diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc.srt
new file mode 100644
index 0000000000000000000000000000000000000000..865b4da49a9e19b614f9d8f95315557b043300d7
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc.srt
@@ -0,0 +1,1833 @@
+
+1
+00:00:21,350 --> 00:00:25,870
+بسم الله الرحمن الرحيم نستأنف اليوم في موضوع ال
+
+2
+00:00:25,870 --> 00:00:30,470
+alkanes و ال cycloalkanes زي ما بتعرفوا المرة
+
+3
+00:00:30,470 --> 00:00:37,030
+الماضية أعطينا فكرة عن ال alkanes من ناحية التسمية
+
+4
+00:00:37,030 --> 00:00:41,330
+و من ناحية بعض الخواص الفيزيائية و من ناحية
+
+5
+00:00:41,330 --> 00:00:51,110
+تركيبها بمعنى عدد ذرات ال carbon و ال hydrogen و
+
+6
+00:00:51,110 --> 00:00:57,310
+الصيغة العامة ربما بتذكروا حكينا للالكينز CnH2n
+
+7
+00:00:57,310 --> 00:01:02,560
+Plus Two الان من انواع ال hydrocarbons اللى بنقول
+
+8
+00:01:02,560 --> 00:01:07,080
+عنها مشبعة saturated ال cycle alkenes عشان ناخد
+
+9
+00:01:07,080 --> 00:01:12,600
+cycle alkenes او حتى بعد هيك alkenes بننطلق احنا
+
+10
+00:01:12,600 --> 00:01:17,220
+من ال alkenes يعني اتخيلوا هذا المركب اللى امامكم
+
+11
+00:01:17,220 --> 00:01:26,060
+هذا عبارة عن بروبين C3H8 واضح؟ لو بدى انا اجعل هذا
+
+12
+00:01:26,060 --> 00:01:32,700
+المركب اشيل ذرتين هيدروجين و احط بدالهم رابطة يعني
+
+13
+00:01:32,700 --> 00:01:37,400
+هي ذرة هيدروجين و من جنبها تماما يعني عندك ذرتين
+
+14
+00:01:37,400 --> 00:01:41,240
+كربون متجاورات شيلت ذرة هيدروجين و حطيت رابطة
+
+15
+00:01:41,240 --> 00:01:48,270
+مكانهم بيصير عندى ال keen بصير عندى الكين اللى فيه
+
+16
+00:01:48,270 --> 00:01:52,210
+double bond لبروبيل الان لو سألت ال الكين ايش
+
+17
+00:01:52,210 --> 00:01:59,970
+الصيغة العامة له لاحظوا معاه C3H6
+
+18
+00:02:01,060 --> 00:02:09,040
+C3H6 معنا ذلك الصيغة العامة للالكينز CnH2n واضح
+
+19
+00:02:09,040 --> 00:02:15,540
+نقص كم هيدروجينة تنتين الان لو جربنا نشيل كمان
+
+20
+00:02:15,540 --> 00:02:19,180
+هيدروجين تان من جنب بعض و نحط رابطة مكانهم يعني
+
+21
+00:02:19,180 --> 00:02:24,060
+هاي كمان هيدروجين شيلتها و كمان هيدروجين و حطيت
+
+22
+00:02:24,060 --> 00:02:32,960
+رابطة صار عندى رابطةثلاثية ال kind صار عندي ال
+
+23
+00:02:32,960 --> 00:02:39,660
+kind هذا ال ال kind الصيغة العامة إيه له CnH2n-2
+
+24
+00:02:39,660 --> 00:02:44,940
+يعني لما أقول C3H326
+
+25
+00:02:44,940 --> 00:02:50,830
+-2 أربعة شايفين الأربعة فهذه الصيغة العامة لل
+
+26
+00:02:50,830 --> 00:02:56,690
+الkins لل الkinds لل الkins الآن خلّينا نرجع مرة
+
+27
+00:02:56,690 --> 00:03:01,890
+تانية لل الkins ونشوف طيب إيش الصيغة العامة لل
+
+28
+00:03:01,890 --> 00:03:06,370
+cycloalkins اللي الآن بدهم يمروا علينا ال
+
+29
+00:03:06,370 --> 00:03:11,050
+cycloalkins يعني لو بدي أعمل حلقة و كل الروابط
+
+30
+00:03:11,050 --> 00:03:17,770
+تبعت هذه الحلقة روابط إيش أحدية عشان اعمل حلقة
+
+31
+00:03:17,770 --> 00:03:24,250
+المفروض ان اشيل ذرتين هيدروجين لكن بشيلهم مش من
+
+32
+00:03:24,250 --> 00:03:28,810
+جنب بعض في هذه الحالة مثلا بشيلهم من الأطراف هشيلت
+
+33
+00:03:28,810 --> 00:03:33,990
+ذرة هيدروجين من هنا و ذرة هيدروجين تانية من
+
+34
+00:03:33,990 --> 00:03:41,210
+الأطراف و حطيت مكانها رابطة صار
+
+35
+00:03:41,210 --> 00:03:47,060
+عند مركب حلقه cycloalkane لأنه إجا من تلت كربونات
+
+36
+00:03:47,060 --> 00:03:53,100
+بروبيل، شو صرت أسميه؟ Cyclopropane طيب، الآن طالما
+
+37
+00:03:53,100 --> 00:03:58,100
+أنا شيلت هيدروجين تان، والواقع أيضا بأيد هالكلام
+
+38
+00:03:58,100 --> 00:04:00,400
+C3H
+
+39
+00:04:01,190 --> 00:04:08,670
+Six إذا ما الصيغة العامة للـ Cycloalkynes CnH2n
+
+40
+00:04:08,670 --> 00:04:15,810
+CnH2n لاحظوا معناه إن ال الكينز و ال Cycloalkynes
+
+41
+00:04:15,810 --> 00:04:19,990
+بينشأوا عنفق الذرتين هيدروجين ولذلك الطرفين اللي
+
+42
+00:04:19,990 --> 00:04:26,110
+همنفس الصيغة العامة لكن لو فقدوا ذرات الهيدروجين
+
+43
+00:04:26,110 --> 00:04:31,050
+من جانب بعض اعملنا رابطة مكانهم صار عند ال الكين
+
+44
+00:04:31,050 --> 00:04:35,450
+لو فقدوا من اماكن بعيدة و اعملنا رابطة صار عند
+
+45
+00:04:35,450 --> 00:04:40,370
+Cycloalkyn و لذلك ال Cycloalkyn و ال الكين هما
+
+46
+00:04:40,370 --> 00:04:46,750
+يمتلون نفس الفورمولة CnH2n
+
+47
+00:04:46,750 --> 00:04:52,900
+هذه النقطة الأولى اللى بدى احكيها في الموضوع الان
+
+48
+00:04:52,900 --> 00:04:57,960
+لو اتطلعنا اكثر على الـ Cyclopropane بدنا معلومات
+
+49
+00:04:57,960 --> 00:05:03,040
+اكثر عنه، لاحظوا ان تلت ذرات الكربون تبعون الـ
+
+50
+00:05:03,040 --> 00:05:09,830
+Cyclopropane في مستوى واحد، واضح؟و أي تلت ذرات في
+
+51
+00:05:09,830 --> 00:05:13,470
+الدنيا بالمناسبة بيكونوا في مستوى واحد يعني مش
+
+52
+00:05:13,470 --> 00:05:17,130
+ممكن تلاتة إلا يكونوا في مستوى واحد واحد اتنين
+
+53
+00:05:17,130 --> 00:05:22,070
+حطوا التالتة هذا في مستوى واحد ولذلك لو سألنا عن
+
+54
+00:05:22,070 --> 00:05:27,370
+الـcyclopropane إيش الشكل تبعه بدنا نقول planner
+
+55
+00:05:27,370 --> 00:05:34,230
+planner يعني في مستوى واحد مش بتلت أبعاد يعني لو
+
+56
+00:05:34,230 --> 00:05:39,070
+كنا بنحكي عن XY هذا في ال XY واضحة الفكرة؟ هذه
+
+57
+00:05:39,070 --> 00:05:41,870
+النقطة الثانية اللى بدنا ننبهها بالنسبة للـ
+
+58
+00:05:41,870 --> 00:05:48,610
+Cyclopropane الان نقطة تالتة كتير مهمة جدا عندنا
+
+59
+00:05:48,610 --> 00:05:55,510
+دائما في أي مركب نعرف أنواع ذرات الهيدروجيل عشان
+
+60
+00:05:55,510 --> 00:05:59,570
+لما بنعمل التفاعلات النواتج تتمد كم نوع ذرات
+
+61
+00:05:59,570 --> 00:06:04,410
+هيدروجين عندك يعني ربما المركب الأصلي اللى قبل ما
+
+62
+00:06:04,410 --> 00:06:08,230
+يكون Cyclopropane اللى هو البروبين لما حكينا المرة
+
+63
+00:06:08,230 --> 00:06:18,590
+الماضية CH3 CH2 CH3 كم نوع من ذرات الهيدروجين فيه
+
+64
+00:06:18,590 --> 00:06:24,250
+نوعين هدولة الستة زي بعض و هدولة التنتين زي بعض و
+
+65
+00:06:24,250 --> 00:06:27,630
+عشان ايه بعد شوية لو بدي اعمل عليه تفاعلات اقول طب
+
+66
+00:06:27,630 --> 00:06:32,530
+نشيل هيدروجينة نحط مركانها كلور لو شيلت من هان
+
+67
+00:06:32,530 --> 00:06:37,610
+بطلع عنده مركب بسميه one chlorobrobil لو شيلت من
+
+68
+00:06:37,610 --> 00:06:43,220
+هانبطلع مركّب تاني بسميه 2-chloropropane فبناء على
+
+69
+00:06:43,220 --> 00:06:47,240
+عدد أنواع الهيدروجين انا بقدر اعرف ايش اللي بيصير
+
+70
+00:06:47,240 --> 00:06:51,340
+عندى بالتفاعل طيب يا تورا لو مسكت ال cyclopropane
+
+71
+00:06:51,340 --> 00:06:59,720
+و سألت هدولة 6 ذرات هيدروجين كام نوع؟نوع واحد
+
+72
+00:06:59,720 --> 00:07:04,400
+بمعنى لو انا امسكت ذرة كلور خلّينا نفترض هذه لمخ
+
+73
+00:07:04,400 --> 00:07:08,520
+اللون الأخضر بدي اشيل اي هيدروجين و احط مكانها
+
+74
+00:07:08,520 --> 00:07:14,180
+كلور مش هذا تفاعل ابدال بدلنا هيدروجين بكلور الان
+
+75
+00:07:14,180 --> 00:07:20,460
+لو شيلت هذه و حطيت كلور هيطلع عندى مركببس بيصير
+
+76
+00:07:20,460 --> 00:07:25,920
+اسمه اكلورو سايكلو بروبين طب لو كنت بده احك مكان
+
+77
+00:07:25,920 --> 00:07:33,120
+هادي نفس الاشي واضح مكان هادي مكان هادي ف ست ذرات
+
+78
+00:07:33,120 --> 00:07:38,520
+الهيدروجين في هذا المركب they are equivalent يعني
+
+79
+00:07:38,520 --> 00:07:43,560
+لو كنا بنسألكم the six hydrogens of cyclopropane
+
+80
+00:07:43,560 --> 00:07:50,880
+are equivalent متكافئات واضحة الفكرة وعشان هيك
+
+81
+00:07:50,880 --> 00:07:56,440
+بنقدر نتبع هالكلام جملة تانية monochlorination of
+
+82
+00:07:56,440 --> 00:07:59,600
+cyclopropane معناه monochlorination إن أنا أبدل
+
+83
+00:07:59,600 --> 00:08:05,680
+هيدروجين واحدة بكلور واحدة شو بسمي العملية؟ mono
+
+84
+00:08:05,680 --> 00:08:11,120
+يعني أحادي monochlorination
+
+85
+00:08:11,120 --> 00:08:18,080
+إيش يعني chlorination؟ تفاعل مع الكلور تفاعل الـ
+
+86
+00:08:18,080 --> 00:08:21,340
+Cyclopropane مع الكلور إبدال بذرة واحدة
+
+87
+00:08:21,340 --> 00:08:27,820
+Monochlorination of Cyclopropane produces only one
+
+88
+00:08:27,820 --> 00:08:34,880
+product بيطلع فقط ناتج واحد، شو سميته أنا؟
+
+89
+00:08:34,880 --> 00:08:40,900
+Chlorocyclopropane واضح؟
+
+90
+00:08:41,270 --> 00:08:48,910
+الان اذا بنستمر بنفس هذه الفكرة وبنقول ان انسان
+
+91
+00:08:48,910 --> 00:08:54,850
+عمل هذا التفاعل وصار عنده chlorocyclopropane وفكر
+
+92
+00:08:54,850 --> 00:09:00,570
+انه بده يعمل تفاعل تاني على ال cyclopropane ابدل
+
+93
+00:09:00,570 --> 00:09:06,850
+كمان هيدروجين لازم يكون عارف كم نوع من الهيدروجين
+
+94
+00:09:06,850 --> 00:09:15,380
+عنده في هذا المركب الان لا أكيد لا الان احنا بحاجة
+
+95
+00:09:15,380 --> 00:09:24,980
+إلى عمق في التفكير و في النظر الأمر مش سهل اكثر
+
+96
+00:09:24,980 --> 00:09:31,580
+من نوع يعني هذا لما بضحط chlorine تانية كان مركب
+
+97
+00:09:31,580 --> 00:09:38,640
+بينتج عندى فيه واضح؟ في الحقيقة هنكتشف انهم اللي
+
+98
+00:09:38,640 --> 00:09:45,540
+بينتجوا تلت مركبات معناه ذلك عندنا تلت أنواع من
+
+99
+00:09:45,540 --> 00:09:49,220
+الهيدروجيل بنعملهم بال model و بعدين بنكتبهم
+
+100
+00:09:49,220 --> 00:09:53,680
+معادلة حتى نأكد المعلومة الآن لو إجت طالبة منكم
+
+101
+00:09:53,680 --> 00:09:59,240
+قالت بدي أشيل هذه الهيدروجيل اللي على نفس الكاربون
+
+102
+00:09:59,240 --> 00:10:05,020
+اللي حامله كلور و أحط محالها كلور طلعت مركّب حامل
+
+103
+00:10:05,020 --> 00:10:08,840
+ذرتين كلور على نفس الكربون هذا
+
+104
+00:10:08,840 --> 00:10:13,180
+Dichlorocyclopropane لكن التسمية بتشترط اني لازم
+
+105
+00:10:13,180 --> 00:10:17,680
+احدد الان مواقعهم وين موجودة هذه عن امر واحد و هذه
+
+106
+00:10:17,680 --> 00:10:23,680
+ع واحد اذا هذا لو كنت بدى اسميه هسميه one one
+
+107
+00:10:23,680 --> 00:10:28,540
+مرتين لازم اقول one يعني ذرة على one والتانية على
+
+108
+00:10:28,540 --> 00:10:32,600
+one one one dichlorocyclopropane
+
+109
+00:10:33,600 --> 00:10:39,640
+هذا مُركّب إجى مكان ذرّة الهيدروجين اللي هنا الان
+
+110
+00:10:39,640 --> 00:10:47,020
+لو إجيت طلعت على هدول الذرات نسبتهم لهذه واحد تنين
+
+111
+00:10:47,020 --> 00:10:56,580
+او واحد تنين واضح؟ الان لو شيلت هذه حطيت مكانها
+
+112
+00:10:56,580 --> 00:11:04,460
+اكلور هيطلع عند مُركّب جديد Dichlorocyclopropane
+
+113
+00:11:04,460 --> 00:11:09,300
+قدرتين لكلور على موقعين متجاورين عشانك بقول one
+
+114
+00:11:09,300 --> 00:11:13,520
+two dichlorocyclopropane
+
+115
+00:11:13,520 --> 00:11:19,240
+one two dichlorocyclopropane هاي مركب تاني الان
+
+116
+00:11:19,240 --> 00:11:25,060
+ممكن واحدة منكم تفكر تقول طب خلينا نشيل هذه الذرعة
+
+117
+00:11:25,060 --> 00:11:30,880
+مش من نفس الجهة اللي هنا من الجهة المعاكسة ونحط
+
+118
+00:11:34,790 --> 00:11:40,130
+one two dichlorocyclopropane الان السؤال هل يا ترى
+
+119
+00:11:40,130 --> 00:11:44,950
+المركب اللى فى ذرتين لكلور على جهة واحدة زى اللى
+
+120
+00:11:44,950 --> 00:11:49,070
+فى ذرتين لكلور متعاكسة ممكن البعض يقول طب احنا
+
+121
+00:11:49,070 --> 00:11:54,190
+بنلف حوالين الرابط لو جربنا اللفتذكروا أن الدوران
+
+122
+00:11:54,190 --> 00:12:00,050
+ممنوع حول الحلقة مافيش إمكانية إذا هدول مركبين طيب
+
+123
+00:12:00,050 --> 00:12:04,210
+هذا اسمه one two و اللي كان ع جهة واحدة برضه اسمه
+
+124
+00:12:04,210 --> 00:12:07,510
+one two dichlorocyclopropane لو بدي أميزهم أكثر
+
+125
+00:12:07,510 --> 00:12:11,890
+بقول اه في عندي one two اللي على جهة واحدة و one
+
+126
+00:12:11,890 --> 00:12:19,170
+two اللي على جهتين متعاكستين هنا بدأنا نتكلم في ال
+
+127
+00:12:19,170 --> 00:12:24,460
+stereo chemistry انه صحيح الذرات موجودين على موقع
+
+128
+00:12:24,460 --> 00:12:28,440
+واحد و اتنين يعني same bonding لكن هنا على واحد و
+
+129
+00:12:28,440 --> 00:12:32,480
+اتنين على جهة واحدة و على واحد و اتنين على جهتين
+
+130
+00:12:32,480 --> 00:12:37,660
+متعاكستين الاسم في الحالتين one two
+
+131
+00:12:37,660 --> 00:12:42,770
+dichlorocyclopropane لكن بدي اضيف عليه مرة معو مرة
+
+132
+00:12:42,770 --> 00:12:49,450
+ضد لو كنا بنكتب بالعربي فعلا بيستعملوا مع كلمتين
+
+133
+00:12:49,450 --> 00:12:55,110
+مع على جهة واحدة و ضد على جهتين متعاكستين الآن
+
+134
+00:12:55,110 --> 00:12:58,550
+بالإنقليزي بيروحوا بيحطوا prefix ال prefix يعني
+
+135
+00:12:58,550 --> 00:13:03,690
+اشي في أول الكلام بادئة توضح هذا الكلام بيروحوا
+
+136
+00:13:03,690 --> 00:13:08,910
+بيضيفوا cis بمعنى على جهة واحدة و trans بمعنى على
+
+137
+00:13:08,910 --> 00:13:16,000
+جهتين Sex و Trans يعني على جهة واحدة وعلى جهتين
+
+138
+00:13:16,000 --> 00:13:24,840
+خلينا هذا الكلام إذا بتسمحوا نتخيله بمعادلة ليش
+
+139
+00:13:24,840 --> 00:13:29,660
+لأنه دائما إنتوا لو بدكوا تكتبوا هتكتبوا معادلات
+
+140
+00:13:29,660 --> 00:13:31,780
+بمعنى هاي في عند أنا
+
+141
+00:13:36,020 --> 00:13:41,100
+Cyclopropane هذا Cyclopropane كام هيدروجين فيه؟
+
+142
+00:13:41,100 --> 00:13:46,860
+ستة لو قلت بدي أعمل إيه له؟ إكلورينايشن Cl2 في
+
+143
+00:13:46,860 --> 00:13:51,460
+البداية بدي أعمل مونوكلورينايشن أبدل ذرة واحدة شو
+
+144
+00:13:51,460 --> 00:13:57,400
+هينشاء عندى؟ إكلورو سايكلوبروبين على أي موقع ابنه
+
+145
+00:13:57,400 --> 00:14:03,840
+كتوبة ماعنداش مشكلة إكلورو سايكلوبروبين
+
+146
+00:14:03,840 --> 00:14:07,900
+هيك حاجة أسميه الان لو افترضت هذا ال
+
+147
+00:14:07,900 --> 00:14:14,440
+chlorocyclopropane بدي اعمله كمان chlorination
+
+148
+00:14:14,440 --> 00:14:20,000
+حيصير بالمجمل كم ذرة ال chlor أبدلت تنتين اه كمان
+
+149
+00:14:20,000 --> 00:14:25,720
+مرة chlorination حيصير عندي عدة احتمالات هذا
+
+150
+00:14:25,720 --> 00:14:29,140
+الاحتمال ان ذرة ال chlor تيجي على نفس الذرة اللي
+
+151
+00:14:29,140 --> 00:14:35,700
+حملة ال chlor الأولى ايش سمناه اللى عملناه في
+
+152
+00:14:35,700 --> 00:14:42,520
+الأولى ال chlorine ال chlorine على نفس الذرة one
+
+153
+00:14:42,520 --> 00:14:45,880
+one one one one one one one one one one one one
+
+154
+00:14:45,880 --> 00:14:46,040
+one one one one one one one one one one one one
+
+155
+00:14:46,040 --> 00:14:46,060
+one one one one one one one one one one one one
+
+156
+00:14:46,060 --> 00:14:53,560
+one one one one one one one one one one one one
+
+157
+00:14:53,560 --> 00:14:53,820
+one one one one one one one one one one one one
+
+158
+00:14:53,820 --> 00:14:54,180
+one one one one one one one one one one one one
+
+159
+00:14:54,180 --> 00:14:54,200
+one one one one one one one one one one one one
+
+160
+00:14:54,200 --> 00:14:54,300
+one one one one one one one one one one one one
+
+161
+00:15:10,380 --> 00:15:18,060
+الان يا تورا لو كنا بدنا نحط ذرة الكلور على الموقع
+
+162
+00:15:18,060 --> 00:15:24,020
+اتنين خلينا نحط واحد و اتنين هنا بهذا الشكل ممكن
+
+163
+00:15:24,020 --> 00:15:30,380
+يكون عنده ذرتين كلور على جهة واحدة او ذرتين كلور
+
+164
+00:15:30,380 --> 00:15:33,920
+على جهتين متعاكسات
+
+165
+00:15:35,440 --> 00:15:40,600
+واضح؟ الان هاي واحد اتنين تلاتة واحد اتنين تلاتة
+
+166
+00:15:40,600 --> 00:15:45,240
+اذا كل مركب من هدوله ايش اسمه one two
+
+167
+00:15:45,240 --> 00:15:56,340
+dichlorocyclopropane one two dichlorocyclopropane
+
+168
+00:15:56,340 --> 00:15:58,800
+لكن
+
+169
+00:16:05,080 --> 00:16:10,380
+لكن لما بدي اميز هدول المركبات هنا الديكلورو جايين
+
+170
+00:16:10,380 --> 00:16:16,680
+على جهة واحدة فهذا الاسم الكامل له شو حيصير cis
+
+171
+00:16:16,680 --> 00:16:22,200
+شرطة one two dichlorocyclopropane يعني لما بدي
+
+172
+00:16:22,200 --> 00:16:27,540
+اجيب هذا في الامتحان سموه هتكتبوا cis شرطة one two
+
+173
+00:16:27,540 --> 00:16:33,430
+dichlorocyclopropane لو كنت بدي اسمي هذاالترانس
+
+174
+
+223
+00:20:26,660 --> 00:20:31,540
+diastereomers؟ بنقول ببساطة التعريف العام التعريف
+
+224
+00:20:31,540 --> 00:20:35,780
+العام ل diastereomers ال diastereomers they are
+
+225
+00:20:35,780 --> 00:20:41,360
+non mirror image stereoisomers يعني stereoisomers
+
+226
+00:20:41,360 --> 00:20:47,140
+ولكن مش صورة بعض في المرآة يعني لو تخيلت أنا أنه
+
+227
+00:20:47,140 --> 00:20:52,280
+بين واحد والتانيفي بينهم مرايا، هل الواحد منهم
+
+228
+00:20:52,280 --> 00:20:57,060
+صورة التالف في المرآة ولا لأ؟ يعني تخيلوا أن أنا
+
+229
+00:20:57,060 --> 00:21:03,800
+هنا حطيت مرآة، دائما و أبدا، أمام المرآة كل جسم له
+
+230
+00:21:03,800 --> 00:21:11,800
+صورة، والصورة في المرآة دائما معاكسة تماما لصورة
+
+231
+00:21:11,800 --> 00:21:16,740
+الجسميعني لو أنا وقفت زي المرأة .. أمام المرأة
+
+232
+00:21:16,740 --> 00:21:22,720
+بهذا الشكل كل النظر تبعي باتجاهكم الآن الصورة اللي
+
+233
+00:21:22,720 --> 00:21:28,960
+في المرأة بكل أبعادها يجب أن تكون معاكسة لصورة
+
+234
+00:21:28,960 --> 00:21:35,380
+الجسم دائما صورة المرأة معاكسة لصورة الجسم بكل
+
+235
+00:21:35,380 --> 00:21:41,560
+مكوناتهاالان لو اتيت يا تورا اتسألت هل هدولة من
+
+236
+00:21:41,560 --> 00:21:47,360
+الاساس صورة مرآه ولا مش صورة مرآه؟ لاحظوا يمكن هنا
+
+237
+00:21:47,360 --> 00:21:50,600
+تلاقي كلور متجه باتجاه هذه عكسها وهذه الهيدروجين
+
+238
+00:21:50,600 --> 00:21:55,600
+باتجاه هذه عكسها يعني لحد هذه النقطةمعاكسات لكن
+
+239
+00:21:55,600 --> 00:22:01,280
+هنا في chlorine إقبالها hydrogen تحت هنا في
+
+240
+00:22:01,280 --> 00:22:05,140
+chlorine إقبالها hydrogen هل هدولة بيصيروا صورة
+
+241
+00:22:05,140 --> 00:22:11,730
+مرآة إذا بطلوا صورة مرآةشرط صورة المرآة أن كل جزء
+
+242
+00:22:11,730 --> 00:22:16,930
+من الجزيئات هيكون بعكس الجثة الآخر هدولة فيهم
+
+243
+00:22:16,930 --> 00:22:19,910
+أشياء أساسا مش اقبال .. مش .. يعني هذه لا فوق،
+
+244
+00:22:19,910 --> 00:22:25,650
+كلور اقبالها هيدروجين، إذا هدولة الشكلين الcess
+
+245
+00:22:25,650 --> 00:22:30,730
+والترانس لما أنا بدي أحكي عنهم بقول they are non
+
+246
+00:22:30,730 --> 00:22:38,720
+mirrorimages، إيش يعني non-mirror images؟ مش صورة
+
+247
+00:22:38,720 --> 00:22:42,120
+بعض في المرأة، الأشياء اللي بتكون مش صورة بعض في
+
+248
+00:22:42,120 --> 00:22:47,960
+المرأة هي اللي تعرف ان اسمها diastereomers، وهذا
+
+249
+00:22:47,960 --> 00:22:53,760
+مثال عليها، ف ال cicatrans، isomers، they are
+
+250
+00:22:53,760 --> 00:22:55,720
+diastereomers
+
+251
+00:22:57,420 --> 00:23:00,580
+They are non-mirror image stereoisomers, so they
+
+252
+00:23:00,580 --> 00:23:06,520
+are diastereomers فكتصنيف من أنواع الاستيريو ايزو
+
+253
+00:23:06,520 --> 00:23:10,460
+مارز، they are diastereomers واضح؟ ولذلك لو
+
+254
+00:23:10,460 --> 00:23:14,080
+جيبنالكم سؤال صح و غلط Sistransisomers are
+
+255
+00:23:14,080 --> 00:23:21,360
+stereoisomers صحالان لو بدى اسأل اكثر عمقًا
+
+256
+00:23:21,360 --> 00:23:26,640
+Sistransisomers are diastereomers برضه صح ما هي
+
+257
+00:23:26,640 --> 00:23:31,080
+diastereomers نوع لكن لو قلنا Sistransisomers are
+
+258
+00:23:31,080 --> 00:23:36,000
+enantiomers لأ و هنتعلم ال enantiomers مستقبلا لو
+
+259
+00:23:36,000 --> 00:23:42,280
+قلنا Sistransisomers are structural isomersبرضه
+
+260
+00:23:42,280 --> 00:23:47,080
+غلط لأ مش structural .. ال structural بيختلفوا في
+
+261
+00:23:47,080 --> 00:23:49,580
+ال bonding هدولة they have the same bonding ع واحد
+
+262
+00:23:49,580 --> 00:23:56,120
+و اتنين ع واحد و اتنين واضح؟ لكن هذا المركب و هذا
+
+263
+00:23:56,120 --> 00:24:00,180
+they are structural isomers بس ال cis trans
+
+264
+00:24:00,180 --> 00:24:04,400
+isomers are stereoisomers أي نوع من ال
+
+265
+00:24:04,400 --> 00:24:10,050
+stereoisomers تحديدا ده يا stereomersتطلعوا معي
+
+266
+00:24:10,050 --> 00:24:14,650
+مرة تانية نرسم أحد هدولة أو نعمل model لأحد هدولة
+
+267
+00:24:14,650 --> 00:24:18,950
+المركبات اللي هم ال sis, trans, isomers واضح؟ هذا
+
+268
+00:24:18,950 --> 00:24:25,810
+أي مركب فيهم؟ ال sis والتاني لترانس متى توجد عندنا
+
+269
+00:24:25,810 --> 00:24:29,840
+ظاهرة ال sis و الترانس؟يعني في ناس بيقولوا وقتش
+
+270
+00:24:29,840 --> 00:24:33,660
+بدأ اقول ان في عندى cis و trans او لأ بنقول القاتل
+
+271
+00:24:33,660 --> 00:24:38,740
+ظاهرة ال cis و ال trans توجد في مكانين اما في
+
+272
+00:24:38,740 --> 00:24:45,400
+الحلقات او المكان التاني حول الروابط الزوجية صار
+
+273
+00:24:45,400 --> 00:24:50,320
+عندى نقطة كتير مهمة ناس بدهم يفهموا كل موضوع
+
+274
+00:24:53,400 --> 00:24:58,400
+كل موضوع ال sis و ال trans وين عمره يمر علي كلمة
+
+275
+00:24:58,400 --> 00:25:07,120
+sis و ال trans بنقول ال sis و ال trans هتشوفهم
+
+276
+00:25:07,120 --> 00:25:18,180
+بمكانين sis و ال trans اما في ال cycles او في ال
+
+277
+00:25:18,180 --> 00:25:23,160
+alkenesالالكينز اللي فيها روابط الزوجين هذا المكان
+
+278
+00:25:23,160 --> 00:25:29,940
+اللي بتشوفه فيه كلمة sis و trans في ال cycles مثل
+
+279
+00:25:29,940 --> 00:25:35,680
+المثال اللي احنا رسمنا زي ما قولنا هذا مثلا بهذا
+
+280
+00:25:35,680 --> 00:25:43,400
+الشكل sis و بهذا الشكل ال trans هاي بال cycle اللي
+
+281
+00:25:43,400 --> 00:25:48,970
+اتعرفنا عليه طيب حوالين ال double bondنفس الاشي لو
+
+282
+00:25:48,970 --> 00:25:52,810
+تخيل انه عندنا carbon double bond carbon حطينا
+
+283
+00:25:52,810 --> 00:25:59,310
+زرتين كلور بهذا الشكل وهنا carbon double bond
+
+284
+00:25:59,310 --> 00:26:07,670
+carbon حطينا زرتين كلور بهذا الشكل هذا
+
+285
+00:26:07,670 --> 00:26:12,890
+إثالين وهذا إثالين هذولة زرتين كلور على واحد
+
+286
+00:26:12,890 --> 00:26:20,030
+واتنين على جهة واحدةانا على واحد و اتنين و اتنين
+
+287
+00:26:20,030 --> 00:26:24,370
+على جهتين مختلفتين اذا الاتنين اسمه one two
+
+288
+00:26:24,370 --> 00:26:33,450
+dichloroethane طب كيف بدي اميزهم هدوله sis و هدوله
+
+289
+00:26:33,450 --> 00:26:38,010
+ال trans هدوله ال sis و هدوله ال trans فدائرة ال
+
+290
+00:26:38,010 --> 00:26:42,570
+sis و ال trans مكان وجودها في الدنيا مكانين ال
+
+291
+00:26:42,570 --> 00:26:44,790
+cycloalkenes و
+
+292
+00:26:46,730 --> 00:26:51,230
+الالكايز الالكينز عفوا ليش هذا الكلام بيتم لأنه
+
+293
+00:26:51,230 --> 00:26:56,390
+انا لو جربت في cycle الكل بدي ألوف هذا هيك أخلي
+
+294
+00:26:56,390 --> 00:27:00,470
+هدول يصيروا عكس بعض يعني ال 6 يصير ال trans لاحظوا
+
+295
+00:27:00,470 --> 00:27:05,210
+لأنه مربوط بالحلقة الدوران حول الحلقة ممنوع
+
+296
+00:27:05,210 --> 00:27:11,210
+الدوران حول الحلقة ممنوع الان طيب لو اتخيلتوا ان
+
+297
+00:27:11,210 --> 00:27:19,360
+انا في عندهالكين وهي مُركّب الـ CIS مش هذا
+
+298
+00:27:19,360 --> 00:27:25,900
+المُركّب اللي مرسوم CIS 1,2-dichloroethane الأن
+
+299
+00:27:25,900 --> 00:27:31,860
+لاحظوا لو بدى ألف و أخلي هدولة يصيروا عكس بعضبرضه
+
+300
+00:27:31,860 --> 00:27:35,500
+لأن الرابطة الزوجية رابطة قوية الدوران حولها
+
+301
+00:27:35,500 --> 00:27:43,500
+ممنوعة إذا العامل المشترك في هذا الموضوع ما بين
+
+302
+00:27:43,500 --> 00:27:51,800
+الحلقة و ما بين الألكين أنه في الحالتين الدوران
+
+303
+00:27:51,800 --> 00:27:57,040
+ممنوعة لذلك مقدرش أنا أعمل دوران أحول واحد للتاني
+
+304
+00:27:59,010 --> 00:28:05,410
+فكل واحد منهم بيصير مركّب منفصل بخواص منفصلة بمعنى
+
+305
+00:28:05,410 --> 00:28:10,150
+لو واحدة راحت تشتري مركّب كيميائي جالت بدّي one
+
+306
+00:28:10,150 --> 00:28:15,030
+two dichlorocyclopropane البياحة يقولها مافيش
+
+307
+00:28:15,030 --> 00:28:20,230
+عندى، في عندى؟two bottles مرتبانين واحد بكتب عليه
+
+308
+00:28:20,230 --> 00:28:26,170
+sis والتاني trans واضح الفكرة زي لما الواحدة
+
+309
+00:28:26,170 --> 00:28:31,510
+بيجيها مولود مافيش يكون عشوائي يا ولد يا بنت لو
+
+310
+00:28:31,510 --> 00:28:37,030
+قلنا مثلا one two dichloroethaneروحنا نشتريه،
+
+311
+00:28:37,030 --> 00:28:42,930
+مافيش، هتلاقوا عند البائع two bottles مرتبان CES 1
+
+312
+00:28:42,930 --> 00:28:49,270
+,2-dichloroethane بقواص معينة و بظائف معينة في
+
+313
+00:28:49,270 --> 00:28:54,590
+الحياة و هتلاقوا مركب تاني مختلف ال Trans و زي ما
+
+314
+00:28:54,590 --> 00:28:59,520
+قلنا العلاقة بين هدولة VRDiastereomers they are
+
+315
+00:28:59,520 --> 00:29:04,740
+non mirror images كلام سليم ولا لأ؟ مش صورة بعض في
+
+316
+00:29:04,740 --> 00:29:10,720
+المرأة في الخصائص
+
+317
+00:29:10,720 --> 00:29:16,420
+الفيزيائية أكيد و الكيميائية بيختلفوا في كل شيء
+
+318
+00:29:16,420 --> 00:29:21,910
+صاروا مركبينواضح مركبين they have different
+
+319
+00:29:21,910 --> 00:29:24,810
+physical properties، واحد من نقطة غليانه مثلا
+
+320
+00:29:24,810 --> 00:29:29,970
+سبعين، التانه نقطة غليانه تسعين، يختلفوا، واضح
+
+321
+00:29:29,970 --> 00:29:37,080
+الفكرة؟الان البعض احيانا بيقول طيب وكتش انا ممكن
+
+322
+00:29:37,080 --> 00:29:42,040
+يكون عندى ظاهرة ال sesual trance وانتبه لها اكثر و
+
+323
+00:29:42,040 --> 00:29:47,880
+وكتش لأ يعني لما أخدنا هذا المركب اللى حطينا فيه
+
+324
+00:29:47,880 --> 00:29:53,180
+chlorine و chlorine هنا طبعا اكيد هنا في hydrogen
+
+325
+00:29:53,180 --> 00:29:59,760
+ماجيبناش سيرة sesual tranceجيبناه إيش صيرت Sis &
+
+326
+00:29:59,760 --> 00:30:05,580
+Trans؟ وسمناها one-one-dichlorocyclo
+
+327
+00:30:05,580 --> 00:30:11,080
+-propane كذلك الحالة لو أنا انطلقت من الاثيليل
+
+328
+00:30:11,080 --> 00:30:16,540
+وحطيت ذرتين كلور على ال carbon الأولى يعني كان
+
+329
+00:30:16,540 --> 00:30:19,600
+عندى هذا المركب carbon double bond carbon ..
+
+330
+00:30:22,850 --> 00:30:26,870
+لو كان عندى هذا المركب carbon double bond carbon
+
+331
+00:30:26,870 --> 00:30:32,450
+وحطيت ذرتين كلور على الموقع الأول وقلنا إيش هذا
+
+332
+00:30:32,450 --> 00:30:39,880
+بدنا نسميهone one dichloroethane one one
+
+333
+00:30:39,880 --> 00:30:44,680
+dichloroethane مظبوط ولا لأ الان جيبنا هانة صيرت
+
+334
+00:30:44,680 --> 00:30:50,740
+cis و trans هان اه هان اه طيب بيصير سؤال وكتش
+
+335
+00:30:50,740 --> 00:30:54,360
+بيكون عندى ظاهرة ال cis و ال trans كلها موجودة
+
+336
+00:30:54,360 --> 00:31:00,220
+وكتش لأ الجواب بسيطبطلّع على الطرفين اللي بيحملوا
+
+337
+00:31:00,220 --> 00:31:03,920
+الذرات اللي هم الطرفين ال double bond أو الطرفين
+
+338
+00:31:03,920 --> 00:31:08,760
+اللي هنا إذا كانت كل ذرة تحمل مجموعتين مختلفتين
+
+339
+00:31:08,760 --> 00:31:11,760
+بيكون عند السيس و ترانس يعني هاي ال double bond
+
+340
+00:31:11,760 --> 00:31:19,200
+هادي غير هادي إذا هدوله مختلفتان ولا لأ هادي غير
+
+341
+00:31:19,200 --> 00:31:24,910
+هادي هدول مختلفتان و هدول مختلفتانإذا في عندي أكيد
+
+342
+00:31:24,910 --> 00:31:28,970
+من هذا المركب sis و trans هذا ال sis كيف بدي أجيب
+
+343
+00:31:28,970 --> 00:31:36,230
+لل trans؟ بال rotation؟ خليني أقول لو جيبنا لكوا
+
+344
+00:31:36,230 --> 00:31:42,070
+سؤال كيف نحول مركب ال sis إلى ال trans؟ أو نقول
+
+345
+00:31:42,070 --> 00:31:46,070
+sis compounds can be converted to trans by
+
+346
+00:31:46,070 --> 00:31:50,810
+rotation هاي الدوران جادر يلوف؟ لأ طب لو بدي أخلي
+
+347
+00:31:50,810 --> 00:31:58,660
+هذا ال sis transbond breaking bond formation اذا
+
+348
+00:31:58,660 --> 00:32:03,740
+انا كيف بحول السسلة ل Trans بال bond breaking و
+
+349
+00:32:03,740 --> 00:32:07,220
+bond formation بكسر الروابط و بحطها من اول و جديد
+
+350
+00:32:07,220 --> 00:32:11,150
+بس الدوران لا يؤدي الى هذا الكلامهنا صرت ما أعطيكم
+
+351
+00:32:11,150 --> 00:32:15,190
+كمان معلومتين إضافيتين عن ظاهرة الـ sexual trance
+
+352
+00:32:15,190 --> 00:32:20,110
+عشان توجد كظاهرة لابد كل carbon من أطراف الـ
+
+353
+00:32:20,110 --> 00:32:26,170
+double bond تحمل مجموعتين مختلفتينواضح؟ و لو بدى
+
+354
+00:32:26,170 --> 00:32:32,790
+احول ال 6 والترانس لازم اعمل
+
+355
+00:32:32,790 --> 00:32:36,870
+bond breaking و bond formation هذا الكلام بينطبق
+
+356
+00:32:36,870 --> 00:32:40,550
+على ال alkenes اللي فيهم ظاهرة ال 6 والترانس و
+
+357
+00:32:40,550 --> 00:32:46,810
+بينطبق أيضا على ال cycloalkenes كل هذه مفاهيم
+
+358
+00:32:46,810 --> 00:32:54,970
+أساسية و مهمة جدا في فعلنا لهذه الظاهرةالـ
+
+359
+00:32:54,970 --> 00:32:58,130
+Stereoisomers أو الـ Diastereomers اللي هي ظاهرة
+
+360
+00:32:58,130 --> 00:33:02,910
+الـ cis والترانس مكان وجودها الـ Cycloalkynes و
+
+361
+00:33:02,910 --> 00:33:09,230
+الـ Alkenes شرط وجودها ان كل طرف من الأطراف تبعت
+
+362
+00:33:09,230 --> 00:33:14,670
+ال carbons المكونة للـ double bond بتحمل مجموعتين
+
+363
+00:33:14,670 --> 00:33:17,890
+مختلفتين عشان ايك لو حد انا بدي احكي عن ال cis
+
+364
+00:33:17,890 --> 00:33:22,420
+والترانس هذه ال carbon شو بتحمل؟نفس المجموعات، هذا
+
+365
+00:33:22,420 --> 00:33:26,000
+ال carbo شو بتحمل؟ هذا شو بتحمل؟ أنا مافيش عنده ال
+
+366
+00:33:26,000 --> 00:33:31,060
+cis و ال trans، خلاص هو مركّب واحد، واضح؟ شرط فكرة
+
+367
+00:33:31,060 --> 00:33:37,870
+ال cis و ال trans أنه يكون عندهع كل طرف من أطراف
+
+368
+00:33:37,870 --> 00:33:41,250
+ال carbon سواء في الحلقة أو في ال double bond
+
+369
+00:33:41,250 --> 00:33:45,510
+مجموعات مختلفة ولذلك لو سألنا مثلا يا ترى هذا
+
+370
+00:33:45,510 --> 00:33:49,210
+المركب ال carbon double bond carbon وحطين هنا CL و
+
+371
+00:33:49,210 --> 00:33:54,690
+هنا CL و هنا H و هنا CL هل هذا في منه cis و trans؟
+
+372
+00:33:54,690 --> 00:34:02,790
+لأ هذا فقط مركب واحد لأن هنا HCL مختلفة لكن نفس
+
+373
+00:34:02,790 --> 00:34:12,160
+الشيءو شرط ال sis و ال trans مختلفة مختلفة غير هيك
+
+374
+00:34:12,160 --> 00:34:18,320
+ما بنتكلمش عن sis و trans سواء كنا بنحكي في ال ال
+
+375
+00:34:18,320 --> 00:34:25,600
+keys أو كنا بنحكي في الحلقات ال cyclo ال keys
+
+376
+00:34:30,680 --> 00:34:36,320
+أتعمقنا كثير في الـ Cyclopropane لكن أخدنا معلومات
+
+377
+00:34:36,320 --> 00:34:42,820
+كثير مهمة بخصوص ظاهرة بتتكرر معنا سواء الآن أو في
+
+378
+00:34:42,820 --> 00:34:48,060
+المستقبل لما ندرس ال الكينز الآن لو إجيت لمركب
+
+379
+00:34:48,060 --> 00:34:50,380
+الـcyclobutane
+
+380
+00:34:53,020 --> 00:34:57,300
+كم هيدروجين فيه؟ أربع كربونات كل كربون تو
+
+381
+00:34:57,300 --> 00:35:03,960
+هيدروجين؟ تمانية التمانية they are equivalent يعني
+
+382
+00:35:03,960 --> 00:35:09,020
+لو كنت أعمل عليه monochlorination بطلع بس مركب
+
+383
+00:35:09,020 --> 00:35:14,340
+واحد لكن لو قلنا نبدأ بالcyclobutane ونعمل
+
+384
+00:35:14,340 --> 00:35:20,260
+dichlorination هيطلع عندنا أكيد عدد أكبر من
+
+385
+00:35:20,260 --> 00:35:24,940
+المركباتواضح؟ يعني انتوا تخيلوا مش كل شي بدنا
+
+386
+00:35:24,940 --> 00:35:28,500
+نفصله بدنا نسيب شي انتوا تجربوه في البيت يعني هي
+
+387
+00:35:28,500 --> 00:35:33,360
+عندى ذرة الكلور الأولى و هنا فيه H لو بدى أحط كلور
+
+388
+00:35:33,360 --> 00:35:41,880
+تانية ممكن أحطها على الموقع الأول اعمل one one
+
+389
+00:35:41,880 --> 00:35:46,200
+dichlorocyclopropane صحيه ولا لأ؟ ممكن أحطها على
+
+390
+00:35:46,200 --> 00:35:53,330
+الموقع التانيأو Trans ممكن احطه على الموقع التالت
+
+391
+00:35:53,330 --> 00:35:59,030
+ايضا SIS او Trans بمعنى في الحلقة مش ضروري مش
+
+392
+00:35:59,030 --> 00:36:02,830
+ضروري ان ال SIS و ال Trans يكونوا جانب بعض يعني
+
+393
+00:36:02,830 --> 00:36:09,910
+هاي تخيلوا هذا Cyclobutane تجاوزا هاي ذرتين لكلور
+
+394
+00:36:09,910 --> 00:36:15,960
+خلينا نتخيلهم باللون الأحمر هذا المركب اي مركبone
+
+395
+00:36:15,960 --> 00:36:22,040
+one-dichlorocyclobutane، الآن هذا المركّب one two
+
+396
+00:36:22,040 --> 00:36:30,660
+-cis، هذا one two-trans، هذا one three-cis، هذا
+
+397
+00:3
+
+445
+00:40:47,820 --> 00:40:52,200
+شايفين كيف أنا مسكها؟ الان هذا الشكل اللي أنا ماسكه
+
+446
+00:40:52,200 --> 00:40:59,000
+يشبه ماذا؟ القارب او الزورق بسمي أنا هيئة القارب
+
+447
+00:40:59,000 --> 00:41:04,740
+boat confirmation boat confirmation موجود عندكم
+
+448
+00:41:04,740 --> 00:41:13,520
+ربما بهذا المكان شايفينه؟
+
+449
+00:41:14,650 --> 00:41:19,050
+بهذا الشكل بيرسم بسهولة boat conformation يمكن أن
+
+450
+00:41:19,050 --> 00:41:26,830
+يكون على هيئة القارب بهذا الشكل و يمكن أن يكون على
+
+451
+00:41:26,830 --> 00:41:34,270
+هيئة الكرسي لو تخيلته زي هيك هي كأنه هذا كرسي هي
+
+452
+00:41:34,270 --> 00:41:37,910
+الرجلين وهي القاعدة اللي الناس بيجلس عليها وهي
+
+453
+00:41:37,910 --> 00:41:42,100
+الظهرطبعا هذا ال chair confirmation و ال boat
+
+454
+00:41:42,100 --> 00:41:46,020
+confirmation بيجلبه يعني هذا الشكل زي ما بتكون
+
+455
+00:41:46,020 --> 00:41:51,040
+تماما معاكم الشمسية ال umbrella في يوم عاصف كيف
+
+456
+00:41:51,040 --> 00:41:56,960
+بتكون؟ بتجلب للأمام و للخلف؟ هاد العملية بسميها
+
+457
+00:41:56,960 --> 00:42:03,200
+عشان flipping الشكل لما بيصير يجلب بهذا الشكل لفوق
+
+458
+00:42:03,200 --> 00:42:06,940
+لتحت زي الشمسية ما بتعمل بسمي العملية عشان
+
+459
+00:42:06,940 --> 00:42:07,540
+flipping
+
+460
+00:42:10,670 --> 00:42:17,390
+flipping الآن ممكن الـcyclohexane يكون بلحظة boat
+
+461
+00:42:17,390 --> 00:42:22,970
+هذه تجلب لتحت صار chair لحظة هذا ال chair هيظهر
+
+462
+00:42:22,970 --> 00:42:26,790
+للخلف و الأرجل للأمام ممكن تجلب هذه الأرجل تصير
+
+463
+00:42:26,790 --> 00:42:31,830
+بهذا الشكل و بهذا الشكل هو في حالة تقلب دائم يعني
+
+464
+00:42:31,830 --> 00:42:37,390
+الذرات في حالة تقلب دائما تماما مثل مثل إيش شمسية
+
+465
+00:42:37,390 --> 00:42:41,930
+في مهب الريحمثل مثل ال umbrella أو الشمسية في ماب
+
+466
+00:42:41,930 --> 00:42:47,450
+بالريح إذا هو يمكن أن يوجد على هيئة القارب ويمكن
+
+467
+00:42:47,450 --> 00:42:54,680
+أن يوجد على هيئةالكرسي لـ Chair Conformation أو
+
+468
+00:42:54,680 --> 00:43:00,120
+Boat Conformation واضح؟ زي ما حكيت، كثير فيه
+
+469
+00:43:00,120 --> 00:43:04,080
+تفاصيل للهيدروجينات و التركيبة لكن احنا بنتجاوز
+
+470
+00:43:04,080 --> 00:43:08,780
+هذا الكلام، بنقف ان الـCyclohexane ممكن يكون على
+
+471
+00:43:08,780 --> 00:43:12,500
+شكل الـChair Conformation وبيعمل flipping، بيقلب
+
+472
+00:43:13,380 --> 00:43:19,880
+مرة تانية انا اكد عادى الظاهر هيه بهذا الشكل بيكون
+
+473
+00:43:19,880 --> 00:43:23,500
+share و بيصير boat و بيرجع ت share و ت share بهذا
+
+474
+00:43:23,500 --> 00:43:27,040
+الشكل و ت share بهذا الشكل هو في حالة تقلب ايش
+
+475
+00:43:27,040 --> 00:43:32,860
+دائم الان اي الأشكال اثبت معنى اثبت هنا انه بيقضي
+
+476
+00:43:32,860 --> 00:43:37,380
+في وقت كتير ال share ولا ال boat ال share بنقول
+
+477
+00:43:37,380 --> 00:43:43,580
+عنه is more stable than the boatmore stable معناه
+
+478
+00:43:43,580 --> 00:43:48,360
+more stable أنه أنا لو بتطلع عليه و هو بيجلب هو
+
+479
+00:43:48,360 --> 00:43:53,440
+يتقلب بين هذه الأشكال لكن يبقى لفترة أطول على هيئة
+
+480
+00:43:53,440 --> 00:43:58,580
+إيش الكرسي يبقى لفترة أطول على هيئة الكرسي الآن
+
+481
+00:43:58,580 --> 00:44:04,040
+عملية أنهليش لفترة أطول على هيئة الكرسي؟ ليش هذا
+
+482
+00:44:04,040 --> 00:44:08,140
+أثبت؟ ما إلى ذلك؟ هذا الكلام لطلبة مختصين في
+
+483
+00:44:08,140 --> 00:44:12,600
+الكيميا فيه تفصيل كتير، يعني اللي الآن بنحكيه بخمس
+
+484
+00:44:12,600 --> 00:44:17,480
+دقائق، بنعمله فصل كامل لطالب الكيميا يتعمق فيه
+
+485
+00:44:17,480 --> 00:44:20,140
+بالcyclohexane، لكن احنا الآن اللي بنايعه
+
+486
+00:44:20,140 --> 00:44:25,480
+الcyclohexaneكلام بسيط ان هو non planar molecule
+
+487
+00:44:25,480 --> 00:44:30,700
+يوجد فيه اكتر من conformation هيئة منها ال boat
+
+488
+00:44:30,700 --> 00:44:35,420
+conformation و ال chair conformation واضح ال boat
+
+489
+00:44:35,420 --> 00:44:39,120
+conformation و ال chair conformation اكتر من هيك
+
+490
+00:44:39,120 --> 00:44:45,770
+مابدناش نتكلم عن هذا الموضوعطبعا الكلام اللي هو
+
+491
+00:44:45,770 --> 00:44:50,290
+حكيناه عن الـcis و الـtrans في الحلقات الخماسية
+
+492
+00:44:50,290 --> 00:44:54,790
+والسوداسية والسبعية والربعية والثلاثية كله موجود
+
+493
+00:44:54,790 --> 00:45:00,910
+واضح؟ كله موجود أخر شغلة بدنا نتكلمها اليوم إن شاء
+
+494
+00:45:00,910 --> 00:45:09,660
+الله تفاعلات الالكانز تفاعلات الالكانزقليلة جدا،
+
+495
+00:45:09,660 --> 00:45:12,880
+عشانيك احنا بنقول الالكينز they are generally
+
+496
+00:45:12,880 --> 00:45:17,220
+inert، ايش يعني inert؟ يعني قليلة التفاعلات،
+
+497
+00:45:17,220 --> 00:45:21,540
+عشانيك كل اشي inert يستعمل ك solvent، يعني يستعمل
+
+498
+00:45:21,540 --> 00:45:25,680
+كمثيب عضوي، لأن الأشياء بتكون في قلبه و بتفعلش
+
+499
+00:45:25,680 --> 00:45:32,220
+معها، في تفاعل مشهور جدا للالكينز، ان الالكينز لو
+
+500
+00:45:32,220 --> 00:45:36,840
+حرقناهم في وجود الأكسجين، بيعطونا ثانو أكسيد كربون
+
+501
+00:45:36,840 --> 00:45:42,940
+وماءوهذا التفاعل هو تفاعل حرق الغاز المنزلي لما
+
+502
+00:45:42,940 --> 00:45:47,660
+احنا بنشعل الغاز هو تفاعل حرق على سبيل المثال
+
+503
+00:45:47,660 --> 00:45:53,220
+الوقود البنزين والديزل في السيارات كله الكان
+
+504
+00:45:53,220 --> 00:45:58,180
+بنحرقه في وجود ال oxygen بنسمي العملية combustion
+
+505
+00:45:58,180 --> 00:46:03,200
+إيش يعني combustion burning in the presence of
+
+506
+00:46:03,200 --> 00:46:09,540
+oxygen burning يعني burningin the presence of
+
+507
+00:46:09,540 --> 00:46:17,980
+oxygen ايش بيعطيني؟ ثاني أكسيد كربون وماء بدون ما
+
+508
+00:46:17,980 --> 00:46:21,480
+ندخل بتفاصيل الأرقام كيف توزن المعادلة مش الموضوع
+
+509
+00:46:21,480 --> 00:46:26,400
+احنا بهمنا الآن النتيجة ان الالكينز بصير التفاعل
+
+510
+00:46:26,400 --> 00:46:32,700
+مع الأكسجين تعطيتانو أكسيد كربون و ماء زائد و ربما
+
+511
+00:46:32,700 --> 00:46:37,880
+أهم من الشغلتين بالنسبة لنا ال heat الحرارة عشان
+
+512
+00:46:37,880 --> 00:46:41,380
+هيك حرق الغاز و حرق البنزين اللي بيعطيني حرارة
+
+513
+00:46:41,380 --> 00:46:45,700
+بشغل عليها موقد الغاز بمشي عليها السيارة كل هذه
+
+514
+00:46:45,700 --> 00:46:50,130
+الأشياءالشغل التاني أو التفاعل التاني ال
+
+515
+00:46:50,130 --> 00:46:54,270
+halogenation هو التفاعل مع ال halogens الكلور و
+
+516
+00:46:54,270 --> 00:46:58,690
+البرومي بشكل أساسي عادة يتم هذا التفاعل في وجود
+
+517
+00:46:58,690 --> 00:47:01,210
+الحرارة أو الضوء
+
+518
+00:47:17,340 --> 00:47:22,460
+كم عدد النواتج اللي بتطلع؟ يعتمد على أنواع
+
+519
+00:47:22,460 --> 00:47:27,240
+الهيدروجين يعني لو كان المركب اللي عندكم هو
+
+520
+00:47:27,240 --> 00:47:32,340
+البروبين زي ما احنا حكينا وين
+
+521
+00:47:32,340 --> 00:47:38,040
+هيحط ال chlorine؟ يا ع موقع واحد و ال chlorine و
+
+522
+00:47:38,040 --> 00:47:40,400
+البروبين يا ع موقع اتنين اتنين اتنين اتنين اتنين
+
+523
+00:47:40,400 --> 00:47:40,820
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+524
+00:47:40,820 --> 00:47:41,480
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+525
+00:47:41,480 --> 00:47:41,500
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+526
+00:47:41,500 --> 00:47:46,500
+اتنين اتنين اتنين اتنين اتنين اتنين ااو ايزوبروبل
+
+527
+00:47:46,500 --> 00:47:49,900
+اكلورايد لو نفس المراكب بيقولنا بيعمله
+
+528
+00:47:49,900 --> 00:47:56,090
+دايكلوريلاشينوين ممكن احض دارتين لكلور؟ يا على
+
+529
+00:47:56,090 --> 00:47:59,750
+نمرة واحد واحد بيصير one one dichlorobropane يا
+
+530
+00:47:59,750 --> 00:48:07,150
+على واحد واثنين يا ع اتنين واثنين او ع واحد واثنين
+
+531
+00:48:07,150 --> 00:48:11,170
+او ع واحد تلاتة اذا لو انا قلتلكم dichlorination
+
+532
+00:48:11,170 --> 00:48:16,210
+of a propane produces come isomers كي بتكون تعمله
+
+533
+00:48:16,210 --> 00:48:22,960
+و تجربه بالورقة و الجلمتستفيدوا من كل المعلومات
+
+534
+00:48:22,960 --> 00:48:28,720
+اللي حكيناها بمعنى لو كان السؤال عندكم عن cycle
+
+535
+00:48:28,720 --> 00:48:33,000
+بتعرفوا تجاوبوه احنا اليوم جاوبناها لـcyclopropane
+
+536
+00:48:33,000 --> 00:48:37,220
+قولنا الـ monochlorination بيعطينا كام مركب؟ واحد
+
+537
+00:48:37,220 --> 00:48:43,300
+ال-dichlorination بيعطينا كام مركب؟ تلاتةسمناهم
+
+538
+00:48:43,300 --> 00:48:48,640
+one one و one two six و one two .. Trans مظبوط ولا
+
+539
+00:48:48,640 --> 00:48:53,860
+لأ؟ و هكذا دائما ممكن يجيكم أسئلة و ممكن الأن
+
+540
+00:48:53,860 --> 00:48:58,540
+ماعطيكم سؤالين أنتوا تحلوهم لوحدكم تتدربوا عليهم و
+
+541
+00:48:58,540 --> 00:49:03,980
+بننهي فيهم المحاضرة لو مثلا قلنالكوا اعملونا لمركب
+
+542
+00:49:03,980 --> 00:49:11,980
+لبيوتينمونو إكلورينايشن ودايكلورينايشن تعملوه و
+
+543
+00:49:11,980 --> 00:49:16,400
+تسلمونا إياه و لهذا المُركّب لو تخيلتوا إنه في
+
+544
+00:49:16,400 --> 00:49:23,000
+عندكم مثل سايكلوبروبين شايفينه
+
+545
+00:49:23,000 --> 00:49:29,160
+المُركّب؟ إيش اسمه؟ مثل سايكلوبروبين اعملوله مونو
+
+546
+00:49:29,160 --> 00:49:34,510
+إكلورينايشنوDichlorination وشوفوا كم ناتج بيطلع
+
+547
+00:49:34,510 --> 00:49:38,230
+عندكم طبعا بتكونوا تنتبهوا ان الchlorination ممكن
+
+548
+00:49:38,230 --> 00:49:43,330
+يجي على المثل او على الحلقة بدي كل النواتج الممكنة
+
+549
+00:49:43,330 --> 00:49:47,830
+وهنا كل النواتج الممكنة هذا بحاجة انكوا تتدربوا
+
+550
+00:49:47,830 --> 00:49:52,700
+بشكل جيدو تعرفوا أنواع الهيدروجينز اللي موجودة و
+
+551
+00:49:52,700 --> 00:49:56,040
+تحددوا كام ناتج بيطلع عندهم من ال monochlorination
+
+552
+00:49:56,040 --> 00:50:00,340
+و ال dichlorination ترسموهم بعد ما ترسموهم انتبهوا
+
+553
+00:50:00,340 --> 00:50:05,180
+إذا في أشكال متشابهة انه ما تكرروهاش وبهيك بننهي
+
+554
+00:50:05,180 --> 00:50:06,040
+اليوم ان شاء الله
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..82a5200cf7ab9e0e4c85df14d592edc3c2b33801
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_postprocess.srt
@@ -0,0 +1,1960 @@
+1
+00:00:18,780 --> 00:00:24,830
+بسم الله الرحمن الرحيمبعد ما اتكلمنا المرة الماضية
+
+2
+00:00:24,830 --> 00:00:29,410
+عن السكريات المنفردة اتعرفنا عليها ال mono
+
+3
+00:00:29,410 --> 00:00:34,750
+-saccharides الان بدنا نتكلم عن ال di-saccharides
+
+4
+00:00:34,750 --> 00:00:39,930
+طبعا اللي بنقصده احنا ب di-saccharides انه جزيئين
+
+5
+00:00:39,930 --> 00:00:43,910
+من ال mono-saccharides يتحدوا مع بعض و بيعملوا
+
+6
+00:00:43,910 --> 00:00:51,360
+ايش؟ di-saccharide الان مش دائما مش دائمامش دائما
+
+7
+00:00:51,360 --> 00:00:54,820
+هدول الجزيئين اللي بدهم يتحدوا مع بعض بيكونوا زي
+
+8
+00:00:54,820 --> 00:01:00,140
+بعض يعني يوم بدأ احكي انا عن دايسا كرايد ممكن اجيب
+
+9
+00:01:00,140 --> 00:01:06,260
+نفس الجزيئين تماما بكل محتوياتهم طبعا بالتأكيد ال
+
+10
+00:01:06,260 --> 00:01:09,680
+stereo chemistry تكون نفس الشيء تماما و يعملوا
+
+11
+00:01:09,680 --> 00:01:14,040
+دايسا كرايد و ممكن اجيب جزيئين مختلفين و يعملوا
+
+12
+00:01:14,040 --> 00:01:19,820
+دايسا كرايد فمش ضروريمش ضروري ان الـ disaccharide
+
+13
+00:01:19,820 --> 00:01:26,240
+يكون مكوّن من الجزيئين نفسهم تماما، واضح؟ يعني
+
+14
+00:01:26,240 --> 00:01:30,560
+ممكن يكون فعلا من نفس الجزيئين مكوّن disaccharide
+
+15
+00:01:30,560 --> 00:01:36,920
+وممكن يكون من جزيئين مختلفين وهذا اللي هنشوفه لما
+
+16
+00:01:36,920 --> 00:01:45,550
+نستعرض بعض الـ disaccharides بشكل عام ويعني جداأول
+
+17
+00:01:45,550 --> 00:01:51,710
+دايسا كارايد بدنا نستعرضه المالتوز، واضح؟
+
+18
+00:01:51,710 --> 00:01:57,970
+المالتوز، الآن هذا الديسا كارايد مكون من سكرين
+
+19
+00:01:57,970 --> 00:02:03,070
+جولوكوز، لكن فيهم اختلاف في ال stereo chemistry
+
+20
+00:02:03,470 --> 00:02:08,830
+فيهم اختلاف في ال stereo chemistry واحد منهم واحد
+
+21
+00:02:08,830 --> 00:02:14,730
+منهم alpha glucose والتاني منهم beta glucose الآن
+
+22
+00:02:14,730 --> 00:02:19,390
+اللي بتذكروا معنا قولنا احنا ان ال alpha و ال beta
+
+23
+00:02:19,390 --> 00:02:24,930
+sugars بصيروا لما نسكر اخر carbon اللي سمناها ال
+
+24
+00:02:24,930 --> 00:02:29,300
+anomeric carbon و نعملفي حالة السكريات هذه الميزات
+
+25
+00:02:29,300 --> 00:02:35,240
+الكربونات ال fifth chiral center فإذا ال OH كانت
+
+26
+00:02:35,240 --> 00:02:40,020
+للأسفل على هذا الكربون تحديدا بنقول هذا السكر
+
+27
+00:02:40,020 --> 00:02:46,120
+Alpha وإذا كانت للأعلى Beta الآن هذا ال maltose لو
+
+28
+00:02:46,120 --> 00:02:50,760
+بتطلع عليه أنا هيمكون من سكر متصل في ال anomeric
+
+29
+00:02:50,760 --> 00:02:54,560
+carbon لاحظوا أنا تركيزي على أي كربون ال anomeric
+
+30
+00:02:54,560 --> 00:02:59,820
+carbon نكون معلمينها إلى أساساهذه السكرين المتحدين
+
+31
+00:02:59,820 --> 00:03:07,180
+الآن اتطلعوا على واحد منهم ال oxygen فيه alpha
+
+32
+00:03:07,180 --> 00:03:18,840
+واضح التاني منهم ال oxygen فيه betaواضح فالملتوز
+
+33
+00:03:18,840 --> 00:03:24,740
+بيكون في هذه الحالة امكون من Alpha-Glucose مع Beta
+
+34
+00:03:24,740 --> 00:03:29,660
+-Glucose هى دول اتنين قبل ما يتصلوا مع بعض هذا
+
+35
+00:03:29,660 --> 00:03:35,440
+بهذا الشكل كان OH كان Alpha-Glucose هذا كان Beta
+
+36
+00:03:35,440 --> 00:03:41,320
+-Glucose فاتنين اتصلوا مع بعض من خلال موقع اربعة
+
+37
+00:03:41,320 --> 00:03:45,060
+لما ناخد الترقيم واحد اتنين تلاتة اربعة هذا الموقع
+
+38
+00:03:46,020 --> 00:03:49,540
+أربعة اتحدوا من خلال هذه ال Oxygenة اللي في موقع
+
+39
+00:03:49,540 --> 00:03:55,920
+أربعة عملوا رابطة واضح فصار عند المركب مكوّن من
+
+40
+00:03:55,920 --> 00:04:03,040
+Alpha و من Dبيتا جولوكوز وعشان هيك لما بدنا نسميه
+
+41
+00:04:03,040 --> 00:04:09,900
+ممكن انه نقرأ الاسم تبعه هتحسوا انه مش صعب هو ممكن
+
+42
+00:04:09,900 --> 00:04:15,120
+تتخيلوا مركب بيتا جولوكوز لو حطيت ع موقع اربعة مثل
+
+43
+00:04:15,120 --> 00:04:19,960
+شو كنتوا هتسموه four مثل بيتا جولوكوز
+
+44
+00:04:23,450 --> 00:04:29,690
+الاسم الـ Beta في آخر الكلام Beta-D-Glucobiranose
+
+45
+00:04:29,690 --> 00:04:35,170
+مش سمناه لأن جولوكوزم سكرة حلقة سداسية
+
+46
+00:04:35,170 --> 00:04:40,030
+Glucobiranose وD و Beta لأن هذه موجودة في الوضع
+
+47
+00:04:40,030 --> 00:04:45,410
+Beta الآن هذا على موقع أربعة هي على موقع أربعة من
+
+48
+00:04:45,410 --> 00:04:50,950
+خلال ال Oxygen متحد بإيش ب Alpha-D-Glucobiranose
+
+49
+00:04:51,620 --> 00:04:57,800
+واضح الفكرة؟ فيذكر الاسم العام على موقع أربعة من
+
+50
+00:04:57,800 --> 00:05:05,690
+هذا السكر، إيش موجود عنده على موقع أربعة؟الفا دي
+
+51
+00:05:05,690 --> 00:05:08,890
+جلوكو بايرانوس طبعا اتصاله من خلال ال O عشان هيك
+
+52
+00:05:08,890 --> 00:05:13,490
+كتبنا O فاللي بده يفهم الاسم الاسم مش صعب انه هاي
+
+53
+00:05:13,490 --> 00:05:18,290
+المركب اللي عندى بيتا جلوكو بايرانوس على موقع
+
+54
+00:05:18,290 --> 00:05:22,650
+اربعة منه ايش ايجا نعتبرها بين قوسينAlpha
+
+55
+00:05:22,650 --> 00:05:28,230
+Glucobiranose فهذا سكر الملتوز ببساطة هذه الأشياء
+
+56
+00:05:28,230 --> 00:05:34,030
+بيبقى تفهموا فيها الأفكار العامة فالملتوز من سكرين
+
+57
+00:05:34,030 --> 00:05:38,350
+جولوكوز لكن اتنين مش Alpha Alpha ولا Beta Beta
+
+58
+00:05:38,350 --> 00:05:46,590
+Alpha مع Betaالان بيجيني سكر تاني السيلو بيوز
+
+59
+00:05:46,590 --> 00:05:55,730
+السيلو بيوز متحد من سكرين متفقين تماما بيتا جلوكو
+
+60
+00:05:55,730 --> 00:06:00,550
+بيرانوز مع بيتا جلوكو بيرانوز واضح؟ ولذلك لو انا
+
+61
+00:06:00,550 --> 00:06:07,550
+بدأ اطلع على هذا السكر هذا بيتا ولا لا؟ بيتا وعلى
+
+62
+00:06:07,550 --> 00:06:14,780
+هذا السكرهذه أيضًا Beta فلما بنسميه نسبة لهذا Beta
+
+63
+00:06:14,780 --> 00:06:20,740
+D Glucopyranose متحد من موقع أربعةواحد اتنين تلاتة
+
+64
+00:06:20,740 --> 00:06:25,880
+اربعة متحد من موقع اربعة من خلال ال oxygen ال beta
+
+65
+00:06:25,880 --> 00:06:31,160
+D-glucobiranose واضح يعني هذا كأننا بنقول beta D
+
+66
+00:06:31,160 --> 00:06:36,660
+-glucobiranose يحمل على موقع اربعة beta D
+
+67
+00:06:36,660 --> 00:06:42,100
+-glucobiranose واضح الفكرة فال cellobiose بيكون من
+
+68
+00:06:42,100 --> 00:06:50,330
+سكرين متماثلينتماما، لاحظوا قداش نسبة الخلاف اللي
+
+69
+00:06:50,330 --> 00:06:56,450
+بتعمل يعني مركبات مختلفة، يعني انا بحكي عن
+
+70
+00:06:56,450 --> 00:07:02,330
+Glucopyranose و Glucopyranose و بحكي عن هذا Beta
+
+71
+00:07:02,330 --> 00:07:06,870
+في الحالتين، بس التاني مرة Beta و مرة ايش Alpha
+
+72
+00:07:07,710 --> 00:07:14,870
+خلاف بسيط جدا بس كايرال سنتر واحد، الآن بعد شوية
+
+73
+00:07:14,870 --> 00:07:19,770
+هتكتشفوا ان هذا الخلاف البسيط جدا في كايرال سنتر
+
+74
+00:07:19,770 --> 00:07:26,510
+الوحيد بيتبع خلاف كبير جدا جدا جدا في الخواص بعد
+
+75
+00:07:26,510 --> 00:07:31,760
+ذلك للمراكباتيعني لما ييجيوا الجزيئات الـ
+
+76
+00:07:31,760 --> 00:07:35,200
+disaccharides بدهم يعملوا polysaccharides هاي
+
+77
+00:07:35,200 --> 00:07:38,540
+disaccharide و خلّينا نعتبر هاي كمان disaccharide
+
+78
+00:07:38,540 --> 00:07:43,120
+هذا كان من Beta و Beta و هذا كان من Beta و Alpha
+
+79
+00:07:43,120 --> 00:07:47,660
+الان اللي كان من Alpha و Beta الملتوز بيعمل جزئ
+
+80
+00:07:47,660 --> 00:07:56,080
+كبير اسمه نشا او glycogenاللي هي تخزين أو أماكن
+
+81
+00:07:56,080 --> 00:07:59,380
+تخزين ال carbohydrates سواء في النبات أو في
+
+82
+00:07:59,380 --> 00:08:03,400
+الحيوان وهذه بتدوب في الميه وبيقدر البني آدم
+
+83
+00:08:03,400 --> 00:08:07,000
+يهضمها يعني البني آدم لما بياكل النشويات بيقدر
+
+84
+00:08:07,000 --> 00:08:12,180
+بسهولة يحللها للسكريات الأولية بتاعتها أكيد الآن
+
+85
+00:08:12,180 --> 00:08:16,060
+اللي مكوّن من ال beta و ال beta هيجي يعمل ال
+
+86
+00:08:16,060 --> 00:08:20,600
+cellulose هيعمل الخشب البني آدم بيقدرش يهضم الخشب
+
+87
+00:08:20,600 --> 00:08:27,570
+الآن هتيجي تقوله شو الفرق؟بين أساس الخشب و أساس
+
+88
+00:08:27,570 --> 00:08:33,270
+النشا أساس الخشب cellobiose و اتحد و أعطاني
+
+89
+00:08:33,270 --> 00:08:39,110
+cellulose و أساس النشا الملتوز و أعطاني starch
+
+90
+00:08:39,110 --> 00:08:46,230
+واضح فقط مختلفين هدول الاتنين بواحد من السكريات
+
+91
+00:08:46,230 --> 00:08:49,770
+جولوكوز جولوكوز صح جولوكوز جولوكوز بس هذا beta و
+
+92
+00:08:49,770 --> 00:08:55,240
+beta هذا beta و alphaمخيلوا كيف اختلاف بسيط في ال
+
+93
+00:08:55,240 --> 00:09:00,740
+stereochemistry بيقدر الاختلاف كبير بعد هيك في
+
+94
+00:09:00,740 --> 00:09:05,480
+الخواص و في الاستفادة من المركبات بيجينا سكر
+
+95
+00:09:05,480 --> 00:09:15,960
+الحليب ال lactoseاللاكتوز أيضا في جولوكوز لكن في
+
+96
+00:09:15,960 --> 00:09:20,900
+جالاكتوز يعني هدولا ال stereo chemical centers
+
+97
+00:09:20,900 --> 00:09:26,320
+اتغير فيهم اكتر كل الفروقات بينهم هي فروقات ايش
+
+98
+00:09:26,320 --> 00:09:30,500
+لحتى لها ال stereo chemistry يعني هذه الوحدة مش
+
+99
+00:09:30,500 --> 00:09:36,340
+بيتا جولوكوز في هذه الحالة الفا جولوكوز متحد مع
+
+100
+00:09:36,340 --> 00:09:42,300
+بيتا جالاكتوزعشانك لو ذكرنا الاسم العام هتلاحظوا
+
+101
+00:09:42,300 --> 00:09:47,260
+في الآخر Alpha D Glucopyranose هي ال Alpha D
+
+102
+00:09:47,260 --> 00:09:54,480
+Glucopyranose وشايفين أنها Alpha الآن متحد من موقع
+
+103
+00:09:54,480 --> 00:10:01,340
+أربعة ال Beta D Galactopyranose طبعا بنكتب Beta D
+
+104
+00:10:01,340 --> 00:10:07,450
+Galactopyranoseال YL اللي هي بصفته أصبح مجموعة زي
+
+105
+00:10:07,450 --> 00:10:14,330
+ما بقول مثل اثل بروبل ال YL لأنه أصبح مجموعة واضحة
+
+106
+00:10:14,330 --> 00:10:20,630
+الفكرة؟ هذا ال lactose طبعا بيجي صاحبنا، مين
+
+107
+00:10:20,630 --> 00:10:27,330
+صاحبنا؟السكاروز ماحدش اقول عن السكاروز العدو
+
+108
+00:10:27,330 --> 00:10:33,030
+تبعنا، يعني في ناس دائما متطرفين في الحكم على اللي
+
+109
+00:10:33,030 --> 00:10:37,090
+هي هذه الأشياء، كل هذه السكريات و كل حتى الدهون
+
+110
+00:10:37,090 --> 00:10:40,730
+بتلزم للإنسان، بس المشكلة مش أن الإنسان ياخد
+
+111
+00:10:40,730 --> 00:10:45,340
+سكريات و ياخد دهونالمشكلة أنه ياخدها بإفراط يعني
+
+112
+00:10:45,340 --> 00:10:49,160
+الإنسان بحاجة للسكريات، بحاجة للدهون بالتأكيد،
+
+113
+00:10:49,160 --> 00:10:53,940
+بحاجة للكلسترول، بحاجة لكل إشي لكن الإفراط في أي
+
+114
+00:10:53,940 --> 00:10:58,840
+شغل هو اللي بيعمل عندنا إيش المشكلة الآن لو إجينا
+
+115
+00:10:58,840 --> 00:11:02,640
+اتطلعنا على السكروز اللي هو السكر اللي إحنا
+
+116
+00:11:02,640 --> 00:11:07,540
+بنستعمله هتلاحظوا مرة تانية في عندى Alpha
+
+117
+00:11:07,540 --> 00:11:11,680
+-Glucopyranose هاي Alpha هذه شايفينها؟
+
+118
+00:11:14,950 --> 00:11:19,930
+طالما لا أسفل إذا هذه إيش؟ Alpha لكن المرة هذه
+
+119
+00:11:19,930 --> 00:11:27,030
+الاتحاد تبعه مش من موقع أربعة هو متحد ب fractose
+
+120
+00:11:27,030 --> 00:11:33,390
+واضح؟ هو متحد ب fractose و ال fractose keto sugar
+
+121
+00:11:33,390 --> 00:11:38,370
+لما أخدنا السكريات قلنا إن في عندنا ال doses من ال
+
+122
+00:11:38,370 --> 00:11:43,920
+aldehydesو Ketosis لفراكتوز كيتو شوجار و لما بيسكر
+
+123
+00:11:43,920 --> 00:11:50,240
+بيسكر على السكر خماسي السكر الخماسي فيورانوز و من
+
+124
+00:11:50,240 --> 00:11:56,020
+الفيورانوز متحد من موقع ايش؟ واحد واضح؟ الان هذا
+
+125
+00:11:56,020 --> 00:12:04,630
+الفيورانوز لما بتطلع فيهبيتا واضح؟ اذا هذا بيتا
+
+126
+00:12:04,630 --> 00:12:09,270
+عشانك هتلاقوا الاسم تبعه اعتبروا ان هذا هو الأصل
+
+127
+00:12:09,270 --> 00:12:14,010
+وهذه هي الاش المجموعة اللي جاية على الأصل واضح؟
+
+128
+00:12:14,010 --> 00:12:19,950
+فهتلاحظوا بيتا دي فراكتو فيورانوزيل طبعا
+
+129
+00:12:19,950 --> 00:12:26,210
+فيورانوزيل لأنه جاي ايش؟ مجموعة متحدة مع الف دي
+
+130
+00:12:26,210 --> 00:12:33,150
+غلوكوما كتبش هنا by rhinos، كتب by rhinocide، ليش؟
+
+131
+00:12:33,150 --> 00:12:37,790
+لأن الاتحاد تم هنا من موقع واحد، لاحظوا في
+
+132
+00:12:37,790 --> 00:12:41,270
+السكريات اللي قبل شوية، لما كنا نيجع هذا السكر،
+
+133
+00:12:41,270 --> 00:12:45,150
+الاتحاد تم من أي موقع؟ أربعة، هنا الاتحاد تم من
+
+134
+00:12:45,150 --> 00:12:53,080
+موقع واحد، فإذا هذه الرابطة بطلت OH صارت O-Carbon
+
+135
+00:12:53,080 --> 00:12:58,340
+معنا ذلك هذه الرابطة ايش بدها تكون؟ Glycosidic
+
+136
+00:12:58,340 --> 00:13:02,280
+bond واضح؟ عشان Glycosidic bond عشان تكون
+
+137
+00:13:02,280 --> 00:13:08,400
+Glycoside هنحط ايش؟ Glucoburanoside لاحظته هنا
+
+138
+00:13:08,400 --> 00:13:12,640
+كلمة؟ Buranoside لو رجعتوا على الأسماء اللي قبل
+
+139
+00:13:12,640 --> 00:13:19,240
+كان حط Glucoburanose لأن هذه كانت تكون OHفي كل
+
+140
+00:13:19,240 --> 00:13:23,280
+اللي قبل هذه كانت OH غلوكو باي رانوس سواء كان
+
+141
+00:13:23,280 --> 00:13:28,860
+Alpha أو Beta لكن هنا بطلت OH صار الاتحاد من عندها
+
+142
+00:13:28,860 --> 00:13:33,420
+و عشان هيك صارت هذه الرابطة Glycosidic bond فقال
+
+143
+00:13:33,420 --> 00:13:38,300
+غلوكو باي رانوسايد غلوكو باي رانوسايد فالحقيقة
+
+144
+00:13:40,010 --> 00:13:46,150
+السكر اللى فيه two glycosidic bonds هو سكر ايش
+
+145
+00:13:46,150 --> 00:13:50,210
+السكروز انتبهوا لو كانوا بيسألكوا multiple choice
+
+146
+00:13:50,210 --> 00:13:58,670
+الان هذه الرابطة carbon و carbon هذى glycosidic
+
+147
+00:13:58,670 --> 00:14:04,230
+bond ولا لأ و هذا الرابطة glycosidic bond فلما
+
+148
+00:14:04,230 --> 00:14:10,320
+نيجي نطلع احنا حقيقة على السكروزكم جليكوسايدك بوند
+
+149
+00:14:10,320 --> 00:14:18,940
+فيه؟ تنتين لو رجعنا اتطلعنا على السكريات
+
+150
+00:14:18,940 --> 00:14:25,100
+اللي قبل هنا كم جليكوسايدك بوند؟ واحدة ماحدش يقول
+
+151
+00:14:25,100 --> 00:14:29,520
+هذه جليكوسايدك بوند ليش؟ لأن الجليكوسايدك بوند
+
+152
+00:14:29,520 --> 00:14:34,700
+اللي بتتكون على الكايرال سنتر الأخير على هذه مش
+
+153
+00:14:34,700 --> 00:14:40,650
+على هذا الموقع أربعةواضح؟ يعني مش اي او كربون
+
+154
+00:14:40,650 --> 00:14:47,850
+glycosidic bond ال glycosidic bond مرتبطة بأي بأي
+
+155
+00:14:47,850 --> 00:14:52,630
+كربون بال anomeric carbon اللي كانت أساسا الديهايد
+
+156
+00:14:52,630 --> 00:14:56,350
+واضح؟ ولذلك هذه glycosidic bond بس هذه مش
+
+157
+00:14:56,350 --> 00:15:01,390
+glycosidic bond واضح؟ فلو أنا اجيت على ال lactose
+
+158
+00:15:01,390 --> 00:15:08,540
+في one glycosidic bond لو رجعتعلى السيلو بيوز على
+
+159
+00:15:08,540 --> 00:15:13,640
+سبيل المثال برضه أي واحدة anomeric carbon كل سكر
+
+160
+00:15:13,640 --> 00:15:17,780
+فيه two anomeric carbon مظبوط ولا لأ هذه فيها
+
+161
+00:15:17,780 --> 00:15:24,200
+glycosidic bond هذه فيها لذلك في السيلو بيوز في
+
+162
+00:15:24,200 --> 00:15:30,950
+عنده one glycosidic bond هذه لأواضحة الفكرة؟ يعني
+
+163
+00:15:30,950 --> 00:15:34,970
+انا عندي two anomeric carbons مين فيهم glycosidic
+
+164
+00:15:34,970 --> 00:15:40,630
+bond؟ هذي ال O H glycosidic، هذي، اه واضحة الفكرة؟
+
+165
+00:15:40,630 --> 00:15:44,950
+فدائما لما بدنا نعرف كام glycosidic bond، نرجع على
+
+166
+00:15:44,950 --> 00:15:53,670
+الملتوز مثلا، هذي ال anomeric carbons الآن لو
+
+167
+00:15:53,670 --> 00:15:57,690
+إجينا سألنا هذي glycosidic bond؟ O H، هذي
+
+168
+00:15:59,540 --> 00:16:07,100
+Glycosidic bond فالملتوز والسيلوبيوز واللاكتوز
+
+169
+00:16:07,100 --> 00:16:11,380
+هدولة فيهم و one glycosidic bond و التانية عادية
+
+170
+00:16:11,380 --> 00:16:16,740
+عشان ايه كنتوا تلاقوا؟ Glucopyranose عادي لكن لما
+
+171
+00:16:16,740 --> 00:16:23,340
+وصلنا للسكروز لو اجينا سألنا وين ال anomeric
+
+172
+00:16:23,340 --> 00:16:24,180
+carbons؟
+
+173
+00:16:26,580 --> 00:16:31,440
+هي الانوميرك كاربونز الان هنا في جليكوسايدك بوند
+
+174
+00:16:31,440 --> 00:16:36,640
+فيه هنا في جليكوسايدك بوند فيه تنتين جليكوسايدك
+
+175
+00:16:36,640 --> 00:16:42,920
+بوند واضح؟ وعشان هيك هذا لما أنهينا اسمه أنهينا ب
+
+176
+00:16:42,920 --> 00:16:49,480
+side اللي هو alpha D-glucopyranoside زي ما اتعلمنا
+
+177
+00:16:49,480 --> 00:16:53,160
+لما أخدنا الجليكوسايدك بوند وقلنا بننهي بإيش؟
+
+178
+00:16:53,160 --> 00:16:54,360
+جليكوسايد
+
+179
+00:16:57,360 --> 00:17:03,560
+هذا بالنسبة لبعض السكريات اللي هي بنستفيد منها ل
+
+180
+00:17:03,560 --> 00:17:08,700
+ال die saccharides الكلام يمكن يجيب بعضه أن القاسم
+
+181
+00:17:08,700 --> 00:17:16,810
+المشترك ربما في الأشياء المحلية طعم الحلوواضح؟
+
+182
+00:17:16,810 --> 00:17:20,550
+يعني الإنسان بيفتش في النهاية عن إيش؟ الطعم كذلك
+
+183
+00:17:20,550 --> 00:17:24,450
+الحال يمكن تلاحظوه في العطور يعني مار علينا و إحنا
+
+184
+00:17:24,450 --> 00:17:31,410
+بنشرح بعض العطور العطور لا يوجد خليني أقول مجموعة
+
+185
+00:17:31,410 --> 00:17:35,810
+كيميائية تكون قاسم مشترك ما بين العطور ما القاسم
+
+186
+00:17:35,810 --> 00:17:41,920
+المشترك؟الرائحة الذكية، الرائحة الجيدة الآن العطر
+
+187
+00:17:41,920 --> 00:17:46,360
+ممكن مرة يكون Easter ممكن مرة يكون الديهيد ممكن
+
+188
+00:17:46,360 --> 00:17:50,440
+مرة يكون كيتون شوفنا الياسمون مثلا شوفنا ..
+
+189
+00:17:50,440 --> 00:17:53,940
+متذكرين الياسمين كان كيتون شوفنا ال Easter's قولنا
+
+190
+00:17:53,940 --> 00:17:58,040
+عنها مواد عطرية مافيش قاسم كيميائي مشترك القاسم
+
+191
+00:17:58,040 --> 00:18:03,310
+الكيميائي ما بين العطورهو الرائحة الجيدة الآن
+
+192
+00:18:03,310 --> 00:18:07,290
+القاسم الكيميائي ما بين ال sweeteners المحليات و
+
+193
+00:18:07,290 --> 00:18:12,970
+منها السكر هو الطعم الاش؟ الحلو ولذلك الآن في
+
+194
+00:18:12,970 --> 00:18:17,490
+سكريات اللي هي السكريات هذه الصناعية اللي بياخدوها
+
+195
+00:18:17,490 --> 00:18:21,430
+الناس اللي عندهم سكر و ما إلى ذلك لو اطلعت على
+
+196
+00:18:21,430 --> 00:18:25,590
+أنواعها المختلفة مش هتلاقيوا شيء مشترك في الشكل
+
+197
+00:18:25,590 --> 00:18:32,500
+بينها لكن هالمراكبات لما حضروهالاحظوا انه طعمها
+
+198
+00:18:32,500 --> 00:18:37,440
+حلو وبشكل عام آمن يعني كتير في مركبات طعمها حلو
+
+199
+00:18:37,440 --> 00:18:40,980
+لكن خطيرة جدا بيقدرش الإنسان يتعامل معايا
+
+200
+00:18:40,980 --> 00:18:45,440
+الكلوروفورم طعمه حلو لكن سامه carcinogenic لكن هذا
+
+201
+00:18:45,440 --> 00:18:50,040
+المركب مثلا بدون ما ناخد طرق تحضيره هو السكارين
+
+202
+00:18:50,040 --> 00:18:54,720
+سواء وجد ع شكل السكارين أو عشان يدوب بيسحبوا القدش
+
+203
+00:18:54,720 --> 00:18:58,580
+بيعملوا ال salt تبعه طبعا دائما لما نقول salt ال
+
+204
+00:18:58,580 --> 00:19:03,300
+salt ليش بنعمله احناعشان الذائبية تكون أعلى في
+
+205
+00:19:03,300 --> 00:19:08,740
+الميه فلو اطلعنا احنا هذا ال sodium سكارين اللي هو
+
+206
+00:19:08,740 --> 00:19:12,740
+اللي بنستعمله و بنحطه على الشاي مافيش علاقة بين
+
+207
+00:19:12,740 --> 00:19:20,080
+شكله وبين شكل السكاروز لكن يوضع بديل للسكاروز،
+
+208
+00:19:20,080 --> 00:19:25,780
+مظبوط ولا لأ؟ ليش يوضع بديل للسكاروز؟ بسبب الطعم
+
+209
+00:19:25,780 --> 00:19:30,730
+الحلو، الآن في سكريات تانية غير السكاروزالسكارين
+
+210
+00:19:30,730 --> 00:19:36,150
+تستعمل منها مثلا ال Aspartame و ال Cyclamates لو
+
+211
+00:19:36,150 --> 00:19:42,110
+فتشته Cyclamates لو فتشته على شكل ال Aspartame و
+
+212
+00:19:42,110 --> 00:19:46,030
+ال Cyclamate و السكارين هتلاقي كل واحد يمثل شكل
+
+213
+00:19:46,030 --> 00:19:52,410
+معين مافيش قاسم مشترك بينهم القاسم المشترك هو إيش؟
+
+214
+00:19:52,410 --> 00:19:57,510
+الطعم الحلو القاسم المشترك هو الطعم الحلو يعني هاي
+
+215
+00:19:57,510 --> 00:20:02,700
+ال Aspartameطلعوا هذا شكل و هذا شكل بتلاحظوا فيه
+
+216
+00:20:02,700 --> 00:20:07,740
+شيء مشترك مع السكرين طب العسل بس زي محلق و بطعم
+
+217
+00:20:07,740 --> 00:20:12,060
+حلو؟ ايه هو؟ العسل؟ ما هو العسل فيه سكريات كتيرة
+
+218
+00:20:12,060 --> 00:20:17,120
+لأ لأ مش من هدولة من السكريات العادية اللي أخدناها
+
+219
+00:20:17,120 --> 00:20:23,000
+بس تركيبته عاد كبيرة في سكريات و فيتامينات و إشي
+
+220
+00:20:23,000 --> 00:20:31,540
+أكثر من شغلها الآنهذه الـ Disaccharides سواء كانت
+
+221
+00:20:31,540 --> 00:20:37,740
+سكريات مختلفة زي الملتوز اللي احنا قلنا عنه Alpha
+
+222
+00:20:37,740 --> 00:20:43,810
+و Beta الجلوكوز متحدين مع بعض أوالسيلو بيوز اللي
+
+223
+00:20:43,810 --> 00:20:47,710
+قلنا عنه بيتا و بيتا يعني خلينا نركز احنا على
+
+224
+00:20:47,710 --> 00:20:52,810
+الملتوز الملتوز كان من ألفة و بيتا جولوكوز مكون
+
+225
+00:20:52,810 --> 00:20:57,790
+واضح؟ و السيلو بيوز من بيتا و بيتا جولوكوز الآن
+
+226
+00:20:57,790 --> 00:21:02,470
+هدولة لما بيجوا بيعملوا بوليمار كبير لما بيعملوا
+
+227
+00:21:02,470 --> 00:21:06,750
+بوليمار كبير بيكون هم الوحدة الأساسية المتكررة في
+
+228
+00:21:06,750 --> 00:21:12,930
+البوليمار بيعطوناالـ starch أو النشا في حالة ما
+
+229
+00:21:12,930 --> 00:21:18,570
+نتكلم عن إيش؟ عن الملتوز، في حالة ما نتكلم عن
+
+230
+00:21:18,570 --> 00:21:22,990
+السيلوبايوز، بيعطينا السيليلوز، واضح؟ فالملتوز
+
+231
+00:21:22,990 --> 00:21:29,130
+بيعطيني إيش؟ النشا، starch، السيلوبايوز بيعطيني
+
+232
+00:21:29,130 --> 00:21:36,470
+السيليلوز، الخشب، واضح؟ بولمار كبير طبعاًلاحظوا
+
+233
+00:21:36,470 --> 00:21:40,990
+عاد حسب ال polymer اللي بتكون يعني يوم ما نحكي عن
+
+234
+00:21:40,990 --> 00:21:45,550
+polymer يعني عدد كبير من الشغلات هتلاحظوا في علم
+
+235
+00:21:45,550 --> 00:21:50,250
+ال polymerization هذا العدد ممكن يكون 300 وحدة
+
+236
+00:21:50,250 --> 00:21:56,200
+ممكن يكون الف ممكن يكون تلت تلافتمام؟ حسب طريقة
+
+237
+00:21:56,200 --> 00:21:59,420
+الارتباط اللى موجودة في هذا العدد وحسب عدد
+
+238
+00:21:59,420 --> 00:22:03,760
+الجزيئات او الوحدات المكونة له الآن وحدة ال stars
+
+239
+00:22:03,760 --> 00:22:08,300
+هي ايش؟ ال maltose هذه الوحدة اللى مكونة من سكرين
+
+240
+00:22:08,300 --> 00:22:13,160
+حسب كمية الأشياء المتصلة بيصير عند نوع ال polymer
+
+241
+00:22:13,160 --> 00:22:16,340
+عشانك انتوا بال plastic بتلاحظوا في عندكوا أنواع
+
+242
+00:22:16,340 --> 00:22:21,460
+كتيرةفي النيلون في عندكم أنواع كتيرة هذا بيصير
+
+243
+00:22:21,460 --> 00:22:25,860
+يدخل فيه جانب الصناعة انه قداش العدد اللي خلناه
+
+244
+00:22:25,860 --> 00:22:31,640
+يتحد تقريبا يعمل polymer هالخليه 300 جزء و وحدة ال
+
+245
+00:22:31,640 --> 00:22:37,640
+polymer 3000 2000 واضح الفكرة؟ الآن نفس الفكرة من
+
+246
+00:22:37,640 --> 00:22:43,350
+الملتوز هلاحظ ان في انهاالـ starch لو حللته
+
+247
+00:22:43,350 --> 00:22:47,990
+بيعطيني ملتوز، الملتوز لو حللته بيعطيني جولوكوز،
+
+248
+00:22:47,990 --> 00:22:52,830
+لكن جولوكوز Alpha
+
+249
+00:22:53,990 --> 00:22:58,410
+وبيتاجولوكوز لكن هذه الوحدة المتكررة وحدة الملتوز
+
+250
+00:22:58,410 --> 00:23:03,350
+اعملوا منها عدد كبير الان لاحظوا ان النشا مكون من
+
+251
+00:23:03,350 --> 00:23:08,230
+شغلتين من اميلوز بنسبة 20% والباقي تقريبا
+
+252
+00:23:08,230 --> 00:23:15,200
+اميلوبكتل ايش بيفرقوا هدولة الشغلتين؟بعدد الجزيئات
+
+253
+00:23:15,200 --> 00:23:19,980
+المكونة له بطريقة الاتحاد يعني ال amylose في
+
+254
+00:23:19,980 --> 00:23:25,840
+جولوكوز units عادة بيكون عددها ما يقارب بين خمسين
+
+255
+00:23:25,840 --> 00:23:30,260
+لتلتمية جولوكوز unit لكن أهم شيء بيميزها أن هي
+
+256
+00:23:30,260 --> 00:23:37,970
+موجودة في إيش؟بسلاسل بدون تفرعات، واضح؟ سلاسل بهذا
+
+257
+00:23:37,970 --> 00:23:42,830
+الشكل بدون ما يصير فيها تفرعات، العدد تبع ال
+
+258
+00:23:42,830 --> 00:23:47,410
+geolocose units بيكون ما بين خمسين إلى تلتمية
+
+259
+00:23:47,410 --> 00:23:52,770
+geolocose unit والاتحاد زي ما انتوا عارفين نمر
+
+260
+00:23:52,770 --> 00:23:58,270
+أربعة من هان وبتحد من واحد مع الجزء التانييعني
+
+261
+00:23:58,270 --> 00:24:02,190
+احنا لما كنا نتكلم عن ال مالتوز، كنا هنا في عنا
+
+262
+00:24:02,190 --> 00:24:07,550
+الاتحاد مع أربعة أو سابين واحد، أوقتش، الآن لما
+
+263
+00:24:07,550 --> 00:24:11,150
+بتعمل polymer، بيجيب التحد منها، يعني لو انتوا
+
+264
+00:24:11,150 --> 00:24:16,630
+تذكرتوا المالتوز، مش كانت هذه تكون فيهقواتش لما
+
+265
+00:24:16,630 --> 00:24:20,930
+نحكي عن الملتوز لوحده الآن بيصير يتحد من هذه
+
+266
+00:24:20,930 --> 00:24:23,690
+القواتش عشان يعمل ال polymer يعني القواتش اللي
+
+267
+00:24:23,690 --> 00:24:28,610
+كانت ماتروكة فاضية بيصير يتحد من خلالها مع موقع
+
+268
+00:24:28,610 --> 00:24:33,130
+أربعة من وحدة ملتوز تانية بطلع عنده جزء كبير
+
+269
+00:24:33,130 --> 00:24:34,210
+بنسميه إيش
+
+270
+00:24:37,020 --> 00:24:43,020
+الاميلوز الاميلوز هذا احد مكونات النشا الان النشا
+
+271
+00:24:43,020 --> 00:24:49,260
+في مكون تاني الاميلوبكتين الاميلوبكتين في ما بين
+
+272
+00:24:49,260 --> 00:24:53,460
+تلتمية الى خمستلاف جولوكوز units يعني الجولوكوز
+
+273
+00:24:53,460 --> 00:24:59,860
+units اللى في عددها اكبر لكن اهم شغل فيه is
+
+274
+00:24:59,860 --> 00:25:06,920
+هايلبراجد واضح يعني الاميلوز سلسلةالـ amylobectin
+
+275
+00:25:06,920 --> 00:25:13,440
+في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300
+
+276
+00:25:13,440 --> 00:25:17,220
+إلى 5000 جولوكوز units is a highly branched
+
+277
+00:25:17,220 --> 00:25:21,660
+molecule او highly branched molecule chains with
+
+278
+00:25:21,660 --> 00:25:24,360
+consecutive one four links شوفنا كيف one four
+
+279
+00:25:24,360 --> 00:25:28,520
+links الارتباط ال average يعني كل مجموعة حوالي
+
+280
+00:25:28,520 --> 00:25:35,070
+خمسة وعشرين لتلاتين وحدةو بعدين بيجي تفرع 25 ل 30
+
+281
+00:25:35,070 --> 00:25:41,110
+و تفرع بيصير الجزء أشماله highly branched واضح
+
+282
+00:25:41,110 --> 00:25:48,470
+فواضح أن جزء ال amylobectin أكبر من ال amylose و
+
+283
+00:25:48,470 --> 00:25:55,150
+بنفس الوقت اللي بيميزه التفرعات واضح فال amylose
+
+284
+00:25:55,150 --> 00:26:02,220
+is a chain moleculeالـ amylobectin هو جزئ عالي جزئ
+
+285
+00:26:02,220 --> 00:26:11,520
+فيه تفرعات كتيرة طبعا هذه كل أشكال تقريبية بتوضح
+
+286
+00:26:11,520 --> 00:26:20,720
+لنا كيف بيتكونوا هذول الجزيئات الأن لو جينا من ال
+
+287
+00:26:20,720 --> 00:26:30,470
+amylose أيضاغير النشق بمكوينه يعني من الملتوز كان
+
+288
+00:26:30,470 --> 00:26:35,130
+في عنده ال starch اللي هو مكوّن من amylose و
+
+289
+00:26:35,130 --> 00:26:40,470
+mylobectin أيضًا من الملتوز في عنده الجليكوجين ال
+
+290
+00:26:40,470 --> 00:26:45,470
+starch ما كان تخزين ال carbohydratesفي النبات
+
+291
+00:26:45,470 --> 00:26:49,410
+الجليكوجين مكان تخزين ال carbohydrates في
+
+292
+00:26:49,410 --> 00:26:55,750
+الحيوانات برضه هو فيه جولوكوز units لكن حوالي مائة
+
+293
+00:26:55,750 --> 00:27:00,590
+ألف جولوكوز unit لاحظوا العدد في الجليكوجين
+
+294
+00:27:00,590 --> 00:27:06,810
+جليكوجين بيزيد بشكل كبير وبرنشد يعني كل ما بين كل
+
+295
+00:27:06,810 --> 00:27:11,010
+تمانية ل 12 جولوكوز unit خلينا هيك نتخيل هتلاحظوا
+
+296
+00:27:11,010 --> 00:27:17,930
+ان في عندكم إيشالجزء هذا الجليكوجين بيكون أيضا
+
+297
+00:27:17,930 --> 00:27:24,090
+highly branched الآن الجليكوجين بيجي من الجلوكوز
+
+298
+00:27:24,090 --> 00:27:30,130
+اللي بيمتص من أمعاء produced from glucose that is
+
+299
+00:27:30,130 --> 00:27:35,930
+absorbed from intestines into the blood الآن إيش
+
+300
+00:27:35,930 --> 00:27:41,060
+وظيفته هذا الجليكوجين؟ يمكن مار عليكمبيولوجيا اللي
+
+301
+00:27:41,060 --> 00:27:45,260
+هو توازن السكر helps maintain the glucose balance
+
+302
+00:27:45,260 --> 00:27:49,660
+واضح يعني إذا في عندي جولوكوز ازيادة بيجي و بتخزن
+
+303
+00:27:49,660 --> 00:27:54,340
+وين في الجليكوجين بدخل ضمن البوليمار الآن إذا
+
+304
+00:27:54,340 --> 00:28:00,770
+الجسم نقص عليه الجولوكوزبصير هذا نفسه يفرز أو يعطي
+
+305
+00:28:00,770 --> 00:28:07,930
+الجسم وحدات جولوكوز واضح الفكرة؟ يعني هو كأنه هاي
+
+306
+00:28:07,930 --> 00:28:12,450
+جزيئات الجولوكوز بتقدروا تتخيلوها بتمطس من المعدة
+
+307
+00:28:12,450 --> 00:28:16,030
+المفروض لازم لحرق الأكل الناس اللي بياكلوا كتير
+
+308
+00:28:16,030 --> 00:28:21,510
+okay بنجمع هذه الجزيئات هيعملنا إيش؟جلايكوجين
+
+309
+00:28:21,510 --> 00:28:25,790
+وخزانة الان بعد هيك صار البني ادم عنده ناقص في
+
+310
+00:28:25,790 --> 00:28:31,010
+السكر جد ما فيه ناقص بيصير يطلع له جولوكوز واضح؟
+
+311
+00:28:31,010 --> 00:28:36,090
+واضحة الفكرة العامة خليني اقول العامة جدا
+
+312
+00:28:36,090 --> 00:28:42,890
+لجلايكوجين الان لو طلعنا على ال cellulose ال
+
+313
+00:28:42,890 --> 00:28:48,830
+cellulose هو ال polymerاللي جاي من الـ cellobiose
+
+314
+00:28:48,830 --> 00:28:55,010
+اللي بيعمل الخشب يعني النشا والجليكوجين جايين من
+
+315
+00:28:55,010 --> 00:29:01,430
+وين؟ من الملتوز من الملتوز لكن ال cellulose جاي من
+
+316
+00:29:01,430 --> 00:29:03,410
+ال cellobiose
+
+317
+00:29:05,410 --> 00:29:11,210
+بيتا وبيتا sugar فالcellulose is an unbranched
+
+318
+00:29:11,210 --> 00:29:16,210
+polymer مستقيم مافيش فيه branches of glucose
+
+319
+00:29:16,210 --> 00:29:20,110
+joined by one four beta glycosidic bonds كل
+
+320
+00:29:20,110 --> 00:29:29,390
+هالكلام شفناه لاحظوا معي كيف فرق في الأساس بسيط
+
+321
+00:29:29,390 --> 00:29:37,500
+جدا انه هذا منسيلو بيوز هذا من مالتوز السيلو بيوز
+
+322
+00:29:37,500 --> 00:29:42,260
+و المالتوز متحدين في beta غلوكوز لكن السكر التاني
+
+323
+00:29:42,260 --> 00:29:46,820
+في كل واحدة واحد منهم واحد alpha واحد beta يعني
+
+324
+00:29:46,820 --> 00:29:51,120
+خلينا نقول هنا في عند بيتا و بيتا نفس الاشي في
+
+325
+00:29:51,120 --> 00:29:57,340
+السكرين الآن في المالتوز هذا alpha في السيلو بيوز
+
+326
+00:29:58,430 --> 00:30:03,590
+هذا beta فهذا alpha beta هذا beta beta الآن هذا
+
+327
+00:30:03,590 --> 00:30:07,690
+بيصير ملتوز و بيعملني نشا و glycogen هذا بيصير
+
+328
+00:30:07,690 --> 00:30:12,970
+cellulose و cellobiose و بيعمله ال cellulose الان
+
+329
+00:30:12,970 --> 00:30:16,990
+البني آدم بيقدر يهضم النشا بيقدر يهضم ال glycogen
+
+330
+00:30:16,990 --> 00:30:22,670
+بيقدرش يهضم ال cellulose ال cellulose واضح فال
+
+331
+00:30:22,670 --> 00:30:26,830
+humans and other animals they digest starch and
+
+332
+00:30:26,830 --> 00:30:32,880
+glycogenبيقدروا يهضموا النشق والجليكوجين، الآن
+
+333
+00:30:32,880 --> 00:30:37,360
+الحيوانات
+
+334
+00:30:37,360 --> 00:30:42,610
+والنمليمكن تقولوا النمل صار أقوى من البني آدم يعني
+
+335
+00:30:42,610 --> 00:30:46,550
+هو النمل بيقدر يخضم الخشب و البني آدم مابيقدرش
+
+336
+00:30:46,550 --> 00:30:52,030
+معنا ذلك النمل أقوى من البني آدم هي المشكلة انه
+
+337
+00:30:52,030 --> 00:30:57,150
+كمان مش النمل اللي بيخضم او مش الحيوانات المجترة
+
+338
+00:30:57,150 --> 00:31:01,570
+اللي بتخضم لأ بكتيريا موجودة جوا أمعاها هذه
+
+339
+00:31:01,570 --> 00:31:05,050
+البكتيريا اللي جوا أمعاها بتفرز اللي هو
+
+340
+00:31:08,560 --> 00:31:14,060
+الانزيمات اللى هى ال beta glycosidase اللى بتساعد
+
+341
+00:31:14,060 --> 00:31:19,960
+على عملية ايش ان تقدر تهضم الخشب وتستفيد منه واضح
+
+342
+00:31:19,960 --> 00:31:27,760
+فماني بكتيريا contain beta glycosidase دايما اذا
+
+343
+00:31:27,760 --> 00:31:33,510
+شفتوا هذه النهاية ايش هذاالنزيم Oxidase و
+
+344
+00:31:33,510 --> 00:31:37,870
+Redactase و glycosidase and they can hydrolyze
+
+345
+00:31:37,870 --> 00:31:42,810
+يعني يفككوا ال cellulose فلو احنا قلنالكم ان ال
+
+346
+00:31:42,810 --> 00:31:46,090
+humans can hydrolyze cellulose
+
+347
+00:31:48,210 --> 00:31:52,250
+واضح؟ لكن في بكتيريا كتير بتقدر تعمل هذا الكلام
+
+348
+00:31:52,250 --> 00:31:55,990
+هذه موجودة في ال termites اللي هو النمل الأبيض و
+
+349
+00:31:55,990 --> 00:31:59,510
+ال ruminants اللي هي الحيوانات المجترة اللي
+
+350
+00:31:59,510 --> 00:32:03,050
+بتلاقوها مستعدة تاكل ال .. إيش؟ زي الجمل و زي ..
+
+351
+00:32:03,050 --> 00:32:08,250
+أه اللي بتاكل الخشب فبكتيريا في معدتها بتقدر تدخل
+
+352
+00:32:08,250 --> 00:32:13,450
+على هذا الخشب و تحلله لوحدات السكر بحيث أنه النمل
+
+353
+00:32:13,450 --> 00:32:18,430
+الأبيض أو الحيوانات هذه المجترة تقدر تستفيد منهأو
+
+354
+00:32:18,430 --> 00:32:22,310
+من السكر اللي موجود فيه لكن البني آدم مابيقدرش
+
+355
+00:32:22,310 --> 00:32:26,730
+يخدمه أخر
+
+356
+00:32:26,730 --> 00:32:33,090
+شغلة أخر شغلة بنحكيها بالنسبة لهذا الجزء أنه في
+
+357
+00:32:33,090 --> 00:32:37,870
+عندى بعض ال sugars يمكن أن ينزع منها أكسجين هذه
+
+358
+00:32:37,870 --> 00:32:42,850
+بتفيدنا لما بدنا ندرس ال nuclear acid اللي هي
+
+359
+00:32:42,850 --> 00:32:49,090
+الأحماض النووية ومنهابصير اسمها deoxy sugars يعني
+
+360
+00:32:49,090 --> 00:32:53,470
+لاحظوا هذا ال sugar لما يكون فيه ال oxygen و سكر
+
+361
+00:32:53,470 --> 00:32:58,610
+من خمس كربونات tripose تمام لما نشيل منه oxygen
+
+362
+00:32:58,610 --> 00:33:02,870
+منها يعني في الأصل كان في عنده OH لو شيلنا منه
+
+363
+00:33:02,870 --> 00:33:09,490
+oxygen ايش بيصير اسمه؟ deoxy، deoxy يعني منزوعأه
+
+364
+00:33:09,490 --> 00:33:14,570
+لحظة ميزه .. ميزه رجاء في الكلمات، عشانك احنا
+
+365
+00:33:14,570 --> 00:33:22,080
+بنقول اتعبوا شوية، يعني لو اتينا قولنالكم ضايقزيدا
+
+366
+00:33:22,080 --> 00:33:27,800
+يعني اتنين اه لكن دي منزوعة زي ما كنا نقول
+
+367
+00:33:27,800 --> 00:33:31,760
+hydrogenation, dehydrogenation, hydration,
+
+368
+00:33:32,600 --> 00:33:38,260
+dehydrogenation, halogenation, dehydrogenation فال
+
+369
+00:33:38,260 --> 00:33:43,820
+دي بتاعنا اللي هو العكس فهذا ال beta دي دي
+
+370
+00:33:43,820 --> 00:33:48,860
+oxyribofuranose طب علشه فيورانوز لأنهمن حلقاء
+
+371
+00:33:48,860 --> 00:33:53,520
+خماسية هو ال sugar تبع ال DNA هو عبارة عن Ribose
+
+372
+00:33:53,520 --> 00:33:58,720
+نزعت منه ال Oxygen و لو كان ال Ribose اللي في ال
+
+373
+00:33:58,720 --> 00:34:05,400
+Oxygen بيعملنا ال RNA Ribonucleic Acid لما يكون ال
+
+374
+00:34:05,400 --> 00:34:09,800
+DNA Deoxyribonucleic Acid واضح؟
+
+375
+00:34:12,560 --> 00:34:19,700
+الكلام عام عن اللي هي ال dice carats و عن ال
+
+376
+00:34:19,700 --> 00:34:26,210
+polymers اللي بتكونوا منهم خلينا يعني نبدأنعطي
+
+377
+00:34:26,210 --> 00:34:31,310
+فكرة عامة ليش أنا محتاجها الآن مقارنة مع
+
+378
+00:34:31,310 --> 00:34:37,050
+البروتينات اللي بدنا ناخدها في الفصل الأخير ان شاء
+
+379
+00:34:37,050 --> 00:34:41,910
+الله اللي هو ال amino acids و ال peptides و ال
+
+380
+00:34:41,910 --> 00:34:48,210
+proteins زي ما لاحظته يمكن أهم شغلة في ال
+
+381
+00:34:48,210 --> 00:34:52,290
+polysaccharides أهم شغلة في ال polysaccharides أن
+
+382
+00:34:52,290 --> 00:34:57,650
+هم polymersماذا يعني polymers؟ يعني لما أقول
+
+383
+00:34:57,650 --> 00:35:04,150
+النشا، إيش الوحدة تبعته؟ هتقولولي مالتوز
+
+384
+00:35:04,150 --> 00:35:10,390
+البيسكريدي المالتوز، تمام؟ لو قولت مثلا السيللوز،
+
+385
+00:35:10,390 --> 00:35:15,870
+بوليمر كبير، إيش الوحدة تبعته؟ السيلوبيوز، ولذلك
+
+386
+00:35:15,870 --> 00:35:23,490
+ال polysaccharidesيمكن التعامل معها يكون أسهل كتير
+
+387
+00:35:23,490 --> 00:35:28,790
+من التعامل مع البروتينات ليش؟ لأن ال
+
+388
+00:35:28,790 --> 00:35:32,930
+polysaccharides عندي وحدة و بتتكرر يعني كأن
+
+389
+00:35:32,930 --> 00:35:37,110
+الإنسان بيقدر يقول عنهم ان they are real polymers
+
+390
+00:35:37,110 --> 00:35:43,710
+واضح؟ ال polymers مكون من إيش؟مونومارز تتحد تصير
+
+391
+00:35:43,710 --> 00:35:47,910
+دايمارز، ترايمارز، تترامارز، في الآخر إيش؟
+
+392
+00:35:47,910 --> 00:35:55,190
+بوليمارز، فالبوليمار من ناحية المبدأ وحدة متكررة،
+
+393
+00:35:55,190 --> 00:36:00,390
+البوليمار وحدة إيش مالها؟ متكررة، فلمّا أجي أقول
+
+394
+00:36:00,390 --> 00:36:05,990
+starch polymer ما وحدته المتكررة؟ الملتوز، انتهى
+
+395
+00:36:06,580 --> 00:36:13,060
+واضح؟ الآن لما بدي اجي .. لما بدي اجي اتكلم عن ال
+
+396
+00:36:13,060 --> 00:36:18,900
+proteins هلاحظ ان في عندي اختلاف أساسي ال proteins
+
+397
+00:36:18,900 --> 00:36:26,580
+عبارة عن amino acids وال amino acids مختلفين
+
+398
+00:36:27,350 --> 00:36:33,110
+واضح ال amino acids مختلفين ولذلك انا لما بدي اجي
+
+399
+00:36:33,110 --> 00:36:38,050
+اعمل مثلا نشا بقدر اقول بقدر اقول في حالة النشا او
+
+400
+00:36:38,050 --> 00:36:44,630
+ال amylose مالتوز تلاتين
+
+401
+00:36:44,630 --> 00:36:50,320
+وحدة مثلا او تلاتميت وحدةملتوز 300 وحدة واضح؟
+
+402
+00:36:50,320 --> 00:36:56,520
+الملتوز مكرر كده؟ 300 مرة هاي صرت عامل مثلا اميلوز
+
+403
+00:36:56,520 --> 00:37:01,240
+لكن لو جيت بدي اعمل البروتين او الأصغر من البروتين
+
+404
+00:37:01,240 --> 00:37:04,720
+ال بيبتايد اللي هيمر علينا بعد شوية مابقدرش اعمل
+
+405
+00:37:04,720 --> 00:37:09,460
+مثل هذه المعادلة واضح؟ يعني هذه المعادلة ان اقول
+
+406
+00:37:09,460 --> 00:37:15,860
+انه is a real polymerاللي هي ال polysaccharides
+
+407
+00:37:15,860 --> 00:37:21,480
+مالتوز منه تلاتمية وحدة او منه مائة الف وحدة في ال
+
+408
+00:37:21,480 --> 00:37:26,640
+glycogen على سبيل المثال او ما إلى ذلك هي وحدة و
+
+409
+00:37:26,640 --> 00:37:32,680
+متكررة لما بدي اجي احكي عن ال protein
+
+410
+00:37:36,730 --> 00:37:43,590
+هلاحظ ان البروتين عبارة عن amino acids عدد كبير من
+
+411
+00:37:43,590 --> 00:37:49,190
+ال amino acids الان كل amino acid من ناحية المبدأ
+
+412
+00:37:49,190 --> 00:37:56,730
+بختلف عن التاني يعني خليني اتخيل ان هذا حقيقة بمثل
+
+413
+00:37:56,730 --> 00:38:03,490
+البروتين الان هذا بقدر احط عليه كذا to the N لأ طب
+
+414
+00:38:03,490 --> 00:38:10,740
+ايش المطلوب اعمله؟أعمله إيش التسلسل تبعه، يعني لو
+
+415
+00:38:10,740 --> 00:38:14,600
+اتخيلت أنا أن هذا بروتين صغير، يعني بيبتايد، بقول
+
+416
+00:38:14,600 --> 00:38:19,700
+لحظة معايا إيش التسلسل تبعه من amino acids، أسود،
+
+417
+00:38:19,700 --> 00:38:27,230
+أخضر، أحمر، أسود، أزرقتمام؟ الآن كل واحد شكل من
+
+418
+00:38:27,230 --> 00:38:29,870
+هدول، يعني هذا في الـ amino acids ممكن يكون
+
+419
+00:38:29,870 --> 00:38:36,990
+إجليسين، ألانين، سيستين، تريبتوفان، كذا، فما بقدرش
+
+420
+00:38:36,990 --> 00:38:38,830
+أصيغه بصيغة
+
+421
+00:38:41,480 --> 00:38:45,080
+amino acid و بعدين اقول عنه to the end فالان
+
+422
+00:38:45,080 --> 00:38:51,640
+تخيلوا لو كان في عندي مثلا protein من 300 amino
+
+423
+00:38:51,640 --> 00:38:58,780
+acid عشان اعرفه جيدا ايش المطلوب مني اعمل احدد ال
+
+424
+00:38:58,780 --> 00:39:04,200
+300 amino acid مرتبين هذا بيسموه ايش؟ sequence
+
+425
+00:39:04,200 --> 00:39:11,930
+يعني كيف هدول مرتبينأعمل التسلسل تبعه، الآن فكرة
+
+426
+00:39:11,930 --> 00:39:16,490
+ال sequence أو التسلسل غير موجودة في ال
+
+427
+00:39:16,490 --> 00:39:21,170
+polysaccharides، ال polysaccharides نفس الشغلة to
+
+428
+00:39:21,170 --> 00:39:28,380
+the Nمالتوز to the M خلصت واضح بينما في ال
+
+429
+00:39:28,380 --> 00:39:33,100
+proteins هتواجهنا صعوبة ان ال proteins وحدتهم
+
+430
+00:39:33,100 --> 00:39:37,660
+الأساسية amino acids ال amino acids عادة اللي
+
+431
+00:39:37,660 --> 00:39:41,720
+موجودين في ال protein عشرين amino acid الان لما
+
+432
+00:39:41,720 --> 00:39:50,400
+يكون عندى protein من تلتمية amino acid كويس
+
+433
+00:39:50,400 --> 00:39:56,960
+في أشياء مكررة لكنلابد من ال sequence هم اكيد هم
+
+434
+00:39:56,960 --> 00:40:00,580
+اكيد عشرين amino acid تقريبا اللي موجودين في ال
+
+435
+00:40:00,580 --> 00:40:07,180
+proteins لكن هدول العشرين لما بدي اخد منهم protein
+
+436
+00:40:07,180 --> 00:40:15,700
+من تلاتمية amino acid كيف هيكونوا؟ هيكونوا
+
+437
+00:40:15,700 --> 00:40:22,050
+مختلفين مافيش ان احك مثلا glycine to the Nعشان
+
+438
+00:40:22,050 --> 00:40:28,290
+اميز اي protein عن التاني لازم اعد ال 300 ولذلك ال
+
+439
+00:40:28,290 --> 00:40:32,950
+protein لو انا بدى اتكلم عنه انه هل هو real
+
+440
+00:40:32,950 --> 00:40:40,870
+polymer يعني حقيقي بمعنى الكلمة الجواب لأ ال real
+
+441
+00:40:40,870 --> 00:40:48,390
+polymer حقيقة ايش هو؟ monomerto the end زي ما
+
+442
+00:40:48,390 --> 00:40:52,770
+شوفنا ال polyethylene و ال PVC و حتى كمان ال
+
+443
+00:40:52,770 --> 00:40:57,750
+polysaccharides مونومر مكرر لكن هنا لما بدي أجي
+
+444
+00:40:57,750 --> 00:41:01,570
+أحكي عن ال protein هصير أجيب ال amino acids أقول
+
+445
+00:41:01,570 --> 00:41:07,910
+glycine, alanine, tryptophan, cysteine كذا كذا
+
+446
+00:41:07,910 --> 00:41:14,270
+هتلاحظوا أنه مطلوب منناانحدد الترتيب تبع ال amino
+
+447
+00:41:14,270 --> 00:41:17,690
+acids ولذلك ال proteins لو الإنسان بده يستعمل
+
+448
+00:41:17,690 --> 00:41:23,010
+الكلام بدقة أكثر they are macro molecules جزيئات
+
+449
+00:41:23,010 --> 00:41:30,490
+كبيرة macro molecules جزيئات كبيرة أكثر منهم إيش
+
+450
+00:41:30,490 --> 00:41:39,610
+polymers they are macro molecules أكثر منهمبولمار
+
+451
+00:41:39,610 --> 00:41:46,310
+طبعا فيهم نوعا ما شيء مشترك بيخلي بعض الناس يقولوا
+
+452
+00:41:46,310 --> 00:41:54,670
+ممكن تجاوزا نعتبر ال protein بولمار ليش؟ لأنه لو
+
+453
+00:41:54,670 --> 00:42:00,010
+أنا اتطلعت على الهيكل تبعه اللي بتكرر هلاحظ ان هو
+
+454
+00:42:00,010 --> 00:42:05,960
+عبارة عن NCEالان هذه الوحدة بتتكرر في البروتين
+
+455
+00:42:05,960 --> 00:42:12,760
+بعدها N C C double bond O بعدها N C C double bond
+
+456
+00:42:12,760 --> 00:42:19,220
+O هتقولولي مش ناقص غير ايش تكتب هذولة to the N طب
+
+457
+00:42:19,220 --> 00:42:25,870
+ليش مش قادر اكتبهم؟لأن كل amino acid فيها R group
+
+458
+00:42:25,870 --> 00:42:33,210
+مختلفة يعني هذه مرة H هذه مرة CH3 هذه مرة CH2SH
+
+459
+00:42:33,210 --> 00:42:40,430
+فلو بتطلع على الهيكل الأساسي للذرات لبروتين NCC
+
+460
+00:42:40,430 --> 00:42:45,870
+double bond O هو مكرر لكن لو طلعت على هذه المجموعة
+
+461
+00:42:46,670 --> 00:42:51,530
+مش مكررة بناء على ذلك لو هذا مثلا كان بيبتايد هذا
+
+462
+00:42:51,530 --> 00:42:55,810
+بيبتايد مكون من كام amino acid من تلاتة هتعلم أن
+
+463
+00:42:55,810 --> 00:43:00,570
+هذا اسمه إجليسين هذا اسمه ألانين هذا اسمه سيستين
+
+464
+00:43:00,570 --> 00:43:05,450
+حصير أقول هذاEglicin, Alanine, Cysteine هيكون بفرق
+
+465
+00:43:05,450 --> 00:43:08,390
+عن Alanine, Eglicin, Cysteine من نفس التلاتة
+
+466
+00:43:08,390 --> 00:43:14,810
+فانفعلكوا لما نصيح نحكي عن تلاتمية فالبروتين بوجهة
+
+467
+00:43:14,810 --> 00:43:19,870
+النظر اللي بده يتطلع الهيكل الأساسي هو كأنه بوليمر
+
+468
+00:43:19,870 --> 00:43:25,170
+امكرر في N, C, C double bond O N, C, C double bond
+
+469
+00:43:25,170 --> 00:43:28,950
+O لكن لما نيجي نلاحظ أن هذه المجموعة اللي هنا
+
+470
+00:43:28,950 --> 00:43:36,740
+اختلفتبطل polymer ولذلك ال polymer مابنعدش ال 300
+
+471
+00:43:36,740 --> 00:43:40,680
+وحدة ولا ال 5000 وحدة تبعته بس ال protein بدي
+
+472
+00:43:40,680 --> 00:43:45,860
+أجهزة و بدي علم يوم أقول هذا protein كذا يذكر لل
+
+473
+00:43:45,860 --> 00:43:54,170
+5000 وحدة مرتبين و نفس الاشي هيتكرر معاكم مهمفي ال
+
+474
+00:43:54,170 --> 00:43:58,670
+nucleic acids عشان هيك في الشفرة الوراثية وغيرها
+
+475
+00:43:58,670 --> 00:44:02,570
+وغيراتها هتلاحظوا ان البني ادم بيختلف عن التاني و
+
+476
+00:44:02,570 --> 00:44:07,270
+الشغل بتختلف عن التاني انه بدي اذكر الأشياء مرتبة
+
+477
+00:44:08,550 --> 00:44:18,550
+كذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+478
+00:44:18,550 --> 00:44:19,230
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+479
+00:44:19,230 --> 00:44:19,250
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+480
+00:44:19,250 --> 00:44:19,450
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+481
+00:44:19,450 --> 00:44:22,470
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+482
+00:44:22,470 --> 00:44:25,070
+وكذا
+
+483
+00:44:25,690 --> 00:44:30,730
+جزيئات كبيرة اكثر من ان نسميها Polymers و نقدر
+
+484
+00:44:30,730 --> 00:44:35,170
+نكتب شغلته دي انا الان حيصير درسنا القادم سهل اللي
+
+485
+00:44:35,170 --> 00:44:39,730
+بده يدرس ال proteins ايش أساسهم اذا اول شئ بدنا
+
+486
+00:44:39,730 --> 00:44:45,310
+نتعلم على ال amino acids بعدين ال amino acids بتحد
+
+487
+00:44:45,310 --> 00:44:48,890
+و بيعملوا ال protein نتعلم كيف نوجد ال sequence و
+
+488
+00:44:48,890 --> 00:44:53,390
+كيف نحضر ال protein لو بدنايالكن حيكون ان شاء الله
+
+489
+00:44:53,390 --> 00:44:58,410
+درسنا القادم على الوحدة المكونة للبروتين اللي هي
+
+490
+00:44:58,410 --> 00:45:00,370
+عبارة عن ايش؟ الامام
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM.srt
new file mode 100644
index 0000000000000000000000000000000000000000..ceaba9d7ce0707c2cd6b1e802d60cd961ca00eee
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM.srt
@@ -0,0 +1,1707 @@
+
+1
+00:00:20,910 --> 00:00:24,950
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:24,950 --> 00:00:30,470
+تسمية ال aromatic compounds وركزنا على نقطة لما
+
+3
+00:00:30,470 --> 00:00:35,010
+بيكون موجود عندنا اكثر من substituent نتبع المركب
+
+4
+00:00:35,010 --> 00:00:42,550
+لأي مجموعة و القمر زي ما بتلاحظه بسيط من خلال انه
+
+5
+00:00:42,550 --> 00:00:45,890
+اعطيناكم ترتيب معين من خلال انه اعطيناكم ترتيب
+
+6
+00:00:45,890 --> 00:00:53,020
+معين يمكن في نقطة بدى انوحلها حتى إذا واجهتكم ما
+
+7
+00:00:53,020 --> 00:00:59,260
+تتخربطوش فيها من خلال هذه المركبات لاحظوا مثلا هذا
+
+8
+00:00:59,260 --> 00:01:07,330
+المركب أعلى مجموعة في ال OH ولذلك سمناهفينول فينول
+
+9
+00:01:07,330 --> 00:01:15,130
+سمناها فينول واضح فبينت ال OH في نهاية المقطع بشكل
+
+10
+00:01:15,130 --> 00:01:21,290
+all الان السؤال لما ال OH ما تكونش هي المجموعة
+
+11
+00:01:21,290 --> 00:01:26,900
+اللي بدها تكون عائلة المركب تيجي عائلة أعلى منها هي
+
+12
+00:01:26,900 --> 00:01:32,300
+إيش بده يصير فيها؟ بده ترجع لاسمها الأصل لما اتبعت
+
+13
+00:01:32,300 --> 00:01:37,740
+العائلة ولذلك في هذا المركب لما وجدت ال OH مع هذه
+
+14
+00:01:37,740 --> 00:01:42,820
+المجموعة الآن ال aldehyde أعلى من ال OH فالمركب
+
+15
+00:01:42,820 --> 00:01:49,280
+ساربينز الديهايد شو سميت ال OH؟ Hydroxy واضح؟ الآن
+
+16
+00:01:49,280 --> 00:01:54,820
+الكلام نفسه بتكرر لو أنا أعطيتكم مركب زي هذا مثلا
+
+17
+00:01:58,460 --> 00:02:04,760
+C double bond O CH3 و حطيت هنا CH3 الآن هنا في
+
+18
+00:02:04,760 --> 00:02:09,620
+عندك كيتون و الكلجروب العائلة الكيتون و هذا
+
+19
+00:02:09,620 --> 00:02:17,720
+الكيتون معروف اسمه أسيتوفينونواضح؟ أسيتوفينون فلما
+
+20
+00:02:17,720 --> 00:02:24,320
+أجي بدي أسم المركب بقول 4-methylacetophenone طيب
+
+21
+00:02:24,320 --> 00:02:30,580
+السؤال لو هذه المجموعة ماكنتش عائلة لو إجت مجموعة
+
+22
+00:02:30,580 --> 00:02:34,440
+أعلى منها و المجموعات الأعلى من الكيتون الالديهيد
+
+23
+00:02:34,440 --> 00:02:39,380
+أو الاسد أو ال Easter شو بيصير اسم هذه المجموعة؟
+
+24
+00:02:40,130 --> 00:02:45,510
+واضح؟ يعني لو حطيت بمثل هذا المثال الآن هاي
+
+25
+00:02:45,510 --> 00:02:49,830
+الديهايد وهاي كيتون ال الديهايد أعلى من ال كيتون
+
+26
+00:02:49,830 --> 00:02:56,550
+إذا للجزء اللي عندي .. الجزء اللي عندي شو هو؟ بنز
+
+27
+00:02:56,550 --> 00:03:02,390
+الديهايد طب هذه المجموعة CH3C double bond O إيش
+
+28
+00:03:02,390 --> 00:03:07,800
+اسمها؟ الان بديكوا تعرفوا إن اسمها Acetyl بنعرف إن
+
+29
+00:03:07,800 --> 00:03:13,000
+اسمها Acetyl الان هذه المجموعة جاية من وين أساساً
+
+30
+00:03:13,000 --> 00:03:18,360
+جاية من حمب ال Acetic Acid اللي هو حمب الخلق لو
+
+31
+00:03:18,360 --> 00:03:26,040
+احنا اتطلعنا على ال Acetic Acid CH3COOH
+
+32
+00:03:26,040 --> 00:03:33,870
+تمام الان مجموعة ال Acetyl هنا هي هذه المجموعة هذه
+
+33
+00:03:33,870 --> 00:03:37,050
+الاستيل وبنرمزلها عادة بالرمز
+
+34
+00:03:40,120 --> 00:03:45,720
+AC و لذلك لو كان عندكم مثلا مركب مكتوب عليه AC
+
+35
+00:03:45,720 --> 00:03:50,620
+بتكون تعرف ان هذه مجموعة ايش ال Acetal اللي هي
+
+36
+00:03:50,620 --> 00:03:57,860
+CH3C double bond O لوحدها الان مر علي مجموعة تانية
+
+37
+00:03:57,860 --> 00:04:04,800
+بتشبهها لو انا أخدت CH3C double bond O مع ال
+
+38
+00:04:04,800 --> 00:04:10,410
+Oxygenعرفت الآن الـ Acetyl فقط هذا الجزء طب يا
+
+39
+00:04:10,410 --> 00:04:17,150
+تورا لو أخدت هذه كمجموعة CH3C O O و عادة هذه تكون
+
+40
+00:04:17,150 --> 00:04:22,830
+minus ممكن يكون معها NA plus نتذكر هذه إيش اسمها
+
+41
+00:04:22,830 --> 00:04:30,590
+كلها كمجموعة هذه بتصير Acetateأيون سالب والأيونات
+
+42
+00:04:30,590 --> 00:04:35,870
+السالبة عادة بتنتهي بـ 8 زي ما بيقول سولفات نيترات
+
+43
+00:04:35,870 --> 00:04:40,810
+كاربونات أسيتات هذه مجموعة الخلات بنسميها بالعربي
+
+44
+00:04:40,810 --> 00:04:44,470
+ولذلك هذا بيصير Sodium Acetate بالإنجليزي أو
+
+45
+00:04:44,470 --> 00:04:51,110
+بالعربي خلات ال Sodium فهذه المجموعة بيكون أسيتات
+
+46
+00:04:51,110 --> 00:04:55,250
+الآن لو بدي أكتب مجموعة الأسيتات مختصرة كيف
+
+47
+00:04:55,250 --> 00:05:04,240
+بكتبها؟ACO- لأن هذه الواحدة AC A capital small c
+
+48
+00:05:04,240 --> 00:05:09,520
+الآن مع ال oxygen بتصير ACO- إذا صار عندي مجموعة
+
+49
+00:05:09,520 --> 00:05:17,620
+AC و مجموعة ACO واضح؟ الآن السؤال لو أجهكم مثلا
+
+50
+00:05:17,620 --> 00:05:20,260
+بتفاعل مكتوب عندكم ACOH
+
+51
+00:05:22,240 --> 00:05:29,940
+اش بده يكون ال acetic acid هاي AC و هاي O و هاي H
+
+52
+00:05:29,940 --> 00:05:36,180
+فال acetic acid ايش بنختصره ACOH هذا ال acetic
+
+53
+00:05:36,180 --> 00:05:42,810
+acidهذه الرموز عادة تتكرر معنا الاسيتك أسد الاسيتك
+
+54
+00:05:42,810 --> 00:05:45,430
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+55
+00:05:45,430 --> 00:05:47,770
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+56
+00:05:47,770 --> 00:05:48,710
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+57
+00:05:48,710 --> 00:05:49,470
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+58
+00:05:49,470 --> 00:05:52,670
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+59
+00:05:52,670 --> 00:05:54,150
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+60
+00:05:54,150 --> 00:06:00,430
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+61
+00:06:00,430 --> 00:06:04,530
+أسإذا رجعت لأصلها في المركب اللي قبل شوية كتبناها
+
+62
+00:06:04,530 --> 00:06:09,070
+كان acetophenon كانت هي العائلة لما صارت فرد وفي
+
+63
+00:06:09,070 --> 00:06:14,390
+إيش أعلى منها بدرجة على إيش لأصلها أصلها اللي هو
+
+64
+00:06:14,390 --> 00:06:21,810
+ال acetyl كذلك الحال في هذا المركب acid و ketone
+
+65
+00:06:23,090 --> 00:06:28,410
+طبعا المركب بده يتبع ايش ال acid بنزويك acid هذي
+
+66
+00:06:28,410 --> 00:06:31,670
+ايش بتكون ال acid ال acid ال acid ال acid ال acid
+
+67
+00:06:31,670 --> 00:06:40,410
+acid
+
+68
+00:06:40,410 --> 00:06:44,930
+the acid the acid the acid the acid the acid the
+
+69
+00:06:44,930 --> 00:06:46,150
+acid the acid the acid the acid the acid the acid
+
+70
+00:06:46,150 --> 00:06:50,190
+the acid the acid the acid the acid the acid the
+
+71
+00:06:50,190 --> 00:06:55,560
+acid the acid theهذا المثال مش موجود عندكم acid
+
+72
+00:06:55,560 --> 00:07:01,700
+and aldehyde من الأعلى ال acid ممتاز طيب هذا
+
+73
+00:07:01,700 --> 00:07:11,440
+بنزويك acid بنزويك acid الآن هذه المجموعة شو اسمها
+
+74
+00:07:11,440 --> 00:07:14,980
+formal
+
+75
+00:07:14,980 --> 00:07:21,020
+واضح وبالتالي هذا بيصير ايش for formal
+
+76
+00:07:22,970 --> 00:07:27,890
+For formal هذه المجموعة الـ C double bond O المتصل
+
+77
+00:07:27,890 --> 00:07:31,570
+بـ H formal و الـ C double bond O لو اتصلت ب مثل
+
+78
+00:07:31,570 --> 00:07:38,380
+بتصير كيتون أسيتل أخدناهاواضحة الفكرة؟ فكل شيء إذا
+
+79
+00:07:38,380 --> 00:07:42,680
+ماكانش هو العائلة بده يرجع لإيش؟ لاسمه تماما
+
+80
+00:07:42,680 --> 00:07:46,560
+الميثل لما بتكون عائلة بنكون نقول طلوين لما تبطل
+
+81
+00:07:46,560 --> 00:07:51,700
+عائلة بترجع مثل ال OH لما تكون عائلة فينول بتبطل
+
+82
+00:07:51,700 --> 00:07:56,500
+عائلة بترجع هيدروكسي الكيتون مثلا هذه المجموعة لما
+
+83
+00:07:56,500 --> 00:08:02,720
+تكون عائلة أسيتوفينون بطلت عائلة أسيتلال Formyl
+
+84
+00:08:02,720 --> 00:08:12,560
+Benzaldehyde بطلت عائلة ترجع لإسم Formyl طبعا ربما
+
+85
+00:08:12,560 --> 00:08:18,140
+البعض منكم يعرف أن Formyl أيضا جاية من هذه
+
+86
+00:08:18,140 --> 00:08:23,680
+المجموعة اللي هي C double bond OH OH هذا اللي اسمه
+
+87
+00:08:23,680 --> 00:08:28,760
+Formic Acid أبسط الأحماض العضويةأبسط الأحماض
+
+88
+00:08:28,760 --> 00:08:33,140
+العضوية اللي فيه H ال Acetic Acid فيه مثل تاني حمض
+
+89
+00:08:33,140 --> 00:08:37,500
+عضوي لكن أبسط واحد في الأحماض العضوية اللي اسمه
+
+90
+00:08:37,500 --> 00:08:44,280
+ايش Formic Acid الأهم منه هذه المجموعة لوحدها
+
+91
+00:08:44,280 --> 00:08:49,440
+كمجموعة عضوية ايش اسمها Formic اسمها Formic
+
+92
+00:08:49,440 --> 00:08:56,170
+بالعربي هذا Formic Acid شو بيسموه حمض النمليكلأ هو
+
+93
+00:08:56,170 --> 00:09:00,430
+ال formalin هو ال formaldehyde مدوب في مياه بمعنى
+
+94
+00:09:00,430 --> 00:09:05,050
+بعدين لكن هذا بنسميه بالعربي حمب النمليك لأن هذا
+
+95
+00:09:05,050 --> 00:09:09,720
+الحمب اللي النملة لما بتجرسبتحطه .. بتفرزه في
+
+96
+00:09:09,720 --> 00:09:13,760
+الإيد و بيسبب القلم الشديد اللي بتعرفه و حتى
+
+97
+00:09:13,760 --> 00:09:17,000
+باللغة الألمانية زي ما احنا بنسمي .. احنا بنسمي
+
+98
+00:09:17,000 --> 00:09:20,720
+النمليك و ما عنده من نمل Amazin فبسموه Amazin
+
+99
+00:09:20,720 --> 00:09:26,860
+Zörey حمض النمل Amazin Zörey واضح؟ فهذه ال form
+
+100
+00:09:26,860 --> 00:09:32,080
+اللي جاية من وين؟ من ال Formic أصل هذه النقطة حسيت
+
+101
+00:09:32,080 --> 00:09:35,820
+أنه ربما بيكون مفيد ان انا أكد عليها في موضوع
+
+102
+00:09:35,820 --> 00:09:40,730
+التسميةالان بالنسبة للتفاعلات لل aromatic
+
+103
+00:09:40,730 --> 00:09:45,910
+compounds اتفقنا احنا على شغلة ان ال aromatic
+
+104
+00:09:45,910 --> 00:09:50,130
+compounds او حلقة البنزين كثافة إلكترونية ولذلك
+
+105
+00:09:50,130 --> 00:09:54,290
+الذي يجب ان يهاجم عليها موجب هذه النقطة الأولى
+
+106
+00:09:54,290 --> 00:10:00,140
+النقطة الثانية انها لا تتفاعل بالاضافةو لذلك
+
+107
+00:10:00,140 --> 00:10:03,340
+لاحظوا ال double bonds هنا في كل التفاعلات حاطينهم
+
+108
+00:10:03,340 --> 00:10:07,160
+على شكل حلقة لأنه تعبير عن ال resonance و ما
+
+109
+00:10:07,160 --> 00:10:11,200
+بنغيرش فيهم طب ها إيش اللي بيصير في تفاعلات ال
+
+110
+00:10:11,200 --> 00:10:16,720
+aromatic compounds؟ تفاعل إبدال ماذا نفعل في هذا
+
+111
+00:10:16,720 --> 00:10:22,780
+تفاعل الإبدال؟ بنيجي بنشيل موجب و بنحط بدله موجب
+
+112
+00:10:22,780 --> 00:10:28,910
+تانيواضح؟ دائما الإبدال اللي بده يبدل شغلة بشغلة
+
+113
+00:10:28,910 --> 00:10:36,080
+بيبدل شغلةمن نفس الشغلة يعني لو بدأ أبدل موجب إذا
+
+114
+00:10:36,080 --> 00:10:40,500
+بدأ أشيل منه المركب موجب شو بدأ أحط بداله موجب
+
+115
+00:10:40,500 --> 00:10:45,500
+الآن هنا بسمي الإبدال Electrophilic Substitution
+
+116
+00:10:45,500 --> 00:10:49,960
+مرت معنى كلمة Electrophilic موجب مظبوط ولا لأ
+
+117
+00:10:49,960 --> 00:10:55,150
+ولذلك هتلاحظوا هنا إيش العنوانElectrophilic
+
+118
+00:10:55,150 --> 00:10:58,330
+Substitution معنى Electrophilic Substitution بدي
+
+119
+00:10:58,330 --> 00:11:05,410
+اشيل اشي موجد و احط مكانه اشي موجد مظبوط ولا لأ و
+
+120
+00:11:05,410 --> 00:11:11,890
+اللي بده يبدل سالبإيش بده يحط مكانه؟ سالب و لذلك
+
+121
+00:11:11,890 --> 00:11:17,070
+هيجعلنا في مكان تاني بل أمر علينا في أمثلة سابقة
+
+122
+00:11:17,070 --> 00:11:22,270
+لو كنتوا منتبهين in eucleophilic substitution إن
+
+123
+00:11:22,270 --> 00:11:26,990
+أشيل سالب أحط مكانه سالب أشيل موجب أحط مكانه موجب
+
+124
+00:11:26,990 --> 00:11:31,610
+لما المرة الماضية على سبيل المثال كنا الفاعل
+
+125
+00:11:32,860 --> 00:11:37,700
+الاسيتالايد انايون مع مركب فيه كلور او يود متذكرين
+
+126
+00:11:37,700 --> 00:11:41,360
+شيلنا ال يود السالب مع الكتروناتو و حطينا
+
+127
+00:11:41,360 --> 00:11:45,780
+الاسيتلايد اخر تفاعل في الاسيتليانز قولنا بنشيل
+
+128
+00:11:45,780 --> 00:11:50,340
+سالب و نحط سالب الان لو اجيت قولتلكم هذا التفاعل
+
+129
+00:11:50,340 --> 00:11:54,830
+شو بدي اسميهبدي أسميه الـ Eucleophilic
+
+130
+00:11:54,830 --> 00:12:00,390
+Substitution لأن أنا بدأت بالـ Eucleophile هنا وين
+
+131
+00:12:00,390 --> 00:12:06,690
+الموجب اللي بدي أشيله؟ الاتش هذه لوحدها بدون زوج
+
+132
+00:12:06,690 --> 00:12:12,530
+الإلكترونة، تنتبهوا معي وجدت بدي أجيب بدلها موجب،
+
+133
+00:12:12,530 --> 00:12:18,700
+نفترض X موجبة، CL موجبة، شيلت الاتش الموجبة؟حطيت
+
+134
+00:12:18,700 --> 00:12:22,720
+ال X الموجبة هذه محصلة التفاعل إذا التفاعل إيش
+
+135
+00:12:22,720 --> 00:12:26,520
+بيصير اسمه Electrophilic Aromatic Substitution
+
+136
+00:12:26,520 --> 00:12:29,680
+ولذلك لو إحنا بنيجي بنسألكم مثلا aromatic
+
+137
+00:12:29,680 --> 00:12:35,450
+compounds undergo addition reactions غلطAromatic
+
+138
+00:12:35,450 --> 00:12:38,990
+compounds undergo a nucleophilic aromatic
+
+139
+00:12:38,990 --> 00:12:42,530
+substitution برضه غلط لليوكليوفال بيجربش عليها
+
+140
+00:12:42,530 --> 00:12:48,630
+لأنها سالبة كثافة إلكترونية هنا فمين اللي بيقدر
+
+141
+00:12:48,630 --> 00:12:54,310
+يجرب عليها الموجب فلمّا ينسقل الطالب سؤال عام حتى
+
+142
+00:12:54,310 --> 00:12:57,890
+في مقابلة التوظيف لما الواحد بيسأل بهمش يخلي
+
+143
+00:12:57,890 --> 00:13:01,490
+الطالب يعيد كل العلم بس ممكن يقوله ببساطة إيش
+
+144
+00:13:01,490 --> 00:13:06,090
+التفاعل الأساسي لل aromatic compounds؟عشان يسمع
+
+145
+00:13:06,090 --> 00:13:10,710
+منه كلمة Electrophilic و Aromatic و Substitution
+
+146
+00:13:10,710 --> 00:13:14,310
+كمان سؤال زي هذا بنقول للطالب انت فاهم كيميا واضحة
+
+147
+00:13:14,310 --> 00:13:20,240
+الفكرة؟الان ايش اللى بدنا نبدله دائما اتش موجبة
+
+148
+00:13:20,240 --> 00:13:24,200
+ونحط بدالها اذا حطينا بدالها halogen بنسمي العملية
+
+149
+00:13:24,200 --> 00:13:28,740
+halogenation اذا حطينا بدالها نيترو بنسمي العملية
+
+150
+00:13:28,740 --> 00:13:32,520
+nitration اذا حطينا بدالها مجموعة ال sulphonic
+
+151
+00:13:32,520 --> 00:13:36,620
+acid sulphonation اذا حطينا مجموعة alkyl
+
+152
+00:13:36,620 --> 00:13:42,920
+alkylation اذا حطينا مجموعة acyl acylation يمكن
+
+153
+00:13:42,920 --> 00:13:48,110
+البعض يقول احنا هذه مجموعة acylما مرتش علينا احنا
+
+154
+00:13:48,110 --> 00:13:53,530
+مرت علينا افراد من مجموعة الاسل تاوي لسه انتبهوا
+
+155
+00:13:53,530 --> 00:13:58,970
+معي المجموعة بشكلها العام R C double bond O هذه
+
+156
+00:13:58,970 --> 00:14:03,690
+اسل لاحظوا زي ما بنقول الكل الكل اللي بيبين فيها
+
+157
+00:14:03,690 --> 00:14:09,930
+كلمة ايش؟ R هذه اسل اللي بيبين فيها R الان لو خلت
+
+158
+00:14:09,930 --> 00:14:11,670
+ال R تحديدا مثل
+
+159
+00:14:14,060 --> 00:14:18,700
+أيش صار اسم المجموعة؟ أسيتل توي أخدناها لو خلّيت
+
+160
+00:14:18,700 --> 00:14:26,040
+ال R تحديدًا H أيش صار اسم المجموعة؟ formal و هكذا
+
+161
+00:14:26,040 --> 00:14:31,840
+خلّيني أستكفى بهدول الأن أسيتل formal فالأسيتل و
+
+162
+00:14:31,840 --> 00:14:39,530
+ال formal are أسل groups أسل عائلةالاسيتل فرد زي
+
+163
+00:14:39,530 --> 00:14:44,090
+ما نقول الكل عائلة من افرادها مثل و اثل و بربل و
+
+164
+00:14:44,090 --> 00:14:48,250
+ايز و بربل الان الاس العائلة من افرادها اسيتل و
+
+165
+00:14:48,250 --> 00:14:52,770
+formal و روبانويل و كذا خلنا الان نضل على الاسيتل
+
+166
+00:14:52,770 --> 00:14:57,230
+و الformal فبنسمي العملية oscillation طب لو حد كتب
+
+167
+00:14:57,230 --> 00:15:01,970
+هنا CH3 و بده العملية بدقة وجد ايش هيسميها؟
+
+168
+00:15:01,970 --> 00:15:07,300
+oscillationواضح فالacetylation عملية خاصة من
+
+169
+00:15:07,300 --> 00:15:11,400
+العملية العامة اللى هى اش اسمها acetylation طبعا
+
+170
+00:15:11,400 --> 00:15:15,660
+بيصير السؤال الأصعب انه كيف انا بدى يكون عندى
+
+171
+00:15:15,660 --> 00:15:21,660
+اكلور مثلا موجب كيف بدى يكون عندى NO2 موجبة كل
+
+172
+00:15:21,660 --> 00:15:27,080
+اللى موجود هنا لاحظين الموجب عليه ولا لأ هى معناه
+
+173
+00:15:27,080 --> 00:15:31,980
+Electrophilicكل اللي موجود حقيقة في لحظة التفاعل
+
+174
+00:15:31,980 --> 00:15:38,040
+بدو يكون ايش موجب الان لو بدنا نفصل كيف انا بصل
+
+175
+00:15:38,040 --> 00:15
+
+223
+00:20:02,050 --> 00:20:07,090
+التفاعل وين بيتم؟ على ال ring نتعلمه على ال ring
+
+224
+00:20:07,090 --> 00:20:16,120
+وضحت هذه الفكرة ال Rبنفس المنطق لما انا بدى اعمل
+
+225
+00:20:16,120 --> 00:20:25,300
+نيتريشن ال N O 2 برضه بالباعش لكن ممكن ان نعمل N O
+
+226
+00:20:25,300 --> 00:20:30,000
+2 من خلال انه بنضيف H N O 3 حمض النيتريك مع H 2 S
+
+227
+00:20:30,000 --> 00:20:35,900
+O 4 بدون تفاصيل هدول الاتنين بتطلعولي ايش N O 2
+
+228
+00:20:35,900 --> 00:20:42,680
+Plus بتتفاعل محل ايش ال H Plusكذلك مثلا في ال
+
+229
+00:20:42,680 --> 00:20:50,820
+cellfonation بحط ال reagent اللي عندى SO3 مع H2SO4
+
+230
+00:20:50,820 --> 00:20:57,990
+هدولة ايش بيطلعولي HSO3 plusيعني بعمل generation
+
+231
+00:20:57,990 --> 00:21:01,850
+توليد لجزء الموجب اللي بده يتفاعل في ال alkylation
+
+232
+00:21:01,850 --> 00:21:09,370
+لما بحط R من وين بده اجيب R ايضا بحط RCl مثلا مع
+
+233
+00:21:09,370 --> 00:21:18,470
+FeCl3 واضحة الفكرة؟ هدول ايش بيعطوا مع بعض؟R plus
+
+234
+00:21:18,470 --> 00:21:23,410
+هدولة مع بعض بيعطوا R plus طبعا بالظبط محل ما
+
+235
+00:21:23,410 --> 00:21:29,310
+بتكون ال R مشبوكة بالهالوجين محل ما بتكون تشبكها
+
+236
+00:21:29,310 --> 00:21:34,010
+بالبنزين خليني اوضحلكوا هذا الكلام يعني لو
+
+237
+00:21:34,010 --> 00:21:38,550
+افترضتوا ان عندكم بنزين بهذا الشكل و اجيت و قلت
+
+238
+00:21:38,550 --> 00:21:49,940
+لكم زائد Hyana CL و FE Cl3و اكتبوا الناتج الان هذه
+
+239
+00:21:49,940 --> 00:21:57,200
+مجموعة R CL مع في CL3 لما بدي اكتب هذه المجموعة
+
+240
+00:21:57,200 --> 00:22:04,700
+كام carbon؟ تلاتة من وين بدي اشبكها؟ محل ما هي
+
+241
+00:22:04,700 --> 00:22:09,020
+شابكة مع ال CL ماعيش اشبكها من هنا او من هنا عشان
+
+242
+00:22:09,020 --> 00:22:16,850
+هيك الناتج هنامحل ما كانت المجموعة متصلة هنا مع ال
+
+243
+00:22:16,850 --> 00:22:23,270
+CL محل ما بدى اشبكها في مثل ما ال CL خلاص طلعت مع
+
+244
+00:22:23,270 --> 00:22:29,050
+ال FECL3 ال CL السالبة زى ما قبل شوية عملنا انا
+
+245
+00:22:29,050 --> 00:22:33,590
+باخد بس ال R واضح انا باخد ال R
+
+246
+00:22:36,500 --> 00:22:43,020
+بعد هيك بتعود ال CL تفلت من ال FECL3 لكن طلع هنا H
+
+247
+00:22:43,020 --> 00:22:47,740
+موجب، شيلنا H موجب؟ ال H الموجب اللي طلعت مع ال CL
+
+248
+00:22:47,740 --> 00:22:53,780
+السالب اللي هنا شو هيعطينا؟ HCL و ال FECL3 هيرجع
+
+249
+00:22:53,780 --> 00:22:58,460
+زي ما هو، هي معنى catalyst واضح؟
+
+250
+00:23:01,810 --> 00:23:06,650
+و كذلك الحال في عملية ال acetylation او ال
+
+251
+00:23:06,650 --> 00:23:13,510
+acetylation بدي استعمل R C double bond O Cl برضه
+
+252
+00:23:13,510 --> 00:23:17,930
+مع Fe Cl3 او Aluminium Cl3 نفس الفكرة الان هذا
+
+253
+00:23:17,930 --> 00:23:23,070
+بياخد ال Cl هيك بهذا الشكل ايش ضال عندى؟ R C
+
+254
+00:23:23,070 --> 00:23:28,310
+double bond O بتشبك من وين؟ من عند الكربون هذه
+
+255
+00:23:28,310 --> 00:23:34,170
+بتعطينا ال acetyl groupواضح؟ فالخلاصة أنه احنا
+
+256
+00:23:34,170 --> 00:23:39,330
+الأشياء الموجبة اللي بنفعلها تولد أثناء التفاعل
+
+257
+00:23:39,330 --> 00:23:43,210
+يعني مابيشتريش الواحد هذه ال reagents الموجبة عادة
+
+258
+00:23:43,210 --> 00:23:47,930
+بيخلق مادتين المادتين بيطلعوا الموجب هم لاحظين هنا
+
+259
+00:23:47,930 --> 00:23:53,640
+حطينا مادتينفي كل منطقة احنا بنخلط مادة اللى بتطلع
+
+260
+00:23:53,640 --> 00:23:57,440
+الشغل الموجبة اللى بتحل محل الهيدروجين الموجب هك
+
+261
+00:23:57,440 --> 00:24:01,320
+بتم ال electrophilic aromatic substitution
+
+262
+00:24:04,770 --> 00:24:09,750
+بصير سهل علينا الآن ان نكمل التفاعل يعني لو قلنا
+
+263
+00:24:09,750 --> 00:24:13,590
+لكوا اكمل المعادلة هاي هنا اللى بده تطلع ال CL
+
+264
+00:24:13,590 --> 00:24:17,850
+وهذه بده تضيف من هذه النقطة هنا هدولة التانية ايش
+
+265
+00:24:17,850 --> 00:24:24,570
+بيحطوا ن او اتو هدولة بتفعل هذا يمكن البعضأقول طب
+
+266
+00:24:24,570 --> 00:24:28,510
+ليش حطينا المجموعة هان؟ تنسوش أن الست مجموعات في
+
+267
+00:24:28,510 --> 00:24:32,810
+البنزين متكافئة يعني لما نقول هان أكمل المعادلة لو
+
+268
+00:24:32,810 --> 00:24:35,570
+واحدة كتبت الجواب هان والتاني هان والتالتة هان
+
+269
+00:24:35,570 --> 00:24:38,210
+والرابعة هان والخمسة هان والثالثة هان كله صح
+
+270
+00:24:38,210 --> 00:24:44,250
+الهيدروجينات الستة في البنزين متكافئة ولذلك بأي
+
+271
+00:24:44,250 --> 00:24:49,310
+نقطة حطوا الجواب يعني هذا اسمه أسيتوفينون طب لو
+
+272
+00:24:49,310 --> 00:24:56,080
+ارتسم هان أهانواضح؟ او لو افترضنا كان كلورو بنزين،
+
+273
+00:24:56,080 --> 00:25:02,740
+كلورو بنزين، واضح؟ فلو سألناكم the six hydrogens
+
+274
+00:25:02,740 --> 00:25:08,580
+of benzene are equivalent واضح الفكرة؟ وين ما بدكم
+
+275
+00:25:08,580 --> 00:25:13,980
+حطوا المجموعة، نفس الشيء تماما، نفس الشيء تماما
+
+276
+00:25:13,980 --> 00:25:18,480
+هذا الكلام الآن وين موجود اللي هو نظام ال
+
+277
+00:25:18,480 --> 00:25:24,850
+equivalent في البنزين؟البنزين ماعلهوش ولا إبدال
+
+278
+00:25:24,850 --> 00:25:29,810
+حطيت الإبدال الأول طيب لما الأن ننتقل للنقطة الأهم
+
+279
+00:25:29,810 --> 00:25:33,830
+في موضوعنا طب لو يا تورا جيبت substituted بنزين
+
+280
+00:25:33,830 --> 00:25:40,310
+عليه إبدال واحد أصلا يعني مثلا جيبنا هذا المركب
+
+281
+00:25:40,310 --> 00:25:44,270
+الطلوين و بدنا نعمل عليه تفاعل chlorineation أو
+
+282
+00:25:44,270 --> 00:25:50,740
+nitration أو أي تفاعلوين بدنا نحطهم؟ بيصير السؤال
+
+283
+00:25:50,740 --> 00:25:55,720
+يا ترى على الحلقة كم هيدروجينة موجود على الحلقة؟
+
+284
+00:25:55,720 --> 00:26:00,440
+خمسة، واحد، اتنين، تلاتة، اربعة، خمسة، اللي على
+
+285
+00:26:00,440 --> 00:26:05,200
+الحلقة كم نوع الهيدروجينات اللي على الحلقة؟ تلاتة،
+
+286
+00:26:05,200 --> 00:26:07,380
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+287
+00:26:07,380 --> 00:26:09,720
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+288
+00:26:09,720 --> 00:26:11,280
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+289
+00:26:11,280 --> 00:26:20,240
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتو هذه نوع تالت إذا
+
+290
+00:26:20,240 --> 00:26:23,600
+هذولة تلت أنواع طبعا لو أنا كنت بسأل كام نوع
+
+291
+00:26:23,600 --> 00:26:26,500
+الهيدروجين اللي على الحلقة هتقوللي تلاتة اللي في
+
+292
+00:26:26,500 --> 00:26:31,500
+الجزيب المجمل أربعة هذا نوع رابع الآن لما أنا بعمل
+
+293
+00:26:31,500 --> 00:26:36,220
+التفاعلات ال aromatic ماليش بهذا اللي هان و هان و
+
+294
+00:26:36,220 --> 00:26:41,450
+هانطيب لو اعملت تفاعل نفترض ال chlorineation بيصير
+
+295
+00:26:41,450 --> 00:26:44,930
+السؤال اللى عندى وين بده احط ال chlorine على هذا
+
+296
+00:26:44,930 --> 00:26:48,270
+الموقع طبعا زى هذا او على هذا زى هذا او على هذا
+
+297
+00:26:48,270 --> 00:26:52,270
+كام احتمال بيصير عندى تلاتة لاحظوا الاحتمال الاول
+
+298
+00:26:52,270 --> 00:26:57,330
+لانه مباشر بنسميه Ortho واللي بعده Meta واللي بعده
+
+299
+00:26:57,330 --> 00:27:04,180
+Para كلام منطقي ولا .. و هذا ايضا و هذا Metaالان
+
+300
+00:27:04,180 --> 00:27:10,600
+المجموعة اللي صارت موجودة بتصير تتحكم هي بالتفاعل
+
+301
+00:27:10,600 --> 00:27:14,640
+مش المجموعة اللي بتيجي من برا اللي بتتحكم بالتفاعل
+
+302
+00:27:14,640 --> 00:27:19,340
+اليوم يوم ما بيجي ضيف عليكم مين اللي بتحكم وبيقول
+
+303
+00:27:19,340 --> 00:27:26,200
+للضيف اتفضل هان و هان صاحب البيت ولا الضيف صاحب
+
+304
+00:27:26,200 --> 00:27:30,220
+البيته عشان ذلك احنا المثل اللي عندنا بنقول الضيف
+
+305
+00:27:30,220 --> 00:27:36,730
+ايش؟أسير لمحلة، يعني زي ما بيقولوا إذا كان مثلا
+
+306
+00:27:36,730 --> 00:27:39,810
+هذا الضيف إنسان غريب شوية، ممكن تقولوله اتفضل على
+
+307
+00:27:39,810 --> 00:27:43,330
+غرفة الضيوف، إذا افترضنا نظيف خالكم، بتقولوله
+
+308
+00:27:43,330 --> 00:27:45,850
+اتفضل على الصالون، إذا مين اللي اتحكم وين يجيب
+
+309
+00:27:45,850 --> 00:27:52,070
+الضيف؟ صاحب البيت، الآن مين صاحب البيت هنا؟ هذه
+
+310
+00:27:52,070 --> 00:27:57,140
+المجموعةواضح؟ ولذلك هذه المجموعة اللي هنا إلها
+
+311
+00:27:57,140 --> 00:28:01,180
+تأثيرين التأثير الأول أنها تؤثر على التفاعل من
+
+312
+00:28:01,180 --> 00:28:05,260
+ناحية السرعة يعني بعض المجموعات بتزيد سرعة
+
+313
+00:28:05,260 --> 00:28:08,280
+التفاعلات وبعضها بتنقص هذا ال effect بنسميه
+
+314
+00:28:08,280 --> 00:28:14,060
+reactivity effect يعني لها تأثير بالسرعة زيادة أو
+
+315
+00:28:14,060 --> 00:28:18,160
+انقاصةهذا التأثير الأول ال reactivity effect
+
+316
+00:28:18,160 --> 00:28:23,500
+التأثير التاني بنسميه orientation effect لها تأثير
+
+317
+00:28:23,500 --> 00:28:27,280
+على أي موقع orientation موقع على أي موقع تقول
+
+318
+00:28:27,280 --> 00:28:30,440
+للمجموعة اللي جاي اتفضلي انت هان اتفضلي هان اتفضلي
+
+319
+00:28:30,440 --> 00:28:35,110
+هان من اللي بيقول اللي جاي ولا اللي موجودالموجود
+
+320
+00:28:35,110 --> 00:28:39,430
+ولذلك إلى التأثير التاني ال orientation أو بنسميه
+
+321
+00:28:39,430 --> 00:28:41,890
+مرات regiochemistry عارفين إيش يعني
+
+322
+00:28:41,890 --> 00:28:46,670
+regiochemistry؟ region موقع يعني أنها تحدد إلى أي
+
+323
+00:28:46,670 --> 00:28:49,990
+موقع تذهب المجموعة الجديدة هي معناه regiochemistry
+
+324
+00:28:50,830 --> 00:28:55,890
+الان المجموعات تصنف إلى نوعين في مجموعات منشطة
+
+325
+00:28:55,890 --> 00:29:00,030
+تزيد سرعة التفاعل بنسميها activating groups وفي
+
+326
+00:29:00,030 --> 00:29:05,150
+مجموعات مثبتة بنسميها ايش deactivating groups وهذه
+
+327
+00:29:05,150 --> 00:29:12,200
+بدنا نتعلمها الان المجموعات المنشطةأشهرها وأعلاها
+
+328
+00:29:12,200 --> 00:29:16,580
+زي ما هي مرتبة هنا في زيادة التنشيط ال H2 اللي في
+
+329
+00:29:16,580 --> 00:29:21,020
+الانالين بعدين ال OH بعدين ال OCH3 بعدين ال CH3 و
+
+330
+00:29:21,020 --> 00:29:24,600
+ال Alkyl هدولة سهلة اللي بنقدر نحفظهم هدولة
+
+331
+00:29:24,600 --> 00:29:30,440
+بنسميهم مجموعات إيش منشطة المجموعات المثبتة بتبدأ
+
+332
+00:29:30,440 --> 00:29:33,520
+من هذا الخط لاحظوا هذا الخط الهيدروجيني عن البنزين
+
+333
+00:29:33,520 --> 00:29:42,690
+اللي أعلى منهمنشط والأقل منه مثبت activating و
+
+334
+00:29:42,690 --> 00:29:46,290
+deactivating كل ما طلعت لفوق بزيد التنشيط كل ما
+
+335
+00:29:46,290 --> 00:29:51,350
+نزلت لتحت بزيد ال ash التفبيط ولذلك ال halogens
+
+336
+00:29:51,350 --> 00:29:56,670
+are deactivating ال nitro deactivating السيانو
+
+337
+00:29:56,670 --> 00:30:00,670
+deactivating الحامض deactivating يعني أن التفاعل
+
+338
+00:30:00,670 --> 00:30:06,120
+هيكون أقل من تفاعل ال ashالبنزين لوحده اللى لو
+
+339
+00:30:06,120 --> 00:30:10,220
+كانت هذه الار اتش المعنى انه لما بنحط هنا اللى
+
+340
+00:30:10,220 --> 00:30:13,620
+الار اتش اللى هي نقطة المرجع لو هذه اتش كان صرت
+
+341
+00:30:13,620 --> 00:30:18,620
+انا ايش البنزين فاللي فوق منها اسرع من البنزين
+
+342
+00:30:18,620 --> 00:30:23,940
+اللى تحتأبطأ من البنزين هذا بالنسبة للسرعة الآن
+
+343
+00:30:23,940 --> 00:30:27,080
+السرعة مش كتير بتفرج معاكم عارفين ليش؟ لأنه مش
+
+344
+00:30:27,080 --> 00:30:30,240
+كتير بنيجي نسألكوا مين أسرع ومين أبطأ لكن لما
+
+345
+00:30:30,240 --> 00:30:36,220
+نقولكوا أكمل المعادلة بيفرج معاكم على أي جهة تحطوا
+
+346
+00:30:36,220 --> 00:30:42,120
+ناتج ال orientation عندنا قاعدة بسيطة لل
+
+347
+00:30:42,120 --> 00:30:49,180
+orientation بشكل عام المجموعات المنشطةمضاف إليها
+
+348
+00:30:49,180 --> 00:30:52,920
+الهالوجينات يعني بيبقى الخط من عند هنا هذه بتودع
+
+349
+00:30:52,920 --> 00:30:57,440
+على موقع Orthopara والمجموعات ال .. ال
+
+350
+00:30:57,440 --> 00:31:02,320
+deactivating بتودع موقع Meta يعني لو كنت أنا بفعل
+
+351
+00:31:02,320 --> 00:31:08,980
+مثلا مع Toluene وبفعله مع CL2 وين هي يجي الناتج؟
+
+352
+00:31:08,980 --> 00:31:15,420
+CL2 في وجود FECL3 على Orthopara الآن بحطش على نفس
+
+353
+00:31:15,420 --> 00:31:20,510
+الجزء Orthopara لأ بكتب ناتجينيعني مثل وعلى
+
+354
+00:31:20,510 --> 00:31:25,930
+Orthochlor و مثل وعلى Barachlor واضح؟ خليط من
+
+355
+00:31:25,930 --> 00:31:32,750
+ناتجين الاحتمالين لما بنفعل مع المجموعات اللي فوق
+
+356
+00:31:32,750 --> 00:31:37,270
+الخط اللي موجود عندنا الناتج خليط من المركبين ال
+
+357
+00:31:37,270 --> 00:31:43,770
+Ortho والBara الآن انتبهوا معي لخطأ شائع دائما
+
+358
+00:31:43,770 --> 00:31:49,590
+بيعملوه الطلاب رغم انه انا حكيت عليهأكام مرة؟ ألف
+
+359
+00:31:49,590 --> 00:31:54,370
+مرة اليوم ورغم هيك من خبرتنا تلاتين في المية من
+
+360
+00:31:54,370 --> 00:31:57,590
+الطلاب بيعملوا هذا الخطأ لاحظوا ال Nitro مجموعة
+
+361
+00:31:57,590 --> 00:32:04,990
+ايش؟ مثبتة وين بتودي؟ على ميتا اه الان طب شو هو
+
+362
+00:32:04,990 --> 00:32:08,710
+الخطأ اللي بيعمله الطلاب و مش عمال ابطله عنه ع مدى
+
+363
+00:32:08,710 --> 00:32:15,890
+السنين لما اجي اقول اكمل المعادلة وين
+
+364
+00:32:15,890 --> 00:32:17,070
+بده احط الجواب؟
+
+365
+00:32:20,310 --> 00:32:27,470
+الحمد لله انه كغلطه لاحظوا معاك انا قلتلكوا اللي
+
+366
+00:32:27,470 --> 00:32:34,050
+بتحكم اللي هنا ع طول راح مخته هنا هذه لو هي موجودة
+
+367
+00:32:34,050 --> 00:32:37,630
+هنا بتودي ع ميتا اللي بتحكم في التفاعل المجموعة
+
+368
+00:32:37,630 --> 00:32:42,650
+الموجودة كم مرة حكيتها؟هذه الموجودة وين بتودّي
+
+369
+00:32:42,650 --> 00:32:47,790
+اللي جاي؟ وعشان هيك المفروض أنه قبل ما أكتب ماعيش
+
+370
+00:32:47,790 --> 00:32:52,230
+بتفعل، لو كتبت بس هيك و لسه قاعد بكمل، لسه ماكتبتش
+
+371
+00:32:52,230 --> 00:32:55,950
+ماعيش بده يتفعل، أنتوا تكونوا جاهزة الجواب، هذا
+
+372
+00:32:55,950 --> 00:33:01,590
+وين بده يودّي؟على اورثو بارا سواء اتفاعل مع مثليشن
+
+373
+00:33:01,590 --> 00:33:05,510
+تاني مع اتش مع floor مع halogen اللي بتحكم
+
+374
+00:33:05,510 --> 00:33:10,370
+بالتفاعل هذا ولذلك لما هنا بدي اكتب HNO3 H2SO4
+
+375
+00:33:10,370 --> 00:33:16,150
+اللي بتحكم الأصلي الناتج هتكتبوه بهذا الشكل CH3 و
+
+376
+00:33:16,150 --> 00:33:24,150
+تحطوا هنا NO2 زائد هي على اورثو CH3 و تحطوا هنا
+
+377
+00:33:24,150 --> 00:33:26,970
+NO2 خليط
+
+378
+00:33:28,710 --> 00:33:33,650
+تكتبوا الاحتمالين لو انا كنت بادي مثلا بنايترو
+
+379
+00:33:33,650 --> 00:33:40,370
+بنزين وجهته بده يودي على ويت على ميته فهي المرة
+
+380
+00:33:40,370 --> 00:33:45,890
+العشرين اللي بتحكم بالتفاعل من؟ الموجودة أصلا وليس
+
+381
+00:33:45,890 --> 00:33:51,990
+الطريقة وكلام بتهيألي منطق مافيه ولا مشكلة واضحة
+
+382
+00:33:51,990 --> 00:33:57,730
+الأفكار؟ يكاد يكون معظم الأشياء اللي ضايلة عندنا
+
+383
+00:33:58,480 --> 00:34:05,680
+أشياء تطبيقية على هذه الفكرة خلّينا نشوف هاي هذا
+
+384
+00:34:05,680 --> 00:34:10,580
+الكلام بيجيب للي بيودوا Orthobara لحد ال halogens
+
+385
+00:34:10,580 --> 00:34:15,680
+لاحظوا ان ال halogens لو أنا بدى أصنفهم شو بدى
+
+386
+00:34:15,680 --> 00:34:20,620
+أقول عنهم من ناحية تأثيرهم activating ولا
+
+387
+00:34:20,620 --> 00:34:24,120
+deactivating دي activating لكن من ناحية التوجيه
+
+388
+00:34:26,320 --> 00:34:35,220
+الهالوجين دي اكتفت الهالوجين
+
+389
+00:34:35,220 --> 00:34:39,920
+دي اكتفت الهالوجين دي اكتفت الهالوجين دي اكتفت
+
+390
+00:34:39,920 --> 00:34:44,380
+الهال
+
+445
+00:39:26,120 --> 00:39:30,020
+OCL مع الومليوم كلورايت لحظوا ان الكلام بتكون
+
+446
+00:39:30,020 --> 00:39:33,320
+تتدربوا ع كتابته احنا الآن محاضرة بتكون ترجعوا
+
+447
+00:39:33,320 --> 00:39:37,500
+تحضروا التصوير و تتدربوا و تحفظوا بيحط في اي موقع
+
+448
+00:39:37,500 --> 00:39:46,340
+ال Ortho زائد ال Vara احنا اللي مطلوب منها ايش
+
+449
+00:39:47,240 --> 00:39:53,540
+البارة وبنكتب هنا كمان زائد ال orthocompound صح؟
+
+450
+00:39:53,540 --> 00:39:59,240
+بس هو طالب كيف بنحضر ال ortho البارة عفوا الان نفس
+
+451
+00:39:59,240 --> 00:40:11,060
+الأمثلة اللي عندكم سجلتوا؟ يلا سجلوا و
+
+452
+00:40:11,060 --> 00:40:17,360
+بكون سعيد ان انتوا تجاوبوا لو قلنالكواهذا المركب
+
+453
+00:40:17,360 --> 00:40:21,420
+كام مجموعة فيه؟ طب إذا بدأ أبدأ من البنزين هذه وين
+
+454
+00:40:21,420 --> 00:40:26,040
+بتودي؟ يالها أورتوبالا و هذه؟ ميتا العلاقة اللي
+
+455
+00:40:26,040 --> 00:40:31,580
+موجودة إذا المقش اللي لازم أبدأ فيها start by
+
+456
+00:40:31,580 --> 00:40:37,540
+nitration الآن هذه COCH3
+
+457
+00:40:37,540 --> 00:40:44,480
+هذه اللي هي سيضة بالبند OCH3 هي كده ميتا و هذه؟
+
+458
+00:40:48,050 --> 00:40:53,270
+العلاقة الموجودة اذا ايش اللي لازم ابدأ فيه ال
+
+459
+00:40:53,270 --> 00:40:53,730
+isolation
+
+460
+00:40:57,190 --> 00:41:01,690
+ميتا بتودى على ميتا position هذى وين بتودى
+
+461
+00:41:01,690 --> 00:41:06,750
+اورتوبارا اللى موجود عندى اذا ايش اللى لازم ابدأ
+
+462
+00:41:06,750 --> 00:41:10,850
+فيه هذا الكلام طبقه عد انتوا بالإيد واستمتعوا
+
+463
+00:41:10,850 --> 00:41:14,670
+بتطبيقه وأكيد لو دخلتوا على الامتحانات السابقة
+
+464
+00:41:14,670 --> 00:41:19,610
+هتلاقوا في كل امتحان سؤال من هذا النوع انه بنجيب
+
+465
+00:41:19,610 --> 00:41:24,550
+مركب ال two substituents و بنقولكواكيف بتحضر هذا
+
+466
+00:41:24,550 --> 00:41:33,290
+المركب من البنزين عشان نشوف كيف فهمته قصة
+
+467
+00:41:33,290 --> 00:41:39,710
+ال radiochemistry بضل عندى شغلتين صغار بتجيجتين
+
+468
+00:41:39,710 --> 00:41:45,910
+الحمد لله خلصناانه غير البنزين في عندى مراكبات
+
+469
+00:41:45,910 --> 00:41:51,390
+كتير فيها اكثر من حلقة بنزين تمام الان اذا
+
+470
+00:41:51,390 --> 00:41:59,550
+بتلاحظوا انتوا البنزين كان by electron كان فيه ستة
+
+471
+00:41:59,550 --> 00:42:07,140
+ستة بعد البنزين بيجيه من النفثالين جديش فيهأربعة
+
+472
+00:42:07,140 --> 00:42:09,800
+في اتنين اربعة في اتنين اربعة في اتنين اربعة في
+
+473
+00:42:09,800 --> 00:42:14,520
+اتنين اربعة
+
+474
+00:42:14,520 --> 00:42:18,000
+في اتنين اربعة في اتنين اربعة في اتنين اربعة في
+
+475
+00:42:18,000 --> 00:42:23,380
+اتنين اربعة في اتنين اربعة
+
+476
+00:42:23,380 --> 00:42:27,760
+في اتنين
+
+477
+00:42:27,760 --> 00:42:29,820
+اربعة في اتنين اربعة في اتنين اربعة في اتنين اربعة
+
+478
+00:42:29,820 --> 00:42:31,820
+في اتنين اربعة في اتنين اربعة في اتنين اربعة في
+
+479
+00:42:31,820 --> 00:42:32,120
+اتنين اربعة في اتنين اربعة في اتنين اربعة في اتنين
+
+480
+00:42:32,120 --> 00:42:33,280
+اربعة في اتنين اربعة في اتنين اربعة في اتنين اربعة
+
+481
+00:42:33,280 --> 00:42:34,400
+في اتنين اربعة في اتنين اربعة في اتنين اربعة في
+
+482
+00:42:34,400 --> 00:42:40,330
+اتنين اربعة في اتنينعشرين زاد اتنين اتنين و عشرين
+
+483
+00:42:40,330 --> 00:42:44,590
+الان عدد ال by electrons لازم يكون زي هيك اذا كان
+
+484
+00:42:44,590 --> 00:42:50,100
+زي هيك بيكون المركب اللي عندى ايش aromaticيعني
+
+485
+00:42:50,100 --> 00:42:52,880
+المركب عشان يكون aromatic بدوا يكون فيه by
+
+486
+00:42:52,880 --> 00:42:57,940
+electrons يا 6 يا 10 يا 14 يا 18 يا 22 لاحظوا هنا
+
+487
+00:42:57,940 --> 00:43:04,400
+قداش عددهم بالنفثالين عشرة هنا 2 4 6 8 10 12 14
+
+488
+00:43:04,400 --> 00:43:09,520
+تلت حلقات بيصير اسمهم أنثراسين أو فنانثرين بهذا
+
+489
+00:43:09,520 --> 00:43:15,660
+الشكل الآن بعد هيك هذا المركب هذا المركب هي فيه ال
+
+490
+00:43:15,660 --> 00:43:20,480
+بيرين مع بنزينة عشان هيك إيش بيسموهبنزو ايه
+
+491
+00:43:20,480 --> 00:43:24,620
+بايرين؟ يعني هو damage من البنزين مع ال بايرين
+
+492
+00:43:24,620 --> 00:43:29,740
+فإيش سمناه؟ بنزو بايرين هذا المركب اللي موجود في
+
+493
+00:43:29,740 --> 00:43:36,560
+السجائر وبيسبب السرطان وموجود في الحرق، بيطلع من
+
+494
+00:43:36,560 --> 00:43:43,380
+الحرق سواء حرجنا كاكاو، بخور، سجائر، تبغ، شيشة،
+
+495
+00:43:43,380 --> 00:43:49,600
+معسلكل الحرق هذا دايما بيطلع ال بنزو A بايرين اللي
+
+496
+00:43:49,600 --> 00:43:53,720
+هو ال carcinogenic compound كل الحرق اللي هنا
+
+497
+00:43:53,720 --> 00:43:59,480
+بيطلع بنزو A بايرين اللي هو ايش؟ carcinogenic
+
+498
+00:43:59,480 --> 00:44:05,560
+compound مركب مسرطن حتى .. انتبهوا معي البخور مش
+
+499
+00:44:05,560 --> 00:44:10,880
+كتير تولعوه في الدور نفس الاشي بيطلع ال بنزو A
+
+500
+00:44:10,880 --> 00:44:15,630
+بايرينالكاكاو إذا الحرج كتير في الكيك أو ما إلى
+
+501
+00:44:15,630 --> 00:44:18,810
+ذلك كل المنطقة المحروجة بصير فيها بنزو اي بايرين
+
+502
+00:44:18,810 --> 00:44:23,010
+ماتاكلوش الاشي المحروج واضح؟ بيكون فيه ال بنزو اي
+
+503
+00:44:23,010 --> 00:44:30,030
+بايرين المركب الكارسينوجينب الخشب
+
+504
+00:44:30,030 --> 00:44:33,150
+بيطلع ثانو أكسيد كربونه أول أكسيد كربونه بيخنج
+
+505
+00:44:33,150 --> 00:44:43,110
+الناس اخر شغلة عشان أخلصهي عبارة عن اكتشاف حديث
+
+506
+00:44:43,110 --> 00:44:47,130
+يمكن لما حكيت عن الالوتروبز حكيت لكم ياه كرة
+
+507
+00:44:47,130 --> 00:44:51,050
+الكربون ستين كلكم بتعرفوا الكربون في الطبيعة موجود
+
+508
+00:44:51,050 --> 00:44:57,060
+على أي أشكالGraphite و Diamonds الآن بال ألف و
+
+509
+00:44:57,060 --> 00:45:01,540
+تسعمية و ثمانية و بعد لقوا صورة جديدة من ستين ذرة
+
+510
+00:45:01,540 --> 00:45:08,300
+كربون هذه الصورة سموها carbon sixty لأن هدولة
+
+511
+00:45:08,300 --> 00:45:14,930
+النقاط كم ذرةواللي حدد او ساعد تحديدها انسان اسمه
+
+512
+00:45:14,930 --> 00:45:17,630
+book monster fullero عشان هيك سماوه fullerine
+
+513
+00:45:17,630 --> 00:45:21,370
+الناس اللي اكتشفوا هذا الكلام اخدوا عليه جائزة
+
+514
+00:45:21,370 --> 00:45:24,490
+نوبل في الكيميا اخدوا عليه جائزة نوبل في الكيميا
+
+515
+00:45:24,490 --> 00:45:30,680
+بحدود 95 مش زمانواضح؟ اللي هو الفوليرين إيش اللي
+
+516
+00:45:30,680 --> 00:45:36,160
+قالوا؟ قالوا 60 ذرة موجودين على سطح كرة و الكرة
+
+517
+00:45:36,160 --> 00:45:43,280
+عبارة عن أشكال سداسية و خماسية 32 وجه ال 32 منهم
+
+518
+00:45:43,280 --> 00:45:49,900
+أظن 20 سداسي و 12 خماسي لو روحتوا أنتوا على البيت
+
+519
+00:45:49,900 --> 00:45:54,520
+و شوفتوا أي كرة موجودة عديتوا الوجوه اللي موجودة
+
+520
+00:45:54,520 --> 00:46:00,220
+عليها كتبتوا 1,2,3,4 هتلاقوهم كام وجه؟32 لو عديته
+
+521
+00:46:00,220 --> 00:46:03,800
+النقاط اللي هذا اللي تمثل ال carbon هتلاقوهم كام
+
+522
+00:46:03,800 --> 00:46:08,240
+نقطة؟ 60 نقطة ولذلك سمو هذا كرة الكربون وقيلها
+
+523
+00:46:08,240 --> 00:46:14,600
+تطبيقات كتيرة في الحياة هي أساسا بتشبه المراكبات
+
+524
+00:46:14,600 --> 00:46:19,170
+ال aromatic لكن علم خاص مش موضوعنا أنهاانه الآن
+
+525
+00:46:19,170 --> 00:46:23,150
+نحكي فيه اللي جابها اللي فيها الحلقات السداسية
+
+526
+00:46:23,150 --> 00:46:29,010
+اللي فيها الحلقات السداسية واكتشاف يعني جديد ويله
+
+527
+00:46:29,010 --> 00:46:33,830
+كثير من التطبيقات، ابهيك بننهي اليوم ونشكركوا على
+
+528
+00:46:33,830 --> 00:46:35,230
+حصن باسمنا
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..931026af035b737c383ecbe8fe415c09a36bf8e9
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_postprocess.srt
@@ -0,0 +1,2112 @@
+1
+00:00:20,910 --> 00:00:24,950
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:24,950 --> 00:00:30,470
+تسمية ال aromatic compounds وركزنا على نقطة لما
+
+3
+00:00:30,470 --> 00:00:35,010
+بيكون موجود عندنا اكثر من substituent نتبع المركب
+
+4
+00:00:35,010 --> 00:00:42,550
+لأي مجموعة و القمر زي ما بتلاحظه بسيط من خلال انه
+
+5
+00:00:42,550 --> 00:00:45,890
+اعطيناكم ترتيب معين من خلال انه اعطيناكم ترتيب
+
+6
+00:00:45,890 --> 00:00:53,020
+معين يمكن في نقطة بدى انوحلهاحتى إذا واجهتكم ما
+
+7
+00:00:53,020 --> 00:00:59,260
+تتخربطوش فيها من خلال هذه المركبات لاحظوا مثلا هذا
+
+8
+00:00:59,260 --> 00:01:07,330
+المركب أعلى مجموعة في ال OH ولذلك سمناهفينول فينول
+
+9
+00:01:07,330 --> 00:01:15,130
+سمناها فينول واضح فبينت ال OH في نهاية المقطع بشكل
+
+10
+00:01:15,130 --> 00:01:21,290
+all الان السؤال لما ال OH ما تكونش هي المجموعة
+
+11
+00:01:21,290 --> 00:01:26,900
+اللي بدها تكون عائلة المركب تيجي عائلة أعلى منهاهي
+
+12
+00:01:26,900 --> 00:01:32,300
+إيش بده يصير فيها؟ بده ترجع لاسمها الأصل لما اتبعت
+
+13
+00:01:32,300 --> 00:01:37,740
+العائلة ولذلك في هذا المركب لما وجدت ال OH مع هذه
+
+14
+00:01:37,740 --> 00:01:42,820
+المجموعة الآن ال aldehyde أعلى من ال OH فالمركب
+
+15
+00:01:42,820 --> 00:01:49,280
+ساربينز الديهايد شو سميت ال OH؟ Hydroxy واضح؟ الآن
+
+16
+00:01:49,280 --> 00:01:54,820
+الكلام نفسه بتكرر لو أنا أعطيتكم مركب زي هذا مثلا
+
+17
+00:01:58,460 --> 00:02:04,760
+C double bond O CH3 و حطيت هنا CH3 الآن هنا في
+
+18
+00:02:04,760 --> 00:02:09,620
+عندك كيتون و الكلجروب العائلة الكيتون و هذا
+
+19
+00:02:09,620 --> 00:02:17,720
+الكيتون معروف اسمه أسيتوفينونواضح؟ أسيتوفينون فلما
+
+20
+00:02:17,720 --> 00:02:24,320
+أجي بدي أسم المركب بقول 4-methylacetophenone طيب
+
+21
+00:02:24,320 --> 00:02:30,580
+السؤال لو هذه المجموعة ماكنتش عائلة لو إجت مجموعة
+
+22
+00:02:30,580 --> 00:02:34,440
+أعلى منها و المجموعات الأعلى من الكيتون الالديهيد
+
+23
+00:02:34,440 --> 00:02:39,380
+أو الاسد أو ال Easter شو بيصير اسم هذه المجموعة؟
+
+24
+00:02:40,130 --> 00:02:45,510
+واضح؟ يعني لو حطيت بمثل هذا المثال الآن هاي
+
+25
+00:02:45,510 --> 00:02:49,830
+الديهايد وهاي كيتون ال الديهايد أعلى من ال كيتون
+
+26
+00:02:49,830 --> 00:02:56,550
+إذا للجزء اللي عندي .. الجزء اللي عندي شو هو؟ بنز
+
+27
+00:02:56,550 --> 00:03:02,390
+الديهايد طب هذه المجموعة CH3C double bond O إيش
+
+28
+00:03:02,390 --> 00:03:07,800
+اسمها؟ الان بديكوا تعرفوا إن اسمها Acetylبنعرف إن
+
+29
+00:03:07,800 --> 00:03:13,000
+اسمها Acetyl الان هذه المجموعة جاية من وين أساساً
+
+30
+00:03:13,000 --> 00:03:18,360
+جاية من حمب ال Acetic Acid اللي هو حمب الخلق لو
+
+31
+00:03:18,360 --> 00:03:26,040
+احنا اتطلعنا على ال Acetic Acid CH3COOH
+
+32
+00:03:26,040 --> 00:03:33,870
+تمام الان مجموعة ال Acetyl هنا هي هذه المجموعةهذه
+
+33
+00:03:33,870 --> 00:03:37,050
+الاستيل وبنرمزلها عادة بالرمز
+
+34
+00:03:40,120 --> 00:03:45,720
+AC و لذلك لو كان عندكم مثلا مركب مكتوب عليه AC
+
+35
+00:03:45,720 --> 00:03:50,620
+بتكون تعرف ان هذه مجموعة ايش ال Acetal اللي هي
+
+36
+00:03:50,620 --> 00:03:57,860
+CH3C double bond O لوحدها الان مر علي مجموعة تانية
+
+37
+00:03:57,860 --> 00:04:04,800
+بتشبهها لو انا أخدت CH3C double bond O مع ال
+
+38
+00:04:04,800 --> 00:04:10,410
+Oxygenعرفت الآن الـ Acetyl فقط هذا الجزء طب يا
+
+39
+00:04:10,410 --> 00:04:17,150
+تورا لو أخدت هذه كمجموعة CH3C O O و عادة هذه تكون
+
+40
+00:04:17,150 --> 00:04:22,830
+minus ممكن يكون معها NA plus نتذكر هذه إيش اسمها
+
+41
+00:04:22,830 --> 00:04:30,590
+كلها كمجموعة هذه بتصير Acetateأيون سالب والأيونات
+
+42
+00:04:30,590 --> 00:04:35,870
+السالبة عادة بتنتهي بـ 8 زي ما بيقول سولفات نيترات
+
+43
+00:04:35,870 --> 00:04:40,810
+كاربونات أسيتات هذه مجموعة الخلات بنسميها بالعربي
+
+44
+00:04:40,810 --> 00:04:44,470
+ولذلك هذا بيصير Sodium Acetate بالإنجليزي أو
+
+45
+00:04:44,470 --> 00:04:51,110
+بالعربي خلات ال Sodium فهذه المجموعة بيكون أسيتات
+
+46
+00:04:51,110 --> 00:04:55,250
+الآن لو بدي أكتب مجموعة الأسيتات مختصرة كيف
+
+47
+00:04:55,250 --> 00:05:04,240
+بكتبها؟ACO- لأن هذه الواحدة AC A capital small c
+
+48
+00:05:04,240 --> 00:05:09,520
+الآن مع ال oxygen بتصير ACO- إذا صار عندي مجموعة
+
+49
+00:05:09,520 --> 00:05:17,620
+AC و مجموعة ACO واضح؟ الآن السؤال لو أجهكم مثلا
+
+50
+00:05:17,620 --> 00:05:20,260
+بتفاعل مكتوب عندكم ACOH
+
+51
+00:05:22,240 --> 00:05:29,940
+اش بده يكون ال acetic acid هاي AC و هاي O و هاي H
+
+52
+00:05:29,940 --> 00:05:36,180
+فال acetic acid ايش بنختصره ACOH هذا ال acetic
+
+53
+00:05:36,180 --> 00:05:42,810
+acidهذه الرموز عادة تتكرر معنا الاسيتك أسد الاسيتك
+
+54
+00:05:42,810 --> 00:05:45,430
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+55
+00:05:45,430 --> 00:05:47,770
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+56
+00:05:47,770 --> 00:05:48,710
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+57
+00:05:48,710 --> 00:05:49,470
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+58
+00:05:49,470 --> 00:05:52,670
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+59
+00:05:52,670 --> 00:05:54,150
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+60
+00:05:54,150 --> 00:06:00,430
+أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك
+
+61
+00:06:00,430 --> 00:06:04,530
+أسإذا رجعت لأصلها في المركب اللي قبل شوية كتبناها
+
+62
+00:06:04,530 --> 00:06:09,070
+كان acetophenon كانت هي العائلة لما صارت فرد وفي
+
+63
+00:06:09,070 --> 00:06:14,390
+إيش أعلى منها بدرجة على إيش لأصلها أصلها اللي هو
+
+64
+00:06:14,390 --> 00:06:21,810
+ال acetyl كذلك الحال في هذا المركب acid و ketone
+
+65
+00:06:23,090 --> 00:06:28,410
+طبعا المركب بده يتبع ايش ال acid بنزويك acid هذي
+
+66
+00:06:28,410 --> 00:06:31,670
+ايش بتكون ال acid ال acid ال acid ال acid ال acid
+
+67
+00:06:31,670 --> 00:06:40,410
+acid
+
+68
+00:06:40,410 --> 00:06:44,930
+the acid the acid the acid the acid the acid the
+
+69
+00:06:44,930 --> 00:06:46,150
+acid the acid the acid the acid the acid the acid
+
+70
+00:06:46,150 --> 00:06:50,190
+the acid the acid the acid the acid the acid the
+
+71
+00:06:50,190 --> 00:06:55,560
+acid the acid theهذا المثال مش موجود عندكم acid
+
+72
+00:06:55,560 --> 00:07:01,700
+and aldehyde من الأعلى ال acid ممتاز طيب هذا
+
+73
+00:07:01,700 --> 00:07:11,440
+بنزويك acid بنزويك acid الآن هذه المجموعة شو اسمها
+
+74
+00:07:11,440 --> 00:07:14,980
+formal
+
+75
+00:07:14,980 --> 00:07:21,020
+واضح وبالتالي هذا بيصير ايش for formal
+
+76
+00:07:22,970 --> 00:07:27,890
+For formal هذه المجموعة الـ C double bond O المتصل
+
+77
+00:07:27,890 --> 00:07:31,570
+بـ H formal و الـ C double bond O لو اتصلت ب مثل
+
+78
+00:07:31,570 --> 00:07:38,380
+بتصير كيتون أسيتل أخدناهاواضحة الفكرة؟ فكل شيء إذا
+
+79
+00:07:38,380 --> 00:07:42,680
+ماكانش هو العائلة بده يرجع لإيش؟ لاسمه تماما
+
+80
+00:07:42,680 --> 00:07:46,560
+الميثل لما بتكون عائلة بنكون نقول طلوين لما تبطل
+
+81
+00:07:46,560 --> 00:07:51,700
+عائلة بترجع مثل ال OH لما تكون عائلة فينول بتبطل
+
+82
+00:07:51,700 --> 00:07:56,500
+عائلة بترجع هيدروكسي الكيتون مثلا هذه المجموعة لما
+
+83
+00:07:56,500 --> 00:08:02,720
+تكون عائلة أسيتوفينون بطلت عائلة أسيتلال Formyl
+
+84
+00:08:02,720 --> 00:08:12,560
+Benzaldehyde بطلت عائلة ترجع لإسم Formyl طبعا ربما
+
+85
+00:08:12,560 --> 00:08:18,140
+البعض منكم يعرف أن Formyl أيضا جاية من هذه
+
+86
+00:08:18,140 --> 00:08:23,680
+المجموعة اللي هي C double bond OH OH هذا اللي اسمه
+
+87
+00:08:23,680 --> 00:08:28,760
+Formic Acid أبسط الأحماض العضويةأبسط الأحماض
+
+88
+00:08:28,760 --> 00:08:33,140
+العضوية اللي فيه H ال Acetic Acid فيه مثل تاني حمض
+
+89
+00:08:33,140 --> 00:08:37,500
+عضوي لكن أبسط واحد في الأحماض العضوية اللي اسمه
+
+90
+00:08:37,500 --> 00:08:44,280
+ايش Formic Acid الأهم منه هذه المجموعة لوحدها
+
+91
+00:08:44,280 --> 00:08:49,440
+كمجموعة عضوية ايش اسمها Formic اسمها Formic
+
+92
+00:08:49,440 --> 00:08:56,170
+بالعربي هذا Formic Acid شو بيسموه حمض النمليكلأ هو
+
+93
+00:08:56,170 --> 00:09:00,430
+ال formalin هو ال formaldehyde مدوب في مياه بمعنى
+
+94
+00:09:00,430 --> 00:09:05,050
+بعدين لكن هذا بنسميه بالعربي حمب النمليك لأن هذا
+
+95
+00:09:05,050 --> 00:09:09,720
+الحمب اللي النملة لما بتجرسبتحطه .. بتفرزه في
+
+96
+00:09:09,720 --> 00:09:13,760
+الإيد و بيسبب القلم الشديد اللي بتعرفه و حتى
+
+97
+00:09:13,760 --> 00:09:17,000
+باللغة الألمانية زي ما احنا بنسمي .. احنا بنسمي
+
+98
+00:09:17,000 --> 00:09:20,720
+النمليك و ما عنده من نمل Amazin فبسموه Amazin
+
+99
+00:09:20,720 --> 00:09:26,860
+Zörey حمض النمل Amazin Zörey واضح؟ فهذه ال form
+
+100
+00:09:26,860 --> 00:09:32,080
+اللي جاية من وين؟ من ال Formic أصل هذه النقطة حسيت
+
+101
+00:09:32,080 --> 00:09:35,820
+أنه ربما بيكون مفيد ان انا أكد عليها في موضوع
+
+102
+00:09:35,820 --> 00:09:40,730
+التسميةالان بالنسبة للتفاعلات لل aromatic
+
+103
+00:09:40,730 --> 00:09:45,910
+compounds اتفقنا احنا على شغلة ان ال aromatic
+
+104
+00:09:45,910 --> 00:09:50,130
+compounds او حلقة البنزين كثافة إلكترونية ولذلك
+
+105
+00:09:50,130 --> 00:09:54,290
+الذي يجب ان يهاجم عليها موجب هذه النقطة الأولى
+
+106
+00:09:54,290 --> 00:10:00,140
+النقطة الثانية انها لا تتفاعل بالاضافةو لذلك
+
+107
+00:10:00,140 --> 00:10:03,340
+لاحظوا ال double bonds هنا في كل التفاعلات حاطينهم
+
+108
+00:10:03,340 --> 00:10:07,160
+على شكل حلقة لأنه تعبير عن ال resonance و ما
+
+109
+00:10:07,160 --> 00:10:11,200
+بنغيرش فيهم طب ها إيش اللي بيصير في تفاعلات ال
+
+110
+00:10:11,200 --> 00:10:16,720
+aromatic compounds؟ تفاعل إبدال ماذا نفعل في هذا
+
+111
+00:10:16,720 --> 00:10:22,780
+تفاعل الإبدال؟ بنيجي بنشيل موجب و بنحط بدله موجب
+
+112
+00:10:22,780 --> 00:10:28,910
+تانيواضح؟ دائما الإبدال اللي بده يبدل شغلة بشغلة
+
+113
+00:10:28,910 --> 00:10:36,080
+بيبدل شغلةمن نفس الشغلة يعني لو بدأ أبدل موجب إذا
+
+114
+00:10:36,080 --> 00:10:40,500
+بدأ أشيل منه المركب موجب شو بدأ أحط بداله موجب
+
+115
+00:10:40,500 --> 00:10:45,500
+الآن هنا بسمي الإبدال Electrophilic Substitution
+
+116
+00:10:45,500 --> 00:10:49,960
+مرت معنى كلمة Electrophilic موجب مظبوط ولا لأ
+
+117
+00:10:49,960 --> 00:10:55,150
+ولذلك هتلاحظوا هنا إيش العنوانElectrophilic
+
+118
+00:10:55,150 --> 00:10:58,330
+Substitution معنى Electrophilic Substitution بدي
+
+119
+00:10:58,330 --> 00:11:05,410
+اشيل اشي موجد و احط مكانه اشي موجد مظبوط ولا لأ و
+
+120
+00:11:05,410 --> 00:11:11,890
+اللي بده يبدل سالبإيش بده يحط مكانه؟ سالب و لذلك
+
+121
+00:11:11,890 --> 00:11:17,070
+هيجعلنا في مكان تاني بل أمر علينا في أمثلة سابقة
+
+122
+00:11:17,070 --> 00:11:22,270
+لو كنتوا منتبهين in eucleophilic substitution إن
+
+123
+00:11:22,270 --> 00:11:26,990
+أشيل سالب أحط مكانه سالب أشيل موجب أحط مكانه موجب
+
+124
+00:11:26,990 --> 00:11:31,610
+لما المرة الماضية على سبيل المثال كنا الفاعل
+
+125
+00:11:32,860 --> 00:11:37,700
+الاسيتالايد انايون مع مركب فيه كلور او يود متذكرين
+
+126
+00:11:37,700 --> 00:11:41,360
+شيلنا ال يود السالب مع الكتروناتو و حطينا
+
+127
+00:11:41,360 --> 00:11:45,780
+الاسيتلايد اخر تفاعل في الاسيتليانز قولنا بنشيل
+
+128
+00:11:45,780 --> 00:11:50,340
+سالب و نحط سالب الان لو اجيت قولتلكم هذا التفاعل
+
+129
+00:11:50,340 --> 00:11:54,830
+شو بدي اسميهبدي أسميه الـ Eucleophilic
+
+130
+00:11:54,830 --> 00:12:00,390
+Substitution لأن أنا بدأت بالـ Eucleophile هنا وين
+
+131
+00:12:00,390 --> 00:12:06,690
+الموجب اللي بدي أشيله؟ الاتش هذه لوحدها بدون زوج
+
+132
+00:12:06,690 --> 00:12:12,530
+الإلكترونة، تنتبهوا معي وجدت بدي أجيب بدلها موجب،
+
+133
+00:12:12,530 --> 00:12:18,700
+نفترض X موجبة، CL موجبة، شيلت الاتش الموجبة؟حطيت
+
+134
+00:12:18,700 --> 00:12:22,720
+ال X الموجبة هذه محصلة التفاعل إذا التفاعل إيش
+
+135
+00:12:22,720 --> 00:12:26,520
+بيصير اسمه Electrophilic Aromatic Substitution
+
+136
+00:12:26,520 --> 00:12:29,680
+ولذلك لو إحنا بنيجي بنسألكم مثلا aromatic
+
+137
+00:12:29,680 --> 00:12:35,450
+compounds undergo addition reactions غلطAromatic
+
+138
+00:12:35,450 --> 00:12:38,990
+compounds undergo a nucleophilic aromatic
+
+139
+00:12:38,990 --> 00:12:42,530
+substitution برضه غلط لليوكليوفال بيجربش عليها
+
+140
+00:12:42,530 --> 00:12:48,630
+لأنها سالبة كثافة إلكترونية هنا فمين اللي بيقدر
+
+141
+00:12:48,630 --> 00:12:54,310
+يجرب عليها الموجب فلمّا ينسقل الطالب سؤال عام حتى
+
+142
+00:12:54,310 --> 00:12:57,890
+في مقابلة التوظيف لما الواحد بيسأل بهمش يخلي
+
+143
+00:12:57,890 --> 00:13:01,490
+الطالب يعيد كل العلم بس ممكن يقوله ببساطة إيش
+
+144
+00:13:01,490 --> 00:13:06,090
+التفاعل الأساسي لل aromatic compounds؟عشان يسمع
+
+145
+00:13:06,090 --> 00:13:10,710
+منه كلمة Electrophilic و Aromatic و Substitution
+
+146
+00:13:10,710 --> 00:13:14,310
+كمان سؤال زي هذا بنقول للطالب انت فاهم كيميا واضحة
+
+147
+00:13:14,310 --> 00:13:20,240
+الفكرة؟الان ايش اللى بدنا نبدله دائما اتش موجبة
+
+148
+00:13:20,240 --> 00:13:24,200
+ونحط بدالها اذا حطينا بدالها halogen بنسمي العملية
+
+149
+00:13:24,200 --> 00:13:28,740
+halogenation اذا حطينا بدالها نيترو بنسمي العملية
+
+150
+00:13:28,740 --> 00:13:32,520
+nitration اذا حطينا بدالها مجموعة ال sulphonic
+
+151
+00:13:32,520 --> 00:13:36,620
+acid sulphonation اذا حطينا مجموعة alkyl
+
+152
+00:13:36,620 --> 00:13:42,920
+alkylation اذا حطينا مجموعة acyl acylation يمكن
+
+153
+00:13:42,920 --> 00:13:48,110
+البعض يقول احنا هذه مجموعة acylما مرتش علينا احنا
+
+154
+00:13:48,110 --> 00:13:53,530
+مرت علينا افراد من مجموعة الاسل تاوي لسه انتبهوا
+
+155
+00:13:53,530 --> 00:13:58,970
+معي المجموعة بشكلها العام R C double bond O هذه
+
+156
+00:13:58,970 --> 00:14:03,690
+اسل لاحظوا زي ما بنقول الكل الكل اللي بيبين فيها
+
+157
+00:14:03,690 --> 00:14:09,930
+كلمة ايش؟ R هذه اسل اللي بيبين فيها R الان لو خلت
+
+158
+00:14:09,930 --> 00:14:11,670
+ال R تحديدا مثل
+
+159
+00:14:14,060 --> 00:14:18,700
+أيش صار اسم المجموعة؟ أسيتل توي أخدناها لو خلّيت
+
+160
+00:14:18,700 --> 00:14:26,040
+ال R تحديدًا H أيش صار اسم المجموعة؟ formal و هكذا
+
+161
+00:14:26,040 --> 00:14:31,840
+خلّيني أستكفى بهدول الأن أسيتل formal فالأسيتل و
+
+162
+00:14:31,840 --> 00:14:39,530
+ال formal are أسل groups أسل عائلةالاسيتل فرد زي
+
+163
+00:14:39,530 --> 00:14:44,090
+ما نقول الكل عائلة من افرادها مثل و اثل و بربل و
+
+164
+00:14:44,090 --> 00:14:48,250
+ايز و بربل الان الاس العائلة من افرادها اسيتل و
+
+165
+00:14:48,250 --> 00:14:52,770
+formal و روبانويل و كذا خلنا الان نضل على الاسيتل
+
+166
+00:14:52,770 --> 00:14:57,230
+و الformal فبنسمي العملية oscillation طب لو حد كتب
+
+167
+00:14:57,230 --> 00:15:01,970
+هنا CH3 و بده العملية بدقة وجد ايش هيسميها؟
+
+168
+00:15:01,970 --> 00:15:07,300
+oscillationواضح فالacetylation عملية خاصة من
+
+169
+00:15:07,300 --> 00:15:11,400
+العملية العامة اللى هى اش اسمها acetylation طبعا
+
+170
+00:15:11,400 --> 00:15:15,660
+بيصير السؤال الأصعب انه كيف انا بدى يكون عندى
+
+171
+00:15:15,660 --> 00:15:21,660
+اكلور مثلا موجب كيف بدى يكون عندى NO2 موجبة كل
+
+172
+00:15:21,660 --> 00:15:27,080
+اللى موجود هنا لاحظين الموجب عليه ولا لأ هى معناه
+
+173
+00:15:27,080 --> 00:15:31,980
+Electrophilicكل اللي موجود حقيقة في لحظة التفاعل
+
+174
+00:15:31,980 --> 00:15:38,040
+بدو يكون ايش موجب الان لو بدنا نفصل كيف انا بصل
+
+175
+00:15:38,040 --> 00:15:43,980
+لاشياء موجبة كيف انا بصل لاشياء موجبة عادة هذا
+
+176
+00:15:43,980 --> 00:15:49,880
+ممكن يتم باكثر من طريقة لو افترضت مثلا بدي لكلور
+
+177
+00:15:49,880 --> 00:15:54,320
+الموجب اللي هي اول واحدة بعمل chlorination بدي
+
+178
+00:15:54,320 --> 00:15:59,150
+لكلور الموجب لكلور في الدنيا كيف بنباع؟لأ مش minus
+
+179
+00:15:59,150 --> 00:16:06,430
+CLCL CL2 أو NA plus CL minus على العلم الراسي ال
+
+180
+00:16:06,430 --> 00:16:11,590
+minus موجود و ال CLCL موجود لكن الموجب مش موجود
+
+181
+00:16:11,590 --> 00:16:16,110
+الآن بضيف catalyst عامل حفاظ عادة بنقوله Lewis
+
+182
+00:16:16,110 --> 00:16:21,950
+acid حسب تعريفات Lewis FE Cl3 لو بتلاحظوا ال FE
+
+183
+00:16:21,950 --> 00:16:27,570
+متصل بكم ذرة كلور يعني كام electrode حواليهستة
+
+184
+00:16:27,570 --> 00:16:33,730
+ثلاثة في اتنين وضعوا الطبيعي المتريح تمانية إذا
+
+185
+00:16:33,730 --> 00:16:39,510
+ينقصوا اتنين الآن هدول لما بحطهم مع بعض بيجي هذا
+
+186
+00:16:39,510 --> 00:16:43,570
+على طول بتحد مع هدول بإمكاننا نتخيله بهذا الشكل
+
+187
+00:16:43,570 --> 00:16:48,330
+هاي أخد CL مع إلكتروناتها عشان يصير FECL4 صار
+
+188
+00:16:48,330 --> 00:16:56,800
+تمانية شو ضال عندى؟ CL مجبة تتفاعلفلابد لإتمام هذا
+
+189
+00:16:56,800 --> 00:17:00,840
+التفاعل أنه لو أنا بدي أتمم الهالوجيناشن، إيش ال
+
+190
+00:17:00,840 --> 00:17:07,020
+agent اللي بدي أحطه؟ الـCl2 و الـFeCl3 ماحدش يجي
+
+191
+00:17:07,020 --> 00:17:13,560
+يقوله بحط الـCl2 لحاله، بتفعلشواضح؟ ما حد يقول بده
+
+192
+00:17:13,560 --> 00:17:21,180
+أحط Cl2 لحانه، بتفعلش اللي بده يتفعل Cl2 مع FeCl3
+
+193
+00:17:21,180 --> 00:17:27,380
+لاحظوا، ثانية بس، بده أذكر شغلة أنه أنا لما أخدت
+
+194
+00:17:27,380 --> 00:17:30,740
+ال chlorination في ال اليفاتيك كومباونز زي ما كنت
+
+195
+00:17:30,740 --> 00:17:36,220
+أقول مثلا ميثين زائد هالوجين كنت أفعل إيش؟ Cl2 في
+
+196
+00:17:36,220 --> 00:17:43,330
+وجود الضوء أو الحرارةهذا التفاعل مختلف، يتفاعل على
+
+197
+00:17:43,330 --> 00:17:48,670
+الـ aliphatic carbon لما كنا نقول مثان CH4 و بعدين
+
+198
+00:17:48,670 --> 00:17:54,410
+Cl2 في وجود الضوء اللي بنعبر عليه frequency يعني
+
+199
+00:17:54,410 --> 00:18:00,030
+اللي هو تعبير عن الضوء، plant constant في التردد،
+
+200
+00:18:00,030 --> 00:18:04,110
+هذا طاقة الضوء أو heatمش هيك احنا عملنا ال
+
+201
+00:18:04,110 --> 00:18:09,390
+chlorineation Cl2 في وجود كذا كذا اه بيعطيني CH3Cl
+
+202
+00:18:09,390 --> 00:18:13,050
+هذا ابدال على ال aliphatic compounds لان لو هذا
+
+203
+00:18:13,050 --> 00:18:20,250
+الكلام اجيت اعمله على aromatic compound على بنزينة
+
+204
+00:18:20,250 --> 00:18:23,270
+مافيش
+
+205
+00:18:23,270 --> 00:18:29,300
+reactionإذا بدى أنتبه للشروط الشروط لما كنت بفعل
+
+206
+00:18:29,300 --> 00:18:32,980
+على الميثيل والإيثيل وكذا كنت بدي CL2 في وجود ضوء
+
+207
+00:18:32,980 --> 00:18:37,500
+أو حرارة لما بفعل على البنزين بدي CL2 في وجود ثم
+
+208
+00:18:37,500 --> 00:18:46,990
+فى CL3 الآن بيصير عندنا سؤال للأذكية أحيانابهذا
+
+209
+00:18:46,990 --> 00:18:52,070
+الشكل انه انا لو جبت المركب نفسه لو جبت المركب
+
+210
+00:18:52,070 --> 00:18:57,110
+نفسه و حطيت عليه جزء aromatic يعني ممكن يعمل ادالة
+
+211
+00:18:57,110 --> 00:19:03,530
+على الحلقة و كتبت هنا CH2 CH3 و بدى اعمله
+
+212
+00:19:03,530 --> 00:19:11,190
+halogenation اه بيصير اذا قلتلكم فعلوا مع CL2 في
+
+213
+00:19:11,190 --> 00:19:15,500
+وجود FECL3 اذا بتكون حطوا CL على الحلقةوإذا
+
+214
+00:19:15,500 --> 00:19:20,560
+قلتلكوا فعلوه مع CL2 في وجود الضوء أو الحرارة
+
+215
+00:19:20,560 --> 00:19:26,480
+بتحطوا CL2 وين؟ هنا، الآن هذه أو هذه كام ناتج ممكن
+
+216
+00:19:26,480 --> 00:19:31,320
+نعمل؟ اتنين، واضح؟ يعني هذا لما نيجي نقولكوا أكمل
+
+217
+00:19:31,320 --> 00:19:38,220
+المعادلة ونحط CL2 H frequency أو heat شو الناتج
+
+218
+00:19:38,220 --> 00:19:42,440
+اللي بدكم تكتبوه؟ نفس هذا إما تحطوا CL على هذه
+
+219
+00:19:42,440 --> 00:19:43,980
+الكربون أو على هذه
+
+220
+00:19:47,550 --> 00:19:55,570
+واضح؟ لكن لو كان الكلام CL2 مع FECL3 بدنا نحطه على
+
+221
+00:19:55,570 --> 00:19:58,950
+الحلقة و بعد شوية بيصير طبعا على أي موقع بدنا نحطه
+
+222
+00:19:58,950 --> 00:20:02,050
+على الحلقة بنتعلمه ان شاء الله اليوم المهم ان
+
+223
+00:20:02,050 --> 00:20:07,090
+التفاعل وين بيتم؟ على ال ring نتعلمه على ال ring
+
+224
+00:20:07,090 --> 00:20:16,120
+وضحت هذه الفكرة ال Rبنفس المنطق لما انا بدى اعمل
+
+225
+00:20:16,120 --> 00:20:25,300
+نيتريشن ال N O 2 برضه بالباعش لكن ممكن ان نعمل N O
+
+226
+00:20:25,300 --> 00:20:30,000
+2 من خلال انه بنضيف H N O 3 حمض النيتريك مع H 2 S
+
+227
+00:20:30,000 --> 00:20:35,900
+O 4 بدون تفاصيل هدول الاتنين بتطلعولي ايش N O 2
+
+228
+00:20:35,900 --> 00:20:42,680
+Plus بتتفاعل محل ايش ال H Plusكذلك مثلا في ال
+
+229
+00:20:42,680 --> 00:20:50,820
+cellfonation بحط ال reagent اللي عندى SO3 مع H2SO4
+
+230
+00:20:50,820 --> 00:20:57,990
+هدولة ايش بيطلعولي HSO3 plusيعني بعمل generation
+
+231
+00:20:57,990 --> 00:21:01,850
+توليد لجزء الموجب اللي بده يتفاعل في ال alkylation
+
+232
+00:21:01,850 --> 00:21:09,370
+لما بحط R من وين بده اجيب R ايضا بحط RCl مثلا مع
+
+233
+00:21:09,370 --> 00:21:18,470
+FeCl3 واضحة الفكرة؟ هدول ايش بيعطوا مع بعض؟R plus
+
+234
+00:21:18,470 --> 00:21:23,410
+هدولة مع بعض بيعطوا R plus طبعا بالظبط محل ما
+
+235
+00:21:23,410 --> 00:21:29,310
+بتكون ال R مشبوكة بالهالوجين محل ما بتكون تشبكها
+
+236
+00:21:29,310 --> 00:21:34,010
+بالبنزين خليني اوضحلكوا هذا الكلام يعني لو
+
+237
+00:21:34,010 --> 00:21:38,550
+افترضتوا ان عندكم بنزين بهذا الشكل و اجيت و قلت
+
+238
+00:21:38,550 --> 00:21:49,940
+لكم زائد Hyana CL و FE Cl3و اكتبوا الناتج الان هذه
+
+239
+00:21:49,940 --> 00:21:57,200
+مجموعة R CL مع في CL3 لما بدي اكتب هذه المجموعة
+
+240
+00:21:57,200 --> 00:22:04,700
+كام carbon؟ تلاتة من وين بدي اشبكها؟ محل ما هي
+
+241
+00:22:04,700 --> 00:22:09,020
+شابكة مع ال CL ماعيش اشبكها من هنا او من هنا عشان
+
+242
+00:22:09,020 --> 00:22:16,850
+هيك الناتج هنامحل ما كانت المجموعة متصلة هنا مع ال
+
+243
+00:22:16,850 --> 00:22:23,270
+CL محل ما بدى اشبكها في مثل ما ال CL خلاص طلعت مع
+
+244
+00:22:23,270 --> 00:22:29,050
+ال FECL3 ال CL السالبة زى ما قبل شوية عملنا انا
+
+245
+00:22:29,050 --> 00:22:33,590
+باخد بس ال R واضح انا باخد ال R
+
+246
+00:22:36,500 --> 00:22:43,020
+بعد هيك بتعود ال CL تفلت من ال FECL3 لكن طلع هنا H
+
+247
+00:22:43,020 --> 00:22:47,740
+موجب، شيلنا H موجب؟ ال H الموجب اللي طلعت مع ال CL
+
+248
+00:22:47,740 --> 00:22:53,780
+السالب اللي هنا شو هيعطينا؟ HCL و ال FECL3 هيرجع
+
+249
+00:22:53,780 --> 00:22:58,460
+زي ما هو، هي معنى catalyst واضح؟
+
+250
+00:23:01,810 --> 00:23:06,650
+و كذلك الحال في عملية ال acetylation او ال
+
+251
+00:23:06,650 --> 00:23:13,510
+acetylation بدي استعمل R C double bond O Cl برضه
+
+252
+00:23:13,510 --> 00:23:17,930
+مع Fe Cl3 او Aluminium Cl3 نفس الفكرة الان هذا
+
+253
+00:23:17,930 --> 00:23:23,070
+بياخد ال Cl هيك بهذا الشكل ايش ضال عندى؟ R C
+
+254
+00:23:23,070 --> 00:23:28,310
+double bond O بتشبك من وين؟ من عند الكربون هذه
+
+255
+00:23:28,310 --> 00:23:34,170
+بتعطينا ال acetyl groupواضح؟ فالخلاصة أنه احنا
+
+256
+00:23:34,170 --> 00:23:39,330
+الأشياء الموجبة اللي بنفعلها تولد أثناء التفاعل
+
+257
+00:23:39,330 --> 00:23:43,210
+يعني مابيشتريش الواحد هذه ال reagents الموجبة عادة
+
+258
+00:23:43,210 --> 00:23:47,930
+بيخلق مادتين المادتين بيطلعوا الموجب هم لاحظين هنا
+
+259
+00:23:47,930 --> 00:23:53,640
+حطينا مادتينفي كل منطقة احنا بنخلط مادة اللى بتطلع
+
+260
+00:23:53,640 --> 00:23:57,440
+الشغل الموجبة اللى بتحل محل الهيدروجين الموجب هك
+
+261
+00:23:57,440 --> 00:24:01,320
+بتم ال electrophilic aromatic substitution
+
+262
+00:24:04,770 --> 00:24:09,750
+بصير سهل علينا الآن ان نكمل التفاعل يعني لو قلنا
+
+263
+00:24:09,750 --> 00:24:13,590
+لكوا اكمل المعادلة هاي هنا اللى بده تطلع ال CL
+
+264
+00:24:13,590 --> 00:24:17,850
+وهذه بده تضيف من هذه النقطة هنا هدولة التانية ايش
+
+265
+00:24:17,850 --> 00:24:24,570
+بيحطوا ن او اتو هدولة بتفعل هذا يمكن البعضأقول طب
+
+266
+00:24:24,570 --> 00:24:28,510
+ليش حطينا المجموعة هان؟ تنسوش أن الست مجموعات في
+
+267
+00:24:28,510 --> 00:24:32,810
+البنزين متكافئة يعني لما نقول هان أكمل المعادلة لو
+
+268
+00:24:32,810 --> 00:24:35,570
+واحدة كتبت الجواب هان والتاني هان والتالتة هان
+
+269
+00:24:35,570 --> 00:24:38,210
+والرابعة هان والخمسة هان والثالثة هان كله صح
+
+270
+00:24:38,210 --> 00:24:44,250
+الهيدروجينات الستة في البنزين متكافئة ولذلك بأي
+
+271
+00:24:44,250 --> 00:24:49,310
+نقطة حطوا الجواب يعني هذا اسمه أسيتوفينون طب لو
+
+272
+00:24:49,310 --> 00:24:56,080
+ارتسم هان أهانواضح؟ او لو افترضنا كان كلورو بنزين،
+
+273
+00:24:56,080 --> 00:25:02,740
+كلورو بنزين، واضح؟ فلو سألناكم the six hydrogens
+
+274
+00:25:02,740 --> 00:25:08,580
+of benzene are equivalent واضح الفكرة؟ وين ما بدكم
+
+275
+00:25:08,580 --> 00:25:13,980
+حطوا المجموعة، نفس الشيء تماما، نفس الشيء تماما
+
+276
+00:25:13,980 --> 00:25:18,480
+هذا الكلام الآن وين موجود اللي هو نظام ال
+
+277
+00:25:18,480 --> 00:25:24,850
+equivalent في البنزين؟البنزين ماعلهوش ولا إبدال
+
+278
+00:25:24,850 --> 00:25:29,810
+حطيت الإبدال الأول طيب لما الأن ننتقل للنقطة الأهم
+
+279
+00:25:29,810 --> 00:25:33,830
+في موضوعنا طب لو يا تورا جيبت substituted بنزين
+
+280
+00:25:33,830 --> 00:25:40,310
+عليه إبدال واحد أصلا يعني مثلا جيبنا هذا المركب
+
+281
+00:25:40,310 --> 00:25:44,270
+الطلوين و بدنا نعمل عليه تفاعل chlorineation أو
+
+282
+00:25:44,270 --> 00:25:50,740
+nitration أو أي تفاعلوين بدنا نحطهم؟ بيصير السؤال
+
+283
+00:25:50,740 --> 00:25:55,720
+يا ترى على الحلقة كم هيدروجينة موجود على الحلقة؟
+
+284
+00:25:55,720 --> 00:26:00,440
+خمسة، واحد، اتنين، تلاتة، اربعة، خمسة، اللي على
+
+285
+00:26:00,440 --> 00:26:05,200
+الحلقة كم نوع الهيدروجينات اللي على الحلقة؟ تلاتة،
+
+286
+00:26:05,200 --> 00:26:07,380
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+287
+00:26:07,380 --> 00:26:09,720
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+288
+00:26:09,720 --> 00:26:11,280
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+289
+00:26:11,280 --> 00:26:20,240
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتو هذه نوع تالت إذا
+
+290
+00:26:20,240 --> 00:26:23,600
+هذولة تلت أنواع طبعا لو أنا كنت بسأل كام نوع
+
+291
+00:26:23,600 --> 00:26:26,500
+الهيدروجين اللي على الحلقة هتقوللي تلاتة اللي في
+
+292
+00:26:26,500 --> 00:26:31,500
+الجزيب المجمل أربعة هذا نوع رابع الآن لما أنا بعمل
+
+293
+00:26:31,500 --> 00:26:36,220
+التفاعلات ال aromatic ماليش بهذا اللي هان و هان و
+
+294
+00:26:36,220 --> 00:26:41,450
+هانطيب لو اعملت تفاعل نفترض ال chlorineation بيصير
+
+295
+00:26:41,450 --> 00:26:44,930
+السؤال اللى عندى وين بده احط ال chlorine على هذا
+
+296
+00:26:44,930 --> 00:26:48,270
+الموقع طبعا زى هذا او على هذا زى هذا او على هذا
+
+297
+00:26:48,270 --> 00:26:52,270
+كام احتمال بيصير عندى تلاتة لاحظوا الاحتمال الاول
+
+298
+00:26:52,270 --> 00:26:57,330
+لانه مباشر بنسميه Ortho واللي بعده Meta واللي بعده
+
+299
+00:26:57,330 --> 00:27:04,180
+Para كلام منطقي ولا .. و هذا ايضا و هذا Metaالان
+
+300
+00:27:04,180 --> 00:27:10,600
+المجموعة اللي صارت موجودة بتصير تتحكم هي بالتفاعل
+
+301
+00:27:10,600 --> 00:27:14,640
+مش المجموعة اللي بتيجي من برا اللي بتتحكم بالتفاعل
+
+302
+00:27:14,640 --> 00:27:19,340
+اليوم يوم ما بيجي ضيف عليكم مين اللي بتحكم وبيقول
+
+303
+00:27:19,340 --> 00:27:26,200
+للضيف اتفضل هان و هان صاحب البيت ولا الضيف صاحب
+
+304
+00:27:26,200 --> 00:27:30,220
+البيته عشان ذلك احنا المثل اللي عندنا بنقول الضيف
+
+305
+00:27:30,220 --> 00:27:36,730
+ايش؟أسير لمحلة، يعني زي ما بيقولوا إذا كان مثلا
+
+306
+00:27:36,730 --> 00:27:39,810
+هذا الضيف إنسان غريب شوية، ممكن تقولوله اتفضل على
+
+307
+00:27:39,810 --> 00:27:43,330
+غرفة الضيوف، إذا افترضنا نظيف خالكم، بتقولوله
+
+308
+00:27:43,330 --> 00:27:45,850
+اتفضل على الصالون، إذا مين اللي اتحكم وين يجيب
+
+309
+00:27:45,850 --> 00:27:52,070
+الضيف؟ صاحب البيت، الآن مين صاحب البيت هنا؟ هذه
+
+310
+00:27:52,070 --> 00:27:57,140
+المجموعةواضح؟ ولذلك هذه المجموعة اللي هنا إلها
+
+311
+00:27:57,140 --> 00:28:01,180
+تأثيرين التأثير الأول أنها تؤثر على التفاعل من
+
+312
+00:28:01,180 --> 00:28:05,260
+ناحية السرعة يعني بعض المجموعات بتزيد سرعة
+
+313
+00:28:05,260 --> 00:28:08,280
+التفاعلات وبعضها بتنقص هذا ال effect بنسميه
+
+314
+00:28:08,280 --> 00:28:14,060
+reactivity effect يعني لها تأثير بالسرعة زيادة أو
+
+315
+00:28:14,060 --> 00:28:18,160
+انقاصةهذا التأثير الأول ال reactivity effect
+
+316
+00:28:18,160 --> 00:28:23,500
+التأثير التاني بنسميه orientation effect لها تأثير
+
+317
+00:28:23,500 --> 00:28:27,280
+على أي موقع orientation موقع على أي موقع تقول
+
+318
+00:28:27,280 --> 00:28:30,440
+للمجموعة اللي جاي اتفضلي انت هان اتفضلي هان اتفضلي
+
+319
+00:28:30,440 --> 00:28:35,110
+هان من اللي بيقول اللي جاي ولا اللي موجودالموجود
+
+320
+00:28:35,110 --> 00:28:39,430
+ولذلك إلى التأثير التاني ال orientation أو بنسميه
+
+321
+00:28:39,430 --> 00:28:41,890
+مرات regiochemistry عارفين إيش يعني
+
+322
+00:28:41,890 --> 00:28:46,670
+regiochemistry؟ region موقع يعني أنها تحدد إلى أي
+
+323
+00:28:46,670 --> 00:28:49,990
+موقع تذهب المجموعة الجديدة هي معناه regiochemistry
+
+324
+00:28:50,830 --> 00:28:55,890
+الان المجموعات تصنف إلى نوعين في مجموعات منشطة
+
+325
+00:28:55,890 --> 00:29:00,030
+تزيد سرعة التفاعل بنسميها activating groups وفي
+
+326
+00:29:00,030 --> 00:29:05,150
+مجموعات مثبتة بنسميها ايش deactivating groups وهذه
+
+327
+00:29:05,150 --> 00:29:12,200
+بدنا نتعلمها الان المجموعات المنشطةأشهرها وأعلاها
+
+328
+00:29:12,200 --> 00:29:16,580
+زي ما هي مرتبة هنا في زيادة التنشيط ال H2 اللي في
+
+329
+00:29:16,580 --> 00:29:21,020
+الانالين بعدين ال OH بعدين ال OCH3 بعدين ال CH3 و
+
+330
+00:29:21,020 --> 00:29:24,600
+ال Alkyl هدولة سهلة اللي بنقدر نحفظهم هدولة
+
+331
+00:29:24,600 --> 00:29:30,440
+بنسميهم مجموعات إيش منشطة المجموعات المثبتة بتبدأ
+
+332
+00:29:30,440 --> 00:29:33,520
+من هذا الخط لاحظوا هذا الخط الهيدروجيني عن البنزين
+
+333
+00:29:33,520 --> 00:29:42,690
+اللي أعلى منهمنشط والأقل منه مثبت activating و
+
+334
+00:29:42,690 --> 00:29:46,290
+deactivating كل ما طلعت لفوق بزيد التنشيط كل ما
+
+335
+00:29:46,290 --> 00:29:51,350
+نزلت لتحت بزيد ال ash التفبيط ولذلك ال halogens
+
+336
+00:29:51,350 --> 00:29:56,670
+are deactivating ال nitro deactivating السيانو
+
+337
+00:29:56,670 --> 00:30:00,670
+deactivating الحامض deactivating يعني أن التفاعل
+
+338
+00:30:00,670 --> 00:30:06,120
+هيكون أقل من تفاعل ال ashالبنزين لوحده اللى لو
+
+339
+00:30:06,120 --> 00:30:10,220
+كانت هذه الار اتش المعنى انه لما بنحط هنا اللى
+
+340
+00:30:10,220 --> 00:30:13,620
+الار اتش اللى هي نقطة المرجع لو هذه اتش كان صرت
+
+341
+00:30:13,620 --> 00:30:18,620
+انا ايش البنزين فاللي فوق منها اسرع من البنزين
+
+342
+00:30:18,620 --> 00:30:23,940
+اللى تحتأبطأ من البنزين هذا بالنسبة للسرعة الآن
+
+343
+00:30:23,940 --> 00:30:27,080
+السرعة مش كتير بتفرج معاكم عارفين ليش؟ لأنه مش
+
+344
+00:30:27,080 --> 00:30:30,240
+كتير بنيجي نسألكوا مين أسرع ومين أبطأ لكن لما
+
+345
+00:30:30,240 --> 00:30:36,220
+نقولكوا أكمل المعادلة بيفرج معاكم على أي جهة تحطوا
+
+346
+00:30:36,220 --> 00:30:42,120
+ناتج ال orientation عندنا قاعدة بسيطة لل
+
+347
+00:30:42,120 --> 00:30:49,180
+orientation بشكل عام المجموعات المنشطةمضاف إليها
+
+348
+00:30:49,180 --> 00:30:52,920
+الهالوجينات يعني بيبقى الخط من عند هنا هذه بتودع
+
+349
+00:30:52,920 --> 00:30:57,440
+على موقع Orthopara والمجموعات ال .. ال
+
+350
+00:30:57,440 --> 00:31:02,320
+deactivating بتودع موقع Meta يعني لو كنت أنا بفعل
+
+351
+00:31:02,320 --> 00:31:08,980
+مثلا مع Toluene وبفعله مع CL2 وين هي يجي الناتج؟
+
+352
+00:31:08,980 --> 00:31:15,420
+CL2 في وجود FECL3 على Orthopara الآن بحطش على نفس
+
+353
+00:31:15,420 --> 00:31:20,510
+الجزء Orthopara لأ بكتب ناتجينيعني مثل وعلى
+
+354
+00:31:20,510 --> 00:31:25,930
+Orthochlor و مثل وعلى Barachlor واضح؟ خليط من
+
+355
+00:31:25,930 --> 00:31:32,750
+ناتجين الاحتمالين لما بنفعل مع المجموعات اللي فوق
+
+356
+00:31:32,750 --> 00:31:37,270
+الخط اللي موجود عندنا الناتج خليط من المركبين ال
+
+357
+00:31:37,270 --> 00:31:43,770
+Ortho والBara الآن انتبهوا معي لخطأ شائع دائما
+
+358
+00:31:43,770 --> 00:31:49,590
+بيعملوه الطلاب رغم انه انا حكيت عليهأكام مرة؟ ألف
+
+359
+00:31:49,590 --> 00:31:54,370
+مرة اليوم ورغم هيك من خبرتنا تلاتين في المية من
+
+360
+00:31:54,370 --> 00:31:57,590
+الطلاب بيعملوا هذا الخطأ لاحظوا ال Nitro مجموعة
+
+361
+00:31:57,590 --> 00:32:04,990
+ايش؟ مثبتة وين بتودي؟ على ميتا اه الان طب شو هو
+
+362
+00:32:04,990 --> 00:32:08,710
+الخطأ اللي بيعمله الطلاب و مش عمال ابطله عنه ع مدى
+
+363
+00:32:08,710 --> 00:32:15,890
+السنين لما اجي اقول اكمل المعادلة وين
+
+364
+00:32:15,890 --> 00:32:17,070
+بده احط الجواب؟
+
+365
+00:32:20,310 --> 00:32:27,470
+الحمد لله انه كغلطه لاحظوا معاك انا قلتلكوا اللي
+
+366
+00:32:27,470 --> 00:32:34,050
+بتحكم اللي هنا ع طول راح مخته هنا هذه لو هي موجودة
+
+367
+00:32:34,050 --> 00:32:37,630
+هنا بتودي ع ميتا اللي بتحكم في التفاعل المجموعة
+
+368
+00:32:37,630 --> 00:32:42,650
+الموجودة كم مرة حكيتها؟هذه الموجودة وين بتودّي
+
+369
+00:32:42,650 --> 00:32:47,790
+اللي جاي؟ وعشان هيك المفروض أنه قبل ما أكتب ماعيش
+
+370
+00:32:47,790 --> 00:32:52,230
+بتفعل، لو كتبت بس هيك و لسه قاعد بكمل، لسه ماكتبتش
+
+371
+00:32:52,230 --> 00:32:55,950
+ماعيش بده يتفعل، أنتوا تكونوا جاهزة الجواب، هذا
+
+372
+00:32:55,950 --> 00:33:01,590
+وين بده يودّي؟على اورثو بارا سواء اتفاعل مع مثليشن
+
+373
+00:33:01,590 --> 00:33:05,510
+تاني مع اتش مع floor مع halogen اللي بتحكم
+
+374
+00:33:05,510 --> 00:33:10,370
+بالتفاعل هذا ولذلك لما هنا بدي اكتب HNO3 H2SO4
+
+375
+00:33:10,370 --> 00:33:16,150
+اللي بتحكم الأصلي الناتج هتكتبوه بهذا الشكل CH3 و
+
+376
+00:33:16,150 --> 00:33:24,150
+تحطوا هنا NO2 زائد هي على اورثو CH3 و تحطوا هنا
+
+377
+00:33:24,150 --> 00:33:26,970
+NO2 خليط
+
+378
+00:33:28,710 --> 00:33:33,650
+تكتبوا الاحتمالين لو انا كنت بادي مثلا بنايترو
+
+379
+00:33:33,650 --> 00:33:40,370
+بنزين وجهته بده يودي على ويت على ميته فهي المرة
+
+380
+00:33:40,370 --> 00:33:45,890
+العشرين اللي بتحكم بالتفاعل من؟ الموجودة أصلا وليس
+
+381
+00:33:45,890 --> 00:33:51,990
+الطريقة وكلام بتهيألي منطق مافيه ولا مشكلة واضحة
+
+382
+00:33:51,990 --> 00:33:57,730
+الأفكار؟ يكاد يكون معظم الأشياء اللي ضايلة عندنا
+
+383
+00:33:58,480 --> 00:34:05,680
+أشياء تطبيقية على هذه الفكرة خلّينا نشوف هاي هذا
+
+384
+00:34:05,680 --> 00:34:10,580
+الكلام بيجيب للي بيودوا Orthobara لحد ال halogens
+
+385
+00:34:10,580 --> 00:34:15,680
+لاحظوا ان ال halogens لو أنا بدى أصنفهم شو بدى
+
+386
+00:34:15,680 --> 00:34:20,620
+أقول عنهم من ناحية تأثيرهم activating ولا
+
+387
+00:34:20,620 --> 00:34:24,120
+deactivating دي activating لكن من ناحية التوجيه
+
+388
+00:34:26,320 --> 00:34:35,220
+الهالوجين دي اكتفت الهالوجين
+
+389
+00:34:35,220 --> 00:34:39,920
+دي اكتفت الهالوجين دي اكتفت الهالوجين دي اكتفت
+
+390
+00:34:39,920 --> 00:34:44,380
+الهالوجين دي اكتفت الهالوجين دي اكتفت الهالوجين دي
+
+391
+00:34:44,380 --> 00:34:48,040
+اكتفت الهالوجين دي اكتفت الهالوجين دي اكتفت
+
+392
+00:34:48,040 --> 00:34:48,980
+الهالوجين دي اكتفت الهالوجين دي اكتفت الهالوجين دي
+
+393
+00:34:48,980 --> 00:34:50,920
+اكتفت الهالوجين دي اكتفت الهالوجين دي اكتفت
+
+394
+00:34:50,920 --> 00:34:53,700
+الهالوجين دي اكتفت الهالوجين دي اكتفت الهالوجين دي
+
+395
+00:34:53,700 --> 00:34:54,390
+اكتفت الهالوجين دي اكتفت الهالوجين دي اواضحة
+
+396
+00:34:54,390 --> 00:35:02,190
+الفكرة؟ الهيدروجين بنزين خلاص نقطة التعادل، واضح؟
+
+397
+00:35:02,190 --> 00:35:06,010
+ترجع بنزين و بيبطل فيه أورتو برا برجعله ست مواقع
+
+398
+00:35:06,010 --> 00:35:11,610
+متكافئة، واضح؟ الهيدروجين خلاص رجعه ست مواقع
+
+399
+00:35:11,610 --> 00:35:13,050
+متكافئة، بنزين
+
+400
+00:35:22,700 --> 00:35:26,600
+الان لاحظوا على أرض الواقع هاي أمثلة تطبيقية ..
