموعة إيه شمالها؟مطرودة طردت جيبت
+
+76
+00:07:07,070 --> 00:07:14,170
+سيرتها لأ طيب يا تورا لو بعد شوية أخدنا ال acid
+
+77
+00:07:14,170 --> 00:07:19,090
+halides بمعنى ماكناش نبدأ ب E star و المجموعة
+
+78
+00:07:19,090 --> 00:07:23,670
+المطرودة OR كان عندنا acid halide كان تادي CL أو
+
+79
+00:07:23,670 --> 00:07:32,570
+PR و إجيت قولت تفاعل ال acid halide مع ال hydrides
+
+80
+00:07:32,570 --> 00:07:40,530
+شو هيعطيلي؟نفس الكلام تماماً لأنه طردت OR أو طردت
+
+81
+00:07:40,530 --> 00:07:45,310
+CL وباقي الناتج زي ما هو ال primary alcohol تفاعل
+
+82
+00:07:45,310 --> 00:07:50,170
+acid halide مع grignard reagent tertiary alcohol
+
+83
+00:07:50,170 --> 00:07:54,890
+واضح؟ شو بديفرق التفاعل إذا كانت المجموعة اللي
+
+84
+00:07:54,890 --> 00:07:59,810
+طردت OR و أخدت H طلعت على شكل alcohol ولا CL minus
+
+85
+00:07:59,810 --> 00:08:06,360
+و أخدت H طلعت على HCLواضح؟ وعشان هيك اللي بيعرف
+
+86
+00:08:06,360 --> 00:08:10,240
+أنه ال Easter بتفاعل مع ال hydrates ومع greenery
+
+87
+00:08:10,240 --> 00:08:15,880
+agent بطريقة معينة بنقوله كمان و ال acid chlorides
+
+88
+00:08:15,880 --> 00:08:21,970
+بتفاعلوا مع ال hydrates ومع greenery agentبنفس
+
+89
+00:08:21,970 --> 00:08:27,090
+الطريقة تماما مافرجش انه يكونش المجموعة المطرودة
+
+90
+00:08:27,090 --> 00:08:31,710
+هي OR ولا CL هذه مجموعة مطرودة لكن الجزء ال
+
+91
+00:08:31,710 --> 00:08:36,870
+organic اللي عندى جزء اشماله ثابت واضح الفكرة
+
+92
+00:08:49,670 --> 00:08:55,890
+الان بننتقل ل ال acid halides ال acid halides قلنا
+
+93
+00:08:55,890 --> 00:09:00,290
+عنهم مشتقات ايضا من الأحماض و لما اتكلمنا عن
+
+94
+00:09:00,290 --> 00:09:06,030
+تفاعلات الأحماض اتكلمنا عن تحضيرهم قلنا اذا أخدنا
+
+95
+00:09:06,030 --> 00:09:10,990
+ال organic acid مع ال phosphorus trichloride او ال
+
+96
+00:09:10,990 --> 00:09:20,920
+SOCl2 يهدي يهدي بيشيل ال OH و بيحطلهCL فال acid
+
+97
+00:09:20,920 --> 00:09:25,480
+بتحول الى acid chlorides طريقة التحضير طريقة ايش
+
+98
+00:09:25,480 --> 00:09:31,600
+سهلة الان لو اجينا للتسمية كيف بنسمي ال acid
+
+99
+00:09:31,600 --> 00:09:39,190
+halides احنا كان هنا في عندنا OECacid الآن بدنا
+
+100
+00:09:39,190 --> 00:09:44,930
+نغير كلمة acid بكلمة halide بدنا نغير كلمة acid
+
+101
+00:09:44,930 --> 00:09:49,790
+بكلمة halide و ال oic بنخليها oil يعني لو أخدنا
+
+102
+00:09:49,790 --> 00:09:56,510
+ethanoic acid اللي هو الحامض اللي من carbon 10 بدو
+
+103
+00:09:56,510 --> 00:10:02,350
+يصير ethanoic chloride لو هنا bromالبروميد لو
+
+104
+00:10:02,350 --> 00:10:07,770
+أخدنا ال common name تبعه acidic acid بس بنشيل ايش
+
+105
+00:10:07,770 --> 00:10:13,490
+كلمة acid و بنحط chloride فهذا المركب ايش بيصير
+
+106
+00:10:13,490 --> 00:10:19,750
+Acetyl لأ بنرجع للمجموعة YL Acetic منها Acetyl
+
+107
+00:10:19,750 --> 00:10:27,400
+واضح لأن هذه اتعرفنا عليها Acetylمتذكرينها؟ أسيتل
+
+108
+00:10:27,400 --> 00:10:33,560
+و بنكتب إيش؟ أكلورايد فالفكرة بدنا نشيل هذا جزء
+
+109
+00:10:33,560 --> 00:10:39,000
+الأسيتل و ننهب وي الهلايد أسيتل أكلورايد و منها
+
+110
+00:10:39,000 --> 00:10:43,380
+كمان سبق إن اتعرفنا على مجموعة ال بنزويل من وين
+
+111
+00:10:43,380 --> 00:10:48,920
+بنجيب ال بنزويل أكلورايد؟ لو أجينا سألناكم بنزويل
+
+112
+00:10:48,920 --> 00:10:54,300
+أكلورايد بدنا نجيبه من؟
+
+113
+00:10:55,720 --> 00:11:03,440
+البنزويك أسد C double bond O OH في ال BCL3 أو أي
+
+114
+00:11:03,440 --> 00:11:07,640
+حاجة C
+
+115
+00:11:07,640 --> 00:11:14,360
+double bond O Cl هذا إيش بده يصير بنزويل لإن هذه
+
+116
+00:11:14,360 --> 00:11:19,900
+مجموعة البنزويل فنل C double bond O بنزويل
+
+117
+00:11:19,900 --> 00:11:29,870
+إكلورايدوالبنزول كمجموعة مرات بتختصر بي زد هيك
+
+118
+00:11:29,870 --> 00:11:35,250
+بنزول إكلورايد فإذا قرأته كلمة بي زد هذا اختصار
+
+119
+00:11:35,250 --> 00:11:40,330
+إيش بنزول بنزول إكلورايد واللي علمكوا ال بنزول
+
+120
+00:11:40,330 --> 00:11:45,230
+جالكوا تذكروا أنه في إلها بنت عم بتشبهها في
+
+121
+00:11:45,230 --> 00:11:49,510
+الكتابة اللي هي بنزل إكلورايد بس ال بنزل إكلورايد
+
+122
+00:11:49,510 --> 00:11:57,190
+عبارة عنفين ال CH2 نفترض CH2 فين ال CH2 هذه مجموعة
+
+123
+00:11:57,190 --> 00:12:06,230
+البنزل مش بنزايل بنزل طبعا لو جيت سألكوا البنزل
+
+124
+00:12:06,230 --> 00:12:11,650
+كلورايد كهيلايد أي نوع من الهيلايد primary
+
+125
+00:12:11,650 --> 00:12:12,890
+alkalihilide
+
+126
+00:12:16,310 --> 00:12:21,030
+الكل واضح ماحدش ييجي يشوف هنا ال aromatic ويقول
+
+127
+00:12:21,030 --> 00:12:24,630
+عنه aromatic halide لأ هو ال aromatic halide لو
+
+128
+00:12:24,630 --> 00:12:29,370
+كانت ال CL متصلة مباشرة بالحلقة لكن طالما ال CL
+
+129
+00:12:29,370 --> 00:12:34,930
+متصلة ب CH2 إذا هذا الكل halide وبناء على ذلك بتيم
+
+130
+00:12:34,930 --> 00:12:37,970
+عليكوا التفاعلات الإبدال اللي درسناها في شبتر 6
+
+131
+00:12:37,970 --> 00:12:42,070
+ولا لأ اه فهذا بنزل chloride
+
+132
+00:12:43,690 --> 00:12:47,390
+فبفرق بنزل الكلورايد عن بنزول الكلورايد وبنزل الى
+
+133
+00:12:47,390 --> 00:12:52,650
+اختصار بيختصرها BN واضح
+
+134
+00:12:52,650 --> 00:13:01,050
+بيختصرها BN بنزل فننتبه لهدول المجموعتين هذا ال
+
+135
+00:13:01,050 --> 00:13:07,150
+بنزول الكلورايد يعني إذا بدنا نوصفه بنقول عنه انه
+
+136
+00:13:07,150 --> 00:13:16,970
+إيش انه لعينليش بنوصف بهذا الوصف القاسي؟ لأن هذا
+
+137
+00:13:16,970 --> 00:13:22,430
+اللي هو عادة يستعمل كغاز مسيل للدموع يعني بتعرفوا
+
+138
+00:13:22,430 --> 00:13:27,630
+الغازات اللي في المظاهرات وغيرها، الغازات المسيلة
+
+139
+00:13:27,630 --> 00:13:34,930
+للدموع، معظمها acid halides، ومن ضمنهاالبنزول
+
+140
+00:13:34,930 --> 00:13:40,230
+الكلورايد من ضمنها البنزول الكلورايد طبعا لو اجينا
+
+141
+00:13:40,230 --> 00:13:45,850
+نقول ايش السبب ايش السبب ان هذا البنزول الكلورايد
+
+142
+00:13:45,850 --> 00:13:53,110
+يستعمل كغاز مسيل للدموع ناخد احنا بشكل عام
+
+143
+00:13:53,110 --> 00:13:58,330
+الكلورايد و تفاعلاتها ناخد بشكل عام الكلورايد و
+
+144
+00:13:58,330 --> 00:14:03,550
+تفاعلاتها طبعا مرتان تفاعلات الكلورايد هي تفاعلات
+
+145
+00:14:05,010 --> 00:14:09,570
+الإبدال يعني ال acid chloride مجرد ما بديه يتعرض
+
+146
+00:14:09,570 --> 00:14:14,410
+للميه مجرد ما بديه يتعرض للميه بديه يفقد ال CL و
+
+147
+00:14:14,410 --> 00:14:21,470
+يحط ال OH رجع لإيش؟ لل carboxylic acid واضح؟من حد
+
+148
+00:14:21,470 --> 00:14:25,590
+ما يتعرض للميه برجع ل acid لو فعلنا مع ال ethanol
+
+149
+00:14:25,590 --> 00:14:32,050
+بدو يشيل ال CL ويحط O-ethyl برجع ل E-star لو فعلنا
+
+150
+00:14:32,050 --> 00:14:37,890
+مع ال ammonia بدو يشيل ال CL ويحط NH2 بصير أمل فزي
+
+151
+00:14:37,890 --> 00:14:41,770
+ما اتفقنا أنه من واحد بنحضر التاني الآن خلينا على
+
+152
+00:14:41,770 --> 00:14:47,480
+المعادلة الأولىخلّينا على المعادلة الأولى و نتخيل
+
+153
+00:14:47,480 --> 00:14:52,020
+مثلا أنه إحنا اللي بدين فيه ال benzoyl chloride
+
+154
+00:14:52,020 --> 00:14:54,920
+اللي هو إيش موجود فيه بدل ال acetyl chloride هنا
+
+155
+00:14:55,790 --> 00:15:00,610
+فنل سيبا بالبوند OCL هذا البيزويل الكلوري
+
+156
+00:15:00,610 --> 00:15:06,190
+بيستعملوه كغاز مصير للدموع الآن السؤال هل هو غاز
+
+157
+00:15:06,190 --> 00:15:13,310
+أصلا لأ هو مادة زيتية يعني مادة
+
+158
+00:15:15,850 --> 00:15:22,150
+بحرارة غليان فوق المية درجة مئوية لكن لما بيرموه
+
+159
+00:15:22,150 --> 00:15:27,130
+في الجو بيطلع على شكل .. بيطلع على شكل رذاذ صغير
+
+160
+00:15:27,130 --> 00:15:31,350
+فبييجي على الناس بيبدو الناس يشموه بييجي على وجههم
+
+161
+00:15:31,350 --> 00:15:37,250
+يعني عملية قذفهفي الجو بيخليه يطلع على شكل إيش؟
+
+162
+00:15:37,250 --> 00:15:42,470
+رذاذ، رذاذ صغير، الآن هذا الرذاذ الصغير اللي طلع
+
+163
+00:15:42,470 --> 00:15:49,750
+لو دخل على جسم الإنسان، هيدخل على الزور، هيجي على
+
+164
+00:15:49,750 --> 00:15:56,450
+العنين، شكل أساسي، الآن الزور و العنين فيهم مياه
+
+165
+00:15:57,990 --> 00:16:03,730
+إذا وجدت أنا هأعمل تفاعل البنزويلي كلوراي مع الميه
+
+166
+00:16:03,730 --> 00:16:09,590
+هطلع بنزويك أسد البنزويك أسد حمضه ضعيف مش منه
+
+167
+00:16:09,590 --> 00:16:16,350
+المشكلة لكن المشكلة أكتر من ال HCL ال HCL هو اللي
+
+168
+00:16:16,350 --> 00:16:22,950
+هيسبب الحرقان في العينين وفي الزور واضح ال HCL
+
+169
+00:16:22,950 --> 00:16:31,010
+الآن هذا نفسه لو إجه على الجلدمافيش منه مشكلة إذا
+
+170
+00:16:31,010 --> 00:16:34,350
+الجلد جافلكن بتعرفوا الناس اللي بيكونوا في
+
+171
+00:16:34,350 --> 00:16:39,010
+المظاهرات مرات بيكونوا عرقانين اه لو اجى معي العرق
+
+172
+00:16:39,010 --> 00:16:43,630
+و اجي اتعمل HCL بيصير الجلد يحرج لو افترضنا ان
+
+173
+00:16:43,630 --> 00:16:49,310
+البني ادم اللي كان في المظاهرة اجى عليه هو عبارة
+
+174
+00:16:49,310 --> 00:16:53,070
+عن سائل على الوجه على الجسم مافيش عنده مشكلة
+
+175
+00:16:53,070 --> 00:16:56,790
+ماحسشه مشاكل كتير غير في العنان و الزور لكن بعد
+
+176
+00:16:56,790 --> 00:17:02,630
+هيك لو راح يتوضى بالميةيغسل الإيدان و يغسل الوجه
+
+177
+00:17:02,630 --> 00:17:06,650
+بكمية ميه صغيرة بصير وشه و إيديه زي النار ليش؟ لإن
+
+178
+00:17:06,650 --> 00:17:14,530
+هو بحط ميه على رذاف بالزويل الكلورايفبتفعلوا بيطلع
+
+179
+00:17:14,530 --> 00:17:18,690
+إيش ال HCL و لذلك البني آدم اللي بده يمر بهذه
+
+180
+00:17:18,690 --> 00:17:24,670
+الظروف المفروض أنه بده يغير ملابسه بده يغسل بميه و
+
+181
+00:17:24,670 --> 00:17:29,870
+صابونة و كمية كبيرة جدا عشان يشيل هذه المادة ما
+
+182
+00:17:29,870 --> 00:17:34,450
+احنا قولنا مادة زيتية سائلة لو كان غاز كان اتبخر
+
+183
+00:17:34,450 --> 00:17:40,550
+في الهواء مع السلامة لكن هم بيرشوه و هم عارفينإنه
+
+184
+00:17:40,550 --> 00:17:43,850
+أنا بديش إياه يطير معي الهواء، إياه يظل ملزج في
+
+185
+00:17:43,850 --> 00:17:50,630
+الإنسان وفي الوجه ما هدوله اسمه فن إيش الإذاء اللي
+
+186
+00:17:50,630 --> 00:17:55,090
+بديه يرشي الغاز المسيل اللي قدوموه بديه يضر الناس
+
+187
+00:17:55,090 --> 00:17:59,790
+كذلك الحال بالمناسبة في موضوع غازات الأعصاب اللي
+
+188
+00:17:59,790 --> 00:18:06,700
+بتتدخل على الأعصاب أقوى الغازات أقلها تطيراهي كلها
+
+189
+00:18:06,700 --> 00:18:12,760
+سوائل بيسموها غازات تجاوزا، لكن ليش بيسموها غازات؟
+
+190
+00:18:12,760 --> 00:18:16,800
+لأنه بينشروها على شكل رذاذ زي الميه لما بتنشرها
+
+191
+00:18:16,800 --> 00:18:21,220
+على شكل رذاذ أو ال spray العطر لما بتنشره على شكل
+
+192
+00:18:21,220 --> 00:18:28,440
+رذاذ، واضح الفكرة؟أكثرها تبخرا، أقلها تبخرا، لأنها
+
+193
+00:18:28,440 --> 00:18:32,660
+تبقى ملازقة في الأواعي، ملازقة في الأرض، ملازقة
+
+194
+00:18:32,660 --> 00:18:36,880
+على الحيطان، على السيارات، على الشجر وبهدوء تتبخر
+
+195
+00:18:36,880 --> 00:18:42,960
+وبتطلع كميات الغاز وبتضر البني آدم، بينما أكثرها
+
+196
+00:18:42,960 --> 00:18:50,180
+تبخرابيجي الهواء بياخده، بالتالي خطورته إيش؟ بتخف،
+
+197
+00:18:50,180 --> 00:18:55,220
+فالغازات الأعصاب مشهور منها غاز A، غاز B، غاز
+
+198
+00:18:55,220 --> 00:19:04,890
+بيسموه C في Novichok في VX، مسميات كثيرةاختارها
+
+199
+00:19:04,890 --> 00:19:11,070
+اقلها ايش؟ تبخرا، بيسموها nerve gases هذه الغازات
+
+200
+00:19:11,070 --> 00:19:17,150
+تبعت الدموع شو بيسموها؟ tear gases، tear يعني دموع
+
+201
+00:19:18,030 --> 00:19:22,610
+Tear gases او لكريماتر لكريماتر الغاز المثيل
+
+202
+00:19:22,610 --> 00:19:28,490
+للدموع او tear gas فالبنزويل الكلورايد is لكريماتر
+
+203
+00:19:28,490 --> 00:19:33,950
+or is a tear gas الفكرة الأساسية منه ان هو بتطلع
+
+204
+00:19:33,950 --> 00:19:40,320
+hcl اللي بيسبب ايشالحرقان طبعا في المجتمع الدولي
+
+205
+00:19:40,320 --> 00:19:44,260
+اللي موجود اليوم المجتمع الشيطاني البنزويل
+
+206
+00:19:44,260 --> 00:19:51,060
+الكلورايد هو حقيقة أرحم ما يمكن أن يُقذَف على
+
+207
+00:19:51,060 --> 00:19:54,820
+الناس اليوم بيستعملوا غازات أعصاب و بيستعملوا
+
+208
+00:19:54,820 --> 00:20:00,520
+غازات دموع مخلوطة بغازات أعصاب بنسب قليلة و كلها
+
+209
+00:20:00,520 --> 00:20:05,440
+أشد تأثيرا من البنزويل الكلورايد يعني أشرف غازات
+
+210
+00:20:05,440 --> 00:20:12,460
+للمظاهراتالبنزوليكلوريد وما عداها أكثر شدة وأكثر
+
+211
+00:20:12,460 --> 00:20:16,960
+إجراما وعشان ذلك لاحظوا أننا لما حكينا على
+
+212
+00:20:16,960 --> 00:20:20,620
+الخواصلة ال acid helites in general قلنا noxious
+
+213
+00:20:20,620 --> 00:20:27,580
+يعني مهيجة irritating بتعمل إصابات أو جروح react
+
+214
+00:20:27,580 --> 00:20:33,660
+violently with water بتتفاعل بقوة مع الميه معطية
+
+215
+00:20:33,660 --> 00:20:41,830
+الحامض الأصلي زائدالـ HCL نيجي
+
+216
+00:20:41,830 --> 00:20:47,760
+للعائلة اللي بعدهامن ال derivatives اللي هي ال
+
+217
+00:20:47,760 --> 00:20:53,660
+acid anhydrides ال acid anhydrides بتيجي من تفاعل
+
+218
+00:20:53,660 --> 00:20:59,940
+جزيئين من الحامض مع بعضهم البعض لاحظوا في موضوع ال
+
+219
+00:20:59,940 --> 00:21:04,500
+acid anhydrides من ناحية المبدأ من ناحية المبدأ
+
+220
+00:21:04,500 --> 00:21:12,330
+هناك شبه الطالب المنتبه بموضوع ال etherبموضوع إيش
+
+221
+00:21:12,330 --> 00:21:17,470
+ال ether إذا بتتذكروا لما كنا نتكلم عن ال ether
+
+222
+00:21:17,470 --> 00:21:21,390
+قسمنا ال ethers إلى نوعين قلنا في عندنا
+
+223
+00:21:21,390 --> 00:21:28,510
+symmetrical ethers و unsymmetrical ethersإذا كانت
+
+224
+00:21:28,510 --> 00:21:33,090
+الـR و الـR زي بعض هذا سمنا إيش؟ symmetrical ether
+
+225
+00:21:33,090 --> 00:21:38,030
+و لذلك لما كنا مثلا بدنا نضاي إيثل إيثر كنا ناخد
+
+226
+00:21:38,030 --> 00:21:42,370
+الكحول مش الحامض في النهاية في OH اللي هو على سبيل
+
+227
+00:21:42,370 --> 00:21:50,450
+المثال لو أخدنا الإيثانول بنسبة 2 مع H plus هو نفس
+
+228
+00:21:50,450 --> 00:21:58,660
+الفكرة تماما إيش كان هذا يعطينا؟ إيثل أوDiethyl
+
+229
+00:21:58,660 --> 00:22:03,100
+ether من
+
+230
+00:22:03,100 --> 00:22:09,660
+الكحول و Diethyl ether is symmetrical ether رور
+
+231
+00:22:11,320 --> 00:22:14,800
+شوف نقاش ال symmetrical فالكحول بيتفاعل مع نفسه
+
+232
+00:22:14,800 --> 00:22:19,800
+جوزيق بيهاجم على التاني و بيطرده مية و بتفاعله
+
+233
+00:22:19,800 --> 00:22:25,960
+الان الكلام نفسه بتم مع ال unhydrates لكن في هذه
+
+234
+00:22:25,960 --> 00:22:32,280
+الحالة الحامض بيتفاعل مع نفسهواضح؟ في هذه الحالة
+
+235
+00:22:32,280 --> 00:22:36,680
+الحامض يتفاعل مع نفسه يعني احنا اليوم موضوعنا ال
+
+236
+00:22:36,680 --> 00:22:41,000
+unhydrates لو بدأ اركز اكثر عليها بدأ اقول تخيلوا
+
+237
+00:22:41,000 --> 00:22:47,120
+ان هذا جزيق حامض بدأ افعله مع ايش؟ مع جزيق تاني
+
+238
+00:22:47,120 --> 00:22:54,980
+اللي هو OH سيضة بال bond Oنفترض CH3 هاي Acetic
+
+239
+00:22:54,980 --> 00:23:00,040
+Acid جزئ و هاي Acetic Acid كمان جزئ هاي الجزئين
+
+240
+00:23:00,040 --> 00:23:04,740
+خلصنا واضح؟ الآن هذا بده ييجي من خلال الـ OH اللي
+
+241
+00:23:04,740 --> 00:23:10,620
+هي الـ nucleophile إهاجمها يطرد الـ OH هذا تفاعل
+
+242
+00:23:10,620 --> 00:23:15,380
+الإبدال ولا لأ؟ هذا تفاعل الإبدال بناء على ذلك لما
+
+243
+00:23:15,380 --> 00:23:18,920
+تطرد الـ OH من هنا مع الـ H هذه
+
+244
+00:23:21,660 --> 00:23:29,940
+الجزء الأول اللي مبين بالأسود هي CH3COO
+
+245
+00:23:29,940 --> 00:23:35,100
+والجزء التاني OCOO
+
+246
+00:23:36,520 --> 00:23:42,080
+CH3 هيتكون عندى الـ Symmetrical Anhydride اتكون
+
+247
+00:23:42,080 --> 00:23:46,840
+عندى الـ Symmetrical Anhydride لاحظوا انه مجموعة
+
+248
+00:23:46,840 --> 00:23:52,840
+الانهيدريد كمجموعة عبارة عن ايش C double bond O O
+
+249
+00:23:52,840 --> 00:23:57,580
+C double bond O يعني لو بدى اقول ال ether كانت O
+
+250
+00:23:57,580 --> 00:24:03,620
+متصلة بتنتين R طيب الانهيدريد هى
+
+251
+00:24:06,590 --> 00:24:13,350
+هذه ثابتة C double bond O O C double bond O هذه
+
+252
+00:24:13,350 --> 00:24:17,670
+مجموعة الانهيدريد الآن لما فعلت الحامض مع نفسه
+
+253
+00:24:17,670 --> 00:24:23,890
+صارت هذه ال R و هذه ال R زي بعض ولذلك سميت هذا
+
+254
+00:24:23,890 --> 00:24:28,530
+symmetrical anhydride الآن السؤال طب لو خلت هذه
+
+255
+00:24:28,530 --> 00:24:33,690
+مثل وهذه اثلبتصير Unsymmetrical لو خلّيت فينيل و
+
+256
+00:24:33,690 --> 00:24:40,130
+إثل Unsymmetrical طبعا بيلزمنا نسمي و نحضر ال
+
+257
+00:24:40,130 --> 00:24:43,210
+symmetrical anhydride و الunsymmetrical anhydride
+
+258
+00:24:43,210 --> 00:24:47,050
+تماما زي ما عملنا مع ال aether احنا قولنا ال
+
+259
+00:24:47,050 --> 00:24:49,870
+aether كان الكحول مع نفسه أعطاني symmetrical
+
+260
+00:24:49,870 --> 00:24:54,350
+aether الآن ال symmetrical anhydride الحامض مع
+
+261
+00:24:54,350 --> 00:24:57,350
+نفسه بنسخنه في وجود حمض
+
+262
+00:25:00,190 --> 00:25:06,170
+بش ان مش واضح بنسخنه في وجود حمض و طبعا بنتخلي
+
+263
+00:25:06,170 --> 00:25:09,610
+شروط التفاعل تسحب الميه للخارج ليش؟ لأن هذا
+
+264
+00:25:09,610 --> 00:25:13,510
+التفاعل ما عدا ذلك عكس بترد الميه تهاجمها و ترجع
+
+265
+00:25:13,510 --> 00:25:17,230
+لحمضين ولذلك اللي بيعمل unhydrate بيكون عنده طريقة
+
+266
+00:25:17,230 --> 00:25:22,160
+يسحب فيها الميه لوينل الخارج يتخلص منها طب الآن
+
+267
+00:25:22,160 --> 00:25:27,640
+هذا كيف بدي أسميه على اسم الحامض بشيل كلمة acid و
+
+268
+00:25:27,640 --> 00:25:32,880
+بكتب unhydrate يعني هذا لو سمناه ethanoic acid ال
+
+269
+00:25:32,880 --> 00:25:37,700
+unhydrate تبعه إيش بدي يصير ethanoic unhydrate طب
+
+270
+00:25:37,700 --> 00:25:43,820
+لو سمناه بال common name acetic acid إيش بدي يتسمى
+
+271
+00:25:44,770 --> 00:25:53,230
+acetic anhydride فالتسمية إن نشيل كلمة
+
+272
+00:25:53,230 --> 00:25:59,850
+acid ونحط anhydride واضح التسمية إن نشيل كلمة acid
+
+273
+00:25:59,850 --> 00:26:04,250
+ونحط إيش anhydride الحامض اللي فيه المثل هو
+
+274
+00:26:04,250 --> 00:26:12,990
+الaceticالان لو اجينا وقلنالكم لو سمحتوا ارسمولنا
+
+275
+00:26:12,990 --> 00:26:20,510
+المركب القاتل بنزوك unhydrate بنزوك
+
+276
+00:26:20,510 --> 00:26:29,870
+unhydrate اول اشي ع طول بدكم تحطولي ايش هي مجموعة
+
+277
+00:26:29,870 --> 00:26:35,670
+ال unhydrate مجموعة ال unhydrate C double bond O O
+
+278
+00:26:37,550 --> 00:26:42,130
+خلّينا نعملها هيك C double bond O تابع هذه مجموعة
+
+279
+00:26:42,130 --> 00:26:47,810
+الانهيدريد الآن إذا كانت بنزوك فنل معناه ذلك سأضع
+
+280
+00:26:47,810 --> 00:26:55,250
+على الجهتين مجموعة الفنل فنل و فنل هذه بنزوك
+
+281
+00:26:55,250 --> 00:27:00,350
+انهيدريد لما نقول أسيتك مثل و مثل المجموعة تبع
+
+282
+00:27:00,350 --> 00:27:02,550
+الأسيتك أسيتك بروبانوك
+
+283
+00:27:07,410 --> 00:27:12,490
+بدوا يكون المجموع تلاتة اه انتبهوا معاك خلصنا من
+
+284
+00:27:12,490 --> 00:27:20,310
+ال benzoic اه اه لو اتيتكن اتكتبلكم بروبانوك لأنه
+
+285
+00:27:20,310 --> 00:27:25,810
+مرات بيغلطوا الطلاب بهذه النقطة بروبانوك unhydrate
+
+286
+00:27:25,810 --> 00:27:33,950
+بدي الكربونات تلاتة هذه واحدة منهمهذه واحدة و لذلك
+
+287
+00:27:33,950 --> 00:27:38,310
+لما كان عند ال E ثانوك كنت بس حاطط ال CH3 المجموع
+
+288
+00:27:38,310 --> 00:27:45,430
+تنتين لما بدل بربانوك بدأ اكتب CH2 CH3 المجموع
+
+289
+00:27:45,430 --> 00:27:54,830
+تلاتة و هنا CH2 CH3 واضح فالمجموع تلاتة بربانوك و
+
+290
+00:27:54,830 --> 00:28:01,830
+مثلها بيوتانوك واضحةطيب الآن يا تورا الكلام شوفوا
+
+291
+00:28:01,830 --> 00:28:08,370
+كيف ما أسهل الكيميا ولا أمتعها بتفهم لحالها لو
+
+292
+00:28:08,370 --> 00:28:19,610
+إجيت و روحت كتبتلكم هنا CH3 و كتبتلكم هنا فنل و
+
+293
+00:28:19,610 --> 00:28:21,810
+قلتلكوا سموا هذا المركب
+
+294
+00:28:27,020 --> 00:28:34,240
+هذا مكون من كام حامض؟ هذا الحامض شو هو؟
+
+295
+00:28:42,280 --> 00:28:47,600
+جيد جيد هذا التردد .. هذا التردد بحل مشكلتك الناس
+
+296
+00:28:47,600 --> 00:28:50,380
+اللي سألوني عن الامتحان لأ في الامتحان مش عامليني
+
+297
+00:28:50,380 --> 00:28:55,120
+كويس لإن مصيرين ما تسمعوش نصيحتي إن إذا في الكيميا
+
+298
+00:28:55,120 --> 00:29:00,400
+ما طبقتوش و ما كتبتوش الجملة ألف مرة لن تتعلموا
+
+299
+00:29:00,400 --> 00:29:05,340
+كيميا تمام؟ لن تتعلموا كيميا هذا اللي فيه تنتين
+
+300
+00:29:05,340 --> 00:29:12,810
+اثانوك و بال common أسيتكمظبوط ولا لأ؟ هذا كحمد
+
+301
+00:29:12,810 --> 00:29:19,010
+CH3C double bond O إيش ماله؟ Acetic و هذا الفنل C
+
+302
+00:29:19,010 --> 00:29:23,430
+double bond O بنزوك و خلّيني أحطهم alphabetical
+
+303
+00:29:23,430 --> 00:29:28,190
+مين بيجي قبل ال Acetic ولا ال بنزوك؟ Acetic بنزوك
+
+304
+00:29:28,190 --> 00:29:29,850
+Unhydrate
+
+305
+00:29:31,620 --> 00:29:35,840
+واضح؟ بذكر اسم الحامضين و بحطه ممرتبين
+
+306
+00:29:35,840 --> 00:29:40,520
+alphabetically فبكون هيك اقدرت اسمي ال
+
+307
+00:29:40,520 --> 00:29:47,620
+unsymmetrical .. unhydrite .. واضح؟أسيتك بنزوك
+
+308
+00:29:47,620 --> 00:29:51,080
+أنهايدرايد طبعا واحدة ممكن تقول ممكن نسميه إيثانوك
+
+309
+00:29:51,080 --> 00:29:56,060
+ممكن موادة كاربون تنتيل إيثانوك و أجي تبدأ تكتب
+
+310
+00:29:56,060 --> 00:30:01,740
+بنزوك إيثانوك أنهايدرايد عشان تحط ال B قبل ال E
+
+311
+00:30:01,740 --> 00:30:06,920
+alphabeticalإذا إعرفنا كيف بنسمي الـ unsymmetrical
+
+312
+00:30:06,920 --> 00:30:12,680
+anhydride بذكر الحامضين alphabetically وإضافة
+
+313
+00:30:12,680 --> 00:30:18,860
+النهاية anhydride الآن إذا هذا الكلام إعرفنا كيف
+
+314
+00:30:18,860 --> 00:30:26,860
+نسميه، ضال كيف؟ انحضروه، ضال كيف انحضروه اللي
+
+315
+00:30:26,860 --> 00:30:34,400
+فاهمين الethers، إيش كنا نعمل فيهم؟نفس الفكرة
+
+316
+00:30:34,400 --> 00:30:39,520
+تماما اللي اتذكره William Sun William Sun's
+
+317
+00:30:39,520 --> 00:30:44,320
+synthesis of ethers هل يا تورا كنت بقدر انا اجي
+
+318
+00:30:44,320 --> 00:30:55,280
+اقول Methanol زائد Ethanol بالحرارة و الحامض هذا
+
+319
+00:30:55,280 --> 00:31:01,790
+كام مركب كام Ether كان يعطيليكان يعطيني تلاتة مثل
+
+320
+00:31:01,790 --> 00:31:11,130
+او مثل او اثل او اثل او مثل او اثل طب هتقول هذا ال
+
+321
+00:31:11,130 --> 00:31:16,610
+synthesis مقبول ولا لأ مرفوض في ال ethers مرفوض
+
+322
+00:31:16,610 --> 00:31:19,650
+لان انا بدي اطلع تلاتة و اقعد افصلهم طب كيف كنا
+
+323
+00:31:19,650 --> 00:31:24,810
+نعمل كنا نقول خلي واحد منهم يصير مثل او minus
+
+324
+00:31:24,810 --> 00:31:33,920
+التاني يصير اثل CLCH3 CH2 CL نبدل ال OH بCL مثلا
+
+325
+00:31:33,920 --> 00:31:39,000
+من PCL3 و بعدين نفعل هدول التنين مع بعض كانوا
+
+326
+00:31:39,000 --> 00:31:45,980
+بيعطوني بس المثل O Ethan واضح؟
+
+327
+00:31:45,980 --> 00:31:52,720
+واحد نخليه O minus والتاني نخليه CL و نخلطهم هيك
+
+328
+00:31:52,720 --> 00:32:00,300
+بيعطيني فقطناتج واحد لا غير بضحك الفكرة؟ هذه إيش
+
+329
+00:32:00,300 --> 00:32:06,500
+كان اسمها؟ طريقة William Sun لتحضير ال ether الآن
+
+330
+00:32:06,500 --> 00:32:13,220
+لما بدي أحضر ال un-symmetrical unhydride نفسها
+
+331
+00:32:13,220 --> 00:32:19,520
+تماما 100% لكن بدل ما أنا مبتدئ بكحول في ال
+
+332
+00:32:19,520 --> 00:32:25,140
+unhydride بدي أبتدئ من إيش؟من الـ Acid خلّيني أقول
+
+333
+00:32:25,140 --> 00:32:29,460
+بدي مثلا الـ Acetic Benzoic Anhydrate إذا إيش
+
+334
+00:32:29,460 --> 00:32:37,300
+الحامضين اللي بدي أبتدأ منهم Acetic Acid هاي CH3C
+
+335
+00:32:37,300 --> 00:32:44,280
+double bond O OH زائد Benzoic Acid Phenyl C double
+
+336
+00:32:44,280 --> 00:32:53,200
+bond O OH الآن لو خلطناهم بـ H Plus و Heatكم ناتج
+
+337
+00:32:53,200 --> 00:32:58,880
+الـ three products بنفع هذا الكلام مقبول اللي بعمل
+
+338
+00:32:58,880 --> 00:33:03,060
+زي هيك ايش بيكون بيشتغل غلط ال three products
+
+339
+00:33:03,060 --> 00:33:07,580
+موازية تماما لفكرة ال ethers الان واحد منهم بدنا
+
+340
+00:33:07,580 --> 00:33:11,220
+نخلي O minus نفترض هذا
+
+341
+00:33:13,840 --> 00:33:19,860
+CH3C double bond O O minus والتاني بدنا نخلي CL
+
+342
+00:33:19,860 --> 00:33:26,220
+فنل C double bond O CL هدولة لما نخلطهم بده يطلع
+
+343
+00:33:26,220 --> 00:33:33,700
+عندنا ناتج واحد فقط نرسمها CH3C double bond O O C
+
+344
+00:33:33,700 --> 00:33:41,680
+double bond O فنل على أساس أن هذه بتهاجمها و بتطرد
+
+345
+00:33:42,840 --> 00:33:48,240
+الـ Cl واضح؟ طبعا ممكن حد يقول كيف هذا بنحول ال
+
+346
+00:33:48,240 --> 00:33:54,840
+acid ال acid ل O minus بالتفاعل مع N A O H حمزاد
+
+347
+00:33:54,840 --> 00:33:55,680
+قاعدة
+
+348
+00:33:59,270 --> 00:34:03,890
+NA قدش كتير عليه دائما مستعمل أقل شغلة مع ال NA
+
+349
+00:34:03,890 --> 00:34:08,170
+هياعمل حريقة هيكون التفاعل violent مع ال NA و لا
+
+350
+00:34:08,170 --> 00:34:14,470
+مع ال NA او ال NA قدش كتير عليه هيعمل حريقةمع ال N
+
+351
+00:34:14,470 --> 00:34:17,470
+A و N A H ماشي الحمض يتفاعل مع ال N A و N A H
+
+352
+00:34:17,470 --> 00:34:21,570
+الكحول هداج زنبه ع جنبه مكانش يتفاعل مع ال N A و N
+
+353
+00:34:21,570 --> 00:34:26,970
+A H ولذلك استعملتله N A و N A H لكن الحمض بتفاعل
+
+354
+00:34:26,970 --> 00:34:31,670
+مع ال N A و N A H ولا لأ بتفاعل و هذا بي سي ال
+
+355
+00:34:31,670 --> 00:34:37,050
+اثنين اذا حامض طبعا واحدة ممكن تسأل انواع نخلي O
+
+356
+00:34:37,050 --> 00:34:42,970
+minus وانواع C L مش فارقفى ال ethers كان فارق ال
+
+357
+00:34:42,970 --> 00:34:48,330
+CL بنا نخليه ال primary هنا مش فارق واحد بخليه O
+
+358
+00:34:48,330 --> 00:34:55,210
+minus والتانى بخليه CL و بعدين بفعلهم هيطلع عندى
+
+359
+00:34:55,210 --> 00:35:01,650
+ال unsymmetrical anhydride
+
+360
+00:35:01,650 --> 00:35:10,810
+واضحة الفكرةوهي طريقة تحضير الـ Acidic Benzoic
+
+361
+00:35:10,810 --> 00:35:16,290
+Anhydride فيه أوضح من هيك؟ مرة جيبناها سؤال هذا
+
+362
+00:35:16,290 --> 00:35:20,230
+المركب، قولنا للطلاب سمي المركب التالي واذكر طريقة
+
+363
+00:35:20,230 --> 00:35:27,250
+تحضيره، ما جوابوش عشرة في المية، بتصدقوا؟ ليش؟لأنه
+
+364
+00:35:27,250 --> 00:35:31,370
+مابيطبقوش مابيعدوش الكتابة خمس مرات لحد ما إيدهم
+
+365
+00:35:31,370 --> 00:35:36,830
+تتعود على الكيميا ولذلك لو بدكوا تطلعوا على سبيل
+
+366
+00:35:36,830 --> 00:35:42,270
+المثال هذا الكلام جيد إنه الكل يسمعوا حتى الناس
+
+367
+00:35:42,270 --> 00:35:46,470
+اللي بيشاهدوا الفيديو الطالب اللي مابيكتب كيميا
+
+368
+00:35:46,470 --> 00:35:53,090
+كتيرما بيكتب كيميا كتير هذا فن بحاجة إلى تدريب
+
+369
+00:35:53,090 --> 00:36:00,310
+ولذلك قد تستغربوا انه لما جيبنالكم بنزين وقلنا
+
+370
+00:36:00,310 --> 00:36:06,890
+حطوا عليها بس مجموعة إثل زي هيك يعني كتبنا CH3
+
+371
+00:36:06,890 --> 00:36:15,070
+CH2Cl في وجود الـFeCl3 تمام؟
+
+372
+00:36:16,720 --> 00:36:24,060
+الآن بنسبة 70% منكم عندهم فهم ولكن عندهم خطأ في
+
+373
+00:36:24,060 --> 00:36:28,300
+التنفيذ لأنهم مادربوش إيديهم يكتبوا كان الجواب
+
+374
+00:36:28,300 --> 00:36:40,280
+اللي كتب بهذا الشكل الان
+
+375
+00:36:40,280 --> 00:36:44,720
+انتوا بتحكوا لكن انا عندى إحصائيةأنا بعمل إحصائية
+
+376
+00:36:44,720 --> 00:36:49,560
+كيف بتكتبوا، 70% منكم كتبوا بهذا الشكل، لا هذه ال
+
+377
+00:36:49,560 --> 00:36:53,780
+carbon أربع روابط ولا هذه أربع روابط ولا محل مكانة
+
+378
+00:36:53,780 --> 00:36:59,280
+ال CL عملوا التفاعل كل هذه الأشياء ليش؟ لأنه مافيش
+
+379
+00:36:59,280 --> 00:37:05,900
+تطبيق، الأصل أنه هنا نكون كاتبين CH2 CH3
+
+380
+00:37:07,280 --> 00:37:14,480
+الان لما جيبنالكم فاعله مع CH3CWOCL الاصل بدكوا
+
+381
+00:37:14,480 --> 00:37:23,960
+تحطه من هنا من محل ال CL يعني تحطه CWOCL
+
+382
+00:37:23,960 --> 00:37:31,560
+ربما خمسين في المية منكم حطوا هنا CWO وحطوا هنا
+
+383
+00:37:31,560 --> 00:37:40,360
+CH3 بهذا الشكل بهذا الشكللا تحزروا روسكو و إلا
+
+384
+00:37:40,360 --> 00:37:44,380
+بجيب الورق و بفرجيكوا إياه ليش؟ لأنه ماصارش عندكم
+
+385
+00:37:44,380 --> 00:37:49,140
+تطبيق اللي بيدخل على كلية علمية جامعية بده يتعب و
+
+386
+00:37:49,140 --> 00:37:54,980
+هو بيطبق و يكتب كتير و يتعب كتير عشان يشتغل صح لكن
+
+387
+00:37:54,980 --> 00:37:59,020
+هذا الكلام خمسين في المية يمكن كتبوه من الطالبات و
+
+388
+00:37:59,020 --> 00:38:02,440
+هذا الكلام اللي كان تول سبعين في المية من الطالبات
+
+389
+00:38:02,440 --> 00:38:07,760
+كتبوه ليش؟ لأنهم بدهم يقرؤوا ال organic قراءة
+
+390
+00:38:08,820 --> 00:38:14,640
+أدبيات الرافعي الرافعي يقرأ استلقاء و ال organic
+
+391
+00:38:14,640 --> 00:38:28,580
+تقرأ كتابة و تطبيقا واضحة الفكرة هاي
+
+392
+00:38:28,580 --> 00:38:36,210
+ال acid anhydride الان لاحظوا من الأحماضاللي
+
+393
+00:38:36,210 --> 00:38:42,090
+درسناها ال die acids يعني يكون عندى حامضين في نفس
+
+394
+00:38:42,090 --> 00:38:49,250
+الجزء أخدنا لما يكون عندى أربع ذرات كربون الحامض
+
+395
+00:38:49,250 --> 00:38:53,750
+اللى بيكون بال sis form اسمه malic acid و اللى بال
+
+396
+00:38:53,750 --> 00:39:01,690
+transform يهودا ايوة اللى بال transform زى هذا شو
+
+397
+00:39:01,690 --> 00:39:02,450
+اسمه؟
+
+398
+00:39:15,400 --> 00:39:21,740
+لاحظوا أفضل واحدة فيكم برضه نتيجة عدم التطبيق جابت
+
+399
+00:39:21,740 --> 00:39:26,200
+زرع من الإسم وأكيد لو كانت متحة هيكون خطأ جالت
+
+400
+00:39:26,200 --> 00:39:31,680
+فورمك لكن تأكيدا والمحاضرات ابتشرت عليكم اسمه
+
+401
+00:39:31,680 --> 00:39:39,850
+fumaric acidmalic acid و fumaric acid شوفتوا كيف
+
+402
+00:39:39,850 --> 00:39:44,830
+التطبيق بيفرق عندنا أكيد لو ارجعنا أول ما أخدنا ال
+
+403
+00:39:44,830 --> 00:39:49,130
+die acids حكيناهم و قولنا واحد بناخده من التفاح و
+
+404
+00:39:49,130 --> 00:39:54,650
+التاني من الأغنام و كل هذا الكلام لكن كم مرة كتبت
+
+405
+00:39:54,650 --> 00:39:58,990
+أنا شكل ال malic acid و ال fumaric acid ولا مرة
+
+406
+00:39:58,990 --> 00:40:05,280
+كيف بدي أتذكرهممش هتذكرهم الان لاحظوا معي المالية
+
+407
+00:40:05,280 --> 00:40:12,040
+كان SIS الفيومارك كانت Trans يعني كان في مجمعتين
+
+408
+00:40:12,040 --> 00:40:18,810
+ال OHSمجمعتين ال acid بعاد عن بعض الان هذا مركب ال
+
+409
+00:40:18,810 --> 00:40:24,370
+cess لو سخنته انا عند 135 حامض بتفعلها حامض هذه
+
+410
+00:40:24,370 --> 00:40:29,210
+بتيجي هان و بتطرد ال OH بتعطيني unhydrate لما بدي
+
+411
+00:40:29,210 --> 00:40:34,930
+اسميه شو هسميه مليك unhydrate مليك قولنا كمان و
+
+412
+00:40:34,930 --> 00:40:38,410
+أكدنا انه بنستعمل ال E اللي هي تعبير على ال alkyl
+
+413
+00:40:38,410 --> 00:40:45,220
+وقولنا الملكحمض تاني بدون ال E حامض تاني ملك acid
+
+414
+00:40:45,220 --> 00:40:52,660
+موجود ومليك acid موجود واضح؟ الان لو اجت واحدة
+
+415
+00:40:52,660 --> 00:40:59,880
+سخنت هذا الحامض بالحرارة ايش رأيكوا هيصير؟ هيعمل
+
+416
+00:40:59,880 --> 00:41:04,540
+unhydrate مع نفسه؟
+
+417
+00:41:04,540 --> 00:41:09,720
+يعني هذه تهاجم هنا؟ ليش؟
+
+418
+00:41:10,730 --> 00:41:16,310
+لأن هم بعاد .. لأن هم بعاد .. طيب بتقولون ما بتلف
+
+419
+00:41:16,310 --> 00:41:21,030
+حوالين ال double bond .. الدوران حوالين ال double
+
+420
+00:41:21,030 --> 00:41:28,300
+bond .. ممنوع .. ولذلك تسخين الماليك أسدبيعمل
+
+421
+00:41:28,300 --> 00:41:33,920
+unhydrate تسخين لثيوميرك أسد بيعملش unhydrate فلو
+
+422
+00:41:33,920 --> 00:41:37,920
+انتوا اتطلعتوا في كاتالوجي الكيميا بتلاقوا مركب
+
+423
+00:41:37,920 --> 00:41:42,580
+اسمه مليك unhydrate بس بتلاقوش مركب اسمه ثيوميرك
+
+424
+00:41:42,580 --> 00:41:49,100
+unhydrate لأن مجمعتين ال OHS ابعاد عن بعضهم البعض
+
+425
+00:41:49,100 --> 00:41:54,890
+واضح فمش هيصل يتفاعلوا مع بعضهم البعضالان نفس
+
+426
+00:41:54,890 --> 00:42:01,430
+الفكرة تماما لو اجيت على مجموعتين acid موجودات على
+
+427
+00:42:01,430 --> 00:42:09,450
+بنزينة قولت هدول المجموعتين كيف يمكن ان يوجدوا يا
+
+428
+00:42:09,450 --> 00:42:16,170
+اما واحد اتنين اورثو يا واحد تلاتة ميتا يا واحد
+
+429
+00:42:16,170 --> 00:42:21,520
+اربعة باراتمام يعني غير هذا اللي موجود المجموعتين
+
+430
+00:42:21,520 --> 00:42:26,580
+على واحد اتنين ايضا موجود انه يكونوا مجموعتين ال
+
+431
+00:42:26,580 --> 00:42:34,900
+acid COOH و COOH على نمرة واحد واحد اتنين تلاتة
+
+432
+00:42:34,900 --> 00:42:40,860
+وموجود كمان انهم يكونوا على نمرة واحد واربعة COOH
+
+433
+00:42:40,860 --> 00:42:48,750
+مثلا و COOH واحد اتنين تلاتة اربعةهدولة التلت
+
+434
+00:42:48,750 --> 00:42:54,170
+أحماض موجودين و سمناهم اللي على ال Ortho سمناه
+
+435
+00:42:54,170 --> 00:43:00,950
+Phthalic Acid و اللي على ال NETA Isophthalic Acid
+
+436
+00:43:00,950 --> 00:43:05,910
+و اللي على البارا Terephthalic Acid و قولنالكوا
+
+437
+00:43:05,910 --> 00:43:11,010
+احفظوهم الآن لو يا ترى إجينا نسخن هدولة التلاتة
+
+438
+00:43:11,010 --> 00:43:17,070
+مين فكركوا منهم اللي ممكن يعمل Unhydrate؟الأورثو
+
+439
+00:43:17,070 --> 00:43:22,990
+ولا النيتا ولا البارا بس الأورثو لأن هدول بعاد عن
+
+440
+00:43:22,990 --> 00:43:29,090
+بعض مابيجوش فهذا بيعملش أنهيدريد ال isothelic acid
+
+441
+00:43:29,090 --> 00:43:33,010
+و ال teraphthalic acid بيعملش أنهيدريد هذا بيعمل
+
+442
+00:43:33,010 --> 00:43:39,150
+أنهيدريد لو قلنالكوا أرسم الانهيدريد الناتجهي
+
+443
+00:43:39,150 --> 00:43:45,690
+البنزينة عندى C double bond O و هنا C double bond
+
+444
+00:43:45,690 --> 00:43:52,570
+O و بينهم O هى مجموعة الانهيدريد C double bond O O
+
+445
+00:43:52,570 --> 00:43:58,850
+C double bond O و هذا بيصير ايش اسمه افثالك
+
+446
+00:43:58,850 --> 00:44:01,810
+انهيدريد
+
+447
+00:44:04,120 --> 00:44:12,560
+أفثالك أنهايدرايد واضح طبعا
+
+448
+00:44:12,560 --> 00:44:16,960
+هذه ال mix انهايدرايد حكينا عنها كيف بتتحضر واحد O
+
+449
+00:44:16,960 --> 00:44:20,520
+minus والتاني CL وهي تسميتهم acidic benzoic
+
+450
+00:44:20,520 --> 00:44:22,060
+anhydride حكينا عنه
+
+451
+00:44:29,520 --> 00:44:36,740
+طبعا لو كنا بدنا ندرس تفاعلات الانهيدريد واحدة
+
+452
+00:44:36,740 --> 00:44:40,340
+تختصر تفاعلات الانهيدريد بكلمة شو هتقول عنهم
+
+453
+00:44:40,340 --> 00:44:47,660
+substitution reaction طبعا ال substitution بده يتم
+
+454
+00:44:47,660 --> 00:44:56,020
+هان و نطرد كل هذه المجموعة بتخرج على شكل إيشحمض مع
+
+455
+00:44:56,020 --> 00:45:00,360
+الأموليا بيعطيني أمد مثلا مع الكحول بيعطيني Easter
+
+456
+00:45:00,360 --> 00:45:05,240
+مع الميه بيعطيني ال acid التاني و هكذا من هذه
+
+457
+00:45:05,240 --> 00:45:09,960
+النقطة ان شاء الله المرة القادمة بنبدأ بنأكد عليها
+
+458
+00:45:09,960 --> 00:45:14,960
+بس بتكونوا تدربتوا عليها تفاعلات ال acid
+
+459
+00:45:14,960 --> 00:45:18,000
+anhydrides بال substitution بالإبدال
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..8a06adf79a4985df8d654ffe7d661b3938145a66
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_raw.json
@@ -0,0 +1 @@
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"end": 1244.39, "text": "الـ HCL نيجي للعائلة اللي بعدها", "tokens": [6027, 39184, 389, 22458, 8717, 1829, 7435, 1829, 24976, 3615, 16373, 37977, 13672, 1829, 45030, 3215, 11296], "avg_logprob": -0.2879774272441864, "compression_ratio": 0.9310344827586207, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1236.29, "end": 1236.69, "word": "الـ", "probability": 0.8759765625}, {"start": 1236.69, "end": 1237.25, "word": " HCL", "probability": 0.5880126953125}, {"start": 1237.25, "end": 1241.83, "word": " نيجي", "probability": 0.77044677734375}, {"start": 1241.83, "end": 1243.55, "word": " للعائلة", "probability": 0.8154296875}, {"start": 1243.55, "end": 1243.75, "word": " اللي", "probability": 0.858642578125}, {"start": 1243.75, "end": 1244.39, "word": " بعدها", "probability": 0.7568359375}], "temperature": 1.0}, {"id": 54, "seek": 127032, "start": 1245.2, "end": 1270.32, "text": "من ال derivatives اللي هي ال acid anhydrides ال acid anhydrides بتيجي من تفاعل جزيئين من الحامض مع بعضهم البعض لاحظوا في موضوع ال acid anhydrides من ناحية المبدأ من ناحية المبدأ هناك شبه الطالب المنتبه بموضوع ال ether", "tokens": [27842, 2423, 33733, 13672, 1829, 39896, 2423, 8258, 18931, 6655, 81, 1875, 2423, 8258, 18931, 6655, 81, 1875, 39894, 1829, 7435, 1829, 9154, 6055, 5172, 995, 30241, 10874, 11622, 1829, 19986, 9957, 9154, 21542, 10943, 11242, 20449, 45030, 11242, 16095, 29739, 3615, 11242, 20193, 5016, 19913, 14407, 8978, 3714, 2407, 11242, 45367, 2423, 8258, 18931, 6655, 81, 1875, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 34105, 4117, 13412, 3555, 3224, 41950, 6027, 3555, 9673, 29399, 3555, 3224, 4724, 2304, 2407, 11242, 45367, 2423, 37096], "avg_logprob": -0.10011888773221037, "compression_ratio": 1.9096045197740112, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1245.2, "end": 1245.62, "word": "من", "probability": 0.7158203125}, {"start": 1245.62, "end": 1246.48, "word": " ال", "probability": 0.73974609375}, 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1349.82, "text": "شوف نقاش ال symmetrical فالكحول بيتفاعل مع نفسه جوزيق بيهاجم على التاني و بيطرده مية و بتفاعله الان الكلام نفسه بتم مع ال unhydrates لكن في هذه الحالة الحامض بيتفاعل مع نفسه", "tokens": [8592, 38688, 8717, 4587, 33599, 2423, 40360, 6156, 6027, 4117, 5016, 12610, 4724, 36081, 5172, 995, 30241, 20449, 8717, 36178, 3224, 10874, 2407, 11622, 1829, 4587, 4724, 1829, 3224, 26108, 2304, 15844, 16712, 7649, 1829, 4032, 4724, 1829, 9566, 2288, 3215, 3224, 3714, 10632, 4032, 39894, 5172, 995, 30241, 3224, 2423, 7649, 2423, 28820, 10943, 8717, 36178, 3224, 4724, 39237, 20449, 2423, 517, 21591, 12507, 44381, 8978, 29538, 21542, 6027, 3660, 21542, 10943, 11242, 4724, 36081, 5172, 995, 30241, 20449, 8717, 36178, 3224], "avg_logprob": -0.22730655134433791, "compression_ratio": 1.7396449704142012, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1331.32, "end": 1331.62, "word": "شوف", "probability": 0.6883544921875}, {"start": 1331.62, "end": 1331.88, "word": " نقاش", 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"text": "نفترض CH3 هاي Acetic Acid جزئ و هاي Acetic Acid كمان جزئ هاي الجزئين خلصنا واضح؟ الآن هذا بده ييجي من خلال الـ OH اللي هي الـ nucleophile إهاجمها يطرد الـ OH هذا تفاعل الإبدال ولا لأ؟ هذا تفاعل الإبدال بناء على ذلك لما تطرد الـ OH من هنا مع الـ H هذه", "tokens": [1863, 5172, 2655, 43042, 5995, 18, 8032, 47302, 5097, 3532, 5097, 327, 10874, 11622, 19986, 4032, 8032, 47302, 5097, 3532, 5097, 327, 9122, 2304, 7649, 10874, 11622, 19986, 8032, 47302, 25724, 11622, 19986, 9957, 16490, 1211, 9381, 8315, 4032, 46958, 5016, 22807, 6024, 48506, 23758, 47525, 3224, 7251, 1829, 7435, 1829, 9154, 16490, 1211, 6027, 2423, 39184, 13931, 13672, 1829, 39896, 2423, 39184, 14962, 49242, 11933, 3224, 26108, 2304, 11296, 7251, 9566, 2288, 3215, 2423, 39184, 13931, 23758, 6055, 5172, 995, 30241, 33688, 44510, 6027, 49429, 5296, 10721, 22807, 23758, 6055, 5172, 995, 30241, 33688, 44510, 6027, 44945, 16606, 15844, 29910, 23275, 5296, 15042, 6055, 9566, 2288, 3215, 2423, 39184, 13931, 9154, 34105, 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الـ Symmetrical Anhydride اتكون عندى الـ Symmetrical Anhydride لاحظوا انه مجموعة الانهيدريد كمجموعة عبارة عن ايش C double bond O O C double bond O يعني لو بدى اقول ال ether كانت O متصلة بتنتين R طيب الانهيدريد هى", "tokens": [5462, 18, 39896, 2655, 30544, 43242, 7578, 2423, 39184, 3902, 2174, 32283, 1107, 21591, 25502, 1975, 2655, 30544, 43242, 7578, 2423, 39184, 3902, 2174, 32283, 23574, 6655, 25502, 20193, 5016, 19913, 14407, 16472, 3224, 3714, 7435, 2304, 2407, 27884, 2423, 7649, 3224, 25708, 2288, 25708, 9122, 2304, 7435, 2304, 2407, 27884, 6225, 3555, 9640, 3660, 18871, 1975, 1829, 8592, 383, 3834, 6086, 422, 422, 383, 3834, 6086, 422, 37495, 22653, 45164, 47525, 7578, 1975, 39648, 2423, 37096, 25961, 2655, 422, 44650, 36520, 3660, 39894, 29399, 9957, 497, 23032, 1829, 3555, 2423, 7649, 3224, 25708, 2288, 25708, 8032, 7578], "avg_logprob": -0.2877209662186979, "compression_ratio": 1.7085427135678393, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1416.52, "end": 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"probability": 0.568359375}, {"start": 1432.84, "end": 1433.32, "word": " C", "probability": 0.81884765625}, {"start": 1433.32, "end": 1433.56, "word": " double", "probability": 0.90771484375}, {"start": 1433.56, "end": 1433.96, "word": " bond", "probability": 0.982421875}, {"start": 1433.96, "end": 1434.34, "word": " O", "probability": 0.97705078125}, {"start": 1434.34, "end": 1434.98, "word": " يعني", "probability": 0.874267578125}, {"start": 1434.98, "end": 1435.06, "word": " لو", "probability": 0.82568359375}, {"start": 1435.06, "end": 1435.26, "word": " بدى", "probability": 0.69677734375}, {"start": 1435.26, "end": 1435.48, "word": " اقول", "probability": 0.8994140625}, {"start": 1435.48, "end": 1436.04, "word": " ال", "probability": 0.89306640625}, {"start": 1436.04, "end": 1436.48, "word": " ether", "probability": 0.426513671875}, {"start": 1436.48, "end": 1437.42, "word": " كانت", "probability": 0.967529296875}, {"start": 1437.42, "end": 1437.58, "word": " O", "probability": 0.8623046875}, {"start": 1437.58, "end": 1438.26, "word": " متصلة", "probability": 0.9563802083333334}, {"start": 1438.26, "end": 1438.8, "word": " بتنتين", "probability": 0.7216796875}, {"start": 1438.8, "end": 1439.12, "word": " R", "probability": 0.94189453125}, {"start": 1439.12, "end": 1439.62, "word": " طيب", "probability": 0.771484375}, {"start": 1439.62, "end": 1440.86, "word": " الانهيدريد", "probability": 0.8788248697916666}, {"start": 1440.86, "end": 1443.62, "word": " هى", "probability": 0.6357421875}], "temperature": 1.0}, {"id": 63, "seek": 147015, "start": 1446.59, "end": 1470.15, "text": "هذه ثابتة C double bond O O C double bond O هذه مجموعة الانهيدريد الآن لما فعلت الحامض مع نفسه صارت هذه ال R و هذه ال R زي بعض ولذلك سميت هذا symmetrical anhydride الآن السؤال طب لو خلت هذه مثل وهذه اثل", "tokens": [3224, 24192, 38637, 16758, 2655, 3660, 383, 3834, 6086, 422, 422, 383, 3834, 6086, 422, 29538, 3714, 7435, 2304, 2407, 27884, 2423, 7649, 3224, 25708, 2288, 25708, 6024, 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من هنا من محل ال CL يعني تحطه CWOCL ربما خمسين في المية منكم حطوا هنا CWO وحطوا هنا CH3 بهذا الشكل بهذا الشكل", "tokens": [6027, 7649, 5296, 15042, 10874, 1829, 3555, 8315, 23275, 2304, 6156, 995, 30241, 3224, 20449, 5995, 18, 34, 54, 46, 22458, 2423, 33546, 1211, 47525, 4117, 14407, 6055, 5016, 9566, 3224, 9154, 34105, 9154, 3714, 5016, 1211, 2423, 12855, 37495, 22653, 6055, 5016, 9566, 3224, 383, 54, 46, 22458, 12602, 3555, 15042, 16490, 2304, 3794, 9957, 8978, 9673, 10632, 9154, 24793, 11331, 9566, 14407, 34105, 383, 54, 46, 4032, 5016, 9566, 14407, 34105, 5995, 18, 39627, 15730, 25124, 28820, 39627, 15730, 25124, 28820], "avg_logprob": -0.2070312476938679, "compression_ratio": 1.7261146496815287, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2227.28, "end": 2227.9, "word": "الان", "probability": 0.77734375}, {"start": 2227.9, "end": 2228.38, "word": " لما", "probability": 0.826171875}, {"start": 2228.38, "end": 2229.1, "word": " جيبنالكم", "probability": 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acids حكيناهم و قولنا واحد بناخده من التفاح و التاني من الأغنام و كل هذا الكلام لكن كم مرة كتبت أنا شكل ال malic acid و ال fumaric acid ولا مرة كيف بدي أتذكرهم", "tokens": [5579, 299, 8258, 4032, 43845, 289, 299, 8258, 13412, 38688, 2655, 14407, 9122, 33911, 16712, 9566, 21292, 4587, 4724, 33911, 2288, 4587, 43242, 8315, 5551, 4117, 25708, 45164, 1975, 47341, 3615, 8315, 5551, 12610, 19446, 5551, 9778, 3215, 8315, 2423, 978, 21667, 11331, 4117, 1829, 8315, 16095, 4032, 12174, 12610, 8315, 36764, 24401, 44945, 47283, 3215, 3224, 9154, 16712, 5172, 39319, 4032, 16712, 7649, 1829, 9154, 16247, 17082, 8315, 2304, 4032, 28242, 23758, 2423, 28820, 10943, 44381, 9122, 2304, 3714, 25720, 9122, 2655, 3555, 2655, 41850, 13412, 28820, 2423, 2806, 299, 8258, 4032, 2423, 43845, 289, 299, 8258, 49429, 3714, 25720, 9122, 33911, 4724, 16254, 5551, 2655, 8848, 37983, 16095], "avg_logprob": -0.2156531542271107, "compression_ratio": 1.8318181818181818, "no_speech_prob": 5.960464477539063e-08, "words": 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"الأورثو", "probability": 0.756494140625}, {"start": 2597.07, "end": 2597.67, "word": " ولا", "probability": 0.751953125}, {"start": 2597.67, "end": 2598.45, "word": " النيتا", "probability": 0.711273193359375}, {"start": 2598.45, "end": 2598.83, "word": " ولا", "probability": 0.95703125}, {"start": 2598.83, "end": 2599.35, "word": " البارا", "probability": 0.83349609375}, {"start": 2599.35, "end": 2600.69, "word": " بس", "probability": 0.809326171875}, {"start": 2600.69, "end": 2601.39, "word": " الأورثو", "probability": 0.8792724609375}, {"start": 2601.39, "end": 2601.81, "word": " لأن", "probability": 0.746826171875}, {"start": 2601.81, "end": 2602.15, "word": " هدول", "probability": 0.87451171875}, {"start": 2602.15, "end": 2602.77, "word": " بعاد", "probability": 0.90576171875}, {"start": 2602.77, "end": 2602.99, "word": " عن", "probability": 0.98876953125}, {"start": 2602.99, "end": 2603.57, "word": " بعض", "probability": 0.989013671875}, {"start": 2603.57, "end": 2604.61, "word": " مابيجوش", "probability": 0.843017578125}, {"start": 2604.61, "end": 2605.37, "word": " فهذا", "probability": 0.80810546875}, {"start": 2605.37, "end": 2606.09, "word": " بيعملش", "probability": 0.94716796875}, {"start": 2606.09, "end": 2607.07, "word": " أنهيدريد", "probability": 0.6462890625}, {"start": 2607.07, "end": 2607.61, "word": " ال", "probability": 0.73681640625}, {"start": 2607.61, "end": 2608.65, "word": " isothelic", "probability": 0.6292724609375}, {"start": 2608.65, "end": 2609.09, "word": " acid", "probability": 0.92919921875}, {"start": 2609.09, "end": 2609.53, "word": " و", "probability": 0.66357421875}, {"start": 2609.53, "end": 2609.69, "word": " ال", "probability": 0.6005859375}, {"start": 2609.69, "end": 2610.55, "word": " teraphthalic", "probability": 0.549346923828125}, {"start": 2610.55, "end": 2610.83, "word": " acid", "probability": 0.97021484375}, {"start": 2610.83, "end": 2611.37, "word": " بيعملش", "probability": 0.9291015625}, {"start": 2611.37, 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"word": " عنها", "probability": 0.98388671875}, {"start": 2654.64, "end": 2654.86, "word": " كيف", "probability": 0.94921875}, {"start": 2654.86, "end": 2655.72, "word": " بتتحضر", "probability": 0.848974609375}, {"start": 2655.72, "end": 2656.76, "word": " واحد", "probability": 0.854736328125}, {"start": 2656.76, "end": 2656.96, "word": " O", "probability": 0.357177734375}, {"start": 2656.96, "end": 2657.36, "word": " minus", "probability": 0.23291015625}, {"start": 2657.36, "end": 2657.88, "word": " والتاني", "probability": 0.77734375}, {"start": 2657.88, "end": 2658.2, "word": " CL", "probability": 0.462158203125}, {"start": 2658.2, "end": 2658.72, "word": " وهي", "probability": 0.5098876953125}, {"start": 2658.72, "end": 2659.44, "word": " تسميتهم", "probability": 0.8685302734375}, {"start": 2659.44, "end": 2659.9, "word": " acidic", "probability": 0.476318359375}, {"start": 2659.9, "end": 2660.52, "word": " benzoic", "probability": 0.6573893229166666}, {"start": 2660.52, "end": 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diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..029ffdf816eca3c352289ce77f625d396a1992f9
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk_raw.json
@@ -0,0 +1 @@
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"seek": 12450, "start": 107.98, "end": 124.5, "text": "الـ Ethylene اللى انتوا شايفينه بهذا الشكل اكيد لو طلعنا على الصيغة العامة تبعته C2H4 CNH2N لما احنا عملنا ال double bond حذفنا مقابلها ذرتين هيدروجين", "tokens": [6027, 39184, 10540, 46830, 13672, 7578, 16472, 2655, 14407, 13412, 995, 33911, 9957, 3224, 39627, 15730, 25124, 28820, 1975, 4117, 25708, 45164, 23032, 1211, 3615, 8315, 15844, 31767, 1829, 17082, 3660, 18863, 10943, 3660, 6055, 3555, 34268, 3224, 383, 17, 39, 19, 14589, 39, 17, 45, 5296, 15042, 1975, 5016, 8315, 6225, 42213, 8315, 2423, 3834, 6086, 11331, 8848, 5172, 8315, 3714, 4587, 16758, 1211, 11296, 29910, 43500, 9957, 8032, 25708, 2288, 29245, 9957], "avg_logprob": -0.16614583492279053, "compression_ratio": 1.3932584269662922, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 107.98, "end": 108.38, "word": "الـ", "probability": 0.45220947265625}, {"start": 108.38, "end": 108.9, "word": " Ethylene", "probability": 0.72900390625}, {"start": 108.9, "end": 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{"start": 506.37, "end": 506.79, "word": " بيعمل", "probability": 0.8594970703125}, {"start": 506.79, "end": 507.27, "word": " flipping", "probability": 0.7255859375}, {"start": 507.27, "end": 507.77, "word": " زى", "probability": 0.9326171875}, {"start": 507.77, "end": 508.41, "word": " الشمسية", "probability": 0.9920654296875}, {"start": 508.41, "end": 508.57, "word": " اللى", "probability": 0.995361328125}, {"start": 508.57, "end": 509.03, "word": " بتجلب", "probability": 0.9609375}, {"start": 509.03, "end": 509.67, "word": " للامام", "probability": 0.712890625}, {"start": 509.67, "end": 509.77, "word": " و", "probability": 0.88818359375}, {"start": 509.77, "end": 510.27, "word": " للخلف", "probability": 0.8575846354166666}, {"start": 510.27, "end": 510.75, "word": " للامام", "probability": 0.8164876302083334}, {"start": 510.75, "end": 510.85, "word": " و", "probability": 0.97412109375}, {"start": 510.85, "end": 511.23, "word": " للخلف", "probability": 0.96142578125}, {"start": 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" و", "probability": 0.90869140625}, {"start": 518.99, "end": 519.29, "word": " نمرة", "probability": 0.6041666666666666}, {"start": 519.29, "end": 519.63, "word": " اتنين", "probability": 0.84521484375}, {"start": 519.63, "end": 519.97, "word": " يمكن", "probability": 0.9794921875}, {"start": 519.97, "end": 520.15, "word": " أن", "probability": 0.8759765625}, {"start": 520.15, "end": 520.61, "word": " تنشأ", "probability": 0.9906005859375}, {"start": 520.61, "end": 520.95, "word": " عن", "probability": 0.9951171875}, {"start": 520.95, "end": 521.89, "word": " ال", "probability": 0.97021484375}, {"start": 521.89, "end": 522.33, "word": " rotation", "probability": 0.984375}, {"start": 522.33, "end": 523.15, "word": " الدوران", "probability": 0.8660481770833334}], "temperature": 1.0}, {"id": 22, "seek": 52779, "start": 524.27, "end": 527.79, "text": "فيكون المُركّب مُركّب واحد", "tokens": [41185, 30544, 9673, 10859, 31747, 11703, 3555, 3714, 10859, 31747, 11703, 3555, 36764, 24401], "avg_logprob": -0.21575520237286885, "compression_ratio": 1.065217391304348, "no_speech_prob": 0.0, "words": [{"start": 524.27, "end": 525.17, "word": "فيكون", "probability": 0.5936279296875}, {"start": 525.17, "end": 526.47, "word": " المُركّب", "probability": 0.8205078125}, {"start": 526.47, "end": 527.13, "word": " مُركّب", "probability": 0.95498046875}, {"start": 527.13, "end": 527.79, "word": " واحد", "probability": 0.9736328125}], "temperature": 1.0}, {"id": 23, "seek": 55423, "start": 528.73, "end": 554.23, "text": "بشكل واحد وبهيئات كثيرة مختلفة ولذلك ال one two dichloroethane هو مركب واحد فقط بهيئات مختلفة وهو في حالة دوران أبدي يعني ربنا خالجه زي ما بتقول الآية الكريمة وكل في فلك يسبحون بالنسبة لعلم الكيميا هذا دوران لا يتوقف", "tokens": [3555, 8592, 28820, 36764, 24401, 46599, 3224, 1829, 19986, 9307, 9122, 12984, 48923, 3714, 46456, 46538, 3660, 35525, 8848, 23275, 2423, 472, 732, 10390, 6746, 78, 3293, 1929, 31439, 3714, 31747, 3555, 36764, 24401, 6156, 47432, 39627, 1829, 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"word": " وكل", "probability": 0.7705078125}, {"start": 548.41, "end": 548.73, "word": " في", "probability": 0.66796875}, {"start": 548.73, "end": 549.19, "word": " فلك", "probability": 0.920166015625}, {"start": 549.19, "end": 550.05, "word": " يسبحون", "probability": 0.955810546875}, {"start": 550.05, "end": 551.27, "word": " بالنسبة", "probability": 0.9791259765625}, {"start": 551.27, "end": 551.61, "word": " لعلم", "probability": 0.8351236979166666}, {"start": 551.61, "end": 552.13, "word": " الكيميا", "probability": 0.9152018229166666}, {"start": 552.13, "end": 552.47, "word": " هذا", "probability": 0.9326171875}, {"start": 552.47, "end": 553.09, "word": " دوران", "probability": 0.9879557291666666}, {"start": 553.09, "end": 553.27, "word": " لا", "probability": 0.93017578125}, {"start": 553.27, "end": 554.23, "word": " يتوقف", "probability": 0.985595703125}], "temperature": 1.0}, {"id": 24, "seek": 56560, "start": 554.7, "end": 565.6, "text": "الدوران حول الرابطة الأوحادية تماما زى المروحة اللى بالسجف لما بتلوف بنقولش عنها مروحة كتيرة بتكون بهذا الشكل بعد شوية بتزيد زوايا كمان", "tokens": [6027, 3215, 13063, 7649, 11331, 12610, 34892, 16758, 9566, 3660, 16247, 2407, 5016, 18513, 10632, 46811, 10943, 995, 30767, 7578, 9673, 32887, 5016, 3660, 13672, 7578, 20666, 3794, 7435, 5172, 5296, 15042, 39894, 1211, 38688, 44945, 39648, 8592, 18871, 11296, 3714, 32887, 5016, 3660, 9122, 2655, 48923, 39894, 30544, 39627, 15730, 25124, 28820, 39182, 13412, 2407, 10632, 39894, 11622, 25708, 30767, 14407, 25528, 9122, 2304, 7649], "avg_logprob": -0.22446361451006647, "compression_ratio": 1.6870748299319729, "no_speech_prob": 1.9073486328125e-06, "words": [{"start": 554.7, "end": 555.46, "word": "الدوران", "probability": 0.7742919921875}, {"start": 555.46, "end": 555.74, "word": " حول", "probability": 0.919677734375}, {"start": 555.74, "end": 556.28, "word": " الرابطة", "probability": 0.86669921875}, {"start": 556.28, "end": 556.8, "word": " الأوحادية", "probability": 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"word": " bond،", "probability": 0.783203125}, {"start": 871.18, "end": 871.64, "word": " لاحظوا", "probability": 0.84478759765625}, {"start": 871.64, "end": 871.84, "word": " هنا", "probability": 0.59375}, {"start": 871.84, "end": 872.0, "word": " ال", "probability": 0.841796875}, {"start": 872.0, "end": 872.22, "word": " double", "probability": 0.95703125}, {"start": 872.22, "end": 872.56, "word": " bond", "probability": 0.95751953125}, {"start": 872.56, "end": 873.74, "word": " بدايتها", "probability": 0.960693359375}, {"start": 873.74, "end": 874.6, "word": " وين؟", "probability": 0.76513671875}, {"start": 874.6, "end": 875.36, "word": " اتنين،", "probability": 0.8759765625}, {"start": 875.36, "end": 875.48, "word": " لو", "probability": 0.96826171875}, {"start": 875.48, "end": 875.96, "word": " برقم", "probability": 0.933349609375}, {"start": 875.96, "end": 876.1, "word": " من", "probability": 0.6484375}, {"start": 876.1, "end": 876.2, "word": " هنا", "probability": 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"word": " بنتين", "probability": 0.7654622395833334}, {"start": 892.21, "end": 893.51, "word": " بنتين", "probability": 0.7906087239583334}, {"start": 893.51, "end": 895.45, "word": " يلتهي", "probability": 0.5423126220703125}, {"start": 895.45, "end": 896.79, "word": " بين", "probability": 0.32177734375}, {"start": 896.79, "end": 896.97, "word": " في", "probability": 0.611328125}, {"start": 896.97, "end": 897.27, "word": " double", "probability": 0.75048828125}, {"start": 897.27, "end": 897.63, "word": " bond", "probability": 0.9375}, {"start": 897.63, "end": 898.47, "word": " الآن", "probability": 0.6180419921875}, {"start": 898.47, "end": 898.99, "word": " الين", "probability": 0.5718994140625}, {"start": 898.99, "end": 899.39, "word": " هذه", "probability": 0.572265625}, {"start": 899.39, "end": 899.53, "word": " اللي", "probability": 0.9013671875}, {"start": 899.53, "end": 899.73, "word": " هي", "probability": 0.87255859375}, {"start": 899.73, "end": 899.87, "word": " ال", 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سميت الآن هذه two مثل و four promo طب لو عديت من هنا two مثل و four promo لو قلت واحد اتنين تلاتة اربعة خمسة two مثل و four promo نفس الأشياء طالما عندك مجموعتين مثل على نفس ال carbon ابدأ من أي واحدة مافيش عندك مشكلة", "tokens": [2407, 8032, 1829, 28543, 2288, 14407, 5296, 1863, 36178, 2423, 32277, 2304, 45164, 12174, 1211, 2655, 8608, 1211, 3794, 37977, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 4032, 45164, 8608, 2304, 36081, 6024, 48506, 29538, 732, 50113, 1211, 4032, 1451, 26750, 23032, 3555, 45164, 6225, 16254, 2655, 9154, 34105, 732, 50113, 1211, 4032, 1451, 26750, 45164, 12174, 1211, 2655, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 732, 50113, 1211, 4032, 1451, 26750, 8717, 36178, 16247, 8592, 1829, 16606, 23032, 6027, 15042, 43242, 4117, 3714, 7435, 2304, 45367, 2655, 9957, 50113, 1211, 15844, 8717, 36178, 2423, 5954, 1975, 44510, 10721, 9154, 36632, 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{"start": 1208.74, "end": 1209.36, "word": " مجموعة", "probability": 0.9619140625}, {"start": 1209.36, "end": 1209.7, "word": " و", "probability": 0.61181640625}, {"start": 1209.7, "end": 1210.32, "word": " التنتين", "probability": 0.90673828125}, {"start": 1210.32, "end": 1211.24, "word": " موجودات", "probability": 0.942626953125}, {"start": 1211.24, "end": 1213.48, "word": " كجزء", "probability": 0.97265625}, {"start": 1213.48, "end": 1213.68, "word": " من", "probability": 0.99462890625}, {"start": 1213.68, "end": 1214.14, "word": " أطول", "probability": 0.9879557291666666}, {"start": 1214.14, "end": 1215.0, "word": " سلسلة", "probability": 0.993408203125}, {"start": 1215.0, "end": 1216.22, "word": " واضحة", "probability": 0.78662109375}, {"start": 1216.22, "end": 1216.88, "word": " الفكرة؟", "probability": 0.94091796875}], "temperature": 1.0}, {"id": 53, "seek": 125941, "start": 1236.77, "end": 1259.41, "text": "وعشان هيك لا بأس ان اعطيكم مسألة تانية تفكروا فيها تعملوها homework على هذا الموضوع تحديدا مسألة جميلة جدا", "tokens": [45367, 8592, 7649, 39896, 4117, 20193, 4724, 10721, 3794, 16472, 1975, 3615, 9566, 1829, 24793, 47524, 10721, 37977, 6055, 7649, 10632, 6055, 5172, 37983, 14407, 8978, 11296, 6055, 25957, 1211, 2407, 11296, 14578, 15844, 23758, 9673, 2407, 11242, 45367, 6055, 5016, 16254, 28259, 47524, 10721, 37977, 10874, 2304, 26895, 3660, 10874, 28259], "avg_logprob": -0.10333136736222033, "compression_ratio": 1.4090909090909092, "no_speech_prob": 0.0, "words": [{"start": 1236.77, "end": 1237.33, "word": "وعشان", "probability": 0.8126627604166666}, {"start": 1237.33, "end": 1237.99, "word": " هيك", "probability": 0.982666015625}, {"start": 1237.99, "end": 1238.27, "word": " لا", "probability": 0.6318359375}, {"start": 1238.27, "end": 1238.81, "word": " بأس", "probability": 0.9664713541666666}, {"start": 1238.81, "end": 1239.05, "word": " ان", "probability": 0.4375}, {"start": 1239.05, "end": 1239.93, "word": " اعطيكم", "probability": 0.97041015625}, 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بقول فينل في حرف ال V هذه فينل فلو حملت ال chlorine بتصير vinyl chloride ليش رفضنا؟", "tokens": [28814, 11622, 42213, 2655, 4117, 14407, 4724, 43042, 3224, 8608, 2304, 34268, 22653, 9122, 19528, 3660, 37893, 3714, 19913, 3555, 2407, 9566, 3660, 10874, 6027, 2655, 8978, 1863, 1211, 41850, 4724, 39648, 8978, 1863, 1211, 8978, 11331, 28480, 2423, 691, 29538, 8978, 1863, 1211, 6156, 1211, 2407, 11331, 42213, 2655, 2423, 39888, 39894, 9381, 13546, 25226, 35434, 32239, 8592, 12602, 5172, 11242, 8315, 22807], "avg_logprob": -0.28076923076923077, "compression_ratio": 1.4038461538461537, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1359.08, "end": 1359.94, "word": "إزملتكوا", "probability": 0.6207682291666666}, {"start": 1359.94, "end": 1360.26, "word": " برضه", "probability": 0.9493815104166666}, {"start": 1360.26, "end": 1360.96, "word": " سمعتني", "probability": 0.814697265625}, {"start": 1360.96, "end": 1361.34, "word": " كلمة", "probability": 0.904296875}, {"start": 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هيكون عنده من أربع ذرّات كربون أنا هنا ماسك التلاتة ممكن واحدة تقول بسيطة حطوا هنا الكربون هنا", "tokens": [5172, 37983, 14407, 20449, 1863, 7578, 5551, 9957, 3714, 43020, 8717, 5016, 9566, 33251, 25513, 11536, 33688, 11242, 31845, 10632, 4724, 2304, 3615, 1863, 7578, 9122, 2304, 3714, 31747, 11703, 3555, 2423, 39184, 42, 2030, 8032, 1829, 30544, 43242, 3224, 9154, 5551, 25513, 3615, 29910, 2288, 11703, 9307, 9122, 25513, 11536, 41850, 34105, 19446, 3794, 4117, 16712, 1211, 9307, 3660, 3714, 43020, 36764, 24401, 3660, 6055, 39648, 4724, 3794, 1829, 9566, 3660, 11331, 9566, 14407, 34105, 33251, 25513, 11536, 34105], "avg_logprob": -0.2824073956336504, "compression_ratio": 1.7048192771084338, "no_speech_prob": 0.0, "words": [{"start": 1834.53, "end": 1835.15, "word": "فكروا", "probability": 0.8717447916666666}, {"start": 1835.15, "end": 1835.57, "word": " معنى", "probability": 0.7037760416666666}, {"start": 1835.57, "end": 1835.73, "word": " أين", "probability": 0.64404296875}, {"start": 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"probability": 0.85693359375}, {"start": 2034.66, "end": 2035.04, "word": " هذه", "probability": 0.88671875}, {"start": 2035.04, "end": 2035.18, "word": " و", "probability": 0.99267578125}, {"start": 2035.18, "end": 2035.72, "word": " حطينا", "probability": 0.94140625}, {"start": 2035.72, "end": 2036.04, "word": " مثل", "probability": 0.98583984375}, {"start": 2036.04, "end": 2039.2, "word": " هنطلع", "probability": 0.7451904296875}, {"start": 2039.2, "end": 2039.36, "word": " في", "probability": 0.931640625}, {"start": 2039.36, "end": 2039.98, "word": " المركب", "probability": 0.9332682291666666}, {"start": 2039.98, "end": 2041.5, "word": " المتفرع", "probability": 0.97939453125}, {"start": 2041.5, "end": 2046.68, "word": " اتطلع", "probability": 0.749609375}, {"start": 2046.68, "end": 2046.92, "word": " على", "probability": 0.89599609375}, {"start": 2046.92, "end": 2047.54, "word": " شكله", "probability": 0.99072265625}, {"start": 2047.54, "end": 2048.42, "word": " بدأ", "probability": 0.682861328125}, {"start": 2048.42, "end": 2048.96, "word": " يغلبني", "probability": 0.965576171875}], "temperature": 1.0}, {"id": 88, "seek": 207567, "start": 2053.2, "end": 2075.68, "text": "الثلاثة اللي اتفرع منهم واحد واحد اتنين تلاتة اتفرع لما كان في ال ال كيرز ال double bond سمينا ايزو بيوتين هنا ايش هنسميه ايزو بيوتين ايزو بيوتين طب لو قلت لو واحد اسميه بال ايو باكنيم هايوا قدام عينيكم اطول سلسلة فيه", "tokens": [6027, 12984, 1211, 5718, 104, 3660, 13672, 1829, 1975, 2655, 5172, 2288, 3615, 9154, 16095, 36764, 24401, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 2655, 5172, 2288, 3615, 5296, 15042, 25961, 8978, 2423, 2423, 9122, 13546, 11622, 2423, 3834, 6086, 8608, 2304, 1829, 8315, 1975, 1829, 11622, 2407, 4724, 1829, 35473, 9957, 34105, 1975, 1829, 8592, 8032, 1863, 38251, 1829, 3224, 1975, 1829, 11622, 2407, 4724, 1829, 35473, 9957, 1975, 1829, 11622, 2407, 4724, 1829, 35473, 9957, 23032, 3555, 45164, 12174, 1211, 2655, 45164, 36764, 24401, 1975, 38251, 1829, 3224, 20666, 1975, 1829, 2407, 4724, 995, 19452, 32640, 8032, 47302, 14407, 12174, 3215, 10943, 6225, 9957, 1829, 24793, 1975, 9566, 12610, 8608, 1211, 3794, 37977, 8978, 3224], "avg_logprob": -0.22694672790707135, "compression_ratio": 1.9792746113989637, "no_speech_prob": 0.0, "words": [{"start": 2053.2, "end": 2053.94, "word": "الثلاثة", "probability": 0.8320719401041666}, {"start": 2053.94, "end": 2054.04, "word": " اللي", "probability": 0.76220703125}, {"start": 2054.04, "end": 2054.5, "word": " اتفرع", "probability": 0.896875}, {"start": 2054.5, "end": 2054.9, "word": " منهم", "probability": 0.97314453125}, {"start": 2054.9, "end": 2055.32, "word": " واحد", "probability": 0.90869140625}, {"start": 2055.32, "end": 2055.7, "word": " واحد", "probability": 0.771240234375}, {"start": 2055.7, "end": 2056.02, "word": " اتنين", "probability": 0.97412109375}, {"start": 2056.02, "end": 2056.44, "word": " تلاتة", "probability": 0.8773193359375}, {"start": 2056.44, "end": 2056.98, "word": " اتفرع", "probability": 0.98017578125}, {"start": 2056.98, "end": 2057.9, "word": " لما", "probability": 0.87939453125}, {"start": 2057.9, "end": 2058.12, "word": " كان", "probability": 0.990234375}, {"start": 2058.12, "end": 2058.28, "word": " في", "probability": 0.89697265625}, {"start": 2058.28, "end": 2058.4, "word": " ال", "probability": 0.8974609375}, {"start": 2058.4, "end": 2058.56, "word": " ال", "probability": 0.44873046875}, {"start": 2058.56, "end": 2058.92, "word": " كيرز", "probability": 0.48455810546875}, {"start": 2058.92, "end": 2059.04, "word": " ال", "probability": 0.3935546875}, {"start": 2059.04, "end": 2059.22, "word": " double", "probability": 0.47265625}, {"start": 2059.22, "end": 2059.48, "word": " bond", "probability": 0.65380859375}, {"start": 2059.48, "end": 2059.88, "word": " سمينا", "probability": 0.8243408203125}, {"start": 2059.88, "end": 2060.34, "word": " ايزو", "probability": 0.75579833984375}, {"start": 2060.34, "end": 2061.04, "word": " بيوتين", "probability": 0.88623046875}, {"start": 2061.04, "end": 2061.82, "word": " هنا", "probability": 0.386474609375}, {"start": 2061.82, "end": 2062.1, "word": " ايش", "probability": 0.8857421875}, {"start": 2062.1, "end": 2062.86, "word": " هنسميه", "probability": 0.912109375}, {"start": 2062.86, "end": 2064.02, "word": " ايزو", "probability": 0.87646484375}, {"start": 2064.02, "end": 2065.18, "word": " بيوتين", "probability": 0.9627685546875}, {"start": 2065.18, "end": 2065.86, "word": " ايزو", "probability": 0.9227294921875}, {"start": 2065.86, "end": 2066.38, "word": " بيوتين", "probability": 0.9891357421875}, {"start": 2066.38, "end": 2066.86, "word": " طب", "probability": 0.86767578125}, {"start": 2066.86, "end": 2067.04, "word": " لو", "probability": 0.9892578125}, {"start": 2067.04, "end": 2067.34, "word": " قلت", "probability": 0.6685384114583334}, {"start": 2067.34, "end": 2067.48, "word": " لو", "probability": 0.87109375}, {"start": 2067.48, "end": 2067.66, "word": " واحد", "probability": 0.6591796875}, {"start": 2067.66, "end": 2068.18, "word": " اسميه", "probability": 0.83203125}, {"start": 2068.18, "end": 2068.34, "word": " بال", "probability": 0.7568359375}, {"start": 2068.34, "end": 2068.82, "word": " ايو", "probability": 0.5703938802083334}, {"start": 2068.82, "end": 2069.64, "word": " باكنيم", "probability": 0.830322265625}, {"start": 2069.64, "end": 2071.68, "word": " هايوا", "probability": 0.5369466145833334}, {"start": 2071.68, "end": 2072.0, "word": " قدام", "probability": 0.8684895833333334}, {"start": 2072.0, "end": 2072.64, "word": " عينيكم", "probability": 0.9266357421875}, {"start": 2072.64, "end": 2074.72, "word": " اطول", "probability": 0.8465169270833334}, {"start": 2074.72, "end": 2075.3, "word": " سلسلة", "probability": 0.982177734375}, {"start": 2075.3, "end": 2075.68, "word": " فيه", "probability": 0.9814453125}], "temperature": 1.0}, {"id": 89, "seek": 210596, "start": 2077.6, "end": 2105.96, "text": "One Ibropine وعن إمرأتين يحمل مثل إذا ال isobutene اسمه two مثل و one ibropine بناء على ذلك هذه الصيغة العامة C4H8 كم ألكين منها؟ C4H8 كم ألكين؟", "tokens": [15426, 40790, 1513, 533, 4032, 3615, 1863, 11933, 29973, 10721, 2655, 9957, 7251, 35571, 1211, 50113, 1211, 11933, 15730, 2423, 307, 996, 325, 1450, 24525, 2304, 3224, 732, 50113, 1211, 4032, 472, 39073, 1513, 533, 44945, 16606, 15844, 29910, 23275, 29538, 31767, 1829, 17082, 3660, 18863, 10943, 3660, 383, 19, 39, 23, 9122, 2304, 5551, 1211, 4117, 9957, 9154, 11296, 22807, 383, 19, 39, 23, 9122, 2304, 5551, 1211, 4117, 9957, 22807], "avg_logprob": -0.29708905415992215, "compression_ratio": 1.3773584905660377, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2077.6, "end": 2078.04, "word": "One", "probability": 0.07373046875}, {"start": 2078.04, "end": 2078.86, "word": " Ibropine", "probability": 0.5654296875}, {"start": 2078.86, "end": 2081.12, "word": " وعن", "probability": 0.6410319010416666}, {"start": 2081.12, "end": 2081.62, "word": " إمرأتين", "probability": 0.71552734375}, {"start": 2081.62, "end": 2082.2, "word": " يحمل", "probability": 0.97705078125}, {"start": 2082.2, "end": 2083.5, "word": " مثل", "probability": 0.86767578125}, {"start": 2083.5, "end": 2084.3, "word": " إذا", "probability": 0.681884765625}, {"start": 2084.3, "end": 2085.14, "word": " ال", "probability": 0.544921875}, {"start": 2085.14, "end": 2086.6, "word": " isobutene", "probability": 0.72686767578125}, {"start": 2086.6, "end": 2087.28, "word": " اسمه", "probability": 0.9554036458333334}, {"start": 2087.28, "end": 2088.18, "word": " two", "probability": 0.368408203125}, {"start": 2088.18, "end": 2088.7, "word": " مثل", "probability": 0.870361328125}, {"start": 2088.7, "end": 2089.0, "word": " و", "probability": 0.493896484375}, {"start": 2089.0, "end": 2089.14, "word": " one", "probability": 0.4853515625}, {"start": 2089.14, "end": 2089.72, "word": " ibropine", "probability": 0.7479654947916666}, {"start": 2089.72, "end": 2090.7, "word": " بناء", "probability": 0.932861328125}, {"start": 2090.7, "end": 2091.02, "word": " على", "probability": 0.8544921875}, {"start": 2091.02, "end": 2091.76, "word": " ذلك", "probability": 0.9921875}, {"start": 2091.76, "end": 2092.9, "word": " هذه", "probability": 0.57958984375}, {"start": 2092.9, "end": 2093.4, "word": " الصيغة", "probability": 0.97802734375}, {"start": 2093.4, "end": 2094.04, "word": " العامة", "probability": 0.99169921875}, {"start": 2094.04, "end": 2096.56, "word": " C4H8", "probability": 0.786834716796875}, {"start": 2096.56, "end": 2098.48, "word": " كم", "probability": 0.838623046875}, {"start": 2098.48, "end": 2099.14, "word": " ألكين", "probability": 0.765869140625}, {"start": 2099.14, "end": 2100.48, "word": " منها؟", "probability": 0.7765299479166666}, {"start": 2100.48, "end": 2104.48, "word": " C4H8", "probability": 0.9195556640625}, {"start": 2104.48, "end": 2105.2, "word": " كم", "probability": 0.888427734375}, {"start": 2105.2, "end": 2105.96, "word": " ألكين؟", "probability": 0.93447265625}], "temperature": 1.0}, {"id": 90, "seek": 213164, "start": 2108.36, "end": 2131.64, "text": "عدوهم أربعة أربعة شفتهم يعني لو بدى يكون عندكوا سؤال draw all the possible alkenes that have the formula C4H8 one butane, cistobutane, trans-tobutane, isobutane إذا كام ألكين؟ أربعة الآن انتبهوا معي سؤال دقيق جدا", "tokens": [3615, 3215, 2407, 16095, 5551, 25513, 27884, 5551, 25513, 27884, 13412, 5172, 2655, 16095, 37495, 22653, 45164, 47525, 7578, 7251, 30544, 43242, 4117, 14407, 8608, 33604, 6027, 2642, 439, 264, 1944, 37688, 25973, 300, 362, 264, 8513, 383, 19, 39, 23, 472, 457, 1929, 11, 269, 468, 996, 325, 1929, 11, 1145, 12, 83, 996, 325, 1929, 11, 307, 996, 325, 1929, 11933, 15730, 9122, 10943, 5551, 1211, 4117, 9957, 22807, 5551, 25513, 27884, 6024, 48506, 16472, 2655, 3555, 3224, 14407, 20449, 1829, 8608, 33604, 6027, 11778, 38436, 4587, 10874, 28259], "avg_logprob": -0.28311821267656656, "compression_ratio": 1.400943396226415, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2108.36, "end": 2108.88, "word": "عدوهم", "probability": 0.78662109375}, {"start": 2108.88, "end": 2109.68, "word": " أربعة", "probability": 0.6930745442708334}, {"start": 2109.68, "end": 2110.26, "word": " أربعة", "probability": 0.7486165364583334}, {"start": 2110.26, "end": 2111.9, "word": " شفتهم", "probability": 0.73388671875}, {"start": 2111.9, "end": 2113.12, "word": " يعني", "probability": 0.7333984375}, {"start": 2113.12, "end": 2113.2, "word": " لو", "probability": 0.912109375}, {"start": 2113.2, "end": 2113.36, "word": " بدى", "probability": 0.5087890625}, {"start": 2113.36, "end": 2113.52, "word": " يكون", "probability": 0.943603515625}, {"start": 2113.52, "end": 2113.84, "word": " عندكوا", "probability": 0.7902018229166666}, {"start": 2113.84, "end": 2114.34, "word": " سؤال", "probability": 0.9866536458333334}, {"start": 2114.34, "end": 2114.96, "word": " draw", "probability": 0.56201171875}, {"start": 2114.96, "end": 2115.78, "word": " all", "probability": 0.92333984375}, {"start": 2115.78, "end": 2116.04, "word": " the", "probability": 0.7451171875}, {"start": 2116.04, "end": 2116.52, "word": " possible", "probability": 0.94384765625}, {"start": 2116.52, "end": 2117.28, "word": " alkenes", "probability": 0.641357421875}, {"start": 2117.28, "end": 2117.6, "word": " that", "probability": 0.92041015625}, {"start": 2117.6, "end": 2117.88, "word": " have", "probability": 0.94482421875}, {"start": 2117.88, "end": 2118.06, "word": " the", "probability": 0.65869140625}, {"start": 2118.06, "end": 2118.52, "word": " formula", "probability": 0.89306640625}, {"start": 2118.52, "end": 2119.74, "word": " C4H8", "probability": 0.93408203125}, {"start": 2119.74, "end": 2120.22, "word": " one", "probability": 0.51123046875}, {"start": 2120.22, "end": 2120.82, "word": " butane,", "probability": 0.70654296875}, {"start": 2121.22, "end": 2122.16, "word": " cistobutane,", "probability": 0.68994140625}, {"start": 2122.46, "end": 2122.82, "word": " trans", "probability": 0.36376953125}, {"start": 2122.82, "end": 2123.56, "word": "-tobutane,", "probability": 0.7286865234375}, {"start": 2124.18, "end": 2125.08, "word": " isobutane", "probability": 0.9412841796875}, {"start": 2125.08, "end": 2125.32, "word": " إذا", "probability": 0.556640625}, {"start": 2125.32, "end": 2125.6, "word": " كام", "probability": 0.727294921875}, {"start": 2125.6, "end": 2126.58, "word": " ألكين؟", "probability": 0.74921875}, {"start": 2126.58, "end": 2127.48, "word": " أربعة", "probability": 0.9640299479166666}, {"start": 2127.48, "end": 2128.52, "word": " الآن", "probability": 0.54608154296875}, {"start": 2128.52, "end": 2129.08, "word": " انتبهوا", "probability": 0.95830078125}, {"start": 2129.08, "end": 2129.94, "word": " معي", "probability": 0.929931640625}, {"start": 2129.94, "end": 2130.76, "word": " سؤال", "probability": 0.9451497395833334}, {"start": 2130.76, "end": 2131.22, "word": " دقيق", "probability": 0.9964192708333334}, {"start": 2131.22, "end": 2131.64, "word": " جدا", "probability": 0.991455078125}], "temperature": 1.0}, {"id": 91, "seek": 215686, "start": 2133.12, "end": 2156.86, "text": "لو أنا سألتكم draw all the possible compounds المركبات أنا قولت ال keys انتبهوا جيدا draw all the possible compounds كل المركبات that have the formula C4H8 كيف بدكوا تبدأوا تفكروا تفضلي", "tokens": [1211, 2407, 41850, 8608, 10721, 1211, 2655, 24793, 2642, 439, 264, 1944, 21810, 9673, 31747, 3555, 9307, 41850, 12174, 12610, 2655, 2423, 9317, 16472, 2655, 3555, 3224, 14407, 10874, 25708, 995, 2642, 439, 264, 1944, 21810, 28242, 9673, 31747, 3555, 9307, 300, 362, 264, 8513, 383, 19, 39, 23, 9122, 33911, 47525, 4117, 14407, 6055, 44510, 10721, 14407, 6055, 5172, 37983, 14407, 6055, 5172, 11242, 20292], "avg_logprob": -0.2237639956509889, "compression_ratio": 1.5146198830409356, "no_speech_prob": 0.0, "words": [{"start": 2133.12, "end": 2133.4, "word": "لو", "probability": 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0.07635498046875}, {"start": 2142.22, "end": 2142.96, "word": " انتبهوا", "probability": 0.823681640625}, {"start": 2142.96, "end": 2143.64, "word": " جيدا", "probability": 0.98583984375}, {"start": 2143.64, "end": 2144.34, "word": " draw", "probability": 0.4375}, {"start": 2144.34, "end": 2144.74, "word": " all", "probability": 0.955078125}, {"start": 2144.74, "end": 2145.0, "word": " the", "probability": 0.84619140625}, {"start": 2145.0, "end": 2145.38, "word": " possible", "probability": 0.92724609375}, {"start": 2145.38, "end": 2146.12, "word": " compounds", "probability": 0.90576171875}, {"start": 2146.12, "end": 2146.6, "word": " كل", "probability": 0.7841796875}, {"start": 2146.6, "end": 2147.92, "word": " المركبات", "probability": 0.9730224609375}, {"start": 2147.92, "end": 2148.54, "word": " that", "probability": 0.830078125}, {"start": 2148.54, "end": 2148.98, "word": " have", "probability": 0.9541015625}, {"start": 2148.98, "end": 2149.24, "word": " the", "probability": 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{"start": 2434.27, "end": 2434.63, "word": " واحد،", "probability": 0.7989908854166666}, {"start": 2434.63, "end": 2434.99, "word": " اتنين", "probability": 0.9344482421875}, {"start": 2434.99, "end": 2435.59, "word": " إجت", "probability": 0.72509765625}, {"start": 2435.59, "end": 2435.75, "word": " ال", "probability": 0.53857421875}, {"start": 2435.75, "end": 2436.03, "word": " مثل", "probability": 0.953369140625}, {"start": 2436.03, "end": 2436.19, "word": " الآن", "probability": 0.6629638671875}, {"start": 2436.19, "end": 2436.39, "word": " على", "probability": 0.9453125}, {"start": 2436.39, "end": 2436.95, "word": " أكم؟", "probability": 0.7727864583333334}], "temperature": 1.0}, {"id": 103, "seek": 245523, "start": 2437.41, "end": 2455.23, "text": "تلاتة لو واحدة رقمت من هنا واحد اتنين هتقول تلاتة اربعة هتخل ال مثل على خمسة ان هو الأصحى اذا من هنا برقم واحد اتنين تلاتة اربعة خمسة ال three مثل Cyclopentane المركب اللي بعده", "tokens": [2655, 1211, 9307, 3660, 45164, 36764, 24401, 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"probability": 0.95458984375}, {"start": 2501.43, "end": 2501.55, "word": " و", "probability": 0.849609375}, {"start": 2501.55, "end": 2501.67, "word": " هذا", "probability": 0.95458984375}, {"start": 2501.67, "end": 2501.85, "word": " one", "probability": 0.92138671875}, {"start": 2501.85, "end": 2502.29, "word": " three", "probability": 0.96142578125}, {"start": 2502.29, "end": 2503.07, "word": " لكن", "probability": 0.84033203125}, {"start": 2503.07, "end": 2504.45, "word": " هذا", "probability": 0.953125}, {"start": 2504.45, "end": 2504.59, "word": " ال", "probability": 0.91796875}, {"start": 2504.59, "end": 2504.73, "word": " one", "probability": 0.88232421875}, {"start": 2504.73, "end": 2505.13, "word": " three", "probability": 0.94921875}, {"start": 2505.13, "end": 2505.85, "word": " four", "probability": 0.63330078125}, {"start": 2505.85, "end": 2506.37, "word": " five", "probability": 0.92626953125}, {"start": 2506.37, "end": 2506.77, "word": " six", "probability": 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"probability": 0.99560546875}, {"start": 2515.29, "end": 2516.27, "word": " five", "probability": 0.2958984375}, {"start": 2516.27, "end": 2516.65, "word": " brom", "probability": 0.191650390625}, {"start": 2516.65, "end": 2516.89, "word": " one", "probability": 0.265869140625}, {"start": 2516.89, "end": 2517.19, "word": " three", "probability": 0.92041015625}, {"start": 2517.19, "end": 2520.09, "word": " cyclohexadiene", "probability": 0.6335042317708334}, {"start": 2520.09, "end": 2520.83, "word": " لو", "probability": 0.64794921875}, {"start": 2520.83, "end": 2521.43, "word": " تلاتة", "probability": 0.947265625}, {"start": 2521.43, "end": 2521.67, "word": " double", "probability": 0.787109375}, {"start": 2521.67, "end": 2522.23, "word": " bonds", "probability": 0.75146484375}, {"start": 2522.23, "end": 2524.29, "word": " تريين", "probability": 0.5240071614583334}, {"start": 2524.29, "end": 2524.91, "word": " تلاتة", "probability": 0.88916015625}, {"start": 2524.91, "end": 2525.53, "word": " تريين", "probability": 0.8313802083333334}, {"start": 2525.53, "end": 2525.61, "word": " و", "probability": 0.5263671875}, {"start": 2525.61, "end": 2526.57, "word": " بتحطوا", "probability": 0.865966796875}, {"start": 2526.57, "end": 2528.99, "word": " الأرقام", "probability": 0.947265625}, {"start": 2528.99, "end": 2529.13, "word": " و", "probability": 0.8125}, {"start": 2529.13, "end": 2529.99, "word": " بتنتبهولها", "probability": 0.898193359375}, {"start": 2529.99, "end": 2530.47, "word": " لو", "probability": 0.607421875}, {"start": 2530.47, "end": 2531.03, "word": " أربعة", "probability": 0.9026692708333334}, {"start": 2531.03, "end": 2531.33, "word": " double", "probability": 0.923828125}, {"start": 2531.33, "end": 2531.77, "word": " bonds", "probability": 0.923828125}], "temperature": 1.0}, {"id": 107, "seek": 255437, "start": 2533.63, "end": 2554.37, "text": "تتراين و هكذا واضح؟ لكن هنا يجب أن ننوح لأمر لحظة ال Cyclohexane هذا ايش اسمه؟ Cyclohexane هذا تنتين", 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"probability": 0.85107421875}, {"start": 2590.63, "end": 2590.83, "word": " double", "probability": 0.7890625}, {"start": 2590.83, "end": 2591.17, "word": " bond", "probability": 0.90771484375}, {"start": 2591.17, "end": 2591.41, "word": " هاي", "probability": 0.744873046875}, {"start": 2591.41, "end": 2591.77, "word": " بداية", "probability": 0.97900390625}, {"start": 2591.77, "end": 2592.01, "word": " اللي", "probability": 0.971923828125}, {"start": 2592.01, "end": 2592.33, "word": " بعدها", "probability": 0.725341796875}, {"start": 2592.33, "end": 2592.45, "word": " هاي", "probability": 0.6475830078125}, {"start": 2592.45, "end": 2592.75, "word": " بداية", "probability": 0.98193359375}, {"start": 2592.75, "end": 2592.97, "word": " اللي", "probability": 0.99609375}, {"start": 2592.97, "end": 2593.53, "word": " بعدها", "probability": 0.889404296875}, {"start": 2593.53, "end": 2593.97, "word": " و", "probability": 0.58349609375}, {"start": 2593.97, "end": 2594.29, "word": " تروح", "probability": 0.9860026041666666}, {"start": 2594.29, "end": 2595.25, "word": " تسميه", "probability": 0.98486328125}, {"start": 2595.25, "end": 2596.99, "word": " one", "probability": 0.6455078125}, {"start": 2596.99, "end": 2598.17, "word": " three", "probability": 0.81494140625}, {"start": 2598.17, "end": 2599.49, "word": " five", "probability": 0.9130859375}, {"start": 2599.49, "end": 2603.95, "word": " cyclohexatriene", "probability": 0.8004557291666666}, {"start": 2603.95, "end": 2604.53, "word": " هذا", "probability": 0.86572265625}, {"start": 2604.53, "end": 2605.27, "word": " الاسم", "probability": 0.8330078125}, {"start": 2605.27, "end": 2606.67, "word": " غير", "probability": 0.99609375}, {"start": 2606.67, "end": 2607.19, "word": " مقبول", "probability": 0.9794921875}], "temperature": 1.0}, {"id": 110, "seek": 263601, "start": 2607.91, "end": 2636.01, "text": "هذا المركب أخد اسم شهرة عبر التاريخ من ايام ما فصلوا العالم فرده في ال .. يمكن الف وتمنمية ولا اشي زي هيك، خمسة و عشرين زمان، قبل متين سنة، أخد اسم بنزين فما بنسميه إطلاقا Cyclohexatriene ف Cyclohexatriene is not a correct name، شو ال correct name؟ بنزين", "tokens": [3224, 15730, 9673, 31747, 3555, 5551, 9778, 3215, 24525, 2304, 13412, 3224, 25720, 6225, 26890, 16712, 9640, 1829, 9778, 9154, 1975, 1829, 10943, 19446, 6156, 36520, 14407, 18863, 45340, 6156, 2288, 3215, 3224, 8978, 2423, 4386, 7251, 43020, 27188, 34683, 27842, 2304, 10632, 49429, 1975, 8592, 1829, 30767, 1829, 39896, 4117, 12399, 16490, 2304, 3794, 3660, 4032, 6225, 46309, 9957, 30767, 2304, 7649, 12399, 12174, 36150, 44650, 9957, 8608, 1863, 3660, 12399, 5551, 9778, 3215, 24525, 2304, 44945, 11622, 9957, 6156, 15042, 44945, 38251, 1829, 3224, 11933, 9566, 15040, 4587, 995, 10295, 66, 752, 675, 87, 31674, 1450, 6156, 10295, 66, 752, 675, 87, 31674, 1450, 307, 406, 257, 3006, 1315, 12399, 13412, 2407, 2423, 3006, 1315, 22807, 44945, 11622, 9957], "avg_logprob": -0.1790471243076637, "compression_ratio": 1.639344262295082, "no_speech_prob": 0.0, "words": [{"start": 2607.91, "end": 2608.29, "word": "هذا", "probability": 0.982666015625}, {"start": 2608.29, "end": 2608.87, "word": " المركب", "probability": 0.8401692708333334}, {"start": 2608.87, "end": 2609.21, "word": " أخد", "probability": 0.8680013020833334}, {"start": 2609.21, "end": 2609.49, "word": " اسم", "probability": 0.915283203125}, {"start": 2609.49, "end": 2610.01, "word": " شهرة", "probability": 0.9788411458333334}, {"start": 2610.01, "end": 2610.63, "word": " عبر", "probability": 0.985107421875}, {"start": 2610.63, "end": 2611.39, "word": " التاريخ", "probability": 0.9959716796875}, {"start": 2611.39, "end": 2611.85, "word": " من", "probability": 0.97314453125}, {"start": 2611.85, "end": 2612.39, "word": " ايام", "probability": 0.723388671875}, {"start": 2612.39, "end": 2612.57, "word": " ما", "probability": 0.9638671875}, {"start": 2612.57, "end": 2613.21, "word": " فصلوا", "probability": 0.8404947916666666}, {"start": 2613.21, "end": 2613.93, "word": " العالم", "probability": 0.98974609375}, {"start": 2613.93, "end": 2614.59, "word": " فرده", "probability": 0.8001708984375}, {"start": 2614.59, "end": 2614.75, "word": " في", "probability": 0.83837890625}, {"start": 2614.75, "end": 2615.11, "word": " ال", "probability": 0.7392578125}, {"start": 2615.11, "end": 2615.57, "word": " ..", "probability": 0.59521484375}, {"start": 2615.57, "end": 2616.39, "word": " يمكن", "probability": 0.88525390625}, {"start": 2616.39, "end": 2616.65, "word": " الف", "probability": 0.384033203125}, {"start": 2616.65, "end": 2617.37, "word": " وتمنمية", "probability": 0.78857421875}, {"start": 2617.37, "end": 2617.61, "word": " ولا", "probability": 0.5712890625}, {"start": 2617.61, "end": 2617.91, "word": " اشي", "probability": 0.74462890625}, {"start": 2617.91, "end": 2618.15, "word": " زي", "probability": 0.96728515625}, {"start": 2618.15, "end": 2619.05, "word": " هيك،", "probability": 0.7305501302083334}, {"start": 2619.05, "end": 2619.43, "word": " خمسة", "probability": 0.87548828125}, {"start": 2619.43, "end": 2619.51, "word": " و", "probability": 0.9833984375}, {"start": 2619.51, "end": 2619.97, "word": " عشرين", "probability": 0.87109375}, {"start": 2619.97, "end": 2621.55, "word": " زمان،", "probability": 0.8133544921875}, {"start": 2621.55, "end": 2621.75, "word": " قبل", "probability": 0.7191162109375}, {"start": 2621.75, "end": 2622.09, "word": " متين", "probability": 0.787353515625}, {"start": 2622.09, "end": 2622.71, "word": " سنة،", "probability": 0.86553955078125}, {"start": 2622.71, "end": 2623.57, "word": " أخد", "probability": 0.9306640625}, {"start": 2623.57, "end": 2623.83, "word": " اسم", "probability": 0.984130859375}, {"start": 2623.83, "end": 2624.33, "word": " بنزين", "probability": 0.9485677083333334}, {"start": 2624.33, "end": 2626.33, "word": " فما", "probability": 0.8349609375}, {"start": 2626.33, "end": 2627.01, "word": " بنسميه", "probability": 0.962158203125}, {"start": 2627.01, "end": 2627.77, "word": " إطلاقا", "probability": 0.87421875}, {"start": 2627.77, "end": 2630.97, "word": " Cyclohexatriene", "probability": 0.7723214285714286}, {"start": 2630.97, "end": 2631.41, "word": " ف", "probability": 0.72412109375}, {"start": 2631.41, "end": 2632.51, "word": " Cyclohexatriene", "probability": 0.93701171875}, {"start": 2632.51, "end": 2632.75, "word": " is", "probability": 0.85400390625}, {"start": 2632.75, "end": 2633.17, "word": " not", "probability": 0.96533203125}, {"start": 2633.17, "end": 2633.45, "word": " a", "probability": 0.93603515625}, {"start": 2633.45, "end": 2633.75, "word": " correct", "probability": 0.951171875}, {"start": 2633.75, "end": 2634.03, "word": " name،", "probability": 0.6805419921875}, {"start": 2634.03, "end": 2634.13, "word": " شو", "probability": 0.85595703125}, {"start": 2634.13, "end": 2634.25, "word": " ال", "probability": 0.67578125}, {"start": 2634.25, "end": 2634.53, "word": " correct", "probability": 0.96337890625}, {"start": 2634.53, "end": 2635.03, "word": " name؟", "probability": 0.942626953125}, {"start": 2635.03, "end": 2636.01, "word": " بنزين", "probability": 0.853515625}], "temperature": 1.0}, {"id": 111, "seek": 263856, "start": 2636.72, "end": 2638.56, "text": "وبهيك بننهي اليوم ان شاء الله", "tokens": [37746, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984], "avg_logprob": -0.16653645237286885, "compression_ratio": 1.0392156862745099, "no_speech_prob": 0.0, "words": [{"start": 2636.7200000000003, "end": 2637.26, "word": "وبهيك", "probability": 0.8765869140625}, {"start": 2637.26, "end": 2637.8, "word": " بننهي", "probability": 0.79705810546875}, {"start": 2637.8, "end": 2638.08, "word": " اليوم", "probability": 0.973876953125}, {"start": 2638.08, "end": 2638.18, "word": " ان", "probability": 0.60791015625}, {"start": 2638.18, "end": 2638.44, "word": " شاء", "probability": 0.98779296875}, {"start": 2638.44, "end": 2638.56, "word": " الله", "probability": 0.95458984375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2639.45875, "duration_after_vad": 2497.617499999992}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b2e90e18512e8133626ac5ab048d29f286e7ee34
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_postprocess.srt
@@ -0,0 +1,1896 @@
+1
+00:00:20,180 --> 00:00:26,240
+بسم الله الرحمن الرحيم الفصل التاسع موضوعه ال
+
+2
+00:00:26,240 --> 00:00:31,480
+aldehydes and ketones طبعا ال aldehydes and
+
+3
+00:00:31,480 --> 00:00:36,420
+ketones ربما انتوا اتلاحظوا انه عائلتين مش عائلة
+
+4
+00:00:36,420 --> 00:00:41,000
+واحدة لو اطلعنا هنلاقي ان ال aldehydes و ال
+
+5
+00:00:41,000 --> 00:00:47,000
+ketones هم جزء من عائلة اكبر جزء من عائلة اكبر
+
+6
+00:00:47,000 --> 00:00:53,230
+اسمهاالكربونيل containing compounds يعني المركبات
+
+7
+00:00:53,230 --> 00:00:56,870
+اللى بتحتوي على مجموعة الكربونيل الان ايش مجموعة
+
+8
+00:00:56,870 --> 00:01:02,490
+الكربونيل مجموعة الكربونيل هي ال C double bond O
+
+9
+00:01:02,490 --> 00:01:08,130
+واضح ال C double bond O هي المجموعة اللى اسمها ايش
+
+10
+00:01:08,130 --> 00:01:15,110
+كربونيلالان كتير في مراكبات .. كتير في مراكبات
+
+11
+00:01:15,110 --> 00:01:19,530
+فيهم هذه المجموعة الـ C double bond O يعني من هدول
+
+12
+00:01:19,530 --> 00:01:23,910
+المراكبات الـ aldehydes لما يكون عند الـ C double
+
+13
+00:01:23,910 --> 00:01:28,970
+bond O مجموعة R وH على الجهة التانية منهم الـ
+
+14
+00:01:28,970 --> 00:01:32,110
+ketones لما تكون الـ C double bond O محشورة بين
+
+15
+00:01:32,110 --> 00:01:36,990
+مجمعتين Rمنهم الـ Carboxylic Acids الـ C double
+
+16
+00:01:36,990 --> 00:01:41,750
+bond O متصلة بـ OH الان المراكبات اللي ضايلة
+
+17
+00:01:41,750 --> 00:01:46,030
+بنسميها مشتقات من الـ Carboxylic Acids منها الـ E
+
+18
+00:01:46,030 --> 00:01:49,970
+star C double bond O OR منها الامد C double bond O
+
+19
+00:01:49,970 --> 00:01:57,970
+NH2 منها ال Acid C double bond OCL وفي كمان مركب
+
+20
+00:01:57,970 --> 00:02:03,030
+أيضا موجود ومشهور ولو مش مكتوب هنا R C double bond
+
+21
+00:02:03,030 --> 00:02:09,150
+O O C double bond O R تانية هذا بنسميه acid
+
+22
+00:02:09,150 --> 00:02:15,610
+anhydride بنسميه acid anhydride
+
+23
+00:02:17,770 --> 00:02:23,130
+الان اللى بتطلع على هذه العائلة الكبيرة كتير خلينا
+
+24
+00:02:23,130 --> 00:02:27,630
+نسميه عائلة ال carbonyl compounds هيلحظ انه احنا
+
+25
+00:02:27,630 --> 00:02:31,890
+صارنا بنحكي عن عائلات فرعية موجودة فيها واحد اتنين
+
+26
+00:02:31,890 --> 00:02:38,890
+تلاتة اربع خمسة ستةسبعة يعني عدد كبير من العائلات
+
+27
+00:02:38,890 --> 00:02:42,710
+الفرعية جوا العائلة العاملة هي عائلة الاش ال
+
+28
+00:02:42,710 --> 00:02:46,390
+carbonyl compounds المركبات اللي بتحتوي على مجموعة
+
+29
+00:02:46,390 --> 00:02:53,690
+ال C double bond O لحسن الحظ ان هدول العائلات
+
+30
+00:02:54,350 --> 00:03:01,030
+يقسموا أو يجمعوا إلى عائلتين ال الديهيدس والكيتونز
+
+31
+00:03:01,030 --> 00:03:04,790
+في كل كتب الكيميا العضوية بتلاقوهم محطوطين مع بعض
+
+32
+00:03:04,790 --> 00:03:11,170
+في شبتر واحد والأحماض ومشتقاتها بنسميها assets and
+
+33
+00:03:11,170 --> 00:03:15,710
+their derivatives ال acid derivatives يعني هدولة
+
+34
+00:03:15,710 --> 00:03:19,290
+derivatives لل acid مشتقات derivative يعني إيش؟
+
+35
+00:03:19,970 --> 00:03:25,510
+الاسد ديريفاتيف لو قلنا لكم شو هم الاستر الامد
+
+36
+00:03:25,510 --> 00:03:32,190
+الاسد هيلايد والاسد انهيدريد هدولة الخمسة بنحط
+
+37
+00:03:32,190 --> 00:03:38,330
+بعيلة واحدةلاحظوا صار عندى تقسيم بدل ما هو ل سبع
+
+38
+00:03:38,330 --> 00:03:43,370
+عائلات كلها مختلفة حاطناهم بإيش؟ بعائلتين فقط
+
+39
+00:03:43,370 --> 00:03:48,850
+الهيتز و الفيتون عائلة الاسيتز و مصادرهم كلهم دول
+
+40
+00:03:48,850 --> 00:03:53,290
+عائلة و لذلك عادة في الكيميا العضوية في غالب الكتب
+
+41
+00:03:53,290 --> 00:03:56,630
+هتلاقي انه بنعمل عن كل هذه المركبات chapter يعني
+
+42
+00:03:56,630 --> 00:04:01,490
+فاصلين هدول بنحطه بفصل لحالهم و هدول بنحطه بفصل
+
+43
+00:04:01,490 --> 00:04:02,710
+لحالهم
+
+44
+00:04:05,560 --> 00:04:10,240
+لسه بإمكاننا نبسط الموضوع بإمكاننا نبسط الموضوع
+
+45
+00:04:10,240 --> 00:04:16,230
+أكثر كثير من هيكنقول ليش هذه التقسيمة و كيف أنا
+
+46
+00:04:16,230 --> 00:04:20,450
+الاشي الكتير بدي أسهل التعامل معه بنقول هذه
+
+47
+00:04:20,450 --> 00:04:26,050
+التقسيمة قائمة على كلمتين فقط كلمتين اللي بيفهم
+
+48
+00:04:26,050 --> 00:04:31,150
+دول الكلمتين بنقدر نقول عنه أنه فيهم ست إلى سبع
+
+49
+00:04:31,150 --> 00:04:36,090
+محاضرات للأمام هنضلنا نعيد و نزيد فيهم بنفس
+
+50
+00:04:36,090 --> 00:04:42,790
+الكلمتينواضح؟ صعب على البني آدم يفهم كلمتين كان
+
+51
+00:04:42,790 --> 00:04:48,130
+زمان برنامج بالتلفزيون بالإذاعة اسمه كلمتين و بس
+
+52
+00:04:48,130 --> 00:04:52,630
+خلوه و ميرك معاكم مين اللي كان يقدم هذا البرنامج
+
+53
+00:04:52,630 --> 00:04:58,330
+زمان اسأله الآباء والأجداد المهم ايش الكلمتين
+
+54
+00:04:58,330 --> 00:05:06,290
+المرتبطات بكل هذه العائلات الكلمة الأولىخاصة بأهم
+
+55
+00:05:06,290 --> 00:05:12,070
+تفاعل أساسي لهدول المركبات اللي هم ال aldehydes و
+
+56
+00:05:12,070 --> 00:05:19,630
+ال ketones بيتفاعلوا تفاعل ال addition الإضافة ال
+
+57
+00:05:19,630 --> 00:05:24,730
+addition و الكلمة التانية لهدول الخمسة اللي ضايقين
+
+58
+00:05:24,730 --> 00:05:29,750
+معهم ال unhydrate اللي شطبناه بتفاعلوا تفاعل ال
+
+59
+00:05:29,750 --> 00:05:32,930
+substitution الإبدال تمام؟
+
+60
+00:05:37,060 --> 00:05:43,120
+إذن سبب تقسيم هدول السبع مركبات إلى عائلات يعني
+
+61
+00:05:43,120 --> 00:05:46,440
+أحيانا الإنسان كان ممكن يسأل إذا السبعة بدنا
+
+62
+00:05:46,440 --> 00:05:50,180
+نعملهم عيلتين أو شبترين كان خلينا أربعة في شبتر
+
+63
+00:05:50,180 --> 00:05:56,620
+وتلاتة في شبتر تاني ليش خلينا اتنين وخمسة تمام؟ لأ
+
+64
+00:05:56,620 --> 00:06:03,470
+التقسيم مش تقسيم عددي التقسيم تقسيم وظيفي بمعنىإيش
+
+65
+00:06:03,470 --> 00:06:10,370
+التفاعل الأساسي لهذه العائلة هو تفاعل الإضافة؟ إيش
+
+66
+00:06:10,370 --> 00:06:16,450
+التفاعل الأساسي لهذه العائلة هو تفاعل الإبدال؟
+
+67
+00:06:16,450 --> 00:06:21,310
+ولذلك لو أي طالب organic chemistry بده يدخل مقابل
+
+68
+00:06:21,310 --> 00:06:25,510
+التوظيف، مانعش يمسك ورق و جلم و يكتب، لكن أبسط
+
+69
+00:06:25,510 --> 00:06:29,510
+سؤال بده يسأله ببساطة إيش التفاعل الأساسي
+
+70
+00:06:29,510 --> 00:06:33,660
+للالدهايتز والكيتونز؟ماعرفش يجاوب ايش التفاعل
+
+71
+00:06:33,660 --> 00:06:38,720
+الأساسي لل assets ومش رقاتها ماعرفش يجاوب نراكم في
+
+72
+00:06:38,720 --> 00:06:43,750
+السنة القادمةبالزمش يكون دراسة organic واضح اهتموا
+
+73
+00:06:43,750 --> 00:06:48,950
+كتير بهدول الكلمتين اللي بيفهموهم جيدا بيكونوا
+
+74
+00:06:48,950 --> 00:06:53,530
+فاهموا سبع عائلات اللي بيفهموا دول الكلمتين جيدا
+
+75
+00:06:53,530 --> 00:06:58,350
+بيكونوا فاهموا ايش سبع عائلات ولذلك خلينا نتعمق
+
+76
+00:06:58,350 --> 00:07:03,070
+اكتر بفهم هدول الكلمتين خلينا نتعمق اكتر بفهم هدول
+
+77
+00:07:03,070 --> 00:07:07,280
+الكلمتين الان احنا قولنا ايش ال carbonyl groupالـ
+
+78
+00:07:07,280 --> 00:07:11,960
+C double bond O طب لو كتبنا تحت الكربونيل C double
+
+79
+00:07:11,960 --> 00:07:17,120
+bond O ورجعنا للكلام اللي بنعرفه بخصوص السالبية
+
+80
+00:07:17,120 --> 00:07:22,640
+مين أكثر سالبية؟ ال oxygen مين أقل سالبية؟ ال
+
+81
+00:07:22,640 --> 00:07:26,880
+carbon إذا هذه ال carbon partially positive و هذه
+
+82
+00:07:26,880 --> 00:07:32,180
+ال oxygen partially negative واضح؟ الآن المحور
+
+83
+00:07:32,180 --> 00:07:36,410
+الأساسيفي فهم الكيميا كاملة تبعتي السبع عائلات
+
+84
+00:07:36,410 --> 00:07:43,210
+هدولة بينطلق من انه ال carbon موجبة يعني يمكن أهم
+
+85
+00:07:43,210 --> 00:07:49,530
+كلمة في فهم هذه العائلات السبعة كلها مجتمعة يعني
+
+86
+00:07:49,530 --> 00:07:54,250
+في فهم ال two chapters ان نقول ان هذا ال carbon
+
+87
+00:07:54,250 --> 00:07:59,030
+هاي بدنا نعلمها فيهم كلهم باللون الأحمر اشمالها
+
+88
+00:07:59,030 --> 00:08:07,920
+موجبةالان من باب تحصيل الحاصل الموجب لما يتفاعل ..
+
+89
+00:08:07,920 --> 00:08:14,280
+بنفتح بس على واحدة منهم الموجب لما يتفاعل ايش بده؟
+
+90
+00:08:14,280 --> 00:08:20,460
+بلغة الكيميا ال يوكليوفالالموجب لما يتفاعل بده
+
+91
+00:08:20,460 --> 00:08:24,980
+سالب بده نيوكليوفايل بناء على ذلك طالما جميعهم
+
+92
+00:08:24,980 --> 00:08:29,260
+عندهم ال carbon الموجبة إذا جميعهم تفاعلهم الأساسي
+
+93
+00:08:29,260 --> 00:08:33,580
+بيستنوا نيوكليوفايل واضح؟ يعني بدي أجيب ان
+
+94
+00:08:33,580 --> 00:08:40,360
+نيوكليوفايل و هذا عليه زوجمن الالكترونات زي ما
+
+95
+00:08:40,360 --> 00:08:43,500
+انتوا عارفين سواء كان مشحون او متعادل مش موضوعنا
+
+96
+00:08:43,500 --> 00:08:47,480
+.. وين بده يروح يجري يهاجم ال nucleophile على ال
+
+97
+00:08:47,480 --> 00:08:52,420
+carbon نفس ال nucleophile .. نفس ال nucleophile
+
+98
+00:08:52,420 --> 00:08:59,670
+على ال carbonالان هذا الـ nucleophile لما بيهاجم
+
+99
+00:08:59,670 --> 00:09:04,370
+على الكربون مرة هيعمل تفاعل إضافة في الحالتين
+
+100
+00:09:04,370 --> 00:09:08,870
+الأولانيات و في باقى الحالات هيعمل تفاعل إبدال إذا
+
+101
+00:09:08,870 --> 00:09:13,530
+لو جينا سألناكم قولنا لكم ال aldehydes بيعملوا
+
+102
+00:09:13,530 --> 00:09:19,150
+addition بتقولوا صحو ال acids و المشتقاتة بيعملوا
+
+103
+00:09:19,150 --> 00:09:24,510
+substitution صح لو سألنا هل يا ترى ال eucleophilic
+
+104
+00:09:24,510 --> 00:09:27,850
+addition و ال eucleophilic substitution ولا ال
+
+105
+00:09:27,850 --> 00:09:30,630
+electrophilic addition و ال electrophilic
+
+106
+00:09:30,630 --> 00:09:35,440
+substitution؟ ال eucleophilicإذن الآن بنقدر نزيد
+
+107
+00:09:35,440 --> 00:09:40,440
+كلمة إن ال الديهايدز تفاعلهم الأساسي اللي بديها
+
+108
+00:09:40,440 --> 00:09:45,340
+بالظبط الـ Eucleophilic addition وفهمنا ليش؟ ال
+
+109
+00:09:45,340 --> 00:09:50,460
+Eucleophilic addition و الأحماض و مشتقاتها تفاعلهم
+
+110
+00:09:50,460 --> 00:09:56,390
+الأساسي ال Eucleophilic substitution واضح؟لحد الآن
+
+111
+00:09:56,390 --> 00:10:02,230
+تمام الان بيصير ايش الناتج اللى بده يتكون عندى ايش
+
+112
+00:10:02,230 --> 00:10:06,510
+الناتج اللى بده يتكون في حالة ما كنا بنحكي عن ال
+
+113
+00:10:06,510 --> 00:10:10,870
+aldehydes و ال ketones addition معناه ان ال C
+
+114
+00:10:10,870 --> 00:10:15,070
+double bond O او ال double bond تصير single bondمش
+
+115
+00:10:15,070 --> 00:10:18,050
+هيك احنا قولنا ال addition يعني مجرد ماذا ال
+
+116
+00:10:18,050 --> 00:10:21,830
+nucleophile يهاجم هنا ويعمل رابطة هل معقول يصير
+
+117
+00:10:21,830 --> 00:10:26,290
+عندي خمس روابط؟ لأ، إذا هذه الرابطة بتتحرك تصبح O
+
+118
+00:10:26,290 --> 00:10:31,470
+minus بتصفح OH بتاخد H من اللي ال nucleophile أو
+
+119
+00:10:31,470 --> 00:10:36,310
+من ال solvent إذا الناتج اللي هيصير عندي ناتج ال
+
+120
+00:10:36,310 --> 00:10:40,310
+addition ببساطة إنه سيضة بال bond O تبعت ال ketone
+
+121
+00:10:40,310 --> 00:10:43,830
+أو تبعت ال aldehyde شو بده تصير؟ OH
+
+122
+00:10:46,820 --> 00:10:50,500
+شوفت وين ال addition هنا تم ال addition double
+
+123
+00:10:50,500 --> 00:10:56,980
+single إضافة شو هو ال addition تحويل ال double
+
+124
+00:10:56,980 --> 00:11:00,520
+bond إلى single bond إذا في ال aldehydes و ال
+
+125
+00:11:00,520 --> 00:11:05,060
+ketones ال C double bond O هتصير OH طبّاق
+
+126
+00:11:05,060 --> 00:11:12,240
+المجموعات R زي ما هي H أو R زي ما هي و اللي إجه
+
+127
+00:11:12,240 --> 00:11:14,900
+هنا ال nucleophile
+
+128
+00:11:17,240 --> 00:11:20,840
+مشهور الـ nucleophile اللي هاجمه عام الرابط إذا
+
+129
+00:11:20,840 --> 00:11:26,440
+هذا الشكل العام تبع نتيجة تفاعل ال الديهيد أو ال
+
+130
+00:11:26,440 --> 00:11:30,400
+ketones يعني لو إجينا قولنا مثلا لل nucleophile
+
+131
+00:11:30,400 --> 00:11:32,900
+H2O
+
+132
+00:11:35,400 --> 00:11:39,820
+ماذا سيحصل؟ هذه في كل الأحوال ستصبح OH مع كل أنواع
+
+133
+00:11:39,820 --> 00:11:44,040
+الـ nucleophiles لكن الـ H2O ماذا تضع هنا؟ OH
+
+134
+00:11:44,040 --> 00:11:48,140
+دائما الـ nucleophile المتعدد سنخصه من OH ولو قلنا
+
+135
+00:11:48,140 --> 00:11:53,420
+لـ nucleophile OH-, سيضع أيضًا OH و بعد ذلك نضع
+
+136
+00:11:53,420 --> 00:11:57,880
+acid ستصبح هذه OH إذا لو لـ nucleophile H2O أو H-,
+
+137
+00:11:57,880 --> 00:12:02,700
+سيصبح عندكم على الكربون OH من الألديهيد الأصلي و
+
+138
+00:12:02,700 --> 00:12:10,190
+OHالمهاجمة لو النيوكليوفايل الكهول شوف دي جهانة OR
+
+139
+00:12:10,190 --> 00:12:17,210
+هذه OH لا خلافة فيها ثابتة هذه ثابتة اللي هي ال C
+
+140
+00:12:17,210 --> 00:12:20,290
+double bond O لكن أنا بقول النيوكليوفايل الميا
+
+141
+00:12:20,290 --> 00:12:29,950
+بتحط OH الكحول بيحط OR ال HCl بيحط Cl و هكذا واضحة
+
+142
+00:12:29,950 --> 00:12:36,010
+الفكرة؟هي هذا الشكل العام تبع تفاعل إضافة وهو الذي
+
+143
+00:12:36,010 --> 00:12:41,130
+يميز جميع تفاعلات ال device و ال ketones و هناخد
+
+144
+00:12:41,130 --> 00:12:46,210
+أمثلة تصير كلها تكرار نضل نعيد يقول بيعمل إضافة و
+
+145
+00:12:46,210 --> 00:12:52,290
+بس في كل الأمثلة اللي بناخدها إيش بتصير القصة؟هنا
+
+146
+00:12:52,290 --> 00:12:55,470
+نقول ايه شو هو لليوكليوفايل؟ اذا كان ليوكليوفايل
+
+147
+00:12:55,470 --> 00:12:58,450
+ماء فهذه كذا، اذا كان الكول هذه كذا، اذا كان
+
+148
+00:12:58,450 --> 00:13:02,870
+سياناد كذا، اذا كان هايدرايد هذه كذا، يعني فقط هذا
+
+149
+00:13:02,870 --> 00:13:07,450
+المتغير الوحيد حيصفى عندكم شو هو ليوكليوفايل؟
+
+150
+00:13:07,450 --> 00:13:13,950
+واضح؟ الان لو اجينا وقلنا نفس ليوكليوفايل بده
+
+151
+00:13:13,950 --> 00:13:20,770
+يهاجم علىالكيتون على الكربون الحمراء عفوا على
+
+152
+00:13:20,770 --> 00:13:24,870
+الاسد لأ ما هو الكيتون زي الألدياد خلصنا منه على
+
+153
+00:13:24,870 --> 00:13:31,630
+الاسد أو مشتقاته إيش بيكون التفاعل؟ هذا بيجي هنا و
+
+154
+00:13:31,630 --> 00:13:38,020
+يطرد المجموعة هذهواضح؟ طبعا O H minus لما تترد
+
+155
+00:13:38,020 --> 00:13:43,920
+تاخد H من برا شو هتصير؟ O R minus لما تترد تاخد H
+
+156
+00:13:43,920 --> 00:13:51,460
+R O H كحول N H 2 لما تترد N H 3 C L minus لما يترد
+
+157
+00:13:51,460 --> 00:13:57,140
+C L اذا صار عندى هذه المجموعة هي اللتي تستبدل اللى
+
+158
+00:13:57,140 --> 00:14:03,380
+جنب ايش اللى جنب الصيغة بال bond O بناء على ذلك
+
+159
+00:14:03,380 --> 00:14:09,940
+الناتج ايش هيكون؟R C double bond O هذه ما زالت زي
+
+160
+00:14:09,940 --> 00:14:15,140
+ما هي لكن بدل ال OH او ال OR او ال NH2 whatever
+
+161
+00:14:15,140 --> 00:14:21,120
+whatever صار إبدال enucleophile نيو ن أيه صوديوم
+
+162
+00:14:21,120 --> 00:14:25,480
+نيوكليوفايل واضح يعني شيلنا هذه المجموعة و حطينا
+
+163
+00:14:25,480 --> 00:14:29,880
+مكانها إيش نيوكليوفايل هذا substitution ولا لأ
+
+164
+00:14:29,880 --> 00:14:35,430
+مجموعة جاية مجموعة طالعةواضحك الفكرة و الجزء اللي
+
+165
+00:14:35,430 --> 00:14:39,390
+طلع بياخد H بطلع على شكل ماء على شكل أمونيا على
+
+166
+00:14:39,390 --> 00:14:45,380
+شكل كحول على شكل HClهذا الكلام بتلاقوه بتكرر في كل
+
+167
+00:14:45,380 --> 00:14:50,660
+عائلات الأحماض ومشتقاتها إذا لو احنا كنا حتى
+
+168
+00:14:50,660 --> 00:14:55,280
+chapter 9 هذا اللي بدنا نبدأ فيه بدنا نعطيه عنوان
+
+169
+00:14:55,280 --> 00:14:59,820
+جديد ال dehydes and ketones بين قصين إيش بدنا نكتب
+
+170
+00:14:59,820 --> 00:15:04,300
+ال eucleophilic addition لو كنا في chapter 10 بدنا
+
+171
+00:15:04,300 --> 00:15:08,460
+نقول acids and their derivatives بين قصين ال
+
+172
+00:15:08,460 --> 00:15:12,910
+eucleophilic substitutionاللي فهموا هدولا الكلمتين
+
+173
+00:15:12,910 --> 00:15:19,430
+جيدا واتدربوا عليهم بيقدروا يتريحوا أربع أو خمس
+
+174
+00:15:19,430 --> 00:15:24,370
+محاضرات جاية خلاص بيصيروا بس بتذكروا الكلام اللي
+
+175
+00:15:24,370 --> 00:15:29,230
+قاله الشاعر الجاهلي ما ترانا نقوله إلا معادا من
+
+176
+00:15:29,230 --> 00:15:36,720
+قولنا .. إيش؟ مكرورةبس بنبقى بنقول addition of
+
+177
+00:15:36,720 --> 00:15:42,640
+chapter يعني هتشبعه من كلمة addition of chapter
+
+178
+00:15:43,830 --> 00:15:47,630
+وتشبعوا من كلمة substitution in chapter واضحة
+
+179
+00:15:47,630 --> 00:15:53,230
+الفكرة ما عدا ذلك بيصير كله بالنسبة لنا رتوش بسيطة
+
+180
+00:15:53,230 --> 00:15:56,390
+يعني كيف نسمي ال aldehydes ال ketones إيش أشهر ما
+
+181
+00:15:56,390 --> 00:16:00,590
+هو موجود فيها إيش تطبيقاتها كله تعتبر أشياء بسيطة
+
+182
+00:16:00,590 --> 00:16:06,110
+الفكرة الأساسية لعبلة التصنيف هي متعلقة بطبيعة
+
+183
+00:16:06,110 --> 00:16:13,100
+التفاعل الأساسي لكل عائلة واضحة هذه الفكرةالان لو
+
+184
+00:16:13,100 --> 00:16:18,580
+اتينا مثلا لخواص ال aldehydes و ال ketones بشكل
+
+185
+00:16:18,580 --> 00:16:24,580
+عام لاحظوا كتب عنهم moderately polar يعني متوسطي
+
+186
+00:16:24,580 --> 00:16:30,840
+القطبية الان هو يقارن بين ايش؟ بين شغلتين بين ال R
+
+187
+00:16:30,840 --> 00:16:35,140
+اللي هي ال alkanes لحالها اللي فيها ال London
+
+188
+00:16:35,140 --> 00:16:44,180
+forces و بين ال alcohols اللي فيها ال OHواضح؟ ال
+
+189
+00:16:44,180 --> 00:16:48,480
+alcohols اللي فيها ال OH هيدروجين bonding واضحة
+
+190
+00:16:48,480 --> 00:16:53,080
+الفكرة؟ هنا إيش نوع ال bonding؟ هيدروجين bonding
+
+191
+00:16:53,080 --> 00:17:01,480
+ممتاز وفي ال alkanes لندن forces طب في الألدهات و
+
+192
+00:17:01,480 --> 00:17:03,780
+ال ketones اللي إلها partial positive و partial
+
+193
+00:17:03,780 --> 00:17:08,280
+negative Dipole-dipole attraction اللي تيجي in
+
+194
+00:17:08,280 --> 00:17:16,870
+between Dipole-dipole اللي هيبالظبطواللي ال
+
+195
+00:17:16,870 --> 00:17:20,510
+hydrogen bonding أقوى أنواعها وبناء على ذلك هم
+
+196
+00:17:20,510 --> 00:17:24,610
+أصبحوا moderately polar الان كونهم moderately
+
+197
+00:17:24,610 --> 00:17:28,890
+polar هذا الكلام على طول بنعكس على ايش؟ على نقطة
+
+198
+00:17:28,890 --> 00:17:34,290
+الغليان على نقطة الغليان يعني مثلا لو احنا بدنا
+
+199
+00:17:34,290 --> 00:17:39,270
+نيجي نعمل مقارنة بدنا نيجي نعمل مقارنة بين أشياء
+
+200
+00:17:39,270 --> 00:17:46,320
+شبه متساوية شبه متساوية في الوزن الجزائييعني خدوا
+
+201
+00:17:46,320 --> 00:17:55,400
+على سبيل المثال الميثانول ايش صيغته العامة CH3OH
+
+202
+00:17:55,400 --> 00:18:07,020
+خدوا على سبيل المثال ال formaldehyde CH3OH
+
+203
+00:18:07,020 --> 00:18:08,000
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+204
+00:18:08,000 --> 00:18:11,180
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+205
+00:18:11,180 --> 00:18:12,160
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+206
+00:18:12,160 --> 00:18:12,260
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+207
+00:18:12,260 --> 00:18:18,210
+CH3OH CH3OH CH3CH3 CH3 هدول التلت مركبات يكاف
+
+208
+00:18:18,210 --> 00:18:22,910
+يكونوا متساويين في إيش؟ في الوزن الجزية لو حسبته
+
+209
+00:18:22,910 --> 00:18:29,330
+هنا اتناش و تلاتة خمستاش و ستاش و ستاش، كدش هنا
+
+210
+00:18:29,330 --> 00:18:34,170
+الوزن؟ اتنين و تلاتين لو أجينا على ال formaldehyde
+
+211
+00:18:34,170 --> 00:18:42,130
+ستاش و اتناش و اتنينتلاتين لو اجينا على هذا خمستعش
+
+212
+00:18:42,130 --> 00:18:46,430
+خمستعش تلاتين يعني يكاد يكون ال molecular weight
+
+213
+00:18:46,430 --> 00:18:54,350
+لهم ايش ماله متساوي لكن لو اجينا لو اجينا ل .. ال
+
+214
+00:18:54,350 --> 00:18:58,570
+boiling point لهم التلاتة مين اعلى واحد هيكون
+
+215
+00:18:58,570 --> 00:19:05,490
+الكحول الكحول boiling point خمسة وستينالميثانول
+
+216
+00:19:05,490 --> 00:19:14,670
+هذا الاثانول بيعلق بيصير قداش تقريبا 78 اه الان لو
+
+217
+00:19:14,670 --> 00:19:19,750
+اجينا على ال formaldehyde ال formaldehyde غاز لكن
+
+218
+00:19:19,750 --> 00:19:23,710
+مش كتير منخفضة نقطة غليانه يعني قوله مثلا ناقص
+
+219
+00:19:23,710 --> 00:19:27,370
+عشرين انا مش متأكد بإمكانكوا تبحثوا عنها او نجيبها
+
+220
+00:19:27,370 --> 00:19:32,290
+مرة تانية تعالوا على الاثانهتلاقو ناجس 100 ولا
+
+221
+00:19:32,290 --> 00:19:38,130
+ناجس 120 تقريبا هانا بحثوا تطلعوا كيف ال boiling
+
+222
+00:19:38,130 --> 00:19:41,970
+point بتتغير إذا ال boiling point مرتبطة بإيش
+
+223
+00:19:41,970 --> 00:19:46,350
+مرتبطة بالقطبية بس هذه القيم خليني أقول تقريبية
+
+224
+00:19:46,350 --> 00:19:51,190
+ممكن مرة تانية نجيب القيم الدقيقة واضحة الفكرة ف
+
+225
+00:19:51,190 --> 00:19:57,930
+ال polarity أطول إلى انعكاس علىالقطبية الان طيب و
+
+226
+00:19:57,930 --> 00:20:03,370
+الان عكس على شغل تاني البولاريكي شو هي الذائبية و
+
+227
+00:20:03,370 --> 00:20:09,470
+القاعدة العامة في الموضوع ايش like dissolves like
+
+228
+00:20:09,470 --> 00:20:15,950
+الان اكتر حاجة فيها قطبية ايش الكحولات اللي فيها O
+
+229
+00:20:15,950 --> 00:20:20,190
+H's و بتذكروا حتى لما قلنا عن الكحولات قلنا
+
+230
+00:20:20,190 --> 00:20:26,280
+مابدناش ننسى ان الكحولفي المجمعتين في الجزء القطبي
+
+231
+00:20:26,280 --> 00:20:33,200
+ال R والجزء القطبي ال OH والجزء غير القطبي ال R
+
+232
+00:20:33,200 --> 00:20:37,020
+وبناء على ذلك ال lower alcohols كانت water soluble
+
+233
+00:20:37,020 --> 00:20:42,000
+وال higher alcohols كانت water solubleتذكرين هذه
+
+234
+00:20:42,000 --> 00:20:46,180
+المعلومة؟ الكلام نفسه بتكرر وين؟ في ال ketones
+
+235
+00:20:46,180 --> 00:20:50,400
+برضه ال ketones فيهم جزء قطبة ال C double bond O و
+
+236
+00:20:50,400 --> 00:20:54,780
+فيهم ال R لما تصير ال R هذه كبيرة بيبطلوا يدوبوا
+
+237
+00:20:54,780 --> 00:20:57,840
+في الميه بس R صغيرة يعني مثل و مثل بيصير ال
+
+238
+00:20:57,840 --> 00:21:03,660
+acetone ال acetone بدوب في الميهلكن خلوها إثل و
+
+239
+00:21:03,660 --> 00:21:07,760
+إثل، إبروبل و إبروبل، فينل و إثل، كبرت، بتبطل
+
+240
+00:21:07,760 --> 00:21:12,140
+الدوب في المياه، واضح؟ فال lower molecular weight
+
+241
+00:21:12,140 --> 00:21:14,540
+species، يعني الأشياء اللي ال molecular weight
+
+242
+00:21:14,540 --> 00:21:18,560
+فيها إجليل في الأذيهات والكيتونز، بتكون إيش؟ water
+
+243
+00:21:18,560 --> 00:21:23,320
+soluble، كل ما ال R كبرت، بتبطل، يعني زي زي إيش؟
+
+244
+00:21:23,320 --> 00:21:27,720
+الكحولاتفمن ال الديهيدس اللي بيدوبوا في الميا بشكل
+
+245
+00:21:27,720 --> 00:21:30,600
+عام ال formaldehyde بيدوب في الميا بيعطي ال
+
+246
+00:21:30,600 --> 00:21:34,340
+formalin ال acetaldehyde نسبيا بيدوب بعد هيك بيبطل
+
+247
+00:21:34,340 --> 00:21:38,000
+يدوب من ال ketones ال acetone بيدوب في الميا بعد
+
+248
+00:21:38,000 --> 00:21:43,270
+هيكلما يكبروا ببطله يدوبوا واضح فال low molecular
+
+249
+00:21:43,270 --> 00:21:45,830
+weight species are soluble in water and the
+
+250
+00:21:45,830 --> 00:21:50,270
+solubility decreases بتنقص as the R chain gets
+
+251
+00:21:50,270 --> 00:21:54,570
+longer كل ما كبرت ال R كل ما قلت التأبية وهذا
+
+252
+00:21:54,570 --> 00:21:58,710
+الكلام أيضا في الكحولات لاحظنا واضح الفكرة هذا
+
+253
+00:21:58,710 --> 00:22:02,710
+الكلام أيضا لاحظنا في الكحولات
+
+254
+00:22:06,830 --> 00:22:09,910
+طيب كيف بنسمي ال الديهايد و ال ketones؟ احنا قولنا
+
+255
+00:22:09,910 --> 00:22:14,510
+أساسا كل نظام التسمية في الكيميا العضوية نظام سهل
+
+256
+00:22:14,510 --> 00:22:20,230
+ليش سهل؟ لأنه مبني على ذكر طول السلسلة منتهي برمز
+
+257
+00:22:20,230 --> 00:22:28,770
+للمجموعة الوظيفية ال ال K نهايته L E I O للكحول ال
+
+258
+00:22:28,770 --> 00:22:35,330
+L ل ال الديهايد L و ل ال ketone Oوالذلك ال الديهيد
+
+259
+00:22:35,330 --> 00:22:40,670
+اللى متكون من كربونة واحدة بنقول مثانال مثانال
+
+260
+00:22:40,670 --> 00:22:45,130
+ماخد common name formaldehyde الان لو صاروا
+
+261
+00:22:45,130 --> 00:22:51,120
+كربونتينإيه ثانال؟ أسيتالديهيد الكمونومتينام لو
+
+262
+00:22:51,120 --> 00:22:56,400
+صاروا تلاتة بروبانال بروبيونالديهيد لو صاروا أربعة
+
+263
+00:22:56,400 --> 00:23:01,860
+بيوتانال بيوتيرالديهيد بيوتيرالديهيد الآن لاحظوا
+
+264
+00:23:01,860 --> 00:23:07,320
+هتلاحظوا الفرقبين ال aldehydes و الكحولات يعني في
+
+265
+00:23:07,320 --> 00:23:11,520
+الكحول كنا نقول ethanol, methanol, ethanol,
+
+266
+00:23:11,620 --> 00:23:15,320
+propanol, butanol وهنا بنقول methanol, ethanol,
+
+267
+00:23:15,440 --> 00:23:20,740
+propanol, butanol وين الفرق؟ لأ في فرق تاني أنا
+
+268
+00:23:20,740 --> 00:23:24,760
+عارف ال all و ال al هذه الفرق لكن في فرق تاني
+
+269
+00:23:24,760 --> 00:23:32,360
+الاسم كامل هنافي الكحولات لما أجي أقول بروبانول
+
+270
+00:23:32,360 --> 00:23:36,440
+بكفي؟
+
+271
+00:23:36,440 --> 00:23:42,640
+آه الكحول تلت ذرات كربون الآن هل يتر الأو اتش فيه
+
+272
+00:23:42,640 --> 00:23:47,480
+على واحد؟ one probanol و لا على اتنين؟ two
+
+273
+00:23:47,480 --> 00:23:52,360
+probanol واضح؟ إذا البروبانول في الكحولات منه
+
+274
+00:23:52,360 --> 00:23:59,290
+اتنين و البيوتانول كمان لو صار هذه اربع كربوناتهل
+
+275
+00:23:59,290 --> 00:24:05,490
+الكحول هنا one بيوتانول
+
+276
+00:24:05,490 --> 00:24:10,050
+ولا two بيوتانول ولا two بيوتانول من هنا مش تلاتة
+
+277
+00:24:10,050 --> 00:24:18,590
+ال بيوتانول منه كم الكحول واضح؟ لتشين المتسلسل
+
+278
+00:24:18,590 --> 00:24:23,430
+يعني لو اجاكوا سؤال في الامتحان انه لتشين بيوتانول
+
+279
+00:24:23,430 --> 00:24:30,280
+اللي زي هيك كم كحول بالمجمل منه اتنينهك هتكون
+
+280
+00:24:30,280 --> 00:24:34,660
+جوابته غلط واضح؟
+
+281
+00:24:34,660 --> 00:24:41,060
+ليش؟ مين تقول لي ليش الغلط؟
+
+282
+00:24:41,060 --> 00:24:47,860
+لحظة أنا قلت المتسلسل، بعرف أنه في ISO و في
+
+283
+00:24:47,860 --> 00:24:53,750
+tertiary، هذه قصة تانيةما بدكوا تظلوا تعودوا اه ال
+
+284
+00:24:53,750 --> 00:24:55,910
+chiral center مش ال cis و ال trans ال cis و ال
+
+285
+00:24:55,910 --> 00:24:58,910
+trans كل ما يلي علاقة بالضبط بالبونس و بالحلقات ال
+
+286
+00:24:58,910 --> 00:25:03,870
+chiral center لما بيصير هذا هنا و بحط O H و H ع
+
+287
+00:25:03,870 --> 00:25:08,510
+طول صار عندى ROS من ال two butanol ال two butanol
+
+288
+00:25:08,510 --> 00:25:12,390
+منه ROS ال one butanol مافيش فيه chiral center one
+
+289
+00:25:12,390 --> 00:25:18,170
+butanolواضح؟ طبعا ما بننساش أنه فيه isobutanol و
+
+290
+00:25:18,170 --> 00:25:22,790
+tertiarybutanol كل هدول الأشياء لازم تكونوا
+
+291
+00:25:22,790 --> 00:25:27,470
+عارفينها الان ال aldehydes اللي جابنا للكلام ال
+
+292
+00:25:27,470 --> 00:25:32,190
+aldehydes لأ مافيش منها واحد و اتنين لأن مجموعة ال
+
+293
+00:25:32,190 --> 00:25:36,730
+aldehydes لا تكون الا على نمرة واحد و لانها لا
+
+294
+00:25:36,730 --> 00:25:41,310
+تكون الا على نمرة واحد بنحط ال hash رقميعني ما
+
+295
+00:25:41,310 --> 00:25:46,110
+إجيناش كتبنا إيثان وان قالب روبان وان قالب يوتان
+
+296
+00:25:46,110 --> 00:25:49,510
+وان قالب لأنها لا تكون إلا على واحد فالاشي اللي
+
+297
+00:25:49,510 --> 00:25:54,830
+معروف ضلنا بلزم نكتبه واضح؟ ومثل ال الديهايد
+
+298
+00:25:54,830 --> 00:25:59,210
+بالمناسبة اللي ما بيكونش إلا على نمرة واحد وفقط
+
+299
+00:25:59,210 --> 00:26:07,770
+على واحد ال acid الحامض الحامض ما بيكون إلا على
+
+300
+00:26:07,770 --> 00:26:09,370
+الطرف
+
+301
+00:26:11,040 --> 00:26:15,620
+هيو زي هيو ولا ممكن يكون c double bond o o h في
+
+302
+00:26:15,620 --> 00:26:21,440
+النص مستحيل طب الحامض لو اجيت رقمت من هنا واحد
+
+303
+00:26:21,440 --> 00:26:25,500
+اتنين تلاتة اربعة و بدي اسميه طبعا هقول اكيد
+
+304
+00:26:25,500 --> 00:26:30,580
+بيوتان مافيش فيها لقاش هتقولي اللي هو الحامض ايش
+
+305
+00:26:30,580 --> 00:26:39,300
+نهايته اوك اسدأوك أسد بيوتانووك أسد الان هل يا ترى
+
+306
+00:26:39,300 --> 00:26:44,360
+بنحط بيوتان وان أوك أسد لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+307
+00:26:44,360 --> 00:26:45,200
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+308
+00:26:45,200 --> 00:26:46,700
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+309
+00:26:46,700 --> 00:26:47,880
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+310
+00:26:47,880 --> 00:26:48,340
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+311
+00:26:48,340 --> 00:26:52,440
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ ل
+
+312
+00:26:55,860 --> 00:27:00,100
+لأ ممكن يكون على موقع اتنين او تلاتة او اكتر يعني
+
+313
+00:27:00,100 --> 00:27:03,900
+في ال ketone بعد شوية هتلاحظوا لو كان عندنا خمس
+
+314
+00:27:03,900 --> 00:27:11,720
+ذرات كربون او ستة كم ذرة اللي رسمناهم واحد
+
+315
+00:27:11,720 --> 00:27:17,200
+اتنين تلاتة اربعة خمسة ستة سبعة و اجينا قولنا من
+
+316
+00:27:17,200 --> 00:27:24,440
+هذا المركب كسلسلة كم ketone بقدر اطلعلو قولت كام
+
+317
+00:27:24,440 --> 00:27:29,620
+الديهايد بقدر أعمل منه؟ واحد اسمه Heptanal و الـ C
+
+318
+00:27:29,620 --> 00:27:33,140
+double bond هو Hannah و Jamal لو قولت كام Acid
+
+319
+00:27:33,140 --> 00:27:39,020
+بقدر أطلع؟ Acid، واحد Heptanoic Acid لو قولت كام
+
+320
+00:27:39,020 --> 00:27:43,500
+كيتون؟ إذا إجت Hannah، two Heptanon وإذا إجت
+
+321
+00:27:43,500 --> 00:27:47,880
+Hannah، three Heptanon وإذا إجت Hannah، four
+
+322
+00:27:47,880 --> 00:27:56,330
+Heptanon one, twotwo عفوا واحد اتنين تلات عفوا two
+
+323
+00:27:56,330 --> 00:28:01,070
+و three و four اذا صار عندى two هبتانون و three
+
+324
+00:28:01,070 --> 00:28:05,490
+هبتانون و four هبتانون الا لو اجت هنا بتصير three
+
+325
+00:28:05,490 --> 00:28:08,470
+هبتانون من الجهة التانية او لو اجت هنا two هبتانون
+
+326
+00:28:08,470 --> 00:28:12,490
+من الجهة التانية اذا من هذا صار عندى اكتر من كيتون
+
+327
+00:28:12,490 --> 00:28:16,930
+فالكيتون يحتاج الى ترقيم لما بيلزم بينما ال
+
+328
+00:28:16,930 --> 00:28:22,270
+الديهايد لا يكون الا على موقع واحدوأبعد الفكرة
+
+329
+00:28:22,270 --> 00:28:27,970
+ومثل الديهيد ال acid ومثل ال ketone ال alcohol إذا
+
+330
+00:28:27,970 --> 00:28:32,990
+الأشياء اللي احنا بنسمي بلزم نحطلها أرقام اللي أنا
+
+331
+00:28:32,990 --> 00:28:35,750
+خدوها كلها مين يذكرنا في الأشياء اللي بلزمها
+
+332
+00:28:35,750 --> 00:28:42,450
+أرقامه الأشياء اللي مابلزمها ال alkeneيلزموا أرقام
+
+333
+00:28:42,450 --> 00:28:47,310
+انتبهوا معايا هاي سبع كاربونات لو كنت بعمل الكيل
+
+334
+00:28:47,310 --> 00:28:52,670
+ممكن يكون هنا او هنا او هنا اذا ال الكيل بيلزموا
+
+335
+00:28:52,670 --> 00:28:59,370
+أرقام ال الكاين one-heptane, two-heptane, three
+
+336
+00:28:59,370 --> 00:29:05,030
+-heptane يلزموا أرقام ال alcohol one-heptanol, two
+
+337
+00:29:05,030 --> 00:29:08,690
+-heptanol, three-heptanol, four-heptanol يلزموا
+
+338
+00:29:08,690 --> 00:29:14,920
+أرقامالكيتون two-heptanone، three-heptanone، four
+
+339
+00:29:14,920 --> 00:29:20,340
+-heptanone يلزم أرقام، إذا الالكيل والالكايد
+
+340
+00:29:20,340 --> 00:29:25,760
+والالكول والكيتون هدولة بلزمهم أرقام، لكن لو كنت
+
+341
+00:29:25,760 --> 00:29:30,960
+بحكي عن الديهيد، لأ، هبتنال فقط عن إمرأة واحدة
+
+342
+00:29:31,450 --> 00:29:36,250
+acid, heptanoic acid فالالدهاد والاسد ما بيكونوا
+
+343
+00:29:36,250 --> 00:29:54,710
+غير على موقع واحد واضحة تاني الفكرة حابين
+
+344
+00:29:54,710 --> 00:30:02,640
+تسمعوا الجوابلا بأس السؤال اللي سألته زملتكم أنه
+
+345
+00:30:02,640 --> 00:30:07,460
+لو كان في عندها رابطة ثلاثية و رابطة ثنائية كيف
+
+346
+00:30:07,460 --> 00:30:12,600
+بدي أسم المركب؟ تمام؟ لو عندي رابطة ثلاثية و رابطة
+
+347
+00:30:12,600 --> 00:30:16,800
+ثنائية كيف بدي أسم المركب؟ المركب بدي يكون في ال
+
+348
+00:30:16,800 --> 00:30:23,190
+keen و ال kind، الآن alphabeticalال E قبل ال I،
+
+349
+00:30:23,190 --> 00:30:26,570
+يعني لو كان بسبع ذرات، في double bond و triple
+
+350
+00:30:26,570 --> 00:30:32,170
+bond، إيش هيتسمى؟ هبتين I، يعني بتكونوا تتخيلوه،
+
+351
+00:30:32,170 --> 00:30:37,410
+سبع ذرات بهذا الشكل، بتأكدوا حيكون لإنه سبعة جاب
+
+352
+00:30:37,410 --> 00:30:43,720
+كلمة إيش؟ هبتسبع ذرات إيش هيجيبه؟ Hept لما يكون في
+
+353
+00:30:43,720 --> 00:30:48,960
+double bond ال double bond إيش هيجيبه؟ En لما يكون
+
+354
+00:30:48,960 --> 00:30:56,120
+في triple bond ل triple bond إيش هيجيبه؟ Ein زي
+
+355
+00:30:56,120 --> 00:31:01,490
+هيك لازم اسمه يبينحاجة بتعبر عن العدد بعدين عن
+
+356
+00:31:01,490 --> 00:31:05,650
+الألكين بعدين عن الألكاين هذا الكلام هذا الكلام
+
+357
+00:31:05,650 --> 00:31:12,530
+ككتابة اسم و كذكر مجموعات لكن بيجي سؤال لما بدي
+
+358
+00:31:12,530 --> 00:31:19,920
+أرقم أحدد وين موقع ال E وين موقع ال Iهذه لها جثة
+
+359
+00:31:19,920 --> 00:31:25,080
+تانية و الموقع ال ال و الموقع ال I هذه لها جثة
+
+360
+00:31:25,080 --> 00:31:28,680
+تانية الآن القصة بتقول القات يعني خليني أعمل سبعة
+
+361
+00:31:28,680 --> 00:31:35,560
+واحد اتنين تلاتة اربع خمسة ستة سبعة و حطيت هذه زي
+
+362
+00:31:35,560 --> 00:31:37,300
+هيك و حطيت هنا triple bond
+
+363
+00:31:40,170 --> 00:31:44,050
+هذا heaped in I الان من وان بده ارقمه من هنا ولا
+
+364
+00:31:44,050 --> 00:31:50,230
+من هناك بنقول بنرقمه من الأقرب لأحد الأطراف يعني
+
+365
+00:31:50,230 --> 00:31:53,430
+تكون سواء double او triple اقرب يعني هنا لو عديت
+
+366
+00:31:53,430 --> 00:31:56,130
+واحد اتنين اول multiple point بتقابلني هنا عن
+
+367
+00:31:56,130 --> 00:31:59,930
+امرأة كم؟ تلاتة اول واحدة بتقابلني عن امرأة ايش؟
+
+368
+00:31:59,930 --> 00:32:04,110
+واحد وبناء على ذلك هرقم واحد اتنين تلاتة اربعة
+
+369
+00:32:04,110 --> 00:32:14,600
+خمسة ستة سبعة فهذا هيكون heapedone in أربعة I هبت
+
+370
+00:32:14,600 --> 00:32:23,520
+one in four I واضح طبعا لو انعكس سجلوا هذا الشغل ب
+
+371
+00:32:23,520 --> 00:32:31,160
+ثانية بقول برقم من الأقرب لأحد الأطراف الأقرب
+
+372
+00:32:31,160 --> 00:32:35,760
+بشتغل عليه تمام يعني هذا المركب .. بصوا بري ثانية
+
+373
+00:32:35,760 --> 00:32:41,500
+يا هودايعني هذا المركب نفسه الآن لو كان زي هيك ايش
+
+374
+00:32:41,500 --> 00:32:45,740
+رأيكم؟ هيظلوا على نفس الترقيم؟ اه .. اه .. اه ..
+
+375
+00:32:45,740 --> 00:32:45,840
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+376
+00:32:45,840 --> 00:32:46,020
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+377
+00:32:46,020 --> 00:32:47,260
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+378
+00:32:47,260 --> 00:32:47,540
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+379
+00:32:47,540 --> 00:32:48,040
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+380
+00:32:48,040 --> 00:32:48,460
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+381
+00:32:48,460 --> 00:32:52,340
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. ا
+
+382
+00:32:53,210 --> 00:32:58,710
+يعني مافيش تسمية نهائية تكون I'm in هذه ضد ال
+
+383
+00:32:58,710 --> 00:33:01,910
+alphabetical دائما الاتقاء ال double و ال triple
+
+384
+00:33:01,910 --> 00:33:06,210
+bond يجب أن تكون إيش؟ in I'm مافيش إشي في الكون
+
+385
+00:33:06,210 --> 00:33:11,990
+اسمه I'm in ضد ال alphabetical واضح؟ الآن الترقيم
+
+386
+00:33:11,990 --> 00:33:16,190
+هلجيته؟ هذي جاي ع نمره واحد لو بتعد من هنا بتجي ع
+
+387
+00:33:16,190 --> 00:33:19,770
+نمره واحد اتنين تلاتة إذا هذا الترقيم الصح وجدت
+
+388
+00:33:19,770 --> 00:33:22,470
+هذا المركب لما بده يتسمى مرة تانية
+
+389
+00:33:26,270 --> 00:33:34,090
+لاحظوا in و i عشان يتقارنوا المركبين الان هذا ال
+
+390
+00:33:34,090 --> 00:33:40,250
+in تبع وين اربعة و ال i تبع واحد خلصنا من المركب
+
+391
+00:33:40,250 --> 00:33:46,310
+اللي قبله ماناش فيه هذا بيصير اسمه four in one i
+
+392
+00:33:46,310 --> 00:33:51,450
+فتسمية ال double و ال triple bond إذا التقوا مع
+
+393
+00:33:51,450 --> 00:33:57,650
+بعضيجب أن يُذكروا in I ويجب أن يكون الترقيم من
+
+394
+00:33:57,650 --> 00:34:01,910
+الأقرب إلى أحد الأطراف الآن بيجوا الناس الاش
+
+395
+00:34:01,910 --> 00:34:09,090
+الملولوين عارفين هم؟ اه دول تعون لو بيقولوا طيب يا
+
+396
+00:34:09,090 --> 00:34:14,470
+تورا لو كانوا التنتين على نفس البعد يعني لو حطيت
+
+397
+00:34:14,470 --> 00:34:20,920
+هنا نشطب هدول احنا الآن مش عارفينأه لو كانوا
+
+398
+00:34:20,920 --> 00:34:25,600
+التنتين على نفس البعد حطيتها الرابطة و هالرابطة
+
+399
+00:34:25,600 --> 00:34:30,900
+جيت هنا عديت واحد هاي أول ما بلجي واحدة منه مع
+
+400
+00:34:30,900 --> 00:34:36,320
+نمرقاش اتنين و هنا واحد اتنين على اليمين اتنين و
+
+401
+00:34:36,320 --> 00:34:39,300
+على الشمال اتنين و أكتب نعطي الأولوية لا إيش في
+
+402
+00:34:39,300 --> 00:34:43,880
+الترخيم للتنائية إذا تساوإذا تساوى الأولوي
+
+403
+00:34:43,880 --> 00:34:48,900
+للثنائية فمثل هذا المركب برضه هيكون hip و in و I
+
+404
+00:34:48,900 --> 00:34:53,160
+ان هذا مما لا خلافة فيه كلمة in و I الآن الترقيم
+
+405
+00:34:53,160 --> 00:34:59,180
+لأ بنخليه إذا تساوى المرور على الرابطة الثنائية
+
+406
+00:34:59,180 --> 00:35:08,100
+قبل الرابطة الثلاثية إذا هذا بيكون two in five
+
+407
+00:35:08,100 --> 00:35:15,930
+I واضح الفكرةفهذا الكلام لو انتقى رابطة ثنائية أو
+
+408
+00:35:15,930 --> 00:35:22,750
+ثلاثية يذكره قولا واحدا in I الترقيم من الأقرب
+
+409
+00:35:22,750 --> 00:35:26,610
+لأحد الأطراف بغض النظر كرابطة زوجية أو ثنائية إلا
+
+410
+00:35:26,610 --> 00:35:32,130
+إذا تساووا فالأفضلية هتكون لإيش ال in بتكون مفضلة
+
+411
+00:35:32,130 --> 00:35:37,070
+على ال I احنا هذه المعلومة كنا مختصرينها طالما
+
+412
+00:35:37,070 --> 00:35:40,410
+سألت زمنكوا فيها فصرنا ضايفينها
+
+413
+00:35:44,460 --> 00:35:48,380
+لاحظوا معي ال الديهايد لما تيجي على ال aromatic
+
+414
+00:35:48,380 --> 00:35:54,960
+compounds أخدنا تسميتها يعني هذا benzaldehyde هنا
+
+415
+00:35:54,960 --> 00:35:59,520
+التقاء الديهايد مع الكهول ال الديهايد أقوى من
+
+416
+00:35:59,520 --> 00:36:08,220
+الكهول وعشان هيصير two-hydroxy benzaldehyde
+
+417
+00:36:08,220 --> 00:36:09,540
+شوف الحرف ال بيه رايح
+
+418
+00:36:12,860 --> 00:36:17,280
+2-hydroxybenzaldehyde اللي هو اسمه salicyldehyde
+
+419
+00:36:17,280 --> 00:36:20,720
+يمكن مار عليك انتوا salicylic acid لما تكون هذه OH
+
+420
+00:36:20,720 --> 00:36:25,560
+و هذا acid لو كان الديهايد salicyldehyde مثلا هذا
+
+421
+00:36:25,560 --> 00:36:29,940
+المركب في الديهايد و OH او مثل من اعلى واحدة ال
+
+422
+00:36:29,940 --> 00:36:36,840
+الديهايد اذا مركبي كله هذا اسمهبنزالدهيد ايش بيحمل
+
+423
+00:36:36,840 --> 00:36:42,320
+على نمرة أربعة؟ هيدروكسي وع نمرة تلاتة؟ ميثوكسي
+
+424
+00:36:42,320 --> 00:36:46,860
+إذا هذا لو بدأ أسميه اسم كامل، إيش هقول؟ four
+
+425
+00:36:46,860 --> 00:36:55,780
+-hydroxy three-methoxy، بنستعمل بهرة وميتا؟ four
+
+426
+00:36:55,780 --> 00:37:01,280
+-hydroxy، three-methoxy، benzaldehyde، اللي هو
+
+427
+00:37:01,280 --> 00:37:08,950
+مركب إيش؟الفانيلا يعني الفانيلا هي نفس الاسم تبعها
+
+428
+00:37:08,950 --> 00:37:16,070
+4-hydroxy-3-methoxy-benzaldehyde الآن أخر شغلة بدي
+
+429
+00:37:16,070 --> 00:37:23,250
+أحكيها لو يا ترى إجا الكحول أو الالديهايد أو
+
+430
+00:37:23,250 --> 00:37:29,710
+الكيتون على حلقة لاحظوا معي بدي أخد دراسة مقارنة
+
+431
+00:37:29,710 --> 00:37:38,320
+للثلاثة كحولالديهاي كيتون ييجوا على حلقة نفترض على
+
+432
+00:37:38,320 --> 00:37:46,280
+سايكلوبنتين خلّينا نتطلع بالشكل القاتل هنعمل هنعمل
+
+433
+00:37:46,280 --> 00:37:51,220
+تلت مرات الكلام الآن هي السايكلوبنتين عملناها مرة
+
+434
+00:37:51,220 --> 00:38:02,620
+مرتين تلاتة في مرة حطينا عليها إيش مجموعة OH هذا
+
+435
+00:38:02,620 --> 00:38:08,930
+إيشكحول و في المرة حاطينا عليها C double bond O
+
+436
+00:38:08,930 --> 00:38:13,730
+هذا كيتون في المرة التالتة اجينا نحط عليهم
+
+437
+00:38:13,730 --> 00:38:18,170
+الديهايد ال الديهايد شو هو كيف بقدر احط انا هنا
+
+438
+00:38:18,170 --> 00:38:23,920
+الديهايد جربوامافيش غير ان كل مجموعة ال الديهايد
+
+439
+00:38:23,920 --> 00:38:29,900
+اطلعها برا يعني اطلع برا C double bond O H شوفتوا
+
+440
+00:38:29,900 --> 00:38:33,660
+الفرق بينهم كيف ان انا هنا حطيت O مشبوكة مباشرة
+
+441
+00:38:33,660 --> 00:38:37,680
+بالحلقة هنا حطيت C double bond O مشبوكة مباشرة
+
+442
+00:38:37,680 --> 00:38:41,960
+بالحلقة هنا مافيش طريقة ان اطلع الديهايد ال oxygen
+
+443
+00:38:41,960 --> 00:38:46,100
+فيه مشبوكة مباشرة بالحلقة فبطلع كل مجموعة ال
+
+444
+00:38:46,100 --> 00:38:53,320
+الديهايد براواضح؟ اللي هي مع Carbon هذي زادت عن
+
+445
+00:38:53,320 --> 00:38:57,620
+هذي بإيش؟ ب Carbon ولذلك هذا لما بدنا نسميه
+
+446
+00:38:57,620 --> 00:39:02,560
+Cyclopentanol
+
+447
+00:39:02,560 --> 00:39:08,340
+تان و بنضيف النهاية تبعته All Cyclopentanol خلصنا
+
+448
+00:39:08,340 --> 00:39:16,050
+هذا لما بدنا نسميه نفس الفكرة Cycloبنتان وبنحطله
+
+449
+00:39:16,050 --> 00:39:23,250
+نهاية ال ketone بنتانون وخلصنا هذا لما بدي اسميه
+
+450
+00:39:23,250 --> 00:39:30,330
+.. لأ بسميهوش cycle بالتنالليش؟ لأنه إجي عليه
+
+451
+00:39:30,330 --> 00:39:33,690
+مجموعة كاملة خارجية، إجي عليه كمان carbon، C
+
+452
+00:39:33,690 --> 00:39:39,350
+double bond OH، بنسميه Cyclopenten-carb-aldehyde
+
+453
+00:39:39,350 --> 00:39:43,410
+لأنه إجت carbon زيادة عن اللي جابله، ولذلك هذا إيش
+
+454
+00:39:43,410 --> 00:39:50,910
+بده يتسمى؟ Cyclopenten-carb-aldehyde
+
+455
+00:39:53,820 --> 00:39:58,780
+ملاحظين الفرق بينهم؟ أنه أنا مابقدرش أشبك أكسوجين
+
+456
+00:39:58,780 --> 00:40:02,560
+الالديهايد مباشرة بالحلقة إلا من خلال ذرة كربون
+
+457
+00:40:02,560 --> 00:40:07,620
+ولذلك بنسميه Cyclopentane Carbaldehyde شفتوا الفرق
+
+458
+00:40:07,620 --> 00:40:11,500
+بين الكحول والكيتون والالديهايد لو يجي على حلقة؟
+
+459
+00:40:12,310 --> 00:40:16,630
+الان لو واحدة فيكم شاطرة بعد ما نختم المحاضرة بذكر
+
+460
+00:40:16,630 --> 00:40:20,210
+الله اتقولي كمان اخر مثال عشان نسكر هذه النقطة
+
+461
+00:40:20,210 --> 00:40:26,510
+المفروض يلحق هدولة كلهم ايش هيكون ال acid ال acid
+
+462
+00:40:26,510 --> 00:40:32,070
+لو بده ييجي على الحلقة كيف بده ييجي زي ال aldehyde
+
+463
+00:40:32,070 --> 00:40:37,150
+ال acid لو بده ييجي على الحلقة بده ييجي كله معلج
+
+464
+00:40:37,150 --> 00:40:38,010
+على الحلقة
+
+465
+00:40:42,740 --> 00:40:46,200
+ماقدرش أحطه على نفس الحلقة الأكسجينة المتصلة ولذلك
+
+466
+00:40:46,200 --> 00:40:49,820
+لما بدي أسميه بدي أسميه بشكل موازن لنظام ال
+
+467
+00:40:49,820 --> 00:40:57,680
+الديهايد إيش وجدت حاجة أقول عنه؟ Cyclo .. بنتين ..
+
+468
+00:40:57,680 --> 00:41:03,300
+Carboxylic acid كمان Carboxylic acid
+
+469
+00:41:05,250 --> 00:41:09,150
+شوفتوا كيف مقارنة الأمور بتيجي الكحول والكيتون
+
+470
+00:41:09,150 --> 00:41:11,750
+بيجيوا مباشرة على الحلقة فبنقول cyclopentanol
+
+471
+00:41:11,750 --> 00:41:16,090
+وcyclopentanol ال aldehyde لأ cyclopentane وcarb
+
+472
+00:41:16,090 --> 00:41:20,670
+aldehyde ال acid cyclopentane وcarboxylic acid
+
+473
+00:41:20,670 --> 00:41:26,650
+واضحة الفكرة وبهيك بننهي المحاضرة اليوم المرة اللي
+
+474
+00:41:26,650 --> 00:41:29,970
+جاي بنستمر في موضوع التسمية وموضوع ال aldehydes
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..cb50ad256d4a4255679a2ff2158f2b7afb875bbd
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4782, "start": 20.18, "end": 47.82, "text": "بسم الله الرحمن الرحيم الفصل التاسع موضوعه ال aldehydes and ketones طبعا ال aldehydes and ketones ربما انتوا اتلاحظوا انه عائلتين مش عائلة واحدة لو اطلعنا هنلاقي ان ال aldehydes و ال ketones هم جزء من عائلة اكبر جزء من عائلة اكبر اسمها", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 27188, 36520, 16712, 32277, 3615, 3714, 2407, 11242, 45367, 3224, 2423, 16798, 68, 3495, 14792, 293, 14979, 2213, 23032, 3555, 3615, 995, 2423, 16798, 68, 3495, 14792, 293, 14979, 2213, 12602, 3555, 15042, 16472, 2655, 14407, 1975, 2655, 15040, 5016, 19913, 14407, 16472, 3224, 6225, 16373, 1211, 2655, 9957, 37893, 6225, 16373, 37977, 36764, 24401, 3660, 45164, 1975, 9566, 1211, 3615, 8315, 8032, 1863, 15040, 38436, 16472, 2423, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 8032, 2304, 10874, 11622, 38207, 9154, 6225, 16373, 37977, 1975, 4117, 26890, 10874, 11622, 38207, 9154, 6225, 16373, 37977, 1975, 4117, 26890, 24525, 2304, 11296], "avg_logprob": -0.11043074498842428, "compression_ratio": 1.9479166666666667, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 20.18, "end": 20.52, "word": "بسم", "probability": 0.917724609375}, {"start": 20.52, "end": 20.7, "word": " الله", "probability": 0.97021484375}, {"start": 20.7, "end": 21.02, "word": " الرحمن", "probability": 0.9646809895833334}, {"start": 21.02, "end": 21.5, "word": " الرحيم", "probability": 0.9928385416666666}, {"start": 21.5, "end": 23.48, "word": " الفصل", "probability": 0.855712890625}, {"start": 23.48, "end": 24.24, "word": " التاسع", "probability": 0.9933268229166666}, {"start": 24.24, "end": 26.02, "word": " موضوعه", "probability": 0.98115234375}, {"start": 26.02, "end": 26.24, "word": " ال", "probability": 0.955078125}, {"start": 26.24, "end": 26.94, "word": " aldehydes", "probability": 0.734619140625}, {"start": 26.94, "end": 27.36, "word": " and", "probability": 0.859375}, {"start": 27.36, "end": 28.44, 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"probability": 0.9874674479166666}, {"start": 36.42, "end": 37.08, "word": " واحدة", "probability": 0.9386393229166666}, {"start": 37.08, "end": 38.1, "word": " لو", "probability": 0.96435546875}, {"start": 38.1, "end": 38.84, "word": " اطلعنا", "probability": 0.843359375}, {"start": 38.84, "end": 39.76, "word": " هنلاقي", "probability": 0.7628173828125}, {"start": 39.76, "end": 39.9, "word": " ان", "probability": 0.890625}, {"start": 39.9, "end": 40.02, "word": " ال", "probability": 0.9697265625}, {"start": 40.02, "end": 40.64, "word": " aldehydes", "probability": 0.95361328125}, {"start": 40.64, "end": 40.86, "word": " و", "probability": 0.7744140625}, {"start": 40.86, "end": 41.0, "word": " ال", "probability": 0.80712890625}, {"start": 41.0, "end": 41.78, "word": " ketones", "probability": 0.93359375}, {"start": 41.78, "end": 42.7, "word": " هم", "probability": 0.96826171875}, {"start": 42.7, "end": 43.2, "word": " جزء", "probability": 0.99755859375}, {"start": 43.2, "end": 44.0, 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329.11, "end": 329.75, "word": " ال", "probability": 0.88671875}, {"start": 329.75, "end": 330.65, "word": " substitution", "probability": 0.96435546875}, {"start": 330.65, "end": 332.27, "word": " الإبدال", "probability": 0.80908203125}, {"start": 332.27, "end": 332.93, "word": " تمام؟", "probability": 0.8248697916666666}], "temperature": 1.0}, {"id": 15, "seek": 36238, "start": 337.06, "end": 362.38, "text": "إذن سبب تقسيم هدول السبع مركبات إلى عائلات يعني أحيانا الإنسان كان ممكن يسأل إذا السبعة بدنا نعملهم عيلتين أو شبترين كان خلينا أربعة في شبتر وتلاتة في شبتر تاني ليش خلينا اتنين وخمسة تمام؟ لأ التقسيم مش تقسيم عددي التقسيم تقسيم وظيفي بمعنى", "tokens": [28814, 8848, 1863, 8608, 3555, 3555, 6055, 4587, 3794, 32640, 8032, 3215, 12610, 21136, 3555, 3615, 3714, 31747, 3555, 9307, 30731, 6225, 16373, 1211, 9307, 37495, 22653, 5551, 5016, 1829, 7649, 995, 33688, 1863, 3794, 7649, 25961, 3714, 43020, 7251, 3794, 10721, 1211, 11933, 15730, 21136, 3555, 27884, 47525, 8315, 8717, 25957, 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"word": " إيش", "probability": 0.8818359375}, {"start": 388.47, "end": 388.99, "word": " التفاعل", "probability": 0.9700927734375}, {"start": 388.99, "end": 389.51, "word": " الأساسي", "probability": 0.985107421875}, {"start": 389.51, "end": 390.23, "word": " للالدهايتز", "probability": 0.5361328125}, {"start": 390.23, "end": 391.13, "word": " والكيتونز؟", "probability": 0.8427734375}], "temperature": 1.0}, {"id": 17, "seek": 39956, "start": 391.6, "end": 399.56, "text": "ماعرفش يجاوب ايش التفاعل الأساسي لل assets ومش رقاتها ماعرفش يجاوب نراكم في السنة القادمة", "tokens": [15042, 3615, 28480, 8592, 7251, 7435, 995, 37746, 1975, 1829, 8592, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 24976, 9769, 4032, 2304, 8592, 12602, 4587, 9307, 11296, 19446, 3615, 28480, 8592, 7251, 7435, 995, 37746, 8717, 23557, 24793, 8978, 21136, 1863, 3660, 25062, 18513, 46007], "avg_logprob": -0.22091090171895128, "compression_ratio": 1.4363636363636363, "no_speech_prob": 5.960464477539063e-08, "words": 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"text": "واضح؟ طبعا O H minus لما تترد تاخد H من برا شو هتصير؟ O R minus لما تترد تاخد H R O H كحول N H 2 لما تترد N H 3 C L minus لما يترد C L اذا صار عندى هذه المجموعة هي اللتي تستبدل اللى جنب ايش اللى جنب الصيغة بال bond O بناء على ذلك الناتج ايش هيكون؟", "tokens": [2407, 46958, 5016, 22807, 23032, 3555, 3615, 995, 422, 389, 3175, 5296, 15042, 6055, 2655, 2288, 3215, 6055, 47283, 3215, 389, 9154, 4724, 23557, 13412, 2407, 8032, 2655, 9381, 13546, 22807, 422, 497, 3175, 5296, 15042, 6055, 2655, 2288, 3215, 6055, 47283, 3215, 389, 497, 422, 389, 9122, 5016, 12610, 426, 389, 568, 5296, 15042, 6055, 2655, 2288, 3215, 426, 389, 805, 383, 441, 3175, 5296, 15042, 7251, 2655, 2288, 3215, 383, 441, 1975, 15730, 20328, 9640, 43242, 7578, 29538, 9673, 7435, 2304, 2407, 27884, 39896, 13672, 31371, 6055, 14851, 44510, 1211, 13672, 7578, 10874, 1863, 3555, 1975, 1829, 8592, 13672, 7578, 10874, 1863, 3555, 31767, 1829, 17082, 3660, 20666, 6086, 422, 44945, 16606, 15844, 29910, 23275, 28239, 9307, 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0.5606689453125}, {"start": 1198.17, "end": 1198.61, "word": " عكس", "probability": 0.7174479166666666}, {"start": 1198.61, "end": 1198.79, "word": " على", "probability": 0.6728515625}, {"start": 1198.79, "end": 1199.17, "word": " شغل", "probability": 0.9005533854166666}, {"start": 1199.17, "end": 1199.55, "word": " تاني", "probability": 0.845703125}, {"start": 1199.55, "end": 1200.19, "word": " البولاريكي", "probability": 0.7840169270833334}, {"start": 1200.19, "end": 1200.41, "word": " شو", "probability": 0.70458984375}, {"start": 1200.41, "end": 1200.67, "word": " هي", "probability": 0.80322265625}, {"start": 1200.67, "end": 1202.31, "word": " الذائبية", "probability": 0.977294921875}, {"start": 1202.31, "end": 1203.37, "word": " و", "probability": 0.3916015625}, {"start": 1203.37, "end": 1203.97, "word": " القاعدة", "probability": 0.9827880859375}, {"start": 1203.97, "end": 1204.45, "word": " العامة", "probability": 0.99169921875}, {"start": 1204.45, "end": 1204.59, "word": " في", "probability": 0.85986328125}, {"start": 1204.59, "end": 1205.13, "word": " الموضوع", "probability": 0.998046875}, {"start": 1205.13, "end": 1205.57, "word": " ايش", "probability": 0.90234375}, {"start": 1205.57, "end": 1206.91, "word": " like", "probability": 0.3427734375}, {"start": 1206.91, "end": 1209.07, "word": " dissolves", "probability": 0.6446533203125}, {"start": 1209.07, "end": 1209.47, "word": " like", "probability": 0.9384765625}, {"start": 1209.47, "end": 1210.33, "word": " الان", "probability": 0.758544921875}, {"start": 1210.33, "end": 1211.35, "word": " اكتر", "probability": 0.9322509765625}, {"start": 1211.35, "end": 1211.77, "word": " حاجة", "probability": 0.9913736979166666}, {"start": 1211.77, "end": 1212.05, "word": " فيها", "probability": 0.9814453125}, {"start": 1212.05, "end": 1212.59, "word": " قطبية", "probability": 0.9813232421875}, {"start": 1212.59, "end": 1214.25, "word": " ايش", "probability": 0.9376627604166666}, {"start": 1214.25, "end": 1215.27, "word": " الكحولات", "probability": 0.97607421875}, {"start": 1215.27, "end": 1215.53, "word": " اللي", "probability": 0.805908203125}, {"start": 1215.53, "end": 1215.77, "word": " فيها", "probability": 0.97998046875}, {"start": 1215.77, "end": 1215.95, "word": " O", "probability": 0.55859375}, {"start": 1215.95, "end": 1216.61, "word": " H's", "probability": 0.385986328125}, {"start": 1216.61, "end": 1217.07, "word": " و", "probability": 0.81591796875}, {"start": 1217.07, "end": 1217.69, "word": " بتذكروا", "probability": 0.9580078125}, {"start": 1217.69, "end": 1217.97, "word": " حتى", "probability": 0.8955078125}, {"start": 1217.97, "end": 1218.21, "word": " لما", "probability": 0.91162109375}, {"start": 1218.21, "end": 1218.51, "word": " قلنا", "probability": 0.7890625}, {"start": 1218.51, "end": 1218.75, "word": " عن", "probability": 0.99169921875}, {"start": 1218.75, "end": 1219.69, "word": " الكحولات", "probability": 0.994873046875}, {"start": 1219.69, "end": 1220.19, "word": " قلنا", "probability": 0.9327799479166666}, {"start": 1220.19, "end": 1220.59, "word": " مابدناش", "probability": 0.71015625}, {"start": 1220.59, "end": 1221.13, "word": " ننسى", "probability": 0.9478759765625}, {"start": 1221.13, "end": 1221.27, "word": " ان", "probability": 0.81201171875}, {"start": 1221.27, "end": 1222.03, "word": " الكحول", "probability": 0.9923502604166666}], "temperature": 1.0}, {"id": 53, "seek": 124050, "start": 1223.28, "end": 1240.5, "text": "في المجمعتين في الجزء القطبي ال R والجزء القطبي ال OH والجزء غير القطبي ال R وبناء على ذلك ال lower alcohols كانت water soluble وال higher alcohols كانت water soluble", "tokens": [41185, 9673, 7435, 2304, 34268, 9957, 8978, 25724, 11622, 38207, 25062, 9566, 21292, 2423, 497, 16070, 7435, 11622, 38207, 25062, 9566, 21292, 2423, 13931, 16070, 7435, 11622, 38207, 32771, 13546, 25062, 9566, 21292, 2423, 497, 46599, 1863, 16606, 15844, 29910, 23275, 2423, 3126, 7658, 82, 25961, 2655, 1281, 24807, 638, 16070, 2946, 7658, 82, 25961, 2655, 1281, 24807, 638], "avg_logprob": -0.20768228471279143, "compression_ratio": 1.8432835820895523, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1223.28, "end": 1223.52, "word": "في", "probability": 0.68115234375}, {"start": 1223.52, "end": 1224.5, "word": " المجمعتين", "probability": 0.9328125}, {"start": 1224.5, "end": 1225.0, "word": " في", "probability": 0.57958984375}, {"start": 1225.0, "end": 1225.54, "word": " الجزء", "probability": 0.9581705729166666}, {"start": 1225.54, "end": 1226.28, "word": " القطبي", "probability": 0.803466796875}, {"start": 1226.28, "end": 1227.36, "word": " ال", "probability": 0.720703125}, {"start": 1227.36, "end": 1227.88, "word": " R", "probability": 0.1990966796875}, {"start": 1227.88, "end": 1228.84, "word": " والجزء", "probability": 0.84588623046875}, {"start": 1228.84, "end": 1230.78, "word": " القطبي", "probability": 0.85595703125}, {"start": 1230.78, "end": 1230.96, "word": " ال", "probability": 0.79150390625}, 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"end": 1493.61, "word": " اه", "probability": 0.51177978515625}, {"start": 1493.61, "end": 1493.75, "word": " ال", "probability": 0.5244140625}, {"start": 1493.75, "end": 1494.11, "word": " chiral", "probability": 0.7442626953125}, {"start": 1494.11, "end": 1494.45, "word": " center", "probability": 0.76025390625}, {"start": 1494.45, "end": 1494.69, "word": " مش", "probability": 0.89453125}, {"start": 1494.69, "end": 1494.87, "word": " ال", "probability": 0.8935546875}, {"start": 1494.87, "end": 1495.03, "word": " cis", "probability": 0.45703125}, {"start": 1495.03, "end": 1495.19, "word": " و", "probability": 0.93798828125}, {"start": 1495.19, "end": 1495.23, "word": " ال", "probability": 0.3173828125}, {"start": 1495.23, "end": 1495.49, "word": " trans", "probability": 0.88427734375}, {"start": 1495.49, "end": 1495.63, "word": " ال", "probability": 0.15869140625}, {"start": 1495.63, "end": 1495.77, "word": " cis", "probability": 0.87109375}, {"start": 1495.77, "end": 1495.89, "word": " و", "probability": 0.98046875}, {"start": 1495.89, "end": 1495.91, "word": " ال", "probability": 0.81689453125}, {"start": 1495.91, "end": 1496.15, "word": " trans", "probability": 0.93017578125}, {"start": 1496.15, "end": 1496.39, "word": " كل", "probability": 0.6591796875}, {"start": 1496.39, "end": 1496.49, "word": " ما", "probability": 0.9052734375}, {"start": 1496.49, "end": 1496.61, "word": " يلي", "probability": 0.3017578125}, {"start": 1496.61, "end": 1496.97, "word": " علاقة", "probability": 0.90087890625}, {"start": 1496.97, "end": 1497.31, "word": " بالضبط", "probability": 0.8052978515625}, {"start": 1497.31, "end": 1497.75, "word": " بالبونس", "probability": 0.6680908203125}, {"start": 1497.75, "end": 1497.83, "word": " و", "probability": 0.7294921875}, {"start": 1497.83, "end": 1498.51, "word": " بالحلقات", "probability": 0.87578125}, {"start": 1498.51, "end": 1498.91, "word": " ال", "probability": 0.6123046875}, {"start": 1498.91, "end": 1499.39, "word": " chiral", "probability": 0.963623046875}, {"start": 1499.39, "end": 1499.91, "word": " center", "probability": 0.919921875}, {"start": 1499.91, "end": 1500.45, "word": " لما", "probability": 0.9384765625}, {"start": 1500.45, "end": 1500.87, "word": " بيصير", "probability": 0.8380126953125}, {"start": 1500.87, "end": 1501.39, "word": " هذا", "probability": 0.92138671875}, {"start": 1501.39, "end": 1501.95, "word": " هنا", "probability": 0.7265625}, {"start": 1501.95, "end": 1502.09, "word": " و", "probability": 0.876953125}, {"start": 1502.09, "end": 1502.55, "word": " بحط", "probability": 0.9562174479166666}, {"start": 1502.55, "end": 1502.83, "word": " O", "probability": 0.36328125}, {"start": 1502.83, "end": 1503.21, "word": " H", "probability": 0.44091796875}, {"start": 1503.21, "end": 1503.39, "word": " و", "probability": 0.79443359375}, {"start": 1503.39, "end": 1503.69, "word": " H", "probability": 0.82080078125}, {"start": 1503.69, "end": 1503.87, "word": " ع", "probability": 0.72509765625}, {"start": 1503.87, "end": 1504.07, "word": " طول", "probability": 0.8564453125}, {"start": 1504.07, "end": 1504.35, "word": " صار", "probability": 0.925048828125}, {"start": 1504.35, "end": 1504.65, "word": " عندى", "probability": 0.76806640625}, {"start": 1504.65, "end": 1505.07, "word": " ROS", "probability": 0.52978515625}, {"start": 1505.07, "end": 1505.37, "word": " من", "probability": 0.99267578125}, {"start": 1505.37, "end": 1505.51, "word": " ال", "probability": 0.9580078125}, {"start": 1505.51, "end": 1505.69, "word": " two", "probability": 0.57421875}, {"start": 1505.69, "end": 1506.47, "word": " butanol", "probability": 0.8068033854166666}, {"start": 1506.47, "end": 1507.65, "word": " ال", "probability": 0.939453125}, {"start": 1507.65, "end": 1507.83, "word": " two", "probability": 0.74560546875}, {"start": 1507.83, "end": 1508.51, "word": " butanol", "probability": 0.9736328125}, {"start": 1508.51, "end": 1508.99, "word": " منه", "probability": 0.906982421875}, {"start": 1508.99, "end": 1509.61, "word": " ROS", "probability": 0.63427734375}, {"start": 1509.61, "end": 1510.27, "word": " ال", "probability": 0.97998046875}, {"start": 1510.27, "end": 1510.43, "word": " one", "probability": 0.966796875}, {"start": 1510.43, "end": 1510.95, "word": " butanol", "probability": 0.9759114583333334}, {"start": 1510.95, "end": 1511.15, "word": " مافيش", "probability": 0.7291666666666666}, {"start": 1511.15, "end": 1511.31, "word": " فيه", "probability": 0.89794921875}, {"start": 1511.31, "end": 1511.73, "word": " chiral", "probability": 0.936767578125}, {"start": 1511.73, "end": 1512.15, "word": " center", "probability": 0.931640625}, {"start": 1512.15, "end": 1512.39, "word": " one", "probability": 0.630859375}, {"start": 1512.39, "end": 1513.09, "word": " butanol", "probability": 0.9723307291666666}], "temperature": 1.0}, {"id": 66, "seek": 153959, "start": 1513.95, "end": 1539.59, "text": "واضح؟ طبعا ما بننساش أنه فيه isobutanol و tertiarybutanol كل هدول الأشياء لازم تكونوا عارفينها الان ال aldehydes اللي جابنا للكلام ال aldehydes لأ مافيش منها واحد و اتنين لأن مجموعة ال aldehydes لا تكون الا على نمرة واحد و لانها لا تكون الا على نمرة واحد بنحط ال hash رقم", "tokens": [2407, 46958, 5016, 22807, 23032, 3555, 3615, 995, 19446, 44945, 1863, 3794, 33599, 14739, 3224, 8978, 3224, 307, 996, 30624, 401, 4032, 38726, 29104, 5955, 282, 401, 28242, 8032, 3215, 12610, 16247, 8592, 1829, 16606, 5296, 31377, 2304, 6055, 30544, 14407, 6225, 9640, 5172, 9957, 11296, 2423, 7649, 2423, 16798, 68, 3495, 14792, 13672, 1829, 10874, 16758, 8315, 24976, 28820, 10943, 2423, 16798, 68, 3495, 14792, 5296, 10721, 19446, 41185, 8592, 9154, 11296, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 5296, 33456, 3714, 7435, 2304, 2407, 27884, 2423, 16798, 68, 3495, 14792, 20193, 6055, 30544, 42963, 15844, 8717, 2304, 25720, 36764, 24401, 4032, 5296, 7649, 11296, 20193, 6055, 30544, 42963, 15844, 8717, 2304, 25720, 36764, 24401, 44945, 5016, 9566, 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1519.65, "end": 1520.03, "word": " هدول", "probability": 0.8898111979166666}, {"start": 1520.03, "end": 1521.63, "word": " الأشياء", "probability": 0.826171875}, {"start": 1521.63, "end": 1522.49, "word": " لازم", "probability": 0.9744466145833334}, {"start": 1522.49, "end": 1522.79, "word": " تكونوا", "probability": 0.9860026041666666}, {"start": 1522.79, "end": 1523.35, "word": " عارفينها", "probability": 0.98916015625}, {"start": 1523.35, "end": 1524.15, "word": " الان", "probability": 0.461181640625}, {"start": 1524.15, "end": 1524.41, "word": " ال", "probability": 0.96435546875}, {"start": 1524.41, "end": 1525.33, "word": " aldehydes", "probability": 0.68634033203125}, {"start": 1525.33, "end": 1525.57, "word": " اللي", "probability": 0.85205078125}, {"start": 1525.57, "end": 1525.95, "word": " جابنا", "probability": 0.9236653645833334}, {"start": 1525.95, "end": 1527.13, "word": " للكلام", "probability": 0.9176432291666666}, {"start": 1527.13, "end": 1527.47, "word": " ال", 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"end": 1839.03, "text": "ال E قبل ال I، يعني لو كان بسبع ذرات، في double bond و triple bond، إيش هيتسمى؟ هبتين I، يعني بتكونوا تتخيلوه، سبع ذرات بهذا الشكل، بتأكدوا حيكون لإنه سبعة جاب كلمة إيش؟ هبت", "tokens": [6027, 462, 12174, 36150, 2423, 286, 12399, 37495, 22653, 45164, 25961, 4724, 35457, 3615, 29910, 2288, 9307, 12399, 8978, 3834, 6086, 4032, 15508, 6086, 12399, 11933, 1829, 8592, 8032, 36081, 38251, 7578, 22807, 8032, 3555, 2655, 9957, 286, 12399, 37495, 22653, 39894, 30544, 14407, 6055, 2655, 9778, 26895, 2407, 3224, 12399, 8608, 3555, 3615, 29910, 2288, 9307, 39627, 15730, 25124, 28820, 12399, 39894, 10721, 4117, 3215, 14407, 11331, 1829, 30544, 5296, 28814, 1863, 3224, 8608, 3555, 27884, 10874, 16758, 9122, 19528, 3660, 11933, 1829, 8592, 22807, 8032, 3555, 2655], "avg_logprob": -0.23020833002196417, "compression_ratio": 1.5706521739130435, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1820.69, "end": 1820.99, "word": "ال", "probability": 0.91064453125}, 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"probability": 0.97705078125}, {"start": 2179.78, "end": 2180.16, "word": " لما", "probability": 0.796630859375}, {"start": 2180.16, "end": 2180.36, "word": " تكون", "probability": 0.955322265625}, {"start": 2180.36, "end": 2180.54, "word": " هذه", "probability": 0.0987548828125}, {"start": 2180.54, "end": 2180.72, "word": " OH", "probability": 0.76123046875}, {"start": 2180.72, "end": 2180.98, "word": " و", "probability": 0.70556640625}, {"start": 2180.98, "end": 2181.12, "word": " هذا", "probability": 0.53955078125}, {"start": 2181.12, "end": 2181.56, "word": " acid", "probability": 0.705078125}, {"start": 2181.56, "end": 2181.96, "word": " لو", "probability": 0.75927734375}, {"start": 2181.96, "end": 2182.18, "word": " كان", "probability": 0.98974609375}, {"start": 2182.18, "end": 2182.8, "word": " الديهايد", "probability": 0.56390380859375}, {"start": 2182.8, "end": 2184.42, "word": " salicyldehyde", "probability": 0.8476155598958334}, {"start": 2184.42, "end": 2185.28, "word": " مثلا", "probability": 0.9658203125}, {"start": 2185.28, "end": 2185.56, "word": " هذا", "probability": 0.939453125}, {"start": 2185.56, "end": 2186.3, "word": " المركب", "probability": 0.8878580729166666}, {"start": 2186.3, "end": 2186.6, "word": " في", "probability": 0.92919921875}, {"start": 2186.6, "end": 2187.26, "word": " الديهايد", "probability": 0.9483642578125}, {"start": 2187.26, "end": 2187.36, "word": " و", "probability": 0.450439453125}, {"start": 2187.36, "end": 2187.72, "word": " OH", "probability": 0.7060546875}, {"start": 2187.72, "end": 2187.98, "word": " او", "probability": 0.581787109375}, {"start": 2187.98, "end": 2188.3, "word": " مثل", "probability": 0.9501953125}, {"start": 2188.3, "end": 2188.46, "word": " من", "probability": 0.90185546875}, {"start": 2188.46, "end": 2188.72, "word": " اعلى", "probability": 0.9166666666666666}, {"start": 2188.72, "end": 2189.36, "word": " واحدة", "probability": 0.9210611979166666}, {"start": 2189.36, "end": 2189.94, "word": " ال", "probability": 0.9140625}, {"start": 2189.94, "end": 2190.6, "word": " الديهايد", "probability": 0.84429931640625}, {"start": 2190.6, "end": 2191.12, "word": " اذا", "probability": 0.75390625}, {"start": 2191.12, "end": 2192.28, "word": " مركبي", "probability": 0.7311197916666666}, {"start": 2192.28, "end": 2192.7, "word": " كله", "probability": 0.81884765625}, {"start": 2192.7, "end": 2192.94, "word": " هذا", "probability": 0.91552734375}, {"start": 2192.94, "end": 2193.54, "word": " اسمه", "probability": 0.9768880208333334}], "temperature": 1.0}, {"id": 93, "seek": 222262, "start": 2194.9, "end": 2222.62, "text": "بنزالدهيد ايش بيحمل على نمرة أربعة؟ هيدروكسي وع نمرة تلاتة؟ ميثوكسي إذا هذا لو بدأ أسميه اسم كامل، إيش هقول؟ four-hydroxy three-methoxy، بنستعمل بهرة وميتا؟ four-hydroxy، three-methoxy، benzaldehyde، اللي هو مركب إيش؟", "tokens": [3555, 1863, 11622, 6027, 3215, 3224, 25708, 1975, 1829, 8592, 4724, 1829, 35571, 1211, 15844, 8717, 2304, 25720, 5551, 25513, 27884, 22807, 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"end": 2203.88, "word": " أسميه", "probability": 0.8563232421875}, {"start": 2203.88, "end": 2204.16, "word": " اسم", "probability": 0.9013671875}, {"start": 2204.16, "end": 2204.68, "word": " كامل،", "probability": 0.8411865234375}, {"start": 2204.68, "end": 2204.78, "word": " إيش", "probability": 0.8699544270833334}, {"start": 2204.78, "end": 2206.36, "word": " هقول؟", "probability": 0.7600911458333334}, {"start": 2206.36, "end": 2206.86, "word": " four", "probability": 0.79833984375}, {"start": 2206.86, "end": 2207.8, "word": "-hydroxy", "probability": 0.76708984375}, {"start": 2207.8, "end": 2210.36, "word": " three", "probability": 0.353515625}, {"start": 2210.36, "end": 2211.22, "word": "-methoxy،", "probability": 0.7496744791666666}, {"start": 2211.22, "end": 2211.9, "word": " بنستعمل", "probability": 0.9227294921875}, {"start": 2211.9, "end": 2212.26, "word": " بهرة", "probability": 0.7994791666666666}, {"start": 2212.26, "end": 2213.58, "word": " وميتا؟", "probability": 0.81220703125}, {"start": 2213.58, "end": 2215.78, "word": " four", "probability": 0.1993408203125}, {"start": 2215.78, "end": 2217.98, "word": "-hydroxy،", "probability": 0.8380859375}, {"start": 2217.98, "end": 2218.18, "word": " three", "probability": 0.93701171875}, {"start": 2218.18, "end": 2219.9, "word": "-methoxy،", "probability": 0.86669921875}, {"start": 2219.9, "end": 2221.0, "word": " benzaldehyde،", "probability": 0.836181640625}, {"start": 2221.0, "end": 2221.1, "word": " اللي", "probability": 0.7744140625}, {"start": 2221.1, "end": 2221.28, "word": " هو", "probability": 0.9794921875}, {"start": 2221.28, "end": 2221.86, "word": " مركب", "probability": 0.8987630208333334}, {"start": 2221.86, "end": 2222.62, "word": " إيش؟", "probability": 0.9083251953125}], "temperature": 1.0}, {"id": 94, "seek": 225303, "start": 2224.19, "end": 2253.03, "text": "الفانيلا يعني الفانيلا هي نفس الاسم تبعها 4-hydroxy-3-methoxy-benzaldehyde الآن أخر شغلة بدي أحكيها لو يا ترى إجا الكحول أو الالديهايد أو الكيتون على حلقة لاحظوا معي بدي أخد دراسة مقارنة للثلاثة كحول", "tokens": [6027, 5172, 7649, 1829, 15040, 37495, 22653, 27188, 7649, 1829, 15040, 39896, 8717, 36178, 2423, 32277, 2304, 6055, 3555, 3615, 11296, 1017, 12, 21591, 340, 12876, 12, 18, 12, 76, 3293, 5230, 88, 12, 1799, 89, 304, 1479, 3495, 1479, 6024, 48506, 5551, 34740, 13412, 17082, 37977, 4724, 16254, 5551, 5016, 4117, 1829, 11296, 45164, 35186, 6055, 2288, 7578, 11933, 7435, 995, 33251, 5016, 12610, 34051, 2423, 6027, 16254, 11296, 25708, 34051, 33251, 36081, 11536, 15844, 11331, 1211, 28671, 20193, 5016, 19913, 14407, 20449, 1829, 4724, 16254, 5551, 9778, 3215, 11778, 23557, 3794, 3660, 3714, 4587, 9640, 1863, 3660, 24976, 12984, 1211, 5718, 104, 3660, 9122, 5016, 12610], "avg_logprob": -0.22233370903435104, "compression_ratio": 1.6183574879227054, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2224.19, "end": 2224.95, "word": "الفانيلا", "probability": 0.695703125}, {"start": 2224.95, "end": 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{"start": 2234.25, "end": 2235.51, "word": " أخر", "probability": 0.7568359375}, {"start": 2235.51, "end": 2235.83, "word": " شغلة", "probability": 0.8108723958333334}, {"start": 2235.83, "end": 2236.07, "word": " بدي", "probability": 0.752685546875}, {"start": 2236.07, "end": 2236.87, "word": " أحكيها", "probability": 0.969921875}, {"start": 2236.87, "end": 2238.15, "word": " لو", "probability": 0.91357421875}, {"start": 2238.15, "end": 2238.39, "word": " يا", "probability": 0.53955078125}, {"start": 2238.39, "end": 2238.67, "word": " ترى", "probability": 0.8819986979166666}, {"start": 2238.67, "end": 2239.09, "word": " إجا", "probability": 0.6946614583333334}, {"start": 2239.09, "end": 2240.19, "word": " الكحول", "probability": 0.9931640625}, {"start": 2240.19, "end": 2241.71, "word": " أو", "probability": 0.890625}, {"start": 2241.71, "end": 2242.97, "word": " الالديهايد", "probability": 0.682470703125}, {"start": 2242.97, "end": 2243.25, "word": " أو", "probability": 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228308, "start": 2253.96, "end": 2283.08, "text": "الديهاي كيتون ييجوا على حلقة نفترض على سايكلوبنتين خلّينا نتطلع بالشكل القاتل هنعمل هنعمل تلت مرات الكلام الآن هي السايكلوبنتين عملناها مرة مرتين تلاتة في مرة حطينا عليها إيش مجموعة OH هذا إيش", "tokens": [6027, 16254, 11296, 1829, 9122, 36081, 11536, 7251, 1829, 7435, 14407, 15844, 11331, 1211, 28671, 8717, 5172, 2655, 43042, 15844, 8608, 47302, 28820, 2407, 3555, 29399, 9957, 16490, 1211, 11703, 9957, 995, 8717, 2655, 9566, 1211, 3615, 20666, 8592, 28820, 25062, 9307, 1211, 8032, 1863, 25957, 1211, 8032, 1863, 25957, 1211, 6055, 1211, 2655, 3714, 2288, 9307, 2423, 28820, 10943, 6024, 48506, 39896, 21136, 47302, 28820, 37746, 29399, 9957, 6225, 42213, 8315, 11296, 3714, 25720, 3714, 43500, 9957, 6055, 1211, 9307, 3660, 8978, 3714, 25720, 11331, 9566, 1829, 8315, 25894, 11296, 11933, 1829, 8592, 3714, 7435, 2304, 2407, 27884, 13931, 23758, 11933, 1829, 8592], "avg_logprob": -0.231994054431007, "compression_ratio": 1.8518518518518519, 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المرة التالتة اجينا نحط عليهم الديهايد ال الديهايد شو هو كيف بقدر احط انا هنا الديهايد جربوا", "tokens": [4117, 5016, 12610, 4032, 8978, 9673, 25720, 11331, 41193, 1829, 8315, 25894, 11296, 383, 3834, 6086, 422, 23758, 9122, 36081, 11536, 8978, 9673, 25720, 16712, 6027, 2655, 3660, 1975, 7435, 1829, 8315, 8717, 5016, 9566, 25894, 16095, 2423, 16254, 11296, 25708, 2423, 2423, 16254, 11296, 25708, 13412, 2407, 31439, 9122, 33911, 4724, 28543, 2288, 1975, 5016, 9566, 1975, 8315, 34105, 2423, 16254, 11296, 25708, 10874, 25513, 14407], "avg_logprob": -0.23288142944083495, "compression_ratio": 1.7152317880794703, "no_speech_prob": 1.430511474609375e-06, "words": [{"start": 2284.01, "end": 2284.55, "word": "كحول", "probability": 0.7886555989583334}, {"start": 2284.55, "end": 2285.11, "word": " و", "probability": 0.83935546875}, {"start": 2285.11, "end": 2285.29, "word": " في", "probability": 0.64453125}, {"start": 2285.29, "end": 2285.57, "word": " المرة", "probability": 0.84326171875}, 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236698, "start": 2353.23, "end": 2366.99, "text": "بنتان وبنحطله نهاية ال ketone بنتانون وخلصنا هذا لما بدي اسميه .. لأ بسميهوش cycle بالتنال", "tokens": [3555, 29399, 7649, 46599, 1863, 5016, 9566, 43761, 8717, 11296, 10632, 2423, 14979, 546, 4724, 29399, 7649, 11536, 4032, 9778, 1211, 9381, 8315, 23758, 5296, 15042, 4724, 16254, 24525, 2304, 1829, 3224, 4386, 5296, 10721, 4724, 38251, 1829, 3224, 2407, 8592, 6586, 20666, 2655, 1863, 6027], "avg_logprob": -0.3500664842889664, "compression_ratio": 1.2991452991452992, "no_speech_prob": 0.0, "words": [{"start": 2353.23, "end": 2354.57, "word": "بنتان", "probability": 0.8035481770833334}, {"start": 2354.57, "end": 2356.05, "word": " وبنحطله", "probability": 0.631201171875}, {"start": 2356.05, "end": 2356.47, "word": " نهاية", "probability": 0.9469401041666666}, {"start": 2356.47, "end": 2356.67, "word": " ال", "probability": 0.8837890625}, {"start": 2356.67, "end": 2357.23, "word": " ketone", "probability": 0.6370849609375}, {"start": 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2390.91, "text": "ليش؟ لأنه إجي عليه مجموعة كاملة خارجية، إجي عليه كمان carbon، C double bond OH، بنسميه Cyclopenten-carb-aldehyde لأنه إجت carbon زيادة عن اللي جابله، ولذلك هذا إيش بده يتسمى؟ Cyclopenten-carb-aldehyde", "tokens": [20292, 8592, 22807, 5296, 33456, 3224, 11933, 7435, 1829, 47356, 3714, 7435, 2304, 2407, 27884, 9122, 10943, 37977, 16490, 9640, 7435, 10632, 12399, 11933, 7435, 1829, 47356, 9122, 2304, 7649, 5954, 12399, 383, 3834, 6086, 13931, 12399, 44945, 38251, 1829, 3224, 10295, 3474, 404, 317, 268, 12, 6166, 65, 12, 304, 1479, 3495, 1479, 5296, 33456, 3224, 11933, 7435, 2655, 5954, 30767, 1829, 18513, 3660, 18871, 13672, 1829, 10874, 16758, 43761, 12399, 35525, 8848, 23275, 23758, 11933, 1829, 8592, 47525, 3224, 7251, 2655, 38251, 7578, 22807, 49173, 404, 317, 268, 12, 6166, 65, 12, 304, 1479, 3495, 1479], "avg_logprob": -0.21227904612367804, "compression_ratio": 1.5416666666666667, "no_speech_prob": 0.0, "words": [{"start": 2368.17, "end": 2368.91, "word": "ليش؟", "probability": 0.7708333333333334}, {"start": 2368.91, "end": 2369.35, "word": " لأنه", "probability": 0.8404947916666666}, {"start": 2369.35, "end": 2370.07, "word": " إجي", "probability": 0.5015462239583334}, {"start": 2370.07, "end": 2370.33, "word": " عليه", "probability": 0.93017578125}, {"start": 2370.33, "end": 2370.91, "word": " مجموعة", "probability": 0.95}, {"start": 2370.91, "end": 2371.45, "word": " كاملة", "probability": 0.99169921875}, {"start": 2371.45, "end": 2372.19, "word": " خارجية،", "probability": 0.859765625}, {"start": 2372.19, "end": 2372.37, "word": " إجي", "probability": 0.8707682291666666}, {"start": 2372.37, "end": 2372.57, "word": " عليه", "probability": 0.99169921875}, {"start": 2372.57, "end": 2372.93, "word": " كمان", "probability": 0.9944661458333334}, {"start": 2372.93, "end": 2373.55, "word": " carbon،", "probability": 0.67822265625}, {"start": 2373.55, "end": 2373.69, "word": " C", "probability": 0.419677734375}, {"start": 2373.69, "end": 2373.89, "word": " double", "probability": 0.5537109375}, {"start": 2373.89, "end": 2374.13, "word": " bond", "probability": 0.82861328125}, {"start": 2374.13, "end": 2374.67, "word": " OH،", "probability": 0.60791015625}, {"start": 2374.67, "end": 2375.81, "word": " بنسميه", "probability": 0.968994140625}, {"start": 2375.81, "end": 2377.51, "word": " Cyclopenten", "probability": 0.5794921875}, {"start": 2377.51, "end": 2378.41, "word": "-carb", "probability": 0.5738118489583334}, {"start": 2378.41, "end": 2379.35, "word": "-aldehyde", "probability": 0.8953125}, {"start": 2379.35, "end": 2380.07, "word": " لأنه", "probability": 0.7151692708333334}, {"start": 2380.07, "end": 2380.53, "word": " إجت", "probability": 0.91357421875}, {"start": 2380.53, "end": 2381.03, "word": " carbon", "probability": 0.83447265625}, {"start": 2381.03, "end": 2381.51, "word": " زيادة", "probability": 0.8902587890625}, {"start": 2381.51, "end": 2381.69, "word": " عن", "probability": 0.94580078125}, {"start": 2381.69, 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خلال ذرة كربون ولذلك بنسميه Cyclopentane Carbaldehyde شفتوا الفرق بين الكحول والكيتون والالديهايد لو يجي على حلقة؟", "tokens": [2304, 15040, 5016, 19913, 9957, 27188, 2288, 4587, 49374, 16095, 22807, 14739, 3224, 41850, 3714, 16758, 28543, 2288, 8592, 5551, 8592, 3555, 4117, 5551, 4117, 3794, 29245, 9957, 2423, 6027, 16254, 11296, 25708, 3714, 3555, 33599, 25720, 20666, 5016, 1211, 28671, 11933, 15040, 9154, 16490, 1211, 6027, 29910, 25720, 9122, 25513, 11536, 35525, 8848, 23275, 44945, 38251, 1829, 3224, 10295, 3474, 404, 317, 1929, 2741, 2645, 1479, 3495, 1479, 13412, 5172, 2655, 14407, 27188, 2288, 4587, 49374, 33251, 5016, 12610, 16070, 4117, 36081, 11536, 16070, 6027, 16254, 11296, 25708, 45164, 7251, 7435, 1829, 15844, 11331, 1211, 28671, 22807], "avg_logprob": -0.22253788330338217, "compression_ratio": 1.6715686274509804, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2393.82, "end": 2394.4, "word": "ملاحظين", "probability": 0.8228515625}, {"start": 2394.4, "end": 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Carboxylic acid كمان Carboxylic acid", "tokens": [15042, 28543, 2288, 8592, 5551, 5016, 9566, 3224, 15844, 8717, 36178, 21542, 1211, 28671, 16247, 4117, 3794, 7435, 9957, 3660, 9673, 2655, 36520, 3660, 35525, 8848, 23275, 5296, 15042, 4724, 16254, 5551, 38251, 1829, 3224, 4724, 16254, 5551, 38251, 1829, 3224, 4724, 8592, 28820, 3714, 2407, 31377, 1863, 5296, 1863, 19913, 10943, 2423, 2423, 16254, 11296, 25708, 11933, 1829, 8592, 49610, 3215, 2655, 11331, 26108, 3660, 5551, 39648, 18871, 3224, 22807, 10295, 66, 752, 4386, 4724, 29399, 9957, 4386, 2741, 4995, 88, 1050, 8258, 9122, 2304, 7649, 2741, 4995, 88, 1050, 8258], "avg_logprob": -0.23655914234858688, "compression_ratio": 1.5336787564766838, "no_speech_prob": 0.0, "words": [{"start": 2442.74, "end": 2443.26, "word": "ماقدرش", "probability": 0.74261474609375}, {"start": 2443.26, "end": 2443.6, "word": " أحطه", "probability": 0.8751220703125}, {"start": 2443.6, "end": 2443.74, "word": " على", "probability": 0.822265625}, {"start": 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"probability": 0.59912109375}, {"start": 2457.68, "end": 2458.66, "word": " Carboxylic", "probability": 0.7337646484375}, {"start": 2458.66, "end": 2459.04, "word": " acid", "probability": 0.56201171875}, {"start": 2459.04, "end": 2459.46, "word": " كمان", "probability": 0.9578450520833334}, {"start": 2459.46, "end": 2461.76, "word": " Carboxylic", "probability": 0.8741455078125}, {"start": 2461.76, "end": 2463.3, "word": " acid", "probability": 0.822265625}], "temperature": 1.0}, {"id": 104, "seek": 248996, "start": 2465.25, "end": 2489.97, "text": "شوفتوا كيف مقارنة الأمور بتيجي الكحول والكيتون بيجيوا مباشرة على الحلقة فبنقول cyclopentanol وcyclopentanol ال aldehyde لأ cyclopentane وcarb aldehyde ال acid cyclopentane وcarboxylic acid واضحة الفكرة وبهيك بننهي المحاضرة اليوم المرة اللي جاي بنستمر في موضوع التسمية وموضوع ال aldehydes", "tokens": [8592, 38688, 2655, 14407, 9122, 33911, 3714, 4587, 9640, 1863, 3660, 16247, 2304, 13063, 39894, 1829, 7435, 1829, 33251, 5016, 12610, 16070, 4117, 36081, 11536, 4724, 1829, 7435, 1829, 14407, 3714, 3555, 33599, 25720, 15844, 21542, 1211, 28671, 6156, 3555, 1863, 39648, 19474, 404, 317, 282, 401, 4032, 34080, 404, 317, 282, 401, 2423, 16798, 68, 3495, 1479, 5296, 10721, 19474, 404, 317, 1929, 4032, 6166, 65, 16798, 68, 3495, 1479, 2423, 8258, 19474, 404, 317, 1929, 4032, 6166, 4995, 88, 1050, 8258, 4032, 46958, 5016, 3660, 27188, 4117, 25720, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 9673, 5016, 46958, 25720, 45595, 20498, 9673, 25720, 13672, 1829, 10874, 47302, 44945, 14851, 29973, 8978, 3714, 2407, 11242, 45367, 16712, 38251, 10632, 4032, 2304, 2407, 11242, 45367, 2423, 16798, 68, 3495, 14792], "avg_logprob": -0.23283617729038902, "compression_ratio": 1.8675213675213675, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2465.25, "end": 2465.73, "word": "شوفتوا", "probability": 0.5811767578125}, {"start": 2465.73, "end": 2465.93, "word": " كيف", "probability": 0.919677734375}, {"start": 2465.93, "end": 2466.67, "word": " مقارنة", "probability": 0.94794921875}, {"start": 2466.67, "end": 2467.19, "word": " الأمور", "probability": 0.91455078125}, {"start": 2467.19, "end": 2467.73, "word": " بتيجي", "probability": 0.8502197265625}, {"start": 2467.73, "end": 2468.63, "word": " الكحول", "probability": 0.8728841145833334}, {"start": 2468.63, "end": 2469.15, "word": " والكيتون", "probability": 0.744384765625}, {"start": 2469.15, "end": 2469.43, "word": " بيجيوا", "probability": 0.856640625}, {"start": 2469.43, "end": 2469.95, "word": " مباشرة", "probability": 0.9830322265625}, {"start": 2469.95, "end": 2470.07, "word": " على", "probability": 0.66748046875}, {"start": 2470.07, "end": 2470.47, "word": " الحلقة", "probability": 0.9856770833333334}, {"start": 2470.47, "end": 2470.87, "word": " فبنقول", "probability": 0.7342529296875}, {"start": 2470.87, "end": 2471.75, "word": " cyclopentanol", "probability": 0.75693359375}, {"start": 2471.75, "end": 2472.69, "word": " وcyclopentanol", "probability": 0.7860107421875}, {"start": 2472.69, "end": 2473.21, "word": " ال", "probability": 0.52197265625}, {"start": 2473.21, "end": 2473.69, "word": " aldehyde", "probability": 0.6895751953125}, {"start": 2473.69, "end": 2473.93, "word": " لأ", "probability": 0.951904296875}, {"start": 2473.93, "end": 2475.25, "word": " cyclopentane", "probability": 0.845947265625}, {"start": 2475.25, "end": 2476.09, "word": " وcarb", "probability": 0.3960774739583333}, {"start": 2476.09, "end": 2476.59, "word": " aldehyde", "probability": 0.83599853515625}, {"start": 2476.59, "end": 2476.95, "word": " ال", "probability": 0.826171875}, {"start": 2476.95, "end": 2477.29, "word": " acid", "probability": 0.89404296875}, {"start": 2477.29, "end": 2478.63, "word": " cyclopentane", "probability": 0.9287109375}, {"start": 2478.63, "end": 2480.01, "word": " وcarboxylic", "probability": 0.72568359375}, {"start": 2480.01, "end": 2480.67, "word": " acid", "probability": 0.96826171875}, {"start": 2480.67, "end": 2481.81, "word": " واضحة", "probability": 0.8563232421875}, {"start": 2481.81, "end": 2482.27, "word": " الفكرة", "probability": 0.98974609375}, {"start": 2482.27, "end": 2484.77, "word": " وبهيك", "probability": 0.730621337890625}, {"start": 2484.77, "end": 2485.47, "word": " بننهي", "probability": 0.71240234375}, {"start": 2485.47, "end": 2485.99, "word": " المحاضرة", "probability": 0.9737548828125}, {"start": 2485.99, "end": 2486.23, "word": " اليوم", "probability": 0.912109375}, {"start": 2486.23, "end": 2486.53, "word": " المرة", "probability": 0.919921875}, {"start": 2486.53, "end": 2486.65, "word": " اللي", "probability": 0.677490234375}, {"start": 2486.65, "end": 2486.81, "word": " جاي", "probability": 0.8671875}, {"start": 2486.81, "end": 2487.35, "word": " بنستمر", "probability": 0.89306640625}, {"start": 2487.35, "end": 2487.51, "word": " في", "probability": 0.9072265625}, {"start": 2487.51, "end": 2487.85, "word": " موضوع", "probability": 0.9644775390625}, {"start": 2487.85, "end": 2488.57, "word": " التسمية", "probability": 0.9708658854166666}, {"start": 2488.57, "end": 2489.35, "word": " وموضوع", "probability": 0.97548828125}, {"start": 2489.35, "end": 2489.47, "word": " ال", "probability": 0.96728515625}, {"start": 2489.47, "end": 2489.97, "word": " aldehydes", "probability": 0.8426513671875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2490.8045, "duration_after_vad": 2386.49187499999}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4.srt
new file mode 100644
index 0000000000000000000000000000000000000000..5b73b52232cb929e3d255665729f33e9cf4283a2
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4.srt
@@ -0,0 +1,1535 @@
+
+1
+00:00:19,490 --> 00:00:24,290
+بسم الله الرحمن الرحيم المرة الماضية بدينا في
+
+2
+00:00:24,290 --> 00:00:28,130
+موضوع ال carbohydrates بدينا في موضوع ال
+
+3
+00:00:28,130 --> 00:00:34,450
+carbohydrates وقولنا انه امكوانين من carbon و ما
+
+4
+00:00:34,450 --> 00:00:41,130
+.. و بعدين طبعا بدينا في ال sugarsقولنا ال sugars
+
+5
+00:00:41,130 --> 00:00:45,030
+في النهاية هما ال الديهيدز او كيتونز لكن فيهم
+
+6
+00:00:45,030 --> 00:00:48,670
+مجموعات اوقاتش كثيرة بوليهيدروكسي الديهيدز او
+
+7
+00:00:48,670 --> 00:00:55,050
+بوليهيدروكسي كيتونز طبعا بسبب وجود ال chiral
+
+8
+00:00:55,050 --> 00:01:00,910
+centersبصير عندنا عدد ال isomers للصيغة الواحدة
+
+9
+00:01:00,910 --> 00:01:06,330
+كتير و اتدرجنا طبعا من أبسط مركب في one chiral
+
+10
+00:01:06,330 --> 00:01:11,690
+center اللي هو ال glycerol dihyde و رسمنا بطرق
+
+11
+00:01:11,690 --> 00:01:22,940
+مختلفة شوفنا كيف المركبات هذه ممكن تكونD أو L في
+
+12
+00:01:22,940 --> 00:01:25,300
+المرحلة الأولى و لو قلنا لو عندنا one chiral
+
+13
+00:01:25,300 --> 00:01:30,540
+center بيصير في عندنا مركبين بعد هيك قصة ال D و L
+
+14
+00:01:30,540 --> 00:01:34,580
+بتستمر بزيادة ال chiral center و بيبدأ العدد يزيد
+
+15
+00:01:34,580 --> 00:01:43,040
+فبناء على ذلك بناء على ذلك فبموضوع
+
+16
+00:01:43,040 --> 00:01:46,140
+ال sugars
+
+17
+00:01:47,420 --> 00:01:52,440
+قلنا أساسي جدا نتطلع على ال chiral centers و نتذكر
+
+18
+00:01:52,440 --> 00:01:55,620
+كل الكلام اللي حكيناه في chiral centers في chapter
+
+19
+00:01:55,620 --> 00:01:59,460
+4 إذا عندنا one chiral center بنتوقع مركبين two
+
+20
+00:01:59,460 --> 00:02:04,480
+chiral centers بنتوقع أربعة و هكذا بدأنا بالتدريج
+
+21
+00:02:04,480 --> 00:02:09,980
+و أخر شيء انتهينا عنده احنا لما كان في عندنا ست
+
+22
+00:02:09,980 --> 00:02:17,870
+ذرات كربون طبعا لما بيكون عندى ست ذرات كربونعلى
+
+23
+00:02:17,870 --> 00:02:22,090
+حسب ما بنرسم احنا ال sugar بالطريقة اللي اتعلمناها
+
+24
+00:02:22,090 --> 00:02:27,370
+الذرة الأولى من فوق الديهايد وبناء على ذلك هذا مش
+
+25
+00:02:27,370 --> 00:02:32,550
+chiral center والذرة الأخيرة من تحت CH2OH مش
+
+26
+00:02:32,550 --> 00:02:36,970
+chiral center واجتها لو رسمنا الشكل اللي بنسميه
+
+27
+00:02:36,970 --> 00:02:42,950
+الacyclic structure بيكون فينا كام isomer كام
+
+28
+00:02:42,950 --> 00:02:50,800
+chiral center أربعة بيقدروا إلىالان طالما ان السكر
+
+29
+00:02:50,800 --> 00:02:55,840
+عبارة عن الكهول و الديهايد لو جربنا نجعل الكهول
+
+30
+00:02:55,840 --> 00:03:00,640
+يسكر على الديهايد هيعمل a new chiral center هيصير
+
+31
+00:03:00,640 --> 00:03:07,080
+اندفعخمسة كايرال سنترز وجدت بنتوقع انه لسكر مكون
+
+32
+00:03:07,080 --> 00:03:11,460
+من ست ذرات كربون بهذا الشكل يكون عنده اتنين و
+
+33
+00:03:11,460 --> 00:03:17,320
+تلاتين ايزومات طبعا لما تمت عملية الاغلاق لما تمت
+
+34
+00:03:17,320 --> 00:03:23,040
+عملية اغلاق الالكول على ال الديهايدبهذا الشكل
+
+35
+00:03:23,040 --> 00:03:28,100
+اتكون عندى هنا ال new chiral center وقولنا
+
+36
+00:03:28,100 --> 00:03:30,920
+الكاربون هذه اللى بتعمل ال new chiral center شو
+
+37
+00:03:30,920 --> 00:03:35,460
+بنسميها احنا انوميرك كاربون الان معنى new chiral
+
+38
+00:03:35,460 --> 00:03:40,060
+center ان هو ال OH هذى بنسميها اما لأعلىوإما لأسفل
+
+39
+00:03:40,060 --> 00:03:44,460
+وقلنا إذا بتكون لأسفل بنقول هذا Alpha compound
+
+40
+00:03:44,460 --> 00:03:48,740
+وإذا بتكون لأعلى بيقول هذا Beta الآن طالما أنه في
+
+41
+00:03:48,740 --> 00:03:52,560
+أربعة chiral centers كان عنده 16 مركب كل واحد فيهم
+
+42
+00:03:52,560 --> 00:03:55,840
+لما بده يسكر بده يقسم Alpha Beta Alpha Beta معنا
+
+43
+00:03:55,840 --> 00:04:01,820
+ذلك المجموع صار إيش 32 مركب هذا تقريبا أخر شيء
+
+44
+00:04:01,820 --> 00:04:08,390
+انتهينا فيه الآن اللي بدي أنبهلهطيب الآن قلنا في
+
+45
+00:04:08,390 --> 00:04:15,210
+عندنا شكل a cyclic و أشكال cyclic لأ هذا السكر ال
+
+46
+00:04:15,210 --> 00:04:21,450
+a cyclic يترى بأي نسبة عادة موجود في المحلول و ال
+
+47
+00:04:21,450 --> 00:04:26,860
+cyclic بأي نسبة موجودين في المحلولالصحيح أن الـ
+
+48
+00:04:26,860 --> 00:04:33,080
+acyclic في محلول مائي يوجد بنسبة قليلة جدا جدا جدا
+
+49
+00:04:33,080 --> 00:04:37,000
+يعني معظم السكر بينوجد على شكل الحلقة النسبة اللي
+
+50
+00:04:37,000 --> 00:04:43,460
+بينوجد فيها ال acyclic في محلول مائي هي 0.003
+
+51
+00:04:43,460 --> 00:04:50,780
+بيرزة تلاتة من ألف يعني أكاد يكون مش موجود إذا
+
+52
+00:04:50,780 --> 00:04:57,310
+كأنه كل السكربسكر واضح كأنه كل السكر بيسكر لما
+
+53
+00:04:57,310 --> 00:05:01,290
+نقول هذه النسبة قليلة جدا اللى بينوجد فيها الـA
+
+54
+00:05:01,290 --> 00:05:05,630
+Cycle طيب كل السكر بيسكر بيسكر على ايش Alpha و
+
+55
+00:05:05,630 --> 00:05:10,550
+Beta هل بيكونوا بنفس النسبة اتعودنا او حكينا انه
+
+56
+00:05:10,550 --> 00:05:16,930
+لأ بيكون ال Beta بالمعدل حوالي 64والألف حوالي 36
+
+57
+00:05:16,930 --> 00:05:24,030
+او هنا 35.5 يمكن هناك 64.5 و هنا 35.5 لو بدنا نسيب
+
+58
+00:05:24,030 --> 00:05:31,860
+شوية دقيقة واضح يمكن البعض يقولطب كيف جدروا يفصلوا
+
+59
+00:05:31,860 --> 00:05:36,080
+هذا لوحده يعني طالما انه هذا اتزان ما بين ال alpha
+
+60
+00:05:36,080 --> 00:05:40,540
+و ال beta يعني دايما المخلوط موجود فيه التنين كيف
+
+61
+00:05:40,540 --> 00:05:43,940
+يتعرفوا على ال alpha لحاله اذا انا بحط في المحلول
+
+62
+00:05:43,940 --> 00:05:48,560
+المائي بينوجدوا التنين الجواب اه في المحلول المائي
+
+63
+00:05:48,560 --> 00:05:53,160
+بينوجدوا التنين فعلالكن لو اعملنا للمركب
+
+64
+00:05:53,160 --> 00:05:59,460
+crystallization تبلر من محلول Methanol فقط بيطلع
+
+65
+00:05:59,460 --> 00:06:04,300
+عند ال alpha نقي يعني انا في غير الميه بقدر احصل
+
+66
+00:06:04,300 --> 00:06:10,400
+ال alpha نقي ال alpha ال pure alpha وين بشوفه
+
+67
+00:06:10,400 --> 00:06:15,440
+بمحلول ايش؟الميثانول فلو عملنا crystallization
+
+68
+00:06:15,440 --> 00:06:19,180
+للسكر هذا ال جولوكوز بمحلول الميثانول باخد ال
+
+69
+00:06:19,180 --> 00:06:23,320
+alpha لوحده واضح الفكرة؟ الان لو عملت
+
+70
+00:06:23,320 --> 00:06:30,020
+crystallization بال acidic acid بحصل على ال beta
+
+71
+00:06:30,020 --> 00:06:38,760
+لوحده فقط ايش؟ ال beta ال pure betaواضح؟ الان لو
+
+72
+00:06:38,760 --> 00:06:42,760
+اجيت اخدت انا صار في عندى alpha pure يعني صار في
+
+73
+00:06:42,760 --> 00:06:47,100
+عندى بوتل في alpha pure بوتل تاني في beta pure ال
+
+74
+00:06:47,100 --> 00:06:51,590
+alpha pure من وين باخده؟من خلال الميثانول ال beta
+
+75
+00:06:51,590 --> 00:06:55,910
+pure من ال acetic acid الآن لو جبت ال alpha pure
+
+76
+00:06:55,910 --> 00:07:01,750
+حطيته في الميه في محلول الميه بيصير يعمل التحول
+
+77
+00:07:01,750 --> 00:07:05,730
+لacyclic و برد سكر alpha beta إلى أن يصل إلى
+
+78
+00:07:05,730 --> 00:07:10,410
+الاتزان اللى اتفقنا عليه ال 36 و64 فهذا الاتزان
+
+79
+00:07:10,410 --> 00:07:16,370
+وين بيكون موجود في ال aqueous solutionفي المحلول
+
+80
+00:07:16,370 --> 00:07:21,370
+المائي لو بدأت بالألفة النقي هيصل لهذا الاتزان و
+
+81
+00:07:21,370 --> 00:07:26,730
+لو بدأت بالبيتا النقي أيضا هيصل لهذا الاتزان واضح؟
+
+82
+00:07:26,730 --> 00:07:31,510
+إذا بالإمكان إن أنا أفصل ألفة نقي ب solvent غير
+
+83
+00:07:31,510 --> 00:07:35,870
+الميه وبيتا نقي ب solvent غير الميه لكن في الميه
+
+84
+00:07:35,870 --> 00:07:41,270
+لو بدأت بأي واحد فهيحصل الاتزان اللي هو بين ألفة
+
+85
+00:07:41,270 --> 00:07:48,250
+وبيتابنسبة 36 ل 64 هذا الكلام بيعني شغلة بيعني ان
+
+86
+00:07:48,250 --> 00:07:53,770
+which is more stable ال alpha ولا ال beta ال beta
+
+87
+00:07:53,770 --> 00:07:58,870
+اللي موجود بنسبة اكبر هو اللي بيكون more stable
+
+88
+00:07:58,870 --> 00:08:01,490
+واضح هذه الفكرة
+
+89
+00:08:05,630 --> 00:08:10,350
+بعد هيك بدنا ننتبه لنقطة أنه لما بتم الإغلاق ال
+
+90
+00:08:10,350 --> 00:08:15,130
+الديهايد مجموعة واحدة مش موضوع خلافي لكن ال OHS
+
+91
+00:08:17,200 --> 00:08:25,520
+أكتار زي ما اتكلمنا هذه OH ممكن تسكرها و إغلاق
+
+92
+00:08:25,520 --> 00:08:29,580
+أي OH يعطي حلقة بحجم مختلف يعني لو أغلقت من هنا
+
+93
+00:08:29,580 --> 00:08:35,060
+ستكون حلقة ثلاثية لو هيك سكرت ربعية لو هذه سكرت
+
+94
+00:08:35,060 --> 00:08:40,980
+خمسية هذه اللي سكرت السداسية هذه سبعية هل يترا
+
+95
+00:08:40,980 --> 00:08:47,530
+ممكن أن يتم إغلاقات لغير الحلقة السداسية؟اللي
+
+96
+00:08:47,530 --> 00:08:53,130
+مشهور حقيقة انه بتم اغلاق من ال OH اللي موجودة هنا
+
+97
+00:08:53,130 --> 00:08:59,730
+وبيعطيني حلقة خماسية لكن قداش نسبة السكر اللي
+
+98
+00:08:59,730 --> 00:09:05,970
+بيكون كحلقة خماسية واحد في المية يعني لاحظوا لو
+
+99
+00:09:05,970 --> 00:09:09,930
+انا بدي اجي على المحلول بالمجمل هقول في عندي واحد
+
+100
+00:09:09,930 --> 00:09:15,870
+في المية حلقة خماسية في عندي تلاتة بالألف إيه
+
+101
+00:09:15,870 --> 00:09:23,200
+صايفلك؟فاتح والباقي حلقة سداسية بتكون النسبة بين
+
+102
+00:09:23,200 --> 00:09:31,200
+مكوناتها 64 إلى 36 واضح فالمحلول هيكون فيه اكثر من
+
+103
+00:09:31,200 --> 00:09:36,100
+شغلة هيكون فيه محلول الجولوكوز الacyclic بنسبة
+
+104
+00:09:36,770 --> 00:09:43,010
+تلاتة في الألف المسكّر على حلقة خماسية بيكون بنسبة
+
+105
+00:09:43,010 --> 00:09:46,370
+واحد في المية الاناليبيكي اللي هو التسعة وتسعين في
+
+106
+00:09:46,370 --> 00:09:51,050
+المية كيف بتكون مقصومة اربعة وستين في المية منها
+
+107
+00:09:51,050 --> 00:09:55,410
+بيتا ستة و تلاتين في المية منها الفة واضح الفكرة
+
+108
+00:10:01,460 --> 00:10:06,660
+طبعا احنا قولنا كلمة و وضحناها المرة الماضية ان ال
+
+109
+00:10:06,660 --> 00:10:10,860
+beta is more stable than the alpha لان لو رسمنا
+
+110
+00:10:10,860 --> 00:10:14,920
+الحلقة السوداسية على الشكل اللى عادة بتكون موجودة
+
+111
+00:10:14,920 --> 00:10:18,420
+فيه و يمكن مار علينا لما أخدنا الحلقات السوداسية
+
+112
+00:10:18,420 --> 00:10:21,140
+نقطين وجد على شكل both
+
+113
+00:10:23,360 --> 00:10:27,920
+أو chair which is more stable chair conformation
+
+114
+00:10:27,920 --> 00:10:31,620
+الان لو حطيتها على هيئة الكرسي في ال chair
+
+115
+00:10:31,620 --> 00:10:37,480
+conformation ال OH ممكن تكون بشكل أفقي بهذا الشكل
+
+116
+00:10:37,480 --> 00:10:43,460
+بنقول عنها equatorial equatorial يعني بشكل أفقي
+
+117
+00:10:43,460 --> 00:10:48,040
+يعني لما نتخيل أنه الشكل العام للحلقات بهذا الشكل
+
+118
+00:10:48,040 --> 00:10:55,070
+هي بتكون زي هيكهذه equatorial الان ممكن تكون في
+
+119
+00:10:55,070 --> 00:11:01,830
+شكل تاني axial رأس عمودي هيك equatorial هيك axial
+
+120
+00:11:01,830 --> 00:11:09,740
+الان بالشكل هذا بتكون ايش؟أكسيال طبعا ال
+
+121
+00:11:09,740 --> 00:11:13,820
+equatorial الفراغ اللي حواليها أفضل من الفراغ اللي
+
+122
+00:11:13,820 --> 00:11:18,180
+حواليه الأكسيال الأكسيال crowded لاحظوا فيها
+
+123
+00:11:18,180 --> 00:11:21,600
+steric hindrance فيها ممانعة فراغية مالهاش واسعة
+
+124
+00:11:21,600 --> 00:11:26,840
+واضحالـ equatorial مترايحة أكثر ولذلك هذا الشكل ال
+
+125
+00:11:26,840 --> 00:11:31,200
+equatorial هو ال beta هذا الشكل ال axial هو ال
+
+126
+00:11:31,200 --> 00:11:35,900
+alpha عشان هيك ال beta بيكون more stable لأن ال OH
+
+127
+00:11:35,900 --> 00:11:39,820
+اللي موجودة فيه ال new chiral center لأنميرك كربون
+
+128
+00:11:39,820 --> 00:11:43,860
+بتكون مترايحة من الناحية الفرغية مافيش حد مضايقها
+
+129
+00:11:43,860 --> 00:11:48,440
+واضح؟ لحظوا هذه ال OH الجديدة اللي اتكونت عندىالان
+
+130
+00:11:48,440 --> 00:11:52,740
+في ال equatorial form هي مترايحة في ال axial form
+
+131
+00:11:52,740 --> 00:11:57,160
+مش مترايحة في جنبها مجموعات تانية بتعمل ازدحام
+
+132
+00:11:57,160 --> 00:12:02,240
+فراغي فلما نكون بدنا نفسر ليش ال beta موجودة اكثر
+
+133
+00:12:02,240 --> 00:12:08,020
+من ال alpha بنقول because the beta o h is found in
+
+134
+00:12:08,020 --> 00:12:13,140
+the equatorial position لان موجودة في ال
+
+135
+00:12:13,140 --> 00:12:16,960
+equatorial ال equatorial is not a crowded position
+
+136
+00:12:17,870 --> 00:12:24,070
+واضح فسبب الثبات ل ال beta ان ال OH الجديدة هذه
+
+137
+00:12:24,070 --> 00:12:28,650
+اللي اتكونت عندي هنا لو رسمت الشكل على هيئة الكرسي
+
+138
+00:12:28,650 --> 00:12:32,330
+بتكون موجودة وين؟ في ال axial ولا في ال
+
+139
+00:12:32,330 --> 00:12:36,070
+equatorial؟ في ال equatorial ال equatorial is not
+
+140
+00:12:36,070 --> 00:12:39,350
+a sterically hindered molecule
+
+141
+00:12:41,870 --> 00:12:44,730
+طبعا الـ mutarotation حكينا عنه برضه المرة
+
+142
+00:12:44,730 --> 00:12:49,450
+الماضية، قلنا لو بدنا من أي واحد، حيصل لإيش؟
+
+143
+00:12:49,450 --> 00:12:50,310
+للإتزان
+
+144
+00:12:52,690 --> 00:12:57,850
+ال بيرانوز and فيرانوز structures الموضوع بسيط
+
+145
+00:12:57,850 --> 00:13:02,650
+فيهم انه احنا قلنا السكر اشهر الإغلاقات تبعته اما
+
+146
+00:13:02,650 --> 00:13:08,630
+على حلقة سداسية او على حلقة خماسية الان في ال
+
+147
+00:13:08,630 --> 00:13:12,610
+heterocyclic chemistry الحلقة السداسية اللى فيها
+
+148
+00:13:12,610 --> 00:13:18,190
+ال oxygen بهذا الشكل اسمها بيرينواضح؟ هذه الحلقة
+
+149
+00:13:18,190 --> 00:13:22,910
+اللي فيها ال oxygen اسمها بيرين والحلقة الخماسية
+
+150
+00:13:22,910 --> 00:13:28,290
+اللي فيها ال oxygen اسمها إيش؟ فيوران بناء على ذلك
+
+151
+00:13:28,290 --> 00:13:33,530
+السكر لما بيسكر على حلقة سداسية صاروا ينسبوا لل
+
+152
+00:13:33,530 --> 00:13:37,290
+بيرين فكل السكريات اللي مسكرة على حلقة سداسية
+
+153
+00:13:37,290 --> 00:13:42,190
+بيصيروا يقولوا عنها بيرانوزز بيرانوزز يعني مسكر
+
+154
+00:13:42,190 --> 00:13:46,210
+على حلقة سداسية لما بيشوف بيرين بدي أقول أن الحلقة
+
+155
+00:13:46,740 --> 00:13:53,340
+لو كان مسكر على حلقة خماسية نسبة إلى الفيوران
+
+156
+00:13:53,340 --> 00:13:58,360
+الخماسي بقول عنه ايش؟ فيرانوز فبنصير من الآن
+
+157
+00:13:58,360 --> 00:14:01,700
+نستعمل كلمتين اجداد انه لما نحكي عن الحلقة
+
+158
+00:14:01,700 --> 00:14:07,020
+السوداسية بنستعمل كلمة بيرانوز فالجولوكوز اللى
+
+159
+00:14:07,020 --> 00:14:12,620
+مسكر على حلقة سوداسية الآن بيقول عنه جلوكو بيرانوز
+
+160
+00:14:13,420 --> 00:14:17,300
+معنى Glucopyranose أنه جولوكوز مسكّر على حلقة
+
+161
+00:14:17,300 --> 00:14:23,400
+سدسية طب لو سكّر على حلقة خماسية Glucofuranose فمن
+
+162
+00:14:23,400 --> 00:14:28,200
+الآن و طالع هنصير نشوف اسمين Glucopyranose و
+
+163
+00:14:28,200 --> 00:14:32,320
+Glucofuranose لما نقول لحد إيش يعني Glucopyranose؟
+
+164
+00:14:33,530 --> 00:14:40,490
+جولوكوز مسكر على حلقة صداسية إيش معناه؟ جولوكوز
+
+165
+00:14:40,490 --> 00:14:42,830
+مسكر على حلقة خمسية، جولوكوز مسكر على حلقة خمسية،
+
+166
+00:14:42,830 --> 00:14:42,870
+جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر على حلقة
+
+167
+00:14:42,870 --> 00:14:43,730
+خمسية، جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر
+
+168
+00:14:43,730 --> 00:14:44,790
+على حلقة خمسية، جولوكوز مسكر على حلقة خمسية،
+
+169
+00:14:44,790 --> 00:14:49,350
+جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر على حلقة
+
+170
+00:14:49,350 --> 00:14:57,390
+خمسية، جولوكوز مسكر على حلقة خمسية، جولوكوز
+
+171
+00:14:57,390 --> 00:15:04,480
+مسكر على حلقة خمسية، جولوكوز مسكر على حلقة خممرتبط
+
+172
+00:15:04,480 --> 00:15:09,620
+فيها اسم Byronose واسم Furanose عشان نعرف هو مسكر
+
+173
+00:15:09,620 --> 00:15:13,840
+على أي نوع من الحلقات هتبدأوا الآن لما تشوفوا
+
+174
+00:15:13,840 --> 00:15:19,900
+الأسماء تقرؤوا هذا الكلام لاحظوا مثلا لفراكتوز لو
+
+175
+00:15:19,900 --> 00:15:25,200
+سكر
+
+223
+00:19:37,060 --> 00:19:43,280
+alcohol with anhydrides produces كلمة واحدة أستر
+
+224
+00:19:43,280 --> 00:19:50,340
+أستر الناس اللي بيدرسوا بنتبهوا كلمة سهلة جدا لما 
+
+225
+00:19:50,340 --> 00:19:54,580
+أخدنا تفاعل الكحول مع ال acids بيعطينا أستر مع ال
+
+226
+00:19:54,580 --> 00:19:59,690
+acid chloride بيعطينا أستر مع ال anhydride بيعطينا
+
+227
+00:19:59,690 --> 00:20:03,310
+Easter، مظبوط ولا لأ؟ طب لو بدنا نفعل الكحول مع ال
+
+228
+00:20:03,310 --> 00:20:08,510
+Easter، شو بيعطينا؟ 
+
+229
+00:20:08,510 --> 00:20:15,450
+كحول 
+
+230
+00:20:15,450 --> 00:20:20,330
+مع Easter كحول 
+
+231
+00:20:20,330 --> 00:20:30,950
+مع Easter إيش رأيكوا؟ Easter طبعا ي start تاني من 
+
+232
+00:20:30,950 --> 00:20:34,710
+سير الإنسان بالعملية trans esterification لأن 
+
+233
+00:20:34,710 --> 00:20:41,750
+متابعتك اضعيفة شوية في الموضوع اللي أخدناه سابقا و
+
+234
+00:20:41,750 --> 00:20:47,210
+اللي احنا محتاجينه مضطر ان اعمل شوية ايش شوية
+
+235
+00:20:47,210 --> 00:20:48,250
+مراجعة معكم
+
+236
+00:20:50,980 --> 00:20:59,460
+نعمل شوية المراجعة هى نحط كحول ميثانول كويس و 
+
+237
+00:20:59,460 --> 00:21:01,320
+نعمله بأى لون الميثانول
+
+238
+00:21:04,970 --> 00:21:11,590
+CH3OH زائد فعلوه مع الاسد ايه صيغة الاسد اي اسد
+
+239
+00:21:11,590 --> 00:21:17,070
+ناخد ال بنزويك اسد ال بنزويك اسد فنل C double bond
+
+240
+00:21:17,070 --> 00:21:23,330
+O OH فعلوه مع ال بنزويل كلورايد الاسد كلورايد فنل
+
+241
+00:21:23,330 --> 00:21:31,340
+C double bond O Cl فعلوه مع البنزويت كان هيدرايد
+
+242
+00:21:31,340 --> 00:21:38,900
+فانل C double bond O O C double bond O فانل فعلوه 
+
+243
+00:21:38,900 --> 00:21:46,680
+كمان مع الاثل بنزويت فانل C double bond O O اثلهي 
+
+244
+00:21:46,680 --> 00:21:50,860
+الكحول بتفعل مع الحمض أو مع ال acid chloride أو مع 
+
+245
+00:21:50,860 --> 00:21:55,600
+ال acid anhydride أو حتى مع ال E star الألم بده
+
+246
+00:21:55,600 --> 00:22:01,340
+يعطيني في كل الأحوال هو تفاعل واحد إبدال هذي بده
+
+247
+00:22:01,340 --> 00:22:09,200
+تخرج ييجي بدالها مثل هذي لين يفعل اللي بده يهاجم و 
+
+248
+00:22:09,200 --> 00:22:16,980
+هذي تخرج هذي بده تخرج هذي بده تخرجو بناء على ذلك
+
+249
+00:22:16,980 --> 00:22:23,660
+الناتج من كل هدولة هيكون نفس ال Easter اللي هو 
+
+250
+00:22:23,660 --> 00:22:30,220
+Phenyl C double bond O O Methyl بدل المجموعة 
+
+251
+00:22:30,220 --> 00:22:34,440
+المغادرة هذه الآن بعد ذلك أنه هنا بطلع H مع ال OH
+
+252
+00:22:34,440 --> 00:22:39,340
+زائد ميه زائد HCl زائد Benzoic acid زائد Ethanol 
+
+253
+00:22:39,340 --> 00:22:45,200
+مش مشكلة ف تفاعل الكحول مع أي واحد من الأحماض 
+
+254
+00:22:45,200 --> 00:22:50,040
+ومشتقاتها بيعطيني إيه؟ Easter كحول مع أسد، كحول مع 
+
+255
+00:22:50,040 --> 00:22:53,600
+أسد كلورايت، كحول مع أنهايدرايت، كحول مع Easter، 
+
+256
+00:22:53,600 --> 00:22:59,050
+يمكن أنا تقوله يا الله Easter أعطى Easter تاني اه
+
+257
+00:22:59,050 --> 00:23:04,630
+بس هذا ال Easter كان فنل C double bond O او اثل
+
+258
+00:23:04,630 --> 00:23:11,370
+صار فنل C double bond O او مثل اذا بدلت ال Easter 
+
+259
+00:23:11,370 --> 00:23:17,010
+ولا لأ عشان هيك بنسميه ال Transesterification ايش 
+
+260
+00:23:17,010 --> 00:23:22,610
+يعني ال Trans تحويل بتعرفوا Trans الكهربا كيف
+
+261
+00:23:22,610 --> 00:23:27,910
+بيحول بتعرفوا معناه Transformation بتعرفوا كلمة 
+
+262
+00:23:27,910 --> 00:23:33,390
+Transport انه بننجل البني .. اه ف Trans لما 
+
+263
+00:23:33,390 --> 00:23:37,550
+بتيجيكوا في أول الكلام شو معناها؟ تحويل، الآن كان
+
+264
+00:23:37,550 --> 00:23:42,210
+ال Easter، C double bond O، O-ethyl خلت ال Easter، 
+
+265
+00:23:42,210 --> 00:23:47,930
+C double bond O، O-methyl ف الكحول مع Easter بيبدل،
+
+266
+00:23:47,930 --> 00:23:52,270
+بيعمل Transesterification بدل ما كان O-ethyl صار O
+
+267
+00:23:52,270 --> 00:23:55,250
+-methyl هذه العملية شو بنسميها اللي هنا؟
+
+268
+00:24:02,320 --> 00:24:05,640
+transesterification واضح الفكرة؟ إذا مابدوش 
+
+269
+00:24:05,640 --> 00:24:10,000
+يتغلبوني لما أقولكوا الكحول مع ال acid chloride و 
+
+270
+00:24:10,000 --> 00:24:14,040
+لا مع ال anhydride، شو بده يعطيني؟ شو بده يعطي
+
+271
+00:24:14,040 --> 00:24:19,880
+الكحول مع ال anhydride؟ إيستر واضح؟ و مع ال 
+
+272
+00:24:19,880 --> 00:24:25,230
+chloride إيستر؟ مع كلهم إيسترو .. الآن إذا الكلام
+
+273
+00:24:25,230 --> 00:24:31,790
+هذا كله صار واضح عندكم بدي أجي أرجع للسكر السكر
+
+274
+00:24:31,790 --> 00:24:40,010
+اللي مسكر عبارة عن كحول ال sugar عبارة عن كحول هذا 
+
+275
+00:24:40,010 --> 00:24:45,230
+الكحول لو فعلته مع ال unhydrate شو هيعطيلي Easter
+
+276
+00:24:45,230 --> 00:24:54,480
+كل OH بده تصيرهذه الـ O H تهاجم هنا O CH3 أعمل
+
+277
+00:24:54,480 --> 00:25:00,260
+واحدة منهم واضحة O CH3 الآن الـ C double bond O
+
+278
+00:25:00,260 --> 00:25:05,680
+CH3 شو أخدنا اسمها الـ Acetyl group فالخمسة O H
+
+279
+00:25:05,680 --> 00:25:10,140
+بيصيروا كلهم O Acetyl طبعا تطلعوا معي هذا Easter
+
+280
+00:25:10,140 --> 00:25:19,280
+ولا لأ R C double bond O OR Easter فالسكر مع 
+
+281
+00:25:19,280 --> 00:25:24,100
+الانهيدريد بيعطيني Easter طيب لو جبنالكوا السؤال
+
+282
+00:25:24,100 --> 00:25:26,940
+قولنا لكوا طب لو فعلنا ال sugar مع ال acid
+
+283
+00:25:26,940 --> 00:25:31,060
+chloride برضه Easter برضه Easter المهم انه في ما
+
+284
+00:25:31,060 --> 00:25:37,820
+.. طب لو فعلنا مع ال .. مع Easter برضه Easter تاني 
+
+285
+00:25:38,910 --> 00:25:42,570
+نفس المثال اللي هناك هذا الكلام إذا ما بتتدربوش
+
+286
+00:25:42,570 --> 00:25:47,430
+عليه ما بتتقنوه الخمسة OHS كلهم اللي موجودين 
+
+287
+00:25:47,430 --> 00:25:52,790
+بيصيروا Easter اتنين تلاتة اربعة خمسة فتفاعل ال 
+
+288
+00:25:52,790 --> 00:25:58,070
+sugar مع ال acid unhydrated بيعطيني Easter خلصنا 
+
+289
+00:25:58,070 --> 00:26:04,170
+من هذه النقطة؟ كويس لاحظوا كده بتفيدني الكيميا
+
+290
+00:26:04,170 --> 00:26:10,900
+العادية وهي مقدمة ايش؟ ال biochemistry يعني مش ممكن
+
+291
+00:26:10,900 --> 00:26:14,100
+حد يجي يدرس biochemistry و نشرحله هذا التفاعل هو 
+
+292
+00:26:14,100 --> 00:26:17,500
+مش عارف الكحول و ال anhydride و ال aster و كيف 
+
+293
+00:26:17,500 --> 00:26:21,500
+بتفاعلوا مع بعض و مع البعض فكل تفاعل بمر معنها 
+
+294
+00:26:21,500 --> 00:26:27,930
+عشان تفهمه بسهولة لازم يكون المخ يرجع وين؟ للـ
+
+295
+00:26:27,930 --> 00:26:31,630
+Organic Chemistry العادية اللي استعلمته فيها هو
+
+296
+00:26:31,630 --> 00:26:35,910
+اللي بيرجع يمر علينا هنا يعني لو مثلا أخدنا هذا 
+
+297
+00:26:35,910 --> 00:26:49,170
+التفاعل R O H زائد CH3I هاي التفاعل العادي Alkyl 
+
+298
+00:26:49,170 --> 00:26:49,790
+Halide
+
+299
+00:26:52,600 --> 00:26:55,880
+النيوكليوفايل ايش بيعمل النيوكليوفايل بالالكي
+
+300
+00:26:55,880 --> 00:27:04,160
+الهيلايد؟ هذا الشبطر ايش؟ ستة بيهاجر، بيحل محل و 
+
+301
+00:27:04,160 --> 00:27:08,460
+النيوترال نيوكليوفايل اللي بيفقد؟ H إذا هنا إيش
+
+302
+00:27:08,460 --> 00:27:16,980
+بده يصير عندكم؟ R O CH3 إذا كحول مع الالكي
+
+303
+00:27:16,980 --> 00:27:19,500
+الهيلايد، شو بيعطيني؟ إيثر 
+
+304
+00:27:22,220 --> 00:27:30,660
+ROR Ether الآن ال sugar عبارة عن كحول ولا خمس
+
+305
+00:27:30,660 --> 00:27:34,940
+كحولات في بعض؟ خمس كحولات فعلوه مع المثل Iodide 
+
+306
+00:27:35,670 --> 00:27:41,650
+هيعطيني كم إيثر؟ خمس إيثرات مثل او كاربون مثل او 
+
+307
+00:27:41,650 --> 00:27:45,070
+كاربون مثل او كاربون مثل او كاربون مثل او كاربون 
+
+308
+00:27:45,070 --> 00:27:49,570
+واضح الفكرة؟ هو نفس هذا التفاعل البسيط أن الكحول
+
+309
+00:27:49,570 --> 00:27:55,450
+بيحل محل اليود ولذلك ملخص هدول التنتين أن الكحول
+
+310
+00:27:55,450 --> 00:28:00,950
+مع الانهيدريد بيعطيني إيثر للشجر والكحول مع ال مثل
+
+311
+00:28:00,950 --> 00:28:07,890
+أيودايد بيعطيني إيثرلل sugar و طالما انه موجود من
+
+312
+00:28:07,890 --> 00:28:12,230
+الكحول خمس مجموعات اذا كم Easter و كم Ether هيتكون 
+
+313
+00:28:12,230 --> 00:28:20,020
+عندى اذا بعد ما أخدنا تفاعلالشجر بصفته alcohol مع
+
+314
+00:28:20,020 --> 00:28:23,620
+ال unhydrate قولنا بيعطي ether مع ال alkyl halide
+
+315
+00:28:23,620 --> 00:28:27,800
+زي ال methyl iodide قولنا بيعطي ether بدنا ناخد 
+
+316
+00:28:27,800 --> 00:28:33,380
+تفاعل تاني للشجر أيضا مر علينا هذا التفاعل لو 
+
+317
+00:28:33,380 --> 00:28:38,500
+أجينا بدنا نعمل reduction للشجر هنحتاج جملة من 
+
+318
+00:28:38,500 --> 00:28:43,420
+الكيميا القديمة نقول reduction of aldehyde
+
+319
+00:28:43,420 --> 00:28:49,910
+produces ايش primary الكوكبوس تمام هتقول هو ال
+
+320
+00:28:49,910 --> 00:28:55,390
+sugar ال dehyde احنا بنقول ال sugar موجود أساسا
+
+321
+00:28:55,390 --> 00:29:03,790
+بشكل acyclic او بشكل cyclic و بينهم اتزان ان هو
+
+322
+00:29:03,790 --> 00:29:08,390
+اللي موجود بنسبة أكبر ال cyclic ولا ال acyclic ال 
+
+323
+00:29:08,390 --> 00:29:13,310
+cyclic هذا موجود بنسبة قليلة جدا قولنا بنسبة ايش
+
+324
+00:29:13,310 --> 00:29:19,430
+تلاتة بال ألف نسبة قليلة جدا المهم هذا الشكل في 
+
+325
+00:29:19,430 --> 00:29:23,390
+الديهيد لو جيت اعمله reduction بالهيدروجين في وجود 
+
+326
+00:29:23,390 --> 00:29:28,130
+كتاليست ال الديهيد شو بده يصير ال primary alcohol
+
+327
+00:29:28,130 --> 00:29:34,270
+طبعا الان بيصير السؤال reduction of sugars
+
+328
+00:29:34,270 --> 00:29:38,650
+produces primary alcohol طبعا طالما كل هدولة أساسا
+
+329
+00:29:38,650 --> 00:29:44,940
+OH كان في الديهيد واحدة وصارت OH صار Polyhydroxy 
+
+330
+00:29:44,940 --> 00:29:49,740
+Alcohol اللي هو مار عليكم الـ Sorbitol اللي فيه ست
+
+331
+00:29:49,740 --> 00:29:54,060
+مجموعات OH بطل في ال الديهيد هو كان خمسة OH و 
+
+332
+00:29:54,060 --> 00:29:55,840
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+333
+00:29:55,840 --> 00:29:56,120
+الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و
+
+334
+00:29:56,120 --> 00:29:57,620
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال 
+
+335
+00:29:57,620 --> 00:29:57,880
+الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و
+
+336
+00:29:57,880 --> 00:29:59,140
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+337
+00:29:59,140 --> 00:30:01,540
+الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و
+
+338
+00:30:01,540 --> 00:30:05,260
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+339
+00:30:05,260 --> 00:30:11,460
+الديهيد و واحدة ال الديهيد و واحدة ال ال
+
+340
+00:30:13,000 --> 00:30:19,980
+أمنا و اتحول و أصار الكهول طب و اللي ضايل هنا إيش
+
+341
+00:30:19,980 --> 00:30:20,680
+رأيكوا فيه؟
+
+342
+00:30:24,980 --> 00:30:29,960
+كل ما هذا جزء منه صار alcohol بعوضه جزء من هذا 
+
+343
+00:30:29,960 --> 00:30:34,760
+بيعمل ring opening في نهاية التفاعل إيش بتتوقعوا
+
+344
+00:30:34,760 --> 00:30:40,960
+نشوف ان هذا كله هينتهي يعني كل ما هذا بتحول بيروح
+
+345
+00:30:40,960 --> 00:30:45,780
+المسكر بيفتح كل ما هذا بتحول المسكر بيفتح هذه
+
+346
+00:30:45,780 --> 00:30:50,200
+القاعدة في الاتزان من اذكرنا ايش اسمها مرت عليكم
+
+347
+00:30:52,610 --> 00:30:56,330
+إعادة الإتزان، إنه الإتزان يعود إلى وضعه الطبيعي، 
+
+348
+00:30:56,330 --> 00:31:01,290
+يعني دول الاتنين في اتزان، سحبنا هذا، فعلناه،
+
+349
+00:31:01,290 --> 00:31:04,710
+بيرود هذا يعمل اتزان من أول لجديد، سحبنا هذا، 
+
+350
+00:31:04,710 --> 00:31:11,850
+بيرود هذا يفتح، لتشكله principal واضح؟ وبناء على
+
+351
+00:31:11,850 --> 00:31:17,210
+ذلك لو احنا جيبنالكوا سؤال في الامتحان قولنا هذا و 
+
+352
+00:31:17,210 --> 00:31:22,150
+هذا في حالة اتزان اكملوا المعادلة هتكملونهان طيب
+
+353
+00:31:22,150 --> 00:31:26,930
+يا ترى لو اجينا سألناكوا ما حطيناش هذا من الأساس 
+
+354
+00:31:26,930 --> 00:31:32,710
+كتبنالكوا بس هذا و reduction إيش هتعملونه؟ هتقولوا 
+
+355
+00:31:32,710 --> 00:31:39,630
+مفهوم ضمنه إن هذا متزل مع الفاتح و بناء على ذلك
+
+356
+00:31:39,630 --> 00:31:43,710
+سيعمل reduction ويعطي هذا يعني لو رسمت أنا بس هذا 
+
+357
+00:31:43,710 --> 00:31:49,070
+وقلت لكم H2 و Catalyst في نهاية هذه الجواب لكن للفهم 
+
+358
+00:31:49,070 --> 00:31:53,250
+كيف هذا الكلام بيصير بيقول ال .. ال cyclic صار إيه
+
+359
+00:31:53,250 --> 00:31:57,350
+ال cyclic؟ و صار إله reduction وكل ما هذا صار إله
+
+360
+00:31:57,350 --> 00:32:02,450
+reduction كل ما ال cyclic من أول و جديد بيفتح إلى
+
+361
+00:32:02,450 --> 00:32:08,840
+أن يتحول كل ال cyclic اللي موجود هنا إلى إلى الكحول
+
+362
+00:32:08,840 --> 00:32:13,320
+اللي هو sorbitol واضح؟ لاحظوا معنا احنا الان
+
+363
+00:32:13,320 --> 00:32:20,360
+استفدنا من ايش؟ من مجموعة ال aldehyde الناس
+
+364
+00:32:20,360 --> 00:32:24,280
+اللي متذكرين كويس معنا لما شرحنا ال aldehyde قولنا
+
+365
+00:32:24,280 --> 00:32:28,180
+ال aldehyde واقف على نص السلم إيش يعني ال aldehyde
+
+366
+00:32:28,180 --> 00:32:34,900
+واقف على نص السلم او في نص الطريقالديهايد ممكن 
+
+367
+00:32:34,900 --> 00:32:42,320
+تنزل لالكهول زي ما عملت هنا بال reduction و بنفس
+
+368
+00:32:42,320 --> 00:32:52,120
+الوقت ممكن تطلع فوق ل acid بال oxidation واضح؟
+
+369
+00:32:52,120 --> 00:32:58,320
+ماشي الترتيب اللي عندى ال alcohol الديهايد
+
+370
+00:32:59,060 --> 00:33:06,000
+acid أكسدة الكحول تعطي الديهايد أكسدة الديهايد
+
+371
+00:33:06,000 --> 00:33:11,020
+تعطي acid اختزال الكحول بيصير alcohol اختزال 
+
+372
+00:33:11,020 --> 00:33:15,520
+الديهايد بيصير alcohol أكسدة الديهايد بيصير acid
+
+373
+00:33:15,520 --> 00:33:19,820
+الآن احنا التفاعل اللي موجود عندنا اختزال الديهايد 
+
+374
+00:33:19,820 --> 00:33:25,990
+رجع لإيش؟ لالكحول طب لو عملنا أكسدة للديهايد هيصير
+
+375
+00:33:25,990 --> 00:33:30,990
+acid واضح الفكرة المشكلة في الموضوع كالقاتل انه 
+
+376
+00:33:30,990 --> 00:33:35,470
+احنا قولنا اكسدة ال الديهيد بال oxidation بيصير 
+
+377
+00:33:35,470 --> 00:33:40,150
+acid و اكسدة الكحول بعمل مؤكسد قوي برضه بيصير إيش 
+
+378
+00:33:40,150 --> 00:33:44,410
+acid متذكرين لما أخدنا oxidation و في primary
+
+379
+00:33:44,410 --> 00:33:50,330
+alcohol حسب نوع المؤكسد تمام طيب هذا ال sugar إيش 
+
+380
+00:33:50,330 --> 00:33:57,020
+موجود فيه في الديهيد و في كحولات بالذات ال primary
+
+381
+00:33:57,020 --> 00:34:01,540
+alcohol بناء على ذلك هتلاحظوا لما نيجي ندرس ال
+
+382
+00:34:01,540 --> 00:34:05,900
+acid ده انه هيمروا معناه حالتين ممكن عامل مؤكسد
+
+383
+00:34:05,900 --> 00:34:10,560
+نستعمله فقط acid ال aldehyde ل acid يعني يصير عندى 
+
+384
+00:34:10,560 --> 00:34:15,240
+على الطرف هذا إيش acid عامل مؤكسد تاني اقوى منه ب
+
+385
+00:34:15,240 --> 00:34:19,400
+acid ال aldehyde و ب acid ال primary alcohol بيصير 
+
+386
+00:34:19,400 --> 00:34:23,780
+عندى إيش dye acid إن شوف هذا الكلام
+
+387
+00:34:26,870 --> 00:34:31,270
+لو أخدنا Sugar مع عامل مؤكسد خلينا نقول ضعيف 
+
+388
+00:34:31,270 --> 00:34:36,330
+لبرومين ميّه أو فضّه مع انحاس خلينا نركز برومين 
+
+389
+00:34:36,330 --> 00:34:41,670
+و وتر ب أكسد ال الديهيد بدل ما هو CHO بصير سيضه
+
+390
+00:34:41,670 --> 00:34:46,490
+بالموند OOH صار أسد، إذا لبرومين ووتر كام أكسدة
+
+391
+00:34:46,490 --> 00:34:51,010
+عمل عندى؟ أكسدة واحدة، بس أكسد ال الديهيد خلّاه
+
+392
+00:34:51,010 --> 00:34:55,250
+أيش أسد؟ الآن وقت الديجلوكوز بنقول عنه بصير
+
+393
+00:34:55,250 --> 00:35:00,030
+gluconic acid فال gluconic acid يحتوي على كام 
+
+394
+00:35:00,030 --> 00
+
+445
+00:39:31,220 --> 00:39:36,080
+anomeric carbon بنقول عنها glycosides هذه الرابطة
+
+446
+00:39:36,080 --> 00:39:38,720
+اللي بين ال anomeric carbon و ال oxygen اللي هي
+
+447
+00:39:38,720 --> 00:39:43,760
+carbon O مثل او carbon OR بنسميها glycosidic bond
+
+448
+00:39:43,760 --> 00:39:49,740
+هذه الرابطة الجديدة اللي كانت متصلة مع ال OH صارت
+
+449
+00:39:49,740 --> 00:39:55,840
+متصلة مع ايش؟ مع ال OR شو بنسميها؟ Glycosidic bond
+
+450
+00:39:55,840 --> 00:40:03,080
+موجودة و لها أهمية جزء كبير من أهمية هذه المنطقة
+
+451
+00:40:03,080 --> 00:40:07,660
+أنه لما بعدك السكريات بدهم يبدوا يعملوا dimers مع 
+
+452
+00:40:07,660 --> 00:40:11,560
+بعض يتحدوا هنلاحظ فائدة هذه ال glycosidic bond
+
+453
+00:40:11,560 --> 00:40:15,000
+لأنه بربطوا من خلالها واضح؟ يربطوا مع بعض من 
+
+454
+00:40:15,000 --> 00:40:22,700
+خلالها و اجينا رسمنالكم مركب هذا sugar من 
+
+455
+00:40:22,700 --> 00:40:27,900
+الجلوكوز هل هذا يا تورا فيه glycosidic bond ولا 
+
+456
+00:40:27,900 --> 00:40:38,380
+لأ تطلع عليه هاي carbon اوCarbon اذا هذا المركب 
+
+457
+00:40:38,380 --> 00:40:43,600
+اللى اسمه ساليسين من شجر الصفصاف لما كانوا بيغلو 
+
+458
+00:40:43,600 --> 00:40:47,140
+شجر الصفصاف بيطلع هذا المركب كانوا ياخدوله الصداع 
+
+459
+00:40:47,140 --> 00:40:52,440
+الناس زمان فيه glycosidic bond لاحظوا اللى 
+
+460
+00:40:52,440 --> 00:40:58,900
+بتتأمل فيه بشكل بشكل قوي هتلاحظ ان هذا بيشبه ايش 
+
+461
+00:40:58,900 --> 00:41:02,040
+الاسبيرين 
+
+462
+00:41:03,920 --> 00:41:10,960
+تذكروا الاسبيرين كان بنزينة و COOH و CH2O و بعدين 
+
+463
+00:41:10,960 --> 00:41:15,500
+أوهانة OH نخليها OCOC double bond Oacetyl يعني
+
+464
+00:41:15,500 --> 00:41:20,020
+وجود البنزينة و ال orthoposition هذا بشبه أي دوة؟
+
+465
+00:41:20,020 --> 00:41:25,580
+بشبه الاسبيرين هذا مثلا منتج طبيعي فيه glycosidic
+
+466
+00:41:25,580 --> 00:41:30,170
+bond ولا لأ؟ هيهالما تكون هذه الرابطة اللي هنا مش
+
+467
+00:41:30,170 --> 00:41:36,350
+OH OR بنقول هذا إيش المركب glycoside و ال bond إيش 
+
+468
+00:41:36,350 --> 00:41:43,650
+بنوصفها؟ بنقول عنها glycosidic bond الآن زي ما 
+
+469
+00:41:43,650 --> 00:41:48,330
+اتفقنا أن ال glycosides وين بيفيدوني كتير أنا؟لما 
+
+470
+00:41:48,330 --> 00:41:53,550
+بدي ادمج سكارين مع بعض لما بدي ادمج سكارين مع بعض 
+
+471
+00:41:53,550 --> 00:41:57,390
+هاجي على هذه ال oxygen و اصير اربط من خلالها الان 
+
+472
+00:41:57,390 --> 00:42:01,410
+دمج سكارين مع بعض قصة طويلة اش السكارين و اش 
+
+473
+00:42:01,410 --> 00:42:06,370
+السكارتونة اللى بده يطلع عندى هو ملتوز سكاروز سيلو 
+
+474
+00:42:06,370 --> 00:42:11,490
+بيوز كذا كذا موضوع كبير بحاجة الى ان نفرد له ان شاء 
+
+475
+00:42:11,490 --> 00:42:17,580
+الله محاضرة كاملة بس لاحظوا مباشرة هتلاحظوا انه اول 
+
+476
+00:42:17,580 --> 00:42:22,580
+ما بدي احكي عن سكارين دمجتهم هاي رابط هنا تطلعوا 
+
+477
+00:42:22,580 --> 00:42:27,980
+عليها carbon او carbon ال glycosidic bond ولا لأ 
+
+478
+00:42:27,980 --> 00:42:33,520
+عشانك احنا أخدنا ال glycosides لأنه في ال 
+
+479
+00:42:33,520 --> 00:42:37,620
+disaccharides هتلاقوا عندي ال glycosidic bond طبعا 
+
+480
+00:42:37,620 --> 00:42:41,760
+إيش السكارين اللي بيندمجوا و إيش السكر ثناء اللي
+
+481
+00:42:41,760 --> 00:42:46,920
+بيطلع هذا بيكون موضوع المحاضرة القادمة ان شاء الله
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4a075348eece73c87e077b423cbeb4fa63de7f1f
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_postprocess.srt
@@ -0,0 +1,1924 @@
+1
+00:00:19,490 --> 00:00:24,290
+بسم الله الرحمن الرحيم المرة الماضية بدينا في
+
+2
+00:00:24,290 --> 00:00:28,130
+موضوع ال carbohydrates بدينا في موضوع ال
+
+3
+00:00:28,130 --> 00:00:34,450
+carbohydrates وقولنا انه امكوانين من carbon و ما
+
+4
+00:00:34,450 --> 00:00:41,130
+.. و بعدين طبعا بدينا في ال sugarsقولنا ال sugars
+
+5
+00:00:41,130 --> 00:00:45,030
+في النهاية هما ال الديهيدز او كيتونز لكن فيهم
+
+6
+00:00:45,030 --> 00:00:48,670
+مجموعات اوقاتش كثيرة بوليهيدروكسي الديهيدز او
+
+7
+00:00:48,670 --> 00:00:55,050
+بوليهيدروكسي كيتونز طبعا بسبب وجود ال chiral
+
+8
+00:00:55,050 --> 00:01:00,910
+centersبصير عندنا عدد ال isomers للصيغة الواحدة
+
+9
+00:01:00,910 --> 00:01:06,330
+كتير و اتدرجنا طبعا من أبسط مركب في one chiral
+
+10
+00:01:06,330 --> 00:01:11,690
+center اللي هو ال glycerol dihyde و رسمنا بطرق
+
+11
+00:01:11,690 --> 00:01:22,940
+مختلفة شوفنا كيف المركبات هذه ممكن تكونD أو L في
+
+12
+00:01:22,940 --> 00:01:25,300
+المرحلة الأولى و لو قلنا لو عندنا one chiral
+
+13
+00:01:25,300 --> 00:01:30,540
+center بيصير في عندنا مركبين بعد هيك قصة ال D و L
+
+14
+00:01:30,540 --> 00:01:34,580
+بتستمر بزيادة ال chiral center و بيبدأ العدد يزيد
+
+15
+00:01:34,580 --> 00:01:43,040
+فبناء على ذلك بناء على ذلك فبموضوع
+
+16
+00:01:43,040 --> 00:01:46,140
+ال sugars
+
+17
+00:01:47,420 --> 00:01:52,440
+قلنا أساسي جدا نتطلع على ال chiral centers و نتذكر
+
+18
+00:01:52,440 --> 00:01:55,620
+كل الكلام اللي حكيناه في chiral centers في chapter
+
+19
+00:01:55,620 --> 00:01:59,460
+4 إذا عندنا one chiral center بنتوقع مركبين two
+
+20
+00:01:59,460 --> 00:02:04,480
+chiral centers بنتوقع أربعة و هكذا بدأنا بالتدريج
+
+21
+00:02:04,480 --> 00:02:09,980
+و أخر شيء انتهينا عنده احنا لما كان في عندنا ست
+
+22
+00:02:09,980 --> 00:02:17,870
+ذرات كربون طبعا لما بيكون عندى ست ذرات كربونعلى
+
+23
+00:02:17,870 --> 00:02:22,090
+حسب ما بنرسم احنا ال sugar بالطريقة اللي اتعلمناها
+
+24
+00:02:22,090 --> 00:02:27,370
+الذرة الأولى من فوق الديهايد وبناء على ذلك هذا مش
+
+25
+00:02:27,370 --> 00:02:32,550
+chiral center والذرة الأخيرة من تحت CH2OH مش
+
+26
+00:02:32,550 --> 00:02:36,970
+chiral center واجتها لو رسمنا الشكل اللي بنسميه
+
+27
+00:02:36,970 --> 00:02:42,950
+الacyclic structure بيكون فينا كام isomer كام
+
+28
+00:02:42,950 --> 00:02:50,800
+chiral center أربعة بيقدروا إلىالان طالما ان السكر
+
+29
+00:02:50,800 --> 00:02:55,840
+عبارة عن الكهول و الديهايد لو جربنا نجعل الكهول
+
+30
+00:02:55,840 --> 00:03:00,640
+يسكر على الديهايد هيعمل a new chiral center هيصير
+
+31
+00:03:00,640 --> 00:03:07,080
+اندفعخمسة كايرال سنترز وجدت بنتوقع انه لسكر مكون
+
+32
+00:03:07,080 --> 00:03:11,460
+من ست ذرات كربون بهذا الشكل يكون عنده اتنين و
+
+33
+00:03:11,460 --> 00:03:17,320
+تلاتين ايزومات طبعا لما تمت عملية الاغلاق لما تمت
+
+34
+00:03:17,320 --> 00:03:23,040
+عملية اغلاق الالكول على ال الديهايدبهذا الشكل
+
+35
+00:03:23,040 --> 00:03:28,100
+اتكون عندى هنا ال new chiral center وقولنا
+
+36
+00:03:28,100 --> 00:03:30,920
+الكاربون هذه اللى بتعمل ال new chiral center شو
+
+37
+00:03:30,920 --> 00:03:35,460
+بنسميها احنا انوميرك كاربون الان معنى new chiral
+
+38
+00:03:35,460 --> 00:03:40,060
+center ان هو ال OH هذى بنسميها اما لأعلىوإما لأسفل
+
+39
+00:03:40,060 --> 00:03:44,460
+وقلنا إذا بتكون لأسفل بنقول هذا Alpha compound
+
+40
+00:03:44,460 --> 00:03:48,740
+وإذا بتكون لأعلى بيقول هذا Beta الآن طالما أنه في
+
+41
+00:03:48,740 --> 00:03:52,560
+أربعة chiral centers كان عنده 16 مركب كل واحد فيهم
+
+42
+00:03:52,560 --> 00:03:55,840
+لما بده يسكر بده يقسم Alpha Beta Alpha Beta معنا
+
+43
+00:03:55,840 --> 00:04:01,820
+ذلك المجموع صار إيش 32 مركب هذا تقريبا أخر شيء
+
+44
+00:04:01,820 --> 00:04:08,390
+انتهينا فيه الآن اللي بدي أنبهلهطيب الآن قلنا في
+
+45
+00:04:08,390 --> 00:04:15,210
+عندنا شكل a cyclic و أشكال cyclic لأ هذا السكر ال
+
+46
+00:04:15,210 --> 00:04:21,450
+a cyclic يترى بأي نسبة عادة موجود في المحلول و ال
+
+47
+00:04:21,450 --> 00:04:26,860
+cyclic بأي نسبة موجودين في المحلولالصحيح أن الـ
+
+48
+00:04:26,860 --> 00:04:33,080
+acyclic في محلول مائي يوجد بنسبة قليلة جدا جدا جدا
+
+49
+00:04:33,080 --> 00:04:37,000
+يعني معظم السكر بينوجد على شكل الحلقة النسبة اللي
+
+50
+00:04:37,000 --> 00:04:43,460
+بينوجد فيها ال acyclic في محلول مائي هي 0.003
+
+51
+00:04:43,460 --> 00:04:50,780
+بيرزة تلاتة من ألف يعني أكاد يكون مش موجود إذا
+
+52
+00:04:50,780 --> 00:04:57,310
+كأنه كل السكربسكر واضح كأنه كل السكر بيسكر لما
+
+53
+00:04:57,310 --> 00:05:01,290
+نقول هذه النسبة قليلة جدا اللى بينوجد فيها الـA
+
+54
+00:05:01,290 --> 00:05:05,630
+Cycle طيب كل السكر بيسكر بيسكر على ايش Alpha و
+
+55
+00:05:05,630 --> 00:05:10,550
+Beta هل بيكونوا بنفس النسبة اتعودنا او حكينا انه
+
+56
+00:05:10,550 --> 00:05:16,930
+لأ بيكون ال Beta بالمعدل حوالي 64والألف حوالي 36
+
+57
+00:05:16,930 --> 00:05:24,030
+او هنا 35.5 يمكن هناك 64.5 و هنا 35.5 لو بدنا نسيب
+
+58
+00:05:24,030 --> 00:05:31,860
+شوية دقيقة واضح يمكن البعض يقولطب كيف جدروا يفصلوا
+
+59
+00:05:31,860 --> 00:05:36,080
+هذا لوحده يعني طالما انه هذا اتزان ما بين ال alpha
+
+60
+00:05:36,080 --> 00:05:40,540
+و ال beta يعني دايما المخلوط موجود فيه التنين كيف
+
+61
+00:05:40,540 --> 00:05:43,940
+يتعرفوا على ال alpha لحاله اذا انا بحط في المحلول
+
+62
+00:05:43,940 --> 00:05:48,560
+المائي بينوجدوا التنين الجواب اه في المحلول المائي
+
+63
+00:05:48,560 --> 00:05:53,160
+بينوجدوا التنين فعلالكن لو اعملنا للمركب
+
+64
+00:05:53,160 --> 00:05:59,460
+crystallization تبلر من محلول Methanol فقط بيطلع
+
+65
+00:05:59,460 --> 00:06:04,300
+عند ال alpha نقي يعني انا في غير الميه بقدر احصل
+
+66
+00:06:04,300 --> 00:06:10,400
+ال alpha نقي ال alpha ال pure alpha وين بشوفه
+
+67
+00:06:10,400 --> 00:06:15,440
+بمحلول ايش؟الميثانول فلو عملنا crystallization
+
+68
+00:06:15,440 --> 00:06:19,180
+للسكر هذا ال جولوكوز بمحلول الميثانول باخد ال
+
+69
+00:06:19,180 --> 00:06:23,320
+alpha لوحده واضح الفكرة؟ الان لو عملت
+
+70
+00:06:23,320 --> 00:06:30,020
+crystallization بال acidic acid بحصل على ال beta
+
+71
+00:06:30,020 --> 00:06:38,760
+لوحده فقط ايش؟ ال beta ال pure betaواضح؟ الان لو
+
+72
+00:06:38,760 --> 00:06:42,760
+اجيت اخدت انا صار في عندى alpha pure يعني صار في
+
+73
+00:06:42,760 --> 00:06:47,100
+عندى بوتل في alpha pure بوتل تاني في beta pure ال
+
+74
+00:06:47,100 --> 00:06:51,590
+alpha pure من وين باخده؟من خلال الميثانول ال beta
+
+75
+00:06:51,590 --> 00:06:55,910
+pure من ال acetic acid الآن لو جبت ال alpha pure
+
+76
+00:06:55,910 --> 00:07:01,750
+حطيته في الميه في محلول الميه بيصير يعمل التحول
+
+77
+00:07:01,750 --> 00:07:05,730
+لacyclic و برد سكر alpha beta إلى أن يصل إلى
+
+78
+00:07:05,730 --> 00:07:10,410
+الاتزان اللى اتفقنا عليه ال 36 و64 فهذا الاتزان
+
+79
+00:07:10,410 --> 00:07:16,370
+وين بيكون موجود في ال aqueous solutionفي المحلول
+
+80
+00:07:16,370 --> 00:07:21,370
+المائي لو بدأت بالألفة النقي هيصل لهذا الاتزان و
+
+81
+00:07:21,370 --> 00:07:26,730
+لو بدأت بالبيتا النقي أيضا هيصل لهذا الاتزان واضح؟
+
+82
+00:07:26,730 --> 00:07:31,510
+إذا بالإمكان إن أنا أفصل ألفة نقي ب solvent غير
+
+83
+00:07:31,510 --> 00:07:35,870
+الميه وبيتا نقي ب solvent غير الميه لكن في الميه
+
+84
+00:07:35,870 --> 00:07:41,270
+لو بدأت بأي واحد فهيحصل الاتزان اللي هو بين ألفة
+
+85
+00:07:41,270 --> 00:07:48,250
+وبيتابنسبة 36 ل 64 هذا الكلام بيعني شغلة بيعني ان
+
+86
+00:07:48,250 --> 00:07:53,770
+which is more stable ال alpha ولا ال beta ال beta
+
+87
+00:07:53,770 --> 00:07:58,870
+اللي موجود بنسبة اكبر هو اللي بيكون more stable
+
+88
+00:07:58,870 --> 00:08:01,490
+واضح هذه الفكرة
+
+89
+00:08:05,630 --> 00:08:10,350
+بعد هيك بدنا ننتبه لنقطة أنه لما بتم الإغلاق ال
+
+90
+00:08:10,350 --> 00:08:15,130
+الديهايد مجموعة واحدة مش موضوع خلافي لكن ال OHS
+
+91
+00:08:17,200 --> 00:08:25,520
+أكتار زي ما اتكلمنا هذه OH ممكن تسكرها و إغلاق
+
+92
+00:08:25,520 --> 00:08:29,580
+أي OH يعطي حلقة بحجم مختلف يعني لو أغلقت من هنا
+
+93
+00:08:29,580 --> 00:08:35,060
+ستكون حلقة ثلاثية لو هيك سكرت ربعية لو هذه سكرت
+
+94
+00:08:35,060 --> 00:08:40,980
+خمسية هذه اللي سكرت السداسية هذه سبعية هل يترا
+
+95
+00:08:40,980 --> 00:08:47,530
+ممكن أن يتم إغلاقات لغير الحلقة السداسية؟اللي
+
+96
+00:08:47,530 --> 00:08:53,130
+مشهور حقيقة انه بتم اغلاق من ال OH اللي موجودة هنا
+
+97
+00:08:53,130 --> 00:08:59,730
+وبيعطيني حلقة خماسية لكن قداش نسبة السكر اللي
+
+98
+00:08:59,730 --> 00:09:05,970
+بيكون كحلقة خماسية واحد في المية يعني لاحظوا لو
+
+99
+00:09:05,970 --> 00:09:09,930
+انا بدي اجي على المحلول بالمجمل هقول في عندي واحد
+
+100
+00:09:09,930 --> 00:09:15,870
+في المية حلقة خماسية في عندي تلاتة بالألف إيه
+
+101
+00:09:15,870 --> 00:09:23,200
+صايفلك؟فاتح والباقي حلقة سداسية بتكون النسبة بين
+
+102
+00:09:23,200 --> 00:09:31,200
+مكوناتها 64 إلى 36 واضح فالمحلول هيكون فيه اكثر من
+
+103