+
+401
+00:35:26,600 --> 00:35:31,560
+هاي أمثلة تطبيقية .. هاي طلوين بتعمله نيترشل .. شو
+
+402
+00:35:31,560 --> 00:35:36,720
+النواتج اللي بتطلع .. هاي ال ortho .. جداش نسبته
+
+403
+00:35:36,720 --> 00:35:40,740
+.. تلاتة و ستين في المية .. هاي ال bara جداش نسبته
+
+404
+00:35:40,740 --> 00:35:44,380
+.. أربعة و تلاتين ..الان ال meet هذا طلع شوية
+
+405
+00:35:44,380 --> 00:35:49,840
+صغيرة .. تلاتة في المية .. تعتبر عدمهذا منطقي في
+
+406
+00:35:49,840 --> 00:35:54,420
+الدنيا بالمناسبة يعني احنا على سبيل المثال بنقول
+
+407
+00:35:54,420 --> 00:35:58,180
+انه الاصل في المسلمين انهم بيقتلوش و بيؤذوش الناس
+
+408
+00:35:58,180 --> 00:36:01,420
+لكن مالنجلناش اتنين تلاتة بيقتلوا و بيؤذوا الناس؟
+
+409
+00:36:03,080 --> 00:36:08,200
+فمعنى ان انا بقول اورثوبارا اورثوبارا ان الناواتج
+
+410
+00:36:08,200 --> 00:36:12,600
+الأساسية اورثوبارا الان بطلعش شوية شدوث بطلع طلع
+
+411
+00:36:12,600 --> 00:36:17,520
+بالنسبة 3% واضح بس احنا في اكمال المعادلات مديش
+
+412
+00:36:17,520 --> 00:36:22,100
+تكتبواها 3% سامحكم هنا احنا بنجيب نتيجة تجربة
+
+413
+00:36:22,100 --> 00:36:25,900
+حقيقية لكن لو اكمل المعادلة بس اللي باجبله منكم
+
+414
+00:36:27,180 --> 00:36:31,160
+لسبب بسيط انه ماعندكوش انتوا الإجابات انتبهوا معي
+
+415
+00:36:31,160 --> 00:36:36,860
+ليش ال ortho يكاد يكون طلع ضعف الفارة؟ في واحدة
+
+416
+00:36:36,860 --> 00:36:42,800
+شاطرة تجاوبنا؟ لأنه في تنتين لأنه في احتمالين
+
+417
+00:36:42,800 --> 00:36:51,520
+البارة واحدة Ortho احتمالين هاي
+
+418
+00:36:51,520 --> 00:36:58,020
+مثال تاني تأكيديالسيانو هذي بتودي على ميتا لاحظوا
+
+419
+00:36:58,020 --> 00:37:02,680
+مركب الميتا جداش طلعت نسبته واحد تمانية في المية
+
+420
+00:37:02,680 --> 00:37:06,020
+هو الأساس الأن بتطلع شوية ارثو وشوية برة لكن
+
+421
+00:37:06,020 --> 00:37:09,780
+بنعتبره نسب قليلة فالجواب اللي بدنا نشوفه حقيقة
+
+422
+00:37:09,780 --> 00:37:17,920
+الميتا و بس واضح؟
+
+423
+00:37:23,280 --> 00:37:29,840
+الان ع السريع و انا بدى اجف هنا اسكر على هدول عشان
+
+424
+00:37:29,840 --> 00:37:33,640
+نأكد انكوا فاهمين الكلام لما نقول هنا بدنا نكمل
+
+425
+00:37:33,640 --> 00:37:37,900
+المعادلة انتوا ع طول بدكوا تجاوب و بدون ما تعرفوا
+
+426
+00:37:37,900 --> 00:37:44,420
+ايش اللي موجود هنا بدكوا تقولوا ارتباط هذي مائة
+
+427
+00:37:44,420 --> 00:37:51,620
+هذي مائة و بعدين كملوا الجواب انتهى واضح الفكرة؟
+
+428
+00:37:56,470 --> 00:38:00,070
+هذا بيحط brom هذا بيحط chlorine و هدول ال reagents
+
+429
+00:38:00,070 --> 00:38:08,810
+مع بعض بيحط يود من
+
+430
+00:38:08,810 --> 00:38:12,730
+الأسئلة المتكررة هنا و دائما يجب أن نسأل عنها
+
+431
+00:38:12,730 --> 00:38:18,150
+الطلاب أنه احنا بنجيب مركب فيه مجمعتين و بنقولكوا
+
+432
+00:38:18,150 --> 00:38:24,570
+يا تورا مبتدئا من البنزين كيف بتحضرولنا هذا المركب
+
+433
+00:38:26,240 --> 00:38:30,800
+انتبهوا معايا هاي مثلا هذا مركب الآن انا بقولكم
+
+434
+00:38:30,800 --> 00:38:35,920
+مبتدئا من البنزين كيف بدكم تحضروا هذا المركب
+
+435
+00:38:35,920 --> 00:38:42,840
+عارفين وين محور السؤال ها؟ محور السؤال ان انا عندي
+
+436
+00:38:42,840 --> 00:38:47,480
+مجموعتين يا تورا بدي اضيف هذه في الأول و بعدها هذه
+
+437
+00:38:47,480 --> 00:38:52,690
+و لا هذه في الأول و بعدها هذهبديش أنسى انا ان
+
+438
+00:38:52,690 --> 00:38:56,090
+المجموعة اللى بضيفها بالأول هي اللى تتحكم بالتفاعل
+
+439
+00:38:56,090 --> 00:38:59,870
+الان لو يا ترى ضيفت الميثل في الأول الميثل وين
+
+440
+00:38:59,870 --> 00:39:03,950
+بتودى ارتوبرا ارتوبرا يعني بتطلعلي هذا الناتج اه
+
+441
+00:39:03,950 --> 00:39:07,090
+طب لو ضيفت هذه في الأول ال acid اللى لو رجعنا
+
+442
+00:39:07,090 --> 00:39:11,830
+بتودى ميتا مش هتطلعلي الناتج ولذلك هذا لما باجي
+
+443
+00:39:11,830 --> 00:39:18,170
+بشتغل الان تنفيذة بقول CH3Cl مع ألمنيوم كلورايد
+
+444
+00:39:18,170 --> 00:39:26,120
+هيحط ايشالـ CH3 بعد هيك باجي بقول CH3C double bond
+
+445
+00:39:26,120 --> 00:39:30,020
+OCL مع الومليوم كلورايت لحظوا ان الكلام بتكون
+
+446
+00:39:30,020 --> 00:39:33,320
+تتدربوا ع كتابته احنا الآن محاضرة بتكون ترجعوا
+
+447
+00:39:33,320 --> 00:39:37,500
+تحضروا التصوير و تتدربوا و تحفظوا بيحط في اي موقع
+
+448
+00:39:37,500 --> 00:39:46,340
+ال Ortho زائد ال Vara احنا اللي مطلوب منها ايش
+
+449
+00:39:47,240 --> 00:39:53,540
+البارة وبنكتب هنا كمان زائد ال orthocompound صح؟
+
+450
+00:39:53,540 --> 00:39:59,240
+بس هو طالب كيف بنحضر ال ortho البارة عفوا الان نفس
+
+451
+00:39:59,240 --> 00:40:11,060
+الأمثلة اللي عندكم سجلتوا؟ يلا سجلوا و
+
+452
+00:40:11,060 --> 00:40:17,360
+بكون سعيد ان انتوا تجاوبوا لو قلنالكواهذا المركب
+
+453
+00:40:17,360 --> 00:40:21,420
+كام مجموعة فيه؟ طب إذا بدأ أبدأ من البنزين هذه وين
+
+454
+00:40:21,420 --> 00:40:26,040
+بتودي؟ يالها أورتوبالا و هذه؟ ميتا العلاقة اللي
+
+455
+00:40:26,040 --> 00:40:31,580
+موجودة إذا المقش اللي لازم أبدأ فيها start by
+
+456
+00:40:31,580 --> 00:40:37,540
+nitration الآن هذه COCH3
+
+457
+00:40:37,540 --> 00:40:44,480
+هذه اللي هي سيضة بالبند OCH3 هي كده ميتا و هذه؟
+
+458
+00:40:48,050 --> 00:40:53,270
+العلاقة الموجودة اذا ايش اللي لازم ابدأ فيه ال
+
+459
+00:40:53,270 --> 00:40:53,730
+isolation
+
+460
+00:40:57,190 --> 00:41:01,690
+ميتا بتودى على ميتا position هذى وين بتودى
+
+461
+00:41:01,690 --> 00:41:06,750
+اورتوبارا اللى موجود عندى اذا ايش اللى لازم ابدأ
+
+462
+00:41:06,750 --> 00:41:10,850
+فيه هذا الكلام طبقه عد انتوا بالإيد واستمتعوا
+
+463
+00:41:10,850 --> 00:41:14,670
+بتطبيقه وأكيد لو دخلتوا على الامتحانات السابقة
+
+464
+00:41:14,670 --> 00:41:19,610
+هتلاقوا في كل امتحان سؤال من هذا النوع انه بنجيب
+
+465
+00:41:19,610 --> 00:41:24,550
+مركب ال two substituents و بنقولكواكيف بتحضر هذا
+
+466
+00:41:24,550 --> 00:41:33,290
+المركب من البنزين عشان نشوف كيف فهمته قصة
+
+467
+00:41:33,290 --> 00:41:39,710
+ال radiochemistry بضل عندى شغلتين صغار بتجيجتين
+
+468
+00:41:39,710 --> 00:41:45,910
+الحمد لله خلصناانه غير البنزين في عندى مراكبات
+
+469
+00:41:45,910 --> 00:41:51,390
+كتير فيها اكثر من حلقة بنزين تمام الان اذا
+
+470
+00:41:51,390 --> 00:41:59,550
+بتلاحظوا انتوا البنزين كان by electron كان فيه ستة
+
+471
+00:41:59,550 --> 00:42:07,140
+ستة بعد البنزين بيجيه من النفثالين جديش فيهأربعة
+
+472
+00:42:07,140 --> 00:42:09,800
+في اتنين اربعة في اتنين اربعة في اتنين اربعة في
+
+473
+00:42:09,800 --> 00:42:14,520
+اتنين اربعة
+
+474
+00:42:14,520 --> 00:42:18,000
+في اتنين اربعة في اتنين اربعة في اتنين اربعة في
+
+475
+00:42:18,000 --> 00:42:23,380
+اتنين اربعة في اتنين اربعة
+
+476
+00:42:23,380 --> 00:42:27,760
+في اتنين
+
+477
+00:42:27,760 --> 00:42:29,820
+اربعة في اتنين اربعة في اتنين اربعة في اتنين اربعة
+
+478
+00:42:29,820 --> 00:42:31,820
+في اتنين اربعة في اتنين اربعة في اتنين اربعة في
+
+479
+00:42:31,820 --> 00:42:32,120
+اتنين اربعة في اتنين اربعة في اتنين اربعة في اتنين
+
+480
+00:42:32,120 --> 00:42:33,280
+اربعة في اتنين اربعة في اتنين اربعة في اتنين اربعة
+
+481
+00:42:33,280 --> 00:42:34,400
+في اتنين اربعة في اتنين اربعة في اتنين اربعة في
+
+482
+00:42:34,400 --> 00:42:40,330
+اتنين اربعة في اتنينعشرين زاد اتنين اتنين و عشرين
+
+483
+00:42:40,330 --> 00:42:44,590
+الان عدد ال by electrons لازم يكون زي هيك اذا كان
+
+484
+00:42:44,590 --> 00:42:50,100
+زي هيك بيكون المركب اللي عندى ايش aromaticيعني
+
+485
+00:42:50,100 --> 00:42:52,880
+المركب عشان يكون aromatic بدوا يكون فيه by
+
+486
+00:42:52,880 --> 00:42:57,940
+electrons يا 6 يا 10 يا 14 يا 18 يا 22 لاحظوا هنا
+
+487
+00:42:57,940 --> 00:43:04,400
+قداش عددهم بالنفثالين عشرة هنا 2 4 6 8 10 12 14
+
+488
+00:43:04,400 --> 00:43:09,520
+تلت حلقات بيصير اسمهم أنثراسين أو فنانثرين بهذا
+
+489
+00:43:09,520 --> 00:43:15,660
+الشكل الآن بعد هيك هذا المركب هذا المركب هي فيه ال
+
+490
+00:43:15,660 --> 00:43:20,480
+بيرين مع بنزينة عشان هيك إيش بيسموهبنزو ايه
+
+491
+00:43:20,480 --> 00:43:24,620
+بايرين؟ يعني هو damage من البنزين مع ال بايرين
+
+492
+00:43:24,620 --> 00:43:29,740
+فإيش سمناه؟ بنزو بايرين هذا المركب اللي موجود في
+
+493
+00:43:29,740 --> 00:43:36,560
+السجائر وبيسبب السرطان وموجود في الحرق، بيطلع من
+
+494
+00:43:36,560 --> 00:43:43,380
+الحرق سواء حرجنا كاكاو، بخور، سجائر، تبغ، شيشة،
+
+495
+00:43:43,380 --> 00:43:49,600
+معسلكل الحرق هذا دايما بيطلع ال بنزو A بايرين اللي
+
+496
+00:43:49,600 --> 00:43:53,720
+هو ال carcinogenic compound كل الحرق اللي هنا
+
+497
+00:43:53,720 --> 00:43:59,480
+بيطلع بنزو A بايرين اللي هو ايش؟ carcinogenic
+
+498
+00:43:59,480 --> 00:44:05,560
+compound مركب مسرطن حتى .. انتبهوا معي البخور مش
+
+499
+00:44:05,560 --> 00:44:10,880
+كتير تولعوه في الدور نفس الاشي بيطلع ال بنزو A
+
+500
+00:44:10,880 --> 00:44:15,630
+بايرينالكاكاو إذا الحرج كتير في الكيك أو ما إلى
+
+501
+00:44:15,630 --> 00:44:18,810
+ذلك كل المنطقة المحروجة بصير فيها بنزو اي بايرين
+
+502
+00:44:18,810 --> 00:44:23,010
+ماتاكلوش الاشي المحروج واضح؟ بيكون فيه ال بنزو اي
+
+503
+00:44:23,010 --> 00:44:30,030
+بايرين المركب الكارسينوجينب الخشب
+
+504
+00:44:30,030 --> 00:44:33,150
+بيطلع ثانو أكسيد كربونه أول أكسيد كربونه بيخنج
+
+505
+00:44:33,150 --> 00:44:43,110
+الناس اخر شغلة عشان أخلصهي عبارة عن اكتشاف حديث
+
+506
+00:44:43,110 --> 00:44:47,130
+يمكن لما حكيت عن الالوتروبز حكيت لكم ياه كرة
+
+507
+00:44:47,130 --> 00:44:51,050
+الكربون ستين كلكم بتعرفوا الكربون في الطبيعة موجود
+
+508
+00:44:51,050 --> 00:44:57,060
+على أي أشكالGraphite و Diamonds الآن بال ألف و
+
+509
+00:44:57,060 --> 00:45:01,540
+تسعمية و ثمانية و بعد لقوا صورة جديدة من ستين ذرة
+
+510
+00:45:01,540 --> 00:45:08,300
+كربون هذه الصورة سموها carbon sixty لأن هدولة
+
+511
+00:45:08,300 --> 00:45:14,930
+النقاط كم ذرةواللي حدد او ساعد تحديدها انسان اسمه
+
+512
+00:45:14,930 --> 00:45:17,630
+book monster fullero عشان هيك سماوه fullerine
+
+513
+00:45:17,630 --> 00:45:21,370
+الناس اللي اكتشفوا هذا الكلام اخدوا عليه جائزة
+
+514
+00:45:21,370 --> 00:45:24,490
+نوبل في الكيميا اخدوا عليه جائزة نوبل في الكيميا
+
+515
+00:45:24,490 --> 00:45:30,680
+بحدود 95 مش زمانواضح؟ اللي هو الفوليرين إيش اللي
+
+516
+00:45:30,680 --> 00:45:36,160
+قالوا؟ قالوا 60 ذرة موجودين على سطح كرة و الكرة
+
+517
+00:45:36,160 --> 00:45:43,280
+عبارة عن أشكال سداسية و خماسية 32 وجه ال 32 منهم
+
+518
+00:45:43,280 --> 00:45:49,900
+أظن 20 سداسي و 12 خماسي لو روحتوا أنتوا على البيت
+
+519
+00:45:49,900 --> 00:45:54,520
+و شوفتوا أي كرة موجودة عديتوا الوجوه اللي موجودة
+
+520
+00:45:54,520 --> 00:46:00,220
+عليها كتبتوا 1,2,3,4 هتلاقوهم كام وجه؟32 لو عديته
+
+521
+00:46:00,220 --> 00:46:03,800
+النقاط اللي هذا اللي تمثل ال carbon هتلاقوهم كام
+
+522
+00:46:03,800 --> 00:46:08,240
+نقطة؟ 60 نقطة ولذلك سمو هذا كرة الكربون وقيلها
+
+523
+00:46:08,240 --> 00:46:14,600
+تطبيقات كتيرة في الحياة هي أساسا بتشبه المراكبات
+
+524
+00:46:14,600 --> 00:46:19,170
+ال aromatic لكن علم خاص مش موضوعنا أنهاانه الآن
+
+525
+00:46:19,170 --> 00:46:23,150
+نحكي فيه اللي جابها اللي فيها الحلقات السداسية
+
+526
+00:46:23,150 --> 00:46:29,010
+اللي فيها الحلقات السداسية واكتشاف يعني جديد ويله
+
+527
+00:46:29,010 --> 00:46:33,830
+كثير من التطبيقات، ابهيك بننهي اليوم ونشكركوا على
+
+528
+00:46:33,830 --> 00:46:35,230
+حصن باسمنا
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1FUjIgJdwak.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1FUjIgJdwak.srt
new file mode 100644
index 0000000000000000000000000000000000000000..54a8b9199adb485b3aa925dbeb3d3b3330c07287
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1FUjIgJdwak.srt
@@ -0,0 +1,1628 @@
+
+1
+00:00:19,930 --> 00:00:24,470
+بسم الله الرحمن الرحيم المرة الماضية بدأنا في
+
+2
+00:00:24,470 --> 00:00:31,090
+موضوع ال alkyl halides ال RX يمكن أخذنا فكرة عن
+
+3
+00:00:31,090 --> 00:00:37,450
+المركبات وتسميتها وربما البعض بيذكر قوة الرابط
+
+4
+00:00:37,450 --> 00:00:42,990
+اللي ما بين ال R و ال X وقلنا بشكل عام رابطة مع ال
+
+5
+00:00:42,990 --> 00:00:49,410
+fluorine رابطة قوية وبالتالي مابتمش عمليةكسر سهل
+
+6
+00:00:49,410 --> 00:00:54,410
+خلينا نقول لهذه الرابطة ما عدا ذلك اليود و البروم
+
+7
+00:00:54,410 --> 00:01:00,050
+و الكلور ممكن كسر الرابطة و أسهل ما تكون مع اليود
+
+8
+00:01:00,050 --> 00:01:06,630
+رابطة إيش معاها بعيفة فأتكلمنا قولنا إنه في ال
+
+9
+00:01:06,630 --> 00:01:11,450
+الكلهيليتز التفاعل الأساسي إما تفاعل إبدالي يعني
+
+10
+00:01:11,450 --> 00:01:15,610
+نشيل ال halogen و ال halogen في كل الأحوال بدأ
+
+11
+00:01:16,660 --> 00:01:21,680
+تنشال مع إلكتروناتها ونحط مكانها نيوكليوفايل مع
+
+12
+00:01:21,680 --> 00:01:26,740
+إلكتروناته يعني كأنه أبدلنا شيء سالب شيء سالب هذه
+
+13
+00:01:26,740 --> 00:01:32,340
+تقريبا أخر نقطة اتكلمنا عنها المرة الماضية الان
+
+14
+00:01:32,340 --> 00:01:39,640
+بالنسبة لل nucleophiles اللى هى تمثل نص التفاعل
+
+15
+00:01:39,640 --> 00:01:44,060
+يعني هذا التفاعل لو احنا بدنا نفهمه هو مكوّن من
+
+16
+00:01:44,060 --> 00:01:52,360
+شقين مكوّن من alkyl halide RX ومكوّن من اشمن الـ
+
+17
+00:01:52,360 --> 00:01:57,240
+nucleophile فالذي يفهم التفاعل جيدا يكون يعرف ال
+
+18
+00:01:57,240 --> 00:02:01,540
+هلايدز و أخذنا فكرة عنهم و عن أنواعهم و عن قوة
+
+19
+00:02:01,540 --> 00:02:05,420
+الرابط فيهم قلنا أسهل شيء التفاعل مع المركبات
+
+20
+00:02:05,420 --> 00:02:10,200
+اللي فيها اليود أكثر من .. الآن بلزمنا أيضا نتعرف
+
+21
+00:02:10,200 --> 00:02:14,600
+على ال nucleophiles واضح؟ يعني لما بيكون في صراع
+
+22
+00:02:14,600 --> 00:02:17,850
+على سبيل المثال بين دولتين الذين يريدون أن يفهموا
+
+23
+00:02:17,850 --> 00:02:21,270
+الأمر جيدا يريدون أن يفهموا الدولتين وقوة
+
+24
+00:02:21,270 --> 00:02:24,150
+الدولتين، والذين يريدون أن يفهموا التفاعل جيدا
+
+25
+00:02:24,150 --> 00:02:28,530
+يريدون أن يكونوا عارف الـ Alkyl Halides وخواصة وكيف
+
+26
+00:02:28,530 --> 00:02:34,310
+تتفاعل ويعرف نيوكليوفايل احنا بدنا المرة الماضية
+
+27
+00:02:34,310 --> 00:02:37,810
+حكينا عن ال الكلهيلايت تصنيفاتها ل primary و
+
+28
+00:02:37,810 --> 00:02:42,170
+secondary و tertiary ان ال X ممكن تكون يودي برومي
+
+29
+00:02:42,170 --> 00:02:46,110
+كلور كل المعلومات هذه شرحناها بخصوص ال الكلهيلايت
+
+30
+00:02:46,110 --> 00:02:50,490
+اذا اليوم هيكون جزء من الكلام اللى هنبدأ فيه ان
+
+31
+00:02:50,490 --> 00:02:56,070
+نتعرف على نيوكليوفايل طبعا سبق اننا قلنا ايش معنى
+
+32
+00:02:56,070 --> 00:03:02,570
+نيوكليوفايل بكل الأحوال نيوكليوفايل عبارة عن جزء او
+
+33
+00:03:02,570 --> 00:03:08,490
+ايون مش مشكلة اهمه يميزه ايش زوج الالكترونات
+
+34
+00:03:08,490 --> 00:03:14,060
+لاحظوا انتوا قلتوا سالب انا ماقلتش سالب مش الزام
+
+35
+00:03:14,060 --> 00:03:20,500
+انه لليوكليوفايل يكون سالب لليوكليوفايل يميزه وجود
+
+36
+00:03:20,500 --> 00:03:25,240
+الزوج الإلكترونات غير الرابط واضح؟ أزواج
+
+37
+00:03:25,240 --> 00:03:30,000
+الإلكترونات الحرة هي اللي بتميزه الآن لليوكليوفايل
+
+38
+00:03:30,000 --> 00:03:35,720
+ضمن هذا التعريف يمكن أن يكون متعادلا ويمكن أن يكون
+
+39
+00:03:35,720 --> 00:03:39,880
+مشحونا إذا كان مشحون هيكون مشحون بشحنه سالبة يعني
+
+40
+00:03:39,880 --> 00:03:45,120
+مثلا ال O H في مركب زي ال N A O H يعني مافيش O H
+
+41
+00:03:45,120 --> 00:03:49,940
+minus بتلبع و بتنشر لحالها مافيش أيونات بتلبع و
+
+42
+00:03:49,940 --> 00:03:54,020
+بتنشر لحالها عادة المركبات ايش بتكون متعادلة يعني
+
+43
+00:03:54,020 --> 00:03:59,540
+يوم بقول O H minus كأن انا بقول ن او اتش او
+
+44
+00:03:59,540 --> 00:04:04,460
+بوتاسيوم هيدروكسيد او اي شئ لكن انا مهتم الآن بال
+
+45
+00:04:04,460 --> 00:04:08,900
+O H جزء ال O H هو اللي هيتفاعل معاه الان هذا ال O
+
+46
+00:04:08,900 --> 00:04:13,060
+H هيتوزيع الالكتروني لو حسب الشحن على ال oxygen
+
+47
+00:04:13,060 --> 00:04:18,780
+بلاحظ انه minus وبناء على ذلك بقول ان ال O H minus
+
+48
+00:04:18,780 --> 00:04:24,440
+is a charged nucleophile نيوكليوفال مشحون كذلك
+
+49
+00:04:24,440 --> 00:04:29,300
+الحال ال CN minusتشارج الـ nucleophile بنبيع لحاله
+
+50
+00:04:29,300 --> 00:04:34,520
+أكيد لأ بنشتريه بنستعمله مثلا ع شكل potassium
+
+51
+00:04:34,520 --> 00:04:39,460
+cyanide واضح هذا المركب السام و الخطير اللي عادة
+
+52
+00:04:39,460 --> 00:04:44,140
+بنسمحش الناس تستعمله في المختبر بدون رقابة لأنه لو
+
+53
+00:04:44,140 --> 00:04:49,700
+طلع كميات صغيرة من ال HCN الناس اتعاملت معه تتسمم
+
+54
+00:04:49,700 --> 00:04:53,940
+و يؤدي إلى وفاة سريعة جدا يعني خلال دقيقة أو
+
+55
+00:04:53,940 --> 00:04:58,340
+دقيقتين فمستقبلكملو جيتوا تشتغلوا مع potassium
+
+56
+00:04:58,340 --> 00:05:02,640
+cyanide مع potassium cyanide بدكوا حذر بدوا ناس
+
+57
+00:05:02,640 --> 00:05:05,860
+يكونوا معاكوا في المختبر يعلموكوا كيف تشتغلوا
+
+58
+00:05:05,860 --> 00:05:10,240
+بخزانة أبخرة إنما واحدة حاطة potassium cyanide
+
+59
+00:05:10,240 --> 00:05:17,650
+وكبت عليه شوية HCl طلع HCl غاز شمته بكون عندها
+
+60
+00:05:17,650 --> 00:05:20,830
+دقيقتين تتشاهد و تقول لا إله إلا الله مش أكثر من
+
+61
+00:05:20,830 --> 00:05:26,310
+هذا واضح النقطة فبدنا نلتبه الخلاصة في كل الأحوال
+
+62
+00:05:26,310 --> 00:05:32,750
+أن هذه الـ charged uq files عادة هي عبارة عن مركبات
+
+63
+00:05:32,750 --> 00:05:37,500
+أيونية فيها ايون موجب و ايون سالب الان احنا اللي
+
+64
+00:05:37,500 --> 00:05:41,680
+بدنا يتفاعل عندنا ايش الايون السالب و عشان هيك
+
+65
+00:05:41,680 --> 00:05:45,520
+بنذكره لحاله يعني عادة مابفرجش عندى لو كان هذا
+
+66
+00:05:45,520 --> 00:05:49,680
+potassium cyanide ولا sodium cyanide مثلا ولا ايش
+
+67
+00:05:49,680 --> 00:05:55,010
+ما كان يكون انا مهتم بالـ Ion الساني هذا بالنسبة
+
+68
+00:05:55,010 --> 00:05:57,950
+للنوع الأول من الـ nucleophiles اللي هو الـ
+
+69
+00:05:57,950 --> 00:06:02,010
+charged nucleophiles النوع التاني الـ neutral
+
+70
+00:06:02,010 --> 00:06:06,570
+nucleophiles الـ neutral nucleophiles مثلا الماء
+
+71
+00:06:06,570 --> 00:06:11,950
+شايفين فيه عادة رابطتين وزوجين من الإلكترونات إذا
+
+72
+00:06:11,950 --> 00:06:16,550
+ممكن يهاجم على الـ Alkyl Halide من خلال زوج
+
+73
+00:06:16,550 --> 00:06:21,830
+الإلكترونات هذا ويتفاعل معها بالتأكيد الماء هنا يمثل
+
+74
+00:06:21,830 --> 00:06:25,950
+الـ neutral الـ nucleophile الأمونيا على سبيل
+
+75
+00:06:25,950 --> 00:06:29,730
+المثال الـ neutral الـ nucleophile الان لو كان
+
+76
+00:06:29,730 --> 00:06:33,310
+عندي substituted أمونيا يعني بدل ما الثلاث ذرات
+
+77
+00:06:33,310 --> 00:06:37,530
+هدول كانوا هيدروجين لو واحدة منهم كانت مجموعة R
+
+78
+00:06:38,180 --> 00:06:42,160
+بيظلوا اليوكليوفايل و لا لأ اكيد و لو تنتين كانوا
+
+79
+00:06:42,160 --> 00:06:45,320
+مجموعة R بيظلوا اليوكليوفايل و لو التلاتة كانوا
+
+80
+00:06:45,320 --> 00:06:49,560
+مجموعة R هيظلوا اليوكليوفايل فحيصير الإنسان يتكلم
+
+81
+00:06:49,560 --> 00:06:53,680
+عن ال nitrogen اليوكليوفايل ال nitrogen
+
+82
+00:06:53,680 --> 00:06:58,760
+اليوكليوفايل واضح يعني مش ضروري بس ال ammoniaمش
+
+83
+00:06:58,760 --> 00:07:02,620
+ضروري بس الأمونيا بنحكي عن ال nitrogen نيوكليوفايل
+
+84
+00:07:02,620 --> 00:07:07,400
+سواء بتلاتة هيدروجين بدون ولا ار ار واحدة اتنين
+
+85
+00:07:07,400 --> 00:07:14,560
+تلاتة كل هذه تعتبر عبارة عن ايش النيوكليوفايل الان
+
+86
+00:07:14,560 --> 00:07:21,000
+بيفيدنا ان نعرف كيف النيوكليوفايل بيكون اقوى او
+
+87
+00:07:21,000 --> 00:07:25,320
+اضعف من النيوكليوفايل التاني اللي بنسميه احنا ال
+
+88
+00:07:25,320 --> 00:07:30,530
+strength of نيوكليوفايلو هذا أمر دائما بيسأل
+
+89
+00:07:30,530 --> 00:07:34,150
+الطالب عنه يعني بنقوله أي ال eucleophile أقوى ألف
+
+90
+00:07:34,150 --> 00:07:39,550
+ولا با هذا ولا هذا في عندنا قواعد عامة القاعدة
+
+91
+00:07:39,550 --> 00:07:46,240
+الأولى بتقول إذا أنا بأقارن شارج النيوكليوفايل
+
+92
+00:07:46,240 --> 00:07:51,540
+يحمل شحنة سالبة بنيوترال نيوكليوفايل دائما و أبدا
+
+93
+00:07:51,540 --> 00:07:55,480
+تشارج النيوكليوفايل أقوى من النيوترال يعني مثلا
+
+94
+00:07:55,480 --> 00:08:02,600
+انقارن ال OH- مع الميه مين الأقوى؟ انقارن ال
+
+95
+00:08:02,600 --> 00:08:08,760
+ethanol O- مع الاثانول مين الأقوى؟ الـ ethyl O-,
+
+96
+00:08:08,760 --> 00:08:15,980
+الـ NH2- مع الـ NH3 من الأقوى، إذا دائما الـ
+
+97
+00:08:15,980 --> 00:08:20,660
+nucleophile اللي بيحمل شحنة سالبة، الـ charged
+
+98
+00:08:20,660 --> 00:08:25,000
+nucleophile are stronger than neutral nucleophile
+
+99
+00:08:25,000 --> 00:08:29,880
+واضح هذا الكلام؟ charged nucleophile are stronger
+
+100
+00:08:29,880 --> 00:08:36,120
+than neutral nucleophile طيب بيجينا السؤال لو بقارن
+
+101
+00:08:36,120 --> 00:08:41,920
+انا enucleophile مشحون مع مشحون او متعادل مع
+
+102
+00:08:41,920 --> 00:08:46,180
+متعادل واضح الفكرة اذا انا بعمل مقارنة ل
+
+103
+00:08:46,180 --> 00:08:51,340
+enucleophile مشحونومشحون او متعادل و متعادل مين
+
+104
+00:08:51,340 --> 00:08:56,920
+بيكون الاقوى الان هنا بلزمنا نتذكر شوية الجدول
+
+105
+00:08:56,920 --> 00:09:00,580
+الدوري كيف العناصر مرتبة في الجدول الدوري في
+
+106
+00:09:00,580 --> 00:09:04,140
+الجدول الدوري كلكم عارفين المهمين عند الكاربون
+
+107
+00:09:04,140 --> 00:09:10,230
+نيتروجين اكسوجين floricloribromide الان قوة
+
+108
+00:09:10,230 --> 00:09:17,530
+اليوكليوفايدز بتزيد حسب السهم بتزيد بهذا الاتجاه و
+
+109
+00:09:17,530 --> 00:09:22,670
+بتزيد بهذا الاتجاه واضح؟
+
+110
+00:09:23,960 --> 00:09:28,600
+فلو أنا بدأ أعمل عدة مقارنات و الأسهم هذه موجودة
+
+111
+00:09:28,600 --> 00:09:33,240
+قدامي، على طول بقدر أتخذ قرار، يعني مثلا لو بدأ
+
+112
+00:09:33,240 --> 00:09:37,100
+أقارن الأمونيا طبعا فيها إلكترونات و الميه فيها
+
+113
+00:09:37,100 --> 00:09:41,860
+إلكترونات أزواج، الأمونيا مع الميه، الأمونيا ذرتها
+
+114
+00:09:41,860 --> 00:09:47,260
+النيتروجين، الميه الوكسوجين، which is stronger؟
+
+115
+00:09:47,260 --> 00:09:52,760
+الأمونيا واضح؟ لحظوا هذا neutral و هذا neutral طب
+
+116
+00:09:52,760 --> 00:09:57,560
+لو أخدت منهم ال charge يعني أخدت من هنا حذفت H
+
+117
+00:09:57,560 --> 00:10:01,080
+plus صار ال ion ال minus ال NH2 minus و من هنا
+
+118
+00:10:01,080 --> 00:10:06,720
+حذفت H plus صار ال OH minus مشحون مع مشحون أيضا
+
+119
+00:10:06,720 --> 00:10:10,500
+مين بده يكون الأقوى ال NH2 minus أقوى من ال OH
+
+120
+00:10:10,500 --> 00:10:17,460
+minus واضح؟ الآن طب لو مشينا حسب المجموعة تحت ال
+
+121
+00:10:17,460 --> 00:10:22,360
+oxygen إيش في عنده؟ الـ Sulphur لو بدأ أقارن الـ
+
+122
+00:10:22,360 --> 00:10:27,560
+H2S مع الـ H2O هاي مركّب Sulphur مركّب واسمه الـ
+
+123
+00:10:27,560 --> 00:10:31,380
+H2S أقوى، هذا نيوترال، هذا نيوترال طب لو بدأ أقارن
+
+124
+00:10:31,380 --> 00:10:39,340
+الـ SH-, الأيون السالب من هذا مع الـ OH-, الـ SH-,
+
+125
+00:10:39,340 --> 00:10:43,540
+لو بدأ أقارن اليود مع البروم، بدأ أقارن البروم مع
+
+126
+00:10:43,540 --> 00:10:48,930
+الكلورو هكذا واضح فال strength of nucleophiles
+
+127
+00:10:48,930 --> 00:10:54,530
+بيكون له كام قاعدة تلاتة القاعدة الأولى المشحون
+
+128
+00:10:54,530 --> 00:10:58,290
+أقوى من المتعدل القاعدة التانية إذا كنا بنحكي عن
+
+129
+00:10:58,290 --> 00:11:02,850
+عناصر بنفس الدورة بدنا نمشي بهذا الاتجاه بيكون
+
+130
+00:11:02,850 --> 00:11:05,850
+أقوى لل nucleophile القاعدة التالتة إذا بحكي عن
+
+131
+00:11:05,850 --> 00:11:11,490
+عناصر بنفس المجموعة بدأ أمشي بهذا الاتجاه واضح
+
+132
+00:11:11,490 --> 00:11:11,970
+الكلام
+
+133
+00:11:16,040 --> 00:11:22,200
+بهيك بيصير عندنا فكرة عن ال alkyl halides لوحدها و
+
+134
+00:11:22,200 --> 00:11:27,560
+أنواعها و بيصير عندنا فكرة عن ال nucleophiles الان
+
+135
+00:11:27,560 --> 00:11:32,040
+بدنا نعمل تفاعل ما بين ال alkyl halide و ال
+
+136
+00:11:32,040 --> 00:11:38,970
+nucleophile خلّينا نحط فرضية ان احنا بدنا ب general
+
+137
+00:11:38,970 --> 00:11:45,330
+reaction يعني نقول ال الهلايد بشكل عام RX هذا ال
+
+138
+00:11:45,330 --> 00:11:52,010
+RX شو بده يفقد؟ الـ X الهالوجين النيكليوفايلز أنواع
+
+139
+00:11:52,010 --> 00:11:57,150
+كتيرة من أشهر أنواع النيكليوفايلز اللي بنسميها ال
+
+140
+00:11:57,150 --> 00:12:03,030
+oxygen نيكليوفايلز اللي فيها أكسوجين و ال أكسوجين
+
+141
+00:12:03,030 --> 00:12:10,410
+عادة إما بيكون متعادل أو مشحون بالمتعادل بيكون
+
+142
+00:12:10,410 --> 00:12:17,260
+عليه رابطتين و زوجين إلكترونات بالمشحونبيكون فيه
+
+143
+00:12:17,260 --> 00:12:22,220
+رابطة واحدة و تلت أزواج، إلكترونات زي ما أجي أقول
+
+144
+00:12:22,220 --> 00:12:29,140
+الميّه، لاحظوا الميّه، هاي ال Oxygen، H و H، كام
+
+145
+00:12:29,140 --> 00:12:34,710
+رابطة شايفين؟ تنتين، كم زوج إلكترونات؟ إتنين، الآن
+
+146
+00:12:34,710 --> 00:12:40,150
+لو بدي منها المشحون، بتكون OH كام رابطة شايفين؟
+
+147
+00:12:40,150 --> 00:12:44,950
+كام زوج إلكترونات هنا؟ تلاتة، في هذه الحالة، هذا
+
+148
+00:12:44,950 --> 00:12:51,430
+النيكليوفايل بيكون مشحون كذلك الحال مع الـ Nitrogen
+
+149
+00:12:51,430 --> 00:12:56,390
+الـ Nucleophile تلت روابط وزوج إلكترونات بيكون
+
+150
+00:12:56,390 --> 00:13:00,290
+عبارة عن الـ Neutral Nucleophile لو شيلنا منه
+
+151
+00:13:00,290 --> 00:13:04,450
+هيدروجينة و خلناها رابطتين و زوجين إلكترونات،
+
+152
+00:13:04,450 --> 00:13:10,100
+بيصير إيش؟ Charged Nucleophile والسلفر زيه تماما زي
+
+153
+00:13:10,100 --> 00:13:16,200
+ال Oxygen الآن لما بنجي نعمل تفاعل ها اننا RX
+
+154
+00:13:16,200 --> 00:13:22,180
+اجينا نفعله مع ال OH- كيف بدنا نعمل المعادلة
+
+155
+00:13:22,180 --> 00:13:29,700
+تبعتنا بدنا ببساطة نشيل ال X مع إلكتروناتها ونحط
+
+156
+00:13:29,700 --> 00:13:37,550
+محلها ال OH واضح؟ بدنا نشيل ال X مع إلكتروناتها
+
+157
+00:13:37,550 --> 00:13:41,130
+ونحط محالة ال O H ولذلك لما أنا بفعل RX مع O H
+
+158
+00:13:41,130 --> 00:13:47,130
+minus إيش الناتج الأساسي ال organic product؟ R O H
+
+159
+00:13:47,130 --> 00:13:55,450
+طبعا أكيد طلع عندى ال X minus هل يا ترى ال X minus
+
+160
+00:13:55,450 --> 00:14:00,530
+بيضطر لتسبح بالفراغ لحالها؟ قامين تقولنا إيش بتعمل
+
+161
+00:14:00,530 --> 00:14:07,850
+ال X minus؟ ما هو أنا أساسا ال OHK هذي في معها N A
+
+162
+00:14:07,850 --> 00:14:17,730
+N A plus R الان هتطلع N A plus X واضح؟ يعني اللي
+
+163
+00:14:17,730 --> 00:14:22,570
+كان ايون موجة مرافق لل OH بيصير ايون موجة مرافق لل
+
+164
+00:14:22,570 --> 00:14:28,190
+X احنا بشكل عام الأشياء ما عدا ال organic products
+
+165
+00:14:28,190 --> 00:14:31,190
+مش مهمة عندنا يعني دائما لما نقولكوا أكمل معادلة
+
+166
+00:14:31,190 --> 00:14:35,030
+في الكيميا العضوية و اكتبولنا ناتج العضوية الأشياء
+
+167
+00:14:35,030 --> 00:14:40,390
+التانية تحصيل حاصل مش مهمة فبالان لو اجينا عملنا
+
+168
+00:14:40,390 --> 00:14:45,210
+التفاعل مع ميّه ايش بدو يكون الناتج نفس ال RX مع
+
+169
+00:14:45,210 --> 00:14:49,640
+الميه لاحظوا الميه لما تتفاعل من خلال أحد أزواج
+
+170
+00:14:49,640 --> 00:14:53,740
+الإلكترونات أول ما تتفاعل هذا أزواج الإلكترونات
+
+171
+00:14:53,740 --> 00:15:01,540
+هيعمل رابطة هي
+
+223
+00:20:24,130 --> 00:20:31,290
+كذا المركب بيكون اسمه صوديوم اث اكسايد لو
+
+224
+00:20:31,290 --> 00:20:37,610
+كتبنالكوا صوديوم اث اكسايد ايش بدكم تحطوه CH3لو
+
+225
+00:20:37,610 --> 00:20:42,670
+قلنا بروبوكسايد تلت
+
+226
+00:20:42,670 --> 00:20:48,970
+كربونات من البروبين و هكذا فال ايون بشكل عام بيكون
+
+227
+00:20:48,970 --> 00:20:54,390
+اسمه الكوكسايد ايش يعني الكو يعني في مجموعة الكل
+
+228
+00:20:54,390 --> 00:20:59,150
+يعني يوم ما بدي اقول ايون ر او ماينوس ايش اسم هذا
+
+229
+00:20:59,150 --> 00:21:05,000
+الايونلو جيبنا لكوا سؤال أكمل الفراغ R O minus is
+
+230
+00:21:05,000 --> 00:21:13,940
+called an alkoxide anion أنيون يعني أيون إيش؟ سالب
+
+231
+00:21:13,940 --> 00:21:18,980
+الكوكسايد أنيون
+
+232
+00:21:18,980 --> 00:21:25,340
+واضح؟ الكوكسايد أنيون إذا صار عندنا فكرة تماما كيف
+
+233
+00:21:25,340 --> 00:21:33,150
+نكمل معادلةبأيون سالب أو بمتعدل في كل الأحوال مكان
+
+234
+00:21:33,150 --> 00:21:37,650
+ما بتكون الهالوجين مكان ما بنحط ايش لنيوكليوفايل
+
+235
+00:21:37,650 --> 00:21:42,590
+ونعمل لنيوكليوفيليك substitution كل الجداول اللي
+
+236
+00:21:42,590 --> 00:21:52,050
+موجودة عندكم هي أمثلة على هذا الموضوع كل الجداول
+
+237
+00:21:52,050 --> 00:21:59,280
+يعني لاحظوا لنيوكليوفايل هنا OH-تشارج RO- تشارج
+
+238
+00:21:59,280 --> 00:22:07,280
+HOH تشارج ROH تشارج HOH تشارج HOH تشارج HOH تشارج
+
+239
+00:22:07,280 --> 00:22:08,700
+HOH تشارج HOH تشارج HOH تشارج HOH تشارج
+
+240
+00:22:08,700 --> 00:22:09,060
+HOH تشارج HOH تشارج HOH تشارج HOH تشارج
+
+241
+00:22:09,060 --> 00:22:09,680
+HOH تشارج HOH تشارج HOH تشارج HOH تشارج
+
+242
+00:22:09,680 --> 00:22:09,740
+HOH تشارج HOH تشارج HOH تشارج HOH تشارج
+
+243
+00:22:09,740 --> 00:22:11,520
+HOH تشارج HOH تشارج HOH تشارج HOH تشارج
+
+244
+00:22:11,520 --> 00:22:16,780
+HOH تشهذا الأكسجين بتحول محل الـCl الـ Nitrogen
+
+245
+00:22:16,780 --> 00:22:22,280
+نيوكليوفايل مثلا نيوترال الأمونيا ومشتقاتها سواء
+
+246
+00:22:22,280 --> 00:22:26,260
+كان عنده R واحدة أو تنتين أو تلاتة في كل الأحوال
+
+247
+00:22:26,260 --> 00:22:32,390
+من وين بكيش بيك؟ من مكانالنيتروجين السلفر
+
+248
+00:22:32,390 --> 00:22:38,370
+النيوكليوفيل على سبيل المثال SH-, RS-, R2S من
+
+249
+00:22:38,370 --> 00:22:44,210
+أزواج الإلكترونات على السلفر الهالوجين
+
+250
+00:22:44,210 --> 00:22:49,410
+النيوكليوفيل الهالوجين عادة عليها أربع أزواج
+
+251
+00:22:49,410 --> 00:22:55,220
+إلكترونات و بتكون سالبةواضح؟ بديكوا تتذكروا نقطة
+
+252
+00:22:55,220 --> 00:22:58,300
+انه احنا قولنا ال halogens لما تحل محال بعضها
+
+253
+00:22:58,300 --> 00:23:05,620
+البعض اليود اقوى من ال brom اقوى من ال chlorine
+
+254
+00:23:05,620 --> 00:23:11,400
+بناء على ذلك لو عندى مركب RX فيه brom وفعلته مع
+
+255
+00:23:11,400 --> 00:23:15,620
+يود اليود بيحل محال ال brom ولا لأ؟ اه لكن ال brom
+
+256
+00:23:15,620 --> 00:23:22,380
+بيحلش محال اليوداليود بيحل محل بروم بمعنى لو كانت
+
+257
+00:23:22,380 --> 00:23:32,240
+المعادلة بهذا الشكل I minus زائد CH3PR وقلنا لك
+
+258
+00:23:32,240 --> 00:23:40,840
+اكمل المعادلة بيحل اليود محل بروم او محل كلور سواء
+
+259
+00:23:40,840 --> 00:23:44,980
+كان بروم او كلور بيصير هذا التفاعل بيصير شو الناتج
+
+260
+00:23:44,980 --> 00:23:48,080
+CH3I
+
+261
+00:23:51,470 --> 00:23:58,690
+زائد PR ماينوس أو CL ماينوس ايش السؤال PR مش كازم
+
+262
+00:23:58,690 --> 00:24:03,850
+ترتبط مثلا باش مهم مش مهم هو هذا NA plus بديش انا
+
+263
+00:24:03,850 --> 00:24:08,430
+اعيد الجملة مية مرة هذا NA plus I minus لما نشوفه
+
+264
+00:24:08,430 --> 00:24:14,170
+كتفاعل كامل NA plus I minus زائد CH3PR إجت ليه محل
+
+265
+00:24:14,170 --> 00:24:28,430
+ال PR شو طلع عندىCH3I PR- N A N A Plus واضح؟
+
+266
+00:24:28,430 --> 00:24:34,770
+لو هذه المعادلة وجدت عندكم بشكل معاكس يعني إيجينا
+
+267
+00:24:34,770 --> 00:24:40,630
+قولنا لكم CL- CH3PR
+
+268
+00:24:43,400 --> 00:24:46,740
+الكلور لا يحل محل البروم، البروم يحل محل الكلور و
+
+269
+00:24:46,740 --> 00:24:54,000
+هكذا واضح الفكرة؟ من الـ nucleophiles أيضا ال
+
+270
+00:24:54,000 --> 00:24:58,320
+carbon nucleophiles منها ال CN اللي حكينا عنه و
+
+271
+00:24:58,320 --> 00:25:02,780
+قولنا موجود ع شكل CN minus ال carbon nucleophiles
+
+272
+00:25:02,780 --> 00:25:08,560
+بالمناسبة لا توجد متعادلة ليش ال carbon
+
+273
+00:25:08,560 --> 00:25:14,070
+nucleophiles لا توجد متعادلة؟لأن الكربون أول ما
+
+274
+00:25:14,070 --> 00:25:18,870
+تعلمنا الكيميا يقولنا بيعمل أربع روابط ولا يبقى
+
+275
+00:25:18,870 --> 00:25:25,010
+فيه أزواج إلكترونات الميّه رابطتين وزوجين
+
+276
+00:25:25,010 --> 00:25:28,470
+إلكترونات النيتروجين تلت روابط وزوج إلكترونات
+
+277
+00:25:28,470 --> 00:25:33,130
+الهالوجين تلت أزواج إلكترونات كلهم عليهم أزواج
+
+278
+00:25:33,130 --> 00:25:34,950
+إلكترونات لكن الكربون
+
+279
+00:25:37,240 --> 00:25:40,500
+الـ Carbon مافيش عليه أزواج إلكترونات وبناء على
+
+280
+00:25:40,500 --> 00:25:43,300
+ذلك في الوضع المتعادل مافيش عندي carbon
+
+281
+00:25:43,300 --> 00:25:48,620
+nucleophile لكن لو هذا فقد H لسبب ما بيصير ايون
+
+282
+00:25:48,620 --> 00:25:53,740
+ايش سالب من أمثلة الايونات السالب اللي فيها Carbon
+
+283
+00:25:53,740 --> 00:25:58,100
+ايون الـ C9 هاي C triple bond N وهنا شايفين في
+
+284
+00:25:58,100 --> 00:26:02,420
+عندكم زوج من الإلكترونات ولا لأ لاحظوا
+
+285
+00:26:03,550 --> 00:26:08,550
+لو واحدة شوية بتدقيق الكلام الـCN- في زوج
+
+286
+00:26:08,550 --> 00:26:12,530
+إلكترونات على الكربون و زوج إلكترونات على
+
+287
+00:26:12,530 --> 00:26:16,190
+النيتروجين يعني من ناحية المبدأ ممكن أي واحدة تفكر
+
+288
+00:26:16,190 --> 00:26:21,250
+إنه الكربون نفسه بيعمل الـNucleophile و النيتروجين
+
+289
+00:26:21,250 --> 00:26:25,590
+نفسه بيعمل الـNucleophile عشان هيك لو إجتها معادلة
+
+290
+00:26:25,590 --> 00:26:34,490
+اتكملها CH3 نفترض CLوبدأ اتفعلها مع ال NACN احنا
+
+291
+00:26:34,490 --> 00:26:38,530
+بدنا ندمج العلم عاد ال carbon ال nucleophile اقوى
+
+292
+00:26:38,530 --> 00:26:44,110
+من ال nitrogen لما حكينا قوة لل nucleophiles وبناء
+
+293
+00:26:44,110 --> 00:26:49,230
+على ذلك هذا لما بدأ افعله مع ال CN minus من وين
+
+294
+00:26:49,230 --> 00:26:57,110
+هييجي يتحد هنا اذا النتج هيكون CH3 اتصلت بال
+
+295
+00:26:57,110 --> 00:27:02,650
+cyanide من خلال carbonمن خلال الكربون مش
+
+296
+00:27:02,650 --> 00:27:07,910
+النيتروجين واضح؟ طبعا النيتروجين بيبقى عليها زوج
+
+297
+00:27:07,910 --> 00:27:13,590
+الالكترونات تبعها ف الـ CN- بتتحد مكان الهالوجين
+
+298
+00:27:13,590 --> 00:27:21,080
+من خلال الكربون مش النيتروجينخدوا في كمان ايون
+
+299
+00:27:21,080 --> 00:27:25,900
+اخدناه اخذنا تفاعله ل triple bond اللي بتكون
+
+300
+00:27:25,900 --> 00:27:31,440
+terminal جنبها H اتفقنا ان هذا الـH اسيدك يمكن ان
+
+301
+00:27:31,440 --> 00:27:37,460
+تفقد وتعمل ايون سالب على الكربون سمناه Acetylide
+
+302
+00:27:37,460 --> 00:27:43,820
+anion هذا اخدناه بتفاعل الالكاينز اخر تفاعل راجعوا
+
+303
+00:27:43,820 --> 00:27:47,980
+الان هذا ال Acetylide anion لو اجيناه فاعلناه مع
+
+304
+00:27:47,980 --> 00:27:58,410
+RXماذا سيفعل؟ سيأتي الكربون تهاجم وتطرد الـ X إذا
+
+305
+00:27:58,410 --> 00:28:05,850
+صار عندي A اللي موجودة هنا C triple bond CR فهيصير
+
+306
+00:28:05,850 --> 00:28:13,210
+إبدال لل X بالacetylide anion من خلال الكربون
+
+307
+00:28:13,210 --> 00:28:17,330
+النيوكليوفال كل هذه الأمثلة اللي انتوا شايفينها هي
+
+308
+00:28:17,330 --> 00:28:23,530
+عبارة عنsubstitution reactions كل الأمثلة اللي مرت
+
+309
+00:28:23,530 --> 00:28:27,930
+علينا substitution reactions استعرضناها بتوسع سواء
+
+310
+00:28:27,930 --> 00:28:33,470
+من ناحية neutral enucleophiles أو من ناحية charged
+
+311
+00:28:33,470 --> 00:28:34,870
+enucleophiles
+
+312
+00:28:38,920 --> 00:28:45,140
+بجينا تفاعل تاني وهذا التفاعل التاني بشكل عام
+
+313
+00:28:45,140 --> 00:28:50,920
+منافس لتفاعل الإبدال بمعنى التفاعلين بيصيروا مع
+
+314
+00:28:50,920 --> 00:28:58,200
+بعض يعني انا بكون بدي اعمل تفاعل إبدال بلاحظ انه
+
+315
+00:28:58,200 --> 00:29:04,380
+مع الإبدال بطلع عندى ناتج تاني حذف ايش هو تفاعل
+
+316
+00:29:04,380 --> 00:29:09,400
+الحذف؟ماذا هو بالظبط تفاعل الحذف؟ تفاعل الإبدال؟
+
+317
+00:29:09,400 --> 00:29:14,420
+اعرفنا يعني لو الآن جيبنالكم أكمل المعادلة هذه CH3
+
+318
+00:29:14,420 --> 00:29:20,320
+CHPR CH3 زائد NUH كل كسرته تتقن الإبدال شيل ال PR
+
+319
+00:29:20,320 --> 00:29:23,180
+حط مكانها هذا
+
+320
+00:29:25,930 --> 00:29:30,410
+Substitution طب إيش تفاعل الحذف اللي بيصير بنفس
+
+321
+00:29:30,410 --> 00:29:33,470
+الشروط عشان هيك لاحظوا نفس المُركّب مع الانيواتش
+
+322
+00:29:33,470 --> 00:29:38,550
+بدنا نكتب إنه بيطلع ناتج تاني إنه يعمل حذف
+
+323
+00:29:38,550 --> 00:29:44,930
+للهالوجين مع هيدروجين عن الكربون المجاورة إيش معنى
+
+324
+00:29:44,930 --> 00:29:51,830
+الحذف إن أشيل الهالوجين مع ذرة هيدروجين يعني كإن
+
+325
+00:29:51,830 --> 00:30:00,140
+اللي بدي أحذف أشههH و PR واضح الان وين ال hydrogen
+
+326
+00:30:00,140 --> 00:30:05,620
+اللى انا بدي اشيله معروف واحد مافيش غيره طب وين ال
+
+327
+00:30:05,620 --> 00:30:10,120
+hydrogens على الكربون المجاورة لو انا اتيت واطلعت
+
+328
+00:30:10,120 --> 00:30:13,400
+هذه الكربون اللى حاملة ال hydrogen فيه جنبها على
+
+329
+00:30:13,400 --> 00:30:20,400
+اليمين CH3 حاملة كم هيدروجينة تلاتة وفيه جنبها على
+
+330
+00:30:20,400 --> 00:30:28,550
+اليسارCH3 حاملة 3 تفاعل الحذف ان اشيل ال PR هذه مع
+
+331
+00:30:28,550 --> 00:30:33,790
+ال Hشطابتهم طبعا هذه الرابطه هتيجي تعمل double
+
+332
+00:30:33,790 --> 00:30:38,210
+bond هنا فبدل ما كان عندي رابطه أحدية بتصير رابطه
+
+333
+00:30:38,210 --> 00:30:43,730
+ثنائية بتكون الألكيد طيب الآن يا ترى بيفرق عندى في
+
+334
+00:30:43,730 --> 00:30:48,710
+هذا المركب لما أعمل الحذف بمساعدة الانقوات ان اعمل
+
+335
+00:30:48,710 --> 00:30:53,770
+الرابطة الزوجية هان او هان نفس المركب نفس المركب
+
+336
+00:30:53,770 --> 00:31:01,860
+في مرات معينة هلاحظ انهبيفرق عندنا بعمل مشكلة
+
+337
+00:31:01,860 --> 00:31:06,820
+بيصير عندى احتمالين يعني لو أخدتوا هذا المركب اللى
+
+338
+00:31:06,820 --> 00:31:13,540
+هو اسمه two bromobutane high carbon اتنين تلاتة
+
+339
+00:31:13,540 --> 00:31:20,820
+اربعة هذا ايش اسمه two bromobutane كل الذرات اللى
+
+340
+00:31:20,820 --> 00:31:27,210
+موجودين عندى عبارة عن ايشهيدروجينز الان انا لما
+
+341
+00:31:27,210 --> 00:31:33,130
+بدي اعمل الحذف بمساعدة ال OH- و لاحظوا كيف بالظبط
+
+342
+00:31:33,130 --> 00:31:38,990
+بتتم عملية الحذف يعني كيف ال OH- هذه بتيجي بتعمل
+
+343
+00:31:38,990 --> 00:31:45,690
+الحذف ال OH- بدها إيش بدها H بلس فبتيجي بتهجم
+
+344
+00:31:45,690 --> 00:31:50,650
+هينفترض هجمت على هذي ال H بلس هى ال OH- أخدت ال H
+
+345
+00:31:50,650 --> 00:31:57,150
+بلس طلعت على شكل جزء إيشماء فهمنا هذه الخطوة
+
+346
+00:31:57,150 --> 00:32:01,390
+الأولى في التفاعل أن الـ OH- هجمت على الـ H أخدتها
+
+347
+00:32:01,390 --> 00:32:08,930
+عملت مية طلعت الآن هذه الرابط اللي ضالة بتلوف بهذا
+
+348
+00:32:08,930 --> 00:32:13,590
+الاتجاه معقول أن يصير خمس روابط إذا إيش هيصير طلوع
+
+349
+00:32:13,590 --> 00:32:21,150
+جبالها للـ PR بتم التفاعل فالـ OH والـ H شو
+
+350
+00:32:21,150 --> 00:32:29,870
+هيعطوني؟H2O طب ال PR minus مع ال NA اللي هنا ما هي
+
+351
+00:32:29,870 --> 00:32:36,450
+ال OH فيه معها إيش NA مش هذه NA plus OH minus
+
+352
+00:32:36,450 --> 00:32:40,230
+Sodium hydroxide ال PR ال minus مع ال NA شو
+
+353
+00:32:40,230 --> 00:32:49,340
+بتعطيني NA PR ال OH مع ال HH2O وبتكون عندى الـ
+
+354
+00:32:49,340 --> 00:32:52,420
+Double bond عشانك لو رجعته مرة تانية بسرعة شوفتوا
+
+355
+00:32:52,420 --> 00:32:59,440
+المعادلة اللى هنا Double bond NABR H2O شوفنا كيف
+
+356
+00:32:59,440 --> 00:33:05,560
+بتكونوا هدول التلاتة الميه انه اجت ال OH أخدت H
+
+357
+00:33:05,560 --> 00:33:10,240
+طلعت ال PR minus ال PR minus لجت ال NA plus عملت
+
+358
+00:33:10,240 --> 00:33:17,130
+معه NABR و المركب العضوى صارDouble bond صار ال
+
+359
+00:33:17,130 --> 00:33:21,750
+keen طبعا انا اللي بهمني كنتيجة اكتر ما يمكن ايش
+
+360
+00:33:21,750 --> 00:33:26,110
+ال organic compound يعني هذه المركبات تحصيل حاصل
+
+361
+00:33:26,110 --> 00:33:33,550
+مافيش فيهامافيش فيها مشكلة الان لاحظوا معاك كلكوا
+
+362
+00:33:33,550 --> 00:33:37,010
+اتفقتوا انه ماناش في ال NA احنا قيلنا في ال OH
+
+363
+00:33:37,010 --> 00:33:42,130
+بدها H مجاورة على هذه ال carbon طب هذه ال OH يا
+
+364
+00:33:42,130 --> 00:33:45,550
+تورا لو بدل ما تيجي هنا وتاخد H من هدول اللي على
+
+365
+00:33:45,550 --> 00:33:52,990
+الشمال لو كانت من أهل اليمين اجت ال OH واخدت هذه
+
+366
+00:33:52,990 --> 00:34:01,220
+ال H وارد ولا لأ؟خلّينا نشطب هذا الكلام الأولاني
+
+367
+00:34:01,220 --> 00:34:06,860
+الـ OH بده اتش مجاورة واحدة شمال واحدة يمين إذا
+
+368
+00:34:06,860 --> 00:34:10,720
+أصطدمت بالشمال وين حيصير الالكين؟ على هذا الموقع،
+
+369
+00:34:10,720 --> 00:34:16,140
+حيطلع هذا النتج طب لو أخدت هذه الـ H هاي ميل، هذه
+
+370
+00:34:16,140 --> 00:34:19,820
+وين بده تيجي على طول؟ هان، بده يتكون عندي أي
+
+371
+00:34:19,820 --> 00:34:24,740
+ألكين؟ ألكين، تاني الـ two butane في الحالة
+
+372
+00:34:24,740 --> 00:34:29,550
+الأولى، الوان بيوتينإذا لو في عندي أكثر من
+
+373
+00:34:29,550 --> 00:34:33,690
+الهيدروجين مجاورة أو كانوا مختلفات متوقع يطلع عندي
+
+374
+00:34:33,690 --> 00:34:39,170
+أكثر من ال keen لو كانوا متشابهات زي المثال السابق
+
+375
+00:34:39,170 --> 00:34:46,290
+يعني هنا CH3 و CH3 زي بعض ناتج واحد لما اختلفوا
+
+376
+00:34:46,290 --> 00:34:53,190
+صار هنا CH3 و هنا CH2 و CH3 صارواتخيل لو هنا كان
+
+377
+00:34:53,190 --> 00:34:59,030
+في مجموعة تالتة اذا ممكن يطلع عندى كام ناتج تلاتة
+
+378
+00:34:59,030 --> 00:35:03,990
+ممكن يكون النواتج اللى عندى مش بس اتنين ممكن يطلع
+
+379
+00:35:03,990 --> 00:35:10,290
+عندى تلت نواتج حدث يعني لو تخيلتوا ان هى عندى Cبر
+
+380
+00:35:10,290 --> 00:35:15,750
+وحطيت على جهة منها CH3 وهي نوع من الهيدروجينز
+
+381
+00:35:15,750 --> 00:35:24,570
+وحطيت على الجهة التانية CH2 CH3 هي مجموعة تانية
+
+382
+00:35:24,570 --> 00:35:35,590
+وحطيت على الجهة التالتة CH2 CH2 CH2 CH3هي مركّب
+
+383
+00:35:35,590 --> 00:35:41,030
+الان الشيء الأكيد اللي بدى أحذفه انا شهو هو ال PR
+
+384
+00:35:41,030 --> 00:35:48,250
+هاي ال PR حذفناها و hydrogen من الكربون المجاورة
+
+385
+00:35:48,250 --> 00:35:52,470
+لو حذفت من هنا وين هتصير ال double bond؟ ع هذا
+
+386
+00:35:52,470 --> 00:35:55,890
+الموقع لو حذفت من هنا وين هتصير ال double bond؟ ع
+
+387
+00:35:55,890 --> 00:35:58,410
+هذا الموقع
+
+445
+00:40:23,530 --> 00:40:25,170
+افدالين افدالين افدالين افدالين افدالين افدالين
+
+446
+00:40:25,170 --> 00:40:25,250
+افدالين افدالين افدالين افدالين افدالين افدالين
+
+447
+00:40:25,250 --> 00:40:28,010
+افدالين افدالين افدالين افدالين افدالين افدالين
+
+448
+00:40:28,010 --> 00:40:37,750
+افدالين افدالين افدالين افدالين
+
+449
+00:40:37,750 --> 00:40:44,260
+افدالالان اذا هذه لاتش نفترض كانت هذا المركب R
+
+450
+00:40:44,260 --> 00:40:49,020
+وهنا كان R قلتلكوا هذا كم substitution عليه اتنين
+
+451
+00:40:49,020 --> 00:40:54,860
+اذا مين more substituted هذا ولا الاتين هذا هذا
+
+452
+00:40:54,860 --> 00:40:59,000
+مافيش عليه ولا ابدال الاتين مافيش عليه ولا ابدال
+
+453
+00:40:59,000 --> 00:41:02,460
+ولا هيدروجينة ابدلة هذا كم ابدال عليه اتنين طيب لو
+
+454
+00:41:02,460 --> 00:41:08,450
+قلتلكوا هذا المركب ولا هذاهذا كام إبدال عليه اللي
+
+455
+00:41:08,450 --> 00:41:13,690
+جابله طب لو حطينا هنا كمان R أربعة which is more
+
+456
+00:41:13,690 --> 00:41:17,810
+substituted واضح الفكرة إيش معنى more substituted
+
+457
+00:41:17,810 --> 00:41:23,490
+كل ما صار عليه مجموعات R أكثر الآن لو إجينا و
+
+458
+00:41:23,490 --> 00:41:26,970
+اتطلعنا على هدول التلان فصلولي حوالين ال double
+
+459
+00:41:26,970 --> 00:41:30,610
+bond يعني قولوا هذه double bond هنا إيش موجود
+
+460
+00:41:30,610 --> 00:41:33,790
+عندكم إبدلات؟ لا
+
+461
+00:41:36,790 --> 00:41:43,570
+و هان H هذي اللي شطبناها و هان K إذا هذا لو بدكوا
+
+462
+00:41:43,570 --> 00:41:49,770
+تقارنوه بال إثليين كام إفدال عليه حقيقة؟ واحد لو
+
+463
+00:41:49,770 --> 00:41:54,550
+هذه تنشر و تصير H بيبطل مبدل إذا هذا كام إفدال
+
+464
+00:41:54,550 --> 00:41:58,970
+عليه؟ واحد طب لو إجيت على المركب التاني هاي ال
+
+465
+00:41:58,970 --> 00:42:05,590
+double bond هنا إيش في عندكم؟ H و هنا فصلتهم
+
+466
+00:42:06,370 --> 00:42:13,290
+وهنا تطلعوا إيش في عندكم؟ carbon إذا هذه مقدلة
+
+467
+00:42:13,290 --> 00:42:20,510
+وهنا carbon إذا هذا كام إبدال؟ اتنين which is more
+
+468
+00:42:20,510 --> 00:42:24,670
+substituted ال two butyl is more substituted than
+
+469
+00:42:24,670 --> 00:42:30,950
+one butyl فهذا اللي بيكون major product شوفته كيف؟
+
+470
+00:42:31,530 --> 00:42:35,370
+الـ two butane is more substituted لأنه في
+
+471
+00:42:35,370 --> 00:42:38,810
+مجموعتين ألكل على ال double bond أنا بس بتطلع على
+
+472
+00:42:38,810 --> 00:42:42,610
+أطراف ال double bond و لحد الأقصى للإبدال جديش
+
+473
+00:42:42,610 --> 00:42:48,110
+أربعة هنا في عندى إبدال واحد هنا في عندى اتنين
+
+474
+00:42:48,710 --> 00:42:54,390
+ابدالين اذا this compound is more substituted than
+
+475
+00:42:54,390 --> 00:42:58,790
+this compound واضح الفكرة اللي more substituted هو
+
+476
+00:42:58,790 --> 00:43:04,510
+بيكون ال major product خليني اعطيكم سؤال homework
+
+477
+00:43:04,510 --> 00:43:08,730
+اتجربوا تعملوه و بننهي فيه لو يا ترى حطينا هذا
+
+478
+00:43:08,730 --> 00:43:14,690
+المركب و حطينا لكم ب ا حطينا هنا c H3 و حطينا هنا
+
+479
+00:43:14,690 --> 00:43:24,890
+عند اللزوم H و هنا حطينا CHCH3 وانا كمان حطينا CH3
+
+480
+00:43:24,890 --> 00:43:33,170
+تانية الان اكتبولي نواتج الابدال و اقولولي اي واحد
+
+481
+00:43:33,170 --> 00:43:39,530
+فيهم ال major يعني هذا بدياه مع ال OH minus يعمل
+
+482
+00:43:39,530 --> 00:43:45,900
+ابدال elimination هو اكيد بيعملعفوا الحدث نواتج
+
+483
+00:43:45,900 --> 00:43:51,160
+الحدث اكتبولي نواتج الحدث الممكنة و اي واحد منهم
+
+484
+00:43:51,160 --> 00:43:58,080
+ال major product الان بالتأكيد مع الحدث فيه كمان
+
+485
+00:43:58,080 --> 00:44:03,980
+ايش ابدال يعني بمعنى ان هذا التفاعل لا يلفك دائما
+
+486
+00:44:03,980 --> 00:44:10,140
+بطلع فيه ناتج ابدالوناتج حذف بنسبة مختلفة حسب ظروف
+
+487
+00:44:10,140 --> 00:44:14,980
+التفاعل وحسب عوامل كتير بتأثر لكن احنا الآن سؤالنا
+
+488
+00:44:14,980 --> 00:44:21,260
+بد نواتج الحذف الممكن لهذا التفاعل واي ناتج من
+
+489
+00:44:21,260 --> 00:44:27,340
+هدول النواتج اللي هو يعتبرالـ major product ضايل
+
+490
+00:44:27,340 --> 00:44:31,260
+عندنا شغلتين صغار بدون دقيقتين عشان المرة الجاية
+
+491
+00:44:31,260 --> 00:44:35,840
+نبدأ المركب من أول و جديد هذه ال slides اللي عندكم
+
+492
+00:44:35,840 --> 00:44:42,280
+كلها مركبات تطبيقية لهنوجين compounds يعنيالـ
+
+493
+00:44:42,280 --> 00:44:44,700
+Methyl bromide يستعمل في الزراعة، الـ
+
+494
+00:44:44,700 --> 00:44:47,940
+Dichloromethane يستعمل solvent، الchloroform
+
+495
+00:44:47,940 --> 00:44:52,680
+solvent، التفلون مار عليكم، اتذكرينه ولا لأ؟
+
+496
+00:44:52,680 --> 00:44:57,300
+المركبات اللي فيها كلور و فلورو كاربون بيستعملوها
+
+497
+00:44:57,300 --> 00:45:02,630
+غازات ثلاجات بنسميها chlorofluorocarbonsمن ضمنها
+
+498
+00:45:02,630 --> 00:45:07,610
+الفريون اللي بتدمر طبقة الأوزون لاحظوا الـCFC شو
+
+499
+00:45:07,610 --> 00:45:12,290
+معناها؟ اكلورو فلورو كاربون يعني هي كلور هي فلور
+
+500
+00:45:12,290 --> 00:45:16,750
+هي كاربون صار اسمها الـCFC فيها كلور و فلور مين
+
+501
+00:45:16,750 --> 00:45:21,930
+اللي طلع زعلان؟ كاربون لأ البروم الهالوجين الأساسي
+
+502
+00:45:21,930 --> 00:45:27,650
+شمه؟ كلور و فلور برومطب هذه المراكبات ال CFCs فيها
+
+503
+00:45:27,650 --> 00:45:32,770
+كلور و فلور فيها بروم؟ طب لو حطينا عليها بروم شو
+
+504
+00:45:32,770 --> 00:45:38,630
+بيصير اسمها؟ هالونز بيصير كلور و فلور و كاربونز و
+
+505
+00:45:38,630 --> 00:45:43,090
+فيهم بروم بيصيروا هالونز عارفين شو ال هالونز؟
+
+506
+00:45:43,090 --> 00:45:46,630
+اتطلع على الطفاية اللى على باب القاعة اللى عادة
+
+507
+00:45:46,630 --> 00:45:50,570
+اللى غطى أخضر هذه طفيات بدي استعملها لإطفاء حرائق
+
+508
+00:45:50,570 --> 00:45:55,210
+الكهربا وغيرها طفاية الغازغازات اللى بتتعبى فى
+
+509
+00:45:55,210 --> 00:45:58,910
+الطفاية اسمهم إيه؟ hellons لو قولنا لكوا شو ال
+
+510
+00:45:58,910 --> 00:46:04,190
+hellons؟ ال chlorofluorocarbons حملين بروم يعنى
+
+511
+00:46:04,190 --> 00:46:07,270
+chlorofluorobromocarbons
+
+512
+00:46:07,270 --> 00:46:12,310
+واضح؟ وكتيرة وكل اسم اللى لها اسم تجارى بنباعه و
+
+513
+00:46:12,310 --> 00:46:16,610
+بنشره و بنعبى فى الطفاية ابهيك بننتهى من chapter
+
+514
+00:46:16,610 --> 00:46:19,710
+ال alkalites ان شاء الله المرة القادمة بنبتدى فى
+
+515
+00:46:19,710 --> 00:46:21,670
+موضوع ال algorithms
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..166903a08d291ea6ec2848df29ff53ccf15fa365
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU.srt
@@ -0,0 +1,1626 @@
+
+1
+00:00:19,570 --> 00:00:24,470
+بسم الله الرحمن الرحيم اليوم إن شاء الله بنشرح
+
+2
+00:00:24,470 --> 00:00:31,450
+معلومات أيضا مختصرة على موضوع ال carbohydrates جزء
+
+3
+00:00:31,450 --> 00:00:39,870
+من ال biochemistry طبعا ال carbohydrates هم أكثر
+
+4
+00:00:40,850 --> 00:00:46,930
+جزيئات يمكن موجودة في الطبيعة من الجزيئات الحيوية
+
+5
+00:00:46,930 --> 00:00:51,770
+يمكن البعض يستغرب لكن لما تفكروا بس قداش في
+
+6
+00:00:51,770 --> 00:00:57,810
+بالدنيا نباتات و النباتات بشكل أساسي cellulose و
+
+7
+00:00:57,810 --> 00:01:03,430
+ال cellulose هو عبارة عن carbohydrates هذا الكلام
+
+8
+00:01:03,430 --> 00:01:09,890
+يمكن يعطيكم إيش فكرة بشكل عام ال carbohydrates
+
+9
+00:01:09,890 --> 00:01:16,010
+الصيغة تبعتهم هي عبارة عن carbon مع مية مكررين
+
+10
+00:01:16,010 --> 00:01:21,890
+يعني CH2O to the N فمن هنا إجت فكرة carbohydrates
+
+11
+00:01:21,890 --> 00:01:29,250
+يعني ال carbons وبعدين المية Carbons وميّه واضح
+
+12
+00:01:29,250 --> 00:01:34,130
+فعلى سبيل المثال يعني لو بدكوا تاخدوا أنتوا أبسط
+
+13
+00:01:34,130 --> 00:01:42,510
+سكر .. أبسط سكر اللي هو C6H12O6
+
+14
+00:01:42,510 --> 00:01:51,010
+الآن بنقدر نقول هذا عبارة عن 6 في C وH2O
+
+15
+00:01:51,010 --> 00:01:58,700
+فهو مضاعف لل Carbon و الميّه واضح؟ C6H12O6
+
+16
+00:01:58,700 --> 00:02:04,900
+واضح الفكرة؟ ومن هنا إجا الاسم carbohydrate لأنه
+
+17
+00:02:04,900 --> 00:02:11,740
+بشكل أساسي الصيغة البسيطة تبعته هي عبارة عن carbon
+
+18
+00:02:11,740 --> 00:02:17,700
+وميه واضح هذه الفكرة؟ يعني لما نيجي نسألكم أن ال
+
+19
+00:02:17,700 --> 00:02:20,660
+carbohydrates الصيغة الأساسية بتاعتهم carbon و
+
+20
+00:02:20,660 --> 00:02:25,540
+oxygen carbon و hydrogen لأ لو كربون و هيدروجين كال
+
+21
+00:02:25,540 --> 00:02:30,800
+سمناها hydrocarbon لكن carbohydrate يعني كربون و
+
+22
+00:02:30,800 --> 00:02:35,840
+مياه الآن ال carbohydrates ببساطة احنا بنقدر
+
+23
+00:02:35,840 --> 00:02:41,260
+نتخيلها اذا بنفهمها بالشكل القاتل هي عبارة عن
+
+24
+00:02:41,260 --> 00:02:47,540
+جزيئات في الغالب كبيرة يعني ممكن نتخيل ان هذا جزيئ
+
+25
+00:02:48,170 --> 00:02:55,070
+كبير أشبه ما تكون بوليمار تمام الآن هذه الجزيئات
+
+26
+00:02:55,070 --> 00:02:59,650
+الكبيرة بنسميها احنا polysaccharides يعني سكريات
+
+27
+00:02:59,650 --> 00:03:05,720
+أشمالها عديدة لو عملنا لها hydrolysis في وجود حمض
+
+28
+00:03:05,720 --> 00:03:12,200
+ميه بتتكسر الى جزيئات أصغر من وحدتين او تلاتة هذه
+
+29
+00:03:12,200 --> 00:03:16,980
+الجزيئات الأصغر بنسميها oligosaccharides يعني هي
+
+30
+00:03:16,980 --> 00:03:21,780
+كانت الكبيرة polysaccharide اتكسرت الى
+
+31
+00:03:21,780 --> 00:03:26,720
+oligosaccharides سكريات بسيطة زى السكريات الثنائية
+
+32
+00:03:26,720 --> 00:03:31,770
+هتمر علينا الان لو كسرناها أكتر بصير عندى
+
+33
+00:03:31,770 --> 00:03:37,150
+monosaccharides اللى هو السكر المنفرد فإحنا لما
+
+34
+00:03:37,150 --> 00:03:41,750
+بدنا ندرس الآن بهذا الفصل و نتعرف على السكريات
+
+35
+00:03:41,750 --> 00:03:47,110
+هيكون المحور تبعنا بسيط جدا هنبدأ نقول إيش والله
+
+36
+00:03:47,110 --> 00:03:53,090
+ال monosaccharides المنفرد بعد هيك من اكثر من
+
+37
+00:03:53,090 --> 00:03:57,690
+monosaccharide هنعمل disaccharide اللي هو نوع من
+
+38
+00:03:57,690 --> 00:04:01,970
+ال oligosaccharide هيطلع عند السكاروز والملتوز
+
+39
+00:04:01,970 --> 00:04:06,430
+والاشياء هذه اللي هي واضح؟ الآن من ال
+
+40
+00:04:06,430 --> 00:04:11,950
+oligosaccharides هنعمل الجزيئات الكبيرة بشكل أساسي
+
+41
+00:04:11,950 --> 00:04:17,870
+النشا ال starch و ال cellulose واضح؟ فاحنا هنمشي
+
+42
+00:04:17,870 --> 00:04:22,110
+بهذا التدريج أن نتعرف في البداية شو هي ال
+
+43
+00:04:22,110 --> 00:04:27,120
+monosaccharides شو معناه sugar منفرد لوحده الآن بعد
+
+44
+00:04:27,120 --> 00:04:32,160
+هيك اتنين من الشجر المنفرد هيعملولي Dysaccharide
+
+45
+00:04:32,160 --> 00:04:36,280
+اللي هو يعتبر نوع من ال Oligosaccharides و بعدين
+
+46
+00:04:36,280 --> 00:04:41,180
+لو اتحدوا ال Dysaccharides بشكل كبير عدد كبير منهم
+
+47
+00:04:41,180 --> 00:04:46,140
+بيعطينا ال إيش ال polysaccharides على سبيل المثال
+
+48
+00:04:46,140 --> 00:04:52,890
+النشا polysaccharide النشط بولي ساكرايد لو عملنا له
+
+49
+00:04:52,890 --> 00:04:58,510
+هيدروليسيز بيعطينا داي ساكرايد اللي هو الملتوز
+
+50
+00:04:58,510 --> 00:05:03,950
+فالملتوز أوليغو ساكرايد أو داي ساكرايد ما هو الداي
+
+51
+00:05:03,950 --> 00:05:08,910
+أحد أنواع الأوليغو ساكرايد الآن لو الملتوز كسرناه
+
+52
+00:05:08,910 --> 00:05:16,240
+للوحدات الأساسية هو مكون من وحدتين جولوكوز الملتوز
+
+53
+00:05:16,240 --> 00:05:21,220
+من وحدتين جولوكوز واضح الفكرة فالجولوكوز مونو
+
+54
+00:05:21,220 --> 00:05:27,760
+ساكرايد الملتوز داي ساكرايد الاسترش بوني ساكرايد
+
+55
+00:05:27,760 --> 00:05:34,260
+واضح طبعا اللي بده يبتدى الان يتعرف إيش هم المونو
+
+56
+00:05:34,260 --> 00:05:37,300
+ساكرايد إيش هم المونو ساكرايد
+
+57
+00:05:40,150 --> 00:05:45,650
+ال sugar بنعرفهم انهم polyhydroxyaldehydes او
+
+58
+00:05:45,650 --> 00:05:49,670
+polyhydroxyketones ال polyhydroxyaldehydes بنسميهم
+
+59
+00:05:49,670 --> 00:05:54,130
+ال doses و ال polyhydroxyketones كيتوزز بمعنى
+
+60
+00:05:54,130 --> 00:06:01,070
+الشجر لازم يكون فيه يا aldehyde يا كيتون مع
+
+61
+00:06:01,070 --> 00:06:09,170
+مجموعات OH كتيرة اكثر من مجموعة OH ولذلك لو احنا
+
+62
+00:06:09,170 --> 00:06:13,850
+اتطلعنا مثلا على المركب اللى موجود عندنا هنا اللى
+
+63
+00:06:13,850 --> 00:06:19,570
+هو الجليسرال ديهايد هل يترى هذا يمكن انه يتصنف
+
+64
+00:06:19,570 --> 00:06:27,510
+بمنطق الكيميا ك sugar في عندي هنا الديهايد وفى
+
+65
+00:06:27,510 --> 00:06:35,050
+عندي هنا مجموعات OH إذا هذا بولي هيدروكسي الديهايد
+
+66
+00:06:35,050 --> 00:06:39,330
+يعني عديد هيدروكسي ال الديهايد ولذلك هذا بنقول عنه
+
+67
+00:06:39,330 --> 00:06:45,550
+إيش ال dose ال dose يعني sugar من ال الديهايد طيب
+
+68
+00:06:45,550 --> 00:06:50,570
+ال dye هيدروكسي أسيتون بتعرفوا ال أسيتون CH3C
+
+69
+00:06:50,570 --> 00:06:55,130
+double bond O CH3 شيلت H حطيت مكان هنا OH وكمان
+
+70
+00:06:55,130 --> 00:07:01,270
+هنا OH صار Dihydroxy-13-Dihydroxyacetone الآن هذا
+
+71
+00:07:01,270 --> 00:07:08,050
+الـDihydroxyacetone فيه كيتون وفيه
+
+72
+00:07:08,050 --> 00:07:14,870
+مجموعات OH إذا هذا عبارة عن بوليهيدروكس كيتون
+
+73
+00:07:14,870 --> 00:07:20,010
+بوليهيدروكس كيتون إذا هذا sugar كيتوز
+
+74
+00:07:21,950 --> 00:07:27,190
+ليش؟ لأنه جاي من كيتون، الدوز من ال الديهايد، واضح
+
+75
+00:07:27,190 --> 00:07:34,110
+الفكرة؟ الآن لو اتطلعت على ال glycerol، ال
+
+76
+00:07:34,110 --> 00:07:37,950
+glycerol او ال glycerin، فيه بس ال O H's، مافيه
+
+77
+00:07:37,950 --> 00:07:43,190
+الديهايد او كيتون، فهل ال glycerin بنصنفه انه
+
+78
+00:07:43,190 --> 00:07:46,930
+sugar كيميائيا؟ لأ واضح الفكرة؟ يعني لما نيجي
+
+79
+00:07:46,930 --> 00:07:51,410
+نقولكم glycerol can be classified as a sugar او is
+
+80
+00:07:51,410 --> 00:07:54,630
+classified as a sugar، لأ، لو قلنالكوا
+
+81
+00:07:54,630 --> 00:08:01,810
+dihydroxyacetone is an aldose، فهمته؟ او لو
+
+82
+00:08:01,810 --> 00:08:07,390
+قلنالكوا glyceraldehyde is equitoseglial aldehyde
+
+83
+00:08:07,390 --> 00:08:11,630
+is an aldose, dihydroxyacetone is a ketose تفهمنا
+
+84
+00:08:11,630 --> 00:08:15,710
+بالظبط إذا إيش معنى sugar، إيش معنى aldose، إيش
+
+85
+00:08:15,710 --> 00:08:20,550
+معنى ketose، واضحة الفكرة؟ والشجر لازم ينوجد فيه
+
+86
+00:08:20,550 --> 00:08:26,790
+كام شغلة؟ شغلتين، يا الديهيد، يا كيتون، ومجموعات
+
+87
+00:08:26,790 --> 00:08:35,230
+الـ OH، هذا اللي بدنا نصنفه sugar لو بدنا ننطلق من
+
+88
+00:08:35,230 --> 00:08:40,850
+ال glyceraldehyde، ال glyceraldehyde كم carbon كان
+
+89
+00:08:40,850 --> 00:08:47,710
+فيه؟ تلاتة، تلاتة، احنا بدنا نعلمكوا العد، تلاتة،
+
+90
+00:08:47,710 --> 00:08:49,670
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+91
+00:08:49,670 --> 00:08:51,370
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+92
+00:08:51,370 --> 00:08:58,720
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تهي الديهيد و
+
+93
+00:08:58,720 --> 00:09:02,360
+أكتر من جمعة أواتش هذا بنقول عنه تيتروز تيتروز
+
+94
+00:09:02,360 --> 00:09:09,430
+يعني سكر إيش من أربع كربونات طب لو كانوا خمسة بنتوز
+
+95
+00:09:09,430 --> 00:09:14,530
+لو كانوا ستة هكسوز طبعا هذه كلها اللي موجودة عندنا
+
+96
+00:09:14,530 --> 00:09:20,150
+لأن الجزء الأول فيها الديهيد they are all doses طب
+
+97
+00:09:20,150 --> 00:09:25,830
+لو كان فيها كيتون برضه هذا تتروز وبنتوز وهكسوز لكن
+
+98
+00:09:25,830 --> 00:09:31,590
+هذه إيش كيتوز واضح؟ الان كل واحد هياخد اسم تفصيلي
+
+99
+00:09:31,590 --> 00:09:36,490
+بس بشكل عام ممكن السكر يكون من تلات ذرات من أربعة
+
+100
+00:09:36,490 --> 00:09:41,610
+من خمسة من ستة يعني هدولة خلينا نقول الاش المشهورين
+
+101
+00:09:41,610 --> 00:09:48,410
+الآن لو بدنا نتطلع في ال sugars و اتطلعنا على أبسط
+
+102
+00:09:48,410 --> 00:09:54,770
+واحد فيهم ال glyceraldehyde ع طول هنلاحظ أن هذا ال
+
+103
+00:09:54,770 --> 00:10:00,310
+glyceraldehyde فيه chiral center يعني لو اتطلعنا
+
+104
+00:10:00,310 --> 00:10:03,210
+ال C double bond OH اللي هو جزء ال aldehyde هذا
+
+105
+00:10:03,210 --> 00:10:06,090
+مافيش فيه chiral center ال chiral center أربع
+
+106
+00:10:06,090 --> 00:10:12,980
+مجموعاتمختلفة، الآن ال CH2OH الأخيرة مافيها chiral
+
+107
+00:10:12,980 --> 00:10:19,460
+center، الكاربون الوسطني هادي فيها chiral center
+
+108
+00:10:19,460 --> 00:10:22,940
+الكربون الوسطاني اللي موجود عندنا فيها chiral
+
+109
+00:10:22,940 --> 00:10:28,920
+center الآن لاحظوا معي انه في ال sugars في ال
+
+110
+00:10:28,920 --> 00:10:34,760
+sugars هذه جزيئات شوية كبيرة وكل واحد ممكن يرسمها
+
+111
+00:10:34,760 --> 00:10:38,880
+بطريقة معينة يعني واحد ممكن يرسم واقف نايم مائل
+
+112
+00:10:38,880 --> 00:10:45,000
+عشان يسهلوا تبعون ال biochemistry على بعض المتابعة
+
+113
+00:10:45,000 --> 00:10:52,080
+اتفقوا إنه يوحدوا طريقة الرسم، يعني ليش أضلني أتعب
+
+114
+00:10:52,080 --> 00:10:55,680
+الطالب مرة أحط مجموعة الالديهايد يمين، مرة شمال،
+
+115
+00:10:55,680 --> 00:10:59,820
+مرة فوق، مرة تحت، بره أرسم الجزء مائل، في كل لحظة
+
+116
+00:10:59,820 --> 00:11:04,670
+هو بيصير بحاجة إلى مزيد من التفكير و من الوقت عشان
+
+117
+00:11:04,670 --> 00:11:10,530
+يفهم إيش شكل الجزء فقالوا إيش المانع؟ إيش المانع؟
+
+118
+00:11:10,530 --> 00:11:15,910
+إن نوحد طريقة الرسم لما نرسم ال sugars بدل ما كل
+
+119
+00:11:15,910 --> 00:11:18,650
+واحد يرسمه بطريقة معينة و نقعد نقول وين ال
+
+120
+00:11:18,650 --> 00:11:22,350
+aldehyde وين ال OHS وين ال chiral center ليش ما
+
+121
+00:11:22,350 --> 00:11:29,310
+نرسم بطريقة موحدة؟ بنسهل على الناس تمام؟ طيب إيش
+
+122
+00:11:29,310 --> 00:11:33,910
+فكرة الرسم بالطريقة الموحدة؟ جال خلّي المجموعة
+
+123
+00:11:33,910 --> 00:11:37,210
+اللي هي الكبيرة ال carbon اللي حاملة أعلى إشي اللي
+
+124
+00:11:37,210 --> 00:11:42,630
+هي ال aldehyde تكون لفوق و ارسم بهذا الشكل العمودي
+
+125
+00:11:42,630 --> 00:11:46,950
+واضح؟ يعني نخلي مجموعة ال aldehyde أو ال keto اللي
+
+126
+00:11:46,950 --> 00:11:54,970
+وجدت لأعلى و بنرسم بشكل عموديطبعا اخر شئ هنا هيكون
+
+127
+00:11:54,970 --> 00:12:03,090
+عندى CH2OH الان إيش ضال عندى على الوسط OH OH ضال
+
+128
+00:12:03,090 --> 00:12:09,030
+عندى في الوسط OH OH هذه ال OH OH بالتأكيد طالما
+
+129
+00:12:09,030 --> 00:12:14,830
+هذا chiral center هيكون فيه الجزئ و صورته في
+
+130
+00:12:14,830 --> 00:12:18,490
+المراية حيكون عند الجزء و صورته فى المراية لو
+
+131
+00:12:18,490 --> 00:12:22,630
+جربنا ان نشوف ال configuration إيه لو جربنا نشوف
+
+132
+00:12:22,630 --> 00:12:29,390
+ال configuration إيه هتتذكروا ان هذه أقل مجموعة و
+
+133
+00:12:29,390 --> 00:12:33,570
+ال oxygen أعلى مجموعة بعدين الكاربون اللى متصل
+
+134
+00:12:33,570 --> 00:12:37,490
+مرتين بال oxygen بعدها بعدين الكاربون اللى متصل
+
+135
+00:12:37,490 --> 00:12:41,830
+مرة بال oxygen وبناء على ذلك لو أنا بدي أمشي هى
+
+136
+00:12:41,830 --> 00:12:50,270
+نمره واحدنمرة اتنين، نمرة تلاتة، مبينة كإنها S،
+
+137
+00:12:50,270 --> 00:12:54,830
+لكن لأن هذه المجموعة الصغيرة للأمام، بنعكس ال
+
+138
+00:12:54,830 --> 00:13:01,270
+configuration، إذن هذا R و بالتجربة ال R طلع بلس
+
+139
+00:13:01,270 --> 00:13:04,390
+بتذكرين لما قولنا ال plus و ال minus هذا من قصة
+
+140
+00:13:04,390 --> 00:13:09,330
+بالتجربة بال بولاريمتر الآن هذا بالتأكيد ال
+
+141
+00:13:09,330 --> 00:13:13,490
+enantiomer التاني هو ال S فبناء على ذلك ال
+
+142
+00:13:13,490 --> 00:13:19,650
+glyceraldehyde طالما في one chiral center إذا في
+
+143
+00:13:19,650 --> 00:13:27,060
+منه كام مركب اتنين R و S الآن تابعون ال
+
+144
+00:13:27,060 --> 00:13:32,020
+biochemistry قالوا احنا بنحب الخصوصية مش حابين
+
+145
+00:13:32,020 --> 00:13:36,580
+نظلنا مربوطين في جماعة الكيميا طب ليش يا عم
+
+146
+00:13:36,580 --> 00:13:41,800
+بتزيدوا غلبتنا قال بهمش الطلاب بتحملونا إيش اللي
+
+147
+00:13:41,800 --> 00:13:48,740
+بدكمياه قال بدل ما نستعمل ال R و ال S نستعمل D و L
+
+148
+00:13:50,330 --> 00:13:54,210
+هما لو ضالوا على ال R و ال S العلم بيمشي لكن قرروا
+
+149
+00:13:54,210 --> 00:13:59,650
+انهم بيستعملوا D و L الآن ضمن هذا الشكل اللي رسمنا
+
+150
+00:13:59,650 --> 00:14:02,450
+فيه يعني المجموعة هذه ال الدياد أو ال keto اللي
+
+151
+00:14:02,450 --> 00:14:07,630
+فوق قالوا إذا كانت ال OH على ال carbon اللي هي قبل
+
+152
+00:14:07,630 --> 00:14:10,770
+الأخيرة منها يعني هي أخر carbon من تحتها دي اللي
+
+153
+00:14:10,770 --> 00:14:16,010
+قبلها إذا كانت ال OH على اليمين بنعطي للمركب الرمز
+
+154
+00:14:16,500 --> 00:14:22,460
+وإذا كانت ال OH على الشمال بنعطي المركب الرمز L
+
+155
+00:14:22,460 --> 00:14:27,540
+فصيرنا نقول هذا دي إجليسرال ديهيد وهال و هذا
+
+156
+00:14:27,540 --> 00:14:33,000
+الإجليسرال ديهيد الآن هم ركزوا على أي كاربون
+
+157
+00:14:33,000 --> 00:14:38,980
+تحديدا حاملة ال OH ال OH اللي جابلي الأخيرة، ليش؟
+
+158
+00:14:38,980 --> 00:14:42,820
+لأنه بعد شوية .. بعد شوية حيصير عندي أكثر من
+
+159
+00:14:42,820 --> 00:14:47,580
+Carbon بتحمل OH OH OH OH و أكثر من chiral center
+
+160
+00:14:47,580 --> 00:14:52,680
+مين فيهم اللي بدي أوصفه أنه D أو L؟ وين بدي أطلع؟
+
+161
+00:14:52,680 --> 00:14:56,940
+بدي أطلع مش على آخر Carbon، آخر Carbon مش chiral
+
+162
+00:14:56,940 --> 00:15:02,660
+أول Carbon chiral من تحت، اللي هي نمرة 2، لأن هو
+
+163
+00:15:02,660 --> 00:15:08,570
+اللي مش chiral واضح فلما انا بدي بعد شوية اصير اطلع
+
+164
+00:15:08,570 --> 00:15:15,310
+هيك على شكله و اقول هذا D ولا L بدي اطلع وين من
+
+165
+00:15:15,310 --> 00:15:23,190
+التحت طبعا هنا في عندي scheme كيف ببدأ انا ازيد في
+
+166
+00:15:23,190 --> 00:15:28,070
+مجموعات ال OH يعني اول ما بدأت تلاتة بعد هيك ببدأ
+
+167
+00:15:28,070 --> 00:15:34,930
+ازيد واضح انه هذا ال scheme يمكنا ضعيف جدا و لذلك
+
+168
+00:15:34,930 --> 00:15:41,230
+انا حاولت ان اجزء هذا ال scheme لأشياء لعلها تكون
+
+169
+00:15:41,230 --> 00:15:47,490
+أوضح لاحظوا معي بالنسبة لل glyceral dehyd هي ال OH
+
+170
+00:15:47,490 --> 00:15:52,200
+هنا على اليمين اذا انا جيبت بس منه إيش؟ ال D
+
+171
+00:15:52,200 --> 00:15:57,540
+-Glyceraldehyde الان يا ترى لو بدى ازيد كربون تاني
+
+172
+00:15:57,540 --> 00:16:03,280
+على ال D-Glyceraldehyde وين بدى اجي احطها؟ بهذا
+
+173
+00:16:03,280 --> 00:16:14,060
+الموقع واضح؟ هذه الكربون حاملة وح وح وح
+
+174
+00:16:14
+
+223
+00:20:31,490 --> 00:20:36,690
+عاليمين، الآن بنصير نقول شو هو الرايبوز؟ الرايبوز
+
+224
+00:20:36,690 --> 00:20:40,790
+السكر الخماسي اللي تلت مجموعات ال OH في جين ع جهة
+
+225
+00:20:40,790 --> 00:20:46,690
+واحدة، الآن الارابينوز شو هو السكر الخماسي اللي
+
+226
+00:20:46,690 --> 00:20:50,930
+هدولة بتنتنع جهة وادي على جهة تانية، لحظوا قاعدة
+
+227
+00:20:50,930 --> 00:20:57,170
+بتكتر المركبات عندي، هذا خمس درات كربون، واحد اتنين
+
+228
+00:20:57,170 --> 00:21:02,690
+تلاتة اربعة خمسة، بكم chiral center؟ تلاتة، طالما
+
+229
+00:21:02,690 --> 00:21:07,410
+عندي تلاتة chiral center اذا كم مركب؟ تمانية، وين
+
+230
+00:21:07,410 --> 00:21:16,070
+التمانية؟ 4D و 4R بالظبط، واضحة؟
+
+231
+00:21:16,070 --> 00:21:22,770
+أنا هنا بس أخدت الاريثروز وجسمته، يتبعوا معك هذا
+
+232
+00:21:22,770 --> 00:21:28,590
+بس اللي نتج من الاريثروز لما أجسم للثريوز بيعطيني
+
+233
+00:21:28,590 --> 00:21:35,410
+كمان اتنين اتنين، واتنين اربع اربع وهكذا، واضح؟
+
+234
+00:21:35,410 --> 00:21:36,430
+هاي للثريوز
+
+235
+00:21:40,860 --> 00:21:44,360
+خلينا هذا اللي اتعودنا نقول عنه دي نخليه باللون
+
+236
+00:21:44,360 --> 00:21:48,780
+الأخضر، هذا السكر التالي للاريثروز، مش احنا قلنا
+
+237
+00:21:48,780 --> 00:21:57,060
+الاريثروز و الاثريوز، الاريثروز بيقسم لاتنين، هاهم
+
+238
+00:21:57,060 --> 00:22:01,760
+و الاثريوز بيقسم لاتنين تانيين، الآن الاثنين اللي
+
+239
+00:22:01,760 --> 00:22:05,820
+بيقسملهم الاثريوز بياخدوا اسم اكزايلوز و لاكزوز
+
+240
+00:22:07,610 --> 00:22:13,030
+فصار المجموع من الخماسي اربعة D و اربعة L كده؟
+
+241
+00:22:13,030 --> 00:22:19,030
+تمانية، لو جينا أي واحد من هدولة بدنا نزيد له
+
+242
+00:22:19,030 --> 00:22:25,250
+chiral center، هيقسم لإيش؟ لاتنين، طالما ما تمانية
+
+243
+00:22:25,250 --> 00:22:29,290
+كل واحد يقسم لاتنين هيصير المجموع ستة عشر، كلام
+
+244
+00:22:29,290 --> 00:22:32,650
+منطقي ليش؟ لأنه لما يصير عندي اربعة chiral centers
+
+245
+00:22:32,650 --> 00:22:39,090
+اتنين أقصى أربعة 16، 16 اتنين أقصى أربعة ستة عشر، فلما
+
+246
+00:22:39,090 --> 00:22:43,230
+نيجي نتعرف عليهم، لما نيجي نتعرف عليهم، لو أخدنا
+
+247
+00:22:43,230 --> 00:22:49,250
+مثلا الريبوز، هاي ال OH هذه، زيدنا
+
+248
+00:22:49,250 --> 00:22:53,690
+كايرال center، وين هنا
+
+249
+00:22:53,690 --> 00:23:01,730
+هذا، هيعمل O H مرة يمين ومرة شمال
+
+250
+00:23:03,120 --> 00:23:07,240
+لو أخدنا الأرابينوز برضه وين بدنا نزيد ال OH؟
+
+251
+00:23:07,240 --> 00:23:14,580
+هنا، هتيجي مرة يمين و مرة شمال، الآن هدولة بنبدأ
+
+252
+00:23:14,580 --> 00:23:19,980
+نعطيهم أسماء، اللي كلهم جايين زي بعض سموه ألوز، هذا
+
+253
+00:23:19,980 --> 00:23:25,360
+تلاتة، وبعدين واحدة زي بعض ألتروز، هذا الجولوكوز
+
+254
+00:23:25,360 --> 00:23:31,300
+صاحبنا، اللي بدأ، تحفظ الجولوكوز، يعني من هدول كلهم بدنا
+
+255
+00:23:31,300 --> 00:23:34,860
+نقولكوا بس احفظوا الجولوكوز، كيف ترتيب مجموعاته
+
+256
+00:23:34,860 --> 00:23:39,960
+طبعاً اللي بدها تحفظ الجولوكوز بدها تقولوا one and
+
+257
+00:23:39,960 --> 00:23:44,440
+six carbonate، صحيح؟ الآن ال C double bond OH
+
+258
+00:23:44,440 --> 00:23:51,400
+الالديهايد، هذه لفوق أكيد مافيها نقاش، والـCH2OH هذه
+
+259
+00:23:51,400 --> 00:23:59,040
+لتحت أكيد ولا فيها نقاش؟ الآن لو قلنا Dجولوكوز،
+
+260
+00:23:59,040 --> 00:24:03,900
+إيش معناه دي؟ إنه هذه لازم تكون على اليمين، الآن
+
+261
+00:24:03,900 --> 00:24:08,080
+في دي جولوكوز، بعد ما نحط هذه على اليمين، ضال عنده
+
+262
+00:24:08,080 --> 00:24:16,960
+يمين شمال يمين، ولو كنا جايين الجولوكوز، هتخلوا
+
+263
+00:24:16,960 --> 00:24:22,200
+هذه تيجي هنا، والباقي زي ما هو، واضح؟ يعني اللي بيغير
+
+264
+00:24:22,200 --> 00:24:25,660
+دي، وقل هذه المجموعة، هذه يمين دي، لو قلتلكوا بدي
+
+265
+00:24:25,660 --> 00:24:31,560
+الـL جولوكوز، خدوا هذا ال D وغيروا بس هذه، إذا
+
+266
+00:24:31,560 --> 00:24:36,520
+كانت هذه يمين، دي جولوكوزة، الآن الخلاصة بهذا
+
+267
+00:24:36,520 --> 00:24:44,240
+الشكل، كم sugar طلع عنده؟ 16، 16 sugar، والكلام
+
+268
+00:24:44,240 --> 00:24:49,740
+منطقي، ليش من ال 6 كربونات؟ لأن ال 6 كربونات فيهم 4
+
+269
+00:24:49,740 --> 00:24:55,760
+chiral centers، و المركب مش symmetric، 2 أس 4، 16
+
+270
+00:24:55,760 --> 00:25:02,220
+الان لو بدنا هدول ال 16 ناخد أسماءهم، هاي أربعة
+
+271
+00:25:02,220 --> 00:25:06,020
+منهم، الالوز و الألتروز و الجولوكوز و المانوز، و لو
+
+272
+00:25:06,020 --> 00:25:12,140
+أخدنا الأربعة التانيين اللي في الأساس جوا منالثريوز
+
+273
+00:25:12,140 --> 00:25:16,660
+الجولوز والأيدوز والجالاكتوز والتالوز، الآن هذول
+
+274
+00:25:16,660 --> 00:25:21,460
+تمانية، إيش التمانية التانية؟ كل هدول التمانية دي
+
+275
+00:25:21,460 --> 00:25:30,640
+التمانية التانية، ال L، واضح؟ فبصف عندي ست عشر مركب
+
+276
+00:25:30,640 --> 00:25:37,340
+لل C6، لاحظوا معايا، هدول الست عشر مركب أخذين بعين
+
+277
+00:25:37,340 --> 00:25:42,040
+الاعتبار أن الجولوكوز بهذا الشكل موجود على شكل
+
+278
+00:25:42,040 --> 00:25:48,300
+فاتح مش مسكر، بعد شوية هنيجي نعمل ال cyclic sugar
+
+279
+00:25:48,300 --> 00:25:51,940
+يعني نخليه يسكر على بعضه، كيف بده يسكر على بعضه؟
+
+280
+00:25:51,940 --> 00:25:55,340
+احنا لما شرحنا ال aldehyde قولنا لكم في عندي OH
+
+281
+00:25:55,340 --> 00:25:59,980
+وفي عندي aldehyde، الكحول بتفعل مع ال aldehyde
+
+282
+00:25:59,980 --> 00:26:04,790
+يعطيني hemiacetal، أخدناها كمثال، فبنخلي هذه تسكر
+
+283
+00:26:04,790 --> 00:26:10,310
+هنا، لو هذه سكرت هنا هنعمل ال Cairo Center الخامس
+
+284
+00:26:10,310 --> 00:26:14,930
+وقت كم ايزومار حيصير عندي، إذا صاروا خمس Cairo
+
+285
+00:26:14,930 --> 00:26:22,010
+Centers؟ اتنين أقصى خمسة، إيش؟ اتنين أقصى خمسة؟ اتنين
+
+286
+00:26:22,010 --> 00:26:28,310
+وتلاتين ايزومار، واضح؟ اتنين وتلاتين ايزومار هيكون
+
+287
+00:26:28,310 --> 00:26:39,230
+عندكم من ال C6، من 6 ذرات كربون، لاحظوا كم هو استيريو
+
+288
+00:26:39,230 --> 00:26:42,870
+كيميستر مهم يعني حد ما درسش استيريو كيميستر عمره
+
+289
+00:26:42,870 --> 00:26:48,360
+ممكن يستوعب موضوع ال sugars، مستحيل وهذا الكلام
+
+290
+00:26:48,360 --> 00:26:51,940
+اللي تقريباً احنا كنا حاطينه في ال scheme العام كنا
+
+291
+00:26:51,940 --> 00:26:57,380
+حاطين لكم كيف الزيادة one chiral center تمام
+
+292
+00:26:57,380 --> 00:27:01,660
+بيكونوا تنين، أخدت واحد منهم عملتله زيادة chiral
+
+293
+00:27:01,660 --> 00:27:06,150
+صاروا يعني هن واحد، وفي واحد تاني موجود، يعني لو حد
+
+294
+00:27:06,150 --> 00:27:09,690
+بده يحط ال scheme كاملا بده يجد هذا ال scheme و
+
+295
+00:27:09,690 --> 00:27:12,310
+يحط واحد تاني ليش؟ لأنه أنا هن بدت بال D
+
+296
+00:27:12,310 --> 00:27:17,870
+-Glyceraldehyde، فيه زيه ال glyceraldehyde و بيقسم
+
+297
+00:27:17,870 --> 00:27:24,430
+بنفس الشكل وبياخد نفس الأسماء، طبعاً لاحظوا معي أن
+
+298
+00:27:24,430 --> 00:27:29,740
+الأسماء الأساسية، الأسماء الأساسية كم اسم؟ تمانية
+
+299
+00:27:29,740 --> 00:27:36,860
+الأسماء الأساسية، تمانية اللي هي موجودين
+
+300
+00:27:36,860 --> 00:27:40,560
+عندكم الالوز والألتروز والجولوكوز والمانوز وكذا
+
+301
+00:27:40,560 --> 00:27:47,020
+كذا، الآن كيف التمانية بيصيروا الست عشّر، طبعاً
+
+302
+00:27:47,020 --> 00:27:51,120
+هذا الكلام بإمكانكم أنتم تجلسوا تتدربوا عليه
+
+303
+00:27:51,120 --> 00:27:58,200
+تقرؤوا، زي ما قلنا، مش ضروري أننا بدنا نحفظه، الآن لسه
+
+304
+00:27:58,200 --> 00:28:03,880
+الكيميائيين ما شبعوش، يعني وصلوكوا ل 16 مركب، وبدهم
+
+305
+00:28:03,880 --> 00:28:11,550
+إيش؟ وبدهم اكتر، قالوا طالما أن السكر فيه OH وفي
+
+306
+00:28:11,550 --> 00:28:16,050
+الديهايد، يعني الكحول و الديهايد، نرجع لكيمية ال
+
+307
+00:28:16,050 --> 00:28:20,790
+الديهايد، ماش، كنا نقول إن ال الديهايد بيعمل تفاعل
+
+308
+00:28:20,790 --> 00:28:26,050
+addition مع الكحولات وبيعطيني hemiacetal، ال OH
+
+309
+00:28:26,050 --> 00:28:32,420
+بتهاجم على ال C double bond O تبعت ال الديهايد
+
+310
+00:28:32,420 --> 00:28:39,080
+بتخليها OH، متذكرينه التفاعل ولا نذكر فيه الناس
+
+311
+00:28:39,080 --> 00:28:43,340
+اللي مش متذكرينه التفاعل؟ نكتبها، لما كنا نقول مثلا
+
+312
+00:28:43,340 --> 00:28:51,840
+Methanol، مثل OH، هي نرسمه بالأسود، زائد CH3C double
+
+313
+00:28:51,840 --> 00:29:00,510
+bond OH، هي الكحول، وهي إيش؟ الالديهيد، هذه الكحول
+
+314
+00:29:00,510 --> 00:29:05,190
+وهذه الالديهيد، لو قلنا لكوا في الامتحان اكمل هذه
+
+315
+00:29:05,190 --> 00:29:08,910
+المعادلة، كيف بتفعل الكحول والالديهيد؟ مش هذا
+
+316
+00:29:08,910 --> 00:29:14,550
+نيوكليوفاين بيعمل addition، بيجي بهاجمهان، وهذا
+
+317
+00:29:14,550 --> 00:29:22,690
+بتصير OH، وبناء على ذلك هيكون الناتج CH3C
+
+318
+00:29:22,690 --> 00:29:29,250
+هذا صفية OH، وهذا ال H الأصلية وإيجي عندنا من هناو
+
+319
+00:29:29,250 --> 00:29:34,870
+مثل هذا، شو سمنا؟ Himacetal، Himacetal، Himacetal
+
+320
+00:29:34,870 --> 00:29:39,790
+Himacetal
+
+321
+00:29:39,790 --> 00:29:44,810
+Himacetal، Himacetal، Himacetal، Himacetal، Himacetal
+
+322
+00:29:44,810 --> 00:29:45,610
+Himacetal، Himacetal، Himacetal، Himacetal، Himacetal
+
+323
+00:29:45,610 --> 00:29:45,770
+Himacetal، Himacetal، Himacetal، Himacetal، Himacetal
+
+324
+00:29:45,770 --> 00:29:45,810
+Himacetal، Himacetal، Himacetal، Himacetal، Himacetal
+
+325
+00:29:45,810 --> 00:29:45,890
+Himacetal، Himacetal، Himacetal، Himacetal، Himacetal
+
+326
+00:29:45,890 --> 00:29:47,790
+Himacetal، Himacetal، Himacetal، Himacetal، Himacetal
+
+327
+00:29:47,790 --> 00:29:55,530
+Himacetal، Himacetal، Himacetal
+
+328
+00:29:55,530 --> 00:30:07,430
+Himacetal، HimacetHemiacetal، OR و OR، أسيتال، الآن
+
+329
+00:30:07,430 --> 00:30:12,770
+السكر فيه OH وفي الديهايد، إيش المانع إنهم
+
+330
+00:30:12,770 --> 00:30:19,560
+يسكروا على بعض؟ فيش مانع، وعشان هيك بيصير بيعمل
+
+331
+00:30:19,560 --> 00:30:23,580
+الشكل الحلقي، بنفس منطقة هذا التفاعل، يعني هذا
+
+332
+00:30:23,580 --> 00:30:28,440
+تفاعل تذكير كيف كان الكحول يتفاعل مع إيش؟ مع ال
+
+333
+00:30:28,440 --> 00:30:35,450
+الديهايد، الآن بدنا نرجع لهم في السكر، بدنا نرجع للسكر
+
+334
+00:30:35,450 --> 00:30:41,710
+ونشوف كيف بتم هذا التفاعل، هاي السكر بنرسمه بشكل
+
+335
+00:30:41,710 --> 00:30:46,070
+ملتوى، خليكوا تطلعوا معنا، هاي ال الديهايد، C double
+
+336
+00:30:46,070 --> 00:30:50,430
+bond O، وبعدين carbon حاملة OH و carbon حاملة OH و
+
+337
+00:30:50,430 --> 00:30:56,150
+carbon حاملة OH، وهذه اللي هي ال carbon اللي كانت
+
+338
+00:30:56,150 --> 00:31:00,710
+معطية ال D، اللي هي القبل الأخيرة
+
+339
+00:31:06,670 --> 00:31:14,590
+الان من ناحية المبدأ كل OH من هدول ممكن تسكر على
+
+340
+00:31:14,590 --> 00:31:19,780
+ال الديهايد، يعني نظرياً هذه ال OH ممكن تسكر على ال
+
+341
+00:31:19,780 --> 00:31:23,320
+الديهاد تعطينا حلقة ثلاثية، هذه ممكن تسكر على ال
+
+342
+00:31:23,320 --> 00:31:26,600
+الديهاد تعطينا حلقة رباعية، هذه ممكن تسكر على
+
+343
+00:31:26,600 --> 00:31:30,260
+الديهاد تعطينا حلقات خماسية، هذه ممكن تسكر تعطينا
+
+344
+00:31:30,260 --> 00:31:35,020
+حلقة سداسية، هذه ممكن تسكر تعطينا حلقة سباعية، لكن
+
+345
+00:31:35,020 --> 00:31:41,200
+أشهر إغلاق اللي بيعطي الحلقة السداسية، فال OH اللي
+
+346
+00:31:41,200 --> 00:31:45,600
+بتسكر في حالة الجولوكوز هي ال OH اللي كانت تتحدد
+
+347
+00:31:45,600 --> 00:31:50,620
+ال D وال L، ال OH هذه اللي جاب للاخيرة، الآن هذه بدأ
+
+348
+00:31:50,620 --> 00:31:56,400
+تيجي تسكر هنا، هيصير عندي كايرال سنتر جديد، يعني هذه
+
+349
+00:31:56,400 --> 00:32:01,420
+ال carbon هتعمل إيش؟ كايرال سنتر جديد، طب أنا في
+
+350
+00:32:01,420 --> 00:32:08,060
+الأساس كام كايرال سنتر عندي؟ هي واحد اتنين تلاتة
+
+351
+00:32:08,060 --> 00:32:14,440
+اربعة، ولمّا اجى اعمل هنا الإغلاق هيصيروا إيش؟ خمسة
+
+352
+00:32:15,390 --> 00:32:20,530
+هيصيروا خمسة chiral centers، وبناء على ذلك لاحظوا
+
+353
+00:32:20,530 --> 00:32:25,890
+معاه أن هدولة اللي هم ابعد عن التفاعل بيظلوا زي ما
+
+354
+00:32:25,890 --> 00:32:29,730
+هم، لكن أنا بدي اعمل generation لل chiral center
+
+355
+00:32:29,730 --> 00:32:33,830
+على هذا الكربون تحديدا، بناء على ذلك لما بعمل
+
+356
+00:32:33,830 --> 00:32:37,490
+generation لل chiral center على هذا الكربون إيش
+
+357
+00:32:37,490 --> 00:32:43,330
+بيصير عندي؟ two enantiomers، مظبوط ولا لأ؟ الان
+
+358
+00:32:43,330 --> 00:32:48,470
+هدولة لما بدهم يتموه، طبعا مش two enantiomers، أقفل
+
+359
+00:32:48,470 --> 00:32:51,450
+two diastereomers، ليش؟ لأن أنا مش generation of
+
+360
+00:32:51,450 --> 00:32:55,860
+the first chiral center، احنا قلنا two enantiomars
+
+361
+00:32:55,860 --> 00:33:00,960
+in equal ratios، لو كان إيش؟ اول chiral center، بس
+
+362
+00:33:00,960 --> 00:33:04,700
+هل هذا هو اول chiral center ولا نمرخمسة؟ نمرخمسة
+
+363
+00:33:04,700 --> 00:33:09,580
+نمرخمسة، لما بنعمل chiral center اشديد، second,
+
+364
+00:33:09,940 --> 00:33:13,600
+third, fourth, fifth chiral center، شو كان يطلع
+
+365
+00:33:13,600 --> 00:33:18,860
+عندنا؟ اللي جيبناها سؤال في الامتحان، unequal
+
+366
+00:33:18,860 --> 00:33:24,720
+mixture of diastereomers، متذكرينه؟ generation of a
+
+367
+00:33:24,720 --> 00:33:28,400
+second chiral center، of a third، of a fourth chiral
+
+368
+00:33:28,400 --> 00:33:31,640
+center produces an equal mixture of diastereomers
+
+369
+00:33:31,640 --> 00:33:35,320
+الألم هنا بدنا نشوف كيف هذا بده يصير chiral center
+
+370
+00:33:35,320 --> 00:33:41,720
+ال C ضبط هو بده تصير OH هذه الـOH مرة هتكون للأعلى
+
+371
+00:33:41,720 --> 00:33:50,080
+ومرة هتكون للأسفل، هم
+
+372
+00:33:50,080 --> 00:33:54,910
+لاحظين؟ هي ال chiral center مرة لفوق ومرة لتحت
+
+373
+00:33:54,910 --> 00:34:03,250
+واضح الفكرة؟ الآن في هذا الجزء صار عنده اللي هو ال
+
+374
+00:34:03,250 --> 00:34:07,930
+chiral center الخامس، لحظة، أنا بدأت بأي سكر؟ ال
+
+375
+00:34:07,930 --> 00:34:11,590
+جولوكوز، ال D جولوكوز، الآن ال D جولوكوز أعطاني كم
+
+376
+00:34:11,590 --> 00:34:18,270
+مركب؟ اتنين، طب أنا كل السكريات اللي اتعرفت عليهم
+
+377
+00:34:18,270 --> 00:34:25,650
+قداش كانوا؟ كانوا ستة عشر، تمانية D وتمانية L، إذا ال
+
+378
+00:34:25,650 --> 00:34:30,410
+D جولوكوز أعطى اتنين، الستة عشر، كل واحد فيهم هيعطي
+
+379
+00:34:30,410 --> 00:34:34,950
+اتنين، اتنين، اتنين، اتنين، اتنين، اتنين، بستة عشر اتنين
+
+380
+00:34:34,950 --> 00:34:39,280
+وتلاتين، هي الاتنين والتلاتين I زمرو، واضح؟ الان
+
+381
+00:34:39,280 --> 00:34:42,660
+هدولة اللي جدوا عندنا أجداد جايين من الجولوكوز، و
+
+382
+00:34:42,660 --> 00:34:46,860
+جايين تحديدا من أي جولوكوز؟ من ال D جولوكوز، لما
+
+383
+00:34:46,860 --> 00:34:50,280
+بدنا نميزهم عن بعض، انتم بتقدروا تميزهم تقولوا
+
+384
+00:34:50,280 --> 00:34:57,260
+واحد في ال OH لفوق، واحد في ال OH لتحت، الآن بلغة
+
+385
+00:34:57,260 --> 00:35:01,880
+الكيميا، بنقول اللي بيطلع بهذا الشكل، و ال OH لفوق
+
+386
+00:35:01,880 --> 00:35:08,090
+بنسميه beta، وبنحط الاسم القديم، من وين هذا جاي؟ من
+
+387
+00:35:08,090 -->
+
+445
+00:40:23,460 --> 00:40:30,200
+الان اللي طلع عندنا حقيقة ان ال
+
+446
+00:40:30,200 --> 00:40:37,520
+beta بيطلع بنسبة 64% و ال alpha من الجلوكوز بيطلع
+
+447
+00:40:37,520 --> 00:40:45,380
+بنسبة 36% واضح؟ طبعا ال beta لحاله له زاوية دوران
+
+448
+00:40:45,380 --> 00:40:51,420
+plus 19 و ال alpha لحاله لو فصلوا له زاوية دوران
+
+449
+00:40:51,420 --> 00:40:59,120
+112 الان لو حطيت الخليط تبعهم بطلع زاوية بين
+
+450
+00:40:59,120 --> 00:41:02,700
+التنين ماخدة نسبة بعين الاعتبار الخليط بطلع
+
+451
+00:41:02,700 --> 00:41:10,450
+زاويته حقيقة 52 لاحظوا معي، الآن هذا كله اتزان، هذا
+
+452
+00:41:10,450 --> 00:41:15,750
+كله ايش؟ اتزان، بمعنى، لو أنا بدأت في هذا ال A
+
+453
+00:41:15,750 --> 00:41:21,390
+Cyclic و سبته في المحلول، بعد يوم، ايش هلاجيك؟ في
+
+454
+00:41:21,390 --> 00:41:27,090
+نسبة جليلة من ال Cyclic ضايلة، سكر لهذا و لهذا، و
+
+455
+00:41:27,090 --> 00:41:34,670
+بنسبة 64% إلى 36%، و بخليط الزاوية تبعته تأكد منها
+
+456
+00:41:34,670 --> 00:41:47,210
+بالظبط قداش 52 52 اللي هو ال ash ال mixture الخليط
+
+457
+00:41:47,210 --> 00:41:51,460
+اللي من هذا و من هذا ال A Cyclic له زاوية تانية
+
+458
+00:41:51,460 --> 00:41:55,920
+مالنا و ماله بحكي عن ال mixture اللي من هذا و من
+
+459
+00:41:55,920 --> 00:42:03,260
+هذا بيكون زاوية و قداش 52 طيب يا تورا لو حطينا ال
+
+460
+00:42:03,260 --> 00:42:10,040
+A Cyclic هيسكر لإيش؟ لهدولة بنسبة 64 ل 36 طب لو
+
+461
+00:42:10,040 --> 00:42:16,880
+جيبنا هذا نقي و حطيناه لحاله و غيبنا عنه يوم إيش
+
+462
+00:42:16,880 --> 00:42:24,640
+بيعمل؟ لا بيعمل اشي هذا في حالة اتزان مع الفاتح
+
+463
+00:42:24,640 --> 00:42:32,760
+الان نتيجة الاتزان بيفتح لما بيفتح بيسكر من اول و
+
+464
+00:42:32,760 --> 00:42:38,520
+جديد بالجهتين وبناء على ذلك لو اجينا حاطينا هذا
+
+465
+00:42:38,520 --> 00:42:43,480
+المسكر و سبناه يوم هو في اتزان مع الفاتح فتح سكر
+
+466
+00:42:43,480 --> 00:42:46,920
+اشمال يمين اشمال يمين بعد يوم بنلاقي ايش الناس
+
+467
+00:42:46,920 --> 00:42:53,530
+بصفيت وجود الاتنين ال alpha و ال beta بنفس النسبة
+
+468
+00:42:53,530 --> 00:43:01,190
+اللي هي ال 64 ل 36 طب لو جيبنا هذا المسكر و
+
+469
+00:43:01,190 --> 00:43:08,250
+دوّبناه في المحلول و سيبناه يوم يومين هذا هيفتح ل
+
+470
+00:43:08,250 --> 00:43:13,940
+ال a cyclic ال a cyclic هيسكر من اول و جديد شمال
+
+471
+00:43:13,940 --> 00:43:19,640
+ويمين شمال ويمين الى ان يصل الى الاتزان 64% الى 36
+
+472
+00:43:19,640 --> 00:43:25,120
+% فسواء بدأت بال A cyclic و سبته في المحلول او
+
+473
+00:43:25,120 --> 00:43:27,880
+بدأت بهذا و سبته في المحلول او بدأت بهذا و سبته في
+
+474
+00:43:27,880 --> 00:43:33,760
+المحلول اصل لنفس الخليط نفس النتيجة هذه العملية
+
+475
+00:43:33,760 --> 00:43:39,670
+الحقيقة بيسموها mutarotation لحظة الميوتا روتيشن هي
+
+476
+00:43:39,670 --> 00:43:44,070
+التغيير في الروتيشن الأبطالي بسبب تغيير الانو مارس
+
+477
+00:43:44,070 --> 00:43:53,290
+هدولة .. هدولة التنين الجداد بنسميهم احنا ايش؟ انو
+
+478
+00:43:53,290 --> 00:43:58,300
+مارساللي جايين من ال anomeric carbon اللي اختلفوا
+
+479
+00:43:58,300 --> 00:44:03,420
+في one chiral center واضح؟ يعني ال anomer beta
+
+480
+00:44:03,420 --> 00:44:07,860
+بيصير ال anomer alpha و ال anomer alpha بيصير ال
+
+481
+00:44:07,860 --> 00:44:12,560
+anomer beta لو حطيت ال alpha بصف على اتزان من
+
+482
+00:44:12,560 --> 00:44:17,120
+alpha و beta و لو حطيت ال beta بصف على اتزان من
+
+483
+00:44:17,120 --> 00:44:21,080
+alpha و beta و بنفس النسبة هذه العملية اللي احنا
+
+484
+00:44:21,080 --> 00:44:24,420
+بنسميها ايش ال mutation rotation لما احط ال alpha
+
+485
+00:44:24,420 --> 00:44:27,300
+و اكون جسد في ال polarimeter راح لاحظ ان الزاوية
+
+486
+00:44:27,300 --> 00:44:32,680
+في اولها 146 بعد شوية بتجل بتجل بتجل اخر مابتصف
+
+487
+00:44:32,680 --> 00:44:40,550
+يداش 52 لو حطيت ال betaالزاوية 19 بضلني اديس معي
+
+488
+00:44:40,550 --> 00:44:46,990
+الزمن بتضل ازيد ازيد ازيد اخر ما بتصفح 52 هذا
+
+489
+00:44:46,990 --> 00:44:52,390
+التغير في ال rotation إلى أن يصل 52 يعني إذا بدأت
+
+490
+00:44:52,390 --> 00:44:57,960
+من هنا ستصل ل 52 وإذا بدأت من هنا ستصل ل 52 هذا ايش
+
+491
+00:44:57,960 --> 00:45:03,260
+بنسميه احنا ميوتا روتيشن اللي هو نشوف ايش تعريفه
+
+492
+00:45:03,260 --> 00:45:06,920
+is the change in optical rotation التغيير في ال
+
+493
+00:45:06,920 --> 00:45:09,780
+optical rotation due to inter conversion of
+
+494
+00:45:09,780 --> 00:45:13,360
+animals ان ال alpha بتصير a cyclic و بترجع تصير
+
+495
+00:45:13,360 --> 00:45:17,540
+alpha و beta in solution it is explained by the
+
+496
+00:45:17,540 --> 00:45:22,980
+equilibrium بالفسيرة بإيش أنه في اتزان أنه ال beta
+
+497
+00:45:22,980 --> 00:45:26,080
+بيفتح و بسكر alpha و beta ال alpha بيفتح و بسكر
+
+498
+00:45:26,080 --> 00:45:31,560
+alpha و beta و بنفس إيش الإتزان طبعا بإمكانهم
+
+499
+00:45:31,560 --> 00:45:34,680
+يعملوا حسابات احنا مش موضوعنا الحسابات احنا
+
+500
+00:45:34,680 --> 00:45:38,840
+موضوعنا ببساطة الآن أنه في عندنا سواء بدأت ب alpha
+
+501
+00:45:38,840 --> 00:45:44,980
+أو beta بالمحلول هاصل إلى إيش إلى الاتزان هذا
+
+502
+00:45:44,980 --> 00:45:53,110
+الاتزان 64% Beta و 36% Alpha ايش معناه؟ معناه ان ال
+
+503
+00:45:53,110 --> 00:45:57,810
+.. which is more stable ال Beta ولا ال Alpha؟ ال
+
+504
+00:45:57,810 --> 00:46:03,190
+Beta طبعا هم بيفسروا على انه لو رسمنا السكر على
+
+505
+00:46:03,190 --> 00:46:08,310
+شكل الكرسي مش السكر Cyclohexane في النهاية بتكون
+
+506
+00:46:08,310 --> 00:46:14,250
+ال OH في ال Beta equatorial يعني غير مزدحمة واضح؟
+
+507
+00:46:14,250 --> 00:46:18,690
+هذه ال OH لا تعاني ازدحام، لاحظوا هذه ال OH not
+
+508
+00:46:18,690 --> 00:46:24,830
+crowded غير مزحمة الان هذه ال اواتش اللي طلع عليها
+
+509
+00:46:24,830 --> 00:46:33,450
+crowded مزحمة عشان هيك هو بفضل يكون في ال beta ولا
+
+510
+00:46:33,450 --> 00:46:39,170
+في ال alpha بالنسبة أعلى في ال beta بهيك بننهي
+
+511
+00:46:39,170 --> 00:46:43,430
+اليوم هذا الجزء و المرة اللي جاي ان شاء الله
+
+512
+00:46:43,430 --> 00:46:44,510
+بنستكمل
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..2e75bdedf1cf3578baf973b94c8ca17054408e61
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3986, "start": 19.57, "end": 39.87, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله بنشرح معلومات ايضا مختصرة على موضوع ال carbohydrates جزء من ال biochemistry طبعا ال carbohydrates هم اكثر", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 44945, 46309, 5016, 20449, 1211, 20498, 9307, 1975, 1829, 11242, 995, 3714, 46456, 9381, 25720, 15844, 3714, 2407, 11242, 45367, 2423, 36817, 10874, 11622, 38207, 9154, 2423, 12198, 48353, 23032, 3555, 3615, 995, 2423, 36817, 8032, 2304, 1975, 4117, 49115], "avg_logprob": -0.0793805778292673, "compression_ratio": 1.513157894736842, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 19.57, "end": 19.95, "word": "بسم", "probability": 0.921142578125}, {"start": 19.95, "end": 20.11, "word": " الله", "probability": 0.970703125}, {"start": 20.11, "end": 20.49, "word": " الرحمن", "probability": 0.9500325520833334}, {"start": 20.49, "end": 20.95, 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carbohydrates هذا الكلام يمكن يعطيكم إيش فكرة", "tokens": [7435, 11622, 1829, 19986, 9307, 7251, 43020, 3714, 29245, 23328, 3660, 8978, 41950, 21292, 27884, 9154, 25724, 11622, 1829, 19986, 9307, 21542, 1829, 2407, 10632, 7251, 43020, 29739, 3615, 11242, 7251, 14851, 17082, 25513, 44381, 5296, 15042, 6055, 5172, 37983, 14407, 4724, 3794, 12174, 3215, 33599, 8978, 20666, 3215, 22653, 995, 8717, 3555, 9307, 9307, 4032, 28239, 3555, 9307, 9307, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 2815, 425, 541, 4032, 2423, 2815, 425, 541, 31439, 6225, 3555, 9640, 3660, 18871, 36817, 23758, 2423, 28820, 10943, 7251, 43020, 37495, 9566, 1829, 24793, 11933, 1829, 8592, 6156, 4117, 25720], "avg_logprob": -0.09067235134466729, "compression_ratio": 1.6775700934579438, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 40.85, "end": 42.35, "word": "جزيئات", "probability": 0.92041015625}, {"start": 42.35, "end": 43.13, "word": " يمكن", "probability": 0.830322265625}, {"start": 43.13, "end": 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carbohydrates يعني ال carbons وبعدين المية", "tokens": [3555, 8592, 28820, 6225, 10943, 2423, 36817, 31767, 1829, 17082, 3660, 6055, 3555, 34268, 16095, 39896, 6225, 3555, 9640, 3660, 18871, 5954, 20449, 3714, 10632, 3714, 37983, 2288, 9957, 37495, 22653, 5995, 17, 46, 281, 264, 426, 6156, 27842, 34105, 11933, 7435, 2655, 6156, 4117, 25720, 36817, 37495, 22653, 2423, 12143, 892, 46599, 22488, 9957, 9673, 10632], "avg_logprob": -0.16500538818795105, "compression_ratio": 1.4394904458598725, "no_speech_prob": 0.0, "words": [{"start": 67.35, "end": 68.35, "word": "بشكل", "probability": 0.9619140625}, {"start": 68.35, "end": 68.73, "word": " عام", "probability": 0.997802734375}, {"start": 68.73, "end": 69.23, "word": " ال", "probability": 0.90771484375}, {"start": 69.23, "end": 69.89, "word": " carbohydrates", "probability": 0.88232421875}, {"start": 69.89, "end": 70.61, "word": " الصيغة", "probability": 0.9678955078125}, {"start": 70.61, "end": 71.51, "word": " تبعتهم", "probability": 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فهو مضاعف لل Carbon و الميّه", "tokens": [24437, 33568, 4032, 2304, 1829, 11703, 3224, 4032, 46958, 5016, 6156, 3615, 23942, 8608, 21292, 1211, 9673, 12984, 6027, 37495, 22653, 45164, 47525, 4117, 14407, 6055, 47283, 3215, 14407, 14739, 2655, 14407, 5551, 3555, 3794, 9566, 8608, 37983, 4386, 5551, 3555, 3794, 9566, 8608, 37983, 13672, 1829, 31439, 383, 21, 39, 4762, 46, 21, 6024, 48506, 44945, 28543, 2288, 8717, 39648, 23758, 6225, 3555, 9640, 3660, 18871, 1386, 8978, 383, 4032, 39, 17, 46, 6156, 3224, 2407, 3714, 11242, 45761, 5172, 24976, 31453, 4032, 9673, 1829, 11703, 3224], "avg_logprob": -0.196804769923178, "compression_ratio": 1.4578947368421054, "no_speech_prob": 0.0, "words": [{"start": 86.63, "end": 87.39, "word": "Carbons", "probability": 0.65673828125}, {"start": 87.39, "end": 88.25, "word": " وميّه", "probability": 0.75556640625}, {"start": 88.25, "end": 89.25, "word": " واضح", "probability": 0.8986002604166666}, {"start": 89.25, "end": 90.93, "word": " فعلى", 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وH2O", "probability": 0.8759765625}, {"start": 111.01, "end": 112.19, "word": " فهو", "probability": 0.9905598958333334}, {"start": 112.19, "end": 112.91, "word": " مضاعف", "probability": 0.9822998046875}, {"start": 112.91, "end": 113.13, "word": " لل", "probability": 0.64111328125}, {"start": 113.13, "end": 113.55, "word": " Carbon", "probability": 0.1903076171875}, {"start": 113.55, "end": 113.77, "word": " و", "probability": 0.82421875}, {"start": 113.77, "end": 114.27, "word": " الميّه", "probability": 0.8828125}], "temperature": 1.0}, {"id": 5, "seek": 14291, "start": 114.82, "end": 142.92, "text": "واضح؟ C6H12O6 واضح الفكرة؟ ومن هنا إجا الاسم carbohydrate لأنه بشكل أساسي الصيغة البسيطة تبعته هي عبارة عن carbon وميه واضح هذه الفكرة؟ يعني لما نيجي نسألكم أن ال carbohydrates الصيغة الأساسية بتاعتهم carbon و oxygen carbon و hydrogen", "tokens": [2407, 46958, 5016, 22807, 383, 21, 39, 4762, 46, 21, 4032, 46958, 5016, 27188, 4117, 25720, 22807, 4032, 27842, 34105, 11933, 7435, 995, 2423, 32277, 2304, 47048, 5296, 33456, 3224, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 31767, 1829, 17082, 3660, 29739, 3794, 1829, 9566, 3660, 6055, 3555, 34268, 3224, 39896, 6225, 3555, 9640, 3660, 18871, 5954, 4032, 2304, 1829, 3224, 4032, 46958, 5016, 29538, 27188, 4117, 25720, 22807, 37495, 22653, 5296, 15042, 8717, 1829, 7435, 1829, 8717, 3794, 10721, 23275, 2304, 14739, 2423, 36817, 31767, 1829, 17082, 3660, 16247, 3794, 32277, 10632, 39894, 995, 34268, 16095, 5954, 4032, 9169, 5954, 4032, 12697], "avg_logprob": -0.15234374398222336, "compression_ratio": 1.6712328767123288, "no_speech_prob": 0.0, "words": [{"start": 114.82, "end": 115.52, "word": "واضح؟", "probability": 0.7933349609375}, {"start": 115.52, "end": 118.7, "word": " C6H12O6", "probability": 0.8824869791666666}, {"start": 118.7, "end": 119.56, "word": " واضح", "probability": 0.9772135416666666}, {"start": 119.56, "end": 120.5, "word": " الفكرة؟", "probability": 0.8648681640625}, {"start": 120.5, "end": 120.74, "word": " ومن", "probability": 0.883056640625}, {"start": 120.74, "end": 120.88, "word": " هنا", "probability": 0.8583984375}, {"start": 120.88, "end": 121.2, "word": " إجا", "probability": 0.512451171875}, {"start": 121.2, "end": 121.72, "word": " الاسم", "probability": 0.8125}, {"start": 121.72, "end": 123.18, "word": " carbohydrate", "probability": 0.7861328125}, {"start": 123.18, "end": 124.9, "word": " لأنه", "probability": 0.8946940104166666}, {"start": 124.9, "end": 125.76, "word": " بشكل", "probability": 0.8231608072916666}, {"start": 125.76, "end": 126.54, "word": " أساسي", "probability": 0.9766845703125}, {"start": 126.54, "end": 127.18, "word": " الصيغة", "probability": 0.9779052734375}, {"start": 127.18, "end": 127.74, "word": " البسيطة", "probability": 0.969921875}, {"start": 127.74, "end": 128.44, "word": " تبعته", "probability": 0.924072265625}, {"start": 128.44, "end": 129.06, "word": " هي", "probability": 0.912109375}, {"start": 129.06, "end": 129.52, "word": " عبارة", "probability": 0.99609375}, {"start": 129.52, "end": 129.88, "word": " عن", "probability": 0.9951171875}, {"start": 129.88, "end": 131.74, "word": " carbon", "probability": 0.424072265625}, {"start": 131.74, "end": 132.76, "word": " وميه", "probability": 0.77197265625}, {"start": 132.76, "end": 133.12, "word": " واضح", "probability": 0.9505208333333334}, {"start": 133.12, "end": 133.3, "word": " هذه", "probability": 0.6962890625}, {"start": 133.3, "end": 134.8, "word": " الفكرة؟", "probability": 0.916015625}, {"start": 134.8, "end": 136.14, "word": " يعني", "probability": 0.922607421875}, {"start": 136.14, "end": 136.34, "word": " لما", "probability": 0.75390625}, {"start": 136.34, "end": 136.82, "word": " نيجي", "probability": 0.9417724609375}, {"start": 136.82, "end": 137.42, "word": " نسألكم", "probability": 0.96435546875}, {"start": 137.42, "end": 137.56, "word": " أن", "probability": 0.412841796875}, {"start": 137.56, "end": 137.7, "word": " ال", "probability": 0.884765625}, {"start": 137.7, "end": 138.34, "word": " carbohydrates", "probability": 0.94482421875}, {"start": 138.34, "end": 138.88, "word": " الصيغة", "probability": 0.98828125}, {"start": 138.88, "end": 139.46, "word": " الأساسية", "probability": 0.9886474609375}, {"start": 139.46, "end": 139.98, "word": " بتاعتهم", "probability": 0.89404296875}, {"start": 139.98, "end": 140.46, "word": " carbon", "probability": 0.70458984375}, {"start": 140.46, "end": 140.66, "word": " و", "probability": 0.94775390625}, {"start": 140.66, "end": 141.28, "word": " oxygen", "probability": 0.83203125}, {"start": 141.28, "end": 142.04, "word": " carbon", "probability": 0.42333984375}, {"start": 142.04, "end": 142.28, "word": " و", "probability": 0.93994140625}, {"start": 142.28, "end": 142.92, "word": " hydrogen", "probability": 0.8984375}], "temperature": 1.0}, {"id": 6, "seek": 16754, "start": 143.86, "end": 167.54, "text": "لأ لو كربون و هيدروجين كال سمناها hydrocarbon لكن carbohydrate يعني كربون و مياه الآن ال carbohydrates ببساطة احنا بنقدر نتخيلها اذا بنفهمها بالشكل القاتل هي عبارة عن جزيئات في الغالب كبيرة يعني ممكن نتخيل ان هذا جزيئ", "tokens": [1211, 10721, 45164, 9122, 25513, 11536, 4032, 8032, 25708, 2288, 29245, 9957, 9122, 6027, 8608, 2304, 8315, 11296, 15435, 39294, 44381, 47048, 37495, 22653, 9122, 25513, 11536, 4032, 3714, 25528, 3224, 6024, 48506, 2423, 36817, 4724, 3555, 3794, 41193, 3660, 1975, 5016, 8315, 44945, 28543, 2288, 8717, 2655, 9778, 26895, 11296, 1975, 15730, 44945, 5172, 16095, 11296, 20666, 8592, 28820, 25062, 9307, 1211, 39896, 6225, 3555, 9640, 3660, 18871, 10874, 11622, 1829, 19986, 9307, 8978, 6024, 118, 6027, 3555, 9122, 3555, 48923, 37495, 22653, 3714, 43020, 8717, 2655, 9778, 26895, 16472, 23758, 10874, 11622, 1829, 19986], "avg_logprob": -0.20989046883337276, "compression_ratio": 1.7439613526570048, "no_speech_prob": 0.0, "words": [{"start": 143.86, "end": 144.24, "word": "لأ", "probability": 0.923828125}, {"start": 144.24, "end": 144.44, "word": " لو", "probability": 0.7822265625}, {"start": 144.44, "end": 144.86, "word": " كربون", "probability": 0.6070149739583334}, {"start": 144.86, "end": 144.94, "word": " و", "probability": 0.8759765625}, {"start": 144.94, "end": 145.36, "word": " هيدروجين", "probability": 0.810791015625}, {"start": 145.36, "end": 145.54, "word": " كال", "probability": 0.6243896484375}, {"start": 145.54, "end": 145.96, "word": " سمناها", "probability": 0.45904541015625}, {"start": 145.96, "end": 147.08, "word": " hydrocarbon", "probability": 0.693115234375}, {"start": 147.08, "end": 147.78, "word": " لكن", "probability": 0.66943359375}, {"start": 147.78, "end": 148.6, "word": " carbohydrate", "probability": 0.9150390625}, {"start": 148.6, "end": 149.36, "word": " يعني", "probability": 0.964111328125}, {"start": 149.36, "end": 150.7, "word": " كربون", "probability": 0.9630533854166666}, {"start": 150.7, "end": 150.8, "word": " و", "probability": 0.97998046875}, {"start": 150.8, "end": 151.42, "word": " مياه", "probability": 0.7134602864583334}, {"start": 151.42, "end": 152.18, "word": " الآن", "probability": 0.6148681640625}, {"start": 152.18, "end": 152.9, "word": " ال", "probability": 0.908203125}, {"start": 152.9, "end": 153.68, "word": " carbohydrates", "probability": 0.90771484375}, {"start": 153.68, "end": 155.16, "word": " ببساطة", "probability": 0.906640625}, {"start": 155.16, "end": 155.4, "word": " احنا", "probability": 0.8167317708333334}, {"start": 155.4, "end": 155.84, "word": " بنقدر", "probability": 0.8898111979166666}, {"start": 155.84, "end": 156.7, "word": " نتخيلها", "probability": 0.98876953125}, {"start": 156.7, "end": 157.1, "word": " اذا", "probability": 0.7666015625}, {"start": 157.1, "end": 157.76, "word": " بنفهمها", "probability": 0.830810546875}, {"start": 157.76, "end": 158.24, "word": " بالشكل", "probability": 0.9230143229166666}, {"start": 158.24, "end": 158.94, "word": " القاتل", "probability": 0.5629069010416666}, {"start": 158.94, "end": 159.9, "word": " هي", "probability": 0.77685546875}, {"start": 159.9, "end": 160.38, "word": " عبارة", "probability": 0.9954833984375}, {"start": 160.38, "end": 161.26, "word": " عن", "probability": 0.99462890625}, {"start": 161.26, "end": 162.34, "word": " جزيئات", "probability": 0.9365234375}, {"start": 162.34, "end": 163.2, "word": " في", "probability": 0.8857421875}, {"start": 163.2, "end": 163.72, "word": " الغالب", "probability": 0.991455078125}, {"start": 163.72, "end": 164.34, "word": " كبيرة", "probability": 0.98828125}, {"start": 164.34, "end": 165.04, "word": " يعني", "probability": 0.9072265625}, {"start": 165.04, "end": 165.32, "word": " ممكن", "probability": 0.987548828125}, {"start": 165.32, "end": 165.96, "word": " نتخيل", "probability": 0.98876953125}, {"start": 165.96, "end": 166.48, "word": " ان", "probability": 0.73876953125}, {"start": 166.48, "end": 166.82, "word": " هذا", "probability": 0.892578125}, {"start": 166.82, "end": 167.54, "word": " جزيئ", "probability": 0.850830078125}], "temperature": 1.0}, {"id": 7, "seek": 18401, "start": 168.17, "end": 184.01, "text": "كبير أشبه ما تكون بوليمار تمام الآن هذه الجزيئات الكبيرة بنسميها احنا polysaccharides يعني سكريات اشمالها عديدة لو عملنا لها hydrolysis", "tokens": [4117, 3555, 13546, 5551, 8592, 3555, 3224, 19446, 6055, 30544, 4724, 12610, 32640, 9640, 46811, 10943, 6024, 48506, 29538, 25724, 11622, 1829, 19986, 9307, 33251, 3555, 48923, 44945, 38251, 1829, 11296, 1975, 5016, 8315, 6754, 82, 326, 7374, 1875, 37495, 22653, 8608, 4117, 16572, 9307, 1975, 8592, 2304, 6027, 11296, 6225, 16254, 41891, 45164, 6225, 42213, 8315, 5296, 11296, 15435, 356, 17122], "avg_logprob": -0.22557043035825095, "compression_ratio": 1.4423076923076923, "no_speech_prob": 0.0, "words": [{"start": 168.17, "end": 168.95, "word": "كبير", "probability": 0.6493733723958334}, {"start": 168.95, "end": 170.13, "word": " أشبه", "probability": 0.869140625}, {"start": 170.13, "end": 170.21, "word": " ما", "probability": 0.95361328125}, {"start": 170.21, "end": 170.67, "word": " تكون", "probability": 0.98876953125}, {"start": 170.67, "end": 171.41, "word": " بوليمار", "probability": 0.65374755859375}, {"start": 171.41, "end": 172.39, "word": " تمام", "probability": 0.71484375}, {"start": 172.39, "end": 173.33, "word": " الآن", "probability": 0.562744140625}, {"start": 173.33, "end": 174.17, "word": " هذه", "probability": 0.89794921875}, {"start": 174.17, "end": 175.07, "word": " الجزيئات", "probability": 0.89580078125}, {"start": 175.07, "end": 175.81, "word": " الكبيرة", "probability": 0.9853515625}, {"start": 175.81, "end": 176.69, "word": " بنسميها", "probability": 0.9227294921875}, {"start": 176.69, "end": 177.07, "word": " احنا", "probability": 0.7947591145833334}, {"start": 177.07, "end": 178.69, "word": " polysaccharides", "probability": 0.86259765625}, {"start": 178.69, "end": 178.93, "word": " يعني", "probability": 0.89599609375}, {"start": 178.93, "end": 179.65, "word": " سكريات", "probability": 0.898193359375}, {"start": 179.65, "end": 180.33, "word": " اشمالها", "probability": 0.8318359375}, {"start": 180.33, "end": 181.33, "word": " عديدة", "probability": 0.94873046875}, {"start": 181.33, "end": 181.97, "word": " لو", "probability": 0.87841796875}, {"start": 181.97, "end": 182.43, "word": " عملنا", "probability": 0.9620768229166666}, {"start": 182.43, "end": 182.85, "word": " لها", "probability": 0.92578125}, {"start": 182.85, "end": 184.01, "word": " hydrolysis", "probability": 0.8126627604166666}], "temperature": 1.0}, {"id": 8, "seek": 21020, "start": 184.76, "end": 210.2, "text": "في وجود حمض ميه بتتكسر الى جزيئات اصغر من وحدتين او تلاتة هذه الجزيئات الاصغر بنسميها oligosaccharides يعني هي كانت الكبيرة polysaccharide اتكسرت الى oligosaccharides سكريات بسيطة زى السكريات الثنائية هتمر علينا الان لو كسرناها اكتر", "tokens": [41185, 49610, 23328, 11331, 2304, 11242, 3714, 1829, 3224, 39894, 2655, 4117, 3794, 2288, 2423, 7578, 10874, 11622, 1829, 19986, 9307, 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"probability": 0.681640625}, {"start": 185.98, "end": 186.7, "word": " بتتكسر", "probability": 0.90322265625}, {"start": 186.7, "end": 187.32, "word": " الى", "probability": 0.7198486328125}, {"start": 187.32, "end": 188.5, "word": " جزيئات", "probability": 0.92958984375}, {"start": 188.5, "end": 189.14, "word": " اصغر", "probability": 0.9107666015625}, {"start": 189.14, "end": 190.02, "word": " من", "probability": 0.97802734375}, {"start": 190.02, "end": 190.7, "word": " وحدتين", "probability": 0.75103759765625}, {"start": 190.7, "end": 190.88, "word": " او", "probability": 0.971435546875}, {"start": 190.88, "end": 191.52, "word": " تلاتة", "probability": 0.9617919921875}, {"start": 191.52, "end": 192.2, "word": " هذه", "probability": 0.78076171875}, {"start": 192.2, "end": 193.26, "word": " الجزيئات", "probability": 0.98125}, {"start": 193.26, "end": 193.82, "word": " الاصغر", "probability": 0.8980712890625}, {"start": 193.82, "end": 194.64, "word": " بنسميها", "probability": 0.9649658203125}, {"start": 194.64, "end": 196.44, "word": " oligosaccharides", "probability": 0.82353515625}, {"start": 196.44, "end": 196.82, "word": " يعني", "probability": 0.926025390625}, {"start": 196.82, "end": 196.98, "word": " هي", "probability": 0.70166015625}, {"start": 196.98, "end": 197.34, "word": " كانت", "probability": 0.968994140625}, {"start": 197.34, "end": 197.92, "word": " الكبيرة", "probability": 0.9715169270833334}, {"start": 197.92, "end": 199.54, "word": " polysaccharide", "probability": 0.86103515625}, {"start": 199.54, "end": 200.6, "word": " اتكسرت", "probability": 0.91357421875}, {"start": 200.6, "end": 201.78, "word": " الى", "probability": 0.96435546875}, {"start": 201.78, "end": 203.46, "word": " oligosaccharides", "probability": 0.9330078125}, {"start": 203.46, "end": 204.54, "word": " سكريات", "probability": 0.919677734375}, {"start": 204.54, "end": 205.24, "word": " بسيطة", "probability": 0.99228515625}, {"start": 205.24, "end": 205.42, "word": " زى", "probability": 0.909423828125}, {"start": 205.42, "end": 206.1, "word": " السكريات", "probability": 0.9615478515625}, {"start": 206.1, "end": 206.72, "word": " الثنائية", "probability": 0.93115234375}, {"start": 206.72, "end": 207.48, "word": " هتمر", "probability": 0.8629557291666666}, {"start": 207.48, "end": 207.92, "word": " علينا", "probability": 0.948486328125}, {"start": 207.92, "end": 208.48, "word": " الان", "probability": 0.6907958984375}, {"start": 208.48, "end": 208.86, "word": " لو", "probability": 0.98828125}, {"start": 208.86, "end": 209.62, "word": " كسرناها", "probability": 0.98544921875}, {"start": 209.62, "end": 210.2, "word": " اكتر", "probability": 0.97802734375}], "temperature": 1.0}, {"id": 9, "seek": 22907, "start": 210.97, "end": 229.07, "text": "بصير عندى monosaccharides اللى هو السكر المنفرد فإحنا لما بدنا ندرس الآن بهذا الفصل و نتعرف على السكريات هيكون المحور تبعنا بسيط جدا هنبدأ نقول إيش والله ال monosaccharides", "tokens": [3555, 9381, 13546, 43242, 7578, 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415.75, "end": 416.23, "word": " صار", "probability": 0.940673828125}], "temperature": 1.0}, {"id": 18, "seek": 44001, "start": 416.83, "end": 440.01, "text": "Dihydroxy-13-Dihydroxyacetone الآن هذا الـDihydroxyacetone فيه كيتون وفيه مجموعات OH إذا هذا عبارة عن بوليهيدروكس كيتون بوليهيدروكس كيتون إذا هذا sugar كيتوز", "tokens": [35, 4247, 6655, 340, 12876, 12, 7668, 12, 35, 4247, 6655, 340, 12876, 326, 302, 546, 6024, 48506, 23758, 2423, 39184, 35, 4247, 6655, 340, 12876, 326, 302, 546, 8978, 3224, 9122, 36081, 11536, 4032, 41185, 3224, 3714, 7435, 2304, 45367, 9307, 13931, 11933, 15730, 23758, 6225, 3555, 9640, 3660, 18871, 4724, 12610, 1829, 3224, 25708, 32887, 4117, 3794, 9122, 36081, 11536, 4724, 12610, 1829, 3224, 25708, 32887, 4117, 3794, 9122, 36081, 11536, 11933, 15730, 23758, 5076, 9122, 36081, 2407, 11622], "avg_logprob": -0.2263719561259921, "compression_ratio": 1.6575342465753424, "no_speech_prob": 0.0, "words": [{"start": 416.83, "end": 417.71, "word": "Dihydroxy", "probability": 0.765576171875}, {"start": 417.71, "end": 418.17, "word": "-13", "probability": 0.4459228515625}, {"start": 418.17, "end": 419.95, "word": "-Dihydroxyacetone", "probability": 0.8682996961805556}, {"start": 419.95, "end": 420.79, "word": " الآن", "probability": 0.520355224609375}, {"start": 420.79, "end": 421.27, "word": " هذا", "probability": 0.69921875}, {"start": 421.27, "end": 422.81, "word": " الـDihydroxyacetone", "probability": 0.8497802734375}, {"start": 422.81, "end": 423.59, "word": " فيه", "probability": 0.756591796875}, {"start": 423.59, "end": 424.55, "word": " كيتون", "probability": 0.8395182291666666}, {"start": 424.55, "end": 428.05, "word": " وفيه", "probability": 0.8435872395833334}, {"start": 428.05, "end": 429.43, "word": " مجموعات", "probability": 0.9455078125}, {"start": 429.43, "end": 430.21, "word": " OH", "probability": 0.91357421875}, {"start": 430.21, "end": 431.17, "word": " إذا", "probability": 0.66796875}, {"start": 431.17, "end": 431.81, "word": " هذا", "probability": 0.84521484375}, {"start": 431.81, "end": 432.33, "word": " عبارة", "probability": 0.997802734375}, {"start": 432.33, "end": 432.85, "word": " عن", "probability": 0.99267578125}, {"start": 432.85, "end": 434.19, "word": " بوليهيدروكس", "probability": 0.815643310546875}, {"start": 434.19, "end": 434.87, "word": " كيتون", "probability": 0.8792317708333334}, {"start": 434.87, "end": 436.37, "word": " بوليهيدروكس", "probability": 0.89215087890625}, {"start": 436.37, "end": 436.91, "word": " كيتون", "probability": 0.9830729166666666}, {"start": 436.91, "end": 437.45, "word": " إذا", "probability": 0.857666015625}, {"start": 437.45, "end": 437.91, "word": " هذا", "probability": 0.92333984375}, {"start": 437.91, "end": 438.55, "word": " sugar", "probability": 0.359130859375}, {"start": 438.55, "end": 440.01, "word": " كيتوز", "probability": 0.8475341796875}], "temperature": 1.0}, {"id": 19, "seek": 46491, "start": 441.95, "end": 464.91, "text": "ليش؟ لأنه جاي من كيتون، الدوز من ال الديهايد، واضح الفكرة؟ الآن لو اتطلعت على ال glycerol، ال glycerol او ال glycerin، فيه بس ال O H's، مافيه الديهايد او كيتون، فهل ال glycerin بنصنفه انه sugar كيميائيا؟ لأ", "tokens": [20292, 8592, 22807, 5296, 33456, 3224, 10874, 47302, 9154, 9122, 36081, 11536, 12399, 2423, 3215, 2407, 11622, 9154, 2423, 2423, 16254, 11296, 25708, 12399, 4032, 46958, 5016, 27188, 4117, 25720, 22807, 6024, 48506, 45164, 1975, 2655, 9566, 1211, 34268, 15844, 2423, 22633, 1776, 401, 12399, 2423, 22633, 1776, 401, 1975, 2407, 2423, 22633, 1776, 259, 12399, 8978, 3224, 4724, 3794, 2423, 422, 389, 311, 12399, 19446, 41185, 3224, 2423, 16254, 11296, 25708, 1975, 2407, 9122, 36081, 11536, 12399, 6156, 3224, 1211, 2423, 22633, 1776, 259, 44945, 9381, 1863, 5172, 3224, 16472, 3224, 5076, 9122, 32640, 1829, 16373, 25528, 22807, 5296, 10721], "avg_logprob": -0.24371935558669708, "compression_ratio": 1.7076923076923076, "no_speech_prob": 0.0, "words": [{"start": 441.95, "end": 442.39, "word": "ليش؟", "probability": 0.732421875}, {"start": 442.39, "end": 442.69, "word": " لأنه", "probability": 0.8927408854166666}, {"start": 442.69, "end": 442.99, "word": " جاي", "probability": 0.932861328125}, {"start": 442.99, "end": 443.15, "word": " من", "probability": 0.990234375}, {"start": 443.15, "end": 444.05, "word": " كيتون،", "probability": 0.7210693359375}, {"start": 444.05, "end": 444.85, "word": " الدوز", "probability": 0.66217041015625}, {"start": 444.85, "end": 445.69, "word": " من", "probability": 0.91943359375}, {"start": 445.69, "end": 445.87, "word": " ال", "probability": 0.97705078125}, {"start": 445.87, "end": 446.93, "word": " الديهايد،", "probability": 0.645068359375}, {"start": 446.93, "end": 447.19, "word": " واضح", "probability": 0.9905598958333334}, {"start": 447.19, "end": 448.57, "word": " الفكرة؟", "probability": 0.8907470703125}, {"start": 448.57, "end": 449.13, "word": " الآن", "probability": 0.719482421875}, {"start": 449.13, "end": 450.79, "word": " لو", "probability": 0.77001953125}, {"start": 450.79, "end": 451.93, "word": " اتطلعت", "probability": 0.7798828125}, {"start": 451.93, "end": 452.27, "word": " على", "probability": 0.90185546875}, {"start": 452.27, "end": 452.59, "word": " ال", "probability": 0.697265625}, {"start": 452.59, "end": 453.95, "word": " glycerol،", "probability": 0.85009765625}, {"start": 453.95, "end": 454.11, "word": " ال", "probability": 0.94140625}, {"start": 454.11, "end": 454.83, "word": " glycerol", "probability": 0.9886067708333334}, {"start": 454.83, "end": 454.99, "word": " او", "probability": 0.7061767578125}, {"start": 454.99, "end": 455.09, "word": " ال", "probability": 0.92333984375}, {"start": 455.09, "end": 456.07, "word": " glycerin،", "probability": 0.82470703125}, {"start": 456.07, "end": 456.31, "word": " فيه", "probability": 0.62744140625}, {"start": 456.31, "end": 456.55, "word": " بس", "probability": 0.9912109375}, {"start": 456.55, "end": 456.75, "word": " ال", "probability": 0.990234375}, {"start": 456.75, "end": 456.93, "word": " O", "probability": 0.68408203125}, {"start": 456.93, "end": 457.73, "word": " H's،", "probability": 0.5601399739583334}, {"start": 457.73, "end": 457.95, "word": " مافيه", "probability": 0.5496419270833334}, {"start": 457.95, "end": 458.79, "word": " الديهايد", "probability": 0.8453369140625}, {"start": 458.79, "end": 459.05, "word": " او", "probability": 0.87548828125}, {"start": 459.05, "end": 460.87, "word": " كيتون،", "probability": 0.821533203125}, {"start": 460.87, "end": 461.21, "word": " فهل", "probability": 0.9236653645833334}, {"start": 461.21, "end": 461.31, "word": " ال", "probability": 0.94677734375}, {"start": 461.31, "end": 462.03, "word": " glycerin", "probability": 0.9669596354166666}, {"start": 462.03, "end": 462.97, "word": " بنصنفه", "probability": 0.9029296875}, {"start": 462.97, "end": 463.19, "word": " انه", "probability": 0.684326171875}, {"start": 463.19, "end": 463.53, "word": " sugar", "probability": 0.68798828125}, {"start": 463.53, "end": 464.61, "word": " كيميائيا؟", "probability": 0.8700358072916666}, {"start": 464.61, "end": 464.91, "word": " لأ", "probability": 0.865234375}], "temperature": 1.0}, {"id": 20, "seek": 48519, "start": 465.39, "end": 485.19, "text": "واضحة الفكرة؟ يعني لما نيجي نقولكم glycerol can be classified as a sugar او is classified as a sugar، لأ، لو قلنالكوا dihydroxyacetone is an aldose، فهمته؟ او لو قلنالكوا glyceraldehyde is equitose", "tokens": [2407, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 37495, 22653, 5296, 15042, 8717, 1829, 7435, 1829, 8717, 39648, 24793, 1563, 88, 1776, 401, 393, 312, 20627, 382, 257, 5076, 1975, 2407, 307, 20627, 382, 257, 5076, 12399, 5296, 10721, 12399, 45164, 12174, 1211, 8315, 23275, 14407, 1026, 21591, 340, 12876, 326, 302, 546, 307, 364, 16798, 541, 12399, 6156, 16095, 47395, 22807, 1975, 2407, 45164, 12174, 1211, 8315, 23275, 14407, 22633, 1776, 304, 1479, 3495, 1479, 307, 1267, 270, 541], "avg_logprob": -0.27044752497731905, "compression_ratio": 1.4914285714285713, "no_speech_prob": 0.0, "words": [{"start": 465.39, "end": 465.83, "word": "واضحة", "probability": 0.8326416015625}, {"start": 465.83, "end": 466.35, "word": " الفكرة؟", "probability": 0.866455078125}, {"start": 466.35, "end": 466.55, "word": " يعني", "probability": 0.90869140625}, {"start": 466.55, "end": 466.69, "word": " لما", "probability": 0.798095703125}, {"start": 466.69, "end": 466.93, "word": " نيجي", "probability": 0.78466796875}, {"start": 466.93, "end": 467.41, "word": " نقولكم", "probability": 0.8101399739583334}, {"start": 467.41, "end": 468.87, "word": " glycerol", "probability": 0.6370010375976562}, {"start": 468.87, "end": 469.13, "word": " can", "probability": 0.91455078125}, {"start": 469.13, "end": 469.31, "word": " be", "probability": 0.958984375}, {"start": 469.31, "end": 469.87, "word": " classified", "probability": 0.94970703125}, {"start": 469.87, "end": 470.27, "word": " as", "probability": 0.9833984375}, {"start": 470.27, "end": 470.45, "word": " a", "probability": 0.9580078125}, {"start": 470.45, "end": 470.85, "word": " sugar", "probability": 0.82666015625}, {"start": 470.85, "end": 471.15, "word": " او", "probability": 0.6204833984375}, {"start": 471.15, "end": 471.41, "word": " is", "probability": 0.8564453125}, {"start": 471.41, "end": 471.91, "word": " classified", "probability": 0.96435546875}, {"start": 471.91, "end": 472.31, "word": " as", "probability": 0.98291015625}, {"start": 472.31, "end": 472.49, "word": " a", "probability": 0.9892578125}, {"start": 472.49, "end": 472.95, "word": " sugar،", "probability": 0.681396484375}, {"start": 472.95, "end": 473.69, "word": " لأ،", "probability": 0.7542317708333334}, {"start": 473.69, "end": 473.91, "word": " لو", "probability": 0.974609375}, {"start": 473.91, "end": 474.63, "word": " قلنالكوا", "probability": 0.874609375}, {"start": 474.63, "end": 476.63, "word": " dihydroxyacetone", "probability": 0.83294677734375}, {"start": 476.63, "end": 477.05, "word": " is", "probability": 0.96044921875}, {"start": 477.05, "end": 477.69, "word": " an", "probability": 0.568359375}, {"start": 477.69, "end": 480.69, "word": " aldose،", "probability": 0.746337890625}, {"start": 480.69, "end": 481.29, "word": " فهمته؟", "probability": 0.8424072265625}, {"start": 481.29, "end": 481.65, "word": " او", "probability": 0.8662109375}, {"start": 481.65, "end": 481.81, "word": " لو", "probability": 0.95166015625}, {"start": 481.81, "end": 482.31, "word": " قلنالكوا", "probability": 0.96953125}, {"start": 482.31, "end": 483.81, "word": " glyceraldehyde", "probability": 0.8145345052083334}, {"start": 483.81, "end": 484.31, "word": " is", "probability": 0.96923828125}, {"start": 484.31, "end": 485.19, "word": " equitose", "probability": 0.5823567708333334}], "temperature": 1.0}, {"id": 21, "seek": 50969, "start": 486.23, "end": 509.69, "text": "glial aldehyde is an aldose, dihydroxyacetone is a ketose تفهمنا بالظبط إذا إيش معنى sugar، إيش معنى aldose، إيش معنى ketose، واضحة الفكرة؟ والشجر لازم ينوجد فيه كام شغلة؟ شغلتين، يا الديهيد، يا كيتون، ومجموعات الـOH، هذا اللي بدنا نصنفه sugar", "tokens": [7191, 831, 16798, 68, 3495, 1479, 307, 364, 16798, 541, 11, 1026, 21591, 340, 12876, 326, 302, 546, 307, 257, 14979, 541, 6055, 5172, 16095, 8315, 20666, 19913, 3555, 9566, 11933, 15730, 11933, 1829, 8592, 20449, 1863, 7578, 5076, 12399, 11933, 1829, 8592, 20449, 1863, 7578, 16798, 541, 12399, 11933, 1829, 8592, 20449, 1863, 7578, 14979, 541, 12399, 4032, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 16070, 8592, 7435, 2288, 5296, 31377, 2304, 7251, 1863, 29245, 3215, 8978, 3224, 9122, 10943, 13412, 17082, 37977, 22807, 13412, 17082, 1211, 2655, 9957, 12399, 35186, 2423, 16254, 3224, 25708, 12399, 35186, 9122, 36081, 11536, 12399, 4032, 2304, 7435, 2304, 45367, 9307, 2423, 39184, 31187, 12399, 23758, 13672, 1829, 47525, 8315, 8717, 9381, 1863, 5172, 3224, 5076], "avg_logprob": -0.2535282205189428, "compression_ratio": 1.5672268907563025, "no_speech_prob": 0.0, "words": [{"start": 486.23, "end": 486.67, "word": "glial", "probability": 0.3697509765625}, {"start": 486.67, "end": 487.39, "word": " aldehyde", "probability": 0.7279052734375}, {"start": 487.39, "end": 487.59, "word": " is", "probability": 0.611328125}, {"start": 487.59, "end": 487.85, "word": " an", "probability": 0.5966796875}, {"start": 487.85, "end": 488.41, "word": " aldose,", "probability": 0.9462890625}, {"start": 488.65, "end": 489.83, "word": " dihydroxyacetone", "probability": 0.7763671875}, {"start": 489.83, "end": 490.13, "word": " is", "probability": 0.8984375}, {"start": 490.13, "end": 490.49, "word": " a", "probability": 0.82861328125}, {"start": 490.49, "end": 491.01, "word": " ketose", "probability": 0.830322265625}, {"start": 491.01, "end": 491.63, "word": " تفهمنا", "probability": 0.78179931640625}, {"start": 491.63, "end": 492.09, "word": " بالظبط", "probability": 0.965087890625}, {"start": 492.09, "end": 492.39, "word": " إذا", "probability": 0.765380859375}, {"start": 492.39, "end": 492.73, "word": " إيش", "probability": 0.8665364583333334}, {"start": 492.73, "end": 493.01, "word": " معنى", "probability": 0.7681477864583334}, {"start": 493.01, "end": 493.67, "word": " sugar،", "probability": 0.5579833984375}, {"start": 493.67, "end": 494.19, "word": " إيش", "probability": 0.9607747395833334}, {"start": 494.19, "end": 494.43, "word": " معنى", "probability": 0.9571940104166666}, {"start": 494.43, "end": 495.49, "word": " aldose،", "probability": 0.9064127604166666}, {"start": 495.49, "end": 495.71, "word": " إيش", "probability": 0.98583984375}, {"start": 495.71, "end": 496.17, "word": " معنى", "probability": 0.96826171875}, {"start": 496.17, "end": 497.55, "word": " ketose،", "probability": 0.5900065104166666}, {"start": 497.55, "end": 497.95, "word": " واضحة", "probability": 0.8892822265625}, {"start": 497.95, "end": 498.91, "word": " الفكرة؟", "probability": 0.912841796875}, 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في دي جولوكوز، بعد ما نحط هذه على اليمين، ضال عنده يمين شمال يمين، ولو كنا جايلين الجولوكوز، هتخلوا هذه تيجي هنا والباقي زي ما هو", "tokens": [7435, 12610, 2407, 4117, 2407, 11622, 12399, 11933, 1829, 8592, 20449, 8315, 3224, 11778, 1829, 22807, 36145, 3224, 29538, 5296, 31377, 2304, 6055, 30544, 15844, 2423, 32640, 9957, 12399, 6024, 48506, 8978, 11778, 1829, 10874, 12610, 2407, 4117, 2407, 11622, 12399, 39182, 19446, 8717, 5016, 9566, 29538, 15844, 2423, 32640, 9957, 12399, 48812, 6027, 43242, 3224, 7251, 2304, 9957, 13412, 2304, 6027, 7251, 2304, 9957, 12399, 4032, 1211, 2407, 9122, 8315, 10874, 47302, 1211, 9957, 25724, 12610, 2407, 4117, 2407, 11622, 12399, 8032, 2655, 9778, 1211, 14407, 29538, 6055, 1829, 7435, 1829, 34105, 16070, 3555, 995, 38436, 30767, 1829, 19446, 31439], "avg_logprob": -0.18167892828875898, "compression_ratio": 1.9314285714285715, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1438.32, "end": 1439.04, "word": "جولوكوز،", "probability": 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{"start": 1955.57, "end": 1955.81, "word": " على", "probability": 0.876953125}, {"start": 1955.81, "end": 1956.15, "word": " هذا", "probability": 0.93505859375}, {"start": 1956.15, "end": 1956.91, "word": " الكربون", "probability": 0.98388671875}, {"start": 1956.91, "end": 1957.49, "word": " ايش", "probability": 0.80322265625}, {"start": 1957.49, "end": 1957.89, "word": " بيصير", "probability": 0.7896728515625}, {"start": 1957.89, "end": 1958.67, "word": " عندى؟", "probability": 0.705078125}, {"start": 1958.67, "end": 1959.63, "word": " two", "probability": 0.61669921875}, {"start": 1959.63, "end": 1960.67, "word": " enantiomers", "probability": 0.7694091796875}], "temperature": 1.0}, {"id": 84, "seek": 197295, "start": 1961.63, "end": 1972.95, "text": "مظبوط ولا لأ؟ الان هدولة لما بدهم يتموه طبعا مش two enantiomers أقفل two diastereomers ليش؟ لأن أنا مش generation of the first chiral center", "tokens": [2304, 19913, 3555, 2407, 9566, 49429, 5296, 10721, 22807, 2423, 7649, 8032, 3215, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e0811fe4c9950f5bca860343df18b7123065ddb4
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.srt
@@ -0,0 +1,2092 @@
+1
+00:00:19,570 --> 00:00:24,470
+بسم الله الرحمن الرحيم اليوم ان شاء الله بنشرح
+
+2
+00:00:24,470 --> 00:00:31,450
+معلومات ايضا مختصرة على موضوع ال carbohydrates جزء
+
+3
+00:00:31,450 --> 00:00:39,870
+من ال biochemistry طبعا ال carbohydrates هم اكثر
+
+4
+00:00:40,850 --> 00:00:46,930
+جزيئات يمكن موجودة في الطبيعة من الجزيئات الحيوية
+
+5
+00:00:46,930 --> 00:00:51,770
+يمكن البعض يستغرب لكن لما تفكروا بس قداش في
+
+6
+00:00:51,770 --> 00:00:57,810
+بالدنيا نباتات و النباتات بشكل أساسي cellulose و
+
+7
+00:00:57,810 --> 00:01:03,430
+ال cellulose هو عبارة عن carbohydrates هذا الكلام
+
+8
+00:01:03,430 --> 00:01:09,890
+يمكن يعطيكم إيش فكرةبشكل عام ال carbohydrates
+
+9
+00:01:09,890 --> 00:01:16,010
+الصيغة تبعتهم هي عبارة عن carbon مع مية مكررين
+
+10
+00:01:16,010 --> 00:01:21,890
+يعني CH2O to the N فمن هنا إجت فكرة carbohydrates
+
+11
+00:01:21,890 --> 00:01:29,250
+يعني ال carbons وبعدين الميةCarbons وميّه واضح
+
+12
+00:01:29,250 --> 00:01:34,130
+فعلى سبيل المثال يعني لو بدكوا تاخدوا أنتوا أبسط
+
+13
+00:01:34,130 --> 00:01:42,510
+سكر .. أبسط سكر اللي هو C6H12O6
+
+14
+00:01:42,510 --> 00:01:51,010
+الآن بنقدر نقول هذا عبارة عن 6 في C وH2O
+
+15
+00:01:51,010 --> 00:01:58,700
+فهو مضاعف لل Carbon و الميّهواضح؟ C6H12O6
+
+16
+00:01:58,700 --> 00:02:04,900
+واضح الفكرة؟ ومن هنا إجا الاسم carbohydrate لأنه
+
+17
+00:02:04,900 --> 00:02:11,740
+بشكل أساسي الصيغة البسيطة تبعته هي عبارة عن carbon
+
+18
+00:02:11,740 --> 00:02:17,700
+وميه واضح هذه الفكرة؟ يعني لما نيجي نسألكم أن ال
+
+19
+00:02:17,700 --> 00:02:20,660
+carbohydrates الصيغة الأساسية بتاعتهم carbon و
+
+20
+00:02:20,660 --> 00:02:25,540
+oxygen carbon و hydrogenلأ لو كربون و هيدروجين كال
+
+21
+00:02:25,540 --> 00:02:30,800
+سمناها hydrocarbon لكن carbohydrate يعني كربون و
+
+22
+00:02:30,800 --> 00:02:35,840
+مياه الآن ال carbohydrates ببساطة احنا بنقدر
+
+23
+00:02:35,840 --> 00:02:41,260
+نتخيلها اذا بنفهمها بالشكل القاتل هي عبارة عن
+
+24
+00:02:41,260 --> 00:02:47,540
+جزيئات في الغالب كبيرة يعني ممكن نتخيل ان هذا جزيئ
+
+25
+00:02:48,170 --> 00:02:55,070
+كبير أشبه ما تكون بوليمار تمام الآن هذه الجزيئات
+
+26
+00:02:55,070 --> 00:02:59,650
+الكبيرة بنسميها احنا polysaccharides يعني سكريات
+
+27
+00:02:59,650 --> 00:03:05,720
+اشمالها عديدة لو عملنا لها hydrolysisفي وجود حمض
+
+28
+00:03:05,720 --> 00:03:12,200
+ميه بتتكسر الى جزيئات اصغر من وحدتين او تلاتة هذه
+
+29
+00:03:12,200 --> 00:03:16,980
+الجزيئات الاصغر بنسميها oligosaccharides يعني هي
+
+30
+00:03:16,980 --> 00:03:21,780
+كانت الكبيرة polysaccharide اتكسرت الى
+
+31
+00:03:21,780 --> 00:03:26,720
+oligosaccharides سكريات بسيطة زى السكريات الثنائية
+
+32
+00:03:26,720 --> 00:03:31,770
+هتمر علينا الان لو كسرناها اكتربصير عندى
+
+33
+00:03:31,770 --> 00:03:37,150
+monosaccharides اللى هو السكر المنفرد فإحنا لما
+
+34
+00:03:37,150 --> 00:03:41,750
+بدنا ندرس الآن بهذا الفصل و نتعرف على السكريات
+
+35
+00:03:41,750 --> 00:03:47,110
+هيكون المحور تبعنا بسيط جدا هنبدأ نقول إيش والله
+
+36
+00:03:47,110 --> 00:03:53,090
+ال monosaccharidesالمنفرد بعد هيك من اكثر من
+
+37
+00:03:53,090 --> 00:03:57,690
+monosaccharide هنعمل disaccharide اللي هو نوع من
+
+38
+00:03:57,690 --> 00:04:01,970
+ال oligosaccharide هيطلع عند السكاروز والملتوز
+
+39
+00:04:01,970 --> 00:04:06,430
+والاشياء هذه اللي هيواضح؟ الآن من ال
+
+40
+00:04:06,430 --> 00:04:11,950
+oligosaccharides هنعمل الجزيئات الكبيرة بشكل أساسي
+
+41
+00:04:11,950 --> 00:04:17,870
+النشا ال starch و ال cellulose واضح؟ فاحنا هنمشي
+
+42
+00:04:17,870 --> 00:04:22,110
+بهذا التدريج أن نتعرف في البداية شو هي ال
+
+43
+00:04:22,110 --> 00:04:27,120
+monosaccharides شو معناه sugarمنفرد لوحده الآن بعد
+
+44
+00:04:27,120 --> 00:04:32,160
+هيك اتنين من الشجر المنفرد هيعملولي Dysaccharide
+
+45
+00:04:32,160 --> 00:04:36,280
+اللي هو يعتبر نوع من ال Oligosaccharides و بعدين
+
+46
+00:04:36,280 --> 00:04:41,180
+لو اتحدوا ال Dysaccharides بشكل كبير عدد كبير منهم
+
+47
+00:04:41,180 --> 00:04:46,140
+بيعطينا ال إيش ال polysaccharides على سبيل المثال
+
+48
+00:04:46,140 --> 00:04:52,890
+النشا polysaccharideالنشط بولي ساكرايد لو عملنا له
+
+49
+00:04:52,890 --> 00:04:58,510
+هيدروليسيز بيعطينا داي ساكرايد اللي هو الملتوز
+
+50
+00:04:58,510 --> 00:05:03,950
+فالملتوز أوليغو ساكرايد أو داي ساكرايد ما هو الداي
+
+51
+00:05:03,950 --> 00:05:08,910
+أحد أنواع الأوليغو ساكرايد الآن لو الملتوز كسرناه
+
+52
+00:05:08,910 --> 00:05:16,240
+للوحدات الأساسية هو مكون من وحدتين جولوكوزالملتوز
+
+53
+00:05:16,240 --> 00:05:21,220
+من وحدتين جولوكوز واضح الفكرة فالجولوكوز مونو
+
+54
+00:05:21,220 --> 00:05:27,760
+ساكرايد الملتوز داي ساكرايد الاسترش بوني ساكرايد
+
+55
+00:05:27,760 --> 00:05:34,260
+واضح طبعا اللي بده يبتدى الان يتعرف ايش هم المونو
+
+56
+00:05:34,260 --> 00:05:37,300
+ساكرايد ايش هم المونو ساكرايد
+
+57
+00:05:40,150 --> 00:05:45,650
+ال sugar بنعرفهم انهم polyhydroxyaldehydes او
+
+58
+00:05:45,650 --> 00:05:49,670
+polyhydroxyketones ال polyhydroxyaldehydes بنسميهم
+
+59
+00:05:49,670 --> 00:05:54,130
+ال doses و ال polyhydroxyketones كيتوزز بمعنى
+
+60
+00:05:54,130 --> 00:06:01,070
+الشجر لازم يكون فيه يا aldehyde يا كيتون مع
+
+61
+00:06:01,070 --> 00:06:09,170
+مجموعات OH كتيرة اكثر من مجموعة OHولذلك لو احنا
+
+62
+00:06:09,170 --> 00:06:13,850
+اتطلعنا مثلا على المركب اللى موجود عندنا هنا اللى
+
+63
+00:06:13,850 --> 00:06:19,570
+هو الجليسرال ديهايد هل يترى هذا يمكن انه يتصنف
+
+64
+00:06:19,570 --> 00:06:27,510
+بمنطق الكيميا ك sugar فى عندي هنا الديهايد وفى
+
+65
+00:06:27,510 --> 00:06:35,050
+عندي هنا مجموعاتOH إذا هذا بولي هيدروكسي الديهايد
+
+66
+00:06:35,050 --> 00:06:39,330
+يعني عديد هيدروكسي ال الديهايد ولذلك هذا بنقول عنه
+
+67
+00:06:39,330 --> 00:06:45,550
+إيش ال dose ال dose يعني sugar من ال الديهايد طيب
+
+68
+00:06:45,550 --> 00:06:50,570
+ال dye هيدروكسي أسيتون بتعرفوا ال أسيتون CH3C
+
+69
+00:06:50,570 --> 00:06:55,130
+double bond O CH3 شيلت H حطيت مكان هنا OH وكمان
+
+70
+00:06:55,130 --> 00:07:01,270
+هنا OH صارDihydroxy-13-Dihydroxyacetone الآن هذا
+
+71
+00:07:01,270 --> 00:07:08,050
+الـDihydroxyacetone فيه كيتون وفيه
+
+72
+00:07:08,050 --> 00:07:14,870
+مجموعات OH إذا هذا عبارة عن بوليهيدروكس كيتون
+
+73
+00:07:14,870 --> 00:07:20,010
+بوليهيدروكس كيتون إذا هذا sugar كيتوز
+
+74
+00:07:21,950 --> 00:07:27,190
+ليش؟ لأنه جاي من كيتون، الدوز من ال الديهايد، واضح
+
+75
+00:07:27,190 --> 00:07:34,110
+الفكرة؟ الآن لو اتطلعت على ال glycerol، ال
+
+76
+00:07:34,110 --> 00:07:37,950
+glycerol او ال glycerin، فيه بس ال O H's، مافيه
+
+77
+00:07:37,950 --> 00:07:43,190
+الديهايد او كيتون، فهل ال glycerin بنصنفه انه
+
+78
+00:07:43,190 --> 00:07:46,930
+sugar كيميائيا؟ لأواضحة الفكرة؟ يعني لما نيجي
+
+79
+00:07:46,930 --> 00:07:51,410
+نقولكم glycerol can be classified as a sugar او is
+
+80
+00:07:51,410 --> 00:07:54,630
+classified as a sugar، لأ، لو قلنالكوا
+
+81
+00:07:54,630 --> 00:08:01,810
+dihydroxyacetone is an aldose، فهمته؟ او لو
+
+82
+00:08:01,810 --> 00:08:07,390
+قلنالكوا glyceraldehyde is equitoseglial aldehyde
+
+83
+00:08:07,390 --> 00:08:11,630
+is an aldose, dihydroxyacetone is a ketose تفهمنا
+
+84
+00:08:11,630 --> 00:08:15,710
+بالظبط إذا إيش معنى sugar، إيش معنى aldose، إيش
+
+85
+00:08:15,710 --> 00:08:20,550
+معنى ketose، واضحة الفكرة؟ والشجر لازم ينوجد فيه
+
+86
+00:08:20,550 --> 00:08:26,790
+كام شغلة؟ شغلتين، يا الديهيد، يا كيتون، ومجموعات
+
+87
+00:08:26,790 --> 00:08:35,230
+الـOH، هذا اللي بدنا نصنفه sugarلو بدنا ننطلق من
+
+88
+00:08:35,230 --> 00:08:40,850
+ال glyceraldehyde، ال glyceraldehyde كم carbon كان
+
+89
+00:08:40,850 --> 00:08:47,710
+فيه؟ تلاتة، تلاتة، احنا بدنا نعلمكوا العد، تلاتة،
+
+90
+00:08:47,710 --> 00:08:49,670
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+91
+00:08:49,670 --> 00:08:51,370
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+92
+00:08:51,370 --> 00:08:51,370
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+93
+00:08:51,370 --> 00:08:51,370
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+94
+00:08:51,370 --> 00:08:58,720
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تهي الديهيد و
+
+95
+00:08:58,720 --> 00:09:02,360
+أكتر من جمعة أواتش هذا بنقول عنه تيتروز تيتروز
+
+96
+00:09:02,360 --> 00:09:09,430
+يعني سكر إيش من أربع كربونات طب لو كانوا خمسةبنتوز
+
+97
+00:09:09,430 --> 00:09:14,530
+لو كانوا ستة هكسوز طبعا هذه كلها اللي موجودة عندنا
+
+98
+00:09:14,530 --> 00:09:20,150
+لأن الجزء الأول فيها الديهيد they are all doses طب
+
+99
+00:09:20,150 --> 00:09:25,830
+لو كان فيها كيتون برضه هذا تتروز وبنتوز وهكسوز لكن
+
+100
+00:09:25,830 --> 00:09:31,590
+هذه ايش كيتوز واضح؟ الان كل واحد هياخد اسم تفصيلي
+
+101
+00:09:31,590 --> 00:09:36,490
+بس بشكل عام ممكن السكر يكون من تلات ذرات من أربعة
+
+102
+00:09:36,490 --> 00:09:41,610
+من خمسة من ستةيعني هدولة خلينا نقول الاش المشهورين
+
+103
+00:09:41,610 --> 00:09:48,410
+الآن لو بدنا نتطلع في ال sugars و اتطلعنا على أبسط
+
+104
+00:09:48,410 --> 00:09:54,770
+واحد فيهم ال glyceraldehyde ع طول هنلاحظ أن هذا ال
+
+105
+00:09:54,770 --> 00:10:00,310
+glyceraldehyde فيه chiral center يعني لو اتطلعنا
+
+106
+00:10:00,310 --> 00:10:03,210
+ال C double bond OH اللي هو جزء ال aldehyde هذا
+
+107
+00:10:03,210 --> 00:10:06,090
+مافيش فيه chiral center ال chiral center أربع
+
+108
+00:10:06,090 --> 00:10:12,980
+مجموعاتمختلفة، الآن ال CH2OH الأخيرة مافيها chiral
+
+109
+00:10:12,980 --> 00:10:19,460
+center، الكاربون الوسطني هاديفيها chiral center
+
+110
+00:10:19,460 --> 00:10:22,940
+الكربون الوسطاني اللي موجود عندنا فيها chiral
+
+111
+00:10:22,940 --> 00:10:28,920
+center الآن لاحظوا معي انه في ال sugars في ال
+
+112
+00:10:28,920 --> 00:10:34,760
+sugars هذه جزيئات شوية كبيرة وكل واحد ممكن يرسمها
+
+113
+00:10:34,760 --> 00:10:38,880
+بطريقة معينة يعني واحد ممكن يرسم واقف نايم مائل
+
+114
+00:10:38,880 --> 00:10:45,000
+عشان يسهلوا تبعون ال biochemistry على بعض المتابعة
+
+115
+00:10:45,000 --> 00:10:52,080
+اتفقواإنه يوحدوا طريقة الرسم، يعني ليش أضلني أتعب
+
+116
+00:10:52,080 --> 00:10:55,680
+الطالب مرة أحط مجموعة الالديهايد يمين، مرة شمال،
+
+117
+00:10:55,680 --> 00:10:59,820
+مرة فوق، مرة تحت، بره أرسم الجزء مائل، في كل لحظة
+
+118
+00:10:59,820 --> 00:11:04,670
+هو بيصير بحاجة إلىمزيد من التفكير و من الوقت عشان
+
+119
+00:11:04,670 --> 00:11:10,530
+يفهم إيش شكل الجزء فقالوا إيش المانع؟ إيش المانع؟
+
+120
+00:11:10,530 --> 00:11:15,910
+إن نوحد طريقة الرسم لما نرسم ال sugars بدل ما كل
+
+121
+00:11:15,910 --> 00:11:18,650
+واحد يرسمه بطريقة معينة و نقعد نقول وين ال
+
+122
+00:11:18,650 --> 00:11:22,350
+aldehyde وين ال OHS وين ال chiral center ليش ما
+
+123
+00:11:22,350 --> 00:11:29,310
+نرسم بطريقة موحدة؟بنسهل على الناس تمام؟ طيب إيش
+
+124
+00:11:29,310 --> 00:11:33,910
+فكرة الرسم بالطريقة الموحدة؟ جال خلّي المجموعة
+
+125
+00:11:33,910 --> 00:11:37,210
+اللي هي الكبيرة ال carbon اللي حاملة أعلى إشي اللي
+
+126
+00:11:37,210 --> 00:11:42,630
+هي ال aldehyde تكون لفوق و ارسم بهذا الشكل العمودي
+
+127
+00:11:42,630 --> 00:11:46,950
+واضح؟ يعني نخلي مجموعة ال aldehyde أو ال keto اللي
+
+128
+00:11:46,950 --> 00:11:54,970
+وجدت لأعلى و بنرسم بشكل عموديطبعا اخر شئ هنا هيكون
+
+129
+00:11:54,970 --> 00:12:03,090
+عندى CH2OH الان ايش ضال عندى على الوسط OH OH ضال
+
+130
+00:12:03,090 --> 00:12:09,030
+عندى في الوسط OH OH هذه ال OH OH بالتأكيد طالما
+
+131
+00:12:09,030 --> 00:12:14,830
+هذا chiral center هيكون فيه الجزئ و صورتهفى
+
+132
+00:12:14,830 --> 00:12:18,490
+المراية حيكون عند الجزء و صورته فى المراية لو
+
+133
+00:12:18,490 --> 00:12:22,630
+جربنا ان نشوف ال configuration إيه لو جربنا نشوف
+
+134
+00:12:22,630 --> 00:12:29,390
+ال configuration إيه هتتذكروا ان هذه أقل مجموعة و
+
+135
+00:12:29,390 --> 00:12:33,570
+ال oxygen أعلى مجموعة بعدين الكاربون اللى متصل
+
+136
+00:12:33,570 --> 00:12:37,490
+مرتين بال oxygen بعدها بعدين الكاربون اللى متصل
+
+137
+00:12:37,490 --> 00:12:41,830
+مرة بال oxygen وبناء على ذلك لو أنا بدي أمشي هى
+
+138
+00:12:41,830 --> 00:12:50,270
+نمره واحدنمرة اتنين، نمرة تلاتة، مبينة كإنها S،
+
+139
+00:12:50,270 --> 00:12:54,830
+لكن لأن هذه المجموعة الصغيرة للأمام، بنعكس ال
+
+140
+00:12:54,830 --> 00:13:01,270
+configuration، إذن هذا Rوبالتجربة ال R طلع بلس
+
+141
+00:13:01,270 --> 00:13:04,390
+بتذكرين لما قولنا ال plus و ال minus هذا من قصة
+
+142
+00:13:04,390 --> 00:13:09,330
+بالتجربة بال بولاريمتر الآن هذا بالتأكيد ال
+
+143
+00:13:09,330 --> 00:13:13,490
+enantiomer التاني هو ال S فبناء على ذلك ال
+
+144
+00:13:13,490 --> 00:13:19,650
+glyceraldehyde طالما في one chiral center إذا في
+
+145
+00:13:19,650 --> 00:13:27,060
+منه كام مركب اتنين R و Sالان تابعون ال
+
+146
+00:13:27,060 --> 00:13:32,020
+biochemistry قالوا احنا بنحب الخصوصية مش حابين
+
+147
+00:13:32,020 --> 00:13:36,580
+نظلنا مربوطين في جماعة الكيميا طب ليش يا عم
+
+148
+00:13:36,580 --> 00:13:41,800
+بتزيدوا غلبتنا قال بهمش الطلاب بتحملونا ايش اللي
+
+149
+00:13:41,800 --> 00:13:48,740
+بدكمياه قال بدل ما نستعمل ال R و ال S نستعمل D و L
+
+150
+00:13:50,330 --> 00:13:54,210
+هما لو ضالوا على ال R و ال S العلم بيمشي لكن قرروا
+
+151
+00:13:54,210 --> 00:13:59,650
+انهم بيستعملوا D و L الآن ضمن هذا الشكل اللي رسمنا
+
+152
+00:13:59,650 --> 00:14:02,450
+فيه يعني المجموعة هذه ال الدياد أو ال keto اللي
+
+153
+00:14:02,450 --> 00:14:07,630
+فوق قالوا إذا كانت ال OH على ال carbon اللي هي قبل
+
+154
+00:14:07,630 --> 00:14:10,770
+الأخيرة منها يعني هي أخر carbon من تحتها دي اللي
+
+155
+00:14:10,770 --> 00:14:16,010
+قبلها إذا كانت ال OH على اليمين بنعطي للمركب الرمز
+
+156
+00:14:16,500 --> 00:14:22,460
+وإذا كانت الـ OH على الشمال بنعطي المركب الرمز L
+
+157
+00:14:22,460 --> 00:14:27,540
+فصيرنا نقول هذا دي إجليسرال ديهيد وهال و هذا
+
+158
+00:14:27,540 --> 00:14:33,000
+الإجليسرال ديهيد الآن هم ركزوا على أي كاربون
+
+159
+00:14:33,000 --> 00:14:38,980
+تحديدا حاملة الـ OHالـ OH اللي جابلي الأخيرة، ليش؟
+
+160
+00:14:38,980 --> 00:14:42,820
+لأنه بعد شوية .. بعد شوية حيصير عندى أكثر من
+
+161
+00:14:42,820 --> 00:14:47,580
+Carbon بتحمل OH OH OH OH و أكثر من chiral center
+
+162
+00:14:47,580 --> 00:14:52,680
+مين فيهم اللي بدي أوصفه أنه D أو L؟ وين بدي أطلع؟
+
+163
+00:14:52,680 --> 00:14:56,940
+بدي أطلع مش على آخر Carbon، آخر Carbon مش chiral
+
+164
+00:14:56,940 --> 00:15:02,660
+أول Carbon chiral من تحت، اللي هي نمرة 2، لأن هو
+
+165
+00:15:02,660 --> 00:15:08,570
+اللي مش chiralواضح فلما انا بدي بعد شوية اصير اطلع
+
+166
+00:15:08,570 --> 00:15:15,310
+هيك على شكله و اقول هذا D ولا L بدي اطلع وين من
+
+167
+00:15:15,310 --> 00:15:23,190
+التحت طبعا هنا في عندي scheme كيف ببدأ انا ازيد في
+
+168
+00:15:23,190 --> 00:15:28,070
+مجموعات ال OH يعني اول ما بدأت تلاتة بعد هيك ببدأ
+
+169
+00:15:28,070 --> 00:15:34,930
+ازيد واضح انه هذا ال scheme يمكناضعيف جدا و لذلك
+
+170
+00:15:34,930 --> 00:15:41,230
+انا حاولت ان اجزء هذا ال scheme لأشياء لعلها تكون
+
+171
+00:15:41,230 --> 00:15:47,490
+أوضح لاحظوا معي بالنسبة لل glyceral dehyd هي ال OH
+
+172
+00:15:47,490 --> 00:15:52,200
+هنا على اليمين اذا انا جيبت بس منه ايش؟الـ D
+
+173
+00:15:52,200 --> 00:15:57,540
+-Glyceraldehyde الان يا ترى لو بدى ازيد كربون تانى
+
+174
+00:15:57,540 --> 00:16:03,280
+على ال D-Glyceraldehyde وين بدى اجي احطها؟ بهذا
+
+175
+00:16:03,280 --> 00:16:14,060
+الموقع واضح؟ هذه الكربون حاملةوح وح وح
+
+176
+00:16:14,060 --> 00:16:16,620
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+177
+00:16:16,620 --> 00:16:16,620
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+178
+00:16:16,620 --> 00:16:16,900
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+179
+00:16:16,900 --> 00:16:21,200
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+180
+00:16:21,200 --> 00:16:25,800
+وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+181
+00:16:25,800 --> 00:16:25,800
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+182
+00:16:25,800 --> 00:16:25,920
+وح وح وح وح وح وح وح وح وح وح وح
+
+183
+00:16:36,210 --> 00:16:40,270
+D لكن انا ال carbon اللي زيدتها في الوسط اللي الآن
+
+184
+00:16:40,270 --> 00:16:43,350
+بعلم عليها بالأحمر اللي هو ال chiral center التاني
+
+185
+00:16:43,350 --> 00:16:49,430
+مرة حطيت فيه ال OH علي اليمين و مرة حطيت فيه ال OH
+
+186
+00:16:49,430 --> 00:16:54,990
+علي الشمال بناء على ذلك لما انا زيدت من تلت ذرات
+
+187
+00:16:54,990 --> 00:17:01,630
+لاربع ذرات من ال D اعملت كام مركب اتنين طب لو
+
+188
+00:17:01,630 --> 00:17:07,900
+أخدنا الجزء التاني اللي هو ال Lهتكون ال OH هذه على
+
+189
+00:17:07,900 --> 00:17:11,820
+اليسار و هزيد واحدة مرة يمين و مرة شمال برضه هعمل
+
+190
+00:17:11,820 --> 00:17:19,400
+ايش؟ اتنين واضح؟ اذا كام مركب صار عندي من الاربع
+
+191
+00:17:19,400 --> 00:17:23,280
+ذرات كربون اللي هو two chiral centers؟ اربع احنا
+
+192
+00:17:23,280 --> 00:17:30,700
+أخدنا انهعدد الـ Stereoisomers 2 to the N فلما كان
+
+193
+00:17:30,700 --> 00:17:35,300
+عندي one chiral center كان عندي مركبين اللي هو الـ
+
+194
+00:17:35,300 --> 00:17:39,740
+D-glyceraldehyde و الـ L-glyceraldehyde طب الآن
+
+195
+00:17:39,740 --> 00:17:42,680
+لما زيدت كمان chiral center، one chiral center و
+
+196
+00:17:42,680 --> 00:17:47,170
+one chiral centerصار عندى كام مُركّب؟ أربعة شومة
+
+197
+00:17:47,170 --> 00:17:51,770
+الأربعة في عندى هذا المُركّب لأن هذه الـ OH أول
+
+198
+00:17:51,770 --> 00:17:57,210
+واحدة كيرال من تحت على اليمين دي بسميه D-erythrose
+
+199
+00:17:58,950 --> 00:18:03,570
+تمام؟ و لأن الـ OH هذه على الشمال بيصير مركّب تاني
+
+200
+00:18:03,570 --> 00:18:09,070
+طبعا هذه طالما علي اليمين هتعطيني كلمة إيش؟ D دي
+
+201
+00:18:09,070 --> 00:18:14,070
+هذا بسميه Ethreose فصار في عندي مركّب اسمه D
+
+202
+00:18:14,070 --> 00:18:20,410
+-Erythrose و مركّب اسمه D-Ethreose ال Erythrose زي
+
+203
+00:18:20,410 --> 00:18:24,570
+ما بتلاحظوا اللي موجودة فيه الـ OH التاني على
+
+204
+00:18:25,670 --> 00:18:31,110
+اليمين والثريوز اللي موجودة فيه هذه على اليسار طب
+
+205
+00:18:31,110 --> 00:18:36,720
+الأن وين المركبين التانيين؟الـ L اللي هم الـ L لما
+
+206
+00:18:36,720 --> 00:18:40,320
+بدي الـ L شو بدي أعمل بهدي؟ بدي أعكسها يعني أنا
+
+207
+00:18:40,320 --> 00:18:45,060
+هنا جايب نص الصورة جايب ال D زي ما فيه D بتاخدوا
+
+208
+00:18:45,060 --> 00:18:49,880
+نفس الجزيه تماما و بس بنعكس منه إيش الـ OH الـ OH
+
+209
+00:18:49,880 --> 00:18:55,720
+الخضرة أول واحدة كايرال من تحت طبعا هي بتكون تاني
+
+210
+00:18:55,720 --> 00:18:59,780
+واحدة لإن هذه مش كايرال هي أول واحدة كايرال من تحت
+
+211
+00:19:01,360 --> 00:19:06,880
+واضح الفكرة؟ الآن اتخيلوا من هدول الاتنين لو بدى
+
+212
+00:19:06,880 --> 00:19:12,040
+ازيد كمان ذرة carbon يعني اخليهم بدل اربعة خمسة
+
+213
+00:19:12,040 --> 00:19:20,280
+وين هازيد ذرة ال carbon هادي؟ هنا الان من هذه لما
+
+214
+00:19:20,280 --> 00:19:26,720
+بدى ازيد واحدة هنا وين هتيجي؟يا يمين، يا شمال، يا
+
+215
+00:19:26,720 --> 00:19:29,980
+شمال،
+
+216
+00:19:29,980 --> 00:19:37,580
+يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا
+
+217
+00:19:37,580 --> 00:19:42,640
+شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا شمال،
+
+218
+00:19:42,640 --> 00:19:45,500
+يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا
+
+219
+00:19:45,500 --> 00:19:46,080
+شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا شمال،
+
+220
+00:19:46,080 --> 00:19:46,080
+يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا
+
+221
+00:19:46,080 --> 00:19:52,290
+شمال، يا شمالتمانية اتنين اقصد تلاتة تمانية الان
+
+222
+00:19:52,290 --> 00:19:56,950
+لو بدنا نتعرف عليهم نتعرف على نصهم اللي هم جايين
+
+223
+00:19:56,950 --> 00:20:02,710
+من وين من ال D هاي المركب ال D اللي توي رسمناه
+
+224
+00:20:02,710 --> 00:20:09,850
+طالما هذي على اليمين اذا هذا D صحيح الان بدي ازيد
+
+225
+00:20:09,850 --> 00:20:17,330
+كمان هذا الرباعي لأ هذا صار الخماسي حط هذه وين مرة
+
+226
+00:20:18,610 --> 00:20:25,130
+يمين مرة شمال، الآن هذول أعطاهم أسماء، شو أعطاهم؟
+
+227
+00:20:25,130 --> 00:20:31,490
+دي رايبوز وهذا دي أرابينوز، ليش دي؟ لأنه هذي
+
+228
+00:20:31,490 --> 00:20:36,690
+عاليمين، الآن بنصير نقول شو هو الرايبوز؟ الرايبوز
+
+229
+00:20:36,690 --> 00:20:40,790
+السكر الخماسي اللي تلت مجموعات ال OH في جين ع جهة
+
+230
+00:20:40,790 --> 00:20:46,690
+واحدةالان الارابينوز الشو هو السكر الخماسي اللى
+
+231
+00:20:46,690 --> 00:20:50,930
+هدولة بتنتنع جهة وادي على جهة تانية لحظوا قاعدة
+
+232
+00:20:50,930 --> 00:20:57,170
+بتكتر المراكبات عندى هذا خمس درات كربون واحد اتنين
+
+233
+00:20:57,170 --> 00:21:02,690
+تلاتة اربعة خمسة بكم chiral center تلاتة طالما
+
+234
+00:21:02,690 --> 00:21:07,410
+عندى تلاتة chiral center اذا كم مركب تمانية وين
+
+235
+00:21:07,410 --> 00:21:16,070
+التمانية4D و 4R بالظبط واضحة؟
+
+236
+00:21:16,070 --> 00:21:22,770
+انا هنا بس أخدت الاريثروز و جسمته يتبعوا معاك هذا
+
+237
+00:21:22,770 --> 00:21:28,590
+بس اللي نتج من الاريثروز لما أجسم للثريوز بيعطيني
+
+238
+00:21:28,590 --> 00:21:35,410
+كمان اتنين اتنين و اتنين اربع اربع و هكذا واضح؟
+
+239
+00:21:35,410 --> 00:21:36,430
+هاي للثريوز
+
+240
+00:21:40,860 --> 00:21:44,360
+خلّينا هذا اللي اتعودنا نقول عنه دي نخليه باللون
+
+241
+00:21:44,360 --> 00:21:48,780
+الأخضر هذا السكر التالي الاثريوز مش احنا قولنا
+
+242
+00:21:48,780 --> 00:21:57,060
+الاريثروز و الاثريوز الاريثروز بيقسم لاتنين هايهم
+
+243
+00:21:57,060 --> 00:22:01,760
+و الاثريوز بيقسم لاتنين تانين الان الاتنين اللي
+
+244
+00:22:01,760 --> 00:22:05,820
+بيقسملهم الاثريوز بياخدوا اسم اكزايلوز و لاكزوز
+
+245
+00:22:07,610 --> 00:22:13,030
+فصار المجموع من الخماسي اربعة D و اربعة L كده؟
+
+246
+00:22:13,030 --> 00:22:19,030
+تمانية لو جينا اي واحد من هدولة بدنا نزيد له
+
+247
+00:22:19,030 --> 00:22:25,250
+chiral center هيقسم لإيش؟ لاتنين طالما وما تمانية
+
+248
+00:22:25,250 --> 00:22:29,290
+كل واحد يقسم لاتنين هيصير المجموع ستة عشر كلام
+
+249
+00:22:29,290 --> 00:22:32,650
+منطقي ليش؟ لأنه لما يصير عند اربعة chiral centers
+
+250
+00:22:32,650 --> 00:22:39,090
+اتنين اقص اربعة16 16 اتنين اقصى اربعة ستة عشر فلما
+
+251
+00:22:39,090 --> 00:22:43,230
+نيجي نتعرف عليهم لما نيجي نتعرف عليهم لو أخدنا
+
+252
+00:22:43,230 --> 00:22:49,250
+مثلا الريبوز هاي ال O H هذه العملة دي و زيدنا
+
+253
+00:22:49,250 --> 00:22:53,690
+كايرة ال center وين هنا
+
+254
+00:22:53,690 --> 00:23:01,730
+هذا هيعمل O H مرة يمين و مرة شمال
+
+255
+00:23:03,120 --> 00:23:07,240
+لو أخدنا الأرابينوز برضه وين بدنا نزيد الـ OH؟
+
+256
+00:23:07,240 --> 00:23:14,580
+هنا، هتيجي مرة يمين و مرة شمال، الآن هدولة بنبدأ
+
+257
+00:23:14,580 --> 00:23:19,980
+نعطيهم أسماء اللي كلهم جايين زي بعض سموه ألوز، هذا
+
+258
+00:23:19,980 --> 00:23:25,360
+تلاتة و بعدين واحدة زي بعض ألتروز، هذا الجولوكوز
+
+259
+00:23:25,360 --> 00:23:31,300
+صاحبنا، اللي بدأ تحفظ الجولوكوزيعني منهم كلهم بدنا
+
+260
+00:23:31,300 --> 00:23:34,860
+نقولكوا بس احفظوا الجولوكوز كيف ترتيب مجموعاته
+
+261
+00:23:34,860 --> 00:23:39,960
+طبعا اللي بدها تحفظ الجولوكوز بدها تقولوا one and
+
+262
+00:23:39,960 --> 00:23:44,440
+six carbonate صحيح؟ الآن الـC double bond OH
+
+263
+00:23:44,440 --> 00:23:51,400
+الالديهيد هذه لفوق أكيد مافيها نقاش والـCH2OH هذه
+
+264
+00:23:51,400 --> 00:23:59,040
+لتحت أكيد ولا فيها نقاش؟ الآن لو قلنا Dجولوكوز،
+
+265
+00:23:59,040 --> 00:24:03,900
+إيش معناه دي؟ إنه هذه لازم تكون على اليمين، الآن
+
+266
+00:24:03,900 --> 00:24:08,080
+في دي جولوكوز، بعد ما نحط هذه على اليمين، ضال عنده
+
+267
+00:24:08,080 --> 00:24:16,960
+يمين شمال يمين، ولو كنا جايلين الجولوكوز، هتخلوا
+
+268
+00:24:16,960 --> 00:24:22,200
+هذه تيجي هنا والباقي زي ما هوواضح؟ يعني اللي بيغير
+
+269
+00:24:22,200 --> 00:24:25,660
+دي و قل هذه المجموعة، هذه يمين دي، لو قلتلكوا بدي
+
+270
+00:24:25,660 --> 00:24:31,560
+القل جولوكوز، خدوا هذا الـD و غيروا بس هذه، إذا
+
+271
+00:24:31,560 --> 00:24:36,520
+كانت هذه يمين، دي جولوكوزة، الآن الخلاصة بهذا
+
+272
+00:24:36,520 --> 00:24:44,240
+الشكل، كم sugar طلع عنده؟16 16 sugar و الكلام
+
+273
+00:24:44,240 --> 00:24:49,740
+منطقي ليش من ال 6 كربونات لأن ال 6 كربونات فيهم 4
+
+274
+00:24:49,740 --> 00:24:55,760
+chiral centers و المركب مش symmetric 2 أس 4 16
+
+275
+00:24:55,760 --> 00:25:02,220
+الان لو بدنا هدولا ال 16 ناخد أسماءهم هاي أربعة
+
+276
+00:25:02,220 --> 00:25:06,020
+منهم الألوز و الألتروز و الجولوكوز و المانوز و لو
+
+277
+00:25:06,020 --> 00:25:12,140
+أخدنا الأربعة التانين اللي في الأساس جوا منالثريوز
+
+278
+00:25:12,140 --> 00:25:16,660
+الجولوز والأيدوز والجالاكتوز والتالوز الآن هذول
+
+279
+00:25:16,660 --> 00:25:21,460
+تمانية ايش التمانية التانية كل هذول التمانية دي
+
+280
+00:25:21,460 --> 00:25:30,640
+التمانية التانية ال ال واضح فبصف عندى ست عشر مركب
+
+281
+00:25:30,640 --> 00:25:37,340
+لل C6 لاحظوا معايا هذول الست عشر مركباخذين بعين
+
+282
+00:25:37,340 --> 00:25:42,040
+الاعتبار ان الجولوكوز بهذا الشكل موجود على شكل
+
+283
+00:25:42,040 --> 00:25:48,300
+فاتح مش مسكّر بعد شوية هانيجي نعمل ال cyclic sugar
+
+284
+00:25:48,300 --> 00:25:51,940
+يعني نخليه يسكّر على بعضه كيف بده يسكّر على بعضه
+
+285
+00:25:51,940 --> 00:25:55,340
+احنا لما شرحنا ال aldehyde قولنا لكم في عندي OH
+
+286
+00:25:55,340 --> 00:25:59,980
+وفي عندي aldehyde الكحول بتفعل مع ال aldehyde
+
+287
+00:25:59,980 --> 00:26:04,790
+يعطيني hemiacetalأخدناها كمثال فبنخلّي هذه تسكّر
+
+288
+00:26:04,790 --> 00:26:10,310
+هنا لو هذه سكّرت هنا هنعمل ال Cairo Center الخامس
+
+289
+00:26:10,310 --> 00:26:14,930
+وقت كام ايزومار حيصير عندى اذا صاروا خمس Cairo
+
+290
+00:26:14,930 --> 00:26:22,010
+Centers اتنين اص خمسة ايش اتنين اص خمسة اتنين
+
+291
+00:26:22,010 --> 00:26:28,310
+وتلاتين ايزومار واضح اتنين وتلاتين ايزومار هيكون
+
+292
+00:26:28,310 --> 00:26:39,230
+عندكم من ال C6من 6 ذرات كربون لاحظوا كم هو استيريو
+
+293
+00:26:39,230 --> 00:26:42,870
+كيميستر مهم يعني حد ما درسش استيريو كيميستر عمره
+
+294
+00:26:42,870 --> 00:26:48,360
+ممكن يستوعب موضوعالـ sugars مستحيل وهذا الكلام
+
+295
+00:26:48,360 --> 00:26:51,940
+اللي تقريبا احنا كنا حاطينه في ال scheme العام كنا
+
+296
+00:26:51,940 --> 00:26:57,380
+حاطين لكم كيف الزيادة one chiral center تمام
+
+297
+00:26:57,380 --> 00:27:01,660
+بيكونوا تنين أخدت واحد منهم اعملتله زيادة chiral
+
+298
+00:27:01,660 --> 00:27:06,150
+صاروايعني هن واحد و في واحد تاني موجود يعني لو حد
+
+299
+00:27:06,150 --> 00:27:09,690
+بده يحط ال scheme كاملا بده يجد هذا ال scheme و
+
+300
+00:27:09,690 --> 00:27:12,310
+يحط واحد تاني ليش؟ لأنه انا هن بدت بال D
+
+301
+00:27:12,310 --> 00:27:17,870
+-Glyceraldehyde فيه زيه ال glyceraldehyde و بيقسم
+
+302
+00:27:17,870 --> 00:27:24,430
+بنفس الشكل و بياخد نفس الأسماء طبعا لاحظوا معي أن
+
+303
+00:27:24,430 --> 00:27:29,740
+الأسماء الأساسية الأسماء الأساسية كام اسمتمانية
+
+304
+00:27:29,740 --> 00:27:36,860
+الأسماء الأساسية تمانية اللي هي موجودين
+
+305
+00:27:36,860 --> 00:27:40,560
+عندكم الالوز والألتروز والجولوكوز والمانوز وكذا
+
+306
+00:27:40,560 --> 00:27:47,020
+كذا الآن كيف التمانية بيصيروا الست عاشر طبعا
+
+307
+00:27:47,020 --> 00:27:51,120
+هذا الكلام بإمكانكم أنتم تجلسوا تتدربوا عليه
+
+308
+00:27:51,120 --> 00:27:58,200
+تقرؤوا زي ما قلنا مش ضروري أننا بدنا نحفظهالان لسه
+
+309
+00:27:58,200 --> 00:28:03,880
+الكيميائيين ما شبعوش يعني وصلوكوا ل 16 مركب و بدهم
+
+310
+00:28:03,880 --> 00:28:11,550
+ايش؟وبدهم اكتر قالوا طالما ان السكر فيه OH وفيه
+
+311
+00:28:11,550 --> 00:28:16,050
+الديهايد يعني الكحول و الديهايد نرجع لكيمية ال
+
+312
+00:28:16,050 --> 00:28:20,790
+الديهايد ماش كنا نقول ان ال الديهايد بيعمل تفاعل
+
+313
+00:28:20,790 --> 00:28:26,050
+addition مع الكحولات وبيعطيني hemiacetal ال OH
+
+314
+00:28:26,050 --> 00:28:32,420
+بتهاجم علىالـ C double bond O تبعت ال الديهايد
+
+315
+00:28:32,420 --> 00:28:39,080
+بتخليها OH متذكرينه التفاعل ولا نذكر فيه الناس
+
+316
+00:28:39,080 --> 00:28:43,340
+اللي مش متذكرينه التفاعل نكتبها لما كنا نقول مثلا
+
+317
+00:28:43,340 --> 00:28:51,840
+Methanol مثل OH هي نرسمه بالأسود زائد CH3C double
+
+318
+00:28:51,840 --> 00:29:00,510
+bond OH هي الكحول وهي إيش؟الالديهيد هذه الكحول
+
+319
+00:29:00,510 --> 00:29:05,190
+وهذه الالديهيد لو قلنا لكوا في الامتحان اكمل هذه
+
+320
+00:29:05,190 --> 00:29:08,910
+المعادلة كيف بتفعل الكحول و الالديهيد مش هذا
+
+321
+00:29:08,910 --> 00:29:14,550
+نيوكليوفاين بيعمل addition بيجي بها جمهان وهذا
+
+322
+00:29:14,550 --> 00:29:22,690
+بتصير OH وبناء على ذلك هيكون الناتج CH3C
+
+323
+00:29:22,690 --> 00:29:29,250
+هذا صفية OH وهذا ال H الأصلية وإيجي عندنا من هناو
+
+324
+00:29:29,250 --> 00:29:34,870
+مثل هذا شو سمنا Himacetal Himacetal Himacetal
+
+325
+00:29:34,870 --> 00:29:39,790
+Himacetal
+
+326
+00:29:39,790 --> 00:29:44,810
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+327
+00:29:44,810 --> 00:29:45,610
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+328
+00:29:45,610 --> 00:29:45,770
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+329
+00:29:45,770 --> 00:29:45,810
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+330
+00:29:45,810 --> 00:29:45,810
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+331
+00:29:45,810 --> 00:29:45,890
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+332
+00:29:45,890 --> 00:29:45,890
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+333
+00:29:45,890 --> 00:29:45,890
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+334
+00:29:45,890 --> 00:29:47,790
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+335
+00:29:47,790 --> 00:29:55,530
+Himacetal Himacetal Himacetal
+
+336
+00:29:55,530 --> 00:30:07,430
+Himacetal HimacetHemiacetal OR و OR أسيتال، الآن
+
+337
+00:30:07,430 --> 00:30:12,770
+السكر فيه OH و فيه الديهايد، إيش المانع إنهم
+
+338
+00:30:12,770 --> 00:30:19,560
+يسكروا على بعض؟فيش مانع، وعشان هيك بيصير بيعمل
+
+339
+00:30:19,560 --> 00:30:23,580
+الشكل الحلقي، بنفس منطقة هذا التفاعل، يعني هذا
+
+340
+00:30:23,580 --> 00:30:28,440
+تفاعل تذكير كيف كان الكحول يتفاعل مع إيش؟ مع ال
+
+341
+00:30:28,440 --> 00:30:35,450
+الديهيد، الآن بدنا نرجع لهمفي السكر بدا نرجع للسكر
+
+342
+00:30:35,450 --> 00:30:41,710
+و نشوف كيف بتم هذا التفاعل هاي السكر بنرسمه بشكل
+
+343
+00:30:41,710 --> 00:30:46,070
+ملتوى خليكوا تطلعوا معنا هاي ال الديهايد C double
+
+344
+00:30:46,070 --> 00:30:50,430
+bond O و بعدين carbon حاملة OH و carbon حاملة OH و
+
+345
+00:30:50,430 --> 00:30:56,150
+carbon حاملة OH و هذه اللي هي ال carbon اللي كانت
+
+346
+00:30:56,150 --> 00:31:00,710
+معطية ال D اللي هي القبل الأخيرة
+
+347
+00:31:06,670 --> 00:31:14,590
+الان من ناحية المبدأ كل OH من هدوله ممكن تسكر على
+
+348
+00:31:14,590 --> 00:31:19,780
+ال الديهايديعني نظرياً هذه الـ OH ممكن تسكر على ال
+
+349
+00:31:19,780 --> 00:31:23,320
+الديهاد تعطينا حلقة ثلاثية، هذه ممكن تسكر على ال
+
+350
+00:31:23,320 --> 00:31:26,600
+الديهاد تعطينا حلقة رباعية، هذه ممكن تسكر على
+
+351
+00:31:26,600 --> 00:31:30,260
+الديهاد تعطينا حلقات خماسية، هذه ممكن تسكر تعطينا
+
+352
+00:31:30,260 --> 00:31:35,020
+حلقة سداسية، هذه ممكن تسكرتعطي حلقة سباعية لكن
+
+353
+00:31:35,020 --> 00:31:41,200
+أشهر إغلاق اللي بيعطي الحلقة السداسية فال OH اللي
+
+354
+00:31:41,200 --> 00:31:45,600
+بتسكر في حالة الجولوكوز هي ال OH اللي كانت تتحدد
+
+355
+00:31:45,600 --> 00:31:50,620
+ال D والL ال OH هذه اللي جاب للاخيرة الآن هذه بدأ
+
+356
+00:31:50,620 --> 00:31:56,400
+تيجي تسكر هناهيصير عندى كايرال سنتر جديد يعنى هذه
+
+357
+00:31:56,400 --> 00:32:01,420
+ال carbon هتعمل ايش كايرال سنتر جديد طب انا فى
+
+358
+00:32:01,420 --> 00:32:08,060
+الأساس كام كايرال سنتر عندى هى واحد اتنين تلاتة
+
+359
+00:32:08,060 --> 00:32:14,440
+اربعة ولمّا اجى اعمل هنا الإغلاق هيصيروا ايش خمسة
+
+360
+00:32:15,390 --> 00:32:20,530
+هيصيروا خمسة chiral centers وبناء على ذلك لاحظوا
+
+361
+00:32:20,530 --> 00:32:25,890
+معاه ان هدولة اللي هم ابعد عن التفاعل بيظلوا زي ما
+
+362
+00:32:25,890 --> 00:32:29,730
+هم لكن انا بدي اعمل generation لل chiral center
+
+363
+00:32:29,730 --> 00:32:33,830
+على هذا الكربون تحديدا بناء على ذلك لما بعمل
+
+364
+00:32:33,830 --> 00:32:37,490
+generation لل chiral center على هذا الكربون ايش
+
+365
+00:32:37,490 --> 00:32:43,330
+بيصير عندى؟ two enantiomersمظبوط ولا لأ؟ الان
+
+366
+00:32:43,330 --> 00:32:48,470
+هدولة لما بدهم يتموه طبعا مش two enantiomers أقفل
+
+367
+00:32:48,470 --> 00:32:51,450
+two diastereomers ليش؟ لأن أنا مش generation of
+
+368
+00:32:51,450 --> 00:32:55,860
+the first chiral centerاحنا قولنا two enantiomars
+
+369
+00:32:55,860 --> 00:33:00,960
+in equal ratios لو كان ايش؟ اول chiral center بس
+
+370
+00:33:00,960 --> 00:33:04,700
+هل هذا هو اول chiral center ولا نمرخمسة؟ نمرخمسة
+
+371
+00:33:04,700 --> 00:33:09,580
+نمرخمسة لما بنعمل chiral center اشديد second,
+
+372
+00:33:09,940 --> 00:33:13,600
+third, fourth, fifth chiral center شو كان يطلع
+
+373
+00:33:13,600 --> 00:33:18,860
+عندنا؟ اللي جيبناها سؤال في الامتحان unequal
+
+374
+00:33:18,860 --> 00:33:24,720
+mixture of diastereomersمتذكرينه؟ generation of a
+
+375
+00:33:24,720 --> 00:33:28,400
+second chiral center of a third of a fourth chiral
+
+376
+00:33:28,400 --> 00:33:31,640
+center produces an equal mixture of diastereomers
+
+377
+00:33:31,640 --> 00:33:35,320
+الألم هنا بدنا نشوف كيف هذا بده يصير chiral center
+
+378
+00:33:35,320 --> 00:33:41,720
+الـC ضبط هو بده تصير OH هذه الـOH مرة هتكون للأعلى
+
+379
+00:33:41,720 --> 00:33:50,080
+و مرة هتكون للأسفل هم
+
+380
+00:33:50,080 --> 00:33:54,910
+لاحظين؟هي ال chiral center مرة لفوق و مرة لتحت
+
+381
+00:33:54,910 --> 00:34:03,250
+واضح الفكرة؟ الآن في هذا الجزء صار عنده اللي هو ال
+
+382
+00:34:03,250 --> 00:34:07,930
+chiral center الخامس لحظة أنا بدأت بأي سكر؟ ال
+
+383
+00:34:07,930 --> 00:34:11,590
+جولوكوز ال D جولوكوز الآن ال D جولوكوز أعطاني كم
+
+384
+00:34:11,590 --> 00:34:18,270
+مركب؟ اتنين طب أنا كل السكريات اللي اتعرفت عليهم
+
+385
+00:34:18,270 --> 00:34:25,650
+قداش كانواكانوا ستة عشر تمانية D و تمانية L إذا ال
+
+386
+00:34:25,650 --> 00:34:30,410
+D جولوكوز أعطى اتنين الستة عشر كل واحد فيهم هيعطي
+
+387
+00:34:30,410 --> 00:34:34,950
+اتنين اتنين اتنين اتنين اتنين اتنين بستة عشر اتنين
+
+388
+00:34:34,950 --> 00:34:39,280
+و تلاتين هي الاتنين و التلاتين I زمرواضح؟ الان
+
+389
+00:34:39,280 --> 00:34:42,660
+هدولة اللي جدوا عندنا اجداد جايين من الجولوكوز و
+
+390
+00:34:42,660 --> 00:34:46,860
+جايين تحديدا من اي جولوكوز؟ من ال D جولوكوز لما
+
+391
+00:34:46,860 --> 00:34:50,280
+بدنا نميزهم عن بعض انتوا بتقدروا تميزهم تقولوا
+
+392
+00:34:50,280 --> 00:34:57,260
+واحد في ال OH لفوق واحد في ال OH لتحت الان بلغة
+
+393
+00:34:57,260 --> 00:35:01,880
+الكيميا بنقول اللي بيطلع بهذا الشكل و ال OH لفوق
+
+394
+00:35:01,880 --> 00:35:08,090
+بنسميه beta و بنحط الاسم القديممن وين هذا جاي؟ من
+
+395
+00:35:08,090 --> 00:35:12,070
+D جولوكوز، فصار ده Beta D جولوكوز، يعني ال Beta
+
+396
+00:35:12,070 --> 00:35:21,490
+اللي هي لفوق، اه، وإذا كانت لتحت؟ Alpha D جولوكوز،
+
+397
+00:35:21,490 --> 00:35:27,460
+واضح؟الان مرة تانية عشان تبعون ال biochemistry
+
+398
+00:35:27,460 --> 00:35:33,080
+اسهلوا على نفسهم هذه الحلقة السوداسية يمكن ان ترسم
+
+399
+00:35:33,080 --> 00:35:37,660
+بإيش بطرق كتير مختلفة يعني ممكن تخلوا ال oxygen
+
+400
+00:35:37,660 --> 00:35:42,380
+هان هان هان اعتادوا انهم يرسموها بهذا الشكل اللي
+
+401
+00:35:42,380 --> 00:35:47,920
+موجود أمامكم يعني بدكوا ترسموها حلقة سوداسية بهذا
+
+402
+00:35:47,920 --> 00:35:52,680
+الشكل وتجددوا انكوا تحطوا ال oxygen وين؟ع هذا
+
+403
+00:35:52,680 --> 00:35:58,660
+الموقع وبناء على ذلك واجتها بنقول ان الكاربون اللي
+
+404
+00:35:58,660 --> 00:36:03,320
+ماكنتش كايرال سنتر وصارت كايرال سنتر هي اي كاربون؟
+
+405
+00:36:03,320 --> 00:36:09,600
+هذه عشان الناس مايتخربطوش بطريقة الرسم ترسم الحلقة
+
+406
+00:36:09,600 --> 00:36:14,140
+السوداسية عادة في ال biochemistry بهذا الشكل ال
+
+407
+00:36:14,140 --> 00:36:19,640
+oxygen اللي سكرت هي هان هذه الكاربون اللي كانت
+
+408
+00:36:20,700 --> 00:36:28,460
+الديهايد ماكنتش كايرال سنتر صارت كايرال سنتر واضح؟
+
+409
+00:36:28,460 --> 00:36:33,560
+هيهانة قبل ما يسكركانت كايران ولا لأ؟ لأ كان
+
+410
+00:36:33,560 --> 00:36:37,960
+المركب .. كم كايرال سنتر فيه؟ كانوا أربعة و هذه
+
+411
+00:36:37,960 --> 00:36:41,940
+زادت .. هايهم الكايرال سنتر الأربعة و هذه زادت
+
+412
+00:36:41,940 --> 00:36:47,260
+صاروا كدهش؟ خمسة واضح؟ الآن هذه الكاربون اللي
+
+413
+00:36:47,260 --> 00:36:52,440
+ماكنتش كايرال سنتر كانت الديهايد و صارت كايرال
+
+414
+00:36:52,440 --> 00:36:57,560
+سنتر إلها اسم بنسميها Anomeric Carbon
+
+415
+00:36:59,780 --> 00:37:05,500
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+416
+00:37:05,500 --> 00:37:07,800
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+417
+00:37:07,800 --> 00:37:08,020
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+418
+00:37:08,020 --> 00:37:10,440
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+419
+00:37:10,440 --> 00:37:12,440
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+420
+00:37:12,440 --> 00:37:12,540
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+421
+00:37:12,540 --> 00:37:12,540
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+422
+00:37:12,540 --> 00:37:12,540
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+423
+00:37:12,540 --> 00:37:12,540
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+424
+00:37:12,540 --> 00:37:16,080
+انوميرك كاربونالكاربون اللي عملت الكايرال سنتر
+
+425
+00:37:16,080 --> 00:37:20,660
+الجديد كانوا أربعة صاروا إيش؟ خمسة، مين اللي عملت
+
+426
+00:37:20,660 --> 00:37:24,960
+الكايرال سنتر الجديد؟ هذه تبعت ال الديهايد بسميها
+
+427
+00:37:24,960 --> 00:37:30,100
+Anomeric Carbon، الآن إذا الكايرال سنتر هذا الجديد
+
+428
+00:37:30,730 --> 00:37:36,350
+أجت فيه مجموعة الـ OH لأعلى بقول هذا Beta Sugar
+
+429
+00:37:36,350 --> 00:37:41,070
+وإذا أجت لأسفل Alpha Alpha بيضلوا ماخد نفس الاسم
+
+430
+00:37:41,070 --> 00:37:45,630
+اللي هو الـ D والجولوكوز اللي هو يعبر عن كل
+
+431
+00:37:45,630 --> 00:37:52,230
+الترتيبات هذه واضح؟ الآن طالما كانوا 16 وكل واحد
+
+432
+00:37:52,230 --> 00:37:59,750
+بدأ أعمل منهAlpha و Beta قداش حيصيروا 32 طبعا
+
+433
+00:37:59,750 --> 00:38:04,570
+بتكونوا منتبهين أن الأسماء الأساسية في ال sugars
+
+434
+00:38:04,570 --> 00:38:11,990
+قداش تمانية واضحة الفكرة الأسماء الأساسية اللي هي
+
+435
+00:38:11,990 --> 00:38:16,330
+جولوكوز و جولاكتوز و ألوز و ما إلى ذلك كام اسم
+
+436
+00:38:16,330 --> 00:38:20,750
+تمان أسماء يعني خليني أوضحلكوا الصورة مرة أخيرة
+
+437
+00:38:24,310 --> 00:38:29,390
+تمان أسماء أساسية الان هدولة تمان أسماء أساسية كل
+
+438
+00:38:29,390 --> 00:38:35,690
+اسم فيه منه D و L و بعد هيك كل اسم بيصير ايش فيه
+
+439
+00:38:35,690 --> 00:38:44,130
+منه Alpha هذا بيكون Alpha D و Beta D و هذا بيصير
+
+440
+00:38:44,130 --> 00:38:51,510
+منه Alpha L و Beta L واضح؟ هي هذا كده صفة منه؟
+
+441
+00:38:51,510 --> 00:38:58,660
+أربعةيعني لو قولنا من الجولوكوز الجولوكوز
+
+442
+00:38:58,660 --> 00:39:02,800
+واحد منهم في Alpha D جولوكوز و Beta D جولوكوز
+
+443
+00:39:02,800 --> 00:39:09,440
+Alpha L جولوكوز و Beta L جولوكوز و من كل واحد
+
+444
+00:39:09,440 --> 00:39:14,200
+موجودة نفسها للتقسيمة طالما تمان أسماء أساسية في
+
+445
+00:39:14,200 --> 00:39:23,300
+أربعرموز صفر العدد لكل جداش 32 سكر في حالة ما كان
+
+446
+00:39:23,300 --> 00:39:30,020
+السكر إيه اشماله؟ Cyclic لكن لو كان acyclic بس
+
+447
+00:39:30,020 --> 00:39:34,620
+بنصفة ال 16 لأنه ماعملناش ال chiral center الخامس
+
+448
+00:39:34,620 --> 00:39:39,100
+اللي هو ماهيكون جولوكوز D و L جلاكتوز D و L مانوز
+
+449
+00:39:39,100 --> 00:39:47,570
+D و L و هكذا إذا كان acyclicالسكر السداسي بيكون
+
+450
+00:39:47,570 --> 00:39:53,750
+العدد الكلي 16 وإذا كان Cyclic بيكون العدد الكلي
+
+451
+00:39:53,750 --> 00:40:00,490
+32 الآن في ال A Cyclic تمان أسماء كل واحد بيقسم D
+
+452
+00:40:00,490 --> 00:40:08,530
+و L في ال Cyclic كل D و كل L بتقسم إلى ألفة و بيتا
+
+453
+00:40:08,530 --> 00:40:12,550
+الان
+
+454
+00:40:12,550 --> 00:40:18,700
+انتبهوا معيقلنا احنا انه لما يتكون هذا الدياستيريو
+
+455
+00:40:18,700 --> 00:40:23,460
+مارس بيكونوا ب equal ratios ولا unequal ratios؟
+
+456
+00:40:23,460 --> 00:40:30,200
+unequal ratios الان اللي طلع عندنا حقيقة ان ال
+
+457
+00:40:30,200 --> 00:40:37,520
+beta بيطلع بنسبة 64% و ال alpha من الجولوكوس بيطلع
+
+458
+00:40:37,520 --> 00:40:45,380
+بنسبة 36% واضح؟طبعا ال beta لحاله له زاوية دوران
+
+459
+00:40:45,380 --> 00:40:51,420
+plus 19 و ال alpha لحاله لو فصلوا له زاوية دوران
+
+460
+00:40:51,420 --> 00:40:59,120
+112 الان لو حطيت الخليط تبعهم بطلع زاوية بين
+
+461
+00:40:59,120 --> 00:41:02,700
+التنتين ماخدة نسبة بعين الاعتبار الخليط بطلع
+
+462
+00:41:02,700 --> 00:41:10,450
+زاويته حقيقة 52لاحظوا معي، الآن هذا كله اتزان، هذا
+
+463
+00:41:10,450 --> 00:41:15,750
+كله ايش؟ اتزان، بمعنى، لو أنا بدأت في هذا الـA
+
+464
+00:41:15,750 --> 00:41:21,390
+Cyclic و سبته في المحلول، بعد يوم، ايش هلاجيك؟ في
+
+465
+00:41:21,390 --> 00:41:27,090
+نسبة جليلة من الـCyclic ضايلة، سكر لهذا و لهذا، و
+
+466
+00:41:27,090 --> 00:41:34,670
+بنسبة 64% إلى 36%، و بخليط الزاوية تبعتهنتأكد منها
+
+467
+00:41:34,670 --> 00:41:47,210
+بالظبط قداش 52 52 اللي هو الاش ال mixture الخليط
+
+468
+00:41:47,210 --> 00:41:51,460
+اللي من هذا و من هذاالـ A Cyclic له زاوية تانية
+
+469
+00:41:51,460 --> 00:41:55,920
+مالنا و ماله بحكي عن الـ mixture اللي من هذا و من
+
+470
+00:41:55,920 --> 00:42:03,260
+هذا بيكون زاوية و قداش 52 طيب يا تورا لو حطينا الـ
+
+471
+00:42:03,260 --> 00:42:10,040
+A Cyclic هيسكر لإيش؟ لهدولة بنسبة 64 ل 36 طب لو
+
+472
+00:42:10,040 --> 00:42:16,880
+جيبنا هذا نقي و حطيناه لحاله و غيبنا عنه يوم إيش
+
+473
+00:42:16,880 --> 00:42:24,640
+بيعمل؟لا بيعمل اشي هذا في حالة اتزان مع الفاتح
+
+474
+00:42:24,640 --> 00:42:32,760
+الان نتيجة الاتزان بيفتح لما بيفتح بيسكر من اول و
+
+475
+00:42:32,760 --> 00:42:38,520
+جديد بالجهتين وبناء على ذلك لو اجينا حاطينا هذا
+
+476
+00:42:38,520 --> 00:42:43,480
+المسكر و سبناه يوم هو في اتزان مع الفاتح فتح سكر
+
+477
+00:42:43,480 --> 00:42:46,920
+اشمال يمين اشمال يمين بعد يوم بنلاقي ايش الناس
+
+478
+00:42:46,920 --> 00:42:53,530
+بصفيتوجود الاتنين ال alpha و ال beta بنفس النسبة
+
+479
+00:42:53,530 --> 00:43:01,190
+اللي هي ال 64 ل 36 طب لو جيبنا هذا المسكر و
+
+480
+00:43:01,190 --> 00:43:08,250
+دوّبناه في المحلول و سيبناه يوم يومين هذا هيفتح ل
+
+481
+00:43:08,250 --> 00:43:13,940
+ال a cyclic ال a cyclic هيسكر من أول و جديدشمال
+
+482
+00:43:13,940 --> 00:43:19,640
+ويمين شمال ويمين الى ان يصل الى الاتزان 64% الى 36
+
+483
+00:43:19,640 --> 00:43:25,120
+% فسواء بدأت بال A cyclic و سبته في المحلول او
+
+484
+00:43:25,120 --> 00:43:27,880
+بدأت بهذا و سبته في المحلول او بدأت بهذا و سبته في
+
+485
+00:43:27,880 --> 00:43:33,760
+المحلول اصل لنفس الخليط نفس النتيجة هذه العملية
+
+486
+00:43:33,760 --> 00:43:39,670
+الحقيقة بيسموها mutarotationلحظة الميوتا روتيشن هي
+
+487
+00:43:39,670 --> 00:43:44,070
+التغيير في الروتيشن الأبطالي بسبب تغيير الانو مارس
+
+488
+00:43:44,070 --> 00:43:53,290
+هدولة .. هدولة التنين الجداد بنسميهم احنا ايش؟ انو
+
+489
+00:43:53,290 --> 00:43:58,300
+مارساللي جايين من ال anomeric carbon اللي اختلفوا
+
+490
+00:43:58,300 --> 00:44:03,420
+في one chiral center واضح؟ يعني ال anomer beta
+
+491
+00:44:03,420 --> 00:44:07,860
+بيصير ال anomer alpha و ال anomer alpha بيصير ال
+
+492
+00:44:07,860 --> 00:44:12,560
+anomer beta لو حطيت ال alpha بصف على اتزان من
+
+493
+00:44:12,560 --> 00:44:17,120
+alpha و betaو لو حطيت ال beta بصف على اتزان من
+
+494
+00:44:17,120 --> 00:44:21,080
+alpha و beta و بنفس النسبة هذه العملية اللي احنا
+
+495
+00:44:21,080 --> 00:44:24,420
+بنسميها ايش ال mutation rotation لما احط ال alpha
+
+496
+00:44:24,420 --> 00:44:27,300
+و اكون جسد في ال polarimeter راح لاحظ ان الزاوية
+
+497
+00:44:27,300 --> 00:44:32,680
+في أولها 146 بعد شوية بتجل بتجل بتجل اخر مابتصف
+
+498
+00:44:32,680 --> 00:44:40,550
+يداش 52 لو حطيت ال betaالزاوية 19 بضلني اديس معي
+
+499
+00:44:40,550 --> 00:44:46,990
+الزمن بتضل ازيد ازيد ازيد اخر ما بتصفح 52 هذا
+
+500
+00:44:46,990 --> 00:44:52,390
+التغير في ال rotation إلى أن يصل 52 يعني إذا بدأت
+
+501
+00:44:52,390 --> 00:44:57,960
+من هنا ستصل ل 52 وإذا بدأت من هنا ستصل ل 52هذا ايش
+
+502
+00:44:57,960 --> 00:45:03,260
+بنسميه احنا ميوتا روتيشن اللي هو نشوف ايش تعريفه
+
+503
+00:45:03,260 --> 00:45:06,920
+is the change in optical rotation التغيير في ال
+
+504
+00:45:06,920 --> 00:45:09,780
+optical rotation due to inter conversion of
+
+505
+00:45:09,780 --> 00:45:13,360
+animals ان ال alpha بتصير a cyclic و بترجع تصير
+
+506
+00:45:13,360 --> 00:45:17,540
+alpha و beta in solution it is explained by the
+
+507
+00:45:17,540 --> 00:45:22,980
+equilibriumبالفسيرة بإيش أنه في اتزان أنه ال beta
+
+508
+00:45:22,980 --> 00:45:26,080
+بيفتح و بسكر alpha و beta ال alpha بيفتح و بسكر
+
+509
+00:45:26,080 --> 00:45:31,560
+alpha و beta و بنفس إيش الإتزان طبعا بإمكانهم
+
+510
+00:45:31,560 --> 00:45:34,680
+يعملوا حسابات احنا مش موضوعنا الحسابات احنا
+
+511
+00:45:34,680 --> 00:45:38,840
+موضوعنا ببساطة الآن أنه في عندنا سواء بدأت ب alpha
+
+512
+00:45:38,840 --> 00:45:44,980
+أو beta بالمحلول هاصل إلى إيش إلى الاتزان هذا
+
+513
+00:45:44,980 --> 00:45:53,110
+الاتزان 64%Beta و 36% Alpha ايش معناه؟ معناه ان ال
+
+514
+00:45:53,110 --> 00:45:57,810
+.. which is more stable ال Beta ولا ال Alpha؟ ال
+
+515
+00:45:57,810 --> 00:46:03,190
+Beta طبعا هم بيفسروا على انه لو رسمنا السكر على
+
+516
+00:46:03,190 --> 00:46:08,310
+شكل الكرسي مش السكر Cyclohexane في النهاية بتكون
+
+517
+00:46:08,310 --> 00:46:14,250
+ال OH في ال Beta equatorial يعني غير مزدحمة واضح؟
+
+518
+00:46:14,250 --> 00:46:18,690
+هذه ال OH لا تعاني ازدحام، لاحظوا هذه ال OHnot
+
+519
+00:46:18,690 --> 00:46:24,830
+crowded غير مزحمة الان هذه ال اواتش اللي طلع عليها
+
+520
+00:46:24,830 --> 00:46:33,450
+crowded مزحمة عشان هيك هو بفضل يكون في ال beta ولا
+
+521
+00:46:33,450 --> 00:46:39,170
+في ال alpha بالنسبة أعلى في ال beta بهيك بننهي
+
+522
+00:46:39,170 --> 00:46:43,430
+اليوم هذا الجزء و المرة اللي جاي ان شاء الله
+
+523
+00:46:43,430 --> 00:46:44,510
+بنستكمل
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..cfaf23c719b611051940c75a6cbe464b8e9a88d8
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4865, "start": 20.69, "end": 48.65, "text": "بسم الله الرحمن الرحيم في موضوع ال stereochemistry ربما المرة الماضية نوّهنا من خلال أنفلة تطبيقية من خلال أهمية فهم ال stereo isomers في الحياة العملية أن هذا موضوع مهم ولذلك شوية بنظل نتوسع فيه بعد ما أخدنا المركبات اللي فيها one chiral center قولنا ال one chiral center بيعتق فقط", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 8978, 3714, 2407, 11242, 45367, 2423, 29029, 48353, 12602, 3555, 15042, 9673, 25720, 9673, 46958, 10632, 8717, 2407, 11703, 3224, 8315, 9154, 16490, 1211, 6027, 14739, 5172, 37977, 6055, 9566, 21292, 4587, 10632, 9154, 16490, 1211, 6027, 5551, 16095, 10632, 6156, 16095, 2423, 29029, 307, 298, 433, 8978, 21542, 25528, 3660, 18863, 42213, 10632, 14739, 23758, 3714, 2407, 11242, 45367, 3714, 16095, 35525, 8848, 23275, 13412, 2407, 10632, 44945, 19913, 1211, 8717, 2655, 41779, 3615, 8978, 3224, 39182, 19446, 5551, 9778, 3215, 8315, 9673, 31747, 3555, 9307, 13672, 1829, 8978, 11296, 472, 23782, 304, 3056, 12174, 12610, 8315, 2423, 472, 23782, 304, 3056, 4724, 1829, 34268, 4587, 6156, 47432], "avg_logprob": -0.1389180664755717, "compression_ratio": 1.824, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 20.69, "end": 20.99, "word": "بسم", "probability": 0.90869140625}, {"start": 20.99, "end": 21.17, "word": " الله", "probability": 0.96826171875}, {"start": 21.17, "end": 21.49, "word": " الرحمن", "probability": 0.9777018229166666}, {"start": 21.49, "end": 21.91, "word": " الرحيم", "probability": 0.990234375}, {"start": 21.91, "end": 23.05, "word": " في", "probability": 0.59619140625}, {"start": 23.05, "end": 23.63, "word": " موضوع", "probability": 0.9794921875}, {"start": 23.63, "end": 23.75, "word": " ال", "probability": 0.96337890625}, {"start": 23.75, "end": 24.75, "word": " stereochemistry", "probability": 0.4232177734375}, {"start": 24.75, "end": 25.51, "word": " ربما", "probability": 0.9796549479166666}, {"start": 25.51, "end": 25.87, "word": " المرة", "probability": 0.97216796875}, {"start": 25.87, "end": 26.55, "word": " الماضية", "probability": 0.9915364583333334}, {"start": 26.55, "end": 27.79, "word": " نوّهنا", "probability": 0.839453125}, {"start": 27.79, "end": 27.95, "word": " من", "probability": 0.99462890625}, {"start": 27.95, "end": 28.31, "word": " خلال", "probability": 0.9913736979166666}, {"start": 28.31, "end": 28.75, "word": " أنفلة", "probability": 0.8592122395833334}, {"start": 28.75, "end": 29.55, "word": " تطبيقية", "probability": 0.9244140625}, {"start": 29.55, "end": 29.73, "word": " من", "probability": 0.9521484375}, {"start": 29.73, "end": 31.11, "word": " خلال", "probability": 0.9733072916666666}, {"start": 31.11, "end": 33.25, "word": " أهمية", "probability": 0.9567057291666666}, {"start": 33.25, "end": 33.83, "word": " فهم", "probability": 0.990478515625}, {"start": 33.83, "end": 33.99, "word": " ال", "probability": 0.93017578125}, {"start": 33.99, "end": 34.39, "word": " stereo", "probability": 0.78857421875}, {"start": 34.39, "end": 35.17, "word": " isomers", "probability": 0.9021809895833334}, {"start": 35.17, "end": 35.37, "word": " في", "probability": 0.90185546875}, {"start": 35.37, "end": 36.13, "word": " الحياة", "probability": 0.9921875}, {"start": 36.13, "end": 36.97, "word": " العملية", "probability": 0.9724934895833334}, {"start": 36.97, "end": 38.69, "word": " أن", "probability": 0.4140625}, {"start": 38.69, "end": 38.89, "word": " هذا", "probability": 0.56982421875}, {"start": 38.89, "end": 39.33, "word": " موضوع", "probability": 0.994384765625}, {"start": 39.33, "end": 39.67, "word": " مهم", "probability": 0.992431640625}, {"start": 39.67, "end": 40.39, "word": " ولذلك", "probability": 0.8173828125}, {"start": 40.39, "end": 40.87, "word": " شوية", "probability": 0.84375}, {"start": 40.87, "end": 41.23, "word": " بنظل", "probability": 0.7728678385416666}, {"start": 41.23, "end": 41.81, "word": " نتوسع", "probability": 0.988525390625}, {"start": 41.81, "end": 42.29, "word": " فيه", "probability": 0.980712890625}, {"start": 42.29, "end": 42.81, "word": " بعد", "probability": 0.9365234375}, {"start": 42.81, "end": 42.99, "word": " ما", "probability": 0.904296875}, {"start": 42.99, "end": 43.35, "word": " أخدنا", "probability": 0.94384765625}, {"start": 43.35, "end": 44.33, "word": " المركبات", "probability": 0.8023681640625}, {"start": 44.33, "end": 44.63, "word": " اللي", "probability": 0.842529296875}, {"start": 44.63, "end": 44.91, "word": " فيها", "probability": 0.940185546875}, {"start": 44.91, "end": 45.13, "word": " one", "probability": 0.76904296875}, {"start": 45.13, "end": 45.73, "word": " chiral", "probability": 0.76171875}, {"start": 45.73, "end": 46.29, "word": " center", "probability": 0.8515625}, {"start": 46.29, "end": 46.83, "word": " قولنا", "probability": 0.6873372395833334}, {"start": 46.83, "end": 46.95, "word": " ال", "probability": 0.80224609375}, {"start": 46.95, "end": 47.09, "word": " one", "probability": 0.91552734375}, {"start": 47.09, "end": 47.49, "word": " chiral", "probability": 0.978515625}, {"start": 47.49, "end": 47.83, "word": " center", "probability": 0.931640625}, {"start": 47.83, "end": 48.27, "word": " بيعتق", "probability": 0.70770263671875}, {"start": 48.27, "end": 48.65, "word": " فقط", "probability": 0.931640625}], "temperature": 1.0}, {"id": 2, "seek": 7681, "start": 49.51, "end": 76.81, "text": "two isomers بعد ذلك إذا زاد العدد بيبدأوا يزيدوا ال isomers طبعا بيحكم الأمر المعادلة two to the n لكن ال two to the n هذا أقصى عدد ممكن من ال isomers في كل الأحوال ممكن يكون العدد أقل من هيك وقلنا هنعطي مثال على العدد الأقصى ومثال على وانتش العدد بيصير أقل في حالة ما عندنا two chiral centers", "tokens": [20534, 307, 298, 433, 39182, 29910, 23275, 11933, 15730, 30767, 18513, 18863, 3215, 3215, 4724, 1829, 44510, 10721, 14407, 7251, 11622, 25708, 14407, 2423, 307, 298, 433, 23032, 3555, 3615, 995, 4724, 1829, 5016, 24793, 16247, 29973, 9673, 3615, 18513, 37977, 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واحدة", "probability": 0.9923502604166666}, {"start": 352.62, "end": 352.86, "word": " منهم", "probability": 0.990478515625}, {"start": 352.86, "end": 353.7, "word": " اختلت", "probability": 0.9605712890625}], "temperature": 1.0}, {"id": 15, "seek": 37734, "start": 354.22, "end": 377.34, "text": "ببطلوا in anchormers على طول ببطلوا صورة بعض في المرآة إذا بطلوا صورة بعض في المرآة، شو بدوا يصيروا؟ ديستيريومارز، تنسوش إن احنا عرفنا الديستيريومارز، they are non-mirror image in anchormers ولذلك لو أنا سألت العلاقة بين هدول، خلّينا نوضحها باسم RS عكس بعض", "tokens": [3555, 3555, 9566, 1211, 14407, 294, 12723, 687, 433, 15844, 23032, 12610, 4724, 3555, 9566, 1211, 14407, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 148, 95, 3660, 11933, 15730, 4724, 9566, 1211, 14407, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 148, 95, 3660, 12399, 13412, 2407, 47525, 14407, 7251, 9381, 13546, 14407, 22807, 11778, 1829, 14851, 13546, 1829, 20498, 9640, 11622, 12399, 6055, 1863, 3794, 2407, 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0.94833984375}, {"start": 356.98, "end": 357.32, "word": " صورة", "probability": 0.9915364583333334}, {"start": 357.32, "end": 357.64, "word": " بعض", "probability": 0.97705078125}, {"start": 357.64, "end": 357.8, "word": " في", "probability": 0.8642578125}, {"start": 357.8, "end": 358.32, "word": " المرآة", "probability": 0.797119140625}, {"start": 358.32, "end": 358.74, "word": " إذا", "probability": 0.75537109375}, {"start": 358.74, "end": 359.18, "word": " بطلوا", "probability": 0.9713134765625}, {"start": 359.18, "end": 359.52, "word": " صورة", "probability": 0.9869791666666666}, {"start": 359.52, "end": 359.84, "word": " بعض", "probability": 0.940185546875}, {"start": 359.84, "end": 360.02, "word": " في", "probability": 0.96923828125}, {"start": 360.02, "end": 360.7, "word": " المرآة،", "probability": 0.8747965494791666}, {"start": 360.7, "end": 360.82, "word": " شو", "probability": 0.6453857421875}, {"start": 360.82, "end": 360.98, "word": " بدوا", "probability": 0.427001953125}, {"start": 360.98, "end": 362.46, "word": " يصيروا؟", "probability": 0.90751953125}, {"start": 362.46, "end": 364.04, "word": " ديستيريومارز،", "probability": 0.5852322048611112}, {"start": 364.04, "end": 364.58, "word": " تنسوش", "probability": 0.88369140625}, {"start": 364.58, "end": 364.7, "word": " إن", "probability": 0.52587890625}, {"start": 364.7, "end": 364.88, "word": " احنا", "probability": 0.7618001302083334}, {"start": 364.88, "end": 365.36, "word": " عرفنا", "probability": 0.9005533854166666}, {"start": 365.36, "end": 366.96, "word": " الديستيريومارز،", "probability": 0.8489040798611112}, {"start": 366.96, "end": 367.12, "word": " they", "probability": 0.71923828125}, {"start": 367.12, "end": 367.64, "word": " are", "probability": 0.9541015625}, {"start": 367.64, "end": 368.26, "word": " non", "probability": 0.84765625}, {"start": 368.26, "end": 368.74, "word": "-mirror", "probability": 0.76953125}, {"start": 368.74, "end": 369.34, "word": " image", "probability": 0.896484375}, {"start": 369.34, "end": 369.72, "word": " in", "probability": 0.62744140625}, {"start": 369.72, "end": 370.34, "word": " anchormers", "probability": 0.7932942708333334}, {"start": 370.34, "end": 371.1, "word": " ولذلك", "probability": 0.8277994791666666}, {"start": 371.1, "end": 371.26, "word": " لو", "probability": 0.6962890625}, {"start": 371.26, "end": 371.48, "word": " أنا", "probability": 0.892578125}, {"start": 371.48, "end": 371.86, "word": " سألت", "probability": 0.9697265625}, {"start": 371.86, "end": 372.34, "word": " العلاقة", "probability": 0.9837239583333334}, {"start": 372.34, "end": 372.58, "word": " بين", "probability": 0.98583984375}, {"start": 372.58, "end": 373.74, "word": " هدول،", "probability": 0.887939453125}, {"start": 373.74, "end": 374.06, "word": " خلّينا", "probability": 0.781640625}, {"start": 374.06, "end": 374.64, "word": " نوضحها", "probability": 0.9439453125}, {"start": 374.64, "end": 375.06, "word": " باسم", "probability": 0.9793294270833334}, {"start": 375.06, "end": 375.98, "word": " RS", "probability": 0.2724609375}, {"start": 375.98, "end": 376.92, "word": " عكس", "probability": 0.8719075520833334}, {"start": 376.92, "end": 377.34, "word": " بعض", "probability": 0.9853515625}], "temperature": 1.0}, {"id": 16, "seek": 40654, "start": 378.98, "end": 406.54, "text": "عكس بعض اذا they are enansimals واضح؟ الان لو سئلت هدول الاتنين RS SR عكس طلع عليهم R اقبلها S S اقبلها R عكس بعض they are enansimals الان لو اجيت اخدت مثلا المركب واحد مع تلاتة اتطلعوا R وR", "tokens": [3615, 4117, 3794, 45030, 11242, 1975, 15730, 436, 366, 465, 599, 332, 1124, 4032, 46958, 5016, 22807, 2423, 7649, 45164, 8608, 19986, 1211, 2655, 8032, 3215, 12610, 2423, 9307, 1863, 9957, 25855, 20840, 6225, 4117, 3794, 23032, 1211, 3615, 25894, 16095, 497, 1975, 4587, 36150, 11296, 318, 318, 1975, 4587, 36150, 11296, 497, 6225, 4117, 3794, 45030, 11242, 436, 366, 465, 599, 332, 1124, 2423, 7649, 45164, 1975, 7435, 36081, 1975, 9778, 3215, 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384.28, "word": " سئلت", "probability": 0.8985595703125}, {"start": 384.28, "end": 384.58, "word": " هدول", "probability": 0.7711588541666666}, {"start": 384.58, "end": 385.12, "word": " الاتنين", "probability": 0.74298095703125}, {"start": 385.12, "end": 386.08, "word": " RS", "probability": 0.296875}, {"start": 386.08, "end": 388.12, "word": " SR", "probability": 0.86328125}, {"start": 388.12, "end": 389.54, "word": " عكس", "probability": 0.9466145833333334}, {"start": 389.54, "end": 390.02, "word": " طلع", "probability": 0.765380859375}, {"start": 390.02, "end": 390.54, "word": " عليهم", "probability": 0.99072265625}, {"start": 390.54, "end": 391.34, "word": " R", "probability": 0.736328125}, {"start": 391.34, "end": 391.88, "word": " اقبلها", "probability": 0.6820068359375}, {"start": 391.88, "end": 392.28, "word": " S", "probability": 0.98046875}, {"start": 392.28, "end": 392.66, "word": " S", "probability": 0.576171875}, {"start": 392.66, "end": 393.14, "word": " اقبلها", "probability": 0.96923828125}, {"start": 393.14, "end": 393.56, "word": " R", "probability": 0.98046875}, {"start": 393.56, "end": 394.48, "word": " عكس", "probability": 0.9913736979166666}, {"start": 394.48, "end": 394.74, "word": " بعض", "probability": 0.98583984375}, {"start": 394.74, "end": 394.94, "word": " they", "probability": 0.78857421875}, {"start": 394.94, "end": 395.5, "word": " are", "probability": 0.9638671875}, {"start": 395.5, "end": 396.86, "word": " enansimals", "probability": 0.91357421875}, {"start": 396.86, "end": 397.62, "word": " الان", "probability": 0.9267578125}, {"start": 397.62, "end": 397.96, "word": " لو", "probability": 0.935546875}, {"start": 397.96, "end": 398.36, "word": " اجيت", "probability": 0.6595052083333334}, {"start": 398.36, "end": 398.84, "word": " اخدت", "probability": 0.89013671875}, {"start": 398.84, "end": 399.32, "word": " مثلا", "probability": 0.846923828125}, {"start": 399.32, "end": 400.66, "word": " المركب", "probability": 0.9423828125}, {"start": 400.66, "end": 402.28, "word": " واحد", "probability": 0.96044921875}, {"start": 402.28, "end": 402.58, "word": " مع", "probability": 0.990234375}, {"start": 402.58, "end": 403.28, "word": " تلاتة", "probability": 0.9150390625}, {"start": 403.28, "end": 405.28, "word": " اتطلعوا", "probability": 0.8806966145833334}, {"start": 405.28, "end": 405.9, "word": " R", "probability": 0.8505859375}, {"start": 405.9, "end": 406.54, "word": " وR", "probability": 0.764404296875}], "temperature": 1.0}, {"id": 17, "seek": 43144, "start": 407.58, "end": 431.44, "text": "هدولا متل بعض و are و us عكس بعض هل هدولا عكس بعض بالكامل؟ لأ هدولا متل بعض بالكامل؟ لأ مالو كانوا عكس بعض بالكامل يعني كل نقطة عكس التانية they are enantiomers الان لو كل نقطة زي التانية they are the same compound", "tokens": [3224, 3215, 12610, 995, 44650, 1211, 45030, 11242, 4032, 366, 4032, 505, 6225, 4117, 3794, 45030, 11242, 8032, 1211, 8032, 3215, 12610, 995, 6225, 4117, 3794, 45030, 11242, 20666, 4117, 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"probability": 0.9248046875}, {"start": 411.06, "end": 411.46, "word": " us", "probability": 0.85302734375}, {"start": 411.46, "end": 413.32, "word": " عكس", "probability": 0.95947265625}, {"start": 413.32, "end": 413.74, "word": " بعض", "probability": 0.99560546875}, {"start": 413.74, "end": 414.58, "word": " هل", "probability": 0.828369140625}, {"start": 414.58, "end": 415.0, "word": " هدولا", "probability": 0.9814453125}, {"start": 415.0, "end": 415.3, "word": " عكس", "probability": 0.9951171875}, {"start": 415.3, "end": 415.6, "word": " بعض", "probability": 0.99169921875}, {"start": 415.6, "end": 416.48, "word": " بالكامل؟", "probability": 0.89716796875}, {"start": 416.48, "end": 416.86, "word": " لأ", "probability": 0.6658935546875}, {"start": 416.86, "end": 417.76, "word": " هدولا", "probability": 0.85791015625}, {"start": 417.76, "end": 418.14, "word": " متل", "probability": 0.969970703125}, {"start": 418.14, "end": 418.46, "word": " بعض", "probability": 0.989013671875}, {"start": 418.46, "end": 419.34, "word": " بالكامل؟", "probability": 0.9755859375}, {"start": 419.34, "end": 419.88, "word": " لأ", "probability": 0.93994140625}, {"start": 419.88, "end": 420.36, "word": " مالو", "probability": 0.4036458333333333}, {"start": 420.36, "end": 420.66, "word": " كانوا", "probability": 0.906005859375}, {"start": 420.66, "end": 420.98, "word": " عكس", "probability": 0.9943033854166666}, {"start": 420.98, "end": 421.5, "word": " بعض", "probability": 0.990478515625}, {"start": 421.5, "end": 422.22, "word": " بالكامل", "probability": 0.9886474609375}, {"start": 422.22, "end": 422.46, "word": " يعني", "probability": 0.892822265625}, {"start": 422.46, "end": 422.84, "word": " كل", "probability": 0.94677734375}, {"start": 422.84, "end": 423.22, "word": " نقطة", "probability": 0.9742838541666666}, {"start": 423.22, "end": 423.54, "word": " عكس", "probability": 0.9959309895833334}, {"start": 423.54, "end": 423.96, "word": " التانية", "probability": 0.9654947916666666}, {"start": 423.96, "end": 424.14, "word": " they", "probability": 0.7763671875}, {"start": 424.14, "end": 424.56, "word": " are", "probability": 0.953125}, {"start": 424.56, "end": 426.02, "word": " enantiomers", "probability": 0.8148193359375}, {"start": 426.02, "end": 426.54, "word": " الان", "probability": 0.6298828125}, {"start": 426.54, "end": 426.88, "word": " لو", "probability": 0.9326171875}, {"start": 426.88, "end": 427.24, "word": " كل", "probability": 0.98388671875}, {"start": 427.24, "end": 427.68, "word": " نقطة", "probability": 0.98828125}, {"start": 427.68, "end": 427.96, "word": " زي", "probability": 0.94482421875}, {"start": 427.96, "end": 428.66, "word": " التانية", "probability": 0.98828125}, {"start": 428.66, "end": 429.72, "word": " they", "probability": 0.9404296875}, {"start": 429.72, "end": 430.0, "word": " are", "probability": 0.9638671875}, {"start": 430.0, "end": 430.2, "word": " the", "probability": 0.93798828125}, {"start": 430.2, "end": 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لأ", "probability": 0.857421875}, {"start": 503.67, "end": 504.09, "word": " نفس", "probability": 0.96044921875}, {"start": 504.09, "end": 504.79, "word": " المركب", "probability": 0.8688151041666666}, {"start": 504.79, "end": 505.49, "word": " لأ", "probability": 0.977294921875}, {"start": 505.49, "end": 505.77, "word": " ر", "probability": 0.224609375}, {"start": 505.77, "end": 505.97, "word": " ده", "probability": 0.906982421875}, {"start": 505.97, "end": 506.47, "word": " يستيريو", "probability": 0.9775390625}, {"start": 506.47, "end": 506.75, "word": " مارس", "probability": 0.9861653645833334}, {"start": 506.75, "end": 507.55, "word": " اذا", "probability": 0.876220703125}, {"start": 507.55, "end": 507.99, "word": " واحد", "probability": 0.97998046875}, {"start": 507.99, "end": 508.13, "word": " و", "probability": 0.97705078125}, {"start": 508.13, "end": 508.53, "word": " تلاتة", "probability": 0.9639892578125}, {"start": 508.53, "end": 508.67, "word": " ده", "probability": 0.780029296875}, {"start": 508.67, "end": 509.11, "word": " يستيريو", "probability": 0.985546875}, {"start": 509.11, "end": 509.33, "word": " مارس", "probability": 0.9754231770833334}, {"start": 509.33, "end": 509.77, "word": " لو", "probability": 0.97265625}, {"start": 509.77, "end": 510.53, "word": " طبقته", "probability": 0.9564208984375}, {"start": 510.53, "end": 511.03, "word": " مرة", "probability": 0.73828125}, {"start": 511.03, "end": 511.33, "word": " تانية", "probability": 0.9462890625}, {"start": 511.33, "end": 511.53, "word": " على", "probability": 0.83837890625}, {"start": 511.53, "end": 511.87, "word": " واحد", "probability": 0.97607421875}, {"start": 511.87, "end": 511.97, "word": " و", "probability": 0.9775390625}, {"start": 511.97, "end": 512.43, "word": " أربعة", "probability": 0.7687174479166666}, {"start": 512.43, "end": 512.85, "word": " مثلا", "probability": 0.9599609375}, {"start": 512.85, "end": 513.01, "word": " ما", "probability": 0.68701171875}, {"start": 513.01, "end": 513.51, "word": " العلاقة", "probability": 0.9117838541666666}, {"start": 513.51, "end": 514.07, "word": " بينهم", "probability": 0.98779296875}, {"start": 514.07, "end": 515.07, "word": " R", "probability": 0.370849609375}], "temperature": 1.0}, {"id": 21, "seek": 53484, "start": 515.82, "end": 534.84, "text": "و S عكس بعض، هم لاحظين؟ R و R نفس بعض، they are diastereomers لو إجينا اتطلعنا على اتنين و تلاتة، لاحظوا؟ S و R", "tokens": [2407, 318, 6225, 4117, 3794, 45030, 11242, 12399, 8032, 2304, 20193, 5016, 19913, 9957, 22807, 497, 4032, 497, 8717, 36178, 45030, 11242, 12399, 436, 366, 1026, 525, 323, 298, 433, 45164, 11933, 7435, 1829, 8315, 1975, 2655, 9566, 1211, 3615, 8315, 15844, 1975, 2655, 1863, 9957, 4032, 6055, 1211, 9307, 3660, 12399, 20193, 5016, 19913, 14407, 22807, 318, 4032, 497], "avg_logprob": -0.3017418013244379, "compression_ratio": 1.2814814814814814, "no_speech_prob": 0.0, "words": [{"start": 515.82, "end": 516.1, "word": "و", "probability": 0.6845703125}, {"start": 516.1, "end": 516.54, "word": " S", "probability": 0.67431640625}, {"start": 516.54, "end": 518.38, "word": " عكس", "probability": 0.7684733072916666}, {"start": 518.38, "end": 519.62, "word": " بعض،", "probability": 0.690185546875}, {"start": 519.62, "end": 519.7, "word": " هم", "probability": 0.5926513671875}, {"start": 519.7, "end": 521.28, "word": " لاحظين؟", "probability": 0.9119140625}, {"start": 521.28, "end": 521.66, "word": " R", "probability": 0.76904296875}, {"start": 521.66, "end": 521.84, "word": " و", "probability": 0.9599609375}, {"start": 521.84, "end": 522.26, "word": " R", "probability": 0.77294921875}, {"start": 522.26, "end": 523.66, "word": " نفس", "probability": 0.97265625}, {"start": 523.66, "end": 524.18, "word": " بعض،", "probability": 0.8121744791666666}, {"start": 524.18, "end": 524.58, "word": " they", "probability": 0.646484375}, {"start": 524.58, "end": 525.4, "word": " are", "probability": 0.81396484375}, {"start": 525.4, "end": 526.4, "word": " diastereomers", "probability": 0.667724609375}, {"start": 526.4, "end": 527.54, "word": " لو", "probability": 0.830078125}, {"start": 527.54, "end": 527.9, "word": " إجينا", "probability": 0.73651123046875}, {"start": 527.9, "end": 528.42, "word": " اتطلعنا", "probability": 0.7859700520833334}, {"start": 528.42, "end": 528.62, "word": " على", "probability": 0.904296875}, {"start": 528.62, "end": 529.02, "word": " اتنين", "probability": 0.82177734375}, {"start": 529.02, "end": 529.14, "word": " و", "probability": 0.70263671875}, {"start": 529.14, "end": 532.72, "word": " تلاتة،", "probability": 0.9220703125}, {"start": 532.72, "end": 533.28, "word": " لاحظوا؟", "probability": 0.781298828125}, {"start": 533.28, "end": 533.86, "word": " S", "probability": 0.94287109375}, {"start": 533.86, "end": 534.5, "word": " و", "probability": 0.982421875}, {"start": 534.5, "end": 534.84, "word": " R", "probability": 0.74072265625}], "temperature": 1.0}, {"id": 22, "seek": 55037, "start": 535.85, "end": 550.37, "text": "عكس بعض السؤاس زي بعض كذلك الحال لو اتطلعت اتنين اربع السؤاس نفس الاشي السؤاد عكس بعض they are diastereomers واضح؟", "tokens": [3615, 4117, 3794, 45030, 11242, 21136, 33604, 32277, 30767, 1829, 45030, 11242, 9122, 8848, 23275, 21542, 6027, 45164, 1975, 2655, 9566, 1211, 34268, 1975, 2655, 1863, 9957, 1975, 25513, 3615, 21136, 33604, 32277, 8717, 36178, 2423, 33599, 1829, 21136, 33604, 18513, 6225, 4117, 3794, 45030, 11242, 436, 366, 1026, 525, 323, 298, 433, 4032, 46958, 5016, 22807], "avg_logprob": -0.25969828100040043, "compression_ratio": 1.4573643410852712, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 535.85, "end": 536.35, "word": "عكس", "probability": 0.9309895833333334}, {"start": 536.35, "end": 536.83, "word": " بعض", "probability": 0.995361328125}, {"start": 536.83, "end": 537.89, "word": " السؤاس", "probability": 0.5608317057291666}, {"start": 537.89, "end": 538.95, "word": " زي", "probability": 0.81005859375}, {"start": 538.95, "end": 539.29, "word": " بعض", "probability": 0.990478515625}, {"start": 539.29, "end": 541.59, "word": " كذلك", "probability": 0.6482950846354166}, {"start": 541.59, "end": 541.91, "word": " الحال", "probability": 0.7255859375}, {"start": 541.91, "end": 542.01, "word": " لو", "probability": 0.5458984375}, {"start": 542.01, "end": 542.37, "word": " اتطلعت", "probability": 0.788671875}, {"start": 542.37, "end": 542.75, "word": " اتنين", "probability": 0.9383544921875}, {"start": 542.75, "end": 543.11, "word": " اربع", "probability": 0.7721354166666666}, {"start": 543.11, "end": 543.87, "word": " السؤاس", "probability": 0.9093424479166666}, {"start": 543.87, "end": 544.77, "word": " نفس", "probability": 0.97412109375}, {"start": 544.77, "end": 545.35, "word": " الاشي", "probability": 0.8369140625}, {"start": 545.35, "end": 546.47, "word": " السؤاد", "probability": 0.8349609375}, {"start": 546.47, "end": 547.55, "word": " عكس", "probability": 0.9949544270833334}, {"start": 547.55, "end": 548.07, "word": " بعض", "probability": 0.99560546875}, {"start": 548.07, "end": 548.29, "word": " they", "probability": 0.5634765625}, {"start": 548.29, "end": 548.51, "word": " are", "probability": 0.9404296875}, {"start": 548.51, "end": 549.59, "word": " diastereomers", "probability": 0.77197265625}, {"start": 549.59, "end": 550.37, "word": " واضح؟", "probability": 0.77655029296875}], "temperature": 1.0}, {"id": 23, "seek": 56721, "start": 551.05, "end": 567.21, "text": "صار عندى نوع تانى من الدياستيريو مارز جاي من وين جاي من المركبات فيها chiral centers يعني احنا اول ما أخدنا تعريف الدياستيريو مارز قولنا كل شيء مش صورة بعض في المرقاة they are diastereomars", "tokens": [9381, 9640, 43242, 7578, 8717, 45367, 6055, 7649, 7578, 9154, 2423, 16254, 995, 14851, 13546, 1829, 2407, 3714, 9640, 11622, 10874, 47302, 9154, 4032, 9957, 10874, 47302, 9154, 9673, 31747, 3555, 9307, 8978, 11296, 23782, 304, 10898, 37495, 22653, 1975, 5016, 8315, 1975, 12610, 19446, 5551, 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"probability": 0.875244140625}, {"start": 555.23, "end": 555.41, "word": " من", "probability": 0.9619140625}, {"start": 555.41, "end": 555.79, "word": " وين", "probability": 0.809814453125}, {"start": 555.79, "end": 556.59, "word": " جاي", "probability": 0.6123046875}, {"start": 556.59, "end": 556.71, "word": " من", "probability": 0.9892578125}, {"start": 556.71, "end": 557.31, "word": " المركبات", "probability": 0.8690185546875}, {"start": 557.31, "end": 557.59, "word": " فيها", "probability": 0.8056640625}, {"start": 557.59, "end": 558.03, "word": " chiral", "probability": 0.848876953125}, {"start": 558.03, "end": 558.55, "word": " centers", "probability": 0.93017578125}, {"start": 558.55, "end": 558.87, "word": " يعني", "probability": 0.69921875}, {"start": 558.87, "end": 559.11, "word": " احنا", "probability": 0.9529622395833334}, {"start": 559.11, "end": 559.41, "word": " اول", "probability": 0.93212890625}, {"start": 559.41, "end": 559.53, "word": " ما", "probability": 0.91845703125}, {"start": 559.53, "end": 560.11, "word": " أخدنا", "probability": 0.87451171875}, {"start": 560.11, "end": 560.91, "word": " تعريف", "probability": 0.99072265625}, {"start": 560.91, "end": 561.77, "word": " الدياستيريو", "probability": 0.9767020089285714}, {"start": 561.77, "end": 562.03, "word": " مارز", "probability": 0.9715169270833334}, {"start": 562.03, "end": 562.61, "word": " قولنا", "probability": 0.8107096354166666}, {"start": 562.61, "end": 562.93, "word": " كل", "probability": 0.93359375}, {"start": 562.93, "end": 564.03, "word": " شيء", "probability": 0.760009765625}, {"start": 564.03, "end": 564.31, "word": " مش", "probability": 0.9873046875}, {"start": 564.31, "end": 564.73, "word": " صورة", "probability": 0.9820963541666666}, {"start": 564.73, "end": 565.09, "word": " بعض", "probability": 0.956787109375}, {"start": 565.09, "end": 565.27, "word": " في", "probability": 0.84130859375}, {"start": 565.27, "end": 565.83, "word": " المرقاة", "probability": 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الأولى حملة PR و CL و بعدين CH3 و هاي الكاربون اللي هو حملة PR و CL و بعدين CH3 يعني لو هذا و هذا كنت بدأ أسميهم one-bromo one-chloro-ethane", "tokens": [15040, 5016, 19913, 14407, 29538, 9673, 10859, 31747, 11703, 3555, 9307, 3714, 2288, 3794, 20498, 3660, 4724, 9566, 2288, 4587, 3714, 46456, 46538, 3660, 46811, 10943, 995, 3714, 25720, 2423, 39184, 39, 5296, 5172, 30543, 4032, 3714, 25720, 2423, 39184, 39, 15844, 25724, 7649, 3555, 44381, 16095, 8717, 36178, 9673, 10859, 31747, 11703, 3555, 20666, 2304, 8315, 35457, 3660, 37495, 22653, 9154, 8717, 39319, 10632, 3877, 34051, 12602, 14407, 3555, 9566, 37495, 22653, 9122, 9640, 3555, 11536, 16247, 12610, 7578, 11331, 2304, 37977, 11568, 4032, 12855, 4032, 39182, 9957, 5995, 18, 4032, 8032, 47302, 33251, 9640, 3555, 11536, 13672, 1829, 31439, 11331, 2304, 37977, 11568, 4032, 12855, 4032, 39182, 9957, 5995, 18, 37495, 22653, 45164, 23758, 4032, 23758, 9122, 29399, 47525, 10721, 5551, 38251, 1829, 16095, 472, 12, 1443, 13395, 472, 12, 339, 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أتيت من هنا عملة التاني الان من ناحية الاحتمالات متساوية تماما و لذلك يظهر عندي راسيمك ميكسشر يعني يظهر الاتنين و يظهرون بنسب متساوية يظهر الاتنين و يظهرون بنسب متساوية فبصير المحصلة ان ال generation of a chiral center produces راسيمك ميكسشر", "tokens": [28814, 15730, 5551, 31371, 2655, 9154, 34105, 6225, 42213, 3660, 16472, 7649, 8592, 20498, 2288, 4032, 11933, 15730, 5551, 31371, 2655, 9154, 34105, 6225, 42213, 3660, 16712, 7649, 1829, 2423, 7649, 9154, 8717, 39319, 10632, 42963, 33753, 2304, 6027, 9307, 44650, 3794, 995, 2407, 10632, 46811, 10943, 995, 4032, 5296, 8848, 23275, 7251, 19913, 3224, 2288, 43242, 1829, 12602, 32277, 32640, 4117, 3714, 1829, 4117, 3794, 46309, 37495, 22653, 7251, 19913, 3224, 2288, 2423, 9307, 1863, 9957, 4032, 7251, 19913, 3224, 2288, 11536, 44945, 35457, 44650, 3794, 995, 2407, 10632, 7251, 19913, 3224, 2288, 2423, 9307, 1863, 9957, 4032, 7251, 19913, 3224, 2288, 11536, 44945, 35457, 44650, 3794, 995, 2407, 10632, 6156, 3555, 9381, 13546, 9673, 5016, 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الجملة", "probability": 0.9527994791666666}, {"start": 2465.6, "end": 2468.22, "word": " بالنسبة", "probability": 0.9256591796875}, {"start": 2468.22, "end": 2469.12, "word": " للكيميا", "probability": 0.76629638671875}, {"start": 2469.12, "end": 2469.46, "word": " ما", "probability": 0.5927734375}, {"start": 2469.46, "end": 2469.84, "word": " بين", "probability": 0.99072265625}, {"start": 2469.84, "end": 2470.66, "word": " الكيميا", "probability": 0.88037109375}, {"start": 2470.66, "end": 2470.94, "word": " اللي", "probability": 0.7392578125}, {"start": 2470.94, "end": 2471.66, "word": " بيصنعوها", "probability": 0.9780970982142857}, {"start": 2471.66, "end": 2472.42, "word": " البشر", "probability": 0.990234375}, {"start": 2472.42, "end": 2473.28, "word": " و", "probability": 0.97607421875}, {"start": 2473.28, "end": 2473.42, "word": " ما", "probability": 0.67724609375}, {"start": 2473.42, "end": 2473.92, "word": " بين", "probability": 0.99267578125}, {"start": 2473.92, "end": 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diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..a5ae737f15baa5f3e34d6727b9022160a3112579
--- /dev/null
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@@ -0,0 +1 @@
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41.89, "end": 42.51, "word": " لحال؟", "probability": 0.87109375}, {"start": 42.51, "end": 43.03, "word": " السبب", "probability": 0.9905598958333334}, {"start": 43.03, "end": 44.33, "word": " يعود", "probability": 0.986572265625}, {"start": 44.33, "end": 45.23, "word": " لطبيعة", "probability": 0.9102783203125}, {"start": 45.23, "end": 45.81, "word": " التفاعل", "probability": 0.9578857421875}, {"start": 45.81, "end": 46.41, "word": " الكيميائي", "probability": 0.9154296875}, {"start": 46.41, "end": 46.61, "word": " اللي", "probability": 0.676025390625}, {"start": 46.61, "end": 46.77, "word": " هم", "probability": 0.791259765625}, {"start": 46.77, "end": 46.87, "word": " ال", "probability": 0.9755859375}, {"start": 46.87, "end": 47.41, "word": " aldehydes", "probability": 0.936767578125}, {"start": 47.41, "end": 47.57, "word": " و", "probability": 0.98486328125}, {"start": 47.57, "end": 47.69, "word": " ال", "probability": 0.91259765625}, {"start": 47.69, "end": 48.21, "word": " 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"word": " الديهايد", "probability": 0.50439453125}, {"start": 58.74, "end": 60.02, "word": " والكيتوز", "probability": 0.654541015625}, {"start": 60.02, "end": 61.04, "word": " مقارنة", "probability": 0.976953125}, {"start": 61.04, "end": 61.94, "word": " بالالكوهولز", "probability": 0.7969098772321429}, {"start": 61.94, "end": 62.56, "word": " مقارنة", "probability": 0.87900390625}, {"start": 62.56, "end": 63.26, "word": " بالالكينز", "probability": 0.9115234375}, {"start": 63.26, "end": 63.44, "word": " هم", "probability": 0.538330078125}, {"start": 63.44, "end": 64.04, "word": " حالة", "probability": 0.953125}, {"start": 64.04, "end": 64.54, "word": " بين", "probability": 0.97705078125}, {"start": 64.54, "end": 65.3, "word": " الالكوهولز", "probability": 0.9488002232142857}, {"start": 65.3, "end": 66.06, "word": " والالكينز", "probability": 0.85810546875}, {"start": 66.06, "end": 66.22, "word": " من", "probability": 0.9814453125}, {"start": 66.22, "end": 66.58, "word": " ناحية", 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موقع واحد إلا نادرا", "tokens": [3555, 22488, 9957, 1975, 2655, 4117, 19528, 8315, 18871, 16712, 38251, 10632, 12174, 12610, 8315, 2423, 16798, 68, 3495, 14792, 4724, 1829, 47283, 3215, 14407, 8717, 11296, 10632, 2423, 4032, 2423, 14979, 2213, 4724, 1829, 47283, 3215, 14407, 8717, 11296, 10632, 322, 23032, 3555, 3615, 995, 4724, 32640, 1829, 11622, 2423, 16798, 68, 3495, 14792, 16472, 3224, 11778, 16373, 15042, 8032, 2304, 15844, 3714, 30543, 3615, 36764, 24401, 6156, 36150, 11622, 2304, 8592, 8717, 5016, 9566, 6055, 2288, 4587, 32640, 24976, 2423, 37495, 22653, 2423, 2423, 3714, 16758, 2655, 30544, 8592, 42963, 15844, 3714, 30543, 3615, 36764, 24401, 44381, 5296, 15042, 44945, 44510, 10721, 8717, 1829, 7435, 1829, 15844, 2423, 14979, 2213, 2423, 14979, 2213, 4724, 1829, 30544, 2407, 8592, 15844, 3714, 30543, 3615, 36764, 24401, 11933, 15040, 8717, 18513, 23557], "avg_logprob": -0.15104167400435967, "compression_ratio": 2.0440528634361232, "no_speech_prob": 0.0, "words": [{"start": 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{"start": 89.2, "end": 90.16, "word": " واحد", "probability": 0.989501953125}, {"start": 90.16, "end": 90.92, "word": " لكن", "probability": 0.83203125}, {"start": 90.92, "end": 92.1, "word": " لما", "probability": 0.954833984375}, {"start": 92.1, "end": 92.6, "word": " بنبدأ", "probability": 0.93505859375}, {"start": 92.6, "end": 93.0, "word": " نيجي", "probability": 0.9764404296875}, {"start": 93.0, "end": 93.3, "word": " على", "probability": 0.916015625}, {"start": 93.3, "end": 93.8, "word": " ال", "probability": 0.966796875}, {"start": 93.8, "end": 94.58, "word": " ketones", "probability": 0.9453125}, {"start": 94.58, "end": 95.44, "word": " ال", "probability": 0.8359375}, {"start": 95.44, "end": 96.08, "word": " ketones", "probability": 0.952880859375}, {"start": 96.08, "end": 96.64, "word": " بيكونوش", "probability": 0.89658203125}, {"start": 96.64, "end": 96.84, "word": " على", "probability": 0.912109375}, {"start": 96.84, "end": 97.3, "word": " موقع", "probability": 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"probability": 0.99267578125}, {"start": 113.03, "end": 113.79, "word": " يعني", "probability": 0.87451171875}, {"start": 113.79, "end": 114.05, "word": " على", "probability": 0.90966796875}, {"start": 114.05, "end": 115.19, "word": " سبيل", "probability": 0.9830729166666666}, {"start": 115.19, "end": 115.93, "word": " المثال", "probability": 0.9889322916666666}, {"start": 115.93, "end": 116.63, "word": " لو", "probability": 0.919921875}, {"start": 116.63, "end": 116.89, "word": " كنت", "probability": 0.976806640625}, {"start": 116.89, "end": 117.11, "word": " بدى", "probability": 0.6865234375}, {"start": 117.11, "end": 117.43, "word": " اشوف", "probability": 0.8870442708333334}, {"start": 117.43, "end": 117.99, "word": " مركب", "probability": 0.9000651041666666}, {"start": 117.99, "end": 118.21, "word": " زي", "probability": 0.920166015625}, {"start": 118.21, "end": 118.45, "word": " هذا", "probability": 0.71044921875}, {"start": 118.45, "end": 118.87, "word": " سيضة", "probability": 0.5}, {"start": 118.87, "end": 118.99, "word": " بال", "probability": 0.9560546875}, {"start": 118.99, "end": 119.25, "word": " bond", "probability": 0.533203125}, {"start": 119.25, "end": 119.59, "word": " O", "probability": 0.6611328125}, {"start": 119.59, "end": 120.29, "word": " phenyl", "probability": 0.5479736328125}, {"start": 120.29, "end": 122.21, "word": " CH2", "probability": 0.91455078125}, {"start": 122.21, "end": 123.59, "word": " CH3", "probability": 0.762451171875}], "temperature": 1.0}, {"id": 6, "seek": 14865, "start": 125.13, "end": 148.65, "text": "هذا كيتون والـ C double bond O تبعته جاية على موقع واحد ليش؟ لأنه أنا لما أبدأ أسمي واحد، اتنين، تلاتة، شو بدأ أسمي هذا الـ Ketone؟ Iprobanone على نمرة واحد ولا اتنين الـ C double bond O؟ على واحد، اذا هذا one Iprobanone", "tokens": [3224, 15730, 9122, 36081, 11536, 16070, 39184, 383, 3834, 6086, 422, 6055, 3555, 34268, 3224, 10874, 995, 10632, 15844, 3714, 30543, 3615, 36764, 24401, 32239, 8592, 22807, 5296, 33456, 3224, 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أسمي", "probability": 0.95947265625}, {"start": 133.43, "end": 134.01, "word": " واحد،", "probability": 0.7215983072916666}, {"start": 134.01, "end": 134.59, "word": " اتنين،", "probability": 0.94658203125}, {"start": 134.59, "end": 135.63, "word": " تلاتة،", "probability": 0.93955078125}, {"start": 135.63, "end": 135.77, "word": " شو", "probability": 0.884521484375}, {"start": 135.77, "end": 136.01, "word": " بدأ", "probability": 0.6846923828125}, {"start": 136.01, "end": 136.47, "word": " أسمي", "probability": 0.9208984375}, {"start": 136.47, "end": 136.71, "word": " هذا", "probability": 0.984375}, {"start": 136.71, "end": 136.91, "word": " الـ", "probability": 0.5689697265625}, {"start": 136.91, "end": 138.75, "word": " Ketone؟", "probability": 0.67926025390625}, {"start": 138.75, "end": 139.65, "word": " Iprobanone", "probability": 0.59674072265625}, {"start": 139.65, "end": 140.29, "word": " على", "probability": 0.6748046875}, {"start": 140.29, "end": 140.61, "word": " نمرة", "probability": 0.77001953125}, {"start": 140.61, "end": 140.99, "word": " واحد", "probability": 0.989990234375}, {"start": 140.99, "end": 141.19, "word": " ولا", "probability": 0.716796875}, {"start": 141.19, "end": 141.57, "word": " اتنين", "probability": 0.9822998046875}, {"start": 141.57, "end": 141.79, "word": " الـ", "probability": 0.6346435546875}, {"start": 141.79, "end": 141.91, "word": " C", "probability": 0.833984375}, {"start": 141.91, "end": 142.05, "word": " double", "probability": 0.92578125}, {"start": 142.05, "end": 142.43, "word": " bond", "probability": 0.97802734375}, {"start": 142.43, "end": 142.83, "word": " O؟", "probability": 0.866455078125}, {"start": 142.83, "end": 143.57, "word": " على", "probability": 0.7900390625}, {"start": 143.57, "end": 144.05, "word": " واحد،", "probability": 0.8995768229166666}, {"start": 144.05, "end": 144.23, "word": " اذا", "probability": 0.7291259765625}, {"start": 144.23, "end": 144.61, "word": " هذا", "probability": 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"probability": 0.96435546875}, {"start": 164.33, "end": 164.97, "word": " شبه", "probability": 0.78466796875}, {"start": 164.97, "end": 165.45, "word": " بهذه", "probability": 0.828857421875}, {"start": 165.45, "end": 165.85, "word": " الحالة", "probability": 0.95458984375}, {"start": 165.85, "end": 166.25, "word": " ممكن", "probability": 0.853759765625}, {"start": 166.25, "end": 166.69, "word": " يكون", "probability": 0.9228515625}, {"start": 166.69, "end": 167.33, "word": " الكيتون", "probability": 0.7371419270833334}, {"start": 167.33, "end": 167.55, "word": " على", "probability": 0.8759765625}, {"start": 167.55, "end": 167.93, "word": " موقع", "probability": 0.9811197916666666}, {"start": 167.93, "end": 168.29, "word": " واحد", "probability": 0.986572265625}, {"start": 168.29, "end": 169.01, "word": " بعد", "probability": 0.61474609375}, {"start": 169.01, "end": 169.65, "word": " ذلك", "probability": 0.99365234375}, {"start": 169.65, "end": 170.21, "word": " مثلا", "probability": 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205.86, "text": "لكن اختصرنا الاتنين لإيش؟ لأن لو جت على واحد هيصير بروبانال و هذا المركب لبروبانون هو الاسيتون الان هنا عندي اربع كربونات اذا بحكي انا عن بيوتانون ال C double bond O جاية فيه على موقع اتنين من ناحية المبدأ ايضا ممكن نختصرها", "tokens": [1211, 19452, 1975, 46456, 9381, 2288, 8315, 2423, 9307, 1863, 9957, 5296, 28814, 1829, 8592, 22807, 5296, 33456, 45164, 10874, 2655, 15844, 36764, 24401, 8032, 1829, 9381, 13546, 4724, 32887, 3555, 7649, 6027, 4032, 23758, 9673, 31747, 3555, 5296, 26890, 37746, 7649, 11536, 31439, 2423, 32277, 36081, 11536, 2423, 7649, 34105, 18871, 16254, 1975, 25513, 3615, 9122, 25513, 2407, 8315, 2655, 1975, 15730, 4724, 5016, 4117, 1829, 1975, 8315, 18871, 4724, 1829, 35473, 7649, 11536, 2423, 383, 3834, 6086, 422, 10874, 995, 10632, 8978, 3224, 15844, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 1975, 1829, 11242, 995, 3714, 43020, 8717, 46456, 9381, 2288, 11296], "avg_logprob": -0.2677176312676498, 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"text": "الان لو كنا بنسمي فيه ال common nomenclature وبنعبر عن البروم هنا بنعبرش بنظام الترقيم هذا لأ بنيجي بنقول والله الموقع الأول بعد ال c double bond o بنعطيه alpha الموقع اللي بعده beta الموقع اللي بعده gamma و هكذا فلاحظوا ان الموقع alpha بالنسبة ل c double bond o هو موقع ايش", "tokens": [6027, 7649, 45164, 9122, 8315, 44945, 38251, 1829, 8978, 3224, 2423, 2689, 297, 4726, 3474, 1503, 46599, 1863, 3615, 3555, 2288, 18871, 2423, 26890, 20498, 34105, 44945, 3615, 3555, 2288, 8592, 44945, 19913, 10943, 16712, 2288, 4587, 32640, 23758, 5296, 10721, 44945, 1829, 7435, 1829, 44945, 39648, 16070, 43761, 9673, 30543, 3615, 16247, 12610, 39182, 2423, 269, 3834, 6086, 277, 44945, 3615, 9566, 1829, 3224, 8961, 9673, 30543, 3615, 13672, 1829, 39182, 3224, 9861, 9673, 30543, 3615, 13672, 1829, 39182, 3224, 15546, 4032, 8032, 4117, 15730, 6156, 15040, 5016, 19913, 14407, 16472, 9673, 30543, 3615, 8961, 20666, 1863, 35457, 3660, 5296, 269, 3834, 6086, 277, 31439, 3714, 30543, 3615, 1975, 1829, 8592], "avg_logprob": -0.24999999156040428, "compression_ratio": 1.891304347826087, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 801.91, "end": 803.19, "word": "الان", "probability": 0.5701904296875}, {"start": 803.19, "end": 803.61, "word": " لو", "probability": 0.83251953125}, {"start": 803.61, "end": 803.85, "word": " كنا", "probability": 0.9091796875}, {"start": 803.85, "end": 804.57, "word": " بنسمي", "probability": 0.73486328125}, {"start": 804.57, "end": 804.91, "word": " فيه", "probability": 0.593017578125}, {"start": 804.91, "end": 805.19, "word": " ال", "probability": 0.409912109375}, {"start": 805.19, "end": 805.55, "word": " common", "probability": 0.84716796875}, {"start": 805.55, "end": 806.67, "word": " nomenclature", "probability": 0.852783203125}, {"start": 806.67, "end": 808.09, "word": " وبنعبر", "probability": 0.6484375}, {"start": 808.09, "end": 808.27, "word": " عن", "probability": 0.73291015625}, {"start": 808.27, "end": 808.79, "word": " البروم", "probability": 0.58544921875}, {"start": 808.79, "end": 809.19, "word": " هنا", "probability": 0.83544921875}, {"start": 809.19, "end": 810.27, "word": " بنعبرش", "probability": 0.7341796875}, {"start": 810.27, "end": 810.79, "word": " بنظام", "probability": 0.9031575520833334}, {"start": 810.79, "end": 811.39, "word": " الترقيم", "probability": 0.9791259765625}, {"start": 811.39, "end": 811.65, "word": " هذا", "probability": 0.83935546875}, {"start": 811.65, "end": 811.85, "word": " لأ", "probability": 0.781005859375}, {"start": 811.85, "end": 812.25, "word": " بنيجي", "probability": 0.8148193359375}, {"start": 812.25, "end": 812.81, "word": " بنقول", "probability": 0.92578125}, {"start": 812.81, "end": 813.53, "word": " والله", "probability": 0.779541015625}, {"start": 813.53, "end": 814.83, "word": " الموقع", "probability": 0.9814453125}, {"start": 814.83, "end": 815.81, "word": " الأول", "probability": 0.86865234375}, {"start": 815.81, "end": 816.87, "word": " بعد", "probability": 0.92626953125}, {"start": 816.87, "end": 817.25, "word": " ال", "probability": 0.57861328125}, {"start": 817.25, "end": 817.39, "word": " c", "probability": 0.23779296875}, {"start": 817.39, "end": 817.59, "word": " double", "probability": 0.4384765625}, {"start": 817.59, "end": 817.95, "word": " bond", "probability": 0.89013671875}, {"start": 817.95, "end": 818.09, "word": " o", "probability": 0.76220703125}, {"start": 818.09, "end": 818.71, "word": " بنعطيه", "probability": 0.9353515625}, {"start": 818.71, "end": 819.15, "word": " alpha", "probability": 0.388427734375}, {"start": 819.15, "end": 820.03, "word": " الموقع", "probability": 0.9768880208333334}, {"start": 820.03, "end": 820.23, "word": " اللي", "probability": 0.9111328125}, {"start": 820.23, "end": 820.81, "word": " بعده", "probability": 0.9482421875}, {"start": 820.81, "end": 821.41, "word": " beta", "probability": 0.298095703125}, {"start": 821.41, "end": 821.87, "word": " الموقع", "probability": 0.9462890625}, {"start": 821.87, "end": 822.09, "word": " اللي", "probability": 0.987060546875}, {"start": 822.09, "end": 822.55, "word": " بعده", "probability": 0.953857421875}, {"start": 822.55, "end": 823.53, "word": " gamma", "probability": 0.7802734375}, {"start": 823.53, "end": 823.69, "word": " و", "probability": 0.65234375}, {"start": 823.69, "end": 824.19, "word": " هكذا", "probability": 0.7735188802083334}, {"start": 824.19, "end": 825.39, "word": " فلاحظوا", "probability": 0.98837890625}, {"start": 825.39, "end": 825.57, "word": " ان", "probability": 0.5830078125}, {"start": 825.57, "end": 826.29, "word": " الموقع", "probability": 0.9412434895833334}, {"start": 826.29, "end": 826.91, "word": " alpha", "probability": 0.383056640625}, {"start": 826.91, "end": 828.01, "word": " بالنسبة", "probability": 0.977294921875}, {"start": 828.01, "end": 828.13, "word": " ل", "probability": 0.65087890625}, {"start": 828.13, "end": 828.35, "word": " c", "probability": 0.495361328125}, {"start": 828.35, "end": 828.57, "word": " double", "probability": 0.90869140625}, {"start": 828.57, "end": 828.95, "word": " bond", "probability": 0.974609375}, {"start": 828.95, "end": 829.33, "word": " o", "probability": 0.93212890625}, {"start": 829.33, "end": 829.77, "word": " هو", "probability": 0.986328125}, {"start": 829.77, "end": 830.25, "word": " موقع", "probability": 0.9874674479166666}, {"start": 830.25, "end": 830.63, "word": " ايش", "probability": 0.8214518229166666}], "temperature": 1.0}, {"id": 36, "seek": 85310, "start": 831.36, "end": 853.1, "text": "إتنين فلو هذا أنا بدي أسميه butyraldehyde البرومو أين جاية عليه؟ على Alpha فأنا بدي أجي أقول عنه Alpha Bromo يعني البرومو جاية على موقع Alpha Butyraldehyde واضح الفكرة؟", "tokens": [28814, 2655, 1863, 9957, 6156, 1211, 2407, 23758, 41850, 4724, 16254, 5551, 38251, 1829, 3224, 457, 88, 2155, 1479, 3495, 1479, 2423, 26890, 20498, 2407, 5551, 9957, 10874, 995, 10632, 47356, 22807, 15844, 20588, 6156, 10721, 8315, 4724, 16254, 5551, 7435, 1829, 5551, 39648, 18871, 3224, 20588, 1603, 13395, 37495, 22653, 2423, 26890, 20498, 2407, 10874, 995, 10632, 15844, 3714, 30543, 3615, 20588, 583, 88, 2155, 1479, 3495, 1479, 4032, 46958, 5016, 27188, 4117, 25720, 22807], "avg_logprob": -0.2242288937816372, "compression_ratio": 1.5688622754491017, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 831.36, "end": 832.08, "word": "إتنين", "probability": 0.73944091796875}, {"start": 832.08, "end": 832.72, "word": " فلو", "probability": 0.8162434895833334}, {"start": 832.72, "end": 832.96, "word": " هذا", "probability": 0.92138671875}, {"start": 832.96, "end": 833.12, "word": " أنا", "probability": 0.5224609375}, {"start": 833.12, "end": 833.3, "word": " بدي", "probability": 0.5960693359375}, {"start": 833.3, "end": 833.7, "word": " أسميه", "probability": 0.852783203125}, {"start": 833.7, "end": 835.44, "word": " butyraldehyde", "probability": 0.8474527994791666}, {"start": 835.44, "end": 837.52, "word": " البرومو", "probability": 0.694580078125}, {"start": 837.52, "end": 837.7, "word": " أين", "probability": 0.7052001953125}, {"start": 837.7, "end": 838.08, "word": " جاية", "probability": 0.8527018229166666}, {"start": 838.08, "end": 839.32, "word": " عليه؟", "probability": 0.64306640625}, {"start": 839.32, "end": 839.54, "word": " على", "probability": 0.8720703125}, {"start": 839.54, "end": 840.02, "word": " Alpha", "probability": 0.3056640625}, {"start": 840.02, "end": 840.62, "word": " فأنا", "probability": 0.8470052083333334}, {"start": 840.62, "end": 840.88, "word": " بدي", "probability": 0.938720703125}, {"start": 840.88, "end": 841.12, "word": " أجي", "probability": 0.9147135416666666}, {"start": 841.12, "end": 841.44, "word": " أقول", "probability": 0.9052734375}, {"start": 841.44, "end": 841.82, "word": " عنه", "probability": 0.95361328125}, {"start": 841.82, "end": 842.48, "word": " Alpha", "probability": 0.87353515625}, {"start": 842.48, "end": 843.58, "word": " Bromo", "probability": 0.50775146484375}, {"start": 843.58, "end": 843.86, "word": " يعني", "probability": 0.919189453125}, {"start": 843.86, "end": 844.5, "word": " البرومو", "probability": 0.9652099609375}, {"start": 844.5, "end": 845.0, "word": " جاية", "probability": 0.9879557291666666}, {"start": 845.0, "end": 845.58, "word": " على", "probability": 0.96337890625}, {"start": 845.58, "end": 846.02, "word": " موقع", "probability": 0.9820963541666666}, {"start": 846.02, "end": 846.46, "word": " Alpha", "probability": 0.97265625}, {"start": 846.46, "end": 849.72, "word": " Butyraldehyde", "probability": 0.93017578125}, {"start": 849.72, "end": 852.18, "word": " واضح", "probability": 0.9552408854166666}, {"start": 852.18, "end": 853.1, "word": " الفكرة؟", "probability": 0.8848876953125}], "temperature": 1.0}, {"id": 37, "seek": 87984, "start": 853.62, "end": 879.84, "text": "فإذا استعملنا لوصف المواقع الجانب السيضة بالـ bond O Alpha و Beta و Gamma أو كان عندي أي شغل هان بقول هي بالنسبة للسيضة بال bond O بنظام ال أيوبك على موقع اتنين بنظام ال common موقع اتنين بيكون موقع Alpha مش Beta يعني مابنجيش نحط Alpha هان و Beta هان لأ ال Alpha هي موقع اتنين", "tokens": [5172, 28814, 15730, 44713, 25957, 1211, 8315, 5296, 2407, 9381, 5172, 9673, 14407, 4587, 3615, 25724, 7649, 3555, 21136, 1829, 11242, 3660, 20666, 39184, 6086, 422, 20588, 4032, 33286, 4032, 24723, 1696, 34051, 25961, 18871, 16254, 36632, 13412, 17082, 1211, 8032, 7649, 4724, 39648, 39896, 20666, 1863, 35457, 3660, 24976, 3794, 1829, 11242, 3660, 20666, 6086, 422, 44945, 19913, 10943, 2423, 36632, 37746, 4117, 15844, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 44945, 19913, 10943, 2423, 2689, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 4724, 1829, 30544, 3714, 30543, 3615, 20588, 37893, 33286, 37495, 22653, 3714, 16758, 1863, 7435, 1829, 8592, 8717, 5016, 9566, 20588, 8032, 7649, 4032, 33286, 8032, 7649, 5296, 10721, 2423, 20588, 39896, 3714, 30543, 3615, 1975, 2655, 1863, 9957], "avg_logprob": -0.18447580789366075, "compression_ratio": 1.893162393162393, "no_speech_prob": 0.0, "words": [{"start": 853.62, "end": 854.26, "word": "فإذا", "probability": 0.7569986979166666}, {"start": 854.26, "end": 855.22, "word": " استعملنا", "probability": 0.94482421875}, {"start": 855.22, "end": 855.92, "word": " لوصف", "probability": 0.8499755859375}, {"start": 855.92, "end": 856.62, "word": " المواقع", "probability": 0.98974609375}, {"start": 856.62, "end": 857.12, "word": " الجانب", "probability": 0.6393229166666666}, {"start": 857.12, "end": 857.56, "word": " السيضة", "probability": 0.63531494140625}, {"start": 857.56, "end": 857.76, "word": " بالـ", "probability": 0.587890625}, {"start": 857.76, "end": 857.98, "word": " bond", "probability": 0.38623046875}, {"start": 857.98, "end": 858.34, "word": " O", "probability": 0.58056640625}, {"start": 858.34, "end": 858.94, "word": " Alpha", "probability": 0.403564453125}, {"start": 858.94, "end": 859.2, "word": " و", "probability": 0.896484375}, {"start": 859.2, 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"probability": 0.88671875}, {"start": 863.42, "end": 863.54, "word": " بال", "probability": 0.96337890625}, {"start": 863.54, "end": 863.82, "word": " bond", "probability": 0.7431640625}, {"start": 863.82, "end": 864.22, "word": " O", "probability": 0.94873046875}, {"start": 864.22, "end": 865.24, "word": " بنظام", "probability": 0.9430338541666666}, {"start": 865.24, "end": 865.38, "word": " ال", "probability": 0.904296875}, {"start": 865.38, "end": 865.88, "word": " أيوبك", "probability": 0.6593424479166666}, {"start": 865.88, "end": 866.08, "word": " على", "probability": 0.8349609375}, {"start": 866.08, "end": 866.68, "word": " موقع", "probability": 0.9840494791666666}, {"start": 866.68, "end": 868.06, "word": " اتنين", "probability": 0.9053955078125}, {"start": 868.06, "end": 868.86, "word": " بنظام", "probability": 0.8841145833333334}, {"start": 868.86, "end": 869.02, "word": " ال", "probability": 0.95068359375}, {"start": 869.02, "end": 869.36, "word": " common", "probability": 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"probability": 0.7763671875}, {"start": 921.57, "end": 921.89, "word": " Alpha", "probability": 0.9482421875}, {"start": 921.89, "end": 922.47, "word": " اتنين", "probability": 0.9603271484375}, {"start": 922.47, "end": 922.81, "word": " Beta", "probability": 0.68603515625}, {"start": 922.81, "end": 923.03, "word": " زى", "probability": 0.849609375}, {"start": 923.03, "end": 923.11, "word": " ما", "probability": 0.9775390625}, {"start": 923.11, "end": 923.35, "word": " انتوا", "probability": 0.8154296875}, {"start": 923.35, "end": 923.63, "word": " فاهمين", "probability": 0.98046875}, {"start": 923.63, "end": 924.21, "word": " لأ", "probability": 0.884521484375}, {"start": 924.21, "end": 924.43, "word": " هو", "probability": 0.95947265625}, {"start": 924.43, "end": 925.01, "word": " موقع", "probability": 0.99462890625}, {"start": 925.01, "end": 925.67, "word": " اتنين", "probability": 0.9898681640625}], "temperature": 1.0}, {"id": 40, "seek": 94744, "start": 926.5, "end": 947.44, 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"probability": 0.7056884765625}, {"start": 1161.28, "end": 1162.28, "word": " بتلاحظوا", "probability": 0.9412109375}, {"start": 1162.28, "end": 1164.66, "word": " secondary", "probability": 0.387451171875}, {"start": 1164.66, "end": 1166.84, "word": " butyl", "probability": 0.950439453125}, {"start": 1166.84, "end": 1168.4, "word": " شايفين", "probability": 0.9093017578125}, {"start": 1168.4, "end": 1168.76, "word": " الناس", "probability": 0.9903971354166666}, {"start": 1168.76, "end": 1168.9, "word": " اللي", "probability": 0.984130859375}, {"start": 1168.9, "end": 1169.5, "word": " بدرسوش", "probability": 0.98505859375}, {"start": 1169.5, "end": 1170.02, "word": " كتير", "probability": 0.9820963541666666}, {"start": 1170.02, "end": 1171.62, "word": " secondary", "probability": 0.62060546875}, {"start": 1171.62, "end": 1172.58, "word": " butyl", "probability": 0.96630859375}], "temperature": 1.0}, {"id": 50, "seek": 120402, "start": 1174.4, "end": 1204.02, "text": "اخدتوها بوضوح جدا سكندر بيوت الـ Cyclopropane طيب الآن هنا اعتبرنا الأساس إيش؟ الـ Cyclopropane هل يا تورا ممكن أننا نعتبر الأساس السلسلة؟ أكيد لما نعتبر الأساس السلسلة، شو هنقول؟ البيوتين على نمرأ اتنين من البيوتين، إيش عندكم؟ Cyclopropane", "tokens": [47283, 3215, 2655, 2407, 11296, 4724, 2407, 11242, 2407, 5016, 10874, 28259, 8608, 19452, 3215, 2288, 4724, 1829, 35473, 2423, 39184, 49173, 404, 1513, 1929, 23032, 1829, 3555, 6024, 48506, 34105, 1975, 34268, 26890, 8315, 16247, 3794, 32277, 11933, 1829, 8592, 22807, 2423, 39184, 49173, 404, 1513, 1929, 8032, 1211, 35186, 6055, 13063, 995, 3714, 43020, 14739, 8315, 8717, 34268, 26890, 16247, 3794, 32277, 21136, 1211, 3794, 37977, 22807, 5551, 4117, 25708, 5296, 15042, 8717, 34268, 26890, 16247, 3794, 32277, 21136, 1211, 3794, 37977, 12399, 13412, 2407, 8032, 1863, 39648, 22807, 2423, 21292, 35473, 9957, 15844, 8717, 29973, 10721, 1975, 2655, 1863, 9957, 9154, 2423, 21292, 35473, 9957, 12399, 11933, 1829, 8592, 43242, 24793, 22807, 49173, 404, 1513, 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{"start": 1189.44, "end": 1191.28, "word": " السلسلة؟", "probability": 0.91728515625}, {"start": 1191.28, "end": 1192.2, "word": " أكيد", "probability": 0.9573567708333334}, {"start": 1192.2, "end": 1192.68, "word": " لما", "probability": 0.793212890625}, {"start": 1192.68, "end": 1193.22, "word": " نعتبر", "probability": 0.99462890625}, {"start": 1193.22, "end": 1193.74, "word": " الأساس", "probability": 0.9777018229166666}, {"start": 1193.74, "end": 1194.72, "word": " السلسلة،", "probability": 0.881640625}, {"start": 1194.72, "end": 1194.88, "word": " شو", "probability": 0.927978515625}, {"start": 1194.88, "end": 1196.04, "word": " هنقول؟", "probability": 0.94580078125}, {"start": 1196.04, "end": 1197.46, "word": " البيوتين", "probability": 0.82623291015625}, {"start": 1197.46, "end": 1199.28, "word": " على", "probability": 0.75634765625}, {"start": 1199.28, "end": 1199.9, "word": " نمرأ", "probability": 0.7703450520833334}, {"start": 1199.9, "end": 1200.66, "word": " اتنين", "probability": 0.8958740234375}, {"start": 1200.66, "end": 1200.9, "word": " من", "probability": 0.9951171875}, {"start": 1200.9, "end": 1201.8, "word": " البيوتين،", "probability": 0.9421875}, {"start": 1201.8, "end": 1202.0, "word": " إيش", "probability": 0.9363606770833334}, {"start": 1202.0, "end": 1202.76, "word": " عندكم؟", "probability": 0.982421875}, {"start": 1202.76, "end": 1204.02, "word": " Cyclopropane", "probability": 0.871826171875}], "temperature": 1.0}, {"id": 51, "seek": 122129, "start": 1204.89, "end": 1221.29, "text": "لحتى الآن مش عمال تقدروا تذكرواها بإنصيغة مجموعة بزام Cyclopropane لما يصير مجموعة شو هيصير؟ Cyclopropane اذا اتنين Cyclopropane", "tokens": [1211, 33753, 7578, 6024, 48506, 37893, 6225, 2304, 6027, 6055, 28543, 2288, 14407, 6055, 8848, 37983, 14407, 11296, 4724, 28814, 1863, 9381, 1829, 17082, 3660, 3714, 7435, 2304, 2407, 27884, 4724, 11622, 10943, 49173, 404, 1513, 1929, 5296, 15042, 7251, 9381, 13546, 3714, 7435, 2304, 2407, 27884, 13412, 2407, 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0.5826822916666666}, {"start": 1210.87, "end": 1212.23, "word": " Cyclopropane", "probability": 0.69671630859375}, {"start": 1212.23, "end": 1212.57, "word": " لما", "probability": 0.9267578125}, {"start": 1212.57, "end": 1212.95, "word": " يصير", "probability": 0.9778645833333334}, {"start": 1212.95, "end": 1213.65, "word": " مجموعة", "probability": 0.96708984375}, {"start": 1213.65, "end": 1213.87, "word": " شو", "probability": 0.83740234375}, {"start": 1213.87, "end": 1215.03, "word": " هيصير؟", "probability": 0.8182373046875}, {"start": 1215.03, "end": 1217.31, "word": " Cyclopropane", "probability": 0.88232421875}, {"start": 1217.31, "end": 1217.75, "word": " اذا", "probability": 0.43212890625}, {"start": 1217.75, "end": 1218.55, "word": " اتنين", "probability": 0.903076171875}, {"start": 1218.55, "end": 1221.29, "word": " Cyclopropane", "probability": 0.809326171875}], "temperature": 1.0}, {"id": 52, "seek": 124433, "start": 1223.62, "end": 1244.34, "text": "واضح؟ فالسكندري بيوت ال cyclopropane هو نفسه اتنين cyclopropyl butane يعني انا لما اجيت اسميه .. انا لما اجيت اسميه .. قولت يا تورا بدي اخلي مرجعيتي الحلقة ولا اخلي مرجعيتي ايش؟", "tokens": [2407, 46958, 5016, 22807, 6156, 6027, 3794, 19452, 3215, 2288, 1829, 4724, 1829, 35473, 2423, 19474, 404, 1513, 1929, 31439, 8717, 36178, 3224, 1975, 2655, 1863, 9957, 19474, 404, 1513, 5088, 457, 1929, 37495, 22653, 1975, 8315, 5296, 15042, 1975, 7435, 36081, 24525, 2304, 1829, 3224, 4386, 1975, 8315, 5296, 15042, 1975, 7435, 36081, 24525, 2304, 1829, 3224, 4386, 12174, 12610, 2655, 35186, 6055, 13063, 995, 4724, 16254, 1975, 9778, 20292, 3714, 47341, 3615, 1829, 31371, 21542, 1211, 28671, 49429, 1975, 9778, 20292, 3714, 47341, 3615, 1829, 31371, 1975, 1829, 8592, 22807], "avg_logprob": -0.19506048066641696, "compression_ratio": 1.7159763313609468, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1223.62, "end": 1224.54, "word": "واضح؟", "probability": 0.8824462890625}, {"start": 1224.54, "end": 1225.62, "word": " فالسكندري", "probability": 0.794677734375}, {"start": 1225.62, "end": 1226.02, "word": " بيوت", "probability": 0.8990885416666666}, {"start": 1226.02, "end": 1226.28, "word": " ال", "probability": 0.76318359375}, {"start": 1226.28, "end": 1228.22, "word": " cyclopropane", "probability": 0.72235107421875}, {"start": 1228.22, "end": 1228.74, "word": " هو", "probability": 0.98388671875}, {"start": 1228.74, "end": 1229.7, "word": " نفسه", "probability": 0.99609375}, {"start": 1229.7, "end": 1230.42, "word": " اتنين", "probability": 0.9351806640625}, {"start": 1230.42, "end": 1231.86, "word": " cyclopropyl", "probability": 0.758056640625}, {"start": 1231.86, "end": 1232.64, "word": " butane", "probability": 0.6990966796875}, {"start": 1232.64, "end": 1233.2, "word": " يعني", "probability": 0.869384765625}, {"start": 1233.2, "end": 1233.52, "word": " انا", "probability": 0.782470703125}, {"start": 1233.52, "end": 1233.76, "word": " لما", "probability": 0.934326171875}, {"start": 1233.76, "end": 1234.22, "word": " اجيت", "probability": 0.8492838541666666}, {"start": 1234.22, "end": 1235.22, "word": " اسميه", "probability": 0.8470458984375}, {"start": 1235.22, "end": 1235.22, "word": " ..", "probability": 0.6240234375}, {"start": 1235.22, "end": 1235.46, "word": " انا", "probability": 0.878662109375}, {"start": 1235.46, "end": 1235.64, "word": " لما", "probability": 0.989990234375}, {"start": 1235.64, "end": 1236.0, "word": " اجيت", "probability": 0.9856770833333334}, {"start": 1236.0, "end": 1236.88, "word": " اسميه", "probability": 0.9793701171875}, {"start": 1236.88, "end": 1236.98, "word": " ..", "probability": 0.432373046875}, {"start": 1236.98, "end": 1237.3, "word": " قولت", "probability": 0.8235677083333334}, {"start": 1237.3, "end": 1237.42, "word": " يا", "probability": 0.9130859375}, {"start": 1237.42, "end": 1237.76, "word": " تورا", "probability": 0.7556966145833334}, {"start": 1237.76, "end": 1238.2, "word": " بدي", "probability": 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"probability": 0.9453125}, {"start": 2816.5, "end": 2817.04, "word": " ناتجين", "probability": 0.969970703125}, {"start": 2817.04, "end": 2817.72, "word": " مهمات", "probability": 0.810791015625}, {"start": 2817.72, "end": 2818.12, "word": " مش", "probability": 0.69091796875}, {"start": 2818.12, "end": 2818.5, "word": " ناتج", "probability": 0.99072265625}, {"start": 2818.5, "end": 2818.96, "word": " واحد", "probability": 0.99462890625}, {"start": 2818.96, "end": 2819.56, "word": " من", "probability": 0.76171875}, {"start": 2819.56, "end": 2819.82, "word": " هنا", "probability": 0.9462890625}, {"start": 2819.82, "end": 2820.42, "word": " بيكسل", "probability": 0.93818359375}, {"start": 2820.42, "end": 2820.88, "word": " هذه", "probability": 0.4404296875}, {"start": 2820.88, "end": 2821.32, "word": " بتصير", "probability": 0.84912109375}, {"start": 2821.32, "end": 2822.22, "word": " CWO", "probability": 0.3365885416666667}, {"start": 2822.22, "end": 2822.52, "word": " وهذه", "probability": 0.6563720703125}, {"start": 2822.52, "end": 2822.88, "word": " بتصير", "probability": 0.8719075520833334}, {"start": 2822.88, "end": 2823.68, "word": " CWO", "probability": 0.9293619791666666}, {"start": 2823.68, "end": 2824.42, "word": " الآن", "probability": 0.640380859375}, {"start": 2824.42, "end": 2824.78, "word": " هذا", "probability": 0.9267578125}, {"start": 2824.78, "end": 2825.24, "word": " الجزء", "probability": 0.98291015625}, {"start": 2825.24, "end": 2825.86, "word": " CH3", "probability": 0.95068359375}, {"start": 2825.86, "end": 2827.24, "word": " CH3", "probability": 0.72509765625}, {"start": 2827.24, "end": 2827.54, "word": " هو", "probability": 0.68115234375}, {"start": 2827.54, "end": 2828.04, "word": " ايش", "probability": 0.6817220052083334}, {"start": 2828.04, "end": 2828.84, "word": " ال", "probability": 0.78955078125}, {"start": 2828.84, "end": 2829.42, "word": " Acetone", "probability": 0.710205078125}, {"start": 2829.42, "end": 2829.88, "word": " هذا", "probability": 0.912109375}, {"start": 2829.88, "end": 2830.5, "word": " الجزء", "probability": 0.9931640625}, {"start": 2830.5, "end": 2831.9, "word": " بيحول", "probability": 0.9346923828125}, {"start": 2831.9, "end": 2832.5, "word": " الى", "probability": 0.614990234375}, {"start": 2832.5, "end": 2833.1, "word": " Enol", "probability": 0.6776123046875}, {"start": 2833.1, "end": 2833.66, "word": " بيصير", "probability": 0.8712158203125}, {"start": 2833.66, "end": 2834.46, "word": " Phenol", "probability": 0.9444986979166666}], "temperature": 1.0}, {"id": 119, "seek": 286387, "start": 2836.31, "end": 2863.87, "text": "فتفاعل الكيومين مع الأكسجين وحمض الكابريتيك إيش بيعطينا؟ Phenol and Acetone يعني لو بدنا نسألكوا reaction of الكيومين with أكسجين و presence of sulphuric acid بطريقة معينة produces Phenol and Acetone و هدولة المركبين إيش مالهم؟ مركبات مهمة جدا في ال organ الchemistry", "tokens": [5172, 2655, 5172, 995, 30241, 33251, 1829, 20498, 9957, 20449, 16247, 4117, 3794, 7435, 9957, 4032, 35571, 11242, 33251, 16758, 16572, 31371, 4117, 11933, 1829, 8592, 4724, 40228, 9566, 1829, 8315, 22807, 2623, 268, 401, 293, 5097, 302, 546, 37495, 22653, 45164, 47525, 8315, 8717, 3794, 10721, 23275, 14407, 5480, 295, 33251, 1829, 20498, 9957, 365, 5551, 4117, 3794, 7435, 9957, 4032, 6814, 295, 47286, 374, 299, 8258, 4724, 9566, 16572, 28671, 20449, 9957, 3660, 14725, 2623, 268, 401, 293, 5097, 302, 546, 4032, 8032, 3215, 12610, 3660, 9673, 31747, 3555, 9957, 11933, 1829, 8592, 3714, 6027, 16095, 22807, 3714, 31747, 3555, 9307, 3714, 16095, 3660, 10874, 28259, 8978, 2423, 1798, 2423, 48353], "avg_logprob": -0.2420504417335778, "compression_ratio": 1.597609561752988, "no_speech_prob": 0.0, "words": [{"start": 2836.3100000000004, "end": 2837.51, "word": "فتفاعل", "probability": 0.828515625}, {"start": 2837.51, "end": 2838.25, "word": " الكيومين", "probability": 0.8558349609375}, {"start": 2838.25, "end": 2838.45, "word": " مع", "probability": 0.95654296875}, {"start": 2838.45, "end": 2839.23, "word": " الأكسجين", "probability": 0.803759765625}, {"start": 2839.23, "end": 2839.79, "word": " وحمض", "probability": 0.912109375}, {"start": 2839.79, "end": 2840.73, "word": " الكابريتيك", "probability": 0.82587890625}, {"start": 2840.73, "end": 2841.15, "word": " إيش", "probability": 0.6745402018229166}, {"start": 2841.15, "end": 2842.63, "word": " بيعطينا؟", "probability": 0.8920084635416666}, {"start": 2842.63, "end": 2843.37, "word": " Phenol", "probability": 0.691650390625}, {"start": 2843.37, "end": 2844.11, "word": " and", "probability": 0.79931640625}, {"start": 2844.11, "end": 2844.73, "word": " Acetone", "probability": 0.7842610677083334}, {"start": 2844.73, "end": 2844.93, "word": " يعني", "probability": 0.7197265625}, {"start": 2844.93, "end": 2845.11, "word": " لو", "probability": 0.96630859375}, {"start": 2845.11, "end": 2845.37, "word": " بدنا", "probability": 0.8359375}, {"start": 2845.37, "end": 2846.25, "word": " نسألكوا", "probability": 0.86640625}, {"start": 2846.25, "end": 2846.97, "word": " reaction", "probability": 0.59375}, {"start": 2846.97, "end": 2847.41, "word": " of", "probability": 0.93212890625}, {"start": 2847.41, "end": 2848.01, "word": " الكيومين", "probability": 0.9510498046875}, {"start": 2848.01, "end": 2848.21, "word": " with", "probability": 0.77197265625}, {"start": 2848.21, "end": 2848.79, "word": " أكسجين", "probability": 0.89111328125}, {"start": 2848.79, "end": 2848.91, "word": " و", "probability": 0.196533203125}, {"start": 2848.91, "end": 2849.17, "word": " presence", "probability": 0.1864013671875}, {"start": 2849.17, "end": 2849.83, "word": " of", "probability": 0.95263671875}, {"start": 2849.83, "end": 2850.67, "word": " sulphuric", "probability": 0.7679850260416666}, {"start": 2850.67, "end": 2851.01, "word": " acid", "probability": 0.9619140625}, {"start": 2851.01, "end": 2851.53, "word": " بطريقة", "probability": 0.943603515625}, {"start": 2851.53, "end": 2852.33, "word": " معينة", "probability": 0.98876953125}, {"start": 2852.33, "end": 2854.13, "word": " produces", "probability": 0.73828125}, {"start": 2854.13, "end": 2856.37, "word": " Phenol", "probability": 0.8518880208333334}, {"start": 2856.37, "end": 2856.85, "word": " and", "probability": 0.9638671875}, {"start": 2856.85, "end": 2857.65, "word": " Acetone", "probability": 0.9430338541666666}, {"start": 2857.65, "end": 2857.73, "word": " و", "probability": 0.454833984375}, {"start": 2857.73, "end": 2858.13, "word": " هدولة", "probability": 0.7235107421875}, {"start": 2858.13, "end": 2858.85, "word": " المركبين", "probability": 0.85467529296875}, {"start": 2858.85, "end": 2859.11, "word": " إيش", "probability": 0.9733072916666666}, {"start": 2859.11, "end": 2860.05, "word": " مالهم؟", "probability": 0.8739013671875}, {"start": 2860.05, "end": 2860.89, "word": " مركبات", "probability": 0.9725341796875}, {"start": 2860.89, "end": 2861.97, "word": " مهمة", "probability": 0.9899088541666666}, {"start": 2861.97, "end": 2862.71, "word": " جدا", "probability": 0.975830078125}, {"start": 2862.71, "end": 2862.89, "word": " في", "probability": 0.89697265625}, {"start": 2862.89, "end": 2863.03, "word": " ال", "probability": 0.71728515625}, {"start": 2863.03, "end": 2863.31, "word": " organ", "probability": 0.47021484375}, {"start": 2863.31, "end": 2863.87, "word": " الchemistry", "probability": 0.36767578125}], "temperature": 1.0}, {"id": 120, "seek": 287049, "start": 2866.55, "end": 2870.49, "text": "لحد هنا بننهي اليوم ان شاء الله إلى اللقاء", "tokens": [1211, 24401, 34105, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984, 30731, 13672, 4587, 16606], "avg_logprob": -0.2304687516556846, "compression_ratio": 1.1343283582089552, "no_speech_prob": 0.0, "words": [{"start": 2866.55, "end": 2867.07, "word": "لحد", "probability": 0.986328125}, {"start": 2867.07, "end": 2867.49, "word": " هنا", "probability": 0.9580078125}, {"start": 2867.49, "end": 2868.71, "word": " بننهي", "probability": 0.77838134765625}, {"start": 2868.71, "end": 2869.19, "word": " اليوم", "probability": 0.942626953125}, {"start": 2869.19, "end": 2869.37, "word": " ان", "probability": 0.6064453125}, {"start": 2869.37, "end": 2869.65, "word": " شاء", "probability": 0.982421875}, {"start": 2869.65, "end": 2869.79, "word": " الله", "probability": 0.9541015625}, {"start": 2869.79, "end": 2870.01, "word": " إلى", "probability": 0.332275390625}, {"start": 2870.01, "end": 2870.49, "word": " اللقاء", "probability": 0.827880859375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2871.1475, "duration_after_vad": 2750.8587499999935}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E.srt
new file mode 100644
index 0000000000000000000000000000000000000000..15c65a8c91120044a5f3f02a57d33cb40eb2a436
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E.srt
@@ -0,0 +1,1479 @@
+
+1
+00:00:19,510 --> 00:00:24,470
+بسم الله الرحمن الرحيم المرة الماضية بدأنا في
+
+2
+00:00:24,470 --> 00:00:28,170