+00:09:31,200 --> 00:09:36,100
+شغلة هيكون فيه محلول الجولوكوز الacyclic بنسبة
+
+104
+00:09:36,770 --> 00:09:43,010
+تلاتة في الألف المسكّر على حلقة خماسية بيكون بنسبة
+
+105
+00:09:43,010 --> 00:09:46,370
+واحد في المية الاناليبيكي اللي هو التسعة وتسعين في
+
+106
+00:09:46,370 --> 00:09:51,050
+المية كيف بتكون مقصومة اربعة وستين في المية منها
+
+107
+00:09:51,050 --> 00:09:55,410
+بيتا ستة و تلاتين في المية منها الفة واضح الفكرة
+
+108
+00:10:01,460 --> 00:10:06,660
+طبعا احنا قولنا كلمة و وضحناها المرة الماضية ان ال
+
+109
+00:10:06,660 --> 00:10:10,860
+beta is more stable than the alpha لان لو رسمنا
+
+110
+00:10:10,860 --> 00:10:14,920
+الحلقة السوداسية على الشكل اللى عادة بتكون موجودة
+
+111
+00:10:14,920 --> 00:10:18,420
+فيه و يمكن مار علينا لما أخدنا الحلقات السوداسية
+
+112
+00:10:18,420 --> 00:10:21,140
+نقطين وجد على شكل both
+
+113
+00:10:23,360 --> 00:10:27,920
+أو chair which is more stable chair conformation
+
+114
+00:10:27,920 --> 00:10:31,620
+الان لو حطيتها على هيئة الكرسي في ال chair
+
+115
+00:10:31,620 --> 00:10:37,480
+conformation ال OH ممكن تكون بشكل أفقي بهذا الشكل
+
+116
+00:10:37,480 --> 00:10:43,460
+بنقول عنها equatorial equatorial يعني بشكل أفقي
+
+117
+00:10:43,460 --> 00:10:48,040
+يعني لما نتخيل أنه الشكل العام للحلقات بهذا الشكل
+
+118
+00:10:48,040 --> 00:10:55,070
+هي بتكون زي هيكهذه equatorial الان ممكن تكون في
+
+119
+00:10:55,070 --> 00:11:01,830
+شكل تاني axial رأس عمودي هيك equatorial هيك axial
+
+120
+00:11:01,830 --> 00:11:09,740
+الان بالشكل هذا بتكون ايش؟أكسيال طبعا ال
+
+121
+00:11:09,740 --> 00:11:13,820
+equatorial الفراغ اللي حواليها أفضل من الفراغ اللي
+
+122
+00:11:13,820 --> 00:11:18,180
+حواليه الأكسيال الأكسيال crowded لاحظوا فيها
+
+123
+00:11:18,180 --> 00:11:21,600
+steric hindrance فيها ممانعة فراغية مالهاش واسعة
+
+124
+00:11:21,600 --> 00:11:26,840
+واضحالـ equatorial مترايحة أكثر ولذلك هذا الشكل ال
+
+125
+00:11:26,840 --> 00:11:31,200
+equatorial هو ال beta هذا الشكل ال axial هو ال
+
+126
+00:11:31,200 --> 00:11:35,900
+alpha عشان هيك ال beta بيكون more stable لأن ال OH
+
+127
+00:11:35,900 --> 00:11:39,820
+اللي موجودة فيه ال new chiral center لأنميرك كربون
+
+128
+00:11:39,820 --> 00:11:43,860
+بتكون مترايحة من الناحية الفرغية مافيش حد مضايقها
+
+129
+00:11:43,860 --> 00:11:48,440
+واضح؟ لحظوا هذه ال OH الجديدة اللي اتكونت عندىالان
+
+130
+00:11:48,440 --> 00:11:52,740
+في ال equatorial form هي مترايحة في ال axial form
+
+131
+00:11:52,740 --> 00:11:57,160
+مش مترايحة في جنبها مجموعات تانية بتعمل ازدحام
+
+132
+00:11:57,160 --> 00:12:02,240
+فراغي فلما نكون بدنا نفسر ليش ال beta موجودة اكثر
+
+133
+00:12:02,240 --> 00:12:08,020
+من ال alpha بنقول because the beta o h is found in
+
+134
+00:12:08,020 --> 00:12:13,140
+the equatorial position لان موجودة في ال
+
+135
+00:12:13,140 --> 00:12:16,960
+equatorial ال equatorial is not a crowded position
+
+136
+00:12:17,870 --> 00:12:24,070
+واضح فسبب الثبات ل ال beta ان ال OH الجديدة هذه
+
+137
+00:12:24,070 --> 00:12:28,650
+اللي اتكونت عندي هنا لو رسمت الشكل على هيئة الكرسي
+
+138
+00:12:28,650 --> 00:12:32,330
+بتكون موجودة وين؟ في ال axial ولا في ال
+
+139
+00:12:32,330 --> 00:12:36,070
+equatorial؟ في ال equatorial ال equatorial is not
+
+140
+00:12:36,070 --> 00:12:39,350
+a sterically hindered molecule
+
+141
+00:12:41,870 --> 00:12:44,730
+طبعا الـ mutarotation حكينا عنه برضه المرة
+
+142
+00:12:44,730 --> 00:12:49,450
+الماضية، قلنا لو بدنا من أي واحد، حيصل لإيش؟
+
+143
+00:12:49,450 --> 00:12:50,310
+للإتزان
+
+144
+00:12:52,690 --> 00:12:57,850
+ال بيرانوز and فيرانوز structures الموضوع بسيط
+
+145
+00:12:57,850 --> 00:13:02,650
+فيهم انه احنا قلنا السكر اشهر الإغلاقات تبعته اما
+
+146
+00:13:02,650 --> 00:13:08,630
+على حلقة سداسية او على حلقة خماسية الان في ال
+
+147
+00:13:08,630 --> 00:13:12,610
+heterocyclic chemistry الحلقة السداسية اللى فيها
+
+148
+00:13:12,610 --> 00:13:18,190
+ال oxygen بهذا الشكل اسمها بيرينواضح؟ هذه الحلقة
+
+149
+00:13:18,190 --> 00:13:22,910
+اللي فيها ال oxygen اسمها بيرين والحلقة الخماسية
+
+150
+00:13:22,910 --> 00:13:28,290
+اللي فيها ال oxygen اسمها إيش؟ فيوران بناء على ذلك
+
+151
+00:13:28,290 --> 00:13:33,530
+السكر لما بيسكر على حلقة سداسية صاروا ينسبوا لل
+
+152
+00:13:33,530 --> 00:13:37,290
+بيرين فكل السكريات اللي مسكرة على حلقة سداسية
+
+153
+00:13:37,290 --> 00:13:42,190
+بيصيروا يقولوا عنها بيرانوزز بيرانوزز يعني مسكر
+
+154
+00:13:42,190 --> 00:13:46,210
+على حلقة سداسية لما بيشوف بيرين بدي أقول أن الحلقة
+
+155
+00:13:46,740 --> 00:13:53,340
+لو كان مسكر على حلقة خماسية نسبة إلى الفيوران
+
+156
+00:13:53,340 --> 00:13:58,360
+الخماسي بقول عنه ايش؟ فيرانوز فبنصير من الآن
+
+157
+00:13:58,360 --> 00:14:01,700
+نستعمل كلمتين اجداد انه لما نحكي عن الحلقة
+
+158
+00:14:01,700 --> 00:14:07,020
+السوداسية بنستعمل كلمة بيرانوز فالجولوكوز اللى
+
+159
+00:14:07,020 --> 00:14:12,620
+مسكر على حلقة سوداسية الآن بيقول عنه جلوكو بيرانوز
+
+160
+00:14:13,420 --> 00:14:17,300
+معنى Glucopyranose أنه جولوكوز مسكّر على حلقة
+
+161
+00:14:17,300 --> 00:14:23,400
+سدسية طب لو سكّر على حلقة خماسية Glucofuranose فمن
+
+162
+00:14:23,400 --> 00:14:28,200
+الآن و طالع هنصير نشوف اسمين Glucopyranose و
+
+163
+00:14:28,200 --> 00:14:32,320
+Glucofuranose لما نقول لحد إيش يعني Glucopyranose؟
+
+164
+00:14:33,530 --> 00:14:40,490
+جولوكوز مسكر على حلقة صداسية إيش معناه؟ جولوكوز
+
+165
+00:14:40,490 --> 00:14:42,830
+مسكر على حلقة خمسية، جولوكوز مسكر على حلقة خمسية،
+
+166
+00:14:42,830 --> 00:14:42,870
+جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر على حلقة
+
+167
+00:14:42,870 --> 00:14:43,730
+خمسية، جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر
+
+168
+00:14:43,730 --> 00:14:44,790
+على حلقة خمسية، جولوكوز مسكر على حلقة خمسية،
+
+169
+00:14:44,790 --> 00:14:49,350
+جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر على حلقة
+
+170
+00:14:49,350 --> 00:14:57,390
+خمسية، جولوكوز مسكر على حلقة خمسية، جولوكوز
+
+171
+00:14:57,390 --> 00:15:04,480
+مسكر على حلقة خمسية، جولوكوز مسكر على حلقة خممرتبط
+
+172
+00:15:04,480 --> 00:15:09,620
+فيها اسم Byronose واسم Furanose عشان نعرف هو مسكر
+
+173
+00:15:09,620 --> 00:15:13,840
+على أي نوع من الحلقات هتبدأوا الآن لما تشوفوا
+
+174
+00:15:13,840 --> 00:15:19,900
+الأسماء تقرؤوا هذا الكلام لاحظوا مثلا لفراكتوز لو
+
+175
+00:15:19,900 --> 00:15:25,200
+سكر على حلقة خمسية شو بدي أسميه فراكتوفيرانوز
+
+176
+00:15:25,200 --> 00:15:29,260
+فيرانوز عفوا فراكتوفيرانوز هي هذا شكل لفراكتوز
+
+177
+00:15:29,260 --> 00:15:34,340
+لفراكتوز نتذكر أن هو keto sugarالفراكتوز سكر
+
+178
+00:15:34,340 --> 00:15:38,060
+العناب بتكون السيضة بالبندقوفي ع موقع اتنين هو
+
+179
+00:15:38,060 --> 00:15:42,060
+كيتون مش الديهايد فلما تيجي هذه ال O H تسكر هنا
+
+180
+00:15:42,060 --> 00:15:48,580
+وتعمل chiral center هنا يعني تصير ال Ketone هذه O
+
+181
+00:15:48,580 --> 00:15:55,480
+H يا بده تكون ال O H لفوق يا بده تكون ال O H لتحت
+
+182
+00:15:55,480 --> 00:16:01,060
+إذا كانت لفوق معنا ذلك أنا بوصفهبيتا وإذا كانت
+
+183
+00:16:01,060 --> 00:16:07,240
+لاتحت أنا بوصفه ألفة الآن وصفنا كل الكلام وحسب ما
+
+184
+00:16:07,240 --> 00:16:11,340
+هو اسمه افراكتوز لأنه سكر على حلقة خمسية شو بدي
+
+185
+00:16:11,340 --> 00:16:16,880
+أقول عنه افراكتو فيورانوسو ال D و ال Alpha فاهمين
+
+186
+00:16:16,880 --> 00:16:20,940
+هو ال D من ال Stereochemistry لباقي المجموعات
+
+187
+00:16:20,940 --> 00:16:26,100
+تحديدا للمجموعة اللي قبل الأخيرة، واضح؟ فلما نقرأ
+
+188
+00:16:26,100 --> 00:16:29,740
+هذه الأسماء ما نستغرب عشان نكون عارفين معنى كل
+
+189
+00:16:29,740 --> 00:16:33,600
+مفردة بالمفردات يعني لما بتيجوا تقرؤوا اسم Sugar
+
+190
+00:16:33,600 --> 00:16:41,100
+هتلاقوا حالكوا بتقرؤوا بيتا دي إجلوكو بيرانوسالان
+
+191
+00:16:41,100 --> 00:16:47,260
+لما نيجي نسأل اي واحدة فيكم ايش يعني بيتا و دي و
+
+192
+00:16:47,260 --> 00:16:51,400
+جلوكو و بيرانوز كل هذا الكلام معناه اي هذا مركب
+
+193
+00:16:51,400 --> 00:16:59,320
+مثلا بيتا دي جلوكو بيرانوز البيتا معنا ذلك لما سكر
+
+194
+00:16:59,320 --> 00:17:06,020
+السكر كانت ال OH لفوق ولا لتحت لفوق ال Dلما نرسم
+
+195
+00:17:06,020 --> 00:17:11,060
+ال acyclic structure ال O H اللي قبل الأخيرة اللي
+
+196
+00:17:11,060 --> 00:17:17,680
+هي بتكون على اليمين طبعا لما نعمله بشكل حلقي بتكون
+
+197
+00:17:17,680 --> 00:17:22,280
+مرسومة بشكل معين ال glucose السكر اللي عندى
+
+198
+00:17:22,280 --> 00:17:29,460
+جولوكوز بيرانوز نسكر على حلقة سداسية واضح الفكرة؟
+
+199
+00:17:30,180 --> 00:17:35,240
+فكل هذه المفردات الحقيقة بتلزمنا الان لو اجينا
+
+200
+00:17:35,240 --> 00:17:42,600
+بدنا نحكي عن تفاعلات ال sugars الان في المحصلة
+
+201
+00:17:42,600 --> 00:17:49,840
+السكر ايش هو تعريفه البسيط polyhydroxy
+
+202
+00:17:49,840 --> 00:17:54,880
+aldehyde او كيتولhydroxy يعني الكهول الديهايد او
+
+203
+00:17:54,880 --> 00:17:59,040
+كيتون معروف بناء على ذلك لما انا بدي اخد تفاعلات
+
+204
+00:17:59,040 --> 00:18:04,540
+ال sugars معنى ذلك هي تفاعلات الكحولات وتفاعلات
+
+205
+00:18:04,540 --> 00:18:10,800
+الكيتونات يا بدي افعله على الكحول يا على ال C
+
+206
+00:18:10,800 --> 00:18:15,900
+double bond O تبع ال الديهايد او الكيتون خلينا
+
+207
+00:18:15,900 --> 00:18:22,180
+ناخد مثال لو اخدنا مثلا السكر المسكراللي قلنا عنه
+
+208
+00:18:22,180 --> 00:18:27,000
+بيتا دي جلوكو بيرانوز وين رسمينه على هيئة الكرسي
+
+209
+00:18:27,000 --> 00:18:33,300
+هل هذا لما سكر لما صار بيرانوز ضال فيه الديهايد؟
+
+210
+00:18:33,780 --> 00:18:38,000
+ولا اتحولت ل New Cairo Center اتحولت ل New Cairo
+
+211
+00:18:38,000 --> 00:18:43,880
+Center اذا انا اول ما بدي اقرأ اسم Byranose او
+
+212
+00:18:43,880 --> 00:18:48,160
+اقرأ اسم Furanose لو بدي اخده لوحده بدون الاتزان
+
+213
+00:18:48,160 --> 00:18:52,380
+مافيش فيه Aldehyde لكن لو بدي اخده ضمن ان هو في
+
+214
+00:18:52,380 --> 00:18:56,620
+اتزان مع الفاتح الفاتح فيه Aldehyde واضح؟ خلينا
+
+215
+00:18:56,620 --> 00:19:00,380
+ناخد ال glucobyranose لوحده مجموعة ال aldehyde
+
+216
+00:19:00,380 --> 00:19:04,090
+اللي كانت فيه سارةأو أتش يعني هنا في أو أتش تنتين
+
+217
+00:19:04,090 --> 00:19:09,490
+تلاتة أربعة خمسة يعني هذا بدل ما يكون كحول هو
+
+218
+00:19:09,490 --> 00:19:15,650
+عبارة عن خمس كحولات مش في خمس أو أتش كل أو أتش
+
+219
+00:19:15,650 --> 00:19:21,810
+عبارة عن كحول الآن لو إجيت قلتلكوا بدي أفاعل كحول
+
+220
+00:19:21,810 --> 00:19:29,390
+مع unhydrate شو بيعطيني من الكيميا العادية كحول
+
+221
+00:19:29,390 --> 00:19:30,730
+زاد unhydrate
+
+222
+00:19:33,300 --> 00:19:37,060
+يعني نجيبلكوا سؤال أكمل الفرق ال reaction of
+
+223
+00:19:37,060 --> 00:19:43,280
+alcohol with anhydrides produces كلمة واحدة أستر
+
+224
+00:19:43,280 --> 00:19:50,340
+أستر الناس اللي بيدرسوا بنتبهوا كلمة سهلة جدا لما
+
+225
+00:19:50,340 --> 00:19:54,580
+أخدنا تفاعل الكحول مع ال acids بيعطينا أستر مع ال
+
+226
+00:19:54,580 --> 00:19:59,690
+acid chloride بيعطينا أستر مع ال anhydrideبيعطينا
+
+227
+00:19:59,690 --> 00:20:03,310
+Easter، مظبوط ولا لأ؟ طب لو بدنا نفعل الكحول مع ال
+
+228
+00:20:03,310 --> 00:20:08,510
+Easter، شو بيعطينا؟
+
+229
+00:20:08,510 --> 00:20:15,450
+كحول
+
+230
+00:20:15,450 --> 00:20:20,330
+مع Easter كحول
+
+231
+00:20:20,330 --> 00:20:30,950
+مع Easter إيش رأيكوا؟ Easterطبعا ي start تاني من
+
+232
+00:20:30,950 --> 00:20:34,710
+سير الإنسان بالعملية trans esterification لأن
+
+233
+00:20:34,710 --> 00:20:41,750
+متابعتك اضعيفة شوية في الموضوع اللي أخدناه سابقا و
+
+234
+00:20:41,750 --> 00:20:47,210
+اللي احنا محتاجينه مضطر ان اعمل شوية ايش شوية
+
+235
+00:20:47,210 --> 00:20:48,250
+مراجعة معكم
+
+236
+00:20:50,980 --> 00:20:59,460
+نعمل شوية المراجعة هى نحط كحول ميثانول كويس و
+
+237
+00:20:59,460 --> 00:21:01,320
+نعمله بأى لون الميثانول
+
+238
+00:21:04,970 --> 00:21:11,590
+CH3OH زائد فعلوه مع الاسد ايه صيغة الاسد اي اسد
+
+239
+00:21:11,590 --> 00:21:17,070
+ناخد ال بنزويك اسد ال بنزويك اسد فنل C double bond
+
+240
+00:21:17,070 --> 00:21:23,330
+O OH فعلوه مع ال بنزويل كلورايد الاسد كلورايد فنل
+
+241
+00:21:23,330 --> 00:21:31,340
+C double bond O Cl فعلوه معالبنزويت كان هيدرايد
+
+242
+00:21:31,340 --> 00:21:38,900
+فانل C double bond O O C double bond O فانل فعلوه
+
+243
+00:21:38,900 --> 00:21:46,680
+كمان مع الاثل بنزويت فانل C double bond O O اثلهي
+
+244
+00:21:46,680 --> 00:21:50,860
+الكحول بتفعل مع الحمض أو مع ال acid chloride أو مع
+
+245
+00:21:50,860 --> 00:21:55,600
+ال acid anhydride أو حتى مع ال E star الألم بده
+
+246
+00:21:55,600 --> 00:22:01,340
+يعطيني في كل الأحوال هو تفاعل واحد إبدال هذي بده
+
+247
+00:22:01,340 --> 00:22:09,200
+تخرج ييجي بدالها مثل هذي لين يفعل اللي بده يهاجم و
+
+248
+00:22:09,200 --> 00:22:16,980
+هذي تخرج هذي بده تخرج هذي بده تخرجو بناء على ذلك
+
+249
+00:22:16,980 --> 00:22:23,660
+الناتج من كل هدولة هيكون نفس ال Easter اللي هو
+
+250
+00:22:23,660 --> 00:22:30,220
+Phenyl C double bond O O Methyl بدل المجموعة
+
+251
+00:22:30,220 --> 00:22:34,440
+المغادرة هذه الآن بعد ذلك أنه هنا بطلع H مع ال OH
+
+252
+00:22:34,440 --> 00:22:39,340
+زائد ميه زائد HCl زائد Benzoic acid زائد Ethanol
+
+253
+00:22:39,340 --> 00:22:45,200
+مش مشكلةفتفاعل الكحول مع أي واحد من الأحماض
+
+254
+00:22:45,200 --> 00:22:50,040
+ومشتقاتها بيعطيني إيه؟ Easter كحول مع أسد، كحول مع
+
+255
+00:22:50,040 --> 00:22:53,600
+أسد كلورايت، كحول مع أنهايدرايت، كحول مع Easter،
+
+256
+00:22:53,600 --> 00:22:59,050
+يمكن أنا تقوله يا الله Easter أعطىEaster تاني اه
+
+257
+00:22:59,050 --> 00:23:04,630
+بس هذا ال Easter كان فنل C double bond O او اثل
+
+258
+00:23:04,630 --> 00:23:11,370
+صار فنل C double bond O او مثل اذا بدلت ال Easter
+
+259
+00:23:11,370 --> 00:23:17,010
+ولا لأ عشان هيك بنسميه ال Transesterification ايش
+
+260
+00:23:17,010 --> 00:23:22,610
+يعني ال Trans تحويل بتعرفوا Trans الكهربا كيف
+
+261
+00:23:22,610 --> 00:23:27,910
+بيحول بتعرفوا معناه Transformationبتعرفوا كلمة
+
+262
+00:23:27,910 --> 00:23:33,390
+Transport انه بننجل البني .. اه ف Trans لما
+
+263
+00:23:33,390 --> 00:23:37,550
+بتيجيكوا في أول الكلام شو معناها؟ تحويل، الآن كان
+
+264
+00:23:37,550 --> 00:23:42,210
+ال Easter، C double bond O، O-ethyl خلت ال Easter،
+
+265
+00:23:42,210 --> 00:23:47,930
+C double bond O، O-methyl فالكحول مع Easter بيبدل،
+
+266
+00:23:47,930 --> 00:23:52,270
+بيعمل Transesterification بدل ما كان O-ethyl صار O
+
+267
+00:23:52,270 --> 00:23:55,250
+-methyl هذه العملية شو بنسميها اللي هنا؟
+
+268
+00:24:02,320 --> 00:24:05,640
+transesterification واضح الفكرة؟ إذا مابدوش
+
+269
+00:24:05,640 --> 00:24:10,000
+يتغلبوني لما أقولكوا الكحول مع ال acid chloride و
+
+270
+00:24:10,000 --> 00:24:14,040
+لا مع ال anhydride، شو بده يعطيني؟ شو بده يعطي
+
+271
+00:24:14,040 --> 00:24:19,880
+الكحول مع ال anhydride؟ إيستر واضح؟ و مع ال
+
+272
+00:24:19,880 --> 00:24:25,230
+chloride إيستر؟ مع كلهم إيسترو .. الآن إذا الكلام
+
+273
+00:24:25,230 --> 00:24:31,790
+هذا كله صار واضح عندكم بدي أجي أرجع للسكر السكر
+
+274
+00:24:31,790 --> 00:24:40,010
+اللي مسكر عبارة عن كحول ال sugar عبارة عن كحول هذا
+
+275
+00:24:40,010 --> 00:24:45,230
+الكحول لو فعلته مع ال unhydrate شو هيعطيلي Easter
+
+276
+00:24:45,230 --> 00:24:54,480
+كل OH بده تصيرهذه الـ O H تهاجم هنا O CH3 أعمل
+
+277
+00:24:54,480 --> 00:25:00,260
+واحدة منهم واضحة O CH3 الآن الـ C double bond O
+
+278
+00:25:00,260 --> 00:25:05,680
+CH3 شو أخدنا اسمها الـ Acetyl group فالخمسة O H
+
+279
+00:25:05,680 --> 00:25:10,140
+بيصيروا كلهم O Acetyl طبعا تطلعوا معي هذا Easter
+
+280
+00:25:10,140 --> 00:25:19,280
+ولا لأ R C double bond O OR Easterفالسكر مع
+
+281
+00:25:19,280 --> 00:25:24,100
+الانهيدريد بيعطيني Easter طيب لو جبنالكوا السؤال
+
+282
+00:25:24,100 --> 00:25:26,940
+قولنا لكوا طب لو فعلنا ال sugar مع ال acid
+
+283
+00:25:26,940 --> 00:25:31,060
+chloride برضه Easter برضه Easter المهم انه في ما
+
+284
+00:25:31,060 --> 00:25:37,820
+.. طب لو فعلنا مع ال .. مع Easter برضه Easter تاني
+
+285
+00:25:38,910 --> 00:25:42,570
+نفس المثال اللي هناك هذا الكلام إذا ما بتتدربوش
+
+286
+00:25:42,570 --> 00:25:47,430
+عليه ما بتتقنوه الخمسة OHS كلهم اللي موجودين
+
+287
+00:25:47,430 --> 00:25:52,790
+بيصيروا Easter اتنين تلاتة اربعة خمسة فتفاعل ال
+
+288
+00:25:52,790 --> 00:25:58,070
+sugar مع ال acid unhydrated بيعطيني Easter خلصنا
+
+289
+00:25:58,070 --> 00:26:04,170
+من هذه النقطة؟ كويس لاحظوا كده بتفيدني الكيميا
+
+290
+00:26:04,170 --> 00:26:10,900
+العاديةوهي مقدمة ايش؟ ال biochemistry يعني مش ممكن
+
+291
+00:26:10,900 --> 00:26:14,100
+حد يجي يدرس biochemistry و نشرحله هذا التفاعل هو
+
+292
+00:26:14,100 --> 00:26:17,500
+مش عارف الكحول و ال anhydride و الaster و كيف
+
+293
+00:26:17,500 --> 00:26:21,500
+بتفاعلوا مع بعض و مع البعض فكل تفاعل بمر معنها
+
+294
+00:26:21,500 --> 00:26:27,930
+عشان تفهمه بسهولة لازم يكون المخ يرجع وين؟للـ
+
+295
+00:26:27,930 --> 00:26:31,630
+Organic Chemistry العادية اللي استعلمته فيها هو
+
+296
+00:26:31,630 --> 00:26:35,910
+اللي بيرجع يمر علينا هنا يعني لو مثلا أخدنا هذا
+
+297
+00:26:35,910 --> 00:26:49,170
+التفاعل R O H زائد CH3I هاي التفاعل العادي Alkyl
+
+298
+00:26:49,170 --> 00:26:49,790
+Halide
+
+299
+00:26:52,600 --> 00:26:55,880
+النيوكليوفايل ايش بيعمل النيوكليوفايل بالالكي
+
+300
+00:26:55,880 --> 00:27:04,160
+الهيلايد؟ هذا الشبطر ايش؟ ستة بيهاجر، بيحل محل و
+
+301
+00:27:04,160 --> 00:27:08,460
+النيوترال نيوكليوفايل اللي بيفقد؟ H إذا هنا إيش
+
+302
+00:27:08,460 --> 00:27:16,980
+بده يصير عندكم؟ R O CH3 إذا كحول مع الالكي
+
+303
+00:27:16,980 --> 00:27:19,500
+الهيلايد، شو بيعطيني؟ إيثر
+
+304
+00:27:22,220 --> 00:27:30,660
+ROR Ether الآن ال sugar عبارة عن كحول ولا خمس
+
+305
+00:27:30,660 --> 00:27:34,940
+كحولات في بعض؟ خمس كحولات فعلوه مع المثل Iodide
+
+306
+00:27:35,670 --> 00:27:41,650
+هيعطيني كم إيثر؟ خمس إيثرات مثل او كاربون مثل او
+
+307
+00:27:41,650 --> 00:27:45,070
+كاربون مثل او كاربون مثل او كاربون مثل او كاربون
+
+308
+00:27:45,070 --> 00:27:49,570
+واضح الفكرة؟ هو نفس هذا التفاعل البسيط أن الكحول
+
+309
+00:27:49,570 --> 00:27:55,450
+بيحل محل اليود ولذلك ملخص هدول التنتين أن الكحول
+
+310
+00:27:55,450 --> 00:28:00,950
+مع الانهيدريد بيعطيني إيثر للشجر والكحول مع ال مثل
+
+311
+00:28:00,950 --> 00:28:07,890
+أيودايد بيعطيني إيثرلل sugar و طالما انه موجود من
+
+312
+00:28:07,890 --> 00:28:12,230
+الكحول خمس مجموعات اذا كم Easter و كم Ether هيتكون
+
+313
+00:28:12,230 --> 00:28:20,020
+عندى اذا بعد ما أخدنا تفاعلالشجر بصفته alcohol مع
+
+314
+00:28:20,020 --> 00:28:23,620
+ال unhydrate قولنا بيعطي ether مع ال alkyl halide
+
+315
+00:28:23,620 --> 00:28:27,800
+زي ال methyl iodide قولنا بيعطي ether بدنا ناخد
+
+316
+00:28:27,800 --> 00:28:33,380
+تفاعل تاني للشجر أيضا مر علينا هذا التفاعل لو
+
+317
+00:28:33,380 --> 00:28:38,500
+أجينا بدنا نعمل reduction للشجر هنحتاج جملة من
+
+318
+00:28:38,500 --> 00:28:43,420
+الكيميا القديمة نقول reduction of aldehyde
+
+319
+00:28:43,420 --> 00:28:49,910
+produces ايشprimary الكوكبوس تمام هتقول هو ال
+
+320
+00:28:49,910 --> 00:28:55,390
+sugar ال dehyde احنا بنقول ال sugar موجود أساسا
+
+321
+00:28:55,390 --> 00:29:03,790
+بشكل acyclic او بشكل cyclic و بينهم اتزان ان هو
+
+322
+00:29:03,790 --> 00:29:08,390
+اللي موجود بنسبة أكبر ال cyclic ولا ال acyclic ال
+
+323
+00:29:08,390 --> 00:29:13,310
+cyclic هذا موجود بنسبة قليلة جدا قولنا بنسبة ايش
+
+324
+00:29:13,310 --> 00:29:19,430
+تلاتة بال ألفنسبة قليلة جدا المهم هذا الشكل في
+
+325
+00:29:19,430 --> 00:29:23,390
+الديهيد لو جيت اعمله reduction بالهيدروجين في وجود
+
+326
+00:29:23,390 --> 00:29:28,130
+كتاليست ال الديهيد شو بده يصير ال primary alcohol
+
+327
+00:29:28,130 --> 00:29:34,270
+طبعا الان بيصير السؤال reduction of sugars
+
+328
+00:29:34,270 --> 00:29:38,650
+produces primary alcohol طبعا طالما كل هدولة أساسا
+
+329
+00:29:38,650 --> 00:29:44,940
+OH كان في الديهيد واحدة وصارت OHصار Polyhydroxy
+
+330
+00:29:44,940 --> 00:29:49,740
+Alcohol اللي هو مار عليكم الـ Sorbitol اللي فيه ست
+
+331
+00:29:49,740 --> 00:29:54,060
+مجموعات OH بطل في ال الديهيد هو كان خمسة OH و
+
+332
+00:29:54,060 --> 00:29:55,840
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+333
+00:29:55,840 --> 00:29:56,120
+الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و
+
+334
+00:29:56,120 --> 00:29:57,620
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+335
+00:29:57,620 --> 00:29:57,880
+الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و
+
+336
+00:29:57,880 --> 00:29:59,140
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+337
+00:29:59,140 --> 00:30:01,540
+الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و
+
+338
+00:30:01,540 --> 00:30:05,260
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+339
+00:30:05,260 --> 00:30:11,460
+الديهيد و واحدة ال الديهيد و واحدة ال ال
+
+340
+00:30:13,000 --> 00:30:19,980
+أمنا و اتحول و أصار الكهول طب و اللي ضايل هنا إيش
+
+341
+00:30:19,980 --> 00:30:20,680
+رأيكوا فيه؟
+
+342
+00:30:24,980 --> 00:30:29,960
+كل ما هذا جزء منه صار alcohol بعوضه جزء من هذا
+
+343
+00:30:29,960 --> 00:30:34,760
+بيعمل ring opening في نهاية التفاعل ايش بتتوقعوا
+
+344
+00:30:34,760 --> 00:30:40,960
+نشوف ان هذا كله هينتهي يعني كل ما هذا بتحول بيروح
+
+345
+00:30:40,960 --> 00:30:45,780
+المسكر بيفتح كل ما هذا بتحول المسكر بيفتح هذه
+
+346
+00:30:45,780 --> 00:30:50,200
+القاعدة في الاتزان من اذكرنا ايش اسمها مرت عليكم
+
+347
+00:30:52,610 --> 00:30:56,330
+إعادة الإتزان، إنه الإتزان يعود إلى وضعه الطبيعي،
+
+348
+00:30:56,330 --> 00:31:01,290
+يعني دول الاتنين في اتزان، سحبنا هذا، فعلناه،
+
+349
+00:31:01,290 --> 00:31:04,710
+بيرود هذا يعمل اتزان من أول لجديد، سحبنا هذا،
+
+350
+00:31:04,710 --> 00:31:11,850
+بيرود هذا يفتح، لتشكله principalواضح؟ وبناء على
+
+351
+00:31:11,850 --> 00:31:17,210
+ذلك لو احنا جيبنالكوا سؤال في الامتحان قولنا هذا و
+
+352
+00:31:17,210 --> 00:31:22,150
+هذا في حالة اتزان اكملوا المعادلة هتكملونهان طيب
+
+353
+00:31:22,150 --> 00:31:26,930
+يا ترى لو اجينا سألناكوا ماحطيناش هذا من الأساس
+
+354
+00:31:26,930 --> 00:31:32,710
+كتبنالكوا بس هذا و reduction ايش هتعملونه؟ هتقولوا
+
+355
+00:31:32,710 --> 00:31:39,630
+مفهوم ضمنهإن هذا متزل مع الفاتح وبناء على ذلك
+
+356
+00:31:39,630 --> 00:31:43,710
+سيعمل reduction ويعطي هذا يعني لو رسمت أنا بس هذا
+
+357
+00:31:43,710 --> 00:31:49,070
+وقلت لكم H2و Catalyst في نهاية هذه الجوابلكن للفهم
+
+358
+00:31:49,070 --> 00:31:53,250
+كيف هذا الكلام بيصير بيقول ال .. ال cyclic صار إيه
+
+359
+00:31:53,250 --> 00:31:57,350
+ال cyclic؟ وصار إله reduction وكل ما هذا صار إله
+
+360
+00:31:57,350 --> 00:32:02,450
+reduction كل ما ال cyclic من أول و جديد بيفتح إلى
+
+361
+00:32:02,450 --> 00:32:08,840
+أن يتحول كل ال cyclic اللي موجود هنا إلىالى الكحول
+
+362
+00:32:08,840 --> 00:32:13,320
+اللى هو sorbitol واضح؟ لاحظوا معنا احنا الان
+
+363
+00:32:13,320 --> 00:32:20,360
+استفدنا من ايش؟ من مجموعة ال aldehyde الناس
+
+364
+00:32:20,360 --> 00:32:24,280
+اللى متذكرين كويس معنا لما شرحنا ال aldehyde قولنا
+
+365
+00:32:24,280 --> 00:32:28,180
+ال aldehyde واقف على نص السلم ايش يعني ال aldehyde
+
+366
+00:32:28,180 --> 00:32:34,900
+واقف على نص السلم او في نص الطريقالديهايد ممكن
+
+367
+00:32:34,900 --> 00:32:42,320
+تنزل لالكهول زي ما عملت هنا بال reduction و بنفس
+
+368
+00:32:42,320 --> 00:32:52,120
+الوقت ممكن تطلع فوق ل acid بال oxidation واضح؟
+
+369
+00:32:52,120 --> 00:32:58,320
+ماشي الترتيب اللي عندى ال alcohol الديهايد
+
+370
+00:32:59,060 --> 00:33:06,000
+acid أكسدة الكحول تعطي الديهايد أكسدة الديهايد
+
+371
+00:33:06,000 --> 00:33:11,020
+تعطي acid اختزال الكحول بيصير alcohol اختزال
+
+372
+00:33:11,020 --> 00:33:15,520
+الديهايد بيصير alcohol أكسدة الديهايد بيصير acid
+
+373
+00:33:15,520 --> 00:33:19,820
+الآن احنا التفاعل اللي موجود عندنا اختزال الديهايد
+
+374
+00:33:19,820 --> 00:33:25,990
+رجع لإيش؟ لالكحول طب لو عملنا أكسدة للديهايدهيصير
+
+375
+00:33:25,990 --> 00:33:30,990
+acid واضح الفكرة المشكلة في الموضوع كالقاتل انه
+
+376
+00:33:30,990 --> 00:33:35,470
+احنا قولنا اكسدة ال الديهيد بال oxidation بيصير
+
+377
+00:33:35,470 --> 00:33:40,150
+acid و اكسدة الكحول بعمل مؤكسد قوي برضه بيصير ايش
+
+378
+00:33:40,150 --> 00:33:44,410
+acid متذكرين لما أخدنا oxidation و في primary
+
+379
+00:33:44,410 --> 00:33:50,330
+alcohol حسب نوع المؤكسد تمام طيب هذا ال sugar ايش
+
+380
+00:33:50,330 --> 00:33:57,020
+موجود فيه في الديهيدو في كحولات بالذات ال primary
+
+381
+00:33:57,020 --> 00:34:01,540
+alcohol بناء على ذلك هتلاحظوا لما نيجي ندرس ال
+
+382
+00:34:01,540 --> 00:34:05,900
+acid ده انه هيمروا معناه حالتين ممكن عامل مؤكسد
+
+383
+00:34:05,900 --> 00:34:10,560
+نستعمله فقط acid ال aldehyde ل acid يعني يصير عندى
+
+384
+00:34:10,560 --> 00:34:15,240
+على الطرف هذا ايش acid عامل مؤكسد تاني اقوى منه ب
+
+385
+00:34:15,240 --> 00:34:19,400
+acid ال aldehyde و ب acid ال primary alcohol بيصير
+
+386
+00:34:19,400 --> 00:34:23,780
+عندى ايش dye acid انشوف هذا الكلام
+
+387
+00:34:26,870 --> 00:34:31,270
+لو أخدنا Sugar مع عامل مؤكسد خلّينا نقول ضعيف
+
+388
+00:34:31,270 --> 00:34:36,330
+لبرومين ميّه أو فضّه مع انحاس خلّينا نركز برومين
+
+389
+00:34:36,330 --> 00:34:41,670
+ووتر ب أكسد ال الديهايد بدل ما هو CHO بصير سيضه
+
+390
+00:34:41,670 --> 00:34:46,490
+بالموند OOH صار أسد، إذا لبرومين ووتر كام أكسدة
+
+391
+00:34:46,490 --> 00:34:51,010
+عمل عندى؟ أكسدة واحدة، بس أكسد ال الديهايد خلّاه
+
+392
+00:34:51,010 --> 00:34:55,250
+أيش أسد؟ الآن وقت الديجلوكوز بنقول عنه بصير
+
+393
+00:34:55,250 --> 00:35:00,030
+gluconic acidفال gluconic acid يحتوي على كام
+
+394
+00:35:00,030 --> 00:35:05,630
+مجموعة حمضية؟ واحدة عشانك لو انا اجيت سألتكم
+
+395
+00:35:05,630 --> 00:35:12,150
+gluconic acids contain one ولا two acidic groups؟
+
+396
+00:35:12,150 --> 00:35:20,130
+oneone الان نفس هذا المركب لو جبتله عامل مؤكسد قوي
+
+397
+00:35:20,130 --> 00:35:25,890
+أقوى من هذا بيروح ب أكسد الألديهيد والألكوهول وجدت
+
+398
+00:35:25,890 --> 00:35:32,790
+بده يعطيني كام أسد اتنين بيصير اتنين هذه الأكسدات
+
+399
+00:35:32,790 --> 00:35:36,730
+اللي بتصير الان ايش العامل المؤكسد الأقوى ال
+
+400
+00:35:36,730 --> 00:35:41,170
+nitric acid الألديهيد بيصير أسد وال primary
+
+401
+00:35:41,170 --> 00:35:47,740
+alcohol بتصير أسدصار عنده ايش؟ داي أسد وجدتها الدي
+
+402
+00:35:47,740 --> 00:35:53,080
+جلوكوز بيصير دي جلوكارك أسد لاحظوا الأول ايش كان
+
+403
+00:35:53,080 --> 00:35:58,580
+اسمه؟ جلوكونك جلوكونك يعني في one acidic group
+
+404
+00:35:58,580 --> 00:36:05,540
+جلوكارك يعني في two acidic groups أكسدنا في جزء ال
+
+405
+00:36:05,540 --> 00:36:10,950
+الديهايد وأكسدنا في جزء الكحولفبناء على العامل
+
+406
+00:36:10,950 --> 00:36:15,990
+المؤكسد ممكن نعمل أكسدة لجزء واحد بيصير عنده
+
+407
+00:36:15,990 --> 00:36:20,010
+glucanic acid اللي بأكسد جزء واحد هو ال bromine
+
+408
+00:36:20,010 --> 00:36:26,410
+water إذا استعملت نيترك أسد بأكسد ال aldehyde و
+
+409
+00:36:26,410 --> 00:36:31,550
+بأكسد ال primary alcohol بيصير عنده داي أسد
+
+410
+00:36:35,990 --> 00:36:41,490
+لأ في التجربة هي اللي بتأكسده واضح؟ هدول هو نظريا
+
+411
+00:36:41,490 --> 00:36:45,370
+لو بدى تأكسد حصير كيتون لأنه secondary alcohol بس
+
+412
+00:36:45,370 --> 00:36:50,550
+بالتجربة هدول اللي بتأكسده أخر
+
+413
+00:36:50,550 --> 00:36:59,330
+تفاعل ممكن امر علينا لو فعلناهذا الكحول تحديدا مع
+
+414
+00:36:59,330 --> 00:37:05,190
+.. أو هذا ال sugar عفوا Beta D-Glucobiranose مع
+
+415
+00:37:05,190 --> 00:37:10,210
+الميثانولاحنا فعلنا مع ال acid anhydride أعطانا
+
+416
+00:37:10,210 --> 00:37:14,470
+ester فعلنا مع ال acid halide أعطانا ether فعلنا
+
+417
+00:37:14,470 --> 00:37:17,830
+مع ال bromine أعطانا acid واحد فعلنا مع ال nitric
+
+418
+00:37:17,830 --> 00:37:22,370
+acid أعطانا two acids لو فعلنا مع الكحول في وجود
+
+419
+00:37:22,370 --> 00:37:27,830
+الميه شو بيعمل؟ بيشيل واحدة من ال OHS بنتقيها
+
+420
+00:37:27,830 --> 00:37:31,610
+انتقاءطبعا في ميكانيزم تفسر على الكلام لكن مش
+
+421
+00:37:31,610 --> 00:37:35,390
+موضوعنا و بيحل محلها ال o-methyl يعني بيشيل ال OH
+
+422
+00:37:35,390 --> 00:37:40,090
+و بيحط مكانها ايش o-methyl الان اي OH اللي بدو
+
+423
+00:37:40,090 --> 00:37:43,770
+يشيلها ال OH الجديدة اللي ع ال anomeric carbon
+
+424
+00:37:43,770 --> 00:37:47,110
+متذاكرين هذه اللي كانت مش chiral سمنها anomeric
+
+425
+00:37:47,110 --> 00:37:51,530
+carbon فالتفاعل مع الكحول زي ال methanol بيشيل هذه
+
+426
+00:37:51,530 --> 00:37:57,970
+ال OH بيشيل هذه ال OH و بيحط بدالها ايش o-methyl
+
+427
+00:37:58,410 --> 00:38:01,650
+طبعا هل يا ترى بيحط ال O مثل على ال Alpha ولا على
+
+428
+00:38:01,650 --> 00:38:05,370
+ال Beta؟ هيعمل خليط .. هيعمل خليط من الاتنين، احنا
+
+429
+00:38:05,370 --> 00:38:09,170
+راسمين واحد منهم واضح بيحطوا على ال Alpha و ال
+
+430
+00:38:09,170 --> 00:38:13,410
+Beta لما تكون ال O مثل ال A4، هذا Beta، لو كانت
+
+431
+00:38:13,410 --> 00:38:19,070
+لتحت Alpha الآن هذه المركبات اللي بدل ما كانت ال
+
+432
+00:38:19,070 --> 00:38:25,110
+Oxygen على ال Anomeric Carbon OH صارت OR بنسميها
+
+433
+00:38:25,110 --> 00:38:31,310
+احنا ايش؟ Glycosidesفلو إجينا سألنا شو هم ال
+
+434
+00:38:31,310 --> 00:38:37,230
+glycosides؟ ال glycosides هم السكريات اللي قبدلت
+
+435
+00:38:37,230 --> 00:38:45,850
+فيهم ال OH صارت OR واضح؟بدل ما كانت او متصلة ب اتش
+
+436
+00:38:45,850 --> 00:38:52,390
+صارت او متصلة بار بنسميهم glycosides طبعا في أمثلة
+
+437
+00:38:52,390 --> 00:38:55,930
+هتمروا معاكم بعدين في أماكن تانية أنه يا تورا لو
+
+438
+00:38:55,930 --> 00:39:01,690
+حطينا هنا ال متصلة باربنصير نقول عنها
+
+439
+00:39:01,690 --> 00:39:06,150
+anoglycosides يعني غلايكو سايتس بس من خلال ذرة إيش
+
+440
+00:39:06,150 --> 00:39:11,130
+نيتروجين بس إذا قولنا كلمة غلايكو سايتس عادية معنى
+
+441
+00:39:11,130 --> 00:39:15,750
+ذلك أنا بدي سكر و مرسوم عليه على هذا الموقع تحديدا
+
+442
+00:39:15,750 --> 00:39:20,670
+OR لاحظوا أن التفاعل مع الميثانول ما بيغير هدول ال
+
+443
+00:39:20,670 --> 00:39:26,420
+OHSفقط بيغير ال OH اللي ع ال anomeric carbon
+
+444
+00:39:26,420 --> 00:39:31,220
+بيخليها ايش OR والمركبات اللي فيها OR ع ال
+
+445
+00:39:31,220 --> 00:39:36,080
+anomeric carbon بنقول عنها glycosides هذه الرابطة
+
+446
+00:39:36,080 --> 00:39:38,720
+اللي بين ال anomeric carbon و ال oxygen اللي هي
+
+447
+00:39:38,720 --> 00:39:43,760
+carbon O مثل او carbon OR بنسميها glycosidic bond
+
+448
+00:39:43,760 --> 00:39:49,740
+هذه الرابطة الجديدة اللي كانت متصلةمع ال OH صارت
+
+449
+00:39:49,740 --> 00:39:55,840
+متصلة مع ايش؟ مع ال OR شو بنسميها؟ Glycosidic bond
+
+450
+00:39:55,840 --> 00:40:03,080
+موجودة ويلها أهمية جزء كبير من أهمية هذه المنطقة
+
+451
+00:40:03,080 --> 00:40:07,660
+أنه لما بعدك السكريات بدهم يبدوا يعملوا dimers مع
+
+452
+00:40:07,660 --> 00:40:11,560
+بعض يتحدوا هنلاحظ فائدة هذه ال glycosidic bond
+
+453
+00:40:11,560 --> 00:40:15,000
+لأنه بربطوا من خلالها واضح؟ يربطوا مع بعض من
+
+454
+00:40:15,000 --> 00:40:22,700
+خلالهالو اجينا رسمنالكم مركب هذا sugar من
+
+455
+00:40:22,700 --> 00:40:27,900
+الجولوكوز هل هذا يا تورا فيه glycosidic bond ولا
+
+456
+00:40:27,900 --> 00:40:38,380
+لأ تطلع عليه هاي carbon اوCarbon اذا هذا المركب
+
+457
+00:40:38,380 --> 00:40:43,600
+اللى اسمه ساليسين من شجر الصفصاف لما كانوا بيغلو
+
+458
+00:40:43,600 --> 00:40:47,140
+شجر الصفصاف بيطلع هذا المركب كانوا ياخدوله الصداع
+
+459
+00:40:47,140 --> 00:40:52,440
+الناس الزمان فيه glycosidic bond لاحظوا اللى
+
+460
+00:40:52,440 --> 00:40:58,900
+بتتأمل فيه بشكل بشكل قوى هتلاحظ ان هذا بيشبه ايش
+
+461
+00:40:58,900 --> 00:41:02,040
+الاسميرين
+
+462
+00:41:03,920 --> 00:41:10,960
+تذكروا الاسبيرين كان بنزينة و COOH و CH2O و بعدين
+
+463
+00:41:10,960 --> 00:41:15,500
+أوهانة OH نخليها OCOC double bond Oacetyl يعني
+
+464
+00:41:15,500 --> 00:41:20,020
+وجود البنزينة و ال orthoposition هذا بشبه أي دوة؟
+
+465
+00:41:20,020 --> 00:41:25,580
+بشبه الاسبيرين هذا مثلا منتج طبيعي فيه glycosidic
+
+466
+00:41:25,580 --> 00:41:30,170
+bond ولا لأ؟ هيهالما تكون هذه الرابطة اللي هنا مش
+
+467
+00:41:30,170 --> 00:41:36,350
+OH OR بنقول هذا إيش المركب glycoside و ال bond إيش
+
+468
+00:41:36,350 --> 00:41:43,650
+بنوصفها؟ بنقول عنها glycosidic bond الآن زي ما
+
+469
+00:41:43,650 --> 00:41:48,330
+اتفقنا أن ال glycosides وين بيفيدوني كتير أنا؟لما
+
+470
+00:41:48,330 --> 00:41:53,550
+بدى ادمج سكارين مع بعض لما بدى ادمج سكارين مع بعض
+
+471
+00:41:53,550 --> 00:41:57,390
+هاجي على هذه ال oxygen و اصير اربط من خلالها الان
+
+472
+00:41:57,390 --> 00:42:01,410
+دمج سكارين مع بعض قصة طويلة اش السكارين و اش
+
+473
+00:42:01,410 --> 00:42:06,370
+السكارتونة اللى بده يطلع عندى هو ملتوز سكاروز سيلو
+
+474
+00:42:06,370 --> 00:42:11,490
+بيوز كذا كذا موضوع كبير بحاجة الى ان نفردله ان شاء
+
+475
+00:42:11,490 --> 00:42:17,580
+الله محاضرة كاملة بس لاحظوا مباشرةهتلاحظوا أنه أول
+
+476
+00:42:17,580 --> 00:42:22,580
+ما بدي أحكي عن سكارين دمجتهم هاي رابط هانا تطلعوا
+
+477
+00:42:22,580 --> 00:42:27,980
+عليها carbon او carbon ال glycosidic bond ولا لأ
+
+478
+00:42:27,980 --> 00:42:33,520
+عشانك احنا أخدنا ال glycosides لأنه في ال
+
+479
+00:42:33,520 --> 00:42:37,620
+disaccharides هتلاقوا عندي ال glycosidic bond طبعا
+
+480
+00:42:37,620 --> 00:42:41,760
+إيش السكارين اللي بيندمجوا و إيش السكر ثناء اللي
+
+481
+00:42:41,760 --> 00:42:46,920
+بيطلع هذا بيكون موضوعالمحاضرة القادمة ان شاء الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..4c342af0b63b9b65c1322fa5acc09dd6d0cbd7da
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3925, "start": 19.49, "end": 39.25, "text": "بسم الله الرحمن الرحيم المرة الماضية بدينا في موضوع ال carbohydrates بدينا في موضوع ال carbohydrates وقولنا انه امكوانين من carbon و ما .. و بعدين طبعا بدينا في ال sugars", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 1829, 8315, 8978, 3714, 2407, 11242, 45367, 2423, 36817, 47525, 1829, 8315, 8978, 3714, 2407, 11242, 45367, 2423, 36817, 4032, 39648, 8315, 16472, 3224, 1975, 2304, 4117, 2407, 7649, 9957, 9154, 5954, 4032, 19446, 4386, 4032, 39182, 9957, 23032, 3555, 3615, 995, 47525, 1829, 8315, 8978, 2423, 37551], "avg_logprob": -0.14636230375617743, "compression_ratio": 1.8243243243243243, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 19.49, "end": 19.83, "word": "بسم", "probability": 0.929931640625}, {"start": 19.83, "end": 19.97, "word": " الله", "probability": 0.9697265625}, {"start": 19.97, "end": 20.31, "word": " الرحمن", 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68.67, "word": " dihyde", "probability": 0.6520182291666666}, {"start": 68.67, "end": 69.47, "word": " و", "probability": 0.947265625}, {"start": 69.47, "end": 70.33, "word": " رسمنا", "probability": 0.97216796875}, {"start": 70.33, "end": 71.69, "word": " بطرق", "probability": 0.8839111328125}, {"start": 71.69, "end": 72.81, "word": " مختلفة", "probability": 0.9954833984375}, {"start": 72.81, "end": 74.75, "word": " شوفنا", "probability": 0.8487955729166666}, {"start": 74.75, "end": 75.15, "word": " كيف", "probability": 0.982666015625}, {"start": 75.15, "end": 76.91, "word": " المركبات", "probability": 0.9114990234375}, {"start": 76.91, "end": 77.31, "word": " هذه", "probability": 0.7509765625}, {"start": 77.31, "end": 78.17, "word": " ممكن", "probability": 0.9921875}, {"start": 78.17, "end": 78.75, "word": " تكون", "probability": 0.98974609375}], "temperature": 1.0}, {"id": 4, "seek": 10614, "start": 79.34, "end": 106.14, "text": "D أو L في المرحلة الأولى و لو قلنا لو عندنا one chiral center بيصير في عندنا مركبين بعد هيك قصة ال D و L بتستمر بزيادة ال chiral center و بيبدأ العدد يزيد فبناء على ذلك بناء على ذلك فبموضوع ال sugars", "tokens": [35, 34051, 441, 8978, 9673, 2288, 5016, 37977, 16247, 12610, 7578, 4032, 45164, 12174, 1211, 8315, 45164, 43242, 8315, 472, 23782, 304, 3056, 4724, 1829, 9381, 13546, 8978, 43242, 8315, 3714, 31747, 3555, 9957, 39182, 39896, 4117, 12174, 9381, 3660, 2423, 413, 4032, 441, 39894, 14851, 29973, 4724, 11622, 1829, 18513, 3660, 2423, 23782, 304, 3056, 4032, 4724, 1829, 44510, 10721, 18863, 3215, 3215, 7251, 11622, 25708, 6156, 3555, 1863, 16606, 15844, 29910, 23275, 44945, 16606, 15844, 29910, 23275, 6156, 3555, 2304, 2407, 11242, 45367, 2423, 37551], "avg_logprob": -0.24751421639865095, "compression_ratio": 1.6789473684210525, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 79.34, "end": 79.84, "word": "D", "probability": 0.477294921875}, {"start": 79.84, "end": 80.94, "word": " أو", "probability": 0.51220703125}, {"start": 80.94, "end": 81.9, "word": " L", "probability": 0.92578125}, {"start": 81.9, "end": 82.94, "word": " في", "probability": 0.254150390625}, {"start": 82.94, "end": 83.48, "word": " المرحلة", "probability": 0.9527587890625}, {"start": 83.48, "end": 83.78, "word": " الأولى", "probability": 0.7939453125}, {"start": 83.78, "end": 84.0, "word": " و", "probability": 0.372314453125}, {"start": 84.0, "end": 84.02, "word": " لو", "probability": 0.1995849609375}, {"start": 84.02, "end": 84.18, "word": " قلنا", "probability": 0.7354329427083334}, {"start": 84.18, "end": 84.34, "word": " لو", "probability": 0.5341796875}, {"start": 84.34, "end": 84.62, "word": " عندنا", "probability": 0.9228515625}, {"start": 84.62, "end": 84.78, "word": " one", "probability": 0.68798828125}, {"start": 84.78, "end": 85.3, "word": " chiral", "probability": 0.9208984375}, {"start": 85.3, "end": 85.72, "word": " center", "probability": 0.8076171875}, {"start": 85.72, "end": 86.18, "word": " بيصير", "probability": 0.77471923828125}, {"start": 86.18, "end": 86.28, "word": " في", "probability": 0.626953125}, {"start": 86.28, "end": 86.72, "word": " عندنا", "probability": 0.89697265625}, {"start": 86.72, "end": 87.84, "word": " مركبين", "probability": 0.9237060546875}, {"start": 87.84, "end": 88.84, "word": " بعد", "probability": 0.69775390625}, {"start": 88.84, "end": 89.26, "word": " هيك", "probability": 0.52447509765625}, {"start": 89.26, "end": 89.84, "word": " قصة", "probability": 0.9856770833333334}, {"start": 89.84, "end": 89.98, "word": " ال", "probability": 0.6884765625}, {"start": 89.98, "end": 90.08, "word": " D", "probability": 0.791015625}, {"start": 90.08, "end": 90.24, "word": " و", "probability": 0.60986328125}, {"start": 90.24, "end": 90.54, "word": " L", "probability": 0.53076171875}, {"start": 90.54, "end": 91.32, "word": " بتستمر", "probability": 0.88671875}, {"start": 91.32, "end": 92.0, "word": " بزيادة", "probability": 0.98251953125}, {"start": 92.0, "end": 92.18, "word": " ال", "probability": 0.703125}, {"start": 92.18, "end": 92.6, "word": " chiral", "probability": 0.87646484375}, {"start": 92.6, "end": 92.92, "word": " center", "probability": 0.8828125}, {"start": 92.92, "end": 93.08, "word": " و", "probability": 0.7763671875}, {"start": 93.08, "end": 93.38, "word": " بيبدأ", "probability": 0.75927734375}, {"start": 93.38, "end": 93.94, "word": " العدد", "probability": 0.9720052083333334}, {"start": 93.94, "end": 94.58, "word": " يزيد", "probability": 0.9884440104166666}, {"start": 94.58, "end": 95.44, "word": " فبناء", "probability": 0.9019775390625}, {"start": 95.44, "end": 95.74, "word": " على", "probability": 0.8994140625}, {"start": 95.74, "end": 96.34, "word": " ذلك", "probability": 0.991455078125}, {"start": 96.34, "end": 96.9, "word": " بناء", "probability": 0.680419921875}, {"start": 96.9, "end": 97.18, "word": " على", "probability": 0.95556640625}, {"start": 97.18, "end": 99.66, "word": " ذلك", "probability": 0.99267578125}, {"start": 99.66, "end": 103.04, "word": " فبموضوع", "probability": 0.913330078125}, {"start": 103.04, "end": 103.76, "word": " ال", "probability": 0.8583984375}, {"start": 103.76, "end": 106.14, "word": " sugars", "probability": 0.33056640625}], "temperature": 1.0}, {"id": 5, "seek": 13558, "start": 107.42, "end": 135.58, "text": "قلنا أساسي جدا نتطلع على ال chiral centers و نتذكر كل الكلام اللي حكيناه في chiral centers في chapter 4 إذا عندنا one chiral center بنتوقع مركبين two chiral centers بنتوقع أربعة و هكذا بدأنا بالتدريج و أخر شيء انتهينا عنده احنا لما كان في عندنا ست ذرات كربون طبعا لما بيكون عندى ست ذرات كربون", "tokens": [4587, 1211, 8315, 5551, 3794, 32277, 1829, 10874, 28259, 8717, 2655, 9566, 1211, 3615, 15844, 2423, 23782, 304, 10898, 4032, 8717, 2655, 8848, 37983, 28242, 2423, 28820, 10943, 13672, 1829, 11331, 4117, 1829, 8315, 3224, 8978, 23782, 304, 10898, 8978, 7187, 1017, 11933, 15730, 43242, 8315, 472, 23782, 304, 3056, 44945, 2655, 30543, 3615, 3714, 31747, 3555, 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0.93994140625}, {"start": 120.48, "end": 121.1, "word": " بنتوقع", "probability": 0.9046630859375}, {"start": 121.1, "end": 121.72, "word": " أربعة", "probability": 0.7587890625}, {"start": 121.72, "end": 122.02, "word": " و", "probability": 0.8173828125}, {"start": 122.02, "end": 122.78, "word": " هكذا", "probability": 0.9612630208333334}, {"start": 122.78, "end": 123.74, "word": " بدأنا", "probability": 0.7996419270833334}, {"start": 123.74, "end": 124.48, "word": " بالتدريج", "probability": 0.9890625}, {"start": 124.48, "end": 124.68, "word": " و", "probability": 0.93359375}, {"start": 124.68, "end": 125.04, "word": " أخر", "probability": 0.74365234375}, {"start": 125.04, "end": 125.36, "word": " شيء", "probability": 0.552734375}, {"start": 125.36, "end": 125.9, "word": " انتهينا", "probability": 0.8880615234375}, {"start": 125.9, "end": 126.24, "word": " عنده", "probability": 0.98388671875}, {"start": 126.24, "end": 126.64, "word": " احنا", "probability": 0.8416341145833334}, {"start": 126.64, "end": 127.64, "word": " لما", "probability": 0.95751953125}, {"start": 127.64, "end": 127.88, "word": " كان", "probability": 0.9912109375}, {"start": 127.88, "end": 128.06, "word": " في", "probability": 0.91748046875}, {"start": 128.06, "end": 129.06, "word": " عندنا", "probability": 0.9892578125}, {"start": 129.06, "end": 129.98, "word": " ست", "probability": 0.75048828125}, {"start": 129.98, "end": 130.46, "word": " ذرات", "probability": 0.8924153645833334}, {"start": 130.46, "end": 131.04, "word": " كربون", "probability": 0.8076171875}, {"start": 131.04, "end": 132.22, "word": " طبعا", "probability": 0.98486328125}, {"start": 132.22, "end": 132.6, "word": " لما", "probability": 0.93896484375}, {"start": 132.6, "end": 132.92, "word": " بيكون", "probability": 0.751953125}, {"start": 132.92, "end": 133.56, "word": " عندى", "probability": 0.793212890625}, {"start": 133.56, "end": 133.98, "word": " ست", "probability": 0.978271484375}, {"start": 133.98, "end": 134.64, "word": " ذرات", "probability": 0.9856770833333334}, {"start": 134.64, "end": 135.58, "word": " كربون", "probability": 0.9910481770833334}], "temperature": 1.0}, {"id": 6, "seek": 16551, "start": 137.29, "end": 165.51, "text": "على حسب ما بنرسم احنا ال sugar بالطريقة اللي اتعلمناها الذرة الأولى من فوق الديهايد وبناء على ذلك هذا مش chiral center والذرة الأخيرة من تحت CH2OH مش chiral center واجتها لو رسمنا الشكل اللي بنسميه الacyclic structure بيكون فينا كام isomer كام chiral center أربعة بيقدروا إلى", "tokens": [3615, 23942, 11331, 35457, 19446, 44945, 2288, 38251, 1975, 5016, 8315, 2423, 5076, 20666, 9566, 16572, 28671, 13672, 1829, 1975, 2655, 3615, 19528, 8315, 11296, 32545, 25720, 16247, 12610, 7578, 9154, 6156, 30543, 2423, 16254, 11296, 25708, 46599, 1863, 16606, 15844, 29910, 23275, 23758, 37893, 23782, 304, 3056, 16070, 8848, 25720, 16247, 9778, 48923, 9154, 6055, 33753, 5995, 17, 31187, 37893, 23782, 304, 3056, 4032, 26108, 2655, 11296, 45164, 12602, 38251, 8315, 25124, 28820, 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{"start": 141.11, "end": 141.23, "word": " اللي", "probability": 0.70654296875}, {"start": 141.23, "end": 142.09, "word": " اتعلمناها", "probability": 0.9561360677083334}, {"start": 142.09, "end": 143.03, "word": " الذرة", "probability": 0.6434326171875}, {"start": 143.03, "end": 143.39, "word": " الأولى", "probability": 0.9373372395833334}, {"start": 143.39, "end": 143.57, "word": " من", "probability": 0.9931640625}, {"start": 143.57, "end": 144.01, "word": " فوق", "probability": 0.98779296875}, {"start": 144.01, "end": 145.15, "word": " الديهايد", "probability": 0.68017578125}, {"start": 145.15, "end": 146.29, "word": " وبناء", "probability": 0.7469075520833334}, {"start": 146.29, "end": 146.53, "word": " على", "probability": 0.81201171875}, {"start": 146.53, "end": 146.89, "word": " ذلك", "probability": 0.9931640625}, {"start": 146.89, "end": 147.13, "word": " هذا", "probability": 0.5302734375}, {"start": 147.13, "end": 147.37, "word": " مش", "probability": 0.93798828125}, {"start": 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"end": 155.03, "word": " رسمنا", "probability": 0.9847005208333334}, {"start": 155.03, "end": 155.61, "word": " الشكل", "probability": 0.98095703125}, {"start": 155.61, "end": 155.77, "word": " اللي", "probability": 0.7841796875}, {"start": 155.77, "end": 156.97, "word": " بنسميه", "probability": 0.9613037109375}, {"start": 156.97, "end": 158.05, "word": " الacyclic", "probability": 0.785888671875}, {"start": 158.05, "end": 158.91, "word": " structure", "probability": 0.89599609375}, {"start": 158.91, "end": 159.59, "word": " بيكون", "probability": 0.9069010416666666}, {"start": 159.59, "end": 159.99, "word": " فينا", "probability": 0.71533203125}, {"start": 159.99, "end": 160.63, "word": " كام", "probability": 0.885009765625}, {"start": 160.63, "end": 162.05, "word": " isomer", "probability": 0.46197509765625}, {"start": 162.05, "end": 162.95, "word": " كام", "probability": 0.8037109375}, {"start": 162.95, "end": 163.37, "word": " chiral", "probability": 0.98046875}, {"start": 163.37, "end": 163.83, "word": " center", "probability": 0.93896484375}, {"start": 163.83, "end": 164.67, "word": " أربعة", "probability": 0.7657877604166666}, {"start": 164.67, "end": 165.25, "word": " بيقدروا", "probability": 0.7392578125}, {"start": 165.25, "end": 165.51, "word": " إلى", "probability": 0.7109375}], "temperature": 1.0}, {"id": 7, "seek": 18134, "start": 167.44, "end": 181.34, "text": "الان طالما ان السكر عبارة عن الكهول و الديهايد لو جربنا نجعل الكهول يسكر على الديهايد هيعمل a new chiral center هيصير اندفع", "tokens": [6027, 7649, 23032, 6027, 15042, 16472, 21136, 37983, 6225, 3555, 9640, 3660, 18871, 33251, 3224, 12610, 4032, 2423, 16254, 11296, 25708, 45164, 10874, 25513, 8315, 8717, 7435, 30241, 33251, 3224, 12610, 7251, 3794, 37983, 15844, 2423, 16254, 11296, 25708, 8032, 1829, 25957, 1211, 257, 777, 23782, 304, 3056, 8032, 1829, 9381, 13546, 16472, 3215, 5172, 3615], "avg_logprob": -0.3034539390028569, "compression_ratio": 1.5407407407407407, "no_speech_prob": 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"text": "خمسة كايرال سنترز وجدت بنتوقع انه لسكر مكون من ست ذرات كربون بهذا الشكل يكون عنده اتنين و تلاتين ايزومات طبعا لما تمت عملية الاغلاق لما تمت عملية اغلاق الالكول على ال الديهايد", "tokens": [9778, 2304, 3794, 3660, 9122, 995, 13546, 6027, 8608, 29399, 2288, 11622, 49610, 3215, 2655, 4724, 29399, 30543, 3615, 16472, 3224, 5296, 3794, 37983, 3714, 4117, 2407, 1863, 9154, 8608, 2655, 29910, 2288, 9307, 9122, 25513, 11536, 39627, 15730, 25124, 28820, 7251, 30544, 43242, 3224, 1975, 2655, 1863, 9957, 4032, 6055, 1211, 9307, 9957, 1975, 1829, 11622, 20498, 9307, 23032, 3555, 3615, 995, 5296, 15042, 46811, 2655, 6225, 42213, 10632, 2423, 5718, 118, 15040, 4587, 5296, 15042, 46811, 2655, 6225, 42213, 10632, 1975, 17082, 15040, 4587, 2423, 6027, 4117, 12610, 15844, 2423, 2423, 16254, 11296, 25708], "avg_logprob": -0.2453286033315757, "compression_ratio": 1.8705882352941177, "no_speech_prob": 0.0, "words": [{"start": 181.62, "end": 182.26, "word": "خمسة", "probability": 0.8182373046875}, {"start": 182.26, "end": 182.74, "word": " كايرال", "probability": 0.626220703125}, {"start": 182.74, "end": 183.32, "word": " سنترز", "probability": 0.6751708984375}, {"start": 183.32, "end": 183.7, "word": " وجدت", "probability": 0.601318359375}, {"start": 183.7, "end": 184.42, "word": " بنتوقع", "probability": 0.7833251953125}, {"start": 184.42, "end": 185.04, "word": " انه", "probability": 0.609619140625}, {"start": 185.04, "end": 186.58, "word": " لسكر", "probability": 0.8326822916666666}, {"start": 186.58, "end": 187.08, "word": " مكون", "probability": 0.6051025390625}, {"start": 187.08, "end": 187.28, "word": " من", "probability": 0.98779296875}, {"start": 187.28, "end": 187.56, "word": " ست", "probability": 0.81298828125}, {"start": 187.56, "end": 188.0, "word": " ذرات", "probability": 0.81591796875}, {"start": 188.0, "end": 188.48, "word": " كربون", "probability": 0.953125}, {"start": 188.48, "end": 188.94, "word": " بهذا", "probability": 0.794189453125}, {"start": 188.94, "end": 189.46, "word": " الشكل", "probability": 0.9921875}, {"start": 189.46, "end": 190.14, "word": " يكون", "probability": 0.9326171875}, {"start": 190.14, "end": 190.82, "word": " عنده", "probability": 0.904541015625}, {"start": 190.82, "end": 191.36, "word": " اتنين", "probability": 0.86572265625}, {"start": 191.36, "end": 191.46, "word": " و", "probability": 0.736328125}, {"start": 191.46, "end": 192.14, "word": " تلاتين", "probability": 0.947265625}, {"start": 192.14, "end": 193.36, "word": " ايزومات", "probability": 0.68916015625}, {"start": 193.36, "end": 194.16, "word": " طبعا", "probability": 0.9464111328125}, {"start": 194.16, "end": 194.62, "word": " لما", "probability": 0.879638671875}, {"start": 194.62, "end": 195.08, "word": " تمت", "probability": 0.983154296875}, {"start": 195.08, "end": 195.6, "word": " عملية", "probability": 0.986328125}, {"start": 195.6, "end": 196.48, "word": " الاغلاق", "probability": 0.781884765625}, {"start": 196.48, "end": 196.9, "word": " لما", "probability": 0.73291015625}, {"start": 196.9, "end": 197.32, "word": " تمت", "probability": 0.983154296875}, {"start": 197.32, "end": 197.76, "word": " عملية", "probability": 0.9754231770833334}, {"start": 197.76, "end": 198.3, "word": " اغلاق", "probability": 0.984130859375}, {"start": 198.3, "end": 199.2, "word": " الالكول", "probability": 0.7208251953125}, {"start": 199.2, "end": 200.24, "word": " على", "probability": 0.86669921875}, {"start": 200.24, "end": 200.58, "word": " ال", "probability": 0.9501953125}, {"start": 200.58, "end": 201.54, "word": " الديهايد", "probability": 0.703857421875}], "temperature": 1.0}, {"id": 9, "seek": 21844, "start": 201.96, "end": 218.44, "text": "بهذا الشكل اتكون عندى هنا ال new chiral center وقولنا الكاربون هذه اللى بتعمل ال new chiral center شو بنسميها احنا انوميرك كاربون الان معنى new chiral center ان هو ال OH هذى بنسميها اما لأعلى", "tokens": [3555, 3224, 15730, 25124, 28820, 1975, 2655, 30544, 43242, 7578, 34105, 2423, 777, 23782, 304, 3056, 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210.74, "end": 210.92, "word": " شو", "probability": 0.7998046875}, {"start": 210.92, "end": 211.4, "word": " بنسميها", "probability": 0.918701171875}, {"start": 211.4, "end": 211.7, "word": " احنا", "probability": 0.9602864583333334}, {"start": 211.7, "end": 212.84, "word": " انوميرك", "probability": 0.6132965087890625}, {"start": 212.84, "end": 213.32, "word": " كاربون", "probability": 0.9700927734375}, {"start": 213.32, "end": 214.14, "word": " الان", "probability": 0.6695556640625}, {"start": 214.14, "end": 214.8, "word": " معنى", "probability": 0.8631184895833334}, {"start": 214.8, "end": 214.98, "word": " new", "probability": 0.705078125}, {"start": 214.98, "end": 215.46, "word": " chiral", "probability": 0.974365234375}, {"start": 215.46, "end": 215.78, "word": " center", "probability": 0.92236328125}, {"start": 215.78, "end": 215.96, "word": " ان", "probability": 0.280517578125}, {"start": 215.96, "end": 216.08, "word": " هو", "probability": 0.52587890625}, {"start": 216.08, 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243.0, "end": 244.24, "word": " الآن", "probability": 0.81884765625}, {"start": 244.24, "end": 244.48, "word": " اللي", "probability": 0.953369140625}, {"start": 244.48, "end": 244.84, "word": " بدي", "probability": 0.6981201171875}, {"start": 244.84, "end": 245.76, "word": " أنبهله", "probability": 0.71929931640625}], "temperature": 1.0}, {"id": 11, "seek": 26449, "start": 246.71, "end": 264.49, "text": "طيب الآن قلنا في عندنا شكل a cyclic و أشكال cyclic لأ هذا السكر ال a cyclic يترى بأي نسبة عادة موجود في المحلول و ال cyclic بأي نسبة موجودين في المحلول", "tokens": [9566, 1829, 3555, 6024, 48506, 12174, 1211, 8315, 8978, 43242, 8315, 13412, 28820, 257, 38154, 1050, 4032, 5551, 8592, 4117, 6027, 38154, 1050, 5296, 10721, 23758, 21136, 37983, 2423, 257, 38154, 1050, 7251, 2655, 2288, 7578, 4724, 10721, 1829, 8717, 35457, 3660, 6225, 18513, 3660, 3714, 29245, 23328, 8978, 9673, 5016, 1211, 12610, 4032, 2423, 38154, 1050, 4724, 10721, 1829, 8717, 35457, 3660, 3714, 29245, 23328, 9957, 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{"start": 701.28, "end": 701.66, "word": " الناحية", "probability": 0.8551025390625}, {"start": 701.66, "end": 702.16, "word": " الفرغية", "probability": 0.80841064453125}, {"start": 702.16, "end": 702.66, "word": " مافيش", "probability": 0.7388509114583334}, {"start": 702.66, "end": 702.98, "word": " حد", "probability": 0.98388671875}, {"start": 702.98, "end": 703.86, "word": " مضايقها", "probability": 0.81220703125}, {"start": 703.86, "end": 704.82, "word": " واضح؟", "probability": 0.74761962890625}, {"start": 704.82, "end": 705.2, "word": " لحظوا", "probability": 0.8824462890625}, {"start": 705.2, "end": 705.36, "word": " هذه", "probability": 0.7958984375}, {"start": 705.36, "end": 705.5, "word": " ال", "probability": 0.9736328125}, {"start": 705.5, "end": 705.84, "word": " OH", "probability": 0.6865234375}, {"start": 705.84, "end": 706.46, "word": " الجديدة", "probability": 0.94140625}, {"start": 706.46, "end": 706.62, "word": " اللي", "probability": 0.8955078125}, {"start": 706.62, "end": 707.14, "word": " اتكونت", "probability": 0.9078369140625}, {"start": 707.14, "end": 707.6, "word": " عندى", "probability": 0.851318359375}], "temperature": 1.0}, {"id": 32, "seek": 73696, "start": 708.02, "end": 736.96, "text": "الان في ال equatorial form هي مترايحة في ال axial form مش مترايحة في جنبها مجموعات تانية بتعمل ازدحام فراغي فلما نكون بدنا نفسر ليش ال beta موجودة اكثر من ال alpha بنقول because the beta o h is found in the equatorial position لان موجودة في ال equatorial ال equatorial is not a crowded position", "tokens": [6027, 7649, 8978, 2423, 45544, 831, 1254, 39896, 44650, 23557, 1829, 5016, 3660, 8978, 2423, 46851, 1254, 37893, 44650, 23557, 1829, 5016, 3660, 8978, 10874, 1863, 3555, 11296, 3714, 7435, 2304, 45367, 9307, 6055, 7649, 10632, 39894, 25957, 1211, 1975, 11622, 3215, 5016, 10943, 6156, 2288, 5718, 118, 1829, 6156, 1211, 15042, 8717, 30544, 47525, 8315, 8717, 36178, 2288, 32239, 8592, 2423, 9861, 3714, 29245, 23328, 3660, 1975, 4117, 49115, 9154, 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الشكل على هيئة الكرسي بتكون موجودة وين؟ في ال axial ولا في ال equatorial؟ في ال equatorial ال equatorial is not a sterically hindered molecule", "tokens": [2407, 46958, 5016, 6156, 35457, 3555, 6024, 104, 3555, 9307, 5296, 2423, 9861, 16472, 2423, 13931, 25724, 16254, 41891, 29538, 13672, 1829, 1975, 2655, 30544, 2655, 43242, 1829, 34105, 45164, 12602, 38251, 2655, 25124, 28820, 15844, 39896, 19986, 3660, 33251, 2288, 3794, 1829, 39894, 30544, 3714, 29245, 23328, 3660, 4032, 9957, 22807, 8978, 2423, 46851, 49429, 8978, 2423, 45544, 831, 22807, 8978, 2423, 45544, 831, 2423, 45544, 831, 307, 406, 257, 18924, 984, 20138, 4073, 15582], "avg_logprob": -0.24411525509574197, "compression_ratio": 1.5804878048780489, "no_speech_prob": 0.0, "words": [{"start": 737.87, "end": 738.41, "word": "واضح", "probability": 0.958984375}, {"start": 738.41, "end": 739.57, "word": " فسبب", "probability": 0.783935546875}, {"start": 739.57, "end": 740.39, "word": " الثبات", "probability": 0.9559326171875}, 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0.857177734375}, {"start": 758.03, "end": 758.61, "word": " hindered", "probability": 0.79736328125}, {"start": 758.61, "end": 759.35, "word": " molecule", "probability": 0.89599609375}], "temperature": 1.0}, {"id": 34, "seek": 77031, "start": 761.87, "end": 770.31, "text": "طبعا الـ mutarotation حكينا عنه برضه المرة الماضية، قلنا لو بدنا من أي واحد، حيصل لإيش؟ للإتزان", "tokens": [9566, 3555, 3615, 995, 2423, 39184, 5839, 289, 310, 399, 11331, 4117, 1829, 8315, 18871, 3224, 4724, 43042, 3224, 9673, 25720, 9673, 46958, 10632, 12399, 12174, 1211, 8315, 45164, 47525, 8315, 9154, 36632, 36764, 24401, 12399, 11331, 1829, 36520, 5296, 28814, 1829, 8592, 22807, 24976, 28814, 2655, 11622, 7649], "avg_logprob": -0.2918749922513962, "compression_ratio": 1.265625, "no_speech_prob": 0.0, "words": [{"start": 761.87, "end": 762.33, "word": "طبعا", "probability": 0.798614501953125}, {"start": 762.33, "end": 762.49, "word": " الـ", "probability": 0.74951171875}, {"start": 762.49, "end": 763.33, 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" اختزال", "probability": 0.8983154296875}, {"start": 1991.02, "end": 1992.02, "word": " الديهايد", "probability": 0.8134765625}, {"start": 1992.02, "end": 1992.7, "word": " بيصير", "probability": 0.970947265625}, {"start": 1992.7, "end": 1993.14, "word": " alcohol", "probability": 0.78857421875}, {"start": 1993.14, "end": 1993.76, "word": " أكسدة", "probability": 0.937255859375}, {"start": 1993.76, "end": 1994.46, "word": " الديهايد", "probability": 0.968505859375}, {"start": 1994.46, "end": 1995.14, "word": " بيصير", "probability": 0.977294921875}, {"start": 1995.14, "end": 1995.52, "word": " acid", "probability": 0.94091796875}, {"start": 1995.52, "end": 1996.1, "word": " الآن", "probability": 0.55889892578125}, {"start": 1996.1, "end": 1996.38, "word": " احنا", "probability": 0.816650390625}, {"start": 1996.38, "end": 1996.92, "word": " التفاعل", "probability": 0.947509765625}, {"start": 1996.92, "end": 1997.08, "word": " اللي", "probability": 0.8349609375}, {"start": 1997.08, "end": 1997.42, "word": " موجود", "probability": 0.98681640625}, {"start": 1997.42, "end": 1997.94, "word": " عندنا", "probability": 0.994873046875}, {"start": 1997.94, "end": 1998.96, "word": " اختزال", "probability": 0.942138671875}, {"start": 1998.96, "end": 1999.82, "word": " الديهايد", "probability": 0.9608154296875}, {"start": 1999.82, "end": 2000.48, "word": " رجع", "probability": 0.962890625}, {"start": 2000.48, "end": 2001.08, "word": " لإيش؟", "probability": 0.757080078125}, {"start": 2001.08, "end": 2001.96, "word": " لالكحول", "probability": 0.79365234375}, {"start": 2001.96, "end": 2002.38, "word": " طب", "probability": 0.857421875}, {"start": 2002.38, "end": 2002.52, "word": " لو", "probability": 0.98486328125}, {"start": 2002.52, "end": 2002.9, "word": " عملنا", "probability": 0.9842122395833334}, {"start": 2002.9, "end": 2003.5, "word": " أكسدة", "probability": 0.9774169921875}, {"start": 2003.5, "end": 2004.56, "word": " للديهايد", "probability": 0.8790283203125}], "temperature": 1.0}, {"id": 86, "seek": 203325, "start": 2005.37, "end": 2033.25, "text": "هيصير acid واضح الفكرة المشكلة في الموضوع كالقاتل انه احنا قولنا اكسدة ال الديهيد بال oxidation بيصير acid و اكسدة الكحول بعمل مؤكسد قوي برضه بيصير ايش acid متذكرين لما أخدنا oxidation و في primary alcohol حسب نوع المؤكسد تمام طيب هذا ال sugar ايش موجود فيه في الديهيد", "tokens": [3224, 1829, 9381, 13546, 8258, 4032, 46958, 5016, 27188, 4117, 25720, 9673, 8592, 28820, 3660, 8978, 9673, 2407, 11242, 45367, 9122, 6027, 4587, 9307, 1211, 16472, 3224, 1975, 5016, 8315, 12174, 12610, 8315, 1975, 4117, 3794, 41891, 2423, 2423, 16254, 3224, 25708, 20666, 36767, 4724, 1829, 9381, 13546, 8258, 4032, 1975, 4117, 3794, 41891, 33251, 5016, 12610, 4724, 25957, 1211, 3714, 33604, 4117, 3794, 3215, 12174, 45865, 4724, 43042, 3224, 4724, 1829, 9381, 13546, 1975, 1829, 8592, 8258, 44650, 8848, 37983, 9957, 5296, 15042, 5551, 9778, 3215, 8315, 36767, 4032, 8978, 6194, 7658, 11331, 35457, 8717, 45367, 9673, 33604, 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"probability": 0.543701171875}, {"start": 2010.99, "end": 2011.25, "word": " احنا", "probability": 0.9552408854166666}, {"start": 2011.25, "end": 2011.55, "word": " قولنا", "probability": 0.8933919270833334}, {"start": 2011.55, "end": 2012.05, "word": " اكسدة", "probability": 0.810546875}, {"start": 2012.05, "end": 2012.29, "word": " ال", "probability": 0.94287109375}, {"start": 2012.29, "end": 2013.01, "word": " الديهيد", "probability": 0.626708984375}, {"start": 2013.01, "end": 2013.83, "word": " بال", "probability": 0.90283203125}, {"start": 2013.83, "end": 2014.33, "word": " oxidation", "probability": 0.640625}, {"start": 2014.33, "end": 2015.47, "word": " بيصير", "probability": 0.8525390625}, {"start": 2015.47, "end": 2015.91, "word": " acid", "probability": 0.9560546875}, {"start": 2015.91, "end": 2016.29, "word": " و", "probability": 0.61083984375}, {"start": 2016.29, "end": 2016.89, "word": " اكسدة", "probability": 0.928466796875}, {"start": 2016.89, "end": 2017.57, "word": " 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2051.76, "end": 2052.48, "word": " acid", "probability": 0.435546875}, {"start": 2052.48, "end": 2053.18, "word": " عامل", "probability": 0.9912109375}, {"start": 2053.18, "end": 2053.72, "word": " مؤكسد", "probability": 0.99619140625}, {"start": 2053.72, "end": 2054.08, "word": " تاني", "probability": 0.9182942708333334}, {"start": 2054.08, "end": 2054.52, "word": " اقوى", "probability": 0.931396484375}, {"start": 2054.52, "end": 2054.88, "word": " منه", "probability": 0.994384765625}, {"start": 2054.88, "end": 2055.24, "word": " ب", "probability": 0.8974609375}, {"start": 2055.24, "end": 2055.58, "word": " acid", "probability": 0.9033203125}, {"start": 2055.58, "end": 2055.78, "word": " ال", "probability": 0.97265625}, {"start": 2055.78, "end": 2056.46, "word": " aldehyde", "probability": 0.9521484375}, {"start": 2056.46, "end": 2056.8, "word": " و", "probability": 0.876953125}, {"start": 2056.8, "end": 2056.92, "word": " ب", "probability": 0.8935546875}, {"start": 2056.92, "end": 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88, "seek": 209673, "start": 2066.87, "end": 2096.73, "text": "لو أخدنا Sugar مع عامل مؤكسد خلّينا نقول ضعيف لبرومين ميّه أو فضّه مع انحاس خلّينا نركز برومين ووتر ب أكسد ال الديهايد بدل ما هو CHO بصير سيضه بالموند OOH صار أسد، إذا لبرومين ووتر كام أكسدة عمل عندى؟ أكسدة واحدة، بس أكسد ال الديهايد خلّاه أيش أسد؟ الآن وقت الديجلوكوز بنقول عنه بصير gluconic acid", "tokens": [1211, 2407, 5551, 9778, 3215, 8315, 24576, 20449, 6225, 10943, 1211, 3714, 33604, 4117, 3794, 3215, 16490, 1211, 11703, 9957, 995, 8717, 39648, 48812, 3615, 33911, 5296, 26890, 20498, 9957, 3714, 1829, 11703, 3224, 34051, 6156, 11242, 11703, 3224, 20449, 16472, 5016, 32277, 16490, 1211, 11703, 9957, 995, 8717, 31747, 11622, 4724, 2288, 20498, 9957, 4032, 35473, 2288, 4724, 5551, 4117, 3794, 3215, 2423, 2423, 16254, 11296, 25708, 47525, 1211, 19446, 31439, 5995, 46, 4724, 9381, 13546, 8608, 1829, 11242, 3224, 20666, 2304, 11536, 3215, 422, 31187, 20328, 9640, 5551, 3794, 3215, 12399, 11933, 15730, 5296, 26890, 20498, 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غلايكو سايتس عادية معنى ذلك أنا بدي سكر و مرسوم عليه على هذا الموقع تحديدا OR لاحظوا أن التفاعل مع الميثانول ما بيغير هدول ال OHS", "tokens": [3555, 1863, 9381, 13546, 8717, 39648, 18871, 11296, 364, 38353, 6877, 1875, 37495, 22653, 32771, 15040, 1829, 4117, 2407, 8608, 995, 36081, 3794, 4724, 3794, 9154, 16490, 1211, 6027, 29910, 25720, 11933, 1829, 8592, 8717, 36081, 2288, 29245, 9957, 4724, 3794, 11933, 15730, 12174, 12610, 8315, 9122, 19528, 3660, 32771, 15040, 1829, 4117, 2407, 8608, 995, 36081, 3794, 6225, 18513, 10632, 20449, 1863, 7578, 29910, 23275, 41850, 4724, 16254, 8608, 37983, 4032, 3714, 2288, 3794, 20498, 47356, 15844, 23758, 9673, 30543, 3615, 6055, 5016, 16254, 28259, 19654, 20193, 5016, 19913, 14407, 14739, 16712, 5172, 995, 30241, 20449, 9673, 1829, 12984, 7649, 12610, 19446, 4724, 1829, 17082, 13546, 8032, 3215, 12610, 2423, 422, 12527], "avg_logprob": -0.19997259268635198, "compression_ratio": 1.6355932203389831, "no_speech_prob": 0.0, "words": [{"start": 2340.61, 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بنسميها؟ Glycosidic bond موجودة ويلها أهمية جزء كبير من أهمية هذه المنطقة أنه لما بعدك السكريات بدهم يبدوا يعملوا dimers مع بعض يتحدوا هنلاحظ فائدة هذه ال glycosidic bond لأنه بربطوا من خلالها واضح؟ يربطوا مع بعض من خلالها", "tokens": [2304, 3615, 2423, 13931, 20328, 9640, 2655, 44650, 36520, 3660, 20449, 1975, 1829, 8592, 22807, 20449, 2423, 19654, 13412, 2407, 44945, 38251, 1829, 11296, 22807, 460, 356, 6877, 327, 299, 6086, 3714, 29245, 23328, 3660, 4032, 26895, 11296, 5551, 16095, 10632, 10874, 11622, 38207, 9122, 3555, 13546, 9154, 5551, 16095, 10632, 29538, 9673, 1863, 9566, 28671, 14739, 3224, 5296, 15042, 39182, 4117, 21136, 4117, 16572, 9307, 47525, 16095, 7251, 44510, 14407, 7251, 25957, 1211, 14407, 5013, 433, 20449, 45030, 11242, 7251, 2655, 24401, 14407, 8032, 1863, 15040, 5016, 19913, 6156, 16373, 41891, 29538, 2423, 22633, 6877, 327, 299, 6086, 5296, 33456, 3224, 4724, 25513, 9566, 14407, 9154, 16490, 1211, 6027, 11296, 4032, 46958, 5016, 22807, 7251, 25513, 9566, 14407, 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الصفصاف لما كانوا بيغلو شجر الصفصاف بيطلع هذا المركب كانوا ياخدوله الصداع الناس الزمان فيه glycosidic bond لاحظوا اللى بتتأمل فيه بشكل بشكل قوى هتلاحظ ان هذا بيشبه ايش الاسميرين", "tokens": [24437, 4351, 1975, 15730, 23758, 9673, 31747, 3555, 13672, 7578, 24525, 2304, 3224, 8608, 6027, 1829, 3794, 9957, 9154, 13412, 7435, 2288, 31767, 5172, 9381, 31845, 5296, 15042, 25961, 14407, 4724, 1829, 17082, 1211, 2407, 13412, 7435, 2288, 31767, 5172, 9381, 31845, 4724, 1829, 9566, 1211, 3615, 23758, 9673, 31747, 3555, 25961, 14407, 7251, 47283, 3215, 12610, 3224, 31767, 28259, 3615, 2423, 8315, 3794, 6024, 110, 2304, 7649, 8978, 3224, 22633, 6877, 327, 299, 6086, 20193, 5016, 19913, 14407, 13672, 7578, 39894, 2655, 10721, 42213, 8978, 3224, 4724, 8592, 28820, 4724, 8592, 28820, 12174, 2407, 7578, 8032, 2655, 15040, 5016, 19913, 16472, 23758, 4724, 1829, 8592, 3555, 3224, 1975, 1829, 8592, 2423, 32277, 2304, 13546, 9957], "avg_logprob": -0.19070512616736257, "compression_ratio": 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CH2O", "probability": 0.90087890625}, {"start": 2469.88, "end": 2470.34, "word": " و", "probability": 0.78662109375}, {"start": 2470.34, "end": 2470.96, "word": " بعدين", "probability": 0.669677734375}, {"start": 2470.96, "end": 2471.54, "word": " أوهانة", "probability": 0.7462158203125}, {"start": 2471.54, "end": 2472.12, "word": " OH", "probability": 0.9248046875}, {"start": 2472.12, "end": 2473.04, "word": " نخليها", "probability": 0.8607177734375}, {"start": 2473.04, "end": 2473.56, "word": " OCOC", "probability": 0.5084635416666666}, {"start": 2473.56, "end": 2473.8, "word": " double", "probability": 0.377685546875}, {"start": 2473.8, "end": 2474.12, "word": " bond", "probability": 0.92041015625}, {"start": 2474.12, "end": 2475.04, "word": " Oacetyl", "probability": 0.5487060546875}, {"start": 2475.04, "end": 2475.5, "word": " يعني", "probability": 0.7646484375}, {"start": 2475.5, "end": 2476.04, "word": " وجود", "probability": 0.983154296875}, {"start": 2476.04, "end": 2477.0, 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"probability": 0.922607421875}, {"start": 2523.33, "end": 2523.73, "word": " هو", "probability": 0.919921875}, {"start": 2523.73, "end": 2524.39, "word": " ملتوز", "probability": 0.810546875}, {"start": 2524.39, "end": 2525.51, "word": " سكاروز", "probability": 0.7541015625}, {"start": 2525.51, "end": 2526.37, "word": " سيلو", "probability": 0.7128092447916666}, {"start": 2526.37, "end": 2526.83, "word": " بيوز", "probability": 0.8289794921875}, {"start": 2526.83, "end": 2527.13, "word": " كذا", "probability": 0.856689453125}, {"start": 2527.13, "end": 2527.53, "word": " كذا", "probability": 0.952880859375}, {"start": 2527.53, "end": 2528.49, "word": " موضوع", "probability": 0.98388671875}, {"start": 2528.49, "end": 2528.99, "word": " كبير", "probability": 0.9970703125}, {"start": 2528.99, "end": 2529.59, "word": " بحاجة", "probability": 0.989501953125}, {"start": 2529.59, "end": 2529.87, "word": " الى", "probability": 0.673095703125}, {"start": 2529.87, "end": 2530.07, "word": " ان", 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..b5357d128cf3182a46feaf57b85ed601ef8bab6d
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4533, "start": 20.79, "end": 45.33, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله في المحاضرة الأخيرة بدنا نحاول نراجع بعض الامتحانات نشوف كيف بتيجي الصورة الكلية في الامتحانات على هذه المادة في عندنا هذا الامتحان هذا الامتحان كان في الفصل الأول الماضي لطلاب السنة الأولى في كلية الطب", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 8978, 9673, 5016, 46958, 25720, 16247, 9778, 48923, 47525, 8315, 8717, 5016, 995, 12610, 8717, 2288, 26108, 3615, 45030, 11242, 2423, 10943, 2655, 5016, 7649, 9307, 8717, 8592, 38688, 9122, 33911, 4724, 31371, 7435, 1829, 31767, 13063, 3660, 33251, 1211, 10632, 8978, 2423, 10943, 2655, 5016, 7649, 9307, 15844, 29538, 9673, 18513, 3660, 8978, 43242, 8315, 23758, 2423, 10943, 2655, 5016, 7649, 23758, 2423, 10943, 2655, 5016, 7649, 25961, 8978, 27188, 36520, 16247, 12610, 9673, 46958, 1829, 5296, 9566, 15040, 3555, 21136, 1863, 3660, 16247, 12610, 7578, 8978, 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ما تاجم الفنل هنا محل ال CL بيعطيني ال ketone و بكمل ل tertiary alcohol أخدنا ال Easter و ال acid chloride مع Greenyard شو بيعطوني؟ tertiary alcohol و بال reduction؟ primary alcohol الان", "tokens": [2304, 7435, 2304, 34268, 9957, 6156, 1863, 1211, 15844, 3714, 43500, 9957, 8032, 36081, 5172, 995, 30241, 5551, 12610, 1975, 8592, 1829, 4724, 40228, 9566, 1829, 22653, 2423, 14979, 546, 5551, 12610, 19446, 6055, 26108, 2304, 27188, 1863, 1211, 34105, 3714, 5016, 1211, 2423, 12855, 4724, 40228, 9566, 1829, 22653, 2423, 14979, 546, 4032, 4724, 24793, 1211, 5296, 38726, 29104, 7658, 5551, 9778, 3215, 8315, 2423, 9403, 4032, 2423, 8258, 35434, 20449, 6969, 13862, 13412, 2407, 4724, 40228, 9566, 11536, 1829, 22807, 38726, 29104, 7658, 4032, 20666, 11004, 22807, 6194, 7658, 2423, 7649], "avg_logprob": -0.2588098442300837, "compression_ratio": 1.6619718309859155, "no_speech_prob": 0.0, "words": [{"start": 1494.1, "end": 1495.02, "word": "مجمعتين", "probability": 0.87568359375}, {"start": 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قلانين الستين هو ال بيبتايد ايش NCCO وكمان NCCO الان هاي بيبتايد من شغلتين القلانين شو المجموعة اللي هنا CH3 وهي ال amino terminal وهنا بدو يكون عندكم NH الستين شو المجموعة CH2SH وهنا بدو يكون", "tokens": [6027, 7649, 4724, 16254, 12174, 1211, 7649, 9957, 2423, 14851, 9957, 31439, 2423, 4724, 1829, 3555, 2655, 995, 25708, 1975, 1829, 8592, 426, 11717, 46, 4032, 24793, 7649, 426, 11717, 46, 2423, 7649, 8032, 47302, 4724, 1829, 3555, 2655, 995, 25708, 9154, 13412, 17082, 1211, 2655, 9957, 25062, 1211, 7649, 9957, 13412, 2407, 9673, 7435, 2304, 2407, 27884, 13672, 1829, 34105, 5995, 18, 37037, 1829, 2423, 24674, 14709, 37037, 8315, 47525, 2407, 7251, 30544, 43242, 24793, 31118, 2423, 14851, 9957, 13412, 2407, 9673, 7435, 2304, 2407, 27884, 5995, 17, 17308, 37037, 8315, 47525, 2407, 7251, 30544], "avg_logprob": -0.28237756748789367, "compression_ratio": 1.8764044943820224, "no_speech_prob": 0.0, "words": [{"start": 2072.05, "end": 2072.43, "word": "الان", "probability": 0.848876953125}, 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amino", "probability": 0.4775390625}, {"start": 2089.91, "end": 2090.91, "word": " terminal", "probability": 0.8671875}, {"start": 2090.91, "end": 2091.79, "word": " وهنا", "probability": 0.77490234375}, {"start": 2091.79, "end": 2092.01, "word": " بدو", "probability": 0.561767578125}, {"start": 2092.01, "end": 2092.23, "word": " يكون", "probability": 0.967041015625}, {"start": 2092.23, "end": 2092.81, "word": " عندكم", "probability": 0.96044921875}, {"start": 2092.81, "end": 2093.87, "word": " NH", "probability": 0.716796875}, {"start": 2093.87, "end": 2094.61, "word": " الستين", "probability": 0.85302734375}, {"start": 2094.61, "end": 2094.81, "word": " شو", "probability": 0.988037109375}, {"start": 2094.81, "end": 2095.65, "word": " المجموعة", "probability": 0.95791015625}, {"start": 2095.65, "end": 2099.93, "word": " CH2SH", "probability": 0.8977864583333334}, {"start": 2099.93, "end": 2100.43, "word": " وهنا", "probability": 0.86376953125}, {"start": 2100.43, "end": 2100.67, 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بيعملوا hydrolysis ال peptides واضح؟ hydrolysis peptide hydrolysis بدو يتكسر ضايق الاشياء؟", "tokens": [11622, 16373, 3215, 23032, 3555, 3615, 995, 6245, 17, 9122, 2304, 7649, 6245, 17, 5995, 6866, 5995, 17, 17308, 37893, 17082, 12610, 995, 4724, 1829, 25957, 1211, 14407, 15435, 356, 17122, 2423, 41781, 1875, 4032, 46958, 5016, 22807, 15435, 356, 17122, 41781, 482, 15435, 356, 17122, 47525, 2407, 7251, 2655, 4117, 3794, 2288, 48812, 47302, 4587, 2423, 33599, 1829, 16606, 22807], "avg_logprob": -0.2971270247813194, "compression_ratio": 1.2448979591836735, "no_speech_prob": 0.0, "words": [{"start": 2320.13, "end": 2320.97, "word": "زائد", "probability": 0.8069661458333334}, {"start": 2320.97, "end": 2322.31, "word": " طبعا", "probability": 0.8304443359375}, {"start": 2322.31, "end": 2323.13, "word": " nh2", "probability": 0.6480712890625}, {"start": 2323.13, "end": 2323.59, "word": " كمان", "probability": 0.7496744791666666}, {"start": 2323.59, "end": 2324.47, "word": " nh2", 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"word": " خمسة", "probability": 0.975830078125}, {"start": 2881.53, "end": 2883.05, "word": " ستة", "probability": 0.9718424479166666}, {"start": 2883.05, "end": 2883.49, "word": " اذا", "probability": 0.811767578125}, {"start": 2883.49, "end": 2883.81, "word": " هذا", "probability": 0.8388671875}, {"start": 2883.81, "end": 2884.25, "word": " عبارة", "probability": 0.9952392578125}, {"start": 2884.25, "end": 2884.59, "word": " عن", "probability": 0.9921875}, {"start": 2884.59, "end": 2886.09, "word": " three", "probability": 0.26220703125}], "temperature": 1.0}, {"id": 105, "seek": 291624, "start": 2887.34, "end": 2916.24, "text": "هكسانون شو بيحمل ال three hexanone مثل و دايمثل بيحط مواقعهم يعني two مثل و six daimethylamino هذي إيش اسمها الآن مثل مثل six daimethylamino المركب الأخير هذا مر علينا في ال unhydrate افتلك unhydrate", "tokens": [3224, 4117, 3794, 7649, 11536, 13412, 2407, 4724, 1829, 35571, 1211, 2423, 1045, 23291, 282, 546, 50113, 1211, 4032, 11778, 995, 32640, 12984, 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"word": " hexanone", "probability": 0.7060546875}, {"start": 2890.52, "end": 2891.12, "word": " مثل", "probability": 0.9208984375}, {"start": 2891.12, "end": 2892.46, "word": " و", "probability": 0.88525390625}, {"start": 2892.46, "end": 2893.14, "word": " دايمثل", "probability": 0.75419921875}, {"start": 2893.14, "end": 2893.8, "word": " بيحط", "probability": 0.66534423828125}, {"start": 2893.8, "end": 2894.72, "word": " مواقعهم", "probability": 0.9640625}, {"start": 2894.72, "end": 2895.8, "word": " يعني", "probability": 0.817138671875}, {"start": 2895.8, "end": 2896.08, "word": " two", "probability": 0.85595703125}, {"start": 2896.08, "end": 2896.96, "word": " مثل", "probability": 0.839599609375}, {"start": 2896.96, "end": 2897.42, "word": " و", "probability": 0.875}, {"start": 2897.42, "end": 2897.94, "word": " six", "probability": 0.8408203125}, {"start": 2897.94, "end": 2899.54, "word": " daimethylamino", "probability": 0.6846516927083334}, {"start": 2899.54, "end": 2900.2, "word": " هذي", "probability": 0.5343017578125}, {"start": 2900.2, "end": 2900.32, "word": " إيش", "probability": 0.8035481770833334}, {"start": 2900.32, "end": 2900.7, "word": " اسمها", "probability": 0.8504231770833334}, {"start": 2900.7, "end": 2900.92, "word": " الآن", "probability": 0.652587890625}, {"start": 2900.92, "end": 2901.3, "word": " مثل", "probability": 0.956787109375}, {"start": 2901.3, "end": 2901.72, "word": " مثل", "probability": 0.9912109375}, {"start": 2901.72, "end": 2903.02, "word": " six", "probability": 0.33837890625}, {"start": 2903.02, "end": 2904.32, "word": " daimethylamino", "probability": 0.9130859375}, {"start": 2904.32, "end": 2906.0, "word": " المركب", "probability": 0.8948567708333334}, {"start": 2906.0, "end": 2906.8, "word": " الأخير", "probability": 0.9173177083333334}, {"start": 2906.8, "end": 2907.2, "word": " هذا", "probability": 0.623046875}, {"start": 2907.2, "end": 2907.5, "word": " مر", "probability": 0.897705078125}, {"start": 2907.5, "end": 2907.84, "word": " علينا", "probability": 0.947265625}, {"start": 2907.84, "end": 2908.0, "word": " في", "probability": 0.86328125}, {"start": 2908.0, "end": 2908.14, "word": " ال", "probability": 0.9541015625}, {"start": 2908.14, "end": 2909.12, "word": " unhydrate", "probability": 0.58984375}, {"start": 2909.12, "end": 2910.5, "word": " افتلك", "probability": 0.79425048828125}, {"start": 2910.5, "end": 2916.24, "word": " unhydrate", "probability": 0.6554361979166666}], "temperature": 1.0}, {"id": 106, "seek": 292872, "start": 2917.52, "end": 2928.72, "text": "على اي حال بيكفي لهذا الجزء الباقي عبارة عن معادلات شبيهة بالامثلة التانية، بننهي الآن و بنتمنى لكم التوفيق", "tokens": [3615, 23942, 1975, 1829, 11331, 6027, 4724, 1829, 4117, 41185, 46740, 15730, 25724, 11622, 38207, 29739, 995, 38436, 6225, 3555, 9640, 3660, 18871, 20449, 18513, 1211, 9307, 13412, 21292, 3224, 3660, 20666, 10943, 12984, 37977, 16712, 7649, 10632, 12399, 44945, 1863, 3224, 1829, 6024, 48506, 4032, 4724, 29399, 27842, 7578, 5296, 24793, 16712, 38688, 1829, 4587], "avg_logprob": -0.16529605890575208, "compression_ratio": 1.5193798449612403, "no_speech_prob": 0.0, "words": [{"start": 2917.52, "end": 2917.8, "word": "على", "probability": 0.916748046875}, {"start": 2917.8, "end": 2918.0, "word": " اي", "probability": 0.68017578125}, {"start": 2918.0, "end": 2918.28, "word": " حال", "probability": 0.99755859375}, {"start": 2918.28, "end": 2919.46, "word": " بيكفي", "probability": 0.72076416015625}, {"start": 2919.46, "end": 2920.4, "word": " لهذا", "probability": 0.92529296875}, {"start": 2920.4, "end": 2920.82, "word": " الجزء", "probability": 0.96484375}, {"start": 2920.82, "end": 2921.36, "word": " الباقي", "probability": 0.96728515625}, {"start": 2921.36, "end": 2921.98, "word": " عبارة", "probability": 0.9600830078125}, {"start": 2921.98, "end": 2922.14, "word": " عن", "probability": 0.9873046875}, {"start": 2922.14, "end": 2922.92, "word": " معادلات", "probability": 0.9893798828125}, {"start": 2922.92, "end": 2923.52, "word": " شبيهة", "probability": 0.8448486328125}, {"start": 2923.52, "end": 2924.08, "word": " بالامثلة", "probability": 0.890625}, {"start": 2924.08, "end": 2925.16, "word": " التانية،", "probability": 0.7880859375}, {"start": 2925.16, "end": 2925.86, "word": " بننهي", "probability": 0.846435546875}, {"start": 2925.86, "end": 2926.32, "word": " الآن", "probability": 0.7890625}, {"start": 2926.32, "end": 2926.86, "word": " و", "probability": 0.607421875}, {"start": 2926.86, "end": 2927.46, "word": " بنتمنى", "probability": 0.75970458984375}, {"start": 2927.46, "end": 2927.82, "word": " لكم", "probability": 0.90380859375}, {"start": 2927.82, "end": 2928.72, "word": " التوفيق", "probability": 0.9820556640625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2929.476, "duration_after_vad": 2695.5443749999886}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..37866b5d2623ee7274e72feb0da3a05be78b0de3
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8.srt
@@ -0,0 +1,1484 @@
+1
+00:00:21,450 --> 00:00:26,690
+بسم الله الرحمن الرحيم طبعا سعاداء أن احنا نلتقي
+
+2
+00:00:26,690 --> 00:00:31,710
+فيكم في المحاضرة الأولى في هذا المساق هذا مساق
+
+3
+00:00:31,710 --> 00:00:38,510
+كيميا عضوية أو كيميا عضوية و حيوية يدرس عادةً بأرقام 
+
+4
+00:00:38,510 --> 00:00:43,510
+مختلفة في الجامعة لأكثر من تخصص يعني لطلبة العلوم
+
+5
+00:00:43,510 --> 00:00:49,690
+الصحية احنا بندرسه بالرقم Bioc 1301 لطلبة كلية 
+
+6
+00:00:49,690 --> 00:00:55,770
+الطب بندرسه بالرقم Medic 1310 ولطلبة العلوم 
+
+7
+00:00:55,770 --> 00:00:59,390
+الحياتية البيولوجيا والبيئة وما إلى ذلك برضه 
+
+8
+00:00:59,390 --> 00:01:07,060
+بندرسه برقم Chem 2311 فكل هؤلاء الطلبة بإذن الله 
+
+9
+00:01:07,060 --> 00:01:10,700
+بيستطيعوا أنهم يستفيدوا من هذا المساق و اللي يعني 
+
+10
+00:01:10,700 --> 00:01:15,900
+إن شاء الله سيكون مسجل حتى يعني يمكنكم تدارك أي 
+
+11
+00:01:15,900 --> 00:01:19,760
+معلومات نقصت عليكم أثناء يعني سماع المحاضرة 
+
+12
+00:01:19,760 --> 00:01:24,960
+الأصلية، مسموح طبعا أنه يكون في نقاش علمي هادق و 
+
+13
+00:01:24,960 --> 00:01:29,280
+بيظهر في التصوير أنتوَ كلكم كمان واضحين أمام 
+
+14
+00:01:29,280 --> 00:01:35,120
+الكاميرات ومناقشاتكوا هتكون يعني مثرية لتدريس هذا 
+
+15
+00:01:35,120 --> 00:01:40,020
+المساق إن شاء الله الكتاب
+
+16
+00:01:40,020 --> 00:01:45,600
+المقرر هو كتاب مشهور جدا في مجاله كتاب organic 
+
+17
+00:01:45,600 --> 00:01:50,540
+chemistry للمؤلف heart and heart هذا الكتاب طبعا
+
+18
+00:01:50,540 --> 00:01:55,700
+مع المحتويات الإلكترونية كلها موفرة لكم إن شاء 
+
+19
+00:01:55,700 --> 00:02:01,560
+الله، الجزء الأول من المساق اللي هندرسه مقدمة في
+
+20
+00:02:01,560 --> 00:02:06,220
+الكيمياء العضوية بنتعرف جيد على المجموعات الوظيفية 
+
+21
+00:02:06,220 --> 00:02:10,420
+على أنواع المركبات العضوية هذه المقدمة في الكيمياء 
+
+22
+00:02:10,420 --> 00:02:16,400
+العضوية حوالى 11 فاصل لما تصير موجودة عندنا بشكل
+
+23
+00:02:16,400 --> 00:02:21,960
+جيد بيصير بإمكاننا أنه نعطي بعدها مقدمة في الكيمياء
+
+24
+00:02:21,960 --> 00:02:28,080
+الحيوية باربع فصول إن شاء الله بهيك بيكون يعني ال
+
+25
+00:02:28,080 --> 00:02:32,660
+course اكتملت مكوناته مقدمة في الكيمياع العضوية و 
+
+26
+00:02:32,660 --> 00:02:36,220
+بعد هيك الجزء الثاني من ال course مقدمة في
+
+27
+00:02:36,220 --> 00:02:43,110
+الكيمياع الحيوية طبعا بدنا نبدأ مباشرة ما بضيقش وقت
+
+28
+00:02:43,110 --> 00:02:47,830
+الفصل الأول في المقدمة في الكيمياء الأضوية مفاهيم 
+
+29
+00:02:47,830 --> 00:02:51,750
+عامة بالذات أنه يعني أنتوَ أخدتوا شغلتين أخدتوا 
+
+30
+00:02:51,750 --> 00:02:56,730
+كيمياء عامة في الجامعة و أخدتوا أشياء مختلفة من
+
+31
+00:02:56,730 --> 00:03:02,090
+الكيمياء في المدارس بعضها أحيانا أو جزء خفيف في 
+
+32
+00:03:02,090 --> 00:03:06,830
+الكيمياء الأضوية هذه الاساسية المبادئ الأساسية
+
+33
+00:03:06,830 --> 00:03:11,710
+بتساعدكم في انكم تتعاملوا مع مساق الكيميا الأضوية
+
+34
+00:03:11,710 --> 00:03:19,130
+هذا الفصل اللي في المقدمة هنتكلم فيه عن الارتباط 
+
+35
+00:03:19,130 --> 00:03:22,990
+والتشكل bonding and isomerism يعني طالما أنه احنا
+
+36
+00:03:22,990 --> 00:03:28,650
+بنحكي عن مركبات في الكيميا الأضوية اكيد ذرات معينة
+
+37
+00:03:28,650 --> 00:03:34,950
+هترتبط تعطينا مركب bonding الآن هذه الذرات اللي 
+
+38
+00:03:34,950 --> 00:03:40,550
+بترتبط يمكن ان ترتبط بطرق مختلفة وبالتالي يمكن أن
+
+39
+00:03:40,550 --> 00:03:46,910
+تعطي اكثر من مركب اكثر من شكل او متشكل تماما زي ما
+
+40
+00:03:46,910 --> 00:03:51,360
+أنا هتعامل مع هذه الاقلام هنا بقدر اعمل ارتباط
+
+41
+00:03:51,360 --> 00:03:54,920
+بينهم كإني عملت مُركّب يعني لو تخيلتوا أن هدولة 
+
+42
+00:03:54,920 --> 00:03:58,840
+تلت ذرات مثلا Carbon, Hydrogen, Oxygen عملوا
+
+43
+00:03:58,840 --> 00:04:03,820
+مُركّب بطريقة معينة الآن لو غيرت ترتيب هدول الذرات
+
+44
+00:04:04,600 --> 00:04:10,560
+بكون عملت بكون عملت مركب تاني واضح لو غيرت هدول 
+
+45
+00:04:10,560 --> 00:04:14,760
+الذرات بكون عملت مركب تاني الآن المركب الأول و
+
+46
+00:04:14,760 --> 00:04:19,540
+المركب الثاني ما العلاقة بينهم هدول المركبين
+
+47
+00:04:19,540 --> 00:04:25,180
+بنسميهم ايش احنا isomers يعني لما بنقول المركب A و 
+
+48
+00:04:25,180 --> 00:04:31,360
+المركب B they are isomers متشكلات الآن الظاهرة كلها
+
+49
+00:04:31,360 --> 00:04:37,980
+إيش بنسميها isomerism، ظاهرة التشكل، و هنتعمق في 
+
+50
+00:04:37,980 --> 00:04:43,280
+هذا الموضوع بالتأكيد أثناء دراستنا، نتعمق في هذا 
+
+51
+00:04:43,280 --> 00:04:48,510
+الموضوع أثناء دراستنا الآن إذا بدنا نبدأ في موضوع
+
+52
+00:04:48,510 --> 00:04:53,950
+ال bonding طبعا مر عليكم أنواع الروابط مر عليكم
+
+53
+00:04:53,950 --> 00:04:57,770
+أنواع الروابط اللي بتكون في داخل الجزيئة أرجو 
+
+54
+00:04:57,770 --> 00:05:01,390
+انكوا تنتبهوا للي بقصده انا في ال bonding اللي
+
+55
+00:05:01,390 --> 00:05:06,270
+بقصده في ال bonding مش الروابط بين الجزيئات اللي
+
+56
+00:05:06,270 --> 00:05:11,070
+اسمها intermolecular forces لا الروابط في داخل
+
+57
+00:05:11,070 --> 00:05:16,720
+الجزيئة الروابط في داخل الجزيئ يعني في روابط بين 
+
+58
+00:05:16,720 --> 00:05:22,520
+الجزيئات مش هي المقصودة هنا يعني افترضوا مثلا جزيئ
+
+59
+00:05:22,520 --> 00:05:31,420
+الميّه H2O الآن هذا جزيئ هذه جزيئ ميّه تاني HOO
+
+60
+00:05:33,470 --> 00:05:38,730
+الآن هذه الروابط اللي في داخل الجزئ هي اللي أنا 
+
+61
+00:05:38,730 --> 00:05:44,650
+بقصدها في الكيميا بنعطيها اسم بنقول عنها intra 
+
+62
+00:05:44,650 --> 00:05:49,650
+molecular bonds يعني روابط within the molecule جوا 
+
+63
+00:05:49,650 --> 00:05:54,030
+الجزئ يعني هذه الروابط شو بيقول عنها intra 
+
+64
+00:05:56,090 --> 00:06:01,750
+موليكيولار بوندي انترا يعني روابط جوه الجزيه الآن
+
+65
+00:06:01,750 --> 00:06:04,550
+إذا اجيت بعد هيك بقول مثلا في عندي روابط 
+
+66
+00:06:04,550 --> 00:06:09,620
+هيدروجينية بين ال أكسجون والهيدروجين هذه روابط بين
+
+67
+00:06:09,620 --> 00:06:15,160
+الجزيئات Intermolecular forces فميزوا الكلمتين
+
+68
+00:06:15,160 --> 00:06:20,940
+Intramolecular اللي هي الروابط الأصلية القوية اللي 
+
+69
+00:06:20,940 --> 00:06:25,720
+في داخل الجزيئ بينما الروابط بين الجزيئات between
+
+70
+00:06:25,720 --> 00:06:31,070
+molecules شو بسميها أنا؟ Intermolecular forces
+
+71
+00:06:31,070 --> 00:06:37,790
+الأقوى نوع في الـ Intermolecular forces هذه قوتها
+
+72
+00:06:37,790 --> 00:06:42,230
+ما بتيجيش خمسة لعشرة في المية من قوة هذه الروابط
+
+73
+00:06:42,230 --> 00:06:47,250
+بمعنى لو أنا بدي أكسر الروابط من اللي سهل أني
+
+74
+00:06:47,250 --> 00:06:53,210
+أكسره ال Intermolecular forces تماما زي ما نتخيل
+
+75
+00:06:53,210 --> 00:06:59,070
+اتنين بيجوا بيسلموا على بعض في رابطة أصلية .. رابطة
+
+76
+00:06:59,070 --> 00:07:04,750
+هذا الكف مع الجسم .. هذي Intramolecular وفي رابطة
+
+77
+00:07:04,750 --> 00:07:08,010
+بين التنين اللي بيسلموا مع بعض .. هذي 
+
+78
+00:07:08,010 --> 00:07:13,110
+Intermolecular الأن لو ولدين صغار سلموا مع بعض و
+
+79
+00:07:13,110 --> 00:07:16,550
+الأم كل واحدة بدها تسحب ابنها وتمشي في طريقها ..
+
+80
+00:07:16,550 --> 00:07:22,030
+بيسحبوا الولد أن هي اللي بتنكسر .. هذي الرابطة ولا
+
+81
+00:07:22,030 --> 00:07:26,400
+هذي الرابطة؟ هذه الرابطة الـ Intermolecular Forces 
+
+82
+00:07:26,400 --> 00:07:29,500
+فالـ Intermolecular Forces اللي منها الـ London
+
+83
+00:07:29,500 --> 00:07:32,740
+Forces و الـ Dipole-Dipole Attractions و الـ
+
+84
+00:07:32,740 --> 00:07:37,780
+Hydrogen Bonding هذه روابط ضعيفة بين الجزيئات
+
+85
+00:07:37,780 --> 00:07:41,500
+بتأثر بشكل كبير على الخواص الفيزيائية لكن لما أنا 
+
+86
+00:07:41,500 --> 00:07:46,600
+بدأ ادرس تفاعلات و أقول أن التفاعل الكيميائي بعد
+
+87
+00:07:46,600 --> 00:07:52,500
+شوية كسر وتكوين روابط أنا لا أتكلم إطلاقا عن هذه
+
+88
+00:07:52,500 --> 00:07:57,340
+الروابط أنا بتكلم عن الروابط within the molecule
+
+89
+00:07:57,340 --> 00:08:02,640
+الـ Intramolecular forces و لما الآن بنصنف أنواع
+
+90
+00:08:02,640 --> 00:08:07,860
+هذه الروابط و بنحكي ionic bonds و covalent bonds و
+
+91
+00:08:07,860 --> 00:08:11,680
+coordinate covalent bonds بنكون بنحكي عن الروابط
+
+92
+00:08:11,680 --> 00:08:18,580
+اللي في جوة الجزء الـ Intramolecular واضح؟ اللي
+
+93
+00:08:18,580 --> 00:08:24,020
+بتكون الجزء نفسه الآن من هذه الروابط زي ما سبق 
+
+94
+00:08:24,020 --> 00:08:27,540
+أنكم اتعلمتوا من هذه الروابط زي ما سبق أنكم
+
+95
+00:08:27,540 --> 00:08:33,020
+اتعلمتوا ال ionic bonds ال ionic bonds بتنشأ لما
+
+96
+00:08:33,020 --> 00:08:37,680
+بيتكون عند أيونات في عناصر معينة عندها إلكترونات
+
+97
+00:08:37,680 --> 00:08:42,080
+زيادة عادة بتكون موجودة في أول الجدول الدوري على
+
+98
+00:08:42,080 --> 00:08:47,840
+اليسار بنسميها electropositive atoms زي الصوديوم
+
+99
+00:08:47,840 --> 00:08:51,240
+على سبيل المثال وكلكوا عارفين تركيبه الإلكتروني
+
+100
+00:08:51,240 --> 00:08:57,780
+1s2 2s2 2b6 3s1 لإن عنده إلكتروني زيادة لو فقدوا 
+
+101
+00:08:57,780 --> 00:09:02,600
+بيصل ال octet structure واضح لكن لما بيفقدوا هيصير 
+
+102
+00:09:02,600 --> 00:09:08,580
+عبارة عن أيونموجة في عند ذرات بنقول عنها electro
+
+103
+00:09:08,580 --> 00:09:13,000
+negative atoms هدولة نقصهم إلكترون عشان يصلوا لل
+
+104
+00:09:13,000 --> 00:09:18,480
+octet structures هدولة لو اكتسبوا لو اكتسبوا هذا 
+
+105
+00:09:18,480 --> 00:09:25,500
+الإلكترون بيصيروا أيونات سالبة زي الكلور مثلا 1s2
+
+106
+00:09:25,500 --> 00:09:32,320
+2s2 2b6 بعدين بيصير عندي 3s2 3b5 هذا ال 3b5 ما زال
+
+107
+00:09:32,320 --> 00:09:37,660
+عنده وسع لإيش لإلكترون واحد لو اكتسب هذا الإلكترون
+
+108
+00:09:37,660 --> 00:09:42,890
+طبعا هيكتسب أي إلكترون اللي فقط الصوديوم هيصير كلور
+
+109
+00:09:42,890 --> 00:09:47,990
+سالب اذا هنا صار في عندك صوديوم موجب و صار عندك 
+
+110
+00:09:47,990 --> 00:09:51,490
+كلور سالب هدول ال ايونات لما بيعملوا ال attraction
+
+111
+00:09:51,490 --> 00:09:57,690
+مع بعض بيكونوا ليه ال ionic bond واضح طبعا ممكن 
+
+112
+00:09:57,690 --> 00:10:02,250
+بعض العناصر اللي في المجموعة الثانية يفقدوا 
+
+113
+00:10:02,250 --> 00:10:07,880
+إلكترونين و بيكونوا Ion موجب اتنين ممكن يفقدوا 
+
+114
+00:10:07,880 --> 00:10:11,240
+تلاتة مثلا زي الالمنيون موجب تلاتة كل هذا الكلام 
+
+115
+00:10:11,240 --> 00:10:16,360
+بتاعي اللي عرفته وكيف نكتب صيغة مركب ايوني هذا
+
+116
+00:10:16,360 --> 00:10:20,720
+الكلام كله بيمور وين عندنا في الكيمياء العامة
+
+117
+00:10:20,720 --> 00:10:29,460
+بالنسبة ل ال covalent compounds بيفرقوا بشغلة أنه 
+
+118
+00:10:30,790 --> 00:10:35,610
+الروابط اللي بتتكون تتكون نتيجة مشاركة في
+
+119
+00:10:35,610 --> 00:10:39,210
+الإلكترونات يعني هذه عندها إلكترونات معينة هذه
+
+120
+00:10:39,210 --> 00:10:43,990
+عندها إلكترونات بيعملوا sharing للإلكترون فكل ذرة
+
+121
+00:10:43,990 --> 00:10:48,370
+بتصل للتركيب اللي هو المستقر إذا كنا بنحكي عن
+
+122
+00:10:48,370 --> 00:10:51,710
+هيدروجين كل ذرة بتصير اتنين و اتنين زي مثلا ما
+
+123
+00:10:51,710 --> 00:10:56,330
+نتخيل هيدروجين فيه إلكترونهذا مش يبين وهيدروجين
+
+124
+00:10:56,330 --> 00:11:00,050
+فيه إلكترون هيعملوا جزء الهيدروجين كأنه الآن كل 
+
+125
+00:11:00,050 --> 00:11:03,590
+ذرة هيدروجين عندها كام إلكترون اتنين هذا التركيب
+
+126
+00:11:03,590 --> 00:11:09,840
+ثابت أو الكلور مثلا مداره الأخير في سبع إلكترونات
+
+127
+00:11:09,840 --> 00:11:14,460
+الـ valence shell اللي موجود فيه الآن لما أنا بحكي
+
+128
+00:11:14,460 --> 00:11:18,940
+عن سبع إلكترونات لو صار مشاركة في هدول الإلكترونات
+
+129
+00:11:18,940 --> 00:11:23,780
+صارت كل ذرّة كلور كام إلكترون حولها تمانية إذا 
+
+130
+00:11:23,780 --> 00:11:29,240
+عملنا covalent compound كذلك لو بدى أخد H مع CL
+
+131
+00:11:29,240 --> 00:11:36,830
+برضه الرابط أيش بتكون covalent bond الـ bonds هذه 
+
+132
+00:11:36,830 --> 00:11:42,130
+الـ bonds هذه في إلها إشي بنسميه bond energy هذا 
+
+133
+00:11:42,130 --> 00:11:47,530
+تعبير عن قوة الروابط ال bond energy هو الطاقة 
+
+134
+00:11:47,530 --> 00:11:54,570
+اللازمة لكسر روابط واحد مول من الروابط الواحد مول 
+
+135
+00:11:54,570 --> 00:11:59,410
+عرفينه عدد مضاعف عدد ال 26 من الف في عشر أقصى
+
+136
+00:11:59,410 --> 00:12:04,030
+تلاتة وعشرين الآن عشان أكسر هذه الروابط .. هاي
+
+137
+00:12:04,030 --> 00:12:08,590
+رابطة .. لما أقول بدي أكسر الرابطة .. إيش بدي؟ بدي 
+
+138
+00:12:08,590 --> 00:12:14,870
+طاقة دايما معروف عندنا انه كسر الرابطة عملية بحاجة 
+
+139
+00:12:14,870 --> 00:12:21,590
+الى طاقة بقول عنها endothermic process بينما تكوين
+
+140
+00:12:21,590 --> 00:12:26,810
+الرابطة عملية طاردة للطاقة بقول عنها exothermic
+
+141
+00:12:26,810 --> 00:12:31,930
+process فال bond energy هي الطاقة اللي لازم الكسر
+
+142
+00:12:31,930 --> 00:12:36,170
+روابط او واحد مول من الروابط من ال covalent bonds 
+
+143
+00:12:36,170 --> 00:12:41,180
+كذلك في عندي إيش اسمه ال bond length ال bond length 
+
+144
+00:12:41,180 --> 00:12:48,660
+هو المسافة المتوسطة ما بين ذرتين ليش مسافة متوسطة
+
+145
+00:12:48,660 --> 00:12:54,420
+لأنه الرابطة هي عبارة عن مسافة بالفراغ ليست ثابتة
+
+146
+00:12:54,420 --> 00:12:58,260
+يعني ذرتين بينهم مسافة معينة في الفراغ بنقول هدول
+
+147
+00:12:58,260 --> 00:13:03,240
+الذرتين بينهم إيش رابطة الآن هذه المسافة تزيد
+
+148
+00:13:03,240 --> 00:13:08,500
+وتقصر ليست ثابتة تماما و لذلك احنا بناخد المسافة 
+
+149
+00:13:08,500 --> 00:13:12,000
+المتوسطة بيصير عندنا ال bond length الآن ال bond
+
+150
+00:13:12,000 --> 00:13:17,660
+length يقاس عادة بال angstrom اللي هو واحد في عشر 
+
+151
+00:13:17,660 --> 00:13:22,300
+أقصى ناقص عشرة من المتر أو بنقيسه في ال picometer 
+
+152
+00:13:22,300 --> 00:13:28,140
+اللي هو واحد في عشر أقصى ناقص اثنا عشرة من المتر واضح
+
+153
+00:13:28,140 --> 00:13:34,010
+طبعا لما نقيس ال bond length بالبيكميتر هتطلع 
+
+154
+00:13:34,010 --> 00:13:39,330
+أطوال الروابط عندنا سهلة الملاحظة وسهلة الحفظ يعني
+
+155
+00:13:39,330 --> 00:13:44,630
+خليني أفرجيكم كيف هي أنا بعطيكم مقارنة بين الرابطة
+
+156
+00:13:44,630 --> 00:13:49,590
+الأحادية هذه الرابطة اللي أنا بقصدها الأحادية
+
+157
+00:13:49,590 --> 00:13:52,890
+والثنائية والرابطة
+
+158
+00:13:54,550 --> 00:14:01,830
+الثلاثية الآن لاحظوا ان عدد الروابط بيزيد أُحادية
+
+159
+00:14:01,830 --> 00:14:07,970
+ثنائية ثلاثية هذا احنا بنسميه ال bond order إيش ال
+
+160
+00:14:07,970 --> 00:14:11,490
+bond order ال bond order is the number of chemical
+
+161
+00:14:11,490 --> 00:14:15,850
+bonds between a pair of atoms عدد الروابط ما بين
+
+162
+00:14:15,850 --> 00:14:22,270
+ذرتين هل يترى هدول الروابط منها ذرتين أُحادية ثنائية 
+
+163
+00:14:22,270 --> 00:14:28,490
+ثلاثية إيش بسمي أنا ال bond order الآن انتبهوا معي
+
+164
+00:14:28,490 --> 00:14:31,970
+as the bond order increases يعني كل ما بزيد من
+
+165
+00:14:31,970 --> 00:14:36,150
+الرابط أُحادية لا ثنائية لا ثلاثية بقول the bond 
+
+166
+00:14:36,150 --> 00:14:43,810
+will be stronger and shorter بتصير اقوى و اقصر 
+
+167
+00:14:43,810 --> 00:14:48,270
+ليش؟ لان الرابطة الأُحادية هي عبارة عن sigma bond
+
+168
+00:14:49,600 --> 00:14:56,440
+الرابطة الثلاثية هي عبارة عن سيجما و باي و لذلك 
+
+169
+00:14:56,440 --> 00:14:57,900
+أصبحت أقوى
+
+170
+00:15:06,370 --> 00:15:10,150
+بتخيلوها الأيام بتصير سهلة الفهم، هذه sigma bond
+
+171
+00:15:10,150 --> 00:15:15,350
+فقط، هذه sigma و by bond، هذه sigma و by و by، مين
+
+172
+00:15:15,350 --> 00:15:20,730
+أكتر واحدة فيها قوة؟ الرابطة الثلاثية، هذا الكلام
+
+173
+00:15:20,730 --> 00:15:25,930
+
+223
+00:20:03,330 --> 00:20:07,890
+بيعملوا رابطة واحدة و بيبقى عليهم كام زوج من
+
+224
+00:20:07,890 --> 00:20:13,190
+الإلكترونات؟ ثلاث أزواج، واضح؟ الآن هي أنا راسم
+
+225
+00:20:13,190 --> 00:20:20,730
+مركّب كبير لو بتتطلع عليه، كل رأس في هذا المركب
+
+226
+00:20:20,730 --> 00:20:25,770
+يمثل ذرة كربون إذا لاقيتوا إشي ناقص في أعداد
+
+227
+00:20:25,770 --> 00:20:30,270
+الروابط، معناه ذلك هذا الشيء اللي ناقص هو عبارة عن
+
+228
+00:20:30,270 --> 00:20:34,910
+هيدروجين اختصر في الكتابة لأنه إحنا عندنا شيء
+
+229
+00:20:34,910 --> 00:20:38,530
+بنسميه abbreviated structure اللي هو شكل مختصر
+
+230
+00:20:38,530 --> 00:20:43,590
+يعني اللي بينفهم ضمنه مرات مابنكتبهوش واضح؟ اللي
+
+231
+00:20:43,590 --> 00:20:47,930
+بينفهم ضمنه مرات مابنكتبوش فلاحظوا مثلا هاي ذرات
+
+232
+00:20:47,930 --> 00:20:53,830
+ال carbon هذه carbon هذه carbon carbon كل هذه
+
+233
+00:20:53,830 --> 00:20:59,630
+الذرات كل رأس هنا في الرسم يعتبر ذرة carbon و هاي
+
+234
+00:20:59,630 --> 00:21:04,470
+كمان carbon لو بنطلع عليهم كلهم كلهم عليهم أربع
+
+235
+00:21:04,470 --> 00:21:08,610
+روابط إذا في إشي مبين أقل معنا ذلك هذا فيه
+
+236
+00:21:08,610 --> 00:21:15,600
+هيدروجين اختصراكتابة يعني هذه CH3EC مبينين أربع
+
+237
+00:21:15,600 --> 00:21:19,720
+روابط هنا يمكن تطلع كربون متصلة بكربون و كربون إذا
+
+238
+00:21:19,720 --> 00:21:24,240
+ما المختصر هنا ذرتين هيدروجين بتكون تفهموهم يعني
+
+239
+00:21:24,240 --> 00:21:27,600
+لما نقول إقرأوا إيش فيه هنا بتقولوا هذه عبارة عن
+
+240
+00:21:27,600 --> 00:21:33,180
+CH2 مختصر من hydrogen و hydrogen كتابة هذه من بين
+
+241
+00:21:33,180 --> 00:21:37,380
+أربع روابط هذه من بين أربعة هذه carbon رابطة تنتين
+
+242
+00:21:37,380 --> 00:21:41,480
+و تنتين مع ال oxygen سليمة ال oxygen كم رابطة
+
+243
+00:21:41,480 --> 00:21:48,000
+تنتين ال oxygen هنا بطريقة تانية رابطتين بمعنى انه
+
+244
+00:21:48,000 --> 00:21:51,600
+ممكن يكونوا رابطة ثنائية في نهاية العدد تنتين او
+
+245
+00:21:51,600 --> 00:21:56,540
+رابطتين احديتين مافيش مشكلة كذلك مع ال carbon ممكن
+
+246
+00:21:56,540 --> 00:22:01,580
+يكونوا اربع روابط احدية ممكن يكون رابطة ثنائية و
+
+247
+00:22:01,580 --> 00:22:07,200
+رابطتين احديات ممكن تلت روابط يعني رابطة ثلاثية و
+
+248
+00:22:07,200 --> 00:22:10,360
+رابطة احدية المهم المجموع يكون في النهاية ايش
+
+249
+00:22:10,360 --> 00:22:13,900
+اربعة المهم المجموع يكون في النهاية اربعة لاحظوا
+
+250
+00:22:13,900 --> 00:22:19,500
+ال halogen هنارابطة واحدة بيكون أكيد عليه أزواج
+
+251
+00:22:19,500 --> 00:22:23,580
+إلكترونات لو كنا محتاجين إيه لفهم تفاعل بنكتبها مش
+
+252
+00:22:23,580 --> 00:22:28,240
+محتاجين عادة مابنكتبهاش يعني لو كنت بدي أكمل أزواج
+
+253
+00:22:28,240 --> 00:22:33,000
+الإلكترونات هنا أكيد ال oxygen عليه زوجين أكيد ال
+
+254
+00:22:33,000 --> 00:22:36,100
+nitrogen عليه زوج أكيد ال halogen عليه تلاتة
+
+255
+00:22:36,100 --> 00:22:42,740
+بالمناسبة بالنسبة لموضوع الروابط رسم الأشكال زي ما
+
+256
+00:22:42,740 --> 00:22:47,440
+هتلاحظوا ربما بعد two or three slides انه احنا
+
+257
+00:22:47,440 --> 00:22:54,900
+بنرسم الأشكال بأكثر من طريقة بمعنى ممكن احنا نرسم
+
+258
+00:22:54,900 --> 00:23:01,620
+شكل مركب بتفصيل كامل يعني نبيّن فيه كل ذرة من
+
+259
+00:23:01,620 --> 00:23:05,500
+الذرات ممكن نبين في المراكب كل ذرة من الذرات زي ما
+
+260
+00:23:05,500 --> 00:23:14,600
+احنا رسمين هنا CH3 CH2 CH2 OH هذا قواعد الروابط
+
+261
+00:23:14,600 --> 00:23:18,740
+كلها بتنطبق عليه سليم الان لو هذا كنت بدي اكتبه
+
+262
+00:23:18,740 --> 00:23:26,880
+بطريقة الكتابة العادية هاكتبه CH3 CH2 CH2 OH لو بدى
+
+263
+00:23:26,880 --> 00:23:32,540
+اختصره باستعمال برامج الرسم هارسمه بهذا الشكل واحد
+
+264
+00:23:32,540 --> 00:23:36,860
+اتنين تلاتة الان هدوله اش يفهموا كرر رأس يفهم
+
+265
+00:23:37,630 --> 00:23:44,750
+carbon كرر اس يفهم carbon فانا لو شفت هذا المركب و
+
+266
+00:23:44,750 --> 00:23:51,110
+قلت لطالب اقرأ هذا الشكل المفروض هي تقرأه CH3 CH2
+
+267
+00:23:51,110 --> 00:23:58,260
+CH2 OH او مثلا لو شفت مركب زي هذا كل رأس carbon
+
+268
+00:23:58,260 --> 00:24:03,060
+يعني كم carbon عندى في هذا المركب خمس ذرات carbon
+
+269
+00:24:03,060 --> 00:24:09,500
+فيقرأ CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 
+
+270
+00:24:09,500 --> 00:24:09,800
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+271
+00:24:09,800 --> 00:24:10,480
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+272
+00:24:10,480 --> 00:24:10,520
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+273
+00:24:10,520 --> 00:24:14,220
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+274
+00:24:14,220 --> 00:24:14,280
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+275
+00:24:14,280 --> 00:24:15,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+276
+00:24:15,020 --> 00:24:21,380
+CH2 CH2 CH2 بدنا نكون متعودين على معرفة الصيغة
+
+277
+00:24:21,380 --> 00:24:27,240
+الجزائية للمراكبات و حسابها و الروابط المختصرة على
+
+278
+00:24:27,240 --> 00:24:33,120
+طول احنا بمخنا ايش نعمل نجيبها و نحطها خليني
+
+279
+00:24:33,120 --> 00:24:40,450
+اعطيكم خليني أعطيكم مثال إضافي أعطيكم مثال إضافي
+
+280
+00:24:40,450 --> 00:24:49,190
+يعني لو على السريع جربنا مثلا أنه نرسم جزئ زي هيك
+
+281
+00:24:49,190 --> 00:25:02,150
+و هذا الجزئ عملنا فيه ناخد
+
+282
+00:25:02,150 --> 00:25:03,990
+ثانية في الرسم مش مشكلة
+
+283
+00:25:25,060 --> 00:25:30,720
+الان يا تورا هى عندكم جزيق و خلينا نكبره عشان
+
+284
+00:25:30,720 --> 00:25:36,720
+انتوا كلكم تشوفوه لو سألنا هذا الجزيق اللى موجود
+
+285
+00:25:36,720 --> 00:25:41,380
+قدامكم ايش صيغته الجزيقية؟ ايش اللى مبينه؟ ايش
+
+286
+00:25:41,380 --> 00:25:46,250
+اللى مختصر فيه؟ واحدة تقولنا إيه صيغته الجزائية،
+
+287
+00:25:46,250 --> 00:25:54,630
+يعني كام carbon يوجد عندى في هذا الجزء؟ carbon؟
+
+288
+00:25:54,630 --> 00:25:57,270
+كل رأس بالنسبة ليه carbon؟
+
+289
+00:26:00,180 --> 00:26:05,660
+هذا اللي هنا Carbon، إذاً هذا صيرته الجزائية C5،
+
+290
+00:26:05,660 --> 00:26:12,800
+الان الأصعب شوية كم هيدروجين عندى في هذا الجزء
+
+291
+00:26:16,380 --> 00:26:21,680
+كل شي بتكون تكمله حسب ما اتفقنا الكربون لأربع
+
+292
+00:26:21,680 --> 00:26:28,320
+روابط النيتروجين لثلاثة الأكسجل لرابطتين كل ما هو
+
+293
+00:26:28,320 --> 00:26:36,020
+محدوث عبارة عن هيدروجين يعني هنا موجود عندي
+
+294
+00:26:36,020 --> 00:26:43,670
+هيدروجين هنا هيدروجين هنا هيدروجين هناتنتين
+
+295
+00:26:43,670 --> 00:26:47,530
+هيدروجين هنا عشان يصير الكاربون أربع هذه
+
+296
+00:26:47,530 --> 00:26:52,010
+النيتروجين كام رابط مابين عليها تنتين تنتين اذا
+
+297
+00:26:52,010 --> 00:27:04,070
+ينقصها عشان تصير تلت روابط هذه كاربون عدوهم
+
+298
+00:27:04,070 --> 00:27:10,460
+واحد اتنين أنا أكيد بقول الناس اللي بيقولوا رقم
+
+299
+00:27:10,460 --> 00:27:15,700
+مفرد هم الكلام الصح و قدوا انتوا اربع ستة تمانية
+
+300
+00:27:15,700 --> 00:27:26,900
+عشرة احداشر اذا ن ا واضح هي عدد الروابط و بالمناسبة
+
+301
+00:27:26,900 --> 00:27:30,920
+برنامج الرسم بإمكانه يحسب إن الصيغة تبعت هذا
+
+302
+00:27:30,920 --> 00:27:34,780
+المركب يعني لو علمناه كيميستر كالكوليت موليكيلار
+
+303
+00:27:34,780 --> 00:27:39,460
+فاليوز و كالكوليت و قلنا له لزجلنا إياهم هاي
+
+304
+00:27:39,460 --> 00:27:46,920
+الصيغة إيش حسبها البرنامج اقرأوا C5H11NO
+
+305
+00:27:46,920 --> 00:27:52,010
+زي ما احنا كتبناها ولا لأ زي ما احنا كتبناها واضح؟
+
+306
+00:27:52,010 --> 00:27:57,110
+فعندكم انتوا برنامج الرسم موجود بإمكانكوا ترسموا
+
+307
+00:27:57,110 --> 00:28:02,770
+جزيئات زي ما بدكم بإمكانكوا ترسموا جزيئات زي ما
+
+308
+00:28:02,770 --> 00:28:08,110
+بدكم والبرنامج بحسبها وبالتالي بتقدروا تراجعوا
+
+309
+00:28:08,110 --> 00:28:12,110
+لنفسكم يعني حتى لو اجت طالبة قالت انا بدي بدل ما
+
+310
+00:28:12,110 --> 00:28:16,690
+هذه هيدروجين تكون زي هيك الان هذه ايش تصبح؟ carbon
+
+311
+00:28:20,260 --> 00:28:25,990
+هذا الآن تصبح carbon، كل رأس اسمه carbon هذه من
+
+312
+00:28:25,990 --> 00:28:29,530
+الأخطاء الشائعة جدا راجعنا نتبهولها ان احنا لما
+
+313
+00:28:29,530 --> 00:28:32,550
+بنحط رأس زي هيك زي هذا او زي هذا بتيجي الطالب
+
+314
+00:28:32,550 --> 00:28:36,630
+بتكتب عليه hydrogen لأ هذا الرأس يفهم على انه
+
+315
+00:28:36,630 --> 00:28:41,370
+carbon مش hydrogen و بالمناسبة لو بدكم تغلطوا
+
+316
+00:28:41,370 --> 00:28:46,570
+برامج الرسم عادة شاطرة و بتفهمكم يعني لو اجيتوا
+
+317
+00:28:46,570 --> 00:28:49,470
+تحطوا هنا على ال oxygen رابطة ثالثة يعني هذه
+
+318
+00:28:49,470 --> 00:28:54,070
+الرابطة نعص و نحط كمان رابطة لاحظوا إيش كتبلكوا
+
+319
+00:28:54,070 --> 00:28:59,650
+جملة؟ Valence exceeded on atoms زاد الإرتباط على
+
+320
+00:28:59,650 --> 00:29:04,390
+الذرّار، ليش؟ لأنه أنا قاعد بدأ أحط رابطتين هنا و
+
+321
+00:29:04,390 --> 00:29:09,690
+رابطة، قداش المجموع بيصير على ال oxygen، تلاتة
+
+322
+00:29:10,240 --> 00:29:15,300
+بالفعل ولذلك اعطاني اشارة تنبيه انه عدد الارتباط
+
+323
+00:29:15,300 --> 00:29:19,960
+زاد فانتوا في البيت اتعودوا ان عندكم برامج رسم
+
+324
+00:29:19,960 --> 00:29:24,480
+معينة او هذا البرنامج ايضا موجود عندكم بترسموا فيه
+
+325
+00:29:24,480 --> 00:29:28,700
+بتتدربوا كل ما رسمتوا اكتر اتعبتوا اكتر بتتدربوا
+
+326
+00:29:28,700 --> 00:29:33,600
+أكتر على إنكوا تفهموا الأشكال بالشكل السليم، وهذه
+
+327
+00:29:33,600 --> 00:29:38,460
+مشكلة للمن مابتدربش وبيتعب من البداية، بيتغلب
+
+328
+00:29:38,460 --> 00:29:41,020
+أثناء دراسته للمسار
+
+329
+00:29:50,540 --> 00:29:55,560
+هذا بالنسبة للأشكال و كيف نرسمها بأكثر من طريقة و
+
+330
+00:29:55,560 --> 00:30:00,800
+احنا دائما في الكيميا بنفضل اي طرق الطريقة
+
+331
+00:30:00,800 --> 00:30:08,170
+المختصرة و انتوا بتكملوا الحساب في اللي هينكم الان
+
+332
+00:30:08,170 --> 00:30:14,050
+بيجينا برضه من المراجعات شيء متعلق في قطبية
+
+333
+00:30:14,050 --> 00:30:19,890
+الروابط متى تكون الرابطة قطبية و متى يكون الجزء
+
+334
+00:30:19,890 --> 00:30:25,870
+قطبيا، الرابطة بتكون قطبية يعني لها قطب موجب و قطب
+
+335
+00:30:25,870 --> 00:30:31,210
+سالب إذا اختلفت السالبية الـ electronegativity بين
+
+336
+00:30:31,210 --> 00:30:36,450
+الذرتين تعون الرابطة طبعا الذرة الأكثر سالبية تصبح
+
+337
+00:30:36,450 --> 00:30:42,290
+كأنها طرف سالب والأقل سالبية تصبح كأنها طرف موجب
+
+338
+00:30:42,290 --> 00:30:48,770
+وبنعبر عن هذا الكلام بوضع إشارة الشحنة الجزائية
+
+339
+00:30:48,770 --> 00:30:52,930
+بالحق partial positive أو partial negative في
+
+340
+00:30:52,930 --> 00:30:57,110
+عندنا احنا جدول للسالبية اعلى السالبية اللي هي
+
+341
+00:30:57,110 --> 00:31:02,290
+سالبية الفلورين اربعة فمثلا لو كان عندكوا رابطة
+
+342
+00:31:02,290 --> 00:31:08,530
+بين الكاربون والفلورين بهذا الشكل هي كاربون الفلور
+
+343
+00:31:09,820 --> 00:31:14,040
+مين اللي سالبيتها أعلى؟ الـ Floor الـ Floor، إذا أي
+
+344
+00:31:14,040 --> 00:31:17,760
+طرف هيكون سالب؟ الـ Floor أي طرف هيكون موجب؟
+
+345
+00:31:17,760 --> 00:31:23,060
+الـ Carbon وقتها بنحط إشارة القطبية إما بهذا الشكل
+
+346
+00:31:23,060 --> 00:31:28,140
+يفهم إن هذا هو الطرف السالب وهذا هو الطرف الموجب
+
+347
+00:31:28,140 --> 00:31:33,820
+أو بنحطها بإشارة إن الـ Floor بنقول عنه partially
+
+348
+00:31:33,820 --> 00:31:40,020
+negative والـ Carbon partially positive هذا بالنسبة
+
+349
+00:31:40,020 --> 00:31:43,820
+لقطبية الروابط الـ polarity of bonds it depends on
+
+350
+00:31:43,820 --> 00:31:46,820
+the electronegativity difference of the atoms
+
+351
+00:31:46,820 --> 00:31:52,560
+forming this bond بيعتمدوا على فرق السلبية لكن لو
+
+352
+00:31:52,560 --> 00:32:00,860
+مثلا قلنا جزء مثل البرومهل يا ترى هذا الجزء .. هذا
+
+353
+00:32:00,860 --> 00:32:05,900
+الرابط عفوا بين البروم و البروم بتكون قطبية؟ ليش؟
+
+354
+00:32:05,900 --> 00:32:09,780
+لأن هذه السلبية زي هذه السلبية فما بيكون في عنده
+
+355
+00:32:09,780 --> 00:32:17,650
+قطبية بين ذرتين مثل بعضهم تماما او هاي أمثلة كتير
+
+356
+00:32:17,650 --> 00:32:22,010
+بين الهيدروجين والكلور قطبية تعبر عنها بهذا الشكل
+
+357
+00:32:22,010 --> 00:32:25,250
+أو بهذا أو بهذا ال carbon و ال nitrogen ال carbon
+
+358
+00:32:25,250 --> 00:32:29,370
+و ال oxygen كل هذه أمثلة بإمكانكوا ترجعوها واضح أن
+
+359
+00:32:29,370 --> 00:32:34,630
+الذرتين لمكونات للرابطة مختلفات واحدة سلبيتها أكثر
+
+360
+00:32:34,630 --> 00:32:38,490
+هتكون هي الطرف السالب والتانية أقل هتكون هي الطرف
+
+361
+00:32:38,490 --> 00:32:44,270
+الموجب هذا الكلام بينقلنا لقطبية الجزائي الجزائي
+
+362
+00:32:44,270 --> 00:32:49,310
+يتكون من عدة روابط هل الجزائي بمجمله يكون قطبي ولا
+
+363
+00:32:49,310 --> 00:32:55,030
+لأ هذا الكلام بيعتمد على إن نجد المحاصلة لهذه
+
+364
+00:32:55,030 --> 00:33:01,210
+الروابط طبعا أي إنسان بده يوجد محاصلة لازم يفهم
+
+365
+00:33:01,210 --> 00:33:05,950
+الشكل يعني لو أنا قلتلكم هذه الطاولة بيأثر عليها
+
+366
+00:33:05,950 --> 00:33:12,210
+قوتين ما المحاصلة؟ هتقولولي مباشرة احكيلنا كيف شكل
+
+367
+00:33:12,210 --> 00:33:15,610
+القوتين، والله إذا القوتين كانوا من هذه الجهة
+
+368
+00:33:15,610 --> 00:33:20,690
+بيدغطوا، الطاولة هتمشي، هتنجمع القوة الأولى مع
+
+369
+00:33:20,690 --> 00:33:24,150
+القوة التانية، لو القوتين واحدة بهذا الشكل، واحدة
+
+370
+00:33:24,150 --> 00:33:29,930
+من اتجاه المعاكس هيسطبوا بعض إذا لكي أعرف المحصلة
+
+371
+00:33:29,930 --> 00:33:34,130
+لابد إلا أن أعرف الشكل الهندسي والأصل إن هذا موضوع
+
+372
+00:33:34,130 --> 00:33:38,530
+بتتعلموه في الكيميا العامة مش مجالنا الآن إننا
+
+373
+00:33:38,530 --> 00:33:42,350
+ناخد ال geometrical structures لكن خلّيني أخد عدة
+
+374
+00:33:42,350 --> 00:33:46,990
+أمثلة مثلا درسنا إحنا إن الشكل الهندسي لثاني أكسيد
+
+375
+00:33:46,990 --> 00:33:51,810
+الكربون ليليا الآن الأكسجين عندها قطبية أكتر من
+
+376
+00:33:51,810 --> 00:33:56,260
+الكربون بناء ع ذلك لو بدأ احكي عن carbon oxygen
+
+377
+00:33:56,260 --> 00:34:01,840
+bond لها قطبية بهذا الشكلو هذه كمان القطمية بهذا
+
+378
+00:34:01,840 --> 00:34:05,800
+الشكل ايش بتلاعبوا في القطميتين؟ شطبوا بعض فالجزء
+
+379
+00:34:05,800 --> 00:34:09,860
+صار non-polar ال carbon dioxide لايه non-polar
+
+380
+00:34:09,860 --> 00:34:14,460
+بينما لو اجيت للميه، الميه الشكل تبعها ايش ماله؟ V
+
+381
+00:34:14,460 --> 00:34:19,120
+-shaped او bent، منثني الآن، فيه اندهانة قطمية
+
+382
+00:34:19,120 --> 00:34:23,900
+بهذا الشكل وبهذا الشكل هدول قوتين جايين بزاوية
+
+383
+00:34:23,900 --> 00:34:31,010
+المحصلة بتاعتهم وين بتكون؟ بينهم زي هيك هيصف محصلة
+
+384
+00:34:31,010 --> 00:34:39,000
+الجزاء فجزاء الماء يصبح جزاء قطبة واضح؟ لو أخدنا
+
+385
+00:34:39,000 --> 00:34:43,200
+جزء الميثين اللي مكوّن من أربع روابط و هناخد تفصيل
+
+386
+00:34:43,200 --> 00:34:47,420
+الشكل تبعه اللي هو tetrahedral structure بإمكاننا
+
+387
+00:34:47,420 --> 00:34:55,480
+الآن على السريع نعمل شكل لجزء الميثين حتى نتأكد أن
+
+388
+00:34:55,480 --> 00:35:01,380
+هذا الجزء يترى قطبي ولا غير قطبي هاي عندنا جزء
+
+389
+00:35:01,380 --> 00:35:09,510
+الميثين بالشكل ال tetrahedral رباع الأوجه و هدولة
+
+390
+00:35:09,510 --> 00:35:13,690
+اللونهم بوردجاني اللي هم كأنهم بيمثلوا إيش ال
+
+391
+00:35:13,690 --> 00:35:19,570
+hydrogens الآن بهذا الشكل يكون جزء الميثين لو أنا
+
+3
+
+445
+00:39:50,760 --> 00:39:55,840
+different bonding different names طالما الارتباط 
+
+446
+00:39:55,840 --> 00:40:01,060
+اختلف اذا كمان الاسماء هتصير ايش مختلفة فاول ما 
+
+447
+00:40:01,060 --> 00:40:05,800
+بنقول احنا structural isomers بدنا نتذكر ان هدولة 
+
+448
+00:40:05,800 --> 00:40:11,850
+فيهم ارتباط مختلف ولهم اسماء مختلفةالنوع التاني من 
+
+449
+00:40:11,850 --> 00:40:17,450
+ال isomers نوع أصعب شوية ولذلك بندرسه احنا ب 
+
+450
+00:40:17,450 --> 00:40:21,730
+chapter منفصل اللي هو الفصل الخامس من المادة هذه 
+
+451
+00:40:21,730 --> 00:40:27,130
+بنسميه stereo isomers ال stereo isomers الذرات 
+
+452
+00:40:27,130 --> 00:40:31,790
+بتكون لها نفس الارتباط يعني هنا أنا قولت same 
+
+453
+00:40:31,790 --> 00:40:35,270
+different bonding في ال stereo isomers على طول 
+
+454
+00:40:35,270 --> 00:40:40,850
+بقول sameconstitution أو same bonding نفس الارتباط 
+
+455
+00:40:40,850 --> 00:40:46,410
+طب نفس الارتباط هوين بيختلفوا؟ بالشكل بالفراغ ممكن 
+
+456
+00:40:46,410 --> 00:40:51,410
+أشياء يكون لها نفس الارتباط وتختلف بالشكل بالفراغ 
+
+457
+00:40:51,410 --> 00:40:55,690
+الجواب أه بدي أعطيكم مثال من برا الكيميا لما 
+
+458
+00:40:55,690 --> 00:41:00,430
+الطلاب في المدرسة بيجفوا بطابور الصبح هي إيد وجسمه 
+
+459
+00:41:00,430 --> 00:41:06,270
+إيد هذا الارتباط إيش هو؟إيد وجسم وإيد، طب لو عملوا 
+
+460
+00:41:06,270 --> 00:41:12,350
+هيك، هذا الشكل، لو عملوا هيك، هذا الشكل، الآن هل 
+
+461
+00:41:12,350 --> 00:41:16,630
+تغير شيء في الإرتباط؟ إيد وجسم إيد 
+
+462
+00:41:19,410 --> 00:41:22,950
+لو عملوا هيك، طب هدول الأشكال التلاتة، لو أخدت 
+
+463
+00:41:22,950 --> 00:41:27,910
+تلات صور و حاطيتهم قدام الطالب وسألته ما العلاقة 
+
+464
+00:41:27,910 --> 00:41:31,990
+بين هدول التلات صور، هيقول لي ال same bonding، 
+
+465
+00:41:31,990 --> 00:41:36,150
+مافكتش ولا إيد من إيدين البني آدم، نفس الإرتباط، 
+
+466
+00:41:36,150 --> 00:41:40,720
+طب أين الاختلاف؟بالشكل الفراغي إذا اللي بيميز ال 
+
+467
+00:41:40,720 --> 00:41:45,060
+stereo isomers ال atoms have the same bonding the 
+
+468
+00:41:45,060 --> 00:41:48,400
+same constitution بط different arrangement in 
+
+469
+00:41:48,400 --> 00:41:52,320
+space لكن شكلهم بالفراغ بختلف طبعا هنتوسع فيهم 
+
+470
+00:41:52,320 --> 00:41:56,220
+نلاحظ أنه في منهم نوع اسمه اناشو مارس و نوع اسمه 
+
+471
+00:41:56,220 --> 00:42:01,340
+استيريو مارس كل هذا التوسع بيكون بفصل كامل اللي هو 
+
+472
+00:42:01,340 --> 00:42:07,570
+الفصلالخامس ابهيك ابننهي اليوم و إلى لقاء آخر ان 
+
+473
+00:42:07,570 --> 00:42:07,950
+شاء الله 
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..66f7c165203597f427c94457ea613da8b2ab0469
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_postprocess.srt
@@ -0,0 +1,2200 @@
+1
+00:00:20,770 --> 00:00:26,070
+بسم الله الرحمن الرحيم المرة الماضية بدأنا معكم في
+
+2
+00:00:26,070 --> 00:00:30,810
+الفصل الثاني بونوان ال alkanes and cycloalkanes
+
+3
+00:00:30,810 --> 00:00:37,130
+ربما حكينا فكرة في البداية عن تصنيفات ال alkanes
+
+4
+00:00:37,130 --> 00:00:41,350
+أو ال hydrocarbons ل saturated alkanes بقولنا
+
+5
+00:00:41,350 --> 00:00:46,350
+هدولة نوعين اللي همالالكينز والسايكلوالكينز و
+
+6
+00:00:46,350 --> 00:00:50,110
+unsaturated hydrocarbons اللي منها المراكبات اللي
+
+7
+00:00:50,110 --> 00:00:52,470
+فيها double bond و triple bond في الالكينز
+
+8
+00:00:52,470 --> 00:00:59,290
+والالكاينز بدنا نتعرف على الالكينز وقلنا هذه سلاسل
+
+9
+00:00:59,290 --> 00:01:05,200
+وممكن أن تكون مراكباتمتفرعة وهذا يؤدي الى تكون عدد
+
+10
+00:01:05,200 --> 00:01:11,340
+كبير جدا من ال isomers او المتشكلات ال isomers زى
+
+11
+00:01:11,340 --> 00:01:16,780
+ما اتفقنا فى ال alkanes بتبدأ تظهر وقتاش لما بنصل
+
+12
+00:01:16,780 --> 00:01:20,080
+لاربع ذرات كربون يعنى لو عندنا ذرة كربون واحدة
+
+13
+00:01:20,080 --> 00:01:24,480
+عندنا مركب واحد فقط ميثين بعدين ايثين بروبين هذا
+
+14
+00:01:24,480 --> 00:01:28,900
+منه مركب واحد لكن لما ابدي اجى احط اربع ذرات كربون
+
+15
+00:01:28,900 --> 00:01:34,130
+ارتبهمصار في عنده احتمالين لترتيبهم اما ان يرتبوا
+
+16
+00:01:34,130 --> 00:01:39,850
+بشكل متسلسل chain structure و بيكون اسم المركب
+
+17
+00:01:39,850 --> 00:01:45,210
+بيوتين او بشكل branch و بيكون اسم المركب ايزو
+
+18
+00:01:45,210 --> 00:01:48,770
+بيوتين و اتكلمنا بعد هيك عن البنتين انه بيكون
+
+19
+00:01:48,770 --> 00:01:53,930
+تلاتة isomers و بعد ذلك اعطيناكم واجب انكوا تجربوا
+
+20
+00:01:53,930 --> 00:02:00,170
+انتوا تتعبوا و ترسموا الخمسةstructures of hexane
+
+21
+00:02:00,170 --> 00:02:06,010
+والمفروض يكون الأمر بالنسبة لكم مش صعب كثير انه
+
+22
+00:02:06,010 --> 00:02:10,830
+تجيبوا 6 ذرات كربون تجربوا ما لم تعملوا هذا الأمر
+
+23
+00:02:10,830 --> 00:02:14,230
+بالإيد و بالجلم لرصاص و بالورق و تتعبوا فيه كثير
+
+24
+00:02:14,230 --> 00:02:20,770
+مابفيدش ان انا اعمله بكل الأحوال هذه وجفنا
+
+25
+00:02:20,770 --> 00:02:26,630
+اخر شي عند ال structure ofميثين وقولنا ان الميثين
+
+26
+00:02:26,630 --> 00:02:32,290
+ماخد الـ tetrahedral structure اللي له أربعة أوجه
+
+27
+00:02:32,290 --> 00:02:38,390
+وهذا أفضل شئ نتعامل معه نرسمه بسهولة اننا نعمله
+
+28
+00:02:38,390 --> 00:02:41,810
+بالشكل اللي موجود بين اديكم تخيل انه عندنا مستويين
+
+29
+00:02:41,960 --> 00:02:48,200
+مستوى أفقي للأمام ومستوى متعامد عليه للخلف هذا
+
+30
+00:02:48,200 --> 00:02:51,960
+المستوى الأفقي للأمام بيكون فيه ذارتين هيدروجين في
+
+31
+00:02:51,960 --> 00:02:56,880
+زاوية 109.5 والمستوى الخلفي أيضا في ذارتين
+
+32
+00:02:56,880 --> 00:03:02,320
+هيدروجينبزاوية 109.5، الآن باقي الزاوية أيضًا 109
+
+33
+00:03:02,320 --> 00:03:05,940
+.5، يعني لو واحد .. لو واحدة بدأ تاخد بين هذه
+
+34
+00:03:05,940 --> 00:03:08,260
+الهيدروجين اللي في المستوى الأمامي و اللي في
+
+35
+00:03:08,260 --> 00:03:14,100
+المستوى الخلفي و انقيس الزاوية 109.5اللي اتوقفنا
+
+36
+00:03:14,100 --> 00:03:19,020
+عنده كيف يرسم هذا الشكل بالفراغ كيف يرسم هذا الشكل
+
+37
+00:03:19,020 --> 00:03:23,860
+بالفراغ قولنا أفضل شيء أنه نرسمه بهذه الطريقة
+
+38
+00:03:23,860 --> 00:03:29,920
+نستعمل ال wedges أو الأسافير بحيث أنه الأشياء اللي
+
+39
+00:03:29,920 --> 00:03:34,400
+للأمام عادة بنعملها ب solid wedge و الأشياء اللي
+
+40
+00:03:34,400 --> 00:03:39,360
+للخلف عادة بنعملها ب dashed wedgeواضح؟ وهذا اللي
+
+41
+00:03:39,360 --> 00:03:43,860
+موجود عندنا الان اذا احنا بندقيق شوية في هذا الشكل
+
+42
+00:03:43,860 --> 00:03:49,360
+هنلاحظ ان الوجه له رأس head و له base قاعدة
+
+43
+00:03:49,360 --> 00:03:56,250
+القاعدة اللي هي عريضة زي هذه و الرأساللي بيكون
+
+44
+00:03:56,250 --> 00:04:02,030
+رفيع هل يا ترى هناك معنى لما انا اجي ارسم مثلا هذا
+
+45
+00:04:02,030 --> 00:04:07,370
+solid wedge تكون القاعدة فيه على جهة الهيدروجين و
+
+46
+00:04:07,370 --> 00:04:11,650
+الرأس على جهة الكاربون لما اجي ارسم ورا ال dashed
+
+47
+00:04:11,650 --> 00:04:16,690
+wedge تكون القاعدة على جهة الكاربون و الرأس على
+
+48
+00:04:16,690 --> 00:04:22,210
+جهة الهيدروجين هذا الكلام بالتأكيد له معنى شو
+
+49
+00:04:22,210 --> 00:04:27,730
+معنى؟ هذا تعبير عنالرسم في الفراغ دائما احنا
+
+50
+00:04:27,730 --> 00:04:32,070
+متعودين .. دائما احنا متعودين ان الشغلة اللى بتكون
+
+51
+00:04:32,070 --> 00:04:37,590
+قريبة علينا كبيرة بتبين كل ما بعدت عننا بتبين ايش
+
+52
+00:04:37,590 --> 00:04:41,150
+صغيرة يعني الناس اللى بيشوفوا الطائرة في المطار
+
+53
+00:04:41,150 --> 00:04:46,710
+طيارة كبيرة بتاخد خمسمية راكب واضح؟ لما بتبعد كتير
+
+54
+00:04:46,710 --> 00:04:53,610
+في السماء بتشوفوا الطائرة نقطة فكل شيء قريب علينا
+
+55
+00:04:54,670 --> 00:05:00,010
+كبير كلما بقعد صغر حتى لو انتوا بترسموا شارع مثلا
+
+56
+00:05:00,010 --> 00:05:02,950
+متعودين انكوا تقولوا هاي الإنسان هنا اللي بترسم
+
+57
+00:05:02,950 --> 00:05:09,970
+الشارع يبدأ الشارع عريض و كل ما بيبعد بيصير إيش؟
+
+58
+00:05:10,790 --> 00:05:16,210
+يصغر الان هذه الأشياء أيضا تعبير عن هذا الأمر يعني
+
+59
+00:05:16,210 --> 00:05:20,590
+لو انا امسكت هذا الشكل زي هيك هاي اللي موجودين في
+
+60
+00:05:20,590 --> 00:05:25,670
+المستوى الأفقي الان ايش القريب عليكم ذرات
+
+61
+00:05:25,670 --> 00:05:31,710
+الهيدروجين و كل ما بتروحوا على الكاربون بتبتعدوا
+
+62
+00:05:32,390 --> 00:05:38,870
+واضح و لذلك الوجه لما رسمناه خلناه عريض من عند
+
+63
+00:05:38,870 --> 00:05:43,430
+الهيدروجين و كل ما راح الكربون بيبعد بيصير ماخد
+
+64
+00:05:43,430 --> 00:05:49,690
+ايش؟ رأس المثلث فلاحظوا قريب و بيبعد عشان هيك
+
+65
+00:05:49,690 --> 00:05:55,830
+رسمناه عريض و بيصغر لو اجيت على الهيدروجين اللي في
+
+66
+00:05:55,830 --> 00:06:01,480
+الخلفأيش القريب عليكم اكثر ال carbon ولا ال
+
+67
+00:06:01,480 --> 00:06:05,580
+hydrogen؟ ال carbon و كل ما بتروحوا باتجاه ال
+
+68
+00:06:05,580 --> 00:06:12,000
+hydrogen بتبعدوا و لذلك هذا قريب بيبتعد، اذا ال
+
+69
+00:06:12,000 --> 00:06:18,780
+wedge تبعه سيبدأ كبيرامن عند الكربون و يصغر فلو
+
+70
+00:06:18,780 --> 00:06:23,900
+رسمت هذا بشكل معاكس بتكونوا بتعملوا غلط وهذا بيصير
+
+71
+00:06:23,900 --> 00:06:28,120
+جزء لما بترسموا أشكال دائما الشيء القريب عليكم
+
+72
+00:06:28,120 --> 00:06:32,280
+اعملوا الوجه تبعه قاعدته باتجاهكم و كل ما بيبعد
+
+73
+00:06:32,280 --> 00:06:39,000
+بيصغر واضح هذه الفكرة فهذا أمر يجب ان ينتبه له شكل
+
+74
+00:06:39,000 --> 00:06:44,200
+الوجه اللي للأمام و اللي للخلف الان ابتيجي نقطة
+
+75
+00:06:44,200 --> 00:06:50,590
+كثير مهمةلما احنا اضطرنا اضطرارا نرسم الشكل بهذه
+
+76
+00:06:50,590 --> 00:06:55,830
+الطريقة ليش؟ لأنه في اللوح مافيش إمكانية لشيء
+
+77
+00:06:55,830 --> 00:07:00,490
+الفراغي يعني مافيش عندي إمكانية أطلع هدول للأمام و
+
+78
+00:07:00,490 --> 00:07:06,090
+أرجع هدول للخلف فهذه الرسمة غير حقيقية الآن لما
+
+79
+00:07:06,090 --> 00:07:10,310
+باجي بقولكوا بدي أقيس الزوايا مابتكونش تقيسوا
+
+80
+00:07:10,310 --> 00:07:15,560
+الزوايا على أساس الشكلاللي مبين عندكم تقيسوها على
+
+81
+00:07:15,560 --> 00:07:20,120
+أساس الشكل الفراغي اللي موجود في ذهنكم ولذلك لما
+
+82
+00:07:20,120 --> 00:07:25,420
+أقول الزاوية بين الهيدروجين والكاربون والهيدروجين
+
+83
+00:07:25,420 --> 00:07:36,470
+على الرسمة مبينة 180180 لكن هي حقيقة جديش 109.5
+
+84
+00:07:36,470 --> 00:07:40,990
+كذلك الحال لو جيت قلتلكوا بدي الزاوية بين
+
+85
+00:07:40,990 --> 00:07:46,430
+الهيدروجين والكاربون والهيدروجين الآن على الرسمة
+
+86
+00:07:47,810 --> 00:07:54,230
+الزاوية كانت 180 لكنها حقيقة 109.5 فلو كنت معلم
+
+87
+00:07:54,230 --> 00:07:59,870
+بالأزرق و قلت له اكتبوا الزاوية ستكتبوها 109.5 مش
+
+88
+00:07:59,870 --> 00:08:06,040
+180 مابناش نخلط هذه الغلطةلو تخيلنا القاعدة ايضا
+
+89
+00:08:06,040 --> 00:08:11,680
+لو انا اجيت قلتلكم بدي الزاوية بين هذه الهيدروجين
+
+90
+00:08:11,680 --> 00:08:15,440
+اللي في المستوى الأفقي وهذه الهيدروجين الخلفية
+
+91
+00:08:15,440 --> 00:08:22,980
+الان هدولة هنا انبينين تسعين لكن هم حقيقة مية
+
+92
+00:08:22,980 --> 00:08:28,000
+وتسعة و نص ايضا واضح؟
+
+93
+00:08:29,450 --> 00:08:35,470
+فيجب الانتباه لهذا الأمر أن هذا الشكل ليس في مستوى
+
+94
+00:08:35,470 --> 00:08:40,630
+واحد وانما شكل في الفراغ وعندما تحدد الزوايا تبعته
+
+95
+00:08:40,630 --> 00:08:44,790
+يجب أن تحدد من الذهن تبعكه اللي اتعلم ان جميع
+
+96
+00:08:44,790 --> 00:08:50,970
+زوايا الـ tetrahedral structure قيمتها 109.5 كل
+
+97
+00:08:50,970 --> 00:08:55,970
+ذرة بعيدة عن التانيةمن خلال الكربون بزاوية 109.5
+
+98
+00:08:55,970 --> 00:09:03,410
+لا في زاوية شكل الميثين 90 ولا في زاوية 180 جميع
+
+99
+00:09:03,410 --> 00:09:07,510
+زاوية هيدروجين كربون هيدروجين من أي جهة بتاخدوها
+
+100
+00:09:07,510 --> 00:09:15,430
+قيمتها 109.5 هذا
+
+101
+00:09:15,430 --> 00:09:22,950
+بالنسبة لشكل الميثينإذا رجعنا لهذه ال slide اللي
+
+102
+00:09:22,950 --> 00:09:26,150
+اتكلمنا فيها عن ال الكانز بالتفصيل المميل قلنا
+
+103
+00:09:26,150 --> 00:09:30,690
+عندنا ميثين إيثين بروبين لحد البيوتين صار في عندنا
+
+104
+00:09:30,690 --> 00:09:36,330
+كام مركب اتنين الآن هدول بنسميهم الكانز من ال
+
+105
+00:09:36,330 --> 00:09:41,350
+الكانز بنطلع شغلة بنقولها ال kilogram لو يا ترى
+
+106
+00:09:41,350 --> 00:09:45,730
+احنا في نيتنا أنه بدنا نعمل تفاعل لما بدنا نعمل
+
+107
+00:09:45,730 --> 00:09:51,350
+التفاعل أول شيء أول شيء بدنا نعملهإنه بدنا نشيل
+
+108
+00:09:51,350 --> 00:09:58,870
+ذرة هيدروجين مثلا عشان نحط مكانها ذرة كلور الآن
+
+109
+00:09:58,870 --> 00:10:02,990
+لما أنا بشيل هيدروجين من الألكان يعني بدل ما
+
+110
+00:10:02,990 --> 00:10:12,030
+الميثين مثلا CH4 شو بده يصير CH3 وفي مكان سترتبط
+
+111
+00:10:12,030 --> 00:10:15,670
+به الذرة الجديدة نفترض اللي هي ذرة الكلور ممكن
+
+112
+00:10:15,670 --> 00:10:21,400
+نتخيل أنه لونها أخضرالان الالكين ناقص الهيدروجين
+
+113
+00:10:21,400 --> 00:10:27,180
+بسميه الكل جروب دائما الالكين ناقص الهيدروجين الكل
+
+114
+00:10:27,180 --> 00:10:32,520
+جروب فمن الميثين بطول مجموعة بسميها ايش مثل يعني
+
+115
+00:10:32,520 --> 00:10:40,940
+بستبدل ال N ب Y L بدل مثل N بصير مثل جروب دائما كل
+
+116
+00:10:41,530 --> 00:10:46,570
+نهاية اسم او شغلة فيها ال YL فانا بحكي عن الكلجروب
+
+117
+00:10:46,570 --> 00:10:52,330
+يعني ال cane مخصوم منه ذرة هيدروجين واضح؟ الان
+
+118
+00:10:52,330 --> 00:10:57,450
+لاحظوا لو هذه الذرة اتيت اعمل مركب طبعا المثل
+
+119
+00:10:57,450 --> 00:11:02,730
+مجموعة لكن لا تكون مركب يعني انا لما اخص منها
+
+120
+00:11:02,730 --> 00:11:07,290
+هيدروجينمباشرة مكانها الهيدروجين شو هتيجي تحط
+
+121
+00:11:07,290 --> 00:11:12,550
+اكلور نفترض الان لو كونت هذا المركب و بدي اعطيه
+
+122
+00:11:12,550 --> 00:11:19,010
+اسم باجي بسأل هذه المجموعة شو اسمها مثل وفي عند
+
+123
+00:11:19,010 --> 00:11:24,910
+اكلور فبقول المركب مثل اكلورايدبصير في ال common
+
+124
+00:11:24,910 --> 00:11:29,510
+nomenclature يعني التسمية المشهورة انه انا لو هنا
+
+125
+00:11:29,510 --> 00:11:34,110
+شيلت hydrogen و افترض و حطيت chlorine ايش هاسم
+
+126
+00:11:34,110 --> 00:11:41,070
+المركب اللي عندى مثل chloride هذه التسميةبنقول
+
+127
+00:11:41,070 --> 00:11:44,890
+عنها احنا ايش common nomenclature، ايش يعني
+
+128
+00:11:44,890 --> 00:11:49,350
+common؟ تسمية مشهورة، مش تسمية حسب القواعد، هناخد
+
+129
+00:11:49,350 --> 00:11:52,890
+نوعين من التسمية، في تسمية بنسميها IUPAC
+
+130
+00:11:52,890 --> 00:11:56,820
+Nomenclatureالتسمية لحسب القواعد اللي بنتعلمها
+
+131
+00:11:56,820 --> 00:12:00,620
+الآن وفيكم ال nomenclature التسمية المشهورة الان
+
+132
+00:12:00,620 --> 00:12:05,620
+التسمية المشهورة في مثل هذه المراكبات كيف بتتم من
+
+133
+00:12:05,620 --> 00:12:11,140
+خلال ذكر اسم المجموعة و بعد هيك بذكر اسم الهالوجين
+
+134
+00:12:11,140 --> 00:12:15,480
+فمن ال مثل لما شيلت هيدروجين صارت مثل حطيت بدلها
+
+135
+00:12:15,480 --> 00:12:20,380
+كلوه بيصير المراكب مثل كلورايد لو حطيت بدلها بروم
+
+136
+00:12:21,110 --> 00:12:27,190
+مثل البروميد و هكذا واضح؟ الان بنفس المنطق لو اجيت
+
+137
+00:12:27,190 --> 00:12:32,770
+على الاثين كام هيدروجين في الاثين بالمجمل؟ ستة
+
+138
+00:12:32,770 --> 00:12:37,170
+لاحظوا الست ذرات هيدروجين اللي في الاثين كلهم زي
+
+139
+00:12:37,170 --> 00:12:40,990
+بعض متكافئات يعني لو شيلت اي واحدة منهم هعمل
+
+140
+00:12:40,990 --> 00:12:47,670
+مجموعة شو هسميها؟ اثل زي ما انا شيلت من الميثين من
+
+141
+00:12:47,670 --> 00:12:53,840
+الأربع المتكافئات هدولةهيدروجينة وسميت المجموعة
+
+142
+00:12:53,840 --> 00:12:58,860
+مثل بقدر انا من ال اثين ايضا اشيل هيدروجينة الست
+
+143
+00:12:58,860 --> 00:13:01,880
+هيدروجينات زي بعض اي واحدة بنشيلها بتعطينا نفس
+
+144
+00:13:01,880 --> 00:13:07,080
+المجموعة هنكون مجموعة اثل لو افترضنا هذه المجموعة
+
+145
+00:13:07,080 --> 00:13:10,740
+مكان الهيدروجين اللي شيلناها حطينا كلور شو هيصير
+
+146
+00:13:10,740 --> 00:13:18,440
+مثلا مركبة اثل كلورايد و هكذا طيب لو اجينا بعد هيك
+
+147
+00:13:18,440 --> 00:13:24,620
+للبروبينوقلنا من مركب البروبين بدنا نشيل هيدروجين
+
+148
+00:13:24,620 --> 00:13:32,000
+ونعمل مجموعة بروبين مثل مثل اثان اثل بروبين بروبين
+
+149
+00:13:32,000 --> 00:13:39,000
+بيوتين بيوتل هتلاحظوا انه هيبدأ يصير عندى مشكلة
+
+150
+00:13:39,000 --> 00:13:46,610
+صغيرة انهالبروبين في كام هيدروجين؟ تمانية هي تلاتة
+
+151
+00:13:46,610 --> 00:13:50,870
+و تلاتة زي بعض وفي هنا الهيدروجينتين اللي اتفقنا
+
+152
+00:13:50,870 --> 00:13:56,470
+انه اختصرناهم في الكتابة اذا شكله العام CH3 CH2
+
+153
+00:13:56,470 --> 00:14:02,830
+CH3 تمان هيدروجينات هذولة تمان هيدروجينات كام نوع؟
+
+154
+00:14:04,020 --> 00:14:07,900
+عبارة عن نوعين التلاتة هذول والتلاتة هذول اللي على
+
+155
+00:14:07,900 --> 00:14:12,400
+الطرف زي بعض وهذه اللي موجودين في النص زي بعض فال
+
+156
+00:14:12,400 --> 00:14:16,960
+تمان هيدروجينات تعون لبروبين نوعين ستة زي بعض
+
+157
+00:14:16,960 --> 00:14:21,800
+وتنتين زي بعض لو شيلت أي واحدة من هان او من هان
+
+158
+00:14:21,800 --> 00:14:26,640
+هعمل مجموعة ولو شيلت واحدة من هان هعمل مجموعة
+
+159
+00:14:26,640 --> 00:14:30,880
+ولذلك بتلاحظوا انه لما باجي بشيل هيدروجين من
+
+160
+00:14:30,880 --> 00:14:35,460
+البروبين بعمل مجموعتيناذا شيلت من الطرف وهي جاهز
+
+161
+00:14:35,460 --> 00:14:39,420
+انه يشبك من هنا من هنا خصمة الهيدروجين هذه معناه
+
+162
+00:14:39,420 --> 00:14:44,140
+الكلام هذا بسميها مجموعة البروبيل ولو بدي اشيل من
+
+163
+00:14:44,140 --> 00:14:50,220
+النص بدي تصير ايزو بروبيل فلاحظوا معي لو بعد هيك
+
+164
+00:14:50,220 --> 00:14:56,360
+اجينا نعمل مركب نضيف كلور ممكن ناس يقولوا حطلي
+
+165
+00:14:56,360 --> 00:15:02,420
+كلور هانأو محل الهيدروجين اللي شلتها في الحالة
+
+166
+00:15:02,420 --> 00:15:06,600
+الأولى شو هيصير اسم المُركّب؟ Isopropyl chloride
+
+167
+00:15:06,600 --> 00:15:11,240
+في الحالة التانية إيش هيصير اسم المُركّب؟
+
+168
+00:15:11,240 --> 00:15:13,020
+Isopropyl chloride
+
+169
+00:15:15,840 --> 00:15:20,340
+واضح؟ و لذلك بدكوا تكونوا منتبهين أن التلات
+
+170
+00:15:20,340 --> 00:15:27,720
+كربونات كم ألكين منهم؟ واحد .. كم ألكين؟ واحد اسمه
+
+171
+00:15:27,720 --> 00:15:33,900
+بروبيل .. كم ألكي لجروب؟ تنتين .. اسمهم بروبيل و
+
+172
+00:15:33,900 --> 00:15:38,660
+ايزو بروبيل .. واضح؟هذا الكلام أكيد بحاجة إلى
+
+173
+00:15:38,660 --> 00:15:44,120
+تدريب وحفظ بعد شوية بنجي على أربع ذرات كربون هنقول
+
+174
+00:15:44,120 --> 00:15:50,960
+الأربع ذرات كربون أساسا منهم كم مركب اتنين بيوتين
+
+175
+00:15:50,960 --> 00:15:57,500
+و ايزو بيوتين طب كم الكل جروب منهم؟ بدي أجي أطلع
+
+176
+00:15:57,500 --> 00:16:05,510
+هنا كم هيدروجين عندى؟في البيوتين العادى عشرة تلاتة
+
+177
+00:16:05,510 --> 00:16:10,950
+و اتنين و اتنين و تلاتة الان هدولة المختصرين لو
+
+178
+00:16:10,950 --> 00:16:18,270
+بيناهم بالاحمر وسألنا العشرة هيدروجين هدولة كام
+
+179
+00:16:18,270 --> 00:16:27,350
+نوع كام نوع هدول العشر هيدروجين نوعين كام نوع كداش
+
+180
+00:16:27,350 --> 00:16:34,450
+و كداشستة زي بعض اللي على الطرف والاربعة هدول زي
+
+181
+00:16:34,450 --> 00:16:38,410
+بعض يعني لو شيلت hydrogen من هان او هان او هان او
+
+182
+00:16:38,410 --> 00:16:44,130
+هدول نفس الاشي هيعطيني مجموعة اش اسمها الـbutyl
+
+183
+00:16:44,130 --> 00:16:48,190
+ولو شيلت اي واحدة من هدول الاربعة هادي او هادي او
+
+184
+00:16:48,190 --> 00:16:52,030
+هادي او هادي كأن بكون شيلت عن موقع اتنين يعني من
+
+185
+00:16:52,030 --> 00:16:55,490
+هان او من هان بشيل عن موقع واحد من هان او من هان
+
+186
+00:16:55,490 --> 00:17:02,320
+بشيل عن موقع اتنينصار عندى من نفس البيوتين العادى
+
+187
+00:17:02,320 --> 00:17:08,340
+كام مجموعة؟ تنتين واحدة بسميها butyl واحدة بسميها
+
+188
+00:17:08,340 --> 00:17:12,060
+secondary butyl secondary اللى احنا شيلنا فيها
+
+189
+00:17:12,060 --> 00:17:16,410
+الهيدروجين من carbon 2الـ Butyl اللي شيلنا فيها
+
+190
+00:17:16,410 --> 00:17:21,910
+الهيدروجين من Carbon-1 مرات كتيرة هتلاحظوا إضافة و
+
+191
+00:17:21,910 --> 00:17:26,270
+ممكن تقرؤوها في بعض الكتب أن هذا الـ Butane بيروح
+
+192
+00:17:26,270 --> 00:17:32,850
+و بيحطه قدام حرف الـ N معناه بيوتين عادي المتسلسل
+
+193
+00:17:32,850 --> 00:17:37,530
+فالـ N هذي جاية من كلمة إيش؟ Normal لـ Butane
+
+194
+00:17:37,530 --> 00:17:41,270
+العادي و المجموعة تبعته هتلاحظوا مرات بيحطوا
+
+195
+00:17:41,270 --> 00:17:46,390
+قدامها حرف الـ Nفإذا قرأنا بيوتين هو نفسه
+
+196
+00:17:46,390 --> 00:17:51,270
+الانبيوتين المتسلسل وإذا قرأنا المجموعة بيوتين هي
+
+197
+00:17:51,270 --> 00:17:55,770
+نفسها الانبيوتين يعني البيوتين العادية اللي من نمر
+
+198
+00:17:55,770 --> 00:18:01,690
+واحد منها شيلنا ذرة إيش الهيدروجين الآن لو حطينا
+
+199
+00:18:01,690 --> 00:18:06,300
+هنا كلور شو هتسمي المركب؟Butylic chloride طب لو
+
+200
+00:18:06,300 --> 00:18:11,440
+حطينا هنا secondary butylic chloride الان لو اجينا
+
+201
+00:18:11,440 --> 00:18:15,120
+على ال isomers التانى اللى من اربع كربونات اللى
+
+202
+00:18:15,120 --> 00:18:21,640
+اسمه ايش ايزو بيوتين و سألنا كام هيدروجين فيه اكيد
+
+203
+00:18:21,640 --> 00:18:27,900
+عشرة لأنه التنين C4H10 طيب اللى مبينين تسعة وين
+
+204
+00:18:27,900 --> 00:18:34,190
+العاشرةالمختصرة هنا عشان يكتمل الشكل الان هدول
+
+205
+00:18:34,190 --> 00:18:41,090
+العشر هيدروجينات كام نوع؟ إذا بتطلع عليهم ممتازة
+
+206
+00:18:41,090 --> 00:18:49,180
+نوعين التسعة هدول زي بعضوهذا الهيدروجين نوع تاني
+
+207
+00:18:49,180 --> 00:18:52,680
+لأن هذا على الطرف وهذا على الطرف وهذا على الطرف
+
+208
+00:18:52,680 --> 00:18:57,020
+وهذا جاء في قلب الجزء فهذه نوع و هذول التسعة زي
+
+209
+00:18:57,020 --> 00:19:01,440
+بعض بناء على ذلك لو شيلنا أي واحدة من هذول هنعمل
+
+210
+00:19:01,440 --> 00:19:09,160
+مجموعةماذا نسمي المجموعة؟ انظروا معي هنا CH3 CH
+
+211
+00:19:09,160 --> 00:19:12,920
+CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+212
+00:19:12,920 --> 00:19:13,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+213
+00:19:13,020 --> 00:19:13,200
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+214
+00:19:13,200 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+215
+00:19:13,560 --> 00:19:15,980
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+216
+00:19:15,980 --> 00:19:20,860
+CH2 CH2 CH2 CH2 CH2والعدد كله أربعة إذا هذه
+
+217
+00:19:20,860 --> 00:19:27,200
+المجموعة إيش اسمها Isobutyl هذه المجموعة اسمها
+
+218
+00:19:27,200 --> 00:19:30,680
+Isobutyl اللي شيلنا فيها هيدروجين سواء من هنا أو
+
+219
+00:19:30,680 --> 00:19:36,160
+من هنا أو من هنا هي Iso هذا الشكل بيعني Iso هذا
+
+220
+00:19:36,160 --> 00:19:40,120
+التفرع كاربون طالع منها مجموعتين مثل Iso لاحظوا
+
+221
+00:19:40,120 --> 00:19:46,290
+هنا كان عندكم تقريبا نفس الاشي انتبهوا معيcarbon
+
+222
+00:19:46,290 --> 00:19:50,190
+منها مجموعتين مثل شو قلنا ايزو العدد الكلي لل
+
+223
+00:19:50,190 --> 00:19:56,810
+carbons كم كان تلاتة ولذلك سمناها ايزو بروبل الان
+
+224
+00:19:56,810 --> 00:20:01,790
+carbon طالع منها مجموعتين مثل ايزو و العدد الكلي
+
+225
+00:20:01,790 --> 00:20:08,630
+اربعة اذا صارت ايزوبيوتل لو الان بدى اقولها واحدة
+
+226
+00:20:08,630 --> 00:20:13,050
+طيب ال ISO pentel مثلا او ال ISO hexel بتقدر
+
+227
+00:20:13,050 --> 00:20:21,410
+ترسمها اه ع طول بقول هي ال ISO CH3 CH3
+
+228
+00:20:21,410 --> 00:20:26,290
+CH3 الان هكذا صار عندى ISO لو قولت ISO pentel جداش
+
+229
+00:20:26,290 --> 00:20:33,220
+بدى يكون عندى خمسة خمسة اذا بدي كمان هنا CH2CH2 و
+
+230
+00:20:33,220 --> 00:20:37,100
+من هنا شيلت الهيدروجين خليني هادي مثلا لو حطيت
+
+231
+00:20:37,100 --> 00:20:41,720
+كلور هنا كل
+
+232
+00:20:41,720 --> 00:20:51,680
+المركب ايش حيصير ايزو اربعة خمسة بنتل اكلورايد لو
+
+233
+00:20:51,680 --> 00:20:59,960
+حطيت الكلور هنا ايزو بيتل اكلورايد واضح بهذا الشكل
+
+234
+00:20:59,960 --> 00:21:00,300
+بيكون
+
+235
+00:21:03,730 --> 00:21:08,510
+جزء ال ISO التلاتة هدول، الآن إذا بس صفيت عليهم
+
+236
+00:21:08,510 --> 00:21:13,470
+بقول ISO Propyl، زيدت Carbon؟ ISO Butyl، زيدت
+
+237
+00:21:13,470 --> 00:21:17,810
+Carbon؟ ISO Bentyl، الآن هنا بدكوا تنتبهوا، إذا
+
+238
+00:21:17,810 --> 00:21:23,250
+كان عندي شئ بينتهي بالنهاية YL، بحكي عن مجموعة،
+
+239
+00:21:23,250 --> 00:21:28,110
+إذا كان عندي شئ بينتهي بالنهاية N؟بحكي عن ال cane
+
+240
+00:21:28,110 --> 00:21:34,110
+يعني مثلا لو قلنا لطالبة بدنا رسمة ال ISO أكتين
+
+241
+00:21:34,110 --> 00:21:42,950
+اتخيلوا أجاكوا في الامتحان بدي ISO أكتين بتغلبش
+
+242
+00:21:42,950 --> 00:21:49,970
+مباشرة ال ISO كيف شكلها CH3 CH3
+
+243
+00:21:50,800 --> 00:21:56,600
+الان هى صار عندى جزء ال ISO بدي اكمل ل ألكين كم
+
+244
+00:21:56,600 --> 00:22:01,280
+carbon بدى يصير المجموع الكله تمانية اذا هى تلاتة
+
+245
+00:22:01,280 --> 00:22:09,160
+اربعة خمسة ستة سبعة تمانية وهنا بكتب ايش CH3 مش
+
+246
+00:22:09,160 --> 00:22:15,190
+شايل ولا هيدروجينه منه ليش لأنه نهاية N الكينلكن
+
+247
+00:22:15,190 --> 00:22:19,130
+لو كنت بدي الـ iso-octal group من وين هشيل
+
+248
+00:22:19,130 --> 00:22:25,890
+الهيدروجينة؟ من هذه الأخيرة واضح؟ الآن إذا هاي تسع
+
+249
+00:22:25,890 --> 00:22:28,410
+هيدروجينات زي بعض لو شيلت منهم هيدروجينة بطلّق
+
+250
+00:22:28,410 --> 00:22:33,370
+مجموعة isobutyl طب لو شيلت هيدروجين من النص بطلّق
+
+251
+00:22:33,370 --> 00:22:38,270
+مجموعة فيها ذرة الكاربون هذه متصلة بتلت مجموعات
+
+252
+00:22:38,270 --> 00:22:46,250
+CH3 بنسميها tertiarybutylTertiarybutyl مرات
+
+253
+00:22:46,250 --> 00:22:51,210
+بيكتبوا ترت اختصارا و مرات بيحطوا T يعني ممكن
+
+254
+00:22:51,210 --> 00:22:59,700
+تلاقوا Tبيوتل أو تيرت بيوتل تيرتشار بيوتل في كل
+
+255
+00:22:59,700 --> 00:23:04,080
+الأحوال لما نحتاج نشوف هذه الأشياء من ناحية
+
+256
+00:23:04,080 --> 00:23:08,680
+alphabetical أي حرف اللي بنعتمده لأنه بعد شوية لما
+
+257
+00:23:08,680 --> 00:23:13,500
+نسمي المراكبات يلزمنا الترتيب ال alphabetical
+
+258
+00:23:13,500 --> 00:23:19,200
+لبيوتل حتى لو كنتي بتاعة بيوتل هي حرف إيشالـ
+
+259
+00:23:19,200 --> 00:23:23,400
+secondary butyl حرف بيه، ال tertiary butyl حرف
+
+260
+00:23:23,400 --> 00:23:30,960
+بيه، ال isobutyl حرف I، ال isobutyl حرف I مش حرف
+
+261
+00:23:30,960 --> 00:23:36,520
+بيهواضح ال isobutyl لو قلتلكوا alphabetically ايش
+
+262
+00:23:36,520 --> 00:23:40,760
+اول اشي باعتمدوا فيها I لكن tertiary butyl باهمل
+
+263
+00:23:40,760 --> 00:23:45,340
+ال T وتعامل على انه حرف الأول B من ناحية
+
+264
+00:23:45,340 --> 00:23:50,720
+alphabetical و لو حطينا هنا Chlor في شغلات مرات مش
+
+265
+00:23:50,720 --> 00:23:55,780
+بحاجة لفهم بحاجة انكم تحفظوها زي هيك تمام يعني مش
+
+266
+00:23:55,780 --> 00:23:58,600
+قصة tertiary butyl alphabetically
+
+267
+00:24:00,680 --> 00:24:09,180
+B Isobutyl خلصنا واضح؟
+
+268
+00:24:09,180 --> 00:24:13,220
+مرات كتير في التسمية في ناس بصروا على ان بعض
+
+269
+00:24:13,220 --> 00:24:17,180
+الأشياء بدهم يفهموها مش كل شيء في التسمية مش كل
+
+270
+00:24:17,180 --> 00:24:22,020
+شيء في التسمية بيفهم يعني لما اجي اقول والله انت
+
+271
+00:24:22,020 --> 00:24:29,660
+اسمك هدا ليش سموكي هدا خلاص هدا خلاصواحدة تيجي
+
+272
+00:24:29,660 --> 00:24:36,640
+تقولي طب ليش سموه بروبين؟ كان سموه نوبا كلين، ليش
+
+273
+00:24:36,640 --> 00:24:43,120
+سموه بروبين؟مش كل شيء في التسمية بالذات أحيانا
+
+274
+00:24:43,120 --> 00:24:46,900
+بتلاقوا إله منطق وقاعدة زي ما أنتوا أهلكوا سموكم
+
+275
+00:24:46,900 --> 00:24:52,280
+واضح؟ زي ما أهلكوا سموكم كان في شيء معين خلهم
+
+276
+00:24:52,280 --> 00:24:58,620
+يسموا مركب معين بنزين كان في شيء معين حادث صديق
+
+277
+00:24:58,620 --> 00:25:04,780
+اللي بيرجع لتاريخ العلوم أحيانا ممكن بلحظة من
+
+278
+00:25:04,780 --> 00:25:11,700
+اللحظات يلاقي هذا الأصلواللي بيرجع لتاريخ الأسماء
+
+279
+00:25:11,700 --> 00:25:16,280
+اللي بيرجع لتاريخ الأسماء ممكن يلاقي أصل لأسماءكم
+
+280
+00:25:16,280 --> 00:25:22,460
+حتى لو أنتم مش عارفينه يعني ممكن لمن ولدتوا كان
+
+281
+00:25:22,460 --> 00:25:26,860
+متوفي عامة إلكم اسمها هودا إكراما إليها سموكوا
+
+282
+00:25:26,860 --> 00:25:30,940
+هودا الآن أنا بالنسبة إيه هذه المعلومة؟ مابعرفاش
+
+283
+00:25:30,940 --> 00:25:35,220
+ولذلك خدوا تسمية العناصر مرة بتلاقي العنصر بيقوله
+
+284
+00:25:35,220 --> 00:25:41,090
+مسمى على اسم مدينةمر على اسم بني آدم اللي اكتشفه،
+
+285
+00:25:41,090 --> 00:25:46,550
+مر على اسم كذا، فأصل الاسم قد لا نعرفه، قد يكون له
+
+286
+00:25:46,550 --> 00:25:52,930
+أصل، لكن احنا ايش؟ ما بنعرفوش، الأن بالنسبة لنا
+
+287
+00:25:52,930 --> 00:25:58,990
+هذه سيارة مرسيدس، اسم، لكن يا تورا لو أعطيتكوا
+
+288
+00:25:58,990 --> 00:26:02,170
+واجب، ليش سموا ال مرسيدس مرسيدس؟
+
+289
+00:26:05,190 --> 00:26:10,310
+فتشوا عليه و هتقولي الجواب المرة الجاية هتلاحظوا
+
+290
+00:26:10,310 --> 00:26:15,530
+إنه إله اسم ومسمى على اسم واحدة وكذا إله أصل بس مش
+
+291
+00:26:15,530 --> 00:26:18,150
+كتير بهمن الأصل في لحظة من لحظات بلاش نضيع وقت
+
+292
+00:26:18,150 --> 00:26:24,610
+كتير الآن هذه المجموعات يجب أن تتدربوا عليها يجب
+
+293
+00:26:24,610 --> 00:26:29,810
+أنكم تحفظوها بشكل جيد هذا الكلام كيف بيجي بالتدريب
+
+294
+00:26:29,810 --> 00:26:33,490
+كيف بيجي بالتدريب الآن
+
+295
+00:26:34,940 --> 00:26:39,940
+بعد ما أخدنا ال الكانز البسيطة و ال alkyl groups
+
+296
+00:26:39,940 --> 00:26:45,120
+البسيطة بدنا ناخد تسمية ال الكانز بال IUPAC system
+
+297
+00:26:45,120 --> 00:26:50,360
+حتى لو كبرت و صارت متفرعة واضح؟ يعني تسمية ال
+
+298
+00:26:50,360 --> 00:26:54,340
+الكانز الكبيرة اللي مامرتش علينا بال IUPAC system
+
+299
+00:26:54,730 --> 00:27:00,050
+ال ايوبك سيستم بيعتمد على ان نبحث عن اطول سلسلة
+
+300
+00:27:00,050 --> 00:27:05,330
+كربونية و اسم عليها يعني لو اطول سلسلة تلاتة نهاية
+
+301
+00:27:05,330 --> 00:27:11,110
+الاسم عندى ابروبين لو اربعة بيوتين تمانية اكتيل
+
+302
+00:27:12,590 --> 00:27:17,830
+فالشيء الأول بيقولنا choose the largest continuous
+
+303
+00:27:17,830 --> 00:27:23,090
+chain الان رجاء ماحدش يفهم السلسلة أن انتوا
+
+304
+00:27:23,090 --> 00:27:28,550
+بتكونوا تشوفوها مرسومة عدل بشكل أفقي أو بشكل عمودي
+
+305
+00:27:28,550 --> 00:27:33,350
+هذا الشيء ليس له معنى أنها تكون أفقي أو عمودي أو
+
+306
+00:27:33,350 --> 00:27:38,740
+مائلة معنى سلسلةذرات كربون ورا بعض بأي طريقة انا
+
+307
+00:27:38,740 --> 00:27:43,180
+ارسمهم هذا الكلام لا معنى له كله ممكن يعني لو بدأ
+
+308
+00:27:43,180 --> 00:27:48,920
+احكي مثلا عن خمسة لو بدأ احكي عن خمسة هذه سلسلة من
+
+309
+00:27:48,920 --> 00:27:59,380
+خمسة تمام وهذه سلسلة من خمسة وممكن ناخد كمان هذه
+
+310
+00:27:59,380 --> 00:28:05,360
+بهذا الشكلسلسلة من الخمسة و ممكن نرسمها بطريقة
+
+311
+00:28:05,360 --> 00:28:12,440
+تانيةسلسلة من خمسة فمعنى سلسلة ذرات متتالية وليس
+
+312
+00:28:12,440 --> 00:28:15,740
+الطريقة المرسومة بعض الناس بيقول سلسلة يعني بيشوفه
+
+313
+00:28:15,740 --> 00:28:21,800
+هيك حسب نظره أفقي أو عمودي لأ لأ معنى سلسلة كام
+
+314
+00:28:21,800 --> 00:28:25,360
+ذرة كربون متتالية فاهمنا إيش معنى سلسلة فلو قولت
+
+315
+00:28:25,360 --> 00:28:29,220
+هنا أما أطول سلسلة واحد اتنين تلاتة أربعة خمسة
+
+316
+00:28:29,220 --> 00:28:33,060
+واحد اتنين تلاتة أربعة خمسة واحد اتنين تلاتة أربعة
+
+317
+00:28:33,060 --> 00:28:36,580
+خمسة واحد اتنين تلاتة أربعة خمسة ابلاحظين مرسومين
+
+318
+00:28:36,580 --> 00:28:43,470
+بطرقمختلفة لكن بالنسبة لي معنى أطول سلسلة أطول عدد
+
+319
+00:28:43,470 --> 00:28:47,870
+متتالي من ذرات الكربون كيف يرتسموا مش مشكلة واضح و
+
+320
+00:28:47,870 --> 00:28:52,010
+لذلك بعد شوية اشوفوا مثلا هذا المركب هين اتكلمت عن
+
+321
+00:28:52,010 --> 00:28:58,190
+سلسلة اللي ماعطيها اللون الأحمر ولو مش مبينة بشكل
+
+322
+00:28:58,190 --> 00:29:04,370
+مستقيم بالنسبة لكم هذا شيء ما لهش معنى الآنحسب
+
+323
+00:29:04,370 --> 00:29:08,130
+أطول سلسلة بيكون اسم المُركّب لو كان عندنا تلاتة
+
+324
+00:29:08,130 --> 00:29:13,050
+نهاية المُركّب ابرو بين خمسة بينتين و هكذا طيب لما
+
+325
+00:29:13,050 --> 00:29:17,370
+بيصير في عندي سلسلة هذه السلسلة أكيد بيتفرع منها
+
+326
+00:29:17,370 --> 00:29:23,010
+شغلات هذه بسميها أنا الأشياء المتفرعة من السلسلة
+
+327
+00:29:23,010 --> 00:29:26,870
+اللي طالعة من أطول سلسلة carbon بقول عنها
+
+328
+00:29:26,870 --> 00:29:31,980
+substituent هذه كلمة هتصير اتمر عليكمكثير
+
+329
+00:29:31,980 --> 00:29:38,040
+Substituents اللي هي الأشياء المبدلة الان كام
+
+330
+00:29:38,040 --> 00:29:43,460
+Substituents على هذا المركب متفرع منه؟ اتنين هدولة
+
+331
+00:29:43,460 --> 00:29:48,920
+ال Substituents لازم انا اوضحهم او اوضح من اي نقطة
+
+332
+00:29:48,920 --> 00:29:53,060
+تفرعوا من اي مكان تفرعوا طب لما هذي بدي اعطيها اسم
+
+333
+00:29:53,060 --> 00:29:57,820
+هعطيها Chloro لما هذي بدي اعطيها اسم هعطيها Abromo
+
+334
+00:29:57,820 --> 00:30:02,830
+بعدين بدي اقول لك Chloro من وين اتفرعت؟من أي موقع
+
+335
+00:30:02,830 --> 00:30:08,690
+لبرومو من وين اتفرعت اذا بالزمن ترقيم لهالسلسلة
+
+336
+00:30:08,690 --> 00:30:12,950
+طالما بحكي سلسلة إذا عندي احتمالين ترقيم ممكن أبدأ
+
+337
+00:30:12,950 --> 00:30:17,770
+من هنا واحد اتنين تلاتة أربعة خمسة أو من هنا واحد
+
+338
+00:30:17,770 --> 00:30:23,130
+اتنين تلاتة أربعة خمسة من أي جهة بدي أبدأ الجهة
+
+339
+00:30:23,130 --> 00:30:26,910
+اللي بتخلي ال substituents أرقامهم أقل ما يمكن
+
+340
+00:30:26,910 --> 00:30:30,230
+يعني لو بدأت من هنا زي ما احنا عاملين ال chlorine
+
+341
+00:30:30,230 --> 00:30:34,280
+على اتنين و ال brom على تلاتة اتنين و تلاتةخمسة لو
+
+342
+00:30:34,280 --> 00:30:38,600
+بدأت منها ان واحد اتنين تلاتة اربعة صارت هذه على
+
+343
+00:30:38,600 --> 00:30:43,840
+تلاتة وهذه على اربعة تلاتة واربعة اذا ماهو اقل
+
+344
+00:30:43,840 --> 00:30:50,900
+ترقيم هذا ولذلك لما بدي ارقم دائما عند احتمالين
+
+345
+00:30:50,900 --> 00:30:56,220
+الاحتمال اللي بدي اختارهالـ lowest possible
+
+346
+00:30:56,220 --> 00:31:00,780
+numbering أقل احتمال بيعطي الـ substituents أرقام
+
+347
+00:31:00,780 --> 00:31:05,640
+طب اعرفنا الأرقام و اعرفنا الآن انه صار عندنا على
+
+348
+00:31:05,640 --> 00:31:13,800
+موقع اتنين ذرة اكلورو مظبوط ولا لأ اكلورو وع موقع
+
+349
+00:31:13,800 --> 00:31:20,410
+تلاتة ذرة ابروموبدي اكتب الاسم كامل الاسم عادة
+
+350
+00:31:20,410 --> 00:31:26,130
+بنبدأ في كتابته من الخلف للامام اول كلمة في الاسم
+
+351
+00:31:26,130 --> 00:31:30,970
+انه عندي خمسة اذا مركبه بنتين يعني اول شي بدي ابدأ
+
+352
+00:31:30,970 --> 00:31:36,070
+اكتبه بنتين هذا البنتين الان بيحمل برومو و كلورو
+
+353
+00:31:36,070 --> 00:31:41,630
+مين بدي اذكره في الاول ال alphabetical اللي بيظهر
+
+354
+00:31:41,630 --> 00:31:47,510
+اولا مين بيجي قبل ال B ولا ال Cالـ B A B C D
+
+355
+00:31:47,510 --> 00:31:51,090
+شوفتوا قبل شوية ليش أنا نبهت كل ال alphabetical في
+
+356
+00:31:51,090 --> 00:31:58,010
+المجموعات أه إذا هذا هيكون three bromo two
+
+357
+00:31:58,010 --> 00:32:03,430
+chlorobentain واضح؟ لأن أنا عندي كام substituent؟
+
+358
+00:32:03,430 --> 00:32:10,670
+هذه و هذه كيف بأذكرهم؟list substituents
+
+359
+00:32:10,670 --> 00:32:15,830
+alphabetically أذكرهم alphabetically أذكر ال B قبل
+
+360
+00:32:15,830 --> 00:32:22,650
+ال C قبل ال D قبل ال E و هكذا طبعا هنا اجتمل الاسم
+
+361
+00:32:22,650 --> 00:32:26,930
+بضيف معلومة أنه لو من مجموعة معينة كان في عندي
+
+362
+00:32:26,930 --> 00:32:33,400
+تنتينبدي أستعمل لمضاي، لو كان في عندي تلاتة ا try،
+
+363
+00:32:33,400 --> 00:32:38,700
+لو عندي أربعة تترى، و هكذا، واضح؟ انشوف أمثلة
+
+364
+00:32:38,700 --> 00:32:46,820
+إضافية، انشوفأمثلة إضافية مثلا هاي مثال أصعب شغلة
+
+365
+00:32:46,820 --> 00:32:52,220
+أنه فعلا طول أطول سلسلة يعني لو إجيت بدي أطول
+
+366
+00:32:52,220 --> 00:32:57,460
+سلسلة ممكن أعد واحد اتنين تلاتة واحد اتنين تلاتة
+
+367
+00:32:57,460 --> 00:33:03,340
+أربعة خمسة واحد اتنين تلاتة أربعة خمسة احتمالات
+
+368
+00:33:03,340 --> 00:33:07,780
+كتيرة بدي أضلني أجرب لحد ما فعلا ألاقي أطول سلسلة
+
+369
+00:33:07,780 --> 00:33:14,930
+واحد اتنين تلاتة أربعة خمسة ستة سبعةإذا مركّب إيش؟
+
+370
+00:33:14,930 --> 00:33:15,730
+هبتين
+
+371
+00:33:23,230 --> 00:33:37,450
+مثل مثل مثل مثل مثل مثل مثل مثل
+
+372
+00:33:46,950 --> 00:33:51,550
+إذا من هنا لازم أرقم فالمثلز اللي عندي وين موجودين
+
+373
+00:33:51,550 --> 00:33:57,350
+على اتنين واربعة هيصير مركبة two four dimethyl
+
+374
+00:33:57,350 --> 00:34:02,850
+heptane two four dimethyl heptane الان هاي مركب
+
+375
+00:34:02,850 --> 00:34:10,610
+تاني بتجارب كتير هتكتشف ان هاي أطول سلسلة سبعة ايش
+
+376
+00:34:10,610 --> 00:34:11,750
+بيتفرع منها
+
+377
+00:34:14,510 --> 00:34:24,070
+هذه المجموعة اللي مرت علينا ايزو بروبل و مثل الان
+
+378
+00:34:24,070 --> 00:34:30,410
+ايزو بروبل حرف I و المثل حرف M و المركب هبتين و I
+
+379
+00:34:30,410 --> 00:34:36,870
+قبل ال M اذا حيصير اسم المركب for aizobrobel انها
+
+380
+00:34:36,870 --> 00:34:38,530
+موجودة على موقع اربعة
+
+381
+00:34:41,630 --> 00:34:46,510
+لاحظوا في كل التسمية لو تطبعوا على الكمبيوتر في أي
+
+382
+00:34:46,510 --> 00:34:54,490
+فراغولا فراغ دائما قبل الرقم وبعد الرقم بتحطه شرطة
+
+383
+00:34:54,490 --> 00:34:58,330
+ما عدا إذا كنا بنحط في أول الإسم بتكون الشرطة فقط
+
+384
+00:34:58,330 --> 00:35:04,170
+بعد الرقم بدون أي فراغات يعني هذا كله متصل بعض
+
+385
+00:35:04,170 --> 00:35:08,830
+كتابة من هنا لهنا مافيش عندي فراغات لو بكتب اسم
+
+386
+00:35:08,830 --> 00:35:14,550
+هذا المركب على الكمبيوتر قبل الرقم شرطة وبعده شرطة
+
+387
+00:35:14,550 --> 00:35:21,380
+ما لم يكن الرقمفي الأول فبس بيكون فيه بعده شرطة
+
+388
+00:35:22,430 --> 00:35:27,630
+الان في عندكم امثلة كتير بإمكانكوا تتدربوا عليها
+
+389
+00:35:27,630 --> 00:35:31,250
+ماعطيكوا انا في الواجبات بالذات في الامتحانات
+
+390
+00:35:31,250 --> 00:35:35,270
+السابقة اللي موجودة عندكم كل امتحان بتلاقي عليه
+
+391
+00:35:35,270 --> 00:35:40,310
+اربع خمس مركبات كيف تسموهم مالم تتدربوا على حفظ
+
+392
+00:35:40,310 --> 00:35:44,890
+أسماء ال الkins على حفظ المجموعات على كيف تسموا
+
+393
+00:35:44,890 --> 00:35:48,970
+مركب مش هتقدروا تطبقوا يعني لازم لو واحد كنتوا
+
+394
+00:35:48,970 --> 00:35:50,210
+تدرسوا و تتدربوا أكثر
+
+395
+00:35:54,510 --> 00:35:58,250
+لأ لأ اعتمدي على اللي احنا بنشرحه بشكل اكبر
+
+396
+00:35:58,250 --> 00:36:02,370
+واعتمدي على الامتحانات الكتيرة اللي موجودة عندكم
+
+397
+00:36:02,370 --> 00:36:08,470
+بتعطيكي اسئلة وافية في الموضوع الآن بنيجي لنقطة
+
+398
+00:36:08,470 --> 00:36:14,350
+خاصة صغيرة بنضيفها في هذا الموضوع أحيانا بنيجي
+
+399
+00:36:14,350 --> 00:36:20,410
+نبحث عن أطول سلسلة بنلاحظ أنه بيطلع عندنا احتمالين
+
+400
+00:36:20,410 --> 00:36:27,520
+مش احتمال واحدمثلا هذا المركب هو نفسه هذا المركب
+
+401
+00:36:27,520 --> 00:36:31,440
+تماما لو بتتطلع عليه يعني احنا رسمنا المركب هذا
+
+402
+00:36:31,440 --> 00:36:36,460
+عملنا له نسخ و لاصق هنا لما نيجي نبحث عن أطول
+
+403
+00:36:36,460 --> 00:36:41,680
+سلسلة عدنا كتير هيقولنا واحد اتنين تلاتة اربعة
+
+404
+00:36:41,680 --> 00:36:47,800
+خمسة ستة سبعة اجت طالبة تانية عدت من هنا واحد
+
+405
+00:36:47,800 --> 00:36:55,600
+اتنين تلاتة اربعة خمسة ستة سبعةطب يا تورا بدي
+
+406
+00:36:55,600 --> 00:37:00,820
+أختار هذه السلسلة و لا بدي أختار هذه السلسلة طلع
+
+407
+00:37:00,820 --> 00:37:05,780
+عندك أكتر من سلسلة سبعة في عندنا قاعدة بتقول if
+
+408
+00:37:05,780 --> 00:37:09,760
+there are two equal along continuous chains يعني
+
+409
+00:37:09,760 --> 00:37:13,180
+لو في عندكوا سلسلتين متساويات في الطول في
+
+410
+00:37:13,180 --> 00:37:16,780
+الاحتمالات ا choose the one with most branches
+
+411
+00:37:16,780 --> 00:37:21,820
+اختار السلسلة اللي فيها تفرعات أكتريعني لو اتطلعت
+
+412
+00:37:21,820 --> 00:37:28,340
+على السلسلة هذه، كم تفرع طالع منها؟ اتنين، شغلتين
+
+413
+00:37:28,340 --> 00:37:31,540
+طالعين منها، لو اتطلعت على السلسلة هذه، كم تفرع
+
+414
+00:37:31,540 --> 00:37:37,980
+طالع منها؟ مجموعة واحدة، واضح؟ هذه طالع منها فقط
+
+415
+00:37:37,980 --> 00:37:42,240
+تفرع واحد، هيو، هنا طالع تفرعين، ابن اختار اللي
+
+416
+00:37:42,240 --> 00:37:47,000
+فيهاتفرعين طبعا لما نختار او ناخد ال lower
+
+417
+00:37:47,000 --> 00:37:51,640
+numbering على نمرة تلاتة في عندي مجموعة CH2 CH3
+
+418
+00:37:51,640 --> 00:37:55,600
+هذه اللي بيقول عنها إثل وعن نمرة اتنين المثل three
+
+419
+00:37:55,600 --> 00:38:00,300
+ethyl two methyl heptane بينما لو واحدة اختارت هذه
+
+420
+00:38:00,300 --> 00:38:04,220
+هتقول heptane على نمرة تلاتة هذه المجموعة
+
+421
+00:38:04,220 --> 00:38:09,520
+isopropyl فهذا الاسم three isopropyl heptane is
+
+422
+00:38:09,520 --> 00:38:14,650
+not a correct nameممكن واحدة في الامتحان تعمله،
+
+423
+00:38:14,650 --> 00:38:18,230
+تعتقد أنها عملت جيدا، في الآخر تتفاجأ أنه غلط
+
+424
+00:38:18,230 --> 00:38:22,670
+بالكامل، ليش؟ لأنها مانتبهتش أنه عندها سلسلتين،
+
+425
+00:38:22,670 --> 00:38:26,690
+ممكن يكونوا سبعة، وأنه لو أخدت من هنا، اللي هي هذه
+
+426
+00:38:26,690 --> 00:38:30,130
+السلسلة، هذه فيها ال most branches، فيها التفرعات
+
+427
+00:38:30,130 --> 00:38:34,390
+الأكثرولذلك اللي بده يشتغل في التسمية بده يكون
+
+428
+00:38:34,390 --> 00:38:39,610
+منتبه أنه فعلا لجأ أطول سلسلة واتأكد أنه مافيش
+
+429
+00:38:39,610 --> 00:38:45,150
+غيرها، لو لجأت إنتين بنفس الطول، بده يختار الأكثر
+
+430
+00:38:45,150 --> 00:38:52,310
+تفرعا، بده يختار السلسلة الأكثر تفرعا، واضح هذا
+
+431
+00:38:52,310 --> 00:39:00,220
+الكلام؟ ممكن نجرب ما أعطيكممثال حتى نشوف انكم
+
+432
+00:39:00,220 --> 00:39:18,060
+أتقنتوا هذا الكلام ولا لا هذا
+
+433
+00:39:18,060 --> 00:39:23,040
+مركب ابدأوا
+
+434
+00:39:23,040 --> 00:39:24,780
+فاكروا فيه وشوفوا
+
+435
+00:39:27,090 --> 00:39:33,530
+أيش أطول سلسلة موجودة فيه و
+
+436
+00:39:33,530 --> 00:39:38,610
+أول ما نعملها بأنصح اكون معاكم قلم فوسفور اتعلموا
+
+437
+00:39:38,610 --> 00:39:44,350
+عليها عشان تقدروا تشوفوا كل ما يتفرع منها واضح؟
+
+438
+00:39:44,350 --> 00:39:49,650
+الآن أكيد هتبدو تعدوا أنتوا واحد تنين تلاتة أربعة
+
+439
+00:39:49,650 --> 00:39:53,310
+أكيد لو قلتوا تلاتة تلاتة أربعة تلاتة أربعة نفس
+
+440
+00:39:53,310 --> 00:40:02,770
+الأشي أوواحد اتنين تلاتة او واحد اتنين تلاتة اربعة
+
+441
+00:40:02,770 --> 00:40:11,370
+خمسة ستة ايش رأيكوا او اي واحدة من هدول هادي زي
+
+442
+00:40:11,370 --> 00:40:14,650
+هادي زي هادي ماهم تلات اطراف واحد اتنين واحد اتنين
+
+443
+00:40:14,650 --> 00:40:22,090
+واحد اتنين اي واحدة بتاخدوها مافيش فيه مشكلة منها
+
+444
+00:40:23,210 --> 00:40:27,150
+أي واحدة من هدولة بيمشي تكون المرة واحدة لأنها
+
+445
+00:40:27,150 --> 00:40:33,650
+وادي وادي زي بعض واحد تانين تلاتة أربعة خمسة ستة
+
+446
+00:40:33,650 --> 00:40:39,630
+سبعة اه الآن هي أطول سلسلة خليني أعلمها و بأنصحكوا
+
+447
+00:40:39,630 --> 00:40:44,630
+لو عندكم طلم فسفور أسفر اتعلموها هي أطول سلسلة
+
+448
+00:40:44,630 --> 00:40:51,050
+عشان نقدر نشوف كام تفرع طالع منها هذه السلسلةاربع
+
+449
+00:40:51,050 --> 00:41:01,330
+انا مع الكلور هذه CH3 وهذه CH3 وهذه CH3 وهنا
+
+450
+00:41:01,330 --> 00:41:06,010
+الكلور اربع تفرعات طالع منها طب لو بدى اعطيها اقل
+
+451
+00:41:06,010 --> 00:41:16,080
+ترقيم من فضل من فضل اكيد واحدتلاتة اربعة خمسة ستة
+
+452
+00:41:16,080 --> 00:41:21,160
+سبعة الان لو بدنا نكتب الاسم كاملا كيف بدنا نبدأ
+
+453
+00:41:21,160 --> 00:41:27,880
+نكتب الاسم؟ من الخلف للامام ايش مركب طالما سبعة؟
+
+454
+00:41:27,880 --> 00:41:35,360
+هبتين الان هذا الهبتين كم نوع من المجموعات يحمل؟
+
+455
+00:41:35,360 --> 00:41:44,910
+نوعين اكلوروومثل ومثل ومثل اتراي مثل اذا هذا حقيقة
+
+456
+00:41:44,910 --> 00:41:54,550
+الـ C في الأول الكلورو اتراي مثل الان الكلورو وين
+
+457
+00:41:54,550 --> 00:42:01,870
+موقعها على نمرة أربعة four شرطة كلورو ال اتراي مثل
+
+458
+00:42:01,870 --> 00:42:10,930
+وين موجودين على اتنينو اتنين و تلاتة لازم احدد
+
+459
+00:42:10,930 --> 00:42:15,330
+تلات ارقام طالما try مثل لازم التلات ارقام بينه
+
+460
+00:42:15,330 --> 00:42:21,090
+اذا هنا فعلا بدي اكتب شرطة اتنين اتنين تلاتة هدف
+
+461
+00:42:21,090 --> 00:42:27,650
+هذا الموقع ان انا اكتبها صح هتكون اتنين اتنين
+
+462
+00:42:27,650 --> 00:42:32,090
+تلاتة try مثل
+
+463
+00:42:37,340 --> 00:42:47,340
+4-chloro-2-2-3-trimethylheptane
+
+464
+00:42:52,160 --> 00:42:56,040
+ماحدش يغلط .. مرات كتير بعض الناس اللي بيحفظوا
+
+465
+00:42:56,040 --> 00:42:59,400
+مجموعات شو الغلط اللي بيجعوا فيه، مابيبحثوش عن
+
+466
+00:42:59,400 --> 00:43:02,480
+أطول سلسلة، بيجوا و بيقولوا اه هذه ال carbon اللي
+
+467
+00:43:02,480 --> 00:43:06,300
+حملة تلت مجموعات tertiary-butyl وهذه السلسلة
+
+468
+00:43:07,580 --> 00:43:11,460
+وبالتالي بيسموه hexane وحمل على نمرة 2 tertiary
+
+469
+00:43:11,460 --> 00:43:16,920
+butyl بالفعش أنا مابخدش أسماء المجموعات إلا بعد ما
+
+470
+00:43:16,920 --> 00:43:23,700
+أحدد أطول سلسلة دائما نمرة واحد حدده أطول سلسلة
+
+471
+00:43:23,700 --> 00:43:28,340
+بعض الناس بيغلط بيجي بيقول لأ هذه تعتبر مجموعة في
+
+472
+00:43:28,340 --> 00:43:32,830
+البداية يعني لو أنا هنا كنت كاتب CH3بروح و بقول
+
+473
+00:43:32,830 --> 00:43:36,210
+ادي مجموعة مثل لأ دي جزء من السلسلة بنفعش اسميها
+
+474
+00:43:36,210 --> 00:43:41,110
+مجموعة هذه من الأخطاء الشائع لبعض الناس بيجي بعمل
+
+475
+00:43:41,110 --> 00:43:44,650
+الترقيم من هان و بعدين بيقول على نمر واحد في عندي
+
+476
+00:43:44,650 --> 00:43:50,950
+try مثل .. لأ مش هيك تأخذه لازم أفتش عليه أطول
+
+477
+00:43:50,950 --> 00:43:54,630
+سلسلة و بعدين أشوف إيش في عندي مجموعات حسب ما
+
+478
+00:43:54,630 --> 00:43:59,010
+اتعلمت بأعمل التسمية تبعي
+
+479
+00:44:04,700 --> 00:44:10,980
+هذه تقريبا فكرة عن ال الكنز بشكل عام لو اتكلمنا عن
+
+480
+00:44:10,980 --> 00:44:15,960
+ال physical properties of الكنز هنلاحظ القاتل اول
+
+481
+00:44:15,960 --> 00:44:23,940
+شئ ال الكنز هم water insoluble ليش؟ لان دائما ال
+
+482
+00:44:23,940 --> 00:44:31,440
+الكنز تتذكر انهم non polar والمية polar حسب قاعدة
+
+483
+00:44:31,440 --> 00:44:36,250
+like dissolves likeالالكينز لا يدوبون في المياه
+
+484
+00:44:36,250 --> 00:44:40,590
+ولذلك من هؤلاء الالكينز على سبيل المثال البنزين
+
+485
+00:44:40,590 --> 00:44:44,890
+اللي هو أقود السيارات واضح هل يا تورا هذا بيدوب في
+
+486
+00:44:44,890 --> 00:44:49,090
+المياه ولا بيعمل طبقة تانية بيعمل طبقة تانية هنا
+
+487
+00:44:49,090 --> 00:44:54,810
+خليني أنبه لنقطة خطأ شائعلأنه احنا باللغة العربية
+
+488
+00:44:54,810 --> 00:44:59,330
+بنستعمل كلمة بنزين لما بنعب السيارة بنقول بنزين
+
+489
+00:44:59,330 --> 00:45:05,310
+فناس كتير بيخطئوا و بيفكروا انه احنا بنعب السيارة
+
+490
+00:45:05,310 --> 00:45:09,150
+البنزين هذا اللي مار عليكم اللي هو البنزين العطري
+
+491
+00:45:09,150 --> 00:45:16,230
+هذا الكلام خطأ طب ايش اسم هو بالانجليزي وقود
+
+492
+00:45:16,230 --> 00:45:23,650
+السيارات ال fuel اسمه جازولينأحنا بالعربي هذا
+
+493
+00:45:23,650 --> 00:45:29,390
+الجازولين بنقول عنه بنزين لكن هو حقيقة خليط من
+
+494
+00:45:29,390 --> 00:45:35,870
+الالكينز بشكل أساسي مركبين من الالكينز هو خليط من
+
+495
+00:45:35,870 --> 00:45:40,190
+الهيبتين والايزو
+
+496
+00:45:40,190 --> 00:45:40,710
+أكتين
+
+497
+00:45:43,660 --> 00:45:48,340
+فالجازولين اللي هو وقود السيارات اللي احنا بنعبيه
+
+498
+00:45:48,340 --> 00:45:52,180
+باللغة العربية متعودين نقول عنه بنزين مالوش هذا ال
+
+499
+00:45:52,180 --> 00:45:56,020
+structure ولا له علاقة بهذا ال structure لأ
+
+500
+00:45:56,020 --> 00:46:02,000
+gasoline is a mixture of alkanes الجازولين وقود
+
+501
+00:46:02,000 --> 00:46:05,780
+السيارات اللي بنعبيه هو خليط من ال alkanes شو ما
+
+502
+00:46:05,780 --> 00:46:10,480
+دول ال alkanes؟الهبتين وال ايزو اكتين و بتهيألي
+
+503
+00:46:10,480 --> 00:46:15,020
+اليوم احنا رسمنا شكل الهبتين سبع كربونات و رسمنا
+
+504
+00:46:15,020 --> 00:46:18,900
+شكل ال ايزو اكتين اللي فيه مجموعة ال ايزو و بنكمل
+
+505
+00:46:18,900 --> 00:46:24,500
+لكم كربونات تمانية الان هدولة الكنز لو أخدنا هذا
+
+506
+00:46:24,500 --> 00:46:29,880
+الجازولين وقود السيارات و حطناه فوق ميهبيخلط
+
+507
+00:46:29,880 --> 00:46:34,640
+معاها، بيدوب فيها؟ لأ، فإذا الالكينز they are
+
+508
+00:46:34,640 --> 00:46:39,880
+water insoluble، ليش؟ لأن هدول المركبات، القوة
+
+509
+00:46:39,880 --> 00:46:46,010
+اللي فيهم، London forces، بينما الميهالهيدروجين
+
+510
+00:46:46,010 --> 00:46:52,810
+بوندنج فيها الميّه بولر والالكينز نان بولر فالبولر
+
+511
+00:46:52,810 --> 00:46:57,370
+والنان بولر بخلطوش مع بعض are water insoluble طبعا
+
+512
+00:46:57,370 --> 00:47:02,000
+كونوا القوة اللي موجودة فيهم ضعيفةاللي هي أضعف نوع
+
+513
+00:47:02,000 --> 00:47:05,440
+من القوة الـ London Forces معناه ذلك الجزيئات
+
+514
+00:47:05,440 --> 00:47:10,880
+بتاعتهم ممسوقة ببعضها بقوة ولا بقوة ضعيفة؟ بقوة
+
+515
+00:47:10,880 --> 00:47:16,160
+ضعيفة، هذا بيقدر إلى إنها بتتبخر بشكل سريع وإلى أن
+
+516
+00:47:16,160 --> 00:47:22,000
+نقطة الغليان تبعتها أيضا منخفضة جدا ولذلك لو أنا
+
+517
+00:47:22,000 --> 00:47:25,380
+إجيت اتطلعت على ال canes اللي في الجدول هلاحظ ال
+
+518
+00:47:25,380 --> 00:47:32,540
+methane غازالإيثين غاز، البروبين غاز، البيوتين
+
+519
+00:47:32,540 --> 00:47:36,600
+غاز، اللي هو الغاز المنزلي، غاز الطهي المنزلي، هو
+
+520
+00:47:36,600 --> 00:47:41,740
+البيوتين البنتين بيبدأ يصير سائل بنقطة غليان حوالي
+
+521
+00:47:41,740 --> 00:47:46,500
+36 درجة مؤوية، نقطة غليان منخفضة البنزين نفسه نقطة
+
+522
+00:47:46,500 --> 00:47:49,920
+غليانه منخفضة، ولذلك بيتبقر بسرعة وبيعمل حرائق
+
+523
+00:47:49,920 --> 00:47:56,570
+بسرعةواضح؟ كل هذا الكلام لأن القوة الترابط اللي
+
+524
+00:47:56,570 --> 00:48:01,070
+موجودة فيه هي ال London forces اللي هي أضعف أنواع
+
+525
+00:48:01,070 --> 00:48:05,550
+قوة الترابط فالجزيئات غير مترابطة بقوة و من هنا
+
+526
+00:48:05,550 --> 00:48:10,910
+بيكون ال alkanes لهم low boiling points بالتأكيد
+
+527
+00:48:10,910 --> 00:48:15,720
+ال cane من ذرةنقطة غليانه اقل من ذرتين اقل من
+
+528
+00:48:15,720 --> 00:48:20,460
+تلاتة وكل ما يبدو يزيدوا عدد ذرات الالكين ايش
+
+529
+00:48:20,460 --> 00:48:26,020
+بيصيلا نقطة الغليان بتزيد واضح؟أخر نقطة اليوم
+
+530
+00:48:26,020 --> 00:48:31,560
+بنحكيها أن الالكينز لنفس المركب يعني لنفس العدد
+
+531
+00:48:31,560 --> 00:48:36,580
+الخمسة مثلا ممكن تكون chain متسلسلة و ممكن تكون
+
+532
+00:48:36,580 --> 00:48:39,900
+branched معناة chain مرة تانية أن الخمسة ورا بعض
+
+533
+00:48:39,900 --> 00:48:44,020
+branched هي عندي واحد اتنين تلاتة مثلا في البنتين
+
+534
+00:48:44,020 --> 00:48:49,800
+و من موقع اتنين اعملت تفرعينهنا خمس ذرات وهنا خمس
+
+535
+00:48:49,800 --> 00:48:53,560
+ذرات الخمس هذول جايين إيش؟ ورا بعض بقول عنهم chain
+
+536
+00:48:53,560 --> 00:49:00,140
+compounds هذول برانش دائما بنقول برانش الكنز have
+
+537
+00:49:00,140 --> 00:49:02,840
+lower boiling points than the corresponding long
+
+538
+00:49:02,840 --> 00:49:10,620
+chain of kens يعني هذا و هذا له نفس الصيغة C5H12
+
+539
+00:49:10,620 --> 00:49:17,970
+لكن مين له نقطة غليان أعلى؟الـ Chain أقل ال branch
+
+540
+00:49:17,970 --> 00:49:23,330
+ليش؟ لأن ال branch بيكون عامل زي الكورة الآن
+
+541
+00:49:23,330 --> 00:49:27,990
+تخيلوا لو حطيتوا أنتوا نفسكم تلت كورات هيك فوق بعض
+
+542
+00:49:27,990 --> 00:49:33,130
+بهذا الشكل هل يتورا بينهم مسافات ارتباط قوية كتير؟
+
+543
+00:49:33,130 --> 00:49:37,620
+هاي بس سطح الارتباطواضحة الفكرة؟ فالجزء اللي
+
+544
+00:49:37,620 --> 00:49:42,220
+branched بصير أعمل زي الكورة، الآن الكورات بحطها
+
+545
+00:49:42,220 --> 00:49:45,880
+بشكل تستقر فوق بعض، يعني أنا بقدر أحطها دولة تلاتة
+
+546
+00:49:45,880 --> 00:49:51,610
+فوق بعض ويثبتوا؟ لأليش؟ لأنه مافيش سطح التقاء كبير
+
+547
+00:49:51,610 --> 00:49:55,730
+بينهم ولذلك الـbranched alkanes they have lower
+
+548
+00:49:55,730 --> 00:49:59,170
+boiling points than the corresponding long chain
+
+549
+00:49:59,170 --> 00:50:03,210
+alkanes هذه مبادئ عامة بال physical properties
+
+550
+00:50:03,210 --> 00:50:06,090
+للالكنز وبهيك بننهي اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..0bc2fc225acaaa5ba7d8b247a9640a6c2c15948f
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4313, "start": 20.77, "end": 43.13, "text": "بسم الله الرحمن الرحيم المرة الماضية بدأنا معكم في الفصل الثاني بونوان ال alkanes and cycloalkanes ربما حكينا فكرة في البداية عن تصنيفات ال alkanes أو ال hydrocarbons ل saturated alkanes بقولنا هدولة نوعين اللي هم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 10721, 8315, 20449, 24793, 8978, 27188, 36520, 6024, 104, 7649, 1829, 4724, 2407, 1863, 2407, 7649, 2423, 419, 5225, 279, 293, 38154, 752, 667, 12779, 12602, 3555, 15042, 11331, 4117, 1829, 8315, 6156, 4117, 25720, 8978, 29739, 28259, 10632, 18871, 6055, 9381, 22653, 5172, 9307, 2423, 419, 5225, 279, 34051, 2423, 15435, 6166, 33568, 5296, 25408, 419, 5225, 279, 4724, 39648, 8315, 8032, 3215, 12610, 3660, 8717, 45367, 9957, 13672, 1829, 8032, 2304], "avg_logprob": -0.16573034109694235, "compression_ratio": 1.7040816326530612, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 20.77, "end": 21.13, "word": "بسم", "probability": 0.924072265625}, {"start": 21.13, "end": 21.31, "word": " الله", "probability": 0.97021484375}, {"start": 21.31, "end": 21.65, "word": " الرحمن", "probability": 0.97314453125}, {"start": 21.65, "end": 22.11, "word": " الرحيم", "probability": 0.9921875}, {"start": 22.11, "end": 23.57, "word": " المرة", "probability": 0.897216796875}, {"start": 23.57, "end": 24.15, "word": " الماضية", "probability": 0.9879557291666666}, {"start": 24.15, "end": 24.97, "word": " بدأنا", "probability": 0.732666015625}, {"start": 24.97, "end": 25.53, "word": " معكم", "probability": 0.80859375}, {"start": 25.53, "end": 26.07, "word": " في", "probability": 0.9140625}, {"start": 26.07, "end": 26.71, "word": " الفصل", "probability": 0.9462890625}, {"start": 26.71, "end": 27.27, "word": " الثاني", "probability": 0.957763671875}, {"start": 27.27, "end": 27.87, "word": " بونوان", "probability": 0.6443359375}, {"start": 27.87, "end": 28.03, "word": " ال", 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والسايكلوالكينز و unsaturated hydrocarbons اللي منها المراكبات اللي فيها double bond و triple bond في الالكينز والالكاينز بدنا نتعرف على الالكينز وقلنا هذه سلاسل وممكن أن تكون مراكبات", "tokens": [6027, 6027, 4117, 9957, 11622, 16070, 3794, 47302, 28820, 2407, 6027, 4117, 9957, 11622, 4032, 2693, 19493, 770, 15435, 6166, 33568, 13672, 1829, 9154, 11296, 9673, 23557, 4117, 3555, 9307, 13672, 1829, 8978, 11296, 3834, 6086, 4032, 15508, 6086, 8978, 2423, 6027, 4117, 9957, 11622, 16070, 6027, 4117, 995, 9957, 11622, 47525, 8315, 8717, 2655, 3615, 28480, 15844, 2423, 6027, 4117, 9957, 11622, 4032, 4587, 1211, 8315, 29538, 8608, 15040, 3794, 1211, 4032, 2304, 43020, 14739, 6055, 30544, 3714, 23557, 4117, 3555, 9307], "avg_logprob": -0.232886902987957, "compression_ratio": 1.768361581920904, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 44.53, "end": 45.370000000000005, "word": "الالكينز", "probability": 0.672509765625}, {"start": 45.370000000000005, "end": 46.21, "word": " 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1033.7, "text": "صار عندى من نفس البيوتين العادى كام مجموعة؟ تنتين واحدة بسميها butyl واحدة بسميها secondary butyl secondary اللى احنا شيلنا فيها الهيدروجين من carbon 2", "tokens": [9381, 9640, 43242, 7578, 9154, 8717, 36178, 2423, 21292, 35473, 9957, 18863, 18513, 7578, 9122, 10943, 3714, 7435, 2304, 2407, 27884, 22807, 6055, 29399, 9957, 36764, 24401, 3660, 4724, 38251, 1829, 11296, 457, 5088, 36764, 24401, 3660, 4724, 38251, 1829, 11296, 11396, 457, 5088, 11396, 13672, 7578, 1975, 5016, 8315, 13412, 26895, 8315, 8978, 11296, 2423, 3224, 25708, 2288, 29245, 9957, 9154, 5954, 568], "avg_logprob": -0.20252403846153846, "compression_ratio": 1.528301886792453, "no_speech_prob": 0.0, "words": [{"start": 1018.22, "end": 1018.76, "word": "صار", "probability": 0.65234375}, {"start": 1018.76, "end": 1019.64, "word": " عندى", "probability": 0.82666015625}, {"start": 1019.64, "end": 1019.9, "word": " من", "probability": 0.91455078125}, {"start": 1019.9, "end": 1020.38, "word": " نفس", 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{"start": 1050.93, "end": 1051.47, "word": " عادي", "probability": 0.9152018229166666}, {"start": 1051.47, "end": 1052.85, "word": " المتسلسل", "probability": 0.951904296875}, {"start": 1052.85, "end": 1053.53, "word": " فالـ", "probability": 0.81787109375}, {"start": 1053.53, "end": 1053.67, "word": " N", "probability": 0.8642578125}, {"start": 1053.67, "end": 1053.99, "word": " هذي", "probability": 0.6044921875}, {"start": 1053.99, "end": 1054.25, "word": " جاية", "probability": 0.8958333333333334}, {"start": 1054.25, "end": 1054.41, "word": " من", "probability": 0.9775390625}, {"start": 1054.41, "end": 1054.85, "word": " كلمة", "probability": 0.9866536458333334}, {"start": 1054.85, "end": 1055.59, "word": " إيش؟", "probability": 0.70220947265625}, {"start": 1055.59, "end": 1056.31, "word": " Normal", "probability": 0.6435546875}, {"start": 1056.31, "end": 1057.07, "word": " لـ", "probability": 0.378662109375}, {"start": 1057.07, "end": 1057.53, "word": " Butane", "probability": 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{"start": 1077.47, "end": 1078.93, "word": " ذرة", "probability": 0.81787109375}, {"start": 1078.93, "end": 1079.41, "word": " إيش", "probability": 0.8738606770833334}, {"start": 1079.41, "end": 1080.59, "word": " الهيدروجين", "probability": 0.8826497395833334}, {"start": 1080.59, "end": 1081.13, "word": " الآن", "probability": 0.5479736328125}, {"start": 1081.13, "end": 1081.27, "word": " لو", "probability": 0.96435546875}, {"start": 1081.27, "end": 1081.69, "word": " حطينا", "probability": 0.816162109375}, {"start": 1081.69, "end": 1081.91, "word": " هنا", "probability": 0.67626953125}, {"start": 1081.91, "end": 1082.27, "word": " كلور", "probability": 0.6287841796875}, {"start": 1082.27, "end": 1082.47, "word": " شو", "probability": 0.679443359375}, {"start": 1082.47, "end": 1082.83, "word": " هتسمي", "probability": 0.78253173828125}, {"start": 1082.83, "end": 1083.73, "word": " المركب؟", "probability": 0.8721923828125}], "temperature": 1.0}, {"id": 47, "seek": 110852, "start": 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هشيل الهيدروجينة؟ من هذه الأخيرة واضح؟ الآن إذا هاي تسع هيدروجينات زي بعض لو شيلت منهم هيدروجينة بطلّق مجموعة isobutyl طب لو شيلت هيدروجين من النص بطلّق مجموعة فيها ذرة الكاربون هذه متصلة بتلت مجموعات CH3 بنسميها tertiarybutyl", "tokens": [1211, 19452, 45164, 9122, 29399, 4724, 16254, 2423, 39184, 307, 78, 12, 78, 349, 304, 1594, 9154, 4032, 9957, 8032, 8592, 26895, 2423, 3224, 25708, 2288, 29245, 9957, 3660, 22807, 9154, 29538, 16247, 9778, 48923, 4032, 46958, 5016, 22807, 6024, 48506, 11933, 15730, 8032, 47302, 6055, 3794, 3615, 8032, 25708, 2288, 29245, 9957, 9307, 30767, 1829, 45030, 11242, 45164, 13412, 26895, 2655, 9154, 16095, 8032, 25708, 2288, 29245, 9957, 3660, 4724, 9566, 1211, 11703, 4587, 3714, 7435, 2304, 2407, 27884, 307, 996, 325, 5088, 23032, 3555, 45164, 13412, 26895, 2655, 8032, 25708, 2288, 29245, 9957, 9154, 28239, 9381, 4724, 9566, 1211, 11703, 4587, 3714, 7435, 2304, 2407, 27884, 8978, 11296, 29910, 25720, 33251, 9640, 3555, 11536, 29538, 44650, 36520, 3660, 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"probability": 0.9646484375}, {"start": 1358.27, "end": 1359.15, "word": " CH3", "probability": 0.96484375}, {"start": 1359.15, "end": 1361.29, "word": " بنسميها", "probability": 0.9158935546875}, {"start": 1361.29, "end": 1363.35, "word": " tertiarybutyl", "probability": 0.7918701171875}], "temperature": 1.0}, {"id": 59, "seek": 137289, "start": 1364.11, "end": 1372.89, "text": "Tertiarybutyl مرات بيكتبوا ترت اختصارا و مرات بيحطوا T يعني ممكن تلاقوا T", "tokens": [51, 911, 29104, 5955, 5088, 3714, 2288, 9307, 4724, 1829, 4117, 2655, 3555, 14407, 6055, 43500, 1975, 46456, 9381, 9640, 995, 4032, 3714, 2288, 9307, 4724, 1829, 5016, 9566, 14407, 314, 37495, 22653, 3714, 43020, 6055, 15040, 4587, 14407, 314], "avg_logprob": -0.2705792682926829, "compression_ratio": 1.202020202020202, "no_speech_prob": 0.0, "words": [{"start": 1364.11, "end": 1365.55, "word": "Tertiarybutyl", "probability": 0.5654296875}, {"start": 1365.55, "end": 1366.25, "word": " مرات", "probability": 0.73974609375}, {"start": 1366.25, "end": 1366.87, "word": " بيكتبوا", "probability": 0.8538411458333334}, {"start": 1366.87, "end": 1367.37, "word": " ترت", "probability": 0.58935546875}, {"start": 1367.37, "end": 1369.13, "word": " اختصارا", "probability": 0.92109375}, {"start": 1369.13, "end": 1369.21, "word": " و", "probability": 0.9169921875}, {"start": 1369.21, "end": 1369.51, "word": " مرات", "probability": 0.9010416666666666}, {"start": 1369.51, "end": 1369.99, "word": " بيحطوا", "probability": 0.79814453125}, {"start": 1369.99, "end": 1370.21, "word": " T", "probability": 0.5380859375}, {"start": 1370.21, "end": 1370.89, "word": " يعني", "probability": 0.859619140625}, {"start": 1370.89, "end": 1371.21, "word": " ممكن", "probability": 0.9736328125}, {"start": 1371.21, "end": 1372.25, "word": " تلاقوا", "probability": 0.8638916015625}, {"start": 1372.25, "end": 1372.89, "word": " T", "probability": 0.7119140625}], "temperature": 1.0}, {"id": 60, "seek": 139772, "start": 1374.5, "end": 1397.72, "text": "بيوتل أو تيرت بيوتل تيرتشار بيوتل في كل الأحوال لما نحتاج نشوف هذه الأشياء من ناحية alphabetical أي حرف اللي بنعتمده لأنه بعد شوية لما نسمي المراكبات يلزمنا الترتيب ال alphabetical لبيوتل حتى لو كنتي بتاعة بيوتل هي حرف إيش", "tokens": [3555, 1829, 35473, 1211, 34051, 6055, 13546, 2655, 4724, 1829, 35473, 1211, 6055, 13546, 2655, 8592, 9640, 4724, 1829, 35473, 1211, 8978, 28242, 16247, 5016, 2407, 6027, 5296, 15042, 8717, 33753, 26108, 8717, 8592, 38688, 29538, 16247, 8592, 1829, 16606, 9154, 8717, 39319, 10632, 23339, 804, 36632, 11331, 28480, 13672, 1829, 44945, 34268, 2304, 3215, 3224, 5296, 33456, 3224, 39182, 13412, 2407, 10632, 5296, 15042, 8717, 38251, 1829, 9673, 23557, 4117, 3555, 9307, 7251, 1211, 11622, 2304, 8315, 16712, 2288, 31371, 3555, 2423, 23339, 804, 5296, 21292, 35473, 1211, 11331, 49975, 45164, 9122, 29399, 1829, 39894, 995, 27884, 4724, 1829, 35473, 1211, 39896, 11331, 28480, 11933, 1829, 8592], "avg_logprob": -0.20541857688798817, "compression_ratio": 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"end": 1382.16, "word": " نشوف", "probability": 0.9606119791666666}, {"start": 1382.16, "end": 1382.64, "word": " هذه", "probability": 0.8740234375}, {"start": 1382.64, "end": 1383.26, "word": " الأشياء", "probability": 0.9921875}, {"start": 1383.26, "end": 1383.62, "word": " من", "probability": 0.98779296875}, {"start": 1383.62, "end": 1384.08, "word": " ناحية", "probability": 0.9835611979166666}, {"start": 1384.08, "end": 1385.16, "word": " alphabetical", "probability": 0.767578125}, {"start": 1385.16, "end": 1385.72, "word": " أي", "probability": 0.71826171875}, {"start": 1385.72, "end": 1386.08, "word": " حرف", "probability": 0.996337890625}, {"start": 1386.08, "end": 1386.26, "word": " اللي", "probability": 0.91357421875}, {"start": 1386.26, "end": 1387.34, "word": " بنعتمده", "probability": 0.9494140625}, {"start": 1387.34, "end": 1388.04, "word": " لأنه", "probability": 0.7615559895833334}, {"start": 1388.04, "end": 1388.2, "word": " بعد", "probability": 0.87841796875}, {"start": 1388.2, "end": 1388.48, "word": " شوية", "probability": 0.9475911458333334}, {"start": 1388.48, "end": 1388.68, "word": " لما", "probability": 0.974609375}, {"start": 1388.68, "end": 1389.04, "word": " نسمي", "probability": 0.9025065104166666}, {"start": 1389.04, "end": 1389.78, "word": " المراكبات", "probability": 0.848828125}, {"start": 1389.78, "end": 1391.98, "word": " يلزمنا", "probability": 0.87216796875}, {"start": 1391.98, "end": 1392.48, "word": " الترتيب", "probability": 0.9267578125}, {"start": 1392.48, "end": 1392.6, "word": " ال", "probability": 0.876953125}, {"start": 1392.6, "end": 1393.5, "word": " alphabetical", "probability": 0.92724609375}, {"start": 1393.5, "end": 1394.78, "word": " لبيوتل", "probability": 0.834228515625}, {"start": 1394.78, "end": 1395.66, "word": " حتى", "probability": 0.87451171875}, {"start": 1395.66, "end": 1395.84, "word": " لو", "probability": 0.99267578125}, {"start": 1395.84, "end": 1396.14, "word": " كنتي", "probability": 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1405.0, "word": " isobutyl", "probability": 0.72674560546875}, {"start": 1405.0, "end": 1405.58, "word": " حرف", "probability": 0.98681640625}, {"start": 1405.58, "end": 1407.4, "word": " I،", "probability": 0.616943359375}, {"start": 1407.4, "end": 1407.8, "word": " ال", "probability": 0.77392578125}, {"start": 1407.8, "end": 1408.8, "word": " isobutyl", "probability": 0.968994140625}, {"start": 1408.8, "end": 1409.18, "word": " حرف", "probability": 0.98974609375}, {"start": 1409.18, "end": 1409.62, "word": " I", "probability": 0.990234375}, {"start": 1409.62, "end": 1410.58, "word": " مش", "probability": 0.482421875}, {"start": 1410.58, "end": 1410.96, "word": " حرف", "probability": 0.84033203125}, {"start": 1410.96, "end": 1411.36, "word": " بيه", "probability": 0.8932291666666666}], "temperature": 1.0}, {"id": 62, "seek": 143860, "start": 1412.18, "end": 1438.6, "text": "واضح ال isobutyl لو قلتلكوا alphabetically ايش اول اشي باعتمدوا فيها I لكن tertiary butyl باهمل ال T وتعامل على انه حرف الأول B من ناحية alphabetical و لو حطينا هنا Chlor في شغلات مرات مش بحاجة لفهم بحاجة انكم تحفظوها زي هيك تمام يعني مش قصة tertiary butyl alphabetically", "tokens": [2407, 46958, 5016, 2423, 307, 996, 325, 5088, 45164, 12174, 1211, 2655, 23275, 14407, 23339, 984, 1975, 1829, 8592, 1975, 12610, 1975, 8592, 1829, 4724, 995, 34268, 2304, 3215, 14407, 8978, 11296, 286, 44381, 38726, 29104, 457, 5088, 4724, 995, 16095, 1211, 2423, 314, 34683, 3615, 10943, 1211, 15844, 16472, 3224, 11331, 28480, 16247, 12610, 363, 9154, 8717, 39319, 10632, 23339, 804, 4032, 45164, 11331, 9566, 1829, 8315, 34105, 761, 6746, 8978, 13412, 17082, 1211, 9307, 3714, 2288, 9307, 37893, 4724, 5016, 26108, 3660, 5296, 5172, 16095, 4724, 5016, 26108, 3660, 16472, 24793, 6055, 5016, 5172, 19913, 2407, 11296, 30767, 1829, 39896, 4117, 6055, 15042, 2304, 37495, 22653, 37893, 12174, 9381, 3660, 38726, 29104, 457, 5088, 23339, 984], "avg_logprob": -0.20824579331053406, "compression_ratio": 1.6374501992031874, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1412.18, "end": 1412.72, "word": "واضح", "probability": 0.9381510416666666}, {"start": 1412.72, "end": 1413.4, "word": " ال", "probability": 0.38037109375}, {"start": 1413.4, "end": 1414.44, "word": " isobutyl", "probability": 0.6898193359375}, {"start": 1414.44, "end": 1414.82, "word": " لو", "probability": 0.71533203125}, {"start": 1414.82, "end": 1415.34, "word": " قلتلكوا", "probability": 0.8015625}, {"start": 1415.34, "end": 1416.3, "word": " alphabetically", "probability": 0.888671875}, {"start": 1416.3, "end": 1416.52, "word": " ايش", "probability": 0.8338216145833334}, {"start": 1416.52, "end": 1416.8, "word": " اول", "probability": 0.860107421875}, {"start": 1416.8, "end": 1417.06, "word": " اشي", "probability": 0.8984375}, {"start": 1417.06, "end": 1417.68, "word": " باعتمدوا", "probability": 0.8527018229166666}, {"start": 1417.68, "end": 1418.1, "word": " فيها", "probability": 0.977783203125}, {"start": 1418.1, 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"word": " مش", "probability": 0.9873046875}, {"start": 1430.72, "end": 1431.26, "word": " بحاجة", "probability": 0.9935302734375}, {"start": 1431.26, "end": 1431.64, "word": " لفهم", "probability": 0.9163411458333334}, {"start": 1431.64, "end": 1432.08, "word": " بحاجة", "probability": 0.9334716796875}, {"start": 1432.08, "end": 1432.3, "word": " انكم", "probability": 0.546630859375}, {"start": 1432.3, "end": 1433.22, "word": " تحفظوها", "probability": 0.8865559895833334}, {"start": 1433.22, "end": 1433.52, "word": " زي", "probability": 0.94921875}, {"start": 1433.52, "end": 1434.04, "word": " هيك", "probability": 0.94970703125}, {"start": 1434.04, "end": 1435.24, "word": " تمام", "probability": 0.7560221354166666}, {"start": 1435.24, "end": 1435.58, "word": " يعني", "probability": 0.6561279296875}, {"start": 1435.58, "end": 1435.78, "word": " مش", "probability": 0.90283203125}, {"start": 1435.78, "end": 1436.18, "word": " قصة", "probability": 0.8986002604166666}, {"start": 1436.18, "end": 1436.92, "word": " tertiary", "probability": 0.90625}, {"start": 1436.92, "end": 1437.42, "word": " butyl", "probability": 0.91259765625}, {"start": 1437.42, "end": 1438.6, "word": " alphabetically", "probability": 0.9404296875}], "temperature": 1.0}, {"id": 63, "seek": 146818, "start": 1440.68, "end": 1468.18, "text": "B Isobutyl خلصنا واضح؟ مرات كتير في التسمية في ناس بصروا على ان بعض الأشياء بدهم يفهموها مش كل شيء في التسمية مش كل شيء في التسمية بيفهم يعني لما اجي اقول والله انت اسمك هدا ليش سموكي هدا خلاص هدا خلاص", "tokens": [33, 286, 539, 5955, 5088, 16490, 1211, 9381, 8315, 4032, 46958, 5016, 22807, 3714, 2288, 9307, 9122, 2655, 13546, 8978, 16712, 38251, 10632, 8978, 8717, 32277, 4724, 9381, 2288, 14407, 15844, 16472, 45030, 11242, 16247, 8592, 1829, 16606, 47525, 16095, 7251, 5172, 16095, 2407, 11296, 37893, 28242, 44049, 38207, 8978, 16712, 38251, 10632, 37893, 28242, 44049, 38207, 8978, 16712, 38251, 10632, 4724, 33911, 16095, 37495, 22653, 5296, 15042, 1975, 7435, 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بروبين؟", "tokens": [14407, 24401, 3660, 6055, 1829, 7435, 1829, 6055, 39648, 1829, 23032, 3555, 32239, 8592, 8608, 2304, 2407, 3224, 4724, 32887, 3555, 9957, 22807, 25961, 8608, 2304, 2407, 3224, 8717, 37746, 995, 28242, 9957, 12399, 32239, 8592, 8608, 2304, 2407, 3224, 4724, 32887, 3555, 9957, 22807], "avg_logprob": -0.21484374676061713, "compression_ratio": 1.5647058823529412, "no_speech_prob": 0.0, "words": [{"start": 1469.0, "end": 1469.46, "word": "واحدة", "probability": 0.7802734375}, {"start": 1469.46, "end": 1469.66, "word": " تيجي", "probability": 0.9635009765625}, {"start": 1469.66, "end": 1470.1, "word": " تقولي", "probability": 0.8821614583333334}, {"start": 1470.1, "end": 1470.52, "word": " طب", "probability": 0.785400390625}, {"start": 1470.52, "end": 1470.78, "word": " ليش", "probability": 0.962646484375}, {"start": 1470.78, "end": 1471.2, "word": " سموه", "probability": 0.9208984375}, {"start": 1471.2, "end": 1473.42, "word": " بروبين؟", "probability": 0.658251953125}, 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يختار السلسلة الأكثر تفرعا، واضح هذا الكلام؟ ممكن نجرب ما أعطيكم", "tokens": [12610, 8848, 23275, 13672, 1829, 47525, 3224, 7251, 8592, 2655, 17082, 1211, 8978, 16712, 38251, 10632, 47525, 3224, 7251, 30544, 9154, 2655, 3555, 3224, 14739, 3224, 6156, 3615, 15040, 5296, 7435, 10721, 5551, 9566, 12610, 8608, 1211, 3794, 37977, 4032, 9307, 10721, 4117, 3215, 14739, 3224, 19446, 41185, 8592, 32771, 13546, 11296, 12399, 45164, 5296, 7435, 10721, 2655, 11933, 29399, 9957, 44945, 36178, 41950, 12610, 12399, 47525, 3224, 7251, 46456, 9640, 16247, 4117, 49115, 6055, 5172, 2288, 3615, 995, 12399, 47525, 3224, 7251, 46456, 9640, 21136, 1211, 3794, 37977, 16247, 4117, 49115, 6055, 5172, 2288, 3615, 995, 12399, 4032, 46958, 5016, 23758, 2423, 28820, 10943, 22807, 3714, 43020, 8717, 7435, 25513, 19446, 5551, 3615, 9566, 1829, 24793], "avg_logprob": -0.14036016481912741, "compression_ratio": 1.9207920792079207, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2311.99, "end": 2312.69, 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ضعيفة", "tokens": [6027, 3224, 25708, 2288, 29245, 9957, 4724, 2407, 1863, 3215, 1863, 7435, 8978, 11296, 9673, 1829, 11703, 3224, 4724, 12610, 2288, 16070, 6027, 4117, 9957, 11622, 8717, 7649, 4724, 12610, 2288, 6156, 6027, 3555, 12610, 2288, 16070, 1863, 7649, 4724, 12610, 2288, 4724, 9778, 1211, 9566, 2407, 8592, 20449, 45030, 11242, 366, 1281, 1028, 39754, 638, 23032, 3555, 3615, 995, 9122, 11536, 14407, 25062, 2407, 3660, 13672, 1829, 3714, 29245, 23328, 3660, 8978, 16095, 48812, 3615, 33911, 3660], "avg_logprob": -0.33662974608095386, "compression_ratio": 1.5679012345679013, "no_speech_prob": 0.0, "words": [{"start": 2805.09, "end": 2806.01, "word": "الهيدروجين", "probability": 0.7965494791666666}, {"start": 2806.01, "end": 2806.51, "word": " بوندنج", "probability": 0.5445556640625}, {"start": 2806.51, "end": 2806.79, "word": " فيها", "probability": 0.633056640625}, {"start": 2806.79, "end": 2807.17, "word": " الميّه", "probability": 0.65655517578125}, {"start": 2807.17, "end": 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"temperature": 1.0}, {"id": 130, "seek": 300609, "start": 2989.13, "end": 3006.09, "text": "ليش؟ لأنه مافيش سطح التقاء كبير بينهم ولذلك الـbranched alkanes they have lower boiling points than the corresponding long chain alkanes هذه مبادئ عامة بال physical properties للالكنز وبهيك بننهي اليوم ان شاء الله", "tokens": [20292, 8592, 22807, 5296, 33456, 3224, 19446, 41185, 8592, 8608, 9566, 5016, 16712, 4587, 16606, 9122, 3555, 13546, 49374, 16095, 35525, 8848, 23275, 2423, 39184, 1443, 4778, 292, 419, 5225, 279, 436, 362, 3126, 16208, 2793, 813, 264, 11760, 938, 5021, 419, 5225, 279, 29538, 3714, 3555, 18513, 19986, 6225, 10943, 3660, 20666, 4001, 7221, 24976, 6027, 19452, 11622, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984], "avg_logprob": -0.26520269062068014, "compression_ratio": 1.360730593607306, "no_speech_prob": 0.0, "words": [{"start": 2989.13, "end": 2989.59, "word": "ليش؟", "probability": 0.6493326822916666}, {"start": 2989.59, "end": 2989.77, "word": " لأنه", "probability": 0.7687174479166666}, {"start": 2989.77, "end": 2990.13, "word": " مافيش", "probability": 0.9306640625}, {"start": 2990.13, "end": 2990.55, "word": " سطح", "probability": 0.9645182291666666}, {"start": 2990.55, "end": 2991.13, "word": " التقاء", "probability": 0.7957356770833334}, {"start": 2991.13, "end": 2991.61, "word": " كبير", "probability": 0.9837239583333334}, {"start": 2991.61, "end": 2992.19, "word": " بينهم", "probability": 0.968994140625}, {"start": 2992.19, "end": 2993.21, "word": " ولذلك", "probability": 0.8274739583333334}, {"start": 2993.21, "end": 2994.25, "word": " الـbranched", "probability": 0.65712890625}, {"start": 2994.25, "end": 2994.83, "word": " alkanes", "probability": 0.655029296875}, {"start": 2994.83, "end": 2995.11, "word": " they", "probability": 0.1942138671875}, {"start": 2995.11, "end": 2995.37, "word": " have", "probability": 0.9599609375}, {"start": 2995.37, "end": 2995.73, "word": " lower", "probability": 0.84814453125}, {"start": 2995.73, "end": 2996.11, "word": " boiling", "probability": 0.9599609375}, {"start": 2996.11, "end": 2996.53, "word": " points", "probability": 0.85791015625}, {"start": 2996.53, "end": 2996.75, "word": " than", "probability": 0.935546875}, {"start": 2996.75, "end": 2996.95, "word": " the", "probability": 0.86474609375}, {"start": 2996.95, "end": 2997.79, "word": " corresponding", "probability": 0.67919921875}, {"start": 2997.79, "end": 2998.65, "word": " long", "probability": 0.456298828125}, {"start": 2998.65, "end": 2999.17, "word": " chain", "probability": 0.84375}, {"start": 2999.17, "end": 3000.07, "word": " alkanes", "probability": 0.8976236979166666}, {"start": 3000.07, "end": 3000.61, "word": " هذه", "probability": 0.6943359375}, {"start": 3000.61, "end": 3001.73, "word": " مبادئ", "probability": 0.951904296875}, {"start": 3001.73, "end": 3002.11, "word": " عامة", "probability": 0.9959309895833334}, {"start": 3002.11, "end": 3002.23, "word": " بال", "probability": 0.70556640625}, {"start": 3002.23, "end": 3002.63, "word": " physical", "probability": 0.463134765625}, {"start": 3002.63, "end": 3003.21, "word": " properties", "probability": 0.69189453125}, {"start": 3003.21, "end": 3004.15, "word": " للالكنز", "probability": 0.555908203125}, {"start": 3004.15, "end": 3004.93, "word": " وبهيك", "probability": 0.8045654296875}, {"start": 3004.93, "end": 3005.31, "word": " بننهي", "probability": 0.928466796875}, {"start": 3005.31, "end": 3005.59, "word": " اليوم", "probability": 0.968017578125}, {"start": 3005.59, "end": 3005.73, "word": " ان", "probability": 0.51904296875}, {"start": 3005.73, "end": 3005.99, "word": " شاء", "probability": 0.9736328125}, {"start": 3005.99, "end": 3006.09, "word": " الله", "probability": 0.9453125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3006.89125, "duration_after_vad": 2900.3418749999923}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d0578e9550a11cc5fc9acafa7ab568bf1af8e2f4
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc.srt
@@ -0,0 +1,1805 @@
+
+1
+00:00:19,570 --> 00:00:26,370
+بسم الله الرحمن الرحيم اليوم ضيلنا أشياء بسيطة في
+
+2
+00:00:26,370 --> 00:00:30,890
+موضوع ال amines قبل ما ننتقل لجزء ال biochemistry
+
+3
+00:00:30,890 --> 00:00:36,850
+طبعا اتفقنا المرة الماضية أن ال amines هم مراكبات
+
+4
+00:00:36,850 --> 00:00:43,470
+ال nitrogen من أهم الأشياء اللي بتميزهم هو وجود
+
+5
+00:00:43,470 --> 00:00:47,730
+إيشالـ lone pair of electrons اللي موجودة على الـ
+
+6
+00:00:47,730 --> 00:00:52,910
+Nitrogens طالما في عليهم lone pair of electrons و
+
+7
+00:00:52,910 --> 00:00:56,150
+ال base is electron donor يعني ال base هي اللي
+
+8
+00:00:56,150 --> 00:01:02,370
+بتعطي إلكترونات فال amines arebasis واضح سبب أنه
+
+9
+00:01:02,370 --> 00:01:06,730
+بالأمينز قواعد هو وجود أزواج الإلكترونات فهم
+
+10
+00:01:06,730 --> 00:01:11,010
+كقاعدة بيعطوا أزواج إلكترونات هذا ضمن تعريف إيش
+
+11
+00:01:11,010 --> 00:01:19,710
+Lewis definition الآن لو إجالهم H plus عندي زوج
+
+12
+00:01:19,710 --> 00:01:23,270
+إلكترونات والـ H مش حاملة إلكترونات شو هيعملوا
+
+13
+00:01:23,270 --> 00:01:28,420
+فيها؟هيتفاعلوا معها هتصير الرابط المتكونة
+
+14
+00:01:28,420 --> 00:01:31,840
+Coordinated Covalent bond بمعنى ان زوجين
+
+15
+00:01:31,840 --> 00:01:37,940
+الالكترونات من النيتروجين والـ H بلس لما تتفاعل
+
+16
+00:01:37,940 --> 00:01:43,340
+معها بتكون مش حاملة الالكترونات ولذلك مثلا هنا
+
+17
+00:01:43,340 --> 00:01:48,380
+ارسملكوا كيف الأمونيا لو اتفاعل معها H بلس لاحظوا
+
+18
+00:01:48,380 --> 00:01:52,990
+الأمونيا الأن H3أساساً الـNitrogen في مداره
+
+19
+00:01:52,990 --> 00:01:57,070
+الخارجي خمس إلكترونات، فلو تخيلتم اللي كانوا
+
+20
+00:01:57,070 --> 00:02:00,470
+باللون الأزرق، تلاتة منهم عملوا روابط مع
+
+21
+00:02:00,470 --> 00:02:03,670
+الـHydrogen، فهذه الرابطة مع الـHydrogen في
+
+22
+00:02:03,670 --> 00:02:07,510
+الأمونيا أصلاً، إلكترون من الـNitrogen وإلكترون من
+
+23
+00:02:07,510 --> 00:02:11,040
+الـHydrogen، اللي بيانه بالأخضركذلك الرابط الثاني
+
+24
+00:02:11,040 --> 00:02:15,520
+والرابط الثالثة بقى عندي زوج إلكترونات إجاله H من
+
+25
+00:02:15,520 --> 00:02:21,180
+الخارج الـH إجت بدون إلكترونات بناء على ذلك الرابط
+
+26
+00:02:21,180 --> 00:02:24,560
+اللي هنا إيش بده تصير Coordinate Covalent bond
+
+27
+00:02:24,560 --> 00:02:29,460
+بمعنى أصلها أنه two electrons from the nitrogen
+
+28
+00:02:29,460 --> 00:02:35,300
+and no electron from hydrogen طبعا هذا بيخلي برضه
+
+29
+00:02:35,300 --> 00:02:41,700
+ال aminesباسيز بمفهوم لوري برونستيد definition
+
+30
+00:02:41,700 --> 00:02:47,240
+ليش؟ لأنه بمفهومه إن الحامض هو اللي بيعطي H plus
+
+31
+00:02:47,240 --> 00:02:53,180
+والباس هي اللي بتكتسب H plus الآن هذه اكتسبت H
+
+32
+00:02:53,180 --> 00:02:57,600
+plus ولا لأ؟ إذا أيضا ضمن تعريف لوري برونستيد
+
+33
+00:02:57,600 --> 00:03:03,860
+definition بتكون هذه base لكن لاحظوا ضمن تعريف
+
+34
+00:03:03,860 --> 00:03:09,080
+Arrheniusإن الـ base لازم يكون فيها OH- الأمونية
+
+35
+00:03:09,080 --> 00:03:13,420
+ما انحسبتش base و لذلك اتدرجوا في تعريفية الأحماض
+
+36
+00:03:13,420 --> 00:03:17,740
+يعني كان أقدم تعريف Arrhenius depression كان حاصر
+
+37
+00:03:17,740 --> 00:03:22,280
+ال bases في المواد ال hydroxides اللي بيعطوا ال OH
+
+38
+00:03:22,280 --> 00:03:29,060
+- بعد إكسرنا نقول لأ هو كل حاجة بتكتسب H plus يمكن
+
+39
+00:03:29,060 --> 00:03:33,960
+أننا نعتبرها base أساسا ال OH- كانت تكتسب H plus و
+
+40
+00:03:33,960 --> 00:03:39,160
+تعمل ميهواضح طب ما الأن H3 كمان بتكتسب جعب H plus
+
+41
+00:03:39,160 --> 00:03:47,280
+واضح الفكرة وإجا اللي هو Lewis definition أكتر
+
+42
+00:03:47,280 --> 00:03:51,440
+تخصيصا وقال أن ال base اللي فيه أزواج إلكترونات
+
+43
+00:03:51,440 --> 00:03:55,340
+مافيش تناقض ما بين التعريفات لكن فيه نظرة أكتر
+
+44
+00:03:55,340 --> 00:04:00,790
+تخصيصيةالان عشانك لو حطينا ال ammonia مع الميه
+
+45
+00:04:00,790 --> 00:04:05,510
+طبعا الميه هنا حاطين ال H3O plus كلكوا عارفين ان
+
+46
+00:04:05,510 --> 00:04:11,070
+الميه ايش هي أساسا H2O لكن هو اتخيل نسبة التأيون
+
+47
+00:04:11,070 --> 00:04:17,430
+اللي هي بسيطة جدا اللي درستها في الميه ان H2O زائد
+
+48
+00:04:17,430 --> 00:04:23,450
+H2O بتفاعل اتزان بطلع نسبة بسيطة جدا من H3O plus
+
+49
+00:04:23,450 --> 00:04:30,600
+زائد OH minusعشان يك هو لما هنا بيكتب h3o plus
+
+50
+00:04:30,600 --> 00:04:36,820
+هالنسبة البسيطة جدا اللي اتكونت من يعني تفاعل
+
+51
+00:04:36,820 --> 00:04:41,950
+الميه مع بعضها، اذا هنا ايش بتفترض انه موجود؟هو H
+
+52
+00:04:41,950 --> 00:04:46,770
+minus كمان ولذلك لما تيجي الأمونيا من الميه هدم ال
+
+53
+00:04:46,770 --> 00:04:52,590
+H3O plus تاخد ال H plus تعمل ان H4 plus زاد H2O هو
+
+54
+00:04:52,590 --> 00:04:57,370
+أساسا في ايون موجب بكل حاله لأ هو الموجب كان معاه
+
+55
+00:04:57,370 --> 00:05:02,330
+سالب الآن لما صارت الأمونيوم ايون هانا موجب ايش
+
+56
+00:05:02,330 --> 00:05:07,500
+صار معاه؟سالم و لذلك احنا سنقول ان الامونيا لما
+
+57
+00:05:07,500 --> 00:05:14,600
+ندوبها في الميه بتعطي امونيوم هيدروكسيد واضح؟ الكل
+
+58
+00:05:14,600 --> 00:05:19,220
+بيعرف ان احنا بندوب الامونيا في الميه بتعطي ايش؟
+
+59
+00:05:19,220 --> 00:05:23,750
+امونيوم هيدروكسيدكذلك الحالة لو دوبنا ال ammonia
+
+60
+00:05:23,750 --> 00:05:29,390
+مثلا في ال HCl ال ammonia هتاخد H من هنا هصير عندى
+
+61
+00:05:29,390 --> 00:05:34,510
+ammonium ion مع ال Cl minus ammonium chloride يمكن
+
+62
+00:05:34,510 --> 00:05:39,130
+هذا ما معاكم في المدرسة انه بإمكاننا احنا نجيب
+
+63
+00:05:39,130 --> 00:05:44,180
+نقطةمن ال ammonia من محلول ال ammonia نحطها هنا
+
+64
+00:05:44,180 --> 00:05:49,760
+نقطة من ال HCl نحطه هنا و نسيبهم جانب بعض بتتبخر
+
+65
+00:05:49,760 --> 00:05:53,860
+.. بتتبخر ال ammonia بتتبخر ال HCl لما يلتجوا مع
+
+66
+00:05:53,860 --> 00:05:57,620
+بعض ال ammonia مع ال HCl شو هيعملوا؟ ammonium
+
+67
+00:05:57,620 --> 00:06:02,660
+chloride ال ammonium chloride إيش لونه؟
+
+68
+00:06:02,660 --> 00:06:08,310
+تذكروا شغل المدرسة؟أبيض و لذلك كنا نقول أنه ال
+
+69
+00:06:08,310 --> 00:06:12,810
+ammonia مع ال HCl بيعطوا سحب بيضاء من ال ammonium
+
+70
+00:06:12,810 --> 00:06:18,820
+chloride بهذا النص مرت عليكم في المدرسة ولا لأ؟سحب
+
+71
+00:06:18,820 --> 00:06:23,780
+.. سحب بيضاء أو بقعة بيضة هم عادة بيعملوها .. عادة
+
+72
+00:06:23,780 --> 00:06:28,660
+بيعملوا هذه الشغلة كتجربة .. كتجربة بيجيبوا انبوبة
+
+73
+00:06:28,660 --> 00:06:32,500
+بهذا الشكل بيجيبوا انبوبة زجاجية مفتوحة الطرفين
+
+74
+00:06:32,500 --> 00:06:38,270
+بهذا الشكل بيحطوا هنا نقطة أمونياو بيحطوا هان طبعا
+
+75
+00:06:38,270 --> 00:06:41,090
+أمونيا البعض هيقوللي غاز أمونيا مدور باب ميه
+
+76
+00:06:41,090 --> 00:06:44,970
+أمونيا ميكروفسيت بيطلع أمونيا واضح؟ و بيحطوا هنا
+
+77
+00:06:44,970 --> 00:06:49,430
+HCl الآن بيمشوا بتبخر الغازين هذا بتبخر و هذا
+
+78
+00:06:49,430 --> 00:06:53,570
+بتبخر و سرعته بتعتمد على ال molecular weight تبعه
+
+79
+00:06:53,570 --> 00:06:58,050
+اللي ال molecular weight تبعه الجيل بيمشي إيش بطيء
+
+80
+00:06:58,050 --> 00:07:00,890
+فهذا بيمشي له شوية هنا هذا بيمشي له شوية هنا لما
+
+81
+00:07:00,890 --> 00:07:05,280
+بيلتقواإيش بدهم يعملوه اموريو ميكلورايت فجأة
+
+82
+00:07:05,280 --> 00:07:09,640
+بيصيروا الناس يشوفوا هنا إيش ابخرة بيضاء واضح
+
+83
+00:07:09,640 --> 00:07:15,310
+بيصيروا يشوفوا ابخرة بيضاء هذه الأبخرة هيالأمونيوم
+
+84
+00:07:15,310 --> 00:07:19,250
+كلورايت لو انتوا بتاخدوا معمل general chemistry
+
+85
+00:07:19,250 --> 00:07:22,410
+بتكون تجربة بتعملواها بتجيبوا الأنبوبة و بتحطوهم
+
+86
+00:07:22,410 --> 00:07:27,450
+بتشوفوا بعينكم و عشان دائما بنقول التعليم الجامعي
+
+87
+00:07:27,450 --> 00:07:32,150
+لا يجب أن ينفصل بحال من الأحوال اللي عاملة عن
+
+88
+00:07:32,150 --> 00:07:36,290
+الجزء النظري في أي خطة تدريسية
+
+89
+00:07:40,010 --> 00:07:45,710
+طالما قلنا ان ال amines are bases معناه ذلك زي ما
+
+90
+00:07:45,710 --> 00:07:50,130
+ال acids كنا نقول عنهم acids ويلهم BKA ال amines
+
+91
+00:07:50,130 --> 00:07:57,350
+بيكونيلهم BKB واضح؟ BKB وقلنا كل ما كانت في ال
+
+92
+00:07:57,350 --> 00:08:02,150
+acids ال BKA أقل كل ما كان الحامض أقوى الآن في ال
+
+93
+00:08:02,150 --> 00:08:07,530
+bases بنقول كل ما ال BKB بتكون أقل كل ما القاعدة
+
+94
+00:08:07,530 --> 00:08:12,460
+أيضا بتكون أقوى واضح؟الجدول اللى موجود عندنا حقيقة
+
+95
+00:08:12,460 --> 00:08:22,240
+مش كاتبنا ال BKB كاتب ال BKA ل ال conjugate acid
+
+96
+00:08:22,240 --> 00:08:26,700
+conjugate acid يعني الحمض المرافق عادة بين ال acid
+
+97
+00:08:26,700 --> 00:08:32,620
+و ال base المرافقة بيكون الفرق إيش؟هيدروجين يعني
+
+98
+00:08:32,620 --> 00:08:38,560
+انا لما بدي اقول nh4 plus هذا الاسل ال base
+
+99
+00:08:38,560 --> 00:08:45,500
+المرافقة nh3 و هكذا بناء على ذلك هدولة اللي بيكي
+
+100
+00:08:45,500 --> 00:08:53,100
+ايه و بيكي بيه كلنا عارفين ان بيكي ايهزائد ال BKB
+
+101
+00:08:53,100 --> 00:08:59,420
+بساوي 14 بناء على ذلك لو احنا كنا لهذه المجموعة من
+
+102
+00:08:59,420 --> 00:09:07,300
+ال Amines بدنا نشوف ال BKB بدنا نطرح من 14 يعني
+
+103
+00:09:07,300 --> 00:09:13,900
+مثلا لل Ammonia ال BKB أربعة و سبعة للميث الأمين
+
+104
+00:09:15,270 --> 00:09:21,390
+تلاتة و أربعة بالعشرة نفترض للضايف مثل أميل تلاتة
+
+105
+00:09:21,390 --> 00:09:25,870
+و تلاتة بالعشرة لو أجينا مقارنة مثلا مع الأنليل
+
+106
+00:09:25,870 --> 00:09:34,290
+حوالي تسعة و أربعة بالعشرةالان لو اجينا للان مثل
+
+107
+00:09:34,290 --> 00:09:40,410
+الأللين ايضا حوالي تسعة و اتنين بالعشرة الان
+
+108
+00:09:40,410 --> 00:09:46,010
+لاحظوا ع طول ملاحظة الأمينز اللي في الأول مثل أمين
+
+109
+00:09:46,010 --> 00:09:51,890
+ضاي مثل أمين و لحد الأللين هنا صار عندى تغير كتير
+
+110
+00:09:51,890 --> 00:09:57,550
+يعني لحد هدولة كلهمكانت ال بي كي بي قليلة تلاتة
+
+111
+00:09:57,550 --> 00:10:03,130
+تلاتة أربعة لما صرت فيه الانليل و التوابع صرت تسعة
+
+112
+00:10:03,130 --> 00:10:09,030
+الان هدول ايش بيفرقوا عن بعض لحد هذا الخط هدول
+
+113
+00:10:09,030 --> 00:10:14,510
+اللي فوق aliphatic amines اللي تحت aromatic amines
+
+114
+00:10:14,510 --> 00:10:22,190
+واضح؟ اذا هذه منطقاتالالفاتك أمين هذي منطقة ال
+
+115
+00:10:22,190 --> 00:10:27,870
+aromatic amines لو إجينا سألنا مين بيكونوا ك basis
+
+116
+00:10:27,870 --> 00:10:33,430
+أقوى الالفاتك أمين ولا ال aromatic amines؟
+
+117
+00:10:33,430 --> 00:10:40,000
+الالفاتك أمينليش؟ لأنه كل ما ال BKB بتكون أقل كل
+
+118
+00:10:40,000 --> 00:10:45,500
+ما كانت القاعدة أقوى، إذا ال aliphatic amines are
+
+119
+00:10:45,500 --> 00:10:50,460
+stronger bases than aromatic amines، يعني لما نجيب
+
+120
+00:10:50,460 --> 00:10:54,740
+ال QA سؤال صح و غلط ال aliphatic amines are فراغ
+
+121
+00:10:54,740 --> 00:11:00,120
+bases than aromatic amines، they arestronger basis
+
+122
+00:11:00,120 --> 00:11:05,660
+هذا عرفناها، الآن بعد كمان ممكن نكمل لكم، نقولكم
+
+123
+00:11:05,660 --> 00:11:14,120
+إيش ال due to بسبب إيش؟ ليش بدنا نحكي غلط؟ بدنا
+
+124
+00:11:14,120 --> 00:11:19,180
+نحكي غلط؟ ليش ال aliphatic a means
+
+125
+00:11:22,420 --> 00:11:27,220
+أقوى كقواعد من ال aromatic amines بهمش بدي أعلق
+
+126
+00:11:27,220 --> 00:11:32,260
+على الخطأ اللي عملته بدي أعلق على الخطأ اللي عملته
+
+127
+00:11:32,260 --> 00:11:38,140
+عشان ما تكرروهش رجاء انا لما بقول انه بسبب فواحدة
+
+128
+00:11:38,140 --> 00:11:44,020
+جالتلي ع طول بسبب ال BKB هذا الكلام غير بقبول منكم
+
+129
+00:11:44,020 --> 00:11:48,400
+انا لما قرأت ال BKB
+
+130
+00:11:50,390 --> 00:11:54,430
+لقيت هذه جليلة و هذه عالية قولت ال aromatic amines
+
+131
+00:11:54,430 --> 00:12:00,510
+أقوى من ال aromatic amines زي ما أجي على اتنين بني
+
+132
+00:12:00,510 --> 00:12:04,830
+أدمين أطفال against طولهم هذا طوله متر و هذا طوله
+
+133
+00:12:04,830 --> 00:12:10,750
+سبعين الآن اللي طوله متر بقول عنه أطول من اللي
+
+134
+00:12:10,750 --> 00:12:15,230
+طوله سبعين الان لما أقولكم ليش ماحدش يقوللي أنه
+
+135
+00:12:15,230 --> 00:12:20,930
+طوله مترthis is nonsense ممكن تقولولي لأنه في
+
+136
+00:12:20,930 --> 00:12:25,730
+العمر أكبر يمكن يكون هذا السبب هذا بيصير سبب لو
+
+137
+00:12:25,730 --> 00:12:29,670
+اتنين بنفس العمر ممكن تقولولي وراثيا هذا كل أسر
+
+138
+00:12:29,670 --> 00:12:33,750
+تطويل هذا أسر .. هيك بيصير سبب بس إن أجيب لقياسه
+
+139
+00:12:33,750 --> 00:12:38,410
+وأقول عنه سبب بسبب ال BKB لو أنا أساسا استنتجت أن
+
+140
+00:12:38,410 --> 00:12:43,790
+هذا أقوى من هذا لأن ال BKB هنا أقل من هنا إذا هذا
+
+141
+00:12:43,790 --> 00:12:44,270
+أقوى
+
+142
+00:12:47,630 --> 00:12:55,650
+بدي كلام إيش؟ بدي كلام كيمية طبعا معنى بيس إنه
+
+143
+00:12:55,650 --> 00:12:59,650
+بتعطي إلكترونات إذا للسبب شيء يمنع من إعطاء
+
+144
+00:12:59,650 --> 00:13:06,400
+الإلكترونات أو يقلل إعطاء الإلكترونات، واضح؟السبب
+
+145
+00:13:06,400 --> 00:13:10,740
+شيء يمنع أو يقلل من إعطاء الإلكترونات هذا السبب
+
+146
+00:13:10,740 --> 00:13:14,400
+فعلا ممكن يكون inductive effect و فعلا ممكن يكون
+
+147
+00:13:14,400 --> 00:13:18,980
+resonance effect في حالة ال aliphatic amines وهي
+
+148
+00:13:18,980 --> 00:13:23,820
+بالقاري المركبين بيشيبوا بعض القليلين مثلا ال BKA
+
+149
+00:13:23,820 --> 00:13:27,740
+تبعت الحامض المرافق له أربعة و ستة يعني ال BKB
+
+150
+00:13:27,740 --> 00:13:33,980
+تبعته جداشتسعة وأربعة هانا لل .. لل Cyclohex
+
+151
+00:13:33,980 --> 00:13:39,400
+الأمين، هذا ألفتك، مافي double bonds، Cyclic
+
+152
+00:13:39,400 --> 00:13:43,700
+alkanes are ألفتك، هذا كدهش؟ أربعة واتنين، مين
+
+153
+00:13:43,700 --> 00:13:48,730
+كباس أقوى؟ ال Cyclohex الأمين ولا الألليين؟الـ
+
+154
+00:13:48,730 --> 00:13:53,770
+Cyclohexane الأمين أقوى الآن السبب أن هذا زوج
+
+155
+00:13:53,770 --> 00:13:58,830
+الإلكترونات بدل ما يكون جاهز يطلع برا و يتفاعل برا
+
+156
+00:13:58,830 --> 00:14:04,310
+قاعد بيعمل resonance جوا الجزء هذا زوج الإلكترونات
+
+157
+00:14:04,310 --> 00:14:09,660
+بيطلع للخارججاهز إنه يُعطى للخارج و ال base هي
+
+158
+00:14:09,660 --> 00:14:15,220
+اللي بتعطي إيش إلكترونات فهذا بدل ما يروح للخارج و
+
+159
+00:14:15,220 --> 00:14:20,640
+يظهر قوة المركب ك base قاعد بيجي بلوف هنا و بيعمل
+
+160
+00:14:20,640 --> 00:14:24,360
+resonance .. resonance تاني بيصير مرة minus على ال
+
+161
+00:14:24,360 --> 00:14:26,420
+carbon مرة على ال carbon التاني مرة على ال carbon
+
+162
+00:14:26,420 --> 00:14:32,020
+التالتة إذا هو قاعد المجهود تبع وين؟ جوا الجزء
+
+163
+00:14:32,020 --> 00:14:37,990
+فبالنسبة للخارجهو لا يعطي إلكترونات هو قاعد بيعمل
+
+164
+00:14:37,990 --> 00:14:41,990
+resonance جوا الجزئ فما بيعطي إلكترونات للخارج ال
+
+165
+00:14:41,990 --> 00:14:46,870
+basic اللي بتعطي إلكترونات لمن؟ للخارج هذا إذا
+
+166
+00:14:46,870 --> 00:14:51,650
+بيكون سبب .. هذا بيكون سبب اللي هو ليش ال alphatic
+
+167
+00:14:51,650 --> 00:14:54,850
+amines are more basic than aromatic amines because
+
+168
+00:14:54,850 --> 00:15:01,710
+of resonance تمام؟ الآن البعض منكم اتكلم كلمة جيدة
+
+169
+00:15:01,710 --> 00:15:08,080
+قال ال inductive effectممكن يكون في مكان تاني غير
+
+170
+00:15:08,080 --> 00:15:12,840
+هذا الان حتى نفهم ال inductive effect حتى نفهم ال
+
+171
+00:15:12,840 --> 00:15:18,200
+inductive effect جيدا انتوا بتكونوا تتخيلوا
+
+172
+00:15:18,200 --> 00:15:26,720
+نيتروجين و عليها زوج إلكترونات و تلت روابط تمام؟
+
+173
+00:15:26,720 --> 00:15:32,040
+إيش اللي ممكن يزيد القاعدية تبعتها و
+
+223
+00:19:44,130 --> 00:19:51,430
+الإلكترونات؟ في الميثلانيلين، بعده الانيلين، بعده 
+
+224
+00:19:51,430 --> 00:19:57,870
+النيترو، فك basis الميثلانيلين أعلى من الانيلين، 
+
+225
+00:19:57,870 --> 00:20:02,350
+أعلى من النيتروانيلين، الآن هنا لما ابدأ أقول شو 
+
+226
+00:20:02,350 --> 00:20:10,330
+السبب؟ ال inductive effectطبعاً بشكل عام كلهم
+
+227
+00:20:10,330 --> 00:20:17,630
+يعتبروا ضعاف، ليش؟ لأن كلهم فيهم resonance، كلهم
+
+228
+00:20:17,630 --> 00:20:21,050
+يعتبروا ك basis ضعاف، لكن واحد أضعف من التاني أضعف 
+
+229
+00:20:21,050 --> 00:20:26,610
+من التالت، الأن فرق الضعف اللي بين لضعاف أساساً
+
+230
+00:20:26,610 --> 00:20:31,670
+بسبب إيش؟ ال inductive effectلكن لو أنا باجي
+
+231
+00:20:31,670 --> 00:20:38,370
+بسألكم والله بشكل عام ال nitroaniline is a weak 
+
+232
+00:20:38,370 --> 00:20:45,560
+base، ليش؟ هتقولولي ال resonance مصيبة؟و الحاجات 
+
+233
+00:20:45,560 --> 00:20:50,980
+هم صيبة تانية ال nitro يعني صار سبب ضعفه شغل فيه
+
+234
+00:20:50,980 --> 00:20:55,280
+ال resonance و ال inductive effect لكن لو كنت بدأ 
+
+235
+00:20:55,280 --> 00:20:58,500
+اقارنه مثلا مع ال methyl aniline لأ بقول ما هو ال
+
+236
+00:20:58,500 --> 00:21:01,720
+resonance و ال resonance هم عامل مشترك بطل هو اللي
+
+237
+00:21:01,720 --> 00:21:07,920
+مفرج صار إيش اللي مفرج؟ شكل أساسي ال inductive 
+
+238
+00:21:07,920 --> 00:21:09,940
+effect واضحة الفكرة؟
+
+239
+00:21:17,860 --> 00:21:23,620
+أخر شغلة في هذا الفصل، لو قلنا تفاعلات الـ Amines،
+
+240
+00:21:23,620 --> 00:21:28,240
+تفاعلات الـ Amines مروا علينا بدل المر ألف طالما
+
+241
+00:21:28,240 --> 00:21:33,140
+في زوج إلكترونات، إذا الـ Amines بيعملوا as الـ 
+
+242
+00:21:33,140 --> 00:21:39,880
+Eucleophiles، واضح؟إذا بدكم تحكوا عن الكليهيليتز،
+
+243
+00:21:39,880 --> 00:21:44,120
+بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن الديهيد
+
+244
+00:21:44,120 --> 00:21:48,260
+وكيتون، بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن 
+
+245
+00:21:48,260 --> 00:21:52,660
+كاربوكسيليك أسيتس ومشتقاتها، بتفعلوا كنيكليوفييل، 
+
+246
+00:21:52,660 --> 00:21:56,280
+وكل الأمثلة مرت علينا، الآن مع الالكليهيليتز
+
+247
+00:21:56,280 --> 00:22:00,700
+بيعملوا النيكليوفيليك سبستيوشن، مع الديهيدس وكيتون
+
+248
+00:22:01,680 --> 00:22:06,140
+بيعملوه الـ Eucleophilic addition مع الـ E stars
+
+249
+00:22:06,140 --> 00:22:10,340
+ومشتقاتها بيعملوه مرة تانية الـ Eucleophilic
+
+250
+00:22:10,340 --> 00:22:14,900
+substitution يعني هاي نشوف عدة أمثلة هاي هذا أمين
+
+251
+00:22:14,900 --> 00:22:20,260
+RNH2 مع أسد الكلورايد هاي الـ Eucleophile هاجم طرد
+
+252
+00:22:20,260 --> 00:22:24,360
+الـ Cl هذا عبارة عن إيش الـ Eucleophilic
+
+253
+00:22:24,360 --> 00:22:29,520
+substitution على أسد الكلورايد هذا primary أمين طب
+
+254
+00:22:29,520 --> 00:22:33,230
+لو secondary أمينبرضه الـ Eucleophilic
+
+255
+00:22:33,230 --> 00:22:38,230
+Substitution على أسد إكلورايد مافيش فيها إشي لو 
+
+256
+00:22:38,230 --> 00:22:41,710
+شوفناه مُركّب تاني برضه هذا سكندريامين مع أسد
+
+257
+00:22:41,710 --> 00:22:46,590
+إكلورايد الـ Eucleophilic Substitution لو شوفنا 
+
+258
+00:22:46,590 --> 00:22:51,150
+أنيلين مع أسد أنهيدرايد بده يهاجمها نطوط رد هادي
+
+259
+00:22:51,150 --> 00:22:55,850
+الـ Eucleophilic Substitution واضح؟ كل هذه
+
+260
+00:22:55,850 --> 00:22:59,250
+التفاعلات حقيقة سبع
+
+261
+00:23:00,470 --> 00:23:07,030
+ومرت علينا في أي منطقة لما اتكلمنا على الأحماط
+
+262
+00:23:07,030 --> 00:23:13,130
+ومشتقاتها ربما البعض يقول طيب ذكرنا بأمثلة على ال
+
+263
+00:23:13,130 --> 00:23:16,630
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+264
+00:23:16,630 --> 00:23:17,190
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+265
+00:23:17,190 --> 00:23:17,570
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+266
+00:23:17,570 --> 00:23:24,530
+ال ال ال ال ال
+
+267
+00:23:24,530 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+268
+00:23:29,470 --> 00:23:29,490
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+269
+00:23:31,660 --> 00:23:42,460
+CH3 CH2 NH2 هذا primary امين زائد هذا المركب و 
+
+270
+00:23:42,460 --> 00:23:49,980
+حامل هنا ب R هذا يعتبر ايش الكلهيلايت هذا في
+
+271
+00:23:49,980 --> 00:23:53,520
+النهاية الكلهيلايت و لو حلقة خمسية كيف هتعملوا 
+
+272
+00:23:56,960 --> 00:24:03,400
+واضح؟ وطالما الـ nucleophile neutral كمحص لإيش
+
+273
+00:24:03,400 --> 00:24:11,020
+هيكون؟ يفقد CH2 CH3 أكيد الـ H اللي فقدها مع ال PR
+
+274
+00:24:11,020 --> 00:24:17,940
+إيش هتعمل؟ HPR هذا من chapter 6 الـ nucleophilic
+
+275
+00:24:17,940 --> 00:24:22,820
+substitution ofAlkyl Halides الوثيقة الوثيقة
+
+276
+00:24:22,820 --> 00:24:27,820
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+277
+00:24:27,820 --> 00:24:30,180
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+278
+00:24:30,180 --> 00:24:31,120
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+279
+00:24:31,120 --> 00:24:31,460
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+280
+00:24:31,460 --> 00:24:36,880
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+281
+00:24:36,880 --> 00:24:41,160
+الوثيقة
+
+282
+00:24:41,160 --> 00:24:45,820
+الوثيقة
+
+283
+00:24:45,820 --> 00:24:47,480
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+284
+00:24:47,480 --> 00:24:49,140
+الوثيقة الوثيقة الوثيقة الوثيناخد كمان مرنو
+
+285
+00:24:49,140 --> 00:24:53,960
+سايكليك كيتون او الديهايد هى C double bond O C
+
+286
+00:24:53,960 --> 00:25:01,580
+double bond O زائد CH3 CH2
+
+287
+00:25:01,580 --> 00:25:08,720
+NH2 تخيلوا اجتكوا اكمل هذه المعادلة كيف هتكملوها؟
+
+288
+00:25:08,720 --> 00:25:12,260
+اه بدكم اتهاجموها على ال الديهايد او ال كيتون و 
+
+289
+00:25:12,260 --> 00:25:16,540
+هذه تصير OH اذا للناتج اللى عندى
+
+290
+00:25:22,140 --> 00:25:30,100
+بدي يصير عندى OH OHANA NH
+
+291
+00:25:30,100 --> 00:25:39,120
+CH2 CH3 مش هذا اللي بدي يصير لكن الطالب الشاطر 
+
+292
+00:25:39,120 --> 00:25:45,900
+اتعلمت كمان شغلة ان هذا هو تفاعل ل nucleophilic 
+
+293
+00:25:45,900 --> 00:25:46,780
+addition
+
+294
+00:25:49,140 --> 00:25:54,660
+هذا هو تفاعل الـ Eucleophilic addition الآن مع ال 
+
+295
+00:25:54,660 --> 00:25:58,600
+amines لما تكون ال H و ال OH جانب بعض، ايش 
+
+296
+00:25:58,600 --> 00:26:05,460
+اتعلمنا؟ بيروح و بيفقد جزء ماء و بعمل double bond
+
+297
+00:26:08,450 --> 00:26:12,470
+قولنا احنا كل N H2 مع C double bond O ماصيرها
+
+298
+00:26:12,470 --> 00:26:17,130
+النهائي C double bond O الديهيد او كيتون تصير C 
+
+299
+00:26:17,130 --> 00:26:23,790
+double bond N CH2 CH3 بصير ال shift basis وقولنا
+
+300
+00:26:23,790 --> 00:26:27,590
+ان التفاعل بهذه الحالة ايش بنقول عنه addition
+
+301
+00:26:27,590 --> 00:26:30,370
+elimination
+
+302
+00:26:31,670 --> 00:26:35,830
+نسيته تفاعل تكوين الأكزينز والهيدرازونز والسمي
+
+303
+00:26:35,830 --> 00:26:39,570
+كربازونز كل ال N-H2 مع ال C double bond O
+
+304
+00:26:39,570 --> 00:26:43,410
+الديهيدوكيتون كانت تعمل C double bond N على خطوتين
+
+305
+00:26:43,410 --> 00:26:51,100
+لكن في الأساس أن الأمين تفاعل كإيش؟كان uqlu5 وعمل
+
+306
+00:26:51,100 --> 00:26:54,760
+addition الان بعد هيك ان ال addition اتبع ال
+
+307
+00:26:54,760 --> 00:26:58,960
+elimination هذا امر ايش تاني هذا المحصلة النهائية
+
+308
+00:26:58,960 --> 00:27:03,480
+لكن ال addition ادشن و ال uqlu5 ال uqlu5 فال
+
+309
+00:27:03,480 --> 00:27:09,240
+amines تفاعلهم الأساسي بنقول هو ايش they react as
+
+310
+00:27:09,240 --> 00:27:14,480
+uqlu5 as uqlu5 واضح؟
+
+311
+00:27:16,420 --> 00:27:20,000
+لكن لو جينا سألناكم ال reaction of amines with 
+
+312
+00:27:20,000 --> 00:27:25,120
+aldehydes and ketones is a nucleophilic addition
+
+313
+00:27:25,120 --> 00:27:30,600
+in a brain cell واضح؟ انه بعدك followed by
+
+314
+00:27:30,600 --> 00:27:34,700
+elimination على أنه الرأس مرة تبسيط واضح؟ with 
+
+315
+00:27:34,700 --> 00:27:39,920
+acids and their derivatives a nucleophilic 
+
+316
+00:27:39,920 --> 00:27:44,620
+substitution with alkyl halides برضه nucleophilic
+
+317
+00:27:44,620 --> 00:27:45,840
+substitution
+
+318
+00:27:56,390 --> 00:28:01,410
+بهيك بنكون خلصنا الفكرة أو الكلام المختصر اللى 
+
+319
+00:28:01,410 --> 00:28:07,510
+بنشرحه عن ال amines و 
+
+320
+00:28:07,510 --> 00:28:11,670
+بنلتقل مباشرة
+
+321
+00:28:11,670 --> 00:28:15,970
+لفصل 
+
+322
+00:28:15,970 --> 00:28:22,850
+الخامس عشر اللى هو يعتبر بداية ال general
+
+323
+00:28:22,850 --> 00:28:28,890
+biochemistry اللى بنحكي عنهاlimits and detergents
+
+324
+00:28:28,890 --> 00:28:37,110
+limits and detergents الان ال limits معناها 
+
+325
+00:28:37,110 --> 00:28:41,190
+بالعربي الدهون اش
+
+326
+00:28:41,190 --> 00:28:50,630
+اللي تلغيه ال libidab اسمها ال libidab دهون اه في
+
+327
+00:28:50,630 --> 00:28:55,570
+مشكلة عندكوا في الورق؟أنا عند ال slides خلص و أنت 
+
+328
+00:28:55,570 --> 00:29:07,090
+عندك إشي؟ من وين صورته؟ أي شباته؟ مالغيين
+
+329
+00:29:07,090 --> 00:29:13,300
+هدولة، مشيولين عن .. مش موجودين في الزمالةلأ لأ
+
+330
+00:29:13,300 --> 00:29:18,440
+هدولة ال slides اللي معكم زيادة فيهم بس كلمة واحدة
+
+331
+00:29:18,440 --> 00:29:22,940
+احنا شرحناها كتابة how to prepare phenol هي اللي 
+
+332
+00:29:22,940 --> 00:29:27,740
+كنا مهتمين فيها متذاكرين المرة الماضية قولنالكم
+
+333
+00:29:27,740 --> 00:29:32,240
+كيف تحضروا ال phenol فقط لحد هنا وبنخلص مافيش اندي
+
+334
+00:29:32,240 --> 00:29:37,420
+انا عن ال computer الان ننتقل للفصل الخامس عشر 
+
+335
+00:29:37,420 --> 00:29:42,280
+limits and detergentsالـ Libids الدهون الـ 
+
+336
+00:29:42,280 --> 00:29:48,420
+detergents المنظفات الصناعية المنظفات الصناعية 
+
+337
+00:29:48,420 --> 00:29:51,400
+الصوابين و الأشياء اللي بتكون في الشنب و غيرها و 
+
+338
+00:29:51,400 --> 00:29:57,520
+غيراتها و هتلاحظوا انه في علاقة بين الدهون و بينال
+
+339
+00:29:57,520 --> 00:30:03,160
+detergents و ربما كلكم اتذكرين اساسا ان الصابون
+
+340
+00:30:03,160 --> 00:30:08,220
+عادة من وين كانوا بيجيبوها؟ من زيت الزتون .. زيت 
+
+341
+00:30:08,220 --> 00:30:14,650
+الزتون، دهون والصابونمنظف طبعا soap الآن صاروا
+
+342
+00:30:14,650 --> 00:30:19,070
+يعملوا أشياء صناعية بنسميها synthetic detergents
+
+343
+00:30:19,070 --> 00:30:23,590
+يعني منظفات صناعية كل هذا الكلام هيكون جزء من
+
+344
+00:30:23,590 --> 00:30:30,270
+الكلام اللي هنناقشه في هذا الشركة الآن لو إجينا و 
+
+345
+00:30:30,270 --> 00:30:38,380
+قولنا إيش هم ال livids إيش هم الدهونلاحظوا أنه 
+
+346
+00:30:38,380 --> 00:30:42,140
+الآن بنبدأ شوية نختلف عن ال organic chemistry يعني 
+
+347
+00:30:42,140 --> 00:30:45,760
+في ال organic chemistry كل chapter لما كنا نجيب
+
+348
+00:30:45,760 --> 00:30:50,080
+عائلة كنا نميز العائلة بالمجموعة الوظيفية اللي
+
+349
+00:30:50,080 --> 00:30:54,780
+موجودة فيها يعني نقول ال alcohols OH ال aldehydes
+
+350
+00:30:54,780 --> 00:31:00,490
+يضا بالبنض OC double bond O of R of R الاسد C
+
+351
+00:31:00,490 --> 00:31:04,830
+double bond O O H هناك كان التصنيف اعتمادا على ايش
+
+352
+00:31:04,830 --> 00:31:11,010
+المجموعة الوظيفية الان لما باجي بقول ال libids هل
+
+353
+00:31:11,010 --> 00:31:16,790
+يا ترى ال libids كعائلة تحكمها مجموعة وظيفية واحدة 
+
+354
+00:31:16,790 --> 00:31:19,870
+يعني في الآخر الواحدة تيجي تقولي C double bond
+
+355
+00:31:19,870 --> 00:31:26,780
+ONH4 C double bond OSHهل تصنيف ال limits منطلق من 
+
+356
+00:31:26,780 --> 00:31:29,980
+ال functional groups من المجموعات الوظيفية
+
+357
+00:31:29,980 --> 00:31:35,710
+الجوانب؟الـ Libids هي عائلة من المنتجات الطبيعية
+
+358
+00:31:35,710 --> 00:31:41,070
+بشكل عام Natural Products عائلة كبيرة جدا و ينضوي
+
+359
+00:31:41,070 --> 00:31:47,030
+تحتها تفرعات كتيرة هدولة بيمتازوا بشكل عام .. 