+موضوع ال lipids و ال detergents بشكل أساسي بدأنا
+
+3
+00:00:28,170 --> 00:00:33,130
+نتعرف على ال triglycerides و قلنا أن ال
+
+4
+00:00:33,130 --> 00:00:39,410
+triglycerides من شغلتين من إجليسرول اللي هو بيمثل
+
+5
+00:00:39,410 --> 00:00:44,310
+جزء ال alcohol و fatty acidواضح هدول لما بتحدوا مع
+
+6
+00:00:44,310 --> 00:00:49,490
+بعض بيعملوا عندنا إيش لـ triglycerides لو عملنا
+
+7
+00:00:49,490 --> 00:00:53,110
+hydrolysis تكسير لـ triglycerides ب Sodium
+
+8
+00:00:53,110 --> 00:00:58,650
+hydroxide بنحصل على إجليسرين و fatty acids الآن ال
+
+9
+00:00:58,650 --> 00:01:03,790
+fatty acids عرفناهم إنهم carboxylic acids عادية
+
+10
+00:01:03,790 --> 00:01:08,610
+يعني فيهم مجموعة COOH لكن السلسلة اللي موجودة فيهم
+
+11
+00:01:08,610 --> 00:01:15,130
+بشكل عامسلسلة طويلة و بذلك بيغلب عليهم جانب ال non
+
+12
+00:01:15,130 --> 00:01:21,410
+-polarity و بالتالي بيصيروا بيدوبوا في المذيبات
+
+13
+00:01:21,410 --> 00:01:27,910
+العضوية بشكل عامالان لو بدنا نتعرف اكتر على ال
+
+14
+00:01:27,910 --> 00:01:32,130
+fatty acids، بنقول ال fatty acids في منهم fatty
+
+15
+00:01:32,130 --> 00:01:37,850
+acids saturated، واضح؟ معنى saturated انه موجود
+
+16
+00:01:37,850 --> 00:01:41,330
+فيهم ولا double bond، مافيش فيهم double bonds، وفي
+
+17
+00:01:41,330 --> 00:01:45,670
+unsaturated فيهم double bond او اكتر، واضح؟ فيهم
+
+18
+00:01:45,670 --> 00:01:51,130
+double bond او اكترالان بشكل عام ال fatty acids
+
+19
+00:01:51,130 --> 00:01:55,630
+اللي موجودين في الزيوت و في الدهون بيكونوا عدد ال
+
+20
+00:01:55,630 --> 00:02:01,190
+carbons اللي فيهم عدد زوجييعني هتلاحظوا لما نتعرف
+
+21
+00:02:01,190 --> 00:02:08,450
+عليهم هنبدأ من 12، 14، 16، 18، 20، مش هنحكي عن 13،
+
+22
+00:02:08,450 --> 00:02:14,010
+مش هنحكي عن 15، واضح؟ هذا بيرجع حقيقة إلى فكرة
+
+23
+00:02:14,010 --> 00:02:17,630
+تحضيرهم في الجسم أنه هي فكرة مضاعفات اتنين، يعني
+
+24
+00:02:17,630 --> 00:02:21,870
+بيكون في عندى اتنينبيجيهم كمان اتنين بيصيروا اربعة
+
+25
+00:02:21,870 --> 00:02:24,730
+كمان اتنين بيصيروا ستة كمان اتنين بيصيروا تمانية
+
+26
+00:02:24,730 --> 00:02:29,050
+فزيادة اتنين اتنين اتنين ولذلك لو بدنا نقول انه
+
+27
+00:02:29,050 --> 00:02:33,530
+عدد ال carbons في ال fatty acids odd ولا even
+
+28
+00:02:33,530 --> 00:02:40,970
+الجواب even واضح؟الان المشهورين منهم .. المشهورين
+
+29
+00:02:40,970 --> 00:02:47,970
+منهم اللوريك أسد بنسميه اللي فيه اتناشر كاربون بعد
+
+30
+00:02:47,970 --> 00:02:54,670
+هيك ميريستك أسد اربعة عشر كاربون بالميتك أسد هذا
+
+31
+00:02:54,670 --> 00:03:00,210
+من البلم يعني زيت الاش النخيل بالميتك أسد ستة عشر
+
+32
+00:03:00,210 --> 00:03:07,250
+استيرك أسداللي هو حامض ضهني تمنتعش و arachidic
+
+33
+00:03:07,250 --> 00:03:12,830
+acid .. arachidic acid اللي هو إيش؟ عشرين يمكن لما
+
+34
+00:03:12,830 --> 00:03:19,110
+تسمعوا كلمة stearic تظل في مخكم تخربطلها مع كلمة
+
+35
+00:03:19,110 --> 00:03:27,970
+تانية مع حمض تاني citric acid مرات
+
+36
+00:03:27,970 --> 00:03:32,320
+اللي ..اللي بيكون مش متعود ع الكلام بيخلطوا
+
+37
+00:03:32,320 --> 00:03:36,720
+الكلمتين citric استيرك بيصير خربطهم citric acid
+
+38
+00:03:36,720 --> 00:03:45,100
+حمض اللمون حمض اللمون و citronel لمون واضح؟ الآن
+
+39
+00:03:45,100 --> 00:03:49,940
+استيرك حمض دهني ال citric acid حامض تاني بشكل معين
+
+40
+00:03:49,940 --> 00:03:54,500
+فيه تلت مجموعات carboxylic acids مش موضوعنا فلما
+
+41
+00:03:54,500 --> 00:04:00,350
+نقول citric غير عنstearic ولذلك انتوا لما تكونوا
+
+42
+00:04:00,350 --> 00:04:05,110
+تقرأوا المكونات ضالكوا ميزوا عن الشغلتين عن بعض
+
+43
+00:04:05,110 --> 00:04:12,250
+يعني لو بتقرأوا مثلا في مادة أخذية على سبيل المثال
+
+44
+00:04:12,250 --> 00:04:18,710
+مع شوية drops للزور لإشي زي هيك يمكن تلاقوا citric
+
+45
+00:04:18,710 --> 00:04:24,570
+acid حمض لمون لكن لو بتقرأوا في شامبوهات وغيرها
+
+46
+00:04:24,570 --> 00:04:30,350
+وغيراتها يمكن تلاقوا stearicفستيرك شيء وستريك شيء
+
+47
+00:04:30,350 --> 00:04:35,190
+الاستيرك أسد is a fatty is a saturated fatty acid
+
+48
+00:04:35,190 --> 00:04:40,550
+in fact containing 18 carbon atoms واضح الفكرة
+
+49
+00:04:40,550 --> 00:04:45,890
+الان لاحظوا لو اطلعتوا على ال melting point لهذه
+
+50
+00:04:45,890 --> 00:04:50,190
+المركبات اربعة واربعين تمانية وخمسين تلاتة وستين
+
+51
+00:04:50,190 --> 00:04:55,170
+يعني كلهم ايش solids in principle الان لو انتقلنا
+
+52
+00:04:55,170 --> 00:05:01,440
+علىالـ unsaturated acids اللي فيهم double bonds
+
+53
+00:05:01,440 --> 00:05:06,360
+لاحظوا لو اجينا في عندي double bond واحدة بتبدأ
+
+54
+00:05:06,360 --> 00:05:11,060
+على الموقع تسعة على carbon تسعة بيصير الحامض اسمه
+
+55
+00:05:11,060 --> 00:05:18,380
+oleic acid الأن لو في عندي تنتين double bonds بعد
+
+56
+00:05:18,380 --> 00:05:23,750
+هيك لينوليك أسدلو في عندى تلاتة double bonds
+
+57
+00:05:23,750 --> 00:05:29,910
+لينولينيك لينولينيك لينولينيك لينولينيك لينولينيك
+
+58
+00:05:29,910 --> 00:05:34,630
+واضح هنا double bond واحدة تلتين تلاتة
+
+59
+00:05:36,580 --> 00:05:40,760
+بالنظر إلى ال melting point لهدول المركبات لاحظوا
+
+60
+00:05:40,760 --> 00:05:44,700
+معايا اللي فيه .. اللي فيش فيه double bond يعني
+
+61
+00:05:44,700 --> 00:05:50,460
+هدول كلهم 18 carbon atom 18 .. 18 .. 18 .. و ال
+
+62
+00:05:50,460 --> 00:05:53,640
+stearic 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+63
+00:05:53,640 --> 00:05:55,780
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+64
+00:05:55,780 --> 00:05:58,060
+.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+65
+00:05:58,060 --> 00:06:01,660
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+66
+00:06:01,660 --> 00:06:04,200
+.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+67
+00:06:04,200 --> 00:06:06,040
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+68
+00:06:06,040 --> 00:06:06,200
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+69
+00:06:06,710 --> 00:06:12,510
+إذا خلصنا من السؤال كل ما زاد كلهم تمنتعش الآن
+
+70
+00:06:12,510 --> 00:06:18,390
+لاحظوا معاه هنا مافيش عندي double points بعد هيك
+
+71
+00:06:18,390 --> 00:06:23,590
+كانت ال melting point سبعين بعدك صار عندي one
+
+72
+00:06:23,590 --> 00:06:28,720
+double point نزلتلتلت عشر صار عندى تنتين double
+
+73
+00:06:28,720 --> 00:06:33,340
+points نزلت لناقص خمسة صار عندى تلاتة double
+
+74
+00:06:33,340 --> 00:06:39,320
+points نزلت لأكم لناقص احد عشر اذا بنقدر احنا
+
+75
+00:06:39,320 --> 00:06:45,180
+نستنتج انه كل ما بيزيدوا ال double points او as
+
+76
+00:06:45,180 --> 00:06:49,180
+the unsaturation increases يعني كل ما بيزيد عدم
+
+77
+00:06:49,180 --> 00:06:55,720
+التشبع ال melting point بتصير اقلكل ما بيزيد عدم
+
+78
+00:06:55,720 --> 00:06:59,920
+التشبع كل ما ال melting point لل fatty acid بتصير
+
+79
+00:06:59,920 --> 00:07:05,940
+ايش اقل طبعا هذا الكلام بحاجة الى تفسير ليش ال
+
+80
+00:07:05,940 --> 00:07:09,900
+saturated fatty acids in general اللي هو ال
+
+81
+00:07:09,900 --> 00:07:14,060
+melting point عالية ال unsaturated منخفضة لاحظوا
+
+82
+00:07:14,060 --> 00:07:17,960
+هنا السبعين معناه على حرارة الغرفة تبعتنا احنا
+
+83
+00:07:17,960 --> 00:07:22,740
+معدل حرارة الغرفة خمسة وعشرين تلاتين solidالان
+
+84
+00:07:22,740 --> 00:07:28,960
+التلتعش في الجو تبعنا اليوم هيكون سائل لأن الحرارة
+
+85
+00:07:28,960 --> 00:07:32,580
+خمسة و عشرين عندنا فهو لما بنصار عن التلتعش إن أنا
+
+86
+00:07:32,580 --> 00:07:36,180
+سائل، إن ناقص خمسة أكيد سائل، إن ناقص إحد أش سائل،
+
+87
+00:07:36,180 --> 00:07:40,640
+يعني كأنه بنقدر ناخد معلومة جديدة إن ال
+
+88
+00:07:40,640 --> 00:07:48,350
+unsaturated they are liquidsيعني انسهار أو انخفاض
+
+89
+00:07:48,350 --> 00:07:51,630
+نقطة الانسهار تبعهم تخلهم liquids ال saturated
+
+90
+00:07:51,630 --> 00:07:59,770
+they are solids الاناذي
+
+91
+00:07:59,770 --> 00:08:05,690
+القصة جديرة ان نكون احنا متوقفين عندها خلينا ناخد
+
+92
+00:08:05,690 --> 00:08:10,920
+اذا شوية معلومات تساعدنا نفسر هذا الكلامأول اشي
+
+93
+00:08:10,920 --> 00:08:14,600
+most fatty acids are unbranched يعني ال fatty
+
+94
+00:08:14,600 --> 00:08:19,080
+acids سلاسل غير متفرعة سلسلة طويلة واضحة مافيها
+
+95
+00:08:19,080 --> 00:08:24,690
+branchingand contain an even number of carbon
+
+96
+00:08:24,690 --> 00:08:29,890
+atoms فيهم عدد ال carbon atoms عدد إيش زوجة الان
+
+97
+00:08:29,890 --> 00:08:34,010
+ال unsaturated acids أول ما أبدأ أقول double bond
+
+98
+00:08:34,010 --> 00:08:39,410
+كلمة ال double bond ارتبطت الذهن بcis و trans او z
+
+99
+00:08:39,410 --> 00:08:46,090
+و e اه unsaturated acids usually have the cis or z
+
+100
+00:08:46,090 --> 00:08:50,720
+configurationالـ Unsaturated بيكون ال
+
+101
+00:08:50,720 --> 00:08:56,020
+configuration فيهم إيش زد يعني ال .. ال أتشز بيجوا
+
+102
+00:08:56,020 --> 00:09:01,420
+على جهة و ال carbons على جهة التانية الآن they
+
+103
+00:09:01,420 --> 00:09:03,720
+have lower boiling points than the corresponding
+
+104
+00:09:03,720 --> 00:09:08,260
+saturated ones شوفنا من خلال القيم أن ال
+
+105
+00:09:08,260 --> 00:09:13,860
+unsaturated نقاط الانسهار بتاعتهم أقل من إيش أقل
+
+106
+00:09:13,860 --> 00:09:17,060
+من ال saturated ممتاز
+
+107
+00:09:20,030 --> 00:09:24,490
+الان بنجي للسؤال الأول ليش هدولة solids والتانين
+
+108
+00:09:24,490 --> 00:09:31,420
+liquids اتطلعوا معايا لو اتخيلت انا هذا شكللـ
+
+109
+00:09:31,420 --> 00:09:35,200
+triglycerides يعني هذا الجزء الجليسرين و هذا الاشي
+
+110
+00:09:35,200 --> 00:09:39,720
+الزهري هو ال oxygen و بعد هيك في عندي تلت سلاسل
+
+111
+00:09:39,720 --> 00:09:45,560
+طويلة سلسلة تنتين تلاتة الان هذه السلاسل لما تكون
+
+112
+00:09:45,560 --> 00:09:50,340
+مشبعة لما تكون مشبعة بشكل عام بنتخيلها بهذا الشكل
+
+113
+00:09:50,340 --> 00:09:55,820
+المستقيم الان لاحظوا كيف شكل المركب هو شكل منتظم
+
+114
+00:09:56,070 --> 00:10:01,290
+قالم المركب الشكل تبعه منتظم معناه ذلك ان الجزيئات
+
+115
+00:10:01,290 --> 00:10:05,930
+بتيجي فوق بعضها بشكل جيد تترتب فوق بعضها في الحالة
+
+116
+00:10:05,930 --> 00:10:10,450
+الصلبة وهذا اللي بيخليها تكون ايه اش solids الان
+
+117
+00:10:10,450 --> 00:10:16,410
+لو فقط واحدة من هدولة صار فيها double bond يعني لو
+
+118
+00:10:16,410 --> 00:10:20,790
+كان عندى ال triglycerides مديش اقول التلاتة فيهم
+
+119
+00:10:20,790 --> 00:10:23,670
+double bonds خليني اقول هذه saturated و هذه
+
+120
+00:10:23,670 --> 00:10:28,530
+saturated واحدة بسقولت يكون فيها double bond و ال
+
+121
+00:10:28,530 --> 00:10:31,550
+double bond اللي بده تكون فيها إيش بده تكون sis
+
+122
+00:10:31,550 --> 00:10:35,990
+هتصير بهذا الشكل اتطلع من عندها هاي ال sis اللي
+
+123
+00:10:35,990 --> 00:10:40,750
+موجود فيها هاي ال double bond و هذا الجزء هاي أنا
+
+124
+00:10:40,750 --> 00:10:45,690
+carbon و أنا carbon على نفس الجهة هذا الشكل عمل
+
+125
+00:10:45,690 --> 00:10:53,030
+إيش فيها انتناقةواضح؟ الآن هذا الانفناق حافظ على
+
+126
+00:10:53,030 --> 00:10:58,750
+الشكل المنتظم للجزيء ولا بطل الجزيء منتظم؟ بطل
+
+127
+00:10:58,750 --> 00:11:02,830
+الجزيء منتظم ولذلك لما تيجي الجزيقات بتنحط فوق بعض
+
+128
+00:11:02,830 --> 00:11:07,130
+في solid lattice في الشبكة عشان تكون المركب الصلب
+
+129
+00:11:07,130 --> 00:11:11,450
+مابتبعدش فوق بعض جيدا، مابتكونش متراسة فوق بعض
+
+130
+00:11:11,450 --> 00:11:16,630
+البعض فالمادة بتحول إلى إيش؟ إلى liquid أو بتنخفض
+
+131
+00:11:16,630 --> 00:11:23,240
+نقاط انصحارهاولذلك هنا احنا انا شفنا ال space
+
+132
+00:11:23,240 --> 00:11:26,860
+filling and schematic model of glycerol التسمية
+
+133
+00:11:26,860 --> 00:11:30,380
+بناخدها tri-palmitate هذا من ال palmitic acid يعني
+
+134
+00:11:30,380 --> 00:11:35,380
+كام كربون؟ 16 اللي متذكرين هذا المشبع ايش ماله؟
+
+135
+00:11:35,380 --> 00:11:41,520
+كان regular كان منتظم بينما لاحظوا معي هنا هذا
+
+136
+00:11:41,520 --> 00:11:46,680
+اللي فيه بس واحدغير مشبع، في double bond، راح
+
+137
+00:11:46,680 --> 00:11:50,220
+الانتظام، الآن اتخيلوا انه لو اكثر من واحد في
+
+138
+00:11:50,220 --> 00:11:53,480
+double bonds، اتخيل لو هذا فيه اكثر من double
+
+139
+00:11:53,480 --> 00:11:58,200
+bond، وكل double bond فيهم صار أشبه بإيش؟
+
+140
+00:12:00,430 --> 00:12:05,610
+لأ صار أشبه حقيقة .. صار أشبه حقيقة بالفكرة اللي
+
+141
+00:12:05,610 --> 00:12:11,730
+أخدناها لما درسنا ال ال can's ال chain ال can's و
+
+142
+00:12:11,730 --> 00:12:15,610
+ال branch ال can's و قولنا أن ال chain they have
+
+143
+00:12:15,610 --> 00:12:20,810
+higherboiling point و melting point than ال branch
+
+144
+00:12:20,810 --> 00:12:25,610
+ليش؟ لأن ال branch أصبح شكلهم زي إيش؟ زي الكرة
+
+145
+00:12:25,610 --> 00:12:30,510
+بطلوا منتظمين فوق بعضهم البعض، واضح؟ لما أخدنا
+
+146
+00:12:30,510 --> 00:12:33,510
+قولنا مين، إله ال boiling point أعلى، ال chain ولا
+
+147
+00:12:33,510 --> 00:12:39,770
+ال branch؟لأن ال branch بطل شكله منتظم الفكرة
+
+148
+00:12:39,770 --> 00:12:43,890
+بالانتظام، الآن هذا اللي في double bonds نفس
+
+149
+00:12:43,890 --> 00:12:48,250
+الفكرة زي ال branch، يعني لاحظوا أنه لو كان هنا في
+
+150
+00:12:48,250 --> 00:12:52,990
+branch مش هتعمل هيك وتقضي على الانتظام اللي كان
+
+151
+00:12:52,990 --> 00:12:59,180
+موجود، الآن هذا الكلام اللي عملته double bondفال
+
+152
+00:12:59,180 --> 00:13:03,560
+branching بيقضي على الانتظام ووجود ال cyst double
+
+153
+00:13:03,560 --> 00:13:07,240
+bond بهذا الشكل ايضا قضى على الانتظام فالفكرة
+
+154
+00:13:07,240 --> 00:13:12,780
+العامة في الحالتين لما نقول ان ال kids بشكل عام
+
+155
+00:13:12,780 --> 00:13:16,060
+انه ال branch they have lower boiling points and
+
+156
+00:13:16,060 --> 00:13:20,150
+melting points because they are irregularالان هنا
+
+157
+00:13:20,150 --> 00:13:24,550
+الـ triglycerides that contain unsaturated fatty
+
+158
+00:13:24,550 --> 00:13:27,470
+acids they have lower boiling point and melting
+
+159
+00:13:27,470 --> 00:13:31,990
+point because they are irregular من وين اجت ال
+
+160
+00:13:31,990 --> 00:13:36,330
+irregularity اللي فيهم، عدم الانتظام من وجود ال
+
+161
+00:13:36,330 --> 00:13:39,370
+double bond و ال cis configuration اللي موجود
+
+162
+00:13:39,370 --> 00:13:44,450
+فيها، واضح؟ الان هذا الكلام بيفرق عندي وين؟ بيفرق
+
+163
+00:13:44,450 --> 00:13:49,870
+عندي وين؟ال oil however are liquid بيصير في عندى
+
+164
+00:13:49,870 --> 00:13:56,350
+اشي اسمه بالمطبخ خلينا نقول شغلتين بيصير في عندكم
+
+165
+00:13:56,350 --> 00:14:01,010
+زيت، زيت الجلي، زيت عباد الشمس، زيت الصوية اللي
+
+166
+00:14:01,010 --> 00:14:06,290
+بتسموه searage، هذا liquid و بيصير في عندكم صلب،
+
+167
+00:14:06,290 --> 00:14:11,260
+السمنة والزبدةملاحظين انتوا هدولة ماشي بيفرجوا
+
+168
+00:14:11,260 --> 00:14:17,240
+ببعض، السمنة والزبدة saturated،
+
+169
+00:14:17,240 --> 00:14:21,650
+الزيت اللي فيه ال double bondsالزيت اللي فيه ال
+
+170
+00:14:21,650 --> 00:14:25,130
+double bonds عشان هيك صار liquid, oils however are
+
+171
+00:14:25,130 --> 00:14:32,190
+liquids because they contain lower percentage of
+
+172
+00:14:32,190 --> 00:14:35,230
+unsaturated .. higher percentage عفوا .. higher
+
+173
+00:14:35,230 --> 00:14:38,490
+percentage of unsaturated fatty acids إذا لو
+
+174
+00:14:38,490 --> 00:14:43,310
+بيناقول مين اللي فيه ال double bonds؟ ال oil ولا
+
+175
+00:14:43,310 --> 00:14:48,010
+ال fat؟ السمنة والزبدة بيناقول عنهم fatsالزيت
+
+176
+00:14:
+
+223
+00:18:46,130 --> 00:18:50,350
+الإنسان طبعا هياخد مع الأشياء المجلية زيوت كمان و
+
+224
+00:18:50,350 --> 00:18:56,550
+هذه الأشياء fatty acids، انتبهوا معي، fatty acids
+
+225
+00:18:56,550 --> 00:19:03,430
+with trans bonds are carcinogenic، مسارتمينو لذلك
+
+226
+00:19:03,430 --> 00:19:08,350
+يعني اكثر من مرة و تانية ما اتجربوش تجلو انما انه
+
+227
+00:19:08,350 --> 00:19:13,910
+الزيت بينجل فيه ايام و ليالي كل هذا الكلام يعتبر
+
+228
+00:19:13,910 --> 00:19:18,430
+كلام إيش خاطر الآن لاحظوا معاك انه برضه عملية
+
+229
+00:19:18,430 --> 00:19:26,120
+الهدرجة برضه عملية الهدرجة عملية كيميائية بنحول
+
+230
+00:19:26,120 --> 00:19:32,420
+فيها احنا نسبة كبيرة من ال double bonds إلى single
+
+231
+00:19:32,420 --> 00:19:36,140
+bonds يعني جاعدين احنا نحول double bond إلى single
+
+232
+00:19:36,140 --> 00:19:39,800
+bond هذه ال double bond اللي احنا بنحولها sis ولا
+
+233
+00:19:39,800 --> 00:19:44,680
+trans؟ sisالان هذه ال هدرجة لما بنحكي عن زيت مش زي
+
+234
+00:19:44,680 --> 00:19:49,440
+مركب كيميائي يعني مش عملية سهلة عادة ما بتتمش على
+
+235
+00:19:49,440 --> 00:19:53,840
+كل ال double bonds لكن بتعمل نسبة كبيرة منهم واضحة
+
+236
+00:19:53,840 --> 00:19:59,820
+الفكرة؟ الان في هذه الأثناء بعض ال six double
+
+237
+00:19:59,820 --> 00:20:03,000
+bonds بيظلهم six يعني ما بيصلهمش الدور انهم ايش
+
+238
+00:20:03,000 --> 00:20:08,240
+انه يصيرلهم هدرجة وبعض ال six منهم بتتحولوا إلى
+
+239
+00:20:08,240 --> 00:20:16,060
+transوبالتالي بتصير الهدرجة أيضا عاملة مشكلة مش من
+
+240
+00:20:16,060 --> 00:20:20,040
+منطقة ان هي حولت ال double bond إلى single bond
+
+241
+00:20:20,040 --> 00:20:25,580
+يعني لو ان هي بشكل نظيف ودقيق ومتقن حولت ال double
+
+242
+00:20:25,580 --> 00:20:29,320
+bonds إلى single bonds يعني حولت الزيت إلى سمنة
+
+243
+00:20:29,320 --> 00:20:35,410
+مافيش مشكلةلكن المشكلة ان هذه الهدرجة غالبا بتكون
+
+244
+00:20:35,410 --> 00:20:40,410
+غير كاملة لحد معين بيضل شوية SIS BONS ونتيجة
+
+245
+00:20:40,410 --> 00:20:45,750
+التفاعل الكيميائي بعض ال SISBONS بيصيروا Trans
+
+246
+00:20:45,750 --> 00:20:54,780
+واضح؟ ولذلك اليومصار يعني في دول معينة يجبروا
+
+247
+00:20:54,780 --> 00:20:59,920
+الشركات المصنعة انه تعمل فحوصات و انه على نفس
+
+248
+00:20:59,920 --> 00:21:05,920
+الزبدة و على نفس السمنة تكتب جداش نسبة لترانس فيها
+
+249
+00:21:06,870 --> 00:21:10,710
+والمواطن لازم يعرف اقل تقدير انتوا الان كمتعلمين
+
+250
+00:21:10,710 --> 00:21:16,130
+انه كل ما نسبة لل Trans بتزيد كل ما المركب بيكون
+
+251
+00:21:16,130 --> 00:21:22,750
+ايش اخطر كل ما المركب بيكون carcinogenic واضح؟
+
+252
+00:21:22,750 --> 00:21:30,570
+الان بنيجي لكيف يا ترى بنسمي ال triglycerides
+
+253
+00:21:30,570 --> 00:21:37,170
+خلينا ننتبه لشغلةإنهم لـ triglycerides عبارة عن
+
+254
+00:21:37,170 --> 00:21:44,870
+glycerol صح؟ حامل كام fatty acid؟ تلاتة، الآن لـ
+
+255
+00:21:44,870 --> 00:21:49,570
+triglycerides نوعين،
+
+256
+00:21:49,570 --> 00:21:53,790
+ع طول، أي واحدة بتقدر تقولي شو النوعين، انتظر،
+
+257
+00:21:53,790 --> 00:21:59,250
+ممكن يكونوا متماثلين، يعني فيهم نفس ال fatty acid
+
+258
+00:22:00,450 --> 00:22:04,870
+واضح؟ يعني اربعتاش اربعتاش اربعتاش مشبه او ستاش
+
+259
+00:22:04,870 --> 00:22:10,890
+ستاش ستاش مشبه وممكن يكونوا غير متماثلين صارت
+
+260
+00:22:10,890 --> 00:22:13,830
+الأفكار شبيهة بأشياء أخدتها زي لما أخدنا ال ether
+
+261
+00:22:13,830 --> 00:22:18,250
+متماثل وغير متماثل زي ما أخدنا ال anhydride متماثل
+
+262
+00:22:18,250 --> 00:22:22,650
+وغير متماثل كمان ال triglycerides ممكن يكونوا
+
+263
+00:22:23,260 --> 00:22:28,120
+Simple يعني متماثلين أو Mixed Mixed يعني مخلطين
+
+264
+00:22:28,120 --> 00:22:32,680
+يعني يكون هذا 16 هذا 18 هذا 18 فيه double bond
+
+265
+00:22:32,680 --> 00:22:40,160
+واضح؟ الآن أكيد لما بدنا نسمي لو كانوا متماثلين
+
+266
+00:22:40,160 --> 00:22:46,220
+هنذكر اسم الفاتئاسد لمرة واحدة و لو كانوا غير
+
+267
+00:22:46,220 --> 00:22:51,530
+متماثلين بدنا نذكر إيش؟الثلاث أسماء اللي موجودة مش
+
+268
+00:22:51,530 --> 00:22:55,890
+هذه لازم تكون الفكرة العامة الآن بشكل عام ك common
+
+269
+00:22:55,890 --> 00:23:01,070
+name وخلينا نبدأ بال common name للمتماثلين لو كان
+
+270
+00:23:01,070 --> 00:23:07,970
+ال fatty acid ال 12 اللي هو اللوريك أسد تمام بنسمي
+
+271
+00:23:07,970 --> 00:23:10,630
+المركب Trilaurin
+
+272
+00:23:13,300 --> 00:23:19,580
+واضح؟ إذا من ال acid lauryl بحط إيش؟ lauryl tri
+
+273
+00:23:19,580 --> 00:23:27,660
+-lauryl طيب لو كان stearic tri-stearic يعني لاحظوا
+
+274
+00:23:27,660 --> 00:23:35,300
+معي كان ال acid الأصلي lauryl لما عملت منه ال tri
+
+275
+00:23:35,300 --> 00:23:41,860
+-glyceride ضفت كلمة trialهذه إجت جديدة اللورك
+
+276
+00:23:41,860 --> 00:23:50,100
+خلّيت منها لور و حطيت لها إيش؟ حطيت لها in بدل اك
+
+277
+00:23:50,100 --> 00:23:58,260
+in ال try لورن طيب من ال steerك المتماثل try
+
+278
+00:23:58,260 --> 00:24:06,150
+steering من الأوليك المتماثل try أولينواضح؟
+
+279
+00:24:06,150 --> 00:24:10,870
+ترايقليا ولاحظوا على طول طبعا هيبين معاكم كيف
+
+280
+00:24:10,870 --> 00:24:14,890
+لتراي لاورين مثلا ال melting point له لأن كل ال
+
+281
+00:24:14,890 --> 00:24:20,510
+fatty acids تبعته مشبعة خمسة واربعين هذا
+
+282
+00:24:20,510 --> 00:24:27,490
+لترايستيرين واحد وسبعين الان لو سألت واحدة منكم لو
+
+283
+00:24:27,490 --> 00:24:31,650
+سألت واحدة منكم ليش لتراي لاورين خمسة واربعين و
+
+284
+00:24:31,650 --> 00:24:37,120
+لترايستيرين واحد وسبعينالسلسلة أطول، الموليكولا
+
+285
+00:24:37,120 --> 00:24:41,400
+رويت، الكلمتين صح، التنين مشبع، مشبع، بطل، التشبع
+
+286
+00:24:41,400 --> 00:24:47,300
+هو الفارق، فقط طول السلسلة، أه، لكن لما هنا أجيت
+
+287
+00:24:47,300 --> 00:24:53,430
+18 و 18و حطيت تلاتة double bonds يعني خصام ست
+
+288
+00:24:53,430 --> 00:24:56,410
+هيدروجينات مش المشكلة بفرق ال molecular weight
+
+289
+00:24:56,410 --> 00:25:00,290
+يعني ست وحدات في جزاء كبير زي هذا في ال molecular
+
+290
+00:25:00,290 --> 00:25:04,550
+weight ماسهمهم مش فرق لكن المشكلة حقيقة لما أنا
+
+291
+00:25:04,550 --> 00:25:11,450
+بنزل هذا 18 و هذا 18 قليل ال 18 في one double bond
+
+292
+00:25:11,450 --> 00:25:16,970
+لما بنزل من 71 ل 4 هذا مش فاتقش التغير في ال
+
+293
+00:25:16,970 --> 00:25:21,280
+molecular weightهذا نتيجة وجود ال double bonds،
+
+294
+00:25:21,280 --> 00:25:24,300
+ليش؟ لأن وجدت لو بدي أجي هنا، بدي أعمل هذه ال
+
+295
+00:25:24,300 --> 00:25:26,840
+double bonds زي هيك و زي هيك، بعدين هذه زي هيك و
+
+296
+00:25:26,840 --> 00:25:34,010
+زي هيك، بعدين هذه، صار إيش؟ زي الكرةالجزيق وجده
+
+297
+00:25:34,010 --> 00:25:39,090
+بده يصير زي كرة كيف بده يكون منتظم في solid state
+
+298
+00:25:39,090 --> 00:25:44,550
+واضح الفكرة فلما بده أقول ليش ال triolين لو بده
+
+299
+00:25:44,550 --> 00:25:49,710
+أجي أسألكم ال triolين have lower melting point
+
+300
+00:25:49,710 --> 00:25:54,770
+than tristerine because of the presence of the
+
+301
+00:25:54,770 --> 00:26:00,230
+double bonds or because it is unsaturated واضح
+
+302
+00:26:00,230 --> 00:26:05,250
+الفكرةو هذا وجود ال double bond أو ال unsaturation
+
+303
+00:26:05,250 --> 00:26:09,790
+خلّاه regular ولا irregular؟ irregular بطل منتظم
+
+304
+00:26:09,790 --> 00:26:14,070
+بطل زي .. زي حجار الطوب المنتظمة كيف بتصفق بعض
+
+305
+00:26:14,070 --> 00:26:18,870
+بشكل قوى بينما حجار مش منتظمة بتضل إيش؟ توجع أو
+
+306
+00:26:18,870 --> 00:26:26,600
+ألعاب الأطفال اللي بيسموها ال Legoالان موضوع
+
+307
+00:26:26,600 --> 00:26:30,780
+الهيدروجينيشن of vegetable oils حكينا قولنا ان
+
+308
+00:26:30,780 --> 00:26:36,420
+احنا ممكن ناخد ال oil ويصير زبدة او سمنة
+
+309
+00:26:36,420 --> 00:26:40,120
+بالهيدروجينيشن تحويل ال double bond الى single
+
+310
+00:26:40,120 --> 00:26:42,780
+bond هذا الكلام برفع ال melting point بيحول ال
+
+311
+00:26:42,780 --> 00:26:47,380
+liquid الى solid الهيدروجينيشن عادة بتنفي وجود
+
+312
+00:26:47,380 --> 00:26:52,360
+الهيدروجين و نكلكتاليست و heat لكن هناك خطورة
+
+313
+00:26:52,360 --> 00:26:54,420
+مصاحبة للهيدروجينيشن
+
+314
+00:26:56,690 --> 00:27:02,110
+تحويل بعض ال sis bonds إلى trans يعني التحويل من
+
+315
+00:27:02,110 --> 00:27:05,630
+sis إلى saturated أو من double bond إلى saturated
+
+316
+00:27:05,630 --> 00:27:10,750
+هذا مافيش فيه مشكلة لكن كتفاعل جانبي بعض ال sis
+
+317
+00:27:10,750 --> 00:27:15,450
+بصير trans هنا توجد المشكلة
+
+318
+00:27:16,590 --> 00:27:21,350
+الان مرة تانية نرجع لل simple and mixed
+
+319
+00:27:21,350 --> 00:27:25,210
+triglycerides اللي هي المتماثلة و غير المتماثلة
+
+320
+00:27:25,210 --> 00:27:32,490
+اتفقنا احنا ان المتماثل بنعطي اسم common name
+
+321
+00:27:32,490 --> 00:27:38,470
+trystyrian يعني هذا 18 اذا ايش الحامض تبعه؟ Styric
+
+322
+00:27:38,470 --> 00:27:44,190
+Styric Styric فالمركب trystyrian طيب لو كنا بنسمي
+
+323
+00:27:44,190 --> 00:27:51,210
+ايوبكيعني Triglycerides is a common name و أنا
+
+324
+00:27:51,210 --> 00:27:55,470
+مرات بجيبلكوا سؤال في الامتحان .. بجيبلكوا سؤال في
+
+325
+00:27:55,470 --> 00:28:00,810
+الامتحان ال Triglycerides is also called .. or the
+
+326
+00:28:00,810 --> 00:28:06,830
+Ayurvedic name of Triglycerides is .. الآن عشان
+
+327
+00:28:06,830 --> 00:28:11,650
+نجاوبه صح احنا قولنا ال Triglycerides they are
+
+328
+00:28:11,650 --> 00:28:18,550
+Easter'sEaster صح ولا لأ؟ كيف أنا كنت أسمي ال
+
+329
+00:28:18,550 --> 00:28:22,970
+Easter؟ خليني أتذكر كيف أنا كنت أسمي ال Easter،
+
+330
+00:28:22,970 --> 00:28:29,370
+هيني بدي أكتب Easter عشان واحدة تذكرني كيف،
+
+331
+00:28:29,370 --> 00:28:32,690
+هاي Easter، شايفينه اللي على اللوح؟ واحدة تسميه
+
+332
+00:28:32,690 --> 00:28:37,370
+جزء الكحول في الأول
+
+333
+00:28:40,150 --> 00:28:49,150
+مثل هاي جزء الكحول وبعدين جزء الحامض انتوا بتكونوا
+
+334
+00:28:49,150 --> 00:28:52,910
+شايفوني ومن جلة دراستكوا بنزويك أسد ال Easter
+
+335
+00:28:52,910 --> 00:28:58,130
+بنتهي بنزويت مثل بنزويت أسيتات بيوتانويت اه هذا
+
+336
+00:28:58,130 --> 00:29:04,970
+مثل ايش؟ بنزويت اذا تسمية ال Easterلعبوا لو أنكوا
+
+337
+00:29:04,970 --> 00:29:09,030
+بتحاولوا تحفظوا الكيميا كرموز بتتغلبوا لو أنكوا
+
+338
+00:29:09,030 --> 00:29:13,310
+حفظتوا الكيميا أنه تسمية ال Easter مجموعة الكحول
+
+339
+00:29:13,310 --> 00:29:18,690
+في الأول بعدين ال acid منتهي ب إيه؟ إثل أستيت مثل
+
+340
+00:29:18,690 --> 00:29:24,730
+بنزويت فين ال بيوتانويت صح ولا لأ؟ طيب الآن كويس
+
+341
+00:29:24,730 --> 00:29:31,770
+لو إجيت على هذا شو هو جزء الكحول فيه؟ ال glycerin
+
+342
+00:29:32,770 --> 00:29:38,250
+وشو الأحمض؟ الاستيرك أسد مش هذا الحامض و هذا
+
+343
+00:29:38,250 --> 00:29:44,590
+الكحول ولا لأ ايش اول اشي بنذكره؟ جزء الكحول
+
+344
+00:29:44,590 --> 00:29:53,350
+إجليسارين إجليساريل و الاستيرك أسدStraight لكن لأن
+
+345
+00:29:53,350 --> 00:29:58,330
+في عندي منه تلاتة بقول glycerol ال try straight
+
+346
+00:29:58,330 --> 00:30:03,290
+إذا أنا نفس المنطقة ده اسمها ال Easter الكحول في
+
+347
+00:30:03,290 --> 00:30:09,070
+الأول و بعدين النهاية eight و حطيت try لأن عندي كم
+
+348
+00:30:09,070 --> 00:30:16,160
+حامض تلاتةإذا هذا هي جزء الكحول اللي فيه في واحدة
+
+349
+00:30:16,160 --> 00:30:19,140
+منكم مالخومة كتير عشان الكحول مرسوم على اليمين مش
+
+350
+00:30:19,140 --> 00:30:22,660
+على الشمال المهم نذكر الكحول في الأول كيف نرسمه مش
+
+351
+00:30:22,660 --> 00:30:28,360
+مشكلة واضحة الفكرة ولا لأ؟ واضحات؟ يعني هذا لو كنت
+
+352
+00:30:28,360 --> 00:30:35,540
+راسمه بالعكس إيش برضه هسميه؟ واضح؟ شايف هي كناس
+
+353
+00:30:35,540 --> 00:30:40,360
+مرات بهمش بيغرجوا بشبهر ميه؟
+
+354
+00:30:43,590 --> 00:30:46,990
+يعني اتعودتوا انتوا انه هذا نعمله زي هيك او يبدو
+
+355
+00:30:46,990 --> 00:30:53,130
+معكوس لان لما يرسم زي هيك وين جزء الكحول مثل وين
+
+356
+00:30:53,130 --> 00:30:57,250
+جزء الاسد مثل بنزويت مثل بنزويت خلاص يعني الفكرة
+
+357
+00:30:57,250 --> 00:31:01,950
+مش انه بدهم يبينوا هدولة معكوسين دائما لأ لأ مش
+
+358
+00:31:01,950 --> 00:31:06,890
+هذه الفكرة حسب طريقة الرسم يذكر جزء الكحول اولا ثم
+
+359
+00:31:06,890 --> 00:31:10,770
+جزء الحامض منتهي بالنهاية ايه ولذلك هذا هيك ايش
+
+360
+00:31:10,770 --> 00:31:14,780
+بدنا نسميهمثل؟ بنزوية
+
+361
+00:31:18,100 --> 00:31:22,640
+أكيد اكيد طبعا اه ليش مايجيكيش ارسمي نفسي كل هذان
+
+362
+00:31:22,640 --> 00:31:27,800
+الكربونات بترسم ترسم شو وراكم انتوا دافعين رسوم
+
+363
+00:31:27,800 --> 00:31:32,760
+بتكونوا بتتعلموا واضح تسمية ال easter تسمية ال
+
+364
+00:31:32,760 --> 00:31:37,840
+easter ببساطة انه تذكروا جزء الكحول بعدين جزء
+
+365
+00:31:37,840 --> 00:31:42,400
+الحامض المساهي بالنهاية ايش ات فهذا صار glycerol
+
+366
+00:31:42,400 --> 00:31:50,100
+tryStirate هذه فهمناها طيب لو كانوا الأحماض الآن
+
+367
+00:31:50,100 --> 00:31:56,200
+مختلفين يعني صار عنده اللي أنا بسميه إيش mixed
+
+368
+00:31:56,200 --> 00:32:02,760
+triglyceride مرة تانية هحط في الأول جزء الكحول إذا
+
+369
+00:32:02,760 --> 00:32:09,450
+هنا هذا الجزء الكحول هي الجزء اللي جاي من الكحولمش
+
+370
+00:32:09,450 --> 00:32:16,310
+بختلف عليه، الآن الأحماض بدي أذكرهم مرتبين، واحد،
+
+371
+00:32:16,310 --> 00:32:20,950
+اتنين، تلاتة، طبعا هتقولولي إذا عرفنا واحد، بعده
+
+372
+00:32:20,950 --> 00:32:24,270
+بنقول اتنين، تلاتة، يمكن تصير المشكلة عندكم أن هذا
+
+373
+00:32:24,270 --> 00:32:28,730
+واحد، بعدين اتنين، تلاتة، ولا هذا واحد، بعدين
+
+374
+00:32:28,730 --> 00:32:33,800
+اتنين، تلاتةواضح؟ يعني المشكلة أن أذكر واحد، بعد
+
+375
+00:32:33,800 --> 00:32:38,020
+ما أذكر واحد لازم أمشي فيهم إيش، امرتبين، الآن
+
+376
+00:32:38,020 --> 00:32:44,760
+ببساطة بنقول الأصغر والأكثر تشبعا هو اللي بنحطه
+
+377
+00:32:44,760 --> 00:32:49,940
+نمرة واحد يعني لما أنا بدأ أختار وين نمرة واحد،
+
+378
+00:32:49,940 --> 00:32:54,960
+بدأ أختار الأصغر منهم والأكثر تشبعايعني لو لجيت
+
+379
+00:32:54,960 --> 00:32:58,980
+هنا ستة عشر وهنا تمانت عشر مشبعين التنين مين بدي
+
+380
+00:32:58,980 --> 00:33:05,540
+أحطهم؟ ستة عشر الان لو لجيت هنا ستة عشر وهنا تمانت
+
+381
+00:33:05,540 --> 00:33:11,280
+عشر وكمان هذا مشبع الستة عشر الآن بعد ما أحط الستة
+
+382
+00:33:11,280 --> 00:33:16,280
+عشر مامشي فيهم بالترتيب واضح؟ ولذلك هدولة لو انا
+
+383
+00:33:16,280 --> 00:33:22,470
+اجيت اطلعت الستة عشر بال methic acidالـ 18 المشبع
+
+384
+00:33:22,470 --> 00:33:27,790
+استيرك الـ 18 اللي فيه double bond أوليك لما أنا
+
+385
+00:33:27,790 --> 00:33:32,150
+بدي أسميهم بقول glycerin بعدين بجعل بالميتو
+
+386
+00:33:32,150 --> 00:33:38,510
+بالميتو بعدين الاستيرك استيره بعدين على الأوليك
+
+387
+00:33:38,510 --> 00:33:45,490
+أولييت بحط ات في النهاية لاحظوا معي أن الأوليك أن
+
+388
+00:33:45,490 --> 00:33:46,390
+الأوليك
+
+389
+00:33:50,390 --> 00:33:58,870
+الـ O تبعته عليها إيش؟ نجوطين طبعا على الكمبيوتر
+
+390
+00:33:58,870 --> 00:34:03,230
+ممكن تلاقوا الـ O اللي عليها نجوطين و ممكن أنه
+
+391
+00:34:03,230 --> 00:34:06,430
+ماتلاقوهاش، الآن لو مالاجيتوهاش الـ O اللي عليها
+
+392
+00:34:06,430 --> 00:34:08,870
+نجوطين اكتبوها إيش؟
+
+393
+00:34:10,720 --> 00:34:17,820
+والفظوها OE فهي O ممالة إلى الكسر يعني بمنطق
+
+394
+00:34:17,820 --> 00:34
+
+445
+00:38:44,950 --> 00:38:48,350
+بالميتو ستيرو أوليات، التاني glycerol ستيرو
+
+446
+00:38:48,350 --> 00:38:51,150
+بالميتو أوليات، الآن هذول أخدوا different names
+
+447
+00:38:51,150 --> 00:38:54,230
+ولا لأ؟ طالما different names، إذا they are
+
+448
+00:38:54,230 --> 00:38:59,470
+structural isomers، ال stereo isomers كانوا ياخدوا
+
+449
+00:38:59,470 --> 00:39:05,780
+نفس الاسميفرقوا بس في البادقة في الانانشو مارز R
+
+450
+00:39:05,780 --> 00:39:11,680
+ولا S ولا كذا وفي الدياستيريو مارز S أو Trans أو Z
+
+451
+00:39:11,680 --> 00:39:16,340
+أو E same name وكانوا ياخدوا different descriptive
+
+452
+00:39:16,340 --> 00:39:20,680
+البادقة اللي بتوصف الشكل الفراغي مش سميناها
+
+453
+00:39:20,680 --> 00:39:25,520
+descriptive البادقة ال R أو ال S أو ال Z أو ال E
+
+454
+00:39:25,520 --> 00:39:30,460
+أو ال S أو ال Trans لكن إلهم نفس الاش نفس الإسم
+
+455
+00:39:31,530 --> 00:39:35,470
+الان لاحظوا معاه لو قلنا لكم draw this structure
+
+456
+00:39:35,470 --> 00:39:41,210
+for glyceryl trimeristate اللي هو meristic acid ال
+
+457
+00:39:41,210 --> 00:39:48,210
+14 موجود عندكم بدكوا تحطوهربما من الأخطاء اللي
+
+458
+00:39:48,210 --> 00:39:50,450
+كتير الطلاب بيخطئوها
+
+459
+00:40:19,820 --> 00:40:23,880
+تطلعوا كيف الشكل الصحيح ال O هان هذا جزء الكحول
+
+460
+00:40:23,880 --> 00:40:29,400
+هذا جزء الحامض ال glycerin هو المتصل بال O العادية
+
+461
+00:40:29,400 --> 00:40:33,400
+single bond بعدين ال C double bond O مش العكس هذا
+
+462
+00:40:33,400 --> 00:40:36,340
+من الأخطاء الشائعة لما نقول للطلبة ارسمولنا
+
+463
+00:40:36,340 --> 00:40:41,640
+triglyceride بيروحوا بيرسموليا معكوس واضح؟
+
+464
+00:40:44,360 --> 00:40:49,780
+على أي حال، بهيك تقريبا بننهي اليوم بكرا إجازة عيد
+
+465
+00:40:49,780 --> 00:40:54,740
+العمال، ماعرفش وقتاش بيكون عيد الطلاب، عيدنا يوم
+
+466
+00:40:54,740 --> 00:40:57,280
+نجاحنا
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..568d9416148a87b1e6d5323b09df9fe822cdbac8
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E_postprocess.srt
@@ -0,0 +1,1864 @@
+1
+00:00:19,510 --> 00:00:24,470
+بسم الله الرحمن الرحيم المرة الماضية بدأنا في
+
+2
+00:00:24,470 --> 00:00:28,170
+موضوع ال libids و ال detergents بشكل أساسي بدأنا
+
+3
+00:00:28,170 --> 00:00:33,130
+نتعرف على ال triglycerides و قلنا أن ال
+
+4
+00:00:33,130 --> 00:00:39,410
+triglycerides من شغلتين من إجليسرول اللي هو بيمثل
+
+5
+00:00:39,410 --> 00:00:44,310
+جزء ال alcohol و fatty acidواضح هدول لما بتحدوا مع
+
+6
+00:00:44,310 --> 00:00:49,490
+بعض بيعملوا عندنا إيش لـ triglycerides لو عملنا
+
+7
+00:00:49,490 --> 00:00:53,110
+hydrolysis تكسير لـ triglycerides ب Sodium
+
+8
+00:00:53,110 --> 00:00:58,650
+hydroxide بنحصل على إجليسرين و fatty acids الآن ال
+
+9
+00:00:58,650 --> 00:01:03,790
+fatty acids عرفناهم إنهم carboxylic acids عادية
+
+10
+00:01:03,790 --> 00:01:08,610
+يعني فيهم مجموعة COOH لكن السلسلة اللي موجودة فيهم
+
+11
+00:01:08,610 --> 00:01:15,130
+بشكل عامسلسلة طويلة و بذلك بيغلب عليهم جانب ال non
+
+12
+00:01:15,130 --> 00:01:21,410
+-polarity و بالتالي بيصيروا بيدوبوا في المذيبات
+
+13
+00:01:21,410 --> 00:01:27,910
+العضوية بشكل عامالان لو بدنا نتعرف اكتر على ال
+
+14
+00:01:27,910 --> 00:01:32,130
+fatty acids، بنقول ال fatty acids في منهم fatty
+
+15
+00:01:32,130 --> 00:01:37,850
+acids saturated، واضح؟ معنى saturated انه موجود
+
+16
+00:01:37,850 --> 00:01:41,330
+فيهم ولا double bond، مافيش فيهم double bonds، وفي
+
+17
+00:01:41,330 --> 00:01:45,670
+unsaturated فيهم double bond او اكتر، واضح؟ فيهم
+
+18
+00:01:45,670 --> 00:01:51,130
+double bond او اكترالان بشكل عام ال fatty acids
+
+19
+00:01:51,130 --> 00:01:55,630
+اللي موجودين في الزيوت و في الدهون بيكونوا عدد ال
+
+20
+00:01:55,630 --> 00:02:01,190
+carbons اللي فيهم عدد زوجييعني هتلاحظوا لما نتعرف
+
+21
+00:02:01,190 --> 00:02:08,450
+عليهم هنبدأ من 12، 14، 16، 18، 20، مش هنحكي عن 13،
+
+22
+00:02:08,450 --> 00:02:14,010
+مش هنحكي عن 15، واضح؟ هذا بيرجع حقيقة إلى فكرة
+
+23
+00:02:14,010 --> 00:02:17,630
+تحضيرهم في الجسم أنه هي فكرة مضاعفات اتنين، يعني
+
+24
+00:02:17,630 --> 00:02:21,870
+بيكون في عندى اتنينبيجيهم كمان اتنين بيصيروا اربعة
+
+25
+00:02:21,870 --> 00:02:24,730
+كمان اتنين بيصيروا ستة كمان اتنين بيصيروا تمانية
+
+26
+00:02:24,730 --> 00:02:29,050
+فزيادة اتنين اتنين اتنين ولذلك لو بدنا نقول انه
+
+27
+00:02:29,050 --> 00:02:33,530
+عدد ال carbons في ال fatty acids odd ولا even
+
+28
+00:02:33,530 --> 00:02:40,970
+الجواب even واضح؟الان المشهورين منهم .. المشهورين
+
+29
+00:02:40,970 --> 00:02:47,970
+منهم اللوريك أسد بنسميه اللي فيه اتناشر كاربون بعد
+
+30
+00:02:47,970 --> 00:02:54,670
+هيك ميريستك أسد اربعة عشر كاربون بالميتك أسد هذا
+
+31
+00:02:54,670 --> 00:03:00,210
+من البلم يعني زيت الاش النخيل بالميتك أسد ستة عشر
+
+32
+00:03:00,210 --> 00:03:07,250
+استيرك أسداللي هو حامض ضهني تمنتعش و arachidic
+
+33
+00:03:07,250 --> 00:03:12,830
+acid .. arachidic acid اللي هو إيش؟ عشرين يمكن لما
+
+34
+00:03:12,830 --> 00:03:19,110
+تسمعوا كلمة stearic تظل في مخكم تخربطلها مع كلمة
+
+35
+00:03:19,110 --> 00:03:27,970
+تانية مع حمض تاني citric acid مرات
+
+36
+00:03:27,970 --> 00:03:32,320
+اللي ..اللي بيكون مش متعود ع الكلام بيخلطوا
+
+37
+00:03:32,320 --> 00:03:36,720
+الكلمتين citric استيرك بيصير خربطهم citric acid
+
+38
+00:03:36,720 --> 00:03:45,100
+حمض اللمون حمض اللمون و citronel لمون واضح؟ الآن
+
+39
+00:03:45,100 --> 00:03:49,940
+استيرك حمض دهني ال citric acid حامض تاني بشكل معين
+
+40
+00:03:49,940 --> 00:03:54,500
+فيه تلت مجموعات carboxylic acids مش موضوعنا فلما
+
+41
+00:03:54,500 --> 00:04:00,350
+نقول citric غير عنstearic ولذلك انتوا لما تكونوا
+
+42
+00:04:00,350 --> 00:04:05,110
+تقرأوا المكونات ضالكوا ميزوا عن الشغلتين عن بعض
+
+43
+00:04:05,110 --> 00:04:12,250
+يعني لو بتقرأوا مثلا في مادة أخذية على سبيل المثال
+
+44
+00:04:12,250 --> 00:04:18,710
+مع شوية drops للزور لإشي زي هيك يمكن تلاقوا citric
+
+45
+00:04:18,710 --> 00:04:24,570
+acid حمض لمون لكن لو بتقرأوا في شامبوهات وغيرها
+
+46
+00:04:24,570 --> 00:04:30,350
+وغيراتها يمكن تلاقوا stearicفستيرك شيء وستريك شيء
+
+47
+00:04:30,350 --> 00:04:35,190
+الاستيرك أسد is a fatty is a saturated fatty acid
+
+48
+00:04:35,190 --> 00:04:40,550
+in fact containing 18 carbon atoms واضح الفكرة
+
+49
+00:04:40,550 --> 00:04:45,890
+الان لاحظوا لو اطلعتوا على ال melting point لهذه
+
+50
+00:04:45,890 --> 00:04:50,190
+المركبات اربعة واربعين تمانية وخمسين تلاتة وستين
+
+51
+00:04:50,190 --> 00:04:55,170
+يعني كلهم ايش solids in principle الان لو انتقلنا
+
+52
+00:04:55,170 --> 00:05:01,440
+علىالـ unsaturated acids اللي فيهم double bonds
+
+53
+00:05:01,440 --> 00:05:06,360
+لاحظوا لو اجينا في عندي double bond واحدة بتبدأ
+
+54
+00:05:06,360 --> 00:05:11,060
+على الموقع تسعة على carbon تسعة بيصير الحامض اسمه
+
+55
+00:05:11,060 --> 00:05:18,380
+oleic acid الأن لو في عندي تنتين double bonds بعد
+
+56
+00:05:18,380 --> 00:05:23,750
+هيك لينوليك أسدلو في عندى تلاتة double bonds
+
+57
+00:05:23,750 --> 00:05:29,910
+لينولينيك لينولينيك لينولينيك لينولينيك لينولينيك
+
+58
+00:05:29,910 --> 00:05:34,630
+واضح هنا double bond واحدة تلتين تلاتة
+
+59
+00:05:36,580 --> 00:05:40,760
+بالنظر إلى ال melting point لهدول المركبات لاحظوا
+
+60
+00:05:40,760 --> 00:05:44,700
+معايا اللي فيه .. اللي فيش فيه double bond يعني
+
+61
+00:05:44,700 --> 00:05:50,460
+هدول كلهم 18 carbon atom 18 .. 18 .. 18 .. و ال
+
+62
+00:05:50,460 --> 00:05:53,640
+stearic 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+63
+00:05:53,640 --> 00:05:55,780
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+64
+00:05:55,780 --> 00:05:58,060
+.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+65
+00:05:58,060 --> 00:06:01,660
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+66
+00:06:01,660 --> 00:06:04,200
+.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+67
+00:06:04,200 --> 00:06:06,040
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+68
+00:06:06,040 --> 00:06:06,200
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+69
+00:06:06,710 --> 00:06:12,510
+إذا خلصنا من السؤال كل ما زاد كلهم تمنتعش الآن
+
+70
+00:06:12,510 --> 00:06:18,390
+لاحظوا معاه هنا مافيش عندي double points بعد هيك
+
+71
+00:06:18,390 --> 00:06:23,590
+كانت ال melting point سبعين بعدك صار عندي one
+
+72
+00:06:23,590 --> 00:06:28,720
+double point نزلتلتلت عشر صار عندى تنتين double
+
+73
+00:06:28,720 --> 00:06:33,340
+points نزلت لناقص خمسة صار عندى تلاتة double
+
+74
+00:06:33,340 --> 00:06:39,320
+points نزلت لأكم لناقص احد عشر اذا بنقدر احنا
+
+75
+00:06:39,320 --> 00:06:45,180
+نستنتج انه كل ما بيزيدوا ال double points او as
+
+76
+00:06:45,180 --> 00:06:49,180
+the unsaturation increases يعني كل ما بيزيد عدم
+
+77
+00:06:49,180 --> 00:06:55,720
+التشبع ال melting point بتصير اقلكل ما بيزيد عدم
+
+78
+00:06:55,720 --> 00:06:59,920
+التشبع كل ما ال melting point لل fatty acid بتصير
+
+79
+00:06:59,920 --> 00:07:05,940
+ايش اقل طبعا هذا الكلام بحاجة الى تفسير ليش ال
+
+80
+00:07:05,940 --> 00:07:09,900
+saturated fatty acids in general اللي هو ال
+
+81
+00:07:09,900 --> 00:07:14,060
+melting point عالية ال unsaturated منخفضة لاحظوا
+
+82
+00:07:14,060 --> 00:07:17,960
+هنا السبعين معناه على حرارة الغرفة تبعتنا احنا
+
+83
+00:07:17,960 --> 00:07:22,740
+معدل حرارة الغرفة خمسة وعشرين تلاتين solidالان
+
+84
+00:07:22,740 --> 00:07:28,960
+التلتعش في الجو تبعنا اليوم هيكون سائل لأن الحرارة
+
+85
+00:07:28,960 --> 00:07:32,580
+خمسة و عشرين عندنا فهو لما بنصار عن التلتعش إن أنا
+
+86
+00:07:32,580 --> 00:07:36,180
+سائل، إن ناقص خمسة أكيد سائل، إن ناقص إحد أش سائل،
+
+87
+00:07:36,180 --> 00:07:40,640
+يعني كأنه بنقدر ناخد معلومة جديدة إن ال
+
+88
+00:07:40,640 --> 00:07:48,350
+unsaturated they are liquidsيعني انسهار أو انخفاض
+
+89
+00:07:48,350 --> 00:07:51,630
+نقطة الانسهار تبعهم تخلهم liquids ال saturated
+
+90
+00:07:51,630 --> 00:07:59,770
+they are solids الاناذي
+
+91
+00:07:59,770 --> 00:08:05,690
+القصة جديرة ان نكون احنا متوقفين عندها خلينا ناخد
+
+92
+00:08:05,690 --> 00:08:10,920
+اذا شوية معلومات تساعدنا نفسر هذا الكلامأول اشي
+
+93
+00:08:10,920 --> 00:08:14,600
+most fatty acids are unbranched يعني ال fatty
+
+94
+00:08:14,600 --> 00:08:19,080
+acids سلاسل غير متفرعة سلسلة طويلة واضحة مافيها
+
+95
+00:08:19,080 --> 00:08:24,690
+branchingand contain an even number of carbon
+
+96
+00:08:24,690 --> 00:08:29,890
+atoms فيهم عدد ال carbon atoms عدد إيش زوجة الان
+
+97
+00:08:29,890 --> 00:08:34,010
+ال unsaturated acids أول ما أبدأ أقول double bond
+
+98
+00:08:34,010 --> 00:08:39,410
+كلمة ال double bond ارتبطت الذهن بcis و trans او z
+
+99
+00:08:39,410 --> 00:08:46,090
+و e اه unsaturated acids usually have the cis or z
+
+100
+00:08:46,090 --> 00:08:50,720
+configurationالـ Unsaturated بيكون ال
+
+101
+00:08:50,720 --> 00:08:56,020
+configuration فيهم إيش زد يعني ال .. ال أتشز بيجوا
+
+102
+00:08:56,020 --> 00:09:01,420
+على جهة و ال carbons على جهة التانية الآن they
+
+103
+00:09:01,420 --> 00:09:03,720
+have lower boiling points than the corresponding
+
+104
+00:09:03,720 --> 00:09:08,260
+saturated ones شوفنا من خلال القيم أن ال
+
+105
+00:09:08,260 --> 00:09:13,860
+unsaturated نقاط الانسهار بتاعتهم أقل من إيش أقل
+
+106
+00:09:13,860 --> 00:09:17,060
+من ال saturated ممتاز
+
+107
+00:09:20,030 --> 00:09:24,490
+الان بنجي للسؤال الأول ليش هدولة solids والتانين
+
+108
+00:09:24,490 --> 00:09:31,420
+liquids اتطلعوا معايا لو اتخيلت انا هذا شكللـ
+
+109
+00:09:31,420 --> 00:09:35,200
+triglycerides يعني هذا الجزء الجليسرين و هذا الاشي
+
+110
+00:09:35,200 --> 00:09:39,720
+الزهري هو ال oxygen و بعد هيك في عندي تلت سلاسل
+
+111
+00:09:39,720 --> 00:09:45,560
+طويلة سلسلة تنتين تلاتة الان هذه السلاسل لما تكون
+
+112
+00:09:45,560 --> 00:09:50,340
+مشبعة لما تكون مشبعة بشكل عام بنتخيلها بهذا الشكل
+
+113
+00:09:50,340 --> 00:09:55,820
+المستقيم الان لاحظوا كيف شكل المركب هو شكل منتظم
+
+114
+00:09:56,070 --> 00:10:01,290
+قالم المركب الشكل تبعه منتظم معناه ذلك ان الجزيئات
+
+115
+00:10:01,290 --> 00:10:05,930
+بتيجي فوق بعضها بشكل جيد تترتب فوق بعضها في الحالة
+
+116
+00:10:05,930 --> 00:10:10,450
+الصلبة وهذا اللي بيخليها تكون ايه اش solids الان
+
+117
+00:10:10,450 --> 00:10:16,410
+لو فقط واحدة من هدولة صار فيها double bond يعني لو
+
+118
+00:10:16,410 --> 00:10:20,790
+كان عندى ال triglycerides مديش اقول التلاتة فيهم
+
+119
+00:10:20,790 --> 00:10:23,670
+double bonds خليني اقول هذه saturated و هذه
+
+120
+00:10:23,670 --> 00:10:28,530
+saturated واحدة بسقولت يكون فيها double bond و ال
+
+121
+00:10:28,530 --> 00:10:31,550
+double bond اللي بده تكون فيها إيش بده تكون sis
+
+122
+00:10:31,550 --> 00:10:35,990
+هتصير بهذا الشكل اتطلع من عندها هاي ال sis اللي
+
+123
+00:10:35,990 --> 00:10:40,750
+موجود فيها هاي ال double bond و هذا الجزء هاي أنا
+
+124
+00:10:40,750 --> 00:10:45,690
+carbon و أنا carbon على نفس الجهة هذا الشكل عمل
+
+125
+00:10:45,690 --> 00:10:53,030
+إيش فيها انتناقةواضح؟ الآن هذا الانفناق حافظ على
+
+126
+00:10:53,030 --> 00:10:58,750
+الشكل المنتظم للجزيء ولا بطل الجزيء منتظم؟ بطل
+
+127
+00:10:58,750 --> 00:11:02,830
+الجزيء منتظم ولذلك لما تيجي الجزيقات بتنحط فوق بعض
+
+128
+00:11:02,830 --> 00:11:07,130
+في solid lattice في الشبكة عشان تكون المركب الصلب
+
+129
+00:11:07,130 --> 00:11:11,450
+مابتبعدش فوق بعض جيدا، مابتكونش متراسة فوق بعض
+
+130
+00:11:11,450 --> 00:11:16,630
+البعض فالمادة بتحول إلى إيش؟ إلى liquid أو بتنخفض
+
+131
+00:11:16,630 --> 00:11:23,240
+نقاط انصحارهاولذلك هنا احنا انا شفنا ال space
+
+132
+00:11:23,240 --> 00:11:26,860
+filling and schematic model of glycerol التسمية
+
+133
+00:11:26,860 --> 00:11:30,380
+بناخدها tri-palmitate هذا من ال palmitic acid يعني
+
+134
+00:11:30,380 --> 00:11:35,380
+كام كربون؟ 16 اللي متذكرين هذا المشبع ايش ماله؟
+
+135
+00:11:35,380 --> 00:11:41,520
+كان regular كان منتظم بينما لاحظوا معي هنا هذا
+
+136
+00:11:41,520 --> 00:11:46,680
+اللي فيه بس واحدغير مشبع، في double bond، راح
+
+137
+00:11:46,680 --> 00:11:50,220
+الانتظام، الآن اتخيلوا انه لو اكثر من واحد في
+
+138
+00:11:50,220 --> 00:11:53,480
+double bonds، اتخيل لو هذا فيه اكثر من double
+
+139
+00:11:53,480 --> 00:11:58,200
+bond، وكل double bond فيهم صار أشبه بإيش؟
+
+140
+00:12:00,430 --> 00:12:05,610
+لأ صار أشبه حقيقة .. صار أشبه حقيقة بالفكرة اللي
+
+141
+00:12:05,610 --> 00:12:11,730
+أخدناها لما درسنا ال ال can's ال chain ال can's و
+
+142
+00:12:11,730 --> 00:12:15,610
+ال branch ال can's و قولنا أن ال chain they have
+
+143
+00:12:15,610 --> 00:12:20,810
+higherboiling point و melting point than ال branch
+
+144
+00:12:20,810 --> 00:12:25,610
+ليش؟ لأن ال branch أصبح شكلهم زي إيش؟ زي الكرة
+
+145
+00:12:25,610 --> 00:12:30,510
+بطلوا منتظمين فوق بعضهم البعض، واضح؟ لما أخدنا
+
+146
+00:12:30,510 --> 00:12:33,510
+قولنا مين، إله ال boiling point أعلى، ال chain ولا
+
+147
+00:12:33,510 --> 00:12:39,770
+ال branch؟لأن ال branch بطل شكله منتظم الفكرة
+
+148
+00:12:39,770 --> 00:12:43,890
+بالانتظام، الآن هذا اللي في double bonds نفس
+
+149
+00:12:43,890 --> 00:12:48,250
+الفكرة زي ال branch، يعني لاحظوا أنه لو كان هنا في
+
+150
+00:12:48,250 --> 00:12:52,990
+branch مش هتعمل هيك وتقضي على الانتظام اللي كان
+
+151
+00:12:52,990 --> 00:12:59,180
+موجود، الآن هذا الكلام اللي عملته double bondفال
+
+152
+00:12:59,180 --> 00:13:03,560
+branching بيقضي على الانتظام ووجود ال cyst double
+
+153
+00:13:03,560 --> 00:13:07,240
+bond بهذا الشكل ايضا قضى على الانتظام فالفكرة
+
+154
+00:13:07,240 --> 00:13:12,780
+العامة في الحالتين لما نقول ان ال kids بشكل عام
+
+155
+00:13:12,780 --> 00:13:16,060
+انه ال branch they have lower boiling points and
+
+156
+00:13:16,060 --> 00:13:20,150
+melting points because they are irregularالان هنا
+
+157
+00:13:20,150 --> 00:13:24,550
+الـ triglycerides that contain unsaturated fatty
+
+158
+00:13:24,550 --> 00:13:27,470
+acids they have lower boiling point and melting
+
+159
+00:13:27,470 --> 00:13:31,990
+point because they are irregular من وين اجت ال
+
+160
+00:13:31,990 --> 00:13:36,330
+irregularity اللي فيهم، عدم الانتظام من وجود ال
+
+161
+00:13:36,330 --> 00:13:39,370
+double bond و ال cis configuration اللي موجود
+
+162
+00:13:39,370 --> 00:13:44,450
+فيها، واضح؟ الان هذا الكلام بيفرق عندي وين؟ بيفرق
+
+163
+00:13:44,450 --> 00:13:49,870
+عندي وين؟ال oil however are liquid بيصير في عندى
+
+164
+00:13:49,870 --> 00:13:56,350
+اشي اسمه بالمطبخ خلينا نقول شغلتين بيصير في عندكم
+
+165
+00:13:56,350 --> 00:14:01,010
+زيت، زيت الجلي، زيت عباد الشمس، زيت الصوية اللي
+
+166
+00:14:01,010 --> 00:14:06,290
+بتسموه searage، هذا liquid و بيصير في عندكم صلب،
+
+167
+00:14:06,290 --> 00:14:11,260
+السمنة والزبدةملاحظين انتوا هدولة ماشي بيفرجوا
+
+168
+00:14:11,260 --> 00:14:17,240
+ببعض، السمنة والزبدة saturated،
+
+169
+00:14:17,240 --> 00:14:21,650
+الزيت اللي فيه ال double bondsالزيت اللي فيه ال
+
+170
+00:14:21,650 --> 00:14:25,130
+double bonds عشان هيك صار liquid, oils however are
+
+171
+00:14:25,130 --> 00:14:32,190
+liquids because they contain lower percentage of
+
+172
+00:14:32,190 --> 00:14:35,230
+unsaturated .. higher percentage عفوا .. higher
+
+173
+00:14:35,230 --> 00:14:38,490
+percentage of unsaturated fatty acids إذا لو
+
+174
+00:14:38,490 --> 00:14:43,310
+بيناقول مين اللي فيه ال double bonds؟ ال oil ولا
+
+175
+00:14:43,310 --> 00:14:48,010
+ال fat؟ السمنة والزبدة بيناقول عنهم fatsالزيت
+
+176
+00:14:48,010 --> 00:14:51,170
+والسيرش .. زيت الزتون والسيرش .. بنقول عنهم إيش؟
+
+177
+00:14:51,170 --> 00:14:54,830
+Oil .. ال oil هو اللي فيه ال double bonds .. و ال
+
+178
+00:14:54,830 --> 00:14:59,150
+double bonds هي اللي خفضت إيش نقطة انسهاره .. الآن
+
+179
+00:14:59,150 --> 00:15:03,050
+لاحظوا معاك ان انتوا اتعلمتوا كيميا .. ان انتوا
+
+180
+00:15:03,050 --> 00:15:08,300
+اتعلمتوا كيميااتعلمتوا ان ال double bond ممكن
+
+181
+00:15:08,300 --> 00:15:14,140
+نعملها ايش؟ hydrogenation نعملها single bond الان
+
+182
+00:15:14,140 --> 00:15:21,060
+لو اعملت لهذا المركب hydrogenation هذا زيت اعملت
+
+183
+00:15:21,060 --> 00:15:25,300
+هدرجة اللي هو شو بيصير؟ بيصير solid بيصير سمنة
+
+184
+00:15:25,300 --> 00:15:30,830
+فالسمنة تنتج من هدرجة الزيوتبس حطوا هنا هيدروجين و
+
+185
+00:15:30,830 --> 00:15:37,190
+هيدروجين، هذا صار saturated فحولت ال oil إلى fat،
+
+186
+00:15:37,190 --> 00:15:42,750
+سر السمنة والزبدة واضح اذا وين؟ بتيجي بالظبط فكرة
+
+187
+00:15:42,750 --> 00:15:49,070
+الهدرجة، الهدرجة بتحول السائل إلى صلب، في ناس
+
+188
+00:15:49,070 --> 00:15:52,030
+بيحبوا الشغلات الصلبة، يتعاملوا معها،
+
+189
+00:15:52,030 --> 00:15:57,540
+hydrogenationواضح؟ اتعلمنا ان ال hydrogenation على
+
+190
+00:15:57,540 --> 00:16:01,060
+ال double bond بيحول ال double bond إلى single
+
+191
+00:16:01,060 --> 00:16:05,620
+bond هاي ال unsaturated صار saturated معناه ذلك ال
+
+192
+00:16:05,620 --> 00:16:11,520
+liquid صار solid لأنه غير المنتظم بسبب ال double
+
+193
+00:16:11,520 --> 00:16:15,840
+bond سيصبح منتظم بعد أن تذهب ال double bond واضحة
+
+194
+00:16:15,840 --> 00:16:16,480
+الفكرة؟
+
+195
+00:16:18,930 --> 00:16:23,230
+ما بنعملش عملية عكسية العملية اللى موجودة ال هدرجة
+
+196
+00:16:23,230 --> 00:16:29,310
+مش العكسي السمنة لما بتكويها تصير سائل فاطوها على
+
+197
+00:16:29,310 --> 00:16:34,810
+النار سايحوها على النار هذا تسخين اسمه بس أنا بحكي
+
+198
+00:16:34,810 --> 00:16:41,230
+على هدرجة واضح؟ الآن هنا بتجيني مشكلة جديدة هنا
+
+199
+00:16:41,230 --> 00:16:46,630
+بتجيني مشكلة جديدة وانتبهوا لها جيدا انتبهوا لها
+
+200
+00:16:46,630 --> 00:16:52,820
+جيدا لأنها مشكلة خطيرةالان زي ما اتفقنا احنا ان
+
+201
+00:16:52,820 --> 00:16:57,480
+الزيوت بشكل عام فيها double bonds وال double bonds
+
+202
+00:16:57,480 --> 00:17:04,580
+ايش ال configuration فيها سيس الان لو يا ترىنتيجة
+
+203
+00:17:04,580 --> 00:17:09,440
+عمل كيميائي أو عمل إنساني أو تسخين زائد السس اتحول
+
+204
+00:17:09,440 --> 00:17:13,460
+ل Trans بالحرارة احنا قلنا بالوضع الطبيعي بتتحولش
+
+205
+00:17:13,460 --> 00:17:17,820
+يعني حرارة الغرفة بدون تفاعلات كيميائية بدون تسخين
+
+206
+00:17:17,820 --> 00:17:24,460
+السس Trans are not interconvertable easyب .. ب ..
+
+207
+00:17:24,460 --> 00:17:28,340
+ب .. ليش؟ لأن الدوران حوالين ال double bond صعب مش
+
+208
+00:17:28,340 --> 00:17:34,080
+سهل لكن بالتسخين أو بعوامل كيميائية ممكن تتم
+
+209
+00:17:34,080 --> 00:17:38,560
+العملية؟ ممكن، بالذات بالتسخين طب وين احنا بنسخن
+
+210
+00:17:38,560 --> 00:17:43,820
+اكتر اشيء؟ لما نجلي بال series الآن جاليا مرة
+
+211
+00:17:43,820 --> 00:17:49,210
+واحدةزي ما بتجلو بيضة مش مشكلة تحطوا زيت زاتون و
+
+212
+00:17:49,210 --> 00:17:53,670
+البيضة دقيقة وقال ماشي لكن الناس اللي بيجلو
+
+213
+00:17:53,670 --> 00:18:00,510
+بالسيرج عشر مرات البطاطا و الفلافل معناه ذلك ان
+
+214
+00:18:00,510 --> 00:18:05,090
+معها التسخين نسبة كبيرة جدا من ال ces ممكن تصير
+
+215
+00:18:05,090 --> 00:18:09,750
+ايش؟ Trans الان ال Trans compounds are
+
+216
+00:18:09,750 --> 00:18:15,660
+carcinogenic ال Trans مصارطنينهم لاحظين و لذلك
+
+217
+00:18:15,660 --> 00:18:22,820
+يحذر من القلي المتكرر في الزيوت يعني مش شطارة انه
+
+218
+00:18:22,820 --> 00:18:27,840
+رابط البيت والله بتجلي مرة مارتين تلاتة عشرة او
+
+219
+00:18:27,840 --> 00:18:32,700
+الناس اللي بيشتغلوا في الشوارع او المطاعم بيجلوا
+
+220
+00:18:32,700 --> 00:18:36,240
+عشر مرات ما هو كل ما احنا جاعدين بنسخن على السيرج
+
+221
+00:18:36,240 --> 00:18:40,520
+و كل ما بنجلي فيه بزيادة كل ما بنحول double bones
+
+222
+00:18:40,520 --> 00:18:46,130
+اكترنتيجة الحرارة من cis إلى trans كل ما بيصير
+
+223
+00:18:46,130 --> 00:18:50,350
+الإنسان طبعا هياخد مع الأشياء المجلية زيوت كمان و
+
+224
+00:18:50,350 --> 00:18:56,550
+هذه الأشياء fatty acids، انتبهوا معي، fatty acids
+
+225
+00:18:56,550 --> 00:19:03,430
+with trans bonds are carcinogenic، مسارتمينو لذلك
+
+226
+00:19:03,430 --> 00:19:08,350
+يعني اكثر من مرة و تانية ما اتجربوش تجلو انما انه
+
+227
+00:19:08,350 --> 00:19:13,910
+الزيت بينجل فيه ايام و ليالي كل هذا الكلام يعتبر
+
+228
+00:19:13,910 --> 00:19:18,430
+كلام إيش خاطر الآن لاحظوا معاك انه برضه عملية
+
+229
+00:19:18,430 --> 00:19:26,120
+الهدرجة برضه عملية الهدرجة عملية كيميائيةبنحول
+
+230
+00:19:26,120 --> 00:19:32,420
+فيها احنا نسبة كبيرة من ال double bonds إلى single
+
+231
+00:19:32,420 --> 00:19:36,140
+bonds يعني جاعدين احنا نحول double bond إلى single
+
+232
+00:19:36,140 --> 00:19:39,800
+bond هذه ال double bond اللي احنا بنحولها sis ولا
+
+233
+00:19:39,800 --> 00:19:44,680
+trans؟ sisالان هذه ال هدرجة لما بنحكي عن زيت مش زي
+
+234
+00:19:44,680 --> 00:19:49,440
+مركب كيميائي يعني مش عملية سهلة عادة ما بتتمش على
+
+235
+00:19:49,440 --> 00:19:53,840
+كل ال double bonds لكن بتعمل نسبة كبيرة منهم واضحة
+
+236
+00:19:53,840 --> 00:19:59,820
+الفكرة؟ الان في هذه الأثناء بعض ال six double
+
+237
+00:19:59,820 --> 00:20:03,000
+bonds بيظلهم six يعني ما بيصلهمش الدور انهم ايش
+
+238
+00:20:03,000 --> 00:20:08,240
+انه يصيرلهم هدرجة وبعض ال six منهم بتتحولوا إلى
+
+239
+00:20:08,240 --> 00:20:16,060
+transوبالتالي بتصير الهدرجة أيضا عاملة مشكلة مش من
+
+240
+00:20:16,060 --> 00:20:20,040
+منطقة ان هي حولت ال double bond إلى single bond
+
+241
+00:20:20,040 --> 00:20:25,580
+يعني لو ان هي بشكل نظيف ودقيق ومتقن حولت ال double
+
+242
+00:20:25,580 --> 00:20:29,320
+bonds إلى single bonds يعني حولت الزيت إلى سمنة
+
+243
+00:20:29,320 --> 00:20:35,410
+مافيش مشكلةلكن المشكلة ان هذه الهدرجة غالبا بتكون
+
+244
+00:20:35,410 --> 00:20:40,410
+غير كاملة لحد معين بيضل شوية SIS BONS ونتيجة
+
+245
+00:20:40,410 --> 00:20:45,750
+التفاعل الكيميائي بعض ال SISBONS بيصيروا Trans
+
+246
+00:20:45,750 --> 00:20:54,780
+واضح؟ ولذلك اليومصار يعني في دول معينة يجبروا
+
+247
+00:20:54,780 --> 00:20:59,920
+الشركات المصنعة انه تعمل فحوصات و انه على نفس
+
+248
+00:20:59,920 --> 00:21:05,920
+الزبدة و على نفس السمنة تكتب جداش نسبة لترانس فيها
+
+249
+00:21:06,870 --> 00:21:10,710
+والمواطن لازم يعرف اقل تقدير انتوا الان كمتعلمين
+
+250
+00:21:10,710 --> 00:21:16,130
+انه كل ما نسبة لل Trans بتزيد كل ما المركب بيكون
+
+251
+00:21:16,130 --> 00:21:22,750
+ايش اخطر كل ما المركب بيكون carcinogenic واضح؟
+
+252
+00:21:22,750 --> 00:21:30,570
+الان بنيجي لكيف يا ترى بنسمي ال triglycerides
+
+253
+00:21:30,570 --> 00:21:37,170
+خلينا ننتبه لشغلةإنهم لـ triglycerides عبارة عن
+
+254
+00:21:37,170 --> 00:21:44,870
+glycerol صح؟ حامل كام fatty acid؟ تلاتة، الآن لـ
+
+255
+00:21:44,870 --> 00:21:49,570
+triglycerides نوعين،
+
+256
+00:21:49,570 --> 00:21:53,790
+ع طول، أي واحدة بتقدر تقولي شو النوعين، انتظر،
+
+257
+00:21:53,790 --> 00:21:59,250
+ممكن يكونوا متماثلين، يعني فيهم نفس ال fatty acid
+
+258
+00:22:00,450 --> 00:22:04,870
+واضح؟ يعني اربعتاش اربعتاش اربعتاش مشبه او ستاش
+
+259
+00:22:04,870 --> 00:22:10,890
+ستاش ستاش مشبه وممكن يكونوا غير متماثلين صارت
+
+260
+00:22:10,890 --> 00:22:13,830
+الأفكار شبيهة بأشياء أخدتها زي لما أخدنا ال ether
+
+261
+00:22:13,830 --> 00:22:18,250
+متماثل وغير متماثل زي ما أخدنا ال anhydride متماثل
+
+262
+00:22:18,250 --> 00:22:22,650
+وغير متماثل كمان ال triglycerides ممكن يكونوا
+
+263
+00:22:23,260 --> 00:22:28,120
+Simple يعني متماثلين أو Mixed Mixed يعني مخلطين
+
+264
+00:22:28,120 --> 00:22:32,680
+يعني يكون هذا 16 هذا 18 هذا 18 فيه double bond
+
+265
+00:22:32,680 --> 00:22:40,160
+واضح؟ الآن أكيد لما بدنا نسمي لو كانوا متماثلين
+
+266
+00:22:40,160 --> 00:22:46,220
+هنذكر اسم الفاتئاسد لمرة واحدة و لو كانوا غير
+
+267
+00:22:46,220 --> 00:22:51,530
+متماثلين بدنا نذكر إيش؟الثلاث أسماء اللي موجودة مش
+
+268
+00:22:51,530 --> 00:22:55,890
+هذه لازم تكون الفكرة العامة الآن بشكل عام ك common
+
+269
+00:22:55,890 --> 00:23:01,070
+name وخلينا نبدأ بال common name للمتماثلين لو كان
+
+270
+00:23:01,070 --> 00:23:07,970
+ال fatty acid ال 12 اللي هو اللوريك أسد تمام بنسمي
+
+271
+00:23:07,970 --> 00:23:10,630
+المركب Trilaurin
+
+272
+00:23:13,300 --> 00:23:19,580
+واضح؟ إذا من ال acid lauryl بحط إيش؟ lauryl tri
+
+273
+00:23:19,580 --> 00:23:27,660
+-lauryl طيب لو كان stearic tri-stearic يعني لاحظوا
+
+274
+00:23:27,660 --> 00:23:35,300
+معي كان ال acid الأصلي lauryl لما عملت منه ال tri
+
+275
+00:23:35,300 --> 00:23:41,860
+-glyceride ضفت كلمة trialهذه إجت جديدة اللورك
+
+276
+00:23:41,860 --> 00:23:50,100
+خلّيت منها لور و حطيت لها إيش؟ حطيت لها in بدل اك
+
+277
+00:23:50,100 --> 00:23:58,260
+in ال try لورن طيب من ال steerك المتماثل try
+
+278
+00:23:58,260 --> 00:24:06,150
+steering من الأوليك المتماثل try أولينواضح؟
+
+279
+00:24:06,150 --> 00:24:10,870
+ترايقليا ولاحظوا على طول طبعا هيبين معاكم كيف
+
+280
+00:24:10,870 --> 00:24:14,890
+لتراي لاورين مثلا ال melting point له لأن كل ال
+
+281
+00:24:14,890 --> 00:24:20,510
+fatty acids تبعته مشبعة خمسة واربعين هذا
+
+282
+00:24:20,510 --> 00:24:27,490
+لترايستيرين واحد وسبعين الان لو سألت واحدة منكم لو
+
+283
+00:24:27,490 --> 00:24:31,650
+سألت واحدة منكم ليش لتراي لاورين خمسة واربعين و
+
+284
+00:24:31,650 --> 00:24:37,120
+لترايستيرين واحد وسبعينالسلسلة أطول، الموليكولا
+
+285
+00:24:37,120 --> 00:24:41,400
+رويت، الكلمتين صح، التنين مشبع، مشبع، بطل، التشبع
+
+286
+00:24:41,400 --> 00:24:47,300
+هو الفارق، فقط طول السلسلة، أه، لكن لما هنا أجيت
+
+287
+00:24:47,300 --> 00:24:53,430
+18 و 18و حطيت تلاتة double bonds يعني خصام ست
+
+288
+00:24:53,430 --> 00:24:56,410
+هيدروجينات مش المشكلة بفرق ال molecular weight
+
+289
+00:24:56,410 --> 00:25:00,290
+يعني ست وحدات في جزاء كبير زي هذا في ال molecular
+
+290
+00:25:00,290 --> 00:25:04,550
+weight ماسهمهم مش فرق لكن المشكلة حقيقة لما أنا
+
+291
+00:25:04,550 --> 00:25:11,450
+بنزل هذا 18 و هذا 18 قليل ال 18 في one double bond
+
+292
+00:25:11,450 --> 00:25:16,970
+لما بنزل من 71 ل 4 هذا مش فاتقش التغير في ال
+
+293
+00:25:16,970 --> 00:25:21,280
+molecular weightهذا نتيجة وجود ال double bonds،
+
+294
+00:25:21,280 --> 00:25:24,300
+ليش؟ لأن وجدت لو بدي أجي هنا، بدي أعمل هذه ال
+
+295
+00:25:24,300 --> 00:25:26,840
+double bonds زي هيك و زي هيك، بعدين هذه زي هيك و
+
+296
+00:25:26,840 --> 00:25:34,010
+زي هيك، بعدين هذه، صار إيش؟ زي الكرةالجزيق وجده
+
+297
+00:25:34,010 --> 00:25:39,090
+بده يصير زي كرة كيف بده يكون منتظم في solid state
+
+298
+00:25:39,090 --> 00:25:44,550
+واضح الفكرة فلما بده أقول ليش ال triolين لو بده
+
+299
+00:25:44,550 --> 00:25:49,710
+أجي أسألكم ال triolين have lower melting point
+
+300
+00:25:49,710 --> 00:25:54,770
+than tristerine because of the presence of the
+
+301
+00:25:54,770 --> 00:26:00,230
+double bonds or because it is unsaturated واضح
+
+302
+00:26:00,230 --> 00:26:05,250
+الفكرةو هذا وجود ال double bond أو ال unsaturation
+
+303
+00:26:05,250 --> 00:26:09,790
+خلّاه regular ولا irregular؟ irregular بطل منتظم
+
+304
+00:26:09,790 --> 00:26:14,070
+بطل زي .. زي حجار الطوب المنتظمة كيف بتصفق بعض
+
+305
+00:26:14,070 --> 00:26:18,870
+بشكل قوى بينما حجار مش منتظمة بتضل إيش؟ توجع أو
+
+306
+00:26:18,870 --> 00:26:26,600
+ألعاب الأطفال اللي بيسموها ال Legoالان موضوع
+
+307
+00:26:26,600 --> 00:26:30,780
+الهيدروجينيشن of vegetable oils حكينا قولنا ان
+
+308
+00:26:30,780 --> 00:26:36,420
+احنا ممكن ناخد ال oil ويصير زبدة او سمنة
+
+309
+00:26:36,420 --> 00:26:40,120
+بالهيدروجينيشن تحويل ال double bond الى single
+
+310
+00:26:40,120 --> 00:26:42,780
+bond هذا الكلام برفع ال melting point بيحول ال
+
+311
+00:26:42,780 --> 00:26:47,380
+liquid الى solid الهيدروجينيشن عادة بتنفي وجود
+
+312
+00:26:47,380 --> 00:26:52,360
+الهيدروجين و نكلكتاليست و heat لكن هناك خطورة
+
+313
+00:26:52,360 --> 00:26:54,420
+مصاحبة للهيدروجينيشن
+
+314
+00:26:56,690 --> 00:27:02,110
+تحويل بعض ال sis bonds إلى trans يعني التحويل من
+
+315
+00:27:02,110 --> 00:27:05,630
+sis إلى saturated أو من double bond إلى saturated
+
+316
+00:27:05,630 --> 00:27:10,750
+هذا مافيش فيه مشكلة لكن كتفاعل جانبي بعض ال sis
+
+317
+00:27:10,750 --> 00:27:15,450
+بصير trans هنا توجد المشكلة
+
+318
+00:27:16,590 --> 00:27:21,350
+الان مرة تانية نرجع لل simple and mixed
+
+319
+00:27:21,350 --> 00:27:25,210
+triglycerides اللي هي المتماثلة و غير المتماثلة
+
+320
+00:27:25,210 --> 00:27:32,490
+اتفقنا احنا ان المتماثل بنعطي اسم common name
+
+321
+00:27:32,490 --> 00:27:38,470
+trystyrian يعني هذا 18 اذا ايش الحامض تبعه؟ Styric
+
+322
+00:27:38,470 --> 00:27:44,190
+Styric Styric فالمركب trystyrian طيب لو كنا بنسمي
+
+323
+00:27:44,190 --> 00:27:51,210
+ايوبكيعني Triglycerides is a common name و أنا
+
+324
+00:27:51,210 --> 00:27:55,470
+مرات بجيبلكوا سؤال في الامتحان .. بجيبلكوا سؤال في
+
+325
+00:27:55,470 --> 00:28:00,810
+الامتحان ال Triglycerides is also called .. or the
+
+326
+00:28:00,810 --> 00:28:06,830
+Ayurvedic name of Triglycerides is .. الآن عشان
+
+327
+00:28:06,830 --> 00:28:11,650
+نجاوبه صح احنا قولنا ال Triglycerides they are
+
+328
+00:28:11,650 --> 00:28:18,550
+Easter'sEaster صح ولا لأ؟ كيف أنا كنت أسمي ال
+
+329
+00:28:18,550 --> 00:28:22,970
+Easter؟ خليني أتذكر كيف أنا كنت أسمي ال Easter،
+
+330
+00:28:22,970 --> 00:28:29,370
+هيني بدي أكتب Easter عشان واحدة تذكرني كيف،
+
+331
+00:28:29,370 --> 00:28:32,690
+هاي Easter، شايفينه اللي على اللوح؟ واحدة تسميه
+
+332
+00:28:32,690 --> 00:28:37,370
+جزء الكحول في الأول
+
+333
+00:28:40,150 --> 00:28:49,150
+مثل هاي جزء الكحول وبعدين جزء الحامض انتوا بتكونوا
+
+334
+00:28:49,150 --> 00:28:52,910
+شايفوني ومن جلة دراستكوا بنزويك أسد ال Easter
+
+335
+00:28:52,910 --> 00:28:58,130
+بنتهي بنزويت مثل بنزويت أسيتات بيوتانويت اه هذا
+
+336
+00:28:58,130 --> 00:29:04,970
+مثل ايش؟ بنزويت اذا تسمية ال Easterلعبوا لو أنكوا
+
+337
+00:29:04,970 --> 00:29:09,030
+بتحاولوا تحفظوا الكيميا كرموز بتتغلبوا لو أنكوا
+
+338
+00:29:09,030 --> 00:29:13,310
+حفظتوا الكيميا أنه تسمية ال Easter مجموعة الكحول
+
+339
+00:29:13,310 --> 00:29:18,690
+في الأول بعدين ال acid منتهي ب إيه؟ إثل أستيت مثل
+
+340
+00:29:18,690 --> 00:29:24,730
+بنزويت فين ال بيوتانويت صح ولا لأ؟ طيب الآن كويس
+
+341
+00:29:24,730 --> 00:29:31,770
+لو إجيت على هذا شو هو جزء الكحول فيه؟ ال glycerin
+
+342
+00:29:32,770 --> 00:29:38,250
+وشو الأحمض؟ الاستيرك أسد مش هذا الحامض و هذا
+
+343
+00:29:38,250 --> 00:29:44,590
+الكحول ولا لأ ايش اول اشي بنذكره؟ جزء الكحول
+
+344
+00:29:44,590 --> 00:29:53,350
+إجليسارين إجليساريل و الاستيرك أسدStraight لكن لأن
+
+345
+00:29:53,350 --> 00:29:58,330
+في عندي منه تلاتة بقول glycerol ال try straight
+
+346
+00:29:58,330 --> 00:30:03,290
+إذا أنا نفس المنطقة ده اسمها ال Easter الكحول في
+
+347
+00:30:03,290 --> 00:30:09,070
+الأول و بعدين النهاية eight و حطيت try لأن عندي كم
+
+348
+00:30:09,070 --> 00:30:16,160
+حامض تلاتةإذا هذا هي جزء الكحول اللي فيه في واحدة
+
+349
+00:30:16,160 --> 00:30:19,140
+منكم مالخومة كتير عشان الكحول مرسوم على اليمين مش
+
+350
+00:30:19,140 --> 00:30:22,660
+على الشمال المهم نذكر الكحول في الأول كيف نرسمه مش
+
+351
+00:30:22,660 --> 00:30:28,360
+مشكلة واضحة الفكرة ولا لأ؟ واضحات؟ يعني هذا لو كنت
+
+352
+00:30:28,360 --> 00:30:35,540
+راسمه بالعكس إيش برضه هسميه؟ واضح؟ شايف هي كناس
+
+353
+00:30:35,540 --> 00:30:40,360
+مرات بهمش بيغرجوا بشبهر ميه؟
+
+354
+00:30:43,590 --> 00:30:46,990
+يعني اتعودتوا انتوا انه هذا نعمله زي هيك او يبدو
+
+355
+00:30:46,990 --> 00:30:53,130
+معكوس لان لما يرسم زي هيك وين جزء الكحول مثل وين
+
+356
+00:30:53,130 --> 00:30:57,250
+جزء الاسد مثل بنزويت مثل بنزويت خلاص يعني الفكرة
+
+357
+00:30:57,250 --> 00:31:01,950
+مش انه بدهم يبينوا هدولة معكوسين دائما لأ لأ مش
+
+358
+00:31:01,950 --> 00:31:06,890
+هذه الفكرة حسب طريقة الرسم يذكر جزء الكحول اولا ثم
+
+359
+00:31:06,890 --> 00:31:10,770
+جزء الحامض منتهي بالنهاية ايه ولذلك هذا هيك ايش
+
+360
+00:31:10,770 --> 00:31:14,780
+بدنا نسميهمثل؟ بنزوية
+
+361
+00:31:18,100 --> 00:31:22,640
+أكيد اكيد طبعا اه ليش مايجيكيش ارسمي نفسي كل هذان
+
+362
+00:31:22,640 --> 00:31:27,800
+الكربونات بترسم ترسم شو وراكم انتوا دافعين رسوم
+
+363
+00:31:27,800 --> 00:31:32,760
+بتكونوا بتتعلموا واضح تسمية ال easter تسمية ال
+
+364
+00:31:32,760 --> 00:31:37,840
+easter ببساطة انه تذكروا جزء الكحول بعدين جزء
+
+365
+00:31:37,840 --> 00:31:42,400
+الحامض المساهي بالنهاية ايش ات فهذا صار glycerol
+
+366
+00:31:42,400 --> 00:31:50,100
+tryStirate هذه فهمناها طيب لو كانوا الأحماض الآن
+
+367
+00:31:50,100 --> 00:31:56,200
+مختلفين يعني صار عنده اللي أنا بسميه إيش mixed
+
+368
+00:31:56,200 --> 00:32:02,760
+triglyceride مرة تانية هحط في الأول جزء الكحول إذا
+
+369
+00:32:02,760 --> 00:32:09,450
+هنا هذا الجزء الكحول هي الجزء اللي جاي من الكحولمش
+
+370
+00:32:09,450 --> 00:32:16,310
+بختلف عليه، الآن الأحماض بدي أذكرهم مرتبين، واحد،
+
+371
+00:32:16,310 --> 00:32:20,950
+اتنين، تلاتة، طبعا هتقولولي إذا عرفنا واحد، بعده
+
+372
+00:32:20,950 --> 00:32:24,270
+بنقول اتنين، تلاتة، يمكن تصير المشكلة عندكم أن هذا
+
+373
+00:32:24,270 --> 00:32:28,730
+واحد، بعدين اتنين، تلاتة، ولا هذا واحد، بعدين
+
+374
+00:32:28,730 --> 00:32:33,800
+اتنين، تلاتةواضح؟ يعني المشكلة أن أذكر واحد، بعد
+
+375
+00:32:33,800 --> 00:32:38,020
+ما أذكر واحد لازم أمشي فيهم إيش، امرتبين، الآن
+
+376
+00:32:38,020 --> 00:32:44,760
+ببساطة بنقول الأصغر والأكثر تشبعا هو اللي بنحطه
+
+377
+00:32:44,760 --> 00:32:49,940
+نمرة واحد يعني لما أنا بدأ أختار وين نمرة واحد،
+
+378
+00:32:49,940 --> 00:32:54,960
+بدأ أختار الأصغر منهم والأكثر تشبعايعني لو لجيت
+
+379
+00:32:54,960 --> 00:32:58,980
+هنا ستة عشر وهنا تمانت عشر مشبعين التنين مين بدي
+
+380
+00:32:58,980 --> 00:33:05,540
+أحطهم؟ ستة عشر الان لو لجيت هنا ستة عشر وهنا تمانت
+
+381
+00:33:05,540 --> 00:33:11,280
+عشر وكمان هذا مشبع الستة عشر الآن بعد ما أحط الستة
+
+382
+00:33:11,280 --> 00:33:16,280
+عشر مامشي فيهم بالترتيب واضح؟ ولذلك هدولة لو انا
+
+383
+00:33:16,280 --> 00:33:22,470
+اجيت اطلعت الستة عشر بال methic acidالـ 18 المشبع
+
+384
+00:33:22,470 --> 00:33:27,790
+استيرك الـ 18 اللي فيه double bond أوليك لما أنا
+
+385
+00:33:27,790 --> 00:33:32,150
+بدي أسميهم بقول glycerin بعدين بجعل بالميتو
+
+386
+00:33:32,150 --> 00:33:38,510
+بالميتو بعدين الاستيرك استيره بعدين على الأوليك
+
+387
+00:33:38,510 --> 00:33:45,490
+أولييت بحط ات في النهاية لاحظوا معي أن الأوليك أن
+
+388
+00:33:45,490 --> 00:33:46,390
+الأوليك
+
+389
+00:33:50,390 --> 00:33:58,870
+الـ O تبعته عليها إيش؟ نجوطين طبعا على الكمبيوتر
+
+390
+00:33:58,870 --> 00:34:03,230
+ممكن تلاقوا الـ O اللي عليها نجوطين و ممكن أنه
+
+391
+00:34:03,230 --> 00:34:06,430
+ماتلاقوهاش، الآن لو مالاجيتوهاش الـ O اللي عليها
+
+392
+00:34:06,430 --> 00:34:08,870
+نجوطين اكتبوها إيش؟
+
+393
+00:34:10,720 --> 00:34:17,820
+والفظوها OE فهي O ممالة إلى الكسر يعني بمنطق
+
+394
+00:34:17,820 --> 00:34:24,480
+التجويد هي O ممالة للكسر و ال A اللي عليها نقطين A
+
+395
+00:34:24,480 --> 00:34:30,400
+ممالة للكسر و ال U اللي عليها نقطين ممالة للكسر
+
+396
+00:34:30,400 --> 00:34:38,300
+كمان ولذلك لما الألمان بيقرؤوا هذه الكلمة أول أول
+
+397
+00:34:39,500 --> 00:34:44,840
+لحظوا الفك كيف بنزل لتحت إمالة للكسر مار عليكم
+
+398
+00:34:44,840 --> 00:34:49,320
+الإمالات ولا لأ؟
+
+399
+00:34:49,320 --> 00:34:55,740
+ولا في عندنا ولا إمالة في القرآن الكريم برواية حفظ
+
+400
+00:34:55,740 --> 00:35:02,450
+عن عاصرهي إمالة واحدة لكن روحوا على روايات تانية
+
+401
+00:35:02,450 --> 00:35:08,870
+زي مثلا الكساء وغير وغيرات كله إمالات واضح؟ أه في
+
+402
+00:35:08,870 --> 00:35:14,550
+القرآن الكريم وقال اركبوا فيها بسم الله مجريها ما
+
+403
+00:35:14,550 --> 00:35:19,490
+تقولوش مجريها هادفرة كسر كامل هي ألف ممالة للكسر
+
+404
+00:35:19,490 --> 00:35:26,690
+بسم الله مجريها ومرساها طبعاعند غير حفظة عن عاصم
+
+405
+00:35:26,690 --> 00:35:32,110
+معظم بيقرأوا باسم الله مجراها بيرجعوها مجراها و
+
+406
+00:35:32,110 --> 00:35:36,530
+مرساها بيحطوهم زي ما .. فهذه قول هذه قوليك قوليك
+
+407
+00:35:36,530 --> 00:35:44,270
+الفك يكون ميل للكسر او تقرأوها ايش اوأو نقرأها OE
+
+408
+00:35:44,270 --> 00:35:50,130
+إذا سهلة تسمية بدي أحط glycerin وإذا كانوا زي بعض
+
+409
+00:35:50,130 --> 00:35:55,330
+بحط ال tri و الحمض eight وإذا كانوا مش زي بعض بدي
+
+410
+00:35:55,330 --> 00:35:58,770
+أذكر التلاتة هقول مين بدي أبدأ واحد و بعدين اتنين
+
+411
+00:35:58,770 --> 00:36:04,210
+تلاتة الواحد هو الأصغر و الأكتر تشبعانيعني لو
+
+412
+00:36:04,210 --> 00:36:07,990
+إجينا اتطلعنا على هذا المثال نتطلع فيه عندنا
+
+413
+00:36:07,990 --> 00:36:13,210
+هاناستيرك أسد وهانا بالميتك أسد وهانا أوليك أسد
+
+414
+00:36:13,210 --> 00:36:17,630
+الآن أنا بأتطلع على الأطراف أنا مقارنتني من أين
+
+415
+00:36:17,630 --> 00:36:21,350
+بدي أبدأ من هذا الطرف و لا من هذا الطرف واضحة
+
+416
+00:36:21,350 --> 00:36:28,690
+الفكرة؟ الآن اتطلعوا من هذا الطرف أوليك 18 غير
+
+417
+00:36:28,690 --> 00:36:34,880
+مشبعاستيرك تمانتعش مشبع تمانتعش و تمانتعش مشبع و
+
+418
+00:36:34,880 --> 00:36:41,320
+غير مشبع من وين بدي أبدأ تمانتعش مشبع تمانتعش مشبع
+
+419
+00:36:41,320 --> 00:36:49,500
+و لذلك هذا المركب لما أنا بدي أسميه إجليساريل
+
+420
+00:36:49,500 --> 00:36:53,720
+بعدين بسيب فراغ مشبولنا في ال Easter بنسيب فراغ زي
+
+421
+00:36:53,720 --> 00:36:59,640
+إتل فراغ أستيتل إجليساريل فراغ استيرو بالميتو
+
+422
+00:37:02,340 --> 00:37:10,300
+واضح؟ الار اتخيلوا لو اجاكم سؤال اجليساريل بالميتو
+
+423
+00:37:10,300 --> 00:37:15,340
+استيروا قليل واجليساريل استيروا بالميتو قليل يعني
+
+424
+00:37:15,340 --> 00:37:20,300
+عكس التانين فيهم حطيت فيهم التلاتة هذا بيبدأ
+
+425
+00:37:20,300 --> 00:37:24,440
+بالميتو بعدين استيره بعدين قليل هذا بيبدأ استيره
+
+426
+00:37:24,440 --> 00:37:30,300
+بعدين بالميتو قليل هدول اش بيكون العلاقة بينهم؟We
+
+427
+00:37:30,300 --> 00:37:37,280
+are surely isomers فش نقاش إنهم isomers الآن أي
+
+428
+00:37:37,280 --> 00:37:41,840
+نوع من ال isomers؟
+
+429
+00:37:41,840 --> 00:37:47,960
+الآن اطلعوا معي هايهم، تلاتة، واحدة تشوفهم ك ..
+
+430
+00:37:47,960 --> 00:37:50,820
+برا الكيميا، برا الكيميا مش هاي ال glycerol وهيو
+
+431
+00:37:50,820 --> 00:37:55,860
+حاملهم التلاتة، حاملهم التلاتة أزرق، أحمر، يعني
+
+432
+00:37:55,860 --> 00:38:01,600
+يجربوا بيصيروا زي أعلام فلسطينأزرق، أحمر، أصمر،
+
+433
+00:38:01,600 --> 00:38:11,200
+أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق،
+
+434
+00:38:11,200 --> 00:38:11,220
+أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر،
+
+435
+00:38:11,220 --> 00:38:11,240
+أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر،
+
+436
+00:38:11,240 --> 00:38:11,720
+أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق،
+
+437
+00:38:11,720 --> 00:38:13,520
+أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر،
+
+438
+00:38:13,520 --> 00:38:16,920
+أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر،
+
+439
+00:38:16,920 --> 00:38:22,200
+أحمرمواقع الارتباط اتغيرت، هذا كان شابق في أول
+
+440
+00:38:22,200 --> 00:38:25,980
+كاربون الأزرق والأحمر في التانية، الأحمر صار في
+
+441
+00:38:25,980 --> 00:38:30,540
+الأولى والأزرق في التانية، different bonding، بزن
+
+442
+00:38:30,540 --> 00:38:35,820
+different bonding، اذا structural isomers،
+
+443
+00:38:35,820 --> 00:38:40,040
+different bonding تبعها كمان شغلة، different names
+
+444
+00:38:41,090 --> 00:38:44,950
+واضح؟ عشان ايك، لاحظوا واحد كان اسمه glycerol
+
+445
+00:38:44,950 --> 00:38:48,350
+بالميتو ستيرو أوليات، التاني glycerol ستيرو
+
+446
+00:38:48,350 --> 00:38:51,150
+بالميتو أوليات، الآن هذول أخدوا different names
+
+447
+00:38:51,150 --> 00:38:54,230
+ولا لأ؟ طالما different names، إذا they are
+
+448
+00:38:54,230 --> 00:38:59,470
+structural isomers، ال stereo isomers كانوا ياخدوا
+
+449
+00:38:59,470 --> 00:39:05,780
+نفس الاسميفرقوا بس في البادقة في الانانشو مارز R
+
+450
+00:39:05,780 --> 00:39:11,680
+ولا S ولا كذا وفي الدياستيريو مارز S أو Trans أو Z
+
+451
+00:39:11,680 --> 00:39:16,340
+أو E same name وكانوا ياخدوا different descriptive
+
+452
+00:39:16,340 --> 00:39:20,680
+البادقة اللي بتوصف الشكل الفراغي مش سميناها
+
+453
+00:39:20,680 --> 00:39:25,520
+descriptive البادقة ال R أو ال S أو ال Z أو ال E
+
+454
+00:39:25,520 --> 00:39:30,460
+أو ال S أو ال Trans لكن إلهم نفس الاش نفس الإسم
+
+455
+00:39:31,530 --> 00:39:35,470
+الان لاحظوا معاه لو قلنا لكم draw this structure
+
+456
+00:39:35,470 --> 00:39:41,210
+for glyceryl trimeristate اللي هو meristic acid ال
+
+457
+00:39:41,210 --> 00:39:48,210
+14 موجود عندكم بدكوا تحطوهربما من الأخطاء اللي
+
+458
+00:39:48,210 --> 00:39:50,450
+كتير الطلاب بيخطئوها
+
+459
+00:40:19,820 --> 00:40:23,880
+تطلعوا كيف الشكل الصحيح ال O هان هذا جزء الكحول
+
+460
+00:40:23,880 --> 00:40:29,400
+هذا جزء الحامض ال glycerin هو المتصل بال O العادية
+
+461
+00:40:29,400 --> 00:40:33,400
+single bond بعدين ال C double bond O مش العكس هذا
+
+462
+00:40:33,400 --> 00:40:36,340
+من الأخطاء الشائعة لما نقول للطلبة ارسمولنا
+
+463
+00:40:36,340 --> 00:40:41,640
+triglyceride بيروحوا بيرسموليا معكوس واضح؟
+
+464
+00:40:44,360 --> 00:40:49,780
+على أي حال، بهيك تقريبا بننهي اليوم بكرا إجازة عيد
+
+465
+00:40:49,780 --> 00:40:54,740
+العمال، ماعرفش وقتاش بيكون عيد الطلاب، عيدنا يوم
+
+466
+00:40:54,740 --> 00:40:57,280
+نجاحنا
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..fb6d6837eba461ceaaca22b71b32343165a6d781
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.srt
@@ -0,0 +1,1884 @@
+1
+00:00:19,520 --> 00:00:23,540
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:23,540 --> 00:00:28,820
+موضوع ال acidity و عرفنا بالظبط ايش معنى الأحمار و
+
+3
+00:00:28,820 --> 00:00:35,360
+وضحنا انه مهم جدا نعرف ايش معنى ال BKAال acidity
+
+4
+00:00:35,360 --> 00:00:39,820
+constant و قولنا كل ما ال PKA قلة كل ما الحامض
+
+5
+00:00:39,820 --> 00:00:45,000
+بيكون ايش اقوى بعد هي طرحنا سؤال و أعطينا عليه
+
+6
+00:00:45,000 --> 00:00:49,940
+إجابة عامة بدون ما ندخل بأنفلة تفصيلية كان السؤال
+
+7
+00:00:49,940 --> 00:00:54,540
+لما بدأ قارن حامض مع حامض تاني من الأقوى و من
+
+8
+00:00:54,540 --> 00:00:59,250
+الأقل بدأ اعتمد على ايشلما بقارن الأحماض في قوتها
+
+9
+00:00:59,250 --> 00:01:05,270
+بدي أنظر لل أيون السالب اللي بتكون نتيجة اللي هو
+
+10
+00:01:05,270 --> 00:01:10,430
+تحلل الحمض بالماء هذا ال أيون السالب بدي الشحنة
+
+11
+00:01:10,430 --> 00:01:14,110
+تبعته تكون أقل ما يمكن هذا اللي بنسميه إيش احنا ال
+
+12
+00:01:14,110 --> 00:01:18,470
+stability ل ال negative أيون معنى ال stability أن
+
+13
+00:01:18,470 --> 00:01:21,710
+الشحنة تكون أقل ما يمكن الآن إيش اللي بيقلل
+
+14
+00:01:21,710 --> 00:01:27,060
+الشحنة؟تلات تأثيرات ممكن الحجم اللي بيحمل الشحنة
+
+15
+00:01:27,060 --> 00:01:30,920
+وممكن شيء نسميه ال inductive effect اللي هو تأثير
+
+16
+00:01:30,920 --> 00:01:36,180
+المساعدة وممكن شيء نسميه ال resonance effect
+
+17
+00:01:36,180 --> 00:01:42,660
+أعطينا بعض الأمثلة لكن خلينا نأكد الآن مثلا لو
+
+18
+00:01:42,660 --> 00:01:48,420
+أجينا نقارن ال phenolsمع الالكوهولز العادية
+
+19
+00:01:48,420 --> 00:01:54,480
+الاليفاتك الالكوهولز بمعنى انا بدي اقارن ROH مع
+
+20
+00:01:54,480 --> 00:01:59,320
+فنل OH لاحظوا المقطة الأولى انه لما ايجي يعمل
+
+21
+00:01:59,320 --> 00:02:04,680
+المقارنة ويفهم المقارنة سابه هو من الحامض ايش كتب؟
+
+22
+00:02:04,680 --> 00:02:10,760
+الايون السالد يعني كتب أنا R O minus وفنل O minus
+
+23
+00:02:10,760 --> 00:02:17,990
+فالحكم هوالـ Ion السالب الان هذا الـ RO- الشحن
+
+24
+00:02:17,990 --> 00:02:22,450
+اللي موجود عليه ثابت على ال oxygen مافيش فيها حركة
+
+25
+00:02:22,450 --> 00:02:25,970
+مافيش فيها resonance ال oxygen ذرة صغيرة يعني
+
+26
+00:02:25,970 --> 00:02:29,710
+بيقول it cannot carry the negative charge صعب
+
+27
+00:02:29,710 --> 00:02:33,250
+عليها تحمل ال negative charge ولذلك ال Ion كله
+
+28
+00:02:33,250 --> 00:02:37,050
+بيكون unstable فلاحظوا الكلام ان ال charge is
+
+29
+00:02:37,050 --> 00:02:43,570
+localized يعني محمولة على موقع واحد مش عملهاتتنجل
+
+30
+00:02:43,570 --> 00:02:48,730
+localized متموضعة محمولة في موضع واحد عكسها ايش؟
+
+31
+00:02:48,730 --> 00:02:53,410
+delocalized فبصير عندي كلمتين localized اشي على
+
+32
+00:02:53,410 --> 00:02:57,550
+موضع واحد delocalized زي ما انا اجي احمل هذا هيك
+
+33
+00:02:57,550 --> 00:03:01,550
+بس عن ايد هذه و فقط لا غير هيك بيكون هذا الحمل
+
+34
+00:03:01,550 --> 00:03:07,590
+localized الآن لو كنت بنجلهبيكون De-localized واضح
+
+35
+00:03:07,590 --> 00:03:13,210
+فإذا بنلاحظ أنه بالفينول الشحنة السالبة في أحد ال
+
+36
+00:03:13,210 --> 00:03:16,350
+resonance structures على ال oxygen لكن لو عملنا
+
+37
+00:03:16,350 --> 00:03:20,450
+حركة إلكترونات زوج من الإلكترونات بهذا الشكل و
+
+38
+00:03:20,450 --> 00:03:23,710
+حركنا ال bond هنلاحظ أنها ممكن تصير على ال carbon
+
+39
+00:03:23,710 --> 00:03:26,510
+اللي موجودة هنا بحركة تانية على ال carbon اللي
+
+40
+00:03:26,510 --> 00:03:29,750
+موجودة هنا بحركة تالتة على ال carbon لاحظوا أنه
+
+41
+00:03:29,750 --> 00:03:34,460
+بطلت الشحنةمحمولة على مكان واحد بطلت localized
+
+42
+00:03:34,460 --> 00:03:39,000
+صارت delocalized هذا resonance واضح او
+
+43
+00:03:39,000 --> 00:03:42,400
+delocalization يعني بيستعملوا كلمة resonance او
+
+44
+00:03:42,400 --> 00:03:46,900
+delocalization بنفس المعنى واضح ف because of the
+
+45
+00:03:46,900 --> 00:03:52,360
+delocalization of the charge in phenoxide and ion
+
+46
+00:03:52,360 --> 00:03:56,540
+or anion لحظوا ال phenyl O minus شو بنسميه
+
+47
+00:03:58,860 --> 00:04:02,960
+فينوكسايد انا يعني يمكن سابقا حكينالكم هي اللي لو
+
+48
+00:04:02,960 --> 00:04:09,300
+كانت هذه مثل O minus مثوكسايد مثل O minus إثوكسايد
+
+49
+00:04:09,300 --> 00:04:16,880
+HO minusHydroxide هيدروكسايد هيدروكسايد
+
+50
+00:04:16,880 --> 00:04:17,360
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+51
+00:04:17,360 --> 00:04:20,000
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+52
+00:04:20,000 --> 00:04:20,660
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+53
+00:04:20,660 --> 00:04:22,780
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+54
+00:04:22,780 --> 00:04:27,020
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+55
+00:04:27,020 --> 00:04:30,260
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+56
+00:04:30,260 --> 00:04:37,420
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+57
+00:04:37,420 --> 00:04:43,720
+هيدروكسايد هيدروحوالي ست عشر، خمس عشر و نص و خمس
+
+58
+00:04:43,720 --> 00:04:47,340
+عشر و تسعة فلما نيجي نسأل ليش ال phenols are more
+
+59
+00:04:47,340 --> 00:04:51,140
+acidic than alcohols الجواب because of resonance
+
+60
+00:04:51,140 --> 00:04:56,460
+or because of delocalization of its chargeطبعا لو
+
+61
+00:04:56,460 --> 00:05:02,800
+صار عندى Nitrophenol ال delocalization بزيد يعني
+
+62
+00:05:02,800 --> 00:05:07,600
+الشحنة السالبة بالاضافة لإنها ممكن تنوجد على مواضع
+
+63
+00:05:07,600 --> 00:05:12,500
+كثيرة كمان بصير بإمكانها تنوجد على ذرات ال oxygen
+
+64
+00:05:12,500 --> 00:05:15,260
+بتاعون ال Nitro فبصير
+
+65
+00:05:17,450 --> 00:05:22,290
+الـ Delocalization للـ negative charge ايش ماله
+
+66
+00:05:22,290 --> 00:05:27,270
+اكتر بيصير عندي more delocalization يعني الشحنة
+
+67
+00:05:27,270 --> 00:05:31,350
+موزعة زي حمل بيحملوا اتنين اتريحوا شوية طب لو
+
+68
+00:05:31,350 --> 00:05:36,630
+حملوا تلاتة افضل لو حملوا اربعة أسهل واضح الفكرة
+
+69
+00:05:36,630 --> 00:05:42,650
+فبالنيتروفينول عندي more delocalization ولذلك نزل
+
+70
+00:05:42,650 --> 00:05:48,190
+النيتروفينول لقداشلسبعة و اتنين من عشرة ال BKA اذا
+
+71
+00:05:48,190 --> 00:05:52,510
+which is more acidic ال Nitrophenol is more acidic
+
+72
+00:05:52,510 --> 00:05:57,290
+لانه فيه more resonance طب لو صارت Trinitrophenol
+
+73
+00:05:57,290 --> 00:06:02,970
+more and more فهيصل ل point two five وبناء على ذلك
+
+74
+00:06:02,970 --> 00:06:08,670
+سمنا ايش احنا بكريك اسد ل Trinitrophenolهذه كلها
+
+75
+00:06:08,670 --> 00:06:12,850
+أمثلة على الـ Resonance Effect الآن لو كنت بدي
+
+76
+00:06:12,850 --> 00:06:17,290
+أمثلة على ال Inductive Effect لو بدأت بالإيثانول
+
+77
+00:06:17,290 --> 00:06:24,150
+فيه تلت مجموعات هيدروجين CH2OH CH3 طيب لو حطيت
+
+78
+00:06:24,150 --> 00:06:28,830
+واحدة من الهيدروجين زي كلور بتبدأ هذه الكلور تسحب
+
+79
+00:06:28,830 --> 00:06:30,210
+جزء من الشحنة
+
+80
+00:06:32,900 --> 00:06:36,200
+افترضوا ان كلهم فيهم شحنة سالبة قللت الشحنة
+
+81
+00:06:36,200 --> 00:06:41,580
+السالبة هذا ال effect سحب الشحنة with drawing of
+
+82
+00:06:41,580 --> 00:06:47,930
+the chargeأو إعطاء شحنة إيش بنسميه إحنا Inductive
+
+83
+00:06:47,930 --> 00:06:51,050
+Effect فال Inductive Effect هو سحب الشحنة أو
+
+84
+00:06:51,050 --> 00:06:55,470
+إعطائها مش نقلها لأ الشحنة موجودة هنا لكن افترض
+
+85
+00:06:55,470 --> 00:07:00,090
+الشحنة هنا عشر وحدات سحبنا منها واحدتين ال CL اللي
+
+86
+00:07:00,090 --> 00:07:05,050
+أنا بتحب السالب سحبت واحدتين جديش صفية بدل عشرة
+
+87
+00:07:05,050 --> 00:07:11,820
+تمانية واضح؟ الآن لو حطيت انتين CLصار عندى more
+
+88
+00:07:11,820 --> 00:07:17,220
+and more with the drawing لو حطيت تلاتة CL كلهم
+
+89
+00:07:17,220 --> 00:07:22,160
+بيسحبوا الشحنة السالبة بناء على ذلك ال effect هنا
+
+90
+00:07:22,160 --> 00:07:25,480
+لما انا بقول ان ال trichloroethanol is more acidic
+
+91
+00:07:25,480 --> 00:07:28,240
+than dichloroethanol than chloroethanol than
+
+92
+00:07:28,240 --> 00:07:32,340
+ethanol هذا ايش اللي بنسميه احنا inductive effect
+
+93
+00:07:32,340 --> 00:07:39,750
+واضح؟لمّا قررنا الـ RSH و الـ ROH مين اللي قلنا
+
+94
+00:07:39,750 --> 00:07:45,010
+فيهم أقوى كأسس؟ RSH طب الآن بنقول الـ RSH أقوى من
+
+95
+00:07:45,010 --> 00:07:51,310
+الـ ROH، why؟ because of the size، إذن هاي نعرفه
+
+96
+00:07:51,310 --> 00:08:00,410
+طيب، لو بدأجي أقول الـ ARSH مع الـ ROH، مين أقوى؟
+
+97
+00:08:02,130 --> 00:08:06,990
+because of the size لحظوا ال AR هنا و ال AR هنا
+
+98
+00:08:06,990 --> 00:08:11,890
+فيهم resonance فبطل ال resonance هو السبب يعني ال
+
+99
+00:08:11,890 --> 00:08:16,150
+aromatic او البنزينة هنا و البنزينة هنا فينول و
+
+100
+00:08:16,150 --> 00:08:22,040
+ثيوفينول ال AR عامل مشتركاللي بيعمل resonance بناء
+
+101
+00:08:22,040 --> 00:08:25,900
+على ذلك لو حد .. لو بدنا نجيب سؤال arsh is more
+
+102
+00:08:25,900 --> 00:08:30,240
+acidic than aroh due to resonance غلط لأنه هنا فيه
+
+103
+00:08:30,240 --> 00:08:33,680
+resonance و هنا فيه resonance طب هاش المختلف
+
+104
+00:08:33,680 --> 00:08:41,950
+sulfur و oxygen اذا because of the sizeلكن لو اجيت
+
+105
+00:08:41,950 --> 00:08:49,470
+قلتلكم بدأ اقارن ARSH و RSH، لاحظوا ال sulphur،
+
+106
+00:08:49,470 --> 00:08:53,990
+sulphur the same size، اذا وين صار الفرق؟ AR ولا
+
+107
+00:08:53,990 --> 00:09:00,310
+R؟ اذا why؟ because of resonance
+
+108
+00:09:04,470 --> 00:09:11,150
+لو كنت بدأ اقارن A R O H مع R O H ال O و ال O نفس
+
+109
+00:09:11,150 --> 00:09:16,870
+ال size اللي اتغير R و A R إذا مين أعلى؟ A R
+
+110
+00:09:16,870 --> 00:09:23,650
+because of resonance بضحك الفكرة لما بنعمل مقارنة
+
+111
+00:09:23,650 --> 00:09:29,630
+الآن لو إجيت على هدولة كلهم و قولت بدأ أسطب كل
+
+112
+00:09:29,630 --> 00:09:37,500
+الكلاموبلغة عربية بسيطة جدا بدي أقول من الأقوى ومن
+
+113
+00:09:37,500 --> 00:09:44,240
+الأضعف في الأربعة ال A R S H هو أقوى حاجة ال A R S
+
+114
+00:09:44,240 --> 00:09:51,560
+H هو الأقوى the strongest وال R O H هو الأضعف
+
+115
+00:09:54,370 --> 00:10:00,150
+يعني لو بقارن ال alcohols و ال thyols و ال phenols
+
+116
+00:10:00,150 --> 00:10:04,330
+و ال thyophenols أقوى واحد فيهم ال thyophenol و
+
+117
+00:10:04,330 --> 00:10:08,710
+أضعف واحد فيهم بالحمضية اللي هو إيش ال alcohol هذا
+
+118
+00:10:08,710 --> 00:10:14,970
+الكلام بينعكس على التفاعلات الكيميائيةهذا الكلام
+
+119
+00:10:14,970 --> 00:10:19,170
+الآن ان هذا الأضعف بنعكس على التفاعلات الكيميائية
+
+120
+00:10:19,170 --> 00:10:22,990
+وين بنعكس على التفاعلات الكيميائية مش احنا قاعدين
+
+121
+00:10:22,990 --> 00:10:28,010
+نقول هدولة أحماط مظبوط ولا لأ طول عمرنا بنعرف
+
+122
+00:10:28,010 --> 00:10:35,170
+الجملة الشهيرة حمض زاد قاعدة ملح زاد ماء بناء على
+
+123
+00:10:35,170 --> 00:10:40,570
+ذلك لو اجيت أفاعل هدولة مثلا مع قاعدة قوية زي ال N
+
+124
+00:10:40,570 --> 00:10:53,890
+A O Hزائد NaOH كلهم مش هم زائد قاعدة اه هلاحظ ان
+
+125
+00:10:53,890 --> 00:10:57,670
+تلاتة منهم بتفاعل وبيعطوا ملح زائد ماء واحد
+
+126
+00:10:57,670 --> 00:11:05,990
+مابتفعلش الا مابتفعلش هذا هذا بتفعل هذا بتفعل هذا
+
+127
+00:11:05,990 --> 00:11:11,040
+بتفعلواضح؟ طبعا لو قولنا لكم اكتبوا المعادلة،
+
+128
+00:11:11,040 --> 00:11:17,080
+عندنا مثال، لو أخدنا هذا ال R O H زي N A O H، إيش
+
+129
+00:11:17,080 --> 00:11:24,600
+كتبنا؟ No reaction لكن لو قولنا R S H زي N A O H،
+
+130
+00:11:24,600 --> 00:11:29,770
+ال H مع ال O H، إيش بيعملوا؟ ميّهطول عمره و ال RS
+
+131
+00:11:29,770 --> 00:11:36,350
+minus مع ال NA NA plus RS minus و بنفس الطريقة
+
+132
+00:11:36,350 --> 00:11:45,830
+بإمكانكم تكتبوا إيش كل الأشياء RSH
+
+133
+00:11:45,830 --> 00:11:46,050
+مع
+
+134
+00:11:57,410 --> 00:12:03,230
+فاهم الان دائما اذا وجد عندك مش سؤال مش سؤالك هذا
+
+135
+00:12:03,230 --> 00:12:08,170
+ال specific مش سؤالك هذا ال specific لأ اذا اي
+
+136
+00:12:08,170 --> 00:12:15,110
+شغلة حطيت فيها متغيرين معناه ذلك مش هيكون عندك ثقة
+
+137
+00:12:15,110 --> 00:12:20,110
+كاملة انك بتقدر تاخد الجواب مباشرة الا من التجربة
+
+138
+00:12:20,110 --> 00:12:27,210
+و من قيمة اش بتطلع التجربة ال BKAإذا صار عندك
+
+139
+00:12:27,210 --> 00:12:31,910
+متغيرين سؤالك انا بعتبره جيد انه انت غيرتي هنا ال
+
+140
+00:12:31,910 --> 00:12:37,970
+ar و r و هنا ال o و ال s و سألت مين الأقوى فيهم
+
+141
+00:12:37,970 --> 00:12:44,250
+كام متغير عندك اتنين الحل انك تبحثي تعمل التجربة و
+
+142
+00:12:44,250 --> 00:12:48,550
+تشوف ال bk ايه لهذا و ال bk لهذا و تعمل المقارنة
+
+143
+00:12:48,550 --> 00:12:54,180
+ولذلك في العلم دائما لما بتعملوا المقارنةبتثبتوا
+
+144
+00:12:54,180 --> 00:12:59,600
+جميع المتغيرات ما عدا متغير واحد بيصير بإمكانكوا
+
+145
+00:12:59,600 --> 00:13:03,420
+تعملوله مقارنة و تعملوله قوانين يمكن هذا الكلام
+
+146
+00:13:03,420 --> 00:13:08,780
+أكثر شيء مر عليكم في منطقة الغازات ليش؟ لأن
+
+147
+00:13:08,780 --> 00:13:13,500
+الغازات لها أكتر من متغير الضغط والحجم وعدد
+
+148
+00:13:13,500 --> 00:13:19,790
+المولات ودرجة الحرارةأربع متغيرات في الغازات واضح؟
+
+149
+00:13:19,790 --> 00:13:23,810
+الآن الغازات في النهاية كانت بتنجمع بمعادلة B في V
+
+150
+00:13:23,810 --> 00:13:28,570
+بساوي N في R في T pressure في volume بساوي number
+
+151
+00:13:28,570 --> 00:13:32,610
+of moles في R تابع الغازات في ال temperature الآن
+
+152
+00:13:32,610 --> 00:13:36,770
+لما كنت قادش أقول بدي أقارن ال volume مع ال
+
+153
+00:13:36,770 --> 00:13:43,210
+temperature كنت أحط لنفس الكمية من الغاز عندنفس
+
+154
+00:13:43,210 --> 00:13:49,550
+الضغط واضح بعد ذلك تصبح المقارنة أصعب تعمل تجربة
+
+155
+00:13:49,550 --> 00:13:55,930
+الان هنا ال O و O مشتركات ال R و AR مختلفات سهل
+
+156
+00:13:55,930 --> 00:14:01,650
+علي أعطي جواب واضح الفكرة؟ لكن هنا ال S أفضل من ال
+
+157
+00:14:01,650 --> 00:14:07,940
+O و ال AR أفضل من ال Rإيش النتيجة؟ التجربة
+
+158
+00:14:07,940 --> 00:14:14,040
+المجموعة التجربة واضح؟ يعني مافيش عندك جواب هذي
+
+159
+00:14:14,040 --> 00:14:16,880
+أفضل من هذي و هذي أفضل من هذي طب هذي أفضل من هذي
+
+160
+00:14:16,880 --> 00:14:20,440
+بقدش و هذي أفضل من هذي بقدش عشان يطلع عندي جواب؟
+
+161
+00:14:20,440 --> 00:14:29,160
+لأ بدك تعمل التجربة واضح؟ سؤال جيد الآن لاحظوا معي
+
+162
+00:14:29,160 --> 00:14:32,340
+هل يا ترى الكيميائي
+
+163
+00:14:33,600 --> 00:14:38,120
+بيستسلم؟ لأ، يعني سبحان الله زي ما بتقول آية كريمة
+
+164
+00:14:38,120 --> 00:14:44,820
+وفوق كل ذي علم عليم واضح؟ يعني احنا قولنا الكحول
+
+165
+00:14:44,820 --> 00:14:52,580
+هذا زائد N A O H لا يتفاعل طب ال N A O H كان تصنيف
+
+166
+00:14:52,580 --> 00:15:00,380
+strong baseقاعدة قوية الان ال N A O H is a strong
+
+167
+00:15:00,380 --> 00:15:05,360
+base مركب ايوني و قاعدة قوية طب حبيل غصب عنه
+
+168
+00:15:05,360 --> 00:15:11,000
+الكحول الفاعله ايش بنعمله بنجيبله very strong base
+
+169
+00:15:11,000 --> 00:15:16,460
+يعني بنجيبله قاعدة تكون اقوى من ال N A O H موجود
+
+170
+00:15:16,460 --> 00:15:20,860
+يعني بدل ما اجي افعله مع ال N A O H اللي strong
+
+171
+00:15:20,860 --> 00:15:26,490
+base ممكن افعله مع N A Hهذا المركب اسمه Sodium
+
+172
+00:15:26,490 --> 00:15:33,110
+Hydride الجزء القاعد فيه ايون H- الهيدرايد H-
+
+173
+00:15:33,110 --> 00:15:40,510
+واضح؟ ايش بنسمي هذا Sodium Hydride لاحظوا ال I
+
+174
+00:15:40,510 --> 00:15:47,390
+نهاية ايون سالف يعني هذا NA plus H- ويمكن كلكم
+
+175
+00:15:47,390 --> 00:15:54,470
+بتعرفوا او سبق مر عليكم ان ال H لهاتلت حلق ال H
+
+176
+00:15:54,470 --> 00:15:58,910
+ممكن تتخيلوها بتلت حلق ال H لحالها اللي فيها
+
+177
+00:15:58,910 --> 00:16:04,010
+إلكترون و ال H اللي فقدت الإلكترون و ال H لو
+
+178
+00:16:04,010 --> 00:16:09,010
+اكتسبت كمان إلكترون يعني ذرة الهيدروجين هي الذرة
+
+179
+00:16:09,010 --> 00:16:12,430
+اللي فيها إلكترون و بروتون فهذا ال H اللي فيها
+
+180
+00:16:12,430 --> 00:16:17,810
+إلكترون و بروتون هيدروجين أتم الآن لو فقدت
+
+181
+00:16:18,700 --> 00:16:25,900
+الإلكترون شو بنسميها بروتون بروتون ما انتوا تخيلوا
+
+182
+00:16:25,900 --> 00:16:31,020
+الذرة اتخيلوها بالذرة مش عندى نواة موجبة في كل
+
+183
+00:16:31,020 --> 00:16:38,060
+الأحوال و هالنواة الموجبة حواليهاالألكترون صارت
+
+184
+00:16:38,060 --> 00:16:41,660
+هيدروجين أتم الهيدروجين أتم نوال موجبة حوالها
+
+185
+00:16:41,660 --> 00:16:47,140
+إلكترون طيب لو صارت هيك وشيلنا الإلكترون شو الصفة
+
+186
+00:16:47,140 --> 00:16:55,280
+عندي النوال موجبة بس لبروتون واضح؟ الآن لو اكتسبت
+
+187
+00:16:55,280 --> 00:17:00,620
+كمان إلكترون تاني بتصير هيدرايد أنيون فهذه
+
+188
+00:17:00,620 --> 00:17:09,330
+هيدروجين أتمهذا البروتون وهذا الهيدرايد أنيون ال H
+
+189
+00:17:09,330 --> 00:17:14,810
+minus هيدرايد أنيون كتبنا هناك هيدرايد هذا دايما
+
+190
+00:17:14,810 --> 00:17:20,320
+البروتون اش بنسمي احنا او ال H plusبروتون ال H بلس
+
+191
+00:17:20,320 --> 00:17:25,400
+بروتون ولذلك الأحماض لما بنوصفها مثلا بنقول ال
+
+192
+00:17:25,400 --> 00:17:31,020
+HNO3 بنقول عنه في بروتون واحد monobrotic acid ال
+
+193
+00:17:31,020 --> 00:17:38,640
+H2SO4 بنقول dibrotic acid ال H3BO4 بنقول عنه
+
+194
+00:17:38,640 --> 00:17:43,100
+tribrotic acid واضح؟ اللي جابنا عن هالكلام كلمة
+
+195
+00:17:43,100 --> 00:17:51,800
+إيش؟السوديوم هايدرايد هو مصدر
+
+196
+00:17:51,800 --> 00:17:57,080
+قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى
+
+197
+00:17:57,080 --> 00:17:57,100
+قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى
+
+198
+00:17:57,100 --> 00:18:01,200
+قوى قوى قوى قوى قوى قوى قوى
+
+199
+00:18:02,990 --> 00:18:06,750
+اللي هو لو كنا بناخده مع الاثانول مثلا Sodium
+
+200
+00:18:06,750 --> 00:18:11,870
+Ethoxide كذلك الحال لو فعلنا مع ال metal نفسه NA
+
+201
+00:18:11,870 --> 00:18:19,010
+Sodium Metal Sodium Metal كmetal لوحده أقوى كقاعدة
+
+202
+00:18:19,010 --> 00:18:24,350
+من ال NAOH يعني بإمكانه يتفاعل ال ROH مع ال NA
+
+203
+00:18:24,350 --> 00:18:29,290
+ويعطينا RO minus في الحالتين ال بيكتمل التفاعل انه
+
+204
+00:18:29,290 --> 00:18:35,630
+بيطلع غاز هيدروجينفصحيح ان ال R O H بتفعلش مع ال N
+
+205
+00:18:35,630 --> 00:18:40,290
+A O H ولكنه يتفاعل مع ال sodium hydrate او ال
+
+206
+00:18:40,290 --> 00:18:46,090
+sodium metal وبيعطينا ال R O minus N A plus واضح
+
+207
+00:18:46,090 --> 00:18:54,450
+هذه الفكرة لان هذه تعتبر كقواعد اقوى من ال N A O H
+
+208
+00:18:56,180 --> 00:19:01,080
+بهيك بيكفي في موضوع ال acidity لو اجينا على ال
+
+209
+00:19:01,080 --> 00:19:07,040
+preparation of alcohol الحقيقة هتلاحظ انه بشكل عام
+
+210
+00:19:07,040 --> 00:19:14,260
+ال preparation of alcohol مر معنا طب وين مر معنا؟
+
+211
+00:19:14,260 --> 00:19:21,040
+في مكانين المكان الأول لما كنا ناخد double bond و
+
+212
+00:19:21,040 --> 00:19:24,440
+نعمل عليها addition of water in presence of acid
+
+213
+00:19:25,200 --> 00:19:31,800
+إيش كانت الضيف؟ H و OH إذا إنها تيش كحول، واضح؟
+
+214
+00:19:31,800 --> 00:19:37,680
+فإضافة الماء للالكينز هذه الطريقة ولذلك الإثانول
+
+215
+00:19:37,680 --> 00:19:42,800
+مثلا بنحضره بإضافة الماء للإثيلين
+
+216
+00:19:44,070 --> 00:19:48,550
+طبعا إله شغل عملي و ال yield جليل لكن بيعيدوا
+
+217
+00:19:48,550 --> 00:19:51,810
+التفاعل أكتر من مرة لحد ما يمشوا التفاعل يعني
+
+218
+00:19:51,810 --> 00:19:57,110
+الفكرة العلمية أنه بتفاعل و بيضيف واضح صناعيا أكيد
+
+219
+00:19:57,110 --> 00:20:01,690
+إله أجهزة أو إله متابعة صناعية كذلك الحال اللي
+
+220
+00:20:01,690 --> 00:20:06,230
+بتذكر ال alkenes و إضافة الميه لازم يظلوا متذكر
+
+221
+00:20:06,230 --> 00:20:06,710
+إيش
+
+222
+00:20:09,640 --> 00:20:12,940
+Markovnikov وAntimarkovnikov addition يعني انا لما
+
+223
+00:20:12,940 --> 00:20:18,520
+كنت على البروبين اضيف الماء في وجود H بلس وين كنت
+
+224
+00:20:18,520 --> 00:20:23,700
+احط الهيدروجين هان ال O-H هان اطلع البروبان to all
+
+225
+00:20:23,700 --> 00:20:27,780
+او to probanol او ايزو برو بالالكول ماكانش يطلع
+
+226
+00:20:27,780 --> 00:20:34,200
+هذا طب لو بدنا هذا شو كنا نعمل Antimarkovnikov
+
+227
+00:20:36,400 --> 00:20:40,420
+كنا نستعمل طريقة ال boron ال bh3 و توابعها
+
+228
+00:20:40,420 --> 00:20:46,540
+بترجعوها واضح؟ إذا الكحولات يمكن أن تحضر و أخدنا
+
+229
+00:20:46,540 --> 00:20:51,000
+هذا الكلام بالتفصيل من خلال إضافة الماء على ال
+
+230
+00:20:51,000 --> 00:20:56,860
+alkyls برضه طريقة تانية أخدناها لتحضير الكحولات
+
+231
+00:20:56,860 --> 00:20:59,440
+مين اتذكرنا فيها؟
+
+232
+00:21:04,290 --> 00:21:10,270
+الـ RX زائد الماء أو الـ OH ماينوس مش كنا ناخد هذه
+
+233
+00:21:10,270 --> 00:21:18,110
+المعادلة RX زائد H2O in general R OH لنيوكليوفيليك
+
+234
+00:21:18,110 --> 00:21:23,710
+سبستيوشن على ال الكلهيلايت شبتر ستة سواء كنا نفعله
+
+235
+00:21:23,710 --> 00:21:27,940
+مع نيوترال نيوكليوفايل او معit charged the
+
+236
+00:21:27,940 --> 00:21:32,680
+nucleophile واضح ال substitution إذا الطرق العامة
+
+237
+00:21:32,680 --> 00:21:38,340
+لتحضير الكحولات يا إما من ال RX بالإبدال يا إما من
+
+238
+00:21:38,340 --> 00:21:45,840
+ال alkenes بتفاعل إيش بنسميه الإضافة ما هو مع
+
+239
+00:21:45,840 --> 00:21:53,100
+الميه تفاعل إضافة addition reaction واضح الآن لو
+
+240
+00:21:53,100 --> 00:22:00,470
+إجينا بعد هيك على تفاعلاتالكحولات تفاعلات الكحولات
+
+241
+00:22:00,470 --> 00:22:05,210
+طبعا في زميلة لكم بس عشان يعني ما نغمطهاش حقها ان
+
+242
+00:22:05,210 --> 00:22:10,530
+هي منتبهة جالت من ال evoxides كلامها سليم يعني لما
+
+243
+00:22:10,530 --> 00:22:14,950
+كان يكون عندكم الالكين و اضيف عليه ال oxygen أعمل
+
+244
+00:22:14,950 --> 00:22:22,050
+منه evoxide و بعد هيك لو عملنا ring opening
+
+245
+00:22:22,050 --> 00:22:28,320
+باستعمال ال nucleophile كنا نقول CCOH و يجي
+
+246
+00:22:28,320 --> 00:22:32,640
+لنكليوفايل this is an alcohol كلامها سليم ماكنش
+
+247
+00:22:32,640 --> 00:22:39,500
+فيه غلط واضح لكن منطلقوا ايش الالكين برضه منطلقنا
+
+248
+00:22:39,500 --> 00:22:43,860
+الالكين اعملنا ابوكسايد و عملنا ring opening هذا
+
+249
+00:22:43,860 --> 00:22:48,780
+الكلام ماكن ان شاء الله الان لو اجينا على موضوع ال
+
+250
+00:22:48,780 --> 00:22:56,650
+reactions of alcoholsمن تفاعلات ال alcohols تفاعل
+
+251
+00:22:56,650 --> 00:23:01,390
+ال dehydration معنى ال dehydration او acidic
+
+252
+00:23:01,390 --> 00:23:08,500
+dehydration نزع الماء في وجود الحامضنزع الماء في
+
+253
+00:23:08,500 --> 00:23:12,660
+وجود الحامض هذا ايش اسمه dehydration حدف الماء في
+
+254
+00:23:12,660 --> 00:23:17,280
+وجود الحامض الآن بدنا ننتبه هنا لنقطة انه احنا
+
+255
+00:23:17,280 --> 00:23:22,940
+ممكن نعمل هذا التفاعل بطريقتين تؤدي الى ناتجين
+
+256
+00:23:22,940 --> 00:23:28,280
+مختلفين ممكن من نفس الكحول يعني لو أخدنا الاثانول
+
+257
+00:23:28,280 --> 00:23:31,240
+كمثال ننزع من هنا OH
+
+258
+00:23:34,460 --> 00:23:40,300
+OH من carbon مجاورة هنا رفعنا ايش؟ مية لما بنشيل
+
+259
+00:23:40,300 --> 00:23:48,100
+OH مع اتش شو ممكن نعمل؟ الالكين الحد في عكس ايش؟
+
+260
+00:23:48,100 --> 00:23:53,400
+الاضافة اضافة الماء على الالكين بتاعة الالكول حد
+
+261
+00:23:53,400 --> 00:23:58,520
+في ال ..إضافة الماء على الالكين تعطي الالكول وحذف
+
+262
+00:23:58,520 --> 00:24:03,620
+الماء من الالكول ممكن يعطي الالكين هذا أحد النواتج
+
+263
+00:24:03,620 --> 00:24:09,120
+الناتج التاني انه يتفاعلوا جزيئين من الالكول مع
+
+264
+00:24:09,120 --> 00:24:15,040
+بعضواضح؟ يعملول ال ether يعني هذا ال ethanol مع
+
+265
+00:24:15,040 --> 00:24:19,740
+ethanol تاني CH3CH2OH
+
+266
+00:24:19,740 --> 00:24:24,020
+يعني طبعا من و ال ethanol التاني ما انا حاطط ال
+
+267
+00:24:24,020 --> 00:24:29,380
+ethanol ملايين الجزيئات فجزيئ بتفاعل ايش؟ مع جزيئ
+
+268
+00:24:29,380 --> 00:24:35,200
+لاحظوا لما يعمل ال ether CH3CH2OCH2CH3
+
+269
+00:24:35,200 --> 00:24:41,990
+ايش حُدف من هدول الجزيئين؟مية O H من واحد O H من
+
+270
+00:24:41,990 --> 00:24:46,490
+واحد يعني كأنه بالظبط اللي بده يصير هنا أن هذه ال
+
+271
+00:24:46,490 --> 00:24:51,630
+O بدها تهاجم هنا على الكربون وتترد ال O H الآن و
+
+272
+00:24:51,630 --> 00:24:53,230
+هذه ال O شو هتخسر؟
+
+273
+00:24:57,940 --> 00:25:01,920
+هي لما هذه هاجمت من خلال الـ Oxygen كان يوكليوفايل
+
+274
+00:25:01,920 --> 00:25:06,880
+طردت الـ OH والنيوترال يوكليوفايل دايما بيخسر ايش؟
+
+275
+00:25:06,880 --> 00:25:11,740
+H اتفقنا على هذا الكلام هذه خسرت الـ H والـ OH ايش
+
+276
+00:25:11,740 --> 00:25:19,280
+عملوه؟ H2O يعني هنا زائد H2O وهنا زائد H2O لكن هنا
+
+277
+00:25:19,280 --> 00:25:23,780
+ما حُدفت من جزء واحد اعطت الالكين لو حُدفت من
+
+278
+00:25:23,780 --> 00:25:31,820
+التفاعل بين جزيين بتعطي ايش؟الـ Ether الـ ROR هو
+
+279
+00:25:31,820 --> 00:25:36,780
+الـ Ether طبعاً بيصير السؤال يا ترى أي التفاعلات
+
+280
+00:25:36,780 --> 00:25:42,640
+بيمشي بيعتمد على عدة عوامل من أهمها درجة الحرارة
+
+281
+00:25:42,640 --> 00:25:47,580
+زائد العوامل الحفازة اللي بيستعملوها للتفاعل خلينا
+
+282
+00:25:47,580 --> 00:25:51,260
+نكون مركزين على درجة الحرارة لو هذا التفاعل عملناه
+
+283
+00:25:51,260 --> 00:25:56,280
+عند 140 درجة مئوية هيعطينا بشكل أساس الـ Etherو لو
+
+284
+00:25:56,280 --> 00:26:00,740
+عملناها عند 180 درجة مئوية هيعطينا بشكل أساسي
+
+285
+00:26:00,740 --> 00:26:06,220
+الالكيد لكن بقولكوا أن التفاعل صناعيا له شغلات
+
+286
+00:26:06,220 --> 00:26:11,300
+تانية و بيستعمله catalyst معينة اللي مع الحرارة
+
+287
+00:26:11,300 --> 00:26:16,960
+تفضل هذا أو هذا يعني بعض العوامل الحفازة مع حرارة
+
+288
+00:26:16,960 --> 00:26:21,760
+أعلى من 180 ع 250 ممكن تخلي التفاعل يعطي بس ال
+
+289
+00:26:21,760 --> 00:26:27,030
+الكيد و بعض العوامل الحفازةعلى مية و اربعين، مية و
+
+290
+00:26:27,030 --> 00:26:34,050
+خمسين، ممكن تخليه يعطي بس إيش؟الإيثر الآن بدناش
+
+291
+00:26:34,050 --> 00:26:37,510
+ندخل في التفصيل الممل احنا بنقول انه تسخين
+
+292
+00:26:37,510 --> 00:26:42,030
+الاثانول في وجود الحامض 140 هيعطيني ال ether و 180
+
+293
+00:26:42,030 --> 00:26:47,950
+هيعطيني ال alkene و القمر لما يصير في الصناعة اكيد
+
+294
+00:26:47,950 --> 00:26:52,310
+اللي بيشتغلوا فيه يعني عندهم انتباه لأشياء إضافية
+
+295
+00:26:52,310 --> 00:26:56,290
+و لعوامل حفازة اللي يتحكموا ايش الناتج اللي بيطلع
+
+296
+00:26:56,290 --> 00:26:56,670
+عندهم
+
+297
+00:26:59,310 --> 00:27:04,610
+الان لو أخدنا مثال تاني لو أخدنا ال tertiary butyl
+
+298
+00:27:04,610 --> 00:27:08,770
+alcohol عارفينه ال tertiary butyl alcohol اللي هو
+
+299
+00:27:08,770 --> 00:27:12,470
+ال carbon اللي حامله تلت مجموعات مثل يعني لو رسمته
+
+300
+00:27:12,470 --> 00:27:22,330
+انا OH CH3 CH3 CH3 و سخناه في وجود حامض بالتأكيد
+
+301
+00:27:22,330 --> 00:27:31,490
+هيفقدالـ OH و هيفقد معها H من كاربون مجاورة الآن
+
+302
+00:27:31,490 --> 00:27:35,770
+التلت ذرات اللي هنا متكافئات ولا لأ؟ والتسع
+
+303
+00:27:35,770 --> 00:27:39,150
+هيدروجينات متكافئات عشان ايه؟ لو بدأ أقولكوا هذا
+
+304
+00:27:39,150 --> 00:27:42,990
+الحذف أو هذا ال dehydrationيعني جيكوا اك سؤال
+
+305
+00:27:42,990 --> 00:27:46,930
+dehydration of tertiary-butanol او tertiary-butyl
+
+306
+00:27:46,930 --> 00:27:51,770
+alcohol produces how many products؟ one يعني لو
+
+307
+00:27:51,770 --> 00:27:55,970
+شال H من هان زي هان زي هان بدون ما ندخل في
+
+308
+00:27:55,970 --> 00:27:59,250
+الميكانيزم لو رسمتوا double bond هان او رسمتوها
+
+309
+00:27:59,250 --> 00:28:03,230
+هان او رسمتوها هان هو ايش؟ نفس المركب هنا مثلا
+
+310
+00:28:03,230 --> 00:28:09,230
+رسمنا الـOH هذه مع H من هدولة هي الناتج ايش اسمه؟
+
+311
+00:28:09,230 --> 00:28:15,840
+ISOبيوتين مار عليكم ايزو بيوتين او لو بتكوينها بال
+
+312
+00:28:15,840 --> 00:28:22,300
+ايوبك one two three وعنمرة اتنين حامل ايش مثل اذا
+
+313
+00:28:22,300 --> 00:28:27,660
+two مثل بروبين two مثل بروبين هو نفس ال ايزو
+
+314
+00:28:27,660 --> 00:28:32,300
+بيوتين الان لاحظوا معايا ان انتوا صارت عندكم
+
+315
+00:28:32,300 --> 00:28:39,490
+الفكرة انه بتحذف OHو Hydrogen مجاورة لحسن الحظ في
+
+316
+00:28:39,490 --> 00:28:43,830
+ال tertiary butanol التلاتة زي بعض طلع بيطلع عندى
+
+317
+00:28:43,830 --> 00:28:49,330
+كام ناتج طب لو التلاتة مختلفات هيعطينى كام ناتج
+
+318
+00:28:49,330 --> 00:28:55,080
+اعملتوا مثال شبيه جدا بس لما كنتوا تحلفوا ايشمش ال
+
+319
+00:28:55,080 --> 00:29:01,400
+H O H ال H C L و سلمتوه homeware الحد في الميه زي
+
+320
+00:29:01,400 --> 00:29:06,420
+حد في ال H C L طب حد في ال H C L متذاكرين قاعدة
+
+321
+00:29:06,420 --> 00:29:14,280
+أخدتوها عشان اتقولكوا أي نواتج أفضل ال more
+
+322
+00:29:14,280 --> 00:29:18,740
+substituted زي سفرول ولذلك لو مثلا أخدتوا ال two
+
+323
+00:29:18,740 --> 00:29:25,870
+butanol أكيد بدنا نحدفالـ OH لكن يا تراب نحذف H من
+
+324
+00:29:25,870 --> 00:29:32,670
+هنا و لا H من هنا إذا حذفنا هذه ال H بنطلع هذا و
+
+325
+00:29:32,670 --> 00:29:36,350
+إذا حذفنا هذه ال H بنطلع هذا which is more
+
+326
+00:29:36,350 --> 00:29:41,780
+substitutedفي حد في ال alkalites زيها تماما ال
+
+327
+00:29:41,780 --> 00:29:45,020
+alcohols هذا more substituted بيكون ال major
+
+328
+00:29:45,020 --> 00:29:50,780
+product ال less substituted ال minor product واضح؟
+
+329
+00:29:50,780 --> 00:29:56,640
+كذلك الحالة بهذا المثال هيبدأ احذف ال OH تأكيد مش
+
+330
+00:29:56,640 --> 00:30:03,450
+فيها نقاش بس بدي Hمجاورة هنا في اتش وهذا المثل
+
+331
+00:30:03,450 --> 00:30:08,030
+كمان فيها اتش لو حذفت هذا الاتش اللي هنا بيطلع
+
+332
+00:30:08,030 --> 00:30:12,110
+الناتج التاني و لو حذفت الاتش من هنا او اتش او اتش
+
+333
+00:30:12,110 --> 00:30:17,050
+بيطلع هذا نتطلع عليهم which is more substituted
+
+334
+00:30:17,050 --> 00:30:21,470
+اكيد هذا more substituted ال major ال minor نفس
+
+335
+00:30:21,470 --> 00:30:24,610
+الكلام كنا نجيب السؤال بس بدل ما نكون كاتبين OH
+
+336
+00:30:24,610 --> 00:30:31,410
+نكون كاتبين CL او PRاللي عملناه لما كان دا يكون CL
+
+337
+00:30:31,410 --> 00:30:35,170
+او PR في chapter ال elimination في ال alkalites هو
+
+338
+00:30:35,170 --> 00:30:40,270
+نفسه بنطبقه على ال alcohol ف ال dehydration of
+
+339
+00:30:40,270 --> 00:30:46,530
+alcohol بيعطي نتائج موازية تماما ل ال
+
+340
+00:30:46,530 --> 00:30:51,100
+dehydrohalogenation of alcoholAlkyl Halides لاحظوا
+
+341
+00:30:51,100 --> 00:30:55,720
+في ال alcohols شو سمينا العملية؟ dehydration نزع
+
+342
+00:30:55,720 --> 00:31:00,780
+الماء OH وH طب لو كانت هذه بيه R او halogen X وH
+
+343
+00:31:00,780 --> 00:31:05,380
+ايش قولنا عنها؟ dehydrohalogenation
+
+344
+00:31:05,380 --> 00:31:11,600
+واضح؟ يعني لو هذه كانت X, hydro و halogen فصارت
+
+345
+00:31:11,600 --> 00:31:15,280
+dehydrohalogenation
+
+346
+00:31:15,280 --> 00:31:22,830
+لما H و OHdehydration و سبق أن وضحت لكم إيش معناه
+
+347
+00:31:22,830 --> 00:31:26,710
+الإضافات و النزع hydrogenation, dehydrogenation,
+
+348
+00:31:26,850 --> 00:31:30,290
+hydration, dehydration, hydrogenation,
+
+349
+00:31:30,410 --> 00:31:36,990
+dehydrogenation هذه المصطلحات لازم تكون واضحة لازم
+
+350
+00:31:36,990 --> 00:31:44,750
+تكون واضحة عندكم من تفاعلات ال alcohols التفاعل مع
+
+351
+00:31:44,750 --> 00:31:49,670
+ال hydrogen halidesالان هذا التفاعل سبق اننا
+
+352
+00:31:49,670 --> 00:31:54,870
+شرحناه لكن بنعيد نأكد عليه مرة ثانية ال alcohol مع
+
+353
+00:31:54,870 --> 00:32:00,370
+ال hydrogen halide بيبدل ال OH ب X بيعطيني RX زائد
+
+354
+00:32:00,370 --> 00:32:06,290
+H2O الان لو اتيت انا اتطلعت على ال alcohol ايش
+
+355
+00:32:06,290 --> 00:32:10,900
+ممكن يكون ال alcohol ممكن يكون tertiaryو secondary
+
+356
+00:32:10,900 --> 00:32:14,800
+و primary افضل اش هيتفاعل مع ال tertiary ال
+
+357
+00:32:14,800 --> 00:32:24,040
+hydrogen halides ممكن تكون يود و بروم و كلور واضح؟
+
+358
+00:32:25,040 --> 00:32:28,740
+الـ hydrogen halides يا يود يا بروم يا كلور، مين
+
+359
+00:32:28,740 --> 00:32:32,420
+أحسن واحدة بتتفعل؟ أفضل من البروم، أفضل من الكلور
+
+360
+00:32:32,420 --> 00:32:36,580
+والالكهول تيرتشري أفضل من سكندريا، أفضل من إيش؟ ال
+
+361
+00:32:36,580 --> 00:32:41,280
+primary بناء على ذلك، لو أنا أجي اتفعلت أي ألكهول
+
+362
+00:32:41,280 --> 00:32:47,660
+من هدولة مع يود أو بروم، يعني مع HI أو HPR، هيتفعل
+
+363
+00:32:47,660 --> 00:32:53,360
+بدون مشاكل ويعمل إبدالهتصير المشكلة وين؟ لو بدأ
+
+364
+00:32:53,360 --> 00:32:59,060
+ضقة فاعل، الأضعف هان مع الأضعف هان، بتمشي التفاعل
+
+365
+00:33:00,250 --> 00:33:05,650
+بشكل عام يعني لو أخدت ال primary alkyl halide مع
+
+366
+00:33:05,650 --> 00:33:10,450
+HCl مش هيعمل إبدال يعني لو أخدت ال ethanol مع ال
+
+367
+00:33:10,450 --> 00:33:16,090
+HCl إيثانول مع HCl بيعمل إبدال إيثانول primary HCl
+
+368
+00:33:16,090 --> 00:33:20,250
+للأضعف بيعملش إبدال بعد ذلك خدوا على سبيل المثال
+
+369
+00:33:20,250 --> 00:33:25,890
+high tertiary alkyl halide ملاحظين انتوا؟ مع HCl
+
+370
+00:33:25,890 --> 00:33:29,070
+عمل
+
+371
+00:33:29,070 --> 00:33:34,250
+إبدالTertiary Alkylide مع HCl عمل إبدالة اللي ما
+
+372
+00:33:34,250 --> 00:33:42,010
+بيعملش أي واحد ال primary مع ال HCl يمكن هنا مرات
+
+373
+00:33:42,010 --> 00:33:45,270
+التفاعل بيكون إيش قوي زي التانين يعني حطوله
+
+374
+00:33:45,270 --> 00:33:50,670
+catalyst zinc chloride ما بضرش مش مشكلة بس بيمشي
+
+375
+00:33:50,670 --> 00:33:57,220
+في الآخر واضح؟ بيمشيحتى لو أخدت secondary alcohol
+
+376
+00:33:57,220 --> 00:34:01,200
+ماقعدش CL في وجود ذنك كلورادي و شوية تسخين بمشي
+
+377
+00:34:01,200 --> 00:34:06,560
+لكن مين اللي فيه المشكلة ال primary؟ اه مع ال FCL
+
+378
+00:34:06,560 --> 00:34:12,580
+لاحظوا هنا عشان هيك بنلاقي حلول بديلة لما يصير عند
+
+379
+00:34:12,580 --> 00:34:17,340
+primary لو قلتلكوا ماقعدش CL إيش الجواب؟ نوريا
+
+380
+00:34:20,520 --> 00:34:24,140
+بدّو البني آدم هيك هيك لازم يحوّل الـ OH لـCl
+
+381
+00:34:24,140 --> 00:34:28,180
+بيغير ال reagent يعني لو استعمل ال primary مع ال
+
+382
+00:34:28,180 --> 00:34:35,080
+BCL3 فوسفوراس الـ Trichloride بيعمل تفاعل واضح؟
+
+383
+00:34:35,080 --> 00:34:38,780
+يعني ال primary الكهول مع فوسفوراس ال Trichloride
+
+384
+00:34:38,780 --> 00:34:43,080
+بتفاعل بيبدّي ال OH بCL لكن مع ال HCL لأ بتفاعل
+
+385
+00:34:43,080 --> 00:34:47,320
+وغير الفوسفوراس ال Trichloride أخدنا كمان reagent
+
+386
+00:34:47,320 --> 00:34:56,800
+SOCL2 هذا مشهور بيسميه ثيونيليكلورايد واضح؟ برضه
+
+387
+00:34:56,800 --> 00:35:02,920
+هذا ايش بيعمل؟ بتفاعل و بيبدل ال OH ل ال primary
+
+388
+00:35:02,920 --> 00:35:08,880
+بCL فسواء استعملت الفوسفوراس ال trichloride او
+
+389
+00:35:08,880 --> 00:35:12,380
+الثيونيليكلورايد بقدر اعمل التفاعل لكن لو استعملت
+
+390
+00:35:12,380 --> 00:35:19,650
+ال HCl بمشيش التفاعلطبعا ما عدا ذلك مع اليود و مع
+
+391
+00:35:19,650 --> 00:35:23,730
+البروم بيمشي مع كله تيرتشاري .. سكندر .. برايماري
+
+392
+00:35:23,730 --> 00:35:29,370
+.. يعني المشكلة حقيقة بين ال primary و ال hcl في
+
+393
+00:35:29,370 --> 00:35:32,150
+حلول بديلة ولا لأ؟ كم حل؟
+
+394
+00:35:40,460 --> 00:35:46,160
+هي هنا على سبيل المثال ال primary مع ال SOCl2
+
+395
+00:35:46,160 --> 00:35:51,480
+بتفاعل مية في المية الان لاحظوا ان هذا التفاعل
+
+396
+00:35:51,480 --> 00:35:57,100
+تفاعل إبدال ال OH ب X خاص بال alcohol يعني ال
+
+397
+00:35:57,100 --> 00:36:03,950
+phenols لا يتم عليها إبداليعني لو قلنا لكوا ال A R
+
+398
+00:36:03,950 --> 00:36:16,610
+O H مع HBR مع HCL مع BCL3 مع SOCL2 بكل لغات الأرض
+
+399
+00:36:16,610 --> 00:36:25,460
+لا تتفاعل مافيش إبدال علىالاروماتيك كومباونز لإيش؟
+
+400
+00:36:25,460 --> 00:36:29,400
+لأنه أنا هنا بدي أجيب سالب الـ nucleophile سالب و
+
+401
+00:36:29,400 --> 00:36:32,740
+أخليه يهاجم على البنزينة و احنا من البداية اتفقنا
+
+402
+00:36:32,740 --> 00:36:36,080
+انه الإبدال اللي على البنزين Electrophilic
+
+403
+00:36:36,080 --> 00:36:39,460
+Substitution in general واضح؟ يعني انا لو اجيت
+
+404
+00:36:39,460 --> 00:36:43,740
+افعل مع هدولة في النهاية هاجيب PR minus او I minus
+
+405
+00:36:43,740 --> 00:36:47,960
+minus على minus بيصير و لذلك الإبدالات اللي هنا
+
+406
+00:36:47,960 --> 00:36:53,940
+كلها اللي أخدناها هي متعلقةبالكحولات بال R O H لكن
+
+407
+00:36:53,940 --> 00:36:58,440
+لو صارت A R O H بنزينة أو حملة O H و قلتلكوا
+
+408
+00:36:58,440 --> 00:37:03,740
+بدلوها ب C L و ب R لأواضح؟ هنا مافيش substitution
+
+409
+00:37:03,740 --> 00:37:07,840
+في ال aromatic compounds ال substitution في إيش؟
+
+410
+00:37:07,840 --> 00:37:12,200
+في ال aliphatic compounds تبوا هذا الكلام ممكن
+
+411
+00:37:12,200 --> 00:37:16,440
+نسألكوا يا صح و غلط aromatic alcohols undergo
+
+412
+00:37:16,440 --> 00:37:22,540
+substitution in uneasy manner مثلا ولا .. no they
+
+413
+00:37:22,540 --> 00:37:26,320
+don't undergo substitution
+
+414
+00:37:30,300 --> 00:37:34,040
+ما هو الـ Electrophilic Substitution بيبطل في هذه
+
+415
+00:37:34,040 --> 00:37:38,420
+الحالة للـ OH بيصير في مكان تاني على البنزينة
+
+416
+00:37:38,420 --> 00:37:44,520
+بيختلف التفاعل يعني زي ما تجيب فينول و بدك تعمل
+
+417
+00:37:44,520 --> 00:37:50,200
+مثلا مع الchlor FeCl3 على سبيل المثال أو تاخد O
+
+418
+00:37:50,200 --> 00:37:57,880
+Methyl بتصير تبدل هنا بتبدل Hydrogens مش بتبدلطبعا
+
+419
+00:37:57,880 --> 00:38:01,320
+المشكلة ان الفينول نفسه بعارض مع ال FEC الاتنين
+
+420
+00:38:01,320 --> 00:38:05,420
+افترض او مثل مثلا بتبدليش ال او مثل بتبدلي ايش
+
+421
+00:38:05,420 --> 00:38:11,540
+بتبدلي على الحلقة هيدروجينات بتبدلي هيدروجينات على
+
+422
+00:38:11,540 --> 00:38:20,140
+الحلقة الان ال alcohol من تفاعلاتها الشهيرة تفاعل
+
+423
+00:38:20,140 --> 00:38:25,720
+ال oxidation خليني اقول ايش معنى ال oxidationال
+
+424
+00:38:25,720 --> 00:38:29,920
+Oxidation بلغة الكيميا ما انا عارف ترجمتها انه
+
+425
+00:38:29,920 --> 00:38:34,900
+افقد ال H تبعت ال OH يعني لو انا اطلعت على المركب
+
+426
+00:38:34,900 --> 00:38:41,420
+CHOH زي هيك و ايش ما كان يكون عندى هنا ان افقد
+
+427
+00:38:41,420 --> 00:38:47,910
+جزئها هيدروجينأفقد الـ H اللي على الأكسجين و H على
+
+428
+00:38:47,910 --> 00:38:52,310
+الكربون المتسقة بها الأكسجين مباشرة الآن هدولة لو
+
+429
+00:38:52,310 --> 00:38:56,550
+فقدوا زي هيك على شكل جزء هيدروجين هذه إيش بنتيجة
+
+430
+00:38:56,550 --> 00:39:02,950
+تعمل هنا double bond طالما عملت double bond شو
+
+431
+00:39:02,950 --> 00:39:09,330
+هيصير النتج الديهايد أو كيتونباعتمد على هدول
+
+432
+00:39:09,330 --> 00:39:13,130
+المجموعتين خلّينا نكون في البداية فاهمين قصة
+
+433
+00:39:13,130 --> 00:39:18,950
+الأكسدة الأكسدة معناها ان ال COH بيصير C double
+
+434
+00:39:18,950 --> 00:39:24,090
+bond O طالما C double bond O صارت اذا صارت الجهاي
+
+435
+00:39:24,090 --> 00:39:29,870
+او كيتون هتفقد ال H تعطي ال OH OH عن الكربون اللي
+
+436
+00:39:29,870 --> 00:39:35,790
+هنا اول سؤال هيجيكم طب يا ترى لو فيش هنا H
+
+437
+00:39:38,560 --> 00:39:43,880
+يعني لو هذه كانت R و R و R فى عندي OH مستعدة تفقد
+
+438
+00:39:43,880 --> 00:39:48,860
+ال H بس فىش هنا H يعني صار إيش نوع ال alcohol?
+
+439
+00:39:50,620 --> 00:39:55,800
+tertiary واضحة؟ يعني افترضوا هذه كانت C وهذه C
+
+440
+00:39:55,800 --> 00:40:02,370
+وهذه C CH3 CH3 CH3 هنا فى H هنا مافيش Hبدوا يتم
+
+441
+00:40:02,370 --> 00:40:07,270
+الأكسدة؟ إذا على طول هنطلع قاعدة أن الـ tertiary
+
+442
+00:40:07,270 --> 00:40:11,070
+alcohols اللي مافيش عليهم هيدروجينة هنا بتأكسدوش
+
+443
+00:40:11,070 --> 00:40:17,150
+إذا التأكسد خاص بماذا؟ ال primary و ال secondary
+
+444
+00:40:17,150 --> 00:40:22,090
+التيرتشاري مابصله أكسدة ليش؟ لأن الأكسد بدأ أفقد
+
+445
+00:40:22,090 --> 00:40:25,130
+من ال OH هيدروجينة و من الكربون اللي حامله
+
+446
+00:40:25,130 --> 00:40:27,850
+هيدروجينة طب الكربون اللي حامله مش حامله هيدروجينة
+
+447
+00:40:28,820 --> 00:40:33,540
+إذا الأكسدة لا تتم مع إيش؟ مع ال tertiary
+
+448
+00:40:33,540 --> 00:40:37,860
+alcohols، الآن مع ال primary وال secondary؟ بالتم،
+
+449
+00:40:37,860 --> 00:40:44,160
+شو بدها تعطيني؟الديهايد او كيتون وقت ايش بتعطي
+
+450
+00:40:44,160 --> 00:40:49,760
+الديهايد و وقت ايش بتعطي كيتون ال primary ببساطة
+
+451
+00:40:49,760 --> 00:40:55,480
+بيعطي الديهايد و ال secondary بيعطي كيتون واضح؟
+
+452
+00:40:55,480 --> 00:40:59,380
+اذا كأنه لو الانسان بده يلخص الكلام ان ال alcohol
+
+453
+00:40:59,380 --> 00:41:03,920
+في كام نوع؟ primary secondary و tertiary ال
+
+454
+00:41:03,920 --> 00:41:11,080
+tertiaryكفى الله المؤمنين القتال ..مش فيها كلمة شر
+
+455
+00:41:11,080 --> 00:41:17,300
+..وكفى الله المؤمنين القتال ال tertiary بتأكسدش ال
+
+456
+00:41:17,300 --> 00:41:22,400
+primary لما يتأكسد شو هيعطيني ال dihyde ال
+
+457
+00:41:22,400 --> 00:41:28,130
+secondary لما يتأكسد شو هيعطيني كيتونلحظته هيك
+
+458
+00:41:28,130 --> 00:41:34,290
+بيصير العلم ايش ماله؟ سهل انه ال alcohols تلاتة ال
+
+459
+00:41:34,290 --> 00:41:38,630
+primary او ال secondary او ال tertiary ال primary
+
+460
+00:41:38,630 --> 00:41:44,560
+هيعطيني aldehyde ال secondary كيتون ال tertiaryمش
+
+461
+00:41:44,560 --> 00:41:50,320
+حيت أكسد الان المرة الجاية بتجيجتين هنوضح ايش
+
+462
+00:41:50,320 --> 00:41:54,440
+العامل المؤكسد اللي بتتم فيه العملية يعني نبدأ من
+
+463
+00:41:54,440 --> 00:41:58,820
+هذه بنشرحها بتجيجتين وننتبه ان ال الديهايد ممكن
+
+464
+00:41:58,820 --> 00:42:06,400
+بعدين يعمل تفاعل تاني يصير أسد هذه زيادة واضح؟ لكن
+
+465
+00:42:06,400 --> 00:42:12,560
+الأكسد الأساسية الأولى ال primary شو بيصير؟الـ
+
+466
+00:42:12,560 --> 00:42:17,640
+secondary الـ tertiary لا يتأكسد الان ال primary
+
+467
+00:42:17,640 --> 00:42:22,200
+بعد ما يصير الديهاي ممكن لو العامل المؤكسد قوي
+
+468
+00:42:22,200 --> 00:42:28,660
+يمشي كمان مرحلة يصير أسد لو ضعيف بيظل زي ما هو إذا
+
+469
+00:42:28,660 --> 00:42:32,340
+بتصير قصتنا إيش العامل المؤكسد اللي استعملنا هان و
+
+470
+00:42:32,340 --> 00:42:37,340
+هان هان من الأساس مافيش أكسدة من هذه المقطة ان شاء
+
+471
+00:42:37,340 --> 00:42:40,120
+الله بنبدأ المرة الجاية
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b1ff61fb564655edd9f3fec95105a569bd4a5b59
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_raw.srt
@@ -0,0 +1,2012 @@
+1
+00:00:20,330 --> 00:00:25,410
+بسم الله الرحمن الرحيم اليوم ان شاء الله درسنا مش
+
+2
+00:00:25,410 --> 00:00:30,670
+في موضوع معين لأ هو مراجعة شاملة من خلال حل
+
+3
+00:00:30,670 --> 00:00:36,320
+الامتحانات السابقة استعدادا للامتحانالنصفي ربما
+
+4
+00:00:36,320 --> 00:00:40,320
+أحيانا اتلاحظوا بعض الأسئلة لامتحان النصفي كان
+
+5
+00:00:40,320 --> 00:00:44,380
+للفصل السابع المرة هذه طلبنا منكوا للفصل السادس
+
+6
+00:00:44,380 --> 00:00:49,160
+فمش مشكلة يعني الإنسان بيقدر يعرف الأسئلة هتلاحظوا
+
+7
+00:00:49,160 --> 00:00:54,980
+ان في عندنا أسئلة متنوعة بشكل عام دائما ننصح
+
+8
+00:00:54,980 --> 00:01:01,250
+الطلاب انه يهتموابالأفكار الأساسية العامة يكونوا
+
+9
+00:01:01,250 --> 00:01:06,030
+فاهمينها بنسبة أكبر هذا بمنعش أنه في أشياء متخصصة
+
+10
+00:01:06,030 --> 00:01:09,730
+لكن دائما الطالب أول شيء يجب أن يكون عنده يعني
+
+11
+00:01:09,730 --> 00:01:14,190
+قناع أن هو فاهم الاشي الأفكار العامة ولذلك ربما
+
+12
+00:01:14,190 --> 00:01:19,110
+تلاحظوا أنه يعني لو أنا بدأ أصنف الأسئلة مش في هذا
+
+13
+00:01:19,110 --> 00:01:24,450
+الامتحان في معظم الامتحانات هنكتشف أنه هي عنوين
+
+14
+00:01:25,470 --> 00:01:30,250
+يعني هي عنوين لأشياء احنا درسناها خلينا نشوف هذا
+
+15
+00:01:30,250 --> 00:01:35,710
+الكلام من خلال التطبيق الآن في هذا الامتحان اللي
+
+16
+00:01:35,710 --> 00:01:41,350
+أمامنا في عندنا مجموعة من الجمال هذه المجموعة من
+
+17
+00:01:41,350 --> 00:01:46,450
+الجمال بدنا نكمل الفراغ فيها complete the
+
+18
+00:01:46,450 --> 00:01:50,450
+following السؤال أول مثلا بيسألنا الدياستيريو
+
+19
+00:01:50,450 --> 00:01:55,210
+مارزهاف و بيحكي عن ال physical propertiesالان كان
+
+20
+00:01:55,210 --> 00:01:58,970
+واضح تماما ان ال بيستيريو مارز هيف different
+
+21
+00:01:58,970 --> 00:02:02,390
+physical
+
+22
+00:02:02,390 --> 00:02:10,670
+properties واضح الان السؤال التاني addition of HBr
+
+23
+00:02:10,670 --> 00:02:17,410
+H plus to isobutene produces لاحظوا هنا السؤال هذا
+
+24
+00:02:17,410 --> 00:02:22,070
+في فكرتين ان الطالب لازم في الأول يعرف ايش هو ال
+
+25
+00:02:22,070 --> 00:02:28,970
+isobuteneهذا ال isobutene واضح بعد هيك إضافة ال
+
+26
+00:02:28,970 --> 00:02:35,930
+HBR H plus معناه ذلك هذه إضافة حسب Markov-Nikov
+
+27
+00:02:35,930 --> 00:02:40,670
+addition يعني هذه بدها تروح يجي عند هنا H و يجي
+
+28
+00:02:40,670 --> 00:02:44,070
+عند هنا CL او PR و بنحكي عن PR
+
+29
+00:02:47,350 --> 00:02:53,650
+الان هذا المركب اللى طلع عندى carbon حاملة CH3 CH3
+
+30
+00:02:53,650 --> 00:03:01,230
+CH3Br هذه مجموعة لها اسم ولا لأ تيرتشاري بيوتل
+
+31
+00:03:01,230 --> 00:03:09,310
+إبرومايد produces tertiary butyl bromide من تسمية
+
+32
+00:03:09,310 --> 00:03:16,810
+المجموعات produces tertiary butyl bromideالان فكرة
+
+33
+00:03:16,810 --> 00:03:20,890
+عامة قلنا ال branched alkanes اللي هم ال boiling
+
+34
+00:03:20,890 --> 00:03:23,930
+point و ال melting point lower than ال chain
+
+35
+00:03:23,930 --> 00:03:28,390
+alkanes الان ال branched alkanes هم اكيد هنا هتكون
+
+36
+00:03:28,390 --> 00:03:32,110
+higher او lower boiling point than the
+
+37
+00:03:32,110 --> 00:03:37,890
+corresponding chain lower ال
+
+38
+00:03:37,890 --> 00:03:44,850
+curved arrows قلنا عنهمالهم رأسين are used to
+
+39
+00:03:44,850 --> 00:03:53,830
+indicate the movement of two electrons ممتاز ال
+
+40
+00:03:53,830 --> 00:04:00,350
+reaction المهم من البنزين هو أي تحديد تحديد
+
+41
+00:04:00,350 --> 00:04:07,070
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+42
+00:04:07,070 --> 00:04:10,130
+الهواتف الهواتف
+
+43
+00:04:10,130 --> 00:04:10,910
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+44
+00:04:10,910 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+45
+00:04:11,090 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+46
+00:04:11,090 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+47
+00:04:11,090 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف ال
+
+48
+00:04:11,810 --> 00:04:24,490
+الكلهيليتز اليوكليوفيليك اليوكليوفيليك
+
+49
+00:04:28,790 --> 00:04:33,570
+Dipromination of a Neopentane gives a total of ..
+
+50
+00:04:33,570 --> 00:04:38,110
+لاحظوا معي تكونوا عارفين لـ Neopentane يعني أنا
+
+51
+00:04:38,110 --> 00:04:41,950
+هنا باختبركم أن تكونوا عارفين هذا المُركّب لـ
+
+52
+00:04:41,950 --> 00:04:45,470
+Neopentane اللي هي الكربون اللي حاملة كام مثل؟
+
+53
+00:04:45,470 --> 00:04:49,910
+أربعة الأربعة الأربعة دي دي Dipromination
+
+54
+00:04:51,580 --> 00:04:57,320
+يعني احض ذرتين abroad كم ناتج بتوقع التنتين ممكن
+
+55
+00:04:57,320 --> 00:05:00,880
+ييجوا على نفس الذرع اذا اجوا تنتين هان زي هان زي
+
+56
+00:05:00,880 --> 00:05:08,060
+هان و ممكن ييجوا علىدرتين مختلفتين يعني ايه ييجي
+
+57
+00:05:08,060 --> 00:05:12,460
+هان و هان لحظوا هان و هان زي هذه و هذه زي هذه و
+
+58
+00:05:12,460 --> 00:05:15,860
+هذه زي هذه و هذه لأن المجموعات كلها ماخدة
+
+59
+00:05:15,860 --> 00:05:19,140
+tetrahedral arrangement متذكرين لما كنا نقول مافيش
+
+60
+00:05:19,140 --> 00:05:23,100
+اشي اسمه مجموعتين جان بعض و اشي اسمه مجموعتين قبال
+
+61
+00:05:23,100 --> 00:05:27,280
+بعض يعني تيجي طالبة تقول حط ال .. البروم هان و هان
+
+62
+00:05:27,280 --> 00:05:30,860
+بتختلف عن البروم هان و هان لأ هذه الزاوية PR, CPR
+
+63
+00:05:30,860 --> 00:05:37,280
+قداش مقدارهامية و تسعة و نص كربون حملة PR كربون كم
+
+64
+00:05:37,280 --> 00:05:40,640
+.. كربون حملة PR كدهش مقدارها؟ مية و تسعة و نص إذا
+
+65
+00:05:40,640 --> 00:05:45,260
+كم ناتج هنا؟ أربعة ليش أربعة؟ مش هو two bromine
+
+66
+00:05:45,260 --> 00:05:50,800
+atoms طيب انا .. انا حطيت two bromine atoms أو
+
+67
+00:05:50,800 --> 00:05:53,720
+حطيت وحدها وحدها هاي معناه die bromination طيب و
+
+68
+00:05:53,720 --> 00:05:57,100
+لو حطنا على ال carbon نفل نص ال carbon نفل نص
+
+69
+00:05:57,100 --> 00:05:58,540
+بيصير على خمس روابط؟
+
+70
+00:06:01,850 --> 00:06:05,670
+يا التنتين على هذه الذرة، يا التنتين كل واحدة على
+
+71
+00:06:05,670 --> 00:06:11,690
+ذرة، سواء كانت هان أو هان أو هان، إذا كان مركب two
+
+72
+00:06:11,690 --> 00:06:15,910
+isomers، structural isomers of course
+
+73
+00:06:18,990 --> 00:06:24,790
+The IUPAC name of allyl chloride لاحظوا كام سؤال
+
+74
+00:06:24,790 --> 00:06:28,970
+صار جايكم اؤكد انكوا تكونوا عارفين المجموعات
+
+75
+00:06:28,970 --> 00:06:32,150
+والمركبات الأساسية اللي أخدناها جيبنا ال tertiary
+
+76
+00:06:32,150 --> 00:06:38,430
+butyl هاي جيبنا ال allyl اللي هي CH2 CH double
+
+77
+00:06:38,430 --> 00:06:44,770
+bond CH2 Hanachlor وقولنا سابقا ان هذا بدو يتسمى
+
+78
+00:06:44,770 --> 00:06:53,810
+واحد اتنينتلاتة اذا three chloro one
+
+79
+00:06:53,810 --> 00:07:04,450
+propene three chloro one propene واضح؟
+
+80
+00:07:04,450 --> 00:07:09,150
+فحفظ المجموعات بين القليل ايزو بروبيل ايزو بيوتل
+
+81
+00:07:09,150 --> 00:07:13,250
+اساسي جداgeneration of the second chiral center
+
+82
+00:07:13,250 --> 00:07:19,290
+produces unequal mixture of diastereomers هذا أكمل
+
+83
+00:07:19,290 --> 00:07:26,470
+الجواب، هيك العنوان صح ولا لأ؟ unequal mixture of
+
+84
+00:07:26,470 --> 00:07:32,470
+diastereomers والfirst
+
+85
+00:07:32,470 --> 00:07:36,350
+chiral center شو كان بيعمل؟ racemic mixture of
+
+86
+00:07:36,350 --> 00:07:42,090
+enantiomers the meso compound is opticallyinactive
+
+87
+00:07:42,090 --> 00:07:47,630
+كان عنوان meso compounds are optically inactive
+
+88
+00:07:47,630 --> 00:07:54,790
+واضح هي دي مراجعة شاملة خلينا نقوله بعتقد جميلة
+
+89
+00:07:54,790 --> 00:07:59,930
+لمفاهيم أساسية أخدناها واضحة
+
+90
+00:08:12,680 --> 00:08:18,980
+الان بعد هيك ارسمولنا أشكال بعض المركبات
+
+91
+00:08:18,980 --> 00:08:22,000
+Cyclobentane
+
+92
+00:08:22,000 --> 00:08:26,500
+مين ما بيعرفوا ال Cyclobentane؟ هاي ال
+
+93
+00:08:26,500 --> 00:08:30,500
+Cyclobentane أسس على نمرة واحد و تلت يعني لو قولنا
+
+94
+00:08:30,500 --> 00:08:38,230
+هنا مثلا خلينا نحط إبروم للأمام وهنابروم هاي واحد
+
+95
+00:08:38,230 --> 00:08:43,990
+اتنين تلاتة وستعملنا
+
+96
+00:08:43,990 --> 00:08:51,070
+الشكل الفراغي عشان نبين انه مجموعتين للامام الان
+
+97
+00:08:51,070 --> 00:08:58,450
+Cyclohexane نعرف ال Cyclohexane هاي Cyclohexane
+
+98
+00:08:58,450 --> 00:09:03,980
+والترقيم بيكون واحدتنين و نستمر نمر عبر ال double
+
+99
+00:09:03,980 --> 00:09:09,280
+bond صح ولا لأ يعني واحد اتنين تلاتة اربعة خمسة
+
+100
+00:09:09,280 --> 00:09:12,280
+ستة الان على نمرة اتنين ايش في اندي في ال
+
+101
+00:09:12,280 --> 00:09:24,860
+Cyclohexane بروم وعلى نمرة تلاتة isopropyl for
+
+102
+00:09:24,860 --> 00:09:32,020
+nitroicumin اخدنا الاكيومين انه ال isopropylبنزين
+
+103
+00:09:32,020 --> 00:09:38,360
+قلنا ايزوبروب البنزين is كيومين لما بتحط على
+
+104
+00:09:38,360 --> 00:09:49,060
+الأربعة ن او اتو for نيترو كيومين الان المركب هذا
+
+105
+00:09:49,060 --> 00:09:54,420
+بدنا نسميه اين و اين ضايقين
+
+106
+00:09:55,420 --> 00:10:01,040
+لما بدنا ننتبه من وين بدنا نعمل الترقيم يعني واحد
+
+107
+00:10:01,040 --> 00:10:06,460
+اتنين تلاتة اربعة خمسة و هنا في كمان carbon ستة
+
+108
+00:10:06,460 --> 00:10:10,840
+طبعا لاحظوا انه انا لو برقم من هنا بيكون double
+
+109
+00:10:10,840 --> 00:10:16,120
+points عند اتنينوخمسة لو برقم هنا عند واحد اتنين
+
+110
+00:10:16,120 --> 00:10:19,860
+واحد واربعة لازم اسعى ان ال double poles يكونوا
+
+111
+00:10:19,860 --> 00:10:25,160
+اقل ترقيم اذا هذا هقول واحد اتنين تلاتة اربعة خمسة
+
+112
+00:10:25,160 --> 00:10:33,960
+ستة فهذا المركب هيكون one four hexadien
+
+113
+00:10:33,960 --> 00:10:41,370
+ايش بيحمل على نمرة تلاتة وعلى نمرة اربعةأه إذا هذا
+
+114
+00:10:41,370 --> 00:10:49,490
+كمان بدو ييجي عليه three four diapromo one four
+
+115
+00:10:49,490 --> 00:10:55,660
+الآن هذا double bondمافيش عليها مجموعات مختلفان و
+
+116
+00:10:55,660 --> 00:10:58,500
+.. يعني مافيش فيها ظاهرة ال sexual trance بس هذا
+
+117
+00:10:58,500 --> 00:11:02,700
+ال double bond فيها .. يعني هنا في عندى مثل و أتش،
+
+118
+00:11:02,700 --> 00:11:07,040
+لاحظوا كل رأس زي هذا يعتبر مثل، انتبهوله في العد و
+
+119
+00:11:07,040 --> 00:11:12,110
+انتبهوله لما تشتغلوا، المثل أعلى من الأتشالمثل
+
+120
+00:11:12,110 --> 00:11:17,350
+أعلى من الـ H هنا PR و Carbon أنا باطلع فقط على
+
+121
+00:11:17,350 --> 00:11:20,470
+الذرة الأولى و الأولى هذه PR وهذه Carbon الآن
+
+122
+00:11:20,470 --> 00:11:25,410
+هذولا المجمعتين على جهة واحدة إذا هذا المركب Z
+
+123
+00:11:25,410 --> 00:11:31,610
+فلما بدي تسمية كاملة Z three four dibromo one four
+
+124
+00:11:31,610 --> 00:11:33,050
+hexadien
+
+125
+00:11:35,670 --> 00:11:38,790
+واضح؟ ال double bond التانية مافيش فيها أي شيء
+
+126
+00:11:38,790 --> 00:11:42,490
+طبعا واضح أنه هنا في chiral center لكن طالما أنا
+
+127
+00:11:42,490 --> 00:11:47,010
+ماحطتوش على شكل صليب معناه ذلك أنا مش مركز أني
+
+128
+00:11:47,010 --> 00:11:54,470
+اتحددولي IR أو استركتو مفتوح هذا المركب مثلا في
+
+129
+00:11:54,470 --> 00:11:58,330
+chiral center وموضح أنه أنا طالب ال chiral center
+
+130
+00:11:58,330 --> 00:12:06,270
+هنا واضح؟ لو أتيت طلعت أطول سلسلةانعلمها بالاحمر
+
+131
+00:12:06,270 --> 00:12:14,430
+واحد اتنين تلاتة اربعة اذا هذا بيوتين ايش بيحمل
+
+132
+00:12:14,430 --> 00:12:19,450
+هذا البيوتين على البيوتين واحد اتنين تلاتة اربعة
+
+133
+00:12:19,450 --> 00:12:26,870
+على نمرة واحد اكلور وعلى نمرة تلاتة فنل والترقيم
+
+134
+00:12:26,870 --> 00:12:29,770
+منها لان لو رقمتي منها هيصيروا على اتنين واربعة
+
+135
+00:12:29,770 --> 00:12:38,510
+بدي ال lower numbering اذا هذاone chloro three
+
+136
+00:12:38,510 --> 00:12:47,330
+phenyl بيوتين الان في chiral center ال chiral
+
+137
+00:12:47,330 --> 00:12:53,370
+center هنا ال H أقل مجموعة أكيد البنزينة نمرة واحد
+
+138
+00:12:53,370 --> 00:13:00,310
+الكاربون هذه نمرة اتنين وال CH3 نمرة تلاتةواحد
+
+139
+00:13:00,310 --> 00:13:06,870
+اتنين تلاتة وهذه موجودة اذا هذا اس one chlorine
+
+140
+00:13:06,870 --> 00:13:08,750
+three phenyl butane
+
+141
+00:13:15,300 --> 00:13:19,960
+المُركّب اللي بعده aromatic فيه مجموعتين، معنا ذلك
+
+142
+00:13:19,960 --> 00:13:24,020
+السؤال إنه مين أعلى في الأولوية عشان أسمه إيه؟ ال
+
+143
+00:13:24,020 --> 00:13:27,600
+ketone ولا ال alcohol؟ ال ketone، الآن هذا
+
+144
+00:13:27,600 --> 00:13:32,320
+المُركّب إيش اسمه؟ أسيتوفينون، نكتب small letter
+
+145
+00:13:34,690 --> 00:13:40,030
+acetophenon ال O H بترجع على أصلها ال three one
+
+146
+00:13:40,030 --> 00:13:45,710
+two three ال three أو ميتا هيدروكسي الشغلتين صح ال
+
+147
+00:13:45,710 --> 00:13:50,470
+three هيدروكسي أسيتوفينون كلمة واحدة واضح ال three
+
+148
+00:13:50,470 --> 00:13:57,030
+هيدروكسي أسيتوفينون بتيعني كل هذه من ضمن الأفكار
+
+149
+00:13:57,030 --> 00:14:01,610
+العامة الأساسية اللي احنا درسناكم
+
+150
+00:14:18,380 --> 00:14:25,580
+الان بعد ذلك عندى اكمال معادلات هذا المركب مثل
+
+151
+00:14:25,580 --> 00:14:32,160
+Cyclopropane مثل Cyclopropane وحطينا لكوا بدنا
+
+152
+00:14:32,160 --> 00:14:37,020
+نشوف all structural isomers يعني مش مركز انا على
+
+153
+00:14:37,020 --> 00:14:40,720
+ال stereo isomers او اعمله monochlorination يعني
+
+154
+00:14:40,720 --> 00:14:46,860
+احط one chlorine atomواضح؟ وين بده احط هذه ال
+
+155
+00:14:46,860 --> 00:14:55,400
+chlorine طبعا هنبدأ نرسم اكثر من شكل مش عارف تلاتة
+
+156
+00:14:55,400 --> 00:14:59,900
+اربعة بنجرب احنا الان اكيد ال chlorine بإمكانها
+
+157
+00:14:59,900 --> 00:15:06,810
+تيجي هنا على المثلوأكيد ال chlorine بإمكانها تيجي
+
+158
+00:15:06,810 --> 00:15:11,250
+على هذا الموقع وأكيد ال chlorine بإمكانها تيجي على
+
+159
+00:15:11,250 --> 00:15:15,510
+هذا الموقع لأن هذا و هذا زي بعض، ضال عندكم إشي
+
+160
+00:15:15,510 --> 00:15:21,170
+تاني؟ خلاص وكل
+
+161
+00:15:21,170 --> 00:15:23,210
+واحد فيهم أكيد إله اسم مختلف
+
+162
+00:15:29,980 --> 00:15:35,600
+الان لاحظوا معي هذا المركب فيه double bond بنقول
+
+163
+00:15:35,600 --> 00:15:40,880
+في نمر واحد بدنا نضيف عليه pear acid ايش معناه
+
+164
+00:15:40,880 --> 00:15:48,260
+pear acid انه بده يلغي هذه و يعملي حلقة لكن انا
+
+165
+00:15:48,260 --> 00:15:53,160
+كمان بعد ما عملت هذه الحلقة بده اعمل ring opening
+
+166
+00:15:53,160 --> 00:15:59,920
+ضيفت ميهواضحة الفكرة؟ كيف هذي بتعمل ring opening؟
+
+167
+00:15:59,920 --> 00:16:07,240
+بيكونوا سن ولا أنتي؟ مجموعات ال OHS ال
+
+168
+00:16:07,240 --> 00:16:10,360
+ring opening من البرأس الانتي
+
+169
+00:16:12,610 --> 00:16:17,550
+هي الميه من وين بتيجي عكس هذه اللي كان يعمل sin
+
+170
+00:16:17,550 --> 00:16:22,350
+addition لمجموعتين OH الكيامان O4 والأزوميوم O4
+
+171
+00:16:22,350 --> 00:16:27,590
+أخدناهم بيعملوا sin addition لمجموعتين OH لكن بهذه
+
+172
+00:16:27,590 --> 00:16:31,890
+الطريقة بنطلع ال Anti product اللي كان واضح تماما
+
+173
+00:16:31,890 --> 00:16:37,350
+يعني بدكوا تحطوا OH على جهة و OH على الجهة التانية
+
+174
+00:16:37,350 --> 00:16:42,720
+بالتأكيد هنا هتكون هذه المجموعة هيكهيأجوا اشمالهم
+
+175
+00:16:42,720 --> 00:16:47,880
+انتي طبعا
+
+176
+00:16:47,880 --> 00:16:51,600
+اي واحدة متذاكرة جيدا مش ضروري تفكر تعمل زي هيك
+
+177
+00:16:51,600 --> 00:16:54,900
+خلاص هو ال bare acid و بعدين نعمل ring opening في
+
+178
+00:16:54,900 --> 00:17:00,660
+الميه هذا محصلته في الدماغ بيحط مجمعتين OH انتي
+
+179
+00:17:00,660 --> 00:17:09,120
+انتي طبعا الان لما نضيف H2 في وجود platinum
+
+180
+00:17:20,030 --> 00:17:25,790
+هذا المُركّب اللي فيه ال PR لحظة انا هنا حاططلكم
+
+181
+00:17:25,790 --> 00:17:29,290
+KOH و جايلكم ان انا بدي ال major elimination
+
+182
+00:17:29,290 --> 00:17:33,950
+product كأني بقول انو حطوا double bond هان او هان
+
+183
+00:17:33,950 --> 00:17:39,750
+واضح انه كتير ركزنا معاكم انه the more substituted
+
+184
+00:17:39,750 --> 00:17:44,710
+ال keenوالـ Form حسب قاعدة Zaitsev إذا هنا بدو
+
+185
+00:17:44,710 --> 00:17:52,170
+ييجي ال الـ K واضح؟ مش هتيجي ال PR مع هذه ال H لأن
+
+186
+00:17:52,170 --> 00:17:56,530
+هذا less substituted ال K هذا ال more substituted
+
+187
+00:17:56,530 --> 00:18:00,890
+الآن بعد هيك هذا المركب بدنا نضيف عليه ميا في وجود
+
+188
+00:18:00,890 --> 00:18:06,590
+H plus هذا إضافة Markovnikov لحظة هنا في carbon
+
+189
+00:18:06,590 --> 00:18:12,190
+تحمل H و هذه ال carbon لأ تحملش H إذالو حطينا
+
+190
+00:18:12,190 --> 00:18:19,390
+الشكل العام بس بتكون المشكلة وين أحط ال H وين أحط
+
+191
+00:18:19,390 --> 00:18:30,150
+ال OH حسب
+
+192
+00:18:30,150 --> 00:18:36,430
+قاعدة Markovnikov لأنه في الأساس هنا في عندكم H
+
+193
+00:18:36,430 --> 00:18:38,650
+اللي كانت متروكة فاضية
+
+194
+00:18:56,340 --> 00:19:03,760
+الان هنا بدنا نضيف HPR في وجود البروكسايد اذا هنا
+
+195
+00:19:03,760 --> 00:19:09,600
+الإضافة مع ولا عكس قاعدة Markovnikov عكس قاعدة
+
+196
+00:19:09,600 --> 00:19:15,520
+Markovnikov لاحظوا لما انا هنا بد اضيف H على هذه
+
+197
+00:19:15,520 --> 00:19:21,870
+الجهة و ال PR على اللي بتحمل Hانتبهوا معي ال H هنا
+
+198
+00:19:21,870 --> 00:19:26,350
+طالما عندكم مثل و مثل ماعملتش chiral center هنا
+
+199
+00:19:26,350 --> 00:19:30,390
+لأن هدول المجموعتين زي بعض يعني مافيش اد اربع
+
+200
+00:19:30,390 --> 00:19:35,850
+مجموعات مختلفة لكن هنا بدي يكون عندكم مثل و H و
+
+201
+00:19:35,850 --> 00:19:44,410
+هتيجيها ب Rهي مثل وهي H و إيش هيجي عندك PR في هذه
+
+202
+00:19:44,410 --> 00:19:50,450
+الحالة حيصير في كايرال سنتر على هذا الكربون الان
+
+203
+00:19:50,450 --> 00:19:56,410
+ال generation و في كايرال سنتر شو بيطلعلك رسمك
+
+204
+00:19:56,410 --> 00:20:01,550
+mixture كان هذا عنوان إذا انا لما بدي أجي أشتغل
+
+205
+00:20:01,550 --> 00:20:07,250
+الأصل بدي أشتغل بهذا الشكلهدولة بأي طريقة تكتبوها
+
+206
+00:20:07,250 --> 00:20:10,370
+مافيش فيها مشكلة إطلاقا لأنه مش chiral center في
+
+207
+00:20:10,370 --> 00:20:14,410
+النهاية يعني
+
+208
+00:20:14,410 --> 00:20:19,050
+لو كتبيه بأي طريقة مش مشكلة لكن هنا بدي أجي مثلا
+
+209
+00:20:19,050 --> 00:20:25,470
+أقول ال PR هان ال PR عكسها ممكن نكتب ال H و ال H و
+
+210
+00:20:25,470 --> 00:20:30,710
+نكتبالـ CH3 والـ CH3 أهم شيء نعمله .. أهم شيء
+
+211
+00:20:30,710 --> 00:20:38,610
+نعمله أن هذه المنطقة يكونوا هذولة أشملهم عكس بعض و
+
+212
+00:20:38,610 --> 00:20:42,330
+هذولة بيطلعوا ال 50 50 ratio
+
+213
+00:20:44,190 --> 00:20:47,510
+الان بأي طريقة تكتبوها مافيش مشكلة مش هيكون خلاف
+
+214
+00:20:47,510 --> 00:20:51,270
+يعني واحدة كتبت هنا PR و هنا CH3 و هنا H و عملت
+
+215
+00:20:51,270 --> 00:20:54,770
+صورتها مش مشكلة واحدة كتبت هنا CH3 و هنا H و هنا
+
+216
+00:20:54,770 --> 00:21:01,330
+PR مافيش مشكلة اهم يعني ارسموا التلاتة بأي شكل
+
+217
+00:21:01,330 --> 00:21:06,150
+بدكم إياه بس حطوا صورتهم في المرايا لو احنا نفس
+
+218
+00:21:06,150 --> 00:21:08,930
+الشكل بس شيلنا لابتا ثنائية و حاطينا ال PR هيك و
+
+219
+00:21:08,930 --> 00:21:10,770
+هيك وين تحط ال PR؟
+
+220
+00:21:25,670 --> 00:21:29,510
+الان السؤال اللي بعده draw all the possible
+
+221
+00:21:29,510 --> 00:21:34,870
+isomers having the formula C3H4
+
+222
+00:21:35,800 --> 00:21:41,180
+الان عندما تفكر في هذا الكلام تفكر في صيغة العامة
+
+223
+00:21:41,180 --> 00:21:52,320
+للمركبات الوضع الطبيعي ال C3 بتاخد HS في
+
+224
+00:21:52,320 --> 00:21:59,470
+الألكال اللي كله single bonds يعني ال C3H8 في
+
+225
+00:21:59,470 --> 00:22:07,170
+الالكينز صح؟ الان اذا شيلت منها هيدروجينتين صارت
+
+226
+00:22:07,170 --> 00:22:12,870
+C3H6 مقابل ان شيلتم يا عملت bubble bond يا حلقة
+
+227
+00:22:12,870 --> 00:22:17,910
+الان لسه انا مش بس هيدروجنتين بده اشيل كمان تنتين
+
+228
+00:22:17,910 --> 00:22:22,690
+يعني شيلت هيدروجنتين وكمان هيدروجنتين معنى ذلك
+
+229
+00:22:22,690 --> 00:22:27,870
+التفكير اللي بده يكون عندكم اما تنتين bubble bonds
+
+230
+00:22:28,750 --> 00:22:35,290
+أو تنتين حلقات او حلقة و double bond واضح؟ لأن كل
+
+231
+00:22:35,290 --> 00:22:39,130
+هيدروجينتين معناهم ان انت شيلتوا ايش؟ يا عملتوا
+
+232
+00:22:39,130 --> 00:22:42,810
+double bond يا عملتوا حلقة واضح؟ فانا شيلت
+
+233
+00:22:42,810 --> 00:22:46,310
+هيدروجين مرتين بين التمانية والاربعة اربع
+
+234
+00:22:46,310 --> 00:22:50,750
+هيدروجينات تنتين و تنتين الآن بدكوا تقولوا يا
+
+235
+00:22:50,750 --> 00:22:54,790
+تنتين double bonds يا تنتين حلقات يا double bond
+
+236
+00:22:54,790 --> 00:23:01,040
+وحلقة طبعا ال C3H4 ما بتحتملتلتين حلقات يعني كلها
+
+237
+00:23:01,040 --> 00:23:05,860
+كم ذرة هي تلاتة بناء على ذلك لو أنا فكرت أني بدأ
+
+238
+00:23:05,860 --> 00:23:10,220
+أعمل منهم حلقة حلقة واحدة لازم ألاحقها بكمان ايش
+
+239
+00:23:10,220 --> 00:23:14,760
+double bond لاحظوا لو هنا اتيتوا تكملوا ال
+
+240
+00:23:14,760 --> 00:23:20,420
+hydrogens هتطلع الفورموله صح اتش اتش اتش اتش اتش
+
+241
+00:23:20,420 --> 00:23:23,500
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+242
+00:23:26,930 --> 00:23:32,270
+هذا الاحتمال اللى فيه حلقات الان بعد هيك ممكن اعمل
+
+243
+00:23:32,270 --> 00:23:37,870
+التنتين bubble bonds اعتبرهم ال kind triple bond
+
+244
+00:23:37,870 --> 00:23:48,130
+يعني احط C triple bond C و هنا CH3 CH3
+
+245
+00:23:48,130 --> 00:23:55,510
+و هذه H هدولة بمثابة تنتين bubble bonds هاي CH3
+
+246
+00:23:57,130 --> 00:24:02,770
+ممكن احط تنتين double bonds جانب بعض carbon double
+
+247
+00:24:02,770 --> 00:24:07,490
+bond carbon double bond carbon وهنا بدو يكون عندكم
+
+248
+00:24:07,490 --> 00:24:14,490
+CH2 CH2
+
+249
+00:24:14,490 --> 00:24:15,910
+في غير هيك؟
+
+250
+00:24:19,310 --> 00:24:23,910
+أهم شيء اللى بنى عليها هذا السؤال انه نفهم احنا ان
+
+251
+00:24:23,910 --> 00:24:31,610
+الصيغة المشبعة تماما لل C3 هي H8 الان مقابل كل
+
+252
+00:24:31,610 --> 00:24:35,990
+هيدروجينتين بخصومهم بدي اعمل double bond او حلقة
+
+253
+00:24:35,990 --> 00:24:41,170
+واضح فخصمت هيدروجنتين على كام مرة امرتين اربعة
+
+254
+00:24:41,170 --> 00:24:44,730
+تقسيم اتنين اتنين فهنا عملت حلقة و double bond هنا
+
+255
+00:24:44,730 --> 00:24:47,370
+عملت تنتين by bonds هنا عملت تنتين double bonds
+
+256
+00:24:49,120 --> 00:24:53,720
+ولما تكملوا الشكل كيميائيا شكل سليم 100% ولا لأ؟
+
+257
+00:25:08,560 --> 00:25:13,280
+الان هذا السؤال نمشي أسرع على تفاعل ال الكاينز
+
+258
+00:25:13,280 --> 00:25:17,380
+قلنا ال terminal الكاينز are acidic يعني هذا شو
+
+259
+00:25:17,380 --> 00:25:23,400
+بده يعطينا فنل C triple bond C minus الان إذا
+
+260
+00:25:23,400 --> 00:25:31,440
+فعلتوا مع إيثالبروميد CH3 CH2Br بده يعمل عليها ال
+
+261
+00:25:31,440 --> 00:25:36,890
+eucleophilic substitution هذه الكربون اتهاجمهاتطرد
+
+262
+00:25:36,890 --> 00:25:43,610
+ال PR ما هو ذا نيوكليو 5 إذا النتيجة فينيل C
+
+263
+00:25:43,610 --> 00:25:55,130
+triple bond C وهنا هياتحدت مع CH2 CH3 طردت ال PR
+
+264
+00:25:55,130 --> 00:26:02,330
+إبدالي نيوكليو فينيل الان هذا المركب مع ال lithium
+
+265
+00:26:02,330 --> 00:26:07,730
+و ال ammonia شو بيعمل؟Double bond هو اكيد بيضيف
+
+266
+00:26:07,730 --> 00:26:16,630
+الهيدروجين عكس بعض لكن مافيش فارق بالنتيجة هايو
+
+267
+00:26:16,630 --> 00:26:20,910
+الهيدروجين اللي ضفته كيف اجوا عكس بعض لكن المراكب
+
+268
+00:26:20,910 --> 00:26:26,810
+لا فيه cis ولا trans لأن هدوله زي بعض الان بعد هيك
+
+269
+00:26:26,810 --> 00:26:30,450
+هذا المراكب بتعمله اوزونوليسيز شو ال اوزونوليسيز
+
+270
+00:26:30,450 --> 00:26:35,130
+نكسر ال double bond لتنتين
+
+271
+00:26:36,290 --> 00:26:42,030
+C double bond O إذا
+
+272
+00:26:42,030 --> 00:26:47,130
+انكوّننا الألكين وبعدين كسرنا لتنتين C double bond
+
+273
+00:26:47,130 --> 00:26:48,830
+O هذا ال ozoneolysis
+
+274
+00:27:03,880 --> 00:27:10,080
+بعد هيك السؤال كيف ممكن نحضر المراكبات الآتية سيس
+
+275
+00:27:10,080 --> 00:27:15,900
+وانتو سايكلو بنتين دايول يعني
+
+276
+00:27:15,900 --> 00:27:26,420
+هنا سايكلو بنتين و OH و OH على جهة واحدة الآن أي
+
+277
+00:27:26,420 --> 00:27:32,140
+واحدة فيكوا شاطرة هتقول السيس كيف كنت أجيبه ترجع
+
+278
+00:27:32,140 --> 00:27:41,640
+برجوعالألكين مع الكيامان او فور في ال basic medium
+
+279
+00:27:41,640 --> 00:27:48,440
+او اوزميام او فور الان انا كنت حاكي هنا مابديش
+
+280
+00:27:48,440 --> 00:27:51,820
+ابدأ من ال cyclopentane مابدي ابدأ من ال promo
+
+281
+00:27:51,820 --> 00:27:58,240
+cyclopentane يعني هنا في عند بي ار الان يا تورا
+
+282
+00:27:58,240 --> 00:28:06,550
+هذه ال بي ار فيش جنب هاتشها اكيدبقدر استعمل KOH
+
+283
+00:28:06,550 --> 00:28:20,150
+بتصير ألكيل والألكيل بضيف عليه الميه starting
+
+284
+00:28:20,150 --> 00:28:29,490
+from بنزين برا نيترو كيومين هيلي
+
+285
+00:28:29,490 --> 00:28:35,410
+كيومين وحملة نيترواللي متذكرة هذي بتودي على الميتا
+
+286
+00:28:35,410 --> 00:28:39,790
+هذي Orthobara ال الكلي جروبز كلهم ال R Orthobara
+
+287
+00:28:39,790 --> 00:28:44,610
+الآن الوضع اللي موجود عندك اذا اول اشي انا بدي
+
+288
+00:28:44,610 --> 00:28:54,250
+اعمله اني بدي احضر هذا المركب وبعدين اه الان بيضل
+
+289
+00:28:54,250 --> 00:28:56,350
+ايش ال reagents ايزوبروبليكلورايد
+
+290
+00:28:56,350 --> 00:29:02,740
+ايزوبروبليكلورايد معالألمنيوميكلورايد او whatever
+
+291
+00:29:02,740 --> 00:29:11,080
+وبعدين هنا بدي اعمل نيتريشن بيطلع
+
+292
+00:29:11,080 --> 00:29:19,680
+ال ortho زائد البارا product واضح؟
+
+293
+00:29:21,290 --> 00:29:26,590
+هي الامتحان كامل مع الشريح والتفصيل الممل اعملناه
+
+294
+00:29:26,590 --> 00:29:29,350
+معاكم بطول الساعة اكيد لما يجيكوا انتوا كطلاب
+
+295
+00:29:29,350 --> 00:29:34,430
+هتاخدوا عليه ساعة لكن السؤال في حرف منه خارج عن
+
+296
+00:29:34,430 --> 00:29:37,590
+اللي درسته؟ الحمد لله ربنا
+
+297
+00:29:48,970 --> 00:29:54,650
+خلّينا نكسب الوقت و نحل امتحان من باب المراجعة
+
+298
+00:29:54,650 --> 00:29:58,030
+الشاملة
+
+299
+00:29:58,030 --> 00:30:16,490
+هذا
+
+300
+00:30:16,490 --> 00:30:27,530
+الامتحانالنمط تبعه في سؤال صح و غلط خلينا
+
+301
+00:30:27,530 --> 00:30:31,930
+نشوفه there are four types of hydrogen and
+
+302
+00:30:31,930 --> 00:30:37,170
+isobentane هذا بيستلزم ان انا اعرف ايش ال
+
+303
+00:30:37,170 --> 00:30:43,070
+isobentaneالان هاي ال eyes وبينتين كام نوع عندى من
+
+304
+00:30:43,070 --> 00:30:49,890
+ال hydrogens خلينا نقول هدول ال hydrogens زى بعض و
+
+305
+00:30:49,890 --> 00:30:59,490
+هدى و هدى و هدى نفس ايش؟ كيف؟
+
+306
+00:31:01,530 --> 00:31:06,390
+رجاءً لما بجيبلكوا سؤال ما تفكروش أنه أنواع ال
+
+307
+00:31:06,390 --> 00:31:10,970
+hydrogens أنه primary و secondary و tertiary مش
+
+308
+00:31:10,970 --> 00:31:14,590
+هذا اللي علمتكوا إياه إطلاقا، يعني من ال primary
+
+309
+00:31:14,590 --> 00:31:20,200
+ممكن يكون عندهكذا مجموعة برايمر لكن كل واحدة تمثل
+
+310
+00:31:20,200 --> 00:31:25,060
+نوع في الهيدروجينز واضح؟ عمره ماكان السؤال حددولي
+
+311
+00:31:25,060 --> 00:31:28,540
+كام نوع هيدروجينز انكوا تفكروا بكلمة برايمر و
+
+312
+00:31:28,540 --> 00:31:31,700
+سكندر و تيرتشل ولا هذا اللي علمناكم إياه يعني على
+
+313
+00:31:31,700 --> 00:31:36,520
+سبيل المثال على سبيل المثال حتى نأكد المعلومة الآن
+
+314
+00:31:36,520 --> 00:31:45,540
+لو حطيت هذا المركب هي هذه CH3 وهي هذه CH3 هذه زي
+
+315
+00:31:45,540 --> 00:31:51,700
+هذه؟لو حطيت هنا كلور بدل H من هنا زي ما حطي بدل H
+
+316
+00:31:51,700 --> 00:31:57,120
+من هنا مش كل CH3 بدي أقول عنها زي بعض ولا كل CH2
+
+317
+00:31:57,120 --> 00:32:04,380
+زي بعض لأ واضح؟ ولذلك هذا المركب الآن كام هيدروجين
+
+318
+00:32:04,380 --> 00:32:08,580
+فيه هدول المجمعتين زي بعض هي كمان نوع هي كمان نوع
+
+319
+00:32:08,580 --> 00:32:15,260
+هي كمان نوع أربع أنواع من الهيدروجين واضح؟طيب
+
+320
+00:32:15,260 --> 00:32:20,480
+احبطت شوية اتجاوزجالبة تقولي في هذا كام نوع من
+
+321
+00:32:20,480 --> 00:32:26,860
+الهيدروجين عندك؟ يعني لو قولنا لكوا برائث التلوين
+
+322
+00:32:26,860 --> 00:32:34,280
+كام نوع من الهيدروجين؟ واحد هدولة تنتين زي بعض،
+
+323
+00:32:34,280 --> 00:32:41,860
+هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول زي
+
+324
+00:32:41,860 --> 00:32:43,760
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول
+
+325
+00:32:43,760 --> 00:32:43,760
+زي بعض، هدول زي بعض، هدول زي بعض، هدول زي بعض،
+
+326
+00:32:43,760 --> 00:32:43,760
+هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول زي
+
+327
+00:32:43,760 --> 00:32:45,480
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعهتنسيش ان
+
+328
+00:32:45,480 --> 00:32:52,860
+هذه double bond ان هذه الدويرة اصلا و هدولة مافيش
+
+329
+00:32:52,860 --> 00:32:58,000
+عليهم غير مجموعة واحدة يعني انا واحد اتنين تلاتة
+
+330
+00:32:58,000 --> 00:33:02,100
+اربعة مافيش انا hydrogen فلما نكون راسمين دائرة
+
+331
+00:33:02,100 --> 00:33:05,840
+ماحدش يفكر ان هوان و هوان فيها hydrogen واضحة
+
+332
+00:33:05,840 --> 00:33:09,240
+الفكرة؟ هي اللي بيوجع الانسان في الغلط ان انا مش
+
+333
+00:33:09,240 --> 00:33:13,220
+راسم ال double bonds ان انا عامل هيك بس هذه لها
+
+334
+00:33:13,220 --> 00:33:17,180
+معنى في الكيميافما تفكروش ان هنا وهنا يوجد
+
+335
+00:33:17,180 --> 00:33:23,500
+هيدروجينز في الشكل يا
+
+336
+00:33:23,500 --> 00:33:28,780
+ريتما ماحطتش الامتحان كان جيبتي الكويزمة اه there
+
+337
+00:33:28,780 --> 00:33:33,460
+are three possible stereoisomers of 1,2
+
+338
+00:33:33,460 --> 00:33:39,460
+-dichlorobrobane الان لاحظوا بالكتورث مش شكل
+
+339
+00:33:39,460 --> 00:33:46,160
+البروبين كام كاربونتلاتة على نمرة واحد و اتنين في
+
+340
+00:33:46,160 --> 00:33:50,120
+عندى chlorine يعني هذه حملة chlorine و هذه حملة
+
+341
+00:33:50,120 --> 00:33:54,780
+chlorine لو كملنا ال hydrogens الان هنا CH2 هنا
+
+342
+00:33:54,780 --> 00:34:04,140
+CH3 الان من هذا المركب كم isomer عندى اه
+
+343
+00:34:04,140 --> 00:34:09,580
+بديش انسى ان في عندى chiral center هنا مافيش هنا
+
+344
+00:34:09,580 --> 00:34:13,940
+في chiral centerطالما عندي chiral center إذا
+
+345
+00:34:13,940 --> 00:34:23,740
+المركب و صورته إذا كام stereo isomer عند هنا الصح؟
+
+346
+00:34:23,740 --> 00:34:30,220
+نان .. نان هذا واحد اللي موجود عندكم حقيقة هو ال S
+
+347
+00:34:30,220 --> 00:34:35,900
+بتقدر ترسم صورته في المرايا ال R اللي موجود هو ال
+
+348
+00:34:35,900 --> 00:34:40,200
+S بتقدر ترسم ال R إذا هذه الجملة غلط
+
+349
+00:34:46,280 --> 00:34:53,080
+Addition of HBr Peroxide to styrene produces two
+
+350
+00:34:53,080 --> 00:34:59,040
+stereoisomers طبعا اللي مش عارف ال styrene زنبها ع
+
+351
+00:34:59,040 --> 00:35:08,500
+جنبها CH double bond CH2 لاحظوا هذا سؤال جميل لو
+
+352
+00:35:08,500 --> 00:35:13,060
+انا كنت باضيف HBr في وجود H plus هضيفه حسب قاعدة
+
+353
+00:35:13,060 --> 00:35:18,780
+Markovnikov هحط هنا ال Hوهنا ال PR وجدت في هذه
+
+354
+00:35:18,780 --> 00:35:24,080
+الحالة هعمل chiral center هنا هيطلع عندى ناتجين لو
+
+355
+00:35:24,080 --> 00:35:28,460
+أنا بضيف ال HPR في وجود H Plus هنا ال H هنا ال PR
+
+356
+00:35:28,460 --> 00:35:32,920
+إذا انا عملت chiral center لأن لما بضيف في وجود ال
+
+357
+00:35:32,920 --> 00:35:37,780
+peroxide Anti Markovnikov's addition يعني بدي ألغى
+
+358
+00:35:37,780 --> 00:35:45,050
+هذا ال double bond و أحط هنا H و هنا PRبر فيها انا
+
+359
+00:35:45,050 --> 00:35:50,050
+كايرال سنتر فيها انا كايرال سنتر اذا الكم ايزو مار
+
+360
+00:35:50,050 --> 00:35:57,430
+طلع عني واحد مش اتنين لو كنا بنضيف hbr في وجود h
+
+361
+00:35:57,430 --> 00:35:58,550
+plus بطلع اتنين
+
+362
+00:36:08,270 --> 00:36:11,910
+هذا السؤال MAI reacts with ethyl chloride
+
+363
+00:36:11,910 --> 00:36:16,410
+producing ethyl iodide لاحظوا هنا إبدال أن اليود
+
+364
+00:36:16,410 --> 00:36:23,670
+بيحل محل كلور هذه المعلومة أخدناها ولا لأ اليود
+
+365
+00:36:23,670 --> 00:36:32,630
+بيحل محل كلور و العكس مش صحيح Cyclohexanol بتكون
+
+366
+00:36:32,630 --> 00:36:37,730
+تتذكروا بمخكوا ع طول ال Cyclohexanolركزنا عليه في
+
+367
+00:36:37,730 --> 00:36:43,130
+الرسم ولا لأ؟ اللي متصل ب OH لو عملتله أكسدة شو
+
+368
+00:36:43,130 --> 00:36:52,690
+هيعمل؟ هيحذف ال H و ال H هاي الأكسدة تبعته، هاي
+
+369
+00:36:52,690 --> 00:36:57,360
+أكسدته، إيش أعطاني؟عطاني كيتون أساسا
+
+370
+00:36:57,360 --> 00:37:00,680
+الـcyclohexanol is secondary alcohol secondary
+
+371
+00:37:00,680 --> 00:37:05,420
+alcohols are oxidized to ketones وهي بالرسمة بيعطي
+
+372
+00:37:05,420 --> 00:37:13,660
+كيتون أنا كاتبلكم غلط مش الديهيد كيتون dehydration
+
+373
+00:37:13,660 --> 00:37:18,180
+of secondary butyl alcohol مرة تانية رجعنا تكونوا
+
+374
+00:37:18,180 --> 00:37:23,060
+حافظين أسماء إيش المجموعات ال secondary butyl اللي
+
+375
+00:37:23,060 --> 00:37:30,120
+حاملة هناعلى هذا الموقع وهذا لما يحمل OH سكندر
+
+376
+00:37:30,120 --> 00:37:35,020
+بيوت الالكهول طبعا ال dehydration يا ال OH من هنا
+
+377
+00:37:35,020 --> 00:37:42,620
+او من هنا اخدنا انه حسب قاعدة زي سف الحذف و more
+
+378
+00:37:42,620 --> 00:37:47,320
+substituted product will form اذا ال one butane
+
+379
+00:37:47,320 --> 00:37:51,260
+ولا ال two butane انا كاتبينلكم بشكل أساسي one
+
+380
+00:37:51,260 --> 00:37:52,820
+butane اذا خطأ
+
+381
+00:38:10,810 --> 00:38:15,070
+dichlorination of cyclobutane gives a total of
+
+382
+00:38:15,070 --> 00:38:19,310
+لحظوا ال cyclobutane بهذا الشكل بدي أضع عليه
+
+383
+00:38:19,310 --> 00:38:25,830
+مجموعتين كلور كيف ممكن أضعهم على واحد و واحد أو
+
+384
+00:38:25,830 --> 00:38:29,150
+على واحد و اتنين على واحد و اتنين بيجي ال ces و ال
+
+385
+00:38:29,150 --> 00:38:29,810
+trans
+
+386
+00:38:39,260 --> 00:38:45,180
+cyclobutane ..cyclobutane ..انا متأسف okay ..الان
+
+387
+00:38:45,180 --> 00:38:48,500
+ال ..cyclobutane ..حطوا مجموعتين كلور على واحد
+
+388
+00:38:48,500 --> 00:38:53,980
+واحد ..هذا مركب ..بعدين ع واحد و اتنين .. six و
+
+389
+00:38:53,980 --> 00:38:57,860
+trance .. بعدين ع واحد و تلاتة .. six و trance ..
+
+390
+00:38:57,860 --> 00:39:02,300
+اذا قداش المجموعة؟ خمسة ..هي نفس فكرة ال
+
+391
+00:39:02,300 --> 00:39:07,200
+..cyclobrote .. بس على أوصةThe common name of two
+
+392
+00:39:07,200 --> 00:39:19,360
+propene one all يعني هاي CH2OH CH double bond CH2
+
+393
+00:39:19,360 --> 00:39:26,160
+لحظوا هذا two propene واحد اتنين تلاتة one all هنا
+
+394
+00:39:26,160 --> 00:39:30,340
+فسرناه الآن الناس اللي متذكرة شكل المجموعة شو هي
+
+395
+00:39:30,340 --> 00:39:32,400
+الالكول
+
+396
+00:39:34,300 --> 00:39:40,940
+قلل ألكول قلل ألكول إذا كان شوكارو مستعمل لإيصال
+
+397
+00:39:40,940 --> 00:39:45,440
+حركة محركة واحدة إلكترون واحدة إلكترون فالمثال لـ
+
+398
+00:39:45,440 --> 00:39:51,880
+Cyclic Alkenes هو CNH2N-2 لاحظوا الـ Cyclic بدأ
+
+399
+00:39:51,880 --> 00:39:55,660
+أقسم جبالها اتنين من الفورمولة الأصلية والـ E بدأ
+
+400
+00:39:55,660 --> 00:40:00,400
+أقسم اتنين إذا صارت زي formula of الكائنات يعني
+
+401
+00:40:00,400 --> 00:40:08,300
+CNHتو ان ماينوس تو وبتاعة اللي عملناها مركبة زيها
+
+402
+00:40:08,300 --> 00:40:14,260
+اوزونوليسيس او سيس اوري ترانس تو بيوتين خليني
+
+403
+00:40:14,260 --> 00:40:19,860
+اخد ال سيس تو بيوتين ارسمه هان هاي ال سيس تو
+
+404
+00:40:19,860 --> 00:40:23,880
+بيوتين بدي اكسره من هان C double bond O وهذه H
+
+405
+00:40:23,880 --> 00:40:30,660
+بالتأكيدهذا C double bond OH CH3 Acetaldehyde هذا
+
+406
+00:40:30,660 --> 00:40:38,400
+C double bond OH CH3 Acetaldehyde و لل Trans هاي
+
+407
+00:40:38,400 --> 00:40:47,640
+CH3H و هنا CH3H الان اكسروا هذا من هنا و اكسروا
+
+408
+00:40:47,640 --> 00:40:53,400
+هذا من هنا و حطوا ايش Oxygen Oxygen Oxygen Oxygen
+
+409
+00:40:53,980 --> 00:40:59,480
+كل النواتج ايش؟ أسيتلديهيد بيعطي نفس الناتج
+
+410
+00:40:59,480 --> 00:41:07,000
+produces only أسيتلديهيد أو إيثانال أسيتلديهيد
+
+411
+00:41:07,000 --> 00:41:14,960
+CH3SH is more acidic than CH3OH due to size
+
+412
+00:41:17,520 --> 00:41:22,560
+سلفر مع اكسجين ايش العامل المحدد في ال acidity ال
+
+413
+00:41:22,560 --> 00:41:27,820
+size ال due to size
+
+414
+00:41:27,820 --> 00:41:34,740
+الان
+
+415
+00:41:34,740 --> 00:41:40,660
+ارسموا المراكبات التالية بدي بيوتينيعني carbon
+
+416
+00:41:40,660 --> 00:41:46,820
+تنتين تلاتة أربعة على لمرة اتنين ايش موجود عندكم؟
+
+417
+00:41:46,820 --> 00:41:56,900
+فينوكسي يعني O phenyl OH OHANA CH3 CH2 CH3 الآن
+
+418
+00:41:56,900 --> 00:42:01,120
+انا برسم المركب بعدين بشوفه اذا طلع R كان بيها
+
+419
+00:42:01,120 --> 00:42:06,970
+ماطلعش Rبعكس اي مجموع تاني الا لو جيت تطلعت عليه
+
+420
+00:42:06,970 --> 00:42:11,890
+كيف مبين هذي واحد هذي اتنين هذي تلاتة مبين اس و
+
+421
+00:42:11,890 --> 00:42:18,590
+هذي على الجانب اذا هذا فعلا الار ايزو مار عندي
+
+422
+00:42:18,590 --> 00:42:24,770
+سايكلو بنتين هاي السايكلو بنتين خليني ارسمه بهذا
+
+423
+00:42:24,770 --> 00:42:30,530
+الشكلcyclopentane واحد اتنين تلاتة اربعة خمسة على
+
+424
+00:42:30,530 --> 00:42:38,950
+نمرة تلاتة واربعة شو بدي احط كلور وكلور بالزويك
+
+425
+00:42:38,950 --> 00:42:47,010
+أسد C double bond O OH وهنا ال formal C double
+
+426
+00:42:47,010 --> 00:42:57,620
+bond OH هذا ميتاميتا أو بارا هذا موضوع بسيط هذا
+
+427
+00:42:57,620 --> 00:43:01,020
+المركب
+
+428
+00:43:01,020 --> 00:43:10,120
+Cyclopentane شو هذه المجموعة؟ Isobutyl Isobutyl
+
+429
+00:43:10,120 --> 00:43:15,680
+Cyclopentane هذا
+
+430
+00:43:15,680 --> 00:43:22,160
+كحول ألكين من وين الترقيم؟ من عند الكحول يعني هذا
+
+431
+00:43:25,670 --> 00:43:36,290
+بيوتين بيوت two in one all و إيش بيحمل بعد هى two
+
+432
+00:43:36,290 --> 00:43:43,710
+bromo فيه زده E لحظوا هنا ال brom و هنا الميثل ال
+
+433
+00:43:43,710 --> 00:43:47,270
+brom أعلى من الكربون و الميثل أعلى من ال H إذا هذا
+
+434
+00:43:47,270 --> 00:43:51,750
+E هذا أسيتوفينون
+
+435
+00:44:14,250 --> 00:44:18,730
+مش كتير معنا وقت ان شاء الله بخمس دقائق نمشي أسرع
+
+436
+00:44:18,730 --> 00:44:21,270
+بدنا خمس دقائق نمشي أسرع شوية
+
+437
+00:44:24,120 --> 00:44:30,000
+هحاول امشي بشكل سريع الان هنا في ال HBr Peroxide
+
+438
+00:44:30,000 --> 00:44:35,140
+الفكرة الأساسية اللى بتكون تعمله شو هي انت
+
+439
+00:44:35,140 --> 00:44:43,000
+Markovnikov واضح فلو انتوا جيتوا واشتغلتوا H CH3
+
+440
+00:44:43,000 --> 00:44:51,740
+CH2 هنا H هنا H وين هتحطوا ال Br وهنا
+
+441
+00:44:51,740 --> 00:44:56,880
+ال Hهي الـ Antimark of Nikon واضح؟ الان هذا لو
+
+442
+00:44:56,880 --> 00:45:00,320
+فعلته مع ال Oethel minus Can you clear your file؟
+
+443
+00:45:00,320 --> 00:45:08,700
+شو بتعمل؟ بتحيل محل لبروم يعني بتحط كل الجزيء و
+
+444
+00:45:08,700 --> 00:45:18,540
+تكتبوا هنا Oethel و لو فعلته مع ال SH minus بدنا
+
+445
+00:45:18,540 --> 00:45:26,810
+نحط كل الجزيء مرة تانيةوبنحط هنا sh ابدال يعني هذا
+
+446
+00:45:26,810 --> 00:45:30,870
+البروم بتبدل هذا عنوان chapter 6 انه البروم بتبدل
+
+447
+00:45:30,870 --> 00:45:36,310
+بال او اثل او بال sh هنا بالكئمن او فور مع ال o h
+
+448
+00:45:36,310 --> 00:45:44,090
+minus شو بدها تحط مجمعتين o h على جهة واحدة بال
+
+449
+00:45:44,090 --> 00:45:50,730
+ozonolysis بدوا يعمل تلتين c double point o بتكمل
+
+450
+00:45:50,730 --> 00:45:58,340
+الجزيةبالميه هذه بتضيف حسب قاعدة Markovnikov
+
+451
+00:45:58,340 --> 00:46:03,220
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+452
+00:46:03,220 --> 00:46:07,800
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+453
+00:46:07,800 --> 00:46:07,980
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+454
+00:46:07,980 --> 00:46:09,020
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+455
+00:46:09,020 --> 00:46:09,960
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+456
+00:46:09,960 --> 00:46:20,320
+اتش اتش اتش اتش اتش اتش اتش اتش
+
+457
+00:46:20,320 --> 00:46:22,320
+ات
+
+458
+00:46:33,790 --> 00:46:41,490
+أخر شغلة الأفكار الأساسية هنا إضافة ميه وبعدين
+
+459
+00:46:41,490 --> 00:46:47,110
+توتوميرزم متذاكرينها ال
+
+460
+00:46:47,110 --> 00:46:54,030
+ISOبنتين هي ال ISOبنتين اعملولها إكلوريناشن توي
+
+461
+00:46:54,030 --> 00:47:01,240
+حكينا كام موقع فيها؟واحد اتنين تلاتة اربعة لما
+
+462
+00:47:01,240 --> 00:47:05,440
+احطولكوا all possible monochlorination products
+
+463
+00:47:05,440 --> 00:47:10,700
+انتبهوا معي لما احط كلور هان و هان هذا ناتج و اذا
+
+464
+00:47:10,700 --> 00:47:13,740
+حطيت هان هذا ناتج هذا فيش فيه chiral center هذا
+
+465
+00:47:13,740 --> 00:47:17,500
+فيش فيه chiral center لو حطيت هان CH2Cl فيش فيه
+
+466
+00:47:17,500 --> 00:47:23,210
+chiral center لو حطيت هانأتش و CL في كايرالسنتر
+
+467
+00:47:23,210 --> 00:47:27,430
+هدا بده يطلع منه كام واحد اتنين اذا المجموع كده؟
+
+468
+00:47:27,430 --> 00:47:32,890
+خمسة product لما ادخل ال stereo isomers هذه النقطة
+
+469
+00:47:32,890 --> 00:47:38,510
+تحديدا بحط فيها ال H و ال CL يعني الناتجين اللي
+
+470
+00:47:38,510 --> 00:47:44,450
+بدهم يكونوا هنا لو رسمت الناتج و صورته في المرايا
+
+471
+00:47:44,450 --> 00:47:52,680
+بدكوا تكونوا حاطين هنا مثلاH و CH3 و CL وهنا تحطوا
+
+472
+00:47:52,680 --> 00:48:02,100
+CL و H و CH3 الناتج و صورته في المرأة واضح
+
+473
+00:48:02,100 --> 00:48:06,300
+الناتج و صورته في المرأة هذوله اتنين و بعدين
+
+474
+00:48:06,300 --> 00:48:09,920
+بتحطوا هن واحد و هن واحد و هن واحد المجموع كده؟
+
+475
+00:48:09,920 --> 00:48:17,300
+خمسة خمسة بقى لعنا اتنين صغار كتير
+
+476
+00:48:25,790 --> 00:48:29,490
+isopropylacetophenon الفكرة فقط انكوا تعرفوا مين
+
+477
+00:48:29,490 --> 00:48:34,550
+بده احطها في الأول انهي المجموعة اللي بتلحط نمرا
+
+478
+00:48:34,550 --> 00:48:42,090
+واحد ال isopropyl ال isopropyl orthopara ال
+
+479
+00:48:42,090 --> 00:48:46,290
+isopropyl orthopara directing و بعدين ال
+
+480
+00:48:46,290 --> 00:48:47,270
+acetophenon
+
+481
+00:48:49,330 --> 00:48:54,330
+Cl ألمنيوم كلورايد و هنا ايزو بروبل كلورايد
+
+482
+00:48:54,330 --> 00:49:02,530
+ألمنيوم كلورايد أخر سؤال سيث ثريهكسيني من ون
+
+483
+00:49:02,530 --> 00:49:07,430
+بيوتايل لاحظوا هذا ال ون بيوتايل بهذا الشكل CH3
+
+484
+00:49:07,430 --> 00:49:15,670
+CH2 C triple bond CH من أربعة بده أحضر ستة
+
+485
+00:49:15,670 --> 00:49:17,890
+ملاحظين؟
+
+486
+00:49:18,690 --> 00:49:24,670
+من الأربعة شو بده احضر؟ ستة كيف بده اعمل هذا
+
+487
+00:49:24,670 --> 00:49:31,470
+الكلام؟ اول اشي بده ازيد ذاتين carbon فانا لو فعلت
+
+488
+00:49:31,470 --> 00:49:38,380
+مع ال NANH2 نمرة واحد خلت هذه minusو بعدين نمرة
+
+489
+00:49:38,380 --> 00:49:44,540
+اتنين فعلتها مع إثيل بروميد CH3 CH2Br ال minus
+
+490
+00:49:44,540 --> 00:49:48,760
+اللي بيحجم على ال PR و أجتها بيصير عندي هذا ال
+
+491
+00:49:48,760 --> 00:49:56,140
+كائن CH3 CH2 C triple bond C وهي ال إثيل اللي أنا
+
+492
+00:49:56,140 --> 00:50:04,950
+حطيتها CH2 CH3 الان من هذه بدي أخليهاالكين
+
+493
+00:50:04,950 --> 00:50:09,090
+والالكين يكون إيش؟ SES كيف بحول ال triple bond
+
+494
+00:50:09,090 --> 00:50:18,610
+لالكين SES؟ H2 Lendlers Catalyst Lendlers Catalyst
+
+495
+00:50:18,610 --> 00:50:24,350
+إذا هذا السؤال فيه فكرتين أساسيات الفكرة الأولى أن
+
+496
+00:50:24,350 --> 00:50:28,010
+ال terminal alkyl بيصير نيوكليوفايل ممكن يعمل
+
+497
+00:50:28,010 --> 00:50:34,070
+إبدال علىالكالهلايد كبرت السلسلة و بعدين ل triple
+
+498
+00:50:34,070 --> 00:50:38,010
+bond ان اخليها cis او trans اخدته قولت انا ل
+
+499
+00:50:38,010 --> 00:50:43,470
+triple bond يا بخليها الكن يا cis الكن يا trans
+
+500
+00:50:43,470 --> 00:50:48,590
+الكن كل واحدة في إلها شروط معينة ابقى اك تقريبا
+
+501
+00:50:48,590 --> 00:50:53,810
+بنكون غطينا يعني باسئلة مختلفة معظم الأشياء اللي
+
+502
+00:50:53,810 --> 00:50:57,490
+درسناها و بنتمنالكوا ان شاء الله النجاح و التوفيق
+
+503
+00:50:57,490 --> 00:50:59,050
+في الامتحان اللي بدكنوا تقدموه
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..ffbb8549591e234bfbf82e23005f6cd28c4107ce
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4964, "start": 21.24, "end": 49.64, "text": "بسم الله الرحمن الرحيم موضوعنا اليوم عن ال stereochemistry ربما يعني انتوا اتشوقتوا اليها لان احنا من اول محاضرة لما اتكلمنا عن المتشكلات او ال isomers قسمناهم وقلنا هم نوعين اساسيين structural isomers او constitutional isomers سمناهم و stereo isomers", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 3714, 2407, 11242, 45367, 8315, 45595, 20498, 18871, 2423, 29029, 48353, 12602, 3555, 15042, 37495, 22653, 16472, 2655, 14407, 1975, 2655, 8592, 30543, 2655, 14407, 45595, 11296, 5296, 7649, 1975, 5016, 8315, 9154, 1975, 12610, 3714, 5016, 46958, 25720, 5296, 15042, 1975, 2655, 4117, 19528, 8315, 18871, 9673, 2655, 8592, 28820, 9307, 1975, 2407, 2423, 307, 298, 433, 12174, 38251, 8315, 16095, 4032, 4587, 1211, 8315, 8032, 2304, 8717, 45367, 9957, 24525, 32277, 1829, 9957, 15067, 307, 298, 433, 1975, 2407, 20176, 307, 298, 433, 8608, 2304, 8315, 16095, 4032, 29029, 307, 298, 433], 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"probability": 0.9534912109375}, {"start": 116.91, "end": 117.19, "word": " two", "probability": 0.79248046875}, {"start": 117.19, "end": 118.29, "word": " chloroborbine", "probability": 0.94384765625}, {"start": 118.29, "end": 119.05, "word": " هدولة", "probability": 0.8555908203125}, {"start": 119.05, "end": 119.65, "word": " اسمين", "probability": 0.9239908854166666}, {"start": 119.65, "end": 120.41, "word": " مختلفين", "probability": 0.993408203125}], "temperature": 1.0}, {"id": 5, "seek": 14297, "start": 121.3, "end": 142.98, "text": "الان الشيء التاني في ال isomers اللى حتى ايضا بدنا فيه اللى هو ال stereo isomers المركبات اللى بتكون لها نفس الارتباط ولكن اختلاف في شكلها بالفراغ ولذلك احنا قولنا ال stereo isomers ال atoms they have the same constitution", "tokens": [6027, 7649, 25124, 1829, 38207, 16712, 7649, 1829, 8978, 2423, 307, 298, 433, 13672, 7578, 11331, 49975, 1975, 1829, 11242, 995, 47525, 8315, 8978, 3224, 13672, 7578, 31439, 2423, 29029, 307, 298, 433, 9673, 31747, 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138.36, "end": 138.74, "word": " stereo", "probability": 0.75244140625}, {"start": 138.74, "end": 139.52, "word": " isomers", "probability": 0.9814453125}, {"start": 139.52, "end": 140.2, "word": " ال", "probability": 0.90625}, {"start": 140.2, "end": 140.64, "word": " atoms", "probability": 0.78125}, {"start": 140.64, "end": 140.94, "word": " they", "probability": 0.78759765625}, {"start": 140.94, "end": 141.2, "word": " have", "probability": 0.970703125}, {"start": 141.2, "end": 141.4, "word": " the", "probability": 0.92138671875}, {"start": 141.4, "end": 141.88, "word": " same", "probability": 0.90087890625}, {"start": 141.88, "end": 142.98, "word": " constitution", "probability": 0.91748046875}], "temperature": 1.0}, {"id": 6, "seek": 16797, "start": 144.79, "end": 167.97, "text": "different arrangement in space بدأنا فيهم الحقيقة لما احنا أخدنا مراكبات ال sis والترانس يعني مثلا عندنا اثين على موقع واحد كلور هاي اثين جزئي ب double bond على موقع واحد كلور وعلى موقع اتنين كلور وبناء على ذلك شو هيصير اسمه one two dichloro ethane", "tokens": [67, 15790, 17620, 294, 1901, 47525, 10721, 8315, 8978, 16095, 21542, 38436, 28671, 5296, 15042, 1975, 5016, 8315, 5551, 9778, 3215, 8315, 3714, 23557, 4117, 3555, 9307, 2423, 26288, 16070, 2655, 2288, 7649, 3794, 37495, 22653, 50113, 15040, 43242, 8315, 1975, 12984, 9957, 15844, 3714, 30543, 3615, 36764, 24401, 9122, 1211, 13063, 8032, 47302, 1975, 12984, 9957, 10874, 11622, 19986, 1829, 4724, 3834, 6086, 15844, 3714, 30543, 3615, 36764, 24401, 9122, 1211, 13063, 4032, 3615, 23942, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 9122, 1211, 13063, 46599, 1863, 16606, 15844, 29910, 23275, 13412, 2407, 39896, 9381, 13546, 24525, 2304, 3224, 472, 732, 10390, 6746, 78, 6468, 1929], "avg_logprob": -0.22149884852546234, "compression_ratio": 1.649789029535865, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 144.79, "end": 145.41, "word": "different", "probability": 0.537353515625}, {"start": 145.41, "end": 146.05, "word": " 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1225.82, "word": " ذرد", "probability": 0.5900065104166666}, {"start": 1225.82, "end": 1226.18, "word": " كاربون", "probability": 0.9237060546875}, {"start": 1226.18, "end": 1226.56, "word": " واحدة", "probability": 0.9679361979166666}, {"start": 1226.56, "end": 1227.02, "word": " بسرعة", "probability": 0.9873046875}], "temperature": 1.0}, {"id": 52, "seek": 123027, "start": 1227.81, "end": 1230.27, "text": "ميتين؟ شو بتحمل؟", "tokens": [2304, 36081, 9957, 22807, 13412, 2407, 39894, 35571, 1211, 22807], "avg_logprob": -0.22514205087314954, "compression_ratio": 0.7317073170731707, "no_speech_prob": 0.0, "words": [{"start": 1227.81, "end": 1228.97, "word": "ميتين؟", "probability": 0.7315673828125}, {"start": 1228.97, "end": 1229.47, "word": " شو", "probability": 0.69970703125}, {"start": 1229.47, "end": 1230.27, "word": " بتحمل؟", "probability": 0.959716796875}], "temperature": 1.0}, {"id": 53, "seek": 126117, "start": 1232.11, "end": 1261.17, "text": "مافيش غير الواحد ما تقولوهوش إبرومو كلورو أيودو ميثيل و بنذكرهم alphabetical مش هذي الف باقي التسمية يعني هذا الجزيء لما تجيب الكياشو اسمه إبرومو كلورو أيودو ميثيل في مشكلة لحد الآن؟ الآن لو عملت صورته في المرقاة يعني مسكته زي هيك و جيبت كمان إبرومو هيدروجيل", "tokens": [15042, 41185, 8592, 32771, 13546, 2423, 14407, 24401, 19446, 6055, 39648, 2407, 3224, 2407, 8592, 11933, 26890, 20498, 2407, 9122, 1211, 13063, 2407, 36632, 2407, 3215, 2407, 3714, 1829, 12984, 26895, 4032, 44945, 8848, 37983, 16095, 23339, 804, 37893, 8032, 8848, 1829, 27188, 4724, 995, 38436, 16712, 38251, 10632, 37495, 22653, 23758, 25724, 11622, 1829, 38207, 5296, 15042, 6055, 7435, 1829, 3555, 33251, 1829, 33599, 2407, 24525, 2304, 3224, 11933, 26890, 20498, 2407, 9122, 1211, 13063, 2407, 36632, 2407, 3215, 2407, 3714, 1829, 12984, 26895, 8978, 37893, 28820, 3660, 5296, 24401, 6024, 48506, 22807, 6024, 48506, 45164, 6225, 42213, 2655, 20328, 13063, 47395, 8978, 9673, 2288, 4587, 995, 3660, 37495, 22653, 3714, 3794, 4117, 47395, 30767, 1829, 39896, 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1270.14, "word": " ولا", "probability": 0.69775390625}, {"start": 1270.14, "end": 1270.64, "word": " لأ", "probability": 0.77783203125}, {"start": 1270.64, "end": 1273.52, "word": " واضح", "probability": 0.7862141927083334}, {"start": 1273.52, "end": 1274.46, "word": " صورة", "probability": 0.84716796875}, {"start": 1274.46, "end": 1274.74, "word": " بعض", "probability": 0.959716796875}, {"start": 1274.74, "end": 1274.9, "word": " في", "probability": 0.9345703125}, {"start": 1274.9, "end": 1275.26, "word": " المرأة", "probability": 0.9683837890625}, {"start": 1275.26, "end": 1275.54, "word": " مية", "probability": 0.71875}, {"start": 1275.54, "end": 1275.7, "word": " في", "probability": 0.73876953125}, {"start": 1275.7, "end": 1276.02, "word": " المية", "probability": 0.965576171875}, {"start": 1276.02, "end": 1276.48, "word": " طب", "probability": 0.78759765625}, {"start": 1276.48, "end": 1276.66, "word": " لو", "probability": 0.98974609375}, {"start": 1276.66, "end": 1276.98, "word": 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{"start": 1291.98, "end": 1292.52, "word": " الجملة", "probability": 0.9541015625}, {"start": 1292.52, "end": 1293.06, "word": " العامة", "probability": 0.9920247395833334}, {"start": 1293.06, "end": 1293.18, "word": " في", "probability": 0.8740234375}, {"start": 1293.18, "end": 1293.56, "word": " تعريف", "probability": 0.9767252604166666}, {"start": 1293.56, "end": 1293.66, "word": " ال", "probability": 0.85009765625}, {"start": 1293.66, "end": 1294.02, "word": " stereo", "probability": 0.1546630859375}, {"start": 1294.02, "end": 1294.7, "word": " isomers", "probability": 0.9578450520833334}, {"start": 1294.7, "end": 1294.88, "word": " they", "probability": 0.382080078125}, {"start": 1294.88, "end": 1295.1, "word": " have", "probability": 0.958984375}, {"start": 1295.1, "end": 1295.28, "word": " the", "probability": 0.9140625}, {"start": 1295.28, "end": 1295.54, "word": " same", "probability": 0.9150390625}, {"start": 1295.54, "end": 1296.06, "word": " bonding", "probability": 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1365.54, "end": 1384.42, "text": "هيدروجين و هيدروجين هدولة انطبقوا على بعض هدولة انطبقوا على بعض هدولة انطبقوا على بعض صح؟ الان هدولة تنتيل كلورو هيدروجين كلورو هيدروجين بينطبقوا؟ لا بينطبقوا", "tokens": [3224, 25708, 2288, 29245, 9957, 4032, 8032, 25708, 2288, 29245, 9957, 8032, 3215, 12610, 3660, 16472, 9566, 3555, 4587, 14407, 15844, 45030, 11242, 8032, 3215, 12610, 3660, 16472, 9566, 3555, 4587, 14407, 15844, 45030, 11242, 8032, 3215, 12610, 3660, 16472, 9566, 3555, 4587, 14407, 15844, 45030, 11242, 20328, 5016, 22807, 2423, 7649, 8032, 3215, 12610, 3660, 6055, 29399, 26895, 9122, 1211, 13063, 2407, 8032, 25708, 2288, 29245, 9957, 9122, 1211, 13063, 2407, 8032, 25708, 2288, 29245, 9957, 4724, 9957, 9566, 3555, 4587, 14407, 22807, 20193, 4724, 9957, 9566, 3555, 4587, 14407], "avg_logprob": -0.193444290238878, "compression_ratio": 2.7452830188679247, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1365.54, "end": 1365.96, "word": "هيدروجين", "probability": 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{"start": 1393.56, "end": 1394.22, "word": " سنين،", "probability": 0.912841796875}, {"start": 1394.22, "end": 1394.54, "word": " خليهم", "probability": 0.9479166666666666}, {"start": 1394.54, "end": 1395.24, "word": " ينطبقوا", "probability": 0.9449055989583334}, {"start": 1395.24, "end": 1395.78, "word": " على", "probability": 0.8984375}, {"start": 1395.78, "end": 1397.16, "word": " بعض،", "probability": 0.9567057291666666}, {"start": 1397.16, "end": 1397.34, "word": " لا", "probability": 0.669921875}, {"start": 1397.34, "end": 1398.1, "word": " ينطبقوا", "probability": 0.9657389322916666}], "temperature": 1.0}, {"id": 61, "seek": 142567, "start": 1399.03, "end": 1425.67, "text": "واضح؟ إذا بدأت أكسر رابطتين و أبدلهم هيصيروا نفس الجزء، هيبطلوا صورة بعض في المرآة، هيصيروا نفس الجزء، واضح؟ لكن طالما هم صورة بعض في المرآة، فغير متطابقين، إذا هذول أول مثال في الكيميا على ال enantiomers و ال enantiomers بتوجد لما يكون عند ذرة carbon تحمل أربع مجموعات مختلفة", "tokens": [2407, 46958, 5016, 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1411.71, "word": " بعض", "probability": 0.963134765625}, {"start": 1411.71, "end": 1411.87, "word": " في", "probability": 0.98681640625}, {"start": 1411.87, "end": 1413.01, "word": " المرآة،", "probability": 0.9110514322916666}, {"start": 1413.01, "end": 1413.37, "word": " فغير", "probability": 0.9645182291666666}, {"start": 1413.37, "end": 1414.49, "word": " متطابقين،", "probability": 0.96337890625}, {"start": 1414.49, "end": 1414.73, "word": " إذا", "probability": 0.80517578125}, {"start": 1414.73, "end": 1415.15, "word": " هذول", "probability": 0.7443033854166666}, {"start": 1415.15, "end": 1415.59, "word": " أول", "probability": 0.904541015625}, {"start": 1415.59, "end": 1416.15, "word": " مثال", "probability": 0.97119140625}, {"start": 1416.15, "end": 1416.33, "word": " في", "probability": 0.978515625}, {"start": 1416.33, "end": 1416.77, "word": " الكيميا", "probability": 0.8839518229166666}, {"start": 1416.77, "end": 1416.97, "word": " على", "probability": 0.427978515625}, {"start": 1416.97, "end": 1417.13, "word": " ال", "probability": 0.89306640625}, {"start": 1417.13, "end": 1417.85, "word": " enantiomers", "probability": 0.7738037109375}, {"start": 1417.85, "end": 1418.31, "word": " و", "probability": 0.48486328125}, {"start": 1418.31, "end": 1418.45, "word": " ال", "probability": 0.9267578125}, {"start": 1418.45, "end": 1419.25, "word": " enantiomers", "probability": 0.91455078125}, {"start": 1419.25, "end": 1420.11, "word": " بتوجد", "probability": 0.88818359375}, {"start": 1420.11, "end": 1420.61, "word": " لما", "probability": 0.887451171875}, {"start": 1420.61, "end": 1420.99, "word": " يكون", "probability": 0.989501953125}, {"start": 1420.99, "end": 1421.43, "word": " عند", "probability": 0.791015625}, {"start": 1421.43, "end": 1422.31, "word": " ذرة", "probability": 0.749267578125}, {"start": 1422.31, "end": 1422.95, "word": " carbon", "probability": 0.4033203125}, {"start": 1422.95, "end": 1423.59, "word": " تحمل", "probability": 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{"start": 1430.1, "end": 1430.22, "word": " في", "probability": 0.955078125}, {"start": 1430.22, "end": 1431.9, "word": " الكيمياء؟", "probability": 0.7681640625}, {"start": 1431.9, "end": 1432.1, "word": " إذا", "probability": 0.91552734375}, {"start": 1432.1, "end": 1432.44, "word": " وجد", "probability": 0.9453125}, {"start": 1432.44, "end": 1432.76, "word": " عندي", "probability": 0.6279296875}, {"start": 1432.76, "end": 1433.14, "word": " ذرّة", "probability": 0.6905517578125}, {"start": 1433.14, "end": 1433.5, "word": " كاربون", "probability": 0.753173828125}, {"start": 1433.5, "end": 1433.88, "word": " تحمل", "probability": 0.9736328125}, {"start": 1433.88, "end": 1434.2, "word": " أربع", "probability": 0.8987630208333334}, {"start": 1434.2, "end": 1434.76, "word": " مجموعات", "probability": 0.98115234375}, {"start": 1434.76, "end": 1435.46, "word": " مختلفة", "probability": 0.9947509765625}, {"start": 1435.46, "end": 1436.06, "word": " الآن", "probability": 0.6082763671875}, {"start": 1436.06, "end": 1436.5, "word": " هذه", "probability": 0.63525390625}, {"start": 1436.5, "end": 1437.12, "word": " الكاربون", "probability": 0.86572265625}, {"start": 1437.12, "end": 1437.76, "word": " بنسميها", "probability": 0.8717041015625}, {"start": 1437.76, "end": 1439.64, "word": " كايرالكاربون", "probability": 0.803955078125}, {"start": 1439.64, "end": 1441.16, "word": " إيش", "probability": 0.6906331380208334}, {"start": 1441.16, "end": 1442.3, "word": " بنسميها؟", "probability": 0.93623046875}, {"start": 1442.3, "end": 1443.76, "word": " كايرالكاربون", "probability": 0.96221923828125}, {"start": 1443.76, "end": 1444.4, "word": " أو", "probability": 0.8330078125}, {"start": 1444.4, "end": 1446.96, "word": " stereogenic", "probability": 0.678955078125}, {"start": 1446.96, "end": 1447.58, "word": " center", "probability": 0.76025390625}, {"start": 1447.58, "end": 1452.08, "word": " أو", "probability": 0.712890625}, {"start": 1452.08, "end": 1454.6, "word": " أحيانا", "probability": 0.92841796875}, {"start": 1454.6, "end": 1455.9, "word": " كايرالسنتر", "probability": 0.7957240513392857}], "temperature": 1.0}, {"id": 63, "seek": 147615, "start": 1456.87, "end": 1476.15, "text": "يعني هو يا مركز المشكلة أو مركز الـ Stereochemistry بأي من هذه الأسماء شفتوها سواء شفتوها chiral carbon أو chiral center أو stereogenic center الفكرة فيها أن الكربون تحمل أربع مجموعات مختلفة", "tokens": [40228, 22653, 31439, 35186, 3714, 31747, 11622, 9673, 8592, 28820, 3660, 34051, 3714, 31747, 11622, 2423, 39184, 745, 323, 8997, 443, 5980, 4724, 10721, 1829, 9154, 29538, 16247, 38251, 16606, 13412, 5172, 2655, 2407, 11296, 8608, 2407, 16606, 13412, 5172, 2655, 2407, 11296, 23782, 304, 5954, 34051, 23782, 304, 3056, 34051, 12730, 25473, 3056, 27188, 4117, 25720, 8978, 11296, 14739, 33251, 25513, 11536, 6055, 35571, 1211, 5551, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660], "avg_logprob": -0.1307357530805129, "compression_ratio": 1.5502645502645502, 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"word": " هذه", "probability": 0.92822265625}, {"start": 1461.85, "end": 1462.39, "word": " الأسماء", "probability": 0.9825846354166666}, {"start": 1462.39, "end": 1462.93, "word": " شفتوها", "probability": 0.8708984375}, {"start": 1462.93, "end": 1463.41, "word": " سواء", "probability": 0.822265625}, {"start": 1463.41, "end": 1463.83, "word": " شفتوها", "probability": 0.959765625}, {"start": 1463.83, "end": 1464.33, "word": " chiral", "probability": 0.6884765625}, {"start": 1464.33, "end": 1464.87, "word": " carbon", "probability": 0.939453125}, {"start": 1464.87, "end": 1465.33, "word": " أو", "probability": 0.85888671875}, {"start": 1465.33, "end": 1465.95, "word": " chiral", "probability": 0.951416015625}, {"start": 1465.95, "end": 1466.43, "word": " center", "probability": 0.79443359375}, {"start": 1466.43, "end": 1466.91, "word": " أو", "probability": 0.87548828125}, {"start": 1466.91, "end": 1467.79, "word": " stereogenic", "probability": 0.682373046875}, {"start": 1467.79, "end": 1468.43, "word": " center", "probability": 0.91748046875}, {"start": 1468.43, "end": 1469.39, "word": " الفكرة", "probability": 0.9783528645833334}, {"start": 1469.39, "end": 1469.93, "word": " فيها", "probability": 0.98291015625}, {"start": 1469.93, "end": 1472.05, "word": " أن", "probability": 0.76611328125}, {"start": 1472.05, "end": 1472.67, "word": " الكربون", "probability": 0.9130859375}, {"start": 1472.67, "end": 1473.29, "word": " تحمل", "probability": 0.9918619791666666}, {"start": 1473.29, "end": 1473.99, "word": " أربع", "probability": 0.7916666666666666}, {"start": 1473.99, "end": 1475.53, "word": " مجموعات", "probability": 0.9552734375}, {"start": 1475.53, "end": 1476.15, "word": " مختلفة", "probability": 0.9940185546875}], "temperature": 1.0}, {"id": 64, "seek": 150338, "start": 1477.08, "end": 1503.38, "text": "لحظة أنا بحبش أني أتعبكم في صياغات لغوية the carbon carries four different groups البفروض بس تفهموا كلمة إيش أربعة و بعدين زي ما بيقول الشاعر و بكل لغات الأرض عبروا عنها المهم إيش ذرة الكربون تحمل أربع مجموعات مختلفة فبصير الشكل و صورته في المرأة غير متطابقين في هذه الحالة صاروا إيش", "tokens": [1211, 5016, 19913, 3660, 41850, 4724, 5016, 3555, 8592, 14739, 1829, 5551, 2655, 3615, 3555, 24793, 8978, 20328, 1829, 5718, 118, 9307, 5296, 17082, 2407, 10632, 264, 5954, 16402, 1451, 819, 3935, 29739, 5172, 32887, 11242, 4724, 3794, 6055, 5172, 16095, 14407, 9122, 19528, 3660, 11933, 1829, 8592, 5551, 25513, 27884, 4032, 39182, 9957, 30767, 1829, 19446, 4724, 1829, 39648, 25124, 45761, 2288, 4032, 4724, 28820, 5296, 17082, 9307, 16247, 43042, 6225, 26890, 14407, 18871, 11296, 9673, 16095, 11933, 1829, 8592, 29910, 25720, 33251, 25513, 11536, 6055, 35571, 1211, 5551, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660, 6156, 3555, 9381, 13546, 25124, 28820, 4032, 20328, 13063, 47395, 8978, 9673, 2288, 10721, 3660, 32771, 13546, 44650, 9566, 16758, 4587, 9957, 8978, 29538, 21542, 6027, 3660, 20328, 9640, 14407, 11933, 1829, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..37ccd439f8634f0919a6395f5d56831b1eb43a1e
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4318, "start": 19.64, "end": 43.18, "text": "بسم الله الرحمن الرحيم موضوعنا اليوم عن عائلة كيميائية جديدة مجموعة وظيفية جديدة اللي هي ال aethers طبعا على طول عدد كبير منكم هيتذكر ان ال aethers اللي هم الصيغة العامة ROR يعني Oxygen محصورة بين ذرتين", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 3714, 2407, 11242, 45367, 8315, 45595, 20498, 18871, 6225, 16373, 37977, 9122, 32640, 1829, 16373, 10632, 10874, 16254, 41891, 3714, 7435, 2304, 2407, 27884, 4032, 19913, 33911, 10632, 10874, 16254, 41891, 13672, 1829, 39896, 2423, 257, 3293, 433, 23032, 3555, 3615, 995, 15844, 23032, 12610, 6225, 3215, 3215, 9122, 3555, 13546, 9154, 24793, 39896, 2655, 8848, 37983, 16472, 2423, 257, 3293, 433, 13672, 1829, 8032, 2304, 31767, 1829, 17082, 3660, 18863, 10943, 3660, 497, 2483, 37495, 22653, 16489, 8647, 3714, 5016, 9381, 13063, 3660, 49374, 29910, 43500, 9957], "avg_logprob": -0.14548787611479663, "compression_ratio": 1.6995073891625616, 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المختبر يعني نفترض ان حد عنده بنزين burner مولعه هنا و قاعد بيشتغل و هنا فيه وعاء فيه ether مفتوح ال ether نفسه بتبخر سبعة و تلاتين احنا مرات في غزة الحرارة سبعة و تلاتين طبعا هو بتبخر على كل الدرجات و كل ما ارتفعت الحرارة بتزيد التبخر و لذلك ممكن و ال ether هنا و فيناعرف مكان تاني", "tokens": [2407, 46958, 5016, 22807, 4032, 5296, 8848, 23275, 7251, 2304, 12984, 1211, 16490, 9566, 2288, 8978, 9673, 46456, 26890, 37495, 22653, 8717, 5172, 2655, 43042, 16472, 11331, 3215, 43242, 3224, 44945, 11622, 9957, 36116, 3714, 12610, 3615, 3224, 34105, 4032, 12174, 995, 22488, 4724, 1829, 8592, 2655, 17082, 1211, 4032, 34105, 8978, 3224, 4032, 3615, 16606, 8978, 3224, 37096, 3714, 5172, 2655, 2407, 5016, 2423, 37096, 8717, 36178, 3224, 39894, 3555, 34740, 8608, 3555, 27884, 4032, 6055, 1211, 9307, 9957, 1975, 5016, 8315, 3714, 2288, 9307, 8978, 32771, 11622, 3660, 21542, 2288, 9640, 3660, 8608, 3555, 27884, 4032, 6055, 1211, 9307, 9957, 23032, 3555, 3615, 995, 31439, 39894, 3555, 34740, 15844, 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بيتبخر واضح؟ تماما زي التعامل مع وقود السيارات أو مع التنر هذه المراكبات الكيميائية بحاجة إلى نوع من الحذر الشديد", "tokens": [270, 393, 3745, 2610, 30767, 1829, 19446, 4724, 1829, 38251, 2407, 3224, 37495, 22653, 3714, 43020, 7251, 8592, 2655, 30241, 4032, 7251, 25957, 1211, 11331, 16572, 28671, 6156, 6027, 2655, 3615, 10943, 1211, 20449, 2423, 37096, 4724, 5016, 26108, 3660, 30731, 11331, 8848, 2288, 5296, 33456, 31439, 588, 932, 5136, 712, 4032, 46740, 8717, 47432, 3660, 32771, 20292, 7649, 9154, 9778, 5172, 11242, 3660, 37495, 22653, 4724, 1829, 1863, 29245, 3215, 4386, 4724, 36081, 3555, 34740, 4032, 46958, 5016, 22807, 46811, 10943, 995, 30767, 1829, 16712, 3615, 10943, 1211, 20449, 4032, 4587, 23328, 21136, 1829, 9640, 9307, 34051, 20449, 16712, 1863, 2288, 29538, 9673, 23557, 4117, 3555, 9307, 33251, 32640, 1829, 16373, 10632, 4724, 5016, 26108, 3660, 30731, 8717, 45367, 9154, 21542, 8848, 2288, 25124, 16254, 3215], "avg_logprob": -0.14746094110887498, "compression_ratio": 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كربونتين واجيتها بدي ارجع اسم المركب كأنه ال cane عادي ابحث عن اطول سلسلة اطول سلسلة تلاتة مركبة بروبين اربعة بيوتين خمسة بنتين و هكذا طيب بعد ما اطول اطول سلسلة يعني هاي هذا مركب", "tokens": [2304, 3615, 32887, 5172, 3660, 23032, 1829, 3555, 2423, 7649, 45164, 9673, 31747, 3555, 9122, 26890, 4032, 41185, 1975, 1829, 49115, 1975, 1829, 49115, 20449, 8315, 3224, 1975, 4117, 3794, 29245, 9957, 3660, 49374, 9122, 25513, 11536, 2655, 9957, 4032, 26108, 36081, 11296, 4724, 16254, 1975, 47341, 3615, 24525, 2304, 9673, 31747, 3555, 9122, 33456, 3224, 2423, 27518, 6225, 995, 16254, 48127, 5016, 12984, 18871, 1975, 9566, 12610, 8608, 1211, 3794, 37977, 1975, 9566, 12610, 8608, 1211, 3794, 37977, 6055, 1211, 9307, 3660, 3714, 31747, 49401, 4724, 32887, 3555, 9957, 1975, 25513, 27884, 4724, 1829, 35473, 9957, 16490, 2304, 3794, 3660, 4724, 29399, 9957, 4032, 8032, 4117, 15730, 23032, 1829, 3555, 39182, 19446, 1975, 9566, 12610, 1975, 9566, 12610, 8608, 1211, 3794, 37977, 37495, 22653, 8032, 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{"start": 591.03, "end": 591.67, "word": " اكسوجينة", "probability": 0.74072265625}, {"start": 591.67, "end": 591.81, "word": " بين", "probability": 0.9482421875}, {"start": 591.81, "end": 592.57, "word": " كربونتين", "probability": 0.77705078125}, {"start": 592.57, "end": 593.61, "word": " واجيتها", "probability": 0.65899658203125}, {"start": 593.61, "end": 593.87, "word": " بدي", "probability": 0.642333984375}, {"start": 593.87, "end": 594.33, "word": " ارجع", "probability": 0.9158528645833334}, {"start": 594.33, "end": 594.75, "word": " اسم", "probability": 0.761962890625}, {"start": 594.75, "end": 595.61, "word": " المركب", "probability": 0.94482421875}, {"start": 595.61, "end": 596.69, "word": " كأنه", "probability": 0.8623046875}, {"start": 596.69, "end": 597.13, "word": " ال", "probability": 0.826171875}, {"start": 597.13, "end": 597.51, "word": " cane", "probability": 0.5810546875}, {"start": 597.51, "end": 598.35, "word": " عادي", "probability": 0.90576171875}, {"start": 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"temperature": 1.0}, {"id": 37, "seek": 93510, "start": 912.68, "end": 935.1, "text": "الان بهذا المثال كم نظام ترقيم استعملت حتى ممكن بالألوان تشايفينهم كيف صاروا واضحين هذا ال four تبقى لهان ان المجموعة اللتي بين القوسين موجودة على الموقع أربعة على السنسلة لكن هذا ترقيم تاني عشان هيك الأنسب لهذا الترقيم التاني اللي كنت كاتبه بالأزرق", "tokens": [6027, 7649, 39627, 15730, 9673, 12984, 6027, 9122, 2304, 8717, 19913, 10943, 6055, 2288, 4587, 32640, 44713, 25957, 1211, 2655, 11331, 49975, 3714, 43020, 20666, 10721, 1211, 2407, 7649, 6055, 8592, 995, 33911, 9957, 16095, 9122, 33911, 20328, 9640, 14407, 4032, 46958, 5016, 9957, 23758, 2423, 1451, 6055, 3555, 4587, 7578, 46740, 7649, 16472, 9673, 7435, 2304, 2407, 27884, 13672, 31371, 49374, 25062, 41779, 9957, 3714, 29245, 23328, 3660, 15844, 9673, 30543, 3615, 5551, 25513, 27884, 15844, 21136, 1863, 3794, 37977, 44381, 23758, 6055, 2288, 4587, 32640, 6055, 7649, 1829, 6225, 8592, 7649, 39896, 4117, 16247, 1863, 35457, 46740, 15730, 16712, 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تاني ممكن يصير كمان تالت و باجيتها ممكن أحطله double prime وارد بتصير الأمور أصعب لكن المبدأ بأمل أنه صار إيش واضح عندكم", "tokens": [28814, 1863, 5551, 5016, 9566, 43761, 11933, 1829, 8592, 2423, 39184, 5835, 23032, 3555, 3615, 995, 23758, 4724, 1829, 27842, 3615, 8592, 14739, 3224, 4724, 11622, 10943, 8978, 3224, 6055, 7649, 1829, 3714, 43020, 7251, 9381, 13546, 9122, 2304, 7649, 6055, 6027, 2655, 4032, 4724, 26108, 36081, 11296, 3714, 43020, 5551, 5016, 9566, 43761, 3834, 5835, 4032, 9640, 3215, 39894, 9381, 13546, 16247, 2304, 13063, 5551, 9381, 3615, 3555, 44381, 9673, 44510, 10721, 4724, 10721, 42213, 14739, 3224, 20328, 9640, 11933, 1829, 8592, 4032, 46958, 5016, 43242, 24793], "avg_logprob": -0.21787219502952662, "compression_ratio": 1.6032608695652173, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 935.8, "end": 936.06, "word": "إن", "probability": 0.46710205078125}, {"start": 936.06, "end": 936.58, "word": " أحطله", "probability": 0.720947265625}, {"start": 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كلها المجموعة التانية؟ مالهاش اسم و لو قلت هذه فنل شو المجموعة التانية؟ مالهاش اسم لكن ان نقول في سلسلة و هذه يا مسهلها مثوكسي و في سلسلة و هذه يا مسهلها فينوكسي القمر بيكون إيش؟", "tokens": [3555, 10721, 9566, 12610, 8608, 1211, 3794, 37977, 19446, 6055, 8592, 38688, 2407, 8592, 6055, 5172, 37983, 14407, 20666, 11933, 1829, 12984, 995, 5296, 28814, 1863, 45164, 12174, 1211, 2655, 29538, 50113, 1211, 23032, 3555, 4032, 8592, 28242, 11296, 9673, 7435, 2304, 2407, 27884, 16712, 7649, 10632, 22807, 3714, 6027, 3224, 33599, 24525, 2304, 4032, 45164, 12174, 1211, 2655, 29538, 6156, 1863, 1211, 13412, 2407, 9673, 7435, 2304, 2407, 27884, 16712, 7649, 10632, 22807, 3714, 6027, 3224, 33599, 24525, 2304, 44381, 16472, 8717, 39648, 8978, 8608, 1211, 3794, 37977, 4032, 29538, 35186, 47524, 3224, 1211, 11296, 50113, 2407, 4117, 3794, 1829, 4032, 8978, 8608, 1211, 3794, 37977, 4032, 29538, 35186, 47524, 3224, 1211, 11296, 6156, 9957, 2407, 4117, 3794, 1829, 25062, 29973, 4724, 1829, 30544, 11933, 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1440.14, "word": " كيمية", "probability": 0.9309895833333334}, {"start": 1440.14, "end": 1440.36, "word": " ال", "probability": 0.77294921875}, {"start": 1440.36, "end": 1440.98, "word": " alcohols", "probability": 0.5999755859375}, {"start": 1440.98, "end": 1441.38, "word": " اذا", "probability": 0.614990234375}, {"start": 1441.38, "end": 1441.6, "word": " ال", "probability": 0.96044921875}, {"start": 1441.6, "end": 1442.36, "word": " ethers", "probability": 0.7135009765625}, {"start": 1442.36, "end": 1442.86, "word": " they", "probability": 0.62939453125}, {"start": 1442.86, "end": 1443.12, "word": " can", "probability": 0.9501953125}, {"start": 1443.12, "end": 1443.3, "word": " be", "probability": 0.82666015625}, {"start": 1443.3, "end": 1443.84, "word": " prepared", "probability": 0.90625}, {"start": 1443.84, "end": 1444.22, "word": " from", "probability": 0.89208984375}, {"start": 1444.22, "end": 1445.18, "word": " alcohols", "probability": 0.799560546875}, {"start": 1445.18, 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"seek": 146967, "start": 1449.81, "end": 1469.67, "text": "ماذا؟ إن إيثانول يهاجم على إيثانول ويفقد ميّه وهذه المعادلة سابق وضحتها إيها إيثانول زي إيثانول يخص منهم ميّه يعني هذه المعادلة لو أريدها موزنة، ماذا أكتب هنا؟ H2O واضح؟ جزء يهاجم على التانى ويطلع ميّه ويكون له إيثر", "tokens": [2304, 45636, 995, 22807, 36145, 11933, 1829, 12984, 7649, 12610, 7251, 3224, 26108, 2304, 15844, 11933, 1829, 12984, 7649, 12610, 4032, 33911, 28543, 3714, 1829, 11703, 3224, 37037, 24192, 9673, 3615, 18513, 37977, 8608, 16758, 4587, 4032, 11242, 33753, 11296, 11933, 1829, 11296, 11933, 1829, 12984, 7649, 12610, 30767, 1829, 11933, 1829, 12984, 7649, 12610, 7251, 9778, 9381, 9154, 16095, 3714, 1829, 11703, 3224, 37495, 22653, 29538, 9673, 3615, 18513, 37977, 45164, 5551, 16572, 3215, 11296, 3714, 2407, 11622, 1863, 3660, 12399, 3714, 45636, 995, 5551, 4117, 2655, 3555, 34105, 22807, 389, 17, 46, 4032, 46958, 5016, 22807, 10874, 11622, 38207, 7251, 3224, 26108, 2304, 15844, 16712, 7649, 7578, 4032, 1829, 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"word": " ايش", "probability": 0.9012044270833334}, {"start": 1486.68, "end": 1487.04, "word": " اول", "probability": 0.92626953125}, {"start": 1487.04, "end": 1487.52, "word": " شيء", "probability": 0.548583984375}, {"start": 1487.52, "end": 1487.88, "word": " ممكن", "probability": 0.941162109375}, {"start": 1487.88, "end": 1488.3, "word": " يخطر", "probability": 0.9305419921875}, {"start": 1488.3, "end": 1488.46, "word": " ع", "probability": 0.52490234375}, {"start": 1488.46, "end": 1489.08, "word": " بالكم", "probability": 0.878173828125}, {"start": 1489.08, "end": 1490.72, "word": " يعني", "probability": 0.74267578125}, {"start": 1490.72, "end": 1490.9, "word": " لو", "probability": 0.9736328125}, {"start": 1490.9, "end": 1491.14, "word": " بدي", "probability": 0.953369140625}, {"start": 1491.14, "end": 1491.4, "word": " انا", "probability": 0.919189453125}, {"start": 1491.4, "end": 1491.74, "word": " دايم", "probability": 0.5685221354166666}, {"start": 1491.74, "end": 1491.98, "word": " في", "probability": 0.640625}, {"start": 1491.98, "end": 1492.1, "word": " ال", "probability": 0.9560546875}, {"start": 1492.1, "end": 1492.46, "word": " ether", "probability": 0.404052734375}, {"start": 1492.46, "end": 1492.96, "word": " شو", "probability": 0.87744140625}, {"start": 1492.96, "end": 1493.08, "word": " اللي", "probability": 0.959716796875}, {"start": 1493.08, "end": 1493.54, "word": " بسخنه", "probability": 0.889453125}, {"start": 1493.54, "end": 1493.7, "word": " مع", "probability": 0.99169921875}, {"start": 1493.7, "end": 1494.64, "word": " الحامض؟", "probability": 0.9334716796875}], "temperature": 1.0}, {"id": 61, "seek": 151288, "start": 1495.28, "end": 1512.88, "text": "ميثانول لو بدى داي إثل إيثار شو اللى بسخنه مع الحامض إثانول طيب لو بدى مثل إثل إيثار شو بدى أسخن مع الحامض واضحة الفكرة لو بدى مثل إثل إيثار", "tokens": [2304, 1829, 12984, 7649, 12610, 45164, 47525, 7578, 11778, 47302, 11933, 12984, 1211, 11933, 1829, 12984, 9640, 13412, 2407, 13672, 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0.7711181640625}, {"start": 1498.12, "end": 1498.54, "word": " شو", "probability": 0.839599609375}, {"start": 1498.54, "end": 1498.64, "word": " اللى", "probability": 0.692138671875}, {"start": 1498.64, "end": 1499.04, "word": " بسخنه", "probability": 0.9177734375}, {"start": 1499.04, "end": 1499.16, "word": " مع", "probability": 0.99267578125}, {"start": 1499.16, "end": 1499.76, "word": " الحامض", "probability": 0.9697265625}, {"start": 1499.76, "end": 1501.0, "word": " إثانول", "probability": 0.77197265625}, {"start": 1501.0, "end": 1501.48, "word": " طيب", "probability": 0.8640950520833334}, {"start": 1501.48, "end": 1501.84, "word": " لو", "probability": 0.96826171875}, {"start": 1501.84, "end": 1502.34, "word": " بدى", "probability": 0.935791015625}, {"start": 1502.34, "end": 1503.16, "word": " مثل", "probability": 0.989990234375}, {"start": 1503.16, "end": 1503.68, "word": " إثل", "probability": 0.9835611979166666}, {"start": 1503.68, "end": 1504.24, "word": " إيثار", 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"temperature": 1.0}, {"id": 109, "seek": 265100, "start": 2633.58, "end": 2651.0, "text": "و بيقدر يحمل واحد من الاتنين، مين اللي بيقدر يحمله؟ ال potassium المتناسب مع حجم ال cavity بناء على ذلك هو في الأول بيحمل ال potassium، بعدين هو بما حمله بيدخل جوا الخلية بزامو دخل، نجل ال potassium من برا لجوا", "tokens": [2407, 4724, 1829, 28543, 2288, 7251, 35571, 1211, 36764, 24401, 9154, 2423, 9307, 1863, 9957, 12399, 3714, 9957, 13672, 1829, 4724, 1829, 28543, 2288, 7251, 35571, 43761, 22807, 2423, 29547, 9673, 2655, 8315, 35457, 20449, 11331, 7435, 2304, 2423, 32425, 44945, 16606, 15844, 29910, 23275, 31439, 8978, 16247, 12610, 4724, 1829, 35571, 1211, 2423, 29547, 12399, 39182, 9957, 31439, 4724, 15042, 11331, 42213, 3224, 4724, 25708, 9778, 1211, 10874, 14407, 33962, 1211, 10632, 4724, 11622, 10943, 2407, 11778, 9778, 1211, 12399, 8717, 7435, 1211, 2423, 29547, 9154, 4724, 23557, 5296, 7435, 14407], "avg_logprob": -0.16036626344086022, "compression_ratio": 1.7614213197969544, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 2633.58, "end": 2633.8, "word": "و", "probability": 0.59423828125}, {"start": 2633.8, "end": 2634.18, "word": " بيقدر", "probability": 0.8583984375}, {"start": 2634.18, "end": 2634.74, "word": " يحمل", "probability": 0.98779296875}, {"start": 2634.74, "end": 2635.34, "word": " واحد", "probability": 0.98583984375}, {"start": 2635.34, "end": 2635.56, "word": " من", "probability": 0.9921875}, {"start": 2635.56, "end": 2636.1, "word": " الاتنين،", "probability": 0.732177734375}, {"start": 2636.1, "end": 2636.28, "word": " مين", "probability": 0.765380859375}, {"start": 2636.28, "end": 2636.38, "word": " اللي", "probability": 0.91455078125}, {"start": 2636.38, "end": 2636.7, "word": " بيقدر", "probability": 0.978271484375}, {"start": 2636.7, "end": 2637.94, "word": " يحمله؟", "probability": 0.9564208984375}, {"start": 2637.94, "end": 2638.18, "word": " ال", "probability": 0.6025390625}, {"start": 2638.18, "end": 2638.62, "word": " potassium", "probability": 0.341796875}, {"start": 2638.62, "end": 2639.44, "word": " المتناسب", "probability": 0.873046875}, {"start": 2639.44, "end": 2639.6, "word": " مع", "probability": 0.79541015625}, {"start": 2639.6, "end": 2639.9, "word": " حجم", "probability": 0.9903971354166666}, {"start": 2639.9, "end": 2640.0, "word": " ال", "probability": 0.64599609375}, {"start": 2640.0, "end": 2640.42, "word": " cavity", "probability": 0.7353515625}, {"start": 2640.42, "end": 2641.08, "word": " بناء", "probability": 0.8095703125}, {"start": 2641.08, "end": 2641.2, "word": " على", "probability": 0.72119140625}, {"start": 2641.2, "end": 2641.4, "word": " ذلك", "probability": 0.994873046875}, {"start": 2641.4, "end": 2641.56, "word": " هو", "probability": 0.72265625}, {"start": 2641.56, "end": 2641.68, "word": " في", "probability": 0.89599609375}, {"start": 2641.68, "end": 2641.92, "word": " الأول", "probability": 0.943359375}, {"start": 2641.92, "end": 2642.28, "word": " بيحمل", "probability": 0.9571533203125}, {"start": 2642.28, "end": 2642.38, "word": " ال", "probability": 0.9384765625}, {"start": 2642.38, "end": 2643.28, "word": " potassium،", "probability": 0.7783203125}, {"start": 2643.28, "end": 2643.76, "word": " بعدين", "probability": 0.819091796875}, {"start": 2643.76, "end": 2644.18, "word": " هو", "probability": 0.97802734375}, {"start": 2644.18, "end": 2644.56, "word": " بما", "probability": 0.93408203125}, {"start": 2644.56, "end": 2644.98, "word": " حمله", "probability": 0.9078776041666666}, {"start": 2644.98, "end": 2645.3, "word": " بيدخل", "probability": 0.904052734375}, {"start": 2645.3, "end": 2645.5, "word": " جوا", "probability": 0.75}, {"start": 2645.5, "end": 2645.98, "word": " الخلية", "probability": 0.9734700520833334}, {"start": 2645.98, "end": 2646.7, "word": " بزامو", "probability": 0.7320556640625}, {"start": 2646.7, "end": 2647.4, "word": " دخل،", "probability": 0.84271240234375}, {"start": 2647.4, "end": 2647.72, "word": " نجل", "probability": 0.98681640625}, {"start": 2647.72, "end": 2647.84, "word": " ال", "probability": 0.9765625}, {"start": 2647.84, "end": 2648.32, "word": " potassium", "probability": 0.9951171875}, {"start": 2648.32, "end": 2648.58, "word": " من", "probability": 0.99462890625}, {"start": 2648.58, "end": 2649.1, "word": " برا", "probability": 0.75341796875}, {"start": 2649.1, "end": 2651.0, "word": " لجوا", "probability": 0.9166666666666666}], "temperature": 1.0}, {"id": 110, "seek": 266414, "start": 2651.7, "end": 2664.14, "text": "فاهمتوا أين الجمال بفكرة crown ethers يعني بسرها انعكاس على واقع التطبيق الطبي بهك بنكون أنهينا هذا ال chapter اللي اسمه ال ethers", "tokens": [5172, 995, 16095, 2655, 14407, 5551, 9957, 25724, 2304, 6027, 4724, 5172, 4117, 25720, 11841, 6468, 433, 37495, 22653, 4724, 3794, 2288, 11296, 16472, 3615, 4117, 32277, 15844, 36764, 4587, 3615, 16712, 9566, 21292, 4587, 41950, 21292, 39627, 4117, 44945, 30544, 14739, 3224, 1829, 8315, 23758, 2423, 7187, 13672, 1829, 24525, 2304, 3224, 2423, 6468, 433], "avg_logprob": -0.31387060985230564, "compression_ratio": 1.4078947368421053, "no_speech_prob": 0.0, "words": [{"start": 2651.7, "end": 2652.24, "word": "فاهمتوا", "probability": 0.640478515625}, {"start": 2652.24, "end": 2652.44, "word": " أين", "probability": 0.65576171875}, {"start": 2652.44, "end": 2653.32, "word": " الجمال", "probability": 0.84619140625}, {"start": 2653.32, "end": 2653.8, "word": " بفكرة", "probability": 0.85345458984375}, {"start": 2653.8, "end": 2654.26, "word": " crown", "probability": 0.350830078125}, {"start": 2654.26, "end": 2654.92, "word": " ethers", "probability": 0.731201171875}, {"start": 2654.92, "end": 2655.34, "word": " يعني", "probability": 0.73583984375}, {"start": 2655.34, "end": 2655.9, "word": " بسرها", "probability": 0.75140380859375}, {"start": 2655.9, "end": 2657.14, "word": " انعكاس", "probability": 0.925048828125}, {"start": 2657.14, "end": 2657.36, "word": " على", "probability": 0.87255859375}, {"start": 2657.36, "end": 2657.88, "word": " واقع", "probability": 0.9889322916666666}, {"start": 2657.88, "end": 2658.56, "word": " التطبيق", "probability": 0.9854736328125}, {"start": 2658.56, "end": 2659.02, "word": " الطبي", "probability": 0.9150390625}, {"start": 2659.02, "end": 2659.74, "word": " بهك", "probability": 0.49322509765625}, {"start": 2659.74, "end": 2660.28, "word": " بنكون", "probability": 0.5845947265625}, {"start": 2660.28, "end": 2661.4, "word": " أنهينا", "probability": 0.73138427734375}, {"start": 2661.4, "end": 2661.9, "word": " هذا", "probability": 0.96240234375}, {"start": 2661.9, "end": 2662.04, "word": " ال", "probability": 0.6748046875}, {"start": 2662.04, "end": 2662.48, "word": " chapter", "probability": 0.6962890625}, {"start": 2662.48, "end": 2662.88, "word": " اللي", "probability": 0.77685546875}, {"start": 2662.88, "end": 2663.4, "word": " اسمه", "probability": 0.955078125}, {"start": 2663.4, "end": 2663.58, "word": " ال", "probability": 0.9033203125}, {"start": 2663.58, "end": 2664.14, "word": " ethers", "probability": 0.59027099609375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2664.95425, "duration_after_vad": 2531.0074999999956}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/DfMI5-FZy7w.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/DfMI5-FZy7w.srt
new file mode 100644
index 0000000000000000000000000000000000000000..18ef62b8a72e6efc210fdfe686d6c0d53610c04e
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/DfMI5-FZy7w.srt
@@ -0,0 +1,1382 @@
+1
+00:00:19,710 --> 00:00:23,950
+بسم الله الرحمن الرحيم المرة الماضية آخر شيء
+
+2
+00:00:23,950 --> 00:00:28,510
+اتكلمنا فيه عن تحضير ال carboxylic acids وربما
+
+3
+00:00:28,510 --> 00:00:33,890
+يعني كلكم ملاحظين أن عنوان الفصل هذا carboxylic
+
+4
+00:00:33,890 --> 00:00:38,130
+acids and their derivatives لاحظوا لما أقول
+
+5
+00:00:38,130 --> 00:00:42,860
+derivative يعني مشتقة يعني بنجيبها من إيش؟ من
+
+6
+00:00:42,860 --> 00:00:48,100
+الكربوكسيلك أسد ولذلك لو بنطلع على slide واحد
+
+7
+00:00:48,100 --> 00:00:53,500
+وبنحط هنا الكربوكسيلك أسد وبنفعله وقلنا إحنا إن
+
+8
+00:00:53,500 --> 00:00:58,460
+التفاعل الأساسي هو تفاعل الإبدال يعني بدنا نطلع
+
+9
+00:00:58,460 --> 00:01:04,220
+هذا ال OH ونحط شغلة مكانها واضح فلو فعلنا مع
+
+10
+00:01:04,220 --> 00:01:08,380
+الثيون الكلوريد على سبيل المثال في وجود base بنحط
+
+11
+00:01:08,380 --> 00:01:13,070
+ال CL بدل ال OH صار عند ال acid chloride الاسد
+
+12
+00:01:13,070 --> 00:01:20,810
+كلوريد الاسد
+
+13
+00:01:20,810 --> 00:01:25,950
+كلوريد الاسد كلوريد الاسد كلوريد الاسد كلوريد
+
+14
+00:01:25,950 --> 00:01:26,130
+كلوريد الاسد كلوريد الاسد كلوريد الاسد كلوريد
+
+15
+00:01:26,130 --> 00:01:26,530
+الاسد كلوريد الاسد كلوريد الاسد كلوريد الاسد
+
+16
+00:01:26,530 --> 00:01:27,970
+كلوريد الاسد كلوريد الاسد كلوريد الاسد كلوريد
+
+17
+00:01:27,970 --> 00:01:28,210
+الاسد كلوريد الاسد كلوريد الاسد كلوريد الاسد
+
+18
+00:01:28,210 --> 00:01:31,050
+كلوريد الاسد كلوريد الاسد كلوريد الاسد كلوريد
+
+19
+00:01:31,050 --> 00:01:34,650
+الاسد كلوريد الاسد كلوريد
+
+20
+00:01:38,040 --> 00:01:42,160
+هذا الجزء و من الحامض الثاني اللي بتفعل كان
+
+21
+00:01:42,160 --> 00:01:45,700
+يوكليوفايل كان يوكليوفايل اللي بيجينا R C double
+
+22
+00:01:45,700 --> 00:01:51,060
+bond O O واضح الحامض الثاني أصلا كان OH و
+
+23
+00:01:51,060 --> 00:01:54,840
+لليوكليوفايل لما يكون neutral بيفقد H الآن هذا
+
+24
+00:01:54,840 --> 00:01:59,020
+الشكل العام C double bond O O C double bond O هو
+
+25
+00:01:59,020 --> 00:02:05,760
+اللي بنسمي إحنا إيش acid anhydride unhydrate إذا
+
+26
+00:02:05,760 --> 00:02:10,080
+بالتفاعل الأول حضرنا ال acid chloride او الهيلايد
+
+27
+00:02:10,080 --> 00:02:15,720
+بالتفاعل الثاني حضرنا ال unhydrate الآن لو فعلنا
+
+28
+00:02:15,720 --> 00:02:19,440
+مع الكحول النيكليوفال اللي بده تهاجم ال O تحت ال
+
+29
+00:02:19,440 --> 00:02:24,700
+OH هيصير عندنا R C double bond O O R prime طبعا
+
+30
+00:02:24,700 --> 00:02:29,120
+هذا ال E star و
+
+31
+00:02:29,120 --> 00:02:35,150
+لو فعلنا مع ammonia derivative سواء NH3 ولا NH2R
+
+32
+00:02:35,150 --> 00:02:40,310
+ولا NHR2 المهم نيتروجين النيتروجين بتهاجم مكان ال
+
+33
+00:02:40,310 --> 00:02:45,770
+OH في هذه الحالة بده يطلع عندك الأمد سيضة بال bond
+
+34
+00:02:45,770 --> 00:02:53,310
+ON هذه الأمد سواء كانت NH2 ولا NHR ولا NR2 كل هذا
+
+35
+00:02:53,310 --> 00:03:02,240
+الكلام ممكن إذا بهذا الشكل بنكون حضرنا ال الأمد هدول
+
+36
+00:03:02,240 --> 00:03:07,020
+بشكل أساسي هم ال derivatives بتاع الكربوكسيلك أسد
+
+37
+00:03:07,020 --> 00:03:11,360
+فزي ما بنلاحظ إن كل هذه ال derivatives للكربوكسيلك
+
+38
+00:03:11,360 --> 00:03:16,680
+أسد من وأن حضرناها من نفس الكربوكسيلك أسد ربما
+
+39
+00:03:16,680 --> 00:03:21,680
+التفاعل الأخير اللي بتشوفوه تفاعل مختلف شوية مش
+
+40
+00:03:21,680 --> 00:03:26,620
+تفاعل إبدال لأ هو تفاعل أسد مع base يعني تخيلوا ال
+
+41
+00:03:26,620 --> 00:03:32,480
+base اللي هنا مثلا NaOH زي ما نفعل ال acetic acid
+
+42
+00:03:32,480 --> 00:03:35,740
+مع ال sodium hydroxide بسرعة تفاعل ال
+
+43
+00:03:35,740 --> 00:03:41,920
+neutralization بمعنى ال OH هتاخد ال H فقط منها مش
+
+44
+00:03:41,920 --> 00:03:49,940
+هتشيل ال OH, OH مع H هتعطينا ال الماء H2O والنا هنا
+
+45
+00:03:49,940 --> 00:03:56,020
+بيصير ايون موجب زي ما بتلاحظوا أنتوا إن هنا صار حم
+
+46
+00:03:56,020 --> 00:04:01,580
+ض زائد قاعدة ملح زائد ماء لو افترضنا إن الحمض acidic
+
+47
+00:04:01,580 --> 00:04:08,000
+acid زائد NaOH بتصير sodium acetate لما هذه تكون
+
+48
+00:04:08,000 --> 00:04:15,440
+خلينا نحط مثال حقيقي CH3C double bond OOH الآن
+
+49
+00:04:15,440 --> 00:04:21,940
+تفاعل ال neutralization إن ال OH مع ال H هذه
+
+50
+00:04:21,940 --> 00:04:28,540
+هيعملوا عندنا ال ميه صارها ايون سالب هذا ايون موجب
+
+51
+00:04:28,540 --> 00:04:30,980
+صوديوم استيت
+
+52
+00:04:33,070 --> 00:04:38,010
+CH3 هذا neutralization reaction أخر تفاعل إذا
+
+53
+00:04:38,010 --> 00:04:44,610
+تفاعلات الأحماض بشكل عام يا إما تفاعلات إبدال تبدل
+
+54
+00:04:44,610 --> 00:04:50,450
+فيها ال OH كاملة يا إما تفاعلات neutralization او
+
+55
+00:04:50,450 --> 00:04:55,750
+معادلة neutralization
+
+56
+00:04:57,520 --> 00:05:01,640
+أنه تفاعل ال neutralization الأخير التفاعلات
+
+57
+00:05:01,640 --> 00:05:03,240
+الأربع الأولانيين
+
+58
+00:05:05,900 --> 00:05:10,580
+substitution واضح يعني ضلكم اتذاكرين هذه الكلمة
+
+59
+00:05:10,580 --> 00:05:14,840
+لما نقولكم reaction of acids with alcohols is a
+
+60
+00:05:14,840 --> 00:05:18,100
+substitution reaction with ammonia or amine
+
+61
+00:05:18,100 --> 00:05:21,460
+derivative is a substitution with other acids with
+
+62
+00:05:21,460 --> 00:05:25,400
+thionyl chloride لكن reaction of acids with sodium
+
+63
+00:05:25,400 --> 00:05:31,740
+hydroxide is a neutralization reaction تفاعلمعادلة
+
+64
+00:05:31,740 --> 00:05:38,760
+حمض زائد قاعدة ملح زائد ماء واضح؟ إذ هيك بنكون مش
+
+65
+00:05:38,760 --> 00:05:44,800
+بس إحنا أخدنا تفاعلات الأحماض لأ أخدنا طرق تحضير
+
+66
+00:05:44,800 --> 00:05:48,400
+جميع العائلات يعني يوم ما بنيجي نقول والله كيف
+
+67
+00:05:48,400 --> 00:05:54,620
+بنحضر ال Easter على سبيل المثال هنقول حمض زائد كحول
+
+68
+00:05:55,200 --> 00:05:59,940
+حمض زائد كحول ولذلك هنا لو بدنا نيجي نركز أكتر على
+
+69
+00:05:59,940 --> 00:06:06,660
+ال Easter ال Easter دائما بيتكون من حمض و كحول
+
+70
+00:06:06,660 --> 00:06:12,480
+ولذلك ما أعرفش إذا هذه الصورة يمكن مش كثيرو واضحة لأ
+
+71
+00:06:12,480 --> 00:06:18,400
+بس بنعملها بوضوح إحنا لو أخدنا مثلا ابروبانووك أسد
+
+72
+00:06:18,400 --> 00:06:26,520
+خليني أخذ المعادلة المعادلة كاملة CH3 CH2 CH2 CH2
+
+73
+00:06:26,520 --> 00:06:26,660
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+74
+00:06:26,660 --> 00:06:35,240
+CH2 CH2 CH2 CH2
+
+75
+00:06:35,240 --> 00:06:38,400
+CH2
+
+76
+00:06:38,400 --> 00:06:41,080
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+77
+00:06:41,080 --> 00:06:41,100
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+78
+00:06:41,100 --> 00:06:41,120
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+79
+00:06:52,770 --> 00:06:57,670
+بناء على ذلك لو كنا بدنا نشوف الناتج CH3
+
+80
+00:07:00,330 --> 00:07:06,310
+CH2 CH2 C double bond O هذا الجزء أتي من حمض من
+
+81
+00:07:06,310 --> 00:07:09,850
+الحمض من الحمض من الحمض من الحمض من الحمض من الحمض
+
+82
+00:07:09,850 --> 00:07:09,990
+من الحمض من الحمض من الحمض من الحمض من الحمض من
+
+83
+00:07:09,990 --> 00:07:10,550
+الحمض من الحمض من الحمض من الحمض من الحمض من الحمض
+
+84
+00:07:10,550 --> 00:07:10,950
+من الحمض من الحمض من الحمض من الحمض من الحمض من
+
+85
+00:07:10,950 --> 00:07:11,550
+الحمض من الحمض من الحمض من الحمض من الحمض من الحمض
+
+86
+00:07:11,550 --> 00:07:13,550
+من الحمض من الحمض من الحمض من الحمض من الحمض من
+
+87
+00:07:13,550 --> 00:07:17,130
+الحمض من الحمض من الحمض من الحمض من الحمض من الحمض
+
+88
+00:07:17,130 --> 00:07:23,390
+الحمض من الحمض من الحمض من الحمض من الحمض من الحمض
+
+89
+00:07:23,390 --> 00:07:32,300
+من الحمض من ال Easter هو عبارة عن خليط من جزئين جزء
+
+90
+00:07:32,300 --> 00:07:35,500
+من الحامض اللي فيه ال C double bond O و جزء من
+
+91
+00:07:35,500 --> 00:07:42,680
+الكحول اللي متصل بالـ O العادية الآن لما بنيجي نسمي
+
+92
+00:07:42,680 --> 00:07:48,720
+هذا المركب لما بنيجي نسمي هذا المركب كيف بنسمي مثل
+
+93
+00:07:48,720 --> 00:07:53,540
+هذا المركب بنجيب في الأول الجزء تبع الكحول هذا
+
+94
+00:07:53,540 --> 00:07:58,680
+بنحطه في الأول بعدين الجزء تبع الحامض بنحطه بعدين
+
+95
+00:07:58,680 --> 00:08:04,080
+الآن من جزء الكحول باخد المجموعة المجموعة كام
+
+96
+00:08:04,080 --> 00:08:11,820
+carbon؟ تلاتة، تلاتة كربونات، شو هما؟ بروبل مش
+
+97
+00:08:11,820 --> 00:08:16,160
+لليوم بدنا نضل نقول بروبان، بروبان المركب المجموعة
+
+98
+00:08:16,160 --> 00:08:24,080
+بروبل واضح؟ بروبل وجزء الحامض باخده بس بنهيب ده
+
+99
+00:08:24,080 --> 00:08:30,780
+هاي eight ف butanoic acid بدو يصير ايش؟ بيوتانويت
+
+100
+00:08:30,780 --> 00:08:32,880
+بيوتانويت
+
+101
+00:08:33,880 --> 00:08:38,560
+ليش جزء الحامض أنا انهيته بالنهاية ايه لانه أنا
+
+102
+00:08:38,560 --> 00:08:43,660
+تخيلته مع ال O هذه صار كأنه سيضب البند O O minus
+
+103
+00:08:43,660 --> 00:08:49,140
+الآن كأنه ايون سالب يعني لو تخيلته بدل الاثل كان
+
+104
+00:08:49,140 --> 00:08:55,880
+عندكم صوديوم ايش هتسموا المركب صوديوم بيوتانويت لو
+
+105
+00:08:55,880 --> 00:09:02,270
+بوتاسيوم بوتاسيوم بيوتانويت لو اثل ethyl butanoate
+
+106
+00:09:02,270 --> 00:09:08,130
+فدائما هذا الشكل من الاسم هو اسم ال Easter جزء
+
+107
+00:09:08,130 --> 00:09:12,390
+الكحول في الأول مذكورة المجموعة لحظة بيقول بس
+
+108
+00:09:12,390 --> 00:09:17,380
+propyl ما حدش يقول propoxy باخد بس ال الكلي جروب
+
+109
+00:09:17,380 --> 00:09:21,840
+بربل و من الحامض لان اعتبرت كأنه جايب c double
+
+110
+00:09:21,840 --> 00:09:26,580
+bond o o minus اعتبرت كأنه ايون سالب بيوتانوويت
+
+111
+00:09:26,580 --> 00:09:32,680
+الآن هذه التسمية هنشوف عليها عدة أمثلة لحد ما
+
+112
+00:09:32,680 --> 00:09:38,920
+نتأكد لحد ما نتأكد تماما إن أصبح واضح تسمية ال
+
+113
+00:09:38,920 --> 00:09:45,470
+easters في ذهنكم دائما و أبدالما بنشوف شكل ال
+
+114
+00:09:45,470 --> 00:09:50,710
+Easter C double bond O OR إذا هذا Easter الإسم
+
+115
+00:09:50,710 --> 00:09:57,370
+العام تبعه إيش؟ مجموعة الكل و نهاية eight الآن هنا
+
+116
+00:09:57,370 --> 00:10:02,310
+شو مجموعة الكل؟ مثل إذا لازم يجيني في الأول مثل
+
+117
+00:10:02,310 --> 00:10:09,650
+الحامض اللي من كربونتين acidic acid طالما أسيتك أسد
+
+118
+00:10:09,650 --> 00:10:14,490
+إذا نحن حنحط أسيتيت طب لو ناس سموه بال أيوبك
+
+119
+00:10:14,490 --> 00:10:21,210
+ايثانويك أسيد ايثانويت فالميثل أسيتيت هي الميثل
+
+120
+00:10:21,210 --> 00:10:26,010
+ايثانويت لسبب بسيط إنه الأسيتك أسيد هو نفسه ال
+
+121
+00:10:26,010 --> 00:10:31,110
+ايثانويك أسيد واضح ال Acetic Acid اللي من كربونتين
+
+122
+00:10:31,110 --> 00:10:36,570
+هو نفسه ال Ethanoic Acid زي ما كمان ال Formic Acid
+
+123
+00:10:36,570 --> 00:10:41,150
+هو نفسه ال إيش ال Methanoic Acid هذا الكلام حكيناه
+
+124
+00:10:41,150 --> 00:10:44,150
+فدائما انظروا ل ال Alkyl group و اذكرواها في الأول
+
+125
+00:10:44,150 --> 00:10:48,510
+الآن هذا المركب اللي هنا شو ال Alkyl group اللي
+
+126
+00:10:48,510 --> 00:10:54,390
+موجودة فيه اثل و طالما إنكوا two carbons اذا اثل
+
+127
+00:10:55,120 --> 00:11:05,440
+أسيتيت أو اثل اثانويت هذا المركب إيش المجموعة مثل
+
+128
+00:11:05,440 --> 00:11:13,260
+مثل أربع كربونات بيوتانويت مثل بيوتانويت الآن
+
+129
+00:11:13,260 --> 00:11:17,720
+لاحظوا هذا المركب و هذا المركب بتشوفهم بيشبهوا بعض
+
+130
+00:11:17,720 --> 00:11:21,820
+حقيقة لو أي حد اتطلع they are structural isomers
+
+131
+00:11:21,820 --> 00:11:26,640
+بس بيختلفوا بمواقع الارتباط مرة هنا ال O مرتبطة
+
+132
+00:11:26,640 --> 00:11:30,780
+بالفنل و ال C double bond O بالمثل مرة ال O بالمثل
+
+133
+00:11:30,780 --> 00:11:35,500
+و ال C double bond O بالفنل لكن لو كنا بنسميهم الآن
+
+134
+00:11:35,500 --> 00:11:40,280
+هذا الجزء يجب أن يُذكر في الأول شو هذا الجزء؟ فنل
+
+135
+00:11:40,280 --> 00:11:46,020
+و Carbontene أسيتيت أو إيثانويت الآن لو بدأ أسمي
+
+136
+00:11:46,020 --> 00:11:52,540
+هذا المُركّب مثل .. هذا من أي حامض جاية؟ بنزويك
+
+137
+00:11:52,540 --> 00:12:01,300
+أسد بنزويك أسد بنزويت مثل بنزويت واضح؟ لاحظوا كثير
+
+138
+00:12:01,300 --> 00:12:05,940
+مرات بيمروا معاكم بالعربي بنزوات السوديوم و مرة
+
+139
+00:12:05,940 --> 00:12:10,860
+سألنا .. قولنا للطلاب ارسموا شكل السوديوم بنزويت
+
+140
+00:12:10,860 --> 00:12:19,860
+كيف بدنا نعمله؟ بتقولوا هاي البنزويت فنل سيضة
+
+141
+00:12:19,860 --> 00:12:25,420
+بالبند O O minus هذه البنزويت تلحق معها السوديوم
+
+142
+00:12:27,810 --> 00:12:33,650
+Sodium Benzoate مثل Benzoate بنفس المنطق تماما
+
+143
+00:12:36,540 --> 00:12:41,060
+يعني تسمية ال salt شبيهة بتسمية ال easter سوديوم
+
+144
+00:12:41,060 --> 00:12:46,640
+بنزويت مثل بنزويت الآن كل هدول عبارة عن easters
+
+145
+00:12:46,640 --> 00:12:52,620
+ضلكم الذاكرين شغلة إن ال easter في الأولويات جايب
+
+146
+00:12:52,620 --> 00:12:55,800
+أعلى الأولويات يعني أعلى من ال aldehyde و من ال
+
+147
+00:12:55,800 --> 00:12:59,520
+alcohol و من ال ketone و من ال carboxylic acid
+
+148
+00:12:59,520 --> 00:13:05,810
+ولذلك لو كنا بدنا نعطي أمثلة بتحتوي على أكثر من
+
+149
+00:13:05,810 --> 00:13:12,010
+مجموعة وظيفية بدنا ال Easter يكون في الأول، واضح؟
+
+150
+00:13:12,010 --> 00:13:15,550
+يعني بناخد جزء ال Easter في الأول، بنعتبر هذه
+
+151
+00:13:15,550 --> 00:13:20,210
+المجموعة الوظيفية زايدة، الآن رغم إنه الكلام الآن
+
+152
+00:13:20,210 --> 00:13:23,910
+عشان تكون الأمور واضحة عندكم، رغم إنه الكلام الآن
+
+153
+00:13:23,910 --> 00:13:32,750
+بيبدو بسيط لكن واقع التجربة بيقول إن نسبة 95% منكم
+
+154
+00:13:32,750 --> 00:13:38,190
+لانه ما بكتبوش كتير وما بعدوش كتير وما بتعبوش كتير لا
+
+155
+00:13:38,190 --> 00:13:43,840
+يجيبوا سؤال تسمية ال Easter صح التجربة جديش بتقول
+
+156
+00:13:43,840 --> 00:13:52,040
+95% ما بيجاوبوش صح رغم إن الكلام واضح ليش؟ بيبدأ
+
+157
+00:13:52,040 --> 00:13:55,880
+يخربطوا بيبدأ يقولوا هذا الديهايد حامل على موقع
+
+158
+00:13:55,880 --> 00:14:02,860
+واحد اثوكسي مثلا لأ هي ال سيطة بال bond O OR كلها E
+
+159
+00:14:02,860 --> 00:14:07,980
+star خلاص بتنتهي أحيانا بيسمي اثل بعدين بيجي يقول
+
+160
+00:14:07,980 --> 00:14:13,830
+one oxo كله دخل الـ C double bond O و الـ O ethyl
+
+161
+00:14:13,830 --> 00:14:18,570
+يعني الأصل في هذا المُركّب انه تتطلع على الهيكل
+
+162
+00:14:18,570 --> 00:14:23,570
+العام هذا ماعدل ذلك هدول إيش اللي موجودين عليه
+
+163
+00:14:23,570 --> 00:14:28,770
+Substitutes الآن هنا في عندي C double bond O و O
+
+164
+00:14:28,770 --> 00:14:32,770
+ethyl إذا المُركّب E star فلو أنا كنت بدي أسمي بدي
+
+165
+00:14:32,770 --> 00:14:39,420
+أحط في البداية Ethane و في أخر الاسم اعد الكربونات
+
+166
+00:14:39,420 --> 00:14:43,860
+الآن واحد اثنين تلاتة أربعة إذا هذا المركب حقيقة
+
+167
+00:14:43,860 --> 00:14:51,960
+اثن ايش بيوتانو ويت ethyl butanoate الآن هذا ال
+
+168
+00:14:51,960 --> 00:14:55,760
+ethyl butanoate بيحمل مجموعات شو المجموعات اللي
+
+169
+00:14:55,760 --> 00:15:00,100
+بيحملها بنذكرها alphabetically على ال اثنين كلورو و
+
+170
+00:15:00,100 --> 00:15:04,680
+على ال تلاتة أوكزو هذا كيتون رجع لأصله لما يكون مش
+
+171
+00:15:04,680 --> 00:15:09,180
+هو العائلة شو بده أسميه أوكزو إذا هذا إثل و دائما
+
+172
+00:15:09,180 --> 00:15:14,900
+بنسيب فراغ بين مجموعة القلقل و باقي الإسم فبصير
+
+173
+00:15:14,900 --> 00:15:26,150
+إثلتنين كلورو نكتب لتنين اثلتو كلورو ثري أكزو
+
+174
+00:
+
+223
+00:20:52,140 --> 00:20:56,740
+فنل بروبانويت الآن هذا الفنل بروبانويت إيجي على
+
+224
+00:20:56,740 --> 00:21:05,070
+نمرة تلاتة منهأجزو صار اثري أجزو في نل او في نل
+
+225
+00:21:05,070 --> 00:21:13,310
+اثري أجزو بربا نويت واضح؟ اتفضلي اثل اول مجموع اسم
+
+226
+00:21:13,310 --> 00:21:18,470
+بعدها بنت .. بنتاي و ايه؟ الان هنا في عند اثل هي
+
+227
+00:21:18,470 --> 00:21:24,290
+جزء ال Easter عدت واحد اتنين تلاتة اربعة خمسة
+
+228
+00:21:24,290 --> 00:21:27,690
+فقالت بنتاي
+
+229
+00:21:29,570 --> 00:21:38,250
+بنتين و ويت واضح الآن هذه البنتين الأين وين بتبدأ
+
+230
+00:21:38,250 --> 00:21:45,190
+اذا اثن اتو بنتين و ويت لاحظوا انا مابنحطش قبلها
+
+231
+00:21:45,190 --> 00:21:50,510
+شرطة لأن هذه كلمة مفصولة عن هدولفي تسمية ال
+
+232
+00:21:50,510 --> 00:21:54,870
+Easter's ال Easter's زي ما بتسموه Sodium فراغ
+
+233
+00:21:54,870 --> 00:21:59,690
+Hydroxide Sodium فراغ Acetate في فراغ هنا مش شرطة
+
+234
+00:21:59,690 --> 00:22:05,490
+مش كلمة واحدة بتيألي يعني هذه المجموعة من الأمثلة
+
+235
+00:22:05,490 --> 00:22:10,990
+ل Easter مع مجموعات وظيفية مختلفة يعني كافية
+
+236
+00:22:10,990 --> 00:22:14,590
+لتوضيح طريقة تسمية هذه المركبات
+
+237
+00:22:17,340 --> 00:22:23,060
+الان هنا تأكيد طبعا كيف بنكون ال Easter هاي كمان
+
+238
+00:22:23,060 --> 00:22:30,100
+معادلتين تأكيديات حمض زائد كحول حمض زائد كحول و
+
+239
+00:22:30,100 --> 00:22:34,680
+دائما بالكوتيجو الكحول يتخلو يحل محل ال OH و الاسم
+
+240
+00:22:34,680 --> 00:22:41,000
+من جزئين يعني هذا اثل استيت او اثانويت هذا مثل
+
+241
+00:22:41,000 --> 00:22:51,250
+واحداتنين تلاتة بروبانويت و هكذاالان هذه ال
+
+242
+00:22:51,250 --> 00:23:00,070
+easters مشهور عنها ان ذات رائحة جميلة ولذلك احيانا
+
+243
+00:23:00,070 --> 00:23:04,170
+تستخدم في المراكبات العطرية لكن اكثر تستخدم
+
+244
+00:23:04,170 --> 00:23:10,450
+كاضافات للاطعمة وهي حقيقة اللي بتعطي الروائح
+
+245
+00:23:10,450 --> 00:23:16,610
+المميزة .. الروائح المميزة لكثير من الفواكه
+
+246
+00:23:16,940 --> 00:23:20,280
+فبتلاحظوا أنه الريحة المميزة للواحد لما بيشم
+
+247
+00:23:20,280 --> 00:23:27,320
+الفراولة بيشم المشمش في رائحة مميزة له الآن هذه
+
+248
+00:23:27,320 --> 00:23:31,500
+الرائحة المميزة من ال easters so easters are
+
+249
+00:23:31,500 --> 00:23:38,340
+smelly stuffs يعني مواد رائحة بالمجمل جيدة فعلى
+
+250
+00:23:38,340 --> 00:23:43,060
+سبيل المثال هذا ال easter الأول مثل من ال butanoic
+
+251
+00:23:43,060 --> 00:23:48,790
+acid مثل ال butanoateهذا اللي بيعطي ريحة الطفاح
+
+252
+00:23:48,790 --> 00:23:55,450
+الابل فالريحة تبعت الطفاح مثل ال butanoid هو اللي
+
+253
+00:23:55,450 --> 00:24:01,030
+بيعطي ريحة الطفاح الان يبدو ال butanoic acid متكرر
+
+254
+00:24:01,030 --> 00:24:07,230
+كتير يعني لو بدل ال مثل حطينا sh3 صار مثل فيومثل
+
+255
+00:24:07,230 --> 00:24:17,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+256
+00:24:17,950 --> 00:24:18,530
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+257
+00:24:18,530 --> 00:24:24,570
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+258
+00:24:24,570 --> 00:24:27,430
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+259
+00:24:27,430 --> 00:24:31,650
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+260
+00:24:31,650 --> 00:24:32,870
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+261
+00:24:32,870 --> 00:24:33,370
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+262
+00:24:33,370 --> 00:24:33,390
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+263
+00:24:33,390 --> 00:24:38,310
+مثل مثل مثو الاثل مثل بيوتانويت هذا اثل بيوتانويت
+
+264
+00:24:38,310 --> 00:24:43,290
+لما يصير اثل بيوتانويت بيصير رائحة الفني بالز
+
+265
+00:24:43,290 --> 00:24:50,930
+عارفينه الاناناس الاناناس اه الان لو صار بنتل يعني
+
+266
+00:24:50,930 --> 00:24:58,030
+خمس كربونات بنتل بيوتانويت مختلفين على الاناناس
+
+267
+00:24:58,030 --> 00:25:06,540
+اناناسبنت الابيوتانويت هذا ريحة الابريكوت المشمش
+
+268
+00:25:06,540 --> 00:25:13,620
+مش الخوخ الابريكوت مشمش apricosen بالالماني الخوخ
+
+269
+00:25:13,620 --> 00:25:19,620
+فريشي أو هات إشي الآن
+
+270
+00:25:19,620 --> 00:25:24,580
+في النهاية كيف بنجيب ال E star؟
+
+271
+00:25:26,760 --> 00:25:31,860
+كحول اتطلعوا معاه، كحول هي كحول جيبنا كحول من San
+
+272
+00:25:31,860 --> 00:25:36,220
+Salvador و acid من Honolulu شبكناهم شو اعطونا
+
+273
+00:25:36,220 --> 00:25:42,840
+Easter طيب السؤال عاد لو يا تورا الكحول و الحامض
+
+274
+00:25:42,840 --> 00:25:46,260
+كانوا بجزء واحد ممكن يتفاعلوا؟
+
+275
+00:25:48,950 --> 00:25:54,490
+يعني على طرف الجزيء حامض و على الطرف التاني كحول،
+
+276
+00:25:54,490 --> 00:25:57,750
+بتفاعلوا ولا بتفاعلوش؟ واجده إيش بيكون اسمه
+
+277
+00:25:57,750 --> 00:26:04,910
+التفاعل؟لأ إله اسم إذا فعلت جزيئين مفصولين عن بعض
+
+278
+00:26:04,910 --> 00:26:07,670
+زي هيك وعمله مركّب إيش قولنا هذا التفاعل
+
+279
+00:26:07,670 --> 00:26:12,870
+Intermolecular إذا جبت الجزيئين شبكت
+
+280
+00:26:12,870 --> 00:26:17,110
+Intermolecular reaction خلّينا نشوف إنه بنقدر إحنا
+
+281
+00:26:17,110 --> 00:26:24,710
+فعلا نحطبنقدر نحط حامض على أحد الأطراف و كحول على
+
+282
+00:26:24,710 --> 00:26:28,490
+الطرف التالي و نخليهم يتفاعلوا يعني زي ما نيجي
+
+283
+00:26:28,490 --> 00:26:33,710
+تماما نقول هنا C double bond O OH هذا إيش؟ حامض
+
+284
+00:26:33,710 --> 00:26:42,190
+CH2 CH2 CH2 CH2 خلينا هنا نحط OH الآن في هذا
+
+285
+00:26:42,190 --> 00:26:50,500
+المركب إيش موجود عندكم؟ acid و alcohol عادةالكحول
+
+286
+00:26:50,500 --> 00:26:57,200
+بتفاعل مع الحامض كان يوكليوفايل وبيطرد يعني هذه
+
+287
+00:26:57,200 --> 00:27:05,220
+بدأ تيجي ها و تطرد ايش ال OH واضح نفس التفاعل هو
+
+288
+00:27:05,220 --> 00:27:09,460
+لو كانوا مفصلين مجرد ان انا هذا ممكن اكون كاتب CH3
+
+289
+00:27:09,460 --> 00:27:13,280
+و هذا CH3OH كيف كنت اكمله يعني تخيلوا ال
+
+290
+00:27:13,280 --> 00:27:17,940
+Intermolecular reaction لو هذا زي هيككيف كنتوا
+
+291
+00:27:17,940 --> 00:27:23,060
+تكملوا؟ من هنا يهاجم و من هنا يطرد الان هذولة
+
+292
+00:27:23,060 --> 00:27:28,940
+كانوا ضمن جزء واحد ايش المانع؟ مش ولا مانع الان
+
+293
+00:27:28,940 --> 00:27:37,320
+الناتج C double bond O واحد و هنا O بهذا الشكل
+
+294
+00:27:37,320 --> 00:27:46,020
+طبعا ال O H مع ال Hالان لاحظوا الناتج المتكول لو
+
+295
+00:27:46,020 --> 00:27:51,800
+بدى اعطيه وصف هو عبارة عن ايش؟ Cyclic Easter هو
+
+296
+00:27:51,800 --> 00:27:57,860
+عبارة عن C double bond OOR لكن موجودين بحلقة فهذا
+
+297
+00:27:57,860 --> 00:28:05,580
+الناتج هو عبارة عن Cyclic Easterواضح؟ الان ال
+
+298
+00:28:05,580 --> 00:28:13,220
+cyclic esters اللي هم اسم عام بنسميهم lactones ال
+
+299
+00:28:13,220 --> 00:28:22,000
+cyclic esters بنسميهم lactones الان
+
+300
+00:28:22,000 --> 00:28:28,140
+لو جينا قولنالكم lactones are cyclic amides or
+
+301
+00:28:28,140 --> 00:28:38,140
+cyclic anhydridesاللاكتونز are cyclic esters طبعا
+
+302
+00:28:38,140 --> 00:28:44,980
+مرات عشان يوضحوا كده كبر الحلقة تبعت هذا ال cyclic
+
+303
+00:28:44,980 --> 00:28:49,570
+esters يعني هذه الحلقة الآن خماسيةلو كانت ال
+
+304
+00:28:49,570 --> 00:28:52,770
+oxygen على هذه الكربون نشبكناها كانت ممكن تكون
+
+305
+00:28:52,770 --> 00:28:56,110
+حلقة رباعية لو ال oxygen هنا نشبكناها ممكن تكون
+
+306
+00:28:56,110 --> 00:29:01,250
+حلقة ثلاثية ولذلك مرات بيستعملوا الرموز اللاتينية
+
+307
+00:29:01,250 --> 00:29:04,890
+بيقولوا خلينا نيجي جنب السيضة بال bond O ونبدأ
+
+308
+00:29:04,890 --> 00:29:11,830
+نقول AlphaBeta Gamma الآن ال Oxygen اللي عملت ال
+
+309
+00:29:11,830 --> 00:29:17,210
+Easter محمولة على أي Carbon Gamma ولذلك هذا مرات
+
+310
+00:29:17,210 --> 00:29:22,770
+كتير بيقولوا عنه Gamma Lactone طبعا بيصير سهل
+
+311
+00:29:22,770 --> 00:29:27,630
+عليكم انه تعرفوا ان ال Gamma Lactone هو تبع الحلقة
+
+312
+00:29:27,630 --> 00:29:33,950
+الخمسية واضح؟ اللي فيه ال Oxygen محمولة على الموقع
+
+313
+00:29:35,010 --> 00:29:39,230
+Gamma طب لو كانت ال Oxygen على الموقع Beta وقتها
+
+314
+00:29:39,230 --> 00:29:45,630
+شو بده يصير الحلقة رباعية Beta Lactone يعني لو
+
+315
+00:29:45,630 --> 00:29:51,030
+احنا اتينا الآن بعد ما خلصنا هذا و جيبنالكم سؤال
+
+316
+00:29:51,030 --> 00:29:55,410
+ارسمولنا في الامتحان Beta Lactone
+
+317
+00:30:04,170 --> 00:30:08,410
+Draw a general structure زي هي جايكم of a beta
+
+318
+00:30:08,410 --> 00:30:13,410
+-lactone الآن اللي شاطرة بتعرف اللي هو ال beta
+
+319
+00:30:13,410 --> 00:30:19,470
+-lactone Cyclic Eastern يعني هتبدأ هنا سيضة بال
+
+320
+00:30:19,470 --> 00:30:24,830
+bond O وتقول هاي ال carbon Alpha هاي ال carbon
+
+321
+00:30:24,830 --> 00:30:30,530
+Beta على ال beta حط ال oxygen هاي Alpha وهاي Beta
+
+322
+00:30:32,930 --> 00:30:39,230
+هي ال beta-lactone واضح؟ على موقع بيتا حط الأكسجين
+
+323
+00:30:39,230 --> 00:30:47,250
+و سكر الإيستر طبعا ال lactones مركبات مهمة لكن
+
+324
+00:30:47,250 --> 00:30:54,530
+اللي أهم منها في الدنيا بكتير مين؟
+
+325
+00:30:54,530 --> 00:31:02,400
+مين اللي أهم من ال lactone؟ أولاد عمهمولاد عم
+
+326
+00:31:02,400 --> 00:31:05,960
+اللاكتون طبعا مين ولاد عم اللاكتون؟ إيش اسمها
+
+327
+00:31:05,960 --> 00:31:10,560
+العيلة اللي بيكونوا ولاد عم اللاكتون؟ اسمها lactam
+
+328
+00:31:10,560 --> 00:31:16,340
+يعني زي ما في لاكتون في إيش lactam الآن لو قولنا
+
+329
+00:31:16,340 --> 00:31:21,620
+إيش ال lactams lactams are cyclic amides يعني لو
+
+330
+00:31:21,620 --> 00:31:22,580
+كررنا
+
+331
+00:31:24,870 --> 00:31:29,030
+نفس المعادلة اللى كانت عندنا قبل شوية C double
+
+332
+00:31:29,030 --> 00:31:34,050
+bond O OH وحطينا carbon تنتين تلاتة وهنا كنا حاطين
+
+333
+00:31:34,050 --> 00:31:41,470
+NH2 النيوكليوفايل وقلنا لهذا المركب سكر ايش اللى
+
+334
+00:31:41,470 --> 00:31:47,330
+بده يصير ال nitrogen بده تهاجم هنا تترد ال OH
+
+335
+00:31:47,330 --> 00:31:49,970
+لاحظوا شو النتج اللى هيتكون عندكم
+
+336
+00:32:08,570 --> 00:32:14,610
+cyclic amides are called lactams
+
+337
+00:32:15,920 --> 00:32:23,080
+إذا صار في علتين في Cyclic Esters اسمهم Lactones
+
+338
+00:32:23,080 --> 00:32:28,900
+وفي Cyclic Amides اسمهم Lactams إذا في عندي
+
+339
+00:32:28,900 --> 00:32:34,000
+Lactones و Lactams طبعا هذا لو قولت أي Lactam هاي
+
+340
+00:32:34,000 --> 00:32:40,360
+Alpha Beta Gamma هذا Gamma Lactam فالGamma Lactam
+
+341
+00:32:40,360 --> 00:32:47,480
+كم الحلقة تبعته؟خماسية طب لو كنت بده ال beta
+
+342
+00:32:47,480 --> 00:32:59,780
+lactam رباعية واضح نرسم
+
+343
+00:32:59,780 --> 00:33:00,700
+beta lactam
+
+344
+00:33:06,300 --> 00:33:12,300
+هي عندنا C double bond O carbon تنتين تلاتة هنا
+
+345
+00:33:12,300 --> 00:33:20,340
+نيتروجين هذه عبارة عن ايش هاي الفا
+
+346
+00:33:20,340 --> 00:33:27,560
+هاي بيتا هذه عبارة عن بيتا لكتب
+
+347
+00:33:30,900 --> 00:33:35,860
+تمام؟ الآن .. الآن بنحط الألاجة لاحظوا معايا ..
+
+348
+00:33:35,860 --> 00:33:40,220
+يمكن أنا من وجهة نظري .. يمكن أنا من وجهة نظري أن
+
+349
+00:33:40,220 --> 00:33:47,360
+أهم .. خدوها و أنتم غامضين .. يمكن أهم مركبات في
+
+350
+00:33:47,360 --> 00:33:52,640
+الكيميا اكتشفت و اشتغل عليها في القرن الماضي كله
+
+351
+00:33:52,640 --> 00:33:59,500
+ربما تكون ال beta lactams شوف لحد وين مهمةأهم
+
+352
+00:33:59,500 --> 00:34:06,380
+مركبات ممكن و من أهم اكتشافات القرن الماضي كله ال
+
+353
+00:34:06,380 --> 00:34:11,300
+beta-lactams ليش؟
+
+354
+00:34:11,300 --> 00:34:18,840
+ليش ال beta-lactams؟ عشان نظلنا متذكرينهم وين السر
+
+355
+00:34:18,840 --> 00:34:26,650
+اللي فيهم؟هما تعون المضادات الحيوية البنسالين وكل
+
+356
+00:34:26,650 --> 00:34:32,130
+مشتقاته beta lactams ال antibiotics طبعا في مضادات
+
+357
+00:34:32,130 --> 00:34:36,450
+غير ال beta lactams البنسالين بشكل عام هو عبارة عن
+
+358
+00:34:36,450 --> 00:34:41,550
+الحلقة الرابعية هذه مع حلقة خماسية و عليهم شوية
+
+359
+00:34:41,550 --> 00:34:46,650
+شغلات بيصير البنسالين واضح؟
+
+360
+00:34:48,010 --> 00:34:54,730
+اللي اكتشف تقريبا في الـ 1928 البنسالين الآن
+
+361
+00:34:54,730 --> 00:35:00,270
+المضادات الحيوية جديش بتعالج الأطفال يوميا الناس
+
+362
+00:35:00,270 --> 00:35:03,690
+جاعدة بتاخد مضادات حيوية والأطفال بياخدوا مضادات
+
+363
+00:35:03,690 --> 00:35:09,170
+حيوية وفيات الأطفال انخفضت من الاتهابات إلى ما
+
+364
+00:35:09,170 --> 00:35:13,590
+يقارب الصفريعني لو رجعتوا قبل خمسين، ستين، سبعين
+
+365
+00:35:13,590 --> 00:35:20,410
+سنة كان معدل كل أم وكل أب يقول بوضع طبيعي جدا أنا
+
+366
+00:35:20,410 --> 00:35:24,150
+ماتلي ولدين، أنا ماتلي تلت أولاد، أنا ماتلي أربع
+
+367
+00:35:24,150 --> 00:35:28,530
+.. كان الولد بيسخن بيموتاليوم بيصير السخونة مع
+
+368
+00:35:28,530 --> 00:35:32,310
+الأطفال و ربما بتلاحظوا عند أخوتكوا وجرايبكوا و ما
+
+369
+00:35:32,310 --> 00:35:37,130
+إلى ذلك على الدكتورها المضادات الحيوية و بيروحوا
+
+370
+00:35:37,130 --> 00:35:41,170
+الاتهاب مظبوط ولا لأ أساس هذه المضادات أول ما
+
+371
+00:35:41,170 --> 00:35:45,070
+اكتشفوا كانت من البنسليل و بعدين اتطورت كتير حسب
+
+372
+00:35:45,070 --> 00:35:47,990
+ال substitute ones اللي هان و هان و هان و هان و
+
+373
+00:35:47,990 --> 00:35:52,850
+حتى بعدين لما درسوا هذه المضادات الحيوية لاحظوا أن
+
+374
+00:35:52,850 --> 00:35:57,890
+الأساس فيهاوجود الحلقة الرباعية يعني الحلقة
+
+375
+00:35:57,890 --> 00:36:02,230
+الخماسية ليست أساس يعني بعض المضادات الحيوية اللي
+
+376
+00:36:02,230 --> 00:36:06,030
+اشتقوها ليش؟ لأنه بيشتقوا مضادات حتى يظلوا يقاوموا
+
+377
+00:36:06,030 --> 00:36:11,470
+البكتيريا اللي بتتأقلم على المضادات يعني كانت بدون
+
+378
+00:36:11,470 --> 00:36:16,630
+حلقة مشيت طبعا جيل كامل من المضادات الحيوية بدل
+
+379
+00:36:16,630 --> 00:36:20,510
+الحلقة الخماسية ده حضر تحضير خلوها حلقة سداسية
+
+380
+00:36:20,510 --> 00:36:25,160
+صارت عائلة جديدة cephalosporins وما إلى ذلكيعني
+
+381
+00:36:25,160 --> 00:36:30,140
+أساس البنساليل كمادة من الفقر حلقة رباعية مع
+
+382
+00:36:30,140 --> 00:36:34,500
+الخماسية لكن سر القوة تبع البنساليل في الحلقة
+
+383
+00:36:34,500 --> 00:36:38,640
+الرباعية ولا الخماسية؟ في ال beta-lactam ولذلك
+
+384
+00:36:38,640 --> 00:36:43,020
+العنوان بيصير أن المضادات الحيوية بيسموها beta
+
+385
+00:36:43,020 --> 00:36:48,940
+-lactam antibioticsيعني عنوين كتب كاملة هتدرسوها
+
+386
+00:36:48,940 --> 00:36:53,620
+بس اسمها beta lactam antibiotics بنسالين A بنسالين
+
+387
+00:36:53,620 --> 00:36:59,460
+B بنسالين G سفالوس بورين كذا بتقرأوا أسماء كثيرة
+
+388
+00:36:59,460 --> 00:37:04,280
+ومشتقات كثيرة الآن هي اللي بتستعمل في علاج
+
+389
+00:37:04,280 --> 00:37:10,300
+الالتهابات واضحة الفكرة فهذه ال cyclic amides الآن
+
+390
+00:37:10,300 --> 00:37:16,980
+شو سمناها؟Lactams و الـ Cyclic E stars Lactones
+
+391
+00:37:16,980 --> 00:37:27,980
+فما اتخربتوا ال Lactam بال Lactone طبعا
+
+392
+00:37:27,980 --> 00:37:35,060
+ال Amides كيف بتتكونمن تفاعل الأمونيا مع الحامض،
+
+393
+00:37:35,060 --> 00:37:40,900
+هذا عارفينه، واضح؟ أمونيا بتحل محل الحامض، الـ OH
+
+394
+00:37:40,900 --> 00:37:45,100
+طب يا تورا مع ال Easter لو فعلت
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg.srt
new file mode 100644
index 0000000000000000000000000000000000000000..16f353eeed7564296e7576853039c0bf4908e91b
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg.srt
@@ -0,0 +1,1445 @@
+
+1
+00:00:24,690 --> 00:00:29,550
+الحدي عشر في جزء الكيميا الرجوية العادى قبل ما
+
+2
+00:00:29,550 --> 00:00:35,290
+ننتقل لمقدمة البيت الاسطي اللى هو بعنوان amines
+
+3
+00:00:35,290 --> 00:00:43,010
+amines يعني مركبات ال nitrogen المركبات اللى فيها
+
+4
+00:00:43,010 --> 00:00:49,250
+ال nitrogen طبعا كلنا عارفين ان ال amine او ال
+
+5
+00:00:49,250 --> 00:00:49,810
+nitrogen
+
+6
+00:01:07,020 --> 00:01:13,380
+الان هذول ال ثلاث روابط في أبسط المركبات على
+
+7
+00:01:13,380 --> 00:01:18,940
+الإطلاق تبع ال نيتروجيز لما بيكونوا إيش هيدروجيز
+
+8
+00:01:18,940 --> 00:01:26,200
+بيكون عنده جزء الأمونيا يعني أبسط مركب للنيتروجيز
+
+9
+00:01:26,200 --> 00:01:30,640
+هو جزء الأمونيا الآن الأمونيا ممكن ما نعتبرهاش
+
+10
+00:01:30,640 --> 00:01:31,220
+مركبة
+
+11
+00:01:45,690 --> 00:01:47,650
+إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا
+
+12
+00:01:47,650 --> 00:01:48,170
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+13
+00:01:48,170 --> 00:01:48,250
+إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا
+
+14
+00:01:48,250 --> 00:01:49,730
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+15
+00:01:49,730 --> 00:01:51,150
+إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا
+
+16
+00:01:51,150 --> 00:01:51,170
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+17
+00:01:51,170 --> 00:01:51,390
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+18
+00:01:51,390 --> 00:02:01,170
+إبدال إذا بدنا نعمل إبدال إبدال إذا
+
+19
+00:02:01,170 --> 00:02:03,150
+بدنا نعمل إ
+
+20
+00:02:16,910 --> 00:02:20,930
+هذا بنسميه primary amine يعني نيتوجن متصل فيه بكام
+
+21
+00:02:20,930 --> 00:02:26,630
+carbon واحدة الآن لو بدّرنا التانية صار انتزلتين R
+
+22
+00:02:26,630 --> 00:02:33,370
+صار secondary amine لو بدّرنا التالتة صار tertiary
+
+23
+00:02:33,370 --> 00:02:37,310
+amine فال amines المشهورة ال primary و ال
+
+24
+00:02:37,310 --> 00:02:42,370
+secondary و ال tertiary الآن هل يا ترى ممكن نعمل
+
+25
+00:02:42,370 --> 00:02:49,030
+كمان R رابعة؟في مرات معينة لو جيبنا R موجبة فعنا
+
+26
+00:02:49,030 --> 00:02:53,970
+مع هذا زوج الإلكترونات بيعمل رابط بهذا الشكل
+
+27
+00:02:53,970 --> 00:02:58,650
+وبيعمل الـR الرابعة لكن في هذه الحالة لو حسبنا
+
+28
+00:02:58,650 --> 00:03:04,910
+الـformal charge عن الـNitrogen بتصير موجبة واضح؟
+
+29
+00:03:04,910 --> 00:03:11,290
+فبصير عنده صوت يعني طالما فيه موجب إذا في مرافق له
+
+30
+00:03:13,270 --> 00:03:18,630
+واضح طالما فيه موجب إذا فيه إله مرافق سارق تماما
+
+31
+00:03:18,630 --> 00:03:22,270
+زي لما كنتوا تاخدوا المركب المشهور مثلا ال
+
+32
+00:03:22,270 --> 00:03:26,430
+ammonium chloride كنتوا توصلوا على ال nitrogen
+
+33
+00:03:26,430 --> 00:03:34,990
+أربع روابط تحطوا على ال nitrogen اتش تدين تلاتة
+
+34
+00:03:34,990 --> 00:03:39,690
+أربعة رحزوج الإلكترونات و واحد منها دولة الارش هذا
+
+35
+00:03:39,690 --> 00:03:40,330
+الشكل ال
+
+36
+00:03:44,910 --> 00:03:52,370
+الأيون الموجة دائما بنتهيأ باسم ايش ات الايون
+
+37
+00:03:52,370 --> 00:03:57,030
+السالب كربونيت نيتريت سولفيت هذه الايونات السالبة
+
+38
+00:03:57,030 --> 00:04:02,470
+الايونات الموجة بنهيتها اونيوم امونيوم هيدرونيوم
+
+39
+00:04:02,470 --> 00:04:07,730
+اكزونيوم فوسفونيوم وضع ولذلك هذا ايش كان يتسمى
+
+40
+00:04:07,730 --> 00:04:08,470
+المركب
+
+41
+00:04:18,250 --> 00:04:23,590
+هذه النهاية onium نستعملها لأيون الموجة عشان ايه
+
+42
+00:04:23,590 --> 00:04:26,970
+لو بنيجي نسألكم the ending onium is used for
+
+43
+00:04:26,970 --> 00:04:31,210
+negative ions it's for the positive ions واضح
+
+44
+00:04:31,210 --> 00:04:36,670
+onium امونيوم اوزونيوم وهكذا الان هذا لما يكون
+
+45
+00:04:36,670 --> 00:04:40,350
+عليه مجموعات R بيقول فهذه الحالة
+
+46
+00:04:46,500 --> 00:04:50,560
+يعني عليها كام رابطة؟ أربع فبصير عندك ال
+
+47
+00:04:50,560 --> 00:04:54,200
+quaternary ammonium salts اللي هي R for N positive
+
+48
+00:04:54,200 --> 00:04:57,780
+أكيد طالما عندكوا N positive لازم يكون فيه معها
+
+49
+00:04:57,780 --> 00:05:04,580
+إيش؟ X سالبة واضح أكيد هيكون معها X سالبة وهذه
+
+50
+00:05:04,580 --> 00:05:08,560
+موجودة كثير الآن التشكيل العالمي ال nitrogen
+
+51
+00:05:08,560 --> 00:05:14,080
+compounds they are very importantin chemistry and
+
+52
+00:05:14,080 --> 00:05:19,060
+in biology يعني ال amino acids أساسي فيهم ال
+
+53
+00:05:19,060 --> 00:05:24,680
+nitrogen ال DNA ال RNA فيهم ال basis واضح ال
+
+54
+00:05:24,680 --> 00:05:29,920
+nitrogen basis اسمها ال alkaloids اللي هي المركبات
+
+55
+00:05:29,920 --> 00:05:32,300
+ال natural product اللي بتكون عادة
+
+56
+00:05:38,200 --> 00:05:44,760
+النيتروجين هو السبب ال basicity و لذلك بنسميها ال
+
+57
+00:05:44,760 --> 00:05:49,460
+caloids، ال caloids جاي من القالي، القالي يعني
+
+58
+00:05:49,460 --> 00:05:49,980
+قلوي
+
+59
+00:05:53,060 --> 00:05:59,080
+الان طبعا بالنسبة لخلاص ال amines كنا بنتذكر ان ال
+
+60
+00:05:59,080 --> 00:06:02,200
+nitrogen من أعلى السليبيات يعني ال hydrogen
+
+61
+00:06:02,200 --> 00:06:07,540
+bonding أساسا لما بنعرفه احنا بنربطه بتلت ذرات
+
+62
+00:06:07,540 --> 00:06:13,580
+أساسية إذا اتصلت ال hydrogen مع ال fluorine أو ال
+
+63
+00:06:13,580 --> 00:06:19,280
+oxygen أو ال nitrogen فهو أحد التلاتة اللي بيعملوا
+
+64
+00:06:19,280 --> 00:06:22,750
+hydrogen bondingواضح؟ ليش؟ لأن الـ
+
+65
+00:06:22,750 --> 00:06:26,650
+electronegativity للنيتروجين عالية حوالي تلاتة
+
+66
+00:06:26,650 --> 00:06:30,570
+فالـ unatched bond is very polar تعمل hydrogen
+
+67
+00:06:30,570 --> 00:06:33,710
+bonding is possible طالما في عندي hydrogen
+
+68
+00:06:33,710 --> 00:06:37,130
+bonding، إذا ال boiling points للأمين يفترض أن
+
+69
+00:06:37,130 --> 00:06:41,710
+تكون إيش؟ مرتفعة وزي ما قلنا طالما في عندي أزواج
+
+70
+00:06:41,710 --> 00:06:46,710
+إلكترونية على النيتروجين، إذا الـ nitrogen's are
+
+71
+00:06:46,710 --> 00:06:55,660
+basesالـ A كيف بنسمي ال Amines؟ ال Amines تسميتها
+
+72
+00:06:55,660 --> 00:07:01,720
+في ال IUPAC system سهلة مابنعطيهاش اسم عائلة
+
+73
+00:07:01,720 --> 00:07:07,680
+بنعتبرها substitute فبصير
+
+74
+00:07:07,680 --> 00:07:13,220
+أصل الاسم للألكين يعني زي ما الألكين على سبيل
+
+75
+00:07:13,220 --> 00:07:19,370
+المثال بنرسمه سلسلة من ستة، شو بنسميها؟هكسين لو
+
+76
+00:07:19,370 --> 00:07:23,370
+عليها على موقع اتنين كلور شو بيصير المقارنة two
+
+77
+00:07:23,370 --> 00:07:27,310
+chloro hexane الان لو عليها على موقع اتنين NH2
+
+78
+00:07:27,310 --> 00:07:34,830
+بنسميها two amino hexane فاحنا بنسمي المركبات ال
+
+79
+00:07:34,830 --> 00:07:40,250
+amines كأنها ال cans و بنستعمل ايش NH2
+
+80
+00:07:41,530 --> 00:07:47,430
+بنسميها إيش؟ قمائم الان يمكن هنا .. يمكن هنا البعض
+
+81
+00:07:47,430 --> 00:07:52,870
+يقول طب لو كانت مش هنقدش توقف، يعني هاي عندى ..
+
+82
+00:07:52,870 --> 00:07:58,310
+نفترض سلسلة بهذا الشكل، جدري نشوفها كام carbon؟
+
+83
+00:07:58,310 --> 00:08:01,970
+واحد، اتنين، تلاتة، اربعة، خمسة، ستة، ستة، ستة
+
+84
+00:08:01,970 --> 00:08:07,630
+الان لو افترضنا أن عندكم على هذا الموقع برومماذا
+
+85
+00:08:07,630 --> 00:08:12,850
+سنذكره إبراهيم إبراهيم طيب لو افترضنا الآن إنه على
+
+86
+00:08:12,850 --> 00:08:22,190
+هذا الموقع إجا عنده ال H2 امينو إيش هسميه امينو
+
+87
+00:08:22,190 --> 00:08:26,490
+امينو و بعدين هسمي الاسم طيب لو افترضت إنه اللي
+
+88
+00:08:26,490 --> 00:08:32,350
+إجت عنده مش NH2 NHCH3
+
+89
+00:08:39,710 --> 00:08:43,470
+هذا الشبكة بهذا الشكل من خلال الـ Nitrogen هذي إيش
+
+90
+00:08:43,470 --> 00:08:50,890
+اسمها؟ Amino طب لو كان الشبكة مجموعة NHCH3 ميثل
+
+91
+00:08:50,890 --> 00:08:59,150
+امايو طب لو الشبكة ن تنتل CH3 داي ميثل امايو،
+
+92
+00:08:59,150 --> 00:09:06,710
+واضح؟ إذن هذه المجموعة الـNH2 اسمها امايو الـNH
+
+93
+00:09:06,710 --> 00:09:07,570
+لحملة ميثل امايو
+
+94
+00:09:13,190 --> 00:09:20,990
+والألهج اللي حملة الدين مثل دايمثل
+
+95
+00:09:20,990 --> 00:09:32,110
+امايو و لذلك لو احنا بنانيجي نتطلع تكون عندنا مركب
+
+96
+00:09:43,560 --> 00:09:50,920
+تلاتة برومود اتنين تلاتة اربعة خمسة ستة تلاتة
+
+97
+00:09:50,920 --> 00:09:56,160
+برومود اتنين تلاتة اربعة خمسة ستة تلاتة برومود
+
+98
+00:09:56,160 --> 00:10:01,680
+اتنين تلاتة اربعة خمسة ستة اتنين تلاتة برومود
+
+99
+00:10:01,680 --> 00:10:02,240
+اتنين تلاتة برومود اتنين تلاتة برومود اتنين تلاتة
+
+100
+00:10:02,240 --> 00:10:02,460
+برومود اتنين تلاتة برومود اتنين تلاتة برومود اتنين
+
+101
+00:10:02,460 --> 00:10:02,680
+اتنين تلاتة برومود اتنين تلاتة برومود اتنين تلاتة
+
+102
+00:10:02,680 --> 00:10:03,440
+برومود ات
+
+103
+00:10:09,470 --> 00:10:13,950
+واضحين to dimethylaminohexane
+
+104
+00:10:58,850 --> 00:11:05,550
+الان بدنا نبحث عن أطول سلسلة ألفاتية أطول سلسلة
+
+105
+00:11:05,550 --> 00:11:08,750
+ألفاتية من 1،2،3،4
+
+106
+00:11:13,720 --> 00:11:19,620
+طبعا واحد اتنين تلاتة اربعة خمسة ستة بناء على ذلك
+
+107
+00:11:19,620 --> 00:11:25,680
+المركب اللي عندنا شو اسمه اكسين اكسين اكسين اكسين
+
+108
+00:11:25,680 --> 00:11:31,980
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+109
+00:11:31,980 --> 00:11:36,300
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+110
+00:11:36,300 --> 00:11:41,440
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+111
+00:11:41,440 --> 00:11:43,640
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+112
+00:11:47,630 --> 00:11:54,130
+الكلام في موازاة ولا لأ اثل مع ال oxygen اثل مع ال
+
+113
+00:11:54,130 --> 00:11:59,830
+nitrogen اثل امينو الآن لما بنشوفه من بين اليوتيوب
+
+114
+00:11:59,830 --> 00:12:11,510
+أولا تلاتة اثل امينو هذه مجموعة اتنين اثوكسي
+
+115
+00:12:11,510 --> 00:12:18,910
+علمناها اكسير واضح؟يعني مش بس الأمور بتقف عند مثل
+
+116
+00:12:18,910 --> 00:12:23,370
+أمينو ضاي مثل أمينو ممكن يكون عندكم إثل أمينو ضاي
+
+117
+00:12:23,370 --> 00:12:28,670
+إثل أمينو بروبل أمينو مثلا ضاي بروبل أمينو وممكن
+
+118
+00:12:28,670 --> 00:12:31,870
+كمان اللي يكونوا على الأمينو يكونوا مجمعتين
+
+119
+00:12:31,870 --> 00:12:36,310
+مختلفتين بأذكر التنتين بأسمعهم يعني لو أقول إثل و
+
+120
+00:12:36,310 --> 00:12:41,210
+مثل شو هسمي المجموعة إثل مثل أمينو
+
+121
+00:12:43,590 --> 00:12:47,870
+يعني اللي اتعلم organic كويس خلاص بصير تحل المشاكل
+
+122
+00:12:47,870 --> 00:12:52,050
+اللي بتواجهه لوحده طب لو ذكرنا ال ethoxy قبل ال
+
+123
+00:12:52,050 --> 00:12:58,710
+ethyl اشتغل alphabetical لما حرف الأول مايمشيش
+
+124
+00:12:58,710 --> 00:13:02,710
+معاك امشي على اللي بعده واضح؟ إذا لاجيت أن ال
+
+125
+00:13:02,710 --> 00:13:08,230
+ethoxy سابق في ال alphabetical سبجيها واضح؟ يعني
+
+126
+00:13:08,230 --> 00:13:11,790
+ارجعوا للي كتبنا مين سابق ethyl ولا ethoxy
+
+127
+00:13:18,030 --> 00:13:24,370
+اللي بيشتغل براحته يرتب الأمور Alpha Beta, إيش ما
+
+128
+00:13:24,370 --> 00:13:27,630
+بتكون المجموعات، بمشي حرف حرفة، واضحة فيك
+
+129
+00:13:34,790 --> 00:13:39,210
+طبعا لاحظوا هنا مثلا إيجا مع كثول، ضال الأساس
+
+130
+00:13:39,210 --> 00:13:42,650
+الكثول، يعني واحد، اتنين، تلاتة، أربعة، هذا
+
+131
+00:13:42,650 --> 00:13:45,650
+بيوتالول، وانت بيوتالول، على نبرة اتنين، ابروم،
+
+132
+00:13:45,650 --> 00:13:51,190
+مثلا على نبرة أربعة، أمين، واضح الفكرة؟ لو كان مع
+
+133
+00:13:51,190 --> 00:13:54,270
+الديهيد أو كيتون، نفس الأشياء، لو مع carboxylic
+
+134
+00:13:54,270 --> 00:14:00,110
+acid، نفس الأشياء، ومن هنا هتبدأ تلاقوا مثلا ال
+
+135
+00:14:00,110 --> 00:14:02,190
+amino acids
+
+136
+00:14:03,900 --> 00:14:08,120
+لما ندرس البروتينات، البروتينات من إيش بشكل أساسي
+
+137
+00:14:08,120 --> 00:14:14,100
+متكونة؟ من ال amino acids فلما نيجي نسمي، لما نيجي
+
+138
+00:14:14,100 --> 00:14:19,920
+نسمي، حق نعتبر أنه إحنا في عندنا ال acid زي هيك
+
+139
+00:14:19,920 --> 00:14:28,140
+مثلا، سي ده بيكون OH لو بيجينا هنا CH وحطينا هنا
+
+140
+00:14:28,140 --> 00:14:31,960
+NH2 CH2
+
+141
+00:14:53,340 --> 00:14:57,800
+الان في البيو كيميستر اذا بدنا نعطي اسم glycine
+
+142
+00:14:57,800 --> 00:15:00,340
+بيصير اسم شهرة تاني
+
+143
+00:15:06,760 --> 00:15:12,160
+هذه بدأت تسمى a mind أو أسمي للكيتون أو للالدهاي
+
+144
+00:15:12,160 --> 00:15:13,880
+أو للالكوبول
+
+145
+00:15:29,090 --> 00:15:33,330
+واضح؟ هاي أمثلة إضافية، هاي أطول سلسلة تلاتة
+
+146
+00:15:33,330 --> 00:15:38,630
+بروبين، على نجرة واحد أماين، one a minor بروبين،
+
+147
+00:15:38,630 --> 00:15:45,200
+هذا بروبينto aminopropane واضح؟ الان لاحظوا معاك
+
+148
+00:15:45,200 --> 00:15:49,420
+طب لو كنا بيجينا ال common nomenclature ال common
+
+149
+00:15:49,420 --> 00:15:53,880
+nomenclature وعطيناها قاعدة عامة كلنا بنذكر اسم
+
+150
+00:15:53,880 --> 00:15:58,760
+المجموعة و بعدها عائلة يعني لو كان أنا كله كنا
+
+151
+00:15:58,760 --> 00:16:02,500
+نسميه propane، نسميه chloride لو بروم، نسميه
+
+152
+00:16:02,500 --> 00:16:06,080
+propane، نسميه bromide لو و أش، نسميه propane،
+
+153
+00:16:06,080 --> 00:16:06,560
+نسميه alcohol
+
+154
+00:16:09,400 --> 00:16:18,860
+هذا البروبل هو اسم المجموعة و بعدين امين هذا
+
+155
+00:16:18,860 --> 00:16:24,500
+البروبل هو ايزو بروبل
+
+156
+00:16:33,510 --> 00:16:37,930
+و هكذا واضح طبعا هذه ال common nouns هتكون في
+
+157
+00:16:37,930 --> 00:16:43,490
+المركبات اللي هي المجموعات اللي اتعلمناها مثل اثر
+
+158
+00:16:43,490 --> 00:16:47,310
+بربل ايزو بربل ايزو بيوتل تيرتشير بيوتل المجموعات
+
+159
+00:16:47,310 --> 00:16:50,510
+اللي اتعلمناها في أشياء مااخدنا لاش اس المجموعات
+
+160
+00:16:50,510 --> 00:16:54,310
+مش هتاخد ال common nomenclature هذا مثلا ستة على
+
+161
+00:16:54,310 --> 00:16:59,190
+بوضع اتنين امين اتنين امين او اكسين مش هتلاقي انه
+
+162
+00:16:59,190 --> 00:17:05,670
+اخدنا اس المجموعةواضح؟ طبعا فى ناس ممكن يقولوا عنه
+
+163
+00:17:05,670 --> 00:17:09,930
+two hex الأمين لإنه سهل شوية لكن بعد هيك لو هانصر
+
+164
+00:17:09,930 --> 00:17:15,010
+شغلة و شغلة خلاص بتسموه إيش؟ أيوبة بتسموه أيوبة
+
+165
+00:17:15,010 --> 00:17:19,450
+تمام واضحة فكرة ال أيوبة ال nomenclature و ال
+
+166
+00:17:19,450 --> 00:17:21,890
+common nomenclature ال common nomenclature أيضا
+
+167
+00:17:21,890 --> 00:17:28,090
+إلها trait العائلة المجموعة تسمى إيش؟ العائلة
+
+168
+00:17:28,090 --> 00:17:29,530
+واضح؟
+
+169
+00:17:31,820 --> 00:17:36,060
+هذا المُركّب لو بجنب عليه وأطول سلسلة فيه
+
+170
+00:17:39,800 --> 00:17:44,360
+إذا هذا problem على مين راح واحد حامل كل هذه
+
+171
+00:17:44,360 --> 00:17:48,640
+المجموعة؟ مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+172
+00:17:48,640 --> 00:17:49,660
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+173
+00:17:49,660 --> 00:17:51,140
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+174
+00:17:51
+
+223
+00:23:02,170 --> 00:23:28,830
+نيتروجينكتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناترام
+
+224
+00:23:29,650 --> 00:23:35,910
+إنه هذه ethyl و ethyl و ethyl و ethyl و ethyl و
+
+225
+00:23:35,910 --> 00:23:41,010
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+226
+00:23:41,010 --> 00:23:43,710
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+227
+00:23:43,710 --> 00:23:44,510
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+228
+00:23:44,510 --> 00:23:45,090
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+229
+00:23:45,090 --> 00:23:45,670
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+230
+00:23:45,670 --> 00:23:51,290
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+231
+00:23:51,290 --> 00:23:54,950
+ethyl و ethyl و
+
+232
+00:23:59,000 --> 00:24:03,700
+بتذكرهم alphabetical اثل مثل امين الافضل
+
+233
+00:24:03,700 --> 00:24:11,320
+alphabetical يعني اثل مثل اثل مثل امين الخلاصة انه
+
+234
+00:24:11,320 --> 00:24:15,740
+التسمية بال common nomenclature التسمية بال common
+
+235
+00:24:15,740 --> 00:24:19,860
+nomenclature بنذكر فيها اسم المجموعة و بعدين بننهي
+
+236
+00:24:19,860 --> 00:24:26,770
+بالنهاية امين اللي هي العائلة واضح؟فزي ما بتلاحظوا
+
+237
+00:24:26,770 --> 00:24:30,890
+الأمينز أكتر من تسمية لهم أشهر نظام الـ Iopaque
+
+238
+00:24:30,890 --> 00:24:34,350
+أنه نعتبرهم ألكين وهي أمثلة إضافية حتى أنه
+
+239
+00:24:34,350 --> 00:24:39,310
+اترجعوها ال Iopaque بنذكرهم ألكينزي ال common
+
+240
+00:24:39,310 --> 00:24:46,450
+بنذكر المجموعة ثم العائلة الأهم في نظام تسمية تالت
+
+241
+00:24:46,450 --> 00:24:47,850
+حسب ال chemical abstract
+
+242
+00:25:06,820 --> 00:25:13,020
+بس لما بيسميه بيسميش طبعا مركب رباع بيوت الأمين لأ
+
+243
+00:25:13,020 --> 00:25:21,000
+بيسميه بيوتان أمينبعرفش إذا دي واضحة ولا بنزم أني
+
+244
+00:25:21,000 --> 00:25:27,160
+أوضحها أكتر لكم يعني خليني
+
+245
+00:25:27,160 --> 00:25:35,080
+أخد هذا المركب و أحط هنا OH عشان أنتوا تنتبهوا لما
+
+246
+00:25:35,080 --> 00:25:41,600
+أنا كنت أسمي هذا بيوتان
+
+247
+00:25:48,620 --> 00:25:56,180
+و أحطله one هذا ال IOPAC منه الان لما كنت أسميه
+
+248
+00:25:56,180 --> 00:26:04,600
+بال common nominative شو كنت أسميه؟ butyl و أحط
+
+249
+00:26:04,600 --> 00:26:12,820
+العائلة alcohol butyl alcohol okay butyl alcohol
+
+250
+00:26:12,820 --> 00:26:17,360
+الان الناس اللي بيعملوا على نظام تسمية تالف
+
+251
+00:26:21,690 --> 00:26:28,830
+عندي nh2، بدي أعطي العائلة أمين، يعني نغير هذه
+
+252
+00:26:28,830 --> 00:26:36,910
+نخليها nh2، فبصير بيوتان أمين، طب وهذا بيوت
+
+253
+00:26:36,910 --> 00:26:43,790
+الأمين، واضح تلاحظين أنه الفرق ما بينبيوتان و
+
+254
+00:26:43,790 --> 00:26:47,870
+بيوتين في كل الأحوال هذا النظام مابتيش يقتصر معالي
+
+255
+00:26:47,870 --> 00:26:51,730
+لكن مرات بنذكر أشياء اللي لو قرأتوها ماتحسوش
+
+256
+00:26:51,730 --> 00:26:54,790
+باستغراب احنا اللي بدنا نسمي عليه the iopac
+
+257
+00:26:54,790 --> 00:27:00,230
+nomenclature ان مراكبات ال amines بتتبع الalkenes
+
+258
+00:27:00,230 --> 00:27:04,490
+هي مشتقات للalkenes و لو كنا بتناقلكم ال common
+
+259
+00:27:04,490 --> 00:27:07,730
+nomenclatures تبعها فبنكتم المجموعة و بعدين ال
+
+260
+00:27:07,730 --> 00:27:14,400
+amine لكن لو قرأتوا اشي تانيما تستمر مش واضح؟
+
+261
+00:27:14,400 --> 00:27:19,940
+باختصار المركبات تبعت ال amines تتبع عائلة ال
+
+262
+00:27:19,940 --> 00:27:23,720
+alkanes يعني نهيتها إيفين بروبين بيوتين هكسل
+
+263
+00:27:23,720 --> 00:27:29,140
+whatever طبعا مركبات ال amines في الدنيا كتيرة
+
+264
+00:27:29,140 --> 00:27:33,700
+كلها مركبات في الكيميا الحلقية مش بطلب نحفظها بس
+
+265
+00:27:33,700 --> 00:27:38,100
+حتى تحسوا كدهش موضوع ال nitrogen موضوع واسع يعني
+
+266
+00:27:38,100 --> 00:27:43,010
+يمكن تقوله ربع الكيميا العضوية المركبات معاهواضح؟
+
+267
+00:27:43,010 --> 00:27:47,110
+البُركّب هذا الوحيد يمكن يعرفي أنه البنزينة اللي
+
+268
+00:27:47,110 --> 00:27:54,630
+عليها الأن H2O هي عبارة عن أنيليا الأن بالنسبة للـ
+
+269
+00:27:54,630 --> 00:27:59,010
+physical properties of amines بشكل عام احنا بيقول
+
+270
+00:27:59,010 --> 00:28:03,680
+أن ال physical properties ofhydrogen bonding
+
+271
+00:28:03,680 --> 00:28:10,440
+وبالتالي من ناحية من ناحية من ناحية مقارنة ال
+
+272
+00:28:10,440 --> 00:28:14,340
+boiling point تبعتهم يفترض انها ليش تكون عالية
+
+273
+00:28:14,340 --> 00:28:18,820
+مرتفعة طبعا اللي بده يعمل المقارنة ويفهمها جيدا
+
+274
+00:28:18,820 --> 00:28:24,120
+بده يقارن مع إشي مافيش فيه hydrogen bonding يعني
+
+275
+00:28:24,120 --> 00:28:26,640
+إشي فيه hydrogen bonding وإشي مافيه hydrogen
+
+276
+00:28:26,640 --> 00:28:29,200
+bonding وبده يوحد العوامل التانية
+
+277
+00:28:38,870 --> 00:28:42,670
+طب هذا ليش مرتفع كتير اكتر من هذا؟ بطل ال
+
+278
+00:28:42,670 --> 00:28:46,450
+molecular weight هو السبب و قداش بديكون السبب ال
+
+279
+00:28:46,450 --> 00:28:52,910
+hydrogen بدي ولذلك هلأ اعمللكم مثال كتير جميل أخد
+
+280
+00:28:52,910 --> 00:28:58,830
+من ال alkanes ال ethane و لاحظوا عندى ال ethane ال
+
+281
+00:28:58,830 --> 00:29:03,540
+molecular weight تبعه قداش تلاتينكامهم كامهم 12,
+
+282
+00:29:03,640 --> 00:29:09,400
+12, 24, 26 هيدروجين تلاتين و أخد الميث الأمين
+
+283
+00:29:09,400 --> 00:29:15,520
+الميث الأمين لو حسبنا ال molecular weight 31 هذا
+
+284
+00:29:15,520 --> 00:29:21,160
+أمين هذا الكلب و أخد الميثانول ال alcohol ال
+
+285
+00:29:21,160 --> 00:29:28,740
+molecular weight تبعه 32تجاوزا او تقريبا التلاتين
+
+286
+00:29:28,740 --> 00:29:31,640
+في ال molecular weight زي الواحد و التلاتين زي
+
+287
+00:29:31,640 --> 00:29:36,260
+الاتنين و التلاتين إذا هدولة التلات مراكبات equal
+
+288
+00:29:36,260 --> 00:29:39,040
+بالنسبالي .. اللي هم equal molecular weight فلو
+
+289
+00:29:39,040 --> 00:29:43,380
+اختلفوا بال boiling point هيكون اختلاف بسبب ال
+
+290
+00:29:43,380 --> 00:29:47,920
+molecular weight لأ لأ بنفتش على إشي تاني الآن لو
+
+291
+00:29:47,920 --> 00:29:53,480
+إجهنا اتطلعنا على قداش ال boiling point اللي هو
+
+292
+00:29:55,080 --> 00:30:04,760
+هنلاحظ ان الاثان ناقص 88 المثل أمين ناقص 6 جديش
+
+293
+00:30:04,760 --> 00:30:12,340
+زاد المثل أمين عن الاثان من ناقص 88 لناقص 6 82
+
+294
+00:30:12,340 --> 00:30:20,660
+درجة82 درجة هذا زيادة من وين نجوله الـ 82 درجة من
+
+295
+00:30:20,660 --> 00:30:26,940
+الهيدروجين البونديني الان الميثانول 65 جداش زاد
+
+296
+00:30:26,940 --> 00:30:34,560
+الميثانول عن الميثين احسبوا 88 و 65 حوالي 140 درجة
+
+297
+00:30:34,560 --> 00:30:39,320
+من وين نجول 140 درجة من الهيدروجين البونديني طبعا
+
+298
+00:30:39,320 --> 00:30:43,160
+ممكن واحدة تيجي تتساءل ما هو مش كل هيدروجين
+
+299
+00:30:43,160 --> 00:30:49,270
+بوندينيزي بعضه، يعني مع ال مثل أمين زادت ال
+
+300
+00:30:49,270 --> 00:30:53,230
+boiling point، لكن كده زادت؟ تمانين درجة، مع
+
+301
+00:30:53,230 --> 00:30:56,970
+الميثانول زادت ال boiling point، كده زادت؟ مية و
+
+302
+00:30:56,970 --> 00:31:00,690
+أربعين درجة، اه ما احنا بنعرف أن ال oxygen
+
+303
+00:31:00,690 --> 00:31:07,780
+السليلية تبعته أعلى من ال nitrogenواضح؟ ولذلك الـ
+
+304
+00:31:07,780 --> 00:31:11,140
+hydrogen bonding اللي موجود في حالات ال oxygen
+
+305
+00:31:11,140 --> 00:31:14,980
+أكتر من اللي في ال nitrogen فارتفاع رخطة الغليان
+
+306
+00:31:14,980 --> 00:31:18,900
+لمركب في oxygen بيكون أكتر من اللي مركب في
+
+307
+00:31:18,900 --> 00:31:23,320
+nitrogen في كل الأحوال .. في كل الأحوال المركبين
+
+308
+00:31:23,320 --> 00:31:25,780
+أشمالهم مرتفعين
+
+309
+00:31:27,590 --> 00:31:33,390
+عشان اقولك انه في عندك ناقص 88 للإيثين وقاعدة
+
+310
+00:31:33,390 --> 00:31:38,970
+بتزيد الحرارة لما صارت مثل الامين ناقص 6 ولا ..