+
+360
+00:31:47,030 --> 00:31:51,490
+بيمتازوا بشكل عام المراكبات المنتجة طبيعيا انه
+
+361
+00:31:51,490 --> 00:31:56,230
+بتدوب في ال organic solvents زي ال ether, 
+
+362
+00:31:56,450 --> 00:32:00,330
+chloroform, أسيتون, بنزين وبشكل عام بدوبوش في 
+
+363
+00:32:00,330 --> 00:32:05,710
+الميهإذا هنا اللي ميزهم كعائلة إن هما منتجات 
+
+364
+00:32:05,710 --> 00:32:12,190
+طبيعية وشغل تانية soluble in organic solvents يعني
+
+365
+00:32:12,190 --> 00:32:19,870
+أنا بدي إن they are natural و soluble in non-polar 
+
+366
+00:32:19,870 --> 00:32:24,370
+organic solvents insoluble in water
+
+367
+00:32:27,950 --> 00:32:31,530
+اللي أنا بدياهم عن ال limits they are natural
+
+368
+00:32:31,530 --> 00:32:37,510
+compounds soluble in non-polar organic solvents
+
+369
+00:32:37,510 --> 00:32:43,050
+insoluble in water طبعا طالما كانوا soluble in non 
+
+370
+00:32:43,050 --> 00:32:46,090
+-polar organic solvents إذا انتوا هتستنتجوا ان هم
+
+371
+00:32:46,090 --> 00:32:51,790
+non-polar ليش؟ لأنه likelike واضح إذا هما non
+
+372
+00:32:51,790 --> 00:32:55,910
+polar و بدوبوا فيه ال non polar solvents الانب 
+
+373
+00:32:55,910 --> 00:33:00,370
+يندرج تحتهم الحقيقة مجموعة كبيرة من المراكبات منهم
+
+374
+00:33:00,370 --> 00:33:05,090
+اللي بنسميه ال fatty acids الأحماض الدهنية بنشوف
+
+375
+00:33:05,090 --> 00:33:08,510
+شو هي ال fatty acids منهم ال soaps and detergents 
+
+376
+00:33:08,510 --> 00:33:13,370
+الصوابين و المنظفات منهم ال fats and oils الدهون و
+
+377
+00:33:13,370 --> 00:33:18,770
+الزيون منهم ال waxes الشموةمنهم الـ Phospholipids
+
+378
+00:33:18,770 --> 00:33:23,330
+بنسميها Phospholipids منهم الـ Icosanoids مركبات
+
+379
+00:33:23,330 --> 00:33:28,590
+انكونا من عشرين ذرة كربون منهم Terbenes مجموعة
+
+380
+00:33:28,590 --> 00:33:34,590
+مركبات بتحده بصفة معينة بنشوفها وجود isoprene unit
+
+381
+00:33:34,590 --> 00:33:40,400
+منهم الستيرويد مركبات ممتازة وجود أربع حلقاتمنهم
+
+382
+00:33:40,400 --> 00:33:45,620
+بعض ال vitamins أشياء منوعة مافيش خاسم مشترك بينها
+
+383
+00:33:45,620 --> 00:33:50,980
+كل هدولة من ناحية المبدأ natural productsSoluble 
+
+384
+00:33:50,980 --> 00:33:54,940
+in organic solvents and soluble in water are
+
+385
+00:33:54,940 --> 00:33:57,580
+classified as lipids
+
+386
+00:34:20,310 --> 00:34:24,990
+يعني التلات أشياء بنفهموا مع بعض، واضح؟ يعني اللي 
+
+387
+00:34:24,990 --> 00:34:28,150
+بده يفهم ال fatty acids، بده يفهم ال fats، اللي
+
+388
+00:34:28,150 --> 00:34:30,890
+بده يفهم ال fats، بده يفهم ال oils، اللي بده يفهم
+
+389
+00:34:30,890 --> 00:34:33,110
+ال fats و ال oils، بده يفهم ال soaps و ال
+
+390
+00:34:33,110 --> 00:34:38,310
+detergents، التلاتة هتلاحظوا أن فيهم إيش؟ قاسم
+
+391
+00:34:38,310 --> 00:34:45,240
+مشترك، التلاتة هتلاحظوا أن فيهم قاسم مشتركوعشان
+
+392
+00:34:45,240 --> 00:34:51,440
+هيك خلّينا نبدأ بال fats and oils الآن بشكل عام
+
+393
+00:34:51,440 --> 00:34:57,640
+الدهون والزيوت أشهر شيء موجودين فيه على شكل اللي
+
+394
+00:34:57,640 --> 00:35:04,700
+بنسميه triglycerides إيش هما ال triglycerides؟ ال
+
+395
+00:35:04,700 --> 00:35:13,120
+triglycerides ببساطة عبارة عن إيسترز ل .. ال .. 
+
+396
+00:35:14,640 --> 00:35:20,620
+للجليسارين طبعا كلكم اتذكرين انه احنا ايش اخدنا
+
+397
+00:35:20,620 --> 00:35:27,380
+الجليسارين سابقا قلنا تلات ذرات كربون ت
+
+445
+00:39:55,280 --> 00:40:02,420
+بحصل؟ بحصل على ال glycerin أو ال glycerol و ال 
+
+446
+00:40:02,420 --> 00:40:10,380
+fatty acids بحصل على ال glycerol و ال fatty acids
+
+447
+00:40:10,380 --> 00:40:17,060
+واضح الفكرة؟ إذا ال fatty acids هما في الأساس جزء 
+
+448
+00:40:17,060 --> 00:40:22,280
+من ال tri glycerides بالتكسير بحصل على glycerin و 
+
+449
+00:40:22,280 --> 00:40:27,600
+بحصل على fatty acid واضح الفكرة؟ 
+
+450
+00:40:29,710 --> 00:40:34,910
+خلّينا شوية صغيرة نخرج عن السياق خلّينا شوية صغيرة
+
+451
+00:40:34,910 --> 00:40:41,870
+نخرج عن السياق الان جزء ال الكانز نرجع لل الكانز
+
+452
+00:40:41,870 --> 00:40:48,790
+مش هذا الجزء الأحمر هو عبارة عن ال الكانز طيب أول
+
+453
+00:40:48,790 --> 00:40:54,150
+chapter أخدناه في الكيميا العضوية شو كان؟ال الكينز، 
+
+454
+00:40:54,150 --> 00:41:02,530
+وإيش أهم تفاعلات ال الكينز اللي احنا أخدناها؟ أن 
+
+455
+00:41:02,530 --> 00:41:08,710
+ال الكينز بنحرقهم في وجود ال oxygen، بيعطونا ثاني
+
+456
+00:41:08,710 --> 00:41:15,970
+أكسيد الكربون وماء وحرارة طيب هذه المركبات اللي
+
+457
+00:41:15,970 --> 00:41:20,090
+قال فيها Alkanes واحدة مين كنتيش تتخيل القاتل انه
+
+458
+00:41:20,090 --> 00:41:25,970
+حطينا السيرج على النار بدنا نولع السيرج حد بيمنعنا 
+
+459
+00:41:25,970 --> 00:41:36,930
+يعني سيرج زائد Oxygen شو هيعطيني CO2 زائد H2O زائد 
+
+460
+00:41:36,930 --> 00:41:43,730
+Heat مش هذه الـ aliphatic compounds الحمرة بتنحرج
+
+461
+00:41:43,730 --> 00:41:48,730
+وبتعطيني ثانو أكسيد كربون وميه وحرارة؟ إذا الـ
+
+462
+00:41:48,730 --> 00:41:53,790
+seerage ممكن ينحرج ويعطيني ثانو أكسيد كربون وميه 
+
+463
+00:41:53,790 --> 00:41:59,530
+وحرارة؟ ولا مش ممكن؟ بتشوفوه بنحرج في الدار و 
+
+464
+00:41:59,530 --> 00:42:04,530
+بتكونوا تنتبهوا لما بتشتغلوا؟ طب كويس الآن لو واحد 
+
+465
+00:42:04,530 --> 00:42:11,060
+مخه مش مريحه أو الحصار مش مريحه وقطعوا البنزين .. 
+
+466
+00:42:11,060 --> 00:42:15,720
+جطعوا السولار عن البلد وإيجى حط في سيارة ال مرسيدس 
+
+467
+00:42:15,720 --> 00:42:18,920
+تبعته اللي بتمشي على السولار ولا في ال bus؟ سيرج
+
+468
+00:42:18,920 --> 00:42:25,740
+.. سيرج ومشى .. بيمشي ولا لأ؟ بيمشي .. بيمشي ..
+
+469
+00:42:25,740 --> 00:42:32,920
+بيمشي وعشان هيك في غزة في ظروف الحصار لما عدم
+
+470
+00:42:32,920 --> 00:42:38,270
+الوقود وكانوا بعض الباصات والسيارات المرسيدس مضطرة 
+
+471
+00:42:38,270 --> 00:42:45,030
+تمشي حطوا searage في السيارة واشتغلت ومشيت صح لكن 
+
+472
+00:42:45,030 --> 00:42:54,350
+كان عندكم مشكلة الشيء انه طلعت رائحة فظيعة جدا و 
+
+473
+00:42:54,350 --> 00:42:58,850
+الناس كانت بتنخنيهم ظبوط ولا لأ؟ طب هم الناس
+
+474
+00:42:58,850 --> 00:43:02,030
+مانخنجوش من ال solar العادى و من البنزين يعني،
+
+475
+00:43:02,030 --> 00:43:05,990
+يقولوا تأثيرات سلبية، لكن مابتصلش لإنه الناس 
+
+476
+00:43:05,990 --> 00:43:11,650
+ينخنجوا، إيش اللي صار إذا لما احنا ولّعنا السيرج؟ 
+
+477
+00:43:11,650 --> 00:43:16,210
+اه، اللي صار لما ولّعنا السيرج، إنه السيرج جزءين، 
+
+478
+00:43:16,210 --> 00:43:22,310
+هذا الجزء هو اللي عمل كوقود هذا الجزء التابع لـ 
+
+479
+00:43:22,310 --> 00:43:28,990
+Glycerin راح يعمل مصيبة هذا بالحرق بيعطي مركب تاني 
+
+480
+00:43:28,990 --> 00:43:36,990
+CH ضب البند OH CH ضب البند CH2 بنسميه أكرولين و لا 
+
+481
+00:43:36,990 --> 00:43:42,450
+أكرالدهايد هذا المركب هو اللي ريحته كانت سيئة و 
+
+482
+00:43:42,450 --> 00:43:49,350
+يطلع على الشوارع و غيره و غيراته و خنج الناس واضحة 
+
+483
+00:43:49,350 --> 00:43:55,130
+الفكرة؟ فالغلطة اللى كانت ان الناس لما اجوا يحرقوا 
+
+484
+00:43:55,130 --> 00:44:01,330
+ال series في متورات السيارات حرقوا ايش؟ الجزء اللى 
+
+485
+00:44:01,330 --> 00:44:06,110
+عادة بيعطيه الطاقة والجزء الجيد زائد الجزء ايش؟
+
+486
+00:44:06,110 --> 00:44:12,470
+السام والدار فطلعت عندهم حرارة ومشيت السيارة وكل 
+
+487
+00:44:12,470 --> 00:44:16,810
+اشي لكن طلع عندهم كمان هذا المركب انتشر في الجو
+
+488
+00:44:16,810 --> 00:44:24,620
+خلق الناس واضحة الفكرة؟ طيب الآن لو في ناس بيفكروا
+
+489
+00:44:24,620 --> 00:44:31,940
+جيدا وقالوا يا تورا بدنا نحل المشكلة نطلع وقود من
+
+490
+00:44:31,940 --> 00:44:40,080
+الزيت ومن السيرج بيقدروا يعمله؟ لو إنهم في الأول 
+
+491
+00:44:40,850 --> 00:44:46,750
+عملوا القاتل فصلوا هدول المركبين عن بعض يعني جابوا 
+
+492
+00:44:46,750 --> 00:44:51,630
+ال searage قبل ما يحطوا كله في ماتور السيارة قبل 
+
+493
+00:44:51,630 --> 00:44:57,410
+ما يحطوا كله في ماتور السيارة كسروا نصين الان هذا 
+
+494
+00:44:57,410 --> 00:45:04,480
+النص المفيد هذا ال fuel هذا الوقود وهذا إيش؟
+
+495
+00:45:04,480 --> 00:45:08,860
+الجليسيرين الان أنا لما أكسره بداية قبل ما أحطه في 
+
+496
+00:45:08,860 --> 00:45:13,340
+موتور السيارة الجليسيرين صار على جانب بفصله ولا
+
+497
+00:45:13,340 --> 00:45:17,600
+مابفصلوش بفصله باخده و باستفيد منه كمان بعمل منه
+
+498
+00:45:17,600 --> 00:45:21,220
+كريمات مش كل كريمات و شامبوات فيها جليسيرين عشان
+
+499
+00:45:21,220 --> 00:45:27,850
+نعمة الإيدين يعني أنا مش بس اتخلصت من ضرر حرقه أنا
+
+500
+00:45:27,850 --> 00:45:32,470
+أخدته واستفادت منه وهذا الجزء عادة بيفصله على شكل
+
+501
+00:45:32,470 --> 00:45:39,650
+E star أو إثل أو إثل أو إثل واضح؟
+
+502
+00:45:39,650 --> 00:45:43,250
+يعني لما يعملوا التكسير بيفصلوا على شكل E star هذا
+
+503
+00:45:43,250 --> 00:45:50,610
+بناخده كوقود اليوم هذا الوقود اللي أخدنا إيش
+
+504
+00:45:50,610 --> 00:45:57,770
+بيسموه؟ بيو ديزل بيو ديزل إيش يعني بيو ديزل يعني
+
+505
+00:45:57,770 --> 00:46:03,910
+الديزل الحيوي اللي جاي من الزيوت هتقولولي في ديزل
+
+506
+00:46:03,910 --> 00:46:11,610
+بالطول من الزيت الجواب آه اليوم طائرات وسيارات
+
+507
+00:46:11,610 --> 00:46:17,370
+طائرات كاملة بتمشي على بيو ديزل بطوله من الزيوت 
+
+508
+00:46:17,960 --> 00:46:23,540
+طبعا هالياطورة احنا ملاقين زيت ناكله سيرج و زيت
+
+509
+00:46:23,540 --> 00:46:29,620
+ناكله لما نحوله لوخود؟ الجواب اه كيف؟ الزيوت مش بس
+
+510
+00:46:29,620 --> 00:46:34,760
+كله مأكولة edible مأكول في زيوت inedible زيوت لا 
+
+511
+00:46:34,760 --> 00:46:40,480
+تؤكل تمام؟ بيزرعوها في أماكن كبيرة في الهند و في
+
+512
+00:46:40,480 --> 00:46:44,580
+غيرها و في غيراتها مثل مثلا زيت الجاتروفة و زيت
+
+513
+00:46:44,580 --> 00:46:49,520
+الكامليانة و زيت كذا في زيوت تؤكل و زيوت لا تؤكل
+
+514
+00:46:49,520 --> 00:46:54,800
+الزيوت اللتي لا تؤكل هي اللي بيحضروا منها المنظفات
+
+515
+00:46:54,800 --> 00:47:00,740
+و هي اللي بيحولوها لإيش؟ ل bio diesel و أشهرها زيت 
+
+516
+00:47:00,740 --> 00:47:08,350
+اسمه الجاتروفة Gatrofa Oil أشرب هذه الزيوت .. زيت
+
+517
+00:47:08,350 --> 00:47:13,010
+بنسميه إيش؟ زيت الجاتروفا فلاحظوا أنتوا كيف منطق
+
+518
+00:47:13,010 --> 00:47:17,350
+التفكير و منطق حل المشكلة في العلم أنه أنا فهمت
+
+519
+00:47:17,350 --> 00:47:22,450
+بداية .. أنه أنا فهمت بداية أن الحرارة بتجيني من
+
+520
+00:47:22,450 --> 00:47:29,170
+حرق هذا واضح؟ الحرارة بتجيني من حرق هذا لكن هذا 
+
+521
+00:47:29,170 --> 00:47:34,090
+موجود مع مركب تاني سام لما فصلته من الصين صار 
+
+522
+00:47:34,090 --> 00:47:37,370
+بإمكاني أخد هذا و أسميه biodiesel و أحرب ولا لأ 
+
+523
+00:47:37,370 --> 00:47:44,590
+الان ضايقلي عشرين ثانية أحكيهم عارفين شو هم؟
+
+524
+00:47:44,590 --> 00:47:52,180
+العشرين ثانية اللي بدنا نحكيهم و نخلص العشرين ثانية 
+
+525
+00:47:52,180 --> 00:47:56,160
+اللي بنحكيهم و بنخلص القاتل اتخيلوا لو أخدتوا هذا
+
+526
+00:47:56,160 --> 00:48:03,780
+ال Easter و حطيتوا هنا سلسلة طويلة و حطيتوا هنا
+
+527
+00:48:03,780 --> 00:48:11,850
+كمان سلسلة طويلة هذه السلاسل ايش بتعمل؟ بتولع مع ال 
+
+528
+00:48:11,850 --> 00:48:17,110
+Oxygen و بتعطي حرارة و إضاءة و إشي هذه المركبات ال
+
+529
+00:48:17,110 --> 00:48:22,090
+E Stars اللي فيها سلسلة طويلة يمين و سلسلة طويلة
+
+530
+00:48:22,090 --> 00:48:30,910
+الشمال عارفين هي إيش؟ هي الشمع ال wax الان أنا لما 
+
+531
+00:48:30,910 --> 00:48:37,390
+بولع الشمع حقيقة إيش بولع؟ السلاسل الألفاتية 
+
+532
+00:48:40,000 --> 00:48:45,380
+وبهك بيكون يعرفنا إيش هو الشمع الشمع هو Easter لكن
+
+533
+00:48:45,380 --> 00:48:50,160
+هذا ال Easter بسلسلتين كبار هانا وإحنا عرفنا إنه 
+
+534
+00:48:50,160 --> 00:48:55,180
+هذه السلاسل لما بتولع هي اللي بتعطينا شوية الحرارة
+
+535
+00:48:55,180 --> 00:48:57,880
+و ثاني أكسيد الكربون و الميه مش مهمين أهم شيء 
+
+536
+00:48:57,880 --> 00:49:02,720
+الحرارة و الإضاءة واضح؟ فلو قلنا لكم إيش ال wax
+
+537
+00:49:02,720 --> 00:49:12,010
+بالظبط ال wax are أو الواكس هم أسطارين مع شبكات 
+
+538
+00:49:12,010 --> 00:49:16,370
+طويلة أو شبكات ألفاتية طويلة يعني اللي بيميزهم 
+
+539
+00:49:16,370 --> 00:49:21,530
+الشبكات الطويلة الشبكات الألفاتية وكلنا عارفين
+
+540
+00:49:21,530 --> 00:49:25,810
+الان الشبكات الألفاتية إيش بنعمل فيها هي اللي
+
+541
+00:49:25,810 --> 00:49:30,250
+بنولعها و بتعطينا الطاقة هي اللي بنولعها و بتعطينا
+
+542
+00:49:30,250 --> 00:49:34,850
+الطاقة فبكون هذا هو إيش الشمال فلاحظوا كيف أنا
+
+543
+00:49:34,850 --> 00:49:41,570
+استفدت من ال sealage كوقود كيف أنا استفدت كمان من
+
+544
+00:49:41,570 --> 00:49:46,710
+ال wax أنه أولعه و يطلعلي حرارة من خلال أنه أنا 
+
+545
+00:49:46,710 --> 00:49:50,110
+بستفيد من التفاعل الأصلي اللي أخدته في شبتر واحد
+
+546
+00:49:50,110 --> 00:49:55,350
+أنه الألكيز بتحض مع ال oxygen و ال combustion
+
+547
+00:49:55,350 --> 00:49:58,630
+طلعوا ثانو أكسيد كربون و ميه و حرارة 
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d63786d546ffad1946dfdf895f0101f76e774594
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.srt
@@ -0,0 +1,2208 @@
+1
+00:00:19,570 --> 00:00:26,370
+بسم الله الرحمن الرحيم اليوم ضيلنا أشياء بسيطة في
+
+2
+00:00:26,370 --> 00:00:30,890
+موضوع ال amines قبل ما ننتقل لجزء ال biochemistry
+
+3
+00:00:30,890 --> 00:00:36,850
+طبعا اتفقنا المرة الماضية أن ال amines هم مراكبات
+
+4
+00:00:36,850 --> 00:00:43,470
+ال nitrogen من أهم الأشياء اللي بتميزهم هو وجود
+
+5
+00:00:43,470 --> 00:00:47,730
+إيشالـ lone pair of electrons اللي موجودة على الـ
+
+6
+00:00:47,730 --> 00:00:52,910
+Nitrogens طالما في عليهم lone pair of electrons و
+
+7
+00:00:52,910 --> 00:00:56,150
+ال base is electron donor يعني ال base هي اللي
+
+8
+00:00:56,150 --> 00:01:02,370
+بتعطي إلكترونات فال amines arebasis واضح سبب أنه
+
+9
+00:01:02,370 --> 00:01:06,730
+بالأمينز قواعد هو وجود أزواج الإلكترونات فهم
+
+10
+00:01:06,730 --> 00:01:11,010
+كقاعدة بيعطوا أزواج إلكترونات هذا ضمن تعريف إيش
+
+11
+00:01:11,010 --> 00:01:19,710
+Lewis definition الآن لو إجالهم H plus عندي زوج
+
+12
+00:01:19,710 --> 00:01:23,270
+إلكترونات والـ H مش حاملة إلكترونات شو هيعملوا
+
+13
+00:01:23,270 --> 00:01:28,420
+فيها؟هيتفاعلوا معها هتصير الرابط المتكونة
+
+14
+00:01:28,420 --> 00:01:31,840
+Coordinated Covalent bond بمعنى ان زوجين
+
+15
+00:01:31,840 --> 00:01:37,940
+الالكترونات من النيتروجين والـ H بلس لما تتفاعل
+
+16
+00:01:37,940 --> 00:01:43,340
+معها بتكون مش حاملة الالكترونات ولذلك مثلا هنا
+
+17
+00:01:43,340 --> 00:01:48,380
+ارسملكوا كيف الأمونيا لو اتفاعل معها H بلس لاحظوا
+
+18
+00:01:48,380 --> 00:01:52,990
+الأمونيا الأن H3أساساً الـNitrogen في مداره
+
+19
+00:01:52,990 --> 00:01:57,070
+الخارجي خمس إلكترونات، فلو تخيلتم اللي كانوا
+
+20
+00:01:57,070 --> 00:02:00,470
+باللون الأزرق، تلاتة منهم عملوا روابط مع
+
+21
+00:02:00,470 --> 00:02:03,670
+الـHydrogen، فهذه الرابطة مع الـHydrogen في
+
+22
+00:02:03,670 --> 00:02:07,510
+الأمونيا أصلاً، إلكترون من الـNitrogen وإلكترون من
+
+23
+00:02:07,510 --> 00:02:11,040
+الـHydrogen، اللي بيانه بالأخضركذلك الرابط الثاني
+
+24
+00:02:11,040 --> 00:02:15,520
+والرابط الثالثة بقى عندي زوج إلكترونات إجاله H من
+
+25
+00:02:15,520 --> 00:02:21,180
+الخارج الـH إجت بدون إلكترونات بناء على ذلك الرابط
+
+26
+00:02:21,180 --> 00:02:24,560
+اللي هنا إيش بده تصير Coordinate Covalent bond
+
+27
+00:02:24,560 --> 00:02:29,460
+بمعنى أصلها أنه two electrons from the nitrogen
+
+28
+00:02:29,460 --> 00:02:35,300
+and no electron from hydrogen طبعا هذا بيخلي برضه
+
+29
+00:02:35,300 --> 00:02:41,700
+ال aminesباسيز بمفهوم لوري برونستيد definition
+
+30
+00:02:41,700 --> 00:02:47,240
+ليش؟ لأنه بمفهومه إن الحامض هو اللي بيعطي H plus
+
+31
+00:02:47,240 --> 00:02:53,180
+والباس هي اللي بتكتسب H plus الآن هذه اكتسبت H
+
+32
+00:02:53,180 --> 00:02:57,600
+plus ولا لأ؟ إذا أيضا ضمن تعريف لوري برونستيد
+
+33
+00:02:57,600 --> 00:03:03,860
+definition بتكون هذه base لكن لاحظوا ضمن تعريف
+
+34
+00:03:03,860 --> 00:03:09,080
+Arrheniusإن الـ base لازم يكون فيها OH- الأمونية
+
+35
+00:03:09,080 --> 00:03:13,420
+ما انحسبتش base و لذلك اتدرجوا في تعريفية الأحماض
+
+36
+00:03:13,420 --> 00:03:17,740
+يعني كان أقدم تعريف Arrhenius depression كان حاصر
+
+37
+00:03:17,740 --> 00:03:22,280
+ال bases في المواد ال hydroxides اللي بيعطوا ال OH
+
+38
+00:03:22,280 --> 00:03:29,060
+- بعد إكسرنا نقول لأ هو كل حاجة بتكتسب H plus يمكن
+
+39
+00:03:29,060 --> 00:03:33,960
+أننا نعتبرها base أساسا ال OH- كانت تكتسب H plus و
+
+40
+00:03:33,960 --> 00:03:39,160
+تعمل ميهواضح طب ما الأن H3 كمان بتكتسب جعب H plus
+
+41
+00:03:39,160 --> 00:03:47,280
+واضح الفكرة وإجا اللي هو Lewis definition أكتر
+
+42
+00:03:47,280 --> 00:03:51,440
+تخصيصا وقال أن ال base اللي فيه أزواج إلكترونات
+
+43
+00:03:51,440 --> 00:03:55,340
+مافيش تناقض ما بين التعريفات لكن فيه نظرة أكتر
+
+44
+00:03:55,340 --> 00:04:00,790
+تخصيصيةالان عشانك لو حطينا ال ammonia مع الميه
+
+45
+00:04:00,790 --> 00:04:05,510
+طبعا الميه هنا حاطين ال H3O plus كلكوا عارفين ان
+
+46
+00:04:05,510 --> 00:04:11,070
+الميه ايش هي أساسا H2O لكن هو اتخيل نسبة التأيون
+
+47
+00:04:11,070 --> 00:04:17,430
+اللي هي بسيطة جدا اللي درستها في الميه ان H2O زائد
+
+48
+00:04:17,430 --> 00:04:23,450
+H2O بتفاعل اتزان بطلع نسبة بسيطة جدا من H3O plus
+
+49
+00:04:23,450 --> 00:04:30,600
+زائد OH minusعشان يك هو لما هنا بيكتب h3o plus
+
+50
+00:04:30,600 --> 00:04:36,820
+هالنسبة البسيطة جدا اللي اتكونت من يعني تفاعل
+
+51
+00:04:36,820 --> 00:04:41,950
+الميه مع بعضها، اذا هنا ايش بتفترض انه موجود؟هو H
+
+52
+00:04:41,950 --> 00:04:46,770
+minus كمان ولذلك لما تيجي الأمونيا من الميه هدم ال
+
+53
+00:04:46,770 --> 00:04:52,590
+H3O plus تاخد ال H plus تعمل ان H4 plus زاد H2O هو
+
+54
+00:04:52,590 --> 00:04:57,370
+أساسا في ايون موجب بكل حاله لأ هو الموجب كان معاه
+
+55
+00:04:57,370 --> 00:05:02,330
+سالب الآن لما صارت الأمونيوم ايون هانا موجب ايش
+
+56
+00:05:02,330 --> 00:05:07,500
+صار معاه؟سالم و لذلك احنا سنقول ان الامونيا لما
+
+57
+00:05:07,500 --> 00:05:14,600
+ندوبها في الميه بتعطي امونيوم هيدروكسيد واضح؟ الكل
+
+58
+00:05:14,600 --> 00:05:19,220
+بيعرف ان احنا بندوب الامونيا في الميه بتعطي ايش؟
+
+59
+00:05:19,220 --> 00:05:23,750
+امونيوم هيدروكسيدكذلك الحالة لو دوبنا ال ammonia
+
+60
+00:05:23,750 --> 00:05:29,390
+مثلا في ال HCl ال ammonia هتاخد H من هنا هصير عندى
+
+61
+00:05:29,390 --> 00:05:34,510
+ammonium ion مع ال Cl minus ammonium chloride يمكن
+
+62
+00:05:34,510 --> 00:05:39,130
+هذا ما معاكم في المدرسة انه بإمكاننا احنا نجيب
+
+63
+00:05:39,130 --> 00:05:44,180
+نقطةمن ال ammonia من محلول ال ammonia نحطها هنا
+
+64
+00:05:44,180 --> 00:05:49,760
+نقطة من ال HCl نحطه هنا و نسيبهم جانب بعض بتتبخر
+
+65
+00:05:49,760 --> 00:05:53,860
+.. بتتبخر ال ammonia بتتبخر ال HCl لما يلتجوا مع
+
+66
+00:05:53,860 --> 00:05:57,620
+بعض ال ammonia مع ال HCl شو هيعملوا؟ ammonium
+
+67
+00:05:57,620 --> 00:06:02,660
+chloride ال ammonium chloride إيش لونه؟
+
+68
+00:06:02,660 --> 00:06:08,310
+تذكروا شغل المدرسة؟أبيض و لذلك كنا نقول أنه ال
+
+69
+00:06:08,310 --> 00:06:12,810
+ammonia مع ال HCl بيعطوا سحب بيضاء من ال ammonium
+
+70
+00:06:12,810 --> 00:06:18,820
+chloride بهذا النص مرت عليكم في المدرسة ولا لأ؟سحب
+
+71
+00:06:18,820 --> 00:06:23,780
+.. سحب بيضاء أو بقعة بيضة هم عادة بيعملوها .. عادة
+
+72
+00:06:23,780 --> 00:06:28,660
+بيعملوا هذه الشغلة كتجربة .. كتجربة بيجيبوا انبوبة
+
+73
+00:06:28,660 --> 00:06:32,500
+بهذا الشكل بيجيبوا انبوبة زجاجية مفتوحة الطرفين
+
+74
+00:06:32,500 --> 00:06:38,270
+بهذا الشكل بيحطوا هنا نقطة أمونياو بيحطوا هان طبعا
+
+75
+00:06:38,270 --> 00:06:41,090
+أمونيا البعض هيقوللي غاز أمونيا مدور باب ميه
+
+76
+00:06:41,090 --> 00:06:44,970
+أمونيا ميكروفسيت بيطلع أمونيا واضح؟ و بيحطوا هنا
+
+77
+00:06:44,970 --> 00:06:49,430
+HCl الآن بيمشوا بتبخر الغازين هذا بتبخر و هذا
+
+78
+00:06:49,430 --> 00:06:53,570
+بتبخر و سرعته بتعتمد على ال molecular weight تبعه
+
+79
+00:06:53,570 --> 00:06:58,050
+اللي ال molecular weight تبعه الجيل بيمشي إيش بطيء
+
+80
+00:06:58,050 --> 00:07:00,890
+فهذا بيمشي له شوية هنا هذا بيمشي له شوية هنا لما
+
+81
+00:07:00,890 --> 00:07:05,280
+بيلتقواإيش بدهم يعملوه اموريو ميكلورايت فجأة
+
+82
+00:07:05,280 --> 00:07:09,640
+بيصيروا الناس يشوفوا هنا إيش ابخرة بيضاء واضح
+
+83
+00:07:09,640 --> 00:07:15,310
+بيصيروا يشوفوا ابخرة بيضاء هذه الأبخرة هيالأمونيوم
+
+84
+00:07:15,310 --> 00:07:19,250
+كلورايت لو انتوا بتاخدوا معمل general chemistry
+
+85
+00:07:19,250 --> 00:07:22,410
+بتكون تجربة بتعملواها بتجيبوا الأنبوبة و بتحطوهم
+
+86
+00:07:22,410 --> 00:07:27,450
+بتشوفوا بعينكم و عشان دائما بنقول التعليم الجامعي
+
+87
+00:07:27,450 --> 00:07:32,150
+لا يجب أن ينفصل بحال من الأحوال اللي عاملة عن
+
+88
+00:07:32,150 --> 00:07:36,290
+الجزء النظري في أي خطة تدريسية
+
+89
+00:07:40,010 --> 00:07:45,710
+طالما قلنا ان ال amines are bases معناه ذلك زي ما
+
+90
+00:07:45,710 --> 00:07:50,130
+ال acids كنا نقول عنهم acids ويلهم BKA ال amines
+
+91
+00:07:50,130 --> 00:07:57,350
+بيكونيلهم BKB واضح؟ BKB وقلنا كل ما كانت في ال
+
+92
+00:07:57,350 --> 00:08:02,150
+acids ال BKA أقل كل ما كان الحامض أقوى الآن في ال
+
+93
+00:08:02,150 --> 00:08:07,530
+bases بنقول كل ما ال BKB بتكون أقل كل ما القاعدة
+
+94
+00:08:07,530 --> 00:08:12,460
+أيضا بتكون أقوى واضح؟الجدول اللى موجود عندنا حقيقة
+
+95
+00:08:12,460 --> 00:08:22,240
+مش كاتبنا ال BKB كاتب ال BKA ل ال conjugate acid
+
+96
+00:08:22,240 --> 00:08:26,700
+conjugate acid يعني الحمض المرافق عادة بين ال acid
+
+97
+00:08:26,700 --> 00:08:32,620
+و ال base المرافقة بيكون الفرق إيش؟هيدروجين يعني
+
+98
+00:08:32,620 --> 00:08:38,560
+انا لما بدي اقول nh4 plus هذا الاسل ال base
+
+99
+00:08:38,560 --> 00:08:45,500
+المرافقة nh3 و هكذا بناء على ذلك هدولة اللي بيكي
+
+100
+00:08:45,500 --> 00:08:53,100
+ايه و بيكي بيه كلنا عارفين ان بيكي ايهزائد ال BKB
+
+101
+00:08:53,100 --> 00:08:59,420
+بساوي 14 بناء على ذلك لو احنا كنا لهذه المجموعة من
+
+102
+00:08:59,420 --> 00:09:07,300
+ال Amines بدنا نشوف ال BKB بدنا نطرح من 14 يعني
+
+103
+00:09:07,300 --> 00:09:13,900
+مثلا لل Ammonia ال BKB أربعة و سبعة للميث الأمين
+
+104
+00:09:15,270 --> 00:09:21,390
+تلاتة و أربعة بالعشرة نفترض للضايف مثل أميل تلاتة
+
+105
+00:09:21,390 --> 00:09:25,870
+و تلاتة بالعشرة لو أجينا مقارنة مثلا مع الأنليل
+
+106
+00:09:25,870 --> 00:09:34,290
+حوالي تسعة و أربعة بالعشرةالان لو اجينا للان مثل
+
+107
+00:09:34,290 --> 00:09:40,410
+الأللين ايضا حوالي تسعة و اتنين بالعشرة الان
+
+108
+00:09:40,410 --> 00:09:46,010
+لاحظوا ع طول ملاحظة الأمينز اللي في الأول مثل أمين
+
+109
+00:09:46,010 --> 00:09:51,890
+ضاي مثل أمين و لحد الأللين هنا صار عندى تغير كتير
+
+110
+00:09:51,890 --> 00:09:57,550
+يعني لحد هدولة كلهمكانت ال بي كي بي قليلة تلاتة
+
+111
+00:09:57,550 --> 00:10:03,130
+تلاتة أربعة لما صرت فيه الانليل و التوابع صرت تسعة
+
+112
+00:10:03,130 --> 00:10:09,030
+الان هدول ايش بيفرقوا عن بعض لحد هذا الخط هدول
+
+113
+00:10:09,030 --> 00:10:14,510
+اللي فوق aliphatic amines اللي تحت aromatic amines
+
+114
+00:10:14,510 --> 00:10:22,190
+واضح؟ اذا هذه منطقاتالالفاتك أمين هذي منطقة ال
+
+115
+00:10:22,190 --> 00:10:27,870
+aromatic amines لو إجينا سألنا مين بيكونوا ك basis
+
+116
+00:10:27,870 --> 00:10:33,430
+أقوى الالفاتك أمين ولا ال aromatic amines؟
+
+117
+00:10:33,430 --> 00:10:40,000
+الالفاتك أمينليش؟ لأنه كل ما ال BKB بتكون أقل كل
+
+118
+00:10:40,000 --> 00:10:45,500
+ما كانت القاعدة أقوى، إذا ال aliphatic amines are
+
+119
+00:10:45,500 --> 00:10:50,460
+stronger bases than aromatic amines، يعني لما نجيب
+
+120
+00:10:50,460 --> 00:10:54,740
+ال QA سؤال صح و غلط ال aliphatic amines are فراغ
+
+121
+00:10:54,740 --> 00:11:00,120
+bases than aromatic amines، they arestronger basis
+
+122
+00:11:00,120 --> 00:11:05,660
+هذا عرفناها، الآن بعد كمان ممكن نكمل لكم، نقولكم
+
+123
+00:11:05,660 --> 00:11:14,120
+إيش ال due to بسبب إيش؟ ليش بدنا نحكي غلط؟ بدنا
+
+124
+00:11:14,120 --> 00:11:19,180
+نحكي غلط؟ ليش ال aliphatic a means
+
+125
+00:11:22,420 --> 00:11:27,220
+أقوى كقواعد من ال aromatic amines بهمش بدي أعلق
+
+126
+00:11:27,220 --> 00:11:32,260
+على الخطأ اللي عملته بدي أعلق على الخطأ اللي عملته
+
+127
+00:11:32,260 --> 00:11:38,140
+عشان ما تكرروهش رجاء انا لما بقول انه بسبب فواحدة
+
+128
+00:11:38,140 --> 00:11:44,020
+جالتلي ع طول بسبب ال BKB هذا الكلام غير بقبول منكم
+
+129
+00:11:44,020 --> 00:11:48,400
+انا لما قرأت ال BKB
+
+130
+00:11:50,390 --> 00:11:54,430
+لقيت هذه جليلة و هذه عالية قولت ال aromatic amines
+
+131
+00:11:54,430 --> 00:12:00,510
+أقوى من ال aromatic amines زي ما أجي على اتنين بني
+
+132
+00:12:00,510 --> 00:12:04,830
+أدمين أطفال against طولهم هذا طوله متر و هذا طوله
+
+133
+00:12:04,830 --> 00:12:10,750
+سبعين الآن اللي طوله متر بقول عنه أطول من اللي
+
+134
+00:12:10,750 --> 00:12:15,230
+طوله سبعين الان لما أقولكم ليش ماحدش يقوللي أنه
+
+135
+00:12:15,230 --> 00:12:20,930
+طوله مترthis is nonsense ممكن تقولولي لأنه في
+
+136
+00:12:20,930 --> 00:12:25,730
+العمر أكبر يمكن يكون هذا السبب هذا بيصير سبب لو
+
+137
+00:12:25,730 --> 00:12:29,670
+اتنين بنفس العمر ممكن تقولولي وراثيا هذا كل أسر
+
+138
+00:12:29,670 --> 00:12:33,750
+تطويل هذا أسر .. هيك بيصير سبب بس إن أجيب لقياسه
+
+139
+00:12:33,750 --> 00:12:38,410
+وأقول عنه سبب بسبب ال BKB لو أنا أساسا استنتجت أن
+
+140
+00:12:38,410 --> 00:12:43,790
+هذا أقوى من هذا لأن ال BKB هنا أقل من هنا إذا هذا
+
+141
+00:12:43,790 --> 00:12:44,270
+أقوى
+
+142
+00:12:47,630 --> 00:12:55,650
+بدي كلام إيش؟ بدي كلام كيمية طبعا معنى بيس إنه
+
+143
+00:12:55,650 --> 00:12:59,650
+بتعطي إلكترونات إذا للسبب شيء يمنع من إعطاء
+
+144
+00:12:59,650 --> 00:13:06,400
+الإلكترونات أو يقلل إعطاء الإلكترونات، واضح؟السبب
+
+145
+00:13:06,400 --> 00:13:10,740
+شيء يمنع أو يقلل من إعطاء الإلكترونات هذا السبب
+
+146
+00:13:10,740 --> 00:13:14,400
+فعلا ممكن يكون inductive effect و فعلا ممكن يكون
+
+147
+00:13:14,400 --> 00:13:18,980
+resonance effect في حالة ال aliphatic amines وهي
+
+148
+00:13:18,980 --> 00:13:23,820
+بالقاري المركبين بيشيبوا بعض القليلين مثلا ال BKA
+
+149
+00:13:23,820 --> 00:13:27,740
+تبعت الحامض المرافق له أربعة و ستة يعني ال BKB
+
+150
+00:13:27,740 --> 00:13:33,980
+تبعته جداشتسعة وأربعة هانا لل .. لل Cyclohex
+
+151
+00:13:33,980 --> 00:13:39,400
+الأمين، هذا ألفتك، مافي double bonds، Cyclic
+
+152
+00:13:39,400 --> 00:13:43,700
+alkanes are ألفتك، هذا كدهش؟ أربعة واتنين، مين
+
+153
+00:13:43,700 --> 00:13:48,730
+كباس أقوى؟ ال Cyclohex الأمين ولا الألليين؟الـ
+
+154
+00:13:48,730 --> 00:13:53,770
+Cyclohexane الأمين أقوى الآن السبب أن هذا زوج
+
+155
+00:13:53,770 --> 00:13:58,830
+الإلكترونات بدل ما يكون جاهز يطلع برا و يتفاعل برا
+
+156
+00:13:58,830 --> 00:14:04,310
+قاعد بيعمل resonance جوا الجزء هذا زوج الإلكترونات
+
+157
+00:14:04,310 --> 00:14:09,660
+بيطلع للخارججاهز إنه يُعطى للخارج و ال base هي
+
+158
+00:14:09,660 --> 00:14:15,220
+اللي بتعطي إيش إلكترونات فهذا بدل ما يروح للخارج و
+
+159
+00:14:15,220 --> 00:14:20,640
+يظهر قوة المركب ك base قاعد بيجي بلوف هنا و بيعمل
+
+160
+00:14:20,640 --> 00:14:24,360
+resonance .. resonance تاني بيصير مرة minus على ال
+
+161
+00:14:24,360 --> 00:14:26,420
+carbon مرة على ال carbon التاني مرة على ال carbon
+
+162
+00:14:26,420 --> 00:14:32,020
+التالتة إذا هو قاعد المجهود تبع وين؟ جوا الجزء
+
+163
+00:14:32,020 --> 00:14:37,990
+فبالنسبة للخارجهو لا يعطي إلكترونات هو قاعد بيعمل
+
+164
+00:14:37,990 --> 00:14:41,990
+resonance جوا الجزئ فما بيعطي إلكترونات للخارج ال
+
+165
+00:14:41,990 --> 00:14:46,870
+basic اللي بتعطي إلكترونات لمن؟ للخارج هذا إذا
+
+166
+00:14:46,870 --> 00:14:51,650
+بيكون سبب .. هذا بيكون سبب اللي هو ليش ال alphatic
+
+167
+00:14:51,650 --> 00:14:54,850
+amines are more basic than aromatic amines because
+
+168
+00:14:54,850 --> 00:15:01,710
+of resonance تمام؟ الآن البعض منكم اتكلم كلمة جيدة
+
+169
+00:15:01,710 --> 00:15:08,080
+قال ال inductive effectممكن يكون في مكان تاني غير
+
+170
+00:15:08,080 --> 00:15:12,840
+هذا الان حتى نفهم ال inductive effect حتى نفهم ال
+
+171
+00:15:12,840 --> 00:15:18,200
+inductive effect جيدا انتوا بتكونوا تتخيلوا
+
+172
+00:15:18,200 --> 00:15:26,720
+نيتروجين و عليها زوج إلكترونات و تلت روابط تمام؟
+
+173
+00:15:26,720 --> 00:15:32,040
+إيش اللي ممكن يزيد القاعدية تبعتها و إيش اللي ممكن
+
+174
+00:15:32,040 --> 00:15:41,510
+ينجس؟أي مجموعة تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+175
+00:15:41,510 --> 00:15:48,750
+تقدر تقدر تقدر
+
+176
+00:15:48,750 --> 00:15:49,430
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+177
+00:15:49,430 --> 00:15:49,450
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+178
+00:15:49,450 --> 00:15:49,570
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+179
+00:15:49,570 --> 00:15:49,690
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+180
+00:15:49,690 --> 00:15:49,710
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+181
+00:15:49,710 --> 00:15:53,850
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+182
+00:15:53,850 --> 00:16:02,860
+تقدر تقدر تincreases basicity لأنه زدت كمية
+
+183
+00:16:02,860 --> 00:16:12,420
+الإلكترونات increases او increase basicity الان لو
+
+184
+00:16:12,420 --> 00:16:18,380
+كان عندى electron with drawing groups with drawing
+
+185
+00:16:18,380 --> 00:16:24,220
+مجموعات ساحبة للإلكترونات يعني إذا أنا عندى كمية
+
+186
+00:16:24,220 --> 00:16:28,740
+الإلكترونات إجت أشياء ساحبتهاإيش هيعمله في ال
+
+187
+00:16:28,740 --> 00:16:37,240
+basicity؟ decrease basicity واضحة الفكرة المجموعات
+
+188
+00:16:37,240 --> 00:16:41,300
+المعطية للإلكترونات بتزيد كمية الإلكترونات بتزيد
+
+189
+00:16:41,300 --> 00:16:46,080
+الإعقاء بتزيد القاعدية المجموعات الساحبة تقلل كمية
+
+190
+00:16:46,080 --> 00:16:50,640
+الإلكترونات تقلل ما يُعطى للخارج وبالتالي تقلل
+
+191
+00:16:50,640 --> 00:16:55,480
+إيش؟ القاعدية واضحة هذه الفكرة؟ واضحة؟
+
+192
+00:17:01,610 --> 00:17:06,190
+طبعا هتلاحظوا القمر هنا عكس ايش ال acidity للناس
+
+193
+00:17:06,190 --> 00:17:12,530
+اللي بدهم ينتبهوا ويعملوا مقارنة خلينا نعطي مثال
+
+194
+00:17:12,530 --> 00:17:21,590
+لو اجيت انا اعطيت هدولة المثالين F الأمين لاحظوا
+
+195
+00:17:21,590 --> 00:17:27,020
+هاي ال F الأمين وين زوج ال electronic اللي عليهعلى
+
+196
+00:17:27,020 --> 00:17:35,580
+الـ Nitrogen و أعطيت Chloroethelamine هاي
+
+197
+00:17:35,580 --> 00:17:41,040
+أنا فيه الاتنين Aliphatic واضح بطلت الفكرة
+
+198
+00:17:41,040 --> 00:17:44,800
+Aliphatic و Aromatic الاتنين إيش مالهم؟ Aliphatic
+
+199
+00:17:44,800 --> 00:17:50,160
+مين بدو يكون stronger base بالتجربة الـ Ethelamine
+
+200
+00:17:50,160 --> 00:17:57,430
+أقوى من الchloroethelamine الآن إيش السبب؟اه هنا
+
+201
+00:17:57,430 --> 00:18:03,010
+في عندى CL، إيش بتعمل ال CL في الإلكترونات؟ بتسحب
+
+202
+00:18:03,010 --> 00:18:06,810
+الإلكترونات، يعني لو افترضتوا كانت كمية
+
+203
+00:18:06,810 --> 00:18:10,870
+الإلكترونات كرقم عشوائي، هنا عشرة، ال CL سحبت إلى
+
+204
+00:18:10,870 --> 00:18:14,190
+منهم اتنين، صف يوجد إيش؟ تمانية، إذا وين
+
+205
+00:18:14,190 --> 00:18:20,630
+الإلكترونات أكثر؟أه بينما لاحظ لو إجيت أنا حطيت
+
+206
+00:18:20,630 --> 00:18:24,730
+مثل و مثل بيعطوا إلكترونات شو بده يصير لل BCCT؟
+
+207
+00:18:24,730 --> 00:18:31,290
+بده يزيد إذا المجموعات الساحبة تقلل القاعدية
+
+208
+00:18:31,290 --> 00:18:36,530
+والمجموعات المعطية تزيد القاعدية طبعا بشرط إنكوا
+
+209
+00:18:36,530 --> 00:18:40,550
+لما تعملوا المقارنات قارنوا أشياء متحدة من جوانب
+
+210
+00:18:40,550 --> 00:18:44,210
+أخرى يعني أنا لما عملت هذه المقارنة ساحب ومعطي
+
+211
+00:18:44,210 --> 00:18:49,850
+قارنت ألفتكممكن اكرر العملية اقارن aromatic مع
+
+212
+00:18:49,850 --> 00:18:56,350
+aromatic يعني لو اخدت الانيلين والنيتروانيلين
+
+213
+00:18:56,350 --> 00:19:02,830
+والميثلانيلين اللي هو البراتوليدين اسمه الآن هدول
+
+214
+00:19:02,830 --> 00:19:06,150
+التلاتة فيهم resonance إذا ال resonance مش هيكون
+
+215
+00:19:06,150 --> 00:19:10,030
+هو السبب وهدول التلاتة القاعدية تبعتهم من ناحية
+
+216
+00:19:10,030 --> 00:19:12,550
+المبدأ قليلة
+
+217
+00:19:13,930 --> 00:19:17,630
+ليش؟ لأنه فيهم resonance لكن في القاعدية القليلة
+
+218
+00:19:17,630 --> 00:19:20,850
+واحد منهم أقل من التاني أقل من التالت يعني التلاتة
+
+219
+00:19:20,850 --> 00:19:27,310
+ك basis إضعاف لكن في واحد أفضل من التاني أفضل من
+
+220
+00:19:27,310 --> 00:19:31,970
+التالت الآن خلّينا نيجي نتطلع المثل كمجموعة شو
+
+221
+00:19:31,970 --> 00:19:37,890
+بتعمل؟ بتعطي إلكترونات إذا معنا الإلكترونات بـ 0
+
+222
+00:19:37,890 --> 00:19:44,130
+الـ H نعتبرها متعادلة الـ Nitroبتسحب، إذا وين أعلى
+
+223
+00:19:44,130 --> 00:19:51,430
+الإلكترونات؟ في الميثلانيلين، بعده الانيلين، بعده
+
+224
+00:19:51,430 --> 00:19:57,870
+النيترو، فك basis الميثلانيلين أعلى من الانيلين،
+
+225
+00:19:57,870 --> 00:20:02,350
+أعلى من النيتروانيلين، الآن هنا لما ابدأ أقول شو
+
+226
+00:20:02,350 --> 00:20:10,330
+السبب؟ ال inductive effectطبعاً بشكل عام كلهم
+
+227
+00:20:10,330 --> 00:20:17,630
+يعتبروا ضعاف، ليش؟ لأن كلهم فيهم resonance، كلهم
+
+228
+00:20:17,630 --> 00:20:21,050
+يعتبروا ك basis ضعاف، لكن واحد أضعف من التاني أضعف
+
+229
+00:20:21,050 --> 00:20:26,610
+من التالت، الأن فرق الضعف اللي بين لضعاف أساساً
+
+230
+00:20:26,610 --> 00:20:31,670
+بسبب إيش؟ ال inductive effectلكن لو أنا باجي
+
+231
+00:20:31,670 --> 00:20:38,370
+بسألكم والله بشكل عام ال nitroaniline is a weak
+
+232
+00:20:38,370 --> 00:20:45,560
+base، ليش؟ هتقولولي ال resonance مصيبة؟و الحاجات
+
+233
+00:20:45,560 --> 00:20:50,980
+هم صيبة تانية ال nitro يعني صار سبب ضعفه شغل فيه
+
+234
+00:20:50,980 --> 00:20:55,280
+ال resonance و ال inductive effect لكن لو كنت بدأ
+
+235
+00:20:55,280 --> 00:20:58,500
+اقارنه مثلا مع ال methyl aniline لأ بقول ما هو ال
+
+236
+00:20:58,500 --> 00:21:01,720
+resonance و ال resonance هم عامل مشترك بطل هو اللي
+
+237
+00:21:01,720 --> 00:21:07,920
+مفرج صار إيش اللي مفرج؟ شكل أساسي ال inductive
+
+238
+00:21:07,920 --> 00:21:09,940
+effect واضحة الفكرة؟
+
+239
+00:21:17,860 --> 00:21:23,620
+أخر شغلة في هذا الفصل، لو قلنا تفاعلات الـ Amines،
+
+240
+00:21:23,620 --> 00:21:28,240
+تفاعلات الـ Amines مروا علينا بدل المر ألف طالما
+
+241
+00:21:28,240 --> 00:21:33,140
+في زوج إلكترونات، إذا الـ Amines بيعملوا as الـ
+
+242
+00:21:33,140 --> 00:21:39,880
+Eucleophiles، واضح؟إذا بدكم تحكوا عن الكليهيليتز،
+
+243
+00:21:39,880 --> 00:21:44,120
+بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن الديهيد
+
+244
+00:21:44,120 --> 00:21:48,260
+وكيتون، بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن
+
+245
+00:21:48,260 --> 00:21:52,660
+كاربوكسيليك أسيتس ومشتقاتها، بتفعلوا كنيكليوفييل،
+
+246
+00:21:52,660 --> 00:21:56,280
+وكل الأمثلة مرت علينا، الآن مع الالكليهيليتز
+
+247
+00:21:56,280 --> 00:22:00,700
+بيعملوا النيكليوفيليك سبستيوشن، مع الديهيدس وكيتون
+
+248
+00:22:01,680 --> 00:22:06,140
+بيعملوه الـ Eucleophilic addition مع الـ E stars
+
+249
+00:22:06,140 --> 00:22:10,340
+ومشتقاتها بيعملوه مرة تانية الـ Eucleophilic
+
+250
+00:22:10,340 --> 00:22:14,900
+substitution يعني هاي نشوف عدة أمثلة هاي هذا أمين
+
+251
+00:22:14,900 --> 00:22:20,260
+RNH2 مع أسد الكلورايد هاي الـ Eucleophile هاجم طرد
+
+252
+00:22:20,260 --> 00:22:24,360
+الـ Cl هذا عبارة عن إيش الـ Eucleophilic
+
+253
+00:22:24,360 --> 00:22:29,520
+substitution على أسد الكلورايد هذا primary أمين طب
+
+254
+00:22:29,520 --> 00:22:33,230
+لو secondary أمينبرضه الـ Eucleophilic
+
+255
+00:22:33,230 --> 00:22:38,230
+Substitution على أسد إكلورايد مافيش فيها إشي لو
+
+256
+00:22:38,230 --> 00:22:41,710
+شوفناه مُركّب تاني برضه هذا سكندريامين مع أسد
+
+257
+00:22:41,710 --> 00:22:46,590
+إكلورايد الـ Eucleophilic Substitution لو شوفنا
+
+258
+00:22:46,590 --> 00:22:51,150
+أنيلين مع أسد أنهيدرايد بده يهاجمها نطوط رد هادي
+
+259
+00:22:51,150 --> 00:22:55,850
+الـ Eucleophilic Substitution واضح؟ كل هذه
+
+260
+00:22:55,850 --> 00:22:59,250
+التفاعلات حقيقة سبع
+
+261
+00:23:00,470 --> 00:23:07,030
+ومرت علينا في أي منطقة لما اتكلمنا على الأحماط
+
+262
+00:23:07,030 --> 00:23:13,130
+ومشتقاتها ربما البعض يقول طيب ذكرنا بأمثلة على ال
+
+263
+00:23:13,130 --> 00:23:16,630
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+264
+00:23:16,630 --> 00:23:17,190
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+265
+00:23:17,190 --> 00:23:17,190
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+266
+00:23:17,190 --> 00:23:17,570
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+267
+00:23:17,570 --> 00:23:24,530
+ال ال ال ال ال
+
+268
+00:23:24,530 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+269
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+270
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+271
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+272
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+273
+00:23:29,470 --> 00:23:29,490
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+274
+00:23:31,660 --> 00:23:42,460
+CH3 CH2 NH2 هذا primary امين زائد هذا المركب و
+
+275
+00:23:42,460 --> 00:23:49,980
+حامل هنا ب R هذا يعتبر ايش الكلهيلايت هذا في
+
+276
+00:23:49,980 --> 00:23:53,520
+النهاية الكلهيلايت و لو حلقة خمسية كيف هتعملوا
+
+277
+00:23:56,960 --> 00:24:03,400
+واضح؟ وطالما الـ nucleophile neutral كمحص لإيش
+
+278
+00:24:03,400 --> 00:24:11,020
+هيكون؟ يفقد CH2 CH3 أكيد الـ H اللي فقدها مع ال PR
+
+279
+00:24:11,020 --> 00:24:17,940
+إيش هتعمل؟ HPR هذا من chapter 6 الـ nucleophilic
+
+280
+00:24:17,940 --> 00:24:22,820
+substitution ofAlkyl Halides الوثيقة الوثيقة
+
+281
+00:24:22,820 --> 00:24:27,820
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+282
+00:24:27,820 --> 00:24:30,180
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+283
+00:24:30,180 --> 00:24:31,120
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+284
+00:24:31,120 --> 00:24:31,460
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+285
+00:24:31,460 --> 00:24:36,880
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+286
+00:24:36,880 --> 00:24:41,160
+الوثيقة
+
+287
+00:24:41,160 --> 00:24:45,820
+الوثيقة
+
+288
+00:24:45,820 --> 00:24:47,480
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+289
+00:24:47,480 --> 00:24:49,140
+الوثيقة الوثيقة الوثيقة الوثيناخد كمان مرنو
+
+290
+00:24:49,140 --> 00:24:53,960
+سايكليك كيتون او الديهايد هى C double bond O C
+
+291
+00:24:53,960 --> 00:25:01,580
+double bond O زائد CH3 CH2
+
+292
+00:25:01,580 --> 00:25:08,720
+NH2 تخيلوا اجتكوا اكمل هذه المعادلة كيف هتكملوها؟
+
+293
+00:25:08,720 --> 00:25:12,260
+اه بدكم اتهاجموها على ال الديهايد او ال كيتون و
+
+294
+00:25:12,260 --> 00:25:16,540
+هذه تصير OH اذا للناتج اللى عندى
+
+295
+00:25:22,140 --> 00:25:30,100
+بدي يصير عندى OH OHANA NH
+
+296
+00:25:30,100 --> 00:25:39,120
+CH2 CH3 مش هذا اللي بدي يصير لكن الطالب الشاطر
+
+297
+00:25:39,120 --> 00:25:45,900
+اتعلمت كمان شغلة ان هذا هو تفاعل ل nucleophilic
+
+298
+00:25:45,900 --> 00:25:46,780
+addition
+
+299
+00:25:49,140 --> 00:25:54,660
+هذا هو تفاعل الـ Eucleophilic addition الآن مع ال
+
+300
+00:25:54,660 --> 00:25:58,600
+amines لما تكون ال H و ال OH جانب بعض، ايش
+
+301
+00:25:58,600 --> 00:26:05,460
+اتعلمنا؟ بيروح و بيفقد جزء ماء و بعمل double bond
+
+302
+00:26:08,450 --> 00:26:12,470
+قولنا احنا كل N H2 مع C double bond O ماصيرها
+
+303
+00:26:12,470 --> 00:26:17,130
+النهائي C double bond O الديهيد او كيتون تصير C
+
+304
+00:26:17,130 --> 00:26:23,790
+double bond N CH2 CH3 بصير ال shift basis وقولنا
+
+305
+00:26:23,790 --> 00:26:27,590
+ان التفاعل بهذه الحالة ايش بنقول عنه addition
+
+306
+00:26:27,590 --> 00:26:30,370
+elimination
+
+307
+00:26:31,670 --> 00:26:35,830
+نسيته تفاعل تكوين الأكزينز والهيدرازونز والسمي
+
+308
+00:26:35,830 --> 00:26:39,570
+كربازونز كل ال N-H2 مع ال C double bond O
+
+309
+00:26:39,570 --> 00:26:43,410
+الديهيدوكيتون كانت تعمل C double bond N على خطوتين
+
+310
+00:26:43,410 --> 00:26:51,100
+لكن في الأساس أن الأمين تفاعل كإيش؟كان uqlu5 وعمل
+
+311
+00:26:51,100 --> 00:26:54,760
+addition الان بعد هيك ان ال addition اتبع ال
+
+312
+00:26:54,760 --> 00:26:58,960
+elimination هذا امر ايش تاني هذا المحصلة النهائية
+
+313
+00:26:58,960 --> 00:27:03,480
+لكن ال addition ادشن و ال uqlu5 ال uqlu5 فال
+
+314
+00:27:03,480 --> 00:27:09,240
+amines تفاعلهم الأساسي بنقول هو ايش they react as
+
+315
+00:27:09,240 --> 00:27:14,480
+uqlu5 as uqlu5 واضح؟
+
+316
+00:27:16,420 --> 00:27:20,000
+لكن لو جينا سألناكم ال reaction of amines with
+
+317
+00:27:20,000 --> 00:27:25,120
+aldehydes and ketones is a nucleophilic addition
+
+318
+00:27:25,120 --> 00:27:30,600
+in a brain cell واضح؟ انه بعدك followed by
+
+319
+00:27:30,600 --> 00:27:34,700
+elimination على أنه الرأس مرة تبسيط واضح؟ with
+
+320
+00:27:34,700 --> 00:27:39,920
+acids and their derivatives a nucleophilic
+
+321
+00:27:39,920 --> 00:27:44,620
+substitution with alkyl halides برضه nucleophilic
+
+322
+00:27:44,620 --> 00:27:45,840
+substitution
+
+323
+00:27:56,390 --> 00:28:01,410
+بهيك بنكون خلصنا الفكرة أو الكلام المختصر اللى
+
+324
+00:28:01,410 --> 00:28:07,510
+بنشرحه عن ال amines و
+
+325
+00:28:07,510 --> 00:28:11,670
+بنلتقل مباشرة
+
+326
+00:28:11,670 --> 00:28:15,970
+لفصل
+
+327
+00:28:15,970 --> 00:28:22,850
+الخامس عشر اللى هو يعتبر بداية ال general
+
+328
+00:28:22,850 --> 00:28:28,890
+biochemistry اللى بنحكي عنهاlimits and detergents
+
+329
+00:28:28,890 --> 00:28:37,110
+limits and detergents الان ال limits معناها
+
+330
+00:28:37,110 --> 00:28:41,190
+بالعربي الدهون اش
+
+331
+00:28:41,190 --> 00:28:50,630
+اللي تلغيه ال libidab اسمها ال libidab دهون اه في
+
+332
+00:28:50,630 --> 00:28:55,570
+مشكلة عندكوا في الورق؟أنا عند ال slides خلص و أنت
+
+333
+00:28:55,570 --> 00:29:07,090
+عندك إشي؟ من وين صورته؟ أي شباته؟ مالغيين
+
+334
+00:29:07,090 --> 00:29:13,300
+هدولة، مشيولين عن .. مش موجودين في الزمالةلأ لأ
+
+335
+00:29:13,300 --> 00:29:18,440
+هدولة ال slides اللي معكم زيادة فيهم بس كلمة واحدة
+
+336
+00:29:18,440 --> 00:29:22,940
+احنا شرحناها كتابة how to prepare phenol هي اللي
+
+337
+00:29:22,940 --> 00:29:27,740
+كنا مهتمين فيها متذاكرين المرة الماضية قولنالكم
+
+338
+00:29:27,740 --> 00:29:32,240
+كيف تحضروا ال phenol فقط لحد هنا وبنخلص مافيش اندي
+
+339
+00:29:32,240 --> 00:29:37,420
+انا عن ال computer الان ننتقل للفصل الخامس عشر
+
+340
+00:29:37,420 --> 00:29:42,280
+limits and detergentsالـ Libids الدهون الـ
+
+341
+00:29:42,280 --> 00:29:48,420
+detergents المنظفات الصناعية المنظفات الصناعية
+
+342
+00:29:48,420 --> 00:29:51,400
+الصوابين و الأشياء اللي بتكون في الشنب و غيرها و
+
+343
+00:29:51,400 --> 00:29:57,520
+غيراتها و هتلاحظوا انه في علاقة بين الدهون و بينال
+
+344
+00:29:57,520 --> 00:30:03,160
+detergents و ربما كلكم اتذكرين اساسا ان الصابون
+
+345
+00:30:03,160 --> 00:30:08,220
+عادة من وين كانوا بيجيبوها؟ من زيت الزتون .. زيت
+
+346
+00:30:08,220 --> 00:30:14,650
+الزتون، دهون والصابونمنظف طبعا soap الآن صاروا
+
+347
+00:30:14,650 --> 00:30:19,070
+يعملوا أشياء صناعية بنسميها synthetic detergents
+
+348
+00:30:19,070 --> 00:30:23,590
+يعني منظفات صناعية كل هذا الكلام هيكون جزء من
+
+349
+00:30:23,590 --> 00:30:30,270
+الكلام اللي هنناقشه في هذا الشركة الآن لو إجينا و
+
+350
+00:30:30,270 --> 00:30:38,380
+قولنا إيش هم ال livids إيش هم الدهونلاحظوا أنه
+
+351
+00:30:38,380 --> 00:30:42,140
+الأن بنبدأ شوية نختلف عن ال organic chemistry يعني
+
+352
+00:30:42,140 --> 00:30:45,760
+في ال organic chemistry كل chapter لما كنا نجيب
+
+353
+00:30:45,760 --> 00:30:50,080
+عائلة كنا نميز العائلة بالمجموعة الوظيفية اللي
+
+354
+00:30:50,080 --> 00:30:54,780
+موجودة فيها يعني نقول ال alcohols OH ال aldehydes
+
+355
+00:30:54,780 --> 00:31:00,490
+يضا بالبنض OC double bond O of R of R الاسد C
+
+356
+00:31:00,490 --> 00:31:04,830
+double bond O O H هناك كان التصنيف اعتمادا على ايش
+
+357
+00:31:04,830 --> 00:31:11,010
+المجموعة الوظيفية الان لما باجي بقول ال libids هل
+
+358
+00:31:11,010 --> 00:31:16,790
+يا ترى ال libids كعائلة تحكمها مجموعة وظيفية واحدة
+
+359
+00:31:16,790 --> 00:31:19,870
+يعني في الآخر الواحدة تيجي تقولي C double bond
+
+360
+00:31:19,870 --> 00:31:26,780
+ONH4 C double bond OSHهل تصنيف ال limits منطلق من
+
+361
+00:31:26,780 --> 00:31:29,980
+ال functional groups من المجموعات الوظيفية
+
+362
+00:31:29,980 --> 00:31:35,710
+الجوانب؟الـ Libids هي عائلة من المنتجات الطبيعية
+
+363
+00:31:35,710 --> 00:31:41,070
+بشكل عام Natural Products عائلة كبيرة جدا و ينضوي
+
+364
+00:31:41,070 --> 00:31:47,030
+تحتها تفرعات كتيرة هدولة بيمتازوا بشكل عام ..
+
+365
+00:31:47,030 --> 00:31:51,490
+بيمتازوا بشكل عام المراكبات المنتجة طبيعيا انه
+
+366
+00:31:51,490 --> 00:31:56,230
+بتدوب في ال organic solvents زي ال ether,
+
+367
+00:31:56,450 --> 00:32:00,330
+chloroform, أسيتون, بنزين وبشكل عام بدوبوش في
+
+368
+00:32:00,330 --> 00:32:05,710
+الميهإذا هنا اللي ميزهم كعائلة إن هما منتجات
+
+369
+00:32:05,710 --> 00:32:12,190
+طبيعية وشغل تانية soluble in organic solvents يعني
+
+370
+00:32:12,190 --> 00:32:19,870
+أنا بدي إن they are natural و soluble in non-polar
+
+371
+00:32:19,870 --> 00:32:24,370
+organic solvents insoluble in water
+
+372
+00:32:27,950 --> 00:32:31,530
+اللي أنا بدياهم عن ال limits they are natural
+
+373
+00:32:31,530 --> 00:32:37,510
+compounds soluble in non-polar organic solvents
+
+374
+00:32:37,510 --> 00:32:43,050
+insoluble in water طبعا طالما كانوا soluble in non
+
+375
+00:32:43,050 --> 00:32:46,090
+-polar organic solvents إذا انتوا هتستنتجوا ان هم
+
+376
+00:32:46,090 --> 00:32:51,790
+non-polar ليش؟ لأنه likelike واضح إذا هما non
+
+377
+00:32:51,790 --> 00:32:55,910
+polar و بدوبوا فيه ال non polar solvents الانب
+
+378
+00:32:55,910 --> 00:33:00,370
+يندرج تحتهم الحقيقة مجموعة كبيرة من المراكبات منهم
+
+379
+00:33:00,370 --> 00:33:05,090
+اللي بنسميه ال fatty acids الأحماض الدهنية بنشوف
+
+380
+00:33:05,090 --> 00:33:08,510
+شو هي ال fatty acids منهم ال soaps and detergents
+
+381
+00:33:08,510 --> 00:33:13,370
+الصوابين و المنظفات منهم ال fats and oils الدهون و
+
+382
+00:33:13,370 --> 00:33:18,770
+الزيون منهم ال waxes الشموةمنهم الـ Phospholipids
+
+383
+00:33:18,770 --> 00:33:23,330
+بنسميها Phospholipids منهم الـ Icosanoids مركبات
+
+384
+00:33:23,330 --> 00:33:28,590
+انكونا من عشرين ذرة كربون منهم Terbenes مجموعة
+
+385
+00:33:28,590 --> 00:33:34,590
+مركبات بتحده بصفة معينة بنشوفها وجود isoprene unit
+
+386
+00:33:34,590 --> 00:33:40,400
+منهم الستيرويد مركبات ممتازة وجود أربع حلقاتمنهم
+
+387
+00:33:40,400 --> 00:33:45,620
+بعض ال vitamins أشياء منوعة مافيش خاسم مشترك بينها
+
+388
+00:33:45,620 --> 00:33:50,980
+كل هدولة من ناحية المبدأ natural productsSoluble
+
+389
+00:33:50,980 --> 00:33:54,940
+in organic solvents and soluble in water are
+
+390
+00:33:54,940 --> 00:33:57,580
+classified as lipids
+
+391
+00:34:20,310 --> 00:34:24,990
+يعني التلات أشياء بنفهموا مع بعض، واضح؟ يعني اللي
+
+392
+00:34:24,990 --> 00:34:28,150
+بده يفهم ال fatty acids، بده يفهم ال fats، اللي
+
+393
+00:34:28,150 --> 00:34:30,890
+بده يفهم ال fats، بده يفهم ال oils، اللي بده يفهم
+
+394
+00:34:30,890 --> 00:34:33,110
+ال fats و ال oils، بده يفهم ال soaps و ال
+
+395
+00:34:33,110 --> 00:34:38,310
+detergents، التلاتة هتلاحظوا أن فيهم إيش؟ قاسم
+
+396
+00:34:38,310 --> 00:34:45,240
+مشترك، التلاتة هتلاحظوا أن فيهم قاسم مشتركوعشان
+
+397
+00:34:45,240 --> 00:34:51,440
+هيك خلّينا نبدأ بال fats and oils الآن بشكل عام
+
+398
+00:34:51,440 --> 00:34:57,640
+الدهون والزيوت أشهر شيء موجودين فيه على شكل اللي
+
+399
+00:34:57,640 --> 00:35:04,700
+بنسميه triglycerides إيش هما ال triglycerides؟ ال
+
+400
+00:35:04,700 --> 00:35:13,120
+triglycerides ببساطة عبارة عن إيسترز ل .. ال ..
+
+401
+00:35:14,640 --> 00:35:20,620
+للجليسارين طبعا كلكم اتذكرين انه احنا ايش اخدنا
+
+402
+00:35:20,620 --> 00:35:27,380
+الجليسارين سابقا قلنا تلات ذرات كربون تلات ذرات
+
+403
+00:35:27,380 --> 00:35:34,660
+كربون فيهم OH OH OH عشانك الجليسارول one two three
+
+404
+00:35:34,660 --> 00:35:41,880
+بروبان الترايول مظبوط ولا لأ one two three بروبان
+
+405
+00:35:41,880 --> 00:35:48,090
+الترايولهذا ال glycerin في الأساس اتفاعل مع أشياء
+
+406
+00:35:48,090 --> 00:35:53,850
+بنسميها fatty acids هتيجي تقولون احنا اتعلمنا ال
+
+407
+00:35:53,850 --> 00:35:58,370
+carboxylic acids اللي صيغتهم العامة C double bond
+
+408
+00:35:58,370 --> 00:36:04,570
+O OH متصلين في R بنقول ال fatty acids هم نفسهم
+
+409
+00:36:04,570 --> 00:36:14,080
+ولكن ال R تبعتهم كبيرةيعني بتكون عشر كربونات،
+
+410
+00:36:14,080 --> 00:36:17,220
+اتنائش، اربعة عاشر، ستة عاشر، تمانة عاشر، اشرين
+
+411
+00:36:17,220 --> 00:36:22,780
+الآن كلكم اتذكرين انه في ال alcohol و في ال acids
+
+412
+00:36:22,780 --> 00:36:32,300
+قولنا هذه المركبات التمتاز ان فيها طرف polar و طرف
+
+413
+00:36:32,300 --> 00:36:39,800
+non polarالـ R في الـ fatty acids الـ non-polar
+
+414
+00:36:39,800 --> 00:36:46,180
+الكبير، خلّينا نقول من عشرة و فوقوبناء على ذلك
+
+415
+00:36:46,180 --> 00:36:52,280
+الجزيء بمجمله يغلب عليه الـ non-polar part فبصير
+
+416
+00:36:52,280 --> 00:36:56,480
+water soluble ولا insoluble؟ بصير non-polar طالما
+
+417
+00:36:56,480 --> 00:37:01,680
+صار non-polar صار water insoluble بصير دوب في ال
+
+418
+00:37:01,680 --> 00:37:06,640
+organic solvent إذا هذه الجزيئات اللي فيها القاري
+
+419
+00:37:06,640 --> 00:37:10,190
+الكبيرة هي اللي بنسميها الـ fatty acidsفال fatty
+
+420
+00:37:10,190 --> 00:37:17,150
+acids ببساطة هي أحماض كربوكسيلية بسلسلة طويلة
+
+421
+00:37:17,150 --> 00:37:24,080
+وبناء على ذلك أصبحت هذه الأحماض non polarما بتدوبش
+
+422
+00:37:24,080 --> 00:37:27,220
+في الميه وعشان هيك بتدوبش في الميه بتدوب في
+
+423
+00:37:27,220 --> 00:37:33,500
+المراكبات العضوية عشان هيك سمنها مواد ايش؟ دهنية
+
+424
+00:37:33,500 --> 00:37:38,620
+او احماض دهنية فهما الأحماض الدهنية مجموعتهم
+
+425
+00:37:38,620 --> 00:37:42,600
+الأساسية زي ال carboxylic acids COOH هما
+
+426
+00:37:42,600 --> 00:37:49,330
+carboxylic acids اكبرواضح؟ هم ببساطة كربوكسيلك
+
+427
+00:37:49,330 --> 00:37:55,190
+أسنس كبار، الآن لو أجينا و قولنا كحول زائد حمض، شو
+
+428
+00:37:55,190 --> 00:38:04,910
+بيعطيني؟ إيستر، لو أخدنا أي كحول زائد حمض، إيستر،
+
+429
+00:38:04,910 --> 00:38:08,410
+هذا أخدنا التفاعل، الآن هاي كحول في الجليسرين و
+
+430
+00:38:08,410 --> 00:38:13,690
+هاي حمض، خليهم يتفاعلواهذه الكحولة اتفاعل، ماذا
+
+431
+00:38:13,690 --> 00:38:21,550
+سيعطينا؟ CH2O C double bond OR هذا Easter ولا لا؟
+
+432
+00:38:21,550 --> 00:38:28,430
+و هذا؟ Easter تاني على الكحولة و هذا؟يستار تالت،
+
+433
+00:38:28,430 --> 00:38:33,570
+إذا كم إيستار عمل لجليسارين؟ لأنه فيه تلاتة أواتشز
+
+434
+00:38:33,570 --> 00:38:40,410
+عمل تلاتة إيستار الآن هذه المركبات بنسميها احنا
+
+435
+00:38:40,410 --> 00:38:46,410
+الـ triglycerides الـ tri لأنهم تلاتة، الجليساريدز
+
+436
+00:38:46,410 --> 00:38:49,150
+لأنهم إيستارز of جليسارين
+
+437
+00:38:51,280 --> 00:38:55,480
+اعرفنا إذا ليش الـ triglycerides؟ لأنه there are E
+
+438
+00:38:55,480 --> 00:39:02,700
+stars of glycerin وكم E star؟ هان و هان و هان، إذا
+
+439
+00:39:02,700 --> 00:39:08,690
+هذه الـ triglycerides هي عبارة عن الفات والـ oilهي
+
+440
+00:39:08,690 --> 00:39:12,230
+عبارة عن الزيت و الذهن و الزبدة و السمنة و زيت
+
+441
+00:39:12,230 --> 00:39:16,270
+الزتون و زيت عباد الشمس هو عبارة عن الـ
+
+442
+00:39:16,270 --> 00:39:19,310
+Triglycerides الميزة الأساسية اللي بتبقى بالكم
+
+443
+00:39:19,310 --> 00:39:26,230
+متذاكرينها فيه ان القعر هذه طويلة لأن القعر طويلة
+
+444
+00:39:26,230 --> 00:39:31,030
+كله water soluble ولا insoluble عشان هيك الزيت
+
+445
+00:39:31,030 --> 00:39:39,160
+الزيرج زيت الزتون بخلط مع الميه لأ واضح ف ..لاحظوا
+
+446
+00:39:39,160 --> 00:39:43,600
+اللي فهم هذا الكلام، بلاحظ العلاقة ما بين الـ
+
+447
+00:39:43,600 --> 00:39:46,800
+triglycerides و الـ fatty acids، انه انا لو عملت
+
+448
+00:39:46,800 --> 00:39:51,200
+هيدروليسيز، لو كسرت الـ triglycerides، سخنتهم
+
+449
+00:39:51,200 --> 00:39:55,280
+بالسوديوم هيدروكسيد و ضفت عليهم بعدين حامض، عاش
+
+450
+00:39:55,280 --> 00:40:02,420
+بحصل؟ بحصل على ال glycerin أو ال glycerol و ال
+
+451
+00:40:02,420 --> 00:40:10,380
+fatty acidsبحصل على ال glycerol و ال fatty acids
+
+452
+00:40:10,380 --> 00:40:17,060
+واضح الفكرة؟ اذا ال fatty acids هما في الأساس جزء
+
+453
+00:40:17,060 --> 00:40:22,280
+من ال tri glycerides بالتكسير بحصل على glycerin و
+
+454
+00:40:22,280 --> 00:40:27,600
+بحصل على fatty acid واضح الفكرة؟
+
+455
+00:40:29,710 --> 00:40:34,910
+خلّينا شوية صغيرة نخرج عن السياق خلّينا شوية صغيرة
+
+456
+00:40:34,910 --> 00:40:41,870
+نخرج عن السياق الان جزء ال الكانز نرجع لل الكانز
+
+457
+00:40:41,870 --> 00:40:48,790
+مش هذا الجزء الأحمر هو عبارة عن الكانز طيب أول
+
+458
+00:40:48,790 --> 00:40:54,150
+chapter أخدناه في الكيميا العضوية شو كان؟الكينز،
+
+459
+00:40:54,150 --> 00:41:02,530
+وإيش أهم تفاعلات ال الكينز اللي احنا أخدناها؟ ان
+
+460
+00:41:02,530 --> 00:41:08,710
+ال الكينز بنحرقهم في وجود ال oxygen، بيعطونا ثاني
+
+461
+00:41:08,710 --> 00:41:15,970
+أكسيد الكربون وماء وحرارةطيب هذه المراكبات اللي
+
+462
+00:41:15,970 --> 00:41:20,090
+قال فيها Alkanes واحدة مين كنتيش تتخيل القاتل انه
+
+463
+00:41:20,090 --> 00:41:25,970
+حطينا السيرج على النار بدنا نولع السيرج حد بيمنعنا
+
+464
+00:41:25,970 --> 00:41:36,930
+يعني سيرج زائد Oxygen شو هيعطيني CO2 زائد H2O زائد
+
+465
+00:41:36,930 --> 00:41:43,730
+Heatمش هذه الـ aliphatic compounds الحمرة بتنحرج
+
+466
+00:41:43,730 --> 00:41:48,730
+وبتعطيني ثانو أكسيد كربون وميه وحرارة؟ إذا الـ
+
+467
+00:41:48,730 --> 00:41:53,790
+seerage ممكن ينحرج ويعطيني ثانو أكسيد كربون وميه
+
+468
+00:41:53,790 --> 00:41:59,530
+وحرارة؟ ولا مش ممكن؟ بتشوفوه بنحرج في الدار و
+
+469
+00:41:59,530 --> 00:42:04,530
+بتكونوا تنتبهوا لما بتشتغلوا؟ طب كويس الآن لو واحد
+
+470
+00:42:04,530 --> 00:42:11,060
+مخه مش مريحه أو الحصار مش مريحهوجطعوا البنزين ..
+
+471
+00:42:11,060 --> 00:42:15,720
+جطعوا السولار عن البلد وإيجى حط في سيارة ال مرسيدس
+
+472
+00:42:15,720 --> 00:42:18,920
+تبعته اللي بتمشي على السولار ولا في ال bus؟ سيرج
+
+473
+00:42:18,920 --> 00:42:25,740
+.. سيرج ومشى .. بيمشي ولا لأ؟ بيمشي .. بيمشي ..
+
+474
+00:42:25,740 --> 00:42:32,920
+بيمشي وعشان هيك في غزة في ظروف الحصار لما عدم
+
+475
+00:42:32,920 --> 00:42:38,270
+الوقودوكانوا بعض الباصات والسيارات المرسيدس مضطرة
+
+476
+00:42:38,270 --> 00:42:45,030
+تمشي حطوا searage في السيارة واشتغلت ومشيت صح لكن
+
+477
+00:42:45,030 --> 00:42:54,350
+كان عندكم مشكلة الشيء انه طلعت رائحة فظيعة جدا و
+
+478
+00:42:54,350 --> 00:42:58,850
+الناس كانت بتنخنيهمظبوط ولا لأ؟ طب هم الناس
+
+479
+00:42:58,850 --> 00:43:02,030
+مانخنجوش من ال solar العادى و من البنزين يعنى،
+
+480
+00:43:02,030 --> 00:43:05,990
+يقولوا تأثيرات سلبية، لكن مابتصلش لإنه الناس
+
+481
+00:43:05,990 --> 00:43:11,650
+ينخنجوا، إيش اللي صار إذا لما احنا ولّعنا السيرج؟
+
+482
+00:43:11,650 --> 00:43:16,210
+اه، اللي صار لما ولّعنا السيرج، إنه السيرج جزءين،
+
+483
+00:43:16,210 --> 00:43:22,310
+هذا الجزء هو اللي عمل كوقودهذا الجزء التابع لـ
+
+484
+00:43:22,310 --> 00:43:28,990
+Glycerin راح يعمل مصيبة هذا بالحرق بيعطي مركب تاني
+
+485
+00:43:28,990 --> 00:43:36,990
+CH ضب البند OH CH ضب البند CH2 بنسميه أكرولين و لا
+
+486
+00:43:36,990 --> 00:43:42,450
+أكرالدهايد هذا المركب هو اللي ريحته كانت سيئة و
+
+487
+00:43:42,450 --> 00:43:49,350
+يطلع على الشوارع و غيره و غيراته و خنج الناسواضحة
+
+488
+00:43:49,350 --> 00:43:55,130
+الفكرة؟ فالغلطة اللى كانت ان الناس لما اجوا يحرقوا
+
+489
+00:43:55,130 --> 00:44:01,330
+ال series في متورات السيارات حرقوا ايش؟ الجزء اللى
+
+490
+00:44:01,330 --> 00:44:06,110
+عادة بيعطيه الطاقة والجزء الجيد زائد الجزء ايش؟
+
+491
+00:44:06,110 --> 00:44:12,470
+السام والدار فطلعت عندهم حرارة ومشيت السيارة وكل
+
+492
+00:44:12,470 --> 00:44:16,810
+اشي لكن طلع عندهم كمان هذا المركب انتشر في الجو
+
+493
+00:44:16,810 --> 00:44:24,620
+خلق الناسواضحة الفكرة؟ طيب الآن لو في ناس بيفكروا
+
+494
+00:44:24,620 --> 00:44:31,940
+جيدا وقالوا يا تورا بدنا نحل المشكلة نطلع وقود من
+
+495
+00:44:31,940 --> 00:44:40,080
+الزيت ومن السيرج بيقدروا يعمله؟ لو إنهم في الأول
+
+496
+00:44:40,850 --> 00:44:46,750
+عملوا القاتل فصلوا هدول المركبين عن بعض يعني جابوا
+
+497
+00:44:46,750 --> 00:44:51,630
+ال searage قبل ما يحطوا كله في ماتور السيارة قبل
+
+498
+00:44:51,630 --> 00:44:57,410
+ما يحطوا كله في ماتور السيارة كسروا نصين الأن هذا
+
+499
+00:44:57,410 --> 00:45:04,480
+النصالمفيد هذا ال fuel هذا الوقود وهذا إيش؟
+
+500
+00:45:04,480 --> 00:45:08,860
+الجليسيرين الآن أنا لما أكسره بداية قبل ما أحطه في
+
+501
+00:45:08,860 --> 00:45:13,340
+موتور السيارة الجليسيرين صار على جانب بفصله ولا
+
+502
+00:45:13,340 --> 00:45:17,600
+مابفصلوش بفصله باخده و باستفيد منه كمان بعمل منه
+
+503
+00:45:17,600 --> 00:45:21,220
+كريمات مش كل كريمات و شامبوات فيها جليسيرين عشان
+
+504
+00:45:21,220 --> 00:45:27,850
+نعمة الإيدين يعني أنا مش بس اتخلصت من ضرر حرقهأنا
+
+505
+00:45:27,850 --> 00:45:32,470
+أخدته واستفادت منه وهذا الجزء عادة بيفصله على شكل
+
+506
+00:45:32,470 --> 00:45:39,650
+E star أو إثل أو إثل أو إثل واضح؟
+
+507
+00:45:39,650 --> 00:45:43,250
+يعني لما يعملوا التكسير بيفصلوا على شكل E star هذا
+
+508
+00:45:43,250 --> 00:45:50,610
+بناخده كوقود اليوم هذا الوقود اللي أخدنا إيش
+
+509
+00:45:50,610 --> 00:45:57,770
+بيسموه؟بيو ديزل بيو ديزل إيش يعني بيو ديزل يعني
+
+510
+00:45:57,770 --> 00:46:03,910
+الديزل الحيو اللي جاي من الزيوت هتقولولي في ديزل
+
+511
+00:46:03,910 --> 00:46:11,610
+بالطول من الزيت الجواب آه اليوم طائرات وسيارات
+
+512
+00:46:11,610 --> 00:46:17,370
+طائرات كاملة بتمشي على بيو ديزل بطوله من الزيوت
+
+513
+00:46:17,960 --> 00:46:23,540
+طبعا هالياطورة احنا ملاقين زيت ناكله سيرج و زيت
+
+514
+00:46:23,540 --> 00:46:29,620
+ناكله لما نحوله لوخود؟ الجواب اه كيف؟ الزيوت مش بس
+
+515
+00:46:29,620 --> 00:46:34,760
+كله مأكولة edible مأكول في زيوت inedibleزيوت لا
+
+516
+00:46:34,760 --> 00:46:40,480
+تؤكل تمام؟ بيزرعوها في أماكن كبيرة في الهند و في
+
+517
+00:46:40,480 --> 00:46:44,580
+غيرها و في غيراتها مثل مثلا زيت الجاتروفة و زيت
+
+518
+00:46:44,580 --> 00:46:49,520
+الكامليانة و زيت كذا في زيوت تؤكل و زيوت لا تؤكل
+
+519
+00:46:49,520 --> 00:46:54,800
+الزيوت اللتي لا تؤكل هي اللي بيحضروا منها المنظفات
+
+520
+00:46:54,800 --> 00:47:00,740
+و هي اللي بيحولوها لإيش؟ ل bio diesel و أشهرها زيت
+
+521
+00:47:00,740 --> 00:47:08,350
+اسمه الجاتروفةGatrofa Oil أشرب هذه الزيوت .. زيت
+
+522
+00:47:08,350 --> 00:47:13,010
+بنسميه إيش؟ زيت الجاتروفا فلاحظوا أنتوا كيف منطق
+
+523
+00:47:13,010 --> 00:47:17,350
+التفكير و منطق حل المشكلة في العلم أنه أنا فهمت
+
+524
+00:47:17,350 --> 00:47:22,450
+بداية .. أنه أنا فهمت بداية أن الحرارة بتجيني من
+
+525
+00:47:22,450 --> 00:47:29,170
+حرق هذا واضح؟الحرارة بتجيني من حرق هذا لكن هذا
+
+526
+00:47:29,170 --> 00:47:34,090
+موجود مع مركب تاني سام لما فصلته من الصين صار
+
+527
+00:47:34,090 --> 00:47:37,370
+بإمكاني أخد هذا و أسميه biodiesel و أحرب ولا لأ
+
+528
+00:47:37,370 --> 00:47:44,590
+الآن ضايقلي عشرين ثانية أحكيهم عارفين شو هم؟
+
+529
+00:47:44,590 --> 00:47:52,180
+العشرين ثانية اللي بدنا نحكيهم و نخلصالعشرين ثانية
+
+530
+00:47:52,180 --> 00:47:56,160
+اللي بنحكيهم و بنخلص القاتل اتخيلوا لو أخدتوا هذا
+
+531
+00:47:56,160 --> 00:48:03,780
+ال Easter و حطيتوا هنا سلسلة طويلة و حطيتوا هنا
+
+532
+00:48:03,780 --> 00:48:11,850
+كمان سلسلة طويلة هذه السلاسل ايش بتعمل؟بتولع مع ال
+
+533
+00:48:11,850 --> 00:48:17,110
+Oxygen و بتعطي حرارة و إضاءة و إشي هذه المركبات ال
+
+534
+00:48:17,110 --> 00:48:22,090
+E Stars اللي فيها سلسلة طويلة يمين و سلسلة طويلة
+
+535
+00:48:22,090 --> 00:48:30,910
+الشمال عارفين هي إيش؟ هي الشمع ال wax الآن أنا لما
+
+536
+00:48:30,910 --> 00:48:37,390
+بولع الشمع حقيقة إيش بولع؟ السلاسل الألفاتية
+
+537
+00:48:40,000 --> 00:48:45,380
+وبهك بيكون يعرفنا إيش هو الشمع الشمع هو Easter لكن
+
+538
+00:48:45,380 --> 00:48:50,160
+هذا ال Easter بسلسلتين كبار هانا وإحنا عرفنا إنه
+
+539
+00:48:50,160 --> 00:48:55,180
+هذه السلاسل لما بتولع هي اللي بتعطينا شوية الحرارة
+
+540
+00:48:55,180 --> 00:48:57,880
+و ثاني أكسيد الكربون و الميه مش مهمين أهم شيء
+
+541
+00:48:57,880 --> 00:49:02,720
+الحرارة و الإضاءة واضح؟ فلو قلنا لكم إيش ال wax
+
+542
+00:49:02,720 --> 00:49:12,010
+بالظبط ال wax areأو الواكس هم أسطارين مع شبكات
+
+543
+00:49:12,010 --> 00:49:16,370
+طويلة أو شبكات ألفاتية طويلة يعني اللي بيميزهم
+
+544
+00:49:16,370 --> 00:49:21,530
+الشبكات الطويلة الشبكات الألفاتية وكلنا عارفين
+
+545
+00:49:21,530 --> 00:49:25,810
+الأن الشبكات الألفاتية إيش بنعمل فيها هي اللي
+
+546
+00:49:25,810 --> 00:49:30,250
+بنولعها و بتعطينا الطاقة هي اللي بنولعها و بتعطينا
+
+547
+00:49:30,250 --> 00:49:34,850
+الطاقةفبكون هذا هو إيش الشمال فلاحظوا كيف أنا
+
+548
+00:49:34,850 --> 00:49:41,570
+استفدت من ال sealage كوقود كيف أنا استفدت كمان من
+
+549
+00:49:41,570 --> 00:49:46,710
+ال wax أنه أولعه و يطلعلي حرارة من خلال أنه أنا
+
+550
+00:49:46,710 --> 00:49:50,110
+بستفيد من التفاعل الأصلي اللي أخدته في شبتر واحد
+
+551
+00:49:50,110 --> 00:49:55,350
+أنه الألكيز بتحض مع ال oxygen و ال combustion
+
+552
+00:49:55,350 --> 00:49:58,630
+طلعوا ثانو أكسيد كربون و ميه و حرارة
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/rNQZEu2DPCw_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/rNQZEu2DPCw_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..b82ab429e41de0c2ceb099747487e0382ce76e7b
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/rNQZEu2DPCw_raw.json
@@ -0,0 +1 @@
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الـ", "probability": 0.62548828125}, {"start": 121.38, "end": 122.08, "word": " Structural", "probability": 0.8946940104166666}, {"start": 122.08, "end": 122.94, "word": " Isomers", "probability": 0.85107421875}, {"start": 122.94, "end": 123.44, "word": " اللي", "probability": 0.50579833984375}, {"start": 123.44, "end": 123.92, "word": " الذرات", "probability": 0.8818359375}, {"start": 123.92, "end": 124.54, "word": " بتختلف", "probability": 0.8805338541666666}, {"start": 124.54, "end": 124.7, "word": " في", "probability": 0.8662109375}, {"start": 124.7, "end": 125.36, "word": " ارتباطها", "probability": 0.94345703125}, {"start": 125.36, "end": 126.0, "word": " والجزيات", "probability": 0.815966796875}, {"start": 126.0, "end": 126.5, "word": " بتختلف", "probability": 0.9700520833333334}, {"start": 126.5, "end": 126.62, "word": " في", "probability": 0.79541015625}, {"start": 126.62, "end": 127.42, "word": " تسميتها", "probability": 0.9879150390625}, {"start": 127.42, "end": 128.1, 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بيصير؟ بنقدر نجيبه لكن يا تورة هل معقول اللي كاربون تصير خمس روابط؟ لأ وجدت هأ بدأت طار أحرك رابطة ما هي الرابطة إلكترونية", "tokens": [9566, 6027, 15042, 18871, 16254, 5551, 11622, 2407, 26108, 11933, 23275, 2655, 2288, 11536, 9307, 4032, 12602, 14407, 3555, 9566, 4724, 28814, 2304, 41361, 1829, 41850, 5551, 5016, 31747, 5551, 11622, 2407, 26108, 33688, 23275, 2655, 2288, 11536, 9307, 9154, 3714, 41361, 11296, 4032, 5551, 25957, 1211, 6055, 17082, 1829, 13546, 8978, 34892, 14407, 3555, 9566, 37495, 22653, 50113, 15040, 45164, 11933, 5016, 8315, 11933, 7435, 1829, 8315, 4032, 12174, 12610, 8315, 47525, 8315, 8717, 5016, 31747, 23758, 30767, 29245, 33688, 23275, 2655, 2288, 11536, 9307, 8717, 7435, 1829, 3555, 3224, 15844, 23758, 9673, 30543, 3615, 4724, 1829, 9381, 13546, 22807, 44945, 28543, 2288, 8717, 7435, 1829, 3555, 3224, 44381, 35186, 6055, 13063, 3660, 8032, 1211, 20449, 39648, 13672, 1829, 9122, 9640, 3555, 11536, 6055, 9381, 13546, 16490, 2304, 3794, 12602, 14407, 3555, 9566, 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double headed straight arrows are used for structures with different arrangements of atoms and electrons", "tokens": [4520, 44513, 365, 819, 22435, 295, 14265, 3714, 2288, 9307, 44945, 1829, 7435, 1829, 8717, 3794, 10721, 1211, 41950, 15040, 3555, 44945, 39648, 16095, 341, 11610, 420, 3834, 12798, 2997, 19669, 366, 1143, 337, 9227, 365, 819, 22435, 295, 16871, 293, 14265], "avg_logprob": -0.20076308693996694, "compression_ratio": 1.455128205128205, "no_speech_prob": 0.0, "words": [{"start": 1020.3299999999999, "end": 1021.29, "word": "Structures", "probability": 0.4573974609375}, {"start": 1021.29, "end": 1021.67, "word": " with", "probability": 0.9189453125}, {"start": 1021.67, "end": 1022.27, "word": " different", "probability": 0.9130859375}, {"start": 1022.27, "end": 1023.41, "word": " arrangements", "probability": 0.8740234375}, {"start": 1023.41, "end": 1024.27, "word": " of", "probability": 0.97119140625}, {"start": 1024.27, "end": 1025.23, "word": " electrons", "probability": 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"Curved Arrow فالـ Curved Arrow is used to indicate the movement of a pair of electrons، two electrons، واضح؟", "tokens": [34, 374, 937, 40269, 6156, 6027, 39184, 7907, 937, 40269, 307, 1143, 281, 13330, 264, 3963, 295, 257, 6119, 295, 14265, 12399, 732, 14265, 12399, 4032, 46958, 5016, 22807], "avg_logprob": -0.3377604047457377, "compression_ratio": 1.1782178217821782, "no_speech_prob": 0.0, "words": [{"start": 1113.63, "end": 1114.31, "word": "Curved", "probability": 0.678955078125}, {"start": 1114.31, "end": 1114.67, "word": " Arrow", "probability": 0.5986328125}, {"start": 1114.67, "end": 1115.33, "word": " فالـ", "probability": 0.5243326822916666}, {"start": 1115.33, "end": 1115.71, "word": " Curved", "probability": 0.748779296875}, {"start": 1115.71, "end": 1116.05, "word": " Arrow", "probability": 0.99072265625}, {"start": 1116.05, "end": 1116.53, "word": " is", "probability": 0.5869140625}, {"start": 1116.53, "end": 1117.61, "word": " used", "probability": 0.62255859375}, 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"word": " السنارة", "probability": 0.7232259114583334}, {"start": 1155.45, "end": 1156.23, "word": " ولذلك", "probability": 0.8292643229166666}, {"start": 1156.23, "end": 1156.63, "word": " هذا", "probability": 0.953125}, {"start": 1156.63, "end": 1157.27, "word": " السهم", "probability": 0.94091796875}, {"start": 1157.27, "end": 1158.67, "word": " بنسميه", "probability": 0.884033203125}, {"start": 1158.67, "end": 1158.89, "word": " احنا", "probability": 0.869140625}, {"start": 1158.89, "end": 1159.27, "word": " ايش", "probability": 0.73974609375}, {"start": 1159.27, "end": 1159.81, "word": " fish", "probability": 0.55078125}, {"start": 1159.81, "end": 1160.41, "word": " hook", "probability": 0.89794921875}, {"start": 1160.41, "end": 1160.97, "word": " يعني", "probability": 0.89453125}, {"start": 1160.97, "end": 1161.29, "word": " سهم", "probability": 0.956787109375}, {"start": 1161.29, "end": 1162.11, "word": " السنارة", "probability": 0.86865234375}, {"start": 1162.11, "end": 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ال", "probability": 0.841796875}, {"start": 1250.65, "end": 1251.05, "word": " Formal", "probability": 0.5733642578125}, {"start": 1251.05, "end": 1251.51, "word": " Charge", "probability": 0.88916015625}, {"start": 1251.51, "end": 1251.97, "word": " لهدول", "probability": 0.8419596354166666}, {"start": 1251.97, "end": 1252.73, "word": " القطعتين", "probability": 0.9464111328125}, {"start": 1252.73, "end": 1252.89, "word": " اللي", "probability": 0.96044921875}, {"start": 1252.89, "end": 1254.03, "word": " طلعوا", "probability": 0.9351806640625}, {"start": 1254.03, "end": 1255.31, "word": " اتذكروا", "probability": 0.8859375}, {"start": 1255.31, "end": 1255.99, "word": " الكربون", "probability": 0.8197428385416666}, {"start": 1255.99, "end": 1257.09, "word": " أربعة", "probability": 0.7420247395833334}, {"start": 1257.09, "end": 1257.99, "word": " ناقص", "probability": 0.966552734375}, {"start": 1257.99, "end": 1258.47, "word": " تلت", "probability": 0.8912760416666666}, {"start": 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عن", "probability": 0.9716796875}, {"start": 1303.48, "end": 1303.88, "word": " ايش", "probability": 0.90771484375}, {"start": 1303.88, "end": 1305.2, "word": " الأسهم", "probability": 0.8533528645833334}, {"start": 1305.2, "end": 1306.22, "word": " لابد", "probability": 0.95849609375}, {"start": 1306.22, "end": 1306.46, "word": " الا", "probability": 0.34033203125}, {"start": 1306.46, "end": 1307.02, "word": " يجيكم", "probability": 0.93505859375}, {"start": 1307.02, "end": 1307.78, "word": " سؤال", "probability": 0.9855143229166666}, {"start": 1307.78, "end": 1308.08, "word": " ايش", "probability": 0.92919921875}, {"start": 1308.08, "end": 1308.46, "word": " معنى", "probability": 0.94189453125}, {"start": 1308.46, "end": 1308.76, "word": " هذا", "probability": 0.96728515625}, {"start": 1308.76, "end": 1309.18, "word": " السهم", "probability": 0.98828125}, {"start": 1309.18, "end": 1309.56, "word": " لإيش", "probability": 0.7635498046875}, {"start": 1309.56, "end": 1310.84, "word": " يستعمل", "probability": 0.99462890625}, {"start": 1310.84, "end": 1311.96, "word": " هذا", "probability": 0.9619140625}, {"start": 1311.96, "end": 1312.4, "word": " السهم", "probability": 0.984375}, {"start": 1312.4, "end": 1315.52, "word": " اخر", "probability": 0.7705078125}, {"start": 1315.52, "end": 1316.1, "word": " شغلة", "probability": 0.9407552083333334}, {"start": 1316.1, "end": 1316.44, "word": " في", "probability": 0.95849609375}, {"start": 1316.44, "end": 1316.84, "word": " هذا", "probability": 0.982421875}, {"start": 1316.84, "end": 1317.76, "word": " الفصل", "probability": 0.971923828125}], "temperature": 1.0}, {"id": 57, "seek": 133388, "start": 1319.24, "end": 1333.88, "text": "الكيميا العضوية قبل قليل خفتوا و الأن نقطع الخوف و ننزل الخوف لماذا خفنا من الكيميا العضوية لأن الكيميا العضوية عشرين مليون مركب", "tokens": [6027, 4117, 32640, 25528, 18863, 11242, 2407, 10632, 12174, 36150, 12174, 20292, 1211, 16490, 5172, 2655, 14407, 4032, 16247, 1863, 8717, 47432, 3615, 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{"start": 1322.34, "end": 1323.82, "word": " نقطع", "probability": 0.7333170572916666}, {"start": 1323.82, "end": 1324.24, "word": " الخوف", "probability": 0.90966796875}, {"start": 1324.24, "end": 1324.82, "word": " و", "probability": 0.0716552734375}, {"start": 1324.82, "end": 1326.16, "word": " ننزل", "probability": 0.73370361328125}, {"start": 1326.16, "end": 1326.6, "word": " الخوف", "probability": 0.95703125}, {"start": 1326.6, "end": 1327.38, "word": " لماذا", "probability": 0.6777547200520834}, {"start": 1327.38, "end": 1327.68, "word": " خفنا", "probability": 0.8367513020833334}, {"start": 1327.68, "end": 1328.0, "word": " من", "probability": 0.8642578125}, {"start": 1328.0, "end": 1328.46, "word": " الكيميا", "probability": 0.95458984375}, {"start": 1328.46, "end": 1329.06, "word": " العضوية", "probability": 0.997314453125}, {"start": 1329.06, "end": 1329.76, "word": " لأن", "probability": 0.6328125}, {"start": 1329.76, "end": 1330.58, "word": " الكيميا", "probability": 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صار رابطة ثلاثية عائلة ال alkynes لو صار حلقة بروابط زوجية بقول هدولة ال aromatic compounds لو صار مركبات في مجموعة ال OH", "tokens": [1211, 2407, 20328, 9640, 8978, 43242, 7578, 49374, 2423, 5954, 4032, 2423, 5954, 12602, 16758, 9566, 3660, 38637, 1863, 16373, 10632, 4724, 39648, 29538, 6225, 16373, 37977, 2423, 419, 2653, 279, 45164, 20328, 9640, 12602, 16758, 9566, 3660, 38637, 1211, 5718, 104, 10632, 6225, 16373, 37977, 2423, 37688, 2534, 279, 45164, 20328, 9640, 11331, 1211, 28671, 4724, 2288, 14407, 3555, 9566, 30767, 29245, 10632, 4724, 39648, 8032, 3215, 12610, 3660, 2423, 45831, 21810, 45164, 20328, 9640, 3714, 31747, 3555, 9307, 8978, 3714, 7435, 2304, 2407, 27884, 2423, 13931], "avg_logprob": -0.13869382424300977, "compression_ratio": 1.7944444444444445, "no_speech_prob": 0.0, "words": [{"start": 1456.99, "end": 1457.35, "word": "لو", "probability": 0.931396484375}, {"start": 1457.35, "end": 1457.61, "word": " صار", "probability": 0.89501953125}, {"start": 1457.61, "end": 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Isobutane هاي ال carbon الجديدة كان عندي تلاتة CH3 CH .. 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butane أو من الصيغة C4H10 كام isomers عندى؟ two isomers إيش اسم هما دول ال two isomers؟ butane و isobutane هذا الكلام بيجي بالتجريب الآن لو برجع للخلف لاحظوا معاه لو بديت أحكي عن البنتين", "tokens": [3224, 8315, 9154, 28239, 9381, 37037, 8315, 9154, 41950, 28480, 11933, 15730, 9154, 2423, 39184, 457, 1929, 34051, 9154, 31767, 1829, 17082, 3660, 383, 19, 39, 3279, 9122, 10943, 307, 298, 433, 43242, 7578, 22807, 732, 307, 298, 433, 11933, 1829, 8592, 24525, 2304, 8032, 15042, 11778, 12610, 2423, 732, 307, 298, 433, 22807, 457, 1929, 4032, 307, 996, 325, 1929, 23758, 2423, 28820, 10943, 4724, 1829, 7435, 1829, 20666, 2655, 7435, 16572, 3555, 6024, 48506, 45164, 4724, 47341, 3615, 24976, 9778, 46538, 20193, 5016, 19913, 14407, 20449, 40294, 45164, 47525, 36081, 5551, 5016, 4117, 1829, 18871, 29739, 29399, 9957], "avg_logprob": -0.20281558874810096, "compression_ratio": 1.6203703703703705, "no_speech_prob": 0.0, "words": [{"start": 2091.3, "end": 2091.68, "word": "هنا", "probability": 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new file mode 100644
index 0000000000000000000000000000000000000000..926179726f782890f12de14f8d594f3e5bd9164c
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@@ -0,0 +1 @@
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"seek": 40384, "start": 375.32, "end": 403.84, "text": "بكون Optically Active ولا Inactive؟ Inactive لو انا حطيت مثلا Dichloromethane CH2 Cl2 بكون Optically Active ولا Inactive؟ Inactive لأنه عشان يبدأ يصير أحد ال enantiomers في وجود chiral center واحد المفروض يكون عندى أربع مجموعات مختلفة فخلينا نقول انه نسبة كبيرة جدا من المراكبات العضوية أساسا", "tokens": [3555, 30544, 21455, 984, 26635, 49429, 682, 12596, 22807, 682, 12596, 45164, 1975, 8315, 11331, 9566, 36081, 50113, 15040, 413, 480, 6746, 649, 71, 1929, 5995, 17, 2033, 17, 4724, 30544, 21455, 984, 26635, 49429, 682, 12596, 22807, 682, 12596, 5296, 33456, 3224, 6225, 8592, 7649, 7251, 44510, 10721, 7251, 9381, 13546, 5551, 24401, 2423, 465, 11520, 298, 433, 8978, 49610, 23328, 23782, 304, 3056, 36764, 24401, 9673, 5172, 32887, 11242, 7251, 30544, 43242, 7578, 5551, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660, 6156, 9778, 1211, 9957, 995, 8717, 39648, 16472, 3224, 8717, 35457, 3660, 9122, 3555, 48923, 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"word": " يبدأ", "probability": 0.9899088541666666}, {"start": 390.46, "end": 390.8, "word": " يصير", "probability": 0.98876953125}, {"start": 390.8, "end": 391.2, "word": " أحد", "probability": 0.78125}, {"start": 391.2, "end": 391.38, "word": " ال", "probability": 0.9501953125}, {"start": 391.38, "end": 392.4, "word": " enantiomers", "probability": 0.7257080078125}, {"start": 392.4, "end": 392.82, "word": " في", "probability": 0.92578125}, {"start": 392.82, "end": 393.18, "word": " وجود", "probability": 0.966064453125}, {"start": 393.18, "end": 393.62, "word": " chiral", "probability": 0.685546875}, {"start": 393.62, "end": 393.92, "word": " center", "probability": 0.80908203125}, {"start": 393.92, "end": 394.34, "word": " واحد", "probability": 0.85546875}, {"start": 394.34, "end": 395.18, "word": " المفروض", "probability": 0.989013671875}, {"start": 395.18, "end": 395.4, "word": " يكون", "probability": 0.977294921875}, {"start": 395.4, "end": 395.68, "word": " عندى", "probability": 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0.995361328125}, {"start": 403.06, "end": 403.84, "word": " أساسا", "probability": 0.9737548828125}], "temperature": 1.0}, {"id": 18, "seek": 41522, "start": 404.94, "end": 415.22, "text": "بتكون A chiral لاحظوا معاه هنا بنيجي لنقطة كتير مهمة لما وصفنا مركب انه chiral بمعنى هو أحد", "tokens": [3555, 2655, 30544, 316, 23782, 304, 20193, 5016, 19913, 14407, 20449, 40294, 34105, 44945, 1829, 7435, 1829, 5296, 1863, 47432, 3660, 9122, 2655, 13546, 3714, 16095, 3660, 5296, 15042, 4032, 9381, 5172, 8315, 3714, 31747, 3555, 16472, 3224, 23782, 304, 4724, 2304, 3615, 1863, 7578, 31439, 5551, 24401], "avg_logprob": -0.19786351554247797, "compression_ratio": 1.2459016393442623, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 404.94, "end": 405.94, "word": "بتكون", "probability": 0.7762858072916666}, {"start": 405.94, "end": 406.58, "word": " A", "probability": 0.2119140625}, {"start": 406.58, "end": 407.32, "word": " chiral", "probability": 0.59783935546875}, {"start": 407.32, "end": 408.2, "word": " لاحظوا", "probability": 0.8719482421875}, {"start": 408.2, "end": 408.64, "word": " معاه", "probability": 0.937255859375}, {"start": 408.64, "end": 409.14, "word": " هنا", "probability": 0.5673828125}, {"start": 409.14, "end": 409.56, "word": " بنيجي", "probability": 0.819580078125}, {"start": 409.56, "end": 410.04, "word": " لنقطة", "probability": 0.9378662109375}, {"start": 410.04, "end": 410.3, "word": " كتير", "probability": 0.8981119791666666}, {"start": 410.3, "end": 410.94, "word": " مهمة", "probability": 0.9920247395833334}, {"start": 410.94, "end": 411.4, "word": " لما", "probability": 0.875244140625}, {"start": 411.4, "end": 411.88, "word": " وصفنا", "probability": 0.98681640625}, {"start": 411.88, "end": 412.38, "word": " مركب", "probability": 0.9080403645833334}, {"start": 412.38, "end": 412.7, "word": " انه", "probability": 0.85791015625}, {"start": 412.7, "end": 413.36, "word": " chiral", "probability": 0.84423828125}, {"start": 413.36, "end": 414.04, "word": " بمعنى", "probability": 0.983203125}, {"start": 414.04, "end": 414.28, "word": " هو", "probability": 0.81005859375}, {"start": 414.28, "end": 415.22, "word": " أحد", "probability": 0.764892578125}], "temperature": 1.0}, {"id": 19, "seek": 43835, "start": 416.43, "end": 438.35, "text": "الإنانشومارز يعني كلمة chiral بتكون لما بيكون عندى two enanchomars هذا المركب لو حاطيته لحاله بقول عنه chiral بلف الضوء بزاوية معينة الآن ال enanchomar التاني لو حاطيته في ال polarimeter برضه chiral بنسميه بلف الضوء ولكن باتجاه", "tokens": [6027, 28814, 1863, 7649, 8592, 20498, 9640, 11622, 37495, 22653, 9122, 19528, 3660, 23782, 304, 39894, 30544, 5296, 15042, 4724, 1829, 30544, 43242, 7578, 732, 465, 4778, 298, 685, 23758, 9673, 31747, 3555, 45164, 11331, 41193, 36081, 3224, 5296, 5016, 6027, 3224, 4724, 39648, 18871, 3224, 23782, 304, 4724, 46538, 6024, 114, 2407, 38207, 4724, 11622, 995, 2407, 10632, 20449, 9957, 3660, 6024, 48506, 2423, 465, 4778, 298, 289, 16712, 7649, 1829, 45164, 11331, 41193, 36081, 3224, 8978, 2423, 12367, 9685, 4724, 43042, 3224, 23782, 304, 44945, 38251, 1829, 3224, 4724, 46538, 6024, 114, 2407, 38207, 35525, 19452, 4724, 9307, 7435, 40294], "avg_logprob": -0.2345267062626996, "compression_ratio": 1.6851851851851851, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 416.42999999999995, "end": 417.53, "word": "الإنانشومارز", "probability": 0.5523681640625}, {"start": 417.53, "end": 418.27, "word": " يعني", "probability": 0.7373046875}, {"start": 418.27, "end": 418.73, "word": " كلمة", "probability": 0.9679361979166666}, {"start": 418.73, "end": 419.19, "word": " chiral", "probability": 0.700927734375}, {"start": 419.19, "end": 419.71, "word": " بتكون", "probability": 0.92822265625}, {"start": 419.71, "end": 420.17, "word": " لما", "probability": 0.93115234375}, {"start": 420.17, "end": 420.51, "word": " بيكون", "probability": 0.71728515625}, {"start": 420.51, "end": 421.01, "word": " عندى", "probability": 0.788330078125}, {"start": 421.01, "end": 421.43, "word": " two", "probability": 0.75390625}, {"start": 421.43, "end": 422.47, "word": " enanchomars", "probability": 0.539520263671875}, {"start": 422.47, "end": 423.27, "word": " هذا", "probability": 0.8955078125}, {"start": 423.27, "end": 423.89, "word": " المركب", "probability": 0.8665364583333334}, {"start": 423.89, "end": 424.05, "word": " لو", "probability": 0.98681640625}, {"start": 424.05, "end": 424.55, "word": " حاطيته", "probability": 0.8609619140625}, {"start": 424.55, "end": 425.13, "word": " لحاله", "probability": 0.988525390625}, {"start": 425.13, "end": 425.73, "word": " بقول", "probability": 0.9658203125}, {"start": 425.73, "end": 426.03, "word": " عنه", "probability": 0.976318359375}, {"start": 426.03, "end": 426.61, "word": " chiral", "probability": 0.9248046875}, {"start": 426.61, "end": 427.05, "word": " بلف", "probability": 0.84033203125}, {"start": 427.05, "end": 427.39, "word": " الضوء", "probability": 0.96728515625}, {"start": 427.39, "end": 427.99, "word": " بزاوية", "probability": 0.94541015625}, {"start": 427.99, "end": 429.03, "word": " معينة", "probability": 0.9752604166666666}, {"start": 429.03, "end": 429.77, "word": " الآن", "probability": 0.6673583984375}, {"start": 429.77, "end": 430.65, "word": " ال", "probability": 0.88037109375}, {"start": 430.65, "end": 431.27, "word": " enanchomar", "probability": 0.6666259765625}, {"start": 431.27, "end": 431.67, "word": " التاني", "probability": 0.7858072916666666}, {"start": 431.67, "end": 431.83, "word": " لو", "probability": 0.97509765625}, {"start": 431.83, "end": 432.41, "word": " حاطيته", "probability": 0.986083984375}, {"start": 432.41, "end": 432.51, "word": " في", "probability": 0.87890625}, {"start": 432.51, "end": 432.61, "word": " ال", "probability": 0.7392578125}, {"start": 432.61, "end": 434.09, "word": " polarimeter", "probability": 0.5748291015625}, {"start": 434.09, "end": 434.53, "word": " برضه", "probability": 0.78369140625}, {"start": 434.53, "end": 435.21, "word": " chiral", "probability": 0.925048828125}, {"start": 435.21, "end": 436.23, "word": " بنسميه", "probability": 0.94140625}, {"start": 436.23, "end": 436.85, "word": " بلف", "probability": 0.870849609375}, {"start": 436.85, "end": 437.19, "word": " الضوء", "probability": 0.98583984375}, {"start": 437.19, "end": 437.63, "word": " ولكن", "probability": 0.879638671875}, {"start": 437.63, "end": 438.35, "word": " باتجاه", "probability": 0.9117431640625}], "temperature": 1.0}, {"id": 20, "seek": 46718, "start": 439.42, "end": 467.18, "text": "معاكس إذا صار عندى مركب chiral و مركب chiral طيب لو حطيت مركب من الأساس مافيه chiral center بلفش الضوء وجدت إيش بدى أسمي هذا المركب A chiral هنا ال A بتصير أداة نفي لاحظوا معناه .. لاحظوا معناه بتكونوا فاهمين شوية باللغة الإنجليزية أدوات النكرة و أدوات المعرفة يعني المركب هنا .. المركب هنا", "tokens": [2304, 3615, 995, 4117, 3794, 11933, 15730, 20328, 9640, 43242, 7578, 3714, 31747, 3555, 23782, 304, 4032, 3714, 31747, 3555, 23782, 304, 23032, 1829, 3555, 45164, 11331, 9566, 36081, 3714, 31747, 3555, 9154, 16247, 3794, 32277, 19446, 41185, 3224, 23782, 304, 3056, 4724, 1211, 5172, 8592, 6024, 114, 2407, 38207, 49610, 3215, 2655, 11933, 1829, 8592, 47525, 7578, 5551, 38251, 1829, 23758, 9673, 31747, 3555, 316, 23782, 304, 34105, 2423, 316, 39894, 9381, 13546, 5551, 28259, 3660, 8717, 41185, 20193, 5016, 19913, 14407, 20449, 8315, 3224, 4386, 20193, 5016, 19913, 14407, 20449, 8315, 3224, 39894, 30544, 14407, 6156, 995, 16095, 9957, 13412, 2407, 10632, 20666, 1211, 17082, 3660, 33688, 1863, 7435, 20292, 11622, 10632, 5551, 3215, 2407, 9307, 28239, 4117, 25720, 4032, 5551, 3215, 2407, 9307, 9673, 3615, 28480, 3660, 37495, 22653, 9673, 31747, 3555, 34105, 4386, 9673, 31747, 3555, 34105], "avg_logprob": -0.18364877222289502, "compression_ratio": 1.9291338582677164, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 439.42, "end": 440.22, "word": "معاكس", "probability": 0.953125}, {"start": 440.22, "end": 440.6, "word": " إذا", "probability": 0.687744140625}, {"start": 440.6, "end": 440.9, "word": " صار", "probability": 0.8505859375}, {"start": 440.9, "end": 441.14, "word": " عندى", "probability": 0.73095703125}, {"start": 441.14, "end": 441.56, "word": " مركب", "probability": 0.8084309895833334}, {"start": 441.56, "end": 442.12, "word": " chiral", "probability": 0.6153564453125}, {"start": 442.12, "end": 442.36, "word": " و", "probability": 0.962890625}, {"start": 442.36, "end": 442.82, "word": " مركب", "probability": 0.7962239583333334}, {"start": 442.82, "end": 443.22, "word": " chiral", "probability": 0.93798828125}, {"start": 443.22, "end": 443.74, "word": " طيب", "probability": 0.8650716145833334}, {"start": 443.74, "end": 443.88, "word": " لو", "probability": 0.9609375}, {"start": 443.88, "end": 444.26, "word": " حطيت", "probability": 0.8361002604166666}, {"start": 444.26, "end": 444.7, "word": " مركب", "probability": 0.9833984375}, {"start": 444.7, "end": 444.84, "word": " من", "probability": 0.91845703125}, {"start": 444.84, "end": 445.26, "word": " الأساس", "probability": 0.9599609375}, {"start": 445.26, "end": 445.66, "word": " مافيه", "probability": 0.6956380208333334}, {"start": 445.66, "end": 446.28, "word": " chiral", "probability": 0.895263671875}, {"start": 446.28, "end": 446.72, "word": " center", "probability": 0.8134765625}, {"start": 446.72, "end": 447.28, "word": " بلفش", "probability": 0.56884765625}, {"start": 447.28, "end": 447.64, "word": " الضوء", "probability": 0.9061279296875}, {"start": 447.64, "end": 448.3, "word": " وجدت", "probability": 0.6856689453125}, {"start": 448.3, "end": 448.44, "word": " إيش", "probability": 0.8369140625}, {"start": 448.44, "end": 448.66, "word": " بدى", "probability": 0.6854248046875}, {"start": 448.66, "end": 449.2, "word": " أسمي", "probability": 0.8621419270833334}, {"start": 449.2, "end": 449.4, "word": " هذا", "probability": 0.94482421875}, {"start": 449.4, "end": 450.16, "word": " المركب", "probability": 0.98388671875}, {"start": 450.16, "end": 451.44, "word": " A", "probability": 0.1558837890625}, {"start": 451.44, "end": 452.44, "word": " chiral", "probability": 0.93212890625}, {"start": 452.44, "end": 452.78, "word": " هنا", "probability": 0.69873046875}, {"start": 452.78, "end": 453.04, "word": " ال", "probability": 0.97607421875}, {"start": 453.04, "end": 453.3, "word": " A", "probability": 0.55908203125}, {"start": 453.3, "end": 453.92, "word": " بتصير", "probability": 0.8938802083333334}, {"start": 453.92, "end": 454.38, "word": " أداة", "probability": 0.8356119791666666}, {"start": 454.38, "end": 454.84, "word": " نفي", "probability": 0.8779296875}, {"start": 454.84, "end": 455.74, "word": " لاحظوا", "probability": 0.9276123046875}, {"start": 455.74, "end": 456.36, "word": " معناه", "probability": 0.8580729166666666}, {"start": 456.36, "end": 456.4, "word": " ..", "probability": 0.478759765625}, {"start": 456.4, "end": 456.78, "word": " لاحظوا", "probability": 0.9234619140625}, {"start": 456.78, "end": 457.18, "word": " معناه", "probability": 0.9889322916666666}, {"start": 457.18, "end": 457.84, "word": " بتكونوا", "probability": 0.8445638020833334}, {"start": 457.84, "end": 458.26, "word": " فاهمين", "probability": 0.908447265625}, {"start": 458.26, "end": 458.84, "word": " شوية", "probability": 0.8082682291666666}, {"start": 458.84, "end": 459.6, "word": " باللغة", "probability": 0.9874267578125}, {"start": 459.6, "end": 460.58, "word": " الإنجليزية", "probability": 0.9171549479166666}, {"start": 460.58, "end": 461.8, "word": " أدوات", "probability": 0.96630859375}, {"start": 461.8, "end": 462.74, "word": " النكرة", "probability": 0.80712890625}, {"start": 462.74, "end": 463.0, "word": " و", "probability": 0.84619140625}, {"start": 463.0, "end": 463.58, "word": " أدوات", "probability": 0.974365234375}, {"start": 463.58, "end": 464.42, "word": " المعرفة", "probability": 0.995361328125}, {"start": 464.42, "end": 464.88, "word": " يعني", "probability": 0.884033203125}, {"start": 464.88, "end": 465.58, "word": " المركب", "probability": 0.98193359375}, {"start": 465.58, "end": 466.0, "word": " هنا", "probability": 0.9853515625}, {"start": 466.0, "end": 466.22, "word": " ..", "probability": 0.70654296875}, {"start": 466.22, "end": 466.86, "word": " المركب", "probability": 0.9837239583333334}, {"start": 466.86, "end": 467.18, "word": " هنا", "probability": 0.9951171875}], "temperature": 1.0}, {"id": 21, "seek": 49610, "start": 468.9, "end": 496.1, "text": "كايرال ال a اللي موجودة فيه هي أداة نكرة ولذلك إذا أنا مثلا بدي أجي أحكي باللغة الإنقليزية أقول this is a chiral compound معناه ذلك هذا مركب بلف الضوء ال a أداة نكرة زي ما بنيجي نقول this is a table this is a pen واضح الفكرة؟ الآن لو كنت بدي أحكي عن مركب زي هذا شو بدي أقول عنه؟", "tokens": [4117, 995, 13546, 6027, 2423, 257, 13672, 1829, 3714, 29245, 23328, 3660, 8978, 3224, 39896, 5551, 28259, 3660, 8717, 4117, 25720, 35525, 8848, 23275, 11933, 15730, 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"probability": 0.373291015625}, {"start": 470.52, "end": 470.84, "word": " اللي", "probability": 0.815185546875}, {"start": 470.84, "end": 471.62, "word": " موجودة", "probability": 0.96044921875}, {"start": 471.62, "end": 472.0, "word": " فيه", "probability": 0.947998046875}, {"start": 472.0, "end": 472.46, "word": " هي", "probability": 0.80322265625}, {"start": 472.46, "end": 473.1, "word": " أداة", "probability": 0.8512369791666666}, {"start": 473.1, "end": 473.8, "word": " نكرة", "probability": 0.869140625}, {"start": 473.8, "end": 475.16, "word": " ولذلك", "probability": 0.84619140625}, {"start": 475.16, "end": 475.46, "word": " إذا", "probability": 0.81298828125}, {"start": 475.46, "end": 475.66, "word": " أنا", "probability": 0.7763671875}, {"start": 475.66, "end": 475.86, "word": " مثلا", "probability": 0.893310546875}, {"start": 475.86, "end": 476.06, "word": " بدي", "probability": 0.6978759765625}, {"start": 476.06, "end": 476.26, "word": " أجي", "probability": 0.677490234375}, {"start": 476.26, "end": 476.5, "word": " أحكي", "probability": 0.9581298828125}, {"start": 476.5, "end": 476.78, "word": " باللغة", "probability": 0.98388671875}, {"start": 476.78, "end": 477.36, "word": " الإنقليزية", "probability": 0.8899739583333334}, {"start": 477.36, "end": 477.74, "word": " أقول", "probability": 0.84716796875}, {"start": 477.74, "end": 478.32, "word": " this", "probability": 0.82275390625}, {"start": 478.32, "end": 478.92, "word": " is", "probability": 0.9638671875}, {"start": 478.92, "end": 479.48, "word": " a", "probability": 0.98095703125}, {"start": 479.48, "end": 480.34, "word": " chiral", "probability": 0.7139892578125}, {"start": 480.34, "end": 480.98, "word": " compound", "probability": 0.9541015625}, {"start": 480.98, "end": 481.66, "word": " معناه", "probability": 0.7819010416666666}, {"start": 481.66, "end": 481.94, "word": " ذلك", "probability": 0.978759765625}, {"start": 481.94, "end": 482.3, "word": " هذا", "probability": 0.95263671875}, {"start": 482.3, "end": 483.1, "word": " مركب", "probability": 0.8580729166666666}, {"start": 483.1, "end": 483.88, "word": " بلف", "probability": 0.890380859375}, {"start": 483.88, "end": 484.82, "word": " الضوء", "probability": 0.9515380859375}, {"start": 484.82, "end": 485.24, "word": " ال", "probability": 0.9287109375}, {"start": 485.24, "end": 485.46, "word": " a", "probability": 0.93505859375}, {"start": 485.46, "end": 485.9, "word": " أداة", "probability": 0.93310546875}, {"start": 485.9, "end": 486.26, "word": " نكرة", "probability": 0.9677734375}, {"start": 486.26, "end": 486.74, "word": " زي", "probability": 0.927978515625}, {"start": 486.74, "end": 486.82, "word": " ما", "probability": 0.9345703125}, {"start": 486.82, "end": 487.08, "word": " بنيجي", "probability": 0.875}, {"start": 487.08, "end": 487.32, "word": " نقول", "probability": 0.877685546875}, {"start": 487.32, "end": 487.62, "word": " this", "probability": 0.95458984375}, {"start": 487.62, "end": 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588.55, "end": 589.37, "word": " بيهدم", "probability": 0.990478515625}, {"start": 589.37, "end": 589.89, "word": " ايش", "probability": 0.6905924479166666}, {"start": 589.89, "end": 590.03, "word": " في", "probability": 0.869140625}, {"start": 590.03, "end": 590.31, "word": " نهاية", "probability": 0.8875325520833334}, {"start": 590.31, "end": 591.25, "word": " المحصلة؟", "probability": 0.81767578125}, {"start": 591.25, "end": 592.09, "word": " صفر", "probability": 0.9469401041666666}, {"start": 592.09, "end": 592.65, "word": " متى", "probability": 0.733154296875}, {"start": 592.65, "end": 593.05, "word": " يبلغ", "probability": 0.9921875}, {"start": 593.05, "end": 594.41, "word": " البنيانو؟", "probability": 0.86337890625}, {"start": 594.41, "end": 594.99, "word": " تماما", "probability": 0.9677734375}, {"start": 594.99, "end": 595.17, "word": " هو", "probability": 0.98583984375}, {"start": 595.17, "end": 595.59, "word": " أنت", "probability": 0.845947265625}, {"start": 595.59, "end": 596.05, "word": " تبني", "probability": 0.9700520833333334}, {"start": 596.05, "end": 596.89, "word": " وغيرك", "probability": 0.9208984375}, {"start": 596.89, "end": 597.81, "word": " يهدم", "probability": 0.9806315104166666}, {"start": 597.81, "end": 598.97, "word": " واضح", "probability": 0.88818359375}, {"start": 598.97, "end": 600.07, "word": " الفكرة؟", "probability": 0.9493408203125}, {"start": 600.07, "end": 600.63, "word": " ولذلك", "probability": 0.83740234375}, {"start": 600.63, "end": 601.09, "word": " إذا", "probability": 0.848388671875}, {"start": 601.09, "end": 601.37, "word": " كان", "probability": 0.99267578125}, {"start": 601.37, "end": 601.73, "word": " عندى", "probability": 0.6044921875}, {"start": 601.73, "end": 602.45, "word": " خليط", "probability": 0.9208984375}, {"start": 602.45, "end": 603.39, "word": " متساوي", "probability": 0.9688720703125}, {"start": 603.39, "end": 603.47, "word": " ..", "probability": 0.272216796875}, {"start": 603.47, "end": 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optically active ولا optically inactive؟ optically inactive طبعا هنا ممكن يجيني السؤال طب يا تورا لو كان عندي خليط بنسب غير متساوية", "tokens": [6027, 9778, 20292, 9566, 23782, 304, 49429, 2800, 35083, 28242, 3224, 2427, 984, 4967, 49429, 2427, 984, 294, 12596, 22807, 2427, 984, 294, 12596, 23032, 3555, 3615, 995, 34105, 3714, 43020, 7251, 7435, 9957, 1829, 21136, 33604, 6027, 23032, 3555, 35186, 6055, 13063, 995, 45164, 25961, 18871, 16254, 16490, 20292, 9566, 44945, 35457, 32771, 13546, 44650, 3794, 995, 2407, 10632], "avg_logprob": -0.13524590457072022, "compression_ratio": 1.5096774193548388, "no_speech_prob": 0.0, "words": [{"start": 610.32, "end": 611.56, "word": "الخليط", "probability": 0.9085693359375}, {"start": 611.56, "end": 612.72, "word": " chiral", "probability": 0.865478515625}, {"start": 612.72, "end": 613.04, "word": " ولا", "probability": 0.720703125}, {"start": 613.04, "end": 614.26, "word": " achiral", "probability": 0.789306640625}, {"start": 614.26, "end": 615.12, "word": " كله", "probability": 0.789794921875}, {"start": 615.12, "end": 615.82, "word": " optically", "probability": 0.79833984375}, {"start": 615.82, "end": 616.48, "word": " active", "probability": 0.97119140625}, {"start": 616.48, "end": 616.78, "word": " ولا", "probability": 0.931640625}, {"start": 616.78, "end": 617.36, "word": " optically", "probability": 0.94189453125}, {"start": 617.36, "end": 618.58, "word": " inactive؟", "probability": 0.7327473958333334}, {"start": 618.58, "end": 619.14, "word": " optically", "probability": 0.878173828125}, {"start": 619.14, "end": 619.66, "word": " inactive", "probability": 0.9453125}, {"start": 619.66, "end": 620.3, "word": " طبعا", "probability": 0.986083984375}, {"start": 620.3, "end": 620.48, "word": " هنا", "probability": 0.87939453125}, {"start": 620.48, "end": 620.9, "word": " ممكن", "probability": 0.869384765625}, {"start": 620.9, "end": 621.38, "word": " يجيني", "probability": 0.8980712890625}, {"start": 621.38, "end": 621.94, "word": " السؤال", "probability": 0.9949544270833334}, {"start": 621.94, "end": 622.96, "word": " طب", "probability": 0.813720703125}, {"start": 622.96, "end": 623.26, "word": " يا", "probability": 0.90478515625}, {"start": 623.26, "end": 623.72, "word": " تورا", "probability": 0.7278645833333334}, {"start": 623.72, "end": 624.08, "word": " لو", "probability": 0.98095703125}, {"start": 624.08, "end": 624.36, "word": " كان", "probability": 0.978515625}, {"start": 624.36, "end": 624.66, "word": " عندي", "probability": 0.765869140625}, {"start": 624.66, "end": 626.02, "word": " خليط", "probability": 0.9505208333333334}, {"start": 626.02, "end": 626.74, "word": " بنسب", "probability": 0.949462890625}, {"start": 626.74, "end": 627.2, "word": " غير", "probability": 0.99560546875}, {"start": 627.2, "end": 628.3, "word": " متساوية", "probability": 0.9580078125}], "temperature": 1.0}, {"id": 28, "seek": 64211, "start": 630.33, "end": 642.11, "text": "يعني مثلا خلطت من ال isomer الموجب نسبة 70% من ال isomer السالب نسبة 30% هذا الخليط", "tokens": [40228, 22653, 50113, 15040, 16490, 1211, 9566, 2655, 9154, 2423, 307, 14301, 9673, 29245, 3555, 8717, 35457, 3660, 5285, 4, 9154, 2423, 307, 14301, 21136, 6027, 3555, 8717, 35457, 3660, 2217, 4, 23758, 33962, 20292, 9566], "avg_logprob": -0.17535895431363904, "compression_ratio": 1.346938775510204, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 630.33, "end": 630.89, "word": "يعني", "probability": 0.672119140625}, {"start": 630.89, "end": 631.67, "word": " مثلا", "probability": 0.908447265625}, {"start": 631.67, "end": 632.31, "word": " خلطت", "probability": 0.94921875}, {"start": 632.31, "end": 632.49, "word": " من", "probability": 0.984375}, {"start": 632.49, "end": 632.67, "word": " ال", "probability": 0.8330078125}, {"start": 632.67, "end": 633.27, "word": " isomer", "probability": 0.43499755859375}, {"start": 633.27, "end": 634.07, "word": " الموجب", "probability": 0.8400065104166666}, {"start": 634.07, "end": 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644.42, "end": 663.44, "text": "هيكون optically active هذا الخليط هيكون optically active ولكن بشكل ايش؟ جزئي بشكل جزئي تماما زي ما بنيجي نقول مثلا بني ادم الله ربح سبعين كذا خسر تلاتين كدهش في النهاية؟", "tokens": [3224, 1829, 30544, 2427, 984, 4967, 23758, 33962, 20292, 9566, 39896, 30544, 2427, 984, 4967, 35525, 19452, 4724, 8592, 28820, 1975, 1829, 8592, 22807, 10874, 11622, 19986, 1829, 4724, 8592, 28820, 10874, 11622, 19986, 1829, 46811, 10943, 995, 30767, 1829, 19446, 44945, 1829, 7435, 1829, 8717, 39648, 50113, 15040, 4724, 22653, 1975, 40448, 21984, 12602, 49628, 8608, 3555, 3615, 9957, 9122, 15730, 16490, 3794, 2288, 6055, 1211, 9307, 9957, 9122, 3215, 3224, 8592, 8978, 28239, 11296, 10632, 22807], "avg_logprob": -0.18552215831189217, "compression_ratio": 1.606936416184971, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 644.42, "end": 645.54, "word": "هيكون", "probability": 0.8170572916666666}, {"start": 645.54, "end": 646.66, "word": " optically", "probability": 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معين يتطابق معاه نجيب المفتاح التاني مابفتحش مستفدناش اشي و لذلك في الخواص الكيميائية ال enantiomers لهم نفس الخواص الكيميائية ما عدا", "tokens": [2304, 25720, 6055, 7649, 10632, 6055, 8592, 3555, 3224, 12174, 9381, 3660, 9673, 5172, 2655, 39319, 16070, 8848, 28480, 26895, 32545, 28480, 26895, 9122, 995, 48923, 27188, 2288, 5718, 118, 1829, 4724, 25708, 3224, 3714, 5172, 2655, 39319, 20449, 9957, 7251, 2655, 9566, 16758, 4587, 20449, 40294, 8717, 7435, 1829, 3555, 9673, 5172, 2655, 39319, 16712, 7649, 1829, 3714, 16758, 5172, 2655, 5016, 8592, 3714, 14851, 5172, 3215, 8315, 8592, 1975, 8592, 1829, 4032, 5296, 8848, 23275, 8978, 33962, 2407, 33546, 33251, 32640, 1829, 16373, 10632, 2423, 465, 11520, 298, 433, 5296, 16095, 8717, 36178, 33962, 2407, 33546, 33251, 32640, 1829, 16373, 10632, 19446, 6225, 28259], "avg_logprob": -0.22663550816963765, "compression_ratio": 1.8608247422680413, "no_speech_prob": 0.0, "words": [{"start": 1512.77, "end": 1513.21, "word": "مرة", "probability": 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{"start": 1528.31, "end": 1529.39, "word": " الكيميائية", "probability": 0.88916015625}, {"start": 1529.39, "end": 1531.73, "word": " ال", "probability": 0.5751953125}, {"start": 1531.73, "end": 1532.87, "word": " enantiomers", "probability": 0.684478759765625}, {"start": 1532.87, "end": 1533.63, "word": " لهم", "probability": 0.7354736328125}, {"start": 1533.63, "end": 1534.27, "word": " نفس", "probability": 0.991455078125}, {"start": 1534.27, "end": 1534.97, "word": " الخواص", "probability": 0.9366861979166666}, {"start": 1534.97, "end": 1535.95, "word": " الكيميائية", "probability": 0.92412109375}, {"start": 1535.95, "end": 1536.55, "word": " ما", "probability": 0.8388671875}, {"start": 1536.55, "end": 1537.09, "word": " عدا", "probability": 0.84619140625}], "temperature": 1.0}, {"id": 69, "seek": 155894, "start": 1537.8, "end": 1558.94, "text": "اذا اتفعلوا مع مركبات فراغية زيهم يعني لما بتفعل ال chiral مع ال chiral اشي ماخد اتجاه فراغي شمال او يمين مع اشي ماخد اتجاه فراغي شمال او يمين بيصير الاختلاف زي الزرفيل بتاع الباب في شمال ويمين جوا والمفتاح في شمال ويمين بيصير مفتاح معين", "tokens": [45636, 995, 1975, 2655, 5172, 30241, 14407, 20449, 3714, 31747, 3555, 9307, 6156, 2288, 5718, 118, 10632, 30767, 1829, 16095, 37495, 22653, 5296, 15042, 39894, 5172, 30241, 2423, 23782, 304, 20449, 2423, 23782, 304, 1975, 8592, 1829, 3714, 47283, 3215, 1975, 2655, 7435, 40294, 6156, 2288, 5718, 118, 1829, 13412, 2304, 6027, 1975, 2407, 7251, 2304, 9957, 20449, 1975, 8592, 1829, 3714, 47283, 3215, 1975, 2655, 7435, 40294, 6156, 2288, 5718, 118, 1829, 13412, 2304, 6027, 1975, 2407, 7251, 2304, 9957, 4724, 1829, 9381, 13546, 2423, 47283, 2655, 15040, 5172, 30767, 1829, 6024, 110, 28480, 26895, 39894, 45761, 29739, 16758, 8978, 13412, 2304, 6027, 4032, 32640, 9957, 10874, 14407, 4032, 45340, 5172, 2655, 39319, 8978, 13412, 2304, 6027, 4032, 32640, 9957, 4724, 1829, 9381, 13546, 3714, 5172, 2655, 39319, 20449, 9957], "avg_logprob": -0.1263020901065884, "compression_ratio": 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المريض بيروح على المستشفى لما المريض بيروح على المستشفى و بيقولوا بدنا نعطيه محلول سكر بتعرفوا بيعطيه واحد من الاتنين و تلاتين", "tokens": [2655, 9778, 26895, 14407, 14739, 3224, 47525, 8315, 8717, 2655, 3615, 19528, 5296, 15042, 8717, 1829, 7435, 1829, 8717, 47283, 3215, 21136, 37983, 21136, 3215, 32277, 1829, 9673, 47283, 3215, 31767, 1829, 17082, 3660, 18863, 10943, 3660, 383, 21, 39, 4762, 46, 21, 47525, 8315, 8717, 2288, 38251, 37893, 3714, 31747, 3555, 36764, 24401, 1975, 2655, 1863, 9957, 4032, 6055, 1211, 9307, 9957, 3714, 31747, 3555, 4032, 8717, 3615, 28480, 16095, 4032, 8717, 2304, 1829, 11622, 16095, 20666, 32277, 2304, 2423, 7649, 5296, 15042, 9673, 16572, 11242, 4724, 13546, 2407, 5016, 15844, 9673, 14851, 8592, 5172, 7578, 5296, 15042, 9673, 16572, 11242, 4724, 13546, 2407, 5016, 15844, 9673, 14851, 8592, 5172, 7578, 4032, 4724, 1829, 39648, 14407, 47525, 8315, 8717, 3615, 9566, 1829, 3224, 3714, 5016, 1211, 12610, 8608, 37983, 39894, 3615, 28480, 14407, 4724, 40228, 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dichlorination مش monochlorination ربما ان انتوا حليتوا السؤال لكن بدون ماشي", "tokens": [6027, 7649, 45164, 1975, 31371, 8315, 1975, 5016, 8315, 47525, 8315, 8717, 11622, 25708, 16490, 9566, 2407, 3660, 47525, 8315, 8717, 39648, 309, 311, 732, 18178, 996, 317, 2315, 4724, 3794, 8717, 25957, 43761, 10390, 6746, 2486, 37893, 1108, 8997, 6746, 2486, 12602, 3555, 15042, 16472, 16472, 2655, 14407, 11331, 1211, 36081, 14407, 21136, 33604, 6027, 44381, 47525, 11536, 3714, 33599, 1829], "avg_logprob": -0.2157738090507568, "compression_ratio": 1.44375, "no_speech_prob": 0.0, "words": [{"start": 2211.06, "end": 2211.68, "word": "الان", "probability": 0.812744140625}, {"start": 2211.68, "end": 2212.38, "word": " لو", "probability": 0.9375}, {"start": 2212.38, "end": 2213.04, "word": " اتينا", "probability": 0.69287109375}, {"start": 2213.04, "end": 2213.56, "word": " احنا", "probability": 0.939453125}, {"start": 2213.56, "end": 2214.42, "word": " بدنا", "probability": 0.796875}, {"start": 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2294.98, "end": 2295.22, "word": " هنا", "probability": 0.96826171875}, {"start": 2295.22, "end": 2295.9, "word": " تخيلوا", "probability": 0.958984375}, {"start": 2295.9, "end": 2296.24, "word": " لما", "probability": 0.801513671875}, {"start": 2296.24, "end": 2296.56, "word": " تحطوا", "probability": 0.9793701171875}, {"start": 2296.56, "end": 2296.7, "word": " هنا", "probability": 0.9150390625}, {"start": 2296.7, "end": 2297.04, "word": " CL", "probability": 0.34716796875}, {"start": 2297.04, "end": 2297.44, "word": " ما", "probability": 0.59521484375}, {"start": 2297.44, "end": 2297.66, "word": " زال", "probability": 0.917236328125}, {"start": 2297.66, "end": 2298.04, "word": " عندكم", "probability": 0.9765625}, {"start": 2298.04, "end": 2298.88, "word": " CH2", "probability": 0.9775390625}, {"start": 2298.88, "end": 2299.34, "word": " مش", "probability": 0.896484375}, {"start": 2299.34, "end": 2299.84, "word": " chiral", "probability": 0.9384765625}, {"start": 2299.84, "end": 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لو", "probability": 0.96630859375}, {"start": 2306.64, "end": 2306.86, "word": " انا", "probability": 0.7958984375}, {"start": 2306.86, "end": 2307.38, "word": " جبتلكوا", "probability": 0.87451171875}, {"start": 2307.38, "end": 2308.28, "word": " سؤال", "probability": 0.9568684895833334}, {"start": 2308.28, "end": 2308.86, "word": " ال", "probability": 0.97705078125}, {"start": 2308.86, "end": 2309.1, "word": " one", "probability": 0.513671875}, {"start": 2309.1, "end": 2309.86, "word": " five", "probability": 0.8076171875}, {"start": 2309.86, "end": 2312.0, "word": " dichlorobentane", "probability": 0.6947224934895834}, {"start": 2312.0, "end": 2312.44, "word": " has", "probability": 0.76318359375}, {"start": 2312.44, "end": 2313.22, "word": " two", "probability": 0.93359375}, {"start": 2313.22, "end": 2314.64, "word": " stereoisomers", "probability": 0.9366455078125}, {"start": 2314.64, "end": 2315.34, "word": " طلعوا", "probability": 0.9312744140625}, {"start": 2315.34, "end": 2316.1, "word": " معاه", "probability": 0.7161865234375}, {"start": 2316.1, "end": 2316.36, "word": " هي", "probability": 0.454345703125}, {"start": 2316.36, "end": 2316.88, "word": " كلور", "probability": 0.56475830078125}, {"start": 2316.88, "end": 2317.68, "word": " هي", "probability": 0.775390625}, {"start": 2317.68, "end": 2318.14, "word": " كلور", "probability": 0.968994140625}], "temperature": 1.0}, {"id": 101, "seek": 234531, "start": 2318.81, "end": 2345.31, "text": "شوفوا هنا كم كايرال سنتر فيه CH2H2H2H2 ولا كايرال سنتر إذا ال 1,5 ده يكلوره بين 2 فيه مركب واحد لكن لو أنا كنت مثلا باجي بسألكم ال 1,2 هيكلور أكيد هنا H هنا CL هتكون مكملة H2 HH صح ولا لأ هذا كم مركب منه 2", "tokens": [8592, 38688, 14407, 34105, 9122, 2304, 9122, 995, 13546, 6027, 8608, 29399, 2288, 8978, 3224, 5995, 17, 39, 17, 39, 17, 39, 17, 49429, 9122, 995, 13546, 6027, 8608, 29399, 2288, 11933, 15730, 2423, 502, 11, 20, 11778, 3224, 7251, 28820, 13063, 3224, 49374, 568, 8978, 3224, 3714, 31747, 3555, 36764, 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"probability": 0.56201171875}, {"start": 2329.21, "end": 2329.55, "word": " مركب", "probability": 0.9005533854166666}, {"start": 2329.55, "end": 2329.85, "word": " واحد", "probability": 0.935791015625}, {"start": 2329.85, "end": 2330.41, "word": " لكن", "probability": 0.88671875}, {"start": 2330.41, "end": 2330.85, "word": " لو", "probability": 0.96630859375}, {"start": 2330.85, "end": 2331.09, "word": " أنا", "probability": 0.8212890625}, {"start": 2331.09, "end": 2331.29, "word": " كنت", "probability": 0.961669921875}, {"start": 2331.29, "end": 2331.65, "word": " مثلا", "probability": 0.9814453125}, {"start": 2331.65, "end": 2331.99, "word": " باجي", "probability": 0.93359375}, {"start": 2331.99, "end": 2332.71, "word": " بسألكم", "probability": 0.8654296875}, {"start": 2332.71, "end": 2333.17, "word": " ال", "probability": 0.96044921875}, {"start": 2333.17, "end": 2333.39, "word": " 1", "probability": 0.861328125}, {"start": 2333.39, "end": 2333.71, "word": ",2", "probability": 0.9755859375}, {"start": 2333.71, "end": 2335.07, "word": " هيكلور", "probability": 0.697509765625}, {"start": 2335.07, "end": 2335.49, "word": " أكيد", "probability": 0.853515625}, {"start": 2335.49, "end": 2335.77, "word": " هنا", "probability": 0.89892578125}, {"start": 2335.77, "end": 2336.11, "word": " H", "probability": 0.92041015625}, {"start": 2336.11, "end": 2336.49, "word": " هنا", "probability": 0.69580078125}, {"start": 2336.49, "end": 2337.79, "word": " CL", "probability": 0.7041015625}, {"start": 2337.79, "end": 2338.75, "word": " هتكون", "probability": 0.8216145833333334}, {"start": 2338.75, "end": 2339.17, "word": " مكملة", "probability": 0.77685546875}, {"start": 2339.17, "end": 2339.97, "word": " H2", "probability": 0.907470703125}, {"start": 2339.97, "end": 2340.99, "word": " HH", "probability": 0.3681640625}, {"start": 2340.99, "end": 2343.05, "word": " صح", "probability": 0.989501953125}, {"start": 2343.05, "end": 2343.21, "word": " ولا", "probability": 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{"start": 2358.89, "end": 2359.25, "word": " H2", "probability": 0.89697265625}, {"start": 2359.25, "end": 2359.37, "word": " و", "probability": 0.828125}, {"start": 2359.37, "end": 2359.49, "word": " هذه", "probability": 0.79296875}, {"start": 2359.49, "end": 2359.83, "word": " H2", "probability": 0.978271484375}, {"start": 2359.83, "end": 2359.93, "word": " و", "probability": 0.9794921875}, {"start": 2359.93, "end": 2360.07, "word": " هذه", "probability": 0.87451171875}, {"start": 2360.07, "end": 2360.63, "word": " H3", "probability": 0.9873046875}, {"start": 2360.63, "end": 2361.57, "word": " one", "probability": 0.81298828125}, {"start": 2361.57, "end": 2362.11, "word": " chiral", "probability": 0.984375}, {"start": 2362.11, "end": 2362.59, "word": " center", "probability": 0.93505859375}, {"start": 2362.59, "end": 2363.11, "word": " إذا", "probability": 0.707275390625}, {"start": 2363.11, "end": 2363.27, "word": " ال", "probability": 0.97265625}, {"start": 2363.27, "end": 2363.43, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e3cff9744b87d28d777fdb0c75d8ccc79873fa43
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU.srt
@@ -0,0 +1,1451 @@
+
+1
+00:00:20,990 --> 00:00:24,950
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:24,950 --> 00:00:29,290
+تفاعلات ال alkenes وقلنا اللى بينظر للموضوع نظرة
+
+3
+00:00:29,290 --> 00:00:34,610
+كلية الموضوع بسيط الموضوع انه double bond هيوم
+
+4
+00:00:34,610 --> 00:00:40,230
+رابطتين بالاضافة بتصير single bond هذه العملية شو
+
+5
+00:00:40,230 --> 00:00:46,110
+بنسميها عملية addition عملية addition واتفقنا ان
+
+6
+00:00:46,110 --> 00:00:48,810
+في ال addition فى عندنا مكونات لل addition فى
+
+7
+00:00:48,810 --> 00:00:52,730
+عندنا ال alkeneو في عندنا ال reagent وهذا ممكن
+
+8
+00:00:52,730 --> 00:00:56,610
+يكون symmetric و لا unsymmetric وهذا نفس الشيء و
+
+9
+00:00:56,610 --> 00:00:59,610
+دائما قلنا بدنا ننتبه لو كان في عندنا
+
+10
+00:00:59,610 --> 00:01:03,550
+unsymmetrical alkene مع unsymmetrical reagent
+
+11
+00:01:03,550 --> 00:01:09,070
+بنتوقع انه بيكون عندنا two products الآن هنبدأ
+
+12
+00:01:09,070 --> 00:01:13,510
+ناخد أمثلة على هذا الموضوع تحديدا لو بدنا نتكلم
+
+13
+00:01:13,510 --> 00:01:18,580
+على إضافة الماء إضافة الماء، الماء بيضيف جزء إيه؟
+
+14
+00:01:18,580 --> 00:01:25,940
+بيضيف H و O H هذه العملية بنسميها hydration لاحظوا
+
+15
+00:01:25,940 --> 00:01:30,780
+أنه عمليات الإضافة حسب ال reagent يعني المرة
+
+16
+00:01:30,780 --> 00:01:35,840
+الماضية إحنا لما إضفنا ال hydrogen عملية إضافة ال
+
+17
+00:01:35,840 --> 00:01:42,940
+hydrogen hydrogenation اسمها واضح؟عملية إضافة
+
+18
+00:01:42,940 --> 00:01:49,120
+الهيدروجين الان ممكن نضيف الهالوجين بشكل عام
+
+19
+00:01:49,120 --> 00:01:57,020
+بنسميها الهالوجيناشن طبعا بشكل خاص إكلوريناشن
+
+20
+00:01:57,020 --> 00:02:05,100
+بروميناشن و هكذا ممكن نضيف الميه بنسميها هيدريشن
+
+21
+00:02:05,100 --> 00:02:14,210
+إضافة الميه Hydration واضح؟ ممكن نضيف HX خلّينا
+
+22
+00:02:14,210 --> 00:02:22,530
+نقول HBR و لا HCL على الطرفين الرابطة HX بنسميها
+
+23
+00:02:22,530 --> 00:02:27,530
+Hydro لأن فيها Hydrogen Hydro وHalogen
+
+24
+00:02:27,530 --> 00:02:34,730
+Halogenation Hydro Halogenation كل هذه العمليات هي
+
+25
+00:02:34,730 --> 00:02:40,670
+عمليات إيش؟ إضافة إذا إليها أسماء hydrogenation,
+
+26
+00:02:40,750 --> 00:02:44,430
+halogenation, hydration, hydrohalogenation
+
+27
+00:02:44,430 --> 00:02:49,010
+ابتفاعلات تانية هنتعلمها بعدين و هتلاحظوا إنه في
+
+28
+00:02:49,010 --> 00:02:53,430
+الكيميا العضوية دائما عندكم الشغلات المتعاكسة
+
+29
+00:02:53,430 --> 00:02:57,770
+بمعنىان ال double bond لما اضيف عليها reagent
+
+30
+00:02:57,770 --> 00:03:01,370
+بتصير single bond يعني لو افترضنا ان هاي double
+
+31
+00:03:01,370 --> 00:03:06,030
+bond اضفت عليها reagent الناتج single bond الان لو
+
+32
+00:03:06,030 --> 00:03:11,470
+هذه ال single bond ابتفاعل تاني رفعت منها شغلتين
+
+33
+00:03:11,470 --> 00:03:16,510
+هتصير double bond اذا انا ممكن اعمل اضافة و ممكن
+
+34
+00:03:16,510 --> 00:03:22,760
+اعمل حذف واضح ال elimination بسميه فزي ما في عند ا
+
+35
+00:03:22,760 --> 00:03:28,840
+addition في عند كمان عكسه elimination هذه عمليات
+
+36
+00:03:28,840 --> 00:03:34,860
+ال elimination أيضا لها أسماء بمعنى لو كنا بنحذف
+
+37
+00:03:34,860 --> 00:03:39,240
+ذرتين هيدروجين و بنعمل double bond تاني هنسمي
+
+38
+00:03:39,240 --> 00:03:44,880
+العملية dehydrogenation هستخدم ل prefix دي هذا
+
+39
+00:03:44,880 --> 00:03:51,360
+للنفيD فحقول dehydrogenation لو كنت برفع زرتين
+
+40
+00:03:51,360 --> 00:03:58,300
+كلور او بروم Dehydrogenation لو كنت برفع HOH
+
+41
+00:03:58,300 --> 00:04:03,900
+Dehydration هذه الكلمة الشهيرة نزع الماء
+
+42
+00:04:03,900 --> 00:04:07,520
+Dehydration
+
+43
+00:04:08,520 --> 00:04:12,700
+لو كنا بنرفع ال .. ال hydrogen وال halogen
+
+44
+00:04:12,700 --> 00:04:17,120
+dehydrohalogenation واضح؟ dehydrohalogenation
+
+45
+00:04:17,120 --> 00:04:21,640
+ولذلك بتلاقوا هذه الكلمة انتبهولها جيدا واحفظوها
+
+46
+00:04:21,640 --> 00:04:26,460
+انتوا في المستقبل بتصيروا أمهات dehydration لما
+
+47
+00:04:26,460 --> 00:04:30,620
+الأطفال الصغار بيمرضوا بتروح فيهم على المستشفيات
+
+48
+00:04:30,620 --> 00:04:35,630
+بيكون ..عندهم جفاف فالطبيب ايش بيقول عنه عنده
+
+49
+00:04:35,630 --> 00:04:40,070
+dehydration يعني فقد الماء اللي عنده صار عنده جفاف
+
+50
+00:04:40,070 --> 00:04:44,350
+فبيسموها بالانجليزي ايش الجفاف dehydration يعني
+
+51
+00:04:44,350 --> 00:04:48,370
+ايه تسمعوا عن الطفل عنده dehydration لازم تعطوه
+
+52
+00:04:48,370 --> 00:04:53,830
+ايش محليل الان اول شئ بدنا نبدأ فيه ال hydration
+
+53
+00:04:53,830 --> 00:04:57,750
+اضافة الماء الان اضافة الماء على طرفين الرابط
+
+54
+00:04:57,750 --> 00:05:05,860
+الزوجية شو هيحط عنده H و OH واضح القصة طبعا في كل
+
+55
+00:05:05,860 --> 00:05:09,920
+شيء في تفاصيل كثيرة لكن احنا احيانا بنتجوزها في ال
+
+56
+00:05:09,920 --> 00:05:12,880
+course العام يعني كيف بنضافه مش مشكلة المهم ان ال
+
+57
+00:05:12,880 --> 00:05:17,600
+double bond راحت ال bi bond ألغيت صارت two new
+
+58
+00:05:17,600 --> 00:05:24,160
+sigma bonds واحدة H واحدة OH هذا التفاعل بشكل عام
+
+59
+00:05:24,160 --> 00:05:31,000
+الان لو اتيت للتفاعل بحالة خاصة اتطلعت على هذا الـ
+
+60
+00:05:31,000 --> 00:05:35,620
+Alkene اللي هو الـ Isobutyl الان لو اتطلعت على هذا
+
+61
+00:05:35,620 --> 00:05:40,380
+ال Isobutyl هتلاحظوا انه Unsymmetrical الكين بمعنى
+
+62
+00:05:40,380 --> 00:05:43,860
+لو اتيت في نص ال bubble bond اتخيلت اني بدأ اجسم
+
+63
+00:05:43,860 --> 00:05:50,680
+نصين هلعنى C ايش بتحمل؟ H و H مختصرات وهنا C بتحمل
+
+64
+00:05:50,680 --> 00:05:57,620
+CH3 و CH3 طيب لما أنا بدي أضيف الميه نتخيل الميه
+
+65
+00:05:57,620 --> 00:06:02,560
+هدول الجزئين الأزرق و الأحمر بدي أضيف الميه هل يا
+
+66
+00:06:02,560 --> 00:06:07,620
+تورا ال H نعتبرها الزرقه نعتبر ال H الزرقه و ال OH
+
+67
+00:06:07,620 --> 00:06:12,980
+الحمره هل يا تورا بدي أحط هنا ال H و هنا ال OH ولا
+
+68
+00:06:12,980 --> 00:06:15,200
+هنا ال H و هنا ال OH
+
+69
+00:06:19,900 --> 00:06:24,640
+من الناحية النظرية البحتة، من ناحية النظرية
+
+70
+00:06:24,640 --> 00:06:29,560
+البحتة، لو احنا بنقول لطفل صغير تعال شيل هادي وحق
+
+71
+00:06:29,560 --> 00:06:36,060
+التنتين، ممكن يعمل هيك و ممكن يعمل هيك، من ناحية
+
+72
+00:06:36,060 --> 00:06:41,000
+النظرية البحتة، الأمرين ممكنين، مافيش فيهم ولا
+
+73
+00:06:41,000 --> 00:06:47,280
+مشكلة الان هدولة الأمرين احنا اعطيناهم اسماء قولنا
+
+74
+00:06:47,280 --> 00:06:53,500
+اذا بنضيف الهيدروجين على الكربون اللى بتحمل
+
+75
+00:06:53,500 --> 00:06:57,520
+هيدروجين اكثر هذه الان لو فصلناها بشكل كامل هي
+
+76
+00:06:57,520 --> 00:07:03,850
+عبارة عن C بتحمل H وH تمام؟ هذه C لا تحمل اش ولا
+
+77
+00:07:03,850 --> 00:07:08,950
+اتش لو ضفنا الهيدروجين على الكاربون اللي حامل
+
+78
+00:07:08,950 --> 00:07:13,630
+هيدروجين اكثر بنقول هذه الإضافة حسب قواعد
+
+79
+00:07:13,630 --> 00:07:17,650
+Markovnikov أو حسب قاعدة Markovnikov وقتها بروح
+
+80
+00:07:17,650 --> 00:07:22,190
+بحط ال H هنا نفترض باللون الأزرق و ال O أتش هنا و
+
+81
+00:07:22,190 --> 00:07:28,710
+بطلع عندى ناتج واضح؟ ان جرب نعمل الجواب لو جربنا
+
+82
+00:07:28,710 --> 00:07:36,900
+هنحط CCH3 CH3 وهذه ستصبح single bond CH2 هذا ما
+
+83
+00:07:36,900 --> 00:07:46,540
+كان موجود أصلا كله ما جاء عليه H و OH الأن بهذا
+
+84
+00:07:46,540 --> 00:07:50,560
+الشكل الهيدروجين جاء على أي كربون على اللي حملة
+
+85
+00:07:50,560 --> 00:07:56,940
+هيدروجين أكتر وهذه الإضافة بنسميها إضافة حسب قاعدة
+
+86
+00:07:56,940 --> 00:07:58,140
+Markov-Nikov
+
+87
+00:08:05,760 --> 00:08:11,760
+ماركوف نيكوفز اديشن اضافة ماركوف نيكوفز اضافة
+
+88
+00:08:11,760 --> 00:08:12,480
+ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف
+
+89
+00:08:12,480 --> 00:08:14,080
+نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز
+
+90
+00:08:14,080 --> 00:08:14,240
+اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة
+
+91
+00:08:14,240 --> 00:08:14,300
+ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف
+
+92
+00:08:14,300 --> 00:08:15,260
+نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز
+
+93
+00:08:15,260 --> 00:08:19,420
+اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة
+
+94
+00:08:19,420 --> 00:08:26,320
+ماركوف نيكوفز اضاف CH3 CH3 وهخلّي هذه single bond
+
+95
+00:08:26,320 --> 00:08:31,380
+CH2 هاي الألكين الأصلي و أحطهم بالعكس يعني ال H
+
+96
+00:08:31,380 --> 00:08:41,120
+هنا و ال OH هنا إيش
+
+97
+00:08:41,120 --> 00:08:49,170
+المانع؟ مش مانع هاي إضافة مية وهي إضافة مية هذه
+
+98
+00:08:49,170 --> 00:08:54,330
+الإضافة بنعطيها اسم بنقولها Anti-Markovnikov
+
+99
+00:08:54,330 --> 00:08:58,650
+addition إضافة عكس قاعدة Markovnikov
+
+100
+00:09:03,760 --> 00:09:07,420
+Nikov's addition إذا يمكن أن تكون الإضافة زيك
+
+101
+00:09:07,420 --> 00:09:10,380
+ويمكن أن تكون زيك هتقولوا طب وإحنا شو بده يعرفنا
+
+102
+00:09:10,380 --> 00:09:16,380
+كيف نعمل الإضافة بنقول أه حسب ال reagent المستعمل
+
+103
+00:09:16,380 --> 00:09:22,200
+الماء يمكن أن يضيف بهذا الشكل وينتج المركب اللي
+
+104
+00:09:22,200 --> 00:09:25,960
+أمامنا هنا على الجهة اليامين ويمكن أنه يضيف بالشكل
+
+105
+00:09:25,960 --> 00:09:31,500
+التاني وينتج مركب تانيممكن يعطي ناتج إضافة حسب
+
+106
+00:09:31,500 --> 00:09:35,480
+قاعدة Markovnikov وممكن يعطي عكسها هتقولولنا طب
+
+107
+00:09:35,480 --> 00:09:39,440
+وقت إيش بيعمل هيك ووقت إيش بيعمل هيك الجواب بسيط
+
+108
+00:09:39,440 --> 00:09:42,680
+لأ وإحنا بنحكي الصورة الكلية اللي تفهم من خلالها
+
+109
+00:09:42,680 --> 00:09:46,440
+إذا كانت إضافة الماء يعني هنا على السهم كتبنا
+
+110
+00:09:46,440 --> 00:09:51,980
+الماء في وجود الحامض H plus فإنه يضيف حسب قاعدة
+
+111
+00:09:51,980 --> 00:09:57,190
+Markovnikov إذا عرفنا ما الشرط الذي من خلاله تتم
+
+112
+00:09:57,190 --> 00:10:02,570
+الإضافة حسب قاعدة Markov Nikov أن نضيف الماء في
+
+113
+00:10:02,570 --> 00:10:08,950
+وجود كمية قليلة من الحامض وجدها بنضيف حسب قاعدة
+
+114
+00:10:08,950 --> 00:10:17,600
+Markov Nikov الآن طب كيف بضيف عكس قاعدة Markovnikov
+
+115
+00:10:17,600 --> 00:10:21,200
+إذا 
+
+116
+00:10:21,200 --> 00:10:28,020
+ضفنا الماء باستعمال reagent مختلف طبعا ظروف كاملة
+
+117
+00:10:28,020 --> 00:10:34,520
+مختلفة باستعمال مركب ال borane اللي بنقوله BH3 طبعا
+
+118
+00:10:34,520 --> 00:10:39,660
+بعد هيكذا البرين بنحط عليه H2O2 هيدروجين بيروكسايد
+
+119
+00:10:39,660 --> 00:10:46,180
+لو ضفنا في وجود هذه المتفاعلات بضيف عكس قاعدة
+
+120
+00:10:46,180 --> 00:10:52,160
+ماركوف نيكوف طبعا ربما الآن بدت الصورة تتضح لكم
+
+121
+00:10:52,160 --> 00:10:56,980
+لأنه انا حاسس الصمت عندكم لأن انتوا اتعلمتوا نص
+
+122
+00:10:56,980 --> 00:11:01,180
+المعلومة بالثانوية انه الإضافة فقط حسب قاعدة
+
+123
+00:11:01,180 --> 00:11:05,560
+Markovnikov حسب قاعدة Markovnikov ضمن هذا الشرط
+
+124
+00:11:05,560 --> 00:11:11,480
+غير الشرط تحصل على إضافة عكس قاعدة Markovnikov إذا 
+
+125
+00:11:11,480 --> 00:11:17,710
+الأمرين ممكنين واضح؟ اللي اتعلمتوا بالثانوية نص
+
+126
+00:11:17,710 --> 00:11:23,030
+القصة مش كل القصة، واضح؟ اللي اتعلمته بالثانوية
+
+127
+00:11:23,030 --> 00:11:29,390
+نصف هذه القصة مش كلها فقط، الآن احنا استكملنا
+
+128
+00:11:29,390 --> 00:11:32,850
+القصة لكم، اننا نقولكم لأ والله يا المية بتضيف
+
+129
+00:11:34,860 --> 00:11:39,160
+الميّه بتضيف بالطريقتين هذا الكلام بعد شوية
+
+130
+00:11:39,160 --> 00:11:43,520
+هتلاحظوه مش بسمع الميّه هذا الكلام بعد شوية
+
+131
+00:11:43,520 --> 00:11:49,200
+هتلاحظوه مش بسمع الميّه هتلاحظوه حتى مع ال HPR على
+
+132
+00:11:49,200 --> 00:11:52,920
+سبيل المثال يعني لو أخذنا نفس ال ال keen اللي كان
+
+133
+00:11:52,920 --> 00:11:56,820
+عندنا هان عارفينه ال C double bond C
+
+134
+00:11:59,940 --> 00:12:08,040
+CH3 و CH3 و قلنا بدنا نكمله باتجاهين مع الـHBr و
+
+135
+00:12:08,040 --> 00:12:13,520
+هنا كمان كتبنا HBr لو قلنا بدنا نكمل التفاعل مع
+
+136
+00:12:13,520 --> 00:12:20,460
+HBr في وجود H Plus سيضيف حسب قاعدة Markov Nikov و
+
+137
+00:12:20,460 --> 00:12:24,520
+لو قلنا بدنا نكمل التفاعل مع الـHBr في وجود
+
+138
+00:12:24,520 --> 00:12:30,160
+بيروكسايد سيضيف عكس قاعدة Markov Nikov الناتج
+
+139
+00:12:30,160 --> 00:12:33,340
+ببساطة نفس اللي موجود عندكم بدل كلمة OH اللي
+
+140
+00:12:33,340 --> 00:12:34,660
+بالأحمر شو بتحطه
+
+141
+00:12:41,060 --> 00:12:46,580
+إذا إضافة الماء أو إضافة الـ HPR يمكن أن تتم
+
+142
+00:12:46,580 --> 00:12:51,360
+بطريقة ولا بطريقتين وهنا بيصير مهم عندي جدا أن
+
+143
+00:12:51,360 --> 00:12:55,460
+أنتبه لل reactant للمتفاعل يعني لو احنا مرات بدنا
+
+144
+00:12:55,460 --> 00:12:59,840
+نسألكوا عن هذا الموضوع ممكن نجيبلكوا ال reactant
+
+145
+00:12:59,840 --> 00:13:03,100
+مع هذا نقولكوا اكتبوا النتيجة ممكن نجيب هذا ال
+
+146
+00:13:03,100 --> 00:13:06,300
+reactant و ال product و نقولكوا شو اللي استعملته
+
+147
+00:13:06,300 --> 00:13:11,620
+كمتفاعل كتبولي ال reactant اللي على السهل واضحك
+
+148
+00:13:11,620 --> 00:13:16,680
+الصورة؟ طبعا لو إجينا سألنا هذه النواتج ال
+
+149
+00:13:16,680 --> 00:13:20,100
+markovnikov product هذا بيسموه markovnikov product
+
+150
+00:13:20,100 --> 00:13:26,020
+و ال antimarkovnikov product ما العلاقة بينهما؟
+
+151
+00:13:26,020 --> 00:13:30,000
+isomers
+
+152
+00:13:30,000 --> 00:13:32,540
+أي نوع من ال isomers هذا اللي بقصدي
+
+153
+00:13:36,070 --> 00:13:40,470
+الـ Markovnikov's product والـ Antimarkovnikov's
+
+154
+00:13:40,470 --> 00:13:45,250
+product They are isomers ليش؟ لأنه نفس الذرات
+
+155
+00:13:45,250 --> 00:13:50,610
+وحطيت H و OH حطيت ال H و OH بنفس المواقع ولا
+
+156
+00:13:50,610 --> 00:13:57,670
+بمواقع مختلفة طالما مواقع مختلفة Different bonding
+
+157
+00:13:57,670 --> 00:14:04,290
+عطول الجواب Structural isomers They are structural
+
+158
+00:14:04,290 --> 00:14:09,910
+isomers مش فيها نقاش مش ارتبطوا الذرات من مواقع
+
+159
+00:14:09,910 --> 00:14:13,210
+مختلفة هنا الهيدروجين على الأولى و ال OH على
+
+160
+00:14:13,210 --> 00:14:17,470
+التانية هنا ال OH على الأولى و ال H على التانية صح
+
+161
+00:14:17,470 --> 00:14:20,570
+ولا لأ different bonding different names
+
+162
+00:14:20,570 --> 00:14:27,490
+structural isomers واضح إذا فكرة إضافة ال
+
+163
+00:14:27,490 --> 00:14:33,850
+unsymmetrical agents ممكن تضيف بطريقتين ماركوف نيكوف
+
+164
+00:14:33,850 --> 00:14:37,450
+وانتي ماركوف نيكوف حسب ظروف التفاعل شو الأمثلة
+
+165
+00:14:37,450 --> 00:14:43,840
+المطلوب من ان اعرفها الماءو ال HVR بدون تفاصيل
+
+166
+00:14:43,840 --> 00:14:47,600
+الميكانيزم اللي أحيانا ممكن تلاقوها موجودة عندكم
+
+167
+00:14:47,600 --> 00:14:50,920
+يعني أنا في النهاية ال course general organic
+
+168
+00:14:50,920 --> 00:14:56,340
+course بهمني تصلوا فيه للنتيجة بشكل عام ولذلك على
+
+169
+00:14:56,340 --> 00:14:59,960
+طول الآن ممكن ناخد أمثلة إضافية و تشوفوا كيف
+
+170
+00:14:59,960 --> 00:15:04,520
+الأمثلة الإضافية بنكملها بدون ما ندخل بتفاصيل كيف
+
+171
+00:15:04,520 --> 00:15:08,260
+تمت العملية المهم عنده النتج
+
+172
+00:15:19,100 --> 00:15:22,820
+الشرط اللي بتتم فيه الإضافة عكس قاعدة Markovnikov
+
+173
+00:15:22,820 --> 00:15:27,160
+موجود في هذا ال slide لاحظوا لأنه بضيف مركب اسمه
+
+174
+00:15:27,160 --> 00:15:32,960
+BH3 ال بي بورون مش بروم انتبه بورون ال بورون لما
+
+175
+00:15:32,960 --> 00:15:36,760
+تيجي على الجدول الدوري في أوله اللي هو العنصر
+
+176
+00:15:36,760 --> 00:15:43,920
+الخامس هيدروجين هيليوم ليثيوم بيريليوم بورون Boron
+
+177
+00:15:43,920 --> 00:15:50,200
+الأنصار الخامس تمام لما يكون BH3 بنسم
+
+223
+00:19:27,380 --> 00:19:33,680
+بعد أنا بحكي عن الاتصال المباشر مش موراء ما بعد
+
+224
+00:19:33,680 --> 00:19:38,460
+بعد حيفا شو مالي و ماله هذا اه هنا هيدروجين تان
+
+225
+00:19:38,460 --> 00:19:42,400
+مباشر هنا هيدروجين و كربون مين عليها هيدروجين أكثر
+
+226
+00:19:42,400 --> 00:19:48,780
+هذه بناء على ذلك لما أنا بقول بدي اضيف HPR في وجود 
+
+227
+00:19:48,780 --> 00:19:53,320
+H Plus وين اجت الهيدروجين؟ بهذا الشكل وين اجت ال
+
+228
+00:19:53,320 --> 00:20:02,760
+PR؟ بهذا الشكل واضح؟ هي اللي بديها دلوقت بتجي 
+
+229
+00:20:02,760 --> 00:20:09,060
+بالجهتين، من فوق و من تحت، قليلا بس شوية هذه 
+
+230
+00:20:09,060 --> 00:20:14,000
+الفكرة متطورة أكثر من ان ابيع فيها بقى بتيجي من 
+
+231
+00:20:14,000 --> 00:20:17,260
+فوق و من تحت يعني، بس مش موضوعنا لإنه علاقة 
+
+232
+00:20:17,260 --> 00:20:22,410
+بالستيريو كيمسترا، الآن هاي مركب تانية عندكم 
+
+233
+00:20:22,410 --> 00:20:27,170
+double bond وين الطرفين ال double bond؟ هدا و هدا، 
+
+234
+00:20:27,170 --> 00:20:33,570
+الآن هنا في شيء مش مرسوم ولا لأ؟ أكيد ال H الأكيد
+
+235
+00:20:33,570 --> 00:20:35,150
+ال H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال
+
+236
+00:20:35,150 --> 00:20:35,390
+H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+237
+00:20:35,390 --> 00:20:35,870
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H 
+
+238
+00:20:35,870 --> 00:20:35,890
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H 
+
+239
+00:20:35,890 --> 00:20:36,110
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+240
+00:20:36,110 --> 00:20:36,610
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+241
+00:20:36,610 --> 00:20:39,010
+الأكيد ال H ال أكيد ال H ال أكيد ال H ال أكيد ال H 
+
+242
+00:20:39,010 --> 00:20:44,980
+ال أكيد ال H ال أكيد ال H الإذا لو أنا كنت بدي 
+
+243
+00:20:44,980 --> 00:20:51,000
+أكمل HPR في وجود H Plus كيف سأكتب الناتج؟ يعني لو
+
+244
+00:20:51,000 --> 00:20:57,060
+أنه أكمل المعادلة HPR H Plus بدى أحط الهيدروجين ع 
+
+245
+00:20:57,060 --> 00:21:02,360
+اللي حاملة هيدروجين أكثر يعني بدى أحطها ناسيه H3
+
+246
+00:21:02,360 --> 00:21:12,340
+وH هدول اللي كانوا أصلا وجدت بدى أحط ال H تحتو ال 
+
+247
+00:21:12,340 --> 00:21:18,800
+PR على هذا الكربون هذه إضافة ماركوفنيكوف الان لما 
+
+248
+00:21:18,800 --> 00:21:24,560
+نيجي نعطيكم كملوا المعادلة HPR في وجود البروكسايد 
+
+249
+00:21:24,560 --> 00:21:29,300
+بدي أحط بالعكس بدي أحط بالعكس ولذلك لو بتيجي 
+
+250
+00:21:29,300 --> 00:21:33,080
+تتطلعوا هنا وين ال PR موجودة على أي كربون 
+
+251
+00:21:35,850 --> 00:21:39,270
+هيها طبعا هو ورا السماء مرة لتحت و مرة لفوق هذا
+
+252
+00:21:39,270 --> 00:21:43,710
+السؤال الذكي اللي سألته زملتكوا بس بدناش نطول فيه
+
+253
+00:21:43,710 --> 00:21:46,830
+بيجعل
+
+254
+00:21:46,830 --> 00:21:51,550
+جهتين مش فيها مشكلة بس في كل الأحوال على أي carbon 
+
+255
+00:21:51,550 --> 00:21:56,560
+إجت ال PR على حملة الهيدروجين على أي كاربون إجت 
+
+256
+00:21:56,560 --> 00:22:00,840
+الهيدروجين على اللي أقل هذي Markov Nikov ولا أنت 
+
+257
+00:22:00,840 --> 00:22:05,680
+Markov Nikov؟ أنا ما بديش ياكلتوه في الشكل فوق و
+
+258
+00:22:05,680 --> 00:22:11,140
+تحت، حطوهم بس بالموقع الصح و غلط و مكفي، واضح؟
+
+259
+00:22:11,140 --> 00:22:15,140
+يعني لما بنكمل هذه المعادلة، ببساطة إيش يكون
+
+260
+00:22:15,140 --> 00:22:24,560
+الجواب؟ هنا ال H وهنا ال PR هك النتج بدون يصفر أكثر 
+
+261
+00:22:24,560 --> 00:22:29,580
+من هيك تفصيل مابلزمنيش هذه مع ولا عكس Markovnikov
+
+262
+00:22:29,580 --> 00:22:33,700
+لما يكون هيك جوابه لغير ال double bond عكس 
+
+263
+00:22:33,700 --> 00:22:38,500
+Markovnikov هنا ال H هنا ال PR مع Markovnikov
+
+264
+00:22:38,500 --> 00:22:39,200
+فاهمنا؟
+
+265
+00:22:50,600 --> 00:22:58,020
+بيجينا بعد هذه الإضافة إضافة جديدة هذه الإضافة 
+
+266
+00:22:58,020 --> 00:22:59,980
+الجديدة
+
+267
+00:23:01,170 --> 00:23:07,110
+ان برضه احنا بنلغي فيها ال double bond و بنعمل two
+
+268
+00:23:07,110 --> 00:23:11,010
+new sigma bonds لكن هدول ال two new sigma bonds
+
+269
+00:23:11,010 --> 00:23:15,450
+بيكونوا على نفس ذرة ال oxygen ولذلك بيعطوني حلقة 
+
+270
+00:23:15,450 --> 00:23:19,250
+ثلاثية لاحظوا هذا الكلام كيف هي عندكم carbon
+
+271
+00:23:19,250 --> 00:23:24,450
+carbon double bond صح ولا لأ الان لو فعلناها مع
+
+272
+00:23:24,450 --> 00:23:31,330
+bare acid Bear بادئة معناها فوق يعني فيه ازيادة 
+
+273
+00:23:31,330 --> 00:23:40,170
+الحامض العضوي كام أكسوجين فيه عادة ال acid؟ تنتين 
+
+274
+00:23:40,170 --> 00:23:44,570
+تلت روابط مع الأكسوجين يعني ال acid شكله العام 
+
+275
+00:23:44,570 --> 00:23:55,300
+بهذا الشكل R C double bond O OH مشاكل الحامض؟ RCOH 
+
+276
+00:23:55,300 --> 00:23:59,640
+لو كانت هذه CH3 بيكون الاسيتك أسد لو كانت فنل
+
+277
+00:23:59,640 --> 00:24:05,260
+بيكون ال بنزويك أسد الان لو اجينا جنب ال COH 
+
+278
+00:24:05,260 --> 00:24:12,400
+هتضيفنا كمان O يعني خلينا COOH زي هذا المركب اللي
+
+279
+00:24:12,400 --> 00:24:17,700
+هنا RCOOH
+
+280
+00:24:17,700 --> 00:24:24,640
+هذا زاد عندى بإيش؟ بأكسوجينة صار فيه تلت أكسوجينات
+
+281
+00:24:24,640 --> 00:24:28,640
+هذا كام أكسوجينة في تنتين الآن هذا المركب اللي
+
+282
+00:24:28,640 --> 00:24:34,920
+صيرته العامة R C double bond O O O H بنسميه pear
+
+283
+00:24:34,920 --> 00:24:41,230
+acid فوق حامضيعني زاد فيه ال oxygen بمقدار ضرر 
+
+284
+00:24:41,230 --> 00:24:46,310
+يعرفنا إيش معنى pear acid و لما نسميه بنسميه على 
+
+285
+00:24:46,310 --> 00:24:49,570
+اسم الحامض الأصلي اللي كان موجود يعني لو افترضنا
+
+286
+00:24:49,570 --> 00:24:54,810
+الحامض الأصلي acidic acid بصير اللي فيه أكسجينة
+
+287
+00:24:54,810 --> 00:25:01,350
+زيادة بير أسيتك أسد، بنزويك أسد، بير بنزويك أسد،
+
+288
+00:25:01,350 --> 00:25:06,930
+يعني نفس الحامض تماما بس بنزيد عليه إيش؟ بير، يمكن
+
+289
+00:25:06,930 --> 00:25:12,590
+مرت عليكم لما أخدتوا أحماض الكلور مع الأكسجين لما
+
+290
+00:25:12,590 --> 00:25:18,510
+أخدتوا ال بيريكلوريك أسد مش كان عندكوا ClO3 لكلوريك
+
+291
+00:25:18,510 --> 00:25:25,530
+أسد لما صار ClO4 زاد أكسوجينة بيريكلوريك أسد واضح
+
+292
+00:25:25,530 --> 00:25:31,230
+فبير هنا بمعنى إيش الزيادة لو فعلنا الالكين مع
+
+293
+00:25:31,230 --> 00:25:36,480
+البر أسد مرة تانية بتنكسر ال double bond و بتعمل
+
+294
+00:25:36,480 --> 00:25:40,900
+رابطتين sigma لكن مع نفس ذرة ال oxygen اذا هذه
+
+295
+00:25:40,900 --> 00:25:48,220
+العملية أيضا عملية ايش اضافة تحويل ال pi bond الى
+
+296
+00:25:48,220 --> 00:25:54,080
+two new sigma bonds اضافة ولا مش اضافة اضافة لكن
+
+297
+00:25:54,080 --> 00:25:56,880
+الان ال two new sigma bonds على نفس ال oxygen
+
+298
+00:25:56,880 --> 00:26:04,040
+فالناتج حلقة ثلاثية الناتج حلقة ثلاثية هذه الحلقة 
+
+299
+00:26:04,040 --> 00:26:10,460
+الثلاثية من ذرتين كربون و من أكسوجينة حلقة ثلاثية 
+
+300
+00:26:10,460 --> 00:26:14,560
+ذرتين كربون و أكسوجينة هذه الثلاث ذرات تعونها الآن
+
+301
+00:26:14,560 --> 00:26:21,140
+هذه الحلقة الثلاثية كعائلة بيسموها ابوكسايد يعني
+
+302
+00:26:21,140 --> 00:26:25,380
+لو قلتلكم ما هي عائلة الابوكسايد لاحظوا family في
+
+303
+00:26:25,380 --> 00:26:29,660
+عندنا family و في عندنا في جوا ال family إيش أفراد
+
+304
+00:26:30,500 --> 00:26:33,720
+هك بتكون تفهموا الكيميا ان في العائلة العامة زي ال 
+
+305
+00:26:33,720 --> 00:26:40,800
+ketones ال ketone family عائلة الآن جواتها acetone 
+
+306
+00:26:40,800 --> 00:26:46,740
+وcyclohexanone وكذا وكذا ال alkenes عائلة جواتها
+
+307
+00:26:46,740 --> 00:26:53,910
+methane إيثين بروبين الآن ال epoxides عائلة أيضا مش
+
+308
+00:26:53,910 --> 00:26:59,130
+اسم مركب الابوكسايد عائلة الان طب ايش في جوات هذه
+
+309
+00:26:59,130 --> 00:27:05,730
+العائلة مركّبات؟ carbon تانو اكسوجينة وين بدو يصير
+
+310
+00:27:05,730 --> 00:27:10,630
+الخلاف؟ بدو يصير الخلاف في هدول المجموعات هل هدول
+
+311
+00:27:10,630 --> 00:27:14,130
+الأربعة هيدروجينز؟ هل واحدة فيهم مثل؟ هل تنتين 
+
+312
+00:27:14,130 --> 00:27:16,910
+مثل؟ هل التلاتة مثل؟ هل الأربعة مثل؟ هل واحدة إثل؟
+
+313
+00:27:16,910 --> 00:27:23,540
+هل واحدة بروبل؟ وجدتها بيصير لكل مركب اسم طب كيف 
+
+314
+00:27:23,540 --> 00:27:28,760
+بنسمي كل مركب؟ العملية سهلة بنيجي بنسأل نفسنا إيش 
+
+315
+00:27:28,760 --> 00:27:36,160
+اسم الألكين الأصلي تبعه اللي كونه؟ والناتج لما 
+
+316
+00:27:36,160 --> 00:27:39,900
+نعمله بنسميه باسم الالكين بنضيف عليه oxide يعني
+
+317
+00:27:39,900 --> 00:27:46,200
+مثلا لو كان الالكين اللي عندكم CH2 double bond CH2
+
+318
+00:27:46,200 --> 00:27:53,580
+هين حددنا مركب محدد هذا إيش اسمه اثيلين او اثيل
+
+319
+00:27:53,580 --> 00:27:59,300
+اثيلين الآن فعلنا مع ال bare acid هذا اللي موجود 
+
+320
+00:27:59,300 --> 00:28:05,840
+عندناه تلتغي هذه الـ bi-bond وتعطيني أكسوجينة صار 
+
+321
+00:28:05,840 --> 00:28:11,480
+عندى CH2 خلّيني نخلي الهيدروجين يخلع برا مرسومين
+
+322
+00:28:11,480 --> 00:28:14,620
+CH2
+
+323
+00:28:14,620 --> 00:28:23,280
+CH2 و هنا أكسوجين الآن هذا من أي مركب نتاج من
+
+324
+00:28:23,280 --> 00:28:30,910
+الإثالين شو بدي أسميه إثالين أكسيد نسبة للأصل إذا
+
+325
+00:28:30,910 --> 00:28:35,970
+تسمية هذه المراكبات تسمية هذه المراكبات كل فرد
+
+326
+00:28:35,970 --> 00:28:42,350
+منها كيف بسميه باسم القلقين الأصلي مضاف إليه كلمة
+
+327
+00:28:42,350 --> 00:28:49,350
+أكسايد أثالين أكسايد واضحة الفكرة ولا لأ ماشي 
+
+328
+00:28:49,350 --> 00:28:53,410
+أتأكد أنها واضحة ولا لأ الآن لو اني جيبت هذا 
+
+329
+00:28:53,410 --> 00:28:58,310
+المركب في الامتحان وقلتلك لو سمحته سمولي هذا 
+
+330
+00:28:58,310 --> 00:29:04,760
+المركب زي هيك هذا جايكوا في الامتحان و أنا قلتلكوا
+
+331
+00:29:04,760 --> 00:29:11,860
+صموه واحدة
+
+332
+00:29:11,860 --> 00:29:15,960
+بس Cyclohexane
+
+333
+00:29:15,960 --> 00:29:22,210
+Oxide بتكون تقولوا هذا إيش كان أصلاهي اللي شيلت
+
+334
+00:29:22,210 --> 00:29:26,990
+هذه .. هذا أصلا كان هيك لما ضيفت عليه شيلت ال
+
+335
+00:29:26,990 --> 00:29:30,910
+double bond و حطيت ال oxygen طب زي هيك إيش اسمه؟
+
+336
+00:29:30,910 --> 00:29:41,120
+Cyclohexane شيلنا هذه صار Cyclohexane oxide واضح؟
+
+337
+00:29:41,120 --> 00:29:48,940
+إذا هذه المركبات كأفراد تسمى باسم القلقين الأصلي
+
+338
+00:29:48,940 --> 00:29:55,160
+باسم القلقين الأصلي مضاف إلى كلمة Oxide واضحة ولا
+
+339
+00:29:55,160 --> 00:30:04,340
+ما واضحت؟ واضحة تماما، الآن إلها تسمية تانية كتير 
+
+340
+00:30:04,340 --> 00:30:10,260
+في ناس بياخدوا أكثر من اسم، إلها تسمية تانية أبسط
+
+341
+00:30:10,260 --> 00:30:15,340
+مُركّب في هذه العائلة كلها أي واحد الـ ethylene
+
+342
+00:30:15,340 --> 00:30:22,620
+oxide ليش؟ لأنه هنا O CH H H H H هذا المُركّب
+
+343
+00:30:22,620 --> 00:30:27,980
+الأبسط فيهم هذا المُركّب الأبسط ماخد اسم اسمه
+
+344
+00:30:27,980 --> 00:30:37,990
+Oxirane Oxirane تمام؟ Oxirane بنحفظه ايه كويس الان 
+
+345
+00:30:37,990 --> 00:30:43,270
+هذا ال Oxirane بنتخيله تلت مواقع بنبدأ ترقيمه من
+
+346
+00:30:43,270 --> 00:30:50,170
+ال Oxygen بنقول واحد اتنين تلاتة بنسميه ال parent
+
+347
+00:30:50,170 --> 00:30:55,410
+compound عمرنا قولنا كلمة parent المركب الأبسط
+
+348
+00:30:55,410 --> 00:30:59,310
+دائما بنقول عنه ال parent compound الآن هذا ال
+
+349
+00:30:59,310 --> 00:31:02,610
+parent compound لو يا ترى شيلنا من هدول ال 
+
+350
+00:31:02,610 --> 00:31:10,870
+hydrogen ال hydrogen واحدة وحطينا بدلها CH3 واحدة
+
+351
+00:31:10,870 --> 00:31:12,610
+تقولي ايش بدها تسمي وجتها
+
+352
+00:31:15,250 --> 00:31:20,130
+أوكز إيرين المركب الأصلي على موقع اتنين إيش إجاله
+
+353
+00:31:20,130 --> 00:31:30,210
+مثل إذا هذا بيصير two مثل أوكز إيرين أنا اعتبرت ال 
+
+354
+00:31:30,210 --> 00:31:34,990
+أوكز إيرين اللي فيه أربعة هيدروجين شلت منه واحدة
+
+355
+00:31:34,990 --> 00:31:39,630
+محل ما شلت بكتب اسم المجموعة لو كان كلور two chlor
+
+356
+00:31:39,630 --> 00:31:44,780
+أوكز إيرين لو كانت إثلتوقث ال Oxirane تعرفنا كيف 
+
+357
+00:31:44,780 --> 00:31:49,800
+هذا سمنها؟ الآن هي تسمية هذا المركب اللي أمامكم 
+
+358
+00:31:49,800 --> 00:31:54,360
+بطريقة ال Oxirane طب لو واحدة بدأت تسميه بطريقة ال
+
+359
+00:31:54,360 --> 00:32:02,200
+Alkyl Oxide، شو هتسميه؟ بروبين أكسيد، بروبين 
+
+360
+00:32:02,200 --> 00:32:04,780
+أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد،
+
+361
+00:32:04,780 --> 00:32:05,560
+بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين
+
+362
+00:32:05,560 --> 00:32:06,080
+أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد،
+
+363
+00:32:06,080 --> 00:32:08,440
+بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين
+
+364
+00:32:08,440 --> 00:32:16,320
+أكسيد، بروبين أكسما هذا الالكين؟ واحد CH2 double
+
+365
+00:32:16,320 --> 00:32:22,300
+bond CH CH3 هذا الابروبيل و لذلك بيصير ابروبيل 
+
+366
+00:32:22,300 --> 00:32:27,900
+أكسيد فلو جيبنالكم مثلا سؤال ابروبيل أكسيد is also 
+
+367
+00:32:27,900 --> 00:32:32,780
+called وقتها بتقولوا 2-methyl oxirane 2-methyl 
+
+368
+00:32:32,780 --> 00:32:38,900
+oxirane is also calledPropyl Oxide طبعا ال Oxirans
+
+369
+00:32:38,900 --> 00:32:42,760
+هذه في الكيميا الحلقية غير المتجانسة بنستعملها
+
+370
+00:32:42,760 --> 00:32:46,480
+أكثر في الكيميا العادية المشهورة أكتر يكون تسموها 
+
+371
+00:32:46,480 --> 00:32:54,720
+نسبة للالكيم و تحطو إيش Oxide الإسمين بتلاقوهم إذا
+
+372
+00:32:54,720 --> 00:33:01,620
+شفنا هذه المراكبات كيف بنحضرها و كيف بنسميها كيف
+
+373
+00:33:01,620 --> 00:33:05,560
+بنحضرها و كيف بنسميها عساريا مينندسيا هل هذه 
+
+374
+00:33:05,560 --> 00:33:08,800
+التسمية بتسميها ايوباك ولا ايوباك؟ لأ لأ هي 
+
+375
+00:33:08,800 --> 00:33:14,240
+التسمية اللي هي ال auxirene نظام تسمي بسموه Hans 
+
+376
+00:33:14,240 --> 00:33:18,550
+Wiedemann system of nomenclature يستعمل عن طلاب
+
+377
+00:33:18,550 --> 00:33:23,570
+الكيميا للـ heterocyclic compounds واضح؟ hence
+
+378
+00:33:23,570 --> 00:33:26,570
+Vedman system of nomenclature الآن خلينا ناخد 
+
+379
+00:33:26,570 --> 00:33:32,050
+أمثلة انسهل الموضوع هي كذا مثال جيبنا أكمل مع pear 
+
+380
+00:33:32,050 --> 00:33:36,950
+acid شو عرفني pear acid؟ تلت أكسوجينات في كل
+
+381
+00:33:36,950 --> 00:33:42,370
+الأحوال شو اللي بدى أعمله؟ أشيل ال double bond؟ أحط 
+
+382
+00:33:42,370 --> 00:33:48,510
+مكانها أكسجين أشيل ال double bond أحط أكسجين أشيل 
+
+383
+00:33:48,510 --> 00:33:52,630
+ال double bond أحط أكسجين إذا الأمر سهل و بسيط ولا
+
+384
+00:33:52,630 --> 00:33:57,110
+لأ الالكيل مع ال bear acid أشيل ال double bond أحط
+
+385
+00:33:57,110 --> 00:34:02,350
+أكسجين في حلقة ثلاثية كل هذه لو إجا شخص من برة و
+
+386
+00:34:02,350 --> 00:34:07,070
+يتطلع على السبورة ويقول له شو هذه المركبات؟ شو بدي
+
+387
+00:34:07,070 --> 00:34:14,200
+يجاوبنا؟ Epoxides مش العائلة ابوكسايدز فلو يوم من
+
+388
+00:34:14,200 --> 00:34:19,140
+الأيام جريتوا مثلا عائلة الابوكسايدز افبالكم بلغة
+
+389
+00:34:19,140 --> 00:34:24,740
+بسيطة الحلقات الثلاثية التي تحتوي على ذرة أكسجين 
+
+390
+00:34:24,740 --> 00:34:32,280
+واحدة هي عائلة الابوكسايدز واضحة؟ الآن بنلاحظ شغلة
+
+391
+00:34:32,2
+
+445
+00:39:09,790 --> 00:39:16,470
+Electrophile شيء موجب يحب السالب لأنّ نيوكليوفايل شئ
+
+446
+00:39:16,470 --> 00:39:20,350
+سالب يحب الموجب هذول شغلتين بتفاعلوا مع بعض يعني
+
+447
+00:39:20,350 --> 00:39:24,090
+كأنّه ببساطة ممكن واحد اللي مش كثير حابّه
+
+448
+00:39:24,090 --> 00:39:28,050
+هالمصطلحين لأول واحد بتقول يعني موجب وسالب أه
+
+449
+00:39:28,050 --> 00:39:32,110
+ببساطة يعني موجب وسالب لكنّ احنا من اليوم وطالع في
+
+450
+00:39:32,110 --> 00:39:34,750
+الـ organic chemistry الموجب ايش هنسمّيه؟
+
+451
+00:39:35,390 --> 00:39:40,390
+Electrophile والسالب ايش هنسمّيه النيوكليوفايل الآن
+
+452
+00:39:40,390 --> 00:39:47,510
+هنقول أنّ النيوكليوفايل بيهاجم على الـ Electrophile
+
+453
+00:39:47,510 --> 00:39:52,390
+بيعمل رابطة ممكن النيوكليوفايل يكون OH جاية من 
+
+454
+00:39:52,390 --> 00:39:56,030
+المياه أو تيجي من المياه فلما ييجي هذا الـ OH
+
+455
+00:39:56,030 --> 00:40:00,470
+هنهيهاجم معقول يصيروا خمس روابط ولا هتكسر هذه 
+
+456
+00:40:00,470 --> 00:40:10,140
+الرابطة تكسر وتفتح هتتحول الـ O هذه إلى OH الآن بهذه
+
+457
+00:40:10,140 --> 00:40:13,220
+المنطقة راجعوا المرة اللي جايب الـ roadmap نبدأ من عند 
+
+458
+00:40:13,220 --> 00:40:16,400
+هذه النقطة لكنّ بتكونوا اتدربتوا أكتر و بنشرح كل
+
+459
+00:40:16,400 --> 00:40:20,940
+الأمثلة ايش معنى Electrophile ايش معنى Nucleophile
+
+460
+00:40:20,940 --> 00:40:24,680
+هات بتتدربوا عليها بنشوف كيف الـ ring opening بيصير
+
+461
+00:40:24,680 --> 00:40:26,600
+باكثر من مثل 
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..ab5049a9c1ee46e3f328ab2e7517035a38f7572b
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 5005, "start": 20.99, "end": 50.05, "text": "بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في تفاعلات ال alkenes وقلنا اللى بينظر للموضوع نظرة كلية الموضوع بسيط الموضوع انه double bond هيوم رابطتين بالاضافة بتصير single bond هذه العملية شو بنسميها عملية addition عملية addition واتفقنا ان في ال addition فى عندنا مكونات لل addition فى عندنا ال alkene", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 1975, 2655, 4117, 19528, 8315, 8978, 6055, 5172, 995, 30241, 9307, 2423, 419, 2653, 279, 4032, 4587, 1211, 8315, 13672, 7578, 4724, 9957, 19913, 2288, 5296, 19528, 2407, 11242, 45367, 8717, 19913, 25720, 28242, 10632, 9673, 2407, 11242, 45367, 4724, 3794, 1829, 9566, 9673, 2407, 11242, 45367, 16472, 3224, 3834, 6086, 8032, 1829, 20498, 12602, 16758, 9566, 2655, 9957, 20666, 46958, 31845, 3660, 39894, 9381, 13546, 2167, 6086, 29538, 18863, 42213, 10632, 13412, 2407, 44945, 38251, 1829, 11296, 6225, 42213, 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ولا بطريقتين وهنا بيصير مهم عندي جدا أن أنتبه لل reactant للمتفاعل يعني لو احنا مرات بدنا نسألكوا عن هذا الموضوع ممكن نجيبلكوا ال reactant مع هذا نقولكوا اكتبوا النتيجة ممكن نجيب هذا ال reactant و ال product و نقولكوا شو اللي استعملته كمتفاعل كتبولي ال reactant اللي على السهل", "tokens": [28814, 15730, 11933, 11242, 31845, 3660, 9673, 16606, 34051, 11933, 11242, 31845, 3660, 2423, 39184, 12557, 49, 7251, 43020, 14739, 6055, 39237, 4724, 9566, 16572, 28671, 49429, 4724, 9566, 16572, 38149, 9957, 37037, 8315, 4724, 1829, 9381, 13546, 3714, 16095, 18871, 16254, 10874, 28259, 14739, 5551, 29399, 3555, 3224, 24976, 4515, 394, 5296, 19528, 2655, 5172, 995, 30241, 37495, 22653, 45164, 1975, 5016, 8315, 3714, 2288, 9307, 47525, 8315, 8717, 3794, 10721, 23275, 14407, 18871, 23758, 9673, 2407, 11242, 45367, 3714, 43020, 8717, 7435, 1829, 3555, 23275, 14407, 2423, 4515, 394, 20449, 23758, 8717, 39648, 4117, 14407, 1975, 4117, 2655, 3555, 14407, 28239, 31371, 7435, 3660, 3714, 43020, 8717, 7435, 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"probability": 0.9606119791666666}, {"start": 802.92, "end": 806.02, "word": " بينهما؟", "probability": 0.78436279296875}, {"start": 806.02, "end": 810.0, "word": " isomers", "probability": 0.738525390625}, {"start": 810.0, "end": 810.32, "word": " أي", "probability": 0.53466796875}, {"start": 810.32, "end": 810.68, "word": " نوع", "probability": 0.996826171875}, {"start": 810.68, "end": 810.9, "word": " من", "probability": 0.99609375}, {"start": 810.9, "end": 811.06, "word": " ال", "probability": 0.95654296875}, {"start": 811.06, "end": 811.7, "word": " isomers", "probability": 0.958984375}, {"start": 811.7, "end": 811.92, "word": " هذا", "probability": 0.7802734375}, {"start": 811.92, "end": 812.06, "word": " اللي", "probability": 0.97705078125}, {"start": 812.06, "end": 812.54, "word": " بقصدي", "probability": 0.86279296875}], "temperature": 1.0}, {"id": 34, "seek": 84521, "start": 816.07, "end": 845.21, "text": "الـ Markovnikov's product والـ Antimarkovnikov's product They are isomers ليش؟ لأنه نفس الذرات وحطيت H و OH حطيت ال H و OH بنفس المواقع ولا بمواقع مختلفة طالما مواقع مختلفة Different bonding عطول الجواب Structural isomers They are structural isomers", "tokens": [6027, 39184, 3934, 5179, 13123, 5179, 311, 1674, 16070, 39184, 5130, 332, 809, 5179, 13123, 5179, 311, 1674, 814, 366, 307, 298, 433, 32239, 8592, 22807, 5296, 33456, 3224, 8717, 36178, 32545, 2288, 9307, 4032, 5016, 9566, 36081, 389, 4032, 13931, 11331, 9566, 36081, 2423, 389, 4032, 13931, 4724, 1863, 36178, 9673, 14407, 4587, 3615, 49429, 4724, 2304, 14407, 4587, 3615, 3714, 46456, 46538, 3660, 23032, 6027, 15042, 3714, 14407, 4587, 3615, 3714, 46456, 46538, 3660, 20825, 28824, 6225, 9566, 12610, 25724, 14407, 3555, 745, 1757, 1807, 307, 298, 433, 814, 366, 15067, 307, 298, 433], "avg_logprob": -0.2139175208573489, "compression_ratio": 1.6650246305418719, "no_speech_prob": 0.0, "words": [{"start": 816.07, "end": 816.47, "word": "الـ", "probability": 0.435791015625}, {"start": 816.47, "end": 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825.25, "end": 826.05, "word": " وحطيت", "probability": 0.886474609375}, {"start": 826.05, "end": 826.35, "word": " H", "probability": 0.826171875}, {"start": 826.35, "end": 826.55, "word": " و", "probability": 0.87939453125}, {"start": 826.55, "end": 826.91, "word": " OH", "probability": 0.421875}, {"start": 826.91, "end": 827.67, "word": " حطيت", "probability": 0.8572591145833334}, {"start": 827.67, "end": 827.83, "word": " ال", "probability": 0.9208984375}, {"start": 827.83, "end": 828.05, "word": " H", "probability": 0.6318359375}, {"start": 828.05, "end": 828.25, "word": " و", "probability": 0.9892578125}, {"start": 828.25, "end": 828.43, "word": " OH", "probability": 0.83349609375}, {"start": 828.43, "end": 829.61, "word": " بنفس", "probability": 0.770751953125}, {"start": 829.61, "end": 830.39, "word": " المواقع", "probability": 0.9937744140625}, {"start": 830.39, "end": 830.61, "word": " ولا", "probability": 0.7607421875}, {"start": 830.61, "end": 831.25, "word": " بمواقع", "probability": 0.9884765625}, {"start": 831.25, "end": 832.25, "word": " مختلفة", "probability": 0.992919921875}, {"start": 832.25, "end": 833.97, "word": " طالما", "probability": 0.9108072916666666}, {"start": 833.97, "end": 834.77, "word": " مواقع", "probability": 0.9820556640625}, {"start": 834.77, "end": 835.71, "word": " مختلفة", "probability": 0.991455078125}, {"start": 835.71, "end": 836.41, "word": " Different", "probability": 0.349365234375}, {"start": 836.41, "end": 837.67, "word": " bonding", "probability": 0.83349609375}, {"start": 837.67, "end": 838.25, "word": " عطول", "probability": 0.6844889322916666}, {"start": 838.25, "end": 839.17, "word": " الجواب", "probability": 0.9793294270833334}, {"start": 839.17, "end": 840.91, "word": " Structural", "probability": 0.91748046875}, {"start": 840.91, "end": 842.89, "word": " isomers", "probability": 0.9661458333333334}, {"start": 842.89, "end": 843.47, "word": " They", "probability": 0.7275390625}, {"start": 843.47, "end": 843.65, "word": " are", "probability": 0.9521484375}, {"start": 843.65, "end": 844.29, "word": " structural", "probability": 0.87158203125}, {"start": 844.29, "end": 845.21, "word": " isomers", "probability": 0.9884440104166666}], "temperature": 1.0}, {"id": 35, "seek": 87125, "start": 845.79, "end": 871.25, "text": "مش فيها نقاش مش ارتبطوا الذرات من مواقع مختلفة هنا الهيدروجين على الأولى و ال OH على التانية هنا ال OH على الأولى و ال H على التانية صح ولا لأ different bonding different names structural isomers واضح إذا فكرة إضافة ال unsymmetrical agents ممكن تضيف", "tokens": [2304, 8592, 8978, 11296, 8717, 4587, 33599, 37893, 1975, 43500, 3555, 9566, 14407, 32545, 2288, 9307, 9154, 3714, 14407, 4587, 3615, 3714, 46456, 46538, 3660, 34105, 2423, 3224, 25708, 2288, 29245, 9957, 15844, 16247, 12610, 7578, 4032, 2423, 13931, 15844, 16712, 7649, 10632, 34105, 2423, 13931, 15844, 16247, 12610, 7578, 4032, 2423, 389, 15844, 16712, 7649, 10632, 20328, 5016, 49429, 5296, 10721, 819, 28824, 819, 5288, 15067, 307, 298, 433, 4032, 46958, 5016, 11933, 15730, 6156, 4117, 25720, 11933, 11242, 31845, 3660, 2423, 2693, 32497, 32283, 12554, 3714, 43020, 6055, 11242, 33911], "avg_logprob": -0.1962365565761443, "compression_ratio": 1.6754385964912282, "no_speech_prob": 0.0, "words": [{"start": 845.79, "end": 846.03, "word": "مش", "probability": 0.33551025390625}, {"start": 846.03, "end": 846.29, "word": " فيها", "probability": 0.922607421875}, {"start": 846.29, "end": 846.83, "word": " نقاش", "probability": 0.9892578125}, {"start": 846.83, "end": 848.01, "word": " مش", "probability": 0.1820068359375}, {"start": 848.01, "end": 848.93, "word": " ارتبطوا", "probability": 0.95458984375}, {"start": 848.93, "end": 849.33, "word": " الذرات", "probability": 0.9415690104166666}, {"start": 849.33, "end": 849.49, "word": " من", "probability": 0.958984375}, {"start": 849.49, "end": 849.91, "word": " مواقع", "probability": 0.9892578125}, {"start": 849.91, "end": 850.63, "word": " مختلفة", "probability": 0.991943359375}, {"start": 850.63, "end": 851.03, "word": " هنا", "probability": 0.6162109375}, {"start": 851.03, "end": 851.79, "word": " الهيدروجين", "probability": 0.9080403645833334}, {"start": 851.79, "end": 851.97, "word": " على", "probability": 0.60986328125}, {"start": 851.97, "end": 852.33, "word": " الأولى", "probability": 0.9542643229166666}, {"start": 852.33, "end": 852.43, "word": " و", "probability": 0.5595703125}, {"start": 852.43, "end": 852.55, "word": " ال", "probability": 0.81982421875}, {"start": 852.55, "end": 852.73, "word": " OH", "probability": 0.2374267578125}, {"start": 852.73, "end": 853.21, "word": " على", "probability": 0.8466796875}, {"start": 853.21, "end": 853.83, "word": " التانية", "probability": 0.93408203125}, {"start": 853.83, "end": 854.33, "word": " هنا", "probability": 0.56689453125}, {"start": 854.33, "end": 854.51, "word": " ال", "probability": 0.98583984375}, {"start": 854.51, "end": 854.81, "word": " OH", "probability": 0.83837890625}, {"start": 854.81, "end": 855.03, "word": " على", "probability": 0.90869140625}, {"start": 855.03, "end": 855.35, "word": " الأولى", "probability": 0.9807942708333334}, {"start": 855.35, "end": 855.45, "word": " و", "probability": 0.9716796875}, {"start": 855.45, "end": 855.55, "word": " ال", "probability": 0.92333984375}, {"start": 855.55, "end": 855.75, "word": " H", "probability": 0.900390625}, {"start": 855.75, "end": 855.95, "word": " على", "probability": 0.92041015625}, {"start": 855.95, "end": 856.47, "word": " التانية", "probability": 0.9889322916666666}, {"start": 856.47, "end": 857.47, "word": " صح", "probability": 0.965576171875}, {"start": 857.47, "end": 857.65, "word": " ولا", "probability": 0.95947265625}, {"start": 857.65, "end": 857.97, "word": " لأ", "probability": 0.905517578125}, {"start": 857.97, "end": 858.73, "word": " different", "probability": 0.456787109375}, {"start": 858.73, "end": 859.37, "word": " bonding", "probability": 0.79443359375}, {"start": 859.37, "end": 859.85, "word": " different", "probability": 0.533203125}, {"start": 859.85, "end": 860.57, "word": " names", "probability": 0.888671875}, {"start": 860.57, "end": 862.11, "word": " structural", "probability": 0.452392578125}, {"start": 862.11, "end": 863.21, "word": " isomers", "probability": 0.96923828125}, {"start": 863.21, "end": 864.23, "word": " واضح", "probability": 0.9532877604166666}, {"start": 864.23, "end": 864.59, "word": " إذا", "probability": 0.5096435546875}, {"start": 864.59, "end": 865.57, "word": " فكرة", "probability": 0.982421875}, {"start": 865.57, "end": 866.79, "word": " إضافة", "probability": 0.9830322265625}, {"start": 866.79, "end": 867.49, "word": " ال", "probability": 0.94091796875}, {"start": 867.49, "end": 868.31, "word": " unsymmetrical", "probability": 0.6771647135416666}, {"start": 868.31, "end": 869.15, "word": " agents", "probability": 0.68603515625}, {"start": 869.15, "end": 870.67, "word": " ممكن", "probability": 0.9580078125}, {"start": 870.67, "end": 871.25, "word": " تضيف", "probability": 0.9064127604166666}], "temperature": 1.0}, {"id": 36, "seek": 88079, "start": 872.17, "end": 880.79, "text": "طريقتين ماركوف نيكوف وانتي ماركوف نيكوف حسب ظروف التفاعل شو الأمثلة المطلوب من ان اعرفها الماء", "tokens": [9566, 16572, 38149, 9957, 3714, 9640, 4117, 38688, 8717, 1829, 4117, 38688, 4032, 7649, 31371, 3714, 9640, 4117, 38688, 8717, 1829, 4117, 38688, 11331, 35457, 1357, 116, 32887, 5172, 16712, 5172, 995, 30241, 13412, 2407, 16247, 2304, 12984, 37977, 9673, 9566, 1211, 37746, 9154, 16472, 1975, 3615, 28480, 11296, 9673, 16606], "avg_logprob": -0.244290864524933, "compression_ratio": 1.5871559633027523, "no_speech_prob": 0.0, "words": [{"start": 872.17, "end": 872.99, "word": "طريقتين", "probability": 0.9415283203125}, {"start": 872.99, "end": 873.61, "word": " ماركوف", "probability": 0.712371826171875}, {"start": 873.61, "end": 873.85, "word": " نيكوف", "probability": 0.9244384765625}, {"start": 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هيدروجين أكتر يعني بدى أحطها ناسيه H3 وH هدولة اللي كانوا أصلا وجدت بدى أحط ال H تحت", "tokens": [28814, 15730, 45164, 41850, 9122, 29399, 47525, 7578, 5551, 24793, 1211, 389, 15958, 8978, 49610, 23328, 389, 7721, 9122, 33911, 8608, 10721, 4117, 2655, 3555, 2423, 8315, 2655, 7435, 22807, 37495, 22653, 45164, 14739, 3224, 5551, 24793, 1211, 9673, 3615, 18513, 37977, 389, 15958, 389, 7721, 47525, 7578, 5551, 5016, 9566, 2423, 3224, 25708, 2288, 29245, 9957, 6225, 13672, 1829, 11331, 10943, 37977, 8032, 25708, 2288, 29245, 9957, 5551, 4117, 2655, 2288, 37495, 22653, 47525, 7578, 5551, 5016, 9566, 11296, 8717, 32277, 1829, 3224, 389, 18, 4032, 39, 8032, 3215, 12610, 3660, 13672, 1829, 25961, 14407, 5551, 9381, 15040, 49610, 3215, 2655, 47525, 7578, 5551, 5016, 9566, 2423, 389, 6055, 33753], "avg_logprob": -0.28348215110599995, "compression_ratio": 1.815, "no_speech_prob": 0.0, "words": [{"start": 1242.86, "end": 1243.32, "word": "إذا", "probability": 0.5987548828125}, {"start": 1243.32, 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الجديدة", "tokens": [21292, 7435, 1829, 8315, 39182, 29538, 33688, 11242, 31845, 3660, 11933, 11242, 31845, 3660, 10874, 16254, 41891, 29538, 33688, 11242, 31845, 3660, 25724, 16254, 41891], "avg_logprob": -0.19501201235331023, "compression_ratio": 1.4705882352941178, "no_speech_prob": 0.0, "words": [{"start": 1370.6, "end": 1371.48, "word": "بيجينا", "probability": 0.7560577392578125}, {"start": 1371.48, "end": 1372.8, "word": " بعد", "probability": 0.857421875}, {"start": 1372.8, "end": 1373.16, "word": " هذه", "probability": 0.8193359375}, {"start": 1373.16, "end": 1373.92, "word": " الإضافة", "probability": 0.9510498046875}, {"start": 1373.92, "end": 1374.66, "word": " إضافة", "probability": 0.9124755859375}, {"start": 1374.66, "end": 1375.34, "word": " جديدة", "probability": 0.98779296875}, {"start": 1375.34, "end": 1377.0, "word": " هذه", "probability": 0.3662109375}, {"start": 1377.0, "end": 1378.02, "word": " الإضافة", "probability": 0.98779296875}, {"start": 1378.02, "end": 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@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4684, "start": 21.14, "end": 46.84, "text": "بسم الله الرحمن الرحيم المرة الماضية بدأنا في الفصل الثالث في الكيميا العضوية اللي هو بعنوان ال alkenes and alkynes طبعا بشكل أساسي اتعرفنا على خواص الروابط الأوحدية الثنائية الثلاثية واخدنا تسمية ال alkenes و ال alkynes وركزنا على فكرة", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 10721, 8315, 8978, 27188, 36520, 6024, 104, 6027, 12984, 8978, 33251, 32640, 25528, 18863, 11242, 2407, 10632, 13672, 1829, 31439, 45030, 1863, 2407, 7649, 2423, 419, 2653, 279, 293, 419, 4133, 4081, 23032, 3555, 3615, 995, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 1975, 2655, 3615, 28480, 8315, 15844, 16490, 14407, 9381, 34892, 14407, 3555, 9566, 16247, 2407, 24401, 10632, 6024, 104, 1863, 16373, 10632, 6024, 104, 1211, 5718, 104, 10632, 4032, 47283, 3215, 8315, 6055, 38251, 10632, 2423, 419, 2653, 279, 4032, 2423, 419, 4133, 4081, 4032, 31747, 11622, 8315, 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"end": 2852.92, "word": " of", "probability": 0.9765625}, {"start": 2852.92, "end": 2853.54, "word": " addition", "probability": 0.9609375}, {"start": 2853.54, "end": 2853.98, "word": " ال", "probability": 0.81298828125}, {"start": 2853.98, "end": 2854.58, "word": " product", "probability": 0.88720703125}, {"start": 2854.58, "end": 2855.7, "word": " depends", "probability": 0.9228515625}, {"start": 2855.7, "end": 2855.98, "word": " on", "probability": 0.93212890625}, {"start": 2855.98, "end": 2856.28, "word": " the", "probability": 0.85791015625}, {"start": 2856.28, "end": 2856.88, "word": " nature", "probability": 0.9609375}, {"start": 2856.88, "end": 2857.12, "word": " of", "probability": 0.97998046875}, {"start": 2857.12, "end": 2857.3, "word": " the", "probability": 0.85400390625}, {"start": 2857.3, "end": 2857.74, "word": " molecule", "probability": 0.85693359375}, {"start": 2857.74, "end": 2857.98, "word": " على", "probability": 0.75390625}, {"start": 2857.98, "end": 2858.44, "word": " طبيعة", "probability": 0.890625}, {"start": 2858.44, "end": 2859.86, "word": " الجزيء", "probability": 0.7137451171875}, {"start": 2859.86, "end": 2860.22, "word": " على", "probability": 0.56494140625}, {"start": 2860.22, "end": 2861.06, "word": " المجموعات", "probability": 0.97685546875}, {"start": 2861.06, "end": 2861.24, "word": " اللي", "probability": 0.76513671875}, {"start": 2861.24, "end": 2861.84, "word": " موجودة", "probability": 0.9892578125}, {"start": 2861.84, "end": 2862.44, "word": " أساسا", "probability": 0.8653564453125}, {"start": 2862.44, "end": 2862.74, "word": " على", "probability": 0.8896484375}, {"start": 2862.74, "end": 2863.9, "word": " أطراف", "probability": 0.970703125}, {"start": 2863.9, "end": 2864.52, "word": " الكربون", "probability": 0.7594401041666666}, {"start": 2864.52, "end": 2864.74, "word": " هل", "probability": 0.860595703125}, {"start": 2864.74, "end": 2865.22, "word": " الجزيء", "probability": 0.9639892578125}, {"start": 2865.22, "end": 2865.58, "word": " حلقة", "probability": 0.9755859375}, {"start": 2865.58, "end": 2865.76, "word": " مش", "probability": 0.91748046875}, {"start": 2865.76, "end": 2866.16, "word": " حلقة", "probability": 0.9586588541666666}, {"start": 2866.16, "end": 2866.32, "word": " ما", "probability": 0.890625}, {"start": 2866.32, "end": 2866.54, "word": " إلى", "probability": 0.849609375}, {"start": 2866.54, "end": 2866.96, "word": " ذلك", "probability": 0.99560546875}], "temperature": 1.0}, {"id": 117, "seek": 286978, "start": 2867.7, "end": 2869.78, "text": "و منكتفي بهذا القدر", "tokens": [2407, 9154, 4117, 2655, 41185, 39627, 15730, 25062, 3215, 2288], "avg_logprob": -0.2801846645095132, "compression_ratio": 0.7608695652173914, "no_speech_prob": 0.0, "words": [{"start": 2867.7, "end": 2868.14, "word": "و", "probability": 0.426513671875}, {"start": 2868.14, "end": 2868.82, "word": " منكتفي", "probability": 0.727935791015625}, {"start": 2868.82, "end": 2869.34, "word": " بهذا", "probability": 0.938232421875}, {"start": 2869.34, "end": 2869.78, "word": " القدر", "probability": 0.9908854166666666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2870.49725, "duration_after_vad": 2737.156874999989}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/z4_9i2lZ2eY_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/z4_9i2lZ2eY_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..06221a431179ca47bac4a540fef3cdf8472859e0
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/z4_9i2lZ2eY_raw.srt
@@ -0,0 +1,2084 @@
+1
+00:00:21,140 --> 00:00:26,480
+بسم الله الرحمن الرحيم المرة الماضية بدأنا في
+
+2
+00:00:26,480 --> 00:00:32,300
+الفصل الثالث في الكيميا العضوية اللي هو بعنوان ال
+
+3
+00:00:32,300 --> 00:00:37,500
+alkenes and alkynes طبعا بشكل أساسي اتعرفنا على
+
+4
+00:00:37,500 --> 00:00:42,020
+خواص الروابط الأوحدية الثنائية الثلاثية واخدنا
+
+5
+00:00:42,020 --> 00:00:46,840
+تسمية ال alkenes و ال alkynes وركزنا على فكرة
+
+6
+00:00:47,640 --> 00:00:53,300
+موجودة كثير في هذا المجال هي فكرة وجود ال stereo
+
+7
+00:00:53,300 --> 00:00:57,700
+isomers تحديدا ال cis و ال trans اللي قولنا عنهم
+
+8
+00:00:57,700 --> 00:01:00,780
+هدول عبارة عن diastereomers
+
+9
+00:01:03,880 --> 00:01:08,860
+كامتداد بسيط فقط لفكرة ال sis و ال trans احنا قلنا
+
+10
+00:01:08,860 --> 00:01:12,940
+بيكون عندنا موجود sis او trans سواء حول ال double
+
+11
+00:01:12,940 --> 00:01:17,340
+bond او حول ال single bond في حلقة اذا كان في عندى
+
+12
+00:01:17,340 --> 00:01:21,380
+على كل ذرة كربون من الذرات المعنية مجمعتين
+
+13
+00:01:21,380 --> 00:01:26,500
+مختلفتين بقدر اقول sis و trans يعني المركب بيكون
+
+14
+00:01:26,500 --> 00:01:33,310
+في منه اتنين الان لو يا ترى أخدنا مثال جديدهذا
+
+15
+00:01:33,310 --> 00:01:39,310
+المثال هي double bond وهي carbon وهي carbon هل هنا
+
+16
+00:01:39,310 --> 00:01:43,250
+في عندي مجموعتين مختلفتين ولا لأ؟ عندي مجموعتين
+
+17
+00:01:43,250 --> 00:01:47,910
+مختلفتين هل هنا في عندي مجموعتين مختلفتين ولا لأ؟
+
+18
+00:01:47,910 --> 00:01:52,230
+في عندي مجموعتين مختلفتين إذا هذا المركب في منه
+
+19
+00:01:52,230 --> 00:01:57,130
+مركب واحد ولا اتنين؟في منه مراكبين لو بده المراكب
+
+20
+00:01:57,130 --> 00:02:02,650
+التاني بثبت اي تنتين وبعكس التنتين التانية يعني
+
+21
+00:02:02,650 --> 00:02:06,990
+لاحظوا هذا المراكب نفسه رسمناها تخلينا على سبيل
+
+22
+00:02:06,990 --> 00:02:12,190
+المثال اليود والكلور زي ما هما عكسنا مجموعة المثل
+
+23
+00:02:12,190 --> 00:02:16,170
+لتحت ال PR لفوق تخلينا ال PR لتحت المثل لفوق هاي
+
+24
+00:02:16,170 --> 00:02:22,320
+المراكب التانيواضح؟ ولو هذا المركب احنا بدنا نسميه
+
+25
+00:02:22,320 --> 00:02:28,540
+مش صعب علينا نسميه كمواقع ذرات كمواقع ذرات carbon
+
+26
+00:02:28,540 --> 00:02:34,400
+تنتين تلاتة أطول سلسلة اذا هذا المركب اي مركب
+
+27
+00:02:34,400 --> 00:02:44,250
+بروبيل بروبيل هذا المركب حامل يود وبروم وكلوربدنا
+
+28
+00:02:44,250 --> 00:02:47,990
+نذكرهم alphabetically، لاحظوا ما حد يقول إنه حامل
+
+29
+00:02:47,990 --> 00:02:53,430
+مثل، المثل جزء من السلسلات الطويلة، هو حامل تلاتة
+
+30
+00:02:53,430 --> 00:02:56,410
+substituents، يود و بروم و كلور، لما نذكرهم
+
+31
+00:02:56,410 --> 00:03:00,870
+alphabetically، two bromo, one cloro, one iodo,
+
+32
+00:03:01,090 --> 00:03:06,750
+one probine لكن، ضالت المشكلة، هل يترى هذا المركب
+
+33
+00:03:06,750 --> 00:03:12,470
+cis ولا trans؟اللي بتيجي تفكر بالعلم البسيط اللي
+
+34
+00:03:12,470 --> 00:03:18,050
+اتعلمته هتفكر بالقاتل انه احنا قولنا اذا في عندى
+
+35
+00:03:18,050 --> 00:03:21,430
+مثلا مجموعتين زي بعض كنا نقول كلور و كلور عجية
+
+36
+00:03:21,430 --> 00:03:26,130
+واحدة سس عجيتين متعاكسات Trans لكن الحمد لله هذا
+
+37
+00:03:26,130 --> 00:03:33,460
+المركب فيه اربع مجموعات مختلفة وبناء على ذلكرغم ان
+
+38
+00:03:33,460 --> 00:03:36,580
+انتوا قادرين تقولوا انه منه two compounds، two
+
+39
+00:03:36,580 --> 00:03:39,720
+stereoisomers، بس ولا واحدة قادرة تقول سيس ولا
+
+40
+00:03:39,720 --> 00:03:44,900
+ترانس تمام؟ الحقيقة الظاهرة هنا شوية اكبر من السيس
+
+41
+00:03:44,900 --> 00:03:49,660
+والترانس لما نيجي نحلها، بنحلها بالشكل القاتل،
+
+42
+00:03:49,660 --> 00:03:53,980
+بنسأل نفسنا، بنقول بدنا نقارن هذه الذرة وهذه
+
+43
+00:03:53,980 --> 00:04:00,320
+الذرة، يود وكلور، هدول مختلفتان، مين فيهم إلها
+
+44
+00:04:00,320 --> 00:04:05,880
+atomic number أعلى؟واضح؟ طبعا مابديش حد يقول مرة
+
+45
+00:04:05,880 --> 00:04:08,840
+تانية مش حافظ الجدول الدوري انا مابديش ال atomic
+
+46
+00:04:08,840 --> 00:04:15,380
+number انا بدي مقارنة والمقارنة الأصل معروفة معروف
+
+47
+00:04:15,380 --> 00:04:18,740
+جزء الجدول الدوري مائة مرة حكينا اللي فيه carbon,
+
+48
+00:04:18,960 --> 00:04:22,160
+nitrogen, oxygen, fluorine, chlorine, bromine,
+
+49
+00:04:22,160 --> 00:04:26,200
+iodine, sulfur هذي أعلى من هذه أعلى من هذه أعلى من
+
+50
+00:04:26,200 --> 00:04:30,350
+هذه أعلى من هذه أعلى من هذه أعلى من هذه واضح؟هذا
+
+51
+00:04:30,350 --> 00:04:34,670
+الكلام معروف اذا لما انا بدي اقارن يود مع كلور مين
+
+52
+00:04:34,670 --> 00:04:39,890
+الأعلى ال يود ممتازة في ال atomic number لما بدي
+
+53
+00:04:39,890 --> 00:04:45,150
+اقارن بروم مع كاربون اطلع ذرة ذرة مديش اقول مع ال
+
+54
+00:04:45,150 --> 00:04:48,550
+CH3 لأ مع الذرة المتصلة مباشرة مع اي ذرة المتصلة
+
+55
+00:04:48,550 --> 00:04:53,090
+مباشرة بال double bond كاربون الذرة هنا بروم مين
+
+56
+00:04:53,090 --> 00:04:58,510
+أعلى بروم ولا كاربونأكيد لبروم، الآن هذه الأعلى و
+
+57
+00:04:58,510 --> 00:05:03,350
+هذه الأعلى إجوا على جهة واحدة، في هذه الحالة كإني
+
+58
+00:05:03,350 --> 00:05:09,210
+بتخيل إنه المركب إيش؟ سس، لو إجيت هنا يود و كلور،
+
+59
+00:05:09,210 --> 00:05:17,270
+اليود أعلىبروم و Carbon البروم أعلى بناء على ذلك
+
+60
+00:05:17,270 --> 00:05:23,790
+المجموعات الأعلى أتوا على جهتين متعاكستين كأن هذا
+
+61
+00:05:23,790 --> 00:05:30,070
+المركب Trans لكن الحقيقة هنا جرت العادة أننا
+
+62
+00:05:30,070 --> 00:05:37,150
+مانستعملش مصطلح زد Trans و Cis لأ بنستعمل بديل له
+
+63
+00:05:37,150 --> 00:05:43,510
+ال Cis و ال Trans عادةتستعمل للمراكبات البسيطة
+
+64
+00:05:43,510 --> 00:05:50,170
+الواضحة اللي عمل هذه القواعد إنسان معتزب لغته لغته
+
+65
+00:05:50,170 --> 00:05:55,170
+ألمانية احنا في العربي كنا نستعمل بدل cis و trans
+
+66
+00:05:55,170 --> 00:06:04,930
+مع و ضد الإنجليز cis و trans الآن هو ألماني مش أقل
+
+67
+00:06:04,930 --> 00:06:09,680
+منه قال لأ أنا بدي أجيب من اللغة الألمانيةإيش معنى
+
+68
+00:06:09,680 --> 00:06:14,400
+مع وإيش معنى ضد، يعني البادئة تبقى .. البادئة
+
+69
+00:06:14,400 --> 00:06:17,960
+بديها من اللغة الألمانية، فباللغة الألمانية مع
+
+70
+00:06:17,960 --> 00:06:25,940
+اللي هي together، it's zusammen، zusammen بالزدسو
+
+71
+00:06:25,940 --> 00:06:31,600
+زامن الآن جال من سو زامن بدي أخد حرف ال Z فال Z
+
+72
+00:06:31,600 --> 00:06:38,080
+هذه صارت موازية لل سس اللي بالإنقليزي و لكلمة مع
+
+73
+00:06:38,080 --> 00:06:46,480
+اللي احنا بنستعملها بالعربي واضح ف Z بمعنى سس من
+
+74
+00:06:46,480 --> 00:06:51,940
+ناحية المعنى او مع الان اتيه ايش معنى ضد برضه راح
+
+75
+00:06:51,940 --> 00:06:59,280
+على اللغة تبعتهانت جاجل انت جاجل اخد منها حرف ايش؟
+
+76
+00:07:00,080 --> 00:07:06,360
+انت جي جن اخد منها حرف ال E فال E هذه صارت بمعنى
+
+77
+00:07:06,360 --> 00:07:12,040
+Trans او بمعنى ضد للناس اللي بيكتبوا باللغة
+
+78
+00:07:12,040 --> 00:07:17,620
+العربية واضح طبعا البعض هيقول طب احنا وقتاش نكتب
+
+79
+00:07:17,620 --> 00:07:23,580
+Sis و Trans و وقتاش نكتب Z و E بنقول في المراكبات
+
+80
+00:07:23,580 --> 00:07:30,440
+البسيطة الواضحة بنكتب Sis و Transفي المُركّبات
+
+81
+00:07:30,440 --> 00:07:34,680
+اللي فيها أكتر من مجموعة و بنتغلب و نحسب ال atomic
+
+82
+00:07:34,680 --> 00:07:41,520
+number بنكتب Z to E بالمناسبة هل هذه القواعد اللي
+
+83
+00:07:41,520 --> 00:07:47,160
+هي ترتيب المجموعات حسب ال atomic number جديدة؟ لأ
+
+84
+00:07:47,160 --> 00:07:51,020
+يعني لو أنا أخدت نفس المُركّب البسيط اللي كنت
+
+85
+00:07:51,020 --> 00:07:59,810
+أحكيه CL CL H H هذا المُركّب عارفينه ولا لأ؟واضح؟
+
+86
+00:07:59,810 --> 00:08:04,230
+الان لو اتيت سؤالك CL او H؟ مين اعلى في ال atomic
+
+87
+00:08:04,230 --> 00:08:10,650
+number؟ CLCl وH هاي مختلفتان و هاي مختلفتان مين
+
+88
+00:08:10,650 --> 00:08:13,550
+أعلى في ال atomic number اللي أعلى في ال atomic
+
+89
+00:08:13,550 --> 00:08:19,270
+number على جهة واحدة إذا هذا المركب Z بس لأنه بسيط
+
+90
+00:08:19,270 --> 00:08:24,530
+و مبين بالنظر استعمالنا له مصطلح إيش SIS واضح و
+
+91
+00:08:24,530 --> 00:08:30,310
+لذلك مش غلط كبير إنه مرات بتلاقوا بعض الناس بدل
+
+92
+00:08:30,310 --> 00:08:35,840
+كلمة SIS بيكتبوا Z أو بدل Z بيكتبوا SIS يعنيلكن
+
+93
+00:08:35,840 --> 00:08:39,540
+لما انتوا بدكم شبه قاعدة عامة بنقول إذا المركبات
+
+94
+00:08:39,540 --> 00:08:42,980
+بسيطة في الغالب هتلاقي الكتب كاتبة معها مصطلحات
+
+95
+00:08:42,980 --> 00:08:48,080
+SIS وTRANS إذا شوية أصعب هتلاقي الكتب كاتبة معها
+
+96
+00:08:48,080 --> 00:08:53,360
+مصطلحات Z وE واضح فقط لغاية
+
+97
+00:08:57,330 --> 00:09:03,570
+الان هذه القواعد عادة بيسموها Can Engel de Brelog
+
+98
+00:09:03,570 --> 00:09:08,050
+Rules اللي هي قواعد ترتيب المجموعات حسب الأعلى في
+
+99
+00:09:08,050 --> 00:09:11,610
+ال atomic number هتعود تلزمنا في ال stereo
+
+100
+00:09:11,610 --> 00:09:16,430
+chemistry و بنكتب اسم الآن مش مستعجلين عليه خلينا
+
+101
+00:09:16,430 --> 00:09:22,090
+ناخدها ببساطة قواعد ترتيب المجموعات حسب الاشالـ
+
+102
+00:09:22,090 --> 00:09:27,030
+atomic number أحيانا بيجي نحل مشكلتنا نشوف مين
+
+103
+00:09:27,030 --> 00:09:31,190
+أعلى في ال atomic number هنا سهل جدا يود ولا CL
+
+104
+00:09:31,190 --> 00:09:37,910
+يود ابتثانية أحيانا بيلاقي الذرتين زي بعض وجدتها
+
+105
+00:09:37,910 --> 00:09:44,390
+بيروح للذرة اللي بعدهمبالهم زي بعض بنروح للبعدها
+
+106
+00:09:44,390 --> 00:09:49,610
+لحد ما نصل لأول اختلاف بيخلي مجموعة أعلى من
+
+107
+00:09:49,610 --> 00:09:54,090
+التانية واضح يعني مثلا هذا المركب لو كنتوا بتطلع
+
+108
+00:09:54,090 --> 00:09:59,950
+عليه هاي carbon شو المجموعات اللي عليها CH3 CH2
+
+109
+00:09:59,950 --> 00:10:06,530
+CH3 لو أجينا نسأل مين أعلى هدول مختلفات هنا carbon
+
+110
+00:10:07,430 --> 00:10:14,550
+وهنا carbon زي بعض وقت أروح للذرة التانية لو بدكوا
+
+111
+00:10:14,550 --> 00:10:20,430
+بالتفصيل الممل أكيد هتقولوا أن هنا في عندي H وH و
+
+112
+00:10:20,430 --> 00:10:31,390
+بعدها carbon هذه H وH و بعدها H فلو إجيتوا تقارنوا
+
+113
+00:10:31,390 --> 00:10:38,490
+C وحملة كل هذا زي بعضه C وحملةوين أول اختلاف؟ نمر
+
+114
+00:10:38,490 --> 00:10:43,810
+اتنين carbon، نمر اتنين H، اذا من المجموعة الأعلى
+
+115
+00:10:43,810 --> 00:10:50,010
+صفيات؟ فانا لما بمشي في المجموعاتبالترتيب يعني
+
+116
+00:10:50,010 --> 00:10:53,090
+الذرة الأولى ماحلتش المشكلة عند ما قالتليش مين
+
+117
+00:10:53,090 --> 00:10:57,330
+أعلى في ال atomic number بروح لا إيش للي بعدها أول
+
+118
+00:10:57,330 --> 00:11:01,370
+ذرة بتعمل الفرق هي اللي بتحدد هل هذه المجموعة أعلى
+
+119
+00:11:01,370 --> 00:11:05,050
+و هدى مع الخبرة بيصير سهل عليكم أنه لو بتشوفوا زي
+
+120
+00:11:05,050 --> 00:11:09,090
+إثل و مثل أنه بتاني تقولوا ال إثل بدون ما تقعدوا
+
+121
+00:11:09,090 --> 00:11:14,110
+تعملوا كل هالتحليل لكن القاعدة العامة ذرة ذرة
+
+122
+00:11:14,110 --> 00:11:14,950
+بنكون ماشيين
+
+123
+00:11:17,660 --> 00:11:24,700
+انجلي حالك صعب ان انا اعيد كتاب واضح و لذلك هذه
+
+124
+00:11:24,700 --> 00:11:30,040
+الاثل صارت اعلى من المثل الان هنحطين مركب او
+
+125
+00:11:30,040 --> 00:11:37,260
+مجمعتين شويه كبار لاحظوا carbon و carbonزي بعض هذه
+
+126
+00:11:37,260 --> 00:11:42,740
+carbon و هذه الذرة carbon الان هذه ال carbon متصلة
+
+127
+00:11:42,740 --> 00:11:47,700
+ب CH3 و هذه ال carbon متصلة ب CH3 كل ما هو مشترك
+
+128
+00:11:47,700 --> 00:11:51,480
+لن يحدد الفرق شو اللي بده يحدد الفرق؟ شي مختلف
+
+129
+00:11:51,480 --> 00:11:57,440
+الان بعد هيك هذه متصلة برابطة واحدة مع ال O هذه
+
+130
+00:11:57,440 --> 00:12:02,190
+متصلة بكم رابطة مع ال O؟ برابطة تانيةيعني كأنه هذه
+
+131
+00:12:02,190 --> 00:12:06,910
+متصلة بـ O وهذه متصلة بـ O اتفقنا طب الرابط الرابع
+
+132
+00:12:06,910 --> 00:12:14,480
+هنا H هنا Oابتبوا معي عاملوا هذه كإنها رابطتين مع
+
+133
+00:12:14,480 --> 00:12:18,080
+O و هذه كإنها رابطة يعني لو جيت سألت الأربع روابط
+
+134
+00:12:18,080 --> 00:12:24,980
+اللي على ال carbon واحدة مع CH3 مع CH3 مع O مع O
+
+135
+00:12:24,980 --> 00:12:29,640
+مع ال carbon هذه مع ال carbon هذه إيش ضال؟ الرابعة
+
+136
+00:12:29,640 --> 00:12:36,620
+مع H الرابعة مع O رابطة التانية، أنه أعلى و لذلك
+
+137
+00:12:36,620 --> 00:12:41,900
+كل المجموعة هذه صارت أعلىواضح؟ فأنا بالتدريج بقدر
+
+138
+00:12:41,900 --> 00:12:45,300
+أحل المشاكل الآن هذولا المجمعتين العليا على جهة
+
+139
+00:12:45,300 --> 00:12:52,100
+واحدة إذا هذا المركب إيش؟ Z واضح؟ هاي مركب تالت
+
+140
+00:12:52,100 --> 00:12:58,940
+هاي عندكم يود و كلور هذه الحالة السهلة من أعلى ال
+
+141
+00:12:58,940 --> 00:13:05,040
+يود أعلى من الكلور okay الآن هنا عندك carbon و
+
+142
+00:13:05,040 --> 00:13:07,100
+carbon
+
+143
+00:13:09,230 --> 00:13:13,670
+الذرتين زي بعض طالما زي بعض بتطلع على الذرات اللي
+
+144
+00:13:13,670 --> 00:13:18,610
+بعضهم هذه ال carbon متصلة ب carbon الرابطة الأولى
+
+145
+00:13:18,610 --> 00:13:24,090
+و الرابطة الثانية ب carbon و التالتة ب H يعني لو
+
+146
+00:13:24,090 --> 00:13:29,570
+جيتوا التلت روا بتاعونها carbon carbon H تعالوا
+
+147
+00:13:29,570 --> 00:13:36,410
+على هذه carbon carbon carbon اذا مين أعلى شوفت
+
+148
+00:13:36,410 --> 00:13:40,490
+واحدة افرجتهمفبصير كل هذه المجموعة على و لذلك هذا
+
+149
+00:13:40,490 --> 00:13:46,770
+المُركّب Z الآن بالتدريب بإمكانكم تتعودوا من خلال
+
+150
+00:13:46,770 --> 00:13:51,030
+حل أسئلة امتحانات سابقة او اشهر تلاحظوا و تميزوا
+
+151
+00:13:51,030 --> 00:13:54,570
+المُركّبات اللي فيها Z و E لكن في كل الأحوال إذا
+
+152
+00:13:54,570 --> 00:13:59,630
+إجاكوا تسمية ال keenإذا إجاكوا تسمية ال keen بتكون
+
+153
+00:13:59,630 --> 00:14:03,170
+تتطلعوا على أطراف ال double bond اللي موجودة فيه
+
+154
+00:14:03,170 --> 00:14:06,990
+إذا عليها مجموعات مختلفة ومجموعات مختلفة يجب أن
+
+155
+00:14:06,990 --> 00:14:12,950
+يوجد في التسمية z أو e وإذا كان الأمر بسيط جدا
+
+156
+00:14:12,950 --> 00:14:18,650
+ممكن تكتبوا cis وtrans واضح؟ ممكن تكتبوا cis
+
+157
+00:14:18,650 --> 00:14:23,630
+وtrans هذا بالنسبة لاستعمال البادئة z وe
+
+158
+00:14:26,930 --> 00:14:32,890
+الان بننتقل لموضوع جديد اللي هو تفاعلات ال الكنز
+
+159
+00:14:32,890 --> 00:14:39,090
+ال الكنز اللي هم تفاعل أساسي هتلاحظوا انه بتكرر
+
+160
+00:14:39,090 --> 00:14:44,470
+عندى كثير هذا التفاعل الأساسي اللي لل الكنز بسميه
+
+161
+00:14:44,470 --> 00:14:50,450
+انا addition reaction addition تفاعل إيش الإضافة
+
+162
+00:14:50,860 --> 00:14:55,580
+إيش هو باختصار تفاعل الإضافة؟ باختصار إنه بيكون
+
+163
+00:14:55,580 --> 00:15:00,650
+عندي carbonDouble bond carbon هاي ال double bond
+
+164
+00:15:00,650 --> 00:15:05,250
+يعني بركز تفاعل وين؟ ع ال double bond لما أجي أضيف
+
+165
+00:15:05,250 --> 00:15:10,250
+عليها أي reagent زي خلينا هيك ناخده بشكل عام HX
+
+166
+00:15:10,250 --> 00:15:14,810
+بيصير carbon single bond carbon لاحظوا ال double
+
+167
+00:15:14,810 --> 00:15:21,910
+bond صارت single bond ال bi bond هادي اتحولت لإيش؟
+
+168
+00:15:21,910 --> 00:15:31,810
+انضاف رابطتين بدالها هنا Hو X اتش و X اتش و X اللي
+
+169
+00:15:31,810 --> 00:15:37,310
+انضافوا واضح طبعا هنا في عنده أشياء تانية كانت
+
+170
+00:15:37,310 --> 00:15:42,770
+موجودة بتظل زي ما هيأي ما كانت تكون يعني هذا
+
+171
+00:15:42,770 --> 00:15:46,170
+المركب شكله الكامل carbon عليها رابطات المتصلات
+
+172
+00:15:46,170 --> 00:15:49,830
+بإيش ما كان مش موضوعي وهذه نفس الاشياء أنا تركيزي
+
+173
+00:15:49,830 --> 00:15:55,770
+على carbon double bond carbon بخليها carbon single
+
+174
+00:15:55,770 --> 00:16:02,040
+bond carbon الآن هذه ال by bond اتحولت لإيشلـ two
+
+175
+00:16:02,040 --> 00:16:06,840
+new sigma bonds يعني تفاعل الـ addition لو بدي
+
+176
+00:16:06,840 --> 00:16:14,560
+تعريف له بدي أقول تحويل ال buy bond هذه الى two
+
+177
+00:16:14,560 --> 00:16:24,210
+new sigma bondsواضح تحويل ال buy bond ل two new
+
+178
+00:16:24,210 --> 00:16:28,990
+sigma bonds او ال double bond صارت single bond هذا
+
+179
+00:16:28,990 --> 00:16:33,510
+هو التفاعل الأساسي في ال ال keys تفاعل ال addition
+
+180
+00:16:33,510 --> 00:16:39,050
+ان احول انا ال double bond ل single bond واضح الان
+
+181
+00:16:39,050 --> 00:16:45,210
+لو بدنا نتطلع على مكونات هذا التفاعل هلاحظ ان هذا
+
+182
+00:16:45,210 --> 00:16:52,150
+التفاعل بتكون من شغلتينبتكون من الكين اللى بتم
+
+183
+00:16:52,150 --> 00:16:57,250
+عليه التفاعل والمادة المتفاعلة بسميها reagent واضح
+
+184
+00:16:57,250 --> 00:17:04,610
+فالكين هيكم شايفينه ال الكين بتفاعل مع ال reagent
+
+185
+00:17:04,610 --> 00:17:11,620
+اللى انا بدي اضيفه بيعمل additionمكونات عملية
+
+186
+00:17:11,620 --> 00:17:17,540
+الإضافة الكينورياجين الان لو بدى أطلع على أحوال
+
+187
+00:17:17,540 --> 00:17:21,260
+الألكين اللى موجود عندى هذا الألكين اللى موجود
+
+188
+00:17:21,260 --> 00:17:26,900
+عندى يمكن أن يكون ألكين متماثل ويمكن أن يكون ألكين
+
+189
+00:17:26,900 --> 00:17:34,660
+غير متماثل يعنى الألكين ممكن يكون symmetric متماثل
+
+190
+00:17:34,660 --> 00:17:38,000
+أو متشابه أو unsymmetric
+
+191
+00:17:40,420 --> 00:17:44,840
+خلّينا نعطيكم مثال على كل واحد، إيش يعني symmetry؟
+
+192
+00:17:44,840 --> 00:17:49,200
+لو افترضت الألكين اللي عندى إيثيلين أبسط واحد،
+
+193
+00:17:49,200 --> 00:17:59,040
+يعني C double bond C وهنا H اتنين تلاتة أربعةهذا
+
+194
+00:17:59,040 --> 00:18:02,280
+متماثل ولا لأ؟ يعني لو اتخيلت ان هنا في مرايا
+
+195
+00:18:02,280 --> 00:18:06,460
+carbon CH2 و carbon CH2 هذا symmetric alkene ولا
+
+196
+00:18:06,460 --> 00:18:11,580
+لأ؟ أكيد الآن ممكن ناخد unsymmetric alkene لو
+
+197
+00:18:11,580 --> 00:18:16,980
+افترضت انه عند البروبين C double bond C حطيت هنا H
+
+198
+00:18:16,980 --> 00:18:25,720
+OH و هنا H و هنا CH3 البروبينهل يا ترى هذا الالكين
+
+199
+00:18:25,720 --> 00:18:32,180
+متماثل؟ هذا متماثل
+
+200
+00:18:32,180 --> 00:18:42,280
+CH2 CH2 هذا CH2 CH3 إذا الالكين ممكن يكون
+
+201
+00:18:42,280 --> 00:18:49,080
+symmetric وممكن يكون unsymmetric واضح الفكرة؟ الآن
+
+202
+00:18:49,080 --> 00:18:54,230
+لو جيت لل reagent اللي بدي أضيفهنفس الاشي كمان
+
+203
+00:18:54,230 --> 00:18:58,210
+ممكن يكون symmetric يعني الشغلتين زي بعض او
+
+204
+00:18:58,210 --> 00:19:03,270
+unsymmetric ناخد أنفلة بسيطة مثلا لو ناس بيضيفوا
+
+205
+00:19:03,270 --> 00:19:10,390
+الهيدروجين الهيدروجين عبارة عن ايش H وH هله
+
+206
+00:19:10,390 --> 00:19:14,730
+symmetric ولا لأ symmetric لو ناس بيضيفوا برومين
+
+207
+00:19:14,730 --> 00:19:17,470
+PR PR
+
+208
+00:19:19,970 --> 00:19:23,850
+Symmetric ولا لأ؟ Symmetric طب لو بدي أشوف الـ
+
+209
+00:19:23,850 --> 00:19:33,350
+Unsymmetric لو ناس بيضيفوا ميّه H و OH زي هي كي
+
+210
+00:19:33,350 --> 00:19:40,550
+بنعتبرها قطعة تانية H و OH لو بيضيفوا HBR او HCL
+
+211
+00:19:40,550 --> 00:19:48,840
+هاي HCL او HBR واضح ف ..اللي بنلاحظه لما بنعمل هذه
+
+212
+00:19:48,840 --> 00:19:52,280
+العملية ان ال الكين ممكن يكون symmetric او
+
+213
+00:19:52,280 --> 00:19:55,200
+unsymmetric و ال reagent ممكن يكون symmetric او
+
+214
+00:19:55,200 --> 00:20:01,800
+unsymmetric طيب عملية الإضافة كام ناتج بتطلع؟عملية
+
+215
+00:20:01,800 --> 00:20:08,040
+الإضافة في حالة واحدة بتطلع ناتجين بدنا نكون
+
+216
+00:20:08,040 --> 00:20:12,000
+منتبهين لها تماما، بعد ذلك بتطلع عندي ناتج واحد
+
+217
+00:20:12,000 --> 00:20:18,840
+إذا ضفت Unsymmetric reagent على Unsymmetric alkene
+
+218
+00:20:18,840 --> 00:20:27,500
+بتوقع ناتجين الآن بنرسمهم و بنوضحهممعد ذلك لو ضيفت
+
+219
+00:20:27,500 --> 00:20:29,940
+symmetric على symmetric أو symmetric على
+
+220
+00:20:29,940 --> 00:20:36,700
+unsymmetric ناتج واحد إذا متى يتوقع ناتجين؟ إذا
+
+221
+00:20:36,700 --> 00:20:41,980
+أنا بضيف unsymmetric alkene على unsymmetric
+
+222
+00:20:41,980 --> 00:20:46,720
+reagent هذه الحالة على طول يتوقع فيها كم ناتج؟
+
+223
+00:20:46,720 --> 00:20:55,920
+ناتجين معد ذلك فيطلع عندى ناتج واحدخلّينا نبدأ
+
+224
+00:20:55,920 --> 00:21:02,300
+نشوف أمثلة على الحالات اللي بنضيف فيها أحد الأطراف
+
+225
+00:21:02,300 --> 00:21:06,820
+symmetric، قدش هيطلع عندنا؟ ناتج واحدة، بعدها
+
+226
+00:21:06,820 --> 00:21:12,020
+بننتقل لـ unsymmetric مع unsymmetric و بنشوف
+
+227
+00:21:12,020 --> 00:21:15,740
+ناتجين، نمشي الآن مع ال slides
+
+228
+00:21:26,510 --> 00:21:32,170
+هذه أول تفاعل لو احنا يا تورا بدنا نضيف الهيدروجين
+
+229
+00:21:32,170 --> 00:21:37,110
+الهيدروجين سيمتريك ولا انسيمتريك؟ سيمتريك إذا كام
+
+230
+00:21:37,110 --> 00:21:41,410
+ناتج بتوقع يطلع عنده؟ ناتج واحد أي أن كان الالكيد
+
+231
+00:21:41,410 --> 00:21:44,570
+سواء كان هذا الالكيد سيمتريك أو انسيمتريك طالما
+
+232
+00:21:44,570 --> 00:21:50,450
+الهيدروجين متماثل إذا اللي هيطلع عنده ناتج واحد
+
+233
+00:21:50,450 --> 00:21:54,930
+الآن لو بدنا نكتب هذا الناتج بدنا نضيف هيدروجين
+
+234
+00:21:54,930 --> 00:22:02,870
+وهيدروجينواضح؟ انتهى الجواب هذا الكن ضفنا عليه جزء
+
+235
+00:22:02,870 --> 00:22:07,010
+الهيدروجين حط هيدروجين هان وهيدروجين هان صار الكن
+
+236
+00:22:07,960 --> 00:22:13,200
+الالكيل باضافة الهيدروجين صار عبارة عن الكل
+
+237
+00:22:13,200 --> 00:22:16,460
+الهيدروجين
+
+238
+00:22:16,460 --> 00:22:22,080
+هنا بنضيف معلومة صغيرة انه لما بيضيف بيضيف من جهة
+
+239
+00:22:22,080 --> 00:22:25,980
+واحدة يعني مابتيجيش ذرة هيدروجين من فوق و ذرة
+
+240
+00:22:25,980 --> 00:22:30,190
+هيدروجين من التحت لأ الذرتين الهيدروجين بيجوامن
+
+241
+00:22:30,190 --> 00:22:34,610
+جهة واحدة يعني بهذا الشكل زي ما تتخيلوا انه انا
+
+242
+00:22:34,610 --> 00:22:38,710
+الان ماسك جزء الهيدروجين هذا قاعد بضيفه نفترض هان
+
+243
+00:22:38,710 --> 00:22:44,370
+دابل بوند الذرتين اجوا على الجهة هذه ما بيجيشبجهات
+
+244
+00:22:44,370 --> 00:22:48,990
+متعاكسة الان هذه الإضافة اللى من جهة واحدة انا
+
+245
+00:22:48,990 --> 00:22:53,630
+بسميها sin addition لو كان بضيف من جهتين عكس بعض
+
+246
+00:22:53,630 --> 00:22:57,890
+بسميها ايش Anti addition فالهيدروجين هنا ايش نوع
+
+247
+00:22:57,890 --> 00:23:03,230
+الإضافة اللى بعملها sin addition معنى sin addition
+
+248
+00:23:03,230 --> 00:23:09,360
+انه بضيف من جهة واحدةواضح؟ معنى sin addition انه
+
+249
+00:23:09,360 --> 00:23:15,160
+بيضيف من جهة واحدة ممكن نعطي تفسير سريع ليش
+
+250
+00:23:15,160 --> 00:23:19,360
+الهيدروجين بيضيف من جهة واحدة لو بتطلعوا بالاتباه
+
+251
+00:23:19,360 --> 00:23:25,260
+هذا التفاعل بتم من خلال إضافة غاز الهيدروجين في
+
+252
+00:23:25,260 --> 00:23:30,660
+وجود معدن هذا المعدن غالبا بنستعمل بلاتين قطع من
+
+253
+00:23:30,660 --> 00:23:37,380
+المعدن الصغيرةبلاتين ممكن نستعمل معدن تاني ممكن
+
+254
+00:23:37,380 --> 00:23:42,820
+نستعمل بلاديم ممكن نستعمل nickel وعشانك مرات
+
+255
+00:23:42,820 --> 00:23:48,340
+بتلاحظوا مكتوب عندكم ايش ام ايش يعني ام هنا metal
+
+256
+00:23:48,340 --> 00:23:55,460
+في وجود metal catalyst هذا عامل حفاز catalyst ام
+
+257
+00:23:55,460 --> 00:24:01,940
+يعني metalكتاليست ايش كتاليست؟ أعمل حفاظ أعمل حفاظ
+
+258
+00:24:01,940 --> 00:24:06,100
+الآن هذا ال كتاليست ممكن يكون platinum ممكن يكون
+
+259
+00:24:06,100 --> 00:24:11,140
+palladium ممكن يكون nickel واضح هذا بيخلي التفاعل
+
+260
+00:24:11,140 --> 00:24:16,860
+يمشي بشكل سريع طب إيش بيعمل هذا الكتاليست؟ هذا
+
+261
+00:24:16,860 --> 00:24:21,180
+الكتاليست يلتصق الهيدروجين على سطحه يعني تخيلوا
+
+262
+00:24:21,180 --> 00:24:27,310
+هذا هو الكتاليستهذا سطح معدن هو الـ catalyst الان
+
+263
+00:24:27,310 --> 00:24:32,030
+الهيدروجين كجزء بيجي يلتصق على سطح ال catalyst
+
+264
+00:24:32,030 --> 00:24:37,870
+طالما يلتصق على سطح ال catalyst بهذا الشكل لما
+
+265
+00:24:37,870 --> 00:24:42,370
+بيجي يضيف ع double bond هاي double bond شايفينهم؟
+
+266
+00:24:42,370 --> 00:24:47,170
+هل ممكن هو ملتصق انه يضيف من جهتين؟ لأ بيجي زي هيك
+
+267
+00:24:47,170 --> 00:24:56,280
+زي هيكوترك الميتل كان ممسوك بالميتل جزء الهيدروجين
+
+268
+00:25:00,170 --> 00:25:05,170
+ضاف بهذا الشكل وبناء على ذلك ضاف من جهة واحدة
+
+269
+00:25:05,170 --> 00:25:11,170
+فبنقول احنا ان ال hydrogen gas adsorbs to the
+
+270
+00:25:11,170 --> 00:25:15,510
+metal surface لاحظوا تتذكروا معنا كلمة adsorption
+
+271
+00:25:15,510 --> 00:25:22,070
+adsorption شو معناها التصاق على السطح بديش اسمع
+
+272
+00:25:22,070 --> 00:25:29,510
+كلمة امتصاص كلمة امتصاصabsorption بالعربي شو
+
+273
+00:25:29,510 --> 00:25:33,830
+بنقولها absorption ادمصاص
+
+274
+00:25:33,830 --> 00:25:39,170
+بالدالة لاحظوا عندكم مصطلحين عندكم مصطلحين يعني
+
+275
+00:25:39,170 --> 00:25:44,070
+تخيلوا high metal surface و high metal surface بده
+
+276
+00:25:44,070 --> 00:25:49,290
+احط شيء عليه إذا الشيء هذا التسق هنا التساق على
+
+277
+00:25:49,290 --> 00:25:54,110
+السطح الخارجي هذا بسميه absorption
+
+278
+00:25:58,830 --> 00:26:06,610
+absorption وإذا هذا الشيء دخل جوا المتل تماما زي
+
+279
+00:26:06,610 --> 00:26:09,430
+ما الإنسان أحيانا بياخد برهام بيحطه على الإيد
+
+280
+00:26:09,430 --> 00:26:14,770
+بيدخل جوا الإيد هذه العملية إيش بنسميها absorption
+
+281
+00:26:14,770 --> 00:26:21,630
+absorption هدولة مصطلحين باللغة العربية بنسميه
+
+282
+00:26:21,630 --> 00:26:30,690
+absorptionادمصاص وال absorption امتصاص واضح فال
+
+283
+00:26:30,690 --> 00:26:35,030
+absorption عادة بيكون at the surface على السطح ال
+
+284
+00:26:35,030 --> 00:26:41,780
+absorption جواواضح الفكرة؟ بالمصطلحين الآن الغاز
+
+285
+00:26:41,780 --> 00:26:46,680
+يا ترى بقدر يدخل جوا المعدن إذا إيش بيصيرله؟
+
+286
+00:26:46,680 --> 00:26:53,580
+absorption تماما زي مثلا الفحم ما بيمطص الغازاته
+
+287
+00:26:53,580 --> 00:26:57,300
+عشان هيك يستعمل في الأقنعة اللي بيستعملوها في
+
+288
+00:26:57,300 --> 00:27:01,780
+الحروب وما إلى ذلك بيخلوا الفحم باودر على أساس
+
+289
+00:27:01,780 --> 00:27:06,760
+يصيرله surface كبير الغاز وين بيجي بيلتصق؟على
+
+290
+00:27:06,760 --> 00:27:12,080
+السطح الخارجي لبودرة الفحم ولذلك القناع أو الكمامة
+
+291
+00:27:12,080 --> 00:27:17,700
+تبع الحرب بتكون ملانا ايش؟ فحم لأن الغازات بيصير
+
+292
+00:27:17,700 --> 00:27:22,420
+الالتصاق على سطح الفحم يمكن احنا الفكرة بنستعملها
+
+293
+00:27:22,420 --> 00:27:27,240
+شوية تطبيقيا لما الناس مرات بيسافروا و بدهم يسيبوا
+
+294
+00:27:27,240 --> 00:27:31,220
+التلاجة بتاعتهم لفترة مش شغالة بيجيبوا خمس ست
+
+295
+00:27:31,220 --> 00:27:36,790
+فحمات و بيحطوهم بالفريزر عشان مايصلوشواضح الفكرة؟
+
+296
+00:27:36,790 --> 00:27:41,350
+الآن هذا الفحم بيلتصق عليه الغاز، كذلك الـmetal
+
+297
+00:27:41,350 --> 00:27:46,250
+هنا بيلتصق وين؟ الهيدروجين بيلتصق على الـmetal،
+
+298
+00:27:46,250 --> 00:27:49,730
+الآن هذا الهيدروجين اللي ملتصق على الـmetal لما
+
+299
+00:27:49,730 --> 00:27:54,310
+يلاقي الـdouble bond، هيضيف عليها من جهة واحدة،
+
+300
+00:27:54,310 --> 00:28:00,640
+يعمل عند إيش؟Sin addition يعني هاي مثال تاني هاي
+
+301
+00:28:00,640 --> 00:28:04,440
+double bond الهيدروجين ملتصق على سطح المعدن، هاي
+
+302
+00:28:04,440 --> 00:28:08,640
+المعدن هي ملتصق لما ضاف، ضاف من جهة واحدة ولا من
+
+303
+00:28:08,640 --> 00:28:13,260
+جهتين؟ من جهة واحدة فما نوع الإضافة هنا؟ Sin
+
+304
+00:28:13,260 --> 00:28:19,200
+addition الآن، هل يا ترى الـ Sin addition تؤدي
+
+305
+00:28:19,200 --> 00:28:24,750
+لتكون مركب cis أو trans أو لأ؟ هذا موضوع تانيبتكون
+
+306
+00:28:24,750 --> 00:28:30,090
+تميزه بين شغلتين، بين شيء اسمه كيف تمت الإضافة،
+
+307
+00:28:30,090 --> 00:28:33,910
+بنقول قولا واحدا تمت الإضافة من جهة واحدة، the
+
+308
+00:28:33,910 --> 00:28:38,730
+same addition، الآن الناتج، هل يا تورا الناتج اللي
+
+309
+00:28:38,730 --> 00:28:43,090
+موجود عندي، cis ولا trans؟كلمة Sis و Trans تعتمد
+
+310
+00:28:43,090 --> 00:28:46,730
+على المجموعات اللي موجودة، يعني هنا بعد ما تمت
+
+311
+00:28:46,730 --> 00:28:51,670
+الإضافة، و تمت من اتجاه واحد، باجي بسأل يا ترى،
+
+312
+00:28:51,670 --> 00:28:57,910
+هذا في Sis و Trans؟ بقول أتش و أتش متشابهتان، و
+
+313
+00:28:57,910 --> 00:29:01,090
+أتش مثل مختلفتان، مافيش ظاهرة الـ Sis و الـ Trans
+
+314
+00:29:02,120 --> 00:29:08,160
+لكن الإضافة تمت من جهة واحدة دائما الآن إن الإضافة
+
+315
+00:29:08,160 --> 00:29:11,480
+اللي من جهة واحدة اللي هي الـ Sin addition هل
+
+316
+00:29:11,480 --> 00:29:16,080
+إجباري إنها تطلع Sis و Trans؟ لأ Sis و Trans
+
+317
+00:29:16,080 --> 00:29:21,760
+بتعتمد على المجموعات الموجودة ولذلك نفس هذا المثال
+
+318
+00:29:21,760 --> 00:29:30,330
+لو طلعته هنا هاي Double bond عليها مجموعتين مثلو
+
+319
+00:29:30,330 --> 00:29:35,830
+بدنا نضيف عليها هيدروجين كيف هنضيف الهيدروجين؟ من
+
+320
+00:29:35,830 --> 00:29:40,110
+جهة واحدة هينضفنا الهيدروجين و الهيدروجين من جهة
+
+321
+00:29:40,110 --> 00:29:44,750
+واحدة لتحت يعني صار عندى الحلقة الخماسية فيها
+
+322
+00:29:44,750 --> 00:29:49,880
+مجموعتين الميثلعلى جهة واحدة والهيدروجينز على جهة
+
+323
+00:29:49,880 --> 00:29:54,760
+واحدة الان هذا المركب في سيس وترانز اطلعوا كاربون
+
+324
+00:29:54,760 --> 00:29:59,840
+حاملة مثل و اتش مختلفتان كاربون حاملة مثل و اتش
+
+325
+00:29:59,840 --> 00:30:04,280
+مختلفتان المثل والمثل على جهة واحدة اذا هذا المركب
+
+326
+00:30:04,280 --> 00:30:09,760
+سيس لاحظوا هنا صار عندي sin addition ادى لتكون
+
+327
+00:30:09,760 --> 00:30:15,460
+المركب الـSYS في المثال السابق صار عندي sin
+
+328
+00:30:15,460 --> 00:30:22,670
+additionما اداش لأشي ف ال sim addition دائما موجود
+
+329
+00:30:22,670 --> 00:30:26,590
+يؤدي ل sis او trans او مايكونش موجود هذا بيعتمد
+
+330
+00:30:26,590 --> 00:30:32,790
+على طبيعة المجموعات اللي موجودة وين على الalkene
+
+331
+00:30:32,790 --> 00:30:39,270
+هذا بالنسبة للجزء الأول اللي هو إضافة الهيدروجين
+
+332
+00:30:39,270 --> 00:30:45,400
+لاحظوا يمكن بيظل عندى كلمةموجودة في العنوان و لازم
+
+333
+00:30:45,400 --> 00:30:52,060
+نجف عندها سمى العملية reduction of alkenes هو ال
+
+334
+00:30:52,060 --> 00:31:05,760
+alkene هنا، شو صار؟ ال alkene صار ال ال ال ال ال
+
+335
+00:31:05,760 --> 00:31:05,840
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+336
+00:31:05,840 --> 00:31:05,840
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+337
+00:31:05,840 --> 00:31:05,920
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+338
+00:31:05,920 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+339
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+340
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+341
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+342
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+343
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+344
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+345
+00:31:06,060 --> 00:31:10,590
+ال الالان احنا في ال organ ال chemistry في عندنا
+
+346
+00:31:10,590 --> 00:31:15,270
+قاعدة لما المركبات بتتحول من عائلة لعائلة لعائلة
+
+347
+00:31:15,270 --> 00:31:19,450
+لعائلة إذا تحولت باتجاه معين بقول هذه العملية
+
+348
+00:31:19,450 --> 00:31:24,430
+oxidation وإذا تحولت باتجاه آخر بقول هذه العملية
+
+349
+00:31:24,430 --> 00:31:31,090
+reduction فانا لو بدأ أعطيكم مختصر لهذا الأمر بقول
+
+350
+00:31:31,090 --> 00:31:40,850
+أبسط الأشياء ال alkanesتمام بعدها ال الكيلز بعد
+
+351
+00:31:40,850 --> 00:31:46,030
+هيك ربما عند ال alcohols ال RCH2OH
+
+352
+00:31:46,030 --> 00:31:52,350
+بعد هيك في عندك ال ketones و ال aldehydes اللي
+
+353
+00:31:52,350 --> 00:31:59,130
+فيهم C double bond O بعدهم الأحمار C double bond O
+
+354
+00:31:59,130 --> 00:32:06,780
+OH و أعلى مرتبة في الأكسدةتاني اكسيد الكربون اللى
+
+355
+00:32:06,780 --> 00:32:11,420
+متصل باربع روابط اكسجين الان اذا اتحولنا من الكن
+
+356
+00:32:11,420 --> 00:32:16,880
+لالكين فالعملية اكسدة من الكن لالكاي بعد شوية كمان
+
+357
+00:32:16,880 --> 00:32:22,320
+اكسدة لالكهول اكسدة لالديهايد اكسدة لاحظوا انا
+
+358
+00:32:22,320 --> 00:32:26,620
+عندى رابطة احدية مع الاكسجين هنا رابطتين في
+
+359
+00:32:26,620 --> 00:32:31,110
+الكيتون هناتلاتة للي بدهم يفهموا الأكسدا حتى من
+
+360
+00:32:31,110 --> 00:32:37,410
+ناحية ال Oxygen هنا أربعة الآن إذا مشينا بالعكس
+
+361
+00:32:37,410 --> 00:32:42,370
+بنقول العملية reduction عشان هيك لما ندرس الكيميا
+
+362
+00:32:42,370 --> 00:32:46,190
+بعد شوية نحول الكحول لالديهايد أو كيتون شو هنسمي
+
+363
+00:32:46,190 --> 00:32:50,870
+العملية؟ أكسدا يعني لما ندرس شapter ال alcohol و
+
+364
+00:32:50,870 --> 00:32:55,170
+بنقول alcohol اتحول لالديهايد أو كيتون هنسمي
+
+365
+00:32:55,170 --> 00:33:02,560
+العملية أكسدا كيتونرجع لالكهن Reduction الكن صار
+
+366
+00:33:02,560 --> 00:33:09,140
+الكن Oxidation الكن رجع ل الكن Reduction واضح؟
+
+367
+00:33:09,140 --> 00:33:17,560
+فضمن هالسلسلة بنقدر نفهم .. ضمن هالسلسلة بنقدر
+
+368
+00:33:17,560 --> 00:33:22,860
+نفهم اللي احنا بنعنيه بالأكسدة والاختزال هذه كلها
+
+369
+00:33:22,860 --> 00:33:28,020
+أمثلة بتوضح كيف ضفنا ال hydrogenالان التفاعل
+
+370
+00:33:28,020 --> 00:33:33,440
+التاني إضافة لبروم مرة تانية لبروم Symmetric ولا
+
+371
+00:33:33,440 --> 00:33:39,180
+Unsymmetric؟ Symmetric Reagent لكن بالتجربة ..
+
+372
+00:33:39,180 --> 00:33:43,400
+بالدليل التجريبي مش كل شيء بالفصل فيه اللي لاحظوا
+
+373
+00:33:43,400 --> 00:33:48,660
+أن لبروم لما بيضيف .. بيضيف Anti addition من جهتين
+
+374
+00:33:48,660 --> 00:33:54,320
+متعاكستينيعني ما بيضيفش من نفس الجهة، لاحظوا هاي
+
+375
+00:33:54,320 --> 00:33:59,680
+الكين ضفنا عليه برومين أعطانا sin ولا anti
+
+376
+00:33:59,680 --> 00:34:04,700
+addition؟ Anti addition إذا الهيدروجين كأول
+
+377
+00:34:04,700 --> 00:34:09,360
+symmetric reagent ضاف من جهة واحدة لبرومين، يعني
+
+378
+00:34:09,360 --> 00:34:12,460
+لو تخيلت أن هذا جزء لبرومين و جاي يضيف على double
+
+379
+00:34:12,460 --> 00:34:19,650
+bond هنابيضيف من جهتين مختلفتين الآن مرة تانية
+
+380
+00:34:19,650 --> 00:34:25,570
+لبرومين دائما Anti-addition يعطي cis أو trans لأ
+
+381
+00:34:25,570 --> 00:34:32,610
+حسب الجزاء اللي موجود عنده حسب المجموعات اللي
+
+382
+00:34:32,610 --> 00:34:36,310
+موجودة على الجزاء عنده ممكن يعطي cis ممكن يعطي
+
+383
+00:34:36,310 --> 00:34:41,190
+trans ممكن مايعطيش إشي واضح؟ يعني في حالة زي هذه
+
+384
+00:34:41,190 --> 00:34:46,260
+لما بيضيف لو افترضنا ان هدولة كلهم Hydrogensلأ
+
+385
+00:34:46,260 --> 00:34:54,520
+طبعا لأ اكيد اكيد لأ لو افترضنا ان البروميل بيضيف
+
+386
+00:34:54,520 --> 00:35:00,060
+على الهيدروجين كل هدول الذرات الأربعة ما زالوا
+
+387
+00:35:00,060 --> 00:35:06,320
+هيدروجين الان لاحظوا زملتكم على طول غلطة، غلطة
+
+388
+00:35:06,320 --> 00:35:14,060
+كبيرة جد البحر ليش؟لأنه قلنا ظاهرة الـcis والترانس
+
+389
+00:35:14,060 --> 00:35:18,780
+أساسا كظاهرة يا بتنوجد حوالين ال double bond يا
+
+390
+00:35:18,780 --> 00:35:24,500
+حوالين ال single bond في الحلقة في منها؟ لأ وحكينا
+
+391
+00:35:24,500 --> 00:35:29,280
+أن هذا طالما single bond في حالة دوران دائم أبدت
+
+392
+00:35:29,280 --> 00:35:36,560
+هو في لحظة الإضافة بدى زي هيك لكن بعد ثانية بلوف
+
+393
+00:35:38,450 --> 00:35:40,690
+مافيش فيه كل ظاهرة الـcis و الـtrans الرابطة
+
+394
+00:35:40,690 --> 00:35:44,970
+الوحيدية فيها ظاهرة الـcis و الـtrans لا مافيش
+
+395
+00:35:44,970 --> 00:35:49,070
+فيها ظاهرة الـcis و الـtrans لكن الإضافة في لحظة
+
+396
+00:35:49,070 --> 00:35:54,270
+الإضافة كيف ضافوا إن فكوا الظارتين عن بعض إجت
+
+397
+00:35:54,270 --> 00:35:56,710
+واحدة من الأمام واحدة من الخلف هي معنى Anti
+
+398
+00:35:56,710 --> 00:36:02,190
+-addition إذا لو واحدة بتفكر في أي وقت بده يظهر
+
+399
+00:36:02,190 --> 00:36:07,720
+عند الـcis و الـtrans في الحلقاتفي الحلقات لأن
+
+400
+00:36:07,720 --> 00:36:14,000
+الحلقات هم الوحيدين اللي فيهم رابطة أحدية و فيهم
+
+401
+00:36:14,000 --> 00:36:18,360
+دائرة ال cis و ال trans انما في المناطق اللي زي
+
+402
+00:36:18,360 --> 00:36:23,460
+هذه مابطلعش عنده cis و trans بطلع غالبا في الحلقات
+
+403
+00:36:25,730 --> 00:36:30,370
+بدون ما نفصل ليش تم هذا الكلام تم بالتأكيد على
+
+404
+00:36:30,370 --> 00:36:33,970
+خطوطين يعني ضافة ذرة بروم وبعدين كملت البروم الجهة
+
+405
+00:36:33,970 --> 00:36:39,570
+التانية مش كثير مهتم بهذا ال ميكانيزم لكن خليني
+
+406
+00:36:39,570 --> 00:36:43,090
+أرجع مثلا على هذا المثال اللي ضيفنا فيه الهيدروجين
+
+407
+00:36:43,090 --> 00:36:49,050
+لو كنا جايبينه في الامتحان وقلنالكم أكمل وهينضيفنا
+
+408
+00:36:49,050 --> 00:36:53,390
+الهيدروجين بهذا الاتجاه وبالاتجاه التاني قلنا لكم
+
+409
+00:36:54,740 --> 00:37:00,080
+ضيفنا الـ PR 2 كيف
+
+410
+00:37:00,080 --> 00:37:06,760
+فجأة هكمل؟ هرسم
+
+411
+00:37:06,760 --> 00:37:13,500
+نفس الحلقة هذه بعدين
+
+412
+00:37:13,500 --> 00:37:24,380
+أخلي مجموعة مثل لفوق و مجموعة لتحت و ال PR لفوق
+
+413
+00:37:30,400 --> 00:37:38,660
+هذه لفوق وهذه PR وين بتصير؟ لتحت ال .. واضح؟ ربما
+
+414
+00:37:38,660 --> 00:37:45,240
+لو كانت الحلقة مرسومة بهذا الشكل يكون أسهل لكم نفس
+
+415
+00:37:45,240 --> 00:37:49,240
+الحلقة كأنه بتكون .. تتخيلوا بهذا الشكل كأنه عندكم
+
+416
+00:37:49,240 --> 00:37:59,400
+CH3 و CH3 بيصيروا عكس بعض و PR عكس بعض انتي ولا
+
+417
+00:37:59,400 --> 00:38:07,680
+لأ؟الان هدولة SES ولا TRANS هذا المُركّب TRANS هاي
+
+418
+00:38:07,680 --> 00:38:15,740
+ال PR و PR عكس بعض و مثل و مثل لأ هو انا .. بدل ..
+
+419
+00:38:15,740 --> 00:38:19,740
+لو النتج كان H2و بتكون تخلوا مجمعتين ال مثل ع جهة
+
+420
+00:38:19,740 --> 00:38:23,340
+واحدة مجمعتين ال H ع جهة واحدة بتكون تعملوا SEND
+
+421
+00:38:23,340 --> 00:38:26,500
+ADDITION واضح؟
+
+422
+00:38:33,560 --> 00:38:40,620
+لأ لأ لأ ال CH3 ال CH3 لو كان عندنا model هذا
+
+423
+00:38:40,620 --> 00:38:45,620
+المركب بيكونوا في نفس مستوى الحلقة مش عكس بعض
+
+424
+00:38:45,620 --> 00:38:51,580
+تنسوش أحيانا في معلومات مبنية على بعض لما أخدنا
+
+425
+00:38:51,580 --> 00:38:58,300
+الشكل الهندسي حوالين ال double bondقلنا ان حوالين
+
+426
+00:38:58,300 --> 00:39:03,900
+ال double bond الشكل بلانر بزاوية 120 يعني هذه
+
+427
+00:39:03,900 --> 00:39:11,240
+الزاوية 120 وهذه 120 وهذه 120 هدولة في مستوى واحد
+
+428
+00:39:11,240 --> 00:39:15,820
+لو انا بدي افرجيكم بشكل عام كيف منظرهم باخد ملزمة
+
+429
+00:39:15,820 --> 00:39:21,850
+من هنازي هيك بتكون تتخيلوا الحلقة لما بيكون عند
+
+430
+00:39:21,850 --> 00:39:26,490
+هنا double bond لو تخيلتوا هاي مجمعتين ال CH3 هدول
+
+431
+00:39:26,490 --> 00:39:31,170
+ناخدهم
+
+432
+00:39:31,170 --> 00:39:36,010
+باللون الأسمر بيكونوا في نفس مستوى الحلقة ليش لأن
+
+433
+00:39:36,010 --> 00:39:40,190
+هنا في عند double bond لما هنا بيكون عند double
+
+434
+00:39:40,190 --> 00:39:46,590
+bond هدولة في نفس المستوى تبع الحلقةواضح؟ هدولة في
+
+435
+00:39:46,590 --> 00:39:51,510
+نفس المستوى تبع الحلقة لما بيجي البروم اضيف بيخلي
+
+436
+00:39:51,510 --> 00:39:55,570
+واحدة لتحت واحدة لفوق و البروم بنعكس لو اجي
+
+437
+00:39:55,570 --> 00:40:01,090
+الهيدروجين اضيف بيخلي تنتين لتحت و الهيدروجين بيجي
+
+438
+00:40:01,090 --> 00:40:07,770
+لفوق طبعا ما عدا ما عدا ال double bond بيكون انا
+
+439
+00:40:07,770 --> 00:40:13,050
+في عندى كام ذرة هيدروجين في الجزء؟ تنتينهنا في
+
+440
+00:40:13,050 --> 00:40:15,550
+واحدة لفوق واحدة لتحت هنا واحدة لفوق واحدة لتحت
+
+441
+00:40:15,550 --> 00:40:20,090
+هنا واحدة لفوق واحدة لتحت لكن هذه وهذه في مستوى
+
+442
+00:40:20,090 --> 00:40:25,070
+الجزء هذه وهذه في مستوى الجزء شوية بنحس ان الموضوع
+
+443
+00:40:25,070 --> 00:40:38,210
+صعب مافيش مشكلة بالمرة ناخد دقيقة و نعمل لكم model
+
+444
+00:40:38,210 --> 00:40:39,970
+هتفهموا
+
+445
+00:40:42,640 --> 00:40:47,920
+هتفهموا الموضوع بشكل جيد عشان هي احنا بنقول ال
+
+446
+00:40:47,920 --> 00:40:56,080
+models مرات كتير بتساعد لاحظوا
+
+447
+00:40:56,080 --> 00:41:00,580
+هاي عندى حلقة خماسية طبعا هي قولنا مش planner شوية
+
+448
+00:41:00,580 --> 00:41:06,040
+فيها زى ال envelope مش مشكلة كبيرة هذه الان لما
+
+449
+00:41:06,040 --> 00:41:13,610
+بدي اجي اعمل لما بدي اجي اعمل double bondعلى جهة
+
+450
+00:41:13,610 --> 00:41:17,850
+من الجهات هانا بدى اعمل double bond واحدة فيها
+
+451
+00:41:17,850 --> 00:41:28,510
+هينعمل ال double bond تمام شو تبقى عندى مجموعة CH3
+
+452
+00:41:28,510 --> 00:41:35,470
+ومجموعة تانية CH3 هين بيانتهم باللون الأصمر الان
+
+453
+00:41:35,470 --> 00:41:40,310
+لاحظوا هدول المجمعتين في مستوى الحلقة ولا لأ في
+
+454
+00:41:40,310 --> 00:41:46,380
+مستوى الحلقةالان باقي الكربونات ايش عليهم؟ كل
+
+455
+00:41:46,380 --> 00:41:50,260
+واحدة تنتين CH2 العلم الجديد اللي اتعلمناه واحدة
+
+456
+00:41:50,260 --> 00:41:58,100
+لفوق واحدة لتحت هنا عند تنتين CH2 لفوق و لتحت هنا
+
+457
+00:41:58,100 --> 00:42:02,440
+في عند تنتين
+
+458
+00:42:02,440 --> 00:42:03,260
+هيدروجين
+
+459
+00:42:05,710 --> 00:42:09,730
+لا فوق ولا تحت هذا هو الجزء اللي موجود عندكم الان
+
+460
+00:42:09,730 --> 00:42:14,090
+لاحظوا ان هدولة في مستوى واحد carbon carbon carbon
+
+461
+00:42:14,090 --> 00:42:19,550
+carbon carbon carbon واضح فبناء على ذلك هدولة في
+
+462
+00:42:19,550 --> 00:42:23,970
+البداية كان السؤال هم أساسا مثل ال sex ولا ال
+
+463
+00:42:23,970 --> 00:42:29,470
+transلأ في الحلقة بيكونوا على نفس المستوى مافيش
+
+464
+00:42:29,470 --> 00:42:32,930
+فيه sis و trans ال sis و ال trans انه في فوق و تحت
+
+465
+00:42:32,930 --> 00:42:35,810
+حوالين ال single bond في الحلقة مش حوالين ال
+
+466
+00:42:35,810 --> 00:42:41,110
+double bond في الحلقة انما هدولة جايين على جهة
+
+467
+00:42:41,110 --> 00:42:46,030
+واحدة اللي محتمال يكونوا فوق او تحت الحلقة لأ لما
+
+468
+00:42:46,030 --> 00:42:51,890
+انا بعمل الاضافة خليني افترض ان انا بدي اضيف لبروم
+
+469
+00:42:51,890 --> 00:42:59,330
+و خليني اعطي لبروممجمعتين زرق او للهيدروجين
+
+470
+00:42:59,330 --> 00:43:05,670
+ونوضحهم بروابط كبيرة قلنا
+
+471
+00:43:05,670 --> 00:43:12,550
+عملية الإضافة هي عملية ايش؟ كسر رابطة زوجية الان
+
+472
+00:43:12,550 --> 00:43:20,410
+هي نكسرتها ونحط بدالها two new sigma bonds الان لو
+
+473
+00:43:20,410 --> 00:43:24,270
+كنت بضيف الهيدروجين هدول هيصيروا على جهة واحدة
+
+474
+00:43:25,230 --> 00:43:30,450
+والمثل على جهة واحدة هذه هي الـ Sin Addition اللي
+
+475
+00:43:30,450 --> 00:43:38,690
+قدّت لـ SIS مرة تانية لو رجعت و كنت بدأ أضيف لبروم
+
+476
+00:43:38,690 --> 00:43:42,550
+وقتها
+
+477
+00:43:42,550 --> 00:43:49,510
+لما بدأ أكسر الرابطة بدّو هدولة يتحركوا بهذا الشكل
+
+478
+00:43:56,030 --> 00:44:00,630
+واضح الفكرة؟ انا كسرت الروابط لأنهم مربطين، بس هم
+
+479
+00:44:00,630 --> 00:44:06,710
+في النهاية فراغات يعني، بالتالي سهل يتحركوا، واضح؟
+
+480
+00:44:06,710 --> 00:44:10,850
+يعني انا عشان اعملكوا الشكل اضطريتوا ان تشوفوني
+
+481
+00:44:10,850 --> 00:44:14,870
+بكسر الرابطة، لكن في كل الأحوال، بدكم تكونوا
+
+482
+00:44:14,870 --> 00:44:19,390
+فاهمين من الأساس انتوا، لاحظوا الكيميا ما هي كل
+
+483
+00:44:19,390 --> 00:44:24,630
+كلمة مبنية على الثانيةلحظة ما كنا بنحكي عن تعريف
+
+484
+00:44:24,630 --> 00:44:31,110
+الرابطة إيش قولنا هي الرابطة؟ هي مسافة في الفراغ
+
+485
+00:44:31,110 --> 00:44:37,990
+يعني هذه وهذه بالظبط
+
+486
+00:44:37,990 --> 00:44:48,790
+برات
+
+487
+00:44:48,790 --> 00:44:55,120
+..يعني هذه المفاهيم تعبير عن خبرة في الكيميا الآن
+
+488
+00:44:55,120 --> 00:45:01,480
+هذه و هذه مسافات في الفراغ واضح ليست روابط جامدة
+
+489
+00:45:01,480 --> 00:45:07,380
+وبالتالي انا لما اجيب برم من جهتين وهذه مسافة
+
+490
+00:45:07,380 --> 00:45:11,280
+بالفراغ وهذه مسافة بالفراغ هتيجي برم من فوق هذه
+
+491
+00:45:11,280 --> 00:45:16,750
+تنزل لتحت هتيجي برم من تحت هذه تطلع لفوقواضح؟ لما
+
+492
+00:45:16,750 --> 00:45:20,750
+اجيب الهيدروجين حيجي الهيدروجين و الهيدروجين بهذا
+
+493
+00:45:20,750 --> 00:45:25,430
+الشكل ممسكين على سطح الميتال هذه و هذه هينزلوا
+
+494
+00:45:25,430 --> 00:45:31,050
+لتحت الان لما انا بشتغل بروابط صلبة في الهيدروجين
+
+495
+00:45:31,050 --> 00:45:37,790
+كان سهل ان اوضحلكوا هذا بالموديل صح؟في البروم لما
+
+496
+00:45:37,790 --> 00:45:41,810
+كسرت الرابطة اضطريت ان ابين كاني بكس الرابطة لكن
+
+497
+00:45:41,810 --> 00:45:47,050
+هي حقيقة لما تكونوا متخيلين مسافة بالفراغ ما كسرت
+
+498
+00:45:47,050 --> 00:45:52,710
+رابطة فقط هذه اتحركت لأعلى اجت البروم من جهة وهنا
+
+499
+00:45:52,710 --> 00:45:57,850
+اجت البروم من جهة تانية حوالين ال single bond ممكن
+
+500
+00:45:57,850 --> 00:46:01,590
+sis و trans طالما مختلفتان مختلفتان هذا المركب
+
+501
+00:46:01,590 --> 00:46:06,950
+اللي طلع عندي ايشtrans واضح؟ احنا في كل الأحوال
+
+502
+00:46:06,950 --> 00:46:13,170
+اللي بنركز عليه أنه إضافة الـhydrogen سن إضافة
+
+503
+00:46:13,170 --> 00:46:17,910
+البروم أنت الآن النتيجة سلسة الـtrans تعتمد على
+
+504
+00:46:17,910 --> 00:46:23,570
+طبيعة الجزء هل الجزء جزء حلقي جزء غير حلقي هل
+
+505
+00:46:23,570 --> 00:46:29,630
+المجموعات اللي فيه إيش نوعهاواضح؟ يعني خلّيني
+
+506
+00:46:29,630 --> 00:46:34,290
+بثانية أستأذنكم وأستاذن الأستاذ كمان لأننا خلّصنا
+
+507
+00:46:34,290 --> 00:46:41,010
+لو كنا بنضيف هيدروجين على هذا الجزء اللي في الأساس
+
+508
+00:46:41,010 --> 00:46:47,970
+كان عليه تنتين هيدروجين يعني هذا الجزء كان بهذا
+
+509
+00:46:47,970 --> 00:46:54,730
+الشكل وكنا جاعدين بنضيف عليههذه الـ double bundle
+
+510
+00:46:54,730 --> 00:47:01,030
+في الحلقة وكنا قاعدين بنضيف عليها هيدروجينز هيصير
+
+511
+00:47:01,030 --> 00:47:07,470
+H لتحت وهذه لتحت وH جديدة لفوق وH جديدة لفوق طلعت
+
+512
+00:47:07,470 --> 00:47:11,730
+كل ظاهرة الـ cis والترانس؟ لأ تعتمد على ال
+
+513
+00:47:11,730 --> 00:47:15,350
+substituents يعني لما كانوا المجموعتين مثل طلع
+
+514
+00:47:15,350 --> 00:47:20,140
+المركب cis لكن لو افترضنا المجموعتين Hمافيش كل
+
+515
+00:47:20,140 --> 00:47:23,380
+الظاهرة بس في كل الأحوال انا لما ضيفت ال hydrogen
+
+516
+00:47:23,380 --> 00:47:28,740
+من جهة واحدة لما ضيفت ال brom عرفنا ايش معنى سنه
+
+517
+00:47:28,740 --> 00:47:32,920
+addition و لذلك عملية الإضافة بسميها mood of
+
+518
+00:47:32,920 --> 00:47:37,300
+addition ال product depends on the nature of the
+
+519
+00:47:37,300 --> 00:47:41,240
+molecule على طبيعة الجزيء على المجموعات اللي
+
+520
+00:47:41,240 --> 00:47:45,760
+موجودة أساسا على أطراف الكربون هل الجزيء حلقة مش
+
+521
+00:47:45,760 --> 00:47:49,780
+حلقة ما إلى ذلكو منكتفي بهذا القدر
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/49RclsCO0NU_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/49RclsCO0NU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8cc8eef32c4dc86897305b0e2252207c108b83cb
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/49RclsCO0NU_raw.srt
@@ -0,0 +1,2264 @@
+1
+00:00:00,000 --> 00:00:02,680
+موسيقى
+
+2
+00:00:12,150 --> 00:00:15,710
+هنكمل ان شاء الله على ال section الماضي ال section
+
+3
+00:00:15,710 --> 00:00:20,270
+الماضي بدأنا بال natural logarithmic function و
+
+4
+00:00:20,270 --> 00:00:23,650
+اعطينا تعريف الله و شرحنا الجزء النظري و اعطينا
+
+5
+00:00:23,650 --> 00:00:28,450
+بعض الأمثلة وصلنا الى مجموعة أمثلة اللي هي
+
+6
+00:00:28,450 --> 00:00:31,650
+derivatives لل functions تحتوي على ال natural
+
+7
+00:00:31,650 --> 00:00:36,270
+logarithm وبعدين دخلنا في آخر مثال اللي هو مجموعة
+
+8
+00:00:36,270 --> 00:00:42,200
+أمثلة التكاملوكملنا الاربع دوا المثلثية اللى كنا
+
+9
+00:00:42,200 --> 00:00:47,920
+مانقدرش نكملها في calculus A وهي تكامل tan X و
+
+10
+00:00:47,920 --> 00:00:55,560
+cotan X وsecant X و cosecant X اليوم نكمل ثابع
+
+11
+00:00:55,560 --> 00:01:01,180
+لنفس الأمثلة تبعت المرة الماضية هدول الأربع دوا
+
+12
+00:01:01,180 --> 00:01:05,740
+المثلثية سمنها مثال رقم واحداذا احنا الان بروح
+
+13
+00:01:05,740 --> 00:01:11,560
+لمثال رقم اتنين ان شاء الله تعالى يبقى المثال رقم
+
+14
+00:01:11,560 --> 00:01:20,680
+اتنين بيقوللي تكامل نين بدنا تكامل لمين لل X تكيب
+
+15
+00:01:20,680 --> 00:01:28,240
+على اتنين X أص أربعة زائد تلاتة كله بالنسبة الى DX
+
+16
+00:01:30,770 --> 00:01:37,110
+لو جينا نظرنا لهذا المثال ونشوف كيف بدنا نحل هذا
+
+17
+00:01:37,110 --> 00:01:42,050
+المثال باستخدام القاعدة اللي في جزء النظر ياخدناها
+
+18
+00:01:42,050 --> 00:01:51,250
+طبعا المرة الماضية أخدنا تكامل 1 على x dx يساويلن
+
+19
+00:01:51,250 --> 00:01:56,990
+absolute value ل X زي الconstancy وقلنا in general
+
+20
+00:01:56,990 --> 00:02:04,740
+روحنا عمّمناها وقلنا لو كان عندي تكاملللـ f prime
+
+21
+00:02:04,740 --> 00:02:11,200
+of x على ال f of x dx يبقى الجواب لين absolute
+
+22
+00:02:11,200 --> 00:02:18,040
+value لل f of x plus constant c طبعا يبقى احنا كل
+
+23
+00:02:18,040 --> 00:02:23,760
+مسألة عندنا بلزم فيها شغلة زي هيك بدنا نحورها بها
+
+24
+00:02:23,760 --> 00:02:27,880
+تصير زيها وبالتالي يصير الجواب عندنا ممكن لأ لو
+
+25
+00:02:27,880 --> 00:02:33,850
+نظرنا لكل من البسط والمقاب في المسألة بتابعتنايبقى
+
+26
+00:02:33,850 --> 00:02:40,490
+الفرق ما بين هذه و هذه انه مشتقتي المقام تمانية X
+
+27
+00:02:40,490 --> 00:02:46,010
+كيب صح ولا لأ؟ لكن اللي فوق عندي جداش X كيب اذا
+
+28
+00:02:46,010 --> 00:02:50,710
+بدأ اضرب في هذا المقدار الثابت و اقسم علي انه كان
+
+29
+00:02:50,710 --> 00:02:54,710
+ضرب في جداش وبالتالي بصير ماعندي مشكلة في هذه
+
+30
+00:02:54,710 --> 00:03:00,670
+الحالةيبقى هذه المسألة الحل تبعها بده يساوي هو
+
+31
+00:03:00,670 --> 00:03:06,790
+تكامل هيتمن برا التكامل والتمانية هدخلها جوا x
+
+32
+00:03:06,790 --> 00:03:14,810
+تكيب على اتنين x أص أربعة زائد تلاتة في ال dx الان
+
+33
+00:03:14,810 --> 00:03:18,630
+لو نظرت لكل من ال bus والمقام بلاحظ ان ال bus هو
+
+34
+00:03:18,630 --> 00:03:24,670
+مشتق اتنينيبقى هذا التمن اللي برا وبناء على هذه
+
+35
+00:03:24,670 --> 00:03:30,330
+القاعدة لن absolute value للي اتنين X أُس أربعة
+
+36
+00:03:30,330 --> 00:03:38,930
+زائد تلاتة زائد constant C السؤال هو طب لو كتبتش
+
+37
+00:03:38,930 --> 00:03:42,830
+ال absolute value هذه بدون absolute كلامي صح ولا
+
+38
+00:03:42,830 --> 00:03:49,180
+غلط؟صحيح لأن هذا المقدار لا يأخذ إلا قيمة منموجة
+
+39
+00:03:49,180 --> 00:03:52,640
+بقى يبقى إذا المقدار اللي بياخدش إلا قيمة منموجة
+
+40
+00:03:52,640 --> 00:03:55,740
+بقى كتبت ال absolute و الله شيلت ال absolute
+
+41
+00:03:55,740 --> 00:04:01,340
+لإثنين أردسين بس إذا لإحتمالين وردات أو كان سالب
+
+42
+00:04:01,340 --> 00:04:05,840
+إجباري بدك تحط ال absolute value ولذلك بيقول كتبها
+
+43
+00:04:05,840 --> 00:04:10,620
+دائما و أبدا و بلاش تدقيق ماشي يبقى بتكتب دائما و
+
+44
+00:04:10,620 --> 00:04:15,300
+أبدا absolute valueناخد كمان مثال اللي هو تكامل
+
+45
+00:04:15,300 --> 00:04:23,940
+لمن؟ لل X زائد تلاتة على X تربية زائد ستة X زائد
+
+46
+00:04:23,940 --> 00:04:29,840
+خمسة كله في DX لو
+
+47
+00:04:29,840 --> 00:04:34,800
+قلنالكوا بدنا نحلل المقام إلى حصل ضرب قوسين طبعا
+
+48
+00:04:34,800 --> 00:04:39,360
+ممكن لكن هل هذا التحليل له فائدة عندي في أتناء
+
+49
+00:04:39,360 --> 00:04:44,180
+الحل؟في ذا في اختصارات لكن لما تقول اكس زائد واحد
+
+50
+00:04:44,180 --> 00:04:48,020
+في اكس زائد خمسة فيش اختصارات يمكن تبصير هذا لا
+
+51
+00:04:48,020 --> 00:04:53,420
+قيمة له لإذا نفكر بطريقة تانية هل ال bus تفاضل
+
+52
+00:04:53,420 --> 00:05:01,820
+المقام طبعا لأ لكن لو كانت هذه اتنين اكس زائد ستة
+
+53
+00:05:01,820 --> 00:05:08,470
+لكانت هي منمش تقة اللي في الجزء الصفلي مفهوم يبقى
+
+54
+00:05:08,470 --> 00:05:12,910
+اضرب في اتنين و اقسم على اتنين او اضرب نصف في
+
+55
+00:05:12,910 --> 00:05:18,070
+اتنين يبقى بناء عليه هذا بدي يسوى هاي النص برا وهي
+
+56
+00:05:18,070 --> 00:05:25,230
+تكامل اتنين X زائد ستة على X تربية زائد ستة X زائد
+
+57
+00:05:25,230 --> 00:05:32,930
+خمسة كله بالنسبة الى DX يبقى هاي النص اللي براوهذا
+
+58
+00:05:32,930 --> 00:05:41,370
+لين absolute value لل X ثربية زيد 6X زيد 5 زيد
+
+59
+00:05:41,370 --> 00:05:48,850
+constant C مثال أربعة بدنا تكامل
+
+60
+00:06:03,590 --> 00:06:07,570
+طبعا النظر في هذا السؤال لبس تفضل مقام ولا حتى
+
+61
+00:06:07,570 --> 00:06:13,130
+جريب منه كل واحد من البلد لكن في شغل مش عاجبان
+
+62
+00:06:13,130 --> 00:06:18,230
+هيكم صعب المسألة أو وضعها مش طبيعي زي مين؟زي
+
+63
+00:06:18,230 --> 00:06:22,710
+الزاوية كوصين تربية X كوصين تربية ثيتا بيقول كوصين
+
+64
+00:06:22,710 --> 00:06:26,490
+تربية تمانية زائد لن X إذا الشغل اللي مكلك على
+
+65
+00:06:26,490 --> 00:06:33,530
+المثل هذه من عوضة ناهيك إنه هذه لو اشتقت بتعطيك من
+
+66
+00:06:33,530 --> 00:06:38,410
+الجزء اللي برا عندنا هذا كله تمام؟ إذا بروح بقول
+
+67
+00:06:38,410 --> 00:06:47,880
+put مثلا ثيتا تساوي تمانية زائد لن Xكل هذا المشكلة
+
+68
+00:06:47,880 --> 00:06:52,760
+بشكل المثال يجب ان اضافه بـθيتا نشتق يبقى دي ثيتا
+
+69
+00:06:52,760 --> 00:06:57,540
+بدي الساعة مشتقة الكون الصينت بزيرو مشتقة لن ال X
+
+70
+00:06:57,540 --> 00:07:04,120
+بواحد على X DX اذا بقدر اشيل الواحد على X DX هذه
+
+71
+00:07:04,120 --> 00:07:10,660
+كلها و اكتب هذا الهميةDθ يبقى قلة المسألة الى
+
+72
+00:07:10,660 --> 00:07:22,540
+integration لDθ على cosine تربية ثيتا يساوي نقدر
+
+73
+00:07:22,540 --> 00:07:27,700
+نكمل هيك؟ طب ممكن احطها في شكل اخر باستخدام حساب
+
+74
+00:07:27,700 --> 00:07:30,700
+المثلثات ال cosine مقنوب مين؟
+
+75
+00:07:38,900 --> 00:07:45,770
+تفاضل ال 10 ثيتا بقداش؟ تفاضل ال 10سكتر بيعة ان
+
+76
+00:07:45,770 --> 00:07:52,310
+انت كامل سكتر بيعة بيعطيك تان ثيتا زائد كونستان سي
+
+77
+00:07:52,310 --> 00:07:58,990
+هذا الكلام بده يساوي تان بدنا بالمتغير X بده تنتهي
+
+78
+00:07:58,990 --> 00:08:03,830
+بالمتغير X يبقى بده اشيل ثيتا و احط مثلي تمانية
+
+79
+00:08:03,830 --> 00:08:11,170
+زائد لن ال X يبقى تمانية زائد لن ال X زائد كونستان
+
+80
+00:08:11,170 --> 00:08:18,530
+سيمرة جيبنا هذا السؤال في إحدى الامتحانات السابقة
+
+81
+00:08:18,530 --> 00:08:25,750
+طيب هذا سؤال أربعة سؤال خمسة بدنا تكامل من اتنين
+
+82
+00:08:25,750 --> 00:08:35,310
+لغاية ستاشر لدي X على اتنين X الجذر التربيهي لن ال
+
+83
+00:08:35,310 --> 00:08:40,090
+X لو جيك هذا السؤال في الامتحان بصيحة تقول يا سيطر
+
+84
+00:08:40,090 --> 00:08:46,800
+تسطرلن و تحت الجدر و برا مضوج يعني شكله غير شكل بس
+
+85
+00:08:46,800 --> 00:08:52,740
+بكل بساطة لايجي استخدام عجلك مش كاملا حتى بس شوية
+
+86
+00:08:52,740 --> 00:08:57,180
+منه، بتلاقي سؤال بسيط و بسيط خالص كمانيبقى باجي
+
+87
+00:08:57,180 --> 00:09:01,640
+هنا لمين؟ مين اللي صعب المثال؟ لن ال X لكن لو كان
+
+88
+00:09:01,640 --> 00:09:05,420
+جدر ال X بتلاقيها سهلة لكن لن ال X هو اللي صعب
+
+89
+00:09:05,420 --> 00:09:12,560
+المثال إذا بقدر أحط ال W مثلا تساوي لن ال X يبقى
+
+90
+00:09:12,560 --> 00:09:19,520
+DW بدي ساوي واحد على X DX إذا واحد على X DX هذه
+
+91
+00:09:19,520 --> 00:09:26,300
+بقدر أشيل و أكتب لها جدر XDW يبقى يا نص خليك برا و
+
+92
+00:09:26,300 --> 00:09:31,940
+اي تكامل و اي DW و اي الجدر اللي انه و اللي انه ال
+
+93
+00:09:31,940 --> 00:09:38,350
+X هي ال Wبقيت حدود التكامل الحدود التكامل اتنين
+
+94
+00:09:38,350 --> 00:09:42,770
+والست عشر هذه للمتغير X لكن المتغير انه اصبح مين
+
+95
+00:09:42,770 --> 00:09:50,130
+اذا بدي اشوف ماهي حدود التكامل المناظرة للحدود تبع
+
+96
+00:09:50,130 --> 00:09:50,710
+ال X
+
+97
+00:09:54,500 --> 00:09:59,500
+الان بده اشيل اكسه و احطه مكانه قداش 16 يبقى ال W
+
+98
+00:09:59,500 --> 00:10:06,920
+بده يساوي ال N 16 يبقى هنا ال N 16 و هنا ال N قداش
+
+99
+00:10:06,920 --> 00:10:13,760
+2 يبقى هذا الكلام بده يساوي نص تكامل هذا W أص نص
+
+100
+00:10:13,760 --> 00:10:20,280
+لو طلعته فوق بصير W أص نالب نص دي W 16 قداش هذه
+
+101
+00:10:20,280 --> 00:10:28,620
+يعنيأتنين أقصى أربعة صح ولا لا؟ إذا لن اتنين أقصى
+
+102
+00:10:28,620 --> 00:10:33,600
+أربعة تعني أربعة لن اتنين إذا هذه بقدر أكتبها
+
+103
+00:10:33,600 --> 00:10:39,960
+أربعة لن اتنين وهذه لن اتنينيعني التكامل بصير من
+
+104
+00:10:39,960 --> 00:10:44,340
+لن اتنين إلى أربعة لن اتنين اللي هو أربعة أمثاله
+
+105
+00:10:44,340 --> 00:10:50,380
+طيب هذا الكلام بيدرس ساوي نص وهذه W مضيف للأس واحد
+
+106
+00:10:50,380 --> 00:10:56,840
+وبنقسم على الأس الجديد على نصه حدود التكامل من لن
+
+107
+00:10:56,840 --> 00:11:02,180
+اتنين إلى أربعة لن اتنين النص مع النص اللي سهل
+
+108
+00:11:02,180 --> 00:11:09,560
+عليه وهذه W تعني جذري Wيبقى هذا الجذر التربية إلى
+
+109
+00:11:09,560 --> 00:11:17,500
+أربعة لن اتنين ناقص الجذر التربية إلى لن اتنين هذا
+
+110
+00:11:17,500 --> 00:11:21,660
+بيعطينا مين؟ بيعطينا اتنين الجذر التربية إلى لن
+
+111
+00:11:21,660 --> 00:11:27,100
+اتنين ناقص الجذر التربية إلى لن اتنين ويساوي الجذر
+
+112
+00:11:27,100 --> 00:11:31,680
+التربية إلى لن اتنين هذه الإجابة النهائية تبعت من؟
+
+113
+00:11:31,680 --> 00:11:40,540
+تبعت السؤال؟ تبعنا طب مثال رقم ستةبنتكامل لدي x
+
+114
+00:11:40,540 --> 00:11:48,700
+على جذر ال x زائد ال x برضه
+
+115
+00:11:48,700 --> 00:11:54,220
+لا البسطى فاض المقام ولا حتى جريب منه مش مبين لكن
+
+116
+00:11:54,220 --> 00:12:00,180
+فكر كيف بدنا نعمل مافيش بتقترح علينا نسمع لو واحد
+
+117
+00:12:00,180 --> 00:12:04,300
+عنده اقتراح جيد نستخدمه مشان نقدر نكامل هذه الدلة
+
+118
+00:12:05,510 --> 00:12:13,030
+أحد أسئلة الكتاب في التمرين نسمع
+
+119
+00:12:13,030 --> 00:12:16,050
+نفرض
+
+120
+00:12:16,050 --> 00:12:23,130
+الجدر كل ايه؟ يعني
+
+121
+00:12:23,130 --> 00:12:29,470
+ناخد الجدر X لحاله نفرضه يه؟ بصير عندك هذه U و هذه
+
+122
+00:12:29,470 --> 00:12:34,920
+U ترميةمظبوط؟ ولمّا نقول لما تربيعها بصير الـ U
+
+123
+00:12:34,920 --> 00:12:39,860
+تربيع التساويكس يبقى مشتقتها اتنين U دي U وجهة نظر
+
+124
+00:12:39,860 --> 00:12:44,700
+سليمة مية لمية صحية واحد قال ان عندي وجهة نظر أخرى
+
+125
+00:12:44,700 --> 00:12:49,240
+نضرب
+
+126
+00:12:49,240 --> 00:12:54,680
+في المرافق مش هيجيب ليه نتيجة والله أعلم يعنيجذر
+
+127
+00:12:54,680 --> 00:12:59,400
+ال X عامل مشترك؟ نعم جذر ال X عامل مشترك، ممكيز،
+
+128
+00:12:59,400 --> 00:13:05,520
+كلام جيد، بقول كيف؟ بقول هذه بدي أعملها كتالي DX و
+
+129
+00:13:05,520 --> 00:13:10,560
+بدي أخد جذر X كل عامل مشترك من المقدار ككل، يبقى
+
+130
+00:13:10,560 --> 00:13:17,050
+بضال عندي قداش واحد زائد جذر ال Xكتبت المثلة على
+
+131
+00:13:17,050 --> 00:13:22,210
+صيغة جديدة مين المصعب المثلة الجذر الأول ولا الجثر
+
+132
+00:13:22,210 --> 00:13:27,030
+كله الجثر هو المصعب المثلة اذا بدى اشيل الجثر كله
+
+133
+00:13:27,030 --> 00:13:33,550
+و احطه بأي variable جديد اذا لو حطيتي T تساوي واحد
+
+134
+00:13:33,550 --> 00:13:40,710
+زائد جذر ال X يبقى DT يساوي واحد على اتنين جذر ال
+
+135
+00:13:40,710 --> 00:13:46,820
+X في DXمظبوطك تفاضل جذر واحد على اتنين جذر في
+
+136
+00:13:46,820 --> 00:13:51,130
+مشتقة ما تحت الجذرماعنديش اتنينات اذا بضرب في
+
+137
+00:13:51,130 --> 00:13:57,150
+اتنين يبقى اتنين DT بدي اساوي واحد على جذر ال X
+
+138
+00:13:57,150 --> 00:14:03,710
+كله في DX اذا هذا كل واحد على جذر ال X DX بقدر
+
+139
+00:14:03,710 --> 00:14:08,990
+اشيل و اكتب داله جداش اتنين DT يبقى آلة المسألة
+
+140
+00:14:08,990 --> 00:14:16,230
+الى تكامل لاتنين مقدار ثابت خليه برا و بضل عندي DT
+
+141
+00:14:16,230 --> 00:14:21,700
+على Tهو صار بسيط جدا يعني المثل اللي كانت معقدة
+
+142
+00:14:21,700 --> 00:14:26,760
+صارت ولا حاجة بتاعه يعني بسيطة جدا يبقى هذه بقدر
+
+143
+00:14:26,760 --> 00:14:32,560
+اقول اتنين لن absolute value ل T زائد constant C
+
+144
+00:14:32,560 --> 00:14:37,100
+بنشيل ال T و بنكتبها بدلها ل X يبقى اتنين لن
+
+145
+00:14:37,100 --> 00:14:43,260
+absolute value T اللي هو واحد زائد جذر ال X زائد
+
+146
+00:14:43,260 --> 00:14:50,890
+constant Cناخد كمان مثال رقم سبعة بيقول ال
+
+147
+00:14:50,890 --> 00:15:00,850
+integration لمين؟ لإن ال X على 2 زائد لإن ال X كله
+
+148
+00:15:00,850 --> 00:15:02,330
+في X في DX
+
+149
+00:15:08,510 --> 00:15:12,310
+يبقى من المصعب مثلا لإن ال X والله اتنين زائد لإن
+
+150
+00:15:12,310 --> 00:15:15,510
+ال X اتنين زائد لإن ال X هي المصعبة لإن في المقام
+
+151
+00:15:15,510 --> 00:15:22,150
+وشكلها كيف تمام إذا بقدر أشيلها و أكتب Z تساوي
+
+152
+00:15:22,150 --> 00:15:30,330
+اتنين زائد لإن ال X يبقى DZ يساوي واحد على X DX
+
+153
+00:15:30,330 --> 00:15:36,210
+إذا واحد على X DX هذه كلها بقدر أشيلها و أكتب منها
+
+154
+00:15:36,210 --> 00:15:43,360
+كدهيبقى ادت المسألة الى integration لان ال X من
+
+155
+00:15:43,360 --> 00:15:49,100
+هنا كم تسوى بدل ال Z يا شباب؟ Z ناقص اتنين يبقى
+
+156
+00:15:49,100 --> 00:15:55,400
+بقدر اشيلها و اكتب بدلها Z ناقص اتنين و اتنين زائد
+
+157
+00:15:55,400 --> 00:16:01,240
+لان ال X هي كم؟ بزد وهذه كلها بDZ
+
+158
+00:16:03,510 --> 00:16:09,490
+بقدر اوزع البصط على المقام يبقى تكم ال z على z
+
+159
+00:16:09,490 --> 00:16:18,490
+مقدرش ناقص اتنين في واحد على z كله بالنسبة إلى dz
+
+160
+00:16:19,390 --> 00:16:24,190
+تمام اتنين على زد يعني اتنين في واحد على زد الآن
+
+161
+00:16:24,190 --> 00:16:31,230
+بنقدر نكمل تكمل واحد هو جداش زد ونقص اتنين لين
+
+162
+00:16:31,230 --> 00:16:38,730
+absolute value لزد زاد constant C يساويبدي أشيل ال
+
+163
+00:16:38,730 --> 00:16:44,830
+z و أضيف قيمتها يبقى ال z عندي مقداش 2 زائد لن ال
+
+164
+00:16:44,830 --> 00:16:53,090
+x يبقى لي 2 زائد لن ال x نقص 2 لن absolute value
+
+165
+00:16:53,090 --> 00:17:01,980
+للي 2 زائد لن ال x زائد constant Cلو كان هذا
+
+166
+00:17:01,980 --> 00:17:07,800
+السؤال في الكتاب و روحت و السؤال عدد فردي لو روحت
+
+167
+00:17:07,800 --> 00:17:12,120
+دورت على الإجابة بتلاقيش الإجابة هذه هتلاقيها بشكل
+
+168
+00:17:12,120 --> 00:17:16,580
+آخر بصير تقول لو الله حل غلط و تبقى تتباطح في
+
+169
+00:17:16,580 --> 00:17:21,020
+المسألة من جديد و يطلع معاك نفس الجواب طب وين
+
+170
+00:17:21,020 --> 00:17:25,020
+الخلاف بينه و بين الجواب؟ اه طلعليه كويس ايه ايش
+
+171
+00:17:25,020 --> 00:17:33,000
+رأيك في اتنين؟ هذا مقدر ثابت؟الـ C مقدار ثابتيبقى
+
+172
+00:17:33,000 --> 00:17:36,240
+بده اجمعهم كلهم مقدار ثابت واحد يبقى لو كان هذا
+
+173
+00:17:36,240 --> 00:17:39,020
+السؤال في الكتابة هتلاقي الإجابة على الشكل التالي
+
+174
+00:17:39,020 --> 00:17:46,820
+لن ال X ناقص 2 لن absolute value 2 زائد لن ال X
+
+175
+00:17:46,820 --> 00:17:56,220
+زائد constant C1 where ال C1 بده يساوي C زائد 2
+
+176
+00:17:56,220 --> 00:18:00,600
+يبقى بتلاقي الإجابة على الشكل اللي عندنا هذاوليس
+
+177
+00:18:00,600 --> 00:18:07,020
+على الشكل أعلاه يعني بيخليش two constants في
+
+178
+00:18:07,020 --> 00:18:11,600
+الإجابة بيجمع اتنين وبحطهم ب constant جديدة
+
+179
+00:18:48,380 --> 00:18:55,860
+طيب هذا سؤال سبعة سؤال تمانية بدنا تكامل لقطان ال
+
+180
+00:18:55,860 --> 00:19:07,200
+X لين ساين ال X كله بالنسبة إلى DX سؤال
+
+181
+00:19:07,200 --> 00:19:13,470
+كله نسبة مثلثية مش زي اللي فاتالمفروض ان اقسم كل
+
+182
+00:19:13,470 --> 00:19:17,490
+مرة واحد ان اتخلص منه لان عند الاشياء القادرة ان
+
+183
+00:19:17,490 --> 00:19:21,690
+اتخلص منه لان بثالث بيصير مسئلتي أسهل يبقى انا لو
+
+184
+00:19:21,690 --> 00:19:30,120
+جيت قلت هنا putحط للتعويضة التالية مثلا y تساوي ln
+
+185
+00:19:30,120 --> 00:19:39,920
+لصين ال X بدنا dy هي واحد على صين ال X في مشتقة
+
+186
+00:19:39,920 --> 00:19:42,720
+الصين بكوصين ال X في DX
+
+187
+00:19:45,670 --> 00:19:52,510
+كتان ال X DX إذا ال DX مع الكتان ال X هذه كلها
+
+188
+00:19:52,510 --> 00:19:57,590
+بقدر أشيلها و أكتب بدلها جداش DY وبالتالي اتقالت
+
+189
+00:19:57,590 --> 00:20:01,390
+المسألة إلى تكامل Y DY
+
+190
+00:20:04,960 --> 00:20:11,020
+خلاص يبقى هذه بدها تساوي Y تربيع على 2 زائد
+
+191
+00:20:11,020 --> 00:20:16,100
+constant C تساوي نص، بده أشيل ال Y و أحط مكان
+
+192
+00:20:16,100 --> 00:20:25,380
+أجداش لإن sin X الكل تربيع زائد constant C
+
+193
+00:20:28,110 --> 00:20:34,430
+طيب، بدي أحاول أكتب هذه بالصيغم مختلفة، وشوفولي
+
+194
+00:20:34,430 --> 00:20:40,550
+أين الصح و أين الخطأ في كتابتي فمثلا، لو جيت قلتلك
+
+195
+00:20:40,550 --> 00:20:52,730
+لن صين ال X لكل تربيع تساوي لن تربيع لصين ال X أو
+
+196
+00:20:53,520 --> 00:21:04,180
+لن تربيع لصين تربيع ال X أو لن لصين تربيع ال X
+
+197
+00:21:04,180 --> 00:21:13,840
+الأولى صح والتنتين هدول غلط متأكدين؟ قولوا غيره
+
+198
+00:21:14,520 --> 00:21:20,620
+يبقى إياك واحد يعملها. هذه غلط وهذه غلط. وهذه هي
+
+199
+00:21:20,620 --> 00:21:26,460
+الوحيدة اللي صح. تمام؟ يبقى التربية يكون للدالة
+
+200
+00:21:26,460 --> 00:21:30,820
+وليست لمن؟ للمتغير، لما أقول كله هيك.تقول للن
+
+201
+00:21:30,820 --> 00:21:34,780
+تربية الصين، تربية لأن للن لحالها بدون الصين لا
+
+202
+00:21:34,780 --> 00:21:40,360
+معنى لها، إذا التربية للن وليس لمن وليس للصين،
+
+203
+00:21:40,360 --> 00:21:44,200
+يبقى هذه خطأ يبقى إياكوا ثم إياكوا واحد يعملها
+
+204
+00:21:44,200 --> 00:21:48,380
+ورغم ذلك لازم يجيلي اتنين تلاتة يعملوها، يبقى دير
+
+205
+00:21:48,380 --> 00:21:52,740
+بالك، يعني احنا بننبي عليك من اليوم حتى ما توجعش
+
+206
+00:21:52,740 --> 00:21:59,090
+في مشكلة من هذه المشاكلالسؤال التاسع والاخير بدي
+
+207
+00:21:59,090 --> 00:22:07,430
+تكامل لسك ال X على الجدر التربيعي لن سك ال X زائد
+
+208
+00:22:07,430 --> 00:22:17,250
+تان ال X كله بالنسبة إلى DX اه
+
+209
+00:22:17,250 --> 00:22:25,330
+في حاجة صعبها؟ اه في مين؟ الجدر واللي تحته كمانلكن
+
+210
+00:22:25,330 --> 00:22:30,770
+لو كان جدر ال X لحاله ماعجبه اللي بنقدر عليه بس لن
+
+211
+00:22:30,770 --> 00:22:35,430
+لسك زي او تاني و كله اذا بده اشيل كل لن باللي معاه
+
+212
+00:22:35,430 --> 00:22:38,790
+و احطه متغيره و اشوف اللي هو لين بدنا نوصل اذا
+
+213
+00:22:38,790 --> 00:22:45,790
+بقدر اقول put حط للتعويضة التالية حط ل W تساوي لن
+
+214
+00:22:46,150 --> 00:22:54,190
+سك ال X زائد تان ال X هذا بده يعطيك ان دي W بده
+
+215
+00:22:54,190 --> 00:23:00,150
+يساوي تفاضل ال N بواحد على اللي داخل اللي انه سك
+
+216
+00:23:00,150 --> 00:23:10,190
+ال X زائد تان ال Xفي مشتقة مداخل الان، مشتقة السك
+
+217
+00:23:10,190 --> 00:23:19,250
+بقداش بسك ال X في تان ال X ومشتقة التان بسك تربيع
+
+218
+00:23:19,250 --> 00:23:28,640
+ال X وكل هذا في DXهذا الكلام يساوي ال DW تساوي
+
+219
+00:23:28,640 --> 00:23:34,260
+شرايك لو أخدت سك عامل مشترك من البسط يبقى لو أخدت
+
+220
+00:23:34,260 --> 00:23:39,920
+سك بصير عندي سك ال X عامل مشترك بيبقى تان ال X
+
+221
+00:23:39,920 --> 00:23:48,920
+زائد سك ال X كله مقسوما على سك ال X زائد تان ال X
+
+222
+00:23:48,920 --> 00:23:54,450
+نسبة إلى DX شرايك الجثة اللي فوق هو المقام؟يبقى
+
+223
+00:23:54,450 --> 00:24:01,150
+الله سهل عليكم مع السلامة غير مأسوف عليكم سك ال X
+
+224
+00:24:01,150 --> 00:24:08,970
+في DX هدا مين؟ DW طب اتطلع هنا ماهي سك ال X في DX
+
+225
+00:24:08,970 --> 00:24:15,970
+كلها ب DW يبقى آلة المثلة عندي ال integration ال
+
+226
+00:24:15,970 --> 00:24:22,730
+DW على الجذر التربية ال Wيبقى اللي كانت مكلقة أو
+
+227
+00:24:22,730 --> 00:24:28,150
+بتخوف كبيرة هك صارت بسيطة جدا يبقى هذا الكلام بده
+
+228
+00:24:28,150 --> 00:24:36,150
+يساوي تكامل ل W أس ناقص نص دي W بنضيف للأس واحد
+
+229
+00:24:36,150 --> 00:24:42,790
+وبنجسم على الأس لجديد يبقى W أس نص على نص زائد
+
+230
+00:24:42,790 --> 00:24:48,710
+constant C هذه معناها اتنين نص بنجل من فوق بصير
+
+231
+00:24:48,710 --> 00:24:56,300
+اتنينوالأُص نُص تعني الجذر و ال W هي فرضنا اللي هو
+
+232
+00:24:56,300 --> 00:25:05,560
+ال N سك ال X زائد تان ال X كله بالنسبة إلى مين؟
+
+233
+00:25:05,560 --> 00:25:07,100
+زائد كونستانسي
+
+234
+00:25:11,190 --> 00:25:16,910
+طب لحد هنا انتهى ال section ويليكم أرقام المسائل
+
+235
+00:25:16,910 --> 00:25:26,330
+اله exercises اله سبعة اتنين المسائل التالية من
+
+236
+00:25:26,330 --> 00:25:33,330
+واحد لغاية تمانية وستين القدر وبنضيف عليهم سؤال
+
+237
+00:25:33,330 --> 00:25:38,490
+واحد وتمانين وسؤال اتنين وتمانين كمالك
+
+238
+00:25:41,140 --> 00:25:45,880
+بننتقل الان الى سيكشن سبعة تلاتة اله ال
+
+239
+00:25:45,880 --> 00:25:56,100
+exponential functions هظن
+
+240
+00:25:56,100 --> 00:26:03,680
+ان هذا انتهينا منه كيف لأ عادي هذا بقول انتهينا
+
+241
+00:26:03,680 --> 00:26:06,540
+منه الأول تمام
+
+242
+00:26:08,660 --> 00:26:13,920
+والثاني اذا كان الحين مش كاتب ادا وين كان؟ يا راجل
+
+243
+00:26:13,920 --> 00:26:18,360
+انت ولاد تربية كله التهندسة وتكنولوجيا المعلومات
+
+244
+00:26:18,360 --> 00:26:23,360
+وعلوم واللي عرفيكوا تربية كمان علوم يعني كلكوا
+
+245
+00:26:23,360 --> 00:26:27,520
+قيادين للمستقبل وانتوا يعني علاماتكوا عالية في
+
+246
+00:26:27,520 --> 00:26:34,030
+الثانوية العامة كما علمونا أساتذتنا المصريينأكتب و
+
+247
+00:26:34,030 --> 00:26:39,150
+أفهم و أرسم في أهل الواحد يعني تبقى من هناك تخليك
+
+248
+00:26:39,150 --> 00:26:46,150
+مفتح و صاحي، تسرحش برا طيب، مدام هيك، يبقى هذه
+
+249
+00:26:46,150 --> 00:26:52,770
+التعويضة و مشتقتها خلصنا منها تعويضة و مشتقتها
+
+250
+00:26:52,770 --> 00:26:59,150
+صارت هذه فارغة ولا هاجة ولا ماها هي دي يعني، و
+
+251
+00:26:59,150 --> 00:27:01,930
+ليش؟ يبقى هذه خلصنا منها
+
+252
+00:27:12,410 --> 00:27:18,410
+تنساشلي السطر الأخير اللي هو أهم من كل ما سمعت بعد
+
+253
+00:27:18,410 --> 00:27:30,430
+بنيجي لسبعة تلاتة اللي هو ال exponential functions
+
+254
+00:27:35,380 --> 00:27:42,740
+الدالة الأسية طبعا حياة الواحد هي الدالة الأسية
+
+255
+00:27:42,740 --> 00:27:47,980
+هذه هي دالة القوة اللي كنا نقول عليها زمن X تربيها
+
+256
+00:27:47,980 --> 00:27:55,000
+و X تكيب و X to the power and بيجهبوا لبعض، بس ايش
+
+257
+00:27:55,000 --> 00:27:58,320
+فرق شاسع ما بين الاتنين، كيف فرق شاسع ما بين
+
+258
+00:27:58,320 --> 00:27:59,120
+الاتنين؟
+
+259
+00:28:05,200 --> 00:28:12,560
+الأساس متغير والأس ثابت الأساس
+
+260
+00:28:12,560 --> 00:28:19,640
+ثابت والأس متغيروقد يكون الاساس متغير والقص متغير
+
+261
+00:28:19,640 --> 00:28:23,960
+في آن واحد يعني الاحتماليان وردات هذه بيسميها ال
+
+262
+00:28:23,960 --> 00:28:27,580
+exponential function قبل ما نبدأ في ال exponential
+
+263
+00:28:27,580 --> 00:28:32,540
+في نقطتين صغار بدنا نجيبهم في section 7-2 لهم
+
+264
+00:28:32,540 --> 00:28:34,680
+الأساسيات عندنا في section 7
+
+265
+00:28:37,240 --> 00:28:41,980
+النقطة الأولى يا سيدي جاب المانيجي لتعريف ال
+
+266
+00:28:41,980 --> 00:28:48,860
+exponential function بقول since بما أن لن ال X is
+
+267
+00:28:48,860 --> 00:28:52,480
+an increasing
+
+268
+00:28:54,090 --> 00:28:57,830
+function طبعا هذه كتبناها المرة الماضية في الوزن
+
+269
+00:28:57,830 --> 00:29:05,110
+نظري صحيح مدام increasing يبقى لن ال x is one to
+
+270
+00:29:05,110 --> 00:29:11,850
+one مدام لن ال x is one to one يبقى معناته لن
+
+271
+00:29:11,850 --> 00:29:17,770
+inverse x exist مظبوط
+
+272
+00:29:18,760 --> 00:29:24,380
+يبقى معكوسة بأن هذا لازم يكون وجد شو شكله الله
+
+273
+00:29:24,380 --> 00:29:31,020
+أعلم لكن مش هنطول فنشير اليها بعد قليل النقطة
+
+274
+00:29:31,020 --> 00:29:38,700
+الثانيةاخدنا ان لن ال E تساوي 1 اخر definition
+
+275
+00:29:38,700 --> 00:29:43,900
+كتبناه في الجزء النظري قلنا العدد E هو العدد اللي
+
+276
+00:29:43,900 --> 00:29:51,180
+في دمية لن X بحيث القيمة تبعته تساوي 12وحد صحيح طب
+
+277
+00:29:51,180 --> 00:29:56,700
+إيش رأيك هذا لو أثرت على الطرفين ب len inverse؟
+
+278
+00:29:56,700 --> 00:30:03,140
+إيش بيصير؟ بيصير len inverse ل len ال E بدي ساوي
+
+279
+00:30:03,140 --> 00:30:08,600
+len inverse ل len ال Nهذا هو الوضع بين الدلة
+
+280
+00:30:08,600 --> 00:30:17,020
+ومعكوسة يبقى واحدة تلغي تأثير التانية بيصير عندك
+
+281
+00:30:17,020 --> 00:30:24,740
+ال E تساوي لن inverse oneوهذا حسبه لجوه حوالي
+
+282
+00:30:24,740 --> 00:30:30,640
+اتنين وسبعة من عشرة تقريبا يعني مش يساوي بالدقة
+
+283
+00:30:30,640 --> 00:30:37,240
+يساوي تقريبا اتنين وسبعة من عشرة فيه تابع له كسر
+
+284
+00:30:37,240 --> 00:30:41,810
+صغيربعد السبعة بيجيك الف و تمانية و تمانية و عشرين
+
+285
+00:30:41,810 --> 00:30:45,030
+و كمان الف و تمانية و تمانية و عشرين و خمسة و
+
+286
+00:30:45,030 --> 00:30:48,710
+أربعين و تسعين و خمسة و أربعين و تسعين و تسعين و
+
+287
+00:30:48,710 --> 00:30:49,050
+تسعين و تسعين و تسعين و تسعين و تسعين و تسعين و
+
+288
+00:30:49,050 --> 00:30:49,550
+تسعين و تسعين و تسعين و تسعين و تسعين و تسعين و
+
+289
+00:30:49,550 --> 00:30:49,810
+تسعين و تسعين و تسعين و تسعين و تسعين و تسعين و
+
+290
+00:30:49,810 --> 00:30:52,950
+تسعين و تسعين و تسعين و تسعين و تسعين و تسعين و
+
+291
+00:30:52,950 --> 00:31:02,430
+تسعين و تسعين و تسعين و تسعين و تسعين و تسع
+
+292
+00:31:05,070 --> 00:31:09,010
+تمام طيب بدنا نيجي للعلوان اللي احنا رافعينه و
+
+293
+00:31:09,010 --> 00:31:15,250
+نعطيله تعريف يبقى definition definition
+
+294
+00:31:15,250 --> 00:31:30,130
+for any real number x لأي number x we define the
+
+295
+00:31:30,130 --> 00:31:30,870
+natural
+
+296
+00:31:34,790 --> 00:31:44,150
+الشركة الطبيعية الأكسبونيشية الشركة
+
+297
+00:31:44,150 --> 00:31:53,290
+الطبيعية الأكسبونيشية لكي تكون الاختلاف لكي تكون
+
+298
+00:31:53,290 --> 00:31:58,230
+الشركة الأكسبونيشية لـ
+
+299
+00:31:58,230 --> 00:31:59,290
+Null X
+
+300
+00:32:06,750 --> 00:32:12,210
+الـ exponential للـ X هي إيه هو الـ 6؟ هو اللي هي
+
+301
+00:32:12,210 --> 00:32:23,750
+بدأت ساوي الـ ln inverse X نرجع
+
+302
+00:32:23,750 --> 00:32:28,950
+للتعريف اللي احنا كتبينه مرة ثانية ونتوقف معه
+
+303
+00:32:28,950 --> 00:32:38,170
+قليلا ثم نواصل الخواص لهذه الدالة خلّينا كذاالان
+
+304
+00:32:38,170 --> 00:32:44,710
+لما قدرنا بهذه المقدمة قاصدينها بعينها لإن ال X
+
+305
+00:32:44,710 --> 00:32:48,310
+increasing يبقى لإن ال X one to one يبقى المعكوس
+
+306
+00:32:48,310 --> 00:32:51,990
+ماله موجود، من هو المعكوس هو اللي بنعطيه التعريف
+
+307
+00:32:51,990 --> 00:32:56,090
+اللي عندنا هذافجهزة قلنا تاريخ for any real number
+
+308
+00:32:56,090 --> 00:33:00,550
+x we define the natural exponential function a
+
+309
+00:33:00,550 --> 00:33:06,870
+bell الأسية الطبيعية to be the inverse function of
+
+310
+00:33:06,870 --> 00:33:13,980
+len xيبقى هي معكوس قبل لن ال X طبعا لن ال X ايش
+
+311
+00:33:13,980 --> 00:33:18,060
+سمنها؟ ال natural logarithm، ال logarithm الطبيعي
+
+312
+00:33:18,060 --> 00:33:21,820
+و نظرا لان هذه اعتمدت عليه اوي المعكوس طبعا
+
+313
+00:33:21,820 --> 00:33:25,660
+فسمناها ال natural exponential يعني في exponential
+
+314
+00:33:25,660 --> 00:33:29,780
+تانية اه في حاجة مسمية ال general exponential
+
+315
+00:33:29,780 --> 00:33:33,140
+function برضه في هذا ال section بدنا ناخدها و
+
+316
+00:33:33,140 --> 00:33:36,970
+خواصها و ما إلى ذلكيبقى خلّينا بس في الأول مع ال
+
+317
+00:33:36,970 --> 00:33:41,490
+nature of exponential function هي معكوسة بالا لل X
+
+318
+00:33:41,490 --> 00:33:47,570
+بدي أعيد صياغة هذا السطر رياضيا فبقول that is ال X
+
+319
+00:33:47,570 --> 00:33:52,610
+بلا X ال X بأول تلت حروف من كلمة exponential يعني
+
+320
+00:33:52,610 --> 00:33:57,420
+في كتاب الفيزياء يمكن تلاقوها مكتوب X بXتمام؟ يبقى
+
+321
+00:33:57,420 --> 00:34:02,580
+X exponential X أو ال E والسكس ال E والسكس هو
+
+322
+00:34:02,580 --> 00:34:06,500
+العدد اللي هنا رجع نقله تاني يبقى هو العدد اللي
+
+323
+00:34:06,500 --> 00:34:09,560
+بيساوي قداشر نين وسبعة من .. اللي كنتوا في
+
+324
+00:34:09,560 --> 00:34:13,080
+الثانوية بيسموه العدد ال library يعني جاي من ال
+
+325
+00:34:13,080 --> 00:34:19,300
+library زي واحد معاه شنطة جال شنطة دبلوماسية جال
+
+326
+00:34:19,300 --> 00:34:23,360
+من وين جابها جال من دبلوماسيا يعني بس على سبيل
+
+327
+00:34:23,360 --> 00:34:29,310
+النقطةطيب يبقى أصبح عندك ال exponential function
+
+328
+00:34:29,310 --> 00:34:35,390
+لل X هي EOSX وتساوم من لن انفرس X طبقا للتعريف
+
+329
+00:34:35,390 --> 00:34:40,530
+اللي احنا كاتبينه إذا هذه دالة جديدة بدنا نشوف
+
+330
+00:34:40,530 --> 00:34:47,810
+خواص هذه الدالة يبقى بقى دي بقول some properties
+
+331
+00:34:47,810 --> 00:34:51,070
+of
+
+332
+00:34:51,070 --> 00:34:54,130
+Y تساوي EOSX
+
+333
+00:34:58,610 --> 00:35:04,930
+أيش رأيك؟ بدي أبدأ بالرسمة والرسمة بدي أجيبها من
+
+334
+00:35:04,930 --> 00:35:12,470
+مفهوم المعكوس تبع section 7-1 و 7-2 وبالتالي بصير
+
+335
+00:35:12,470 --> 00:35:16,950
+رسم القضية عندي بسيطة جدا، إذا لو جيت قلت هي
+
+336
+00:35:16,950 --> 00:35:24,470
+الرسمة هذا محور X وهذا محور Y وهذا نقطة الأصل اللي
+
+337
+00:35:24,470 --> 00:35:31,170
+هي Zeroقلنا لك بنرسم الدالة Y تساوي لن X وكل
+
+338
+00:35:31,170 --> 00:35:38,010
+رسمناها هي بالهيك، يبقى رسمة الدالة Y تساوي لن X
+
+339
+00:35:38,010 --> 00:35:45,720
+بالشكل اللي عندنا هذا يبقى هذه Y تساوي لن Xبنجيب
+
+340
+00:35:45,720 --> 00:35:52,340
+رسمة المعكوس لنقل المعكوس من الخواص الدل لو معكوسة
+
+341
+00:35:52,340 --> 00:35:59,060
+بدك تقلب هذه الرسمة عبر محور او عبر الخط Y to X
+
+342
+00:35:59,060 --> 00:36:04,040
+بيكون حصلت على رسمة المعكوس لهذه الدل اللي هي مين؟
+
+343
+00:36:06,320 --> 00:36:15,440
+بنروح نرسم الخط Y تساوي X يبقى هذا Y تساوي X
+
+344
+00:36:15,440 --> 00:36:21,900
+النقطة هذه كم كانت احداثيها يا شباب؟ واحد وزيرو
+
+345
+00:36:21,900 --> 00:36:27,060
+لما نقلب ايش بيصير؟ Zero واحد ممتاز يبقى Zero واحد
+
+346
+00:36:27,060 --> 00:36:32,670
+بنتيجين النقطة هذه Zero واحدالان مش هنجيب صوت
+
+347
+00:36:32,670 --> 00:36:37,270
+المقوس كأنه بدك تجيب مرآة مستوية و تحطها هنا و
+
+348
+00:36:37,270 --> 00:36:42,050
+تظهر الصورة مقلوبة في الناحيات التانية زي سياتك
+
+349
+00:36:42,050 --> 00:36:45,330
+الصبح قبل تجي على الجامعة و بدك تظبط شعرتك بتوجه
+
+350
+00:36:45,330 --> 00:36:50,500
+قدام المرآةاذا انت موجه غرب تشوف صورتك وين؟ شرق
+
+351
+00:36:50,500 --> 00:36:54,800
+على عكسك تماما يبقى احنا بدنا نجلب هذه في النحل
+
+352
+00:36:54,800 --> 00:36:59,760
+هذه كانت concave down يبقى ال EOSX بصير وين؟
+
+353
+00:36:59,760 --> 00:37:05,020
+concave up يبقى لو روحت رسمت هتجيلك الصورة بالشكل
+
+354
+00:37:05,020 --> 00:37:11,020
+اللي عندنا هنا يبقى الخط الأزج المتواصل هذا هو
+
+355
+00:37:11,020 --> 00:37:14,340
+منحنة دالة EOSX
+
+356
+00:37:16,750 --> 00:37:25,570
+طيب، لو على سبيل المثال بدي E أس اتنين X تقلع أعلى
+
+357
+00:37:25,570 --> 00:37:34,390
+هذه ولا أسفلها؟ E أس اتنين X الرسم،
+
+358
+00:37:34,390 --> 00:37:39,170
+لو رسمت E أس اتنين X الدالة هذه تقلع رسمتها منها و
+
+359
+00:37:39,170 --> 00:37:43,210
+فوق ولا منها و تحتها؟ انا بقول
+
+360
+00:37:47,680 --> 00:37:54,920
+تنظر كيف؟ جزء
+
+361
+00:37:54,920 --> 00:38:00,760
+بدي يكون أعلى هذه الرسمة و جزء بدي يكون أسفلها
+
+362
+00:38:00,760 --> 00:38:05,800
+طبعا في غربة من كلامي، مش هيك؟ ولا في غربة ولا
+
+363
+00:38:05,800 --> 00:38:11,300
+حاجة مقربة للشيطان، كيف؟ لو قلت عندي الواحد، هذي
+
+364
+00:38:11,300 --> 00:38:18,400
+بيصير إيس واحد؟لكن لما نقول E أس اتنين X بيصير E
+
+365
+00:38:18,400 --> 00:38:23,440
+تربيع يبقى بتيجي من وين؟ منها و فوق لكن اذا جيت
+
+366
+00:38:23,440 --> 00:38:28,640
+تحت الواحد بيصير من هذا الرسمة و تحت يعني رسمة ال
+
+367
+00:38:28,640 --> 00:38:34,040
+E أس اتنين X بيبدأ تجيلك بالشكل اللي عندك هذا هذا
+
+368
+00:38:34,040 --> 00:38:40,800
+هيك يبقى هذا السودا ال E أس اتنين X
+
+369
+00:38:43,310 --> 00:38:50,330
+طبعا يبقى اجت منها و تحت بالشكل اللي قدامك هذا طيب
+
+370
+00:38:50,330 --> 00:38:56,350
+الان خد مني نبدأ في الخواص اشي هنجيبه من الرسم و
+
+371
+00:38:56,350 --> 00:39:03,330
+اشي هنجيبه من غير الرسم الخاصية الأولى ال a و ال
+
+372
+00:39:03,330 --> 00:39:07,570
+six هذه بدي اجيب ال domain تبعها يبقى ال domain
+
+373
+00:39:07,570 --> 00:39:15,110
+بتبع ال a و ال six يساوي قداشالـ Range تبع الـ Lin
+
+374
+00:39:15,110 --> 00:39:20,870
+يساوي الـ Range بتبع الـ Lin الـ X جديش الـ Range
+
+375
+00:39:20,870 --> 00:39:27,600
+لLin X من سالب Infinity ل Infinity andالـ Range
+
+376
+00:39:27,600 --> 00:39:33,960
+بتابع الـ EO6 بده يساوي الـ domain بتابع الـ N للـ
+
+377
+00:39:33,960 --> 00:39:39,940
+X اللي هو من Zero لغاية لل Infinity طيب يا ناس هذا
+
+378
+00:39:39,940 --> 00:39:44,020
+الكلام صحيح على الرسم اللي احنا حاطينه تعالى شوف
+
+379
+00:39:44,020 --> 00:39:49,060
+هذه الـ EO6 ال domain تابعها كل الـ real line
+
+380
+00:39:49,060 --> 00:39:52,160
+معرفة عليها كل الـ real line مافيش نقطة ماهياش
+
+381
+00:39:52,160 --> 00:39:56,940
+معرفة عليهاإذا ال domain تبع ال EO6 من سالب
+
+382
+00:39:56,940 --> 00:40:01,230
+infinity ل infinity بالداجة لل rangeالـ Range هي
+
+383
+00:40:01,230 --> 00:40:06,430
+الرسمة كلها من محور X وين وفوق يعني أعلى ال Excess
+
+384
+00:40:06,430 --> 00:40:11,730
+يبقى من وين لوين من صفر ل Infinity as an open
+
+385
+00:40:11,730 --> 00:40:17,770
+interval طيب بناء عليه بدأ أسأل السؤال التالي هل
+
+386
+00:40:17,770 --> 00:40:23,350
+يمكن لل EO6 إنها تاخد قيمة سالبة في يوم من الأيام؟
+
+387
+00:40:24,310 --> 00:40:28,950
+فى الشمكانية ليش لإن هدى اتنين وسبعة من عشرة اص
+
+388
+00:40:28,950 --> 00:40:33,370
+رقم موجب بيعطينا رقم موجب اتنين وسبعة من عشرة اص
+
+389
+00:40:33,370 --> 00:40:38,270
+زيرو واحد صحيح موجب اتنين وسبعة من عشرة اص ناقص
+
+390
+00:40:38,270 --> 00:40:42,490
+خمسة بيصير واحد على اتنين وسبعة من عشرة اص خمسة
+
+391
+00:40:42,640 --> 00:40:47,080
+يبقى رقم موجب يبقى لها يمكن تاخد قيمة سالبة و زي
+
+392
+00:40:47,080 --> 00:40:52,420
+ما تشوف هي رسمتها كلها أعلى ال X Axis تمام يبقى
+
+393
+00:40:52,420 --> 00:40:57,400
+بقدر أقول الخاصية الثانية أظن هذه النقطة انتهينا
+
+394
+00:40:57,400 --> 00:41:05,360
+منها هذه اللي فوق يبقى ال EOS X هذه أكبر من Zero
+
+395
+00:41:05,360 --> 00:41:08,700
+Four All X بلا استثناء
+
+396
+00:41:12,660 --> 00:41:19,700
+عرفنا ليش اكبر من ال zero بلا استثناء نجي النقطة
+
+397
+00:41:19,700 --> 00:41:26,480
+الثانية النقطة التالتة خلي بالك معايا هنا بدي اي
+
+398
+00:41:26,480 --> 00:41:35,000
+أس لان ال X كده تساوي كده توقع يكون؟ Y X
+
+399
+00:41:39,280 --> 00:41:45,540
+بنقول بسيطة جدا اتطلعلي في التعريف هنا جل ال E أس
+
+400
+00:41:45,540 --> 00:41:52,360
+X بده يساوي جداش لن انفرس لل X يعني لن انفرس لل
+
+401
+00:41:52,360 --> 00:42:00,060
+element اللي هنا يبقى E أس لن X بده يساوي لن انفرس
+
+402
+00:42:00,060 --> 00:42:07,110
+للمقدار اللي عندنا هذايبقى لن انفرس واللن هدول عكس
+
+403
+00:42:07,110 --> 00:42:13,470
+بعض طبعا مدام عكس بعض واحد بالغ التاني بصير عندي E
+
+404
+00:42:13,470 --> 00:42:22,570
+أس لن ال X يساوي ال X طب بمزيد عليها كمان نقطة and
+
+405
+00:42:22,570 --> 00:42:32,450
+لو بده أخد لن ال E أس Xيبقى هذا الكلام بده يساوي X
+
+406
+00:42:32,450 --> 00:42:37,390
+في لن الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن
+
+407
+00:42:37,390 --> 00:42:38,030
+الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن
+
+408
+00:42:38,030 --> 00:42:38,970
+الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن
+
+409
+00:42:38,970 --> 00:42:41,930
+الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن
+
+410
+00:42:41,930 --> 00:42:43,990
+الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن
+
+411
+00:42:43,990 --> 00:42:44,490
+الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن
+
+412
+00:42:44,490 --> 00:42:50,610
+الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن الإيه؟ لن
+
+413
+00:42:50,610 --> 00:42:54,370
+الإي
+
+414
+00:42:54,900 --> 00:43:01,020
+تعالى نشوف الان هذه ايه أس لن ال X اللين هذا
+
+415
+00:43:01,020 --> 00:43:07,400
+ماكنتش معرف من أين لأين من الصفر لما من يعني X
+
+416
+00:43:07,400 --> 00:43:13,940
+greater than 0 دائما و أبدا يبقى هذه معرفة فقط ل X
+
+417
+00:43:13,940 --> 00:43:21,070
+اللي أكبر من ال zeroهذه ال E و ال 6 اشترطنا انها
+
+418
+00:43:21,070 --> 00:43:27,030
+معرفة للكل الموجب والسالب والصفر يعني مين كل ال
+
+419
+00:43:27,030 --> 00:43:32,930
+real line بلا استثناء يبقى هذه for all X بلا
+
+420
+00:43:32,930 --> 00:43:37,390
+استثناء ان X بتاعتنا هذه غير X بتاعتنا هذه ايش
+
+421
+00:43:37,390 --> 00:43:43,270
+رأيك انه هذه بدي احطها لك في مربع وهذه very
+
+422
+00:43:43,270 --> 00:43:49,720
+importantبتلزمك بدل المرة مائة مرة اذا لم يكن اكتر
+
+423
+00:43:49,720 --> 00:43:54,100
+خلال شغلك وانت بتشتغل فيه كالكلاس بيه كل شوية و هي
+
+424
+00:43:54,100 --> 00:43:56,980
+طالع عليك مش عاجبني ال chapter هذا لا و ال
+
+425
+00:43:56,980 --> 00:44:01,340
+chapters القادمة كمان يبقى هذه very important
+
+426
+00:44:05,480 --> 00:44:10,440
+الـ X ذاتها اللي أكبر منها لأن الـ Lin الأولى الـ
+
+427
+00:44:10,440 --> 00:44:14,940
+X هذه الـ Lin مش معرفة إلا لـ X اللي أكبر منها الـ
+
+428
+00:44:14,940 --> 00:44:19,820
+Zero X تبعتنا هذه هي هذه إذا X greater عن Zero
+
+429
+00:44:19,820 --> 00:44:25,480
+ممتاز
+
+430
+00:44:30,600 --> 00:44:36,060
+موجب، صح ولا لأ؟ ال EO6 موجب، يعني اللن X جبتلي
+
+431
+00:44:36,060 --> 00:44:40,700
+موجب، ولا سالب ولا صفر زي لن الواحد، فانها ليست
+
+432
+00:44:40,700 --> 00:44:45,400
+قيمة موجب، صح ولا لأ؟ وهذا حطناه وقلنا هنا إن ال
+
+433
+00:44:45,400 --> 00:44:50,240
+EO6 greater than zero for all X بلا استثناء، تمام؟
+
+434
+00:44:51,040 --> 00:44:54,440
+يبقى هؤلاء الشباب دي ربالكوا منهم مهمات جدا بإذنك
+
+435
+00:44:54,440 --> 00:45:00,600
+تعرفهم مثل اسمك ال E و Lن عكس بعض كأنه ها كأنه
+
+436
+00:45:00,600 --> 00:45:06,400
+واحدة بتلغي التانية والجواب X تمام هاد ال X تصير
+
+437
+00:45:06,400 --> 00:45:10,140
+برا في لن ال E لن ال E بواحد صحيح يبقوا بظلمين
+
+438
+00:45:10,140 --> 00:45:14,940
+عندي بظل عندي X فقط الآن بدنا نجي لخاصية اللي
+
+439
+00:45:14,940 --> 00:45:24,880
+بعدها خاصية أربعةالـ EOS X تخضع لقوانين الأسس إذا
+
+440
+00:45:24,880 --> 00:45:30,700
+تساوت
+
+441
+00:45:30,700 --> 00:45:36,210
+الأساسات عند الضرب تجمع الأسسيبقى هذا بدى يساوي
+
+442
+00:45:36,210 --> 00:45:44,690
+EOS X1 زائد X2 النقطة الثانية ال EOS X1 تقسيم EOS
+
+443
+00:45:44,690 --> 00:45:55,530
+X2 يساوي EOS X1 minus X2النقطة الثالثة ال E Os X E
+
+444
+00:45:55,530 --> 00:46:02,710
+Os سالب X بدي سوى واحد على E Os X النقطة الرابعة
+
+445
+00:46:02,710 --> 00:46:10,030
+والاخيرة E Os X One كل E Os X Two بدي اعطيك E Os X
+
+446
+00:46:10,030 --> 00:46:18,640
+One مضروبة في X Two بهذا الشكلطيب، ظهرت عندي هنا E
+
+447
+00:46:18,640 --> 00:46:26,040
+أص ناقص X، تمام؟ يعني لو حبيت أرسمها، أرسم هيك،
+
+448
+00:46:26,040 --> 00:46:33,900
+بروح بقول هذا محور X وهذا محور Y، هذه هيك، رسم
+
+449
+00:46:33,900 --> 00:46:41,820
+تمين، E أص X، والنقطة هذه هنا و Zero و واحد، Zero
+
+450
+00:46:41,820 --> 00:46:50,580
+و واحدلو بد او سالب اكس يعني واحد على ا أو سكس
+
+451
+00:46:50,580 --> 00:46:54,720
+واحد على ا أو سكس هي عبارة عن نفس الرسمة بتيجي من
+
+452
+00:46:54,720 --> 00:47:01,100
+وين؟ من الناحية التانية يبقى هذه نفسها بس بتيجي من
+
+453
+00:47:01,100 --> 00:47:08,220
+وين؟ من الناحية التانية بهذا الشكل يبقى هذه رسمة
+
+454
+00:47:08,220 --> 00:47:16,450
+اللي همين ا أو سالب اكسطب خلّيني أسأل السؤال لو
+
+455
+00:47:16,450 --> 00:47:21,710
+جيت لل E و ال 6 هذه و قُلت لك قداش ال limit لها
+
+456
+00:47:21,710 --> 00:47:28,870
+لما ال X بدها تروح لما لا نهاية اعتبرها رقم خمسة
+
+457
+00:47:28,870 --> 00:47:34,890
+بدنا limit ال E و ال 6 لما ال X بدها تروح لما لا
+
+458
+00:47:34,890 --> 00:47:38,970
+نهاية لما ال X بدها تروح لما لا نهاية يبقى تبين لي
+
+459
+00:47:38,970 --> 00:47:45,590
+هذه راحة لوين؟للمالة نهاية طيب و لو جذلك limit ال
+
+460
+00:47:45,590 --> 00:47:51,370
+E و ال 6 لما ال X بده تروح لسالب infinity لما ال X
+
+461
+00:47:51,370 --> 00:47:57,590
+بده تروح لسالب infinity ده اللي رايح لوين سمعت
+
+462
+00:47:57,590 --> 00:48:00,630
+روايات كتيرة بد اللي يعرف يرفع يده عشان نتناقش
+
+463
+00:48:00,630 --> 00:48:06,790
+احنا ويا ايه سالب مالة نهاية تعالى هنا اشوفك تعالى
+
+464
+00:48:06,790 --> 00:48:14,640
+شوية بس الحاجة يا راجلالعاجل شو اسمك انت؟ عماد
+
+465
+00:48:14,640 --> 00:48:21,760
+تعالى عماد هنا الحين لو جيت عند الواحد بتبقى ال
+
+466
+00:48:21,760 --> 00:48:26,740
+six القيمة هذه صح؟ لو جيت عند ال zero تبقى القيمة
+
+467
+00:48:26,740 --> 00:48:30,480
+واحد لو جيت عند السلم واحد تبقى القيمة هذه
+
+468
+00:48:42,220 --> 00:48:51,700
+يبدأ الـ EO6 عندما الـ X تنزل إلى 0 يبدأ الـ
+
+469
+00:48:51,700 --> 00:48:58,940
+EO6
+
+470
+00:48:58,940 --> 00:49:01,000
+عندما الـ X تنزل إلى 0
+
+471
+00:49:22,690 --> 00:49:28,870
+هذه هي النقطة الخامسة بالنسبة للـ Limb نجي إلى
+
+472
+00:49:28,870 --> 00:49:37,100
+اشتقاقهاطيب الان بدنا نجي لرقم ستة ال D على DX لل
+
+473
+00:49:37,100 --> 00:49:46,620
+EO6 انا ازعم انها EO6 itself لا تتأثر الريح ماجدرش
+
+474
+00:49:46,620 --> 00:49:51,020
+يأثر في البلاط بقوله وهي تشتقى يبعت الله انا ثابت
+
+475
+00:49:51,020 --> 00:49:56,720
+ماليش علاقة بقوله كيف يبقى بدنا نحاول نبينها هذه
+
+476
+00:49:56,720 --> 00:50:03,490
+Proبدي اقول افترض ان Y تساوي U6 بدي اثبت انه
+
+477
+00:50:03,490 --> 00:50:10,770
+مشتقتها بنفسها بقول كويس خد لن للطرفين يبقى بصير
+
+478
+00:50:10,770 --> 00:50:17,070
+ان لن ال Y يساوي لن U6 اللي هو قداش
+
+479
+00:50:22,020 --> 00:50:26,980
+هذه المشتقة ليه واحد على Y في الـ Y' بده يساوي
+
+480
+00:50:26,980 --> 00:50:28,040
+واحد صحيح
+
+481
+00:50:33,530 --> 00:50:40,610
+من هي ال Y؟ هي رأس المسألة اللي هي A أُس X يبقى من
+
+482
+00:50:40,610 --> 00:50:47,350
+الآن فصاعدا مشتقة ال E أُس X هي ال E أُس X itself
+
+483
+00:50:47,350 --> 00:50:54,470
+طيب، هذا لو كان الأُس تبع ال E هو المتغير X فقط،
+
+484
+00:50:54,470 --> 00:51:02,110
+لا غير طب لو أصبح المتغير دالة في Xإذا بدنا نروح
+
+485
+00:51:02,110 --> 00:51:09,730
+نعمم هذه طبق ال let's share rule ونقول if ال U is
+
+486
+00:51:09,730 --> 00:51:15,810
+a differentiable function of X
+
+487
+00:51:18,230 --> 00:51:27,470
+بدنا دي على دي اكس لل EOSU تعطينا EOSU في ال DU
+
+488
+00:51:27,470 --> 00:51:32,730
+على DX طبق اللي تشاهدونه نعطيك توضيح بسيط
+
+489
+00:51:35,650 --> 00:51:44,750
+كمثال على ذلك لو بدنا D على DX لل E أس A X where
+
+490
+00:51:44,750 --> 00:51:46,870
+ال A is constant
+
+491
+00:52:06,920 --> 00:52:15,640
+بإيه؟ طيب هذا بده يقودنا إلى النقطة الرقم سبعة
+
+492
+00:52:15,640 --> 00:52:26,840
+سبعة تكامل EOSXDX مشتقتها نفسها إذا تكاملها نفسها
+
+493
+00:52:26,840 --> 00:52:36,840
+زي ما هو بضيف عليه كنصة Cطيب لو بدى تكامل لل E أُس
+
+494
+00:52:36,840 --> 00:52:46,960
+AX DX يبقى هنا نفسها مقسوما على A زائد constant C
+
+495
+00:52:46,960 --> 00:52:52,120
+يعني في حالة الشيقاق بنضرب في A وفي حالة التكامل
+
+496
+00:52:52,120 --> 00:52:59,640
+بنقسم عالمين على A طيب فى عندي هنا نظرية بسيطة
+
+497
+00:52:59,970 --> 00:53:01,450
+النظرية بتقول
+
+498
+00:53:08,970 --> 00:53:15,030
+بتقول ال E تساوي ال limit لما ال X بدها تروح لل
+
+499
+00:53:15,030 --> 00:53:22,630
+zero لل واحد زائد X كله سواحد على X وتساوي ال
+
+500
+00:53:22,630 --> 00:53:28,010
+limit لما ال Y بدها تروح لل infinity لل واحد زائد
+
+501
+00:53:28,010 --> 00:53:35,510
+واحد على Y كله to the power Y السؤال
+
+502
+00:53:35,510 --> 00:53:42,460
+هو من أين لك هذا؟ما ده من اين لك هذا خلّينا نثبت
+
+503
+00:53:42,460 --> 00:53:50,560
+صحتها تمام يبقى بدنا نثبت ان العدد E هو عبارة عن
+
+504
+00:53:50,560 --> 00:53:54,020
+limit واحد زاد X أس واحد على X لما ال X بدأ تروح
+
+505
+00:53:54,020 --> 00:53:59,420
+لل zero أو limit Y بدأ تروح للملا نهائية واحد زاد
+
+506
+00:53:59,420 --> 00:54:04,930
+واحد على Y كله أس Yخلّينا نثبت الأولى و نثبت
+
+507
+00:54:04,930 --> 00:54:09,790
+الأولى التانية بالصغير تحصيل حصل خلّي بالك معايا
+
+508
+00:54:09,790 --> 00:54:17,470
+الان لو جيت قولتلك خدلي F of X بده يساوي لنا ال X
+
+509
+00:54:17,470 --> 00:54:29,750
+اشتقها يبقى F prime of X يساوي كده؟يبقى f prime of
+
+510
+00:54:29,750 --> 00:54:36,410
+one يبقى
+
+511
+00:54:36,410 --> 00:54:41,850
+هذا اشتقاق عادي جيبناه بدون اي مشاكل طب لو حبيت
+
+512
+00:54:41,850 --> 00:54:49,010
+اشتقه بالتعريف تبع المشتقة اذا باجي بقوله احنا
+
+513
+00:54:49,010 --> 00:54:57,130
+اخدناالـ F prime of one يسوي ال limit لما ال H
+
+514
+00:54:57,130 --> 00:55:03,530
+بدها تروح لل zero لل F of واحد زائد H نقص ال F of
+
+515
+00:55:03,530 --> 00:55:09,670
+واحد على H مش هيك اخدت فكرة كلصية تعريف المشتقلونة
+
+516
+00:55:11,030 --> 00:55:16,790
+أو تعريف المستقل الأولى عند نقطة طبعا بقوله كويس
+
+517
+00:55:16,790 --> 00:55:21,610
+يبقى هذا الكلام بده يساوي ال limit لما ال H بده
+
+518
+00:55:21,610 --> 00:55:28,070
+تروح لل zero ال F of X هي من؟ لن ال X يبقى F of 1
+
+519
+00:55:28,070 --> 00:55:38,670
+زائد H لن 1 زائد H يبقى هذه لن 1زائد H ناقص لإن
+
+520
+00:55:38,670 --> 00:55:44,530
+الواحد كل هذا الكلام على مين؟ على H لإن الواحد
+
+521
+00:55:44,530 --> 00:55:52,070
+بيجداش Zero مع السلامة يبقى آلة المسألة ال F prime
+
+522
+00:55:52,070 --> 00:55:58,450
+of one بيساوي مين؟ limit لما ال H بيذهب ل Zero
+
+523
+00:55:58,450 --> 00:56:11,390
+لواحد على H فلن واحد زائد Hتمام؟ طيب، أليست هذه هي
+
+524
+00:56:11,390 --> 00:56:18,490
+F prime of واحد يسوى واحد؟اللي قال بلى يكف عن شر
+
+525
+00:56:18,490 --> 00:56:26,930
+البلى، بلى بلاء، لغتنا العربية الحقيقة فيها أشياء
+
+526
+00:56:26,930 --> 00:56:32,090
+كثيرة جدا، بدأت تكون صعيبة مثلا، لو واحد سألناه
+
+527
+00:56:32,090 --> 00:56:35,830
+ويعطاني إجابة سديدة، نقول له أه صابت، يبقى مسميه
+
+528
+00:56:35,830 --> 00:56:41,050
+مصيب في الإجابة، تمام؟ ولو كان الطالب، نقول ليه؟
+
+529
+00:56:41,050 --> 00:56:48,290
+انت مصيبةالمصير يعني مشكلة كبيرة جدا، لو كان نائب
+
+530
+00:56:48,290 --> 00:56:52,450
+في البرلمان يقول نائبلو كانت واحدة تقول انها
+
+531
+00:56:52,450 --> 00:56:56,490
+نائبة، نائبة موجودة مصيبة ولا لا ولا لا، لكن الصح
+
+532
+00:56:56,490 --> 00:57:01,370
+ان تقول النائب للذكر والأنثى وان تقول مصيب للذكر
+
+533
+00:57:01,370 --> 00:57:04,430
+والأنثى حتى ما نوجعش في الخطأ، في اللغة، على اي
+
+534
+00:57:04,430 --> 00:57:11,310
+حال. F prime of one يساوي كده؟ يساوي one، يساوي،
+
+535
+00:57:11,310 --> 00:57:18,170
+صح صح معانا كويس، يساوي ال limit لما ال H بدأ تروح
+
+536
+00:57:18,170 --> 00:57:18,770
+لل zero.
+
+537
+00:57:21,490 --> 00:57:29,690
+لمن؟ هذا رقم موجود قبل الـ lin إذا بقدر أحط اس
+
+538
+00:57:29,690 --> 00:57:34,330
+لدالة لجوه الـ lin من خلاص الـ lin صحيح ولا لأ
+
+539
+00:57:34,330 --> 00:57:44,410
+يبقى بصير limit واحد زائد H كل اس واحد على H تمام؟
+
+540
+00:57:44,410 --> 00:57:52,100
+ال lin اه ماكتبناش ال lin لا ولا هم هذه ال linواحد
+
+541
+00:57:52,100 --> 00:58:11,180
+زائد H كل اس واحد على H على
+
+542
+00:58:11,180 --> 00:58:17,780
+أي حالالـ limit معها VIP very important person
+
+543
+00:58:17,780 --> 00:58:22,200
+تتعدى الحدود والقيود والسدود ماحدش بيقدر يمنعها
+
+544
+00:58:22,200 --> 00:58:27,320
+إذن هتدخل داخل مين؟ الـ lin يبقى بقدر أقول إذا
+
+545
+00:58:27,320 --> 00:58:34,340
+الواحد بده يساوي ال lin ل limit لما ال H بده تروح
+
+546
+00:58:34,340 --> 00:58:42,240
+لل zero لل واحد زائد H أس واحد على Hبدي اتخلص من
+
+547
+00:58:42,240 --> 00:58:48,360
+الـ Lin بارفع اتنين كأس للعدد E يبقى E أس واحد
+
+548
+00:58:48,360 --> 00:58:55,200
+يساوي E أس Lin ل limit لما ال H بدها تروح ل Zero
+
+549
+00:58:55,200 --> 00:59:01,920
+لمن؟ لل واحد زائد H أس واحد على H ال E و ال Lin
+
+550
+00:59:01,920 --> 00:59:07,660
+واحدة بتلغي التانيةيبقى ال E limit لما ال H بتروح
+
+551
+00:59:07,660 --> 00:59:16,520
+ل Zero واحد زائد H أس واحد على H تمام على هيك هذا
+
+552
+00:59:16,520 --> 00:59:22,180
+يثبت صحة الكلام حط H حط X حط Z اللي بدركيها لك
+
+553
+00:59:22,180 --> 00:59:30,840
+الجزء الثاني هذا بحصل عليه فقط عشان اقولك potيبقى
+
+554
+00:59:30,840 --> 00:59:39,780
+X يسوى واحد على Y يبقى Y يسوى واحد على X يبقى X
+
+555
+00:59:39,780 --> 00:59:46,820
+يسوى واحد
+
+556
+00:59:46,820 --> 00:59:51,760
+على Y يبقى X يسوى واحد على Y يبقى X يسوى واحد على
+
+557
+00:59:51,760 --> 00:59:53,020
+Y يبقى X يسوى واحد على Y يبقى X يسوى واحد على Y
+
+558
+00:59:53,020 --> 00:59:56,920
+يبقى X يسوى واحد على Y يبقىأس واحد واحد على اكس
+
+559
+00:59:56,920 --> 01:00:04,920
+اللي بمان بالواحد زائد ال X حطيناها بواحد على Y
+
+560
+01:00:04,920 --> 01:00:12,520
+وده كله أس Y لكن يا شباب لما تكون ال Y او واحد على
+
+561
+01:00:12,520 --> 01:00:17,220
+Y بده تروح ل Zero ليش اقلبتها بتصير ال Y بتروح
+
+562
+01:00:17,220 --> 01:00:22,860
+لواحد على صفر اللي بمانب Infinity يبقى هذا بصير
+
+563
+01:00:22,860 --> 01:00:29,320
+limit لما Y بدأ تروح لل Infinity لواحد زائد واحد
+
+564
+01:00:29,320 --> 01:00:34,600
+على Y كل غصوى Y وهو المطول لازلنا في نفس ال
+
+565
+01:00:34,600 --> 01:00:40,100
+section لازلنا في نفس ال section ولما ننتهي بعد
+
+566
+01:00:40,100 --> 01:00:44,400
+للمرة القادمة ان شاء الله تعالى
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/4L2irOydHGA.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/4L2irOydHGA.srt
new file mode 100644
index 0000000000000000000000000000000000000000..10f0fb1b605e2678970e845c00847edc6c4c14f2
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/4L2irOydHGA.srt
@@ -0,0 +1,2071 @@
+1
+00:00:10,020 --> 00:00:15,610
+بسم الله الرحمن الرحيم مواصلة ما ابتدأنا به في المرة
+
+2
+00:00:15,610 --> 00:00:20,670
+الماضية وهو موضوع ال power series طبعًا ابتدينا
+
+3
+00:00:20,670 --> 00:00:25,230
+فيه المرة الماضية وأخذنا على ذلك أربعة أمثلة و
+
+4
+00:00:25,230 --> 00:00:29,950
+بنعطي الآن مثالًا بشكل آخر غير الأشكال الأربعة اللي
+
+5
+00:00:29,950 --> 00:00:34,790
+شفناها في المرة الماضية المثال بقول ما يأتي هات لي
+
+6
+00:00:34,790 --> 00:00:40,250
+فترة التقارب لل power series اللي قدامنا هذه and 
+
+7
+00:00:40,250 --> 00:00:44,290
+find the sum of the series as a function وهات لي
+
+8
+00:00:44,290 --> 00:00:49,170
+مجموع هذه المتسلسلة كدالة يبقى في الأول بدنا نروح
+
+9
+00:00:49,170 --> 00:00:55,650
+نجيب فترة التقارب لهذه ال series يبقى solution
+
+10
+00:00:58,390 --> 00:01:02,470
+حابين نتعرف على شكل ال series فبجي بقول summation
+
+11
+00:01:02,470 --> 00:01:07,330
+من N equal zero to infinity لل X تربيع زائد واحد 
+
+12
+00:01:07,330 --> 00:01:13,250
+على ثلاثة to the power N الحد الأول بواحد الحد
+
+13
+00:01:13,250 --> 00:01:19,110
+الثاني X تربيع زائد واحد على ثلاثة الحد الثاني X
+
+14
+00:01:19,110 --> 00:01:24,220
+تربيع زائد واحد على ثلاثة لكل تربيع بنبقى ماشي
+
+15
+00:01:24,220 --> 00:01:30,500
+لغاية ما نوصل ل X تربيع زائد واحد على ثلاثة كله to
+
+16
+00:01:30,500 --> 00:01:38,080
+the power N زائد إلى آخرين يبقى كتبنا ال series
+
+17
+00:01:38,080 --> 00:01:42,560
+على الشكل اللي قدامنا السؤال هو هل هذه ال series هل هي
+
+18
+00:01:42,560 --> 00:01:46,040
+من ال series الثلاث المشهورة اللي كنا بنتعامل
+
+19
+00:01:46,040 --> 00:01:51,770
+معاها طيلة هذا ال chapter بالمرة النهائية يعني هذه
+
+20
+00:01:51,770 --> 00:01:55,070
+ليست Geometric ليست P Series ليست Harmonic؟
+
+21
+00:01:55,070 --> 00:02:00,310
+Geometric يعني يعني هي واحدة منها من الثلاث اقسم
+
+22
+00:02:00,310 --> 00:02:05,110
+الحد هذا على هذا كده إيش بيطلع الجواب أكثر بها زي
+
+23
+00:02:05,110 --> 00:02:07,950
+واحدة على ثلاثة اقسم هذا على هذا أكثر بها زي
+
+24
+00:02:07,950 --> 00:02:12,050
+واحدة على ثلاثة يعني كده إذا هذه Geometric Series
+
+25
+00:02:12,050 --> 00:02:17,500
+Converged إذا كان الأساس تبعها هذا ماله أقل من
+
+26
+00:02:17,500 --> 00:02:25,200
+الواحد الصحيح يبقى هذه Convergent Geometric Series
+
+27
+00:02:25,200 --> 00:02:33,660
+إذا كان absolute value لل R لو بدي أسوي absolute
+
+28
+00:02:33,660 --> 00:02:39,380
+value لإكس تربيع زائد واحد على ثلاثة أقل من مين؟ أقل
+
+29
+00:02:39,380 --> 00:02:44,840
+من واحد طيب هذه عمرها بتاخد قيمة سالبة تقول
+
+30
+00:02:44,840 --> 00:02:49,020
+absolute value كتبناها والله شيلناها سياد يبقى هذا
+
+31
+00:02:49,020 --> 00:02:54,900
+معناه أن ال X تربيع زائد واحد على ثلاثة أقل من مهم
+
+32
+00:02:54,900 --> 00:03:00,980
+أقل من الواحد أو إن شئتم فقولوا أن هذه convert
+
+33
+00:03:00,980 --> 00:03:10,310
+geometric إذا كان ال X تربيع زائد واحد أقل من من
+
+34
+00:03:10,310 --> 00:03:18,590
+ثلاثة وإن شئتم فقولوا X تربيع أقل من اثنين وإذا
+
+35
+00:03:18,590 --> 00:03:23,570
+أخذنا الجذر التربيعي بيصير absolute value ل X أقل من
+
+36
+00:03:23,570 --> 00:03:28,730
+square root للاثنين يبقى باجي بقول له the series
+
+37
+00:03:28,730 --> 00:03:39,070
+converge on the interval على الفترة هذه إيش
+
+38
+00:03:39,070 --> 00:03:44,910
+معناها؟ X محصورة من سالب جذر اثنين وجذر اثنين، إذا
+
+39
+00:03:44,910 --> 00:03:52,380
+على الفترة من سالب جذر اثنين إلى جذر اثنين يبقى أنت
+
+40
+00:03:52,380 --> 00:03:56,520
+هنا من المطلوب الأول قال لي هات لي فترة التقارب لل
+
+41
+00:03:56,520 --> 00:04:05,720
+power series اللي عندنا أيوة السؤال
+
+42
+00:04:05,720 --> 00:04:10,280
+بيسأل بيقول أنت كانت بفترة مفتوحة بنعرفش تكون مغلقة
+
+43
+00:04:10,280 --> 00:04:15,740
+بنقول له تعالى نشوف بنفعله بنفعش إيش سميناها ال
+
+44
+00:04:15,740 --> 00:04:20,060
+series هذه؟ Geometric وانتش ال geometric converge
+
+45
+00:04:22,530 --> 00:04:30,510
+طب لو كانت تساوي واحد يعني بنفع نجلها هي؟ هي بنفع؟
+
+46
+00:04:30,510 --> 00:04:36,450
+خلاص ما يبقى مينفعش ليش؟ لأنه إذا كانت أكبر من أو
+
+47
+00:04:36,450 --> 00:04:40,230
+تساوي واحد ال series مالها؟ بي vary بقدرش أقول
+
+48
+00:04:40,230 --> 00:04:45,170
+closed interval وإنما بقول open interval طب
+
+49
+00:04:45,170 --> 00:04:48,730
+انتهينا من المطلب الأول المطلب الثاني بيقول لي على فترة
+
+50
+00:04:48,730 --> 00:04:54,410
+التقارب هذه بتجيب لي المجموع تبع السيريز هذه as a
+
+51
+00:04:54,410 --> 00:05:03,270
+function باجيب أقول له it's sum المجموع تبعها as بدي
+
+52
+00:05:03,270 --> 00:05:09,330
+أديله capital S capital S يساوي الحد الأول على
+
+53
+00:05:09,330 --> 00:05:14,970
+واحد ناقص الأساس الأساس يقول X تربيع زائد واحد
+
+54
+00:05:14,970 --> 00:05:22,000
+على ثلاثة هذه هي اللي هي بدها تساوي من ثلاثة على
+
+55
+00:05:22,000 --> 00:05:29,280
+مين؟ على ثلاثة ناقص X تربيع ناقص واحد أو إن شئتم 
+
+56
+00:05:29,280 --> 00:05:37,700
+فقولوا ثلاثة على اثنين ناقص X تربيع سؤال هو أليست
+
+57
+00:05:37,700 --> 00:05:45,500
+هذه function في X يبقى بناء عليه المجموعة S as a
+
+58
+00:05:45,500 --> 00:05:51,480
+function of X فالـ F of X بدّه يساوي ثلاثة على
+
+59
+00:05:51,480 --> 00:05:58,920
+الاثنين ناقص X تربيع المطلوب الثاني من المثال
+
+60
+00:06:01,980 --> 00:06:06,340
+الآن انتهينا من الجزء الأول من هذا ال section بدنا
+
+61
+00:06:06,340 --> 00:06:10,500
+ننتقل إلى الجزء الثاني الجزء الثاني من هذا ال
+
+62
+00:06:10,500 --> 00:06:14,960
+section هو differentiation term by term and
+
+63
+00:06:14,960 --> 00:06:22,620
+integration term by term يبقى بدنا نيجي اللي هو
+
+64
+00:06:22,620 --> 00:06:27,100
+differentiation term by term بالنسبة لل power
+
+65
+00:06:27,100 --> 00:06:35,000
+series يبقى باجي بقول له term by term
+
+66
+00:06:35,000 --> 00:06:42,800
+differentiation theorem
+
+67
+00:06:47,600 --> 00:06:55,200
+النص التالي F summation من N equal zero to
+
+68
+00:06:55,200 --> 00:07:04,360
+infinity ل C N X نقص ال A to the power N converge
+
+69
+00:07:04,360 --> 00:07:12,900
+for ال A نقص ال R أقل من X أقل من ال A زائد ال R
+
+70
+00:07:12,900 --> 00:07:15,880
+for some
+
+71
+00:07:17,290 --> 00:07:31,270
+اللي greater than zero it defines بتعرف
+
+72
+00:07:31,270 --> 00:07:40,410
+a function هنسميها f of x تساوي هذا ال summation
+
+73
+00:07:40,410 --> 00:07:46,050
+اللي عندنا summation من n equal zero to infinity
+
+74
+00:07:46,560 --> 00:07:54,940
+للـCN الـ X نقص الـ A to the power M والـ X بتتحرك
+
+75
+00:07:54,940 --> 00:08:04,280
+في الفترة من الـ A سالب R إلى الـ A plus R This
+
+76
+00:08:04,280 --> 00:08:14,350
+function has a derivatives Has derivatives of all
+
+77
+00:08:14,350 --> 00:08:19,650
+orders
+
+78
+00:08:19,650 --> 00:08:31,670
+من كل الرتب Inside the interval of convergence
+
+79
+00:08:44,360 --> 00:08:49,660
+interval of convergence as follow كتابة
+
+80
+00:09:25,800 --> 00:09:28,920
+النقطة الأولى هي term by term differentiation
+
+81
+00:09:28,920 --> 00:09:33,060
+theorem والنقطة الثانية term by term integration
+
+82
+00:09:33,060 --> 00:09:38,300
+theorem خلينا مع النقطة الأولى في الأول فباجي
+
+83
+00:09:38,300 --> 00:09:42,700
+بقول لو كانت ال series اللي عندنا هذه convert على
+
+84
+00:09:42,700 --> 00:09:48,640
+الفترة اللي عندنا من a-r أو ال x محصورة من a-r والـ
+
+85
+00:09:48,640 --> 00:09:53,160
+A زائد R إذا بتذكروا وإحنا لما اتكلمنا في الجزء
+
+86
+00:09:53,160 --> 00:09:58,060
+النظري تبع ال power series نقول لو عندنا فترة زي
+
+87
+00:09:58,060 --> 00:10:05,080
+الفترة هذه وأجت A في منتصف الفترة كان هذا نصف قطر
+
+88
+00:10:05,080 --> 00:10:11,380
+التقارب R وهذا نصف قطر التقارب R يبقى إحداثيات
+
+89
+00:10:11,380 --> 00:10:18,180
+النقطة هذه A زائد R وإحداثيات النقطة هذه لإيه
+
+90
+00:10:18,180 --> 00:10:24,220
+الناقصات بعد النقطة هذه ال series مختلفة وقبل
+
+91
+00:10:24,220 --> 00:10:29,160
+النقطة هذه ال series كذلك مختلفة وفي الداخل هنا ال
+
+92
+00:10:29,160 --> 00:10:34,090
+series مالها؟ مختلفة بالشكل اللي عندنا هذا فبقول لو
+
+93
+00:10:34,090 --> 00:10:37,510
+ال series converge على الفترة اللي عندنا هذه it
+
+94
+00:10:37,510 --> 00:10:43,170
+defines a function يعني ال series هذه يمكن كتابتها
+
+95
+00:10:43,170 --> 00:10:48,230
+على شكل function f of x تساوي هذا ال summation
+
+96
+00:10:48,230 --> 00:10:52,450
+صارت هذه فترة التقارب لهذه الدالة اللي هي تعتبر
+
+97
+00:10:52,450 --> 00:10:59,180
+domain لمين؟ Domain للدالة F of X يعني إحنا لأن
+
+98
+00:10:59,180 --> 00:11:05,200
+كتبنا ال function على شكل power series بقول لي هذه
+
+99
+00:11:05,200 --> 00:11:11,260
+الدالة لها مشتقات من جميع الرتب خلال فترة التقارب
+
+100
+00:11:11,350 --> 00:11:17,250
+تبع السيريز كيف؟ كالتالي يبقى إحنا لو جينا وقلنا
+
+101
+00:11:17,250 --> 00:11:24,830
+هذا ال F of X اللي تساوي ال summation يبقى C0 زائد
+
+102
+00:11:24,830 --> 00:11:34,620
+C1 في X نقص ال A زائد C2 في X نقص A لكل تربيع زائد C3
+
+103
+00:11:34,620 --> 00:11:44,200
+في X نقص A لكل تكعيب زائد زائد CN في X نقص A to the
+
+104
+00:11:44,200 --> 00:11:50,430
+power N زائد الآخرين يبقى هذا الـ function كتبناها
+
+105
+00:11:50,430 --> 00:11:54,090
+على شكل ال power series اللي قدامي يعني اللي أنا
+
+106
+00:11:54,090 --> 00:12:00,690
+بدي أبدأ اشتق لو قلت f prime of x يبقى الأول هذا
+
+107
+00:12:00,690 --> 00:12:07,870
+مشتقته بقداش؟ مش هيظهر عندي C1 مقدار ثابت الـA
+
+108
+00:12:07,870 --> 00:12:15,010
+مشتقتها بـ0 مشتقة الـX بـ1 في C1 مقدار ثابت C1 فقط
+
+109
+00:12:15,010 --> 00:12:23,690
+C2 مقدار ثابت يبقى الأس في القوس مرفوع لنفس الأس
+
+110
+00:12:23,690 --> 00:12:27,810
+مطروح منه واحد في تفاضل مداخل القوس اللي هو مقدار
+
+111
+00:12:27,810 --> 00:12:29,210
+ثابت C1 مقدار ثابت C2 مقدار ثابت C1 مقدار ثابت C2
+
+112
+00:12:29,210 --> 00:12:33,130
+مقدار ثابت C2 مقدار ثابت C2 مقدار ثابت C2 مقدار
+
+113
+00:12:33,130 --> 00:12:34,210
+ثابت C2 مقدار ثابت C2 مقدار ثابت C2 مقدار ثابت C2
+
+114
+00:12:34,210 --> 00:12:36,110
+ثابت C2 مقدار ثابت C2 مقدار ثابت C2 مزيد ثلاثة C
+
+115
+00:12:36,110 --> 00:12:42,050
+ثلاثة X ناقص ال A لكل تربيع في مشتقة مداخل القوس
+
+116
+00:12:42,050 --> 00:12:51,030
+اللي هو بقداش؟ بواحد زائد زائد N CN X ناقص ال A to
+
+117
+00:12:51,030 --> 00:12:58,070
+the power N زائد واحد زائد الآخرين يبقى هذا الشغل
+
+118
+00:12:58,070 --> 00:13:04,570
+اللي اشتغلنا اسمه differentiation term by term يبقى
+
+119
+00:13:04,570 --> 00:13:09,510
+روحنا اشتقينا term by term كل series لغاية
+
+120
+00:13:09,510 --> 00:13:14,050
+infinitive شو رأيك إني بقدر أكتب هذه المشتقة على
+
+121
+00:13:14,050 --> 00:13:18,430
+شكل power series بدل ما هي بالشكل الكبير بدي
+
+122
+00:13:18,430 --> 00:13:24,490
+أكتبها بالشكل الجديد يبقى summation وبروح بحط
+
+123
+00:13:24,490 --> 00:13:31,220
+الحد النوني N في CN في ال X ناقص ال A to the power
+
+124
+00:13:31,220 --> 00:13:36,380
+N زائد واحد من عند ال N تساوي أكثر قدره لغاية
+
+125
+00:13:36,380 --> 00:13:41,440
+Infinity من أين بدنا نبدأ؟ من عندها تساوي قدره؟ 
+
+126
+00:13:41,440 --> 00:13:48,770
+متأكدين؟ فما هو السبب؟ أنا موافق، بس ليش؟ أيوة لأن
+
+127
+00:13:48,770 --> 00:13:52,730
+الحد الأول هذا طارِ يعني ال series نقصت حدًّا من 
+
+128
+00:13:52,730 --> 00:13:58,770
+بداية ال series ومشان تتأكد ابدأ حط n بواحد اثنين
+
+129
+00:13:58,770 --> 00:14:02,130
+ثلاثة في الصيغة اللي عندك شوف يطلع ال series اللي
+
+130
+00:14:02,130 --> 00:14:08,190
+عندنا هذه ولا لأ فمثلا لو قلنا n بواحد C واحد ودق
+
+131
+00:14:08,190 --> 00:14:14,670
+ال zero اللي بواحد يبقى الجواب بس جديد C واحد حط n 
+
+132
+00:14:14,670 --> 00:14:25,110
+بـ 2 بصير 2C2 X ناقص A و S 1 يبقى 2C2 X ناقص A 2C2
+
+133
+00:14:25,110 --> 00:14:25,830
+X ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص A
+
+134
+00:14:25,830 --> 00:14:27,450
+2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص
+
+135
+00:14:27,450 --> 00:14:28,530
+A 2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2
+
+136
+00:14:28,530 --> 00:14:28,610
+ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2
+
+137
+00:14:28,610 --> 00:14:33,930
+2C2 X ناقص A 2C2
+
+138
+00:14:33,930 --> 00:14:39,130
+X ناقص A
+
+139
+00:14:39,130 --> 00:14:40,590
+2
+
+140
+00:14:45,040 --> 00:14:50,840
+سي واحد مقدار ثابت يبقى مشتقته مع السلامة بصير هذا
+
+141
+00:14:50,840 --> 00:14:58,320
+اثنين سي اثنين زائد ستة سي ثلاثة في ال X نقص ال A
+
+142
+00:14:58,320 --> 00:15:06,520
+زائد زائد N في N نقص واحد في C N في ال X نقص ال A
+
+143
+00:15:06,520 --> 00:15:12,320
+تدفع power N زائد اثنين زائد الآخرين نبدأ نكتب هذا
+
+144
+00:15:12,320 --> 00:15:18,740
+على شكل summation من N تساوي أبصر قداش لغاية ال
+
+145
+00:15:18,740 --> 00:15:26,560
+infinity لل N في ال N ناقص واحد في ال C N في ال X
+
+146
+00:15:26,560 --> 00:15:35,160
+ناقص ال A to the power N minus two N من وين؟ من
+
+147
+00:15:35,160 --> 00:15:41,340
+عند اثنين متأكدين؟ آه من عند اثنين لأنه طارت term
+
+148
+00:15:41,340 --> 00:15:46,120
+الأول لأن هذا راح طيب شوف تعال تأكد كلامنا صح ولا
+
+149
+00:15:46,120 --> 00:15:50,640
+لأ اثنين اثنين ناقص واحدة بواحد يبقى هذا كله
+
+150
+00:15:50,640 --> 00:15:55,300
+بـ اثنين سي اثنين وهذا zero يبقى واحد يبقى الحد
+
+151
+00:15:55,300 --> 00:16:00,960
+الأول اثنين سي اثنين مظبوط بعد اثنين حط ثلاثة بصير
+
+152
+00:16:00,960 --> 00:16:12,520
+ثلاثة في اثنين اللي هو بستة C3X-A1 يبقى 6C3X-A1
+
+153
+00:16:12,520 --> 00:16:17,320
+وهكذا يبقى شغلنا سليم مائة بالمائة بنطلع من هذا
+
+154
+00:16:17,320 --> 00:16:22,820
+الكلام يبقى أنه عند الاشتقاق مرة ال index اللي تحت
+
+155
+00:16:22,820 --> 00:16:27,280
+ال summation بينقص واحد اشتق كمان مرة، بنقص كمان واحد،
+
+156
+00:16:27,280 --> 00:16:31,440
+اشتق كمان مرة، بنقص كمان واحد، وهكذا يعني لو
+
+157
+00:16:31,440 --> 00:16:37,140
+اشتقيت N من ال K من المرات بيصير ال summation هذا
+
+158
+00:16:37,140 --> 00:16:43,620
+من عند N تساوي K إلى Infinity وهذا بيصير K من
+
+159
+00:16:43,620 --> 00:16:50,020
+المشتقات، تمام؟ طيب كويس، وهكذا لو استمرنا بهذه
+
+160
+00:16:50,020 --> 00:16:55,390
+الطريقة، فمش بدنا نوصل ل R صار عندنا two series
+
+161
+00:16:55,390 --> 00:17:01,590
+جداد وعندنا ال series الأصلية هي هذي converge على
+
+162
+00:17:01,590 --> 00:17:06,720
+الفترة اللي عندنا هذي السيريز المشتقة التنتين هدول
+
+163
+00:17:06,720 --> 00:17:11,380
+converge على نفس الفترة وكمان لو اشتقت مئة مرة
+
+164
+00:17:11,380 --> 00:17:16,680
+كمان بعد ذلك برضه converge على مين يبقى ال series
+
+165
+00:17:16,680 --> 00:17:24,200
+الأصلية ومشتقتها converge على نفس الفترة يبقى بدنا
+
+166
+00:17:24,200 --> 00:17:27,740
+نشيل هذا بما يأتي فبروح بقول
+
+167
+00:17:34,410 --> 00:17:41,350
+هذه الـ derived كل
+
+168
+00:17:41,350 --> 00:17:46,510
+واحد من هذه السلسلة الوحيدة الوحيدة
+
+169
+00:17:46,510 --> 00:17:54,250
+الوحيدة موجودة في كل موقع
+
+170
+00:17:54,250 --> 00:17:57,570
+في كل
+
+171
+00:17:57,570 --> 00:17:58,350
+موقع في كل موقع في كل موقع
+
+172
+00:18:08,230 --> 00:18:15,550
+مقارنة مقارنة مقارنة مقارنة مقارنة
+
+173
+00:18:24,950 --> 00:18:32,430
+original series يبقى كل من المتسلسلات المشتقة
+
+174
+00:18:32,430 --> 00:18:36,670
+converge على نفس الفترة الاساسية الأصلية converge
+
+175
+00:18:36,670 --> 00:18:43,630
+عليها نبدأ نيجي للنقطة الثانية والأخيرة في هذا ال
+
+176
+00:18:43,630 --> 00:18:50,770
+section term by term integration theorem بعد ما
+
+177
+00:18:50,770 --> 00:18:54,030
+فاضلنا بدنا نروح هنا نكامل
+
+178
+00:18:58,810 --> 00:19:05,930
+بقول افترض أن suppose that suppose
+
+179
+00:19:05,930 --> 00:19:12,350
+that ال F of X بده تساوي ال summation من N equal
+
+180
+00:19:12,350 --> 00:19:19,490
+zero to infinity ل C N X نقص ال A to the power N
+
+181
+00:19:19,490 --> 00:19:30,510
+converged for X اللي هي أكبر من ال A ناقص ال R وأقل
+
+182
+00:19:30,510 --> 00:19:38,270
+من ال A زائد ال R وال R greater than zero
+
+183
+00:20:02,330 --> 00:20:09,770
+نفس الفترة اللي عندنا هذه الـ A ناقص الـ R إلى
+
+184
+00:20:09,770 --> 00:20:19,270
+الـ A زائد R and وفي نفس الوقت تكامل لل F of X DX
+
+185
+00:20:19,270 --> 00:20:25,890
+بدي يساوي اللي هو summation من N equal zero to
+
+186
+00:20:25,890 --> 00:20:35,140
+infinity لمين؟ للـCN X ناقص الـ A to the power n
+
+187
+00:20:35,140 --> 00:20:42,740
+plus one على n plus one plus constant c على نفس
+
+188
+00:20:42,740 --> 00:20:53,220
+الفترة اللي هو من a ناقص r إلى a زائد r examples
+
+189
+00:20:53,220 --> 00:20:59,040
+consider
+
+190
+00:20:59,040 --> 00:20:59,960
+the function
+
+191
+00:21:04,680 --> 00:21:12,160
+يعتبر الدالة EO6 يساوي summation من N equal zero
+
+192
+00:21:12,160 --> 00:21:17,980
+to infinity للـ x to the power n على n factorial
+
+193
+00:21:17,980 --> 00:21:25,260
+اللي هي واحد زائد x زائد x تربيع على اثنين factorial x
+
+194
+00:21:25,260 --> 00:21:30,100
+تكعيب على ثلاثة factorial زائد x أس n على n
+
+195
+00:21:30,100 --> 00:21:41,040
+factorial زائد الآخرين that converge for all x
+
+196
+00:21:42,530 --> 00:21:53,770
+المطلوب الأول show that بيّن لي أن مشتقة ال EO6 بده
+
+197
+00:21:53,770 --> 00:22:04,190
+تساوي ال EO6 نمرا بيه show that بيّن لي تكامل ال EO6
+
+198
+00:22:04,190 --> 00:22:09,830
+DX بده يساوي ال EO6 زائد constant C
+
+199
+00:22:38,330 --> 00:22:43,830
+إحنا هنا كنا بنتكلم عن الاشتقاق لل power series و
+
+200
+00:22:43,830 --> 00:22:48,930
+as a function محطوطة ال series اللي عندنا as a
+
+201
+00:22:48,930 --> 00:22:53,170
+function على الشكل اللي عندنا هذا اشتقينا مرة و
+
+202
+00:22:53,170 --> 00:22:57,930
+مرتين وفي كل مرة بتغير ال index اللي تحت ال
+
+203
+00:22:57,930 --> 00:23:04,550
+summation كل اشتقاق بنقص ال index بمقدار واحد ال
+
+204
+00:23:04,550 --> 00:23:08,730
+series المشتقة وال series الأصلية كلهم converge
+
+205
+00:23:08,730 --> 00:23:13,530
+على نفس الفترة تعليل ال integration term by term
+
+206
+00:23:14,010 --> 00:23:20,430
+يعني بدنا نكامل كل term من حدود ال series ونعرف ما
+
+207
+00:23:20,430 --> 00:23:25,870
+هو شكل ال series الناتجة يفترض أن ال F of X مكتوبة
+
+208
+00:23:25,870 --> 00:23:30,190
+عندي على شكل summation بهذا الشكل طبعًا يمكن
+
+209
+00:23:30,190 --> 00:23:35,420
+تستغربوا أن ال function مكتوبة على شكل summation
+
+210
+00:23:35,420 --> 00:23:40,680
+بهذا الشكل ولا تستغرب ولا حاجة المحاضرة القادمة إن
+
+211
+00:23:40,680 --> 00:23:45,720
+شاء الله يعني ال section القادم كله كيفية كتابة ال
+
+212
+00:23:45,720 --> 00:23:50,780
+functions على شكل power series وهذه اللي بنسميها
+
+213
+00:23:50,780 --> 00:23:56,430
+taylor series و maclaurin series يبقى افترض أنه
+
+214
+00:23:56,430 --> 00:23:59,870
+عنده function محطوط على شكل power series وهذي ت
+
+215
+00:23:59,870 --> 00:24:03,430
+converge على نفس الفترة اللي عندنا هذي then
+
+216
+00:24:03,430 --> 00:24:08,710
+summation على ال series هذي هذي شو بتفرق عن هذي سي
+
+217
+00:24:08,710 --> 00:24:13,250
+إن مقدار ثابت زي ما هو يبقى أرفعنا للأس واحدة وقسمنا
+
+218
+00:24:13,250 --> 00:24:18,570
+عليها على الأس الجديد يبقى كأنه إيش عملنا
+
+219
+00:24:18,570 --> 00:24:24,190
+لهذه عاملنا لها تكامل كأنه كاملناها يبقى ال series
+
+220
+00:24:24,190 --> 00:24:30,050
+هذي converge على نفس الفترة وبالتالي تكامل لل f of
+
+221
+00:24:30,050 --> 00:24:34,490
+x dx يساوي النتيجة اللي عندنا هذي بالضبط تمامًا زائد
+
+222
+00:24:34,490 --> 00:24:39,770
+constant زائد constant وعلى نفس ال interval اللي عندنا
+
+223
+00:24:42,060 --> 00:24:46,560
+بناخذ أمثلة على ال differentiation term by term و
+
+224
+00:24:46,560 --> 00:24:52,420
+ال integration term by term سواء جلي أو مجليش يعني
+
+225
+00:24:52,420 --> 00:24:54,740
+مجليش استخدم ال differentiation أو استخدم ال
+
+226
+00:24:54,740 --> 00:24:59,730
+integration أو أطالي مثلًا وبده حل بقول هنا اعتبر
+
+227
+00:24:59,730 --> 00:25:03,530
+الدالة EO6 مكتوبة على شكل ال summation اللي عندنا
+
+228
+00:25:03,530 --> 00:25:07,770
+هذا أو ال summation الطويل اللي عندنا هذا بقول
+
+229
+00:25:07,770 --> 00:25:10,910
+كويسة اللي بتبقى converge على كل ال real line
+
+230
+00:25:10,910 --> 00:25:15,070
+بالاستثناء يعني ال interval of convergence من سالب
+
+231
+00:25:15,070 --> 00:25:19,370
+infinity إلى infinity وإحنا شوفنا في ال power
+
+232
+00:25:19,370 --> 00:25:23,510
+series ممكن تكون ال series converge على كل ال real
+
+233
+00:25:23,510 --> 00:25:28,890
+line بلا ستة نار المطلوب الأول بيقول إن مشتقة ال
+
+234
+00:25:28,890 --> 00:25:34,430
+EO6 هي ال EO6 itself طب هذا خدناه أين؟
+
+235
+00:25:42,900 --> 00:25:46,640
+أثبتنا إن مشتقة الـ EO6 هي الـ EO6 بس عن طريق الـ
+
+236
+00:25:46,640 --> 00:25:51,240
+LEN هنا لا بدك تثبت عن طريق الـ Power Series اثنين
+
+237
+00:25:51,240 --> 00:25:57,100
+بدك تثبت تكامل الـ EO6 هو بالـ EO6 itself زائد كنصة
+
+238
+00:25:57,100 --> 00:26:02,280
+برضه باستخدام من الـ Power Series نقول كويس خلينا
+
+239
+00:26:02,280 --> 00:26:10,360
+نمسك الأولى يبقى بداش أقول له D على D لل E وال 6
+
+240
+00:26:10,360 --> 00:26:15,940
+يساوي بدي اشتق معناته هذه يعني بدي اشتق كل
+
+241
+00:26:15,940 --> 00:26:21,740
+الحدود اللي عندنا مشتقة الواحد بقداش؟ صفر هذا،
+
+242
+00:26:21,740 --> 00:26:30,240
+مشتقة ال X بواحد؟ اللي بعده 2x على 2 factorial زائد
+
+243
+00:26:30,240 --> 00:26:38,380
+2x على 2 factorial زائد 3x تربيع على 3 factorial
+
+244
+00:26:38,380 --> 00:26:45,920
+زائد n x أُس n ناقص واحد على n factorial زائد إلى
+
+245
+00:26:45,920 --> 00:26:54,760
+آخرهم طيب تمام يبقى صار عندي D على DX لل EO6 يساوي
+
+246
+00:26:54,760 --> 00:27:03,400
+واحد زائد هذه لو فكيتها عبارة عن اثنين في واحد factorial هذه ثلاثة في اثنين factorial هذه N
+
+247
+00:27:03,400 --> 00:27:10,100
+في N ناقص واحد factorial يبقى الاثنين هتروح مع
+
+248
+00:27:10,100 --> 00:27:15,760
+اثنين والثلاثة هتروح مع الثلاثة يبقى بيظل عندي
+
+249
+00:27:15,760 --> 00:27:20,840
+زائد x على واحد factorial زائد x تربيع على اثنين
+
+251
+00:27:26,340 --> 00:27:32,660
+factorial زائد x تكعيب على ثلاثة factorial زائد
+
+252
+00:27:32,660 --> 00:27:40,770
+زائد بتروح الـ N مع الـ N يبقى X أس N minus الـ one N
+
+253
+00:27:40,770 --> 00:27:48,810
+minus الـ one factorial بالشكل اللي عندنا هنا زائد
+
+254
+00:27:48,810 --> 00:27:54,350
+إلى آخره يبقى الـ N بتروح اكتبها على شكل summation
+
+255
+00:27:54,350 --> 00:27:58,530
+يبقى لو كتبتها على شكل summation بده يصير
+
+256
+00:27:58,530 --> 00:28:07,410
+summation للحد هنا x أُس n-1 على n-1 factorial
+
+257
+00:28:07,410 --> 00:28:10,950
+بالشكل اللي عندنا هذا طب الـ index اللي تحت الـ
+
+258
+00:28:10,950 --> 00:28:15,380
+summation من وين بده يبدأ؟ عند الواحدة لو أصلا عندي
+
+259
+00:28:15,380 --> 00:28:21,580
+zero طار أول term يبقى summation من N equal one to
+
+260
+00:28:21,580 --> 00:28:26,120
+infinity بالفعل لو بدأت أحط N بواحد و اثنين و
+
+261
+00:28:26,120 --> 00:28:31,320
+ثلاثة بلاقي الـ series اللي عندنا هذه يبقى لا يزال
+
+262
+00:28:31,320 --> 00:28:35,720
+المشكلة عندنا قائمة هل الـ summation اللي احنا
+
+263
+00:28:35,720 --> 00:28:41,680
+كتبناه هو الـ E و الـ six اللي احنا حكينا عليها هذه
+
+264
+00:28:43,190 --> 00:28:48,910
+هي بالضبط و الله في خلاف اه في خلاف الـ index اللى
+
+265
+00:28:48,910 --> 00:28:53,630
+فوق بيبدأ من عند الـ zero هذا الـ index بيبدأ من وين
+
+266
+00:28:53,630 --> 00:28:58,990
+من عند الـ واحد ما نفعش بدها تتساوي بها بدها تكون
+
+267
+00:28:58,990 --> 00:29:07,790
+زيها رسمًا بنقوله كويس إذا أصبح عندي D على DX للـ
+
+268
+00:29:07,790 --> 00:29:15,420
+EO6 يساوي طلّال الـ summation هذاممكن أخليه يبدأ
+
+269
+00:29:15,420 --> 00:29:20,240
+من اندزيرو لو شيلت كل N وحطيت مكانها N زائد واحد
+
+270
+00:29:20,240 --> 00:29:24,540
+يبقى بدي أشيل كل N وحط مكانها N زائد واحد ده يصير
+
+271
+00:29:24,540 --> 00:29:31,310
+N زائد واحد تساوي واحد الى infinity لل X أُس N زائد
+
+272
+00:29:31,310 --> 00:29:36,750
+واحد وين ناقص واحد على N زائد واحد ناقص واحد
+
+273
+00:29:36,750 --> 00:29:42,390
+factorial يبقى هذه الـ summation من عند N equal
+
+274
+00:29:42,390 --> 00:29:47,350
+zero to infinity لل X to the power N على N
+
+275
+00:29:47,350 --> 00:29:52,270
+factorial بروح واحد وسالب واحد وفوق واحد وسالب واحد
+
+276
+00:29:52,730 --> 00:29:57,310
+مين هي هذه؟ مش هذه الصيغة لأن هذه بالضبط تماما
+
+277
+00:29:57,310 --> 00:30:04,570
+يبقى هذه بدها تعطينا مين؟ EO6 وكأن هذا برهان آخر
+
+278
+00:30:04,570 --> 00:30:10,050
+ليثبت أن الـ derivative لل EO6 بيعطينا مين؟ EO6
+
+279
+00:30:10,050 --> 00:30:19,720
+itself خلص المطلوب A، روح للمطلوب B بنتكامل لل E أس
+
+280
+00:30:19,720 --> 00:30:26,040
+X DX يبقى تكامل بدنا نشيل الـ E أس X ونحط المفكوك
+
+281
+00:30:26,040 --> 00:30:30,980
+تبعها اللي هو واحد زائد X زائد X تربيع على اثنين
+
+282
+00:30:30,980 --> 00:30:37,020
+factorial X تكعيب على ثلاثة factorial زائد X أس N
+
+283
+00:30:37,020 --> 00:30:41,980
+على N factorial زائد إلى ما شاء الله كله بالنسبة
+
+284
+00:30:41,980 --> 00:30:50,780
+لمن؟ إلى DX إذا أصبح تكامل ال EOSX DX بده يساوي
+
+285
+00:30:50,780 --> 00:30:57,820
+بدنا نكامل الحد الأول تكامله كده؟ الثاني X تربيع
+
+286
+00:30:57,820 --> 00:31:03,160
+على اثنين ثالث X تكعيب على ثلاثة في الاثنين
+
+287
+00:31:03,160 --> 00:31:08,920
+factorial كما هي زيد الـ X ثلاثة بيصير X أس أربعة
+
+288
+00:31:08,920 --> 00:31:15,780
+على أربعة في ثلاثة factorial كما هي زيد X أس N
+
+289
+00:31:15,780 --> 00:31:22,520
+plus one على N plus one في الـ N factorial زيد إلى
+
+290
+00:31:22,520 --> 00:31:30,220
+آخرى وهذه بيجيها كمان جداش يا شباب كونس فانتبه عدت
+
+291
+00:31:30,220 --> 00:31:40,000
+كمّة فهذه بدأت ساوية طلع لي كويس هنا هـ هذه X هذه X
+
+292
+00:31:40,000 --> 00:31:44,460
+تربيع اثنين هذه مش هتبقى قريب اثنين في واحد يعني
+
+293
+00:31:44,460 --> 00:31:50,180
+اثنين factorial يبقى اثنين factorial وهذه واحد
+
+294
+00:31:50,180 --> 00:31:55,710
+ثاني واحد factorial وهذه x تكعيب ثلاثة في اثنين
+
+295
+00:31:55,710 --> 00:32:01,010
+factorial يعني ثلاثة factorial x أُص أربعة أربعة
+
+296
+00:32:01,010 --> 00:32:07,130
+في ثلاثة factorial تعني أربعة factorial زائد هذه
+
+297
+00:32:07,130 --> 00:32:13,450
+كمان بنفس الطريقة xn زائد واحد على n زائد واحد
+
+298
+00:32:13,450 --> 00:32:21,430
+اللي هو factorial زائد الآخرى زائد constant C طيب
+
+299
+00:32:21,430 --> 00:32:27,670
+الخطة أحطها على شكل summation يبقى هذه summation
+
+300
+00:32:27,670 --> 00:32:34,430
+لمن؟ لل x to the power n plus one على n plus one
+
+301
+00:32:34,430 --> 00:32:41,490
+factorial من عند n تساوي أبصر جداش ل infinity هل
+
+302
+00:32:41,490 --> 00:32:45,830
+لما نكاملنا هنا الـ series هذه طار أي term من
+
+303
+00:32:45,830 --> 00:32:51,440
+الترمات؟ لا كله ظلم زي ما هو إذا الـ index اللي تحت
+
+304
+00:32:51,440 --> 00:32:56,640
+الـ summation بتغير والله بيبقى كما هو يبقى كما هو
+
+305
+00:32:56,640 --> 00:33:02,440
+كما ذكرنا في الجزء النظري قبل قليل يبقى بدء ظلم
+
+306
+00:33:02,440 --> 00:33:09,660
+عند n تساوي zero إلى infinity طيب زاد الـ constant
+
+307
+00:33:09,660 --> 00:33:10,220
+C
+
+308
+00:33:13,470 --> 00:33:24,310
+خليني أضغط و أقول C1 C1 C1 مثلًا هل هذا شكل الـ E و
+
+309
+00:33:24,310 --> 00:33:31,070
+S X؟ طبعًا لا هذي بدها تبقى X أس N و هذي N factorial
+
+310
+00:33:31,070 --> 00:33:36,050
+بسيطة الشغلة في دينها إذا بدي أشيل كل N و أكتب
+
+311
+00:33:36,050 --> 00:33:41,490
+مكانها N ناقص واحد يبقى هذا الكلام يساوي الـ
+
+312
+00:33:41,490 --> 00:33:47,930
+summation N ناقص واحد تساوي zero الى infinity لل X
+
+313
+00:33:47,930 --> 00:33:54,510
+أس N ناقص واحد زائد واحد على N ناقص واحد زائد واحد
+
+314
+00:33:54,510 --> 00:34:00,390
+كله factorial ويساوي الـ summation من N equal one
+
+315
+00:34:00,390 --> 00:34:06,290
+to infinity لل X أس N على N factorial
+
+316
+00:34:08,940 --> 00:34:14,520
+هل هادي يبقى .. طبعًا في constant C1 يبقى هنا زائد
+
+317
+00:34:14,520 --> 00:34:25,000
+C1 وهنا زائد C1 هل هادي هي الـ exponential اللى
+
+318
+00:34:25,000 --> 00:34:30,470
+عندنا هادي؟ لا، من هنا بتبدأ من وين؟ من اين دي
+
+319
+00:34:30,470 --> 00:34:35,230
+Zero؟ من هنا بتبدأ من وين؟ بدنا حل هالمشكلة هذه
+
+320
+00:34:35,230 --> 00:34:40,170
+وديها بالك بدك تحل وتحافظ على المكتسبات الوطنية
+
+321
+00:34:40,170 --> 00:34:45,350
+اللي عندك هذه اللي حصلت عليها تلعبش يضيعش ودبر
+
+322
+00:34:45,350 --> 00:34:53,110
+حالك بأي طريقة رياضية سليمة اقترح أن احنا في أي حد
+
+323
+00:34:55,870 --> 00:35:01,410
+ممتاز أنا بدي شكل يعطيني الشكل هذا يعني بنفع احذف
+
+324
+00:35:01,410 --> 00:35:07,570
+حد من الحدود من هنا نضيف نضيف مش نحذف طب ما هو
+
+325
+00:35:07,570 --> 00:35:13,390
+الحد اللي جاي في بالك نضيفه كلام كويس الـ zero هل
+
+326
+00:35:13,390 --> 00:35:18,910
+الـ zero بيغير من هذا الشكل بيغير بس ما تحطش zero
+
+327
+00:35:18,910 --> 00:35:23,310
+حطه بشكل آخر اللي بدك تضيفه بدك تطرحه
+
+328
+00:35:26,950 --> 00:35:32,370
+أنا لو روحت أضفت واحد و طرحت واحد كان أضفت كم؟
+
+329
+00:35:32,370 --> 00:35:39,050
+zero ليش أي إشكالية بقول كويس إذا هذه بقدر
+
+330
+00:35:39,050 --> 00:35:43,950
+أكتبها واحد زائد summation من N equal one to
+
+331
+00:35:43,950 --> 00:35:50,770
+infinity لل X to the power N على N factorial زائد C
+
+332
+00:35:50,770 --> 00:35:57,010
+one ناقص واحد يبقى أضفت واحد و طرحت واحد كأنه أضفت
+
+333
+00:35:57,010 --> 00:36:03,350
+zero كمقترحة أحدكم لكن الـ zero حطيت واحد وسالب واحد
+
+334
+00:36:03,350 --> 00:36:10,550
+طيب شوف لهذا شو بيساوي هذا summation من N equal
+
+335
+00:36:10,550 --> 00:36:15,890
+zero to infinity لل X to the power N على N
+
+336
+00:36:15,890 --> 00:36:22,930
+factorial هذا الجزء يعني هذا صحيح يقول لك ماشي مصدق
+
+337
+00:36:22,930 --> 00:36:30,170
+جرب وضع N بزيرو فاكتوريا اللي بيجي داشر بواحد هنا
+
+338
+00:36:30,170 --> 00:36:33,570
+X و Zero بواحد يبقى واحد على واحد بواحد اللي هو
+
+339
+00:36:33,570 --> 00:36:38,950
+الحد الأول زائد وضع N بواحد بيجيب الحد الثاني و
+
+340
+00:36:38,950 --> 00:36:45,190
+الحد الثالث والرابع يبقى بالكلام سليم مئة بالمئة
+
+341
+00:36:45,480 --> 00:36:51,220
+بالله إن دي زائد مين زائد هذا كله يعتبر constant
+
+342
+00:36:51,220 --> 00:36:57,340
+كمان بده يسميه C يبقى هذا زائد constant C و الـ C
+
+343
+00:36:57,340 --> 00:37:04,980
+بده يساوي C one ناقص واحد أليست هذه هي الـ E و الـ 6
+
+344
+00:37:04,980 --> 00:37:13,500
+زائد constant C تمام؟ لتركها بكويسها لترك هو اللي
+
+345
+00:37:13,500 --> 00:37:18,520
+جدر اللي جدرنا بواسطته نوصل للصيغة المطلوبة
+
+346
+00:37:18,520 --> 00:37:23,960
+ويتكامل EO6 يساوي EO6 زائد constant وبالتالي كأنه
+
+347
+00:37:23,960 --> 00:37:29,760
+احنا أثبتنا أن تكامل EO6 يساوي EO6 زايد constant
+
+348
+00:37:29,760 --> 00:37:35,620
+بطريقة غير الطريقة المتعرف عليها قبل ذلك في
+
+349
+00:37:35,620 --> 00:37:38,600
+section 7 3
+
+350
+00:37:48,580 --> 00:37:57,740
+طيب، هذا مثال يوضح كيف استخدمنا التكامل في الحصول
+
+351
+00:37:57,740 --> 00:38:03,560
+على شكل الـ series وسليّة قبله كانت فاضل، أيوة ما
+
+352
+00:38:03,560 --> 00:38:10,450
+الاخر خطوة هذه؟ ابدا، لحد اين تمام هذه؟ ضيف واحد
+
+353
+00:38:10,450 --> 00:38:16,970
+واطرح واحد كأنك باقي في قداش هل تتغير القيمة؟ لا
+
+354
+00:38:16,970 --> 00:38:22,210
+بدنا نضيف هي أضفنا واحد و طرحنا واحد الواحد هذا مع
+
+355
+00:38:22,210 --> 00:38:26,290
+الـ summation بدي أجمعهم بـ summation واحد يبقى هي
+
+356
+00:38:26,290 --> 00:38:29,810
+جمعتهم بـ summation واحد ممكن ولا مش ممكن تعالى
+
+357
+00:38:29,810 --> 00:38:35,670
+نشوف حط N ب Zero بطلع الحد الأول عندك بواحد حط in
+
+358
+00:38:35,670 --> 00:38:38,310
+من واحد إلى المقل النهائي بيعطيك الـ sub machine
+
+359
+00:38:38,310 --> 00:38:42,670
+الثاني يبقى كلامنا سليم مئة بالمئة جينا على الـ C
+
+360
+00:38:42,670 --> 00:38:46,310
+والنقص واحد هذا كله constant سميته constant z
+
+361
+00:38:46,310 --> 00:38:50,390
+ويساوي من C sub machine هو الـ exponential function
+
+362
+00:38:50,390 --> 00:38:55,330
+وده الـ constant يبقى فعلا تكامل E والـ 6 بـ E والـ 6 زائد
+
+363
+00:38:55,330 --> 00:39:01,230
+constant C طيب برضه بيناعطيك كمان مثال على هذا
+
+364
+00:39:01,230 --> 00:39:07,010
+الموضوع وفتح عينك كويس دجج معاي مثال رقم اثنين
+
+365
+00:39:07,010 --> 00:39:15,570
+بيقول
+
+366
+00:39:15,570 --> 00:39:20,950
+find a function
+
+367
+00:39:20,950 --> 00:39:29,730
+f of x that represented
+
+368
+00:39:29,730 --> 00:39:31,690
+by
+
+369
+00:39:37,510 --> 00:39:41,970
+بعد عملية عملية عملية عملية عملية عملية عملية
+
+370
+00:39:41,970 --> 00:39:56,610
+عملية عملية عملية عملية عملية
+
+371
+00:39:59,320 --> 00:40:05,580
+the result استخدم النتيجة اللي حصلت عليها to find
+
+372
+00:40:05,580 --> 00:40:10,080
+a
+
+373
+00:40:10,080 --> 00:40:16,240
+power series that
+
+374
+00:40:16,240 --> 00:40:22,120
+represent that represent
+
+375
+00:40:22,120 --> 00:40:25,240
+that
+
+376
+00:40:25,240 --> 00:40:27,780
+represent the following
+
+377
+00:40:33,020 --> 00:40:39,520
+التي تمثل الدوالة التالية الدالة الأولى  نمرة A
+
+378
+00:40:39,520 --> 00:40:47,120
+الـG of X يساوي واحد على واحد زائد X لكل تربيع
+
+379
+00:40:47,120 --> 00:40:56,660
+نمرة B الـG of X بده يساوي Ln واحد زائد X
+
+380
+00:41:29,460 --> 00:41:35,240
+هاتلي دالة تمثل هذه الـ Power Series
+
+381
+00:41:42,560 --> 00:41:48,140
+بعد هيك النتيجة اللي تحصل عليها بدك تستخدمها في
+
+382
+00:41:48,140 --> 00:41:52,280
+الحصول على power series لتو functions اللي عندك
+
+383
+00:41:52,280 --> 00:41:57,680
+يعني عملية عكسية بتعطيني power series بدي أدلتها 
+
+384
+00:41:57,680 --> 00:42:01,460
+تبعتها يبقى سعر اندي دالة و سعر power series بد
+
+385
+00:42:01,460 --> 00:42:07,160
+تستخدم هذه النتيجة للحصول على شكل ال power series
+
+386
+00:42:07,160 --> 00:42:13,760
+لها تين اتدلتينكم مطلوب عندي في السؤال؟ ثلاثة،
+
+387
+00:42:13,760 --> 00:42:17,480
+خلّينا بالمطلوب الأول نجيبه وبعدين بروح ندور على A
+
+388
+00:42:17,480 --> 00:42:21,980
+وB يبقى بدنا نيجي للمطلوب الأول قبل ما نبدأ بالمطلوب
+
+389
+00:42:21,980 --> 00:42:26,220
+الأول بدي أعرف ما هو الشكل ال power series اللي
+
+390
+00:42:26,220 --> 00:42:30,700
+معطهالي هذه يبقى باجي بقوله summation من n equal
+
+391
+00:42:30,700 --> 00:42:35,640
+zero to infinity لسالب واحد to the power n لل x to
+
+392
+00:42:35,640 --> 00:42:41,680
+the power n هذه واحد ناقص x زائد x تربيع ناقص x
+
+393
+00:42:41,680 --> 00:42:46,660
+تكعيب زائد ناقص واحد to the power n x to the power
+
+394
+00:42:46,660 --> 00:42:54,300
+n زائد إلى آخرين طيب السؤال هو مين ال series هذه هل
+
+395
+00:42:54,300 --> 00:42:59,540
+واحدة هذه من التلاتة series المشهورة ال geometric
+
+396
+00:42:59,540 --> 00:43:07,240
+ال P ال harmonic هذه واحدة منهم geometric ليش اجسم
+
+397
+00:43:07,240 --> 00:43:14,240
+اي حد على السابق له بطلع كله سالب X يبقى هذه بقوله
+
+398
+00:43:14,240 --> 00:43:21,810
+convert geometric series إذا كان ال absolute value
+
+399
+00:43:21,810 --> 00:43:26,910
+ل R هو absolute value ل سلب X قداش absolute value
+
+400
+00:43:26,910 --> 00:43:32,410
+ل سلب X أليس هو absolute value ل X وهذا يجب أن
+
+401
+00:43:32,410 --> 00:43:35,830
+يكون أقل من واحد إذا كان ال absolute value ل X أقل
+
+402
+00:43:35,830 --> 00:43:37,950
+من واحد إذا كان ال absolute value ل X أقل من واحد
+
+403
+00:43:37,950 --> 00:43:42,690
+إذا كان ال absolute value ل X أقل من واحد إذا كان
+
+404
+00:43:42,690 --> 00:43:42,910
+ال absolute value ل X أقل من واحد إذا كان ال
+
+405
+00:43:42,910 --> 00:43:46,030
+absolute value ل X أقل من واحد إذا كان ال absolute
+
+406
+00:43:46,030 --> 00:43:55,900
+value ل X أقل من واحد interval of convergence as
+
+407
+00:43:55,900 --> 00:43:58,120
+سالب واحد و واحد
+
+408
+00:44:02,490 --> 00:44:06,490
+يبقى الرياضة اصلا كده؟ برضه واحد بهمني شرية دي
+
+409
+00:44:06,490 --> 00:44:11,090
+الصينة خلاص نجيبناله فترة التقارب تبع ال series
+
+410
+00:44:11,090 --> 00:44:16,070
+يبقى على فترة التقارب من سلب واحد إلى واحد بقدر
+
+411
+00:44:16,070 --> 00:44:21,890
+اوجد مجموع هذه ال series جالي هاتلي الدالة التي
+
+412
+00:44:21,890 --> 00:44:30,180
+تمثل هذه ال power series يبقى باجي بقوله the sum of
+
+413
+00:44:30,180 --> 00:44:40,540
+the series S ال S تساوي الحد الأول على واحد ناقص
+
+414
+00:44:40,540 --> 00:44:48,620
+الأساس هذا شو بيعطينا؟ هذا بيعطينا أن ال S يساوي
+
+415
+00:44:48,620 --> 00:44:55,930
+واحد على واحد زائد ال X أليس هذه function في X؟ صح
+
+416
+00:44:55,930 --> 00:45:03,190
+ولا لا؟ يبقى هذه بدها تساوي ال F of X تمام تمام
+
+417
+00:45:03,190 --> 00:45:09,990
+يبقى هاي كتبتله المجموع تبع ال series as a
+
+418
+00:45:09,990 --> 00:45:14,690
+function هات ال F of X التي تمثل بال power series
+
+419
+00:45:14,690 --> 00:45:18,390
+يبقى كأنه جمعت ال power series فطلها المجموع
+
+420
+00:45:18,390 --> 00:45:25,940
+بالشكل هذا يبقى هذا الذي يساوي منF of X. إذا خلصنا
+
+421
+00:45:25,940 --> 00:45:31,680
+المطلوب الأول جيبنا دالة ان ال power series عندها
+
+422
+00:45:31,680 --> 00:45:36,660
+المُعطَع يبقى ال power series كان هبقى L 1 على 1
+
+423
+00:45:36,660 --> 00:45:42,660
+زائد X. تمام؟ طبعا كويس. بدنا نيجي الآن للمطلوب
+
+424
+00:45:42,660 --> 00:45:48,700
+الأول جاب المبدأ المطلوب الأول بدي أقوله f of x ليه
+
+425
+00:45:48,700 --> 00:45:54,280
+واحد على واحد زائد x وليه بدي تساوي واحد ناقص x
+
+426
+00:45:54,280 --> 00:46:00,340
+زائد x تربيع ناقص x تكعيب زائد ناقص one to the
+
+427
+00:46:00,340 --> 00:46:04,060
+power n x to the power n زائد إلى آخرين
+
+428
+00:46:09,070 --> 00:46:16,440
+هذه المقارنة هي نفس النتيجة بس المقارنة مربع يعني
+
+429
+00:46:16,440 --> 00:46:21,200
+نربعها و نمشي الحال خلاصنا طيب خلنا نناقش احنا
+
+430
+00:46:21,200 --> 00:46:27,380
+وياكم لو ترمين وربعتهم بتطلع تلت ترمات ودي سهل
+
+431
+00:46:27,380 --> 00:46:32,880
+مربع الأول اتنين حصل ضرب اتنين مربع التاني سهل طيب
+
+432
+00:46:32,880 --> 00:46:38,680
+لو كانوا تلاتة بيبدأ الحرارة ترتفع عندك بتقدروا
+
+433
+00:46:38,680 --> 00:46:43,620
+تلت ترمات زي تلت ترمات اضربهم ببعض طيب لو قلت خلي
+
+434
+00:46:43,620 --> 00:46:50,080
+تملك أربعة بتبقى النبض يرتفع، مش هيك؟ لو قولتلك خمس
+
+435
+00:46:50,080 --> 00:46:55,040
+ترمات، ستة بعشر ترمات، وقول اه ورا دي بدي أقعد
+
+436
+00:46:55,040 --> 00:46:59,360
+ساعتين وانا أضرب فيهم ولا تلت ساعات، فما بالك إذا
+
+437
+00:46:59,360 --> 00:47:04,080
+كان مالة نهاية من الحدود، يبقى إحكاية إن ربي
+
+438
+00:47:04,080 --> 00:47:10,480
+أحصفها على شجة ده بتوصلكش إلى نتيجة طبعا فادبر حالك
+
+439
+00:47:10,480 --> 00:47:14,380
+شو موضوع ده هنا موضوع من derivative term by term
+
+440
+00:47:14,380 --> 00:47:18,920
+او integration term by term بدي بسأل نفسي هل الدلة
+
+441
+00:47:18,920 --> 00:47:23,240
+دي لو عملت لها derivative او integral بحصل على
+
+442
+00:47:23,240 --> 00:47:28,740
+واحد على واحد زائد X لكل تربيع نشتاق نشتاق اذا لو
+
+443
+00:47:28,740 --> 00:47:33,040
+اشتقنا بتطلع الدلة المطلوبة بقولك كويس يبقى اذا
+
+444
+00:47:33,040 --> 00:47:37,360
+تعال نشتاق .. ماجالليش هو اشتق انا لحالة أرفقهذا
+
+445
+00:47:37,360 --> 00:47:41,640
+يجب أن تبقى دقيق الملاحظة لما هو المطلوب، أما لو
+
+446
+00:47:41,640 --> 00:47:45,440
+ربعتها تقول تربيها 12 أكل استراليزي، تقول يا الله
+
+447
+00:47:45,440 --> 00:47:49,010
+من أعرف فيش حاجة مش عارف انت بيجي جيبلي ال series
+
+448
+00:47:49,010 --> 00:47:53,470
+اللي تمثله هذه الدلة و بعدين جالك ايش مش جالك روح
+
+449
+00:47:53,470 --> 00:47:58,970
+ربها جالك use the result يعني قيدك كيف تشتغل بقوله
+
+450
+00:47:58,970 --> 00:48:05,310
+انا بروح اشتقها يبقى هذه ال F prime of X سالب واحد
+
+451
+00:48:05,310 --> 00:48:10,710
+على واحد زائد X لكل تربيع what و ساوي أظن الأول
+
+452
+00:48:10,710 --> 00:48:18,520
+بيروح ناقص واحد زيدي اتنين X ناقص ثلاثة X تربيع زيد
+
+453
+00:48:18,520 --> 00:48:25,360
+أبصر مين؟ زائد ناقص واحد to the power N في ال N في
+
+454
+00:48:25,360 --> 00:48:29,140
+ال X أس N ناقص واحد إلى ما شاء الله
+
+455
+00:48:31,830 --> 00:48:35,470
+طب انا بديش سالب واحد على المقدار اللي عناها، بدي
+
+456
+00:48:35,470 --> 00:48:39,330
+بياها مين؟ بالموجب، إذا بدي أضغط الطرفين كله في
+
+457
+00:48:39,330 --> 00:48:45,590
+إشارة يبقى بيصير الـG of X اللي بده إياها واحد على
+
+458
+00:48:45,590 --> 00:48:52,030
+واحد زائد X لكل تربيع يساوي واحد نقص اتنين اكس زائد
+
+459
+00:48:52,030 --> 00:48:58,370
+تلاتة اكس تربيع نقص ابصر مين زائد نقص واحد قص ابصر
+
+460
+00:48:58,370 --> 00:49:04,990
+جديش ان اكس نقص واحد زائد نقص واحد قص جديش
+
+461
+00:49:11,550 --> 00:49:15,650
+أنا عندي ناقص واحد أس ان في الأصل وجدوا كمان إشارة
+
+462
+00:49:15,650 --> 00:49:18,770
+سالب يعني كمان سالب واحد يبقى صير سالب واحد أس
+
+463
+00:49:18,770 --> 00:49:26,770
+كده؟ N زائد واحد يبقى بصير أس N زائد واحد وهي هي
+
+464
+00:49:26,770 --> 00:49:32,870
+سيدي على الشكل summation لناقص واحد أس N زائد واحد
+
+465
+00:49:32,870 --> 00:49:39,270
+لل N X أس N ناقص واحد وال summation ببدأ من وين؟ من
+
+466
+00:49:39,270 --> 00:49:46,950
+عند الواحد لأنه طار أول term تمام؟ اللي هي مين؟
+
+467
+00:49:46,950 --> 00:49:52,230
+انت عندك سالب واحد قسين أجاله كمان سالب واحد قس
+
+468
+00:49:52,230 --> 00:49:58,290
+واحد بصير كده؟ تساوة الأساسات بنجمع الأساس بصير N
+
+469
+00:49:58,290 --> 00:50:04,090
+زائد واحد خلصنا؟ يبقى يا بيخليها زي هيك يا حابب
+
+470
+00:50:04,390 --> 00:50:09,450
+أخلّيها من عند ال zero بروح بشيل كل N و بحط مكانها
+
+471
+00:50:09,450 --> 00:50:14,750
+N زائد واحد حابب زيكي أهلا وسهلا بدكش تقولي ال
+
+472
+00:50:14,750 --> 00:50:20,110
+summation من عند ال zero ل infinity لنقص واحد أس N
+
+473
+00:50:20,110 --> 00:50:29,180
+زائد اتنين لل N زائد واحد لل X أس N يعني شيلت كل
+
+474
+00:50:29,180 --> 00:50:33,740
+إنه حطيت مكانها، انزلت، كتبتها على الصيغة هذه، و
+
+475
+00:50:33,740 --> 00:50:38,560
+الله على الصيغة هذه، الأتنين are the same طيب،
+
+476
+00:50:38,560 --> 00:50:43,200
+خلصنا، نمر بيه؟ نمر بيه جالي هاتلي الدالة هذه،
+
+477
+00:50:43,200 --> 00:50:48,220
+الدالة هذه عبارة عن إيش؟ تكامل الدالة هذه مظبوط إذا
+
+478
+00:50:48,220 --> 00:50:56,740
+لو جي تقوله ها ال جي of X هي تكامل واحد على واحد
+
+479
+00:50:56,740 --> 00:51:02,200
+زائد X DX معناته الدالة اللي فوق بدي أعملها إيش
+
+480
+00:51:02,200 --> 00:51:08,660
+integration term by term يبقى X ناقص X تربيع على
+
+481
+00:51:08,660 --> 00:51:12,380
+اتنين زائد X تكعيب على تلاتة
+
+482
+00:51:32,480 --> 00:51:39,300
+يبقى هذا نتيجة التكامل بروح اضيف له زائد constant
+
+483
+00:51:39,300 --> 00:51:47,260
+C كويس الان شوفيش النتيجة اللي حصلنا عليها الان
+
+484
+00:51:47,260 --> 00:51:52,580
+قولنا زيادة كونستانسية احنا عندنا ال interval و ال
+
+485
+00:51:52,580 --> 00:51:56,840
+convergence اللي هذى اتدالى من و لا وين يعني محتوى
+
+486
+00:51:56,840 --> 00:52:07,280
+على ال zero كويس بدي بقوله at x يساوي zero بس قبل
+
+487
+00:52:07,280 --> 00:52:12,700
+ال X يستوي Zero التكامل هذي بقداش أبلن absolute
+
+488
+00:52:12,700 --> 00:52:18,560
+value ل 1 زائد X بدي أشوف هل ال absolute هذي
+
+489
+00:52:18,560 --> 00:52:22,510
+ضرورية ولا ماهياش ضرورية احنا عندنا ال interval من
+
+490
+00:52:22,510 --> 00:52:28,210
+واحد لسالب واحد لا بيساوي واحد ولا بيساوي سالب
+
+491
+00:52:28,210 --> 00:52:33,290
+واحد إذا عمره المقدار بين القوسين بدي أخد قيمة
+
+492
+00:52:33,290 --> 00:52:38,670
+سالبة مش إمكانية على ال interval من سالب واحد إلى
+
+493
+00:52:38,670 --> 00:52:44,970
+واحد يعني أكبر من سالب واحد و أجل من واحد إذا لا
+
+494
+00:52:44,970 --> 00:52:51,660
+يمكن هذا عمره ياخد قيمة سالبة يبقى هذا بده يساوي لن
+
+495
+00:52:51,660 --> 00:52:58,580
+واحد زائد X on الفترة من سالب واحد إلى واحد يبقى
+
+496
+00:52:58,580 --> 00:53:05,660
+ايش حصل عندنا حصل عندنا اللي هو لن وقبل لن واحد
+
+497
+00:53:05,660 --> 00:53:13,700
+زائد X بالشكل أن هذا اللي هو g of x بده يسوي قداش x
+
+498
+00:53:13,700 --> 00:53:20,580
+ناقص x تربيع على 2 زائد x تكعيب على 3 ناقص x أربع
+
+499
+00:53:20,580 --> 00:53:27,780
+على 4 زائد ناقص 1 to the power n x أس n زائد 1 n
+
+500
+00:53:27,780 --> 00:53:33,140
+زائد 1 زائد constant C الان zero موجود في الفترة
+
+501
+00:53:33,140 --> 00:53:37,260
+عادية صحيح ولا لا ممكن أحسب ال constant عند ال
+
+502
+00:53:37,260 --> 00:53:45,160
+zero فبجي بقوله at x يساوي zero وبيحط x بزيرو
+
+503
+00:53:45,160 --> 00:53:51,600
+بظهر جداش لن الواحد لن الواحد اللي هو بزيرو زيرو
+
+504
+00:53:51,600 --> 00:53:57,200
+زيرو كله زائد زيرو زائد زيرو زائد مش عارف إيه زائد
+
+505
+00:53:57,200 --> 00:54:01,560
+ال constant c يبقى بناء عليها ال c جداش بده يساوي
+
+506
+00:54:01,560 --> 00:54:09,600
+يبقى ال c بيساوي زيرو إذا أصبح عندي لن واحد زائد x
+
+507
+00:54:09,600 --> 00:54:21,210
+هو x ناقص x تربيع على اتنين زائد x تكعيب على 3 ناقص x
+
+508
+00:54:21,210 --> 00:54:28,490
+أس 4 على 4 زائد ناقص 1 to the power n x to the
+
+509
+00:54:28,490 --> 00:54:33,990
+power n plus 1 على n plus 1 أو إذا حبيت تكتبها
+
+510
+00:54:33,990 --> 00:54:40,170
+summation من عند ال n equal 0 to infinity لسالب 1
+
+511
+00:54:40,170 --> 00:54:47,620
+to the power n ل x أس n زائد 1 على n زائد واحد
+
+512
+00:54:47,620 --> 00:54:54,240
+انتهى ال section وإليكم أرقام المسائل يبقى
+
+513
+00:54:54,240 --> 00:55:08,640
+exercises اللي هو عشرة exercises عشرة عشرة سبعة
+
+514
+00:55:08,640 --> 00:55:15,290
+عشرة سبعة المسائل يا سيدي من واحد لتمانية وأربعين
+
+515
+00:55:15,290 --> 00:55:25,430
+من واحد لتمانية وأربعين multiple of three الامتحان
+
+516
+00:55:25,430 --> 00:55:29,470
+واصل حتى نهاية هذا ال section يعني ال section اللي
+
+517
+00:55:29,470 --> 00:55:35,030
+نبدأ بكرا إن شاء الله مش داخل في الامتحان القادم
+
+518
+00:55:35,490 --> 00:55:40,350
+يعني ابتداء من section تمانية تلاتة وحتى نهاية
+
+519
+00:55:40,350 --> 00:55:44,670
+section عشرة سبعة إن شاء الله تعالى 
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/4L2irOydHGA_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/4L2irOydHGA_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e16a91e3defcfc84f97532d8dd4fe4461d6869f0
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/4L2irOydHGA_raw.srt
@@ -0,0 +1,2084 @@
+1
+00:00:10,020 --> 00:00:15,610
+بسم الله الرحمن الرحيممواصل ما ابتدأنا به في المرة
+
+2
+00:00:15,610 --> 00:00:20,670
+الماضية و هو موضوع ال power series طبعا ابتدينا
+
+3
+00:00:20,670 --> 00:00:25,230
+فيه المرة الماضية و أخدنا على ذلك أربعة أمثلة و
+
+4
+00:00:25,230 --> 00:00:29,950
+بنعطي الآن مثال بشكل آخر غير الأشكال الأربع اللي
+
+5
+00:00:29,950 --> 00:00:34,790
+شفناها في المرة الماضيةالمثال بقول ما ياتي هاتلي
+
+6
+00:00:34,790 --> 00:00:40,250
+فترة التقارب لل power series اللي قدامنا هذه and
+
+7
+00:00:40,250 --> 00:00:44,290
+find the sum of the series as a function وهاتلي
+
+8
+00:00:44,290 --> 00:00:49,170
+مجموع هذه المتسلسلة كدالة يبقى في الأول بدنا نروح
+
+9
+00:00:49,170 --> 00:00:55,650
+نجيب فترة التقارب لهذه ال series يبقى solution
+
+10
+00:00:58,390 --> 00:01:02,470
+حابين اتعرف على شكل ال series فبجي بقول summation
+
+11
+00:01:02,470 --> 00:01:07,330
+من N equal zero to infinity لل X تربيع زائد واحد
+
+12
+00:01:07,330 --> 00:01:13,250
+على تلاتة to the power N الحد الأول بواحد الحد
+
+13
+00:01:13,250 --> 00:01:19,110
+التاني X تربيع زائد واحد على تلاتة الحد التاني X
+
+14
+00:01:19,110 --> 00:01:24,220
+تربيع زائد واحد على تلاتة لكل تربيعبنبقى الماشي
+
+15
+00:01:24,220 --> 00:01:30,500
+لغاية ما نوصل ل X تربيع زائد واحد على تلاتة كله to
+
+16
+00:01:30,500 --> 00:01:38,080
+the power N زائد إلى آخرين يبقى كتبنا ال series
+
+17
+00:01:38,080 --> 00:01:42,560
+على الشكل اللي قدامنا السؤال هو هد ال series هل هي
+
+18
+00:01:42,560 --> 00:01:46,040
+من ال series التلاتة المشهورة اللي كنا بنتعامل
+
+19
+00:01:46,040 --> 00:01:51,770
+معاها طيلة هذا ال chapter بالمرة النهائيةيعني هذه
+
+20
+00:01:51,770 --> 00:01:55,070
+ليست Geometric ليست P Series ليست Harmonic؟
+
+21
+00:01:55,070 --> 00:02:00,310
+Geometric يعني يعني هي واحدة منها من التلاتة اقسم
+
+22
+00:02:00,310 --> 00:02:05,110
+الحد هذا على هذا كده ايش بيطلع الجواب اكثر بيها زي
+
+23
+00:02:05,110 --> 00:02:07,950
+واحدة على تلاتة اقسم هذا على هذا اكثر بيها زي
+
+24
+00:02:07,950 --> 00:02:12,050
+واحدة على تلاتة يعني كده اذا هذه Geometric Series
+
+25
+00:02:12,050 --> 00:02:17,500
+Convergedإذا كان الاساس تبعها هذا ماله أقل من
+
+26
+00:02:17,500 --> 00:02:25,200
+الواحد الصحيح يبقى هذه Convergent Geometric Series
+
+27
+00:02:25,200 --> 00:02:33,660
+إذا كان absolute value لل R لو بدي أسوأ absolute
+
+28
+00:02:33,660 --> 00:02:39,380
+value لإكس تربية زي واحد على تلاتة أقل من مين أقل
+
+29
+00:02:39,380 --> 00:02:44,840
+من واحدطيب هذه عمرها بتاخد قيمة سالبة تقول
+
+30
+00:02:44,840 --> 00:02:49,020
+absolute value كتبناها والله شيلناها سياد يبقى هذا
+
+31
+00:02:49,020 --> 00:02:54,900
+معناه ان ال X تربية زائد واحد على تلاتة اقل من مهم
+
+32
+00:02:54,900 --> 00:03:00,980
+اقل من الواحد او ان شئتم فقولوا ان هذه convert
+
+33
+00:03:00,980 --> 00:03:10,310
+geometricإذا كان ال X تربية زائد واحد أقل من من
+
+34
+00:03:10,310 --> 00:03:18,590
+تلاتة وإن شئتم فقولوا X تربية أقل من اتنين وإذا
+
+35
+00:03:18,590 --> 00:03:23,570
+خدنا الجدر التربية بيصير absolute value ل X أقل من
+
+36
+00:03:23,570 --> 00:03:28,730
+square root للاتنينيبقى باجي بقوله the series
+
+37
+00:03:28,730 --> 00:03:39,070
+converge on the interval على الفترة هذه ايش
+
+38
+00:03:39,070 --> 00:03:44,910
+معناها؟ X محصولة من سلب جذر اتنين وجذر اتنين، اذا
+
+39
+00:03:44,910 --> 00:03:52,380
+على الفترة من سلب جذر اتنين إلى جذر اتنينيبقى انت
+
+40
+00:03:52,380 --> 00:03:56,520
+هنا من المطلوب الأول قال لي هاتلي فترة التقارب لل
+
+41
+00:03:56,520 --> 00:04:05,720
+power series اللي عندنا ايوة السؤال
+
+42
+00:04:05,720 --> 00:04:10,280
+بيسأل بيقول انت كانت بفترة مفتوحة بنفعش تكون مغلقة
+
+43
+00:04:10,280 --> 00:04:15,740
+بنقوله تعالى نشوف بنفعله بنفعش ايش سمناها ال
+
+44
+00:04:15,740 --> 00:04:20,060
+series هذه؟ Geometric وانتش ال geometric converge
+
+45
+00:04:22,530 --> 00:04:30,510
+طب لو كانت تساوي واحد يعني بنفع نجفل هى؟ هى بنفع؟
+
+46
+00:04:30,510 --> 00:04:36,450
+خلاص مايبقى مينفعش ليش؟ لأنه إذا كانت أكبر من أو
+
+47
+00:04:36,450 --> 00:04:40,230
+تساوي واحد ال series مالها بي vary بقدرش أقول
+
+48
+00:04:40,230 --> 00:04:45,170
+closed interval وإنما بقول open interval طب
+
+49
+00:04:45,170 --> 00:04:48,730
+انتهينا من مقوب الأول مقوب التاني بيقوللي على فترة
+
+50
+00:04:48,730 --> 00:04:54,410
+التقارب هذهبتجيب للمجموع تبع السيريز هذه as a
+
+51
+00:04:54,410 --> 00:05:03,270
+function باجيب اقوله it's sum المجموع تبعها as بدي
+
+52
+00:05:03,270 --> 00:05:09,330
+اديله capital S capital S يساوي الحد الاول على
+
+53
+00:05:09,330 --> 00:05:14,970
+واحد ناقص الاساس الاساس يقول اكس تربيه زائد واحد
+
+54
+00:05:14,970 --> 00:05:22,000
+على تلاتةهذه هى اللى هي بدها تساوي من تلاتة على
+
+55
+00:05:22,000 --> 00:05:29,280
+مين على تلاتة ناقص x تربيع ناقص واحد او انشئتم
+
+56
+00:05:29,280 --> 00:05:37,700
+فقولوا تلاتة على اتنين ناقص x تربيع سؤال هو أليست
+
+57
+00:05:37,700 --> 00:05:45,500
+هذه function في xيبقى بناء عليه المجموعة S as a
+
+58
+00:05:45,500 --> 00:05:51,480
+function of X فالـ F of X بده يسوى ثلاثة على
+
+59
+00:05:51,480 --> 00:05:58,920
+الإتنين ناقص X تربيع المطلوب الثاني من المثلة
+
+60
+00:06:01,980 --> 00:06:06,340
+الان انتهينا من الجزء الاول من هذا ال section بدنا
+
+61
+00:06:06,340 --> 00:06:10,500
+ننتقل الى الجزء الثاني الجزء الثاني من هذا ال
+
+62
+00:06:10,500 --> 00:06:14,960
+section هو differentiation term by termand
+
+63
+00:06:14,960 --> 00:06:22,620
+integration term by term يبقى بدنا نيجي اللي هو
+
+64
+00:06:22,620 --> 00:06:27,100
+differentiation term by term بالنسبة لل power
+
+65
+00:06:27,100 --> 00:06:35,000
+series يبقى باجي بقوله term by term
+
+66
+00:06:35,000 --> 00:06:42,800
+differentiation theorem
+
+67
+00:06:47,600 --> 00:06:55,200
+النص التالي F summation من N equal zero to
+
+68
+00:06:55,200 --> 00:07:04,360
+infinity ل C N X نقص ال A to the power N converge
+
+69
+00:07:04,360 --> 00:07:12,900
+for ال A minus ال R أقل من X أقل من ال A زائد ال R
+
+70
+00:07:12,900 --> 00:07:15,880
+for some
+
+71
+00:07:17,290 --> 00:07:31,270
+اللي greater than zero it defines بتعرف
+
+72
+00:07:31,270 --> 00:07:40,410
+a function هنسميها f of x تساوي هذا ال summation
+
+73
+00:07:40,410 --> 00:07:46,050
+اللي عندنا summation من n equal zero to infinity
+
+74
+00:07:46,560 --> 00:07:54,940
+للـCN الـ X نقص الـ A to the power M والـ X بتتحرك
+
+75
+00:07:54,940 --> 00:08:04,280
+في الفترة من الـ A سالب R إلى الـ A plus R This
+
+76
+00:08:04,280 --> 00:08:14,350
+function has a derivativesHas derivatives of all
+
+77
+00:08:14,350 --> 00:08:19,650
+orders
+
+78
+00:08:19,650 --> 00:08:31,670
+من كل الرتب Inside the interval of convergence
+
+79
+00:08:44,360 --> 00:08:49,660
+interval of convergence as follow كتالة
+
+80
+00:09:25,800 --> 00:09:28,920
+النقطة الأولى هي term by term differentiation
+
+81
+00:09:28,920 --> 00:09:33,060
+theorem والنقطة التانية term by term integration
+
+82
+00:09:33,060 --> 00:09:38,300
+theorem خلّينا مع النقطة الأولى في الأول فباجي
+
+83
+00:09:38,300 --> 00:09:42,700
+بقول لو كانت ال series اللى عندنا هذى convert على
+
+84
+00:09:42,700 --> 00:09:48,640
+الفترة اللى عندنا من a-r او ال x محصورة من a-rوالـ
+
+85
+00:09:48,640 --> 00:09:53,160
+A زائد R إذا بتذكروا و احنا لما اتكلمنا في الجزء
+
+86
+00:09:53,160 --> 00:09:58,060
+النظري تبع ال power series نقول لو عندنا فترة زي
+
+87
+00:09:58,060 --> 00:10:05,080
+الفترة هذه و أجت A في منتصف الفترة كان هذا نصف قطر
+
+88
+00:10:05,080 --> 00:10:11,380
+التقارب R وهذا نصف قطر التقارب R يبقى إحداثيات
+
+89
+00:10:11,380 --> 00:10:18,180
+النقطة هذه A زائد Rوإحداثيات النقطة هذه لإيه
+
+90
+00:10:18,180 --> 00:10:24,220
+الناقصات بعد النقطة هذه ال series مختلفة وقبل
+
+91
+00:10:24,220 --> 00:10:29,160
+النقطة هذه ال series كذلك مختلفة وفي الداخل هنا ال
+
+92
+00:10:29,160 --> 00:10:34,090
+series مالها مختلفة بالشكل اللي عندنا هذافبقول لو
+
+93
+00:10:34,090 --> 00:10:37,510
+ال series converge على الفترة اللي عندنا هذه it
+
+94
+00:10:37,510 --> 00:10:43,170
+defines a function يعني ال series هذه يمكن كتابتها
+
+95
+00:10:43,170 --> 00:10:48,230
+على شكل function f of x تساوي هذا ال summation
+
+96
+00:10:48,230 --> 00:10:52,450
+صارت هذه فترة التقارب لهذه دالة اللي هي تعتبر
+
+97
+00:10:52,450 --> 00:10:59,180
+domain لمينDomain للدالة F of X يعني احنا لان
+
+98
+00:10:59,180 --> 00:11:05,200
+كتبنا ال function على شكل power series بقولي هذه
+
+99
+00:11:05,200 --> 00:11:11,260
+الدالة لها مشتقات من جميع الرتب خلال فترة التقارب
+
+100
+00:11:11,350 --> 00:11:17,250
+تبع السيريز كيف؟ كالتالي يبقى احنا لو جينا و قولنا
+
+101
+00:11:17,250 --> 00:11:24,830
+هذا ال F of X اللي تساوي ال summation يبقى C0 زيد
+
+102
+00:11:24,830 --> 00:11:34,620
+C1 في X نقص ال Aزاد C2 في X نقص A لكل تربية زاد C3
+
+103
+00:11:34,620 --> 00:11:44,200
+في X نقص A لكل تكعيب زاد زاد CN في X نقص A to the
+
+104
+00:11:44,200 --> 00:11:50,430
+power N زاد الاخرينيبقى هذا الـ function كتبناها
+
+105
+00:11:50,430 --> 00:11:54,090
+على شكل ال power series اللي قدامي يعنى اللي انا
+
+106
+00:11:54,090 --> 00:12:00,690
+بدى ابدأ اشتق لو قلت f prime of x يبقى الأول هذا
+
+107
+00:12:00,690 --> 00:12:07,870
+مشتقته بقداش مش هيظهر عندىC1 مقدار ثابت الـA
+
+108
+00:12:07,870 --> 00:12:15,010
+مشتقتها بـ0 مشتقت الـX بـ1 في C1 مقدار ثابت C1 فقط
+
+109
+00:12:15,010 --> 00:12:23,690
+C2 مقدار ثابت يبقى الأس في الجوس مرفوع لنفس الأس
+
+110
+00:12:23,690 --> 00:12:27,810
+مطروح منه واحد في تفاضل مداخل القوس اللي هو مقدار
+
+111
+00:12:27,810 --> 00:12:29,210
+ثابت C1 مقدار ثابت C2 مقدار ثابت C1 مقدار ثابت C2
+
+112
+00:12:29,210 --> 00:12:33,130
+مقدار ثابت C2 مقدار ثابت C2 مقدار ثابت C2 مقدار
+
+113
+00:12:33,130 --> 00:12:34,210
+ثابت C2 مقدار ثابت C2 مقدار ثابت C2 مقدار ثابت C2
+
+114
+00:12:34,210 --> 00:12:34,210
+مقدار ثابت C2 مقدار ثابت C2 مقدار ثابت C2 مقدار
+
+115
+00:12:34,210 --> 00:12:36,110
+ثابت C2 مقدار ثابت C2 مقدار ثابت C2 مزائد ثلاثة C
+
+116
+00:12:36,110 --> 00:12:42,050
+ثلاثة X ناقص ال A لكل تربية في مشتقة مداخل قصر
+
+117
+00:12:42,050 --> 00:12:51,030
+اللي هو بقداش بواحد زائد زائد N CN X ناقص ال A to
+
+118
+00:12:51,030 --> 00:12:58,070
+the power N plus one زائد الاخرين يبقى هذا الشغل
+
+119
+00:12:58,070 --> 00:13:04,570
+اللي اشتغلنا اسمه differentiation term by termيبقى
+
+120
+00:13:04,570 --> 00:13:09,510
+روحنا اشتقنا term by term كل series لغاية
+
+121
+00:13:09,510 --> 00:13:14,050
+infinitive شو رايك اني بقدر اكتب هذه المشتقة على
+
+122
+00:13:14,050 --> 00:13:18,430
+شكل power series بدل ما هي بالشكل الكبير بدي
+
+123
+00:13:18,430 --> 00:13:24,490
+اكتبها بالشكل الجديد يبقى summation و بروح بحط
+
+124
+00:13:24,490 --> 00:13:31,220
+الحد النوني N في CNفى ال X ناقص ال A to the power
+
+125
+00:13:31,220 --> 00:13:36,380
+N plus one من عند ال N تسوى أكثر قدره لغاية
+
+126
+00:13:36,380 --> 00:13:41,440
+Infinity من أين بدنا نبدأ؟ من عندهم تسوى قدره؟
+
+127
+00:13:41,440 --> 00:13:48,770
+متأكدين؟ فما هو السبب؟ أنا موافق، بس ليش؟أيوة لأن
+
+128
+00:13:48,770 --> 00:13:52,730
+الحد الأول هذا طاري يعني ال series نقصت حد من
+
+129
+00:13:52,730 --> 00:13:58,770
+بداية ال series ومشان تتأكد ابدا حط ان واحد اتنين
+
+130
+00:13:58,770 --> 00:14:02,130
+تلاتة في الصيغة اللي عندك شوف يطلع ال series اللي
+
+131
+00:14:02,130 --> 00:14:08,190
+عندنا هذه ولا لأ فمثلا لو قلنا ان بواحد C واحد ودق
+
+132
+00:14:08,190 --> 00:14:14,670
+ال zero اللي بواحد يبقى الجواب بس جديد C واحدحط N
+
+133
+00:14:14,670 --> 00:14:25,110
+بـ 2 بصير 2C2 X ناقص A و S 1 يبقى 2C2 X ناقص A 2C2
+
+134
+00:14:25,110 --> 00:14:25,830
+X ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص A
+
+135
+00:14:25,830 --> 00:14:27,450
+2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص
+
+136
+00:14:27,450 --> 00:14:28,530
+A 2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2 X
+
+137
+00:14:28,530 --> 00:14:28,610
+ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2
+
+138
+00:14:28,610 --> 00:14:28,610
+X ناقص A 2C2 X ناقص A 2C2 X ناقص A 2C2 X ناقص A
+
+139
+00:14:28,610 --> 00:14:33,930
+2C2 X ناقص A 2C2
+
+140
+00:14:33,930 --> 00:14:39,130
+X ناقص A
+
+141
+00:14:39,130 --> 00:14:40,590
+2
+
+142
+00:14:45,040 --> 00:14:50,840
+سي واحد مقدار ثابت يبقى مشتقته مع السلامة بصير هذا
+
+143
+00:14:50,840 --> 00:14:58,320
+اتنين سي اتنين زائد ستة سي تلاتة في ال X نقص ال A
+
+144
+00:14:58,320 --> 00:15:06,520
+زائد زائد N في N نقص واحد في C N في ال X نقص ال A
+
+145
+00:15:06,520 --> 00:15:12,320
+تدفع power N زائد اتنين زائد الاخرينبدي اكتب هذا
+
+146
+00:15:12,320 --> 00:15:18,740
+على شكل summation من N تساوي أبصر جداش لغاية ال
+
+147
+00:15:18,740 --> 00:15:26,560
+infinity لل N في ال N ناقص واحد في ال C N في ال X
+
+148
+00:15:26,560 --> 00:15:35,160
+ناقص ال A to the power N minus two N من وين؟ من
+
+149
+00:15:35,160 --> 00:15:41,340
+ناجد اتنين متأكدين؟أه من عند اتنين لأنه طارت term
+
+150
+00:15:41,340 --> 00:15:46,120
+الأول لأن هذا راح طب شوف تعالى تأكد كلامنا صح ولا
+
+151
+00:15:46,120 --> 00:15:50,640
+لأ اتنين اتنين ناقص واحدة بواحد يبقى هذا كله
+
+152
+00:15:50,640 --> 00:15:55,300
+باتنين سي اتنين وهذا zero يبقى واحد يبقى الحد
+
+153
+00:15:55,300 --> 00:16:00,960
+الأول اتنين سي اتنين مظبوط بعد اتنين حط تلاتة بصير
+
+154
+00:16:00,960 --> 00:16:12,520
+تلاتة في اتنين اللي هو بستةC3X-A1 يبقى 6C3X-A1
+
+155
+00:16:12,520 --> 00:16:17,320
+وهكذا يبقى شغلنا سليم مائة بالمائة بنطلع من هذا
+
+156
+00:16:17,320 --> 00:16:22,820
+الكلام يبقى انه عند الاشتقاق مرة ال index اللي تحت
+
+157
+00:16:22,820 --> 00:16:27,280
+الصممش مينجس واحداشتق كمان مرة، بنقص كمان واحد،
+
+158
+00:16:27,280 --> 00:16:31,440
+اشتق كمان مرة، بنقص كمان واحد، و هكذا يعني لو
+
+159
+00:16:31,440 --> 00:16:37,140
+اشتقت N من ال K من المرات بيصير ال summation هذا
+
+160
+00:16:37,140 --> 00:16:43,620
+من عند N تساوي K إلى Infinity وهذا بيصير K من
+
+161
+00:16:43,620 --> 00:16:50,020
+المشتقات، تمام؟ طيب كويس، و هكذا لو استمرنا بهذه
+
+162
+00:16:50,020 --> 00:16:55,390
+الطريقة، فمش بدنا نوصل ل Rصار عندنا two series
+
+163
+00:16:55,390 --> 00:17:01,590
+جداد وعندنا ال series الأصلية هي هذي converge على
+
+164
+00:17:01,590 --> 00:17:06,720
+الفترة اللي عندنا هذيالسيريز المشتقة التنتين هدول
+
+165
+00:17:06,720 --> 00:17:11,380
+converge على نفس الفترة وكمان لو اشتقت ميت مرة
+
+166
+00:17:11,380 --> 00:17:16,680
+كمان بعد ذلك برضه converge على مين يبقى السيريز
+
+167
+00:17:16,680 --> 00:17:24,200
+الأصلية ومشتقتها converge على نفس الفترة يبقى بدنا
+
+168
+00:17:24,200 --> 00:17:27,740
+نشيل هذا بما يأتي فبروح بقول
+
+169
+00:17:34,410 --> 00:17:41,350
+هذه الـ derived كل
+
+170
+00:17:41,350 --> 00:17:46,510
+واحد من هذه السلسلة الوحيدة الوحيدة
+
+171
+00:17:46,510 --> 00:17:54,250
+الوحيدة موجودة في كل موقع
+
+172
+00:17:54,250 --> 00:17:57,570
+في كل
+
+173
+00:17:57,570 --> 00:17:58,350
+موقع في كل موقع في كل موقع
+
+174
+00:18:08,230 --> 00:18:15,550
+مقارنة مقارنة مقارنة مقارنة مقارنة
+
+175
+00:18:24,950 --> 00:18:32,430
+original series يبقى كل من المتسلسلات المشتقة
+
+176
+00:18:32,430 --> 00:18:36,670
+converge على نفس الفترة الاسيسي الأصلية converge
+
+177
+00:18:36,670 --> 00:18:43,630
+عليها بدأ نيجي للنقطة الثانية والاخيرة في هذا ال
+
+178
+00:18:43,630 --> 00:18:50,770
+section term by term integration theorem بعد ما
+
+179
+00:18:50,770 --> 00:18:54,030
+فاضلنا بدنا نروح هنا ان كامل
+
+180
+00:18:58,810 --> 00:19:05,930
+بقول افترض انه suppose that suppose
+
+181
+00:19:05,930 --> 00:19:12,350
+that ال F of X بده تسوي ال summation من N equal
+
+182
+00:19:12,350 --> 00:19:19,490
+zero to infinity ل C N X نقص ال A to the power N
+
+183
+00:19:19,490 --> 00:19:30,510
+converged for Xاللي هي أكبر من ال A ناقص ال R وأقل
+
+184
+00:19:30,510 --> 00:19:38,270
+من ال A زائد ال R وال R greater than zero
+
+185
+00:20:02,330 --> 00:20:09,770
+النفس الفترة اللي عندنا هذهالـ A ناقص الـ R إلى
+
+186
+00:20:09,770 --> 00:20:19,270
+الـ A زائد R and وفي نفس الوقت تكامل لل F of X DX
+
+187
+00:20:19,270 --> 00:20:25,890
+بدي ساوي اللي هو summation من N equal zero to
+
+188
+00:20:25,890 --> 00:20:35,140
+infinity لمين؟ للـCN X ناقص الـ Ato the power n
+
+189
+00:20:35,140 --> 00:20:42,740
+plus one على n plus one plus constant c على نفس
+
+190
+00:20:42,740 --> 00:20:53,220
+الفترة اللي هو من a ناقص r إلى a زائد r examples
+
+191
+00:20:53,220 --> 00:20:59,040
+consider
+
+192
+00:20:59,040 --> 00:20:59,960
+the function
+
+193
+00:21:04,680 --> 00:21:12,160
+يعتبر الدالة EO6 يساوي summation من N equal zero
+
+194
+00:21:12,160 --> 00:21:17,980
+to infinityللـ x to the power n على n factorial
+
+195
+00:21:17,980 --> 00:21:25,260
+اللي هي واحد زاد x زاد x تربيع اتنين factorial x
+
+196
+00:21:25,260 --> 00:21:30,100
+تكيب على تلاتة factorial زاد x أس n على n
+
+197
+00:21:30,100 --> 00:21:41,040
+factorial زاد الاخرين that converge for all x
+
+198
+00:21:42,530 --> 00:21:53,770
+المطلوب الأول show that بيّلي ان مشتقة ال EO6 بده
+
+199
+00:21:53,770 --> 00:22:04,190
+تساوي ال EO6 نمرا بيه show that بيّلي تكامل ال EO6
+
+200
+00:22:04,190 --> 00:22:09,830
+DX بده يساوي ال EO6 زائد constant C
+
+201
+00:22:38,330 --> 00:22:43,830
+أحنا هنا كنا بنتكلم عن الاشتقاق لل power series و
+
+202
+00:22:43,830 --> 00:22:48,930
+as a functionمحطوطة ال series اللي عندنا as a
+
+203
+00:22:48,930 --> 00:22:53,170
+function على الشكل اللي عندنا هذا اشتقنا مرة و
+
+204
+00:22:53,170 --> 00:22:57,930
+مرتين و في كل مرة بتغير ال index اللي تحت ال
+
+205
+00:22:57,930 --> 00:23:04,550
+summation كل اشتقاق بنجس ال index بمقدار واحد ال
+
+206
+00:23:04,550 --> 00:23:08,730
+series المشتقة و ال series الأصلية كلهم converge
+
+207
+00:23:08,730 --> 00:23:13,530
+على نفس الفترة تعليل ال integration term by term
+
+208
+00:23:14,010 --> 00:23:20,430
+يعني بدنا نكامل كل term من حدود ال series ونعرف ما
+
+209
+00:23:20,430 --> 00:23:25,870
+هو شكل ال series الناتجة يفترض ان ال F of X مكتوبة
+
+210
+00:23:25,870 --> 00:23:30,190
+عندي على شكل summation بهذا الشكل طبعا يمكن
+
+211
+00:23:30,190 --> 00:23:35,420
+تستغربواان ال function مكتوبة على شكل summation
+
+212
+00:23:35,420 --> 00:23:40,680
+بهذا الشكل ولا استغرب ولا حاجة المحاضرة القادمة ان
+
+213
+00:23:40,680 --> 00:23:45,720
+شاء الله يعني ال section القادم كله كيفية كتابة ال
+
+214
+00:23:45,720 --> 00:23:50,780
+functions على شكل power series وهذه اللي بنسميها
+
+215
+00:23:50,780 --> 00:23:56,430
+taylor series و maclaurin seriesيبقى افترض انه
+
+216
+00:23:56,430 --> 00:23:59,870
+عنده function محطوط على شكل power series و هذي ت
+
+217
+00:23:59,870 --> 00:24:03,430
+converge على نفس الفترة اللي عندنا هذي then
+
+218
+00:24:03,430 --> 00:24:08,710
+summation على ال series هذي هذي شو بتفرق عن هذي سي
+
+219
+00:24:08,710 --> 00:24:13,250
+ان مقدار ثابت زي ما هو يبقى aboveنا لل أس واحدة و
+
+220
+00:24:13,250 --> 00:24:18,570
+قسمنا علمين على الأس الجديد يبقى كأنه اش عملنا
+
+221
+00:24:18,570 --> 00:24:24,190
+لهذهعاملنا لها تكامل كأنه كاملناها يبقى ال series
+
+222
+00:24:24,190 --> 00:24:30,050
+هذي converge على نفس الفترة وبالتالي تكامل لل f of
+
+223
+00:24:30,050 --> 00:24:34,490
+x dx يسوى النتيجة اللي عندنا هذي بالضبط تماما زاد
+
+224
+00:24:34,490 --> 00:24:39,770
+man زاد constant وعلى نفس ال interval اللي عندنا
+
+225
+00:24:42,060 --> 00:24:46,560
+بناخد أمثلة على ال differentiation term by term و
+
+226
+00:24:46,560 --> 00:24:52,420
+ال integration term by term سواء جلي او مجليش يعني
+
+227
+00:24:52,420 --> 00:24:54,740
+مجليش استخدم ال differentiation او استخدم ال
+
+228
+00:24:54,740 --> 00:24:59,730
+integration او اطالي مثلا و بده حلةبقول هنا اعتبر
+
+229
+00:24:59,730 --> 00:25:03,530
+الدالة EO6 مكتوبة على شكل ال summation اللى عندنا
+
+230
+00:25:03,530 --> 00:25:07,770
+هذا او ال summation الطويل اللى عندنا هذا بقول
+
+231
+00:25:07,770 --> 00:25:10,910
+كويسه اللى بتبقى converge على كل ال real line
+
+232
+00:25:10,910 --> 00:25:15,070
+بالاستثناء يعني ال interval of convergenceمن سالب
+
+233
+00:25:15,070 --> 00:25:19,370
+infinity إلى infinity واحنا شوفنا في ال power
+
+234
+00:25:19,370 --> 00:25:23,510
+series ممكن تكون ال series converge على كل ال real
+
+235
+00:25:23,510 --> 00:25:28,890
+line بلا ستة نار المطلوب الأول بيقول إن مشتقة ال
+
+236
+00:25:28,890 --> 00:25:34,430
+EO6 هي ال EO6 itself طب هذا خدناه أين؟
+
+237
+00:25:42,900 --> 00:25:46,640
+أثبتنا إن مشتقة الـ EO6 هي الـ EO6 بس عن طريق الـ
+
+238
+00:25:46,640 --> 00:25:51,240
+LEN هنا لأ بدك تثبت عن طريق الـ Power Series اتنين
+
+239
+00:25:51,240 --> 00:25:57,100
+بدك تثبت تكمل الـ EO6 هو بالـ EO6 itself زاد كنصة
+
+240
+00:25:57,100 --> 00:26:02,280
+برضه باستخدام من الـ Power Series نقوله كويس خلينا
+
+241
+00:26:02,280 --> 00:26:10,360
+نمسك الأولىيبقى بداش اقوله D على D لل E وال6
+
+242
+00:26:10,360 --> 00:26:15,940
+يساوي، بدى اشتق معناته هذه، يعني بدى اشتق كل
+
+243
+00:26:15,940 --> 00:26:21,740
+الحدود اللي عندنا، مشتقة الواحد بقداش؟ Par هذا،
+
+244
+00:26:21,740 --> 00:26:30,240
+مشتقة ال X بواحد؟اللي بعده 2x على 2 factorial زائد
+
+245
+00:26:30,240 --> 00:26:38,380
+2x على 2 factorial زائد 3x تربيع على 3 factorial
+
+246
+00:26:38,380 --> 00:26:45,920
+زائد n x أُس n ناقص واحد على n factorial زائد إلى
+
+247
+00:26:45,920 --> 00:26:54,760
+آخرهمطيب تمام يبقى صار عندي D على DX لل EO6 يساوي
+
+248
+00:26:54,760 --> 00:27:03,400
+واحد زائر هذه لو فكيتها عبارة عن اتنين في اتنين في
+
+249
+00:27:03,400 --> 00:27:10,100
+واحد factorial هذه تلاتة في اتنين factorial هذه N
+
+250
+00:27:10,100 --> 00:27:15,760
+في N ناقص واحد factorialيبقى الاتنين هتروح مع
+
+251
+00:27:15,760 --> 00:27:20,840
+اتنين والتلاتة هتروح مع التلاتة يبقى بيظل عندي
+
+252
+00:27:20,840 --> 00:27:26,340
+زائد x على واحد factorial زائد x تربيع على اتنين
+
+253
+00:27:26,340 --> 00:27:32,660
+factorial زائد x تكيب على تلاتة factorial زائد
+
+254
+00:27:32,660 --> 00:27:40,770
+زائدبتروح ال N مع ال N يبقى X أس N minus ال one N
+
+255
+00:27:40,770 --> 00:27:48,810
+minus ال one factorial بالشكل اللي عندنا هنا زائد
+
+256
+00:27:48,810 --> 00:27:54,350
+إلى آخرينيبقى الان بتروح اكتبها على شكل summation
+
+257
+00:27:54,350 --> 00:27:58,530
+يبقى لو كتبتها على شكل summation بده أصير
+
+258
+00:27:58,530 --> 00:28:07,410
+summation للحد انهني x أُس n-1 على n-1 factorial
+
+259
+00:28:07,410 --> 00:28:10,950
+بالشكل اللي عندنا هذا طب ال index اللي تحت ال
+
+260
+00:28:10,950 --> 00:28:15,380
+summation من وين بده يبدأ؟عند الواحدة لو أصلا عندي
+
+261
+00:28:15,380 --> 00:28:21,580
+zero طار أول term يبقى summation من N equal one to
+
+262
+00:28:21,580 --> 00:28:26,120
+infinity بالفعل لو بدأت أحط N بواحد و اتنين و
+
+263
+00:28:26,120 --> 00:28:31,320
+تلاتة بلاقي ال series اللي عندنا هذه يبقى لا يزال
+
+264
+00:28:31,320 --> 00:28:35,720
+المشكلة عندنا قائمة هل ال summation اللي احنا
+
+265
+00:28:35,720 --> 00:28:41,680
+كتبناه هو ال E و ال six اللي احنا حكينا عليها هذه
+
+266
+00:28:43,190 --> 00:28:48,910
+هي بالضبط و الله في خلاف اه في خلاف ال index اللى
+
+267
+00:28:48,910 --> 00:28:53,630
+فوق بيبدأ من عند ال zero هذا ال index بيبدأ من وين
+
+268
+00:28:53,630 --> 00:28:58,990
+من عند ال واحد مانفعش بدك يتساوي بها بدها تكون
+
+269
+00:28:58,990 --> 00:29:07,790
+زيها رسمًا بنقوله كويس اذا أصبح عندي D على DX لل
+
+270
+00:29:07,790 --> 00:29:15,420
+EO6 يساوي طلّال ال summation هذاممكن اخلّيه يبدأ
+
+271
+00:29:15,420 --> 00:29:20,240
+من اندزيرو لو شيلت كل N وحطيت مكانها N زائد واحد
+
+272
+00:29:20,240 --> 00:29:24,540
+يبقى بدي اشيل كل N وحط مكانها N زائد واحد ده يصير
+
+273
+00:29:24,540 --> 00:29:31,310
+N زائد واحد تساوي واحد الى infinityلل X أُس N زائد
+
+274
+00:29:31,310 --> 00:29:36,750
+واحد وين ناقص واحد على N زائد واحد ناقص واحد
+
+275
+00:29:36,750 --> 00:29:42,390
+factorial يبقى هذه ال summation من عند N equal
+
+276
+00:29:42,390 --> 00:29:47,350
+zero to infinity لل X to the power N على N
+
+277
+00:29:47,350 --> 00:29:52,270
+factorial بروح واحد وسلب واحد وفوق واحد وسلب واحد
+
+278
+00:29:52,730 --> 00:29:57,310
+مين هي هذه؟ مش هذه الصيغة لأن هذه بالضبط تماما
+
+279
+00:29:57,310 --> 00:30:04,570
+يبقى هذه بدها تعطينا مين؟ EO6 وكأن هذا برهان أخر
+
+280
+00:30:04,570 --> 00:30:10,050
+ليثبت أن ال derivative لل EO6 بيعطينا مين؟ EO6
+
+281
+00:30:10,050 --> 00:30:19,720
+itself خلص المطلوب A، روح للمطلوب Bبنتكامل لل E أس
+
+282
+00:30:19,720 --> 00:30:26,040
+X DX يبقى تكامل بدنا نشيل ال E أس X ونحط المفكوك
+
+283
+00:30:26,040 --> 00:30:30,980
+تبعها اللي هو واحد زائد X زائد X تربيه على اتنين
+
+284
+00:30:30,980 --> 00:30:37,020
+factorial X تكيب على تلاتة factorial زائد X أس N
+
+285
+00:30:37,020 --> 00:30:41,980
+على N factorial زائد إلى ما شاء الله كله بالنسبة
+
+286
+00:30:41,980 --> 00:30:50,780
+لمن؟ إلى DXإذا أصبح تكامل ال EOSX DX بده يساوي
+
+287
+00:30:50,780 --> 00:30:57,820
+بدنا نكامل الحد الأول تكامله كده؟ التاني X تربيه
+
+288
+00:30:57,820 --> 00:31:03,160
+على تانية تالت X تكايبعلى تلاتة في الاتنين
+
+289
+00:31:03,160 --> 00:31:08,920
+factorial كما هي زيد ال X تلاتة بيصير X أص أربعة
+
+290
+00:31:08,920 --> 00:31:15,780
+على أربعة في تلاتة factorial كما هي زيد X أص N
+
+291
+00:31:15,780 --> 00:31:22,520
+plus one على N plus one في ال N factorial زيد إلى
+
+292
+00:31:22,520 --> 00:31:30,220
+آخرى وهذه بيجيها كمان جداش يا شبابكنوس فانتبه عدت
+
+293
+00:31:30,220 --> 00:31:40,000
+كامة فهذه بدات ساوية طلعليه كويس هنا ه هذه X هذه X
+
+294
+00:31:40,000 --> 00:31:44,460
+تربيع اتنين هذه مش هبقى اقارب اتنين في واحد يعني
+
+295
+00:31:44,460 --> 00:31:50,180
+اتنين factorial يبقى اتنين factorial وهذه واحد
+
+296
+00:31:50,180 --> 00:31:55,710
+تاني واحد factorialوهذه x تكييب تلاتة في اتنين
+
+297
+00:31:55,710 --> 00:32:01,010
+factorial يعني تلاتة factorial x أُص أربعة أربعة
+
+298
+00:32:01,010 --> 00:32:07,130
+في تلاتة factorial تعني أربعة factorial زائد هذه
+
+299
+00:32:07,130 --> 00:32:13,450
+كمان بنفس الطريقة xn زائد واحد على n زائد واحد
+
+300
+00:32:13,450 --> 00:32:21,430
+اللي هو factorial زائد الآخرى زائد constant Cطيب
+
+301
+00:32:21,430 --> 00:32:27,670
+الخطة أحطها على شكل summation يبقى هذه summation
+
+302
+00:32:27,670 --> 00:32:34,430
+لمن؟ لل x to the power n plus one على n plus one
+
+303
+00:32:34,430 --> 00:32:41,490
+factorial من عند n تسوى أبصر جداش ل infinity هل
+
+304
+00:32:41,490 --> 00:32:45,830
+لما نكملنا هنا ال series هذه طار أي term من
+
+305
+00:32:45,830 --> 00:32:51,440
+الترمات؟لا كله ظلم زي ما هو إذا ال index اللي تحت
+
+306
+00:32:51,440 --> 00:32:56,640
+ال summation بتغير والله بيبقى كما هو يبقى كما هو
+
+307
+00:32:56,640 --> 00:33:02,440
+كما ذكرنا في الجزء النظري قبل قليل يبقى بدء ظلم
+
+308
+00:33:02,440 --> 00:33:09,660
+عند n تساوي zero إلى infinity طيب زاد ال constant
+
+309
+00:33:09,660 --> 00:33:10,220
+C
+
+310
+00:33:13,470 --> 00:33:24,310
+خلّيني اضغط و اقول C1 C1 C1 مثلا هل هذا شكل ال E و
+
+311
+00:33:24,310 --> 00:33:31,070
+S X؟ طبعا لأ هذي بده تبقى X أس N و هذي N factorial
+
+312
+00:33:31,070 --> 00:33:36,050
+بسيطة الشغلة في دينها إذا بدي أشيل كل N و أكتب
+
+313
+00:33:36,050 --> 00:33:41,490
+مكانهان ناقص واحد يبقى هذا الكلام يساوي ال
+
+314
+00:33:41,490 --> 00:33:47,930
+summation ن ناقص واحد تساوي zero الى infinity لل X
+
+315
+00:33:47,930 --> 00:33:54,510
+أس N ناقص واحد زائد واحد على N ناقص واحد زائد واحد
+
+316
+00:33:54,510 --> 00:34:00,390
+كله factorial ويساوي ال summation من N equal one
+
+317
+00:34:00,390 --> 00:34:06,290
+to infinity لل X أس N على N factorial
+
+318
+00:34:08,940 --> 00:34:14,520
+هل هادى يبقى .. طبعا في constant C1 يبقى هنا زائد
+
+319
+00:34:14,520 --> 00:34:25,000
+C1 وهنا زائد C1 هل هادى هي ال exponential اللى
+
+320
+00:34:25,000 --> 00:34:30,470
+عندنا هادى؟ لأ، من هنا بتبدأ من وين؟من اين دي
+
+321
+00:34:30,470 --> 00:34:35,230
+Zero؟ من هنا بتبدأ من وين؟ بدنا حل هالمشكلة هذه
+
+322
+00:34:35,230 --> 00:34:40,170
+وديها بالك بدك تحل وتحافظ على المكتسبات الوطنية
+
+323
+00:34:40,170 --> 00:34:45,350
+اللي عندك هذه اللي حصلت عليها تلعبش يضيعاش ودبر
+
+324
+00:34:45,350 --> 00:34:53,110
+حالك بأي طريقة رياضية سليمة اقترح ان احنا في أي حد
+
+325
+00:34:55,870 --> 00:35:01,410
+ممتاز انا بدي شكل يعطيني الشكل هذا يعني بنفع احذف
+
+326
+00:35:01,410 --> 00:35:07,570
+حد من الحدود من هنا نضيف نضيف مش نحذر طب ما هو
+
+327
+00:35:07,570 --> 00:35:13,390
+الحد اللي جاي في بالك نضيفه كلام كويس ال zero هل
+
+328
+00:35:13,390 --> 00:35:18,910
+ال zero بيغير من هذا الشكل بيغير بس ماتحطش zero
+
+329
+00:35:18,910 --> 00:35:23,310
+حطه بشكل اخر اللي بدك تضيفه بدك تطرحه
+
+330
+00:35:26,950 --> 00:35:32,370
+أنا لو روحت اضافت واحد و طرحت واحد كان ضائف كم؟
+
+331
+00:35:32,370 --> 00:35:39,050
+Zero لان ليش اي اشكالية بقول كويس اذا هذه بقدر
+
+332
+00:35:39,050 --> 00:35:43,950
+اكتبها واحد زاد summation من N equal one to
+
+333
+00:35:43,950 --> 00:35:50,770
+infinity لل X to the power N على N factorial زاد C
+
+334
+00:35:50,770 --> 00:35:57,010
+one ناقص واحديبقى اضافت واحد واطرحت واحد كأنه ضايف
+
+335
+00:35:57,010 --> 00:36:03,350
+Zero كمقترحة أحدكم لكن ال Zero حطيت واحد وسلب واحد
+
+336
+00:36:03,350 --> 00:36:10,550
+طيب شوف لهذا شو بيساوي هذا summation من N equal
+
+337
+00:36:10,550 --> 00:36:15,890
+zero to infinity لل X to the power N على N
+
+338
+00:36:15,890 --> 00:36:22,930
+factorial هذا الجزء يعني هذا صحيحيقولك ماشي مصدق
+
+339
+00:36:22,930 --> 00:36:30,170
+جرب وضع ن بزيرو فاكتوريا اللي بيجي داشر بواحد هنا
+
+340
+00:36:30,170 --> 00:36:33,570
+X و Zero بواحد يبقى واحد على واحد بواحد اللي هو
+
+341
+00:36:33,570 --> 00:36:38,950
+الحد الاول زاد وضع ن بواحد بيجيب الحد التاني و
+
+342
+00:36:38,950 --> 00:36:45,190
+الحد التالت والربع يبقى بالكلام سليم مائة بالمائة
+
+343
+00:36:45,480 --> 00:36:51,220
+بالله ان دي زائد مين زاد هذا كله يعتبر constant
+
+344
+00:36:51,220 --> 00:36:57,340
+كمان بده يسميه C يبقى هذا زائد constant C و ال C
+
+345
+00:36:57,340 --> 00:37:04,980
+بده يساوي C one ناقص واحد أليست هذه هي ال E و ال 6
+
+346
+00:37:04,980 --> 00:37:13,500
+زائد constant Cتمام؟ لتركها بكويسها لترك هو اللي
+
+347
+00:37:13,500 --> 00:37:18,520
+جدر اللي جدرنا بواصفته نوصل للصيغة المطلوبة
+
+348
+00:37:18,520 --> 00:37:23,960
+ويتكامل EO6 يساوي EO6 زائد constant وبالتالي كأنه
+
+349
+00:37:23,960 --> 00:37:29,760
+احنا أثبتنا ان تكامل EO6 يساوي EO6 زايد constant
+
+350
+00:37:29,760 --> 00:37:35,620
+بطريقة غير الطريقة المتعرف عليها قبل ذلك في
+
+351
+00:37:35,620 --> 00:37:38,600
+section 7 3
+
+352
+00:37:48,580 --> 00:37:57,740
+طيب، هذا مثال يوضح كيف استخدمنا التكامل في الحصول
+
+353
+00:37:57,740 --> 00:38:03,560
+على شكل ال series وسليه قبله كانت فاضل، ايوة ما
+
+354
+00:38:03,560 --> 00:38:10,450
+الاخر خطوة هذه؟ ابدا، لحد اين تمام هذه؟ضيف واحد
+
+355
+00:38:10,450 --> 00:38:16,970
+واطرح واحد كأنك باقى فى قداش هل تتغير القيمة؟ لأ
+
+356
+00:38:16,970 --> 00:38:22,210
+بدنا نضيف هي اضفنا واحد واطرحنا واحد الواحد هذا مع
+
+357
+00:38:22,210 --> 00:38:26,290
+ال summation بدي اجملهم ب summation واحد يبقى هي
+
+358
+00:38:26,290 --> 00:38:29,810
+جمالتهم ب summation واحد ممكن و لا مش ممكن تعالى
+
+359
+00:38:29,810 --> 00:38:35,670
+نشوف حط N ب Zero بطلع الحد الاول عندك بواحدحط in
+
+360
+00:38:35,670 --> 00:38:38,310
+من واحد إلى المقل النهائي بيعطيك ال sub machine
+
+361
+00:38:38,310 --> 00:38:42,670
+التاني يبقى كلامنا سليم مئة بالمئة جينا على ال C
+
+362
+00:38:42,670 --> 00:38:46,310
+والنقص واحد هذا كله constant سميته constant z
+
+363
+00:38:46,310 --> 00:38:50,390
+ويسوى من C sub machine هو ال exponential function
+
+364
+00:38:50,390 --> 00:38:55,330
+وده ال constant يبقى فعلا تكمل E وال6 بE وال6 زاد
+
+365
+00:38:55,330 --> 00:39:01,230
+constant C طيب برضه بيناعطيك كمان مثال على هذا
+
+366
+00:39:01,230 --> 00:39:07,010
+الموضوع وفتح عينك كويس دجج معايامثال رقم اتنين
+
+367
+00:39:07,010 --> 00:39:15,570
+بيقول
+
+368
+00:39:15,570 --> 00:39:20,950
+find a function
+
+369
+00:39:20,950 --> 00:39:29,730
+f of x that represented
+
+370
+00:39:29,730 --> 00:39:31,690
+by
+
+371
+00:39:37,510 --> 00:39:41,970
+بعد عملية عملية عملية عملية عملية عملية عملية
+
+372
+00:39:41,970 --> 00:39:56,610
+عملية عملية عملية عملية عملية
+
+373
+00:39:59,320 --> 00:40:05,580
+the result استخدم النتيجة اللي حصلت عليها to find
+
+374
+00:40:05,580 --> 00:40:10,080
+a
+
+375
+00:40:10,080 --> 00:40:16,240
+power series that
+
+376
+00:40:16,240 --> 00:40:22,120
+represent that represent
+
+377
+00:40:22,120 --> 00:40:25,240
+that
+
+378
+00:40:25,240 --> 00:40:27,780
+represent the following
+
+379
+00:40:33,020 --> 00:40:39,520
+التي تمثل الدوالة التالية الدالة الأولى نمره A
+
+380
+00:40:39,520 --> 00:40:47,120
+الـG of X يساوي واحد على واحد زائد X لكل تربية
+
+381
+00:40:47,120 --> 00:40:56,660
+نمره B الـG of X بده يساوي Len واحد زائد X
+
+382
+00:41:29,460 --> 00:41:35,240
+هاتلي دالة تمثل هذه الـ Power Series
+
+383
+00:41:42,560 --> 00:41:48,140
+بعد هيك النتيجة اللى تحصل عليها بدك تستخدمها في
+
+384
+00:41:48,140 --> 00:41:52,280
+الحصول على power series لتو functions اللى عندك
+
+385
+00:41:52,280 --> 00:41:57,680
+يعني عملية عكسية ماتيني power series بد اتدلتها
+
+386
+00:41:57,680 --> 00:42:01,460
+تبعتها يبقى سعر اندي دالة و سعر power series بد
+
+387
+00:42:01,460 --> 00:42:07,160
+تستخدم هذه النتيجة للحصول على شكل ال power series
+
+388
+00:42:07,160 --> 00:42:13,760
+لها تين اتدلتينكم مطموض عندي في السؤال؟ ثلاثة،
+
+389
+00:42:13,760 --> 00:42:17,480
+خلّينا المطموض الأول نجيبه وبعدين بروح ندور على A
+
+390
+00:42:17,480 --> 00:42:21,980
+وBيبقى بدنا نيجي المطلوب الأول قبل ما نبدأ المطلوب
+
+391
+00:42:21,980 --> 00:42:26,220
+الأول بدي أعرف ما هو الشكل ال power series اللي
+
+392
+00:42:26,220 --> 00:42:30,700
+معطهالي هذه يبقى باجي بقوله summation من n equal
+
+393
+00:42:30,700 --> 00:42:35,640
+zero to infinity لسالب واحد to the power n لل x to
+
+394
+00:42:35,640 --> 00:42:41,680
+the power n هذه واحد ناقص x زائد x تربية ناقص x
+
+395
+00:42:41,680 --> 00:42:46,660
+تكييب زائد ناقص واحد to the power n x to the power
+
+396
+00:42:46,660 --> 00:42:54,300
+n زائد إلى آخرينطيب السؤال هو مين ال series هذه هل
+
+397
+00:42:54,300 --> 00:42:59,540
+واحدة هذه من التلاتة series المشهورة ال geometric
+
+398
+00:42:59,540 --> 00:43:07,240
+ال P ال harmonic هذه واحدة منهم geometric ليش اجسم
+
+399
+00:43:07,240 --> 00:43:14,240
+اي حد على السابق له بطلع كله سالب X يبقى هذه بقوله
+
+400
+00:43:14,240 --> 00:43:21,810
+convert geometric seriesإذا كان ال absolute value
+
+401
+00:43:21,810 --> 00:43:26,910
+ل R هو absolute value ل سلب X قداش absolute value
+
+402
+00:43:26,910 --> 00:43:32,410
+ل سلب X أليس هو absolute value ل X وهذا يجب أن
+
+403
+00:43:32,410 --> 00:43:35,830
+يكون أقل من واحد إذا كان ال absolute value ل X أقل
+
+404
+00:43:35,830 --> 00:43:37,950
+من واحد إذا كان ال absolute value ل X أقل من واحد
+
+405
+00:43:37,950 --> 00:43:42,690
+إذا كان ال absolute value ل X أقل من واحد إذا كان
+
+406
+00:43:42,690 --> 00:43:42,910
+ال absolute value ل X أقل من واحد إذا كان ال
+
+407
+00:43:42,910 --> 00:43:46,030
+absolute value ل X أقل من واحد إذا كان ال absolute
+
+408
+00:43:46,030 --> 00:43:55,900
+value ل X أقل من واحدinterval of convergence as
+
+409
+00:43:55,900 --> 00:43:58,120
+سالب واحد و واحد
+
+410
+00:44:02,490 --> 00:44:06,490
+يبقى الرياضة اصلا كده؟ برضه واحد بهمني شرية دي
+
+411
+00:44:06,490 --> 00:44:11,090
+الصينة خلاص نجيبناله فترة التقارب تبع ال series
+
+412
+00:44:11,090 --> 00:44:16,070
+يبقى على فترة التقارب من سلب واحد إلى واحد بقدر
+
+413
+00:44:16,070 --> 00:44:21,890
+اوجد مجموع هذه ال series جالي هاتلي الدالة التي
+
+414
+00:44:21,890 --> 00:44:30,180
+تمثل هذه ال power series يبقى باجي بقوله the sumof
+
+415
+00:44:30,180 --> 00:44:40,540
+the series S ال S تساوي الحد الأول على واحد ناقص
+
+416
+00:44:40,540 --> 00:44:48,620
+الأساس هذا شو بيعطينا؟ هذا بيعطينا أن ال S يساوي
+
+417
+00:44:48,620 --> 00:44:55,930
+واحد على واحد زائد ال X أليس هذه function في X؟صح
+
+418
+00:44:55,930 --> 00:45:03,190
+ولا لا؟ يبقى هذه بدها تساوي ال F of X تمام تمام
+
+419
+00:45:03,190 --> 00:45:09,990
+يبقى هاي كتبتله المجموع تبع ال series as a
+
+420
+00:45:09,990 --> 00:45:14,690
+function هات ال F of X التي تمثل بال power series
+
+421
+00:45:14,690 --> 00:45:18,390
+يبقى كأنه جمعت ال power series فطلها المجموع
+
+422
+00:45:18,390 --> 00:45:25,940
+بالشكل هذا يبقى هذا الذي يساوي منF of X. إذا خلصنا
+
+423
+00:45:25,940 --> 00:45:31,680
+المطلوب الأول جيبنا دالة ان ال power series عندها
+
+424
+00:45:31,680 --> 00:45:36,660
+المُعطَع يبقى ال power series كان هبقى L 1 على 1
+
+425
+00:45:36,660 --> 00:45:42,660
+زائد X. تمام؟ طبعا كويس. بدنا نيجي الآن للمطلوب
+
+426
+00:45:42,660 --> 00:45:48,700
+الأولجاب المبدأ المطلوب الأول بدي أقوله f of x ليه
+
+427
+00:45:48,700 --> 00:45:54,280
+واحد على واحد زائد x وليه بدي تساوي واحد ناقص x
+
+428
+00:45:54,280 --> 00:46:00,340
+زائد x تربية ناقص x تكييب زائد ناقص one to the
+
+429
+00:46:00,340 --> 00:46:04,060
+power n x to the power n زائد إلى آخرين
+
+430
+00:46:09,070 --> 00:46:16,440
+هذه المقارنة هي نفس النتيجة بس المقارنة مربعيعني
+
+431
+00:46:16,440 --> 00:46:21,200
+نربعها و نمشي الحال خلاصنا طيب خلنا نناقش احنا
+
+432
+00:46:21,200 --> 00:46:27,380
+وياكم لو ترمين وربعتهم بتطلع تلت ترمات ودي سهل
+
+433
+00:46:27,380 --> 00:46:32,880
+مربع الأول اتنين حصل ضرب اتنين مربع التاني سهل طيب
+
+434
+00:46:32,880 --> 00:46:38,680
+لو كانوا تلاتة بيبدأ الحرارة ترتفع عندك بتقدروا
+
+435
+00:46:38,680 --> 00:46:43,620
+تلت ترمات زي تلت ترمات اضربهم ببعض طيب لو قلت خلي
+
+436
+00:46:43,620 --> 00:46:50,080
+تملك أربعةبتبقى النبض يرتفع، مش هيك؟ لو قولتلك خمس
+
+437
+00:46:50,080 --> 00:46:55,040
+ترمات، ستة بعشر ترمات، وقول اه ورا دي بدي أقعد
+
+438
+00:46:55,040 --> 00:46:59,360
+ساعتين وانا أضرب فيهم ولا تلت ساعات، فما بالك إذا
+
+439
+00:46:59,360 --> 00:47:04,080
+كان مالة نهاية من الحدود، يبقى إحكاية إن ربي
+
+440
+00:47:04,080 --> 00:47:10,480
+أحصفها على شجة ده بتوصلكش إلى نتيجةطبعا فادبر حالك
+
+441
+00:47:10,480 --> 00:47:14,380
+شو موضوع ده هنا موضوع من derivative term by term
+
+442
+00:47:14,380 --> 00:47:18,920
+او integration term by term بدي بسأل نفسي هل الدلة
+
+443
+00:47:18,920 --> 00:47:23,240
+دي لو عملت لها derivative او integral بحصل على
+
+444
+00:47:23,240 --> 00:47:28,740
+واحد على واحد زي ديكستربية نشتاق نشتاق اذا لو
+
+445
+00:47:28,740 --> 00:47:33,040
+اشتقنا بتطلع الدلة المطلوبة بقولك كويس يبقى اذا
+
+446
+00:47:33,040 --> 00:47:37,360
+تعال نشتاق .. ماجالليش هو اشتق انا لحالة أرفكهذا
+
+447
+00:47:37,360 --> 00:47:41,640
+يجب أن تبقى دقيق الملاحظة لما هو المطلوب، أما لو
+
+448
+00:47:41,640 --> 00:47:45,440
+ربعتها تقول تربيها 12 أكل استراليزي، تقول يا الله
+
+449
+00:47:45,440 --> 00:47:49,010
+من أعرففيش حاجة مش عارف انت بيجي جيبلي ال series
+
+450
+00:47:49,010 --> 00:47:53,470
+اللي تمثله هذه الدلة و بعدين جالك ايش مش جالك روح
+
+451
+00:47:53,470 --> 00:47:58,970
+ربها جالك use the result يعني قيدك كيف تشتغل بقوله
+
+452
+00:47:58,970 --> 00:48:05,310
+انا بروح اشتقها يبقى هذه ال F prime of X سالب واحد
+
+453
+00:48:05,310 --> 00:48:10,710
+على واحد زائد X لكل تربية whatو ساوي اظن الأول
+
+454
+00:48:10,710 --> 00:48:18,520
+بيروح ناقص واحدزيدي اتنين X ناقص ثلاثة X تربية زيد
+
+455
+00:48:18,520 --> 00:48:25,360
+أبصر مين؟ زائد ناقص واحد to the power N في ال N في
+
+456
+00:48:25,360 --> 00:48:29,140
+ال X أس N ناقص واحد إلى ما شاء الله
+
+457
+00:48:31,830 --> 00:48:35,470
+طب انا بديش سالب واحد على المقدار اللي عناها، بدي
+
+458
+00:48:35,470 --> 00:48:39,330
+بياها مين؟ بالموجب، إذا بدي أضغط الطرفين كله في
+
+459
+00:48:39,330 --> 00:48:45,590
+إشارة يبقى بيصير الـG of X اللي بده إياها واحد على
+
+460
+00:48:45,590 --> 00:48:52,030
+واحد زاد X لكل تربية يساوي واحدنقص اتنين اكس زائد
+
+461
+00:48:52,030 --> 00:48:58,370
+تلاتة اكس تربية نقص ابصر مين زائد نقص واحد قص ابصر
+
+462
+00:48:58,370 --> 00:49:04,990
+جديش ان اكس نقص واحد زائد نقص واحد قص جديش
+
+463
+00:49:11,550 --> 00:49:15,650
+أنا عندى ناقص واحد أس ان في الأصل وجدوا كمان إشارة
+
+464
+00:49:15,650 --> 00:49:18,770
+سالب يعني كمان سالب واحد يبقى صير سالب واحد أس
+
+465
+00:49:18,770 --> 00:49:26,770
+كده؟ N زائد واحد يبقى بصير أس N زائد واحد وهي هي
+
+466
+00:49:26,770 --> 00:49:32,870
+سيدي على الشكل summation لناقص واحد أس N زائد واحد
+
+467
+00:49:32,870 --> 00:49:39,270
+لل N X أس N ناقص واحد وال summation ببدأ من وين؟من
+
+468
+00:49:39,270 --> 00:49:46,950
+عند الواحد لأنه طار أول term تمام؟ اللي هي مين؟
+
+469
+00:49:46,950 --> 00:49:52,230
+انت عندك سالب واحد قسين أجاله كمان سالب واحد قس
+
+470
+00:49:52,230 --> 00:49:58,290
+واحد بصير كده؟ تساوة الأساسات بنجمع الأساس بصير N
+
+471
+00:49:58,290 --> 00:50:04,090
+زائد واحد خلصنا؟ يبقى يا بيخليها زي هيك يا حابب
+
+472
+00:50:04,390 --> 00:50:09,450
+أخلّيها من عند ال zero بروح بشيل كل N و بحط مكانها
+
+473
+00:50:09,450 --> 00:50:14,750
+N زائد واحد حابب زيكي أهلا وسهلا بدكش تقولي ال
+
+474
+00:50:14,750 --> 00:50:20,110
+summation من عند ال zero ل infinity لنقص واحد أس N
+
+475
+00:50:20,110 --> 00:50:29,180
+زائد اتنين لل N زائد واحد لل X أس Nيعني شيلت كل
+
+476
+00:50:29,180 --> 00:50:33,740
+إنه حطيت مكانها، انزلت، كتبتها على الصيغة هذه، و
+
+477
+00:50:33,740 --> 00:50:38,560
+الله على الصيغة هذه، الأتنين are the same طيب،
+
+478
+00:50:38,560 --> 00:50:43,200
+خلصنا، نمر بيه؟ نمر بيه جالي هاتلي الدالة هذه،
+
+479
+00:50:43,200 --> 00:50:48,220
+الدالة هذه عبارة عن إيش؟تكامل الدالة هذه مظبوط إذا
+
+480
+00:50:48,220 --> 00:50:56,740
+لو جي تقوله ها ال جي of X هي تكامل واحد على واحد
+
+481
+00:50:56,740 --> 00:51:02,200
+زائد X DX معناته الدالة اللي فوق بدي أعملها إيش
+
+482
+00:51:02,200 --> 00:51:08,660
+integration term by term يبقى X ناقص X تربيه على
+
+483
+00:51:08,660 --> 00:51:12,380
+اتنين زاد X تكيب على تلاتة
+
+484
+00:51:32,480 --> 00:51:39,300
+يبقى هذا نتيجة التكامل بروح اضيف له زائد constant
+
+485
+00:51:39,300 --> 00:51:47,260
+Cكويس الان شوفيش النتيجة اللى حصلنا عليها الان
+
+486
+00:51:47,260 --> 00:51:52,580
+قولنا زيادة كونستانسية احنا عندنا ال interval و ال
+
+487
+00:51:52,580 --> 00:51:56,840
+convergence اللى هذى اتدالى من و لا وين يعني محتوى
+
+488
+00:51:56,840 --> 00:52:07,280
+على ال zero كويس بدي بقوله at x يساوي zeroبس قبل
+
+489
+00:52:07,280 --> 00:52:12,700
+ال X يستوي Zero التكامل هذي بقداش أبلن absolute
+
+490
+00:52:12,700 --> 00:52:18,560
+value ل 1 زائد X بدي أشوف هل ال absolute هذي
+
+491
+00:52:18,560 --> 00:52:22,510
+ضرورية ولا ماهياش ضروريةأحنا عندنا ال interval من
+
+492
+00:52:22,510 --> 00:52:28,210
+واحد لسالب واحد لا بيساوي واحد ولا بيساوي سالب
+
+493
+00:52:28,210 --> 00:52:33,290
+واحد إذا عمره المقدار بين القوسين بدي أخد قيمة
+
+494
+00:52:33,290 --> 00:52:38,670
+سالبة مش إمكانية على ال interval من سالب واحد إلى
+
+495
+00:52:38,670 --> 00:52:44,970
+واحد يعني أكبر من سالب واحد و أجل من واحد إذا لا
+
+496
+00:52:44,970 --> 00:52:51,660
+يمكن هذا عمره ياخد قيمةسالبة يبقى هذا بده يساوي لن
+
+497
+00:52:51,660 --> 00:52:58,580
+واحد زائد X on الفترة من سالب واحد إلى واحد يبقى
+
+498
+00:52:58,580 --> 00:53:05,660
+ايش حصل عندنا حصل عندنا اللي هو لن وقبل لن واحد
+
+499
+00:53:05,660 --> 00:53:13,700
+زائد Xبالشكل أن هذا اللي هو g of x بده يسوي قداش x
+
+500
+00:53:13,700 --> 00:53:20,580
+ناقص x تربيه على 2 زيد x تكيب على 3 ناقص x أربع
+
+501
+00:53:20,580 --> 00:53:27,780
+على 4 زائد ناقص 1 to the power n x أس n زائد 1 n
+
+502
+00:53:27,780 --> 00:53:33,140
+زائد 1 زائد constant Cالان zero موجود في الفترة
+
+503
+00:53:33,140 --> 00:53:37,260
+عادية صحيح ولا لا ممكن احسب ال constant عند ال
+
+504
+00:53:37,260 --> 00:53:45,160
+zero فبجي بقوله at x يساوي zero ويهربحط x بزيرو
+
+505
+00:53:45,160 --> 00:53:51,600
+بظهر جداش لن الواحد لن الواحد اللي هو بزيرو زيرو
+
+506
+00:53:51,600 --> 00:53:57,200
+زيرو كله زائد زيرو زائد زيرو زائد مش عارف ايه زائد
+
+507
+00:53:57,200 --> 00:54:01,560
+ال constant c يبقى بناء عليها ال c جداش بده يساوي
+
+508
+00:54:01,560 --> 00:54:09,600
+يبقى ال c بيساوي زيرو اذا أصبح عندي لن واحد زائد x
+
+509
+00:54:09,600 --> 00:54:21,210
+هو x ناقص x تربيه علىاتنين زائدx تكيب على 3 ناقص x
+
+510
+00:54:21,210 --> 00:54:28,490
+أس 4 على 4 زائد ناقص 1 to the power n x to the
+
+511
+00:54:28,490 --> 00:54:33,990
+power n plus 1 على n plus 1 أو إذا حبيت تكتبها
+
+512
+00:54:33,990 --> 00:54:40,170
+summation من عند ال n equal 0 to infinity لسالب 1
+
+513
+00:54:40,170 --> 00:54:47,620
+to the power n ل x أس n زائد 1على n زائد واحد
+
+514
+00:54:47,620 --> 00:54:54,240
+انتهى ال section وإليكم أرقام المسائل يبقى
+
+515
+00:54:54,240 --> 00:55:08,640
+exercises اللي هو عشرة exercises عشرة عشرة سبعة
+
+516
+00:55:08,640 --> 00:55:15,290
+عشرة سبعةالمسائل يا سيدي من واحد لتمانية واربعين
+
+517
+00:55:15,290 --> 00:55:25,430
+من واحد لتمانية واربعين multiple of three الامتحان
+
+518
+00:55:25,430 --> 00:55:29,470
+واصل حتى نهاية هذا ال section يعني ال section اللي
+
+519
+00:55:29,470 --> 00:55:35,030
+نبدأ بكرا ان شاء الله مش داخل في الامتحان القادم
+
+520
+00:55:35,490 --> 00:55:40,350
+يعني ابتداء من section تمانية تلاتة وحتى نهاية
+
+521
+00:55:40,350 --> 00:55:44,670
+section عشرة سبعة ان شاء الله تعالى
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/DV4dIOf0KUg_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/DV4dIOf0KUg_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b971d4bbd9208dcb8b5552a07ebbfadf49d677af
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/DV4dIOf0KUg_raw.srt
@@ -0,0 +1,1704 @@
+1
+00:00:14,700 --> 00:00:19,860
+عودة على بدء المرة الماضية بدأنا في بداية ال
+
+2
+00:00:19,860 --> 00:00:23,760
+alternating seriesعطينا تعريف لل alternating
+
+3
+00:00:23,760 --> 00:00:28,120
+series وبدأنا في ال convergence لل alternating
+
+4
+00:00:28,120 --> 00:00:33,420
+series و أعطينا نظرية على هذا الموضوع نذكر بما
+
+5
+00:00:33,420 --> 00:00:36,780
+قلناه في المرة الماضية قلنا بنيجي على ال
+
+6
+00:00:36,780 --> 00:00:41,340
+alternating series وباخد ال a1 و ال a2 و ال a3
+
+7
+00:00:41,340 --> 00:00:47,560
+بدون الإشارات طبعا إذا لجيت كل الحدود هذه positive
+
+8
+00:00:48,800 --> 00:00:55,140
+أتنين لقيت الحدود هذه decreasing تلاتة لقيت limit
+
+9
+00:00:55,140 --> 00:00:58,840
+الحد انه لما ال N بده يروح ل المال انها بده يساوي
+
+10
+00:00:58,840 --> 00:01:03,880
+zero معناته تحققت الشروط التلاتة يبقى ال series او
+
+11
+00:01:03,880 --> 00:01:07,460
+ال alternating series بقول عنها converge في هذه
+
+12
+00:01:07,460 --> 00:01:12,600
+الحالة واطلناكم مثال بسيط عليها اللي كانت
+
+13
+00:01:12,600 --> 00:01:16,220
+alternating harmonic series و أثبتنا
+
+14
+00:01:29,070 --> 00:01:33,650
+التعريف الأول if the series of absolute values
+
+15
+00:01:33,650 --> 00:01:36,490
+summation على a n
+
+16
+00:01:43,390 --> 00:01:46,930
+لأن سالب واحد أُس N زي واحد لما أخده ال absolute
+
+17
+00:01:46,930 --> 00:01:50,890
+value أو سالب واحد أُس N لما أخده ال absolute
+
+18
+00:01:50,890 --> 00:01:55,510
+value النتج جداش يعني كتابته بصير كلك عزيزي، بيضل
+
+19
+00:01:55,510 --> 00:02:00,470
+بس ال absolute value لمن؟ لل A N لو كانت ال series
+
+20
+00:02:00,470 --> 00:02:04,730
+of absolute values converge بروح بقول ال series
+
+21
+00:02:04,730 --> 00:02:08,750
+الأصلية هذه converge absolutely
+
+22
+00:02:16,870 --> 00:02:20,850
+التعريف الثاني بيقول لو ال summation under ال
+
+23
+00:02:20,850 --> 00:02:26,980
+alternating series هذه ما طلعتش convergeيعني ال
+
+24
+00:02:26,980 --> 00:02:31,840
+alternating series هذي طلعت diverge شونعمل is not
+
+25
+00:02:31,840 --> 00:02:34,840
+converge absolutely يعني ماطلعتش converge
+
+26
+00:02:34,840 --> 00:02:38,860
+absolutely يعني طلعت diverge يبجيش في هذه الحلبات
+
+27
+00:02:38,860 --> 00:02:42,420
+satisfy the conditions of the previous theorem
+
+28
+00:02:42,720 --> 00:02:55,080
+بتحقق الشروط التالتة اللي قلت لكم قبل قليل انتقال
+
+29
+00:02:55,080 --> 00:03:00,060
+تقارب
+
+30
+00:03:00,060 --> 00:03:08,120
+تقارب شرطيا او تقارب مشروطا المباحظات التالية اللي
+
+31
+00:03:08,120 --> 00:03:13,220
+عندناالأولى حكيناها التانية converge absolutely
+
+32
+00:03:13,220 --> 00:03:17,120
+تعني converge، converge conditionally تعني كذلك
+
+33
+00:03:17,120 --> 00:03:20,900
+converge يبقى انطلاق تكون ان converge absolutely و
+
+34
+00:03:20,900 --> 00:03:23,720
+لا converge conditionally معناه هذا الكلام ان ال
+
+35
+00:03:23,720 --> 00:03:28,020
+series هذي converge طب لو جيت على الشروط التلاتة و
+
+36
+00:03:28,020 --> 00:03:30,120
+اتطلعت في الشرط التالت
+
+37
+00:03:37,440 --> 00:03:44,100
+الشرط التالت في النظرية لم يتحقق بصير سيرز مالها؟
+
+38
+00:03:44,100 --> 00:03:47,760
+السؤال هو طب ليش الشرط التالت من دون الشروط
+
+39
+00:03:47,760 --> 00:03:52,800
+الأخرى؟الإجابة بسيطة جدا الشرط التالت يعني اختبار
+
+40
+00:03:52,800 --> 00:03:57,500
+الحد النونيالمتر للان لما الان بتروح لمالها لنهاية
+
+41
+00:03:57,500 --> 00:04:02,420
+إذا كان لا يسوى zero يبقى ال series مالها by value
+
+42
+00:04:02,420 --> 00:04:06,020
+مش هيك اختبارها لحد نوني يبقى هنا لحد نوني فأحلى
+
+43
+00:04:06,020 --> 00:04:12,040
+من جولإذا الشرط التالت لم يتحقق كان لا يساوي Zero
+
+44
+00:04:12,040 --> 00:04:16,040
+يبقى في هذه الحالة Series وعن هذه بقول عنها مالها
+
+45
+00:04:16,040 --> 00:04:20,820
+Diverged ايوة طب ايش رأيك؟ بدي الم كلام المرة اللي
+
+46
+00:04:20,820 --> 00:04:25,800
+فاتت و المرة هذه في استراتيجية حل ال alternating
+
+47
+00:04:25,800 --> 00:04:30,860
+series كيف بدنا نحل سؤال ال alternating series؟
+
+48
+00:04:31,230 --> 00:04:34,830
+انتبه معايا كويس الكلام اللى هقوله لك نظري هطبقه
+
+49
+00:04:34,830 --> 00:04:39,350
+الآن على الأمثلة حرفيا ابنجي على ال alternative
+
+50
+00:04:39,350 --> 00:04:43,950
+series الأساسية اللى عندنا هذه و باخدلها series of
+
+51
+00:04:43,950 --> 00:04:47,730
+absolute value بالشكل اللى عندنا هنا طب ليش بدي
+
+52
+00:04:47,730 --> 00:04:51,450
+اخدلها series of absolute value؟ اه بقول انا بدي
+
+53
+00:04:51,450 --> 00:04:55,590
+استخدم الاختباراتوالاختبارات اللي خدناها هما على
+
+54
+00:04:55,590 --> 00:04:59,330
+الاختبار الأول تبع ال end term test كل الاختبارات
+
+55
+00:04:59,330 --> 00:05:04,110
+بيشترق انه series with positive terms الحدود كلها
+
+56
+00:05:04,110 --> 00:05:08,790
+موجبة اذا مشان اقدر استخدم اي اختبار منهم لازم
+
+57
+00:05:08,790 --> 00:05:13,630
+بالنسبة للانتقال اخد منه the series of absolute
+
+58
+00:05:13,630 --> 00:05:18,290
+values مشان اضمن انه كل الحدود موجبة وبالتالي اي
+
+59
+00:05:18,290 --> 00:05:22,010
+استخدم اي اختبار من الاختبارات اللتي سابقة دراستها
+
+60
+00:05:22,410 --> 00:05:27,410
+وكان هذا ال section هو مراجعة لما سبقت دراسته في
+
+61
+00:05:27,410 --> 00:05:34,270
+ال sections الماضية واضح كلامي؟ طيب نرجع للخطوات
+
+62
+00:05:34,270 --> 00:05:38,730
+العملية أخدنا series of absolute values طلعت ال
+
+63
+00:05:38,730 --> 00:05:43,750
+series of absolute values converge يبقى براحة بقول
+
+64
+00:05:43,750 --> 00:05:49,910
+ال series الأصلية converge absolutelyإذا ال series
+
+65
+00:05:49,910 --> 00:05:52,910
+of absolute values لكل حدودها موجة بقلها ت
+
+66
+00:05:52,910 --> 00:05:57,050
+converge بأي اختبار من الاختبارات الستة والتلاتة
+
+67
+00:05:57,050 --> 00:06:00,030
+ال series المشهورة بقول ال series عندي converge
+
+68
+00:06:00,030 --> 00:06:04,230
+absolutely للأصلية طيب إذا ال series of absolute
+
+69
+00:06:04,230 --> 00:06:08,570
+values دايفيرت أقول ال alternative للأصلية دايفيرت
+
+70
+00:06:08,570 --> 00:06:12,910
+بقوله لا لا لا استنى شوية بروح على الشروط التلاتة
+
+71
+00:06:12,910 --> 00:06:18,890
+إذا تحققت الشروط التلاتة في آن واحدبقول ال series
+
+72
+00:06:18,890 --> 00:06:25,310
+converge conditionally طيب إذا الشرط التالت لم
+
+73
+00:06:25,310 --> 00:06:30,190
+يتحقق بقول يبقى ال series اللي لنا مالها diverse
+
+74
+00:06:30,190 --> 00:06:35,910
+تمام؟ طب السؤال هو هل ضروري ترتيب الشروط التلاتة
+
+75
+00:06:35,910 --> 00:06:39,610
+واحد اتنين تلاتة بالترتيب؟ و الله ممكن اروح الشرط
+
+76
+00:06:39,610 --> 00:06:43,800
+التالت دغريممكن على الشرط التالت دقري، إذا الشرط
+
+77
+00:06:43,800 --> 00:06:46,960
+التالت لم يتحقق، مافيش داعي أدور على الشرطين
+
+78
+00:06:46,960 --> 00:06:50,500
+الأثنين هدولك، لكن إذا اتحقق الشرط التالت، بتروح
+
+79
+00:06:50,500 --> 00:06:55,480
+أدور على مين؟ على الشرطين الأثنين التانية طيب،
+
+80
+00:06:55,480 --> 00:07:01,050
+واحد حيسن السؤال التاليهيقول ليش الشرط التالت إذا
+
+81
+00:07:01,050 --> 00:07:04,910
+لم يتحقق ف ال series diverge لكن الشرطين الأولين
+
+82
+00:07:04,910 --> 00:07:09,750
+يعني شو أخبارهم مش هذا سؤال بنقولك بسيطة احنا لما
+
+83
+00:07:09,750 --> 00:07:14,450
+قلنا إذا لم يتحقق الشرط التالت ف ال series diverge
+
+84
+00:07:14,450 --> 00:07:19,350
+روحت استخدمت أحد الاختبارات وهو اختبار الحد النوني
+
+85
+00:07:19,350 --> 00:07:23,130
+فحكمت automatic بصمت ان ال series هذه مالها
+
+86
+00:07:23,130 --> 00:07:29,350
+divergeلكن لو لم يتحقق الشرط الأول أو الشرط الثاني
+
+87
+00:07:29,350 --> 00:07:32,870
+في عندي قاعدة بتحكم هل ال students converge ولا
+
+88
+00:07:32,870 --> 00:07:39,290
+diverge؟ ماعنديش وبالتالي الشرط الأول في في يعني
+
+89
+00:07:39,290 --> 00:07:43,970
+خليني أقولك تسعة وتسعين وشلة تسعات زي الانتخابات
+
+90
+00:07:43,970 --> 00:07:49,650
+العربية كلها بتطلع اه الشرط الأول محقق automatic
+
+91
+00:07:49,650 --> 00:07:55,000
+الشرط التاني بده فحص إما بواسط الاشتقاءأو المقارنة
+
+92
+00:07:55,000 --> 00:07:58,620
+بين الحد النوني والحد النوني زائد واحد ومن خلاله
+
+93
+00:07:58,620 --> 00:08:03,280
+هنحكم على هذي ال series هل هي converge او diverge
+
+94
+00:08:03,280 --> 00:08:08,140
+قبل ان احل الأمثلة عشان اتركز معايا كويس انا بدي
+
+95
+00:08:08,140 --> 00:08:10,800
+ابحث ال series هذي converge و لا diverge بعمل ما
+
+96
+00:08:10,800 --> 00:08:14,220
+يأتي باخد ال series with absolute values طلعت
+
+97
+00:08:14,220 --> 00:08:17,420
+converge بقول converge absolutely طلعت diverge
+
+98
+00:08:17,420 --> 00:08:21,840
+بقول استنى شوية بروح على الشروط التلاتةتحقق الشروط
+
+99
+00:08:21,840 --> 00:08:26,200
+التالتة بقول converge conditionally لم يتحقق الشرط
+
+100
+00:08:26,200 --> 00:08:28,880
+التالت بقول الأصلية diverge وقلصنا كما الله
+
+101
+00:08:28,880 --> 00:08:33,600
+المؤمنين قلت تعالى يبقى هدول ملخص الجزء النضري تبع
+
+102
+00:08:33,600 --> 00:08:37,720
+ال section كله تمام؟ الكلام اللي اسمعته بدنا نروح
+
+103
+00:08:37,720 --> 00:08:41,700
+نطبقه عاملين يبقى انا ميعطيني series وقاللي هل ال
+
+104
+00:08:41,700 --> 00:08:45,000
+series هدى converge absolutely و الله converge
+
+105
+00:08:45,000 --> 00:08:49,060
+conditionally و الله diverge بقوله تعالى نشوفيبقى
+
+106
+00:08:49,060 --> 00:08:52,480
+بدي أبدأ بالخطوة الأولى بدي أخد the series of
+
+107
+00:08:52,480 --> 00:08:59,860
+absolute values فبجي بقول له solution the series
+
+108
+00:08:59,860 --> 00:09:02,020
+of
+
+109
+00:09:04,410 --> 00:09:11,650
+absolute values is summation للأربعة to the power
+
+110
+00:09:11,650 --> 00:09:18,050
+n تلتة to the power n plus one يعني هذه يا شباب هي
+
+111
+00:09:18,050 --> 00:09:25,570
+عبارة عن summation لتلت في أربعة على تلتة كله to
+
+112
+00:09:25,570 --> 00:09:30,440
+the power nهذه عملتها تلاتة في تلاتة to the power
+
+113
+00:09:30,440 --> 00:09:34,920
+n يبقى تلت في أربع على تلاتة to the power n
+
+114
+00:09:34,920 --> 00:09:44,300
+السيريز هذه شو أخبارها عندكم الاساس
+
+115
+00:09:44,300 --> 00:09:48,720
+تبعها أكبر من الواحد الصحيح يبقى هذه
+
+116
+00:09:59,670 --> 00:10:04,950
+النسبة يسوى أربعة على تلاتة أكبر من الواحد الصحيح
+
+117
+00:10:04,950 --> 00:10:10,170
+إذا بقدر أقول السيطرة الأصلية by where بقدرش بقدر
+
+118
+00:10:10,170 --> 00:10:14,630
+أروح على وين على الشروط التالتة ونفضل أن نبدأ
+
+119
+00:10:14,630 --> 00:10:19,610
+بالشرط التالت طب لو جيت ابتدت بالشرط التالت يبقى
+
+120
+00:10:19,610 --> 00:10:25,510
+الشرط التالت بيقول لي ال limitللان لما ال N tends
+
+121
+00:10:25,510 --> 00:10:31,750
+to infinity لتلت
+
+122
+00:10:31,750 --> 00:10:35,390
+في أربعة على تلتة to the power N
+
+123
+00:10:38,770 --> 00:10:44,210
+جديش؟ هذا كثر اكبر من واحد الصحيح ربه كعبه اربعة
+
+124
+00:10:44,210 --> 00:10:48,350
+من الله سهل عليه رايح على وين؟ على infinity يبقى
+
+125
+00:10:48,350 --> 00:10:55,260
+هذا سوى جديش؟ سوى infinityأيوة يبقى هذا اختبار
+
+126
+00:10:55,260 --> 00:11:00,660
+مين؟ الحد النوني مظبوط اختبار الحد انه يعطاني مالة
+
+127
+00:11:00,660 --> 00:11:05,040
+نهاية تعني ال series هذه مالها diverse طبقا لل
+
+128
+00:11:05,040 --> 00:11:11,480
+instruments ممتاز جدا يبقى الشرط التالت عندي هذا
+
+129
+00:11:11,480 --> 00:11:17,240
+ماله لم يتحقق مدى ما اتحققش يبقى ال series مالها
+
+130
+00:11:17,240 --> 00:11:24,230
+diverse وكفى الله المؤمن القتال يبقى thismeans
+
+131
+00:11:24,230 --> 00:11:34,050
+that أنه the third condition
+
+132
+00:11:34,050 --> 00:11:48,450
+of the theorem is not satisfied that
+
+133
+00:11:48,450 --> 00:11:51,490
+is ان
+
+134
+00:11:54,110 --> 00:12:02,610
+That is limit لان لما ال N tends to infinity لا
+
+135
+00:12:02,610 --> 00:12:11,270
+يسوى Zero So the series الهي summation ل minus one
+
+136
+00:12:11,270 --> 00:12:16,470
+to the power N plus one لاربعة to the power N
+
+137
+00:12:16,470 --> 00:12:21,650
+تلاتة to the power N plus one مالها Diverge
+
+138
+00:12:38,660 --> 00:12:48,600
+المثال الثاني مشان
+
+139
+00:12:48,600 --> 00:12:53,240
+تبقى ال converge بدت تلاتة في آن واحد مشان تبقى
+
+140
+00:12:53,240 --> 00:12:55,840
+diverse بدور على الشرط التالف بدورش على اتنين
+
+141
+00:12:55,840 --> 00:13:00,080
+هذولاك لأن هذولاك لو اتحققوا وما اتحققوش بقدرش
+
+142
+00:13:00,080 --> 00:13:07,730
+احكم تمام بقدرش احكمطيب نجي للسؤال الثاني نمره
+
+143
+00:13:07,730 --> 00:13:15,930
+اتنين summation من n equal to infinity لسلب واحد
+
+144
+00:13:15,930 --> 00:13:25,110
+to the power n plus one لواحد على n فلن ال n يبقى
+
+145
+00:13:25,110 --> 00:13:29,570
+الخطوة الأولى باخد ال series of absolute values
+
+146
+00:13:29,570 --> 00:13:32,710
+solution the series
+
+147
+00:13:34,840 --> 00:13:46,340
+of absolute values is summation ل 1 على N لن ال N
+
+148
+00:13:46,340 --> 00:13:55,680
+تيجي
+
+149
+00:13:55,680 --> 00:14:01,320
+بالاختبار الأول هذه اختبار الحد النوني
+
+150
+00:14:10,270 --> 00:14:17,010
+الاختبار التاني هو التكامل
+
+151
+00:14:18,380 --> 00:14:21,860
+طيب تعالى نشوف التكامل integral test بحل المثلة و
+
+152
+00:14:21,860 --> 00:14:26,640
+لا بحلهاش طبعا هذا من عند N تساوي اتنين ل infinity
+
+153
+00:14:26,640 --> 00:14:33,740
+يبقى ال F of X يسوى واحد على X لن ال X هذي
+
+154
+00:14:33,740 --> 00:14:40,120
+positive من عند اتنين فما فوق ولا لا و كذلك
+
+155
+00:14:40,120 --> 00:14:41,880
+continuous
+
+156
+00:14:45,940 --> 00:14:51,400
+4 all x أكبر من أوي سوى 2 لأن ال discontinuity عند
+
+157
+00:14:51,400 --> 00:14:55,840
+ال zero و عند ال واحد يبقى احنا مالاش علاقة فيه هم
+
+158
+00:14:55,840 --> 00:14:59,220
+دول برا فترة الكاول يجب ان يكون عند اثنين فما فوق
+
+159
+00:14:59,220 --> 00:15:05,080
+متحققة طيب ده يلقى decreasing لو أخدت الحد انه يجب
+
+160
+00:15:05,080 --> 00:15:11,980
+ان يكون واحد على N من ال Nواخدت الحد انوني زائد
+
+161
+00:15:11,980 --> 00:15:18,460
+واحد واحد على ان زائد واحد لان الان زائد واحد طبعا
+
+162
+00:15:18,460 --> 00:15:23,160
+الأول اكبر من مين من التاني هذه يعني انها
+
+163
+00:15:23,160 --> 00:15:31,610
+decreasing كذلكلكل N أكبر من أو تساوي منهم اتنين
+
+164
+00:15:31,610 --> 00:15:37,830
+اذا تحققت الشروط التلاتة لمن؟ للتكامل اذا بقدر اخد
+
+165
+00:15:37,830 --> 00:15:46,970
+تكامل من اتنين ل infinity لواحد على X لان ال X كله
+
+166
+00:15:46,970 --> 00:15:52,160
+بالنسبة لمن؟ لDXهذا الـ Improper Integral يجب أن
+
+167
+00:15:52,160 --> 00:15:56,620
+أعمله بمعاملة الـ Improper Integral من النوع الأول
+
+168
+00:15:56,620 --> 00:16:01,560
+limit تكامل من 2 إلى P لما P tends to infinity
+
+169
+00:16:06,230 --> 00:16:13,170
+مش هدى مشتاقة لن ال X تمام تمام يبقى هدى D ل لن ال
+
+170
+00:16:13,170 --> 00:16:19,510
+X على مين؟ على لن ال X ويسوى ال limit لما B tends
+
+171
+00:16:19,510 --> 00:16:27,450
+to infinity اظن البس تفاضل المقام صح؟ يبقى لن
+
+172
+00:16:27,450 --> 00:16:35,080
+المقام لن ل لن ال Xيبقى النتيجة لن absolute value
+
+173
+00:16:35,080 --> 00:16:42,800
+لن ال X والكلام من اتنين لغاية ال B يبقى هذا يسوي
+
+174
+00:16:42,800 --> 00:16:49,100
+ال limit لما B tends to infinity لن absolute value
+
+175
+00:16:49,100 --> 00:16:57,960
+لن ال B نقص لن absolute value لن اتنين Y ساويلما
+
+176
+00:16:57,960 --> 00:17:03,760
+بيبدها تروح الى infinity لن ال infinity و كمان لن
+
+177
+00:17:03,760 --> 00:17:09,580
+ال infinity ب infinity ناقص رقم بيعطيني قداش يبقى
+
+178
+00:17:09,580 --> 00:17:18,500
+تكامل ماله ضعيفات يبقى باجي بقول سا تكامل من اتنين
+
+179
+00:17:18,500 --> 00:17:26,540
+ل infinity لواحد على X لن ال X بالنسبة ل X ماله
+
+180
+00:17:26,540 --> 00:17:32,100
+هذاby where يبقى بال integral test series of
+
+181
+00:17:32,100 --> 00:17:37,620
+absolute values مالها by where يبقى باجي بقوله هنا
+
+182
+00:17:37,620 --> 00:17:49,840
+هذا بدي يعطينا by the integral test the series of
+
+183
+00:17:49,840 --> 00:18:00,140
+absolute values by whereما دام diverge يبقى ال
+
+184
+00:18:00,140 --> 00:18:06,400
+series الأصلية ما لها؟ مش عارفين هل هي converge
+
+185
+00:18:06,400 --> 00:18:12,240
+ولا diverge؟ الله أعلم يبقى بنروح على مين؟ على
+
+186
+00:18:12,240 --> 00:18:17,860
+الشروط التلاتة إذا اتحققوا الشروط التلاتة بصير
+
+187
+00:18:17,860 --> 00:18:23,240
+converge conditionally اختل الشرط التالد بقول ال
+
+188
+00:18:23,240 --> 00:18:29,100
+series ما لها؟ diverse طيب شفويلو جيت على الشرط
+
+189
+00:18:29,100 --> 00:18:33,820
+التالت لذا اللي هذي واخدتله ال limit او هذا اخدتله
+
+190
+00:18:33,820 --> 00:18:37,360
+ال limit لما ال N بدا تروح للملنة يعني كدهش نتج
+
+191
+00:18:37,360 --> 00:18:42,220
+بيطلع يعني الشرط التالت محقق يعني بتروح ادور على
+
+192
+00:18:42,220 --> 00:18:48,140
+الشرطين الاتنين الأولاني الشرط الأولاني الشرط
+
+193
+00:18:48,140 --> 00:18:53,520
+الأولاني هلفي يوم من الأيام هذا بياخد قيمة سلبة من
+
+194
+00:18:53,520 --> 00:18:58,700
+اتنين فصاعدا اللي اللي اللي اللي اللي اللي اللي
+
+195
+00:18:58,700 --> 00:18:58,780
+اللي اللي اللي اللي اللي اللي اللي اللي اللي اللي
+
+196
+00:18:58,780 --> 00:18:59,600
+اللي اللي اللي اللي اللي اللي اللي اللي اللي اللي
+
+197
+00:18:59,600 --> 00:18:59,620
+اللي اللي اللي اللي اللي اللي اللي اللي اللي اللي
+
+198
+00:18:59,620 --> 00:19:00,680
+اللي اللي اللي اللي اللي اللي اللي اللي اللي اللي
+
+199
+00:19:00,680 --> 00:19:00,820
+اللي اللي اللي اللي اللي اللي اللي اللي اللي اللي
+
+200
+00:19:00,820 --> 00:19:00,820
+اللي اللي اللي اللي اللي اللي اللي اللي اللي اللي
+
+201
+00:19:00,820 --> 00:19:00,860
+اللي اللي اللي اللي اللي اللي اللي اللي اللي اللي
+
+202
+00:19:00,860 --> 00:19:01,340
+اللي اللي اللي اللي اللي اللي اللي اللي اللي اللي
+
+203
+00:19:01,340 --> 00:19:10,160
+اللي اللي اللي اللي اللي اللي اللي اللي اللي اللي
+
+204
+00:19:10,160 --> 00:19:17,380
+الليالشرط هذا محقق لكل الان اللي اكبر من او تساوي
+
+205
+00:19:17,380 --> 00:19:24,300
+اتنين الشرط الثاني الان اللي هو واحد على ان لان
+
+206
+00:19:24,300 --> 00:19:29,860
+الان اكبر من الان زائد واحد اللي هو واحد على ان
+
+207
+00:19:29,860 --> 00:19:36,280
+زائد واحد لان الان زائد واحد لكل الان اللي اكبر من
+
+208
+00:19:36,280 --> 00:19:40,700
+او يساوي اتنين هذا الشرط الثاني اللي هو مين
+
+209
+00:19:45,150 --> 00:19:47,610
+الشرط التالت
+
+210
+00:19:49,790 --> 00:19:57,870
+لما ال N تنزل لإنفينيتي لواحد
+
+211
+00:19:57,870 --> 00:20:04,390
+على N لإن ال N واحد على ماله نهاية Zero إذا تحققت
+
+212
+00:20:04,390 --> 00:20:10,030
+الشروط التلاتة مدام تحققت الشروط التلاتة بروح بقول
+
+213
+00:20:10,030 --> 00:20:16,650
+له the seriesSummation لناقص واحد to the power N
+
+214
+00:20:16,650 --> 00:20:23,130
+plus one واحد على N لأن ال N converge
+
+215
+00:20:23,130 --> 00:20:30,050
+conditionally يبقى
+
+216
+00:20:30,050 --> 00:20:35,990
+معنا هذا الكلام ان احنا فعلا قاعدين بالراجع كل ما
+
+217
+00:20:35,990 --> 00:20:42,400
+سبق الدراسة في ال sections الماضيةطب السؤال التالت
+
+218
+00:20:42,400 --> 00:20:49,500
+بيقول ال summation من n equal one to infinity لسلب
+
+219
+00:20:49,500 --> 00:21:00,920
+واحد to the power n لصين ال n على n تربية بدنا
+
+220
+00:21:00,920 --> 00:21:05,240
+ناخد بنفس الطريقة the series of absolute values
+
+221
+00:21:05,240 --> 00:21:08,580
+the
+
+222
+00:21:08,580 --> 00:21:22,580
+seriesof absolute values is summation من n equal
+
+223
+00:21:22,580 --> 00:21:29,780
+one to infinity لabsolute value للصين ال N عالميا
+
+224
+00:21:29,780 --> 00:21:31,700
+على N تربيع
+
+225
+00:21:35,100 --> 00:21:38,860
+طب ليش هالمرة هذه كتبتلها ال absolute و المرة اللي
+
+226
+00:21:38,860 --> 00:21:43,100
+فيها دي ما كتبتيه؟ اه لإن الصين هذا بتاخد قيم سلبة
+
+227
+00:21:43,100 --> 00:21:47,480
+و قيم موجة، ولكن لما أخد ال absolute يعني ضمنت
+
+228
+00:21:47,480 --> 00:21:52,360
+أنها كلها مالها بالموجة، بسيطةيبقى هذه ال series
+
+229
+00:21:52,360 --> 00:21:55,840
+with positive terms إذا ما بقدر أطبق عليها
+
+230
+00:21:55,840 --> 00:22:01,220
+الاختبارات التي سبقت دراستها، بنقولها بسيطة جدا،
+
+231
+00:22:01,220 --> 00:22:08,630
+هذا الحد النوني له sign ال end على interviewبدي
+
+232
+00:22:08,630 --> 00:22:12,170
+أشوف هذا الشيخ باره السيلزاي بقوله بسيطة هو ال
+
+233
+00:22:12,170 --> 00:22:16,970
+sign ال absolute معصور بين مين و مين ال 01 لإنه
+
+234
+00:22:16,970 --> 00:22:20,530
+absolute ماعنديش سالب كله بيصير موجة يبقى من الصفر
+
+235
+00:22:20,530 --> 00:22:22,910
+لواحد يبقى هذا مالوش داعو في ال conversion و ال
+
+236
+00:22:22,910 --> 00:22:25,710
+divergence يبقى اللي بدي اتحكم في ال conversion و
+
+237
+00:22:25,710 --> 00:22:30,410
+ال divergence واحد على ان تربية واحد على ان تربية
+
+238
+00:22:30,410 --> 00:22:34,960
+مالهاConverge في سيريز لأن فيه ساوة اتنين اقل من
+
+239
+00:22:34,960 --> 00:22:40,280
+واحد الصحيح يبقى مع الconverge بدنا نمشي اقل من
+
+240
+00:22:40,280 --> 00:22:42,700
+واحد على N تربية
+
+241
+00:22:47,090 --> 00:22:52,450
+اللي يساوي لإن الصين ممكن يتساوي واحد يبقى ده less
+
+242
+00:22:52,450 --> 00:22:57,970
+than or equal to واحد على انتر بيع طب اللي قال
+
+243
+00:22:57,970 --> 00:23:02,950
+واحد على انتر بيع convert بيه series يبقى باجي
+
+244
+00:23:02,950 --> 00:23:09,350
+بقوله but ولكن summation واحد على انتر بيع convert
+
+245
+00:23:09,350 --> 00:23:20,540
+بيه series السبب becauseإن P يساوي اتنين أكتر من
+
+246
+00:23:20,540 --> 00:23:26,500
+واحد يبقى بال comparison test بسيارة سيارة لأن هذه
+
+247
+00:23:26,500 --> 00:23:34,360
+مالها convert بجي بقوله by the comparison test the
+
+248
+00:23:34,360 --> 00:23:44,140
+series of absoluteValues اللي هي main اللي هي
+
+249
+00:23:44,140 --> 00:23:50,760
+summation absolute value لصين ال N على N ترابيع
+
+250
+00:23:50,760 --> 00:23:56,370
+convert مدام convert يبقى series الأصليةconvert
+
+251
+00:23:56,370 --> 00:24:02,770
+absolutely يبقى summation لنقص واحد to the power n
+
+252
+00:24:02,770 --> 00:24:12,210
+لصين ال n على n تربيع converge absolutely جاي في
+
+253
+00:24:12,210 --> 00:24:18,080
+بالي أسأل سؤال هيكو اشوف ايش رأيكوا فيه انت قاعد
+
+254
+00:24:18,080 --> 00:24:22,860
+بتاخد ان ال absolute value و بتروح شوف converge
+
+255
+00:24:22,860 --> 00:24:27,060
+بتقول انك converge absolutely ماهياش converge
+
+256
+00:24:27,060 --> 00:24:32,680
+بتروح على الشروط السؤال هو بنفع اروح الشروط دغري؟
+
+257
+00:24:50,160 --> 00:24:55,200
+السؤال الرابع يقول
+
+258
+00:24:58,380 --> 00:25:04,540
+مرة أربعة summation من عند ال N equal one to
+
+259
+00:25:04,540 --> 00:25:13,980
+infinity لنقص اتنين أس N plus one كله على N زائد
+
+260
+00:25:13,980 --> 00:25:16,320
+خمسة to the power N
+
+261
+00:25:19,250 --> 00:25:23,490
+بنشوف ال series هذه هل هي converge absolutely ولا
+
+262
+00:25:23,490 --> 00:25:27,870
+converge conditionally ولا ضعيفة بنقولها بسيطة
+
+263
+00:25:27,870 --> 00:25:34,670
+بنحاول نصيحها صياغة أخرى ل N تساوي واحد إلى N تدوي
+
+264
+00:25:34,670 --> 00:25:39,330
+هذا يا شباب اللي هو ناقص اتنين مش عبارة عن ناقص
+
+265
+00:25:39,330 --> 00:25:45,210
+واحد ضرب اتنينيعني هذه باعتبارها ناقص واحد to the
+
+266
+00:25:45,210 --> 00:25:51,270
+power اللي هو mean to the power n plus one في
+
+267
+00:25:51,270 --> 00:25:58,670
+الاتنين أس n plus one على n زائد خمسة to the power
+
+268
+00:25:58,670 --> 00:26:03,990
+nإذا انا اعطي المسألة بالشكل هذا يبقى واضح ان
+
+269
+00:26:03,990 --> 00:26:08,590
+الصورات هذه مالها alternating مادام ال alternating
+
+270
+00:26:08,590 --> 00:26:13,610
+يمكن ان انا اخد ال series of absolute values يبقى
+
+271
+00:26:13,610 --> 00:26:22,650
+باجي بقوله هنا solution of the series of absolute
+
+272
+00:26:22,650 --> 00:26:30,500
+valuesabsolute values is summation from n equal
+
+273
+00:26:30,500 --> 00:26:38,440
+one to infinity لإتنين في الإتنين أُس n على مين
+
+274
+00:26:38,440 --> 00:26:48,960
+على n زائد خمسة أُس n يبقى سارة series كل الحدود
+
+275
+00:26:48,960 --> 00:26:54,580
+موجبةمدام كل الحدود موجة باجي بشوف ماهو الاختبار
+
+276
+00:26:54,580 --> 00:26:59,480
+الأنسب للحكم على هذه ال series هل هي a conveyor و
+
+277
+00:26:59,480 --> 00:27:03,840
+الله طيب يعني مين أنسب اختبار بجيبها في خطوة هكذا
+
+278
+00:27:03,840 --> 00:27:10,880
+و الله تنتهي ال route ال route الجدرد هذا مجمع
+
+279
+00:27:10,880 --> 00:27:15,820
+زائد من حد ما شوف كمية تيماني و مابنقدرش يبقى لكوا
+
+280
+00:27:15,820 --> 00:27:21,540
+comparison دوري على كل الخط فباجي بقوله مينلإتنين
+
+281
+00:27:21,540 --> 00:27:28,260
+لإتنين to the power n على n زائد خمسة to the power
+
+282
+00:27:28,260 --> 00:27:35,310
+n يبقى اتنين هذا صغير إذا قُرن ب2 أس Mالـ N صغير
+
+283
+00:27:35,310 --> 00:27:39,370
+إذا قُرن بالخمسة و أس إن اللي بدي اتحكم في البصرة
+
+284
+00:27:39,370 --> 00:27:44,150
+اتنين أس M و بدي اتحكم في المقام خمسة to the power
+
+285
+00:27:44,150 --> 00:27:50,170
+M إذا لو أهملنا هم بيقولوا لك بضل كده؟ خمسين أس إن
+
+286
+00:27:50,170 --> 00:27:55,290
+يعني Geometrics الاساس تبعها خمسين أقل من واحد
+
+287
+00:27:55,290 --> 00:28:00,480
+يبقى converged يبقى خلاصة بدي أمشي إيه؟أقل من ..