+
+311
+00:31:38,970 --> 00:31:47,650
+ناقص 6 ارتفاع 80 درجة لما قولت ميثانون زائد 65 هذا
+
+312
+00:31:47,650 --> 00:31:51,510
+ارتفاع و هذا ارتفاع لكن الارتفاع الناشئ عن
+
+313
+00:31:51,510 --> 00:31:52,470
+الأكسجين
+
+314
+00:31:55,140 --> 00:31:59,080
+النيتروجين انا مابتش انسى ان الـ electronegativity
+
+315
+00:31:59,080 --> 00:32:01,840
+للأكسجين تلاتة و نص ال electronegativity
+
+316
+00:32:01,840 --> 00:32:07,480
+للنيتروجين تلاتة فلأنه السليبية لأن الأكسجين أعلى
+
+317
+00:32:07,480 --> 00:32:09,520
+فال hydrogen bonding اللي فيه
+
+318
+00:32:13,840 --> 00:32:17,520
+الارتفاع ارتفاع وهيدروجين bonding هيدروجين bonding
+
+319
+00:32:17,520 --> 00:32:22,320
+واضح لكن لو جيت بتهاجأت أسألكوا تحديدًا ليش
+
+320
+00:32:22,320 --> 00:32:26,460
+الميثانول أعلى من الميث الأمين؟ هنال أكسجين؟ اه
+
+321
+00:32:26,460 --> 00:32:30,000
+مالكشنش يقولولي هيدروجين bonding أنا فيه هيدروجين
+
+322
+00:32:30,000 --> 00:32:33,920
+bonding وانا فيه هيدروجين bonding لأن السالبية
+
+323
+00:32:33,920 --> 00:32:38,000
+للأكسجين أعلى فالهيدروجين bonding تبعه أقل
+
+324
+00:32:47,850 --> 00:32:55,250
+المقارنة نفسها تماما بس تختلف القيامة، واضح؟ فال
+
+325
+00:32:55,250 --> 00:33:00,110
+alcohol بتكون أعلى من ال amines أعلى كتير كتير من
+
+326
+00:33:00,110 --> 00:33:09,370
+ال alkyls، والسبب الhydrogen bonyالان كيف بنحضر ال
+
+327
+00:33:09,370 --> 00:33:14,330
+amines؟ نسبة من هذه الطرق اللي هي طرق تحضير ال
+
+328
+00:33:14,330 --> 00:33:19,830
+amines مرت معنا على سبيل المثال المرة الماضية لما
+
+329
+00:33:19,830 --> 00:33:25,130
+درسنا ال amides أخدنا أن ال production of amides
+
+330
+00:33:25,130 --> 00:33:29,490
+produces amine، produces amine، ان هذا ال c double
+
+331
+00:33:29,490 --> 00:33:36,270
+point هو تشفت CHOإذا إحدى طرق تحضير الأمين
+
+332
+00:33:36,270 --> 00:33:41,230
+reduction of amides واضح؟ reduction of amides
+
+333
+00:33:41,230 --> 00:33:47,290
+produces amines طبعا الناس الشطرين ما بدهم يشيفوا
+
+334
+00:33:47,290 --> 00:33:52,010
+عند هذه النقطة بيقدروا يرجعوا لورا كام خطوة جد ما
+
+335
+00:33:52,010 --> 00:33:59,390
+بدهم بمعنى الأمد من وين جاي؟ من الاسد والاسد إيه
+
+336
+00:33:59,390 --> 00:34:00,650
+طرق تحضيره؟
+
+337
+00:34:02,750 --> 00:34:07,250
+كان في عنده طرق تساوي و طرق زيادة و .. كل هذا
+
+338
+00:34:07,250 --> 00:34:12,890
+الكلام بدي أنتبهله يعني لو أنا طلبت بيكم amines من
+
+339
+00:34:12,890 --> 00:34:20,710
+ال amide فهذا هو السؤال السهل، الآن ممكن أرجعه بال
+
+340
+00:34:20,710 --> 00:34:28,330
+amine من ال acid؟ طب ال acid من إيش؟ مثلا من
+
+341
+00:34:28,330 --> 00:34:35,080
+الكحول، طريقة التساويأو الـ Dehydrate بطريقة
+
+342
+00:34:35,080 --> 00:34:40,600
+التساوي أو RX و بزيد عليها CO2 ولا بزيد عليها
+
+343
+00:34:40,600 --> 00:34:48,320
+Greenium CN أو من الكيل والكيل بحط عليه بعد هيك
+
+344
+00:34:48,320 --> 00:34:52,660
+Alcohol أو بحط عليه بيئة بمعنى كل الكيميا اللي قبل
+
+345
+00:34:52,660 --> 00:34:57,450
+اللي أعطينا عليها أمثلة كيف تحضروا ال acidبتصير
+
+346
+00:34:57,450 --> 00:35:02,530
+بعد هيك تلقاء الأسد بيصير أمد و الأمد بيصير أمين
+
+347
+00:35:02,530 --> 00:35:07,670
+فمش ضروري أنه هنا بتصير اللي هو الناس الشطريين
+
+348
+00:35:07,670 --> 00:35:11,270
+اللي بدوا يقعدوا بينهم بين نفسهم يفكروا لمدة نص
+
+349
+00:35:11,270 --> 00:35:15,350
+ساعة ساعة يتخيلوا كيف ممكن ينسقلوا في هذه المنطقة
+
+350
+00:35:15,350 --> 00:35:21,270
+مش بس يقولوا أنه والله الأمين من الأمد، كويس، و
+
+351
+00:35:21,270 --> 00:35:27,880
+الأمد من الأسد، و الأسدراجعوا الخمس طرق تبعونه
+
+352
+00:35:27,880 --> 00:35:32,840
+الان كل نقطة بداية بيحطل الإنسان يقولكم كيف منها
+
+353
+00:35:32,840 --> 00:35:39,440
+بتحضروا amines إذا الطالب ماعملش هالكلام لوحده
+
+354
+00:35:39,440 --> 00:35:45,660
+باستمتاع واجع ما نبدأ به لل acid و بعدين ال acid و
+
+355
+00:35:45,660 --> 00:35:49,940
+بعدين ال amide و بعدين ال amine مش هيتعلم واضحة
+
+356
+00:35:49,940 --> 00:35:55,760
+الفكرة؟ الان بيجينا ال aromatic amineاللي هو
+
+357
+00:35:55,760 --> 00:36:00,440
+الأليلين الآن لاحظوا من الأخطاء الشائعة دايما لما
+
+358
+00:36:00,440 --> 00:36:05,240
+نقول حضرونا الأليلين أنه أي حد فيكم بالذات إذا كنا
+
+359
+00:36:05,240 --> 00:36:10,640
+الأليلين من البنزين how can you prepare أليلين
+
+360
+00:36:10,640 --> 00:36:18,080
+starting from بنزين أكبر غلطة ممكن تعملوا عندكوا
+
+361
+00:36:18,080 --> 00:36:21,020
+تقولوا زي هيك و تيشوا تكتبوا لأنهاتين three
+
+362
+00:36:24,650 --> 00:36:30,170
+طبعا ليش هذه أكبر غلطة في الدنيا لأنه احنا اتفقنا
+
+363
+00:36:30,170 --> 00:36:36,770
+ان البنزين عبارة عن سحابة إلكترونية سالب السالب لا
+
+364
+00:36:36,770 --> 00:36:43,130
+يستطيع ان يهاجم عليه سالب ولذلك لا يمكن ان نيجي
+
+365
+00:36:43,130 --> 00:36:47,430
+نقول بدنا نجيب الأمونيا السالبة على البنزين السالب
+
+366
+00:36:47,430 --> 00:36:48,610
+ونحضر هذا الكلام
+
+367
+00:36:52,670 --> 00:36:56,730
+بنقول حضرولنا الانيلين من البنزين ماحدش يقول بنزين
+
+368
+00:36:56,730 --> 00:37:01,630
+زايد أمونيا أنيلين إيش من يجلبوا الأمونيا هنا إما
+
+369
+00:37:01,630 --> 00:37:05,450
+إذا كنتوا أقطام المغناطيس اللي زي بعض الشمالي
+
+370
+00:37:05,450 --> 00:37:09,650
+والشمالي بتاعون ألعاب الأطفال جربوهم مع بعض كيف
+
+371
+00:37:09,650 --> 00:37:15,530
+بيكونوا جاعدين نفس الشي هذا سهل وسهلعمرهم هيقدروا
+
+372
+00:37:15,530 --> 00:37:19,850
+يجربوا على بعض؟ لأ، إذا هذه الطريقة غير سليمة
+
+373
+00:37:19,850 --> 00:37:24,950
+إطلاقا لإنه محضر من خلالها الأدلين طب ها إيش
+
+374
+00:37:24,950 --> 00:37:29,310
+الطريقة السليمة؟ الطريقة السليمة إنه إحنا محضر
+
+375
+00:37:29,310 --> 00:37:34,230
+الـNitro Benzene هذا من الـHNO3 و الـH2SO4
+
+376
+00:37:34,230 --> 00:37:40,210
+اتعلمناه بعدين الـNitro Benzene الـNitro Benzene
+
+377
+00:37:40,210 --> 00:37:46,490
+بال reductionبنضيف عليها هيدروجين reduction
+
+378
+00:37:46,490 --> 00:37:52,470
+بالهيدروجين هيدروجينونيكل مثلا بتحول إلى إيش؟
+
+379
+00:37:52,470 --> 00:37:59,090
+الانيلين إذا الانيلين من البنزين يمر تأكيدا عبر
+
+380
+00:37:59,090 --> 00:38:04,390
+النيترو بنزين لما نقول بدنا انيلين من البنزين
+
+381
+00:38:04,390 --> 00:38:12,070
+بتكون قولولي المسار بنزين نيترو بنزين انيلين
+
+382
+00:38:14,070 --> 00:38:20,930
+وقع الفكرة هذا هو المسار بنزين نايترو بنزين قليل
+
+383
+00:38:20,930 --> 00:38:29,950
+الآن لبس ان انا اضيفلكم هنا كمان معلومة كتير مهمة
+
+384
+00:38:29,950 --> 00:38:32,990
+مر
+
+385
+00:38:32,990 --> 00:38:40,250
+علينا طبعا هنا قلنا HRO3H2O4 مر علينا الفيلول
+
+386
+00:38:41,480 --> 00:38:46,700
+بتعرفوا ال phenol؟ اه لو اتينا و قولنالكم how can
+
+387
+00:38:46,700 --> 00:38:52,560
+you prepare phenol يعني
+
+388
+00:38:52,560 --> 00:39:00,160
+هنا OH starting from بنزين كيف
+
+389
+00:39:00,160 --> 00:39:05,780
+تحضر ال phenol من البنزين؟ الآن أكبر غلط ممكن
+
+390
+00:39:05,780 --> 00:39:08,820
+الواحد يعمله إيش؟ يقول بنزين
+
+391
+00:39:17,390 --> 00:39:24,350
+- أزواج إلكترونال ليش؟ لأن هذا السالب لا يهاجم على
+
+392
+00:39:24,350 --> 00:39:30,770
+هذا السالب إذن مش ممكن أقول البنزين .. مش ممكن
+
+393
+00:39:30,770 --> 00:39:34,290
+أقول البنزين فعله مع الـ OH بيعطينا فينول أول ما
+
+39
+
+445
+00:44:34,330 --> 00:44:40,790
+هلاي بعمل إبداع وهذا حلنا عليه مسائل كتير في الفصل
+
+446
+00:44:40,790 --> 00:44:47,330
+هذه أيضًا طريقة و عليها مثالين توضحيين
+
+447
+00:44:47,330 --> 00:44:52,970
+عندكم، اللي هي طريقة إبدال على ال الكلهيلات، طريقة
+
+448
+00:44:52,970 --> 00:44:57,510
+الإبدال على ال الكلهيلات، يعني لاحظوا هذا ال
+
+449
+00:44:57,510 --> 00:45:03,850
+الكلهيلات وينه؟ المثل أيضاري، بجيب بداله الأمين،
+
+450
+00:45:03,850 --> 00:45:05,850
+هذه الأمين، اتجه الآن
+
+451
+00:45:09,910 --> 00:45:15,350
+لأ هو بهذا المثال هاي ال kilohydride هاي ال PR إيش
+
+452
+00:45:15,350 --> 00:45:18,790
+في عنده هنا ال unatomobiles ال unatomobiles خلّى
+
+453
+00:45:18,790 --> 00:45:25,250
+الآن نتاجر تجربة ال PR و إذا بتعمل إيش حلقات صار
+
+454
+00:45:25,250 --> 00:45:30,470
+عندي مركب النكوتين هذا المركب النكوتين كيف نحطه
+
+455
+00:45:30,470 --> 00:45:35,190
+نكوتين السجاني في كل الأحوال ال unat
+
+456
+00:45:39,910 --> 00:45:43,910
+الـ PR أو الـ CL ابتفعوا الإدالة، فطرق تحضير
+
+457
+00:45:43,910 --> 00:45:49,370
+الأمين استلخيصا من الـ Amides، من الـ CL، من
+
+458
+00:45:49,370 --> 00:45:52,690
+الإدالة محل الـ Halogens، والـ Aromatic أمين
+
+459
+00:45:52,690 --> 00:45:58,190
+باختزال الـ Nitrobenzene، واضحة الفكرة؟ إن شاء
+
+460
+00:45:58,190 --> 00:45:58,290
+الله
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4b8131f65ab6d70a139d0eb9aeb6fd4046050680
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_postprocess.srt
@@ -0,0 +1,1840 @@
+1
+00:00:24,690 --> 00:00:29,550
+الحدي عشر في جزء الكيميا الرجوية العادى قبل ما
+
+2
+00:00:29,550 --> 00:00:35,290
+ننتقل لمقدمة البيت الاسطي اللى هو بعنوان amines
+
+3
+00:00:35,290 --> 00:00:43,010
+amines يعني مركبات ال nitrogen المركبات اللى فيها
+
+4
+00:00:43,010 --> 00:00:49,250
+ال nitrogen طبعا كلنا عارفين ان ال amine او ال
+
+5
+00:00:49,250 --> 00:00:49,810
+nitrogen
+
+6
+00:01:07,020 --> 00:01:13,380
+الان هذول ال ثلاث روابط في أبسط المركبات على
+
+7
+00:01:13,380 --> 00:01:18,940
+الإطلاق تبع ال نيتروجيز لما بيكونوا إيش هيدروجيز
+
+8
+00:01:18,940 --> 00:01:26,200
+بيكون عنده جزء الأمونيا يعني أبسط مركب للنيتروجيز
+
+9
+00:01:26,200 --> 00:01:30,640
+هو جزء الأمونيا الآن الأمونيا ممكن ما نعتبرهاش
+
+10
+00:01:30,640 --> 00:01:31,220
+مركبة
+
+11
+00:01:45,690 --> 00:01:47,650
+إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا
+
+12
+00:01:47,650 --> 00:01:48,170
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+13
+00:01:48,170 --> 00:01:48,250
+إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا
+
+14
+00:01:48,250 --> 00:01:49,730
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+15
+00:01:49,730 --> 00:01:51,150
+إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا
+
+16
+00:01:51,150 --> 00:01:51,170
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+17
+00:01:51,170 --> 00:01:51,390
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+18
+00:01:51,390 --> 00:02:01,170
+إبدال إذا بدنا نعمل إبدال إبدال إذا
+
+19
+00:02:01,170 --> 00:02:03,150
+بدنا نعمل إ
+
+20
+00:02:16,910 --> 00:02:20,930
+هذا بنسميه primary amine يعني نيتوجن متصل فيه بكام
+
+21
+00:02:20,930 --> 00:02:26,630
+carbon واحدة الآن لو بدّرنا التانية صار انتزلتين R
+
+22
+00:02:26,630 --> 00:02:33,370
+صار secondary amine لو بدّرنا التالتة صار tertiary
+
+23
+00:02:33,370 --> 00:02:37,310
+amine فال amines المشهورة ال primary و ال
+
+24
+00:02:37,310 --> 00:02:42,370
+secondary و ال tertiary الآن هل يا ترى ممكن نعمل
+
+25
+00:02:42,370 --> 00:02:49,030
+كمان R رابعة؟في مرات معينة لو جيبنا R موجبة فعنا
+
+26
+00:02:49,030 --> 00:02:53,970
+مع هذا زوج الإلكترونات بيعمل رابط بهذا الشكل
+
+27
+00:02:53,970 --> 00:02:58,650
+وبيعمل الـR الرابعة لكن في هذه الحالة لو حسبنا
+
+28
+00:02:58,650 --> 00:03:04,910
+الـformal charge عن الـNitrogen بتصير موجبة واضح؟
+
+29
+00:03:04,910 --> 00:03:11,290
+فبصير عنده صوت يعني طالما فيه موجب إذا في مرافق له
+
+30
+00:03:13,270 --> 00:03:18,630
+واضح طالما فيه موجب إذا فيه إله مرافق سارق تماما
+
+31
+00:03:18,630 --> 00:03:22,270
+زي لما كنتوا تاخدوا المركب المشهور مثلا ال
+
+32
+00:03:22,270 --> 00:03:26,430
+ammonium chloride كنتوا توصلوا على ال nitrogen
+
+33
+00:03:26,430 --> 00:03:34,990
+أربع روابط تحطوا على ال nitrogen اتش تدين تلاتة
+
+34
+00:03:34,990 --> 00:03:39,690
+أربعة رحزوج الإلكترونات و واحد منها دولة الارش هذا
+
+35
+00:03:39,690 --> 00:03:40,330
+الشكل ال
+
+36
+00:03:44,910 --> 00:03:52,370
+الأيون الموجة دائما بنتهيأ باسم ايش ات الايون
+
+37
+00:03:52,370 --> 00:03:57,030
+السالب كربونيت نيتريت سولفيت هذه الايونات السالبة
+
+38
+00:03:57,030 --> 00:04:02,470
+الايونات الموجة بنهيتها اونيوم امونيوم هيدرونيوم
+
+39
+00:04:02,470 --> 00:04:07,730
+اكزونيوم فوسفونيوم وضع ولذلك هذا ايش كان يتسمى
+
+40
+00:04:07,730 --> 00:04:08,470
+المركب
+
+41
+00:04:18,250 --> 00:04:23,590
+هذه النهاية onium نستعملها لأيون الموجة عشان ايه
+
+42
+00:04:23,590 --> 00:04:26,970
+لو بنيجي نسألكم the ending onium is used for
+
+43
+00:04:26,970 --> 00:04:31,210
+negative ions it's for the positive ions واضح
+
+44
+00:04:31,210 --> 00:04:36,670
+onium امونيوم اوزونيوم وهكذا الان هذا لما يكون
+
+45
+00:04:36,670 --> 00:04:40,350
+عليه مجموعات R بيقول فهذه الحالة
+
+46
+00:04:46,500 --> 00:04:50,560
+يعني عليها كام رابطة؟ أربع فبصير عندك ال
+
+47
+00:04:50,560 --> 00:04:54,200
+quaternary ammonium salts اللي هي R for N positive
+
+48
+00:04:54,200 --> 00:04:57,780
+أكيد طالما عندكوا N positive لازم يكون فيه معها
+
+49
+00:04:57,780 --> 00:05:04,580
+إيش؟ X سالبة واضح أكيد هيكون معها X سالبة وهذه
+
+50
+00:05:04,580 --> 00:05:08,560
+موجودة كثير الآن التشكيل العالمي ال nitrogen
+
+51
+00:05:08,560 --> 00:05:14,080
+compounds they are very importantin chemistry and
+
+52
+00:05:14,080 --> 00:05:19,060
+in biology يعني ال amino acids أساسي فيهم ال
+
+53
+00:05:19,060 --> 00:05:24,680
+nitrogen ال DNA ال RNA فيهم ال basis واضح ال
+
+54
+00:05:24,680 --> 00:05:29,920
+nitrogen basis اسمها ال alkaloids اللي هي المركبات
+
+55
+00:05:29,920 --> 00:05:32,300
+ال natural product اللي بتكون عادة
+
+56
+00:05:38,200 --> 00:05:44,760
+النيتروجين هو السبب ال basicity و لذلك بنسميها ال
+
+57
+00:05:44,760 --> 00:05:49,460
+caloids، ال caloids جاي من القالي، القالي يعني
+
+58
+00:05:49,460 --> 00:05:49,980
+قلوي
+
+59
+00:05:53,060 --> 00:05:59,080
+الان طبعا بالنسبة لخلاص ال amines كنا بنتذكر ان ال
+
+60
+00:05:59,080 --> 00:06:02,200
+nitrogen من أعلى السليبيات يعني ال hydrogen
+
+61
+00:06:02,200 --> 00:06:07,540
+bonding أساسا لما بنعرفه احنا بنربطه بتلت ذرات
+
+62
+00:06:07,540 --> 00:06:13,580
+أساسية إذا اتصلت ال hydrogen مع ال fluorine أو ال
+
+63
+00:06:13,580 --> 00:06:19,280
+oxygen أو ال nitrogen فهو أحد التلاتة اللي بيعملوا
+
+64
+00:06:19,280 --> 00:06:22,750
+hydrogen bondingواضح؟ ليش؟ لأن الـ
+
+65
+00:06:22,750 --> 00:06:26,650
+electronegativity للنيتروجين عالية حوالي تلاتة
+
+66
+00:06:26,650 --> 00:06:30,570
+فالـ unatched bond is very polar تعمل hydrogen
+
+67
+00:06:30,570 --> 00:06:33,710
+bonding is possible طالما في عندي hydrogen
+
+68
+00:06:33,710 --> 00:06:37,130
+bonding، إذا ال boiling points للأمين يفترض أن
+
+69
+00:06:37,130 --> 00:06:41,710
+تكون إيش؟ مرتفعة وزي ما قلنا طالما في عندي أزواج
+
+70
+00:06:41,710 --> 00:06:46,710
+إلكترونية على النيتروجين، إذا الـ nitrogen's are
+
+71
+00:06:46,710 --> 00:06:55,660
+basesالـ A كيف بنسمي ال Amines؟ ال Amines تسميتها
+
+72
+00:06:55,660 --> 00:07:01,720
+في ال IUPAC system سهلة مابنعطيهاش اسم عائلة
+
+73
+00:07:01,720 --> 00:07:07,680
+بنعتبرها substitute فبصير
+
+74
+00:07:07,680 --> 00:07:13,220
+أصل الاسم للألكين يعني زي ما الألكين على سبيل
+
+75
+00:07:13,220 --> 00:07:19,370
+المثال بنرسمه سلسلة من ستة، شو بنسميها؟هكسين لو
+
+76
+00:07:19,370 --> 00:07:23,370
+عليها على موقع اتنين كلور شو بيصير المقارنة two
+
+77
+00:07:23,370 --> 00:07:27,310
+chloro hexane الان لو عليها على موقع اتنين NH2
+
+78
+00:07:27,310 --> 00:07:34,830
+بنسميها two amino hexane فاحنا بنسمي المركبات ال
+
+79
+00:07:34,830 --> 00:07:40,250
+amines كأنها ال cans و بنستعمل ايش NH2
+
+80
+00:07:41,530 --> 00:07:47,430
+بنسميها إيش؟ قمائم الان يمكن هنا .. يمكن هنا البعض
+
+81
+00:07:47,430 --> 00:07:52,870
+يقول طب لو كانت مش هنقدش توقف، يعني هاي عندى ..
+
+82
+00:07:52,870 --> 00:07:58,310
+نفترض سلسلة بهذا الشكل، جدري نشوفها كام carbon؟
+
+83
+00:07:58,310 --> 00:08:01,970
+واحد، اتنين، تلاتة، اربعة، خمسة، ستة، ستة، ستة
+
+84
+00:08:01,970 --> 00:08:07,630
+الان لو افترضنا أن عندكم على هذا الموقع برومماذا
+
+85
+00:08:07,630 --> 00:08:12,850
+سنذكره إبراهيم إبراهيم طيب لو افترضنا الآن إنه على
+
+86
+00:08:12,850 --> 00:08:22,190
+هذا الموقع إجا عنده ال H2 امينو إيش هسميه امينو
+
+87
+00:08:22,190 --> 00:08:26,490
+امينو و بعدين هسمي الاسم طيب لو افترضت إنه اللي
+
+88
+00:08:26,490 --> 00:08:32,350
+إجت عنده مش NH2 NHCH3
+
+89
+00:08:39,710 --> 00:08:43,470
+هذا الشبكة بهذا الشكل من خلال الـ Nitrogen هذي إيش
+
+90
+00:08:43,470 --> 00:08:50,890
+اسمها؟ Amino طب لو كان الشبكة مجموعة NHCH3 ميثل
+
+91
+00:08:50,890 --> 00:08:59,150
+امايو طب لو الشبكة ن تنتل CH3 داي ميثل امايو،
+
+92
+00:08:59,150 --> 00:09:06,710
+واضح؟ إذن هذه المجموعة الـNH2 اسمها امايو الـNH
+
+93
+00:09:06,710 --> 00:09:07,570
+لحملة ميثل امايو
+
+94
+00:09:13,190 --> 00:09:20,990
+والألهج اللي حملة الدين مثل دايمثل
+
+95
+00:09:20,990 --> 00:09:32,110
+امايو و لذلك لو احنا بنانيجي نتطلع تكون عندنا مركب
+
+96
+00:09:43,560 --> 00:09:50,920
+تلاتة برومود اتنين تلاتة اربعة خمسة ستة تلاتة
+
+97
+00:09:50,920 --> 00:09:56,160
+برومود اتنين تلاتة اربعة خمسة ستة تلاتة برومود
+
+98
+00:09:56,160 --> 00:10:01,680
+اتنين تلاتة اربعة خمسة ستة اتنين تلاتة برومود
+
+99
+00:10:01,680 --> 00:10:02,240
+اتنين تلاتة برومود اتنين تلاتة برومود اتنين تلاتة
+
+100
+00:10:02,240 --> 00:10:02,460
+برومود اتنين تلاتة برومود اتنين تلاتة برومود اتنين
+
+101
+00:10:02,460 --> 00:10:02,680
+اتنين تلاتة برومود اتنين تلاتة برومود اتنين تلاتة
+
+102
+00:10:02,680 --> 00:10:03,440
+برومود ات
+
+103
+00:10:09,470 --> 00:10:13,950
+واضحين to dimethylaminohexane
+
+104
+00:10:58,850 --> 00:11:05,550
+الان بدنا نبحث عن أطول سلسلة ألفاتية أطول سلسلة
+
+105
+00:11:05,550 --> 00:11:08,750
+ألفاتية من 1،2،3،4
+
+106
+00:11:13,720 --> 00:11:19,620
+طبعا واحد اتنين تلاتة اربعة خمسة ستة بناء على ذلك
+
+107
+00:11:19,620 --> 00:11:25,680
+المركب اللي عندنا شو اسمه اكسين اكسين اكسين اكسين
+
+108
+00:11:25,680 --> 00:11:31,980
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+109
+00:11:31,980 --> 00:11:36,300
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+110
+00:11:36,300 --> 00:11:41,440
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+111
+00:11:41,440 --> 00:11:43,640
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+112
+00:11:47,630 --> 00:11:54,130
+الكلام في موازاة ولا لأ اثل مع ال oxygen اثل مع ال
+
+113
+00:11:54,130 --> 00:11:59,830
+nitrogen اثل امينو الآن لما بنشوفه من بين اليوتيوب
+
+114
+00:11:59,830 --> 00:12:11,510
+أولا تلاتة اثل امينو هذه مجموعة اتنين اثوكسي
+
+115
+00:12:11,510 --> 00:12:18,910
+علمناها اكسير واضح؟يعني مش بس الأمور بتقف عند مثل
+
+116
+00:12:18,910 --> 00:12:23,370
+أمينو ضاي مثل أمينو ممكن يكون عندكم إثل أمينو ضاي
+
+117
+00:12:23,370 --> 00:12:28,670
+إثل أمينو بروبل أمينو مثلا ضاي بروبل أمينو وممكن
+
+118
+00:12:28,670 --> 00:12:31,870
+كمان اللي يكونوا على الأمينو يكونوا مجمعتين
+
+119
+00:12:31,870 --> 00:12:36,310
+مختلفتين بأذكر التنتين بأسمعهم يعني لو أقول إثل و
+
+120
+00:12:36,310 --> 00:12:41,210
+مثل شو هسمي المجموعة إثل مثل أمينو
+
+121
+00:12:43,590 --> 00:12:47,870
+يعني اللي اتعلم organic كويس خلاص بصير تحل المشاكل
+
+122
+00:12:47,870 --> 00:12:52,050
+اللي بتواجهه لوحده طب لو ذكرنا ال ethoxy قبل ال
+
+123
+00:12:52,050 --> 00:12:58,710
+ethyl اشتغل alphabetical لما حرف الأول مايمشيش
+
+124
+00:12:58,710 --> 00:13:02,710
+معاك امشي على اللي بعده واضح؟ إذا لاجيت أن ال
+
+125
+00:13:02,710 --> 00:13:08,230
+ethoxy سابق في ال alphabetical سبجيها واضح؟ يعني
+
+126
+00:13:08,230 --> 00:13:11,790
+ارجعوا للي كتبنا مين سابق ethyl ولا ethoxy
+
+127
+00:13:18,030 --> 00:13:24,370
+اللي بيشتغل براحته يرتب الأمور Alpha Beta, إيش ما
+
+128
+00:13:24,370 --> 00:13:27,630
+بتكون المجموعات، بمشي حرف حرفة، واضحة فيك
+
+129
+00:13:34,790 --> 00:13:39,210
+طبعا لاحظوا هنا مثلا إيجا مع كثول، ضال الأساس
+
+130
+00:13:39,210 --> 00:13:42,650
+الكثول، يعني واحد، اتنين، تلاتة، أربعة، هذا
+
+131
+00:13:42,650 --> 00:13:45,650
+بيوتالول، وانت بيوتالول، على نبرة اتنين، ابروم،
+
+132
+00:13:45,650 --> 00:13:51,190
+مثلا على نبرة أربعة، أمين، واضح الفكرة؟ لو كان مع
+
+133
+00:13:51,190 --> 00:13:54,270
+الديهيد أو كيتون، نفس الأشياء، لو مع carboxylic
+
+134
+00:13:54,270 --> 00:14:00,110
+acid، نفس الأشياء، ومن هنا هتبدأ تلاقوا مثلا ال
+
+135
+00:14:00,110 --> 00:14:02,190
+amino acids
+
+136
+00:14:03,900 --> 00:14:08,120
+لما ندرس البروتينات، البروتينات من إيش بشكل أساسي
+
+137
+00:14:08,120 --> 00:14:14,100
+متكونة؟ من ال amino acids فلما نيجي نسمي، لما نيجي
+
+138
+00:14:14,100 --> 00:14:19,920
+نسمي، حق نعتبر أنه إحنا في عندنا ال acid زي هيك
+
+139
+00:14:19,920 --> 00:14:28,140
+مثلا، سي ده بيكون OH لو بيجينا هنا CH وحطينا هنا
+
+140
+00:14:28,140 --> 00:14:31,960
+NH2 CH2
+
+141
+00:14:53,340 --> 00:14:57,800
+الان في البيو كيميستر اذا بدنا نعطي اسم glycine
+
+142
+00:14:57,800 --> 00:15:00,340
+بيصير اسم شهرة تاني
+
+143
+00:15:06,760 --> 00:15:12,160
+هذه بدأت تسمى a mind أو أسمي للكيتون أو للالدهاي
+
+144
+00:15:12,160 --> 00:15:13,880
+أو للالكوبول
+
+145
+00:15:29,090 --> 00:15:33,330
+واضح؟ هاي أمثلة إضافية، هاي أطول سلسلة تلاتة
+
+146
+00:15:33,330 --> 00:15:38,630
+بروبين، على نجرة واحد أماين، one a minor بروبين،
+
+147
+00:15:38,630 --> 00:15:45,200
+هذا بروبينto aminopropane واضح؟ الان لاحظوا معاك
+
+148
+00:15:45,200 --> 00:15:49,420
+طب لو كنا بيجينا ال common nomenclature ال common
+
+149
+00:15:49,420 --> 00:15:53,880
+nomenclature وعطيناها قاعدة عامة كلنا بنذكر اسم
+
+150
+00:15:53,880 --> 00:15:58,760
+المجموعة و بعدها عائلة يعني لو كان أنا كله كنا
+
+151
+00:15:58,760 --> 00:16:02,500
+نسميه propane، نسميه chloride لو بروم، نسميه
+
+152
+00:16:02,500 --> 00:16:06,080
+propane، نسميه bromide لو و أش، نسميه propane،
+
+153
+00:16:06,080 --> 00:16:06,560
+نسميه alcohol
+
+154
+00:16:09,400 --> 00:16:18,860
+هذا البروبل هو اسم المجموعة و بعدين امين هذا
+
+155
+00:16:18,860 --> 00:16:24,500
+البروبل هو ايزو بروبل
+
+156
+00:16:33,510 --> 00:16:37,930
+و هكذا واضح طبعا هذه ال common nouns هتكون في
+
+157
+00:16:37,930 --> 00:16:43,490
+المركبات اللي هي المجموعات اللي اتعلمناها مثل اثر
+
+158
+00:16:43,490 --> 00:16:47,310
+بربل ايزو بربل ايزو بيوتل تيرتشير بيوتل المجموعات
+
+159
+00:16:47,310 --> 00:16:50,510
+اللي اتعلمناها في أشياء مااخدنا لاش اس المجموعات
+
+160
+00:16:50,510 --> 00:16:54,310
+مش هتاخد ال common nomenclature هذا مثلا ستة على
+
+161
+00:16:54,310 --> 00:16:59,190
+بوضع اتنين امين اتنين امين او اكسين مش هتلاقي انه
+
+162
+00:16:59,190 --> 00:17:05,670
+اخدنا اس المجموعةواضح؟ طبعا فى ناس ممكن يقولوا عنه
+
+163
+00:17:05,670 --> 00:17:09,930
+two hex الأمين لإنه سهل شوية لكن بعد هيك لو هانصر
+
+164
+00:17:09,930 --> 00:17:15,010
+شغلة و شغلة خلاص بتسموه إيش؟ أيوبة بتسموه أيوبة
+
+165
+00:17:15,010 --> 00:17:19,450
+تمام واضحة فكرة ال أيوبة ال nomenclature و ال
+
+166
+00:17:19,450 --> 00:17:21,890
+common nomenclature ال common nomenclature أيضا
+
+167
+00:17:21,890 --> 00:17:28,090
+إلها trait العائلة المجموعة تسمى إيش؟ العائلة
+
+168
+00:17:28,090 --> 00:17:29,530
+واضح؟
+
+169
+00:17:31,820 --> 00:17:36,060
+هذا المُركّب لو بجنب عليه وأطول سلسلة فيه
+
+170
+00:17:39,800 --> 00:17:44,360
+إذا هذا problem على مين راح واحد حامل كل هذه
+
+171
+00:17:44,360 --> 00:17:48,640
+المجموعة؟ مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+172
+00:17:48,640 --> 00:17:49,660
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+173
+00:17:49,660 --> 00:17:51,140
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+174
+00:17:51,140 --> 00:17:54,640
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+175
+00:17:54,640 --> 00:17:57,260
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+176
+00:17:57,260 --> 00:17:57,600
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+177
+00:17:57,600 --> 00:18:04,580
+مثل مثل مثل مثل مثل مثل مثل
+
+178
+00:18:05,720 --> 00:18:11,160
+هك بيصير أسهل لكم one methyl aminopropane لكن لو
+
+179
+00:18:11,160 --> 00:18:15,180
+شفتواها مكتوبة بطريقة تانية مثل هذه الطريقة ال مثل
+
+180
+00:18:15,180 --> 00:18:20,580
+معناها أن المثل متصلة بإيش بالنيتروجين و كأنه هذا
+
+181
+00:18:20,580 --> 00:18:23,340
+one aminopropane
+
+182
+00:18:33,770 --> 00:18:36,790
+Dimethyl Amino Cyclohexane
+
+183
+00:19:11,700 --> 00:19:20,220
+الان CH2 CH3 الان عند سلسلة اتل و سلسلة اتل بتاخد
+
+184
+00:19:20,220 --> 00:19:24,120
+واحدة منهم خليني افترض ان هذا الاساس اللي بنيت
+
+185
+00:19:24,120 --> 00:19:30,260
+الاسم عليه واحد اتنين هذا عبارة عن ايش عبارة عن
+
+186
+00:19:30,260 --> 00:19:37,000
+اتل لو بتاخدوا هذه السلسلة CH2 CH3 اذا تمركب ايش
+
+187
+00:19:37,520 --> 00:19:44,480
+Ethane هذا الـ Ethane على ممر واحد شو بيحمل؟
+
+188
+00:19:44,480 --> 00:19:49,300
+بس one substitute كل هذه عبارة عن one substitute
+
+189
+00:19:49,300 --> 00:19:56,700
+انا اصلا المركب Ethane CH3 CH3 شيلت H وحطيت كل هذا
+
+190
+00:19:56,700 --> 00:20:01,320
+الكلام الآن بيصير هذه المجموعة بدي اسميها هذا
+
+191
+00:20:01,320 --> 00:20:09,940
+Ethane مثل Amineإثل مثل أمينو عشان تسمها إثل مثل
+
+192
+00:20:09,940 --> 00:20:14,880
+أمينو أو ضعف من عنده أن إثل يعني أنه اتبعوا إن
+
+193
+00:20:14,880 --> 00:20:20,980
+الإثل برسمة وين عن أن أن مثل و أين موجود هذا كله
+
+194
+00:20:20,980 --> 00:20:25,500
+على دمر واحد ولا اتنين هو واحد طبعا لو ماحطش
+
+195
+00:20:25,500 --> 00:20:29,320
+الواحد لما تكون إثل مافيش مشكلة لأن مافيش فيها إلا
+
+196
+00:20:29,320 --> 00:20:35,440
+تكون واحد لكن لو كبرت لازم واضح واضحفزي هيك بتسمو
+
+197
+00:20:35,440 --> 00:20:40,840
+ايش بتكتبوه يكون صحيح لو كتبتوا one أساس طريقة
+
+198
+00:20:40,840 --> 00:20:48,700
+أيكم ايش بتكتبوه one مثل مثل أمينو أمينو هذي
+
+199
+00:20:48,700 --> 00:20:54,240
+المجموعة اللي بالأحمر one و أمينو سن المجموعة مثل
+
+200
+00:20:54,240 --> 00:20:56,140
+أمينو و كله عبارة عن
+
+201
+00:21:00,110 --> 00:21:05,370
+واضح حتى لو لغينا ال one هنا ابتفها بس بالخاص انه
+
+202
+00:21:05,370 --> 00:21:08,490
+حد يروح يحطلنا ال ethyl و ال methyl باماكن تانية
+
+203
+00:21:08,490 --> 00:21:13,110
+عشان نحاول ايش نوضحهم او مرات خوف لو واحد ييجي
+
+204
+00:21:13,110 --> 00:21:17,370
+يصير و يحط ethyl و methyl هنا بيضيفوا كلمة ايش أن
+
+205
+00:21:17,370 --> 00:21:22,390
+انه يعني تأكيدا في انه ماتغلطوش يعني ان ال ethyl
+
+206
+00:21:22,390 --> 00:21:24,430
+على ال nitrogen ال methyl على
+
+207
+00:21:31,700 --> 00:21:35,460
+لو اتينا هنا بروبين على نمرة واحد امينو على نمرة
+
+208
+00:21:35,460 --> 00:21:42,140
+اتنين امينو، شو هيكون؟ هذا المركب واحد اتنين تلاتة
+
+209
+00:21:42,140 --> 00:21:47,100
+اربعة two-butanol على نمرة تلاتة امينو على نمرة
+
+210
+00:21:47,100 --> 00:21:51,920
+تلاتة مثل اي واحد اتنين تلاتة اربعة، ليش الترقيم
+
+211
+00:21:51,920 --> 00:21:58,930
+حببنا هنا؟ عشان القول تكون أفضل ما يمكن العائلةالـ
+
+212
+00:21:58,930 --> 00:22:02,370
+All بتكون أقل ما يمكن، هذا الـ Core، أساسه الـ
+
+213
+00:22:02,370 --> 00:22:06,250
+Core، واضح؟ فبدي أنا الـ OH تكون أقل ما يمكن، لو
+
+214
+00:22:06,250 --> 00:22:10,730
+ملقمت منها أنا الـ OH هتطلع على لبرة تلاتة، واضح؟
+
+215
+00:22:10,730 --> 00:22:14,770
+فهو عبارة عن الـ Good على لبرة تلاتة حامل أمينو
+
+216
+00:22:14,770 --> 00:22:16,410
+وعلى لبرة تلاتة حامل
+
+217
+00:22:25,780 --> 00:22:29,800
+طبعا زي ما حكينا بالنسبة ل ال common nomenclature
+
+218
+00:22:29,800 --> 00:22:35,480
+عادة بنذكر اسم المجموعة و بعدها بنحط ايش امين و
+
+219
+00:22:35,480 --> 00:22:44,420
+لذلك هذه CH3 and H2 مثل امين، هذي دايمثل امين،
+
+220
+00:22:44,420 --> 00:22:49,680
+الامين حملة كام مثل؟ تنتهي المجموعة دايمثل امين في
+
+221
+00:22:49,680 --> 00:22:52,400
+ممكن يكون ال try مثل امين
+
+222
+00:23:00,290 --> 00:23:02,170
+كله اسمه amine باسم مُركّب
+
+223
+00:23:02,170 --> 00:23:28,830
+نيتروجينكتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناترام
+
+224
+00:23:29,650 --> 00:23:35,910
+إنه هذه ethyl و ethyl و ethyl و ethyl و ethyl و
+
+225
+00:23:35,910 --> 00:23:41,010
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+226
+00:23:41,010 --> 00:23:43,710
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+227
+00:23:43,710 --> 00:23:44,510
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+228
+00:23:44,510 --> 00:23:45,090
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+229
+00:23:45,090 --> 00:23:45,670
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+230
+00:23:45,670 --> 00:23:51,290
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+231
+00:23:51,290 --> 00:23:54,950
+ethyl و ethyl و
+
+232
+00:23:59,000 --> 00:24:03,700
+بتذكرهم alphabetical اثل مثل امين الافضل
+
+233
+00:24:03,700 --> 00:24:11,320
+alphabetical يعني اثل مثل اثل مثل امين الخلاصة انه
+
+234
+00:24:11,320 --> 00:24:15,740
+التسمية بال common nomenclature التسمية بال common
+
+235
+00:24:15,740 --> 00:24:19,860
+nomenclature بنذكر فيها اسم المجموعة و بعدين بننهي
+
+236
+00:24:19,860 --> 00:24:26,770
+بالنهاية امين اللي هي العائلة واضح؟فزي ما بتلاحظوا
+
+237
+00:24:26,770 --> 00:24:30,890
+الأمينز أكتر من تسمية لهم أشهر نظام الـ Iopaque
+
+238
+00:24:30,890 --> 00:24:34,350
+أنه نعتبرهم ألكين وهي أمثلة إضافية حتى أنه
+
+239
+00:24:34,350 --> 00:24:39,310
+اترجعوها ال Iopaque بنذكرهم ألكينزي ال common
+
+240
+00:24:39,310 --> 00:24:46,450
+بنذكر المجموعة ثم العائلة الأهم في نظام تسمية تالت
+
+241
+00:24:46,450 --> 00:24:47,850
+حسب ال chemical abstract
+
+242
+00:25:06,820 --> 00:25:13,020
+بس لما بيسميه بيسميش طبعا مركب رباع بيوت الأمين لأ
+
+243
+00:25:13,020 --> 00:25:21,000
+بيسميه بيوتان أمينبعرفش إذا دي واضحة ولا بنزم أني
+
+244
+00:25:21,000 --> 00:25:27,160
+أوضحها أكتر لكم يعني خليني
+
+245
+00:25:27,160 --> 00:25:35,080
+أخد هذا المركب و أحط هنا OH عشان أنتوا تنتبهوا لما
+
+246
+00:25:35,080 --> 00:25:41,600
+أنا كنت أسمي هذا بيوتان
+
+247
+00:25:48,620 --> 00:25:56,180
+و أحطله one هذا ال IOPAC منه الان لما كنت أسميه
+
+248
+00:25:56,180 --> 00:26:04,600
+بال common nominative شو كنت أسميه؟ butyl و أحط
+
+249
+00:26:04,600 --> 00:26:12,820
+العائلة alcohol butyl alcohol okay butyl alcohol
+
+250
+00:26:12,820 --> 00:26:17,360
+الان الناس اللي بيعملوا على نظام تسمية تالف
+
+251
+00:26:21,690 --> 00:26:28,830
+عندي nh2، بدي أعطي العائلة أمين، يعني نغير هذه
+
+252
+00:26:28,830 --> 00:26:36,910
+نخليها nh2، فبصير بيوتان أمين، طب وهذا بيوت
+
+253
+00:26:36,910 --> 00:26:43,790
+الأمين، واضح تلاحظين أنه الفرق ما بينبيوتان و
+
+254
+00:26:43,790 --> 00:26:47,870
+بيوتين في كل الأحوال هذا النظام مابتيش يقتصر معالي
+
+255
+00:26:47,870 --> 00:26:51,730
+لكن مرات بنذكر أشياء اللي لو قرأتوها ماتحسوش
+
+256
+00:26:51,730 --> 00:26:54,790
+باستغراب احنا اللي بدنا نسمي عليه the iopac
+
+257
+00:26:54,790 --> 00:27:00,230
+nomenclature ان مراكبات ال amines بتتبع الalkenes
+
+258
+00:27:00,230 --> 00:27:04,490
+هي مشتقات للalkenes و لو كنا بتناقلكم ال common
+
+259
+00:27:04,490 --> 00:27:07,730
+nomenclatures تبعها فبنكتم المجموعة و بعدين ال
+
+260
+00:27:07,730 --> 00:27:14,400
+amine لكن لو قرأتوا اشي تانيما تستمر مش واضح؟
+
+261
+00:27:14,400 --> 00:27:19,940
+باختصار المركبات تبعت ال amines تتبع عائلة ال
+
+262
+00:27:19,940 --> 00:27:23,720
+alkanes يعني نهيتها إيفين بروبين بيوتين هكسل
+
+263
+00:27:23,720 --> 00:27:29,140
+whatever طبعا مركبات ال amines في الدنيا كتيرة
+
+264
+00:27:29,140 --> 00:27:33,700
+كلها مركبات في الكيميا الحلقية مش بطلب نحفظها بس
+
+265
+00:27:33,700 --> 00:27:38,100
+حتى تحسوا كدهش موضوع ال nitrogen موضوع واسع يعني
+
+266
+00:27:38,100 --> 00:27:43,010
+يمكن تقوله ربع الكيميا العضوية المركبات معاهواضح؟
+
+267
+00:27:43,010 --> 00:27:47,110
+البُركّب هذا الوحيد يمكن يعرفي أنه البنزينة اللي
+
+268
+00:27:47,110 --> 00:27:54,630
+عليها الأن H2O هي عبارة عن أنيليا الأن بالنسبة للـ
+
+269
+00:27:54,630 --> 00:27:59,010
+physical properties of amines بشكل عام احنا بيقول
+
+270
+00:27:59,010 --> 00:28:03,680
+أن ال physical properties ofhydrogen bonding
+
+271
+00:28:03,680 --> 00:28:10,440
+وبالتالي من ناحية من ناحية من ناحية مقارنة ال
+
+272
+00:28:10,440 --> 00:28:14,340
+boiling point تبعتهم يفترض انها ليش تكون عالية
+
+273
+00:28:14,340 --> 00:28:18,820
+مرتفعة طبعا اللي بده يعمل المقارنة ويفهمها جيدا
+
+274
+00:28:18,820 --> 00:28:24,120
+بده يقارن مع إشي مافيش فيه hydrogen bonding يعني
+
+275
+00:28:24,120 --> 00:28:26,640
+إشي فيه hydrogen bonding وإشي مافيه hydrogen
+
+276
+00:28:26,640 --> 00:28:29,200
+bonding وبده يوحد العوامل التانية
+
+277
+00:28:38,870 --> 00:28:42,670
+طب هذا ليش مرتفع كتير اكتر من هذا؟ بطل ال
+
+278
+00:28:42,670 --> 00:28:46,450
+molecular weight هو السبب و قداش بديكون السبب ال
+
+279
+00:28:46,450 --> 00:28:52,910
+hydrogen بدي ولذلك هلأ اعمللكم مثال كتير جميل أخد
+
+280
+00:28:52,910 --> 00:28:58,830
+من ال alkanes ال ethane و لاحظوا عندى ال ethane ال
+
+281
+00:28:58,830 --> 00:29:03,540
+molecular weight تبعه قداش تلاتينكامهم كامهم 12,
+
+282
+00:29:03,640 --> 00:29:09,400
+12, 24, 26 هيدروجين تلاتين و أخد الميث الأمين
+
+283
+00:29:09,400 --> 00:29:15,520
+الميث الأمين لو حسبنا ال molecular weight 31 هذا
+
+284
+00:29:15,520 --> 00:29:21,160
+أمين هذا الكلب و أخد الميثانول ال alcohol ال
+
+285
+00:29:21,160 --> 00:29:28,740
+molecular weight تبعه 32تجاوزا او تقريبا التلاتين
+
+286
+00:29:28,740 --> 00:29:31,640
+في ال molecular weight زي الواحد و التلاتين زي
+
+287
+00:29:31,640 --> 00:29:36,260
+الاتنين و التلاتين إذا هدولة التلات مراكبات equal
+
+288
+00:29:36,260 --> 00:29:39,040
+بالنسبالي .. اللي هم equal molecular weight فلو
+
+289
+00:29:39,040 --> 00:29:43,380
+اختلفوا بال boiling point هيكون اختلاف بسبب ال
+
+290
+00:29:43,380 --> 00:29:47,920
+molecular weight لأ لأ بنفتش على إشي تاني الآن لو
+
+291
+00:29:47,920 --> 00:29:53,480
+إجهنا اتطلعنا على قداش ال boiling point اللي هو
+
+292
+00:29:55,080 --> 00:30:04,760
+هنلاحظ ان الاثان ناقص 88 المثل أمين ناقص 6 جديش
+
+293
+00:30:04,760 --> 00:30:12,340
+زاد المثل أمين عن الاثان من ناقص 88 لناقص 6 82
+
+294
+00:30:12,340 --> 00:30:20,660
+درجة82 درجة هذا زيادة من وين نجوله الـ 82 درجة من
+
+295
+00:30:20,660 --> 00:30:26,940
+الهيدروجين البونديني الان الميثانول 65 جداش زاد
+
+296
+00:30:26,940 --> 00:30:34,560
+الميثانول عن الميثين احسبوا 88 و 65 حوالي 140 درجة
+
+297
+00:30:34,560 --> 00:30:39,320
+من وين نجول 140 درجة من الهيدروجين البونديني طبعا
+
+298
+00:30:39,320 --> 00:30:43,160
+ممكن واحدة تيجي تتساءل ما هو مش كل هيدروجين
+
+299
+00:30:43,160 --> 00:30:49,270
+بوندينيزي بعضه، يعني مع ال مثل أمين زادت ال
+
+300
+00:30:49,270 --> 00:30:53,230
+boiling point، لكن كده زادت؟ تمانين درجة، مع
+
+301
+00:30:53,230 --> 00:30:56,970
+الميثانول زادت ال boiling point، كده زادت؟ مية و
+
+302
+00:30:56,970 --> 00:31:00,690
+أربعين درجة، اه ما احنا بنعرف أن ال oxygen
+
+303
+00:31:00,690 --> 00:31:07,780
+السليلية تبعته أعلى من ال nitrogenواضح؟ ولذلك الـ
+
+304
+00:31:07,780 --> 00:31:11,140
+hydrogen bonding اللي موجود في حالات ال oxygen
+
+305
+00:31:11,140 --> 00:31:14,980
+أكتر من اللي في ال nitrogen فارتفاع رخطة الغليان
+
+306
+00:31:14,980 --> 00:31:18,900
+لمركب في oxygen بيكون أكتر من اللي مركب في
+
+307
+00:31:18,900 --> 00:31:23,320
+nitrogen في كل الأحوال .. في كل الأحوال المركبين
+
+308
+00:31:23,320 --> 00:31:25,780
+أشمالهم مرتفعين
+
+309
+00:31:27,590 --> 00:31:33,390
+عشان اقولك انه في عندك ناقص 88 للإيثين وقاعدة
+
+310
+00:31:33,390 --> 00:31:38,970
+بتزيد الحرارة لما صارت مثل الامين ناقص 6 ولا ..
+
+311
+00:31:38,970 --> 00:31:47,650
+ناقص 6 ارتفاع 80 درجة لما قولت ميثانون زائد 65 هذا
+
+312
+00:31:47,650 --> 00:31:51,510
+ارتفاع و هذا ارتفاع لكن الارتفاع الناشئ عن
+
+313
+00:31:51,510 --> 00:31:52,470
+الأكسجين
+
+314
+00:31:55,140 --> 00:31:59,080
+النيتروجين انا مابتش انسى ان الـ electronegativity
+
+315
+00:31:59,080 --> 00:32:01,840
+للأكسجين تلاتة و نص ال electronegativity
+
+316
+00:32:01,840 --> 00:32:07,480
+للنيتروجين تلاتة فلأنه السليبية لأن الأكسجين أعلى
+
+317
+00:32:07,480 --> 00:32:09,520
+فال hydrogen bonding اللي فيه
+
+318
+00:32:13,840 --> 00:32:17,520
+الارتفاع ارتفاع وهيدروجين bonding هيدروجين bonding
+
+319
+00:32:17,520 --> 00:32:22,320
+واضح لكن لو جيت بتهاجأت أسألكوا تحديدًا ليش
+
+320
+00:32:22,320 --> 00:32:26,460
+الميثانول أعلى من الميث الأمين؟ هنال أكسجين؟ اه
+
+321
+00:32:26,460 --> 00:32:30,000
+مالكشنش يقولولي هيدروجين bonding أنا فيه هيدروجين
+
+322
+00:32:30,000 --> 00:32:33,920
+bonding وانا فيه هيدروجين bonding لأن السالبية
+
+323
+00:32:33,920 --> 00:32:38,000
+للأكسجين أعلى فالهيدروجين bonding تبعه أقل
+
+324
+00:32:47,850 --> 00:32:55,250
+المقارنة نفسها تماما بس تختلف القيامة، واضح؟ فال
+
+325
+00:32:55,250 --> 00:33:00,110
+alcohol بتكون أعلى من ال amines أعلى كتير كتير من
+
+326
+00:33:00,110 --> 00:33:09,370
+ال alkyls، والسبب الhydrogen bonyالان كيف بنحضر ال
+
+327
+00:33:09,370 --> 00:33:14,330
+amines؟ نسبة من هذه الطرق اللي هي طرق تحضير ال
+
+328
+00:33:14,330 --> 00:33:19,830
+amines مرت معنا على سبيل المثال المرة الماضية لما
+
+329
+00:33:19,830 --> 00:33:25,130
+درسنا ال amides أخدنا أن ال production of amides
+
+330
+00:33:25,130 --> 00:33:29,490
+produces amine، produces amine، ان هذا ال c double
+
+331
+00:33:29,490 --> 00:33:36,270
+point هو تشفت CHOإذا إحدى طرق تحضير الأمين
+
+332
+00:33:36,270 --> 00:33:41,230
+reduction of amides واضح؟ reduction of amides
+
+333
+00:33:41,230 --> 00:33:47,290
+produces amines طبعا الناس الشطرين ما بدهم يشيفوا
+
+334
+00:33:47,290 --> 00:33:52,010
+عند هذه النقطة بيقدروا يرجعوا لورا كام خطوة جد ما
+
+335
+00:33:52,010 --> 00:33:59,390
+بدهم بمعنى الأمد من وين جاي؟ من الاسد والاسد إيه
+
+336
+00:33:59,390 --> 00:34:00,650
+طرق تحضيره؟
+
+337
+00:34:02,750 --> 00:34:07,250
+كان في عنده طرق تساوي و طرق زيادة و .. كل هذا
+
+338
+00:34:07,250 --> 00:34:12,890
+الكلام بدي أنتبهله يعني لو أنا طلبت بيكم amines من
+
+339
+00:34:12,890 --> 00:34:20,710
+ال amide فهذا هو السؤال السهل، الآن ممكن أرجعه بال
+
+340
+00:34:20,710 --> 00:34:28,330
+amine من ال acid؟ طب ال acid من إيش؟ مثلا من
+
+341
+00:34:28,330 --> 00:34:35,080
+الكحول، طريقة التساويأو الـ Dehydrate بطريقة
+
+342
+00:34:35,080 --> 00:34:40,600
+التساوي أو RX و بزيد عليها CO2 ولا بزيد عليها
+
+343
+00:34:40,600 --> 00:34:48,320
+Greenium CN أو من الكيل والكيل بحط عليه بعد هيك
+
+344
+00:34:48,320 --> 00:34:52,660
+Alcohol أو بحط عليه بيئة بمعنى كل الكيميا اللي قبل
+
+345
+00:34:52,660 --> 00:34:57,450
+اللي أعطينا عليها أمثلة كيف تحضروا ال acidبتصير
+
+346
+00:34:57,450 --> 00:35:02,530
+بعد هيك تلقاء الأسد بيصير أمد و الأمد بيصير أمين
+
+347
+00:35:02,530 --> 00:35:07,670
+فمش ضروري أنه هنا بتصير اللي هو الناس الشطريين
+
+348
+00:35:07,670 --> 00:35:11,270
+اللي بدوا يقعدوا بينهم بين نفسهم يفكروا لمدة نص
+
+349
+00:35:11,270 --> 00:35:15,350
+ساعة ساعة يتخيلوا كيف ممكن ينسقلوا في هذه المنطقة
+
+350
+00:35:15,350 --> 00:35:21,270
+مش بس يقولوا أنه والله الأمين من الأمد، كويس، و
+
+351
+00:35:21,270 --> 00:35:27,880
+الأمد من الأسد، و الأسدراجعوا الخمس طرق تبعونه
+
+352
+00:35:27,880 --> 00:35:32,840
+الان كل نقطة بداية بيحطل الإنسان يقولكم كيف منها
+
+353
+00:35:32,840 --> 00:35:39,440
+بتحضروا amines إذا الطالب ماعملش هالكلام لوحده
+
+354
+00:35:39,440 --> 00:35:45,660
+باستمتاع واجع ما نبدأ به لل acid و بعدين ال acid و
+
+355
+00:35:45,660 --> 00:35:49,940
+بعدين ال amide و بعدين ال amine مش هيتعلم واضحة
+
+356
+00:35:49,940 --> 00:35:55,760
+الفكرة؟ الان بيجينا ال aromatic amineاللي هو
+
+357
+00:35:55,760 --> 00:36:00,440
+الأليلين الآن لاحظوا من الأخطاء الشائعة دايما لما
+
+358
+00:36:00,440 --> 00:36:05,240
+نقول حضرونا الأليلين أنه أي حد فيكم بالذات إذا كنا
+
+359
+00:36:05,240 --> 00:36:10,640
+الأليلين من البنزين how can you prepare أليلين
+
+360
+00:36:10,640 --> 00:36:18,080
+starting from بنزين أكبر غلطة ممكن تعملوا عندكوا
+
+361
+00:36:18,080 --> 00:36:21,020
+تقولوا زي هيك و تيشوا تكتبوا لأنهاتين three
+
+362
+00:36:24,650 --> 00:36:30,170
+طبعا ليش هذه أكبر غلطة في الدنيا لأنه احنا اتفقنا
+
+363
+00:36:30,170 --> 00:36:36,770
+ان البنزين عبارة عن سحابة إلكترونية سالب السالب لا
+
+364
+00:36:36,770 --> 00:36:43,130
+يستطيع ان يهاجم عليه سالب ولذلك لا يمكن ان نيجي
+
+365
+00:36:43,130 --> 00:36:47,430
+نقول بدنا نجيب الأمونيا السالبة على البنزين السالب
+
+366
+00:36:47,430 --> 00:36:48,610
+ونحضر هذا الكلام
+
+367
+00:36:52,670 --> 00:36:56,730
+بنقول حضرولنا الانيلين من البنزين ماحدش يقول بنزين
+
+368
+00:36:56,730 --> 00:37:01,630
+زايد أمونيا أنيلين إيش من يجلبوا الأمونيا هنا إما
+
+369
+00:37:01,630 --> 00:37:05,450
+إذا كنتوا أقطام المغناطيس اللي زي بعض الشمالي
+
+370
+00:37:05,450 --> 00:37:09,650
+والشمالي بتاعون ألعاب الأطفال جربوهم مع بعض كيف
+
+371
+00:37:09,650 --> 00:37:15,530
+بيكونوا جاعدين نفس الشي هذا سهل وسهلعمرهم هيقدروا
+
+372
+00:37:15,530 --> 00:37:19,850
+يجربوا على بعض؟ لأ، إذا هذه الطريقة غير سليمة
+
+373
+00:37:19,850 --> 00:37:24,950
+إطلاقا لإنه محضر من خلالها الأدلين طب ها إيش
+
+374
+00:37:24,950 --> 00:37:29,310
+الطريقة السليمة؟ الطريقة السليمة إنه إحنا محضر
+
+375
+00:37:29,310 --> 00:37:34,230
+الـNitro Benzene هذا من الـHNO3 و الـH2SO4
+
+376
+00:37:34,230 --> 00:37:40,210
+اتعلمناه بعدين الـNitro Benzene الـNitro Benzene
+
+377
+00:37:40,210 --> 00:37:46,490
+بال reductionبنضيف عليها هيدروجين reduction
+
+378
+00:37:46,490 --> 00:37:52,470
+بالهيدروجين هيدروجينونيكل مثلا بتحول إلى إيش؟
+
+379
+00:37:52,470 --> 00:37:59,090
+الانيلين إذا الانيلين من البنزين يمر تأكيدا عبر
+
+380
+00:37:59,090 --> 00:38:04,390
+النيترو بنزين لما نقول بدنا انيلين من البنزين
+
+381
+00:38:04,390 --> 00:38:12,070
+بتكون قولولي المسار بنزين نيترو بنزين انيلين
+
+382
+00:38:14,070 --> 00:38:20,930
+وقع الفكرة هذا هو المسار بنزين نايترو بنزين قليل
+
+383
+00:38:20,930 --> 00:38:29,950
+الآن لبس ان انا اضيفلكم هنا كمان معلومة كتير مهمة
+
+384
+00:38:29,950 --> 00:38:32,990
+مر
+
+385
+00:38:32,990 --> 00:38:40,250
+علينا طبعا هنا قلنا HRO3H2O4 مر علينا الفيلول
+
+386
+00:38:41,480 --> 00:38:46,700
+بتعرفوا ال phenol؟ اه لو اتينا و قولنالكم how can
+
+387
+00:38:46,700 --> 00:38:52,560
+you prepare phenol يعني
+
+388
+00:38:52,560 --> 00:39:00,160
+هنا OH starting from بنزين كيف
+
+389
+00:39:00,160 --> 00:39:05,780
+تحضر ال phenol من البنزين؟ الآن أكبر غلط ممكن
+
+390
+00:39:05,780 --> 00:39:08,820
+الواحد يعمله إيش؟ يقول بنزين
+
+391
+00:39:17,390 --> 00:39:24,350
+- أزواج إلكترونال ليش؟ لأن هذا السالب لا يهاجم على
+
+392
+00:39:24,350 --> 00:39:30,770
+هذا السالب إذن مش ممكن أقول البنزين .. مش ممكن
+
+393
+00:39:30,770 --> 00:39:34,290
+أقول البنزين فعله مع الـ OH بيعطينا فينول أول ما
+
+394
+00:39:34,290 --> 00:39:40,830
+جالبهم OH على بنزين بتنافر واضح؟ إذن لابد من طريقة
+
+395
+00:39:40,830 --> 00:39:46,880
+تانيةلتحضير الفينول هذه الطريقة التالية لتحضير
+
+396
+00:39:46,880 --> 00:39:51,680
+الفينول بتمشي عبر هذا المسار تمام عبر هذا المسار
+
+397
+00:39:51,680 --> 00:39:58,820
+بيقول بنزين نيترو بنزين أنيلين و بعدين بدي كمان
+
+398
+00:39:58,820 --> 00:40:05,440
+reactions هنا بحط نمرة واحد NKF2 صوديوم نيترايت
+
+399
+00:40:05,440 --> 00:40:09,980
+تمام و نمرة اتنين بحط H2O
+
+400
+00:40:13,640 --> 00:40:22,220
+أش فبصير الفيلول من البنزين سلسله أطول كمان بنزين
+
+401
+00:40:22,220 --> 00:40:30,200
+نيترو بنزين أنيلين فيلول واضح؟ فأي تحضير الأنيلين
+
+402
+00:40:30,200 --> 00:40:34,640
+من البنزين عبر نيترو بنزين؟ وتحضير الفيلول من
+
+403
+00:40:34,640 --> 00:40:39,700
+البنزين عبر نيترو بنزين أنيلين فيلول هانا ال
+
+404
+00:40:39,700 --> 00:40:41,640
+reduction دايما باستعمال أش
+
+405
+00:40:44,660 --> 00:40:51,720
+مع metal زي ال nickel او ما شبه و هذا كثير مرات
+
+406
+00:40:51,720 --> 00:40:56,020
+بتجيبوا .. بتجيبوا يا سؤال صح و غلط اكمل معادلة
+
+407
+00:40:56,020 --> 00:40:59,440
+فيلون can be prepared from the reaction مثلا of
+
+408
+00:40:59,440 --> 00:41:04,260
+بنزين والسوديوم هيدروكسايد هو السوديوم هيدروكسايد
+
+409
+00:41:04,260 --> 00:41:13,990
+COH- خطأ خطأ خطأ إلو إيش سلسلة متتاليةزي سلاسل
+
+410
+00:41:13,990 --> 00:41:19,530
+الرواد في علم الحديث، عارفينها؟ سلسلة ذهبية وسلسلة
+
+411
+00:41:19,530 --> 00:41:26,410
+كذا، وراوة النعمان وعنمان السماء، كيف يروي مالك عن
+
+412
+00:41:26,410 --> 00:41:32,590
+أنسى طيب،
+
+413
+00:41:32,590 --> 00:41:37,820
+كام طريقة هيك منكون أخدنا لتحضير الأمينس؟Tintin من
+
+414
+00:41:37,820 --> 00:41:41,980
+الـ Amides وتحضير الـ aromatic amines من الـ
+
+415
+00:41:41,980 --> 00:41:47,620
+Nitrobenzene الآن في عندى طريقة تالتة reduction of
+
+416
+00:41:47,620 --> 00:41:53,120
+cyanide يعني الـCN هذه هي عبارة عن إيش لو إحنا
+
+417
+00:41:53,120 --> 00:42:02,680
+طلعنا عليها C driven on Nلو طفنا عليها هيدروجين
+
+418
+00:42:02,680 --> 00:42:08,860
+هيكتبلكوا 4H طبعا 4H هذي بتيجينا غالبا من Lithium
+
+419
+00:42:08,860 --> 00:42:12,600
+Aluminum Hydride الهيدروجين مش هذا مصدق ده
+
+420
+00:42:12,600 --> 00:42:19,040
+هيدروجين، هتنقضوا بالبند وتحطوا H وH و تنقضوا كمان
+
+421
+00:42:19,040 --> 00:42:21,800
+بند وتحطوا H وH
+
+422
+00:42:23,770 --> 00:42:29,050
+صارت عبارة عن أميل، إذا ال reduction of nitro
+
+423
+00:42:29,050 --> 00:42:32,410
+compounds في الغضب لل triple bonds البايبل دي
+
+424
+00:42:32,410 --> 00:42:38,310
+الأولى والبايبل دي التانية بنتهي CH2NH2 هل كانت CE
+
+425
+00:42:38,310 --> 00:42:42,830
+N؟ ضيفنا H وH وH وH وH وH وH وH وH وH وH وH وH وH
+
+426
+00:42:42,830 --> 00:42:45,870
+وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH
+
+427
+00:42:45,870 --> 00:42:46,050
+وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH
+
+428
+00:42:46,050 --> 00:42:46,310
+وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH
+
+429
+00:42:46,310 --> 00:42:50,930
+وH وH وH وH وH وH وH وH وH وH وH وH وH وH وبترجع
+
+430
+00:42:50,930 --> 00:43:00,150
+خطوة لبرا هذه مثلا كانت CH3CL مع CL minus بالإبدال
+
+431
+00:43:00,150 --> 00:43:10,390
+بتحل ال CL محل ال CL بتحل ال CL محل ال CL إذا من
+
+432
+00:43:10,390 --> 00:43:16,250
+ال highlights كنا نبدل ال CL و ال PR بCL بعد هيك
+
+433
+00:43:16,250 --> 00:43:19,430
+ال CL بنضيف عليها هيدروجين نعملها reduction
+
+434
+00:43:28,380 --> 00:43:34,500
+أخر طريقة أخدناها عشان يكب نذكرها بدقيقة لما أخدنا
+
+435
+00:43:34,500 --> 00:43:38,820
+chapter ال Rx لو قلنا لكم أكمل المعادلة لغاية كل
+
+436
+00:43:38,820 --> 00:43:42,660
+هدول اللي قدامكم بس عشان تتأكدوا أن احنا أخدناها
+
+437
+00:43:42,660 --> 00:43:52,500
+قلنا لكم CH3 CH2PR هذا عبارة عن إيش الكلهلان زائد
+
+438
+00:43:52,500 --> 00:43:59,100
+NH3 ال Euclidean 5كيف كنتوا تكملوا هذه المعادلة؟
+
+439
+00:43:59,100 --> 00:44:04,820
+امير او اموريا مع هالك اللي lied الـ eucleophilic
+
+440
+00:44:04,820 --> 00:44:13,260
+substitution اللي بدأ بوضوع شبطة ستة CH3 CH2 و هذا
+
+441
+00:44:13,260 --> 00:44:16,560
+ال neutral ال eucleophil دائما بيفقد H
+
+442
+00:44:21,410 --> 00:44:26,030
+أي مشتقة أمونيا المهم يكون فيها على أقل تقدير أتش
+
+443
+00:44:26,030 --> 00:44:29,450
+يعني المهم
+
+444
+00:44:29,450 --> 00:44:34,330
+يكون عندكم إيش أتش عشان الأتش تفقد أمين زي الأكل
+
+445
+00:44:34,330 --> 00:44:40,790
+هلاي بعمل إبداع وهذا حلنا عليه مسائل كتير في الفصل
+
+446
+00:44:40,790 --> 00:44:47,330
+السادسهذه أيضًا طريقة و عليها مثالين توضحيين
+
+447
+00:44:47,330 --> 00:44:52,970
+عندكم، اللي هي طريقة إبدال على ال الكلهيلات، طريقة
+
+448
+00:44:52,970 --> 00:44:57,510
+الإبدال على ال الكلهيلات، يعني لاحظوا هذا ال
+
+449
+00:44:57,510 --> 00:45:03,850
+الكلهيلات وينه؟ المثل أيضاري، بجيب بداله الأمين،
+
+450
+00:45:03,850 --> 00:45:05,850
+هذه الأمين، اتجه الآن
+
+451
+00:45:09,910 --> 00:45:15,350
+لأ هو بهذا المثال هاي ال kilohydride هاي ال PR إيش
+
+452
+00:45:15,350 --> 00:45:18,790
+في عنده هنا ال unatomobiles ال unatomobiles خلّى
+
+453
+00:45:18,790 --> 00:45:25,250
+الآن نتاجر تجربة ال PR و إذا بتعمل إيش حلقات صار
+
+454
+00:45:25,250 --> 00:45:30,470
+عندى مركب النكوتين هذا المركب النكوتين كيف نحطه
+
+455
+00:45:30,470 --> 00:45:35,190
+نكوتين السجاني في كل الأحوال ال unat
+
+456
+00:45:39,910 --> 00:45:43,910
+الـ PR أو الـ CL ابتفعوا الإدالة، فطرق تحضير
+
+457
+00:45:43,910 --> 00:45:49,370
+الأمين استلخيصا من الـ Amides، من الـ CL، من
+
+458
+00:45:49,370 --> 00:45:52,690
+الإدالة محل الـ Halogens، والـ Aromatic أمين
+
+459
+00:45:52,690 --> 00:45:58,190
+باختزال الـ Nitrobenzene، واضحة الفكرة؟ إن شاء
+
+460
+00:45:58,190 --> 00:45:58,290
+الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..97446cc63ea6fa0d0d19aa97472ba5e031d7b545
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4981, "start": 24.69, "end": 49.81, "text": "الحدي عشر في جزء الكيميا الرجوية العادى قبل ما ننتقل لمقدمة البيت الاسطي اللى هو بعنوان amines amines يعني مركبات ال nitrogen المركبات اللى فيها ال nitrogen طبعا كلنا عارفين ان ال amine او ال nitrogen", "tokens": [6027, 5016, 16254, 6225, 46309, 8978, 10874, 11622, 38207, 33251, 32640, 25528, 34892, 7435, 2407, 10632, 18863, 18513, 7578, 12174, 36150, 19446, 8717, 29399, 4587, 1211, 32767, 28543, 46007, 2423, 21292, 2655, 2423, 32277, 9566, 1829, 13672, 7578, 31439, 4724, 3615, 1863, 2407, 7649, 669, 1652, 669, 1652, 37495, 22653, 3714, 31747, 3555, 9307, 2423, 17903, 9673, 31747, 3555, 9307, 13672, 7578, 8978, 11296, 2423, 17903, 23032, 3555, 3615, 995, 28242, 8315, 6225, 9640, 5172, 9957, 16472, 2423, 669, 533, 1975, 2407, 2423, 17903], "avg_logprob": -0.29025735013625203, "compression_ratio": 1.7608695652173914, "no_speech_prob": 5.125999450683594e-06, "words": [{"start": 24.69, "end": 24.99, "word": "الحدي", "probability": 0.3006998697916667}, {"start": 24.99, "end": 25.61, "word": " عشر", "probability": 0.6773681640625}, {"start": 25.61, "end": 27.17, "word": " في", "probability": 0.84521484375}, {"start": 27.17, "end": 27.57, "word": " جزء", "probability": 0.986328125}, {"start": 27.57, "end": 28.03, "word": " الكيميا", "probability": 0.9197591145833334}, {"start": 28.03, "end": 28.57, "word": " الرجوية", "probability": 0.8310546875}, {"start": 28.57, "end": 29.09, "word": " العادى", "probability": 0.9173177083333334}, {"start": 29.09, "end": 29.41, "word": " قبل", "probability": 0.916015625}, {"start": 29.41, "end": 29.55, "word": " ما", "probability": 0.86669921875}, {"start": 29.55, "end": 30.19, "word": " ننتقل", "probability": 0.888916015625}, {"start": 30.19, "end": 31.25, "word": " لمقدمة", "probability": 0.84619140625}, {"start": 31.25, "end": 31.67, "word": " البيت", "probability": 0.5181477864583334}, {"start": 31.67, "end": 32.33, "word": " الاسطي", "probability": 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لما بيكونوا إيش هيدروجيز بيكون عنده جزء الأمونيا يعني أبسط مركب للنيتروجيز هو جزء الأمونيا الآن الأمونيا ممكن ما نعتبرهاش مركبة", "tokens": [6027, 7649, 8032, 8848, 12610, 2423, 38637, 1211, 5718, 104, 12602, 14407, 3555, 9566, 8978, 5551, 3555, 3794, 9566, 9673, 31747, 3555, 9307, 15844, 33688, 9566, 15040, 4587, 6055, 3555, 3615, 2423, 8717, 36081, 2288, 29245, 1829, 11622, 5296, 15042, 4724, 1829, 30544, 14407, 11933, 1829, 8592, 8032, 25708, 2288, 29245, 1829, 11622, 4724, 1829, 30544, 43242, 3224, 10874, 11622, 38207, 16247, 2304, 11536, 25528, 37495, 22653, 5551, 3555, 3794, 9566, 3714, 31747, 3555, 24976, 22653, 2655, 2288, 29245, 1829, 11622, 31439, 10874, 11622, 38207, 16247, 2304, 11536, 25528, 6024, 48506, 16247, 2304, 11536, 25528, 3714, 43020, 19446, 8717, 34268, 26890, 3224, 33599, 3714, 31747, 49401], "avg_logprob": -0.2469334131646379, "compression_ratio": 2.0168539325842696, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 67.02000000000001, "end": 68.34, 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السليبيات يعني ال hydrogen bonding أساسا لما بنعرفه احنا بنربطه بتلت ذرات أساسية إذا اتصلت ال hydrogen مع ال fluorine أو ال oxygen أو ال nitrogen فهو أحد التلاتة اللي بيعملوا hydrogen bonding", "tokens": [6027, 7649, 23032, 3555, 3615, 995, 20666, 1863, 35457, 3660, 5296, 9778, 1211, 33546, 2423, 669, 1652, 9122, 8315, 44945, 2655, 8848, 37983, 16472, 2423, 17903, 9154, 5551, 3615, 23942, 21136, 20292, 21292, 9307, 37495, 22653, 2423, 12697, 28824, 5551, 3794, 32277, 995, 5296, 15042, 44945, 3615, 28480, 3224, 1975, 5016, 8315, 44945, 25513, 9566, 3224, 39894, 1211, 2655, 29910, 2288, 9307, 5551, 3794, 32277, 10632, 11933, 15730, 1975, 2655, 36520, 2655, 2423, 12697, 20449, 2423, 40540, 533, 34051, 2423, 9169, 34051, 2423, 17903, 6156, 3224, 2407, 5551, 24401, 16712, 1211, 9307, 3660, 13672, 1829, 4724, 1829, 25957, 1211, 14407, 12697, 28824], "avg_logprob": -0.14798240262327841, "compression_ratio": 1.78125, "no_speech_prob": 0.0, "words": [{"start": 353.06, "end": 353.98, "word": 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"seek": 140883, "start": 1380.29, "end": 1408.83, "text": "كله اسمه amine باسم مُركّب نيتروجينكتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناترام", "tokens": [28820, 3224, 24525, 2304, 3224, 669, 533, 4724, 32277, 2304, 3714, 10859, 31747, 11703, 3555, 8717, 36081, 2288, 29245, 9957, 4117, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 2288, 10943, 1829, 8315, 2655, 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ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و", "tokens": [28814, 1863, 3224, 29538, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 4032, 1030, 3495, 75, 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"probability": 0.85595703125}, {"start": 1512.8, "end": 1513.02, "word": " لأ", "probability": 0.4217529296875}, {"start": 1513.02, "end": 1513.48, "word": " بيسميه", "probability": 0.9451171875}, {"start": 1513.48, "end": 1515.18, "word": " بيوتان", "probability": 0.88525390625}, {"start": 1515.18, "end": 1515.8, "word": " أمين", "probability": 0.8746744791666666}], "temperature": 1.0}, {"id": 54, "seek": 154160, "start": 1516.42, "end": 1541.6, "text": "بعرفش إذا دي واضحة ولا بنزم أني أوضحها أكتر لكم يعني خليني أخد هذا المركب و أحط هنا OH عشان أنتوا تنتبهوا لما أنا كنت أسمي هذا بيوتان", "tokens": [3555, 3615, 28480, 8592, 11933, 15730, 11778, 1829, 4032, 46958, 5016, 3660, 49429, 44945, 11622, 2304, 14739, 1829, 34051, 11242, 5016, 11296, 5551, 4117, 2655, 2288, 5296, 24793, 37495, 22653, 16490, 1211, 9957, 1829, 5551, 9778, 3215, 23758, 9673, 31747, 3555, 4032, 5551, 5016, 9566, 34105, 13931, 6225, 8592, 7649, 14739, 2655, 14407, 6055, 29399, 3555, 3224, 14407, 5296, 15042, 41850, 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"probability": 0.6402587890625}, {"start": 1522.62, "end": 1523.42, "word": " يعني", "probability": 0.744873046875}, {"start": 1523.42, "end": 1527.16, "word": " خليني", "probability": 0.9365234375}, {"start": 1527.16, "end": 1528.26, "word": " أخد", "probability": 0.8277994791666666}, {"start": 1528.26, "end": 1528.56, "word": " هذا", "probability": 0.97509765625}, {"start": 1528.56, "end": 1529.28, "word": " المركب", "probability": 0.86962890625}, {"start": 1529.28, "end": 1529.5, "word": " و", "probability": 0.623046875}, {"start": 1529.5, "end": 1529.88, "word": " أحط", "probability": 0.8981119791666666}, {"start": 1529.88, "end": 1530.28, "word": " هنا", "probability": 0.970703125}, {"start": 1530.28, "end": 1531.04, "word": " OH", "probability": 0.27490234375}, {"start": 1531.04, "end": 1533.3, "word": " عشان", "probability": 0.9762369791666666}, {"start": 1533.3, "end": 1533.54, "word": " أنتوا", "probability": 0.6796061197916666}, {"start": 1533.54, "end": 1534.7, "word": " تنتبهوا", "probability": 0.97060546875}, {"start": 1534.7, "end": 1535.08, "word": " لما", "probability": 0.861083984375}, {"start": 1535.08, "end": 1535.48, "word": " أنا", "probability": 0.8681640625}, {"start": 1535.48, "end": 1535.94, "word": " كنت", "probability": 0.99560546875}, {"start": 1535.94, "end": 1536.6, "word": " أسمي", "probability": 0.89990234375}, {"start": 1536.6, "end": 1537.2, "word": " هذا", "probability": 0.98583984375}, {"start": 1537.2, "end": 1541.6, "word": " بيوتان", "probability": 0.74383544921875}], "temperature": 1.0}, {"id": 55, "seek": 157736, "start": 1548.62, "end": 1577.36, "text": "و أحطله one هذا ال IOPAC منه الان لما كنت أسميه بال common nominative شو كنت أسميه؟ butyl و أحط العائلة alcohol butyl alcohol okay butyl alcohol الان الناس اللي بيعملوا على نظام تسمية تالف", "tokens": [2407, 5551, 5016, 9566, 43761, 472, 23758, 2423, 286, 12059, 4378, 9154, 3224, 2423, 7649, 5296, 15042, 9122, 29399, 5551, 38251, 1829, 3224, 20666, 2689, 5369, 259, 1166, 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"end": 1554.02, "word": " الان", "probability": 0.6005859375}, {"start": 1554.02, "end": 1554.66, "word": " لما", "probability": 0.911376953125}, {"start": 1554.66, "end": 1555.02, "word": " كنت", "probability": 0.99169921875}, {"start": 1555.02, "end": 1556.18, "word": " أسميه", "probability": 0.8836669921875}, {"start": 1556.18, "end": 1557.16, "word": " بال", "probability": 0.93896484375}, {"start": 1557.16, "end": 1557.54, "word": " common", "probability": 0.828125}, {"start": 1557.54, "end": 1558.38, "word": " nominative", "probability": 0.44287109375}, {"start": 1558.38, "end": 1559.1, "word": " شو", "probability": 0.771728515625}, {"start": 1559.1, "end": 1559.28, "word": " كنت", "probability": 0.9892578125}, {"start": 1559.28, "end": 1560.98, "word": " أسميه؟", "probability": 0.8283203125}, {"start": 1560.98, "end": 1561.68, "word": " butyl", "probability": 0.526580810546875}, {"start": 1561.68, "end": 1564.08, "word": " و", "probability": 0.2374267578125}, {"start": 1564.08, "end": 1564.6, "word": " أحط", "probability": 0.96044921875}, {"start": 1564.6, "end": 1565.38, "word": " العائلة", "probability": 0.9871419270833334}, {"start": 1565.38, "end": 1566.34, "word": " alcohol", "probability": 0.849609375}, {"start": 1566.34, "end": 1567.76, "word": " butyl", "probability": 0.7470703125}, {"start": 1567.76, "end": 1568.84, "word": " alcohol", "probability": 0.8203125}, {"start": 1568.84, "end": 1570.92, "word": " okay", "probability": 0.407958984375}, {"start": 1570.92, "end": 1572.18, "word": " butyl", "probability": 0.809814453125}, {"start": 1572.18, "end": 1572.82, "word": " alcohol", "probability": 0.900390625}, {"start": 1572.82, "end": 1573.74, "word": " الان", "probability": 0.846923828125}, {"start": 1573.74, "end": 1574.98, "word": " الناس", "probability": 0.984375}, {"start": 1574.98, "end": 1575.14, "word": " اللي", "probability": 0.87451171875}, {"start": 1575.14, "end": 1575.58, "word": " بيعملوا", "probability": 0.9642578125}, {"start": 1575.58, "end": 1575.78, "word": " على", "probability": 0.87890625}, {"start": 1575.78, "end": 1576.18, "word": " نظام", "probability": 0.9327799479166666}, {"start": 1576.18, "end": 1576.78, "word": " تسمية", "probability": 0.9112955729166666}, {"start": 1576.78, "end": 1577.36, "word": " تالف", "probability": 0.6871744791666666}], "temperature": 1.0}, {"id": 56, "seek": 160161, "start": 1581.69, "end": 1601.61, "text": "عندي nh2، بدي أعطي العائلة أمين، يعني نغير هذه نخليها nh2، فبصير بيوتان أمين، طب وهذا بيوت الأمين، واضح تلاحظين أنه الفرق ما بين", "tokens": [3615, 1863, 16254, 6245, 17, 12399, 4724, 16254, 5551, 3615, 9566, 1829, 18863, 16373, 37977, 5551, 2304, 9957, 12399, 37495, 22653, 8717, 17082, 13546, 29538, 8717, 9778, 20292, 11296, 6245, 17, 12399, 6156, 3555, 9381, 13546, 4724, 1829, 35473, 7649, 5551, 2304, 9957, 12399, 23032, 3555, 37037, 15730, 4724, 1829, 35473, 2423, 10721, 2304, 9957, 12399, 4032, 46958, 5016, 6055, 15040, 5016, 19913, 9957, 14739, 3224, 27188, 2288, 4587, 19446, 49374], "avg_logprob": -0.3337673644224803, "compression_ratio": 1.5763888888888888, "no_speech_prob": 5.346536636352539e-05, "words": [{"start": 1581.69, "end": 1581.89, "word": "عندي", "probability": 0.5288899739583334}, {"start": 1581.89, "end": 1583.15, "word": " nh2،", "probability": 0.4435831705729167}, {"start": 1583.15, "end": 1583.47, "word": " بدي", "probability": 0.67333984375}, {"start": 1583.47, "end": 1583.83, "word": " أعطي", "probability": 0.90576171875}, {"start": 1583.83, "end": 1584.45, "word": " العائلة", "probability": 0.9830729166666666}, {"start": 1584.45, "end": 1585.85, "word": " أمين،", "probability": 0.624053955078125}, {"start": 1585.85, "end": 1587.95, "word": " يعني", "probability": 0.798828125}, {"start": 1587.95, "end": 1588.59, "word": " نغير", "probability": 0.8728841145833334}, {"start": 1588.59, "end": 1588.83, "word": " هذه", "probability": 0.67138671875}, {"start": 1588.83, "end": 1589.55, "word": " نخليها", "probability": 0.81109619140625}, {"start": 1589.55, "end": 1591.19, "word": " nh2،", "probability": 0.8499348958333334}, {"start": 1591.19, "end": 1591.73, "word": " فبصير", "probability": 0.86083984375}, {"start": 1591.73, "end": 1592.73, "word": " بيوتان", "probability": 0.913330078125}, {"start": 1592.73, "end": 1594.41, "word": " أمين،", "probability": 0.884765625}, {"start": 1594.41, "end": 1595.37, "word": " طب", "probability": 0.6156005859375}, {"start": 1595.37, "end": 1596.17, "word": " وهذا", "probability": 0.737548828125}, {"start": 1596.17, "end": 1596.91, "word": " بيوت", "probability": 0.92626953125}, {"start": 1596.91, "end": 1599.61, "word": " الأمين،", "probability": 0.76767578125}, {"start": 1599.61, "end": 1600.03, "word": " واضح", "probability": 0.93017578125}, {"start": 1600.03, "end": 1600.63, "word": " تلاحظين", "probability": 0.801416015625}, {"start": 1600.63, "end": 1600.91, "word": " أنه", "probability": 0.5511474609375}, {"start": 1600.91, "end": 1601.29, "word": " الفرق", "probability": 0.97802734375}, {"start": 1601.29, "end": 1601.47, "word": " ما", "probability": 0.7958984375}, {"start": 1601.47, "end": 1601.61, "word": " بين", "probability": 0.453369140625}], "temperature": 1.0}, {"id": 57, "seek": 163059, "start": 1602.53, "end": 1630.59, "text": "بيوتان و بيوتين في كل الأحوال هذا النظام مابتيش يقتصر معالي لكن مرات بنذكر أشياء اللي لو قرأتوها ماتحسوش باستغراب احنا اللي بدنا نسمي عليه the iopac nomenclature ان مراكبات ال amines بتتبع الalkenes هي مشتقات للalkenes و لو كنا بتناقلكم ال common nomenclatures تبعها فبنكتم المجموعة و بعدين ال amine لكن لو قرأتوا اشي تاني", "tokens": [3555, 1829, 35473, 7649, 4032, 4724, 1829, 35473, 9957, 8978, 28242, 16247, 5016, 2407, 6027, 23758, 28239, 19913, 10943, 3714, 16758, 31371, 8592, 7251, 38149, 9381, 2288, 20449, 995, 20292, 44381, 3714, 2288, 9307, 44945, 8848, 37983, 5551, 8592, 1829, 16606, 13672, 1829, 45164, 12174, 2288, 10721, 2655, 2407, 11296, 3714, 9307, 5016, 3794, 2407, 8592, 4724, 995, 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{"start": 1609.51, "end": 1609.65, "word": " اللي", "probability": 0.8740234375}, {"start": 1609.65, "end": 1609.83, "word": " لو", "probability": 0.9853515625}, {"start": 1609.83, "end": 1610.67, "word": " قرأتوها", "probability": 0.9029947916666666}, {"start": 1610.67, "end": 1611.73, "word": " ماتحسوش", "probability": 0.9007975260416666}, {"start": 1611.73, "end": 1612.69, "word": " باستغراب", "probability": 0.8578287760416666}, {"start": 1612.69, "end": 1613.27, "word": " احنا", "probability": 0.9069010416666666}, {"start": 1613.27, "end": 1613.39, "word": " اللي", "probability": 0.9755859375}, {"start": 1613.39, "end": 1613.55, "word": " بدنا", "probability": 0.71337890625}, {"start": 1613.55, "end": 1613.95, "word": " نسمي", "probability": 0.9783528645833334}, {"start": 1613.95, "end": 1614.21, "word": " عليه", "probability": 0.97705078125}, {"start": 1614.21, "end": 1614.37, "word": " the", "probability": 0.09539794921875}, {"start": 1614.37, "end": 1614.79, "word": " iopac", 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"text": "hydrogen bonding وبالتالي من ناحية من ناحية من ناحية مقارنة ال boiling point تبعتهم يفترض انها ليش تكون عالية مرتفعة طبعا اللي بده يعمل المقارنة ويفهمها جيدا بده يقارن مع إشي مافيش فيه hydrogen bonding يعني إشي فيه hydrogen bonding وإشي مافيه hydrogen bonding وبده يوحد العوامل التانية", "tokens": [21591, 7747, 28824, 46599, 6027, 2655, 6027, 1829, 9154, 8717, 39319, 10632, 9154, 8717, 39319, 10632, 9154, 8717, 39319, 10632, 3714, 4587, 9640, 1863, 3660, 2423, 16208, 935, 6055, 3555, 34268, 16095, 7251, 5172, 2655, 43042, 16472, 11296, 32239, 8592, 6055, 30544, 6225, 6027, 10632, 3714, 43500, 5172, 27884, 23032, 3555, 3615, 995, 13672, 1829, 47525, 3224, 7251, 25957, 1211, 9673, 4587, 9640, 1863, 3660, 4032, 33911, 16095, 11296, 10874, 25708, 995, 47525, 3224, 7251, 4587, 9640, 1863, 20449, 11933, 8592, 1829, 19446, 41185, 8592, 8978, 3224, 12697, 28824, 37495, 22653, 11933, 8592, 1829, 8978, 3224, 12697, 28824, 4032, 28814, 8592, 1829, 19446, 41185, 3224, 12697, 28824, 4032, 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هيدروجين", "probability": 0.816650390625}, {"start": 2265.11, "end": 2266.49, "word": " reduction", "probability": 0.462890625}, {"start": 2266.49, "end": 2267.29, "word": " بالهيدروجين", "probability": 0.9554036458333334}, {"start": 2267.29, "end": 2268.45, "word": " هيدروجينونيكل", "probability": 0.6464614868164062}, {"start": 2268.45, "end": 2268.99, "word": " مثلا", "probability": 0.954345703125}, {"start": 2268.99, "end": 2271.51, "word": " بتحول", "probability": 0.8974609375}, {"start": 2271.51, "end": 2271.83, "word": " إلى", "probability": 0.341064453125}, {"start": 2271.83, "end": 2272.47, "word": " إيش؟", "probability": 0.8138427734375}, {"start": 2272.47, "end": 2273.33, "word": " الانيلين", "probability": 0.67706298828125}, {"start": 2273.33, "end": 2274.05, "word": " إذا", "probability": 0.79736328125}, {"start": 2274.05, "end": 2275.23, "word": " الانيلين", "probability": 0.9129638671875}, {"start": 2275.23, "end": 2275.47, "word": " من", "probability": 0.994140625}, {"start": 2275.47, "end": 2276.29, "word": " البنزين", "probability": 0.97509765625}, {"start": 2276.29, "end": 2277.17, "word": " يمر", "probability": 0.927001953125}, {"start": 2277.17, "end": 2278.31, "word": " تأكيدا", "probability": 0.92294921875}, {"start": 2278.31, "end": 2279.09, "word": " عبر", "probability": 0.9853515625}, {"start": 2279.09, "end": 2281.79, "word": " النيترو", "probability": 0.7040252685546875}, {"start": 2281.79, "end": 2282.47, "word": " بنزين", "probability": 0.9674479166666666}, {"start": 2282.47, "end": 2282.83, "word": " لما", "probability": 0.907958984375}, {"start": 2282.83, "end": 2283.05, "word": " نقول", "probability": 0.789306640625}, {"start": 2283.05, "end": 2283.33, "word": " بدنا", "probability": 0.6004638671875}, {"start": 2283.33, "end": 2283.79, "word": " انيلين", "probability": 0.7926432291666666}, {"start": 2283.79, "end": 2283.93, "word": " من", "probability": 0.99609375}, {"start": 2283.93, "end": 2284.39, "word": " البنزين", "probability": 0.9930419921875}, {"start": 2284.39, "end": 2284.71, "word": " بتكون", "probability": 0.781982421875}, {"start": 2284.71, "end": 2285.29, "word": " قولولي", "probability": 0.73785400390625}, {"start": 2285.29, "end": 2286.37, "word": " المسار", "probability": 0.7412923177083334}, {"start": 2286.37, "end": 2287.51, "word": " بنزين", "probability": 0.9638671875}, {"start": 2287.51, "end": 2289.59, "word": " نيترو", "probability": 0.873046875}, {"start": 2289.59, "end": 2290.53, "word": " بنزين", "probability": 0.9915364583333334}, {"start": 2290.53, "end": 2292.07, "word": " انيلين", "probability": 0.79296875}], "temperature": 1.0}, {"id": 83, "seek": 232025, "start": 2294.07, "end": 2320.25, "text": "وقع الفكرة هذا هو المسار بنزين نايترو بنزين قليل الآن لبس ان انا اضيفلكم هنا كمان معلومة كتير مهمة مر علينا طبعا هنا قلنا HRO3H2O4 مر علينا الفيلول", "tokens": [2407, 4587, 3615, 27188, 4117, 25720, 23758, 31439, 9673, 3794, 9640, 44945, 11622, 9957, 8717, 995, 36081, 32887, 44945, 11622, 9957, 12174, 20292, 1211, 6024, 48506, 5296, 3555, 3794, 16472, 1975, 8315, 1975, 11242, 33911, 23275, 2304, 34105, 9122, 2304, 7649, 20449, 1211, 20498, 3660, 9122, 2655, 13546, 3714, 16095, 3660, 3714, 2288, 25894, 8315, 23032, 3555, 3615, 995, 34105, 12174, 1211, 8315, 19460, 46, 18, 39, 17, 46, 19, 3714, 2288, 25894, 8315, 27188, 26895, 12610], "avg_logprob": -0.2802483928509248, "compression_ratio": 1.6709677419354838, "no_speech_prob": 0.0, "words": [{"start": 2294.07, "end": 2294.45, "word": "وقع", "probability": 0.5751139322916666}, {"start": 2294.45, "end": 2294.97, "word": " الفكرة", "probability": 0.9920247395833334}, {"start": 2294.97, "end": 2296.03, "word": " هذا", "probability": 0.525390625}, {"start": 2296.03, "end": 2296.29, "word": " هو", "probability": 0.97314453125}, {"start": 2296.29, "end": 2297.17, "word": " المسار", "probability": 0.8349609375}, {"start": 2297.17, "end": 2298.67, "word": " بنزين", "probability": 0.931640625}, {"start": 2298.67, "end": 2299.45, "word": " نايترو", "probability": 0.69244384765625}, {"start": 2299.45, "end": 2300.13, "word": " بنزين", "probability": 0.990234375}, {"start": 2300.13, "end": 2300.93, "word": " قليل", "probability": 0.6192220052083334}, {"start": 2300.93, "end": 2302.19, "word": " الآن", "probability": 0.642578125}, {"start": 2302.19, "end": 2303.47, "word": " لبس", "probability": 0.7610677083333334}, {"start": 2303.47, "end": 2303.93, "word": " ان", "probability": 0.45458984375}, {"start": 2303.93, "end": 2304.61, "word": " انا", "probability": 0.6160888671875}, {"start": 2304.61, "end": 2306.11, "word": " اضيفلكم", "probability": 0.77197265625}, {"start": 2306.11, "end": 2306.61, "word": " هنا", "probability": 0.86474609375}, {"start": 2306.61, "end": 2307.23, "word": " كمان", "probability": 0.8072102864583334}, {"start": 2307.23, "end": 2308.03, "word": " معلومة", "probability": 0.94384765625}, {"start": 2308.03, "end": 2308.57, "word": " كتير", "probability": 0.8673502604166666}, {"start": 2308.57, "end": 2309.95, "word": " مهمة", "probability": 0.9820963541666666}, {"start": 2309.95, "end": 2312.99, "word": " مر", "probability": 0.79638671875}, {"start": 2312.99, "end": 2313.65, "word": " علينا", "probability": 0.968994140625}, {"start": 2313.65, "end": 2314.49, "word": " طبعا", "probability": 0.8721923828125}, {"start": 2314.49, "end": 2314.65, "word": " هنا", "probability": 0.30810546875}, {"start": 2314.65, "end": 2314.95, "word": " قلنا", "probability": 0.67041015625}, {"start": 2314.95, "end": 2317.35, "word": " HRO3H2O4", "probability": 0.6719796316964286}, {"start": 2317.35, "end": 2318.29, "word": " مر", "probability": 0.86572265625}, {"start": 2318.29, "end": 2318.97, "word": " علينا", "probability": 0.978759765625}, {"start": 2318.97, "end": 2320.25, "word": " الفيلول", "probability": 0.8077799479166666}], "temperature": 1.0}, {"id": 84, "seek": 234882, "start": 2321.48, "end": 2348.82, "text": "بتعرفوا ال phenol؟ اه لو اتينا و قولنالكم how can you prepare phenol يعني هنا OH starting from بنزين كيف تحضر ال phenol من البنزين؟ الآن أكبر غلط ممكن الواحد يعمله إيش؟ يقول بنزين", "tokens": [3555, 2655, 3615, 28480, 14407, 2423, 7279, 401, 22807, 1975, 3224, 45164, 1975, 31371, 8315, 4032, 12174, 12610, 8315, 23275, 2304, 577, 393, 291, 5940, 7279, 401, 37495, 22653, 34105, 13931, 2891, 490, 44945, 11622, 9957, 9122, 33911, 6055, 5016, 11242, 2288, 2423, 7279, 401, 9154, 29739, 1863, 11622, 9957, 22807, 6024, 48506, 5551, 4117, 26890, 32771, 1211, 9566, 3714, 43020, 2423, 14407, 24401, 7251, 25957, 43761, 11933, 1829, 8592, 22807, 7251, 39648, 44945, 11622, 9957], "avg_logprob": -0.20961850107490243, "compression_ratio": 1.4734042553191489, "no_speech_prob": 0.0, "words": [{"start": 2321.48, "end": 2322.02, "word": "بتعرفوا", "probability": 0.88955078125}, {"start": 2322.02, "end": 2322.16, "word": " ال", "probability": 0.583984375}, {"start": 2322.16, "end": 2323.36, "word": " phenol؟", "probability": 0.725830078125}, {"start": 2323.36, "end": 2323.88, "word": " اه", "probability": 0.756103515625}, {"start": 2323.88, "end": 2324.48, "word": " لو", "probability": 0.70361328125}, {"start": 2324.48, "end": 2325.04, "word": " اتينا", "probability": 0.79296875}, {"start": 2325.04, "end": 2325.2, "word": " و", "probability": 0.9609375}, {"start": 2325.2, "end": 2325.94, "word": " قولنالكم", "probability": 0.732275390625}, {"start": 2325.94, "end": 2326.32, "word": " how", "probability": 0.73095703125}, {"start": 2326.32, "end": 2326.7, "word": " can", "probability": 0.93701171875}, {"start": 2326.7, "end": 2326.94, "word": " you", "probability": 0.9697265625}, {"start": 2326.94, "end": 2327.58, "word": " prepare", "probability": 0.94140625}, {"start": 2327.58, "end": 2328.76, "word": " phenol", "probability": 0.9384765625}, {"start": 2328.76, "end": 2332.56, "word": " يعني", "probability": 0.7353515625}, {"start": 2332.56, "end": 2333.1, "word": " هنا", "probability": 0.7333984375}, {"start": 2333.1, "end": 2334.34, "word": " OH", "probability": 0.428466796875}, {"start": 2334.34, "end": 2335.5, "word": " starting", "probability": 0.8759765625}, {"start": 2335.5, "end": 2336.1, "word": " from", "probability": 0.91357421875}, {"start": 2336.1, "end": 2336.8, "word": " بنزين", "probability": 0.9314778645833334}, {"start": 2336.8, "end": 2340.16, "word": " كيف", "probability": 0.951171875}, {"start": 2340.16, "end": 2340.82, "word": " تحضر", "probability": 0.8409423828125}, {"start": 2340.82, "end": 2341.06, "word": " ال", "probability": 0.84912109375}, {"start": 2341.06, "end": 2341.46, "word": " phenol", "probability": 0.923095703125}, {"start": 2341.46, "end": 2341.66, "word": " من", "probability": 0.9970703125}, {"start": 2341.66, "end": 2343.0, "word": " البنزين؟", "probability": 0.85478515625}, {"start": 2343.0, "end": 2343.98, "word": " الآن", "probability": 0.66943359375}, {"start": 2343.98, "end": 2344.88, "word": " أكبر", "probability": 0.8880208333333334}, {"start": 2344.88, "end": 2345.38, "word": " غلط", "probability": 0.9806315104166666}, {"start": 2345.38, "end": 2345.78, "word": " ممكن", "probability": 0.9833984375}, {"start": 2345.78, "end": 2346.26, "word": " الواحد", "probability": 0.9095052083333334}, {"start": 2346.26, "end": 2346.72, "word": " يعمله", "probability": 0.8880208333333334}, {"start": 2346.72, "end": 2347.52, "word": " إيش؟", "probability": 0.66705322265625}, {"start": 2347.52, "end": 2347.84, "word": " يقول", "probability": 0.984130859375}, {"start": 2347.84, "end": 2348.82, "word": " بنزين", "probability": 0.94140625}], "temperature": 1.0}, {"id": 85, "seek": 238239, "start": 2357.39, "end": 2382.39, "text": "- أزواج إلكترونال ليش؟ لأن هذا السالب لا يهاجم على هذا السالب إذن مش ممكن أقول البنزين .. مش ممكن أقول البنزين فعله مع الـ OH بيعطينا فينول أول ما جالبهم OH على بنزين بتنافر واضح؟ إذن لابد من طريقة تانية", "tokens": [12, 5551, 11622, 2407, 26108, 11933, 23275, 2655, 2288, 11536, 6027, 32239, 8592, 22807, 5296, 33456, 23758, 21136, 6027, 3555, 20193, 7251, 3224, 26108, 2304, 15844, 23758, 21136, 6027, 3555, 11933, 8848, 1863, 37893, 3714, 43020, 5551, 39648, 29739, 1863, 11622, 9957, 4386, 37893, 3714, 43020, 5551, 39648, 29739, 1863, 11622, 9957, 6156, 30241, 3224, 20449, 2423, 39184, 13931, 4724, 1829, 3615, 9566, 1829, 8315, 8978, 1863, 12610, 5551, 12610, 19446, 10874, 6027, 3555, 16095, 13931, 15844, 44945, 11622, 9957, 39894, 8315, 5172, 2288, 4032, 46958, 5016, 22807, 11933, 8848, 1863, 5296, 16758, 3215, 9154, 23032, 16572, 28671, 6055, 7649, 10632], "avg_logprob": -0.20925245317173938, "compression_ratio": 1.841025641025641, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2357.39, "end": 2357.87, "word": "-", "probability": 0.34033203125}, {"start": 2357.87, "end": 2358.55, "word": " أزواج", "probability": 0.8438720703125}, {"start": 2358.55, "end": 2359.41, "word": " إلكترونال", "probability": 0.86767578125}, {"start": 2359.41, "end": 2360.79, "word": " ليش؟", "probability": 0.61767578125}, {"start": 2360.79, "end": 2361.23, "word": " لأن", "probability": 0.888916015625}, {"start": 2361.23, "end": 2361.81, "word": " هذا", "probability": 0.9580078125}, {"start": 2361.81, "end": 2362.63, "word": " السالب", "probability": 0.8203125}, {"start": 2362.63, "end": 2363.31, "word": " لا", "probability": 0.85546875}, {"start": 2363.31, "end": 2364.07, "word": " يهاجم", "probability": 0.9814453125}, {"start": 2364.07, "end": 2364.35, "word": " على", "probability": 0.93603515625}, {"start": 2364.35, "end": 2364.75, "word": " هذا", "probability": 0.9765625}, {"start": 2364.75, "end": 2365.51, "word": " السالب", "probability": 0.9812825520833334}, {"start": 2365.51, "end": 2367.17, "word": " إذن", "probability": 0.59375}, {"start": 2367.17, "end": 2367.53, "word": " مش", "probability": 0.509765625}, {"start": 2367.53, "end": 2367.89, "word": " ممكن", "probability": 0.991455078125}, {"start": 2367.89, "end": 2368.33, "word": " أقول", "probability": 0.908203125}, {"start": 2368.33, "end": 2369.43, "word": " البنزين", "probability": 0.9620361328125}, {"start": 2369.43, "end": 2369.63, "word": " ..", "probability": 0.307373046875}, {"start": 2369.63, "end": 2370.47, "word": " مش", "probability": 0.7421875}, {"start": 2370.47, "end": 2370.77, "word": " ممكن", "probability": 0.994873046875}, {"start": 2370.77, "end": 2371.09, "word": " أقول", "probability": 0.977783203125}, {"start": 2371.09, "end": 2371.63, "word": " البنزين", "probability": 0.9901123046875}, {"start": 2371.63, "end": 2372.03, "word": " فعله", "probability": 0.9391276041666666}, {"start": 2372.03, "end": 2372.19, "word": " مع", "probability": 0.98681640625}, {"start": 2372.19, "end": 2372.35, "word": " الـ", "probability": 0.7342529296875}, {"start": 2372.35, "end": 2372.57, "word": " OH", "probability": 0.59033203125}, {"start": 2372.57, "end": 2373.21, "word": " بيعطينا", "probability": 0.856201171875}, {"start": 2373.21, "end": 2373.65, "word": " فينول", "probability": 0.8587239583333334}, {"start": 2373.65, "end": 2374.13, "word": " أول", "probability": 0.775634765625}, {"start": 2374.13, "end": 2374.29, "word": " ما", "probability": 0.9013671875}, {"start": 2374.29, "end": 2374.69, "word": " جالبهم", "probability": 0.582733154296875}, {"start": 2374.69, "end": 2375.05, "word": " OH", "probability": 0.8037109375}, {"start": 2375.05, "end": 2375.25, "word": " على", "probability": 0.55126953125}, {"start": 2375.25, "end": 2375.65, "word": " بنزين", "probability": 0.96142578125}, {"start": 2375.65, "end": 2376.47, "word": " بتنافر", "probability": 0.69085693359375}, {"start": 2376.47, "end": 2377.97, "word": " واضح؟", "probability": 0.80584716796875}, {"start": 2377.97, "end": 2378.53, "word": " إذن", "probability": 0.8795572916666666}, {"start": 2378.53, "end": 2379.37, "word": " لابد", "probability": 0.9275716145833334}, {"start": 2379.37, "end": 2380.05, "word": " من", "probability": 0.9921875}, {"start": 2380.05, "end": 2380.83, "word": " طريقة", "probability": 0.9894205729166666}, {"start": 2380.83, "end": 2382.39, "word": " تانية", "probability": 0.9871419270833334}], "temperature": 1.0}, {"id": 86, "seek": 240998, "start": 2383.02, "end": 2409.98, "text": "لتحضير الفينول هذه الطريقة التالية لتحضير الفينول بتمشي عبر هذا المسار تمام عبر هذا المسار بيقول بنزين نيترو بنزين أنيلين و بعدين بدي كمان reactions هنا بحط نمرة واحد NKF2 صوديوم نيترايت تمام و نمرة اتنين بحط H2O", "tokens": [1211, 2655, 5016, 11242, 13546, 27188, 9957, 12610, 29538, 41950, 16572, 28671, 16712, 6027, 10632, 5296, 2655, 5016, 11242, 13546, 27188, 9957, 12610, 39894, 2304, 8592, 1829, 6225, 26890, 23758, 9673, 3794, 9640, 46811, 10943, 6225, 26890, 23758, 9673, 3794, 9640, 4724, 1829, 39648, 44945, 11622, 9957, 8717, 36081, 32887, 44945, 11622, 9957, 14739, 26895, 9957, 4032, 39182, 9957, 4724, 16254, 9122, 2304, 7649, 12215, 34105, 4724, 5016, 9566, 8717, 2304, 25720, 36764, 24401, 426, 42, 37, 17, 20328, 2407, 16254, 20498, 8717, 36081, 23557, 36081, 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2688.67, "word": " هي", "probability": 0.9716796875}, {"start": 2688.67, "end": 2689.35, "word": " طريقة", "probability": 0.9783528645833334}, {"start": 2689.35, "end": 2690.39, "word": " إبدال", "probability": 0.6412353515625}, {"start": 2690.39, "end": 2691.01, "word": " على", "probability": 0.90673828125}, {"start": 2691.01, "end": 2691.27, "word": " ال", "probability": 0.90087890625}, {"start": 2691.27, "end": 2692.37, "word": " الكلهيلات،", "probability": 0.4008585611979167}, {"start": 2692.37, "end": 2692.97, "word": " طريقة", "probability": 0.958984375}, {"start": 2692.97, "end": 2693.85, "word": " الإبدال", "probability": 0.76715087890625}, {"start": 2693.85, "end": 2694.17, "word": " على", "probability": 0.91943359375}, {"start": 2694.17, "end": 2694.83, "word": " ال", "probability": 0.98583984375}, {"start": 2694.83, "end": 2696.27, "word": " الكلهيلات،", "probability": 0.9190266927083334}, {"start": 2696.27, "end": 2696.53, "word": " يعني", "probability": 0.954345703125}, {"start": 2696.53, "end": 2697.07, "word": " لاحظوا", "probability": 0.98388671875}, {"start": 2697.07, "end": 2697.33, "word": " هذا", "probability": 0.8037109375}, {"start": 2697.33, "end": 2697.51, "word": " ال", "probability": 0.98779296875}, {"start": 2697.51, "end": 2698.27, "word": " الكلهيلات", "probability": 0.8927734375}, {"start": 2698.27, "end": 2699.49, "word": " وينه؟", "probability": 0.75}, {"start": 2699.49, "end": 2700.09, "word": " المثل", "probability": 0.7862955729166666}, {"start": 2700.09, "end": 2702.21, "word": " أيضاري،", "probability": 0.6206298828125}, {"start": 2702.21, "end": 2702.73, "word": " بجيب", "probability": 0.9327392578125}, {"start": 2702.73, "end": 2703.21, "word": " بداله", "probability": 0.92041015625}, {"start": 2703.21, "end": 2703.85, "word": " الأمين،", "probability": 0.9647216796875}, {"start": 2703.85, "end": 2704.09, "word": " هذه", "probability": 0.62158203125}, {"start": 2704.09, "end": 2705.11, "word": " الأمين،", "probability": 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0.741943359375}, {"start": 2713.69, "end": 2713.83, "word": " ال", "probability": 0.974609375}, {"start": 2713.83, "end": 2714.15, "word": " PR", "probability": 0.82958984375}, {"start": 2714.15, "end": 2715.35, "word": " إيش", "probability": 0.7047526041666666}, {"start": 2715.35, "end": 2715.49, "word": " في", "probability": 0.81201171875}, {"start": 2715.49, "end": 2715.81, "word": " عنده", "probability": 0.64599609375}, {"start": 2715.81, "end": 2716.15, "word": " هنا", "probability": 0.5673828125}, {"start": 2716.15, "end": 2717.45, "word": " ال", "probability": 0.403564453125}, {"start": 2717.45, "end": 2718.03, "word": " unatomobiles", "probability": 0.2953369140625}, {"start": 2718.03, "end": 2718.13, "word": " ال", "probability": 0.339111328125}, {"start": 2718.13, "end": 2718.43, "word": " unatomobiles", "probability": 0.71357421875}, {"start": 2718.43, "end": 2718.79, "word": " خلّى", "probability": 0.58038330078125}, {"start": 2718.79, "end": 2718.97, "word": " الآن", "probability": 0.783203125}, {"start": 2718.97, "end": 2719.45, "word": " نتاجر", "probability": 0.685791015625}, {"start": 2719.45, "end": 2719.91, "word": " تجربة", "probability": 0.517120361328125}, {"start": 2719.91, "end": 2720.07, "word": " ال", "probability": 0.97998046875}, {"start": 2720.07, "end": 2720.47, "word": " PR", "probability": 0.96044921875}, {"start": 2720.47, "end": 2721.61, "word": " و", "probability": 0.67578125}, {"start": 2721.61, "end": 2721.81, "word": " إذا", "probability": 0.552978515625}, {"start": 2721.81, "end": 2722.31, "word": " بتعمل", "probability": 0.9474283854166666}, {"start": 2722.31, "end": 2722.71, "word": " إيش", "probability": 0.86181640625}, {"start": 2722.71, "end": 2724.13, "word": " حلقات", "probability": 0.8182373046875}, {"start": 2724.13, "end": 2725.25, "word": " صار", "probability": 0.892333984375}, {"start": 2725.25, "end": 2725.53, "word": " عندى", "probability": 0.718017578125}, {"start": 2725.53, "end": 2725.99, "word": " مركب", 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21984], "avg_logprob": -0.2529189580089443, "compression_ratio": 1.5625, "no_speech_prob": 5.030632019042969e-05, "words": [{"start": 2739.91, "end": 2740.19, "word": "الـ", "probability": 0.655029296875}, {"start": 2740.19, "end": 2740.45, "word": " PR", "probability": 0.458251953125}, {"start": 2740.45, "end": 2740.83, "word": " أو", "probability": 0.7587890625}, {"start": 2740.83, "end": 2741.07, "word": " الـ", "probability": 0.825439453125}, {"start": 2741.07, "end": 2741.49, "word": " CL", "probability": 0.56884765625}, {"start": 2741.49, "end": 2742.39, "word": " ابتفعوا", "probability": 0.80205078125}, {"start": 2742.39, "end": 2743.09, "word": " الإدالة،", "probability": 0.665185546875}, {"start": 2743.09, "end": 2743.47, "word": " فطرق", "probability": 0.910888671875}, {"start": 2743.47, "end": 2743.91, "word": " تحضير", "probability": 0.9249267578125}, {"start": 2743.91, "end": 2744.91, "word": " الأمين", "probability": 0.8860677083333334}, {"start": 2744.91, "end": 2745.81, "word": " استلخيصا", "probability": 0.7929280598958334}, {"start": 2745.81, "end": 2746.25, "word": " من", "probability": 0.8798828125}, {"start": 2746.25, "end": 2746.45, "word": " الـ", "probability": 0.751220703125}, {"start": 2746.45, "end": 2747.73, "word": " Amides،", "probability": 0.5367838541666666}, {"start": 2747.73, "end": 2747.97, "word": " من", "probability": 0.9580078125}, {"start": 2747.97, "end": 2748.17, "word": " الـ", "probability": 0.9755859375}, {"start": 2748.17, "end": 2749.21, "word": " CL،", "probability": 0.5115966796875}, {"start": 2749.21, "end": 2749.37, "word": " من", "probability": 0.98681640625}, {"start": 2749.37, "end": 2750.01, "word": " الإدالة", "probability": 0.957275390625}, {"start": 2750.01, "end": 2750.37, "word": " محل", "probability": 0.8388671875}, {"start": 2750.37, "end": 2750.55, "word": " الـ", "probability": 0.904541015625}, {"start": 2750.55, "end": 2751.59, "word": " Halogens،", "probability": 0.580810546875}, {"start": 2751.59, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d82554c6651f42c5944c21b82685881bb1b382ce
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_raw.srt
@@ -0,0 +1,1924 @@
+1
+00:00:19,740 --> 00:00:25,800
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في ال
+
+2
+00:00:25,800 --> 00:00:30,360
+dry glycerides و ال fats and oils يمكن لاحقته
+
+3
+00:00:30,360 --> 00:00:36,240
+انتوا شغلة ان فيهم شيء مشترك الشيء المشترك اللي
+
+4
+00:00:36,240 --> 00:00:43,090
+فيهم هو ال glycerol واضح؟الان فيهم بعد هيك أشياء
+
+5
+00:00:43,090 --> 00:00:49,130
+مختلفة، الأشياء المختلفة هي ال fatty acids، يعني
+
+6
+00:00:49,130 --> 00:00:53,450
+احنا اتفقنا ان الـ triglycerides، ال glycerol متصل
+
+7
+00:00:53,450 --> 00:00:58,920
+فيه تلاتة fatty acids عاملين E starsهدولة التلات
+
+8
+00:00:58,920 --> 00:01:03,240
+شغلات بيختلفوا يعني ال glycerol واحد مش فيه خلافة
+
+9
+00:01:03,240 --> 00:01:08,440
+لكن هل يتر هدولة تلات فات أسيتس من نفس النوع بداية
+
+10
+00:01:08,440 --> 00:01:13,460
+بيكون simply triglycerides او مختلفين بيكون mixed
+
+11
+00:01:13,460 --> 00:01:14,540
+triglycerides
+
+12
+00:01:17,790 --> 00:01:22,530
+ايش الاحتمالات انهم يكونوا موجودين saturated كلهم
+
+13
+00:01:22,530 --> 00:01:27,870
+ولا unsaturated ولا بنسب مختلفة الان هذا الاختلاف
+
+14
+00:01:27,870 --> 00:01:33,390
+في التلاتة fatty acids اللي موجودين هو اللي بسبب
+
+15
+00:01:33,390 --> 00:01:38,210
+اختلاف بين انه المركب نفسه او المادة نفسها تكون
+
+16
+00:01:38,210 --> 00:01:44,110
+fat يعني بحالة صلبة او تكون oil وحتى لما تكون oil
+
+17
+00:01:44,110 --> 00:01:50,030
+ما بين زيت وزيتأو ما بين fat و fat أيضا في ايش
+
+18
+00:01:50,030 --> 00:01:54,930
+عندنا؟ في اختلاف هذا الاختلاف مرده لإيش؟ مرده
+
+19
+00:01:54,930 --> 00:01:59,790
+لاختلاف أنواع و نسب ال fatty acids اللي موجودين
+
+20
+00:01:59,790 --> 00:02:05,790
+يعني مثلا بشكل عام بنقدر نقول ان الزيوت تحتوي على
+
+21
+00:02:05,790 --> 00:02:10,270
+نسبة أكثر من ال saturated ولا ال unsaturated fatty
+
+22
+00:02:10,270 --> 00:02:14,130
+acidsالـ Unsaturated و هم اللي بيخلوها Liquid و
+
+23
+00:02:14,130 --> 00:02:18,310
+عشان هيك لو بدنا نتطلع مثلا على ال olive oil على
+
+24
+00:02:18,310 --> 00:02:23,930
+زيت الزتون هلاحظ انه في من ال unsaturated acids 83
+
+25
+00:02:23,930 --> 00:02:29,710
+من ال oleic acid اللي في double bond واحدة 83% و 7
+
+26
+00:02:29,710 --> 00:02:33,950
+% من ال linoleic acid اللي فيه تنتين double bonds
+
+27
+00:02:33,950 --> 00:02:40,390
+بمعنى مجموع ال unsaturated في زيت الزتون كدهش 90%
+
+28
+00:02:41,360 --> 00:02:46,620
+إذا معظم الزيت المجموع اللي فيه جديش 90% لو طلعنا
+
+29
+00:02:46,620 --> 00:02:53,220
+على زيت النخل بنلاحظ النسبة 51% على زيت الدرة 80%
+
+30
+00:02:53,220 --> 00:03:02,280
+هنا زيت ال peanut اللي هي الصوية 85% يعني الزيوتي
+
+31
+00:03:02,280 --> 00:03:05,960
+بشكل عام بنقدر نقوله هذه الجملة اللي بنضال
+
+32
+00:03:05,960 --> 00:03:10,150
+متذاكرينها بيكون فيها higherpercentage of
+
+33
+00:03:10,150 --> 00:03:14,430
+saturated ولا unsaturated .. unsaturated fatty
+
+34
+00:03:14,430 --> 00:03:20,090
+acids الآن بالنسبة للأشياء التانية اللي بتصير fat
+
+35
+00:03:20,090 --> 00:03:24,110
+يعني نوعا ما صلب يعني على سبيل المثال الزبدة لو
+
+36
+00:03:24,110 --> 00:03:27,010
+بنتطلع على الزبدة قداش فيها unsaturated fatty
+
+37
+00:03:27,010 --> 00:03:31,110
+acids من اللي وليك و اللي نوليك ستة و عشرين و
+
+38
+00:03:31,110 --> 00:03:39,300
+اتنين28 بينما معظمها مخلوط فيها عدة أنواع من ال
+
+39
+00:03:39,300 --> 00:03:45,300
+saturated fatty acids سواء كانت اللي هي ال C10 اقل
+
+40
+00:03:45,300 --> 00:03:50,480
+من C10 .. C12 اللورك، الميرستك، البلمتك، الاستيرك،
+
+41
+00:03:50,480 --> 00:03:57,220
+كلهم موجودين إيش؟كنسب من الـ saturated fatty acids
+
+42
+00:03:57,220 --> 00:04:02,120
+فبشكل عام احنا بيقول ان ال fats بيكون فيهم ال
+
+43
+00:04:02,120 --> 00:04:08,060
+higher percentage من ال ايش؟ ال higher من ال
+
+44
+00:04:08,060 --> 00:04:13,810
+saturated fatty acidsمن ال unsaturated لكن ما بين
+
+45
+00:04:13,810 --> 00:04:17,130
+زيت و زيت ليش بيختلفوا الزيوت في الطعم يعني مش كل
+
+46
+00:04:17,130 --> 00:04:21,150
+الزيت واحد و مش كل الفات واحد لما نيجي نقول والله
+
+47
+00:04:21,150 --> 00:04:27,990
+زيت الزتون ولا زيت الصوية على سبيل المثالبختلفه كل
+
+48
+00:04:27,990 --> 00:04:32,490
+واحد فيه نسبة معينة بتعطي طعم معين ولذلك بشكل عام
+
+49
+00:04:32,490 --> 00:04:36,630
+احنا متعودين اكتر ان زيت الزيتون نستعمله باستعمال
+
+50
+00:04:36,630 --> 00:04:41,710
+معين زيت الصيام يمكن للجالي باستعمال تاني هذا فقط
+
+51
+00:04:41,710 --> 00:04:47,930
+على اختلاف نسبة ايش ال fatty acids وانواعهم واضح
+
+52
+00:04:47,930 --> 00:04:51,670
+الفكرة هذا اللي بيميز الزيوت و الدون عن بعض نسب ال
+
+53
+00:04:51,670 --> 00:04:59,210
+fatty acids وانواعها الآنمن سواء قلنا الدهون او
+
+54
+00:04:59,210 --> 00:05:04,550
+الزيوت بنعمل احنا ايش تفاعل بنسميه soapification
+
+55
+00:05:04,550 --> 00:05:09,130
+تفاعل تحلل لها وهو التفاعل اللي من خلاله بنحضر
+
+56
+00:05:09,130 --> 00:05:12,850
+احنا الصابون اللي احنا عارفين يعني عادة الصابون
+
+57
+00:05:12,850 --> 00:05:18,270
+تحضيرها الصابون العادي البلدي من زيت الزتون انه
+
+58
+00:05:18,270 --> 00:05:23,130
+انا باخد ال triglycerides مثلاTriglyceride معين اي
+
+59
+00:05:23,130 --> 00:05:26,650
+زيت زتون انا ماخد زيت عادي من زيت النخل على سبيل
+
+60
+00:05:26,650 --> 00:05:31,150
+المثال وبعد هيك بالفعل مع ال sodium hydroxide
+
+61
+00:05:31,150 --> 00:05:37,730
+بيصيرله تحلل بناخد جزء لجليسرين وجزء لجليسرين خلاص
+
+62
+00:05:37,730 --> 00:05:41,590
+مابناشي يا ابن فصله الان الجزء التاني بيصير على
+
+63
+00:05:41,590 --> 00:05:47,380
+شكل حامضتلات أحماض و الحامض في وجود ال sodium
+
+64
+00:05:47,380 --> 00:05:52,340
+hydroxide هيكون على شكل إيش؟ الملح تبعه، الأن لما
+
+65
+00:05:52,340 --> 00:05:56,940
+صار الحامض على شكل الملح، هذا ملح الحامض هو
+
+66
+00:05:56,940 --> 00:06:03,200
+الصابون يعني اللبنانيش يقولكم إيش ببساطة الصابون؟
+
+67
+00:06:03,200 --> 00:06:11,290
+الجواب بيكون salt إيش هو ال salt؟ Saltملح يعني
+
+68
+00:06:11,290 --> 00:06:15,430
+طرفه C double bond O O minus نفترض مع ال A plus
+
+69
+00:06:15,430 --> 00:06:22,650
+Salt of fatty acid هو ملح الفاتي أسد Salt of fatty
+
+70
+00:06:22,650 --> 00:06:26,570
+acid بنحضره من خلال إن انفاع الزيوت أو الدهون ل
+
+71
+00:06:26,570 --> 00:06:30,790
+Triglycerides مع Sodium hydroxide طبعا هتلاحظوا
+
+72
+00:06:30,790 --> 00:06:36,790
+انتوا ان هذا الصابون بيمتاز بإيش بيمتاز بوجود طرف
+
+73
+00:06:37,690 --> 00:06:43,630
+ننقل إلى السلسلة يعني هذا مثلا من ال بالميتك أسد
+
+74
+00:06:43,630 --> 00:06:48,630
+يعني ستة عشر كاربون وعشانك بيسموه سوديوم بالميتيت
+
+75
+00:06:48,630 --> 00:06:53,050
+زي اللي من الاسيتك أسد كنا نسميه سوديوم أسيتيت
+
+76
+00:06:53,050 --> 00:06:57,310
+الآن هاي عندي ستة عشر كاربون هذه السلسلة اللي هي
+
+77
+00:06:57,310 --> 00:07:04,970
+الالفتك وعلى طرفها C double bond O O minusالان صار
+
+78
+00:07:04,970 --> 00:07:08,390
+الصابوني مكون من شغلتين polar part
+
+79
+00:07:13,350 --> 00:07:17,870
+واضح؟ طبعا ال non-polar part في الصابون هو جزء
+
+80
+00:07:17,870 --> 00:07:23,890
+كبير ولذلك الصابون يستخدم لغسل ايش؟ الدهون لأن
+
+81
+00:07:23,890 --> 00:07:28,190
+الدهون non-polar و هذا الجزء non-polar فالدهون لما
+
+82
+00:07:28,190 --> 00:07:32,650
+احنا بنغسل الأيدان بالصابون بتدوب في أي جزء في ال
+
+83
+00:07:32,650 --> 00:07:38,310
+non-polar يعني هذا الجزء بيصير ادوب الدهونواضح؟
+
+84
+00:07:38,310 --> 00:07:42,070
+هذا الجزء الـ non-polar هو اللي بدوّب الدهون عن
+
+85
+00:07:42,070 --> 00:07:45,790
+إيد الإنسان لما بيعمل الغسل باستعمال .. إيش؟
+
+86
+00:07:45,790 --> 00:07:53,090
+الصابون، الآن لاحظوا معنى، الزيوت غالية وإلى
+
+87
+00:07:53,090 --> 00:07:57,940
+استعمالات لازمة للناس في الأكل وغيره وغيراتهمظبوط
+
+88
+00:07:57,940 --> 00:08:02,840
+ولا لأ؟ يعني مثلا زيت الزتون اليوم صار غالي جدا
+
+89
+00:08:02,840 --> 00:08:06,600
+زمان يمكن كان متوفر والناس جلال وبالتالي كانوا
+
+90
+00:08:06,600 --> 00:08:10,760
+ياخدوا زيت زتون ويعملوا صابونة اليوم لو بدنا نلاحق
+
+91
+00:08:10,760 --> 00:08:14,860
+عن ناس صابون كل زيت الزتون ماحدش هيكله كله هنحاوله
+
+92
+00:08:14,860 --> 00:08:19,860
+لإيش؟ لصابون ولذلك بدأت الفكرة انه لأ ليش ما نعمل
+
+93
+00:08:19,860 --> 00:08:26,020
+احنا صابونصناعي من غير زيت الزتون الآن اللي بيعمل
+
+94
+00:08:26,020 --> 00:08:29,840
+صابون صناعي بيقول ما هي الفكرة العامة للصابون
+
+95
+00:08:29,840 --> 00:08:36,960
+الفكرة العامة للصابون polar مع non polar تمام؟
+
+96
+00:08:36,960 --> 00:08:42,140
+جيبهم من أي جهة كانت في الدنيا بتطلع شبيه الصابون
+
+97
+00:08:42,140 --> 00:08:47,100
+ليش؟ لأن ال non polar هيدوب الدهون اللي هي non
+
+98
+00:08:47,100 --> 00:08:52,630
+polar وبناء على ذلك صار عندناالاشياء اللي بنسميها
+
+99
+00:08:52,630 --> 00:08:55,970
+احنا ال synthetic detergents يعني المنظفات
+
+100
+00:08:55,970 --> 00:09:02,850
+الصناعية او Sidnets لاحظوا كيف انطلقوا بالفكرة هم
+
+101
+00:09:02,850 --> 00:09:06,790
+جالوا هاي الصابون مثلا من الاستيرك اسد عندي لزوم
+
+102
+00:09:06,790 --> 00:09:11,690
+Sodium Sterate لو قلالكم اي سؤال في الامتحان
+
+103
+00:09:11,690 --> 00:09:18,290
+Sodium Sterate او Sodium Palmitateهو سلطة استيريت
+
+104
+00:09:18,290 --> 00:09:25,010
+بلمتات ميرستات كل هذه صوابين الآن فيها جزء بولا
+
+105
+00:09:25,010 --> 00:09:34,010
+وجزء نان بولالكن هذا مأخوذ من الزيت الزتون، الآن
+
+106
+00:09:34,010 --> 00:09:38,890
+كيميائيا قالوا خلينا نجيب جزء non-polar من الكيميا
+
+107
+00:09:38,890 --> 00:09:42,410
+من عندنا، جابوا سلسلة طويلة وكمان فيها حلقة بنزين،
+
+108
+00:09:42,410 --> 00:09:46,350
+في كل الأحوال هذه السلسلة إيش مالها؟ non-polar،
+
+109
+00:09:46,350 --> 00:09:51,800
+وشبكوا معها شيء ما polarمرة تانية مرة تالتة لاحظوا
+
+110
+00:09:51,800 --> 00:09:57,020
+معي كلمة بولر أهم شيء يكون لها قطب الان ان القطب
+
+111
+00:09:57,020 --> 00:10:01,580
+يكون موجب او سالب او حتى شيء قطبي مافيش فيه موجب
+
+112
+00:10:01,580 --> 00:10:06,300
+او سالب بس زي OH بيمشي ولذلك في الصوابين الصناعية
+
+113
+00:10:06,300 --> 00:10:10,080
+هتلاحظوا ان هذا الجزء مثلا ممكن يكون S double bond
+
+114
+00:10:10,080 --> 00:10:14,830
+O double bond O O minusسالب عشان هيك بنقول عن هذا
+
+115
+00:10:14,830 --> 00:10:20,650
+الصابون anionic detergent لأن ال ion هنا سالب ممكن
+
+116
+00:10:20,650 --> 00:10:26,590
+نحطه موجب السالب قطب والموجب قطب يعني مش إلزام أن
+
+117
+00:10:26,590 --> 00:10:31,590
+القطب يكون سالب ولذلك لو حطينا ammonium salt هنا
+
+118
+00:10:31,590 --> 00:10:37,690
+هذا موجب الموجب برضه قطب أو شي قطبة ممكن نحطه شي
+
+119
+00:10:37,690 --> 00:10:43,370
+متعادل لكن فيه مجموعة قطبية زي ال OHفبصير عندى
+
+120
+00:10:43,370 --> 00:10:49,110
+ايش؟ non-ionic فالجزء البولر مش الزام انه يكون
+
+121
+00:10:49,110 --> 00:10:54,950
+سالب لأ ممكن يكون سالب بنقول عنه المنظفات anionic
+
+122
+00:10:54,950 --> 00:10:58,730
+detergents ممكن يكون موجب بنقول عنها cationic
+
+123
+00:10:58,730 --> 00:11:03,370
+detergents وممكن يكون لا موجب ولا سالب يعني متعادل
+
+124
+00:11:03,370 --> 00:11:08,090
+نيوترال او non-ionic detergents و هذه السلاسل
+
+125
+00:11:08,090 --> 00:11:13,260
+بنحطها من عندنا في الكيمياالكيميا فيها مركبات و
+
+126
+00:11:13,260 --> 00:11:17,900
+تحضيرات سلسلة كل هذا بتصير عبارة عن ايش؟ Synthetic
+
+127
+00:11:17,900 --> 00:11:22,060
+detergents أخذت من الصبون فكرته الأساسية اللي هي
+
+128
+00:11:22,060 --> 00:11:27,280
+بولر و نانبولر وغيرت شو هو البولر وغيرت شو هو ال
+
+129
+00:11:27,280 --> 00:11:31,620
+نانبولر كمان يعني لاحظوا هنا البولر متغير و ال
+
+130
+00:11:31,620 --> 00:11:38,500
+نانبولر متغير لكن الفكرة العامة بولر مع نانبولر ما
+
+131
+00:11:38,500 --> 00:11:39,760
+زالت موجودة
+
+132
+00:11:42,300 --> 00:11:47,360
+الان ابهيك بنكون خلصنا الـ triglycerides الـ
+
+133
+00:11:47,360 --> 00:11:53,000
+triglycerides الحقيقة مشتق منهم ال phospholipids
+
+134
+00:11:53,000 --> 00:11:58,420
+واضح؟ ال triglycerides مشتق منهم ال phospholipids
+
+135
+00:11:58,420 --> 00:12:02,260
+لو انا بنفس المنطق اللي تو اتكلمت فيه عن ال
+
+136
+00:12:02,260 --> 00:12:05,660
+triglycerides بدي اقول شومة ال triglycerides عشان
+
+137
+00:12:05,660 --> 00:12:10,700
+انتقل منهم لل phospholipids كان عندى إجليسرولو
+
+138
+00:12:10,700 --> 00:12:17,140
+fatty acid أول و fatty acid تاني و fatty acid تالت
+
+139
+00:12:17,140 --> 00:12:22,810
+مظبوط ولا لأ؟ الآن ال phospholipids بنحافظ فيهمعلى
+
+140
+00:12:22,810 --> 00:12:27,350
+ال aglycerol وعلى اتنين من ال fatty acids هدول
+
+141
+00:12:27,350 --> 00:12:31,790
+بيخليهم زي ما هم معناه تالت fatty acid بنشيله بنحط
+
+142
+00:12:31,790 --> 00:12:36,590
+عليه مجموعة فوسفات مع مجموعة ماء صغيرة معروفة
+
+143
+00:12:36,590 --> 00:12:40,510
+بالكيميا بيصير اسمه ايش؟ phospholipid لأنه هنا اجى
+
+144
+00:12:40,510 --> 00:12:46,320
+عندىمجموعة ال .. ال .. ال .. ال .. PO4 فالشئ
+
+145
+00:12:46,320 --> 00:12:50,540
+المشترك ما بين ال triglycerides و ال phospholipids
+
+146
+00:12:50,540 --> 00:12:56,690
+هو ال glycerolو اتنين من ال fatty acids واحد من ال
+
+147
+00:12:56,690 --> 00:13:03,110
+fatty acids بيحولوا الى مجموعة فوسفات مع جزيق صغير
+
+148
+00:13:03,110 --> 00:13:09,650
+طبعا بشكل عام غير ال glycerol يعني هل كل ال lipids
+
+149
+00:13:09,650 --> 00:13:15,090
+مبنية على glycerol اللي هو التلاتة carbon يعني هذا
+
+150
+00:13:15,090 --> 00:13:23,060
+ال glycerol كام carbon؟تلاتة CH2 CH CH2 و بستكمل
+
+151
+00:13:23,060 --> 00:13:27,360
+من هنا ال limits هدولة اللي مبنيين على ال glycerol
+
+152
+00:13:27,360 --> 00:13:34,420
+بنسميهم احنا ايش ال tri glycerides الان في عنبنوع
+
+153
+00:13:34,420 --> 00:13:38,880
+تاني من ال limits يمكن ما جيبناش سيرته مبني على
+
+154
+00:13:38,880 --> 00:13:44,220
+اربع ذرات كربون بنسميه ايش sphingothenes
+
+155
+00:13:45,050 --> 00:13:49,150
+السفينجوسينز بدل الجليسيرين بحب انا شبه في
+
+156
+00:13:49,150 --> 00:13:55,930
+الجليسيرين بالمناسبة CH2OH بعدين CHNH2 بعدين CHOH
+
+157
+00:13:55,930 --> 00:13:59,530
+بعدين CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+158
+00:13:59,530 --> 00:14:00,270
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+159
+00:14:00,270 --> 00:14:01,230
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+160
+00:14:01,230 --> 00:14:02,590
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+161
+00:14:02,590 --> 00:14:05,810
+CH CH CH CH CH CH CH
+
+162
+00:14:05,810 --> 00:14:05,810
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+163
+00:14:05,810 --> 00:14:05,810
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+164
+00:14:05,810 --> 00:14:07,610
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+165
+00:14:07,610 --> 00:14:09,590
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+166
+00:14:09,590 --> 00:14:09,590
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+167
+00:14:09,590 --> 00:14:12,710
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+168
+00:14:12,710 --> 00:14:20,690
+CH CH CHتلاتة O H's هنا صار عندى تنتين O H's و
+
+169
+00:14:20,690 --> 00:14:26,850
+واحدة N H2 بناء على ذلك ال O H's بيعملوا إيش؟ E
+
+170
+00:14:26,850 --> 00:14:33,290
+star و ال N H2 بيعملوا أمد فالسفينجوسين موجود في E
+
+171
+00:14:33,290 --> 00:14:38,190
+stars و أمد يعني اتنين E stars و واحد أمد بينما
+
+172
+00:14:38,190 --> 00:14:43,930
+للـ triglycerides في تلاتة E starsهذا نوع من الـ
+
+173
+00:14:43,930 --> 00:14:49,730
+lipids و هذا نوع من الـ triglycerides في كل
+
+174
+00:14:49,730 --> 00:14:54,230
+الأحوال سواء كان البناء الأساسي اللي أنا مبني عندي
+
+175
+00:14:54,230 --> 00:15:00,930
+على غليسرول بثلاث أواتش أو على الاسفينجوسين بتنتين
+
+176
+00:15:00,930 --> 00:15:08,310
+أواتش واحدة مجموعة الفاتككل هدولة لو اجينا شبكنا
+
+177
+00:15:08,310 --> 00:15:12,050
+مع واحدة منهم مجموعة ال phosphoric acid او
+
+178
+00:15:12,050 --> 00:15:16,270
+الفوسفات و جزء صغير زي ال ethanol امين او زي
+
+179
+00:15:16,270 --> 00:15:20,530
+الكولين هيدروكسايد بيصير عند ال ايش ال
+
+180
+00:15:20,530 --> 00:15:25,850
+phospholipids و بناء على ذلك لو احنا بنشوف منظر ال
+
+181
+00:15:25,850 --> 00:15:30,480
+phospholipidsهتلاحظوا بالشكل القاتل هي
+
+182
+00:15:30,480 --> 00:15:35,160
+phospholipids من ال glycerol CH2O C double bond O
+
+183
+00:15:35,160 --> 00:15:38,780
+هذا الجزء زي ما هو زي ما هو في ال tri glycerides E
+
+184
+00:15:38,780 --> 00:15:45,660
+star وكمان CO O C double bond O whatever هذا نفسه
+
+185
+00:15:45,660 --> 00:15:49,020
+fatty acid على الموقع التالت ايش حطينا
+
+186
+00:16:02,680 --> 00:16:04,080
+وبووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو
+
+187
+00:16:19,850 --> 00:16:23,830
+اللي هو ال phospholipids وبناء على ذلك مرات لما
+
+188
+00:16:23,830 --> 00:16:27,070
+بييجوا بيختصروا ال phospholipids طبعا هنا مجموعة
+
+189
+00:16:27,070 --> 00:16:32,090
+الفوسفات مع هذا الجزء بيعملوا طرف منفصل طرف بولر
+
+190
+00:16:32,090 --> 00:16:36,130
+عشانك مرات لما بيختصروا ال phospholipids بيروحوا
+
+191
+00:16:36,130 --> 00:16:40,530
+بيعملوا هيك سلسلتين هدول السلسلتين بيقصروا فيهم
+
+192
+00:16:40,530 --> 00:16:46,070
+الاتنين fatty acids اللي ضالهم إيش موجودينمش احنا
+
+193
+00:16:46,070 --> 00:16:51,090
+قولنا في تلاتة fatty acids اتنين ضالوا موجودين و
+
+194
+00:16:51,090 --> 00:16:55,750
+التالت صار phosphate بعلمه بإيش؟ أو ionic بكرة
+
+195
+00:16:55,750 --> 00:17:02,070
+زرقاء أو برأس أزرق فهي التلاتة fatty acid و الأزرق
+
+196
+00:17:02,070 --> 00:17:07,100
+هذا إيش؟ phosphate فبصير هذا المنظر العاميعني يمثل
+
+197
+00:17:07,100 --> 00:17:11,600
+اختصار للإيش؟ لل phospholipid الآن لاحظوا هذا
+
+198
+00:17:11,600 --> 00:17:16,760
+الجزء مرة تانية polar هذا الجزء non polar فصار
+
+199
+00:17:16,760 --> 00:17:22,860
+كأنه ال phospholipid polar و non polarواضح؟ هذه
+
+200
+00:17:22,860 --> 00:17:27,500
+الصفات انه يكون polar و non-polar ع طول بتدخل في
+
+201
+00:17:27,500 --> 00:17:32,000
+إيش؟ في الوظيفة تبعته يعني ال phospholipid بشكل
+
+202
+00:17:32,000 --> 00:17:36,820
+أساسي زي ما انتوا شايفين في ال slide السابقة بشكل
+
+203
+00:17:36,820 --> 00:17:42,900
+جداش؟ 40% من ال cell membrane يعني الجدار ..
+
+204
+00:17:42,900 --> 00:17:47,620
+الجدار تبع الخلية بنسبة كبيرة منه بيكون عبارة عن
+
+205
+00:17:47,620 --> 00:17:52,270
+إيش؟phospholipids وعرفنا الـ phospholipids الآن
+
+206
+00:17:52,270 --> 00:17:58,310
+حسب ترتيب الـ phospholipids بهذا الشكل لو وضعناهم
+
+207
+00:17:58,310 --> 00:18:04,850
+او لو لفناهم على شكل زي كرة بيسموها ليبوزوم لاحظوا
+
+208
+00:18:04,850 --> 00:18:09,290
+بيكون في عندى جزء بولر الجزء البولر بتلتصق فيه ايش
+
+209
+00:18:09,290 --> 00:18:14,570
+الميه اكيواس بيكون و هذا الجزء الخارجي بولر برضه
+
+210
+00:18:14,570 --> 00:18:19,110
+اكيواس فصار عندى هنا اكيواس interiorو aqueous
+
+211
+00:18:19,110 --> 00:18:23,390
+exterior aqueous interior و aqueous exterior ليش؟
+
+212
+00:18:23,390 --> 00:18:27,230
+لأن هذا الجزء هو الجزء ال إيش ال polar الجزء ال
+
+213
+00:18:27,230 --> 00:18:30,910
+non polar وين موجود؟ في النص، هذي بيسموها
+
+214
+00:18:30,910 --> 00:18:35,130
+liposomes بتعني يمكن هي ك aggregates aggregate
+
+215
+00:18:35,130 --> 00:18:41,100
+يعني تجمع مرت معاكوا في ال biology أوىفي الأحياء
+
+216
+00:18:41,100 --> 00:18:45,680
+بيمور معاكم أكتر هذا الكلام يعني فقط في منطقة
+
+217
+00:18:45,680 --> 00:18:50,880
+الكيميا بهمنا أننا نعرفكوا الشكل الكيميائي لكن بعد
+
+218
+00:18:50,880 --> 00:18:54,940
+هيك إيش وظيفته وكيف بيدخل في الخلية وكيف بيساعد
+
+219
+00:18:54,940 --> 00:18:58,760
+فيها كل هذا منطقة Biology يعني لما بنجرب على ال
+
+220
+00:18:58,760 --> 00:19:04,150
+biochemistry بشكل عام بنعطيكوا إيش؟الشكل الكيميائي
+
+221
+00:19:04,150 --> 00:19:07,270
+ان نكون فاهمين بالظبط ايش ال phospholipids الان
+
+222
+00:19:07,270 --> 00:19:09,990
+افهمنا انه في اتنين fatty acids دلوا زي ما هم
+
+223
+00:19:09,990 --> 00:19:14,030
+مجموعة phosphate مع كذا صار في جزء polar جزء non
+
+224
+00:19:14,030 --> 00:19:17,530
+polar ما إلى ذلك الان بعد ذلك لما تروحوا على ال
+
+225
+00:19:17,530 --> 00:19:20,930
+biology ينحكوا قدامكوا phospholipids ويبدوا
+
+226
+00:19:20,930 --> 00:19:29,370
+يعطوكوا تفاصيل اكثر you have an idea واضح غير
+
+227
+00:19:29,370 --> 00:19:34,760
+ال phospholipidsالـ waxes احنا بتيالي حكينا عنها
+
+228
+00:19:34,760 --> 00:19:40,500
+قولنا E stars فيها aliphatic chain طويل يمين و
+
+229
+00:19:40,500 --> 00:19:44,260
+شمال وهذه ال aliphatic chain هي اللي بتتفاعل مع ال
+
+230
+00:19:44,260 --> 00:19:50,360
+oxygen بتعطيني CO2 زائد H2O زائد ال heat أو ال
+
+231
+00:19:50,360 --> 00:19:54,060
+light الحرارة اللي احنا بنشوفها وعشانك بنحرق الشمع
+
+232
+00:19:54,060 --> 00:20:01,450
+فاحنا لما نحرق الشمع بنحرق حقيقةالسلاسل الألفاتية
+
+233
+00:20:01,450 --> 00:20:07,590
+اللي موجودة على طرفي هذا ال Easter اتكلمنا عن ال
+
+234
+00:20:07,590 --> 00:20:14,830
+waxes مافيش فيه فكرة اكتر بنجي لنوع تاني من ال
+
+235
+00:20:14,830 --> 00:20:18,810
+lipids اللي هم ال terbenes و من ال terbenes هنكتشف
+
+236
+00:20:18,810 --> 00:20:26,150
+انه مشتقة بعدين ل ال steroidsال تيربينز يمكن أكبر
+
+237
+00:20:26,150 --> 00:20:30,590
+عائلة في ال natural products الطبيعية بتطلعها
+
+238
+00:20:30,590 --> 00:20:35,570
+النباتات وغيرها وغيراتها، هذه العائلة بتمتاز إنها
+
+239
+00:20:35,570 --> 00:20:40,250
+مكونة من وحدة أساسية، هذه الوحدة الأساسية هي ال
+
+240
+00:20:40,250 --> 00:20:44,930
+isopentaneالأيزو بنتين الان هنا بيسموها ايزو brain
+
+241
+00:20:44,930 --> 00:20:48,850
+unit فالأيزو brain unit هي الأيزو بنتين، لاحظوا،
+
+242
+00:20:48,850 --> 00:20:52,950
+واحد، اتنين، تلاتة، بهذا الشكل، قولنا هذه ايزو،
+
+243
+00:20:52,950 --> 00:20:57,710
+العدد الكل، أربعة، خمسة، ايزو، بنتين، لو كانت بس
+
+244
+00:20:57,710 --> 00:21:00,670
+تلاتة، شابكا، من هنا، كنا نقول ايزو بروبين، مع
+
+245
+00:21:00,670 --> 00:21:05,650
+أربع ايزو بنتين، بيوتين، ايزو بنتين، ايزو هكسين،
+
+246
+00:21:05,650 --> 00:21:11,590
+هذه الوحدة الـبنتين او ال isoprene unit من اليوم
+
+247
+00:21:11,590 --> 00:21:17,050
+الطالع بنسميها بتتجمع مع بعضها بتعمل جزيئات
+
+248
+00:21:17,050 --> 00:21:20,770
+بنسميها ايش ال turbines فهتلاحظوا القاعدة مباشرة
+
+249
+00:21:20,770 --> 00:21:25,050
+ان ال turbines هتكون مضاعفات عددها لكل مضاعفات ال
+
+250
+00:21:25,050 --> 00:21:30,970
+ايش الخامسة يعني ممكن يجتمعوا جزيئين من ال
+
+251
+00:21:30,970 --> 00:21:34,590
+isoprene unit يعني خمسة و خمسة لما بيجتمع two
+
+252
+00:21:34,590 --> 00:21:40,520
+isoprene units هيصير عندى كام carbonعشرة تمام هذا
+
+253
+00:21:40,520 --> 00:21:47,200
+اللي فيه اجتماع جزيئين من ال isoprene units بنسميه
+
+254
+00:21:47,200 --> 00:21:51,440
+mono turbine ممكن يجتمعوا تلت جزيئات بيصير المجموع
+
+255
+00:21:51,440 --> 00:21:55,960
+الكل خمستاشر بنسميه cis-q turbines ممكن يجتمعوا
+
+256
+00:21:55,960 --> 00:22:01,740
+اربع جزيئات بنسميه di turbines اربعة في خمسةعشرين
+
+257
+00:22:01,740 --> 00:22:05,680
+خمس جزيات خمسة بخمسة خمسة وعشرين sister turbines
+
+258
+00:22:05,680 --> 00:22:10,160
+ممكن يجتمعوا ست جزيات بنسميها tri turbines ممكن
+
+259
+00:22:10,160 --> 00:22:16,680
+تمان جزيات tetra turbines فلاحظوا دائما لما تشوفوا
+
+260
+00:22:16,680 --> 00:22:20,520
+هنا تمانية onygenous alcohol isobarine units هذا
+
+261
+00:22:20,520 --> 00:22:23,920
+أي نوع من ال turbines ايه اسمه على اتنين التمانية
+
+262
+00:22:23,920 --> 00:22:27,940
+tetra turbines الستة tri turbines الأربعة
+
+263
+00:22:30,300 --> 00:22:37,060
+مونو تربين و بيكونوا هدولة جزيئات مختلفة لاحظوا
+
+264
+00:22:37,060 --> 00:22:41,880
+مثلا هاي جزيئ انتوا بتطلع عليه كأنه جزيئ عادي لكن
+
+265
+00:22:41,880 --> 00:22:52,320
+لو احنا اتينا اتطلعنا و قسمنا بهذا الشكل هذا
+
+266
+00:22:52,320 --> 00:22:56,780
+الجزيئ من عشر كربونات عدوا الآن من هنا هاي وحدة ال
+
+267
+00:22:56,780 --> 00:23:02,700
+ISOطلعوا هاي carbon اتنين تلاتة هاذي ال ISO ولا لأ
+
+268
+00:23:02,700 --> 00:23:11,000
+اربعة خمسة هاي الخمس درات هاي isoprene unit ونش
+
+269
+00:23:11,000 --> 00:23:16,240
+نطلع كمان مرة هاي واحد اتنين تلاتة هاي ال ISO
+
+270
+00:23:16,240 --> 00:23:19,640
+اربعة خمسة
+
+271
+00:23:21,670 --> 00:23:25,150
+هي isoprene unit و isoprene unit طبعاً لما بتحدوا
+
+272
+00:23:25,150 --> 00:23:29,190
+بيزيد عليهم مجموعات بيعملوا روابط ثنائية غيره لكن
+
+273
+00:23:29,190 --> 00:23:34,570
+العدد الكلي لل carbons عشرة، خمسة في اتنين، اذا
+
+274
+00:23:34,570 --> 00:23:39,830
+هذا اي نوع من التربين، mono-terbine، إله اسم طبعاً
+
+275
+00:23:40,860 --> 00:23:45,120
+هذا نفس الفكرة لو إجينا نقسمه من هنا أحيانا
+
+276
+00:23:45,120 --> 00:23:49,820
+المركبات زي هذه بتبين يعني مابخترش على بالك أن هي
+
+277
+00:23:49,820 --> 00:23:56,060
+فعلا مكونة من الخمستين لكن لو إحنا إجينا أخدناها
+
+278
+00:23:56,060 --> 00:24:05,940
+بهذا الشكل واضح؟ خلينا نتطلع هاي واحد اتنين تلاتة
+
+279
+00:24:05,940 --> 00:24:12,720
+هي ال ISO أربعةخمسة هذي isoprene unit ولا لأ اه لو
+
+280
+00:24:12,720 --> 00:24:20,420
+اتينا واطلعنا منها واحد اتنين تلاتة اربعة خمسة
+
+281
+00:24:20,420 --> 00:24:26,060
+isoprene unit ولا لأ واضح و بيصير مركبات ماخدة
+
+282
+00:24:26,060 --> 00:24:29,860
+اسماء كتيرة في الدنيا الآن افهمنا ايش معنى
+
+283
+00:24:29,860 --> 00:24:34,600
+turbines مش مطلوب مننا نحفظ ولا مركب لكن لما نسمع
+
+284
+00:24:34,600 --> 00:24:40,130
+turbines they are compounds formed fromIsobrane
+
+285
+00:24:40,130 --> 00:24:44,210
+units الان لو قلنا لكم الـ Monoturbine كم Isobrane
+
+286
+00:24:44,210 --> 00:24:51,390
+unit؟ الـ Diterbine، الـ Triterbine، التتراتربين،
+
+287
+00:24:51,390 --> 00:24:55,510
+وقيتا لو جينا قلنا لكم كم carbon atom التتراتربين
+
+288
+00:24:58,300 --> 00:25:02,120
+تمانية في خمسة مش تمانية ايزوبرين يونيتز تمانية في
+
+289
+00:25:02,120 --> 00:25:07,040
+خمسة اربعين هذه السؤال مرات بتجيكوا اكمل الفراغ و
+
+290
+00:25:07,040 --> 00:25:11,220
+صح و غلط يعني نيجي نقولكوا تتراتيربينز contain 30
+
+291
+00:25:11,220 --> 00:25:17,160
+carbon atoms او 3 ايزوبرين يونيتز او 7 ايزوبرين
+
+292
+00:25:17,160 --> 00:25:24,800
+يونيتز واضح الفكرة اقل التقدير احفظولي ايش يسمى ال
+
+293
+00:25:24,800 --> 00:25:30,670
+monoوالداي و الاتراي و التترا بلاش تحفظوا الإسمين
+
+294
+00:25:30,670 --> 00:25:35,170
+اللي تقعدوا فيهم سيسكيو تيربينز و سيستر تيربينز
+
+295
+00:25:35,830 --> 00:25:42,250
+مونو، داي، تراي، تترا، واضح؟ فلو نسألنا عن عدد ال
+
+296
+00:25:42,250 --> 00:25:45,670
+isoprene units أو عن عدد ال carbon atoms اللي
+
+297
+00:25:45,670 --> 00:25:50,690
+موجودة فيهم، نكون إيش؟ عارفين طبعا اكتر في منهم
+
+298
+00:25:50,690 --> 00:25:55,330
+أحيانا البعض حتى من مصدر حيوان بيسموه squalene هذا
+
+299
+00:25:55,330 --> 00:26:01,060
+في أزل تلاتين6 isoprene units 30 carbon atoms
+
+300
+00:26:01,060 --> 00:26:06,420
+لاحظوا معنى ال beta carotene ال beta carotene اللي
+
+301
+00:26:06,420 --> 00:26:10,240
+موجود في الجزر و اللي بيعطي الجزر اللون الأصفر
+
+302
+00:26:10,240 --> 00:26:17,380
+تبعه برضه هذا لو اجينا جسمناه هلاحظ انه عبارة عن
+
+303
+00:26:17,380 --> 00:26:22,930
+ايشتربين من عدة isobrain units هذا ال beta
+
+304
+00:26:22,930 --> 00:26:28,310
+-carotene لما الإنسان بياخده في ال enzymes بيكسر
+
+305
+00:26:28,310 --> 00:26:32,150
+من النص يعني اتخيلوا هذا الشكل العام بدون تفاصيل
+
+306
+00:26:32,150 --> 00:26:38,690
+كسرناه من النص من هنا نصه اتطلع عليه هذا النص
+
+307
+00:26:38,690 --> 00:26:45,480
+المشترك منههو عبارة عن ايش؟ vitamin A بناء على ذلك
+
+308
+00:26:45,480 --> 00:26:51,560
+البني آدم اللي بياكل جزر كتير اللي بياكل جزر كتير
+
+309
+00:26:51,560 --> 00:26:59,440
+بإمكانكوا تتخيلوا ان الجزر بهذا الشكل تمام؟ ان
+
+310
+00:26:59,440 --> 00:27:04,880
+الجزر بهذا الشكل الان vitamin A هو هذا الجزء
+
+311
+00:27:05,720 --> 00:27:08,920
+Vitamin A هو هذا الجزر الآن اللي أخد ال beta
+
+312
+00:27:08,920 --> 00:27:14,460
+-carotene من الجزر بعملية كسر من نص ال beta
+
+313
+00:27:14,460 --> 00:27:17,920
+-carotene بيطلع عنده ال vitamin A تخيلوا أن حد ما
+
+314
+00:27:17,920 --> 00:27:23,960
+أخدش ال beta-carotene وقعد يكوّن هذا من مكوناته
+
+315
+00:27:23,960 --> 00:27:29,910
+الأولية فأسهل أشياء البني آدم يأكل الجزرالجزر فيه
+
+316
+00:27:29,910 --> 00:27:34,710
+ال beta-carotene الكامل بعملية تكسور بسيطة صار في
+
+317
+00:27:34,710 --> 00:27:39,950
+عنده vitamin A و vitamin A طبعا اللي لما تدرسوا
+
+318
+00:27:39,950 --> 00:27:42,710
+عملية الإبصار بالذات الناس اللي هيدرسوا بصريات
+
+319
+00:27:42,710 --> 00:27:48,510
+طبية في رابطة cis بتصير trans اسمه retinol
+
+320
+00:27:48,510 --> 00:27:52,310
+بالأكسجين بيصير له أكسدة مع isomerization cis
+
+321
+00:27:52,310 --> 00:27:57,260
+trans بيصير cis-retinalهذا الانتقال بعد ذلك بين
+
+322
+00:27:57,260 --> 00:28:00,640
+الـ cis والـ trans مع انتصاص الضوء هو اللي بيبقى
+
+323
+00:28:00,640 --> 00:28:05,570
+مسئول عن كل عملية الإبصاريعني هذا ال 11-cis
+
+324
+00:28:05,570 --> 00:28:09,890
+-retinal اللي فيها دي موجودة الرابطة cis ومع
+
+325
+00:28:09,890 --> 00:28:13,070
+امتصاص الضوء بتصير ال Trans بعدين بتعود تفقد الضوء
+
+326
+00:28:13,070 --> 00:28:17,350
+بترجع cis هذه الإشارات الضوئية كلها هي اللي بتنقل
+
+327
+00:28:17,350 --> 00:28:22,190
+للمخ و بتعمل إيش الصورة فكل عملية الإبصار معتمد
+
+328
+00:28:22,190 --> 00:28:26,730
+على إيش؟ على ال 11-cis-retinal 11 طبعا على موقع
+
+329
+00:28:26,730 --> 00:28:31,170
+الرابطة الزوجية هنا 11 11-cis-retinal طب 11-cis
+
+330
+00:28:31,170 --> 00:28:35,380
+-retinal من وين جبناها؟من vitamin A، طب vitamin A
+
+331
+00:28:35,380 --> 00:28:39,800
+من وين جيبناه؟ من الجزر، إذا المادة الأساسية
+
+332
+00:28:39,800 --> 00:28:43,860
+للإبصار ال 11th-seretinal إجت من vitamin A، إجت من
+
+333
+00:28:43,860 --> 00:28:50,780
+الجزر، فالناس اعترافا بالأصل، إيش بيقولوا؟ الجزر
+
+334
+00:28:50,780 --> 00:28:54,510
+بيقوى النظر، بيقولوش vitamin A بيقوى النظرقولوا
+
+335
+00:28:54,510 --> 00:29:00,710
+الجزر بجوّل نظر لأن الجزر هو مصدر ايش؟ vitamin A و
+
+336
+00:29:00,710 --> 00:29:04,970
+vitamin A هو اللي عمل لهذا واضح؟ ولذلك لو سألنا أي
+
+337
+00:29:04,970 --> 00:29:10,470
+بني آدم من الأصل تبعك ممكن يقول الأب بس بنفس الوقت
+
+338
+00:29:10,470 --> 00:29:15,990
+ممكن يقول ايش؟ الجد فالعرب لما كانوا بيتباهوا
+
+339
+00:29:15,990 --> 00:29:21,910
+كانوا بيتباهوا بإيش مرات كتيرة؟ بالأجدادمظبوط ولا
+
+340
+00:29:21,910 --> 00:29:28,350
+لأ؟ لما الفرزق كان بيتباهى بأجداده وببيته وبعيلته
+
+341
+00:29:28,350 --> 00:29:34,070
+ويقول بيت بناه لنا المليك وما بنى حكم السماء فإنه
+
+342
+00:29:34,070 --> 00:29:40,270
+لا ينقض بيت زرارة محتبن بفنائه ومجاشع وابو الفوارس
+
+343
+00:29:40,270 --> 00:29:45,870
+نحشله، هدول أجداده، الآن مين جد السسر تنال؟ الجزر
+
+344
+00:29:47,990 --> 00:29:52,570
+احنا مابنقولش عاد انتبهوا معناه احنا لما نرجع خطوة
+
+345
+00:29:52,570 --> 00:29:57,830
+خطوة للخلف بالكيميا بنقول ال beta-carotene الان
+
+346
+00:29:57,830 --> 00:30:00,230
+واحدة منكم بدها تروح تقول عند إمها ال beta
+
+347
+00:30:00,230 --> 00:30:03,110
+-carotene ولا بتقول اهو ال beta-carotene نفسه من
+
+348
+00:30:03,110 --> 00:30:09,510
+وين من الجزر اه فبنقول في الآخر الجزر بجوّر نظر
+
+349
+00:30:09,510 --> 00:30:13,250
+الان السلسلة جزر beta-carotene، vitamin A، S،
+
+350
+00:30:13,250 --> 00:30:17,470
+ريتينال افهمنا كيف بتيجي السلسلة؟
+
+351
+00:30:21,760 --> 00:30:29,200
+الآن من هذه الـ Isobrane units أيضا بتكون مركبات
+
+352
+00:30:29,200 --> 00:30:35,760
+من أربع حلقات تلت حلقات سداسيات و حلقة خماسية بهذا
+
+353
+00:30:35,760 --> 00:30:39,880
+الشكل هذول أفلا كمان جايين من ال Isobrane units
+
+354
+00:30:39,880 --> 00:30:46,620
+بنسميهم إيش؟ Steroids فال Steroids ببساطة هم عبارة
+
+355
+00:30:46,620 --> 00:30:52,330
+عن Lipidsمن أربع حلقات تلت حلقات سداسية و حلقة
+
+356
+00:30:52,330 --> 00:30:56,570
+خمسية بالشكل هذا يعني ما نحطهم مش بشكل مستقيم لأ
+
+357
+00:30:56,570 --> 00:31:02,050
+لهم شكل خلاص بينطبع إيش صورة في ذهن الإنسان طبعا
+
+358
+00:31:02,050 --> 00:31:07,430
+هدول الأربع حلقات فيهم مجموعات في أماكن مختلفة حسب
+
+359
+00:31:07,430 --> 00:31:12,770
+اختلاف المجموعات تبعتهم بيصيروا يطلعولنا إيشأنواع
+
+360
+00:31:12,770 --> 00:31:17,470
+من الجزيئات و من الهرمونات و ما إلى ذلك ال
+
+361
+00:31:17,470 --> 00:31:22,510
+backbone تبعهم اللي هو الهيكل الأساسي تبعهم الأربع
+
+362
+00:31:22,510 --> 00:31:27,990
+حلقات لكن الاختلاف في المجموعات اللي موجودة عليهم
+
+363
+00:31:27,990 --> 00:31:35,160
+فمن أشهرهم على سبيل المثال الكوليسترونواضح؟
+
+364
+00:31:35,160 --> 00:31:41,360
+الكوليسترول في النهاية بيصف من 27 carbon atom محضر
+
+365
+00:31:41,360 --> 00:31:48,100
+من الانوستيرول موجود في ال animal cells بشكل أساسي
+
+366
+00:31:48,100 --> 00:31:54,490
+بتركز في ال brain و في الحبل الشوكةSpinal cord هو
+
+367
+00:31:54,490 --> 00:31:59,450
+المكون الأساسي للجاليستون الجاليستون يعني حصوة
+
+368
+00:31:59,450 --> 00:32:04,290
+المرارة طبعا الناس اللي منكوا حدرسوا الحصوات سبق
+
+369
+00:32:04,290 --> 00:32:08,070
+أنه مرات اتكلمنا عن الحصوات اللي من الأملاح في
+
+370
+00:32:08,070 --> 00:32:14,970
+الكيلية وقلنا انها الشرر الاش؟ مين متذكرة؟الـ
+
+371
+00:32:14,970 --> 00:32:19,070
+Oxalic Acid Salts لما حكينا عن ال Oxalic Acid و
+
+372
+00:32:19,070 --> 00:32:23,090
+قلتلكوا احفظوا شكل ال Oxalic Acid ال Oxalic Acid
+
+373
+00:32:23,090 --> 00:32:27,070
+Salts متذكرينه؟ اقول لكوا فيه فوسفات و فيه من ال
+
+374
+00:32:27,070 --> 00:32:31,610
+Oxalic Acid، ال Oxalic Acid هذا الحامض اللي مكون
+
+375
+00:32:31,610 --> 00:32:39,440
+من كم؟ Carbon, Diacid, Oxalic AcidOxalic acid لما
+
+376
+00:32:39,440 --> 00:32:43,040
+يعمل salts من هنا هذه ال salts بتعمل حصوات إيش
+
+377
+00:32:43,040 --> 00:32:47,680
+الكيلية؟ حصوات الكيلية حجار stones يعني لما ناس
+
+378
+00:32:47,680 --> 00:32:52,280
+أحيانا حد منهم بيعمل عملية الحصوة و بيطلق ..
+
+379
+00:32:52,280 --> 00:32:56,900
+بيحطوها بالشكوش بيكسروها حصوة إيش؟ حجار بينما
+
+380
+00:32:56,900 --> 00:33:03,850
+حصوات المرارة حصوات مطاطيةيعني دهنية بتنجص بإش
+
+381
+00:33:03,850 --> 00:33:08,790
+بالسكينة بتنجص بالسكينة هذه حصوات المرارة من الإش
+
+382
+00:33:08,790 --> 00:33:17,120
+مكونها الأساسي هوالكلسترول واضح مكونها الأساسي هو
+
+383
+00:33:17,120 --> 00:33:24,020
+الكلسترول طبعا الكلسترول بيضلوا يرتبط في الذهن هو
+
+384
+00:33:24,020 --> 00:33:29,500
+الكلسترول واحد الكلسترول واحد كليسترول كيميائيا
+
+385
+00:33:29,500 --> 00:33:35,580
+كلسترول لكن مرات ربما تصيروا تسمعوا والان بحكي
+
+386
+00:33:35,580 --> 00:33:40,390
+بشكل عام كثقافة عامة جداو بتعود تتوسع فيه اكيد في
+
+387
+00:33:40,390 --> 00:33:47,430
+ال biology بتسمع كوليسترول سيء و كوليسترولحميد او
+
+388
+00:33:47,430 --> 00:33:55,970
+مفيد اه اللي هي ال HDL و LDL high density
+
+389
+00:33:55,970 --> 00:34:00,210
+lipoprotein و low density lipoprotein الان بيصير
+
+390
+00:34:00,210 --> 00:34:04,610
+الكوليسترول نفسه هذا يعني الكوليسترول واحد لكن هذا
+
+391
+00:34:04,610 --> 00:34:13,300
+الكوليسترول لما نقول انه في عنده HDLو LDL و هذا ال
+
+392
+00:34:13,300 --> 00:34:16,900
+LDL هو اللي بيقولوا عنه الكوليسترول ايش السيء اللي
+
+393
+00:34:16,900 --> 00:34:21,200
+بيعمل ترسبات وجلطات هذا الكوليسترول نفسه بيصير
+
+394
+00:34:21,200 --> 00:34:27,630
+محمول هيكا في قلب بروتين معينالان البروتين انواع
+
+395
+00:34:27,630 --> 00:34:31,510
+يعني خلينا نتخيل انه ممكن البروتين الأحمر و ممكن
+
+396
+00:34:31,510 --> 00:34:36,350
+بروتين تاني أخضر يحمله فحسب نوع البروتين الان
+
+397
+00:34:36,350 --> 00:34:40,090
+الكلسترول نفترض اللي محمول في البروتين الأحمر
+
+398
+00:34:40,090 --> 00:34:46,590
+بيكون كثافته أقل شوية صغيرة من الكلسترول إذا كان
+
+399
+00:34:46,590 --> 00:34:52,510
+محمول في بروتين تاني في بروتين تاني هيك نفترضههذا
+
+400
+00:34:52,510 --> 00:34:57,190
+البروتين الأخضر فبصير بالمجموع في عنده low density
+
+401
+00:34:57,190 --> 00:35:02,730
+lipoprotein و high density lipoprotein طبعا واحد
+
+402
+00:35:02,730 --> 00:35:09,420
+منهمدار والثاني مفيد اللي داره بيحب ان نسبته تكون
+
+403
+00:35:09,420 --> 00:35:12,680
+دائما قليلة ومحددة بتاخدوها في التحاليل الطبية
+
+404
+00:35:12,680 --> 00:35:16,600
+اللي هو ال low density ال high density حتى لما
+
+405
+00:35:16,600 --> 00:35:21,140
+بيزيد بيكون ايش بيكون كويس في كل الأحوال مش ال
+
+406
+00:35:21,140 --> 00:35:26,650
+cholesterol نوعينلأ الكوليسترول ككلسترول نوع واحد
+
+407
+00:35:26,650 --> 00:35:31,670
+هو هذا الجزء كوليسترول جزء محدد لكن الكوليسترول
+
+408
+00:35:31,670 --> 00:35:38,140
+محمول في أي بروتينصار نوعين يعني الكوليسترول مع
+
+409
+00:35:38,140 --> 00:35:42,720
+بروتين ألف صار نوع بكثافة منخفضة الكوليسترول مع
+
+410
+00:35:42,720 --> 00:35:47,900
+بروتين با صار نوع تاني بكثافة مرتفعة لكن
+
+411
+00:35:47,900 --> 00:35:54,440
+الكوليسترول نوع واحد الكوليسترول كجزء كيميائي كجزء
+
+412
+00:35:54,440 --> 00:35:59,140
+كيميائي نوع واحد لكن هذا الكوليسترول محمول في أي
+
+413
+00:35:59,140 --> 00:36:06,910
+بروتين هنا بيصير إيش الخلاف واضح؟فعشان هيك حيصير
+
+414
+00:36:06,910 --> 00:36:13,070
+عندكم HDL و LDL و لما تصيروا تحللوا بعدها
+
+415
+00:36:13,070 --> 00:36:19,330
+كوليسترول بتصيروا و الله تبحثوا عن total كوليسترول
+
+416
+00:36:19,330 --> 00:36:23,690
+و لا تقعدوا تفصلوا فيه بدي أشوف جديش ال HDL و جديش
+
+417
+00:36:23,690 --> 00:36:28,390
+ال LDL بصير هذا جزء من العلم اللي هتاخدوه بالتفصيل
+
+418
+00:36:29,230 --> 00:36:34,110
+بس احنا الآن بناخد الشكل العام للكلسترول وقلنا عنه
+
+419
+00:36:34,110 --> 00:36:38,110
+مكون أساسي لحصوة المرارة وقلنا عنه انه مكون من أكم
+
+420
+00:36:38,110 --> 00:36:45,910
+حلقة؟ أربع حلقات وهي هنا شكل حصوة المرارة الان
+
+421
+00:36:45,910 --> 00:36:50,910
+لاحظوا ان الكوليسترول أساسي في الهرمونات الجنسية
+
+422
+00:36:51,910 --> 00:36:57,310
+سواء كانت الهرمونات الجنسية الذكورية أو الأنثوية
+
+423
+00:36:57,310 --> 00:37:01,930
+الهرمونات الأنثوية بيسموها Astrogens ال Astrogens
+
+424
+00:37:01,930 --> 00:37:06,730
+اللي هي ال Female Hormones والهرمونات بتاع ال Male
+
+425
+00:37:06,730 --> 00:37:11,270
+Hormones إيش بيسموهم؟ Androgens من أشهرهم بتاع ال
+
+426
+00:37:11,270 --> 00:37:16,810
+females ال Estradiol و ال Progesteroneلمّا نطلع
+
+427
+00:37:16,810 --> 00:37:21,110
+عليهم، إيش الوظائف تبعتهم؟ وظائفهم تنظيم الصفات
+
+428
+00:37:21,110 --> 00:37:25,930
+الجنسية، خشونة .. نعومة الصوت عند الإناف مثلا،
+
+429
+00:37:25,930 --> 00:37:30,010
+خشونة الصوت عند الرجال، الشعر، بعدين بتدخلوا في
+
+430
+00:37:30,010 --> 00:37:33,590
+الدورة الشهرية عند النساء، كل هذا الكلام بيمنعوا
+
+431
+00:37:33,590 --> 00:37:37,310
+التبويض في مرحلة معينة لما بيصير الحمل، بييجي في
+
+432
+00:37:37,310 --> 00:37:40,850
+التبويض، كل هذا الكلام، مين اللي بيقوم فيه؟ اللي
+
+433
+00:37:40,850 --> 00:37:44,710
+هي ال Astrogens استرديولوبروجسترون
+
+434
+00:37:45,920 --> 00:37:51,480
+عند الرجال الهرمون او عند الذكور ايش تستوستيرون و
+
+435
+00:37:51,480 --> 00:37:56,740
+أندروستيرون الان لو اجينا تطلعنا عليهم كلهم ايش
+
+436
+00:37:56,740 --> 00:38:01,120
+استيرويد انا عملتلهم صورة مكبرة شوية تطلعوا
+
+437
+00:38:01,120 --> 00:38:07,100
+استيرويد استيرويد استيرويداستيرويد طب وين الاختلاف
+
+438
+00:38:07,100 --> 00:38:12,180
+بينهم؟ في المجموعات الوظيفية يعني لو اجيت انا
+
+439
+00:38:12,180 --> 00:38:18,660
+لليبروجيستيرون مثلا والتيستيستيرون اشهر هرمون عند
+
+440
+00:38:18,660 --> 00:38:22,140
+الاناث دائما بيكونوا ايش يقولوا؟ ليبروجيستيرون عند
+
+441
+00:38:22,140 --> 00:38:26,280
+الذكور؟ التيستيستيرون ابدوا واتأملوا في الشكلين
+
+442
+00:38:26,280 --> 00:38:31,980
+تبعونهم ابدوا من عندها الـ C double bond O و
+
+443
+00:38:31,980 --> 00:38:38,570
+الحلقةو CH3 و لاحظوا كيف ال stereochemistry مهمة
+
+444
+00:38:38,570 --> 00:38:43,310
+جدا .. ال stereochemistry .. الأن منها .. منها ..
+
+445
+00:38:43,310 --> 00:38:48,790
+منها .. في الآخر ماصفش غير هذا الفرق .. Acetyl
+
+446
+00:38:48,790 --> 00:38:53,630
+group و لا OH group .. بتخلي واحد هرمون أنثوي و
+
+447
+00:38:53,630 --> 00:38:59,440
+بتخلي الثاني هرمون ذكوريلاحظوا كم التغير البسيط ..
+
+448
+00:38:59,440 --> 00:39:04,180
+التغير البسيط في مجموعة كيميائية جاعت بعكس الوظائف
+
+449
+00:39:04,180 --> 00:39:07,680
+احنا شوفنا اكتر من هيك احنا شوفنا كمان في ال
+
+450
+00:39:07,680 --> 00:39:11,580
+stereo chemistry انه تغير شكل المجموعات بيحول
+
+451
+00:39:11,580 --> 00:39:15,980
+المركب من سام إلى مفيده عشان هيك انا لاحظوا كم
+
+452
+00:39:15,980 --> 00:39:19,460
+عندي stereo chemistry هانو هانو هانو كل هذا الكلام
+
+453
+00:39:19,460 --> 00:39:25,280
+مدروس بشكل كامل عند العلماء فهذه ال six hormones
+
+454
+00:39:25,280 --> 00:39:31,280
+they arein general استيرويدز بينقسموا زي ما اتفقنا
+
+455
+00:39:31,280 --> 00:39:35,620
+إلى كام نوع استروجينز اللي هي ال female hormones و
+
+456
+00:39:35,620 --> 00:39:39,420
+أندروجينز و في منها أنواع و أشكال مش مطلوب نحفظ
+
+457
+00:39:39,420 --> 00:39:44,620
+بالتأكيد ولا شكل بس يكون فاهمين الفكرة أن كلهم
+
+458
+00:39:44,620 --> 00:39:49,800
+استيرويدز و أن الشبه بينهم كبير جدا لكن اختلاف
+
+459
+00:39:49,800 --> 00:39:55,400
+مجموعة يؤدي إلى اختلاف كبير في الوظيفةطبعا من
+
+460
+00:39:55,400 --> 00:40:00,960
+هدولة بيصير عندي أشياء اللي هي بنطلع منهم أدوية
+
+461
+00:40:00,960 --> 00:40:10,870
+على سبيل المثال الدواء اللي هيالأقراس منع الحمل هي
+
+462
+00:40:10,870 --> 00:40:17,290
+أقراس شبيهة بهذه الهرمونات مثلا هنا دوة هي بيشبه
+
+463
+00:40:17,290 --> 00:40:22,530
+ال استيرويد برضه هذا بيساعد على الإجهاد بدون
+
+464
+00:40:22,530 --> 00:40:26,590
+عمليات جراحية في مراحل معينة مقارنة في أوروبا
+
+465
+00:40:26,590 --> 00:40:31,150
+وغيرها لو بدنا نشوف ال cortisone اللي بيستعملوه
+
+466
+00:40:31,150 --> 00:40:35,770
+لالتهاب المفاصل و للناس اللي عندهم تكسر في ال
+
+467
+00:40:35,770 --> 00:40:41,090
+plateletsفي التجلط هذا ال Cortisone الناس اللي
+
+468
+00:40:41,090 --> 00:40:46,150
+بياخدوه بتشوفوهم كيف بينتفخوا اه هاي ال Cortisone
+
+469
+00:40:46,150 --> 00:40:52,230
+استيرويدز بالنسبة شبه .. بالنسبة شبه كبيرة في ال
+
+470
+00:40:52,230 --> 00:40:56,630
+sex hormone يستعمل بشكل أساسي in the treatment of
+
+471
+00:40:56,630 --> 00:41:05,210
+arthritis التي هي إيش؟ التهاب المفاصلالمفاصل والـ
+
+472
+00:41:05,210 --> 00:41:09,890
+platelets فالخلاصة انه هيرمونات كتير مأخوذ منها
+
+473
+00:41:09,890 --> 00:41:14,950
+كمان أدوية كتير كلها في طبيعتها ايش بنسميها؟
+
+474
+00:41:14,950 --> 00:41:19,270
+استيرويدال وعشان هيك هتصيروا تلاقوا في الأدوية وفي
+
+475
+00:41:19,270 --> 00:41:23,850
+المضادات الحيوية انه تلاقوا استيرويدال drugs يعني
+
+476
+00:41:23,850 --> 00:41:26,830
+أدوية من الاستيرويدس ايش يعني أدوية من
+
+477
+00:41:26,830 --> 00:41:27,810
+الاستيرويدس؟
+
+478
+00:41:32,390 --> 00:41:36,590
+اربع حلقات حتى لو زعلوا جماعة رابعة مش موضوع احنا
+
+479
+00:41:36,590 --> 00:41:44,430
+بنقول ايش اربع حلقات الاستيرويد اربع حلقات ابهيك
+
+480
+00:41:44,430 --> 00:41:50,350
+بننتهي من اعطاء فكرة عامة عن موضوع ال labels و الى
+
+481
+00:41:50,350 --> 00:41:51,710
+لقاء قادم ان شاء الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b4f6a3df1e3f9279ab64b48b736cccfce14619ad
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU.srt
@@ -0,0 +1,1424 @@
+
+1
+00:00:21,210 --> 00:00:26,340
+بسم الله الرحمن الرحيم باقي عندنا في موضوع
+
+2
+00:00:26,340 --> 00:00:30,340
+التفاعلات أو التفاعلات المرتبطة بال
+
+3
+00:00:30,340 --> 00:00:34,940
+stereochemistry شغلتين بسيطات احنا اتكلمنا في
+
+4
+00:00:34,940 --> 00:00:38,600
+الأول على نقطة كتير مهمة أو على تفاعل كتير مهم
+
+5
+00:00:38,600 --> 00:00:43,740
+قولنا دائما في المختبر بالوضع الطبيعي لما نعمل
+
+6
+00:00:43,740 --> 00:00:47,560
+generation of a chiral center بيطلع عندي racemic
+
+7
+00:00:47,560 --> 00:00:50,400
+mixture equal mixture of enantiomers وهذا بده
+
+8
+00:00:50,400 --> 00:00:54,830
+غلبة و بده فصل و ما إلى ذلك والان بيحاولوا انهم
+
+9
+00:00:54,830 --> 00:00:59,250
+يتغلبوا على هذا الكلام من خلال تقنيات حديثة في
+
+10
+00:00:59,250 --> 00:01:04,390
+التحضير بيسموها asymmetric synthesis هذا التفاعل
+
+11
+00:01:04,390 --> 00:01:10,030
+الأول التفاعل التاني، لو أنا يا تورا بعمل تفاعل
+
+12
+00:01:10,030 --> 00:01:15,450
+بعيدا عن ال chiral center، الآن إيش معنى بعيدا عن
+
+13
+00:01:15,450 --> 00:01:21,310
+ال chiral center؟ بمعنى لأكسر رابطة متصلة بال
+
+14
+00:01:21,310 --> 00:01:25,330
+chiral center، يعني الأربع روابط المتصلين بال
+
+15
+00:01:25,330 --> 00:01:30,950
+chiral center بكسرهم مشكل ما بعد ذلك يعتبر ايش؟
+
+16
+00:01:30,950 --> 00:01:35,230
+تفاعل بعيد عن الـ Chiral Center واضح الفكرة؟ يعني
+
+17
+00:01:35,230 --> 00:01:39,110
+مثلا في هذا المركب، عندي هنا أنا Chiral Center
+
+18
+00:01:39,110 --> 00:01:45,010
+متصل بـ Methyl و بـ Ethyl و COH و بH، الآن هذا الـ
+
+19
+00:01:45,010 --> 00:01:50,240
+Chiral Center عليه كام رابطة؟ أربع روابط لو أنا بدي
+
+20
+00:01:50,240 --> 00:01:55,460
+أبدل مجموعة ال O H هنا اللي هي ال acidic O H
+
+21
+00:01:55,460 --> 00:02:01,200
+مجموعة ال O H الحامضية هذه كلها بمجموعة O Ethyl
+
+22
+00:02:01,200 --> 00:02:06,420
+بمعنى في الكيميا هذا التفاعل هنتعلمه بنبدل فيه ال
+
+23
+00:02:06,420 --> 00:02:12,340
+acid ل E starباستعمال التفاعل مع الكحول شيلت الـ
+
+24
+00:02:12,340 --> 00:02:19,240
+OH و خلتها ايش؟ O Ethan الان هذه الأربع رواضة كسرت
+
+25
+00:02:19,240 --> 00:02:25,380
+جزء منها؟ لأ وبناء على ذلك الجيومتري حوالين
+
+26
+00:02:25,380 --> 00:02:28,640
+الكايرال كاربون الشكل اللذس حوالين الكايرال كاربون
+
+27
+00:02:28,640 --> 00:02:33,620
+بيضل زي ما هو فأنا كأن بعمل عملية ايش نسخ و لصق
+
+28
+00:02:33,620 --> 00:02:38,960
+بلغة الكمبيوتر يعني باجي بعمل نسخ لهذا بكل موابط و
+
+29
+00:02:38,960 --> 00:02:43,740
+لاحظوا ال H باتجاه ال CO باتجاه ال CH3 ال إثل بحطه
+
+30
+00:02:43,740 --> 00:02:48,120
+هنا و بعمل التغيير اللي عندهو بناء على ذلك بنقول
+
+31
+00:02:48,120 --> 00:02:52,740
+انه تم عنده retention of configuration يعني الشكل
+
+32
+00:02:52,740 --> 00:02:58,360
+ضل زي ما هو اتجاه الاربع روابط اللي محيطين بال
+
+33
+00:02:58,360 --> 00:03:03,440
+chiral center ضالهم ايش زي ما هو لو أنا بدي أعطيكم
+
+34
+00:03:03,440 --> 00:03:07,700
+مثال يعني تخيلوا مثلا أنا بهذا الشكل هينعمل chiral
+
+35
+00:03:07,700 --> 00:03:12,260
+center من اربع شغلات و أتيت أعمل التفاعل هنا كان
+
+36
+00:03:12,260 --> 00:03:15,900
+ما فيش في إيدي جلم امسكت جلم هل غيرت في اتجاه
+
+37
+00:03:15,900 --> 00:03:19,480
+الأربع روابط ولا في عند retention of configuration
+
+38
+00:03:19,480 --> 00:03:23,760
+في عند retention of configuration إذا التفاعل
+
+39
+00:03:23,760 --> 00:03:28,720
+بعيدا عن ال chiral center بتم في retention of
+
+40
+00:03:28,720 --> 00:03:31,660
+configuration معنى retention of configuration أن
+
+41
+00:03:31,660 --> 00:03:36,600
+اتجاهات الروابط الأربع تبقى كما هي لم نكسر شيء
+
+42
+00:03:36,600 --> 00:03:42,300
+حولها كذلك الحال هنا احنا حاطين مثال تاني لو فعلنا
+
+43
+00:03:42,300 --> 00:03:47,740
+هذا المركب يعلن الكايرال سنتر بدلنا هذه ال O H
+
+44
+00:03:47,740 --> 00:03:51,740
+خلناها C double bond O باستعمال اكسدة ابعام
+
+45
+00:03:51,740 --> 00:03:53,620
+المؤكسل عادة بنسميه
+
+46
+00:03:56,470 --> 00:04:01,290
+الان هذول الاربع روابط صار عندهم تغيير و لا تغيير
+
+47
+00:04:01,290 --> 00:04:06,390
+بعد الكايرالسينفاق بعد اذا كل الاتجاهات تبقى كما
+
+48
+00:04:06,390 --> 00:04:13,840
+هي CLH CH2 CH3 الـC هادى التغير بعدها ما كسرت روابط
+
+49
+00:04:13,840 --> 00:04:16,660
+بالتصيلة بال chiral center مرة تانية في عندي
+
+50
+00:04:16,660 --> 00:04:20,280
+retention of configuration إذا ال reaction away
+
+51
+00:04:20,280 --> 00:04:23,160
+from a chiral center results in retention of
+
+52
+00:04:23,160 --> 00:04:30,000
+configuration الآن بهمني أعطي بس ملاحظة خفيفة الـ
+
+53
+00:04:30,000 --> 00:04:34,600
+retention of configuration معناه أن الأربع روابط
+
+54
+00:04:34,600 --> 00:04:39,720
+تبقى في اتجاهاتها ليس له علاقة .. ليس له علاقة
+
+55
+00:04:39,720 --> 00:04:46,100
+بكلمة R و S أنا هنا و أنا بشتغل كتبت R ولا S ولا
+
+56
+00:04:46,100 --> 00:04:50,380
+شفت أن ال R دلت R ولا ال S دلت S؟ ماجبتش سيرة
+
+57
+00:04:50,380 --> 00:04:55,100
+هالكلام، ليش؟ لأنه أنا لما بغير مجموعة هنا أو هنا
+
+58
+00:04:55,100 --> 00:05:02,890
+ممكن الأولويات تتغير؟ أكيد أكيد حتى لو غيرت مجموعة
+
+59
+00:05:02,890 --> 00:05:06,790
+بعيد ممكن يصير فيه تغيير بالأولويات و لذلك ممكن R
+
+60
+00:05:06,790 --> 00:05:11,430
+عند الضل R ممكن R تصير S ممكن S تصير R ممكن S تظل
+
+61
+00:05:11,430 --> 00:05:16,370
+S أو تتقلب إلى R هذا موضوع ما درسته أنا اطلاقا أنا
+
+62
+00:05:16,370 --> 00:05:21,650
+بدرس الأربع روابط في اتجاهاتهم فيهم تغيير ولا لأ
+
+63
+00:05:21,650 --> 00:05:26,020
+هى معناه retention of configuration الان R و S من
+
+64
+00:05:26,020 --> 00:05:31,160
+أول و جديد في عندكم إشي اسمه قواعد ترتيب المجموعات
+
+65
+00:05:31,160 --> 00:05:36,320
+حسب الأولويات واحد اتنين تلاتة اربعة بنرتبهم ضلت
+
+66
+00:05:36,320 --> 00:05:41,460
+الارار صارت اسم مش مشيء بالنسبة الي واضح الفكرة
+
+67
+00:05:41,460 --> 00:05:47,200
+فكلمة retention of configuration لا تعني اطلاقا ..