+
+288
+00:28:00,480 --> 00:28:09,320
+طيب هذه أقل من اتنين في الاتنين أس N على خمسة أس N
+
+289
+00:28:09,320 --> 00:28:18,120
+صح كتبتنا هيك؟ غلط صح صح صح صح صح صح صح صح صح صح
+
+290
+00:28:18,120 --> 00:28:18,320
+صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح
+
+291
+00:28:18,320 --> 00:28:18,600
+صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح
+
+292
+00:28:18,600 --> 00:28:18,680
+صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح
+
+293
+00:28:18,680 --> 00:28:18,680
+صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح صح
+
+294
+00:28:18,680 --> 00:28:22,560
+صح صح صح صح صح صح صح صح صح صح صحمافيش امكانية بدا
+
+295
+00:28:22,560 --> 00:28:27,480
+شو ساوي ليش لان ال N فيش حاجة اقبلها هنا يبقى انما
+
+296
+00:28:27,480 --> 00:28:33,540
+صح مائة بالمائة هذه هي اتنين في خمسين to the power
+
+297
+00:28:33,540 --> 00:28:41,940
+N فبجي بقوله but ولكن اتنين او summation دُغري but
+
+298
+00:28:41,940 --> 00:28:48,130
+summation من N equal one to infinityللي اتنين في
+
+299
+00:28:48,130 --> 00:28:54,010
+اتنين على خمسة to the power n convert geometric
+
+300
+00:28:54,010 --> 00:29:01,750
+series السبب because ان ال absolute value لR يسوى
+
+301
+00:29:01,750 --> 00:29:07,350
+خمسين اقل من الواحد الصحيح مادام convert يقولي
+
+302
+00:29:07,350 --> 00:29:13,720
+اصغر منها convert يبقى باجي بقوله byeThe
+
+303
+00:29:13,720 --> 00:29:23,820
+comparison tests the series of absolute values
+
+304
+00:29:23,820 --> 00:29:33,780
+لصميم لمين لان اتنين أس ان plus one على ان زاد
+
+305
+00:29:33,780 --> 00:29:40,450
+خمسة to the power nConvert يبقى الأصلية Convert
+
+306
+00:29:40,450 --> 00:29:49,310
+absolutely يبقى the series للصميم من n equal one
+
+307
+00:29:49,310 --> 00:29:55,850
+to infinity لنقص اتنين to the power n plus one على
+
+308
+00:29:55,850 --> 00:30:03,730
+n زائد خمسة to the power n Convert absolutely
+
+309
+00:30:28,570 --> 00:30:30,410
+مثال رقم 5
+
+310
+00:30:41,310 --> 00:30:47,070
+مثال رقم خمسة بيقول ال summation من n equal one to
+
+311
+00:30:47,070 --> 00:30:53,490
+infinity ل minus one to the power n plus one لمين؟
+
+312
+00:30:53,490 --> 00:30:58,670
+لل n تكييب اتنين ال n تكييب زائد تلاتة
+
+313
+00:31:01,040 --> 00:31:05,760
+الجامعة اللى عملنا فيه كل الأمثلة السابقة بدنا
+
+314
+00:31:05,760 --> 00:31:16,340
+ناخد the series of absolute values is summation من
+
+315
+00:31:16,340 --> 00:31:23,960
+n equal one to infinity للإنت كيب على اتنين انت
+
+316
+00:31:23,960 --> 00:31:31,300
+كيب زائد تلاتةبنشوف هل هذه ال series converge و
+
+317
+00:31:31,300 --> 00:31:35,640
+الله diverse تمام؟ مين افضل اختبار لهذه الشغل
+
+318
+00:31:35,640 --> 00:31:41,360
+دوري؟ comparison بيجيبها بس في عندي احسن منه limit
+
+319
+00:31:41,360 --> 00:31:46,520
+اختبار الحد النوني و باختبار الحد النوني بنصيد
+
+320
+00:31:46,520 --> 00:31:53,480
+عصفرين بحجرين واحد تمام؟ تعالى شوف اختبار الحد
+
+321
+00:31:53,480 --> 00:31:59,930
+النوني يبقى بدي اخد limitللان لما ال N tends to
+
+322
+00:31:59,930 --> 00:32:05,290
+infinity يبقى limit لما ال N tends to infinity لل
+
+323
+00:32:05,290 --> 00:32:11,990
+N تكيب على 2 انت كيب زائد 3 limit لما ال N tends
+
+324
+00:32:11,990 --> 00:32:17,040
+to infinityأما تستخدم قاعدة لومتاليا تقسم كل من
+
+325
+00:32:17,040 --> 00:32:23,560
+البص والمقام على انت كي بيبصير واحد على اتنين
+
+326
+00:32:23,560 --> 00:32:28,980
+تلاتة على انت كي بيبص هذا يساوي زيرو إذا الناتج
+
+327
+00:32:28,980 --> 00:32:33,840
+يساوي من؟ يبقى بالإنثيرم تستخدم the series of
+
+328
+00:32:33,840 --> 00:32:39,140
+absolute values مالها by various يبقى بروح بقوله
+
+329
+00:32:39,140 --> 00:32:54,970
+by the infterm test the series of absolute values
+
+330
+00:32:54,970 --> 00:33:01,350
+by various طيب مادام by various بدنا نروح الشروط
+
+331
+00:33:01,350 --> 00:33:06,830
+التلاتة لكن السؤال هو هذا هو الشرط التالت؟ ممتاز
+
+332
+00:33:06,830 --> 00:33:14,240
+يبقى جاهز وخالص يبقى هنا but ولكن thatthird
+
+333
+00:33:14,240 --> 00:33:29,740
+condition of the theorem is not satisfied that
+
+334
+00:33:29,740 --> 00:33:38,360
+is يعني a n limit لل a nلما ال intensity of
+
+335
+00:33:38,360 --> 00:33:43,580
+infinity يساوي نص لا يساوي zero هذا معناه ايه يا
+
+336
+00:33:43,580 --> 00:33:49,880
+عزيزي ال series لل summation لنقص واحد to the
+
+337
+00:33:49,880 --> 00:33:55,800
+power n لل انت كيب اتنين انت كيب زائد تلاتة مالها
+
+338
+00:33:55,800 --> 00:34:01,240
+diverse تمام التمام السؤال السادس
+
+339
+00:34:03,830 --> 00:34:08,430
+المثال رقم ستة بيقول ال summation من n equal one
+
+340
+00:34:08,430 --> 00:34:15,350
+to infinity لسالب واحد to the power n اتنين to the
+
+341
+00:34:15,350 --> 00:34:27,890
+power n n factorial على n to the power n n
+
+342
+00:34:27,890 --> 00:34:32,240
+والله n زاد واحد مش مشكلةلأن ال alternating بدل ما
+
+343
+00:34:32,240 --> 00:34:36,840
+تبدأ بالموجة تبدأ بالسالب وعلى كده الأمرين فهي
+
+344
+00:34:36,840 --> 00:34:46,680
+alternating series ليس
+
+345
+00:34:46,680 --> 00:34:56,700
+بالضرورة حتى لو كانت ناقص واحد بتمشي معانا كمان اه
+
+346
+00:34:56,700 --> 00:35:01,170
+طب من دقيقة alternating كده كيف تصير؟سالب اتنين
+
+347
+00:35:01,170 --> 00:35:05,990
+بحط سالب واحد اص في اتنين اص كذا وانا ان شاء الله
+
+348
+00:35:05,990 --> 00:35:10,510
+اكون سالب مية مش مشكلة طب عندي مثلة بالشكل ان هذا
+
+349
+00:35:10,510 --> 00:35:17,230
+يبقى بدي اخد ال series of absolute values solution
+
+350
+00:35:17,230 --> 00:35:22,130
+باخد
+
+351
+00:35:22,130 --> 00:35:27,030
+the series of absolute
+
+352
+00:35:28,490 --> 00:35:36,130
+values is summation من n equal one to infinity
+
+353
+00:35:36,130 --> 00:35:43,730
+للإتنين أُس n n factorial into the power n مين
+
+354
+00:35:43,730 --> 00:35:49,470
+أفضل اختبار لهذه الشغله ال ratio of gain limit لما
+
+355
+00:35:49,470 --> 00:35:55,400
+ال n tends to infinityللحد النوني زائد واحد يبقى
+
+356
+00:35:55,400 --> 00:36:02,660
+اتنين أس N زائد واحد في N زائد واحد factorial على
+
+357
+00:36:02,660 --> 00:36:10,880
+N زائد واحد مرفوع للأس N زائد واحد تقسيم اتنين أس
+
+358
+00:36:10,880 --> 00:36:17,700
+N في ال N factorial على N to the power Nطيب هذا
+
+359
+00:36:17,700 --> 00:36:22,280
+الكلام بده يساوي limit لما ال int tends to
+
+360
+00:36:22,280 --> 00:36:28,420
+infinityبدا فاك هاد اتنين فى اتنين اث ان هاد ان
+
+361
+00:36:28,420 --> 00:36:34,480
+زائد واحد فى الان فاكتوريال مقسومة على ان زائد
+
+362
+00:36:34,480 --> 00:36:40,360
+واحد فالان زائد واحد to the power ان الجسم هحولها
+
+363
+00:36:40,360 --> 00:36:47,080
+الى ضرب بصير ان اث ان على الاتنين اث ان فى ان
+
+364
+00:36:47,080 --> 00:36:53,020
+فاكتوريال نبدأ نختصرن فاكتوريال مع ن فاكتوريال
+
+365
+00:36:53,020 --> 00:36:59,480
+اتنين قص ان مع اتنين قص ان ان زائد واحد مع ان زائد
+
+366
+00:36:59,480 --> 00:37:04,200
+واحد يبقى يا اتنين خليك برا ال limit و اي limit
+
+367
+00:37:04,200 --> 00:37:09,300
+لما الان بده تروح للان شو بيبقى اللي عندي ان قص ان
+
+368
+00:37:09,300 --> 00:37:16,520
+و ان زائد واحد قص ان يعني ان على ان زائد واحد كله
+
+369
+00:37:16,520 --> 00:37:23,650
+to the power n كم مرة سويناها هذهكتير يبقى الجواب
+
+370
+00:37:23,650 --> 00:37:31,070
+كده؟ واحد على ايه؟ يبقى الجواب اتنين على ايه؟ اكبر
+
+371
+00:37:31,070 --> 00:37:36,110
+من الواحد الصحيح ولا اقل؟ اقل من الواحد الصحيح
+
+372
+00:37:36,110 --> 00:37:40,870
+يبقى هذه اقل من الواحد الصحيح مدام اقل من الواحد
+
+373
+00:37:40,870 --> 00:37:51,010
+الصحيح بروح بقوله by the ratio test the seriesof
+
+374
+00:37:51,010 --> 00:37:59,030
+absolute values مالها converge يبقى ال series
+
+375
+00:37:59,030 --> 00:38:06,830
+الأصلية ال series لل summation لناقص واحد أس N
+
+376
+00:38:06,830 --> 00:38:13,970
+plus one لاتنين أس N في ال N factorial على N to
+
+377
+00:38:13,970 --> 00:38:16,250
+the power N converge
+
+378
+00:38:18,560 --> 00:38:23,700
+سؤال السابع السؤال
+
+379
+00:38:23,700 --> 00:38:29,680
+السابع بيقول ليه؟ summation من N equal one to
+
+380
+00:38:29,680 --> 00:38:36,900
+infinity لسلب واحد to the power N لتان inverse N
+
+381
+00:38:36,900 --> 00:38:40,260
+على N جدر ال N زائد واحد
+
+382
+00:38:43,450 --> 00:38:47,650
+برضه بنشوف ال series هذي converge و لا diverge
+
+383
+00:38:47,650 --> 00:38:55,950
+بروح باخد من ال series of absolute values فبجي
+
+384
+00:38:55,950 --> 00:39:06,750
+بقوله the series of absolute values is summation
+
+385
+00:39:06,750 --> 00:39:21,470
+لمينلتان inverse N على N جذر ال N زائد واحد نبحث
+
+386
+00:39:21,470 --> 00:39:27,670
+ال series تبعتنا هل هي converge او diverge فبنروح
+
+387
+00:39:27,670 --> 00:39:33,950
+ندور على اختبار مناسب لهذه الشغل يالا اقترف علينا
+
+388
+00:39:33,950 --> 00:39:42,530
+ناخد اختبار الحد النونياختبار حد اول واحد طبعا
+
+389
+00:39:42,530 --> 00:39:48,070
+بايع اتنين على ماله نهاية صفر فاشيل الاختبار صفه ع
+
+390
+00:39:48,070 --> 00:39:55,050
+شجة حد فيكم يقدر يكتمل هذه وانا زيكم برضه تمام؟
+
+391
+00:39:55,050 --> 00:39:59,730
+يبقى صف جانبه نيجي لل comparison إذا ضبطت كنا بها
+
+392
+00:39:59,730 --> 00:40:04,370
+وما ضبطش بروح أدور غيره تمام؟يبقى خلّينا نجرب ال
+
+393
+00:40:04,370 --> 00:40:10,530
+comparison يمكن والله أعلم يبقى هذا tan inverse N
+
+394
+00:40:10,530 --> 00:40:17,430
+على N general N زائد واحد بدأ أمشي أقل منه ولا
+
+395
+00:40:17,430 --> 00:40:22,030
+أكبر منه الله أعلم بعرفش لكن حالة طلعله في ال bus
+
+396
+00:40:22,030 --> 00:40:27,990
+قداشر أقصى ما ممكن يصله لل bus باية اتنين صحيح ولا
+
+397
+00:40:27,990 --> 00:40:32,080
+لأ tan inverse infinity باية اتنينيبقى بقى اثنين
+
+398
+00:40:32,080 --> 00:40:36,520
+الرقم لا هيقدم ولا هيأخر عندي يبقى اتحكم ال
+
+399
+00:40:36,520 --> 00:40:41,040
+conversion المقام طيب الواحد ولا الان جدر الان؟
+
+400
+00:40:41,040 --> 00:40:45,080
+مين اللي أكبر؟ هو اللي أكبر يبقى الواحد صوف جنب
+
+401
+00:40:45,080 --> 00:40:49,520
+واروح على شجة يبقى صار عندي رقم على ان أس جدر ال
+
+402
+00:40:49,520 --> 00:40:55,780
+conversion يعني يبقى بدي أمشي أقل منه مظبوطيبجه
+
+403
+00:40:55,780 --> 00:41:03,640
+هذه دائما و أبدا أقل من باي على اتنين على ان جذر
+
+404
+00:41:03,640 --> 00:41:05,720
+الان زائد واحد
+
+405
+00:41:12,610 --> 00:41:17,690
+ممكن يحصل تساوي، يعني بيحصل تساوي، عمرك بتوصل ما
+
+406
+00:41:17,690 --> 00:41:24,590
+لنهاية حتى تحط التساوي، مش ممكنية، مش ممكنية، يبقى
+
+407
+00:41:24,590 --> 00:41:27,990
+بنجرش يحط تساوي، لو حطيت مخصوم لك عليها دي لبالك
+
+408
+00:41:29,040 --> 00:41:33,160
+معناته انت مش فاهم تاني انفرسالي يبقى يدير بالك
+
+409
+00:41:33,160 --> 00:41:38,940
+دقيق و كتابة رياضية دقيقة طب
+
+410
+00:41:38,940 --> 00:41:43,660
+ما احنا مش هنحط يساوي بس من عندنا
+
+411
+00:41:43,660 --> 00:41:48,120
+ممكن ادجلك عليه هك او احطها لك و اتغاب عنها انت و
+
+412
+00:41:48,120 --> 00:41:53,510
+اختك حسب نفس الوضعطيب، على أي حال، خلّي بالكم معنا
+
+413
+00:41:53,510 --> 00:41:59,030
+هنا، الآن مشيت أقل من بقال ماشي أقل من، بقول له
+
+414
+00:41:59,030 --> 00:42:06,430
+هذه أقل من by على اتنين على n في جدر ال N، وبسأل
+
+415
+00:42:06,430 --> 00:42:12,240
+السؤال التالي، كتاب هذا صح ولا خطأ؟طبعا 100% لأن
+
+416
+00:42:12,240 --> 00:42:18,300
+المقام الأول أكبر وبالتالي الكثير أقل طيب هذه هي
+
+417
+00:42:18,300 --> 00:42:24,040
+عبارة عن باي على اتنين على N أس تلاتة على اتنين
+
+418
+00:42:24,040 --> 00:42:31,440
+بقوله ماشي بقى ولكن باي على اتنين summation لواحد
+
+419
+00:42:31,440 --> 00:42:35,880
+على N أس تلاتة على اتنين من N equal one to
+
+420
+00:42:35,880 --> 00:42:36,500
+infinity
+
+421
+00:42:40,510 --> 00:42:48,270
+السبب ان P يسوى تلاتة على اتنين اكبر من الواحد
+
+422
+00:42:48,270 --> 00:42:54,830
+الصحيح يبدأ الاقل منها by the comparison test
+
+423
+00:43:10,350 --> 00:43:18,370
+بنان على الأصليةconverge absolutely so the series
+
+424
+00:43:18,370 --> 00:43:24,890
+الاصلي اللي هي summation لمين لسلب واحد to the
+
+425
+00:43:24,890 --> 00:43:32,570
+power n لتان inverse n على n جدر ال n زائد واحد
+
+426
+00:43:32,570 --> 00:43:40,990
+converge absolutely فهنا ضايق الفلتان أمثلة
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/Dcb02BSs1w4.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/Dcb02BSs1w4.srt
new file mode 100644
index 0000000000000000000000000000000000000000..16321c91a693ecb6621f336170e6ca4ed99e131d
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/Dcb02BSs1w4.srt
@@ -0,0 +1,1855 @@
+1
+00:00:09,880 --> 00:00:14,580
+بسم الله الرحمن الرحيم نكمل ما بدأنا به في المرة
+
+2
+00:00:14,580 --> 00:00:19,920
+الماضية المرة الماضية أخذنا أول اختبار الذي اسمه 
+
+3
+00:00:19,920 --> 00:00:24,600
+limit الذي اسمه direct comparison test الذي اختبار
+
+4
+00:00:24,600 --> 00:00:30,520
+المقارنة و أخذنا عليه أول مثال و الآن نروح للمثال 
+
+5
+00:00:30,520 --> 00:00:36,300
+رقم اثنين بنشوف هذا تكامل converge  ولا diverge
+
+6
+00:00:36,300 --> 00:00:42,740
+فبروح بأخذ الدالة نفسها التي هو E أس ناقص X تمين
+
+7
+00:00:42,740 --> 00:00:48,580
+في cosine تربيع ال X يعني التي هي cosine تربيع ال
+
+8
+00:00:48,580 --> 00:00:56,080
+X على E أس X السؤال هو من أقرب دالة على هذه
+
+9
+00:00:56,080 --> 00:00:58,680
+الدالة؟ نخلقها منها
+
+10
+00:01:01,790 --> 00:01:07,210
+التي هو من؟ واحد على E O6، هذه أقرب واحد عليها،
+
+11
+00:01:07,210 --> 00:01:12,270
+الدالة التي بدك تجيبها، بدك كنت تعرفها مسبقا هل هي
+
+12
+00:01:12,270 --> 00:01:17,510
+converge أو diverge، يبقى أقرب دالة عليها، التي هي
+
+13
+00:01:17,510 --> 00:01:23,910
+عبارة عن من؟ واحد على E O6 طب السؤال هو، من التي
+
+14
+00:01:23,910 --> 00:01:26,110
+أصغر، الأولى ولا الثانية؟
+
+15
+00:01:37,140 --> 00:01:44,820
+يبقى من Zero لواحد، يبقى أقل من الدالة الثانية ولا
+
+16
+00:01:44,820 --> 00:01:50,880
+أكبر منها دائماً أقل من وقت تساويها لما ربنا يحط
+
+17
+00:01:50,880 --> 00:01:55,820
+فيها البركة بتساويها تمام؟ إذا هذه ال function أقل
+
+18
+00:01:55,820 --> 00:02:03,080
+من وقت تساوي هذه الدالة لأخر المرة التي فاتت بقى
+
+19
+00:02:03,080 --> 00:02:09,720
+ولكن تكامل من واحد إلى infinity لواحد على E O6DH
+
+20
+00:02:09,720 --> 00:02:18,640
+converge الذي هو ال previous المثال السابق بالضبط
+
+21
+00:02:18,640 --> 00:02:23,960
+تماماً يبقى هذي converged بإشارة comparison test
+
+22
+00:02:23,960 --> 00:02:30,160
+التي أصغر منها converged يبقى بروح بقوله by the
+
+23
+00:02:30,160 --> 00:02:35,460
+direct comparison test التكامل من واحد إلى infinity
+
+24
+00:02:35,460 --> 00:02:42,260
+لـ E Oس نقص X cos تربيع X DX converged وانتهينا من
+
+25
+00:02:42,260 --> 00:02:47,770
+المثال هذا يبقى هذه النمرة الوساية بلزم ليش تكامل،
+
+26
+00:02:47,770 --> 00:02:54,770
+بلزم نقارنه بس، نمرة ثلاثة نمرة ثلاثة بدنا تكامل
+
+27
+00:02:54,770 --> 00:03:02,170
+من واحد إلى infinity لل X DX على الجذر التربيعي
+
+28
+00:03:02,170 --> 00:03:10,610
+لأربعة X أُس خمسة زائد واحد بنجي على الدالة التي
+
+29
+00:03:10,610 --> 00:03:15,750
+عندنا هذه التي هي من X على الجذر التربيعي لأربعة
+
+30
+00:03:15,750 --> 00:03:23,310
+X أس خمسة زائد واحد شوفوا يا شباب كيف بدنا نجيب
+
+31
+00:03:23,310 --> 00:03:28,730
+الدالة التي بدنا نقارن معاها بدي بقول ال boss جاهز
+
+32
+00:03:28,730 --> 00:03:33,270
+X لا بد أزيد عليه ولا ننقص بدأي على دالة المقام
+
+33
+00:03:33,270 --> 00:03:38,670
+الواحد مقدار ثابت إذا قورن بالإكسوس خمسة يبقى إكسوس
+
+34
+00:03:38,670 --> 00:03:42,370
+خمسة هي الكبيرة لأن الإكسوس بتروح لوين؟ للملة
+
+35
+00:03:42,370 --> 00:03:45,190
+النهائية، أنت جراش لغاية الملة النهائية، هو الأربعة
+
+36
+00:03:45,190 --> 00:03:50,210
+مقدار ثابت سيبك منه يبقى المقام كله كأنه الجدر
+
+37
+00:03:50,210 --> 00:03:55,010
+التربيعي للإكسوس خمسة يعني إكسوس جداش خمسة على
+
+38
+00:03:55,010 --> 00:04:00,030
+اثنين اثنين و نصف، وعندي فوق إكسوس واحد لما نختصرهم
+
+39
+00:04:00,030 --> 00:04:05,040
+يظل واحد على إكسوس جداش أو 3 على 2 التكامل عليها
+
+40
+00:04:05,040 --> 00:04:10,480
+convergence ولا divergence؟ نعم لأن هناك نظرية
+
+41
+00:04:10,480 --> 00:04:14,900
+مكتوبة معنا المرة الماضية 1 على X to the power P
+
+42
+00:04:14,900 --> 00:04:19,160
+DX convergence إذا P أكبر من 1 و divergence إذا P
+
+43
+00:04:19,160 --> 00:04:22,680
+أقل من أو تساوي الواحد يبقى التكامل عليها
+
+44
+00:04:22,680 --> 00:04:24,900
+convergence قلنا لك المرة الماضية مع ال
+
+45
+00:04:24,900 --> 00:04:28,080
+convergence بالدمشي أصغر منه مع ال divergence
+
+46
+00:04:28,080 --> 00:04:33,120
+بالدمشي أكبر منه يبقى barrier functional لأنها مدام
+
+47
+00:04:33,120 --> 00:04:38,360
+convert إذا بدي أمشي أقل من X على الجذر التربيعي
+
+48
+00:04:38,360 --> 00:04:43,380
+إلى أربعة X أُس خامسة يعني شيلت من؟ شيلت الواحد
+
+49
+00:04:43,380 --> 00:04:47,820
+سؤال هو هل الكلام التي يعني كاتبه كان quality صحيح
+
+50
+00:04:47,820 --> 00:04:54,520
+ولا خطأ؟ التي قال خطأ يوجه فارباسي يقولي وين هو؟
+
+51
+00:04:54,520 --> 00:04:58,600
+خليني أتنبأ أنت التي قالت خطأ؟ طب ليش خطأ قد يفرق؟
+
+52
+00:05:00,440 --> 00:05:06,060
+فبلا ما أكبر المقام بزيد الكثر ولا بقل؟ بقل ولا
+
+53
+00:05:06,060 --> 00:05:09,540
+بزيد؟ بقل، بقل، بقل، بقل، بقل، بقل
+
+54
+00:05:13,420 --> 00:05:19,200
+كل ما يكبر المقام، بيقل الكثر. النصف ولا الثمن؟
+
+55
+00:05:19,200 --> 00:05:23,300
+النصف أكبر أو كبير، يبقى الثمن أجنب من النصف، رغم
+
+56
+00:05:23,300 --> 00:05:28,360
+يقامه كبير. إذا كل ما يكبر المقام، بيقل من؟ بيقل
+
+57
+00:05:28,360 --> 00:05:31,900
+الكثر. يبقى الكلام التي قاله هو مش صحيح، وكلامنا
+
+58
+00:05:31,900 --> 00:05:37,480
+هو الصحيح. تمام؟ إذا هذا المقدار كله أقل من
+
+59
+00:05:37,480 --> 00:05:43,880
+المقدار هذا كله. يبقى هذا عبارة عن X على 2 X أس
+
+60
+00:05:43,880 --> 00:05:49,160
+خمسة على اثنين يعني واحد على اثنين X أس ثلاثة على
+
+61
+00:05:49,160 --> 00:05:56,080
+اثنين بروح بقوله بطل ولكن الذي هو نصف تكامل من واحد
+
+62
+00:05:56,080 --> 00:06:01,100
+إلى infinity لوحد على X أس ثلاثة على اثنين DX
+
+63
+00:06:01,100 --> 00:06:09,590
+converge السبب بسبب أن P تساوي 3 على 2 أكبر من
+
+64
+00:06:09,590 --> 00:06:16,990
+الواحد الصحيح By the direct comparison test تكامل
+
+65
+00:06:16,990 --> 00:06:24,230
+من 1 إلى infinity لل X DX على الجذر التربيعي ل 4X
+
+66
+00:06:24,230 --> 00:06:32,490
+أُس 5 زائد 1 convergence هنا من المسألة
+
+67
+00:06:34,280 --> 00:06:39,900
+طيب نروح لسؤال التي بعده الذي هو السؤال الرابع
+
+68
+00:06:39,900 --> 00:06:45,800
+السؤال الرابع بيقول يتكامل من واحد إلى infinity
+
+69
+00:06:45,800 --> 00:06:54,180
+للإثنين زائد cosine x على x كله في ال dx بدي أشوف
+
+70
+00:06:54,180 --> 00:07:00,080
+إن هذا تكامل converge ولا diverge بدي بسأل نفسي
+
+71
+00:07:00,080 --> 00:07:05,840
+أكبر قيمة بياخدها ال X كده؟ كوصين ال X واحد و عندك
+
+72
+00:07:05,840 --> 00:07:11,540
+اثنين يعني أكبر قيمة بياخدها البسط هو ثلاثة نيجي
+
+73
+00:07:11,540 --> 00:07:16,980
+أصغر قيمة بياخدها البسط كده؟ واحد لأن كوصين سالب
+
+74
+00:07:16,980 --> 00:07:21,620
+واحد و اثنين بيصير واحد إذا البسط محصور بين واحد لا
+
+75
+00:07:21,620 --> 00:07:25,480
+ينجز عن الواحد ولا يزيد عن الثالث. عندما يحط ربك
+
+76
+00:07:25,480 --> 00:07:30,040
+في البركة تصبح ثلاثة وعندما ينخسف تصبح واحد صحيح.
+
+77
+00:07:30,200 --> 00:07:35,040
+إذا البسط هذا دائماً هو أبداً قنسة، رقم. طب تعال خد
+
+78
+00:07:35,040 --> 00:07:41,080
+المقام هذا. يبقى هذا المقام بظل بروح الله سلاله
+
+79
+00:07:41,080 --> 00:07:46,700
+مالة نهاية. أنا أصلاً عندي رقم على X. قول مثلاً واحد
+
+80
+00:07:46,700 --> 00:07:52,270
+على X. واحد على X، converge ولا diverge؟ واحد على
+
+81
+00:07:52,270 --> 00:07:57,950
+إكس diverge لأن P واحدة صحيحة هي يبقى diverge مدام
+
+82
+00:07:57,950 --> 00:08:04,170
+diverge يبقى بيمشي أكبر من ولا أقل من .. مع
+
+83
+00:08:04,170 --> 00:08:08,350
+الدايفير يبقى بيمشي أقل ولا أكبر؟ أكبر هيك التي
+
+84
+00:08:08,350 --> 00:08:14,190
+هالاختبار بيقول يبقى باري بيقول الاثنين زائد كوصين
+
+85
+00:08:14,190 --> 00:08:21,910
+ال X على X أكبر مش عارف منين أكبر من من؟ أحط واحد
+
+86
+00:08:21,910 --> 00:08:29,010
+ولا ثلاثة؟ واحد، إذا ثلاثة، ما تعداش الثلاثة أصلاً،
+
+87
+00:08:29,010 --> 00:08:35,790
+يبقى أكبر من واحد وقد يساويه، تمام؟ الآن هذه
+
+88
+00:08:35,790 --> 00:08:38,830
+التكامل عليها Divergent يبقى ليه أكبر Divergent
+
+89
+00:08:38,830 --> 00:08:45,230
+وخلاص، يبقى باجي بقوله بطل، ولكن تكامل من واحد إلى
+
+90
+00:08:45,230 --> 00:08:55,350
+الانفينيتي لواحد على x dx because أن P تساوي واحد
+
+91
+00:08:55,350 --> 00:08:56,130
+صحيح
+
+92
+00:09:05,930 --> 00:09:11,230
+تكامل من واحد إلى انفنتا دي لان اثنين زائد cosine
+
+93
+00:09:11,230 --> 00:09:20,030
+X على X DX Diverge وانتهينا من هنا شافوي سوف يعطيك
+
+94
+00:09:20,030 --> 00:09:24,870
+نفس السؤال بس سوف أغير الأس تبع ال X ال X هنا الأس
+
+95
+00:09:24,870 --> 00:09:30,600
+تبعها كده؟ سوف أعطيك واحد و نصف نشوف هل التكامل هذا
+
+96
+00:09:30,600 --> 00:09:35,640
+converge ولا diverge converge مظبوط يعني بدي نمشي
+
+97
+00:09:35,640 --> 00:09:40,760
+أقل من ولا أكبر من أقل من يبقى بروح بقوله اثنين
+
+98
+00:09:40,760 --> 00:09:46,020
+زائد cosine ال X على X ثلاثة على اثنين أقل من وقد
+
+99
+00:09:46,020 --> 00:09:51,560
+يساوي جداش ثلاثة على X ثلاثة على اثنين ثلاثة مقدار
+
+100
+00:09:51,560 --> 00:09:55,120
+ثابت صفل برا بضل التكامل واحد على X ثلاثة على
+
+101
+00:09:55,120 --> 00:09:56,540
+اثنين converge يبقى
+
+102
+00:10:13,540 --> 00:10:21,360
+السؤال الخامس بيقول يتكامل من اثنين لغاية infinity
+
+103
+00:10:21,360 --> 00:10:28,700
+لمن؟ لل X على الجذر التربيعي ل X أس أربعة ناقص
+
+104
+00:10:28,700 --> 00:10:34,650
+واحد في DX بقى دي بقول له هاي ال function التي
+
+105
+00:10:34,650 --> 00:10:38,690
+عندنا x على الجذر التربيعي ل X أقصى أربعة ناقص
+
+106
+00:10:38,690 --> 00:10:44,630
+واحد أنا مش عارف بدي أمشي أقل من ولا أكبر من بقول
+
+107
+00:10:44,630 --> 00:10:49,430
+كويس الباص جاهز المقام شيل الواحد بضل الجذر
+
+108
+00:10:49,430 --> 00:10:54,470
+التربيعي على X أُس أربعة الذي هو جداش صار عند X على
+
+109
+00:10:54,470 --> 00:10:59,730
+X التربيعي يعني جداش واحد على X يعني التكامل عليها
+
+110
+00:10:59,730 --> 00:11:04,630
+diverge من واحد إلى infinity يبقى قدام شيهش أكبر
+
+111
+00:11:04,630 --> 00:11:10,530
+منه يبقى هذه أكبر من X على الجذر التربيعي ل X أُس
+
+112
+00:11:10,530 --> 00:11:14,490
+أربعة ايه رأيك بره موافق عليها أيها دي والله كله
+
+113
+00:11:14,490 --> 00:11:21,810
+كلام شيلت بالسالب واحد صح هذه يا شباب؟ خلّوا فيها
+
+114
+00:11:21,810 --> 00:11:30,470
+كويس، هذه أكبر من هذه صحيح؟ مظبوط؟ ولا مش مظبوط؟
+
+115
+00:11:30,470 --> 00:11:35,890
+يبقى البسط أكبرها، يبقى هذه البنية أكبر؟ مية
+
+116
+00:11:35,890 --> 00:11:41,590
+لمية، كل ما يصغر المقام بيكبر الكسب، لكن كبر
+
+117
+00:11:41,590 --> 00:11:47,870
+المقام .. أيوة يعني يا شباب لو كانت هذه زائد بدل
+
+118
+00:11:47,870 --> 00:11:52,630
+النقص كانت، تبقى هذه هيك صحيح؟ لا مش صحيح، بتصير
+
+119
+00:11:52,630 --> 00:11:57,550
+أقل من يبقى المعنى الناقص اكتبتنا هذه السليمة مائة
+
+120
+00:11:57,550 --> 00:12:03,230
+بالمائة يبقى النتيجة x على x تربيع يعني واحد على x
+
+121
+00:12:03,230 --> 00:12:09,870
+بقوله بطل ولكن تكامل من اثنين لإنفنتي إلى واحد على
+
+122
+00:12:09,870 --> 00:12:19,720
+x dx diverged because السبب أن P تساوي واحد صحيح
+
+123
+00:12:19,720 --> 00:12:26,020
+هذا بده يعطيك by the direct comparison test
+
+124
+00:12:26,020 --> 00:12:31,500
+التكامل من اثنين ل infinity لل X على الجذر
+
+125
+00:12:31,500 --> 00:12:38,220
+التربيعي ل X أربعة ناقص واحد DX by VAR طيب السؤال
+
+126
+00:12:38,220 --> 00:12:40,860
+اللي بعد سؤال ستة
+
+127
+00:12:43,290 --> 00:12:50,310
+سؤال ستة بيقول يتكامل من تلاتة لـ Infinity للجذر 
+
+128
+00:12:50,310 --> 00:12:56,710
+التربيعي لـ 2X تربيع زائد سبعة كله على مين؟ على
+
+129
+00:12:56,710 --> 00:13:02,270
+X تكعيب DX يبقى 
+
+130
+00:13:02,270 --> 00:13:08,750
+هاي الدالة اللي هو 2X تربيع زائد سبعة كله
+
+131
+00:13:08,750 --> 00:13:14,930
+مقسوما على X تكعيب عليه البركة، ما عيب إن أشوف
+
+132
+00:13:14,930 --> 00:13:19,480
+هالدالة، هالكسر اللي فيها، أبناء ما نقول شيل 2
+
+133
+00:13:19,480 --> 00:13:23,080
+وشيل السبعة بيبقى الجذر X تربيع، اللي هو الجذر دي
+
+134
+00:13:23,080 --> 00:13:28,680
+إيش؟ X وعندك هنا X تكعيب، فالواحد على X تربيع، كون
+
+135
+00:13:28,680 --> 00:13:34,620
+غيري ولا ضايفان، إذا بدنا نمشي أقل من، يبقى هذه
+
+136
+00:13:34,620 --> 00:13:41,580
+أقل من X تكعيب وهذا الجذر التربيعي لـ 2
+
+137
+00:13:41,580 --> 00:13:48,120
+X تربيع، صحيك ولا غلط؟ X تربيع بقى مش مشكلة 2
+
+138
+00:13:48,120 --> 00:13:50,200
+أكثر بيها، والله أكثر بيها، بتفرقش عند 2،
+
+139
+00:13:50,200 --> 00:13:54,860
+ما تأثرش، بس الكتاب دي هيك صح ولا غلط؟ غلط. غلط؟ لأ
+
+140
+00:13:54,860 --> 00:13:58,240
+صحيح الصراحة. الناس يقولوا غيرهم. صحيح صحيح. أنا
+
+141
+00:13:58,240 --> 00:14:00,580
+بقوله غلط وكده في حد و بس، مش هنناقش احنا و
+
+142
+00:14:00,580 --> 00:14:05,300
+أنا بدي واحد بس، إيه؟ بس نجمع دي، بس نجمع نناقش
+
+143
+00:14:05,960 --> 00:14:10,560
+البوصة الأولى يعني أكبر من الـ 2 المقام 8.
+
+144
+00:14:10,560 --> 00:14:16,540
+إذا هذا المقدار أكبر من هذا المقدار وليس أقل، يعني
+
+145
+00:14:16,540 --> 00:14:22,200
+كتابتنا هذه ما لها خلق. طيب، بالذات هقوله زائد
+
+146
+00:14:22,200 --> 00:14:26,300
+8، تشير كلامي صح ولا لا؟ صح مية المية، طب
+
+147
+00:14:26,300 --> 00:14:33,000
+زائد 9؟ زائد 100، صح، مظبوط، لكن هل حلت
+
+148
+00:14:33,000 --> 00:14:36,320
+الإشكالية السابعة ولا الثامنة ولا المية ولا المليون ولا
+
+149
+00:14:36,320 --> 00:14:40,590
+500؟ ما حلت الإشكالية بالمرة، لكن أنا بدي أحلي
+
+150
+00:14:40,590 --> 00:14:45,370
+الإشكالية بمعنى بدي أتخلص من الجذر مشان اختصر مع
+
+151
+00:14:45,370 --> 00:14:49,890
+المقام يبقى من حد ما اتجابلِك مسألة بهذا الشكل
+
+152
+00:14:49,890 --> 00:14:56,450
+بسيطة الرقم اللي عندك هذا اكتبه بدلالة المتغير
+
+153
+00:14:56,450 --> 00:15:00,330
+اللي عندك هذا وبالتالي بيصير ما فيش إشكالية خالص
+
+154
+00:15:00,330 --> 00:15:09,950
+يعني بقدر أقول زائد 7X تربيع صح ولا غلط؟ صحيح
+
+155
+00:15:09,950 --> 00:15:14,630
+100% وما حدش يعترض كمان، هذا أقل من هذا صحيح،
+
+156
+00:15:14,630 --> 00:15:19,250
+لأن هذا المقدار هو هذا، والـ 7 أقل من 7X ترجع
+
+157
+00:15:19,250 --> 00:15:24,130
+إلى X من 1، من 3 لـ مال نهاية، كلها من 3
+
+158
+00:15:24,130 --> 00:15:29,320
+لمال نهاية، إذا لن يحدث تساوي، لكن لو كان من 1
+
+159
+00:15:29,320 --> 00:15:34,320
+لما لا نهاية، بيحدث التساوي عند X يساوي 1، أنت
+
+160
+00:15:34,320 --> 00:15:38,920
+لا تنفيش تساوي بالمرة، يفاجئ إن حدث الشغل زي اللي
+
+161
+00:15:38,920 --> 00:15:42,480
+توا، بروح، بكتب الرقم اللي عندنا هذا بدلالة
+
+162
+00:15:42,480 --> 00:15:46,620
+المتغير، يبقى صار 7X تربيع هو الكلام صحيح مائة
+
+163
+00:15:46,620 --> 00:15:51,360
+بالمائة طيب 2X تربيع و 7X تربيع، 9X
+
+164
+00:15:51,360 --> 00:15:57,370
+تربيع يعني بتطلع 3X، 3X على X تكعيب
+
+165
+00:15:57,370 --> 00:16:00,350
+يعني 3 على X تربيع
+
+166
+00:16:06,210 --> 00:16:11,270
+تكامل من 3 لـ إنفينيتي لـ 1 على X تربيع DX
+
+167
+00:16:11,270 --> 00:16:19,330
+Converge السبب because إن T تساوي 2 أكبر من
+
+168
+00:16:19,330 --> 00:16:24,270
+واحدة الصحيحة هذا بدي أعطيك by the direct
+
+169
+00:16:24,270 --> 00:16:30,610
+comparison test التكامل اللي عندك من 3 لغاية
+
+170
+00:16:30,610 --> 00:16:34,950
+infinity إلى الجذر التربيعي لـ 2X تربيع
+
+171
+00:16:34,950 --> 00:16:42,230
+زائد 7 على X تكعيب DX converge وانتهينا من
+
+172
+00:16:42,230 --> 00:16:42,830
+المثال
+
+173
+00:16:58,320 --> 00:17:04,200
+طيب هذا كان السؤال السادس، خذ السؤال السابع، السؤال
+
+174
+00:17:04,200 --> 00:17:13,380
+السابع بيقول التكامل من zero لغاية π من zero لغاية
+
+175
+00:17:13,380 --> 00:17:21,760
+π لـ dx على جذر الـ X زائد sin X
+
+176
+00:17:26,420 --> 00:17:33,380
+هذا يبقى مدينة دالة لأنها 1 على جذر الـ X زائد
+
+177
+00:17:33,380 --> 00:17:37,920
+sin X، اقرأ الدالة عليها اللي احنا عارفينها 1
+
+178
+00:17:37,920 --> 00:17:42,800
+على sin ولا 1 على X أص نص، 1 على X أص نص ولا
+
+179
+00:17:42,800 --> 00:17:49,360
+1 على sin، 1 على X أص نص، يبقى هذه 1 على X
+
+180
+00:17:49,360 --> 00:17:54,540
+أص نص، طيب هذه أصغر ولا أكبر من الثانية؟ بيصيرش في
+
+181
+00:17:54,540 --> 00:17:59,360
+يوم من الأيام أصغر؟ بيصير بس احنا مقيدين من وين
+
+182
+00:17:59,360 --> 00:18:02,840
+لوين؟ من الصفر اللي بايعنا الرابع الأول والرابع
+
+183
+00:18:02,840 --> 00:18:06,160
+الثانية الرابع الأول والرابع الثانية الـ sign دائما
+
+184
+00:18:06,160 --> 00:18:13,700
+وأبدا موجبة يبقى هذه دائما وأبدا أقل من وقت تساوي
+
+185
+00:18:13,700 --> 00:18:20,790
+1 على X أص نص، مظبوط؟ يبقى هذه أقل من هذه، طب
+
+186
+00:18:20,790 --> 00:18:25,390
+التكامل 1 على X أص نص هذا converge ولا ضيوفي؟
+
+187
+00:18:25,390 --> 00:18:31,450
+يعني بنفع شغلي هذا؟ لأن مع الـ converge بدأ نمشي
+
+188
+00:18:31,450 --> 00:18:34,970
+أكبر منه، مع الـ converge بدأ أمشي أقل منه، بنفع
+
+189
+00:18:34,970 --> 00:18:41,790
+شغلي هذا؟ بنفع بس أنت فاهم غلطة هم غلط، افتح على
+
+190
+00:18:41,790 --> 00:18:46,870
+النظرية تحت المرة اللي فاتت يلا افتح عليها لـ تكامل
+
+191
+00:18:46,870 --> 00:18:51,390
+1 على X to the power P افتح يلا فلعب واطلع
+
+192
+00:18:51,390 --> 00:18:59,110
+فيها تكامل من إيه لوين؟ من إيه لوين؟ وهذا من إيه
+
+193
+00:18:59,110 --> 00:19:04,860
+لوين؟ يبقى بطل يصير الكلام تبقى عن نظرية يبقى أنت
+
+194
+00:19:04,860 --> 00:19:11,320
+جيت تطبق النظرية تطبيقا خاطئا لأن النظرية بتجلي من
+
+195
+00:19:11,320 --> 00:19:14,860
+عند الـ a والـ a تجليها تبقى from zero to infinity
+
+196
+00:19:14,860 --> 00:19:19,320
+لكن هذا من غير لـ وان، فكرة صغيرة باسم الصفر الموجود
+
+197
+00:19:19,320 --> 00:19:23,440
+تيجي تجلي على النظرية بيجيش عن نظرية يبقى لك تطبق
+
+198
+00:19:23,440 --> 00:19:27,320
+النظرية تطبيقا صحيحا لازم يكون التكامل عندك من
+
+199
+00:19:27,320 --> 00:19:32,830
+constant لـ infinity مش من zero لغاية π، طب هل هذا
+
+200
+00:19:32,830 --> 00:19:38,570
+improper integral؟ لا طبعا، كيف لا؟ طبعا عند الـ π
+
+201
+00:19:38,570 --> 00:19:44,490
+مثلا يبقى عند الـ zero على سبيل المثال الـ X بـ zero
+
+202
+00:19:44,490 --> 00:19:47,270
+والـ sin zero بـ zero ده لغة المعرفة يبقى هذا
+
+203
+00:19:47,270 --> 00:19:53,390
+improper integral طيب هذه كمان لحالها ده لك تافه
+
+204
+00:19:53,390 --> 00:19:57,750
+هذه صحيحة مية المية بس التطبيق اللي بيحصل الطبقة على
+
+205
+00:19:57,750 --> 00:20:01,670
+غير تطبيق الخطأ إن هو ده كلام ما ينفعش، طب تعالى نشوف
+
+206
+00:20:01,670 --> 00:20:09,390
+تكامل من zero لغاية π لـ 1 على X أص نص DX طبعا
+
+207
+00:20:09,390 --> 00:20:14,890
+عند zero تبقى لغير معرفة، مدام غير معرفة يبقى هذا
+
+208
+00:20:14,890 --> 00:20:21,150
+improper integral يبقى تكامل من A إلى B لما A
+
+209
+00:20:21,150 --> 00:20:27,160
+بدها تروح لـ zero من وين؟ من جهة اليمين لـ X أص ناقص
+
+210
+00:20:27,160 --> 00:20:34,780
+نص DX يبقى limit لما الـ A بدها تروح للـ zero من جهة
+
+211
+00:20:34,780 --> 00:20:42,500
+اليمين تمام لـ مين؟ لـ X أص نص على نص والحاجة هذا من
+
+212
+00:20:42,500 --> 00:20:52,380
+A لغاية π طيب يساوي 2 وهذا الـ limit لما a بدأت
+
+213
+00:20:52,380 --> 00:21:00,680
+تروح لـ zero من جهة اليمين لجذر الـ π ناقص جذر الـ a
+
+214
+00:21:01,880 --> 00:21:05,760
+هذه المقادير اللي عندناها الآن لما قبلها تروح للـ
+
+215
+00:21:05,760 --> 00:21:10,040
+zero يبقى هذا الـ term كله بقى dead بـ zero نهاية
+
+216
+00:21:10,040 --> 00:21:14,980
+المقدار الثابت بالمقدار الثابت itself يبقى 2
+
+217
+00:21:14,980 --> 00:21:20,820
+جذري 4 يبقى التكامل هذا معله converge وليس
+
+218
+00:21:20,820 --> 00:21:26,720
+diverge كما زعم بعضكم قبل قليل يبقى so تكامل من
+
+219
+00:21:26,720 --> 00:21:34,100
+zero لـ π لـ 1 على X أص نص DX convergence مدام
+
+220
+00:21:34,100 --> 00:21:38,000
+convergence يبقى التكامل على الدالة اللي أقل منها
+
+221
+00:21:38,000 --> 00:21:45,100
+convergence فبقى يبقى أقوله π ز دائرة comparison
+
+222
+00:21:45,100 --> 00:21:54,470
+test التكامل من zero لغاية π لـ DX على جذر الـ X
+
+223
+00:21:54,470 --> 00:22:05,630
+زائد sin X converge طب خذي كمان سؤال، الثامن، سؤال
+
+224
+00:22:05,630 --> 00:22:16,170
+الثامن بدنا تكامل من 100 لغاية infinity لـ X ناقص
+
+225
+00:22:16,170 --> 00:22:25,970
+99 على الجذر التربيعي لـ X أُس 5 زائد X زائد
+
+226
+00:22:25,970 --> 00:22:26,970
+1 DX
+
+227
+00:22:31,640 --> 00:22:35,800
+يا الله فكر لي في السؤال كويس، علشان أشوف كيف الحل
+
+228
+00:22:35,800 --> 00:22:37,520
+تبع هذا السؤال
+
+229
+00:22:55,070 --> 00:23:00,590
+بدأ ناخد الدالة اللي عندنا هذا X ناقص 99
+
+230
+00:23:00,590 --> 00:23:08,510
+على الجذر التربيعي لـ X أُس 5 زائد X زائد 1
+
+231
+00:23:08,510 --> 00:23:15,090
+هذا السؤال يختلف عن سابقاته ليش؟ لأنك تشتغل في كل
+
+232
+00:23:15,090 --> 00:23:18,830
+من البسط والمقام، طب في البداية بدي أعرف إني بدي
+
+233
+00:23:18,830 --> 00:23:23,690
+أمشي أقل من ولا أكبر من، بنقول بنشيل الـ 99
+
+234
+00:23:23,690 --> 00:23:29,960
+بدل الـ X، الـ 1 والـ X صغار جدا إذا قارنتهم بـ مين؟
+
+235
+00:23:29,960 --> 00:23:34,240
+بالـ X أُس 5 واللي بتتحكم في المسألة الكميات
+
+236
+00:23:34,240 --> 00:23:37,720
+الكبيرة زي ما العالم بتتحكم فيه الدول الكبرى،
+
+237
+00:23:37,720 --> 00:23:42,600
+تمام؟ يبقى أحلى من اعتبر إن هذا مش موجود ودول مش
+
+238
+00:23:42,600 --> 00:23:46,360
+موجود، بظل الجذر التربيعي لـ X أُس 5 يعني X أُس
+
+239
+00:23:46,360 --> 00:23:51,300
+5 على 2 وعندك فوق 1 ضمن واحدة الـ X يبقى
+
+240
+00:23:51,300 --> 00:23:55,740
+أقل من، بدي أمشي لإن 1 تكامل عليها conversion
+
+241
+00:23:55,740 --> 00:24:01,900
+تمام؟ هذه أقل من .. لما يكون عندك شغل في الـ bus في
+
+242
+00:24:01,900 --> 00:24:05,240
+المقام، تشغلش متنين مع بعض، يا بتشغل في الـ bus
+
+243
+00:24:05,240 --> 00:24:09,840
+أولا ثم المقام، يا بتشغل في المقام أولا ثم الـ bus
+
+244
+00:24:09,840 --> 00:24:15,440
+اللي بدك إياه، سيام يبقى باجي بقوله هذا X على
+
+245
+00:24:15,440 --> 00:24:21,180
+الجذر التربيعي لـ X أُس 5 زائد X زائد 1،
+
+246
+00:24:21,180 --> 00:24:27,360
+مظبوط كلامنا هنا؟ المقام ثبته وغيرت بس في البسط
+
+247
+00:24:27,790 --> 00:24:33,610
+مظلوم؟ صح لأن البسط أقل من مين؟ من البسط التاني،
+
+248
+00:24:33,610 --> 00:24:41,510
+يبقى بطول هذه أقل منها، طيب، هذا أقل من X على الجذر
+
+249
+00:24:41,510 --> 00:24:43,290
+التربيعي لـ X أُس 5
+
+250
+00:24:47,730 --> 00:24:53,530
+مظبوط؟ لأن ذاك مقامه أكبر، إذن هذا أقل. هذا سيصبح 
+
+251
+00:24:53,530 --> 00:25:00,430
+X على X أس خمسة على اتنين، يعني واحد على X أس
+
+252
+00:25:00,430 --> 00:25:06,060
+ثلاثة على اتنين. بعد ذلك سأقول بعض، لكن التكامل من
+
+253
+00:25:06,060 --> 00:25:13,740
+100 لـ infinity لـ 1 على x أُس 3 على 2 dx converge
+
+254
+00:25:13,740 --> 00:25:23,500
+السبب because أن P تساوي 3 على 2 اللي هو أكبر من
+
+255
+00:25:23,500 --> 00:25:30,340
+الواحد الصحيح هذا بده يعطيلك by the direct
+
+256
+00:25:30,340 --> 00:25:38,320
+comparison test التكامل من مية الى infinity للـ X
+
+257
+00:25:38,320 --> 00:25:43,000
+ناقص تسعة وتسعين على الجذر التربيعي لـ X أس خمسة
+
+258
+00:25:43,000 --> 00:25:52,440
+زائد X زائد واحد DX ماله converge طيب بعض الناس
+
+259
+00:25:52,440 --> 00:25:57,860
+بتصعبوا من أكثر الأصغر منه و الأكبر من هذه جبنا
+
+260
+00:25:57,860 --> 00:26:04,470
+لهم طريقة ثانية لاختبار التكامل اسمه نمرة اتنين الـ
+
+261
+00:26:04,470 --> 00:26:10,690
+limit comparison test
+
+262
+00:26:10,690 --> 00:26:16,930
+بيقول
+
+263
+00:26:16,930 --> 00:26:29,550
+معاكي if الـ if عند الـ g are positive continuous
+
+264
+00:26:33,410 --> 00:26:41,510
+functions دوال موجبة ومتصلة على الفترة من عند الـ a
+
+265
+00:26:41,510 --> 00:26:53,690
+لغاية infinity and if وإذا كان limit الـ f of x على
+
+266
+00:26:53,690 --> 00:27:02,020
+الـ g of x لما الـ x tends to infinity بدو يساوي L و
+
+267
+00:27:02,020 --> 00:27:07,600
+الـ L هذه أكبر من الـ zero أقل من infinity then
+
+268
+00:27:07,600 --> 00:27:15,240
+تكامل من A إلى infinity للـ F of X DX and تكامل من
+
+269
+00:27:15,240 --> 00:27:26,840
+A إلى infinity للـ G of X DX are both converge or
+
+270
+00:27:26,840 --> 00:27:42,450
+both بهذه الطريقة إما هذه أو تلك مثال تجارب
+
+271
+00:27:42,450 --> 00:27:47,910
+تتبع تجارات
+
+272
+00:27:47,910 --> 00:27:52,970
+تتبع
+
+273
+00:27:52,970 --> 00:27:56,290
+تجارات تتبع تجارات
+
+274
+00:28:00,600 --> 00:28:06,820
+أول تكامل من هذه التكاملات نمرة واحد تكامل من
+
+275
+00:28:06,820 --> 00:28:17,180
+اربعة لغاية infinity لـ 2 DX على X أس
+
+276
+00:28:17,180 --> 00:28:20,720
+ثلاثة على اتنين ناقص واحد
+
+277
+00:28:46,010 --> 00:28:49,650
+يبقى انتهينا من اختبار الـ Direct Comparison Test
+
+278
+00:28:49,650 --> 00:28:54,030
+بدنا نيجي للاختبار الثاني وهو الاختبار الأخير في
+
+279
+00:28:54,030 --> 00:28:57,850
+مجموعة اختبارات الـ Improper Integral اللي هو limit
+
+280
+00:28:57,850 --> 00:29:03,430
+comparison test نهاية اختبار المقارنة هذا الاختبار
+
+281
+00:29:03,430 --> 00:29:08,950
+مهم ليش مين أصغر منه ومين أكبر منه بهمني مين
+
+282
+00:29:08,950 --> 00:29:12,130
+الدالة اللي أصغر ومين الدالة الأكبر، لكن بهمني
+
+283
+00:29:12,130 --> 00:29:18,350
+أنك تخلق دالة من الدالة اللي موجودة و تعمل مقارنة
+
+284
+00:29:18,350 --> 00:29:23,050
+معاها الدالة المخلقة هذه بتكون معروفة بالنسبة لك،
+
+285
+00:29:23,050 --> 00:29:28,370
+هل هي converge أو diverge مسبقا، طالعش بقول لو كان
+
+286
+00:29:28,370 --> 00:29:33,210
+عندي دالتين F و G والتنتين كانوا بإشارة موجبة و
+
+287
+00:29:33,210 --> 00:29:37,730
+اتنين دوال متصلة مشان يكون التكامل exist على
+
+288
+00:29:37,730 --> 00:29:42,650
+الفترة هذه بروح باخد الدالة F و الدالة G و بقسم
+
+289
+00:29:42,650 --> 00:29:46,270
+اتنين على بعض و باخد الـ X لما تروح لما لا نهاية
+
+290
+00:29:46,270 --> 00:29:52,310
+افترض طلعت نهاية عندي والنهاية طلع رقم الرقم هذا
+
+291
+00:29:52,310 --> 00:29:58,050
+ليس سالبا لأن دالتين بالموجب فلا يمكن أن يكون سالب
+
+292
+00:29:58,370 --> 00:30:03,490
+اتنين ممنوع يكون صفر، تلاتة ممنوع يكون infinity
+
+293
+00:30:03,490 --> 00:30:08,310
+يبقى بين الصفر والإنفينتي يطلع أي رقم، أيش ما يكون
+
+294
+00:30:08,310 --> 00:30:13,290
+يكون تمام؟ يبقى إن حدث ذلك، يبقى التكامل على
+
+295
+00:30:13,290 --> 00:30:16,570
+الدالة الأولى والتكامل على الدالة الثانية، اتنين
+
+296
+00:30:16,570 --> 00:30:23,780
+بيكونوا converge مع بعض السؤال هو هل يعطيني دالتين
+
+297
+00:30:23,780 --> 00:30:30,220
+في المثال ولا دالة واحدة؟ يعني يعطيني تكامل على دالة
+
+298
+00:30:30,220 --> 00:30:37,150
+واحدة الشغل يذهب ويتجيب دالة ثانية ويتخلق دالة
+
+299
+00:30:37,150 --> 00:30:41,050
+ثانية من الدالة الموجودة والدالة المخلقة تريد أن
+
+300
+00:30:41,050 --> 00:30:45,890
+تكون معرفة أنت مسبقا هل هي convert ولا diverse
+
+301
+00:30:45,890 --> 00:30:50,950
+وبعد ذلك تمسك الأصلية على الدالة لأنك وبتاخد اللي
+
+302
+00:30:50,950 --> 00:30:55,090
+هم الـ limit إذا اللي ما طلع قيمة عددية بين الـ صفر
+
+303
+00:30:55,090 --> 00:30:59,230
+والمالا نهاية يبقى تكمل على الدالتين زي بعض إذا
+
+304
+00:30:59,230 --> 00:31:03,610
+المخلقة اللي تعرفها convert يبقى الأصلية converge،
+
+305
+00:31:03,610 --> 00:31:08,350
+إذا المخلقة diverse، يبقى الأصلية diverse حلوله هي
+
+306
+00:31:08,350 --> 00:31:13,590
+السفسار هنا قبل ما ندخل على الأمثلة طيب example
+
+307
+00:31:13,590 --> 00:31:19,410
+يبقى أول تكامل هي التكامل اللي عندنا، سؤالنا هو
+
+308
+00:31:19,410 --> 00:31:25,170
+مين أقرب دالة احنا عارفين التكامل عليها converge
+
+309
+00:31:25,170 --> 00:31:31,960
+أو diverge لاسم الدالة هذه، لمين؟ ممتاز جدا يبقى
+
+310
+00:31:31,960 --> 00:31:37,040
+احنا بنعرف أن تكامل من اربعة الى infinity لواحد
+
+311
+00:31:37,040 --> 00:31:43,260
+على X أس تلاتة على اتنين DX converge السبب
+
+312
+00:31:43,260 --> 00:31:48,380
+because أن P تساوي تلاتة على اتنين أكبر من واحد
+
+313
+00:31:48,380 --> 00:31:53,260
+على اتنين يبقى امتنانة من جثة التكامل بتروح اخد الـ
+
+314
+00:31:53,260 --> 00:31:57,820
+limit يبقى هذه الـ limit لما الـ x tends to infinity
+
+315
+00:31:57,820 --> 00:32:05,800
+للي 2 على x أس 3 على 2 ناقص 1 تقسيم 1 على x أس 3
+
+316
+00:32:05,800 --> 00:32:12,440
+على 2 بعد هيك هذا الكلام يساوي الـ limit لما الـ X
+
+317
+00:32:12,440 --> 00:32:18,140
+tends to infinity للي اتنين X أس ثلاثة على اتنين X
+
+318
+00:32:18,140 --> 00:32:22,900
+أس ثلاثة على اتنين ناقص واحد قعدنا صيابة المثلة
+
+319
+00:32:22,900 --> 00:32:26,770
+بالشكل اللي قدامنا هذا التعويض المباشر بيجيب لـ
+
+320
+00:32:26,770 --> 00:32:31,230
+infinity على infinity يبقى استخدام صلاحياتك الـ
+
+321
+00:32:31,230 --> 00:32:35,090
+l'Hôpital تجسم كله من البسط والمقام على x أس ثلاثة
+
+322
+00:32:35,090 --> 00:32:41,050
+على اتنين سيا اللي بدك يجه هذا الكلام limit لما
+
+323
+00:32:41,050 --> 00:32:47,630
+الـ x tends to infinity لـ 2 على 1 x أس ثلاثة على
+
+324
+00:32:47,630 --> 00:32:51,850
+اتنين جسمنا كل من الـ bus و المقام على x ثلاثة على
+
+325
+00:32:51,850 --> 00:32:56,770
+اتنين واحد على مالا نهاية بـ zero فلا الجواب جداش
+
+326
+00:33:03,560 --> 00:33:11,120
+تبعت المقام تبعت المقام هذي converge إذا تبعت الـ
+
+327
+00:33:11,120 --> 00:33:16,620
+bus converge وانتهينا منها يبقى بادي بقوله by the
+
+328
+00:33:16,620 --> 00:33:25,350
+limit comparison test تكامل 2 على x أس 3 على 2 ناقص
+
+329
+00:33:25,350 --> 00:33:32,470
+1 dx من 4 لغاية infinity converge وانتهينا منها،
+
+330
+00:33:32,470 --> 00:33:39,210
+يبقى بالديش مين لا أصغر منه ولا أكبر منه سؤال ثاني
+
+331
+00:33:39,210 --> 00:33:47,150
+يقول لي تكامل من 1 لغاية infinity للـ dx على الجذر
+
+332
+00:33:47,150 --> 00:33:49,830
+التربيعي لـ 3x زائد 1
+
+333
+00:33:53,930 --> 00:33:57,410
+بتخلق ده لو أنا كنت عارف اللي هي mean واحد عادي
+
+334
+00:33:57,410 --> 00:34:01,650
+يا در الـ X يعني واحد على X أس نص convert ولا
+
+335
+00:34:01,650 --> 00:34:06,830
+diverge؟ diverge يبقى احنا بنعرف تكامل من واحد لـ
+
+336
+00:34:06,830 --> 00:34:14,030
+infinity لواحد على X أس نص DX هذي diverge because
+
+337
+00:34:14,030 --> 00:34:20,940
+P يساوي النص أقل من الواحد الصحيح بتروح اخد limit
+
+338
+00:34:20,940 --> 00:34:25,940
+لما الـ X tends to infinity لـ 1 على الجذر التربيعي لـ
+
+339
+00:34:25,940 --> 00:34:36,470
+3X زائد 1 تقسيم 1 على الجذر X يبقى هذا الـ limit لما
+
+340
+00:34:36,470 --> 00:34:41,170
+الـ x tends to infinity لجذر الـ x على الجذر
+
+341
+00:34:41,170 --> 00:34:46,790
+التربيعي لـ 3x زائد واحد أو إن شئتم فاقولوا الـ
+
+342
+00:34:46,790 --> 00:34:51,210
+limit لما الـ x tends to infinity بدي اخليه جذر
+
+343
+00:34:51,210 --> 00:34:56,820
+واحد على 3x زائد واحد مش عاجبك و بس الـ limit معاها
+
+344
+00:34:56,820 --> 00:35:02,560
+صلاحيات الدخول داخل الـ geodor يتجا limit لما الـ x
+
+345
+00:35:02,560 --> 00:35:10,710
+tends to infinity للـ x على 3x زائد 1 طبعا التعويض
+
+346
+00:35:10,710 --> 00:35:15,970
+المباشر بيجيب لي ما لا نهاية على ما لا نهاية يبقى
+
+347
+00:35:15,970 --> 00:35:20,790
+الـ l'Hôpital Rule أو نقص البسط والمقام على X يبقى
+
+348
+00:35:20,790 --> 00:35:26,970
+النتيجة الجذر التربيعي الواحد على جذر 3
+
+349
+00:35:26,970 --> 00:35:32,990
+يعني واحد على جذر التلاتة رقم محصور بين Zero و
+
+350
+00:35:32,990 --> 00:35:39,940
+Infinity يبقى باجي بقوله هنا باي The Limit
+
+351
+00:35:39,940 --> 00:35:47,680
+Comparison Test التكامل من واحد لإنفينيتي للـ dx
+
+352
+00:35:47,680 --> 00:35:52,020
+على الجذر التربيعي لـ 3x زائد الواحد ماله، by
+
+353
+00:35:52,020 --> 00:35:57,660
+where؟ هذا واحد كان يفكر غير تفكيرنا هذا، قلنا له
+
+354
+00:35:57,660 --> 00:36:01,890
+أيوه قال لي أنا أريد أن أحل بالـ Direct، لا أريد أن
+
+355
+00:36:01,890 --> 00:36:05,310
+أحل بالـ Limit، لم نستطيع أن نقول له لا، لكننا كل
+
+356
+00:36:05,310 --> 00:36:08,190
+الموضوع موضوعنا الـ Limit Comparison، حلناه بالـ
+
+357
+00:36:08,190 --> 00:36:11,150
+Limit Comparison، لكنه لو راح في الـ Ham الشيخ
+
+358
+00:36:11,150 --> 00:36:18,050
+وقال لي واحد على الجذر التربيعي لـ 3X زائد 1 أكبر من
+
+359
+00:36:18,050 --> 00:36:25,590
+واحد على الجذر التربيعي لـ 3X زائد X وقد يساويه عند
+
+360
+00:36:25,590 --> 00:36:32,490
+الواحد، مصبور؟ هذا أكبر منه و قد يساوي هذا يعني هذا
+
+361
+00:36:32,490 --> 00:36:39,190
+واحد على اتنين اكس و أس نص تلات اكس زائد اكس باربع
+
+362
+00:36:39,190 --> 00:36:43,010
+اكس تطلع من تحت الجلد بتكون أصلا التكامل هذا by
+
+363
+00:36:43,010 --> 00:36:47,300
+variable أكبر منه تكامل عليها by virtue وانتهينا
+
+364
+00:36:47,300 --> 00:36:51,600
+منها يبقى أي حل بطريقة من الدائرة الـ comparison
+
+365
+00:36:51,600 --> 00:36:55,900
+test وليس بطريقة الـ limit comparison test أجي واحد
+
+366
+00:36:55,900 --> 00:37:00,160
+تالي قال لي أنا ما أقدر أكملها و بدي اروح احله بدون
+
+367
+00:37:00,160 --> 00:37:04,120
+التكامل و بديش استخدم لاختبارات اتنين أقوله مافيش
+
+368
+00:37:04,120 --> 00:37:08,110
+مشكلة بقدر يكملها وبالتالي التكامل هيطلع عنده أيش
+
+369
+00:37:08,110 --> 00:37:12,710
+كذلك؟ By-Variable طب سؤالنا هو لو استخدمنا اختبار
+
+370
+00:37:12,710 --> 00:37:16,930
+وطلع converge وروحنا استخدمنا اختبار ثاني وطلع by
+
+371
+00:37:16,930 --> 00:37:23,630
+-variable يكون فيه خطأ في إحدى الحلين لازم بأي
+
+372
+00:37:23,630 --> 00:37:27,570
+اختبار اشتغلنا شغل سياطلة converge بطريقة ثانية
+
+373
+00:37:27,570 --> 00:37:32,300
+بده يطلع converge مش مرة convergent ومرة divergent،
+
+374
+00:37:32,300 --> 00:37:36,060
+تلاعب، لا لا فيش منها هذا الكلام، طيب فهذا كان
+
+375
+00:37:36,060 --> 00:37:41,920
+المثال رقم اثنين، بدنا نروح للمثال رقم تلاتة مثال
+
+376
+00:37:41,920 --> 00:37:48,100
+رقم تلاتة بيقول يتكامل من واحد إلى infinity لtan
+
+377
+00:37:48,100 --> 00:37:54,730
+inverse x على x تربيع dx من أقنع الدالة على هذه
+
+378
+00:37:54,730 --> 00:37:57,710
+الدالة ممكن نقارن معاها ويكون التكامل عليها
+
+379
+00:37:57,710 --> 00:38:04,370
+معروف؟ 1 على x تربيع يبقى احنا عندنا تكامل من 1
+
+380
+00:38:04,370 --> 00:38:11,680
+إلى infinity ل 1 على x تربيع DX converge السبب بسبب
+
+381
+00:38:11,680 --> 00:38:17,980
+أن P تساوي 2 أكبر من الواحد الصحيح إذا بنروح ناخد
+
+382
+00:38:17,980 --> 00:38:25,760
+limit لما X tends to infinity لتان inverse X على
+
+383
+00:38:25,760 --> 00:38:32,160
+مين؟ على X تربيع تقسيم واحد على X تربيع اللي هي
+
+384
+00:38:32,160 --> 00:38:38,060
+بتبدأ تساوي limit لما ال X tends to infinity بس لتان
+
+385
+00:38:38,060 --> 00:38:43,950
+inverse X X تربيع هتطلع فوق تختصر مع تبع المقام
+
+386
+00:38:43,950 --> 00:38:50,650
+بيظل بس tan inverse X عند النهاية هذي بيجي π على 2
+
+387
+00:38:50,650 --> 00:38:55,310
+يبقى تساوي π بيقوله بال limit comparison test
+
+388
+00:38:55,310 --> 00:39:00,590
+الدالة التانية هذي converge يبقى باجي بقوله بي ل
+
+389
+00:39:00,980 --> 00:39:07,300
+Limit Comparison Test التكامل من واحد إلى infinity 
+
+390
+00:39:07,300 --> 00:39:13,800
+لتان inverse X على X تربيع DX converge وانتهينا منها
+
+391
+00:39:13,800 --> 00:39:18,680
+أجي واحد قال لأ أنا بحله بال comparison بالطريقة ال
+
+392
+00:39:18,680 --> 00:39:23,140
+comparison وليس بال limit comparison قلت له كيف؟
+
+393
+00:39:23,140 --> 00:39:31,870
+قال لي هاي tan inverse X على مين؟ على X تربيع هذه هي
+
+394
+00:39:31,870 --> 00:39:37,610
+tan inverse X عند النهاية أقصى ما يمكن، فهذه بيصير
+
+395
+00:39:37,610 --> 00:39:43,890
+π على اتنين، إذا هذه أقل من π على اتنين
+
+396
+00:39:43,890 --> 00:39:47,710
+على X تربيع، π على اتنين هذا كله صارت برة
+
+397
+00:39:47,710 --> 00:39:50,270
+التكامل وصارت 1 على X تربيع التكامل هذا ال
+
+398
+00:39:50,270 --> 00:39:54,350
+converge يبقى أصغر منها converge وانتهينا من وين
+
+399
+00:39:54,350 --> 00:39:57,130
+من هذه المسألة
+
+400
+00:40:11,550 --> 00:40:17,950
+طيب هذا كان السؤال التالت خد السؤال الرابع السؤال
+
+401
+00:40:17,950 --> 00:40:26,270
+الرابع بيقول لي تكامل من واحد إلى infinity ل dx
+
+402
+00:40:26,270 --> 00:40:33,930
+على الجذر التربيعي ل x تربيع ناقص x زائد واحد مين
+
+403
+00:40:33,930 --> 00:40:39,470
+أقرب دالة على هذه الدالة؟ واحد على x تحت
+
+404
+00:40:39,470 --> 00:40:44,870
+الجذر يعني جداش واحد على x الآن تكامل من واحد ل
+
+405
+00:40:44,870 --> 00:40:52,950
+infinity لواحد على x DX diverge because ان P تساوي
+
+406
+00:40:52,950 --> 00:40:58,450
+واحد صحيح إذا بدنا نروح ناخد ال limit لما ال x
+
+407
+00:40:58,450 --> 00:41:03,610
+tends to infinity لواحد على الجذر التربيعي ل x تربيع ناقص x
+
+408
+00:41:03,610 --> 00:41:09,970
+زائد واحد تقسيم 1 على x يبقى limit لما ال x تنسى
+
+409
+00:41:09,970 --> 00:41:15,190
+infinity لل x على الجذر التربيعي ل x تربيع ناقص x
+
+410
+00:41:15,190 --> 00:41:24,580
+زائد 1 بنروح نقسم كل من ال بسط و المقام على كم؟ على
+
+411
+00:41:24,580 --> 00:41:30,360
+x لأن الجذر التربيعي على x تربيع هي ب x وهي أكبر أس
+
+412
+00:41:30,360 --> 00:41:35,040
+موجود في المقام يبقى هذه تساوي ال limit لما ال x
+
+413
+00:41:35,040 --> 00:41:41,810
+تنسى من x على x كم؟ بواحد على الجذر التربيعي ل x
+
+414
+00:41:41,810 --> 00:41:46,830
+لما ندخلها تحت الجذر تدخل x تربيع يبقى بيصير
+
+415
+00:41:46,830 --> 00:41:51,970
+واحد ناقص واحد على x زائد واحد على x تربيع
+
+416
+00:41:56,210 --> 00:42:01,450
+يبقى التنتين هذول زي بعض يبقى باجي بقوله by the
+
+417
+00:42:01,450 --> 00:42:08,570
+limit comparison test التكامل من 1 ل infinity ل dx
+
+418
+00:42:08,570 --> 00:42:13,490
+على الجذر التربيعي ل x تربيع ناقص x زائد 1 مالها
+
+419
+00:42:13,490 --> 00:42:20,760
+diverge طب ايش رأيك واحد جلن بحله بال comparison؟
+
+420
+00:42:20,760 --> 00:42:27,880
+حل زي ما بدك ما فيش قيود يبقى واحد على الجذر
+
+421
+00:42:27,880 --> 00:42:33,780
+التربيعي ل x تربيع ناقص x زائد واحد شيل اتنين
+
+422
+00:42:33,780 --> 00:42:38,520
+هدول بيبقوا واحد على x diverge يبقى بدي امشي أكبر
+
+423
+00:42:38,520 --> 00:42:44,720
+من واحد على الجذر التربيعي ل x تربيع ل x صح كلامي؟
+
+424
+00:42:46,570 --> 00:42:51,930
+هذا أكبر من هذا، مظبوط؟ لا مش مظبوط، مش صحيح، طب
+
+425
+00:42:51,930 --> 00:43:01,110
+قولي هذا ناقص x صح كلامي؟ لازم غلط، طبعا، طيب لو
+
+426
+00:43:01,110 --> 00:43:07,740
+جيت قلت زائد x وهذا التكامل عند الواحد ممكن يحصل
+
+427
+00:43:07,740 --> 00:43:12,460
+التساوي عند الواحد تمام؟ هي الكلام سليم مئة بالمئة
+
+428
+00:43:12,460 --> 00:43:20,700
+بدل الواحد روحت كتبت x يبقى هنا بتروح هادي مع هادي
+
+429
+00:43:20,700 --> 00:43:25,740
+وبفضل واحد على جذر x تربيع اليومين واحدة ال x هادي
+
+430
+00:43:25,740 --> 00:43:29,160
+diverge التكامل عليها إذا هادي diverge
+
+431
+00:43:31,890 --> 00:43:36,230
+كيف؟ لأ لأ لأ لأ انت حر استخدم الطريقة اللي بدك
+
+432
+00:43:36,230 --> 00:43:42,650
+إياها كل اللي بنقدر نقوله decide قرر هل التكامل
+
+433
+00:43:42,650 --> 00:43:46,490
+يتالي converge و لا diverge تستخدم اختبار الأول
+
+434
+00:43:46,490 --> 00:43:55,930
+اختبار التاني التكامل انت حر هذا الشأن المثال
+
+435
+00:43:55,930 --> 00:44:03,490
+الخامس المثال الخامس تكامل من واحد إلى infinity
+
+436
+00:44:03,490 --> 00:44:12,490
+لواحد على E أس x ناقص 2 أس x DX أقرب دالة
+
+437
+00:44:12,490 --> 00:44:18,310
+على هذه الدالة تكامل من واحد infinity لواحد على E
+
+438
+00:44:18,310 --> 00:44:23,390
+أس x DX هذه اظنها convergence من المرة اللي فاتت
+
+439
+00:44:24,070 --> 00:44:31,170
+يبقى هذه converge a previous example
+
+440
+00:44:33,070 --> 00:44:38,750
+يبقى بنروح ناخد limit لما ال x tends to infinity
+
+441
+00:44:38,750 --> 00:44:47,810
+لمين؟ ل 1 على E أس x نقص 2 أس x تقسيم 1 على E أس
+
+442
+00:44:47,810 --> 00:44:55,050
+x بتبدأ تروح لل infinity لل E أس x على ال E أس x
+
+443
+00:44:55,050 --> 00:45:00,210
+ناقص 2 أس x تمام؟
+
+444
+00:45:01,040 --> 00:45:06,240
+يبقى هذا الكلام بده يساوي ال limit لما ال x tends
+
+445
+00:45:06,240 --> 00:45:11,180
+to infinity نقسم البسط والمقام على E أس x و ال
+
+446
+00:45:11,180 --> 00:45:18,740
+2 أس x لأن هي الأكبر، مظبوط؟ يبقى بصير عندك
+
+447
+00:45:18,740 --> 00:45:26,900
+واحد على واحد زائد 2 على E كل أس x هذا بقداش
+
+448
+00:45:26,900 --> 00:45:31,200
+ال limit له 1 مش مشكلة مش مشكلة مش
+
+449
+00:45:31,200 --> 00:45:32,040
+مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة
+
+450
+00:45:32,040 --> 00:45:32,300
+مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش
+
+451
+00:45:32,300 --> 00:45:34,040
+مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة
+
+452
+00:45:34,040 --> 00:45:36,340
+مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش
+
+453
+00:45:36,340 --> 00:45:36,360
+مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة
+
+454
+00:45:36,360 --> 00:45:36,520
+مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش
+
+455
+00:45:36,520 --> 00:45:54,020
+مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة مش مشكلة
+
+456
+00:45:54,020 --> 00:45:59,320
+مش التكامل من واحد الى infinity لواحد عليه E أس x
+
+457
+00:45:59,320 --> 00:46:05,080
+ناقص 2 أس x DX ماله converge وانتهينا من
+
+458
+00:46:05,080 --> 00:46:11,380
+المسألة إليكم أرقام المسائل المطلوب حلها من section
+
+459
+00:46:11,380 --> 00:46:17,700
+ثمانية سبعة ثمانية سبعة من واحد لخمسة وستين القدر
+
+460
+00:46:17,700 --> 00:46:24,560
+يبقى exercises ثمانية سبعة من واحد لغاية خمسة
+
+461
+00:46:24,560 --> 00:46:26,840
+وستين القدر
+
+462
+00:46:29,930 --> 00:46:35,510
+هنا لحد هنا انتهت المحاضرة وبالتالي انتهى هذا ال
+
+463
+00:46:35,510 --> 00:46:39,750
+section بالمرة الجاية إن شاء الله بنبدأ chapter
+
+464
+00:46:39,750 --> 00:46:41,750
+اللي جديد chapter عشرة
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/Dcb02BSs1w4_raw.json b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/Dcb02BSs1w4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..2f9556b38e608bce2abd10196f9f19872dc49aad
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/Dcb02BSs1w4_raw.json
@@ -0,0 +1 @@
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الطريقة اما هذه او تلك مثال تجارب تتبع اتجارات تتبع اتجارات تتبع اتجارات", "tokens": [3555, 3224, 24192, 41950, 16572, 28671, 1975, 15042, 29538, 1975, 2407, 6055, 23275, 50113, 6027, 6055, 7435, 9640, 3555, 6055, 2655, 3555, 3615, 1975, 2655, 7435, 9640, 9307, 6055, 2655, 3555, 3615, 1975, 2655, 7435, 9640, 9307, 6055, 2655, 3555, 3615, 1975, 2655, 7435, 9640, 9307], "avg_logprob": -0.5069813550786769, "compression_ratio": 1.88, "no_speech_prob": 0.0, "words": [{"start": 1649.23, "end": 1650.15, "word": "بهذه", "probability": 0.5262858072916666}, {"start": 1650.15, "end": 1650.19, "word": " الطريقة", "probability": 0.78662109375}, {"start": 1650.19, "end": 1651.99, "word": " اما", "probability": 0.5587158203125}, {"start": 1651.99, "end": 1652.51, "word": " هذه", "probability": 0.62744140625}, {"start": 1652.51, "end": 1653.11, "word": " او", "probability": 0.81103515625}, {"start": 1653.11, "end": 1653.43, "word": " تلك", "probability": 0.95068359375}, {"start": 1653.43, "end": 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مشكلة", "probability": 0.87841796875}, {"start": 2736.52, "end": 2736.52, "word": " مش", "probability": 0.9775390625}, {"start": 2736.52, "end": 2736.52, "word": " مشكلة", "probability": 0.8533528645833334}, {"start": 2736.52, "end": 2736.52, "word": " مش", "probability": 0.9755859375}, {"start": 2736.52, "end": 2736.52, "word": " مشكلة", "probability": 0.84619140625}, {"start": 2736.52, "end": 2736.52, "word": " مش", "probability": 0.97412109375}, {"start": 2736.52, "end": 2736.52, "word": " مشكلة", "probability": 0.8447265625}, {"start": 2736.52, "end": 2736.52, "word": " مش", "probability": 0.9716796875}, {"start": 2736.52, "end": 2736.52, "word": " مشكلة", "probability": 0.80029296875}, {"start": 2736.52, "end": 2736.52, "word": " مش", "probability": 0.96923828125}, {"start": 2736.52, "end": 2736.52, "word": " مشكلة", "probability": 0.7638346354166666}, {"start": 2736.52, "end": 2738.52, "word": " مش", "probability": 0.96630859375}, {"start": 2738.52, "end": 2754.02, "word": " مشكلة", "probability": 0.8644205729166666}, {"start": 2754.02, "end": 2754.04, "word": " مش", "probability": 0.96337890625}], "temperature": 1.0}, {"id": 120, "seek": 276892, "start": 2754.06, "end": 2768.92, "text": "التكامل من واحد الى infinity لواحد عليه ال six ناقص اتنين وال six DX ماله converge وانتهينا من الرسلة إليكم أرقام المسائل", "tokens": [6027, 2655, 4117, 10943, 1211, 9154, 36764, 24401, 2423, 7578, 13202, 5296, 14407, 24401, 25894, 3224, 2423, 2309, 8717, 995, 4587, 9381, 1975, 2655, 1863, 9957, 16070, 2309, 48817, 3714, 6027, 3224, 41881, 4032, 7649, 47395, 1829, 8315, 9154, 34892, 3794, 37977, 11933, 20292, 24793, 5551, 2288, 4587, 10943, 9673, 3794, 16373, 1211], "avg_logprob": -0.2567997701742031, "compression_ratio": 1.3776223776223777, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2754.06, "end": 2755.18, "word": "التكامل", "probability": 0.84140625}, {"start": 2755.18, "end": 2755.6, "word": " من", "probability": 0.9111328125}, {"start": 2755.6, "end": 2756.18, "word": " واحد", "probability": 0.773681640625}, {"start": 2756.18, "end": 2756.54, "word": " الى", "probability": 0.6307373046875}, {"start": 2756.54, "end": 2757.2, "word": " infinity", "probability": 0.347900390625}, {"start": 2757.2, "end": 2758.36, "word": " لواحد", "probability": 0.759765625}, {"start": 2758.36, "end": 2758.82, "word": " عليه", "probability": 0.607177734375}, {"start": 2758.82, "end": 2759.02, "word": " ال", "probability": 0.89306640625}, {"start": 2759.02, "end": 2759.32, "word": " six", "probability": 0.4697265625}, {"start": 2759.32, "end": 2760.22, "word": " ناقص", "probability": 0.81793212890625}, {"start": 2760.22, "end": 2760.78, "word": " اتنين", "probability": 0.969482421875}, {"start": 2760.78, "end": 2761.0, "word": " وال", "probability": 0.64501953125}, {"start": 2761.0, "end": 2761.32, "word": " six", "probability": 0.64306640625}, {"start": 2761.32, "end": 2761.84, "word": " DX", "probability": 0.6240234375}, {"start": 2761.84, "end": 2762.58, "word": " ماله", "probability": 0.8753255208333334}, {"start": 2762.58, "end": 2763.8, "word": " converge", "probability": 0.38623046875}, {"start": 2763.8, "end": 2764.64, "word": " وانتهينا", "probability": 0.941015625}, {"start": 2764.64, "end": 2765.08, "word": " من", "probability": 0.9833984375}, {"start": 2765.08, "end": 2766.0, "word": " الرسلة", "probability": 0.89599609375}, {"start": 2766.0, "end": 2767.14, "word": " إليكم", "probability": 0.7108154296875}, {"start": 2767.14, "end": 2767.78, "word": " أرقام", "probability": 0.961669921875}, {"start": 2767.78, "end": 2768.92, "word": " المسائل", "probability": 0.9293212890625}], "temperature": 1.0}, {"id": 121, "seek": 278684, "start": 2769.3, "end": 2786.84, "text": "المطلوب حلها من section تمانية سبعة تمانية سبعة من واحد لخمسة وستين القدر يبقى exercises تمانية سبعة من واحد لغاية خمسة وستين القدر", "tokens": [45340, 9566, 1211, 37746, 11331, 1211, 11296, 9154, 3541, 46811, 7649, 10632, 8608, 3555, 27884, 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"probability": 0.8688151041666666}, {"start": 2773.86, "end": 2774.56, "word": " سبعة", "probability": 0.9737955729166666}, {"start": 2774.56, "end": 2775.0, "word": " من", "probability": 0.9326171875}, {"start": 2775.0, "end": 2775.4, "word": " واحد", "probability": 0.979736328125}, {"start": 2775.4, "end": 2775.98, "word": " لخمسة", "probability": 0.93271484375}, {"start": 2775.98, "end": 2776.66, "word": " وستين", "probability": 0.9244791666666666}, {"start": 2776.66, "end": 2777.7, "word": " القدر", "probability": 0.6250813802083334}, {"start": 2777.7, "end": 2778.2, "word": " يبقى", "probability": 0.79052734375}, {"start": 2778.2, "end": 2779.4, "word": " exercises", "probability": 0.8974609375}, {"start": 2779.4, "end": 2780.7, "word": " تمانية", "probability": 0.98095703125}, {"start": 2780.7, "end": 2781.52, "word": " سبعة", "probability": 0.98046875}, {"start": 2781.52, "end": 2782.32, "word": " من", "probability": 0.95556640625}, {"start": 2782.32, "end": 2783.12, "word": " واحد", "probability": 0.99365234375}, {"start": 2783.12, "end": 2784.02, "word": " لغاية", "probability": 0.9715576171875}, {"start": 2784.02, "end": 2784.56, "word": " خمسة", "probability": 0.9930419921875}, {"start": 2784.56, "end": 2785.5, "word": " وستين", "probability": 0.9869791666666666}, {"start": 2785.5, "end": 2786.84, "word": " القدر", "probability": 0.9754231770833334}], "temperature": 1.0}, {"id": 122, "seek": 280175, "start": 2789.93, "end": 2801.75, "text": "هنا لحد هنا انتهت المحاضرة وبالتالي انتهى هذا ال section بالمرة الجاية ان شاء الله بنبدأ الشبتر اللي جديد الشبتر عشرة", "tokens": [3224, 8315, 5296, 24401, 34105, 16472, 47395, 2655, 9673, 5016, 46958, 25720, 46599, 6027, 2655, 6027, 1829, 16472, 47395, 7578, 23758, 2423, 3541, 4724, 45340, 25720, 25724, 995, 10632, 16472, 13412, 16606, 21984, 44945, 44510, 10721, 25124, 3555, 2655, 2288, 13672, 1829, 10874, 16254, 3215, 25124, 3555, 2655, 2288, 6225, 8592, 25720], "avg_logprob": -0.3275353841061862, "compression_ratio": 1.5681818181818181, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2789.93, "end": 2790.25, "word": "هنا", "probability": 0.68359375}, {"start": 2790.25, "end": 2790.59, "word": " لحد", "probability": 0.615966796875}, {"start": 2790.59, "end": 2790.79, "word": " هنا", "probability": 0.90185546875}, {"start": 2790.79, "end": 2791.41, "word": " انتهت", "probability": 0.9365234375}, {"start": 2791.41, "end": 2792.83, "word": " المحاضرة", "probability": 0.8114013671875}, {"start": 2792.83, "end": 2794.03, "word": " وبالتالي", "probability": 0.88779296875}, {"start": 2794.03, "end": 2794.73, "word": " انتهى", "probability": 0.9619140625}, {"start": 2794.73, "end": 2795.29, "word": " هذا", "probability": 0.8994140625}, {"start": 2795.29, "end": 2795.51, "word": " ال", "probability": 0.463623046875}, {"start": 2795.51, "end": 2796.15, "word": " section", "probability": 0.88525390625}, {"start": 2796.15, "end": 2797.45, "word": " بالمرة", "probability": 0.5495808919270834}, {"start": 2797.45, "end": 2797.81, "word": " الجاية", "probability": 0.7613932291666666}, {"start": 2797.81, "end": 2797.93, "word": " ان", "probability": 0.89892578125}, {"start": 2797.93, "end": 2798.23, "word": " شاء", "probability": 0.961181640625}, {"start": 2798.23, "end": 2798.41, "word": " الله", "probability": 0.95751953125}, {"start": 2798.41, "end": 2799.27, "word": " بنبدأ", "probability": 0.7464192708333334}, {"start": 2799.27, "end": 2799.75, "word": " الشبتر", "probability": 0.6220703125}, {"start": 2799.75, "end": 2799.87, "word": " اللي", "probability": 0.5780029296875}, {"start": 2799.87, "end": 2800.21, "word": " جديد", "probability": 0.7401529947916666}, {"start": 2800.21, "end": 2801.13, "word": " الشبتر", "probability": 0.80560302734375}, {"start": 2801.13, "end": 2801.75, "word": " عشرة", "probability": 0.85546875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2802.393, "duration_after_vad": 2689.4259687499916}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/GFIdpUdWyYA_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/GFIdpUdWyYA_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1dbe7ed9d6ae9aaa581f63a304b90a4c57affc53
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/GFIdpUdWyYA_raw.srt
@@ -0,0 +1,1904 @@
+1
+00:00:00,000 --> 00:00:02,680
+موسيقى
+
+2
+00:00:11,910 --> 00:00:16,610
+بسم الله الرحمن الرحيم اللى بنكمل المرة هذه على ما
+
+3
+00:00:16,610 --> 00:00:21,350
+ابتدأنا بيه في المرة الماضية وهو موضوع inverse
+
+4
+00:00:21,350 --> 00:00:25,510
+trigonometric functions طبعا المرة اللى فاتت رسمنا
+
+5
+00:00:25,510 --> 00:00:30,790
+الرسومات تبعة معكوس الدوال المثلثية وابتدأنا ناخد
+
+6
+00:00:30,790 --> 00:00:35,850
+أمثلة واخدنا مثالا واحدا فقطوابتدأنا في المثال
+
+7
+00:00:35,850 --> 00:00:41,270
+الثاني وفي المثال الثاني أخدنا ثلاث نقاط والان
+
+8
+00:00:41,270 --> 00:00:47,050
+بنروح للنقطة الرابعة وهي إيجاد قيمة cosine ل
+
+9
+00:00:47,050 --> 00:00:53,730
+cosine inverse أربعة تلاتة إن أمكن ذلكطبعا السؤال
+
+10
+00:00:53,730 --> 00:00:59,110
+اللى كان بالصيرة التالية هاتني قيمة او بالنص كان
+
+11
+00:00:59,110 --> 00:01:05,370
+كالتالي Find the exact value of each of the
+
+12
+00:01:05,370 --> 00:01:10,270
+following separations if it exists يعني اذا كانت
+
+13
+00:01:10,270 --> 00:01:13,310
+موجودة بدنا هذه القيمة مش موجودة خلاص عفو الله
+
+14
+00:01:13,310 --> 00:01:16,680
+عنهاأخدنا المرة اللى فاترة تلات نقاط و لجينا ان
+
+15
+00:01:16,680 --> 00:01:21,920
+تلات نقاط exist و طلعنالها قيمة محددة الآن بنجي
+
+16
+00:01:21,920 --> 00:01:26,860
+للنقطة الرادعى ل cosine ل cosine inverse أربعة على
+
+17
+00:01:26,860 --> 00:01:34,480
+تلاتة السؤال هو هل هذه تساوي أربعة تلاتة؟ لأ
+
+18
+00:01:34,480 --> 00:01:40,560
+لماذا؟ لأن الأربعة على تلاتة ليست في domain ال
+
+19
+00:01:40,560 --> 00:01:43,040
+cosine inverse domain ال cosine inverse من يولا
+
+20
+00:01:43,040 --> 00:01:47,710
+وين؟من سالب واحد إلى واحد آخر النقطتين المرة
+
+21
+00:01:47,710 --> 00:01:52,490
+الماضية استطعنا نجيب زاوية مكافئة للزاوية هذه بعد
+
+22
+00:01:52,490 --> 00:01:57,190
+ما شيلنا ال period تابعة الدالة تمام؟ وبالتالي
+
+23
+00:01:57,190 --> 00:02:00,970
+جيبنا مقدار الزاوية، بس هنا ماعنديش period هنا
+
+24
+00:02:00,970 --> 00:02:06,250
+أربعة، تلاتة رقم هذا، كويس؟ إذا هذا موجود خارج ال
+
+25
+00:02:06,250 --> 00:02:12,230
+domain، إذا هذه القيمة does not existيبقى الإجابة
+
+26
+00:02:12,230 --> 00:02:23,730
+هذا المقدار does not exist السبب because أن
+
+27
+00:02:23,730 --> 00:02:28,850
+الأربعة على تلاتة does not belong لل closed
+
+28
+00:02:28,850 --> 00:02:33,930
+interval سالب واحد واحد اللي هو ال domain تبع ال
+
+29
+00:02:33,930 --> 00:02:35,450
+cosine inverse
+
+30
+00:02:41,420 --> 00:02:49,040
+طيب كان هذا نمرة D نمرة E نمرة E بدنا sign ل
+
+31
+00:02:49,040 --> 00:03:02,300
+cosine inverse جدر اتنين على اتنين لاحظ
+
+32
+00:03:02,300 --> 00:03:07,040
+في الأمثلة التلاتة السابقة كان بدنا sign inverse ل
+
+33
+00:03:07,040 --> 00:03:13,690
+signوبيدنا cosine ل cosine inverse يعني النسبة
+
+34
+00:03:13,690 --> 00:03:18,130
+واحدة هي و معكوسة لكن الآن هذا السؤال sine ل
+
+35
+00:03:18,130 --> 00:03:23,710
+cosine inverse جدر اتنين على اتنين اذا هذا شكله
+
+36
+00:03:23,710 --> 00:03:29,770
+مختلف عن الأربع نقاط الماضية عشان يحسب هذه القيمة
+
+37
+00:03:29,770 --> 00:03:36,220
+بدي اتبع ما يأتيبديك تيجي تقولي افترض ان ثيتا
+
+38
+00:03:36,220 --> 00:03:45,060
+تساوي cosine inverse لجذر 2 على 2 اثر على الطرفين
+
+39
+00:03:45,060 --> 00:03:52,320
+ب cosine بصير cosine ثيتا يساوي cosine ل cosine
+
+40
+00:03:52,320 --> 00:03:59,460
+يبقى مع السلامة قبل اندي جذر 2 على 2جذر اتنين على
+
+41
+00:03:59,460 --> 00:04:05,100
+اتنين لو راح ضربت في جذر اتنين على جذر اتنين ما
+
+42
+00:04:05,100 --> 00:04:11,040
+أصبح النتيجد كده؟ واحد على جذر اتنين ابنا دي نسأل
+
+43
+00:04:11,040 --> 00:04:16,300
+نفسنا ال cosine دائما هو ياخد قيمة مجرة من صفر
+
+44
+00:04:16,300 --> 00:04:19,680
+لباية على اتنين لكن من باية على اتنين لباية ماياخد
+
+45
+00:04:19,680 --> 00:04:25,240
+كده؟ قيمة سالمة و احنا لما جيبنا معكوس ال cosine
+
+46
+00:04:25,540 --> 00:04:31,280
+سنقوم بعمل Restriction من Zero لغاية Pi طيب إذا ال
+
+47
+00:04:31,280 --> 00:04:36,240
+cosine يجب أن يكون قيمة موجبة في الرابع وليس في
+
+48
+00:04:36,240 --> 00:04:40,340
+الثاني إذا هذه بتقع في الرابع لو ال mean الزادة
+
+49
+00:04:40,340 --> 00:04:46,380
+اللي جبت أمامها واحد على جدر اتنين يبقى θ تسوا
+
+50
+00:04:46,380 --> 00:04:51,510
+مقداش خمسة واربعين درجة اللي هو Pi على أربعإذا
+
+51
+00:04:51,510 --> 00:04:58,630
+أصبحت المسألة لأن هذه كالتالي اللي هو sin ل cos
+
+52
+00:04:58,630 --> 00:05:06,970
+inverse جنر 2 على 2 بدل سوى sin ل θ أنا فرضها كلها
+
+53
+00:05:06,970 --> 00:05:12,700
+بثيتا طب ثيتا كده شخصية عندي؟باي على أربع يعني هذه
+
+54
+00:05:12,700 --> 00:05:18,740
+بدأت تساوي ال sign باي على أربع جدرخمسة واربعين
+
+55
+00:05:18,740 --> 00:05:24,940
+كذا لجدار واحد على جدر اتنين اذا sign يكون sign
+
+56
+00:05:24,940 --> 00:05:32,110
+inverse هو عبارة عن واحد على جدر اتنينالنقاط هذه
+
+57
+00:05:32,110 --> 00:05:36,070
+كلها الخمسة اللي أخدتها كلها من السؤال تحسبها على
+
+58
+00:05:36,070 --> 00:05:42,330
+الآلة الحاسبة لكن ممكن أجيب لك سؤال و أجيب لك
+
+59
+00:05:42,330 --> 00:05:48,050
+تحييض الآلة الحاسبة على شجة و تضطر الشغل مخك فاروح
+
+60
+00:05:48,050 --> 00:05:54,590
+لي ال example رقم تلاتة مثال
+
+61
+00:05:54,590 --> 00:05:56,830
+رقم تلاتة بيقول simply
+
+62
+00:06:11,860 --> 00:06:18,980
+بسيط لي كل من الصيغة التالية نمر ايه؟ بدنتان
+
+63
+00:06:18,980 --> 00:06:25,360
+لكوساين انفرس X على تلاتة
+
+64
+00:06:43,600 --> 00:06:47,640
+لاحظ إن هذا السؤال شبيه بالسؤال اللي فوق، بس
+
+65
+00:06:47,640 --> 00:06:52,700
+الفارق بينهم. هذه قيمة محددة، لكن هذه ما هياش قيمة
+
+66
+00:06:52,700 --> 00:06:56,760
+محددة. X على تلاتة بيكون محصورة بين سالب واحد
+
+67
+00:06:56,760 --> 00:07:02,000
+وواحد يعني X محصورة بين سالب تلاتة وتلاتة. بدنا
+
+68
+00:07:02,000 --> 00:07:06,820
+نعرف قداش القيمة الحقيقية لهذا المقدار.يعني القيمة
+
+69
+00:07:06,820 --> 00:07:09,420
+الحقيقية المطلوب إيجادها ببنان 8
+
+70
+00:07:15,730 --> 00:07:19,470
+يبقى التكتيك اللي يتبعه مثل التكتيك اللي اتبعناها
+
+71
+00:07:19,470 --> 00:07:24,550
+لحل المسألة اللي فوق يبقى بالداخل اقول له افترض ان
+
+72
+00:07:24,550 --> 00:07:29,210
+θ تساوي cos inverse x على 3
+
+73
+00:07:33,240 --> 00:07:40,440
+أثرني بـcos على الطرفين بصير cos θ يساوي x على 3
+
+74
+00:07:40,440 --> 00:07:47,440
+بعد ذلك تعمل مثلث قائم الزاوية بهذا الشكل و تقول
+
+75
+00:07:47,440 --> 00:07:52,580
+هذا الزاوية θ هو أي زاوية القائمةجيب التمام
+
+76
+00:07:52,580 --> 00:08:00,300
+يساومان المجاور على الوطر، إذا المجاور هو X والوطر
+
+77
+00:08:00,300 --> 00:08:07,020
+هو مام تلاتة، إذا بقدر أجيب الدولة تالتة طبقا
+
+78
+00:08:07,020 --> 00:08:14,930
+لنظرية فيثا غورت تسعة ناقص X تربيةاذا أصبحت المثال
+
+79
+00:08:14,930 --> 00:08:23,390
+اللي عندي tan ل cosine inverse x على 3 بدي ساعتان
+
+80
+00:08:23,390 --> 00:08:28,770
+ثيتالأن الشلفة هذه كلها وحطيها في بينها مين؟ ثيتا
+
+81
+00:08:28,770 --> 00:08:34,090
+لأن ثيتا واضح عندي هي من خلال المثلة الظل يساوي
+
+82
+00:08:34,090 --> 00:08:39,950
+المقابل على المجاور يبقى هذا الكلام يساوي الجدرى
+
+83
+00:08:39,950 --> 00:08:45,510
+التربية لتسعة ناقص X تربية على X هذه هي القيمة
+
+84
+00:08:45,510 --> 00:08:50,510
+الحقيقية لمين؟للمقدار اللي عندنا يبقى اتخلصنا من
+
+85
+00:08:50,510 --> 00:08:57,890
+هذه الصيرة وحطناها بدلة ال X فكانت على شكل الجدر
+
+86
+00:08:57,890 --> 00:09:06,350
+التربية لتسعة نقص X تربية كله على X خد نمرة B نمرة
+
+87
+00:09:06,350 --> 00:09:15,910
+B بدي six تربيع لمين؟ لكتان inverse Xبدي أعرف كده
+
+88
+00:09:15,910 --> 00:09:20,550
+الصيغة لإن هذه برضه، برضه بنفس التفتيك اللي اتجه
+
+89
+00:09:20,550 --> 00:09:28,880
+في النقطة A، بدأت أقول الحل كالتاليLet θ مثلا
+
+90
+00:09:28,880 --> 00:09:37,020
+تساوي كتان inverse x أثر على الطرفين بنين بالكتان
+
+91
+00:09:37,020 --> 00:09:45,500
+بيصير عندنا كتان ثيتا تساوي x أروح أرسم المثلث
+
+92
+00:09:48,650 --> 00:09:53,950
+هذا الزاوية ثيتا وهذا المثلث القائم الزاوية كتام
+
+93
+00:09:53,950 --> 00:09:59,990
+يساوي المجاور على المقابل يبقى المجاور هو x
+
+94
+00:09:59,990 --> 00:10:06,750
+والمقابل 1 لأن هذا باعتبارها x على 1 يبقى الضالة
+
+95
+00:10:06,750 --> 00:10:13,160
+التالت بدي ساوي x تربيها زائد 1 تحت الجدرالتربية
+
+96
+00:10:13,160 --> 00:10:20,140
+تبقى لنظرية فيثا غورف يبقى أصبحت المسألة سيك تربية
+
+97
+00:10:20,140 --> 00:10:28,400
+لكوتان inverse x يساوي سيك تربية ثيتاهذا الكلام
+
+98
+00:10:28,400 --> 00:10:33,400
+بده يساوي.الان بده نجي الى six theta هي الوطر على
+
+99
+00:10:33,400 --> 00:10:39,080
+مين؟ على المجاور لإنها مقنوبة ال cosine يبقى الوطر
+
+100
+00:10:39,080 --> 00:10:43,900
+هو الجدر التربية إلى x تربية زائد واحد والمجاور
+
+101
+00:10:43,900 --> 00:10:50,920
+مين؟ والمجاور هو xهذه سك تربية إذا المقدار هذا كله
+
+102
+00:10:50,920 --> 00:10:56,480
+بيصير تربية يبقى النتيجة X تربية زائد واحد عالميا
+
+103
+00:10:56,480 --> 00:11:04,100
+على X تربية هذه القيمة الحقيقية لهذا المقدار ناخد
+
+104
+00:11:04,100 --> 00:11:13,160
+كمان نقطة نمرة Cنمرسي بيقول لي بدي cosine للإتنين
+
+105
+00:11:13,160 --> 00:11:22,880
+sin inverse x زائد اتنين في أربعة مرفوعة للأس
+
+106
+00:11:22,880 --> 00:11:31,040
+لغارت من ال X للأساس اتنين طبعا
+
+107
+00:11:31,040 --> 00:11:40,080
+واضح؟ قدرنا النقطة الأولىبمين؟ بتان لكتان انفرس زي
+
+108
+00:11:40,080 --> 00:11:44,680
+العادية أخدنا مربع النسبة المثلثية ال sector B
+
+109
+00:11:44,680 --> 00:11:51,120
+لكتان انفرس هذا لأ ربطنا القديم بالجديد روحنا
+
+110
+00:11:51,120 --> 00:11:55,560
+ربطنا ال section سبعة تلاتة اللي هو ال general
+
+111
+00:11:55,560 --> 00:12:01,990
+exponential function و ال generalلغرتم معناه مع ال
+
+112
+00:12:01,990 --> 00:12:06,870
+cos لنسبة مثلثية ناهية عن أن هذا الجزء هو cos
+
+113
+00:12:06,870 --> 00:12:11,830
+لإتنين sin inverse وليس sin inverse يعني برضه في
+
+114
+00:12:11,830 --> 00:12:18,010
+فكرة شوية يبقى هذا السؤال ممكن لو شوفت الامتحانات
+
+115
+00:12:18,010 --> 00:12:24,280
+السابقة قد تجد مشابه له في الامتحانات السابقةإذا
+
+116
+00:12:24,280 --> 00:12:28,940
+أنا عند جزئين بدي أحاول أبسط كل جزء من هذه الأجزاء
+
+117
+00:12:28,940 --> 00:12:34,600
+على حدى و أحسب بالاخر قيمة هذا المقدار إذا لو
+
+118
+00:12:34,600 --> 00:12:40,080
+جيتلي هذا المقدار بقدر أكتبه على الشكل التالي بدي
+
+119
+00:12:40,080 --> 00:12:47,180
+أقوله افترض ان θ تساوي sin inverse x تاخدش اتنين
+
+120
+00:12:47,180 --> 00:12:52,980
+sin inverse خدلي sin inverse أسلك في الشغليبقى اثر
+
+121
+00:12:52,980 --> 00:12:58,660
+على الطرفين بصير صين صين ثيتا يساوي قداشر يساوي
+
+122
+00:12:58,660 --> 00:12:58,960
+اكس
+
+123
+00:13:09,580 --> 00:13:15,080
+هو هذه الزاوية ثيتا وهو هذه الزاوية القائمة الصين
+
+124
+00:13:15,080 --> 00:13:20,280
+يسوى المقابل على مين على الوطر لأن هذه باعتبار X
+
+125
+00:13:20,280 --> 00:13:25,880
+على واحد يبقى المقابل X والوطر واحد والضلة التالت
+
+126
+00:13:25,880 --> 00:13:30,660
+الجذر التربيه على واحدماقص اكس تربية تبقى لنظرية
+
+127
+00:13:30,660 --> 00:13:35,840
+فيثا غوث إذا أصبحت المسألة اللي عندي هذه cosine
+
+128
+00:13:35,840 --> 00:13:45,260
+اتنين ثيتا شكل اللي قعدنا على زائد اتنين فيههذه
+
+129
+00:13:45,260 --> 00:13:49,060
+اتنين وهذه اربعة لو كانت هذه اتنين اللي كان قصتنا
+
+130
+00:13:49,060 --> 00:13:53,660
+محلولة وسهلة لكن الأربعة هذه بقدر اكتبها بدلالة
+
+131
+00:13:53,660 --> 00:14:01,480
+اتنين اللي هي اتنين تربيع يبقى هذا اتنين تربيع هذا
+
+132
+00:14:01,480 --> 00:14:06,940
+اص مركب يبقى بدورب في ال log يبقى اتنين logarithm
+
+133
+00:14:06,940 --> 00:14:16,010
+X للأساس اتنين بهذا الشكلطب انا بدرساه انا ماعنديش
+
+134
+00:14:16,010 --> 00:14:20,070
+هنا اتنين ثيتا، انا عندي ثيتا واحدة لكن بقدر اكتب
+
+135
+00:14:20,070 --> 00:14:26,610
+cosine اتنين ثيتا بدلالة ثيتا طبعا لو رجعنا
+
+136
+00:14:26,610 --> 00:14:31,360
+بالذاكرة الى calculus A section واحد تلاتةقصين
+
+137
+00:14:31,360 --> 00:14:35,780
+اتنين ثيتا لها كم صيغة؟ ثلاث صيغة. الصيغة الأولى
+
+138
+00:14:35,780 --> 00:14:40,440
+قصين تربية ثيتا نقص ثين تربية ثيتا. الصيغة التانية
+
+139
+00:14:40,440 --> 00:14:44,140
+اتنين قصين تربية ثيتا نقص واحد. الصيغة التالتة
+
+140
+00:14:44,140 --> 00:14:48,920
+واحد نقص اتنين ثين تربية ثيتا.حط أي صيغة من الصيغة
+
+141
+00:14:48,920 --> 00:14:53,250
+التلاتةوامشي واتوكل على الله بكون انتقلت من cosine
+
+142
+00:14:53,250 --> 00:14:57,910
+إتنين ثيتا إلى cosine ثيتا أو cosine ثيتا و sine
+
+143
+00:14:57,910 --> 00:15:03,430
+ثيتا فمثلا لو أخدنا الصيغة الأولى بصير هذه cosine
+
+144
+00:15:03,430 --> 00:15:12,700
+تربيع ثيتا اللي هو ناقص sine تربيع ثيتاإتنين في
+
+145
+00:15:12,700 --> 00:15:18,960
+هذه اتنين هذا لو جينا الرقم موجود قبل اللغتين يبقى
+
+146
+00:15:18,960 --> 00:15:25,520
+بدخل جوا اللغتين كأس للمقدار X يبقى بصير اتنين أس
+
+147
+00:15:25,520 --> 00:15:34,990
+لك X تربيع للأساس اتنينويساوي نجي لقصين ثيتا الآن
+
+148
+00:15:34,990 --> 00:15:40,970
+بطل على المثلث القصين يساوي المجاور على الوطر يبقى
+
+149
+00:15:40,970 --> 00:15:46,310
+الجذر التربيعي لواحد ناقص x تربيع على واحد لكل
+
+150
+00:15:46,310 --> 00:15:54,070
+تربيع نجي لصين تربيع المقابل على الوطر يبقى x على
+
+151
+00:15:54,070 --> 00:16:02,430
+واحد تربيع يبقى لكل تربيعأتنين هذا الأساس اتنين هو
+
+152
+00:16:02,430 --> 00:16:06,630
+هذا الأساس اتنين يبقى داشور يقول عندي X تربية يبقى
+
+153
+00:16:06,630 --> 00:16:11,210
+داشور يقول عندي اتنين X تربية يبقى المقبر بين
+
+154
+00:16:11,210 --> 00:16:16,540
+القوسين هو X تربية فقط لا غيرلو جينا ردانا يبقى
+
+155
+00:16:16,540 --> 00:16:21,400
+هيطيروا الجذر واحد ناقص X تربية والتاني ناقص X
+
+156
+00:16:21,400 --> 00:16:26,640
+تربية وزائد اتنين X تربية إذا النتيجة يساوي 1000
+
+157
+00:16:26,640 --> 00:16:34,160
+يساوي واحد صحيح يبقى هيبسطنا المقدار وطلعنا بواحد
+
+158
+00:16:34,160 --> 00:16:41,440
+صحيح وربطنا بهذا السؤال section 7-6 بsection 7-3
+
+159
+00:16:41,440 --> 00:16:44,120
+بسؤال واحد
+
+160
+00:16:48,970 --> 00:16:55,310
+فهذا كان المثال رقم تلاتة بناروح للمثال رقم أربعة
+
+161
+00:16:55,310 --> 00:17:06,110
+مثال رقم أربعة بيقول solve for x solve for x حل
+
+162
+00:17:06,110 --> 00:17:14,370
+المعادلة بالنسبة ل x لأن x ناقص ال E بدي ساوي E أس
+
+163
+00:17:14,370 --> 00:17:24,060
+ناقص ثلاثة في لن ال Xفي الـ X أُس خمسة ناقص تان
+
+164
+00:17:24,060 --> 00:17:32,680
+تربيع لسك Inverse X جيبنا
+
+165
+00:17:32,680 --> 00:17:37,240
+هذا السؤال في إحدى الامتحانات وقعدنا بجيبه لك الآن
+
+166
+00:17:37,240 --> 00:17:45,920
+كمثال انحل وشوف كيف بنحل هذا المثال هل
+
+167
+00:17:45,920 --> 00:17:47,100
+كل الكلام خلاص؟
+
+168
+00:18:01,200 --> 00:18:08,020
+طب ارجع الأسئلة هنا solution لما يقول ي solve for
+
+169
+00:18:08,020 --> 00:18:15,020
+x يعني بده قداش القيمة العددية للمتغير x التي تحقق
+
+170
+00:18:15,020 --> 00:18:21,550
+هذه المعادلةموجود عندي هنا لن X ناقص لن E، إذا
+
+171
+00:18:21,550 --> 00:18:32,770
+بقدر أقول لن X ناقص لن Eغلط؟ ايوة غلط يعني طب اياك
+
+172
+00:18:32,770 --> 00:18:37,470
+و ثم اياك واحد يعملها هذا انا بنبغى و رغم ذلك لو
+
+173
+00:18:37,470 --> 00:18:40,830
+وجدتك في الامتحان هلاجي كذا واحد عملها خليني
+
+174
+00:18:40,830 --> 00:18:44,510
+متواضع هلاجي الرابع خمسة و عشرين في المية يعملها
+
+175
+00:18:44,510 --> 00:18:49,190
+بأكد عليك مرة تانية و بقولك اللي لا تدخل على جمع
+
+176
+00:18:49,190 --> 00:18:53,930
+ولا تدخل على طرحبارفق قسمًا عاماشي، بس جامعة و طرح
+
+177
+00:18:53,930 --> 00:18:57,430
+لا، يبقى هذا بيجردش يعمل فيها ولا حاجة، بيخليها زي
+
+178
+00:18:57,430 --> 00:19:03,370
+ما إيه، يبقى عندنا هنا إيش؟ هذا ال N X نقص الإيه
+
+179
+00:19:03,370 --> 00:19:07,150
+كما هي، نجي نشوف حتى لا بنقدر نشتغل فيهم ولا لا
+
+180
+00:19:10,600 --> 00:19:15,740
+يبقى الأس هذا بقدر أخليه لمين؟ للإكس يبقى بصير
+
+181
+00:19:15,740 --> 00:19:23,480
+عندي E أس لين إكس أس سالب تلاتة شكل هذا في مين؟ في
+
+182
+00:19:23,480 --> 00:19:32,210
+إكس أس خمسة زائد تام تربية شو رأيك هذا؟كيف؟ ناقص
+
+183
+00:19:32,210 --> 00:19:37,870
+ناقص نعم ناقص هذا بدي احط اللي بين قسيان ثيتا يبقى
+
+184
+00:19:37,870 --> 00:19:42,750
+بقى كما قلت في الهامش هي الهامش ثيتا تساوي سك
+
+185
+00:19:42,750 --> 00:19:49,970
+inverse X يبقى سك ثيتا بدي يساوي X واروح نرسمله من
+
+186
+00:19:49,970 --> 00:19:54,470
+المثلث بالشكل اللي عندنا هذا هاي المثلث القائم
+
+187
+00:19:54,470 --> 00:20:01,110
+الزاوية وهي الزاوية ثيتا سك يساوي الوتر علاهعلى
+
+188
+00:20:01,110 --> 00:20:07,290
+مين؟ على المجاور يبقى هذا X وهذا واحد وهذا الجدر
+
+189
+00:20:07,290 --> 00:20:15,950
+التربيهي ل X تربية ناقص واحد طيب هذا بيصير لن X
+
+190
+00:20:15,950 --> 00:20:22,030
+ناقص ال E وسبع ال E لن مع السلامة بيبقى X السالب
+
+191
+00:20:22,030 --> 00:20:28,970
+تلاتة في X الخامسةناقص كان تربيعتي طول يساوي
+
+192
+00:20:28,970 --> 00:20:36,170
+المقابل على المجاور يبقى ناقص الجذر التربيعي ل X
+
+193
+00:20:36,170 --> 00:20:43,410
+تربيع ناقص واحد على واحد لكل تربيع نبسطها هنا بضل
+
+194
+00:20:43,410 --> 00:20:51,770
+قداش X تربيع ناقص هذا هو برضه X تربيع ناقص واحد
+
+195
+00:20:52,430 --> 00:20:58,050
+يبقى ايش اللي حصل انها هذا بده يساوي X ثربيه ناقص
+
+196
+00:20:58,050 --> 00:21:03,630
+X ثربيه زائد واحد يبقى هذا و هذا مع السلامة مضل
+
+197
+00:21:03,630 --> 00:21:11,010
+جداش اذا قامت مسألة الى الشكل التالي لين X ناقص E
+
+198
+00:21:11,010 --> 00:21:15,450
+بده يساوي واحد يبقى المعادلة الكبيرة اللي فوق هذا
+
+199
+00:21:15,450 --> 00:21:20,660
+بسطناها و أصبحت بهذا الشكلالان هذه سهلة جدا تخلص
+
+200
+00:21:20,660 --> 00:21:26,100
+منها و جيب قيمة X يبقى بارفع اتنين ماله كأس للعدد
+
+201
+00:21:26,100 --> 00:21:33,520
+E يبقى E أس لن ال X نقص ال E يبدو يسوى E أس واحد
+
+202
+00:21:33,520 --> 00:21:38,800
+يبقى هذا معناته ان X نقص ال E يبدو يسوى جداش ال E
+
+203
+00:21:38,800 --> 00:21:47,720
+ومنها ال X يسوى اتنين Eيبقى هذا حل المعادلة اللي
+
+204
+00:21:47,720 --> 00:21:55,500
+انا جئنا بها في احدى الامتحانات السابقة طيب لحد
+
+205
+00:21:55,500 --> 00:21:59,860
+هنا شباب انتهينا من النقطة الأولى في الجزء النظري
+
+206
+00:21:59,860 --> 00:22:03,980
+التابع على ال section لسه بقيت نقطتان زي ما قلتلكم
+
+207
+00:22:03,980 --> 00:22:09,340
+المرة الماضية ننتقل الآن إلى النقطة الثانية من هذا
+
+208
+00:22:09,340 --> 00:22:11,620
+ال section وهي sum
+
+209
+00:22:18,070 --> 00:22:26,370
+بعض الواقعات التي تتعلق بالإنفار
+
+210
+00:22:26,370 --> 00:22:30,690
+تريجونومتريك
+
+211
+00:22:30,690 --> 00:22:39,570
+تريجونومتريك
+
+212
+00:22:45,020 --> 00:22:52,560
+بعض المتطابقات المجتملة على معكس الدوال المثلثية
+
+213
+00:22:52,560 --> 00:22:58,260
+بدا أخد أول مجموعة من المتطابقات المجموعة الأولى
+
+214
+00:22:58,260 --> 00:23:06,460
+اللي هي sin inverse x زائد cosine inverse x يساوي
+
+215
+00:23:06,460 --> 00:23:12,840
+pi على اتنين وبشرط ان ال absolute value X أقل من
+
+216
+00:23:12,840 --> 00:23:17,620
+او تساوي واحداللي هو domain الـ sine inverse و
+
+217
+00:23:17,620 --> 00:23:25,220
+domain من ال cosine inverse هذا نمرة A نمرة B tan
+
+218
+00:23:25,220 --> 00:23:33,200
+inverse X زائد كتان inverse X بدي يسوى باي على
+
+219
+00:23:33,200 --> 00:23:41,400
+اتنين والحكي هذا لجميع قيم X بلاستي اتنين نمرة C
+
+220
+00:24:06,230 --> 00:24:11,610
+السؤال هو من أين لك هذا البرو
+
+221
+00:24:14,980 --> 00:24:21,500
+بنروح نثبت صحة المتطابقات التماته هذه طبعا هذه
+
+222
+00:24:21,500 --> 00:24:26,780
+very important ده بنجيب هنا امتعانات برضه كتير نجي
+
+223
+00:24:26,780 --> 00:24:30,680
+للمتطابقه الأولى اللي هي sin inverse x زائد cosine
+
+224
+00:24:30,680 --> 00:24:36,380
+inverse x ساوي pi على اتنين لو جيت تخيلت عندي ان
+
+225
+00:24:36,380 --> 00:24:39,800
+في دائرة دائرة الوحدة
+
+226
+00:24:42,500 --> 00:24:50,060
+دائرة الوحدة وعندي محاور بالشكل هذا محور X ومحور Y
+
+227
+00:24:50,060 --> 00:24:55,160
+واتنين متقاطعين في مركز هذه الدائرة يعني الدائرة
+
+228
+00:24:55,160 --> 00:25:02,320
+مركزها نقطة الأصل و نصف قطرة يساوي واحد صحيحيبقى
+
+229
+00:25:02,320 --> 00:25:07,980
+لو رسمنا نصف القطر يبقى نصف القطر هيكون بالشكل هذا
+
+230
+00:25:07,980 --> 00:25:15,340
+طوله واحد صحيح من هنا هذه سميناها unit circle يبقى
+
+231
+00:25:15,340 --> 00:25:23,880
+هذه unit circle ده
+
+232
+00:25:23,880 --> 00:25:30,490
+قرأت الواحدةطيب لو جينا قولنا النقطة هذه الاحداثي
+
+233
+00:25:30,490 --> 00:25:37,930
+تبعها هو النقطة X وY يبقى وين ال X وين ال Y لبروح
+
+234
+00:25:37,930 --> 00:25:45,440
+من هنا بنزل عمود رأسي بهذا الشكليبقى X هي المسافة
+
+235
+00:25:45,440 --> 00:25:50,840
+هذه من هنا لغاية هنا يقول الجزء المقطوع من محور
+
+236
+00:25:50,840 --> 00:25:57,440
+السيناء Y اللي هي هذه طب حد بيقدر يكتب لي Y بدلالة
+
+237
+00:25:57,440 --> 00:25:57,900
+X
+
+238
+00:26:04,750 --> 00:26:10,530
+الجبل يبقى هذا الجدري التربيهي لمين لو واحد ناقص X
+
+239
+00:26:10,530 --> 00:26:17,570
+تربية تبقى لنظرية في ثقافات طيب تمام شو رأيك هذه
+
+240
+00:26:17,570 --> 00:26:23,570
+90 لو جيت سميت الزاوية هذه Alpha والزاوية هذه Beta
+
+241
+00:26:24,650 --> 00:26:30,030
+كم مجموع Alpha و Beta؟ الـSame يبقى باجي بقول انا
+
+242
+00:26:30,030 --> 00:26:35,070
+عند ال Alpha زائدي ال Beta بدني أساوي مين؟ باي على
+
+243
+00:26:35,070 --> 00:26:41,590
+اتنين خلّي هذه المعلومة اللي عندك يمكن تلزمني طيب
+
+244
+00:26:41,590 --> 00:26:48,310
+لو جيت الآن للزاوية Alpha بدي أخد جيب تمام الزاوية
+
+245
+00:26:48,310 --> 00:26:56,990
+Alpha Cos الزاوية Alphaالكوصين يساوي المجاور على
+
+246
+00:26:56,990 --> 00:27:03,830
+الوطن يبقى X صحيح ولا لا؟ بدي أجيب ال Alpha جداش
+
+247
+00:27:03,830 --> 00:27:09,030
+تساوي الجملة المكافئة لهذه الجملة هي Alpha يساوي
+
+248
+00:27:09,030 --> 00:27:16,390
+cosine inverse X طيب تمام بتروح للزاوية Beta لوحة
+
+249
+00:27:16,390 --> 00:27:23,500
+Sin الزاوية Betaبتساوي المقابل على الوطن يبقى X
+
+250
+00:27:23,500 --> 00:27:32,220
+على واحد له جد X يبقى Beta تساوي Sin inverse X لو
+
+251
+00:27:32,220 --> 00:27:37,020
+جينا جمعنا الاتنين هدول، ايش بدي يصير عندي؟ بدي
+
+252
+00:27:37,020 --> 00:27:43,380
+يصير عندي Cos inverse X زائد Sin inverse X بدي
+
+253
+00:27:43,380 --> 00:27:49,590
+ساوي Alpha زائد Betaطب α زاد ال b تبقى جداش ممتاز
+
+254
+00:27:49,590 --> 00:27:56,870
+جدا يبقى هذا يعطيك ال cosine inverse x زاد sin
+
+255
+00:27:56,870 --> 00:28:03,050
+inverse x يسوى جداش بقى على اتنين نصف القطر هو
+
+256
+00:28:03,050 --> 00:28:06,890
+جداشيعني X لمّا رب يحط فيها الفرقة في السوري
+
+257
+00:28:06,890 --> 00:28:12,930
+الجداشي، is an absolute value ل X أقل من أو يسوى
+
+258
+00:28:12,930 --> 00:28:20,010
+من الواحد، أظن هو هو المطلوب الأول تمام، المطلوب
+
+259
+00:28:20,010 --> 00:28:26,510
+التاني، يبقى هذه نمرأة إيه؟ بالده دي لا نمرأ بيه،
+
+260
+00:28:26,510 --> 00:28:31,500
+نمرأ بيه؟بدي اثبت ان تان انفرس اكس زائد كتان انفرس
+
+261
+00:28:31,500 --> 00:28:36,700
+اكس بيساوي جداش بيعتنوا هذا for all x بيلاستيطنار
+
+262
+00:28:36,700 --> 00:28:41,260
+بنقوله بسيطة نفس الكلام بيبقى جديد لو جيت قلت
+
+263
+00:28:41,260 --> 00:28:47,520
+بالله تان الف جداش يساوي المقابل على المجاور يبقى
+
+264
+00:28:47,520 --> 00:28:53,710
+الجذر التربيه الاحد ناقص x تربيه على xيبقى هذا
+
+265
+00:28:53,710 --> 00:29:01,610
+الكلام يعطيك أن Alpha تساوي تان Inverse لجدر
+
+266
+00:29:01,610 --> 00:29:06,850
+التربية إلى واحد ناقص X تربية على Xما رأيك اللي
+
+267
+00:29:06,850 --> 00:29:13,670
+بين قصين كله بدي أسميه theta يبقى هذا tan inverse
+
+268
+00:29:13,670 --> 00:29:20,890
+theta و ال theta هذه هي عبارة عن الجذر التربيهي لو
+
+269
+00:29:20,890 --> 00:29:29,630
+أحد ناقص x تربيع على x يبقى أصبح تاندي alpha تساوي
+
+270
+00:29:29,630 --> 00:29:37,330
+tan inverse theta طب خدلي كتان betaاللي اللي فوق
+
+271
+00:29:37,330 --> 00:29:46,230
+يساوي. الكتان يساوي مان؟ مقلب التان. مظبوط؟ يبقى
+
+272
+00:29:46,230 --> 00:29:52,080
+المجاور على المقابل. المجاور لبيته مين؟الجذر
+
+273
+00:29:52,080 --> 00:29:56,520
+التربية الواحد ناقص X تربية يبقى الجذر التربية
+
+274
+00:29:56,520 --> 00:30:02,420
+الواحد ناقص X تربية المجاري اللي هو ماين المقابل
+
+275
+00:30:02,420 --> 00:30:07,120
+اللي هو X و الله ممتاز بنفس القيمة اللي فوق يبقى
+
+276
+00:30:07,120 --> 00:30:12,920
+هذا بده يعطيك ان بيتا تساوي كتان inverse الجذر
+
+277
+00:30:12,920 --> 00:30:19,900
+التربية الواحد ناقص X تربية على X كتان inverse ثتا
+
+278
+00:30:21,080 --> 00:30:26,760
+طب من الاتنين هدول اللي وجد جماعة تان انفرث ثيتا
+
+279
+00:30:26,760 --> 00:30:36,100
+زائد كتان انفرث ثيتا شوف كده اش بده يساوي اش بده
+
+280
+00:30:36,100 --> 00:30:41,020
+يساوي كده اش الف زائد بيتا اللي هو باي على اتنين
+
+281
+00:30:41,020 --> 00:30:49,530
+تمام تمام ثيتا هذهعندي عليها قيود اي رمز اخترته
+
+282
+00:30:49,530 --> 00:30:54,470
+يساوي هذا المقدار اذا ممكن اقول تان انفرستي ت زايد
+
+283
+00:30:54,470 --> 00:30:58,190
+كتان انفرستي تبدو ساوي باية على اتنين او تان
+
+284
+00:30:58,190 --> 00:31:02,790
+انفرستي زايد كتان انفرستي زايد كتان انفرستي زايد
+
+285
+00:31:02,790 --> 00:31:05,190
+كتان انفرستي زايد كتان انفرستي زايد كتان انفرستي
+
+286
+00:31:05,190 --> 00:31:05,810
+زايد كتان انفرستي زايد كتان انفرستي زايد كتان
+
+287
+00:31:05,810 --> 00:31:09,170
+انفرستي زايد كتان انفرستي زايد كتان انفرستيبقدر
+
+288
+00:31:09,170 --> 00:31:17,930
+اقول هذا لتان inverse x زاد كتان inverse x بده
+
+289
+00:31:17,930 --> 00:31:23,750
+يساوي ال by على اتنين والكلام هذا صحيح for all x
+
+290
+00:31:23,750 --> 00:31:28,970
+لأن ال domain تبع كل منهما من سالب infinity إلى
+
+291
+00:31:28,970 --> 00:31:33,550
+infinity نمرى c similarly
+
+292
+00:31:36,210 --> 00:31:45,370
+as a and lb يعني ايش بدك تبدأ؟ تبدأ بالسك inverse
+
+293
+00:31:45,370 --> 00:31:50,430
+X بدك تبدأ بالألف يسوى السك inverse X يبقى تاخد
+
+294
+00:31:50,430 --> 00:31:56,750
+السك للطرفين بسك Alpha يسوى X و هكذا طيب بدنا نيجي
+
+295
+00:31:56,750 --> 00:32:03,860
+للنقطة الثانية النقطة الثانية يا شبابمن معكوس
+
+296
+00:32:03,860 --> 00:32:14,340
+الدول المثلثية sign inverse لسلب x بده يساوي سالب
+
+297
+00:32:14,340 --> 00:32:25,130
+sign inverse x and اللي هو كتانوليس كتان تان تان
+
+298
+00:32:25,130 --> 00:32:34,290
+inverse لسلب X يسوي سلب تان inverse X السبب
+
+299
+00:32:34,290 --> 00:32:40,430
+because the
+
+300
+00:32:40,430 --> 00:32:44,910
+graph of
+
+301
+00:32:44,910 --> 00:32:51,110
+sine inverse X and
+
+302
+00:32:52,230 --> 00:33:04,190
+Ten inverse X are symmetric about
+
+303
+00:33:04,190 --> 00:33:12,790
+the origin
+
+304
+00:33:14,020 --> 00:33:23,020
+هذا اللي هو قد يعطيك انه sin inverse x and tan
+
+305
+00:33:23,020 --> 00:33:29,480
+inverse x are odd functions
+
+306
+00:33:49,000 --> 00:33:59,480
+نروح للنقطة التالتة النقطة
+
+307
+00:33:59,480 --> 00:34:10,000
+التالتة نمرة a six inverse x يساوي cosine inverse
+
+308
+00:34:10,000 --> 00:34:17,640
+واحد على x والx greater than or equal to one نمرة
+
+309
+00:34:17,640 --> 00:34:25,470
+bcosecant inverse x يساوي sin inverse واحد على x
+
+310
+00:34:25,470 --> 00:34:32,650
+والx greater than or equal to one c cotan inverse
+
+311
+00:34:32,650 --> 00:34:40,950
+x يساوي tan inverse واحد على x والx greater than
+
+312
+00:34:40,950 --> 00:34:41,830
+zero
+
+313
+00:34:51,030 --> 00:34:56,070
+بتبارك ان واحدة بس من التلاتة واتنين زيها حرفيا
+
+314
+00:34:56,070 --> 00:35:01,710
+طالع ليه ان ال six inverse x يبقى ال x أكبر من من
+
+315
+00:35:01,710 --> 00:35:06,810
+الواحد طب هل هات exist لو كانت x أكبر من واحد يبقى
+
+316
+00:35:06,810 --> 00:35:12,490
+ده كاسير أقل من الواحد الصحيح إذا فعلا داخل domain
+
+317
+00:35:12,490 --> 00:35:17,890
+من ال cosine inverse وهكذا بالنسبة للي بعد هو ادل
+
+318
+00:35:17,890 --> 00:35:22,660
+كل ال x اللي أكبر من 100 من 0أفترض أننا نبرهن
+
+319
+00:35:22,660 --> 00:35:27,300
+النقطة A التكتيك اللي علينا تتبعه عند A هو اللي
+
+320
+00:35:27,300 --> 00:35:31,660
+علينا تتبعه عند B هو اللي علينا تتبعه عند C حرفيا
+
+321
+00:35:31,660 --> 00:35:43,180
+الان بداجة جلد θ تساوي sec inverse xإذا قدرت أثبت
+
+322
+00:35:43,180 --> 00:35:48,620
+أن ثيتا هي cosine inverse اك واحد علي اكس فبتم
+
+323
+00:35:48,620 --> 00:35:58,060
+المقلوب والاكس greater than or equal to one ثم اثر
+
+324
+00:35:58,060 --> 00:36:04,600
+على الطرفين بالسك ليه بقاش بسيط سك ثيتا بده يساوي
+
+325
+00:36:04,600 --> 00:36:12,160
+كده؟ بده يساوي اكس السك مقلوب مين؟الكو ساين يبقى
+
+326
+00:36:12,160 --> 00:36:19,360
+بصير ان من واحد على كو ساين ثيتا يسوى جدول X اجلب
+
+327
+00:36:19,360 --> 00:36:27,750
+يبقى بصير من كو ساين ثيتا يسوى من واحد على Xيبقى
+
+328
+00:36:27,750 --> 00:36:34,490
+هنا بدنا ثيتا يبقى ثيتا تساوي cosine inverse واحد
+
+329
+00:36:34,490 --> 00:36:39,570
+على X أظن هو المطلوب يبقى أخدنا ثيتا بالسكت
+
+330
+00:36:39,570 --> 00:36:45,250
+inverse X أثبتنا أن ثيتا تساوي cosine inverse واحد
+
+331
+00:36:45,250 --> 00:36:52,860
+على X يبقى بناء عليه أصبحسيك انفرس X يساوي كوصين
+
+332
+00:36:52,860 --> 00:36:58,880
+انفرس واحد علي X و X is greater than or equal to
+
+333
+00:36:58,880 --> 00:37:09,360
+one يبقى B and C similarly as
+
+334
+00:37:09,360 --> 00:37:14,160
+A هذا النقطة التالتة بدنا نروح للنقطة الرابعة
+
+335
+00:37:16,390 --> 00:37:22,710
+النقطة الرابعة اللي هي ايه اللي هي cosine inverse
+
+336
+00:37:22,710 --> 00:37:35,550
+لسلب x يساوي by ناقص cosine inverse x وال
+
+337
+00:37:35,550 --> 00:37:42,950
+absolute value ل x اقل من او يساوي واحدعندك كمال
+
+338
+00:37:42,950 --> 00:37:52,310
+سك انفرس لسالف X يساوي بالناقص سك انفرس X والقيم
+
+339
+00:37:52,310 --> 00:38:04,450
+الأكبر لل X مالها هو أكبر من أو تساوي الواحد برضه
+
+340
+00:38:04,450 --> 00:38:05,250
+بدون برهن
+
+341
+00:38:10,590 --> 00:38:19,030
+هذه نمرة A وهذه نمرة B نبحث عن نمرة Aخلّيني برأيك،
+
+342
+00:38:19,030 --> 00:38:25,930
+سنرى نمرة ايه باستخدام نمرة ايه من المقطة الأولى
+
+343
+00:38:25,930 --> 00:38:30,890
+اللي هو cos inverse x زي sin inverse x ساوي باي
+
+344
+00:38:30,890 --> 00:38:37,590
+على اتنين، بس ايش بده يبدل؟ كل x بمين؟ بساقل باكس،
+
+345
+00:38:37,590 --> 00:38:43,780
+تمام؟ يبقى بالدهجة اقول له since بما انكو ساين
+
+346
+00:38:43,780 --> 00:38:52,140
+انفرس X زائد ساين انفرس X بديه ساوي باي على اتنين
+
+347
+00:38:52,140 --> 00:38:59,220
+وال absolute value لل X اقل من او تساوي الواحد
+
+348
+00:39:24,460 --> 00:39:31,180
+طلب منك أن تخلص من كل X وانتقل إلى مكانها وهو سالب
+
+349
+00:39:31,180 --> 00:39:38,100
+X ونرى ماذا سيحدث هنا ماذا سيحدث هنا كوساين انفرس
+
+350
+00:39:38,100 --> 00:39:45,340
+لسالب X زائد ساين انفرس لسالب X يجب أن يساوي باي
+
+351
+00:39:45,340 --> 00:39:50,660
+على اتنين وبالشرب انه absolute value لسالب X سيكون
+
+352
+00:39:50,660 --> 00:39:56,490
+كم من خواصل ال absolute valueabsolute value للسالب
+
+353
+00:39:56,490 --> 00:40:02,370
+x هي absolute value للإكس absolute value للسالب
+
+354
+00:40:02,370 --> 00:40:05,970
+تلاتة هي absolute value للتلاتة absolute value
+
+355
+00:40:05,970 --> 00:40:10,630
+للناقص نص هي absolute value للنص كل real number
+
+356
+00:40:10,630 --> 00:40:15,190
+بلا استثناء احدى خاص لل absolute value يبدأ تكون
+
+357
+00:40:15,190 --> 00:40:21,740
+اقل من او يسوى منالواحد تمام التمام طب ايش رأيك
+
+358
+00:40:21,740 --> 00:40:26,060
+احنا حصلنا على هذه الآن بالشكل اللي قدامنا هذا
+
+359
+00:40:26,060 --> 00:40:31,960
+احنا ايش بدنا بدنا هذه بدلالة cosine inverse طب
+
+360
+00:40:31,960 --> 00:40:35,920
+هذه من النقطة التانية مش عبارة عن سالب sine
+
+361
+00:40:35,920 --> 00:40:41,970
+inverse xيبقى صرتها دي ايه؟ اللي هي cosine inverse
+
+362
+00:40:41,970 --> 00:40:49,070
+لسالب x سالب sin inverse x بده يسوى باي على اتنين
+
+363
+00:40:49,070 --> 00:40:58,130
+او cosine inverse لسالب x يسوى باي على اتنين زاد
+
+364
+00:40:58,130 --> 00:41:08,240
+sin inverse x طلعلنا النقطة الأولىلو sin inverse x
+
+365
+00:41:08,240 --> 00:41:12,580
+زاد cos inverse x يساوي بي على اتنين إذا sin
+
+366
+00:41:12,580 --> 00:41:18,640
+inverse x بقدر اكتب بي على اتنين ناقص cos inverse
+
+367
+00:41:18,640 --> 00:41:25,400
+x يبقى هذه بدأت تساوي بي على اتنين اللي برا زادهذه
+
+368
+00:41:25,400 --> 00:41:32,960
+هاها من النقطة الأولى part one a باي على اتنين
+
+369
+00:41:32,960 --> 00:41:42,740
+ناقص cosine inverse x يبقى from واحد part a من
+
+370
+00:41:42,740 --> 00:41:47,840
+النقطة الأولىشيلنا ال sign inverse و كتبنا عليها
+
+371
+00:41:47,840 --> 00:41:52,540
+باي ناقص cosine inverse X يبقى بناء عليها أصبحت
+
+372
+00:41:52,540 --> 00:42:00,360
+cosine inverse لسلب X يسوى باي ناقص cosine inverse
+
+373
+00:42:00,360 --> 00:42:07,940
+X وال X هذهها اللي هو أقل من أو تسوى 101 ال
+
+374
+00:42:07,940 --> 00:42:15,390
+absolute value طيب نمر بيه؟بنجي للتانية اللي هي
+
+375
+00:42:15,390 --> 00:42:20,310
+نمرة B. Cos inverse يبقى بناء عليه هل ال cosine
+
+376
+00:42:20,310 --> 00:42:23,610
+odd inverse؟
+
+377
+00:42:28,550 --> 00:42:34,850
+يبقى باجي بقوله اه انا عندي لو بدأت عندك من مين لو
+
+378
+00:42:34,850 --> 00:42:40,090
+جيت قلت هذي لتوصل لها بيبقى نشوف كده هذي بده
+
+379
+00:42:40,090 --> 00:42:49,830
+تعطينا او لو جيت قلت اللي هو بدي اخد انا اللي هو
+
+380
+00:42:49,830 --> 00:42:50,950
+cosine
+
+381
+00:42:53,020 --> 00:43:00,580
+inverse لسلب x يسوي by ناقص cosine inverse x و
+
+382
+00:43:00,580 --> 00:43:04,660
+absolute value x اقل من او يساوي واحد in plus
+
+383
+00:43:04,660 --> 00:43:07,680
+خلوني
+
+384
+00:43:07,680 --> 00:43:13,840
+ابقى كده لو جيت جالبتهم يعني ايه؟ يعني بدي اخد
+
+385
+00:43:13,840 --> 00:43:21,000
+cosine inverse لسلب واحد على x تساوي
+
+386
+00:43:21,670 --> 00:43:32,930
+بالنقص cosine inverse ل 1 على x بشرط Nكم فاندي اكس
+
+387
+00:43:32,930 --> 00:43:37,830
+واشاملتها واحد على اكس هنا absolute value الاكس لو
+
+388
+00:43:37,830 --> 00:43:43,510
+كان اقل من الواحد يبقى هذا بيصير اكبر من الواحد
+
+389
+00:43:43,510 --> 00:43:48,870
+الصحية بالتالي الدالة غير معرفة يبقى الصح اني اقول
+
+390
+00:43:48,870 --> 00:43:54,170
+main absolute value الاكس اكبر من او تساوي واحد
+
+391
+00:43:54,170 --> 00:44:00,990
+مشان تصبح الدالة مالها معرفةلو خلّيتها زي قبل جلبت
+
+392
+00:44:00,990 --> 00:44:06,390
+هدول وما جلبتش وضع عادي، بصير كلامي مش صحيح، تمام؟
+
+393
+00:44:06,390 --> 00:44:10,690
+يبقى هيك مضمونة إنها معرفة، X أكبر من أوي سوى
+
+394
+00:44:10,690 --> 00:44:15,930
+الواحد، يبقى بضمن إن هذا كسر أقل من الواحد الصحيح،
+
+395
+00:44:15,930 --> 00:44:20,050
+ولم ياخد طب تبعه يكون جديدش، واحد وهاكذا بالنسبة
+
+396
+00:44:20,050 --> 00:44:25,530
+لمين؟ على الشمال، فبنرجع ليه تاماتةتلاتة بيقول لي
+
+397
+00:44:25,530 --> 00:44:30,850
+cos inverse واحد علي x هي sec inverse x إذا باجي
+
+398
+00:44:30,850 --> 00:44:39,170
+بيقول له from three we have .. شوف ليه هذا، إيش
+
+399
+00:44:39,170 --> 00:44:42,910
+بصير هذه؟ Sec inverse لسالب x
+
+400
+00:44:45,790 --> 00:44:51,210
+كوصين انفرس واحد على X سك انفرس X يبقى كوصين انفرس
+
+401
+00:44:51,210 --> 00:44:57,370
+سالب واحد على X هي سك انفرس لمن؟ لسالب X بده ساوي
+
+402
+00:44:57,370 --> 00:45:04,970
+بالناقص كوصين انفرس واحد على X هي من؟ بسك انفرس X
+
+403
+00:45:04,970 --> 00:45:11,310
+سك انفرس X سلوى تباع ال X أكبر من أوي سوى الواحد
+
+404
+00:45:11,310 --> 00:45:18,420
+وهو المقلوبيبقى هؤلاء الأربع مصادر تعرفهم مثل اسمك
+
+405
+00:45:18,420 --> 00:45:24,520
+بيجي عليهم أسئلة نبدأ ناخد أمثلة على ذلك يبقى
+
+406
+00:45:24,520 --> 00:45:30,300
+examples يبقى هذا الجزء النظر يا رقم اتنين من هذا
+
+407
+00:45:30,300 --> 00:45:36,960
+ال section السؤال الأول خليك معايا والله ايوة
+
+408
+00:45:40,890 --> 00:45:45,710
+مانتقل جمالك هادر من يقولك اتبع هديك أولا ثم هادي
+
+409
+00:45:45,710 --> 00:45:51,510
+ثانيا اه مش بجيخ على اخر أخليك سايح في الليلة لا
+
+410
+00:45:51,510 --> 00:46:00,270
+صاحبي اتخافش نعرف نحطه سلسلة امتعانات sketch the
+
+411
+00:46:00,270 --> 00:46:08,630
+graph sketch the graph of the following
+
+412
+00:46:11,580 --> 00:46:19,780
+كيرز ارسم لي كل من المنحنيات التالية نمرة a y
+
+413
+00:46:19,780 --> 00:46:31,020
+تساوي cosine inverse لسلب x نمرة b y تساوي اتنين
+
+414
+00:46:31,020 --> 00:46:34,900
+tan inverse لسلب x
+
+415
+00:46:56,820 --> 00:47:02,210
+فانا بارك معانا هناطبعا لو احنا بنرسم لما رسمنا
+
+416
+00:47:02,210 --> 00:47:06,470
+معاكس الدوالة المثلثية رسمنا y تساوي cosine
+
+417
+00:47:06,470 --> 00:47:10,150
+inverse x لكن cosine inverse سالب x ما رسمناش
+
+418
+00:47:10,150 --> 00:47:16,070
+بالمرة تمام؟ إذا بدأنا رسمة الدالة الأولى نمره
+
+419
+00:47:16,070 --> 00:47:19,110
+ايه؟
+
+420
+00:47:19,110 --> 00:47:26,270
+بدنا y تساوي cosine inverse لسالب x لو رجعنا
+
+421
+00:47:26,270 --> 00:47:32,880
+بالذاكرة إلى الوراقوقلنا هذا محور X وهذا محور Y
+
+422
+00:47:32,880 --> 00:47:40,150
+وهذا نقطة الأصل Zالـ cosine inverse لو كان بالموجب
+
+423
+00:47:40,150 --> 00:47:45,950
+فال domain تبعه من عند السالب واحد لغاية من لغاية
+
+424
+00:47:45,950 --> 00:47:50,370
+الواحد و لو جينا و قولنا هذا خط رأسي بالشكل لأن
+
+425
+00:47:50,370 --> 00:47:56,890
+هذا و هذا خط رأسي تاني زيه كويس يبقى و جينا نرسم
+
+426
+00:47:56,890 --> 00:48:05,440
+هذه الدالةالدالة هنا بتجينا باي على اتنين وهنا باي
+
+427
+00:48:05,440 --> 00:48:12,000
+لو رسمنا منحنى ال cosine بيجينا بالشكل هذاهذا
+
+428
+00:48:12,000 --> 00:48:19,020
+مُنحنى cos inverse x هذا هو cos inverse x لكن مش
+
+429
+00:48:19,020 --> 00:48:22,900
+هذا اللي احنا بدناه احنا بدناه cos inverse لمن
+
+430
+00:48:22,900 --> 00:48:31,480
+لسالة x بقول بسيطة لو رجعنا ل calculus aبنقلب
+
+431
+00:48:31,480 --> 00:48:36,400
+الرسمة عبر محور Y، مش هيك اخدناه؟ لو شيلنا كل
+
+432
+00:48:36,400 --> 00:48:40,920
+متغير X وحطينا بمانه سلب X، بتقلب الرسمة تبعتك عبر
+
+433
+00:48:40,920 --> 00:48:44,240
+محور Y اللي على يمينه بده يصير على شماله، و اللي
+
+434
+00:48:44,240 --> 00:48:48,740
+على شماله بده يصير على يمينه، اذا حرسمها لك باللون
+
+435
+00:48:48,740 --> 00:48:53,560
+تاني، هتيجي من عنده النقطة Y هنا، ويجي لك المنحنة
+
+436
+00:48:53,560 --> 00:48:59,920
+بالشكل اللي عندك كذايبقى الخط الأزرق هذا هذا اللي
+
+437
+00:48:59,920 --> 00:49:05,660
+هو cosine inverse لسالف x أجي واحد تاني قال لها
+
+438
+00:49:05,660 --> 00:49:09,060
+أنا بديش أنظر لهذه الطريقة هذه قلت له أيوة قلت له
+
+439
+00:49:09,060 --> 00:49:12,100
+بدي أنظرها بمعلومات calculus بيقول صح والله مظبوط
+
+440
+00:49:12,100 --> 00:49:18,100
+قلت له cosine inverse لسالف x هذه هي by ناقص
+
+441
+00:49:18,100 --> 00:49:23,380
+cosine inverse xقلت له مظبوط جالي انت رسمت cosine
+
+442
+00:49:23,380 --> 00:49:26,880
+inverse X في الخط اللي هي السوداء ده قلت له صحيح
+
+443
+00:49:26,880 --> 00:49:31,560
+اجي جابله ايش؟ اشارت ثالث حسب كرته اللي بتجنب
+
+444
+00:49:31,560 --> 00:49:37,480
+الرسم عبر محور X يبقى هذه اللي كلها فوق بتغسير ت
+
+445
+00:49:38,330 --> 00:49:44,110
+بعد اكشفت إلى أعلى بمقدار، بدأ تعارض كما كانت على
+
+446
+00:49:44,110 --> 00:49:49,070
+الأزرق، يعني ان لو راحت جلبت هذه هاها و صارت
+
+447
+00:49:49,070 --> 00:49:56,110
+الرسمة بالشكل هذاهذا هو الخط المنجب هنا طبعا اللي
+
+448
+00:49:56,110 --> 00:50:00,390
+هو السالف باي وهذه السالف باي على إت جيت لها الرسم
+
+449
+00:50:00,390 --> 00:50:05,710
+عملتلها shift إلى أعلى يبقى فتصيره أثنان فكرت
+
+450
+00:50:05,710 --> 00:50:10,990
+بطريقة هذه و بطريقة هذه سيئا لإتنين أردسين طيب
+
+451
+00:50:10,990 --> 00:50:15,790
+بدنا نيجي لنمرة B نمرة B جيناها مرة في إحدى
+
+452
+00:50:15,790 --> 00:50:20,220
+الامتحاناتالان تان انفرس ماعرف اكس ومجرس تان انفرس
+
+453
+00:50:20,220 --> 00:50:24,140
+تان انفرس اكس ماعرفش لكن هذه ال function اخدناها
+
+454
+00:50:24,140 --> 00:50:29,500
+قبل قليل مجرد يبقى ايش بدنا نعمل يبقى ادي واي
+
+455
+00:50:29,500 --> 00:50:36,820
+تساوي سالي باتنين تان انفرس اكسو نرسم هذا الكلام
+
+456
+00:50:36,820 --> 00:50:43,460
+فنقول هذا محور X وهذا محور Y وهذا نقطة الاصل وهي
+
+457
+00:50:43,460 --> 00:50:51,860
+Zero لو رحت قلت هذا الخط الوهمي لن وهذا التاني هذا
+
+458
+00:50:51,860 --> 00:50:57,670
+سالف باي على اتنين وهذا باي على اتنينو روحنا رسمنا
+
+459
+00:50:57,670 --> 00:51:03,710
+منحنى tan inverse x روحت رسمته في مجة طيب و نزل
+
+460
+00:51:03,710 --> 00:51:10,590
+عندك و أجي بهذا الشكل يبقى هذا رسمت من؟ tan
+
+461
+00:51:10,590 --> 00:51:17,070
+inverse xتعني ان فرسكس اندراج في كم؟ في اتنين يبقى
+
+462
+00:51:17,070 --> 00:51:22,810
+ال range تبعه بيصير جد ال range هذا مرتين يبقى وين
+
+463
+00:51:22,810 --> 00:51:29,850
+بدي اوصل؟ بدي اوصل لهنا لحد ال bye بدي يصير هذا
+
+464
+00:51:29,850 --> 00:51:37,440
+bye و بدي انزل هنا كمان لوين؟ لسالف byeشكلها نادر،
+
+465
+00:51:37,440 --> 00:51:41,680
+طيب، بعدين كان ضرر في إشارة مين؟ سالب، يعني كأنه
+
+466
+00:51:41,680 --> 00:51:45,360
+الرسمة أصبحت بالشكل المنقط هذا إيه؟
+
+467
+00:51:50,030 --> 00:51:57,090
+طبعا يبقى هذه رسمتي اتنين تان inverse X اتنين تان
+
+468
+00:51:57,090 --> 00:52:01,930
+inverse X سابقا في شر 2 يبقى اللي فوق بده يصير تحت
+
+469
+00:52:01,930 --> 00:52:06,750
+و اللي تحت بده يصير فوق يبقى الرسمة بدها تجيلك من
+
+470
+00:52:06,750 --> 00:52:15,050
+هناك و تجي تطلع هناك و هنا بهذا الشكليبقى الخط
+
+471
+00:52:15,050 --> 00:52:22,590
+الأزرق الغامض هذا اللي هو سالب اتنين تان inverse X
+
+472
+00:52:22,590 --> 00:52:26,630
+اللي احنا بدنا اياها يبقى رسمتنا هي الخط الأزرق
+
+473
+00:52:26,630 --> 00:52:29,910
+الغامض طبعا انا مرضيتش هرسملك اياها على طول ايه
+
+474
+00:52:29,910 --> 00:52:36,350
+وانا ماشيتلك مراحل مشان تعرف كيف حصلنا على هذا لسه
+
+475
+00:52:36,350 --> 00:52:40,660
+لا يزال هناك مجموعة من امثلهاعلى هذه النقطة ثم
+
+476
+00:52:40,660 --> 00:52:46,420
+نذهب للنقطة الأخيرة وهي مشتقة معكس الدالة وتكاملها
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/LdYD_Mn7ME8_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/LdYD_Mn7ME8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..9ab466254b00b1c91c3c7250b55c768d9da7279e
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/LdYD_Mn7ME8_raw.srt
@@ -0,0 +1,2112 @@
+1
+00:00:09,860 --> 00:00:16,280
+اليوم سنبدأ في صميم الموضوع وهو ال inverse
+
+2
+00:00:16,280 --> 00:00:17,180
+function
+
+3
+00:00:30,190 --> 00:00:32,910
+قبل ان ندخل في الانفراد الانفراد الانفراد الانفراد
+
+4
+00:00:32,910 --> 00:00:42,250
+الانفراد الانفراد الانفراد الانفراد
+
+5
+00:00:42,250 --> 00:00:44,790
+الانفراد الانفراد الانفراد الانفراد الانفراد
+
+6
+00:00:44,790 --> 00:00:44,850
+الانفراد الانفراد الانفراد الانفراد الانفراد
+
+7
+00:00:44,850 --> 00:00:45,910
+الانفراد الانفراد الانفراد الانفراد الانفراد
+
+8
+00:00:45,910 --> 00:00:45,950
+الانفراد الانفراد الانفراد الانفراد الانفراد
+
+9
+00:00:45,950 --> 00:00:46,570
+الانفراد الانفراد الانفراد الانفراد الانفراد
+
+10
+00:00:46,570 --> 00:00:46,570
+الانفراد الانفراد الانفراد الانفراد الانفراد
+
+11
+00:00:46,570 --> 00:00:58,430
+الانفراد الانفراد الانفراد الانفراد الانفراد
+
+12
+00:00:58,430 --> 00:01:08,360
+اليبقى definition a function f is
+
+13
+00:01:08,360 --> 00:01:13,180
+a rule that
+
+14
+00:01:13,180 --> 00:01:18,340
+assumes to
+
+15
+00:01:18,340 --> 00:01:24,720
+each
+
+16
+00:01:24,720 --> 00:01:29,080
+element x
+
+17
+00:01:30,570 --> 00:01:42,610
+m a set a a unique element عنصرا وحيدا a unique
+
+18
+00:01:42,610 --> 00:01:49,170
+element f of x m a set
+
+19
+00:01:59,660 --> 00:02:05,000
+نعود للكلام اللي كنا نكتبه ونبدأ بملاحظاتنا عليه
+
+20
+00:02:05,000 --> 00:02:09,880
+نفس التعريف تبع كالغلصين ما غيرناهوش يبقى جدالة F
+
+21
+00:02:09,880 --> 00:02:17,040
+هي صيرة او قاعدة مالها؟ شو بتعمل؟ ذات essence تعين
+
+22
+00:02:17,040 --> 00:02:25,650
+او تحدد او تخفف لكلموجود في الـ set A تخصص له
+
+23
+00:02:25,650 --> 00:02:31,690
+عنصرا واحدا unique element عنصرا واحدا f of x في
+
+24
+00:02:31,690 --> 00:02:36,570
+ال set B يعني لو كان عندي على سبيل المثال هذه هي
+
+25
+00:02:36,570 --> 00:02:43,070
+ال set A وكان عندي هنا هذه هي ال set B يبقى الدالة
+
+26
+00:02:49,050 --> 00:02:56,890
+بخصص للعنصر X اللي موجود في الست A عنصر وحيد في
+
+27
+00:02:56,890 --> 00:03:05,790
+الست B اسمه F of X الشكل اللي عندنا طيب نرجع نقرأ
+
+28
+00:03:05,790 --> 00:03:09,750
+النص تاني و نسقط هذا النص على الرسم اللي احنا
+
+29
+00:03:09,750 --> 00:03:15,190
+جاينه و نشوف كدهبقول الدالة F هي عبارة عن صيغة أو
+
+30
+00:03:15,190 --> 00:03:22,150
+قاعدة ذات أسلوب تحدد لكل عنصر X في الست Aيبقى الست
+
+31
+00:03:22,150 --> 00:03:25,890
+ليس بالضرورة أن يكون فيها عنصر واحدة إنما فيها
+
+32
+00:03:25,890 --> 00:03:31,810
+مجموعة من العناصر يبدأ لو جيت افترض ان هذا X واحد
+
+33
+00:03:31,810 --> 00:03:38,530
+وعندي هنا X اتنين وعندي عنصر تالت هنا X تلاتة طبعا
+
+34
+00:03:38,530 --> 00:03:45,390
+ال X واحد هذا كان في صورته هي F of X واحد لان
+
+35
+00:03:50,090 --> 00:03:58,770
+صورته f of x واحد والx اتنين كانت صورته هنا f of x
+
+36
+00:03:58,770 --> 00:04:06,290
+اتنين لكن ليزال هذه فيها عناصر اخرى زي العناصر
+
+37
+00:04:06,290 --> 00:04:13,300
+اللي عندنا قدر كويس؟نجي نقرا هنا to each element
+
+38
+00:04:13,300 --> 00:04:20,760
+in a set A هل الدالة F ستوطي أو ستمر على كل عنصر
+
+39
+00:04:20,760 --> 00:04:24,520
+من عناصر A ولا لأ؟ ولا هتمر على البعد والبعد
+
+40
+00:04:24,520 --> 00:04:30,290
+الآخر؟ لأع الجميع بلا استثناء لنقل to each element
+
+41
+00:04:30,290 --> 00:04:35,070
+لكل عنصر في ال set A طيب مدينة بدها تغطي جميع
+
+42
+00:04:35,070 --> 00:04:40,670
+العناصر هدول بلا استثناء إذا ال set A بسميها مجال
+
+43
+00:04:40,670 --> 00:04:46,510
+الدالة ال domain تبع ال function F يبقى هذه ال set
+
+44
+00:04:46,510 --> 00:04:53,370
+A هي عبارة عن domain الدالة F طيب
+
+45
+00:04:55,340 --> 00:05:02,560
+سؤال هو هل يمكن لأنصر واحد من الست A يطلع له
+
+46
+00:05:02,560 --> 00:05:09,660
+فارقين او قيمتين في الست B؟ما جالش تعرف ايه؟ جاليه
+
+47
+00:05:09,660 --> 00:05:14,320
+unique element، أنصر الوحيدة، يعني اذا كان أنصر
+
+48
+00:05:14,320 --> 00:05:19,120
+الوحيد من الست ايه، بلاجيله أنصر وحيد وين؟ في الست
+
+49
+00:05:19,120 --> 00:05:25,420
+بي فقط لغاية، السؤال هو هل يمكن أنصراني من الست
+
+50
+00:05:25,420 --> 00:05:31,210
+ايه أن يشترك في نفس الصورة من الست بي؟هذا يعني
+
+51
+00:05:31,210 --> 00:05:34,330
+اننا ماعندناش مشكلة في الشمالة يبقى مدام في
+
+52
+00:05:34,330 --> 00:05:38,150
+الشمالة يبقى خلاص مافي مشكلة ليش؟ لأنه منصش
+
+53
+00:05:38,150 --> 00:05:42,330
+وبالتالي لما نقوم في روم زي X واحد و X تلاتة
+
+54
+00:05:45,750 --> 00:05:50,310
+يبقى f of x واحد وf of x ثلاثة يبقى f of x واحد وf
+
+55
+00:05:50,310 --> 00:05:53,950
+of x ثلاثة اعلى ايكل اتنين نفس الشيء يبقى مافي
+
+56
+00:05:53,950 --> 00:05:58,550
+مشكلة في هذه الحالة لأن مافيش نص ينغي هذا الكلام
+
+57
+00:05:58,550 --> 00:06:04,930
+اذا ممنوع أنصر واحد كله صورتين لامنع ان يشتري
+
+58
+00:06:04,930 --> 00:06:09,970
+كأنصران في نفس الصورة مافيش مشكلة عندنا في هذه
+
+59
+00:06:09,970 --> 00:06:17,400
+الحالة تمام تمام طيبهل يمكن للدالة if صورها اتغطي
+
+60
+00:06:17,400 --> 00:06:22,560
+جميع عناصر بيه؟ لأ لأن هاي لثانثة و هاي اتنين و
+
+61
+00:06:22,560 --> 00:06:30,000
+هاي تلاتة ماضعروش كصور لعناصر من الانإذاً ال B هنا
+
+62
+00:06:30,000 --> 00:06:35,880
+بسميه ال code domain المجال المصاحب المجال المناظر
+
+63
+00:06:35,880 --> 00:06:41,020
+المجال المقابل اللي بدك اللي هيبقى B هنا بسميه ال
+
+64
+00:06:41,020 --> 00:06:51,690
+code domain of Fهنا اظهر لي العواصرين اللي اتنين
+
+65
+00:06:51,690 --> 00:06:57,190
+هدول اللي هم الصورة الصورانش بيسميهم ال range تبع
+
+66
+00:06:57,190 --> 00:07:01,730
+ال F اي ال image تبع ال F الصورة تبع اتنين ال F
+
+67
+00:07:01,730 --> 00:07:07,030
+يبقى هذه اللي هي العواصرين اللي اتنين هدول بسميهم
+
+68
+00:07:07,030 --> 00:07:07,830
+ال range
+
+69
+00:07:16,640 --> 00:07:22,060
+يبقى هي صورة the life، ممتاز جدا، إذا في أننا
+
+70
+00:07:22,060 --> 00:07:28,420
+بنان، في أننا كودمان، في أننا range، السؤال هو هل
+
+71
+00:07:28,420 --> 00:07:34,640
+يمكن لل range أن يكون أكبر من الكودمان؟ مش ممكنية
+
+72
+00:07:36,600 --> 00:07:40,860
+البركة بصير جد مين؟ جد الكود مين؟ و in general هو
+
+73
+00:07:40,860 --> 00:07:46,660
+أقل منه، صحيحة أو لا؟ تمام، على أي حال هذه المقدمة
+
+74
+00:07:46,660 --> 00:07:51,160
+البسيطة اللي هو ال function يبقى، بدك تعرفلي إنه
+
+75
+00:07:51,160 --> 00:07:54,540
+ممكن لأوصارين إنهم يشتركوا في نفس الصورة، ماعناش
+
+76
+00:07:54,540 --> 00:07:58,880
+مشكلة، لكن لايمكن لأوصر واحد يذهب لمين، يذهب
+
+77
+00:07:58,880 --> 00:08:00,540
+لصوتين، فالتعريف
+
+78
+00:08:05,140 --> 00:08:10,640
+حالة خاصة او لما اقول حالة خاصة انا قصدها بعينها
+
+79
+00:08:10,640 --> 00:08:15,980
+لهدف احنا بدنا ياسا نعرفه خلال هذه المحاضرة ان شاء
+
+80
+00:08:15,980 --> 00:08:19,940
+الله بداخل حالة خاصة من ال function هي ال function
+
+81
+00:08:19,940 --> 00:08:23,560
+اللي بنسميها one to one تعالي يا ابني انت موجود
+
+82
+00:08:23,560 --> 00:08:29,380
+فهو واضح هنا تعالي واضح هنا في حاجة عنه كرسي فاضي
+
+83
+00:08:29,380 --> 00:08:33,740
+تاني؟ تعالي واضح تاني
+
+84
+00:08:39,240 --> 00:08:43,920
+يبقى الأن بدأ نجي لحالة خاصة من ال function اللى
+
+85
+00:08:43,920 --> 00:08:49,320
+بدى سميها ال one to one function ده لو أخد لواحد
+
+86
+00:08:49,320 --> 00:08:54,980
+نكتب التعريف نحاول نستوعبه تماما و بعدين نشوف ليش
+
+87
+00:08:54,980 --> 00:09:00,300
+أخدنا هذه الحالة الخاصة دون غيرها يبقى definition
+
+88
+00:09:00,300 --> 00:09:04,280
+a function f
+
+89
+00:09:15,830 --> 00:09:23,570
+بنسميها one through one if no two different
+
+90
+00:09:32,300 --> 00:09:41,200
+إذا لم يكن هناك اشياء مختلفة او
+
+91
+00:09:41,200 --> 00:09:44,260
+او
+
+92
+00:09:44,260 --> 00:09:45,780
+او او او او او او او او او او او او او او او او او
+
+93
+00:09:45,780 --> 00:09:45,780
+او او او او او او او او او او او او او او او او او
+
+94
+00:09:45,780 --> 00:09:47,280
+او او او او او او او او او او او او او او او او او
+
+95
+00:09:47,280 --> 00:09:48,720
+او او او او او او او او او او او او او او او او او
+
+96
+00:09:48,720 --> 00:09:54,140
+او او او او او او او او او او او او او او او
+
+97
+00:09:54,140 --> 00:09:54,660
+او او او او او او او او او او او او او او او او او
+
+98
+00:09:54,660 --> 00:09:58,560
+او
+
+99
+00:09:58,560 --> 00:10:00,200
+او ا
+
+100
+00:10:03,810 --> 00:10:06,570
+بنعبر على هذا الكلام بصيغة رياضية
+
+101
+00:10:27,380 --> 00:10:36,960
+والـ x1 و الـ x2 موجودات في الـ set D equivalently
+
+102
+00:10:36,960 --> 00:10:45,200
+التعريف
+
+103
+00:10:45,200 --> 00:10:54,740
+المكافئ لهذا التعريف F او دلة F من ال set D إلى ال
+
+104
+00:10:54,740 --> 00:11:06,290
+set Ris one to one if ال f of x واحد بدها تساوي ال
+
+105
+00:11:06,290 --> 00:11:13,930
+f of x اتنين then ال x واحد بدها تساوي ال x اتنين
+
+106
+00:11:13,930 --> 00:11:22,170
+و ال x واحد و ال x اتنين موجودات في ال set D برضه
+
+107
+00:11:22,170 --> 00:11:26,030
+هذا له معنى هندسي graphically
+
+108
+00:11:30,100 --> 00:11:38,600
+من الناحية الهندسية هذا شو معناه a function if is
+
+109
+00:11:38,600 --> 00:11:46,960
+one to one if and only if no
+
+110
+00:11:46,960 --> 00:11:57,340
+horizontal line no horizontal line intersects
+
+111
+00:12:03,930 --> 00:12:17,010
+its graph الرسم البياني more than once
+
+112
+00:12:22,820 --> 00:12:29,860
+نقرأ كل ما كتبناه من جديد ونحاول أن نفهم كل نقطة
+
+113
+00:12:29,860 --> 00:12:32,880
+موجودة قدامنا على اللغة.
+
+114
+00:12:38,970 --> 00:12:46,310
+بناخد الـ one to one function اذا لم
+
+115
+00:12:46,310 --> 00:12:55,210
+يكن هناك اشياء مختلفة من D لديها نفس الصورة في R
+
+116
+00:12:59,920 --> 00:13:06,200
+ألا يمكن أن أجد صورة عمالة تبقى متساومة، ليس لها
+
+117
+00:13:06,200 --> 00:13:11,720
+نفس الصورة يعني بالبلد هيك العماصر المختلفة لها
+
+118
+00:13:11,720 --> 00:13:17,120
+صور مختلفة تمام هذا الكلام النظري بناروح نصير هذا
+
+119
+00:13:17,120 --> 00:13:21,500
+الكلام بصيرة رياضية فروحنا وقلنا that is
+
+120
+00:13:26,450 --> 00:13:32,350
+يعني أنصار مختلفة then f of x واحد لا يمكن أن تكون
+
+121
+00:13:32,350 --> 00:13:37,590
+f of x اتنين يعني الصوتين تبعاتهم غير متسامتين اما
+
+122
+00:13:37,590 --> 00:13:38,990
+then x واحد x اتنين
+
+123
+00:13:44,380 --> 00:13:48,440
+هذا سيلة رياضية للتريف اللي احنا قلناه، فيه سيلة
+
+124
+00:13:48,440 --> 00:13:52,560
+اخرى، ايش السيلة اخرى؟ فيها المليارات حاجة اسمها
+
+125
+00:13:52,560 --> 00:13:57,220
+ال negation، ال negation المفي، انا عندي بطولة،
+
+126
+00:13:57,220 --> 00:14:03,020
+بدأت اعطيني مطلوبالشغل المكافئة لها نفي المطلوب
+
+127
+00:14:03,020 --> 00:14:07,240
+داخل نفي مين المعطيات وقعد ندرسها في موضوع ال
+
+128
+00:14:07,240 --> 00:14:12,440
+logic المنطق الرياضي تمام؟ طب إيش هنا ال negation
+
+129
+00:14:12,440 --> 00:14:17,610
+للعبارة اللي بدها تنفي؟مافي هذه يعني ايش؟
+
+130
+00:14:17,610 --> 00:14:22,330
+بالمساواة يبدأ يجيبي الكوبلن ب F مانديلا is one to
+
+131
+00:14:22,330 --> 00:14:29,050
+one F لفظ X1 يبدأ يصير F of X2 يبدأ يعطوني مافي
+
+132
+00:14:29,050 --> 00:14:35,970
+هذه يتجرن X1 يساوي X2إن الطريقة الأخرى أو التعريف
+
+133
+00:14:35,970 --> 00:14:39,670
+الأخر لل one to one function إن ما يحصل إن
+
+134
+00:14:39,670 --> 00:14:44,830
+الصورتين متساويتين للدالة لأنصرين من ال domain
+
+135
+00:14:44,830 --> 00:14:50,630
+تبعها إن حصلت إن الصورتين متساويتين يجب أن يكون
+
+136
+00:14:50,630 --> 00:14:53,470
+الأصل متساوي
+
+137
+00:14:54,520 --> 00:14:59,080
+يوجد حاجة اسمها ناحية هندسية أو ناحية رسم جراف
+
+138
+00:14:59,080 --> 00:15:02,540
+الورسم البياني يبقى graphically من الناحية
+
+139
+00:15:02,540 --> 00:15:07,620
+البيانية أو من ناحية الرسم الهندسي اللي بنرسمه a
+
+140
+00:15:07,620 --> 00:15:11,540
+function f is one-to-one if and only if no
+
+141
+00:15:11,540 --> 00:15:15,840
+horizontal line intersects its graph more than
+
+142
+00:15:15,840 --> 00:15:22,780
+once يعني أكثر من مرة وعلى كيف يعني؟لو رسمت منحلة
+
+143
+00:15:22,780 --> 00:15:28,080
+دولة اللي عندك و جبت اي horizontal line رسمته
+
+144
+00:15:28,080 --> 00:15:33,560
+انقطع المنحلة في اكثر من نقطة اذا الدولة هذه التي
+
+145
+00:15:33,560 --> 00:15:38,600
+يمثلها هذا المنحلة ليست one to one لكن اذا قطعها
+
+146
+00:15:38,600 --> 00:15:43,380
+في نقطة واحدة فقط بقول المنحلة هذا او الدولة هذه
+
+147
+00:15:43,380 --> 00:15:48,740
+one to one يبقى هذا بيسميه horizontal line
+
+148
+00:15:53,010 --> 00:15:58,250
+يعني انت عندك رسمة بدي اعرف هل هذه الرسمة تمثل one
+
+149
+00:15:58,250 --> 00:16:01,930
+to one function ولا لا بقول بجيبها الوسطى و ببرسه
+
+150
+00:16:01,930 --> 00:16:07,130
+موازية محو اكس والله اذا قطع المنحنة طبعا مش خطبة
+
+151
+00:16:07,130 --> 00:16:12,490
+يعني اي خط افقي موازية محو اكس اعلى ال X ولا اسفل
+
+152
+00:16:12,490 --> 00:16:17,330
+ال X ان قطع المنحنة فقط في نقطة واحدة يعني اي خط
+
+153
+00:16:17,330 --> 00:16:20,960
+رسمةإذا لم يقطع المنحنة إلا في نقطة واحدة، فهذه
+
+154
+00:16:20,960 --> 00:16:25,860
+المنحنة يمثل one to one function. إذا قطع في نقطة
+
+155
+00:16:25,860 --> 00:16:26,720
+يعني.
+
+156
+00:16:32,500 --> 00:16:37,180
+هذا السبب يجب أن نقول إن أنا لو عندي منحلجات
+
+157
+00:16:37,180 --> 00:16:42,260
+horizontal قطعة في نقطة، إذا لو أخذت أي نقطة تين
+
+158
+00:16:42,260 --> 00:16:46,600
+مختلفتين على محور السينات، فانا هتشيخ صورتين
+
+159
+00:16:46,600 --> 00:16:50,630
+منحلجات متن تين مختلفتين وانا واحد زي التانيةمصبوح
+
+160
+00:16:50,630 --> 00:16:54,010
+او لا؟ لماذا؟ لأن النقطة الوحيدة ليست في نقطة
+
+161
+00:16:54,010 --> 00:16:58,590
+واحدة وليس أكتر. اذا لماذا يمكن لنقطتين مختلفتين
+
+162
+00:16:58,590 --> 00:17:03,310
+ان تطلع من نفس الصورة بتالي أدمين وانترن؟ مثل ايش
+
+163
+00:17:03,310 --> 00:17:08,810
+مثلا؟ الأوجياء تقول لك ملحنة Y تساوي X تكيد مرة
+
+164
+00:17:08,810 --> 00:17:12,450
+علانة كتير في كل قلصية، مصبوح؟ يعني الأوجياء تقول
+
+165
+00:17:12,450 --> 00:17:14,230
+لك هنا for example
+
+166
+00:17:19,120 --> 00:17:27,680
+functions اللي هو y تساوي x تقريب مثلا and دالة
+
+167
+00:17:27,680 --> 00:17:36,440
+تانية y تساوي الجدرى التربية اللي x are one to one
+
+168
+00:17:36,440 --> 00:17:47,360
+but ولكن the function y تساوي x تربية is not one
+
+169
+00:17:47,360 --> 00:17:58,310
+to oneبشوف السبب بقوله because of the horizontal
+
+170
+00:17:58,310 --> 00:18:08,710
+line test اللي هو اختبار الخطأ و كيف كانت تانيةلو
+
+171
+00:18:08,710 --> 00:18:15,350
+جيت قلت للمحارب هذا محور X و هذا محور Y و روحنا و
+
+172
+00:18:15,350 --> 00:18:20,910
+رسمنا منحنى الدالة اللى هو Y تساوي X تكايب زى ما
+
+173
+00:18:20,910 --> 00:18:24,970
+كنا بنرسمها في كام كراس آية يبقى المنحنى بيجي
+
+174
+00:18:24,970 --> 00:18:30,170
+بالشكل اللى عندك هذا ياك تمام و بيجي نازل بهذا
+
+175
+00:18:30,170 --> 00:18:36,420
+الشكل يبقى هذا Y تساوي X تكايباللي ورا شايفين
+
+176
+00:18:36,420 --> 00:18:41,260
+اللون هذا، اولا تخليه خط أسود. الأخضر هذا واضح للي
+
+177
+00:18:41,260 --> 00:18:46,480
+وراه؟ ماشي الحالة. يبقى هذه Y تساوي X تقيمة. لو
+
+178
+00:18:46,480 --> 00:18:53,220
+جيت أرسمت أي horizontal line، لو جيت رسمت أي
+
+179
+00:18:53,220 --> 00:18:58,320
+horizontal line، يبقى ال horizontal line كان
+
+180
+00:18:58,320 --> 00:18:59,640
+بالشكل هذا هيك.
+
+181
+00:19:03,840 --> 00:19:11,840
+لا يمكن ان
+
+182
+00:19:11,840 --> 00:19:16,160
+يقطع هذا المنخلة في نقطة او نقطة او نقطة او نقطة
+
+183
+00:19:16,160 --> 00:19:16,680
+او نقطة او نقطة او نقطة او نقطة او نقطة او نقطة او
+
+184
+00:19:16,680 --> 00:19:16,820
+نقطة او نقطة او نقطة او نقطة او نقطة او نقطة او
+
+185
+00:19:16,820 --> 00:19:16,820
+نقطة او نقطة او نقطة او نقطة او نقطة او نقطة او
+
+186
+00:19:16,820 --> 00:19:16,820
+نقطة او نقطة او نقطة او نقطة او نقطة او نقطة او
+
+187
+00:19:16,820 --> 00:19:16,820
+نقطة او نقطة او نقطة او نقطة او نقطة او نقطة او
+
+188
+00:19:16,820 --> 00:19:19,200
+نقطة او نقطة او نقطة او نقطة او نقطة او نقطة او
+
+189
+00:19:19,200 --> 00:19:31,380
+نقطة او نقطة او نهذا محور X وهذا محور Y وهذا
+
+190
+00:19:31,380 --> 00:19:41,880
+المنحنة Y تساوي ال square root لل X لو جيك رسمت أي
+
+191
+00:19:41,880 --> 00:19:45,360
+خط أفق بهذا الشكل هيقطع المنحنة
+
+192
+00:19:49,160 --> 00:19:54,420
+إذا أبني الـ two functions اللي هم دارعان one to
+
+193
+00:19:54,420 --> 00:20:02,080
+one functions one to one functions قلت لو جيتنا
+
+194
+00:20:02,080 --> 00:20:07,360
+الدالة Y تساوي X تربية يوجه هذا الملحانة الدالة
+
+195
+00:20:07,360 --> 00:20:13,800
+هذا محور X هذا محور Y هي نقطة الأصل لـ zero جينما
+
+196
+00:20:13,800 --> 00:20:17,880
+سمنا الملحانة Y تساوي X تربية
+
+197
+00:20:26,840 --> 00:20:35,300
+Y تساوي X تربية. ارسم اي خط افق يهيك. يجب ان اقطع
+
+198
+00:20:35,300 --> 00:20:40,540
+المنحنة في النقطة التانية. وهنا النقطة التانية.
+
+199
+00:20:40,600 --> 00:20:45,240
+هذه بدي اسميها X واحد وهذه بدي اسميها X اتنين.
+
+200
+00:20:45,680 --> 00:20:48,280
+البعد المنقط هذا هو
+
+201
+00:20:51,140 --> 00:20:57,040
+البعد الملقق التووي هو f of x اتنين شو له علاقة
+
+202
+00:20:57,040 --> 00:21:01,280
+بين f of x واحد وf of x اتنين؟ طريقه اللي هو
+
+203
+00:21:01,280 --> 00:21:06,240
+البعدين ما بين خطين متوازين البعد بين خطين متوازين
+
+204
+00:21:06,240 --> 00:21:11,540
+اللي هو يساوي مقدارا ثابتا اللي هو تفيره مهما رسم
+
+205
+00:21:11,540 --> 00:21:20,100
+اي خط يصل بين هذين الخطين طيب انا الان هذي النقone
+
+206
+00:21:20,100 --> 00:21:26,640
+to one الصدر بكواز ان القوق بكواز
+
+207
+00:21:38,300 --> 00:21:44,120
+عنصرين مختلفين لكن الصور كانت متساوية
+
+208
+00:21:50,950 --> 00:21:56,750
+بصير الجهاز مدهش وعبارة حط لي X بسالب اتنين يبقى
+
+209
+00:21:56,750 --> 00:22:01,510
+برضه باطني كمان اربع اذا متساوت الصورة تان لكل
+
+210
+00:22:01,510 --> 00:22:07,350
+الاصل غير متساوي اتنين وسالب اتنين ومن هنا فالدالة
+
+211
+00:22:07,350 --> 00:22:14,530
+ليست one to one طيب نرجع بالذاكرة وراي شوية لكل
+
+212
+00:22:14,530 --> 00:22:21,630
+قرص Aلو عندي ذلة زيولية على طول اي ذلة تناقصية على
+
+213
+00:22:21,630 --> 00:22:29,310
+طول ورسمت اي horizontal line؟ واحدة بس يبقى any
+
+214
+00:22:29,310 --> 00:22:33,690
+increasing function او decreasing function is one
+
+215
+00:22:33,690 --> 00:22:38,830
+to one صحيح ام لا؟ يبقى خود نكتب هذه ملاحظة remark
+
+216
+00:22:38,830 --> 00:22:43,510
+اي
+
+217
+00:22:44,750 --> 00:22:50,310
+increasing or
+
+218
+00:22:50,310 --> 00:22:55,870
+decreasing function
+
+219
+00:23:05,150 --> 00:23:13,490
+هذا محور X وهذا محور Y يبقى تزايدية يبقى تزايدية
+
+220
+00:23:13,490 --> 00:23:21,130
+تقريبا تزايدية يبقى
+
+221
+00:23:21,130 --> 00:23:24,090
+تزايدية
+
+222
+00:23:28,610 --> 00:23:39,030
+وهذه دالة تزامدية. او أي خط أفقي في نقطة واحدة فقط
+
+223
+00:23:39,030 --> 00:23:42,350
+لابدة. لأن هذه الدالة وانتهت.
+
+224
+00:23:44,990 --> 00:23:50,530
+بالشكل اللي لنا هذا هذا محور X وهذا محور Y. وكذا
+
+225
+00:23:50,530 --> 00:23:55,030
+تبدأ على سبيل المثال بالشكل اللي لنا هذا. يبقى هذا
+
+226
+00:23:55,030 --> 00:24:00,370
+اللي لنا معاها decreasing تنافسية. يبقى هذه
+
+227
+00:24:00,370 --> 00:24:01,910
+decreasing
+
+228
+00:24:05,240 --> 00:24:11,300
+function ارسم اي خط افضل طيب نقلها الى نقطة واحدة
+
+229
+00:24:11,300 --> 00:24:15,220
+وامن هنا فأي increasing function او decreasing
+
+230
+00:24:15,220 --> 00:24:22,480
+function هي عجبا عن one to one function طيب
+
+231
+00:24:22,480 --> 00:24:27,640
+نوجف حاجة بسيطة ناخد بعض الأمثلة العادلية اللي
+
+232
+00:24:27,640 --> 00:24:31,020
+بتلطف الجو هيك ملاش يكون كله كلام ناسي
+
+233
+00:24:47,350 --> 00:24:57,910
+زائد اتنين and الـ g of x اللي يتساوي and الـ g of
+
+234
+00:24:57,910 --> 00:25:09,990
+x يساوي x زائد واحد على x one to one سؤال
+
+235
+00:25:09,990 --> 00:25:13,270
+بيطلع نفسه وبنحاول انجازه
+
+236
+00:25:18,140 --> 00:25:22,440
+هل الدوال اللي عندنا هذه تبقى دوال one to one أم
+
+237
+00:25:22,440 --> 00:25:22,480
+لا؟
+
+238
+00:25:27,070 --> 00:25:34,750
+هل هذه الدالة واحدة واحدة او لا؟ هناك أكثر من
+
+239
+00:25:34,750 --> 00:25:39,750
+طريقة لإثبات المستدالة هل هي واحدة واحدة او لا،
+
+240
+00:25:39,750 --> 00:25:41,970
+وليس واحدة واحدة او لا، وليس واحدة واحدة او لا،
+
+241
+00:25:41,970 --> 00:25:43,970
+وليس واحدة واحدة او لا، وليس واحدة واحدة او لا،
+
+242
+00:25:43,970 --> 00:25:50,750
+وليس واحدة واحدة او لا،
+
+243
+00:26:00,480 --> 00:26:07,180
+أفترض إنه في عندي صورتين متساوياتين إذا بدأت أثبت
+
+244
+00:26:07,180 --> 00:26:11,820
+إن الأصل المتساوي بصير وانت وما قدرت يرجع ينسى
+
+245
+00:26:11,820 --> 00:26:21,040
+الموضوع يرجع بالتاجر أقول Assume أفترض إن ال F of
+
+246
+00:26:21,040 --> 00:26:27,040
+X1 تساوي ال F of X2
+
+247
+00:26:30,720 --> 00:26:35,500
+إن الصوتين متساوتين، إيش بدي أثبت؟ إن ال X واحد
+
+248
+00:26:35,500 --> 00:26:39,760
+بدي أثبت ال X اتنين، إن جدرت أثبت هذا، بصير البام
+
+249
+00:26:39,760 --> 00:26:44,320
+هاد مالها وانت واحد.فبقى بدي أسأل سؤال، أنا خدت ال
+
+250
+00:26:44,320 --> 00:26:49,240
+elements بعينيهم ولا اختياري من ما يكون يكون؟
+
+251
+00:26:49,240 --> 00:26:52,880
+ممتاز جدا، يعني يا شباب لو أنا راح أدج الباب اللي
+
+252
+00:26:52,880 --> 00:26:59,380
+هناك، و أنا بقال لقلك، علي تبديك شويةيبقى هل اختار
+
+253
+00:26:59,380 --> 00:27:03,720
+طالب بعينه علشان فلان فلان؟ طبعاً لأ، مرقعه أخذ أي
+
+254
+00:27:03,720 --> 00:27:07,260
+طالب، لكن لو زجج الجابر هاجه جانبه محمد محمود
+
+255
+00:27:07,260 --> 00:27:13,200
+عبدالهادي، مثلا، كيف؟ يبقى عقوبة، إذا موجود، اقوله
+
+256
+00:27:13,200 --> 00:27:15,600
+موجود، إذا موجود، هذا يعني هو بيقطع، إذا مش موجود،
+
+257
+00:27:15,600 --> 00:27:19,420
+اقوله مش موجودوهذا الكلام في الحالة التانية قال
+
+258
+00:27:19,420 --> 00:27:23,940
+يختار طالب بعينه. لأ طبعا هذا ما ينفعش حد ما في
+
+259
+00:27:23,940 --> 00:27:27,940
+الاتباعت. لما تاخد X واحد و X اتنين، اي انصر ينطبق
+
+260
+00:27:27,940 --> 00:27:32,280
+على اي انصر موجودة في الدماغ. اذا ما ينطبق عليهم
+
+261
+00:27:32,280 --> 00:27:35,840
+ينطبق على باقي منهم عن عناصر اخرى اللي من الخارج.
+
+262
+00:27:41,530 --> 00:27:48,370
+أنا اخترقت ان f of x1 يكون ايضا f of x2 يكون ايضا
+
+263
+00:28:11,510 --> 00:28:16,830
+طب هو بيحصل باتنين للطرفين يبقى ايش بيصير عندي؟
+
+264
+00:28:16,830 --> 00:28:22,390
+بيصير عندي x واحد زائد واحد لكل تكييب يساوي x
+
+265
+00:28:22,390 --> 00:28:29,610
+اتنين زائد واحد لكل تكييب خد الجدر التالت للطرفين
+
+266
+00:28:29,610 --> 00:28:34,970
+يبقى بيصير عندي x واحد زائد واحد يساوي x اتنين
+
+267
+00:28:34,970 --> 00:28:41,950
+زائد واحدواضيف لي سالب واحد للطرفين يبقى بصير
+
+268
+00:28:41,950 --> 00:28:50,510
+عندنا X واحد يساومين X اتنين شو تفسيرك لهذا؟ يبقى
+
+269
+00:28:50,510 --> 00:29:00,010
+هذا يعطينا ان ال F is one to one يبقى
+
+270
+00:29:00,010 --> 00:29:04,330
+مضام بلقة F one to one خلاص هذا هو المطموب تبع
+
+271
+00:29:04,330 --> 00:29:04,690
+السؤال
+
+272
+00:29:08,080 --> 00:29:19,040
+بداية للدالة التانية يبقى شباب إحدى الطرق ليثبت
+
+273
+00:29:19,040 --> 00:29:22,980
+إن الدالة one to one إنه ياخد صورتين متساويتين
+
+274
+00:29:22,980 --> 00:29:29,260
+عشوائيا ويحاول يثبت إن الأصل تبعهم ماله متساوين،
+
+275
+00:29:29,260 --> 00:29:32,040
+يقول خلاص وحلنا مشكلتنا والقبلة
+
+276
+00:29:34,270 --> 00:29:40,490
+طب ناخد طريقة أخرى لو جيت لك دلة لإن هذه الـ g of
+
+277
+00:29:40,490 --> 00:29:48,470
+x بدها تساوي x زائد واحد على x لازم تثبتها بنفس
+
+278
+00:29:48,470 --> 00:29:53,030
+الطريقة اللي فاتت لازم تغير الطريقة الآن لما أقول
+
+279
+00:29:53,030 --> 00:30:01,590
+اثبت ان هذه تساوي هذه لو جبت counter example مثال
+
+280
+00:30:05,270 --> 00:30:08,990
+بنغير الشغل هذه، مظبوط ولا لأ؟ يبقى احنا جالي نشوف
+
+281
+00:30:08,990 --> 00:30:14,670
+لهذه هل هي انت وانه ولا لأ. اذا كنت اجيب له مثال
+
+282
+00:30:14,670 --> 00:30:22,150
+انه صورتين متساوية لكن أصلهم غير متساوي، ده كنت
+
+283
+00:30:22,150 --> 00:30:27,950
+مايربيه صورة.يعني مثال ضد انها one to one بست وليس
+
+284
+00:30:27,950 --> 00:30:31,490
+بالضرورة ان انا اروحها برهن زي جامع بدمان برهن زي
+
+285
+00:30:31,490 --> 00:30:35,390
+جامع برضه مافي مشكلة تمام؟ فبقاش ال counter
+
+286
+00:30:35,390 --> 00:30:40,870
+example يعني مثال ضد هالشغل هذا نطلع فيها كويس لو
+
+287
+00:30:40,870 --> 00:30:47,970
+أخدت العنصرين اتنين ونص عنصر رقم اتنين وعنصر نص
+
+288
+00:30:47,970 --> 00:30:51,670
+وشوف قداش قيمة الدلة في كل الحالتين
+
+289
+00:30:54,040 --> 00:30:58,340
+هذا يجب أن يكون واقينا ان ال جي of اتنين يساوي
+
+290
+00:30:58,340 --> 00:31:03,200
+اتنين زائد واحد على اتنين اتنين و نص يعني كده؟
+
+291
+00:31:03,200 --> 00:31:12,400
+خمسة على اتنين and ال جي of نص يساوي نص زائد واحد
+
+292
+00:31:12,400 --> 00:31:18,250
+على نصواحد ع الاصل هو اتنين، او الاصل جا اتنين، او
+
+293
+00:31:18,250 --> 00:31:23,650
+الاصل جا خمسة على اتنين. إذا صار أنت واصلتين
+
+294
+00:31:23,650 --> 00:31:29,570
+متساوتين، كل واحدة منهم خمسة على اتنين. لكن هل
+
+295
+00:31:29,570 --> 00:31:34,030
+الاصل متساوي؟ لأ. يعني هل انا واحد وانت واحد؟ لأ.
+
+296
+00:31:44,610 --> 00:31:55,030
+الجي اغ اتنين سوى الجي اغ نص ولكن اتنين لا تسوى نص
+
+297
+00:31:55,030 --> 00:32:03,730
+يعني هذا مثال عددي يثبت ان هذه الدالة ليست one to
+
+298
+00:32:03,730 --> 00:32:11,580
+oneطب لو روحت أنا جبت مثال عددي يثبت إنها one to
+
+299
+00:32:11,580 --> 00:32:16,240
+one، بصير كلام صحيح للجميع؟ لأ، لأ، لأ، لأ، لأ،
+
+300
+00:32:16,240 --> 00:32:17,520
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ،
+
+301
+00:32:17,520 --> 00:32:18,540
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ،
+
+302
+00:32:18,540 --> 00:32:20,420
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ،
+
+303
+00:32:20,420 --> 00:32:22,880
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ،
+
+304
+00:32:22,880 --> 00:32:31,960
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ
+
+305
+00:32:36,860 --> 00:32:40,920
+بـ Increasing يبقى one to one لو طلعت Decreasing
+
+306
+00:32:40,920 --> 00:32:45,540
+على طول يبدو كمان one to one هي طريقة ثالثة وهاتلة
+
+307
+00:32:45,540 --> 00:32:51,040
+يعني يمكن إثبات ال one to one بعدد طوق أو بأكثر من
+
+308
+00:32:51,040 --> 00:32:57,800
+طريقة نجي الآن للتعريف الألوان اللي رفعناه في
+
+309
+00:32:57,800 --> 00:33:02,640
+بداية المحاضرة وهو ال inverse function يبقى بدنا
+
+310
+00:33:02,640 --> 00:33:03,640
+نجي ل definition
+
+311
+00:33:07,400 --> 00:33:14,580
+أفترض أن الـ
+
+312
+00:33:14,580 --> 00:33:23,460
+F هو عملية واحدة واحدة عملية واحدة واحدة على
+
+313
+00:33:23,460 --> 00:33:26,600
+مصدرها
+
+314
+00:33:26,600 --> 00:33:35,300
+D مع مجموعة R مع مجموعة
+
+315
+00:33:38,750 --> 00:33:45,590
+the inverse function
+
+316
+00:33:45,590 --> 00:33:56,230
+الف انفرس is defined by
+
+317
+00:33:56,230 --> 00:33:58,850
+العلفة التالية
+
+318
+00:34:26,530 --> 00:34:30,950
+يبقى the inverse function if inverse is defined by
+
+319
+00:34:30,950 --> 00:34:33,290
+بعرفها كالتالي
+
+320
+00:34:36,150 --> 00:34:45,450
+F inverse of B يكون ايضا F of A يكون ايضا F of A
+
+321
+00:34:45,450 --> 00:34:52,510
+يكون ايضا
+
+322
+00:34:52,510 --> 00:35:05,050
+F of A
+
+323
+00:35:05,140 --> 00:35:11,340
+the revenge of
+
+324
+00:35:11,340 --> 00:35:25,760
+if and the else as دي.بنروح
+
+325
+00:35:25,760 --> 00:35:34,100
+نوضح التعريف هذا.شوفوا شباب أنا عندي ست دي وست ا.
+
+326
+00:35:35,070 --> 00:35:40,730
+الـ set D لو جئت و قلت هذه هي ال set D او هذه هي
+
+327
+00:35:40,730 --> 00:35:46,850
+ال main هذه هي ال set R هي عبارة عن ال range دالة
+
+328
+00:35:46,850 --> 00:35:51,990
+F مش ال code main لأن ال code main يمكن أن عناصر
+
+329
+00:35:51,990 --> 00:35:56,250
+ما يظهروش كصورة يعني انا بدي ال range معناته كل
+
+330
+00:35:56,250 --> 00:36:01,190
+العناصر اللي في ال range هم الصور لعناصر من ال
+
+331
+00:36:01,190 --> 00:36:09,040
+domainهتجيني F من D إلى A يبقى A يبدأ بالـ F لو
+
+332
+00:36:09,040 --> 00:36:16,860
+كان عندي غنصر هنا اسمه A في D F هتأثر عليه هتدهر
+
+333
+00:36:16,860 --> 00:36:26,580
+صوته هنا F of A لأن F of A هتسميه كمان بيه يبقى
+
+334
+00:36:26,580 --> 00:36:28,880
+بيه غنصر في ال range
+
+335
+00:36:32,110 --> 00:36:41,630
+عكسية بدأت تأخذ من D الى الـRange تبع الـF ترجع
+
+336
+00:36:41,630 --> 00:36:48,750
+لها الى D تماما يجه الـF البرس سيأتي له كيك بالشكل
+
+337
+00:36:48,750 --> 00:36:55,090
+لأن هذا في اتجاه المعكس يجه هذا F البرس بشكل
+
+338
+00:36:55,090 --> 00:37:00,600
+لانانانقرأ الكلام ونشوفه على الرسم نقرأ التاريخ
+
+339
+00:37:00,600 --> 00:37:07,040
+نفترض أن الدولة F is one to one one to one يعني F
+
+340
+00:37:07,040 --> 00:37:11,920
+لما انأثرت على نعاصر الفيديو كل واحد نظرت له صورة
+
+341
+00:37:11,920 --> 00:37:16,920
+ممفاصلة مالهاش علاقة بالتانية عندي ثلاث عناصر يبدو
+
+342
+00:37:16,920 --> 00:37:20,880
+عندي ثلاث صور عندي عشر عناصر يبدو عندي عشر صور و
+
+343
+00:37:20,880 --> 00:37:28,040
+هكذا مافيش اشتراك بينهم أكتر افينلو كانت وكأن ال F
+
+344
+00:37:28,040 --> 00:37:34,880
+is one to one هو شارب لضمان وجود المعقول.هي احنا
+
+345
+00:37:34,880 --> 00:37:38,520
+ليش بنشتغل من أول محرر على ال one to one؟نشتغلش
+
+346
+00:37:38,520 --> 00:37:43,440
+عليها بلاش، لأنها لازمانة، لازمانة بعد قليل.فبعدين
+
+347
+00:37:43,440 --> 00:37:46,940
+بيقولوا ده لأ if is one to one function على الدمون
+
+348
+00:37:46,940 --> 00:37:53,160
+تبعها وكان ال range تبعها R يبقى the inverse
+
+349
+00:37:53,160 --> 00:37:58,760
+function ال F فوقها سالق واحد F فوقها سالق واحد
+
+350
+00:37:58,760 --> 00:38:05,000
+ليست F أساسي واحدفقص سالب واحد بيبقى واحد على F
+
+351
+00:38:05,000 --> 00:38:10,740
+فهذا ما يسمونه الـ Spherical مقلوب طبعا لإن ما
+
+352
+00:38:10,740 --> 00:38:14,960
+قبلناش المقلوب بدنا المعكوس فالـ F وفوقها سالب
+
+353
+00:38:14,960 --> 00:38:21,120
+واحد رمز يدل على معكوس الدلة وليس على مقلوب الدلة
+
+354
+00:38:40,480 --> 00:38:48,810
+فإذا كان f of a سوى مين سوى b فإذا كان f of aنرجع
+
+355
+00:38:48,810 --> 00:38:53,830
+مرة تانية. أنا قلت بالله اخدي one to one. يبقى
+
+356
+00:38:53,830 --> 00:38:59,510
+الأنفر الواحد هذا فتنهر له صورة اسم F of A ولا
+
+357
+00:38:59,510 --> 00:39:02,610
+واحد هيشارك فيها. زواج كاتوليكي.
+
+358
+00:39:08,220 --> 00:39:12,960
+أيه اللي هو مين؟ اللي هو بيه. واترجعه أين؟ واترجعه
+
+359
+00:39:12,960 --> 00:39:17,280
+الذي يعني كان ما حصلش حاجة. اللي عملناه بوقعناه.
+
+360
+00:39:17,380 --> 00:39:21,100
+ما رجعناه كل شيء في المكان. زي ما ييجي يخلى واحد
+
+361
+00:39:21,100 --> 00:39:25,700
+يمشي من هنا لغاية هناك. قصرت عليه ذلة نجلة من هنا
+
+362
+00:39:25,700 --> 00:39:29,100
+لغاية هناك. قدرت ذلة من هنا لغاية هناك ورجعت
+
+363
+00:39:29,100 --> 00:39:29,620
+مكانه.
+
+364
+00:39:32,720 --> 00:39:37,300
+يبقى اللي رجعتها اللي نسميها المعكوس ودك هي الاصل
+
+365
+00:39:37,300 --> 00:39:43,340
+يبحث الصورة على التمام يبقى هذا من تعريف ال one to
+
+366
+00:39:43,340 --> 00:39:47,640
+one function نجم يطلع على الرسمة وين دمين ال FN بس
+
+367
+00:39:50,710 --> 00:39:55,370
+الـ R هي الـ Range تبع الـ F و أين الـ Range تبع
+
+368
+00:39:55,370 --> 00:39:59,570
+الـ F inverse؟ ممتاز جدا، يبدأ الشخص يشوف أن هنا
+
+369
+00:39:59,570 --> 00:40:03,950
+الـ Domain تبع الـ F inverse هو R اللي هو الـ
+
+370
+00:40:03,950 --> 00:40:08,650
+Range تبع الـ F و كذلك الـ Range تبع الـ F inverse
+
+371
+00:40:08,650 --> 00:40:13,910
+هو دي اللي هو الـ Domain تبع من قبل الـ F، و بقى
+
+372
+00:40:13,910 --> 00:40:18,730
+كمان كويس يعني يا شباب، لو جيت سؤالكم سؤال بسيط
+
+373
+00:40:18,730 --> 00:40:26,130
+هذالو كانت النقطة a و b موجودة على منحنى الدالة f
+
+374
+00:40:26,130 --> 00:40:33,290
+من النقطة المناظرة لها على منحنى f inverse بيويت
+
+375
+00:40:34,570 --> 00:40:39,570
+يبقى A صورتها بيه وهذه الطريقة هيرمي لدّالة F يبقى
+
+376
+00:40:39,570 --> 00:40:44,690
+ال A و B موجود على رفم البيانة لدّالة F لكن ال B و
+
+377
+00:40:44,690 --> 00:40:48,910
+A موجودة على رفم البيانة لدّالة F inverse وهذا ما
+
+378
+00:40:48,910 --> 00:40:52,570
+سرشير إليه بعد قليل ان شاء الله تعالى
+
+379
+00:41:02,990 --> 00:41:08,550
+بنحل عليها أسئلة اكتر يبقى بداخله ياخد ال
+
+380
+00:41:08,550 --> 00:41:13,990
+properties of
+
+381
+00:41:13,990 --> 00:41:21,970
+f inverse of x الخاصية
+
+382
+00:41:21,970 --> 00:41:30,510
+الأولى f ال f inverse is the inverse
+
+383
+00:41:38,570 --> 00:41:44,530
+فانفرس لأ تساوي واحدة ال F وهذا ما أشارنا اليه قبل
+
+384
+00:41:44,530 --> 00:41:50,630
+قليل.لو كان ال F of A بدي ساوي ال B
+
+385
+00:41:57,360 --> 00:42:03,560
+أحنا في التعريف هنا قلنا ياشي F of A بدي أساول بيه
+
+386
+00:42:03,560 --> 00:42:08,980
+قلت أن أنا بدي أوصل لهذه اللي جال عليها لأن هذه
+
+387
+00:42:08,980 --> 00:42:14,100
+نتجت من هذه طيب أنا قلت له شو رأيك بدي أكثر على
+
+388
+00:42:14,100 --> 00:42:20,680
+الطرفين ب F inverse طبعا عندما جيت هنا قلت F
+
+389
+00:42:20,680 --> 00:42:23,100
+inverse لمين؟
+
+390
+00:42:26,070 --> 00:42:35,750
+بتصير الـ F inverse R V. طبعا هذا composition بين
+
+391
+00:42:35,750 --> 00:42:40,470
+الـ F و الـ F inverse. لو رجعنا لكالكلصية، هذا
+
+392
+00:42:40,470 --> 00:42:43,530
+اللي على الشمال تعريف مين؟ تعريف ال composition.
+
+393
+00:42:43,630 --> 00:42:47,890
+No functions. يعني هذا كأن مين؟ كأن
+
+394
+00:42:54,990 --> 00:42:59,510
+F inverse of A. الـ Composition من الدالة و
+
+395
+00:42:59,510 --> 00:43:03,370
+معاكسها بيعطينا ال identity function فهو مش هنقولك
+
+396
+00:43:03,370 --> 00:43:07,830
+identity لأن هذا أكبر منك شوية يبقى واحدة هتنغيط
+
+397
+00:43:07,830 --> 00:43:15,430
+تانية إذا هذا بيعطينا A تساوي F inverse of B تمام؟
+
+398
+00:43:15,430 --> 00:43:21,350
+يبقى هنا في التعريف اللي F inverse of Bما كان الـ
+
+399
+00:43:21,350 --> 00:43:25,690
+F of A يساوي الـ B وهي الـ F of A أخدناها تساوي
+
+400
+00:43:25,690 --> 00:43:30,110
+الـ B واخرناها تقفل من الـ F inverse فقلنا إن الـ
+
+401
+00:43:30,110 --> 00:43:33,990
+A بتساوي الـ F inverse of B دي بالك من كلام هذا
+
+402
+00:43:33,990 --> 00:43:37,290
+هناخد عليه مثال بعد قليل
+
+403
+00:43:49,170 --> 00:43:55,950
+هذا يجب أن يعطينا ان ال F انفرز لل F of X طبقا
+
+404
+00:43:55,950 --> 00:44:00,310
+لتعريف ال composition of functions فهذه الواحدة
+
+405
+00:44:00,310 --> 00:44:06,690
+سوف تلغي التانية جدتش جدتش بدي أقول X السؤال هو X
+
+406
+00:44:06,690 --> 00:44:11,510
+يا ترى في دمين الدلة F ولا في دمين الف انفرز
+
+407
+00:44:14,620 --> 00:44:18,040
+طلع اللي هو حاجة مكتوبة قدامك، بس طلع فيها، مش
+
+408
+00:44:18,040 --> 00:44:22,440
+تحذير يعني، في domain مين؟ لو ما كنتش في domain
+
+409
+00:44:22,440 --> 00:44:27,640
+الـF، هى بتقدر تأثر عليها الـF؟ مش ممكنية، لأن X
+
+410
+00:44:27,640 --> 00:44:32,380
+هذه اللي عندنا عنصر في domain مين؟ في domain الـX،
+
+411
+00:44:32,380 --> 00:44:38,860
+والـX هذه موجودة في domain الـF طيب، في المقابل
+
+412
+00:44:38,860 --> 00:44:40,940
+لرقم اربعة لغة F
+
+413
+00:44:46,840 --> 00:44:52,320
+بترى ان الـ composition بتكون F لل F inverse of X
+
+414
+00:44:52,320 --> 00:44:56,440
+بيبدو يساوي الـ X والـ X سبساوية موجودة دوية
+
+415
+00:44:59,460 --> 00:45:04,300
+في مستوى من؟ في مستوى الانفراد. تمام. يبقى هذه
+
+416
+00:45:04,300 --> 00:45:11,040
+موجودة في مستوى الانفراد. يبقى شايف الفرق ما بين
+
+417
+00:45:11,040 --> 00:45:16,240
+الاتنين. فنجي نقول هذه هي هذه، لأ، هذه مش هي هذه،
+
+418
+00:45:16,240 --> 00:45:19,860
+بختلفوا.يبدو أن هذا الكمبوزيشن من الـ F inverse
+
+419
+00:45:19,860 --> 00:45:24,180
+والـ F وهذا الكمبوزيشن من الـ F والـ I ولو راجعنا
+
+420
+00:45:24,180 --> 00:45:29,420
+بالذاكرة إلى الوراق لـ Calculus A بجينا نقول الـ F
+
+421
+00:45:29,420 --> 00:45:35,120
+composition G ليس بالضرورة للثانوية جي كمبوزيشن F
+
+422
+00:45:35,120 --> 00:45:40,220
+صحيح ولا لأ؟ وهذا يعني أنه اكسد في دومين الـ F لكن
+
+423
+00:45:40,220 --> 00:45:44,780
+اكسد في دومين الـ F inverse ورنج الـ Fمش الـ
+
+424
+00:45:44,780 --> 00:45:48,600
+domain تبع الـ يبقى فرق شاسع ما بين الأتنين. طبعا
+
+425
+00:45:48,600 --> 00:45:55,460
+ال .. نجل النقطة الخامسة والأخيرة من الخواص اللي
+
+426
+00:45:55,460 --> 00:46:03,200
+بنشير إليها. متى يمكن ان كل الدنيا معاكوس؟ يعني مش
+
+427
+00:46:03,200 --> 00:46:08,400
+كل دنيا لها معاكوس. صح ولا؟ احنا قبل شوية أخدنا
+
+428
+00:46:08,400 --> 00:46:12,660
+حلقة خاصة من يدنيا اللي هي one to one. ال one to
+
+429
+00:46:12,660 --> 00:46:12,800
+one
+
+430
+00:46:16,020 --> 00:46:20,800
+فإذا بقدر أرجع كل واحد لأصله، لكن لو أنصرهم
+
+431
+00:46:20,800 --> 00:46:26,620
+اشتركوا في نفس الصورة، لما بدي أرجعه؟ أوجهه لين؟
+
+432
+00:46:26,620 --> 00:46:32,160
+الله يعلم، بيبطل الصير الـ F inverse exists يبقى
+
+433
+00:46:32,160 --> 00:46:37,220
+الشرق الأساسي لوجود الـ F المصحوقة تكون الدالة one
+
+434
+00:46:37,220 --> 00:46:37,800
+to one
+
+435
+00:46:44,120 --> 00:46:53,140
+يبقى نقطة خامسة ال F has an inverse لها مراكز F
+
+436
+00:46:53,140 --> 00:47:04,360
+inverse if and only if ال F is one to one يبقى
+
+437
+00:47:04,360 --> 00:47:08,660
+من الآن فصاعدا لو جالي السؤال و جالي شوف
+
+438
+00:47:15,280 --> 00:47:19,200
+والله إذا طلعت الدالة one to one يبقى المعكوس
+
+439
+00:47:19,200 --> 00:47:23,760
+موجود مرة طلعت one to one يبقى المعكوس غير موجود
+
+440
+00:47:23,760 --> 00:47:29,040
+وكفى الله المؤمنين القتال.طب بعد ذلك بناخد بعض
+
+441
+00:47:29,040 --> 00:47:32,860
+الأمثلة التوضيحية عليها الخواص اللي بنحكي عنها
+
+442
+00:47:32,860 --> 00:47:33,240
+الآن.
+
+443
+00:47:59,020 --> 00:48:10,340
+بقول لك ال F of X يسار تماما X تقريب زائد تلاتة
+
+444
+00:48:10,340 --> 00:48:16,640
+شهرات ضيّلي M شهرات
+
+445
+00:49:00,400 --> 00:49:06,800
+تلاتة وطلع مطلوبين.المطلوب الأول اخبطني ان هذا
+
+446
+00:49:06,800 --> 00:49:08,360
+المعكوس موجود
+
+447
+00:49:10,610 --> 00:49:14,770
+أثبت لي أن هذا المعكوس يكون على مين؟ على الشكل
+
+448
+00:49:14,770 --> 00:49:18,350
+اللي عندنا هنا خلينا مع المطموق الأول بعد ذلك نروح
+
+449
+00:49:18,350 --> 00:49:19,350
+لمطموق الثاني
+
+450
+00:49:28,760 --> 00:49:31,780
+بنقول إذا طلعت الدالة one to one يبقى المعقوس
+
+451
+00:49:31,780 --> 00:49:36,200
+موجود وبعد ذلك بنروح ندور على قصة مين المعقوس شو
+
+452
+00:49:36,200 --> 00:49:40,700
+شكله هذا يبقى أنا هنا بدي أثبت أن هذا يبقى بدي
+
+453
+00:49:40,700 --> 00:49:45,840
+أثبت أن هذه مالها one to one بسيطة جدا كله يثبتها
+
+454
+00:49:45,840 --> 00:49:50,820
+one to one زي ما أثبتنا قبل شويه ممكن ناخد صورة
+
+455
+00:50:25,430 --> 00:50:32,150
+لو أضفنا سالب تلاتة للطرفين بصير تمانية اكس اكس
+
+456
+00:50:32,150 --> 00:50:39,670
+واحد تكييب يسوى تمانية اكس اتنين تكييب يبقى
+
+457
+00:50:39,670 --> 00:50:45,350
+نفسنا على تمانية بصير جداش اكس واحد تكييب يسوى اكس
+
+458
+00:50:45,350 --> 00:50:55,750
+اتنين تكييبخد الجدرى التالت يبقى X1 يبقى X2 يبقى
+
+459
+00:50:55,750 --> 00:51:04,590
+هنا ف ال F is one to one هذا سيعطينا ان ال F exist
+
+460
+00:51:07,790 --> 00:51:11,410
+أجي واحد تاني قال لي انت ليش تعملت كتير هيك؟ مكان
+
+461
+00:51:11,410 --> 00:51:15,190
+في السطر واحد و خلاصنا بقولك ايه؟ قال لي ماكانش
+
+462
+00:51:15,190 --> 00:51:18,130
+تقالة دول و خلاص هذه ماهي السهلة لما درجة تلتة
+
+463
+00:51:18,130 --> 00:51:21,330
+مستقلة لما درجة تانية هي موجبة على طول. قلت والله
+
+464
+00:51:21,330 --> 00:51:25,230
+كلامك مصبوح يعني لإن انا هادر ثلاثة في ثمانية
+
+465
+00:51:25,230 --> 00:51:29,790
+اربعة وعشرين X ثابت يجي دايما أول أكبر من أول
+
+466
+00:51:29,790 --> 00:51:33,990
+تساوي Zero يبقى increasing يبقى one to oneيبقى هذا
+
+467
+00:51:33,990 --> 00:51:39,450
+حل آخر لمين؟ لأن مثلا يبقى هنا لو جينا وقلنا
+
+468
+00:51:39,450 --> 00:51:44,090
+another solution، حل آخر.
+
+469
+00:51:56,710 --> 00:52:01,870
+بالإكس بالاستثناء هذا بدي يعطيك ان ال F is
+
+470
+00:52:01,870 --> 00:52:13,010
+increasing هذا بدي يعطيك ان ال F is one ten يبقى
+
+471
+00:52:13,010 --> 00:52:18,370
+هذا الطريقة او الطريقة الأولى سيال اتنين are the
+
+472
+00:52:18,370 --> 00:52:23,200
+sameبالحالة اللي تشوفها في رحلك ممكن تشتغل
+
+473
+00:52:23,200 --> 00:52:27,720
+باخلاصها من النقطة الأولى من المثلة بانجلا النقطة
+
+474
+00:52:27,720 --> 00:52:33,780
+الثانية جالي بيقول لي ان ال F inverse of X سوى نصف
+
+475
+00:52:33,780 --> 00:52:38,640
+الجذري التالت ل X ناقص ثلاثة كيف بتثبت له ان هذا
+
+476
+00:52:38,640 --> 00:52:45,100
+المعقوس تبعها؟ طاولة طاولة كيف يعني؟ بقول اه انت
+
+477
+00:52:45,100 --> 00:52:49,840
+كتبت خواص تنتينلو عملت ال composition من اليمين و
+
+478
+00:52:49,840 --> 00:52:55,220
+من الشمال سيظهر نفس المتغير الذي هو X صحيح ولا لأ؟
+
+479
+00:52:55,220 --> 00:53:04,360
+يرجى بالدرجة أقوله مقبل أولى أخد F inverse لل F of
+
+480
+00:53:04,360 --> 00:53:11,940
+X ويساوي ال F inverse ليه؟ وال F of X هي تمانية
+
+481
+00:53:17,910 --> 00:53:24,690
+تعريف الـ F inverse هو نص الجذر التالت لل element
+
+482
+00:53:24,690 --> 00:53:30,330
+اللي عندك ناقص تلاتة، يبقى هذا كله يعتبر element
+
+483
+00:53:30,330 --> 00:53:35,070
+في دمية مين؟ دمية ال F inverse، يبقى بناء العلم
+
+484
+00:53:35,070 --> 00:53:42,440
+يبدأ يصير نصالجنرال التالت هو الجنرال التالت X
+
+485
+00:53:42,440 --> 00:53:47,320
+اللي في domain of inverse هذه كلها في domain of
+
+486
+00:53:47,320 --> 00:53:55,200
+inverse إذا X أجى مكانها تماما X تكيّب زائد 3 عنده
+
+487
+00:53:55,200 --> 00:54:03,430
+هنا كماش ماقص 3 الشكل اللي عندنا هذابقص تلاتة مع
+
+488
+00:54:03,430 --> 00:54:11,690
+السلامة يبقى بصير نص الجدرى التالت لتمانية X تقريب
+
+489
+00:54:11,690 --> 00:54:20,130
+يبقى نص الجدرى التالت لاتنين X اتنين مع نص الوارد
+
+490
+00:54:20,130 --> 00:54:25,470
+السهل عليها من مر جداش X بكفي؟ لأ لأ لأ لأ لأ لأ
+
+491
+00:54:25,470 --> 00:54:26,410
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+492
+00:54:26,410 --> 00:54:27,870
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+493
+00:54:27,870 --> 00:54:27,870
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+494
+00:54:27,870 --> 00:54:30,130
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+495
+00:54:39,540 --> 00:54:45,620
+بدوا يسأل ال F او ال F inverse اللي هي النص في
+
+496
+00:54:45,620 --> 00:54:52,780
+الجدرى التالية لل X ماقص تلاتة. بده يشوف هذا كده و
+
+497
+00:54:52,780 --> 00:54:58,320
+بده يتعطيه. ال F لما اتأثر على العنصر يسوي تمانية
+
+498
+00:54:58,320 --> 00:55:04,450
+في مقعب العنصر زي التلاتة. يبقى هاي تمانية.ببنى
+
+499
+00:55:04,450 --> 00:55:11,490
+الكعب العنصر هذا يبقى ياله نص الجدرى التالت لل X
+
+500
+00:55:11,490 --> 00:55:18,650
+ماقص تلاتة هذا وهيه لكل تكريم وبتروح بيه فانيه
+
+501
+00:55:18,650 --> 00:55:26,410
+قداش برا زائد تلاتةلأن هدف لما اتأثر على الانصر
+
+502
+00:55:26,410 --> 00:55:32,850
+بيكون سوى تمانية في مكعب الانصر زائد تلاتة، تمام
+
+503
+00:55:32,850 --> 00:55:37,770
+التمام، يبقى هذا الكلام بيكون سوى تمانية فيه،
+
+504
+00:55:37,770 --> 00:55:44,910
+مستكيب، يبقى دياشر، تمان، هاي تمانالتقريب مع
+
+505
+00:55:44,910 --> 00:55:51,970
+الجدرى التالت الله سهل عليه بضل قدير X مراقص ثلاثة
+
+506
+00:55:51,970 --> 00:55:57,410
+وهي التلاتة اللي برا زائد تلاتة يفجر هذا الكلام
+
+507
+00:55:57,410 --> 00:56:02,530
+بالدراسة تمانية في الكلمة الله سهل عليها بضل قدير
+
+508
+00:56:02,530 --> 00:56:10,330
+X مراقص ثلاثة وهي التلاتة اللي برا هانا أظن بطلع
+
+509
+00:56:10,330 --> 00:56:16,010
+الجرم قدير Xيبقى أخدت ال composition اليمني و الله
+
+510
+00:56:16,010 --> 00:56:20,230
+ال composition الأشمال و أصلني لنفس النتيجة، إذا
+
+511
+00:56:20,230 --> 00:56:24,810
+المعنى لكلام الدالة هذه فعلا هي عكوس الدالة
+
+512
+00:56:24,810 --> 00:56:33,230
+الأصلية، يبقى بقالي بقول نص اللي هو ال .. اللي هو
+
+513
+00:56:33,230 --> 00:56:35,070
+النص ال general
+
+514
+00:56:39,300 --> 00:56:55,900
+is the inverse function of تمانية X تكييب زائد
+
+515
+00:56:55,900 --> 00:56:58,520
+تلتة
+
+516
+00:57:06,400 --> 00:57:11,920
+اللي هي أي طريقة بتاعة ال composition لإن ما
+
+517
+00:57:11,920 --> 00:57:17,260
+عرفنكش حتى هذه اللحظة كيف بدك تنجد المعكوس، مش
+
+518
+00:57:17,260 --> 00:57:21,900
+هنطول عليك بكرة ان شاء الله في محاضرة الغد، هنقفل
+
+519
+00:57:21,900 --> 00:57:26,820
+كيف تحسب المعكوس، هنا أطاني دالة و أطاني دالة
+
+520
+00:57:26,820 --> 00:57:30,910
+تنبغي يثبت إن هذه معكوس لهذهروحنا على القواس
+
+521
+00:57:30,910 --> 00:57:34,370
+استخدامناه وطلعنا ان هو دي المعكوس لكن في محاضرة
+
+522
+00:57:34,370 --> 00:57:39,130
+غدا ان شاء الله هنعلمك كيف بدك توجد معكوس الدالة
+
+523
+00:57:39,130 --> 00:57:43,550
+من الدالة الموجودة ان شاء الله حد بقى يتصرف هنا يا
+
+524
+00:57:43,550 --> 00:57:50,910
+شباب؟ او يستخدم؟ اه دي اتصرف من ال domain orange
+
+525
+00:57:50,910 --> 00:57:51,530
+ال inverse
+
+526
+00:57:54,150 --> 00:58:00,750
+Domain of the range inverse هو ال range تبع ال F
+
+527
+00:58:00,750 --> 00:58:05,890
+كتبناه قبل شويه صحيح ولا لأ؟ و ال range تبع ال F
+
+528
+00:58:05,890 --> 00:58:09,790
+inverse هو ال domain تبع ال F
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/RUWtLhZpb-g_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/RUWtLhZpb-g_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e6f9de245d262a4bb89930626ddcc60103d6f04b
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/RUWtLhZpb-g_raw.srt
@@ -0,0 +1,2044 @@
+1
+00:00:00,000 --> 00:00:02,680
+موسيقى
+
+2
+00:00:14,990 --> 00:00:19,870
+بنكمل ال section اللى ابتدأناه المرة الماضية وهو
+
+3
+00:00:19,870 --> 00:00:24,030
+ال hyperbolic functions طبعا عرفنا الدوالي
+
+4
+00:00:24,030 --> 00:00:26,910
+الزائدية الستة اللى هى ال hyperbolic functions
+
+5
+00:00:26,910 --> 00:00:30,830
+اللى هوا essential x, gaussial x, tensial x,
+
+6
+00:00:31,330 --> 00:00:35,610
+equotential x, sessial x, cotential x يبقى هم اللى
+
+7
+00:00:35,610 --> 00:00:41,130
+عرفناهم بدلات ال exponential function E و6 وEو-Xثم
+
+8
+00:00:41,130 --> 00:00:45,970
+رسمنا الرسومات الستة هذا آخر ما أخدنا المرة
+
+9
+00:00:45,970 --> 00:00:54,390
+الماضية الآن فينا بعض المتطابقات المرتبطة بالدوال
+
+10
+00:00:54,390 --> 00:01:00,370
+الزائدية يبقى بيننا نيجي هنا اللي هو some
+
+11
+00:01:00,370 --> 00:01:03,030
+identities
+
+12
+00:01:06,440 --> 00:01:21,700
+بعض الواقعات المتطابقات
+
+13
+00:01:21,700 --> 00:01:26,920
+المثلثية التي درسناها في Calculus Aأول متطابقة
+
+14
+00:01:26,920 --> 00:01:32,100
+كامة cosine تربيع ال X زي تصين تربيع ال X ساوي إذن
+
+15
+00:01:32,100 --> 00:01:38,240
+هنا في متطابقة مناظرة إلها تماماً أول متطابقة من
+
+16
+00:01:38,240 --> 00:01:44,180
+هذه المتطابقات وحنقول النقطة الأولى منها اللي هي
+
+17
+00:01:44,180 --> 00:01:51,760
+Gauss square X ماقصينش square X كله بده يساوي كده؟
+
+18
+00:01:51,760 --> 00:01:56,720
+بده يساوي واحد صحيحاللي هناك تبع تتبع المثلثية
+
+19
+00:01:56,720 --> 00:02:02,600
+كانت بمين بالذات البرهان very easy كيف very easy؟
+
+20
+00:02:02,600 --> 00:02:06,200
+أبدا المرة اللي فاتت كتبنا جداش اللي هو الجوش و
+
+21
+00:02:06,200 --> 00:02:10,800
+جداش الصنش فقلنا الصنش ال X هي E و ال 6 نقص E و S
+
+22
+00:02:10,800 --> 00:02:15,660
+نقص 6 على 2 و التاني E و 6 زادي E و S نقص 6 على 2
+
+23
+00:02:15,660 --> 00:02:19,440
+رابع عادي و رابع عادي و اطرحهم من بعض بطلع منك
+
+24
+00:02:19,440 --> 00:02:26,660
+واحد صحيح يبقى very easyمن هذه سأخرج تنتين الأولى
+
+25
+00:02:26,660 --> 00:02:33,260
+فيهم شكل التالي أقسم على جوش square يبقى لو قسمت
+
+26
+00:02:33,260 --> 00:02:38,100
+على جوش square يبقى لدي واحد نخص سنش square على
+
+27
+00:02:38,100 --> 00:02:43,300
+جوش square واليمين تانش square يبقى هنا تانش
+
+28
+00:02:43,300 --> 00:02:49,380
+square X يسوى واحد على جوش square اللي هو مقلب من
+
+29
+00:02:49,380 --> 00:02:58,450
+سنش square Xكمان هطلع واحدة تالتة من الاصلية اللى
+
+30
+00:02:58,450 --> 00:03:04,590
+عندنا هذه قبل ما جسمت على جوش square هجسم على سنش
+
+31
+00:03:04,590 --> 00:03:09,450
+square يبقى لو جسمت على سنش square بصير جوش square
+
+32
+00:03:09,450 --> 00:03:17,020
+على سنش squareاللي هو cot²x ناقص واحد يساوي واحد
+
+33
+00:03:17,020 --> 00:03:22,620
+على سنش square اللي هو مان اللي يكسش square X
+
+34
+00:03:22,620 --> 00:03:28,340
+بالشكل اللي عندنا هذا يبقى دول ثلاث متطابقات لكن
+
+35
+00:03:28,340 --> 00:03:33,420
+في الحقيقة هي متطابقة واحدة مش تلاتة نقلت انترا
+
+36
+00:03:33,420 --> 00:03:38,820
+بالولدناهم من الاصلي اللي موجود عندنانمر اتنين في
+
+37
+00:03:38,820 --> 00:03:46,300
+عندنا كمان اللي هو سنش اتنين X يساوي اتنين سنش ال
+
+38
+00:03:46,300 --> 00:03:53,410
+X في جوش ال Xالي اثبات بسيطة جدا عند قيمة السنش
+
+39
+00:03:53,410 --> 00:03:57,530
+وعند قيمة الجوش تضربوا في بعض تضربوا في اتنين
+
+40
+00:03:57,530 --> 00:04:03,250
+بيطلع عندك سنش اتنين اكس اللي يتساوم من اي أس
+
+41
+00:04:03,250 --> 00:04:09,210
+اتنين اكس ناقص اي أس ناقص اتنين اكس على اتنين يعني
+
+42
+00:04:09,210 --> 00:04:11,430
+كل اكس بيجي مكان مجداش
+
+43
+00:04:21,500 --> 00:04:28,040
+تشبه تماما تبعت الدل المثلثية الو ال sin 2x يسوى 2
+
+44
+00:04:28,040 --> 00:04:39,530
+sin x cos x نمر تلتة نقاش 2xجوش اتنين اكس اللي هي
+
+45
+00:04:39,530 --> 00:04:48,650
+عبارة عن جوش square X زائد سنش square X لأ بزايد
+
+46
+00:04:48,650 --> 00:04:53,910
+بناقص تبع اتنين كوصين اتنين X كوصين اتنين X تبع
+
+47
+00:04:53,910 --> 00:04:58,130
+الدالة المثلثية كانت كوصين اتنين X يساوي كوصين
+
+48
+00:04:58,130 --> 00:05:05,260
+تربيع X ناقص تربيع X هذا بمين؟ بالزايدفي كمان
+
+49
+00:05:05,260 --> 00:05:10,940
+صغتين أخرين لجوش اتنين اكس، شو الصغتين الأتنين
+
+50
+00:05:10,940 --> 00:05:16,000
+هدول؟ يساوي، هذه الصيغة الأولى مكتوبة بدلالة السنش
+
+51
+00:05:16,000 --> 00:05:20,280
+والجوش، أنا مرة بدي اكتبها بدلالة الجوشو مرة ثانية
+
+52
+00:05:20,280 --> 00:05:26,040
+بدي اكتبها بدل ال 8 سنش يبقى بدي ادى للأولى اده و
+
+53
+00:05:26,040 --> 00:05:27,860
+اده و اده و اده و اده و اده و اده و اده و اده و
+
+54
+00:05:27,860 --> 00:05:28,260
+اده و اده و اده و اده و اده و اده و اده و اده و
+
+55
+00:05:28,260 --> 00:05:29,540
+اده و اده و اده و اده و اده و اده و اده و اده و
+
+56
+00:05:29,540 --> 00:05:29,620
+اده و اده و اده و اده و اده و اده و اده و اده و
+
+57
+00:05:29,620 --> 00:05:30,960
+اده و اده و اده و اده و اده و اده و اده و اده و
+
+58
+00:05:30,960 --> 00:05:38,830
+اده و اده و اده و اده و اده و اده و ادهيبقى من هنا
+
+59
+00:05:38,830 --> 00:05:47,150
+من الأولى sin²x يساوي cos²x ناقص واحد إذا لو شيلت
+
+60
+00:05:47,150 --> 00:05:53,430
+sin² و حطيت بذلك cos² ناقص واحد بصير اتنين sin²
+
+61
+00:05:53,430 --> 00:05:59,890
+ناقص واحد يبقى هذه اتنين cos²
+
+62
+00:06:07,550 --> 00:06:16,040
+from one من الأولطيب هذا الصيغة التانية بدالي
+
+63
+00:06:16,040 --> 00:06:20,920
+للصيغة التالتة بدل ما كتبتها بدلالة الجوش بدي
+
+64
+00:06:20,920 --> 00:06:26,520
+اكتبها بدلالة two cinch اذا الجوش square هذه ليه
+
+65
+00:06:26,520 --> 00:06:32,360
+تساوي cinch square زائد واحد عندك cinch square و
+
+66
+00:06:32,360 --> 00:06:36,080
+عندك cinch square يبقى اتنين cinch square زائد
+
+67
+00:06:36,080 --> 00:06:42,950
+واحديبقى هذه اتنين sinh square x زائد واحد وهذا
+
+68
+00:06:42,950 --> 00:06:49,410
+كمان from one زي ما هى اذا اصبح عندى جوش اتنين اكس
+
+69
+00:06:49,410 --> 00:06:55,270
+لها تلات صيغ زي ما كوصين اتنين اكس لها تلات صيغ
+
+70
+00:06:55,270 --> 00:07:02,310
+تماما مع الفرق في الاشارات طب بدى اروح للمتطابق
+
+71
+00:07:02,310 --> 00:07:08,300
+الرابعة الرابعة بدى اطلعها من التلتةالرابعة نطلع
+
+72
+00:07:08,300 --> 00:07:15,980
+من التالتة كيف؟ بدها جيب جوش
+
+73
+00:07:15,980 --> 00:07:21,740
+square X بدلالة جوش 2X بنقول بسيطة انجل الواحد على
+
+74
+00:07:21,740 --> 00:07:27,520
+الشجة التانية و اجسم على مين؟ بتحصل على مين؟ على
+
+75
+00:07:27,520 --> 00:07:35,240
+جوش square X بده يساويتمام يبقى جوش square X هات
+
+76
+00:07:35,240 --> 00:07:41,640
+هات هنا بيصير جوش 2X زائد وكل جسمها اتنين يعني
+
+77
+00:07:41,640 --> 00:07:51,060
+النص في مين؟ في جوش 2X زائد 1 تمام هذه هي النقطة
+
+78
+00:07:51,060 --> 00:07:57,040
+الأولى النقطة الثانيةطبعا يجب ان يعملها بنفس
+
+79
+00:07:57,040 --> 00:08:01,560
+الطريقة يجب ان يجيب من هنا cinche square يبقى
+
+80
+00:08:01,560 --> 00:08:08,580
+cinche square x يساوي طبعا يجيب من هنا على الشاشة
+
+81
+00:08:08,580 --> 00:08:14,300
+التانية يجيب من شارة سالب وجسم على اتنين يبقى نصف
+
+82
+00:08:14,300 --> 00:08:21,900
+في جوش اتنين اكس ماقص واحد بالشكل اللي عندنالو
+
+83
+00:08:21,900 --> 00:08:26,860
+رجعنا بالذاكرة إلى الورق للدول المثلثية كان عندك
+
+84
+00:08:26,860 --> 00:08:32,220
+cos تربيه x يسوى النص في واحد زائد cos اتنين x
+
+85
+00:08:32,220 --> 00:08:39,440
+وكان عندك sin تربيه ال x نص في واحد ناقص cos اتنين
+
+86
+00:08:39,440 --> 00:08:43,780
+x الفرق بينهم إشارة ناقص وهذا الكمال الفرق بينهم
+
+87
+00:08:43,780 --> 00:08:48,240
+إشارة ناقص زي ما انت شايف هذا النقطة الرابعة نجي
+
+88
+00:08:48,240 --> 00:08:53,370
+للنقطة الخامسةالنقطة الخامسة بدي اياكوا ان تطلعوها
+
+89
+00:08:53,370 --> 00:08:58,830
+لحالكوا من تعريف الأتنين كيف؟ بدي هاي جوش ال X
+
+90
+00:08:58,830 --> 00:09:04,530
+زائد سنش ال X يساوي يلا اجمعلي شفة و عندك هي
+
+91
+00:09:04,530 --> 00:09:09,410
+مكتوبة معاك هي جيمة الجوش بدلات ال exponential و
+
+92
+00:09:09,410 --> 00:09:12,670
+جيمة السنش بدلات ال exponential و يلا اجمعوا و
+
+93
+00:09:12,670 --> 00:09:19,450
+اعطيني النتج يلا مين جمعها؟إيه إتنين إيه والإكس
+
+94
+00:09:19,450 --> 00:09:23,550
+على إتنين؟ يعني إيه والإكس بس يبقى النتيجة فعلا
+
+95
+00:09:23,550 --> 00:09:29,850
+إيه والإكس هذا النقطة من الأولى النقطة الثانية لو
+
+96
+00:09:29,850 --> 00:09:37,930
+قلت جوش ال X ماقصش ال X يالا أعطينا النتيجة سالب
+
+97
+00:09:37,930 --> 00:09:49,820
+إيه والسالب X يبقى إيه والسالب Xطبعا، يبقى دول
+
+98
+00:09:49,820 --> 00:09:53,280
+استنتاجهم استنتاج بكل بساطة جامع عادى جدا من
+
+99
+00:09:53,280 --> 00:09:58,620
+التعريف يبقى لكن هذه أفادنى انه تبصير المقدار هذا
+
+100
+00:09:58,620 --> 00:10:02,120
+كله بدل مكتب اذا لجيت اتنين بقدر أشيله محق بدلهم
+
+101
+00:10:02,120 --> 00:10:07,220
+واتنين هدول اذا لجيتهم بقدر أشيله محق بدلهم طيب
+
+102
+00:10:07,220 --> 00:10:12,360
+نمرى ستة بدخليك كمان انت اطلعها لحالك اطلعلي في
+
+103
+00:10:12,360 --> 00:10:17,630
+جوش عندك في التعريف يلا افتح على التعريف عندكجوش
+
+104
+00:10:17,630 --> 00:10:21,790
+ال X يُسمى E و ال 6 زي دي و صناعة ال 6 على 2
+
+105
+00:10:21,790 --> 00:10:27,990
+مظبوط؟ بدي أشوف هذي odd و الله even يبقى بدي أشيل
+
+106
+00:10:27,990 --> 00:10:32,330
+كل X و أحط مكانها E و ال 6 يلا أشيل و أشوف هذي
+
+107
+00:10:32,330 --> 00:10:37,370
+تتغير و الله بيظن هي هي هي هي هي مظبوط؟ إذن الجوش
+
+108
+00:10:37,370 --> 00:10:43,810
+عبارة عن even function طيب فلا نلسشهو اللي هي
+
+109
+00:10:43,810 --> 00:10:49,210
+مقلوبة؟ طلع
+
+110
+00:10:49,210 --> 00:10:59,760
+فيها كويسeven زيها اذا انا عندي تنتين من هدول even
+
+111
+00:10:59,760 --> 00:11:06,180
+والباقي الأربعة odd كل الأربعة الباقية odd يبجي
+
+112
+00:11:06,180 --> 00:11:15,900
+هنا بجي بقول اللي هو سيش ال X and جوش ال X اللي هي
+
+113
+00:11:15,900 --> 00:11:19,040
+مقلوبة are even
+
+114
+00:11:23,120 --> 00:11:35,000
+but the others are odd لكن البقيات كله إيش؟ كله
+
+115
+00:11:35,000 --> 00:11:42,120
+oddيبقى تنتين even والاربعة الأخرى يتمالهم odd زي
+
+116
+00:11:42,120 --> 00:11:47,560
+تماما في الدوال المثلثية كان الكوصة عين X وسقل X
+
+117
+00:11:47,560 --> 00:11:51,600
+اتنين are even والاربعة odd بالشكل اللي قلنا هذا
+
+118
+00:11:51,600 --> 00:11:59,320
+نجي الأن لمشتقة الدوال الزائدية يرجى بالذات
+
+119
+00:11:59,320 --> 00:12:01,480
+لدريفاتيف
+
+120
+00:12:03,110 --> 00:12:08,870
+or high parabolic functions
+
+121
+00:12:11,780 --> 00:12:19,180
+مش تقت الدوالي زادية باجي بقوله if ال U is a
+
+122
+00:12:19,180 --> 00:12:27,100
+differentiable function of X then نمره واحد بدنا
+
+123
+00:12:27,100 --> 00:12:37,180
+دي على دي X لمن؟ ل essential U يساوي بدوش اكتبلك
+
+124
+00:12:37,180 --> 00:12:41,930
+الجواب بده اخليك انت تطلع الجوابتشوف التعريف
+
+125
+00:12:41,930 --> 00:12:47,270
+السُنش عندك يالا اللي هي نص في U ال 6 زي D و S
+
+126
+00:12:47,270 --> 00:12:48,930
+ناقص X اشتقها
+
+127
+00:12:53,510 --> 00:12:59,710
+نص زي ما هو واليو سكس زي ما هي وزاد او عندك هنا
+
+128
+00:12:59,710 --> 00:13:04,990
+ناقص يوس ناقص اكس لما اشتغل نفسه في سالب يصير موجب
+
+129
+00:13:04,990 --> 00:13:11,130
+يعني مين؟ جوش إذا انتفضل السنش بجوش يبقى هذه جوش
+
+130
+00:13:11,130 --> 00:13:17,830
+اليو في الدي يورو على دي اكس نمر اثنان بدنا دي على
+
+131
+00:13:17,830 --> 00:13:24,410
+دي اكس لجوش اليوسالب، سالب، سالب، سالب، سالب،
+
+132
+00:13:24,410 --> 00:13:27,750
+سالب، سالب، سالب، سالب، سالب
+
+133
+00:13:31,820 --> 00:13:36,840
+موجب، يعني مش زي الدول المثلثية، تفاضل قصان بيسالب
+
+134
+00:13:36,840 --> 00:13:42,200
+صين هنا الجوش، فاقلها بيطلع سنش، تمام؟ إذا تفاضل
+
+135
+00:13:42,200 --> 00:13:47,860
+السنش بيجوش و تفاضل الجوش بيسنش طيب، نمر تلاتة،
+
+136
+00:13:47,860 --> 00:13:57,160
+بيبنا دي على DX لتانش ال X يزاوييالا باختصار هيك
+
+137
+00:13:57,160 --> 00:14:01,920
+تانش هي سنش على جوش يالا المقام في مشتقة البص نقص
+
+138
+00:14:01,920 --> 00:14:06,460
+البص في مشتقة المقام على مربع المقام الأصلي علما
+
+139
+00:14:06,460 --> 00:14:12,220
+بإنما جوش square نقص سنش square يساوي واحد صحيح
+
+140
+00:14:12,220 --> 00:14:19,400
+يالا شوف هالي كده بتطلع يالا بسرعة أيوة كده؟ كده
+
+141
+00:14:19,400 --> 00:14:25,820
+يا راجل قوله غير تاج اللهبطلع واحد على جوش square
+
+142
+00:14:25,820 --> 00:14:31,300
+صح ولا لأ؟ واحد على جوش square يومين سيش square
+
+143
+00:14:31,300 --> 00:14:40,580
+إذا انت فاضل تنش بسيش square U في DU على DX الرابع
+
+144
+00:14:40,580 --> 00:14:49,980
+بدنا D على DX ل potential U potential U
+
+145
+00:14:49,980 --> 00:14:57,210
+و U الساوينفس الطريقة جوش فوق وجوش انش تحت يبقى
+
+146
+00:14:57,210 --> 00:15:06,750
+سالب كسش square U في الـ Du على DX ننتقل الآن إلى
+
+147
+00:15:06,750 --> 00:15:15,950
+النقطة الخامسة بدنا D على DX لمين؟ لسش الـU ويساوي
+
+148
+00:15:15,950 --> 00:15:23,300
+تفاضل السك بجدشسك X في تم ال X بس هذه السش بسالب
+
+149
+00:15:23,300 --> 00:15:33,180
+سش تانش يبقى هذه سالب سش ال X في تانش سش ال U سش
+
+150
+00:15:33,180 --> 00:15:40,120
+ال U في تانش ال U في DU على DX أخر حاجة نمره 6D
+
+151
+00:15:40,120 --> 00:15:47,760
+على DX لكو سش ال U سالب كو سش ال U كو تانش
+
+152
+00:16:01,270 --> 00:16:07,930
+أول تلاتة بالموجب وتاني تلاتة بالسالب موجب موجب
+
+153
+00:16:07,930 --> 00:16:09,690
+موجب سالب سالب سالب
+
+154
+00:16:23,680 --> 00:16:26,780
+بترجع الاصطناع الاصطناع الاصطناع الاصطناع الاصطناع
+
+155
+00:16:26,780 --> 00:16:26,840
+الاصطناع الاصطناع الاصطناع الاصطناع الاصطناع
+
+156
+00:16:26,840 --> 00:16:28,840
+الاصطناع الاصطناع الاصطناع الاصطناع الاصطناع
+
+157
+00:16:28,840 --> 00:16:32,000
+الاصطناع الاصطناع الاصطناع الاصطناع الاصطناع
+
+158
+00:16:32,000 --> 00:16:34,140
+الاصطناع الاصطناع الاصطناع الاصطناع الاصطناع
+
+159
+00:16:34,140 --> 00:16:34,160
+الاصطناع الاصطناع الاصطناع الاصطناع الاصطناع
+
+160
+00:16:34,160 --> 00:16:34,500
+الاصطناع الاصطناع الاصطناع الاصطناع الاصطناع
+
+161
+00:16:34,500 --> 00:16:35,680
+الاصطناع الاصطناع الاصطناع الاصطناع الاصطناع
+
+162
+00:16:35,680 --> 00:16:37,180
+الاصطناع الاصطناع الاصطناع الاصطناع
+
+163
+00:16:40,990 --> 00:16:46,610
+لأ لأ مش السنش بتقول E أُس X ناقص E أُس ناقص X على
+
+164
+00:16:46,610 --> 00:16:51,370
+اتنين بده اشيل X وحط مكانه سالب X يعني هو بيصير E
+
+165
+00:16:51,370 --> 00:16:57,850
+أُس سالب X ناقص E أُس X على اتنين خد إشارة سلب برا
+
+166
+00:16:57,850 --> 00:17:01,050
+بيصير E أُس X ناقص E أُس ناقص X على اتنين يعني
+
+167
+00:17:01,050 --> 00:17:07,590
+سالب سنش ال X يعني أصبح F أُس سالب X يساوي سالب F
+
+168
+00:17:07,590 --> 00:17:12,220
+أُس X it is an odd functionمظبوط ولا لا؟ اتلخبط من
+
+169
+00:17:12,220 --> 00:17:15,160
+ال session. يا زماده خلاص هو اتلخبطون عدل يعني، هو
+
+170
+00:17:15,160 --> 00:17:20,560
+غلط فيه، هو غلط في المصحف. خلاص ليه؟ خلاص، خلاص.
+
+171
+00:17:21,040 --> 00:17:25,720
+الواحد يسأل امليه قال ولم تؤمن قال بلى، ولكن
+
+172
+00:17:25,720 --> 00:17:31,880
+ليطمئن قلبي، حابب اتأكد، وهذا حصل مع نبينا إبراهيم
+
+173
+00:17:31,880 --> 00:17:35,540
+عليه السلام مع الله سبحانه وتعالى. والراجل يا
+
+174
+00:17:35,540 --> 00:17:39,760
+عزيزي لما نيسأل سؤاله ونجاوب عليه.حابب يتأكد قال
+
+175
+00:17:39,760 --> 00:17:44,180
+لك ربما لكون أخطأنا فاجتهد فوجد نجتهده في غير محق
+
+176
+00:17:44,180 --> 00:17:49,900
+ليه ومن اجتهد فأصف له أجران ومن انتهد فأقطف له أجر
+
+177
+00:17:49,900 --> 00:17:54,160
+واحد يعني ماعناش مشكلة في هذه خليكم معنا خليكم
+
+178
+00:17:54,160 --> 00:17:58,980
+معنا خلاص بجدطيب، زي ما فيه مشتقات، معناته فيه
+
+179
+00:17:58,980 --> 00:18:04,720
+تكاملات، إذا بدنا نروح للتكاملات تانية، يبقى هنا
+
+180
+00:18:04,720 --> 00:18:10,780
+بدنا نيجي لأول تكامل من هذه التكاملة، خلّا معايا
+
+181
+00:18:10,780 --> 00:18:14,560
+كل سنة، طبعا زي ما تجيب في مستقبل، مشتقة السنش
+
+182
+00:18:14,560 --> 00:18:20,030
+بيجوش، إذا مشتقة الجوشمشتقت الجوش بالسنش إذا
+
+183
+00:18:20,030 --> 00:18:26,050
+متكامل السنش بجوش يبقى على كل الخط الان نمرة واحد
+
+184
+00:18:26,050 --> 00:18:32,830
+تكامل لسنش ال X DX بدي يعطيلك جوش ال X زائد
+
+185
+00:18:32,830 --> 00:18:39,810
+constant C نمرة اتنين بدنا تكامل لجوش ال X بدي
+
+186
+00:18:39,810 --> 00:18:48,410
+ساوي ال همين DXبدي يساوي اللي هو سنش LX زائد كل
+
+187
+00:18:48,410 --> 00:18:53,750
+صندسي، نمرة تلت طيب
+
+188
+00:18:53,750 --> 00:18:56,370
+شيفاه، لو بدنا تكامل التانش
+
+189
+00:19:01,670 --> 00:19:05,690
+سلشة على جوش البسطى مش ساقة المقارنة يبقى لنا
+
+190
+00:19:05,690 --> 00:19:09,050
+المقارنة مش هذا اللي بديه خلّيه مع الأسلحة اللي
+
+191
+00:19:09,050 --> 00:19:17,940
+بدك هيها بقول اه بدي تكامل لسشة square x dxتفاهم
+
+192
+00:19:17,940 --> 00:19:27,540
+التنش بسيش سكوير بمين؟ بتنش يبقى هنا تنش ال X زائد
+
+193
+00:19:27,540 --> 00:19:33,520
+كونستانسي نمرة أربعة بدي تكامل كسيش سكوير X
+
+194
+00:19:36,900 --> 00:19:42,680
+سالب كتانش يبقى سالب كتانش ال X
+
+195
+00:20:25,730 --> 00:20:34,320
+طيب يبقى ضال مين؟الاربع دوال زائدية الأخرى خليهم
+
+196
+00:20:34,320 --> 00:20:40,440
+مع الأمثلة ليه؟ فعليهم مع الأمثلة طيب هنشوف كيف
+
+197
+00:20:40,440 --> 00:20:44,800
+هنخليهم مع الأمثلة يبقى الأن نذهب إلى الأمثلة
+
+198
+00:20:44,800 --> 00:20:50,360
+لغاية هنا شباب احنا خلصنا الشطر الأول من الجزء
+
+199
+00:20:50,360 --> 00:20:55,870
+النظري في هذا ال sectionو لسه في جزء تاني اللي هو
+
+200
+00:20:55,870 --> 00:21:01,030
+معكوس الدول الزائدية لكن بنقول لك خدك راست شوية
+
+201
+00:21:01,030 --> 00:21:05,870
+هنا و خلينا نحل مجموعة من الأمثلة مجموعة من
+
+202
+00:21:05,870 --> 00:21:12,190
+الأمثلة على ما سبقت دراسته المثال الأول examples
+
+203
+00:21:12,190 --> 00:21:16,330
+أول
+
+204
+00:21:16,330 --> 00:21:27,560
+مثال بيقول ifجوش ال X بده يساوي تلتاشر على خمسة و
+
+205
+00:21:27,560 --> 00:21:34,480
+ال X greater than zero فاين اجد انه نمرة واحد او
+
+206
+00:21:34,480 --> 00:21:44,860
+نمرة A بدنا يا سيدي اللي هو مين تانش ال X and اللي
+
+207
+00:21:44,860 --> 00:21:55,130
+هو مين and سش ال Xالاتنين هدول نمرى بيه بدنا the
+
+208
+00:21:55,130 --> 00:21:59,210
+value of x
+
+209
+00:22:16,940 --> 00:22:21,640
+بنعطيني جداش القيمة العددية لجوش ال X اللي 13 على
+
+210
+00:22:21,640 --> 00:22:27,440
+5 ومن خلالها طلب مني تلت شغلات شغلة الأولى بده
+
+211
+00:22:27,440 --> 00:22:33,480
+جداش مقدار تانش X الثانية جداش قيمة سش X ثمانية
+
+212
+00:22:33,480 --> 00:22:38,920
+جداش القيمة الحقيقية ل X اللي خلتلي المقدار هذا
+
+213
+00:22:38,920 --> 00:22:42,920
+يسوى جداش 13 على 5 solution
+
+214
+00:22:45,390 --> 00:22:50,190
+يبقى بدنا نيجي للنقطة الأولى اللى هى نمرة A اظن فى
+
+215
+00:22:50,190 --> 00:22:57,150
+جزء منهم بقدر اجيبه مباشرة اللى هم سش بقول بسيطة
+
+216
+00:22:57,150 --> 00:23:07,700
+سش ال X بدي ساوي واحد على جوش ال Xفالجوش معروفة
+
+217
+00:23:07,700 --> 00:23:12,500
+اللي 13 على 5، ايه من ال social؟ يسوى خمسة على
+
+218
+00:23:12,500 --> 00:23:20,020
+تلتاشر، يبقى هذه بلغة سهلة جدا، الآن هيا عندنا صار
+
+219
+00:23:20,020 --> 00:23:27,020
+اللي هو ال social و بدنا الآن التانش بدنا التانش،
+
+220
+00:23:27,020 --> 00:23:34,160
+طبعا قدامك أكثر من طريقطريق الأول أنه أنا أخد قوش
+
+221
+00:23:34,160 --> 00:23:39,620
+square X ناقص سنش square X يسوي قداش واحد، من هذه
+
+222
+00:23:39,620 --> 00:23:44,900
+بحسب السنش، بصير السنش عندي و القوش عندي، بقدر
+
+223
+00:23:44,900 --> 00:23:49,760
+أجيبله التاني، هذا تفكير، تفكير آخر، بقول لأ أنت
+
+224
+00:23:49,760 --> 00:23:54,500
+حسبت السنش قداش يسوي، بقول له أيوة، قال احنا عنده
+
+225
+00:23:54,500 --> 00:24:00,740
+متفادقة، بتقول إن واحدنقص تانش سكوير يساوي من؟ سش
+
+226
+00:24:00,740 --> 00:24:04,260
+سكوير نقول الله كلامك مظبوط نقدر نجيب التانية
+
+227
+00:24:04,260 --> 00:24:11,580
+مباشرة يبقى باجي بقوله and ايش عندنا احنا؟ اللي هو
+
+228
+00:24:11,580 --> 00:24:22,440
+من واحد ناقص تانش سكوير تانش سكوير X بده يساوي سش
+
+229
+00:24:22,440 --> 00:24:30,690
+سكوير Xهذه النقطة الثانية في أول متطابقة أخذناها،
+
+230
+00:24:30,690 --> 00:24:35,290
+إذا بدنا نعود فيها مباشرة يبقى هاي الواحد ناقص
+
+231
+00:24:41,150 --> 00:24:46,890
+بدو يساوي الله أعلم تانش بدنا ياما سش سكوير هي
+
+232
+00:24:46,890 --> 00:24:54,170
+السش إذا الخمسة على تلتاشر الكل تربيه هذا بده
+
+233
+00:24:54,170 --> 00:25:01,710
+يعطيك ما يأتي انه تانش square X بده يساويهنا اللي
+
+234
+00:25:01,710 --> 00:25:09,870
+هو مين واحد ناقص واحد ناقص خمسة وعشرين تلتاش في
+
+235
+00:25:09,870 --> 00:25:16,710
+تلتاش بمية وتسعة وستين يبقى بناء عليه أصبح تانش
+
+236
+00:25:16,710 --> 00:25:21,550
+square X يساوي المضاعف المشترك لليه اتنين مية
+
+237
+00:25:21,550 --> 00:25:26,870
+وتسعة وستين بصير مية وتسعة وستين ناقص خمسة وعشرين
+
+238
+00:25:26,870 --> 00:25:33,800
+اللي هو مية واربعة واربعينكويس هذا بده يعطيلك ان
+
+239
+00:25:33,800 --> 00:25:42,280
+تانش ال X بده ساوي اتناشر على تلتاشر بإشارة موجبة
+
+240
+00:25:42,280 --> 00:25:47,480
+لإن في البداية اتاني X مالها greater than zero
+
+241
+00:25:47,480 --> 00:25:52,160
+كويس يبقى أصبح تانش X اللي بده إياها اللي عبارة عن
+
+242
+00:25:52,160 --> 00:25:55,420
+اتناشر على تلتاشر وبالتالي بكون انت هنا من المطلوب
+
+243
+00:25:55,420 --> 00:25:58,820
+الأول ايه هو الفرق يعني ممكن احنا طريقة المجاور
+
+244
+00:25:58,820 --> 00:26:07,760
+المقابلهذه دوالة مثلثة مثلثة مثلثة مثلثة مثلثة
+
+245
+00:26:07,760 --> 00:26:10,980
+مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة
+
+246
+00:26:10,980 --> 00:26:12,340
+مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة
+
+247
+00:26:12,340 --> 00:26:15,100
+مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة
+
+248
+00:26:15,100 --> 00:26:18,380
+مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة
+
+249
+00:26:18,380 --> 00:26:18,380
+مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة
+
+250
+00:26:18,380 --> 00:26:22,400
+مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة مثلثة
+
+251
+00:26:22,400 --> 00:26:26,960
+مثلثة مثل
+
+252
+00:26:28,760 --> 00:26:31,820
+أه يمكن يجربوا لبعض، بس يمكن يجربوا ليس لبعض،
+
+253
+00:26:31,820 --> 00:26:37,660
+تمام؟ احنا بنقول شكلًا تفرق عن بعض بالحرف إتش، لكن
+
+254
+00:26:37,660 --> 00:26:42,360
+هذا الفرق جعل فرق مفتاشة ما بين الأثنين طيب إذا
+
+255
+00:26:42,360 --> 00:26:46,580
+بتلاقي المثلث كل عنه، خلّيني أستفيد برضه، مش غلط،
+
+256
+00:26:46,580 --> 00:26:51,660
+ماشي؟ طيب، خلصوا المطلوب الأول إن هو نمرة A، بدنا
+
+257
+00:26:51,660 --> 00:26:58,660
+نيجي لنمرة Bنمر بيه ويقول هاتلي قيمة X التي جعلت
+
+258
+00:26:58,660 --> 00:27:05,140
+هذا المقدار يساوي تلات عشر على خمسة بقوله يبقى انت
+
+259
+00:27:05,140 --> 00:27:13,460
+عند جوش ال X بده يساويولو كنا ماخدين المعكوز كما
+
+260
+00:27:13,460 --> 00:27:17,260
+قلنا X يساوي جوش Inverse بس انا مااخدناش اللي ممكن
+
+261
+00:27:17,260 --> 00:27:21,960
+نعرفوش تمام لكن اخدنا ال exponential اللي الجوش
+
+262
+00:27:21,960 --> 00:27:26,760
+بدلات ال exponential E وال 6 زائد E و اصناق ال 6
+
+263
+00:27:26,760 --> 00:27:33,260
+على 2 هذا اللي بده يساوي جداش اللي هو 13 على 5
+
+264
+00:27:34,920 --> 00:27:41,280
+المعادلة اللى عندنا هذه حولنا مسألة بدلالة ال EOS
+
+265
+00:27:41,280 --> 00:27:45,560
+X ال EOS X هذه بقدر عليها بقدر اشتغل بيمين و شمال
+
+266
+00:27:45,560 --> 00:27:49,820
+زي ما بدى هذه المعادلة لو روح ضرب ضرب التبادل يبصى
+
+267
+00:27:49,820 --> 00:27:57,160
+لنا ايه؟ خمسة EOS X زائد خمسة EOS نقص X يسبج اداش
+
+268
+00:27:57,160 --> 00:28:03,650
+ستة و عشرينهذه الأس سالب والأس موجب لا أعجبني فهو
+
+269
+00:28:03,650 --> 00:28:06,870
+يريد أن يتخلص من السالب و يتعامل معاه يعني يريد أس
+
+270
+00:28:06,870 --> 00:28:12,490
+واحد يتعامل معاه إذا لو رحت ضربت طرفي المعادلة في
+
+271
+00:28:12,490 --> 00:28:20,310
+E أس X بس هنا لدينا خمسة E أس X لكل تربيع زائد
+
+272
+00:28:20,310 --> 00:28:27,180
+خمسة بده يساوي لهو ستة وعشرين E أس Xيبقى قربنا
+
+273
+00:28:27,180 --> 00:28:32,120
+الطرفين في E أس X وبالتالي تخلصنا من مين؟ من الأس
+
+274
+00:28:32,120 --> 00:28:37,980
+السالف طب بتعملها معادلة صفرية يبقى خمسة في E أس
+
+275
+00:28:37,980 --> 00:28:46,660
+اتنين X ماقص ستة وعشرين E أس X يبقى زائد خمسة زائد
+
+276
+00:28:46,660 --> 00:28:52,100
+خمسة كلها تساوي مين؟ تساوي Zero زي ما انت شايف هذه
+
+277
+00:28:52,100 --> 00:28:59,950
+أصبحت معادلة من الدرجة الثانيةفى المتغير E أُس X E
+
+278
+00:28:59,950 --> 00:29:04,070
+أُس X الكل تربيع كل صين في ال E أُس X وهنا كل صين
+
+279
+00:29:04,070 --> 00:29:07,790
+كله بده يساوي Zero يبقى بدنا نروح نحل معادلة
+
+280
+00:29:07,790 --> 00:29:12,700
+الدرجة الثانيةبتحللها تحليل، ماشي، بتقدرش بتروح
+
+281
+00:29:12,700 --> 00:29:17,200
+على القانون، بصبون؟ طب نشوف بنقدر نحللها و الله
+
+282
+00:29:17,200 --> 00:29:21,620
+إذا ما نقدرش علمونا في الإعدادية إنه ممكن تسوي مقص
+
+283
+00:29:21,620 --> 00:29:27,320
+أو ممكن تحلل على طول، تمام؟ لو جينا لهذه قلنا خمسة
+
+284
+00:29:27,320 --> 00:29:34,950
+في E وال6 وهنا E وال6 لوحدها فقطهذه اللي بعد خمسة
+
+285
+00:29:34,950 --> 00:29:39,010
+في واحد يبقى هذا الخمسة وهذا الواحد الإشارة زائد
+
+286
+00:29:39,010 --> 00:29:43,930
+اللي في النص بالنقص يبقى تنتين بالنقص تعالى نشوف
+
+287
+00:29:43,930 --> 00:29:49,230
+هل كلام هذا صحيح ولا لأ طبعا نقص في نقص بزائد خمسة
+
+288
+00:29:49,230 --> 00:29:55,790
+مظبوط هي زائد خمسة وهذه EO6 في خمسة EO6 بخمسة EO2
+
+289
+00:29:55,790 --> 00:30:00,150
+نقص إذا المطلوب اللي في النص يكون جديش نقص ستة
+
+290
+00:30:00,150 --> 00:30:07,790
+وعشرين EO6أضرب لهك سالب خمسة وعشرين EO6 و سالب EO6
+
+291
+00:30:07,790 --> 00:30:12,070
+يبقى سالب ستة وعشرين يمكن تحليلنا مصبوخ مائة
+
+292
+00:30:12,070 --> 00:30:17,690
+بالمائة يبقى المعادلة هذه صارت خمسة EO6 ناقص واحد
+
+293
+00:30:17,690 --> 00:30:23,910
+في EO6 ناقص خمسة كله بده يساوي Zero يبقى اما خمسة
+
+294
+00:30:23,910 --> 00:30:28,930
+في EO6 ناقص واحد بده يساوي Zero والتانية ال EO6
+
+295
+00:30:28,930 --> 00:30:34,280
+ناقص خمسة بده يساوي Zeroهذه معناها ان ال E اقص X
+
+296
+00:30:34,280 --> 00:30:38,800
+بده يساوي خمس وهذه معناها ان ال E اقص X بده يساوي
+
+297
+00:30:38,800 --> 00:30:49,760
+كده؟ خمسة خذ للطرفين يبقى ال X يساوي للخمس للخمس
+
+298
+00:30:49,760 --> 00:30:56,720
+اللي هو كده؟ سالب للخمس يبقى هذا سالب للخمس ايه
+
+299
+00:30:56,720 --> 00:31:02,770
+ايش رأيك في الشغل هذا؟ مقبول هذا؟مش مقبول ليش انه
+
+300
+00:31:02,770 --> 00:31:07,410
+قال شرط علي X أكبر من ال zero هذا بيعطينا رقم أقل
+
+301
+00:31:07,410 --> 00:31:13,230
+من ال zero يبقى هذا الكلام مرفوض يبقى impossible
+
+302
+00:31:13,230 --> 00:31:21,010
+هذا كلام غير ممكن هشول ممكن خد ال len للتانية يبقى
+
+303
+00:31:21,010 --> 00:31:27,210
+X بدها تساوي قداش لن الخمسة هذه هي الإجابة الصحيحة
+
+304
+00:31:27,210 --> 00:31:29,790
+لهذه المسألة
+
+305
+00:31:36,970 --> 00:31:47,290
+المثال الثاني بيقول simplify the
+
+306
+00:31:47,290 --> 00:31:51,990
+following expressions
+
+307
+00:31:55,290 --> 00:32:01,370
+بسيط لي كله من الصيغة التالية الصيغة الأولى اللى
+
+308
+00:32:01,370 --> 00:32:10,550
+هو sin لمن لأتنين لإن الأكس أظن
+
+309
+00:32:10,550 --> 00:32:14,510
+أخدنا هذه الأشكال في معكوس الدول المثلثية فره
+
+310
+00:32:14,510 --> 00:32:19,770
+مظبوطوكنا بنجل المثلثة و بنرسمه و بنطلق القيام،
+
+311
+00:32:19,770 --> 00:32:24,310
+طبعا، بس أنا ماعنديش مثلثة، لكن عندي تعريف لمين؟
+
+312
+00:32:24,310 --> 00:32:29,390
+للسنج، يبقى أنا الآن مشان أعرف هذه القيمة، بدي
+
+313
+00:32:29,390 --> 00:32:34,810
+أرجع لتعريف السنجسنش ال X هو E أس X ناقص E أس ناقص
+
+314
+00:32:34,810 --> 00:32:41,330
+X على اتنين مكان ال X كده شجاني يبقى E أس اتنين لن
+
+315
+00:32:41,330 --> 00:32:47,470
+ال X ناقص E أس ناقص اتنين لن ال X على اتنين يبقى
+
+316
+00:32:47,470 --> 00:32:53,710
+هذا يسوي E أس اتنين لن ال X ناقص E أس ناقص اتنين
+
+317
+00:32:53,710 --> 00:32:59,060
+لن ال X كل هذا على ايه؟ على اتنينبنرجع لـ
+
+318
+00:32:59,060 --> 00:33:04,840
+Exponential Function سبعة تلاتة نقول له اه يعني
+
+319
+00:33:04,840 --> 00:33:10,060
+هذا لو بسط بديش اشوف المسألة لا exponential ولا
+
+320
+00:33:10,060 --> 00:33:15,060
+حتى len مشان هيك بنقول بسيطة هذا رقم قبل ال len
+
+321
+00:33:15,060 --> 00:33:23,330
+إذا بيجي أسلمينلل X يبقى هذا E أس ل X تربية وهذا
+
+322
+00:33:23,330 --> 00:33:32,500
+ناقص E أس ل X أسالي باتنينهذا بيلغى التاني لإن هو
+
+323
+00:33:32,500 --> 00:33:38,120
+ده لو معكوسها بيبقى لاندي قداش X تربية ناقص X أس
+
+324
+00:33:38,120 --> 00:33:44,580
+ناقص اتنين على اتنين او ان شئتم فقولوا X square
+
+325
+00:33:44,580 --> 00:33:50,380
+ناقص واحد على X square كله على اتنين او بصيغة اخرى
+
+326
+00:33:50,380 --> 00:33:56,620
+لو وحدنا المقامات بيصير X أس اربعة ناقص واحد كله
+
+327
+00:33:56,620 --> 00:34:02,180
+على اتنين X تربيةيبقى هذه المثلة لا فيها Sing ولا
+
+328
+00:34:02,180 --> 00:34:06,380
+فيها Lin يبقى لما يقول لبسطها يعني اتخلص من كل
+
+329
+00:34:06,380 --> 00:34:11,420
+الكلكة اللي عندك واتهالي بدلالة من؟ بدلالة X طيب
+
+330
+00:34:11,420 --> 00:34:19,980
+نجي لنمر بيه اول نقطة ثانية اعتبر هذه A وهذه Bنمر
+
+331
+00:34:19,980 --> 00:34:30,400
+بيه بيقول بدي قداش لن لجوش ال X زائد سنش ال X زائد
+
+332
+00:34:30,400 --> 00:34:37,420
+لن جوش ال X ناقص سنش ال X ما شاء الله عليها يعني
+
+333
+00:34:37,420 --> 00:34:44,820
+مش صغيرةكبيرة خالص، طبعا؟ طيب، هذه بسيطة، بقوله
+
+334
+00:34:44,820 --> 00:34:49,620
+يستوي، إيش بتختارها علينا مشان نبسط قيمة المعرفة؟
+
+335
+00:34:49,620 --> 00:34:54,680
+نسمع المقترح الأول نعمل هضر نعمل هضر، هذه وجهة نظر
+
+336
+00:34:54,680 --> 00:34:59,080
+سليمة، لما نشوف هل هناك وجهات نظر أخرى ولا لا،
+
+337
+00:34:59,080 --> 00:35:03,240
+خلينا نطبق اللي قال عنه، زميكو بيقول، شو اسمك أنت؟
+
+338
+00:35:06,420 --> 00:35:12,040
+أخوك محمد حمدا بيقول ايه بيقول لن زائد ان لو
+
+339
+00:35:12,040 --> 00:35:16,540
+راجعنا ل section 7 اتنين بيقول هذا لن حاصل الضرب
+
+340
+00:35:16,540 --> 00:35:20,240
+لإن اللي لما بيدخل على الضرب بيحاوله إلى جامعة
+
+341
+00:35:20,240 --> 00:35:26,420
+بيقوله والله مظبوط يبقى لن جوش ال X زائد essential
+
+342
+00:35:26,420 --> 00:35:33,440
+X في جوش ال X ناقص essential X بيقوله والله كلامك
+
+343
+00:35:33,440 --> 00:35:41,870
+مظبوطللكل سؤال هو شرايك في الجثين هدول مش هو تحليل
+
+344
+00:35:41,870 --> 00:35:46,970
+فرق بين المربعين إذا بدي أرجعه إلى أصله قبل
+
+345
+00:35:46,970 --> 00:35:54,830
+التحليل يبقى هذا بده يساوي لان جوش square X ناقص
+
+346
+00:35:54,830 --> 00:36:00,650
+سنش square X ويساوي لان
+
+347
+00:36:01,300 --> 00:36:06,780
+قداش هذا من المتطابقات قبل شوية؟ واحد صحيح طب و
+
+348
+00:36:06,780 --> 00:36:11,060
+لإن الواحد صحيح فقداش؟ يعني هالكلكة علي كبيره ما
+
+349
+00:36:11,060 --> 00:36:15,460
+شاء الله عليه طلعت بالصفر طب هذا اقتراح محمد حمدا،
+
+350
+00:36:15,460 --> 00:36:20,490
+نسمع اقتراح، شو اسمك انت؟محمد أبو الخير محمد أبو
+
+351
+00:36:20,490 --> 00:36:23,730
+محمد أبو الخير هاتبنا من هذا الخير اللي عندك يالا
+
+352
+00:36:23,730 --> 00:36:26,870
+كلام
+
+353
+00:36:26,870 --> 00:36:31,170
+كويس يبقى هذا رجع لمين؟ محمد أبو الخير رجع
+
+354
+00:36:31,170 --> 00:36:38,250
+للمتطابقات اللي اتكلمنا عليها و راح لآخر متطابقتين
+
+355
+00:36:38,250 --> 00:36:43,490
+كتبناهم فمين؟ في مجموعة المتطابقات جالي هنا
+
+356
+00:36:43,490 --> 00:36:47,110
+another solution
+
+357
+00:36:48,400 --> 00:36:53,700
+شوف يا سيدي، أجي قال لي هذا الـLin الأولى هذي شلة
+
+358
+00:36:53,700 --> 00:36:59,260
+و حط بدلها مين؟ EO6، قلنا له والله كلامك مظبوط، و
+
+359
+00:36:59,260 --> 00:37:05,180
+أجي للتانية و قال لي لن هذي EO سالب X، و بعد ذلك
+
+360
+00:37:05,180 --> 00:37:10,820
+راح أستخدم صلاحيات الـLin، يبقى هذي بيصير X في لن
+
+361
+00:37:10,820 --> 00:37:17,000
+الـE، طب لن الـE بقداش؟بواحد يبقى بدل ال X وهذه
+
+362
+00:37:17,000 --> 00:37:21,600
+ناقص X في لن ال E اللي هي بواحد إلا لو هي طلعت
+
+363
+00:37:21,600 --> 00:37:27,120
+جداش Zero زي اللي جابلها يبقى الحل الأول أو الحل
+
+364
+00:37:27,120 --> 00:37:34,860
+الثاني كلاهما صحيح ولا اعتراب على أي منهما ولكن
+
+365
+00:37:34,860 --> 00:37:38,420
+الخيار عادل تشوفه أسهلك امشي فيه
+
+366
+00:37:48,770 --> 00:37:54,370
+طيب هذا كان المثال الثاني نذهب إلى المثال الثالث
+
+367
+00:37:54,370 --> 00:38:08,210
+تلاتة find y' for each of the following بدنا مشتقة
+
+368
+00:38:08,210 --> 00:38:20,150
+كل من الدوال التاليةY تساوي اتنين جذر ال X في تانش
+
+369
+00:38:20,150 --> 00:38:23,430
+لجذر ال X
+
+370
+00:38:32,010 --> 00:38:36,790
+لو نظرت لي هذه الدالة بلاحظ ان هذه تعتبر دالة و
+
+371
+00:38:36,790 --> 00:38:42,110
+هذه دالة اذا ان عندي مشتق تحاصل ضرب دلتين يبقى
+
+372
+00:38:42,110 --> 00:38:48,900
+باجي بقوله ال Y' يسوى الدالة الأولىفي مشتقة الدالة
+
+373
+00:38:48,900 --> 00:38:57,080
+الثانية تفاضل التانش جدر six squared جدر ال X ضرب
+
+374
+00:38:57,080 --> 00:39:02,140
+مشتقة من الجدر الزاوية مشتقة الجدر الواحد على
+
+375
+00:39:02,140 --> 00:39:08,460
+اتنين الجدر يبقى هذا الأولى في مشتقة التانية زائد
+
+376
+00:39:08,460 --> 00:39:16,690
+الدالة التانية اللي هي تانشجذر ال X في مشتقة
+
+377
+00:39:16,690 --> 00:39:21,250
+الأولى اتنين مالكش دعوة ومشتقة جذر ال X اللي هو
+
+378
+00:39:21,250 --> 00:39:29,630
+جداش واحد على اتنين جذر ال X يساويعظم ان اتنين جذر
+
+379
+00:39:29,630 --> 00:39:34,950
+ال X مع اتنين جذر ال X مع السلامة و اتنين هذه مع
+
+380
+00:39:34,950 --> 00:39:39,470
+السلامة مع اتنين هذه يبقى آلة المسألة الى الشكل
+
+381
+00:39:39,470 --> 00:39:48,150
+التالي سش Square لجذر ال X زائد تانش لجذر ال X كله
+
+382
+00:39:48,150 --> 00:39:55,230
+مقسوما عالميا على جذر ال X النقطة الثانية من ال
+
+383
+00:39:55,230 --> 00:40:05,690
+derivatives نمر اتنينبيقول لي Y تساوي لن سنش ال X
+
+384
+00:40:05,690 --> 00:40:17,110
+لن سنش ال X زائد كساش لمين للن تلاتة X الشكل عنها
+
+385
+00:40:17,110 --> 00:40:25,310
+بيبقى ال Y Prime تساويطبعا واضح هذه function و هذه
+
+386
+00:40:25,310 --> 00:40:30,830
+function و اتنين مجموعات مع بعض جامعة اذا احنا
+
+387
+00:40:30,830 --> 00:40:37,390
+بدنا مشتقة المجموع الجبري لدالتين يبقى مشتقة
+
+388
+00:40:37,390 --> 00:40:42,770
+الأولى زائد مشتقة الدالة الثانية
+
+389
+00:40:45,480 --> 00:40:53,260
+مشتقة لن ال U بواحد على U يبقى واحد على سنش ال X
+
+390
+00:40:53,260 --> 00:41:00,120
+في مين؟ في تفاضل السنش اللي هو بجوش يبقى جوش ال X
+
+391
+00:41:00,120 --> 00:41:09,380
+زائدالكسيش تفاضلها بالسالب سش تانش يبقى سالب سالب
+
+392
+00:41:09,380 --> 00:41:16,060
+كسيش كتانش قصدي سالب كسيش اللي هو لن تلاتة اكس
+
+393
+00:41:16,060 --> 00:41:26,080
+كتانش لمن للن تلاتة اكس لمشتقة من الزاوية يبقى هنا
+
+394
+00:41:26,080 --> 00:41:33,690
+واحدعلى تلاتة X في جداش فيه تلاتة طبعا في اختصارات
+
+395
+00:41:33,690 --> 00:41:39,470
+بنقدر نقول التلاتة هذه مع التلاتة هذه وبالتالي آلة
+
+396
+00:41:39,470 --> 00:41:44,970
+المشتقة إلى الشكل التالي جوش على سنشاللي هو
+
+397
+00:41:44,970 --> 00:41:53,690
+potential X وهذه ناقص وهذا قصش لمين لين تلاتة X
+
+398
+00:41:53,690 --> 00:42:01,730
+potential لين تلاتة X كله مقسوما على مين على X
+
+399
+00:42:01,730 --> 00:42:06,470
+الشكل اللي عندها النقطة
+
+400
+00:42:06,470 --> 00:42:12,610
+التالتة النقطة التالتة بيقول لي Y تساوي
+
+401
+00:42:15,690 --> 00:42:26,090
+جوش أُس خمسة جوش الجدري التربيعي لإي أُس تلاتة إكس
+
+402
+00:42:26,090 --> 00:42:27,430
+زائد اتنين
+
+403
+00:42:32,580 --> 00:42:38,740
+هذا كأنه قوس و القوس كل قوس كم؟ قوس خمسة يبقى من
+
+404
+00:42:38,740 --> 00:42:42,560
+ال share rule قولنا القوس في القوس مرفوع لنفس
+
+405
+00:42:42,560 --> 00:42:48,020
+القوس مطروح منه واحد في مشتقد ما داخل القوس يبقى
+
+406
+00:42:48,020 --> 00:42:54,440
+ال wire prime تساوي القوس في القوش مرفوع لنفس
+
+407
+00:42:54,440 --> 00:42:57,440
+القوس مطروح منه واحد
+
+408
+00:42:59,600 --> 00:43:06,620
+تمام؟ في مشتقة مداخل القوس مشتقة القوش الـ cinch
+
+409
+00:43:06,620 --> 00:43:13,940
+يبقى هذا cinch من الجدر التربيع إلى E أس ثلاثة X
+
+410
+00:43:13,940 --> 00:43:22,000
+زائد اتنين في مشتقة الجدر نفسه لسه قبل ما بدأ
+
+411
+00:43:22,000 --> 00:43:28,380
+مشتقة الجدر بقى واحد على اتنين الجدريبقى واحد على
+
+412
+00:43:28,380 --> 00:43:34,580
+اتنين الجذر التربيه الي E أس تلاتة X زائد اتنين
+
+413
+00:43:34,580 --> 00:43:41,720
+الان في مشتقة مداخل الجذر مشتقة ال X بننشل بال X
+
+414
+00:43:41,720 --> 00:43:48,180
+بننشل itself ضرب مشتقة الأس مشتقة اتنين F0
+
+415
+00:43:48,180 --> 00:43:53,700
+اختصارات الحمد لله لا يوجد فيها اي اختصار يبقى
+
+416
+00:43:53,700 --> 00:43:55,000
+بنخليها زي ما هي
+
+417
+00:44:02,040 --> 00:44:17,740
+Y تساوي سنش لمن؟ لتان ال X سنش لتان ال X زائد كتان
+
+418
+00:44:17,740 --> 00:44:22,780
+inverse لمن؟ لسنش ال X
+
+419
+00:44:26,010 --> 00:44:33,910
+خلّي بالك معانا شايف كيف مكتوبة حرفيا رابط الدوال
+
+420
+00:44:33,910 --> 00:44:41,630
+المثلثية مع الدوال الزائدية قصدينها متعمدين طبعا
+
+421
+00:44:41,630 --> 00:44:46,350
+نهيك على أن هذه معرفة لأن السنش على كل ال real
+
+422
+00:44:46,350 --> 00:44:50,950
+line و ال cotton inverse على كل ال real line
+
+423
+00:44:52,770 --> 00:44:58,470
+متعملين وبالتالي ماعنا مشكلة في هذه الحالة يبقى Y'
+
+424
+00:44:59,010 --> 00:45:03,990
+يساوي هذه كلها تعتبر كيانها زي الزاوية بالنسبة
+
+425
+00:45:03,990 --> 00:45:12,110
+لمن؟ للسنش إذا انتفضل السنش بقداش؟ بجوشلتان ال X
+
+426
+00:45:12,110 --> 00:45:21,110
+في تفاضل تان سك تربيع يبقى سك تربيع ال X دي بالك و
+
+427
+00:45:21,110 --> 00:45:24,150
+احنا بمصحى في الامتحان الملاجئ كتير ال H هذي
+
+428
+00:45:24,150 --> 00:45:29,210
+بتنتقل و انه كله على كيفك زي اللي بنتقل من زهرة
+
+429
+00:45:29,210 --> 00:45:33,390
+الى زهرة النحل يعني انت مافيش انت جوش ممكن تبقى
+
+430
+00:45:33,390 --> 00:45:38,130
+جوش يعني cosine cosine يبقى هذي لكن اتفرج بين
+
+431
+00:45:38,130 --> 00:45:43,460
+الدوال الزائدية والدوالالمثلثية يبقى يخلصها من
+
+432
+00:45:43,460 --> 00:45:48,800
+مشتقت الأولى ال quotient inverse مشتقتها بالناقص
+
+433
+00:45:48,800 --> 00:45:53,320
+مظبوط quotient inverse بالزائد و quotient inverse
+
+434
+00:45:53,320 --> 00:46:01,740
+بالسالب سالب واحد على واحد زائد سنش square X في
+
+435
+00:46:01,740 --> 00:46:08,310
+تفاضل السنش اللي هو جداش بجوش ال Xيبقى الـ 10
+
+436
+00:46:08,310 --> 00:46:14,730
+inverse x سالب واحد على واحد زائد x تربية في مشتقة
+
+437
+00:46:14,730 --> 00:46:22,390
+اللي هو ال .. اللي هي الجوش طيب الآن هذه عبارة عن
+
+438
+00:46:22,390 --> 00:46:29,430
+جوش لمين لتاني ال x كله مضروب في سيك تربية ال x
+
+439
+00:46:29,430 --> 00:46:36,100
+ناقص هذا ال term يا شباب موجدشواحد زي .. مين اللي
+
+440
+00:46:36,100 --> 00:46:43,060
+قال واحد؟ استعجل الزلمة يعني، ايوة يبقى إياك
+
+441
+00:46:43,060 --> 00:46:48,600
+والاستعجال في التأمن السلامة وفي العجلة الندابة،
+
+442
+00:46:48,600 --> 00:46:52,600
+مين اللي قال واحد توقفلي شوية انت؟ انت؟ طب بتقدر
+
+443
+00:46:52,600 --> 00:46:56,440
+تجيبلي آية فيها شغلة على الاستعجال هيك من كتاب
+
+444
+00:46:56,440 --> 00:47:03,730
+الله؟بتقدر؟ بالمرة؟ طب لو غششتك الصورة، بتقدر تجيب
+
+445
+00:47:03,730 --> 00:47:11,270
+الآية؟ صورة الإسراء اسمعك
+
+446
+00:47:11,270 --> 00:47:18,190
+وين؟ ويدعو الإنسان بالشر دعاه بالخير وكان الإنسان
+
+447
+00:47:18,190 --> 00:47:23,230
+عجولة، بيستعجل كتير، تمام؟ وهذا هو الذي حدث معاك
+
+448
+00:47:24,330 --> 00:47:25,850
+يبقى واطنة واطنة واطنة واطنة واطنة واطنة واطنة
+
+449
+00:47:25,850 --> 00:47:27,190
+واطنة واطنة واطنة واطنة واطنة واطنة واطنة واطنة
+
+450
+00:47:27,190 --> 00:47:29,890
+واطنة واطنة واطنة واطنة واطنة واطنة واطنة واطنة
+
+451
+00:47:29,890 --> 00:47:37,330
+واطنة واطنة واطنة واطنة
+
+452
+00:47:37,330 --> 00:47:39,630
+واطنة واطنة واطنة واطنة واطنة واطنة واطنة واطنة
+
+453
+00:47:39,630 --> 00:47:41,790
+واطنة واطنة واطنة واطنة واطنة واطنة واطنة واطنة
+
+454
+00:47:41,790 --> 00:47:44,930
+واطنة واطنة واطنة واطنة واطنة واطنة واطنة واطنة
+
+455
+00:47:44,930 --> 00:47:53,270
+واطنة واطنة واطنة واطنة
+
+456
+00:47:53,640 --> 00:48:04,220
+لمن؟ لتان ال X في سك تربيع ال X ناقص سش ال X
+
+457
+00:48:04,220 --> 00:48:11,380
+النقطة الخامسة النقطة
+
+458
+00:48:11,380 --> 00:48:17,960
+الخامسة عندك Y تساوي جوش ال X
+
+459
+00:48:33,320 --> 00:48:37,440
+واضح ان هذه عبارة عن اياشوهذه عبارة عن function
+
+460
+00:48:37,440 --> 00:48:43,020
+تانية إذاً هذه مشتقة حاصل ضرب دالتين بدنا نرجع إلى
+
+461
+00:48:43,020 --> 00:48:47,880
+مشتقة حاصل ضرب دالتين اللي هو الأولى في مشتقة
+
+462
+00:48:47,880 --> 00:48:55,180
+الثانية زائد الثانية في مشتقة الأولى يبقى هاي Y
+
+463
+00:48:55,180 --> 00:49:02,320
+يساوي جوش ال X اللي هو الأولىمشتقة 10 inverse هو 1
+
+464
+00:49:02,320 --> 00:49:07,520
+على 1 زائد sinh square x في مشتقة ال sinh اللي هو
+
+465
+00:49:07,520 --> 00:49:14,230
+main بقاش ال x هذه لسه الأولى في مشتقة mainالثانية
+
+466
+00:49:14,230 --> 00:49:22,470
+زائد الثانية في مشتقة الأولى يبقى هنا tan inverse
+
+467
+00:49:22,470 --> 00:49:31,770
+لسنش ال X في مشتقة الجوش اللي هو main بسنش ال X حد
+
+468
+00:49:31,770 --> 00:49:37,170
+شافه يقدر يقولي كده المقدار هذا سيكون واحد صحيح
+
+469
+00:49:45,460 --> 00:49:53,360
+النتيجة تساوي واحد صحيح و هنا زائد اللي هو ten
+
+470
+00:49:53,360 --> 00:50:04,600
+inverse لسنش ال X في من في سنش ال Xطيب نروح للنقطة
+
+471
+00:50:04,600 --> 00:50:11,500
+السادسة والاخيرة من ال derivatives يقول
+
+472
+00:50:11,500 --> 00:50:17,620
+الحمد لله الراجل متضايق تنفذ السعاداء طيب يبقى ستة
+
+473
+00:50:17,620 --> 00:50:26,240
+Y تساوي ال X في جوش ال X مين قال فيك الحمد لله
+
+474
+00:50:26,240 --> 00:50:30,320
+خنشوف احنا ويا شغلنا مع المسألة هذه مين اللي قال
+
+475
+00:50:30,320 --> 00:50:36,500
+الحمد لله يعني ان انا متضايق او زهقانت؟ عم انت اسم
+
+476
+00:50:36,500 --> 00:50:41,420
+ابني هناك شو اسمك انت؟ item البنى item البنى بده
+
+477
+00:50:41,420 --> 00:50:46,100
+يبنينا الحل اللي هنا عندني هذه المثلة نشوف هل هو
+
+478
+00:50:46,100 --> 00:50:51,020
+بده يبني بناء صحيحا ولا بناء خاصة إذا كان من كلية
+
+479
+00:50:51,020 --> 00:50:56,060
+الهندسة يعني طيب ايش بدك تقترح علينا؟
+
+480
+00:50:58,610 --> 00:51:02,850
+وجهة نظر سليمة جدا لما ناخد دل الطرفات
+
+481
+00:51:08,580 --> 00:51:14,400
+يبقى انا عندي طريقين و اي طريق نصركوا صحيح يا اما
+
+482
+00:51:14,400 --> 00:51:18,700
+باخد اللمن الطرفين ثم الاشتقاق و هذا اللي كنا
+
+483
+00:51:18,700 --> 00:51:26,260
+نسميه التفاضل اللغاريثمي يا اما يا اما بروح تمام
+
+484
+00:51:26,260 --> 00:51:31,640
+تمام يبقى بدى اكتب هذه بدلالة ال exponential يبقى
+
+485
+00:51:31,640 --> 00:51:39,030
+E أس جوش ال X لمن ال X بالشكل اللي عندهاأو بمن؟
+
+486
+00:51:39,030 --> 00:51:43,990
+بطريقتنا الأولى طيب يبقى الآن بدأج أقوله ال Y'
+
+487
+00:51:44,570 --> 00:51:51,910
+يساوي ال exponential كما هي جوش ال X في لن ال X في
+
+488
+00:51:51,910 --> 00:51:56,270
+تفاضل الأس تبع ال exponential اللي هو حصل ضرب
+
+489
+00:51:56,270 --> 00:52:04,100
+دالتين يبقى جوش ال X في واحد على Xزائد لن ال X في
+
+490
+00:52:04,100 --> 00:52:09,220
+تفاضل الجوش اللي هو بسنش ال X الشكل اللي عندنا هنا
+
+491
+00:52:09,220 --> 00:52:16,580
+ممكن نرجعها إلى أصلها و نكتب X أس جوش ال X في مين؟
+
+492
+00:52:16,580 --> 00:52:26,100
+في جوش ال X على X زائد لن ال X في سنش ال X آخر
+
+493
+00:52:26,100 --> 00:52:29,700
+سؤال اللي هو مثال 4 evaluate
+
+494
+00:52:32,250 --> 00:52:37,950
+the following integrals
+
+495
+00:52:37,950 --> 00:52:42,650
+سبل التكاملات التالية
+
+496
+00:52:44,700 --> 00:52:51,560
+النقطة الأولى اللى وعدناكوا فيها قبل قليل اللى هي
+
+497
+00:52:51,560 --> 00:53:01,140
+تكامل لمين؟ لتنش ال X DX و أيه السوء تكامل ليه؟
+
+498
+00:53:01,140 --> 00:53:09,730
+تنش اللى هو سنش ال X على جوش ال X DXالبسطة فضل
+
+499
+00:53:09,730 --> 00:53:16,510
+المقام يبقى لإن absolute value في دعية كتبها لإن
+
+500
+00:53:16,510 --> 00:53:21,770
+الجوش من واحد فمفروض لغاية الملأ نهائية يبقى لإن
+
+501
+00:53:21,770 --> 00:53:30,430
+جوش ال X زاد كلص تلسي يبقى good exercise إلك تكامل
+
+502
+00:53:30,430 --> 00:53:32,610
+ل potential X
+
+503
+00:53:40,240 --> 00:53:51,840
+النقطة التانية بدنا تكامل لسش X DX Y ساوي يلّا
+
+504
+00:53:51,840 --> 00:53:55,940
+اتنين
+
+505
+00:53:55,940 --> 00:54:07,080
+على EOS X زائد EOS ناقص X DXوادرب في EO6 و اجسم
+
+506
+00:54:07,080 --> 00:54:19,380
+على EO6 بصير اتنين تكامل EO6 DX على EO2X زائد واحد
+
+507
+00:54:21,430 --> 00:54:30,710
+تمام؟ لو حطيت EO6 بvariable وليكن T تساوي EO6 يبقى
+
+508
+00:54:30,710 --> 00:54:41,250
+DT بEO6 DX إذا قالت المسألة الاتنين تكامل DT على T
+
+509
+00:54:41,250 --> 00:54:48,410
+تربية زائد واحداللي هو اتنين تان inverse T زائد
+
+510
+00:54:48,410 --> 00:54:55,950
+constant C يبقى اتنين تان inverse U of X زائد
+
+511
+00:54:55,950 --> 00:54:57,810
+constant C يعطيك العافية
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/RYqeweOZGPs_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/RYqeweOZGPs_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..0bdb2e9933c17a4050c4f93eab7f833d11ef7f03
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/RYqeweOZGPs_raw.srt
@@ -0,0 +1,2048 @@
+1
+00:00:10,220 --> 00:00:14,340
+بسم الله الرحمن الرحيم لان نرجع لل section اللي
+
+2
+00:00:14,340 --> 00:00:17,120
+ابتدأنا فيه المرة الماضية وهو ال trigonometric
+
+3
+00:00:17,120 --> 00:00:23,380
+substitutionوقلنا إننا ناخد الطريقة الثانية من طرف
+
+4
+00:00:23,380 --> 00:00:29,400
+التكمل وهي التعويض بدالة مثلثية قلنا إذا لدينا جذر
+
+5
+00:00:29,400 --> 00:00:34,500
+على شكل A تربية ناقص X تربية تحت الجذر أو A تربية
+
+6
+00:00:34,500 --> 00:00:40,800
+ناقص X تربية مرفوعة لأس معين التعويض A sin θ وθ ما
+
+7
+00:00:40,800 --> 00:00:45,760
+بين سلبي ع اتنين إلى باي على اتنينوإذا كان لتحت
+
+8
+00:00:45,760 --> 00:00:52,280
+الجدر ا تربية زائد X تربية تعويضة بA تان ثيتا
+
+9
+00:00:52,280 --> 00:00:56,380
+وثيتا مابين سالب باية اتنين الاباية اتنين ك open
+
+10
+00:00:56,380 --> 00:01:01,000
+interval لكن في حالة الصين ك closed intervalوإذا
+
+11
+00:01:01,000 --> 00:01:05,520
+كان الجدر التربية إلى ال X تربية ناقص ال A تربية
+
+12
+00:01:05,520 --> 00:01:10,940
+عن الإشارة السالبة للثابت وليست للمتغير فالتعويضة
+
+13
+00:01:10,940 --> 00:01:15,540
+X يساوي A سك ثيتا وثيتا محصورة ما بين ال zero و ال
+
+14
+00:01:15,540 --> 00:01:19,060
+pi على اتنين من عند ال zero مغلقة و من عند ال pi
+
+15
+00:01:19,060 --> 00:01:22,280
+على اتنين مفتوحة يبقى هذا اللي اتعرضنا له المرة
+
+16
+00:01:22,280 --> 00:01:26,780
+الماضية و رسمنا المثلة في كل حالةوابتدأنا ان انا
+
+17
+00:01:26,780 --> 00:01:30,520
+اخد مثل لو اخدنا مثلا واحدا وهذا اللي قدامنا مثال
+
+18
+00:01:30,520 --> 00:01:35,460
+رقم تمام واضح انه ماعنديش جذر بس عندي جوس و الجوس
+
+19
+00:01:35,460 --> 00:01:39,140
+مرفوع لأس واحد اتنين تلاتة عشرة جد ما يكون هنا
+
+20
+00:01:39,140 --> 00:01:43,370
+الحمد لله لأس بس واحديبقى بدنا نيجي نحل الهدف
+
+21
+00:01:43,370 --> 00:01:48,570
+بطريقة Trigonometric Substitution بقوله قويس يبقى
+
+22
+00:01:48,570 --> 00:01:52,250
+احنا عنا X سربية زائدة ربعا اشارة هنا داخل القوس
+
+23
+00:01:52,250 --> 00:01:57,410
+عبارة عن زائدة يبقى التعويضة بدلالة تان ثيتا اذا
+
+24
+00:01:57,410 --> 00:02:05,130
+بدنا نقوله هنا حط لل X يساوي اتنين تان ثيتا وثيتا
+
+25
+00:02:05,130 --> 00:02:11,350
+اكبر من سالب باي على اتنين واقل من باي على اعلى
+
+26
+00:02:11,350 --> 00:02:18,610
+اتنين بدنا نجيب DX كمان يبقى باتنين سكة ربيع ثيتا
+
+27
+00:02:18,610 --> 00:02:24,690
+في دي ثيتا اذا انقلت مسألة الى الشكل التالي ال DX
+
+28
+00:02:24,690 --> 00:02:30,490
+اللي هي باتنين سكة ربيع ثيتا دي ثيتا على X تكييب
+
+29
+00:02:30,490 --> 00:02:37,490
+بدنا نكعب هذا المقدار يبقى تمانيتان تكييب ثيتا
+
+30
+00:02:37,490 --> 00:02:42,730
+وافتح جوزالـ x أربعة بدنا نربعها يبقى أربعتان
+
+31
+00:02:42,730 --> 00:02:48,570
+تربية ثيتا زائد أربعة يبقى مثلتي بدل ما كانت
+
+32
+00:02:48,570 --> 00:02:53,630
+بدلالة x حولتها كلها بدلالة mainبدلالة ثيتا يبقى
+
+33
+00:02:53,630 --> 00:02:59,530
+أصبحت المثل على الشكل التالف هي تكمل عند في البسط
+
+34
+00:02:59,530 --> 00:03:05,170
+هي اتنين على طلعلي هنا اربعة مع اربعة تقلع برا
+
+35
+00:03:05,170 --> 00:03:11,990
+اربعة في تمانية يبقى هي الاربعة في تمانية بالشكل
+
+36
+00:03:11,990 --> 00:03:21,900
+اللي عندنا اربعة في تمانيةبلادنا مين؟ بلادنا تان
+
+37
+00:03:21,900 --> 00:03:25,640
+تكعيب ثيتا و بلادنا تان تكعيب ثيتا و واحد زائد تان
+
+38
+00:03:25,640 --> 00:03:34,080
+تربيه لهمين؟ بسكت ربيع ثيتا و هيديه ثيتا فوقهذه لو
+
+39
+00:03:34,080 --> 00:03:41,240
+جينا اختصرناها بيظل واحد على ست عشر في تكامل سيك
+
+40
+00:03:41,240 --> 00:03:47,000
+تربيع هتروح مع السيك تربيع ويبقى عندنا ايه واحد
+
+41
+00:03:47,000 --> 00:03:52,160
+على تان تكييب التان مقلوب من كتان يبقى واحد على
+
+42
+00:03:52,160 --> 00:04:00,490
+تان تكييب هي كتان تكييب ثيتا في دي ثيتايبقى تحولت
+
+43
+00:04:00,490 --> 00:04:05,790
+مسئلتي بدل ما هي بدلالة x بدلالة θ واصلت مسئلتي
+
+44
+00:04:05,790 --> 00:04:11,970
+كلها كتان تكييب θ هذا الشغل كنا نشتغله في calculus
+
+45
+00:04:11,970 --> 00:04:17,850
+A وليس في calculus B كنا في calculus A بنقول كتان
+
+46
+00:04:17,850 --> 00:04:25,850
+تربية ثيتا في كتان ثيتا في D ثيتابعد ذلك واحد على
+
+47
+00:04:25,850 --> 00:04:32,190
+ستاشر تكامل الكتان بروح اكتفه بدلالة ال cosecant
+
+48
+00:04:32,190 --> 00:04:40,190
+يبقى cosecant تربيع ثيتا ماقص واحد في كتان ثيتا في
+
+49
+00:04:40,190 --> 00:04:47,390
+دي ثيتالو فكنا هذه بيصير واحد على ستاشر تكمل
+
+50
+00:04:47,390 --> 00:04:55,970
+لكوسيكا تربية ثيتا كتان ثيتا في d ثيتا ناقص كتان
+
+51
+00:04:55,970 --> 00:05:02,210
+ثيتا كل هذا الكلام بالنسبة إلى من؟ بالنسبة إلى d
+
+52
+00:05:02,210 --> 00:05:09,510
+ثيتاأو إن شئتم كتان دي ثيتا بدون دي ثيتا هنا فكيت
+
+53
+00:05:09,510 --> 00:05:14,810
+بس القصة هاي دي ثيتا للكل برا، طبعا؟ يبقى هذه لا
+
+54
+00:05:14,810 --> 00:05:21,130
+وجود لها هنا، طبعا؟
+
+55
+00:05:21,650 --> 00:05:27,570
+يبقى هذا الكلام بده يساوي واحد على ستة عشر فيه
+
+56
+00:05:27,570 --> 00:05:33,250
+تكامل، ممكن اوزع الآن التكامل للاتنين، الكثير كانت
+
+57
+00:05:33,250 --> 00:05:39,780
+تربية هي مشتقة مين؟كتان يعني هذه ال cos كانت تربيع
+
+58
+00:05:39,780 --> 00:05:45,580
+theta مع ال d theta هذه ممكن أشيل و أكتب بدلها
+
+59
+00:05:45,580 --> 00:05:51,900
+لومين دي كتان بس تفهموا كتان بالسالب cos كانت
+
+60
+00:05:51,900 --> 00:05:57,280
+تربيع معناته بدي إشارة من كمان بدي إشارة سالب يبقى
+
+61
+00:05:57,280 --> 00:06:06,280
+هذه السالب كتان theta مشتقة كتان ال thetaوكأنه
+
+62
+00:06:06,280 --> 00:06:11,260
+احنا صرنا بدنا الكائن كامل بالنسبة لمن؟ بالنسبة
+
+63
+00:06:11,260 --> 00:06:17,140
+لكتان الثيتا هذا الجزء الأول وصلنا للناقص هذه
+
+64
+00:06:17,140 --> 00:06:22,520
+بجهينا ناقص واحد على ستاشر وهي تكامل الكتان هي
+
+65
+00:06:22,520 --> 00:06:28,120
+عبارة عن cosine ثيتا على sin θ دي ثيتا بس بكتبها
+
+66
+00:06:28,120 --> 00:06:31,930
+للي ناسي اما الأصل اللي حطلك على طوللأن أول ما
+
+67
+00:06:31,930 --> 00:06:35,870
+قدرنا ال chapter كتبنا لك جداش تكامل الكتان اللي
+
+68
+00:06:35,870 --> 00:06:41,190
+عنها ده يبقى هذا الكلام يساوي سالب واحد على ستة
+
+69
+00:06:41,190 --> 00:06:49,570
+عشر وهذه جداش كتان تربية ثيتا على اتنين ماقص واحد
+
+70
+00:06:49,570 --> 00:06:56,210
+على ستة عشر لين absolute value لثين ثيتا زائد
+
+71
+00:06:56,210 --> 00:07:01,380
+constant C طب استنى شويةمثلتك في الأساس بدلالة ال
+
+72
+00:07:01,380 --> 00:07:05,560
+X وانت طلعتها لي بدلالة مين؟ بدلالة الثيتا ايه؟
+
+73
+00:07:05,560 --> 00:07:10,600
+انت بتحول مثلتك كلها بدلالة مين؟ بدلالة ال X بنجي
+
+74
+00:07:10,600 --> 00:07:19,140
+على هذهالاساسية و بنجي من قول هذه تعني ان تان ثيتا
+
+75
+00:07:19,140 --> 00:07:24,460
+بد يساوي ال X على مين؟ على الإتنين إذا لو روحنا و
+
+76
+00:07:24,460 --> 00:07:29,220
+رسمنا المثلث بالشكل اللي عندنا هذا و قولنا هذه
+
+77
+00:07:29,220 --> 00:07:34,310
+الزاوية ثيتا وهذه الزاوية القائمةالظلم يساوي
+
+78
+00:07:34,310 --> 00:07:40,610
+المقابل على المجاور يبقى هذا X وهذا 2 وهذا الجدرد
+
+79
+00:07:40,610 --> 00:07:49,210
+تربية ل X تربية زائد 4 حسب نظرية منه في ثغورف يبقى
+
+80
+00:07:49,210 --> 00:07:53,970
+هذا الكلام يساوي سالب واحد على ستاش في اتنين
+
+81
+00:07:53,970 --> 00:07:59,030
+باتنين وتلاتين يبقى اتنين وتلاتين
+
+82
+00:08:01,090 --> 00:08:08,510
+بالله الكتان في تلكتان المجاور على المقابل، يعني
+
+83
+00:08:08,510 --> 00:08:16,150
+اتنين على اكس الكل تربيع، هذه خلاصنا من هذه، نجي
+
+84
+00:08:16,150 --> 00:08:26,050
+لبعدها، ناقص واحد على ستاشر، ونجي لإنabsolute
+
+85
+00:08:26,050 --> 00:08:30,350
+value للصيد هيتا الصيد هيتا يساوي بالمقابل على
+
+86
+00:08:30,350 --> 00:08:35,590
+الوتر يبقى ال X على الجدرى التربية إلى X تربية
+
+87
+00:08:35,590 --> 00:08:42,630
+زائد أربعة زائد كونستانسي هديها لو ربعناها بيصير
+
+88
+00:08:42,630 --> 00:08:49,800
+أربعة مع اتنين و تلاتين بيصير قداشسالب تمل في واحد
+
+89
+00:08:49,800 --> 00:08:55,860
+على X تربية وهذه اختصارات مافيهش ناقص واحد على
+
+90
+00:08:55,860 --> 00:09:01,920
+ستاشر لين absolute value X على اللي هو الجدر
+
+91
+00:09:01,920 --> 00:09:08,840
+التربية اللي هي X تربية زائد أربعة زائد أربعة و
+
+92
+00:09:08,840 --> 00:09:16,500
+هنا زائد constant Cيبقى التعييدة بتاع كامد على شكل
+
+93
+00:09:16,500 --> 00:09:23,440
+الإشارة داخل القوس أو تحت الجدر المثال رقم تلاتة
+
+94
+00:09:23,440 --> 00:09:32,620
+بدنا تكامل للجدر التربيعي لخمسة X تربيع ماقص تسعة
+
+95
+00:09:32,620 --> 00:09:41,920
+على X كله بالنسبة إلى دي Xبنروح للمثال رقم تلاتة،
+
+96
+00:09:41,920 --> 00:09:48,500
+فلاحظة عندي الجبر بس لأول مرة بيجابلنا شغلة زيك مش
+
+97
+00:09:48,500 --> 00:09:55,060
+X تربيها وإنما الرقم مضروب في من؟ في ال X بسيطة
+
+98
+00:09:55,060 --> 00:09:59,820
+ممكن هذا الرقم ياخده برا عامل مشترك ويطلع برا خالص
+
+99
+00:09:59,820 --> 00:10:05,530
+وممكن يخلي زي ما هو معناهاش مشكلةيعني ممكن اخده
+
+100
+00:10:05,530 --> 00:10:11,350
+برا عامل مشترك و ممكن اخليه جوا خليه جدر خمسة اكسل
+
+101
+00:10:11,350 --> 00:10:16,350
+كل تربية سياسية عملت هيك و الله هيك بتفرجش عنا
+
+102
+00:10:16,350 --> 00:10:22,530
+يعني قدامي خيارين يا باخد خمسة بطلعها برا الجدر
+
+103
+00:10:22,530 --> 00:10:27,570
+تطلع بجدر خمسة عامل مشترك برا خالص بالمرة يا بقول
+
+104
+00:10:27,570 --> 00:10:33,240
+جدرخمسة مضروبة في اكسل كل تربية هو عبارة عن هذا
+
+105
+00:10:33,240 --> 00:10:38,020
+المقدار، هيك و الله هيك سيان لي اتنين نفس الشيء،
+
+106
+00:10:38,020 --> 00:10:44,690
+فمثلا لو جيت قلت هذه تكاملتحب ان تبقى الخمسة جدر
+
+107
+00:10:44,690 --> 00:10:52,090
+الخمسة او جدر الخمسة اكس لكل تربية؟ برا برا برا
+
+108
+00:10:52,090 --> 00:10:53,190
+برا برا برا برا برا برا برا برا برا برا برا برا
+
+109
+00:10:53,190 --> 00:10:53,410
+برا برا برا برا برا برا برا برا برا برا برا برا
+
+110
+00:10:53,410 --> 00:10:53,410
+برا برا برا برا برا برا برا برا برا برا برا برا
+
+111
+00:10:53,410 --> 00:10:53,430
+برا برا برا برا برا برا برا برا برا برا برا برا
+
+112
+00:10:53,430 --> 00:10:54,230
+برا برا برا برا برا برا برا برا برا برا برا برا
+
+113
+00:10:54,230 --> 00:10:58,710
+برا برا برا برا برا برا برا برا برا برا برا برا
+
+114
+00:10:58,710 --> 00:11:00,510
+برا برا برا برا برا برا برا برا برا برا برا برا
+
+115
+00:11:00,510 --> 00:11:04,370
+برا برا برا برا برا برا ب
+
+116
+00:11:08,470 --> 00:11:13,350
+يبقى يا جدر خمسة خليك برا على الهياد الإيجابي وعدم
+
+117
+00:11:13,350 --> 00:11:18,210
+الانحياز نجي لما قال الباقى شو ضال عندي؟ ضال عندي
+
+118
+00:11:18,210 --> 00:11:24,810
+الجدر التربية ل X تربية ناقص تسعة أخمس كله على X
+
+119
+00:11:24,810 --> 00:11:26,430
+في الDX
+
+120
+00:11:28,410 --> 00:11:32,390
+نجي نطلع للإشارة تحت الجذر، الإشارة تحت الجذر
+
+121
+00:11:32,390 --> 00:11:38,630
+بمين؟ بالسالب السالب للمتغير ولا للثابت، للثابت
+
+122
+00:11:38,630 --> 00:11:44,910
+يبقى تعويضة بدلالة six theta إذا بدك تقولي حط ال X
+
+123
+00:11:44,910 --> 00:11:52,030
+يساوي ال A اللي هي تلاتة على جذر خمسة في six theta
+
+124
+00:11:53,570 --> 00:12:00,150
+والثيتا هذه محصورة ما بين الصفر وما بين البي على
+
+125
+00:12:00,150 --> 00:12:07,570
+اتنين بلزمنا هنا DX إذا هضطر أشتق هذه إذا لو جينا
+
+126
+00:12:07,570 --> 00:12:15,590
+أشتقين هذه بصير ال DX بدي ساوي تلتة على جدر خمسة
+
+127
+00:12:15,590 --> 00:12:24,420
+اهه وتفاضل ب6 ثيتا 10 ثيتا في D ثيتايبقى آلة
+
+128
+00:12:24,420 --> 00:12:29,000
+المسألة إلى الشكل التالي جدر خمسة مالكش دعوة Y
+
+129
+00:12:29,000 --> 00:12:35,440
+تكامل Y الجدر التربيعي X تربيع بدنا نربع هذه يبقى
+
+130
+00:12:35,440 --> 00:12:41,900
+تسعة على خمسة سك تربيع يبقى تسعة على خمسة في سك
+
+131
+00:12:41,900 --> 00:12:49,550
+تربيع ثيتا ناقص تسعة على خمسة كله علىX اللي في
+
+132
+00:12:49,550 --> 00:12:56,470
+المقام اللي هي تلاتة على جذر خمسة تلاتة على جذر
+
+133
+00:12:56,470 --> 00:13:03,890
+خمسة في سك الزاوية ثيتا في DX DX اللي هي تلاتة على
+
+134
+00:13:03,890 --> 00:13:09,190
+جذر خمسة سك ثيتا تان ثيتا في DX
+
+135
+00:13:12,380 --> 00:13:17,620
+طيب نبدأ نختصر الاختصارات تلاتة على جذر خمسة مع
+
+136
+00:13:17,620 --> 00:13:23,660
+تلاتة على جذر خمسة سك مع سك الله يسهل عليها من هنا
+
+137
+00:13:23,660 --> 00:13:29,900
+نطلع تسعة على خمسة برا الجذر بتطلع تلاتة على جذر
+
+138
+00:13:29,900 --> 00:13:36,700
+خمسة و عندك هنا جذر خمسةيبقى يسوي هي جدر خمسة لبرا
+
+139
+00:13:36,700 --> 00:13:44,200
+وهي تلاتة على الجدر خمسة وهي تكامل تسعة أخمس مع
+
+140
+00:13:44,200 --> 00:13:49,400
+تسعة أخمس أخدناها برا الجدر تلاتة على الجدر خمسة
+
+141
+00:13:49,400 --> 00:13:54,160
+بظل ال sector بيناقص واحد ليه بقدرش؟ ال center
+
+142
+00:13:54,160 --> 00:14:02,120
+بيطلع من تحت الجدر بتانيبقى هاي تان ثيتا و برا
+
+143
+00:14:02,120 --> 00:14:08,340
+طايل عندي جديش تان ثيتا دي ثيتا والباجي كله
+
+144
+00:14:08,340 --> 00:14:14,620
+انتهينا منهتمام؟ يبقى النتيجة يساوي جدر بساوي
+
+145
+00:14:14,620 --> 00:14:21,900
+تلاتة طبعا جدر خمسة مع جدر خمسة وهذه تكامل تان في
+
+146
+00:14:21,900 --> 00:14:26,960
+تان تان تربية ماعرفش كمانها لكن لو حاولت بدلت ال
+
+147
+00:14:26,960 --> 00:14:31,940
+six تربية تتكامل على طول يبقى هذه عبارة عن six
+
+148
+00:14:31,940 --> 00:14:39,490
+تربية ثيتا ناقص واحد دي ثيتايبقى تلاتة تان ثيتا
+
+149
+00:14:39,490 --> 00:14:46,850
+ناقص تلاتة ثيتا زائد constant C المثل ابتدت بدلالة
+
+150
+00:14:46,850 --> 00:14:51,750
+ال X بدك تنهيها بدلالة ال X يبقى بدأ أرجع ثيتا دي
+
+151
+00:14:51,750 --> 00:14:58,270
+بدلالة 8 بدلالة X لذلك بدنا نيجي على هذه التعويضة
+
+152
+00:14:58,270 --> 00:15:04,710
+اللي استخدمناها وبدأ أجيب منها six ثيتا فsix ثيتا
+
+153
+00:15:04,710 --> 00:15:12,150
+عندك هنابيده يساوي اللي هو جدر خمسة X على تلاتة
+
+154
+00:15:12,150 --> 00:15:21,110
+جدر خمسة X كله على مين؟ على تلاتة ولو رسمنا المثلث
+
+155
+00:15:21,110 --> 00:15:25,610
+بالشكل أن هذا هي ثيتا وهي الزاوية القايمة السك
+
+156
+00:15:25,610 --> 00:15:32,350
+يساوي الوطرعلى المجاور يبقى ال water جذر خمسة X
+
+157
+00:15:32,350 --> 00:15:39,270
+والمجاور تلاتة وحسب في ثورف الضلة التالت خمسة X
+
+158
+00:15:39,270 --> 00:15:48,690
+تربيع ناقص إسعة إذا هذه صارت تلاتة فيهتان ثيتا
+
+159
+00:15:48,690 --> 00:15:54,030
+يبقى المقابل على المجاور يبقى الجدر التربية إلى
+
+160
+00:15:54,030 --> 00:16:00,310
+خمسة X تربية ناقص تسعة على المجاور اللي هو تلاتة
+
+161
+00:16:00,310 --> 00:16:12,350
+وهنا عندك ناقص تلاتةسيك انفرس جزر
+
+162
+00:16:12,350 --> 00:16:20,050
+خمسة اكس كلها تلاتة زائد كل أسطن سي ويساوي تلاتة
+
+163
+00:16:20,050 --> 00:16:24,250
+مع تلاتة الله يسهل عليها يبقى الإجابة النهائية ال
+
+164
+00:16:24,250 --> 00:16:25,750
+square root
+
+165
+00:16:43,840 --> 00:16:54,080
+الرابع السؤال الرابعبيقول يتكامل لل X tan inverse
+
+166
+00:16:54,080 --> 00:17:02,200
+X على واحد زائد X تربيع قص تلاتة على اتنين كله في
+
+167
+00:17:02,200 --> 00:17:02,580
+DX
+
+168
+00:17:17,640 --> 00:17:22,500
+والله ليه كويس هنا للسؤال الرابع السؤال الرابع مرة
+
+169
+00:17:22,500 --> 00:17:28,600
+جيبناه في إحدى الامتحانات والسبب لإنه بستاهل يكون
+
+170
+00:17:28,600 --> 00:17:36,600
+سؤال امتحان لماذا هذا ما ستعرفونه بعد قليل باختصار
+
+171
+00:17:36,600 --> 00:17:42,000
+هيك يعني نستخدم أكثر من طريقة من طرق التكامل اللي
+
+172
+00:17:42,000 --> 00:17:47,490
+اتعلمناها لحل هذا السؤاليبقى بمجرد النظر هل
+
+173
+00:17:47,490 --> 00:17:53,170
+التكامل هذا يحتوي على جدر تربيهي؟ كيف يا عزيزي؟
+
+174
+00:17:53,170 --> 00:17:57,290
+خلّيه، شهوز ثلاثة على اتنين؟ يعني الجدر التربيهي
+
+175
+00:17:57,290 --> 00:18:01,070
+للجوز تكيب، مظبوط ولا لأ؟ إذن يحتوي على الجدر
+
+176
+00:18:01,070 --> 00:18:05,110
+التربيهي، يبقى أول ما افكر بدأ اتخلص من الجدر
+
+177
+00:18:05,110 --> 00:18:10,530
+التربيهي، يبقى الجدر التربيهي هنا إشارةموجة بيبقى
+
+178
+00:18:10,530 --> 00:18:16,550
+ال X هي بدلال التان ثيتا يبقى باجي بقوله حط لل X
+
+179
+00:18:16,550 --> 00:18:23,630
+تساوي تان ثيتا فقط لا غير وثيتا أكبر من سالب باي
+
+180
+00:18:23,630 --> 00:18:29,580
+على اتنين وأقل من مين من باي على اتنينيبقى هذا
+
+181
+00:18:29,580 --> 00:18:35,640
+الكلام يستوي تكامل ال x هي عبارة عن tan θ و هذه
+
+182
+00:18:35,640 --> 00:18:44,340
+tan inverse ل tan θ و ال dx اللي عبارة عن sector
+
+183
+00:18:44,340 --> 00:18:51,280
+بيه θ في dθ يبقى sector بيه θ في dθ انتهينا من
+
+184
+00:18:52,930 --> 00:18:56,990
+البسط او ال numerator نيجي للمقام اللي هو ال
+
+185
+00:18:56,990 --> 00:19:02,390
+denominator واحد زائد ال X تربيه اللي هي عبارة عن
+
+186
+00:19:02,390 --> 00:19:09,630
+تان تربيه ثيتا كله أس تلاتة على اتنين يبقى هذا
+
+187
+00:19:09,630 --> 00:19:16,070
+الكلام بده يساوي تكاملتان انفرس لتان ثيتا جداش بده
+
+188
+00:19:16,070 --> 00:19:19,270
+يعطينا .. لما تيتا تبقى محصورة في الفترة هذه
+
+189
+00:19:19,270 --> 00:19:26,230
+بيعطينا تيتا فقط، ما غير إذا صار هذا ثيتا في تان
+
+190
+00:19:26,230 --> 00:19:33,690
+ثيتا وعندنا هنا سك تربيع ثيتا على طلعلي هنا واحد
+
+191
+00:19:33,690 --> 00:19:40,810
+زي التان تربيع سك تربيع أقصى تلاتة على اتنين جداش؟
+
+192
+00:19:40,810 --> 00:19:51,150
+سكتكيب ثيتا وكله في d ثيتا نختصر ال sec تربيع مع
+
+193
+00:19:51,150 --> 00:19:57,870
+الsec تربيع من المقام بصير ثيتا تان ثيتا كله قادة
+
+194
+00:19:57,870 --> 00:20:06,470
+على sec ثيتا في d ثيتافبنشوف لوين وصلتنا هذه تكامل
+
+195
+00:20:06,470 --> 00:20:14,290
+لثيتا في ال 10 بيبقى sin ثيتا
+
+196
+00:20:14,290 --> 00:20:21,850
+على cos ثيتاوالـ Sec مخلوق من الـ Cos يبقى في Cos
+
+197
+00:20:21,850 --> 00:20:28,190
+θ في dθ Cos مع Cos الله يسهل عليها يبقى آلة
+
+198
+00:20:28,190 --> 00:20:33,990
+المسألة يتكامل θ Sin θ dθ
+
+199
+00:20:37,680 --> 00:20:42,800
+Integration by parts من هنا بستهل يكون سؤال امتحان
+
+200
+00:20:42,800 --> 00:20:47,060
+لو في كمان كلام تاني مش هجد هيك يبقى بكون استخدام
+
+201
+00:20:47,060 --> 00:20:52,360
+طريقتين من طرق التكامل في حل هذا المثال الطريقة
+
+202
+00:20:52,360 --> 00:20:55,620
+الأولى is trigonometric substitution الطريقة
+
+203
+00:20:55,620 --> 00:20:59,550
+التانية integration by partsمش integration by
+
+204
+00:20:59,550 --> 00:21:04,130
+parts لأ الجدول تبع integration by parts الست علاء
+
+205
+00:21:04,130 --> 00:21:08,510
+اللي ذكرناهم هذه عبارة عن ايه؟ عن واحدة فيهم، اذا
+
+206
+00:21:08,510 --> 00:21:14,280
+باجي بقوله بتاخد هنا ال derivativesوبتاخد هنا ال
+
+207
+00:21:14,280 --> 00:21:21,220
+integrals ل derivative theta sin theta تفاضلها
+
+208
+00:21:21,220 --> 00:21:26,560
+بواحد تكملها ب سالب cosine theta تفاضلها ب zero
+
+209
+00:21:26,560 --> 00:21:32,280
+تكملها بسالب sin theta هدف هدف الموجبهذا في هدف
+
+210
+00:21:32,280 --> 00:21:39,640
+السالب، إذا قالك المسألة إلى سالب ثيتا cosine ثيتا
+
+211
+00:21:39,640 --> 00:21:48,970
+زائد sine ثيتا زائد constant Cيبقى باركتين، الأولى
+
+212
+00:21:48,970 --> 00:21:53,050
+الـ Trigonometric Substitution وصلتني إلى
+
+213
+00:21:53,050 --> 00:21:57,610
+Integration By Parts هذه من الستة المشهورات، روحنا
+
+214
+00:21:57,610 --> 00:22:02,510
+عملنا لها الجدول، كتبنا النتيجة بعد هيك بدأت انت
+
+215
+00:22:02,510 --> 00:22:07,920
+بال X، بدك ترجع لمين؟ تكتب مسلتك بدلالة ال Xاذا
+
+216
+00:22:07,920 --> 00:22:14,440
+برجع لتعويضة تابعتي هذي يبقى هاي التعويضة تابعتنا
+
+217
+00:22:14,440 --> 00:22:20,520
+اللى بتقول تان تيتا بدى سوى جدرش اكس اذا بدنا نروح
+
+218
+00:22:20,520 --> 00:22:26,580
+نرسم له المثلث هذا المثلث وهذا الزاوية تيتا وهذا
+
+219
+00:22:26,580 --> 00:22:32,450
+الزاوية القاعدة او الظليساوي المقابل على المجاور
+
+220
+00:22:32,450 --> 00:22:40,910
+حسب فيثا غورت هذا واحد زائد X تربيع طيب كده صارت
+
+221
+00:22:40,910 --> 00:22:47,430
+المسألة ناقص ثيتا من هنا عبارة عن إيش يا شباب يعني
+
+222
+00:22:47,430 --> 00:22:52,050
+العبارة المكافية لهذه العبارة هي ثيتا تسمي تان
+
+223
+00:22:52,050 --> 00:23:00,000
+inverse X كده صار هنا تان inverse Xيجي لكوا sin θ
+
+224
+00:23:00,000 --> 00:23:06,160
+المجاور على ال water يبقى على الجدرى التربية إلى
+
+225
+00:23:06,160 --> 00:23:13,000
+واحد زائد x تربية زائد sin θ اللي هو المقابل على
+
+226
+00:23:13,000 --> 00:23:17,760
+ال water يبقى زائد x على الجدرى التربية إلى واحد
+
+227
+00:23:17,760 --> 00:23:24,210
+زائد x تربيةزائد constant C يبقى راجعنا استخدمنا
+
+228
+00:23:24,210 --> 00:23:28,330
+من قانون ال inverse trigonometric functions يبقى
+
+229
+00:23:28,330 --> 00:23:34,150
+جيبنا تلت شغلات في تكامل واحد و بستهلكون سؤال
+
+230
+00:23:34,150 --> 00:23:42,010
+امتحان للطالب المتميز اه يعني هذا قصدنا انخصبوا
+
+231
+00:23:42,010 --> 00:23:45,310
+الطلاب اللي هم بيجتهدوا و بيشتغلوا و بيفرجوا على
+
+232
+00:23:45,310 --> 00:23:51,170
+الطلاب العادى تفضلتربيع مثل ال W متغير اشتغلناها
+
+233
+00:23:51,170 --> 00:23:58,430
+بتروح ال X وبعدين نفحها فوق وضيعنا
+
+234
+00:23:58,430 --> 00:24:03,290
+ال X وبعدين رفعناها فوق وكملناها بالأجزاء وكان
+
+235
+00:24:03,290 --> 00:24:07,450
+inverse نكتبرها
+
+236
+00:24:07,450 --> 00:24:15,930
+اشتغلت معاكبأي طريقة تنشيط حل بس بده طريقة تبده
+
+237
+00:24:15,930 --> 00:24:16,810
+طريقة صحيحة
+
+238
+00:24:21,300 --> 00:24:28,600
+طب لكيف يفجأ بنا ناخد بأي طريقة صحيحة نحل نقلة
+
+239
+00:24:28,600 --> 00:24:33,000
+ماعناه مشكلة وماعناه أتراب لكن لما كان موضوع
+
+240
+00:24:33,000 --> 00:24:37,460
+لموضوع trigonometric substitution حلنا حبينا نحل
+
+241
+00:24:37,460 --> 00:24:41,680
+بطريقة trigonometric substitution السؤال هو في
+
+242
+00:24:41,680 --> 00:24:46,570
+الامتحان بيحددنا الطريقةلأ بيقولك و بيليوز اتقالب
+
+243
+00:24:46,570 --> 00:24:50,170
+انتجار و بيحط لك تكامل ان ثلاثة و الله اربعة و
+
+244
+00:24:50,170 --> 00:24:53,990
+الله جد من كلهم بيقولك حل و بس و انت حل حالك
+
+245
+00:24:53,990 --> 00:24:57,990
+بالطريقة اللي بتعجبك يعني لا قيود عليك أثناء
+
+246
+00:24:57,990 --> 00:25:03,700
+الامتحان حل بالتكامل اللي بتعرفي فضلالتعويض اللي
+
+247
+00:25:03,700 --> 00:25:06,400
+تيجي معاها بتاعة تانية تلاتة نعوض فيها و نص
+
+248
+00:25:06,400 --> 00:25:12,580
+التمارين لو تجينا تعويض مجانا ترايب رومنتيكي اه لا
+
+249
+00:25:12,580 --> 00:25:18,140
+يا صاحب انت لغاية حبيته مانفوتش لغاية تمانية اتنين
+
+250
+00:25:18,140 --> 00:25:21,620
+احنا بنتقيل بيه تمانية اتنين و ماليش تمانية تلاتة
+
+251
+00:25:21,620 --> 00:25:27,280
+ولا حتى تمانية اربع طبعا؟ ايوة في تكملات
+
+252
+00:25:32,880 --> 00:25:42,620
+طب مش ممكن نكملها بعد الطريقة؟ اللي أخدته قبل كله
+
+253
+00:25:42,620 --> 00:25:47,680
+بتقدر تستخدمه، مع إنك مشكلة بيها، بس اللي ماخدناش،
+
+254
+00:25:47,680 --> 00:25:51,170
+ماخدناش لسه قبل ما لسهصحيح ولا لا؟ لأن ما أخدتهوش
+
+255
+00:25:51,170 --> 00:25:56,330
+يبقى أن كل شغل أخدتها قبل تمانية اتنين في شبطر
+
+256
+00:25:56,330 --> 00:26:00,550
+سبعة في شبطر تمانية استخدمها ولا واحد يستطيع أن
+
+257
+00:26:00,550 --> 00:26:06,710
+يعترض عليك بكلمة واحد بس استخدام استخدام صحيح ماشي
+
+258
+00:26:06,710 --> 00:26:12,430
+طيب الآن بروح للسؤال اللي بعده هذا السؤال أربع وزي
+
+259
+00:26:12,430 --> 00:26:18,000
+ما انت شاف كلها أسئلة مباشرةونشوف إيش رأيك في سؤال
+
+260
+00:26:18,000 --> 00:26:25,060
+خمسة خمسة برضه جيبناها في إحدى الامتحانات على EOSX
+
+261
+00:26:25,060 --> 00:26:30,520
+الجدرى التربية ل EOS2X-16
+
+262
+00:26:44,790 --> 00:26:51,910
+خلّي منك هذا السؤال برضه جيبناه في احد الامتحانات
+
+263
+00:26:51,910 --> 00:26:58,070
+السابقة، كويس؟ يعني ماعنديش X، ماعنديش X، لكن بدل
+
+264
+00:26:58,070 --> 00:27:03,700
+ال X شوهجة؟يبقى عندك تعرف اذا تحط ايه والسكس يساوي
+
+265
+00:27:03,700 --> 00:27:08,540
+كذا اذا احنا قادم عشان نتخلص من الجدر بيقولوا حطوا
+
+266
+00:27:08,540 --> 00:27:12,840
+ال ax يساوي كذا اللي هو مين ما يطلع يطلع يبقى لما
+
+267
+00:27:12,840 --> 00:27:19,010
+اجي اقول حط ال a والسكس يساويبالإشارة بالسالب
+
+268
+00:27:19,010 --> 00:27:25,990
+والسالب للثابت يبقى التعويضة بدلالة six ممتاز يبقى
+
+269
+00:27:25,990 --> 00:27:32,470
+six ثيتا والثيتا هذه أكبر من أو تسوى zero أقل من
+
+270
+00:27:32,470 --> 00:27:38,010
+بي على اتنين نشتغل يبقى ال E و ال six في ال DX
+
+271
+00:27:38,010 --> 00:27:44,830
+يسوى six ثيتا ten ثيتا في دي ثيتاأنا ماعنديش في ال
+
+272
+00:27:44,830 --> 00:27:52,630
+بسط هنا Dx لحالة يبقى
+
+273
+00:27:52,630 --> 00:28:00,150
+هنا Dx بدها ساوي سك ثيتا تان ثيتا D ثيتا مقسومة
+
+274
+00:28:00,150 --> 00:28:05,750
+على مين على E والسكس لأ شباب E والسكس ساوية أربعة
+
+275
+00:28:05,750 --> 00:28:15,030
+أربعة يبقى هنا أربعة يبقى هنا أربعة تماميبقى هذا
+
+276
+00:28:15,030 --> 00:28:21,550
+ال EO6 اللي هي على EO6، كويس؟ الان انا بدي اشيل
+
+277
+00:28:21,550 --> 00:28:28,010
+EO6، لابديش ثيتا و EO6، بدي ثيتا بس، EO6 هي فوق،
+
+278
+00:28:28,010 --> 00:28:34,330
+اذا بقدر اقول هذه اربع six theta, ten theta, d
+
+279
+00:28:34,330 --> 00:28:41,470
+theta مقسومة على EO6 هي اربع six thetaأربعة سك
+
+280
+00:28:41,470 --> 00:28:46,830
+ثيتا مع أربعة سك ثيتا في درجة دياش تان ثيتا في دي
+
+281
+00:28:46,830 --> 00:28:53,190
+ثيتا إذا صارت مسألة هذه على الشكل التالف بدي أشيل
+
+282
+00:28:53,190 --> 00:28:58,240
+ال dx و أكتب مكانهااللي مذاكنين اللي أخدوا كالكلص
+
+283
+00:28:58,240 --> 00:29:03,020
+ايه جيبنا لهم في الامتحان سؤال زي هذا و لأول مرة
+
+284
+00:29:03,020 --> 00:29:06,060
+جيبناه فكان هذا للطالب الممتاز اللي هو سؤال
+
+285
+00:29:06,060 --> 00:29:10,600
+التكامل هذا البعض طبعا حلو والبعض ماعيش خبرة على
+
+286
+00:29:10,600 --> 00:29:15,740
+أي حال على نفس الفكرة هذه بالضبط تقسم مش ع رقم
+
+287
+00:29:15,740 --> 00:29:20,200
+تقسم على متغير و متغير انت فرضه فوق و يتم اختصارات
+
+288
+00:29:20,200 --> 00:29:26,500
+ايه؟مع بعضهم على اي حال ال DX هي عبارة عن تان ثيتا
+
+289
+00:29:26,500 --> 00:29:32,440
+في دي ثيتا عليهم ال six اللي هي أربعة في six ثيتا
+
+290
+00:29:32,440 --> 00:29:39,260
+وهنا الجدري التربيعي لست عشر six تربية ثيتا ماقص
+
+291
+00:29:39,260 --> 00:29:45,860
+ستة عشر يبقى هذا الكلام بده يساوي تكامل هنا هذا
+
+292
+00:29:45,860 --> 00:29:53,010
+واحد برا16 مع 16 تقلع من تحت الجدر و عندك أربع
+
+293
+00:29:53,010 --> 00:29:59,670
+يبقى واحد على ستاش و في ال bus تان ثيتا في دي ثيتا
+
+294
+00:29:59,670 --> 00:30:07,310
+و المقام سيك ثيتا ابنجي سيك تربية ناقص واحد تان
+
+295
+00:30:07,310 --> 00:30:15,410
+تربية تقلع من تحت الجدر بتان يبقى تان ثيتاطيب تمام
+
+296
+00:30:15,410 --> 00:30:22,070
+اتمام الان ten theta مع ten theta فضل قداش واحد
+
+297
+00:30:22,070 --> 00:30:27,830
+على سك هيق مقلوب من cosine theta في دي فترة يبقى
+
+298
+00:30:27,830 --> 00:30:33,450
+السؤال اللي مكلك عقل شكل طوله بسيط خالص يبقى ده
+
+299
+00:30:33,450 --> 00:30:42,930
+واحد على ست عشر sine theta زائد constant Cبنروح
+
+300
+00:30:42,930 --> 00:30:48,310
+نحسب الوصيلة ثيتا اللى عندنا هذا يا ابجبادي بقوله
+
+301
+00:30:48,310 --> 00:30:54,650
+احنا عندنا مين اللى هو six ثيتا بده يساوي ايه ال
+
+302
+00:30:54,650 --> 00:30:59,910
+six على قداش؟ على اربع اذا لو روحنا رسمنا المثلث
+
+303
+00:30:59,910 --> 00:31:04,770
+القائم الزاويةوقلنا هذه θ وهي الزاوية القناة سك
+
+304
+00:31:04,770 --> 00:31:11,470
+يساوي ال water على المجاور يبقى هذا الضلع التالت E
+
+305
+00:31:11,470 --> 00:31:19,490
+أس اثنين X ماقص ستاشر إذا بصير المسألة هذه تساوي
+
+306
+00:31:19,490 --> 00:31:25,960
+واحد على ستاشرSin يساوي المقابل على ال water يبقى
+
+307
+00:31:25,960 --> 00:31:30,620
+المقابل اللي هو الجدر التربية ل E أس اتنين X ناقص
+
+308
+00:31:30,620 --> 00:31:36,400
+ستة عشر على ال water اللي هو E أس X زائد مين زائد
+
+309
+00:31:36,400 --> 00:31:44,520
+constant C السؤال السادس كمان في شغل من هذا القبيل
+
+310
+00:31:45,100 --> 00:31:53,960
+بيقول تكامل من واحد إلى إيه لإن ال X الكل تكيب على
+
+311
+00:31:53,960 --> 00:32:02,680
+X الجدري التربيعي لمين؟ لواحد زائد للتربيع ال X
+
+312
+00:32:02,680 --> 00:32:06,720
+وهذا كله مين؟ اللي هو DX
+
+313
+00:32:09,670 --> 00:32:14,210
+طلع ليه كويس المثلة، المثلة فيها جدر، الحمد لله
+
+314
+00:32:14,210 --> 00:32:20,910
+فيها جدر، جدر تربيعي، تمام؟ يبقى الإشارة تحت الجدر
+
+315
+00:32:20,910 --> 00:32:28,430
+بمين؟ بالموجة، بس مش X تربية لين X الكل تربية أو
+
+316
+00:32:28,430 --> 00:32:33,130
+لين تربية لك، يبقى كأنه X تبعت القانون، مين أجي
+
+317
+00:32:33,130 --> 00:32:40,050
+مكانها؟هنا بدى أشيل كل إكس بالكامل و أحط بدالها مش
+
+318
+00:32:40,050 --> 00:32:48,780
+عارف من من النسب المثلثيةتان لأن الإشارة بالموجب
+
+319
+00:32:48,780 --> 00:32:49,900
+والمقدار التربية
+
+320
+00:33:14,250 --> 00:33:20,770
+الـDX لو جينا فضلها دي بيصير واحد على X DX يساوي
+
+321
+00:33:20,770 --> 00:33:28,330
+سكتة ربيع ثيتا D ثيتا إذا واحد على X DX هذه كلها
+
+322
+00:33:28,330 --> 00:33:33,230
+بدي أشيلها و أكتب بدا أنا أجدها سكتة ربيع ثيتا
+
+323
+00:33:33,230 --> 00:33:40,330
+يبقى هذا سكتة ربيعثيتا في دي ثيتا خلصنا البس ضايل
+
+324
+00:33:40,330 --> 00:33:46,910
+المقام يبقى على الجدر التربية لواحد زائد تان تربية
+
+325
+00:33:46,910 --> 00:33:57,450
+ثيتا يبقى صلة المثلة تكامل لتان تكييب ثيتا تان
+
+326
+00:33:57,450 --> 00:34:05,800
+تكييب ثيتا فاهمين في سك تربية ثيتا عالىواحد زي تن
+
+327
+00:34:05,800 --> 00:34:13,800
+تربيع سك تربيع تقلع من تحت الجدر بسك ثيتا وهي دي
+
+328
+00:34:13,800 --> 00:34:21,160
+ثيتا و اللي هو بده يساوي تكامل لتان تكييب ثيتا في
+
+329
+00:34:21,160 --> 00:34:29,040
+سك ثيتا في دي ثيتا طيب كيف نسوي هذا فيها نحلل
+
+330
+00:34:29,040 --> 00:34:38,620
+التان موافقينتكامل لتان تربيع ثيتا في تان ثيتا في
+
+331
+00:34:38,620 --> 00:34:51,700
+سك ثيتا في دي ثيتا تكامل
+
+332
+00:34:51,700 --> 00:34:58,460
+لسك تربيع ثيتا ناقص واحد تكامل لسك تربيع ثيتا
+
+333
+00:34:58,460 --> 00:35:06,540
+تربيع ثيتا ناقص واحدسك ثيتا يبقى دي لسك ثيتا اذا
+
+334
+00:35:06,540 --> 00:35:12,660
+نشيل سك ثيتا تان ثيتا دي ثيتا وحطت مكانها دي سك
+
+335
+00:35:12,660 --> 00:35:19,160
+يعني مشتقت سك ثيتا كامل الان احنا بنكمل من W تربية
+
+336
+00:35:19,160 --> 00:35:24,600
+ناقص واحد DW يعني بدنا نضيف للأس واحد ونقسم على
+
+337
+00:35:24,600 --> 00:35:32,090
+الأس الجديد يبقى هذه تساوي تلتسك تكيب ثيتا هذا ال
+
+338
+00:35:32,090 --> 00:35:39,190
+term الأول والواحد تكمله بالنسبة لدي سك بسك يبقى
+
+339
+00:35:39,190 --> 00:35:48,350
+ناقص سك ثيتا زائد constant C نرجع كيف؟ماشي، ماشي،
+
+340
+00:35:48,350 --> 00:35:52,130
+هو لا يهمك، حاضر، يلا حدود التكامل والعوض بقى،
+
+341
+00:35:52,130 --> 00:35:57,670
+يبقى كونوستانسي مافيش، هذا كونوستانسي مافيش، وهذه
+
+342
+00:35:57,670 --> 00:36:05,550
+حدود التكاملطبعاً نرجع لحدود التكامل من خلال
+
+343
+00:36:05,550 --> 00:36:11,490
+التعويضة، لو كانت ال X بي إيه لإن الإيه، مين
+
+344
+00:36:11,490 --> 00:36:16,770
+الزاوية اللي ضلها يسوى واحد وخمسة واربعين درجة،
+
+345
+00:36:16,770 --> 00:36:24,780
+مظبوط، يبقى هذا يصير باي على أربعلو كانت واحد لإن
+
+346
+00:36:24,780 --> 00:36:29,020
+الواحد بصفر مين الزاوية اللي ضلها يساوي Zero في
+
+347
+00:36:29,020 --> 00:36:34,220
+الفترة اللي عندنا هذه يبقى هي Zero إذا تحولت
+
+348
+00:36:34,220 --> 00:36:40,520
+المسألة تكامل من Zero لغاية Pi على 4و من هنا من
+
+349
+00:36:40,520 --> 00:36:47,420
+Zero لغاية Pi على 4 و من هنا ل Zero لغاية Pi على 4
+
+350
+00:36:47,420 --> 00:36:53,060
+و من هنا Zero لغاية Pi على 4 و من هنا Zero لغاية
+
+351
+00:36:53,060 --> 00:37:00,730
+Pi على 4بنعوض بالباية على أربعة طبعا السيك هو
+
+352
+00:37:00,730 --> 00:37:06,470
+مقلوب ال cosine الخمسة وارعين بواحد على جذر اتنين
+
+353
+00:37:06,470 --> 00:37:12,050
+اقلبها بتجيب السيك بصير جذر اتنين الكل تكيب له
+
+354
+00:37:12,050 --> 00:37:19,580
+اتنين جذر اتنين يبقى هذا تلتوهذا اتنين جذري اتنين
+
+355
+00:37:19,580 --> 00:37:26,660
+تغير من الأول ناقص اللي هو six اللي هو جذري اتنين
+
+356
+00:37:26,660 --> 00:37:32,040
+دوري فقط ما غير يبقى جذري اتنين هيعوضه بالقيمة
+
+357
+00:37:32,040 --> 00:37:36,840
+اللي فوق ناقص القيمة اللي تعالى six zero اب واحد
+
+358
+00:37:36,840 --> 00:37:45,300
+في طول يبقى بناقص طول وهذا زائد وsix zero بقداش اب
+
+359
+00:37:45,300 --> 00:37:53,260
+واحديبقى الصارع هذا تلتين جذري اتنين و سالب جذري
+
+360
+00:37:53,260 --> 00:38:02,270
+اتنين مضل كده؟ سالب طول جذري اتنينسالب تلت جدر
+
+361
+00:38:02,270 --> 00:38:07,650
+اتنين يبقى
+
+362
+00:38:07,650 --> 00:38:11,510
+الجواب
+
+363
+00:38:11,510 --> 00:38:17,570
+تلتين ناقص جدر اتنين على تلاتة هذا قيمة التكامل
+
+364
+00:38:17,570 --> 00:38:19,070
+اللي عندنا
+
+365
+00:38:37,920 --> 00:38:44,240
+ننتقل الآن إلى السؤال السابع وما أدرك ما السؤال
+
+366
+00:38:44,240 --> 00:38:50,700
+السابع السؤال السابع بيقول لي تكامل للجدرى التربية
+
+367
+00:38:50,700 --> 00:38:57,700
+إلى أربعة ناقص X على X كله بالنسبة إلى DX
+
+368
+00:39:01,270 --> 00:39:08,410
+هذا السؤال في جذر صحيح بس في عندى جذر فى البصر وفي
+
+369
+00:39:08,410 --> 00:39:12,570
+جذر فى المقام وتبع المقام لا فى مع زاد ولا فى مع
+
+370
+00:39:12,570 --> 00:39:17,870
+ناقص كمية أخرى اتنين الجذر اللى فى البصر مافيش فى
+
+371
+00:39:17,870 --> 00:39:21,870
+تربيع من الشغلات ال standard التلاتة اللى احنا
+
+372
+00:39:21,870 --> 00:39:28,890
+أخدناها المرة الماضية يبقى هذا السؤال ماهواش مباشر
+
+373
+00:39:29,130 --> 00:39:34,790
+زي الستة أمثلة السابقة وإنما في ناحية فنية بدنا
+
+374
+00:39:34,790 --> 00:39:39,430
+نشوف إيش الناحية الفنية يعني هل ممكن أنت تحوله
+
+375
+00:39:39,430 --> 00:39:45,150
+لمين؟ للمسائل تبعها في المرة الماضية نقدر؟ نقدر،
+
+376
+00:39:45,150 --> 00:39:50,930
+نقدر، ليش ما نقدرش؟ يعني هذا كأنه تكامل الجذر
+
+377
+00:39:50,930 --> 00:39:58,780
+التربيه إلى أربعة ناقص X على جذر ال X DXتقوله
+
+378
+00:39:58,780 --> 00:40:05,680
+بسيطة، حط جذر ال X بأي متغير آخر، مظبوط؟ إذا لو
+
+379
+00:40:05,680 --> 00:40:11,920
+حطينا جذر ال X بده يساوي Y، يبقى ال X بده يساوي
+
+380
+00:40:11,920 --> 00:40:19,920
+كده؟ Y تربية، طب احنا بدنا DX، يبقى باتنين Y DY
+
+381
+00:40:21,020 --> 00:40:27,520
+طبعا يبقى شكل مسئلة أصبح على الشكل التالي هذا
+
+382
+00:40:27,520 --> 00:40:33,680
+الجدر التربيعي وهي الأربعة ناقص ال X هي مين؟ Y
+
+383
+00:40:33,680 --> 00:40:41,170
+تربيع و جدر ال X هي مين؟ Yو ال dx هي اتنين y dy
+
+384
+00:40:41,170 --> 00:40:46,750
+افضل ان بنختصر ال y مع ال y و اتنين بشرفنا برا
+
+385
+00:40:46,750 --> 00:40:51,930
+التكامل و بيبقى لدينا الجدر التربيه لاربعة ناقص y
+
+386
+00:40:51,930 --> 00:40:59,890
+تربيه dy يبقى صارت المثلة فيها الجدر تبعناها ا
+
+387
+00:40:59,890 --> 00:41:04,430
+اللى اتحدثنا عنه في الجزء النظري المرة الماضية
+
+388
+00:41:04,430 --> 00:41:10,920
+مظبوطفي جذر و تحت الجذر في إشارة لمقدار و واحد
+
+389
+00:41:10,920 --> 00:41:18,920
+فيهم مقدار ثابت والتاني مربع لمتغير يبقى فعلا هذا
+
+390
+00:41:18,920 --> 00:41:24,640
+تعرضنا لشكله المرة الماضية وبناء عليه بدنا نحكم
+
+391
+00:41:24,640 --> 00:41:30,330
+على شكل التعويضة تبع هذه المثلةمش انا اعرف شكل
+
+392
+00:41:30,330 --> 00:41:33,350
+التعويض، ابقى ابقالي عليه إشارة السلم اللي أمامي
+
+393
+00:41:33,350 --> 00:41:39,610
+المتغير يبقى التعويض بدلالة sign همتاز يبقى بيقولي
+
+394
+00:41:39,610 --> 00:41:45,710
+حطله هنا ال Y يساوي 2 في ال sign الزاوية ثيتا و
+
+395
+00:41:45,710 --> 00:41:50,510
+ثيتا أكبر من سالب بي على اتنين وأقل من بي على
+
+396
+00:41:50,510 --> 00:41:59,360
+اتنينأشتق يبقى dy اتنين cosine ثيتا في d ثيتا يبقى
+
+397
+00:41:59,360 --> 00:42:05,760
+صارت مسألة على الشكل التالي اتنين تكامل الجذر
+
+398
+00:42:05,760 --> 00:42:12,280
+التربيع الى اربعة ناقص اربعة sin تربيع ثيتا ضال
+
+399
+00:42:12,280 --> 00:42:17,980
+عندي ال dy له اتنين cosine ثيتا d ثيتا يبقى اتنين
+
+400
+00:42:17,980 --> 00:42:24,130
+cosine ثيتا في d ثيتاطب اتطلعلي هنا كويس، هاي
+
+401
+00:42:24,130 --> 00:42:30,810
+اتنين اللي برا، واربعة مع اربعة تطلع برا باتنين،
+
+402
+00:42:30,810 --> 00:42:36,770
+يبقى هاي كمان اتنين، واتنين هادي كمان شرفينا برا،
+
+403
+00:42:36,770 --> 00:42:44,060
+وهي تكامل، بلقدش هنا واحد ناقص sign ترجعله مين؟كو
+
+404
+00:42:44,060 --> 00:42:50,060
+ساين تربيع تطلع من تحت الجدر بكو ساين ثيتا وعندك
+
+405
+00:42:50,060 --> 00:42:57,580
+هنا كو ساين ثيتا وهي دي ثيتا تمام؟ طيب هذا الكلام
+
+406
+00:42:57,580 --> 00:43:04,880
+بده يساوي هدول بتمانية وهدي كو ساين في كو ساين كو
+
+407
+00:43:04,880 --> 00:43:10,100
+ساين تربيع مقدرش أكملها إلا إذا حولتها بدلالة
+
+408
+00:43:10,100 --> 00:43:12,040
+بدلالة
+
+409
+00:43:21,760 --> 00:43:28,860
+يبقى من حول ابن ليلة ضعف الزاوية يبقى هذه اللي هي
+
+410
+00:43:28,860 --> 00:43:36,900
+عبارة عن نص واحد زائد cosine اتنين ثيتا كله
+
+411
+00:43:36,900 --> 00:43:44,040
+بالنسبة الى D ثيتايبقى النتيجة تساوي أربعة وهذه
+
+412
+00:43:44,040 --> 00:43:51,740
+تكاملها بثيتا وهذه بصين اتنين ثيتا على اتنين زائد
+
+413
+00:43:51,740 --> 00:43:57,300
+constant C طب احنا الحين لما نروح نرسم مثلث برسمش
+
+414
+00:43:57,300 --> 00:43:59,640
+الزاوية اتنين ثيتا برسم الزاوية
+
+415
+00:44:04,630 --> 00:44:10,890
+يبقى لو جيت على هذه هيك ههه و شيلت و كتبت بدلها
+
+416
+00:44:10,890 --> 00:44:17,380
+تنين cosine تيتا cosine تيتابنختصر اتنين مع اتنين
+
+417
+00:44:17,380 --> 00:44:23,960
+بتروح يبقى آلة مسئلتي الى الشكل التالي اربع ثيتا
+
+418
+00:44:23,960 --> 00:44:30,780
+زاد اتنين مع اتنين راحت بتيجي بس الأربع عندنا اللي
+
+419
+00:44:30,780 --> 00:44:38,200
+هو main sin theta cosine theta زاد constant C
+
+420
+00:44:38,200 --> 00:44:45,890
+بنرجع لثيتا هي ثيتا اللي عندنا يا دييبقى ثيتا
+
+421
+00:44:45,890 --> 00:44:49,630
+يساوي
+
+422
+00:44:49,630 --> 00:44:58,590
+Y على 2 يعني لو روحت رسمت المثلث القائم الزاوية في
+
+423
+00:45:01,730 --> 00:45:08,770
+الجيب يساوي المقابل على ال water يبقى الضلع التالت
+
+424
+00:45:08,770 --> 00:45:15,250
+أربعة ناقص Y تربية. إذا انقلت المثل إلى الشكل
+
+425
+00:45:15,250 --> 00:45:20,690
+التالي أربعةمن هنا بقدر أقول له θ تساوي sin
+
+426
+00:45:20,690 --> 00:45:28,090
+inverse y على اتنين يبقى ايه sin inverse لل y على
+
+427
+00:45:28,090 --> 00:45:37,930
+اتنين زائد اربع sin θ المقابل على الوتر ال y على
+
+428
+00:45:37,930 --> 00:45:46,810
+اتنين cos θ المجاور على الوتر اربع ناقص y تربيعتحت
+
+429
+00:45:46,810 --> 00:45:53,770
+الجدر كله على جداش على اتنين زائد constant C يبقى
+
+430
+00:45:53,770 --> 00:45:59,350
+النتيجة النهائية اربع sign inverse عندنا نوع من
+
+431
+00:45:59,350 --> 00:46:03,910
+جداش يا شباب جدر ال X إذا بدي اشيلها و اكتب مكانها
+
+432
+00:46:03,910 --> 00:46:11,590
+جدر ال X يبقى sign inverse جدر ال X على اتنين زائد
+
+433
+00:46:11,590 --> 00:46:16,750
+اتنين في اتنينةيبقى أربعة مع الأربعة مع السلامة و
+
+434
+00:46:16,750 --> 00:46:24,110
+Y هي جذر ال X وهذا الجذر التربيعي لأربعة ناقص Y
+
+435
+00:46:24,110 --> 00:46:33,270
+تربيع هي ال X وهذا زائد constant C السؤال الأخير
+
+436
+00:46:33,270 --> 00:46:41,650
+في هذا section بيقول ما يأتيسؤال تمانية تكامل X
+
+437
+00:46:41,650 --> 00:46:48,950
+على الجذر التربيعي لل X تربيع ناقص اتنين X ناقص
+
+438
+00:46:48,950 --> 00:46:52,350
+ثلاثة كله في DX
+
+439
+00:46:56,770 --> 00:47:04,070
+أول مرة نشوف جدر بهذا الشكل في هذا ال section هذا
+
+440
+00:47:04,070 --> 00:47:09,030
+الجدر ليس على شكل الجدور اللي شرحناها في جزء النظر
+
+441
+00:47:09,030 --> 00:47:14,030
+لكن تشغل عقلك هكذا، توصل للجدر اللي شرحناها في
+
+442
+00:47:14,030 --> 00:47:19,650
+الجزء النظري كيف كان التالي؟ هى تكامل وهى ال X وهى
+
+443
+00:47:19,650 --> 00:47:26,260
+ال DX وهى الجدر التربية هل هذا مربع كامل؟لا مش
+
+444
+00:47:26,260 --> 00:47:31,400
+مربع كامل يفجأة بدنا نحوله إلى مربع كامل كده
+
+445
+00:47:31,400 --> 00:47:37,340
+بالزموه واحد بنطرح واحد مع ناقص ثلاثة بيصير كده
+
+446
+00:47:37,340 --> 00:47:43,100
+ناقص أربعة يفجأة أضفنا واحد واطرحنا واحد هي الواحد
+
+447
+00:47:43,100 --> 00:47:46,920
+اللي أضفناه سالب واحد مع سالب ثلاثة بيعطيني سالب
+
+448
+00:47:46,920 --> 00:47:53,750
+أربعة طلعلي للمقدر هذا مربع كاملمظبوط هيك يبقى
+
+449
+00:47:53,750 --> 00:48:00,590
+تكامل x dx على مين؟ على ال x ناقص واحد لكل تربية
+
+450
+00:48:00,590 --> 00:48:09,430
+ناقص أربعة كل تحت الجدربعد ذلك، نريد أن نكمل هذه
+
+451
+00:48:09,430 --> 00:48:13,690
+الدلالة. أنا أقول إن هذا أصبح جذب، لكن مكان الـ X
+
+452
+00:48:13,690 --> 00:48:18,850
+شجعني. X ناقص واحد. إذن، عند التعويض، أريد أن أضع
+
+453
+00:48:18,850 --> 00:48:24,610
+X ناقص واحد يسوء. كم يسوء، الله يعلم. إن شرسلي
+
+454
+00:48:24,610 --> 00:48:33,150
+بالأمين، للمقدار الثابت يبقى 2 كم؟تسك تيتا و تيتا
+
+455
+00:48:33,150 --> 00:48:40,340
+أكبر من أو تساوي Zero أقل من Pi على 2طيب ممكن اقول
+
+456
+00:48:40,340 --> 00:48:46,940
+ال X يسوى واحد زائد اتنين في سك الثيتا بدي دي X
+
+457
+00:48:46,940 --> 00:48:54,200
+يبقى اتنين سك ثيتا تان ثيتا دي ثيتا يبقى قلط
+
+458
+00:48:54,200 --> 00:49:00,200
+مسئلتي للشكل التالف بدي اشيل ال X و احط مثل واحد
+
+459
+00:49:00,200 --> 00:49:07,310
+زائد اتنين سك ثيتا يبقى واحد زائد اتنين سك ثيتافى
+
+460
+00:49:07,310 --> 00:49:14,130
+الـDX اللى هو باتنين سيك ثيتا تان ثيتا دي ثيتا كل
+
+461
+00:49:14,130 --> 00:49:22,830
+هذا مقسوما على الجذري التربيعى لاربعة سيك تربيع
+
+462
+00:49:22,830 --> 00:49:29,100
+ثيتا ناقص اربعةهذا المقدار كله شيلته و حاطيت بقاله
+
+463
+00:49:29,100 --> 00:49:34,740
+اتنين سكتاربيع، بيبقى ربع هذا اربعة سكتاربيع ثيتا
+
+464
+00:49:34,740 --> 00:49:41,290
+و هذا الأربعة كما هييبقى قلة مسألتي الى الشكل
+
+465
+00:49:41,290 --> 00:49:45,370
+التالي اظن اتنين هذه فيش غيرها اطلع برضه مع
+
+466
+00:49:45,370 --> 00:49:52,930
+السلامة و ايتا كامة واحد زائد اتنين في six ثيتا و
+
+467
+00:49:52,930 --> 00:50:00,850
+عندك هذه تظل عندي six ثيتا six ثيتا ten ثيتا d
+
+468
+00:50:00,850 --> 00:50:06,540
+ثيتا مقسوما علىهذه اربعة مع اربعة تطلع بره في جدش
+
+469
+00:50:06,540 --> 00:50:11,660
+كمان باتنين بضل الجدر التربيه ل six تربيه ناقص
+
+470
+00:50:11,660 --> 00:50:18,550
+واحد تان تربيه تطلع من تحت الجدر منبتان تيتا تان
+
+471
+00:50:18,550 --> 00:50:23,290
+تيتا مع تان تيتا الله يسهل عليها يبقى آلة المسألة
+
+472
+00:50:23,290 --> 00:50:31,030
+إلى الشكل التالي تكامل ل سك تيتا زائد اتنين سك
+
+473
+00:50:31,030 --> 00:50:38,990
+تربية تيتا كله في دي تيتاالأولى سؤال السنبرت
+
+474
+00:50:38,990 --> 00:50:43,770
+معروفة اللى هى learn absolute value ل six theta
+
+475
+00:50:43,770 --> 00:50:53,530
+زائد تان ثيتا وهادي زائد اتنين تان ثيتا وهنا زائد
+
+476
+00:50:53,530 --> 00:50:59,970
+constant C بعد هيك بدنا نرجع نحول المثلة بدلالة
+
+477
+00:50:59,970 --> 00:51:05,250
+من؟ بدلالة ال X بنقول له اه هادي هاها
+
+478
+00:51:07,690 --> 00:51:14,330
+مرة تانية بقدر أقول سك ثيتا بدي يساوي x ناقص واحد
+
+479
+00:51:14,330 --> 00:51:19,710
+على مين؟ على الإتنين إذا لو روحت رسمت المثلث
+
+480
+00:51:19,710 --> 00:51:25,730
+القائم الزاوية وقلنا هذه الزاوية ثيتا سك يساوي
+
+481
+00:51:25,730 --> 00:51:34,470
+الوطر على المجاوريبقى الضلع التالت هو X ناقص واحد
+
+482
+00:51:34,470 --> 00:51:41,310
+لكل تربية ناقص أربعة حسب نظرية في ثيابورت يبقى هذا
+
+483
+00:51:41,310 --> 00:51:48,640
+الكلام بده يساويLin absolute value سك ال water على
+
+484
+00:51:48,640 --> 00:51:55,100
+المجاور يبقى x ناقص واحد على اتنين زائد تاني
+
+485
+00:51:55,100 --> 00:52:00,580
+المقابل على المجاور يبقى الجدري التربية إلى ال x
+
+486
+00:52:00,580 --> 00:52:07,300
+ناقص واحد لكل تربية ناقص اربعة بالشكل اللي عندنا
+
+487
+00:52:07,300 --> 00:52:14,360
+هذا على مين؟ على الاتنين وهي خلصنا مين؟ ال linزائد
+
+488
+00:52:14,360 --> 00:52:22,220
+اتنين سان الجدري التربيعي لل X ناقص واحد لكل تربيع
+
+489
+00:52:22,220 --> 00:52:33,680
+ناقص اربعة على مين على الاتنين زائد كله سن سين لو
+
+490
+00:52:33,680 --> 00:52:38,700
+رحت فتحت الكتاب، ماتلاقيش الإجابة ده معناته حملة
+
+491
+00:52:38,700 --> 00:52:45,630
+غلط، ما غلط ولا حاجة طلعلي هناممكن اخد عمل مشترك
+
+492
+00:52:45,630 --> 00:52:51,270
+من الاتنين هدول قداش اتنين بصير X ناقص واحد زائد
+
+493
+00:52:51,270 --> 00:52:56,210
+الجذر كله على اتنين بصير لن الباص ناقص لن المقام
+
+494
+00:52:56,210 --> 00:53:03,610
+يبقى بصير لن X ناقص واحد زائد الجذر التربيعي هذا
+
+495
+00:53:03,610 --> 00:53:08,350
+لو رجعته لأصله اللي هو راس المثلة فيه مشكلة؟ لأ
+
+496
+00:53:08,560 --> 00:53:15,060
+يبقى بروح بقوله هاي x تربيع ناقص اتنين x ناقص
+
+497
+00:53:15,060 --> 00:53:20,120
+ثلاثة وجفّل من الabsolute بقى اللي عندي main ناقص
+
+498
+00:53:20,120 --> 00:53:25,860
+للاتنين ايه وروح نقوله اتنين هذول مع اتنين مع
+
+499
+00:53:25,860 --> 00:53:32,480
+السلامة وهذا ال x تربيع ناقص اتنين x ناقص ثلاثة
+
+500
+00:53:32,480 --> 00:53:40,960
+وزائد constant C1حيث الـ C1 بده يساوي الـ C اللي
+
+501
+00:53:40,960 --> 00:53:48,640
+عندنا ناقص لن اتنين يعني من هنا بده يطلع لن الباص
+
+502
+00:53:48,640 --> 00:53:55,300
+ناقص لن اتنين لن A على B لن الـ A ناقص لن الـ B
+
+503
+00:53:55,300 --> 00:53:59,720
+ناقص لن الـ B مقدار ثابت والـ C مقدار ثابت حطيتهم
+
+504
+00:53:59,720 --> 00:54:03,620
+بمقدار ثابت جديد وبالتالي لو روحت على الكتاب بلاقي
+
+505
+00:54:03,620 --> 00:54:08,590
+هذه الإجابةوبلاقيش الإجابة اللي منها أفق وكلا
+
+506
+00:54:08,590 --> 00:54:12,570
+الحالين صحيحة يعني أنت لو وقفت هنا خلاص وروحت
+
+507
+00:54:12,570 --> 00:54:18,210
+وخليتها ماعنا مشكلة في هذه الحالة إذا وصلنا لنهاية
+
+508
+00:54:18,210 --> 00:54:25,680
+هذا ال section وإليكم أرقام المسائليبقى exercises
+
+509
+00:54:25,680 --> 00:54:33,120
+اللي هو تمانية تلاتة المسائل الآيات التالية من
+
+510
+00:54:33,120 --> 00:54:41,860
+واحد لغاية تمانية واربعين الأدر الله يعطيك العافية
+
+511
+00:54:41,860 --> 00:54:46,580
+انتهى ال section غدا ان شاء الله نبدأ ال section
+
+512
+00:54:46,580 --> 00:54:51,260
+الجديد على الطريقة التالتة من طرق التكامل
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/U3pzh94YIHQ_postprocess.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/U3pzh94YIHQ_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1f9bfe6837bbbb9d9cc9fe4163e7a3f4235cd88c
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/U3pzh94YIHQ_postprocess.srt
@@ -0,0 +1,2188 @@
+1
+00:00:17,920 --> 00:00:24,040
+المرة الماضية اتبعنا في استخدام قاعدة libital
+
+2
+00:00:24,040 --> 00:00:30,420
+لإيجاد نهايات للدولواخذنا حالتين و بقيت الحالة
+
+3
+00:00:30,420 --> 00:00:36,360
+الثالثة من باب التذكير و ذكر فإن ذكرى تنفع
+
+4
+00:00:36,360 --> 00:00:42,180
+المؤمنين أقولالنقطة الأولى اللى ذكرناها بالنسبة
+
+5
+00:00:42,180 --> 00:00:45,920
+لقاعة Lobital إذا كانت نتيجة التعود المباشر هي
+
+6
+00:00:45,920 --> 00:00:50,880
+Zero على Zero أو Infinity على Infinity من جول
+
+7
+00:00:50,880 --> 00:00:55,640
+limit لل F of X على G of X لما ال X بدأ تروح إلى A
+
+8
+00:00:55,640 --> 00:01:00,420
+سواء كان A رقم أو Zero أو Infinity يبقى هذا بدى
+
+9
+00:01:00,420 --> 00:01:04,800
+يسوي limit مشتق الدالة البسطى على حده مقصوما على
+
+10
+00:01:04,800 --> 00:01:11,450
+مشتق الدالة المقام واخدنا على ذلكبدل المثال خمسة
+
+11
+00:01:11,450 --> 00:01:17,630
+أمثلة ثم انتقلنا بعد ذلك إلى النقطة الثانية وهي
+
+12
+00:01:18,030 --> 00:01:23,370
+الكمية غير المعينة على الصيغة zero في infinity أو
+
+13
+00:01:23,370 --> 00:01:29,090
+infinity minus infinity مثل هذه القيام بدنا نروح
+
+14
+00:01:29,090 --> 00:01:34,050
+نحسب ل limit يبقى بدنا نروح بأي طريقة رياضية ان
+
+15
+00:01:34,050 --> 00:01:38,470
+حولها إلى الحالة الأولى وهي zero على zero أو
+
+16
+00:01:38,470 --> 00:01:45,100
+infinity على infinityيبقى هتان الحالتان دوري ستاء
+
+17
+00:01:45,100 --> 00:01:49,260
+في المرة الماضية الآن بنروح للحالة الثالثة
+
+18
+00:01:49,260 --> 00:01:54,600
+والاخيرة إذا كانت الكيمية تغير المعينة على صيغة
+
+19
+00:01:54,600 --> 00:02:01,760
+واحد أس مال نهاية أو zero أس zero أو مال مال نهاية
+
+20
+00:02:01,760 --> 00:02:09,060
+أس zeroمش هانيجي ندرس هذه الحالة يبقى بدنا .. بدنا
+
+21
+00:02:09,060 --> 00:02:15,600
+نروح نعطيها الملاحظة هذه ثم ندخل في الحالة لإن هذا
+
+22
+00:02:15,600 --> 00:02:20,940
+أو في كيفية التعامل مع مثل هذه الحالة ال remark
+
+23
+00:02:20,940 --> 00:02:25,440
+بتقول إيه؟ لو كان limit لإن ال f of x لما ال x بده
+
+24
+00:02:25,440 --> 00:02:32,370
+يروح ل zero بده يساوي ال L thenبنرجع لمعلوماتنا عن
+
+25
+00:02:32,370 --> 00:02:36,570
+ال limit لما دراسنا ال limit في calculus ايه لجينا
+
+26
+00:02:36,570 --> 00:02:42,450
+ان ال limit عندها صلاحيات كتيرة جدا بتدخل على
+
+27
+00:02:42,450 --> 00:02:50,430
+الجثه اللي مرفوه لأوسف تدخل تحت الجدور تدخل على
+
+28
+00:02:50,430 --> 00:02:55,910
+الذنب تبع النسبة المثلثية اربعة في هذا الفصل بتدخل
+
+29
+00:02:55,910 --> 00:03:01,570
+على اللي جوا الانهى على الكمية اللى جوا منه اللين
+
+30
+00:03:01,570 --> 00:03:05,770
+اذا بناء عليها هندخلها جوا من اللين اللين هذه
+
+31
+00:03:05,770 --> 00:03:10,670
+تتعدى الحدود والسدود والقيود ماعرفش بقدر اقول هى
+
+32
+00:03:10,670 --> 00:03:15,450
+كأنها من وين من الأمم المتحدة طبعا يبقى بدى اروح
+
+33
+00:03:15,450 --> 00:03:20,810
+ادخل ال limit داخل من؟ داخل اللين يبقى بناء عليها
+
+34
+00:03:20,810 --> 00:03:28,390
+بقدر اقول ان اللينللـ limit f of x لما الـ x بدها
+
+35
+00:03:28,390 --> 00:03:35,670
+تروح الى a الكلام هذا كله بده يساوي الـ L إذا
+
+36
+00:03:35,670 --> 00:03:41,410
+بإمكاننا نتخلص من هذه اللينةفبرفع الطرفين كأس لمين
+
+37
+00:03:41,410 --> 00:03:49,650
+للعدد A يبقى إذا E أس لن لlimit لما ال X بدها تروح
+
+38
+00:03:49,650 --> 00:04:01,960
+لل zero لمين لل F of X بده يساوي E أس Lالـ A قد
+
+39
+00:04:01,960 --> 00:04:07,440
+تكون Zero و قد تكون عدد و قد تكون Infinity كله A
+
+40
+00:04:09,780 --> 00:04:15,760
+طيب الآن ال E و ال N دلتان عكس بعض و طبعا حسبنا
+
+41
+00:04:15,760 --> 00:04:21,280
+القيمة E أسلن X يسوى X إذا E أسلن المقدار هذا كله
+
+42
+00:04:21,280 --> 00:04:27,160
+بهذا المقدار يبقى ال limit لما ال X بده يروح إلى A
+
+43
+00:04:27,160 --> 00:04:35,810
+لل F of X بده يسوى 100 T أسليبقى من الآن فصاعدا لو
+
+44
+00:04:35,810 --> 00:04:41,070
+كان limit ل لن بل لما ال X تروح أين ما تروح يبقى
+
+45
+00:04:41,070 --> 00:04:45,230
+في هذه الحالة كان هذا النتج يسوي L إذا ال limit
+
+46
+00:04:45,230 --> 00:04:51,650
+يتدل نفسه بدون لن هي عبارة عن E أسهل برقمخلّي
+
+47
+00:04:51,650 --> 00:04:56,970
+هالمعلومة عندك و بدنا نستخدمها في كل حالة من
+
+48
+00:04:56,970 --> 00:05:02,610
+الحالات الثلاث إلا أننا لذلك هروح نعطي أمثلة على
+
+49
+00:05:02,610 --> 00:05:08,930
+هذه الحالات الثلاث كيف الأمثلة؟ كالتالي بروح نقول
+
+50
+00:05:08,930 --> 00:05:15,850
+find the following limits
+
+51
+00:05:15,850 --> 00:05:23,160
+بدنا النهايات التاليةالنهاية الأولى بيقول ال limit
+
+52
+00:05:23,160 --> 00:05:33,480
+لما
+
+53
+00:05:33,480 --> 00:05:41,880
+ال x بدها تروح الى infinity لمن؟ ل 1 زائد a على x
+
+54
+00:05:41,880 --> 00:05:47,440
+كله to the power x و ال a is constant
+
+55
+00:05:55,130 --> 00:06:01,070
+انظروا يا عزيزي، من حد ما نرى نتيجة التعويض
+
+56
+00:06:01,070 --> 00:06:05,630
+المباشر في مثل، لو طلع أي واحدة من التلاتة دول،
+
+57
+00:06:05,630 --> 00:06:12,730
+بدنا نعمل أربع خطوات لخامس لها، تمام؟ الآن ما هي
+
+58
+00:06:12,730 --> 00:06:19,430
+الخطوات الأربع التي بها سنحصل على حل هذه المثلة؟
+
+59
+00:06:21,810 --> 00:06:26,230
+بنشوف قبل كل شيء، مين هذه من الحالات التلاتة اللي
+
+60
+00:06:26,230 --> 00:06:30,430
+عندنا، إذا بدي أحط X بمالة نهاية، عدد على مالة
+
+61
+00:06:30,430 --> 00:06:36,690
+نهاية؟ Zero، درجة درجة؟ واحد، أس؟ نين، الحالة اللي
+
+62
+00:06:36,690 --> 00:06:41,290
+فوق، يبقى التعويض المباشر لهذه الحالة جاب لي واحد
+
+63
+00:06:41,290 --> 00:06:46,560
+أس infinityإذا طلعت واحدة من الحلوات التلاتة نذهب
+
+64
+00:06:46,560 --> 00:06:52,600
+إلى الخطوات الأربعة التي نتحدث عنها يبقى بروح بقول
+
+65
+00:06:52,600 --> 00:07:00,860
+الخطوات كتر الخطوة الأولى بتقول افرض ان ال F of X
+
+66
+00:07:00,860 --> 00:07:06,160
+بيساوي واحد زائد A على X to the power X
+
+67
+00:07:08,910 --> 00:07:12,590
+فرضنا ان f of x هي الدالة المراد إيجاد ال limit
+
+68
+00:07:12,590 --> 00:07:21,410
+لها الخطوة الثانية بتروح تاخد لن للطرفين يبجى لن
+
+69
+00:07:21,410 --> 00:07:29,530
+ال f of x بده يساوي لن واحد زائد a على x to the
+
+70
+00:07:29,530 --> 00:07:37,280
+power xهذا ماذا يعطي لك؟ ان ال len f of x بده
+
+71
+00:07:37,280 --> 00:07:42,540
+يساوي هذا يعتبر أسل كمية داخل ال len يبقى الأسل
+
+72
+00:07:42,540 --> 00:07:48,920
+بنقوله شرفنا برا حسب خواص ال len يبقى x في len
+
+73
+00:07:48,920 --> 00:07:55,500
+واحد زائد a على x خلصنا الخطوة التانية الخطوة
+
+74
+00:07:55,500 --> 00:08:00,870
+التالتةالخطوة التالتة بدنا نروح ناخد ال limit
+
+75
+00:08:00,870 --> 00:08:07,810
+للطرفين يبقى limit لما ال x بدها تروح لل infinity
+
+76
+00:08:07,810 --> 00:08:15,830
+لمن؟ لمن ال f of x بدها تساوي ال limit لما ال x
+
+77
+00:08:15,830 --> 00:08:27,070
+بدها تروح لل infinity لمن؟ لل x فمن 1 زائد a على x
+
+78
+00:08:27,180 --> 00:08:34,260
+يبقى احنا في الخطوة التالتة، بنروح للرابع حتى ننجز
+
+79
+00:08:34,260 --> 00:08:40,480
+هذه الخطوة، تمام؟ بقول كويس، عوّط عامله بشري وشوف
+
+80
+00:08:40,480 --> 00:08:46,480
+إيش جباننا، الاكسب من infinity، مضروبة فيه، عدد
+
+81
+00:08:46,480 --> 00:08:52,680
+على infinity؟ Zero، لإن الواحد يبقى يد يسارة
+
+82
+00:08:52,680 --> 00:08:56,790
+infinity في zeroInfinity في Zero والله Zero في
+
+83
+00:08:56,790 --> 00:09:00,810
+Infinity كله نفس الشيء زي ما درسنا في المحاضرة
+
+84
+00:09:00,810 --> 00:09:05,750
+الماضية تمام؟ إذا مدام طلع Infinity في Zero بدي
+
+85
+00:09:05,750 --> 00:09:11,690
+أضبط مسألة بأي طريقة رياضية بحيث أحولها إلى صفر
+
+86
+00:09:11,690 --> 00:09:16,630
+على صفر أوInfinity على Infinity من كله بسيطة جدا
+
+87
+00:09:16,630 --> 00:09:21,830
+يبقى هذه limit لما ال X بدأ تروح الى Infinity
+
+88
+00:09:21,830 --> 00:09:28,190
+لمين؟ ها ممكن أنزل ال X هذه تحت بصير X والسالب
+
+89
+00:09:28,190 --> 00:09:34,610
+واحد يعني مين؟ يعني واحد على X يبقى هذه بدأ تصير
+
+90
+00:09:34,610 --> 00:09:42,230
+Lin الواحد زائد A على X كله على واحد على Xطب لما
+
+91
+00:09:42,230 --> 00:09:46,530
+عملت الحركة البسيطة هذه من ناحية رياضية سليمة، لكن
+
+92
+00:09:46,530 --> 00:09:52,310
+شوف شو أملتنا، أمر بسيط، شو عمل؟ ها infinity،
+
+93
+00:09:52,310 --> 00:09:56,430
+zero، لإن الواحد ب zero يبقى البسط ب zero، واحد
+
+94
+00:09:56,430 --> 00:10:01,050
+علي infinity ب zero، إذا تحولت مسألة بهذه العملية
+
+95
+00:10:01,050 --> 00:10:06,680
+الرياضية البسيطة من infinity في zero إلى0 على 0
+
+96
+00:10:06,680 --> 00:10:12,160
+إذا بقدر استخدم قاعدة لبيتال تمام يبقى بقوله هذه
+
+97
+00:10:12,160 --> 00:10:18,380
+تساوي limit لما ال X بدأ تروح لين ل ال infinity
+
+98
+00:10:18,380 --> 00:10:24,900
+لمشتقة ال bus على مشتقة المقام مشتقة ال bus واحد
+
+99
+00:10:25,060 --> 00:10:32,660
+على واحد زائد a على x في مشتقة مداخل الليل له سالب
+
+100
+00:10:32,660 --> 00:10:38,640
+a على x ثربية a مقدار ثابت مشتقة واحد على x ليه
+
+101
+00:10:38,640 --> 00:10:45,780
+بسالب واحد على x ثربية المقام مشتقته بسالب واحد
+
+102
+00:10:45,780 --> 00:10:51,370
+على x ثربيةنختصر لو اختصرنا سالب واحد على أكثر
+
+103
+00:10:51,370 --> 00:10:53,190
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+104
+00:10:53,190 --> 00:10:53,230
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+105
+00:10:53,230 --> 00:10:53,450
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+106
+00:10:53,450 --> 00:10:53,730
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+107
+00:10:53,730 --> 00:10:54,390
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+108
+00:10:54,390 --> 00:10:55,570
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+109
+00:10:55,570 --> 00:11:00,170
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+110
+00:11:00,170 --> 00:11:04,950
+بيهما سالب
+
+111
+00:11:04,950 --> 00:11:11,010
+واحد على أكثر بيهما سالب واحد علىأيه على infinity
+
+112
+00:11:11,010 --> 00:11:15,190
+بزير؟ رفضان جداش؟ واحد على واحد، يبقى يا ده بده
+
+113
+00:11:15,190 --> 00:11:20,550
+يصير إيه يا في؟ واحد ويساوي جداش؟ إيه؟ إذا ال
+
+114
+00:11:20,550 --> 00:11:26,030
+limit لده ليساوي إيه؟ خلصناه؟ما خلصتش انت اللي
+
+115
+00:11:26,030 --> 00:11:30,910
+جيبته هي انت جيبت limit ل لن الدالة واحنا اش بدنا
+
+116
+00:11:30,910 --> 00:11:34,810
+limit ل الدالة وليس limit ل لن الدالة. اذا احنا
+
+117
+00:11:34,810 --> 00:11:40,630
+اشتغلنا ثلاث خطوات. ايه الخطوة الرابعة؟ اللي هو
+
+118
+00:11:40,630 --> 00:11:46,990
+الموضوع ال remark اللي احنا عشرنا اليها هنا.مش أنا
+
+119
+00:11:46,990 --> 00:11:53,850
+أجيب هذه بدي أرفع اتنين كأس للعدد A هنا limit لإن
+
+120
+00:11:53,850 --> 00:11:59,090
+ال F of X لما ال X بدي يروح إلى A limit لإن ال F
+
+121
+00:11:59,090 --> 00:12:04,530
+of X لما ال X بدي يروح إلى Infinity هذا كان يسوى L
+
+122
+00:12:04,530 --> 00:12:11,910
+لـL طلعت هنا إذا ال limit لدنا بدي يسوى E أس L إذا
+
+123
+00:12:11,910 --> 00:12:16,730
+بنروح للخطوة الرابعةيبقى انا بروح اقول اذا ال
+
+124
+00:12:16,730 --> 00:12:22,690
+limit لدالة الأصلية واحد زائد a على x كله to the
+
+125
+00:12:22,690 --> 00:12:28,450
+power x لما ال x tends to infinity بده يساوي e أس
+
+126
+00:12:28,450 --> 00:12:32,650
+a تمام؟
+
+127
+00:12:32,650 --> 00:12:36,870
+يبقى خلاني اوصلك أربع خطوات وانتهي بقى من المثل
+
+128
+00:12:36,870 --> 00:12:42,030
+اللي عندنا تمامالكن أنا إلى خاطر أطرح بعض
+
+129
+00:12:42,030 --> 00:12:48,210
+التساؤلات من خلال هالشكل اللي وصلنا له هنا بدي بدأ
+
+130
+00:12:48,210 --> 00:12:53,970
+أسأل، يا ناس هذا مرة علينا قبل هيك؟ شفناه؟ فصل
+
+131
+00:12:53,970 --> 00:13:01,510
+الأول؟ يعني لما أخذنا الفصل الأول قبل كم من شهر؟
+
+132
+00:13:04,440 --> 00:13:07,760
+يعني برضه في الوصف الأول و الله في التاني يعني في
+
+133
+00:13:07,760 --> 00:13:09,320
+نية section تقريبا
+
+134
+00:13:13,190 --> 00:13:26,230
+أه يعني سبعة تلاتة سبعة تلاتة سبعة تلاتة سبعة
+
+135
+00:13:26,230 --> 00:13:26,810
+تلاتة سبعة تلاتة سبعة تلاتة سبعة تلاتة سبعة تلاتة
+
+136
+00:13:26,810 --> 00:13:33,230
+سبعة تلاتة سبعة تلاتة سبعة
+
+137
+00:13:33,230 --> 00:13:37,410
+تلاتة
+
+138
+00:13:37,410 --> 00:13:45,190
+سبعة تلاتةبس بدل الواحد اجانبين اجانبين اذا a كله
+
+139
+00:13:45,190 --> 00:13:50,670
+صح لو كانت ال a بواحد يبقى بده اشيل ال a و احط ال
+
+140
+00:13:50,670 --> 00:13:56,210
+واحد بصير العدد a يسوي limit واحد زارد واحد على x
+
+141
+00:13:56,210 --> 00:14:01,010
+لما ال x بده تروح لوين لل infinity يبقى اللي احنا
+
+142
+00:14:01,010 --> 00:14:03,730
+اخدناها كخاصية لل exponential function
+
+143
+00:14:07,680 --> 00:14:13,320
+طب خليني اطرح التساوي التالي لو وضت لك limit واحد
+
+144
+00:14:13,320 --> 00:14:17,600
+زائد تلاتة على X لما ال X بده تروح لإمالانها كده
+
+145
+00:14:17,600 --> 00:14:25,020
+ايش بتتساوي؟تقعيد كلام كويس طب لو قلت لك limit لو
+
+146
+00:14:25,020 --> 00:14:32,020
+واحد ناقص ناقص فا واحد على X لما ال X بتروح ل
+
+147
+00:14:32,020 --> 00:14:39,520
+infinity يبقى هذه بيصير E السلب واحد او واحدة ليش؟
+
+148
+00:14:39,520 --> 00:14:43,600
+لأن السلب بقت را كتبه الزائد ودخل الناقص مكانه
+
+149
+00:14:43,600 --> 00:14:47,550
+اللي زاد في ناقص ميبناقصيقول ماسوّناش شيء يبقى
+
+150
+00:14:47,550 --> 00:14:51,950
+بناء عليها بدأ أخد لهذا general for ونحاول نستخدمه
+
+151
+00:14:51,950 --> 00:14:57,490
+متى أم كان ذلك طيب انت عارف ان هذا الآن هيحللنا
+
+152
+00:14:57,490 --> 00:15:01,750
+مشكلة عويصة كانت لو قابلتنا مش عارفين كيف نسوي
+
+153
+00:15:01,750 --> 00:15:06,930
+فيها؟ شو المشكلة هذه؟ هذه مشكلة مثال رقم اتنين
+
+154
+00:15:06,930 --> 00:15:14,540
+مثال رقم اتنين بيقول لي بدي limitلما الـ X tends
+
+155
+00:15:14,540 --> 00:15:22,240
+to infinity لمن؟ لـ X زائد اتنين على X ناقص واحد
+
+156
+00:15:22,240 --> 00:15:27,240
+كله 6 أحد
+
+157
+00:15:27,240 --> 00:15:31,720
+أسئلة الكتاب في التمرين يبقى نرجعت على هذا السؤال
+
+158
+00:15:31,720 --> 00:15:37,440
+و عوضت عوض مباشر بصير مالة نهاية على مالة نهاية
+
+159
+00:15:37,440 --> 00:15:41,960
+أُسبأعرفها اش هذي مالا نيها لأس مالا نيها يومالا
+
+160
+00:15:41,960 --> 00:15:49,100
+نيها لأس مالا يومالا نيها يومالا نيها يومالا نيها
+
+161
+00:15:49,100 --> 00:15:50,540
+يومالا نيها يومالا نيها يومالا نيها يومالا نيها
+
+162
+00:15:50,540 --> 00:15:50,860
+يومالا نيها يومالا نيها يومالا نيها يومالا نيها
+
+163
+00:15:50,860 --> 00:15:51,100
+يومالا نيها يومالا نيها يومالا نيها يومالا نيها
+
+164
+00:15:51,100 --> 00:15:52,480
+يومالا نيها يومالا نيها يومالا نيها يومالا نيها
+
+165
+00:15:52,480 --> 00:16:00,500
+يومالا نيها يومالا نيها يومالا نيها
+
+166
+00:16:00,500 --> 00:16:06,970
+يومالا نيهطيب، ماذا تقترحه حتى أوصل مسامتي إلى شكل
+
+167
+00:16:06,970 --> 00:16:11,930
+مثل هذا الشكل؟ اه يا عيش، ماكنت تقوله هناك؟ بطلت؟
+
+168
+00:16:11,930 --> 00:16:15,350
+طيب اه، وانا بطلت يعني، اه
+
+169
+00:16:20,790 --> 00:16:29,050
+أضيف و اطرح واحد بصير
+
+170
+00:16:29,050 --> 00:16:35,850
+مثل ذلك صعب اكتر اي نعم لكن انا بندي اقتراح اسهل
+
+171
+00:16:35,850 --> 00:16:41,210
+من ذلك بكثير ايوة كويس يقول يجسم البص على المطبخ
+
+172
+00:16:41,210 --> 00:16:45,720
+عن ايه كل الكلام اللي جاله الاخ؟الحلاج مش هيك
+
+173
+00:16:45,720 --> 00:16:51,060
+الاسم الأول محمد اه محمد فوزي اه محمد فوزي الحلاج
+
+174
+00:16:51,060 --> 00:16:56,940
+كمان؟ كويس يبقى اه بنوصل لمين بنوصل الاقتراح اللي
+
+175
+00:16:56,940 --> 00:17:00,720
+قاله لا احنا عندنا شغل غير هيك ايش الشغل غير
+
+176
+00:17:00,720 --> 00:17:04,880
+هيك؟مش ان اوصل للشكل هذا شو رأيك بيداخل X عامل
+
+177
+00:17:04,880 --> 00:17:10,270
+مشترك من كل من البست والمقام على احدةيعني كيف؟
+
+178
+00:17:10,270 --> 00:17:14,570
+يعني بقدر اقول هذه ال limit لما ال x tends to
+
+179
+00:17:14,570 --> 00:17:20,630
+infinity لمن؟ لأي ال x عم المشترك بظل واحد زائد
+
+180
+00:17:20,630 --> 00:17:26,690
+اتنين على x والمقام بدي اخد x عم المشترك بظل واحد
+
+181
+00:17:26,690 --> 00:17:35,290
+ناقص واحد على x وهذا كله to the power xتمام هلحين
+
+182
+00:17:35,290 --> 00:17:40,690
+هذه ال X ممكن أقولها مع السلامة على هذه وهذا ال X
+
+183
+00:17:40,690 --> 00:17:46,090
+يعتبر لكل من البصف والمقام صحيح ولا لا؟ إذا بقدر
+
+184
+00:17:46,090 --> 00:17:52,190
+أقول هذا limit لما ال X tends to infinity لواحد
+
+185
+00:17:52,190 --> 00:17:58,770
+زائد اتنين على X كله to the power X على واحد ماقص
+
+186
+00:17:58,770 --> 00:18:05,060
+واحد او زائد واحدوهنا بدأ اضع ناقص واحد كله to the
+
+187
+00:18:05,060 --> 00:18:10,920
+power x بالشكل اللي عندنا ناقص
+
+188
+00:18:10,920 --> 00:18:15,240
+واحد كتبتها زائد ناقص واحديبقى اطلعلي في هذا
+
+189
+00:18:15,240 --> 00:18:18,200
+السؤال الأول ال limit كان هو limit للبسط و limit
+
+190
+00:18:18,200 --> 00:18:22,600
+للمقار صحيح ولا لا limit البسط من السؤال هو القدرش
+
+191
+00:18:22,600 --> 00:18:27,660
+بيعطيلك E ثربيع يبقى هذا الكلام بدي يعطيلك E
+
+192
+00:18:27,660 --> 00:18:34,200
+square هذا برضه بنفس المثل بيعطيك ماميبقى E أُس
+
+193
+00:18:34,200 --> 00:18:38,820
+سالب واحد هذا الكلام جيبناه من أين؟ from ال
+
+194
+00:18:38,820 --> 00:18:42,100
+question one يعني من المثال او من ال example one
+
+195
+00:18:42,100 --> 00:18:48,900
+من المثال الأول هذه ال backdrop اقول هي مين؟ هي E
+
+196
+00:18:48,900 --> 00:18:53,080
+تكعين وانتهينا منها لا مشينا لا خط ولا تاني ولا
+
+197
+00:18:53,080 --> 00:18:57,220
+تالتة ولا رابعة طيب لو كان السؤال هذا جاني في
+
+198
+00:18:57,220 --> 00:19:02,350
+الأول لو جبته مثاليبقى بدي أمشي فيه لو إلا حد هنا،
+
+199
+00:19:02,350 --> 00:19:06,950
+و بعدين بدي أروح أخد هذه لحالها، و أجيب اللي متلها
+
+200
+00:19:06,950 --> 00:19:10,050
+الأربع خطوات، و هذه اللي متلها أربع خطوات، و أشوف
+
+201
+00:19:10,050 --> 00:19:14,130
+كده بده ياخد وجد، تمام؟ إذا وجود السؤال هذا في
+
+202
+00:19:14,130 --> 00:19:20,030
+الأول، حلي كل الإشكاليات بعد ذلك، جد ما تكون أي
+
+203
+00:19:20,030 --> 00:19:25,220
+رقم،خلاص النتيجة معروف وبعوض فيها و بنامشيها تمام؟
+
+204
+00:19:25,220 --> 00:19:30,000
+لا لو جالك السؤال هذا لحاله بدك تعمل هذه و تقول
+
+205
+00:19:30,000 --> 00:19:35,600
+هذه similar بنفس الطريقة اه مش همشي دوري ولكن من
+
+206
+00:19:35,600 --> 00:19:40,780
+وين جبت هذه؟ كويس؟ طيب هذه اللي هو المثال رقم
+
+207
+00:19:40,780 --> 00:19:45,060
+اتنين بدنا نروح للمثال رقم ثلاثة
+
+208
+00:19:59,190 --> 00:20:06,730
+يبقى example three بيقول ليه؟ بدى limit لما ال X
+
+209
+00:20:06,730 --> 00:20:14,070
+tends to zero لمن؟ لل E وال6 زائد ال X كله أسواحب
+
+210
+00:20:14,070 --> 00:20:17,870
+على X الآن هذا بده ساوي
+
+211
+00:20:35,570 --> 00:20:42,750
+لو جينا عوض مستعود مباشر Zero E of Zero بواحد واحد
+
+212
+00:20:42,750 --> 00:20:47,390
+على صفر ب Infinity يبقى واحد أس Infinity لازمنا في
+
+213
+00:20:47,390 --> 00:20:52,760
+الحالة الأولى يبقى بنا نمشي الخطوات الأربعيبقى
+
+214
+00:20:52,760 --> 00:20:58,420
+بالدرجة قول له let f of x بدي يساوي e وال6 زائد x
+
+215
+00:20:58,420 --> 00:21:04,580
+كله الواحد على x خد لي لن الطرفين يبقى لن ال f of
+
+216
+00:21:04,580 --> 00:21:11,270
+x بدي يساوي واحد على x لن ال e وال6 زائد xخد ال
+
+217
+00:21:11,270 --> 00:21:15,690
+limit اللي هي الخطوة التالتة limit لما ال x بده
+
+218
+00:21:15,690 --> 00:21:24,170
+يروح لل zero لما ال x بدها تروح لل zero لمن لإن ال
+
+219
+00:21:24,170 --> 00:21:30,170
+f of x بده يسوي limit لما ال x بدها تروح لل zero
+
+220
+00:21:30,170 --> 00:21:38,670
+لواحد على x لإن ال EO6 زائد Xلو جينا عوضنا تعويض
+
+221
+00:21:38,670 --> 00:21:45,570
+مباشر بصيل واحد على الصفر infinity Zero E of Zero
+
+222
+00:21:45,570 --> 00:21:54,510
+بواحد لإن الواحد جداش ب Zeroبتفتح المثلة بطريقة
+
+223
+00:21:54,510 --> 00:21:59,650
+رياضية صحيحة بحيث فعلا تحولها صفر على صفر أو مالة
+
+224
+00:21:59,650 --> 00:22:04,670
+نهاية على مالة نهاية يبقى limit لما ال X بده تروح
+
+225
+00:22:04,670 --> 00:22:11,350
+ل zero هي جازة بس فاتة هناك كويس يعني لن EO6 زائد
+
+226
+00:22:11,350 --> 00:22:12,470
+X على X
+
+227
+00:22:15,890 --> 00:22:22,690
+سنقوم باستخدام قاعدة Lobital يبقى هذا الكلام يستوي
+
+228
+00:22:22,690 --> 00:22:29,500
+ال limit لما ال X يذهب الى 0 مشتاقة ال bus واحدعلى
+
+229
+00:22:29,500 --> 00:22:38,400
+EOSX زائد X في مشتقة مداخل الـ LEN له EOSX زائد 1
+
+230
+00:22:38,400 --> 00:22:44,360
+كله على مشتقة المقام له بواحد صحيح يبقى قالة الى
+
+231
+00:22:44,360 --> 00:22:51,200
+limit لما ال X بدي روح ل 0 لل EOSX زائد 1 على EOSX
+
+232
+00:22:51,200 --> 00:22:57,790
+زائد X نجي نعوض طاولة مباشرة و نشوف جدش تعطيناE of
+
+233
+00:22:57,790 --> 00:23:05,870
+0 ب 1 يبقى بصير عن هنا 1 زائد 1 E of 0 ب 1 زائد 0
+
+234
+00:23:05,870 --> 00:23:13,150
+يبقى 1 زائد 0 يبقى النتيجة جداشلغاية هنا كم خطوة
+
+235
+00:23:13,150 --> 00:23:18,550
+عملنا؟ تلاتة. ضايل علينا خطوة رابعة. دي لبالك. هذه
+
+236
+00:23:18,550 --> 00:23:22,270
+نفسيه تبقى قصم عليها علامة. إذا السؤال عليه أربعة
+
+237
+00:23:22,270 --> 00:23:26,490
+درجات ولا خمسة، بنطير عليه علامة. يبقى ضروري إياك
+
+238
+00:23:26,490 --> 00:23:33,400
+ثم إياك أن تنساه. يبقى بصير عنه limitلما ال X بدي
+
+239
+00:23:33,400 --> 00:23:40,620
+اروح لل Zero لمن؟ لل E of X زاد X أس واحد على X
+
+240
+00:23:40,620 --> 00:23:47,120
+يساوي E ترابيع سؤال
+
+241
+00:23:47,120 --> 00:23:52,020
+الرابع بيقول
+
+242
+00:23:52,020 --> 00:24:00,650
+لي limitلما ال X tends to infinity لمن؟ لل X تكييب
+
+243
+00:24:00,650 --> 00:24:06,210
+زائد A أس واحد على لن ال X
+
+244
+00:24:11,250 --> 00:24:18,330
+مالة نهاية تكيب واضيف عليها رقم مالة نهاية واحد
+
+245
+00:24:18,330 --> 00:24:22,310
+لان المالة نهاية بمالة نهاية واحدة مالة نهاية ب
+
+246
+00:24:22,310 --> 00:24:28,870
+zero يبقى هذه infinity of اللي هي الحالة التالتة
+
+247
+00:24:28,870 --> 00:24:33,610
+مظبوط؟ مدام الحالة التالتة يبقى بأن نشتغل الأربع
+
+248
+00:24:33,610 --> 00:24:36,750
+خطوات يبقى بالدرجة أقوله افترض
+
+249
+00:24:45,310 --> 00:24:52,990
+خطوة التانية خد لن للطرفين يبقى لن ال F of X يسوى
+
+250
+00:24:52,990 --> 00:25:04,380
+واحد على لن ال X في لن ال X تكييب زائد Eخطوة تالتة
+
+251
+00:25:04,380 --> 00:25:24,260
+خطوة
+
+252
+00:25:24,260 --> 00:25:25,760
+تالتة خطوة تالتة خطوة تالتة خطوة تالتة خطوة تالتة
+
+253
+00:25:25,760 --> 00:25:27,380
+خطوة تالتة خطوة تالتة خطوة تالتة خطوة تالتة خطوة
+
+254
+00:25:27,380 --> 00:25:28,360
+تالتة خطوة تالتة خطوة تالتة خطوة تالتة خطوة تالتة
+
+255
+00:25:28,360 --> 00:25:31,090
+خطوة تالتة خطوة تالتةلأن الانفينيتي لمّا راح
+
+256
+00:25:31,090 --> 00:25:37,210
+لانفينيتي لإن رايح لوين؟ لانفينيتيوهذا كمان جداش
+
+257
+00:25:37,210 --> 00:25:44,270
+infinity يبقى اتحولت مثلتنا من infinity of zero
+
+258
+00:25:44,270 --> 00:25:49,050
+إلى infinity على infinity إذا مشتقت دالة البصرة
+
+259
+00:25:49,050 --> 00:25:54,810
+على مشتقت دالة المقام يبقى limit لما ال X tends to
+
+260
+00:25:54,810 --> 00:26:02,810
+infinity لمين لتلاتة X تربيع على X تكيبزائد اي
+
+261
+00:26:02,810 --> 00:26:07,430
+واحد على اكس تكيب زائد اي في مشتقة ال E بتلاتة اكس
+
+262
+00:26:07,430 --> 00:26:11,990
+تربية ومشتقة ال E بزيرو اللي عملنا لدالة اللي فوق
+
+263
+00:26:11,990 --> 00:26:17,150
+بدي نعمله لدالة اللي تحت مشتقة ال N ال X بواحد على
+
+264
+00:26:17,150 --> 00:26:22,790
+اكس بدي اعيد ترتيب المثلة بشكل مهذبأحسن هذا كلكعة
+
+265
+00:26:22,790 --> 00:26:28,510
+كبيرة هذي يبقى بنرجع لكثور الاعتيادية تبع ترابة
+
+266
+00:26:28,510 --> 00:26:36,210
+امتدائي يبقى هذا بيصير تلاتة X تربيع على X تكعيب
+
+267
+00:26:36,210 --> 00:26:42,530
+زادي وهذه ال X بتطلع وين؟ فوق بيصير هذا تلاتة X
+
+268
+00:26:42,530 --> 00:26:50,030
+تكعيب والباقي كما هو طيب الان لو جيت عوض طبعا وانا
+
+269
+00:26:50,030 --> 00:26:57,990
+مش راجعش بطلعInfinity على Infinity كويس يبقى هذا
+
+270
+00:26:57,990 --> 00:27:04,490
+بتطلع Infinity على Infinity شو نعمل؟ كمان مرة يبقى
+
+271
+00:27:04,490 --> 00:27:08,590
+هذا الكلام يساوي ال limit لما ال X tends to
+
+272
+00:27:08,590 --> 00:27:16,490
+Infinity لميم لتسعة X ترابيع على تلاتة X ترابيع
+
+273
+00:27:16,490 --> 00:27:20,110
+تعاود مباشر Infinity على Infinity كمان مرة و كمان
+
+274
+00:27:20,110 --> 00:27:25,400
+مرة طب واش هالشدة يا عباد الله؟ما تختصر X تربية مع
+
+275
+00:27:25,400 --> 00:27:29,800
+X تربية أو تسعة مع تلاتة بيبقى الجداش تلاتة اذا
+
+276
+00:27:29,800 --> 00:27:34,280
+واحد تاني جالي بدل ما سويتك مكان من هنا زي ما
+
+277
+00:27:34,280 --> 00:27:38,120
+أخدنا في calculus A وفي الثانوية العامة هذه ال
+
+278
+00:27:38,120 --> 00:27:40,860
+polynomial و هذه ال polynomial يبقى بنجسم كل من
+
+279
+00:27:40,860 --> 00:27:44,300
+البصر ومن القعام على X المرفوعة لأكبر أُس في
+
+280
+00:27:44,300 --> 00:27:47,980
+المقام لو عملها حد بقدر يقول إنه غلط لأ يا عم صح
+
+281
+00:27:47,980 --> 00:27:51,920
+مدام أخدناها أجابة لهك تشتغلي بها مع أن مانعيبقى
+
+282
+00:27:51,920 --> 00:27:56,960
+لو جسمنا كله على اكسا كيب بصير ثلاثة على واحد E
+
+283
+00:27:56,960 --> 00:27:59,680
+على اكسا كيب ال limit لابزي ربما ثلاثة على واحد
+
+284
+00:27:59,680 --> 00:28:04,260
+اللي هو جداش ثلاثة و احنا طلعناها هنا جداش ثلاثة
+
+285
+00:28:04,260 --> 00:28:10,340
+طب حتى اللي انا احنا عملناثلاث خطوات وبنروح للخطوة
+
+286
+00:28:10,340 --> 00:28:16,800
+الرابعة يبقى بادي بقوله sir limit لما ال X بدها
+
+287
+00:28:16,800 --> 00:28:23,640
+تروح لل infinity لراس المسألة X تكيب زائد E أس
+
+288
+00:28:23,640 --> 00:28:32,000
+واحد على لإن ال X بده يساوي جداش E تكيب طيب السؤال
+
+289
+00:28:32,000 --> 00:28:41,200
+الخامسسؤال الخامس بيقول ما يأتي بدنا limit لمن؟
+
+290
+00:28:41,200 --> 00:28:47,260
+لما ال X بدها تروح لل zero من جهة اليمين ل X
+
+291
+00:28:47,260 --> 00:28:53,680
+مرفوعة لل أس صين ال X بدنا
+
+292
+00:28:53,680 --> 00:28:59,730
+نحط مكان X Zero، بصير Zero أس0 للحالات التانية
+
+293
+00:28:59,730 --> 00:29:06,370
+اللي ماحلناش عليها ولا سؤال يبقى هذه 0 أُس 0 كويس
+
+294
+00:29:06,370 --> 00:29:13,230
+يبقى بدنا نروح للأربع خطوات يبقى let ال F of X
+
+295
+00:29:13,230 --> 00:29:18,680
+يساوي X أُصين ال X هذه الخطوة الأولىالخطوة التانية
+
+296
+00:29:18,680 --> 00:29:24,180
+بدك تاخد limit للطرفين يبقى limit ال f of x بده
+
+297
+00:29:24,180 --> 00:29:29,060
+يساوي ال sign ال x في limit ال x الخطوة التالتة
+
+298
+00:29:29,060 --> 00:29:34,700
+بدك تاخد limit لlimit ال f of x لما ال x بده يروح
+
+299
+00:29:34,700 --> 00:29:40,540
+ل zero من جهة اليمين يساوي ال limit لما ال x بدها
+
+300
+00:29:40,540 --> 00:29:45,760
+تروح ل zero من جهة اليمين ل sign ال x في limit ال
+
+301
+00:29:45,760 --> 00:29:54,580
+xنعوض تعويضا مباشرا sign is zero الان لن zero من
+
+302
+00:29:54,580 --> 00:30:00,540
+جهة اليمين اللي منزل علوان على سالب infinity يبقى
+
+303
+00:30:00,540 --> 00:30:06,760
+zero في سالب infinity والله zero في infinity اتنين
+
+304
+00:30:06,760 --> 00:30:13,720
+كمية غير معينةطيب استخدم صلاحياتك limit لما ال X
+
+305
+00:30:13,720 --> 00:30:18,820
+بده يروح ل zero مشان تحسب هذه ال limit طب ايش
+
+306
+00:30:18,820 --> 00:30:23,980
+صلاحياتي؟ صلاحياتي اشتغل شغل رياضي صحيح ماحدش يقدر
+
+307
+00:30:23,980 --> 00:30:27,860
+يقوللي عليه خطأ يعني بده احول المسألة الى zero على
+
+308
+00:30:27,860 --> 00:30:33,320
+zero او infinity على infinity ماذا تقترحون ايه يا
+
+309
+00:30:33,320 --> 00:30:34,020
+ابنك؟
+
+310
+00:30:36,590 --> 00:30:40,790
+مهم تاعتد ان ال sign هي مقلوب من ال cosecant يعني
+
+311
+00:30:40,790 --> 00:30:46,630
+ريب سبروكال of cosecant ال X يبقى جالي هذا خللي ان
+
+312
+00:30:46,630 --> 00:30:52,010
+ال X زي ما هي و هذه cosecant ال X اللي هي مقلوب ال
+
+313
+00:30:52,010 --> 00:30:56,610
+sign بنقوله والله تمام طب لو عوضنا و تعاودنا و
+
+314
+00:30:56,610 --> 00:31:04,510
+مشرشو بتعطيني هذهInfinity على منحنى الـ cosecant
+
+315
+00:31:04,510 --> 00:31:09,290
+.متذكرينه ولا زي الحلم؟إذا مش متذكرينه، في نهاية
+
+316
+00:31:09,290 --> 00:31:13,330
+هذه المحاضرة، بدنا نبدأ في الsection الجديد، اللي
+
+317
+00:31:13,330 --> 00:31:17,570
+هو الـ trigonometric functions، وبكرا، بديك تيجي
+
+318
+00:31:17,570 --> 00:31:21,930
+مراجعة، لإنه بدنا نكملها ونخش على أمثلتها.يعني
+
+319
+00:31:21,930 --> 00:31:26,710
+بكرا، بديك تيجي مراجعة شكل الرسم البياني لل
+
+320
+00:31:26,710 --> 00:31:31,310
+trigonometric functions.دري بالك.هنبدأ فيه بعد
+
+321
+00:31:31,310 --> 00:31:35,610
+قليل لكن الباقية لك تجي مراجعه يبقى ال consequant
+
+322
+00:31:35,610 --> 00:31:40,070
+هذه لو روحنا لل zero من جهة اليمين ال consequant
+
+323
+00:31:40,070 --> 00:31:44,510
+بيجيني من فوق و بيجي نازل لعند الواحد وبعود بطلع
+
+324
+00:31:44,510 --> 00:31:50,390
+تاني يبقى هذا عبارة عن ايش سالب infinity على
+
+325
+00:31:50,390 --> 00:31:54,690
+infinity ماعناش مشكلة infinity على infinity والله
+
+326
+00:31:54,690 --> 00:31:58,590
+سالب infinity على infinity إذا مشتقة البس على
+
+327
+00:31:58,590 --> 00:32:06,510
+مشتقةالمقام تفضل ال X بواحد على X والكسي كانت
+
+328
+00:32:06,510 --> 00:32:15,930
+بسالب كسي كانت ال X في كتان ال X كيف؟
+
+329
+00:32:15,930 --> 00:32:22,850
+سافر من جهة اليمين، مظبوط؟ اقول لك اعمل هيك و الله
+
+330
+00:32:22,850 --> 00:32:32,880
+يشرفكرسمت الرسمة طلع على الرسمة و كتبناها
+
+331
+00:32:32,880 --> 00:32:38,080
+as a limit اللي من ضمن ال properties of لن ال X
+
+332
+00:32:41,720 --> 00:32:45,860
+طيب يبقى هذا الكلام بدي يساوي ال limit لما ال X
+
+333
+00:32:45,860 --> 00:32:50,220
+بدها تروح ل zero من جهة اليمين، بدي أعيد ترتيب
+
+334
+00:32:50,220 --> 00:32:55,240
+المثلة، يبقى ال X هاد بتنزل وين؟ ال cos كان بدي
+
+335
+00:32:55,240 --> 00:32:59,950
+اكتبها ال sign و ال quotient بدي اكتبهابتعلنه
+
+336
+00:32:59,950 --> 00:33:07,730
+تانية مقلب الكتان إذا بصير هذي sin X و هنا tan X
+
+337
+00:33:07,730 --> 00:33:14,010
+على مين على X وهي إشارة السالب قبلهم كلهم طيب هذا
+
+338
+00:33:14,010 --> 00:33:18,690
+الكلام بدي يساوي سالب برا و limit لما ال X بدي
+
+339
+00:33:18,690 --> 00:33:24,430
+يروح ل zero من جهة اليمين ل sin X على X بنفع ولا
+
+340
+00:33:24,430 --> 00:33:30,780
+لا؟فاهمين؟ في limit لما ال X بدها تروح ل zero من
+
+341
+00:33:30,780 --> 00:33:37,000
+جهة اليمين لتان ال X هذا الكلام بده يساوي السالم
+
+342
+00:33:37,000 --> 00:33:42,200
+هذي ال limit بقداش يا شباب واحد صحيح تمام تمام
+
+343
+00:33:42,200 --> 00:33:49,030
+وهذه تاني ال zero منحنتانيمر بنقطة الأصل، إذا
+
+344
+00:33:49,030 --> 00:33:54,910
+انتهى الـ Zero بقداش؟ بـ Zero و يساوي كداش؟ و
+
+345
+00:33:54,910 --> 00:33:59,790
+يساوي Zero يبقى انتهينا من مين؟ من ثلاث خطوات،
+
+346
+00:33:59,790 --> 00:34:05,900
+باقية الخطوة الرابعةيبقى باجي بقول له سا limit لما
+
+347
+00:34:05,900 --> 00:34:11,720
+ال X بدها تروح لل zero من جهة اليمين لل X أص عين
+
+348
+00:34:11,720 --> 00:34:17,800
+ال X بده يساوي E أزره اللي يبقى داشر بواحد صحيح
+
+349
+00:34:20,660 --> 00:34:27,540
+ملاحظين انه أخدنا بدل المثال خمسة وكله بنمشي بنفس
+
+350
+00:34:27,540 --> 00:34:33,480
+التكتيك ونفس الفكرة يعني لا توجد فيهم الخمسة فكرة
+
+351
+00:34:33,480 --> 00:34:40,700
+جديدة واحد منهم بست بدالهم كلهم لكن بدنا نعطيك نفس
+
+352
+00:34:40,700 --> 00:34:46,740
+الموضوع بفكرة جديدة نفس الموضوع هكتب لمثال جديد
+
+353
+00:34:46,740 --> 00:34:48,180
+يبقى example
+
+354
+00:34:54,110 --> 00:35:05,610
+Find the value of the constant A
+
+355
+00:35:15,030 --> 00:35:22,410
+Such that limit لما ال X tends to zero لل A to the
+
+356
+00:35:22,410 --> 00:35:32,810
+power X زائد X أس واحد على X يساوي أربعة E مرة دي
+
+357
+00:35:32,810 --> 00:35:38,770
+بنا في أحدى الامتحانات سؤال شبيه بهذا السؤال فكر
+
+358
+00:35:38,770 --> 00:35:45,640
+كيف بدنا نحل هذا السؤالوعبال ممسح اللوح بدك تكون
+
+359
+00:35:45,640 --> 00:35:52,800
+فكرت وعطيتن الإجابة طيب
+
+360
+00:35:52,800 --> 00:36:00,200
+السؤال هو كيف ننحل هذا السؤال؟نجي لسؤالنا هذا،
+
+361
+00:36:00,200 --> 00:36:03,780
+يبقى السؤال هذا بمسك الطرف الشمال و كانوا ماعيش
+
+362
+00:36:03,780 --> 00:36:09,860
+خبر مين، الطرف اليمين الأربع خطوات، طبعا؟ و بعدين
+
+363
+00:36:09,860 --> 00:36:15,960
+الله بحلها، يبقى بدي أروح أقول هنا الـالـ F of X
+
+364
+00:36:15,960 --> 00:36:22,300
+يساوي لـ A to the power X زائد X أس واحد على X
+
+365
+00:36:22,300 --> 00:36:28,520
+وبدنا نحاول نجيب مقدار الثابت A من خلال ال limit
+
+366
+00:36:28,520 --> 00:36:33,050
+والإجابة اللي لنا لـ 4Aيبقى بعد ذلك نروح ناخد
+
+367
+00:36:33,050 --> 00:36:40,210
+limit للطرفين يبقى لن ال F of X بده ساوي واحد على
+
+368
+00:36:40,210 --> 00:36:46,410
+X لن ال A to the power X زائد X بعد ذلك نروح ناخد
+
+369
+00:36:46,410 --> 00:36:53,850
+limit للطرفينيبقى هذا بيعطيك limit لإن ال f of x
+
+370
+00:36:53,850 --> 00:37:00,150
+لما ال x بدها تروح ل zero بده يساوي limit لما ال x
+
+371
+00:37:00,150 --> 00:37:06,710
+tends to zero لمن؟ لإن ال a to the power x زائد x
+
+372
+00:37:06,710 --> 00:37:13,210
+كله على من؟ على x لو جيت و عوضت تعويض مباشر يبقى
+
+373
+00:37:13,210 --> 00:37:20,550
+zero a of zeroبواحد لنا الواحد بزيرو على زيرو يبقى
+
+374
+00:37:20,550 --> 00:37:24,970
+صورة هذه زيرو على زيرو تمام؟ مدام زيرو على زيرو
+
+375
+00:37:24,970 --> 00:37:32,210
+إذا بقدر استخدم قاعدة لبتن كويس يبقى واحد على ا
+
+376
+00:37:32,210 --> 00:37:39,450
+والسكس زائد ال X في مشتقة ما داخل اللين ا to the
+
+377
+00:37:39,450 --> 00:37:46,740
+power X في جداش؟لأن الـ a تمامًا مذاكرينه كويس زاد
+
+378
+00:37:46,740 --> 00:37:51,500
+واحد يبقى واحد على a to the power x زاد x في مشتقة
+
+379
+00:37:51,500 --> 00:37:55,680
+هذا المقار a to the power x لإن ال a ومشتقة ال x
+
+380
+00:37:55,680 --> 00:38:01,800
+يامين بواحد كله على مشتقة المقام جداش بواحد صحيح
+
+381
+00:38:01,800 --> 00:38:07,480
+يبقى هذا يساوي طب لو جيت عوّط عن ال x ب zero بده
+
+382
+00:38:07,480 --> 00:38:14,050
+أشوف لإيش بوصلأو الـ Zero يبقى بضال عندي إلا لإن
+
+383
+00:38:14,050 --> 00:38:20,450
+الـ A زائد واحد هذا Zero أو Zero بواحد يبقى هذا
+
+384
+00:38:20,450 --> 00:38:25,250
+كله على واحد مظبوط يبقى مادام هيك مضالش عندي إلا
+
+385
+00:38:25,250 --> 00:38:30,550
+لإن ال A زائد واحد يبقى هذا هو اللي بدي سوى أربعة
+
+386
+00:38:30,550 --> 00:38:38,930
+E مظبوط يعني الكلام غلط طيب ماشي موافقينهذه هي
+
+387
+00:38:38,930 --> 00:38:43,490
+limit للدالة وليست limit للإن الدالة احنا اللي
+
+388
+00:38:43,490 --> 00:38:48,730
+حصلنا عليه هذا هو limit للإن الدالة اه يعني بناء
+
+389
+00:38:48,730 --> 00:38:51,950
+عليها بلعنا لسه الخطوة الرابعة هذول التلات خطوات
+
+390
+00:38:51,950 --> 00:38:59,050
+اذا بروح للخطوة الرابعة و بقول limitللـ F of X لما
+
+391
+00:38:59,050 --> 00:39:06,630
+الـ X بده يروح للـ Zero بده يساوي E أُس لان اللي
+
+392
+00:39:06,630 --> 00:39:13,710
+هو مين الـ A زائد واحد، هيك بالكلامنا صحيحهذا من
+
+393
+00:39:13,710 --> 00:39:23,490
+خواص اللي هو العدد a بقول e أس لإن ال a ضرب e أس
+
+394
+00:39:23,490 --> 00:39:29,450
+واحد عند الضرب بتجمع من ال أس أس ال a و اللي إن
+
+395
+00:39:29,450 --> 00:39:36,310
+عكس بعض بظل جداش a و e أس واحد هي ب e هيك خلصت
+
+396
+00:39:36,310 --> 00:39:40,000
+الأربع خطواتجالي في راسي اللي مسلمت لهذا المقبر
+
+397
+00:39:40,000 --> 00:39:45,900
+يساوي كده؟ يبقى هذا اللي هو بيساوي أربعة ايه، مش
+
+398
+00:39:45,900 --> 00:39:50,160
+الأولاني، تمام؟ يبقى هنا الخطأ اللي بيحصل عند
+
+399
+00:39:50,160 --> 00:39:54,300
+الطلاب لو جيهم هذا السؤال، بوصل لهذا و بروح يساوي
+
+400
+00:39:54,300 --> 00:39:58,600
+هذا، بلعجل عنه و يصير يبطح في المثل هذه، بدي أجيب
+
+401
+00:39:58,600 --> 00:40:02,140
+الأيه بالعافية، تمام؟ بكون نقصة عليها الخطوة
+
+402
+00:40:02,140 --> 00:40:10,810
+وبالتالي ضيعت يعني، جول، تلت السؤالمن هذهها بستنتج
+
+403
+00:40:10,810 --> 00:40:16,990
+تماما ان الـ A تساوي قداشر أربعة يبقى ثابت A
+
+404
+00:40:16,990 --> 00:40:24,250
+دوسائي أربعة لحد يناسب انتهى هذا ال section وإليكم
+
+405
+00:40:24,250 --> 00:40:27,170
+أرقام المسائل
+
+406
+00:40:43,800 --> 00:40:48,700
+يبقى exercises سبعة
+
+407
+00:40:48,700 --> 00:40:57,020
+خمسة المسائل التالية سبعة خمسة من واحد لغاية سبعة
+
+408
+00:40:57,020 --> 00:41:07,200
+وسبعين multiple of three multiple of three وكذلك
+
+409
+00:41:07,200 --> 00:41:10,700
+سؤال خمسة و تمانين
+
+410
+00:41:13,670 --> 00:41:17,270
+لحظين امتنعنا من هذا ال section ننتقل الان الى ال
+
+411
+00:41:17,270 --> 00:41:22,590
+section السابع
+
+412
+00:41:22,590 --> 00:41:34,070
+ستة اللي هو ال inverse trigonometric functions
+
+413
+00:41:39,470 --> 00:41:45,730
+معكوث الدوال المثلثية احنا لما درسنا معكوث الدالة
+
+414
+00:41:45,730 --> 00:41:52,110
+قولنا المعكوث الدالة exist إذا كانت حقق شرط واحد
+
+415
+00:41:52,110 --> 00:41:57,310
+إن الدالة كانت one to one ممتاز جدا تفضل تعالى
+
+416
+00:41:57,310 --> 00:42:02,290
+نشوف الدوال المثلثية الستة هل هي one to one والله
+
+417
+00:42:02,290 --> 00:42:08,090
+ماهياش one to oneنمسك الدالة الأولى نمرة واحدة
+
+418
+00:42:08,090 --> 00:42:17,240
+هقول ان y تساوي sin inverse x او arc sin xبعض
+
+419
+00:42:17,240 --> 00:42:23,060
+الكتب بتكتبها sin inverse x وعليها ناقص واحد وبعض
+
+420
+00:42:23,060 --> 00:42:27,240
+الكتب بتكتبها arc sine X يعني لو روحت المكتبة
+
+421
+00:42:27,240 --> 00:42:33,200
+وفتحت اي كتاب ولاقيت arc sine تفهم ان هذا هو معكوس
+
+422
+00:42:33,200 --> 00:42:39,320
+الدالة المثلثية اللى قدامنا هذه طيب نجي الان
+
+423
+00:42:39,320 --> 00:42:44,340
+للدالة المثلثية اللى arc sine X أو sin inverse X
+
+424
+00:42:46,380 --> 00:42:52,660
+خدنا رسمتها في كل قلص ايه؟ مظبوط؟ صح؟ بتذكر تذكير
+
+425
+00:42:52,660 --> 00:42:57,660
+ليس إلا لما كنا نرسم مكانة موجها طالعة و نازلة،
+
+426
+00:42:57,660 --> 00:43:02,840
+مظبوط؟ و ال top قد إيه شخص حد يرسمه؟ و أقل حاجة؟
+
+427
+00:43:02,840 --> 00:43:07,200
+ممتاز، يبقى الرسم محصورة بين واحد و سالب واحد لو
+
+428
+00:43:07,200 --> 00:43:12,920
+رسمت horizontal line بقطعها في مالة نهاية من
+
+429
+00:43:12,920 --> 00:43:18,950
+النقاط، إذاالـ function ليست one to one، مظبوط؟
+
+430
+00:43:18,950 --> 00:43:23,930
+طيب، يبقى المعكوس غير موجود لكن إيش رايك؟ بدنا
+
+431
+00:43:23,930 --> 00:43:27,710
+نروح ناخد جزء من ال domain يعني بدنا نعمل
+
+432
+00:43:27,710 --> 00:43:32,630
+restriction على ال domain يعني نحصر ال domain في
+
+433
+00:43:32,630 --> 00:43:38,330
+فترة محددة مضمن خلال هذه الفترة لو رسمت أي
+
+434
+00:43:38,330 --> 00:43:42,350
+horizontal line، لا يقطع المنحنة إلا في نقطة M
+
+435
+00:43:44,240 --> 00:43:49,500
+بتذكر بس برسمة الـSin أولا ثم نشوف أين اللي بدنا
+
+436
+00:43:49,500 --> 00:43:53,520
+ناخده يبقى لو جيت لرسمة الـSin الـSin اللي عندنا
+
+437
+00:43:53,520 --> 00:43:59,600
+بهذا الشكل هذا محور X هذا محور Y هذا نقطة الأصل
+
+438
+00:43:59,600 --> 00:44:04,990
+اللي هي Zeroاتفاقنا ان منحنى الـSin لا يزيد عن
+
+439
+00:44:04,990 --> 00:44:11,570
+واحد بأي حال من الأحوال و لا ينزل عن من عن سالب
+
+440
+00:44:11,570 --> 00:44:15,830
+واحد بأي حال من الأحوال إذن الدالة محصورة بين
+
+441
+00:44:15,830 --> 00:44:20,930
+الخطين المنقطين الاتنين هدول اتنين منحنى الـSin
+
+442
+00:44:20,930 --> 00:44:26,280
+يمر بنقطة الأصل ولا بمراشبأمور تمام التملوجين
+
+443
+00:44:26,280 --> 00:44:32,980
+ذكرنا برسمته حرصه بس منقط متعمد اه رسمنا هيك و
+
+444
+00:44:32,980 --> 00:44:38,020
+برجع نازل هيك و برجع نازل و بهذا الشكل و من
+
+445
+00:44:38,020 --> 00:44:43,380
+الناحية التانية بيجي نازل هيك و بيجي طالع و هكذا
+
+446
+00:44:45,260 --> 00:44:54,360
+طبعا هنا zero هنا باي على اتنين وهنا باي and so on
+
+447
+00:44:54,360 --> 00:44:59,800
+وهنا سالب باي على اتنين وهنا سالب باي على اتنين
+
+448
+00:44:59,800 --> 00:45:00,740
+وهكذا
+
+449
+00:45:02,940 --> 00:45:07,860
+بناخد فقط الجزء من المنحنى من النقطة هذه لغاية
+
+450
+00:45:07,860 --> 00:45:13,260
+النقطة هذه يبقى المنحنى يصير عندنا من عند هذه هي
+
+451
+00:45:13,260 --> 00:45:21,080
+بدراسة بالخط الأسود المتراصل بهذا الشكل يبقى هذا
+
+452
+00:45:21,080 --> 00:45:24,840
+خط
+
+453
+00:45:24,840 --> 00:45:28,540
+اللي عندنا لغاية النقطة هذه وهنا لغاية النقطة اللي
+
+454
+00:45:28,540 --> 00:45:34,650
+عندنا هذهكويس يبقى المنحنة هذا لو رسمت اي
+
+455
+00:45:34,650 --> 00:45:39,870
+horizontal line بلقيه يقطع المنحنة في نقطة واحدة
+
+456
+00:45:39,870 --> 00:45:44,330
+في نقطة واحدة يبقى ضمنت من هذا ان هذه ال sign x
+
+457
+00:45:44,330 --> 00:45:47,550
+على الفترة من سالب باية على اتنين لباية على اتنين
+
+458
+00:45:47,550 --> 00:45:53,950
+عبارة عن one to oneطبعا مدام وانت وان يبقى المعكوس
+
+459
+00:45:53,950 --> 00:46:00,550
+موجود يبقى بناء عليه انا بدي اخد y تساوي صين ال x
+
+460
+00:46:00,550 --> 00:46:05,650
+و ال x هذه مش على اطلاقها و انما موجودة في ال
+
+461
+00:46:05,650 --> 00:46:10,770
+class interval سالب by على اتنين و by على اتنين
+
+462
+00:46:10,770 --> 00:46:19,250
+بهذا الشكل هيك ضمنت وجود من المعكوس كيف يقولممكن
+
+463
+00:46:19,250 --> 00:46:23,050
+البايع اتنين لتلت بايع اتنين؟ ممكن، عادي جدا.
+
+464
+00:46:23,490 --> 00:46:27,090
+زميلكوا بيقول انا ممكن اخد الفترة من البايع على
+
+465
+00:46:27,090 --> 00:46:31,210
+اتنين لتلت بايع اتنين، بيقولوا والله صح وعتني قال
+
+466
+00:46:31,210 --> 00:46:34,350
+لي لا، ممكن اخدها من سلب بايع اتنين إلى سلب تلت
+
+467
+00:46:34,350 --> 00:46:38,370
+بايع اتنين صحيح بس إذا أخدت الفترة هذه، بدك تروح
+
+468
+00:46:38,370 --> 00:46:43,290
+على مسائل التمرين كلها و تجلبها طبقا للفترة
+
+469
+00:46:43,290 --> 00:46:47,170
+الجديدة عندك، الأسلة تبعها تمرين مصممة على الفترة
+
+470
+00:46:47,170 --> 00:46:50,470
+اللي عندك كانوبالتالي لو خلّيت المثال و أخدت
+
+471
+00:46:50,470 --> 00:46:54,050
+الفترة التانية، بيروح الدولة و بيقول كله غلط، اه
+
+472
+00:46:54,050 --> 00:46:59,510
+دي بالك، يعني المثال مصممة على الفترة ان X عندي
+
+473
+00:46:59,510 --> 00:47:02,710
+one to one من سالف باية اتنين لباية اتنين
+
+474
+00:47:06,220 --> 00:47:12,500
+والآن بدنا نروح نرسم رسمة المعكوس تبع هذه أبلة
+
+475
+00:47:12,500 --> 00:47:17,920
+فبعدين بقول بدنا نعرف ما هو شكل المعكوس فبعدين
+
+476
+00:47:17,920 --> 00:47:23,160
+باخد المحاور بالشكل اللي عندنا هذا هذا محور X هذا
+
+477
+00:47:23,160 --> 00:47:29,860
+محور Y هذا نقطة الاصلنرجع بالذاكرة إلى الوراق
+
+478
+00:47:29,860 --> 00:47:35,480
+قليلا، لأول section أخدناه، قلنا إذا الدلة من سالب
+
+479
+00:47:35,480 --> 00:47:38,680
+باية على اتنين لباية على اتنين، هذا يعتبر domain
+
+480
+00:47:38,680 --> 00:47:44,800
+الدلة، لكن ال range من سالب واحد إلىالـ Range تبع
+
+481
+00:47:44,800 --> 00:47:49,820
+الـ function هو ال domain تبع المعكوس و ال range
+
+482
+00:47:49,820 --> 00:47:55,960
+تبع المعكوس هو ال domain تبع الدالة تمام؟ إذا هذا
+
+483
+00:47:55,960 --> 00:48:00,300
+اللي هو ال domain بدو يصير ال range و اللي كان ال
+
+484
+00:48:00,300 --> 00:48:04,140
+range بدو يصير ال domain صحيح ولا لأ؟ إذا الرسم
+
+485
+00:48:04,140 --> 00:48:10,290
+هتنحصل عندي من عندي السالب واحد لغاية كداشرإذا
+
+486
+00:48:10,290 --> 00:48:14,910
+الرسم هذي مش هتتعدى الخط الرأسي اللي هو x يساوي
+
+487
+00:48:14,910 --> 00:48:19,430
+سالب واحد ولا هتتعدى الخط الرأسي اللي هو x يساوي
+
+488
+00:48:19,430 --> 00:48:26,290
+قداش واحدالنقطة هذه الإحداثية تبعها سالب باي على
+
+489
+00:48:26,290 --> 00:48:31,430
+اتنين وسالب واحد تصير سالب واحد وسالب باي على
+
+490
+00:48:31,430 --> 00:48:37,730
+اتنين سالب واحد وبدك تنزل سالب باي على اتنين هذه
+
+491
+00:48:37,730 --> 00:48:44,160
+هناها سالب باي على اتنين يعني بدك توجه فيناالنقطة
+
+492
+00:48:44,160 --> 00:48:48,500
+التانية دي إحداثية هي باي على اتنين و واحد بدا
+
+493
+00:48:48,500 --> 00:48:53,300
+تصير واحد و باي على اتنين واحد و بدا تطلع باي على
+
+494
+00:48:53,300 --> 00:48:58,280
+اتنين اللي هو هنا واحد و باي على اتنين يبجه هي
+
+495
+00:48:58,280 --> 00:49:03,630
+النقطة اللي هي main باي على اتنينهذا المنحنى على
+
+496
+00:49:03,630 --> 00:49:08,950
+الجزء هذا concave down لما ترسم الخطوة يتساركس بده
+
+497
+00:49:08,950 --> 00:49:13,730
+ينجلب ويصير concave up يبقى المنحنى هذا بده يصير
+
+498
+00:49:13,730 --> 00:49:18,790
+عندك بده يجيك بالشكل هذا هيك ويجيك ايوة concave up
+
+499
+00:49:18,790 --> 00:49:24,370
+هذا concave up بده يصير concave down يبقى هذا
+
+500
+00:49:24,370 --> 00:49:29,700
+المنحنى لو رحت كملته هيصير بالشكل اللي عندنايبقى
+
+501
+00:49:29,700 --> 00:49:36,240
+هذا الرسم اللي رسمناها هي عبارة عن y تساوي ال sign
+
+502
+00:49:36,240 --> 00:49:42,580
+inverse x والx محصورة ما بين السالب واحد والواحد
+
+503
+00:49:43,190 --> 00:49:49,250
+تمام؟ طيب ممتاز يبقى عرفنا رسمة معكوسة دالة وعرفنا
+
+504
+00:49:49,250 --> 00:49:52,230
+ال domain و ال range ايه اللي هي ال domain من سلب
+
+505
+00:49:52,230 --> 00:49:56,450
+واحد إلى واحد و ال range من سلب باي على اتنين إلى
+
+506
+00:49:56,450 --> 00:50:02,830
+باي على اتنين اذا خلينا نكتب بعض خواص ال sign هذه
+
+507
+00:50:02,830 --> 00:50:07,590
+يبقى بالداجة اقول انه some properties
+
+508
+00:50:11,750 --> 00:50:19,410
+some properties of
+
+509
+00:50:19,410 --> 00:50:26,710
+y تساوي sin inverse x خاصية
+
+510
+00:50:26,710 --> 00:50:34,570
+الأولى بدي أجيب domain sin inverse x يساوي من وين
+
+511
+00:50:34,570 --> 00:50:44,400
+لوين من سالب واحد إلى واحد andالـ Range لـ sine
+
+512
+00:50:44,400 --> 00:50:51,800
+inverse X بدي ساوي برضه سالب باي على اتنين الى باي
+
+513
+00:50:51,800 --> 00:50:58,340
+على اتنين as any closed interval النقطة الثانية لو
+
+514
+00:50:58,340 --> 00:51:04,220
+جيت قولتلك المنحنى Y تساوي sine inverse X is
+
+515
+00:51:04,220 --> 00:51:08,700
+equivalent to
+
+516
+00:51:12,460 --> 00:51:18,000
+بدي اجيب العبارة المكافئة لهذه العبارة تمام؟ شو
+
+517
+00:51:18,000 --> 00:51:24,680
+بدي اعمل؟ بدي اثر على الطرفين domain ب sign يبقى
+
+518
+00:51:24,680 --> 00:51:32,160
+بصير هنا sign ال Y يساوي sign ل sign inverse X كده
+
+519
+00:51:32,160 --> 00:51:38,620
+اش بيقولك X يبقى هذا بدي يقولك X بشرطإن الـ X تبقى
+
+520
+00:51:38,620 --> 00:51:42,360
+موجودة في دمين الـ sine inverse لو ماكنتش بصير
+
+521
+00:51:42,360 --> 00:51:47,280
+كلامنا هذا ماله غلط اذا حازم أريك بغدا ان شاء الله
+
+522
+00:51:47,280 --> 00:51:52,480
+بعض الأمثلة يبقى هنا هذا الكلام بده يساوي الشكل عن
+
+523
+00:51:52,480 --> 00:51:56,120
+هذا إذا كانت ال X فعلا في دمين ال sine inverse
+
+524
+00:51:56,120 --> 00:52:00,440
+يعني إذا كان ال sine inverse X exist automatic
+
+525
+00:52:00,440 --> 00:52:06,130
+بيكون sine ال Y بساوي Xالخاصية التالتة لو أخدت
+
+526
+00:52:06,130 --> 00:52:12,250
+sign inverse ل sign ال X زي ما أنا بقول هذا الكلام
+
+527
+00:52:12,250 --> 00:52:18,250
+فعلا بده يساوي X إذا ال X موجودة في domain mean
+
+528
+00:52:21,430 --> 00:52:24,570
+سالب باى على اتنين لباى اللى ال restriction اللى
+
+529
+00:52:24,570 --> 00:52:30,490
+عملناه يبقى هذا إذا X موجودة من سالب باى على اتنين
+
+530
+00:52:30,490 --> 00:52:38,190
+إلى باى على اتنين وفي نفس الوقت صين ال X لصين
+
+531
+00:52:38,190 --> 00:52:45,630
+inverse X بده يسوى X إذا كانت ال X موجودة في دمية
+
+532
+00:52:45,630 --> 00:52:52,840
+ال main صين inverse يعني قداشمن سالب واحد إلى واحد
+
+533
+00:52:52,840 --> 00:52:59,180
+as any closed interval بلّة أن الخاصية الرابعة
+
+534
+00:52:59,180 --> 00:53:03,860
+والاخيرة من الخواصات اللي بدنا نعطيهم في هذه
+
+535
+00:53:03,860 --> 00:53:10,320
+اللحظة الخاصية الرابعة لو أخدت ال limit يبقى limit
+
+536
+00:53:10,320 --> 00:53:17,480
+ل sign inverse x لما ال x بدأ تروح للواحد من جهة
+
+537
+00:53:17,480 --> 00:53:24,100
+الشماليبقى احنا بدنا نروح للواحد من جهة الشمال
+
+538
+00:53:24,100 --> 00:53:28,180
+يبقى
+
+539
+00:53:28,180 --> 00:53:34,220
+هذا الكلام بده يساوي باي على اتنين and limit لل
+
+540
+00:53:34,220 --> 00:53:40,940
+sign inverse X لما ال X بدها تروح لسالب واحد من
+
+541
+00:53:40,940 --> 00:53:45,300
+جهة اليمين يبقى لو روحنا من جهة اليمين بلاقيها
+
+542
+00:53:45,300 --> 00:53:51,610
+نزلت لمين؟سالم باي على اتنين يبقى سالم باي على
+
+543
+00:53:51,610 --> 00:53:55,810
+اتنين زي ما انتوا شايفينه طيب بكرا ان شاء الله
+
+544
+00:53:55,810 --> 00:54:01,230
+تعالى بدنا نخش على باقى الخمس نسب يبقى عليها اللي
+
+545
+00:54:01,230 --> 00:54:06,230
+عليهم قبل ما تيجي حتى تستفيد فعلا لإننا بدنا نعطي
+
+546
+00:54:06,230 --> 00:54:10,250
+أمثلة عليهم وأمثلة زيها في الكتاب غالبا مافيش زيها
+
+547
+00:54:10,250 --> 00:54:14,690
+في الكتاب دري بالك اه بس كلها أمثلة للذكاء
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/U3pzh94YIHQ_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/U3pzh94YIHQ_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1f9bfe6837bbbb9d9cc9fe4163e7a3f4235cd88c
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/U3pzh94YIHQ_raw.srt
@@ -0,0 +1,2188 @@
+1
+00:00:17,920 --> 00:00:24,040
+المرة الماضية اتبعنا في استخدام قاعدة libital
+
+2
+00:00:24,040 --> 00:00:30,420
+لإيجاد نهايات للدولواخذنا حالتين و بقيت الحالة
+
+3
+00:00:30,420 --> 00:00:36,360
+الثالثة من باب التذكير و ذكر فإن ذكرى تنفع
+
+4
+00:00:36,360 --> 00:00:42,180
+المؤمنين أقولالنقطة الأولى اللى ذكرناها بالنسبة
+
+5
+00:00:42,180 --> 00:00:45,920
+لقاعة Lobital إذا كانت نتيجة التعود المباشر هي
+
+6
+00:00:45,920 --> 00:00:50,880
+Zero على Zero أو Infinity على Infinity من جول
+
+7
+00:00:50,880 --> 00:00:55,640
+limit لل F of X على G of X لما ال X بدأ تروح إلى A
+
+8
+00:00:55,640 --> 00:01:00,420
+سواء كان A رقم أو Zero أو Infinity يبقى هذا بدى
+
+9
+00:01:00,420 --> 00:01:04,800
+يسوي limit مشتق الدالة البسطى على حده مقصوما على
+
+10
+00:01:04,800 --> 00:01:11,450
+مشتق الدالة المقام واخدنا على ذلكبدل المثال خمسة
+
+11
+00:01:11,450 --> 00:01:17,630
+أمثلة ثم انتقلنا بعد ذلك إلى النقطة الثانية وهي
+
+12
+00:01:18,030 --> 00:01:23,370
+الكمية غير المعينة على الصيغة zero في infinity أو
+
+13
+00:01:23,370 --> 00:01:29,090
+infinity minus infinity مثل هذه القيام بدنا نروح
+
+14
+00:01:29,090 --> 00:01:34,050
+نحسب ل limit يبقى بدنا نروح بأي طريقة رياضية ان
+
+15
+00:01:34,050 --> 00:01:38,470
+حولها إلى الحالة الأولى وهي zero على zero أو
+
+16
+00:01:38,470 --> 00:01:45,100
+infinity على infinityيبقى هتان الحالتان دوري ستاء
+
+17
+00:01:45,100 --> 00:01:49,260
+في المرة الماضية الآن بنروح للحالة الثالثة
+
+18
+00:01:49,260 --> 00:01:54,600
+والاخيرة إذا كانت الكيمية تغير المعينة على صيغة
+
+19
+00:01:54,600 --> 00:02:01,760
+واحد أس مال نهاية أو zero أس zero أو مال مال نهاية
+
+20
+00:02:01,760 --> 00:02:09,060
+أس zeroمش هانيجي ندرس هذه الحالة يبقى بدنا .. بدنا
+
+21
+00:02:09,060 --> 00:02:15,600
+نروح نعطيها الملاحظة هذه ثم ندخل في الحالة لإن هذا
+
+22
+00:02:15,600 --> 00:02:20,940
+أو في كيفية التعامل مع مثل هذه الحالة ال remark
+
+23
+00:02:20,940 --> 00:02:25,440
+بتقول إيه؟ لو كان limit لإن ال f of x لما ال x بده
+
+24
+00:02:25,440 --> 00:02:32,370
+يروح ل zero بده يساوي ال L thenبنرجع لمعلوماتنا عن
+
+25
+00:02:32,370 --> 00:02:36,570
+ال limit لما دراسنا ال limit في calculus ايه لجينا
+
+26
+00:02:36,570 --> 00:02:42,450
+ان ال limit عندها صلاحيات كتيرة جدا بتدخل على
+
+27
+00:02:42,450 --> 00:02:50,430
+الجثه اللي مرفوه لأوسف تدخل تحت الجدور تدخل على
+
+28
+00:02:50,430 --> 00:02:55,910
+الذنب تبع النسبة المثلثية اربعة في هذا الفصل بتدخل
+
+29
+00:02:55,910 --> 00:03:01,570
+على اللي جوا الانهى على الكمية اللى جوا منه اللين
+
+30
+00:03:01,570 --> 00:03:05,770
+اذا بناء عليها هندخلها جوا من اللين اللين هذه
+
+31
+00:03:05,770 --> 00:03:10,670
+تتعدى الحدود والسدود والقيود ماعرفش بقدر اقول هى
+
+32
+00:03:10,670 --> 00:03:15,450
+كأنها من وين من الأمم المتحدة طبعا يبقى بدى اروح
+
+33
+00:03:15,450 --> 00:03:20,810
+ادخل ال limit داخل من؟ داخل اللين يبقى بناء عليها
+
+34
+00:03:20,810 --> 00:03:28,390
+بقدر اقول ان اللينللـ limit f of x لما الـ x بدها
+
+35
+00:03:28,390 --> 00:03:35,670
+تروح الى a الكلام هذا كله بده يساوي الـ L إذا
+
+36
+00:03:35,670 --> 00:03:41,410
+بإمكاننا نتخلص من هذه اللينةفبرفع الطرفين كأس لمين
+
+37
+00:03:41,410 --> 00:03:49,650
+للعدد A يبقى إذا E أس لن لlimit لما ال X بدها تروح
+
+38
+00:03:49,650 --> 00:04:01,960
+لل zero لمين لل F of X بده يساوي E أس Lالـ A قد
+
+39
+00:04:01,960 --> 00:04:07,440
+تكون Zero و قد تكون عدد و قد تكون Infinity كله A
+
+40
+00:04:09,780 --> 00:04:15,760
+طيب الآن ال E و ال N دلتان عكس بعض و طبعا حسبنا
+
+41
+00:04:15,760 --> 00:04:21,280
+القيمة E أسلن X يسوى X إذا E أسلن المقدار هذا كله
+
+42
+00:04:21,280 --> 00:04:27,160
+بهذا المقدار يبقى ال limit لما ال X بده يروح إلى A
+
+43
+00:04:27,160 --> 00:04:35,810
+لل F of X بده يسوى 100 T أسليبقى من الآن فصاعدا لو
+
+44
+00:04:35,810 --> 00:04:41,070
+كان limit ل لن بل لما ال X تروح أين ما تروح يبقى
+
+45
+00:04:41,070 --> 00:04:45,230
+في هذه الحالة كان هذا النتج يسوي L إذا ال limit
+
+46
+00:04:45,230 --> 00:04:51,650
+يتدل نفسه بدون لن هي عبارة عن E أسهل برقمخلّي
+
+47
+00:04:51,650 --> 00:04:56,970
+هالمعلومة عندك و بدنا نستخدمها في كل حالة من
+
+48
+00:04:56,970 --> 00:05:02,610
+الحالات الثلاث إلا أننا لذلك هروح نعطي أمثلة على
+
+49
+00:05:02,610 --> 00:05:08,930
+هذه الحالات الثلاث كيف الأمثلة؟ كالتالي بروح نقول
+
+50
+00:05:08,930 --> 00:05:15,850
+find the following limits
+
+51
+00:05:15,850 --> 00:05:23,160
+بدنا النهايات التاليةالنهاية الأولى بيقول ال limit
+
+52
+00:05:23,160 --> 00:05:33,480
+لما
+
+53
+00:05:33,480 --> 00:05:41,880
+ال x بدها تروح الى infinity لمن؟ ل 1 زائد a على x
+
+54
+00:05:41,880 --> 00:05:47,440
+كله to the power x و ال a is constant
+
+55
+00:05:55,130 --> 00:06:01,070
+انظروا يا عزيزي، من حد ما نرى نتيجة التعويض
+
+56
+00:06:01,070 --> 00:06:05,630
+المباشر في مثل، لو طلع أي واحدة من التلاتة دول،
+
+57
+00:06:05,630 --> 00:06:12,730
+بدنا نعمل أربع خطوات لخامس لها، تمام؟ الآن ما هي
+
+58
+00:06:12,730 --> 00:06:19,430
+الخطوات الأربع التي بها سنحصل على حل هذه المثلة؟
+
+59
+00:06:21,810 --> 00:06:26,230
+بنشوف قبل كل شيء، مين هذه من الحالات التلاتة اللي
+
+60
+00:06:26,230 --> 00:06:30,430
+عندنا، إذا بدي أحط X بمالة نهاية، عدد على مالة
+
+61
+00:06:30,430 --> 00:06:36,690
+نهاية؟ Zero، درجة درجة؟ واحد، أس؟ نين، الحالة اللي
+
+62
+00:06:36,690 --> 00:06:41,290
+فوق، يبقى التعويض المباشر لهذه الحالة جاب لي واحد
+
+63
+00:06:41,290 --> 00:06:46,560
+أس infinityإذا طلعت واحدة من الحلوات التلاتة نذهب
+
+64
+00:06:46,560 --> 00:06:52,600
+إلى الخطوات الأربعة التي نتحدث عنها يبقى بروح بقول
+
+65
+00:06:52,600 --> 00:07:00,860
+الخطوات كتر الخطوة الأولى بتقول افرض ان ال F of X
+
+66
+00:07:00,860 --> 00:07:06,160
+بيساوي واحد زائد A على X to the power X
+
+67
+00:07:08,910 --> 00:07:12,590
+فرضنا ان f of x هي الدالة المراد إيجاد ال limit
+
+68
+00:07:12,590 --> 00:07:21,410
+لها الخطوة الثانية بتروح تاخد لن للطرفين يبجى لن
+
+69
+00:07:21,410 --> 00:07:29,530
+ال f of x بده يساوي لن واحد زائد a على x to the
+
+70
+00:07:29,530 --> 00:07:37,280
+power xهذا ماذا يعطي لك؟ ان ال len f of x بده
+
+71
+00:07:37,280 --> 00:07:42,540
+يساوي هذا يعتبر أسل كمية داخل ال len يبقى الأسل
+
+72
+00:07:42,540 --> 00:07:48,920
+بنقوله شرفنا برا حسب خواص ال len يبقى x في len
+
+73
+00:07:48,920 --> 00:07:55,500
+واحد زائد a على x خلصنا الخطوة التانية الخطوة
+
+74
+00:07:55,500 --> 00:08:00,870
+التالتةالخطوة التالتة بدنا نروح ناخد ال limit
+
+75
+00:08:00,870 --> 00:08:07,810
+للطرفين يبقى limit لما ال x بدها تروح لل infinity
+
+76
+00:08:07,810 --> 00:08:15,830
+لمن؟ لمن ال f of x بدها تساوي ال limit لما ال x
+
+77
+00:08:15,830 --> 00:08:27,070
+بدها تروح لل infinity لمن؟ لل x فمن 1 زائد a على x
+
+78
+00:08:27,180 --> 00:08:34,260
+يبقى احنا في الخطوة التالتة، بنروح للرابع حتى ننجز
+
+79
+00:08:34,260 --> 00:08:40,480
+هذه الخطوة، تمام؟ بقول كويس، عوّط عامله بشري وشوف
+
+80
+00:08:40,480 --> 00:08:46,480
+إيش جباننا، الاكسب من infinity، مضروبة فيه، عدد
+
+81
+00:08:46,480 --> 00:08:52,680
+على infinity؟ Zero، لإن الواحد يبقى يد يسارة
+
+82
+00:08:52,680 --> 00:08:56,790
+infinity في zeroInfinity في Zero والله Zero في
+
+83
+00:08:56,790 --> 00:09:00,810
+Infinity كله نفس الشيء زي ما درسنا في المحاضرة
+
+84
+00:09:00,810 --> 00:09:05,750
+الماضية تمام؟ إذا مدام طلع Infinity في Zero بدي
+
+85
+00:09:05,750 --> 00:09:11,690
+أضبط مسألة بأي طريقة رياضية بحيث أحولها إلى صفر
+
+86
+00:09:11,690 --> 00:09:16,630
+على صفر أوInfinity على Infinity من كله بسيطة جدا
+
+87
+00:09:16,630 --> 00:09:21,830
+يبقى هذه limit لما ال X بدأ تروح الى Infinity
+
+88
+00:09:21,830 --> 00:09:28,190
+لمين؟ ها ممكن أنزل ال X هذه تحت بصير X والسالب
+
+89
+00:09:28,190 --> 00:09:34,610
+واحد يعني مين؟ يعني واحد على X يبقى هذه بدأ تصير
+
+90
+00:09:34,610 --> 00:09:42,230
+Lin الواحد زائد A على X كله على واحد على Xطب لما
+
+91
+00:09:42,230 --> 00:09:46,530
+عملت الحركة البسيطة هذه من ناحية رياضية سليمة، لكن
+
+92
+00:09:46,530 --> 00:09:52,310
+شوف شو أملتنا، أمر بسيط، شو عمل؟ ها infinity،
+
+93
+00:09:52,310 --> 00:09:56,430
+zero، لإن الواحد ب zero يبقى البسط ب zero، واحد
+
+94
+00:09:56,430 --> 00:10:01,050
+علي infinity ب zero، إذا تحولت مسألة بهذه العملية
+
+95
+00:10:01,050 --> 00:10:06,680
+الرياضية البسيطة من infinity في zero إلى0 على 0
+
+96
+00:10:06,680 --> 00:10:12,160
+إذا بقدر استخدم قاعدة لبيتال تمام يبقى بقوله هذه
+
+97
+00:10:12,160 --> 00:10:18,380
+تساوي limit لما ال X بدأ تروح لين ل ال infinity
+
+98
+00:10:18,380 --> 00:10:24,900
+لمشتقة ال bus على مشتقة المقام مشتقة ال bus واحد
+
+99
+00:10:25,060 --> 00:10:32,660
+على واحد زائد a على x في مشتقة مداخل الليل له سالب
+
+100
+00:10:32,660 --> 00:10:38,640
+a على x ثربية a مقدار ثابت مشتقة واحد على x ليه
+
+101
+00:10:38,640 --> 00:10:45,780
+بسالب واحد على x ثربية المقام مشتقته بسالب واحد
+
+102
+00:10:45,780 --> 00:10:51,370
+على x ثربيةنختصر لو اختصرنا سالب واحد على أكثر
+
+103
+00:10:51,370 --> 00:10:53,190
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+104
+00:10:53,190 --> 00:10:53,230
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+105
+00:10:53,230 --> 00:10:53,450
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+106
+00:10:53,450 --> 00:10:53,730
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+107
+00:10:53,730 --> 00:10:54,390
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+108
+00:10:54,390 --> 00:10:55,570
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+109
+00:10:55,570 --> 00:11:00,170
+بيهما سالب واحد على أكثر بيهما سالب واحد على أكثر
+
+110
+00:11:00,170 --> 00:11:04,950
+بيهما سالب
+
+111
+00:11:04,950 --> 00:11:11,010
+واحد على أكثر بيهما سالب واحد علىأيه على infinity
+
+112
+00:11:11,010 --> 00:11:15,190
+بزير؟ رفضان جداش؟ واحد على واحد، يبقى يا ده بده
+
+113
+00:11:15,190 --> 00:11:20,550
+يصير إيه يا في؟ واحد ويساوي جداش؟ إيه؟ إذا ال
+
+114
+00:11:20,550 --> 00:11:26,030
+limit لده ليساوي إيه؟ خلصناه؟ما خلصتش انت اللي
+
+115
+00:11:26,030 --> 00:11:30,910
+جيبته هي انت جيبت limit ل لن الدالة واحنا اش بدنا
+
+116
+00:11:30,910 --> 00:11:34,810
+limit ل الدالة وليس limit ل لن الدالة. اذا احنا
+
+117
+00:11:34,810 --> 00:11:40,630
+اشتغلنا ثلاث خطوات. ايه الخطوة الرابعة؟ اللي هو
+
+118
+00:11:40,630 --> 00:11:46,990
+الموضوع ال remark اللي احنا عشرنا اليها هنا.مش أنا
+
+119
+00:11:46,990 --> 00:11:53,850
+أجيب هذه بدي أرفع اتنين كأس للعدد A هنا limit لإن
+
+120
+00:11:53,850 --> 00:11:59,090
+ال F of X لما ال X بدي يروح إلى A limit لإن ال F
+
+121
+00:11:59,090 --> 00:12:04,530
+of X لما ال X بدي يروح إلى Infinity هذا كان يسوى L
+
+122
+00:12:04,530 --> 00:12:11,910
+لـL طلعت هنا إذا ال limit لدنا بدي يسوى E أس L إذا
+
+123
+00:12:11,910 --> 00:12:16,730
+بنروح للخطوة الرابعةيبقى انا بروح اقول اذا ال
+
+124
+00:12:16,730 --> 00:12:22,690
+limit لدالة الأصلية واحد زائد a على x كله to the
+
+125
+00:12:22,690 --> 00:12:28,450
+power x لما ال x tends to infinity بده يساوي e أس
+
+126
+00:12:28,450 --> 00:12:32,650
+a تمام؟
+
+127
+00:12:32,650 --> 00:12:36,870
+يبقى خلاني اوصلك أربع خطوات وانتهي بقى من المثل
+
+128
+00:12:36,870 --> 00:12:42,030
+اللي عندنا تمامالكن أنا إلى خاطر أطرح بعض
+
+129
+00:12:42,030 --> 00:12:48,210
+التساؤلات من خلال هالشكل اللي وصلنا له هنا بدي بدأ
+
+130
+00:12:48,210 --> 00:12:53,970
+أسأل، يا ناس هذا مرة علينا قبل هيك؟ شفناه؟ فصل
+
+131
+00:12:53,970 --> 00:13:01,510
+الأول؟ يعني لما أخذنا الفصل الأول قبل كم من شهر؟
+
+132
+00:13:04,440 --> 00:13:07,760
+يعني برضه في الوصف الأول و الله في التاني يعني في
+
+133
+00:13:07,760 --> 00:13:09,320
+نية section تقريبا
+
+134
+00:13:13,190 --> 00:13:26,230
+أه يعني سبعة تلاتة سبعة تلاتة سبعة تلاتة سبعة
+
+135
+00:13:26,230 --> 00:13:26,810
+تلاتة سبعة تلاتة سبعة تلاتة سبعة تلاتة سبعة تلاتة
+
+136
+00:13:26,810 --> 00:13:33,230
+سبعة تلاتة سبعة تلاتة سبعة
+
+137
+00:13:33,230 --> 00:13:37,410
+تلاتة
+
+138
+00:13:37,410 --> 00:13:45,190
+سبعة تلاتةبس بدل الواحد اجانبين اجانبين اذا a كله
+
+139
+00:13:45,190 --> 00:13:50,670
+صح لو كانت ال a بواحد يبقى بده اشيل ال a و احط ال
+
+140
+00:13:50,670 --> 00:13:56,210
+واحد بصير العدد a يسوي limit واحد زارد واحد على x
+
+141
+00:13:56,210 --> 00:14:01,010
+لما ال x بده تروح لوين لل infinity يبقى اللي احنا
+
+142
+00:14:01,010 --> 00:14:03,730
+اخدناها كخاصية لل exponential function
+
+143
+00:14:07,680 --> 00:14:13,320
+طب خليني اطرح التساوي التالي لو وضت لك limit واحد
+
+144
+00:14:13,320 --> 00:14:17,600
+زائد تلاتة على X لما ال X بده تروح لإمالانها كده
+
+145
+00:14:17,600 --> 00:14:25,020
+ايش بتتساوي؟تقعيد كلام كويس طب لو قلت لك limit لو
+
+146
+00:14:25,020 --> 00:14:32,020
+واحد ناقص ناقص فا واحد على X لما ال X بتروح ل
+
+147
+00:14:32,020 --> 00:14:39,520
+infinity يبقى هذه بيصير E السلب واحد او واحدة ليش؟
+
+148
+00:14:39,520 --> 00:14:43,600
+لأن السلب بقت را كتبه الزائد ودخل الناقص مكانه
+
+149
+00:14:43,600 --> 00:14:47,550
+اللي زاد في ناقص ميبناقصيقول ماسوّناش شيء يبقى
+
+150
+00:14:47,550 --> 00:14:51,950
+بناء عليها بدأ أخد لهذا general for ونحاول نستخدمه
+
+151
+00:14:51,950 --> 00:14:57,490
+متى أم كان ذلك طيب انت عارف ان هذا الآن هيحللنا
+
+152
+00:14:57,490 --> 00:15:01,750
+مشكلة عويصة كانت لو قابلتنا مش عارفين كيف نسوي
+
+153
+00:15:01,750 --> 00:15:06,930
+فيها؟ شو المشكلة هذه؟ هذه مشكلة مثال رقم اتنين
+
+154
+00:15:06,930 --> 00:15:14,540
+مثال رقم اتنين بيقول لي بدي limitلما الـ X tends
+
+155
+00:15:14,540 --> 00:15:22,240
+to infinity لمن؟ لـ X زائد اتنين على X ناقص واحد
+
+156
+00:15:22,240 --> 00:15:27,240
+كله 6 أحد
+
+157
+00:15:27,240 --> 00:15:31,720
+أسئلة الكتاب في التمرين يبقى نرجعت على هذا السؤال
+
+158
+00:15:31,720 --> 00:15:37,440
+و عوضت عوض مباشر بصير مالة نهاية على مالة نهاية
+
+159
+00:15:37,440 --> 00:15:41,960
+أُسبأعرفها اش هذي مالا نيها لأس مالا نيها يومالا
+
+160
+00:15:41,960 --> 00:15:49,100
+نيها لأس مالا يومالا نيها يومالا نيها يومالا نيها
+
+161
+00:15:49,100 --> 00:15:50,540
+يومالا نيها يومالا نيها يومالا نيها يومالا نيها
+
+162
+00:15:50,540 --> 00:15:50,860
+يومالا نيها يومالا نيها يومالا نيها يومالا نيها
+
+163
+00:15:50,860 --> 00:15:51,100
+يومالا نيها يومالا نيها يومالا نيها يومالا نيها
+
+164
+00:15:51,100 --> 00:15:52,480
+يومالا نيها يومالا نيها يومالا نيها يومالا نيها
+
+165
+00:15:52,480 --> 00:16:00,500
+يومالا نيها يومالا نيها يومالا نيها
+
+166
+00:16:00,500 --> 00:16:06,970
+يومالا نيهطيب، ماذا تقترحه حتى أوصل مسامتي إلى شكل
+
+167
+00:16:06,970 --> 00:16:11,930
+مثل هذا الشكل؟ اه يا عيش، ماكنت تقوله هناك؟ بطلت؟
+
+168
+00:16:11,930 --> 00:16:15,350
+طيب اه، وانا بطلت يعني، اه
+
+169
+00:16:20,790 --> 00:16:29,050
+أضيف و اطرح واحد بصير
+
+170
+00:16:29,050 --> 00:16:35,850
+مثل ذلك صعب اكتر اي نعم لكن انا بندي اقتراح اسهل
+
+171
+00:16:35,850 --> 00:16:41,210
+من ذلك بكثير ايوة كويس يقول يجسم البص على المطبخ
+
+172
+00:16:41,210 --> 00:16:45,720
+عن ايه كل الكلام اللي جاله الاخ؟الحلاج مش هيك
+
+173
+00:16:45,720 --> 00:16:51,060
+الاسم الأول محمد اه محمد فوزي اه محمد فوزي الحلاج
+
+174
+00:16:51,060 --> 00:16:56,940
+كمان؟ كويس يبقى اه بنوصل لمين بنوصل الاقتراح اللي
+
+175
+00:16:56,940 --> 00:17:00,720
+قاله لا احنا عندنا شغل غير هيك ايش الشغل غير
+
+176
+00:17:00,720 --> 00:17:04,880
+هيك؟مش ان اوصل للشكل هذا شو رأيك بيداخل X عامل
+
+177
+00:17:04,880 --> 00:17:10,270
+مشترك من كل من البست والمقام على احدةيعني كيف؟
+
+178
+00:17:10,270 --> 00:17:14,570
+يعني بقدر اقول هذه ال limit لما ال x tends to
+
+179
+00:17:14,570 --> 00:17:20,630
+infinity لمن؟ لأي ال x عم المشترك بظل واحد زائد
+
+180
+00:17:20,630 --> 00:17:26,690
+اتنين على x والمقام بدي اخد x عم المشترك بظل واحد
+
+181
+00:17:26,690 --> 00:17:35,290
+ناقص واحد على x وهذا كله to the power xتمام هلحين
+
+182
+00:17:35,290 --> 00:17:40,690
+هذه ال X ممكن أقولها مع السلامة على هذه وهذا ال X
+
+183
+00:17:40,690 --> 00:17:46,090
+يعتبر لكل من البصف والمقام صحيح ولا لا؟ إذا بقدر
+
+184
+00:17:46,090 --> 00:17:52,190
+أقول هذا limit لما ال X tends to infinity لواحد
+
+185
+00:17:52,190 --> 00:17:58,770
+زائد اتنين على X كله to the power X على واحد ماقص
+
+186
+00:17:58,770 --> 00:18:05,060
+واحد او زائد واحدوهنا بدأ اضع ناقص واحد كله to the
+
+187
+00:18:05,060 --> 00:18:10,920
+power x بالشكل اللي عندنا ناقص
+
+188
+00:18:10,920 --> 00:18:15,240
+واحد كتبتها زائد ناقص واحديبقى اطلعلي في هذا
+
+189
+00:18:15,240 --> 00:18:18,200
+السؤال الأول ال limit كان هو limit للبسط و limit
+
+190
+00:18:18,200 --> 00:18:22,600
+للمقار صحيح ولا لا limit البسط من السؤال هو القدرش
+
+191
+00:18:22,600 --> 00:18:27,660
+بيعطيلك E ثربيع يبقى هذا الكلام بدي يعطيلك E
+
+192
+00:18:27,660 --> 00:18:34,200
+square هذا برضه بنفس المثل بيعطيك ماميبقى E أُس
+
+193
+00:18:34,200 --> 00:18:38,820
+سالب واحد هذا الكلام جيبناه من أين؟ from ال
+
+194
+00:18:38,820 --> 00:18:42,100
+question one يعني من المثال او من ال example one
+
+195
+00:18:42,100 --> 00:18:48,900
+من المثال الأول هذه ال backdrop اقول هي مين؟ هي E
+
+196
+00:18:48,900 --> 00:18:53,080
+تكعين وانتهينا منها لا مشينا لا خط ولا تاني ولا
+
+197
+00:18:53,080 --> 00:18:57,220
+تالتة ولا رابعة طيب لو كان السؤال هذا جاني في
+
+198
+00:18:57,220 --> 00:19:02,350
+الأول لو جبته مثاليبقى بدي أمشي فيه لو إلا حد هنا،
+
+199
+00:19:02,350 --> 00:19:06,950
+و بعدين بدي أروح أخد هذه لحالها، و أجيب اللي متلها
+
+200
+00:19:06,950 --> 00:19:10,050
+الأربع خطوات، و هذه اللي متلها أربع خطوات، و أشوف
+
+201
+00:19:10,050 --> 00:19:14,130
+كده بده ياخد وجد، تمام؟ إذا وجود السؤال هذا في
+
+202
+00:19:14,130 --> 00:19:20,030
+الأول، حلي كل الإشكاليات بعد ذلك، جد ما تكون أي
+
+203
+00:19:20,030 --> 00:19:25,220
+رقم،خلاص النتيجة معروف وبعوض فيها و بنامشيها تمام؟
+
+204
+00:19:25,220 --> 00:19:30,000
+لا لو جالك السؤال هذا لحاله بدك تعمل هذه و تقول
+
+205
+00:19:30,000 --> 00:19:35,600
+هذه similar بنفس الطريقة اه مش همشي دوري ولكن من
+
+206
+00:19:35,600 --> 00:19:40,780
+وين جبت هذه؟ كويس؟ طيب هذه اللي هو المثال رقم
+
+207
+00:19:40,780 --> 00:19:45,060
+اتنين بدنا نروح للمثال رقم ثلاثة
+
+208
+00:19:59,190 --> 00:20:06,730
+يبقى example three بيقول ليه؟ بدى limit لما ال X
+
+209
+00:20:06,730 --> 00:20:14,070
+tends to zero لمن؟ لل E وال6 زائد ال X كله أسواحب
+
+210
+00:20:14,070 --> 00:20:17,870
+على X الآن هذا بده ساوي
+
+211
+00:20:35,570 --> 00:20:42,750
+لو جينا عوض مستعود مباشر Zero E of Zero بواحد واحد
+
+212
+00:20:42,750 --> 00:20:47,390
+على صفر ب Infinity يبقى واحد أس Infinity لازمنا في
+
+213
+00:20:47,390 --> 00:20:52,760
+الحالة الأولى يبقى بنا نمشي الخطوات الأربعيبقى
+
+214
+00:20:52,760 --> 00:20:58,420
+بالدرجة قول له let f of x بدي يساوي e وال6 زائد x
+
+215
+00:20:58,420 --> 00:21:04,580
+كله الواحد على x خد لي لن الطرفين يبقى لن ال f of
+
+216
+00:21:04,580 --> 00:21:11,270
+x بدي يساوي واحد على x لن ال e وال6 زائد xخد ال
+
+217
+00:21:11,270 --> 00:21:15,690
+limit اللي هي الخطوة التالتة limit لما ال x بده
+
+218
+00:21:15,690 --> 00:21:24,170
+يروح لل zero لما ال x بدها تروح لل zero لمن لإن ال
+
+219
+00:21:24,170 --> 00:21:30,170
+f of x بده يسوي limit لما ال x بدها تروح لل zero
+
+220
+00:21:30,170 --> 00:21:38,670
+لواحد على x لإن ال EO6 زائد Xلو جينا عوضنا تعويض
+
+221
+00:21:38,670 --> 00:21:45,570
+مباشر بصيل واحد على الصفر infinity Zero E of Zero
+
+222
+00:21:45,570 --> 00:21:54,510
+بواحد لإن الواحد جداش ب Zeroبتفتح المثلة بطريقة
+
+223
+00:21:54,510 --> 00:21:59,650
+رياضية صحيحة بحيث فعلا تحولها صفر على صفر أو مالة
+
+224
+00:21:59,650 --> 00:22:04,670
+نهاية على مالة نهاية يبقى limit لما ال X بده تروح
+
+225
+00:22:04,670 --> 00:22:11,350
+ل zero هي جازة بس فاتة هناك كويس يعني لن EO6 زائد
+
+226
+00:22:11,350 --> 00:22:12,470
+X على X
+
+227
+00:22:15,890 --> 00:22:22,690
+سنقوم باستخدام قاعدة Lobital يبقى هذا الكلام يستوي
+
+228
+00:22:22,690 --> 00:22:29,500
+ال limit لما ال X يذهب الى 0 مشتاقة ال bus واحدعلى
+
+229
+00:22:29,500 --> 00:22:38,400
+EOSX زائد X في مشتقة مداخل الـ LEN له EOSX زائد 1
+
+230
+00:22:38,400 --> 00:22:44,360
+كله على مشتقة المقام له بواحد صحيح يبقى قالة الى
+
+231
+00:22:44,360 --> 00:22:51,200
+limit لما ال X بدي روح ل 0 لل EOSX زائد 1 على EOSX
+
+232
+00:22:51,200 --> 00:22:57,790
+زائد X نجي نعوض طاولة مباشرة و نشوف جدش تعطيناE of
+
+233
+00:22:57,790 --> 00:23:05,870
+0 ب 1 يبقى بصير عن هنا 1 زائد 1 E of 0 ب 1 زائد 0
+
+234
+00:23:05,870 --> 00:23:13,150
+يبقى 1 زائد 0 يبقى النتيجة جداشلغاية هنا كم خطوة
+
+235
+00:23:13,150 --> 00:23:18,550
+عملنا؟ تلاتة. ضايل علينا خطوة رابعة. دي لبالك. هذه
+
+236
+00:23:18,550 --> 00:23:22,270
+نفسيه تبقى قصم عليها علامة. إذا السؤال عليه أربعة
+
+237
+00:23:22,270 --> 00:23:26,490
+درجات ولا خمسة، بنطير عليه علامة. يبقى ضروري إياك
+
+238
+00:23:26,490 --> 00:23:33,400
+ثم إياك أن تنساه. يبقى بصير عنه limitلما ال X بدي
+
+239
+00:23:33,400 --> 00:23:40,620
+اروح لل Zero لمن؟ لل E of X زاد X أس واحد على X
+
+240
+00:23:40,620 --> 00:23:47,120
+يساوي E ترابيع سؤال
+
+241
+00:23:47,120 --> 00:23:52,020
+الرابع بيقول
+
+242
+00:23:52,020 --> 00:24:00,650
+لي limitلما ال X tends to infinity لمن؟ لل X تكييب
+
+243
+00:24:00,650 --> 00:24:06,210
+زائد A أس واحد على لن ال X
+
+244
+00:24:11,250 --> 00:24:18,330
+مالة نهاية تكيب واضيف عليها رقم مالة نهاية واحد
+
+245
+00:24:18,330 --> 00:24:22,310
+لان المالة نهاية بمالة نهاية واحدة مالة نهاية ب
+
+246
+00:24:22,310 --> 00:24:28,870
+zero يبقى هذه infinity of اللي هي الحالة التالتة
+
+247
+00:24:28,870 --> 00:24:33,610
+مظبوط؟ مدام الحالة التالتة يبقى بأن نشتغل الأربع
+
+248
+00:24:33,610 --> 00:24:36,750
+خطوات يبقى بالدرجة أقوله افترض
+
+249
+00:24:45,310 --> 00:24:52,990
+خطوة التانية خد لن للطرفين يبقى لن ال F of X يسوى
+
+250
+00:24:52,990 --> 00:25:04,380
+واحد على لن ال X في لن ال X تكييب زائد Eخطوة تالتة
+
+251
+00:25:04,380 --> 00:25:24,260
+خطوة
+
+252
+00:25:24,260 --> 00:25:25,760
+تالتة خطوة تالتة خطوة تالتة خطوة تالتة خطوة تالتة
+
+253
+00:25:25,760 --> 00:25:27,380
+خطوة تالتة خطوة تالتة خطوة تالتة خطوة تالتة خطوة
+
+254
+00:25:27,380 --> 00:25:28,360
+تالتة خطوة تالتة خطوة تالتة خطوة تالتة خطوة تالتة
+
+255
+00:25:28,360 --> 00:25:31,090
+خطوة تالتة خطوة تالتةلأن الانفينيتي لمّا راح
+
+256
+00:25:31,090 --> 00:25:37,210
+لانفينيتي لإن رايح لوين؟ لانفينيتيوهذا كمان جداش
+
+257
+00:25:37,210 --> 00:25:44,270
+infinity يبقى اتحولت مثلتنا من infinity of zero
+
+258
+00:25:44,270 --> 00:25:49,050
+إلى infinity على infinity إذا مشتقت دالة البصرة
+
+259
+00:25:49,050 --> 00:25:54,810
+على مشتقت دالة المقام يبقى limit لما ال X tends to
+
+260
+00:25:54,810 --> 00:26:02,810
+infinity لمين لتلاتة X تربيع على X تكيبزائد اي
+
+261
+00:26:02,810 --> 00:26:07,430
+واحد على اكس تكيب زائد اي في مشتقة ال E بتلاتة اكس
+
+262
+00:26:07,430 --> 00:26:11,990
+تربية ومشتقة ال E بزيرو اللي عملنا لدالة اللي فوق
+
+263
+00:26:11,990 --> 00:26:17,150
+بدي نعمله لدالة اللي تحت مشتقة ال N ال X بواحد على
+
+264
+00:26:17,150 --> 00:26:22,790
+اكس بدي اعيد ترتيب المثلة بشكل مهذبأحسن هذا كلكعة
+
+265
+00:26:22,790 --> 00:26:28,510
+كبيرة هذي يبقى بنرجع لكثور الاعتيادية تبع ترابة
+
+266
+00:26:28,510 --> 00:26:36,210
+امتدائي يبقى هذا بيصير تلاتة X تربيع على X تكعيب
+
+267
+00:26:36,210 --> 00:26:42,530
+زادي وهذه ال X بتطلع وين؟ فوق بيصير هذا تلاتة X
+
+268
+00:26:42,530 --> 00:26:50,030
+تكعيب والباقي كما هو طيب الان لو جيت عوض طبعا وانا
+
+269
+00:26:50,030 --> 00:26:57,990
+مش راجعش بطلعInfinity على Infinity كويس يبقى هذا
+
+270
+00:26:57,990 --> 00:27:04,490
+بتطلع Infinity على Infinity شو نعمل؟ كمان مرة يبقى
+
+271
+00:27:04,490 --> 00:27:08,590
+هذا الكلام يساوي ال limit لما ال X tends to
+
+272
+00:27:08,590 --> 00:27:16,490
+Infinity لميم لتسعة X ترابيع على تلاتة X ترابيع
+
+273
+00:27:16,490 --> 00:27:20,110
+تعاود مباشر Infinity على Infinity كمان مرة و كمان
+
+274
+00:27:20,110 --> 00:27:25,400
+مرة طب واش هالشدة يا عباد الله؟ما تختصر X تربية مع
+
+275
+00:27:25,400 --> 00:27:29,800
+X تربية أو تسعة مع تلاتة بيبقى الجداش تلاتة اذا
+
+276
+00:27:29,800 --> 00:27:34,280
+واحد تاني جالي بدل ما سويتك مكان من هنا زي ما
+
+277
+00:27:34,280 --> 00:27:38,120
+أخدنا في calculus A وفي الثانوية العامة هذه ال
+
+278
+00:27:38,120 --> 00:27:40,860
+polynomial و هذه ال polynomial يبقى بنجسم كل من
+
+279
+00:27:40,860 --> 00:27:44,300
+البصر ومن القعام على X المرفوعة لأكبر أُس في
+
+280
+00:27:44,300 --> 00:27:47,980
+المقام لو عملها حد بقدر يقول إنه غلط لأ يا عم صح
+
+281
+00:27:47,980 --> 00:27:51,920
+مدام أخدناها أجابة لهك تشتغلي بها مع أن مانعيبقى
+
+282
+00:27:51,920 --> 00:27:56,960
+لو جسمنا كله على اكسا كيب بصير ثلاثة على واحد E
+
+283
+00:27:56,960 --> 00:27:59,680
+على اكسا كيب ال limit لابزي ربما ثلاثة على واحد
+
+284
+00:27:59,680 --> 00:28:04,260
+اللي هو جداش ثلاثة و احنا طلعناها هنا جداش ثلاثة
+
+285
+00:28:04,260 --> 00:28:10,340
+طب حتى اللي انا احنا عملناثلاث خطوات وبنروح للخطوة
+
+286
+00:28:10,340 --> 00:28:16,800
+الرابعة يبقى بادي بقوله sir limit لما ال X بدها
+
+287
+00:28:16,800 --> 00:28:23,640
+تروح لل infinity لراس المسألة X تكيب زائد E أس
+
+288
+00:28:23,640 --> 00:28:32,000
+واحد على لإن ال X بده يساوي جداش E تكيب طيب السؤال
+
+289
+00:28:32,000 --> 00:28:41,200
+الخامسسؤال الخامس بيقول ما يأتي بدنا limit لمن؟
+
+290
+00:28:41,200 --> 00:28:47,260
+لما ال X بدها تروح لل zero من جهة اليمين ل X
+
+291
+00:28:47,260 --> 00:28:53,680
+مرفوعة لل أس صين ال X بدنا
+
+292
+00:28:53,680 --> 00:28:59,730
+نحط مكان X Zero، بصير Zero أس0 للحالات التانية
+
+293
+00:28:59,730 --> 00:29:06,370
+اللي ماحلناش عليها ولا سؤال يبقى هذه 0 أُس 0 كويس
+
+294
+00:29:06,370 --> 00:29:13,230
+يبقى بدنا نروح للأربع خطوات يبقى let ال F of X
+
+295
+00:29:13,230 --> 00:29:18,680
+يساوي X أُصين ال X هذه الخطوة الأولىالخطوة التانية
+
+296
+00:29:18,680 --> 00:29:24,180
+بدك تاخد limit للطرفين يبقى limit ال f of x بده
+
+297
+00:29:24,180 --> 00:29:29,060
+يساوي ال sign ال x في limit ال x الخطوة التالتة
+
+298
+00:29:29,060 --> 00:29:34,700
+بدك تاخد limit لlimit ال f of x لما ال x بده يروح
+
+299
+00:29:34,700 --> 00:29:40,540
+ل zero من جهة اليمين يساوي ال limit لما ال x بدها
+
+300
+00:29:40,540 --> 00:29:45,760
+تروح ل zero من جهة اليمين ل sign ال x في limit ال
+
+301
+00:29:45,760 --> 00:29:54,580
+xنعوض تعويضا مباشرا sign is zero الان لن zero من
+
+302
+00:29:54,580 --> 00:30:00,540
+جهة اليمين اللي منزل علوان على سالب infinity يبقى
+
+303
+00:30:00,540 --> 00:30:06,760
+zero في سالب infinity والله zero في infinity اتنين
+
+304
+00:30:06,760 --> 00:30:13,720
+كمية غير معينةطيب استخدم صلاحياتك limit لما ال X
+
+305
+00:30:13,720 --> 00:30:18,820
+بده يروح ل zero مشان تحسب هذه ال limit طب ايش
+
+306
+00:30:18,820 --> 00:30:23,980
+صلاحياتي؟ صلاحياتي اشتغل شغل رياضي صحيح ماحدش يقدر
+
+307
+00:30:23,980 --> 00:30:27,860
+يقوللي عليه خطأ يعني بده احول المسألة الى zero على
+
+308
+00:30:27,860 --> 00:30:33,320
+zero او infinity على infinity ماذا تقترحون ايه يا
+
+309
+00:30:33,320 --> 00:30:34,020
+ابنك؟
+
+310
+00:30:36,590 --> 00:30:40,790
+مهم تاعتد ان ال sign هي مقلوب من ال cosecant يعني
+
+311
+00:30:40,790 --> 00:30:46,630
+ريب سبروكال of cosecant ال X يبقى جالي هذا خللي ان
+
+312
+00:30:46,630 --> 00:30:52,010
+ال X زي ما هي و هذه cosecant ال X اللي هي مقلوب ال
+
+313
+00:30:52,010 --> 00:30:56,610
+sign بنقوله والله تمام طب لو عوضنا و تعاودنا و
+
+314
+00:30:56,610 --> 00:31:04,510
+مشرشو بتعطيني هذهInfinity على منحنى الـ cosecant
+
+315
+00:31:04,510 --> 00:31:09,290
+.متذكرينه ولا زي الحلم؟إذا مش متذكرينه، في نهاية
+
+316
+00:31:09,290 --> 00:31:13,330
+هذه المحاضرة، بدنا نبدأ في الsection الجديد، اللي
+
+317
+00:31:13,330 --> 00:31:17,570
+هو الـ trigonometric functions، وبكرا، بديك تيجي
+
+318
+00:31:17,570 --> 00:31:21,930
+مراجعة، لإنه بدنا نكملها ونخش على أمثلتها.يعني
+
+319
+00:31:21,930 --> 00:31:26,710
+بكرا، بديك تيجي مراجعة شكل الرسم البياني لل
+
+320
+00:31:26,710 --> 00:31:31,310
+trigonometric functions.دري بالك.هنبدأ فيه بعد
+
+321
+00:31:31,310 --> 00:31:35,610
+قليل لكن الباقية لك تجي مراجعه يبقى ال consequant
+
+322
+00:31:35,610 --> 00:31:40,070
+هذه لو روحنا لل zero من جهة اليمين ال consequant
+
+323
+00:31:40,070 --> 00:31:44,510
+بيجيني من فوق و بيجي نازل لعند الواحد وبعود بطلع
+
+324
+00:31:44,510 --> 00:31:50,390
+تاني يبقى هذا عبارة عن ايش سالب infinity على
+
+325
+00:31:50,390 --> 00:31:54,690
+infinity ماعناش مشكلة infinity على infinity والله
+
+326
+00:31:54,690 --> 00:31:58,590
+سالب infinity على infinity إذا مشتقة البس على
+
+327
+00:31:58,590 --> 00:32:06,510
+مشتقةالمقام تفضل ال X بواحد على X والكسي كانت
+
+328
+00:32:06,510 --> 00:32:15,930
+بسالب كسي كانت ال X في كتان ال X كيف؟
+
+329
+00:32:15,930 --> 00:32:22,850
+سافر من جهة اليمين، مظبوط؟ اقول لك اعمل هيك و الله
+
+330
+00:32:22,850 --> 00:32:32,880
+يشرفكرسمت الرسمة طلع على الرسمة و كتبناها
+
+331
+00:32:32,880 --> 00:32:38,080
+as a limit اللي من ضمن ال properties of لن ال X
+
+332
+00:32:41,720 --> 00:32:45,860
+طيب يبقى هذا الكلام بدي يساوي ال limit لما ال X
+
+333
+00:32:45,860 --> 00:32:50,220
+بدها تروح ل zero من جهة اليمين، بدي أعيد ترتيب
+
+334
+00:32:50,220 --> 00:32:55,240
+المثلة، يبقى ال X هاد بتنزل وين؟ ال cos كان بدي
+
+335
+00:32:55,240 --> 00:32:59,950
+اكتبها ال sign و ال quotient بدي اكتبهابتعلنه
+
+336
+00:32:59,950 --> 00:33:07,730
+تانية مقلب الكتان إذا بصير هذي sin X و هنا tan X
+
+337
+00:33:07,730 --> 00:33:14,010
+على مين على X وهي إشارة السالب قبلهم كلهم طيب هذا
+
+338
+00:33:14,010 --> 00:33:18,690
+الكلام بدي يساوي سالب برا و limit لما ال X بدي
+
+339
+00:33:18,690 --> 00:33:24,430
+يروح ل zero من جهة اليمين ل sin X على X بنفع ولا
+
+340
+00:33:24,430 --> 00:33:30,780
+لا؟فاهمين؟ في limit لما ال X بدها تروح ل zero من
+
+341
+00:33:30,780 --> 00:33:37,000
+جهة اليمين لتان ال X هذا الكلام بده يساوي السالم
+
+342
+00:33:37,000 --> 00:33:42,200
+هذي ال limit بقداش يا شباب واحد صحيح تمام تمام
+
+343
+00:33:42,200 --> 00:33:49,030
+وهذه تاني ال zero منحنتانيمر بنقطة الأصل، إذا
+
+344
+00:33:49,030 --> 00:33:54,910
+انتهى الـ Zero بقداش؟ بـ Zero و يساوي كداش؟ و
+
+345
+00:33:54,910 --> 00:33:59,790
+يساوي Zero يبقى انتهينا من مين؟ من ثلاث خطوات،
+
+346
+00:33:59,790 --> 00:34:05,900
+باقية الخطوة الرابعةيبقى باجي بقول له سا limit لما
+
+347
+00:34:05,900 --> 00:34:11,720
+ال X بدها تروح لل zero من جهة اليمين لل X أص عين
+
+348
+00:34:11,720 --> 00:34:17,800
+ال X بده يساوي E أزره اللي يبقى داشر بواحد صحيح
+
+349
+00:34:20,660 --> 00:34:27,540
+ملاحظين انه أخدنا بدل المثال خمسة وكله بنمشي بنفس
+
+350
+00:34:27,540 --> 00:34:33,480
+التكتيك ونفس الفكرة يعني لا توجد فيهم الخمسة فكرة
+
+351
+00:34:33,480 --> 00:34:40,700
+جديدة واحد منهم بست بدالهم كلهم لكن بدنا نعطيك نفس
+
+352
+00:34:40,700 --> 00:34:46,740
+الموضوع بفكرة جديدة نفس الموضوع هكتب لمثال جديد
+
+353
+00:34:46,740 --> 00:34:48,180
+يبقى example
+
+354
+00:34:54,110 --> 00:35:05,610
+Find the value of the constant A
+
+355
+00:35:15,030 --> 00:35:22,410
+Such that limit لما ال X tends to zero لل A to the
+
+356
+00:35:22,410 --> 00:35:32,810
+power X زائد X أس واحد على X يساوي أربعة E مرة دي
+
+357
+00:35:32,810 --> 00:35:38,770
+بنا في أحدى الامتحانات سؤال شبيه بهذا السؤال فكر
+
+358
+00:35:38,770 --> 00:35:45,640
+كيف بدنا نحل هذا السؤالوعبال ممسح اللوح بدك تكون
+
+359
+00:35:45,640 --> 00:35:52,800
+فكرت وعطيتن الإجابة طيب
+
+360
+00:35:52,800 --> 00:36:00,200
+السؤال هو كيف ننحل هذا السؤال؟نجي لسؤالنا هذا،
+
+361
+00:36:00,200 --> 00:36:03,780
+يبقى السؤال هذا بمسك الطرف الشمال و كانوا ماعيش
+
+362
+00:36:03,780 --> 00:36:09,860
+خبر مين، الطرف اليمين الأربع خطوات، طبعا؟ و بعدين
+
+363
+00:36:09,860 --> 00:36:15,960
+الله بحلها، يبقى بدي أروح أقول هنا الـالـ F of X
+
+364
+00:36:15,960 --> 00:36:22,300
+يساوي لـ A to the power X زائد X أس واحد على X
+
+365
+00:36:22,300 --> 00:36:28,520
+وبدنا نحاول نجيب مقدار الثابت A من خلال ال limit
+
+366
+00:36:28,520 --> 00:36:33,050
+والإجابة اللي لنا لـ 4Aيبقى بعد ذلك نروح ناخد
+
+367
+00:36:33,050 --> 00:36:40,210
+limit للطرفين يبقى لن ال F of X بده ساوي واحد على
+
+368
+00:36:40,210 --> 00:36:46,410
+X لن ال A to the power X زائد X بعد ذلك نروح ناخد
+
+369
+00:36:46,410 --> 00:36:53,850
+limit للطرفينيبقى هذا بيعطيك limit لإن ال f of x
+
+370
+00:36:53,850 --> 00:37:00,150
+لما ال x بدها تروح ل zero بده يساوي limit لما ال x
+
+371
+00:37:00,150 --> 00:37:06,710
+tends to zero لمن؟ لإن ال a to the power x زائد x
+
+372
+00:37:06,710 --> 00:37:13,210
+كله على من؟ على x لو جيت و عوضت تعويض مباشر يبقى
+
+373
+00:37:13,210 --> 00:37:20,550
+zero a of zeroبواحد لنا الواحد بزيرو على زيرو يبقى
+
+374
+00:37:20,550 --> 00:37:24,970
+صورة هذه زيرو على زيرو تمام؟ مدام زيرو على زيرو
+
+375
+00:37:24,970 --> 00:37:32,210
+إذا بقدر استخدم قاعدة لبتن كويس يبقى واحد على ا
+
+376
+00:37:32,210 --> 00:37:39,450
+والسكس زائد ال X في مشتقة ما داخل اللين ا to the
+
+377
+00:37:39,450 --> 00:37:46,740
+power X في جداش؟لأن الـ a تمامًا مذاكرينه كويس زاد
+
+378
+00:37:46,740 --> 00:37:51,500
+واحد يبقى واحد على a to the power x زاد x في مشتقة
+
+379
+00:37:51,500 --> 00:37:55,680
+هذا المقار a to the power x لإن ال a ومشتقة ال x
+
+380
+00:37:55,680 --> 00:38:01,800
+يامين بواحد كله على مشتقة المقام جداش بواحد صحيح
+
+381
+00:38:01,800 --> 00:38:07,480
+يبقى هذا يساوي طب لو جيت عوّط عن ال x ب zero بده
+
+382
+00:38:07,480 --> 00:38:14,050
+أشوف لإيش بوصلأو الـ Zero يبقى بضال عندي إلا لإن
+
+383
+00:38:14,050 --> 00:38:20,450
+الـ A زائد واحد هذا Zero أو Zero بواحد يبقى هذا
+
+384
+00:38:20,450 --> 00:38:25,250
+كله على واحد مظبوط يبقى مادام هيك مضالش عندي إلا
+
+385
+00:38:25,250 --> 00:38:30,550
+لإن ال A زائد واحد يبقى هذا هو اللي بدي سوى أربعة
+
+386
+00:38:30,550 --> 00:38:38,930
+E مظبوط يعني الكلام غلط طيب ماشي موافقينهذه هي
+
+387
+00:38:38,930 --> 00:38:43,490
+limit للدالة وليست limit للإن الدالة احنا اللي
+
+388
+00:38:43,490 --> 00:38:48,730
+حصلنا عليه هذا هو limit للإن الدالة اه يعني بناء
+
+389
+00:38:48,730 --> 00:38:51,950
+عليها بلعنا لسه الخطوة الرابعة هذول التلات خطوات
+
+390
+00:38:51,950 --> 00:38:59,050
+اذا بروح للخطوة الرابعة و بقول limitللـ F of X لما
+
+391
+00:38:59,050 --> 00:39:06,630
+الـ X بده يروح للـ Zero بده يساوي E أُس لان اللي
+
+392
+00:39:06,630 --> 00:39:13,710
+هو مين الـ A زائد واحد، هيك بالكلامنا صحيحهذا من
+
+393
+00:39:13,710 --> 00:39:23,490
+خواص اللي هو العدد a بقول e أس لإن ال a ضرب e أس
+
+394
+00:39:23,490 --> 00:39:29,450
+واحد عند الضرب بتجمع من ال أس أس ال a و اللي إن
+
+395
+00:39:29,450 --> 00:39:36,310
+عكس بعض بظل جداش a و e أس واحد هي ب e هيك خلصت
+
+396
+00:39:36,310 --> 00:39:40,000
+الأربع خطواتجالي في راسي اللي مسلمت لهذا المقبر
+
+397
+00:39:40,000 --> 00:39:45,900
+يساوي كده؟ يبقى هذا اللي هو بيساوي أربعة ايه، مش
+
+398
+00:39:45,900 --> 00:39:50,160
+الأولاني، تمام؟ يبقى هنا الخطأ اللي بيحصل عند
+
+399
+00:39:50,160 --> 00:39:54,300
+الطلاب لو جيهم هذا السؤال، بوصل لهذا و بروح يساوي
+
+400
+00:39:54,300 --> 00:39:58,600
+هذا، بلعجل عنه و يصير يبطح في المثل هذه، بدي أجيب
+
+401
+00:39:58,600 --> 00:40:02,140
+الأيه بالعافية، تمام؟ بكون نقصة عليها الخطوة
+
+402
+00:40:02,140 --> 00:40:10,810
+وبالتالي ضيعت يعني، جول، تلت السؤالمن هذهها بستنتج
+
+403
+00:40:10,810 --> 00:40:16,990
+تماما ان الـ A تساوي قداشر أربعة يبقى ثابت A
+
+404
+00:40:16,990 --> 00:40:24,250
+دوسائي أربعة لحد يناسب انتهى هذا ال section وإليكم
+
+405
+00:40:24,250 --> 00:40:27,170
+أرقام المسائل
+
+406
+00:40:43,800 --> 00:40:48,700
+يبقى exercises سبعة
+
+407
+00:40:48,700 --> 00:40:57,020
+خمسة المسائل التالية سبعة خمسة من واحد لغاية سبعة
+
+408
+00:40:57,020 --> 00:41:07,200
+وسبعين multiple of three multiple of three وكذلك
+
+409
+00:41:07,200 --> 00:41:10,700
+سؤال خمسة و تمانين
+
+410
+00:41:13,670 --> 00:41:17,270
+لحظين امتنعنا من هذا ال section ننتقل الان الى ال
+
+411
+00:41:17,270 --> 00:41:22,590
+section السابع
+
+412
+00:41:22,590 --> 00:41:34,070
+ستة اللي هو ال inverse trigonometric functions
+
+413
+00:41:39,470 --> 00:41:45,730
+معكوث الدوال المثلثية احنا لما درسنا معكوث الدالة
+
+414
+00:41:45,730 --> 00:41:52,110
+قولنا المعكوث الدالة exist إذا كانت حقق شرط واحد
+
+415
+00:41:52,110 --> 00:41:57,310
+إن الدالة كانت one to one ممتاز جدا تفضل تعالى
+
+416
+00:41:57,310 --> 00:42:02,290
+نشوف الدوال المثلثية الستة هل هي one to one والله
+
+417
+00:42:02,290 --> 00:42:08,090
+ماهياش one to oneنمسك الدالة الأولى نمرة واحدة
+
+418
+00:42:08,090 --> 00:42:17,240
+هقول ان y تساوي sin inverse x او arc sin xبعض
+
+419
+00:42:17,240 --> 00:42:23,060
+الكتب بتكتبها sin inverse x وعليها ناقص واحد وبعض
+
+420
+00:42:23,060 --> 00:42:27,240
+الكتب بتكتبها arc sine X يعني لو روحت المكتبة
+
+421
+00:42:27,240 --> 00:42:33,200
+وفتحت اي كتاب ولاقيت arc sine تفهم ان هذا هو معكوس
+
+422
+00:42:33,200 --> 00:42:39,320
+الدالة المثلثية اللى قدامنا هذه طيب نجي الان
+
+423
+00:42:39,320 --> 00:42:44,340
+للدالة المثلثية اللى arc sine X أو sin inverse X
+
+424
+00:42:46,380 --> 00:42:52,660
+خدنا رسمتها في كل قلص ايه؟ مظبوط؟ صح؟ بتذكر تذكير
+
+425
+00:42:52,660 --> 00:42:57,660
+ليس إلا لما كنا نرسم مكانة موجها طالعة و نازلة،
+
+426
+00:42:57,660 --> 00:43:02,840
+مظبوط؟ و ال top قد إيه شخص حد يرسمه؟ و أقل حاجة؟
+
+427
+00:43:02,840 --> 00:43:07,200
+ممتاز، يبقى الرسم محصورة بين واحد و سالب واحد لو
+
+428
+00:43:07,200 --> 00:43:12,920
+رسمت horizontal line بقطعها في مالة نهاية من
+
+429
+00:43:12,920 --> 00:43:18,950
+النقاط، إذاالـ function ليست one to one، مظبوط؟
+
+430
+00:43:18,950 --> 00:43:23,930
+طيب، يبقى المعكوس غير موجود لكن إيش رايك؟ بدنا
+
+431
+00:43:23,930 --> 00:43:27,710
+نروح ناخد جزء من ال domain يعني بدنا نعمل
+
+432
+00:43:27,710 --> 00:43:32,630
+restriction على ال domain يعني نحصر ال domain في
+
+433
+00:43:32,630 --> 00:43:38,330
+فترة محددة مضمن خلال هذه الفترة لو رسمت أي
+
+434
+00:43:38,330 --> 00:43:42,350
+horizontal line، لا يقطع المنحنة إلا في نقطة M
+
+435
+00:43:44,240 --> 00:43:49,500
+بتذكر بس برسمة الـSin أولا ثم نشوف أين اللي بدنا
+
+436
+00:43:49,500 --> 00:43:53,520
+ناخده يبقى لو جيت لرسمة الـSin الـSin اللي عندنا
+
+437
+00:43:53,520 --> 00:43:59,600
+بهذا الشكل هذا محور X هذا محور Y هذا نقطة الأصل
+
+438
+00:43:59,600 --> 00:44:04,990
+اللي هي Zeroاتفاقنا ان منحنى الـSin لا يزيد عن
+
+439
+00:44:04,990 --> 00:44:11,570
+واحد بأي حال من الأحوال و لا ينزل عن من عن سالب
+
+440
+00:44:11,570 --> 00:44:15,830
+واحد بأي حال من الأحوال إذن الدالة محصورة بين
+
+441
+00:44:15,830 --> 00:44:20,930
+الخطين المنقطين الاتنين هدول اتنين منحنى الـSin
+
+442
+00:44:20,930 --> 00:44:26,280
+يمر بنقطة الأصل ولا بمراشبأمور تمام التملوجين
+
+443
+00:44:26,280 --> 00:44:32,980
+ذكرنا برسمته حرصه بس منقط متعمد اه رسمنا هيك و
+
+444
+00:44:32,980 --> 00:44:38,020
+برجع نازل هيك و برجع نازل و بهذا الشكل و من
+
+445
+00:44:38,020 --> 00:44:43,380
+الناحية التانية بيجي نازل هيك و بيجي طالع و هكذا
+
+446
+00:44:45,260 --> 00:44:54,360
+طبعا هنا zero هنا باي على اتنين وهنا باي and so on
+
+447
+00:44:54,360 --> 00:44:59,800
+وهنا سالب باي على اتنين وهنا سالب باي على اتنين
+
+448
+00:44:59,800 --> 00:45:00,740
+وهكذا
+
+449
+00:45:02,940 --> 00:45:07,860
+بناخد فقط الجزء من المنحنى من النقطة هذه لغاية
+
+450
+00:45:07,860 --> 00:45:13,260
+النقطة هذه يبقى المنحنى يصير عندنا من عند هذه هي
+
+451
+00:45:13,260 --> 00:45:21,080
+بدراسة بالخط الأسود المتراصل بهذا الشكل يبقى هذا
+
+452
+00:45:21,080 --> 00:45:24,840
+خط
+
+453
+00:45:24,840 --> 00:45:28,540
+اللي عندنا لغاية النقطة هذه وهنا لغاية النقطة اللي
+
+454
+00:45:28,540 --> 00:45:34,650
+عندنا هذهكويس يبقى المنحنة هذا لو رسمت اي
+
+455
+00:45:34,650 --> 00:45:39,870
+horizontal line بلقيه يقطع المنحنة في نقطة واحدة
+
+456
+00:45:39,870 --> 00:45:44,330
+في نقطة واحدة يبقى ضمنت من هذا ان هذه ال sign x
+
+457
+00:45:44,330 --> 00:45:47,550
+على الفترة من سالب باية على اتنين لباية على اتنين
+
+458
+00:45:47,550 --> 00:45:53,950
+عبارة عن one to oneطبعا مدام وانت وان يبقى المعكوس
+
+459
+00:45:53,950 --> 00:46:00,550
+موجود يبقى بناء عليه انا بدي اخد y تساوي صين ال x
+
+460
+00:46:00,550 --> 00:46:05,650
+و ال x هذه مش على اطلاقها و انما موجودة في ال
+
+461
+00:46:05,650 --> 00:46:10,770
+class interval سالب by على اتنين و by على اتنين
+
+462
+00:46:10,770 --> 00:46:19,250
+بهذا الشكل هيك ضمنت وجود من المعكوس كيف يقولممكن
+
+463
+00:46:19,250 --> 00:46:23,050
+البايع اتنين لتلت بايع اتنين؟ ممكن، عادي جدا.
+
+464
+00:46:23,490 --> 00:46:27,090
+زميلكوا بيقول انا ممكن اخد الفترة من البايع على
+
+465
+00:46:27,090 --> 00:46:31,210
+اتنين لتلت بايع اتنين، بيقولوا والله صح وعتني قال
+
+466
+00:46:31,210 --> 00:46:34,350
+لي لا، ممكن اخدها من سلب بايع اتنين إلى سلب تلت
+
+467
+00:46:34,350 --> 00:46:38,370
+بايع اتنين صحيح بس إذا أخدت الفترة هذه، بدك تروح
+
+468
+00:46:38,370 --> 00:46:43,290
+على مسائل التمرين كلها و تجلبها طبقا للفترة
+
+469
+00:46:43,290 --> 00:46:47,170
+الجديدة عندك، الأسلة تبعها تمرين مصممة على الفترة
+
+470
+00:46:47,170 --> 00:46:50,470
+اللي عندك كانوبالتالي لو خلّيت المثال و أخدت
+
+471
+00:46:50,470 --> 00:46:54,050
+الفترة التانية، بيروح الدولة و بيقول كله غلط، اه
+
+472
+00:46:54,050 --> 00:46:59,510
+دي بالك، يعني المثال مصممة على الفترة ان X عندي
+
+473
+00:46:59,510 --> 00:47:02,710
+one to one من سالف باية اتنين لباية اتنين
+
+474
+00:47:06,220 --> 00:47:12,500
+والآن بدنا نروح نرسم رسمة المعكوس تبع هذه أبلة
+
+475
+00:47:12,500 --> 00:47:17,920
+فبعدين بقول بدنا نعرف ما هو شكل المعكوس فبعدين
+
+476
+00:47:17,920 --> 00:47:23,160
+باخد المحاور بالشكل اللي عندنا هذا هذا محور X هذا
+
+477
+00:47:23,160 --> 00:47:29,860
+محور Y هذا نقطة الاصلنرجع بالذاكرة إلى الوراق
+
+478
+00:47:29,860 --> 00:47:35,480
+قليلا، لأول section أخدناه، قلنا إذا الدلة من سالب
+
+479
+00:47:35,480 --> 00:47:38,680
+باية على اتنين لباية على اتنين، هذا يعتبر domain
+
+480
+00:47:38,680 --> 00:47:44,800
+الدلة، لكن ال range من سالب واحد إلىالـ Range تبع
+
+481
+00:47:44,800 --> 00:47:49,820
+الـ function هو ال domain تبع المعكوس و ال range
+
+482
+00:47:49,820 --> 00:47:55,960
+تبع المعكوس هو ال domain تبع الدالة تمام؟ إذا هذا
+
+483
+00:47:55,960 --> 00:48:00,300
+اللي هو ال domain بدو يصير ال range و اللي كان ال
+
+484
+00:48:00,300 --> 00:48:04,140
+range بدو يصير ال domain صحيح ولا لأ؟ إذا الرسم
+
+485
+00:48:04,140 --> 00:48:10,290
+هتنحصل عندي من عندي السالب واحد لغاية كداشرإذا
+
+486
+00:48:10,290 --> 00:48:14,910
+الرسم هذي مش هتتعدى الخط الرأسي اللي هو x يساوي
+
+487
+00:48:14,910 --> 00:48:19,430
+سالب واحد ولا هتتعدى الخط الرأسي اللي هو x يساوي
+
+488
+00:48:19,430 --> 00:48:26,290
+قداش واحدالنقطة هذه الإحداثية تبعها سالب باي على
+
+489
+00:48:26,290 --> 00:48:31,430
+اتنين وسالب واحد تصير سالب واحد وسالب باي على
+
+490
+00:48:31,430 --> 00:48:37,730
+اتنين سالب واحد وبدك تنزل سالب باي على اتنين هذه
+
+491
+00:48:37,730 --> 00:48:44,160
+هناها سالب باي على اتنين يعني بدك توجه فيناالنقطة
+
+492
+00:48:44,160 --> 00:48:48,500
+التانية دي إحداثية هي باي على اتنين و واحد بدا
+
+493
+00:48:48,500 --> 00:48:53,300
+تصير واحد و باي على اتنين واحد و بدا تطلع باي على
+
+494
+00:48:53,300 --> 00:48:58,280
+اتنين اللي هو هنا واحد و باي على اتنين يبجه هي
+
+495
+00:48:58,280 --> 00:49:03,630
+النقطة اللي هي main باي على اتنينهذا المنحنى على
+
+496
+00:49:03,630 --> 00:49:08,950
+الجزء هذا concave down لما ترسم الخطوة يتساركس بده
+
+497
+00:49:08,950 --> 00:49:13,730
+ينجلب ويصير concave up يبقى المنحنى هذا بده يصير
+
+498
+00:49:13,730 --> 00:49:18,790
+عندك بده يجيك بالشكل هذا هيك ويجيك ايوة concave up
+
+499
+00:49:18,790 --> 00:49:24,370
+هذا concave up بده يصير concave down يبقى هذا
+
+500
+00:49:24,370 --> 00:49:29,700
+المنحنى لو رحت كملته هيصير بالشكل اللي عندنايبقى
+
+501
+00:49:29,700 --> 00:49:36,240
+هذا الرسم اللي رسمناها هي عبارة عن y تساوي ال sign
+
+502
+00:49:36,240 --> 00:49:42,580
+inverse x والx محصورة ما بين السالب واحد والواحد
+
+503
+00:49:43,190 --> 00:49:49,250
+تمام؟ طيب ممتاز يبقى عرفنا رسمة معكوسة دالة وعرفنا
+
+504
+00:49:49,250 --> 00:49:52,230
+ال domain و ال range ايه اللي هي ال domain من سلب
+
+505
+00:49:52,230 --> 00:49:56,450
+واحد إلى واحد و ال range من سلب باي على اتنين إلى
+
+506
+00:49:56,450 --> 00:50:02,830
+باي على اتنين اذا خلينا نكتب بعض خواص ال sign هذه
+
+507
+00:50:02,830 --> 00:50:07,590
+يبقى بالداجة اقول انه some properties
+
+508
+00:50:11,750 --> 00:50:19,410
+some properties of
+
+509
+00:50:19,410 --> 00:50:26,710
+y تساوي sin inverse x خاصية
+
+510
+00:50:26,710 --> 00:50:34,570
+الأولى بدي أجيب domain sin inverse x يساوي من وين
+
+511
+00:50:34,570 --> 00:50:44,400
+لوين من سالب واحد إلى واحد andالـ Range لـ sine
+
+512
+00:50:44,400 --> 00:50:51,800
+inverse X بدي ساوي برضه سالب باي على اتنين الى باي
+
+513
+00:50:51,800 --> 00:50:58,340
+على اتنين as any closed interval النقطة الثانية لو
+
+514
+00:50:58,340 --> 00:51:04,220
+جيت قولتلك المنحنى Y تساوي sine inverse X is
+
+515
+00:51:04,220 --> 00:51:08,700
+equivalent to
+
+516
+00:51:12,460 --> 00:51:18,000
+بدي اجيب العبارة المكافئة لهذه العبارة تمام؟ شو
+
+517
+00:51:18,000 --> 00:51:24,680
+بدي اعمل؟ بدي اثر على الطرفين domain ب sign يبقى
+
+518
+00:51:24,680 --> 00:51:32,160
+بصير هنا sign ال Y يساوي sign ل sign inverse X كده
+
+519
+00:51:32,160 --> 00:51:38,620
+اش بيقولك X يبقى هذا بدي يقولك X بشرطإن الـ X تبقى
+
+520
+00:51:38,620 --> 00:51:42,360
+موجودة في دمين الـ sine inverse لو ماكنتش بصير
+
+521
+00:51:42,360 --> 00:51:47,280
+كلامنا هذا ماله غلط اذا حازم أريك بغدا ان شاء الله
+
+522
+00:51:47,280 --> 00:51:52,480
+بعض الأمثلة يبقى هنا هذا الكلام بده يساوي الشكل عن
+
+523
+00:51:52,480 --> 00:51:56,120
+هذا إذا كانت ال X فعلا في دمين ال sine inverse
+
+524
+00:51:56,120 --> 00:52:00,440
+يعني إذا كان ال sine inverse X exist automatic
+
+525
+00:52:00,440 --> 00:52:06,130
+بيكون sine ال Y بساوي Xالخاصية التالتة لو أخدت
+
+526
+00:52:06,130 --> 00:52:12,250
+sign inverse ل sign ال X زي ما أنا بقول هذا الكلام
+
+527
+00:52:12,250 --> 00:52:18,250
+فعلا بده يساوي X إذا ال X موجودة في domain mean
+
+528
+00:52:21,430 --> 00:52:24,570
+سالب باى على اتنين لباى اللى ال restriction اللى
+
+529
+00:52:24,570 --> 00:52:30,490
+عملناه يبقى هذا إذا X موجودة من سالب باى على اتنين
+
+530
+00:52:30,490 --> 00:52:38,190
+إلى باى على اتنين وفي نفس الوقت صين ال X لصين
+
+531
+00:52:38,190 --> 00:52:45,630
+inverse X بده يسوى X إذا كانت ال X موجودة في دمية
+
+532
+00:52:45,630 --> 00:52:52,840
+ال main صين inverse يعني قداشمن سالب واحد إلى واحد
+
+533
+00:52:52,840 --> 00:52:59,180
+as any closed interval بلّة أن الخاصية الرابعة
+
+534
+00:52:59,180 --> 00:53:03,860
+والاخيرة من الخواصات اللي بدنا نعطيهم في هذه
+
+535
+00:53:03,860 --> 00:53:10,320
+اللحظة الخاصية الرابعة لو أخدت ال limit يبقى limit
+
+536
+00:53:10,320 --> 00:53:17,480
+ل sign inverse x لما ال x بدأ تروح للواحد من جهة
+
+537
+00:53:17,480 --> 00:53:24,100
+الشماليبقى احنا بدنا نروح للواحد من جهة الشمال
+
+538
+00:53:24,100 --> 00:53:28,180
+يبقى
+
+539
+00:53:28,180 --> 00:53:34,220
+هذا الكلام بده يساوي باي على اتنين and limit لل
+
+540
+00:53:34,220 --> 00:53:40,940
+sign inverse X لما ال X بدها تروح لسالب واحد من
+
+541
+00:53:40,940 --> 00:53:45,300
+جهة اليمين يبقى لو روحنا من جهة اليمين بلاقيها
+
+542
+00:53:45,300 --> 00:53:51,610
+نزلت لمين؟سالم باي على اتنين يبقى سالم باي على
+
+543
+00:53:51,610 --> 00:53:55,810
+اتنين زي ما انتوا شايفينه طيب بكرا ان شاء الله
+
+544
+00:53:55,810 --> 00:54:01,230
+تعالى بدنا نخش على باقى الخمس نسب يبقى عليها اللي
+
+545
+00:54:01,230 --> 00:54:06,230
+عليهم قبل ما تيجي حتى تستفيد فعلا لإننا بدنا نعطي
+
+546
+00:54:06,230 --> 00:54:10,250
+أمثلة عليهم وأمثلة زيها في الكتاب غالبا مافيش زيها
+
+547
+00:54:10,250 --> 00:54:14,690
+في الكتاب دري بالك اه بس كلها أمثلة للذكاء
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/VHma_B9Gmf4_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/VHma_B9Gmf4_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..fa5383f0a06923563dcb97d20c9569ea508b7d3e
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/VHma_B9Gmf4_raw.srt
@@ -0,0 +1,1760 @@
+1
+00:00:00,000 --> 00:00:02,700
+موسيقى
+
+2
+00:00:10,610 --> 00:00:14,290
+بسم الله الرحمن الرحيم موضوعنا اليوم موضوع ال
+
+3
+00:00:14,290 --> 00:00:19,450
+connect sections اللي هي القطوع المخروطية تبقى
+
+4
+00:00:19,450 --> 00:00:24,250
+موضوعنا اليوم موضوع القطوع المخروطية صورة أننا
+
+5
+00:00:24,250 --> 00:00:29,890
+ل�نا مخروط بشكل هذا بدنا نعمل له مقاطع لدينا الحمد
+
+6
+00:00:29,890 --> 00:00:36,580
+لله بدل المقطع خمسة مقاطع من القطوع المخروطيةانا
+
+7
+00:00:36,580 --> 00:00:41,280
+اريك الان كيف تنشي هذه القطوة لو جيت قلت له هذا
+
+8
+00:00:41,280 --> 00:00:47,200
+قطع مخروط وجيت قطعته بمستوى من الرأس وضليت ماشي مع
+
+9
+00:00:47,200 --> 00:00:51,940
+المحور تبعه يبقى هيرسم لي خط من هنا وخط من الناحية
+
+10
+00:00:51,940 --> 00:00:56,700
+الثانية يبقى معناه هذا الكلام ان اول قطع مخروط هو
+
+11
+00:00:56,700 --> 00:01:01,890
+الخط المستقيموهذا سبق دراسته في الإعدادية
+
+12
+00:01:01,890 --> 00:01:06,030
+والثانوية وكل كلاص ايه تمام؟ يبقى هذا القطع
+
+13
+00:01:06,030 --> 00:01:10,790
+المخروط الأول اللي هو ال straight line خط المستقيم
+
+14
+00:01:10,790 --> 00:01:16,450
+نجي للقطع الثاني لو قطعته بمستوى عمودي على المحور
+
+15
+00:01:16,450 --> 00:01:20,370
+يبقى المقطع عبارة عن ايه؟ دائرة يبقى ال circle
+
+16
+00:01:20,370 --> 00:01:26,090
+كمان سبق دراستها قبل ذلك يبقى هذا القطع المخروطي
+
+17
+00:01:26,090 --> 00:01:34,370
+الثانيبنجر قطة المخروطة الثالث لو جيت له المخروطة
+
+18
+00:01:34,370 --> 00:01:40,510
+اللى أنا قطعته بمستوى رأسي موازي للمحور تبعه يبقى
+
+19
+00:01:40,510 --> 00:01:45,290
+المقطع هيكون على شكل parabola نوريكي الآن كيف
+
+20
+00:01:45,290 --> 00:01:47,930
+بيكون هذا المقطع
+
+21
+00:01:57,870 --> 00:02:02,450
+يبقى لو جيت بطعت القطع المخروض بدي اعتبر ان الخط
+
+22
+00:02:02,450 --> 00:02:06,990
+الأزرق اللي انا رسمه هذا هو قطع من فوق الى اعلى
+
+23
+00:02:06,990 --> 00:02:12,510
+يبقى طلع شكله كيه بدي يكون خط الأزرق المنحني اللي
+
+24
+00:02:12,510 --> 00:02:16,330
+عندنا هنا يبقى هذا على شكل مين؟ Parabola يبقى
+
+25
+00:02:16,330 --> 00:02:20,510
+القطع المخروض الثالث هو ال Parabola موضوع دراستنا
+
+26
+00:02:20,510 --> 00:02:28,490
+الآنلو جيت قطعته بمستوى مائل على المحور يبقى
+
+27
+00:02:28,490 --> 00:02:32,850
+المقطع عبارة عناش؟ شكل بيضاوي الشكل البيضاوي هذا
+
+28
+00:02:32,850 --> 00:02:39,090
+اللي بنسميه من؟ القطع الناقص أو ال ellipse تمام لو
+
+29
+00:02:39,090 --> 00:02:43,670
+جيت تخيلت أخدت خدت الورقة اللي عندك هاني ماشي لو
+
+30
+00:02:43,670 --> 00:02:49,650
+جيت هات هشوفلو جيت تخيلت إن هذا القطع المخروط
+
+31
+00:02:49,650 --> 00:02:55,750
+التاني والاتنين متعدين في الرأس بهذا الشكل تمام؟
+
+32
+00:02:55,750 --> 00:03:00,450
+وقطعتهم من أعلى إلى أسفل، هتظهر Parabola إلى أعلى
+
+33
+00:03:00,450 --> 00:03:04,590
+و Parabola إلى أسفل، يبقى هذا الاتنين مع بعضهم
+
+34
+00:03:04,590 --> 00:03:08,540
+يسميهم إيه؟هذه البرابولة يبقى هذا القطع المخروط
+
+35
+00:03:08,540 --> 00:03:14,180
+الخامس يبقى line circle parabola ellipse هذه
+
+36
+00:03:14,180 --> 00:03:19,540
+برابولة هذا موضوع درستنا طبعا سابقا في كل كنصية
+
+37
+00:03:19,540 --> 00:03:26,680
+درستناقطعين و نص طبعا كيف قطعين و نص؟ خط مستقيل
+
+38
+00:03:26,680 --> 00:03:31,580
+ديرها هي اتنين الفرابولة درسنا بس فيه نقطتين اللي
+
+39
+00:03:31,580 --> 00:03:37,120
+هو ال vertex و ال axis طبعا هاي اللي كنت بتكلم فيه
+
+40
+00:03:37,120 --> 00:03:42,590
+سابقا يبقى ال vertex و ال axisلكن الان في انا كمان
+
+41
+00:03:42,590 --> 00:03:46,550
+حاجتين اشداد، حاجة اسمها ال focus والتانية
+
+42
+00:03:46,550 --> 00:03:52,810
+directrix يبقى هاي كمان النص التانية تبع من ال
+
+43
+00:03:52,810 --> 00:03:57,330
+parabola يبقى ال parabola هتعرف عليه باربع شغلات،
+
+44
+00:03:57,330 --> 00:04:02,250
+vertex, axis, focus, directrix طب نجي نشوف شو
+
+45
+00:04:02,250 --> 00:04:07,060
+المعلومات هذه اللي بنحكيهابالنسبة للبرابولة سابقة
+
+46
+00:04:07,060 --> 00:04:10,960
+دراسته كمان رسموا كده كتير في كل قلصية وفي
+
+47
+00:04:10,960 --> 00:04:16,500
+الثانوية بنعيده مرة ثانية وبنقول نفترض اني أخدت
+
+48
+00:04:16,500 --> 00:04:21,600
+المحاور وكان هذا محور X وهذا محور Y وهذه نقطة
+
+49
+00:04:21,600 --> 00:04:26,900
+الأصل روحنا رسمنا البرابولة هذه فكانت البرابولة
+
+50
+00:04:26,900 --> 00:04:34,590
+على الشكل التاليبهذا الشكل يبقى هذا الشكل من ال
+
+51
+00:04:34,590 --> 00:04:41,030
+parabola اللى عندنا يبقى
+
+52
+00:04:41,030 --> 00:04:46,290
+ماس نقطة الاصل هنا وجه طالع تاني حاجة ماذا ذكر ايش
+
+53
+00:04:46,290 --> 00:04:53,760
+كنا نكتب المعادلة؟Y تسوي X ربيعها دي حالة خاصة من
+
+54
+00:04:53,760 --> 00:04:58,580
+الحالة العامة، شو الحالة العامة؟ الحالة العامة
+
+55
+00:04:58,580 --> 00:05:06,350
+كانت X تربيع تساوي أربعة PYيبقى هذه الحالة العاملة
+
+56
+00:05:06,350 --> 00:05:12,210
+من ل .. اللي هو البرادنة، لو كانت P بربع، بتيجي
+
+57
+00:05:12,210 --> 00:05:16,650
+المعادلة اللي بتقول عليها N to Y to 7N X ربيع،
+
+58
+00:05:16,650 --> 00:05:21,790
+الان بناعرف شو ال P هذه، بجي بقول هذا اللي كنا
+
+59
+00:05:21,790 --> 00:05:28,470
+نسميه من ال axisتمام؟ وهذه اللي كنا نسميها ال
+
+60
+00:05:28,470 --> 00:05:32,850
+vertex اللي هو ال rise تبع ال parabola فيه ضالانة
+
+61
+00:05:32,850 --> 00:05:38,790
+شغلتين جداد، الشغل الأولى ليه؟ ال focus، البقرة،
+
+62
+00:05:38,790 --> 00:05:46,120
+أظن سمعته بالمراية المقعرةهذا المرحلة لو سقطت
+
+63
+00:05:46,120 --> 00:05:51,360
+عليها الشمس بتجمع الأشعة كلها بتحط عليها النقطة دي
+
+64
+00:05:51,360 --> 00:05:56,520
+بيسميها البقرة يبقى المنحنة اللي عندنا هذا بقله
+
+65
+00:05:56,520 --> 00:06:02,440
+بقرة البقرة تقع على ال axis هنا بشكل اللي عندنا
+
+66
+00:06:02,440 --> 00:06:09,560
+هذا يبقى هذه الإحداث تبعها Zero و PP اللي هو البعد
+
+67
+00:06:09,560 --> 00:06:16,740
+هذا هذا هو البعد P اللي بسميه
+
+68
+00:06:16,740 --> 00:06:22,720
+البعد البقري parabolas focal length البعد البقري
+
+69
+00:06:22,720 --> 00:06:33,140
+للبرابولة يبقى هذا بسميه parabolas focal length
+
+70
+00:06:34,600 --> 00:06:39,000
+البعد البقري للParabola، فبقى كويس، يبقى كويس ورا
+
+71
+00:06:39,000 --> 00:06:40,820
+عنا نقلب دواش؟ تلاتة
+
+72
+00:06:48,350 --> 00:06:55,530
+خط مستقيم عمودي على الـ axis بهذا الشكل تماما
+
+73
+00:06:55,530 --> 00:07:03,070
+ويبعد عنه مسافة مقدارها P يبقى هذه المسافة مقدارها
+
+74
+00:07:03,070 --> 00:07:11,550
+P كذلك إذا هذا الخط معادلة Y تساوي كم؟سالب بي.
+
+75
+00:07:11,570 --> 00:07:17,330
+يبقى سالب بي. إذا الفرابلة لو حبنا نعطيله تعريف
+
+76
+00:07:17,330 --> 00:07:24,470
+رياضي بقول هو المحل الهندسي للنقطة التي تتحرك في
+
+77
+00:07:24,470 --> 00:07:31,290
+المستوى بحيث يكون بعديها عن نقطة ثابتة وعن مستقيم
+
+78
+00:07:31,290 --> 00:07:38,250
+ثابت يسوي مقدارا ثابتا اوهي النقطة التي تتحرك في
+
+79
+00:07:38,250 --> 00:07:44,290
+المستوى بحيث يكون بُعدها عن نقطة ثابتة يساوي
+
+80
+00:07:44,290 --> 00:07:49,650
+بُعدها تماما عن مستقيم ثابت المستقيم الثابت هذا
+
+81
+00:07:49,650 --> 00:07:58,250
+هسميه directrix الدليل يبقى هذا directrix هذه
+
+82
+00:07:58,250 --> 00:08:07,870
+هسميها ال focus للبقرةيبقى سهر علنا Vertexاكسز خط
+
+83
+00:08:07,870 --> 00:08:12,870
+اللي بنصفه لنصين focus by rectrix هاي الأربع
+
+84
+00:08:12,870 --> 00:08:17,850
+معلومات تبعت من ال Parabola يبقى لو شفت معادل
+
+85
+00:08:17,850 --> 00:08:22,930
+Xربيه يسوى أربعة في Y معناته Parabola ال physics
+
+86
+00:08:22,930 --> 00:08:28,470
+تبعه هي نقطة الأصل and open R مفتوح إلى أنا بسبب
+
+87
+00:08:28,470 --> 00:08:33,740
+الإشارة الموجبة هنا طب لو صارت الإشارة سالبةيجب ان
+
+88
+00:08:33,740 --> 00:08:38,200
+ينقلب البرابولة ويسير الى أسفل كيف؟ على الشكل
+
+89
+00:08:38,200 --> 00:08:44,500
+التالي فبعدين بقول لو كان هذا محور X و هذا محور Y
+
+90
+00:08:44,500 --> 00:08:49,580
+يبقى البرابولة بيصير بالشكل اللي انها هذا ويصير
+
+91
+00:08:49,580 --> 00:08:59,420
+معادلة X تربيع يساوي سالب أربعة PYحسنًا، الـP الآن
+
+92
+00:08:59,420 --> 00:09:04,640
+هو الـFocus. الـFocus موجود أين؟ الداخل. الداخل
+
+93
+00:09:04,640 --> 00:09:10,060
+.يعني لو كنت أجرب لك الفكرة بالبلدي، بالبلدي، أين
+
+94
+00:09:10,060 --> 00:09:15,460
+البقرة بالنسبة للإنسان؟ القلب. لو خرب القلب، مات
+
+95
+00:09:15,460 --> 00:09:19,860
+الإنسان. مظبوط؟ يبقى دائمًا أنك بدأت تفهم أن
+
+96
+00:09:19,860 --> 00:09:25,580
+البقرة في داخل الرسم البياني للمنحنط. إذن البقرة
+
+97
+00:09:25,580 --> 00:09:31,590
+بدأ تجينا هنا.هذه البقرة يبقى الإحداث يتبعها كم؟
+
+98
+00:09:31,590 --> 00:09:38,790
+Zero و سالب P يبقى ال directrix على نفس البعد بدي
+
+99
+00:09:38,790 --> 00:09:46,090
+يجينا هنا فوق يبقى هذا هو ال directrix اللي معادلة
+
+100
+00:09:46,090 --> 00:09:52,250
+Y تساوي P على نفس البعد تماما وهذه هي ال vertex
+
+101
+00:09:52,250 --> 00:09:58,170
+والaxis بقية كما هويبقى المعادلة X تربية يساوي سلب
+
+102
+00:09:58,170 --> 00:10:04,010
+أربعة TY طب ممكن ما يكون الشكل ممكن يكون مفتوح ذات
+
+103
+00:10:04,010 --> 00:10:09,030
+اليمين أو ذات الشمال يبقى لو حصل هذا بدي يكون شكل
+
+104
+00:10:09,030 --> 00:10:14,830
+ال parabola على الشكل التالي يبقى هذا محور X هذا
+
+105
+00:10:14,830 --> 00:10:20,090
+محور Y هذه نقطة الأصل parabola بدي يكون بالشكل
+
+106
+00:10:20,090 --> 00:10:26,950
+اللي عندنا هذاهذا شو معاقبته؟ بدنا نبدل ال X مكان
+
+107
+00:10:26,950 --> 00:10:33,830
+ال Y و ال Y مكان ال X فصير Y تربيه يساوي أربعة P X
+
+108
+00:10:33,830 --> 00:10:39,450
+الشكل لأن هذا، وين ال P بدا تيجي؟ في الداخل، يبقى
+
+109
+00:10:39,450 --> 00:10:46,180
+هذا ال P يبقى هذا P و Zeroالـ Directrix دائما هو
+
+110
+00:10:46,180 --> 00:10:51,340
+أبدا عمودي على ال Axis يبقى لو جيت جولت هذا هو ال
+
+111
+00:10:51,340 --> 00:10:55,920
+Directrix البعد هذا جد البعد هذا يبقى هذا هو ال
+
+112
+00:10:55,920 --> 00:11:03,580
+Directrix يبقى معادلته X بدل سوى كده يا شباب سالب
+
+113
+00:11:03,580 --> 00:11:12,340
+P تمام يبقى هذا ال vertex هذا هو ال Axisهذه هي ال
+
+114
+00:11:12,340 --> 00:11:16,500
+focus وهذا هو ال directrix، هذه الأربع شغلات اللي
+
+115
+00:11:16,500 --> 00:11:23,220
+عندنا، الآن لو كان مفتوح جهات الشمال يبقى هذا محور
+
+116
+00:11:23,220 --> 00:11:28,580
+X وهذا محور Y وشكل ال parabola هيكون على الشكل
+
+117
+00:11:28,580 --> 00:11:29,540
+التالي
+
+118
+00:11:31,690 --> 00:11:39,010
+يبقى هذا معدد نفسي اللي فوق Y تربيع سالب أربعة P X
+
+119
+00:11:39,010 --> 00:11:43,810
+يبقى ال focus اللي تيجي في الداخل هنا يبقى بالصينة
+
+120
+00:11:43,810 --> 00:11:49,920
+إحداثي تبعها سالب P و Zeroالـ vertex لم تتغير في
+
+121
+00:11:49,920 --> 00:11:56,600
+الحالات الأربعة، دلت هي ال origin هذا هو ال axis،
+
+122
+00:11:56,600 --> 00:12:03,200
+تمام؟ يبقى vertex، focus، axis، بقى ال directrix
+
+123
+00:12:03,200 --> 00:12:08,580
+عمودي على ال axisيبقى بالشكل اللي عنده هذا ويبعد
+
+124
+00:12:08,580 --> 00:12:13,940
+عنه مثل بُعد ال vertex مثل بُعد ال focus عن ال
+
+125
+00:12:13,940 --> 00:12:19,620
+vertex يبقى المعادلة هذه معادلة x يساوي جداش x
+
+126
+00:12:19,620 --> 00:12:29,400
+يساوي Pأول شيء ال axis ينصف ال parabola إلى نصفين.