+
+68
+00:05:47,200 --> 00:05:52,700
+لا تعني اطلاقا ان ال R دلت R او ال S دلت S لأ تعني
+
+69
+00:05:52,700 --> 00:05:58,520
+ان الأربع روابط ضالهم باتجاههم ال R و ال S اولويات
+
+70
+00:05:58,520 --> 00:06:01,420
+اللي بيحسب اولويات يشوف حسب المثال اللي عنده
+
+71
+00:06:01,420 --> 00:06:05,480
+هتلاقوا مثال بتم فيه تغيير مثال بتم مش فيه تغيير
+
+72
+00:06:05,480 --> 00:06:09,460
+حسب هالمجموعة اللي طلعت و المجموعة اللي اجت هذا
+
+73
+00:06:09,460 --> 00:06:15,200
+موضوع تاني واضح الفكرة؟ وهذا كثير بنسألكم بمعناه
+
+74
+00:06:15,200 --> 00:06:19,280
+انه هالمعنى كلمة retention of configuration means
+
+75
+00:06:19,280 --> 00:06:24,420
+are must be are in the product لأ مش ضروري ممكن
+
+76
+00:06:24,420 --> 00:06:29,400
+تظل ممكن تتغير هذا موضوع و هذا موضوع تاني
+
+77
+00:06:33,710 --> 00:06:39,030
+هذه تفاعلات بناخدها بعدين بس بنعطيها كأمثلة يعني
+
+78
+00:06:39,030 --> 00:06:43,710
+هذا تأكسد كحول إلى aldehyde لما ندرس chapter
+
+79
+00:06:43,710 --> 00:06:49,410
+الكحولات ب chapter 7 بنشرحه الآن بديش أنا أسمي لا
+
+80
+00:06:49,410 --> 00:06:52,750
+كحول ولا aldehyde أنا قلت ال Canada دي CO single
+
+81
+00:06:52,750 --> 00:06:57,840
+bond صارت CO double bond غيرت هان ولا لأ؟ تستعجلوش
+
+82
+00:06:57,840 --> 00:07:02,880
+العلم هذا تحول حامض إلى Easter بدلت ال OH ب Oethel
+
+83
+00:07:02,880 --> 00:07:08,140
+بدرسه ب Chapter 10 مش هو موضوعي غيرت بدي ألغي كل
+
+84
+00:07:08,140 --> 00:07:13,060
+اللي كاتبه و أكتب XY عشان اترايحيني أعصابي خلت XY
+
+85
+00:07:13,060 --> 00:07:14,980
+واضح؟
+
+86
+00:07:16,500 --> 00:07:21,120
+دائما تتعبوش أنفسكم في الفكرة غير الأساسية بدلت X
+
+87
+00:07:21,120 --> 00:07:26,760
+بY إيش التفاعل مش مشكلة مش X صارت Y تفاعل general
+
+88
+00:07:26,760 --> 00:07:31,520
+بدلته بعيدا عن ال chiral center إيش بيظل عنده
+
+89
+00:07:31,520 --> 00:07:37,960
+retention إنما هدولا التفاعلين كتفصيل بناخدهم في
+
+90
+00:07:37,960 --> 00:07:43,160
+chapter 7 أو chapter 10 لكن استعانا فيهم كأمثلة
+
+91
+00:07:45,090 --> 00:07:50,130
+التفاعل التالت generation of a second chiral
+
+92
+00:07:50,130 --> 00:07:54,370
+center يعني لاحظوا احنا اول مرة قولنا ماكنش لنا
+
+93
+00:07:54,370 --> 00:07:57,390
+chiral center نهائي و عملنا له generation، شو طلع
+
+94
+00:07:57,390 --> 00:08:04,840
+عندي؟ رسمic mixture تاني تفاعل لما اعملت تفاعل بعيد
+
+95
+00:08:04,840 --> 00:08:08,320
+عن الكايرال سنتر شو صار عندي retention of
+
+96
+00:08:08,320 --> 00:08:13,880
+configuration طيب الآن لو كان في عندي كايرال سنتر
+
+97
+00:08:13,880 --> 00:08:19,160
+اول و بدى اعمل كايرال سنتر تاني شو بده يصير عندي؟
+
+98
+00:08:19,160 --> 00:08:25,120
+خلّينا نشوف مثال هذه مثال لو طلعنا على هذا المركب
+
+99
+00:08:25,120 --> 00:08:29,880
+الآن هذه الكاربون اللى موجودة هنا بتحمل مثل
+
+100
+00:08:29,880 --> 00:08:33,970
+وchloro Hو المجموعة اللي فيها double bond كايرال
+
+101
+00:08:33,970 --> 00:08:39,290
+سنتر ولا لأ؟ كايرال سنتر أنا مش موضوعي اطلاقا هذه
+
+102
+00:08:39,290 --> 00:08:42,770
+ال carbon بدي اعمل التفاعل على ال double bond يعني
+
+103
+00:08:42,770 --> 00:08:48,160
+على ال double bond بدي اجي اضيف hbr في وجود H plus
+
+104
+00:08:48,160 --> 00:08:53,940
+هذه أخدناها إضافة Markovnikov يعني بدأ أحط ال H
+
+105
+00:08:53,940 --> 00:09:00,080
+هنا في الأول أبدأ تفاعل بإضافة ال H هنا وبعدين
+
+106
+00:09:00,080 --> 00:09:06,260
+أكمل ال PR على هذا الموقع لاحظوا إيش اللي بدو يصير
+
+107
+00:09:06,260 --> 00:09:12,060
+عندي لما أضيف ال H على هذا الموقع كام رابط هيظل
+
+108
+00:09:12,060 --> 00:09:20,250
+على هذه النقطة؟ تلت روابط تلت روابطحاولوا تستحضروا
+
+109
+00:09:20,250 --> 00:09:24,510
+الشكل مع الهيدروجين المحذوف مع الهيدروجين المحذوف
+
+110
+00:09:24,510 --> 00:09:30,210
+أعطيكم H هاي
+
+111
+00:09:30,210 --> 00:09:35,830
+الشكل الكامل واضح؟ لما أضيف هنا H هذا الكربون بدل
+
+112
+00:09:35,830 --> 00:09:41,630
+ما يكون CH2 ماذا سيحصل؟ CH3 سيحصل CH3 و ال double
+
+113
+00:09:41,630 --> 00:09:48,850
+bond هذه ستذهب علىأساس أنه هيجي يخجم عندي هنا PR
+
+114
+00:09:48,850 --> 00:09:53,270
+في الخطوة التالية الآن لاحظوا معي لو اتطلعنا على
+
+115
+00:09:53,270 --> 00:09:58,450
+هذا الجزء هذا الجزء يا ترى هل احنا بنشتغل قريب عنه
+
+116
+00:09:58,450 --> 00:10:04,430
+ولا بالنسبة له بنشتغل reaction away from a chiral
+
+117
+00:10:04,430 --> 00:10:08,290
+center away from a chiral center وعشانك بنحطه زي
+
+118
+00:10:08,290 --> 00:10:10,630
+ما هو لاحظوا إيش معناه retention of configuration
+
+119
+00:10:10,630 --> 00:10:14,750
+المثل اللي فوق ال CL على اليمين ال H على الشمال هذا
+
+120
+00:10:14,750 --> 00:10:19,010
+retention of configuration ولا لأ؟ الآن هذه النقطة
+
+121
+00:10:19,010 --> 00:10:27,690
+هي النقطة اللي هنا ال CH2 شو صارت؟ CH3 و هذه ما
+
+122
+00:10:27,690 --> 00:10:35,090
+زالت H و الآن أنا بانتظار ال PR لما نيجي نطلع
+
+123
+00:10:35,090 --> 00:10:38,130
+حوالين هذه ال carbon ايش الشكل؟
+
+124
+00:10:40,850 --> 00:10:46,950
+بناء على ذلك بنتوقع ان ال PR بإمكانها تهجم من
+
+125
+00:10:46,950 --> 00:10:51,010
+الجهتين زي ما أخذنا في أول مرة لما درسنا ال
+
+126
+00:10:51,010 --> 00:10:53,950
+generation of a chiral center بمعنى ال PR ممكن
+
+127
+00:10:53,950 --> 00:10:58,830
+تيجي من هنا و ال PR ممكن تيجي تهاجي من هنا إذا كام
+
+128
+00:10:58,830 --> 00:11:03,070
+ناتج بدو يطلع عندي هى ال PR إذا إجت من هذا الاتجاه
+
+129
+00:11:03,070 --> 00:11:09,380
+و هى ال PR إذا إجت من الاتجاه التالفزي لما درسنا
+
+130
+00:11:09,380 --> 00:11:12,600
+اول مرة الـ Chiral Center تقولنا عندنا بلانر
+
+131
+00:11:12,600 --> 00:11:18,100
+انترميديت تم التفاعل من ايه؟ من الجهتين الان هنا
+
+132
+00:11:18,100 --> 00:11:22,180
+في عند بلانر انترميديت اتكونت نتيجة انه ضفت اتش
+
+133
+00:11:22,180 --> 00:11:29,780
+لغية ال bubble bond التفاعل بإمكانه تم من الجهتين و
+
+134
+00:11:29,780 --> 00:11:35,340
+بناء على ذلك كام ناتج يطلع عنده؟ اتنين بيفرق عن
+
+135
+00:11:35,340 --> 00:11:40,880
+المثال الأول بشغل واحدة انه هل يترى الاحتمالات
+
+136
+00:11:40,880 --> 00:11:44,860
+متساوية ان هذا ييجي عن اليمين او عن الشمال في
+
+137
+00:11:44,860 --> 00:11:48,960
+generation of a first chiral center كنا نقول
+
+138
+00:11:48,960 --> 00:11:54,000
+الاحتمالات بتكون متساوية و بناء على ذلك يطلع عنده
+
+139
+00:11:55,740 --> 00:12:01,120
+الان بسبب وجود الكايرال سنتر الاول اللى بيخل
+
+140
+00:12:01,120 --> 00:12:06,400
+الفراغات حوالين هذا الكاربون غير متساوية مابيكونوش
+
+141
+00:12:06,400 --> 00:12:13,720
+الاحتمالين بنفس المقدار فبتم صحيح هجوم من الجهتين
+
+142
+00:12:13,720 --> 00:12:20,570
+ولكن ليسبنسب متساوية يعني مابيجيش 50% من التفاعل
+
+143
+00:12:20,570 --> 00:12:24,430
+من هنا و 50% من التفاعل من هنا ليش هذا الكلام
+
+144
+00:12:24,430 --> 00:12:30,240
+امتنع؟ بسبب وجود ال chiral center اللي بيخلي جهة
+
+145
+00:12:30,240 --> 00:12:35,240
+أحيانا مغلقة أكتر من الجهة التانية بيصير فيه فرق
+
+146
+00:12:35,240 --> 00:12:40,180
+بالوسع زي إنسان كان عنده مسارين متساويين تماما
+
+147
+00:12:40,180 --> 00:12:44,520
+بيمكنه يمشي من هنا و من هنا الآن إجا شيء سكر جزء
+
+148
+00:12:44,520 --> 00:12:50,520
+من مسار معين بيضلوا يمشي بنفس النسبة ولا غالبا
+
+149
+00:12:50,520 --> 00:12:55,530
+بيروح على المسار الأكتر يعني ساعة و فراغواضح
+
+150
+00:12:55,530 --> 00:13:00,610
+الفكرة؟ الآن شو اللي خلّى عدم التساوي؟ الكايرال
+
+151
+00:13:00,610 --> 00:13:04,450
+سنتر الأول الكايرال سنتر الأول بيخلّى عدم تساوي
+
+152
+00:13:04,450 --> 00:13:08,890
+إذا لو أنا اتطلعت الآن على هدول الناتجين اللي
+
+153
+00:13:08,890 --> 00:13:13,610
+طلعوا بنسب متساوي ولا غير متساوية؟ غير متساوية غير
+
+154
+00:13:13,610 --> 00:13:17,690
+متساوية in unequal amounts وسألت يا تورا ما
+
+155
+00:13:17,690 --> 00:13:24,530
+العلاقة بين هدول المركبين اللي طلعوا عندهم؟ لاحظوا
+
+156
+00:13:24,530 --> 00:13:30,570
+هذا الجزء و هذا الجزء ايش مالهم؟ صورة بعض في المرأة
+
+157
+00:13:30,570 --> 00:13:36,450
+و متعاكسة طب و هذا و هذا نفس الشيء إذا المركب كله
+
+158
+00:13:36,450 --> 00:13:42,110
+صورة بعض و لا لأ؟ إذا بدكم تعملوا باستعمال الرموز
+
+159
+00:13:42,110 --> 00:13:49,370
+بإمكانكم تعملوا R و S بمعنى نلغي هذه ال edge هعندي
+
+160
+00:13:49,370 --> 00:13:55,180
+واحد اتنين تلاتة هذه البيانة R هذه S الانهان ما
+
+161
+00:13:55,180 --> 00:14:00,540
+اتغيرت ضلت زي ما هي هالكلور و بعدين كربون حملة
+
+162
+00:14:00,540 --> 00:14:06,460
+برون بعدين اذا هذه ايش S طيب لو اتيت و طلعت هنا
+
+163
+00:14:06,460 --> 00:14:09,900
+واحد
+
+164
+00:14:09,900 --> 00:14:14,640
+اتنين R
+
+165
+00:14:14,640 --> 00:14:21,860
+S هذه واحد اتنين R S
+
+166
+00:14:24,660 --> 00:14:31,600
+مكتوبها R رجعوهم بهدوء ال R شيء متعاكس و شيء متساوي
+
+167
+00:14:31,600 --> 00:14:37,740
+إذا هدوله ايش ديستريو مارس ف ال generation of a
+
+168
+00:14:37,740 --> 00:14:42,920
+second chiral center المحاصلة تبعته it results in
+
+169
+00:14:42,920 --> 00:14:46,560
+diastereomeric products at different rates بسرعة
+
+170
+00:14:46,560 --> 00:14:53,300
+مختلفة الأهم منها and inunequal amounts يعني لو
+
+171
+00:14:53,300 --> 00:14:56,520
+أنا باسألكوا سؤال صح و غلط generation of a second
+
+172
+00:14:56,520 --> 00:15:00,580
+chiral center results in the stereomeric mixture
+
+173
+00:15:00,580 --> 00:15:06,440
+or products in equal amounts and unequal amounts
+
+174
+00:15:06,590 --> 00:15:10,050
+طبعا ليش صار الـ unequal amount؟ because of the
+
+175
+00:15:10,050 --> 00:15:14,750
+presence of the first chiral center وجود ال chiral
+
+176
+00:15:14,750 --> 00:15:19,390
+center الأول خلّى احتمالات الهجوم من الجه
+
+223
+00:19:02,860 --> 00:19:07,300
+ما يكون ساعتين يكون تلت ساعات وانتهي ان انا فصلت
+
+224
+00:19:07,300 --> 00:19:11,020
+المادة لأ لما انا بقول ال resolution of
+
+225
+00:19:11,020 --> 00:19:15,520
+enhancements عملية صعبة يعني واحد باحث بيشتغل وطلع
+
+226
+00:19:15,520 --> 00:19:20,340
+عنده mix chart و بده يبدأ يفصل فيه ممكن الأمور معه
+
+227
+00:19:20,340 --> 00:19:23,640
+اذا بدأ من نقطة الصفر وماعندهش اي فكرة على الموضوع
+
+228
+00:19:23,640 --> 00:19:28,770
+يبدأ تجارب تاخد سنة مش بحكي عن ساعتين و تلاتة و
+
+229
+00:19:28,770 --> 00:19:34,410
+أربعة لأ بحكي عن سنة و أكتر كمان من سنة ليست عملية
+
+230
+00:19:34,410 --> 00:19:50,430
+سهلة في الوضع الطبيعي ابهيك
+
+231
+00:19:50,430 --> 00:19:54,930
+بنكون طبعا خلصنا هذا ال chapter اللي اسمه
+
+232
+00:19:58,800 --> 00:20:04,620
+استيريو كيميستري وبننتقل
+
+233
+00:20:04,620 --> 00:20:11,960
+مباشرة الى فصل اخر هذا الفصل الاخر بدنا ناخده نوعا
+
+234
+00:20:11,960 --> 00:20:19,910
+ما باختصار .. نوعا ما باختصار عنوانه الـ الكلهليلايزو
+
+235
+00:20:19,910 --> 00:20:24,950
+طبعا ال الكلهليتز المجموعة هذه من المركبات لها
+
+236
+00:20:24,950 --> 00:20:30,870
+تفاعلين substitution and elimination تفاعل الإبدال
+
+237
+00:20:30,870 --> 00:20:37,980
+وتفاعل الحدث بالنسبة ل الكلاعرفنا إيش يعني الـ الكل؟
+
+238
+00:20:37,980 --> 00:20:44,860
+مجموعة الـ الكل مثل و إثل و بربل و كل شيء مأخوذ من ال
+
+239
+00:20:44,860 --> 00:20:50,260
+الكلس سواء له اسم و لا مالوش اسم و الـ هيليدز متصل
+
+240
+00:20:50,260 --> 00:20:57,300
+بهالوجين كلور بروم يود فلور أحيانا فال الكلهيليدز
+
+241
+00:20:57,300 --> 00:21:03,750
+ببساطة هم ال الكلس المتصلين بهالوجيني يعني لو اجينا
+
+242
+00:21:03,750 --> 00:21:08,130
+و قولنا هذا المركب يا تورا و كتبنا هنا PR عبارة عن
+
+243
+00:21:08,130 --> 00:21:14,170
+إيش الـ الكل هيلايد لأن هذا الجزء الـ كين و هذا الجزء
+
+244
+00:21:14,170 --> 00:21:18,250
+الهالوجين و عشان ذلك مرات بيسموها أي معنى الـ الكل
+
+245
+00:21:18,250 --> 00:21:22,030
+هيلايد في جزء الـ كين و جزء الهالوجين عشان ذلك مرات
+
+246
+00:21:22,030 --> 00:21:28,870
+بيسموهم الهالوجينو الـ كينز الـ الكل هيلايد او الهالوجينو
+
+247
+00:21:28,870 --> 00:21:32,490
+الـ كينز نفس الفكرة تماما
+
+248
+00:21:38,950 --> 00:21:43,570
+الان زي ما حكيت ال الكلهيلايتز بيسموهم مرات
+
+249
+00:21:43,570 --> 00:21:48,410
+الهالوجينوالكينز او هالوالكينز فسواء قرأنا العنوان
+
+250
+00:21:48,410 --> 00:21:53,170
+الـ الكلهيلايتز او هالوجينوالكينز او هالوالكينز هو ال
+
+251
+00:21:53,170 --> 00:21:58,300
+cane حامل الهالوجين البساطة مش مشكلة كبيرة فال
+
+252
+00:21:58,300 --> 00:22:02,040
+الهالوجين محتوى الهالوجين اتوم و الهالوجين اتوم
+
+253
+00:22:02,040 --> 00:22:06,020
+معروفين بالنسبة لنا فلورين و كلورين و برومين و
+
+254
+00:22:06,020 --> 00:22:08,620
+ايودين متصلين ب الهالوجروم
+
+255
+00:22:11,830 --> 00:22:16,410
+الـ الكالهيلايتز ممكن ان نصنفهم احنا الى primary و
+
+256
+00:22:16,410 --> 00:22:19,890
+secondary و tertiary الكلهيلايتز هذا المصطلح
+
+257
+00:22:19,890 --> 00:22:23,770
+بيفيدنا اثناء ما بنشرح عن الموضوع ايش بنقصد احنا
+
+258
+00:22:23,770 --> 00:22:27,490
+بال primary و ال secondary و ال tertiary او باللغة
+
+259
+00:22:27,490 --> 00:22:32,170
+العربية اولي و ثانوي و ثالثي ال primary و ال
+
+260
+00:22:32,170 --> 00:22:35,790
+secondary و ال tertiary الكلهيلايتز باجي انا على
+
+261
+00:22:35,790 --> 00:22:39,430
+ذرة الكربون اللى حاملة ال halogen يعني هذا الكربون
+
+262
+00:22:39,430 --> 00:22:45,830
+اللى حاملة ال halogen متصلة بكم كاربون؟ اذا متصلة
+
+263
+00:22:45,830 --> 00:22:50,610
+بكاربون واحدة بقول عنها primary لحظة ايه الكاربون
+
+264
+00:22:50,610 --> 00:22:54,950
+اللي حاملة الهالوجين متصلة بكم كاربون واحدة اذا
+
+265
+00:22:54,950 --> 00:22:58,170
+بقول عنها primary طبعا الناس الشاطرين بيصيروا
+
+266
+00:22:58,170 --> 00:23:02,530
+يفهموها يعني بشكل سهل بيقولوا لو الكاربون اللي
+
+267
+00:23:02,530 --> 00:23:08,540
+حاملة الهالوجين كانت CH2 لاحظوا CH2 و ال PR هي تلات
+
+268
+00:23:08,540 --> 00:23:13,000
+روابط إذا كده يظل متصلة مع واحدة هذا ال primary
+
+269
+00:23:13,000 --> 00:23:19,140
+فاللي بيميز ال primary وجود ال CH2 هالوجين الان ال
+
+270
+00:23:19,140 --> 00:23:24,540
+secondary الكربون اللى حامله ال halogen هي هي هذه
+
+271
+00:23:24,540 --> 00:23:27,380
+الكربون اللى حامله ال halogen متصلة بكم كربون؟
+
+272
+00:23:27,380 --> 00:23:31,000
+تنتين تنتين بقول عنها ال secondary الان ايش بيكون
+
+273
+00:23:31,000 --> 00:23:36,600
+موجود فيها؟ CH يعني كأنه ال primary CH2 halogen ال
+
+274
+00:23:36,600 --> 00:23:43,960
+secondary CH halogen لو اجيت على ال tertiary C
+
+275
+00:23:43,960 --> 00:23:49,220
+متصلة بالهالوجين طب و التلاتة روابط التانية متصلين
+
+276
+00:23:49,220 --> 00:23:54,600
+بالكاربون هاي C متصلة بالهالوجين و بعد هيك رابطة
+
+277
+00:23:54,600 --> 00:23:58,120
+تنتين تلاتة متصلة بالكاربون هذا النوع من ال
+
+278
+00:23:58,120 --> 00:24:02,340
+الكلهيلايت ش بسمي انا tertiary alkyl halides
+
+279
+00:24:02,340 --> 00:24:06,040
+فإذا قلنا او رسمنا اي الكلهيلايت و قلنا عنه
+
+280
+00:24:06,040 --> 00:24:09,400
+primary او secondary او tertiary بفترض ان هذه
+
+281
+00:24:09,400 --> 00:24:17,540
+الشغلة تكون واضحة عشان نفهم الـ Alkyl Halides محور
+
+282
+00:24:17,540 --> 00:24:22,220
+الـ Alkyl Halides هو رابطة الـ Carbon-Halogen يعني
+
+283
+00:24:22,220 --> 00:24:27,180
+بين الـ Carbon والـ X الـ Halogen في عنده رابطة
+
+284
+00:24:28,310 --> 00:24:32,150
+الان بدي افهم هذه الرابطة جيدا لان التفاعلات
+
+285
+00:24:32,150 --> 00:24:37,330
+هيعتمد على هذه الرابطة الـ carbon halogen bond جزء
+
+286
+00:24:37,330 --> 00:24:41,990
+من فهم هذا الموضوع ان اشوف فرق السالبية هنا هل
+
+287
+00:24:41,990 --> 00:24:47,310
+يترى هذه الرابطة polar ولا non polar عشان اشوف
+
+288
+00:24:47,310 --> 00:24:53,550
+الرابطة جيدا بدي اشوف ايش السالبية للكربون الكربون
+
+289
+00:24:53,550 --> 00:24:58,350
+سالبيته اتنين ونصال carbon ايش السالبية تبعته
+
+290
+00:24:58,350 --> 00:25:05,330
+اتنين و نص الان ال halogens كم واحد اه لاحظوا
+
+291
+00:25:05,330 --> 00:25:16,670
+floor سالبيته قداش اربعة و بروم تلاتة floor
+
+292
+00:25:16,670 --> 00:25:19,750
+تلاتة
+
+293
+00:25:19,750 --> 00:25:21,590
+بروم
+
+294
+00:25:23,000 --> 00:25:29,680
+2.8 و اليود 2.5 لاحظوا اليود و الكربون فيهم فرق
+
+295
+00:25:29,680 --> 00:25:34,620
+سالبية إذا الرابطة بشكل عام non polar مافيش فرق
+
+296
+00:25:34,620 --> 00:25:40,320
+سالبية الكربون 2.5 و اليود 2.5 لكن بعد ذلك مع
+
+297
+00:25:40,320 --> 00:25:45,140
+البروم و الكلور و الفلور في فرق سالبية لمصلحة
+
+298
+00:25:45,140 --> 00:25:50,080
+الهالوجين إذا بشكل عام مع هذول الذرات كيف بنتوقع
+
+299
+00:25:50,080 --> 00:25:57,150
+ال polarity للرابطة تكون إن الكربون تكون موجبة
+
+300
+00:25:57,150 --> 00:26:05,090
+والهالوجين سالبة واضح؟ أكبر فرق وين موجود؟ مع ال
+
+301
+00:26:05,090 --> 00:26:11,910
+floor أقل فرق العدم مع اليود الان لاحظوا معي كل ما
+
+302
+00:26:11,910 --> 00:26:16,390
+كان الفرق كبير كل ما جربت الرابط تشبه الرابط
+
+303
+00:26:16,390 --> 00:26:20,890
+الأيونية بمعنى أخر بتصير أقوى و بناء على ذلك لو انا
+
+304
+00:26:20,890 --> 00:26:25,270
+بدي اشوف قوة هذه الروابط اللي هي مع ال flour و ال
+
+305
+00:26:25,270 --> 00:26:29,330
+brom و ال chlor و ال iod هلاحظ انه و اقارنها بقوة
+
+306
+00:26:29,330 --> 00:26:32,750
+رابطة ال carbon-H اللي هي تعتبر بلغة الكيميا رابطة
+
+307
+00:26:32,750 --> 00:26:38,930
+قوية و مش سائل تنقصت ال carbon-H 413 كيلوجول لكل
+
+308
+00:26:38,930 --> 00:26:42,910
+مول بدي عشان اكسر هذه الرابطة الان ال carbon-flour
+
+309
+00:26:42,910 --> 00:26:48,150
+اقوى منهاليس؟ لأن فرق ال polarity عالي صارت تشبه
+
+310
+00:26:48,150 --> 00:26:52,990
+رابطة ايونية قوية ال carboniclor 346 ال
+
+311
+00:26:52,990 --> 00:26:59,910
+carboniclor 290 ال carboniclor 228 أقوى واحدة فيهم
+
+312
+00:26:59,910 --> 00:27:06,670
+مين؟ مع ال fluor الآن جزء أساسي في بناء الكيميا
+
+313
+00:27:06,670 --> 00:27:09,850
+تبع ال alkyl halides ان انا بدي أكسر الرابطة هذه
+
+314
+00:27:09,850 --> 00:27:15,000
+اللي بين ال carbon و ال halogen يعني سواء في تفاعل
+
+315
+00:27:15,000 --> 00:27:20,020
+الإبدال أو الحذف هذه الرابطة بدها تنكسر طيب ال
+
+316
+00:27:20,020 --> 00:27:23,480
+floor رابطته قوية؟ صعب، صعب، صعب، صعب، صعب، صعب،
+
+317
+00:27:23,480 --> 00:27:24,200
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+318
+00:27:24,200 --> 00:27:24,620
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+319
+00:27:24,620 --> 00:27:24,820
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+320
+00:27:24,820 --> 00:27:33,340
+صعب، صعب، صعب، صعب، صعب، صعب،
+
+321
+00:27:33,340 --> 00:27:41,060
+صعب، صعب، صعب،
+
+322
+00:27:41,060 --> 00:27:45,880
+صوبناء على ذلك عندما أعمل إبدال و أخد أمثلة على
+
+323
+00:27:45,880 --> 00:27:50,360
+الإبدال و أعمل حذف و في التفاعلين الإبدال و الحذف
+
+324
+00:27:50,360 --> 00:27:56,800
+تكسر فيه رابطة الأمثلة اللي هشوفها كلور بروم يود
+
+325
+00:27:56,800 --> 00:28:01,880
+مش هشوف أمثلة على ال floor لأن ال floor رابطة قوية
+
+326
+00:28:01,880 --> 00:28:06,380
+صعب كسرها و بناء على ذلك تفاعلات الإبدال و الحذف
+
+327
+00:28:06,380 --> 00:28:11,010
+مرتبطة بدول التلاتة ال floor برا الموضوع واضح
+
+328
+00:28:11,010 --> 00:28:17,150
+الفكرة؟ الآن
+
+329
+00:28:17,150 --> 00:28:22,890
+طالما احنا بنقول بدنا نكسر الرابط مع ال halogen
+
+330
+00:28:22,890 --> 00:28:28,230
+أني أضعف رابط فيهم اليود بناء على ذلك لو انا بعمل
+
+331
+00:28:28,230 --> 00:28:33,530
+تفاعل مع اليود بيكون سهل ولا صعب؟ سهل جدا البروم
+
+332
+00:28:33,530 --> 00:28:37,350
+بقعده في السهولة الكلور بقعده وعشان هيك لو انا بدي
+
+333
+00:28:37,350 --> 00:28:40,990
+اشوف ال rate of reaction لو كنت بفعل يود وبروم
+
+334
+00:28:40,990 --> 00:28:46,270
+وكلور مقارنة بعض و بالبعض أسرع تفاعل مع اليود أسرع
+
+335
+00:28:46,270 --> 00:28:51,580
+من البروم أسرع من الكلور كلور والسبب قوة الرابطة
+
+336
+00:28:51,580 --> 00:28:56,100
+لأن هنا في رابطة ضعيفة بتنكسر بسهولة واضح الرابطة
+
+337
+00:28:56,100 --> 00:29:00,340
+مع اليود رابطة ضعيفة بتنكسر بسهولة يمكن هذا الكلام
+
+338
+00:29:00,340 --> 00:29:04,100
+حتى في الحياة العملية بتلاحظوا حتى في الحياة
+
+339
+00:29:04,100 --> 00:29:09,320
+العملية بتلاحظوا كثير من الأدوية مثلا موجود مكون
+
+340
+00:29:09,320 --> 00:29:15,660
+أساسي منها اليود هذه الأدوية لو اتعرضت لشوية حرارة
+
+341
+00:29:15,660 --> 00:29:20,980
+بسيطة أو لضوء الشمسبتنكسر الرابطة اللي معاها طبعا
+
+342
+00:29:20,980 --> 00:29:24,240
+كنا انكسرت الرابطة إذا الدواء كله إيش صار فيه؟ خير
+
+343
+00:29:24,240 --> 00:29:28,680
+وعشان هيك هنلاحظ أن هذا النوع من الأدوية بيحطوه في
+
+344
+00:29:28,680 --> 00:29:33,800
+جزايز غامقة لونها بني و غالبا بيحفظوه بعيدا عن
+
+345
+00:29:33,800 --> 00:29:38,930
+الضوء و الحرارة و أحيانا في حرارة باردة يعني شوف
+
+346
+00:29:38,930 --> 00:29:43,690
+كيف لما مراتب تقرأ على شيء معين يحفظ بعيدا عن
+
+347
+00:29:43,690 --> 00:29:46,730
+الضوء و الحرارة ليش؟ بيكون هذا الشيء المعين فيه
+
+348
+00:29:46,730 --> 00:29:52,790
+روابط ضعيفة حتى حرارة الجو حتى على ضو الشمس ممكن
+
+349
+00:29:52,790 --> 00:29:58,410
+تتكسر فبنصير نحط مثلا جزاز بن يمنع أنه يدخل الضوء
+
+350
+00:29:58,410 --> 00:30:02,030
+بشكل كبير بنقبل حطه بعيد عن الضوء و عن الحرارة
+
+351
+00:30:02,030 --> 00:30:06,870
+ممكن يحتفظ فيه بالثلاجة على سبيل المثال كل هذا
+
+352
+00:30:06,870 --> 00:30:12,670
+نتيجة فهم قوة الروابط الكيميائية و دائما انتوا
+
+353
+00:30:12,670 --> 00:30:16,630
+يعني جزء منكوا في علوم الصحة و جزء في غيرها لحتى
+
+354
+00:30:16,630 --> 00:30:20,190
+تتعاملوا مع أدوى او اشياء اول ما بدكوا تمسكوا اي
+
+355
+00:30:20,190 --> 00:30:28,090
+عبو الدواء شغلتين الشيء الاول صحتكما قروا الكلام
+
+356
+00:30:28,090 --> 00:30:33,550
+اللي عليها، ضار، سام، يجوز أن نشمه، لا يجوز، كل
+
+357
+00:30:33,550 --> 00:30:38,050
+هذا الكلام مكتوب على العبوة وله إشارات معينة،
+
+358
+00:30:38,050 --> 00:30:42,230
+بيحرق كوروسف مثلا زي أحماض إذا انكبت على الإيد
+
+359
+00:30:42,230 --> 00:30:46,200
+بتحرقها، إذا انكبت على الملابس بتحرقها منفعش
+
+360
+00:30:46,200 --> 00:30:49,400
+الإنسان يتعامل مع أشياء و هو مش عارفها يكون
+
+361
+00:30:49,400 --> 00:30:55,240
+بيتعامل مع سم و بيسيبه ينكب على إيده و مابيغسلش و
+
+362
+00:30:55,240 --> 00:31:00,040
+مابياخدش احتياطات ولا بيلبس gloves ولا أي شيء و
+
+363
+00:31:00,040 --> 00:31:06,940
+شغلت تانية بيكون مكتوب عندكم كلمة store احفظه وانت
+
+364
+00:31:06,940 --> 00:31:12,160
+احفظه طبعا شغل اضافية بيكون عندكوا expire date انه
+
+365
+00:31:12,160 --> 00:31:16,120
+هذا بعد فترة معينة ما تفتحوه بيخرب بالذات كتير
+
+366
+00:31:16,120 --> 00:31:20,800
+مركبات بيكون مسكر عليها بشكل محكم لكن لما تفتحوها
+
+367
+00:31:20,800 --> 00:31:26,970
+تتفعل مع oxygen الهواء ممكن تتفاعل مع الهوى نفسه أو
+
+368
+00:31:26,970 --> 00:31:31,370
+تمتص رطوبة من الهوى و بناء على ذلك تخرب فهتلاحظوا
+
+369
+00:31:31,370 --> 00:31:35,990
+بعض المراكبات مكتوب عليها لا يستعمل بعد أسبوع أو
+
+370
+00:31:35,990 --> 00:31:41,050
+أسبوعين من فتح العبوة كل إنسان بدي يتعامل بأدوية
+
+371
+00:31:41,050 --> 00:31:45,050
+أو pre agents بدي يكون منتبه لهذه الأمور وإلا
+
+372
+00:31:45,050 --> 00:31:47,470
+بيجعل بإيش؟ بالغلط
+
+373
+00:31:51,720 --> 00:31:57,640
+الان لو اجينا على التفاعلات تبعت ال alkyl halides
+
+374
+00:31:57,640 --> 00:32:04,320
+ممكن البعض يقول طب احنا ما أعطيناش التسمية مشعلة
+
+375
+00:32:04,320 --> 00:32:09,760
+جديدة مرت عليكم لما أخدنا ال alkenes يعني لو انا
+
+376
+00:32:09,760 --> 00:32:15,600
+جبتلكوا هذا المركب هذا
+
+377
+00:32:15,600 --> 00:32:22,830
+ال alkyl halide مين تسميه؟ احد اتنين تلاتة اربعة
+
+378
+00:32:22,830 --> 00:32:30,340
+خمسة بنتين اثنان كلورو اثنان مثل بنتين اخذنا
+
+379
+00:32:30,340 --> 00:32:36,180
+التسمية ولا لأ؟ اخذنا التسمية طيب واحدة بتقول ماشي
+
+380
+00:32:36,180 --> 00:32:40,800
+التسمية اخذناها طيب و ال preparation التحضير هو
+
+381
+00:32:40,800 --> 00:32:45,220
+احنا عادة لما بندرس عائلة كيميائية اول اشي بنتعرف
+
+382
+00:32:45,220 --> 00:32:49,420
+على العائلة بعدين بناخد ال nomenclature التسمية
+
+383
+00:32:49,420 --> 00:32:54,500
+بعدين التحضير بعدين التفاعلات احنا عمال جاعدين
+
+384
+00:32:54,500 --> 00:33:00,060
+بنفض جزء التسمية وشوفنا اننا اخذناها طب و جزء
+
+385
+00:33:00,060 --> 00:33:04,800
+التحضير اخذناها
+
+386
+00:33:04,800 --> 00:33:09,420
+من أكثر من طريقة اخذناها بأكثر من طريقة لما كنا
+
+387
+00:33:09,420 --> 00:33:13,220
+نيجي نقولكم مثلا ابرو بيل و اعملوله chlorination
+
+388
+00:33:13,220 --> 00:33:20,960
+شو كنتوا تطلعوا؟ One Chloro, Two Chloro مش ه
+
+445
+00:38:15,840 --> 00:38:22,560
+سالب للنيوكليوفايل سالب بيجي إيش بيطلعك باله؟ سالب
+
+446
+00:38:23,370 --> 00:38:27,830
+السالب هاجم على الكربون الموجب، طرد سالب إجا سالب،
+
+447
+00:38:27,830 --> 00:38:33,550
+طرد سالب، إجا موجب، طرد موجب أخدنا في البنزين
+
+448
+00:38:33,550 --> 00:38:38,190
+الإبدال إيش كان؟ موجب مكان موجب، سميناها
+
+449
+00:38:38,190 --> 00:38:41,950
+Electrophilic Substitution الآن هنا بدو ييجي سالب
+
+450
+00:38:41,950 --> 00:38:47,030
+مكان سالب، يعني إيش اللي بدو يطرد؟ ال X مع
+
+451
+00:38:47,030 --> 00:38:52,340
+إلكتروناته، شو اللي بدو يهاجم؟ لنيوكليوفايل و بناء
+
+452
+00:38:52,340 --> 00:38:56,880
+على ذلك بيصير المفروض فينا نتذكر ايش معنى
+
+453
+00:38:56,880 --> 00:39:01,040
+النيوكليوفايل اللي بدو يهاجم هنا و يحل محل ال X
+
+454
+00:39:01,040 --> 00:39:06,220
+ولذلك المرة القادمة هنبدأ من كلمة ايش الـ
+
+455
+00:39:06,220 --> 00:39:11,190
+Nucleophilic Substitution يعني نبدأ نتعرف على الـ
+
+456
+00:39:11,190 --> 00:39:14,950
+nucleophile اللي بده يهاجم ويبدأ التفاعل لأن الـ
+
+457
+00:39:14,950 --> 00:39:18,790
+nucleophile هو السالب اللي بده يهاجم ويحل محل
+
+458
+00:39:18,790 --> 00:39:23,630
+الهالوجين السالبة يعمل عملية الإبدال شكرا
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..29d3b37dd2d510479697d54c52c55b8a9345d53a
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2259, "start": 21.21, "end": 22.59, "text": "بسم الله الرحمن الرحيم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640], "avg_logprob": -0.03930663987994194, "compression_ratio": 1.0789473684210527, "no_speech_prob": 0.0, "words": [{"start": 21.21, "end": 21.53, "word": "بسم", "probability": 0.908203125}, {"start": 21.53, "end": 21.73, "word": " الله", "probability": 0.9638671875}, {"start": 21.73, "end": 22.11, "word": " الرحمن", "probability": 0.9713541666666666}, {"start": 22.11, "end": 22.59, "word": " الرحيم", "probability": 0.99462890625}], "temperature": 1.0}, {"id": 2, "seek": 5304, "start": 23.86, "end": 53.04, "text": "باقي عندنا في موضوع التفاعلات او التفاعلات المرتبطة بال stereochemistry شغلتين بسيطات احنا اتكلمنا في الاول على نقطة كتير مهمة او على تفاعل كتير مهم قولنا دائما في المختبر بالوضع الطبيعي لما نعمل generation of a chiral center بيطلع عندى racemic mixture equal mixture of enantiomers و هذا بده غلبة و بده فصل و ما إلى ذلك", "tokens": [3555, 995, 38436, 43242, 8315, 8978, 3714, 2407, 11242, 45367, 16712, 5172, 995, 30241, 9307, 1975, 2407, 16712, 5172, 995, 30241, 9307, 9673, 43500, 3555, 9566, 3660, 20666, 29029, 48353, 13412, 17082, 1211, 2655, 9957, 4724, 3794, 1829, 9566, 9307, 1975, 5016, 8315, 1975, 2655, 4117, 19528, 8315, 8978, 42963, 12610, 15844, 8717, 47432, 3660, 9122, 2655, 13546, 3714, 16095, 3660, 1975, 2407, 15844, 6055, 5172, 995, 30241, 9122, 2655, 13546, 3714, 16095, 12174, 12610, 8315, 11778, 16373, 15042, 8978, 9673, 46456, 26890, 20666, 2407, 11242, 3615, 41950, 21292, 3615, 1829, 5296, 15042, 8717, 25957, 1211, 5125, 295, 257, 23782, 304, 3056, 4724, 1829, 9566, 1211, 3615, 43242, 7578, 4129, 3438, 9925, 2681, 9925, 295, 465, 11520, 298, 433, 4032, 23758, 47525, 3224, 32771, 46152, 3660, 4032, 47525, 3224, 6156, 36520, 4032, 19446, 30731, 29910, 23275], "avg_logprob": -0.17016424053776874, "compression_ratio": 1.7964285714285715, "no_speech_prob": 5.960464477539063e-08, 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Ethyl و COH و بH، الآن هذا الـ Chiral Center عليه كام رابطة", "tokens": [28820, 19446, 39182, 29910, 23275, 7251, 34268, 26890, 1975, 1829, 8592, 22807, 6055, 5172, 995, 30241, 45030, 25708, 18871, 2423, 39184, 761, 35083, 5169, 4032, 46958, 5016, 27188, 4117, 25720, 22807, 37495, 22653, 50113, 15040, 8978, 23758, 9673, 31747, 3555, 12399, 18871, 16254, 34105, 41850, 761, 35083, 5169, 44650, 36520, 4724, 39184, 48602, 5088, 4032, 4724, 39184, 10540, 5088, 4032, 3002, 39, 4032, 4724, 39, 12399, 6024, 48506, 23758, 2423, 39184, 761, 35083, 5169, 47356, 9122, 10943, 12602, 16758, 9566, 3660], "avg_logprob": -0.27191312247660104, "compression_ratio": 1.5816326530612246, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 87.81, "end": 88.25, "word": "كل", "probability": 0.57666015625}, {"start": 88.25, "end": 88.75, "word": " ما", "probability": 0.68798828125}, {"start": 88.75, "end": 89.09, "word": " بعد", "probability": 0.92431640625}, {"start": 89.09, "end": 89.47, "word": " 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"word": " بمجموعة", "probability": 0.9635416666666666}, {"start": 120.34, "end": 120.68, "word": " O", "probability": 0.94677734375}, {"start": 120.68, "end": 121.2, "word": " Ethyl", "probability": 0.711669921875}, {"start": 121.2, "end": 122.14, "word": " بمعنى", "probability": 0.97138671875}, {"start": 122.14, "end": 122.46, "word": " في", "probability": 0.9296875}, {"start": 122.46, "end": 122.9, "word": " الكيميا", "probability": 0.8263346354166666}, {"start": 122.9, "end": 123.1, "word": " هذا", "probability": 0.830078125}, {"start": 123.1, "end": 123.54, "word": " التفاعل", "probability": 0.890869140625}, {"start": 123.54, "end": 124.5, "word": " هنتعلمه", "probability": 0.87958984375}, {"start": 124.5, "end": 125.52, "word": " بنبدل", "probability": 0.9402669270833334}, {"start": 125.52, "end": 126.1, "word": " فيه", "probability": 0.873291015625}, {"start": 126.1, "end": 126.42, "word": " ال", "probability": 0.96435546875}, {"start": 126.42, "end": 126.96, "word": " acid", "probability": 0.93408203125}, {"start": 126.96, "end": 127.34, "word": " ل", "probability": 0.8359375}, {"start": 127.34, "end": 127.56, "word": " E", "probability": 0.69140625}, {"start": 127.56, "end": 127.96, "word": " star", "probability": 0.26904296875}], "temperature": 1.0}, {"id": 7, "seek": 14291, "start": 128.86, "end": 142.92, "text": "باستعمال التفاعل مع الكحول شيلت الـ OH و خلتها ايش؟ O Ethan الان هذه الأربع رواضة كسرت جزء منها؟ لأ وبناء على ذلك", "tokens": [3555, 995, 14851, 25957, 6027, 16712, 5172, 995, 30241, 20449, 33251, 5016, 12610, 13412, 26895, 2655, 2423, 39184, 13931, 4032, 16490, 1211, 2655, 11296, 1975, 1829, 8592, 22807, 422, 23984, 2423, 7649, 29538, 16247, 25513, 3615, 12602, 2407, 46958, 3660, 9122, 3794, 43500, 10874, 11622, 38207, 9154, 11296, 22807, 5296, 10721, 46599, 1863, 16606, 15844, 29910, 23275], "avg_logprob": -0.3041487182008809, "compression_ratio": 1.3517241379310345, "no_speech_prob": 2.086162567138672e-06, "words": [{"start": 128.86, "end": 129.72, "word": "باستعمال", "probability": 0.910546875}, {"start": 129.72, "end": 130.38, "word": " التفاعل", "probability": 0.9376220703125}, {"start": 130.38, "end": 130.58, "word": " مع", "probability": 0.958984375}, {"start": 130.58, "end": 131.18, "word": " الكحول", "probability": 0.994140625}, {"start": 131.18, "end": 132.0, "word": " شيلت", "probability": 0.6923014322916666}, {"start": 132.0, "end": 132.34, "word": " الـ", "probability": 0.4974365234375}, {"start": 132.34, "end": 132.82, "word": " OH", "probability": 0.56201171875}, {"start": 132.82, "end": 133.56, "word": " و", "probability": 0.875}, {"start": 133.56, "end": 134.06, "word": " خلتها", "probability": 0.74505615234375}, {"start": 134.06, "end": 135.16, "word": " ايش؟", "probability": 0.575225830078125}, {"start": 135.16, "end": 135.4, "word": " O", "probability": 0.52197265625}, {"start": 135.4, "end": 135.74, "word": " Ethan", "probability": 0.279052734375}, {"start": 135.74, "end": 136.46, "word": " الان", "probability": 0.58026123046875}, {"start": 136.46, "end": 137.16, "word": " هذه", "probability": 0.6728515625}, {"start": 137.16, "end": 137.76, "word": " الأربع", "probability": 0.8577473958333334}, {"start": 137.76, "end": 138.44, "word": " رواضة", "probability": 0.72393798828125}, {"start": 138.44, "end": 139.24, "word": " كسرت", "probability": 0.8089192708333334}, {"start": 139.24, "end": 139.66, "word": " جزء", "probability": 0.994140625}, {"start": 139.66, "end": 140.46, "word": " منها؟", "probability": 0.9090169270833334}, {"start": 140.46, "end": 141.06, "word": " لأ", "probability": 0.80908203125}, {"start": 141.06, "end": 141.94, "word": " وبناء", "probability": 0.77734375}, {"start": 141.94, "end": 142.26, "word": " على", "probability": 0.853515625}, {"start": 142.26, "end": 142.92, "word": " ذلك", "probability": 0.98974609375}], "temperature": 1.0}, {"id": 8, "seek": 16628, "start": 143.88, "end": 166.28, "text": "الجيومتري حوالين الكايرال كاربون الشكل اللذس حوالين الكايرال كاربون بيضل زي ما هو فأنا كأن بعمل عملية ايش نسخ و لصق بلغة الكمبيوتر يعني باجي بعمل نسخ لهذا بكل موابط و لاحظوا ال H باتجاه ال CO باتجاه ال CH3 ال إثل بحطه هنا و بعمل التغيير اللي عنده", "tokens": [6027, 7435, 1829, 20498, 2655, 16572, 11331, 2407, 6027, 9957, 33251, 995, 13546, 6027, 9122, 9640, 3555, 11536, 25124, 28820, 13672, 8848, 3794, 11331, 2407, 6027, 9957, 33251, 995, 13546, 6027, 9122, 9640, 3555, 11536, 4724, 1829, 11242, 1211, 30767, 1829, 19446, 31439, 6156, 10721, 8315, 9122, 33456, 4724, 25957, 1211, 6225, 42213, 10632, 1975, 1829, 8592, 8717, 3794, 9778, 4032, 5296, 9381, 4587, 4724, 1211, 17082, 3660, 2423, 24793, 21292, 35473, 2288, 37495, 22653, 4724, 26108, 1829, 4724, 25957, 1211, 8717, 3794, 9778, 46740, 15730, 4724, 28820, 3714, 14407, 3555, 9566, 4032, 20193, 5016, 19913, 14407, 2423, 389, 4724, 9307, 7435, 40294, 2423, 3002, 4724, 9307, 7435, 40294, 2423, 5995, 18, 2423, 11933, 12984, 1211, 4724, 5016, 9566, 3224, 34105, 4032, 4724, 25957, 1211, 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0.6488037109375}, {"start": 148.96, "end": 149.3, "word": " زي", "probability": 0.8369140625}, {"start": 149.3, "end": 149.42, "word": " ما", "probability": 0.95068359375}, {"start": 149.42, "end": 149.7, "word": " هو", "probability": 0.99365234375}, {"start": 149.7, "end": 150.6, "word": " فأنا", "probability": 0.7578125}, {"start": 150.6, "end": 151.06, "word": " كأن", "probability": 0.7998046875}, {"start": 151.06, "end": 151.48, "word": " بعمل", "probability": 0.8681640625}, {"start": 151.48, "end": 152.0, "word": " عملية", "probability": 0.9861653645833334}, {"start": 152.0, "end": 152.42, "word": " ايش", "probability": 0.6396484375}, {"start": 152.42, "end": 153.12, "word": " نسخ", "probability": 0.8639322916666666}, {"start": 153.12, "end": 153.26, "word": " و", "probability": 0.9228515625}, {"start": 153.26, "end": 153.62, "word": " لصق", "probability": 0.7819010416666666}, {"start": 153.62, "end": 154.1, "word": " بلغة", "probability": 0.89892578125}, {"start": 154.1, "end": 154.92, "word": " الكمبيوتر", "probability": 0.96328125}, {"start": 154.92, "end": 155.36, "word": " يعني", "probability": 0.86572265625}, {"start": 155.36, "end": 155.88, "word": " باجي", "probability": 0.7662760416666666}, {"start": 155.88, "end": 156.54, "word": " بعمل", "probability": 0.9166666666666666}, {"start": 156.54, "end": 156.98, "word": " نسخ", "probability": 0.9962565104166666}, {"start": 156.98, "end": 157.58, "word": " لهذا", "probability": 0.887939453125}, {"start": 157.58, "end": 158.2, "word": " بكل", "probability": 0.975341796875}, {"start": 158.2, "end": 158.82, "word": " موابط", "probability": 0.8055419921875}, {"start": 158.82, "end": 158.96, "word": " و", "probability": 0.482666015625}, {"start": 158.96, "end": 159.26, "word": " لاحظوا", "probability": 0.875244140625}, {"start": 159.26, "end": 159.32, "word": " ال", "probability": 0.92529296875}, {"start": 159.32, "end": 159.52, "word": " H", "probability": 0.5927734375}, {"start": 159.52, "end": 160.22, "word": " باتجاه", "probability": 0.8907470703125}, {"start": 160.22, "end": 160.58, "word": " ال", "probability": 0.72607421875}, {"start": 160.58, "end": 160.9, "word": " CO", "probability": 0.3984375}, {"start": 160.9, "end": 161.54, "word": " باتجاه", "probability": 0.82330322265625}, {"start": 161.54, "end": 161.66, "word": " ال", "probability": 0.5}, {"start": 161.66, "end": 162.18, "word": " CH3", "probability": 0.924560546875}, {"start": 162.18, "end": 162.36, "word": " ال", "probability": 0.57275390625}, {"start": 162.36, "end": 162.82, "word": " إثل", "probability": 0.6351725260416666}, {"start": 162.82, "end": 163.74, "word": " بحطه", "probability": 0.9542236328125}, {"start": 163.74, "end": 164.1, "word": " هنا", "probability": 0.9501953125}, {"start": 164.1, "end": 164.6, "word": " و", "probability": 0.81103515625}, {"start": 164.6, "end": 165.0, "word": " بعمل", "probability": 0.96923828125}, {"start": 165.0, "end": 165.54, "word": " التغيير", "probability": 0.97021484375}, {"start": 165.54, "end": 165.78, "word": " اللي", "probability": 0.951171875}, {"start": 165.78, "end": 166.28, "word": " عنده", "probability": 0.72900390625}], "temperature": 1.0}, {"id": 9, "seek": 18916, "start": 166.64, "end": 189.16, "text": "و بناء على ذلك بنقول انه تم عنده retention of configuration يعني الشكل ضل زي ما هو اتجاه الاربع روابط اللي محيطين بال chiral center ضالهم ايش زي ما هو لو انا بدي اعطيكم مثال يعني تخيلوا مثلا انا بهذا الشكل هينعمل chiral center من اربع شغلات", "tokens": [2407, 44945, 16606, 15844, 29910, 23275, 44945, 39648, 16472, 3224, 46811, 43242, 3224, 22871, 295, 11694, 37495, 22653, 25124, 28820, 48812, 1211, 30767, 1829, 19446, 31439, 1975, 2655, 7435, 40294, 2423, 9640, 3555, 3615, 12602, 14407, 3555, 9566, 13672, 1829, 3714, 5016, 1829, 9566, 9957, 20666, 23782, 304, 3056, 48812, 6027, 16095, 1975, 1829, 8592, 30767, 1829, 19446, 31439, 45164, 1975, 8315, 4724, 16254, 1975, 3615, 9566, 1829, 24793, 50113, 6027, 37495, 22653, 6055, 9778, 26895, 14407, 50113, 15040, 1975, 8315, 39627, 15730, 25124, 28820, 8032, 9957, 25957, 1211, 23782, 304, 3056, 9154, 1975, 25513, 3615, 13412, 17082, 1211, 9307], "avg_logprob": -0.20142327440847266, "compression_ratio": 1.7309417040358743, "no_speech_prob": 0.0, "words": [{"start": 166.64, "end": 166.82, "word": "و", "probability": 0.29541015625}, {"start": 166.82, "end": 167.16, "word": " بناء", "probability": 0.822509765625}, {"start": 167.16, "end": 167.38, "word": " على", "probability": 0.67333984375}, {"start": 167.38, "end": 167.74, "word": " ذلك", "probability": 0.9873046875}, {"start": 167.74, "end": 168.12, "word": " بنقول", "probability": 0.60528564453125}, {"start": 168.12, "end": 168.48, "word": " انه", "probability": 0.72265625}, {"start": 168.48, "end": 168.72, "word": " تم", "probability": 0.9677734375}, {"start": 168.72, "end": 169.32, "word": " عنده", "probability": 0.828125}, {"start": 169.32, "end": 170.14, "word": " retention", "probability": 0.78955078125}, {"start": 170.14, "end": 170.66, "word": " of", "probability": 0.970703125}, {"start": 170.66, "end": 171.36, "word": " configuration", "probability": 0.8779296875}, {"start": 171.36, "end": 171.72, "word": " يعني", "probability": 0.809814453125}, {"start": 171.72, "end": 172.74, "word": " الشكل", "probability": 0.961669921875}, {"start": 172.74, "end": 173.4, "word": " ضل", "probability": 0.3272705078125}, {"start": 173.4, "end": 173.86, "word": " زي", "probability": 0.87451171875}, {"start": 173.86, "end": 174.0, "word": " ما", "probability": 0.95556640625}, {"start": 174.0, "end": 174.36, "word": " هو", "probability": 0.99462890625}, {"start": 174.36, "end": 175.4, "word": " اتجاه", "probability": 0.9312744140625}, {"start": 175.4, "end": 176.02, "word": " الاربع", "probability": 0.803466796875}, {"start": 176.02, "end": 176.74, "word": " روابط", "probability": 0.935546875}, {"start": 176.74, "end": 177.26, "word": " اللي", "probability": 0.89794921875}, {"start": 177.26, "end": 178.06, "word": " محيطين", "probability": 0.9685546875}, {"start": 178.06, "end": 178.36, "word": " بال", "probability": 0.89453125}, {"start": 178.36, "end": 178.94, "word": " chiral", "probability": 0.6796875}, {"start": 178.94, "end": 179.5, "word": " center", "probability": 0.83251953125}, {"start": 179.5, "end": 180.22, "word": " ضالهم", "probability": 0.7278645833333334}, {"start": 180.22, "end": 180.66, "word": " ايش", "probability": 0.87744140625}, {"start": 180.66, "end": 181.54, "word": " زي", "probability": 0.7235107421875}, {"start": 181.54, "end": 181.66, "word": " ما", "probability": 0.9765625}, {"start": 181.66, "end": 181.92, "word": " هو", "probability": 0.9912109375}, {"start": 181.92, "end": 182.66, "word": " لو", "probability": 0.83837890625}, {"start": 182.66, "end": 182.86, "word": " انا", "probability": 0.86083984375}, {"start": 182.86, "end": 183.08, "word": " بدي", "probability": 0.41546630859375}, {"start": 183.08, "end": 183.44, "word": " اعطيكم", "probability": 0.857666015625}, {"start": 183.44, "end": 183.94, "word": " مثال", "probability": 0.95849609375}, {"start": 183.94, "end": 184.3, "word": " يعني", "probability": 0.7236328125}, {"start": 184.3, "end": 184.8, "word": " تخيلوا", "probability": 0.9716796875}, {"start": 184.8, "end": 185.22, "word": " مثلا", "probability": 0.960205078125}, {"start": 185.22, "end": 185.8, "word": " انا", "probability": 0.908935546875}, {"start": 185.8, "end": 186.2, "word": " بهذا", "probability": 0.974365234375}, {"start": 186.2, "end": 186.6, "word": " الشكل", "probability": 0.98828125}, {"start": 186.6, "end": 187.2, "word": " هينعمل", "probability": 0.78863525390625}, {"start": 187.2, "end": 187.7, "word": " chiral", "probability": 0.955810546875}, {"start": 187.7, "end": 188.08, "word": " center", "probability": 0.93994140625}, {"start": 188.08, "end": 188.28, "word": " من", "probability": 0.98046875}, {"start": 188.28, "end": 188.6, "word": " اربع", "probability": 0.9186197916666666}, {"start": 188.6, "end": 189.16, "word": " شغلات", "probability": 0.9896240234375}], "temperature": 1.0}, {"id": 10, "seek": 21704, "start": 189.74, "end": 217.04, "text": "وأتيت أعمل التفاعل هنا كان مافيش في إيدي جلم امسكت جلم هل غيرت في اتجاه الأربع روابط ولا في عند retention of configuration في عند retention of configuration إذا التفاعل بعيدا عن ال chiral center بتم في retention of configuration معنى retention of configuration أن اتجاهات الروابط الأربع تبقى كما هي لم نكسر شيء حولها", "tokens": [2407, 10721, 31371, 2655, 5551, 25957, 1211, 16712, 5172, 995, 30241, 34105, 25961, 19446, 41185, 8592, 8978, 11933, 1829, 16254, 10874, 19528, 1975, 2304, 3794, 4117, 2655, 10874, 19528, 8032, 1211, 32771, 13546, 2655, 8978, 1975, 2655, 7435, 40294, 16247, 25513, 3615, 12602, 14407, 3555, 9566, 49429, 8978, 43242, 22871, 295, 11694, 8978, 43242, 22871, 295, 11694, 11933, 15730, 16712, 5172, 995, 30241, 45030, 25708, 995, 18871, 2423, 23782, 304, 3056, 39894, 2304, 8978, 22871, 295, 11694, 20449, 1863, 7578, 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"probability": 0.498291015625}, {"start": 211.66, "end": 212.4, "word": " اتجاهات", "probability": 0.94267578125}, {"start": 212.4, "end": 212.98, "word": " الروابط", "probability": 0.956787109375}, {"start": 212.98, "end": 213.48, "word": " الأربع", "probability": 0.8722330729166666}, {"start": 213.48, "end": 214.18, "word": " تبقى", "probability": 0.9910888671875}, {"start": 214.18, "end": 215.04, "word": " كما", "probability": 0.964599609375}, {"start": 215.04, "end": 215.38, "word": " هي", "probability": 0.91015625}, {"start": 215.38, "end": 215.82, "word": " لم", "probability": 0.84521484375}, {"start": 215.82, "end": 216.3, "word": " نكسر", "probability": 0.9547119140625}, {"start": 216.3, "end": 216.6, "word": " شيء", "probability": 0.848388671875}, {"start": 216.6, "end": 217.04, "word": " حولها", "probability": 0.99365234375}], "temperature": 1.0}, {"id": 11, "seek": 23362, "start": 217.6, "end": 233.62, "text": "كذلك الحال هنا احنا حاطين مثال تاني لو فعلنا هذا المركب يعلن الكايرال سنتر بدلنا هذه ال O H خلناها C double bond O باستعمال اكسدة ابعام المؤكسل عادة بنسميه", "tokens": [4117, 8848, 23275, 21542, 6027, 34105, 1975, 5016, 8315, 11331, 41193, 9957, 50113, 6027, 6055, 7649, 1829, 45164, 6156, 30241, 8315, 23758, 9673, 31747, 3555, 7251, 30241, 1863, 33251, 995, 13546, 6027, 8608, 29399, 2288, 47525, 1211, 8315, 29538, 2423, 422, 389, 16490, 1211, 8315, 11296, 383, 3834, 6086, 422, 4724, 995, 14851, 25957, 6027, 1975, 4117, 3794, 41891, 48127, 3615, 10943, 9673, 33604, 4117, 3794, 1211, 6225, 18513, 3660, 44945, 38251, 1829, 3224], "avg_logprob": -0.29145832777023317, "compression_ratio": 1.552325581395349, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 217.6, "end": 218.18, "word": "كذلك", "probability": 0.7083333333333334}, {"start": 218.18, "end": 218.76, "word": " الحال", "probability": 0.915771484375}, {"start": 218.76, "end": 219.4, "word": " هنا", "probability": 0.458251953125}, {"start": 219.4, "end": 219.7, "word": " احنا", "probability": 0.8644205729166666}, {"start": 219.7, "end": 220.14, "word": " حاطين", "probability": 0.8103841145833334}, {"start": 220.14, "end": 220.66, "word": " مثال", "probability": 0.9814453125}, {"start": 220.66, "end": 221.28, "word": " تاني", "probability": 0.8650716145833334}, {"start": 221.28, "end": 221.78, "word": " لو", "probability": 0.876953125}, {"start": 221.78, "end": 222.3, "word": " فعلنا", "probability": 0.9733072916666666}, {"start": 222.3, "end": 222.6, "word": " هذا", "probability": 0.95947265625}, {"start": 222.6, "end": 223.24, "word": " المركب", "probability": 0.84228515625}, {"start": 223.24, "end": 223.64, "word": " يعلن", "probability": 0.4618326822916667}, {"start": 223.64, "end": 224.26, "word": " الكايرال", "probability": 0.67205810546875}, {"start": 224.26, "end": 224.88, "word": " سنتر", "probability": 0.7635091145833334}, {"start": 224.88, "end": 226.36, "word": " بدلنا", "probability": 0.86572265625}, {"start": 226.36, "end": 226.86, "word": " هذه", "probability": 0.82666015625}, {"start": 226.86, "end": 227.08, "word": " ال", "probability": 0.86767578125}, {"start": 227.08, "end": 227.3, "word": " O", "probability": 0.1448974609375}, {"start": 227.3, "end": 227.74, "word": " H", "probability": 0.55712890625}, {"start": 227.74, "end": 228.78, "word": " خلناها", "probability": 0.7828369140625}, {"start": 228.78, "end": 228.92, "word": " C", "probability": 0.278076171875}, {"start": 228.92, "end": 229.14, "word": " double", "probability": 0.318359375}, {"start": 229.14, "end": 229.48, "word": " bond", "probability": 0.90673828125}, {"start": 229.48, "end": 229.62, "word": " O", "probability": 0.93701171875}, {"start": 229.62, "end": 230.26, "word": " باستعمال", "probability": 0.964453125}, {"start": 230.26, "end": 230.86, "word": " اكسدة", "probability": 0.79498291015625}, {"start": 230.86, "end": 231.74, "word": " ابعام", "probability": 0.826171875}, {"start": 231.74, "end": 232.36, "word": " المؤكسل", "probability": 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كسرت روابط بالتصيلة بال chiral center مرة تانية في عندي retention of configuration إذا ال reaction away from a chiral center results in retention of configuration الآن بهمني أعطي بس ملاحظة خفيفة", "tokens": [6027, 2655, 17082, 13546, 39182, 11296, 19446, 9122, 3794, 43500, 12602, 14407, 3555, 9566, 20666, 2655, 9381, 26895, 3660, 20666, 23782, 304, 3056, 3714, 25720, 6055, 7649, 10632, 8978, 43242, 1829, 22871, 295, 11694, 11933, 15730, 2423, 5480, 1314, 490, 257, 23782, 304, 3056, 3542, 294, 22871, 295, 11694, 6024, 48506, 4724, 16095, 22653, 5551, 3615, 9566, 1829, 4724, 3794, 3714, 15040, 5016, 19913, 3660, 16490, 5172, 33911, 3660], "avg_logprob": -0.25915177166461945, "compression_ratio": 1.5078534031413613, "no_speech_prob": 0.0, "words": [{"start": 251.22, "end": 251.92, "word": "التغير", "probability": 0.8763427734375}, {"start": 251.92, "end": 252.52, "word": " بعدها", "probability": 0.9130859375}, {"start": 252.52, "end": 252.64, "word": " ما", "probability": 0.31494140625}, 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257.88, "end": 258.72, "word": " configuration", "probability": 0.85888671875}, {"start": 258.72, "end": 259.32, "word": " إذا", "probability": 0.6572265625}, {"start": 259.32, "end": 259.54, "word": " ال", "probability": 0.80126953125}, {"start": 259.54, "end": 259.92, "word": " reaction", "probability": 0.9443359375}, {"start": 259.92, "end": 260.28, "word": " away", "probability": 0.90673828125}, {"start": 260.28, "end": 260.58, "word": " from", "probability": 0.92529296875}, {"start": 260.58, "end": 260.8, "word": " a", "probability": 0.73779296875}, {"start": 260.8, "end": 261.3, "word": " chiral", "probability": 0.967041015625}, {"start": 261.3, "end": 261.66, "word": " center", "probability": 0.91064453125}, {"start": 261.66, "end": 262.3, "word": " results", "probability": 0.483154296875}, {"start": 262.3, "end": 262.56, "word": " in", "probability": 0.94580078125}, {"start": 262.56, "end": 262.98, "word": " retention", "probability": 0.81298828125}, {"start": 262.98, "end": 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476.13, "word": " عملنا", "probability": 0.804443359375}, {"start": 476.13, "end": 476.29, "word": " له", "probability": 0.85693359375}, {"start": 476.29, "end": 476.99, "word": " generation،", "probability": 0.628173828125}, {"start": 476.99, "end": 477.15, "word": " شو", "probability": 0.899169921875}, {"start": 477.15, "end": 477.39, "word": " طلع", "probability": 0.9264322916666666}, {"start": 477.39, "end": 478.51, "word": " عندى؟", "probability": 0.7509765625}, {"start": 478.51, "end": 479.29, "word": " رسمic", "probability": 0.3650716145833333}, {"start": 479.29, "end": 480.01, "word": " mixture", "probability": 0.76123046875}], "temperature": 1.0}, {"id": 23, "seek": 51088, "start": 481.66, "end": 510.88, "text": "تاني تفاعل لما اعملت تفاعل بعيد عن الكايرال سنتر شو صار عندى retention of configuration طيب الآن لو كان في عندى كايرال سنتر اول و بدى اعمل كايرال سنتر تاني شو بده يصير عندى؟ خلّينا نشوف مثال هذه مثال لو طلعنا على هذا المركب الآن هذه الكاربون اللى موجودة هنا بتحمل مثل 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{"start": 501.0, "end": 502.44, "word": " هذه", "probability": 0.2509765625}, {"start": 502.44, "end": 502.88, "word": " مثال", "probability": 0.905517578125}, {"start": 502.88, "end": 503.06, "word": " لو", "probability": 0.884765625}, {"start": 503.06, "end": 503.6, "word": " طلعنا", "probability": 0.984130859375}, {"start": 503.6, "end": 503.8, "word": " على", "probability": 0.7841796875}, {"start": 503.8, "end": 504.22, "word": " هذا", "probability": 0.93701171875}, {"start": 504.22, "end": 505.12, "word": " المركب", "probability": 0.8849283854166666}, {"start": 505.12, "end": 505.78, "word": " الآن", "probability": 0.5701904296875}, {"start": 505.78, "end": 506.32, "word": " هذه", "probability": 0.701171875}, {"start": 506.32, "end": 506.94, "word": " الكاربون", "probability": 0.8133544921875}, {"start": 506.94, "end": 507.12, "word": " اللى", "probability": 0.88525390625}, {"start": 507.12, "end": 507.66, "word": " موجودة", "probability": 0.9786376953125}, {"start": 507.66, 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على", "probability": 0.91015625}, {"start": 552.28, "end": 552.62, "word": " هذه", "probability": 0.488525390625}, {"start": 552.62, "end": 553.28, "word": " النقطة", "probability": 0.9816080729166666}, {"start": 553.28, "end": 554.8, "word": " تلت", "probability": 0.89208984375}, {"start": 554.8, "end": 555.46, "word": " روابط", "probability": 0.963623046875}, {"start": 555.46, "end": 555.92, "word": " تلت", "probability": 0.9366861979166666}, {"start": 555.92, "end": 556.36, "word": " روابط", "probability": 0.989013671875}], "temperature": 1.0}, {"id": 26, "seek": 58430, "start": 558.25, "end": 584.31, "text": "حاولوا تستحضروا الشكل مع الهيدروجين المحذوف مع الهيدروجين المحذوف أعطيكم H هاي الشكل الكامل واضح؟ لما أضيف هنا H هذا الكربون بدل ما يكون CH2 ماذا سيحصل؟ CH3 سيحصل CH3 و ال double bond هذه ستذهب على", "tokens": [5016, 995, 12610, 14407, 6055, 14851, 5016, 11242, 2288, 14407, 25124, 28820, 20449, 2423, 3224, 25708, 2288, 29245, 9957, 9673, 5016, 8848, 38688, 20449, 2423, 3224, 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"بسبب وجود ال chiral center اللي بيخلي جهة أحيانا مغلقة أكتر من الجهة التانية بيصير فيه فرق بالوسع زي إنسان كان عنده مسارين متساويين تماما بيمكنه يمشي من هنا و من هنا الآن إجا شيء سكر جزء من مسار معين بيضلوا يمشي بنفس النسبة ولا غالبا بيروح على المسار الأكتر يعني ساعة و فراغ", "tokens": [3555, 35457, 3555, 49610, 23328, 2423, 23782, 304, 3056, 13672, 1829, 4724, 1829, 9778, 20292, 10874, 3224, 3660, 5551, 5016, 1829, 7649, 995, 3714, 17082, 1211, 28671, 5551, 4117, 2655, 2288, 9154, 25724, 3224, 3660, 16712, 7649, 10632, 4724, 1829, 9381, 13546, 8978, 3224, 6156, 2288, 4587, 20666, 41779, 3615, 30767, 1829, 36145, 3794, 7649, 25961, 43242, 3224, 47524, 9640, 9957, 44650, 3794, 995, 45865, 9957, 46811, 10943, 995, 4724, 32640, 19452, 3224, 7251, 2304, 8592, 1829, 9154, 34105, 4032, 9154, 34105, 6024, 48506, 11933, 7435, 995, 44049, 38207, 8608, 37983, 10874, 11622, 38207, 9154, 47524, 9640, 20449, 9957, 4724, 1829, 11242, 1211, 14407, 7251, 2304, 8592, 1829, 44945, 36178, 28239, 35457, 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nucleophile هو السالب اللي بده يهاجم ويحل محل الهالوجين السالبة يعمل عملية الإبدال شكرا", "tokens": [1211, 1211, 39184, 14962, 49242, 13672, 1829, 47525, 3224, 7251, 3224, 26108, 2304, 4032, 1829, 44510, 10721, 16712, 5172, 995, 30241, 5296, 33456, 2423, 39184, 14962, 49242, 31439, 21136, 6027, 3555, 13672, 1829, 47525, 3224, 7251, 3224, 26108, 2304, 4032, 1829, 5016, 1211, 3714, 5016, 1211, 2423, 3224, 6027, 29245, 9957, 21136, 6027, 49401, 7251, 25957, 1211, 6225, 42213, 10632, 33688, 44510, 6027, 13412, 4117, 23557], "avg_logprob": -0.19123133705623113, "compression_ratio": 1.7226277372262773, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 2350.77, "end": 2351.19, "word": "للـ", "probability": 0.6194661458333334}, {"start": 2351.19, "end": 2352.09, "word": " nucleophile", "probability": 0.7049560546875}, {"start": 2352.09, "end": 2352.39, "word": " اللي", "probability": 0.884765625}, {"start": 2352.39, "end": 2352.65, "word": " بده", "probability": 0.5738525390625}, {"start": 2352.65, "end": 2353.23, "word": " يهاجم", "probability": 0.9722900390625}, {"start": 2353.23, "end": 2353.77, "word": " ويبدأ", "probability": 0.762939453125}, {"start": 2353.77, "end": 2354.39, "word": " التفاعل", "probability": 0.90966796875}, {"start": 2354.39, "end": 2354.63, "word": " لأن", "probability": 0.759765625}, {"start": 2354.63, "end": 2354.95, "word": " الـ", "probability": 0.611083984375}, {"start": 2354.95, "end": 2355.73, "word": " nucleophile", "probability": 0.894775390625}, {"start": 2355.73, "end": 2356.37, "word": " هو", "probability": 0.97802734375}, {"start": 2356.37, "end": 2357.05, "word": " السالب", "probability": 0.94677734375}, {"start": 2357.05, "end": 2357.25, "word": " اللي", "probability": 0.95458984375}, {"start": 2357.25, "end": 2357.47, "word": " بده", "probability": 0.864990234375}, {"start": 2357.47, "end": 2357.91, "word": " يهاجم", "probability": 0.990478515625}, {"start": 2357.91, "end": 2358.25, "word": " ويحل", "probability": 0.8968505859375}, {"start": 2358.25, "end": 2358.79, "word": " محل", "probability": 0.9671223958333334}, {"start": 2358.79, "end": 2360.19, "word": " الهالوجين", "probability": 0.8106689453125}, {"start": 2360.19, "end": 2360.87, "word": " السالبة", "probability": 0.9358723958333334}, {"start": 2360.87, "end": 2361.37, "word": " يعمل", "probability": 0.766357421875}, {"start": 2361.37, "end": 2361.79, "word": " عملية", "probability": 0.9798177083333334}, {"start": 2361.79, "end": 2362.43, "word": " الإبدال", "probability": 0.8826497395833334}, {"start": 2362.43, "end": 2363.63, "word": " شكرا", "probability": 0.865234375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2364.9525, "duration_after_vad": 2273.398124999997}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6f1cf75f168161bc285449116ce8122bf42e7c12
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs.srt
@@ -0,0 +1,1744 @@
+
+1
+00:00:21,410 --> 00:00:26,010
+بسم الله الرحمن الرحيم بدأنا احنا في محاضرات ماضية
+
+2
+00:00:26,010 --> 00:00:31,390
+في تفاعلات ال alkanes ويمكن لاحظنا ان الأمر في هذه
+
+3
+00:00:31,390 --> 00:00:36,690
+المنطقة هو أمر سهل جدا مافيش فيه مشاكل الرابطة
+
+4
+00:00:36,690 --> 00:00:41,450
+الزوجية من خلال تفاعل الإضافة بتصير رابطة أحدية
+
+5
+00:00:42,020 --> 00:00:45,740
+الاشياء المتعلقة بهذا التفاعل اللى اتكلمنا عنها
+
+6
+00:00:45,740 --> 00:00:50,220
+كانت طبيعة ال الكين و طبيعة ال reagent هل ال الكين
+
+7
+00:00:50,220 --> 00:00:54,400
+symmetric هل ال reagent symmetric و هذا الكلام أدى
+
+8
+00:00:54,400 --> 00:00:58,140
+إلى انه مرات بيكون في عندنا اضافات حسب قاعدة
+
+9
+00:00:58,140 --> 00:01:01,760
+Markovnikov او عكس قاعدة Markovnikov حسب طبيعة
+
+10
+00:01:02,350 --> 00:01:05,850
+التفاعل اللى بنعمله اخر شغل انتهينا عنده في
+
+11
+00:01:05,850 --> 00:01:11,030
+المحاضرة الماضية انه احنا ايضا ممكن نضيف oxygen
+
+12
+00:01:11,030 --> 00:01:16,050
+على ال double bond من خلال تفاعل ال alkenes مع ال
+
+13
+00:01:16,050 --> 00:01:20,030
+bare acids بيعطونا ال epoxides اللى هى الحلقات
+
+14
+00:01:20,030 --> 00:01:25,510
+الثلاثية اتعلمنا تسميتها بطريقتين سواء ان نسميها
+
+15
+00:01:25,510 --> 00:01:30,300
+من خلال ان نقولالكين اكسايد نذكر اسم الالكين
+
+16
+00:01:30,300 --> 00:01:34,720
+الأصلي اللى نتجت منه او من خلال اننا نعتبر ال
+
+17
+00:01:34,720 --> 00:01:37,360
+parent ring يعني الحلقة الأساسية اللى كلها
+
+18
+00:01:37,360 --> 00:01:43,720
+هيدروجين اسمها oxirane و الرقم من عند ال oxygen و
+
+19
+00:01:43,720 --> 00:01:51,200
+نذكر أسماء ال substituents اللى موجودةأيضا ركزنا
+
+20
+00:01:51,200 --> 00:01:55,660
+على نقطة أن هذه الحلقة الثلاثية هي حلقة مضغوطة is
+
+21
+00:01:55,660 --> 00:02:00,560
+a strained ring ليش؟ لأن الزوايا فيها ضغطت إلى
+
+22
+00:02:00,560 --> 00:02:04,720
+الستين الوضع المريح لزاوية ال carbon carbon carbon
+
+23
+00:02:04,720 --> 00:02:10,020
+او ما شابه مية وتسعة و نص ولذلك أسهل تفاعل فيها
+
+24
+00:02:10,020 --> 00:02:14,440
+اللي هو تفاعل ال ring opening فاحنا صح بنكون
+
+25
+00:02:14,440 --> 00:02:20,350
+الحلقةلكن الحلقة strain فلما تتجه تعمل ring
+
+26
+00:02:20,350 --> 00:02:26,250
+-opening فكرة ال ring-opening كانت مبنية على انه
+
+27
+00:02:26,250 --> 00:02:31,670
+اذا اتذكرنا احنا ان الاكسجين electronegative اكثر
+
+28
+00:02:31,670 --> 00:02:35,830
+من الكربون يعني الاكسجين partially negative ال two
+
+29
+00:02:35,830 --> 00:02:42,210
+carbons هيكونوابارشالة positive فانا لو جبت اي شيء
+
+30
+00:02:42,210 --> 00:02:46,250
+بده يتفاعل مع الموجب والاصل يكون سالم سمينا
+
+31
+00:02:46,250 --> 00:02:51,230
+نيوكليوفايل هاجم هنا النتيجة انه هيكسر هذه الرابطة
+
+32
+00:02:51,230 --> 00:02:55,970
+مش هيصير عنده خمس روابط فلما ييجي اي نيوكليوفايل
+
+33
+00:02:57,150 --> 00:03:02,150
+هاجم على هذا الكرمون هتنكسر الرابط أزواج
+
+34
+00:03:02,150 --> 00:03:08,050
+الألكترونات هيكون مع الـ O O minus بياخد H غالبا
+
+35
+00:03:08,050 --> 00:03:12,890
+الـ H هذه بتكون مع الـ nucleophile فهيصف ايش O H
+
+36
+00:03:12,890 --> 00:03:17,230
+او احنا بنعمل catalysis للتفاعل بـ H plus يعني
+
+37
+00:03:17,230 --> 00:03:22,690
+مثلا الميه فيها جزء ايه لو تشوفوا محصلة التفاعل O
+
+38
+00:03:22,690 --> 00:03:31,120
+H اللي هي تمثللنكليوفاي و في اتش فهذا لنكليوفاي لو
+
+39
+00:03:31,120 --> 00:03:38,130
+اتفعل من هنا وصف في الآخر انه حط OHL شو ضال عندكH
+
+40
+00:03:38,130 --> 00:03:42,870
+هتيجي وين؟ على هذه الـ O أو لو أنا كنت عامل acid
+
+41
+00:03:42,870 --> 00:03:47,530
+catalysis الـ H تبعت ال acid في الأساس هي اللي
+
+42
+00:03:47,530 --> 00:03:52,410
+بتيجي و بيطلع بدلها H plus لكن كمحصلة كمعادلة
+
+43
+00:03:52,410 --> 00:03:57,370
+موزونة كمعادلة موزونة لو بتتطلع على هذا المركب لو
+
+44
+00:03:57,370 --> 00:04:02,580
+بتتطلع على هذا المركباللي أنا بادى فيه وهذا المركب
+
+45
+00:04:02,580 --> 00:04:07,140
+اللى طلع عندى هتلاحظوا هى ال OH اللى اجت من الميه
+
+46
+00:04:07,140 --> 00:04:12,700
+وهىالـ H هيصل في ميّه إذا المعادلة بهذا الشكل
+
+47
+00:04:12,700 --> 00:04:17,460
+موصولة ولا لأ تماما كاربون كاربون أكسوجين وإيجي
+
+48
+00:04:17,460 --> 00:04:23,800
+عنده من الميّه الـ OH والـ H في كل الأحوال تفاعل
+
+49
+00:04:23,800 --> 00:04:28,500
+ال ring opening سهل جدا أن نطبقه بدنا نقول أن هذه
+
+50
+00:04:28,500 --> 00:04:35,720
+الحلقة بدأ تصير CCOH بما تحملهيعني لو كانت هنا
+
+51
+00:04:35,720 --> 00:04:40,080
+بتحمل H2 وهنا H2، بيظلوا زي ما هما، H و مثل وهنا
+
+52
+00:04:40,080 --> 00:04:43,820
+H2، بيظلوا زي ما هما، إيش ما بتحمل هنا، هدولة مش
+
+53
+00:04:43,820 --> 00:04:47,760
+موقع تفاعل، ما بتغيروش، أيًا كانوا، إيش ما
+
+54
+00:04:47,760 --> 00:04:51,200
+بيكونوا، هدول المجموعات بتغيروش، اللي بيصير عنده C
+
+55
+00:04:53,120 --> 00:04:58,840
+OH وهنا بدو ييجي عنده لنيوكليوفايل طبعا إذا كان
+
+56
+00:04:58,840 --> 00:05:05,100
+المتفاعل الماء لنيوكليوفايل OH طب إذا المتفاعل HX
+
+57
+00:05:05,100 --> 00:05:13,240
+لنيوكليوفايل X إذا المتفاعل RO- هيكون RO وبتيجي H
+
+58
+00:05:13,240 --> 00:05:18,020
+من هنا بهذا الشكل إذا الشيء المشترك هنا الشيء
+
+59
+00:05:18,020 --> 00:05:22,580
+المشترك هنا أنه هتشوفوا هذه القطعة
+
+60
+00:05:25,740 --> 00:05:37,660
+CCOH CCOH CCOH CCOH CCOH
+
+61
+00:05:37,660 --> 00:05:44,900
+CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH
+
+62
+00:05:44,900 --> 00:05:49,920
+CCOHأي مجموعات كانت موجودة عليهم اصلا يعني لو كنت
+
+63
+00:05:49,920 --> 00:05:53,760
+بدي انا في ال parent compound يعني هذه CH2 CH2
+
+64
+00:05:53,760 --> 00:06:01,540
+هتكون النتيجة OH CH2 CH2 OH لو هدولة C مثل 2 مثل 2
+
+65
+00:06:01,540 --> 00:06:09,100
+هيكون OH C مثل 2 C مثل 2 و هكذا واضح؟ بهذا الشكل
+
+66
+00:06:09,100 --> 00:06:15,230
+بتم التفاعد ولذلك مرات كتير لما بنشوف عندنالما
+
+67
+00:06:15,230 --> 00:06:20,510
+بنشوف إنه في تفاعلات موجود CH2 CH2 OH ممكن نفكر إن
+
+68
+00:06:20,510 --> 00:06:27,150
+هدولة إجوا من حلقة إيش Oxirane حلقة Oxirane CH2
+
+69
+00:06:27,150 --> 00:06:31,190
+CH2 OH اتفاعلت مع نيوكليوفايل بيضطر نيوكليوفايل
+
+70
+00:06:31,190 --> 00:06:39,600
+CH2 CH2واضح؟ طبعا في حالات ممكن المجموعات اللى
+
+71
+00:06:39,600 --> 00:06:43,480
+موجودة على ال carbon في هدولة النقطين تكون مختلفة
+
+72
+00:06:43,480 --> 00:06:49,780
+يعني ممكن مثلا تلاحظوا ان هذه تكونسي أتش تو وهنا
+
+73
+00:06:49,780 --> 00:06:53,700
+سي أتش و سي أتش ثري و بتكون تيجي تفعله الماء
+
+74
+00:06:53,700 --> 00:06:57,560
+لاحظوا هتصيروا متحيرين هل يا ترى النيوكليوفايل
+
+75
+00:06:57,560 --> 00:07:01,540
+هتخلوه يتفعل على هذا الكربون و لا على هذا الكربون
+
+76
+00:07:01,540 --> 00:07:04,600
+من ناحية المبدأ هذا موجبة و هذا موجبة دائما
+
+77
+00:07:04,600 --> 00:07:08,560
+النيوكليوفايل هتفعل على الكربون اللي بتحمل الكربون
+
+78
+00:07:08,560 --> 00:07:14,230
+أكثرتعرفوا تصنيفات ال carbon primary و secondary و
+
+79
+00:07:14,230 --> 00:07:18,090
+tertiary حسب ما بيحمل carbons فالتفاعل على ال
+
+80
+00:07:18,090 --> 00:07:21,930
+carbon اللي بتحمي ال carbons أكثر بيكون مفضل يعني
+
+81
+00:07:21,930 --> 00:07:25,090
+في هذه الحالة لو كنا بنفعل ميه هل يا ترى ال O
+
+82
+00:07:25,090 --> 00:07:28,550
+هتيجي تهاجم على هذا ال carbon ولا هذا ال carbon و
+
+83
+00:07:28,550 --> 00:07:35,650
+هنا هيصير أن ال O أتش هذا لو مر علينامثال بهذا
+
+84
+00:07:35,650 --> 00:07:41,150
+الشكل طبعا في كل الأحوال لأن هذه حلقة لأن هذه حلقة
+
+85
+00:07:41,150 --> 00:07:46,430
+هنلاحظ ان النيوكليوفايل هيجي من جهة و ال OH هتكون
+
+86
+00:07:46,430 --> 00:07:51,390
+من الجهة المعاكزة واضح ان هذا بيأثر على النواتج او
+
+87
+00:07:51,390 --> 00:07:56,510
+لا هذا موضوع ثاني لكن الإضافة هنا بتكون sin ولا
+
+88
+00:07:56,510 --> 00:08:02,550
+anti additionبتكون Anti-Addition الإضافة هنا بتكون
+
+89
+00:08:02,550 --> 00:08:05,750
+Anti-Addition يعني الـ Nucleophile بيجي من الجهة
+
+90
+00:08:05,750 --> 00:08:10,270
+المعاكسة لجهة تكوّن الـ OH ملاحظين منهم Anti
+
+91
+00:08:10,270 --> 00:08:13,690
+-Addition؟
+
+92
+00:08:13,690 --> 00:08:19,970
+الآن لاحظوا لو فكرنا مثلا أنه بدنا نضيف مجمعتين OH
+
+93
+00:08:21,270 --> 00:08:26,050
+من جهة واحدة يعني هذه الطريقة انه حولنا الالكين ل
+
+94
+00:08:26,050 --> 00:08:32,730
+ابوكسايد وفتحنا الحلقة اعطتنا مجموعتين OHمن جهتين
+
+95
+00:08:32,730 --> 00:08:37,370
+متعاكستين طب لو فكرنا انه بدنا نضيف المجموعتين من
+
+96
+00:08:37,370 --> 00:08:42,710
+جهة واحدة في عندنا تفاعل تاني ممكن نعمله مباشرة
+
+97
+00:08:42,710 --> 00:08:48,130
+على ال الكين و بضيف مجموعتين OH من جهة واحدة هذا
+
+98
+00:08:48,130 --> 00:08:54,170
+التفاعل ان نفعل ال الكين سواء مع مركب ال Osmium O4
+
+99
+00:08:54,170 --> 00:08:59,340
+في وجود هذه الأشياءكتاليست او مع مركب كيامان O4
+
+100
+00:08:59,340 --> 00:09:03,540
+بيرمانجانات البوتاسيوم سواء قلنا أزوميام الأزوميام
+
+101
+00:09:03,540 --> 00:09:08,320
+عنصر معدن ثقيل تقريبا هو أثقل العناصر يعني كثافته
+
+102
+00:09:08,320 --> 00:09:14,300
+أعلى حتى من الدهب واشي فوق العشرين جرام لكل سنتمتر
+
+103
+00:09:14,300 --> 00:09:21,180
+مكعبواضح؟ سواء قلنا Osmium O4 او KMnO4 انا بحكي عن
+
+104
+00:09:21,180 --> 00:09:27,520
+معدل مثل ال مثل Osmium او مانجانيز وهذا متصل بكم
+
+105
+00:09:27,520 --> 00:09:32,990
+مجموعة Oهيبقى أربعة، الآن لما بديجي يتفاعل مع
+
+106
+00:09:32,990 --> 00:09:36,310
+double bond لما بديجي يتفاعل مع double bond هي
+
+107
+00:09:36,310 --> 00:09:40,650
+double bond أكيد هيتفاعل من خلال أكسجنتين موجودات
+
+108
+00:09:40,650 --> 00:09:45,630
+على جهة واحدة و بعد هيك تنكسر هذه الرابطة مع
+
+109
+00:09:45,630 --> 00:09:51,530
+المعدنتم التفاعل بهذا الشكل هذي هتاخد من مجمل
+
+110
+00:09:51,530 --> 00:09:58,130
+التفاعل HOOH أكيد أجه من جهة واحدة فالتفاعل هذا
+
+111
+00:09:58,130 --> 00:10:02,150
+بتتم من جهة واحدة لأنه بإمكانكوا ببساطة تتخيلوا
+
+112
+00:10:02,150 --> 00:10:08,050
+الكيامان O4 زي هيك هاي .. هاي الأربع ذرات أكسوجين
+
+113
+00:10:08,050 --> 00:10:12,680
+اللي موجودين فيه الآن بدو يهاجم ع double bondبيقدر
+
+114
+00:10:12,680 --> 00:10:17,060
+يهاجم من جهتين؟ لأ بالتاكيد هيهاجم من هنا و من هنا
+
+115
+00:10:17,060 --> 00:10:22,500
+حذرتين أكسجين من جهة واحدة فإضافة مجموعات ال OH
+
+116
+00:10:22,500 --> 00:10:28,220
+باستعمال ال Osmium O4 أو الكيامان O4 في وجود طبعا
+
+117
+00:10:28,220 --> 00:10:32,000
+ما basic medium كل الأشياء اللي أمامكم هو عبارة عن
+
+118
+00:10:32,000 --> 00:10:37,040
+sin ولا anti addition؟ sin addition ابهيك بنذكر
+
+119
+00:10:37,040 --> 00:10:40,580
+إيش الأشياء اللي بتصيروا ماخدينها sin addition؟
+
+120
+00:10:42,290 --> 00:10:49,270
+إضافة الـ hydrogen و إضافة مجموعات ال OH باستعمال
+
+121
+00:10:49,270 --> 00:10:54,710
+ال Osmium O4 أو الكيامان O4 لما أخدنا إضافة ال PR2
+
+122
+00:10:54,710 --> 00:11:00,150
+أخدناها Anti addition لما أخدنا إضافة ال PR2
+
+123
+00:11:00,150 --> 00:11:06,290
+أخدناها Anti addition مش Sin addition واضح؟ ولذلك
+
+124
+00:11:06,290 --> 00:11:12,720
+لو مثلا جيبنا لكم مركب زي هذاخلنا ناخد مثال
+
+125
+00:11:12,720 --> 00:11:17,540
+Cyclopentane
+
+126
+00:11:17,540 --> 00:11:26,060
+طبعا ك Cyclopentane شو عليها؟H وH وسألناكم سؤال
+
+127
+00:11:26,060 --> 00:11:31,280
+قلنا لكم كيف ممكن تحضروا من هذا Cyclobentane
+
+128
+00:11:31,280 --> 00:11:37,540
+Cyclobentadiol يعني Cyclobentane شيلنا منه ال
+
+129
+00:11:37,540 --> 00:11:40,900
+double bond و حاطينا مجموعتين OH يعني بدل ال
+
+130
+00:11:40,900 --> 00:11:44,780
+double bond مجموعتين OH مرة يكونوا ال cis و مرة
+
+131
+00:11:44,780 --> 00:11:49,600
+يكونوا ال trans كأنه بيصير السؤال انه كيف بدي احضر
+
+132
+00:11:49,600 --> 00:11:59,490
+منههذا المُركّب اللي فيه مجموعتين الـ OH على جهة
+
+133
+00:11:59,490 --> 00:12:06,270
+واحدة و بدي أحضر منه أيضا المُركّب اللي فيه
+
+134
+00:12:06,270 --> 00:12:11,930
+مجموعتين الـ OH على جهتين متعاكستين اللي هم الـ
+
+135
+00:12:11,930 --> 00:12:13,330
+CIS والـ Trans
+
+136
+00:12:18,820 --> 00:12:21,820
+واضح؟ how can you prepare this is and
+
+137
+00:12:21,820 --> 00:12:27,060
+transcyclobentane diol starting from cyclobentene
+
+138
+00:12:27,060 --> 00:12:32,960
+الان في الحالة الأولى الجواب مباشر في الحالة
+
+139
+00:12:32,960 --> 00:12:37,040
+الأولى الجواب مباشر بدى استعمل اما طريقة ال
+
+140
+00:12:37,040 --> 00:12:41,760
+ozomium o4 او ال camon o4 نفس الشيء خلنا نقول مثلا
+
+141
+00:12:41,760 --> 00:12:49,610
+camon o4 فيباسيك ميديام في وجود الماء ألاحظوا
+
+142
+00:12:49,610 --> 00:12:54,210
+انتبهوا جيدا لو سمحتوا الكيامان اوفور عشان تعمل
+
+143
+00:12:54,210 --> 00:12:57,910
+هذا التفاعل و تضيف من جهتين بدا تكون في basic
+
+144
+00:12:57,910 --> 00:13:02,550
+medium في وجود OH- هذه بديكوا تركزوا عليها لسبب
+
+145
+00:13:02,550 --> 00:13:06,590
+بسيط انه في تفاعلات تانية سواء درسناها او
+
+146
+00:13:06,590 --> 00:13:10,850
+مادرسناهاش تفاعل الكيامان اوفور في acidic medium
+
+147
+00:13:10,850 --> 00:13:16,780
+بيعطيني أشياء تانيةواضح فركزوا ان هذا التفاعل بتم
+
+148
+00:13:16,780 --> 00:13:22,320
+في basic و medium الان لو قولنا المركب التاني كيف
+
+149
+00:13:22,320 --> 00:13:30,080
+بدنا نحضره على خطوتين اذا
+
+150
+00:13:30,080 --> 00:13:34,740
+انا في الاول بدي اجي اقول bare acid مثلا فينيل
+
+151
+00:13:34,740 --> 00:13:39,580
+COOOH و
+
+152
+00:13:39,580 --> 00:13:44,720
+استعمل و يعطيني ال ابوكسايدو بعدين بوجود ال ..
+
+153
+00:13:44,720 --> 00:13:49,480
+بساط حمضي مع .. هاي ال Evoxide واضح؟ أخدنا هذا
+
+154
+00:13:49,480 --> 00:13:54,440
+التفاعل بيصير Cyclopentene
+
+155
+00:13:54,440 --> 00:14:01,080
+Oxide و بعد هيك لما أجي أفعله مع ال H2O H plus
+
+156
+00:14:01,080 --> 00:14:05,300
+بيعمل ring opening O H بتيجي من هنا O Hواحدة من
+
+157
+00:14:05,300 --> 00:14:08,600
+التحت وواحدة من الفوق إذا هذا التفاعل بتتم على
+
+158
+00:14:08,600 --> 00:14:12,860
+خطوة ولا على خطوة إيه؟ على خطوة إيه؟ هذا التفاعل
+
+159
+00:14:12,860 --> 00:14:24,220
+على خطوة واحدة واضح
+
+160
+00:14:24,220 --> 00:14:24,960
+المثال؟
+
+161
+00:14:48,060 --> 00:14:52,220
+من التفاعلات اللى بدنا ندرسها ايضا لل Alkanes
+
+162
+00:14:52,220 --> 00:14:59,040
+تفاعل جديد الان مش تفاعل اضافة تفاعل bond cleavage
+
+163
+00:14:59,040 --> 00:15:03,480
+بمعنى بيكسر ال double bond نصين يعني اتطلعوا معاه
+
+164
+00:15:03,480 --> 00:15:07,000
+هذي ال double bond التفاعل اللى بدنا ندرسه الان
+
+165
+00:15:07,000 --> 00:15:11,800
+بدوش يضيف حوله من double ل single كل ما درسناه كان
+
+166
+00:15:11,800 --> 00:15:16,180
+addition reactions لحد الان كل ما درسناه كان
+
+167
+00:15:16,180 --> 00:15:19,970
+addition double bondتصير single bond الآن بدنا
+
+168
+00:15:19,970 --> 00:15:23,590
+ناخد نوع تاني من تفاعلات ال double bond اللي هو
+
+169
+00:15:23,590 --> 00:15:27,030
+cleavage reaction ان اجعل double bond و اكسرها
+
+170
+00:15:27,030 --> 00:15:32,950
+نصين هذا التفاعل بنسميه ozonolysis of alkenes وزي
+
+171
+00:15:32,950 --> 00:15:38,750
+ما قلت هو تفاعل ايشCleavage تفاعل كسر بيكسر ال
+
+172
+00:15:38,750 --> 00:15:43,010
+double bond نصين بتم هذا التفاعل من خلال التفاعل
+
+173
+00:15:43,010 --> 00:15:48,210
+مع ال ozone بتعرفوا ال ozone الأكسجل في الطبيعة O2
+
+174
+00:
+
+223
+00:19:34,320 --> 00:19:38,120
+تكون H بيكون أبسط الديهايد التانية تكون مثل إثل
+
+224
+00:19:38,120 --> 00:19:43,820
+فنل بروبل أي مجموعة بيظلوا الديهيد ايضا فنتج ال
+
+225
+00:19:43,820 --> 00:19:49,580
+اوزونوليسيس بيعطي الديهيد او كيتون باستخدام
+
+226
+00:19:49,580 --> 00:19:55,380
+الاشتراكات على الدبل بوند اعتمادا على الاشتراكات
+
+227
+00:19:55,380 --> 00:19:58,600
+على الدبل بوند الان هي هذا على طول لما واحدة بتطلع
+
+228
+00:19:58,600 --> 00:20:03,500
+هتلاحظ ايش اعطانا هنا الديهيد اكيد لان الدبل بوند
+
+229
+00:20:03,500 --> 00:20:08,910
+عليها اتش وهنا نور على نور الدبل بوند عليهاتنتين H
+
+230
+00:20:08,910 --> 00:20:13,670
+إذا أيضا بالتأكيد الديهايد وإن كان أبسط الديهايد
+
+231
+00:20:13,670 --> 00:20:17,890
+لكن لو أي طرف عليه تنتين كاربون من عند هذا الطرف
+
+232
+00:20:17,890 --> 00:20:25,070
+هيعطيه كيتون هاي أمثلة عندنا تطلع عليها في كل
+
+233
+00:20:25,070 --> 00:20:32,450
+الأحوال من أين ستكسر الرابط من
+
+234
+00:20:32,450 --> 00:20:38,340
+النص الرابط بنكسرها من النص بدون ما نتطلع على
+
+235
+00:20:38,340 --> 00:20:41,860
+الجواب لو إجينا سألنا هذا الناتج بيعطي إيش
+
+236
+00:20:41,860 --> 00:20:46,840
+الديهايد الكربون هذي حملة H at least و هذا
+
+237
+00:20:46,840 --> 00:20:53,920
+الديهايد و الديهايد هنا T ليش المخفي شو هو؟ بديش
+
+238
+00:20:53,920 --> 00:21:01,300
+أبقى أتعب معكم كل ما لم يكتب فهو H طيب إذا من هذه
+
+239
+00:21:01,300 --> 00:21:07,430
+الجهة شو بيعطيه؟ و من هذه الجهة كيتون هذه كل رأس
+
+240
+00:21:07,430 --> 00:21:12,850
+يعتبر carbon الان هذه بنكسرها ايضا من النص بتصير
+
+241
+00:21:12,850 --> 00:21:17,590
+هنا C double bond O وهنا C double bond O اكيد هذه
+
+242
+00:21:17,590 --> 00:21:23,170
+كيتون وهنا فيه H مخفية كيتون
+
+243
+00:21:23,170 --> 00:21:27,250
+والدايت لاحظوا هذا ماعطاش جزيء ايه لكن كسر الرابط
+
+244
+00:21:27,250 --> 00:21:34,720
+بنفس المنطق هذا نفس الشي تماما لاحظوا هنا فيه اتش و
+
+245
+00:21:34,720 --> 00:21:38,160
+هنا فيه اتش خلو ادي سيضه بالبندقه و ادي سيضه
+
+246
+00:21:38,160 --> 00:21:42,200
+بالبندقه بس هو بعد هيك بدل ما الجزيئ يكتبوا عامل
+
+247
+00:21:42,200 --> 00:21:51,680
+زي هيك فرضه اعطاه نفس حرام يعني هذا بمش هو احنا
+
+248
+00:21:51,680 --> 00:21:54,940
+ليش بنعلمكوا ان الجزيئات بتتغير زي ما البني ادم
+
+249
+00:21:54,940 --> 00:21:58,340
+بياخد ميت صورة يعني هذا لو كان بدوا يكتبوا
+
+250
+00:21:58,340 --> 00:22:00,420
+بالطريقة اللي انتوا فاهمينها
+
+251
+00:22:03,590 --> 00:22:09,470
+عمل هيك و هيك زي هيك مبين سهل و اين كسرت الرابطة
+
+252
+00:22:09,470 --> 00:22:16,030
+الان بعد هيك انفرض زي ما الجنيل بيكون متكور في بطن
+
+253
+00:22:16,030 --> 00:22:25,570
+امه هذا هو هداك هذا المركب هو هذا المركب اليوم
+
+254
+00:22:25,570 --> 00:22:30,250
+انا باعطي ناتج تفاعل طالما الديهايد او كيتون موطعه
+
+255
+00:22:30,250 --> 00:22:35,750
+شبتر 9 عشان أسميهم، مش اليوم، واضح؟ في طريقة
+
+256
+00:22:35,750 --> 00:22:44,970
+لتسميتهم ما سُكِت عنه يُصبر عليه، واضح؟
+
+257
+00:22:44,970 --> 00:22:51,710
+الآن
+
+258
+00:22:51,710 --> 00:22:58,890
+من أمثلة ومن تفاعلات الالكينز أيضا تفاعل مهم جدا في
+
+259
+00:22:58,890 --> 00:23:02,110
+الحياة التطبيقية العملية وفي الحياة الصناعية
+
+260
+00:23:02,110 --> 00:23:06,190
+بنسميه احنا free radical polymerization of
+
+261
+00:23:06,190 --> 00:23:10,290
+ethylene ايش احنا اللي بنقصده في polymerization
+
+262
+00:23:10,290 --> 00:23:16,030
+بتعرف بيكون عندنا جزء واحد من المادة هذا الجزء
+
+263
+00:23:16,030 --> 00:23:23,180
+الواحد من المادة ممكن نسميه احنا monomer مونومر جزء
+
+264
+00:23:23,180 --> 00:23:29,500
+واحد الان لو عملت اتنين بيصير دايمر اتنين دايمر
+
+265
+00:23:29,500 --> 00:23:37,760
+تلاتة اترايمر اربعة تترامر تلت اربع مية تلت اربع
+
+266
+00:23:37,760 --> 00:23:45,410
+تلاف وقتها بوليمر طب مش من أولها polymer لأ إذا
+
+267
+00:23:45,410 --> 00:23:50,130
+إحنا لو كنا بنقول الجزء الواحد إيش بنقوله؟ monomer
+
+268
+00:23:50,130 --> 00:23:58,750
+اتنين دايمر تلاتة ترايمر أربعة تترامر
+
+269
+00:24:02,660 --> 00:24:08,120
+بوليمر يعني البوليمر بيكون تلت اربعميت جزيء خمسمية
+
+270
+00:24:08,120 --> 00:24:11,960
+احيانا تلت تلاف احيانا حسب طبيعة المواد خمسين الف
+
+271
+00:24:11,960 --> 00:24:15,680
+ميت الف بيكونوا كلهم مار بعض هذا اللي بنسميه
+
+272
+00:24:15,680 --> 00:24:20,420
+بوليمر مش تلاتة واربعة واضح فالواحد والاتنين
+
+273
+00:24:20,420 --> 00:24:24,770
+والتلاتة دول علهم أسماء لكن لما بيكون كبير بصير
+
+274
+00:24:24,770 --> 00:24:30,390
+عنده ال Polymer الان إذا تخيلتوا ان هذا جزء
+
+275
+00:24:30,390 --> 00:24:36,310
+إيثالين إيثالين والإيثالين غاز و إجينا على هذا
+
+276
+00:24:36,310 --> 00:24:45,400
+الإيثالين و حطناه مع بروكسايد تحت ضغط مرتفع جدا جدا
+
+277
+00:24:45,400 --> 00:24:51,160
+جدا الف أتمسفير عشان تخافوا من كلمة الف أتمسفير
+
+278
+00:24:51,160 --> 00:24:56,300
+يعني تقدروا تتخيلوا شوها الضغط الكبير بس تذكروا أن
+
+279
+00:24:56,300 --> 00:25:00,400
+طنجرة الضغط اللي بتطبخوا فيها و اللي بتكون تصفروا
+
+280
+00:25:00,400 --> 00:25:06,620
+و بتخوف الضغط فيها اتنين أتمسفير فقط
+
+281
+00:25:07,930 --> 00:25:12,510
+الضغط فيها دي طنجرة الضغط اتنين atmosphere فانا
+
+282
+00:25:12,510 --> 00:25:16,650
+لما بحكي عن الف atmosphere بيمكنكم تخيلوا الضغط
+
+283
+00:25:16,650 --> 00:25:21,410
+طبعا اكيد هذا التفاعل مابنعملش بجزاز ولا بحديد
+
+284
+00:25:21,410 --> 00:25:25,050
+بسيط بيكون عندكوا اوعية stainless steel الوعاء
+
+285
+00:25:25,050 --> 00:25:28,450
+يمكن عرضه اتنين تلاتة سانت stainless steel ومكابس
+
+286
+00:25:28,450 --> 00:25:34,820
+هيدروليكية هذا شغل صناعة مش شغل مختبر، الآن بيجيبوا
+
+287
+00:25:34,820 --> 00:25:42,310
+الغاز، بنحطه غاز، بنحط عليه ال ..البروكسايتز هذه
+
+288
+00:25:42,310 --> 00:25:46,030
+عند ألف أتمسفير وبنسخن عند مئة درجة مئوية بنضغط
+
+289
+00:25:46,030 --> 00:25:50,210
+الغاز بندخل جزيئات الغاز، لاحظوا غاز، بندخل
+
+290
+00:25:50,210 --> 00:25:55,970
+جزيئاته في بعضها طالما كبر المركب، هيتحول لإيش؟
+
+291
+00:25:55,970 --> 00:26:00,110
+لصلب، مش بزيادة ال molecular weight كنا نتحول من
+
+292
+00:26:00,110 --> 00:26:03,930
+غاز لسائل لصلب، هيتحول ل polymer، هذا ال polymer
+
+293
+00:26:03,930 --> 00:26:08,470
+هو plastic هو نوع من ال plastic اللي احنا بنستعمله
+
+294
+00:26:08,470 --> 00:26:14,410
+بنسميه polyethylene فال ethylene بكل هذه الشروط
+
+295
+00:26:14,410 --> 00:26:18,450
+بيصير CH2 CH2 to the N لحظة لغية ال double bond
+
+296
+00:26:18,450 --> 00:26:23,570
+خلتها single bond لغية ال double bond و خلتها
+
+297
+00:26:23,570 --> 00:26:30,530
+single bond في هذه الحالة صار الإيثالين بولي
+
+298
+00:26:30,530 --> 00:26:34,570
+إيثالين طبعا في ميكانيزم للتفاعل مش كتير بتفرج
+
+299
+00:26:34,570 --> 00:26:38,910
+عنده البولي إيثالين هو البلاستيك الأبيض إذا دخلتوا
+
+300
+00:26:38,910 --> 00:26:42,050
+على المختبرات بتلاحظوا في عندكم جلانات بنعب فيها
+
+301
+00:26:42,050 --> 00:26:46,330
+ميا ديستيلد ووتر wash bottles أشياء كل هذه عبارة
+
+302
+00:26:46,330 --> 00:26:49,490
+عن بولي إيثالين الأوعية اللى بنحط فيها هيدروكسيد
+
+303
+00:26:49,490 --> 00:26:53,050
+الصوديوم بتشوفوا ال .. ال bottle اللى بنكون معبينه
+
+304
+00:26:53,050 --> 00:27:00,100
+محلولا كل هذه عبارة عن إيش بولي إيثالين الآن بنفس
+
+305
+00:27:00,100 --> 00:27:03,820
+المنطق، شوفوا كيف العلم بتطور، يعني أول ما بدأنا
+
+306
+00:27:03,820 --> 00:27:07,280
+عملنا Polymer عملنا إيش؟ الـ Ethylene و عملنا له
+
+307
+00:27:07,280 --> 00:27:12,200
+Polymerization إلى Polyethylene طيب هم قالوا لازم
+
+308
+00:27:12,200 --> 00:27:16,400
+هدول الأربعة يكونوا Hydrogen و Hydrogen يعني CH2
+
+309
+00:27:16,400 --> 00:27:22,400
+CH2 لو يا ترى بدلنا واحدة منهم بكلور هنا هنا شيلنا
+
+310
+00:27:22,400 --> 00:27:28,860
+واحدة بالغلط صار CH CH2CL وكان double bond وعملنا
+
+311
+00:27:28,860 --> 00:27:33,800
+منه ال polymer هتصير single bond طب هذا المركب
+
+312
+00:27:33,800 --> 00:27:42,680
+الأصلي CH2 double bond CHCL أخدنا اسمه vinyl
+
+313
+00:27:42,680 --> 00:27:47,480
+chloride هذه مجموعة ال vinyl Vinyl chloride اللي
+
+314
+00:27:47,480 --> 00:27:51,760
+قال لو اعملت منه بوليمار بنفس المنطق تبع الاثيلين
+
+315
+00:27:51,760 --> 00:27:58,640
+الغط بابل بوند و اكتبه to the end طالما هذا Vinyl
+
+316
+00:27:58,640 --> 00:28:03,960
+chloride Vinyl chloride شو هيصير البوليمار تبعه
+
+317
+00:28:03,960 --> 00:28:08,320
+بولي و Vinyl chloride اتخيلوا لو بدنا نختصر اسم
+
+318
+00:28:08,320 --> 00:28:14,300
+البوليمار تبعه BVC
+
+319
+00:28:15,850 --> 00:28:23,430
+مين ما بعرفش ال PVC؟ كل شناتكم PVC، كل بلاستيك
+
+320
+00:28:23,430 --> 00:28:27,310
+المحووتكم PVC، كل المواسير اللي بتشوفوها اللي
+
+321
+00:28:27,310 --> 00:28:30,810
+بنستعملها لتمديدات الصرف الصحي، المواسير
+
+322
+00:28:30,810 --> 00:28:35,750
+البردجانية والسكنية، لو جربت عليها، مكتوب عليها
+
+323
+00:28:35,750 --> 00:28:36,230
+PVC
+
+324
+00:28:39,480 --> 00:28:43,960
+Polyvinyl chloride اللي بيعملوها أرضيات أحيانا
+
+325
+00:28:43,960 --> 00:28:48,820
+بيغطوا فيها البلاط ممكن تشوفوها أحيانا في صالونات
+
+326
+00:28:48,820 --> 00:28:53,200
+لحلاجة في المستشفى أرضية بلاستيك و بيلزجوها فوق كل
+
+327
+00:28:53,200 --> 00:28:59,900
+بلاط الغرفة هذه PVC فال PVC موجود وبشكل كبير في
+
+328
+00:28:59,900 --> 00:29:05,640
+الحياة التطبيقية زي وزي البولي إيثالين الآن لاحظوا
+
+329
+00:29:05,640 --> 00:29:09,540
+إذا صارت القصة إن أغير واحدة من الهيدروجين وحطيت
+
+330
+00:29:09,540 --> 00:29:14,960
+كلور لما كانت هيدروجين بولي إيثالين لما كانت كلور
+
+331
+00:29:14,960 --> 00:29:21,020
+PVC أو بولي فينيلي كلورايت طب لو خلناها بنزينة
+
+332
+00:29:22,360 --> 00:29:28,720
+المُركّب الأصلي سيكون CH2 double bond CH حملة
+
+333
+00:29:28,720 --> 00:29:34,920
+بنزينة أو phenyl اسمه styrene اسمه styrene لما
+
+334
+00:29:34,920 --> 00:29:41,130
+أعمل منه polymer إيش بده يصير؟ Polystyrene لما أعمل
+
+335
+00:29:41,130 --> 00:29:45,690
+منه polymer هيصير polystyrene إذا التفاعل مش بس
+
+336
+00:29:45,690 --> 00:29:50,390
+خاص بال إيثيلين لأ اتطور على مواد تانية و كل هذه
+
+337
+00:29:50,390 --> 00:29:54,310
+عبارة عن أنواع من ال plastic موجودة في السوق و
+
+338
+00:29:54,310 --> 00:29:59,950
+بتلباع و بتعامل فيها الناس و أفرجناكوا تطبيقيا وين
+
+339
+00:29:59,950 --> 00:30:02,430
+بتستعمل واضحة هذه الفكرة؟
+
+340
+00:30:05,100 --> 00:30:09,380
+إذا هاي كمان تفاعل تاني لل keys يعني كأنها
+
+341
+00:30:09,380 --> 00:30:14,560
+بنصير كتفاعلات أساسية أخدنا الإضافة أخدنا ال
+
+342
+00:30:14,560 --> 00:30:18,340
+cleavage اللي هو ال ozoneolysis و أخدنا ال
+
+343
+00:30:18,340 --> 00:30:24,690
+polymerization أنه بيعمل polymer كبير طبعا الله
+
+344
+00:30:24,690 --> 00:30:29,510
+يعطيكوا العافية بالنسبله ال Alkenes طب لو انتقلنا
+
+345
+00:30:29,510 --> 00:30:35,130
+لل Alkynes هتلاحظوا أنه بشكل أساسي تفاعلات شبيهة
+
+346
+00:30:35,130 --> 00:30:41,710
+الأساس فيها الإضافة ولكن لاحظوا معي لما أبدأ أحكي
+
+347
+00:30:41,710 --> 00:30:47,590
+عن ال Alkynes ال Alkynes تلت روابط carbon ال
+
+348
+00:30:47,590 --> 00:30:52,230
+triple bond carbon إذا لو بده يبدأ يضيف إيش
+
+349
+00:30:52,230 --> 00:30:56,740
+هيتحول؟ لـ carbon double bond carbon وكمان خطوة
+
+350
+00:30:56,740 --> 00:31:02,560
+carbon single bond carbon إذا الإضافة هنا يمكن أن
+
+351
+00:31:02,560 --> 00:31:07,820
+تتم على مراحل يعني ال triple bond تصير double bond
+
+352
+00:31:07,820 --> 00:31:12,020
+تصير single bond مرات حسب شروط التفاعل وهذا اللي
+
+353
+00:31:12,020 --> 00:31:15,820
+بتكون تنتبهوله ممكن نخل التفاعل يجف لهنا بنص
+
+354
+00:31:15,820 --> 00:31:19,700
+الطريق يعني ال triple تصير double و يجف التفاعل
+
+355
+00:31:19,700 --> 00:31:26,830
+مرات بيستمرمرات ما بنقدرش نفصل المركب اللي بالوسط
+
+356
+00:31:26,830 --> 00:31:31,150
+يعني مجرد ما نحط عليه المادة التانية بيصير double
+
+357
+00:31:31,150 --> 00:31:36,450
+bond و بسرعة كبيرة بيظلوا محول لإيش ل single bond
+
+358
+00:31:36,450 --> 00:31:40,070
+بعمل إضافة تانية طبعا هنا كام إضافة بيصير لو قلت
+
+359
+00:31:40,070 --> 00:31:46,750
+من triple ل single bond إضافتين إضافتين يعني لو
+
+360
+00:31:46,750 --> 00:31:53,720
+قعد بضيف HCl مش لغاية double bond شو حطيت؟ H طب
+
+361
+00:31:53,720 --> 00:31:56,880
+هدولة كيف بدي أضيفهم؟ حسب قاعدة Markov Nikov ولا
+
+362
+00:31:56,880 --> 00:32:00,720
+ضد؟ إذا كانوا مع ال H Plus حسب قاعدة Markov Nikov
+
+363
+00:32:00,720 --> 00:32:06,340
+يعني اتخيلتوا هذه H وهذه CH3 وين هتيجي ال H؟ على
+
+364
+00:32:06,340 --> 00:32:13,940
+الحاملة ال H أكتر وين هتيجي التانية؟ واضح؟ أه بعد
+
+365
+00:32:13,940 --> 00:32:18,780
+هيك لو بدي أضيف كمان مرة سرادة ال K أخدنا كيف بضيف
+
+366
+00:32:18,780 --> 00:32:24,780
+ال K على هذا؟ هتيجي ال H هنا؟ و ال CL هنا وجدت كأنه
+
+367
+00:32:24,780 --> 00:32:30,020
+ضفت التنتين هيدروجين على نفس الكربون وهي
+
+368
+00:32:30,020 --> 00:32:36,120
+الهيدروجين الأصلية والتنتين CL على نفس الكربون وهي
+
+369
+00:32:36,120 --> 00:32:42,660
+CH3 خلّينا الطول الأصلية إذا التفاعل هنا تم على
+
+370
+00:32:42,660 --> 00:32:48,600
+مرحلة ولا مرحلتين؟ ع مرحلتين كل مرحلة منهم تمت حسب
+
+371
+00:32:48,600 --> 00:32:54,750
+قاعدة Markov-Nikov لما أضيف HCL في وجود ال H plus
+
+372
+00:32:54,750 --> 00:33:00,150
+واضح؟ كل مرحلة منهم بتتم حسب قاعدة ماركو بيه
+
+373
+00:33:00,150 --> 00:33:05,190
+خلّينا نشوف هذا الكلام بالتفصيل بعض الإضافات بعض
+
+374
+00:33:05,190 --> 00:33:09,850
+تفاؤلات الإضافة للالكينز لاحظوا هاي أول مثال
+
+375
+00:33:09,850 --> 00:33:18,490
+addition of HX to alkynes هاي عندي كاربون بتحمل H
+
+376
+00:33:18,490 --> 00:33:25,510
+وكاربون بتحمل إيش H وضفت ال HClضعفين كيف هيكون
+
+377
+00:33:25,510 --> 00:33:30,630
+الناتج الأخير انه هضيف مرتين ال H هنا و هنا و
+
+378
+00:33:30,630 --> 00:33:33,590
+مرتين ال CL هنا و هنا هذه الناتج الأخيرة بس
+
+379
+00:33:33,590 --> 00:33:39,030
+بالتأكيد اول ما بيبدأ اضيف الإضافة الأولى إجت هنا
+
+380
+00:33:39,030 --> 00:33:44,270
+H و إجت هنا CL و الإضافة التانية إجت هنا كمان H و
+
+381
+00:33:44,270 --> 00:33:52,640
+هنا كمان CL واضح فمرتين حسب قاعدة ماركوف نيكوف
+
+382
+00:33:52,640 --> 00:33:56,380
+اديشن الان
+
+383
+00:33:56,380 --> 00:34:04,360
+لو كنت بدى اضيف لبروم لبروم بضيف Anti addition
+
+384
+00:34:04,360 --> 00:34:11,540
+المرة الأولى هين اضفت PR و PR عكس بعضه اعطانى
+
+385
+00:34:11,540 --> 00:34:18,660
+الالكيل كمان مرة يعني كأنه هى ال PR 2 الأول وهى ال
+
+386
+00:34:18,660 --> 00:34:23,020
+PR2 التالي كمان مرة حديث من هنا و من هنا صار عندى
+
+387
+00:34:23,020 --> 00:34:27,420
+أربع ذرات إبروم فلاحظوا لو أنا كنت كاتب زيكوا و
+
+388
+00:34:27,420 --> 00:34:34,380
+كاتبلكوا 2PR2 شو ناتج النهاية اللى بدى أكتبه ال
+
+389
+00:34:34,380 --> 00:34:39,700
+كان أو ال كان ال كان ال كان بالإنجليزي ال كان
+
+390
+00:34:39,700 --> 00:34:45,890
+بالعربي ال كان بالإنجليزي ماختلفناهاش كتير الان من
+
+391
+00:34:45,890 --> 00:34:52,230
+التفاعلات المهمة ايضا تفاعل اضافة الميه بس اضافة
+
+392
+00:34:52,230 --> 00:35:02,070
+الميه شوية في فكرة جديدة لو انا اجيت وضفت الميه H2O
+
+393
+00:35:02,070 --> 00:35:06,210
+
+
+445
+00:39:49,570 --> 00:39:53,670
+هيك كل كلانة بتقدروا تتذكروا و تشوفوا كيف أصل
+
+446
+00:39:53,670 --> 00:39:59,190
+الإسم لو اطلعتوا على هذا المركب مين تسمينا إياه؟
+
+447
+00:39:59,190 --> 00:40:09,580
+Phenolفينول أنا بدي أسميه زي هيك في إين أول تطلعوا
+
+448
+00:40:09,580 --> 00:40:15,020
+معاه الفي لأنه عندي بنزينة الفنل الفنل البنزينة و
+
+449
+00:40:15,020 --> 00:40:20,880
+إين هي الإين و all هي
+
+450
+00:40:20,880 --> 00:40:25,980
+ال all هذا الشكل الثابت منه و بنقدر نعطيكوا
+
+451
+00:40:25,980 --> 00:40:29,240
+homework ان جولكوا ارسمونا ال ketone تبعه
+
+452
+00:40:42,070 --> 00:40:47,610
+ما هو الشكل الثابت في الاروماتيك كومباوتز الموجودة
+
+453
+00:40:47,610 --> 00:40:52,520
+بالنسبة أعلى؟الـ Enol في الالفاتيك كومباونز اللي
+
+454
+00:40:52,520 --> 00:40:57,200
+موجود بنسبة أعلى الـ Ketone وهذه التوتوماريزم زي
+
+455
+00:40:57,200 --> 00:41:01,320
+ما اتفقنا هي عبارة عن عملية equilibrium فالسهم
+
+456
+00:41:01,320 --> 00:41:08,350
+اللي بيستعمللهاأي سهم؟ الـ straight arrow او two
+
+457
+00:41:08,350 --> 00:41:12,270
+straight arrows with half heads اللي هو السهمين
+
+458
+00:41:12,270 --> 00:41:16,070
+اللي موجودين كل واحد بنصف رأس زي ما انتوا شايفينه
+
+459
+00:41:16,070 --> 00:41:20,610
+هنا واللي اتفقنا ان هذا يستعمل الاتزان وعملية
+
+460
+00:41:20,610 --> 00:41:25,830
+التوتوماريزم هي حقيقة عملية اتزان عملية
+
+461
+00:41:25,830 --> 00:41:29,490
+التوتوماريزم هي حقيقة عملية اتزان
+
+462
+00:41:34,870 --> 00:41:39,810
+التفاعلات أيضا لو كنت أنا بضيف الميه عكس قاعدة
+
+463
+00:41:39,810 --> 00:41:45,070
+Markov Nikov باستعمال ال boron لاحظوا هنا في عندكم
+
+464
+00:41:45,070 --> 00:41:50,310
+H هذا نفس المثال السابق بس في اللحظة الأولى اللي
+
+465
+00:41:50,310 --> 00:41:54,510
+حطيت فيها H و OH طالما بضيف باستعمال ال boron هل
+
+466
+00:41:54,510 --> 00:41:59,110
+هضيف حسب قاعدة Markov Nikov ولا عكسها عكسها بناء
+
+467
+00:41:59,110 --> 00:42:04,860
+على ذلك حطيت ال H على اللي حامله H أقلو ال O H على
+
+468
+00:42:04,860 --> 00:42:08,900
+اللي حامله H هذا إضافة عكس Markovnikov مرة تانية
+
+469
+00:42:08,900 --> 00:42:18,180
+صار عندى in all هذا ال in all بحوله إلى ال keto
+
+470
+00:42:18,180 --> 00:42:23,560
+form بمعنى هذا ال double bond تيجي هنا و ال H
+
+471
+00:42:23,560 --> 00:42:29,500
+تنتقل مكان ما إجت ال double bondكل هذا الكلام
+
+472
+00:42:29,500 --> 00:42:33,320
+طبقوا بإيدكم عشان تتدربوا عليه، إذا نفس
+
+473
+00:42:33,320 --> 00:42:37,380
+التوتوميرزم، لكن في هذه الحالة بدل ما أحصل على
+
+474
+00:42:37,380 --> 00:42:42,560
+كيتون حصلت على الديهايد، في المرة الأولى، ليش حصلت
+
+475
+00:42:42,560 --> 00:42:48,100
+على كيتون؟ لأن ال OH إجت على الكاربون الداخليةفلما
+
+476
+00:42:48,100 --> 00:42:51,380
+صارت C double bond O صفية متصلة بكاربون و بكاربون
+
+477
+00:42:51,380 --> 00:42:55,480
+كيتون في المرة التانية لما أضيف عكس قاعدة
+
+478
+00:42:55,480 --> 00:42:58,800
+Markovnikov و أعمل التوتوميرزم ال OH جت على
+
+479
+00:42:58,800 --> 00:43:04,720
+الكاربون الطرفية ولذلك حصلت على الديهيد اذا انا
+
+480
+00:43:04,720 --> 00:43:10,100
+ممكن احصل من هذا التفاعل على الديهيد او كيتون
+
+481
+00:43:10,100 --> 00:43:13,840
+اعتمادا على الطريقة اللي انا ببدأ فيها اذا ضفت
+
+482
+00:43:13,840 --> 00:43:19,760
+الماء بقاعدة Markovnikovبحصل على كيتون وإذا ضيفت
+
+483
+00:43:19,760 --> 00:43:24,300
+الماء عنتي ماركوفنيكوف بحصل على الديهايد وهذا
+
+484
+00:43:24,300 --> 00:43:27,360
+الكلام لما انتوا تتدربوا و تطبقوا بيدكم هتلاحظوا
+
+485
+00:43:27,360 --> 00:43:32,900
+انه بيطلع بشكل تلقائي النتيجة هذه تطلع معاكم بشكل
+
+486
+00:43:32,900 --> 00:43:42,700
+تلقائي تقريبا الشغلة الأخيرة في هذا الموضوع إضافة
+
+487
+00:43:42,700 --> 00:43:43,680
+الهيدروجين
+
+488
+00:43:45,820 --> 00:43:52,880
+أخرناها كثير إضافة الهيدروجين للـ triple bond لها
+
+489
+00:43:52,880 --> 00:43:57,780
+عدة حالاتإذا ضيفت الهيدروجين في وجود معدن زي
+
+490
+00:43:57,780 --> 00:44:02,380
+البلاديم والكربون أو مثلا ال nickel أو ال platinum
+
+491
+00:44:02,380 --> 00:44:08,060
+أي واحد من هدول بلاديم نيكل platinum عادة معدن
+
+492
+00:44:08,060 --> 00:44:13,680
+البلاديم بيكون مخلوط بكربون بودرة تمام فبتتحول لل
+
+493
+00:44:13,680 --> 00:44:18,820
+triple bond إلى single bond مباشرة بدون مأمورأو
+
+494
+00:44:18,820 --> 00:44:20,940
+بمر في الـ double bond بدون ما أفصل الـ double
+
+495
+00:44:20,940 --> 00:44:26,760
+bond يعني بضيف هيدروجين و كمان هيدروجين فالالكاين
+
+496
+00:44:26,760 --> 00:44:31,760
+إذا فعلنا مع الهيدروجين في وجود متل بيصير الكين
+
+497
+00:44:31,760 --> 00:44:35,340
+يعني لما نيجي نقولكم reaction of alkynes with
+
+498
+00:44:35,340 --> 00:44:40,270
+hydrogen in presence of metals شو بيعطيناالكينز
+
+499
+00:44:40,270 --> 00:44:46,010
+الان طيب لو جيبت الكاين زي هذا وفعلته مع هيدروجين
+
+500
+00:44:46,010 --> 00:44:51,030
+في وجود مادة اسمها لند لارز كتاليست يمكن بالكتابة
+
+501
+00:44:51,030 --> 00:44:55,170
+ناقص حرف ال L لند لارز كتاليست لند لارز كتاليست
+
+502
+00:44:55,170 --> 00:44:57,530
+لند لارز كتاليست لند لارز كتاليست لند لارز كتاليست
+
+503
+00:44:57,530 --> 00:45:02,890
+لند لارز كتاليست بضيف بهذه الحالة الهيدروجين من
+
+504
+00:45:02,890 --> 00:45:10,320
+جهة واحدة وبيعطينيالالكين بيجي في نص الطريق بس إيش
+
+505
+00:45:10,320 --> 00:45:17,260
+نوع إضافة الهيدروجين في وجود الليندلار
+
+506
+00:45:17,260 --> 00:45:18,700
+كاتاليست الهيدروجين الهيدروجين الهيدروجين
+
+507
+00:45:18,700 --> 00:45:20,760
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+508
+00:45:20,760 --> 00:45:21,100
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+509
+00:45:21,100 --> 00:45:21,420
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+510
+00:45:21,420 --> 00:45:21,440
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+511
+00:45:21,440 --> 00:45:24,080
+الهيدروجين الهيدروجين الهيدروجينسيس كومباوند في
+
+512
+00:45:24,080 --> 00:45:26,840
+حالة تانية ممكن لأ يعني لو كانت هذه قدش و قدش مش
+
+513
+00:45:26,840 --> 00:45:30,900
+هيقد لسيس كومباوند أهم شيء عندنا ان الهيدروجين
+
+514
+00:45:30,900 --> 00:45:36,100
+بيضيف بسين اديشن اذا كانت اضافته في وجود لندلار
+
+515
+00:45:36,100 --> 00:45:39,320
+كتاليست و بيقف عن نص الطريق بيقف في وين؟ عند
+
+516
+00:45:39,320 --> 00:45:44,500
+الألكيد طب يا تورا هل ممكن نضيف الهيدروجين انت
+
+517
+00:45:44,500 --> 00:45:51,300
+اديشن يعني على نفس هذا المركب و نطلعالهيدروجين
+
+518
+00:45:51,300 --> 00:45:55,020
+Anti-addition بمعنى إيصير عندي double bond أخلي
+
+519
+00:45:55,020 --> 00:46:03,960
+البنزنتين على جهتين والهيدروجين على جهتين هذا Anti
+
+520
+00:46:03,960 --> 00:46:09,880
+-addition واضح؟ ممكن لو أعملنا التفاعل في وجود
+
+521
+00:46:09,880 --> 00:46:19,310
+ليثيان مع liquid ammoniaواضح؟ اذا انا بإمكاني اضيف
+
+522
+00:46:19,310 --> 00:46:24,470
+الهيدروجين بطريقة معينة يعملي sin addition و
+
+523
+00:46:24,470 --> 00:46:29,630
+بطريقة تانية يعملي anti addition و ممكن اضيفه على
+
+524
+00:46:29,630 --> 00:46:36,970
+مرتين في وجود الهيدروجين و البلاديم او ال nickel
+
+525
+00:46:36,970 --> 00:46:41,990
+او ال platinum ثانية
+
+526
+00:46:41,990 --> 00:46:46,060
+بس لو سمحتواLindlar's catalyst هو عبارة عن خليط من
+
+527
+00:46:46,060 --> 00:46:49,800
+البلاديم مع الكالسيوم كربونيت مع ليد أسيتيت مع
+
+528
+00:46:49,800 --> 00:46:54,360
+كوينولين بهمنيش نحفظ شكله ماخد اسم، إيش اسمه؟
+
+529
+00:46:54,360 --> 00:46:57,000
+Lindlar's catalyst
+
+530
+00:47:00,060 --> 00:47:04,660
+في عندكم طبعا عدة أمثلة عشان انتوا تدرسوها هي
+
+531
+00:47:04,660 --> 00:47:10,100
+تطبيق مباشر على هذا الموضوع بيظل عندنا للمرة
+
+532
+00:47:10,100 --> 00:47:14,100
+الجاية فقط slide واحدة بنحكيها بدقيقتين في موضوع
+
+533
+00:47:14,100 --> 00:47:17,920
+ال kinds و بننتقل لل chapter الرابع اللي هو
+
+534
+00:47:17,920 --> 00:47:23,020
+chapter ال aromatic compounds يعني فقط ضايل عندنا
+
+535
+00:47:23,020 --> 00:47:26,780
+slide واحدة ان شاء الله المرة القادمة بنشرح
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d4105dde81b13ebaeb7d2352c7972b93f7196cdd
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs.srt
@@ -0,0 +1,1659 @@
+
+1
+00:00:20,860 --> 00:00:25,560
+بسم الله الرحمن الرحيم اليوم موضوعنا إن شاء الله
+
+2
+00:00:25,560 --> 00:00:29,680
+هيكون في الفصل الرابع ال aromatic compounds لكن
+
+3
+00:00:29,680 --> 00:00:36,220
+ضاع علينا شغلة صغيرة أنا بعتقد إنها مهمة من الفصل
+
+4
+00:00:36,220 --> 00:00:41,640
+الثالث من تفاعلات ال alkynes فخلينا نشوف هذه
+
+5
+00:00:41,640 --> 00:00:47,680
+النقطة بسرعة وبعدين ننتقل لموضوعنا الأساسي اللي
+
+6
+00:00:47,680 --> 00:00:53,620
+هو ال aromatic compounds النقطة اللى ضاعت علينا انه
+
+7
+00:00:53,620 --> 00:01:00,580
+احنا لما بننظر لل Alkynes اذا كان على احد أطرافهم
+
+8
+00:01:00,580 --> 00:01:06,020
+على اقل تقدير أو ممكن على الطرفين ذرّة هيدروجين
+
+9
+00:01:06,020 --> 00:01:11,400
+يعني ال Alkyne ممكن يكون R C triple bond C وR تاني
+
+10
+00:01:11,400 --> 00:01:16,040
+يعني مثل و مثل أو فلل و فلل و ممكن يكون R C triple
+
+11
+00:01:16,040 --> 00:01:22,690
+bond C وموجود ذرّة هيدروجين الالكاين اللي بهذا
+
+12
+00:01:22,690 --> 00:01:27,670
+الشكل اللي في أحد أطرافه ذرّة هيدروجين بنسميه احنا
+
+13
+00:01:27,670 --> 00:01:32,350
+terminal الكاين يعني الكاين الطرفي اللي في أحد
+
+14
+00:01:32,350 --> 00:01:39,440
+أطرافه ايش فيها terminal الكاينهذه النقطة الأولى
+
+15
+00:01:39,440 --> 00:01:43,300
+إذا عرفنا إيش معناه Terminal Alkyne اللي على طرف
+
+16
+00:01:43,300 --> 00:01:49,960
+من الرابطة الزوجية فيه موجود عنده ذرة هيدروجين الآن
+
+17
+00:01:49,960 --> 00:01:54,960
+بنضيف معلومة جديدة بنقول ال terminal alkynes are
+
+18
+00:01:54,960 --> 00:02:00,680
+acidic ال terminal alkynes are acidic إيش يعني
+
+19
+00:02:00,680 --> 00:02:07,200
+acidic؟ حامضي الآن لو أنا اجيت أتذكر تعريف الحامض
+
+20
+00:02:07,200 --> 00:02:10,980
+ممكن ناخد في هذه المرحلة تعريف الوري برونستيد الـ
+
+21
+00:02:10,980 --> 00:02:19,780
+acid proton donor بيعطي بروتونات بيفقد بروتون الآن
+
+22
+00:02:19,780 --> 00:02:24,660
+أي بروتون حامضي في هذا المركب يعني لحظوا أنا لما
+
+23
+00:02:24,660 --> 00:02:29,460
+رسمت هنا مركب في عندي هنا حلقة Cyclohexane و عليها
+
+24
+00:02:29,460 --> 00:02:34,030
+هيدروجين أو في مجموعات الميثل والإثل والبروبل
+
+25
+00:02:34,030 --> 00:02:38,430
+الالكينز كلها ملانة هيدروجين كل هذه الهيدروجينات
+
+26
+00:02:38,430 --> 00:02:42,730
+اللي في الالكينز واللي في الالكينز هيدروجينات غير
+
+27
+00:02:42,730 --> 00:02:46,590
+حامضية ايش معنى هيدروجين غير حامضي انه لا يفقد
+
+28
+00:02:46,590 --> 00:02:51,370
+بسهولة عند التفاعل مع قاعدة الهيدروجين الحامضي
+
+29
+00:02:51,370 --> 00:02:56,150
+هيدروجين يفقد بسهولة إذا تم التفاعل مع القاعدة
+
+30
+00:02:56,150 --> 00:03:00,930
+ولذلك لما نتطلع على مركب عضوي هنلاحظ أنه دائما
+
+31
+00:03:00,930 --> 00:03:04,330
+المركب العضوي في نوعين من الهيدروجين يعني خليني
+
+32
+00:03:04,330 --> 00:03:12,190
+آخذ مثلا حمض الخل كمثال بسيط حمض الخل CH3COO
+
+33
+00:03:13,740 --> 00:03:19,780
+OH الآن في عندى نوعين من الهيدروجين هنا هدول التلت
+
+34
+00:03:19,780 --> 00:03:24,400
+هيدروجينات هيدروجينات عادية لو أنا كنت بفاعل مع
+
+35
+00:03:24,400 --> 00:03:28,820
+قاعدة لا يفقدوا مع القاعدة they are non acidic مش
+
+36
+00:03:28,820 --> 00:03:34,580
+هيدروجين حامضى الآن الهيدروجين اللى متصل بال OH في
+
+37
+00:03:34,580 --> 00:03:39,320
+الحامض هذا هيدروجين حامضى هذا اللى بيفقد لما أنا
+
+38
+00:03:39,320 --> 00:03:44,630
+باجى بعمل تفاعل مع base فصار في عندى acidic
+
+39
+00:03:44,630 --> 00:03:49,530
+hydrogen و non acidic hydrogen أو بيكون على أقل
+
+40
+00:03:49,530 --> 00:03:54,370
+تقدير أضعف المسألة مسألة ضعف وقوة يعنى هذه
+
+41
+00:03:54,370 --> 00:03:58,770
+الهيدروجينة حمضية بشكل كبير تفقد بسهولة هذه حمضية
+
+42
+00:03:58,770 --> 00:04:04,270
+بشكل قليل جدًا تفقد بصعوبة ممكن لو جيبنا base قوي
+
+43
+00:04:04,270 --> 00:04:08,810
+جدًا جدًا عود نفقدها لكن على base عادي مثلًا خلّيني
+
+44
+00:04:08,810 --> 00:04:12,410
+أقول Sodium Hydroxide أو حتى Sodium Carbonate
+
+45
+00:04:12,410 --> 00:04:17,490
+قاعدة عادية بدي أفعلها أي هيدروجين اللي بدي تفقد
+
+46
+00:04:17,490 --> 00:04:22,450
+الـ acidic هيدروجين عشان ذلك بكل كوب تذكروا
+
+47
+00:04:22,450 --> 00:04:28,470
+التفاعل زائد MAالـ OH هي الـ base of Sodium
+
+48
+00:04:28,470 --> 00:04:32,670
+Hydroxide الأن الـ OH هي الـ base مع هذه الـ H
+
+49
+00:04:32,670 --> 00:04:39,830
+كنتوا متعودين تقولوا بيكون عندك ماء حمض زائد قاعدة
+
+50
+00:04:39,830 --> 00:04:44,650
+ملح زائد ماء لما هذه الـ H تفقد على شكل H plus
+
+51
+00:04:44,650 --> 00:04:49,880
+هتظل إلكترونات الرابطة بتاعتها بالاضافة لزوجين
+
+52
+00:04:49,880 --> 00:04:54,700
+الأساسيات الاساسيات حيصير عليكم CH3C double bond O
+
+53
+00:04:54,700 --> 00:05:00,100
+O كم زوج إلكترونات عليها تلاتة أصلا زوجين
+
+54
+00:05:00,100 --> 00:05:04,220
+إلكترونات ورابطتين فقدت ال H لواحدها بدون
+
+55
+00:05:04,220 --> 00:05:10,000
+إلكتروناتها عشان ال H plus ال OH minus أخدت إيش ال
+
+56
+00:05:10,000 --> 00:05:18,210
+H plus شو صفية هذه minus مع ال NAplus صار sodium
+
+57
+00:05:18,210 --> 00:05:23,650
+acetate خلات الصوديوم acidic acid زايد NaOH Sodium
+
+58
+00:05:23,650 --> 00:05:30,450
+acetate زايد H2O حمض زايد قاعدة ملح زايد ماء هذا
+
+59
+00:05:30,450 --> 00:05:35,090
+تذكير خلينا نقول بمفهوم الحمض والقاعدة الآن لو
+
+60
+00:05:35,090 --> 00:05:40,690
+اجينا نطبق بنفس المنطق على ال terminal الكاين واتخيلنا
+
+61
+00:05:40,690 --> 00:05:47,550
+ان هذا ال terminal الكاين عبارة عن acid وين ال
+
+62
+00:05:47,550 --> 00:05:53,450
+acidic hydrogen اللي فيه هادف الآن نتخيل انه
+
+63
+00:05:53,450 --> 00:05:57,910
+عندنا رابطة بين الكربون والهيدروجين لاحظوا معي
+
+64
+00:05:57,910 --> 00:06:03,350
+الكربون لا يحمل أي زوج إلكترونات حرة فيه اربع
+
+65
+00:06:03,350 --> 00:06:08,190
+روابط ولذلك حتى الكربون بشكله الطبيعي كان بيصلح
+
+66
+00:06:08,190 --> 00:06:14,950
+اللأ تذكروا المرات الماضية قلنا ان ال oxygen في
+
+67
+00:06:14,950 --> 00:06:18,370
+رابطتين و زوجين إلكترونات من خلال أزواج
+
+68
+00:06:18,370 --> 00:06:22,940
+الإلكترونات بيعمل ال UQ file النيتروجين في تلت
+
+69
+00:06:22,940 --> 00:06:28,060
+روابط وزوج إلكترونات أيضا بيعمل الـ eucleophile من
+
+70
+00:06:28,060 --> 00:06:33,720
+خلال زوج الإلكترونات الهالوجين في رابطة تلت أزواج
+
+71
+00:06:33,720 --> 00:06:37,020
+إلكترونات أيضًا ممكن يعمل الـ eucleophile من خلال
+
+72
+00:06:37,020 --> 00:06:42,850
+أزواج الإلكترونات الكاربون في أربع روابط فبالوضع
+
+73
+00:06:42,850 --> 00:06:47,850
+الطبيعي هل ال carbon بيعمل ال nucleophile لأ واضح
+
+74
+00:06:47,850 --> 00:06:52,490
+الآن لو أتيت لهذا المركب فعاليته مع strong base
+
+75
+00:06:52,490 --> 00:06:59,410
+NaNH2 هذه موازية تماما لل NaOH يعني كلكم بتعرفوا ك
+
+76
+00:06:59,410 --> 00:07:08,630
+base NaOH شو كنا نسميها Sodium Hydroxide الآن
+
+77
+00:07:08,630 --> 00:07:17,130
+NaNH2 شبه بها تماما بنسميها Sodium Amide وهذه
+
+78
+00:07:17,130 --> 00:07:20,670
+قاعدة
+
+79
+00:07:20,670 --> 00:07:25,250
+قوية اقوى من Sodium Hydroxide اقوى من Sodium
+
+80
+00:07:25,250 --> 00:07:31,110
+Hydroxide لما نيجي نتخيل ان هذا الحمد وهذه القاعدة
+
+81
+00:07:31,860 --> 00:07:37,260
+هتيجي ال N H2 تتفاعل مع ال H Plus لوحدها شو
+
+82
+00:07:37,260 --> 00:07:44,800
+هتعطيني N H3 زي ما كانت ال O H minus تاخد ال H ال
+
+83
+00:07:44,800 --> 00:07:52,600
+N H2 minus بتاخد ال H O H مع H H2O N H2 minus مع H
+
+84
+00:07:52,600 --> 00:07:59,980
+N H3 نفس التفاعل الآن لما فقدت هذه ال H شو دل على
+
+85
+00:07:59,980 --> 00:08:07,790
+الكربون؟ تلات روابط وإلكترونين إلكترونين قصدكم زوج
+
+86
+00:08:07,790 --> 00:08:11,930
+إلكترونات واحد تلات روابط وإلكترونين هاي واضحها
+
+87
+00:08:11,930 --> 00:08:17,070
+تلات روابط وإلكترونين الآن لو إجينا حسبنا ال
+
+88
+00:08:17,070 --> 00:08:23,130
+formal charge على هذه ال carbon أربعة الكربون ناقص
+
+89
+00:08:23,130 --> 00:08:28,370
+تلات روابط ناقص إلكترونين minus one صارت الكربون
+
+90
+00:08:28,370 --> 00:08:34,070
+minus والصوديوم plus هذا بنسميه صوديوم أستيلايد زي
+
+91
+00:08:34,070 --> 00:08:37,370
+ما مثلًا مع ال hcl بنقول صوديوم كلورايد وصوديوم
+
+92
+00:08:37,370 --> 00:08:41,710
+برومايد في التفاعلات الآن لاحظوا إيش اللي نشأ عندي
+
+93
+00:08:41,710 --> 00:08:48,050
+الآن Ion سالب carbon nucleophile صار في عندي carbon
+
+94
+00:08:48,050 --> 00:08:52,550
+عليه أزواج إلكترونات يعني لو روحت بدي أخد هذا ال
+
+95
+00:08:52,550 --> 00:08:58,170
+Ion اللي نتج عنده وأفعله أي تفاعل كان nucleophile
+
+96
+00:08:58,170 --> 00:09:03,330
+بتفعل ولا لأ بتفعل فهذه المركبات اللي عادة بنعطيها
+
+97
+00:09:03,330 --> 00:09:10,390
+اسم العام Acetylides they are in fact carbon
+
+98
+00:09:10,390 --> 00:09:14,670
+nucleophiles يعني لو قلنا ال Acetylates إيش ممكن
+
+99
+00:09:14,670 --> 00:09:21,470
+نعتبرها؟ Carbon Enucleophile الآن لاحظوا ان ال
+
+100
+00:09:21,470 --> 00:09:25,290
+carbon بالوضع الطبيعي كان سهل يكون عامل carbon
+
+101
+00:09:25,290 --> 00:09:30,070
+enucleophile لأ بعملش لكن أنا لما فقدت بروتون منه
+
+102
+00:09:30,070 --> 00:09:33,870
+وخلت زوجي الإلكترونات صار هذا زوجي الإلكترونات
+
+103
+00:09:33,870 --> 00:09:39,090
+اللي على ال carbon يمثل carbon enucleophile طالما
+
+104
+00:09:39,090 --> 00:09:44,920
+أنه اتكون عندي carbon enucleophile بقدر يتفاعل الـ
+
+105
+00:09:44,920 --> 00:09:49,900
+nucleophile مثلًا لو أتيت اتفاعلته مع مثل ايودايد
+
+106
+00:09:49,900 --> 00:09:55,160
+ممكن يعمل تفاعل إبدال ان هذا زوج الالكتروناتي هاجم
+
+107
+00:09:55,160 --> 00:09:59,600
+على الكربون ويطرد اليود مع زوج الالكتروناتي هذا
+
+108
+00:09:59,600 --> 00:10:04,190
+ايش اسم التفاعل؟ Substitution Reaction أو تفاعل
+
+109
+00:10:04,190 --> 00:10:10,450
+إحلال الـ Eucleophil بيحل محل الـ Eucleophil بيجي
+
+110
+00:10:10,450 --> 00:10:14,690
+الكربون مع زوج الإلكترونات اللي معه بيحل محل اليود
+
+111
+00:10:14,690 --> 00:10:19,150
+ويطلع اليود مع زوج الإلكترونات بدل ما كان عنده
+
+112
+00:10:19,150 --> 00:10:24,120
+أنا Sodium Acetylide هيطلع عندي في النهاية Sodium
+
+113
+00:10:24,120 --> 00:10:29,920
+Iodide يعني كأنه هذا تفاعل تبادل مزدوج اللي مار
+
+114
+00:10:29,920 --> 00:10:36,540
+عليكم واضح ففائدة هذا التفاعل انه وفر لي ال
+
+115
+00:10:36,540 --> 00:10:40,520
+carbon nucleophile اللي بالوضع المتعادل عادة مش
+
+116
+00:10:40,520 --> 00:10:43,920
+متوفر وأنا بعد هيك باستفيد من ال carbon
+
+117
+00:10:43,920 --> 00:10:49,780
+nucleophile في تفاعلات الإبدال وغيرها ممكن الآن نجي
+
+118
+00:10:49,780 --> 00:10:56,760
+نختبر معلوماتكم احنا المرة الماضية أخدنا عن تفاعل
+
+119
+00:10:56,760 --> 00:11:02,980
+كنا بنستعمل فيه الـ UQ5 مين تتذكر شو هو التفاعل الـ
+
+120
+00:11:02,980 --> 00:11:08,430
+Epoxide كان يعمل ring opening مع اليوكليوفايل لما
+
+121
+00:11:08,430 --> 00:11:12,430
+أخدنا تفاعل الابوكسايد المعادلة العامة اللي
+
+122
+00:11:12,430 --> 00:11:18,270
+كتبناها كنا نقول اليوكليوفايل عليه أزواج إلكترونات
+
+123
+00:11:18,270 --> 00:11:24,510
+زائد الابوكسايد كان بيفتح الحلقة بيعطينا CH2 إذا
+
+124
+00:11:24,510 --> 00:11:33,010
+افترضنا هذه CH2 OH وبيجي هنا بتفاعل إيش النكليوفايل
+
+125
+00:11:33,010 --> 00:11:36,950
+هي ال ring opening اللي أخدناه لل Epoxides الآن
+
+126
+00:11:36,950 --> 00:11:41,250
+بدنا نيجي نعوض بدل كلمة نكليوفايل زي ما تعون
+
+127
+00:11:41,250 --> 00:11:46,850
+الرياضيات بيكتب X وY للمجهول بدنا نجيب لنكليوفايل
+
+128
+00:11:46,850 --> 00:11:55,250
+تبعنا ال acetylide يعنىCH3C triple bond C ويحمل زوج
+
+129
+00:11:55,250 --> 00:12:00,730
+إلكترونات صار إيش minus و الفاعل هذا مع هدف شو
+
+130
+00:12:00,730 --> 00:12:07,430
+بتتوقع بده يكون الناتج بده يشبك من
+
+131
+00:12:07,430 --> 00:12:11,530
+خلال زوج الإلكترونات هذا إذا أنا لما بحط الناتج
+
+132
+00:12:11,530 --> 00:12:16,070
+هنا ممكن أحطه باللون الأحمر هيكون بهذا الشكل C
+
+133
+00:12:16,070 --> 00:12:18,190
+triple bond C
+
+134
+00:12:22,290 --> 00:12:27,350
+هذه الاسيتيلايد اتفاعل كان يوكليوفايل هاجم على
+
+135
+00:12:27,350 --> 00:12:33,490
+الكربون وعمل ring opening وتم التفاعل بشكل كامل
+
+136
+00:12:33,490 --> 00:12:34,770
+واضح؟
+
+137
+00:12:38,830 --> 00:12:43,190
+فهمنا اذا هذه النقطة اللي كانت ضايلة عندنا من ال
+
+138
+00:12:43,190 --> 00:12:47,570
+chapter تلاتة انه نفهم إيش معنى terminal alkynes
+
+139
+00:12:47,570 --> 00:12:51,390
+نمرة واحد، نمرة اتنين ان نقول ان terminal alkynes
+
+140
+00:12:51,390 --> 00:12:56,110
+are acidic when reacted with bases they form
+
+141
+00:12:56,110 --> 00:13:00,170
+carbon enucleophiles الآن ال carbon enucleophiles
+
+142
+00:13:00,170 --> 00:13:02,810
+are like any nucleophile they can undergo
+
+143
+00:13:02,810 --> 00:13:06,590
+substitution reactions or any enucleophilic
+
+144
+00:13:06,590 --> 00:13:07,150
+reaction
+
+145
+00:13:11,320 --> 00:13:17,460
+بهيك بننتهي من الفصل التالت في عندكم بالتأكيد
+
+146
+00:13:17,460 --> 00:13:21,660
+تدريبات موجودة واحيانا محلولة إكمال المعادلات وما
+
+147
+00:13:21,660 --> 00:13:27,320
+إلى ذلك بعتقد انه بيكون جزء من المطلوب منكم ان
+
+148
+00:13:27,320 --> 00:13:36,660
+تجتهدوا في تحضيرها وفاهمها بننتقل مباشرة للفصل
+
+149
+00:13:36,660 --> 00:13:43,940
+الرابع والفصل الرابع بعنوان Aromatic compounds ربما
+
+150
+00:13:43,940 --> 00:13:47,500
+ال aromatic compounds لو بدنا نشوف موقعها من
+
+151
+00:13:47,500 --> 00:13:52,720
+الإعراب في ال hydrocarbons they are unsaturated
+
+152
+00:13:52,720 --> 00:13:56,700
+hydrocarbons احنا درسنا ال الكينز ال cycloalkyns
+
+153
+00:13:56,700 --> 00:14:00,160
+ال الكينز ال alkynes ضاع علينا ال aromatic
+
+154
+00:14:00,160 --> 00:14:03,540
+compounds الآن أبسط تعريف ممكن نعطيله ال aromatic
+
+155
+00:14:03,540 --> 00:14:07,520
+compounds they are بنزين like compounds المركبات
+
+156
+00:14:07,520 --> 00:14:14,170
+اللي زي البنزين بمعنى فيهم الحلقة وفيهم أزواج
+
+157
+00:14:14,170 --> 00:14:20,550
+الإلكترونات أو الروابط الزوجية بشكل معين وعدد
+
+158
+00:14:20,550 --> 00:14:26,730
+معين الآن في نقطة كتير مهمة يمكن كل هذا ال slide
+
+159
+00:14:26,730 --> 00:14:33,530
+أخذناها ماعدا نقطة واحدة اللي هو إيش طول الرابط في
+
+160
+00:14:33,530 --> 00:14:37,930
+البنزين ما هو bond order في البنزين وما هو طول
+
+161
+00:14:37,930 --> 00:14:41,230
+الرابط في البنزين احنا أخدنا معلومات عن الرابط
+
+162
+00:14:41,230 --> 00:14:45,910
+الأحدية والثنائية والثلاثية طبعًا كلكوا انتوا
+
+163
+00:14:45,910 --> 00:14:49,950
+متذكرين البنزين ومتذكرين ال resonance structures
+
+164
+00:14:49,950 --> 00:15:01,270
+اللي بيعملها بهذا الشكل وبهذا الشكل الآن لو أتيت
+
+165
+00:15:01,270 --> 00:15:06,210
+طلعت على رابط معين خليني اقول هذه الرابطة هذه
+
+166
+00:15:06,210 --> 00:15:11,810
+الرابطة هنا تبدو إيش؟ أحدية هذه الرابطة هنا تبدو
+
+167
+00:15:11,810 --> 00:15:16,850
+أحدية هذه الرابطة هنا تبدو ثنائية الآن احنا بنقول
+
+168
+00:15:16,850 --> 00:15:20,770
+البنزيل in resonance structure يعني بين هذه وبين
+
+169
+00:15:20,770 --> 00:15:25,970
+هذه بناء على ذلك لو بدي أجي أسأل ال bond order في
+
+170
+00:15:25,970 --> 00:15:31,130
+البنزيل قداشر هل هو يا ترى أحدى ولا ثنائي؟ هو قاعد
+
+171
+00:15:31,130 --> 00:15:36,830
+بتقلب بين الواحد والاتنين بال average إيش هتطلع ال
+
+172
+00:15:36,830 --> 00:15:41,510
+bond order واحد ونص و ال bond order ممكن تيجي كسب
+
+173
+00:15:41,510 --> 00:15:45,350
+ولذلك لو اجيت سألت إيش ال bond order في البنزين
+
+174
+00:15:45,350 --> 00:15:53,590
+واحد ونص هذه الكلمة مهمة جدا جدًا هذه الكلمة مهمة
+
+175
+00:15:53,590 --> 00:15:59,790
+جدا جدا عارفين ليش لأنه أنا
+
+223
+00:19:47,710 --> 00:19:52,610
+ولا لأ اللي هي ال structural isomers او حتى ال
+
+224
+00:19:52,610 --> 00:19:58,190
+stereo isomers فسهل انهم يعرفوا الصيغة الجزائية
+
+225
+00:19:58,190 --> 00:20:02,590
+بيومين بيعرفوا انه مركب جديد الفصل صيغته الجزائية
+
+226
+00:20:02,590 --> 00:20:08,830
+C6H6 لكن يا تورا الصيغة البنائية للبنزين 6 ذرات
+
+227
+00:20:08,830 --> 00:20:13,950
+كربون و 6 ذرات هيدروجين كيف هدول موجودين بأي شكل
+
+228
+00:20:14,810 --> 00:20:20,350
+هذه العملية معرفة الصيغة البنائية للبنزين أخدت ..
+
+229
+00:20:20,350 --> 00:20:25,450
+نرجع للتاريخ أن الأجهزة مش متقدمة و العلوم صعبة
+
+230
+00:20:25,450 --> 00:20:32,510
+أخدت أربعين سنة أربعين سنة لما قدروا يقولوا أن
+
+231
+00:20:32,510 --> 00:20:38,070
+صيغة C6H6 في النهاية هي صيغة البنزين بهذا الشكل
+
+232
+00:20:38,690 --> 00:20:43,370
+اللي اقترحها العالم Kekuli الآن أثناءها الأربعين
+
+233
+00:20:43,370 --> 00:20:49,350
+سنة اقترحت صياغ كثيرة و أخدت أسماء و أحيانا درست
+
+234
+00:20:49,350 --> 00:20:53,490
+للطلاب لأن اللي كانوا بيقترحوه علماء كبار يعني كل
+
+235
+00:20:53,490 --> 00:20:57,750
+هذه الصياغ فيها Carbons و Hydrogens و لو كملتوا ال
+
+236
+00:20:57,750 --> 00:21:02,510
+Hydrogens حسب ما احنا اتعلمنا هتلاحظوا ان هذه
+
+237
+00:21:02,510 --> 00:21:08,270
+الصياغ كلها او هذه المركبات بأشكالها المختلفة C6H6
+
+238
+00:21:08,780 --> 00:21:14,940
+يعني هذا مثلا هي carbon اتنين تلاتة اربعة خمسة ستة
+
+239
+00:21:14,940 --> 00:21:20,360
+هنا في hydrogen تنتين تلاتة اربعة خمسة ستة C6H6
+
+240
+00:21:21,030 --> 00:21:25,570
+واخد اسم و لذلك بنلاحظ ان بعض هذه المراكبات على
+
+241
+00:21:25,570 --> 00:21:29,570
+سبيل المثال هذا المراكب كان اسمه Dewar Benzin هذا
+
+242
+00:21:29,570 --> 00:21:33,210
+المراكب اسمه Huckel Benzin و هدول علماء كيميا كبار
+
+243
+00:21:33,210 --> 00:21:39,250
+هذا Ladenburg Benzin يمكن الكلام هنا بالالماني
+
+244
+00:21:39,250 --> 00:21:46,010
+Klaus Benzinعلماء كبار حطوا أشكال و درست لفترة و
+
+245
+00:21:46,010 --> 00:21:49,950
+هذا الكلام بده يخلي عندكم دائما الشعور أن العلم
+
+246
+00:21:49,950 --> 00:21:54,930
+متطور و ممكن أشياء الإنسان يكون بيدرسها و بعدين
+
+247
+00:21:54,930 --> 00:21:58,710
+يكتشف أنها خطأ أكبر شغلة كل المختارات اللي احنا
+
+248
+00:21:58,710 --> 00:22:03,950
+بنعيشها أول ما بتطلع بنهلللها بشكل كبير و بعد هيك
+
+249
+00:22:03,950 --> 00:22:08,670
+بنلاحظ أن كل العالم يسعى لمنع هذه المختارات اللي
+
+250
+00:22:08,670 --> 00:22:13,100
+احنا هللنا لها كتيرومن أمثلتها على سبيل المثال
+
+251
+00:22:13,100 --> 00:22:17,420
+الفريون الغاز تبع التلاجات اللى كانوا يحطوه فى
+
+252
+00:22:17,420 --> 00:22:21,000
+علاب الريح عشان يعمل ال spraying ال answer نقول
+
+253
+00:22:21,000 --> 00:22:27,610
+هذه ال chlorofluorocarbons تدمر طبقة ال ozoneواضح؟
+
+254
+00:22:27,610 --> 00:22:33,690
+من ضمنها مثلا المبيد الزراعي ال DDT هذا ممتاز
+
+255
+00:22:33,690 --> 00:22:38,130
+بيقتل الحشرات بيقتل ممتاز جدا لكن المشكلة بيأثر
+
+256
+00:22:38,130 --> 00:22:44,170
+على البشر ولذلك حتى بعد منعه المزارعين ما زالوا
+
+257
+00:22:44,170 --> 00:22:48,290
+بيحصلوه بالسوق السوداء و بيستعملوه لأنه بيجيبلهم
+
+258
+00:22:48,290 --> 00:22:53,540
+محصول لكن هو بنفس الوقت بيفكرش بإيشبفكرش في البشر
+
+259
+00:22:53,540 --> 00:22:57,900
+اللي بده يؤذيهم فهذه المنطقة في العلم انضال من
+
+260
+00:22:57,900 --> 00:23:04,380
+تبهين لها انه ممكن نكتشف أشياء نعتقد انها جيدة
+
+261
+00:23:04,380 --> 00:23:10,620
+وبعد هيك نتفاجأ انها عملت مشاكل بالفصل الخامس ان
+
+262
+00:23:10,620 --> 00:23:17,330
+شاء الله هنحكيلكم عن دوةنزل على السوق و بعد هيك
+
+263
+00:23:17,330 --> 00:23:22,410
+عمل مأساة كبيرة يمكن البعض منكوا لما نتكلم عنها و
+
+264
+00:23:22,410 --> 00:23:25,870
+نحط المأساة بالصور ايش عمل في البشر ممكن البعض
+
+265
+00:23:25,870 --> 00:23:35,030
+يبكي مع العلم انه دوى و سوق و أخدون ناس ابحينه انا
+
+266
+00:23:35,030 --> 00:23:39,540
+مش كل اشي بيعملون دراسة قبل ما ينهاركل إشي .. كل
+
+267
+00:23:39,540 --> 00:23:44,720
+إشي بيعملوله دراسة لكن في النهاية بتيجي دراسة أدق
+
+268
+00:23:44,720 --> 00:23:49,460
+من دراسة، شيء إحنا مش منتبهينله، يعني مابندناش
+
+269
+00:23:49,460 --> 00:23:56,540
+ناخد كل شيء إن هو قطعي تماما، بيحاولوا، بيجتهدوا،
+
+270
+00:23:56,540 --> 00:24:03,730
+طبعا أصعب شيء إذا دخلتالتجارة والصناعة في البحث
+
+271
+00:24:03,730 --> 00:24:08,230
+العلمي أثرت على حيادية النتيجة العلمية يعني أن
+
+272
+00:24:08,230 --> 00:24:13,510
+الشركة تخفي معلومات بخصوص منتوجها عشان تبيعه كل
+
+273
+00:24:13,510 --> 00:24:18,670
+شيء وارد .. كل شيء وارد والأمثلة لا تعد ولا تحصر
+
+274
+00:24:18,670 --> 00:24:24,650
+يعني خدوا على سبيل المثال صبغات الشعراللي استعملت
+
+275
+00:24:24,650 --> 00:24:28,170
+كثير و بشكل أساسي صفغات مُركّبات بسمها الـ
+
+276
+00:24:28,170 --> 00:24:32,030
+Pyrosols الان كلها انتهت من السوق في آخر عشر أو
+
+277
+00:24:32,030 --> 00:24:36,230
+خمس عشر سنة استعملته على المدى البعيد بدأ يبين
+
+278
+00:24:36,230 --> 00:24:40,950
+آثار سلبية لها الان بيخترعوا شغلات جديدة أول ما
+
+279
+00:24:40,950 --> 00:24:43,690
+بيخترعوا شغلة جديدة بيجوا و بيقولوا عملنا لها
+
+280
+00:24:43,690 --> 00:24:50,260
+فحوصات و ثبت إنها آمنة و أفضل ربمابعد 15-20 سنة
+
+281
+00:24:50,260 --> 00:24:54,960
+يكتشفوا أضرار معينة إلها ويعود اللي سمع محاضرة عن
+
+282
+00:24:54,960 --> 00:24:59,680
+فضل هذه الأشياء مثلا صبغات التترازينس يسمع محاضرة
+
+283
+00:24:59,680 --> 00:25:04,740
+جديدة بعد 15-20 سنة عن أضرار هذه المادةفالإنسان في
+
+284
+00:25:04,740 --> 00:25:10,160
+هذه المنطقة بصراحة تبقى منطقة علم وليس منطقة تأكد
+
+285
+00:25:10,160 --> 00:25:16,700
+في التشخيص شخصه غلط وهذا أمر طبيعي وفي النهاية
+
+286
+00:25:16,700 --> 00:25:22,440
+بنقدر نقول بالتأكيد ومن خلال أشعة X من ال 1865
+
+287
+00:25:22,440 --> 00:25:27,200
+لليوم ماحدش بيجادل إطلاقا بخصوص شكل البنزين بهذا
+
+288
+00:25:27,200 --> 00:25:32,270
+الشكليعني احنا بنقدر نقول بنسبة كبيرة بس احتراما
+
+289
+00:25:32,270 --> 00:25:37,490
+لمبدأ ان العلم متغير ممكن يقول بنسبة 100% بس ممكن
+
+290
+00:25:37,490 --> 00:25:44,050
+يقول بنسبة 99.9% ان البنزين بهذا الشكل واضح؟ ومن
+
+291
+00:25:44,050 --> 00:25:49,350
+ال 1865 لليوم لأ ما اجهز شكل جديد درس البنزين بهذا
+
+292
+00:25:49,350 --> 00:25:56,750
+الشكلهذا كيكولي الان حكينا عن ال resonance وهذا
+
+293
+00:25:56,750 --> 00:26:02,590
+بيعمل orbitals بحيث انه بتعمل فوق البنزين و تحت
+
+294
+00:26:02,590 --> 00:26:05,010
+البنزين سحابة إلكترونية
+
+295
+00:26:07,750 --> 00:26:11,830
+فكرة وجود سحابة إلكترونية يعني لما أنا أتخيل أن
+
+296
+00:26:11,830 --> 00:26:17,670
+هذا هو البنزين أن هذا هو البنزين و فوقه إلكترونات
+
+297
+00:26:17,670 --> 00:26:21,230
+و تحته إلكترونات جايين من ال بي أوربيتالز يعني
+
+298
+00:26:21,230 --> 00:26:25,450
+كتلة إلكترونات بناء على ذلك هذا الكلام هيفيدني في
+
+299
+00:26:25,450 --> 00:26:30,630
+التفاعلات شو اللي بيقدر يجرب من البنزين عشان
+
+300
+00:26:30,630 --> 00:26:36,830
+يتفاعل معه إيش لازم يكون موجب موجبElectrophile
+
+301
+00:26:36,830 --> 00:26:43,390
+يعني مش ممكن يقدر بالوضع الطبيعي الـ Eucleophile
+
+302
+00:26:43,390 --> 00:26:49,310
+يجرب على البنزين لأن طبيعة الدنيا أن السالب يتنافر
+
+303
+00:26:49,310 --> 00:26:53,610
+مع السالب انا هنا عندي إلكترونات .. أنا هنا عندي
+
+304
+00:26:53,610 --> 00:27:01,590
+إلكترونات أجيب عليها شيء سالبسالب على سالب بيصير و
+
+305
+00:27:01,590 --> 00:27:05,550
+لذلك من أكبر الأخطاء من أكبر الأخطاء اللي
+
+306
+00:27:05,550 --> 00:27:09,270
+بيرتكبوها الطلاب ان احنا مرات لما نيجي نقولهم و
+
+307
+00:27:09,270 --> 00:27:14,550
+الله كيف بتحضروا الفينول الان الطالب اللي مادرسش
+
+308
+00:27:14,550 --> 00:27:18,390
+روح الكيميا و مبادئ الكيميا بيقول يالا بتمشي هاد
+
+309
+00:27:18,390 --> 00:27:23,830
+معايا بيروح برسوملنا بنزين و بيقول في وجود ال OH
+
+310
+00:27:23,830 --> 00:27:33,430
+minus بتبدل H من هنابال OH صرفيلون هذه مشكلة ليش؟
+
+311
+00:27:33,430 --> 00:27:39,570
+لأن هنا إلكترونات وهذه سالبة ممكن هذا الكلام عمره
+
+312
+00:27:39,570 --> 00:27:47,310
+يصير؟ مش ممكنولذلك التفاعل الأساسي لل aromatic
+
+313
+00:27:47,310 --> 00:27:52,230
+compounds هو ال electrophilic substitution زي ما
+
+314
+00:27:52,230 --> 00:27:56,430
+هيمر علينا انه اللي بده يهاجم بده يكون موجب لأنه
+
+315
+00:27:56,430 --> 00:28:01,450
+البنزين عبارة عن سحابة إلكترونية فوق وتحت الجزيرة
+
+316
+00:28:01,450 --> 00:28:03,350
+كذا بده يجي يهاجم سالب ع سالب
+
+317
+00:28:11,350 --> 00:28:15,070
+الان قبل ما ناخد التفاعلات ناخد تسمية الـ aromatic
+
+318
+00:28:15,070 --> 00:28:21,050
+compounds بالنسبة للتسمية في عندنا مركبات أخدت
+
+319
+00:28:21,050 --> 00:28:24,710
+شهرة عبر الزمن هذه بتصير جزء من التسمية و لازم
+
+320
+00:28:24,710 --> 00:28:29,570
+نحفظها و في تسمية اشتقاقية الان في البداية
+
+321
+00:28:29,570 --> 00:28:34,530
+المركبات اللي أخدت شهرة و لازم نحفظها زي ما هي على
+
+322
+00:28:34,530 --> 00:28:40,810
+رأسهاالبنزين يعني احنا سابقا قلنا ان البنزين كان
+
+323
+00:28:40,810 --> 00:28:46,620
+ممكن نسميه Cyclohexatrieneلأن الـ Cyclohexane فيه
+
+324
+00:28:46,620 --> 00:28:51,380
+تلاتة إيل لكن هذا الكلام غير جائز ما بنسميه
+
+325
+00:28:51,380 --> 00:28:56,760
+Cyclohexatriene شو بنسميه؟ بنزين إذا أخد مجموعة
+
+326
+00:28:56,760 --> 00:29:04,120
+CH3 بصير طلوين إذا أخد مجموعة isopropyl اللي هو ال
+
+327
+00:29:04,120 --> 00:29:08,720
+isopropyl بنزين بصير كيومين حكينا عنه سابقا اللي
+
+328
+00:29:08,720 --> 00:29:16,090
+قلنا عنه في الكمونإذا أخد مجموعة الـ vinyl CH
+
+329
+00:29:16,090 --> 00:29:20,790
+double bond CH2 متذاكرينها ال vinyl؟ اه بنقول عنه
+
+330
+00:29:20,790 --> 00:29:27,210
+ال styrene لاحظوا معاه ان هذه المجموعات لها أسماء
+
+331
+00:29:27,210 --> 00:29:32,570
+درسناها لكن ما بنسميه هنا تسمية اشتقاطية يعني
+
+332
+00:29:32,570 --> 00:29:37,800
+مابنفعش ديجي نقول هذا مثل بنزين لأطولوين هذا
+
+333
+00:29:37,800 --> 00:29:44,420
+ايزوبروب البنزين لأ اكيومين هذا فينيل بنزين لأ
+
+334
+00:29:44,420 --> 00:29:50,260
+استيرين هذا هيدروكسي بنزين لأ فينول هذا مثلا
+
+335
+00:29:50,260 --> 00:29:56,360
+مثوكسي بنزين او مثل مثوكسي مجموعة ال او مثل لوحدها
+
+336
+00:29:56,360 --> 00:30:02,640
+لها اسم شو بنسميها مثوكسي لكن ما بنسميه مثوكسي
+
+337
+00:30:02,640 --> 00:30:08,550
+بنزين شو بنسميه أنيزوللو كان في مجموعة ال الديهيد
+
+338
+00:30:08,550 --> 00:30:13,610
+بنسميه بنزالديهيد لو كان في مجموعة ال C double
+
+339
+00:30:13,610 --> 00:30:20,170
+bond OCH3 بنسميه أسيتوفينون لو كان في مجموعة
+
+340
+00:30:20,170 --> 00:30:26,610
+الحامض C double bond OOH بنسميه بنزويك أسيد لو في
+
+341
+00:30:26,610 --> 00:30:32,170
+ال NH2 أنيلين بنقولوش أمينو بنزين، شو بنقوله؟
+
+342
+00:30:32,170 --> 00:30:38,070
+أنيلينالان هذه الأسماء مع الخبرة بالتأكيد لازم
+
+343
+00:30:38,070 --> 00:30:41,650
+تحفظوها يعني لو جيبنا لك ارسم تفاعل ال benz
+
+344
+00:30:41,650 --> 00:30:44,490
+aldehyde او اكتب تفاعل ال benz aldehyde مع كذا
+
+345
+00:30:44,490 --> 00:30:47,510
+ماحدش يجي يقول مش حافظ ال benz aldehyde لأ كل شيء
+
+346
+00:30:47,510 --> 00:30:52,050
+موجود هنا صار جزء من التسمي اللي لازم طالب بتعلم
+
+347
+00:30:52,050 --> 00:30:57,670
+في الجامعة يعرفهامعد ذلك .. معد ذلك بنصير نسمي
+
+348
+00:30:57,670 --> 00:31:01,730
+تسمية اشتقاقية في التسمية الاشتقاقية بنجيب
+
+349
+00:31:01,730 --> 00:31:06,890
+المجموعة اللي موجودة بننهيها غالبا بال O و بنكتب
+
+350
+00:31:06,890 --> 00:31:12,770
+بنزين يعني هنا بروم بصير بروم و بنزين هنا نيترو ..