+
+127
+00:12:29,840 --> 00:12:33,680
+هذه النقطة الأولى. النقطة الثانية ال directrix
+
+128
+00:12:33,680 --> 00:12:38,640
+دائما هو أقل عمودي على مين؟ على ال axis.نما تلاتة
+
+129
+00:12:38,640 --> 00:12:43,480
+لا يمكن لل directrix أن يقطع مين؟يقطع البرابولة
+
+130
+00:12:43,480 --> 00:12:49,380
+دايما وابدا منه برة، طلع، هي هنا تحت، هنا فوق، هنا
+
+131
+00:12:49,380 --> 00:12:53,980
+على الشمال، هنا على اليمين، ولا مرة قطع من المنحنى
+
+132
+00:12:53,980 --> 00:12:58,020
+ولا يقطع في يوم ليوم الداركس دايما وابدا ماله
+
+133
+00:12:58,020 --> 00:13:02,360
+بيكون برة حسب ال definition اللي قلناها البرابولة
+
+134
+00:13:02,360 --> 00:13:06,670
+هو المحل الهندسي لنقطة تتعرك في ال planeبقى تكون
+
+135
+00:13:06,670 --> 00:13:10,370
+بُعدها على نقطة ثابتة ليه ال focus يساوي نفس
+
+136
+00:13:10,370 --> 00:13:14,950
+بُعدها على المستقيم الثابت اللي همان ال directrix
+
+137
+00:13:14,950 --> 00:13:20,510
+هذا كل جزء النظر اللي يتعلق بمان بالparabola بقيت
+
+138
+00:13:20,510 --> 00:13:26,430
+نقطة واحدة لو عملنا له shift إزاحة إيش بتكون شكل
+
+139
+00:13:26,430 --> 00:13:31,110
+المعادلة في الحالة الأولى أو في الحالات التانيةكيف
+
+140
+00:13:31,110 --> 00:13:35,710
+ال shift؟ قداش احداتي ال vertex هنا؟ Zero Zero،
+
+141
+00:13:35,710 --> 00:13:40,410
+بده أبطل أخليه Zero Zero، بده أخليه H و K فبجي
+
+142
+00:13:40,410 --> 00:13:46,090
+بقول هنا، if the
+
+143
+00:13:46,090 --> 00:13:57,610
+vertex of the طرابلة is H و K
+
+144
+00:14:03,110 --> 00:14:11,190
+نمسك المعادلة الأولى يبقى x ناقص h لكل تربية يسوى
+
+145
+00:14:11,190 --> 00:14:18,350
+أربعة في y ناقص k طبعا بالزائد أو بالناقص
+
+146
+00:14:21,960 --> 00:14:27,940
+الحالة التانية اللي هو ال Y ناقص K لكل تربية يسوي
+
+147
+00:14:27,940 --> 00:14:33,500
+زيد أو ناقص 4PX ناقص ال H بالشكل اللي عندنا هذا
+
+148
+00:14:33,500 --> 00:14:38,020
+يعني لو مسيكنا أي واحدة منهم وعملناها إذا حويل ما
+
+149
+00:14:38,020 --> 00:14:47,320
+بدك يبقى هذا الرسمة وهذا محور X وهذا محور Y نفترض
+
+150
+00:14:47,320 --> 00:14:54,710
+جدلا إن كان هذه هي ال vertexوهي يبقى بدل ما كانت
+
+151
+00:14:54,710 --> 00:15:02,170
+Zero و Zero صارت النقطة H و K وافترضنا ان ال
+
+152
+00:15:02,170 --> 00:15:07,390
+Parabola كان على الشكل اللي عندنا هنايبقى بدنا
+
+153
+00:15:07,390 --> 00:15:15,510
+معادلة وين H و K يبقى اتحركنا هنا مسافة مقدرها H و
+
+154
+00:15:15,510 --> 00:15:21,870
+هنا نزلنا مسافة مقدرها K تمام؟ يبقى K صارت سالبة
+
+155
+00:15:21,870 --> 00:15:23,370
+ولا موجبة؟
+
+156
+00:15:25,860 --> 00:15:30,920
+يبقى المعادلة هذه معادلة مين؟ معادلة الأولى
+
+157
+00:15:30,920 --> 00:15:37,060
+أزحناها جهة اليمين بمقدار H وإلى أسفل بمقدار K
+
+158
+00:15:37,060 --> 00:15:42,520
+يبقى مين من المعادلات الأربعة اللي عندنا هذه؟بصير
+
+159
+00:15:42,520 --> 00:15:47,700
+المعادلة الأولى باس بالزايد كيف؟ كالتالي بصير
+
+160
+00:15:47,700 --> 00:15:53,660
+معادلة هذا المنحنى اللي احنا راسمينه هي X ماقص H
+
+161
+00:15:53,660 --> 00:16:03,000
+لكل تربيع يساوي 4TY ناقص K طب K هنا سالبة صح ولا
+
+162
+00:16:03,000 --> 00:16:09,060
+لأ؟ يبقى Y زائد K بالشكل اللي عندنا هذا ليش؟ لأن
+
+163
+00:16:09,060 --> 00:16:15,460
+هذه K مسافة سالبة وهذه بده يخليها ناقص K بالشكل
+
+164
+00:16:15,460 --> 00:16:16,100
+اللي عندنا
+
+165
+00:16:20,220 --> 00:16:27,480
+طب لو كانت ال H ثالثة بيصير X زائد H لكل تربية و
+
+166
+00:16:27,480 --> 00:16:32,020
+هكذا حد اللي هو يتساؤل قبل أن ندخل إلى الأمثلة على
+
+167
+00:16:32,020 --> 00:16:33,720
+ال Parabola
+
+168
+00:16:37,410 --> 00:16:44,410
+شو ديركشن هذا؟ ديركتركس ماله؟ بده يزل، بده يضل على
+
+169
+00:16:44,410 --> 00:16:50,450
+نفس البعد تبع الفوكر وعناضي أنفلة توضيحية بعد قليل
+
+170
+00:16:50,450 --> 00:16:55,330
+للمسائل العادية ومسائل ب shift و بدون shift يبقى
+
+171
+00:16:55,330 --> 00:16:59,910
+أول مثال بيقول مارأتي examples
+
+172
+00:17:10,650 --> 00:17:28,050
+Find the vertex focus وكذلك Axes وDirectrix
+
+173
+00:17:34,420 --> 00:17:44,640
+Each of the following parabolas
+
+174
+00:17:44,640 --> 00:17:50,960
+نمرة
+
+175
+00:17:50,960 --> 00:18:01,500
+A Y تربيع يساوي ناقص تمانية X نمرة B تمانية Y
+
+176
+00:18:02,550 --> 00:18:11,090
+تمانية Y بديه تساوي X تربيع زائد ستة X زائد
+
+177
+00:18:11,090 --> 00:18:18,990
+سبعتاشر solution نمر
+
+178
+00:18:18,990 --> 00:18:26,620
+ايه؟ شوف يا سيديبادئي بتقلع للمعاملة ويه تربية
+
+179
+00:18:26,620 --> 00:18:32,360
+ناقص تمانية X بادئي بتذكر مين من الرسمات الأربع
+
+180
+00:18:32,360 --> 00:18:38,730
+ويه تربية طبعا عندي اخر رسمتينالإشارة هنا من؟
+
+181
+00:18:38,730 --> 00:18:44,270
+بالصالب يبقى الرسمة من؟ الأخيرة لأن هذه هي الرسمة
+
+182
+00:18:44,270 --> 00:18:50,470
+بس بدي أعرف مقدار P بطلع في المعادلة هذه نفس شكل
+
+183
+00:18:50,470 --> 00:18:56,370
+المعادلة هذه إذا أربعة P هذه بتساوي كده؟ تمانية
+
+184
+00:18:56,370 --> 00:19:03,310
+يبقى هنا عندنا أربعة P تساوي تمانية إذا P تساوي
+
+185
+00:19:03,310 --> 00:19:10,840
+كده؟إتنين تمام تمام بدنا نروح نرسم الرسم هذه ونحدد
+
+186
+00:19:10,840 --> 00:19:15,540
+عليها الشغلات هذه فباجي بقول لو كان هذول المحاور
+
+187
+00:19:15,540 --> 00:19:21,780
+هذا محور X هذا محور Y وهكذا الفرابولة بالشكل اللي
+
+188
+00:19:21,780 --> 00:19:27,660
+عندنا هذاالان P ب 2 يبقى صارت بالشكل اللي عندنا
+
+189
+00:19:27,660 --> 00:19:34,100
+هذا يبقى اليحداتي تبعها سالي ب 2 و 0 و ال vertex
+
+190
+00:19:34,100 --> 00:19:39,600
+هي نقطة الأصل كما هي لم تتغير ندى نشوف المطلوب
+
+191
+00:19:39,600 --> 00:19:44,140
+الأول المطلوب الأول قال يهاتل ال vertex يبقى ال
+
+192
+00:19:44,140 --> 00:19:51,840
+vertex 00 لم تتغيرفبروح بقوله هنا the vertex is
+
+193
+00:19:51,840 --> 00:19:59,760
+the origin اللي هي zero zero المطلب التاني قاللي
+
+194
+00:19:59,760 --> 00:20:06,340
+هاتلي من ال focus البقرة يبقى باجي بقوله هنا the
+
+195
+00:20:06,340 --> 00:20:14,510
+focusis سالي باتنين وزيرو بعد ال focus جالي هات لل
+
+196
+00:20:14,510 --> 00:20:21,370
+axis بروح بقوله هنا the axis is اللي هم هنا يا
+
+197
+00:20:21,370 --> 00:20:29,250
+شباب محور X اللي معدلته Y تساوي زيرو is Y تساوي
+
+198
+00:20:29,250 --> 00:20:35,660
+زيرو اللي هو ال X axisخلصنا النقطة التالتة النقطة
+
+199
+00:20:35,660 --> 00:20:39,140
+الرابعة قال لي هات لمين ال directrix يبقى ال
+
+200
+00:20:39,140 --> 00:20:44,540
+directrix وين بدي ييجي في الخلف شكل اللي عندنا ده
+
+201
+00:20:44,540 --> 00:20:50,620
+معادلة x يساوي اتنين يبقى هذه المسافة جد المسافة
+
+202
+00:20:50,620 --> 00:20:55,960
+هذه اتنين اذا هذه اتنين يبقى باجي بقوله هنا the
+
+203
+00:20:55,960 --> 00:21:04,900
+directrix is x يساوي اتنينيبقى هذه أبسط أنواع
+
+204
+00:21:04,900 --> 00:21:10,600
+المسائل اللي عندنا نيجي للسؤال الثاني لو اطلعنا
+
+205
+00:21:10,600 --> 00:21:15,740
+للسؤال الثاني نمرة B بنلاحظ انه بدي اختلف كليا عن
+
+206
+00:21:15,740 --> 00:21:22,160
+مين عن نمرة A ايش وجه الاختلاف ففكري بيجي عندي ان
+
+207
+00:21:22,160 --> 00:21:27,060
+اعمل اكمال للمربع جداش هذي بدها مشان أصير مربع
+
+208
+00:21:27,060 --> 00:21:31,710
+كامل؟تسعة زي اللي موجودة من عند الجيران بناخدها من
+
+209
+00:21:31,710 --> 00:21:36,750
+عندهم تسعة مقدر أخدها من السبعتاشر بضل قداش زي
+
+210
+00:21:36,750 --> 00:21:41,960
+التسعة زي التمانيةطب التمانية نقولها لي على الشجة
+
+211
+00:21:41,960 --> 00:21:48,060
+التانية بصير تمانية Y ناقص تمانية يساوي X تربية
+
+212
+00:21:48,060 --> 00:21:55,320
+زائد ستة X زائد تسعة وإن شئتم فقولوا هاي تمانية
+
+213
+00:21:55,320 --> 00:22:01,980
+عامل مشترك بيظل Y ناقص واحد بديه يساوي مين؟ بديه
+
+214
+00:22:01,980 --> 00:22:11,480
+يساوي X زائد تلاتة لكل تربيةيبقى صارت كإنها X
+
+215
+00:22:11,480 --> 00:22:18,500
+تربيع يساوي أربعة PY، مصدور؟ بس العمل اللي هي
+
+216
+00:22:18,500 --> 00:22:22,680
+shift باجي بقول ال vertex على طول الخط
+
+217
+00:22:29,220 --> 00:22:35,720
+جد ال H دائما مع X كي دائما مع Y يبقى ال H هنا
+
+218
+00:22:35,720 --> 00:22:42,640
+عندى بقدرش سالب تلاتة وال Y بقدرش واحد تمام بدى
+
+219
+00:22:42,640 --> 00:22:49,220
+الأربعة P تسوى جداش عندى هنا تمام تمانية تمانية
+
+220
+00:22:49,220 --> 00:22:55,160
+تعني ان P تسوى جداش اتنىالان عشان اجيب الباقي
+
+221
+00:22:55,160 --> 00:23:00,680
+بالضروح ارسم الرسمة يبقى باقي بقوله هذا الرسمة
+
+222
+00:23:00,680 --> 00:23:06,740
+اللي عندنا، هذا محور X، هذا محور Y، هذه نقطة الأصل
+
+223
+00:23:06,740 --> 00:23:11,880
+اللي عندناأول شيء يجب أن نفعله هو الـ Vertex الـ
+
+224
+00:23:11,880 --> 00:23:16,780
+Vertex جداش عنا سالب تلاتة واحد يبقى بإننا نتحرك
+
+225
+00:23:16,780 --> 00:23:23,360
+جهة الشمال بسالب تلاتة و نقلع فوق بمقدار الواحد
+
+226
+00:23:23,360 --> 00:23:30,070
+يبقى هذه النقطة ليه سالب تلاتة واحد بعد هيكبنتشوف
+
+227
+00:23:30,070 --> 00:23:35,610
+هل ال parabola مفتوح لليمين، لليشمال، إلى أعلى،
+
+228
+00:23:35,610 --> 00:23:40,490
+إلى أسفل، برجع للمعادلة وين المعادلة هيها؟ الحمد
+
+229
+00:23:40,490 --> 00:23:45,270
+لله ماعناش سالب، يبقى بالموجب، إذا مفتوحة إما جهة
+
+230
+00:23:45,270 --> 00:23:50,370
+اليمين أو إلى أعلى لإنه ماعنديش سالب، بعدين بفطلع،
+
+231
+00:23:50,370 --> 00:23:57,170
+هذه في الأصل X تربية يساوي أربعة PYمفتوح إلى أعلى
+
+232
+00:23:57,170 --> 00:24:02,430
+يبقى المنحلة هيكون مفتوح إلى أعلى بالشكل اللي
+
+233
+00:24:02,430 --> 00:24:07,770
+عندنا هذا طبعا فبقى مفتوح إلى أعلى يبقى ال axis
+
+234
+00:24:07,770 --> 00:24:15,470
+بدي يكون هذا هو ال axis نغري مباشرةطيب إذا إحنا
+
+235
+00:24:15,470 --> 00:24:22,210
+جبناله مين؟ جبناله ال vertex، الآن بقوله the axis
+
+236
+00:24:22,210 --> 00:24:31,790
+is x يسوى كده؟ سالب تلاتة، هذا هو ال axisخلصنا ال
+
+237
+00:24:31,790 --> 00:24:36,750
+vertex و ال axis، ضال ال focus و ال directrix ال P
+
+238
+00:24:36,750 --> 00:24:43,730
+طلعناها بقداش؟ 2 P هي المسافة من ال vertex لغاية
+
+239
+00:24:43,730 --> 00:24:50,710
+ال focus، تمام؟ المسافة هذه كلها اللي هو B2إذا
+
+240
+00:24:50,710 --> 00:24:56,470
+أصبح الاحداثي التابعها هو السالب تلاتة زي ما هو،
+
+241
+00:24:56,470 --> 00:25:02,550
+بضل راسي هذا قداش و هذا قداش، نعم، يبقى بصير قداش
+
+242
+00:25:02,550 --> 00:25:11,250
+تلاتة، يبقى بروح بقوله the focus is سالب تلاتة و
+
+243
+00:25:11,250 --> 00:25:17,830
+تلاتة، شو ضايل عنده؟directors ممتاز جدا يبقى ال
+
+244
+00:25:17,830 --> 00:25:22,150
+directors عمودي على ال axis ويبقى عن ال vertex
+
+245
+00:25:22,150 --> 00:25:28,170
+مسافة مقدرها اتنين هذا كدهش اذا مضي عزل كمان كدهش
+
+246
+00:25:28,170 --> 00:25:34,230
+كمان واحد يبقى بده يجينا هذا ايه؟ هذا هو ال
+
+247
+00:25:34,230 --> 00:25:44,170
+directrix المسافة هذه كلها اللي هو كم؟ باتنينتمام؟
+
+248
+00:25:44,170 --> 00:25:48,350
+المسافة هذه عفوا، المسافة هذه بواحد لإن المسافة
+
+249
+00:25:48,350 --> 00:25:53,390
+اللي فوق كمان هذه بمين هي بواحد طب هذا واحد بس تحت
+
+250
+00:25:53,390 --> 00:25:59,430
+ال X axis إذا بالمعادلة تبعته بتبقى جداش Y يساوي
+
+251
+00:25:59,430 --> 00:26:07,710
+سالب واحد بروح بقوله هنا the biometrics is Y تساوي
+
+252
+00:26:07,710 --> 00:26:14,840
+مين سالب واحد انتهى المطلوب كلهطيب هذا النوع الأول
+
+253
+00:26:14,840 --> 00:26:20,460
+من المثال نذهب إلى النوع الثاني النوع الثاني بيقول
+
+254
+00:26:20,460 --> 00:26:32,580
+consider the Parabola تكستر
+
+255
+00:26:32,580 --> 00:26:38,320
+بيع بده يساوي ستة Y that shifted
+
+256
+00:26:43,800 --> 00:26:50,640
+عملنا لها shift مقدرة تلاتة units تلاتة وحدات
+
+257
+00:26:50,640 --> 00:26:58,680
+تلاتة units to the left تلاتة
+
+258
+00:26:58,680 --> 00:27:09,480
+وحدات جهة اليسار and two units واحدتين down إلى
+
+259
+00:27:09,480 --> 00:27:10,280
+أسفل
+
+260
+00:27:20,940 --> 00:27:24,700
+اكتشف المعادلة الجديدة
+
+261
+00:27:43,510 --> 00:27:51,670
+focus و ال vertex و
+
+262
+00:27:51,670 --> 00:27:56,510
+ال axis و المحور and directrix
+
+263
+00:28:28,890 --> 00:28:33,470
+سؤال مرة ثانيةبقول اعتبر ال parabola x ترميها
+
+264
+00:28:33,470 --> 00:28:40,390
+بساوي 6y بعدين that shifted عملنا لها إزاحة تلت
+
+265
+00:28:40,390 --> 00:28:46,920
+وحدات جهة وين؟ جهة الشمالو وحدتين الى أسفل يبقى
+
+266
+00:28:46,920 --> 00:28:50,680
+الشفات ديما موحلة جهة الشمال تلات وحدات و وحدتين
+
+267
+00:28:50,680 --> 00:28:55,500
+الى أسفل بيقول اكتبلي المعادلة جديدة لل Parabola
+
+268
+00:28:55,500 --> 00:29:00,740
+بعد ما عملتلها main ال shift and find its focus و
+
+269
+00:29:00,740 --> 00:29:04,320
+وقت ال focus و ال vertex و ال axis و ال directrix
+
+270
+00:29:04,500 --> 00:29:08,880
+يبقى كل المعلومات الخاصة بمين بهذه ال parabola
+
+271
+00:29:08,880 --> 00:29:13,820
+بنقولها بسيطة يبقى أول شغلة بدنا نعملها بنقول هذا
+
+272
+00:29:13,820 --> 00:29:19,100
+محور X هذا Y هذا هو ال zero بدي ال parabola
+
+273
+00:29:19,100 --> 00:29:25,340
+الأصلية بتطلع في شكل المعادلة X تربيع يسوى 6 يبقى
+
+274
+00:29:25,340 --> 00:29:29,240
+المركزة النقطة الأصلية مفتوحة إلى أين؟ إلى أعلى
+
+275
+00:29:29,240 --> 00:29:35,900
+يبقى هذا ال parabola اللي عندنا بالشكل هذاالان
+
+276
+00:29:35,900 --> 00:29:41,480
+عملنا لها إزاحة جهة الشمال بمقدار تلت وحدات يبقى
+
+277
+00:29:41,480 --> 00:29:46,180
+جبنة على البراميل هذه وعملنا لها إزاحة بمقدار تلت
+
+278
+00:29:46,180 --> 00:29:51,720
+وحدات يبقى هذا النقطة كده؟ سالب تلتة يبقى كأنها
+
+279
+00:29:51,720 --> 00:29:57,220
+أصبحت بالشكل اللي عندنا هذا تمام؟ بعدين نزلناها
+
+280
+00:29:57,220 --> 00:30:03,600
+إلى أسفل بمقدار وحدتينيبقى جينا نزلنا هنا مقدار
+
+281
+00:30:03,600 --> 00:30:09,280
+واحد اتنين صار هذا سالب تلاتة وسالب اتنين يبقى
+
+282
+00:30:09,280 --> 00:30:14,420
+نزلنا رسمتنا الى اسفل بمقدار سالب تلاتة وسالب
+
+283
+00:30:14,420 --> 00:30:19,400
+اتنين فصار ال parabola هو الخط الأزرق اللى عندنا
+
+284
+00:30:19,400 --> 00:30:26,550
+هذا طيب تمام قل لياكتبلي المعادلة الجديدة، بعدين
+
+285
+00:30:26,550 --> 00:30:35,010
+بقول بسيطة المعادلة X ناقص او بعدين بقول the new
+
+286
+00:30:35,010 --> 00:30:46,870
+equation of the parabola isالـ X عملنا shift جهة
+
+287
+00:30:46,870 --> 00:30:53,130
+الشمال بمقدار سالم 13 بالصغير زائد 3 لكل تربيع
+
+288
+00:30:53,130 --> 00:31:02,190
+يسوى 6Y ناقص ناقص 2 يعني زائد 2 يبقى هذه المعادلة
+
+289
+00:31:02,190 --> 00:31:08,550
+الجديدة لمن؟ للبرابل اللي طلبها قال لي خد البرابل
+
+290
+00:31:08,550 --> 00:31:14,370
+اعملك اكتبلي المعادلة الجديدةهات لل focus و ال
+
+291
+00:31:14,370 --> 00:31:19,370
+vertex و ال axis و كل ما يلزم باجي بقوله the
+
+292
+00:31:19,370 --> 00:31:28,790
+vertex is قداش ال vertex شباب H و K سالب تلاتة و
+
+293
+00:31:28,790 --> 00:31:34,160
+سالب اتنينبنروح نجيب ال focus مشان نجيب ال focus
+
+294
+00:31:34,160 --> 00:31:40,740
+بدنا P يبقى باجي بقول نرجع للمثلة احنا عندنا اربعة
+
+295
+00:31:40,740 --> 00:31:47,320
+P يساوي كده؟ يساوي ستة ومنها P تساوي كده؟ تلاتة
+
+296
+00:31:47,320 --> 00:31:52,520
+على اتنين يعني واحد ونص اذا بدنا نيجي نطلع هذه
+
+297
+00:31:52,520 --> 00:31:58,820
+المسافة كلها كده؟هذه المسافة كل اتنين، وما نطلع
+
+298
+00:31:58,820 --> 00:32:04,220
+واحد ونص يعني بدنا نوصل لهنا، يبقى المسافة الصغيرة
+
+299
+00:32:04,220 --> 00:32:10,480
+كلها هذه كم؟ طولها يساوي نص، إذا الإحداث يتبع هذه
+
+300
+00:32:10,480 --> 00:32:17,500
+النقطة هو كم؟ سالب تلاتة، ما تغيرشه، سالب نصاذا
+
+301
+00:32:17,500 --> 00:32:26,320
+الـ automatic بروح بقوله the focus is اللغمين سالب
+
+302
+00:32:26,320 --> 00:32:33,680
+تلاتة وسالب نصيبقى جيبناه ال vertex اللي جال عليها
+
+303
+00:32:33,680 --> 00:32:38,820
+ها و ال focus جال اللي هات لل axis ال axis هو الخط
+
+304
+00:32:38,820 --> 00:32:46,380
+اللي عندنا، ده جديش ال axis ال axis is ال x يساوي
+
+305
+00:32:46,380 --> 00:32:51,190
+سالم ثلاثة بقى اللي عندنا بس مين؟الـ Directrix
+
+306
+00:32:51,190 --> 00:32:57,290
+يبقى الـ Directrix بدي أنزل هنا تحت مسافة مقدرها
+
+307
+00:32:57,290 --> 00:33:02,910
+اتنين و واحدة و نص، تمام؟ يعني المسافة هذه كمان
+
+308
+00:33:02,910 --> 00:33:10,150
+تلاتة على اتنين لإن المسافة هذه كلها ليه تلاتة على
+
+309
+00:33:10,150 --> 00:33:15,150
+اتنين؟ شوف يا سيديالان بدي اجيب معادلة ال
+
+310
+00:33:15,150 --> 00:33:21,810
+directrix يبقى هذا هو directrix طلعلي كويس هنا
+
+311
+00:33:21,810 --> 00:33:28,970
+المسافة هذه كلها جداش نان والمسافة هذه واحد و نص،
+
+312
+00:33:28,970 --> 00:33:33,490
+يبقى جداش بصير ثلاثة و نص يعني سبعة على تن باس
+
+313
+00:33:33,490 --> 00:33:37,270
+بإشارة فبروح بقوله هنا Z
+
+314
+00:33:39,870 --> 00:33:50,090
+بايركتريكس is ويساوي سالب تلاتة على اتنين ويساوي
+
+315
+00:33:50,090 --> 00:33:57,870
+سالب سبعة على اتنين هذا هو معادلة من البايركتريكس
+
+316
+00:34:02,890 --> 00:34:11,510
+طيب نذهب للسؤال الذي يليه مثال رقم تلاتة بيقول
+
+317
+00:34:11,510 --> 00:34:15,770
+find the equation of the parabola find the
+
+318
+00:34:15,770 --> 00:34:24,490
+equation of the parabola بدنا معادلة ال parabola
+
+319
+00:34:24,490 --> 00:34:25,690
+with
+
+320
+00:34:29,190 --> 00:34:40,870
+Vertex تلاتة وسالب خمسة And directrix ومعادلته
+
+321
+00:34:40,870 --> 00:34:47,830
+الدليل X بده يساوي اتنين X بده يساوي اتنين Find
+
+322
+00:34:47,830 --> 00:34:49,250
+its focus and axis
+
+323
+00:35:26,880 --> 00:35:32,600
+قال لي هاتلي معادلة ال Parabola with vertex تلاتة
+
+324
+00:35:32,600 --> 00:35:38,780
+و سالب خمسة يبقى عطار يمينبعد ذلك قال لي Direct X
+
+325
+00:35:38,780 --> 00:35:44,260
+يساوي 8 إذا بدي بسأل لما لاجي ال vertex رقامين هكي
+
+326
+00:35:44,260 --> 00:35:47,700
+بمعمول و shift و لا مش معمول بقول ان ال vertex
+
+327
+00:35:47,700 --> 00:35:52,400
+الاصلية 00 تغيرت بمعمول و shift شو شكله الله أعلم
+
+328
+00:35:53,100 --> 00:35:56,820
+قال لي هاتلي كمية البورة تبع ثمان و ال access يبقى
+
+329
+00:35:56,820 --> 00:36:01,600
+أول شغلة بدي أعملها بدي أروح أرسم و أشوف كيف بدي
+
+330
+00:36:01,600 --> 00:36:06,200
+أسير معاه يبقى انا لو جيت للمحاور و روحت قولت هذه
+
+331
+00:36:06,200 --> 00:36:11,760
+المحاور اللي عندنا هذا محور X هذا Y هذا نقطة الاصل
+
+332
+00:36:11,760 --> 00:36:17,140
+بدي أجي ال vertex بدي أمشي هنا تلاتة و أنزل هنا
+
+333
+00:36:17,140 --> 00:36:24,050
+قداشرسالب خمسة يبقى هذه النقطة تلاتة و سالب خمسة
+
+334
+00:36:24,050 --> 00:36:30,490
+تمام؟ يبقى هذه هي ال vertex مفتوح يمين شمال فوق
+
+335
+00:36:30,490 --> 00:36:35,790
+تحت الله أعلم اللي بده يحكم هذا الكلام ال axis ال
+
+336
+00:36:35,790 --> 00:36:41,910
+axis بيقول X يساوي اتنينبجي بقولك كويس هذا X يساوي
+
+337
+00:36:41,910 --> 00:36:46,530
+تلاتيك ب X يساوي اتنين جابله ودي يكون صحيح ولا لأ؟
+
+338
+00:36:46,530 --> 00:36:55,090
+اذا هذا الخط هاج اللي هو مين؟ X يساوي اتنين لأن
+
+339
+00:36:55,090 --> 00:37:00,970
+هذا Zero هذا ال directrix يبدي يكون وين؟إذا أعلى،
+
+340
+00:37:00,970 --> 00:37:04,350
+بدّي أقعد دائرة 6، وإذا أسفل، بدّي أقعد دائرة 9،
+
+341
+00:37:04,350 --> 00:37:07,250
+وإذا أشمال، بدّي أقعد دائرة 9، إذا مافيش إمكانية
+
+342
+00:37:07,250 --> 00:37:13,030
+إلا جهة اليمين، يبقى جهة اليمين بدّي يكون بالشكل
+
+343
+00:37:13,030 --> 00:37:19,010
+اللي عندنا هذا، يبقى هي رسمنا شكل البرابولة بهذا
+
+344
+00:37:19,010 --> 00:37:25,220
+الشكلنجلشو اللي مطلوب جالي هاتلي المعادلة تبعته
+
+345
+00:37:25,220 --> 00:37:30,460
+بقول له هذا مفتوح جهة اليمين ومعموله shift يبقى
+
+346
+00:37:30,460 --> 00:37:33,140
+الأصل تبع المعادلة هي
+
+347
+00:37:38,510 --> 00:37:45,930
+نقص كل كل تربيع يبدو يساوي مفتوح جهة اليمين يبقى
+
+348
+00:37:45,930 --> 00:37:54,290
+اربعة P X نقص ال H بدنا نعوض فيها يبقى Y نقص K
+
+349
+00:37:54,290 --> 00:38:01,770
+عندنا مايبدواش سالب خمسة يبقى زائب خمسة الكل تربيع
+
+350
+00:38:01,770 --> 00:38:07,900
+يبدو يساوي اربعة كي جداش P الله أعلم نحسبهايبقى
+
+351
+00:38:07,900 --> 00:38:16,500
+بيبقى لأنه من؟ X ماقص تلاتة طيب هذه المسافة كلها
+
+352
+00:38:16,500 --> 00:38:23,440
+من هنا لهنا كده شباب؟ تلاتة هذه بتروح منها من هنا
+
+353
+00:38:23,440 --> 00:38:29,280
+لهنا اتنين بتبقى المسافة هذه كده؟ واحد يبقى اصبحت
+
+354
+00:38:29,280 --> 00:38:36,180
+P تساوي واحد يبقى باجي بقوله P تساوي تلاتة ناقص
+
+355
+00:38:36,180 --> 00:38:43,060
+اتنينيساوي واحد يبقى ال equation هذه بيصير y زائد
+
+356
+00:38:43,060 --> 00:38:50,300
+خمسة لكل تربية يساوي اربعة x ناقص ثلاثة هذا الشكل
+
+357
+00:38:50,300 --> 00:38:56,030
+المعادلة المطلوبة اللي هو المطلوب الأولجاليات
+
+358
+00:38:56,030 --> 00:39:01,610
+للبقرة، بقول للبقرة بسيطة، يبقى بدنا نتحرك جهة
+
+359
+00:39:01,610 --> 00:39:07,690
+اليمين بمقدار كده؟ مقدار واحد، يبقى هذه بدنا
+
+360
+00:39:07,690 --> 00:39:15,960
+نشيلها من هناكاللي قلنا هي هذه النقطة اللي هي
+
+361
+00:39:15,960 --> 00:39:22,920
+تلاتة وسالب خمسة البورة بدها تيجي هنا في الداخل
+
+362
+00:39:22,920 --> 00:39:25,900
+يبقى المسافة هذه كمان قداش
+
+363
+00:39:30,680 --> 00:39:38,140
+أربعة يبقى بده يصير أربعة و سالب خمسة كما هي شكل
+
+364
+00:39:38,140 --> 00:39:41,300
+انها. فبروح بقوله they focus
+
+365
+00:39:44,540 --> 00:39:50,940
+is أربعة و سالب خمسة بعد ال focus قال هاتلي كمان
+
+366
+00:39:50,940 --> 00:39:56,620
+main ال axis واضح ال axis ان هو يساوي سالب خمسة
+
+367
+00:39:56,620 --> 00:40:04,320
+بعدين بقوله ان ال axis هو Y تساوي سالب خمسة
+
+368
+00:40:18,600 --> 00:40:26,860
+بنجي الآن لنمره اتنين اللي هو ال ellipse القطع
+
+369
+00:40:26,860 --> 00:40:30,800
+الناقص يبقى
+
+370
+00:40:30,800 --> 00:40:36,680
+ال ellipse المعادلة تبعته X تربية علي A تربية زي Y
+
+371
+00:40:36,680 --> 00:40:42,560
+تربية علي B تربية يساوي 1 بدنا نعرف وين ال A وين
+
+372
+00:40:42,560 --> 00:40:48,050
+ال B هذا وين شكلهبنقول له اه هي المحاور بالشكل
+
+373
+00:40:48,050 --> 00:40:53,950
+اللي عندنا هذا هذا محور X هذا Y هذه نقطة الاصلي هو
+
+374
+00:40:53,950 --> 00:41:01,850
+Zero يبقى ال الورس بالشكل اللي عندنا هذا هيك كويس؟
+
+375
+00:41:01,850 --> 00:41:08,110
+المسافة من نقطة الأصل إلى ال vertex هذه بدي أسميها
+
+376
+00:41:08,110 --> 00:41:15,120
+A يبقى أحداثيات النقطة هذه A و Zeroإحداثيات النقطة
+
+377
+00:41:15,120 --> 00:41:24,460
+هذه سالب a و zero إذا هنا بحط كبار فاصلة ال a أكبر
+
+378
+00:41:24,460 --> 00:41:30,550
+من bيعني المقام اللي هنا أكبر من المقام اللي هنا
+
+379
+00:41:30,550 --> 00:41:36,650
+طب لو حصل غير هيك إلا كلام تاني سنعرفه بعد قليل زي
+
+380
+00:41:36,650 --> 00:41:41,810
+ما أنت شايف فيه محور كبير وفيه محور صغير يبقى
+
+381
+00:41:41,810 --> 00:41:46,970
+المحور الكبير بسميه ال major axis يبقى هذا هذا
+
+382
+00:41:46,970 --> 00:41:56,790
+بسميه ال major axis المحور الرئيسيأو الـ polar
+
+383
+00:41:56,790 --> 00:42:05,730
+axis المحور القطبي هذا الصغير بسميه الـ minor axis
+
+384
+00:42:05,730 --> 00:42:11,050
+زي ما أخدنا إحداثيات النقطتين هدول بدنا نيجي
+
+385
+00:42:11,050 --> 00:42:18,350
+لإحداث النقطة هذه Zero و B هذه النقطة Zero و سالب
+
+386
+00:42:18,350 --> 00:42:18,650
+B
+
+387
+00:42:21,630 --> 00:42:32,690
+يبقى المسافة من Zero إلى النقطة هذه اللي هي نصف
+
+388
+00:42:32,690 --> 00:42:38,590
+المحور الرئيسي نصف
+
+389
+00:42:38,590 --> 00:42:44,780
+المحور الثانوأيوة هذا يا شباب لو جاءت قصته من
+
+390
+00:42:44,780 --> 00:42:49,360
+المصر بصير كأنه two parabolas و اتنين موجهين على
+
+391
+00:42:49,360 --> 00:42:54,580
+بعض صحيح؟ يعني معناته في يعني كام بُقرة تين تين
+
+392
+00:42:54,580 --> 00:42:58,080
+يبقى هذا بالفعل على ال parabola انه يلو بُقرتين و
+
+393
+00:42:58,080 --> 00:43:04,960
+ليست بُقرة واحدة هذه البُقرة الأولى وهذه لو كانت
+
+394
+00:43:04,960 --> 00:43:11,750
+البُقرة الثانية يبقى هذه بدي أسميها F1المسافة هذه
+
+395
+00:43:11,750 --> 00:43:18,690
+لو كانت C يبقى بيصير F1 اللي هي ناقص C و Zero
+
+396
+00:43:18,690 --> 00:43:25,990
+البقرة الثانية هذي بده يسميها F2 اللي هو C و Zero
+
+397
+00:43:27,350 --> 00:43:34,170
+يبدأ صار عندنا بُقرتين وصار عندنا رأسين زي ما انت
+
+398
+00:43:34,170 --> 00:43:39,690
+شايف بالنسبة لمن؟ لـ image وفي عندنا major axis
+
+399
+00:43:39,690 --> 00:43:44,750
+وفي عندنا minor axis المعادلة تبعت وهي X تربية علي
+
+400
+00:43:44,750 --> 00:43:49,170
+A تربية زي Y تربية علي B تربية تساويوحد، طب فيه
+
+401
+00:43:49,170 --> 00:43:57,570
+عنا A وB وC، هذا من هنا لهنا A، من هنا لهنا C، من
+
+402
+00:43:57,570 --> 00:44:02,850
+هنا لهنا B، فيه علاقة بتربط فيما بينهم؟ نعم، بعد
+
+403
+00:44:02,850 --> 00:44:08,050
+ما نجيبها في ثغورث ونرسم وكذا إلى آخره، يبقى B
+
+404
+00:44:08,050 --> 00:44:14,330
+يساوي الجذر التربيه إلى A تربيه ناقص C تربيه على
+
+405
+00:44:14,330 --> 00:44:21,020
+طول القطبلو حبينا نعطيله تعريف، بنقول كل النقاط
+
+406
+00:44:21,020 --> 00:44:25,720
+اللي بتتحرك في المستوى، المحل الهندسي، لنقطة تتحرك
+
+407
+00:44:25,720 --> 00:44:33,240
+في المستوى، بعيد يكون مجموعة بعديها عن نقطتين
+
+408
+00:44:33,240 --> 00:44:40,090
+ثابتتين يسوى مقدارا ثابتايعني لو أخدت أي نقطة زي
+
+409
+00:44:40,090 --> 00:44:45,770
+النقطة هذه، البعد هذا، زي البعد هذا، زي البعد هذا،
+
+410
+00:44:45,770 --> 00:44:50,290
+مع البعد هذا و هكذا، انسى، بدنا المعادلة واللي
+
+411
+00:44:50,290 --> 00:44:56,030
+متعلقة بيها طب هذا لو كان A أكبر من B؟ طب لو كان B
+
+412
+00:44:56,030 --> 00:45:01,500
+أكبر من A؟ يرجع بده يصير المحور غامن؟المحور
+
+413
+00:45:01,500 --> 00:45:08,020
+الرئيسي هو محور Y يعني بدأ تصبح الرسمة على الشكل
+
+414
+00:45:08,020 --> 00:45:13,680
+اللي عندها هذا محور X وهذا Y وقد يصبح ال ellipse
+
+415
+00:45:13,680 --> 00:45:21,690
+بالشكل هذاوبتبقى هذه النقطة اللي هي Zero و A وهذا
+
+416
+00:45:21,690 --> 00:45:32,270
+Zero و Zero Zero و سالب A هذه النقطة B و Zero هذه
+
+417
+00:45:32,270 --> 00:45:39,610
+النقطة سالب B و Zero طب البورتين وين بدهم يجوا؟على
+
+418
+00:45:39,610 --> 00:45:46,150
+محور Y يبقى بيصير هذه إحدى البقرتين وهذه البقرة
+
+419
+00:45:46,150 --> 00:45:54,730
+الثانية يبقى هذه بدي أسميها F1 اللي هو Zero وسالب
+
+420
+00:45:54,730 --> 00:46:02,960
+C هذه F2للـ zero و الـ C يعني المسافة هذه كلها C و
+
+421
+00:46:02,960 --> 00:46:08,760
+المسافة هذه كذلك اللي هي C و نفس المعادلة هذه لن
+
+422
+00:46:08,760 --> 00:46:15,860
+تتغير طب كيف بيدميز بين الرسمتين؟ تطلع لصاحب
+
+423
+00:46:15,860 --> 00:46:20,680
+المقام الرفيع لمقامه كبير المتغير اللي من فوقه هو
+
+424
+00:46:20,680 --> 00:46:27,890
+المحور الرئيسي تمام؟ بقى كتابة مش مشكلةأكتب صاحب
+
+425
+00:46:27,890 --> 00:46:34,810
+المتغير اللي مقامه أكبر ما يمكن بيكون هو ال major
+
+426
+00:46:34,810 --> 00:46:41,610
+axis المحور الرئيسي طيب، لأ لو الرسم هذا جينا
+
+427
+00:46:41,610 --> 00:46:47,970
+عملنا له shift يبقى شو بده يصير شكل المعادلة؟ يبقى
+
+428
+00:46:47,970 --> 00:46:55,090
+F و shift the ellipse
+
+429
+00:46:59,220 --> 00:47:05,580
+لو عملنا shift ل ال ellipse then its equation is
+
+430
+00:47:07,280 --> 00:47:15,420
+هيعني بدى يصير X نقص H الكل تربية على A تربية و Y
+
+431
+00:47:15,420 --> 00:47:22,880
+نقص K الكل تربية على B تربية يساوي واحد where حيث
+
+432
+00:47:22,880 --> 00:47:33,360
+ال H والK is the center of the ellipse
+
+433
+00:47:36,360 --> 00:47:40,820
+هيبقى ياله بالصراحة علمائياتي بالنسباله، في عندك
+
+434
+00:47:40,820 --> 00:47:49,120
+center وفي عندك two vertices وفي عندك two فقاعي،
+
+435
+00:47:49,120 --> 00:47:57,390
+بُهرتينو رأسين و major axis و minor axis محور
+
+436
+00:47:57,390 --> 00:48:04,370
+ثانوي محور رئيسي رأسين بقرتين و ال center اللي هو
+
+437
+00:48:04,370 --> 00:48:07,890
+نقطة الاصل لو عملنا له shift بيبطل ال seal ال
+
+438
+00:48:07,890 --> 00:48:12,750
+center نقطة الاصل المرة الجاية بنكمل بناخد عليه
+
+439
+00:48:12,750 --> 00:48:17,070
+أمثلة و بناخد كذلك ال high parabola ان شاء الله
+
+440
+00:48:17,070 --> 00:48:17,730
+تعالى
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/YEsPw6K7LKY_raw.json b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/YEsPw6K7LKY_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..f303ca2f2b4eeda1e6e6fe70b1b0b2674485ce8e
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/YEsPw6K7LKY_raw.json
@@ -0,0 +1 @@
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9381, 9957, 281, 264, 1347, 297, 2031], "avg_logprob": -0.4709051600817976, "compression_ratio": 1.161904761904762, "no_speech_prob": 0.0, "words": [{"start": 133.92, "end": 134.24, "word": "لو", "probability": 0.742431640625}, {"start": 134.24, "end": 134.68, "word": " كانت", "probability": 0.900146484375}, {"start": 134.68, "end": 134.9, "word": " الـ", "probability": 0.532470703125}, {"start": 134.9, "end": 135.18, "word": " n", "probability": 0.2154541015625}, {"start": 135.18, "end": 136.4, "word": " is", "probability": 0.332275390625}, {"start": 136.4, "end": 137.46, "word": " a", "probability": 0.6962890625}, {"start": 137.46, "end": 138.2, "word": " positive", "probability": 0.91455078125}, {"start": 138.2, "end": 140.88, "word": " integer", "probability": 0.958984375}, {"start": 140.88, "end": 143.72, "word": " positive", "probability": 0.258056640625}, {"start": 143.72, "end": 144.68, "word": " integer", "probability": 0.9599609375}, {"start": 144.68, "end": 145.32, "word": " then", "probability": 0.44580078125}, {"start": 145.32, "end": 147.72, "word": " نمرة", "probability": 0.64892578125}, {"start": 147.72, "end": 148.32, "word": " واحد", "probability": 0.988037109375}, {"start": 148.32, "end": 149.74, "word": " integration", "probability": 0.88818359375}, {"start": 149.74, "end": 151.04, "word": " لصين", "probability": 0.5050862630208334}, {"start": 151.04, "end": 151.32, "word": " to", "probability": 0.77685546875}, {"start": 151.32, "end": 151.58, "word": " the", "probability": 0.8935546875}, {"start": 151.58, "end": 152.14, "word": " power", "probability": 0.90185546875}, {"start": 152.14, "end": 152.64, "word": " n", "probability": 0.5439453125}, {"start": 152.64, "end": 153.24, "word": " x", "probability": 0.51123046875}], "temperature": 1.0}, {"id": 8, "seek": 17420, "start": 153.9, "end": 174.2, "text": "DX يساوي سالب واحد على N Sine to the power N minus ال one X فيه Cos X زائد N minus ال one على N تكامل Sine to the power N minus اتنين X DX", 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{"start": 184.45, "end": 184.91, "word": " m", "probability": 0.54443359375}, {"start": 184.91, "end": 185.85, "word": " ل", "probability": 0.919921875}, {"start": 185.85, "end": 186.55, "word": " cosine", "probability": 0.56201171875}, {"start": 186.55, "end": 187.03, "word": " أس", "probability": 0.694580078125}, {"start": 187.03, "end": 187.35, "word": " n", "probability": 0.61083984375}, {"start": 187.35, "end": 187.81, "word": " ناقص", "probability": 0.9107666015625}, {"start": 187.81, "end": 188.29, "word": " واحد", "probability": 0.982666015625}, {"start": 188.29, "end": 188.73, "word": " x", "probability": 0.9697265625}, {"start": 188.73, "end": 189.69, "word": " sin", "probability": 0.30126953125}, {"start": 189.69, "end": 190.43, "word": " x", "probability": 0.587890625}, {"start": 190.43, "end": 191.81, "word": " زائد", "probability": 0.8595377604166666}, {"start": 191.81, "end": 192.53, "word": " n", "probability": 0.8056640625}, {"start": 192.53, "end": 193.01, "word": " ناقص", "probability": 0.9859619140625}, {"start": 193.01, "end": 193.53, "word": " واحد", "probability": 0.985595703125}, {"start": 193.53, "end": 193.85, "word": " على", "probability": 0.912109375}, {"start": 193.85, "end": 194.27, "word": " m", "probability": 0.97509765625}, {"start": 194.27, "end": 195.73, "word": " تكامل", "probability": 0.9844970703125}, {"start": 195.73, "end": 196.35, "word": " ل", "probability": 0.98046875}, {"start": 196.35, "end": 196.91, "word": " cosine", "probability": 0.740234375}, {"start": 196.91, "end": 197.39, "word": " أس", "probability": 0.986572265625}, {"start": 197.39, "end": 197.73, "word": " n", "probability": 0.9638671875}, {"start": 197.73, "end": 198.41, "word": " ناقص", "probability": 0.993408203125}, {"start": 198.41, "end": 199.11, "word": " اتنين", "probability": 0.943359375}, {"start": 199.11, "end": 199.59, "word": " x", "probability": 0.99072265625}, {"start": 199.59, "end": 200.15, "word": " dx", "probability": 0.95166015625}, {"start": 200.15, "end": 201.77, "word": " النقطة", "probability": 0.97265625}, {"start": 201.77, "end": 202.57, "word": " التالتة", "probability": 0.9619140625}], "temperature": 1.0}, {"id": 10, "seek": 23041, "start": 205.01, "end": 230.41, "text": "لتكامل تان أس ان اكس دي اكس يساوي الهمين واحد على ان ناقص واحد تان أس ان ناقص واحد اكس ناقص تكامل لتان أس ان ناقص اتنين اكس دي اكس", "tokens": [1211, 2655, 4117, 10943, 1211, 6055, 7649, 5551, 3794, 16472, 1975, 4117, 3794, 11778, 1829, 1975, 4117, 3794, 7251, 3794, 995, 45865, 2423, 16095, 9957, 36764, 24401, 15844, 16472, 8717, 995, 4587, 9381, 36764, 24401, 6055, 7649, 5551, 3794, 16472, 8717, 995, 4587, 9381, 36764, 24401, 1975, 4117, 3794, 8717, 995, 4587, 9381, 6055, 4117, 10943, 1211, 5296, 2655, 7649, 5551, 3794, 16472, 8717, 995, 4587, 9381, 1975, 2655, 1863, 9957, 1975, 4117, 3794, 11778, 1829, 1975, 4117, 3794], "avg_logprob": -0.13994140438735486, "compression_ratio": 2.2211538461538463, "no_speech_prob": 0.0, "words": 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ان", "probability": 0.90673828125}, {"start": 227.25, "end": 228.29, "word": " ناقص", "probability": 0.996826171875}, {"start": 228.29, "end": 228.99, "word": " اتنين", "probability": 0.9742431640625}, {"start": 228.99, "end": 229.65, "word": " اكس", "probability": 0.98828125}, {"start": 229.65, "end": 229.95, "word": " دي", "probability": 0.986572265625}, {"start": 229.95, "end": 230.41, "word": " اكس", "probability": 0.9861653645833334}], "temperature": 1.0}, {"id": 11, "seek": 25858, "start": 231.35, "end": 258.59, "text": "النقطة الرابعة والاخيرة integration ل sin to the power n x cosine to the power m x في dx بده يساوي سالب sin cos n minus one x cosine m plus one x على مين على n زائد ال m", "tokens": [6027, 1863, 47432, 3660, 34892, 16758, 27884, 16070, 47283, 48923, 10980, 5296, 3343, 281, 264, 1347, 297, 2031, 23565, 281, 264, 1347, 275, 2031, 8978, 30017, 47525, 3224, 7251, 3794, 995, 45865, 8608, 6027, 3555, 3343, 3792, 297, 3175, 472, 2031, 23565, 275, 1804, 472, 2031, 15844, 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"probability": 0.8193359375}, {"start": 246.97, "end": 247.49, "word": " cos", "probability": 0.08056640625}, {"start": 247.49, "end": 247.85, "word": " n", "probability": 0.88037109375}, {"start": 247.85, "end": 248.39, "word": " minus", "probability": 0.83935546875}, {"start": 248.39, "end": 248.87, "word": " one", "probability": 0.65234375}, {"start": 248.87, "end": 249.43, "word": " x", "probability": 0.9873046875}, {"start": 249.43, "end": 250.27, "word": " cosine", "probability": 0.94140625}, {"start": 250.27, "end": 250.87, "word": " m", "probability": 0.8955078125}, {"start": 250.87, "end": 251.51, "word": " plus", "probability": 0.97314453125}, {"start": 251.51, "end": 252.19, "word": " one", "probability": 0.93994140625}, {"start": 252.19, "end": 253.47, "word": " x", "probability": 0.978515625}, {"start": 253.47, "end": 254.27, "word": " على", "probability": 0.638671875}, {"start": 254.27, "end": 254.87, "word": " مين", "probability": 0.70361328125}, {"start": 254.87, "end": 255.73, "word": " على", "probability": 0.473876953125}, {"start": 255.73, "end": 256.43, "word": " n", "probability": 0.90087890625}, {"start": 256.43, "end": 257.71, "word": " زائد", "probability": 0.900390625}, {"start": 257.71, "end": 258.01, "word": " ال", "probability": 0.865234375}, {"start": 258.01, "end": 258.59, "word": " m", "probability": 0.69921875}], "temperature": 1.0}, {"id": 12, "seek": 28476, "start": 259.54, "end": 284.76, "text": "زائد n ناقص واحد على n زائد ال m integration لمن لل sin أس n ناقص اتنين x cosine أس m x dx وبشرط أن ال n لا تساوي سالب m example", "tokens": [11622, 16373, 3215, 297, 8717, 995, 4587, 9381, 36764, 24401, 15844, 297, 30767, 16373, 3215, 2423, 275, 10980, 5296, 27842, 24976, 3343, 5551, 3794, 297, 8717, 995, 4587, 9381, 1975, 2655, 1863, 9957, 2031, 23565, 5551, 3794, 275, 2031, 30017, 46599, 46309, 9566, 14739, 2423, 297, 20193, 6055, 3794, 995, 45865, 8608, 6027, 3555, 275, 1365], "avg_logprob": -0.31853070175438597, "compression_ratio": 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277.24, "word": " أن", "probability": 0.43701171875}, {"start": 277.24, "end": 277.5, "word": " ال", "probability": 0.91748046875}, {"start": 277.5, "end": 277.96, "word": " n", "probability": 0.79931640625}, {"start": 277.96, "end": 278.92, "word": " لا", "probability": 0.68701171875}, {"start": 278.92, "end": 279.98, "word": " تساوي", "probability": 0.9697265625}, {"start": 279.98, "end": 280.96, "word": " سالب", "probability": 0.9415690104166666}, {"start": 280.96, "end": 281.44, "word": " m", "probability": 0.8037109375}, {"start": 281.44, "end": 284.76, "word": " example", "probability": 0.7177734375}], "temperature": 1.0}, {"id": 13, "seek": 30970, "start": 289.62, "end": 309.7, "text": "يحسبلي the following integrals تكاملات التالية تكامل الأول integration ل 10 أُس 6x dx", "tokens": [1829, 5016, 35457, 20292, 264, 3480, 3572, 1124, 6055, 4117, 10943, 1211, 9307, 16712, 6027, 10632, 6055, 4117, 10943, 1211, 16247, 12610, 10980, 5296, 1266, 5551, 10859, 3794, 1386, 87, 30017], 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"word": " the", "probability": 0.8994140625}, {"start": 365.7, "end": 366.22, "word": " power", "probability": 0.890625}, {"start": 366.22, "end": 366.78, "word": " N", "probability": 0.397216796875}, {"start": 366.78, "end": 367.58, "word": " DX", "probability": 0.5625}, {"start": 367.58, "end": 368.92, "word": " وطلعت", "probability": 0.7479248046875}, {"start": 368.92, "end": 369.38, "word": " يومها", "probability": 0.9519856770833334}, {"start": 369.38, "end": 369.78, "word": " X", "probability": 0.955078125}, {"start": 369.78, "end": 370.12, "word": " لان", "probability": 0.8486328125}, {"start": 370.12, "end": 370.38, "word": " X", "probability": 0.8408203125}, {"start": 370.38, "end": 370.54, "word": " to", "probability": 0.91259765625}, {"start": 370.54, "end": 370.76, "word": " the", "probability": 0.9072265625}, {"start": 370.76, "end": 371.2, "word": " power", "probability": 0.8720703125}, {"start": 371.2, "end": 371.72, "word": " N", "probability": 0.95263671875}, {"start": 371.72, "end": 372.76, "word": " ناقص", "probability": 0.93701171875}, {"start": 372.76, "end": 373.4, "word": " تكامل", "probability": 0.9833984375}, {"start": 373.4, "end": 373.76, "word": " لان", "probability": 0.9501953125}, {"start": 373.76, "end": 374.18, "word": " X", "probability": 0.95458984375}, {"start": 374.18, "end": 374.62, "word": " أسن", "probability": 0.6690266927083334}, {"start": 374.62, "end": 375.08, "word": " ناقص", "probability": 0.81201171875}, {"start": 375.08, "end": 375.62, "word": " واحد", "probability": 0.967529296875}, {"start": 375.62, "end": 376.42, "word": " DX", "probability": 0.986328125}], "temperature": 1.0}, {"id": 15, "seek": 39840, "start": 377.02, "end": 398.4, "text": "اليوم ان شاء الله بنكمل بعض القواعد اللي طبعا في غيرهم لكن هم هدول الأساسيات بدنا تكامل ل sign to the power in x dx تكامل ل cosine to the power in x dx tan to the power in x dx او لحاصل الضرب زي ما انت شايف", "tokens": [6027, 1829, 20498, 16472, 13412, 16606, 21984, 44945, 24793, 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386.28, "word": " ل", "probability": 0.8232421875}, {"start": 386.28, "end": 386.62, "word": " sign", "probability": 0.2578125}, {"start": 386.62, "end": 386.82, "word": " to", "probability": 0.90625}, {"start": 386.82, "end": 387.0, "word": " the", "probability": 0.91162109375}, {"start": 387.0, "end": 387.36, "word": " power", "probability": 0.91064453125}, {"start": 387.36, "end": 387.76, "word": " in", "probability": 0.77587890625}, {"start": 387.76, "end": 388.22, "word": " x", "probability": 0.86328125}, {"start": 388.22, "end": 388.72, "word": " dx", "probability": 0.81689453125}, {"start": 388.72, "end": 389.76, "word": " تكامل", "probability": 0.8751220703125}, {"start": 389.76, "end": 389.94, "word": " ل", "probability": 0.97265625}, {"start": 389.94, "end": 390.22, "word": " cosine", "probability": 0.88623046875}, {"start": 390.22, "end": 390.54, "word": " to", "probability": 0.93115234375}, {"start": 390.54, "end": 390.74, "word": " the", "probability": 0.92626953125}, {"start": 390.74, "end": 391.1, "word": " power", "probability": 0.9072265625}, {"start": 391.1, "end": 391.48, "word": " in", "probability": 0.9599609375}, {"start": 391.48, "end": 391.84, "word": " x", "probability": 0.99609375}, {"start": 391.84, "end": 392.42, "word": " dx", "probability": 0.93603515625}, {"start": 392.42, "end": 393.02, "word": " tan", "probability": 0.56396484375}, {"start": 393.02, "end": 393.22, "word": " to", "probability": 0.96826171875}, {"start": 393.22, "end": 393.42, "word": " the", "probability": 0.923828125}, {"start": 393.42, "end": 393.78, "word": " power", "probability": 0.90478515625}, {"start": 393.78, "end": 394.14, "word": " in", "probability": 0.9580078125}, {"start": 394.14, "end": 394.5, "word": " x", "probability": 0.99755859375}, {"start": 394.5, "end": 395.06, "word": " dx", "probability": 0.96533203125}, {"start": 395.06, "end": 395.72, "word": " او", "probability": 0.7724609375}, {"start": 395.72, "end": 396.64, "word": " لحاصل", "probability": 0.8935546875}, {"start": 396.64, "end": 397.2, "word": " الضرب", "probability": 0.8792317708333334}, {"start": 397.2, "end": 397.68, "word": " زي", "probability": 0.93359375}, {"start": 397.68, "end": 397.78, "word": " ما", "probability": 0.9580078125}, {"start": 397.78, "end": 398.0, "word": " انت", "probability": 0.818359375}, {"start": 398.0, "end": 398.4, "word": " شايف", "probability": 0.9853515625}], "temperature": 1.0}, {"id": 16, "seek": 42725, "start": 399.01, "end": 427.25, "text": "طبعا الزوايا كلها نفسي الزاوية لكن باختلاف في مين؟ في الدوال المثلثية طبعا إن هذه مش حيال الله وإنما عدد صحيح موجب لإنه عنده رقم معين بدأ تنتهي التكاملات لكن لو كان السالب والله كاسري لا يمكن نخلص من هالشغلة هذه، تمام؟ السؤال يبقى نطرحه كيف جبنا مين التكاملات اللي عندنا هذه؟ أبدا", "tokens": [9566, 3555, 3615, 995, 6024, 110, 14407, 25528, 28242, 11296, 8717, 36178, 1829, 6024, 110, 995, 2407, 10632, 44381, 4724, 47283, 2655, 15040, 5172, 8978, 3714, 9957, 22807, 8978, 32748, 2407, 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"temperature": 1.0}, {"id": 38, "seek": 90315, "start": 879.71, "end": 903.15, "text": "وصلنا هذه اللي هي الخمس وبدى اطبق قاعدة ال reduction of order تبعت من؟ تبعت ال cosine برجع لل cosine اللي هي القاعدة التانية دى يبقى واحد على n واحد على n لمين؟ لال cosine تك هى بيبقى كده ايش؟ تلت", "tokens": [2407, 36520, 8315, 29538, 13672, 1829, 39896, 33962, 2304, 3794, 4032, 44510, 7578, 1975, 9566, 3555, 4587, 12174, 995, 22488, 3660, 2423, 11004, 295, 1668, 6055, 3555, 34268, 9154, 22807, 6055, 3555, 34268, 2423, 23565, 4724, 47341, 3615, 24976, 23565, 13672, 1829, 39896, 25062, 995, 22488, 3660, 16712, 7649, 10632, 11778, 7578, 7251, 3555, 4587, 7578, 36764, 24401, 15844, 297, 36764, 24401, 15844, 297, 32767, 9957, 22807, 5296, 6027, 23565, 6055, 4117, 8032, 7578, 4724, 1829, 3555, 4587, 7578, 9122, 3215, 3224, 1975, 1829, 8592, 22807, 6055, 1211, 2655], "avg_logprob": -0.30381945305400426, "compression_ratio": 1.76536312849162, "no_speech_prob": 0.0, "words": [{"start": 879.71, "end": 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يبقى بتقول جداش cosine x فقط لا غير cosine ال x في dx كيف؟ مثلا سالب اتنين ع تلاتة كم ولا cosine ال x؟ سالب اتنين ع تلاتة", "tokens": [6027, 39184, 23565, 13672, 1829, 43242, 8315, 34105, 4724, 1829, 9566, 2288, 5016, 9154, 11296, 10874, 3215, 33599, 1975, 2655, 1863, 9957, 7251, 3555, 4587, 7578, 39894, 39648, 10874, 3215, 33599, 23565, 2031, 6156, 47432, 20193, 32771, 13546, 23565, 2423, 2031, 8978, 30017, 9122, 33911, 22807, 50113, 15040, 8608, 6027, 3555, 1975, 2655, 1863, 9957, 6225, 6055, 1211, 9307, 3660, 9122, 2304, 49429, 23565, 2423, 2031, 22807, 8608, 6027, 3555, 1975, 2655, 1863, 9957, 6225, 6055, 1211, 9307, 3660], "avg_logprob": -0.33183592930436134, "compression_ratio": 1.7727272727272727, "no_speech_prob": 0.0, "words": [{"start": 930.37, "end": 930.77, "word": "الـ", "probability": 0.666015625}, {"start": 930.77, "end": 931.15, "word": " cosine", "probability": 0.2242431640625}, {"start": 931.15, "end": 931.39, "word": " اللي", "probability": 0.7685546875}, {"start": 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" من", "probability": 0.9814453125}, {"start": 1308.83, "end": 1308.93, "word": " ال", "probability": 0.9765625}, {"start": 1308.93, "end": 1309.43, "word": " improper", "probability": 0.76123046875}, {"start": 1309.43, "end": 1310.21, "word": " integral", "probability": 0.88671875}, {"start": 1310.21, "end": 1311.25, "word": " يبقى", "probability": 0.960693359375}, {"start": 1311.25, "end": 1311.99, "word": " definition", "probability": 0.80419921875}, {"start": 1311.99, "end": 1314.31, "word": " the", "probability": 0.234130859375}, {"start": 1314.31, "end": 1318.79, "word": " definite", "probability": 0.6865234375}], "temperature": 1.0}, {"id": 56, "seek": 133909, "start": 1324.75, "end": 1339.09, "text": "التكاملات المحدودة with infinite limits of integration", "tokens": [6027, 2655, 4117, 10943, 1211, 9307, 9673, 24401, 23328, 3660, 365, 13785, 10406, 295, 10980], "avg_logprob": -0.25048828683793545, "compression_ratio": 0.922077922077922, "no_speech_prob": 0.0, "words": 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"end": 2090.83, "word": " للأولى", "probability": 0.8875732421875}, {"start": 2090.83, "end": 2091.01, "word": " هي", "probability": 0.83642578125}, {"start": 2091.01, "end": 2091.53, "word": " الحالة", "probability": 0.9521484375}, {"start": 2091.53, "end": 2092.57, "word": " التانية،", "probability": 0.80291748046875}, {"start": 2092.57, "end": 2093.11, "word": " ولو", "probability": 0.7693684895833334}, {"start": 2093.11, "end": 2093.35, "word": " جيت", "probability": 0.90087890625}, {"start": 2093.35, "end": 2094.09, "word": " للتانية", "probability": 0.972900390625}, {"start": 2094.09, "end": 2094.41, "word": " هذه", "probability": 0.66357421875}, {"start": 2094.41, "end": 2094.71, "word": " هي", "probability": 0.9560546875}, {"start": 2094.71, "end": 2095.29, "word": " الحالة", "probability": 0.99462890625}, {"start": 2095.29, "end": 2095.65, "word": " الأولى", "probability": 0.9796549479166666}, {"start": 2095.65, "end": 2095.83, "word": " اللى", "probability": 0.749755859375}, {"start": 2095.83, "end": 2096.27, "word": " فوق،", "probability": 0.9462890625}, {"start": 2096.27, "end": 2096.61, "word": " مظبوط", "probability": 0.76171875}, {"start": 2096.61, "end": 2096.77, "word": " ولا", "probability": 0.64306640625}, {"start": 2096.77, "end": 2097.17, "word": " لا؟", "probability": 0.856689453125}], "temperature": 1.0}, {"id": 85, "seek": 211529, "start": 2097.41, "end": 2115.29, "text": "يبقى بعمل كل واحدة بالحالتين للاتنين، هو كأن الحالة التالتة بتشمل الحالة الأولى والحالة الثانية، يبقى في هذه الحالة حسب التكمل، في احتمال لمن أجي أحسب ال limit، ال limit تطلع قيمة عددية", "tokens": [1829, 3555, 4587, 7578, 4724, 25957, 1211, 28242, 36764, 24401, 3660, 20666, 5016, 6027, 2655, 9957, 24976, 9307, 1863, 9957, 12399, 31439, 9122, 33456, 21542, 6027, 3660, 16712, 6027, 2655, 3660, 39894, 8592, 42213, 21542, 6027, 3660, 16247, 12610, 7578, 16070, 5016, 6027, 3660, 6024, 104, 7649, 10632, 12399, 7251, 3555, 4587, 7578, 8978, 29538, 21542, 6027, 3660, 11331, 35457, 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"probability": 0.98681640625}, {"start": 2114.75, "end": 2115.29, "word": " عددية", "probability": 0.9638671875}], "temperature": 1.0}, {"id": 86, "seek": 213900, "start": 2115.78, "end": 2139.0, "text": "و احتمال تطلع does not exist او infinity او سالب infinity على كل الأمرين بقول ال limit does not exist وبالتالي اذا طلعت ال limit قيمة عددية بقول عن التكامل converge واذا ال limit طلعت ماله نهاية او does not exist بقول التكامل ماله diverse", "tokens": [2407, 1975, 33753, 2304, 6027, 6055, 9566, 1211, 3615, 775, 406, 2514, 1975, 2407, 13202, 1975, 2407, 8608, 6027, 3555, 13202, 15844, 28242, 16247, 29973, 9957, 4724, 39648, 2423, 4948, 775, 406, 2514, 46599, 6027, 2655, 6027, 1829, 1975, 15730, 23032, 1211, 34268, 2423, 4948, 12174, 32640, 3660, 6225, 3215, 3215, 10632, 4724, 39648, 18871, 16712, 4117, 10943, 1211, 41881, 4032, 45636, 995, 2423, 4948, 23032, 1211, 34268, 3714, 6027, 3224, 8717, 11296, 10632, 1975, 2407, 775, 406, 2514, 4724, 39648, 16712, 4117, 10943, 1211, 3714, 6027, 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طلعت", "probability": 0.9851888020833334}, {"start": 2128.3, "end": 2128.5, "word": " ال", "probability": 0.8388671875}, {"start": 2128.5, "end": 2128.74, "word": " limit", "probability": 0.984375}, {"start": 2128.74, "end": 2129.22, "word": " قيمة", "probability": 0.9697265625}, {"start": 2129.22, "end": 2129.84, "word": " عددية", "probability": 0.966552734375}, {"start": 2129.84, "end": 2130.66, "word": " بقول", "probability": 0.924072265625}, {"start": 2130.66, "end": 2130.9, "word": " عن", "probability": 0.97265625}, {"start": 2130.9, "end": 2131.82, "word": " التكامل", "probability": 0.9093017578125}, {"start": 2131.82, "end": 2132.6, "word": " converge", "probability": 0.2415771484375}, {"start": 2132.6, "end": 2133.72, "word": " واذا", "probability": 0.7360026041666666}, {"start": 2133.72, "end": 2133.76, "word": " ال", "probability": 0.61865234375}, {"start": 2133.76, "end": 2134.0, "word": " limit", "probability": 0.97802734375}, {"start": 2134.0, "end": 2134.48, "word": " طلعت", "probability": 0.978515625}, {"start": 2134.48, "end": 2134.84, "word": " ماله", "probability": 0.7391764322916666}, {"start": 2134.84, "end": 2135.3, "word": " نهاية", "probability": 0.8929036458333334}, {"start": 2135.3, "end": 2135.6, "word": " او", "probability": 0.946533203125}, {"start": 2135.6, "end": 2135.88, "word": " does", "probability": 0.92431640625}, {"start": 2135.88, "end": 2136.24, "word": " not", "probability": 0.96533203125}, {"start": 2136.24, "end": 2136.86, "word": " exist", "probability": 0.970703125}, {"start": 2136.86, "end": 2137.22, "word": " بقول", "probability": 0.968994140625}, {"start": 2137.22, "end": 2137.86, "word": " التكامل", "probability": 0.90283203125}, {"start": 2137.86, "end": 2138.34, "word": " ماله", "probability": 0.8240559895833334}, {"start": 2138.34, "end": 2139.0, "word": " diverse", "probability": 0.5859375}], "temperature": 1.0}, {"id": 87, "seek": 216857, "start": 2139.51, "end": 2168.57, "text": "converge بالعربي يعني تقارب التكامل هيصل إلى رقم محدد diverge يبقى الله سهل عليه تباعد لا يمكن نقدر نلحقه تمام؟ كويس يبقى هذه كلمة converge و diverge بدأت من الآن تطرق أسماءنا فبعدين بقول في كل حالة من الحالات اللي فوق إذا ال limit كانت finite يعني سوى رقم محدد بقول التكامل converge", "tokens": [1671, 331, 432, 20666, 3615, 2288, 21292, 37495, 22653, 6055, 4587, 9640, 3555, 16712, 4117, 10943, 1211, 39896, 36520, 30731, 12602, 4587, 2304, 3714, 24401, 3215, 18558, 432, 7251, 3555, 4587, 7578, 21984, 8608, 3224, 1211, 47356, 6055, 3555, 995, 22488, 20193, 7251, 43020, 8717, 28543, 2288, 8717, 1211, 5016, 4587, 3224, 46811, 10943, 22807, 9122, 45865, 3794, 7251, 3555, 4587, 7578, 29538, 9122, 19528, 3660, 41881, 4032, 18558, 432, 47525, 10721, 2655, 9154, 6024, 48506, 6055, 9566, 2288, 4587, 5551, 38251, 16606, 8315, 6156, 3555, 22488, 9957, 4724, 39648, 8978, 28242, 11331, 6027, 3660, 9154, 21542, 6027, 9307, 13672, 1829, 6156, 30543, 11933, 15730, 2423, 4948, 25961, 2655, 19362, 37495, 22653, 8608, 2407, 7578, 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"end": 2364.39, "text": "يبقى هذا improper integral يبقى باجي بقوله هاي ال 16 برا وهذا ال limit و تكامل من zero إلى B و بده اخلى B تروح لوين؟ للماء لنهاية وهذه tan inverse X واش رأيك في هذه؟", "tokens": [1829, 3555, 4587, 7578, 23758, 40651, 11573, 7251, 3555, 4587, 7578, 4724, 26108, 1829, 4724, 39648, 3224, 8032, 47302, 2423, 3165, 4724, 23557, 37037, 15730, 2423, 4948, 4032, 6055, 4117, 10943, 1211, 9154, 4018, 30731, 363, 4032, 47525, 3224, 1975, 9778, 23942, 363, 6055, 32887, 5016, 5296, 2407, 9957, 22807, 5296, 19528, 16606, 5296, 1863, 11296, 10632, 37037, 24192, 7603, 17340, 1783, 4032, 33599, 12602, 10721, 1829, 4117, 8978, 29538, 22807], "avg_logprob": -0.3400607729951541, "compression_ratio": 1.3934426229508197, "no_speech_prob": 0.0, "words": [{"start": 2343.45, "end": 2343.93, "word": "يبقى", "probability": 0.81475830078125}, {"start": 2343.93, "end": 2344.15, "word": " هذا", "probability": 0.62255859375}, {"start": 2344.15, "end": 2344.95, "word": " improper", 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"probability": 0.53125}, {"start": 2351.61, "end": 2352.49, "word": " تكامل", "probability": 0.9000244140625}, {"start": 2352.49, "end": 2353.03, "word": " من", "probability": 0.99267578125}, {"start": 2353.03, "end": 2353.39, "word": " zero", "probability": 0.5}, {"start": 2353.39, "end": 2353.85, "word": " إلى", "probability": 0.64013671875}, {"start": 2353.85, "end": 2354.25, "word": " B", "probability": 0.2607421875}, {"start": 2354.25, "end": 2354.65, "word": " و", "probability": 0.87548828125}, {"start": 2354.65, "end": 2354.97, "word": " بده", "probability": 0.442138671875}, {"start": 2354.97, "end": 2355.43, "word": " اخلى", "probability": 0.6444498697916666}, {"start": 2355.43, "end": 2355.73, "word": " B", "probability": 0.7568359375}, {"start": 2355.73, "end": 2356.13, "word": " تروح", "probability": 0.99169921875}, {"start": 2356.13, "end": 2357.01, "word": " لوين؟", "probability": 0.6168212890625}, {"start": 2357.01, "end": 2357.97, "word": " للماء", "probability": 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tends to infinity لمن لتان", "tokens": [1829, 3555, 4587, 7578, 29538, 37893, 2655, 28671, 6055, 7649, 17340, 1783, 4032, 4117, 33456, 36764, 24401, 3660, 44945, 4117, 10943, 1211, 343, 35, 54, 7251, 3555, 4587, 7578, 47525, 8315, 8717, 11242, 33911, 24976, 10721, 3794, 36764, 24401, 4032, 1863, 4587, 38251, 15844, 16247, 3794, 25724, 16254, 3215, 7251, 3555, 4587, 7578, 29538, 21136, 2655, 6225, 46309, 37037, 15730, 2423, 4948, 5296, 15042, 363, 12258, 281, 13202, 5296, 27842, 5296, 2655, 7649], "avg_logprob": -0.32580235681018316, "compression_ratio": 1.4606741573033708, "no_speech_prob": 0.0, "words": [{"start": 2370.47, "end": 2371.87, "word": "يبقى", "probability": 0.718963623046875}, {"start": 2371.87, "end": 2372.31, "word": " هذه", "probability": 0.1324462890625}, {"start": 2372.31, "end": 2373.39, "word": " مشتقة", "probability": 0.8048502604166666}, {"start": 2373.39, "end": 2374.33, "word": " تان", "probability": 0.564697265625}, {"start": 2374.33, "end": 2375.33, "word": " 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1211], "avg_logprob": -0.1608630963734218, "compression_ratio": 2.1012658227848102, "no_speech_prob": 0.0, "words": [{"start": 2452.54, "end": 2452.94, "word": "بايع", "probability": 0.513916015625}, {"start": 2452.94, "end": 2453.58, "word": " اتنين", "probability": 0.8218994140625}, {"start": 2453.58, "end": 2454.44, "word": " اقصى", "probability": 0.912109375}, {"start": 2454.44, "end": 2454.86, "word": " قيمة", "probability": 0.951171875}, {"start": 2454.86, "end": 2455.54, "word": " بتاخدها", "probability": 0.8494873046875}, {"start": 2455.54, "end": 2455.9, "word": " بايع", "probability": 0.8113606770833334}, {"start": 2455.9, "end": 2456.14, "word": " اتنين", "probability": 0.98046875}, {"start": 2456.14, "end": 2456.28, "word": " و", "probability": 0.568359375}, {"start": 2456.28, "end": 2456.66, "word": " اقل", "probability": 0.91943359375}, {"start": 2456.66, "end": 2457.46, "word": " قيمة", "probability": 0.8546549479166666}, {"start": 2457.46, "end": 2458.24, "word": " سالب", "probability": 0.6381022135416666}, {"start": 2458.24, "end": 2458.5, "word": " بايع", "probability": 0.93603515625}, {"start": 2458.5, "end": 2458.78, "word": " على", "probability": 0.8564453125}, {"start": 2458.78, "end": 2459.26, "word": " اتنين", "probability": 0.9818115234375}, {"start": 2459.26, "end": 2460.32, "word": " يبقى", "probability": 0.9539794921875}, {"start": 2460.32, "end": 2460.66, "word": " هذه", "probability": 0.67919921875}, {"start": 2460.66, "end": 2461.12, "word": " بدها", "probability": 0.6785888671875}, {"start": 2461.12, "end": 2461.9, "word": " تساوي", "probability": 0.8743896484375}, {"start": 2461.9, "end": 2463.28, "word": " تمانية", "probability": 0.9391276041666666}, {"start": 2463.28, "end": 2463.78, "word": " في", "probability": 0.56494140625}, {"start": 2463.78, "end": 2464.32, "word": " بايع", "probability": 0.82080078125}, {"start": 2464.32, "end": 2464.7, "word": " على", "probability": 0.9365234375}, {"start": 2464.7, "end": 2465.36, "word": " اتنين", "probability": 0.9876708984375}, {"start": 2465.36, "end": 2465.92, "word": " لكل", "probability": 0.921875}, {"start": 2465.92, "end": 2466.78, "word": " تربيع", "probability": 0.926025390625}, {"start": 2466.78, "end": 2467.62, "word": " يعني", "probability": 0.880859375}, {"start": 2467.62, "end": 2468.6, "word": " اتنين", "probability": 0.981689453125}, {"start": 2468.6, "end": 2469.12, "word": " بايع", "probability": 0.6318359375}, {"start": 2469.12, "end": 2469.82, "word": " تربيع", "probability": 0.83349609375}, {"start": 2469.82, "end": 2470.52, "word": " طلعت", "probability": 0.8253580729166666}, {"start": 2470.52, "end": 2471.08, "word": " النتيجة", "probability": 0.89697265625}, {"start": 2471.08, "end": 2471.36, "word": " عند", "probability": 0.90087890625}, {"start": 2471.36, "end": 2472.98, "word": " الرقم", "probability": 0.9251302083333334}, {"start": 2472.98, "end": 2473.32, "word": " يبقى", "probability": 0.9705810546875}, {"start": 2473.32, "end": 2474.24, "word": " التكامل", "probability": 0.96630859375}], "temperature": 1.0}, {"id": 101, "seek": 249582, "start": 2475.78, "end": 2495.82, "text": "قيمة التكامل هو الرقم اللي طلع وبالتالي بقول له so تكامل من zero ل infinity ل 16 tan inverse x على 1 زيد x تربية dx converge وانتهينا من هذه المسألة", "tokens": [4587, 32640, 3660, 16712, 4117, 10943, 1211, 31439, 34892, 4587, 2304, 13672, 1829, 23032, 1211, 3615, 46599, 6027, 2655, 6027, 1829, 4724, 39648, 46740, 370, 6055, 4117, 10943, 1211, 9154, 4018, 5296, 13202, 5296, 3165, 7603, 17340, 2031, 15844, 502, 30767, 1829, 3215, 2031, 6055, 25513, 10632, 30017, 41881, 4032, 7649, 47395, 1829, 8315, 9154, 29538, 9673, 3794, 10721, 37977], "avg_logprob": -0.27459016588867685, "compression_ratio": 1.3592814371257484, "no_speech_prob": 0.0, "words": [{"start": 2475.78, "end": 2476.86, "word": "قيمة", "probability": 0.7283121744791666}, {"start": 2476.86, "end": 2477.5, "word": " التكامل", "probability": 0.939697265625}, {"start": 2477.5, "end": 2477.68, "word": " هو", "probability": 0.6962890625}, {"start": 2477.68, "end": 2478.22, "word": " الرقم", "probability": 0.958984375}, {"start": 2478.22, "end": 2478.38, "word": " اللي", "probability": 0.775146484375}, {"start": 2478.38, "end": 2478.86, "word": " طلع", "probability": 0.861328125}, {"start": 2478.86, "end": 2479.84, "word": " وبالتالي", "probability": 0.905078125}, {"start": 2479.84, "end": 2480.28, "word": " بقول", "probability": 0.8515625}, {"start": 2480.28, "end": 2480.58, "word": " له", "probability": 0.58837890625}, {"start": 2480.58, "end": 2481.08, "word": " so", "probability": 0.04827880859375}, {"start": 2481.08, "end": 2482.64, "word": " تكامل", "probability": 0.909912109375}, {"start": 2482.64, "end": 2483.18, "word": " من", "probability": 0.92919921875}, {"start": 2483.18, "end": 2483.58, "word": " zero", "probability": 0.52880859375}, {"start": 2483.58, "end": 2483.84, "word": " ل", "probability": 0.7958984375}, {"start": 2483.84, "end": 2484.68, "word": " infinity", "probability": 0.76806640625}, {"start": 2484.68, "end": 2485.46, "word": " ل", "probability": 0.849609375}, {"start": 2485.46, "end": 2486.3, "word": " 16", "probability": 0.38916015625}, {"start": 2486.3, "end": 2487.1, "word": " tan", "probability": 0.271728515625}, {"start": 2487.1, "end": 2487.94, "word": " inverse", "probability": 0.91650390625}, {"start": 2487.94, "end": 2488.42, "word": " x", "probability": 0.841796875}, {"start": 2488.42, "end": 2488.68, "word": " على", "probability": 0.56201171875}, {"start": 2488.68, "end": 2489.16, "word": " 1", "probability": 0.74560546875}, {"start": 2489.16, "end": 2490.2, "word": " زيد", "probability": 0.6610514322916666}, {"start": 2490.2, "end": 2490.5, "word": " x", "probability": 0.95703125}, {"start": 2490.5, "end": 2491.08, "word": " تربية", "probability": 0.8616536458333334}, {"start": 2491.08, "end": 2491.74, "word": " dx", "probability": 0.947265625}, {"start": 2491.74, "end": 2492.96, "word": " converge", "probability": 0.36669921875}, {"start": 2492.96, "end": 2494.34, "word": " وانتهينا", "probability": 0.94736328125}, {"start": 2494.34, "end": 2494.56, "word": " من", "probability": 0.984375}, {"start": 2494.56, "end": 2494.94, "word": " هذه", "probability": 0.9599609375}, {"start": 2494.94, "end": 2495.82, "word": " المسألة", "probability": 0.9432373046875}], "temperature": 1.0}, {"id": 102, "seek": 253751, "start": 2513.63, "end": 2537.51, "text": "بناخد كمان مثال يبقى example two بدنا تكامل من اتنين الى infinity لل اتنين على x تربية ناقص x dx فالليلي في السؤال كويس الدالة مش معرفة وين", "tokens": [3555, 1863, 47283, 3215, 9122, 2304, 7649, 50113, 6027, 7251, 3555, 4587, 7578, 1365, 732, 47525, 8315, 6055, 4117, 10943, 1211, 9154, 1975, 2655, 1863, 9957, 2423, 7578, 13202, 24976, 1975, 2655, 1863, 9957, 15844, 2031, 6055, 25513, 10632, 8717, 995, 4587, 9381, 2031, 30017, 6156, 6027, 20292, 20292, 8978, 21136, 33604, 6027, 9122, 45865, 3794, 32748, 6027, 3660, 37893, 20449, 28480, 3660, 4032, 9957], "avg_logprob": -0.28574811012455914, "compression_ratio": 1.440251572327044, "no_speech_prob": 0.0, "words": [{"start": 2513.63, "end": 2514.35, "word": "بناخد", "probability": 0.637908935546875}, {"start": 2514.35, "end": 2514.75, "word": " كمان", "probability": 0.7625325520833334}, {"start": 2514.75, "end": 2515.39, "word": " مثال", "probability": 0.9296875}, {"start": 2515.39, "end": 2517.53, "word": " يبقى", "probability": 0.8857421875}, {"start": 2517.53, "end": 2518.13, "word": " example", "probability": 0.86328125}, {"start": 2518.13, "end": 2518.89, "word": " two", "probability": 0.368408203125}, {"start": 2518.89, "end": 2521.37, "word": " بدنا", "probability": 0.8349609375}, {"start": 2521.37, "end": 2522.37, "word": " تكامل", "probability": 0.970947265625}, {"start": 2522.37, "end": 2523.37, "word": " من", "probability": 0.97119140625}, {"start": 2523.37, "end": 2524.51, "word": " اتنين", "probability": 0.9027099609375}, {"start": 2524.51, "end": 2525.15, 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تانية، هذه زي ما هي، كويس؟ و جينا ليها دي، خلينا ليها تروح لسالب infinity، يبقى ده كله بسالب infinity الجذر التالت لسالب infinity تاربية يعني موجب", "tokens": [2304, 25720, 6055, 7649, 10632, 12399, 3714, 25720, 6055, 7649, 10632, 12399, 29538, 30767, 1829, 19446, 39896, 12399, 9122, 45865, 3794, 22807, 4032, 10874, 1829, 8315, 32239, 11296, 11778, 1829, 12399, 16490, 1211, 9957, 995, 32239, 11296, 6055, 32887, 5016, 5296, 3794, 6027, 3555, 13202, 12399, 7251, 3555, 4587, 7578, 11778, 3224, 28242, 3224, 4724, 3794, 6027, 3555, 13202, 25724, 8848, 2288, 16712, 6027, 2655, 5296, 3794, 6027, 3555, 13202, 6055, 9640, 3555, 10632, 37495, 22653, 3714, 29245, 3555], "avg_logprob": -0.2519531108438969, "compression_ratio": 1.8175675675675675, "no_speech_prob": 0.0, "words": [{"start": 2939.88, "end": 2940.38, "word": "مرة", "probability": 0.7171630859375}, {"start": 2940.38, "end": 2941.12, "word": " تانية،", "probability": 0.785888671875}, {"start": 2941.12, "end": 2941.92, "word": " مرة", 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47395, 16712, 4117, 10943, 1211, 23758, 3714, 6027, 3224, 7620, 7251, 3555, 4587, 7578, 6055, 4117, 10943, 1211, 9154, 8608, 6027, 3555, 13202, 30731, 13202], "avg_logprob": -0.32240317321159473, "compression_ratio": 1.6887417218543046, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3173.09, "end": 3173.47, "word": "بظل", "probability": 0.3884684244791667}, {"start": 3173.47, "end": 3173.89, "word": " 45", "probability": 0.60595703125}, {"start": 3173.89, "end": 3174.87, "word": " بواحد", "probability": 0.6146647135416666}, {"start": 3174.87, "end": 3175.19, "word": " يبقى", "probability": 0.823974609375}, {"start": 3175.19, "end": 3175.51, "word": " باي", "probability": 0.5357666015625}, {"start": 3175.51, "end": 3175.81, "word": " على", "probability": 0.67724609375}, {"start": 3175.81, "end": 3176.35, "word": " أربعة", "probability": 0.67431640625}, {"start": 3176.35, "end": 3176.81, "word": " يبقى", "probability": 0.8658447265625}, {"start": 3176.81, "end": 3177.25, "word": " بظل", "probability": 0.7926432291666666}, {"start": 3177.25, "end": 3177.51, "word": " أن", "probability": 0.210693359375}, {"start": 3177.51, "end": 3177.93, "word": " هنا", "probability": 0.771484375}, {"start": 3177.93, "end": 3179.45, "word": " أربعة", "probability": 0.8094075520833334}, {"start": 3179.45, "end": 3179.81, "word": " في", "probability": 0.72900390625}, {"start": 3179.81, "end": 3180.39, "word": " باي", "probability": 0.8232421875}, {"start": 3180.39, "end": 3180.93, "word": " على", "probability": 0.9072265625}, {"start": 3180.93, "end": 3181.75, "word": " أربعة", "probability": 0.9111328125}, {"start": 3181.75, "end": 3181.95, "word": " و", "probability": 0.77392578125}, {"start": 3181.95, "end": 3182.73, "word": " يساوي", "probability": 0.78955078125}, {"start": 3182.73, "end": 3183.29, "word": " باي", "probability": 0.75439453125}, {"start": 3183.29, "end": 3184.15, "word": " معناته", "probability": 0.8191731770833334}, {"start": 3184.15, "end": 3184.73, "word": " التكامل", "probability": 0.8826904296875}, {"start": 3184.73, "end": 3184.97, "word": " هذا", "probability": 0.77099609375}, {"start": 3184.97, "end": 3185.59, "word": " ماله", "probability": 0.781982421875}, {"start": 3185.59, "end": 3186.63, "word": " convert", "probability": 0.22021484375}, {"start": 3186.63, "end": 3188.01, "word": " يبقى", "probability": 0.9654541015625}, {"start": 3188.01, "end": 3189.15, "word": " تكامل", "probability": 0.77789306640625}, {"start": 3189.15, "end": 3189.31, "word": " من", "probability": 0.96435546875}, {"start": 3189.31, "end": 3189.79, "word": " سالب", "probability": 0.7648111979166666}, {"start": 3189.79, "end": 3190.57, "word": " infinity", "probability": 0.78369140625}, {"start": 3190.57, "end": 3191.13, "word": " إلى", "probability": 0.9169921875}, {"start": 3191.13, "end": 3192.19, "word": " infinity", "probability": 0.75830078125}], "temperature": 1.0}, {"id": 131, "seek": 320693, "start": 3198.57, "end": 3206.93, "text": "لازلنا 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/dDx0Ho9ebxY.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/dDx0Ho9ebxY.srt
new file mode 100644
index 0000000000000000000000000000000000000000..64cdb3244acb8378da7e62ad4b6b5fa7081af5b4
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/dDx0Ho9ebxY.srt
@@ -0,0 +1,1340 @@
+1
+00:00:12,060 --> 00:00:18,680
+نكمل سيكشن 11-3 الذي ابتدأنا فيه المرة الماضية وهو
+
+2
+00:00:18,680 --> 00:00:23,210
+الـ polar coordinatesالمرة الفاتة كنا بنحول نقطة من
+
+3
+00:00:23,210 --> 00:00:26,830
+polar coordinates إلى cartesian coordinates والعكس
+
+4
+00:00:26,830 --> 00:00:29,330
+نقطة من cartesian coordinates إلى polar
+
+5
+00:00:29,330 --> 00:00:33,450
+coordinates ثم معادلات نحولها من polar coordinates
+
+6
+00:00:33,450 --> 00:00:38,070
+إلى cartesian coordinatesباقي علينا مثال هي و بدنا 
+
+7
+00:00:38,070 --> 00:00:42,810
+ناخده مثال أربعة الذي هو بيقول replace the
+
+8
+00:00:42,810 --> 00:00:45,730
+following Cartesian equation by its equivalent
+
+9
+00:00:45,730 --> 00:00:50,710
+polar equations يبقى احنا بدنا نروح نحول المعادلات
+
+10
+00:00:50,710 --> 00:00:55,290
+الكارتيزية التي عندنا إلى معادلات قطبية على أكس
+
+11
+00:00:55,290 --> 00:01:00,930
+آخر مثال أخدناه المرة الماضية يبدأ المعادلات مواطعة
+
+12
+00:01:00,930 --> 00:01:05,070
+في الصيغة الكارتزية بدي أحولها إلى الصيغة القطبية
+
+13
+00:01:05,070 --> 00:01:09,730
+بدي أذكر تذكير بالمعادلة تبعات التحويل قبل أن نبدأ
+
+14
+00:01:09,730 --> 00:01:14,570
+التحويل التي مكتوب معاكم في المرة الماضية أخدنا
+
+15
+00:01:14,570 --> 00:01:19,330
+المعادلة الأولى فكانت المعادلة الأولى X يساوي R في
+
+16
+00:01:19,330 --> 00:01:26,380
+Cos الزاوية ثيتا وY تساوي R في Sin الزاوية ثيتا  ومن
+
+17
+00:01:26,380 --> 00:01:31,640
+هاتين المعادلتين كنا بناخد إحداثي قديم x و y
+
+18
+00:01:31,640 --> 00:01:37,340
+بدلالة إحداثيين جديدين الذين هم r و theta هناخد الآن
+
+19
+00:01:37,340 --> 00:01:41,640
+الذي هو إحداثي جديد بدلالة الإحداثيين اثنين
+
+20
+00:01:41,640 --> 00:01:48,270
+الأقدام فبجي بقول تان ثيتا بده يساوي Y على X أو ال
+
+21
+00:01:48,270 --> 00:01:55,310
+R تربيع بده يساوي X تربيع زائد Y تربيع تمام؟ يبجي
+
+22
+00:01:55,310 --> 00:01:59,290
+أن R تربيع يساوي X تربيع يبجي هذه المعادلات الأربع
+
+23
+00:01:59,290 --> 00:02:03,740
+الذي من خلالها بنحول من Polar إلى Cartesianأو من
+
+24
+00:02:03,740 --> 00:02:08,620
+كارتيزيا إلى polar يبقى بإذن الله نجيه solution
+
+25
+00:02:08,620 --> 00:02:15,060
+للسؤال الأول نمره ايه؟ بدي أشيل كل y و أحط مكانها
+
+26
+00:02:15,060 --> 00:02:20,740
+r sin θ و أشيل كل x و أحط مكانها r في cosine
+
+27
+00:02:20,740 --> 00:02:25,600
+الزاوية θ تمام؟ يبقى المعادلة التي بيقولي y تربيها
+
+28
+00:02:25,600 --> 00:02:32,500
+تساوي 4x يبقى عندك ال y بيبقى r في sin الزاوية θ
+
+29
+00:02:33,210 --> 00:02:41,130
+تربيع يبقى لكل تربيع تساوي أربعة في ال X الذي هي ب
+
+30
+00:02:41,130 --> 00:02:46,950
+R Cos Theta يبقى هي ال R Cos Theta إذا كتبنا
+
+31
+00:02:46,950 --> 00:02:51,570
+المعادلة الكارتزية المعطاة كتبناها في الصيغة
+
+32
+00:02:51,570 --> 00:02:57,690
+القطبية بنحاول نرتب شكل المعادلة هذه شوية فهذه لو
+
+33
+00:02:57,690 --> 00:03:02,870
+جينا فكتبناها بطريقة أخرى R تربيع في Sin تربيع
+
+34
+00:03:02,870 --> 00:03:10,910
+ثيتا ناقص أربعة R في Cos الزاوية ثيتا يساوي Zero
+
+35
+00:03:10,910 --> 00:03:16,900
+إذا بدنا نحاول ناخد عامل مشترك ونشوف إيش الذي بدي
+
+36
+00:03:16,900 --> 00:03:22,400
+يحصل يبقى لو أخدنا R عامل مشترك بصير عندنا R في
+
+37
+00:03:22,400 --> 00:03:28,260
+sin تربيع ثيتا ناقص أربعة كوساين الزاوية ثيتا كله
+
+38
+00:03:28,260 --> 00:03:34,820
+بدي أساوي كده؟ بدي أساوي Zero هذا معناه يا إما الار
+
+39
+00:03:34,820 --> 00:03:43,320
+بدها تساوي zero يا إما الار بدها تساوي أربعة كوساين
+
+40
+00:03:43,320 --> 00:03:49,550
+ثيتا على مين على ساين تربيع ثيتا يبقى يا إما هذا
+
+41
+00:03:49,550 --> 00:03:53,990
+بيساوي Zero يا إما القسم هذا بيساوي Zero هذا نجلته
+
+42
+00:03:53,990 --> 00:03:57,290
+على الشجة الثانية فصار أربعة كوساين تيتا عالميا
+
+43
+00:03:57,290 --> 00:04:03,990
+على ساين تربيع تيتا أو يا إما ال R بدها تساوي Zero
+
+44
+00:04:03,990 --> 00:04:12,640
+يا إما ال R تساوي الاربعة خليها زي ما هي بدء أقول
+
+45
+00:04:12,640 --> 00:04:17,940
+cos على sin في 1 على sin cos على sin التي هي كتان
+
+46
+00:04:17,940 --> 00:04:27,140
+و 1 على sin بكوسيكن يبقى أربعة التي هو كتان ثيتا
+
+47
+00:04:27,140 --> 00:04:33,530
+كوسيكن تمام كوسيكن ثيتا بالشكل التي عندنا هذا يبقى
+
+48
+00:04:33,530 --> 00:04:37,970
+قلة المعادلة الكارتزية تمثلها معادلتان أخريان يعني
+
+49
+00:04:37,970 --> 00:04:44,040
+هذا بالنسبة للنقطة A بالنسبة للنقطة B النقطة B
+
+50
+00:04:44,040 --> 00:04:52,020
+بيقول X ناقص خمسة لكل تربيع زائد Y تربيع يساوي 25
+
+51
+00:04:52,020 --> 00:04:58,340
+طبعا ما عنديش هنا في المعادلات تقول X ناقص خمسة إذا
+
+52
+00:04:58,340 --> 00:05:02,680
+بدأ فك الجثة هذا و نشوف شو الذي بده يحصل معنا إذا
+
+53
+00:05:02,680 --> 00:05:08,800
+لو جيت فكيت الجثة هذا و بده يكون X تربيع ناقص عشرة
+
+54
+00:05:08,800 --> 00:05:16,430
+X زائد خمسة وعشرين زائد Y تربيع كله بده يساوي كده؟
+
+55
+00:05:16,430 --> 00:05:23,610
+خمسة وعشرين طلع لي كويس هنا بدي آخد X تربيع زائد Y
+
+56
+00:05:23,610 --> 00:05:29,710
+تربيع مع بعضهم بيظل ناقص عشرة X هذا الكلام بدي
+
+57
+00:05:29,710 --> 00:05:33,630
+يساوي Zero ودينا الخمسة وعشرين عند الخمسة وعشرين
+
+58
+00:05:33,630 --> 00:05:38,330
+يساوي Zero بعد ما بسطت المعادلة و كتبتها في ثوب
+
+59
+00:05:38,330 --> 00:05:43,610
+جديد أو في شكل جديد بدنا نروح نكتبها بالصيغة
+
+60
+00:05:43,610 --> 00:05:49,290
+القطبية الـ X تربيع زي الـ Y تربيع جاهزة علينا التي
+
+61
+00:05:49,290 --> 00:05:55,490
+عبارة عن مين R تربيع يبقى هذه R تربيع ناقص عشرة
+
+62
+00:05:55,490 --> 00:06:01,150
+وهذه جاهزة R في Cos الزاوية ثيتا يساوي Zero إذا
+
+63
+00:06:01,150 --> 00:06:06,710
+ممكن نأخذ R عن المشترك بظل R ناقص عشرة Cos ثيتا
+
+64
+00:06:06,710 --> 00:06:11,090
+بده يساوي Zero يبقى يا إما الـ R بدها تساوي Zero
+
+65
+00:06:11,090 --> 00:06:16,870
+يا إما الـ R بدها تساوي عشرة يوجد كوسايم الزاوية C
+
+66
+00:06:16,870 --> 00:06:22,050
+يعني الشكل هذا أو الشكل هذا للاثنين C يعني توقف إلى
+
+67
+00:06:22,050 --> 00:06:27,990
+هنا انتهى ال section إليكم أربع باعي ال C ولا يهمك
+
+68
+00:06:27,990 --> 00:06:34,670
+أين أمرها C نمر ال C ممكن اخل ال X و ال Y في الشجة
+
+69
+00:06:34,670 --> 00:06:40,630
+والاعداد في ناحية أخرى يمكن ممكن أقول ال X و Y
+
+70
+00:06:40,630 --> 00:06:49,030
+بدوا يساوي تسعة أرباع أو ال X الذي R Cos θ وهذه R
+
+71
+00:06:49,030 --> 00:06:58,430
+Sin θ بدوا يساوي تسعة أرباع ممكن اخل ال R تربيع في
+
+72
+00:06:58,430 --> 00:07:06,090
+ناحية و 9 على 4 Sine Theta Cosine Theta يعني جسمنا
+
+73
+00:07:06,090 --> 00:07:10,590
+الطرفين على Sine Theta Cosine Theta لغاية بدها
+
+74
+00:07:10,590 --> 00:07:19,150
+تساوي 9 على 2 Sine 2 Theta يعني الأربعة اعتبرناها
+
+75
+00:07:19,150 --> 00:07:28,760
+هذه 2 في اثنين في sin θ cos θ sin θ cos θ هذه كلها
+
+76
+00:07:28,760 --> 00:07:34,480
+sin اثنين ثيتا احنا ما بدناش R تربيع بدنا R يبقى
+
+77
+00:07:34,480 --> 00:07:42,660
+بروح ندله R تساوي الزائد أو ناقص تلاتة على جذر
+
+78
+00:07:42,660 --> 00:07:50,690
+اثنين لمين لsin اثنين ثيتا بهذا الشكل يبقى هذا
+
+79
+00:07:50,690 --> 00:07:54,810
+المعادلة القطبية المناظرة للمعادلة الكارثية ال
+
+80
+00:07:54,810 --> 00:07:59,750
+land land هنا stop إليكم أرقام المسائل الخاصة بهذا
+
+81
+00:07:59,750 --> 00:08:07,070
+section وهو section 11 3 يبقى exercises 11 3
+
+82
+00:08:07,070 --> 00:08:16,290
+المسائل التالية من 1 ل 67 الذي هو ال multiple
+
+83
+00:08:18,660 --> 00:08:20,960
+multiple of three
+
+84
+00:08:25,830 --> 00:08:32,730
+طيب ننتقل الآن إلى ال section الذي يليه وهو طريقة
+
+85
+00:08:32,730 --> 00:08:38,610
+الرسم في الإحداثيات القطبية بنشوف كيف بنرسم
+
+86
+00:08:38,610 --> 00:08:45,770
+المنحنيات المختلفة في الإحداثيات القطبية وسنقسم
+
+87
+00:08:45,770 --> 00:08:50,970
+هذا ال section أو الجزء النظري لهذا ال section إلى
+
+88
+00:08:50,970 --> 00:08:57,540
+نقطتين النقطة الأولى التي هي ال symmetry التماثل
+
+89
+00:08:57,540 --> 00:09:02,800
+والنقطة الثانية التي هي ال slope يبقى بدنا نجي
+
+90
+00:09:02,800 --> 00:09:07,620
+للنقطة الأولى يبقى graphing in polar coordinates
+
+91
+00:09:07,620 --> 00:09:18,560
+section 11 أربعة graphing in polar coordinates
+
+92
+00:09:22,950 --> 00:09:30,710
+يبقى الرسم في الإحداثيات القطبية أول نقطة في هذا
+
+93
+00:09:30,710 --> 00:09:33,250
+ال section بدنا ندرس هي symmetry
+
+94
+00:09:37,040 --> 00:09:42,780
+بناخد التماثل حول محور X أو حول ال polar
+
+95
+00:09:42,780 --> 00:09:48,380
+axis ثم التماثل حول محور Y أو الخط θ تساوي Y على
+
+96
+00:09:48,380 --> 00:09:55,680
+2 ثم تماثل حول نقطة الأصل هذه التماثلات الثلاثة
+
+97
+00:09:55,680 --> 00:10:02,300
+التي سندرسها نبدأ من التماثل الأول التماثل الأول
+
+98
+00:10:02,300 --> 00:10:03,740
+الذي هو ال symmetry
+
+99
+00:10:06,440 --> 00:10:17,580
+about symmetry about the x axis هذا شو معناه؟
+
+100
+00:10:17,580 --> 00:10:32,040
+means that if the point r و theta lies on
+
+101
+00:10:32,040 --> 00:10:42,980
+the graph ثم نقطة الـ
+
+102
+00:10:42,980 --> 00:10:59,220
+r و سالب ثيتا أو سالب r و باي ناقص ثيتا موجودة
+
+103
+00:10:59,220 --> 00:11:12,510
+على الجرافي النقطة الثانية سيمتري عن
+
+104
+00:11:12,510 --> 00:11:16,550
+الواي
+
+105
+00:11:16,550 --> 00:11:28,810
+أكسيز يعني أنه إذا كانت النقطة ر أو ثيتا
+
+106
+00:11:43,740 --> 00:11:52,700
+إذا كان الوضع R وثيتا على المقاطع
+
+107
+00:11:52,700 --> 00:11:57,340
+فالوضع
+
+108
+00:11:57,340 --> 00:12:02,380
+R
+
+109
+00:12:02,380 --> 00:12:11,800
+و بي ناقص ثيتا أو سلب R و سلب ثيتا
+
+110
+00:12:13,450 --> 00:12:23,310
+on the graph النقطة الثالثة والاخيرة symmetry
+
+111
+00:12:23,310 --> 00:12:27,390
+about
+
+112
+00:12:27,390 --> 00:12:42,890
+the origin شو معناها هذه means that if the point
+
+113
+00:12:45,160 --> 00:12:55,060
+ار وثيتا موجودة على الجرافة
+
+114
+00:12:55,060 --> 00:13:13,120
+ثم نقطة سالب ار وثيتا أو ار و باي زائد ثيتا موجودة
+
+115
+00:13:13,120 --> 00:13:14,160
+على الجرافة
+
+116
+00:13:19,910 --> 00:13:34,470
+نقطة مهمة ملاحظة Any two symmetries gives
+
+117
+00:13:34,470 --> 00:13:37,550
+the
+
+118
+00:13:37,550 --> 00:13:44,330
+third symmetry
+
+119
+00:14:37,190 --> 00:14:40,830
+العنوان الذي احنا رافعينه الذي هو graph in polar
+
+120
+00:14:40,830 --> 00:14:47,070
+coordinates الرسم في الإحداثيات القطبية وروحنا
+
+121
+00:14:47,070 --> 00:14:52,510
+أخدنا أول عنوان هو ال symmetry طب استنى شوية احنا
+
+122
+00:14:52,510 --> 00:14:57,310
+في كل كلصية بقينا نأخذ الرسم البياني للمنحنيات بس
+
+123
+00:14:57,310 --> 00:15:02,990
+في الإحداثيات الكارتزية و بقينا نروح على المنحنى و
+
+124
+00:15:02,990 --> 00:15:07,810
+نجيب تقاطعه مع محورية الإحداثيات و بعدين نعمله
+
+125
+00:15:07,810 --> 00:15:11,270
+اشتقاق و نجيب ال local maximum و ال local minimum
+
+
+126
+00:15:11,270 --> 00:15:14,690
+و ال critical points و ال concave up و ال concave
+
+127
+00:15:14,690 --> 00:15:19,570
+down و ال inflection points و ال asymptotes in وجه
+
+128
+00:15:19,570 --> 00:15:24,030
+ذاته و بعدين بنروح نرسمه،الرسمة بتبعتنا، هذا
+
+129
+00:15:24,030 --> 00:15:28,210
+الكلام عفى عليه الزمن، هذا كنا بنوصف الإحداث
+
+130
+00:15:28,210 --> 00:15:33,470
+الكارتزية، لكن هنا إحداثيات جديدة، موضوع ال
+
+131
+00:15:33,470 --> 00:15:38,210
+symmetryبالبلدي اللي هو الكلام اللي ذكرناه قبل قليل
+
+132
+00:15:38,210 --> 00:15:41,010
+ال local maximum و ال local minimum و ال concave و
+
+133
+00:15:41,010 --> 00:15:45,570
+up و ال inflection و ما إلى ذلك هذا كله سنستعيد
+
+134
+00:15:45,570 --> 00:15:50,970
+عنه من بالتماثل لما قول تماثل بالنسبة لمحور X لو
+
+135
+00:15:50,970 --> 00:15:55,950
+جيت تخيلت هذا محور X إذا الرسم اللي أعلى محور X
+
+136
+00:15:55,950 --> 00:16:00,220
+بتبقى زي مين؟زي الرسمة اللي أسفل محور X بس مجلوب و
+
+137
+00:16:00,220 --> 00:16:04,060
+بدل ما كانت فوق بيصير إيه تحت هذا معنى التماثل
+
+138
+00:16:04,060 --> 00:16:08,400
+بالنسبة لمحور X تماثل بالنسبة لمحور Y يعني الرسمة
+
+139
+00:16:08,400 --> 00:16:12,140
+اللي على اليمين زي الرسمة اللي على اليمين
+
+140
+00:16:12,140 --> 00:16:17,410
+على الشمال تماثل بالنسبة لنقطة origin فمثلا لو
+
+141
+00:16:17,410 --> 00:16:22,930
+قلت أنا واقف في ال origin يبقى أي نقطة على يمين ال
+
+142
+00:16:22,930 --> 00:16:29,390
+origin ستظهر نقطة على شمالها وعلى نفس البعد من
+
+143
+00:16:29,390 --> 00:16:34,650
+نقطة الأصل، إن حدث ذلك بيقول في تماثل بالنسبة لما ..
+
+144
+00:16:34,650 --> 00:16:40,670
+لنقطة الأصل، هذا كلام بالبلدي لكن بدنا نروح نحطه 
+
+145
+00:16:40,670 --> 00:16:47,740
+رياضيا على أرض الواقع بالرسم والعبارات الرياضية، نمسك
+
+146
+00:16:47,740 --> 00:16:52,000
+النقطة الأولى هي symmetry about the x axis التمثيل
+
+147
+00:16:52,000 --> 00:16:56,460
+حول محور x شو معناه؟ معناه that if the point r و
+
+148
+00:16:56,460 --> 00:17:01,900
+θ lies on the graph يعني لو عندي منحنى مرسوم و
+
+149
+00:17:01,900 --> 00:17:07,540
+بدي ابحث هل هذا المنحنى متمثل بالنسبة لمحور X
+
+150
+00:17:07,540 --> 00:17:13,380
+ولا لأ بأخذ أي نقطة موجودة عليه ما أخذتش نقطة بعينها
+
+151
+00:17:13,380 --> 00:17:18,420
+لأ r و θ أي نقطة تقع على المنحنى إن وقعت هذه
+
+152
+00:17:18,420 --> 00:17:24,060
+النقطة على المنحنى يجب أن تقع النقطة r و سالب θ
+
+153
+00:17:24,060 --> 00:17:29,730
+على المنحنى طيب لو هذه ما وقعتش بجيب مين؟ النقطة
+
+154
+00:17:29,730 --> 00:17:35,050
+المكافئة لها، تمام؟ مين النقطة المكافئة لها؟ خليت
+
+155
+00:17:35,050 --> 00:17:40,170
+r هنا بالسالب و في المقابل أضفت هنا by وهذا ما
+
+156
+00:17:40,170 --> 00:17:44,850
+ذكرناه في المحاضرة الماضية، مظبوط؟ طيب كويس، بجيبه
+
+157
+00:17:44,850 --> 00:17:51,520
+ليا إما r وناقص θيا إما سالب r وبع ناقص θ تتقع
+
+158
+00:17:51,520 --> 00:17:56,460
+الملحوظة هذه أو تلك السؤال الذي يدور في دماغ
+
+159
+00:17:56,460 --> 00:18:02,530
+الكثير منكم طب من وين هذه اجت؟ نزلت بالبراشوت والله
+
+160
+00:18:02,530 --> 00:18:09,490
+إلها قاعدة علمية تعال تطلع معايا كويس هنا لو جيت
+
+161
+00:18:09,490 --> 00:18:16,130
+قلت هاي المحاور هذا اللي هو محور x وهذا محور y أو
+
+162
+00:18:16,130 --> 00:18:22,370
+θ تساوي 0 و θ تساوي π على 2 كارتيزي أو بولر
+
+163
+00:18:22,370 --> 00:18:31,100
+ونفترض إن هذه النقطة لـ p r و θ وقعت وين؟ على
+
+164
+00:18:31,100 --> 00:18:37,780
+المنحنى روحت وصلت منها لنقطة الأصل فكان هذا r و
+
+165
+00:18:37,780 --> 00:18:43,560
+الزاوية هذه هي الزاوية θ لصناعة مع الاتجاه الموجب
+
+166
+00:18:43,560 --> 00:18:49,620
+لل polar axis بقول كويس أنا بدي أدعي أن هذا المنحنى
+
+167
+00:18:49,620 --> 00:18:55,260
+متمثل بالنسبة لمحور x يبقى أي نقطة أعلى محور x
+
+168
+00:18:55,260 --> 00:19:02,420
+ستظهر نقطة أسفل محور x وعلى نفس البعد تبع النقطة
+
+169
+00:19:02,420 --> 00:19:09,140
+لأن هذه r و θ بمعنى آخر لو جيت نزلت عمود من هنا على
+
+170
+00:19:09,140 --> 00:19:16,470
+محور x ومديته على استقامته بقدر طوله للنقطة هذه و
+
+171
+00:19:16,470 --> 00:19:20,330
+جيت وصلت بالشكل اللي عندنا هذا بدي يكون هذا r
+
+172
+00:19:20,330 --> 00:19:25,770
+هذا r لكن الزاوية اللي مشيناها زاوية مالها سالبة
+
+173
+00:19:25,770 --> 00:19:30,330
+يبقى هذه ناقص θ بيصير النقطة هذه إحداثياتها
+
+174
+00:19:30,330 --> 00:19:38,970
+r وناقص θ أو النقطة المكافئة لها هي مين النقطة
+
+175
+00:19:38,970 --> 00:19:43,690
+اللي بتكافئها تماما ممكن أخلي هذه بالسالب وأروح ل
+
+176
+00:19:43,690 --> 00:19:49,630
+θ أضفلها اللي هو 180 درجة هي مين يبقى
+
+177
+00:19:49,630 --> 00:19:54,180
+واضحة ليش شيلت θ وحطيت مكانها ناقص θ السبب
+
+178
+00:19:54,180 --> 00:19:57,820
+أن هذه كانت فوق صارت تحت بالشكل اللي
+
+179
+00:19:57,820 --> 00:20:03,440
+عندنا هذا فقلنا r و θ لو وقعت على المنحنى لازم
+
+180
+00:20:03,440 --> 00:20:08,280
+النقطة r و ناقص θ أو النقطة المكافئة لها هذه
+
+181
+00:20:08,280 --> 00:20:13,320
+ما لها تقع على المنحنى إيش يعني؟ طب ليش هذه أو
+
+182
+00:20:13,320 --> 00:20:17,160
+هذه؟ بنقولك المرة اللي خدنا مثال كان المثال
+
+183
+00:20:17,160 --> 00:20:20,720
+بيقول لي السؤال هو هل هذه النقطة تقع على المنحنى
+
+184
+00:20:20,720 --> 00:20:25,410
+ولا لا مش هيك السؤال كام؟ وروحنا أخذنا θ اللي
+
+185
+00:20:25,410 --> 00:20:28,950
+أطالينا وعوضت في المسألة ما طلعتش هي أعري اللي
+
+186
+00:20:28,950 --> 00:20:32,430
+موجودة عندنا وقلنا طب استنى شوية نجيب النقطة
+
+187
+00:20:32,430 --> 00:20:35,110
+المكافئة لها فروحنا جبنا النقطة المكافئة لها
+
+188
+00:20:35,110 --> 00:20:39,290
+لقينا تقع إيه؟ على المنحنى، لذلك باجي بقول لو
+
+189
+00:20:39,290 --> 00:20:43,730
+النقطة هذه لقيتها على المنحنى، بيكون خلاص كفى الله
+
+190
+00:20:43,730 --> 00:20:46,740
+في المؤمنين القتال، ما لاقيتهاش يبقى إذا كنت تروح
+
+191
+00:20:46,740 --> 00:20:50,860
+تجيب  النقطة المكافئة لأن ما لقتهاش يبقى
+
+192
+00:20:50,860 --> 00:20:57,140
+المنحنى غير متمثل بالنسبة لنقطة الأصل طيب إيش معنى
+
+193
+00:20:57,140 --> 00:21:01,520
+تمثل بالبلدي هيك يعني من استوعبها؟ بقولك بسيطة جدا
+
+194
+00:21:03,060 --> 00:21:08,320
+كيف بسيطة جدا؟ لو جيت على معادلة المنحنى وشيلت كل
+
+195
+00:21:08,320 --> 00:21:14,080
+θ وحطيت مكانها سالب θ ولاقيت المعادلة بقيت كما هي
+
+196
+00:21:14,080 --> 00:21:19,310
+دون تغيير، إذا المنحنى متمثل بالنسبة لها معادلة x طب
+
+197
+00:21:19,310 --> 00:21:23,770
+لجيتها مش هي المعادلة المطابقة عند الأصلية بروح
+
+198
+00:21:23,770 --> 00:21:29,490
+للنقطة المكافئة لها وبشيل كل θ وبحط مكانها بإناقص
+
+199
+00:21:29,490 --> 00:21:33,010
+θ وبفك المعادلة اللي عندي إن طلعت المعادلة
+
+200
+00:21:33,010 --> 00:21:38,150
+الأصلية دون تغيير بقول المنحنى متمثل بالنسبة لمحور
+
+201
+00:21:38,150 --> 00:21:42,750
+x إذا ما طلعتش المعادلة يعني التنتين النقطتين وما
+
+202
+00:21:42,750 --> 00:21:49,210
+وجدتهمش يبقى المنحنى غير متماثل بالنسبة لمحور x طب
+
+203
+00:21:49,210 --> 00:21:53,930
+نيجي للنقطة الثانية محور y بنفس المفهوم إذا أنا
+
+204
+00:21:53,930 --> 00:22:00,650
+بدي أخد المحاور عندي بهذا الشكل هذا محور x وهذا
+
+205
+00:22:00,650 --> 00:22:07,570
+محور y أو θ تساوي Zero وهنا θ تساوي π على
+
+206
+00:22:07,570 --> 00:22:14,290
+2 وهذه النقطة p r و θ اللي كنا بنتكلم عليها
+
+207
+00:22:14,290 --> 00:22:21,750
+قبل قليل وهذه r وهذه الزاوية اليمين هي θ ما قلت
+
+208
+00:22:21,750 --> 00:22:26,370
+مثل بالنسبة لمحور y يبقى النقطة اللي وقعت عليها من
+
+209
+00:22:26,370 --> 00:22:32,250
+اليمين لازم ألاقي نقطة على شمال المحور وعلى نفس
+
+210
+00:22:32,250 --> 00:22:36,970
+البعد بالشكل اللي عندنا هذا، دي النقطة دي، هدول
+
+211
+00:22:36,970 --> 00:22:43,770
+اتنين جت بعض زي ما هدول المسافتين جت بعض تماما بقول
+
+212
+00:22:43,770 --> 00:22:48,390
+أيوه يبقى لو جيت وصلت بالشكل اللي عندنا هذا بتبقى
+
+213
+00:22:48,390 --> 00:22:52,690
+الزاوية هذه من ناحية المقدار هذه θ إذا الزاوية
+
+214
+00:22:52,690 --> 00:23:00,050
+هذه كلها π ناقص θ يعني الزاوية اللي بيعملها
+
+215
+00:23:00,050 --> 00:23:06,310
+r مع مين مع الاتجاه الموجب لل polar axis يبقى لو
+
+216
+00:23:06,310 --> 00:23:12,690
+وقعت النقطة p r و θ على المنحنى فإن النقطة r و π
+
+217
+00:23:12,690 --> 00:23:20,550
+ناقص θ تقع على المنحنى r النقطة المكافئة لها سالب
+
+218
+00:23:20,550 --> 00:23:28,990
+r وهنا سنذهب ونضيف π كم يصبح هذا؟ 2π ناقص
+
+219
+00:23:28,990 --> 00:23:33,690
+θ، مظبوط؟ يبقى بيصير عندي الزاوية 2π ناقص
+
+220
+00:23:33,690 --> 00:23:38,660
+θ، بقول استنى شوية لـ 4 نسب مثلثية sin
+
+221
+00:23:38,660 --> 00:23:44,420
+و cos و sec و cosec ال period إلها 2π يعني
+
+222
+00:23:44,420 --> 00:23:48,140
+لو كان عند أي واحدة من النسب الأربعة شيلت 2π والله
+
+223
+00:23:48,140 --> 00:23:52,420
+تخليها ما تفرقش عندنا طب لو كانت tan أو cot ال
+
+224
+00:23:52,420 --> 00:23:56,960
+period π واحدة يبقى 2π معناته ال period مرتين
+
+225
+00:23:56,960 --> 00:24:01,570
+برضه شيلتها يبقى بدنا نشيلها ونريح دماغنا يبقى لو
+
+226
+00:24:01,570 --> 00:24:07,450
+شيلناها بنحط ناقص r وناقص θ تقع على المنحنى يا إما
+
+227
+00:24:07,450 --> 00:24:10,790
+النقطة هذه يا إما النقطة هذه يعني إيه؟ يعني لو
+
+228
+00:24:10,790 --> 00:24:15,290
+شيلنا θ وحطينا مكانها π ناقص θ طلعت المعادلة
+
+229
+00:24:15,290 --> 00:24:19,730
+الأصلية تبع المنحنى اللي هي r نقوله خلاص متمثل
+
+230
+00:24:19,730 --> 00:24:24,130
+بالنسبة لمحور y ما طلعت ما نقوله استنى شوية بنروح
+
+231
+00:24:24,130 --> 00:24:28,070
+على مين على θ بنشيله ونحط مكانه ناقص θ إن طلعت
+
+232
+00:24:28,070 --> 00:24:33,000
+سالب r بنقول في تماثل بالنسبة لمحور y ما طلعتش يبقى
+
+233
+00:24:33,000 --> 00:24:37,920
+ما فيش تماثل خالص للنقطة الأولى ولا للنقطة الثانية
+
+234
+00:24:37,920 --> 00:24:42,100
+يبقى هذا معنى التماثل بالنسبة لمحور y بنيجي
+
+235
+00:24:42,100 --> 00:24:47,100
+للتماثل بالنسبة لنقطة الأصل يبقى باجي بقوله هاي
+
+236
+00:24:47,100 --> 00:24:55,650
+المحاور وهذا محور x أو θ تساوي Zero وهذا محور y
+
+237
+00:24:55,650 --> 00:25:04,350
+أو θ تساوي π على 2 وهذه النقطة p, r و θ
+
+238
+00:25:04,350 --> 00:25:10,110
+وهذه r لنقطة الأصل وهذه الزاوية θ اللي هي
+
+239
+00:25:10,110 --> 00:25:16,990
+المطلوبة فأنا بلاك هنا لما قاعد أقول أنا واقف الآن
+
+240
+00:25:16,990 --> 00:25:21,360
+في نقطة الأصل وعندي نقطة على اليمين من الجلم الأزرق
+
+241
+00:25:21,360 --> 00:25:27,680
+هذا تمام؟ مالها؟ هذه نقطة موجودة على المنحنى فيه
+
+242
+00:25:27,680 --> 00:25:32,680
+تماثل عندي بالنسبة لنقطة الأصل إذا ستظهر نقطة من
+
+243
+00:25:32,680 --> 00:25:37,960
+الناحية الثانية وعلى نفس البعد يبقى امتداد لمين؟
+
+244
+00:25:37,960 --> 00:25:41,900
+امتداد لل r اللي عندنا بسوان في الناحية الثانية
+
+245
+00:25:41,900 --> 00:25:46,400
+لما كان هذا r إيش بدي يكون هذا؟ سالب r لكن فيه
+
+246
+00:25:46,400 --> 00:25:52,410
+تزايمهين تمام؟ يبقى هذا r و θ يبقى تظهر نقطة علم
+
+247
+00:25:52,410 --> 00:25:58,610
+تداده بالضغط بالشكل اللي عندنا هناك تمام؟ يبقى هذه
+
+248
+00:25:58,610 --> 00:26:05,090
+النقطة بيصير ناقص r و θ تقع على المنحنى أو النقطة
+
+249
+00:26:05,090 --> 00:26:11,370
+المكافئة لها شو النقطة المكافئة لها؟ بدنا نشيل r
+
+250
+00:26:11,370 --> 00:26:16,530
+السالبة ونحط بدالها r الموجبة ونروح على θ و
+
+251
+00:26:16,530 --> 00:26:22,060
+نُنظِفها جدًّا شوي، إن حدث ذلك يبقى فيه تماثل ما
+
+252
+00:26:22,060 --> 00:26:28,580
+هظبطش هذه، بنروح نشيل θ ونحط مكانها θ زائد باي إذا
+
+253
+00:26:28,580 --> 00:26:33,940
+طلع عندي R الأصلية، بيكون عندي المنحنى متماثل ما
+
+254
+00:26:33,940 --> 00:26:39,320
+طلعت إيه، بيكون ما عنديش تماثل بالنسبة لنقطة الأصل
+
+255
+00:26:39,320 --> 00:26:43,800
+طيب، بقيت نقطة أخيرة، الملاحظة اللي احنا كاتبينها هنا
+
+256
+00:26:43,800 --> 00:26:48,310
+تحتها، أخدت أي two symmetries اتحقق اتنين
+
+257
+00:26:48,310 --> 00:26:54,530
+automatically التالت متحقق، يعني لو كان في تماثل بالنسبة
+
+258
+00:26:54,530 --> 00:26:58,470
+لـ X و تماثل بالنسبة لـ Y، إذا هناك تماثل بالنسبة لمين؟
+
+259
+00:26:58,470 --> 00:27:03,030
+للـ origin والعكس، لو كان تماثل بالنسبة للـ origin و
+
+260
+00:27:03,030 --> 00:27:07,670
+تماثل بالنسبة لـ X، يبقى في تماثل بالنسبة لمحور Y و
+
+261
+00:27:07,670 --> 00:27:14,150
+هكذا تمام؟ قبل أن نأخذ أمثلة تطبيقية على ذلك فيها
+
+262
+00:27:14,150 --> 00:27:18,790
+أن بقية نقطة نظرية في هذا الـ section وهي الـ slope
+
+263
+00:27:18,790 --> 00:27:24,910
+تبع المنحنى، بدنا نروح نكتفي بهذه النقطة، ومن ثم نذهب
+
+264
+00:27:24,910 --> 00:27:30,170
+إلى الأمثلة، يبقى النقطة الثانية والأخيرة من هذا الـ
+
+265
+00:27:30,170 --> 00:27:38,270
+section اللي هو الـ slope، فبجي بقول if R تساوي F of
+
+266
+00:27:38,270 --> 00:27:50,150
+θ and الـ X يساوي R cosine θ أو الـ F of θ cosine θ
+
+267
+00:27:50,150 --> 00:27:58,430
+و الـ Y يساوي R في ساين الزاوية θ أو F of θ في ساين 
+
+268
+00:27:58,430 --> 00:28:10,790
+الزاوية θ and if الـ F is differentiable function
+
+269
+00:28:10,790 --> 00:28:17,370
+of θ then هاي
+
+270
+00:28:17,370 --> 00:28:22,030
+الجزء هذا، بالذات إلى الـ slope، الـ slope اللي عنده
+
+271
+00:28:22,030 --> 00:28:28,220
+اللي هو main دي Y على دي X، الـ dy على dx، كل واحدة
+
+272
+00:28:28,220 --> 00:28:38,740
+فيهم دالة في θ، يبقى بأقدر أكتبها dy على dθ على dx
+
+273
+00:28:38,740 --> 00:28:47,820
+على dθ، بشرط أن dx على dθ ما له؟ لا تساوي zero، طب
+
+274
+00:28:47,820 --> 00:28:54,040
+كويس، يبقى صار له slope بده يساوي، بدنا نيجي لـ dy
+
+275
+00:28:54,040 --> 00:29:00,800
+على d theta هذه، كويس، يبقى بدنا نشتقها، لو اشتقناها
+
+276
+00:29:00,800 --> 00:29:06,260
+هذه دالة وهذه دالة، إذا المشتق بتحاصل ضرب دالتين
+
+277
+00:29:06,260 --> 00:29:13,360
+مشتقة الدالة الأولى Df على Dθ في الـ sine الزاوية
+
+278
+00:29:13,360 --> 00:29:20,260
+ثيتا زائد F of ثيتا كما هي ومشتقة الـ sine بيكوساين 
+
+279
+00:29:20,260 --> 00:29:28,110
+الزاوية ثيتا، هذا مين؟ هذا dy على dθ، بدنا dx
+
+280
+00:29:28,110 --> 00:29:37,790
+على dθ، يبقى df على dθ في cosine الزاوية θ ناقص
+
+281
+00:29:37,790 --> 00:29:43,710
+اللي هو f of θ في sine الزاوية θ، لأن تفاضل الـ
+
+282
+00:29:43,710 --> 00:29:49,650
+cosine بمين؟ بسالب sin، حابين نكتبها بدلالة الـR
+
+283
+00:29:49,650 --> 00:29:56,510
+ماعلناش مانع، يبقى هذه تساوي R في ساين الزاوية ثيتا
+
+284
+00:29:56,510 --> 00:30:03,150
+زائد طبعًا R prime في ساين الزاوية ثيتا زائد R في
+
+285
+00:30:03,150 --> 00:30:08,690
+كوساين الزاوية ثيتا، كله على R prime في كوساين
+
+286
+00:30:08,690 --> 00:30:16,680
+الزاوية ثيتا ناقص R في ساين الزاوية ثيتا، طب لو جينا
+
+287
+00:30:16,680 --> 00:30:22,900
+حسبنا الـ slope عند نقطة الأصل، عند نقطة الأصل،
+
+288
+00:30:22,900 --> 00:30:28,320
+يبقى بدي أقعد أياخد الـ slope عند نقطة الأصل، قداش
+
+289
+00:30:28,320 --> 00:30:30,280
+إحداثي نقطة الأصل؟
+
+290
+00:30:33,480 --> 00:30:38,060
+زيرو و ثيتا نود، ورسمنا المرة الماضية وحطينا سؤال
+
+291
+00:30:38,060 --> 00:30:44,980
+للرسم، فطلعت نقطة الأصل زيرو و ثيتا نود، بده يساوي إذا
+
+292
+00:30:44,980 --> 00:30:49,380
+بده يشيل كل R ويحط مكانها زيرو، ويشيل كل ثيتا ويحط
+
+293
+00:30:49,380 --> 00:30:55,710
+مكانها ثيتا نود، أظن زيرو زيرو هدول بيروحوا، مش هيك؟
+
+294
+00:30:55,710 --> 00:31:03,510
+بيبقى لدي هنا R prime sine theta node على R prime
+
+295
+00:31:03,510 --> 00:31:09,210
+cosine theta node، هذه هتروح مع هذه، يبقى هذا بدي
+
+296
+00:31:09,210 --> 00:31:16,070
+أخيلك أن الـ slope عند نقطة الأصل اللي هو زيرو و
+
+297
+00:31:16,070 --> 00:31:23,390
+theta node بدي أساويه tan theta node، يبقى جميل
+
+298
+00:31:23,390 --> 00:31:30,170
+المنحنى عند نقطة الأصل هو عبارة عن تان في تان نود.
+
+299
+00:31:30,450 --> 00:31:36,770
+تمام؟ حد بدّه يسأل لي سؤال قبل أن نذهب إلى الأمثلة؟
+
+300
+00:31:36,770 --> 00:31:39,390
+طيب، نذهب إلى الأمثلة.
+
+301
+00:32:08,180 --> 00:32:12,420
+المثال الأول examples
+
+302
+00:32:21,330 --> 00:32:34,130
+بقول find the slope of the curve R يساوي واحد ناقص
+
+303
+00:32:34,130 --> 00:32:45,170
+cosine زاوية theta at the point عند النقطة اللي هو
+
+304
+00:32:45,170 --> 00:32:53,160
+where theta يساوي ناقص by على اتنين، solution
+
+305
+00:33:03,470 --> 00:33:08,250
+السؤال بيقول ايه؟ هيوجدنا من الـ slope الموجودة في الصيغة R
+
+306
+00:33:08,250 --> 00:33:12,830
+تساوي واحد ناقص cosine الزاوية ثيتا عند النقطة
+
+307
+00:33:12,830 --> 00:33:18,770
+الـ ثيتا عندها تساوي سالب باي على اتنين، بقول له بسيطة
+
+308
+00:33:18,770 --> 00:33:25,440
+الـ slope هيوجدنا هناك، يبقى باجي بقول له الـ slope اللي
+
+309
+00:33:25,440 --> 00:33:32,220
+هو بدّه يساوي، اللي هو مين؟ دي F على دي ثيتا، والله
+
+310
+00:33:32,220 --> 00:33:37,140
+يشعرك أن أعوض دوري، أن أعوض دوري، ماشي يا سيدي،
+
+311
+00:33:37,140 --> 00:33:42,820
+وين الـ F؟ هيها R هي function فيه ثيتا، ده مشتقتها كدهش؟
+
+312
+00:33:42,820 --> 00:33:48,040
+الواحد بـ zero والـ cosine بالسالب sine، بـ cosine
+
+313
+00:33:48,040 --> 00:33:59,320
+ثيتا، يبقى sin θ في sin θ زائد الـ F اللي هو واحد ناقص cos
+
+314
+00:33:59,320 --> 00:34:08,690
+θ في مين؟ في cos θ، كل هذا الكلام على df على dθ اللي
+
+315
+00:34:08,690 --> 00:34:16,390
+هي sin θ في cos θ ناقص الـ F اللي هي واحد ناقص cos
+
+316
+00:34:16,390 --> 00:34:25,010
+θ في مين؟ في sin θ، تمامًا زي ما هلكات ميلابنروح نحسب
+
+317
+00:34:25,010 --> 00:34:32,310
+للـ slope هذا، وأجدش عندما θ تساوي سالب بي على اتنين
+
+318
+00:34:32,310 --> 00:34:39,170
+إذا هشيل كل θ وأحط مكانها سالب بي على اتنين، يبقى
+
+319
+00:34:39,170 --> 00:34:45,890
+صار sign تربيع لسالب بي على اتنين، sin في sin في sin
+
+320
+00:34:45,890 --> 00:34:52,850
+تربيع، وهذه زائد واحد ناقص cos لسالب بي على اتنين
+
+321
+00:34:52,850 --> 00:35:00,830
+في cos لسالب بي على اتنين، كله sin لسالب بي على
+
+322
+00:35:00,830 --> 00:35:08,530
+اتنين cos لسالب بي على اتنين، واحد ناقص cos لسالب
+
+323
+00:35:08,530 --> 00:35:16,730
+بي على اتنين في sin لسالب بي على اتنين، أنا الكلام
+
+324
+00:35:16,730 --> 00:35:22,670
+يساوي، لأن الـ sign even والـ cosine odd، يعني السالب بيطلع
+
+325
+00:35:22,670 --> 00:35:30,150
+برا، يبقى sign التسعين قداش؟ قداش sign التسعين؟
+
+326
+00:35:30,150 --> 00:35:35,210
+يبقى هاي السالب برا وهي الواحد تربيع، يبقى هاي تربيع
+
+327
+00:35:35,210 --> 00:35:43,010
+اللي بعدها، زائد واحد ناقص cosine even والـ sine odd
+
+328
+00:35:43,730 --> 00:35:48,810
+يبقى السالب انسى، فده الـ cosine value كده؟ بزيرو،
+
+329
+00:35:48,810 --> 00:35:53,270
+يبقى واحد ناقص زيرو، فمين في الـ cosine الـ zero
+
+330
+00:35:53,270 --> 00:35:58,970
+اللي هو بزيرو، على مين؟ على المقام، هذا اللي هو
+
+331
+00:35:58,970 --> 00:36:06,290
+بسالب واحد، وهذا بزيرو، وهذا ناقص واحد، ناقص زيرو،
+
+332
+00:36:06,290 --> 00:36:12,370
+كله في سالب واحد، يبقى النتيجة وتساوي واحد على واحد
+
+333
+00:36:12,370 --> 00:36:17,110
+ويساوي واحد. إذا الـ slope تبع المنحنى اللي عندنا كان
+
+334
+00:36:17,110 --> 00:36:23,890
+يساوي قداش؟ كان يساوي واحد صحيح، على أي حال الآن
+
+335
+00:36:23,890 --> 00:36:27,270
+بدنا نروح للمثال اتنين، وهو الرسم
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/dDx0Ho9ebxY_postprocess.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/dDx0Ho9ebxY_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8f882a4f9a723e032850e3626214b25e8d99cf45
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/dDx0Ho9ebxY_postprocess.srt
@@ -0,0 +1,1340 @@
+1
+00:00:12,060 --> 00:00:18,680
+نكمل سيكشن 11-3 اللى ابتدأنا فيه المرة الماضية وهو
+
+2
+00:00:18,680 --> 00:00:23,210
+ال polar coordinatesالمرة الفاتة كنا بنحول نقطة من
+
+3
+00:00:23,210 --> 00:00:26,830
+polar coordinates إلى cartesian coordinates والعكس
+
+4
+00:00:26,830 --> 00:00:29,330
+نقطة من cartesian coordinates إلى polar
+
+5
+00:00:29,330 --> 00:00:33,450
+coordinates ثم معادلات نحولها من polar coordinates
+
+6
+00:00:33,450 --> 00:00:38,070
+إلى cartesian coordinatesباقي علينا مثال هى و بدنا
+
+7
+00:00:38,070 --> 00:00:42,810
+ناخده مثال أربعة اللى هو بيقول replace the
+
+8
+00:00:42,810 --> 00:00:45,730
+following Cartesian equation by its equivalent
+
+9
+00:00:45,730 --> 00:00:50,710
+polar equations يبقى احنا بدنا نروح نحول المعادلات
+
+10
+00:00:50,710 --> 00:00:55,290
+الكارتيزية اللى عندنا الى معادلات قطبية على أكس
+
+11
+00:00:55,290 --> 00:01:00,930
+آخر مثال أخدناه المرة الماضيةيبدأ المعادلات مواطعة
+
+12
+00:01:00,930 --> 00:01:05,070
+في الصيغة الكارتزية بدي أحولها إلى الصيغة القطبية
+
+13
+00:01:05,070 --> 00:01:09,730
+بدي أذكر تذكير بالمعادلة تبعات التحويل قبل أن نبدأ
+
+14
+00:01:09,730 --> 00:01:14,570
+التحويل اللي مكتوب معاكم في المرة الماضية أخدنا
+
+15
+00:01:14,570 --> 00:01:19,330
+المعادلة الأولى فكانت المعادلة الأولى X يساوي R في
+
+16
+00:01:19,330 --> 00:01:26,380
+Cos الزاوية ثيتا وY تساوي R في Sin الزاوية ثيتاومن
+
+17
+00:01:26,380 --> 00:01:31,640
+هاتين المعادلتين كنا بناخد إحداثي قديم x و y
+
+18
+00:01:31,640 --> 00:01:37,340
+بدلالة إحداثيين إجداد اللي هم r و theta هناخد الآن
+
+19
+00:01:37,340 --> 00:01:41,640
+اللي هو إحداثي جديد بدلالة الإحداثيين اتنين
+
+20
+00:01:41,640 --> 00:01:48,270
+الأقدامفبجي بقول تان ثيتا بده يساوي Y على X أو ال
+
+21
+00:01:48,270 --> 00:01:55,310
+R تربيع بده يساوي X تربيع زائد Y تربيع تمام؟ يبجي
+
+22
+00:01:55,310 --> 00:01:59,290
+ان R تربيع يساوي X تربيع يبجي هذه المعادلات الأربع
+
+23
+00:01:59,290 --> 00:02:03,740
+اللي من خلالها بنحول من Polar إلى Cartesianأو من
+
+24
+00:02:03,740 --> 00:02:08,620
+كارتيزيا إلى polar يبقى بإذن الله نجيه solution
+
+25
+00:02:08,620 --> 00:02:15,060
+للسؤال الأول نمره ايه؟ بدي أشيل كل y و أحط مكانها
+
+26
+00:02:15,060 --> 00:02:20,740
+r sin θ و أشيل كل x و أحط مكانها r في cosine
+
+27
+00:02:20,740 --> 00:02:25,600
+الزاوية θ تمام؟ يبقى المعادلة اللي بيقولي y تربيها
+
+28
+00:02:25,600 --> 00:02:32,500
+تساوي 4x يبقى عندك ال y بيبقى r في sin الزاوية θ
+
+29
+00:02:33,210 --> 00:02:41,130
+تربيع يبقى لكل تربيع تساوي أربعاء فيه ال X الهي ب
+
+30
+00:02:41,130 --> 00:02:46,950
+R Cos Theta يبقى هي ال R Cos Theta إذا كتبنا
+
+31
+00:02:46,950 --> 00:02:51,570
+المعادلة الكارتزية المعطاة كتبناها في الصيغة
+
+32
+00:02:51,570 --> 00:02:57,690
+القطبيةبنحاول نرتب شكل المعادلة هذه شوية فهذه لو
+
+33
+00:02:57,690 --> 00:03:02,870
+جينا فكتبناها بطريقة أخرى R تربيع في Sin تربيع
+
+34
+00:03:02,870 --> 00:03:10,910
+ثيتا ماقص أربعة R في Cos الزاوية ثيتا يساوي Zero
+
+35
+00:03:10,910 --> 00:03:16,900
+إذا بدنا نحاول ناخدعامل مشترك ونشوف ايش اللي بدي
+
+36
+00:03:16,900 --> 00:03:22,400
+يحصل يبقى لو أخدنا R عامل مشترك بصير عندنا R في
+
+37
+00:03:22,400 --> 00:03:28,260
+sin تربية ثيتا ماقص اربعة كوصين الزاوية ثيتا كله
+
+38
+00:03:28,260 --> 00:03:34,820
+بدي ساوي كده؟ بدي ساوي Zeroهذا معناه يا إما الار
+
+39
+00:03:34,820 --> 00:03:43,320
+بدها تساوي zero يا إما الار بدها تساوي أربعة كوصين
+
+40
+00:03:43,320 --> 00:03:49,550
+ثيتا على مين على صين تربيع ثيتايبقى يا إما هذا
+
+41
+00:03:49,550 --> 00:03:53,990
+بيساوي Zero يا إما القُس هذا بيساوي Zero هذا نجلته
+
+42
+00:03:53,990 --> 00:03:57,290
+على الشجة التانية فصار أربعة كوساين تيتا عالميا
+
+43
+00:03:57,290 --> 00:04:03,990
+على ساين تربيع تيتا أو يا إما ال R بدها تساوي Zero
+
+44
+00:04:03,990 --> 00:04:12,640
+يا إما ال R تساوي الاربعة خليها زي ما هيبدأ أقول
+
+45
+00:04:12,640 --> 00:04:17,940
+cos على sin في 1 على sin cos على sin اللي هي كتان
+
+46
+00:04:17,940 --> 00:04:27,140
+و 1 على sin بكوسيكن يبقى أربعة اللي هو كتان ثيتا
+
+47
+00:04:27,140 --> 00:04:33,530
+كوسيكن تمين كوسيكن ثيتا بالشكل اللي عندنا هذايبقى
+
+48
+00:04:33,530 --> 00:04:37,970
+قلة المعادلة الكارتزية تمثلها معادلتان أخرى يعني
+
+49
+00:04:37,970 --> 00:04:44,040
+هذا بالنسبة للنقطة A بالنسبة للنقطة Bالنقطة B
+
+50
+00:04:44,040 --> 00:04:52,020
+بيقول X ناقص خمسة لكل تربيع زائد Y تربيع يسوى 25
+
+51
+00:04:52,020 --> 00:04:58,340
+طبعا ماعنديش هنا في المعادلات تقول X ناقص خمسة إذا
+
+52
+00:04:58,340 --> 00:05:02,680
+بدأ فك الجثة هدا و نشوف شو اللي بده يحصل معنا إذا
+
+53
+00:05:02,680 --> 00:05:08,800
+لو جيت فكيت الجثة هدا و بده يكون X تربيع ناقص عشرة
+
+54
+00:05:08,800 --> 00:05:16,430
+Xزائد خمسة وعشرين زائد Y تربية كله بدى يساوي كده؟
+
+55
+00:05:16,430 --> 00:05:23,610
+خمسة وعشرين طلع لي كويس هنا بدى اخد X تربية زائد Y
+
+56
+00:05:23,610 --> 00:05:29,710
+تربية مع بعضهم بيظل ناقص عشرة X هذا الكلام بدى
+
+57
+00:05:29,710 --> 00:05:33,630
+يساوي Zero ودينا الخمسة وعشرين عند الخمسة وعشرين
+
+58
+00:05:33,630 --> 00:05:38,330
+يساوي Zeroبعد ما بسطت المعادلة و كتبتها في ثوب
+
+59
+00:05:38,330 --> 00:05:43,610
+جديد او في شكل جديد بدنا نروح نكتبها بالصيغة
+
+60
+00:05:43,610 --> 00:05:49,290
+القطبيةالـ X تربية زي الـ Y تربية جاهزة علنا اللي
+
+61
+00:05:49,290 --> 00:05:55,490
+عبارة عن مين R تربية يبقى هذه R تربية ناقص عشرة
+
+62
+00:05:55,490 --> 00:06:01,150
+وهذه جاهزة R في Cos الزاوية ثيتا يساوي Zero إذا
+
+63
+00:06:01,150 --> 00:06:06,710
+ممكن ناخد R عن المشترك بظل R ناقص عشرة Cos ثيتا
+
+64
+00:06:06,710 --> 00:06:11,090
+بده يساوي Zero يبقى يا إما الـ R بدها تساوي Zero
+
+65
+00:06:11,090 --> 00:06:16,870
+يا إما الـ R بدها تساوي عشرةيوجد كوسايم الزاوية C
+
+66
+00:06:16,870 --> 00:06:22,050
+يعني الشكل هذا أو الشكل هذا لإطنين C يعني توقف إلى
+
+67
+00:06:22,050 --> 00:06:27,990
+هنا انتهى ال section إليكم أربع باعي ال C ولا يهمك
+
+68
+00:06:27,990 --> 00:06:34,670
+أين أمرها Cنمر ال C ممكن اخل ال X و ال Y في الشجة
+
+69
+00:06:34,670 --> 00:06:40,630
+والاعداد في ناحية اخرى يمكن ممكن اقول ال X و Y
+
+70
+00:06:40,630 --> 00:06:49,030
+بدوا يساوي تسعة ارباع او ال X اللي R Cos θ وهذه R
+
+71
+00:06:49,030 --> 00:06:58,430
+Sin θ بدوا يساوي تسعة ارباعممكن اخل ال R تربيه في
+
+72
+00:06:58,430 --> 00:07:06,090
+ناحية و 9 على 4 Sine Theta Cosine Theta يعني جسمنا
+
+73
+00:07:06,090 --> 00:07:10,590
+الطرفين على Sine Theta Cosine Theta لغاية بدها
+
+74
+00:07:10,590 --> 00:07:19,150
+تساوي 9 على 2 Sine 2 Theta يعني الأربعة اعتبرناها
+
+75
+00:07:19,150 --> 00:07:28,760
+هذه 2فى اتنين فى sin θ cos θ sin θ cos θ هذه كلها
+
+76
+00:07:28,760 --> 00:07:34,480
+sin اتنين ثيتا احنا مابدناش R تربيه بدنا R يبقى
+
+77
+00:07:34,480 --> 00:07:42,660
+بروح ندله R تساوي الزائد او ناقص تلاتة على جذر
+
+78
+00:07:42,660 --> 00:07:50,690
+اتنين لمين لsin اتنين ثيتا بهذا الشكليبقى هذا
+
+79
+00:07:50,690 --> 00:07:54,810
+المعادلة القطبية المناظرة للمعادلة الكارثية ال
+
+80
+00:07:54,810 --> 00:07:59,750
+land land هنا stop اليكم ارقام المسائل الخاصة بهذا
+
+81
+00:07:59,750 --> 00:08:07,070
+section وهو section 11 3 يبقى exercises 11 3
+
+82
+00:08:07,070 --> 00:08:16,290
+المسائل التالية من 1 ل 67 اللي هو ال multiple
+
+83
+00:08:18,660 --> 00:08:20,960
+multiple of three
+
+84
+00:08:25,830 --> 00:08:32,730
+طيب ننتقل الان الى ال section اللذي يليه وهو طريقة
+
+85
+00:08:32,730 --> 00:08:38,610
+الرسم في الإحداثيات القطبية بنشوف كيف بنرسم
+
+86
+00:08:38,610 --> 00:08:45,770
+الملحانيات المختلفة في الإحداثيات القطبية وسنقسم
+
+87
+00:08:45,770 --> 00:08:50,970
+هذا ال section أو الجزء النظري لهذا ال section إلى
+
+88
+00:08:50,970 --> 00:08:57,540
+نقطتينالنقطة الأولى اللى هى ال symmetry التماثل
+
+89
+00:08:57,540 --> 00:09:02,800
+والنقطة الثانية اللى هى ال slope يبقى بدنا نجى
+
+90
+00:09:02,800 --> 00:09:07,620
+للنقطة الأولى يبقى graphing in polar coordinates
+
+91
+00:09:07,620 --> 00:09:18,560
+section 11 أربعة graphing in polar coordinates
+
+92
+00:09:22,950 --> 00:09:30,710
+يبقى الرسم في الإحداثيات القطبية اول نقطة في هذا
+
+93
+00:09:30,710 --> 00:09:33,250
+ال section بدنا ندرس هي symmetry
+
+94
+00:09:37,040 --> 00:09:42,780
+بناخد التماثل حوالين محور X أو حوالين ال polar
+
+95
+00:09:42,780 --> 00:09:48,380
+axis ثم التماثل حوالين محور Y أو الخط θ تسوى Y على
+
+96
+00:09:48,380 --> 00:09:55,680
+2 ثم تماثل حوالين نقطة الأصل هذه التماثلات الثلاثة
+
+97
+00:09:55,680 --> 00:10:02,300
+التي سندرسها نبدأ من التماثل الأول التماثل الأول
+
+98
+00:10:02,300 --> 00:10:03,740
+اللي هو ال symmetry
+
+99
+00:10:06,440 --> 00:10:17,580
+about symmetry about the x axis هذا شو معناه؟
+
+100
+00:10:17,580 --> 00:10:32,040
+means that if the point r و theta lies on
+
+101
+00:10:32,040 --> 00:10:42,980
+the graphثم نقطة الهومين
+
+102
+00:10:42,980 --> 00:10:59,220
+ا و سالب ثيتا او سالب ا و باين ناقص ثيتا موجودة
+
+103
+00:10:59,220 --> 00:11:12,510
+على الجرافي النقطة الثانيةسيمتري عن
+
+104
+00:11:12,510 --> 00:11:16,550
+الواي
+
+105
+00:11:16,550 --> 00:11:28,810
+أكسيز يعني أنه إذا كانت النقطة ر أو ثيتا
+
+106
+00:11:43,740 --> 00:11:52,700
+إذا كان الوضع R وثيتا على المقاطع
+
+107
+00:11:52,700 --> 00:11:57,340
+فالوضع
+
+108
+00:11:57,340 --> 00:12:02,380
+R
+
+109
+00:12:02,380 --> 00:12:11,800
+و بي ناقص ثيتا او سلب R و سلب ثيتا
+
+110
+00:12:13,450 --> 00:12:23,310
+on the graph النقطة الثالثة والاخيرة symmetry
+
+111
+00:12:23,310 --> 00:12:27,390
+about
+
+112
+00:12:27,390 --> 00:12:42,890
+the origin شو معناها هذه means that if the point
+
+113
+00:12:45,160 --> 00:12:55,060
+ار وثيتا موجودة على الجرافة
+
+114
+00:12:55,060 --> 00:13:13,120
+ثم نقطة سالب ار وثيتا او ار و باى زائد ثيتا موجودة
+
+115
+00:13:13,120 --> 00:13:14,160
+على الجرافة
+
+116
+00:13:19,910 --> 00:13:34,470
+نقطة مهمة ملاحظة Any two symmetries gives
+
+117
+00:13:34,470 --> 00:13:37,550
+the
+
+118
+00:13:37,550 --> 00:13:44,330
+third symmetry
+
+119
+00:14:37,190 --> 00:14:40,830
+العنوان اللى احنا رافعينه اللى هو graph in polar
+
+120
+00:14:40,830 --> 00:14:47,070
+coordinates الرسم في الإحداثيات الققبية وروحنا
+
+121
+00:14:47,070 --> 00:14:52,510
+أخدنا أول عنوان هو ال symmetry طب استنى شويةأحنا
+
+122
+00:14:52,510 --> 00:14:57,310
+في كل كلصية بقينا ناخد الرسم البياني للمنحنيات بس
+
+123
+00:14:57,310 --> 00:15:02,990
+في الإحداثيات الكارتزية و بقينا نروح على المنحنى و
+
+124
+00:15:02,990 --> 00:15:07,810
+نجيب تقاطعه مع محورية الإحداثيات و بعدين نعمله
+
+125
+00:15:07,810 --> 00:15:11,270
+اشتقاق و نجيب ال local maximum و ال local minimum
+
+126
+00:15:11,270 --> 00:15:14,690
+و ال critical points و ال concave up و ال concave
+
+127
+00:15:14,690 --> 00:15:19,570
+down و ال reflection points و ال asymptotes in وجه
+
+128
+00:15:19,570 --> 00:15:24,030
+ذاته و بعدين بنروح نرسمهينالرسمة بتبعتنا، هذا
+
+129
+00:15:24,030 --> 00:15:28,210
+الكلام عفى عليه الزمن، هذا كنا بنوصف الإحداث
+
+130
+00:15:28,210 --> 00:15:33,470
+الكارتزية، لكن هنا إحداثيات جديدة، موضوع ال
+
+131
+00:15:33,470 --> 00:15:38,210
+symmetryبابل اللي هو الكلام اللي ذكرناه قبل قليل
+
+132
+00:15:38,210 --> 00:15:41,010
+ال local maximum و ال local minimum و ال concave و
+
+133
+00:15:41,010 --> 00:15:45,570
+up و ال inflection و ما إلى ذلك هذا كله سنستعيد
+
+134
+00:15:45,570 --> 00:15:50,970
+عنه مين بالتماثل لما قول تماثل بالنسبة لمحور X لو
+
+135
+00:15:50,970 --> 00:15:55,950
+جيت تخيلت هذا محور X إذا الرسم اللي أعلى محور X
+
+136
+00:15:55,950 --> 00:16:00,220
+بتبقى زي مين؟زي الرصمة اللى أسفل محور X بس مجلوب و
+
+137
+00:16:00,220 --> 00:16:04,060
+بدل ما كانت فوق بيصير ايه تحت هذا معنى التماثل
+
+138
+00:16:04,060 --> 00:16:08,400
+بالنسبة لمحور X تماثل بالنسبة لمحور Y يعني الرصمة
+
+139
+00:16:08,400 --> 00:16:12,140
+اللى على اليمين Z تساوي او زي الرصمة اللى على ميم
+
+140
+00:16:12,140 --> 00:16:17,410
+على الإشمال تماثل بالنسبة لنقطة ال origin فمثلالو
+
+141
+00:16:17,410 --> 00:16:22,930
+قلت أنا واقف في ال origin يبقى أي نقطة على يمين ال
+
+142
+00:16:22,930 --> 00:16:29,390
+origin ستظهر نقطة على شمالها وعلى نفس البعد من
+
+143
+00:16:29,390 --> 00:16:34,650
+نقطة الاصلإن حدث ذلك بيقول في تماثل بالنسبة لما ..
+
+144
+00:16:34,650 --> 00:16:40,670
+لنقطة الأصل، هذا كلام بلدي لكن بدنا نروح نحطه
+
+145
+00:16:40,670 --> 00:16:47,740
+رياضي على أرض الواقع بالرسم والعبارات الرياضيةنمسك
+
+146
+00:16:47,740 --> 00:16:52,000
+النقطة الأولى هي symmetry about the x axis التمثل
+
+147
+00:16:52,000 --> 00:16:56,460
+حول محورك شو معناه؟ معناه that if the point r و
+
+148
+00:16:56,460 --> 00:17:01,900
+theta lies on the graph يعني لو عندي منحنى مرسوم و
+
+149
+00:17:01,900 --> 00:17:07,540
+بدي ابحث هل هوهذا المنحنى متمثل بالنسبة لمحور X
+
+150
+00:17:07,540 --> 00:17:13,380
+ولا لأ باخد اي نقطة موجودة علي مخدتش نقطة بعينها
+
+151
+00:17:13,380 --> 00:17:18,420
+لأ R و ثيتا اي نقطة تقع على المنحنى ان وقعت هذه
+
+152
+00:17:18,420 --> 00:17:24,060
+النقطة على المنحنى يجب ان تقع النقطة R و سالب ثيتا
+
+153
+00:17:24,060 --> 00:17:29,730
+على المنحنى طيب لو هذه ما وقعتشبجيب مين؟ النقطة
+
+154
+00:17:29,730 --> 00:17:35,050
+المكافئة لها، تمام؟ مين النقطة المكافئة لها؟ خلّيت
+
+155
+00:17:35,050 --> 00:17:40,170
+R هنا بالسالم و في المقابل اضفت هنا by وهذا ما
+
+156
+00:17:40,170 --> 00:17:44,850
+ذكرناه في المحاضرة الماضية، مظبوط؟ طيب كويس، بجيبه
+
+157
+00:17:44,850 --> 00:17:51,520
+ليا اما R وناقص θيا اما سالب R وبع ناقص T تتقع
+
+158
+00:17:51,520 --> 00:17:56,460
+الملحانة هذه او تلك السؤال الذي يدور في دماغ
+
+159
+00:17:56,460 --> 00:18:02,530
+الكثير منكم طب من وين هذه أجت؟ نزلتالبراشوت والله
+
+160
+00:18:02,530 --> 00:18:09,490
+إلها قاعدة علمية تعال تطلع معايا كويس هنا لو جيت
+
+161
+00:18:09,490 --> 00:18:16,130
+قلت هاي المحاور هذا اللي هو محور X وهذا محور Y أو
+
+162
+00:18:16,130 --> 00:18:22,370
+θ تساوي 0 و θ تساوي π على 2 كارتيزين أو بولر
+
+163
+00:18:22,370 --> 00:18:31,100
+ونفترض إن هذه النقطةلـ P R و θ وقعت وين؟ على
+
+164
+00:18:31,100 --> 00:18:37,780
+المنحنى روحت وصلت منها لنقطة الأصل فكان هذا R و
+
+165
+00:18:37,780 --> 00:18:43,560
+الزاوية هذه هي الزاوية θ لصناعة مع الاتجاه الموجب
+
+166
+00:18:43,560 --> 00:18:49,620
+لل polar axis بقول كويسأنا بدي أدعي أن هذا المنحنى
+
+167
+00:18:49,620 --> 00:18:55,260
+متمثل بالنسبة لمحور X يبقى أي نقطة أعلى محور X
+
+168
+00:18:55,260 --> 00:19:02,420
+ستظهر نقطة أسفل محور X وعلى نفس البعد تبع النقطة
+
+169
+00:19:02,420 --> 00:19:09,140
+لأن هذه R وZ بمعنى أخر لو جيت نزلت عمود من هنا على
+
+170
+00:19:09,140 --> 00:19:16,470
+محور X ومديته على استقامتهبقدر طوله للنقطة هذه و
+
+171
+00:19:16,470 --> 00:19:20,330
+جيت وصلت بالشكل اللي عندنا هذا بدي يكون هذا main
+
+172
+00:19:20,330 --> 00:19:25,770
+هذا R لكن الزاوية اللي مشيناها زاوية مالها سالبة
+
+173
+00:19:25,770 --> 00:19:30,330
+يبقى هذه ناقص theta بصير النقطة هذه اليحداتي تبعها
+
+174
+00:19:30,330 --> 00:19:38,970
+R وناقص thetaأو النقطة المكافئة لها الهيمين النقطة
+
+175
+00:19:38,970 --> 00:19:43,690
+اللي بتكافئها تماما ممكن اخلي هذه بالسالب و اروح ل
+
+176
+00:19:43,690 --> 00:19:49,630
+theta اضفلها اللي هو مية وتمانين درجة الهيمين يبقى
+
+177
+00:19:49,630 --> 00:19:54,180
+واضحة ليش شيلت theta و حطيت مكانها ناقص thetaالسبب
+
+178
+00:19:54,180 --> 00:19:57,820
+ان هذي كانت طوية صارت طوية صارت تحت بالشكل اللي
+
+179
+00:19:57,820 --> 00:20:03,440
+عندنا هذا فقلنا ار و ثيتا لو وقعت على المنحنة لازم
+
+180
+00:20:03,440 --> 00:20:08,280
+النقطة ار و لاقص ثيتا او النقطة المكافية لها هذي
+
+181
+00:20:08,280 --> 00:20:13,320
+ما لها تقع على المنحنة ايش يعني؟ طب ليش هذي او
+
+182
+00:20:13,320 --> 00:20:17,160
+هذي؟ بنقولك المرة اللي خدنا مثال كان المثال
+
+183
+00:20:17,160 --> 00:20:20,720
+بيقوللي السؤال هو هل هذه النقطة تقع على المنحنة
+
+184
+00:20:20,720 --> 00:20:25,410
+ولا لا مش هيك السؤال كام؟و روحنا أخدنا ثيتا اللي
+
+185
+00:20:25,410 --> 00:20:28,950
+أطالي و عوضت في المسألة ما طلعتش هي أعري اللي
+
+186
+00:20:28,950 --> 00:20:32,430
+موجودة عندنا و قولنا طب استنى شوية نجيب النقطة
+
+187
+00:20:32,430 --> 00:20:35,110
+المكافئة لها فروحنا جيبنا النقطة المكافئة لها
+
+188
+00:20:35,110 --> 00:20:39,290
+لقينا تقع ايه؟ على المنحنى، لذلك باجي بقول لو
+
+189
+00:20:39,290 --> 00:20:43,730
+النقطة هذه لقيتها على المنحنى، بيكون خلاص كفى الله
+
+190
+00:20:43,730 --> 00:20:46,740
+في المؤمنين القتالي، مالاقيتهاشيبقى إذا كنت تروح
+
+191
+00:20:46,740 --> 00:20:50,860
+تجيب main النقطة المكافئة لأن ما لقتهاش يبقى
+
+192
+00:20:50,860 --> 00:20:57,140
+المنحنى غير متمثل بالنسبة لنقطة الاصل طيب إيش معنى
+
+193
+00:20:57,140 --> 00:21:01,520
+تمثل بالبلد هيك يعني من استوعبها؟ بقولك بسيطة جدا
+
+194
+00:21:03,060 --> 00:21:08,320
+كيف بسيطة جدا؟ لو جيت على معادلة المنحلة وشيلت كل
+
+195
+00:21:08,320 --> 00:21:14,080
+θ وحطيت مكانها سالب θ ولاقيت المعادلة بقيت كما هي
+
+196
+00:21:14,080 --> 00:21:19,310
+دون تغيير، إذا المنحلة متمثل بالنسبة لها معورة Xطب
+
+197
+00:21:19,310 --> 00:21:23,770
+لجيتها مش هي المعادلة المطالة عند الأصلية بروح
+
+198
+00:21:23,770 --> 00:21:29,490
+للنقطة المكافئة له و بشيل كل θ و بحط مكانها بإناقص
+
+199
+00:21:29,490 --> 00:21:33,010
+θ و بفك المعادلة اللي عندي ان طلعت المعادلة
+
+200
+00:21:33,010 --> 00:21:38,150
+الأصلية دون تغيير بقول المنحنة متمثل بالنسبة لمحور
+
+201
+00:21:38,150 --> 00:21:42,750
+Xإذا ما طلعتش المعادلة يعني التنتين النقطتين وما
+
+202
+00:21:42,750 --> 00:21:49,210
+وجدتهمش يبقى المنحنة غير متماثل بالنسبة لمحور X طب
+
+203
+00:21:49,210 --> 00:21:53,930
+نيجي للنقطة التانية محور Y بنفس المفهوم إذا أنا
+
+204
+00:21:53,930 --> 00:22:00,650
+بدي أخد المحاور عندي بهذا الشكلهذا محور X وهذا
+
+205
+00:22:00,650 --> 00:22:07,570
+محور Y أو ثيتا تساوي Zero وهنا ثيتا تساوي باي على
+
+206
+00:22:07,570 --> 00:22:14,290
+اتنين وهذه النقطة PR وثيتا اللى كنا بنتكلم عليها
+
+207
+00:22:14,290 --> 00:22:21,750
+قبل قليل وهذه R وهذه الزاوية اليمين هي ثيتالما قلت
+
+208
+00:22:21,750 --> 00:22:26,370
+مثل بالنسبة لمحور Y يبقى النقطة اللي وقعت عليها من
+
+209
+00:22:26,370 --> 00:22:32,250
+المحور لازم ألاقي نقطة على شمال المحور وعلى نفس
+
+210
+00:22:32,250 --> 00:22:36,970
+البعد بالشكل اللي عندنا هذا، دي النقطة دي، هدول
+
+211
+00:22:36,970 --> 00:22:43,770
+اتنين جت بعض زي ما هدول المسافتين جت بعض تمامابقول
+
+212
+00:22:43,770 --> 00:22:48,390
+ايوة يبقى لو جيت وصلت بالشكل اللي عندنا هذا بتبقى
+
+213
+00:22:48,390 --> 00:22:52,690
+الزاوية هذه من ناحية المقدار هذه ثيتا اذا الزاوية
+
+214
+00:22:52,690 --> 00:23:00,050
+هذه كلها باي ناقص ثيتا يعني الزاوية اللي بيعملها
+
+215
+00:23:00,050 --> 00:23:06,310
+لار مع مين مع الاتجاه الموجب لل polar axisيبقى لو
+
+216
+00:23:06,310 --> 00:23:12,690
+وقعت النقطة PR و θ على المنحلة فإن النقطة R وπ
+
+217
+00:23:12,690 --> 00:23:20,550
+ناقص θ تقع على المنحلة R النقطة المكافئة لها سالب
+
+218
+00:23:20,550 --> 00:23:28,990
+R وهنا سنذهب ونضيف باي كم يصبح هذا؟ اتنين باي ناقص
+
+219
+00:23:28,990 --> 00:23:33,690
+ثيتا، مظبوط؟ يبقى بصير عندي الزاوية اتنين باي ناقص
+
+220
+00:23:33,690 --> 00:23:38,660
+ثيتا، بقول استنى شويةلأربع نسب مُثلثية الصين
+
+221
+00:23:38,660 --> 00:23:44,420
+والكوسين والسكت والكوسيكت ال period إلها 2π يعني
+
+222
+00:23:44,420 --> 00:23:48,140
+لو كان عند أي واحدة من النسب الأربعة شيلت 2π والله
+
+223
+00:23:48,140 --> 00:23:52,420
+تخليها ماتفرجش عندنا طب لو كانتان أو كتان ال
+
+224
+00:23:52,420 --> 00:23:56,960
+period باي واحدة يبقى 2π معناته ال period مرتين
+
+225
+00:23:56,960 --> 00:24:01,570
+برضه شيلتها يبقى بدنا نشيلها و نريح دماغنايبقى لو
+
+226
+00:24:01,570 --> 00:24:07,450
+شيلناها بنحط ناقص R وناقص θ تقع على المنحنى يا إما
+
+227
+00:24:07,450 --> 00:24:10,790
+النقطة هذه يا إما النقطة هذه يعني إيه؟ يعني لو
+
+228
+00:24:10,790 --> 00:24:15,290
+شيلنا θ وحطينا مكانها by ناقص θ طلعت المعادلة
+
+229
+00:24:15,290 --> 00:24:19,730
+الأصلية تبع المنحنى اللي هي R نقوله خلاص متمثل
+
+230
+00:24:19,730 --> 00:24:24,130
+بالنسبة لمحور Y ما طلعت ما نقوله استنى شوية بنروح
+
+231
+00:24:24,130 --> 00:24:28,070
+على مين على θ بنشيله ونحط مكانه ناقص θ ان طلعت
+
+232
+00:24:28,070 --> 00:24:33,000
+سالب Rبنقول في تماثل بالنسبة لمحور Y ما طلعتش يبقى
+
+233
+00:24:33,000 --> 00:24:37,920
+مافيش تماثل خالص للنقطة الأولى ولا للنقطة الثانية
+
+234
+00:24:37,920 --> 00:24:42,100
+يبقى هذا معنى التماثل بالنسبة لمحور Y بنانيج
+
+235
+00:24:42,100 --> 00:24:47,100
+التماثل بالنسبة لنقطة الأصل يبقى باجي بقوله هاي
+
+236
+00:24:47,100 --> 00:24:55,650
+المحاوروهذا محور X أو ثيتا تساوي Zero وهذا محور Y
+
+237
+00:24:55,650 --> 00:25:04,350
+أو ثيتا تساوي باي على اتنين وهذه النقطة P, R وثيتا
+
+238
+00:25:04,350 --> 00:25:10,110
+وهذه R لنقطة الأصل وهذه الزاوية ثيتا اللي هي
+
+239
+00:25:10,110 --> 00:25:16,990
+المولة فانا بلاك هنا لما قاعد أقول أنا واقف الآن
+
+240
+00:25:16,990 --> 00:25:21,360
+في نقطة الأصلوعندي نقطة على اليمين من الجلم الأزرق
+
+241
+00:25:21,360 --> 00:25:27,680
+هذا تمام؟ ماله؟ هذه نقطة موجودة على المنحلة فيه
+
+242
+00:25:27,680 --> 00:25:32,680
+تماثل عندي بالنسبة لنقطة الأصل إذا ستظهر نقطة من
+
+243
+00:25:32,680 --> 00:25:37,960
+الناحية التانية وعلى نفس البعد يبقى امتداد لمين؟
+
+244
+00:25:37,960 --> 00:25:41,900
+امتداد لل R اللي عندنا بسوان في الناحية التانية
+
+245
+00:25:41,900 --> 00:25:46,400
+لما كان هذا R ايش بدي يكون هذا؟ سالف R لكن فيه
+
+246
+00:25:46,400 --> 00:25:52,410
+تزايمهينتمام؟ يبقى هذا R و θ يبقى تظهر نقطة علم
+
+247
+00:25:52,410 --> 00:25:58,610
+تداده بالضغط بالشكل اللي عندنا هناكتمام؟ يبقى هذه
+
+248
+00:25:58,610 --> 00:26:05,090
+النقطة بيصير ناقص R و θ تقع على الملحنة أو النقطة
+
+249
+00:26:05,090 --> 00:26:11,370
+المكافئة لها شو النقطة المكافئة لها؟ بدنا نشيل R
+
+250
+00:26:11,370 --> 00:26:16,530
+السلبة و نحط بدالها R الموجبة و نروح على θ و
+
+251
+00:26:16,530 --> 00:26:22,060
+ننظفلها جداشباى، إن حدث ذلك يبقى فيه تماثل ما
+
+252
+00:26:22,060 --> 00:26:28,580
+هظبطش هذه بنروح نشيل θ ونحط مكانها θ زائد باى إذا
+
+253
+00:26:28,580 --> 00:26:33,940
+طلع عندي R الأصلية بيكون عندي المنحنى متماثل ما
+
+254
+00:26:33,940 --> 00:26:39,320
+طلعت ايه بيكون ماعنديش تماثل بالنسبة لنقطة الاصل
+
+255
+00:26:39,320 --> 00:26:43,800
+طيب بقيت نقطة أخيرة الملاحظة اللي احنا كتبينها هنا
+
+256
+00:26:43,800 --> 00:26:48,310
+تحتلو اخدت اي two stereometers اتحقق اتنين
+
+257
+00:26:48,310 --> 00:26:54,530
+automatic التالت متحقق يعني لو كان في تمثل بالنسبة
+
+258
+00:26:54,530 --> 00:26:58,470
+ل X و تمثل بالنسبة ل Y اذا هناك تمثل بالنسبة لمين
+
+259
+00:26:58,470 --> 00:27:03,030
+لل origin والعكس لو كان تمثل بالنسبة لل origin و
+
+260
+00:27:03,030 --> 00:27:07,670
+تمثل بالنسبة ل X يبقى في تمثل بالنسبة لمحور Y و
+
+261
+00:27:07,670 --> 00:27:14,150
+هكذا تمام؟قبل أن ناخد أمثلة تطبيقية على ذلك فيها
+
+262
+00:27:14,150 --> 00:27:18,790
+أن بقية نقطة نظري في هذا ال section وهي ال slope
+
+263
+00:27:18,790 --> 00:27:24,910
+تبعي المنحلة بدنا نروح نكتف هذه النقطة ومن ثم نذهب
+
+264
+00:27:24,910 --> 00:27:30,170
+إلى الأمثلة يبقى النقطة الثانية والأخيرة من هذا ال
+
+265
+00:27:30,170 --> 00:27:38,270
+section اللي هو ال slopeفبجي بقول if R تساوي F of
+
+266
+00:27:38,270 --> 00:27:50,150
+θ and ال X يساوي R cosine θ أو ال F of θ cosine θ
+
+267
+00:27:50,150 --> 00:27:58,430
+و ال Y يساوي R في صين الزاوية θ او F of θ في صين
+
+268
+00:27:58,430 --> 00:28:10,790
+الزاوية θ and ifالـ F is differentiable function
+
+269
+00:28:10,790 --> 00:28:17,370
+of θ then هاي
+
+270
+00:28:17,370 --> 00:28:22,030
+المركز هذا، بالذات إلى الإسلوب، الإسلوب اللي عنده
+
+271
+00:28:22,030 --> 00:28:28,220
+اللي هو main دي Y على دي Xالـ dy على dx كل واحدة
+
+272
+00:28:28,220 --> 00:28:38,740
+فيهم دالة في θ يبقى باقدر اكتبها dy على dθ على dx
+
+273
+00:28:38,740 --> 00:28:47,820
+على dθ بشرط ان dx على dθ مالهالا تساوي zero طب
+
+274
+00:28:47,820 --> 00:28:54,040
+كويس يبقى صار ليه slope بده يساوي بدنا نيجي ل dy
+
+275
+00:28:54,040 --> 00:29:00,800
+على d theta هذه كويس يبقى بدنا نشتاقها لو اشتقناها
+
+276
+00:29:00,800 --> 00:29:06,260
+هذه دالة وهذه دالة إذا المشتق بتحاصل ضربدالتين
+
+277
+00:29:06,260 --> 00:29:13,360
+مشتقة الدالة الأولى Df على Dθ في الـ sine الزاوية
+
+278
+00:29:13,360 --> 00:29:20,260
+ثيتا زائد F of ثيتا كما هي ومشتقة الـ sine بيكو
+
+279
+00:29:20,260 --> 00:29:28,110
+ساين الزاوية ثيتاهذا مين؟ هذا dy على dθ بدنا dx
+
+280
+00:29:28,110 --> 00:29:37,790
+على dθ يبقى df على dθ في cosine الزاوية θ ناقص
+
+281
+00:29:37,790 --> 00:29:43,710
+اللي هو f of θ في sine الزاوية θ لان اتفاض ال
+
+282
+00:29:43,710 --> 00:29:49,650
+cosine بمين؟ بسالب sinحابين نكتبها بدلالة الـR
+
+283
+00:29:49,650 --> 00:29:56,510
+ماعلناش مانع يبقى هذه تساوي R في صين الزاوية ثيتا
+
+284
+00:29:56,510 --> 00:30:03,150
+زائد طبعا R prime في صين الزاوية ثيتا زائد R في
+
+285
+00:30:03,150 --> 00:30:08,690
+كوصين الزاوية ثيتا كله على R prime في كوصين
+
+286
+00:30:08,690 --> 00:30:16,680
+الزاوية ثيتا ماقس R في صين الزاوية ثيتاطب لو جينا
+
+287
+00:30:16,680 --> 00:30:22,900
+حسبنا ال اسلوب عند نقطة الاصل، عند نقطة الاصل،
+
+288
+00:30:22,900 --> 00:30:28,320
+يبقى بدي اقعد ياخد الاسلوب عند نقطة الاصل، قداش
+
+289
+00:30:28,320 --> 00:30:30,280
+احداثي نقطة الاصل؟
+
+290
+00:30:33,480 --> 00:30:38,060
+زيرو وثيتانود ورسمنا المرة الماضية وحطنا سؤال
+
+291
+00:30:38,060 --> 00:30:44,980
+للرسم فطلعت نقطة الاصل زيرو وثيتانود بده يساوي اذا
+
+292
+00:30:44,980 --> 00:30:49,380
+بده يشيل كل R ويحط مكانها زيرو ويشيل كل ثيتا ويحط
+
+293
+00:30:49,380 --> 00:30:55,710
+مكانها ثيتانود اظن زيرو زيرو هدول بيروحوامش هيك؟
+
+294
+00:30:55,710 --> 00:31:03,510
+بيبقى لدي هنا R prime sine theta node على R prime
+
+295
+00:31:03,510 --> 00:31:09,210
+cosine theta node هذه هتروح مع هذه يبقى هذا بدي
+
+296
+00:31:09,210 --> 00:31:16,070
+اختيلك ان الاسلوب عند نقطة الاصل اللي هو zero و
+
+297
+00:31:16,070 --> 00:31:23,390
+theta node بدي ساوي tan theta nodeيبقى جميل
+
+298
+00:31:23,390 --> 00:31:30,170
+المنحنى عند نقطة الأصل هو عبارة عن تان في تانودة.
+
+299
+00:31:30,450 --> 00:31:36,770
+تمام؟ حد بدى يسأل لي سؤال قبل أن نذهب إلى الأمثلة؟
+
+300
+00:31:36,770 --> 00:31:39,390
+طيب، نذهب إلى الأمثلة.
+
+301
+00:32:08,180 --> 00:32:12,420
+المثال الأول examples
+
+302
+00:32:21,330 --> 00:32:34,130
+بقول find the slope of the curve R يساوي واحد ناقص
+
+303
+00:32:34,130 --> 00:32:45,170
+cosine زاوية theta at the point عند النقطة اللي هو
+
+304
+00:32:45,170 --> 00:32:53,160
+where thetaيساوي ناقص by على اتنين solution
+
+305
+00:33:03,470 --> 00:33:08,250
+السؤال بيقول يهتزي من المنحلة الموجودة في الصيغة R
+
+306
+00:33:08,250 --> 00:33:12,830
+تساوي واحد ناقص cosine الزاوية ثيتا عند النقطة
+
+307
+00:33:12,830 --> 00:33:18,770
+الثيتا عندها تساوي سالب باي على اتنين بقوله بسيطة
+
+308
+00:33:18,770 --> 00:33:25,440
+الاسلوب هيوجدنا هناك يبقى باجي بقوله الاسلوباللي
+
+309
+00:33:25,440 --> 00:33:32,220
+هو بده يساوي، اللي هو مين؟ دي F على دي ثيتا، والله
+
+310
+00:33:32,220 --> 00:33:37,140
+يشعرك أن أعوض دوري، أن أعوض دوري، ماشي يا سيدي،
+
+311
+00:33:37,140 --> 00:33:42,820
+وين ال F؟ هيها R هي function فيه ثيتا، ده مشتقت
+
+312
+00:33:42,820 --> 00:33:48,040
+هذي كدهش؟ الواحد ب zero والقصين بالسالب صين، بقصين
+
+313
+00:33:48,040 --> 00:33:59,320
+ثيتايبقى sin θ في sin θ زاد ال F لي واحد ناقص cos
+
+314
+00:33:59,320 --> 00:34:08,690
+θ في مين؟ في cos θكل هذا الكلام على df على dθ اللي
+
+315
+00:34:08,690 --> 00:34:16,390
+هي sin θ في cos θ ناقص ال F اللي هي واحد ناقص cos
+
+316
+00:34:16,390 --> 00:34:25,010
+θ في مين؟ في sin θ تماما زي مهلكات ميلابنروح نحسب
+
+317
+00:34:25,010 --> 00:34:32,310
+لسلوب هذا و أجدش عندما θ تساوي سالب بي على اتنين
+
+318
+00:34:32,310 --> 00:34:39,170
+إذا هشيل كل θ و أحط مكانها سالب بي على اتنين يبقى
+
+319
+00:34:39,170 --> 00:34:45,890
+صار sign تربية لسالب بي على اتنينSin في Sin في Sin
+
+320
+00:34:45,890 --> 00:34:52,850
+تربيع وهذه زائد واحد ناقص Cos لسالب بي على اتنين
+
+321
+00:34:52,850 --> 00:35:00,830
+في Cos لسالب بي على اتنين كله Sin لسالب بي على
+
+322
+00:35:00,830 --> 00:35:08,530
+اتنين Cos لسالب بي على اتنين واحد ناقص Cos لسالب
+
+323
+00:35:08,530 --> 00:35:16,730
+بي على اتنين في Sin لسالب بي على اتنينانا الكلام
+
+324
+00:35:16,730 --> 00:35:22,670
+يساوي لان ال sign even والله odd يعني السلب بيطلع
+
+325
+00:35:22,670 --> 00:35:30,150
+برا يبقى sign التسعين جديش؟ جديش sign التسعين؟
+
+326
+00:35:30,150 --> 00:35:35,210
+يبقى هاي السلب برا وهي الواحد تربيع يبقى هاي تربيع
+
+327
+00:35:35,210 --> 00:35:43,010
+اللي بعدها زائد واحد ناقص cosine even والله odd
+
+328
+00:35:43,730 --> 00:35:48,810
+يبقى السلب انسى، فده ال cosine value كده؟ بزيرو،
+
+329
+00:35:48,810 --> 00:35:53,270
+يبقى واحد ناقص زيرو، فمين في ال cosine ال zero
+
+330
+00:35:53,270 --> 00:35:58,970
+اللي هو بزيرو، على مين؟ على المقام، هذا اللي هو
+
+331
+00:35:58,970 --> 00:36:06,290
+بسلب واحد، وهذا بزيرو، وهذا ناقص واحد، ناقص زيرو،
+
+332
+00:36:06,290 --> 00:36:12,370
+كله في سلب واحديبقى النتيجة وتساوي واحد على واحد
+
+333
+00:36:12,370 --> 00:36:17,110
+ويساوي واحد.إذا الاسلوب تبع المنحنى اللي عندنا كان
+
+334
+00:36:17,110 --> 00:36:23,890
+يساوي قداش كان يساوي واحد صحيح على أي حال الآن
+
+335
+00:36:23,890 --> 00:36:27,270
+بدنا نروح للمثال اتنين وهو الرسم
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/dDx0Ho9ebxY_raw.json b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/dDx0Ho9ebxY_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..c4fe575601169f07f0bafbf2c7682d7b7949ae27
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/dDx0Ho9ebxY_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2044, "start": 12.06, "end": 20.44, "text": "نكمل سيكشن 11-3 اللى ابتدأنا فيه المرة الماضية وهو ال polar coordinates", "tokens": [1863, 24793, 1211, 8608, 1829, 4117, 8592, 1863, 2975, 12, 18, 13672, 7578, 48127, 2655, 3215, 10721, 8315, 8978, 3224, 9673, 25720, 9673, 46958, 10632, 37037, 2407, 2423, 12367, 21056], "avg_logprob": -0.3533266148259563, "compression_ratio": 1.088235294117647, "no_speech_prob": 0.0, "words": [{"start": 12.060000000000002, "end": 13.260000000000002, "word": "نكمل", "probability": 0.6772867838541666}, {"start": 13.260000000000002, "end": 14.46, "word": " سيكشن", "probability": 0.63798828125}, {"start": 14.46, "end": 15.12, "word": " 11", "probability": 0.5341796875}, {"start": 15.12, "end": 15.72, "word": "-3", "probability": 0.5987548828125}, {"start": 15.72, "end": 15.88, "word": " اللى", "probability": 0.59716796875}, {"start": 15.88, "end": 16.46, "word": " ابتدأنا", "probability": 0.91064453125}, {"start": 16.46, "end": 16.7, "word": " فيه", "probability": 0.86865234375}, {"start": 16.7, "end": 17.06, "word": " المرة", "probability": 0.93359375}, {"start": 17.06, "end": 17.7, "word": " الماضية", "probability": 0.98876953125}, {"start": 17.7, "end": 18.68, "word": " وهو", "probability": 0.798583984375}, {"start": 18.68, "end": 18.98, "word": " ال", "probability": 0.63671875}, {"start": 18.98, "end": 19.54, "word": " polar", "probability": 0.63720703125}, {"start": 19.54, "end": 20.44, "word": " coordinates", "probability": 0.93798828125}], "temperature": 1.0}, {"id": 2, "seek": 3553, "start": 20.81, "end": 35.53, "text": "المرة الفاتة كنا بنحول نقطة من polar coordinates إلى cartesian coordinates والعكس نقطة من cartesian coordinates إلى polar coordinates ثم معادلات نحولها من polar coordinates إلى cartesian coordinates", "tokens": [45340, 25720, 27188, 9307, 3660, 9122, 8315, 44945, 5016, 12610, 8717, 47432, 3660, 9154, 12367, 21056, 30731, 5467, 42434, 21056, 16070, 3615, 4117, 3794, 8717, 47432, 3660, 9154, 5467, 42434, 21056, 30731, 12367, 21056, 38637, 2304, 20449, 18513, 1211, 9307, 8717, 5016, 12610, 11296, 9154, 12367, 21056, 30731, 5467, 42434, 21056], "avg_logprob": -0.15294471612343422, "compression_ratio": 1.9477611940298507, "no_speech_prob": 0.0, "words": [{"start": 20.81, "end": 21.31, "word": "المرة", "probability": 0.69775390625}, {"start": 21.31, "end": 21.87, "word": " الفاتة", "probability": 0.6603190104166666}, {"start": 21.87, "end": 22.11, "word": " كنا", "probability": 0.81640625}, {"start": 22.11, "end": 22.65, "word": " بنحول", "probability": 0.7766927083333334}, {"start": 22.65, "end": 23.07, "word": " نقطة", "probability": 0.908203125}, {"start": 23.07, "end": 23.21, "word": " من", "probability": 0.94921875}, {"start": 23.21, "end": 23.53, "word": " polar", "probability": 0.89306640625}, {"start": 23.53, "end": 23.97, "word": " coordinates", "probability": 0.96875}, {"start": 23.97, "end": 24.31, "word": " إلى", "probability": 0.86181640625}, {"start": 24.31, "end": 24.95, "word": " cartesian", "probability": 0.802001953125}, {"start": 24.95, "end": 25.73, "word": " coordinates", "probability": 0.9599609375}, {"start": 25.73, "end": 26.83, "word": " والعكس", "probability": 0.86798095703125}, {"start": 26.83, "end": 27.41, "word": " نقطة", "probability": 0.9435221354166666}, {"start": 27.41, "end": 27.55, "word": " من", "probability": 0.98388671875}, {"start": 27.55, "end": 28.11, "word": " cartesian", "probability": 0.822021484375}, {"start": 28.11, "end": 28.67, "word": " coordinates", "probability": 0.9453125}, {"start": 28.67, "end": 28.97, "word": " إلى", "probability": 0.97900390625}, {"start": 28.97, "end": 29.33, "word": " polar", "probability": 0.986328125}, {"start": 29.33, "end": 30.13, "word": " coordinates", "probability": 0.95703125}, {"start": 30.13, "end": 30.91, "word": " ثم", "probability": 0.97314453125}, {"start": 30.91, "end": 31.73, "word": " معادلات", "probability": 0.9547119140625}, {"start": 31.73, "end": 32.25, "word": " نحولها", "probability": 0.8740234375}, {"start": 32.25, "end": 32.39, "word": " من", "probability": 0.9921875}, {"start": 32.39, "end": 32.81, "word": " polar", "probability": 0.97802734375}, {"start": 32.81, "end": 33.45, "word": " coordinates", "probability": 0.95849609375}, {"start": 33.45, "end": 33.77, "word": " إلى", "probability": 0.98583984375}, {"start": 33.77, "end": 34.69, "word": " cartesian", "probability": 0.915771484375}, {"start": 34.69, "end": 35.53, "word": " coordinates", "probability": 0.9326171875}], "temperature": 1.0}, {"id": 3, "seek": 5889, "start": 35.91, "end": 58.89, "text": "باقي علينا مثال هى و بدنا ناخده مثال أربعة اللى هو بيقول replace the following Cartesian equation by its equivalent polar equations يبقى احنا بدنا نروح نحول المعادلات الكارتيزية اللى عندنا الى معادلات قطبية على أكس آخر مثال أخدناه المرة الماضية", "tokens": [3555, 995, 38436, 25894, 8315, 50113, 6027, 8032, 7578, 4032, 47525, 8315, 8717, 47283, 3215, 3224, 50113, 6027, 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"text": "يبدأ المعادلات مواطعة في الصيغة الكارتزية بدي أحولها إلى الصيغة القطبية بدي أذكر تذكير بالمعادلة تبعات التحويل قبل أن نبدأ التحويل اللي مكتوب معاكم في المرة الماضية أخدنا المعادلة الأولى فكانت المعادلة الأولى X يساوي R في Cos الزاوية ثيتا وY تساوي R في Sin الزاوية ثيتا", "tokens": [1829, 44510, 10721, 9673, 3615, 18513, 1211, 9307, 3714, 2407, 41193, 27884, 8978, 31767, 1829, 17082, 3660, 33251, 9640, 2655, 11622, 10632, 4724, 16254, 5551, 5016, 12610, 11296, 30731, 31767, 1829, 17082, 3660, 25062, 9566, 3555, 10632, 4724, 16254, 5551, 8848, 37983, 6055, 8848, 4117, 13546, 20666, 2304, 3615, 18513, 37977, 6055, 3555, 3615, 9307, 16712, 5016, 2407, 26895, 12174, 36150, 14739, 8717, 44510, 10721, 16712, 5016, 2407, 26895, 13672, 1829, 3714, 4117, 2655, 37746, 20449, 995, 24793, 8978, 9673, 25720, 9673, 46958, 10632, 5551, 9778, 3215, 8315, 9673, 3615, 18513, 37977, 16247, 12610, 7578, 6156, 41361, 2655, 9673, 3615, 18513, 37977, 16247, 12610, 7578, 1783, 7251, 3794, 995, 45865, 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{"start": 144.44, "end": 144.9, "word": " بيقولي", "probability": 0.68511962890625}, {"start": 144.9, "end": 145.1, "word": " y", "probability": 0.720703125}, {"start": 145.1, "end": 145.6, "word": " تربيها", "probability": 0.7332763671875}, {"start": 145.6, "end": 146.18, "word": " تساوي", "probability": 0.849609375}, {"start": 146.18, "end": 147.46, "word": " 4x", "probability": 0.811767578125}, {"start": 147.46, "end": 148.06, "word": " يبقى", "probability": 0.9642333984375}, {"start": 148.06, "end": 148.68, "word": " عندك", "probability": 0.983642578125}, {"start": 148.68, "end": 148.88, "word": " ال", "probability": 0.982421875}, {"start": 148.88, "end": 149.24, "word": " y", "probability": 0.64599609375}, {"start": 149.24, "end": 150.06, "word": " بيبقى", "probability": 0.95546875}, {"start": 150.06, "end": 150.6, "word": " r", "probability": 0.85986328125}, {"start": 150.6, "end": 150.9, "word": " في", "probability": 0.978515625}, {"start": 150.9, "end": 151.54, "word": " sin", 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168.41, "end": 169.51, "word": " المعطاة", "probability": 0.856640625}, {"start": 169.51, "end": 170.41, "word": " كتبناها", "probability": 0.98603515625}, {"start": 170.41, "end": 170.67, "word": " في", "probability": 0.9443359375}, {"start": 170.67, "end": 171.57, "word": " الصيغة", "probability": 0.9625244140625}, {"start": 171.57, "end": 172.91, "word": " القطبية", "probability": 0.982177734375}], "temperature": 1.0}, {"id": 9, "seek": 19363, "start": 173.15, "end": 193.63, "text": "بنحاول نرتب شكل المعادلة هذه شوية فهذه لو جينا فكتبناها بطريقة أخرى R تربيع في Sin تربيع ثيتا ماقص أربعة R في Cos الزاوية ثيتا يساوي Zero إذا بدنا نحاول ناخد", "tokens": [3555, 1863, 5016, 995, 12610, 8717, 43500, 3555, 13412, 28820, 9673, 3615, 18513, 37977, 29538, 13412, 2407, 10632, 6156, 3224, 24192, 45164, 10874, 1829, 8315, 6156, 4117, 2655, 3555, 8315, 11296, 4724, 9566, 16572, 28671, 5551, 34740, 7578, 497, 6055, 2288, 21292, 3615, 8978, 11187, 6055, 2288, 21292, 3615, 38637, 36081, 995, 3714, 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لو أخدنا R عامل مشترك بصير عندنا R في sin تربية ثيتا ماقص اربعة كوصين الزاوية ثيتا كله بدي ساوي كده؟ بدي ساوي Zero", "tokens": [3615, 10943, 1211, 37893, 2655, 31747, 4032, 1863, 8592, 38688, 1975, 1829, 8592, 13672, 1829, 4724, 16254, 7251, 5016, 36520, 7251, 3555, 4587, 7578, 45164, 5551, 9778, 3215, 8315, 497, 6225, 10943, 1211, 37893, 2655, 31747, 4724, 9381, 13546, 43242, 8315, 497, 8978, 3343, 6055, 25513, 10632, 38637, 36081, 995, 3714, 995, 4587, 9381, 1975, 25513, 27884, 9122, 2407, 9381, 9957, 6024, 110, 995, 2407, 10632, 38637, 36081, 995, 28242, 3224, 4724, 16254, 8608, 995, 45865, 9122, 3215, 3224, 22807, 4724, 16254, 8608, 995, 45865, 17182], "avg_logprob": -0.3036997064776804, "compression_ratio": 1.675, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 194.18, "end": 195.0, "word": "عامل", "probability": 0.5873819986979166}, {"start": 195.0, "end": 195.6, "word": " مشترك", "probability": 0.9109700520833334}, {"start": 195.6, "end": 196.16, "word": " ونشوف", 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بدها", "probability": 0.9775390625}, {"start": 220.66, "end": 221.48, "word": " تساوي", "probability": 0.984619140625}, {"start": 221.48, "end": 222.46, "word": " أربعة", "probability": 0.718994140625}, {"start": 222.46, "end": 223.32, "word": " كوصين", "probability": 0.70452880859375}, {"start": 223.32, "end": 224.06, "word": " ثيتا", "probability": 0.7945963541666666}, {"start": 224.06, "end": 224.38, "word": " على", "probability": 0.70703125}, {"start": 224.38, "end": 224.9, "word": " مين", "probability": 0.867919921875}, {"start": 224.9, "end": 225.74, "word": " على", "probability": 0.80419921875}, {"start": 225.74, "end": 226.38, "word": " صين", "probability": 0.6070556640625}, {"start": 226.38, "end": 227.3, "word": " تربيع", "probability": 0.80059814453125}, {"start": 227.3, "end": 227.88, "word": " ثيتا", "probability": 0.76806640625}], "temperature": 1.0}, {"id": 12, "seek": 24979, "start": 228.47, "end": 249.79, "text": "يبقى يا إما هذا بيساوي Zero يا إما القُس هذا بيساوي 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الجزء", "probability": 0.9749348958333334}, {"start": 528.09, "end": 528.77, "word": " النظري", "probability": 0.9659830729166666}, {"start": 528.77, "end": 529.25, "word": " لهذا", "probability": 0.92626953125}, {"start": 529.25, "end": 529.39, "word": " ال", "probability": 0.9296875}, {"start": 529.39, "end": 529.91, "word": " section", "probability": 0.751953125}, {"start": 529.91, "end": 530.97, "word": " إلى", "probability": 0.69384765625}, {"start": 530.97, "end": 532.41, "word": " نقطتين", "probability": 0.9774169921875}], "temperature": 1.0}, {"id": 26, "seek": 55855, "start": 532.96, "end": 558.56, "text": "النقطة الأولى اللى هى ال symmetry التماثل والنقطة الثانية اللى هى ال slope يبقى بدنا نجى للنقطة الأولى يبقى graphing in polar coordinates section 11 أربعة graphing in polar coordinates", "tokens": [6027, 1863, 47432, 3660, 16247, 12610, 7578, 13672, 7578, 8032, 7578, 2423, 25440, 16712, 15042, 12984, 1211, 16070, 1863, 47432, 3660, 6024, 104, 7649, 10632, 13672, 7578, 8032, 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{"start": 545.68, "end": 546.0, "word": " in", "probability": 0.9150390625}, {"start": 546.0, "end": 546.66, "word": " polar", "probability": 0.92626953125}, {"start": 546.66, "end": 547.62, "word": " coordinates", "probability": 0.9111328125}, {"start": 547.62, "end": 548.62, "word": " section", "probability": 0.564453125}, {"start": 548.62, "end": 549.34, "word": " 11", "probability": 0.78662109375}, {"start": 549.34, "end": 550.66, "word": " أربعة", "probability": 0.6712239583333334}, {"start": 550.66, "end": 552.82, "word": " graphing", "probability": 0.700927734375}, {"start": 552.82, "end": 554.54, "word": " in", "probability": 0.93115234375}, {"start": 554.54, "end": 556.44, "word": " polar", "probability": 0.9609375}, {"start": 556.44, "end": 558.56, "word": " coordinates", "probability": 0.943359375}], "temperature": 1.0}, {"id": 27, "seek": 57325, "start": 562.95, "end": 573.25, "text": "يبقى الرسم في الإحداثيات القطبية اول نقطة في هذا ال section بدنا ندرس هي symmetry", 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الخط", "probability": 0.8291015625}, {"start": 587.2, "end": 587.44, "word": " θ", "probability": 0.477294921875}, {"start": 587.44, "end": 587.94, "word": " تسوى", "probability": 0.5680999755859375}, {"start": 587.94, "end": 588.16, "word": " Y", "probability": 0.393798828125}, {"start": 588.16, "end": 588.38, "word": " على", "probability": 0.63134765625}, {"start": 588.38, "end": 588.74, "word": " 2", "probability": 0.7939453125}, {"start": 588.74, "end": 589.48, "word": " ثم", "probability": 0.9580078125}, {"start": 589.48, "end": 590.1, "word": " تماثل", "probability": 0.90185546875}, {"start": 590.1, "end": 590.7, "word": " حوالين", "probability": 0.990966796875}, {"start": 590.7, "end": 591.38, "word": " نقطة", "probability": 0.9825846354166666}, {"start": 591.38, "end": 592.04, "word": " الأصل", "probability": 0.7744140625}, {"start": 592.04, "end": 592.62, "word": " هذه", "probability": 0.2337646484375}, {"start": 592.62, "end": 594.56, "word": " التماثلات", "probability": 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" axis", "probability": 0.62939453125}, {"start": 614.64, "end": 615.86, "word": " هذا", "probability": 0.5732421875}, {"start": 615.86, "end": 616.2, "word": " شو", "probability": 0.967529296875}, {"start": 616.2, "end": 617.58, "word": " معناه؟", "probability": 0.83489990234375}, {"start": 617.58, "end": 618.36, "word": " means", "probability": 0.84423828125}, {"start": 618.36, "end": 619.14, "word": " that", "probability": 0.951171875}, {"start": 619.14, "end": 620.88, "word": " if", "probability": 0.95166015625}, {"start": 620.88, "end": 622.44, "word": " the", "probability": 0.88720703125}, {"start": 622.44, "end": 623.36, "word": " point", "probability": 0.9833984375}, {"start": 623.36, "end": 625.8, "word": " r", "probability": 0.270263671875}, {"start": 625.8, "end": 626.02, "word": " و", "probability": 0.8046875}, {"start": 626.02, "end": 626.48, "word": " theta", "probability": 0.311767578125}, {"start": 626.48, "end": 628.96, "word": " lies", "probability": 0.8115234375}, 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النتيجة", "probability": 0.96484375}, {"start": 2170.07, "end": 2170.87, "word": " وتساوي", "probability": 0.80291748046875}, {"start": 2170.87, "end": 2171.47, "word": " واحد", "probability": 0.863037109375}, {"start": 2171.47, "end": 2171.75, "word": " على", "probability": 0.78369140625}, {"start": 2171.75, "end": 2172.37, "word": " واحد", "probability": 0.991455078125}, {"start": 2172.37, "end": 2173.21, "word": " ويساوي", "probability": 0.8822265625}, {"start": 2173.21, "end": 2173.53, "word": " واحد", "probability": 0.9951171875}, {"start": 2173.53, "end": 2174.05, "word": ".إذا", "probability": 0.51220703125}, {"start": 2174.05, "end": 2175.29, "word": " الاسلوب", "probability": 0.7569580078125}, {"start": 2175.29, "end": 2175.67, "word": " تبع", "probability": 0.89111328125}, {"start": 2175.67, "end": 2176.33, "word": " المنحنى", "probability": 0.89599609375}, {"start": 2176.33, "end": 2176.49, "word": " اللي", "probability": 0.7744140625}, {"start": 2176.49, "end": 2176.87, "word": " عندنا", "probability": 0.587646484375}, {"start": 2176.87, "end": 2177.11, "word": " كان", "probability": 0.97265625}, {"start": 2177.11, "end": 2177.59, "word": " يساوي", "probability": 0.98583984375}, {"start": 2177.59, "end": 2178.21, "word": " قداش", "probability": 0.7137858072916666}, {"start": 2178.21, "end": 2178.85, "word": " كان", "probability": 0.7060546875}, {"start": 2178.85, "end": 2179.71, "word": " يساوي", "probability": 0.986328125}, {"start": 2179.71, "end": 2180.73, "word": " واحد", "probability": 0.9931640625}, {"start": 2180.73, "end": 2181.93, "word": " صحيح", "probability": 0.81036376953125}, {"start": 2181.93, "end": 2182.37, "word": " على", "probability": 0.415771484375}, {"start": 2182.37, "end": 2182.59, "word": " أي", "probability": 0.7470703125}, {"start": 2182.59, "end": 2183.07, "word": " حال", "probability": 0.998291015625}, {"start": 2183.07, "end": 2183.89, "word": " الآن", "probability": 0.738525390625}, {"start": 2183.89, "end": 2184.25, "word": " بدنا", "probability": 0.832275390625}, {"start": 2184.25, "end": 2184.71, "word": " نروح", "probability": 0.9874674479166666}, {"start": 2184.71, "end": 2185.31, "word": " للمثال", "probability": 0.820068359375}, {"start": 2185.31, "end": 2185.89, "word": " اتنين", "probability": 0.84100341796875}, {"start": 2185.89, "end": 2186.51, "word": " وهو", "probability": 0.939453125}, {"start": 2186.51, "end": 2187.27, "word": " الرسم", "probability": 0.8701171875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2187.80725, "duration_after_vad": 2060.886874999994}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/g42mXbCKncs.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/g42mXbCKncs.srt
new file mode 100644
index 0000000000000000000000000000000000000000..0edd77e759cb7d7daef21fff4b4bc76c3c1590ed
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/g42mXbCKncs.srt
@@ -0,0 +1,1759 @@
+1
+00:00:09,660 --> 00:00:15,660
+بسم الله الرحمن الرحيم نكمل ما ابتدأنا في 
+
+2
+00:00:15,660 --> 00:00:20,000
+المحاضرة الماضية وهو موضوع integration by parts
+
+3
+00:00:20,750 --> 00:00:24,790
+طبعًا عرفنا في قانون ال integration by parts
+
+4
+00:00:24,790 --> 00:00:29,790
+القانون أو هذه القاعدة بتقول integration لـ UDV 
+
+5
+00:00:29,790 --> 00:00:36,670
+يساوي U في V ناقص تكامل V dU واخذنا على ذلك 
+
+6
+00:00:36,670 --> 00:00:41,690
+اللي هو خمسة أمثلة وهذا هو المثال السادس يبقى احنا
+
+7
+00:00:41,690 --> 00:00:48,870
+بدنا integration لـ sin inverse X شوف يا سيدي التكتيك
+
+8
+00:00:48,870 --> 00:00:52,370
+اللي نتابعه عند تكامل sin inverse x هو اللي نتابعه
+
+9
+00:00:52,370 --> 00:00:54,970
+عند الـ cosine inverse وعند الـ tan inverse و الـ
+
+10
+00:00:54,970 --> 00:00:57,770
+cotan inverse يعني باقي معكوسات الدوال الثلاثية
+
+11
+00:00:57,770 --> 00:01:01,970
+الستة لو كان أي واحدة فيهم يبقى بدنا نعملها بنفس
+
+12
+00:01:01,970 --> 00:01:08,370
+الطريقة اللي بنعملها فيها تكامل sin inverse x طيب
+
+13
+00:01:08,370 --> 00:01:13,250
+بنجي لـ sin inverse احنا الآن بدنا نكاملها يبقى 
+
+14
+00:01:13,250 --> 00:01:18,390
+احنا تكاملها السابق ما نعرفوش لكن مشتقتها نعرفها إذا
+
+15
+00:01:18,390 --> 00:01:27,750
+بدي اروح آخذ U تساوي sin inverse X وداخل الـ dv هي
+
+16
+00:01:27,750 --> 00:01:32,210
+عبارة عن dx اللي بظل في المثال يبقى لو جينا
+
+17
+00:01:32,210 --> 00:01:38,410
+اشتقيناها بدها تصير dU واحد على الجذر التربيعي لـ 
+
+18
+00:01:38,410 --> 00:01:44,230
+واحد ناقص X تربيع في dx وهذا لو كاملناه الـ V بدها
+
+19
+00:01:44,230 --> 00:01:52,270
+يساوي ايه؟ بدها تساوي الـ X طلع لي هنا U في V يبقى X في
+
+20
+00:01:52,270 --> 00:01:59,870
+sin inverse X ناقص تكامل V اللي هو X dU واحد
+
+21
+00:01:59,870 --> 00:02:06,630
+على الجذر التربيعي اللي هو واحد ناقص X تربيع DX إذا
+
+22
+00:02:06,630 --> 00:02:12,250
+استخدمنا integration by parts لتكامل sin inverse x 
+
+23
+00:02:12,250 --> 00:02:17,790
+وصلنا إلى هذا الشكل ما انتهيناش إذا لسه ضايل عندنا
+
+24
+00:02:17,790 --> 00:02:25,240
+تكامل هذا التكامل هههههههههههههههههههههههههههههههه
+
+25
+00:02:38,930 --> 00:02:45,630
+إذا لو حطيت الـ W يساوي واحد ناقص X تربيع DW ناقص
+
+26
+00:02:45,630 --> 00:02:51,170
+اثنين X DX لأن مشتقة الكون استغل بـ Zero ما عنديش
+
+27
+00:02:51,170 --> 00:02:57,910
+اثنينات يبقى ممكن آخذ ناقص نص DW اللي هو بدها تساوي
+
+28
+00:02:57,910 --> 00:03:05,290
+من الـ X DX يبقى أنا هشيل الـ X DX و أحط مكانها ناقص
+
+29
+00:03:05,290 --> 00:03:11,820
+نص DW إذا بدها تصير المسألة هي x في sin inverse x
+
+30
+00:03:11,820 --> 00:03:17,380
+ناقص تكامل هذه النص برا بإشارة سالب بيصير هذا
+
+31
+00:03:17,380 --> 00:03:24,300
+موجب بيبقى زائد نص تكامل DW على جذر W 
+
+32
+00:03:27,380 --> 00:03:35,980
+هذا بدها تساوي x في sin inverse x زائد نص وتكامل W
+
+33
+00:03:35,980 --> 00:03:43,450
+أصلًا ناقص نص DW الهم من التكامل هذا يبقى نتيجة x في
+
+34
+00:03:43,450 --> 00:03:50,410
+sin inverse x زائد نص الـ W هذه بدنا نضيف للأس
+
+35
+00:03:50,410 --> 00:03:56,950
+واحد ونقسم على الأس الجديد يبقى بصير أن نص نص على
+
+36
+00:03:56,950 --> 00:04:04,340
+نص زائد constant c الإجابة عندي زي ما أنت شايف فيها
+
+37
+00:04:04,340 --> 00:04:08,580
+two variables اللي هو الـ X و الـ W لكن رأس المثال
+
+38
+00:04:08,580 --> 00:04:14,630
+كان بدلالة X إذا بدنا نرجع ونكتب الـ W بدلالة X كويس
+
+39
+00:04:14,630 --> 00:04:20,690
+يبقى هذا الكلام بدها تساوي x في sin inverse x زائد
+
+40
+00:04:20,690 --> 00:04:25,630
+نص مع نص الله يسهل عليها والـ W اللي هي واحد ناقص X
+
+41
+00:04:25,630 --> 00:04:31,890
+تربيع  أصلًا نص يبقى تحت الجذر التربيعي زائد ميم زائد
+
+42
+00:04:31,890 --> 00:04:40,200
+constant c سؤال السابع سؤال السابع بيقول تكامل X
+
+43
+00:04:40,200 --> 00:04:50,500
+تربيع cos اثنين X يبقى integration لـ X square cos
+
+44
+00:04:50,500 --> 00:04:52,800
+اثنين X في DX
+
+45
+00:04:56,150 --> 00:05:01,170
+يبقى مين بدنا نختار U ومين بدنا نختار DV الـ U لو
+
+46
+00:05:01,170 --> 00:05:04,830
+اخذناها cos يبقى نشتقها والله نكاملها بتفرقش
+
+47
+00:05:04,830 --> 00:05:09,950
+cos sin cos sin ومظل في هذه الدائرة المغلقة لكن
+
+48
+00:05:09,950 --> 00:05:15,550
+الـ X يبقى لو بدي آخذها تكامل يبقى بتنتهي X أربعة
+
+49
+00:05:15,550 --> 00:05:19,990
+X تكامل X أربعة ما عكوا نفسهم ما بتفرقش عننا لكن لو
+
+50
+00:05:19,990 --> 00:05:25,320
+جيت فضلتها بعد مرتين بتنتهي مثلاً إذا automatic بدي
+
+51
+00:05:25,320 --> 00:05:29,960
+آخذ الـ U هي X تربيع والباقي هو مين اللي هو DV
+
+52
+00:05:33,620 --> 00:05:40,720
+تساوي X تربيع وبتاخد الـ DV اللي هي cos 2X في DX
+
+53
+00:05:40,720 --> 00:05:49,760
+بالشكل اللي عندنا نشتق DU يبقى بـ 2X في DX والـ V
+
+54
+00:05:49,760 --> 00:05:55,180
+اللي هو من نص في sinh 2X
+
+55
+00:05:56,990 --> 00:06:00,490
+يبقى تكامل cos اثنين اكس هو sinh اثنين اكس على
+
+56
+00:06:00,490 --> 00:06:07,310
+اثنين يعني نص sinh اثنين اكس هذه الـ U وهذه الـ V
+
+57
+00:06:07,310 --> 00:06:17,740
+يبقى النتيجة بدها تساوي U في V اللي هو نص X² sinh
+
+58
+00:06:17,740 --> 00:06:31,400
+2x ناقص تكامل V اللي هو نص sinh 2x dU اللي هي 2x في dx إذا
+
+59
+00:06:31,400 --> 00:06:38,520
+أصبحت المثال على الشكل التالي integration لـ X² cos
+
+60
+00:06:38,520 --> 00:06:48,110
+2x dx بدها تساوي النتيجة اللي حصلنا عليها نص X² sinh
+
+61
+00:06:48,110 --> 00:06:57,290
+2x ناقص طلعت لنا نص مع اثنين الله يسهل عليها يبقى
+
+62
+00:06:57,290 --> 00:07:05,670
+آلة المسألة اللي تكامل لـ X في sinh اثنين X DX إذا هذا
+
+63
+00:07:05,670 --> 00:07:11,550
+التكامل يشبه الأصل مع الفرق بدل cos صارت sinh و
+
+64
+00:07:11,550 --> 00:07:15,150
+بدل X² صارت بيها نزلت الدرجة اللي ابتدأت فيها إلى
+
+65
+00:07:15,150 --> 00:07:20,410
+الدرجة الأولى وهي X يبقى احنا اضطرينا إجباريًا إلى
+
+66
+00:07:20,410 --> 00:07:25,730
+استخدام integration by parts كمان مرة إذا بروح آخذ
+
+67
+00:07:25,730 --> 00:07:35,540
+الـ U تساوي من X والـ dv بدها تساوي sinh اثنين X في 
+
+68
+00:07:35,540 --> 00:07:45,820
+dx يبقى dU يساوي dx والـ V اللي هو نص cosh اثنين
+
+69
+00:07:45,820 --> 00:07:53,090
+X إذا النتيجة صارت على الشكل التالي integration لـ
+
+70
+00:07:53,090 --> 00:08:08,420
+X² cos 2X DX يساوي النص X² sinh 2X ناقص U في الـ V
+
+71
+00:08:08,420 --> 00:08:17,860
+يبقى ناقص X cosh اثنين X هذا الـ U في الـ V هذا
+
+72
+00:08:17,860 --> 00:08:22,120
+الناقص بالشكل اللي عندنا هذا اللي برا يبقى بالشكل
+
+73
+00:08:22,120 --> 00:08:29,300
+اللي عندنا هذا يبقى هذا U في V ناقص تكامل V dU 
+
+74
+00:08:29,300 --> 00:08:37,820
+يبقى نص cosh 2X dU اللي هي بدها تساوي DX بالشكل اللي عندنا
+
+75
+00:08:37,820 --> 00:08:50,090
+هنا إذا صارت النتيجة هي نص X² sinh 2X ناقص نص X cosh
+
+76
+00:08:50,090 --> 00:08:58,210
+2x ناقص في ناقص بيزيد النص هيبرة وتكامل الـ cosh 
+
+77
+00:08:58,210 --> 00:09:05,970
+بـ sinh 2x مقسوم على 2 زائد constant C
+
+78
+00:09:08,930 --> 00:09:15,410
+يبقى هذه كأنها قد ايه ربع sinh اثنين X يعني اضطرينا
+
+79
+00:09:15,410 --> 00:09:21,430
+في هذه المسألة نعمل ايه integration by parts مرتين
+
+80
+00:09:21,430 --> 00:09:26,610
+في نفس المسألة وقد يكون ثلاث وقد يكون أربع سيان
+
+81
+00:09:26,610 --> 00:09:31,810
+المهم بنضل نشتغل لما نكمل يعني بعد ما نعمل التكامل
+
+82
+00:09:31,810 --> 00:09:36,230
+أول باي بارس إذا اضطريت استخدم نفس القلم كم مرة
+
+83
+00:09:36,230 --> 00:09:40,530
+باستخدمه إذا بدي ارجع تكامل بالتعويض بدي استخدم
+
+84
+00:09:40,530 --> 00:09:44,530
+تكامل بالتعويض يعني أي شغلة من الأشياء التي سبقت
+
+85
+00:09:44,530 --> 00:09:50,330
+دراستها طيب اشاركوا بدنا نقترح الاقتراح التكامل 
+
+86
+00:09:50,330 --> 00:09:58,210
+كان مين؟ كان X² cosh X اخذناها U وفضلناها وصار
+
+87
+00:09:58,210 --> 00:10:03,510
+عندي X بدل X تربيع فضلناها كمان مرة وانتهينا منها
+
+88
+00:10:03,510 --> 00:10:09,930
+الـ cosh كملناها مرتين مرة sinh وكمان مرة طلعت cosh
+
+89
+00:10:09,930 --> 00:10:16,250
+وكمان مرة رجعت لـ sinh تمام طيب ايش رأيكم هنا نعمل
+
+90
+00:10:16,250 --> 00:10:20,110
+هالشغل ونشوف ايش رأيكم فيها بدي آجي أقول اللي
+
+91
+00:10:20,110 --> 00:10:23,690
+اخذتها derivatives بدي اكتبها بالشكل التالي
+
+92
+00:10:23,690 --> 00:10:30,330
+derivatives واللي كاملتها بدي اكتب عليها integrals
+
+93
+00:10:30,330 --> 00:10:36,810
+اللي فضلناها هي X تربيع واللي كاملتها هي cosh اثنين
+
+94
+00:10:36,810 --> 00:10:42,290
+X اللي ابتدأنا فيهم تمام؟ بدي ابدأ أفضّل هذه لغاية
+
+95
+00:10:42,290 --> 00:10:49,990
+ما أوصل لصفر يبقى لو جيت فضلت هذه بقد ايه 2x لو كملت
+
+96
+00:10:49,990 --> 00:10:58,410
+هذه بـ sinh 2x على 2 بدي أفضّل هذه كمان مرة بـ 2 بدي
+
+97
+00:10:58,410 --> 00:11:05,410
+أكامل هذه كمان مرة بـ cosh 2x على 2 وعندي اثنين بصير
+
+98
+00:11:05,410 --> 00:11:11,330
+أربعة لو فضلت هذه كمان مرة بيصير zero لو كملت هذه
+
+99
+00:11:11,330 --> 00:11:18,090
+كمان مرة بيصير sinh اثنين اكس على ثمانية تمام؟ بعدين
+
+100
+00:11:18,090 --> 00:11:24,630
+امسك لي سهم من الأولى للثانية ومن الثانية للثالثة
+
+101
+00:11:24,630 --> 00:11:30,120
+ومن الثالثة لهنا للرابعة هنا الشكل هذا ونبدأ نضع
+
+102
+00:11:30,120 --> 00:11:33,900
+قاعدة الإشارات قاعدة الإشارات بتقول بتبدأ بالموجب
+
+103
+00:11:33,900 --> 00:11:40,340
+سالب موجب سالب موجب لما تكمل يبقى السبت أول واحدة
+
+104
+00:11:40,340 --> 00:11:44,500
+على اليمين وسبت الـ zero اللي هو اين على الشمال
+
+105
+00:11:44,500 --> 00:11:49,940
+تحتنا طيب تعال نضرب هدول في بعض ونجمع ونشوف ايش
+
+106
+00:11:49,940 --> 00:11:58,160
+بيعطينا لو جيت لهنا نص X تربيع sinh اثنين X هذا
+
+107
+00:12:00,530 --> 00:12:06,610
+تمام؟ طيب نضرب هدول في بعض اثنين في ربع بيعطيني نص
+
+108
+00:12:06,610 --> 00:12:12,770
+وعندي إشارة سالب يبقى سالب نص X cosh اثنين X
+
+109
+00:12:12,770 --> 00:12:18,970
+سالب نص X cosh اثنين X اللي بعدها اثنين في 
+
+110
+00:12:18,970 --> 00:12:25,050
+ثمانية بيعطيني الربع sinh اثنين X يبقى الربع sinh
+
+111
+00:12:25,050 --> 00:12:30,820
+اثنين X وبضيف لك نص تاني يبقى لما أشتغل الشغل هذه
+
+112
+00:12:30,820 --> 00:12:36,280
+هتوصلني إلى نفس النتيجة اللي اشتغلتها قبل هيك
+
+113
+00:12:36,280 --> 00:12:43,580
+السؤال هو ايه ما أسهل نستخدم الجدول هذا والله
+
+114
+00:12:43,580 --> 00:12:48,590
+نرجع لطريقتنا الأولانية هذه؟ الجدول يبقى الجدول،
+
+115
+00:12:48,590 --> 00:12:55,110
+بريحل له بدم هيك مظبوط؟ طيب السؤال هو سنة شوية،
+
+116
+00:12:55,110 --> 00:12:59,130
+هتجاوب على أسئلتك من دون بتسأل هتجاوب على أسئلتك،
+
+117
+00:12:59,130 --> 00:13:04,740
+السؤال هو النتيجة بهذه الجدول هي النتيجة اللي
+
+118
+00:13:04,740 --> 00:13:09,300
+اتبعناها في حل المثال integration by parts مرتين،
+
+119
+00:13:09,300 --> 00:13:15,020
+ثلاث أربع قد ما يكون تمام؟ السؤال هو هل هذه
+
+120
+00:13:15,020 --> 00:13:22,680
+الطريقة بتنفع لكل مثال؟ الإجابة لا السؤال هو مرة 
+
+121
+00:13:22,680 --> 00:13:26,940
+ثانية مين هي المثال اللي بتنفعلها الطريقة هذه؟
+
+122
+00:13:35,930 --> 00:13:41,550
+طيب على أي حال هذه الطريقة بتنفع على ستة أنواع
+
+123
+00:13:41,550 --> 00:13:47,370
+من المسائل كويس؟ الآن بدنا نكتب هذه الستة أنواع،
+
+124
+00:13:47,370 --> 00:13:52,330
+وبرضه نسأل كمان تساوي بعد ما نخلصها كويس؟ يفجأ
+
+125
+00:13:52,330 --> 00:13:57,470
+حق والكلام في صيغة الـ remark التالية remark 
+
+126
+00:14:11,270 --> 00:14:20,210
+إذا كانت النتيجة مفضلة مفضلة
+
+127
+00:14:20,210 --> 00:14:23,350
+نستخدم
+
+128
+00:14:31,980 --> 00:14:40,600
+then we use the tabular integration
+
+129
+00:14:40,600 --> 00:14:46,080
+integration 
+
+130
+00:14:46,080 --> 00:14:56,300
+in the following cases in the following cases
+
+131
+00:14:56,300 --> 00:14:59,080
+يعني
+
+132
+00:15:00,040 --> 00:15:07,700
+لو كان n عدد صحيح موجب بنستخدم طريقة الجدول هذه
+
+133
+00:15:07,700 --> 00:15:12,620
+لتابولار انتجريشن لطريقة الجدول اللي قدامنا هذه في
+
+134
+00:15:12,620 --> 00:15:15,800
+الحالات الست التالية
+
+135
+00:15:24,280 --> 00:15:30,360
+اللي هو ax dx يعني زي المثال تبعنا هذا نمرة واحد
+
+136
+00:15:30,360 --> 00:15:39,260
+نمرة اثنين لو كان عندنا تكامل x أُس n في
+
+137
+00:15:39,260 --> 00:15:50,700
+sin ax dx لو كان عندنا تكامل x أُس m cosine ax
+
+138
+00:15:50,700 --> 00:16:02,520
+dx 4 لو كان عندنا تكامل x أُس m sine ax dx 5 لو
+
+139
+00:16:02,520 --> 00:16:10,860
+كان عندنا تكامل x أُس n e أُس ax dx 6 لو كان
+
+140
+00:16:10,860 --> 00:16:13,120
+عندنا تكامل x أُس n
+
+141
+00:16:19,870 --> 00:16:29,190
+طيب السؤال هو ليش هذه الأنواع من المسائل دون 
+
+142
+00:16:29,190 --> 00:16:35,830
+غيرها من هذه الأنواع اللي بنستخدمها طريقة الجدول
+
+143
+00:16:35,830 --> 00:16:44,670
+هذا السؤال الذي يحتاج إلى إجابة شوف ازاي يطلع لي في
+
+144
+00:16:44,670 --> 00:16:53,170
+كل دالة من الدوال الستة اللي مع x أُس m لو فاضلتها
+
+145
+00:16:53,170 --> 00:16:58,650
+والله كاملتها يا بضلها هي نفسها يا إما بتيجي مين
+
+146
+00:16:58,650 --> 00:17:04,210
+دالة ثانية وبعد ثالث مرة بتعود كما كانت فمثلا امسك
+
+147
+00:17:04,210 --> 00:17:09,550
+الأربع الأولانيات هدول كله sin cos sin cos طبعا
+
+148
+00:17:09,550 --> 00:17:12,410
+بتيجي إشارة سالب ما عندناش مشكلة في مقدار ثابت
+
+149
+00:17:12,410 --> 00:17:18,670
+ما يؤثرش عندنا تمام يبقى sin cos sin cos sin cos
+
+150
+00:17:18,670 --> 00:17:21,910
+sin cos إلى آخره تمام هذا بالنسبة للأربع
+
+151
+00:17:21,910 --> 00:17:26,260
+الأولانيات بالنسبة للـ exponential إذا اشتقيتها و
+
+152
+00:17:26,260 --> 00:17:28,640
+والله كاملتها، تبقى اللي قاعدة زي ما هي، يا ابن اضغط
+
+153
+00:17:28,640 --> 00:17:32,000
+في كل نص أنت يا ابن اقسم على مين؟ على كل نص أنت
+
+154
+00:17:32,000 --> 00:17:36,060
+بالنسبة للدوال اللي هو ln x زي ما هي، بس يا ابن
+
+155
+00:17:36,060 --> 00:17:40,420
+اضغط في ln الـ x يا ابن اقسم على ln الـ x لكن لو
+
+156
+00:17:40,420 --> 00:17:47,250
+جيت تختار دوال أخرى، مثلا sin cos قول tan لو جان
+
+157
+00:17:47,250 --> 00:17:51,930
+فاضلة tan ايش بيطلع sec تربيع بيطلع فاضلة كمان مرة
+
+158
+00:17:51,930 --> 00:17:59,150
+بيصير 2 sec تربيع tan بترجعش tan كما كان تمام و من
+
+159
+00:17:59,150 --> 00:18:04,230
+هنا اجت الطريقة هذه للاسف بسبب التكرار الدوري
+
+160
+00:18:04,230 --> 00:18:11,150
+لهذه الدوال نعطيك مثال توضيح على ذلك احسب لي
+
+161
+00:18:11,150 --> 00:18:13,810
+example
+
+162
+00:18:19,860 --> 00:18:29,240
+Evaluate يحسب إنه تكامل لمن؟ للـ x تربيع x تربيع
+
+163
+00:18:29,240 --> 00:18:35,460
+في 3 أُس x كله بالنسبة إلى dx
+
+164
+00:18:45,800 --> 00:18:51,520
+واضح إن هذه السؤالة على صيغة رقم 6 الـ a بس أجب
+
+165
+00:18:51,520 --> 00:18:55,480
+أكانها 3 والـ n أجب أكانها 2 إذا
+
+166
+00:18:55,480 --> 00:18:59,320
+أنا بروح أعمله الجدول إذا لو روحت أعمله الجدول
+
+167
+00:18:59,320 --> 00:19:04,340
+بدي أقوله هنا الـ derivatives أو هنا بدي أخد له الـ
+
+168
+00:19:04,340 --> 00:19:10,970
+integrals طبعا الـ derivative اللي فاضلتها هي x تربيع
+
+169
+00:19:10,970 --> 00:19:16,970
+و 3x هي الـ 3 بدنا نكاملها لو فاضلنا هذه بيطلع
+
+170
+00:19:16,970 --> 00:19:25,610
+2x لو كاملنا هذه 3 أُس x تقسيم للـ 3 لأنها
+
+171
+00:19:25,610 --> 00:19:31,240
+بنكامل تكامل إن فابل هذه كمان مرة بيطلع 2، إن
+
+172
+00:19:31,240 --> 00:19:35,280
+كامل هذه كمان مرة 1 على ln الـ 3 مقدار ثابت
+
+173
+00:19:35,280 --> 00:19:39,720
+ما له دعوة، يبقى بدي أكمل 3 والست كمان مرة
+
+174
+00:19:39,720 --> 00:19:46,060
+بيطلع 3 والست على ln 3 وعندي ln 3 بيصير
+
+175
+00:19:46,060 --> 00:19:53,280
+ln 3 تربيع نشتغل كمان مرة 0 نكامل كمان مرة
+
+176
+00:19:53,280 --> 00:20:00,440
+3 والست تقسيم للـ ln 3 2 تكامل هذه الأولى
+
+177
+00:20:00,440 --> 00:20:04,040
+في الثانية هذه الثانية في الثالثة الثالثة في
+
+178
+00:20:04,040 --> 00:20:09,570
+الرابعة زائد ناقص زائد يبقى نتيجة هذا التكامل على
+
+179
+00:20:09,570 --> 00:20:16,270
+الشكل التالي اللي هو 1 على ln الـ 3 في x
+
+180
+00:20:16,270 --> 00:20:20,350
+تربيع في 3 أُس x
+
+181
+00:20:22,860 --> 00:20:29,820
+جينا لبعديها ناقص 2 على ln الـ 3 الكل تربيع
+
+182
+00:20:29,820 --> 00:20:36,760
+2 على ln الـ 3 الكل تربيع في x في 3 أُس x
+
+183
+00:20:38,250 --> 00:20:44,950
+زائد الـ term الثالث لهولي 2 على ln الـ 3 الكل
+
+184
+00:20:44,950 --> 00:20:51,090
+تكعيب في مين في 3 أُس x و بنروح نضيف مين الـ
+
+185
+00:20:51,090 --> 00:20:53,690
+constant اللي عندنا هذا
+
+186
+00:20:56,750 --> 00:20:59,730
+خلاصنا النقطة الأولى من هذا الـ section بدنا نروح
+
+187
+00:20:59,730 --> 00:21:05,570
+للنقطة الثانية النقطة الثانية أحيانا ما يجيش أستخدم
+
+188
+00:21:05,570 --> 00:21:12,510
+integration by parts مباشرة ربما هضطر أعمل تعويض
+
+189
+00:21:12,510 --> 00:21:18,250
+قبل إيه قبل اللي هو عملية الـ integration by parts
+
+190
+00:21:18,250 --> 00:21:22,830
+يعني ليس بالضرورة مباشرة كيف كانت التالية؟ بدي أكتب
+
+191
+00:21:22,830 --> 00:21:25,610
+هذا كمان في الملاحظة التالية remark
+
+192
+00:21:47,540 --> 00:21:55,000
+أحيانا نستخدم التعويض ومن 
+
+193
+00:21:55,000 --> 00:21:58,040
+ثم نستخدم
+
+194
+00:21:59,640 --> 00:22:11,200
+نستخدم integration by parts ومن
+
+195
+00:22:11,200 --> 00:22:22,180
+ثم بروح نستخدم التكامل بالتجزئة نعطي مثال example
+
+196
+00:22:22,180 --> 00:22:25,400
+احسب لي
+
+197
+00:22:25,400 --> 00:22:28,260
+تكاملات التالية
+
+198
+00:22:39,330 --> 00:22:48,430
+أول تكامل من هذه التكاملات تكامل ln x الكل تربيع
+
+199
+00:22:48,430 --> 00:22:49,490
+dx
+
+200
+00:22:56,240 --> 00:23:00,800
+لا يبقى الواضح إذا بدأ أخد u بدأ أخد المقدار هذا
+
+201
+00:23:00,800 --> 00:23:05,460
+لكن لما أجى الشق بيصير 2 لأن الـ x في 1 على
+
+202
+00:23:05,460 --> 00:23:11,140
+x وهذه كمان x تبقى تتكلك على المثل شوية لكن لو جيت
+
+203
+00:23:11,140 --> 00:23:16,020
+لهذه الدالة اللي قلت اللي مصعبة شوية هيك هو مين؟
+
+204
+00:23:16,560 --> 00:23:20,800
+إذا بدي أشيل ln الـ x وأضعه بأي variable آخر إذا
+
+205
+00:23:20,800 --> 00:23:29,980
+لو قلت حط لي t تساوي ln الـ x بالذنب لنا مين؟ الـ dx
+
+206
+00:23:29,980 --> 00:23:35,040
+لذلك بدي أتخلص من ln وأخلي الـ x لحالها في شجة
+
+207
+00:23:35,040 --> 00:23:41,960
+يبقى لو جيت أتخلص منها بيصير عند مين؟ e أُس t يساوي
+
+208
+00:23:41,960 --> 00:23:48,570
+e أُس ln الـ x اللي هو بمين؟ بـ x طبعا الحين بشتقها
+
+209
+00:23:48,570 --> 00:23:54,670
+بكون جيب dx إذا لو جينا اشتقينا بيصير e أُس t dt بده
+
+210
+00:23:54,670 --> 00:24:00,230
+يساوي مين dx إذا المسألة هذه أصبحت على الشكل
+
+211
+00:24:00,230 --> 00:24:07,170
+التالي بدي أشيل الـ x وأحط مكانها e أُس t وأشيل
+
+212
+00:24:07,170 --> 00:24:13,930
+ln الـ x وأحط مكانها t تربيع والـ dx اللي هو e أُس
+
+213
+00:24:13,930 --> 00:24:15,190
+t dt
+
+214
+00:24:25,180 --> 00:24:33,380
+يبدو كأن المسألة أصبحت هي تكامل t تربيع e أُس 2
+
+215
+00:24:33,380 --> 00:24:34,380
+t dt
+
+216
+00:24:37,830 --> 00:24:43,330
+طيب طلع لي هل هذه تشبه أي واحدة من الستة اللي هما
+
+217
+00:24:43,330 --> 00:24:48,290
+الخالصة يبقى بروح بعمله الجدول يبقى بروح بقوله
+
+218
+00:24:48,290 --> 00:24:54,510
+هنا بدي أخد جزء derivatives وبدي أخد الجزء الثاني
+
+219
+00:24:54,510 --> 00:25:00,710
+integrals يبقى الـ derivatives هي main هي t تربيع
+
+220
+00:25:00,710 --> 00:25:06,630
+والـ derivatives هي e أُس 2t نفضل يبقى 2t
+
+221
+00:25:06,630 --> 00:25:15,090
+نكامل نص e أُس 2t نفضل بـ 2 نكامل ربع e أُس
+
+222
+00:25:15,090 --> 00:25:23,040
+2t نفضل بـ 0 نكامل ثمن e أُس 2t يبقى هذه
+
+223
+00:25:23,040 --> 00:25:27,600
+في هذه بشرة زائد هذه في هذه بشرة ناقص وهذه بشرة
+
+224
+00:25:27,600 --> 00:25:34,280
+ماينص زائد إذن النتيجة أصبحت على الشكل التالي يبقى
+
+225
+00:25:34,280 --> 00:25:43,900
+نص t تربيع e أُس 2t ناقص 2 على 4 اللي
+
+226
+00:25:43,900 --> 00:25:51,100
+هو بنص t e أُس 2t زائد 2 في ثمن ثاني
+
+227
+00:25:51,100 --> 00:25:58,820
+ربع e أُس 2t زائد constant c الآن بدي أشيل كل t
+
+228
+00:25:58,820 --> 00:26:03,520
+وأحط مكانها التعويض اللي حاطينا لها لأن من الـ x
+
+229
+00:26:03,520 --> 00:26:12,520
+يبقى صارت النتيجة ln الـ x الكل تربيع e أُس 2
+
+230
+00:26:12,520 --> 00:26:21,840
+ln الـ x ناقص نص ln الـ x e أُس 2 ln الـ x زائد
+
+231
+00:26:21,840 --> 00:26:29,920
+ربع e أُس 2 ln الـ x زائد constant c هذا الكلام
+
+232
+00:26:29,920 --> 00:26:36,380
+يساوي نص ما لكش دعوة هذه يا شباب على درع المين e أُس
+
+233
+00:26:36,380 --> 00:26:41,880
+ln x تربيع الأس ده هدخل جوا الـ e والـ ln بيلغوا
+
+234
+00:26:41,880 --> 00:26:48,760
+بعض وقداش x تربيع يبقى نص x تربيع ln الـ x الكل
+
+235
+00:26:48,760 --> 00:26:55,610
+تربيع نجي للترم الثاني ناقص نص ln الـ x هذا كمان
+
+236
+00:26:55,610 --> 00:27:02,770
+بقداش ب x تربيع يبقى لو بس مشان الترتيب نص x تربيع
+
+237
+00:27:02,770 --> 00:27:11,770
+في ln الـ x وهذه زائد ربع x تربيع زائد constant c
+
+238
+00:27:11,770 --> 00:27:17,910
+بالشكل اللي قدامنا هذا إذا بعض المسائل سنضطر إلى
+
+239
+00:27:17,910 --> 00:27:24,990
+عملها أو تكاملها أو تحويلها بالتعويض إلى مسألة
+
+240
+00:27:24,990 --> 00:27:29,810
+تكامل بعد ذلك بمهم بالتجزئة، يقوله الـ integration
+
+241
+00:27:29,810 --> 00:27:34,650
+by parts يبقى أنت بدك تكون دقيق نظر في المسألة
+
+242
+00:27:34,650 --> 00:27:38,590
+اللي عندك إذا تعوض وسهلها بتروح اعوض وبعد هيك
+
+243
+00:27:38,590 --> 00:27:44,510
+بتروح تعمل تكامل بالتجزئة بنعطيك مثال آخر بتالي
+
+244
+00:27:44,510 --> 00:27:51,710
+اثنين بدنا تكامل لـ cosine ln اللي هو الجذر
+
+245
+00:27:51,710 --> 00:27:53,910
+التالث لـ x dx
+
+246
+00:27:59,260 --> 00:28:03,120
+احنا اللي مر علينا تكامل لـ cosine الـ x بس الجذر
+
+247
+00:28:03,120 --> 00:28:08,020
+الثالث لـ x هذه أول مرة بنشوفها مظبوط؟ إذا هي هذه
+
+248
+00:28:08,020 --> 00:28:12,580
+الوضع غير طبيعي أو هي المصعبة المثل يبقى لو داجها
+
+249
+00:28:12,580 --> 00:28:16,060
+أكملها بالتجزئة الدوري مباشرة ده إن شاء الله
+
+250
+00:28:16,060 --> 00:28:20,830
+عليها بصيرة في غاية التعقيد تمام؟ لكن بسيطة الشغلة 
+
+251
+00:28:20,830 --> 00:28:26,590
+في دينها، اعمل تعويض لهذه المثلة مثلاً بدي أقول حط
+
+252
+00:28:26,590 --> 00:28:33,620
+الـ Y تساوي الجذر التكعيبي لـ X كعب الطرفين بيصير y 
+
+253
+00:28:33,620 --> 00:28:40,380
+تكعيب يساوي x يبقى سهل جداً لأن بقول تلاتة y تربيع
+
+254
+00:28:40,380 --> 00:28:46,380
+dy بده يساوي dx اللي عندنا هذه لكن لو جيت أجيب dy
+
+255
+00:28:46,380 --> 00:28:51,060
+من هنا بدل و أحولها بدل الـ dx بصير معقدة يبقى أول
+
+256
+00:28:51,060 --> 00:28:55,260
+شغل إذا قابلك سؤال من هذا القبيل بتخلص من الجذر
+
+257
+00:28:55,260 --> 00:28:59,830
+وبعدين بروح بشتق زي ما عملنا هنا بالضبط تمام طب هذه
+
+258
+00:28:59,830 --> 00:29:06,130
+حولتلي لمثلة بالشكل التالي طلعلي هنا هذا اللي هو
+
+259
+00:29:06,130 --> 00:29:13,250
+cosine و الجذر التكعيبي أنا حاطيته بـ Y والـ DX هي
+
+260
+00:29:13,250 --> 00:29:20,270
+تلاتة Y تربيع في DY طب التلاتة هذا مُعامل ثابت خليك
+
+261
+00:29:20,270 --> 00:29:29,020
+برا تظل تكامل لـ Y تربيع Cos Y Dy أتحولت المثلة
+
+262
+00:29:29,020 --> 00:29:34,080
+تبعتي من مثلة مُكلّكة أو شكل غير شكل إلى مثلة شكلها
+
+263
+00:29:34,080 --> 00:29:42,040
+مقبول وهي من الجدول هذه الحل على الجدول اللي هي
+
+264
+00:29:42,040 --> 00:29:46,340
+النقطة رقم تلاتة بنقوله بسيطة يبقى بنروح نعمل
+
+265
+00:29:46,340 --> 00:29:52,520
+الجدول بناخد هنا derivatives وبناخد هنا integrals
+
+266
+00:29:52,520 --> 00:30:05,110
+تمام؟ هنا Y تربيع هنا cosine Y ننزل كمان
+
+267
+00:30:05,110 --> 00:30:12,230
+مرة باتنين ننزل كمان مرة باتنين ننزل كمان مرة
+
+268
+00:30:12,230 --> 00:30:14,070
+باتنين ننزل كمان مرة باتنين ننزل كمان مرة باتنين
+
+269
+00:30:14,070 --> 00:30:18,250
+ننزل كمان مرة باتنين ننزل كمان مرة باتنين هذه في
+
+270
+00:30:18,250 --> 00:30:23,950
+هذه بالموجب هذه في هذه بالسالب هذه في هذه بالموجب
+
+271
+00:30:23,950 --> 00:30:30,010
+إذا انتقلت المسألة إلى الشكل التالي اللي هو Y تربيع
+
+272
+00:30:30,010 --> 00:30:37,630
+في sign الـ Y تمام؟ و هنا ناقص مع ناقص بصير زائد
+
+273
+00:30:37,630 --> 00:30:38,910
+كيف؟
+
+274
+00:30:41,890 --> 00:30:47,490
+أه في تلاتة برا طيب مش مشكلة لما نخلص هي يساوي وهي
+
+275
+00:30:47,490 --> 00:30:57,050
+التلاتة للكل كمان و هنا زائد اتنين y في cosine الـ
+
+276
+00:30:57,050 --> 00:31:04,550
+y و هنا ناقص اتنين sine الـ y ناقص اتنين sine الـ y
+
+277
+00:31:04,550 --> 00:31:12,130
+كله زائد constant C هذا الكلام بده يساوي تلاتة فيه
+
+278
+00:31:12,130 --> 00:31:16,310
+بدنا نيجي للـ Y تربيع بدنا نشيل الـ Y ونحطه مكان
+
+279
+00:31:16,310 --> 00:31:22,550
+أمام الجذر يعني هذا X أس ثلث الكل تربيع يعني X أس
+
+280
+00:31:22,550 --> 00:31:31,090
+ثلثين يبقى تلاتة X أس ثلثين نيجي لهذه الـ sign الـ Y
+
+281
+00:31:31,090 --> 00:31:37,010
+طلع لهنا  إيش اللي عملنا إحنا وين حطينا التعويض؟ حطينا
+
+282
+00:31:37,010 --> 00:31:45,530
+الـ Y يساوي X كعب يعني Y ماشي خليها زي ما هي طيب
+
+283
+00:31:45,530 --> 00:31:51,410
+طلعلي للمثلة اللي عندنا هذا الآن بدي أرجع الـ Y
+
+284
+00:31:51,410 --> 00:31:57,410
+أكتبه بدلالة من؟ بدلالة الـ X يبقى هذه بصير الـ sign
+
+285
+00:31:57,410 --> 00:32:06,150
+لمين؟ للجذر التكعيبي لـ X نيجي لبعدها زائد تلاتة في
+
+286
+00:32:06,150 --> 00:32:12,010
+اتنين بستة والـ Y اللي هي الجذر التكعيبي لـ X و Cos
+
+287
+00:32:12,010 --> 00:32:21,350
+الجذر التكعيبي لـ X وصلنا للسالب من اتنين ساين الجذر
+
+288
+00:32:21,350 --> 00:32:28,130
+التكعيبي لـ X زائد constant C وهي ضربناها في تلاتة
+
+289
+00:32:28,130 --> 00:32:31,070
+بصير إحنا ما قديش هنا ستة
+
+290
+00:32:33,840 --> 00:32:39,860
+طيب هذا كان المثال الثاني المثال الثالث بدنا تكامل
+
+291
+00:32:39,860 --> 00:32:50,060
+لمين؟ لـ sin inverse x sin inverse x الكل تربيع dx
+
+292
+00:32:50,060 --> 00:32:57,000
+هذا السؤال جبناه مرة في إحدى الامتحانات برضه
+
+293
+00:32:57,000 --> 00:33:02,300
+integration by substitution في الأول وبتحول بعدها
+
+294
+00:33:02,300 --> 00:33:08,170
+إلى مثلة أعلم بها إذا لو جينا قولنا هنا حطلي
+
+295
+00:33:08,170 --> 00:33:14,570
+مثلاً الـ y تساوي الـ sign inverse x يبقى الـ sign الـ
+
+296
+00:33:14,570 --> 00:33:20,510
+y هي اللي بدها تساوي x مش هكت يبقى الفاضل يبقى cos
+
+297
+00:33:20,510 --> 00:33:27,790
+y dy بدها تساوي من dx يبقى آلة المسألة إلى الشكل
+
+298
+00:33:27,790 --> 00:33:31,030
+التالي هذه y تربيع
+
+299
+00:33:46,450 --> 00:33:56,450
+سؤال الرابع سؤال الرابع بيقول تكامل x أس خمسة e
+
+300
+00:33:56,450 --> 00:34:05,510
+أس x تربيع dx هذه على الجدول؟ لأ. ليش؟ لأ لأ لأ لأ
+
+301
+00:34:05,510 --> 00:34:07,190
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+302
+00:34:07,190 --> 00:34:09,030
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+303
+00:34:09,030 --> 00:34:11,630
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+304
+00:34:11,630 --> 00:34:12,090
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+305
+00:34:12,090 --> 00:34:17,730
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+306
+00:34:17,730 --> 00:34:26,310
+لأ
+
+307
+00:34:26,310 --> 00:34:31,100
+لأ لأ الـ x أس خمسة ليه x أس أربعة في x؟ والـ x أس
+
+308
+00:34:31,100 --> 00:34:39,580
+أربعة هي x تربيع تربيع في x في e أس x تربيع في dx
+
+309
+00:34:40,430 --> 00:34:44,370
+إذا كتبت المثلة على الشكل الجديد اللي قدامنا هذا
+
+310
+00:34:44,370 --> 00:34:49,950
+للمساعدة المثلة ايه؟ إذا بدي أشيل الـ x تربيع و أحطها
+
+311
+00:34:49,950 --> 00:34:57,270
+بأي متغير آخر، إذا لو جيت حطيتي t تساوي x تربيع
+
+312
+00:34:57,610 --> 00:35:04,650
+يبقى dt باتنين x dx ما عنديش اتنينات بنجسم
+
+313
+00:35:04,650 --> 00:35:09,810
+على اتنين بيصير نص dt بده يساوي الـ x dx
+
+314
+00:35:09,810 --> 00:35:13,790
+يبقى الـ x مع الـ dx هذه كلها بشيلها و بحط مكان
+
+315
+00:35:13,790 --> 00:35:22,210
+أما من نص dt يبقى نص تكامل x تربيع بـ t في تربيع برا
+
+316
+00:35:22,210 --> 00:35:33,270
+يبقى t تربيع وهذا يصبح e أس t و x dx بنص dt على
+
+317
+00:35:33,270 --> 00:35:39,390
+الجدول؟ عملنا واحدة زيها اختبرتوا؟ يبقى هذه زيها
+
+318
+00:35:41,770 --> 00:35:48,590
+طيب، بروح على رقم خمسة، خمسة، بيقول الـ integration
+
+319
+00:35:48,590 --> 00:35:56,190
+من zero لغاية واحد على جذر اتنين للاتنين x sine
+
+320
+00:35:56,190 --> 00:36:01,170
+inverse لمين؟ للـ x تربيعها كله في dx
+
+321
+00:36:04,280 --> 00:36:08,580
+للمساعدة بالمثلة امين أو لوضعها مش طبيعي امين x
+
+322
+00:36:08,580 --> 00:36:14,560
+تربيع طيب إذا بدنا نشيلها ونحطها بحط لي θ تساوي
+
+323
+00:36:14,560 --> 00:36:22,890
+x تربيع يبقى d θ يساوي اتنين x dx إذا اتنين x
+
+324
+00:36:22,890 --> 00:36:26,870
+مع الـ dx هذه كلها بدي أشيلها وأكتبها بدلالة مين؟
+
+325
+00:36:26,870 --> 00:36:35,610
+d θ يبقى صار تكامل لـ sign inverse θ d θ
+
+326
+00:36:35,610 --> 00:36:42,380
+وبقيت مين؟ حدود التكامل لما تبقى x بواحد على الجذر
+
+327
+00:36:42,380 --> 00:36:49,540
+اتنين بصير θ بقد ايش؟ نصف ولما تبقى x بصفر بصير
+
+328
+00:36:49,540 --> 00:36:54,720
+θ بصفر هذا السؤال اللي حليناه قبل شوية أول
+
+329
+00:36:54,720 --> 00:37:00,760
+مبدأ محاضرتنا اليوم فيه تمام؟ يبقى كمان هذا زيه
+
+330
+00:37:00,760 --> 00:37:09,460
+طيب بلاش زيه كتبنا الجواب كده طالع عندك هذا يساوي
+
+331
+00:37:09,460 --> 00:37:18,980
+كده؟ يبقى هذا θ sin inverse θ ناقص الجذر
+
+332
+00:37:18,980 --> 00:37:23,720
+التربيع لاحظ ناقص θ تربيع ناقص ولا زاد،
+
+333
+00:37:23,720 --> 00:37:29,000
+تأكد لي زاد؟ طب الخطية فارقة بتأكد تمام؟ هذا
+
+334
+00:37:29,000 --> 00:37:34,700
+الكلام الحين من وين لوين؟ من zero لغاية نص يبقى
+
+335
+00:37:34,700 --> 00:37:43,470
+هذا previousExample يعني مثال سابق أول ما بدأنا هي
+
+336
+00:37:43,470 --> 00:37:48,330
+المحاضرة اليوم طب
+
+337
+00:37:48,330 --> 00:37:52,540
+بس لما نوصلها يا رايد حلقش تحليك لسه ما وصلنا يا
+
+338
+00:37:52,540 --> 00:37:57,960
+ابن آدم أنا لم أطالبك بعملي غد، فكيف تطالبني
+
+339
+00:37:57,960 --> 00:38:01,560
+برزقه؟ يقول الله تبارك الله في الحديث القدسي،
+
+340
+00:38:01,560 --> 00:38:06,700
+جايينك الحين بصنوصر يبقى هذا الكلام بصير قد ايش؟ نص
+
+341
+00:38:06,700 --> 00:38:15,200
+sign inverse نص زائد الجذر التربيعي لواحد ناقص
+
+342
+00:38:15,200 --> 00:38:20,880
+ربع يبقى هي عوضنا بمين؟ بالقيم اللي فوت ناقص
+
+343
+00:38:30,350 --> 00:38:38,710
+بدر بدر بدر بدر بدر بدر بدر بدر
+
+344
+00:38:41,120 --> 00:38:46,780
+هل منحنى sign inverse يمر بنقطة الأصل؟ يعني sign
+
+345
+00:38:46,780 --> 00:38:52,740
+inverse zero قد ايش؟ بواحد لما يمر بنقطة الأصل دي
+
+346
+00:38:52,740 --> 00:39:00,160
+إكسارة يبقى هنا بصير Zero يبقى ناقص Zero زائد الجذر
+
+347
+00:39:00,160 --> 00:39:03,820
+التربيعي لواحد ناقص Zero خلاص أنتو يا عزيزي خلاص
+
+348
+00:39:03,820 --> 00:39:12,880
+يبقى هذا الكلام اللي فوق هيخلصه منه ناقص Zero ناقص
+
+349
+00:39:12,880 --> 00:39:19,200
+الجذر شكله عندنا يساوي نص Sin inverse نص الزاوية
+
+350
+00:39:19,200 --> 00:39:25,200
+اللي جيبها نص تلاتين درجة يبقى باي على ستة تمام؟
+
+351
+00:39:25,200 --> 00:39:30,620
+وهذا زي الجذر التربيعي واحد ناقص ربع تلت تربيع
+
+352
+00:39:30,620 --> 00:39:36,380
+وهنا ناقص واحد يبقى صارت النتيجة باي على اتناشر
+
+353
+00:39:36,380 --> 00:39:44,720
+زي الجذر تلاتة على اتنين ناقص واحد رقم ستة بيقول
+
+354
+00:39:44,720 --> 00:39:52,880
+لما يأتي ستة بدنا تكامل لمين؟ لـ sec تكعيب
+
+355
+00:39:59,060 --> 00:40:03,580
+x dx هذا السؤال مش تبقى تعويض هنا مش واضح أنه
+
+356
+00:40:03,580 --> 00:40:09,020
+بتتعويض إذا بدي أكامل دوري بس بدي أدبر حالي أن
+
+357
+00:40:09,020 --> 00:40:14,820
+أخدت u مشتقته صعبة وأن أخدت dv طب هو إحنا أصلاً
+
+358
+00:40:14,820 --> 00:40:21,050
+بدنا نتكامل لكن يمكن كتابته على الشكل التالي تكامل
+
+359
+00:40:21,050 --> 00:40:28,230
+لـ sec الـ x في sec تربيع الـ x في dx يبقى هذي جزاية
+
+360
+00:40:28,230 --> 00:40:34,290
+المسألة إلى جزئين يبقى جزئين يخد تفاضل هذا سهل جداً
+
+361
+00:40:34,290 --> 00:40:40,210
+ناخده تكامل هذا اشتقاق سهل إذا لو رحت أخدت الـ u
+
+362
+00:40:40,210 --> 00:40:49,860
+تساوي sec x و dv ليه sec تربيع الـ x dx يبقى الـ du بـ sec
+
+363
+00:40:49,860 --> 00:40:58,160
+الـ x في tan الـ x في dx والـ v اللي بتان الـ x يبقى
+
+364
+00:40:58,160 --> 00:41:05,500
+هذه u وهذه v إذن النتيجة مباشرة تساوي u في v يبقى
+
+365
+00:41:05,500 --> 00:41:12,680
+sec الـ x في tan الـ x ناقص تكامل ذي اللي هي بتان الـ x
+
+366
+00:41:12,680 --> 00:41:18,640
+ده الـ u اللي هي بـ sec يبقى بصير sec الـ x في tan
+
+367
+00:41:18,640 --> 00:41:25,940
+تربيع الـ x في dx طيب هذا السؤال ايش اللي حشره مع
+
+368
+00:41:25,940 --> 00:41:30,700
+المجموعة هذه من المسائل أنت بتقول بدنا نعوض في
+
+369
+00:41:30,700 --> 00:41:35,120
+الأول وبعدين نعمل integration by parts هذه
+
+370
+00:41:35,120 --> 00:41:44,020
+المجموعة كانت زي هيك انتظر قليل انتظر قليل انتظر
+
+371
+00:41:44,020 --> 00:41:45,400
+قليل انتظر قليل انتظر قليل انتظر
+
+372
+00:41:45,400 --> 00:41:45,700
+قليل انتظر قليل انتظر قليل انتظر قليل انتظر
+
+373
+00:41:45,700 --> 00:41:47,920
+قليل انتظر قليل انتظر قليل انتظر قليل انتظر
+
+374
+00:41:47,920 --> 00:41:53,200
+قليل انتظر قليل انتظر قليل انتظر قليل انتظر
+
+375
+00:41:53,200 --> 00:41:56,880
+قليل انتظر قليل انتظر قليل انتظر قليل انتظر 
+
+376
+00:41:56,880 --> 00:42:06,360
+قليل، انتظر قليل،
+
+377
+00:42:06,760 --> 00:42:14,900
+واحد ناقص والعكس صحيح، sec تربيع ناقص واحد تمام يبقى
+
+378
+00:42:14,900 --> 00:42:23,000
+هذه sec الـ x tan الـ x ناقص
+
+379
+00:42:23,000 --> 00:42:31,080
+تكامل sec الـ x tan تربيع لـ sec تربيع الـ x ناقص واحد كله
+
+380
+00:42:31,080 --> 00:42:38,980
+في dx إذا صارت المسألة تكامل لـ sec تكعيب x dx بده
+
+381
+00:42:38,980 --> 00:42:45,040
+يساوي sec الـ x في tan الـ x ناقص تكامل sec في sec
+
+382
+00:42:45,040 --> 00:42:53,660
+تربيع بقداش بسك تكعيب الـ x في dx وناقص فناقص بزائد
+
+383
+00:42:53,660 --> 00:43:03,090
+تكامل sec الـ x في dx طلع لي لهذه الاسم يرسل مثلًا؟
+
+384
+00:43:03,090 --> 00:43:08,570
+بدي أشيلها بسلامة وأجيب عندها بصير كده؟ اثنين sec
+
+385
+00:43:08,570 --> 00:43:16,210
+تكعيب يبقى بصير اثنين تكامل لـ sec تكعيب الـ X DX بدي
+
+386
+00:43:16,210 --> 00:43:25,970
+يساوي sec X في tan الـ X زائد تكامل لـ sec X DX
+
+387
+00:43:28,820 --> 00:43:32,360
+اثنين هذا مش لازمالي، بديش اثنين أنا بدي اتكمل sec
+
+388
+00:43:32,360 --> 00:43:40,480
+تكعيب، بنجسم sec تكعيب لـ x، هذه sec تكعيب صحيح، هذه sec
+
+389
+00:43:40,480 --> 00:43:45,300
+تكعيب، ونجلناها، فهذه sec تكعيب، وهذه كل شيء تمام
+
+390
+00:43:52,480 --> 00:44:00,900
+تكامل sec تكعيب x dx يساوي نصف sec الـ x بتان الـ x
+
+391
+00:44:00,900 --> 00:44:03,100
+زائد نصف
+
+392
+00:44:05,410 --> 00:44:12,970
+خدناها قبلك يبقى الآن absolute value لـ sec الـ X زائد
+
+393
+00:44:12,970 --> 00:44:19,750
+tan الـ X زائد كونستانس كيف تسيبها؟ مطلوب تكمل
+
+394
+00:44:19,750 --> 00:44:26,010
+المثلة حتى النهاية ومشان تمرينِدك good exercise لك
+
+395
+00:44:26,010 --> 00:44:31,930
+بدنا تكامل cosec تكعيب الـ X DX يظهر
+
+396
+00:44:35,680 --> 00:44:45,940
+طيب خدلي كمان سؤال بيقول لي ايش؟ بيقول لي بدنا تكامل
+
+397
+00:44:45,940 --> 00:44:52,540
+e أس اثنين X لـ cosine ثلاثة X DX
+
+398
+00:44:58,190 --> 00:45:03,990
+هذا السؤال ايش بتاخد صح كله مظبوط مش فيه مشكلة
+
+399
+00:45:03,990 --> 00:45:10,010
+يبقى أنا لو أخدت الـ U تساوي e أس اثنين X واخدت الـ
+
+400
+00:45:10,010 --> 00:45:18,130
+DV ليه Cos ثلاثة X DX يبقى DU يساوي اثنين E أس
+
+401
+00:45:18,130 --> 00:45:27,150
+اثنين X DX و V يساوي ثلث ساين ثلاثة X يبقى النتيجة
+
+402
+00:45:27,150 --> 00:45:35,550
+تساوي U في V يبقى ثلث E أس اثنين X في sign ثلاثة X
+
+403
+00:45:35,550 --> 00:45:44,630
+ناقص تكامل V اللي ثلث sign ثلاثة X دال U اثنين E
+
+404
+00:45:44,630 --> 00:45:52,530
+أس اثنين X DX يبقى هذا بده ينزل زي ما هو وهذا ناقص
+
+405
+00:45:52,530 --> 00:45:59,970
+ثلثين تكامل E أس اثنين X Sine ثلاثة X DX
+
+406
+00:46:08,850 --> 00:46:18,710
+يبقى الـ U تساوي E أس اثنين X وDV تساوي Sine ثلاثة 
+
+407
+00:46:18,710 --> 00:46:26,850
+X DX يبقى DU باثنين E أس اثنين X DX و V بطول
+
+408
+00:46:26,850 --> 00:46:34,370
+Cosine ثلاثة X بس بإشارة ثلث طيب صار عندنا مين؟
+
+409
+00:46:34,370 --> 00:46:47,190
+تكامل للـ E أُس 2X Cos 3X DX يساوي طول E أُس 2X Sin
+
+410
+00:46:47,190 --> 00:46:55,970
+3X هنا وصلنا مين؟ ناقص طول 2 وهيقصنرى بالك، لو
+
+411
+00:46:55,970 --> 00:47:00,250
+جالك سؤال زي هيك، ستخلق، سالم ثلثين باخد مرة و
+
+412
+00:47:00,250 --> 00:47:05,010
+بفتح الجزء، هذا الآن integration by parts جديد U
+
+413
+00:47:05,010 --> 00:47:15,220
+في V يبقى سالم ثلث E قوس اثنين X كوسين ثلاثة X سالب
+
+414
+00:47:15,220 --> 00:47:23,680
+تكامل V اللي بسالب ثلث cosine ثلاثة اكس داليه اثنين
+
+415
+00:47:23,680 --> 00:47:31,300
+اقص اثنين اكس DX جفلنا يبقى هذا الكلام يساوي ثلث
+
+416
+00:47:31,300 --> 00:47:41,520
+اقص اثنين اكس sine ثلاثة اكس زائد اثنين على تسعة E أس
+
+417
+00:47:41,520 --> 00:47:51,420
+اثنين X كوسين ثلاثة X ناقص ناقص ناقص يبقى بثلاثة
+
+418
+00:47:51,420 --> 00:47:58,680
+يبقى بصير الناقص نيجي عندك هنا هنا ثلثين وهنا عندك
+
+419
+00:47:58,680 --> 00:48:08,400
+ثلثين يبقى أربعة على تسعة أربعة على تسعة تكامل لإي أس اثنين
+
+420
+00:48:08,400 --> 00:48:15,860
+اكس قصين ثلاثة اكس دي اكس اتطلع في الـ term هذا هو
+
+421
+00:48:15,860 --> 00:48:22,040
+الـ term هذانفسه؟ نفسه يبقى بده أشيله وأديه عنده
+
+422
+00:48:22,040 --> 00:48:29,600
+بطول قداش واحد زائد أربعة تسعة يعني قداش ثلاثة عشر
+
+423
+00:48:29,600 --> 00:48:36,040
+على تسعة. إذن بصير عندي ثلاثة عشر على تسعة تكامل E أس
+
+424
+00:48:36,040 --> 00:48:44,620
+اثنين X Cos ثلاثة X DX يساوي بمسك هذا بنزله هنا زي
+
+425
+00:48:44,620 --> 00:48:49,430
+ما هو أنا ما بديش اللي هو ثلاثة عشر على تسعة بدي
+
+426
+00:48:49,430 --> 00:48:54,610
+التكامل إذا بضرب كله في قداش في تسعة على ثلاثة عشر
+
+427
+00:48:54,610 --> 00:49:04,170
+يبقى صار تكامل للـ E أس اثنين X Cos ثلاثة X DX يساوي
+
+428
+00:49:04,170 --> 00:49:12,930
+تسعة على ثلاثة عشر بيصير ثلاثة على ثلاثة عشر E أس اثنين X
+
+429
+00:49:12,930 --> 00:49:19,500
+Sin ثلاثة X تسعة بصير اثنين على ثلاثة عشر يبقى زائد
+
+430
+00:49:19,500 --> 00:49:27,820
+اثنين على ثلاثة عشر اقصى اثنين X قصاين ثلاثة X و
+
+431
+00:49:27,820 --> 00:49:33,920
+بروح بضيف زايد ايش زائد constant good exercise لك
+
+432
+00:49:33,920 --> 00:49:34,500
+كمان
+
+433
+00:49:52,180 --> 00:50:02,260
+تكامل كوساين لن الـ X DX يبقى حط لي ثيتا تساوي لن
+
+434
+00:50:02,260 --> 00:50:10,500
+الـ X E أس ثيتا يساوي X يبقى E أس ثيتا D ثيتا يبدو
+
+435
+00:50:10,500 --> 00:50:19,320
+سوى من DX يبقى صار التكامل cosine ثيتا E أس ثيتا D
+
+436
+00:50:19,320 --> 00:50:24,840
+ثيتا يبقى صاف زي السؤال اللي قبله ولا لا؟ يبقى هذا
+
+437
+00:50:24,840 --> 00:50:33,260
+as example 7 يبقى هذا زيه بالضبط تماما وهذا زي سك
+
+438
+00:50:33,260 --> 00:50:38,720
+كايب يعني بعد ما وصلنا بعد تكملين طلع رأس المسألة
+
+439
+00:50:38,720 --> 00:50:44,300
+نجلناها على الشجرة الثانية نكتفي بهذا القدر و
+
+440
+00:50:44,300 --> 00:50:47,840
+بنكمل إن شاء الله المحاضرة القادمة
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/jTcVRskg5cM.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/jTcVRskg5cM.srt
new file mode 100644
index 0000000000000000000000000000000000000000..ebce99982f1e22ccd929437ba922e319a1c6a695
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/jTcVRskg5cM.srt
@@ -0,0 +1,1859 @@
+1
+00:00:00,000 --> 00:00:02,680
+موسيقى
+
+2
+00:00:10,930 --> 00:00:15,190
+بسم الله الرحمن الرحيم اليوم إن شاء الله بنكمل عن
+
+3
+00:00:15,190 --> 00:00:18,490
+الموضوع اللي بدنا فيه المرة الماضية وهو الـ inverse
+
+4
+00:00:18,490 --> 00:00:22,650
+function معكوس الدالة آخر حاجة أعطيناها المرة اللي
+
+5
+00:00:22,650 --> 00:00:28,630
+فاتت كان مثال على كيفية إثبات أن دالتين واحدة معكوس 
+
+6
+00:00:28,630 --> 00:00:33,530
+للثانية الآن بناخد مثال آخر حول نفس المفهوم لكن
+
+7
+00:00:33,530 --> 00:00:37,950
+بفكرة أخرى المثال بيقول ما يأتي let الـ F of X
+
+8
+00:00:40,820 --> 00:00:48,340
+الـ f of x تساوي اللي هو الـ x تكعيب زائد اثنين x 
+
+9
+00:00:48,340 --> 00:00:55,700
+ناقص ثلاثة المطلوب
+
+10
+00:00:55,700 --> 00:01:05,320
+find the value of
+
+11
+00:01:05,320 --> 00:01:18,310
+a f الـ F inverse of A بده يساوي اثنين solution
+
+12
+00:01:26,960 --> 00:01:31,980
+هذا المثال يختلف عن المثال السابق لكن يحوم حول نفس
+
+13
+00:01:31,980 --> 00:01:36,260
+الفكرة تمامًا المرة اللي فاتت أعطانا two functions
+
+14
+00:01:36,260 --> 00:01:41,400
+وقلنا اثبت أن هذه الدالة هي معكوس لدالة ثانية وقد
+
+15
+00:01:41,400 --> 00:01:45,740
+أثبتنا ذلك هذا معطيين f of x ساوي x تكعيب زائد
+
+16
+00:01:45,740 --> 00:01:50,540
+اثنين x ناقص ثلاثة و قال لي هاتلي قيمة اللي هو a
+
+17
+00:01:50,540 --> 00:01:55,760
+بحيث أن الـ f inverse of a بده يساوي مين؟ يساوي
+
+18
+00:01:55,760 --> 00:02:00,300
+اثنين إذا المعطيات اللي عندنا في هذه المسألة هي f
+
+19
+00:02:00,300 --> 00:02:08,010
+inverse of a بده يساوي قداش؟ اثنين بدنا قيمة A يعني
+
+20
+00:02:08,010 --> 00:02:12,990
+معناته بدنا نتخلص من الـ F inverse تمام؟ بدك تعمل
+
+21
+00:02:12,990 --> 00:02:18,290
+أي شغلة رياضية بواسطتها تتخلص من الـ F inverse واضح
+
+22
+00:02:18,290 --> 00:02:23,830
+أنه من هذه المعادلة أنه لو جينا أثرنا على الطرفين
+
+23
+00:02:23,830 --> 00:02:29,730
+بمين؟ بدالة F ممتاز جدًا يبقى لو أثرنا على الطرفين
+
+24
+00:02:29,730 --> 00:02:35,270
+بدالة F بنتخلص من مين؟ و بنحصل على مين؟ وبعد هيك
+
+25
+00:02:35,270 --> 00:02:41,570
+ربك بفرجها يبقى بنيجي بنقول هنا الـ F للـ F inverse
+
+26
+00:02:41,570 --> 00:02:49,060
+of A بده يساوي الـ F of اثنين طب الخطوة اللي عملتها
+
+27
+00:02:49,060 --> 00:02:55,160
+خطوة صحيحة ولا خطوة ليست صحيحة؟ الإجابة الخطوة خطوة
+
+28
+00:02:55,160 --> 00:03:00,880
+صحيحة لماذا؟ لإنه لما نقول F inverse of A يساوي 2
+
+29
+00:03:00,880 --> 00:03:06,540
+معناته الـ A في domain الـ F inverse و 2 في الـ range
+
+30
+00:03:06,540 --> 00:03:10,660
+تبع الـ F inverse اللي هو domain مين؟ domain الـ F
+
+31
+00:03:10,660 --> 00:03:14,840
+ممتاز جدًا يبقى مادام في domain الـ F إذا الـ F بتقدر
+
+32
+00:03:14,840 --> 00:03:19,330
+تأثر على 2 يبقى الخطوة اللي عملتها خطوة صحيحة ماحدش
+
+33
+00:03:19,330 --> 00:03:24,530
+بيقدر يقول لي خطوة تكادى خطأ تمام تمام طيب الدالة لو
+
+34
+00:03:24,530 --> 00:03:29,350
+معكوسها هذا يعتبر الـ composition ما بين الاتنين أو
+
+35
+00:03:29,350 --> 00:03:34,170
+واحدة تلغي الثانية يبقى بيصير عندنا الـ A بده يساوي
+
+36
+00:03:34,170 --> 00:03:39,410
+الـ F of اثنين يبقى الـ A تساوي باجي على الدالة اللي
+
+37
+00:03:39,410 --> 00:03:45,350
+عندي و بشيل كل X و بحط مكانها اثنين يبقى اثنين الكل
+
+38
+00:03:45,350 --> 00:03:52,130
+تكعيب زائد اثنين في اثنين ناقص ثلاثة هذا بده يقين
+
+39
+00:03:52,130 --> 00:03:58,710
+أن الـ a تساوي ثمانية وأربعة عشر شيل منهم ثلاثة
+
+40
+00:03:58,710 --> 00:04:04,670
+بيظل كده؟ بيظل تسعة إذا قيمة a تساوي تسعة اللي هو
+
+41
+00:04:04,670 --> 00:04:12,060
+المطلوب تبع المثال الآن حتى الآن ما قلناش كيف بدنا
+
+42
+00:04:12,060 --> 00:04:15,140
+نحسب المعكوس تبع الدالة
+
+43
+00:04:21,910 --> 00:04:33,130
+مش هنجيب شكل
+
+44
+00:04:33,130 --> 00:04:41,770
+المعكوس نعمل خطوات لا ثالث لها ما هي الخطوات
+
+45
+00:04:41,770 --> 00:04:48,330
+الاثنين؟ الخطوة الأولى نحن لدينا y كدالة في x y
+
+46
+00:04:48,330 --> 00:04:55,700
+تساوي f of x هي المعطاة عندنا بتروح تعمل x كدالة في y
+
+47
+00:04:55,700 --> 00:04:59,640
+يعني بدي أعمل إيه؟ كأنه بدي أغير وضع الـ variable
+
+48
+00:04:59,640 --> 00:05:05,540
+يبقى بدي أجيب x as a function of y بعد ما أجيب هذه
+
+49
+00:05:05,540 --> 00:05:10,160
+الخطوة الثانية بدي أعمل interchange تغيير بين الـ x
+
+50
+00:05:10,160 --> 00:05:14,540
+و الـ y يعني بدي أشيل كل x و أحط مكانها y و أشيل كل
+
+51
+00:05:14,540 --> 00:05:20,270
+y و أحط مكانها x اللي بيطلع بيكون هو معكوس الدالة طبعًا
+
+52
+00:05:20,270 --> 00:05:27,310
+يبقى خطوتين لا ثالث لهما نطرح السؤال ثم نجيب عليه how
+
+53
+00:05:27,310 --> 00:05:43,130
+to find if inverse of x from the function y تساوي
+
+54
+00:05:43,130 --> 00:05:44,670
+if of x
+
+55
+00:05:48,370 --> 00:05:55,030
+كيف بدنا نجد معكوسة دالة F من المعادلة Y تساوي F
+
+56
+00:05:55,030 --> 00:05:59,910
+of X قلنا هذا الكلام سيتم على خطوتين الخطوة
+
+57
+00:05:59,910 --> 00:06:06,190
+الأولى بدنا نحل المعادلة هذه مشان نحصل على X as a
+
+58
+00:06:06,190 --> 00:06:12,430
+function of Y يبقى الخطوة الأولى Solve the
+
+59
+00:06:12,430 --> 00:06:26,320
+equation Y تساوي F of X to get x as a function of y
+
+60
+00:06:26,320 --> 00:06:40,540
+as a function of y اثنين interchange interchange
+
+61
+00:06:40,540 --> 00:06:45,460
+الـ x and الـ y
+
+62
+00:06:51,820 --> 00:06:57,840
+والترتيب هو y
+
+63
+00:06:57,840 --> 00:07:01,620
+تساوي f inverse of x
+
+64
+00:07:14,950 --> 00:07:20,090
+يبقى السؤال اللي مطروح عندنا كيف بدنا نجد معكوسة
+
+65
+00:07:20,090 --> 00:07:26,050
+دالة y تساوي f of x الإجابة خطوتين لا ثالث لهما
+
+66
+00:07:26,050 --> 00:07:31,790
+خطوة الأولى بدنا نحل المعادلة y تساوي f of x بحيث
+
+67
+00:07:31,790 --> 00:07:37,730
+تصبح على الصورة x دالة في y بحيث الـ x تصبح هي
+
+68
+00:07:37,730 --> 00:07:41,760
+function في مين؟ في y الـ function اللي حصلنا عليها
+
+69
+00:07:41,760 --> 00:07:46,140
+دي بدأ أبدل خطوة ثانية بدأ أبدل x و y مكان بعض
+
+70
+00:07:46,140 --> 00:07:49,580
+تبدأ أشيل كل x و أحط مكانها y و أشيل كل y و أحط
+
+71
+00:07:49,580 --> 00:07:54,620
+مكانها x المعادلة النتيجة بتكون هي معكوس f ده اللي
+
+72
+00:07:54,620 --> 00:07:59,430
+طيب ممتاز جدًا المرة اللي فاتت لما أخدنا تعريف معكوس
+
+73
+00:07:59,430 --> 00:08:05,070
+الدالة قلنا لو كانت النقطة A و B موجودة على الرسم
+
+74
+00:08:05,070 --> 00:08:10,870
+البياني للدالة يعني F of A بدأ يسمى مين؟ B طيب
+
+75
+00:08:10,870 --> 00:08:17,220
+النقطة B و A موجودة على منحنى مين؟ على منحنى المعكوس
+
+76
+00:08:17,220 --> 00:08:24,920
+يبقى الحالة الأولى إذا A و B موجودة على منحنى
+
+77
+00:08:24,920 --> 00:08:30,840
+الدالة F فان B و A موجودة على معكوس الدالة F 
+
+78
+00:08:30,840 --> 00:08:31,180
+inverse
+
+79
+00:08:33,940 --> 00:08:40,540
+interchanging X ب Y و Y منين؟ ب X يبقى تمامًا إذا كان
+
+80
+00:08:40,540 --> 00:08:45,440
+A و B على منحنى F فان النقطة B و A موجودة على
+
+81
+00:08:45,440 --> 00:08:50,620
+منحنى منين؟ على منحنى الـ F inverse وهذا ينطبق تمامًا
+
+82
+00:08:50,620 --> 00:08:56,000
+مع الخطوات اللي احنا قلنا عليهم دول طيب لو حبينا
+
+83
+00:08:56,000 --> 00:09:02,420
+نرسم رسم بياني لمين؟ للمعكوس تبع الدالة يعني عندي
+
+84
+00:09:02,420 --> 00:09:07,760
+رسمة الدالة و بدي أجيب الرسم البياني لمعكوس الدالة
+
+85
+00:09:07,760 --> 00:09:13,360
+احنا بنقول لو كان a و b على منحلة دالة f يبقى b و
+
+86
+00:09:13,360 --> 00:09:18,780
+a موجودة على الـ F inverse هذا معناه أن احنا بنقلب
+
+87
+00:09:18,780 --> 00:09:27,100
+رسمة الدالة F عبر الخط Y تساوي X مظبوط؟ إذا بتذكروا
+
+88
+00:09:27,100 --> 00:09:31,400
+لما درسنا الـ shift في calculus a في section واحد
+
+89
+00:09:31,400 --> 00:09:36,080
+اثنين بجينا نقول لو شيلنا الـ X و حطينا مكانها
+
+90
+00:09:36,080 --> 00:09:41,140
+السالب X بنقلب الرسم عبر محور one صحيح ولا لأ؟
+
+91
+00:09:41,140 --> 00:09:44,840
+وإذا ضربنا الدالة كلها في إشارة سالب بنقلب الرسم
+
+92
+00:09:44,840 --> 00:09:50,360
+عبر محور X ممتاز إذا نيجي هنا لأ بنقلبها عبر الخط
+
+93
+00:09:50,360 --> 00:09:57,430
+Y تساوي ممتاز أن نكتب الملاحظة هذه ونرسمها كدالة
+
+94
+00:09:57,430 --> 00:10:03,830
+ومعكوسة لنرى كيف يحصل هذا الانقلاب يبقى نكتب هذه
+
+95
+00:10:03,830 --> 00:10:12,450
+الملاحظة التالية Note the graphs of
+
+96
+00:10:12,450 --> 00:10:19,590
+الـ F and الـ F inverse الرسم البياني للدالة F و F
+
+97
+00:10:19,590 --> 00:10:28,210
+inverse are symmetric about
+
+98
+00:10:28,210 --> 00:10:33,810
+the
+
+99
+00:10:33,810 --> 00:10:43,810
+line Y تساوي X كمان
+
+100
+00:10:43,810 --> 00:11:00,210
+من هنا نقول FA و B is a point on the graph of F
+
+101
+00:11:00,210 --> 00:11:14,530
+then the point B و A is a point on
+
+102
+00:11:16,100 --> 00:11:22,140
+هو مقعد على
+
+103
+00:11:22,140 --> 00:11:29,660
+مقعد f انفراد
+
+104
+00:11:33,160 --> 00:11:39,920
+يعني فرض على سبيل المثال رسمنا رسمة الدالة F فكان
+
+105
+00:11:39,920 --> 00:11:44,780
+شكل الرسمة على الشكل اللي عندنا هذا يبقى كان هذا
+
+106
+00:11:44,780 --> 00:11:52,880
+المنحنى Y تساوي F of X قطع محور أو قطع الخط Y
+
+107
+00:11:52,880 --> 00:11:59,950
+تساوي X عند هذه النقطة الآن بدنا نرسم مين؟ المعكوس
+
+108
+00:11:59,950 --> 00:12:05,690
+تبع هذه الدالة يبقى بدنا نقلب هذه الرسم عبر خط Y
+
+109
+00:12:05,690 --> 00:12:11,990
+تسوى مين؟ X يبقى الجزء من الرسم اللي كان أعلى اللي
+
+110
+00:12:11,990 --> 00:12:16,270
+هو الخط Y تسوى X بيصير مين؟ أسفله واللي كان أسفله
+
+111
+00:12:16,270 --> 00:12:22,650
+بيصير مين؟ أعلى وهكذا طيب لو جيت افترضت أن هذه
+
+112
+00:12:22,650 --> 00:12:29,270
+النقطة مثلًا كانت سالب اثنين و Zero لما نقلب إيش
+
+113
+00:12:29,270 --> 00:12:34,490
+بده يحصل؟ Zero سالب اثنين يبقى Zero على محور X و
+
+114
+00:12:34,490 --> 00:12:39,450
+سالب اثنين بده أنزل هنا هذه المسافة جد المسافة
+
+115
+00:12:39,450 --> 00:12:44,960
+هذه بالضبط تمامًا هذا concave down إذا هذه بده يصير
+
+116
+00:12:44,960 --> 00:12:49,760
+concave up هذا هنا concave up بده يصير concave
+
+117
+00:12:49,760 --> 00:12:58,620
+down وهكذا يبقى يجيك المنحنى هكذا بهذا الشكل تمام؟
+
+118
+00:12:58,620 --> 00:13:06,360
+يبقى هذه اللي هي رسمة Y تساوي F inverse of X بهذا
+
+119
+00:13:06,360 --> 00:13:13,020
+الشكل يبقى هاي قلبنا الرسمة عبر main عبر الخط y
+
+120
+00:13:13,020 --> 00:13:18,080
+تساوي x نبدأ نشتغل الشغل الرياضي يعني الشغل العملي
+
+121
+00:13:18,080 --> 00:13:26,220
+فآخد المثال التالي example determine
+
+122
+00:13:26,220 --> 00:13:35,640
+whether or not determine whether or not
+
+123
+00:13:38,620 --> 00:13:49,240
+أو لا فالعملاء اللي يتبعون هم
+
+124
+00:13:49,240 --> 00:13:56,620
+واحد لواحد إذا
+
+125
+00:13:56,620 --> 00:14:01,380
+كان الأمر
+
+126
+00:14:01,380 --> 00:14:07,800
+كذلك فانتج انتج انتج انتج انتج انتج
+
+127
+00:14:11,990 --> 00:14:21,530
+النقطة الأولى F of X يساوي ثلاثة X تربيع زائد
+
+128
+00:14:21,530 --> 00:14:22,290
+واحدة
+
+129
+00:14:25,570 --> 00:14:30,070
+بنجي نشوف هل هذه الدالة one to one أم لا هذا
+
+130
+00:14:30,070 --> 00:14:33,890
+المطلوب الأول إذا طلعت الدالة one to one يبقى
+
+131
+00:14:33,890 --> 00:14:40,910
+المعكوس موجود يبقى بدنا هذا المعكوس تمام تمام بنجي
+
+132
+00:14:40,910 --> 00:14:45,990
+نقول F of X يساوي ثلاثة X تربيع زائد واحد بدنا نتأكد هل
+
+133
+00:14:45,990 --> 00:14:50,910
+هذه one to one أم لا عندنا أكثر من طريقة زي ما
+
+134
+00:14:50,910 --> 00:14:55,980
+اتعودنا بدل الطريقة أيه ثلاثة لكن بمجرد النظر إذا
+
+135
+00:14:55,980 --> 00:15:01,360
+الدالة كلها أسس زوجية automatic طبعا ما عليهاش 
+
+136
+00:15:01,360 --> 00:15:06,060
+condition ما يكونش فيه شرط ثاني هنا خالي هيك يبقى
+
+137
+00:15:06,060 --> 00:15:10,360
+automatic هذه ليست one to one لأن القيمة الموجبة
+
+138
+00:15:10,830 --> 00:15:14,890
+بدها تعطيني نفس القيمة السلبية، يعني لما أعوض بـ X 
+
+139
+00:15:14,890 --> 00:15:19,610
+بقيمة موجبة تماما كما لو أعوض بـ X بقيمة سلبية تطلع
+
+140
+00:15:19,610 --> 00:15:25,230
+نفس النتيجة، يعني بيصير عنصرين مختلفين واحد موجب،
+
+141
+00:15:25,230 --> 00:15:30,130
+لهما نفس الصورة إذا ليست one to one، أنو أوضح هذا
+
+142
+00:15:30,130 --> 00:15:36,990
+الكلام، فباجي بقول لو كان أخد مثلا F لـ 2 يبقى
+
+143
+00:15:36,990 --> 00:15:41,310
+F of 2 اللي هو ثلاثة في 2 تربيع زائد واحد
+
+144
+00:15:41,310 --> 00:15:48,510
+4 في 3 12 و1 13 and الـ F of
+
+145
+00:15:48,510 --> 00:15:53,850
+سالب 2 يساوي ثلاثة في سالب 2 الكل تربيع
+
+146
+00:15:53,850 --> 00:15:59,550
+زائد واحد يساوي كذلك 13 يبقى معناه هذا الكلام
+
+147
+00:15:59,550 --> 00:16:06,280
+ما له؟ الـ F is not
+
+148
+00:16:06,280 --> 00:16:13,580
+one to one because الـ F of 2 بدها تساوي F of
+
+149
+00:16:13,580 --> 00:16:20,620
+سالب 2 but ولكن 2 لا تساوي سالب 2 يبقى
+
+150
+00:16:20,620 --> 00:16:26,360
+في عندي معكوس؟ فيش ليست one to one فبناخد النقطة
+
+151
+00:16:26,360 --> 00:16:35,140
+الثانية يبقى هنا الـ F inverse does not exist مش
+
+152
+00:16:35,140 --> 00:16:42,400
+موجود خذ لي النقطة الثانية نمرة 2 بدي أخذ الـ F
+
+153
+00:16:42,400 --> 00:16:49,640
+of X بدي أساوي اللي هو 2 ناقص X لكل تكعيب
+
+154
+00:16:55,640 --> 00:17:00,620
+الآن بناعطيك طريقة أخرى عملية غير الطريقتين اللي
+
+155
+00:17:00,620 --> 00:17:03,540
+اتعودنا عليهم المرة الماضية وفي الأمثلة السابقة
+
+156
+00:17:03,540 --> 00:17:08,720
+بدي أستخدم الاشتقاق في إثبات أن هذه one to one أم
+
+157
+00:17:08,720 --> 00:17:15,200
+لا إذا هنا لو جيت قلت بدي أخذ الـ F prime of X يبقى
+
+158
+00:17:15,200 --> 00:17:22,950
+مشتقتها كم؟ هي ثلاثة في 2 ناقص X لكل تربيع في
+
+159
+00:17:22,950 --> 00:17:27,310
+مشتقة ما داخل القوس اللي هو السالب واحد يبقى بصير
+
+160
+00:17:27,310 --> 00:17:32,550
+بالشكل اللي عندنا هذا السؤال هو هدا عمرها بتاخذ
+
+161
+00:17:32,550 --> 00:17:38,450
+قيمة سالبة؟ لأ لأنها كمية مربعة سالب والله موجبة
+
+162
+00:17:38,450 --> 00:17:42,780
+لما تربعها بصير موجبة مسبوقة بإشارة مين؟ إذا
+
+163
+00:17:42,780 --> 00:17:48,540
+المقدار هذا دائما وأبدا أقل من صفر بيساوي صفر
+
+164
+00:17:48,540 --> 00:17:53,800
+فقط عند X يساوي 2 صحيح ولا لا؟ إذا هذا الكلام
+
+165
+00:17:53,800 --> 00:18:01,520
+أقل من وقد يساوي صفر for all X طب ما تفسيرك لذلك؟
+
+166
+00:18:01,520 --> 00:18:08,080
+شو الدالة F تبقى؟ decreasing ممتاز يبقى هذا يعطينا
+
+167
+00:18:08,080 --> 00:18:14,750
+أن الـ F is decreasing ما دام الـ f is decreasing
+
+168
+00:18:14,750 --> 00:18:21,530
+يبقى هذا يعطيك أن الـ f is one to one ما دام الـ f
+
+169
+00:18:21,530 --> 00:18:27,310
+one to one يبقى هذا معناه أن الـ f inverse exists
+
+170
+00:18:31,390 --> 00:18:36,750
+يبقى أثبتنا إن المعكوس موجود، الآن بدنا نوجد هذا
+
+171
+00:18:36,750 --> 00:18:41,810
+المعكوس، كيف؟ قال لي if so يعني إذا كانت الدالة
+
+172
+00:18:41,810 --> 00:18:46,170
+one to one يبقى المعكوس موجود، if so إن كان الأمر
+
+173
+00:18:46,170 --> 00:18:52,530
+كذلك أعطاني شكل المعكوس، وطبعا هذه أول مرة بناخد
+
+174
+00:18:52,530 --> 00:18:57,230
+فيها مثال على كيفية إيجاد المعكوس، الآن بنطبق
+
+175
+00:18:57,230 --> 00:19:00,930
+الكلام اللي قلناه هناك الخطوتين اللي حكينا عنهم
+
+176
+00:19:00,930 --> 00:19:07,860
+هنا قبل قليل يبقى بدنا نجي كتابة باجي بقول احنا عندنا
+
+177
+00:19:07,860 --> 00:19:13,620
+هذا الـ F of X يعني يا شباب ممكن أكتبها Y تساوي
+
+178
+00:19:13,620 --> 00:19:21,400
+2 ناقص X لكل تكعيب بدي أحلها بأي طريقة رياضية،
+
+179
+00:19:21,400 --> 00:19:26,880
+جمع، طرح، ضرب، قسمة، أخذ جذور، تكعيب، ما بعرف بأي
+
+180
+00:19:26,880 --> 00:19:31,360
+وسيلة رياضية تقدر عليها بحيث أخل الـ X في جهة
+
+181
+00:19:31,360 --> 00:19:36,220
+والباقي كله أين؟ في جهة ثانية يبقى بقوله بسيطة جدا
+
+182
+00:19:36,220 --> 00:19:41,440
+خذ الجذر الثالث للطرفين مظبوط يبقى لو أخذنا الجذر
+
+183
+00:19:41,440 --> 00:19:47,220
+الثالث للطرفين بصير الجذر الثالث لـ Y يساوي 2
+
+184
+00:19:47,220 --> 00:19:53,620
+ناقص الـ X أنا بدي X في جهة يبقى باجي بقول هنا بصير
+
+185
+00:19:53,620 --> 00:20:00,540
+عندنا الـ X يساوي 2 ناقص الجذر الثالث لـ Y
+
+186
+00:20:01,940 --> 00:20:08,760
+انتهينا من الخطوة الأولى جبنا X as a function of
+
+187
+00:20:08,760 --> 00:20:12,840
+Y اللي هي الخطوة الأولى حلينا المعادلة هذه بحيث
+
+188
+00:20:12,840 --> 00:20:17,340
+خلينا X لحالها في main في Y انتهينا من الخطوة الأولى
+
+189
+00:20:17,340 --> 00:20:22,940
+هذه الخطوة الأولى بدنا نجي للخطوة الثانية الخطوة
+
+190
+00:20:22,940 --> 00:20:26,460
+الثانية ايش بدي أعمل أو بلاش مشان الأرقام ما
+
+191
+00:20:26,460 --> 00:20:33,240
+تكونش زي بعضها حط لي هذه I وهذه II خطوة ثانية
+
+192
+00:20:33,240 --> 00:20:37,680
+بدي أعمل interchange ما بين الـ X وما بين الـ Y
+
+193
+00:20:37,680 --> 00:20:44,700
+يبقى هنا بجي بقول لك interchange الـ
+
+194
+00:20:44,700 --> 00:20:52,060
+X and الـ Y we get نحصل على ما يأتي الـ Y تساوي
+
+195
+00:20:52,060 --> 00:20:59,660
+2 ناقص الجذر الثالث لـ X مين هي هذه؟ هذا هو الـ
+
+196
+00:20:59,660 --> 00:21:07,800
+F inverse of X اللي نبحث عنه طب كويس بجان تهيرا
+
+197
+00:21:07,800 --> 00:21:14,840
+نحل السؤال هذا السؤال يعتبر تطبيق مباشر على الجزء
+
+198
+00:21:14,840 --> 00:21:21,140
+النظري اللي حكينا فيه وهو كيفية إيجاد معكوس الدالة
+
+199
+00:21:21,770 --> 00:21:26,710
+الآن مش كل المثال بتيجي بهالبساطة وبهالسهولة هيك
+
+200
+00:21:26,710 --> 00:21:32,630
+يعني بعض المثال فيها أيه فكري شوية خذ كمان مثال
+
+201
+00:21:32,630 --> 00:21:37,610
+ونشوف كيف بدنا نعمل فيه كمان مثال يبقى example 3
+
+202
+00:21:39,020 --> 00:21:45,880
+أول نقطة ثالثة بيقول الـ F of X يساوي الـ X تربيع
+
+203
+00:21:45,880 --> 00:21:52,220
+ناقص 2 X وحط لي condition أن الـ X أقل من أو
+
+204
+00:21:52,220 --> 00:22:00,000
+يساوي الـ 1 قبل ما نبدأ الحل لو جينا سألنا وقلنا
+
+205
+00:22:00,000 --> 00:22:05,200
+لو ما حط لي الـ condition هذا جالي 1 يساوي X تربيع
+
+206
+00:22:05,200 --> 00:22:14,190
+ناقص 2 هذه معادلة ايش؟ معادلة ايش هذه؟ why
+
+207
+00:22:14,190 --> 00:22:22,310
+ما هيش مربع، لكن الـ X تربيع، يبقى معادلتها ايش؟ معادلة
+
+208
+00:22:22,310 --> 00:22:27,030
+parabola بس معمولة لها shift مظبوط؟ يبقى هذه معادلة
+
+209
+00:22:27,030 --> 00:22:31,110
+parabola بس معمولة لها shift parabola يعني لو جيت
+
+210
+00:22:31,110 --> 00:22:35,090
+رسمت horizontal line هقطعها وين؟ في نقطتين بتبطل
+
+211
+00:22:35,090 --> 00:22:39,370
+تصبح one to one لكن لما أحط لي condition زي هذا x
+
+212
+00:22:39,370 --> 00:22:44,770
+أقل من أو يساوي 1 إذا احنا أخذنا interval من كل
+
+213
+00:22:44,770 --> 00:22:49,600
+real line على هذا الـ interval بأقمن أن أي
+
+214
+00:22:49,600 --> 00:22:54,240
+horizontal line لا يمكن أن يقطع المنحنى إلا في
+
+215
+00:22:54,240 --> 00:22:59,520
+نقطة واحدة وبالتالي المعكوس بيكون معه بيكون موجود
+
+216
+00:22:59,520 --> 00:23:05,560
+طيب الآن بدي أبين أن المعكوس موجود أنه جالي الـ
+
+217
+00:23:05,560 --> 00:23:09,140
+show أبين لي أن هذه الدالة one to one قبل ما تبدأ
+
+218
+00:23:09,140 --> 00:23:11,560
+مش تروح تجيب لي معكوس أو أنت مش عارف أنها one to
+
+219
+00:23:11,560 --> 00:23:17,790
+one أم لا إذاً بدنا نجي للخطوة الأولى فبدي بقوله الـ F
+
+220
+00:23:17,790 --> 00:23:25,710
+prime of X يساوي 2 X ناقص 2 الـ domain تبقى
+
+221
+00:23:25,710 --> 00:23:31,350
+عدالة من عند الواحد وبتاخذ الـ verse للخلف لو حطيت
+
+222
+00:23:31,350 --> 00:23:36,070
+x بـ 1 بيكون الناتج كده؟ صفر طب ارجع جاب لي الواحد
+
+223
+00:23:36,070 --> 00:23:40,730
+لو حطيت x بـ 0 سالب 2 لو حطيت x بسالب 1
+
+224
+00:23:40,730 --> 00:23:46,450
+سالب 2 سالب 3 يبقى كله بتاخذ قيم سالبة ما
+
+225
+00:23:46,450 --> 00:23:52,010
+عدا عند الواحد يعني معناه هذا الكلام أن هذا أقل من
+
+226
+00:23:52,010 --> 00:23:58,910
+أو يساوي صفر for all x اللي أكبر من أو تساوي 1
+
+227
+00:23:58,910 --> 00:24:05,570
+for all x اللي أقل من أو يساوي 1 كلام صحيح
+
+228
+00:24:05,570 --> 00:24:10,250
+علموكوا في الثانوية أنه لما أنت بتشتق بتسيب أول الـ
+
+229
+00:24:10,250 --> 00:24:14,730
+interval وآخر الـ interval مش هيك؟ صح؟ لما تشتقوا
+
+230
+00:24:14,730 --> 00:24:19,310
+بدك تجيب اللي هو الدالة عليك يبقى احنا لو شيلنا
+
+231
+00:24:19,310 --> 00:24:23,350
+اللي يساوي هذا وشيلنا اللي يساوي هذا بتضلها أقل من
+
+232
+00:24:23,350 --> 00:24:26,670
+الـ صفر على طول الخطوة بالثالث بيصير ايش؟
+
+233
+00:24:26,670 --> 00:24:32,510
+decreasing لو أضفت نقطة للفترة بتضلها decreasing
+
+234
+00:24:32,510 --> 00:24:37,890
+بتفرقش عندنا صحيح ولا لا؟ يبقى هذا بدو يعطيك أن
+
+235
+00:24:37,890 --> 00:24:40,730
+الـ F is decreasing
+
+236
+00:24:43,140 --> 00:24:50,160
+الـ F is decreasing يعني معناته أن الـ F is one to
+
+237
+00:24:50,160 --> 00:24:54,400
+one اللي هو المطلوب الأول من المثال ما دام one to
+
+238
+00:24:54,400 --> 00:25:00,660
+one يبقى الـ F inverse exists موجود هذا بدنا نبحث
+
+239
+00:25:00,660 --> 00:25:05,720
+عن هذا اللي هو الـ F inverse يبقى هذا النقطة اللي
+
+240
+00:25:05,720 --> 00:25:11,590
+هو النقطة الثانية بدي أقول له put y تساوي x تربيع
+
+241
+00:25:11,590 --> 00:25:18,930
+ناقص 2 x المعادلة هذه بدي أحلها بها تجيب x كده
+
+242
+00:25:18,930 --> 00:25:23,990
+اللي في main في y والـ condition عليها لا يزال
+
+243
+00:25:23,990 --> 00:25:30,370
+اللي هو الـ x ماله أقل من أو يساوي الواحد طيب بنحل
+
+244
+00:25:30,370 --> 00:25:37,050
+هذه حد بيعرف يقول لي كيف نحل هذه؟ أيوة نكمل المربع
+
+245
+00:25:37,050 --> 00:25:41,550
+ممتاز جدا يبقى لو أكملنا المربع بصير وسيلة عملية
+
+246
+00:25:41,550 --> 00:25:48,490
+سهلة للحصول على الـ X as a function of Y بنقوله
+
+247
+00:25:48,490 --> 00:25:55,190
+بسيطة يبقى Y يساوي X تربيع ناقص 2 X نرجع ثاني
+
+248
+00:25:55,190 --> 00:25:58,970
+لإكمال المربع علمناكوا يا في كل كلاصية بنشوف ضايل
+
+249
+00:25:58,970 --> 00:26:05,720
+في دماغك ولا غاب ممتاز جدا يبقى المعادلة عندي
+
+250
+00:26:05,720 --> 00:26:13,160
+مشان أعملها أكمل المربع بضيف وبطرح مربع معامل x 
+
+251
+00:26:13,160 --> 00:26:17,880
+على أربع أمثال معامل x تربيع اللي ناس يكتب عنده
+
+252
+00:26:17,880 --> 00:26:22,240
+سجل عندك اللي عارف عارف وخلاص يبقى بنضيف للمعادلة
+
+253
+00:26:22,240 --> 00:26:28,680
+وبنطرح مربع معامل x على أربع أمثال معامل x تربيع
+
+254
+00:26:29,170 --> 00:26:36,510
+نشوف هذا على أرض الواقع مربع معامل x أربعة ومعامل
+
+255
+00:26:36,510 --> 00:26:41,510
+x تربيع واحد أربعة أمثاله أربعة أربعة على أربعة
+
+256
+00:26:41,510 --> 00:26:46,830
+يبقى بنضيف واحد ونطرح واحد يبقى باجي بقول هنا زائد
+
+257
+00:26:46,830 --> 00:26:52,450
+واحد ناقص واحد هل تغير وضع المعادلة بهذه الإضافة؟
+
+258
+00:26:52,450 --> 00:26:55,910
+وهذه الطريقة لأ يعني كأن ضايف صفر يبقى احنا
+
+259
+00:26:55,910 --> 00:27:00,530
+ما عملناش جديد ولا حاجة لكن هذا له فائدة كبرى، ما
+
+260
+00:27:00,530 --> 00:27:04,230
+هي الفائدة الكبرى؟ لو نقلت الواحد على الجهة
+
+261
+00:27:04,230 --> 00:27:10,050
+الثانية بصير Y زائد واحد يساوي X ناقص واحد الكل
+
+262
+00:27:10,050 --> 00:27:15,900
+تربيع، أيوة، هيك صارت القصة سهلة إذا بدنا نروح
+
+263
+00:27:15,900 --> 00:27:23,240
+ناخد الجذر التربيعي للطرفين، ممتاز جدا، ها لا يزال
+
+264
+00:27:23,240 --> 00:27:27,720
+عند ال X أقل من أو يساوي الواحد، ناخد الجذر
+
+265
+00:27:27,720 --> 00:27:32,340
+التربيعي للطرفين، يبقى بيصير عند الجذر التربيعي ل
+
+266
+00:27:32,340 --> 00:27:37,220
+Y زائد واحد يساوي، قداش الجذر التربيعي لهذا
+
+267
+00:27:37,220 --> 00:27:43,050
+المقدار؟ حد بيعرف؟ بدي واحد يحكي مشان نتناقش مع
+
+268
+00:27:43,050 --> 00:27:46,550
+هالكلام هو صح ولا غلط، اه مين يا مين عارف القداش
+
+269
+00:27:46,550 --> 00:27:48,090
+الجذر التربيعي لهذا المقدار؟
+
+270
+00:27:51,790 --> 00:27:55,830
+بنقول موجب وسالب X ناقص واحد وموجب وسالب X
+
+271
+00:27:55,830 --> 00:27:59,230
+ناقص واحد وموجب وسالب X ناقص واحد وموجب وسالب
+
+272
+00:27:59,230 --> 00:28:00,610
+X ناقص واحد وموجب وسالب X ناقص واحد وموجب
+
+273
+00:28:00,610 --> 00:28:04,150
+وسالب X ناقص واحد وموجب وسالب X ناقص واحد
+
+274
+00:28:04,150 --> 00:28:07,550
+وموجب وسالب X ناقص واحد وموجب وسالب X ناقص
+
+275
+00:28:07,550 --> 00:28:09,270
+واحد وموجب وسالب X ناقص واحد وموجب وسالب X
+
+276
+00:28:09,270 --> 00:28:15,970
+ناقص واحد وموجب وسالب X ناقص واحد وموجب وسالب
+
+277
+00:28:15,970 --> 00:28:22,380
+X ناقص واحد وعندك هنا ما له؟ ال X أقل من أو
+
+278
+00:28:22,380 --> 00:28:28,140
+يساوي واحد، بالعادة عند الواحد وأقل منه، اللي بين
+
+279
+00:28:28,140 --> 00:28:31,220
+الشرط ال absolute value، قيمة موجبة والله سالبة
+
+280
+00:28:31,830 --> 00:28:36,150
+سالبة مادام سالبة إذا بقدر أتخلص من ال absolute
+
+281
+00:28:36,150 --> 00:28:41,510
+value وأحط قوس وقبله إشارة سالب يبقى هذا بدي
+
+282
+00:28:41,510 --> 00:28:46,950
+أعطيلك إن الجذر التربيعي ل Y زائد واحد يساوي سالب
+
+283
+00:28:46,950 --> 00:28:53,810
+ال X ناقص الواحد أو إن شئتم فقولوا إن سالب الجذر
+
+284
+00:28:53,810 --> 00:28:59,630
+التربيعي ل Y زائد واحد يساوي X ناقص الواحد
+
+285
+00:29:15,700 --> 00:29:22,320
+هذا الشغل اللي اشتغلنا من هنا لغاية هنا كله لسه
+
+286
+00:29:22,320 --> 00:29:29,620
+الخطوة الأولى إن حاولت أحل المعادلة اللي عندي فوق و
+
+287
+00:29:29,620 --> 00:29:34,660
+أعمل X as a function of Y إذا هذا بيختلف عن المثال
+
+288
+00:29:34,660 --> 00:29:37,300
+اللي جاب له مثل اللي جاب له automatic سهل ومشي معانا
+
+289
+00:29:37,300 --> 00:29:42,380
+دغري هذا يحتاج إلى شوية شغل رياضي يبقى أنت بدك
+
+290
+00:29:42,380 --> 00:29:47,640
+تحول المعادلة X بدلالة Y بأي طريقة رياضية تعلمتها
+
+291
+00:29:47,640 --> 00:29:53,490
+قبل هيك بأي وسيلة إن كانت بس تبقى الوسيلة صحيحة مش
+
+292
+00:29:53,490 --> 00:29:57,990
+تبقى تخبيص كويس يبقى ال X صارت بالشكل اللي عندنا
+
+293
+00:29:57,990 --> 00:30:05,430
+هذا الآن بنجي للخطوة الثانية وهي إني أبدل كل X ب
+
+294
+00:30:05,430 --> 00:30:12,840
+Y وكل Y ب X ولا تزال عندنا X أقل من أو تساوي 1 إذا
+
+295
+00:30:12,840 --> 00:30:17,880
+بدي أعمل interchange يبقاش بصير عند هنا بصير عند Y
+
+296
+00:30:17,880 --> 00:30:25,200
+تساوي واحد ناقص الجذر التربيعي ل X زائد واحد وهنا
+
+297
+00:30:25,200 --> 00:30:31,770
+أقول X أقل من أو تساوي واحد غلط لما اتغيرتش وأثبت
+
+298
+00:30:31,770 --> 00:30:36,530
+ثاني؟ ما ينفعش، كل X بدك تغيرها ب Y، أنا عندي هنا X
+
+299
+00:30:36,530 --> 00:30:41,990
+أقل من أو تساوي واحد، يبقى بالعادة أقول له وال Y أقل من
+
+300
+00:30:41,990 --> 00:30:48,110
+أو تساوي من أقل من أو تساوي الواحد طيب استنى شوية
+
+301
+00:30:48,110 --> 00:30:52,670
+احنا دائما من أول حياتنا لما نقول ال Y ده اللي في
+
+302
+00:30:52,670 --> 00:30:56,850
+X بنقول ال X بتتغير من كذا لكذا لأن هي المتغير
+
+303
+00:30:56,850 --> 00:31:01,750
+اللي هو المستقل وال Y هي المتغير التابع مظبوط ولا
+
+304
+00:31:01,750 --> 00:31:06,630
+لا؟ يبقى باجي بقول اه أنا ما بديش Y أقل من أو يساوي
+
+305
+00:31:06,630 --> 00:31:11,290
+واحد بدي X تكون مش عارف على أن هي فترة جد ما تطلع
+
+306
+00:31:11,290 --> 00:31:16,570
+تطلع، بقول بسيطة جدا، ما أنت عندك أي Y بدلالة X،
+
+307
+00:31:16,570 --> 00:31:21,230
+يبقى بدي أشيل Y هذه وأحط قيمتها وأحل ال
+
+308
+00:31:21,230 --> 00:31:24,570
+equality اللي عندي وبالتالي بحدد X حتى تتغير من
+
+309
+00:31:24,570 --> 00:31:32,020
+ويلة و ويلة مظبوط طيب هذه لحالها بقدر أكتبها ايش
+
+310
+00:31:32,020 --> 00:31:36,940
+اللي هو الواحد ناقص الجذر التربيعي ل X زائد واحد
+
+311
+00:31:36,940 --> 00:31:44,150
+أقل من أو يساوي الواحد أنا شيلت ال Y وحطيت قيمتها
+
+312
+00:31:44,150 --> 00:31:46,830
+اللي هو كل القيمة اللي عندنا عليها وبدها حل ال
+
+313
+00:31:46,830 --> 00:31:52,050
+inequality يعني يبقى لو جيبنا هذه هنا وهذه هنا
+
+314
+00:31:52,050 --> 00:32:00,030
+بصير المعادلة الجذر التربيعي ل X زائد واحد أكبر من
+
+315
+00:32:00,030 --> 00:32:05,360
+أو تساوي ال zero صحيح؟ طيب احنا بدنا X بالربع
+
+316
+00:32:05,360 --> 00:32:10,780
+الطرفين إذا لو ربعنا الطرفين بصير إن مين ال X زائد
+
+317
+00:32:10,780 --> 00:32:16,600
+واحد أكبر من أو تساوي zero أو ال X أكبر من أو
+
+318
+00:32:16,600 --> 00:32:24,540
+تساوي من سالب واحد بناء عليه صار ال F inverse of x
+
+319
+00:32:24,540 --> 00:32:30,760
+يساوي واحد ناقص ل square root لل X زائد واحد وال X
+
+320
+00:32:30,760 --> 00:32:37,260
+greater than or equal لسالب one يعني لو جاك سؤال
+
+321
+00:32:37,260 --> 00:32:41,480
+هيك والله قابلت في التمرين سؤال بهذا الشكل مش
+
+322
+00:32:41,480 --> 00:32:45,480
+تشتغل على الدالة وتسيب ال domain زي ما اشتغلت على
+
+323
+00:32:45,480 --> 00:32:47,740
+الدالة بقى تشتغل على ال domain تبعها طبعا ال
+
+324
+00:32:47,740 --> 00:32:51,220
+domain تبعها كان من ولا وين من سالب infinity
+
+325
+00:32:51,220 --> 00:32:56,600
+لغاية الواحد ولع ال domain تبع ال F inverse من عند
+
+326
+00:32:56,600 --> 00:33:01,800
+السالب واحد إلى infinity أكبر من أو يساوي من سالب
+
+327
+00:33:01,800 --> 00:33:08,880
+واحد وهذا نتيجة لقلب المنحنى عبر الخط Y تساوي X
+
+328
+00:33:08,880 --> 00:33:16,360
+طيب ما اختلفناش ما اختلفناش بنفع
+
+329
+00:33:16,360 --> 00:33:16,960
+ايش؟
+
+330
+00:33:21,210 --> 00:33:27,190
+هذا إذا بتقدر، وإذا ما قدرت، بصير صعب، زميلكم بطرح
+
+331
+00:33:27,190 --> 00:33:32,650
+سؤال وجيه، بقول كويس، أنا عندي الدالة هذه، وعندي
+
+332
+00:33:32,650 --> 00:33:38,110
+هذه ال domain تبعها، إذا قدرت أحدد ال range تبع
+
+333
+00:33:38,110 --> 00:33:41,250
+الدالة F يبقى هو ال domain، إلا ال F inverse
+
+334
+00:33:41,250 --> 00:33:44,630
+ما يقوله والله على الروح بيوسعها، كلامك مظبوط وفوق
+
+335
+00:33:44,630 --> 00:33:48,290
+رأسنا، وبالتالي بترتاح من مين؟ من الشغلة اللي
+
+336
+00:33:48,290 --> 00:33:52,110
+اشتغلناها هذه، إذا قلت حدد ال domain تبع الدالة F
+
+337
+00:33:52,110 --> 00:33:58,450
+بيكون هو ال domain تبع مين؟ بيقول له كلامك صحيح،
+
+338
+00:33:58,450 --> 00:34:06,310
+مين أو شو اسمك أنت؟ إبراهيم يبقى إبراهيم جاب لنا وجهة
+
+339
+00:34:06,310 --> 00:34:10,690
+نظر أخرى غير وجهة النظر اللي احنا قلنا لكم إياها وكيلة
+
+340
+00:34:10,690 --> 00:34:14,490
+الوجهتين اللي هو الصحية وجهة النظر تبعتنا وجهة
+
+341
+00:34:14,490 --> 00:34:17,750
+النظر اللي قالها وإذا فينا وجهة نظر أخرى برضه
+
+342
+00:34:17,750 --> 00:34:27,150
+مستعدين نسمعها إذا فيها آية تفضل ماشي
+
+343
+00:34:40,010 --> 00:34:45,590
+ثاني ثاني احكي ثاني اه
+
+344
+00:34:45,590 --> 00:34:52,590
+بطلع صفر ولا لأ ولا بطلع سالب واحد مية المية تمام
+
+345
+00:34:54,080 --> 00:34:58,940
+يبقى ايش صارت؟ صارت دمعة، بس خليك معايا صارت كده؟
+
+346
+00:34:58,940 --> 00:35:03,020
+حبيت أنت تكسب واحد، يبقى صارت النقطة واحد وسالب
+
+347
+00:35:03,020 --> 00:35:08,880
+واحد، تمام؟ ما بيقلبها، ماشي، هتشوف صح هنا ولا لا؟
+
+348
+00:35:10,390 --> 00:35:17,930
+مظبوط؟ خلاص اتفجنا احنا وإياك مافي مشكلة حتى
+
+349
+00:35:17,930 --> 00:35:22,610
+لأن يا شباب احنا جيبنا كيفية إيجاد معكوس الدالة
+
+350
+00:35:22,610 --> 00:35:26,790
+لكن العنوان اللي مكتوب عندك في بداية ال section ال
+
+351
+00:35:26,790 --> 00:35:32,370
+inverse functions and their derivatives يبقى بدنا
+
+352
+00:35:32,370 --> 00:35:39,570
+نروح نبحث عموما عن مشتقة معكوس الدالة يبقى الآن
+
+353
+00:35:39,570 --> 00:35:44,650
+بدنا نتكلم عن ال derivative لمين؟ لمعكوس الدالة
+
+354
+00:35:44,650 --> 00:35:49,810
+اللي عندنا هذه خلينا
+
+355
+00:35:49,810 --> 00:35:55,370
+نطرح السؤال التالي ونشوف كيفية الإجابة عليه الآن
+
+356
+00:35:55,370 --> 00:36:01,250
+عشان أجيب مشتقة معكوس الدالة ضروري أجيب المعكوس ثم
+
+357
+00:36:01,250 --> 00:36:02,410
+أروح أشتقه؟
+
+358
+00:36:04,940 --> 00:36:13,520
+ليس بالضرورة لكن هنجيب ايه؟ مشتقة الدالة هتجيب
+
+359
+00:36:13,520 --> 00:36:19,300
+المعكوس مش بدنا فيه بصير احنا بدنا مشتقة معكوس
+
+360
+00:36:19,300 --> 00:36:27,340
+الدالة طبعا طيب هجربكم الفكرة أنا عندي دالة و
+
+361
+00:36:27,340 --> 00:36:31,940
+أثبت أن المعكوس تبعها exist هل بقدر أوجد شكل
+
+362
+00:36:31,940 --> 00:36:39,780
+المعكوس؟ ممكن نعم بنقدر وممكن لا أعطيك مثال بسيط لو
+
+363
+00:36:39,780 --> 00:36:45,380
+جاتي أقول خذ لي f of x يساوي دقيقة معايا كويس X أس
+
+364
+00:36:45,380 --> 00:36:55,720
+11 زائد 2 X أس 7 زائد 3 X أس 5 زائد 4 X تكعيب زائد
+
+365
+00:36:55,720 --> 00:37:02,050
+X ناقص 1 كل الأسس فردية، بده أشوف ال universe exist
+
+366
+00:37:02,050 --> 00:37:07,010
+ولا لا، بروح أشتقها، بصير الأولى أس 10، والثانية
+
+367
+00:37:07,010 --> 00:37:12,810
+أس 6، واللي بعدها أس 4، واللي بعدها أس
+
+368
+00:37:12,810 --> 00:37:18,220
+2، واللي بعدها كونستانت كلها أكبر من ال zero صح
+
+369
+00:37:18,220 --> 00:37:22,100
+ولا لا؟ لأن الأسس كلها زوجية يبقى هذا الكل
+
+370
+00:37:22,100 --> 00:37:24,260
+أكبر من ال zero يبقى ده اللي increasing يبقى ال
+
+371
+00:37:24,260 --> 00:37:29,540
+inverse exist حد فيكم بيقدر يحل المعادلة هذه وإني
+
+372
+00:37:29,540 --> 00:37:33,160
+زيكم بقدرش مش أنت بتقول لأ لأ وإني زيكم بقدرش
+
+373
+00:37:33,160 --> 00:37:38,110
+أحل المعادلة هذه هذه المعادلة في غاية التعقيد خارج
+
+374
+00:37:38,110 --> 00:37:41,530
+نطاق شغل ما نقدرش عليها يبقى احنا أثبتنا إن
+
+375
+00:37:41,530 --> 00:37:47,130
+المعكوس موجود لكن مش قادرين نوجد هذا المعكوس وهذا 
+
+376
+00:37:47,130 --> 00:37:52,490
+من قصور العقل البشري يعني العقل البشري قاصر
+
+377
+00:37:52,490 --> 00:37:56,420
+عن إدراك مكنونات الأشياء اللي بيحس فيها في هذا
+
+378
+00:37:56,420 --> 00:38:00,520
+الكون أو في هذه الحياة وهذا من قدرة الله تبارك
+
+379
+00:38:00,520 --> 00:38:05,260
+وتعالى زي إيش مثلا؟ زي امبارح كان فيها شوية ريح صح
+
+380
+00:38:05,260 --> 00:38:07,760
+ولا لا؟ كان ريح جو امبارح، مش اليوم ساكت الريح
+
+381
+00:38:07,760 --> 00:38:12,520
+امبارح كان ريح جوي، بقينا نقدر نشوف ضغط الريح اللي
+
+382
+00:38:12,520 --> 00:38:17,180
+حاليا نحس فيه ونقيس اتجاه الريح وسرعة الريح، صح ولا
+
+383
+00:38:17,180 --> 00:38:21,580
+لا؟ لكن حد فينا عمره شاف الريح؟ لا، ولا واحد
+
+384
+00:38:21,580 --> 00:38:25,920
+بيشوفه، بنشوف أثره على الأشجار، نلاقي الأشجار
+
+385
+00:38:25,920 --> 00:38:30,340
+بتتميل، بنشوف هذا تأثيره عليه، لكن هل في واحد عمره 
+
+386
+00:38:30,340 --> 00:38:35,520
+شاف شكل الهواء ولا طعم الهواء ولا كده؟ أبدا،
+
+387
+00:38:35,520 --> 00:38:40,360
+العقل البشري في عنده قصور، لو بريك الكهربا هذه، لو
+
+388
+00:38:40,360 --> 00:38:43,880
+جيبنا سلك الكهربا، مشان تعرف هي كهربا، لازم تحط
+
+389
+00:38:43,880 --> 00:38:48,910
+إصبعك عليها أو تجيب تستر وتشوفه بضج ولا لا، يجي هذا
+
+390
+00:38:48,910 --> 00:38:52,950
+تأثير الكهربا على اللمضة تبع التستر، نوط على إصبعك
+
+391
+00:38:52,950 --> 00:38:58,990
+بتلطعك ولا لا؟ آه، وربما تروح فيها الله أعلم، آه، و
+
+392
+00:38:58,990 --> 00:39:03,450
+بنجرى الفاتحة بعد هيك كويس، يبقى في مثل هذه الحالة
+
+393
+00:39:03,450 --> 00:39:08,230
+لحتى لو جشرنا أو شيلنا الغطاء البلاستيكي اللي على
+
+394
+00:39:08,230 --> 00:39:12,030
+السلك، بنقدر نعرف أنه فيه كهربا من دون تستر ولا من
+
+395
+00:39:12,030 --> 00:39:15,890
+دون ما نلمسها بإصبعنا؟ نقدرش، إذا العقل البشري
+
+396
+00:39:15,890 --> 00:39:22,190
+والنظر البشري والحس البشري قاصر عن إدراك مكنونات
+
+397
+00:39:22,190 --> 00:39:26,950
+الأشياء الموجودة في هذا الكون، وهذا من إعجاز الله 
+
+398
+00:39:26,950 --> 00:39:31,830
+للإنسان حتى نؤمن بالله سبحانه وتعالى الذي لا نراه،
+
+399
+00:39:31,830 --> 00:39:35,930
+تمام؟ إذا نرجع لموضوعنا، بدناش نتشعر كتير، بلاش
+
+400
+00:39:35,930 --> 00:39:38,930
+تقولوا لهذا محاضرة في أصول الدين، في العقيدة يعني،
+
+401
+00:39:38,930 --> 00:39:44,170
+مش هناك، بنقولكوا ماشي، لكن هذه لها ارتباط بموضوعنا،
+
+402
+00:39:44,170 --> 00:39:48,830
+إذا إيش رأيكوا؟ أنا ما أقدرش أجيب المعكوس تبع
+
+403
+00:39:48,830 --> 00:39:53,130
+الدلالة، لكن بقدر أجيب مشتقته، كيف؟ كالتالي، طبقا
+
+404
+00:39:53,130 --> 00:40:06,870
+للنظرية التالية، اكتب معايا: theorem if 
+
+405
+00:40:06,870 --> 00:40:09,250
+the domain
+
+406
+00:40:10,340 --> 00:40:19,980
+of the function F is the interval I
+
+407
+00:40:19,980 --> 00:40:24,280
+and it exists
+
+408
+00:40:24,280 --> 00:40:34,000
+and the F prime of X does not equal to zero على
+
+409
+00:40:34,000 --> 00:40:43,560
+الفترة I on the interval I then the F inverse is
+
+410
+00:40:43,560 --> 00:40:54,200
+differentiable at every point at every point عند
+
+411
+00:40:54,200 --> 00:41:02,560
+كل نقطة in its domain عند كل نقطة في ال domain
+
+412
+00:41:02,560 --> 00:41:08,100
+تبعها the value of
+
+413
+00:41:10,260 --> 00:41:16,400
+the F inverse prime at
+
+414
+00:41:16,400 --> 00:41:30,840
+a point at a point B اللي هي بدها تساوي F of A in
+
+415
+00:41:30,840 --> 00:41:37,980
+the domain of F inverse
+
+416
+00:42:03,550 --> 00:42:18,650
+اللي بده يساوي F inverse of B أي أن D F inverse على
+
+417
+00:42:18,650 --> 00:42:29,130
+DX عندما ال X تساوي ال B لل F of A بده يساوي واحد
+
+418
+00:42:29,130 --> 00:42:39,830
+على DF على DX لما ال X بده يساوي A ل F inverse of
+
+419
+00:42:39,830 --> 00:42:43,670
+B نرجع
+
+420
+00:42:43,670 --> 00:42:49,530
+لكلام اللي احنا كتبينه هذا، نقرأ كل كلامنا ككاتبينه
+
+421
+00:42:49,530 --> 00:42:55,290
+ونشرحه بتفصيل مشان نفهم كل نقطة في نص النظرية بقول
+
+422
+00:42:55,290 --> 00:43:00,610
+لو كان domain دالة F هو الفترة اللي عندنا I وكان
+
+423
+00:43:00,610 --> 00:43:05,250
+مشتقة الدالة exist يبقى الدالة قابلة للاشتقاق
+
+424
+00:43:05,250 --> 00:43:10,070
+اثنين، المشتقة لا يمكن أن تساوي zero does not equal
+
+425
+00:43:10,070 --> 00:43:15,030
+to zero، ليش هذا ما سنعرفه بعد قليل، يعني ليش حطيت ال
+
+426
+00:43:15,030 --> 00:43:20,150
+condition أن ال f prime of x لا تساوي zero، بقول هذا
+
+427
+00:43:20,150 --> 00:43:25,530
+الكلام على الفترة I، يبقى في هذه الحالة بكون معكوسة
+
+428
+00:43:25,530 --> 00:43:30,650
+الدالة هي دالة قابلة لمين؟ للاشتقاق، ال F inverse is
+
+429
+00:43:30,650 --> 00:43:36,330
+differentiable عن كل نقطة في دومينها، الآن قيمة
+
+430
+00:43:36,330 --> 00:43:39,570
+مشتقة معكوسة ده اللي احنا بنقول ال F
+
+431
+00:43:39,570 --> 00:43:43,710
+inverse differentiable يعني قابلة للاشتقاق، إذا مشتقة
+
+432
+00:43:43,710 --> 00:43:49,590
+معكوسة ده اللي عندنا نقطة B اللي أصلها هو A في 
+
+433
+00:43:49,590 --> 00:43:54,850
+domain of the F عند B يعني B في domain الـ F
+
+434
+00:43:54,850 --> 00:43:59,290
+inverse والـ A في دومين الـ F يبقى عند النقطة B
+
+435
+00:43:59,290 --> 00:44:03,230
+بدها تساوي F of A in the domain of F inverse is the
+
+436
+00:44:03,230 --> 00:44:07,930
+reciprocal يعني شبه مقلوب، مقلوب يعني كان في ال bus
+
+437
+00:44:07,930 --> 00:44:13,250
+بنزله في المقام يعني A بصير واحد على A، عشرة بصير
+
+438
+00:44:13,250 --> 00:44:17,090
+واحد على عشرة، هي مقلوبة، is the reciprocal مقلوب
+
+439
+00:44:17,090 --> 00:44:25,490
+the value of F prime هو مقلوب مشتقة الدالة F عند
+
+440
+00:44:25,490 --> 00:44:31,690
+النقطة A التي هي F inverse of B، التلت أسطر ونص
+
+441
+00:44:31,690 --> 00:44:38,240
+هذول بنروح نصيغهم في سطر واحد فقط، لغاية فبنروح نقولنا
+
+442
+00:44:38,240 --> 00:44:42,080
+that is I am نا يعني التلات أسطر ونص بدنا نصيغهم
+
+443
+00:44:42,080 --> 00:44:47,460
+بالصيغة الرياضية العملية نشتغل بها في حال المثال، ديقول
+
+444
+00:44:47,460 --> 00:44:54,740
+يبقى مشتقة معكوس الدالة D F inverse على DX وين؟ عند
+
+445
+00:44:54,740 --> 00:45:00,680
+X تساوي B اللي موجودة في دومين الـ F inverse، من ال
+
+446
+00:45:00,680 --> 00:45:04,680
+A هي اللي في دومين الـ F، بدل ما يساوي F of A يساوي
+
+447
+00:45:04,680 --> 00:45:10,600
+من ريس بروكل يبقى مقلوب، قلنا واحد على مشتقة الدالة
+
+448
+00:45:10,600 --> 00:45:16,080
+F وين؟ عند النقطة A اللي موجودة في دومين الدالة F، وال
+
+449
+00:45:16,080 --> 00:45:21,850
+A هي F inverse of B، يبقى إذا بدي أجيب مشتقة معكوس
+
+450
+00:45:21,850 --> 00:45:26,650
+الدالة عند نقطة بدي أشوف النقطة المكافئة لها أو
+
+451
+00:45:26,650 --> 00:45:32,930
+صورتها وين؟ في domain الدالة F، وبالتالي بقول واحد
+
+452
+00:45:32,930 --> 00:45:39,430
+على مشتقة الدالة F عند هذه النقطة، لحظة، النقطة هذه
+
+453
+00:45:39,430 --> 00:45:45,840
+هي اللي موجودة في domain الدالة أف مظبوط، والإيه هي
+
+454
+00:45:45,840 --> 00:45:51,520
+صورة معكوس الدالة عند بيه في F inverse of B، مين
+
+455
+00:45:51,520 --> 00:45:58,580
+وهذا الكلام التعريف اللي قلناه يوم أمس الأول، طيب
+
+456
+00:45:58,580 --> 00:46:04,680
+يبقى هذا كيفية الحصول على مشتقة معكوس الدالة دون
+
+457
+00:46:04,680 --> 00:46:09,660
+الحصول على شكل المعكوس، هل يتطلب الأمر أعرف شكل
+
+458
+00:46:09,660 --> 00:46:13,030
+المعكوس؟ إذا المثال اللي توسعنا قلنا احنا وياكوا
+
+459
+00:46:13,030 --> 00:46:16,410
+الشفوي هذا الـ Apoxys 11 المعادلة الـ polynomial
+
+460
+00:46:16,410 --> 00:46:20,490
+الطويلة هذه، أثبتنا أن الـ F inverse exist لكن مش
+
+461
+00:46:20,490 --> 00:46:25,150
+قادرين نجيبه، لكن بقدر أجيب مشتقة معكوسة الدالة
+
+462
+00:46:25,150 --> 00:46:30,850
+بواسطة مين؟ بواسطة هذه النظرية عند أي نقطة موجودة
+
+463
+00:46:30,850 --> 00:46:38,440
+في domain الـ F inverse، الآن لم يبقى في هذا section
+
+464
+00:46:38,440 --> 00:46:44,620
+إلا مجموعة من الأمثلة، نتعرض لها في المحاضرة القادمة إن
+
+465
+00:46:44,620 --> 00:46:45,680
+شاء الله تعالى
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/jTcVRskg5cM_raw.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/jTcVRskg5cM_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..df2f364f9282c8a49b6424cf07f6065b95466585
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/jTcVRskg5cM_raw.srt
@@ -0,0 +1,1860 @@
+1
+00:00:00,000 --> 00:00:02,680
+موسيقى
+
+2
+00:00:10,930 --> 00:00:15,190
+بسم الله الرحمن الرحيم اليوم ان شاء الله بنكمل عن
+
+3
+00:00:15,190 --> 00:00:18,490
+الموضوع اللى بدنا فيه المرة الماضية وهو ال inverse
+
+4
+00:00:18,490 --> 00:00:22,650
+function معكوس الدالة اخر حاجة اعطيناها المرة اللى
+
+5
+00:00:22,650 --> 00:00:28,630
+فات كان مثال على كيفية اثبات ان دالتين واحدة معكوس
+
+6
+00:00:28,630 --> 00:00:33,530
+للثانية الان بناخد مثال اخر حول نفس المفهوم لكن
+
+7
+00:00:33,530 --> 00:00:37,950
+بفكرة اخرى المثال بيقول ما يأتي let ال F of X
+
+8
+00:00:40,820 --> 00:00:48,340
+الـ f of x تساوي اللي هو الـ x تكيب زائد اتنين x
+
+9
+00:00:48,340 --> 00:00:55,700
+ناقص ثلاثة المطلوب
+
+10
+00:00:55,700 --> 00:01:05,320
+find the value of
+
+11
+00:01:05,320 --> 00:01:18,310
+a fال F inverse of A بده يساوي اتنين solution
+
+12
+00:01:26,960 --> 00:01:31,980
+هذا المثال يختلف عن المثال السابق لكن يحوم حول نفس
+
+13
+00:01:31,980 --> 00:01:36,260
+الفكرة تماما المرة اللي فاتت اعطاناك two functions
+
+14
+00:01:36,260 --> 00:01:41,400
+وقولنا اثبت ان هذه الدالة هي معكوز لدالة ثانية وقد
+
+15
+00:01:41,400 --> 00:01:45,740
+اثبتنا ذلكهذا المعطيين f of x ساوي x تكييب زايد
+
+16
+00:01:45,740 --> 00:01:50,540
+اتنين x ناقص تلاتة و قال لي هاتلي قيمة اللي هو a
+
+17
+00:01:50,540 --> 00:01:55,760
+بحيث ان ال f inverse of a بده يساوي مين تساوي
+
+18
+00:01:55,760 --> 00:02:00,300
+اتنين اذا المعطيات اللي عندنا في هذه المسألة هي f
+
+19
+00:02:00,300 --> 00:02:08,010
+inverse of a بده يساوي قداش اتنينبدنا قيمة A يعني
+
+20
+00:02:08,010 --> 00:02:12,990
+معناته بدنا نتخلص من ال F inverse تمام؟ بدك تعمل
+
+21
+00:02:12,990 --> 00:02:18,290
+أي شغلة رياضية بواسطتها تتخلص من ال F inverse واضح
+
+22
+00:02:18,290 --> 00:02:23,830
+انه من هذه المعادلة انه لو جينا أثرنا على الطرفين
+
+23
+00:02:23,830 --> 00:02:29,730
+بمين؟بدالة F ممتاز جدا يبقى لو أثرنا على الطرفين
+
+24
+00:02:29,730 --> 00:02:35,270
+بدالة F بنتخلص من مين و بنحصل على مين و بعد هيك
+
+25
+00:02:35,270 --> 00:02:41,570
+ربك بفرجها يبقى بنيجي بنقول هنا ال F لل F inverse
+
+26
+00:02:41,570 --> 00:02:49,060
+of A بده يساوي ال F of اتنينطب الخطوة اللى عملتها
+
+27
+00:02:49,060 --> 00:02:55,160
+خطوة صحيحة ولا خطوة ليست صحيحة الاجابة الخطوة خطوة
+
+28
+00:02:55,160 --> 00:03:00,880
+صحيحة لماذا لإنه لما نقول F inverse of A يساوي 2
+
+29
+00:03:00,880 --> 00:03:06,540
+معناته ال A في domain ال F inverse و 2 في ال range
+
+30
+00:03:06,540 --> 00:03:10,660
+تبع ال F inverse اللى هو domain مين domain ال F
+
+31
+00:03:10,660 --> 00:03:14,840
+ممتاز جدا يبقى مادام في domain ال F إذا ال F بتقدر
+
+32
+00:03:14,840 --> 00:03:19,330
+تأثر على 2 يبقى الخطوة اللى عملتهاخطوة صحيحة ماحدش
+
+33
+00:03:19,330 --> 00:03:24,530
+بقدر يقولي خطوة تكادى خطأ تمام تمام طيب الدالة لو
+
+34
+00:03:24,530 --> 00:03:29,350
+معكوسها هذا يعتبر ال composition ما بين الاتنين او
+
+35
+00:03:29,350 --> 00:03:34,170
+واحدة تلغى التانية يبقى بيصير عندنا ال A بده يساوي
+
+36
+00:03:34,170 --> 00:03:39,410
+ال F of اتنين يبقى ال A تساوي باجي على الدالة اللى
+
+37
+00:03:39,410 --> 00:03:45,350
+عندى و بشيل كل X و بحط مكانهاأتنين يبقى اتنين الكل
+
+38
+00:03:45,350 --> 00:03:52,130
+تكييب زائد اتنين في اتنين ناقص تلاتة هذا بده يقين
+
+39
+00:03:52,130 --> 00:03:58,710
+ان ال a تساوي تمانية واربعة اتناش شيل منهم تلاتة
+
+40
+00:03:58,710 --> 00:04:04,670
+بيظل كده؟ بيظل تسعة اذا قيمة a تساوي تسعة اللي هو
+
+41
+00:04:04,670 --> 00:04:12,060
+المطلوب تبع المثلةالان حتى الان ماقولناش كيف بدنا
+
+42
+00:04:12,060 --> 00:04:15,140
+نحسب المعكوس تبع الدالة
+
+43
+00:04:21,910 --> 00:04:33,130
+مش هنجيب شكل
+
+44
+00:04:33,130 --> 00:04:41,770
+المعكوس نعمل خطوات لا ثالث لهماما هي الخطوات
+
+45
+00:04:41,770 --> 00:04:48,330
+الأثنين؟ الخطوة الأولى نحن لدينا y كدلة في x y
+
+46
+00:04:48,330 --> 00:04:55,700
+تساوي f of x هي المعطة عندنابتروح تعمل x كدلة في y
+
+47
+00:04:55,700 --> 00:04:59,640
+يعني بدي اعمل ايه كأنه بدي اغير وضع ال variable
+
+48
+00:04:59,640 --> 00:05:05,540
+يبقى بدي اجيب x as a function of y بعد ما اجيب هذه
+
+49
+00:05:05,540 --> 00:05:10,160
+الخطوة التانية بدي اعمل interchange تغيير بين ال x
+
+50
+00:05:10,160 --> 00:05:14,540
+و ال y يعني بدي اشيل كل x و احط مكانها y و اشيل كل
+
+51
+00:05:14,540 --> 00:05:20,270
+y و احط مكانها x اللي بطلع بكون هو معكوس الدلةطبعا
+
+52
+00:05:20,270 --> 00:05:27,310
+يبقى خطوتين لثالث لهم نطرح السؤال ثم نجيب عليه how
+
+53
+00:05:27,310 --> 00:05:43,130
+to find if inverse of x from the function y تساوي
+
+54
+00:05:43,130 --> 00:05:44,670
+if of x
+
+55
+00:05:48,370 --> 00:05:55,030
+كيف بدنا نجد معكوسة دالة F من المعادلة Y تساوي F
+
+56
+00:05:55,030 --> 00:05:59,910
+of X قولنا هذا الكلام سيتم على خطوتين الخطوة
+
+57
+00:05:59,910 --> 00:06:06,190
+الأولى بدنا نحل المعادلة هذه مشان نحصل على X as a
+
+58
+00:06:06,190 --> 00:06:12,430
+function of Y يبقى الخطوة الأولى Solve the
+
+59
+00:06:12,430 --> 00:06:26,320
+equation Y تساوي F of Xto get x as a function of y
+
+60
+00:06:26,320 --> 00:06:40,540
+as a function of y اتنين interchange interchange
+
+61
+00:06:40,540 --> 00:06:45,460
+ال x and ال y
+
+62
+00:06:51,820 --> 00:06:57,840
+والترتيب هو y
+
+63
+00:06:57,840 --> 00:07:01,620
+تساوي f inverse of x
+
+64
+00:07:14,950 --> 00:07:20,090
+يبقى السؤال اللي مطروح عندنا كيف بدنا نجد معكوسة
+
+65
+00:07:20,090 --> 00:07:26,050
+دالة y تساوي f of x الإجابة خطواتين لثالثة لهم
+
+66
+00:07:26,050 --> 00:07:31,790
+خطوة الأولى بدنا نحل المعادلة y تساوي f of x بحيث
+
+67
+00:07:31,790 --> 00:07:37,730
+تصبح على الصورة x دالة في y بحيث ال x تصبح هي
+
+68
+00:07:37,730 --> 00:07:41,760
+function في مين؟ في yالـ function اللى حصلنا عليها
+
+69
+00:07:41,760 --> 00:07:46,140
+دى بدأ أبدل خطوة تانية بدأ أبدل x و y مكان بعض
+
+70
+00:07:46,140 --> 00:07:49,580
+تبدأ أشيل كل x و أحط مكانها y و أشيل كل y و أحط
+
+71
+00:07:49,580 --> 00:07:54,620
+مكانها x المعادلة النتيجة بتكون هي معكوس f ده اللى
+
+72
+00:07:54,620 --> 00:07:59,430
+طيب ممتاز جداالمرة اللي فات لما أخدنا تعريف معكوس
+
+73
+00:07:59,430 --> 00:08:05,070
+الدالة قولنا لو كانت النقطة A وB موجودة على الرسم
+
+74
+00:08:05,070 --> 00:08:10,870
+البياني للدالة يعني F of A بدأ يسمى مين؟ B طيب
+
+75
+00:08:10,870 --> 00:08:17,220
+النقطة B وA موجودة على منحنى مين؟على منحنى المعكوس
+
+76
+00:08:17,220 --> 00:08:24,920
+يبقى الحالة الأولى اذا او بي موجودة على منحنى
+
+77
+00:08:24,920 --> 00:08:30,840
+الدالة F فان بي و اي موجودة على معكوس الدالة F
+
+78
+00:08:30,840 --> 00:08:31,180
+inverse
+
+79
+00:08:33,940 --> 00:08:40,540
+انتر اتشينج X ب Y و Y منين ب X يبقى تماما اذا كان
+
+80
+00:08:40,540 --> 00:08:45,440
+A و B على منحنى F فان النقطة B و A موجودة على
+
+81
+00:08:45,440 --> 00:08:50,620
+منحنى منين على منحنى ال F inverse وهذا ينطبق تماما
+
+82
+00:08:50,620 --> 00:08:56,000
+مع الخطوات اللي احنا قلنا عليهم هدول طيب لو حبينا
+
+83
+00:08:56,000 --> 00:09:02,420
+نرسم رسم بيانيلمن؟ للمعكوس تبع الدالة يعني عندي
+
+84
+00:09:02,420 --> 00:09:07,760
+رسمة الدالة و بدى اجيب الرسم البياني لمعكوس الدالة
+
+85
+00:09:07,760 --> 00:09:13,360
+احنا بنقول لو كان a و b على منحلة دالة f يبقى b و
+
+86
+00:09:13,360 --> 00:09:18,780
+a موجودة على ال F inverse هذا معناه ان احنا بنقلب
+
+87
+00:09:18,780 --> 00:09:27,100
+رسمة الدالة F عبر الخط Y تساوي Xمظبوط؟ إذا بتذكروا
+
+88
+00:09:27,100 --> 00:09:31,400
+لما درسنا ال shift في calculus a في section واحد
+
+89
+00:09:31,400 --> 00:09:36,080
+اتنين بجينا نقول لو شيلنا ال X و حطينا مكانها
+
+90
+00:09:36,080 --> 00:09:41,140
+السالم X بنقلب الرسم عبر محور one صحيح ولا لأ؟
+
+91
+00:09:41,140 --> 00:09:44,840
+وإذا ضربنا الدالة كلها في إشارة سالم بنقلب الرسم
+
+92
+00:09:44,840 --> 00:09:50,360
+عبر محور X ممتاز إذا نيبجي هنا لأ بنقلبها عبر الخط
+
+93
+00:09:50,360 --> 00:09:57,430
+Y تساويممتاز ان نكتب الملاحظة هذه ونرسمها كدالة
+
+94
+00:09:57,430 --> 00:10:03,830
+ومعكوسة لنرى كيف يحصل هذا الإنقلاب يبقى نكتب هذه
+
+95
+00:10:03,830 --> 00:10:12,450
+الملاحظة التالية Note the graphs of
+
+96
+00:10:12,450 --> 00:10:19,590
+ال F andالـ F inverse الرسم البياني للدالة F و F
+
+97
+00:10:19,590 --> 00:10:28,210
+inverse are symmetric about
+
+98
+00:10:28,210 --> 00:10:33,810
+the
+
+99
+00:10:33,810 --> 00:10:43,810
+line Y تساوي X كمان
+
+100
+00:10:43,810 --> 00:11:00,210
+من هنا نقول FA وB is a point on the graph of F
+
+101
+00:11:00,210 --> 00:11:14,530
+then the point B وA is a point on
+
+102
+00:11:16,100 --> 00:11:22,140
+هو مقعد على
+
+103
+00:11:22,140 --> 00:11:29,660
+مقعد ف انفراد
+
+104
+00:11:33,160 --> 00:11:39,920
+يعني فرض على سبيل المثال رسمنا رسمة الدالة F فكان
+
+105
+00:11:39,920 --> 00:11:44,780
+شكل الرسمة على الشكل اللي عندنا هذا يبقى كان هذا
+
+106
+00:11:44,780 --> 00:11:52,880
+المنحنى Y تساوي F of X قطع محور أو قطع الخط Y
+
+107
+00:11:52,880 --> 00:11:59,950
+تساوي X عند هذه النقطةالان بدنا نرسم مين؟ المعكوس
+
+108
+00:11:59,950 --> 00:12:05,690
+تبع هذه الدالة يبقى بدنا نقلب هذه الرسم عبر خط Y
+
+109
+00:12:05,690 --> 00:12:11,990
+تسوى مين؟ X يبقى الجزء من الرسم اللي كان أعلى اللي
+
+110
+00:12:11,990 --> 00:12:16,270
+هو الخط Y تسوى X بيصير مين؟ أسفله و اللي كان أسفله
+
+111
+00:12:16,270 --> 00:12:22,650
+بيصير مين؟ أعلى و هكذاطيب لو جيت افترضت ان هذه
+
+112
+00:12:22,650 --> 00:12:29,270
+النقطة مثلا كانت سالي ب اتنين و Zero لما نقلب ايش
+
+113
+00:12:29,270 --> 00:12:34,490
+بده يحصل؟ Zero سالي ب اتنين يبقى Zero على محور X و
+
+114
+00:12:34,490 --> 00:12:39,450
+سالي ب اتنين بده أنزل هنا هذه المسافة جد المسافة
+
+115
+00:12:39,450 --> 00:12:44,960
+هذه بالضبط تماماهذا concave down إذا هذي بده يصير
+
+116
+00:12:44,960 --> 00:12:49,760
+concave up هذا هنا concave up بده يصير concave
+
+117
+00:12:49,760 --> 00:12:58,620
+down وهكذا يبقى يجيك المنحنة هكذا بهذا الشكل تمام؟
+
+118
+00:12:58,620 --> 00:13:06,360
+يبقى هذه اللي هي رسمة Y تساوي F inverse of X بهذا
+
+119
+00:13:06,360 --> 00:13:13,020
+الشكليبقى هاي قلبنا الرسمة عبر main عبر الخط y
+
+120
+00:13:13,020 --> 00:13:18,080
+تساوي x نبدأ نشتغل الشغل الرياضي يعني الشغل العملي
+
+121
+00:13:18,080 --> 00:13:26,220
+فاخد المثال التالي example determine
+
+122
+00:13:26,220 --> 00:13:35,640
+whether or not determine whether or not
+
+123
+00:13:38,620 --> 00:13:49,240
+أو لا فالعملاء اللي يتبعون هم
+
+124
+00:13:49,240 --> 00:13:56,620
+واحد لواحد إذا
+
+125
+00:13:56,620 --> 00:14:01,380
+كان الأمر
+
+126
+00:14:01,380 --> 00:14:07,800
+كذلك فانتج انتج انتج انتج انتج انتج
+
+127
+00:14:11,990 --> 00:14:21,530
+النقطة الأولى F of X يساوي تلاتة X تربيع زائد
+
+128
+00:14:21,530 --> 00:14:22,290
+واحدة
+
+129
+00:14:25,570 --> 00:14:30,070
+بنجي نشوف هل هذه الدالة one to one ام لا هذا
+
+130
+00:14:30,070 --> 00:14:33,890
+المطلوب الاول اذا طلعت الدالة one to one يبقى
+
+131
+00:14:33,890 --> 00:14:40,910
+المعكوس موجود يبقى بدنا هذا المعكوس تمام تمام بنجي
+
+132
+00:14:40,910 --> 00:14:45,990
+نقول F of X سوى تلاتة X تربية زي واحد بدا اتأكد هل
+
+133
+00:14:45,990 --> 00:14:50,910
+هذه one to one ام لا عندنا اكثر من طريقة زي ما
+
+134
+00:14:50,910 --> 00:14:55,980
+اتعودنا بدل الطريقة ايه تلاتةلكن بمجرد النظر إذا
+
+135
+00:14:55,980 --> 00:15:01,360
+الدالة كلها أسس زوجية automatic طبعا ماعليهاش
+
+136
+00:15:01,360 --> 00:15:06,060
+condition مايكونش فيه شرط تاني هنا خالي هيك يبقى
+
+137
+00:15:06,060 --> 00:15:10,360
+automatic هذه ليست one to one لأن القيمة الموجبة
+
+138
+00:15:10,830 --> 00:15:14,890
+بدت يعطيني نفس القيمة السلبية، يعني لما أعوض ب X
+
+139
+00:15:14,890 --> 00:15:19,610
+بقيمة موجبة تماما كما لو أعوض ب X بقيمة سلبية تطلع
+
+140
+00:15:19,610 --> 00:15:25,230
+نفس النتيجة، يعني بيصير عنصرين مختلفين واحد موجوه،
+
+141
+00:15:25,230 --> 00:15:30,130
+لهما نفس الصورة إذا ليست one to one، أنو أضح هذا
+
+142
+00:15:30,130 --> 00:15:36,990
+الكلام، فباجي بقول لو كان أخد مثلا F و B اتنينيبقى
+
+143
+00:15:36,990 --> 00:15:41,310
+F of اتنين اللي هو تلاتة في اتنين تربيه ازايد واحد
+
+144
+00:15:41,310 --> 00:15:48,510
+اربع في تلاتة في اتناش وواحد تلاتاش and ال F of
+
+145
+00:15:48,510 --> 00:15:53,850
+سالي باتنين يساوي تلاتة في سالي باتنين الكل تربيه
+
+146
+00:15:53,850 --> 00:15:59,550
+ازايد واحد يساوي كذلك تلاتاش يبقى معناه هذا الكلام
+
+147
+00:15:59,550 --> 00:16:06,280
+ما له؟ال F is not
+
+148
+00:16:06,280 --> 00:16:13,580
+one to one because ال F of اتنين بده يساوي F of
+
+149
+00:16:13,580 --> 00:16:20,620
+سالب اتنين but ولكن اتنين لا تساوي سالب اتنين يبقى
+
+150
+00:16:20,620 --> 00:16:26,360
+في عندي معكوسفيش ليست one to one فبناخد النقطة
+
+151
+00:16:26,360 --> 00:16:35,140
+التانية يبقى هنا ال F inverse does not exist مش
+
+152
+00:16:35,140 --> 00:16:42,400
+موجود خدلي النقطة الثانية نمره اتنين بدي اخد ال F
+
+153
+00:16:42,400 --> 00:16:49,640
+of X بدي ساوي اللي هو اتنين ناقص X لكل K
+
+154
+00:16:55,640 --> 00:17:00,620
+الان بناعطيك طريقة اخرى عملية غير الطريقتين اللى
+
+155
+00:17:00,620 --> 00:17:03,540
+اتعودنا عليهم المرة الماضية وفي الأمثلة السابقة
+
+156
+00:17:03,540 --> 00:17:08,720
+بدي استخدم الاشتقاق في اثبات ان هذه one to one ام
+
+157
+00:17:08,720 --> 00:17:15,200
+لا اذا هنا لو جيت قلت بدي اخد ال F prime of X يبقى
+
+158
+00:17:15,200 --> 00:17:22,950
+مشتاقة كم؟ هي تلاتةفي اثنين ناقص X لكل ترابيع في
+
+159
+00:17:22,950 --> 00:17:27,310
+مشتقة ما داخل القصر اللي هو السالب واحد يبقى بصير
+
+160
+00:17:27,310 --> 00:17:32,550
+بالشكل اللي عندنا هذا السؤال هو هدى عمرها بتاخد
+
+161
+00:17:32,550 --> 00:17:38,450
+قيمة سالبة؟ لأ لأنها كمية مربعة سالب و الله موجبة
+
+162
+00:17:38,450 --> 00:17:42,780
+لما تربعها بصير موجبة مسبوقة بإشارة مين؟إذا
+
+163
+00:17:42,780 --> 00:17:48,540
+المقدار هذا دائما وأبدا أقل من Zero بيساوي Zero
+
+164
+00:17:48,540 --> 00:17:53,800
+فقط عند X يساوي اتنين صحيح ولا لا؟ إذا هذا الكلام
+
+165
+00:17:53,800 --> 00:18:01,520
+أقل من وقد يساوي Zero for all X طب ما تفسيرك لذلك؟
+
+166
+00:18:01,520 --> 00:18:08,080
+شو الدالة F تبقى؟ decreasing ممتاز يبقى هذا يعطينا
+
+167
+00:18:08,080 --> 00:18:14,750
+أن ال F is decreasingما دام ال f is decreasing
+
+168
+00:18:14,750 --> 00:18:21,530
+يبقى هذا يعطيك ان ال f is one to one ما دام ال f
+
+169
+00:18:21,530 --> 00:18:27,310
+one to one يبقى هذا معناه ان ال f inverse exists
+
+170
+00:18:31,390 --> 00:18:36,750
+يبقى أثبتنا إن المعكوس موجود، الآن بدنا نوجد هذا
+
+171
+00:18:36,750 --> 00:18:41,810
+المعكوس، كيف؟ قال لي if so يعني إذا كانت الدالة
+
+172
+00:18:41,810 --> 00:18:46,170
+one to one يبقى المعكوس موجود، if so إن كان الأمر
+
+173
+00:18:46,170 --> 00:18:52,530
+كذلكهات لي شكل المعكوس، وطبعا هذه أول مرة بناخد
+
+174
+00:18:52,530 --> 00:18:57,230
+فيها مثال على كيفية إيجاد المعكوس، بالأن بنطبق
+
+175
+00:18:57,230 --> 00:19:00,930
+الكلام اللي قلناه هناك الخطوتين اللي حكينا عنهم
+
+176
+00:19:00,930 --> 00:19:07,860
+هنا قبل قليليبقى بداجي كتالة باجي بقول احنا عندنا
+
+177
+00:19:07,860 --> 00:19:13,620
+هذا ال F of X يعني يا شباب ممكن اكتبها Y تساوي
+
+178
+00:19:13,620 --> 00:19:21,400
+اتنين ناقص X لكل تكعيب بدي احلها بأي طريقة رياضية،
+
+179
+00:19:21,400 --> 00:19:26,880
+جامع، طرح، ضرب، قسمة، أخد جذور، تكعيب، ما بعرف بأي
+
+180
+00:19:26,880 --> 00:19:31,360
+وسيلة رياضية تقدر عليها بحيث أخل ال X في الشجرة
+
+181
+00:19:31,360 --> 00:19:36,220
+والباقي كله اين؟فى شجة تانى يبقى بقوله بسيطة جدا
+
+182
+00:19:36,220 --> 00:19:41,440
+خد الجذر التالت للطرفين مظبوط يبقى لو أخدنا الجذر
+
+183
+00:19:41,440 --> 00:19:47,220
+التالت للطرفين بصير الجذر التالت ل Y يساوي اتنين
+
+184
+00:19:47,220 --> 00:19:53,620
+ناقص ال X أنا بده X فى شجة يبقى باجى بقول هنا بصير
+
+185
+00:19:53,620 --> 00:20:00,540
+عندنا ال X يساوي اتنين ناقص الجذر التالت ل Y
+
+186
+00:20:01,940 --> 00:20:08,760
+انتهينا من الخطوة الأولى جيبنا X as a function of
+
+187
+00:20:08,760 --> 00:20:12,840
+Y اللي هي الخطوة الأولى حلينا المعادلة هذه بحيث
+
+188
+00:20:12,840 --> 00:20:17,340
+خلينا X ذلة في main في Y انتهينا من الخطوة الأولى
+
+189
+00:20:17,340 --> 00:20:22,940
+هذه الخطوة الأولى بدأجي للخطوة التانية الخطوة
+
+190
+00:20:22,940 --> 00:20:26,460
+التانية ايش بدي اعمله او بلاشي مشان الأرقام ما
+
+191
+00:20:26,460 --> 00:20:33,240
+تكونش زي بعضها حطلي هذه I و هذه double Iخطوة تانية
+
+192
+00:20:33,240 --> 00:20:37,680
+بدي اعمل interchange ما بين ال X و ما بين ال Y
+
+193
+00:20:37,680 --> 00:20:44,700
+يبقى هنا بجي بقولك interchange ال
+
+194
+00:20:44,700 --> 00:20:52,060
+X and ال Y we get نحصل على ما يأتي ال Y تساوي
+
+195
+00:20:52,060 --> 00:20:59,660
+اتنين ناقص الجذر التالت ال X مين هي هذه؟هذا هو الـ
+
+196
+00:20:59,660 --> 00:21:07,800
+F inverse of X اللي نبحث عليه طب كويسي بجان تهيرا
+
+197
+00:21:07,800 --> 00:21:14,840
+نحل السؤال هذا السؤال يعتبر تطبيق مباشر على الجزء
+
+198
+00:21:14,840 --> 00:21:21,140
+النظري اللي حكينا فيه وهو كيفية إيجاد معكوث الدلة
+
+199
+00:21:21,770 --> 00:21:26,710
+الان مش كل المثال بتيجي بهالبساطة وبهالسهولة هيك
+
+200
+00:21:26,710 --> 00:21:32,630
+يعني بعض المثال فيها ايه فكري شوية خد كمان مثال
+
+201
+00:21:32,630 --> 00:21:37,610
+ونشوف كيف بدنا نعمل فيه كمان مثال يبقى example 3
+
+202
+00:21:39,020 --> 00:21:45,880
+أول نقطة تالتة بيقول ال F of X يساوي ال X تربيع
+
+203
+00:21:45,880 --> 00:21:52,220
+ناقص اتنين X وحطلي condition ان ال X اقل من او
+
+204
+00:21:52,220 --> 00:22:00,000
+يساوي ال واحد قبل ما نبدأ الحل لو جينا سألنا وقلنا
+
+205
+00:22:00,000 --> 00:22:05,200
+لو محطليش ال condition هذا جالي واحد يساوي X تربيع
+
+206
+00:22:05,200 --> 00:22:14,190
+ناقص اتنين هذه معادلة ايش؟معادلة ايش هذه؟ why
+
+207
+00:22:14,190 --> 00:22:22,310
+ماهياش مربع، لكن ال X تاربيع، يبقى معادلتاش؟معادلة
+
+208
+00:22:22,310 --> 00:22:27,030
+فرابولة بس معمولة لها shift مظبوط؟ يبقى هذه معادلة
+
+209
+00:22:27,030 --> 00:22:31,110
+فرابولة بس معمولة لها shift فرابولة يعني لو جيت
+
+210
+00:22:31,110 --> 00:22:35,090
+رسمت horizontal line هقطعها وين؟ في نقطتين بتبطل
+
+211
+00:22:35,090 --> 00:22:39,370
+تصبح one to one لكن لما أحطلي condition زي هذا x
+
+212
+00:22:39,370 --> 00:22:44,770
+أقل من أو يسوى واحد إذا إحنا أخدنا interval من كل
+
+213
+00:22:44,770 --> 00:22:49,600
+real lineعلى هذا ال interval بأقمن ان اي
+
+214
+00:22:49,600 --> 00:22:54,240
+horizontal line لا يمكن ان يقطع المنحنة الا في
+
+215
+00:22:54,240 --> 00:22:59,520
+نقطة واحدة وبالتالي المعكوس بيكون معله بيكون موجود
+
+216
+00:22:59,520 --> 00:23:05,560
+طيب الان بدي أبين ان المعكوس موجود انه جالي ال
+
+217
+00:23:05,560 --> 00:23:09,140
+show أبينلي ان هذه الدالة one to one قبل ما تبدأ
+
+218
+00:23:09,140 --> 00:23:11,560
+مش تروح اجيبلي معكوس او انت مش عارف ان هي one to
+
+219
+00:23:11,560 --> 00:23:17,790
+one ام لاإذاً بدأتي للخطوة الأولى فبدي بقوله ال F
+
+220
+00:23:17,790 --> 00:23:25,710
+prime of X يساوي اتنين X ناقص اتنينالـ domain تبقى
+
+221
+00:23:25,710 --> 00:23:31,350
+عدالة من عند الواحد و بتاخد ال verse للخلف لو حطيت
+
+222
+00:23:31,350 --> 00:23:36,070
+x بواحد بيكون النتج كده؟ zero طب ارجع جابل الواحد
+
+223
+00:23:36,070 --> 00:23:40,730
+لو حطيت x ب zero سالب اتنين لو حطيت x بسالب واحد
+
+224
+00:23:40,730 --> 00:23:46,450
+سالب اتنين سالب تلاتة يبقى كله بتاخد قيم سالبة ما
+
+225
+00:23:46,450 --> 00:23:52,010
+عدا عند الواحديعني معناه هذا الكلام ان هذا اقل من
+
+226
+00:23:52,010 --> 00:23:58,910
+او يساوي zero for all x اللي اكبر من او تساوي واحد
+
+227
+00:23:58,910 --> 00:24:05,570
+for all x اللي اقل من او يساوي واحد كلام صحيح
+
+228
+00:24:05,570 --> 00:24:10,250
+علموكوا في الثانوية انه لما انت اشتق بتسيب اول ال
+
+229
+00:24:10,250 --> 00:24:14,730
+interval و اخر ال interval مش هيك؟صح؟ لما تشقوا
+
+230
+00:24:14,730 --> 00:24:19,310
+بدك تجيب اللي هو الدلال عليك يبقى احنا لو شيلنا
+
+231
+00:24:19,310 --> 00:24:23,350
+اللي يساوي هذا وشيلنا اللي يساوي هذا بتضلها اقل من
+
+232
+00:24:23,350 --> 00:24:26,670
+ال zero على طول الخطوة بالثالث بيصير ايش؟
+
+233
+00:24:26,670 --> 00:24:32,510
+decreasing لو اضفت نقطة للفترة بتضلها decreasing
+
+234
+00:24:32,510 --> 00:24:37,890
+بتفرجش عندنا صحيح ولا لا؟ يبقى هذا بده يعطيلك ان
+
+235
+00:24:37,890 --> 00:24:40,730
+ال F is decreasing
+
+236
+00:24:43,140 --> 00:24:50,160
+ال F is decreasing يعني معناته ان ال F is one to
+
+237
+00:24:50,160 --> 00:24:54,400
+one اللي هو المطلوب الأول من المثلة مدام one to
+
+238
+00:24:54,400 --> 00:25:00,660
+one يبقى ال F inverse exists موجود هذا بدنا نبحث
+
+239
+00:25:00,660 --> 00:25:05,720
+عن هذا اللي هو ال F inverse يبقى هذا النقطة اللي
+
+240
+00:25:05,720 --> 00:25:11,590
+هو النقطة التانيةبدي اقول له put y تساوي x ثربيه
+
+241
+00:25:11,590 --> 00:25:18,930
+ماقص اتنين x المعادلة هذه بدي احلها بها تجيب x كده
+
+242
+00:25:18,930 --> 00:25:23,990
+اللي في main في y و ال condition عليها لا يزال
+
+243
+00:25:23,990 --> 00:25:30,370
+اللي هو ال x ماله اقل من او يساوي الواحد طيب بنحل
+
+244
+00:25:30,370 --> 00:25:37,050
+هذه حد بيعرف يقولي كيف نحل هذه ايوةنكمل المربع
+
+245
+00:25:37,050 --> 00:25:41,550
+ممتاز جدا يبقى لو أكملنا المربع بصير وسيلة عملية
+
+246
+00:25:41,550 --> 00:25:48,490
+سهلة للحصول على ال X as a function of Y بنقوله
+
+247
+00:25:48,490 --> 00:25:55,190
+بسيطة يبقى Y يساوي X تربية ناقص اتنين X نرجع تاني
+
+248
+00:25:55,190 --> 00:25:58,970
+لإكمال المربع علمناكوا يا في كل كلاصية بنشوف ضايل
+
+249
+00:25:58,970 --> 00:26:05,720
+في دماغك ولا غاباتممتاز جدا يبقى المعادلة عندى
+
+250
+00:26:05,720 --> 00:26:13,160
+مشان اعملها اكمل المربع بضيف و بطرح مربع معامل x
+
+251
+00:26:13,160 --> 00:26:17,880
+على اربع امثال معامل x تربيع اللى ناس يكتب عنده
+
+252
+00:26:17,880 --> 00:26:22,240
+سجل عندك اللى عارف عارف و خلاص يبقى بنضيف للمعادلة
+
+253
+00:26:22,240 --> 00:26:28,680
+و بنطرح مربع معامل x على اربع امثال معامل x تربيع
+
+254
+00:26:29,170 --> 00:26:36,510
+نشوف هذا على أرض الواقع مربع معامل x أربعة ومعامل
+
+255
+00:26:36,510 --> 00:26:41,510
+x سربيع واحد أربعة أمثاله أربعة أربعة على أربعة
+
+256
+00:26:41,510 --> 00:26:46,830
+يبقى بنضيف واحد ونطرح واحد يبقى باجي بقول هنا زائد
+
+257
+00:26:46,830 --> 00:26:52,450
+واحد ناقص واحد هل تغير وضع المعادلة بهذه الإضافة
+
+258
+00:26:52,450 --> 00:26:55,910
+وهذه الطريقة لأ يعني كان ضايف صفر يبقى احنا
+
+259
+00:26:55,910 --> 00:27:00,530
+ماعملناش جديد ولا حاجةلكن هذا إله فائدة كبرى، ما
+
+260
+00:27:00,530 --> 00:27:04,230
+هي الفائدة الكبرى؟ لو نجلت الواحد على الشجة
+
+261
+00:27:04,230 --> 00:27:10,050
+التانية بصير Y زائد واحد يسوى X ناقص واحد لكل
+
+262
+00:27:10,050 --> 00:27:15,900
+تاربيع، أيوة، هيك صارت القصة سهلةإذا بدنا نروح
+
+263
+00:27:15,900 --> 00:27:23,240
+ناخد الجذر التربيعي للطرفين، ممتاز جدا، ها لا يزال
+
+264
+00:27:23,240 --> 00:27:27,720
+عند ال X أقل من أو يساوي الواحد، ناخد الجذر
+
+265
+00:27:27,720 --> 00:27:32,340
+التربيعي للطرفين، يبقى بيصير عند الجذر التربيعي ل
+
+266
+00:27:32,340 --> 00:27:37,220
+Y زائد واحد يساوي، قداش الجذر التربيعي لهذا
+
+267
+00:27:37,220 --> 00:27:43,050
+المقدار؟ حد بيعرف؟بدي واحد يحكي مشان نتناقش مع
+
+268
+00:27:43,050 --> 00:27:46,550
+هالكلام هو صح ولا غلط، اه مين يا مين اعرف القداش
+
+269
+00:27:46,550 --> 00:27:48,090
+الجدر التربية لهذا المقدار
+
+270
+00:27:51,790 --> 00:27:55,830
+بنقول موجب وسالب اكس ناقص واحد وموجب وسالب اكس
+
+271
+00:27:55,830 --> 00:27:59,230
+ناقص واحد وموجب وسالب اكس ناقص واحد وموجب وسالب
+
+272
+00:27:59,230 --> 00:28:00,610
+اكس ناقص واحد وموجب وسالب اكس ناقص واحد وموجب
+
+273
+00:28:00,610 --> 00:28:04,150
+وسالب اكس ناقص واحد وموجب وسالب اكس ناقص واحد
+
+274
+00:28:04,150 --> 00:28:07,550
+وموجب وسالب اكس ناقص واحد وموجب وسالب اكس ناقص
+
+275
+00:28:07,550 --> 00:28:09,270
+واحد وموجب وسالب اكس ناقص واحد وموجب وسالب اكس
+
+276
+00:28:09,270 --> 00:28:15,970
+ناقص واحد وموجب وسالب اكس ناقص واحد وموجب وسالب
+
+277
+00:28:15,970 --> 00:28:22,380
+اكس ناقص واحد ووعندك هنا ما له؟ ال X أقل من أو
+
+278
+00:28:22,380 --> 00:28:28,140
+تساوي واحد، بالداجة عند الواحد وأقل منه، اللي بين
+
+279
+00:28:28,140 --> 00:28:31,220
+الشرط ال absolute value، قيمة موجة بوالله سالبة
+
+280
+00:28:31,830 --> 00:28:36,150
+سالبة مادام سالبة اذا بقدر اتخلص من ال absolute
+
+281
+00:28:36,150 --> 00:28:41,510
+value و احط قوس و قبله اشارة سالب يبقى هذا بدي
+
+282
+00:28:41,510 --> 00:28:46,950
+اعطيلك ان الجذر التربيعي ل Y زائد واحد يسوي سالب
+
+283
+00:28:46,950 --> 00:28:53,810
+ال X ناقص الواحد او ان شئتم فقولوا ان سالب الجذر
+
+284
+00:28:53,810 --> 00:28:59,630
+التربيعي ل Y زائد واحد يسوي X ناقص الواحد
+
+285
+00:29:15,700 --> 00:29:22,320
+هذا الشغل اللى اشتغلنا من هنا لغاية هنا كله لسه
+
+286
+00:29:22,320 --> 00:29:29,620
+الخطوة الاولىإن حاولت أحل المعادلة اللى عندي فوق و
+
+287
+00:29:29,620 --> 00:29:34,660
+أعمل X as a function of Y إذا هذا بختلف عن المثال
+
+288
+00:29:34,660 --> 00:29:37,300
+اللى جابله مثل اللى جابله automatic سهل ومشي معانا
+
+289
+00:29:37,300 --> 00:29:42,380
+دغري هذا أحتاج إلى شوية شغل رياضي يبقى أنت بدك
+
+290
+00:29:42,380 --> 00:29:47,640
+تحول المعادلة X بذلالة Y بأى طريقة رياضية تعلمتها
+
+291
+00:29:47,640 --> 00:29:53,490
+قبل هيك بأى وسيلة إن كانت بس تبقى الوسيلة صحيحةمش
+
+292
+00:29:53,490 --> 00:29:57,990
+تبقى تخبيص كويس يبقى ال X صارت بالشكل اللي عندنا
+
+293
+00:29:57,990 --> 00:30:05,430
+هذا الآن بنجي للخطوة الثانية وهي اني ابدل كل X بي
+
+294
+00:30:05,430 --> 00:30:12,840
+Y وكل Y ب X ولا تزال عندنا X أقل من أو تساوي 1اذا
+
+295
+00:30:12,840 --> 00:30:17,880
+بدي اعمل interchange يبقاش بصير عند هنا بصير عند Y
+
+296
+00:30:17,880 --> 00:30:25,200
+تساوي واحد نقص الجدرى التربيه ل X زائد واحد وهنا
+
+297
+00:30:25,200 --> 00:30:31,770
+اقول X اقل من او تساوي واحد غلطلما اتغيرتش واسبت
+
+298
+00:30:31,770 --> 00:30:36,530
+تاني؟ ماينفعش، كل X بدك تغيرها بY، انا عندي هنا X
+
+299
+00:30:36,530 --> 00:30:41,990
+اقل من ساوي واحد، يبقى بالدأجي اقوله و ال Y اقل من
+
+300
+00:30:41,990 --> 00:30:48,110
+او تساوي من اقل من او تساوي الواحدطيب استنى شوية
+
+301
+00:30:48,110 --> 00:30:52,670
+احنا دايما من اول حياتنا لما نقول ال Y ده اللي في
+
+302
+00:30:52,670 --> 00:30:56,850
+X بنقول ال X بتتغير من كذا لكذا لإن هي المتغير
+
+303
+00:30:56,850 --> 00:31:01,750
+اللي هو المستقل وال Y هي المتغير التابع مظبوط ولا
+
+304
+00:31:01,750 --> 00:31:06,630
+لا؟ يبقى باجي بقول اه انا بديش Y اقل من أو يسوى
+
+305
+00:31:06,630 --> 00:31:11,290
+واحد بدي X تكونمش عارف على ان هي فترة جد ما تطلع
+
+306
+00:31:11,290 --> 00:31:16,570
+تطلع، بقول بسيطة جدا، ما انت عندك أي Y بدلالة X،
+
+307
+00:31:16,570 --> 00:31:21,230
+يبقى بدي أشيل Y هذه و أحط قيمتها و أنحل ال
+
+308
+00:31:21,230 --> 00:31:24,570
+Equality اللي عندي وبالتالي بحدد X حتى تتغير من
+
+309
+00:31:24,570 --> 00:31:32,020
+ويلة و ويلةمظبوط طيب هذه لحالها بقدر اكتبها ايش
+
+310
+00:31:32,020 --> 00:31:36,940
+اللي هو الواحد ناقص الجدري التربية ل X زائد واحد
+
+311
+00:31:36,940 --> 00:31:44,150
+اقل من او يساوي الواحدأنا شيلت ال Y و حطيت قيمتها
+
+312
+00:31:44,150 --> 00:31:46,830
+اللي هو كل القيمة اللي عندنا عليها و بدها حل ال
+
+313
+00:31:46,830 --> 00:31:52,050
+inequality يعني يبقى لو جيبنا هذه هنا وهذه هنا
+
+314
+00:31:52,050 --> 00:32:00,030
+بصير المعادلة الجذر التربيعي ل X زائد واحد أكبر من
+
+315
+00:32:00,030 --> 00:32:05,360
+أو تساوي ال zero صحيح؟طيب احنا بدنا x بالربع
+
+316
+00:32:05,360 --> 00:32:10,780
+الطرفين اذا لو ربعنا الطرفين بصير ان مين ال x زائد
+
+317
+00:32:10,780 --> 00:32:16,600
+واحد اكبر من او تساوي zero او ال x اكبر من او
+
+318
+00:32:16,600 --> 00:32:24,540
+تساوي من سالب واحد بناء عليه صار ال F inverse of x
+
+319
+00:32:24,540 --> 00:32:30,760
+يسوى واحد ناقص ل square root لل x زائد واحد والx
+
+320
+00:32:30,760 --> 00:32:37,260
+greater than or equalتسالب one يعني لو جاك سؤال
+
+321
+00:32:37,260 --> 00:32:41,480
+هيك والله قابلت في التمرين سؤال بهذا الشكل مش
+
+322
+00:32:41,480 --> 00:32:45,480
+تشتغل ع الدالة و تسيب ال domain زي ما اشتغلت ع
+
+323
+00:32:45,480 --> 00:32:47,740
+الدالة بقى تشتغل على ال domain تبعها طبعا ال
+
+324
+00:32:47,740 --> 00:32:51,220
+domain تبعها كان من و لا واين من سالب infinity
+
+325
+00:32:51,220 --> 00:32:56,600
+لغاية الواحدولع ال domain تبع ال F inverse من عند
+
+326
+00:32:56,600 --> 00:33:01,800
+السلب واحد الى infinity اكبر من او يسوى من سلب
+
+327
+00:33:01,800 --> 00:33:08,880
+واحد وهذا نتيجة لقلب المنحنى عبر الخط Y تساوي X
+
+328
+00:33:08,880 --> 00:33:16,360
+طيب مختلفناش مختلفناش بنفع
+
+329
+00:33:16,360 --> 00:33:16,960
+ايش؟
+
+330
+00:33:21,210 --> 00:33:27,190
+هذا إذا بتقدر، وإذا ماقدرتش، بصير صعب، زميلكو بطرح
+
+331
+00:33:27,190 --> 00:33:32,650
+سؤال وجيه، بقول كويس، أنا عندي الدالة هذه، وعندي
+
+332
+00:33:32,650 --> 00:33:38,110
+هذه ال domain تبعها، إذا قدرت أحدد ال range تبع
+
+333
+00:33:38,110 --> 00:33:41,250
+الدالة F يبقى هو ال domain، إلا ال F inverse
+
+334
+00:33:41,250 --> 00:33:44,630
+مايقوله والله على الروح بيوسعها، كلامك مظبوط وفوق
+
+335
+00:33:44,630 --> 00:33:48,290
+رأسنا، وبالتالي بترتاح من مين؟من الشغلة اللى
+
+336
+00:33:48,290 --> 00:33:52,110
+اشتغلناها هذى، اذا قلت حدد ال domain تبع الدالة F
+
+337
+00:33:52,110 --> 00:33:58,450
+بيكون هو ال domain تبع مين؟ بيقولوله كلامك صحيح،
+
+338
+00:33:58,450 --> 00:34:06,310
+ميا او شو اسمك انت؟أبراهيم يبقى ابراهيم جابنا وجهة
+
+339
+00:34:06,310 --> 00:34:10,690
+نظر أخرى غير وجهة النظر اللي احنا قلنالكوا وكيلة
+
+340
+00:34:10,690 --> 00:34:14,490
+الوجهتين اللي هو الصحية وجهة النظر تبعتنا وجهة
+
+341
+00:34:14,490 --> 00:34:17,750
+النظر اللي قالها وإذا فينا وجهة نظر أخرى برضه
+
+342
+00:34:17,750 --> 00:34:27,150
+مستعدين نسمعها إذا فيها آية اتفضل ماشي
+
+343
+00:34:40,010 --> 00:34:45,590
+تاني تاني احكي تاني اه
+
+344
+00:34:45,590 --> 00:34:52,590
+بطلع صفر ولا لأ ولا بطلع سالب واحد مية المية تمام
+
+345
+00:34:54,080 --> 00:34:58,940
+يبقى ايش صارت؟ صارت دمعة، بس خليك معايا صارت كده؟
+
+346
+00:34:58,940 --> 00:35:03,020
+حبيت انت يكسب واحد، يبقى صارت النقوة واحد و سالب
+
+347
+00:35:03,020 --> 00:35:08,880
+واحد، تمام؟ ما بيقلبها، ماشي، هتشوف صح هنا ولا لا؟
+
+348
+00:35:10,390 --> 00:35:17,930
+مظبوط؟ خلاص اتفجنا احنا وياك مافي مشكلة حتى
+
+349
+00:35:17,930 --> 00:35:22,610
+لان يا شباب احنا جيبنا كيفية ايجاد معكوس الدالة
+
+350
+00:35:22,610 --> 00:35:26,790
+لكن العنوان اللي مكتوب عندك في بداية ال section ال
+
+351
+00:35:26,790 --> 00:35:32,370
+inverse functions and their derivatives يبقى بدنا
+
+352
+00:35:32,370 --> 00:35:39,570
+نروح نبحث عاميا عن مشتقة معكوس الدالةيبقى الآن
+
+353
+00:35:39,570 --> 00:35:44,650
+بدنا نتكلم عن ال derivative لمين لمعكوس الدالة
+
+354
+00:35:44,650 --> 00:35:49,810
+اللى عندنا هذه خلينا
+
+355
+00:35:49,810 --> 00:35:55,370
+نطرح السؤال التالي و نشوف كيفية الإجابة عليه الآن
+
+356
+00:35:55,370 --> 00:36:01,250
+عشان أجيب مشتقة معكوس الدالة ضروري أجيب المعكوس ثم
+
+357
+00:36:01,250 --> 00:36:02,410
+أروح أشتقه؟
+
+358
+00:36:04,940 --> 00:36:13,520
+ليس بالضرورة لكن هنجيب ايه مشتقة الدالة هتجيب
+
+359
+00:36:13,520 --> 00:36:19,300
+المعكوس مش بدنا فيه بصير احنا بدنا مشتقة معكوس
+
+360
+00:36:19,300 --> 00:36:27,340
+الدالة طبعا طيب هجربكوا الفكرة انا عندي دالة و
+
+361
+00:36:27,340 --> 00:36:31,940
+اثبت ان المعكوس تبعها exist هل بقدر اوجد شكل
+
+362
+00:36:31,940 --> 00:36:39,780
+المعكوسممكن نعم بنقدر و ممكن لا اعطيك مثال بسيط لو
+
+363
+00:36:39,780 --> 00:36:45,380
+جاتي اقول خدلي f of x يساوي دقيق معايا كويس x أص
+
+364
+00:36:45,380 --> 00:36:55,720
+11 زائد 2 x أص 7 زائد 3 x أص 5 زائد 4 x تكيب زائد
+
+365
+00:36:55,720 --> 00:37:02,050
+x ناقص 1كل الأسس فردية، بده أشوف ال universe exist
+
+366
+00:37:02,050 --> 00:37:07,010
+ولا لا، بروح أشتقها، بصير الأولى أس عشرة، والتانية
+
+367
+00:37:07,010 --> 00:37:12,810
+أس ستة، واللي بعدها أس أربعة، واللي بعدها أس
+
+368
+00:37:12,810 --> 00:37:18,220
+اتنين، واللي بعدها كونستانكله أكبر من ال zero صح
+
+369
+00:37:18,220 --> 00:37:22,100
+ولا لا؟ لإن الأسس كلها زوجية يبقى هذا المئة كلها
+
+370
+00:37:22,100 --> 00:37:24,260
+أكبر من ال zero يبقى ده اللي increasing يبقى ال
+
+371
+00:37:24,260 --> 00:37:29,540
+inverse exist حد فيكوا بيقدر يحل المعادلة هذه واني
+
+372
+00:37:29,540 --> 00:37:33,160
+زيكوا بقدرش مش انت بتقول لأ لأ واني زيكوا بقدرش
+
+373
+00:37:33,160 --> 00:37:38,110
+أحل المعادلة هذه هذه المعادلة في غاية التعقيدخارج
+
+374
+00:37:38,110 --> 00:37:41,530
+نطاق شغل ما نقدرش عليها يبقى احنا اثبتنا ان
+
+375
+00:37:41,530 --> 00:37:47,130
+المعكوس موجود لكن مش قادرين نوجد هذا المعكوس وهذا
+
+376
+00:37:47,130 --> 00:37:52,490
+من القصور في العقل البشري يعني العقل البشري قاصر
+
+377
+00:37:52,490 --> 00:37:56,420
+عن إدراك مكنونات الأشياء اللي بيحس فيهافي هذا
+
+378
+00:37:56,420 --> 00:38:00,520
+الكون او في هذه الحياة وهذا من قدرة الله تبارك
+
+379
+00:38:00,520 --> 00:38:05,260
+وتعالى زي ايش مثلا زي امبارح كان فيها شوية ريح صح
+
+380
+00:38:05,260 --> 00:38:07,760
+ولا لا؟ كان ريح جو امبارح مش اليوم ساكت الريح
+
+381
+00:38:07,760 --> 00:38:12,520
+امبارح كان ريح جوي بقينا نقدر نشوف ضغط الريح اللي
+
+382
+00:38:12,520 --> 00:38:17,180
+حاليا نحس فيه ونقيس اتجاه الريح وسرعة الريح صح ولا
+
+383
+00:38:17,180 --> 00:38:21,580
+لا؟ لكن حد فينا عمره شاف الريح؟لا، ولا واحد
+
+384
+00:38:21,580 --> 00:38:25,920
+بيشوفه، بنشوف أثره على الأشجار، نلاقي الأشجار
+
+385
+00:38:25,920 --> 00:38:30,340
+بتتميل، بنشوف هذا تأثيره عليه، لكن هل في واحد عمرك
+
+386
+00:38:30,340 --> 00:38:35,520
+وشاف شكل الهواء ولا طعم الهواء ولا كده؟ أبدا،
+
+387
+00:38:35,520 --> 00:38:40,360
+العقل البشري في عنده قصور، لو بريك الكهربا هذه، لو
+
+388
+00:38:40,360 --> 00:38:43,880
+جيبنا سلخ الكهربا، مشان تعرف هي كهربا، لازم تحط
+
+389
+00:38:43,880 --> 00:38:48,910
+أصبعك عليها أو تجيب تستر وتشوفه بضج ولا لايجي هذا
+
+390
+00:38:48,910 --> 00:38:52,950
+تأثير الكهربا على اللمضة تبع تستر نوط على أصبعك
+
+391
+00:38:52,950 --> 00:38:58,990
+بتلطعك ولا لا؟ اه وربما تروح فيها الله أعلم اه و
+
+392
+00:38:58,990 --> 00:39:03,450
+بنجرى الفاتحة بعد هيك كويس يبقى في مثل هذه الحالة
+
+393
+00:39:03,450 --> 00:39:08,230
+لحتى لو جشرنا او شيلنا للغطاء البلاستيكي اللي على
+
+394
+00:39:08,230 --> 00:39:12,030
+السلك بنقدر نعرف انه فيه كهربا من دون تستر ولا من
+
+395
+00:39:12,030 --> 00:39:15,890
+دون ما نلمسها بأصبعنا؟ نقدرشإذا العقل البشري
+
+396
+00:39:15,890 --> 00:39:22,190
+والنظر البشري والحس البشري عاصر عن إدراك المكنونات
+
+397
+00:39:22,190 --> 00:39:26,950
+الأشياء الموجودة في هذا الكون وهذا من إعجاز الله
+
+398
+00:39:26,950 --> 00:39:31,830
+للبشر حتى نؤمن بالله سبحانه وتعالى الذي لا نرعى،
+
+399
+00:39:31,830 --> 00:39:35,930
+تمام؟ إذا نرجع لموضوعنا، بدناش نتشعر كتير، بلاش
+
+400
+00:39:35,930 --> 00:39:38,930
+تقولوا لهذا محاضرة في أصول الدين، في العقيدة يعني،
+
+401
+00:39:38,930 --> 00:39:44,170
+مش هناكبنقولكوا ماشي، لكن هذه لها ارتباط بموضوعنا،
+
+402
+00:39:44,170 --> 00:39:48,830
+إذا إيش رأيكوا؟ أنا ماقدرش أجيب المعكوس تبع
+
+403
+00:39:48,830 --> 00:39:53,130
+الدلالة، لكن بقدر أجيب مستقبتها كيف؟ كالتالي، طبقا
+
+404
+00:39:53,130 --> 00:40:06,870
+للنظرية التالية اكتب معايا theorem if
+
+405
+00:40:06,870 --> 00:40:09,250
+domain
+
+406
+00:40:10,340 --> 00:40:19,980
+الدالة F is the interval I
+
+407
+00:40:19,980 --> 00:40:24,280
+exists
+
+408
+00:40:24,280 --> 00:40:34,000
+and ال F prime of X does not equal to zero على
+
+409
+00:40:34,000 --> 00:40:43,560
+الفترة I on the interval I thenالـ F inverse is
+
+410
+00:40:43,560 --> 00:40:54,200
+differentiable at every point at every point عند
+
+411
+00:40:54,200 --> 00:41:02,560
+كل نقطة in its domain عند كل نقطة في ال domain
+
+412
+00:41:02,560 --> 00:41:08,100
+تبعها the value of
+
+413
+00:41:10,260 --> 00:41:16,400
+الـ F inverse prime at
+
+414
+00:41:16,400 --> 00:41:30,840
+a point at a point B اللي هي بدها تساوي F of A in
+
+415
+00:41:30,840 --> 00:41:37,980
+the domain of F inverse
+
+416
+00:42:03,550 --> 00:42:18,650
+اللي بده يساوي F inverse of Bأي ان D F انفرستعلى
+
+417
+00:42:18,650 --> 00:42:29,130
+DX عندما ال X تساوي ال B لل F of A بده يساوي واحد
+
+418
+00:42:29,130 --> 00:42:39,830
+على DF على DX لما ال X بده يساوي A ل F inverse of
+
+419
+00:42:39,830 --> 00:42:43,670
+B نرجع
+
+420
+00:42:43,670 --> 00:42:49,530
+لكلام اللي احنا كتبينه هذا نقرأكل كلامنا ككاتب ينه
+
+421
+00:42:49,530 --> 00:42:55,290
+نشرحه بتفصيل مشان نفهم كل نقطة في نص النظرية بقول
+
+422
+00:42:55,290 --> 00:43:00,610
+لو كان dominant دالة F هو الفترة اللي عندنا Iوكان
+
+423
+00:43:00,610 --> 00:43:05,250
+مشتقة الدالة exist يبقى الدالة قابلة للاشتقاء
+
+424
+00:43:05,250 --> 00:43:10,070
+اتنين المشتقة لا يمكن ان تساوي zero does not equal
+
+425
+00:43:10,070 --> 00:43:15,030
+to zero ليش هذا ما سنعرفه بعد قليل يعني ليش حطل ال
+
+426
+00:43:15,030 --> 00:43:20,150
+condition ان ال f prime of x لا تساوي zeroبقول هذا
+
+427
+00:43:20,150 --> 00:43:25,530
+الكلام على الفترة I يبقى في هذه الحالة بكون معكوسة
+
+428
+00:43:25,530 --> 00:43:30,650
+دالة هي دالة قابلة لمين للاشتراك الف انفرس is
+
+429
+00:43:30,650 --> 00:43:36,330
+differentiable عن كل نقطة في دومينهاالان قيمة
+
+430
+00:43:36,330 --> 00:43:39,570
+مشتقة معكوثة ده اللى احنا بنقول ال F
+
+431
+00:43:39,570 --> 00:43:43,710
+differentiable يعني قابلة للاشتقاء إذا مشتقة
+
+432
+00:43:43,710 --> 00:43:49,590
+معكوثة ده اللى عندنا نقطة B اللى أصلها هو A في
+
+433
+00:43:49,590 --> 00:43:54,850
+domain of the left عند B يعني B في domainالـ F
+
+434
+00:43:54,850 --> 00:43:59,290
+inverse والـ A في دومين الـ F يبقى عند النقطة B
+
+435
+00:43:59,290 --> 00:44:03,230
+لتساوي F of A in the domain of F inverse is the
+
+436
+00:44:03,230 --> 00:44:07,930
+reciprocal يعني شبه مقلوب مقلوب يعني كان في ال bus
+
+437
+00:44:07,930 --> 00:44:13,250
+بنزله في المقام يعني A بصير واحد على A عشرة بصير
+
+438
+00:44:13,250 --> 00:44:17,090
+واحد على عشرة هي مقلوبة is the reciprocal مقلوب
+
+439
+00:44:17,090 --> 00:44:25,490
+the value of F primeهو مقلوب مشتقة الدالة F عند
+
+440
+00:44:25,490 --> 00:44:31,690
+النقطة A التي هي F inverse of B التلت أسطر و نص
+
+441
+00:44:31,690 --> 00:44:38,240
+هذول بناروح نصيغهم في سطر واحد فقط لغيرفروح نقولنا
+
+442
+00:44:38,240 --> 00:44:42,080
+that is I amنا يعني التلات تاس و نص بدنا نصيحهم
+
+443
+00:44:42,080 --> 00:44:47,460
+بالصيغة رياضية عملية نشتغل بها في حال المثال ديقول
+
+444
+00:44:47,460 --> 00:44:54,740
+يبقى مشتقة معكوس الدلة D F inverse على DX وين عند
+
+445
+00:44:54,740 --> 00:45:00,680
+X تساوي B اللي موجودة في دمية الميندمن ال F انفرز
+
+446
+00:45:00,680 --> 00:45:04,680
+ال A هي اللي في دمن ال F بدل ما يساوي F of A يساوي
+
+447
+00:45:04,680 --> 00:45:10,600
+من ريس براكل يبقى مقلوب قلنا واحد على مشتقة الدلة
+
+448
+00:45:10,600 --> 00:45:16,080
+F وين عند النقطة A اللي موجودة في دمن الدلة F وال
+
+449
+00:45:16,080 --> 00:45:21,850
+A هي F inverse of Bيبقى إذا بدى أجيب مشتقة معكوس
+
+450
+00:45:21,850 --> 00:45:26,650
+الدالة عند نقطة بدى أشوف النقطة المكافئة لها أو
+
+451
+00:45:26,650 --> 00:45:32,930
+صورتها وين في domain الدالة F وبالتالي بقول واحد
+
+452
+00:45:32,930 --> 00:45:39,430
+على مشتقة الدالة F عند هذه النقطة لحظة النقطة هذه
+
+453
+00:45:39,430 --> 00:45:45,840
+هي اللي موجودة في domain الدالةأف مظبوط والإيه هي
+
+454
+00:45:45,840 --> 00:45:51,520
+صورة معكوس الدالة عند بيه في inverse of بيهامين
+
+455
+00:45:51,520 --> 00:45:58,580
+وهذا الكلام التعريف اللي قلناه يوم أمس الأول طيب
+
+456
+00:45:58,580 --> 00:46:04,680
+يبقى هذا كيفية الحصول على مشتقة معكوس الدالة دون
+
+457
+00:46:04,680 --> 00:46:09,660
+الحصول على شكل المعكوس هل يتطلب الأمر أعرف شكل
+
+458
+00:46:09,660 --> 00:46:13,030
+المعكوس؟إذا المثال اللي توسع قلنا احنا وياكوا
+
+459
+00:46:13,030 --> 00:46:16,410
+الشفوي هذا الـ Apoxys 11 المعادة الـ polynomial
+
+460
+00:46:16,410 --> 00:46:20,490
+الطويلة هذه أثبتنا إن الـ F inverse exist لكن مش
+
+461
+00:46:20,490 --> 00:46:25,150
+قادرين نجيبه لكن بقدر أجيب مشتقة معكوسة درلة
+
+462
+00:46:25,150 --> 00:46:30,850
+بواسطة مين؟ بواسطة هذه النظرية عند أي نقطة موجودة
+
+463
+00:46:30,850 --> 00:46:38,440
+في domain الـ F inverseالان لم يبقى في هذا section
+
+464
+00:46:38,440 --> 00:46:44,620
+إلا مجموعة من الأمثلة نتعرض للمحاضرة القادمة ان
+
+465
+00:46:44,620 --> 00:46:45,680
+شاء الله تعالى
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/lLbv-C3PDbo.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/lLbv-C3PDbo.srt
new file mode 100644
index 0000000000000000000000000000000000000000..dab7e2e7e6acaecb9a01c497029714cb92ea8d07
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/lLbv-C3PDbo.srt
@@ -0,0 +1,1670 @@
+1
+00:00:09,980 --> 00:00:15,520
+بسم الله الرحمن الرحيم المرة الماضية بدأنا في
+
+2
+00:00:15,520 --> 00:00:19,560
+حكاية ال improper integral وعرفنا أن ال improper
+
+3
+00:00:19,560 --> 00:00:25,480
+integral بتجزأ إلى نوعين النوع الأول لو كان أحد
+
+4
+00:00:25,480 --> 00:00:31,950
+حدود التكامل أو كلاهما infinity مثال ذلك تكامل على 
+
+5
+00:00:31,950 --> 00:00:38,190
+f of x من a إلى infinity للـ f of x dx المثال
+
+6
+00:00:38,190 --> 00:00:43,730
+الثاني من هذا
+
+7
+00:00:43,730 --> 00:00:46,110
+وهو تكامل من سالب infinity
+
+8
+00:00:49,160 --> 00:00:53,580
+المثال الثالث هو تكامل من سالب infinity إلى infinity
+
+9
+00:00:53,580 --> 00:00:58,460
+للـ F of X DX وهذا ما عرفناه في المرة الماضية
+
+10
+00:00:58,460 --> 00:01:03,660
+وسمينا هذا improper integral من النوع الأول وأخذنا
+
+11
+00:01:03,660 --> 00:01:09,840
+على ذلك بِدَل المثال أربعة أمثلة المرة الماضية الآن
+
+12
+00:01:09,840 --> 00:01:13,140
+بنجي للنقطة اللي بقعده قبل ما ناخد ال improper
+
+13
+00:01:13,140 --> 00:01:17,260
+integral من النوع الثاني، في عند نظرية، النظرية
+
+14
+00:01:17,260 --> 00:01:23,040
+موجودة عندك في الكتاب على شكل مثال لكن لما كان هذا
+
+15
+00:01:23,040 --> 00:01:27,640
+نحتاجه كثير في حل المسائل، قلنا بأن نعتمد هذا
+
+16
+00:01:27,640 --> 00:01:34,860
+المثال كنظرية ونستخدمها متى ما لزم الأمر. النظرية
+
+17
+00:01:34,860 --> 00:01:39,060
+بتقول لو كان a أكبر من الـ zero رقم موجب يبقى
+
+18
+00:01:39,060 --> 00:01:43,540
+integration من a إلى infinity لـ dx على x to the
+
+19
+00:01:43,540 --> 00:01:49,190
+power P converge إذا كان الـP أكبر من الواحد
+
+20
+00:01:49,190 --> 00:01:54,410
+و diverge إذا كان الـP أقل من أو تساوي الواحد إذا مش
+
+21
+00:01:54,410 --> 00:01:58,050
+هنحكم على تكامل من هذا القبيل هل هو converge ولا
+
+22
+00:01:58,050 --> 00:02:03,350
+diverge بتطلع للـS تبع الـX والله إذا الـS تبع
+
+23
+00:02:03,350 --> 00:02:06,390
+الـX كان أكبر من الواحد الصحيح يمكن التكامل
+
+24
+00:02:06,390 --> 00:02:11,070
+converge وإذا كان الـS أقل من الواحد الصحيح أو
+
+25
+00:02:11,070 --> 00:02:16,560
+يساوي يمكن التكامل diverge مثال وذلك، لو قلنا
+
+26
+00:02:16,560 --> 00:02:23,600
+تكامل آه مثلا من واحد لمعنى نهاية لـ DX على X أس
+
+27
+00:02:23,600 --> 00:02:28,320
+ثلاثة على اثنين convert إن ثلاثة على اثنين كسر
+
+28
+00:02:28,320 --> 00:02:32,540
+أكبر من الواحد الصحيح يبقى هذا التكامل convert لكن
+
+29
+00:02:32,540 --> 00:02:38,040
+لو قلت نفس التكامل واحد على X أس ثلاثة على اثنين بدل ثلاثة
+
+30
+00:02:38,040 --> 00:02:42,860
+على اثنين مشي للتكامل diverge لو قلت واحد على X DX
+
+31
+00:02:43,770 --> 00:02:48,370
+بقى ضايف في يده إن القصة بقدرش بواحد صحيح طبق لمين
+
+32
+00:02:48,370 --> 00:02:52,610
+لهذه الحالة. طبعاً إلها برهان لبرهان، بقول لك مثال
+
+33
+00:02:52,610 --> 00:02:56,090
+محلول في الكتاب، بتروح الكتاب وتقرأ هذا المثال
+
+34
+00:02:56,090 --> 00:03:00,950
+وتجد الكلام اللي احنا بنقوله هذا كلام صحيح. الآن
+
+35
+00:03:00,950 --> 00:03:04,570
+ننتقل إلى النوع الثاني من أنواع الـ Improper
+
+36
+00:03:04,570 --> 00:03:08,650
+Integral النوع الثاني يقول إن إذا دالة المراد
+
+37
+00:03:08,650 --> 00:03:15,290
+تكاملها أصبحت غير معرفة عند نقطة وهذه النقطة خلال
+
+38
+00:03:15,290 --> 00:03:19,910
+فترة التكامل، إن حدث ذلك، بنقول هذا Improper
+
+39
+00:03:19,910 --> 00:03:23,110
+Integral من النوع الثاني.
+
+40
+00:03:25,380 --> 00:03:29,540
+the integrals of functions that become infinite
+
+41
+00:03:29,540 --> 00:03:35,600
+تصبح غير معرفة عند نقطة within the interval of
+
+42
+00:03:35,600 --> 00:03:39,780
+integration خلال فترة التكامل are called improper
+
+43
+00:03:39,780 --> 00:03:45,780
+integral of type two يبقى من النوع الثاني يبقى هذا
+
+44
+00:03:45,780 --> 00:03:50,140
+بنسميه improper integral كيف بدأ نحسبه؟ بنفس
+
+45
+00:03:50,140 --> 00:03:54,600
+الفكرة اللي حسبنا فيها المرة اللي فاتت وهي أخذ ال
+
+46
+00:03:54,600 --> 00:03:59,930
+limit كيف؟ نجيب أقول النقطة الأولى، لو كانت الدالة
+
+47
+00:03:59,930 --> 00:04:04,650
+دالة متصلة على هذه الفترة، يبقى التكامل exist.
+
+48
+00:04:04,890 --> 00:04:10,330
+لاحظ عند الـ A فترة مفتوحة وعند الـ B مغلقة وكانت
+
+49
+00:04:10,330 --> 00:04:16,500
+الدالة غير متصلة عند A عند أول الـ interval يبقى
+
+50
+00:04:16,500 --> 00:04:22,080
+تكامل من A إلى B إلى الـF of X DX يساوي تكامل من C
+
+51
+00:04:22,080 --> 00:04:26,340
+إلى B إلى الـF of X DX وبعد ما أقوم بعملية التكامل
+
+52
+00:04:26,340 --> 00:04:31,680
+وأروح باخد ال limit لما الـC بدأت تروح إلى A من جهة
+
+53
+00:04:31,680 --> 00:04:37,020
+اليمين نحسب هذه الـ Limit والله إذا وجدت الـ Limit
+
+54
+00:04:37,020 --> 00:04:41,660
+هذه exist بيتكامل converge وإذا الـ Limit does not
+
+55
+00:04:41,660 --> 00:04:46,500
+exist بيتكامل diverge بالمثل في الحالة الثانية، لو
+
+56
+00:04:46,500 --> 00:04:51,300
+كانت الدلة دالة متصلة على الفترة من A إلى B مغلقة
+
+57
+00:04:51,300 --> 00:04:57,440
+من عند الـA وافتوحة من عند الـB وكانت دالة غير
+
+58
+00:04:57,440 --> 00:05:01,800
+متصلة عند الـB يبقى التكامل من A إلى B للـF of X
+
+59
+00:05:01,800 --> 00:05:07,420
+DX وتكامل من A إلى C يعني بشيل الـB وبحط مكانها C
+
+60
+00:05:07,420 --> 00:05:11,940
+وبكمل الدالة وبعوض وحدود التكامل وبعد هيك بروح
+
+61
+00:05:11,940 --> 00:05:16,140
+باخد ال limit لما الـC بدها تروح للـB من جهة
+
+62
+00:05:16,140 --> 00:05:20,420
+الشمال والله إذا تكامل exist if limit exist يبقى
+
+63
+00:05:20,420 --> 00:05:24,140
+تكامل converge if limit does not exist يبقى تكامل
+
+64
+00:05:24,140 --> 00:05:28,280
+diverge يبقى النقطة الأولى والثانية الأولى كانت عند
+
+65
+00:05:28,280 --> 00:05:32,580
+بداية الـ interval الثانية كانت عند نهاية الـ
+
+66
+00:05:32,580 --> 00:05:36,360
+interval فبفرض discontinuity حصل عند نقطة وده
+
+67
+00:05:36,360 --> 00:05:40,720
+النقطة لا عند البداية ولا عند النهاية، أي نقطة
+
+68
+00:05:40,720 --> 00:05:45,000
+داخل الـ interval فبجي بقول له ال discontinuity كان
+
+69
+00:05:45,000 --> 00:05:48,960
+C اللي موجودة في الفترة المفتوحة A وB ولم أقول
+
+70
+00:05:48,960 --> 00:05:54,520
+المغلقة يعني الـ C هذه لا حتساوي A ولا حتساوي
+
+71
+00:05:54,520 --> 00:06:01,580
+B بيبقى أي نقطة بينهما and continuous على كل الفترة
+
+72
+00:06:01,580 --> 00:06:06,600
+من A إلى C ومن C إلى B يعني ال discontinuity حاصلة
+
+73
+00:06:06,600 --> 00:06:11,360
+عند C اللي موجودة داخل هذه الـ interval يبقى تكامل
+
+74
+00:06:11,360 --> 00:06:16,580
+من A إلى B للـF of X DX، هروح أجزئه إلى تكاملين،
+
+75
+00:06:16,580 --> 00:06:21,440
+هذا التكامل الأول وهذا هو التكامل الثاني. التكامل
+
+76
+00:06:21,440 --> 00:06:26,020
+الأول هو الحالة الثانية والتكامل الثاني هو الحالة
+
+77
+00:06:26,200 --> 00:06:31,520
+الأولى يبقى راحت كتبتهم as limits والله إذا
+
+78
+00:06:31,520 --> 00:06:35,860
+التنتين converge يبقى التكامل الأصلي converge واحدة
+
+79
+00:06:35,860 --> 00:06:40,940
+converge والثانية diverge يبقى diverge إذا التنتين
+
+80
+00:06:40,940 --> 00:06:46,400
+diverge وبالمثل يبقى التكامل diverse إذا كانتان
+
+81
+00:06:46,400 --> 00:06:51,760
+diverse يوابس سالم maybe diverse or maybe converge
+
+82
+00:06:51,760 --> 00:06:56,200
+ممكن هذه وممكن آية هذه الـ definition هو الكلام
+
+83
+00:06:56,200 --> 00:06:59,940
+اللي قلناه هنا قال لي في كل حالة من الحالات هذول
+
+84
+00:07:00,120 --> 00:07:03,920
+إذا كان هناك قيمة فهي قيمة التكامل. وإذا كان هناك
+
+85
+00:07:03,920 --> 00:07:11,080
+قيمة فهي قيمة التكامل. وإذا كان هناك قيمة فهي قيمة
+
+86
+00:07:11,080 --> 00:07:17,580
+التكامل. وإذا كان هناك قيمة فهي قيمة التكامل. وإذا
+
+87
+00:07:17,580 --> 00:07:23,140
+كان هناك قيمة فهي 
+
+88
+00:07:23,140 --> 00:07:26,700
+قيمة التكامل.
+
+89
+00:07:48,820 --> 00:07:53,380
+قيمة التكامل هي قيمة الـ Limit نفسها بالضبط
+
+90
+00:07:53,380 --> 00:07:58,130
+تمامًا. بنروح الآن إلى أمثلة على هذا الكلام بيقول
+
+91
+00:07:58,130 --> 00:08:02,330
+شوف لمين من التكامل التالي يكون converge ومين منها
+
+92
+00:08:02,330 --> 00:08:07,750
+بيعطاني تكامل من 0 لـ 1 لـ 4 X على الجذر التربيعي لـ
+
+93
+00:08:07,750 --> 00:08:13,590
+1 ناقص X أس 4 بمجرد النظر بلاحظ أن الدالة هذه
+
+94
+00:08:13,590 --> 00:08:19,750
+مالها is not continuous عند الواحد عند الواحد موجود
+
+95
+00:08:19,750 --> 00:08:25,890
+خلال فترة التكامل وهو نهاية هذه الفترة يبقى بناءً
+
+96
+00:08:25,890 --> 00:08:31,690
+عليه هذا الكلام بده يصير ال limit تكامل من zero
+
+97
+00:08:31,690 --> 00:08:37,210
+لغاية B يبقى اللي عنده المشكلة بيحطه بأي رمز آخر و
+
+98
+00:08:37,210 --> 00:08:43,230
+بيخلي الـ B بدها تروح للواحد من جهة الشمال
+
+99
+00:08:50,190 --> 00:08:57,850
+4x يبقى 2 في 2x، لماذا هذا ما سنجيب عليه فورًا واحد
+
+100
+00:08:57,850 --> 00:09:04,170
+ناقص x تربيع لكل تربيع دي x؟ يبقى x و 4 حطيناها x
+
+101
+00:09:04,170 --> 00:09:09,700
+تربيع تربيع المهم بدي أشيل ال X تربيع وأحط بدالها
+
+102
+00:09:09,700 --> 00:09:15,080
+variable مشان نقدر نكامل يبقى بقوله حطلي T تساوي X
+
+103
+00:09:15,080 --> 00:09:22,640
+تربيع يبقى DT بدي أساوي 2X DX من هنا 2X DX اللي
+
+104
+00:09:22,640 --> 00:09:28,970
+كتبناها يعادل DT يبقى صار عندي ال limit لما b
+
+105
+00:09:28,970 --> 00:09:33,070
+بدها تروح للواحد من جهة الشمال وهاي الاثنين
+
+106
+00:09:33,070 --> 00:09:40,610
+خليها برا ال limit وهذا صار تكامل لدي T على الجذر
+
+107
+00:09:40,610 --> 00:09:47,500
+التربيعي لواحد ناقص ت تربيع بديش احط حدود التكامل،
+
+108
+00:09:47,500 --> 00:09:51,340
+بديش اغيرها، لإن لو غيرت من هناك، بتغير ال index
+
+109
+00:09:51,340 --> 00:09:57,880
+اللي بتاع ال limit لذلك بقول هذا اثنين limit لما
+
+110
+00:09:57,880 --> 00:10:02,430
+B بدها تروح للواحد من جهة الشمال تكامل هذه اللي هو
+
+111
+00:10:02,430 --> 00:10:08,370
+مين؟ sign inverse يبقى sign inverse و T اللي هي
+
+112
+00:10:08,370 --> 00:10:13,650
+مجدادش بكسر بيها والحين بحط حدود التكامل اللي هو
+
+113
+00:10:13,650 --> 00:10:19,150
+من ولا وين من zero لغاية الـ B يبقى هذا الكلام
+
+114
+00:10:19,150 --> 00:10:24,850
+بده يساوي هاي اثنين برا وهذا ال limit وهذا ال
+
+115
+00:10:24,850 --> 00:10:30,910
+limit لما B بدها تروح للواحد من جهة الشمال لمين؟
+
+116
+00:10:30,910 --> 00:10:37,590
+لـ sign inverse one ناقص sign inverse zero طبعًا
+
+117
+00:10:37,590 --> 00:10:43,010
+sign inverse zero بـ zero وهذا الكلام يساوي اثنين و
+
+118
+00:10:43,010 --> 00:10:49,340
+sign inverse one مين الزاوية اللي جيبها واحد؟ قد ايه؟
+
+119
+00:10:49,340 --> 00:10:56,580
+90 يبقى باي على 2 يبقى النتيجة تساوي باي فقط الـ
+
+120
+00:10:56,580 --> 00:11:00,640
+limit سوى قيمة عددية يبقى التكامل converge وقيمة
+
+121
+00:11:00,640 --> 00:11:06,100
+التكامل تساوي هذه القيمة العددية إذا هذا بده يعطينا
+
+122
+00:11:06,100 --> 00:11:12,280
+تكامل من zero لغاية واحد للاربعة x على الجذر
+
+123
+00:11:12,280 --> 00:11:18,390
+التربيعي للواحد ناقص x اس اربعة dx converge تهيئنا
+
+124
+00:11:18,390 --> 00:11:43,630
+من المثال مثال
+
+125
+00:11:43,630 --> 00:11:43,890
+8
+
+126
+00:12:04,400 --> 00:12:09,380
+المشكلة هنا يا عزيزي عن مين عندي اتنين يبقى دا
+
+127
+00:12:09,380 --> 00:12:13,460
+improper دا integral لإنه عندي اتنين هذه ال
+
+128
+00:12:13,460 --> 00:12:19,460
+function غير معرفة إذا بتروح اكتب هذا الكلام limit
+
+129
+00:12:19,460 --> 00:12:26,060
+و تكامل من a لغاية أربعة لما ال a بدأ تروح للي
+
+130
+00:12:26,060 --> 00:12:32,400
+اتنين من جهة اليمين لمين لواحد على x ناقص اتنين
+
+131
+00:12:32,400 --> 00:12:34,900
+لكل تربيع dx
+
+132
+00:12:41,500 --> 00:12:47,380
+سالب واحد على X ناقص اتنين يبقى هذا ال limit لما
+
+133
+00:12:47,380 --> 00:12:53,460
+ال A بدأ تروح للاتنين من جهة اليمين لسالب واحد على
+
+134
+00:12:53,460 --> 00:12:59,540
+X ناقص اتنين وكل هذا الكلام من عند ال A لغاية
+
+135
+00:12:59,540 --> 00:13:05,190
+الأربعة يبقى هذا الكلام بده يساوي ال limit لما ال a
+
+136
+00:13:05,190 --> 00:13:09,750
+بده تروح لل اثنين من جهة اليمين و أي شرط السؤال
+
+137
+00:13:09,750 --> 00:13:17,770
+برابعة ناقص اتنين اللي هو بقداش اثنين ناقص واحد
+
+138
+00:13:17,770 --> 00:13:25,290
+على ايه ناقص اتنين ويساوي هذا الناقص برا نهاية
+
+139
+00:13:25,290 --> 00:13:30,770
+المقدار الثابت بالمقدار الثابت itself وصلنا لناقص
+
+140
+00:13:30,770 --> 00:13:36,390
+هاي ناقص الان ايه بده تروح للاتنين من جهة اليمين
+
+141
+00:13:36,630 --> 00:13:40,810
+يبقى اتنين من جهة اليمين يعني اتنين وكسر بسيط جدا
+
+142
+00:13:40,810 --> 00:13:46,790
+ناقص اتنين يبقى very small positive quantity يبقى
+
+143
+00:13:46,790 --> 00:13:53,490
+واحد على very small positive quantity اللي بتعطيه
+
+144
+00:13:53,490 --> 00:13:54,370
+اللانهاية
+
+145
+00:14:16,880 --> 00:14:19,160
+المثال الثالث
+
+146
+00:14:25,760 --> 00:14:36,340
+بنتكامل من 0 لغاية 2 لدى x على الجذر التربيعي ل
+
+147
+00:14:36,340 --> 00:14:40,180
+absolute value ل X ناقص الواحد
+
+148
+00:15:09,070 --> 00:15:14,510
+واضح أن الدالة غير معرفة عند ال واحد والواحد موجود
+
+149
+00:15:14,510 --> 00:15:17,910
+في الفترة من Zero للاتنين، لو كان الرقم هذا برا
+
+150
+00:15:17,910 --> 00:15:21,150
+الفترة ماليش علاقة فيه، بقولش عنه improper
+
+151
+00:15:21,150 --> 00:15:25,150
+integral، بقولش improper إلا إذا كان موجود خلال
+
+152
+00:15:25,150 --> 00:15:31,010
+فترة من التكامل. يبقى هضطر اجزء المثلة الى جزءين من
+
+153
+00:15:31,010 --> 00:15:35,770
+0 لغاية الواحد من واحد للي اتنين و اروح اكمل
+
+154
+00:15:35,770 --> 00:15:41,030
+تمام مية المية صحيح لكن واحد اشتر مننا شوية قال لا
+
+155
+00:15:41,030 --> 00:15:45,570
+لا لا قلت له ايوة قلت لي انا ممكن اعمل تعويضة غير
+
+156
+00:15:45,570 --> 00:15:50,550
+شكل وبالتالي يتشجل بوضع المثل بيقولك اذا ال X ناقص
+
+157
+00:15:50,550 --> 00:15:56,950
+هو هتحطها باي variable اخروقال لي احط لل Y تساوي X
+
+158
+00:15:56,950 --> 00:16:02,410
+ناقص واحد يبقى ال dy بده يساوي قداش dx يبقى صارة
+
+159
+00:16:02,410 --> 00:16:07,810
+المسألة هيها تكامل هي ال dx بده اشيل و احط بدلها
+
+160
+00:16:07,810 --> 00:16:12,590
+dy وهذا الجدر التربيه ال absolute value ل Y
+
+161
+00:16:20,500 --> 00:16:30,780
+بعد ذلك نضع X ب2 يصبح Y ب1 نضع X ب0 يصبح Y ب-1
+
+162
+00:16:30,780 --> 00:16:36,520
+نقول والله مظبوط كلام صحيح نقلت المسألة من وضع إلى
+
+163
+00:16:36,520 --> 00:16:42,670
+وضع جديد لا يزال الـ discontinuity بيحصل وين؟ عند
+
+164
+00:16:42,670 --> 00:16:47,550
+ال Zero وال Zero موجود خلال هذه الفترة، لأننا لم
+
+165
+00:16:47,550 --> 00:16:53,110
+نفعل أي شيء من وجهة النظر الأولى. لكن هل هذه
+
+166
+00:16:53,110 --> 00:16:57,670
+الدالة اللي بنكملها دالة زوجية ولا فردية؟ يعني لو
+
+167
+00:16:57,670 --> 00:17:00,990
+شيلنا ال Y وحطينا مكانها ناقص Y واخدنا لها ال
+
+168
+00:17:00,990 --> 00:17:05,050
+absolute value مش بتظل هي نفسها، يبقى هذه دالة
+
+169
+00:17:05,050 --> 00:17:10,410
+زوجية إذن اتنين التكامل على نصف الفترة يبقى هذا
+
+170
+00:17:10,410 --> 00:17:17,010
+الكلام بده يساوي اتنين تكامل من Zero لواحد لدي Y
+
+171
+00:17:17,010 --> 00:17:22,530
+على الجذر التربيعي ل absolute value ل Y طيب، هذا
+
+172
+00:17:22,530 --> 00:17:27,670
+الكلام يساوي اتنين تكامل من Zero لواحد من Zero
+
+173
+00:17:27,670 --> 00:17:33,950
+لواحد ال Y بتاخد قيم سالبة؟ لأ، يبقى هذه، خلّيت
+
+174
+00:17:33,950 --> 00:17:38,810
+absolute وانشلت ال absolute value كله سيان، يبقى
+
+175
+00:17:38,810 --> 00:17:45,630
+واحد على جذر ال Y دي واحد يبقى الشغل هذه إلها
+
+176
+00:17:45,630 --> 00:17:50,340
+فائدتين الفائدة الأولى اتخلصت من ال absolute value
+
+177
+00:17:50,340 --> 00:17:54,440
+اللي كنت مش عارف اتحرك و هي موجودة الشغل الثاني
+
+178
+00:17:54,440 --> 00:17:58,460
+بدل ما كنت بدي اعمل تكاملين بصير بدي اعمل ايه؟
+
+179
+00:17:58,460 --> 00:18:04,400
+تكامل واحد بقوله كويس يبقي هذي صارتي اتنين limit
+
+180
+00:18:04,400 --> 00:18:09,410
+تكامل المشكلة وين؟ عند ال zero يبقى بده اشيل ال
+
+181
+00:18:09,410 --> 00:18:17,270
+zero و احط a و هنا واحد و هنا y اس نص ناقص نص dy و خل
+
+182
+00:18:17,270 --> 00:18:23,500
+ال a تروح ل zero من جهات اليمين طيب، الروح الكامل
+
+183
+00:18:23,500 --> 00:18:29,880
+هذه دمج هذه تساوي اتنين برا وهي limit لما ال a
+
+184
+00:18:29,880 --> 00:18:36,460
+بدها تروح ل zero من جهة اليمين وهذه y اس نص على نص
+
+185
+00:18:36,460 --> 00:18:42,280
+والحكي من عند ال a لغاية قداش واحد يبقى هذا الكلام
+
+186
+00:18:42,280 --> 00:18:48,160
+بده يساوي أربعة limit لما a بده تروح ل zero من جهة
+
+187
+00:18:48,160 --> 00:18:55,800
+اليمين لجذر الواحد ناقص جذر ال a لما ال a بده تروح
+
+188
+00:18:55,800 --> 00:19:01,040
+ل zero يبقى هذا بقداش zero جذر الواحد بواحد يبقى
+
+189
+00:19:01,040 --> 00:19:07,280
+النتج بقداش أربعة يبقى الأربعة بناء عليه التكامل
+
+190
+00:19:07,280 --> 00:19:15,410
+لأن هذا ماله convert يبقى بجي بقوله هنا س تكامل من
+
+191
+00:19:15,410 --> 00:19:22,070
+zero لغاية اتنين لل dx على الجذر التربيعي لل X
+
+192
+00:19:22,070 --> 00:19:27,530
+ناقص واحد absolute value converged وانتهينا من
+
+193
+00:19:27,530 --> 00:19:36,600
+المثال خُد كمان مسألة أخرى شبيهة بالأشكال هذه تكامل
+
+194
+00:19:36,600 --> 00:19:45,320
+من صفر لغاية لإتنين ل dx على مين على x ناقص واحد
+
+195
+00:19:45,320 --> 00:19:46,480
+لكل تربيع
+
+196
+00:19:49,370 --> 00:19:55,090
+المشكلة تكمل وين؟ عند الواحد، تمام؟ ممكن أعمل
+
+197
+00:19:55,090 --> 00:19:58,910
+تعويضة زيها، بس أنا المرة أنا مش حابب أعمل تعويضة
+
+198
+00:19:58,910 --> 00:20:02,410
+زيها، ما اعرفش تجيبلي نتيجة زيها ولا مش زيها، الله
+
+199
+00:20:02,410 --> 00:20:09,120
+اعلم. المهم لو جيت جزأتي التكامل من صفر لغاية واحد
+
+200
+00:20:09,120 --> 00:20:15,480
+لدي X على X ناقص واحد لكل تربيع زائد تكامل من
+
+201
+00:20:15,480 --> 00:20:23,980
+واحد لليتنين لدي X X ناقص واحد لكل تربيع خلّينا
+
+202
+00:20:23,980 --> 00:20:31,130
+ناكل الان بدي اتي للتكامل الاول اشوف وهل هو convert
+
+203
+00:20:31,130 --> 00:20:38,070
+ولا diverge فبدي بقوله تكامل من صفر لواحد ل dx
+
+204
+00:20:38,070 --> 00:20:46,040
+على x ناقص واحد لكل تربيع يساوي المشكلة تكمن عند
+
+205
+00:20:46,040 --> 00:20:52,660
+الواحد يبقى هذا ال limit و تكامل من zero إلى b لما
+
+206
+00:20:52,660 --> 00:20:58,860
+b بدأ تروح للواحد من جهة الشمال لواحد على x ناقص
+
+207
+00:20:58,860 --> 00:21:06,470
+واحد لكل تربيع dx يبقى limit لما B بدأ تروح إلى
+
+208
+00:21:06,470 --> 00:21:13,290
+واحد من جهة الشمال لمين لا سالب واحد على x ناقص
+
+209
+00:21:13,290 --> 00:21:20,180
+واحد كله من عند ال zero لغاية  main لغاية ال B يبقى
+
+210
+00:21:20,180 --> 00:21:25,860
+هذا الكلام بده يساوي هذا ال limit لما B بدها تروح
+
+211
+00:21:25,860 --> 00:21:31,020
+للواحد من جهة الشمال وهي السالم وبتعود بالقيمة
+
+212
+00:21:31,020 --> 00:21:38,040
+اللي فوق واحد على B ناقص واحد ناقص واحد صفر على
+
+213
+00:21:38,040 --> 00:21:44,720
+ناقص واحد تعال نشوف النتيجة بيبدأ تروح للواحد من
+
+214
+00:21:44,720 --> 00:21:50,160
+جهة الشمال يعني أقل من واحد يبقى المقام very small
+
+215
+00:21:50,160 --> 00:21:57,880
+negative يبقى ما يساوي الناقص واحد على very small
+
+216
+00:21:57,880 --> 00:22:05,170
+negative quantity زائد واحد يبقى هذا الكلام بده
+
+217
+00:22:05,170 --> 00:22:11,770
+يساوي سالب هذا بيعطيك مين؟ سالب infinity هذا
+
+218
+00:22:11,770 --> 00:22:16,810
+بيعطيك سالب infinity زائد واحد
+
+219
+00:22:24,520 --> 00:22:31,180
+يبقى التكامل الأولاني هذا ماله diverge يبقى سواء
+
+220
+00:22:31,180 --> 00:22:37,360
+تكامل من zero لواحد لديه x على x ناقص واحد لكل
+
+221
+00:22:37,360 --> 00:22:46,940
+تربية ماله diverge الان دور عليك تشك يبقى انت
+
+222
+00:22:46,940 --> 00:22:58,680
+تعملي ذات تكامل من 1 ل 2 ل DX علي X ناقص واحد برضه
+
+223
+00:22:58,680 --> 00:23:05,580
+بدى يساوي infinity وهذا معناه ان التكامل من واحد
+
+224
+00:23:05,580 --> 00:23:12,460
+للاتنين ل dx على x ناقص واحد لكل ترابية ماله
+
+225
+00:23:12,460 --> 00:23:12,960
+diverge
+
+226
+00:23:15,850 --> 00:23:21,930
+تكامل من Zero للإتنين للواحد على X ناقص واحد لكل
+
+227
+00:23:21,930 --> 00:23:27,330
+تربية DX ماله diverge ماله نهاية زائد ماله نهاية
+
+228
+00:23:27,330 --> 00:23:32,670
+بمالها نهاية وبالتالي تكامل ماله diverge طيب افترض
+
+229
+00:23:32,670 --> 00:23:39,030
+انه انا جيبتلك هذا السؤال في الامتحان طبعا وانت
+
+230
+00:23:39,030 --> 00:23:43,850
+طلعت فى الامتحان وقلت هي و الله هذا سؤال سهل جدا
+
+231
+00:23:43,850 --> 00:23:50,710
+هذا يبنوه النهدية طبعا و جيت اتكامل على طول لا قلت
+
+232
+00:23:50,710 --> 00:23:54,990
+improper integral ولا اجه فى بالك ال improper
+
+233
+00:23:54,990 --> 00:23:59,850
+integral وقلت اتكامل من zero لاتنين x ناقص واحد
+
+234
+00:23:59,850 --> 00:24:04,990
+لكل تربيع dx وروحت بدل ما تسوي زينا improper
+
+235
+00:24:04,990 --> 00:24:11,010
+integral ونثبت انه بعد كامل يبقى هذا على طول الخط
+
+236
+00:24:11,010 --> 00:24:17,390
+سالب واحد على اكس ناقص واحد والكلام هذا من zero
+
+237
+00:24:17,390 --> 00:24:22,330
+للاثنين تمام؟ و جينا قولنا بينا نعوض بالقيمة اللي
+
+238
+00:24:22,330 --> 00:24:27,790
+فوق ناقص اللي تحت اتنين ناقص واحد بيبقى قداش واحد
+
+239
+00:24:27,790 --> 00:24:33,350
+ناقص نشيل ال X و نحط مكان Zero و حطينا Zero طلع
+
+240
+00:24:33,350 --> 00:24:38,810
+قداش واحد على سالب واحد يعني سالب واحد واحد ناقص
+
+241
+00:24:38,810 --> 00:24:46,610
+سالب صار قداش سالب اثنين ايش
+
+242
+00:24:46,610 --> 00:24:50,220
+رأيك؟ انت كام ال converge؟ وشوف ال conversion هنا
+
+243
+00:24:50,220 --> 00:24:55,980
+ضعيفة، إيش رأيك في طريقة الحل هذه؟ هذه ههه، لو
+
+244
+00:24:55,980 --> 00:25:03,000
+حليت بها، تاخد عليها صفر، صفر كماما، ليش بتاخد
+
+245
+00:25:03,000 --> 00:25:08,080
+عليها صفر؟ لأن هذا improper integral وانت مغفلة في
+
+246
+00:25:08,080 --> 00:25:11,800
+نايم تدريش ان هذا improper integral وروحت عملت
+
+247
+00:25:11,800 --> 00:25:17,460
+تكامل عادي من هنا هذا الفرق ما بين التكامل العادي
+
+248
+00:25:17,460 --> 00:25:22,900
+وما بين ال improper integral يفجأ لو جاءك سؤال في
+
+249
+00:25:22,900 --> 00:25:29,100
+الامتحان وشفت التكامل محدود وما فيه infinity اللي
+
+250
+00:25:29,100 --> 00:25:32,320
+إذا فيه infinity بيكون مبين للعمل خلاص الكل شايفه 
+
+251
+00:25:32,320 --> 00:25:35,480
+وعارفة لكن لما يكون تكامل محدود من صفر لإثنين
+
+252
+00:25:35,480 --> 00:25:39,140
+أرقام automatic بتروح على الدالة اللي إيه اللي
+
+253
+00:25:39,140 --> 00:25:43,640
+بناها كاملة شوف هل هي معرفة خلال فترة التكامل أو 
+
+254
+00:25:43,640 --> 00:25:47,920
+لا إذا معرفة كاملة وتوكل على الله وإذا مش معرفة
+
+255
+00:25:47,920 --> 00:25:52,780
+إذا إحنا قصدنا أن نشوفك صح لها الشغل والله ما نتسّ 
+256
+00:25:52,780 --> 00:25:53,120
+صحّي
+
+257
+00:25:57,100 --> 00:26:02,400
+خليك معاه، إذا الـ Improper Integral ويكون له 
+
+258
+00:26:02,400 --> 00:26:06,720
+قيمة عددية، ممكن يقولك يحسب، واسكت، يعني ممكن يطلع 
+
+259
+00:26:06,720 --> 00:26:09,760
+التكامل هذا الـ Conversion، زي ما شفنا قبل شوية،
+
+260
+00:26:09,760 --> 00:26:11,800
+إيش الـ Conversion، وإيش الـ Divide، إذا الـ
+
+261
+00:26:11,800 --> 00:26:14,620
+Conversion ممكن يقولك يحسب التكامل، واسكت، يبقى 
+
+262
+00:26:14,620 --> 00:26:19,180
+أنت بتجفت عينك وتشوف الدالة المُراد تكاملها، هل هي
+
+263
+00:26:19,180 --> 00:26:20,780
+معرفة ولا غير معرفة؟
+
+264
+00:26:23,630 --> 00:26:28,790
+يوجد نظر أخرى، هل التكامل لأن هذا قيمة سالب أو
+
+265
+00:26:28,790 --> 00:26:33,690
+لا؟ طب ما هو المساحة؟ خلينا نرى كده. المساحة
+
+266
+00:26:33,690 --> 00:26:36,910
+دايما هو مساحة قيمة موجبة. طالع سالب، معناته في 
+
+267
+00:26:36,910 --> 00:26:42,330
+علامة استفهام. يبقى علامة استفهام أمام هذه 
+
+268
+00:26:42,330 --> 00:26:46,710
+النتيجة. إذن هذا بتعطيك أن ما فيش تكامل يعطيك قيمة
+
+269
+00:26:46,710 --> 00:26:53,690
+سلبية وإلا إذا كانت منطقة تين، منطقة أعلى محور X 
+
+270
+00:26:53,690 --> 00:26:58,650
+والثانية أسفل محور X واللي تحت محور X أكبر من اللي 
+
+271
+00:26:58,650 --> 00:27:05,850
+فوق محور X، ممكن يطلع سالب. إيه؟ لو حليت مباشرة، 
+
+272
+00:27:05,850 --> 00:27:10,850
+بنحط لك صفر. Converge، ولا ما نتّش نقول، هقول لك
+
+273
+00:27:10,850 --> 00:27:16,530
+صفر. خلاص؟ إذا معرفة بطل، يصبح الـ Improper
+
+274
+00:27:16,530 --> 00:27:20,840
+Integral. على ما نحكي إذا هو proper or integer هو
+
+275
+00:27:20,840 --> 00:27:23,640
+يفتخر له limit، ما هو مش proper or integer يعني مش 
+
+276
+00:27:23,640 --> 00:27:24,560
+حاجة يصيب له limit.
+
+277
+00:27:28,520 --> 00:27:33,540
+كل مرة نروح نكامل، ناخد limit ونسوي هذه القصة طويلة،
+
+278
+00:27:33,540 --> 00:27:39,140
+مش كل المسائل بنقدر نكاملهم. يعني في بعض المسائل
+
+279
+00:27:39,140 --> 00:27:44,440
+صعب تكاملهم. ما دام صعب، كيف بنعمل؟ بنقول لك بسيطة
+
+280
+00:27:44,440 --> 00:27:49,080
+خالص، في عندنا اختبارين بواسطتهم، بنحكم على هذا
+
+281
+00:27:49,080 --> 00:27:54,150
+التكامل هل هو converge ولا divate باستخدام النظرية 
+
+282
+00:27:54,150 --> 00:27:59,950
+اللي كتبناها قبل قليل هنا كانت في رأس السبورة من 
+
+283
+00:27:59,950 --> 00:28:03,330
+فوق يبقى بإذن الله نجي للاختبارين و مكافئ اليوم
+
+284
+00:28:03,330 --> 00:28:08,890
+نبدأ بس أول اختبار و بدك تفرق مخك معايا شوية هكذا
+
+285
+00:28:08,890 --> 00:28:13,190
+مشان تستطيع تفهم هذا الكلام يبقى بإذن الله نجي
+
+286
+00:28:13,190 --> 00:28:15,370
+لحاجة اسمها tests
+
+287
+00:28:17,670 --> 00:28:23,350
+اختبارات for convergence
+
+288
+00:28:23,350 --> 00:28:33,930
+for convergence of the improper integral
+
+289
+00:28:33,930 --> 00:28:37,890
+أول 
+
+290
+00:28:37,890 --> 00:28:45,090
+اختبار من هذه الاختبارات اسمه direct comparison
+
+291
+00:28:49,310 --> 00:29:00,070
+بقول اختبار ما يأتي let f of x and g of x be
+
+292
+00:29:00,070 --> 00:29:03,370
+continuous
+
+293
+00:29:03,370 --> 00:29:12,730
+دالة متصلة على الفترة a و infinity with
+
+294
+00:29:18,430 --> 00:29:26,690
+صفر أقل من f of x أقل من أو يساوي g of x لكل ال x 
+
+295
+00:29:26,690 --> 00:29:36,150
+اللي أكبر من أو تساوي a then النقطة الأولى تكافئ
+
+296
+00:29:36,150 --> 00:29:47,800
+التكامل من a إلى infinity لل g of x dx converge ثم 
+
+297
+00:29:47,800 --> 00:29:57,160
+التكامل من a إلى infinity لل f of x dx convert
+
+298
+00:30:01,640 --> 00:30:10,320
+فتكامل من a إلى infinity لل F of x dx diverge then
+
+299
+00:30:10,320 --> 00:30:18,820
+تكامل من a إلى infinity لل G of x dx diverge
+
+300
+00:30:58,600 --> 00:31:13,820
+remark let f and g be continuous functions دالتين 
+
+301
+00:31:13,820 --> 00:31:27,930
+المتصلتين على a وb على الفترة من a إلى b if ال if and
+
+302
+00:31:27,930 --> 00:31:33,750
+ال g are discontinuous
+
+303
+00:31:33,750 --> 00:31:38,770
+discontinuous
+
+304
+00:31:38,770 --> 00:31:55,160
+at aand at x يساوي a and 0 أقل من أو يساوي f of x 
+
+305
+00:31:55,160 --> 00:32:02,140
+أقل من أو يساوي g of x لكل ال x اللي موجود في ال
+
+306
+00:32:02,140 --> 00:32:05,820
+interval a و b then
+
+307
+00:32:12,460 --> 00:32:25,680
+تكامل من a إلى b لل g of x dx convert then تكامل
+
+308
+00:32:25,680 --> 00:32:31,440
+من a إلى b لل f of x dx convert
+
+309
+00:32:37,580 --> 00:32:46,160
+تكامل من A إلى B للـ F of X DX diverge then تكامل
+
+310
+00:32:46,160 --> 00:32:56,360
+من A إلى B للـ G of X DX diverge examples و أنا 
+
+311
+00:32:56,360 --> 00:33:01,140
+أجيب ال examples ملاحظة Note
+
+312
+00:33:11,200 --> 00:33:20,360
+the above remark is 
+
+313
+00:33:20,360 --> 00:33:24,940
+true on
+
+314
+00:33:24,940 --> 00:33:37,020
+the interval a وb examples
+
+315
+00:33:41,490 --> 00:33:46,710
+It is the convergence
+
+316
+00:33:46,710 --> 00:33:54,990
+of
+
+317
+00:33:54,990 --> 00:34:03,470
+the following improper
+
+318
+00:34:03,470 --> 00:34:08,390
+integrals
+
+319
+00:34:15,050 --> 00:34:23,490
+أول تكامل تكامل من واحد إلى infinity لل E أس ناقص 
+
+320
+00:34:23,490 --> 00:34:28,910
+X تربيع DX نرجع
+
+321
+00:34:28,910 --> 00:34:34,060
+لكلام اللي إحنا كاتبينه هذا يبدأ في عندنا اختبارين
+
+322
+00:34:34,060 --> 00:34:39,840
+في عندنا اختبارين بدنا نتحدث عنهم في باقية هذا ال
+
+323
+00:34:39,840 --> 00:34:43,660
+section. الآن بس هنتحدث عن الاختبار الأول و المرة
+
+324
+00:34:43,660 --> 00:34:46,940
+جاهزة إن شاء الله بنتحدث عن الاختبار الثاني
+
+325
+00:34:46,940 --> 00:34:52,420
+.الاختبار الأول اللي هو barry comparison test اللي 
+
+326
+00:34:52,420 --> 00:34:58,840
+هو اختبار المقارنة المباشرة هذا الاختبار سنضطر له
+
+327
+00:34:58,840 --> 00:35:03,200
+إذا اتدلب نستطيع أن نتكامل هذا الصعب تكامله ممكن 
+
+328
+00:35:03,200 --> 00:35:08,220
+نستخدم هذا الاختبار للحكم على هذا التكامل هل هو
+
+329
+00:35:08,220 --> 00:35:14,320
+converge أو divet بقول لو أني دالتين F وG و الاثنتين
+
+330
+00:35:14,320 --> 00:35:18,480
+كانوا دوال متصلة على الفترة من A إلى Infinity
+
+331
+00:35:18,480 --> 00:35:26,080
+وكذلك الدالتين الاثنين موجبات بياخدوش إلى قيم موجبة
+
+332
+00:35:26,500 --> 00:35:32,420
+و الـ F أقل من الـ G دائما و أبدا على كل الفترة من
+
+333
+00:35:32,420 --> 00:35:38,140
+A إلى Infinity، إن حدث ذلك يبقى في عنده نقطتين،
+
+334
+00:35:38,140 --> 00:35:43,670
+النقطة الأولى، مين الكبيرة فيهم، F ولا G؟ إذا
+
+335
+00:35:43,670 --> 00:35:48,850
+التكامل على جي كان convert هو التكامل على حضرتها و 
+
+336
+00:35:48,850 --> 00:35:53,150
+مساحة، مساحة مقصورة بين المنحنى و محور X و ركز، إذا 
+
+337
+00:35:53,150 --> 00:35:57,970
+التكامل على الدالة الكبيرة convert، يعني حصرت مساحة 
+
+338
+00:35:57,970 --> 00:36:00,810
+محدودة، إذا التكامل على الدالة اللي أقل منها
+
+339
+00:36:00,810 --> 00:36:05,370
+convert من باب الأولى، المساحة بتبقى أقل. يبقى إذا
+
+340
+00:36:05,370 --> 00:36:11,550
+التكامل على الدالة الكبرى G of X can convert، إذا
+
+341
+00:36:11,550 --> 00:36:17,050
+التكامل على الدالة الصغرى convert، نمر اثنين، إذا
+
+342
+00:36:17,050 --> 00:36:21,750
+التكامل على الدالة الصغرى divers، لصغيرة المساحة
+
+343
+00:36:21,750 --> 00:36:25,550
+الكبيرة وصلت إلى ما لها نهاية، يبقى بصير التكامل على
+
+344
+00:36:25,550 --> 00:36:31,620
+الدالة الكبرى ما له divers هذا هو اختبار المقارنة،
+
+345
+00:36:31,620 --> 00:36:36,620
+الكتاب ذكر هذا الاختبار و بس، لكن بعض الكتب ذكرت
+
+346
+00:36:36,620 --> 00:36:42,380
+الاختبار نفسه بس بصورة أخرى على الفترة الأخرى تبعت 
+
+347
+00:36:42,380 --> 00:36:46,440
+الـ Improper Integration لكن الكتاب راح حط عليه
+
+348
+00:36:46,440 --> 00:36:50,020
+مسائل على ال remarkة، لأن كانت بالك ال remark مش
+
+349
+00:36:50,020 --> 00:36:53,260
+موجودة في الكتاب، لكن في مسائل عديدة في الكتاب
+
+350
+00:36:53,260 --> 00:36:59,210
+عليها مباشرة، تعال نشوف لو كان الدالة F وG دالة 
+
+351
+00:36:59,210 --> 00:37:04,010
+متصلة على الفترة من A إلى B و الـ F وG غير قابل
+
+352
+00:37:04,010 --> 00:37:09,150
+الاتصال وين عند X يساوي A وفي نفس الطريقة F of X
+
+353
+00:37:09,150 --> 00:37:13,530
+أقل من G of X و الاثنتين أكبر من الـ Zero of Them
+
+354
+00:37:14,110 --> 00:37:17,270
+والله إذا التكامل على الكبرى Converge، إذا التكامل
+
+355
+00:37:17,270 --> 00:37:21,250
+على الصغرى Converge، إذا التكامل على الصغرى
+
+356
+00:37:21,250 --> 00:37:26,850
+Diverge، إذا التكامل على الكبرى Diverge، من باب أو
+
+357
+00:37:26,850 --> 00:37:31,010
+لا. يبقى الاختبار هذا هو نفسه، بس الفرق هنا حدود
+
+358
+00:37:31,010 --> 00:37:34,710
+التكامل كانت لما لا نهاية، هنا الدالة المراد
+
+359
+00:37:34,710 --> 00:37:39,640
+تكاملها غير معرفة عند نقطة و هذه النقطة موجودة خلال
+
+360
+00:37:39,640 --> 00:37:44,700
+فترات التكامل يعني قصدنا من هذا الكلام أن ال
+
+361
+00:37:44,700 --> 00:37:48,160
+comparison test بنفعل ال improper integral of type
+
+362
+00:37:48,160 --> 00:37:55,620
+1 و of type 2 على الشكلين الملاحظة هذه بيقول ليه
+
+363
+00:37:55,620 --> 00:38:00,750
+ليس بالضرورة تبقى الفترة من A لB مفتوحة و مغلقة من
+
+364
+00:38:00,750 --> 00:38:04,770
+عند ال B ممكن مغلقة من عند ال A مفتوحة من ما ينطبق 
+
+365
+00:38:04,770 --> 00:38:08,670
+على و لا ينطبق على مين لحالة ثانية كما سنرى من
+
+366
+00:38:08,670 --> 00:38:15,610
+خلال الأمثلة بيقولي اختبرلي تقارب كل من التكاملات
+
+367
+00:38:15,610 --> 00:38:19,210
+التالية لما يقولي اختبر التقارب مش معناه أن
+
+368
+00:38:19,210 --> 00:38:25,520
+التكامل تقاربي قد يكون تقاربي وقد يكون تباعدي. لما
+
+369
+00:38:25,520 --> 00:38:28,860
+أقول لك test the conversion، اختبر التقارب، شوف لي
+
+370
+00:38:28,860 --> 00:38:33,280
+هل هو تقارب ولا ما هوش تقارب، يعني هل هو تقاربي
+
+371
+00:38:33,280 --> 00:38:37,400
+ولا تباعدي، بقول له ماشي. جالي تكامل واحد اللي
+
+372
+00:38:37,400 --> 00:38:42,020
+هو تكامل من واحد إلى Infinity لـ Sin X تربيع DX. حد فيكم يقدر يكمل 
+
+373
+00:38:42,020 --> 00:38:47,790
+الدالة هذه؟ إذا كنا نعرف إنه كامل، فنحكم إذا كنا 
+
+374
+00:38:47,790 --> 00:38:47,990
+نحكم إذا كنا نحكم إذا كنا نحكم إذا كنا نحكم إذا
+
+375
+00:38:47,990 --> 00:38:48,250
+كنا نحكم إذا كنا نحكم إذا كنا نحكم إذا كنا نحكم
+
+376
+00:38:48,250 --> 00:38:49,390
+إذا كنا نحكم إذا كنا نحكم إذا كنا نحكم إذا كنا
+
+377
+00:38:49,390 --> 00:38:50,330
+نحكم إذا كنا نحكم إذا كنا نحكم إذا كنا نحكم إذا
+
+378
+00:38:50,330 --> 00:38:51,430
+كنا نحكم إذا كنا نحكم إذا كنا نحكم إذا كنا نحكم
+
+379
+00:38:51,430 --> 00:38:54,610
+إذا كنا نحكم إذا كنا نحكم إذا كنا نحكم إذا كنا
+
+380
+00:38:54,610 --> 00:38:59,330
+نحكم إذا كنا نحكم إذا كنا نحكم إذا كنا نحكم إذا
+
+381
+00:38:59,330 --> 00:39:05,770
+كنا نحكم إذا كنا نحكم إذا كنا نحكم إذا كنا والدالة
+
+382
+00:39:05,770 --> 00:39:08,670
+اللي بيجي تقارن معاها بيكون معروفة إليك هل هي 
+
+383
+00:39:08,670 --> 00:39:14,310
+convergent ولا divergent بجي بسأل هذه عند الدالة
+
+384
+00:39:14,310 --> 00:39:20,050
+اللي هي E أس ناقص X تربيعا يعني واحد على E أس X
+
+385
+00:39:20,050 --> 00:39:26,170
+تربيعامن أقرب دالة عليها وشبيهة إيه بها؟ واحد عليها
+
+386
+00:39:26,170 --> 00:39:32,350
+والسكس. تمام تمام. يبقى هذه واحد عليها والسكس. طب
+
+387
+00:39:32,350 --> 00:39:37,670
+السؤال هل الدالة الأولى أصغر من الدالة الثانية؟
+
+388
+00:39:37,670 --> 00:39:42,370
+والله أكبر منها من عند الواحد لغاية ما نهاية.
+
+389
+00:39:43,710 --> 00:39:49,490
+الأولى أصغر لأن مقامها أكبر، كل ما يكبر المقام بيقل
+
+390
+00:39:49,490 --> 00:39:56,430
+الكسر، إذن الدالة هذه أقل من هذه دائما وأبدا وقد
+
+391
+00:39:56,430 --> 00:40:03,370
+يتساوى فقط عند الواحد، طبعا يبقى هذه أقل من أو 
+
+392
+00:40:03,370 --> 00:40:07,750
+تساوي الدالة اللي عندها، كويس؟ طيب إذن خلينا نشوف
+
+393
+00:40:07,750 --> 00:40:13,820
+التكامل على الدالة هذه، بيقولوا بعض، ولكن التكامل
+
+394
+00:40:13,820 --> 00:40:19,180
+من واحد إلى انفينيتي على واحد ده الـ e أس ناقص X يبقى
+
+395
+00:40:19,180 --> 00:40:25,200
+هذا الكلام يسوي ال limit تكامل من واحد إلى P لما
+
+396
+00:40:25,200 --> 00:40:31,740
+P بدها تروح إلى انفينيتي للـ e أس ناقص X يسوي ال limit
+
+397
+00:40:31,740 --> 00:40:36,230
+لما P tends to infinity تكامل الـ exponential بالـ
+
+398
+00:40:36,230 --> 00:40:42,450
+exponential نفسها مقسوم على سالب واحد على سالب
+
+399
+00:40:42,450 --> 00:40:47,690
+واحد والحكي هذا من وين؟ من واحد لغاية مين يبقى
+
+400
+00:40:47,690 --> 00:40:52,490
+هي السالب برا وهي ال limit لما P tends to
+
+401
+00:40:52,490 --> 00:40:58,270
+infinity وبدنا نعوض بالقيمة اللي فوق واحد على E
+
+402
+00:40:58,270 --> 00:41:06,490
+أس P ناقص واحد على E أس واحد لما بيبدأ تروح للمالانهاية
+
+403
+00:41:06,490 --> 00:41:12,030
+نهاية ال term هذا كله بروح لوين؟ للمالانهاية نهاية واحد
+
+404
+00:41:12,030 --> 00:41:16,630
+على المالانهاية في جداش ب zero بضل الجواب سالب
+
+405
+00:41:16,630 --> 00:41:21,170
+سالب واحد على ايه؟ يعني واحد على ايه؟ واللي هي
+
+406
+00:41:21,170 --> 00:41:27,420
+عمليا حوالي سبعة وتلاتين من مية يبقى صار التكامل
+
+407
+00:41:27,420 --> 00:41:33,480
+هذا converge ولا diverge؟ converge اللي أقل منه،
+
+408
+00:41:33,480 --> 00:41:38,720
+لأن هذه هي الكبيرة، الكبيرة converge، تكامل عليها،
+
+409
+00:41:38,720 --> 00:41:43,520
+يبقى التكامل على هذه الصغيرة converge من باب أولى
+
+410
+00:41:43,520 --> 00:41:48,760
+طبقا للنقطة الأولى من ال comparison test يبقى باجي
+
+411
+00:41:48,760 --> 00:41:54,740
+بقول هنا سا تكامل من واحد الى infinity ل e أس ناقص X
+
+412
+00:41:54,740 --> 00:42:01,100
+DX converge و بروح بقول هنا by the direct
+
+413
+00:42:01,100 --> 00:42:06,780
+comparison test التكامل من واحد الى infinity لل
+
+414
+00:42:06,780 --> 00:42:12,340
+e أس سالب X تربيع DX Converge وانتهينا منها. إذا
+
+415
+00:42:12,340 --> 00:42:17,840
+حكمنا على المسألة هل هي Converge أو Diverge بدون
+
+416
+00:42:17,840 --> 00:42:23,200
+أن نقوم بإجراء عملية التكامل. المرة القادمة إن شاء
+
+417
+00:42:23,200 --> 00:42:29,440
+الله مزيد من الأمثلة لغليك فعلا تفرط مخك ويصير فكر
+
+418
+00:42:29,440 --> 00:42:31,840
+كويس إن شاء الله تعالى. 
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/vAsKtHN5DoM_postprocess.srt b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/vAsKtHN5DoM_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f870da4a61c1469066d77dd1901c790631e75aad
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/vAsKtHN5DoM_postprocess.srt
@@ -0,0 +1,1836 @@
+1
+00:00:10,100 --> 00:00:15,190
+بسم الله الرحمن الرحيمنكمل مابتدأنا بيه بالمرة
+
+2
+00:00:15,190 --> 00:00:21,650
+الماضية وهو ال infinite sequences طبعا تعرضنا
+
+3
+00:00:21,650 --> 00:00:25,650
+لتعريف ال sequence ثم أخدنا أنواع مختلفة من ال
+
+4
+00:00:25,650 --> 00:00:29,630
+sequence تعرضنا لشكل increasing sequence and
+
+5
+00:00:29,630 --> 00:00:34,150
+decreasing sequenceواخدنا بعض ال limits سواء كان
+
+6
+00:00:34,150 --> 00:00:38,170
+sandwich theorem أو limits عادية وعرفنا ان ال
+
+7
+00:00:38,170 --> 00:00:42,370
+limits لل sequences مثل ال limits لل functions
+
+8
+00:00:42,370 --> 00:00:48,810
+تماما واخدنا على ذلك مثالالمثال كان نصه find a
+
+9
+00:00:48,810 --> 00:00:51,530
+formula for the nth term of the following
+
+10
+00:00:51,530 --> 00:00:56,450
+sequences يعني بدنا ما هو الشكل الحد النوني في ال
+
+11
+00:00:56,450 --> 00:01:00,470
+sequence و بعد ما نعرف هذا الشكل قال لي شوف ليهالي
+
+12
+00:01:00,470 --> 00:01:05,350
+ال sequence هذي converge و الله diverse و ابتدأنا
+
+13
+00:01:05,350 --> 00:01:10,610
+ناخد قد اتنقاطفاخدنا ثلاث نقاط وهي النقطة الرابعة
+
+14
+00:01:10,610 --> 00:01:16,570
+قدام ال sequence نص تلت اربع سبعة اتمان خمستاشر
+
+15
+00:01:16,570 --> 00:01:22,610
+عشان ستاشر و هكذا بدنا نعرف ما هو شكل الحد النوني
+
+16
+00:01:22,610 --> 00:01:27,510
+في ال sequence لذلك بدأ اجرب لك الفكرة و اخليك انت
+
+17
+00:01:27,510 --> 00:01:35,470
+تستنتج شكل الحد النونيالحد الأول هذا نص، نص جاي من
+
+18
+00:01:35,470 --> 00:01:40,890
+واحد ناقص نص، واحد ناقص نص باطن نص، هذا الشكل تلت
+
+19
+00:01:40,890 --> 00:01:47,850
+أربع، يعني واحد ناقص ربع، هذا سبعتمان، يعني واحد
+
+20
+00:01:47,850 --> 00:01:55,030
+ناقص تمن، هذا خمساش ع ستاش، يعني واحد ناقص واحد
+
+21
+00:01:55,030 --> 00:02:00,790
+على ستاشيبقى بدنا نعرف ما هو شكل الحد النوني في
+
+22
+00:02:00,790 --> 00:02:06,710
+هذه الحالة يبقى شكل الحد النوني اللي هو عبارة عن
+
+23
+00:02:06,710 --> 00:02:11,930
+واحد نقص أبصر قداش واحد
+
+24
+00:02:11,930 --> 00:02:17,950
+.. بدي واحد يحكي بس، حتى نتناقش احنا وياه ونوصل،
+
+25
+00:02:17,950 --> 00:02:23,800
+نشوف الأجابة صح ولا .. تفضلواحد على اتنين أس ان
+
+26
+00:02:23,800 --> 00:02:30,340
+يبقى واحد على اتنين أس ان سمات بعض الشباب من واحد
+
+27
+00:02:30,340 --> 00:02:34,560
+ناقص ان تربية توقف لقليل طبعا الكلام غير صحيح لكن
+
+28
+00:02:34,560 --> 00:02:40,120
+هذه هي الإجابة الدقيقة مائة بالمائةطلّع لي هنا، لو
+
+29
+00:02:40,120 --> 00:02:45,380
+كانت in بواحد، بصير واحد نقص نص بنص، لو كانت in
+
+30
+00:02:45,380 --> 00:02:50,160
+باتنين، بصير أربع، يبقى ربع، يبقى واحد نقص ربع
+
+31
+00:02:50,160 --> 00:02:55,220
+تلات تربع، لو كانت in بتلاتة، يبقى تمانية، يبقى
+
+32
+00:02:55,220 --> 00:03:00,420
+واحد نقص تمان، سبعة أتمان، وهكذا، إذن هذا هو الشكل
+
+33
+00:03:00,420 --> 00:03:06,760
+الحد النوني في ال sequence اللي عندنا هذهالان بدأت
+
+34
+00:03:06,760 --> 00:03:14,860
+ياخد ال limit لمن؟ ل 1 ناقص 1 على 2N لما ال N تنسى
+
+35
+00:03:14,860 --> 00:03:22,390
+infinityهذا يعطينا قداش zero يبقى قداش انا انا
+
+36
+00:03:22,390 --> 00:03:26,770
+واحد يبقى هذا يعطينا zero وبالتالي ال limit exist
+
+37
+00:03:26,770 --> 00:03:35,870
+يبقى sequence لي واحد نقص واحد على اتنين أس ان
+
+38
+00:03:35,870 --> 00:03:40,490
+convey وانتهينا منها المهم الحملة اتعرف على الشكل
+
+39
+00:03:40,490 --> 00:03:45,090
+في الأول ومن خلال الشكل بناخد ال limit اللي هنا
+
+40
+00:03:46,700 --> 00:03:54,800
+سؤال الخامس بيقول لي ناقص واحد اتنين ناقص ثلاثة
+
+41
+00:03:54,800 --> 00:03:58,660
+اربع ناقص خمسة و هكذا
+
+42
+00:04:01,600 --> 00:04:06,480
+بنعرف ما هو شكل الحد النوني في ال sequence يبقى
+
+43
+00:04:06,480 --> 00:04:12,400
+هذه sequence بقدر اكتبها على الشكل التالي لاحظ لو
+
+44
+00:04:12,400 --> 00:04:17,300
+ماعنديش سالب يبقى الحدود واحد اتنين تلاتة اربع
+
+45
+00:04:17,300 --> 00:04:22,700
+خمسة ستة الاخرين تمام؟ يبقى باجي بقوله هذا معناته
+
+46
+00:04:22,700 --> 00:04:30,370
+ان هذا لو ماعنديش سالبلما نقجل سالب خلالي حد موجب،
+
+47
+00:04:30,370 --> 00:04:40,170
+حد سالب، حد موجب، حد سالب، حد سالب، حد سالب، حد
+
+48
+00:04:40,170 --> 00:04:45,710
+سالب، حد سالب، حد سالب، حد سالب، حد سالب، حد سالب،
+
+49
+00:04:45,710 --> 00:04:46,530
+حد سالب، حد سالب، حد سالب، حد سالب، حد سالب، حد
+
+50
+00:04:46,530 --> 00:04:47,830
+سالب، حد سالب، حد سالب، حد سالب، حد سالب، حد سالب،
+
+51
+00:04:47,830 --> 00:04:54,250
+حد سالب، حد سالب، حد سالب، حد سالب، حد سالب، حد
+
+52
+00:04:54,250 --> 00:04:55,690
+سالب، حد سالب، حد سالب، حد سالب، حد سالب، حد سالب،
+
+53
+00:04:55,690 --> 00:04:59,630
+حد سالب، حإذا وجدت الإشارة مقلوبة بدل ما هو بادر
+
+54
+00:04:59,630 --> 00:05:05,050
+ناقص بدي يبدأ بزاد حط للأس هنا بس N زائد واحد
+
+55
+00:05:05,050 --> 00:05:10,090
+ابتنع الإشارة معاك وبصير شغلك صحية مائة بالمائة
+
+56
+00:05:10,090 --> 00:05:13,650
+يبقى فار شكل ال sequence فيها سالب واحد to the
+
+57
+00:05:13,650 --> 00:05:20,980
+power Nمقروبة من اين؟ فمقروبة في M. السؤال هو هدى
+
+58
+00:05:20,980 --> 00:05:26,260
+بنسميها oscillating sequence، مظبوط؟ لكن
+
+59
+00:05:26,260 --> 00:05:31,080
+oscillating رايحة لرقم و الله رايحة لرقمين مختلفين
+
+60
+00:05:32,170 --> 00:05:37,790
+طبعاً مش رقمين وإنما كل واحدة منهم رايحة لوين إلى
+
+61
+00:05:37,790 --> 00:05:42,690
+infinity واحدة ل infinity والتانية ل سالب infinity
+
+62
+00:05:42,690 --> 00:05:47,130
+يبقى ال limit exist ولا does not exist وبالتالي ال
+
+63
+00:05:47,130 --> 00:05:52,990
+sequence by then يبقى باجي بقوله هنا ال sequence
+
+64
+00:05:52,990 --> 00:06:00,070
+by then because it oscillated
+
+65
+00:06:02,100 --> 00:06:07,120
+between two
+
+66
+00:06:07,120 --> 00:06:13,780
+different limits
+
+67
+00:06:13,780 --> 00:06:17,320
+اللي
+
+68
+00:06:17,320 --> 00:06:24,740
+هما infinity and سالب infinityيبقى نظرا لأنها
+
+69
+00:06:24,740 --> 00:06:28,880
+تترجح ما بين الاتنين يبقى ال sequence does not
+
+70
+00:06:28,880 --> 00:06:32,000
+convert
+
+71
+00:06:32,000 --> 00:06:36,000
+يبقى ماجي بقوله هي ال sequence معاها converted
+
+72
+00:06:36,000 --> 00:06:46,180
+ننتقل الآن إلى مثال آخر بيقول ما يأتي example two
+
+73
+00:06:52,700 --> 00:07:06,340
+Find the limits of the following sequences
+
+74
+00:07:06,340 --> 00:07:09,640
+and determine
+
+75
+00:07:38,130 --> 00:07:45,970
+الحد النوني في ال sequenceاللي هو 2N زائد 1 على 1
+
+76
+00:07:45,970 --> 00:07:50,470
+ناقص 3 general N
+
+77
+00:07:53,810 --> 00:07:57,570
+قبل أن نحكم على هذه الـ sequence هل هي converge و
+
+78
+00:07:57,570 --> 00:08:03,050
+لا diverge بس قبل ذلك عليك تحسب ال limit لهذه ال
+
+79
+00:08:03,050 --> 00:08:09,510
+sequence إذا بدي أخد ال limit لل a n لما ال n
+
+80
+00:08:09,510 --> 00:08:13,970
+tends to infinity معناته limit لما ال n tends to
+
+81
+00:08:13,970 --> 00:08:23,840
+infinity لل 2n زائد 1 و 1 ناقص 3 جذر ال nالسؤال هو
+
+82
+00:08:23,840 --> 00:08:28,500
+احنا عندنا limit لما ال in بدها تروح لل infinity
+
+83
+00:08:29,420 --> 00:08:34,460
+نرجع لـ Calculus A، أخدنا الشغل هذه في Calculus A،
+
+84
+00:08:34,460 --> 00:08:39,820
+بمعنى بجب أطلع لدرجة البص والمقام، إذا درجة البص
+
+85
+00:08:39,820 --> 00:08:46,140
+أعلى من درجة المقام، يبقى النتيجة Infinity فقط، لا
+
+86
+00:08:46,140 --> 00:08:50,720
+غير، هذا إذا درجة البص أعلى من درجة المقام، إذا
+
+87
+00:08:50,720 --> 00:08:56,610
+درجة البص أقل من درجة المقام الناتج، Zeroإذا درجة
+
+88
+00:08:56,610 --> 00:09:01,890
+البس جت درجة المقام الناتج قيمة عددية ليست صفرا
+
+89
+00:09:01,890 --> 00:09:09,170
+وليست infinity تمام؟ يبقى هذا اسمه صمم أمان لحساب
+
+90
+00:09:09,170 --> 00:09:14,430
+ال limit ان طلع عندك غير هيك معناه حساباتك خطأ نجي
+
+91
+00:09:14,430 --> 00:09:20,820
+للمثل اللي عندى البس من الدرجةوالمقام اص نص مش
+
+92
+00:09:20,820 --> 00:09:25,000
+واحد صحيح اذا انظرية البص اكبر من انظرية المقام ده
+
+93
+00:09:25,000 --> 00:09:31,020
+للنتيجة بتبقى infinity طيب كويس مشان احسب هذه ال
+
+94
+00:09:31,020 --> 00:09:36,420
+limit عندي طريقين الطريق الاول ان اشتق البص على
+
+95
+00:09:36,420 --> 00:09:40,520
+المقام لان النتيجة infinity على infinity بقاعدة
+
+96
+00:09:40,520 --> 00:09:44,980
+lobitalأو أقسم كل من ال bus و المقام على إن
+
+97
+00:09:44,980 --> 00:09:49,460
+المرفوع عليه أكبر أُس في المقام أكبر أُس في المقام
+
+98
+00:09:49,460 --> 00:09:54,300
+اللي هو جدّاش انه أص مُص يبقى بقدر أقول هذا الكلام
+
+99
+00:09:54,300 --> 00:10:00,120
+بدي يساوي ال limit لما ال intensity infinity لمن؟
+
+100
+00:10:00,120 --> 00:10:03,220
+لإتنين
+
+101
+00:10:03,220 --> 00:10:10,740
+إتنين زي ما هيوهذا N أص نص وزيد واحد على N أص نص
+
+102
+00:10:10,740 --> 00:10:20,360
+على واحد على N أص نص ناقص تلاتة الان واحد على ماله
+
+103
+00:10:20,360 --> 00:10:25,540
+نهاية ب Zero واحد على ماله نهاية ب Zero طلع النتج
+
+104
+00:10:25,540 --> 00:10:31,940
+عندك هنا فوق بصير جداش Infinity على سالب تلاتة
+
+105
+00:10:31,940 --> 00:10:36,760
+يبقى النتيجة جداشسالب infinity معناته ال sequence
+
+106
+00:10:36,760 --> 00:10:44,140
+للحد النوني هذا تبعها تبقى معلها by V يبقى هنا the
+
+107
+00:10:44,140 --> 00:10:52,040
+sequence من ال N plus one واحد ناقص ثلاثة جذر ال N
+
+108
+00:10:52,040 --> 00:11:03,240
+by V سؤال ثانيبدنا شكل الحد النوني للـ sequence هو
+
+109
+00:11:03,240 --> 00:11:11,180
+اتنين ناقص واحد على الاتنين قص م في تلاتة زائد
+
+110
+00:11:11,180 --> 00:11:18,480
+واحد على اتنين قص مبنروح ناخد ال limit لهذا الحد
+
+111
+00:11:18,480 --> 00:11:24,120
+النوني يبقى ال limit لما ال N tends to infinity ل
+
+112
+00:11:24,120 --> 00:11:34,020
+2 ناقص 1 على 2 أس N في 3 زائد 1 على 2 أس N هذا
+
+113
+00:11:34,020 --> 00:11:38,060
+الكلام يساوي من خلاص ال limit اللي كتبناها المرة
+
+114
+00:11:38,060 --> 00:11:43,390
+الماضيةإن تعتبر limit للقوس الأول مضروبة في limit
+
+115
+00:11:43,390 --> 00:11:48,910
+للقوس الثاني يبجى هذه تعتبر limit لما ال N tends
+
+116
+00:11:48,910 --> 00:11:55,250
+to infinity لمين؟ لما ال N بدأ تروح لمعنى نهاية
+
+117
+00:11:55,250 --> 00:12:02,610
+لإتنين ناقص واحد على اتنين أس N في limit لما ال N
+
+118
+00:12:02,610 --> 00:12:10,510
+tends to infinityلتلاتة زائد واحد على اتنين أُس M
+
+119
+00:12:10,510 --> 00:12:16,670
+هذا الكلام بده يساوي طبعا هذه ب Zero وهذه ب Zero
+
+120
+00:12:16,670 --> 00:12:23,170
+بيبقى لي اتنين في تلاتة ويساوي ستة ليه قيمة عددية
+
+121
+00:12:23,170 --> 00:12:30,470
+So the sequence اللي هي من اتنين ناقص واحد على
+
+122
+00:12:30,470 --> 00:12:39,030
+اتنين أُس M فيأتنين في تلاتة زائد واحد على اتنين
+
+123
+00:12:39,030 --> 00:12:44,410
+اص ان معناها converge وبالتالي حكمنا على ال series
+
+124
+00:12:44,410 --> 00:12:49,270
+converge او diverge من خلال ال limit اللي عندنا
+
+125
+00:12:49,270 --> 00:12:58,590
+سؤال الثالث بيقول لان يسوى لن الان ماقص لن الان
+
+126
+00:12:58,590 --> 00:13:04,430
+زائد واحدبنشوف ان ال sequence هذي converge ولا
+
+127
+00:13:04,430 --> 00:13:10,290
+divary بس بعد اش ما نحسب اللي هال limit يبقى limit
+
+128
+00:13:10,290 --> 00:13:16,970
+لما ال N tends to infinity لإن ال N ناقص لإن ال N
+
+129
+00:13:16,970 --> 00:13:24,400
+زائد واحدتعويض المباشر بيعطيني infinity ناقص
+
+130
+00:13:24,400 --> 00:13:29,560
+infinity يبقى ماجرش أعمل ولا حاجة إلا أحولها إلى
+
+131
+00:13:29,560 --> 00:13:34,880
+صيغة zero على zero أو infinity على infinity يبقى
+
+132
+00:13:34,880 --> 00:13:39,180
+هذا الكلام بده يسوي ال limit لما ال in tends to
+
+133
+00:13:39,180 --> 00:13:46,880
+infinity للمطبعاً لن ناقص لن تعني لن خارج القسمة
+
+134
+00:13:46,880 --> 00:13:54,800
+يبقى بيصير N على N زائد واحد ال limit لن معاه
+
+135
+00:13:54,800 --> 00:14:01,360
+صلاحيات تدخل داخل لن يبقى limit لما ال N tends to
+
+136
+00:14:01,360 --> 00:14:09,080
+infinity لل N على N زائد واحد يبقى يساوي لنالان
+
+137
+00:14:09,080 --> 00:14:13,380
+هذه بتعطيني infinity على infinity ممكن نستخدم
+
+138
+00:14:13,380 --> 00:14:18,520
+قاعدة logital يبقى مشتقة ال bus على مشتقة المقام
+
+139
+00:14:18,520 --> 00:14:24,380
+بواحد على واحد يبقى لإن واحد اللي هو قداش zero
+
+140
+00:14:24,380 --> 00:14:33,090
+يبقى بناء عليه بقول so the sequence لإن ال Mنقص
+
+141
+00:14:33,090 --> 00:14:38,870
+لإن ال N زائد واحد هذه مالها convert
+
+142
+00:15:05,600 --> 00:15:10,420
+سؤال الرابع بيقول
+
+143
+00:15:10,420 --> 00:15:22,160
+لي ان ال A N تساوي 1 على جذر ال N في Tan inverse N
+
+144
+00:15:23,470 --> 00:15:28,430
+يجب أن نذهب و نأخذ الـ Limit لما الـ N بدها تذهب
+
+145
+00:15:28,430 --> 00:15:36,450
+إلى المالة نهائيا لمن؟ لواحد على جذر الـ N لتان
+
+146
+00:15:36,450 --> 00:15:43,650
+Inverse N لو جينا نعوض تعوض مباشر بصير هنا واحد
+
+147
+00:15:43,650 --> 00:15:45,970
+على Infinity
+
+148
+00:15:48,310 --> 00:15:54,490
+زيرو طيب هنا ten inverse infinity التان لما الان
+
+149
+00:15:54,490 --> 00:15:59,690
+بتروح للملعك ده شو يساوي؟ باي على اتنين يبقى
+
+150
+00:15:59,690 --> 00:16:07,150
+الناتج يساوي قدرش؟ Zero يبقى هنا the sequence اللي
+
+151
+00:16:07,150 --> 00:16:15,490
+هي واحد على جدر الان تان inverse ان convert السؤال
+
+152
+00:16:15,490 --> 00:16:16,250
+الخامس
+
+153
+00:16:19,270 --> 00:16:29,890
+سؤال الخامس بيقول ان يساوي لن الان على لن اتنين ان
+
+154
+00:16:32,550 --> 00:16:38,090
+بارضه بنفس الطريقة بنروح ناخد limit لما ال N tends
+
+155
+00:16:38,090 --> 00:16:45,470
+to infinity لإن ال N على لين اتنين N التعويض
+
+156
+00:16:45,470 --> 00:16:50,950
+المباشر لو جيت حسبت له limit بيعطيني جداش infinity
+
+157
+00:16:50,950 --> 00:16:57,430
+على infinity بقدر استخدم قاعدة Lobital مباشرةيبقى
+
+158
+00:16:57,430 --> 00:17:03,050
+لو جيت استخدم قاعدة لبتال بيصير واحد على ان واحد
+
+159
+00:17:03,050 --> 00:17:09,970
+على اتنين ان ضرب اتنينأظن اتنين مع اتنين بتروح بظل
+
+160
+00:17:09,970 --> 00:17:15,710
+كدهش واحد على ان على واحد على ان اللي هو بقدهش
+
+161
+00:17:15,710 --> 00:17:26,870
+واحد صحيح يبقى هنا sequence لن ال n على لن اتنين
+
+162
+00:17:26,870 --> 00:17:32,270
+ال convert السؤال السادس
+
+163
+00:17:36,880 --> 00:17:44,240
+الثالث سادس بيقول الشكل الحد النوني AN بيساوي N في
+
+164
+00:17:44,240 --> 00:17:48,800
+واحد ناقص cosine واحد على M
+
+165
+00:17:51,780 --> 00:17:56,980
+يبقى لو جينا أخدنا ال limit لهذا الحد يبقى limit
+
+166
+00:17:56,980 --> 00:18:03,400
+لما ال N tends to infinity ل N واحد ناقص cosine
+
+167
+00:18:03,400 --> 00:18:08,680
+واحد على N لو جينا عوضنا التعويض مباشر يبقى هذا
+
+168
+00:18:08,680 --> 00:18:15,300
+بيعطيني infinity P1 على infinity ب zero كصير سكر
+
+169
+00:18:15,300 --> 00:18:21,800
+بواحد واحد ناقص واحد يساوي جداش يساوي zero يبقى
+
+170
+00:18:21,800 --> 00:18:27,680
+بناء عليه بنستخدم قاعدة Lobital بعد ما نحول هذه
+
+171
+00:18:27,680 --> 00:18:33,280
+المسألة إلى صيغة zero على zero او infinity على
+
+172
+00:18:33,280 --> 00:18:39,170
+infinity يبقى هذه بدها تساوي ال limitلما الـ N
+
+173
+00:18:39,170 --> 00:18:44,590
+tends to infinity لواحد ناقص cosine واحد على N
+
+174
+00:18:44,590 --> 00:18:50,910
+وهذه نعمل لها قبل هيك اليمين اللي هي واحد على N
+
+175
+00:19:10,570 --> 00:19:16,150
+لو جينا عوامة تعويض مباشر بيعطيني هذا جباش 0 على 0
+
+176
+00:19:16,150 --> 00:19:22,190
+إذا بقدر استخدم قاعدة Lobital مباشرة يبقى limit
+
+177
+00:19:22,190 --> 00:19:28,600
+لما ال N بده تروح لل infinity ب sign 1 على Nفى
+
+178
+00:19:28,600 --> 00:19:33,940
+مشتقة الزاوية اللى هو سالب واحد على ان تربيع على
+
+179
+00:19:33,940 --> 00:19:39,200
+مشتقة المقام اللى هو سالب واحد على ان تربيع طبعا
+
+180
+00:19:39,200 --> 00:19:43,580
+هذا مع هذا بيروح بظل واحد على ماله نهاية ب zero
+
+181
+00:19:43,580 --> 00:19:48,560
+sign ال zero اللى هو جداش ب zero معناه ال sequence
+
+182
+00:19:48,560 --> 00:19:56,800
+هذه معلهاconvert the sequence اللي هي n في واحد
+
+183
+00:19:56,800 --> 00:20:07,520
+ناقص cosine واحد على n convert خد سؤال السابع مثال
+
+184
+00:20:07,520 --> 00:20:16,500
+السابع بيقول مات ال a n يساوي ال n ناقص الجدري
+
+185
+00:20:16,500 --> 00:20:21,160
+التربيعيلإن تربية ناقص واحدة
+
+186
+00:20:34,790 --> 00:20:41,610
+نضرب في المراتب، ماشي يبقى هذا الكلام limit لما ال
+
+187
+00:20:41,610 --> 00:20:43,550
+N tends to infinity
+
+188
+00:21:04,880 --> 00:21:10,190
+يساوي ال limit لما ال intense to infinityالـ Bus
+
+189
+00:21:10,190 --> 00:21:15,930
+هو تحليل فرق بين المربعين، بدّى رجعه إلى أصله،
+
+190
+00:21:15,930 --> 00:21:24,130
+يبقى مربع الكمية الأولى ناقص مربع الكمية الثانية،
+
+191
+00:21:24,130 --> 00:21:30,810
+اللي هو هيطير الجدر كله على المقام N زائد الجدر
+
+192
+00:21:30,810 --> 00:21:37,940
+التربيعي، لإن تربيع ناقص واحدهذه لو فكتها هيروح
+
+193
+00:21:37,940 --> 00:21:43,240
+سلب M تربيع مع M تربيع بظل واحد بالموجب يبقى هذا
+
+194
+00:21:43,240 --> 00:21:48,460
+الكلام limit لما ال M tends to infinity واحد
+
+195
+00:21:48,460 --> 00:21:56,940
+بالموجب على M زائد M تربيع ناقص واحدلما الان بدها
+
+196
+00:21:56,940 --> 00:22:02,320
+تروح ل infinity بيصير واحد infinity زائد infinity
+
+197
+00:22:02,320 --> 00:22:06,340
+infinity عدد على infinity
+
+198
+00:22:27,950 --> 00:22:35,840
+السؤال السابعتامن؟ آية تامن ولا يهمك آية تامن
+
+199
+00:22:35,840 --> 00:22:43,540
+بيقول الحد إنوني يساوي ال sign تربيع ال N على
+
+200
+00:22:43,540 --> 00:22:51,480
+الإتنين قص M لو
+
+201
+00:22:51,480 --> 00:22:55,380
+بدى أخد ال limit هو دي تعوض مباشر يبقى infinity
+
+202
+00:22:55,380 --> 00:22:58,820
+على infinity لإن ال sign عند ال N أنا بعرفوش هذا
+
+203
+00:22:58,820 --> 00:22:59,840
+تمام؟
+
+204
+00:23:15,750 --> 00:23:20,570
+نفكر في الموضوع بطريقة أخرى خدنا المرة اللى فاتت
+
+205
+00:23:20,570 --> 00:23:25,740
+sandwich theoremإذا ممكن أحل المسألة باستخدام
+
+206
+00:23:25,740 --> 00:23:30,000
+sandwich theorem كيف نطرح السؤال التالي
+
+207
+00:23:34,410 --> 00:23:42,110
+سالب واحد و واحد طب sign تربيه
+
+208
+00:23:42,110 --> 00:23:46,970
+ال in دائما
+
+209
+00:23:46,970 --> 00:23:52,130
+و أبدا أكبر من أو يسوى zero أقل من أو يسوى من
+
+210
+00:23:52,130 --> 00:23:58,170
+الواحد طب واحد على اتنين in عمره بياخد قيمة سالبة؟
+
+211
+00:23:58,540 --> 00:24:03,420
+لأ يبقى لو ضربته في الinquality لا يتغير وقع
+
+212
+00:24:03,420 --> 00:24:11,040
+الinquality يبقى 1 على 2 M في 0 ب0 أقل من sin
+
+213
+00:24:11,040 --> 00:24:20,180
+تربيع ال N على 2 أُس M أقل من 1 على 2 أُس Mخُد ال
+
+214
+00:24:20,180 --> 00:24:24,840
+limit للثلاثة أطرات limit ال constant بال constant
+
+215
+00:24:24,840 --> 00:24:30,340
+itself وهذا limit لما ال N tends to infinity لsin
+
+216
+00:24:30,340 --> 00:24:37,280
+تربيع ال N على ال 2 أُس M وهذا limit لما ال N
+
+217
+00:24:37,280 --> 00:24:43,940
+tends to infinity ل1 على ال 2 أُس Mطيب هذا باعتبار
+
+218
+00:24:43,940 --> 00:24:48,680
+واحد على مالة نهاية بقداش صار limit ال sequence
+
+219
+00:24:48,680 --> 00:24:53,260
+الأولى ب zero والأخيرة ب zero ال sandwich theorem
+
+220
+00:24:53,260 --> 00:24:58,120
+ال limit اللى فى النص بقداش فبقى اجيب اقوله هنا by
+
+221
+00:24:58,120 --> 00:25:06,440
+sandwich theorem ال
+
+222
+00:25:06,440 --> 00:25:12,240
+limitلما ال N tends to infinity لصين تربيع ال N
+
+223
+00:25:12,240 --> 00:25:19,180
+على ال 2 أُس N بدّي نسمع كده؟ Zero مدام Zero saw
+
+224
+00:25:19,180 --> 00:25:27,200
+the sequence اللي هو صين تربيع ال N على ال 2 أُس N
+
+225
+00:25:27,200 --> 00:25:35,300
+مالها converge سؤال التاسع التاسع
+
+226
+00:25:35,960 --> 00:25:45,360
+بيقول لي الحد النوني AN بدي ساوي N factorial على N
+
+227
+00:25:45,360 --> 00:25:49,940
+to the power N بدنا نشوف هل ال sequence هذي
+
+228
+00:25:49,940 --> 00:25:58,840
+converge ولا diverge فكرلي في الموضوع كويس واطلع
+
+229
+00:25:58,840 --> 00:26:04,140
+فيها كويس كيف بدنا نبدأ كيف بدنا ننتهي الله أعلم
+
+230
+00:26:05,420 --> 00:26:09,320
+طبعا المثال السابق كان اول مثال على sandwich
+
+231
+00:26:09,320 --> 00:26:15,620
+theorem ممكن تفكر بنفس الطريقة و نشوف ان هذا هل
+
+232
+00:26:15,620 --> 00:26:19,020
+بنحل على sandwich theorem و الله لا يحل على
+
+233
+00:26:19,020 --> 00:26:25,520
+sandwich theorem بدنا نروح ناخد ال limit لمن؟ لما
+
+234
+00:26:25,520 --> 00:26:32,000
+ال N tends to infinity لل N factorial على N to the
+
+235
+00:26:32,000 --> 00:26:33,180
+power N
+
+236
+00:26:37,100 --> 00:26:41,760
+بشكل غريب مضغوب ال infinity بعرفوش و infinity و
+
+237
+00:26:41,760 --> 00:26:46,240
+infinity هذه بعرفاش كمان لكن بسيطة الشغل في ديك
+
+238
+00:26:46,240 --> 00:26:51,020
+فكر و شوف ايش بالساوي يبقى هذا الكلام بده يساوي ال
+
+239
+00:26:51,020 --> 00:26:56,580
+limit لما ال n tends to infinity كدهش الأربعة
+
+240
+00:26:56,580 --> 00:27:02,620
+factorial يا شباب؟أربعة في تلاتة في اتنين في واحد
+
+241
+00:27:02,620 --> 00:27:08,700
+يبقى N factorial هي N في النقص واحد في النقص اتنين
+
+242
+00:27:08,700 --> 00:27:13,500
+ويبقى لك ماشي لغاية تلاتة في اتنين في واحد مظبوط؟
+
+243
+00:27:13,500 --> 00:27:19,700
+إذا بدي أكتبه بدلالة المفكوك يبقى هذا N في النقص
+
+244
+00:27:19,700 --> 00:27:27,200
+واحد في النقص اتنين في تلاتة في اتنين في واحدتمام
+
+245
+00:27:27,200 --> 00:27:34,680
+تمام طيب N أُس N تعني N مضروبة في نفسها كام مرة N
+
+246
+00:27:34,680 --> 00:27:42,940
+من المرات تمام يجي هذه عبارة عن N في N في N في N
+
+247
+00:27:42,940 --> 00:27:49,420
+في N في N في N طيب اللي تحت عرفنا انهم N من المرات
+
+248
+00:27:49,420 --> 00:27:52,780
+طيب اللي فوق N نقص واحد متأكد
+
+249
+00:27:55,530 --> 00:28:00,990
+إن من المرات كذلك زيها، اي واحد، اتنين، تلاتة،
+
+250
+00:28:00,990 --> 00:28:06,690
+اربع، خمسة، ستة، إن من المرات، يبقى هذا كله in
+
+251
+00:28:06,690 --> 00:28:14,130
+times سواء كان البص ولا المقام هو إن من المراتطب
+
+252
+00:28:14,130 --> 00:28:18,870
+ايش رايك؟ خلينا نسيب هدا ع الشجة و بنرجع لبعد قليل
+
+253
+00:28:18,870 --> 00:28:23,990
+و تعالى تفهموا ع الشجة هيك شوية الان لما نقعد ياخد
+
+254
+00:28:23,990 --> 00:28:29,770
+ال N في N ناقص واحد في N ناقص اتنين في تلاتة في
+
+255
+00:28:29,770 --> 00:28:40,120
+اتنين في واحد على N في N في N في N في N في Nهل يا
+
+256
+00:28:40,120 --> 00:28:46,580
+ترى هذا المقدار بينزل عن الصفر أو بيسوي صفر؟ لا
+
+257
+00:28:46,580 --> 00:28:53,320
+يمكن يبقى هذا دائما و أبدا قيمة مجبة أكبر من الصفر
+
+258
+00:28:53,320 --> 00:29:00,700
+تمام؟ طيب خدلي ال term هذا هيك اللي حطيته أنا في
+
+259
+00:29:00,700 --> 00:29:05,340
+مستاطيل بزيد
+
+260
+00:29:05,340 --> 00:29:07,240
+عن الواحد الصحيح؟
+
+261
+00:29:09,830 --> 00:29:15,110
+اه اجرب لك الفكرة اختصرنا واحدة مع واحدة بصير ايه
+
+262
+00:29:15,110 --> 00:29:18,570
+الناقص واحد علي ان النقص اتنين علي ان النقص عمره
+
+263
+00:29:18,570 --> 00:29:25,650
+بيزيد عن واحد صحيح يعني دائما وأبدا اقل من واحد
+
+264
+00:29:25,650 --> 00:29:33,490
+صحيح في واحد علي ان بظبط هذا اللي هو متساوي مين
+
+265
+00:29:33,490 --> 00:29:41,040
+واحد علي ان طب خدلي ال limit لثلاثة اقرابأذا limit
+
+266
+00:29:41,040 --> 00:29:46,020
+الـ zero بالـ zero itself يبقى هي الـ zero و أقل
+
+267
+00:29:46,020 --> 00:29:52,160
+من limit لما ال N tends to infinity لل N في N ناقص
+
+268
+00:29:52,160 --> 00:30:00,300
+واحد في N ناقص اتنين في تلاتة في اتنين في واحد على
+
+269
+00:30:00,300 --> 00:30:09,910
+N في N في Nفى N فى N فى N وهذا أقل من limit لما ال
+
+270
+00:30:09,910 --> 00:30:13,410
+N tends to infinity ل 1 على N
+
+271
+00:30:25,350 --> 00:30:30,590
+ولا .. ولا في البص .. مين اللي أجل؟ إيه ناقص واحد
+
+272
+00:30:30,590 --> 00:30:38,130
+ولا إيه؟ ناقص واحد أقل؟ جيب جهادة كثر لحاله، أقل
+
+273
+00:30:38,130 --> 00:30:42,810
+من الواحد الصحيح ولا أكبر؟ أقل، طب و اللي بعده؟أقل
+
+274
+00:30:42,810 --> 00:30:49,010
+و اللي بعده؟ كله أقل من واحد صحيح، مظبوط؟ يبقى كل
+
+275
+00:30:49,010 --> 00:30:54,530
+هذا الكثير بيصير أقل من واحد صحيح ضرب واحد علينا
+
+276
+00:30:54,530 --> 00:31:00,400
+اللي ضال تانها دي، مظبوط هيك؟بسويه، بقولك أجال
+
+277
+00:31:00,400 --> 00:31:04,520
+منه، بقول لي بيسويه، لا يتثوى إلا الرقم الأول مع
+
+278
+00:31:04,520 --> 00:31:10,320
+الرقم الأول، ما خل ذلك كل كثير أقل من الواحد
+
+279
+00:31:10,320 --> 00:31:16,660
+الصحيح، تمام؟ إذا هذا كله حاصل ضربه دائما وأبدا
+
+280
+00:31:16,660 --> 00:31:22,020
+أجال من واحد صحيح، تمام؟ أجال من واحد صحيح ثمين،
+
+281
+00:31:22,020 --> 00:31:26,350
+واحد على إن اللي قد يساوي واحد عليهبتاخد ال limit
+
+282
+00:31:26,350 --> 00:31:32,070
+للثلاثة أطراف لما ال N tends to infinity هذه ال
+
+283
+00:31:32,070 --> 00:31:36,790
+limit إيها بقدرش؟ Zero طيب سعر ال limit هذه محصورة
+
+284
+00:31:36,790 --> 00:31:41,230
+بين Zero و Zero لإن ال limit هذه ما لها أكبر من ال
+
+285
+00:31:41,230 --> 00:31:44,450
+Zero أو أقل من ال Zero، مافيش إمكانية إلا تسوى
+
+286
+00:31:44,450 --> 00:31:54,130
+مين؟ Zero، طب عاجب أقولهم، By sandwich theoremالـ
+
+287
+00:31:54,130 --> 00:31:59,210
+limit لما ال N tends to infinity لل N factorial
+
+288
+00:31:59,210 --> 00:32:04,810
+على N to the power N بديه يسوي ال limit لما ال N
+
+289
+00:32:04,810 --> 00:32:11,110
+tends to infinity لل N في N نقص واحد في N نقص
+
+290
+00:32:11,110 --> 00:32:18,170
+اتنين في تلاتة في اتنين في واحد على N في N في N في
+
+291
+00:32:18,170 --> 00:32:25,530
+N بديه يسوي جداشزيرو مادام زيرو يبقى هنا ساعة the
+
+292
+00:32:25,530 --> 00:32:32,810
+sequence اللي هي مين ال N factorial على N to the
+
+293
+00:32:32,810 --> 00:32:39,130
+power N convert يبقى هنا يحط هناك بدل المثال اتنين
+
+294
+00:32:39,130 --> 00:32:44,950
+على مين على ال sandwich third الآن بنيجي لنقطة
+
+295
+00:32:44,950 --> 00:32:46,850
+very important
+
+296
+00:32:50,050 --> 00:32:53,590
+النقطة بتقول المادة دي هحطها لك في صيغة ال remark
+
+297
+00:32:53,590 --> 00:32:59,310
+التالية remark if
+
+298
+00:32:59,310 --> 00:33:12,790
+ال sequence a n is converge or diverge sequence
+
+299
+00:33:12,790 --> 00:33:32,220
+then ال c في ال a nهو convergent او divergent ثم
+
+300
+00:33:32,220 --> 00:33:41,940
+هو convergent او divergent سيقونس حيث ان C هو
+
+301
+00:33:41,940 --> 00:33:45,620
+مستوى غير صحيح
+
+302
+00:34:16,890 --> 00:34:23,960
+عند سيكوانسو ال sequence كانت هذه converge ضربتها
+
+303
+00:34:23,960 --> 00:34:28,820
+في constant لا يساوي ال zero ظهرت sequence جديدة
+
+304
+00:34:28,820 --> 00:34:32,040
+يبقى ال sequence هذه مالها converge إذا ال
+
+305
+00:34:32,040 --> 00:34:36,360
+sequence هذه كانت diverge و ضربتها في constant
+
+306
+00:34:36,360 --> 00:34:40,660
+تظهر sequence جديدة هذه ال sequence مالها بالبلد
+
+307
+00:34:40,660 --> 00:34:45,260
+هيك ضرب ال sequence في constant لا يؤثر على ال
+
+308
+00:34:45,260 --> 00:34:49,340
+convergence ولا على ال divergence لهذه ال sequence
+
+309
+00:34:49,850 --> 00:34:55,190
+يبقى من الآن فصاعدا ضرب ال sequence فيه كنصا يعني
+
+310
+00:34:55,190 --> 00:34:58,970
+معناته بده يضرب فيه كل حد من حدود ال sequence لا
+
+311
+00:34:58,970 --> 00:35:02,550
+يؤثر على ال convergence ولا يؤثر على ال divergence
+
+312
+00:35:02,550 --> 00:35:09,720
+لهذه ال sequence خلال دراستنافي باقية الشبطر هذا
+
+313
+00:35:09,720 --> 00:35:12,500
+مش باقية ال section باقية ال section و باقية
+
+314
+00:35:12,500 --> 00:35:17,860
+الشبطر كله فى عندنا ال limits بتتكرر معانا كثيرا
+
+315
+00:35:17,860 --> 00:35:22,460
+جدا مش كل مرة بدنا نخليك تقعد تقعد تحسبهم لأ بدنا
+
+316
+00:35:22,460 --> 00:35:28,320
+نحطهم كقاعدة و القاعدة نستخدمها متى لازم الأمر ست
+
+317
+00:35:28,320 --> 00:35:33,680
+limits مشهورة من حد ما شوفها بتحكمتها حسب
+
+318
+00:35:42,960 --> 00:35:54,920
+بعض النهايات الأساسية نمر واحد limit لإن ال N على
+
+319
+00:35:54,920 --> 00:36:00,220
+N لما ال N tends to infinity بده يساوي جباش بده
+
+320
+00:36:00,220 --> 00:36:06,360
+يساوي Zero نمر اتنينlimit لما ال N tends to
+
+321
+00:36:06,360 --> 00:36:14,220
+infinity للجذر النوني ل N يعني limit لما ال N
+
+322
+00:36:14,220 --> 00:36:20,720
+tends to infinity لل N أص واحد على N يسوى واحد
+
+323
+00:36:20,720 --> 00:36:29,840
+صحيح نمر تلاتة limitلما الـ N tends to infinity لل
+
+324
+00:36:29,840 --> 00:36:37,300
+X أُس واحد على N بيكون واحد صحيح و X greater than
+
+325
+00:36:37,300 --> 00:36:46,240
+zero لمرة أربعة بدنا limit لل X أُس N لما ال N
+
+326
+00:36:46,240 --> 00:36:53,070
+tends to infinity بيكون زيروإذا كان الـ absolute
+
+327
+00:36:53,070 --> 00:36:57,250
+value للـ X أقل من الواحد
+
+328
+00:37:00,290 --> 00:37:08,170
+limit لما ال N tends to infinity لمن؟ ل 1 زائد X
+
+329
+00:37:08,170 --> 00:37:19,530
+على N كل هذا to the power N بده يساوي إيقص X وهنا
+
+330
+00:37:19,530 --> 00:37:31,180
+أنا X لقي X نمرى ستةنمره ستة limit لما ال N بدها
+
+331
+00:37:31,180 --> 00:37:37,440
+تروح لل infinity لل X to the power N على N
+
+332
+00:37:37,440 --> 00:37:44,580
+factorial بده يساوي Zero وكمان هذه معلها Any X
+
+333
+00:37:58,070 --> 00:38:06,610
+الاربع هدول كلهم هذه مع هذه ال X هذا دائما ورا
+
+334
+00:38:06,610 --> 00:38:17,030
+أبدا عبارة عن رقم ثابت يبقى fixed يبقى from تلاتة
+
+335
+00:38:17,030 --> 00:38:23,830
+to ستة ال X is fixed
+
+336
+00:38:25,900 --> 00:38:33,000
+يبقى ال X عبارة عن رقم ثابت ال
+
+337
+00:38:33,000 --> 00:38:38,940
+limits
+
+338
+00:38:38,940 --> 00:38:43,740
+الستة هنستخدمهم خلال هذا ال section وخلال ال
+
+339
+00:38:43,740 --> 00:38:48,780
+sections القادمة حتى نهاية هذا الشبطة وإن بتلزم أي
+
+340
+00:38:48,780 --> 00:38:51,620
+واحدة من الستة هدول بنحط قيمتها
+
+341
+00:39:01,400 --> 00:39:06,980
+طبعا نطلع لكل واحدة من هذه ال limits على حدة لو
+
+342
+00:39:06,980 --> 00:39:11,000
+جينا لل limit الأولى بيقول ال limit لإن ال N على N
+
+343
+00:39:11,000 --> 00:39:15,680
+لما ال N بتروح لما لنهاية بده تساوي Zero لو جينا
+
+344
+00:39:15,680 --> 00:39:20,450
+عوابنا التعويض مباشر يبقى الباستما لا رهاية
+
+345
+00:39:20,450 --> 00:39:24,890
+والمقام بما لا نهاية إذا بنقدر نستخدم قاعدة لبتر
+
+346
+00:39:24,890 --> 00:39:29,930
+تفاضل بص بواحد على أنه تفاضل مقام بواحد يبقى start
+
+347
+00:39:29,930 --> 00:39:33,830
+limit لما ال N بتروح لما لا واحد على N يبقى واحد
+
+348
+00:39:33,830 --> 00:39:37,630
+على ما لا نهاية زي غير يبقى انتهينا منها مباشرة
+
+349
+00:39:37,990 --> 00:39:43,650
+اللي بعده limit التانية N أس واحد على N لو جينا
+
+350
+00:39:43,650 --> 00:39:48,230
+عوضنا التعويض مباشر بصير مالة نهاية أس إذا بدنا
+
+351
+00:39:48,230 --> 00:39:52,870
+نروح نعمل الأربع خطوات لو تعمل الأربع خطوات من
+
+352
+00:39:52,870 --> 00:39:57,630
+الخطوة الثانية automatic لو بدك تيجي تاخد ال N
+
+353
+00:39:57,630 --> 00:40:03,590
+للطرف N بصير واحد على N في لن ال N يعني لن ال N
+
+354
+00:40:03,590 --> 00:40:09,650
+على N لما تاخد ال limit بطلع جديشزيرو من هايها، من
+
+355
+00:40:09,650 --> 00:40:15,110
+الأولى، الأولى بطلع زيرو، يبقى E أزيرو بواحد اللي
+
+356
+00:40:15,110 --> 00:40:19,310
+هو الخطوة الأخيرة، مدام ال E أزيرو اللي هو بواحد
+
+357
+00:40:19,310 --> 00:40:25,210
+صحيح، يبقى في
+
+358
+00:40:25,210 --> 00:40:30,530
+هذه الحالة بصير E المتساوي واحد صحيح
+
+359
+00:40:33,120 --> 00:40:38,140
+الثالثة حالة خاصة من الاولى بدل ان اللى تحت صار
+
+360
+00:40:38,140 --> 00:40:44,220
+ماله صار fixed تمام يبقى صار fixed عندنا وبالتالي
+
+361
+00:40:44,220 --> 00:40:48,740
+انتهينا منها لو جينا للنقطة الرابعة limit لما ال X
+
+362
+00:40:48,740 --> 00:40:54,820
+ذوقتهاكسوس ان لما الان بدها تروح لما لا نهاية هذه
+
+363
+00:40:54,820 --> 00:41:00,140
+احد امرين يابدها تساوي zero يابدها تساوي ما لها ما
+
+364
+00:41:00,140 --> 00:41:06,180
+لا نهاية كيف كله بيعتمد على شكل ال X إذا والله X
+
+365
+00:41:06,180 --> 00:41:11,900
+كثر محصور بين واحد و سالب واحد يعني كثر اقل من
+
+366
+00:41:11,900 --> 00:41:16,040
+الواحد الصحيح الكثر اقل من واحد لما تربع او تكعبه
+
+367
+00:41:16,040 --> 00:41:20,670
+بزيد ولا بينقص؟يبقى رايح لوين؟ لزينه لكن لو كان
+
+368
+00:41:20,670 --> 00:41:25,710
+أكبر من الواحد الصحيح بتلاقيه بزيد يعني مثلا تلاتة
+
+369
+00:41:25,710 --> 00:41:29,770
+على اتنين واحد و نصف لو ربعناها بتصير جدا تسعة على
+
+370
+00:41:29,770 --> 00:41:35,950
+اربعة اتنين و رابع وهكذا تلاتة تسعة و عشرين على
+
+371
+00:41:35,950 --> 00:41:41,240
+تمانية تلاتة و شويةيبقى كل ما ربعه كعب و كده بيزيد
+
+372
+00:41:41,240 --> 00:41:45,460
+لغاية ما يصل قداش إلى ما لا نهاية، إذا الناتج
+
+373
+00:41:45,460 --> 00:41:50,660
+يساوي Zero إذا كان ال X هذه مالها محصورة بين واحد
+
+374
+00:41:50,660 --> 00:41:55,180
+و سالب واحد أكبر من واحد ولا أقل من سالب واحد،
+
+375
+00:41:55,180 --> 00:42:00,710
+بتروح لوين؟ للمال لا نهايةهذه أظن الساندر أخدناها
+
+376
+00:42:00,710 --> 00:42:06,730
+قبل هيك بس كان مكان ال X جديد واحد كان العدد E
+
+377
+00:42:06,730 --> 00:42:12,310
+يبقى صار عندي E of 6 بنفس التكتيف اللي برهننا فيه
+
+378
+00:42:12,310 --> 00:42:17,770
+هذه بنقدر ندرهم من تانية تانية هذه شبيهة بال limit
+
+379
+00:42:17,770 --> 00:42:22,800
+اللي عملناها قبل قليل بالضبط تمامابس هنا ال X ثابت
+
+380
+00:42:22,800 --> 00:42:24,940
+وليس متغير
+
+381
+00:42:35,460 --> 00:42:40,200
+بقى الـ zero يعني لو جلبتها بيصير infinity يبقى لو
+
+382
+00:42:40,200 --> 00:42:43,400
+جاباني اي سؤال جالي limit x of n على n factorial
+
+383
+00:42:43,400 --> 00:42:48,040
+بيقوليه zero لكن لو جالي limit n factorial على x
+
+384
+00:42:48,040 --> 00:42:54,140
+to the power n يبقى ناتج بيساوي infinityوستأتيك
+
+385
+00:42:54,140 --> 00:43:00,660
+بأمثلة على كل هدول فورا إن شاء الله يبقى نيجي ناخد
+
+386
+00:43:00,660 --> 00:43:07,280
+أمثلة على كيفية استخدام الست هدول يبقى example
+
+387
+00:43:07,280 --> 00:43:12,860
+بقول
+
+388
+00:43:12,860 --> 00:43:16,460
+find the limits of the following sequences find
+
+389
+00:43:16,460 --> 00:43:21,840
+the limits of the
+
+390
+00:43:27,430 --> 00:43:33,870
+Following Sequences Undetermined
+
+391
+00:43:33,870 --> 00:43:38,070
+And Determine
+
+392
+00:43:38,070 --> 00:43:41,570
+Its
+
+393
+00:43:41,570 --> 00:43:48,390
+Convergence حددلي
+
+394
+00:43:48,390 --> 00:43:52,600
+التقارب أو التباع و التباع هذه ال Sequencesأول
+
+395
+00:43:52,600 --> 00:44:01,100
+واحدة نمرة A الـ A N بدي ساوي الجذر النوني لتلاتة
+
+396
+00:44:01,100 --> 00:44:06,420
+Int كيب بقوله
+
+397
+00:44:06,420 --> 00:44:10,600
+كويس بدي أخد ال limit لهذه ال sequence يبقى بعدي
+
+398
+00:44:10,600 --> 00:44:16,250
+بقوله ال limit لما ال Int is to infinityللجذر
+
+399
+00:44:16,250 --> 00:44:22,950
+اللوني لتلاتة في ان تكيب يسوي ال limit لما ال in
+
+400
+00:44:22,950 --> 00:44:27,790
+tends to infinity هذه يا شباب معناته تلاتة to the
+
+401
+00:44:27,790 --> 00:44:35,110
+power واحد على ان في ان أس تلاتة على ان يبقى الجذر
+
+402
+00:44:35,110 --> 00:44:39,250
+اللوني تاني واحد على ان زي ال in الجذر التربيهي
+
+403
+00:44:39,250 --> 00:44:45,740
+واحد على اتنينتمام؟ طيب كويس، هذه هاها ال limit
+
+404
+00:44:45,740 --> 00:44:50,340
+إيه اللي هيبقى قداش؟ واحد، طلع ليه هنا، وهذه؟
+
+405
+00:44:50,340 --> 00:44:55,840
+واحد، ثلاثة fixed يبقى النتيجة اللي هيساوي واحد،
+
+406
+00:44:55,840 --> 00:45:01,070
+يبقى هذه واحد مننعرف الـR2 هناك. تمام؟ نجي
+
+407
+00:45:01,070 --> 00:45:05,890
+للتانية. هذا ال limit لما ال N tends to infinity.
+
+408
+00:45:06,310 --> 00:45:13,490
+هذه بقدر أقول N أس واحد على N الكل تكيد. مظبوط؟
+
+409
+00:45:13,490 --> 00:45:18,930
+هذا أس مركب لو ضبط بصير تلاتة على N. طيب هذه اللي
+
+410
+00:45:18,930 --> 00:45:22,530
+بين جسيل لما تدخل ال limit عندها مش هي التانية؟
+
+411
+00:45:23,080 --> 00:45:28,660
+بارضه كمان قداش واحد تكييب اللي هو يساوي قداش واحد
+
+412
+00:45:28,660 --> 00:45:33,080
+يبقى ال limit لهذا المقدار او لهذا الحد يساوي واحد
+
+413
+00:45:33,080 --> 00:45:41,480
+يبقى هنا the sequence اللي هي الجذري النوني لتلاتة
+
+414
+00:45:41,480 --> 00:45:48,300
+انتكيب مالها converge كذلك سؤال ثاني
+
+415
+00:45:50,990 --> 00:45:59,910
+سؤال ثاني بيقول الـ A N يساوي N زائد أربعة واحد
+
+416
+00:45:59,910 --> 00:46:06,350
+على N زائد أربعة بعدين
+
+417
+00:46:06,350 --> 00:46:12,890
+بتطلع في المثلة هذه لا تشبه أي واحد من الستةلكن
+
+418
+00:46:12,890 --> 00:46:18,610
+أقرب واحدة عليها مين؟ اللي هي هذه، يعني الأساسي
+
+419
+00:46:18,610 --> 00:46:24,430
+اللي تحت N زائد أربعة والأس واحد على N زائد أربعة،
+
+420
+00:46:24,430 --> 00:46:29,830
+يبقى الشغلة في دينها وممكن نحور المسألة اللي عندنا
+
+421
+00:46:29,830 --> 00:46:36,440
+هذه ونخليها تروح لوين؟ لشكل رقمأتنين وبالتالي نكون
+
+422
+00:46:36,440 --> 00:46:42,680
+خلصنا من هذه الشغلة يعني أنا بروح أخد limit لما ال
+
+423
+00:46:42,680 --> 00:46:49,460
+N tends to infinity لمن؟ لل N زائد أربعة أس واحد
+
+424
+00:46:49,460 --> 00:46:56,060
+على N زائد أربعة واجه ال ه مش هيك أقوله أه put
+
+425
+00:46:56,060 --> 00:47:05,180
+حطلي مثلا M يساوي ال N زائد أربعةيبقى هذا معناه ان
+
+426
+00:47:05,180 --> 00:47:12,520
+ال M ناقص أربعة بده يساوي مين؟ بده يساوي ال N إذا
+
+427
+00:47:12,520 --> 00:47:22,660
+هذه صار limit لمن؟ ل M أس واحد على Mبالت ان اللي
+
+428
+00:47:22,660 --> 00:47:27,220
+تحت ان اللي تحت هي العمارة عن مين M ناقص أربعة
+
+429
+00:47:27,220 --> 00:47:33,740
+يبقى M ناقص أربعة tends to infinity يبقى هذا
+
+430
+00:47:33,740 --> 00:47:37,900
+الكلام بده يساوي ال limit لو جبت الأربعة عند ال
+
+431
+00:47:37,900 --> 00:47:43,720
+infinity بصير infinity زاد يعني بقداش infinity
+
+432
+00:47:43,720 --> 00:47:50,640
+يعني هذه اللتي تكافئها هي M tends to infinity لل M
+
+433
+00:47:51,400 --> 00:47:58,260
+قص واحد على M صارت هذه الصيغة اللي عند اتنين نعم
+
+434
+00:47:58,260 --> 00:48:07,400
+يبقى النتيجة تساوي واحد هذا الكلام from parkمن
+
+435
+00:48:07,400 --> 00:48:17,220
+الجزء 2 من الـ sum basic limit يبقى هنا sequence N
+
+436
+00:48:17,220 --> 00:48:23,800
+زائد أربعة مرفوعة لل أس واحد على N زائد أربعة
+
+437
+00:48:23,800 --> 00:48:27,400
+مالها converge كذلك
+
+438
+00:48:49,060 --> 00:48:53,980
+بقى على الـ Sequence التالتة Sequence التالتة
+
+439
+00:48:53,980 --> 00:49:03,470
+بيقول ما ياتي تلاتةيقول الحد إنه يساوي تلت أس M
+
+440
+00:49:03,470 --> 00:49:16,770
+زائد واحد على الجذر التربيعي لإتنين أس M يبدأ
+
+441
+00:49:16,770 --> 00:49:22,780
+ياخد limit لما ال N tends to infinityلتلتو the
+
+442
+00:49:22,780 --> 00:49:31,100
+power n واحد على الجذر التربية للاتنين أُس n يساوي
+
+443
+00:49:31,100 --> 00:49:38,900
+نمسك ال term الأول ال term الأول هو رقم ثابت وأقل
+
+444
+00:49:38,900 --> 00:49:43,300
+من الواحد الصحيح يبقى limit لما ال n بدها تروح ل
+
+445
+00:49:43,300 --> 00:49:46,300
+الملانية كدهش بيعطينا كدهش؟
+
+446
+00:49:52,110 --> 00:49:57,410
+رقم أربعة هذا رقم أربعة هذا رقم أربعة هذا رقم
+
+447
+00:49:57,410 --> 00:49:59,830
+أربعة هذا رقم أربعة هذا رقم أربعة هذا رقم أربعة
+
+448
+00:49:59,830 --> 00:50:01,090
+هذا رقم أربعة هذا رقم أربعة هذا رقم أربعة هذا رقم
+
+449
+00:50:01,090 --> 00:50:10,510
+أربعة هذا رقم أربعة هذا رقم أربعة هذا رقم
+
+450
+00:50:10,510 --> 00:50:18,870
+أربعة هذا رقم أربعةأتنين أقصى الانفينيتي اتنين
+
+451
+00:50:18,870 --> 00:50:19,710
+أقصى الانفينيتي اتنين أقصى الانفينيتي اتنين أقصى
+
+452
+00:50:19,710 --> 00:50:22,290
+الانفينيتي اتنين أقصى الانفينيتي اتنين أقصى
+
+453
+00:50:22,290 --> 00:50:25,750
+الانفينيتي اتنين أقصى الانفينيتي اتنين أقصى
+
+454
+00:50:25,750 --> 00:50:28,030
+الانفينيتي اتنين أقصى الانفينيتي اتنين أقصى
+
+455
+00:50:28,030 --> 00:50:28,390
+الانفينيتي اتنين أقصى الانفينيتي اتنين أقصى
+
+456
+00:50:28,390 --> 00:50:41,890
+الانفينيتي اتنين أقصى الانفينيتي اتنين أقصى
+
+457
+00:50:41,890 --> 00:50:48,820
+الانفينيتيوانتهينا من المثل. لازلنا في نفس ال
+
+458
+00:50:48,820 --> 00:50:56,080
+section وعن المزيد من الأسئلة على هذه النظرية مرة
+
+459
+00:50:56,080 --> 00:50:56,700
+القادمة
+
diff --git a/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/vAsKtHN5DoM_raw.json b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/vAsKtHN5DoM_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..64a746a5690dfc9e657edfbabda384c007fdfd77
--- /dev/null
+++ b/PL9fwy3NUQKwasVXkhUjp6LPUI_sOpX-0N/vAsKtHN5DoM_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 1226, "start": 10.1, "end": 12.26, "text": "بسم الله الرحمن الرحيم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640], "avg_logprob": -0.066357421875, "compression_ratio": 1.0789473684210527, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 10.1, "end": 11.08, "word": "بسم", "probability": 0.8251953125}, {"start": 11.08, "end": 11.28, "word": " الله", "probability": 0.9794921875}, {"start": 11.28, "end": 11.72, "word": " الرحمن", "probability": 0.9430338541666666}, {"start": 11.72, "end": 12.26, "word": " الرحيم", "probability": 0.99365234375}], "temperature": 1.0}, {"id": 2, "seek": 3099, "start": 12.99, "end": 30.99, "text": "نكمل مابتدأنا بيه بالمرة الماضية وهو ال infinite sequences طبعا تعرضنا لتعريف ال sequence ثم أخدنا أنواع مختلفة من ال sequence تعرضنا لشكل increasing sequence and decreasing sequence", "tokens": [1863, 24793, 1211, 3714, 16758, 2655, 3215, 10721, 8315, 4724, 1829, 3224, 20666, 2304, 25720, 9673, 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25.65, "word": " ال", "probability": 0.9248046875}, {"start": 25.65, "end": 26.21, "word": " sequence", "probability": 0.99462890625}, {"start": 26.21, "end": 27.23, "word": " تعرضنا", "probability": 0.9567057291666666}, {"start": 27.23, "end": 27.83, "word": " لشكل", "probability": 0.9314778645833334}, {"start": 27.83, "end": 28.45, "word": " increasing", "probability": 0.41552734375}, {"start": 28.45, "end": 29.25, "word": " sequence", "probability": 0.9716796875}, {"start": 29.25, "end": 29.63, "word": " and", "probability": 0.86865234375}, {"start": 29.63, "end": 30.11, "word": " decreasing", "probability": 0.8251953125}, {"start": 30.11, "end": 30.99, "word": " sequence", "probability": 0.98291015625}], "temperature": 1.0}, {"id": 3, "seek": 4601, "start": 31.25, "end": 46.01, "text": "واخدنا بعض ال limits سواء كان sandwich theorem أو limits عادية وعرفنا ان ال limits لل sequences مثل ال limits لل functions تماما واخدنا على ذلك مثال", "tokens": [2407, 47283, 3215, 8315, 45030, 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{"start": 59.93, "end": 60.17, "word": " شوف", "probability": 0.94873046875}, {"start": 60.17, "end": 60.47, "word": " ليهالي", "probability": 0.62744140625}, {"start": 60.47, "end": 60.59, "word": " ال", "probability": 0.96484375}, {"start": 60.59, "end": 61.01, "word": " sequence", "probability": 0.9931640625}, {"start": 61.01, "end": 61.41, "word": " هذي", "probability": 0.7452799479166666}, {"start": 61.41, "end": 62.25, "word": " converge", "probability": 0.90283203125}, {"start": 62.25, "end": 62.81, "word": " و", "probability": 0.5185546875}, {"start": 62.81, "end": 63.25, "word": " الله", "probability": 0.79443359375}, {"start": 63.25, "end": 64.23, "word": " diverse", "probability": 0.170654296875}, {"start": 64.23, "end": 64.71, "word": " و", "probability": 0.8828125}, {"start": 64.71, "end": 65.35, "word": " ابتدأنا", "probability": 0.89775390625}, {"start": 65.35, "end": 65.87, "word": " ناخد", "probability": 0.9873046875}, {"start": 65.87, "end": 66.11, "word": " قد", 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"text": "إذا وجدت الإشارة مقلوبة بدل ما هو بادر ناقص بدي يبدأ بزاد حط للأس هنا بس N زائد واحد ابتنع الإشارة معاك وبصير شغلك صحية مائة بالمائة يبقى فار شكل ال sequence فيها سالب واحد to the power N", "tokens": [28814, 15730, 49610, 3215, 2655, 33688, 8592, 9640, 3660, 3714, 4587, 1211, 37746, 3660, 47525, 1211, 19446, 31439, 4724, 18513, 2288, 8717, 995, 4587, 9381, 4724, 16254, 7251, 44510, 10721, 4724, 11622, 18513, 11331, 9566, 24976, 10721, 3794, 34105, 4724, 3794, 426, 30767, 16373, 3215, 36764, 24401, 48127, 2655, 1863, 3615, 33688, 8592, 9640, 3660, 20449, 995, 4117, 46599, 9381, 13546, 13412, 17082, 23275, 20328, 5016, 10632, 3714, 16373, 3660, 20666, 2304, 16373, 3660, 7251, 3555, 4587, 7578, 6156, 9640, 13412, 28820, 2423, 8310, 8978, 11296, 8608, 6027, 3555, 36764, 24401, 281, 264, 1347, 426], "avg_logprob": -0.2298177134556075, "compression_ratio": 1.6040609137055837, "no_speech_prob": 0.0, "words": [{"start": 296.07, "end": 296.43, "word": "إذا", "probability": 0.71533203125}, {"start": 296.43, "end": 296.89, "word": " وجدت", "probability": 0.853515625}, {"start": 296.89, "end": 297.43, "word": " الإشارة", "probability": 0.96435546875}, {"start": 297.43, "end": 298.27, "word": " مقلوبة", "probability": 0.90986328125}, {"start": 298.27, "end": 298.71, "word": " بدل", "probability": 0.887451171875}, {"start": 298.71, "end": 298.85, "word": " ما", "probability": 0.828125}, {"start": 298.85, "end": 299.13, "word": " هو", "probability": 0.8974609375}, {"start": 299.13, "end": 299.63, "word": " بادر", "probability": 0.615478515625}, {"start": 299.63, "end": 300.13, "word": " ناقص", "probability": 0.9381103515625}, {"start": 300.13, "end": 300.41, "word": " بدي", "probability": 0.49615478515625}, {"start": 300.41, "end": 300.77, "word": " يبدأ", "probability": 0.8946940104166666}, {"start": 300.77, "end": 301.31, "word": " بزاد", "probability": 0.7950846354166666}, {"start": 301.31, "end": 302.09, "word": " حط", "probability": 0.48223876953125}, {"start": 302.09, "end": 302.75, "word": " للأس", "probability": 0.81005859375}, {"start": 302.75, "end": 303.09, "word": " هنا", "probability": 0.96875}, {"start": 303.09, "end": 303.61, "word": " بس", "probability": 0.928466796875}, {"start": 303.61, "end": 304.03, "word": " N", "probability": 0.3828125}, {"start": 304.03, "end": 304.61, "word": " زائد", "probability": 0.7494303385416666}, {"start": 304.61, "end": 305.05, "word": " واحد", "probability": 0.8076171875}, {"start": 305.05, "end": 305.91, "word": " ابتنع", "probability": 0.789794921875}, {"start": 305.91, "end": 306.55, "word": " الإشارة", "probability": 0.82696533203125}, {"start": 306.55, "end": 306.91, "word": " معاك", "probability": 0.9318033854166666}, {"start": 306.91, "end": 307.29, "word": " وبصير", "probability": 0.84326171875}, {"start": 307.29, "end": 307.71, "word": " شغلك", "probability": 0.9840494791666666}, {"start": 307.71, "end": 308.39, "word": " صحية", "probability": 0.8899739583333334}, {"start": 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"end": 314.23, "word": " power", "probability": 0.91357421875}, {"start": 314.23, "end": 314.87, "word": " N", "probability": 0.865234375}], "temperature": 1.0}, {"id": 16, "seek": 33108, "start": 315.26, "end": 331.08, "text": "مقروبة من اين؟ فمقروبة في M. السؤال هو هدى بنسميها oscillating sequence، مظبوط؟ لكن oscillating رايحة لرقم و الله رايحة لرقمين مختلفين", "tokens": [2304, 4587, 32887, 49401, 9154, 1975, 9957, 22807, 6156, 2304, 4587, 32887, 49401, 8978, 376, 13, 21136, 33604, 6027, 31439, 8032, 3215, 7578, 44945, 38251, 1829, 11296, 18225, 990, 8310, 12399, 3714, 19913, 3555, 2407, 9566, 22807, 44381, 18225, 990, 12602, 47302, 5016, 3660, 5296, 2288, 4587, 2304, 4032, 21984, 12602, 47302, 5016, 3660, 5296, 2288, 4587, 2304, 9957, 3714, 46456, 46538, 9957], "avg_logprob": -0.28320313012227416, "compression_ratio": 1.423841059602649, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 315.26, "end": 316.02, "word": "مقروبة", "probability": 0.6199951171875}, {"start": 316.02, "end": 316.22, "word": " من", "probability": 0.7587890625}, {"start": 316.22, "end": 316.68, "word": " اين؟", "probability": 0.5653076171875}, {"start": 316.68, "end": 317.64, "word": " فمقروبة", "probability": 0.817333984375}, {"start": 317.64, "end": 318.26, "word": " في", "probability": 0.9599609375}, {"start": 318.26, "end": 318.72, "word": " M.", "probability": 0.712890625}, {"start": 319.18, "end": 319.94, "word": " السؤال", "probability": 0.9873046875}, {"start": 319.94, "end": 320.24, "word": " هو", "probability": 0.9765625}, {"start": 320.24, "end": 320.98, "word": " هدى", "probability": 0.564697265625}, {"start": 320.98, "end": 321.72, "word": " بنسميها", "probability": 0.84564208984375}, {"start": 321.72, "end": 323.48, "word": " oscillating", "probability": 0.67333984375}, {"start": 323.48, "end": 325.1, "word": " sequence،", "probability": 0.6737060546875}, {"start": 325.1, "end": 325.94, "word": " مظبوط؟", "probability": 0.8116048177083334}, {"start": 325.94, "end": 326.26, "word": " لكن", "probability": 0.947265625}, {"start": 326.26, "end": 327.26, "word": " oscillating", "probability": 0.704833984375}, {"start": 327.26, "end": 327.84, "word": " رايحة", "probability": 0.79742431640625}, {"start": 327.84, "end": 328.46, "word": " لرقم", "probability": 0.9873046875}, {"start": 328.46, "end": 328.88, "word": " و", "probability": 0.267578125}, {"start": 328.88, "end": 329.1, "word": " الله", "probability": 0.927734375}, {"start": 329.1, "end": 329.52, "word": " رايحة", "probability": 0.979248046875}, {"start": 329.52, "end": 330.12, "word": " لرقمين", "probability": 0.98388671875}, {"start": 330.12, "end": 331.08, "word": " مختلفين", "probability": 0.9945068359375}], "temperature": 1.0}, {"id": 17, "seek": 36007, "start": 332.17, "end": 360.07, "text": "طبعاً مش رقمين وإنما كل واحدة منهم رايحة لوين إلى infinity واحدة ل infinity والتانية ل سالب infinity يبقى ال limit exist ولا does not exist وبالتالي ال sequence by then يبقى باجي بقوله هنا ال sequence by then because it oscillated", "tokens": [9566, 3555, 3615, 995, 14111, 37893, 12602, 4587, 2304, 9957, 4032, 28814, 1863, 15042, 28242, 36764, 24401, 3660, 9154, 16095, 12602, 47302, 5016, 3660, 45164, 9957, 30731, 13202, 36764, 24401, 3660, 5296, 13202, 16070, 2655, 7649, 10632, 5296, 8608, 6027, 3555, 13202, 7251, 3555, 4587, 7578, 2423, 4948, 2514, 49429, 775, 406, 2514, 46599, 6027, 2655, 6027, 1829, 2423, 8310, 538, 550, 7251, 3555, 4587, 7578, 4724, 26108, 1829, 4724, 39648, 3224, 34105, 2423, 8310, 538, 550, 570, 309, 18225, 770], "avg_logprob": -0.2721036509042833, "compression_ratio": 1.6804123711340206, "no_speech_prob": 0.0, "words": [{"start": 332.17, "end": 332.85, "word": "طبعاً", "probability": 0.67333984375}, {"start": 332.85, "end": 333.69, "word": " مش", "probability": 0.521484375}, {"start": 333.69, "end": 334.49, "word": " رقمين", "probability": 0.8839111328125}, {"start": 334.49, "end": 334.99, "word": " وإنما", "probability": 0.798095703125}, {"start": 334.99, "end": 335.37, "word": " كل", "probability": 0.951171875}, {"start": 335.37, "end": 335.81, "word": " واحدة", "probability": 0.9890950520833334}, {"start": 335.81, "end": 336.05, "word": " منهم", "probability": 0.974365234375}, {"start": 336.05, "end": 336.47, "word": " رايحة", "probability": 0.9478759765625}, {"start": 336.47, "end": 336.93, "word": " لوين", "probability": 0.535430908203125}, {"start": 336.93, "end": 337.79, "word": " إلى", "probability": 0.64794921875}, {"start": 337.79, "end": 338.73, "word": " infinity", "probability": 0.489501953125}, {"start": 338.73, "end": 339.33, "word": " واحدة", "probability": 0.8880208333333334}, {"start": 339.33, "end": 339.43, "word": " ل", "probability": 0.55322265625}, {"start": 339.43, "end": 339.97, "word": " infinity", "probability": 0.45654296875}, {"start": 339.97, "end": 341.01, "word": " والتانية", "probability": 0.857666015625}, {"start": 341.01, "end": 341.71, "word": " ل", "probability": 0.9248046875}, {"start": 341.71, "end": 342.13, "word": " سالب", "probability": 0.5769449869791666}, {"start": 342.13, "end": 342.69, "word": " infinity", "probability": 0.89794921875}, {"start": 342.69, "end": 343.13, "word": " يبقى", "probability": 0.8201904296875}, {"start": 343.13, "end": 343.29, "word": " ال", "probability": 0.5849609375}, {"start": 343.29, "end": 343.47, "word": " limit", "probability": 0.85205078125}, {"start": 343.47, "end": 344.03, "word": " exist", "probability": 0.464111328125}, {"start": 344.03, "end": 344.31, "word": " ولا", "probability": 0.62109375}, {"start": 344.31, "end": 344.59, "word": " does", "probability": 0.5}, {"start": 344.59, "end": 344.91, "word": " not", "probability": 0.96728515625}, {"start": 344.91, "end": 345.63, "word": " exist", "probability": 0.96728515625}, {"start": 345.63, "end": 346.97, "word": " وبالتالي", "probability": 0.90673828125}, {"start": 346.97, "end": 347.13, "word": " ال", "probability": 0.88232421875}, {"start": 347.13, "end": 347.81, "word": " sequence", "probability": 0.98486328125}, {"start": 347.81, "end": 348.73, "word": " by", "probability": 0.8408203125}, {"start": 348.73, "end": 349.13, "word": " then", "probability": 0.423583984375}, {"start": 349.13, "end": 349.89, "word": " يبقى", "probability": 0.9700927734375}, {"start": 349.89, "end": 350.27, "word": " باجي", "probability": 0.8260091145833334}, {"start": 350.27, "end": 350.91, "word": " بقوله", "probability": 0.9283854166666666}, {"start": 350.91, "end": 351.41, "word": " هنا", "probability": 0.99072265625}, {"start": 351.41, "end": 352.23, "word": " ال", "probability": 0.52880859375}, {"start": 352.23, "end": 352.99, "word": " sequence", "probability": 0.953125}, {"start": 352.99, "end": 353.97, "word": " by", "probability": 0.884765625}, {"start": 353.97, "end": 354.65, "word": " then", "probability": 0.83642578125}, {"start": 354.65, "end": 355.57, "word": " because", "probability": 0.74462890625}, {"start": 355.57, "end": 358.09, "word": " it", "probability": 0.955078125}, {"start": 358.09, "end": 360.07, "word": " oscillated", "probability": 0.685791015625}], "temperature": 1.0}, {"id": 18, "seek": 38150, "start": 362.1, "end": 381.5, "text": "between two different limits اللي هما infinity and سالب infinity", "tokens": [32387, 732, 819, 10406, 13672, 1829, 8032, 15042, 13202, 293, 8608, 6027, 3555, 13202], "avg_logprob": -0.1671875019868215, "compression_ratio": 1.0273972602739727, "no_speech_prob": 0.0, "words": [{"start": 362.1, "end": 362.8, "word": "between", "probability": 0.74072265625}, {"start": 362.8, "end": 367.12, "word": " two", "probability": 0.8984375}, {"start": 367.12, "end": 369.52, "word": " different", "probability": 0.89453125}, {"start": 369.52, "end": 373.78, "word": " limits", "probability": 0.962890625}, {"start": 373.78, "end": 377.32, "word": " اللي", "probability": 0.893798828125}, {"start": 377.32, "end": 377.72, "word": " هما", "probability": 0.87548828125}, {"start": 377.72, "end": 378.5, "word": " infinity", "probability": 0.701171875}, {"start": 378.5, "end": 379.62, "word": " and", "probability": 0.818359375}, {"start": 379.62, "end": 380.76, "word": " سالب", "probability": 0.7542317708333334}, {"start": 380.76, "end": 381.5, "word": " infinity", "probability": 0.8408203125}], "temperature": 1.0}, {"id": 19, "seek": 40618, "start": 383.36, "end": 406.18, "text": "يبقى نظرا لأنها تترجح ما بين الاتنين يبقى ال sequence does not convert يبقى ماجي بقوله هي ال sequence معاها converted ننتقل الآن إلى مثال آخر بيقول ما يأتي example two", "tokens": [1829, 3555, 4587, 7578, 8717, 19913, 23557, 5296, 33456, 11296, 6055, 2655, 47341, 5016, 19446, 49374, 2423, 9307, 1863, 9957, 7251, 3555, 4587, 7578, 2423, 8310, 775, 406, 7620, 7251, 3555, 4587, 7578, 3714, 26108, 1829, 4724, 39648, 3224, 39896, 2423, 8310, 20449, 995, 11296, 16424, 8717, 29399, 4587, 1211, 6024, 48506, 30731, 50113, 6027, 19753, 34740, 4724, 1829, 39648, 19446, 7251, 10721, 31371, 1365, 732], "avg_logprob": 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{"start": 388.36, "end": 388.88, "word": " not", "probability": 0.96435546875}, {"start": 388.88, "end": 392.0, "word": " convert", "probability": 0.76318359375}, {"start": 392.0, "end": 392.92, "word": " يبقى", "probability": 0.9522705078125}, {"start": 392.92, "end": 393.3, "word": " ماجي", "probability": 0.6124674479166666}, {"start": 393.3, "end": 393.82, "word": " بقوله", "probability": 0.66845703125}, {"start": 393.82, "end": 394.06, "word": " هي", "probability": 0.278076171875}, {"start": 394.06, "end": 394.24, "word": " ال", "probability": 0.9521484375}, {"start": 394.24, "end": 394.68, "word": " sequence", "probability": 0.970703125}, {"start": 394.68, "end": 395.3, "word": " معاها", "probability": 0.6497395833333334}, {"start": 395.3, "end": 396.0, "word": " converted", "probability": 0.1756591796875}, {"start": 396.0, "end": 397.36, "word": " ننتقل", "probability": 0.95263671875}, {"start": 397.36, "end": 397.94, "word": " الآن", "probability": 0.735107421875}, {"start": 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"word": "Find", "probability": 0.55731201171875}, {"start": 414.1, "end": 415.2, "word": " the", "probability": 0.77587890625}, {"start": 415.2, "end": 416.88, "word": " limits", "probability": 0.939453125}, {"start": 416.88, "end": 418.34, "word": " of", "probability": 0.97900390625}, {"start": 418.34, "end": 419.86, "word": " the", "probability": 0.8701171875}, {"start": 419.86, "end": 421.72, "word": " following", "probability": 0.81787109375}, {"start": 421.72, "end": 426.34, "word": " sequences", "probability": 0.96533203125}, {"start": 426.34, "end": 428.86, "word": " and", "probability": 0.42626953125}, {"start": 428.86, "end": 429.64, "word": " determine", "probability": 0.93408203125}], "temperature": 1.0}, {"id": 21, "seek": 46025, "start": 458.13, "end": 460.25, "text": "الحد النوني في ال sequence", "tokens": [6027, 5016, 3215, 28239, 11536, 1829, 8978, 2423, 8310], "avg_logprob": -0.5851562440395355, "compression_ratio": 0.9302325581395349, "no_speech_prob": 0.0, "words": [{"start": 458.13, "end": 458.97, "word": "الحد", "probability": 0.4104410807291667}, {"start": 458.97, "end": 459.57, "word": " النوني", "probability": 0.8440755208333334}, {"start": 459.57, "end": 459.71, "word": " في", "probability": 0.82421875}, {"start": 459.71, "end": 459.83, "word": " ال", "probability": 0.66357421875}, {"start": 459.83, "end": 460.25, "word": " sequence", "probability": 0.42333984375}], "temperature": 1.0}, {"id": 22, "seek": 47047, "start": 460.99, "end": 470.47, "text": "اللي هو 2N زائد 1 على 1 ناقص 3 general N", "tokens": [6027, 20292, 31439, 568, 45, 30767, 16373, 3215, 502, 15844, 502, 8717, 995, 4587, 9381, 805, 2674, 426], "avg_logprob": -0.3509457330954702, "compression_ratio": 0.9047619047619048, "no_speech_prob": 0.0, "words": [{"start": 460.99, "end": 461.35, "word": "اللي", "probability": 0.3753662109375}, {"start": 461.35, "end": 461.53, "word": " هو", "probability": 0.95751953125}, {"start": 461.53, "end": 462.67, "word": " 2N", "probability": 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0.947265625}, {"start": 623.38, "end": 623.62, "word": " ب", "probability": 0.95703125}, {"start": 623.62, "end": 623.96, "word": " Zero", "probability": 0.95361328125}, {"start": 623.96, "end": 624.88, "word": " طلع", "probability": 0.7911783854166666}, {"start": 624.88, "end": 625.54, "word": " النتج", "probability": 0.7688802083333334}, {"start": 625.54, "end": 626.22, "word": " عندك", "probability": 0.9091796875}, {"start": 626.22, "end": 626.48, "word": " هنا", "probability": 0.98095703125}, {"start": 626.48, "end": 626.94, "word": " فوق", "probability": 0.889892578125}, {"start": 626.94, "end": 627.26, "word": " بصير", "probability": 0.7320149739583334}, {"start": 627.26, "end": 627.86, "word": " جداش", "probability": 0.65185546875}, {"start": 627.86, "end": 629.32, "word": " Infinity", "probability": 0.671875}, {"start": 629.32, "end": 630.3, "word": " على", "probability": 0.8798828125}, {"start": 630.3, "end": 631.0, "word": " سالب", "probability": 0.9153645833333334}, {"start": 631.0, "end": 631.94, "word": " تلاتة", "probability": 0.8900146484375}, {"start": 631.94, "end": 632.6, "word": " يبقى", "probability": 0.970458984375}, {"start": 632.6, "end": 633.18, "word": " النتيجة", "probability": 0.8966064453125}, {"start": 633.18, "end": 633.86, "word": " جداش", "probability": 0.9811197916666666}], "temperature": 1.0}, {"id": 30, "seek": 65680, "start": 634.02, "end": 656.8, "text": "سالب infinity معناته ال sequence للحد النوني هذا تبعها تبقى معلها by V يبقى هنا the sequence من ال N plus one واحد ناقص ثلاثة جذر ال N by V سؤال ثاني", "tokens": [3794, 6027, 3555, 13202, 20449, 8315, 47395, 2423, 8310, 24976, 24401, 28239, 11536, 1829, 23758, 6055, 3555, 3615, 11296, 6055, 3555, 4587, 7578, 20449, 1211, 11296, 538, 691, 7251, 3555, 4587, 7578, 34105, 264, 8310, 9154, 2423, 426, 1804, 472, 36764, 24401, 8717, 995, 4587, 9381, 38637, 1211, 5718, 104, 3660, 10874, 8848, 2288, 2423, 426, 538, 691, 8608, 33604, 6027, 38637, 7649, 1829], "avg_logprob": 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{"start": 641.18, "end": 641.62, "word": " by", "probability": 0.54638671875}, {"start": 641.62, "end": 642.12, "word": " V", "probability": 0.41259765625}, {"start": 642.12, "end": 643.28, "word": " يبقى", "probability": 0.950927734375}, {"start": 643.28, "end": 643.62, "word": " هنا", "probability": 0.986328125}, {"start": 643.62, "end": 644.14, "word": " the", "probability": 0.2247314453125}, {"start": 644.14, "end": 646.3, "word": " sequence", "probability": 0.97998046875}, {"start": 646.3, "end": 646.98, "word": " من", "probability": 0.2486572265625}, {"start": 646.98, "end": 647.38, "word": " ال", "probability": 0.6064453125}, {"start": 647.38, "end": 647.68, "word": " N", "probability": 0.79931640625}, {"start": 647.68, "end": 648.28, "word": " plus", "probability": 0.63671875}, {"start": 648.28, "end": 648.78, "word": " one", "probability": 0.779296875}, {"start": 648.78, "end": 649.58, "word": " واحد", "probability": 0.863525390625}, {"start": 649.58, "end": 650.12, "word": " ناقص", "probability": 0.93798828125}, {"start": 650.12, "end": 650.86, "word": " ثلاثة", "probability": 0.921875}, {"start": 650.86, "end": 651.32, "word": " جذر", "probability": 0.6024576822916666}, {"start": 651.32, "end": 651.6, "word": " ال", "probability": 0.939453125}, {"start": 651.6, "end": 652.04, "word": " N", "probability": 0.8994140625}, {"start": 652.04, "end": 652.98, "word": " by", "probability": 0.85546875}, {"start": 652.98, "end": 653.58, "word": " V", "probability": 0.98876953125}, {"start": 653.58, "end": 656.16, "word": " سؤال", "probability": 0.9264322916666666}, {"start": 656.16, "end": 656.8, "word": " ثاني", "probability": 0.853515625}], "temperature": 1.0}, {"id": 31, "seek": 67464, "start": 659.12, "end": 674.64, "text": "بدنا شكل الحد النوني للـ sequence هو اتنين ناقص واحد على الاتنين قص م في تلاتة زائد واحد على اتنين قص م", "tokens": [3555, 3215, 8315, 13412, 28820, 21542, 3215, 28239, 11536, 1829, 24976, 39184, 8310, 31439, 1975, 2655, 1863, 9957, 8717, 995, 4587, 9381, 36764, 24401, 15844, 2423, 9307, 1863, 9957, 12174, 9381, 3714, 8978, 6055, 1211, 9307, 3660, 30767, 16373, 3215, 36764, 24401, 15844, 1975, 2655, 1863, 9957, 12174, 9381, 3714], "avg_logprob": -0.2864583450205186, "compression_ratio": 1.5663716814159292, "no_speech_prob": 0.0, "words": [{"start": 659.12, "end": 659.84, "word": "بدنا", "probability": 0.41015625}, {"start": 659.84, "end": 660.64, "word": " شكل", "probability": 0.81494140625}, {"start": 660.64, "end": 661.34, "word": " الحد", "probability": 0.953369140625}, {"start": 661.34, "end": 661.96, "word": " النوني", "probability": 0.9456380208333334}, {"start": 661.96, "end": 662.26, "word": " للـ", "probability": 0.58251953125}, {"start": 662.26, "end": 662.76, "word": " sequence", "probability": 0.5869140625}, {"start": 662.76, "end": 663.24, "word": " هو", "probability": 0.91357421875}, {"start": 663.24, "end": 664.5, "word": " اتنين", "probability": 0.781829833984375}, {"start": 664.5, "end": 665.14, "word": " ناقص", "probability": 0.92431640625}, {"start": 665.14, "end": 665.72, "word": " واحد", "probability": 0.990478515625}, {"start": 665.72, "end": 666.1, "word": " على", "probability": 0.59765625}, {"start": 666.1, "end": 666.98, "word": " الاتنين", "probability": 0.7845458984375}, {"start": 666.98, "end": 667.52, "word": " قص", "probability": 0.59521484375}, {"start": 667.52, "end": 668.08, "word": " م", "probability": 0.204345703125}, {"start": 668.08, "end": 668.86, "word": " في", "probability": 0.73046875}, {"start": 668.86, "end": 670.12, "word": " تلاتة", "probability": 0.93359375}, {"start": 670.12, "end": 671.18, "word": " زائد", "probability": 0.92822265625}, {"start": 671.18, "end": 671.98, "word": " واحد", "probability": 0.98583984375}, {"start": 671.98, "end": 672.76, "word": " على", "probability": 0.81494140625}, {"start": 672.76, "end": 673.82, "word": " اتنين", "probability": 0.957763671875}, {"start": 673.82, "end": 674.32, "word": " قص", "probability": 0.965087890625}, {"start": 674.32, "end": 674.64, "word": " م", "probability": 0.59228515625}], "temperature": 1.0}, {"id": 32, "seek": 69868, "start": 675.52, "end": 698.68, "text": "بنروح ناخد ال limit لهذا الحد النوني يبقى ال limit لما ال N tends to infinity ل 2 ناقص 1 على 2 أس N في 3 زائد 1 على 2 أس N هذا الكلام يساوي من خلاص ال limit اللي كتبناها المرة الماضية", "tokens": [3555, 1863, 32887, 5016, 8717, 47283, 3215, 2423, 4948, 46740, 15730, 21542, 3215, 28239, 11536, 1829, 7251, 3555, 4587, 7578, 2423, 4948, 5296, 15042, 2423, 426, 12258, 281, 13202, 5296, 568, 8717, 995, 4587, 9381, 502, 15844, 568, 5551, 3794, 426, 8978, 805, 30767, 16373, 3215, 502, 15844, 568, 5551, 3794, 426, 23758, 2423, 28820, 10943, 7251, 3794, 995, 45865, 9154, 16490, 1211, 33546, 2423, 4948, 13672, 1829, 9122, 2655, 3555, 8315, 11296, 9673, 25720, 9673, 46958, 10632], "avg_logprob": -0.1679192970070658, "compression_ratio": 1.6101694915254237, "no_speech_prob": 0.0, "words": [{"start": 675.52, "end": 676.22, "word": 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0.3974609375}, {"start": 682.14, "end": 682.5, "word": " tends", "probability": 0.70849609375}, {"start": 682.5, "end": 682.76, "word": " to", "probability": 0.865234375}, {"start": 682.76, "end": 683.46, "word": " infinity", "probability": 0.80322265625}, {"start": 683.46, "end": 684.12, "word": " ل", "probability": 0.92333984375}, {"start": 684.12, "end": 684.64, "word": " 2", "probability": 0.418212890625}, {"start": 684.64, "end": 685.3, "word": " ناقص", "probability": 0.67236328125}, {"start": 685.3, "end": 685.88, "word": " 1", "probability": 0.853515625}, {"start": 685.88, "end": 686.54, "word": " على", "probability": 0.65380859375}, {"start": 686.54, "end": 687.06, "word": " 2", "probability": 0.97119140625}, {"start": 687.06, "end": 687.52, "word": " أس", "probability": 0.5965576171875}, {"start": 687.52, "end": 687.9, "word": " N", "probability": 0.95751953125}, {"start": 687.9, "end": 688.42, "word": " في", "probability": 0.81982421875}, {"start": 688.42, "end": 689.1, 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{"start": 696.52, "end": 696.82, "word": " limit", "probability": 0.9833984375}, {"start": 696.82, "end": 697.02, "word": " اللي", "probability": 0.902099609375}, {"start": 697.02, "end": 697.62, "word": " كتبناها", "probability": 0.98095703125}, {"start": 697.62, "end": 698.06, "word": " المرة", "probability": 0.975830078125}, {"start": 698.06, "end": 698.68, "word": " الماضية", "probability": 0.9947916666666666}], "temperature": 1.0}, {"id": 33, "seek": 72393, "start": 699.03, "end": 723.93, "text": "إن تعتبر limit للقوس الأول مضروبة في limit للقوس الثاني يبجى هذه تعتبر limit لما ال N tends to infinity لمين؟ لما ال N بدأ تروح لمعنى نهاية لإتنين ناقص واحد على اتنين أس N في limit لما ال N tends to infinity", "tokens": [28814, 1863, 6055, 34268, 26890, 4948, 24976, 4587, 41779, 16247, 12610, 3714, 11242, 32887, 49401, 8978, 4948, 24976, 4587, 41779, 6024, 104, 7649, 1829, 7251, 3555, 7435, 7578, 29538, 6055, 34268, 26890, 4948, 5296, 15042, 2423, 426, 12258, 281, 13202, 32767, 9957, 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0.6650390625}, {"start": 718.57, "end": 719.21, "word": " اتنين", "probability": 0.8992919921875}, {"start": 719.21, "end": 719.65, "word": " أس", "probability": 0.529296875}, {"start": 719.65, "end": 720.07, "word": " N", "probability": 0.935546875}, {"start": 720.07, "end": 720.69, "word": " في", "probability": 0.8369140625}, {"start": 720.69, "end": 721.27, "word": " limit", "probability": 0.97705078125}, {"start": 721.27, "end": 722.07, "word": " لما", "probability": 0.959716796875}, {"start": 722.07, "end": 722.29, "word": " ال", "probability": 0.94287109375}, {"start": 722.29, "end": 722.61, "word": " N", "probability": 0.9833984375}, {"start": 722.61, "end": 723.01, "word": " tends", "probability": 0.84912109375}, {"start": 723.01, "end": 723.31, "word": " to", "probability": 0.970703125}, {"start": 723.31, "end": 723.93, "word": " infinity", "probability": 0.8671875}], "temperature": 1.0}, {"id": 34, "seek": 75341, "start": 724.29, "end": 753.41, "text": "لتلاتة زائد واحد على اتنين أُس M هذا الكلام بده يساوي طبعا هذه ب Zero وهذه ب Zero بيبقى لي اتنين في تلاتة ويساوي ستة ليه قيمة عددية So the sequence اللي هي من اتنين ناقص واحد على اتنين أُس M في", "tokens": [1211, 2655, 1211, 9307, 3660, 30767, 16373, 3215, 36764, 24401, 15844, 1975, 2655, 1863, 9957, 5551, 10859, 3794, 376, 23758, 2423, 28820, 10943, 47525, 3224, 7251, 3794, 995, 45865, 23032, 3555, 3615, 995, 29538, 4724, 17182, 37037, 24192, 4724, 17182, 4724, 1829, 3555, 4587, 7578, 32239, 1975, 2655, 1863, 9957, 8978, 6055, 1211, 9307, 3660, 4032, 1829, 3794, 995, 45865, 8608, 2655, 3660, 32239, 3224, 12174, 32640, 3660, 6225, 3215, 3215, 10632, 407, 264, 8310, 13672, 1829, 39896, 9154, 1975, 2655, 1863, 9957, 8717, 995, 4587, 9381, 36764, 24401, 15844, 1975, 2655, 1863, 9957, 5551, 10859, 3794, 376, 8978], "avg_logprob": -0.22062500596046447, "compression_ratio": 1.7692307692307692, "no_speech_prob": 0.0, "words": [{"start": 724.29, "end": 726.09, "word": "لتلاتة", "probability": 0.6940673828125}, 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{"start": 750.47, "end": 751.29, "word": " اتنين", "probability": 0.9849853515625}, {"start": 751.29, "end": 752.01, "word": " أُس", "probability": 0.8859049479166666}, {"start": 752.01, "end": 752.47, "word": " M", "probability": 0.98876953125}, {"start": 752.47, "end": 753.41, "word": " في", "probability": 0.93505859375}], "temperature": 1.0}, {"id": 35, "seek": 78011, "start": 753.77, "end": 780.11, "text": "أتنين في تلاتة زائد واحد على اتنين اص ان معناها converge وبالتالي حكمنا على ال series converge او diverge من خلال ال limit اللي عندنا سؤال الثالث بيقول لان يسوى لن الان ماقص لن الان زائد واحد", "tokens": [10721, 2655, 1863, 9957, 8978, 6055, 1211, 9307, 3660, 30767, 16373, 3215, 36764, 24401, 15844, 1975, 2655, 1863, 9957, 1975, 9381, 16472, 20449, 8315, 11296, 41881, 46599, 6027, 2655, 6027, 1829, 11331, 24793, 8315, 15844, 2423, 2638, 41881, 1975, 2407, 18558, 432, 9154, 16490, 1211, 6027, 2423, 4948, 13672, 1829, 43242, 8315, 8608, 33604, 6027, 6024, 104, 6027, 12984, 4724, 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{"start": 834.8, "end": 835.7, "word": " صلاحيات", "probability": 0.96748046875}, {"start": 835.7, "end": 836.72, "word": " تدخل", "probability": 0.802642822265625}, {"start": 836.72, "end": 837.62, "word": " داخل", "probability": 0.8727213541666666}, {"start": 837.62, "end": 838.16, "word": " لن", "probability": 0.6090087890625}, {"start": 838.16, "end": 839.12, "word": " يبقى", "probability": 0.94482421875}, {"start": 839.12, "end": 839.7, "word": " limit", "probability": 0.95263671875}, {"start": 839.7, "end": 840.36, "word": " لما", "probability": 0.921630859375}, {"start": 840.36, "end": 840.52, "word": " ال", "probability": 0.82373046875}, {"start": 840.52, "end": 840.82, "word": " N", "probability": 0.73291015625}, {"start": 840.82, "end": 841.16, "word": " tends", "probability": 0.27294921875}, {"start": 841.16, "end": 841.36, "word": " to", "probability": 0.927734375}, {"start": 841.36, "end": 842.08, "word": " infinity", "probability": 0.86376953125}, {"start": 842.08, "end": 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عليه", "probability": 0.7919921875}, {"start": 866.36, "end": 867.24, "word": " بقول", "probability": 0.91162109375}, {"start": 867.24, "end": 867.96, "word": " so", "probability": 0.14501953125}, {"start": 867.96, "end": 868.72, "word": " the", "probability": 0.787109375}, {"start": 868.72, "end": 870.0, "word": " sequence", "probability": 0.9755859375}, {"start": 870.0, "end": 871.18, "word": " لإن", "probability": 0.7877604166666666}, {"start": 871.18, "end": 871.5, "word": " ال", "probability": 0.9267578125}, {"start": 871.5, "end": 871.94, "word": " M", "probability": 0.389404296875}], "temperature": 1.0}, {"id": 40, "seek": 87887, "start": 872.15, "end": 878.87, "text": "نقص لإن ال N زائد واحد هذه مالها convert", "tokens": [1863, 4587, 9381, 5296, 28814, 1863, 2423, 426, 30767, 16373, 3215, 36764, 24401, 29538, 3714, 6027, 11296, 7620], "avg_logprob": -0.31949014099020706, "compression_ratio": 0.9411764705882353, "no_speech_prob": 0.0, "words": [{"start": 872.15, "end": 873.09, "word": "نقص", "probability": 0.7403157552083334}, {"start": 873.09, "end": 873.57, "word": " لإن", "probability": 0.7698567708333334}, {"start": 873.57, "end": 873.83, "word": " ال", "probability": 0.78759765625}, {"start": 873.83, "end": 874.27, "word": " N", "probability": 0.25244140625}, {"start": 874.27, "end": 875.71, "word": " زائد", "probability": 0.736572265625}, {"start": 875.71, "end": 876.47, "word": " واحد", "probability": 0.944091796875}, {"start": 876.47, "end": 877.07, "word": " هذه", "probability": 0.27880859375}, {"start": 877.07, "end": 877.75, "word": " مالها", "probability": 0.8517252604166666}, {"start": 877.75, "end": 878.87, "word": " convert", "probability": 0.84423828125}], "temperature": 1.0}, {"id": 41, "seek": 92216, "start": 905.6, "end": 922.16, "text": "سؤال الرابع بيقول لي ان ال A N تساوي 1 على جذر ال N في Tan inverse N", "tokens": [3794, 33604, 6027, 34892, 16758, 3615, 4724, 1829, 39648, 32239, 16472, 2423, 316, 426, 6055, 3794, 995, 45865, 502, 15844, 10874, 8848, 2288, 2423, 426, 8978, 17046, 17340, 426], "avg_logprob": -0.2992187480131785, "compression_ratio": 1.0505050505050506, "no_speech_prob": 0.0, "words": [{"start": 905.6, "end": 906.14, "word": "سؤال", "probability": 0.7577311197916666}, {"start": 906.14, "end": 906.82, "word": " الرابع", "probability": 0.9765625}, {"start": 906.82, "end": 910.42, "word": " بيقول", "probability": 0.8253580729166666}, {"start": 910.42, "end": 910.68, "word": " لي", "probability": 0.6572265625}, {"start": 910.68, "end": 911.28, "word": " ان", "probability": 0.461181640625}, {"start": 911.28, "end": 911.66, "word": " ال", "probability": 0.80029296875}, {"start": 911.66, "end": 911.98, "word": " A", "probability": 0.31396484375}, {"start": 911.98, "end": 912.5, "word": " N", "probability": 0.728515625}, {"start": 912.5, "end": 913.62, "word": " تساوي", "probability": 0.94482421875}, {"start": 913.62, "end": 915.8, "word": " 1", "probability": 0.41943359375}, {"start": 915.8, "end": 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Limit", "probability": 0.763427734375}, {"start": 925.55, "end": 926.51, "word": " لما", "probability": 0.661376953125}, {"start": 926.51, "end": 926.83, "word": " الـ", "probability": 0.820556640625}, {"start": 926.83, "end": 927.07, "word": " N", "probability": 0.78955078125}, {"start": 927.07, "end": 927.63, "word": " بدها", "probability": 0.716064453125}, {"start": 927.63, "end": 928.43, "word": " تذهب", "probability": 0.9371744791666666}, {"start": 928.43, "end": 929.21, "word": " إلى", "probability": 0.79052734375}, {"start": 929.21, "end": 930.33, "word": " المالة", "probability": 0.6551106770833334}, {"start": 930.33, "end": 930.99, "word": " نهائيا", "probability": 0.6578369140625}, {"start": 930.99, "end": 932.17, "word": " لمن؟", "probability": 0.72802734375}, {"start": 932.17, "end": 933.03, "word": " لواحد", "probability": 0.7449544270833334}, {"start": 933.03, "end": 933.49, "word": " على", "probability": 0.7744140625}, {"start": 933.49, "end": 934.13, "word": " جذر", "probability": 0.9150390625}, {"start": 934.13, "end": 934.53, "word": " الـ", "probability": 0.93017578125}, {"start": 934.53, "end": 934.87, "word": " N", "probability": 0.86474609375}, {"start": 934.87, "end": 936.45, "word": " لتان", "probability": 0.6535237630208334}, {"start": 936.45, "end": 937.45, "word": " Inverse", "probability": 0.6561279296875}, {"start": 937.45, "end": 937.95, "word": " N", "probability": 0.92919921875}, {"start": 937.95, "end": 938.97, "word": " لو", "probability": 0.6298828125}, {"start": 938.97, "end": 939.31, "word": " جينا", "probability": 0.8958333333333334}, {"start": 939.31, "end": 939.83, "word": " نعوض", "probability": 0.87890625}, {"start": 939.83, "end": 940.35, "word": " تعوض", "probability": 0.8419596354166666}, {"start": 940.35, "end": 941.57, "word": " مباشر", "probability": 0.984619140625}, {"start": 941.57, "end": 942.25, "word": " بصير", "probability": 0.7278645833333334}, {"start": 942.25, "end": 942.63, "word": " هنا", "probability": 0.97705078125}, {"start": 942.63, "end": 943.65, "word": " واحد", "probability": 0.95361328125}, {"start": 943.65, "end": 944.41, "word": " على", "probability": 0.8701171875}, {"start": 944.41, "end": 945.97, "word": " Infinity", "probability": 0.61767578125}], "temperature": 1.0}, {"id": 43, "seek": 97625, "start": 948.31, "end": 976.25, "text": "زيرو طيب هنا ten inverse infinity التان لما الان بتروح للملعك ده شو يساوي؟ باي على اتنين يبقى الناتج يساوي قدرش؟ Zero يبقى هنا the sequence اللي هي واحد على جدر الان تان inverse ان convert السؤال الخامس", "tokens": [11622, 13546, 2407, 23032, 1829, 3555, 34105, 2064, 17340, 13202, 16712, 7649, 5296, 15042, 2423, 7649, 39894, 32887, 5016, 5296, 19528, 1211, 3615, 4117, 11778, 3224, 13412, 2407, 7251, 3794, 995, 45865, 22807, 4724, 47302, 15844, 1975, 2655, 1863, 9957, 7251, 3555, 4587, 7578, 2423, 8315, 2655, 7435, 7251, 3794, 995, 45865, 12174, 3215, 2288, 8592, 22807, 17182, 7251, 3555, 4587, 7578, 34105, 264, 8310, 13672, 1829, 39896, 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"word": " Zero", "probability": 0.3916015625}, {"start": 962.47, "end": 963.47, "word": " يبقى", "probability": 0.96044921875}, {"start": 963.47, "end": 963.81, "word": " هنا", "probability": 0.99267578125}, {"start": 963.81, "end": 964.29, "word": " the", "probability": 0.271484375}, {"start": 964.29, "end": 966.41, "word": " sequence", "probability": 0.658203125}, {"start": 966.41, "end": 967.15, "word": " اللي", "probability": 0.888427734375}, {"start": 967.15, "end": 967.39, "word": " هي", "probability": 0.7373046875}, {"start": 967.39, "end": 968.03, "word": " واحد", "probability": 0.98388671875}, {"start": 968.03, "end": 968.57, "word": " على", "probability": 0.76025390625}, {"start": 968.57, "end": 969.21, "word": " جدر", "probability": 0.9248046875}, {"start": 969.21, "end": 969.93, "word": " الان", "probability": 0.864013671875}, {"start": 969.93, "end": 970.97, "word": " تان", "probability": 0.6517333984375}, {"start": 970.97, "end": 971.91, "word": " inverse", "probability": 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بيقول", "probability": 0.9088541666666666}, {"start": 981.67, "end": 982.89, "word": " ان", "probability": 0.05535888671875}, {"start": 982.89, "end": 984.95, "word": " يساوي", "probability": 0.85205078125}, {"start": 984.95, "end": 985.65, "word": " لن", "probability": 0.935546875}, {"start": 985.65, "end": 986.59, "word": " الان", "probability": 0.718994140625}, {"start": 986.59, "end": 987.83, "word": " على", "probability": 0.63720703125}, {"start": 987.83, "end": 988.45, "word": " لن", "probability": 0.993896484375}, {"start": 988.45, "end": 989.35, "word": " اتنين", "probability": 0.917724609375}, {"start": 989.35, "end": 989.89, "word": " ان", "probability": 0.71044921875}], "temperature": 1.0}, {"id": 45, "seek": 101609, "start": 992.55, "end": 1016.09, "text": "بارضه بنفس الطريقة بنروح ناخد limit لما ال N tends to infinity لإن ال N على لين اتنين N التعويض المباشر لو جيت حسبت له limit بيعطيني جداش infinity على infinity بقدر استخدم قاعدة Lobital مباشرة", "tokens": [3555, 9640, 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{"start": 1002.51, "end": 1003.55, "word": " اتنين", "probability": 0.8900146484375}, {"start": 1003.55, "end": 1004.01, "word": " N", "probability": 0.83056640625}, {"start": 1004.01, "end": 1005.47, "word": " التعويض", "probability": 0.8631591796875}, {"start": 1005.47, "end": 1006.35, "word": " المباشر", "probability": 0.9951171875}, {"start": 1006.35, "end": 1006.91, "word": " لو", "probability": 0.83251953125}, {"start": 1006.91, "end": 1007.17, "word": " جيت", "probability": 0.951416015625}, {"start": 1007.17, "end": 1007.71, "word": " حسبت", "probability": 0.79150390625}, {"start": 1007.71, "end": 1007.79, "word": " له", "probability": 0.31640625}, {"start": 1007.79, "end": 1008.07, "word": " limit", "probability": 0.830078125}, {"start": 1008.07, "end": 1008.67, "word": " بيعطيني", "probability": 0.75751953125}, {"start": 1008.67, "end": 1009.27, "word": " جداش", "probability": 0.8103841145833334}, {"start": 1009.27, "end": 1010.95, "word": " infinity", "probability": 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{"start": 1031.89, "end": 1032.23, "word": " على", "probability": 0.6142578125}, {"start": 1032.23, "end": 1032.75, "word": " ان", "probability": 0.37109375}, {"start": 1032.75, "end": 1033.29, "word": " على", "probability": 0.64697265625}, {"start": 1033.29, "end": 1034.01, "word": " واحد", "probability": 0.9814453125}, {"start": 1034.01, "end": 1034.33, "word": " على", "probability": 0.8935546875}, {"start": 1034.33, "end": 1034.71, "word": " ان", "probability": 0.8369140625}, {"start": 1034.71, "end": 1034.85, "word": " اللي", "probability": 0.81494140625}, {"start": 1034.85, "end": 1034.99, "word": " هو", "probability": 0.990234375}, {"start": 1034.99, "end": 1035.71, "word": " بقدهش", "probability": 0.8125}, {"start": 1035.71, "end": 1037.23, "word": " واحد", "probability": 0.888427734375}, {"start": 1037.23, "end": 1038.01, "word": " صحيح", "probability": 0.9254150390625}, {"start": 1038.01, "end": 1038.99, "word": " يبقى", "probability": 0.83447265625}, {"start": 1038.99, "end": 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106880, "start": 1056.88, "end": 1068.8, "text": "الثالث سادس بيقول الشكل الحد النوني AN بيساوي N في واحد ناقص cosine واحد على M", "tokens": [6027, 12984, 6027, 12984, 8608, 18513, 3794, 4724, 1829, 39648, 25124, 28820, 21542, 3215, 28239, 11536, 1829, 5252, 4724, 1829, 3794, 995, 45865, 426, 8978, 36764, 24401, 8717, 995, 4587, 9381, 23565, 36764, 24401, 15844, 376], "avg_logprob": -0.3323479665292276, "compression_ratio": 1.2476190476190476, "no_speech_prob": 0.0, "words": [{"start": 1056.88, "end": 1057.56, "word": "الثالث", "probability": 0.7557373046875}, {"start": 1057.56, "end": 1058.0, "word": " سادس", "probability": 0.74609375}, {"start": 1058.0, "end": 1058.52, "word": " بيقول", "probability": 0.8492838541666666}, {"start": 1058.52, "end": 1059.38, "word": " الشكل", "probability": 0.735107421875}, {"start": 1059.38, "end": 1060.0, "word": " الحد", "probability": 0.83740234375}, {"start": 1060.0, "end": 1060.64, "word": " النوني", "probability": 0.8505859375}, {"start": 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واحد على N لو جينا عوضنا التعويض مباشر يبقى هذا بيعطيني infinity P", "tokens": [1829, 3555, 4587, 7578, 45164, 10874, 1829, 8315, 5551, 9778, 3215, 8315, 2423, 4948, 46740, 15730, 21542, 3215, 7251, 3555, 4587, 7578, 4948, 5296, 15042, 2423, 426, 12258, 281, 13202, 5296, 426, 36764, 24401, 8717, 995, 4587, 9381, 23565, 36764, 24401, 15844, 426, 45164, 10874, 1829, 8315, 6225, 2407, 11242, 8315, 16712, 3615, 45865, 11242, 3714, 3555, 33599, 2288, 7251, 3555, 4587, 7578, 23758, 4724, 1829, 3615, 9566, 9957, 1829, 13202, 430], "avg_logprob": -0.2208904060598922, "compression_ratio": 1.6233766233766234, "no_speech_prob": 0.0, "words": [{"start": 1071.78, "end": 1072.16, "word": "يبقى", "probability": 0.618408203125}, {"start": 1072.16, "end": 1072.4, "word": " لو", "probability": 0.6689453125}, {"start": 1072.4, "end": 1072.84, "word": " جينا", "probability": 0.8927408854166666}, {"start": 1072.84, "end": 1073.8, "word": " أخدنا", "probability": 0.82891845703125}, {"start": 1073.8, "end": 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"probability": 0.966796875}, {"start": 1080.48, "end": 1080.86, "word": " N", "probability": 0.61962890625}, {"start": 1080.86, "end": 1081.92, "word": " واحد", "probability": 0.77587890625}, {"start": 1081.92, "end": 1082.6, "word": " ناقص", "probability": 0.9443359375}, {"start": 1082.6, "end": 1083.4, "word": " cosine", "probability": 0.7275390625}, {"start": 1083.4, "end": 1084.3, "word": " واحد", "probability": 0.931396484375}, {"start": 1084.3, "end": 1084.6, "word": " على", "probability": 0.73193359375}, {"start": 1084.6, "end": 1085.02, "word": " N", "probability": 0.8212890625}, {"start": 1085.02, "end": 1086.06, "word": " لو", "probability": 0.6337890625}, {"start": 1086.06, "end": 1086.36, "word": " جينا", "probability": 0.99462890625}, {"start": 1086.36, "end": 1086.9, "word": " عوضنا", "probability": 0.925537109375}, {"start": 1086.9, "end": 1087.44, "word": " التعويض", "probability": 0.8536376953125}, {"start": 1087.44, "end": 1088.08, "word": " مباشر", "probability": 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{"start": 1095.3, "end": 1095.94, "word": " بواحد", "probability": 0.78759765625}, {"start": 1095.94, "end": 1096.3, "word": " واحد", "probability": 0.914306640625}, {"start": 1096.3, "end": 1096.82, "word": " ناقص", "probability": 0.83526611328125}, {"start": 1096.82, "end": 1097.1, "word": " واحد", "probability": 0.98388671875}, {"start": 1097.1, "end": 1097.58, "word": " يساوي", "probability": 0.9569091796875}, {"start": 1097.58, "end": 1098.38, "word": " جداش", "probability": 0.629150390625}, {"start": 1098.38, "end": 1099.96, "word": " يساوي", "probability": 0.8861083984375}, {"start": 1099.96, "end": 1100.74, "word": " zero", "probability": 0.64990234375}, {"start": 1100.74, "end": 1101.8, "word": " يبقى", "probability": 0.938232421875}, {"start": 1101.8, "end": 1102.22, "word": " بناء", "probability": 0.95654296875}, {"start": 1102.22, "end": 1102.82, "word": " عليه", "probability": 0.9228515625}, {"start": 1102.82, "end": 1104.02, "word": " بنستخدم", "probability": 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قبل هيك اليمين اللي هي واحد على N", "tokens": [1211, 15042, 2423, 39184, 426, 12258, 281, 13202, 5296, 14407, 24401, 8717, 995, 4587, 9381, 23565, 36764, 24401, 15844, 426, 37037, 24192, 8717, 25957, 1211, 5296, 11296, 12174, 36150, 39896, 4117, 2423, 32640, 9957, 13672, 1829, 39896, 36764, 24401, 15844, 426], "avg_logprob": -0.44382440334274653, "compression_ratio": 1.3728813559322033, "no_speech_prob": 0.0, "words": [{"start": 1118.05, "end": 1118.59, "word": "لما", "probability": 0.53656005859375}, {"start": 1118.59, "end": 1118.83, "word": " الـ", "probability": 0.558837890625}, {"start": 1118.83, "end": 1119.17, "word": " N", "probability": 0.42529296875}, {"start": 1119.17, "end": 1119.51, "word": " tends", "probability": 0.57958984375}, {"start": 1119.51, "end": 1119.81, "word": " to", "probability": 0.96142578125}, {"start": 1119.81, "end": 1120.77, "word": " infinity", "probability": 0.7353515625}, {"start": 1120.77, "end": 1122.17, "word": " لواحد", "probability": 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sin", "probability": 0.221923828125}, {"start": 1451.04, "end": 1452.02, "word": " تربيع", "probability": 0.917724609375}, {"start": 1452.02, "end": 1452.22, "word": " ال", "probability": 0.7744140625}, {"start": 1452.22, "end": 1452.56, "word": " N", "probability": 0.806640625}, {"start": 1452.56, "end": 1452.92, "word": " على", "probability": 0.8564453125}, {"start": 1452.92, "end": 1453.58, "word": " 2", "probability": 0.5390625}, {"start": 1453.58, "end": 1454.2, "word": " أُس", "probability": 0.7499186197916666}, {"start": 1454.2, "end": 1454.52, "word": " M", "probability": 0.63818359375}, {"start": 1454.52, "end": 1455.58, "word": " أقل", "probability": 0.9685872395833334}, {"start": 1455.58, "end": 1455.82, "word": " من", "probability": 0.9951171875}, {"start": 1455.82, "end": 1456.28, "word": " 1", "probability": 0.974609375}, {"start": 1456.28, "end": 1456.84, "word": " على", "probability": 0.904296875}, {"start": 1456.84, "end": 1457.46, "word": " 2", "probability": 0.98046875}, {"start": 1457.46, "end": 1458.46, "word": " أُس", "probability": 0.9637044270833334}, {"start": 1458.46, "end": 1458.7, "word": " M", "probability": 0.9892578125}], "temperature": 1.0}, {"id": 67, "seek": 148162, "start": 1459.38, "end": 1481.62, "text": "خُد ال limit للثلاثة أطرات limit ال constant بال constant itself وهذا limit لما ال N tends to infinity لsin تربيع ال N على ال 2 أُس M وهذا limit لما ال N tends to infinity ل1 على ال 2 أُس M", "tokens": [9778, 10859, 3215, 2423, 4948, 24976, 12984, 1211, 5718, 104, 3660, 5551, 9566, 2288, 9307, 4948, 2423, 5754, 20666, 5754, 2564, 37037, 15730, 4948, 5296, 15042, 2423, 426, 12258, 281, 13202, 5296, 19767, 6055, 2288, 21292, 3615, 2423, 426, 15844, 2423, 568, 5551, 10859, 3794, 376, 37037, 15730, 4948, 5296, 15042, 2423, 426, 12258, 281, 13202, 5296, 16, 15844, 2423, 568, 5551, 10859, 3794, 376], "avg_logprob": -0.23177083694573605, "compression_ratio": 1.7517241379310344, "no_speech_prob": 0.0, "words": [{"start": 1459.38, "end": 1459.98, "word": "خُد", "probability": 0.7057291666666666}, {"start": 1459.98, "end": 1460.18, "word": " ال", "probability": 0.74072265625}, {"start": 1460.18, "end": 1460.54, "word": " limit", "probability": 0.65771484375}, {"start": 1460.54, "end": 1461.6, "word": " للثلاثة", "probability": 0.90625}, {"start": 1461.6, "end": 1462.2, "word": " أطرات", "probability": 0.8211669921875}, {"start": 1462.2, "end": 1462.92, "word": " limit", "probability": 0.46826171875}, {"start": 1462.92, "end": 1463.24, "word": " ال", "probability": 0.83251953125}, {"start": 1463.24, "end": 1463.94, "word": " constant", "probability": 0.9697265625}, {"start": 1463.94, "end": 1464.22, "word": " بال", "probability": 0.98876953125}, {"start": 1464.22, "end": 1464.84, "word": " constant", "probability": 0.90673828125}, {"start": 1464.84, "end": 1465.92, "word": " itself", "probability": 0.71240234375}, {"start": 1465.92, "end": 1466.86, "word": " وهذا", "probability": 0.799072265625}, 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"probability": 0.71875}, {"start": 1479.18, "end": 1479.78, "word": " على", "probability": 0.76123046875}, {"start": 1479.78, "end": 1480.0, "word": " ال", "probability": 0.70751953125}, {"start": 1480.0, "end": 1480.6, "word": " 2", "probability": 0.9677734375}, {"start": 1480.6, "end": 1481.28, "word": " أُس", "probability": 0.9803059895833334}, {"start": 1481.28, "end": 1481.62, "word": " M", "probability": 0.91650390625}], "temperature": 1.0}, {"id": 68, "seek": 150694, "start": 1482.62, "end": 1506.94, "text": "طيب هذا باعتبار واحد على مالة نهاية بقداش صار limit ال sequence الأولى ب zero والأخيرة ب zero ال sandwich theorem ال limit اللى فى النص بقداش فبقى اجيب اقوله هنا by sandwich theorem ال limit", "tokens": [9566, 1829, 3555, 23758, 4724, 995, 34268, 3555, 9640, 36764, 24401, 15844, 3714, 6027, 3660, 8717, 11296, 10632, 4724, 28543, 33599, 20328, 9640, 4948, 2423, 8310, 16247, 12610, 7578, 4724, 4018, 16070, 10721, 9778, 48923, 4724, 4018, 2423, 11141, 20904, 2423, 4948, 13672, 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"probability": 0.796875}, {"start": 1493.26, "end": 1493.42, "word": " ال", "probability": 0.50830078125}, {"start": 1493.42, "end": 1493.66, "word": " limit", "probability": 0.95458984375}, {"start": 1493.66, "end": 1493.84, "word": " اللى", "probability": 0.6435546875}, {"start": 1493.84, "end": 1494.0, "word": " فى", "probability": 0.806884765625}, {"start": 1494.0, "end": 1494.26, "word": " النص", "probability": 0.924072265625}, {"start": 1494.26, "end": 1495.12, "word": " بقداش", "probability": 0.8644205729166666}, {"start": 1495.12, "end": 1496.14, "word": " فبقى", "probability": 0.76904296875}, {"start": 1496.14, "end": 1496.4, "word": " اجيب", "probability": 0.67681884765625}, {"start": 1496.4, "end": 1496.92, "word": " اقوله", "probability": 0.8463541666666666}, {"start": 1496.92, "end": 1497.24, "word": " هنا", "probability": 0.9892578125}, {"start": 1497.24, "end": 1498.12, "word": " by", "probability": 0.7109375}, {"start": 1498.12, "end": 1500.92, "word": " sandwich", 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194043, "start": 1913.59, "end": 1940.43, "text": "الـ limit لما ال N tends to infinity لل N factorial على N to the power N بديه يسوي ال limit لما ال N tends to infinity لل N في N نقص واحد في N نقص اتنين في تلاتة في اتنين في واحد على N في N في N في N بديه يسوي جداش", "tokens": [6027, 39184, 4948, 5296, 15042, 2423, 426, 12258, 281, 13202, 24976, 426, 36916, 15844, 426, 281, 264, 1347, 426, 4724, 16254, 3224, 7251, 3794, 45865, 2423, 4948, 5296, 15042, 2423, 426, 12258, 281, 13202, 24976, 426, 8978, 426, 8717, 4587, 9381, 36764, 24401, 8978, 426, 8717, 4587, 9381, 1975, 2655, 1863, 9957, 8978, 6055, 1211, 9307, 3660, 8978, 1975, 2655, 1863, 9957, 8978, 36764, 24401, 15844, 426, 8978, 426, 8978, 426, 8978, 426, 4724, 16254, 3224, 7251, 3794, 45865, 10874, 3215, 33599], "avg_logprob": -0.2123494011810027, "compression_ratio": 1.9119496855345912, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1913.59, "end": 1914.13, "word": "الـ", "probability": 0.28057861328125}, {"start": 1914.13, "end": 1914.59, "word": " limit", "probability": 0.470458984375}, {"start": 1914.59, "end": 1915.59, "word": " لما", "probability": 0.863525390625}, {"start": 1915.59, "end": 1915.81, "word": " ال", "probability": 0.9482421875}, {"start": 1915.81, "end": 1916.03, "word": " N", "probability": 0.329345703125}, {"start": 1916.03, "end": 1916.43, "word": " tends", "probability": 0.252685546875}, {"start": 1916.43, "end": 1916.67, "word": " to", "probability": 0.8984375}, {"start": 1916.67, "end": 1917.35, "word": " infinity", "probability": 0.84375}, {"start": 1917.35, "end": 1917.75, "word": " لل", "probability": 0.6201171875}, {"start": 1917.75, "end": 1918.21, "word": " N", "probability": 0.85693359375}, {"start": 1918.21, "end": 1919.21, "word": " factorial", "probability": 0.6416015625}, {"start": 1919.21, "end": 1920.11, "word": " على", "probability": 0.69287109375}, {"start": 1920.11, "end": 1920.57, "word": " N", "probability": 0.93017578125}, {"start": 1920.57, "end": 1920.75, "word": " to", "probability": 0.89404296875}, {"start": 1920.75, "end": 1921.01, "word": " the", "probability": 0.921875}, {"start": 1921.01, "end": 1921.57, "word": " power", "probability": 0.88330078125}, {"start": 1921.57, "end": 1922.13, "word": " N", "probability": 0.9189453125}, {"start": 1922.13, "end": 1922.87, "word": " بديه", "probability": 0.5072428385416666}, {"start": 1922.87, "end": 1923.23, "word": " يسوي", "probability": 0.8317057291666666}, {"start": 1923.23, "end": 1923.39, "word": " ال", "probability": 0.75927734375}, {"start": 1923.39, "end": 1923.69, "word": " limit", "probability": 0.66650390625}, {"start": 1923.69, "end": 1924.27, "word": " لما", "probability": 0.96533203125}, {"start": 1924.27, "end": 1924.51, "word": " ال", "probability": 0.86962890625}, {"start": 1924.51, "end": 1924.81, "word": " N", "probability": 0.98046875}, {"start": 1924.81, "end": 1925.19, "word": " tends", "probability": 0.39404296875}, {"start": 1925.19, "end": 1926.67, "word": " to", "probability": 0.9658203125}, {"start": 1926.67, "end": 1927.27, "word": " infinity", "probability": 0.90576171875}, {"start": 1927.27, "end": 1928.07, "word": " لل", "probability": 0.74951171875}, {"start": 1928.07, "end": 1928.57, "word": " N", "probability": 0.96142578125}, {"start": 1928.57, "end": 1928.81, "word": " في", "probability": 0.779296875}, {"start": 1928.81, "end": 1929.07, "word": " N", "probability": 0.96435546875}, {"start": 1929.07, "end": 1929.61, "word": " نقص", "probability": 0.80517578125}, {"start": 1929.61, "end": 1930.11, "word": " واحد", "probability": 0.870849609375}, {"start": 1930.11, "end": 1930.33, "word": " في", "probability": 0.93212890625}, {"start": 1930.33, "end": 1930.57, "word": " N", "probability": 0.98193359375}, {"start": 1930.57, "end": 1931.11, "word": " نقص", "probability": 0.9943033854166666}, {"start": 1931.11, "end": 1931.73, "word": " اتنين", "probability": 0.969482421875}, {"start": 1931.73, "end": 1932.15, "word": " في", "probability": 0.9326171875}, {"start": 1932.15, "end": 1932.85, "word": " تلاتة", "probability": 0.9140625}, {"start": 1932.85, "end": 1932.99, "word": " في", "probability": 0.96337890625}, {"start": 1932.99, "end": 1933.73, "word": " اتنين", "probability": 0.984130859375}, {"start": 1933.73, "end": 1934.01, "word": " في", "probability": 0.98095703125}, {"start": 1934.01, "end": 1934.81, "word": " واحد", "probability": 0.991455078125}, {"start": 1934.81, "end": 1935.63, "word": " على", "probability": 0.7763671875}, {"start": 1935.63, "end": 1936.25, "word": " N", "probability": 0.9794921875}, {"start": 1936.25, "end": 1936.47, "word": " في", "probability": 0.96435546875}, {"start": 1936.47, "end": 1936.97, "word": " N", "probability": 0.9951171875}, {"start": 1936.97, "end": 1937.33, "word": " في", "probability": 0.97119140625}, {"start": 1937.33, "end": 1937.77, "word": " N", "probability": 0.9912109375}, {"start": 1937.77, "end": 1938.17, "word": " في", "probability": 0.96630859375}, {"start": 1938.17, "end": 1938.57, "word": " N", "probability": 0.90625}, {"start": 1938.57, "end": 1939.35, "word": " بديه", "probability": 0.9523111979166666}, {"start": 1939.35, "end": 1939.63, "word": " يسوي", "probability": 0.9469401041666666}, {"start": 1939.63, "end": 1940.43, "word": " جداش", "probability": 0.70703125}], "temperature": 1.0}, {"id": 86, "seek": 196685, "start": 1940.69, "end": 1966.85, "text": "زيرو مادام زيرو يبقى هنا ساعة the sequence اللي هي مين ال N factorial على N to the power N convert يبقى هنا يحط هناك بدل المثال اتنين على مين على ال sandwich third الآن بنيجي لنقطة very important", "tokens": [11622, 13546, 2407, 3714, 18513, 10943, 30767, 13546, 2407, 7251, 3555, 4587, 7578, 34105, 8608, 995, 27884, 264, 8310, 13672, 1829, 39896, 3714, 9957, 2423, 426, 36916, 15844, 426, 281, 264, 1347, 426, 7620, 7251, 3555, 4587, 7578, 34105, 7251, 5016, 9566, 34105, 4117, 47525, 1211, 9673, 12984, 6027, 1975, 2655, 1863, 9957, 15844, 3714, 9957, 15844, 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1947.67, "word": " هي", "probability": 0.86083984375}, {"start": 1947.67, "end": 1948.09, "word": " مين", "probability": 0.60833740234375}, {"start": 1948.09, "end": 1949.67, "word": " ال", "probability": 0.8544921875}, {"start": 1949.67, "end": 1950.05, "word": " N", "probability": 0.462646484375}, {"start": 1950.05, "end": 1950.89, "word": " factorial", "probability": 0.5126953125}, {"start": 1950.89, "end": 1951.81, "word": " على", "probability": 0.64453125}, {"start": 1951.81, "end": 1952.29, "word": " N", "probability": 0.474853515625}, {"start": 1952.29, "end": 1952.53, "word": " to", "probability": 0.89599609375}, {"start": 1952.53, "end": 1952.81, "word": " the", "probability": 0.93115234375}, {"start": 1952.81, "end": 1953.27, "word": " power", "probability": 0.87744140625}, {"start": 1953.27, "end": 1953.91, "word": " N", "probability": 0.8525390625}, {"start": 1953.91, "end": 1955.47, "word": " convert", "probability": 0.8212890625}, {"start": 1955.47, "end": 1956.97, "word": " يبقى", "probability": 0.9671630859375}, {"start": 1956.97, "end": 1957.11, "word": " هنا", "probability": 0.405029296875}, {"start": 1957.11, "end": 1957.35, "word": " يحط", "probability": 0.5399169921875}, {"start": 1957.35, "end": 1957.65, "word": " هناك", "probability": 0.9072265625}, {"start": 1957.65, "end": 1958.01, "word": " بدل", "probability": 0.925048828125}, {"start": 1958.01, "end": 1958.51, "word": " المثال", "probability": 0.9816080729166666}, {"start": 1958.51, "end": 1959.13, "word": " اتنين", "probability": 0.95654296875}, {"start": 1959.13, "end": 1959.77, "word": " على", "probability": 0.861328125}, {"start": 1959.77, "end": 1960.31, "word": " مين", "probability": 0.9052734375}, {"start": 1960.31, "end": 1960.89, "word": " على", "probability": 0.791015625}, {"start": 1960.89, "end": 1961.15, "word": " ال", "probability": 0.60498046875}, {"start": 1961.15, "end": 1961.95, "word": " sandwich", "probability": 0.74755859375}, {"start": 1961.95, "end": 1962.55, "word": " third", "probability": 0.1707763671875}, {"start": 1962.55, "end": 1963.65, "word": " الآن", "probability": 0.685546875}, {"start": 1963.65, "end": 1964.13, "word": " بنيجي", "probability": 0.8619384765625}, {"start": 1964.13, "end": 1964.95, "word": " لنقطة", "probability": 0.908447265625}, {"start": 1964.95, "end": 1965.59, "word": " very", "probability": 0.87158203125}, {"start": 1965.59, "end": 1966.85, "word": " important", "probability": 0.95751953125}], "temperature": 1.0}, {"id": 87, "seek": 199911, "start": 1970.05, "end": 1999.11, "text": "النقطة بتقول المادة دي هحطها لك في صيغة ال remark التالية remark if ال sequence a n is converge or diverge sequence then ال c في ال a n", "tokens": [6027, 1863, 47432, 3660, 39894, 39648, 9673, 18513, 3660, 11778, 1829, 8032, 5016, 9566, 11296, 5296, 4117, 8978, 20328, 1829, 17082, 3660, 2423, 7942, 16712, 6027, 10632, 7942, 498, 2423, 8310, 257, 297, 307, 41881, 420, 18558, 432, 8310, 550, 2423, 269, 8978, 2423, 257, 297], "avg_logprob": -0.3188164880935182, "compression_ratio": 1.362962962962963, "no_speech_prob": 0.0, "words": [{"start": 1970.05, "end": 1970.69, "word": "النقطة", "probability": 0.83758544921875}, {"start": 1970.69, "end": 1971.17, "word": " بتقول", "probability": 0.794677734375}, {"start": 1971.17, "end": 1971.75, "word": " المادة", "probability": 0.605224609375}, {"start": 1971.75, "end": 1971.87, "word": " دي", "probability": 0.762939453125}, {"start": 1971.87, "end": 1972.23, "word": " هحطها", "probability": 0.72808837890625}, {"start": 1972.23, "end": 1972.45, "word": " لك", "probability": 0.859619140625}, {"start": 1972.45, "end": 1972.57, "word": " في", "probability": 0.88916015625}, {"start": 1972.57, "end": 1972.97, "word": " صيغة", "probability": 0.66778564453125}, {"start": 1972.97, "end": 1973.15, "word": " ال", "probability": 0.796875}, {"start": 1973.15, "end": 1973.59, "word": " remark", "probability": 0.439697265625}, {"start": 1973.59, "end": 1974.37, "word": " التالية", "probability": 0.9832356770833334}, {"start": 1974.37, "end": 1975.21, "word": " remark", "probability": 0.6162109375}, {"start": 1975.21, "end": 1979.31, "word": " if", "probability": 0.677734375}, {"start": 1979.31, "end": 1981.41, "word": " ال", "probability": 0.81298828125}, {"start": 1981.41, "end": 1982.17, "word": " sequence", "probability": 0.962890625}, {"start": 1982.17, "end": 1982.85, "word": " a", "probability": 0.31005859375}, {"start": 1982.85, "end": 1983.51, "word": " n", "probability": 0.361328125}, {"start": 1983.51, "end": 1985.33, "word": " is", "probability": 0.93310546875}, {"start": 1985.33, "end": 1987.37, "word": " converge", "probability": 0.6201171875}, {"start": 1987.37, "end": 1989.55, "word": " or", "probability": 0.78076171875}, {"start": 1989.55, "end": 1991.73, "word": " diverge", "probability": 0.75}, {"start": 1991.73, "end": 1992.79, "word": " sequence", "probability": 0.96533203125}, {"start": 1992.79, "end": 1994.53, "word": " then", "probability": 0.81884765625}, {"start": 1994.53, "end": 1996.91, "word": " ال", "probability": 0.84423828125}, {"start": 1996.91, "end": 1997.29, "word": " c", "probability": 0.640625}, {"start": 1997.29, "end": 1997.65, "word": " في", "probability": 0.91552734375}, {"start": 1997.65, "end": 1997.97, "word": " ال", "probability": 0.96142578125}, {"start": 1997.97, "end": 1998.43, "word": " a", "probability": 0.953125}, {"start": 1998.43, "end": 1999.11, "word": " n", "probability": 0.783203125}], "temperature": 1.0}, {"id": 88, "seek": 202562, "start": 2000.36, "end": 2025.62, "text": "هو convergent او divergent ثم هو convergent او divergent سيقونس حيث ان C هو مستوى غير صحيح", "tokens": [3224, 2407, 9652, 6930, 1975, 2407, 18558, 6930, 38637, 2304, 31439, 9652, 6930, 1975, 2407, 18558, 6930, 8608, 1829, 4587, 11536, 3794, 11331, 1829, 12984, 16472, 383, 31439, 3714, 14851, 2407, 7578, 32771, 13546, 20328, 5016, 1829, 5016], "avg_logprob": -0.7427884737650553, "compression_ratio": 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"end": 2089.34, "text": "و ال sequence كانت هذه converge ضربتها في constant لا يساوي ال zero ظهرت sequence جديدة يبقى ال sequence هذه مالها converge إذا ال sequence هذه كانت diverge و ضربتها في constant تظهر sequence جديدة هذه ال sequence مالها بالبلد هيك ضرب ال sequence في constant لا يؤثر على ال convergence ولا على ال divergence لهذه ال sequence", "tokens": [2407, 2423, 8310, 25961, 2655, 29538, 41881, 48812, 25513, 2655, 11296, 8978, 5754, 20193, 7251, 3794, 995, 45865, 2423, 4018, 1357, 116, 3224, 43500, 8310, 10874, 16254, 41891, 7251, 3555, 4587, 7578, 2423, 8310, 29538, 3714, 6027, 11296, 41881, 11933, 15730, 2423, 8310, 29538, 25961, 2655, 18558, 432, 4032, 48812, 25513, 2655, 11296, 8978, 5754, 6055, 19913, 3224, 2288, 8310, 10874, 16254, 41891, 29538, 2423, 8310, 3714, 6027, 11296, 20666, 36150, 3215, 39896, 4117, 48812, 25513, 2423, 8310, 8978, 5754, 20193, 7251, 33604, 49115, 15844, 2423, 32181, 49429, 15844, 2423, 47387, 46740, 24192, 2423, 8310], "avg_logprob": 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لازم الأمر ست limits مشهورة من حد ما شوفها بتحكمتها حسب", "tokens": [41185, 4724, 995, 4587, 10632, 25124, 3555, 9566, 2288, 23758, 37893, 4724, 995, 4587, 10632, 2423, 3541, 4724, 995, 4587, 10632, 2423, 3541, 4032, 4724, 995, 4587, 10632, 25124, 3555, 9566, 2288, 28242, 3224, 6156, 7578, 43242, 8315, 2423, 10406, 39894, 2655, 37983, 2288, 20449, 7649, 995, 9122, 12984, 13546, 995, 10874, 28259, 37893, 28242, 3714, 25720, 47525, 8315, 8717, 9778, 20292, 4117, 6055, 4587, 22488, 6055, 4587, 22488, 6055, 5016, 35457, 16095, 5296, 10721, 47525, 8315, 8717, 5016, 9566, 16095, 9122, 4587, 995, 22488, 3660, 4032, 25062, 995, 22488, 3660, 8717, 14851, 9778, 40448, 11296, 44650, 7578, 5296, 31377, 2304, 16247, 29973, 8608, 2655, 10406, 37893, 3224, 13063, 3660, 9154, 11331, 3215, 19446, 13412, 38688, 11296, 39894, 5016, 24793, 2655, 11296, 11331, 35457], "avg_logprob": -0.20275000619888306, "compression_ratio": 1.9506726457399104, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 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infinity للجذر النوني ل N يعني limit لما ال N tends to infinity لل N أص واحد على N يسوى واحد صحيح نمر تلاتة limit", "tokens": [4197, 270, 5296, 15042, 2423, 426, 12258, 281, 13202, 24976, 7435, 8848, 2288, 28239, 11536, 1829, 5296, 426, 37495, 22653, 4948, 5296, 15042, 2423, 426, 12258, 281, 13202, 24976, 426, 5551, 9381, 36764, 24401, 15844, 426, 7251, 3794, 2407, 7578, 36764, 24401, 20328, 5016, 1829, 5016, 8717, 29973, 6055, 1211, 9307, 3660, 4948], "avg_logprob": -0.3249421219031016, "compression_ratio": 1.5275590551181102, "no_speech_prob": 0.0, "words": [{"start": 2163.36, "end": 2164.32, "word": "limit", "probability": 0.60491943359375}, {"start": 2164.32, "end": 2165.12, "word": " لما", "probability": 0.744140625}, {"start": 2165.12, "end": 2165.36, "word": " ال", "probability": 0.92333984375}, {"start": 2165.36, "end": 2165.6, "word": " N", "probability": 0.208740234375}, {"start": 2165.6, "end": 2166.0, "word": " tends", "probability": 0.56103515625}, {"start": 2166.0, "end": 2166.36, "word": " to", "probability": 0.93994140625}, {"start": 2166.36, "end": 2167.16, "word": " infinity", "probability": 0.82080078125}, {"start": 2167.16, "end": 2168.86, "word": " للجذر", "probability": 0.790283203125}, {"start": 2168.86, "end": 2170.04, "word": " النوني", "probability": 0.853515625}, {"start": 2170.04, "end": 2170.3, "word": " ل", "probability": 0.8857421875}, {"start": 2170.3, "end": 2170.86, "word": " N", "probability": 0.463134765625}, {"start": 2170.86, "end": 2171.94, "word": " يعني", "probability": 0.6678466796875}, {"start": 2171.94, "end": 2172.8, "word": " limit", "probability": 0.51953125}, {"start": 2172.8, "end": 2173.62, "word": " لما", "probability": 0.961181640625}, {"start": 2173.62, "end": 2173.86, "word": " ال", "probability": 0.8828125}, {"start": 2173.86, "end": 2174.22, "word": " N", "probability": 0.9794921875}, {"start": 2174.22, "end": 2174.46, "word": " tends", "probability": 0.74462890625}, {"start": 2174.46, "end": 2174.8, "word": " to", "probability": 0.9716796875}, {"start": 2174.8, "end": 2175.58, "word": " infinity", "probability": 0.86962890625}, {"start": 2175.58, "end": 2176.38, "word": " لل", "probability": 0.5625}, {"start": 2176.38, "end": 2176.92, "word": " N", "probability": 0.97216796875}, {"start": 2176.92, "end": 2177.58, "word": " أص", "probability": 0.31134033203125}, {"start": 2177.58, "end": 2178.1, "word": " واحد", "probability": 0.7105712890625}, {"start": 2178.1, "end": 2178.4, "word": " على", "probability": 0.7734375}, {"start": 2178.4, "end": 2178.88, "word": " N", "probability": 0.94921875}, {"start": 2178.88, "end": 2180.02, "word": " يسوى", "probability": 0.803466796875}, {"start": 2180.02, "end": 2180.72, "word": " واحد", "probability": 0.982421875}, {"start": 2180.72, "end": 2181.84, "word": " صحيح", "probability": 0.9156494140625}, {"start": 2181.84, "end": 2182.56, "word": " نمر", "probability": 0.54248046875}, {"start": 2182.56, "end": 2183.58, "word": " تلاتة", "probability": 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0.871337890625}, {"start": 2194.48, "end": 2195.24, "word": " صحيح", "probability": 0.9033203125}, {"start": 2195.24, "end": 2195.78, "word": " و", "probability": 0.46435546875}, {"start": 2195.78, "end": 2196.26, "word": " X", "probability": 0.7607421875}, {"start": 2196.26, "end": 2196.72, "word": " greater", "probability": 0.2344970703125}, {"start": 2196.72, "end": 2197.3, "word": " than", "probability": 0.93359375}, {"start": 2197.3, "end": 2197.8, "word": " zero", "probability": 0.37548828125}, {"start": 2197.8, "end": 2199.34, "word": " لمرة", "probability": 0.3150634765625}, {"start": 2199.34, "end": 2200.26, "word": " أربعة", "probability": 0.9072265625}, {"start": 2200.26, "end": 2201.34, "word": " بدنا", "probability": 0.536346435546875}, {"start": 2201.34, "end": 2201.98, "word": " limit", "probability": 0.6318359375}, {"start": 2201.98, "end": 2203.24, "word": " لل", "probability": 0.83447265625}, {"start": 2203.24, "end": 2203.76, "word": " X", "probability": 0.97314453125}, {"start": 2203.76, "end": 2204.32, "word": " أُس", "probability": 0.9069010416666666}, {"start": 2204.32, "end": 2204.78, "word": " N", "probability": 0.93115234375}, {"start": 2204.78, "end": 2205.74, "word": " لما", "probability": 0.96435546875}, {"start": 2205.74, "end": 2206.0, "word": " ال", "probability": 0.70947265625}, {"start": 2206.0, "end": 2206.24, "word": " N", "probability": 0.6474609375}, {"start": 2206.24, "end": 2206.74, "word": " tends", "probability": 0.796875}, {"start": 2206.74, "end": 2207.08, "word": " to", "probability": 0.9619140625}, {"start": 2207.08, "end": 2207.84, "word": " infinity", "probability": 0.88525390625}, {"start": 2207.84, "end": 2209.02, "word": " بيكون", "probability": 0.8714192708333334}, {"start": 2209.02, "end": 2210.12, "word": " زيرو", "probability": 0.5926920572916666}], "temperature": 1.0}, {"id": 96, "seek": 221725, "start": 2210.51, "end": 2217.25, "text": "إذا كان الـ absolute value للـ X أقل من الواحد", "tokens": 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الواحد", "probability": 0.65771484375}], "temperature": 1.0}, {"id": 97, "seek": 224475, "start": 2220.29, "end": 2244.75, "text": "limit لما ال N tends to infinity لمن؟ ل 1 زائد X على N كل هذا to the power N بده يساوي إيقص X وهنا أنا X لقي X نمرى ستة", "tokens": [4197, 270, 5296, 15042, 2423, 426, 12258, 281, 13202, 5296, 27842, 22807, 5296, 502, 30767, 16373, 3215, 1783, 15844, 426, 28242, 23758, 281, 264, 1347, 426, 47525, 3224, 7251, 3794, 995, 45865, 11933, 1829, 4587, 9381, 1783, 37037, 8315, 41850, 1783, 5296, 38436, 1783, 8717, 29973, 7578, 8608, 2655, 3660], "avg_logprob": -0.4460784442284528, "compression_ratio": 1.1724137931034482, "no_speech_prob": 0.0, "words": [{"start": 2220.29, "end": 2221.25, "word": "limit", "probability": 0.5328369140625}, {"start": 2221.25, "end": 2222.37, "word": " لما", "probability": 0.763427734375}, {"start": 2222.37, "end": 2222.61, "word": " ال", "probability": 0.88671875}, {"start": 2222.61, "end": 2222.91, "word": " N", "probability": 0.16259765625}, {"start": 2222.91, "end": 2223.35, "word": " tends", "probability": 0.56103515625}, {"start": 2223.35, "end": 2223.63, "word": " to", "probability": 0.89990234375}, {"start": 2223.63, "end": 2224.59, "word": " infinity", "probability": 0.82373046875}, {"start": 2224.59, "end": 2226.07, "word": " لمن؟", "probability": 0.4370930989583333}, {"start": 2226.07, "end": 2226.27, "word": " ل", "probability": 0.5859375}, {"start": 2226.27, "end": 2226.73, "word": " 1", "probability": 0.4521484375}, {"start": 2226.73, "end": 2227.67, "word": " زائد", "probability": 0.7815755208333334}, {"start": 2227.67, "end": 2228.17, "word": " X", "probability": 0.7255859375}, {"start": 2228.17, "end": 2228.89, "word": " على", "probability": 0.65234375}, {"start": 2228.89, "end": 2229.95, "word": " N", "probability": 0.97509765625}, {"start": 2229.95, "end": 2230.91, "word": " كل", "probability": 0.78857421875}, {"start": 2230.91, "end": 2231.61, "word": " هذا", "probability": 0.96533203125}, 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مقام بواحد يبقى start limit لما ال N بتروح لما لا واحد على N يبقى واحد على ما لا نهاية زي غير يبقى انتهينا منها مباشرة", "tokens": [15042, 20193, 12602, 11296, 10632, 16070, 2304, 4587, 10943, 4724, 15042, 20193, 8717, 11296, 10632, 11933, 15730, 44945, 28543, 2288, 8717, 14851, 9778, 40448, 12174, 995, 22488, 3660, 5296, 3555, 2655, 2288, 6055, 5172, 46958, 1211, 4724, 9381, 4724, 14407, 24401, 15844, 14739, 3224, 6055, 5172, 46958, 1211, 3714, 4587, 10943, 4724, 14407, 24401, 7251, 3555, 4587, 7578, 722, 4948, 5296, 15042, 2423, 426, 39894, 32887, 5016, 5296, 15042, 20193, 36764, 24401, 15844, 426, 7251, 3555, 4587, 7578, 36764, 24401, 15844, 19446, 20193, 8717, 11296, 10632, 30767, 1829, 32771, 13546, 7251, 3555, 4587, 7578, 16472, 47395, 1829, 8315, 9154, 11296, 3714, 3555, 33599, 25720], "avg_logprob": -0.2793154716491699, "compression_ratio": 1.9202127659574468, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2359.53, "end": 2359.87, "word": "ما", "probability": 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"word": " ال", "probability": 0.9462890625}, {"start": 2371.53, "end": 2371.65, "word": " N", "probability": 0.22998046875}, {"start": 2371.65, "end": 2372.03, "word": " بتروح", "probability": 0.9431966145833334}, {"start": 2372.03, "end": 2372.29, "word": " لما", "probability": 0.6343994140625}, {"start": 2372.29, "end": 2372.43, "word": " لا", "probability": 0.7216796875}, {"start": 2372.43, "end": 2372.77, "word": " واحد", "probability": 0.837646484375}, {"start": 2372.77, "end": 2373.01, "word": " على", "probability": 0.845703125}, {"start": 2373.01, "end": 2373.37, "word": " N", "probability": 0.6171875}, {"start": 2373.37, "end": 2373.61, "word": " يبقى", "probability": 0.9005126953125}, {"start": 2373.61, "end": 2373.83, "word": " واحد", "probability": 0.9873046875}, {"start": 2373.83, "end": 2374.03, "word": " على", "probability": 0.900390625}, {"start": 2374.03, "end": 2374.21, "word": " ما", "probability": 0.96337890625}, {"start": 2374.21, "end": 2374.31, "word": " لا", 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الـ", "probability": 0.389404296875}, {"start": 2555.98, "end": 2556.16, "word": " zero", "probability": 0.2257080078125}, {"start": 2556.16, "end": 2556.5, "word": " يعني", "probability": 0.888427734375}, {"start": 2556.5, "end": 2556.66, "word": " لو", "probability": 0.6748046875}, {"start": 2556.66, "end": 2557.32, "word": " جلبتها", "probability": 0.698486328125}, {"start": 2557.32, "end": 2558.08, "word": " بيصير", "probability": 0.70916748046875}, {"start": 2558.08, "end": 2558.94, "word": " infinity", "probability": 0.69775390625}, {"start": 2558.94, "end": 2560.02, "word": " يبقى", "probability": 0.9114990234375}, {"start": 2560.02, "end": 2560.2, "word": " لو", "probability": 0.8115234375}, {"start": 2560.2, "end": 2560.8, "word": " جاباني", "probability": 0.7215576171875}, {"start": 2560.8, "end": 2561.08, "word": " اي", "probability": 0.67919921875}, {"start": 2561.08, "end": 2561.42, "word": " سؤال", "probability": 0.9866536458333334}, {"start": 2561.42, "end": 2561.7, "word": " جالي", "probability": 0.77197265625}, {"start": 2561.7, "end": 2561.96, "word": " limit", "probability": 0.9345703125}, {"start": 2561.96, "end": 2562.26, "word": " x", "probability": 0.83203125}, {"start": 2562.26, "end": 2562.46, "word": " of", "probability": 0.0633544921875}, {"start": 2562.46, "end": 2562.66, "word": " n", "probability": 0.51025390625}, {"start": 2562.66, "end": 2562.86, "word": " على", "probability": 0.54443359375}, {"start": 2562.86, "end": 2563.04, "word": " n", "probability": 0.84130859375}, {"start": 2563.04, "end": 2563.4, "word": " factorial", "probability": 0.55908203125}, {"start": 2563.4, "end": 2563.98, "word": " بيقوليه", "probability": 0.60625}, {"start": 2563.98, "end": 2564.36, "word": " zero", "probability": 0.716796875}, {"start": 2564.36, "end": 2565.04, "word": " لكن", "probability": 0.79443359375}, {"start": 2565.04, "end": 2565.26, "word": " لو", "probability": 0.94287109375}, {"start": 2565.26, "end": 2565.52, "word": " جالي", "probability": 0.9811197916666666}, {"start": 2565.52, "end": 2565.96, "word": " limit", "probability": 0.87060546875}, {"start": 2565.96, "end": 2566.68, "word": " n", "probability": 0.74169921875}, {"start": 2566.68, "end": 2567.42, "word": " factorial", "probability": 0.771484375}, {"start": 2567.42, "end": 2567.74, "word": " على", "probability": 0.8623046875}, {"start": 2567.74, "end": 2568.04, "word": " x", "probability": 0.95556640625}, {"start": 2568.04, "end": 2568.24, "word": " to", "probability": 0.8466796875}, {"start": 2568.24, "end": 2568.4, "word": " the", "probability": 0.9169921875}, {"start": 2568.4, "end": 2568.86, "word": " power", "probability": 0.8984375}, {"start": 2568.86, "end": 2569.58, "word": " n", "probability": 0.87451171875}, {"start": 2569.58, "end": 2570.38, "word": " يبقى", "probability": 0.95947265625}, {"start": 2570.38, "end": 2570.92, "word": " ناتج", "probability": 0.63037109375}, {"start": 2570.92, "end": 2571.74, "word": " بيساوي", "probability": 0.64072265625}, {"start": 2571.74, "end": 2572.44, "word": " infinity", "probability": 0.81494140625}], "temperature": 1.0}, {"id": 112, "seek": 260184, "start": 2572.88, "end": 2601.84, "text": "وستأتيك بأمثلة على كل هدول فورا إن شاء الله يبقى نيجي ناخد أمثلة على كيفية استخدام الست هدول يبقى example بقول find the limits of the following sequences find the limits of the", "tokens": [2407, 14851, 10721, 31371, 4117, 4724, 10721, 2304, 12984, 37977, 15844, 28242, 8032, 3215, 12610, 6156, 13063, 995, 36145, 13412, 16606, 21984, 7251, 3555, 4587, 7578, 8717, 1829, 7435, 1829, 8717, 47283, 3215, 5551, 2304, 12984, 37977, 15844, 9122, 33911, 10632, 44713, 9778, 3215, 10943, 2423, 14851, 8032, 3215, 12610, 7251, 3555, 4587, 7578, 1365, 4724, 39648, 915, 264, 10406, 295, 264, 3480, 22978, 915, 264, 10406, 295, 264], "avg_logprob": -0.16785714690174375, "compression_ratio": 1.5416666666666667, "no_speech_prob": 0.0, "words": [{"start": 2572.88, "end": 2574.14, "word": "وستأتيك", "probability": 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0.99072265625}, {"start": 2581.32, "end": 2581.98, "word": " على", "probability": 0.8115234375}, {"start": 2581.98, "end": 2582.7, "word": " كيفية", "probability": 0.9864908854166666}, {"start": 2582.7, "end": 2583.58, "word": " استخدام", "probability": 0.982666015625}, {"start": 2583.58, "end": 2584.44, "word": " الست", "probability": 0.698974609375}, {"start": 2584.44, "end": 2585.1, "word": " هدول", "probability": 0.9217122395833334}, {"start": 2585.1, "end": 2586.38, "word": " يبقى", "probability": 0.9638671875}, {"start": 2586.38, "end": 2587.28, "word": " example", "probability": 0.67919921875}, {"start": 2587.28, "end": 2592.86, "word": " بقول", "probability": 0.580322265625}, {"start": 2592.86, "end": 2593.22, "word": " find", "probability": 0.705078125}, {"start": 2593.22, "end": 2593.42, "word": " the", "probability": 0.80859375}, {"start": 2593.42, "end": 2593.7, "word": " limits", "probability": 0.919921875}, {"start": 2593.7, "end": 2593.88, "word": " of", "probability": 0.9755859375}, {"start": 2593.88, "end": 2594.04, "word": " the", "probability": 0.9052734375}, {"start": 2594.04, "end": 2594.34, "word": " following", "probability": 0.78564453125}, {"start": 2594.34, "end": 2595.32, "word": " sequences", "probability": 0.943359375}, {"start": 2595.32, "end": 2596.46, "word": " find", "probability": 0.76123046875}, {"start": 2596.46, "end": 2597.56, "word": " the", "probability": 0.9189453125}, {"start": 2597.56, "end": 2599.3, "word": " limits", "probability": 0.89892578125}, {"start": 2599.3, "end": 2600.54, "word": " of", "probability": 0.9814453125}, {"start": 2600.54, "end": 2601.84, "word": " the", "probability": 0.92919921875}], "temperature": 1.0}, {"id": 113, "seek": 263155, "start": 2607.43, "end": 2631.55, "text": "Following Sequences Undetermined And Determine Its Convergence حددلي التقارب أو التباع و التباع هذه ال Sequences", "tokens": [37, 49082, 278, 46859, 2667, 2719, 35344, 2001, 400, 4237, 966, 533, 6953, 2656, 331, 15260, 11331, 3215, 3215, 20292, 16712, 4587, 9640, 3555, 34051, 16712, 3555, 45761, 4032, 16712, 3555, 45761, 29538, 2423, 46859, 2667], "avg_logprob": -0.45439189833563726, "compression_ratio": 1.2521739130434784, "no_speech_prob": 0.0, "words": [{"start": 2607.43, "end": 2608.83, "word": "Following", "probability": 0.6301981608072916}, {"start": 2608.83, "end": 2610.23, "word": " Sequences", "probability": 0.731689453125}, {"start": 2610.23, "end": 2613.87, "word": " Undetermined", "probability": 0.8263346354166666}, {"start": 2613.87, "end": 2614.53, "word": " And", "probability": 0.20703125}, {"start": 2614.53, "end": 2618.07, "word": " Determine", "probability": 0.68701171875}, {"start": 2618.07, "end": 2621.57, "word": " Its", "probability": 0.5283203125}, {"start": 2621.57, "end": 2624.19, "word": " Convergence", "probability": 0.9327799479166666}, {"start": 2624.19, "end": 2628.39, "word": " حددلي", "probability": 0.688934326171875}, {"start": 2628.39, "end": 2629.07, "word": " التقارب", "probability": 0.9722900390625}, {"start": 2629.07, "end": 2629.31, "word": " أو", "probability": 0.69482421875}, {"start": 2629.31, "end": 2629.79, "word": " التباع", "probability": 0.774169921875}, {"start": 2629.79, "end": 2629.91, "word": " و", "probability": 0.2022705078125}, {"start": 2629.91, "end": 2630.25, "word": " التباع", "probability": 0.89794921875}, {"start": 2630.25, "end": 2630.57, "word": " هذه", "probability": 0.81201171875}, {"start": 2630.57, "end": 2630.77, "word": " ال", "probability": 0.80712890625}, {"start": 2630.77, "end": 2631.55, "word": " Sequences", "probability": 0.5037841796875}], "temperature": 1.0}, {"id": 114, "seek": 265458, "start": 2632.08, "end": 2654.58, "text": "أول واحدة نمرة A الـ A N بدي ساوي الجذر النوني لتلاتة Int كيب بقوله كويس بدي أخد ال limit لهذه ال sequence يبقى بعدي بقوله ال limit لما ال Int is to infinity", "tokens": [10721, 12610, 36764, 24401, 3660, 8717, 2304, 25720, 316, 2423, 39184, 316, 426, 4724, 16254, 8608, 995, 45865, 25724, 8848, 2288, 28239, 11536, 1829, 5296, 2655, 1211, 9307, 3660, 5681, 9122, 1829, 3555, 4724, 39648, 3224, 9122, 45865, 3794, 4724, 16254, 5551, 9778, 3215, 2423, 4948, 46740, 24192, 2423, 8310, 7251, 3555, 4587, 7578, 39182, 1829, 4724, 39648, 3224, 2423, 4948, 5296, 15042, 2423, 5681, 307, 281, 13202], "avg_logprob": -0.38609602658644965, "compression_ratio": 1.4666666666666666, "no_speech_prob": 0.0, "words": [{"start": 2632.08, "end": 2632.6, "word": "أول", "probability": 0.7315673828125}, {"start": 2632.6, "end": 2633.14, "word": " واحدة", "probability": 0.890625}, {"start": 2633.14, "end": 2633.6, "word": " نمرة", "probability": 0.3307291666666667}, {"start": 2633.6, "end": 2634.0, "word": " A", "probability": 0.349365234375}, {"start": 2634.0, "end": 2634.56, "word": " الـ", "probability": 0.346832275390625}, {"start": 2634.56, "end": 2634.82, "word": " A", "probability": 0.25341796875}, {"start": 2634.82, "end": 2635.38, "word": " N", "probability": 0.6748046875}, {"start": 2635.38, "end": 2636.32, "word": " بدي", "probability": 0.2421875}, {"start": 2636.32, "end": 2636.96, "word": " ساوي", "probability": 0.7610677083333334}, {"start": 2636.96, "end": 2637.74, "word": " الجذر", "probability": 0.7198893229166666}, {"start": 2637.74, "end": 2638.96, "word": " النوني", "probability": 0.8857421875}, {"start": 2638.96, "end": 2641.1, "word": " لتلاتة", "probability": 0.86572265625}, {"start": 2641.1, "end": 2641.88, "word": " Int", "probability": 0.279296875}, {"start": 2641.88, "end": 2642.82, "word": " كيب", "probability": 0.8154296875}, {"start": 2642.82, "end": 2646.42, "word": " بقوله", "probability": 0.5680338541666666}, {"start": 2646.42, "end": 2646.82, "word": " كويس", "probability": 0.9697265625}, {"start": 2646.82, "end": 2647.04, "word": " بدي", "probability": 0.775390625}, {"start": 2647.04, "end": 2647.56, "word": " أخد", "probability": 0.7252604166666666}, {"start": 2647.56, "end": 2647.68, "word": " ال", "probability": 0.427978515625}, {"start": 2647.68, "end": 2647.94, "word": " limit", "probability": 0.8955078125}, {"start": 2647.94, "end": 2648.52, "word": " لهذه", "probability": 0.869384765625}, {"start": 2648.52, "end": 2648.74, "word": " ال", "probability": 0.876953125}, {"start": 2648.74, "end": 2649.34, "word": " sequence", "probability": 0.93505859375}, {"start": 2649.34, "end": 2650.24, "word": " يبقى", "probability": 0.8558349609375}, {"start": 2650.24, "end": 2650.6, "word": " بعدي", "probability": 0.4945068359375}, {"start": 2650.6, "end": 2651.18, "word": " بقوله", "probability": 0.9754231770833334}, {"start": 2651.18, "end": 2651.36, "word": " ال", "probability": 0.465576171875}, {"start": 2651.36, "end": 2651.88, "word": " limit", "probability": 0.962890625}, {"start": 2651.88, "end": 2652.72, "word": " لما", "probability": 0.918701171875}, {"start": 2652.72, "end": 2652.94, "word": " ال", "probability": 0.9658203125}, {"start": 2652.94, "end": 2653.34, "word": " Int", "probability": 0.78759765625}, {"start": 2653.34, "end": 2653.66, "word": " is", "probability": 0.6728515625}, {"start": 2653.66, "end": 2653.92, "word": " to", "probability": 0.75341796875}, {"start": 2653.92, "end": 2654.58, "word": " infinity", "probability": 0.77734375}], "temperature": 1.0}, {"id": 115, "seek": 268057, "start": 2655.11, "end": 2680.57, "text": "للجذر اللوني لتلاتة في ان تكيب يسوي ال limit لما ال in tends to infinity هذه يا شباب معناته تلاتة to the power واحد على ان في ان أس تلاتة على ان يبقى الجذر اللوني تاني واحد على ان زي ال in الجذر التربيهي واحد على اتنين", "tokens": [1211, 1211, 7435, 8848, 2288, 13672, 11536, 1829, 5296, 2655, 1211, 9307, 3660, 8978, 16472, 6055, 4117, 1829, 3555, 7251, 3794, 45865, 2423, 4948, 5296, 15042, 2423, 294, 12258, 281, 13202, 29538, 35186, 13412, 3555, 16758, 20449, 8315, 47395, 6055, 1211, 9307, 3660, 281, 264, 1347, 36764, 24401, 15844, 16472, 8978, 16472, 5551, 3794, 6055, 1211, 9307, 3660, 15844, 16472, 7251, 3555, 4587, 7578, 25724, 8848, 2288, 13672, 11536, 1829, 6055, 7649, 1829, 36764, 24401, 15844, 16472, 30767, 1829, 2423, 294, 25724, 8848, 2288, 16712, 2288, 21292, 3224, 1829, 36764, 24401, 15844, 1975, 2655, 1863, 9957], "avg_logprob": -0.24484535590889528, "compression_ratio": 1.934782608695652, "no_speech_prob": 0.0, "words": [{"start": 2655.11, "end": 2656.25, "word": "للجذر", "probability": 0.83623046875}, {"start": 2656.25, "end": 2657.29, "word": " اللوني", "probability": 0.7586263020833334}, {"start": 2657.29, "end": 2658.69, "word": " لتلاتة", "probability": 0.8552734375}, {"start": 2658.69, "end": 2658.99, "word": " في", "probability": 0.90869140625}, {"start": 2658.99, "end": 2659.37, "word": " ان", "probability": 0.326171875}, {"start": 2659.37, "end": 2660.29, "word": " تكيب", "probability": 0.720947265625}, {"start": 2660.29, "end": 2661.41, "word": " يسوي", "probability": 0.6516927083333334}, {"start": 2661.41, "end": 2661.59, "word": " ال", "probability": 0.7021484375}, {"start": 2661.59, "end": 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"probability": 0.97119140625}, {"start": 2880.4, "end": 2881.3, "word": " واحد", "probability": 0.978515625}, {"start": 2881.3, "end": 2882.08, "word": " هذا", "probability": 0.8056640625}, {"start": 2882.08, "end": 2882.78, "word": " الكلام", "probability": 0.9728190104166666}, {"start": 2882.78, "end": 2883.54, "word": " from", "probability": 0.82080078125}, {"start": 2883.54, "end": 2885.02, "word": " park", "probability": 0.295166015625}], "temperature": 1.0}, {"id": 125, "seek": 290740, "start": 2885.88, "end": 2907.4, "text": "من الجزء 2 من الـ sum basic limit يبقى هنا sequence N زائد أربعة مرفوعة لل أس واحد على N زائد أربعة مالها converge كذلك", "tokens": [27842, 25724, 11622, 38207, 568, 9154, 2423, 39184, 2408, 3875, 4948, 7251, 3555, 4587, 7578, 34105, 8310, 426, 30767, 16373, 3215, 5551, 25513, 27884, 3714, 28480, 2407, 27884, 24976, 5551, 3794, 36764, 24401, 15844, 426, 30767, 16373, 3215, 5551, 25513, 27884, 3714, 6027, 11296, 41881, 9122, 8848, 23275], "avg_logprob": 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2904.98, "end": 2906.32, "word": " converge", "probability": 0.8486328125}, {"start": 2906.32, "end": 2907.4, "word": " كذلك", "probability": 0.9742838541666666}], "temperature": 1.0}, {"id": 126, "seek": 293618, "start": 2929.06, "end": 2936.18, "text": "بقى على الـ Sequence التالتة Sequence التالتة بيقول ما ياتي تلاتة", "tokens": [3555, 4587, 7578, 15844, 2423, 39184, 46859, 655, 16712, 6027, 2655, 3660, 46859, 655, 16712, 6027, 2655, 3660, 4724, 1829, 39648, 19446, 7251, 9307, 1829, 6055, 1211, 9307, 3660], "avg_logprob": -0.2895833194255829, "compression_ratio": 1.3866666666666667, "no_speech_prob": 0.0, "words": [{"start": 2929.06, "end": 2930.02, "word": "بقى", "probability": 0.476318359375}, {"start": 2930.02, "end": 2930.18, "word": " على", "probability": 0.7373046875}, {"start": 2930.18, "end": 2930.36, "word": " الـ", "probability": 0.677001953125}, {"start": 2930.36, "end": 2930.84, "word": " Sequence", "probability": 0.6168212890625}, {"start": 2930.84, "end": 2931.74, 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على", "probability": 0.8515625}, {"start": 2947.03, "end": 2947.71, "word": " الجذر", "probability": 0.6752115885416666}, {"start": 2947.71, "end": 2948.99, "word": " التربيعي", "probability": 0.8833984375}, {"start": 2948.99, "end": 2950.75, "word": " لإتنين", "probability": 0.79462890625}, {"start": 2950.75, "end": 2951.35, "word": " أس", "probability": 0.9794921875}, {"start": 2951.35, "end": 2951.81, "word": " M", "probability": 0.80517578125}, {"start": 2951.81, "end": 2956.77, "word": " يبدأ", "probability": 0.8904622395833334}, {"start": 2956.77, "end": 2957.43, "word": " ياخد", "probability": 0.8118489583333334}, {"start": 2957.43, "end": 2958.09, "word": " limit", "probability": 0.7568359375}, {"start": 2958.09, "end": 2958.97, "word": " لما", "probability": 0.730712890625}, {"start": 2958.97, "end": 2959.19, "word": " ال", "probability": 0.89892578125}, {"start": 2959.19, "end": 2959.53, "word": " N", "probability": 0.381591796875}, {"start": 2959.53, "end": 2959.85, "word": 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