+
+351
+00:31:12,770 --> 00:31:19,680
+نيترو بنزين هنا اثلإيه في البنزين بروبل بروبل
+
+352
+00:31:19,680 --> 00:31:23,960
+بنزين هذه تسمية اشتقاقية في التسمية الاشتقاقية ايش
+
+353
+00:31:23,960 --> 00:31:30,070
+اللي بيكون موجود عندك أصل البنزينطبعا هنا بدكوا
+
+354
+00:31:30,070 --> 00:31:34,730
+تنتبهوا لنقطة كتير مهمة ان تكون المجموعة اللى
+
+355
+00:31:34,730 --> 00:31:39,130
+موجودة عند إلها اسم و إلا بتغلب يعني لما طلعت هنا
+
+356
+00:31:39,130 --> 00:31:43,890
+كلنا عارفين إنه هذا إثل ولا لأ فكان سهل علي أقول
+
+357
+00:31:43,890 --> 00:31:48,090
+إثل بنزيل كلنا عارفين إنه هذا بروبل ولا لأ سهل إن
+
+358
+00:31:48,090 --> 00:31:52,550
+أقول بروبل بنزيل أحيانا بتواجهكوا مشكلة كيف بدكم
+
+359
+00:31:52,550 --> 00:31:58,390
+تحلوها يعني مثلا لو أنا رسمت هذا المركب و حطيت هنا
+
+360
+00:32:00,820 --> 00:32:08,100
+حلقة بنزين وحطيت هنا CL الأن انتبهوا معي لو واحدة
+
+361
+00:32:08,100 --> 00:32:13,740
+بدت تقول هذه المجموعة بنزين المشكلة هي لم تدرس اسم
+
+362
+00:32:13,740 --> 00:32:19,380
+لهذه المجموعة وفعلا مالهاش اسم وجيتها بحول بعرفنه
+
+363
+00:32:19,380 --> 00:32:24,720
+كالكانبعمله كالكين بقول طب خليني لما عامله كالكين
+
+364
+00:32:24,720 --> 00:32:30,640
+هاي سلسلة كربون واحد اتنين تلاتة اربعة خمسة هاي
+
+365
+00:32:30,640 --> 00:32:35,880
+اطول سلسلة كربون حسب ما احنا اتعلمنا اذا هذا
+
+366
+00:32:35,880 --> 00:32:45,140
+بينتين وعلى اقل ترقيم واحد اتنين تلاتة اربعة خمسة
+
+367
+00:32:45,140 --> 00:32:50,970
+صار three cloroوهذه المجموعة البنزين نفسها فنل
+
+368
+00:32:50,970 --> 00:32:59,270
+اتنين فنل بنتين بيمشي الحال حلنا المشكلة تبعتنا
+
+369
+00:33:00,360 --> 00:33:05,220
+يعني مش ملزمين كل ما نشوف حلقة بنزين إننا لازم
+
+370
+00:33:05,220 --> 00:33:10,460
+ننهي الإسم تبعنا بنزين لأ إذا المجموعة إلها إسم
+
+371
+00:33:10,460 --> 00:33:15,300
+بسيط okay بنسمي بنزين إذا مالهاش هي نفس حلقة
+
+372
+00:33:15,300 --> 00:33:22,100
+البنزين كمجموعة اسمها إيش؟ فنل و بنعمل المركب على
+
+373
+00:33:22,100 --> 00:33:26,300
+إنه الكن و بيك منكون حلنا مشكلتنا
+
+374
+00:33:28,600 --> 00:33:35,240
+فنل بالظبط المجموعة اللى هو C6H6 لما بفقد H بصير
+
+375
+00:33:35,240 --> 00:33:42,480
+C6H5 اسمه فنل واضح؟ وعشان ايه سابقا بتذكر وقلتلكوا
+
+376
+00:33:42,480 --> 00:33:48,400
+ميزوا كلمة فنل عن فنل لإن الفنل شيء الفنل هي هذه
+
+377
+00:33:48,400 --> 00:33:53,090
+المجموعةلكن هذا ماسميناهوش فينيل لإنه ماخد اسم
+
+378
+00:33:53,090 --> 00:33:56,350
+شهرة الستايرين و أخدناله كمان البوليمار اللي
+
+379
+00:33:56,350 --> 00:34:00,110
+بيعمله شو سمينا البوليمار تبعه بوليستايرين
+
+380
+00:34:00,110 --> 00:34:03,270
+البوليمار سميناه بوليستايرين
+
+381
+00:34:10,410 --> 00:34:16,170
+الان لحتى الان اللي احنا سمنا مركبات بنزين فيها
+
+382
+00:34:16,170 --> 00:34:20,470
+one substituent يعني بس ابدلت فيها هيدروجينة واحدة
+
+383
+00:34:20,470 --> 00:34:28,310
+الان طيب يا ترى لو صار عندى ابدال اكثر من مجموعةلو
+
+384
+00:34:28,310 --> 00:34:33,210
+صار عندى إبدال أكثر من مجموعة هنا الحقيقة بيصير
+
+385
+00:34:33,210 --> 00:34:37,730
+عندنا نقطتين بدنا ننتبه لهم لما بيصير عندى إبدال
+
+386
+00:34:37,730 --> 00:34:44,230
+أكثر من مجموعة خليني أرسم مركب بشكل يعني هيك شوية
+
+387
+00:34:44,230 --> 00:34:53,530
+عشوائي لو كتبت هنا CH3 مثلا و هنا Pro هاي صار عليه
+
+388
+00:34:53,530 --> 00:34:59,680
+مجموع تانيهل يا تورا .. هل يا تورا بدي اعتبر ان
+
+389
+00:34:59,680 --> 00:35:04,880
+المركب الاصلي اللي عندى هو هذا اللى كان اسمه طلوين
+
+390
+00:35:04,880 --> 00:35:09,220
+و اقول ع موقع واحد اتنين تلاتة بيحمل بروم اسميه
+
+391
+00:35:09,
+
+445
+00:40:01,560 --> 00:40:06,600
+two chloro three مثل ال alphabetical ذكرتهم
+
+446
+00:40:06,600 --> 00:40:19,750
+ماتبهين؟ five bromo two chloro three مثل فينول إذا
+
+447
+00:40:19,750 --> 00:40:24,810
+لو زادوا ال substituents اللى عندى عن تنتين أكيد
+
+448
+00:40:24,810 --> 00:40:29,350
+بستعمل الأرقام لو كانوا تنتين ربما نقول الأفضل
+
+449
+00:40:29,350 --> 00:40:33,550
+نستعمل الأرقام و نسيبنا من قصة ارثه ميته برة الان
+
+450
+00:40:33,550 --> 00:40:36,570
+اذا اي واحدة بدأ تيجي بدل رقم اتنين لما بيكون two
+
+451
+00:40:36,570 --> 00:40:40,730
+substituents تحط ارثه بدل تلاتة ميته و بدل اربعة
+
+452
+00:40:40,730 --> 00:40:46,920
+برة مافيش عندنا مشكلة مثلا هذا المركب
+
+453
+00:40:46,920 --> 00:40:52,060
+Orthodiachlorobenzene هذا ميتا دايمثلبنزين لكن
+
+454
+00:40:52,060 --> 00:40:58,080
+دايمثلبنزين بياخد اسم شهرة إكزايلين ولذلك مرة سئلنا
+
+455
+00:40:58,080 --> 00:41:01,580
+الطلاب في الامتحان ارسمولنا بار اكزايلين احنا
+
+456
+00:41:01,580 --> 00:41:05,260
+بنقول اكزايلين اللي فيه مجمعتين مثل اذا كانوا جانب
+
+457
+00:41:05,260 --> 00:41:10,400
+بعض واحد اتنين اورث اكزايلين اذا واحد تلاتة مائة
+
+458
+00:41:10,400 --> 00:41:14,800
+اكزايلين طب لو يجي واحد اربعة بار اكزايلين واضح
+
+459
+00:41:14,800 --> 00:41:20,540
+الفكرة هذا المركب مثلا واضح انه في كلورو الديهايد
+
+460
+00:41:20,540 --> 00:41:25,700
+وانه اعتبر العائلة ال الديهايد ورقم من عندها فجال
+
+461
+00:41:25,700 --> 00:41:30,360
+المركب بنزل ديهايد وحطله بارا كلورو بنزل ديهايد او
+
+462
+00:41:30,360 --> 00:41:34,440
+four كلورو بنزل ديهايد لكن السؤال اللي حتى الآن ما
+
+463
+00:41:34,440 --> 00:41:42,400
+جوابناهوش ليش قلنا العائلة ال الديهايد مش لكلور او
+
+464
+00:41:42,400 --> 00:41:51,490
+الـ OH الـ OH مش الكلور ولا الميثل ولا البروم هذا
+
+465
+00:41:51,490 --> 00:41:57,850
+السؤال مهم ان نشوفه الان ببساطة امرتبين ال
+
+466
+00:41:57,850 --> 00:42:01,530
+constituents بترتيب اللي موجود في اعلى بنعتبره
+
+467
+00:42:01,530 --> 00:42:09,890
+العائلة اول شئ ال halogens هدول اقل مجموعة اقل من
+
+468
+00:42:09,890 --> 00:42:15,330
+ال alkanes الان ابدأوا تلاحظوا لو وجدت .. و زي الـ
+
+469
+00:42:15,330 --> 00:42:19,750
+halogens الـ Nitro، الآن الـ O2 لو وجدت ال halogen
+
+470
+00:42:19,750 --> 00:42:25,450
+مع ال cane، يعني كلور مع مثل، من العائلة؟ المثل لو
+
+471
+00:42:25,450 --> 00:42:31,630
+وجدت Nitro مع مثل، من العائلة؟ المثل، واضح؟ أقل من
+
+472
+00:42:31,630 --> 00:42:40,100
+ال alkenes لو وجدت ال cane و ال cane من العائلة ال
+
+473
+00:42:40,100 --> 00:42:45,100
+الكين الان لاحظوا هي العائلة ال الكين هذا إيه اسمه
+
+474
+00:42:45,100 --> 00:42:51,980
+استيرين حيصير واحد اتنين تلاتة ال three مثل
+
+475
+00:42:51,980 --> 00:42:57,640
+استيرين هذا إيه اسمه طلوين حيصير ال three نيترو
+
+476
+00:42:57,640 --> 00:43:05,060
+طلوين طبعا ال الكين أقل من ال amines أقل من ال OH
+
+477
+00:43:06,510 --> 00:43:10,790
+ولذلك لو وجدت مثلًا OH مع الـ Cl مين العائلة؟ OH
+
+478
+00:43:10,790 --> 00:43:15,910
+إذا مُركّبة فينول؟ فينول لاحظوا إحنا قلنا ال
+
+479
+00:43:15,910 --> 00:43:23,170
+الكينز أقل من إيش؟ النيترو اتطلعوا معاه هاي الكين
+
+480
+00:43:23,170 --> 00:43:28,810
+طلوين و تلاتة نيترو بعتبر إن الترقيم إنها واحد،
+
+481
+00:43:28,810 --> 00:43:32,870
+اتنين، تلاتة، أربعة، خمسة، ستة إذا صار عند اتنين،
+
+482
+00:43:32,870 --> 00:43:36,890
+أربعة، ستة، تري، نيترو، طلوين هذا مُركّب الـ TNT
+
+483
+00:43:36,890 --> 00:43:46,230
+المتفجر لو وجد كيتون أكتر من الـ OH و الألديهيد
+
+484
+00:43:46,230 --> 00:43:51,650
+أعلى من الكيتون و الأسد أعلى منهم كلهم و ال إيستر
+
+485
+00:43:51,650 --> 00:43:56,710
+أعلى و أعلى ولذلك هنا لدي ألديهيد و OH من العائلة
+
+486
+00:43:58,000 --> 00:44:03,540
+الالديهايد اذا بنزالديهايد عند الديهايد وكيتون من
+
+487
+00:44:03,540 --> 00:44:10,980
+العائلة الديهايد عند الاسد وكيتون الاسد عند
+
+488
+00:44:10,980 --> 00:44:18,240
+الالكول ونيترو و أتش ونيترو و أتش
+
+489
+00:44:18,240 --> 00:44:23,930
+واضح؟ لو كان عندى halogens بينهم وبين بعض مش مشكلة
+
+490
+00:44:23,930 --> 00:44:28,250
+بنكتبهم alphabetical يعني ال brom قبل ال chlorine
+
+491
+00:44:28,250 --> 00:44:32,250
+ال alkyn
+
+492
+00:44:32,250 --> 00:44:40,430
+زى ال alkene بيكون أعلى من ال alkene ال eastern
+
+493
+00:44:40,430 --> 00:44:49,760
+من المشتقات الحامض هندرسه السيدة بالمندق OOR عائلة
+
+494
+00:44:49,760 --> 00:44:52,840
+بناخدها بعدين، الآن احنا بنحط الصورة الكلية،
+
+495
+00:44:52,840 --> 00:44:56,040
+بتهيألي ضمن هذه الصورة الكلية بيصير موضوع التسمية
+
+496
+00:44:56,040 --> 00:45:01,870
+أصبح واضح لكم الـ slide اللي بننهي عندها انه هذه
+
+497
+00:45:01,870 --> 00:45:05,650
+بتتدربوا طبعا انتوا على التسمية و لو روحتوا على
+
+498
+00:45:05,650 --> 00:45:09,910
+الأمثلة اللي معاكم في امتحانات سابقة هتلاحظوا
+
+499
+00:45:09,910 --> 00:45:12,730
+دائما جايبيني اللي كنت اسمها aromatic compounds
+
+500
+00:45:12,730 --> 00:45:17,210
+بتفتشوا مين أعلى في المجموعات و تنسبوا إليها زي
+
+501
+00:45:17,210 --> 00:45:20,810
+الأمثلة الكتيرة اللي عرضناها الآن آخر نقطة بنحكيها
+
+502
+00:45:20,810 --> 00:45:25,330
+انه هذه ال aromatic compounds في نهاية مش رموزهي
+
+503
+00:45:25,330 --> 00:45:29,930
+مركبات على أرض الواقع يستفيد الإنسان منها والدليل
+
+504
+00:45:29,930 --> 00:45:34,130
+على هيك هاي بعض ال aromatic compounds اللي في صميم
+
+505
+00:45:34,130 --> 00:45:38,310
+الحياة تبع الإنسان يعني هذا المركب aromatic ولا
+
+506
+00:45:38,310 --> 00:45:43,070
+لأ؟ هذا اسمه Aspirin ال Aspirin اللي أنتوا بتاخدوه
+
+507
+00:45:43,070 --> 00:45:47,010
+تمام؟ تلت ارباع الناس بعد حصة ال organic يا
+
+508
+00:45:47,010 --> 00:45:53,190
+Aspirin يا Trophin تعرفولي Trophin أربع .. هايو ال
+
+509
+00:45:53,190 --> 00:45:59,260
+Ibuprofen وإذا روحوا ع البيت و بدهم ياكلوا بدهم كيك
+
+510
+00:45:59,260 --> 00:46:03,780
+و الكيك بده فانيلا و الفانيلا من الفانيليل من
+
+511
+00:46:03,780 --> 00:46:08,640
+الفانيليل هي الفانيلا واضح فإحنا مش بنحكي عن رموز
+
+512
+00:46:08,640 --> 00:46:12,500
+بقدر ما بنحكي حقيقة عن مركبات في واقع الاستعمال
+
+513
+00:46:12,500 --> 00:46:16,860
+الحياتي و الطب و لذلك بندرس ال organ ال chemistry
+
+514
+00:46:16,860 --> 00:46:21,340
+و ان شاء الله المرة القادمة بكون موضوعنا تفاعلات
+
+515
+00:46:21,340 --> 00:46:22,940
+ال aromatic compounds
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..541778672a8c30813817e5cc129232b4a41f5111
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_postprocess.srt
@@ -0,0 +1,2060 @@
+1
+00:00:20,860 --> 00:00:25,560
+بسم الله الرحمن الرحيم اليوم موضوعنا ان شاء الله
+
+2
+00:00:25,560 --> 00:00:29,680
+هيكون في الفصل الرابع ال aromatic compounds لكن
+
+3
+00:00:29,680 --> 00:00:36,220
+ضال علينا شغلة صغيرة انا بعتقد انها مهمة من الفصل
+
+4
+00:00:36,220 --> 00:00:41,640
+الثالث من تفاعلات ال alkynes فخلينا نشوف هذه
+
+5
+00:00:41,640 --> 00:00:47,680
+النقطة بسرعة و بعدين ننتقل لموضوعنا الأساسي اللي
+
+6
+00:00:47,680 --> 00:00:53,620
+هو ال aromatic compoundsالنقطة اللى ضالت علينا انه
+
+7
+00:00:53,620 --> 00:01:00,580
+احنا لما بننظر لل Alkynes اذا كان على احد أطرافهم
+
+8
+00:01:00,580 --> 00:01:06,020
+على اقل تقدير او ممكن على الطرفين ذرّة هيدروجين
+
+9
+00:01:06,020 --> 00:01:11,400
+يعني ال Alkyne ممكن يكون R C triple bond C وR تاني
+
+10
+00:01:11,400 --> 00:01:16,040
+يعني مثل و مثل او فلل و فلل و ممكن يكون R C triple
+
+11
+00:01:16,040 --> 00:01:22,690
+bond C وموجودزرّة هيدروجين الالكاين اللي بهذا
+
+12
+00:01:22,690 --> 00:01:27,670
+الشكل اللي في أحد أطرافه زرّة هيدروجين بنسميه احنا
+
+13
+00:01:27,670 --> 00:01:32,350
+terminal الكاين يعني الكاين الطرفي اللي في أحد
+
+14
+00:01:32,350 --> 00:01:39,440
+أطرافه ايش فيها terminal الكاينهذه النقطة الأولى
+
+15
+00:01:39,440 --> 00:01:43,300
+إذا عرفنا إيش معناه Terminal Alkyne اللي على طرف
+
+16
+00:01:43,300 --> 00:01:49,960
+من الرابط الزوجية فيه موجود عنده ذرة هيدروجين الآن
+
+17
+00:01:49,960 --> 00:01:54,960
+بنضيف معلومة جديدة بنقول ال terminal alkynes are
+
+18
+00:01:54,960 --> 00:02:00,680
+acidic ال terminal alkynes are acidic إيش يعني
+
+19
+00:02:00,680 --> 00:02:07,200
+acidic؟حامضي الان لو انا اجيت اتذكر تعريف الحامض
+
+20
+00:02:07,200 --> 00:02:10,980
+ممكن ناخد في هذه المرحلة تعريف الوري برونستيد الـ
+
+21
+00:02:10,980 --> 00:02:19,780
+acid proton donor بيعطي بروتونات بيفقد بروتون الان
+
+22
+00:02:19,780 --> 00:02:24,660
+اي بروتون حامضي في هذا المركب يعني لحظوا انا لما
+
+23
+00:02:24,660 --> 00:02:29,460
+رسمت هنا مركب في عندي هنا حلقة Cyclohexane و عليها
+
+24
+00:02:29,460 --> 00:02:34,030
+هيدروجينأو في مجموعات الميثل والإثل والبروبل
+
+25
+00:02:34,030 --> 00:02:38,430
+الالكينز كلها ملانة هيدروجين كل هذه الهيدروجينات
+
+26
+00:02:38,430 --> 00:02:42,730
+اللي في الالكينز و اللي في الالكينز هيدروجينات غير
+
+27
+00:02:42,730 --> 00:02:46,590
+حامضية ايش معنى هيدروجين غير حامضي انه لا يفقد
+
+28
+00:02:46,590 --> 00:02:51,370
+بسهولة عند التفاعل مع قاعدةالهيدروجين الحامضي
+
+29
+00:02:51,370 --> 00:02:56,150
+هيدروجين يفقد بسهولة إذا تم التفاعل مع القاعدة
+
+30
+00:02:56,150 --> 00:03:00,930
+ولذلك لما نتطلع على مركب عضوي هنلاحظ أنه دائما
+
+31
+00:03:00,930 --> 00:03:04,330
+المركب العضوي في نوعين من الهيدروجين يعني خليني
+
+32
+00:03:04,330 --> 00:03:12,190
+أخد مثلا حمض الخل كمثال بسيط حمض الخل CH3COO
+
+33
+00:03:13,740 --> 00:03:19,780
+OH الآن في عندى نوعين من الهيدروجين هنا هدول التلت
+
+34
+00:03:19,780 --> 00:03:24,400
+هيدروجينات هيدروجينات عادية لو انا كنت بفاعل مع
+
+35
+00:03:24,400 --> 00:03:28,820
+قاعدة لا يفقدوا مع القاعدة they are non acidic مش
+
+36
+00:03:28,820 --> 00:03:34,580
+هيدروجين حامضى الان الهيدروجين اللى متصل بال OH في
+
+37
+00:03:34,580 --> 00:03:39,320
+الحامض هذا هيدروجين حامضى هذا اللى بيفقد لما انا
+
+38
+00:03:39,320 --> 00:03:44,630
+باجى بعمل تفاعل مع baseفصار في عندى acidic
+
+39
+00:03:44,630 --> 00:03:49,530
+hydrogen و non acidic hydrogen او بيكون على اقل
+
+40
+00:03:49,530 --> 00:03:54,370
+تقدير اضعف المسألة مسألة ضعف و قوة يعنى هذه
+
+41
+00:03:54,370 --> 00:03:58,770
+الهيدروجينة حمضية بشكل كبير تفقد بسهولة هذه حمضية
+
+42
+00:03:58,770 --> 00:04:04,270
+بشكل قليل جدا تفقد بصعوبةممكن لو جيبنا base قوي
+
+43
+00:04:04,270 --> 00:04:08,810
+جدا جدا عود نفقدها لكن على base عادي مثلا خلّيني
+
+44
+00:04:08,810 --> 00:04:12,410
+أقول Sodium Hydroxide أو حتى Sodium Carbonate
+
+45
+00:04:12,410 --> 00:04:17,490
+قاعدة عادية بدي أفعلها أي هيدروجين اللي بدي تفقد
+
+46
+00:04:17,490 --> 00:04:22,450
+الـ acidic هيدروجين عشان ذلك بكل كوب تذكروا
+
+47
+00:04:22,450 --> 00:04:28,470
+التفاعل زائد MAالـ OH هي الـ base of Sodium
+
+48
+00:04:28,470 --> 00:04:32,670
+Hydroxide الأن الـ OH هي الـ base مع هذه الـ H
+
+49
+00:04:32,670 --> 00:04:39,830
+كنتوا متعودين تقولوا بيكون عندك ماء حمض زائد قاعدة
+
+50
+00:04:39,830 --> 00:04:44,650
+ملح زائد ماء لما هذه الـ H تفقد على شكل H plus
+
+51
+00:04:44,650 --> 00:04:49,880
+هتظل إلكتروناتالرابطة بتاعتها بالاضافة لزوجين
+
+52
+00:04:49,880 --> 00:04:54,700
+الأساسيات الاساسيات حيصير عليكم CH3C double bond O
+
+53
+00:04:54,700 --> 00:05:00,100
+O كم زوج إلكترونات عليها تلاتة أصلا زوجين
+
+54
+00:05:00,100 --> 00:05:04,220
+إلكترونات و رابطتين فقدت ال H لواحدها بدون
+
+55
+00:05:04,220 --> 00:05:10,000
+إلكتروناتها عشان ال H plus ال OH minus أخدت إيش ال
+
+56
+00:05:10,000 --> 00:05:18,210
+H plus شو صفية هذه minus مع ال NAplus صار sodium
+
+57
+00:05:18,210 --> 00:05:23,650
+acetate خلات الصوديوم acidic acid زايد NaOH Sodium
+
+58
+00:05:23,650 --> 00:05:30,450
+acetate زايد H2O حمض زايد قاعدة ملح زايد ماء هذا
+
+59
+00:05:30,450 --> 00:05:35,090
+تذكير خلينا نقول بمفهوم الحمض والقاعدة الآن لو
+
+60
+00:05:35,090 --> 00:05:40,690
+اجينا نطبق بنفس المنطق على ال terminal الكاين و
+
+61
+00:05:40,690 --> 00:05:47,550
+اتخيلنا ان هذا ال terminal الكاين عبارة عنacid وين
+
+62
+00:05:47,550 --> 00:05:53,450
+ال acidic hydrogen اللي فيه هادف الان نتخيل انه
+
+63
+00:05:53,450 --> 00:05:57,910
+عندنا رابطة بين الكربون و الهيدروجين لاحظوا معي
+
+64
+00:05:57,910 --> 00:06:03,350
+الكربون لا يحمل اي زوج إلكترونات حرة فيه اربع
+
+65
+00:06:03,350 --> 00:06:08,190
+روابط و لذلك حتى الكربون بشكله الطبيعي كان بيصلح
+
+66
+00:06:08,190 --> 00:06:14,950
+اللأ تذكروا المرات الماضية قلنا ان ال oxygen في
+
+67
+00:06:14,950 --> 00:06:18,370
+رابطتين و زوجين إلكترونات من خلال أزواج
+
+68
+00:06:18,370 --> 00:06:22,940
+الإلكترونات بيعمل ال UQ fileالنيتروجين في تلت
+
+69
+00:06:22,940 --> 00:06:28,060
+روابط وزوج إلكترونات أيضا بيعمل الـ eucleophile من
+
+70
+00:06:28,060 --> 00:06:33,720
+خلال زوج الإلكترونات الهالوجين في رابطة تلت أزواج
+
+71
+00:06:33,720 --> 00:06:37,020
+إلكترونات أيضا ممكن يعمل الـ eucleophile من خلال
+
+72
+00:06:37,020 --> 00:06:42,850
+أزواج الإلكترونات الكاربونفي أربع روابط فبالوضع
+
+73
+00:06:42,850 --> 00:06:47,850
+الطبيعي هل ال carbon بيعمل ال nucleophile لأ واضح
+
+74
+00:06:47,850 --> 00:06:52,490
+الان لو اتيت لهذا المركب فعالته مع strong base
+
+75
+00:06:52,490 --> 00:06:59,410
+NaNH2 هذه موازية تماما لل NaOH يعني كلكم بتعرفوا ك
+
+76
+00:06:59,410 --> 00:07:08,630
+base NaOH شو كنا نسميها Sodium Hydroxide الان
+
+77
+00:07:08,630 --> 00:07:17,130
+NaNH2 شبه بها تماما بنسميها Sodium Amide وهذه
+
+78
+00:07:17,130 --> 00:07:20,670
+قاعدة
+
+79
+00:07:20,670 --> 00:07:25,250
+قوية اقوى من Sodium Hydroxide اقوى من Sodium
+
+80
+00:07:25,250 --> 00:07:31,110
+Hydroxide لما نيجي نتخيل ان هذا الحمد وهذه القاعدة
+
+81
+00:07:31,860 --> 00:07:37,260
+هتيجي ال N H2 تتفاعل مع ال H Plus لوحدها شو
+
+82
+00:07:37,260 --> 00:07:44,800
+هتعطيني N H3 زي ما كانت ال O H minus تاخد ال H ال
+
+83
+00:07:44,800 --> 00:07:52,600
+N H2 minus بتاخد ال H O H مع H H2O N H2 minus مع H
+
+84
+00:07:52,600 --> 00:07:59,980
+N H3 نفس التفاعل الآن لما فقدت هذه ال H شو دل على
+
+85
+00:07:59,980 --> 00:08:07,790
+الكربون؟تلات روابط و إلكترونين إلكترونين قصدكم زوج
+
+86
+00:08:07,790 --> 00:08:11,930
+إلكترونات واحد تلات روابط و إلكترونين هاي واضحها
+
+87
+00:08:11,930 --> 00:08:17,070
+تلات روابط و إلكترونين الآن لو إجينا حسبنا ال
+
+88
+00:08:17,070 --> 00:08:23,130
+formal charge على هذه ال carbon أربعةالكربون ناقص
+
+89
+00:08:23,130 --> 00:08:28,370
+تلات روابط ناقص إلكترونين minus one صارت الكربون
+
+90
+00:08:28,370 --> 00:08:34,070
+minus والصوديوم plus هذا بنسميه صوديوم أستيلايد زي
+
+91
+00:08:34,070 --> 00:08:37,370
+ما مثلا مع ال hcl بنقول صوديوم كلورايد وصوديوم
+
+92
+00:08:37,370 --> 00:08:41,710
+برومايد في التفاعلات الآن لاحظوا إيش اللي نشأ عندى
+
+93
+00:08:41,710 --> 00:08:48,050
+الآنIon سالب carbon nucleophile صار في عندي carbon
+
+94
+00:08:48,050 --> 00:08:52,550
+عليه أزواج إلكترونات يعني لو روحت بدي أخد هذا ال
+
+95
+00:08:52,550 --> 00:08:58,170
+Ion اللي نتج عنده و أفعله أي تفاعل كان nucleophile
+
+96
+00:08:58,170 --> 00:09:03,330
+بتفعل ولا لأ بتفعل فهذه المركبات اللي عادة بنعطيها
+
+97
+00:09:03,330 --> 00:09:10,390
+اسم العام Acetylides they are in fact carbon
+
+98
+00:09:10,390 --> 00:09:14,670
+nucleophilesيعني لو قلنا ال Acetylates ايش ممكن
+
+99
+00:09:14,670 --> 00:09:21,470
+نعتبرها؟ Carbon Enucleophile الان لاحظوا انه ال
+
+100
+00:09:21,470 --> 00:09:25,290
+carbon بالوضع الطبيعي كان سهل يكون عامل carbon
+
+101
+00:09:25,290 --> 00:09:30,070
+enucleophile لأ بعملش لكن انا لما فقدت بروتون منه
+
+102
+00:09:30,070 --> 00:09:33,870
+و خلت زوجي الإلكترونات صار هذا زوجي الإلكترونات
+
+103
+00:09:33,870 --> 00:09:39,090
+اللي على ال carbon يمثل carbon enucleophile طالما
+
+104
+00:09:39,090 --> 00:09:44,920
+انه اتكون عندي carbon enucleophileبقدر يتفاعل الـ
+
+105
+00:09:44,920 --> 00:09:49,900
+nucleophile مثلا لو اتي اتفاعلته مع مثل ايودايد
+
+106
+00:09:49,900 --> 00:09:55,160
+ممكن يعمل تفاعل ابدال ان هذا زوج الالكتروناتي هاجم
+
+107
+00:09:55,160 --> 00:09:59,600
+على الكربون و يطرد اليود مع زوج الالكتروناتي هذا
+
+108
+00:09:59,600 --> 00:10:04,190
+ايش اسم التفاعل؟Substitution Reaction أو تفاعل
+
+109
+00:10:04,190 --> 00:10:10,450
+إحلال الـ Eucleophil بيحل محل الـ Eucleophil بيجي
+
+110
+00:10:10,450 --> 00:10:14,690
+الكربون مع زوج الإلكترونات اللي معه بيحل محل اليود
+
+111
+00:10:14,690 --> 00:10:19,150
+و بيطلع اليود مع زوج الإلكترونات بدل ما كان عنده
+
+112
+00:10:19,150 --> 00:10:24,120
+أنا Sodium Acetylide هيطلع عندى في النهايةSodium
+
+113
+00:10:24,120 --> 00:10:29,920
+Iodide يعني كأنه هذا تفاعل تبادل مزدوج اللي مار
+
+114
+00:10:29,920 --> 00:10:36,540
+عليكم واضح ففائدة هذا التفاعل ان هو وفر لي ال
+
+115
+00:10:36,540 --> 00:10:40,520
+carbon nucleophile اللي بالوضع المتعادل عادة مش
+
+116
+00:10:40,520 --> 00:10:43,920
+متوفر وانا بعد هيك باستفيد من ال carbon
+
+117
+00:10:43,920 --> 00:10:49,780
+nucleophile في تفاعلات الإبدال وغيرها ممكن الآننجي
+
+118
+00:10:49,780 --> 00:10:56,760
+نختبر معلوماتكم احنا المرة الماضية أخدنا عن تفاعل
+
+119
+00:10:56,760 --> 00:11:02,980
+كنا بنستعمل فيه الـUQ5 مين تتذكر شو هو التفاعل الـ
+
+120
+00:11:02,980 --> 00:11:08,430
+Epoxide كان يعمل ring openingمع اليوكليوفايل لما
+
+121
+00:11:08,430 --> 00:11:12,430
+أخدنا تفاعل الابوكسايد المعادلة العامة اللى
+
+122
+00:11:12,430 --> 00:11:18,270
+كتبناها كنا نقول اليوكليوفايل عليه أزواج إلكترونات
+
+123
+00:11:18,270 --> 00:11:24,510
+زائد الابوكسايد كان بيفتح الحلقة بيعطينا CH2 إذا
+
+124
+00:11:24,510 --> 00:11:33,010
+افترضنا هذه CH2 OH و بيجي هنا بتفاعل إيشلنكليوفايل
+
+125
+00:11:33,010 --> 00:11:36,950
+هى ال ring opening اللى أخدناه لل Epoxides الان
+
+126
+00:11:36,950 --> 00:11:41,250
+بدنا نيجي نعوض بدل كلمة نكليوفايل زى ما تعون
+
+127
+00:11:41,250 --> 00:11:46,850
+الرياضيات بيكتب X و Y للمجهيل بدنا نجيب لنكليوفايل
+
+128
+00:11:46,850 --> 00:11:55,250
+تبعنا الacetylide يعنىCH3C triple bond C ويحمل زوج
+
+129
+00:11:55,250 --> 00:12:00,730
+إلكترونات صار إيش minus و الفاعل هذا مع هدف شو
+
+130
+00:12:00,730 --> 00:12:07,430
+بتتوقع بده يكون الناتج بده يشبك من
+
+131
+00:12:07,430 --> 00:12:11,530
+خلال زوج الإلكترونات هذا إذا أنا لما بحط الناتج
+
+132
+00:12:11,530 --> 00:12:16,070
+هنا ممكن أحطه باللون الأحمر هيكون بهذا الشكل C
+
+133
+00:12:16,070 --> 00:12:18,190
+triple bond C
+
+134
+00:12:22,290 --> 00:12:27,350
+هذه الاسيتيلايد اتفاعل كان يوكليوفايل هاجم على
+
+135
+00:12:27,350 --> 00:12:33,490
+الكربون وعمل ring opening و تم التفاعل بشكل كامل
+
+136
+00:12:33,490 --> 00:12:34,770
+واضح؟
+
+137
+00:12:38,830 --> 00:12:43,190
+فهمنا اذا هذه النقطة اللى كانت ضايلة عندنا من ال
+
+138
+00:12:43,190 --> 00:12:47,570
+chapter تلاتة انه نفهم ايش معنى terminal alkynes
+
+139
+00:12:47,570 --> 00:12:51,390
+نمرة واحد، نمرة اتنين ان نقول ان terminal alkynes
+
+140
+00:12:51,390 --> 00:12:56,110
+are acidic when reacted with bases they form
+
+141
+00:12:56,110 --> 00:13:00,170
+carbon enucleophiles الآن ال carbon enucleophiles
+
+142
+00:13:00,170 --> 00:13:02,810
+are like any nucleophile they can undergo
+
+143
+00:13:02,810 --> 00:13:06,590
+substitution reactions or any enucleophilic
+
+144
+00:13:06,590 --> 00:13:07,150
+reaction
+
+145
+00:13:11,320 --> 00:13:17,460
+بهيك بننتهي من الفصل التالت في عندكم بالتأكيد
+
+146
+00:13:17,460 --> 00:13:21,660
+تدريبات موجودة و احيانا محلولة اكمال المعادلات و
+
+147
+00:13:21,660 --> 00:13:27,320
+ما إلى ذلك بعتقد انه بيكون جزء من المطلوب منكم ان
+
+148
+00:13:27,320 --> 00:13:36,660
+تجتهدوا في تحضيرها و فاهمها بننتقل مباشرة ل الفصل
+
+149
+00:13:36,660 --> 00:13:43,940
+الرابع و الفصل الرابع بعنوانAromatic compoundsربما
+
+150
+00:13:43,940 --> 00:13:47,500
+ال aromatic compounds لو بدنا نشوف موقعها من
+
+151
+00:13:47,500 --> 00:13:52,720
+الإعراب في ال hydrocarbons they are unsaturated
+
+152
+00:13:52,720 --> 00:13:56,700
+hydrocarbons احنا درسنا ال الكينز ال cycloalkyns
+
+153
+00:13:56,700 --> 00:14:00,160
+ال الكينز ال alkynes ضال علينا ال aromatic
+
+154
+00:14:00,160 --> 00:14:03,540
+compounds الآن أبسط تعريف ممكن نعطيله ال aromatic
+
+155
+00:14:03,540 --> 00:14:07,520
+compounds they are بنزين like compounds المركبات
+
+156
+00:14:07,520 --> 00:14:14,170
+اللي زي البنزين بمعنى فيهم الحلقة و فيهمأزواج
+
+157
+00:14:14,170 --> 00:14:20,550
+الألكترونات أو الروابط الزوجية بشكل معين وبعدد
+
+158
+00:14:20,550 --> 00:14:26,730
+معين الان في نقطة كتير مهمة يمكن كل هذا ال slide
+
+159
+00:14:26,730 --> 00:14:33,530
+أخدناها ماعدا نقطة واحدة اللي هو ايش طول الرابط في
+
+160
+00:14:33,530 --> 00:14:37,930
+البنزينما هو bond order في البنزين وما هو طول
+
+161
+00:14:37,930 --> 00:14:41,230
+الرابط في البنزين احنا أخدنا معلومات عن الرابط
+
+162
+00:14:41,230 --> 00:14:45,910
+الأحدية والثنائية والثلاثية طبعا كلكوا انتوا
+
+163
+00:14:45,910 --> 00:14:49,950
+متذكرين البنزين ومتذكرين ال resonance structures
+
+164
+00:14:49,950 --> 00:15:01,270
+اللي بيعملها بهذا الشكل و بهذا الشكل الان لو اتيت
+
+165
+00:15:01,270 --> 00:15:06,210
+طلعت على رابط معين خليني اقول هذه الرابطةهذه
+
+166
+00:15:06,210 --> 00:15:11,810
+الرابطة هنا تبدو إيش؟ أحدية هذه الرابطة هنا تبدو
+
+167
+00:15:11,810 --> 00:15:16,850
+أحدية هذه الرابطة هنا تبدو ثنائية الآن احنا بنقول
+
+168
+00:15:16,850 --> 00:15:20,770
+البنزيل in resonance structure يعني بين هذه وبين
+
+169
+00:15:20,770 --> 00:15:25,970
+هذه بناء على ذلك لو بدي أجي أسأل ال bond order في
+
+170
+00:15:25,970 --> 00:15:31,130
+البنزيل قداشر هل هو يا ترى أحدى ولا ثنائي؟ هو قاعد
+
+171
+00:15:31,130 --> 00:15:36,830
+بتقلببين الواحد والاتنين بال average ايش هتطلع ال
+
+172
+00:15:36,830 --> 00:15:41,510
+bond order واحد و نص و ال bond order ممكن تيجي كسب
+
+173
+00:15:41,510 --> 00:15:45,350
+و لذلك لو اجيت سألت ايش ال bond order في البنزين
+
+174
+00:15:45,350 --> 00:15:53,590
+واحد و نص هذه الكلمة مهمة جدا جدا هذه الكلمة مهمة
+
+175
+00:15:53,590 --> 00:15:59,790
+جدا جدا عارفين ليش لأنه انا درست الرابط الاوحدية
+
+176
+00:15:59,790 --> 00:16:05,520
+في chapter الالكينزو تفاعلاتها و درست الرابط
+
+177
+00:16:05,520 --> 00:16:09,560
+الثنائية في chapter ال alkanes و تفاعلاتها اللي هي
+
+178
+00:16:09,560 --> 00:16:17,570
+بشكل أساس تفاعلات الإضافة ال A بجعل ال aromaticلو
+
+179
+00:16:17,570 --> 00:16:20,710
+ان هذه الرابطة احدية كان كل معلومات ال الكينز
+
+180
+00:16:20,710 --> 00:16:24,770
+منطبق على البنزين لو انها ثنائية كان كل معلومات ال
+
+181
+00:16:24,770 --> 00:16:29,450
+الكينز منطبق على البنزين الان الرابطة لا احدية ولا
+
+182
+00:16:29,450 --> 00:16:34,710
+ثنائية واحد و نص ولذلك ولا تفاعل من تفاعلات ال
+
+183
+00:16:34,710 --> 00:16:39,110
+الكينز ولا تفاعل من تفاعلات ال الكينز منطبق على
+
+184
+00:16:39,110 --> 00:16:43,430
+البنزين بنلاحظ ان البنزين هيصير له كيميا خاصة فيه
+
+185
+00:16:44,110 --> 00:16:48,990
+لأنه لا هو رابطة أحدية ولا هو رابطة ثنائية لا هو
+
+186
+00:16:48,990 --> 00:16:54,770
+الكل ولا هو الكل واضح هذا النقطة هذا الكلام يتبع
+
+187
+00:16:54,770 --> 00:16:58,710
+كمان شغلة أنه لو أنا بدي أتي أحكي عن ال bond
+
+188
+00:16:58,710 --> 00:17:03,310
+length قلنا احنا أنه رابطة الأحدية طويلة الرابطة
+
+189
+00:17:03,310 --> 00:17:10,160
+الثنائية قصيرة الآن رابطة البنزينوين هتكون؟ بين
+
+190
+00:17:10,160 --> 00:17:14,740
+بين وبين
+
+191
+00:17:14,740 --> 00:17:15,160
+وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين
+
+192
+00:17:15,160 --> 00:17:15,760
+وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين
+
+193
+00:17:15,760 --> 00:17:20,320
+وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين
+
+194
+00:17:20,320 --> 00:17:20,380
+وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين
+
+195
+00:17:20,380 --> 00:17:20,540
+وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين
+
+196
+00:17:20,540 --> 00:17:21,340
+وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين
+
+197
+00:17:21,340 --> 00:17:27,820
+وبين وبين وبين وبين وبين
+
+198
+00:17:27,820 --> 00:17:35,990
+وبين وبينفلا هي رابطة ثنائية ولا هي رابطة وحدية
+
+199
+00:17:35,990 --> 00:17:39,650
+ربما احنا اللي بهمنا اكثر النقطة اللي انا ركزت
+
+200
+00:17:39,650 --> 00:17:43,810
+عليها النقطة اللي انا ركزت عليها ان البنزين مش
+
+201
+00:17:43,810 --> 00:17:50,730
+هيعمل تفاعلاتالالكينز بشكل أساسي يعني ربما أنه أول
+
+202
+00:17:50,730 --> 00:17:55,630
+ما نعطي شبتري البنزين و نيجي نرسم بنزينة تفكر
+
+203
+00:17:55,630 --> 00:17:59,910
+طالبة اجتهدت في موضوع الالكينز بهذا الشكل و هي
+
+204
+00:17:59,910 --> 00:18:07,930
+شايفة الروابط و نقولها H2OH plus تيجي أول ما تفكر
+
+205
+00:18:07,930 --> 00:18:15,490
+اضيف H2OH بهاي double bond هنا بيكون إيش عندهخطأ
+
+206
+00:18:15,490 --> 00:18:19,190
+كبير يعني أنا خايف أكتب و لحظة يتسجل علي في اللوحة
+
+207
+00:18:19,190 --> 00:18:23,590
+اني كتبت انه بضيف H OH إياكم تفكروا بهذا الشكل
+
+208
+00:18:23,590 --> 00:18:28,210
+البنزين لا يتعامل كالكيل صح انتوا شايفين تلاتة
+
+209
+00:18:28,210 --> 00:18:32,990
+double bonds لكن على أرض الواقع لا يتعامل إطلاقا
+
+210
+00:18:32,990 --> 00:18:36,390
+بتفاعلات الالكيل واضح هذه النقطة؟
+
+211
+00:18:44,190 --> 00:18:50,570
+خلّينا نقول كنظرة تاريخية كنظرة تاريخية البنزين
+
+212
+00:18:50,570 --> 00:18:55,670
+أول ما اكتشف مركب سائل و تم الاكتشاف سنة الف و
+
+213
+00:18:55,670 --> 00:19:00,390
+تمانمية و خمسة و عشرين من خلال العالم الإنجليزي
+
+214
+00:19:00,390 --> 00:19:07,990
+Faraday وحتى البنزين اللي هو يعني قطره و حضرهكمية
+
+215
+00:19:07,990 --> 00:19:12,410
+صغيرة منه ما زالت موجودة لليوم في متحف بريطانيا
+
+216
+00:19:12,410 --> 00:19:17,170
+نفس السائل البنزين اللي هو فصله فرديه و بيعتزوا
+
+217
+00:19:17,170 --> 00:19:21,910
+فيه يعني بيعتبروه شئ كبير هذا أول مفصل الآن لما
+
+218
+00:19:21,910 --> 00:19:26,150
+فصلوا بدوا يعملوا تحليل شو هالمركب لقوا أن الصيغة
+
+219
+00:19:26,150 --> 00:19:30,830
+الجزائية للبنزين C6H6
+
+220
+00:19:31,830 --> 00:19:35,790
+هذه الصيغة الجزائية، لكن يا ترى إيش الصيغة
+
+221
+00:19:35,790 --> 00:19:41,790
+البنائية؟ الآن صار عندكم خبرة إن صيغة جزائية واحدة
+
+222
+00:19:41,790 --> 00:19:47,710
+يمكن أن يكون لها عدد كبير من الصيغ البنائيةمظبوط
+
+223
+00:19:47,710 --> 00:19:52,610
+ولا لأ اللي هي ال structural isomers او حتى ال
+
+224
+00:19:52,610 --> 00:19:58,190
+stereo isomers فسهل انهم يعرفوا الصيغة الجزائية
+
+225
+00:19:58,190 --> 00:20:02,590
+بيومين بيعرفوا انه مركب جديد الفصل صيغته الجزائية
+
+226
+00:20:02,590 --> 00:20:08,830
+C6H6 لكن يا تورا الصيغة البنائية للبنزين 6 ذرات
+
+227
+00:20:08,830 --> 00:20:13,950
+كربون و 6 ذرات هيدروجين كيف هدول موجودين بأي شكل
+
+228
+00:20:14,810 --> 00:20:20,350
+هذه العملية معرفة الصيغة البنائية للبنزين أخدت ..
+
+229
+00:20:20,350 --> 00:20:25,450
+نرجع للتاريخ أن الأجهزة مش متقدمة و العلوم صعبة
+
+230
+00:20:25,450 --> 00:20:32,510
+أخدت أربعين سنة أربعين سنة لما قدروا يقولوا أن
+
+231
+00:20:32,510 --> 00:20:38,070
+صيغة C6H6 في النهاية هي صيغة البنزين بهذا الشكل
+
+232
+00:20:38,690 --> 00:20:43,370
+اللي اقترحها العالم Kekuli الآن أثناءها الأربعين
+
+233
+00:20:43,370 --> 00:20:49,350
+سنة اقترحت صياغ كثيرة و أخدت أسماء و أحيانا درست
+
+234
+00:20:49,350 --> 00:20:53,490
+للطلاب لأن اللي كانوا بيقترحوه علماء كبار يعني كل
+
+235
+00:20:53,490 --> 00:20:57,750
+هذه الصياغ فيها Carbons و Hydrogens و لو كملتوا ال
+
+236
+00:20:57,750 --> 00:21:02,510
+Hydrogens حسب ما احنا اتعلمنا هتلاحظوا ان هذه
+
+237
+00:21:02,510 --> 00:21:08,270
+الصياغ كلها او هذه المركبات بأشكالها المختلفة C6H6
+
+238
+00:21:08,780 --> 00:21:14,940
+يعني هذا مثلا هي carbon اتنين تلاتة اربعة خمسة ستة
+
+239
+00:21:14,940 --> 00:21:20,360
+هنا في hydrogen تنتين تلاتة اربعة خمسة ستة C6H6
+
+240
+00:21:21,030 --> 00:21:25,570
+واخد اسم و لذلك بنلاحظ ان بعض هذه المراكبات على
+
+241
+00:21:25,570 --> 00:21:29,570
+سبيل المثال هذا المراكب كان اسمه Dewar Benzin هذا
+
+242
+00:21:29,570 --> 00:21:33,210
+المراكب اسمه Huckel Benzin و هدول علماء كيميا كبار
+
+243
+00:21:33,210 --> 00:21:39,250
+هذا Ladenburg Benzin يمكن الكلام هنا بالالماني
+
+244
+00:21:39,250 --> 00:21:46,010
+Klaus Benzinعلماء كبار حطوا أشكال و درست لفترة و
+
+245
+00:21:46,010 --> 00:21:49,950
+هذا الكلام بده يخلي عندكم دائما الشعور أن العلم
+
+246
+00:21:49,950 --> 00:21:54,930
+متطور و ممكن أشياء الإنسان يكون بيدرسها و بعدين
+
+247
+00:21:54,930 --> 00:21:58,710
+يكتشف أنها خطأ أكبر شغلة كل المختارات اللي احنا
+
+248
+00:21:58,710 --> 00:22:03,950
+بنعيشها أول ما بتطلع بنهلللها بشكل كبير و بعد هيك
+
+249
+00:22:03,950 --> 00:22:08,670
+بنلاحظ أن كل العالم يسعى لمنع هذه المختارات اللي
+
+250
+00:22:08,670 --> 00:22:13,100
+احنا هللنا لها كتيرومن أمثلتها على سبيل المثال
+
+251
+00:22:13,100 --> 00:22:17,420
+الفريون الغاز تبع التلاجات اللى كانوا يحطوه فى
+
+252
+00:22:17,420 --> 00:22:21,000
+علاب الريح عشان يعمل ال spraying ال answer نقول
+
+253
+00:22:21,000 --> 00:22:27,610
+هذه ال chlorofluorocarbons تدمر طبقة ال ozoneواضح؟
+
+254
+00:22:27,610 --> 00:22:33,690
+من ضمنها مثلا المبيد الزراعي ال DDT هذا ممتاز
+
+255
+00:22:33,690 --> 00:22:38,130
+بيقتل الحشرات بيقتل ممتاز جدا لكن المشكلة بيأثر
+
+256
+00:22:38,130 --> 00:22:44,170
+على البشر ولذلك حتى بعد منعه المزارعين ما زالوا
+
+257
+00:22:44,170 --> 00:22:48,290
+بيحصلوه بالسوق السوداء و بيستعملوه لأنه بيجيبلهم
+
+258
+00:22:48,290 --> 00:22:53,540
+محصول لكن هو بنفس الوقت بيفكرش بإيشبفكرش في البشر
+
+259
+00:22:53,540 --> 00:22:57,900
+اللي بده يؤذيهم فهذه المنطقة في العلم انضال من
+
+260
+00:22:57,900 --> 00:23:04,380
+تبهين لها انه ممكن نكتشف أشياء نعتقد انها جيدة
+
+261
+00:23:04,380 --> 00:23:10,620
+وبعد هيك نتفاجأ انها عملت مشاكل بالفصل الخامس ان
+
+262
+00:23:10,620 --> 00:23:17,330
+شاء الله هنحكيلكم عن دوةنزل على السوق و بعد هيك
+
+263
+00:23:17,330 --> 00:23:22,410
+عمل مأساة كبيرة يمكن البعض منكوا لما نتكلم عنها و
+
+264
+00:23:22,410 --> 00:23:25,870
+نحط المأساة بالصور ايش عمل في البشر ممكن البعض
+
+265
+00:23:25,870 --> 00:23:35,030
+يبكي مع العلم انه دوى و سوق و أخدون ناس ابحينه انا
+
+266
+00:23:35,030 --> 00:23:39,540
+مش كل اشي بيعملون دراسة قبل ما ينهاركل إشي .. كل
+
+267
+00:23:39,540 --> 00:23:44,720
+إشي بيعملوله دراسة لكن في النهاية بتيجي دراسة أدق
+
+268
+00:23:44,720 --> 00:23:49,460
+من دراسة، شيء إحنا مش منتبهينله، يعني مابندناش
+
+269
+00:23:49,460 --> 00:23:56,540
+ناخد كل شيء إن هو قطعي تماما، بيحاولوا، بيجتهدوا،
+
+270
+00:23:56,540 --> 00:24:03,730
+طبعا أصعب شيء إذا دخلتالتجارة والصناعة في البحث
+
+271
+00:24:03,730 --> 00:24:08,230
+العلمي أثرت على حيادية النتيجة العلمية يعني أن
+
+272
+00:24:08,230 --> 00:24:13,510
+الشركة تخفي معلومات بخصوص منتوجها عشان تبيعه كل
+
+273
+00:24:13,510 --> 00:24:18,670
+شيء وارد .. كل شيء وارد والأمثلة لا تعد ولا تحصر
+
+274
+00:24:18,670 --> 00:24:24,650
+يعني خدوا على سبيل المثال صبغات الشعراللي استعملت
+
+275
+00:24:24,650 --> 00:24:28,170
+كثير و بشكل أساسي صفغات مُركّبات بسمها الـ
+
+276
+00:24:28,170 --> 00:24:32,030
+Pyrosols الان كلها انتهت من السوق في آخر عشر أو
+
+277
+00:24:32,030 --> 00:24:36,230
+خمس عشر سنة استعملته على المدى البعيد بدأ يبين
+
+278
+00:24:36,230 --> 00:24:40,950
+آثار سلبية لها الان بيخترعوا شغلات جديدة أول ما
+
+279
+00:24:40,950 --> 00:24:43,690
+بيخترعوا شغلة جديدة بيجوا و بيقولوا عملنا لها
+
+280
+00:24:43,690 --> 00:24:50,260
+فحوصات و ثبت إنها آمنة و أفضل ربمابعد 15-20 سنة
+
+281
+00:24:50,260 --> 00:24:54,960
+يكتشفوا أضرار معينة إلها ويعود اللي سمع محاضرة عن
+
+282
+00:24:54,960 --> 00:24:59,680
+فضل هذه الأشياء مثلا صبغات التترازينس يسمع محاضرة
+
+283
+00:24:59,680 --> 00:25:04,740
+جديدة بعد 15-20 سنة عن أضرار هذه المادةفالإنسان في
+
+284
+00:25:04,740 --> 00:25:10,160
+هذه المنطقة بصراحة تبقى منطقة علم وليس منطقة تأكد
+
+285
+00:25:10,160 --> 00:25:16,700
+في التشخيص شخصه غلط وهذا أمر طبيعي وفي النهاية
+
+286
+00:25:16,700 --> 00:25:22,440
+بنقدر نقول بالتأكيد ومن خلال أشعة X من ال 1865
+
+287
+00:25:22,440 --> 00:25:27,200
+لليوم ماحدش بيجادل إطلاقا بخصوص شكل البنزين بهذا
+
+288
+00:25:27,200 --> 00:25:32,270
+الشكليعني احنا بنقدر نقول بنسبة كبيرة بس احتراما
+
+289
+00:25:32,270 --> 00:25:37,490
+لمبدأ ان العلم متغير ممكن يقول بنسبة 100% بس ممكن
+
+290
+00:25:37,490 --> 00:25:44,050
+يقول بنسبة 99.9% ان البنزين بهذا الشكل واضح؟ ومن
+
+291
+00:25:44,050 --> 00:25:49,350
+ال 1865 لليوم لأ ما اجهز شكل جديد درس البنزين بهذا
+
+292
+00:25:49,350 --> 00:25:56,750
+الشكلهذا كيكولي الان حكينا عن ال resonance وهذا
+
+293
+00:25:56,750 --> 00:26:02,590
+بيعمل orbitals بحيث انه بتعمل فوق البنزين و تحت
+
+294
+00:26:02,590 --> 00:26:05,010
+البنزين سحابة إلكترونية
+
+295
+00:26:07,750 --> 00:26:11,830
+فكرة وجود سحابة إلكترونية يعني لما أنا أتخيل أن
+
+296
+00:26:11,830 --> 00:26:17,670
+هذا هو البنزين أن هذا هو البنزين و فوقه إلكترونات
+
+297
+00:26:17,670 --> 00:26:21,230
+و تحته إلكترونات جايين من ال بي أوربيتالز يعني
+
+298
+00:26:21,230 --> 00:26:25,450
+كتلة إلكترونات بناء على ذلك هذا الكلام هيفيدني في
+
+299
+00:26:25,450 --> 00:26:30,630
+التفاعلات شو اللي بيقدر يجرب من البنزين عشان
+
+300
+00:26:30,630 --> 00:26:36,830
+يتفاعل معه إيش لازم يكون موجب موجبElectrophile
+
+301
+00:26:36,830 --> 00:26:43,390
+يعني مش ممكن يقدر بالوضع الطبيعي الـ Eucleophile
+
+302
+00:26:43,390 --> 00:26:49,310
+يجرب على البنزين لأن طبيعة الدنيا أن السالب يتنافر
+
+303
+00:26:49,310 --> 00:26:53,610
+مع السالب انا هنا عندي إلكترونات .. أنا هنا عندي
+
+304
+00:26:53,610 --> 00:27:01,590
+إلكترونات أجيب عليها شيء سالبسالب على سالب بيصير و
+
+305
+00:27:01,590 --> 00:27:05,550
+لذلك من أكبر الأخطاء من أكبر الأخطاء اللي
+
+306
+00:27:05,550 --> 00:27:09,270
+بيرتكبوها الطلاب ان احنا مرات لما نيجي نقولهم و
+
+307
+00:27:09,270 --> 00:27:14,550
+الله كيف بتحضروا الفينول الان الطالب اللي مادرسش
+
+308
+00:27:14,550 --> 00:27:18,390
+روح الكيميا و مبادئ الكيميا بيقول يالا بتمشي هاد
+
+309
+00:27:18,390 --> 00:27:23,830
+معايا بيروح برسوملنا بنزين و بيقول في وجود ال OH
+
+310
+00:27:23,830 --> 00:27:33,430
+minus بتبدل H من هنابال OH صرفيلون هذه مشكلة ليش؟
+
+311
+00:27:33,430 --> 00:27:39,570
+لأن هنا إلكترونات وهذه سالبة ممكن هذا الكلام عمره
+
+312
+00:27:39,570 --> 00:27:47,310
+يصير؟ مش ممكنولذلك التفاعل الأساسي لل aromatic
+
+313
+00:27:47,310 --> 00:27:52,230
+compounds هو ال electrophilic substitution زي ما
+
+314
+00:27:52,230 --> 00:27:56,430
+هيمر علينا انه اللي بده يهاجم بده يكون موجب لأنه
+
+315
+00:27:56,430 --> 00:28:01,450
+البنزين عبارة عن سحابة إلكترونية فوق وتحت الجزيرة
+
+316
+00:28:01,450 --> 00:28:03,350
+كذا بده يجي يهاجم سالب ع سالب
+
+317
+00:28:11,350 --> 00:28:15,070
+الان قبل ما ناخد التفاعلات ناخد تسمية الـ aromatic
+
+318
+00:28:15,070 --> 00:28:21,050
+compounds بالنسبة للتسمية في عندنا مركبات أخدت
+
+319
+00:28:21,050 --> 00:28:24,710
+شهرة عبر الزمن هذه بتصير جزء من التسمية و لازم
+
+320
+00:28:24,710 --> 00:28:29,570
+نحفظها و في تسمية اشتقاقية الان في البداية
+
+321
+00:28:29,570 --> 00:28:34,530
+المركبات اللي أخدت شهرة و لازم نحفظها زي ما هي على
+
+322
+00:28:34,530 --> 00:28:40,810
+رأسهاالبنزين يعني احنا سابقا قلنا ان البنزين كان
+
+323
+00:28:40,810 --> 00:28:46,620
+ممكن نسميه Cyclohexatrieneلأن الـ Cyclohexane فيه
+
+324
+00:28:46,620 --> 00:28:51,380
+تلاتة إيل لكن هذا الكلام غير جائز ما بنسميه
+
+325
+00:28:51,380 --> 00:28:56,760
+Cyclohexatriene شو بنسميه؟ بنزين إذا أخد مجموعة
+
+326
+00:28:56,760 --> 00:29:04,120
+CH3 بصير طلوين إذا أخد مجموعة isopropyl اللي هو ال
+
+327
+00:29:04,120 --> 00:29:08,720
+isopropyl بنزين بصير كيومين حكينا عنه سابقا اللي
+
+328
+00:29:08,720 --> 00:29:16,090
+قلنا عنه في الكمونإذا أخد مجموعة الـ vinyl CH
+
+329
+00:29:16,090 --> 00:29:20,790
+double bond CH2 متذاكرينها ال vinyl؟ اه بنقول عنه
+
+330
+00:29:20,790 --> 00:29:27,210
+ال styrene لاحظوا معاه ان هذه المجموعات لها أسماء
+
+331
+00:29:27,210 --> 00:29:32,570
+درسناها لكن ما بنسميه هنا تسمية اشتقاطية يعني
+
+332
+00:29:32,570 --> 00:29:37,800
+مابنفعش ديجي نقول هذا مثل بنزين لأطولوين هذا
+
+333
+00:29:37,800 --> 00:29:44,420
+ايزوبروب البنزين لأ اكيومين هذا فينيل بنزين لأ
+
+334
+00:29:44,420 --> 00:29:50,260
+استيرين هذا هيدروكسي بنزين لأ فينول هذا مثلا
+
+335
+00:29:50,260 --> 00:29:56,360
+مثوكسي بنزين او مثل مثوكسي مجموعة ال او مثل لوحدها
+
+336
+00:29:56,360 --> 00:30:02,640
+لها اسم شو بنسميها مثوكسي لكن ما بنسميه مثوكسي
+
+337
+00:30:02,640 --> 00:30:08,550
+بنزين شو بنسميه أنيزوللو كان في مجموعة ال الديهيد
+
+338
+00:30:08,550 --> 00:30:13,610
+بنسميه بنزالديهيد لو كان في مجموعة ال C double
+
+339
+00:30:13,610 --> 00:30:20,170
+bond OCH3 بنسميه أسيتوفينون لو كان في مجموعة
+
+340
+00:30:20,170 --> 00:30:26,610
+الحامض C double bond OOH بنسميه بنزويك أسيد لو في
+
+341
+00:30:26,610 --> 00:30:32,170
+ال NH2 أنيلين بنقولوش أمينو بنزين، شو بنقوله؟
+
+342
+00:30:32,170 --> 00:30:38,070
+أنيلينالان هذه الأسماء مع الخبرة بالتأكيد لازم
+
+343
+00:30:38,070 --> 00:30:41,650
+تحفظوها يعني لو جيبنا لك ارسم تفاعل ال benz
+
+344
+00:30:41,650 --> 00:30:44,490
+aldehyde او اكتب تفاعل ال benz aldehyde مع كذا
+
+345
+00:30:44,490 --> 00:30:47,510
+ماحدش يجي يقول مش حافظ ال benz aldehyde لأ كل شيء
+
+346
+00:30:47,510 --> 00:30:52,050
+موجود هنا صار جزء من التسمي اللي لازم طالب بتعلم
+
+347
+00:30:52,050 --> 00:30:57,670
+في الجامعة يعرفهامعد ذلك .. معد ذلك بنصير نسمي
+
+348
+00:30:57,670 --> 00:31:01,730
+تسمية اشتقاقية في التسمية الاشتقاقية بنجيب
+
+349
+00:31:01,730 --> 00:31:06,890
+المجموعة اللي موجودة بننهيها غالبا بال O و بنكتب
+
+350
+00:31:06,890 --> 00:31:12,770
+بنزين يعني هنا بروم بصير بروم و بنزين هنا نيترو ..
+
+351
+00:31:12,770 --> 00:31:19,680
+نيترو بنزين هنا اثلإيه في البنزين بروبل بروبل
+
+352
+00:31:19,680 --> 00:31:23,960
+بنزين هذه تسمية اشتقاقية في التسمية الاشتقاقية ايش
+
+353
+00:31:23,960 --> 00:31:30,070
+اللي بيكون موجود عندك أصل البنزينطبعا هنا بدكوا
+
+354
+00:31:30,070 --> 00:31:34,730
+تنتبهوا لنقطة كتير مهمة ان تكون المجموعة اللى
+
+355
+00:31:34,730 --> 00:31:39,130
+موجودة عند إلها اسم و إلا بتغلب يعني لما طلعت هنا
+
+356
+00:31:39,130 --> 00:31:43,890
+كلنا عارفين إنه هذا إثل ولا لأ فكان سهل علي أقول
+
+357
+00:31:43,890 --> 00:31:48,090
+إثل بنزيل كلنا عارفين إنه هذا بروبل ولا لأ سهل إن
+
+358
+00:31:48,090 --> 00:31:52,550
+أقول بروبل بنزيل أحيانا بتواجهكوا مشكلة كيف بدكم
+
+359
+00:31:52,550 --> 00:31:58,390
+تحلوها يعني مثلا لو أنا رسمت هذا المركب و حطيت هنا
+
+360
+00:32:00,820 --> 00:32:08,100
+حلقة بنزين وحطيت هنا CL الأن انتبهوا معي لو واحدة
+
+361
+00:32:08,100 --> 00:32:13,740
+بدت تقول هذه المجموعة بنزين المشكلة هي لم تدرس اسم
+
+362
+00:32:13,740 --> 00:32:19,380
+لهذه المجموعة وفعلا مالهاش اسم وجيتها بحول بعرفنه
+
+363
+00:32:19,380 --> 00:32:24,720
+كالكانبعمله كالكين بقول طب خليني لما عامله كالكين
+
+364
+00:32:24,720 --> 00:32:30,640
+هاي سلسلة كربون واحد اتنين تلاتة اربعة خمسة هاي
+
+365
+00:32:30,640 --> 00:32:35,880
+اطول سلسلة كربون حسب ما احنا اتعلمنا اذا هذا
+
+366
+00:32:35,880 --> 00:32:45,140
+بينتين وعلى اقل ترقيم واحد اتنين تلاتة اربعة خمسة
+
+367
+00:32:45,140 --> 00:32:50,970
+صار three cloroوهذه المجموعة البنزين نفسها فنل
+
+368
+00:32:50,970 --> 00:32:59,270
+اتنين فنل بنتين بيمشي الحال حلنا المشكلة تبعتنا
+
+369
+00:33:00,360 --> 00:33:05,220
+يعني مش ملزمين كل ما نشوف حلقة بنزين إننا لازم
+
+370
+00:33:05,220 --> 00:33:10,460
+ننهي الإسم تبعنا بنزين لأ إذا المجموعة إلها إسم
+
+371
+00:33:10,460 --> 00:33:15,300
+بسيط okay بنسمي بنزين إذا مالهاش هي نفس حلقة
+
+372
+00:33:15,300 --> 00:33:22,100
+البنزين كمجموعة اسمها إيش؟ فنل و بنعمل المركب على
+
+373
+00:33:22,100 --> 00:33:26,300
+إنه الكن و بيك منكون حلنا مشكلتنا
+
+374
+00:33:28,600 --> 00:33:35,240
+فنل بالظبط المجموعة اللى هو C6H6 لما بفقد H بصير
+
+375
+00:33:35,240 --> 00:33:42,480
+C6H5 اسمه فنل واضح؟ وعشان ايه سابقا بتذكر وقلتلكوا
+
+376
+00:33:42,480 --> 00:33:48,400
+ميزوا كلمة فنل عن فنل لإن الفنل شيء الفنل هي هذه
+
+377
+00:33:48,400 --> 00:33:53,090
+المجموعةلكن هذا ماسميناهوش فينيل لإنه ماخد اسم
+
+378
+00:33:53,090 --> 00:33:56,350
+شهرة الستايرين و أخدناله كمان البوليمار اللي
+
+379
+00:33:56,350 --> 00:34:00,110
+بيعمله شو سمينا البوليمار تبعه بوليستايرين
+
+380
+00:34:00,110 --> 00:34:03,270
+البوليمار سميناه بوليستايرين
+
+381
+00:34:10,410 --> 00:34:16,170
+الان لحتى الان اللي احنا سمنا مركبات بنزين فيها
+
+382
+00:34:16,170 --> 00:34:20,470
+one substituent يعني بس ابدلت فيها هيدروجينة واحدة
+
+383
+00:34:20,470 --> 00:34:28,310
+الان طيب يا ترى لو صار عندى ابدال اكثر من مجموعةلو
+
+384
+00:34:28,310 --> 00:34:33,210
+صار عندى إبدال أكثر من مجموعة هنا الحقيقة بيصير
+
+385
+00:34:33,210 --> 00:34:37,730
+عندنا نقطتين بدنا ننتبه لهم لما بيصير عندى إبدال
+
+386
+00:34:37,730 --> 00:34:44,230
+أكثر من مجموعة خليني أرسم مركب بشكل يعني هيك شوية
+
+387
+00:34:44,230 --> 00:34:53,530
+عشوائي لو كتبت هنا CH3 مثلا و هنا Pro هاي صار عليه
+
+388
+00:34:53,530 --> 00:34:59,680
+مجموع تانيهل يا تورا .. هل يا تورا بدي اعتبر ان
+
+389
+00:34:59,680 --> 00:35:04,880
+المركب الاصلي اللي عندى هو هذا اللى كان اسمه طلوين
+
+390
+00:35:04,880 --> 00:35:09,220
+و اقول ع موقع واحد اتنين تلاتة بيحمل بروم اسميه
+
+391
+00:35:09,220 --> 00:35:14,540
+three bromotolwinأو اعتبر المركب الأساسي اللي عندي
+
+392
+00:35:14,540 --> 00:35:20,520
+هو هذا برومو بنزين وع موقع واحد اتنين تلاتة اقول
+
+393
+00:35:20,520 --> 00:35:26,900
+three مثل برومو بنزين بيصير لإيش بدي أنسب المركب
+
+394
+00:35:26,900 --> 00:35:31,680
+تبعي بمعنى انا بدي اعمل عائلة للمركبهل يا ترى
+
+395
+00:35:31,680 --> 00:35:35,300
+العائلة بدت تكون تابعة المثل وبالتالي اخر الاسم
+
+396
+00:35:35,300 --> 00:35:39,420
+اللى بده يبين عندى هيكون تلوين ولا بدت تتبع البروم
+
+397
+00:35:39,420 --> 00:35:43,200
+وبالتالي اخر الاسم اللى بده يبين عندى بده يكون
+
+398
+00:35:43,200 --> 00:35:50,900
+برومو بنزين او مثلا مثال زى هذا لو حطيت هنا c
+
+399
+00:35:50,900 --> 00:35:58,210
+double bond o hالان اذا واحدة اتطلعت بهذا الشكل
+
+400
+00:35:58,210 --> 00:36:02,470
+هتقول طلوين يحمل على نمرة أربعة هذه المجموعة طب
+
+401
+00:36:02,470 --> 00:36:07,710
+اذا واحدة اتطلعت بهذا الشكل هتقول بنزالديهيد يحمل
+
+402
+00:36:07,710 --> 00:36:11,970
+على نمرة أربعة هذه المجموعة الان نهاية المركب تبع
+
+403
+00:36:11,970 --> 00:36:19,910
+عائلته هل هي يا ترى طلوين ولا بنزالديهيدهذا احنا
+
+404
+00:36:19,910 --> 00:36:24,670
+بحاجة انه تصبروا علينا شوية بهدوء حتى نتعلموا الان
+
+405
+00:36:24,670 --> 00:36:29,010
+اذا اتعلمنا ايش العائلة الأساسية اللي موجودة عندنا
+
+406
+00:36:29,010 --> 00:36:33,390
+بعد هيك الأمور بتصير سهلة يعني افترضوا جدلا انه
+
+407
+00:36:33,390 --> 00:36:38,810
+قولنا العائلة الأساسية تتبع هذه المجموعة اذا
+
+408
+00:36:38,810 --> 00:36:43,510
+المركب ايش Benzaldehyde ده المركب الأصلي باجي بقول
+
+409
+00:36:43,510 --> 00:36:47,430
+اذا والله وجدت مجموعة على هذا الموقع ببدأ ترقيمي
+
+410
+00:36:47,430 --> 00:36:55,460
+من هنا1 2 3 4 إذا وجدت مجموعة هذا الموقع بقول two
+
+411
+00:36:55,460 --> 00:37:02,340
+whatever بنزل دي هايت إذا كانتها three بنزل دي
+
+412
+00:37:02,340 --> 00:37:07,500
+هايت إذا كانتها four بنزل دي هايت الآن بدل ال two
+
+413
+00:37:07,500 --> 00:37:14,840
+ممكن أكتب ortho يعني يا بكتب two يا بكتب ايش ortho
+
+414
+00:37:14,840 --> 00:37:21,580
+small o بدل التلاتةميتا بدل الأربعة بارا فالان
+
+415
+00:37:21,580 --> 00:37:25,660
+بهذا المنطق انتبهوا معي هذه من الأخطاء الشائعة جدا
+
+416
+00:37:25,660 --> 00:37:30,220
+عن طلاب الكيميا ان هم بتخيلوا قصة اورتو ميتا و
+
+417
+00:37:30,220 --> 00:37:35,560
+بارا ان انا عندى شكل زى ما احنا كاتبينه هنا ان هذا
+
+418
+00:37:35,560 --> 00:37:41,360
+المكان اورتو هذا المكان ميتا هذا المكان بارابارا
+
+419
+00:37:41,360 --> 00:37:48,560
+لأ ما تفكروش بهذا الشكل فكروا بمجموعة موجودة أصلا
+
+420
+00:37:48,560 --> 00:37:54,140
+اللي بيكون بالنسبة لها على موقع اتنين ايش بدو يكون
+
+421
+00:37:54,140 --> 00:37:59,840
+اورتو اللي على موقع تلاتة ميتا اللي على موقع أربعة
+
+422
+00:37:59,840 --> 00:38:06,720
+بارا يعني لو أنا رسمت مركب بهذا الشكل وحطيت هنا OH
+
+423
+00:38:06,720 --> 00:38:10,690
+وخليني أقول اعتبرها هي الأساساللي بدأ اسمه يعني
+
+424
+00:38:10,690 --> 00:38:19,210
+مركب ايش؟ فينول الان اتيت و حطيت هنا كلور وجدت ايش
+
+425
+00:38:19,210 --> 00:38:23,850
+بدأ اسم هذا المركب طبعا طالما الاساس هذا اذا هي
+
+426
+00:38:23,850 --> 00:38:31,410
+الواحد اما بدأ اقول two chlorofenol
+
+427
+00:38:31,410 --> 00:38:37,370
+او ممكن ال two استبدلها ب orthoأنا مش كتير بحب ال
+
+428
+00:38:37,370 --> 00:38:40,650
+Orth والميتا والبارا، يعني أنا بنصحكم أكتبوا
+
+429
+00:38:40,650 --> 00:38:46,270
+أرقام، أكتبوا أرقام منطلقين أنه نقطة البداية هي
+
+430
+00:38:46,270 --> 00:38:51,960
+العائلة اللي حتى الآن مااتفقناش كيف نعرفهالحد الآن
+
+431
+00:38:51,960 --> 00:38:56,000
+ماحكيناش كيف نعرف العائلة، لكن احنا بنكتب أرقام،
+
+432
+00:38:56,000 --> 00:38:59,700
+الآن بعد ما نسمي، إذا واحدة بتحب هذه الرموز، تروح
+
+433
+00:38:59,700 --> 00:39:03,000
+تشتب الإتنين، تحط مكانها Orth أو تشتب التلاتة،
+
+434
+00:39:03,000 --> 00:39:06,160
+مكانها ميتا أو تشتب الأربعة، مكانها بارا، يحرق،
+
+435
+00:39:06,160 --> 00:39:11,360
+ماعملتش، و من هنا لحد ما خلصت الكورس معنا، ولا مرة
+
+436
+00:39:11,360 --> 00:39:14,660
+كتبت بإيدها Orth و ميتا و بارا، كتبت اتنين و تلاتة
+
+437
+00:39:14,660 --> 00:39:21,460
+و أربعة، هي بتشتغل شغلصحيح و بالمناسبة قصة الارثو
+
+438
+00:39:21,460 --> 00:39:26,400
+والنيتا والبارا هي قصة بس بتنوجد لو عندي two
+
+439
+00:39:26,400 --> 00:39:30,420
+substituents بمعنى لو كان عندي هذا المركب و خليني
+
+440
+00:39:30,420 --> 00:39:34,760
+اقول ما زلت مصير ان العائلة تبعت ال OH و اجيت و
+
+441
+00:39:34,760 --> 00:39:44,680
+حطيت هنا CH3 و هنا PR و بدي اسميه الان قولة واحدة
+
+442
+00:39:44,680 --> 00:39:50,540
+ان انا بستعمل الأرقاممافي امكانية ان اقعد تلاتة
+
+443
+00:39:50,540 --> 00:39:56,300
+اربعة خمسة ستة واتفقت انه مركب ايش؟ Phenol الان
+
+444
+00:39:56,300 --> 00:40:01,560
+هنا فقط باستعمل نظام الأرقام بدي اقول five bromo
+
+445
+00:40:01,560 --> 00:40:06,600
+two cloro three مثل ال alphabetical ذكرتهم
+
+446
+00:40:06,600 --> 00:40:19,750
+ماتبهين؟ five bromo two cloro threeمثل فينول اذا
+
+447
+00:40:19,750 --> 00:40:24,810
+لو زادوا ال substituents اللى عندى عن تنتين اكيد
+
+448
+00:40:24,810 --> 00:40:29,350
+بستعمل الأرقام لو كانوا تنتين ربما نقول الأفضل
+
+449
+00:40:29,350 --> 00:40:33,550
+نستعمل الأرقام و نسيبنا من قصة ارثه ميته برة الان
+
+450
+00:40:33,550 --> 00:40:36,570
+اذا اي واحدة بدأ تيجي بدل رقم اتنين لما بيكون two
+
+451
+00:40:36,570 --> 00:40:40,730
+substituents تحط ارثه بدل تلاتة ميته و بدل اربعة
+
+452
+00:40:40,730 --> 00:40:46,920
+برة مافيش عندنا مشكلةمثلا هذا المركب
+
+453
+00:40:46,920 --> 00:40:52,060
+Orthodiachlorobenzene هذا ميتا دايمثلبنزين لكن
+
+454
+00:40:52,060 --> 00:40:58,080
+دايمثلبنزين بياخد اسم شهرة إكزايلينولذلك مرة سئلنا
+
+455
+00:40:58,080 --> 00:41:01,580
+الطلاب في الامتحان ارسمولنا بار اكزايلين احنا
+
+456
+00:41:01,580 --> 00:41:05,260
+بنقول اكزايلين اللي فيه مجمعتين مثل اذا كانوا جانب
+
+457
+00:41:05,260 --> 00:41:10,400
+بعض واحد اتنين اورث اكزايلين اذا واحد تلاتة مائة
+
+458
+00:41:10,400 --> 00:41:14,800
+اكزايلين طب لو يجي واحد اربعة بار اكزايلين واضح
+
+459
+00:41:14,800 --> 00:41:20,540
+الفكرة هذا المركب مثلاواضح انه في كلورو الديهايد
+
+460
+00:41:20,540 --> 00:41:25,700
+وانه اعتبر العائلة ال الديهايد ورقم من عندها فجال
+
+461
+00:41:25,700 --> 00:41:30,360
+المركب بنزل ديهايد وحطله بارا كلورو بنزل ديهايد او
+
+462
+00:41:30,360 --> 00:41:34,440
+four كلورو بنزل ديهايد لكن السؤال اللي حتى الآن ما
+
+463
+00:41:34,440 --> 00:41:42,400
+جوابناهوش ليش قلنا العائلة ال الديهايد مش لكلور او
+
+464
+00:41:42,400 --> 00:41:51,490
+ال OHالـ OH مش الكلور ولا الميثل ولا البروم هذا
+
+465
+00:41:51,490 --> 00:41:57,850
+السؤال مهم ان نشوفه الان ببساطة امرتبين ال
+
+466
+00:41:57,850 --> 00:42:01,530
+constituents بترتيب اللي موجود في اعلى بنعتبره
+
+467
+00:42:01,530 --> 00:42:09,890
+العائلة اول شئ ال halogens هدول اقل مجموعة اقل من
+
+468
+00:42:09,890 --> 00:42:15,330
+ال alkanesالان ابدأوا تلاحظوا لو وجدت .. و زي الـ
+
+469
+00:42:15,330 --> 00:42:19,750
+halogens الـ Nitro، الآن الـ O2 لو وجدت ال halogen
+
+470
+00:42:19,750 --> 00:42:25,450
+مع ال cane، يعني كلور مع مثل، من العائلة؟ المثل لو
+
+471
+00:42:25,450 --> 00:42:31,630
+وجدت Nitro مع مثل، من العائلة؟ المثل، واضح؟ أقل من
+
+472
+00:42:31,630 --> 00:42:40,100
+ال alkenes لو وجدت ال cane و ال caneمن العائلة ال
+
+473
+00:42:40,100 --> 00:42:45,100
+الكين الان لاحظوا هي العائلة ال الكين هذا إيه اسمه
+
+474
+00:42:45,100 --> 00:42:51,980
+استيرين حيصير واحد اتنين تلاتة ال three مثل
+
+475
+00:42:51,980 --> 00:42:57,640
+استيرين هذا إيه اسمه طلوين حيصير ال three نيترو
+
+476
+00:42:57,640 --> 00:43:05,060
+طلوين طبعا ال الكين أقل من ال amines أقل من ال OH
+
+477
+00:43:06,510 --> 00:43:10,790
+ولذلك لو وجدت مثلًا OH مع الـCl مين العائلة؟ OH
+
+478
+00:43:10,790 --> 00:43:15,910
+إذا مُركّبة فينول؟ فينول لاحظوا إحنا قلنا ال
+
+479
+00:43:15,910 --> 00:43:23,170
+الكينز أقل من إيش؟ النيترو اتطلعوا معاه هاي الكين
+
+480
+00:43:23,170 --> 00:43:28,810
+طلوين و تلاتة نيترو بعتبر إن الترقيم إنها واحد،
+
+481
+00:43:28,810 --> 00:43:32,870
+اتنين، تلاتة، أربعة، خمسة، ستة إذا صار عند اتنين،
+
+482
+00:43:32,870 --> 00:43:36,890
+أربعة، ستة، تري، نيترو، طلوينهذا مُركّب الـ TNT
+
+483
+00:43:36,890 --> 00:43:46,230
+المتفجر لو وجد كيتون أكتر من الـ OH والألديهيد
+
+484
+00:43:46,230 --> 00:43:51,650
+أعلى من الكيتون والأسد أعلى منهم كلهم وال إيستر
+
+485
+00:43:51,650 --> 00:43:56,710
+أعلى وأعلى ولذلك هنا لدي ألديهيد و OH من العائلة
+
+486
+00:43:58,000 --> 00:44:03,540
+الالديهايد اذا بنزالديهايد عند الديهايد وكيتون من
+
+487
+00:44:03,540 --> 00:44:10,980
+العائلة الديهايد عند الاسد وكيتون الاسد عند
+
+488
+00:44:10,980 --> 00:44:18,240
+الالكول ونيترو و أتش ونيترو و أتش
+
+489
+00:44:18,240 --> 00:44:23,930
+واضح؟لو كان عندى halogens بينهم وبين بعض مش مشكلة
+
+490
+00:44:23,930 --> 00:44:28,250
+بنكتبهم alphabetical يعني ال brom قبل ال chlorine
+
+491
+00:44:28,250 --> 00:44:32,250
+ال alkyn
+
+492
+00:44:32,250 --> 00:44:40,430
+زى ال alkene بيكون أعلى من ال alkene ال eastern
+
+493
+00:44:40,430 --> 00:44:49,760
+من المشتقات الحامض هندرسه السيدة بالمندق OORعائلة
+
+494
+00:44:49,760 --> 00:44:52,840
+بناخدها بعدين، الآن احنا بنحط الصورة الكلية،
+
+495
+00:44:52,840 --> 00:44:56,040
+بتهيألي ضمن هذه الصورة الكلية بيصير موضوع التسمية
+
+496
+00:44:56,040 --> 00:45:01,870
+أصبح واضح لكمالـ slide اللي بننهي عندها انه هذه
+
+497
+00:45:01,870 --> 00:45:05,650
+بتتدربوا طبعا انتوا على التسمية و لو روحتوا على
+
+498
+00:45:05,650 --> 00:45:09,910
+الأمثلة اللي معاكم في امتحانات سابقة هتلاحظوا
+
+499
+00:45:09,910 --> 00:45:12,730
+دائما جايبيني اللي كنت اسمها aromatic compounds
+
+500
+00:45:12,730 --> 00:45:17,210
+بتفتشوا مين أعلى في المجموعات و تنسبوا إليها زي
+
+501
+00:45:17,210 --> 00:45:20,810
+الأمثلة الكتيرة اللي عرضناها الآن آخر نقطة بنحكيها
+
+502
+00:45:20,810 --> 00:45:25,330
+انه هذه ال aromatic compounds في نهاية مش رموزهي
+
+503
+00:45:25,330 --> 00:45:29,930
+مركبات على أرض الواقع يستفيد الإنسان منها والدليل
+
+504
+00:45:29,930 --> 00:45:34,130
+على هيك هاي بعض ال aromatic compounds اللي في صميم
+
+505
+00:45:34,130 --> 00:45:38,310
+الحياة تبع الإنسان يعني هذا المركب aromatic ولا
+
+506
+00:45:38,310 --> 00:45:43,070
+لأ؟ هذا اسمه Aspirin ال Aspirin اللي أنتوا بتاخدوه
+
+507
+00:45:43,070 --> 00:45:47,010
+تمام؟ تلت ارباع الناس بعد حصة ال organic يا
+
+508
+00:45:47,010 --> 00:45:53,190
+Aspirin يا Trophin تعرفولي Trophin أربع .. هايو ال
+
+509
+00:45:53,190 --> 00:45:59,260
+Ibuprofenواذا روحوا ع البيت و بدهم ياكلوا بدهم كيك
+
+510
+00:45:59,260 --> 00:46:03,780
+و الكيك بده فانيلا و الفانيلا من الفانيليل من
+
+511
+00:46:03,780 --> 00:46:08,640
+الفانيليل هي الفانيلا واضح فإحنا مش بنحكي عن رموز
+
+512
+00:46:08,640 --> 00:46:12,500
+بقدر ما بنحكي حقيقة عن مركبات في واقع الاستعمال
+
+513
+00:46:12,500 --> 00:46:16,860
+الحياتي و الطب و لذلك بندرس ال organ ال chemistry
+
+514
+00:46:16,860 --> 00:46:21,340
+و ان شاء الله المرة القادمة بكون موضوعنا تفاعلات
+
+515
+00:46:21,340 --> 00:46:22,940
+ال aromatic compounds
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..e4535d4bf7fcddcc29fb367687041d1926cc1089
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_raw.json
@@ -0,0 +1 @@
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"word": " alkynes", "probability": 0.8922526041666666}, {"start": 118.3, "end": 118.8, "word": " are", "probability": 0.94580078125}, {"start": 118.8, "end": 119.64, "word": " acidic", "probability": 0.98486328125}, {"start": 119.64, "end": 120.44, "word": " إيش", "probability": 0.7928059895833334}, {"start": 120.44, "end": 120.68, "word": " يعني", "probability": 0.9736328125}, {"start": 120.68, "end": 121.5, "word": " acidic؟", "probability": 0.912353515625}], "temperature": 1.0}, {"id": 5, "seek": 15028, "start": 122.12, "end": 150.28, "text": "حامضي الان لو انا اجيت اتذكر تعريف الحامض ممكن ناخد في هذه المرحلة تعريف الوري برونستيد الـ acid proton donor بيعطي بروتونات بيفقد بروتون الان اي بروتون حامضي في هذا المركب يعني لحظوا انا لما رسمت هنا مركب في عندي هنا حلقة Cyclohexane و عليها هيدروجين", "tokens": [5016, 10943, 11242, 1829, 2423, 7649, 45164, 1975, 8315, 1975, 7435, 36081, 1975, 2655, 8848, 37983, 37279, 16572, 5172, 21542, 10943, 11242, 3714, 43020, 8717, 47283, 3215, 8978, 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خلال زوج الإلكترونات الهالوجين في رابطة تلت أزواج إلكترونات أيضا ممكن يعمل الـ eucleophile من خلال أزواج الإلكترونات الكاربون", "tokens": [6027, 1863, 36081, 2288, 29245, 9957, 8978, 6055, 1211, 2655, 12602, 14407, 3555, 9566, 4032, 11622, 29245, 11933, 23275, 2655, 2288, 11536, 9307, 36632, 11242, 995, 4724, 1829, 25957, 1211, 2423, 39184, 308, 1311, 306, 49242, 9154, 16490, 1211, 6027, 30767, 29245, 33688, 23275, 2655, 2288, 11536, 9307, 2423, 3224, 6027, 29245, 9957, 8978, 12602, 16758, 9566, 3660, 6055, 1211, 2655, 5551, 11622, 2407, 26108, 11933, 23275, 2655, 2288, 11536, 9307, 36632, 11242, 995, 3714, 43020, 7251, 25957, 1211, 2423, 39184, 308, 1311, 306, 49242, 9154, 16490, 1211, 6027, 5551, 11622, 2407, 26108, 33688, 23275, 2655, 2288, 11536, 9307, 33251, 9640, 3555, 11536], "avg_logprob": -0.13671874914031762, "compression_ratio": 2.2026143790849675, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 381.32, "end": 382.38, "word": "النيتروجين", "probability": 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انتوا متذكرين البنزين ومتذكرين ال resonance structures اللي بيعملها بهذا الشكل و بهذا الشكل الان لو اتيت طلعت على رابط معين خليني اقول هذه الرابطة", "tokens": [15042, 31439, 6086, 1668, 8978, 29739, 1863, 11622, 9957, 4032, 15042, 31439, 23032, 12610, 34892, 16758, 9566, 8978, 29739, 1863, 11622, 9957, 1975, 5016, 8315, 5551, 9778, 3215, 8315, 20449, 1211, 20498, 9307, 18871, 34892, 16758, 9566, 16247, 24401, 10632, 16070, 12984, 1863, 16373, 10632, 16070, 12984, 1211, 5718, 104, 10632, 23032, 3555, 3615, 995, 28242, 4117, 14407, 16472, 2655, 14407, 44650, 8848, 37983, 9957, 29739, 1863, 11622, 9957, 4032, 2304, 2655, 8848, 37983, 9957, 2423, 30944, 9227, 13672, 1829, 4724, 1829, 25957, 1211, 11296, 39627, 15730, 25124, 28820, 4032, 39627, 15730, 25124, 28820, 2423, 7649, 45164, 1975, 31371, 2655, 23032, 1211, 34268, 15844, 12602, 16758, 9566, 20449, 9957, 16490, 1211, 9957, 1829, 1975, 39648, 29538, 34892, 16758, 9566, 3660], "avg_logprob": -0.18607954348414396, "compression_ratio": 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1636.77, "end": 1637.49, "word": " بيقول", "probability": 0.8255208333333334}, {"start": 1637.49, "end": 1637.75, "word": " يالا", "probability": 0.7353515625}, {"start": 1637.75, "end": 1638.21, "word": " بتمشي", "probability": 0.8765869140625}, {"start": 1638.21, "end": 1638.39, "word": " هاد", "probability": 0.5048828125}, {"start": 1638.39, "end": 1638.79, "word": " معايا", "probability": 0.75927734375}, {"start": 1638.79, "end": 1639.31, "word": " بيروح", "probability": 0.865966796875}, {"start": 1639.31, "end": 1640.13, "word": " برسوملنا", "probability": 0.8706868489583334}, {"start": 1640.13, "end": 1641.19, "word": " بنزين", "probability": 0.9407552083333334}, {"start": 1641.19, "end": 1641.85, "word": " و", "probability": 0.84814453125}, {"start": 1641.85, "end": 1642.33, "word": " بيقول", "probability": 0.96923828125}, {"start": 1642.33, "end": 1642.83, "word": " في", "probability": 0.953125}, {"start": 1642.83, "end": 1643.37, "word": " وجود", "probability": 0.968505859375}, {"start": 1643.37, "end": 1643.59, "word": " ال", "probability": 0.947265625}, {"start": 1643.59, "end": 1643.83, "word": " OH", "probability": 0.4755859375}, {"start": 1643.83, "end": 1644.83, "word": " minus", "probability": 0.287841796875}, {"start": 1644.83, "end": 1645.83, "word": " بتبدل", "probability": 0.9212239583333334}, {"start": 1645.83, "end": 1646.21, "word": " H", "probability": 0.71435546875}, {"start": 1646.21, "end": 1646.45, "word": " من", "probability": 0.9892578125}, {"start": 1646.45, "end": 1646.73, "word": " هنا", "probability": 0.9697265625}], "temperature": 1.0}, {"id": 70, "seek": 166235, "start": 1647.91, "end": 1662.35, "text": "بال OH صرفيلون هذه مشكلة ليش؟ لأن هنا إلكترونات وهذه سالبة ممكن هذا الكلام عمره يصير؟ مش ممكن", "tokens": [3555, 6027, 13931, 20328, 28480, 26895, 11536, 29538, 37893, 28820, 3660, 32239, 8592, 22807, 5296, 33456, 34105, 11933, 23275, 2655, 2288, 11536, 9307, 37037, 24192, 8608, 6027, 49401, 3714, 43020, 23758, 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الجزيرة كذا بده يجي يهاجم سالب ع سالب", "tokens": [12610, 8848, 23275, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 24976, 45831, 21810, 31439, 2423, 16717, 950, 388, 299, 35827, 30767, 1829, 19446, 39896, 29973, 25894, 8315, 16472, 3224, 13672, 1829, 47525, 3224, 7251, 3224, 26108, 2304, 47525, 3224, 7251, 30544, 3714, 29245, 3555, 5296, 33456, 3224, 29739, 1863, 11622, 9957, 6225, 3555, 9640, 3660, 18871, 8608, 5016, 16758, 3660, 11933, 23275, 2655, 2288, 11536, 10632, 6156, 30543, 34683, 33753, 25724, 11622, 48923, 9122, 15730, 47525, 3224, 7251, 7435, 1829, 7251, 3224, 26108, 2304, 8608, 6027, 3555, 6225, 8608, 6027, 3555], "avg_logprob": -0.1883400595316323, "compression_ratio": 1.638095238095238, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1663.59, "end": 1664.41, "word": "ولذلك", "probability": 0.9217122395833334}, {"start": 1664.41, "end": 1665.43, "word": " التفاعل", "probability": 0.88720703125}, {"start": 1665.43, "end": 1666.51, "word": " الأساسي", 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ما ناخد التفاعلات ناخد تسمية الـ aromatic compounds بالنسبة للتسمية في عندنا مركبات أخدت شهرة عبر الزمن هذه بتصير جزء من التسمية و لازم نحفظها و في تسمية اشتقاقية الان في البداية المركبات اللي أخدت شهرة و لازم نحفظها زي ما هي على رأسها", "tokens": [6027, 7649, 12174, 36150, 19446, 8717, 47283, 3215, 16712, 5172, 995, 30241, 9307, 8717, 47283, 3215, 6055, 38251, 10632, 2423, 39184, 45831, 21810, 20666, 1863, 35457, 3660, 24976, 2655, 38251, 10632, 8978, 43242, 8315, 3714, 31747, 3555, 9307, 5551, 9778, 3215, 2655, 13412, 3224, 25720, 6225, 26890, 6024, 110, 27842, 29538, 39894, 9381, 13546, 10874, 11622, 38207, 9154, 16712, 38251, 10632, 4032, 5296, 31377, 2304, 8717, 5016, 5172, 19913, 11296, 4032, 8978, 6055, 38251, 10632, 1975, 8592, 2655, 4587, 995, 4587, 10632, 2423, 7649, 8978, 29739, 28259, 10632, 9673, 31747, 3555, 9307, 13672, 1829, 5551, 9778, 3215, 2655, 13412, 3224, 25720, 4032, 5296, 31377, 2304, 8717, 5016, 5172, 19913, 11296, 30767, 1829, 19446, 39896, 15844, 12602, 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"probability": 0.985595703125}], "temperature": 1.0}, {"id": 73, "seek": 172379, "start": 1716.25, "end": 1723.79, "text": "البنزين يعني احنا سابقا قلنا ان البنزين كان ممكن نسميه Cyclohexatriene", "tokens": [6027, 3555, 1863, 11622, 9957, 37495, 22653, 1975, 5016, 8315, 8608, 16758, 4587, 995, 12174, 1211, 8315, 16472, 29739, 1863, 11622, 9957, 25961, 3714, 43020, 8717, 38251, 1829, 3224, 10295, 66, 752, 675, 87, 31674, 1450], "avg_logprob": -0.1517103088868631, "compression_ratio": 1.1855670103092784, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1716.25, "end": 1717.11, "word": "البنزين", "probability": 0.91484375}, {"start": 1717.11, "end": 1718.17, "word": " يعني", "probability": 0.6995849609375}, {"start": 1718.17, "end": 1718.45, "word": " احنا", "probability": 0.8776041666666666}, {"start": 1718.45, "end": 1719.07, "word": " سابقا", "probability": 0.9443359375}, {"start": 1719.07, "end": 1719.53, "word": " قلنا", "probability": 0.8738606770833334}, {"start": 1719.53, "end": 1719.93, "word": " ان", "probability": 0.853515625}, {"start": 1719.93, "end": 1720.55, "word": " البنزين", "probability": 0.927734375}, {"start": 1720.55, "end": 1720.81, "word": " كان", "probability": 0.93798828125}, {"start": 1720.81, "end": 1721.21, "word": " ممكن", "probability": 0.978759765625}, {"start": 1721.21, "end": 1722.17, "word": " نسميه", "probability": 0.9444580078125}, {"start": 1722.17, "end": 1723.79, "word": " Cyclohexatriene", "probability": 0.7667759486607143}], "temperature": 1.0}, {"id": 74, "seek": 175124, "start": 1724.76, "end": 1751.24, "text": "لأن الـ Cyclohexane فيه تلاتة إيل لكن هذا الكلام غير جائز ما بنسميه Cyclohexatriene شو بنسميه؟ بنزين إذا أخد مجموعة CH3 بصير طلوين إذا أخد مجموعة isopropyl اللي هو ال isopropyl بنزين بصير كيومين حكينا عنه سابقا اللي قلنا عنه في الكمون", "tokens": [1211, 33456, 2423, 39184, 10295, 66, 752, 675, 87, 1929, 8978, 3224, 6055, 1211, 9307, 3660, 11933, 26895, 44381, 23758, 2423, 28820, 10943, 32771, 13546, 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{"start": 1726.04, "end": 1726.62, "word": " فيه", "probability": 0.6199951171875}, {"start": 1726.62, "end": 1727.16, "word": " تلاتة", "probability": 0.8868408203125}, {"start": 1727.16, "end": 1727.48, "word": " إيل", "probability": 0.59326171875}, {"start": 1727.48, "end": 1728.52, "word": " لكن", "probability": 0.619140625}, {"start": 1728.52, "end": 1729.18, "word": " هذا", "probability": 0.88525390625}, {"start": 1729.18, "end": 1729.8, "word": " الكلام", "probability": 0.9461263020833334}, {"start": 1729.8, "end": 1730.16, "word": " غير", "probability": 0.994140625}, {"start": 1730.16, "end": 1730.62, "word": " جائز", "probability": 0.9850260416666666}, {"start": 1730.62, "end": 1730.78, "word": " ما", "probability": 0.55810546875}, {"start": 1730.78, "end": 1731.38, "word": " بنسميه", "probability": 0.9276123046875}, {"start": 1731.38, "end": 1732.58, "word": " Cyclohexatriene", "probability": 0.8874860491071429}, {"start": 1732.58, "end": 1732.94, "word": " شو", "probability": 0.5992431640625}, {"start": 1732.94, "end": 1734.12, "word": " بنسميه؟", "probability": 0.91953125}, {"start": 1734.12, "end": 1734.62, "word": " بنزين", "probability": 0.8873697916666666}, {"start": 1734.62, "end": 1735.26, "word": " إذا", "probability": 0.917236328125}, {"start": 1735.26, "end": 1735.76, "word": " أخد", "probability": 0.9147135416666666}, {"start": 1735.76, "end": 1736.76, "word": " مجموعة", "probability": 0.95078125}, {"start": 1736.76, "end": 1737.66, "word": " CH3", "probability": 0.969482421875}, {"start": 1737.66, "end": 1738.82, "word": " بصير", "probability": 0.8844401041666666}, {"start": 1738.82, "end": 1739.56, "word": " طلوين", "probability": 0.61370849609375}, {"start": 1739.56, "end": 1740.62, "word": " إذا", "probability": 0.915771484375}, {"start": 1740.62, "end": 1741.04, "word": " أخد", "probability": 0.9803059895833334}, {"start": 1741.04, "end": 1741.68, "word": " مجموعة", "probability": 0.9798828125}, {"start": 1741.68, "end": 1742.86, "word": " isopropyl", "probability": 0.737640380859375}, {"start": 1742.86, "end": 1743.88, "word": " اللي", "probability": 0.65625}, {"start": 1743.88, "end": 1744.02, "word": " هو", "probability": 0.9765625}, {"start": 1744.02, "end": 1744.12, "word": " ال", "probability": 0.537109375}, {"start": 1744.12, "end": 1744.86, "word": " isopropyl", "probability": 0.86474609375}, {"start": 1744.86, "end": 1745.52, "word": " بنزين", "probability": 0.9778645833333334}, {"start": 1745.52, "end": 1746.2, "word": " بصير", "probability": 0.9353841145833334}, {"start": 1746.2, "end": 1747.0, "word": " كيومين", "probability": 0.9434814453125}, {"start": 1747.0, "end": 1747.7, "word": " حكينا", "probability": 0.9808349609375}, {"start": 1747.7, "end": 1748.0, "word": " عنه", "probability": 0.98193359375}, {"start": 1748.0, "end": 1748.6, "word": " سابقا", "probability": 0.9833984375}, {"start": 1748.6, "end": 1748.72, "word": " اللي", "probability": 0.7037353515625}, {"start": 1748.72, "end": 1749.02, "word": " قلنا", "probability": 0.8938802083333334}, {"start": 1749.02, "end": 1749.44, "word": " عنه", "probability": 0.9921875}, {"start": 1749.44, "end": 1750.6, "word": " في", "probability": 0.9208984375}, {"start": 1750.6, "end": 1751.24, "word": " الكمون", "probability": 0.8909505208333334}], "temperature": 1.0}, {"id": 75, "seek": 177597, "start": 1752.13, "end": 1775.97, "text": "إذا أخد مجموعة الـ vinyl CH double bond CH2 متذاكرينها ال vinyl؟ اه بنقول عنه ال styrene لاحظوا معاه ان هذه المجموعات لها أسماء درسناها لكن ما بنسميه هنا تسمية اشتقاطية يعني مابنفعش ديجي نقول هذا مثل بنزين لأ", "tokens": [28814, 15730, 5551, 9778, 3215, 3714, 7435, 2304, 2407, 27884, 2423, 39184, 27037, 5088, 5995, 3834, 6086, 5995, 17, 44650, 15730, 37983, 9957, 11296, 2423, 25226, 22807, 1975, 3224, 44945, 39648, 18871, 3224, 2423, 7952, 32252, 20193, 5016, 19913, 14407, 20449, 40294, 16472, 29538, 9673, 7435, 2304, 45367, 9307, 5296, 11296, 5551, 38251, 16606, 11778, 2288, 3794, 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bond", "probability": 0.88525390625}, {"start": 1756.93, "end": 1757.61, "word": " CH2", "probability": 0.925048828125}, {"start": 1757.61, "end": 1758.39, "word": " متذاكرينها", "probability": 0.703857421875}, {"start": 1758.39, "end": 1758.55, "word": " ال", "probability": 0.861328125}, {"start": 1758.55, "end": 1759.75, "word": " vinyl؟", "probability": 0.385498046875}, {"start": 1759.75, "end": 1759.99, "word": " اه", "probability": 0.6287841796875}, {"start": 1759.99, "end": 1760.31, "word": " بنقول", "probability": 0.87939453125}, {"start": 1760.31, "end": 1760.79, "word": " عنه", "probability": 0.974609375}, {"start": 1760.79, "end": 1761.59, "word": " ال", "probability": 0.36083984375}, {"start": 1761.59, "end": 1762.25, "word": " styrene", "probability": 0.6668701171875}, {"start": 1762.25, "end": 1763.33, "word": " لاحظوا", "probability": 0.919921875}, {"start": 1763.33, "end": 1763.69, "word": " معاه", "probability": 0.843994140625}, {"start": 1763.69, "end": 1764.87, "word": " ان", "probability": 0.427001953125}, {"start": 1764.87, "end": 1765.47, "word": " هذه", "probability": 0.87744140625}, {"start": 1765.47, "end": 1766.43, "word": " المجموعات", "probability": 0.9580078125}, {"start": 1766.43, "end": 1766.67, "word": " لها", "probability": 0.9755859375}, {"start": 1766.67, "end": 1767.21, "word": " أسماء", "probability": 0.8914388020833334}, {"start": 1767.21, "end": 1768.21, "word": " درسناها", "probability": 0.96650390625}, {"start": 1768.21, "end": 1769.43, "word": " لكن", "probability": 0.9169921875}, {"start": 1769.43, "end": 1770.03, "word": " ما", "probability": 0.78125}, {"start": 1770.03, "end": 1770.79, "word": " بنسميه", "probability": 0.84375}, {"start": 1770.79, "end": 1770.97, "word": " هنا", "probability": 0.5771484375}, {"start": 1770.97, "end": 1771.37, "word": " تسمية", "probability": 0.8772786458333334}, {"start": 1771.37, "end": 1772.09, "word": " اشتقاطية", "probability": 0.9102376302083334}, {"start": 1772.09, "end": 1772.57, "word": " يعني", "probability": 0.923095703125}, {"start": 1772.57, "end": 1773.21, "word": " مابنفعش", "probability": 0.8695068359375}, {"start": 1773.21, "end": 1773.47, "word": " ديجي", "probability": 0.711669921875}, {"start": 1773.47, "end": 1773.69, "word": " نقول", "probability": 0.951904296875}, {"start": 1773.69, "end": 1774.03, "word": " هذا", "probability": 0.93212890625}, {"start": 1774.03, "end": 1774.73, "word": " مثل", "probability": 0.9501953125}, {"start": 1774.73, "end": 1775.45, "word": " بنزين", "probability": 0.8776041666666666}, {"start": 1775.45, "end": 1775.97, "word": " لأ", "probability": 0.78369140625}], "temperature": 1.0}, {"id": 76, "seek": 180528, "start": 1776.56, "end": 1805.28, "text": "طولوين هذا ايزوبروب البنزين لأ اكيومين هذا فينيل بنزين لأ استيرين هذا هيدروكسي بنزين لأ فينول هذا مثلا مثوكسي بنزين او مثل مثوكسي مجموعة ال او مثل لوحدها لها اسم شو بنسميها مثوكسي لكن ما بنسميه مثوكسي بنزين شو بنسميه أنيزول", "tokens": [9566, 12610, 2407, 9957, 23758, 1975, 1829, 11622, 2407, 26890, 37746, 29739, 1863, 11622, 9957, 5296, 10721, 1975, 4117, 1829, 20498, 9957, 23758, 8978, 22653, 1211, 44945, 11622, 9957, 5296, 10721, 44713, 13546, 9957, 23758, 8032, 25708, 32887, 4117, 3794, 1829, 44945, 11622, 9957, 5296, 10721, 8978, 1863, 12610, 23758, 50113, 15040, 50113, 2407, 4117, 3794, 1829, 44945, 11622, 9957, 1975, 2407, 50113, 1211, 50113, 2407, 4117, 3794, 1829, 3714, 7435, 2304, 2407, 27884, 2423, 1975, 2407, 50113, 1211, 45164, 24401, 11296, 5296, 11296, 24525, 2304, 13412, 2407, 44945, 38251, 1829, 11296, 50113, 2407, 4117, 3794, 1829, 44381, 19446, 44945, 38251, 1829, 3224, 50113, 2407, 4117, 3794, 1829, 44945, 11622, 9957, 13412, 2407, 44945, 38251, 1829, 3224, 14739, 1829, 11622, 12610], "avg_logprob": -0.1990266456955769, "compression_ratio": 2.431137724550898, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1776.56, "end": 1777.12, "word": "طولوين", "probability": 0.6763916015625}, {"start": 1777.12, "end": 1777.8, "word": " هذا", "probability": 0.58642578125}, {"start": 1777.8, "end": 1778.92, "word": " ايزوبروب", "probability": 0.7011311848958334}, {"start": 1778.92, "end": 1779.64, "word": " البنزين", "probability": 0.818603515625}, {"start": 1779.64, "end": 1780.22, "word": " لأ", "probability": 0.790771484375}, {"start": 1780.22, "end": 1781.0, "word": " اكيومين", "probability": 0.8640625}, {"start": 1781.0, "end": 1781.68, "word": " هذا", "probability": 0.90869140625}, {"start": 1781.68, "end": 1782.68, "word": " فينيل", "probability": 0.4418131510416667}, {"start": 1782.68, "end": 1783.64, "word": " بنزين", "probability": 0.98779296875}, {"start": 1783.64, "end": 1784.42, "word": " لأ", "probability": 0.93798828125}, {"start": 1784.42, "end": 1785.1, "word": " استيرين", "probability": 0.6861979166666666}, {"start": 1785.1, "end": 1785.7, "word": " هذا", "probability": 0.92822265625}, {"start": 1785.7, "end": 1786.66, "word": " هيدروكسي", "probability": 0.7975260416666666}, {"start": 1786.66, "end": 1787.26, "word": " بنزين", "probability": 0.9925130208333334}, {"start": 1787.26, "end": 1788.3, "word": " لأ", "probability": 0.98779296875}, {"start": 1788.3, "end": 1788.88, "word": " فينول", "probability": 0.9244791666666666}, {"start": 1788.88, "end": 1789.7, "word": " هذا", "probability": 0.9296875}, {"start": 1789.7, "end": 1790.26, "word": " مثلا", "probability": 0.9912109375}, {"start": 1790.26, "end": 1791.5, "word": " مثوكسي", "probability": 0.81533203125}, {"start": 1791.5, "end": 1792.38, "word": " بنزين", "probability": 0.9915364583333334}, {"start": 1792.38, "end": 1792.7, "word": " او", "probability": 0.4588623046875}, {"start": 1792.7, "end": 1793.04, "word": " مثل", "probability": 0.940185546875}, {"start": 1793.04, "end": 1793.88, "word": " مثوكسي", "probability": 0.96015625}, {"start": 1793.88, "end": 1794.96, "word": " مجموعة", "probability": 0.92451171875}, {"start": 1794.96, "end": 1795.14, "word": " ال", "probability": 0.82373046875}, {"start": 1795.14, "end": 1795.36, "word": " او", "probability": 0.775634765625}, {"start": 1795.36, "end": 1795.66, "word": " مثل", "probability": 0.993896484375}, {"start": 1795.66, "end": 1796.36, "word": " لوحدها", "probability": 0.90234375}, {"start": 1796.36, "end": 1796.94, "word": " لها", "probability": 0.5704345703125}, {"start": 1796.94, "end": 1797.24, "word": " اسم", "probability": 0.93212890625}, {"start": 1797.24, "end": 1797.42, "word": " شو", "probability": 0.699951171875}, {"start": 1797.42, "end": 1798.2, "word": " بنسميها", "probability": 0.965087890625}, {"start": 1798.2, "end": 1799.62, "word": " مثوكسي", "probability": 0.95048828125}, {"start": 1799.62, "end": 1800.04, "word": " لكن", "probability": 0.888671875}, {"start": 1800.04, "end": 1800.3, "word": " ما", "probability": 0.85009765625}, {"start": 1800.3, "end": 1801.94, "word": " بنسميه", "probability": 0.8704833984375}, {"start": 1801.94, "end": 1802.64, "word": " مثوكسي", "probability": 0.98212890625}, {"start": 1802.64, "end": 1803.02, "word": " بنزين", "probability": 0.9912109375}, {"start": 1803.02, "end": 1803.24, "word": " شو", "probability": 0.9052734375}, {"start": 1803.24, "end": 1804.46, "word": " بنسميه", "probability": 0.9581298828125}, {"start": 1804.46, "end": 1805.28, "word": " أنيزول", "probability": 0.699951171875}], "temperature": 1.0}, {"id": 77, "seek": 183279, "start": 1806.45, "end": 1832.79, "text": "لو كان في مجموعة ال الديهيد بنسميه بنزالديهيد لو كان في مجموعة ال C double bond OCH3 بنسميه أسيتوفينون لو كان في مجموعة الحامض C double bond OOH بنسميه بنزويك أسيد لو في ال NH2 أنيلين بنقولوش أمينو بنزين، شو بنقوله؟ أنيلين", "tokens": [1211, 2407, 25961, 8978, 3714, 7435, 2304, 2407, 27884, 2423, 2423, 16254, 3224, 25708, 44945, 38251, 1829, 3224, 44945, 11622, 6027, 16254, 3224, 25708, 45164, 25961, 8978, 3714, 7435, 2304, 2407, 27884, 2423, 383, 3834, 6086, 422, 5462, 18, 44945, 38251, 1829, 3224, 5551, 3794, 36081, 38688, 9957, 11536, 45164, 25961, 8978, 3714, 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five bromo two cloro three مثل ال alphabetical ذكرتهم ماتبهين؟ five bromo two cloro three", "tokens": [15042, 41185, 1975, 2304, 41361, 10632, 16472, 1975, 4587, 22488, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 8608, 2655, 3660, 4032, 9307, 5172, 38149, 16472, 3224, 3714, 31747, 3555, 1975, 1829, 8592, 22807, 2623, 268, 401, 2423, 7649, 34105, 6156, 47432, 4724, 995, 14851, 25957, 1211, 8717, 19913, 10943, 16247, 2288, 4587, 10943, 4724, 16254, 1975, 39648, 1732, 738, 13395, 732, 596, 10780, 1045, 50113, 1211, 2423, 23339, 804, 29910, 37983, 2655, 16095, 3714, 9307, 3555, 3224, 9957, 22807, 1732, 738, 13395, 732, 596, 10780, 1045], "avg_logprob": -0.25257554683056505, "compression_ratio": 1.5505050505050506, "no_speech_prob": 0.0, "words": [{"start": 2387.42, "end": 2387.88, "word": "مافي", "probability": 0.861572265625}, {"start": 2387.88, "end": 2388.5, "word": " امكانية", "probability": 0.7979736328125}, {"start": 2388.5, "end": 2389.18, "word": " ان", 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نستعمل الأرقام و نسيبنا من قصة ارثه ميته برة الان اذا اي واحدة بدأ تيجي بدل رقم اتنين لما بيكون two substituents تحط ارثه بدل تلاتة ميته و بدل اربعة برة مافيش عندنا مشكلة", "tokens": [2304, 12984, 1211, 8978, 1863, 12610, 1975, 15730, 45164, 30767, 18513, 14407, 2423, 4594, 6380, 791, 13672, 7578, 43242, 7578, 18871, 6055, 29399, 9957, 1975, 4117, 25708, 4724, 14851, 25957, 1211, 16247, 2288, 4587, 10943, 45164, 25961, 14407, 6055, 29399, 9957, 12602, 3555, 15042, 8717, 39648, 16247, 5172, 11242, 1211, 8717, 14851, 25957, 1211, 16247, 2288, 4587, 10943, 4032, 8717, 3794, 1829, 3555, 8315, 9154, 12174, 9381, 3660, 1975, 2288, 12984, 3224, 3714, 36081, 3224, 4724, 25720, 2423, 7649, 1975, 15730, 1975, 1829, 36764, 24401, 3660, 47525, 10721, 6055, 1829, 7435, 1829, 47525, 1211, 12602, 4587, 2304, 1975, 2655, 1863, 9957, 5296, 15042, 4724, 1829, 30544, 732, 4594, 6380, 791, 6055, 5016, 9566, 1975, 2288, 12984, 3224, 47525, 1211, 6055, 1211, 9307, 3660, 3714, 36081, 3224, 4032, 47525, 1211, 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دايمثلبنزين بياخد اسم شهرة إكزايلين", "tokens": [2304, 12984, 15040, 23758, 9673, 31747, 3555, 27554, 30727, 608, 6746, 996, 11368, 1450, 23758, 3714, 36081, 995, 11778, 995, 32640, 12984, 46152, 1863, 11622, 9957, 44381, 11778, 995, 32640, 12984, 46152, 1863, 11622, 9957, 4724, 1829, 47283, 3215, 24525, 2304, 13412, 3224, 25720, 11933, 4117, 11622, 995, 26895, 9957], "avg_logprob": -0.2774203524870031, "compression_ratio": 1.314516129032258, "no_speech_prob": 0.0, "words": [{"start": 2445.46, "end": 2445.98, "word": "مثلا", "probability": 0.8408203125}, {"start": 2445.98, "end": 2446.24, "word": " هذا", "probability": 0.82080078125}, {"start": 2446.24, "end": 2446.92, "word": " المركب", "probability": 0.7884114583333334}, {"start": 2446.92, "end": 2448.86, "word": " Orthodiachlorobenzene", "probability": 0.7686941964285714}, {"start": 2448.86, "end": 2449.8, "word": " هذا", "probability": 0.494384765625}, {"start": 2449.8, "end": 2450.66, "word": " ميتا", "probability": 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{"start": 2771.68, "end": 2771.94, "word": " واقع", "probability": 0.97216796875}, {"start": 2771.94, "end": 2772.5, "word": " الاستعمال", "probability": 0.90380859375}, {"start": 2772.5, "end": 2773.14, "word": " الحياتي", "probability": 0.9344482421875}, {"start": 2773.14, "end": 2773.28, "word": " و", "probability": 0.86767578125}, {"start": 2773.28, "end": 2773.74, "word": " الطب", "probability": 0.78173828125}, {"start": 2773.74, "end": 2774.36, "word": " و", "probability": 0.7880859375}, {"start": 2774.36, "end": 2774.86, "word": " لذلك", "probability": 0.9573567708333334}, {"start": 2774.86, "end": 2775.84, "word": " بندرس", "probability": 0.8907470703125}, {"start": 2775.84, "end": 2776.0, "word": " ال", "probability": 0.9814453125}, {"start": 2776.0, "end": 2776.26, "word": " organ", "probability": 0.55615234375}, {"start": 2776.26, "end": 2776.46, "word": " ال", "probability": 0.740234375}, {"start": 2776.46, "end": 2776.86, "word": " chemistry", "probability": 0.77978515625}, {"start": 2776.86, "end": 2777.26, "word": " و", "probability": 0.98876953125}, {"start": 2777.26, "end": 2777.38, "word": " ان", "probability": 0.5908203125}, {"start": 2777.38, "end": 2777.54, "word": " شاء", "probability": 0.97900390625}, {"start": 2777.54, "end": 2777.6, "word": " الله", "probability": 0.94873046875}, {"start": 2777.6, "end": 2777.96, "word": " المرة", "probability": 0.973876953125}, {"start": 2777.96, "end": 2778.5, "word": " القادمة", "probability": 0.9913736979166666}, {"start": 2778.5, "end": 2778.84, "word": " بكون", "probability": 0.863037109375}, {"start": 2778.84, "end": 2779.62, "word": " موضوعنا", "probability": 0.99453125}, {"start": 2779.62, "end": 2781.34, "word": " تفاعلات", "probability": 0.937890625}, {"start": 2781.34, "end": 2781.6, "word": " ال", "probability": 0.96337890625}, {"start": 2781.6, "end": 2782.16, "word": " aromatic", "probability": 0.9677734375}, {"start": 2782.16, "end": 2782.94, "word": " compounds", "probability": 0.68603515625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2783.09725, "duration_after_vad": 2682.6393749999897}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..cb98d7dd3a4f4664700923d83aa364c8f947a29e
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_postprocess.srt
@@ -0,0 +1,1876 @@
+1
+00:00:19,780 --> 00:00:23,920
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا على
+
+2
+00:00:23,920 --> 00:00:28,440
+أكسدة الكحولات عرفنا ايش اللي بنقصده في الأكسدة
+
+3
+00:00:28,440 --> 00:00:34,660
+تحويل ال OH إلى C double bond O من خلال فقط ذاتين
+
+4
+00:00:34,660 --> 00:00:40,740
+هيدروجين ولذلك احنا قلنا ان ال primary alcohol
+
+5
+00:00:40,740 --> 00:00:46,000
+بتأكسد و بصير ال aldehydes و ال secondary alcohol
+
+6
+00:00:46,000 --> 00:00:51,060
+بتأكسد و بصير ال ketonesالـ tertiary alcohols مش
+
+7
+00:00:51,060 --> 00:00:55,540
+عندهم إمكانية انهم يتأكسدوا ربما ضالت شغلة صغيرة
+
+8
+00:00:55,540 --> 00:00:59,580
+ان نحكي شو هو العامل المؤكسد اللي احنا بنستعمله
+
+9
+00:00:59,580 --> 00:01:06,160
+عادة لأكسدة ال primary alcohols بحيث تقف الأكسدة
+
+10
+00:01:06,160 --> 00:01:12,340
+عند ال aldehyde بنستعمل reagent بنعطيه رمز BCC
+
+11
+00:01:12,340 --> 00:01:17,380
+بريدينيام كلورو كروميت البريدينيام كلورو كروميت
+
+12
+00:01:18,050 --> 00:01:22,050
+بيحذف هيدروجينتين بيحوّل ال primary alcohol إلى
+
+13
+00:01:22,050 --> 00:01:27,230
+الديهيد يعني لاحظوا هاي إيثانون primary alcohol
+
+14
+00:01:27,230 --> 00:01:30,950
+هيفقد الهيدروجينتين هنا بدها دي تصير double bond
+
+15
+00:01:30,950 --> 00:01:34,670
+صار الديهيد إذا لو قلنا شو العامل المؤكسد اللي
+
+16
+00:01:34,670 --> 00:01:40,180
+استعملناه هناBCC باكسد ال primary alcohol ال
+
+17
+00:01:40,180 --> 00:01:46,340
+الديهايد الان ربما احنا نوحنا المرة الماضية ان ال
+
+18
+00:01:46,340 --> 00:01:51,420
+الديهايد ممكن يصير عليه اكسدة إضافية بإضافة
+
+19
+00:01:51,690 --> 00:01:55,830
+أكسوجينة بدل الهيدروجين يعني عملية إبدال يعني هذا
+
+20
+00:01:55,830 --> 00:02:00,330
+ال الديهايد بعد ما يتكون لو استعملتله عامل مؤكسد
+
+21
+00:02:00,330 --> 00:02:07,170
+أقوى ممكن أن أحوله أخليه بدل ما هو CH3COOH يعني
+
+22
+00:02:07,170 --> 00:02:11,070
+متصل مرتين بالأكسوجين أبدل ال H و أخليه H يعني
+
+23
+00:02:11,070 --> 00:02:17,090
+أخليه إيش يصير Carboxylic Acid يصفةسي أتش ثري سي
+
+24
+00:02:17,090 --> 00:02:21,750
+دبل بوند او الان عملية الأكسدة الإضافية تحويل هذه
+
+25
+00:02:21,750 --> 00:02:31,690
+ال H إلى OH واضح فال primary alcohol بالأكسدة
+
+26
+00:02:31,690 --> 00:02:35,030
+خلّينا نقول الضعيفة بيصير الديهايد و بيجف عند ال
+
+27
+00:02:35,030 --> 00:02:35,890
+الديهايد
+
+28
+00:02:39,060 --> 00:02:44,500
+اذا احنا كملنا بعد هيك في موضوع ال .. الاكسدة اذا
+
+29
+00:02:44,500 --> 00:02:49,040
+احنا كملنا بعد هيك في موضوع الاكسدة بحيث استعملنا
+
+30
+00:02:49,040 --> 00:02:52,500
+عامل مؤكسد اقوى و عادة العامل المؤكسد الاقوى هو
+
+31
+00:02:52,500 --> 00:02:57,260
+احد العوامل المؤكسدة اللي موجودة عندكم هنا كمان او
+
+32
+00:02:57,260 --> 00:03:01,440
+فور بيرمانجانات البوتاسيوم
+
+33
+00:03:02,970 --> 00:03:10,210
+بوتاسيوم بيرمانجانيت كتو كروميام 2 O7 بوتاسيوم
+
+34
+00:03:10,210 --> 00:03:11,050
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+35
+00:03:11,050 --> 00:03:11,270
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+36
+00:03:11,270 --> 00:03:12,210
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+37
+00:03:12,210 --> 00:03:12,890
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+38
+00:03:12,890 --> 00:03:13,030
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+39
+00:03:13,030 --> 00:03:14,450
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+40
+00:03:14,450 --> 00:03:17,470
+بوتاسيوم
+
+41
+00:03:17,470 --> 00:03:24,750
+بوتاسيوم بوتاسيوم بوتاسيوم بفال أكسدة هنا على
+
+42
+00:03:24,750 --> 00:03:29,470
+مرحلة ولا على مرحلتين؟ على مرحلتين بيجي السؤال طب
+
+43
+00:03:29,470 --> 00:03:35,070
+يا تورا لو استعملنا العامل المؤكسد القوي هذا مع ال
+
+44
+00:03:35,070 --> 00:03:42,210
+alcohol مع ال primary alcohol إيش هيعمل؟هيعمل
+
+45
+00:03:42,210 --> 00:03:47,030
+عمليتين الأكسدة هيمر بال الديهايد وبسرعة يظل مستمر
+
+46
+00:03:47,030 --> 00:03:50,730
+لإيش؟ للكربوكسيلك أسد يعني لو استعملت هذا العامل
+
+47
+00:03:50,730 --> 00:03:55,030
+المؤكسد من خلاله اعملت الأكسدة هاحصل على
+
+48
+00:03:55,030 --> 00:03:59,990
+الكربوكسيلك أسد واضح؟ فهيصير عندكم أن ال primary
+
+49
+00:03:59,990 --> 00:04:05,390
+alcohol بعامل مؤكسد قوي واحد من هدول التلاتة
+
+50
+00:04:05,390 --> 00:04:12,000
+نتيجته نهائيةCarboxylic Acid فهمان بمخنا بنقول مر
+
+51
+00:04:12,000 --> 00:04:16,860
+بمرحلة ال الديهايد واتحول بسرعة لاش ل Acid فإذا
+
+52
+00:04:16,860 --> 00:04:20,680
+استعمل عامل قوي النتيجة نهائية ال Acid إذا استعمل
+
+53
+00:04:20,680 --> 00:04:25,620
+عامل ضعيف النتيجة نهائية ال الديهايد لو حد بعد هيك
+
+54
+00:04:25,620 --> 00:04:30,380
+بده يحول ال الديهايد ل Acid يرود يستعمل مرة تانية
+
+55
+00:04:30,380 --> 00:04:35,770
+العامل المؤكسد القويلاحظوا هذه الأكسدة .. هذه
+
+56
+00:04:35,770 --> 00:04:41,150
+الأكسدة أكسدة كثير مهمة و كثير شهيرة يعني ماضلش
+
+57
+00:04:41,150 --> 00:04:45,970
+بعدها انتبهوا معي ال carbon في ال primary alcohol
+
+58
+00:04:45,970 --> 00:04:49,990
+بكم رابطة متصلة مع ال oxygen؟ واحدة .. واحدة ..
+
+59
+00:04:49,990 --> 00:04:51,690
+واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. واحدة
+
+60
+00:04:51,690 --> 00:04:51,850
+واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. واحدة
+
+61
+00:04:51,850 --> 00:04:51,910
+واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. واحدة
+
+62
+00:04:51,910 --> 00:04:52,170
+.. واحدة .. واحدة .. واحدة .. واحدة .. واحدة ..
+
+63
+00:04:52,170 --> 00:05:00,650
+واحدة .. واحدة .. واحدة .. واحدة .. واحد
+
+64
+00:05:02,850 --> 00:05:07,930
+الاربعة بيبطل في إمكانية للاربعة من ناحية المبدأ
+
+65
+00:05:07,930 --> 00:05:13,610
+فيه أعلى مراتب الأكسدة أنه يصير CO2 تاني أكسيد
+
+66
+00:05:13,610 --> 00:05:17,650
+الكربون تطلعوا
+
+67
+00:05:17,650 --> 00:05:20,770
+هنا من ضمن الاتحاد مع الأكسجين بنصير فاهمين
+
+68
+00:05:20,770 --> 00:05:25,370
+الأكسدة بالمفهوم البسيط القديم اتحاد مرة مع
+
+69
+00:05:25,370 --> 00:05:31,970
+الأكسجين مرتينتلاتة الأربع روابط صاروا متحدين مع
+
+70
+00:05:31,970 --> 00:05:37,150
+الأكسجين فأعلى مرحلة في الأكسجين ده أنه يصل لثاني
+
+71
+00:05:37,150 --> 00:05:38,290
+أكسيد الكربون
+
+72
+00:05:43,190 --> 00:05:48,650
+هذه الأكسادات حقيقة بتتم في التطبيق العملي و بتتم
+
+73
+00:05:48,650 --> 00:05:53,530
+كمان في جسم الإنسان يعني في التطبيق العملي لما
+
+74
+00:05:53,530 --> 00:05:58,970
+بيصنعوا الخمر هم بيجيبوا السكريات بيخمروها بتصير
+
+75
+00:05:58,970 --> 00:06:04,830
+إيثانول يعني لما بنفكر إنه عندنا sugar السكر
+
+76
+00:06:04,830 --> 00:06:11,730
+بالتخمير شو بيصير إيثانوللذلك بيخمروا العناب
+
+77
+00:06:11,730 --> 00:06:18,630
+الليزبي بالطمر يصير إيثانول يصير الخمرة طيب و كذلك
+
+78
+00:06:18,630 --> 00:06:23,290
+الفواكه الانجاس والتفاح وما إلى ذلك طب لو خمروه
+
+79
+00:06:23,290 --> 00:06:27,650
+لفترة أطول بظروف معينة يعرفها الناس اللي بيشتغلوا
+
+80
+00:06:27,650 --> 00:06:34,950
+بهذه الأمور هيتحول لإيش؟ لخل و لذلك الخل هو مرحلة
+
+81
+00:06:34,950 --> 00:06:37,690
+بعد الخمر
+
+82
+00:06:39,360 --> 00:06:42,740
+يعني لما بتم عملية التخمر أول اشي بيصير عند ال
+
+83
+00:06:42,740 --> 00:06:46,780
+ethanol الخمر وبعد هيك ال ethanol نفسه بتحول لخل
+
+84
+00:06:46,780 --> 00:06:55,480
+لاحظوا معنى ان الخمر محرم وناجس و الخل محرمحلال
+
+85
+00:06:55,480 --> 00:07:01,340
+وطاهر وفي الحديث افضل ادامكم الخل .. من افضل الأكل
+
+86
+00:07:01,340 --> 00:07:05,140
+اللي ممكن الانسان ياكله يستفيد منه حتى من ناحية
+
+87
+00:07:05,140 --> 00:07:08,800
+بيو كيميسترا يستعمل في تصنيع الجزيئات الأكبر منه
+
+88
+00:07:08,800 --> 00:07:15,790
+الخلالان طب الخمر هذا النجس لما بتحول لخل ايش
+
+89
+00:07:15,790 --> 00:07:21,210
+بيصير فيه؟ يطهر الفقاء ايش بيقولوا عنه؟ يطهر
+
+90
+00:07:21,210 --> 00:07:26,830
+بالتحول يعني إذا تحول النجس من حالته الكيميائية
+
+91
+00:07:26,830 --> 00:07:31,550
+إلى حالة أخرى فإنهم يصبحوا طاهرا ولذلك هذا الخمر
+
+92
+00:07:31,550 --> 00:07:41,490
+حرام هذا الخل حلالواضح؟ إذا تحول النجس إلى طاهر
+
+93
+00:07:41,490 --> 00:07:45,670
+فإنه يطهر، إذا تحول إلى مادة تانية، بيسموها إيش
+
+94
+00:07:45,670 --> 00:07:51,610
+هذه الشغلة؟ التطهير بالتحول، لأنه تحول من المادة
+
+95
+00:07:51,610 --> 00:07:55,870
+النجسة إلى مادة جديدة، فالمادة الجديدة هذه طالما
+
+96
+00:07:55,870 --> 00:07:59,270
+اختلفت في خواصة عن المادة الأولى فهي مادة إشمالها
+
+97
+00:07:59,270 --> 00:08:03,940
+طاهرةالان طيب الناس اللي بيشربوا الخمر إيش بيصير
+
+98
+00:08:03,940 --> 00:08:08,500
+بجسمهم؟ ما هو الخمر بيأثر على العقل بيشرب البني
+
+99
+00:08:08,500 --> 00:08:12,060
+آدم الخمر و بيروح عقله و كل الأشياء الأعراض السكر
+
+100
+00:08:12,060 --> 00:08:15,600
+اللي أنتوا بتعرفوها بعد سبع تمان ساعات تسعة ساعات
+
+101
+00:08:15,600 --> 00:08:19,980
+بيرجع إنسان طبيعي ولا لأ طب كيف الجسم اتخلص من
+
+102
+00:08:19,980 --> 00:08:23,360
+الخمر إذا؟ ما هو الجسم أخد إيثانول هو اللي عمل
+
+103
+00:08:23,360 --> 00:08:27,360
+عنده كل المشاكل كل هذه العمليات بتصير جوا الجسم
+
+104
+00:08:28,560 --> 00:08:33,780
+بالانزيمات المرة هذه إيثانول بيصير الديهايد بيصير
+
+105
+00:08:33,780 --> 00:08:40,070
+acid بيصير ثانو أكسيد الكربون بيطلع مع الزفيريعني
+
+106
+00:08:40,070 --> 00:08:44,390
+في النهاية الخمر كيف البني آدم بده يطلعه على شكل
+
+107
+00:08:44,390 --> 00:08:48,370
+carbon dioxide كل هذه العمليات عمليات الأكسدة
+
+108
+00:08:48,370 --> 00:08:52,890
+حقيقة بالتم في الجسم و زي ما انتوا شايفين بالتم
+
+109
+00:08:52,890 --> 00:08:57,990
+أيضا في الحياة العملية و في الصناعة صناعة الخل هي
+
+110
+00:08:57,990 --> 00:09:02,170
+عبارة عن أكسدة في النهاية هي عبارة عن أكسدة
+
+111
+00:09:06,160 --> 00:09:11,080
+هذا الكلام اللى موجود عندنا هنا الان لو كنا بنعمل
+
+112
+00:09:11,080 --> 00:09:14,900
+ال اكسدة ل secondary alcohol شو اتفقنا عليه بيصير
+
+113
+00:09:14,900 --> 00:09:19,320
+كيتون الان العامل المؤكسد احد العوامل المؤكسدة
+
+114
+00:09:19,320 --> 00:09:24,320
+القوية يعني كيعمل او 4 كي 2 كروميوم 2 او 7 كروميوم
+
+115
+00:09:24,320 --> 00:09:28,920
+او 3 عادة ب sulfuric acid يعني عشان احول ال
+
+116
+00:09:28,920 --> 00:09:34,520
+secondary alcohol الى كيتون بدي استعمل احد العوامل
+
+117
+00:09:34,520 --> 00:09:40,170
+المؤكسدةالقوية التيرتشاري الالكول زي ما اتفقنا مش
+
+118
+00:09:40,170 --> 00:09:45,890
+فيه هيدروجين تفقد ولذلك لا يتأكد بهذا تقريبا بنكون
+
+119
+00:09:45,890 --> 00:09:51,840
+أنهينا موضوعأكسدت الكحولات و دائما بنصحكم ما
+
+120
+00:09:51,840 --> 00:09:55,820
+تحفظوش كأشكال كيميائية لإحفظوه كأفكار ان ال
+
+121
+00:09:55,820 --> 00:09:58,460
+primary alcohol بيصير الديهايد و ممكن ال middle
+
+122
+00:09:58,460 --> 00:10:02,120
+acid حسب قوة العامل مؤكسد ال secondary alcohol
+
+123
+00:10:02,120 --> 00:10:06,140
+بيصير ال ketone و ال tertiary alcohol لايتأكسدش
+
+124
+00:10:06,140 --> 00:10:13,460
+الديهايد بتكون من أول .. احنا من أين يعني جيناها؟
+
+125
+00:10:13,460 --> 00:10:17,120
+هي من نفس التفاعل؟اي O ما هي ال alcohol اللي أنا
+
+126
+00:10:17,120 --> 00:10:21,780
+بادي فيه لأ ال O هذه معناها oxidizing agent
+
+127
+00:10:21,780 --> 00:10:26,920
+احفظوها هذا الرمز ال O اللي مكتوبة بجثين مربعين
+
+128
+00:10:26,920 --> 00:10:31,340
+معناها oxidizing agent بس هو ماحددوش يعني لما
+
+129
+00:10:31,340 --> 00:10:38,420
+تقرؤوا على سهم محطوطة ال O زي هيك معناها بالاكسدة
+
+130
+00:10:39,160 --> 00:10:43,060
+هو مش بواجهة انه يذكر العامل المؤكسد بس وين
+
+131
+00:10:43,060 --> 00:10:47,880
+بتقراوها هذا رمز يعني تفاعل أكسدة باستعمال عامل
+
+132
+00:10:47,880 --> 00:10:50,960
+مؤكسد الآن العوامل المؤكسدة شرحنالكوا إياها اللي
+
+133
+00:10:50,960 --> 00:10:56,480
+في المختبر وقولنالكوا في الجسم في انزيمات عادة
+
+134
+00:10:56,480 --> 00:11:03,200
+Oxidase بتسمى و بتقوم بهذه العملية واضح فهذه ال O
+
+135
+00:11:03,200 --> 00:11:09,350
+اللي مكتوبة بالجسم ربع منها عامل مؤكسدالان ال
+
+136
+00:11:09,350 --> 00:11:15,030
+polyhydroxy compounds هي مركبات تحتوي على اكثر من
+
+137
+00:11:15,030 --> 00:11:19,530
+مجموعة OH و طبعا طالما انه بتحتوي على اكثر من
+
+138
+00:11:19,530 --> 00:11:23,270
+مجموعة OH شو بنتوقع احنا في ال boiling point لهذه
+
+139
+00:11:23,270 --> 00:11:28,150
+المركبات؟ بده تزيد يعني لو عملنا مقارنة مع المركب
+
+140
+00:11:28,150 --> 00:11:31,670
+اللي فيه كربنتين و مجمعتين OH اللي هو ال ethanol
+
+141
+00:11:31,670 --> 00:11:39,330
+CH3 CH2 OH جديش كانت ال boiling point تبعته؟78 لو
+
+142
+00:11:39,330 --> 00:11:45,410
+صاروا مجمعتين OH بتصير يداش 198 لو صاروا تلاتة OH
+
+143
+00:11:45,410 --> 00:11:52,530
+متين وتسعين لو صاروا ستة OH بتحول لصلب بيصير مادة
+
+144
+00:11:52,530 --> 00:11:57,450
+صلبة الها melting point 110 ل 112 واضح؟ وكل هذه
+
+145
+00:11:57,450 --> 00:12:02,210
+المركبات اللي بالذات اللي فيها OH اللي أمامكم عادة
+
+146
+00:12:02,210 --> 00:12:08,120
+بتكون water soluble بتدوب في الميه إيش السبب؟لأنها
+
+147
+00:12:08,120 --> 00:12:12,400
+polar و like dissolves like الآن المركب اللي فيه
+
+148
+00:12:12,400 --> 00:12:16,540
+مجموعتين OH بنسميه احنا إيثالين جليكول لو بدنا
+
+149
+00:12:16,540 --> 00:12:21,480
+يابل ايو باك بزامتين تين OH بدل all دايول حيصير
+
+150
+00:12:21,480 --> 00:12:25,080
+one two اثان دايول اللي فيه تلاتة OH هو ال
+
+151
+00:12:25,080 --> 00:12:30,060
+glycerinاللي بنعمل فيه الإيدين أو ال glycerol one
+
+152
+00:12:30,060 --> 00:12:36,000
+two three بروبان ال triol اللي فيه ستة O H's ال
+
+153
+00:12:36,000 --> 00:12:40,580
+sorbitol المطهر اللي عادة بيستعمله لتطهير الإيدين
+
+154
+00:12:40,580 --> 00:12:43,860
+و الأرضيات اللي هو one two three four five six
+
+155
+00:12:43,860 --> 00:12:53,560
+hexane hexaol ربما بيفيد هنا نقطةتظلوا دائما
+
+156
+00:12:53,560 --> 00:12:59,400
+متذكرينها لأنه ممكن تسألوا عنها ان المركبات عديدة
+
+157
+00:12:59,400 --> 00:13:04,960
+ال O H ليست السكريات طيب السكريات ايش بتكون
+
+158
+00:13:04,960 --> 00:13:09,060
+السكريات او sugars و هنعود ناخد هذا الكلام في ال
+
+159
+00:13:09,060 --> 00:13:14,540
+biochemistry هي مركبات عديدة ال O H لكن بينوجد
+
+160
+00:13:14,540 --> 00:13:18,940
+فيها مجموعة واحدة بالاضافة لل O H الديهيد او كيتون
+
+161
+00:13:19,910 --> 00:13:25,290
+فعشان المُركّب يكون سُكر ضمن تصنيف الكيميائي من
+
+162
+00:13:25,290 --> 00:13:29,250
+السُكريات بدوا يكون فيه مجموعات أوقاتش كتير بس
+
+163
+00:13:29,250 --> 00:13:34,790
+بدوا يكون فيه واحدة الديهايد او كيتون يعني مثلا لو
+
+164
+00:13:34,790 --> 00:13:40,680
+هذه كانت كيتونهذا بلغة الكيميا بيصير إيش؟ sugar لو
+
+165
+00:13:40,680 --> 00:13:44,940
+هذه نفترض كانت الديهيد هذا بلغة الكيميا بيصير
+
+166
+00:13:44,940 --> 00:13:51,980
+sugar فال sugars تعريفها بوليهيدروكسي صح بس مش
+
+167
+00:13:51,980 --> 00:13:57,520
+بوليهيدروكسي compounds لأ بوليهيدروكسي الديهيد أو
+
+168
+00:13:57,520 --> 00:14:04,270
+كيتون واضح؟شوفنا إيش بيفرغوا السكريات عن ال
+
+169
+00:14:04,270 --> 00:14:07,810
+polyhydroxy compounds ال polyhydroxy compounds بس
+
+170
+00:14:07,810 --> 00:14:13,690
+مجموعات OH لو مع مجموعات ال OH إيجي عندى aldehyde
+
+171
+00:14:13,690 --> 00:14:18,050
+أو كيتون وقتها بيصيروا المراكبات إيش sugars ال
+
+172
+00:14:18,050 --> 00:14:22,410
+polyhydroxy aldehydes هنتعلم إنه اسمهم ال doses و
+
+173
+00:14:22,410 --> 00:14:26,690
+ال polyhydroxy ketones هنتعلم إنه اسمهم ketoses
+
+174
+00:14:26,690 --> 00:14:32,120
+واضح؟فنضل متذكرين هذه المعلومة ان السكر الديهيد او
+
+175
+00:14:32,120 --> 00:14:39,220
+كيتون مع مجموعات O H اكتار واضح الديهيد او كيتون
+
+176
+00:14:39,220 --> 00:14:44,480
+لحاله مش Sugar مجموعات O H لحالهابرضه مش sugar
+
+177
+00:14:44,480 --> 00:14:50,940
+واضح ال sugar ال dehydrate او كيتون ومعه مجموعات
+
+178
+00:14:50,940 --> 00:14:57,400
+OH اكتر طبعا في مركبات تانية ربما اخليكوا تعرفوا
+
+179
+00:14:57,400 --> 00:15:01,460
+واحد منها بس aromatic compounds عليهم اكتر من ال
+
+180
+00:15:01,460 --> 00:15:04,480
+OH و بيمروا مرات معاكم في ال biology او ال
+
+181
+00:15:04,480 --> 00:15:08,560
+biochemistry مثلا المركب اللي فيه تنتين OH على ال
+
+182
+00:15:08,560 --> 00:15:13,560
+ortho position اسمه catecholاكتير هتظل تقرأ
+
+183
+00:15:13,560 --> 00:15:17,580
+كاتيكول و ما إلى ذلك و هذا المركب resource ..
+
+184
+00:15:17,580 --> 00:15:23,800
+resource in all هذا hydroquinone هذا بيرو .. بيرو
+
+185
+00:15:23,800 --> 00:15:29,510
+غالول الآن خلّينا اليوميعني إذا بدنا بالتأكيد
+
+186
+00:15:29,510 --> 00:15:32,210
+تكونوا حافظين مركّب تعرفوا الـ hydroquinone
+
+187
+00:15:32,210 --> 00:15:37,850
+الهيدروكوينون المركّب اللي فيه بارا دايهيدروكسي
+
+188
+00:15:37,850 --> 00:15:41,390
+بنزين واضح؟ هذا إيش اسمه؟
+
+189
+00:15:43,500 --> 00:15:49,240
+الان الـ Hydroquinone عادة بيعمل أكسدة و زي ما
+
+190
+00:15:49,240 --> 00:15:54,300
+قلنا احنا محصلة الأكسدة فقد ذرتين الهيدروجين و
+
+191
+00:15:54,300 --> 00:15:57,820
+تكوين رابطة لو انا اطلعت على هذا الجزء الـ
+
+192
+00:15:57,820 --> 00:16:03,300
+Hydroquinone هاي رابطة تنتين تلاتة طب لو فقدت هذه
+
+193
+00:16:03,300 --> 00:16:08,540
+الـ H و هذه الـ Hهعمل كمان رابط اي كداش حيصير
+
+194
+00:16:08,540 --> 00:16:12,840
+مجموع الروابط الزوجية اربعة حيصير بهذا الشكل شكل
+
+195
+00:16:12,840 --> 00:16:17,240
+المركب الان هذا بنسمي احنا Benzoquinone او 1,4
+
+196
+00:16:17,240 --> 00:16:21,600
+-benzoquinone لاحظوا ان هذه العملية تمت في وجود
+
+197
+00:16:21,600 --> 00:16:28,870
+عاملمؤكسد فالفينول تتأكسد
+
+198
+00:16:28,870 --> 00:16:34,710
+و تصبح تحديدا منها الهيدروكوينون بيصبح بالزوكوينون
+
+199
+00:16:34,710 --> 00:16:39,270
+و كل الفينول بشكل عام عادة ما بتتم عليها تأكسد
+
+200
+00:16:39,270 --> 00:16:43,810
+بطريقة او باخره هذا الكلام بيحولنا لتطبيق كتير مهم
+
+201
+00:16:43,810 --> 00:16:48,430
+ان فيه مركبات احنا في الدنيا بنسميها antioxidants
+
+202
+00:16:48,430 --> 00:16:51,790
+يعني مركبات
+
+203
+00:16:53,530 --> 00:17:00,090
+بديش اقول عنها انا مضادة ربما الترجمة مرات تحتاج
+
+204
+00:17:00,090 --> 00:17:06,950
+إلى نوع من الدقة تماما زي ما بنترجم احنا كلمة
+
+205
+00:17:06,950 --> 00:17:11,900
+مانعة الصواعقتمام؟ اكتر ربما مر عليكم انه باللغة
+
+206
+00:17:11,900 --> 00:17:17,280
+العربية بيستعمله مانعة الصواعق الحقيقة الصاعقة من
+
+207
+00:17:17,280 --> 00:17:21,020
+ربنا سبحانه وتعالى هذا العمود الحديد اللي احنا
+
+208
+00:17:21,020 --> 00:17:27,650
+بنحقه هيك هل يا ترى يمنع الصاعقة أن تحدث؟أه إذا هو
+
+209
+00:17:27,650 --> 00:17:32,290
+إيش بيعمل هو يمطس الصائقة و لا يمنع الصائقة و لذلك
+
+210
+00:17:32,290 --> 00:17:36,870
+الصائقة كهربا كبيرة جدا لو نزلت على المبنى بتحرج
+
+211
+00:17:36,870 --> 00:17:40,030
+أو بتحرك شبكات الكهربا اللي فيه لما يحطوا هذه
+
+212
+00:17:40,030 --> 00:17:44,130
+الحديدة كل الكهربا اللي نازلة من الصائقة بتدخل في
+
+213
+00:17:44,130 --> 00:17:48,390
+الحديدة موصولة بسلك في الأرض بتتفرج في الأرض بتتوه
+
+214
+00:17:48,390 --> 00:17:54,170
+بدل ما تنزل على الأجهزة و على المبنى فبهذا المفهوم
+
+215
+00:17:54,170 --> 00:17:59,390
+الصائقة صائقة لم تمنعلكن ايش اللي صار عنده؟ تم
+
+216
+00:17:59,390 --> 00:18:05,690
+انتصاص للصواقة ولذلك ربما يكون أدق انها تتسمى مش
+
+217
+00:18:05,690 --> 00:18:12,310
+مانعة الصواقر، ماصة الصواقر، واضح؟ كذلك الحال في
+
+218
+00:18:12,310 --> 00:18:16,110
+المركبات اللي اسمها antioxidants و اللي احنا عادة
+
+219
+00:18:16,110 --> 00:18:24,150
+بنضيفها على الأطعمةتسميتها بمضادات الأكسدة وكأنها
+
+220
+00:18:24,150 --> 00:18:30,510
+تمنع الأكسدة ليست تسمية أو ليست ترجمة دقيقة لهذا
+
+221
+00:18:30,510 --> 00:18:36,830
+المصطلح الأصل أن نقول عنها مركبات ماصة للأكسدة
+
+222
+00:18:36,830 --> 00:18:43,530
+بمعنى إذا احنا عملنا مثلا علبة معلباتأو مرتاديلة
+
+223
+00:18:43,530 --> 00:18:47,990
+أو ما إلى ذلك وضفنا عليها هذه المادة ودخل عليها ..
+
+224
+00:18:47,990 --> 00:18:52,510
+دخل عليها شوية أكسوجين وهي مغلقة هذا الأكسوجين أو
+
+225
+00:18:52,510 --> 00:18:56,510
+أي مادة مؤكسدة هيك هيك وظيفته هيجوم فيها هيعمل
+
+226
+00:18:56,510 --> 00:19:01,190
+أكسدة لكن اللي بيصير .. اللي بيصير بالظبط .. اللي
+
+227
+00:19:01,190 --> 00:19:06,190
+بيصير بالظبط في فكرة الـ Antioxidants اتخيلوها
+
+228
+00:19:06,190 --> 00:19:11,680
+انتوا بهذا الشكل ان انا هيعندي علبة معلباتواضح؟
+
+229
+00:19:11,680 --> 00:19:19,280
+هذه معلبة لحمة الان هذه المعلبة اللحمة فيها اللحوم
+
+230
+00:19:19,280 --> 00:19:25,440
+خلينا نقول الحمراء وفيها بنسبة قليلة جدا جدا
+
+231
+00:19:25,440 --> 00:19:34,360
+antioxidant المادة هذه اللي بنقول عنهاالان اتيت
+
+232
+00:19:34,360 --> 00:19:41,620
+اكساد او اكسوجين او اكساد اكساد اكساد اكساد اكساد
+
+233
+00:19:41,620 --> 00:19:50,450
+اكساد اكسادإذا أكسدت اللحوم هتطلع مواد سامة برائحة
+
+234
+00:19:50,450 --> 00:19:55,870
+سيئة اللي هو فساد اللحمة، الآن في احتمال تاني إنها
+
+235
+00:19:55,870 --> 00:20:00,290
+ت أكسد ال antioxidant اللي أنا حطيته، بشكل عام
+
+236
+00:20:00,290 --> 00:20:04,490
+ميزة ال antioxidant إنه أسهل في الأكسدة، وبناء على
+
+237
+00:20:04,490 --> 00:20:10,290
+ذلك لما هذه بتتيجي إيش المادة الأسهل أن تتأكسد ال
+
+238
+00:20:10,290 --> 00:20:16,220
+antioxidant؟واضح؟ فالعمل المؤكسد هي كيك بيأكسد
+
+239
+00:20:16,220 --> 00:20:24,440
+فبيأكسد ال antioxid يعني مرة تانية نرجع نقول أن
+
+240
+00:20:24,440 --> 00:20:31,560
+اللحوم دلت زي ما هي ماصارش عليها إشي الآن ال
+
+241
+00:20:31,560 --> 00:20:35,100
+antioxid اتغيرت صارت أشياء جديدة
+
+242
+00:20:38,120 --> 00:20:43,060
+فعملية ال Oxidation حولت ال antioxidant لمادة
+
+243
+00:20:43,060 --> 00:20:46,620
+تانية الآن انتبهوا للناس اللي بيشتغلوا في الأغذية
+
+244
+00:20:46,620 --> 00:20:51,280
+شرط عندهم أن هذه المادة اللي أنا بستعملها
+
+245
+00:20:51,280 --> 00:20:56,320
+antioxidant تكون آمنة وغير سامة، مظبوط ولا لأ؟ ما
+
+246
+00:20:56,320 --> 00:21:01,730
+أنا ضيفة على الأكل، إذا هذه لازم تكون إيش؟ Safeو
+
+247
+00:21:01,730 --> 00:21:07,190
+ناتج أكسادتها أيضا هيضلوا في الأكل برضه لازم ايش
+
+248
+00:21:07,190 --> 00:21:15,490
+يكون safeفهل يا ترى عملية ال Axa ده مُنِعت ولا
+
+249
+00:21:15,490 --> 00:21:21,110
+تمت؟ تمت لكن تمت على إيش؟ على ال antioxidant مش
+
+250
+00:21:21,110 --> 00:21:24,730
+على اللحوم وال antioxidant تحول إلى مادة غير ضارة
+
+251
+00:21:24,730 --> 00:21:28,190
+وبالتالي ماصارش تأثير هذه فكرة بالظبط ال
+
+252
+00:21:28,190 --> 00:21:32,010
+antioxidants الآن من المواد اللي بتستعمل
+
+253
+00:21:32,010 --> 00:21:36,050
+antioxidants اللي هي ال phenolsيعني لو بتكون
+
+254
+00:21:36,050 --> 00:21:39,370
+تبحثوا في google search مثلا اكتبوا antioxidant
+
+255
+00:21:39,370 --> 00:21:43,350
+بتلاقوه بيكمل الكوفينول و آلاف الأبحاث و المواد
+
+256
+00:21:43,350 --> 00:21:50,710
+بعضها طبيعي و بعضها صناعي يعني مثلا هذا vitamin E
+
+257
+00:21:50,710 --> 00:21:55,070
+لاحظوا فيه هنا مجموعة الفينول ولا لأ
+
+258
+00:21:57,730 --> 00:22:02,250
+شكل كبير ماله و ماله لكن الجزء الفعال فيه جزء
+
+259
+00:22:02,250 --> 00:22:08,450
+الفينول ولذلك vitamin E بنقول عنه natural phenolic
+
+260
+00:22:08,450 --> 00:22:13,090
+antioxidant يعني مضاد للأكسدة أو مواصل الأكسدة
+
+261
+00:22:13,090 --> 00:22:19,100
+خلينا هيك اتفقنا عليه من مصادرطبيعية الآن في مواد
+
+262
+00:22:19,100 --> 00:22:22,740
+من مصادر صناعية يعني صنعوها في المختبر و بيضفوها و
+
+263
+00:22:22,740 --> 00:22:26,460
+هذه مشهورة كل علب المرتدلة و البندورة و البصاريش
+
+264
+00:22:26,460 --> 00:22:30,880
+بيضفو عليها منها هذه المراكبات أهم شي انتبهوا فيها
+
+265
+00:22:30,880 --> 00:22:38,020
+مجموعة ال ايش ال O H's الان هذه المراكبات مشتقات
+
+266
+00:22:38,020 --> 00:22:43,900
+أنيزول متذكرين الانيزول البنزينة اللي عليها O مثل
+
+267
+00:22:43,900 --> 00:22:49,510
+هذه اسمها أنيزوللما أخدنا ال aromatic compounds
+
+268
+00:22:49,510 --> 00:22:54,070
+أنيزول بنزين عليها O مثل عشان هيك هذا بنقول عنه
+
+269
+00:22:54,070 --> 00:22:58,350
+butylated لإنه هذا المجموعه butyl اربع كربونات
+
+270
+00:22:58,350 --> 00:23:05,130
+هيدروكسي لإنه فيه OH والاصل أنيزول شوفتوا الاسم من
+
+271
+00:23:05,130 --> 00:23:08,990
+كام قطعة مكوّن بيوتل و هيدروكسي و أنيزول هاي ال
+
+272
+00:23:08,990 --> 00:23:11,270
+butyl انعلمه بالأحمر
+
+273
+00:23:13,790 --> 00:23:21,090
+بيوتليتد هيدروكسي أنيزول الان ايش بيختصروه BHA
+
+274
+00:23:21,090 --> 00:23:26,630
+وهذا زيه بيوتليتد هيدروكسي أنيزول طيب لو الحلقة
+
+275
+00:23:26,630 --> 00:23:35,090
+الأصلية كانت طلوين هي بيوتلأيضا اكثر من مجموعة في
+
+276
+00:23:35,090 --> 00:23:41,510
+هذا المُركّب بيوتل وهيدروكسي وطولوين بيوتلاتد
+
+277
+00:23:41,510 --> 00:23:46,990
+هيدروكسي طولوين بيوتلاتد
+
+278
+00:23:46,990 --> 00:23:51,140
+هيدروكسي طولوينو عادة بتاخد رموز يعني بتلاقوها
+
+279
+00:23:51,140 --> 00:23:58,080
+بكتبوا BHA و BHT فالـ BHA و BHT اللي هي butylated
+
+280
+00:23:58,080 --> 00:24:01,240
+hydroxy anisole و butylated hydroxy toluene are
+
+281
+00:24:01,240 --> 00:24:06,840
+synthetic antioxidants عارفين إيش يعني synthetic
+
+282
+00:24:07,620 --> 00:24:13,500
+يعني مصنعة في المعمل، synthetic، هذه natural من
+
+283
+00:24:13,500 --> 00:24:17,420
+الطبيعة، في أشياء في الطبيعة و في أشياء بنصنعها
+
+284
+00:24:17,420 --> 00:24:26,180
+احنا و بنضيفها على الأطعمة هذا بالنسبة لموضوع الـ
+
+285
+00:24:26,180 --> 00:24:27,560
+Antioxidants
+
+286
+00:24:31,430 --> 00:24:36,590
+المُركّب أنيزول، المُركّب أنيزول، المُركّب أنيزول،
+
+287
+00:24:36,590 --> 00:24:43,090
+أما هي methoxy، methoxy، مش فيها خلافبنجي للعائلة
+
+288
+00:24:43,090 --> 00:24:48,550
+المشتقة من ال alcohols اللي قُبضلت فيها مجموعة ال
+
+289
+00:24:48,550 --> 00:24:55,330
+OH ب SH هذه العائلة شو بنسميها؟ Thyol فبدل ما يصير
+
+290
+00:24:55,330 --> 00:24:59,750
+نهاية المُركّب All بيصير نهاية المُركّب Thyol
+
+291
+00:24:59,750 --> 00:25:04,510
+ولذلك هذا مثلا كنا نسميه بال OH مثال All بيصير
+
+292
+00:25:04,510 --> 00:25:12,160
+مثالثيول هذا ابروبانول بيصير ابروبانثيول او عفوا
+
+293
+00:25:12,160 --> 00:25:16,520
+بيوتان اربعة بيوتانثيول طبعا لازم نحدد الموقع ولا
+
+294
+00:25:16,520 --> 00:25:23,080
+لأ ابيوتانثيول هذا بدل فينول شو بنسميه؟ ثيوفينول
+
+295
+00:25:23,080 --> 00:25:27,640
+ال OH فينول بال سالفر ثيوفينول الآن متذكرين لما
+
+296
+00:25:27,640 --> 00:25:32,960
+كان انا يكون OH شو كنت اسمي المركب؟ مثل ال alcohol
+
+297
+00:25:34,340 --> 00:25:40,120
+أو بيوت ال alcohol بال common name ال common name
+
+298
+00:25:40,120 --> 00:25:45,660
+بذكر المجموعة ثم العائلة مثل مثل alcohol هذا
+
+299
+00:25:45,660 --> 00:25:48,920
+common name المجموعة في العائلة بيوت ال alcohol و
+
+300
+00:25:48,920 --> 00:25:53,460
+هكذا الآن العائلة الموازية لكلمة alcohol في
+
+301
+00:25:53,460 --> 00:26:00,020
+الكبريت مركبتان فهذا بيصير مثلمركبتان هذا بيصير
+
+302
+00:26:00,020 --> 00:26:06,180
+بيوتل مركبتان هذا بيصير فنل مركبتان فمركبتان هي
+
+303
+00:26:06,180 --> 00:26:12,360
+العائلة الموازية لكلمة إيش؟ Alcohol زي ما كنت أقول
+
+304
+00:26:12,360 --> 00:26:15,400
+مثل ألكول، إثل ألكول، برو بالألكول، لو قلتلكوا
+
+305
+00:26:15,400 --> 00:26:19,720
+أرسموا مثل مركبتان، إثل مركبتان، بيوتل مركبتان،
+
+306
+00:26:19,720 --> 00:26:23,420
+ايزو بيوتل مركبتان، بتكون تشيلوا بدل أو أتش و
+
+307
+00:26:23,420 --> 00:26:29,570
+تحطوا الالكول، واضح؟طبعا وين انتوا بتشوفوا كلمة
+
+308
+00:26:29,570 --> 00:26:33,430
+mercapto او ثيو اعرفوا ان انتوا أمام مركب فيه
+
+309
+00:26:33,430 --> 00:26:37,290
+cabret يعني مركبات الكابريت دائما يا هتلاقوا فيها
+
+310
+00:26:37,290 --> 00:26:42,350
+ثيو زي ما شوفته هنا يا mercapto مثلا هذا حمض الخل
+
+311
+00:26:42,350 --> 00:26:49,930
+بس حولنا فيه بدل ما كانت OH أسيتك أسن CH3C double
+
+312
+00:26:49,930 --> 00:26:55,450
+bond O OH أسيتك أسن طب لو شيلت ال O خلتها S صار
+
+313
+00:26:55,450 --> 00:27:04,380
+ثيونacetic acid واضح هذا مثلا sulphide السلفر
+
+314
+00:27:04,380 --> 00:27:12,420
+المتصل فيها مجموعتين R إثل و إثل داي إثل sulphide
+
+315
+00:27:12,420 --> 00:27:16,100
+و الداي مرات تختصر يعني بنقدر نسميه الداي إثل و
+
+316
+00:27:16,100 --> 00:27:20,280
+بنقدر نسميه إثل يعني لما نقول إثل sulphide أو داي
+
+317
+00:27:20,280 --> 00:27:24,560
+إثل sulphide الإسمين صحيحين
+
+318
+00:27:25,800 --> 00:27:29,720
+الان لو اجينا عليها هذه العائلة قولنا يا تورا هذه
+
+319
+00:27:29,720 --> 00:27:33,800
+عائلة التيورس كيف بنحضرها ال R X أخدناها في
+
+320
+00:27:33,800 --> 00:27:37,700
+chapter 6 بال nucleophilic substitution فعلوها مع
+
+321
+00:27:37,700 --> 00:27:42,440
+S H minus charged nucleophile بيهاجم على ال R و
+
+322
+00:27:42,440 --> 00:27:48,580
+بيطرد ال X هذا الإبدال اللي أخدناه في chapter 6
+
+323
+00:27:48,580 --> 00:27:57,270
+مشحون مكان مشحون فال R X بتصيرRSH اذا هى هذا اللى
+
+324
+00:27:57,270 --> 00:28:03,070
+هو how to prepare thyols by reaction of RX يصيروا
+
+325
+00:28:03,070 --> 00:28:08,710
+RSH الان بدى يكون عندكم شوية كيميا كبيرة فى مخكم
+
+326
+00:28:08,710 --> 00:28:13,490
+بمعنى لو انا يا تورا قلتلكم كيف بدكم تحضروا thyol
+
+327
+00:28:13,490 --> 00:28:16,970
+من الالكول الthyol انتوا عامال عندكم من وين بنحضره
+
+328
+00:28:16,970 --> 00:28:25,170
+من ال RX طب لو انا بديلكم ب ROHأخدت طريقة تحوّل ال
+
+329
+00:28:25,170 --> 00:28:32,310
+R OH ل R X تكون متذكرينها طيب ممكن كمان أبدأ من ال
+
+330
+00:28:32,310 --> 00:28:37,290
+كيم أخدت طريقة تحوّل ال ال كيم ل R X ولا لأ إضافة
+
+331
+00:28:37,290 --> 00:28:47,070
+HX فبصير مطلوب منكوا أن تدمجوا أكثر من معلومة في
+
+332
+00:28:47,070 --> 00:28:53,260
+الكيمياأخدنا احنا ان الثيولز are stronger acids
+
+333
+00:28:53,260 --> 00:28:58,520
+than alcohols، والسبب ايش حكينا؟ ال size، ال size،
+
+334
+00:28:58,520 --> 00:29:01,660
+ولذلك الثيولز بتفاعلوا مع ال sodium hydroxide
+
+335
+00:29:01,660 --> 00:29:07,170
+وبيعطوا ملح وماء، هذه المعادلة أخدناهامن أهم
+
+336
+00:29:07,170 --> 00:29:12,450
+التفاعلات تبعت الـthiols أنه بيتم عليهم أكسدة
+
+337
+00:29:12,450 --> 00:29:16,650
+جزيئين thiol بيفقدوا هيدروجين ماشيلنا ساعة بيقول
+
+338
+00:29:16,650 --> 00:29:20,790
+الأكسدة بيدا تفقد ذاتين هيدروجين الأن بنجيب جزيئين
+
+339
+00:29:20,790 --> 00:29:25,830
+thiol RSH بنسبة اتنين مثلا بالأكسدة بيفقدوا
+
+340
+00:29:25,830 --> 00:29:32,760
+هيدروجينيعني ماينوس اكشت و الاكس ده بيصير RSSR هذا
+
+341
+00:29:32,760 --> 00:29:37,940
+صار اسمه داي سالفايد لما عندي سالفار واحدة سالفايد
+
+342
+00:29:37,940 --> 00:29:41,940
+لما عندي تنتين داي سالفايد لو افترضنا هنا اثل و
+
+343
+00:29:41,940 --> 00:29:48,040
+اثل شو بدا اسم المركب داي اثل داي سالفايد طب لو
+
+344
+00:29:48,040 --> 00:29:52,600
+مثل و مثل داي مثل داي سالفايد لو هذه المجموعة اللي
+
+345
+00:29:52,600 --> 00:29:59,580
+مرة أخدناهاالألل اللى موجودة فيه التومة داي ألل
+
+346
+00:29:59,580 --> 00:30:06,300
+داي سالفايد واضح فالثيول هم اكسيدز لثيول داي
+
+347
+00:30:06,300 --> 00:30:11,040
+سالفايد الان لو ضفنا عليهم هيدروجين يعملنا التفاعل
+
+348
+00:30:11,040 --> 00:30:17,820
+العكسى ال داي سالفايد ايش بيرجعوا ثيول اذا هذه
+
+349
+00:30:17,820 --> 00:30:23,900
+عمليةبتمشي باتجاهين بحق في الهيدروجين الثيول بيصير
+
+350
+00:30:23,900 --> 00:30:27,600
+داي سالفايد هذه أكسه ده بإضافة الهيدروجين ال داي
+
+351
+00:30:27,600 --> 00:30:33,160
+سالفايد بترجع لإيش؟لثيول الان هذه العملية .. هذه
+
+352
+00:30:33,160 --> 00:30:37,900
+العملية الحقيقة عملية في ال biology و في الأحياء
+
+353
+00:30:37,900 --> 00:30:42,340
+كتير مهمة ليش؟ لأنه في النهاية البروتينات لما
+
+354
+00:30:42,340 --> 00:30:47,540
+بتتماسك مع بعض لبعض فيها مجموعات الثيول و تحديدا
+
+355
+00:30:47,540 --> 00:30:51,920
+جاية من ال amino acid السيستين فتخيلوا ان عندكم
+
+356
+00:30:51,920 --> 00:30:57,060
+مثلا سلسلتين و في النهاية فيهم SH من البروتين هذا
+
+357
+00:30:57,060 --> 00:31:05,700
+بالأكسدةيفقد الهيدروجنتين و يعمل رابطة، بهيك صار
+
+358
+00:31:05,700 --> 00:31:11,320
+البروتين امسك بشكل قوي ولا لأ؟ بيصير البروتين امسك
+
+359
+00:31:11,320 --> 00:31:18,040
+بشكل قوي، الآن من أمثلة البروتينات اللي فيها الـ
+
+360
+00:31:18,040 --> 00:31:24,390
+disulfides الشعرو عشان هيك الشعر لاحظه أنه أحيانا
+
+361
+00:31:24,390 --> 00:31:28,350
+لما الإنسان إيده بتقترب من النار أو بينحرق شعره
+
+362
+00:31:28,350 --> 00:31:34,090
+بيشم رائحة سيئة رائحة حرق الشعر سيئة شو السبب؟ أن
+
+363
+00:31:34,090 --> 00:31:42,430
+الشعر فيه كبريت الآن هذا الشعر الناس للأسف الشديد
+
+364
+00:31:42,430 --> 00:31:48,730
+مش عاجبها حالها كل من هو بده يغير إيش شكله امتثالا
+
+365
+00:31:51,390 --> 00:31:58,310
+لما قولت الشيطان ثم لأمرنهم فلا يغيرن خلق الله
+
+366
+00:31:58,310 --> 00:32:03,850
+يعني اللي في أفريقيا الشعر عندهم لو لو بيعمل بده
+
+367
+00:32:03,850 --> 00:32:07,510
+يفرده و اللي في أوروبا ربنا ماعطيهم الشعر العدل
+
+368
+00:32:07,510 --> 00:32:13,930
+بتشوفهم كيف بدهم يعملوا الوف الان هذا بالانجليزي
+
+369
+00:32:13,930 --> 00:32:20,920
+احنا بنقوله curly الشعرالمجاعد المجاعد أو straight
+
+370
+00:32:20,920 --> 00:32:24,780
+الشعر المستقيم الشعر المستقيم الان ابتاع ال
+
+371
+00:32:24,780 --> 00:32:28,920
+straight بدو يصير مجاعد وابتاع المجاعد بدو يصير
+
+372
+00:32:28,920 --> 00:32:33,240
+straight ماحدش عاجبه حاله هذه العملية سواء تمت
+
+373
+00:32:33,240 --> 00:32:38,210
+بهذا الاتجاه او بهذا الاتجاه هي عملية كيميائيةهي
+
+374
+00:32:38,210 --> 00:32:41,170
+عملية كيميائية، يعني هذه العملية اللي بتنعمل في
+
+375
+00:32:41,170 --> 00:32:47,250
+صالونات لحلاجة وعند الكوفيرات الحقيقة هي عملية
+
+376
+00:32:47,250 --> 00:32:51,330
+كيميائية الفكرة فيها وين؟ انه احنا بنقدر نتخيل
+
+377
+00:32:51,330 --> 00:32:57,170
+الشعر بروتين وهذا البروتين ممسك بـ disulfide bonds
+
+378
+00:32:57,170 --> 00:33:05,450
+ملاحظين هنا؟هذه بتقدروا تتخيلوها شعرة، الان كونوا
+
+379
+00:33:05,450 --> 00:33:10,470
+الشعر في الـ disulfide bond هذه، بيصير الشعر قوي
+
+380
+00:33:10,470 --> 00:33:15,830
+ولا لأ؟ بالنسبة لخيط، بالنسبة لخيط يعتبر الشعر
+
+381
+00:33:15,830 --> 00:33:23,200
+قوي، سبب القوة تبعته وجود إيش؟ وجود؟الـ disulfide
+
+382
+00:33:23,200 --> 00:33:29,060
+bond الان كيف يتحول
+
+383
+00:33:29,060 --> 00:33:34,800
+الشعر من شكل إلى آخر خلينا نعملها ربما بالجلم
+
+384
+00:33:34,800 --> 00:33:44,260
+بتحبوا نبدأ بإيش؟ بشعر straight ونخليه curly الان
+
+385
+00:33:44,260 --> 00:33:52,020
+هذه الشعره straight هذه الشعره إيش فيها روابط؟SS
+
+386
+00:33:52,020 --> 00:33:58,460
+نعمل رابطتين او تلاتة الان هذه الروابط بيخليها
+
+387
+00:33:58,460 --> 00:34:03,660
+عدلة طب لو انا بدي اتنيها شعره جوية ايش لازم اعمل
+
+388
+00:34:03,660 --> 00:34:08,800
+في الاول اكسر هدوله عشان هيك بييجوا بيعملوا عملية
+
+389
+00:34:08,800 --> 00:34:14,830
+ايش reductionيعني بيحطوا مادة ع الشعر و بيفركوه
+
+390
+00:34:14,830 --> 00:34:19,670
+بتدخل هذه المادة جوا الشعر فبتضعف الشعره بتصير
+
+391
+00:34:19,670 --> 00:34:23,690
+عملية reduction الان ال reduction لاحظوا معي شو
+
+392
+00:34:23,690 --> 00:34:33,170
+عمل؟ كسر ال di-sulfate خلاها SH SH SH SH و هكذا
+
+393
+00:34:33,170 --> 00:34:43,400
+الان هذه كانت شعره قويةصارت شعرة ضعيفة الآن الشعرة
+
+394
+00:34:43,400 --> 00:34:49,800
+الضعيفة بالمشط مع شوية استشوار ممكن نتنيها واضح؟
+
+395
+00:34:49,800 --> 00:34:57,820
+لأنها ضعيفة وعشان هيك ممكن نخليها بهذا الشكل طبعا
+
+396
+00:34:57,820 --> 00:35:05,960
+أسأتش أسأتش تمت المهمة ولا لأ؟ تمت، هذه الشعرة
+
+397
+00:35:05,960 --> 00:35:12,520
+اللي كانتعدلة إيش صارت؟ إضعيفة بس هذه في الأجارة
+
+398
+00:35:12,520 --> 00:35:19,320
+بتستهلش ميت شكل تستهل بس قداشر؟
+
+399
+00:35:19,320 --> 00:35:26,740
+اشرين تلاتين شكل ليش؟ لأنه إضعيفة بتعاود تعدل ما
+
+400
+00:35:26,740 --> 00:35:31,060
+هو اللي بيعمل منكر بده يكمله إذا إيش الحل عشان
+
+401
+00:35:31,060 --> 00:35:38,820
+نكمل هالقصة؟ إننا نرد بشكل جديد نجويهاعشان بتكون
+
+402
+00:35:38,820 --> 00:35:44,440
+تدفعوا مصارى، بتقولش الواحد الشعر يكون طويل، يصاب،
+
+403
+00:35:44,440 --> 00:35:50,640
+املولو، بعدين روح قدر لجارجع زي ما هو، املاحظين
+
+404
+00:35:50,640 --> 00:35:54,360
+انتوا؟ عشان هيك هذى بيعملولها كمان عملية كيميائية،
+
+405
+00:35:54,360 --> 00:35:58,380
+شو العملية الكيميائية؟ أكسدة مرة تانية ع الشكل
+
+406
+00:35:58,380 --> 00:36:08,260
+الجديد عشان ترجع جوية، لإن هذى ضعيفةهذه ضعيفة،
+
+407
+00:36:08,260 --> 00:36:13,300
+بدنا نحافظ على الشكل الجديد اللي عملناه وعشان هيك
+
+408
+00:36:13,300 --> 00:36:17,440
+اللي انتوا مرات بتسموه مثبت أو غيره ميتي الأكسجين
+
+409
+00:36:17,440 --> 00:36:26,800
+اللي بتبحط اه H2O2 أكسدا فلاحظوا
+
+410
+00:36:26,800 --> 00:36:34,040
+عملية تحويل الشعر من شعر straight إلى curly بتمر
+
+411
+00:36:34,040 --> 00:36:40,610
+بكم عملية؟عمليتين العملية
+
+412
+00:36:40,610 --> 00:36:44,150
+الأولى reduction صارت الشعر القوى ضعيفة
+
+413
+00:36:46,370 --> 00:36:51,770
+ملفوفة بشكل معين وبعدين رديت أكسادتها إذا رجعتها
+
+414
+00:36:51,770 --> 00:36:56,570
+لشكل إيش القوي عشان هيك بتثبت بالشكل الجديد
+
+415
+00:36:56,570 --> 00:37:01,710
+فعمليتين بتتموا على الشعرة عشان تتحول هذا التحول
+
+416
+00:37:01,710 --> 00:37:06,850
+عملية reduction وعملية oxidation الآن لو سألنا أي
+
+417
+00:37:06,850 --> 00:37:14,850
+واحدة فيكم طيب ناس من أفريقيا مثلاشعرهم مجعد، بدهم
+
+418
+00:37:14,850 --> 00:37:19,870
+يخلوه عدل، بدهم يعكسوا كل هذه الدائرة، بدهم يبدأوا
+
+419
+00:37:19,870 --> 00:37:25,430
+بال reduction عكس ال oxidation، reduction، تصير
+
+420
+00:37:25,430 --> 00:37:30,410
+زيك ضعيفة، بعدين بيعدلوها بالاستشوار والنار، بتصير
+
+421
+00:37:30,410 --> 00:37:38,250
+عدلة، فرحوا، بعدين بيأكسدوها، بتصير قوية بالشكل
+
+422
+00:37:38,250 --> 00:37:44,070
+الجديدشوفتوا كيف هذه العملية كلها اذا عمليات قصة
+
+423
+00:37:44,070 --> 00:37:49,010
+الشعر هذه عمليات ايش مالها كيميائية الان هذا تطبيق
+
+424
+00:37:49,010 --> 00:37:54,590
+Biology بس انا بهمش لو سمحتوا خلال دقيقتين هحكيلكم
+
+425
+00:37:54,590 --> 00:38:00,070
+على تطبيق اهم كتير منه كمان يعني هذا تطبيق ترفي
+
+426
+00:38:00,070 --> 00:38:04,770
+لكن في تطبيق في الحياة و بالذات بعض الناس منكم
+
+427
+00:38:04,770 --> 00:38:09,790
+يمكن يتخصصوا في البصريات الطبيةتطبيق كتير مهم
+
+428
+00:38:09,790 --> 00:38:19,290
+بتعرفوا الخشب اللي موجود اليوم ال MDF وغيره لو كان
+
+429
+00:38:19,290 --> 00:38:22,650
+محطوط على الأرض و بيصير أحيانا رطوبة في الأرض و
+
+430
+00:38:22,650 --> 00:38:28,070
+بتشطفه اشي زي هيك شو بيصيله؟ بينفش عارفين هذه
+
+431
+00:38:28,070 --> 00:38:32,350
+الشغلة؟ يعني انه بيكون عندكم الخشبة كأنها طبقات زي
+
+432
+00:38:32,350 --> 00:38:35,810
+هيك مع الرطوبة كيف بتصير؟
+
+433
+00:38:38,140 --> 00:38:43,600
+بتنفش، هذه الفكرة عارفينها؟ كويس، الآن في فكرة
+
+434
+00:38:43,600 --> 00:38:47,960
+موازية لها، في فكرة موازية لها تماما، انه احنا
+
+435
+00:38:47,960 --> 00:38:54,350
+عندنا في القرنية تبعت العلم، هذه تحدوبهايعني كما
+
+436
+00:38:54,350 --> 00:38:59,790
+قال الله تعالى وكل شي عنده بمقدار مش المفروض يختل
+
+437
+00:38:59,790 --> 00:39:04,090
+يعني اتخيلوها انتوا و الامر schematic و تفصيله عند
+
+438
+00:39:04,090 --> 00:39:08,510
+الإخوة التعون البصرية تتخيلوها مثلا بهذا الشكل
+
+439
+00:39:08,510 --> 00:39:13,870
+الآن هذا التحدب خلاص لازم نظلنا ايش احنا ملتزمين
+
+440
+00:39:13,870 --> 00:39:19,800
+فيه هذا في عند انا disulfide bondsيعني أس .. أس ..
+
+441
+00:39:19,800 --> 00:39:26,420
+أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس
+
+442
+00:39:26,420 --> 00:39:26,820
+أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس
+
+443
+00:39:26,820 --> 00:39:29,340
+.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس ..
+
+444
+00:39:29,340 --> 00:39:29,920
+أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس
+
+445
+00:39:29,920 --> 00:39:32,400
+.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس ..
+
+446
+00:39:32,400 --> 00:39:33,340
+أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس
+
+447
+00:39:33,340 --> 00:39:33,680
+.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس ..
+
+448
+00:39:33,680 --> 00:39:44,760
+أس .. أس .. أس .. أس
+
+449
+00:39:44,760 --> 00:39:52,110
+..زي الخشب اللي نفش املاحظين؟ تماما، بهذه الحالة
+
+450
+00:39:52,110 --> 00:39:56,150
+صارت مشكلة في الإبصار ولا لأ؟ صار مشكلة في الإبصار
+
+451
+00:39:56,150 --> 00:40:00,430
+طيب يا تورا لو بدنا نعالج هذه المشكلة في الإبصار،
+
+452
+00:40:00,430 --> 00:40:07,310
+شو بدنا نعمل؟ بمنطق الكيميا بدأ
+
+453
+00:40:07,310 --> 00:40:12,490
+أعمل أكسدةبدي أرجح هذه لهذه بدي أكوّن الـ
+
+454
+00:40:12,490 --> 00:40:17,450
+disulfide bonds ولذلك أنا لما بدي أعالج هاي حالة
+
+455
+00:40:17,450 --> 00:40:21,850
+المرض و هاي حالة السليم لما بدي أعالج المريض أرجعه
+
+456
+00:40:21,850 --> 00:40:26,990
+لسليم إيش بدي أعمل؟ Oxidation هذه من العمليات
+
+457
+00:40:26,990 --> 00:40:30,410
+الحديثة اللي تجرى و كمان تجرى في غزة غالبا بتاعة
+
+458
+00:40:30,410 --> 00:40:33,890
+اللي بيستعملوا ال ozone كعمل مؤكسد مع أشياء تقنية
+
+459
+00:40:33,890 --> 00:40:39,230
+كاملة بس الإنسان يكون فاهم إيشال general idea
+
+460
+00:40:39,230 --> 00:40:43,670
+الفكرة العامة الفكرة العامة انه داي سالفايد بتصير
+
+461
+00:40:43,670 --> 00:40:49,230
+ايش ثيول بطل الشكل المنتظم القرنية و ما إلى ذلك
+
+462
+00:40:49,230 --> 00:40:54,390
+لما ارد أعمل الأكسة ده بيرجع الثيول إلى داي
+
+463
+00:40:54,390 --> 00:40:59,830
+سالفايد رجعتهازي ما كانت، فالأفكار البسيطة اللي
+
+464
+00:40:59,830 --> 00:41:05,430
+أحيانا بتمر عليكم يعني ربما أول ما الإنسان بيشرح
+
+465
+00:41:05,430 --> 00:41:08,230
+لما تشوفوا كلمة آسيول
+
+466
+00:41:11,410 --> 00:41:16,530
+ثيول يصير داي سالفايد okay فكرة كيميا لكن الجميل
+
+467
+00:41:16,530 --> 00:41:21,210
+دائما بفكرة الكيميا انها بتتحول لفكرة ايش لفكرة
+
+468
+00:41:21,210 --> 00:41:27,970
+تطبيق ولا فكرة حياة بهيك بننهي chapter ال alcohols
+
+469
+00:41:27,970 --> 00:41:32,430
+ان شاء الله المرة القادمة بنبدأ في موضوع ال ethers
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..24512ba5f9584e23a80a691d856fcec6280af8bc
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4846, "start": 19.78, "end": 48.46, "text": "بسم الله الرحمن الرحيم المرة الماضية اتكلمنا على أكسدة الكحولات عرفنا ايش اللي بنقصده في الأكسدة تحويل ال OH إلى C double bond O من خلال فقط ذاتين هيدروجين ولذلك احنا قلنا ان ال primary alcohol بتأكسد و بصير ال aldehydes و ال secondary alcohol بتأكسد و بصير ال ketones", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 1975, 2655, 4117, 19528, 8315, 15844, 5551, 4117, 3794, 41891, 33251, 5016, 12610, 9307, 6225, 28480, 8315, 1975, 1829, 8592, 13672, 1829, 44945, 4587, 9381, 3215, 3224, 8978, 16247, 4117, 3794, 41891, 6055, 5016, 2407, 26895, 2423, 13931, 30731, 383, 3834, 6086, 422, 9154, 16490, 1211, 6027, 6156, 47432, 29910, 9307, 9957, 8032, 25708, 2288, 29245, 9957, 35525, 8848, 23275, 1975, 5016, 8315, 12174, 1211, 8315, 16472, 2423, 6194, 7658, 39894, 10721, 4117, 3794, 3215, 4032, 4724, 9381, 13546, 2423, 16798, 68, 3495, 14792, 4032, 2423, 11396, 7658, 39894, 10721, 4117, 3794, 3215, 4032, 4724, 9381, 13546, 2423, 14979, 2213], "avg_logprob": -0.15040761102800784, "compression_ratio": 1.7644628099173554, "no_speech_prob": 0.0, "words": [{"start": 19.78, "end": 20.38, "word": "بسم", "probability": 0.92333984375}, {"start": 20.38, "end": 20.56, "word": " الله", "probability": 0.9755859375}, {"start": 20.56, "end": 20.88, "word": " الرحمن", "probability": 0.9659830729166666}, {"start": 20.88, "end": 21.32, "word": " الرحيم", "probability": 0.9921875}, {"start": 21.32, "end": 22.74, "word": " المرة", "probability": 0.928466796875}, {"start": 22.74, "end": 23.1, "word": " الماضية", "probability": 0.951171875}, {"start": 23.1, "end": 23.68, "word": " اتكلمنا", "probability": 0.928125}, {"start": 23.68, "end": 23.92, "word": " على", "probability": 0.67333984375}, {"start": 23.92, "end": 24.46, "word": " أكسدة", "probability": 0.8966064453125}, {"start": 24.46, "end": 25.62, "word": " الكحولات", "probability": 0.9937744140625}, {"start": 25.62, "end": 26.72, "word": " عرفنا", "probability": 0.8839518229166666}, {"start": 26.72, "end": 26.9, "word": " ايش", "probability": 0.6261393229166666}, {"start": 26.9, "end": 27.06, "word": " اللي", "probability": 0.8974609375}, {"start": 27.06, "end": 27.64, "word": " بنقصده", "probability": 0.97841796875}, {"start": 27.64, "end": 27.76, "word": " في", "probability": 0.90771484375}, {"start": 27.76, "end": 28.44, "word": " الأكسدة", "probability": 0.983642578125}, {"start": 28.44, "end": 29.92, "word": " تحويل", "probability": 0.9437255859375}, {"start": 29.92, "end": 30.12, "word": " ال", "probability": 0.95751953125}, {"start": 30.12, "end": 30.6, "word": " OH", "probability": 0.55029296875}, {"start": 30.6, "end": 31.06, "word": " إلى", "probability": 0.755859375}, {"start": 31.06, "end": 31.8, "word": " C", "probability": 0.55810546875}, {"start": 31.8, "end": 31.98, "word": " double", "probability": 0.64501953125}, {"start": 31.98, "end": 32.5, "word": " bond", "probability": 0.94091796875}, {"start": 32.5, "end": 33.2, "word": " O", "probability": 0.88037109375}, {"start": 33.2, "end": 33.58, "word": " من", "probability": 0.986328125}, {"start": 33.58, "end": 33.86, "word": " خلال", "probability": 0.9921875}, {"start": 33.86, "end": 34.22, "word": " فقط", "probability": 0.868408203125}, {"start": 34.22, "end": 34.66, "word": " ذاتين", "probability": 0.7578125}, {"start": 34.66, "end": 35.48, "word": " هيدروجين", "probability": 0.95537109375}, {"start": 35.48, "end": 38.2, "word": " ولذلك", "probability": 0.8816731770833334}, {"start": 38.2, "end": 38.5, "word": " احنا", "probability": 0.94873046875}, {"start": 38.5, "end": 38.86, "word": " قلنا", "probability": 0.84033203125}, {"start": 38.86, "end": 39.06, "word": " ان", "probability": 0.75146484375}, {"start": 39.06, "end": 39.46, "word": " ال", "probability": 0.927734375}, {"start": 39.46, "end": 40.08, "word": " primary", "probability": 0.89111328125}, {"start": 40.08, "end": 40.74, 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Safe", "tokens": [5172, 25957, 1211, 10632, 2423, 16489, 327, 399, 11331, 12610, 2655, 2423, 33369, 394, 32767, 18513, 3660, 6055, 7649, 10632, 6024, 48506, 16472, 2655, 3555, 3224, 14407, 24976, 8315, 3794, 13672, 1829, 4724, 1829, 8592, 2655, 17082, 1211, 14407, 8978, 16247, 17082, 8848, 10632, 13412, 2288, 9566, 43242, 16095, 14739, 29538, 9673, 18513, 3660, 13672, 1829, 41850, 4724, 14851, 25957, 1211, 11296, 33369, 394, 6055, 30544, 19753, 27842, 3660, 4032, 17082, 13546, 8608, 10943, 3660, 12399, 3714, 19913, 3555, 2407, 9566, 49429, 5296, 10721, 22807, 19446, 41850, 48812, 33911, 3660, 15844, 16247, 28820, 12399, 11933, 15730, 29538, 5296, 31377, 2304, 6055, 30544, 11933, 1829, 8592, 22807, 27030], "avg_logprob": -0.1807002336890609, "compression_ratio": 1.6694915254237288, "no_speech_prob": 0.0, "words": [{"start": 1238.1200000000001, "end": 1239.16, "word": "فعملية", "probability": 0.8468017578125}, {"start": 1239.16, "end": 1239.3, "word": " ال", "probability": 0.935546875}, 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تمت لكن تمت على إيش؟ على ال antioxidant مش على اللحوم وال antioxidant تحول إلى مادة غير ضارة وبالتالي ماصارش تأثير هذه فكرة بالظبط ال antioxidants الآن من المواد اللي بتستعمل antioxidants اللي هي ال phenols", "tokens": [5172, 3224, 1211, 35186, 6055, 2288, 7578, 6225, 42213, 10632, 2423, 20118, 64, 11778, 3224, 3714, 10859, 1863, 11082, 34268, 49429, 46811, 2655, 22807, 46811, 2655, 44381, 46811, 2655, 15844, 11933, 1829, 8592, 22807, 15844, 2423, 33369, 394, 37893, 15844, 13672, 5016, 20498, 16070, 33369, 394, 6055, 5016, 12610, 30731, 3714, 18513, 3660, 32771, 13546, 48812, 9640, 3660, 46599, 6027, 2655, 6027, 1829, 19446, 9381, 9640, 8592, 6055, 10721, 12984, 13546, 29538, 6156, 4117, 25720, 20666, 19913, 3555, 9566, 2423, 48767, 6024, 48506, 9154, 9673, 14407, 3215, 13672, 1829, 39894, 14851, 25957, 1211, 48767, 13672, 1829, 39896, 2423, 7279, 19385], "avg_logprob": -0.20157796616601473, "compression_ratio": 1.7882882882882882, "no_speech_prob": 0.0, "words": [{"start": 1270.13, 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antioxidants", "probability": 0.54638671875}, {"start": 1288.95, "end": 1289.91, "word": " الآن", "probability": 0.6649169921875}, {"start": 1289.91, "end": 1290.13, "word": " من", "probability": 0.958984375}, {"start": 1290.13, "end": 1290.81, "word": " المواد", "probability": 0.9453125}, {"start": 1290.81, "end": 1291.27, "word": " اللي", "probability": 0.90087890625}, {"start": 1291.27, "end": 1292.01, "word": " بتستعمل", "probability": 0.97900390625}, {"start": 1292.01, "end": 1292.95, "word": " antioxidants", "probability": 0.54345703125}, {"start": 1292.95, "end": 1293.69, "word": " اللي", "probability": 0.95458984375}, {"start": 1293.69, "end": 1293.87, "word": " هي", "probability": 0.90234375}, {"start": 1293.87, "end": 1294.05, "word": " ال", "probability": 0.919921875}, {"start": 1294.05, "end": 1294.59, "word": " phenols", "probability": 0.777587890625}], "temperature": 1.0}, {"id": 57, "seek": 131507, "start": 1295.07, "end": 1315.07, "text": "يعني لو بتكون تبحثوا في google search مثلا اكتبوا antioxidant بتلاقوه بيكمل الكوفينول و آلاف الأبحاث و المواد بعضها طبيعي و بعضها صناعي يعني مثلا هذا vitamin E لاحظوا فيه هنا مجموعة الفينول ولا لأ", "tokens": [40228, 22653, 45164, 39894, 30544, 6055, 49628, 12984, 14407, 8978, 20742, 3164, 50113, 15040, 1975, 4117, 2655, 3555, 14407, 33369, 394, 39894, 15040, 4587, 2407, 3224, 4724, 1829, 24793, 1211, 33251, 38688, 9957, 12610, 4032, 19753, 15040, 5172, 16247, 49628, 5718, 104, 4032, 9673, 14407, 3215, 45030, 11242, 11296, 23032, 21292, 3615, 1829, 4032, 45030, 11242, 11296, 20328, 8315, 3615, 1829, 37495, 22653, 50113, 15040, 23758, 17163, 462, 20193, 5016, 19913, 14407, 8978, 3224, 34105, 3714, 7435, 2304, 2407, 27884, 27188, 9957, 12610, 49429, 5296, 10721], "avg_logprob": -0.17708333675888763, "compression_ratio": 1.6515151515151516, "no_speech_prob": 0.0, "words": [{"start": 1295.07, "end": 1295.35, "word": "يعني", "probability": 0.681884765625}, {"start": 1295.35, "end": 1295.59, "word": " لو", "probability": 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BHA و BHT فالـ BHA و BHT اللي هي butylated hydroxy anisole و butylated hydroxy toluene are synthetic antioxidants عارفين إيش يعني synthetic", "tokens": [2407, 6225, 18513, 3660, 39894, 47283, 3215, 12602, 2304, 2407, 11622, 37495, 22653, 39894, 15040, 4587, 2407, 11296, 4724, 4117, 2655, 3555, 14407, 363, 4983, 4032, 40342, 51, 6156, 6027, 39184, 363, 4983, 4032, 40342, 51, 13672, 1829, 39896, 457, 5088, 770, 15435, 12876, 364, 271, 4812, 4032, 457, 5088, 770, 15435, 12876, 281, 2781, 1450, 366, 23420, 48767, 6225, 9640, 5172, 9957, 11933, 1829, 8592, 37495, 22653, 23420], "avg_logprob": -0.3180803584200995, "compression_ratio": 1.388235294117647, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1427.98, "end": 1428.92, "word": "و", "probability": 0.12347412109375}, {"start": 1428.92, "end": 1429.4, "word": " عادة", "probability": 0.7981770833333334}, {"start": 1429.4, "end": 1429.92, "word": " بتاخد", "probability": 0.7215169270833334}, {"start": 1429.92, "end": 1430.4, 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"word": " ذلك", "probability": 0.995849609375}, {"start": 2449.23, "end": 2449.77, "word": " لما", "probability": 0.9033203125}, {"start": 2449.77, "end": 2450.11, "word": " ارد", "probability": 0.7097981770833334}, {"start": 2450.11, "end": 2450.59, "word": " أعمل", "probability": 0.8406575520833334}, {"start": 2450.59, "end": 2451.33, "word": " الأكسة", "probability": 0.73150634765625}, {"start": 2451.33, "end": 2451.85, "word": " ده", "probability": 0.9892578125}, {"start": 2451.85, "end": 2452.69, "word": " بيرجع", "probability": 0.9296875}, {"start": 2452.69, "end": 2453.85, "word": " الثيول", "probability": 0.9041748046875}, {"start": 2453.85, "end": 2454.09, "word": " إلى", "probability": 0.689453125}, {"start": 2454.09, "end": 2454.39, "word": " داي", "probability": 0.827880859375}, {"start": 2454.39, "end": 2455.05, "word": " سالفايد", "probability": 0.9857421875}, {"start": 2455.05, "end": 2456.07, "word": " رجعتها", "probability": 0.9874267578125}], "temperature": 1.0}, {"id": 105, "seek": 246823, "start": 2456.91, "end": 2468.23, "text": "زي ما كانت، فالأفكار البسيطة اللي أحيانا بتمر عليكم يعني ربما أول ما الإنسان بيشرح لما تشوفوا كلمة آسيول", "tokens": [11622, 1829, 19446, 25961, 2655, 12399, 6156, 6027, 10721, 5172, 4117, 9640, 29739, 3794, 1829, 9566, 3660, 13672, 1829, 5551, 5016, 1829, 7649, 995, 39894, 29973, 25894, 24793, 37495, 22653, 12602, 3555, 15042, 5551, 12610, 19446, 33688, 1863, 3794, 7649, 4724, 1829, 46309, 5016, 5296, 15042, 6055, 8592, 38688, 14407, 9122, 19528, 3660, 19753, 3794, 1829, 12610], "avg_logprob": -0.1480334115953281, "compression_ratio": 1.532258064516129, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2456.91, "end": 2457.31, "word": "زي", "probability": 0.969482421875}, {"start": 2457.31, "end": 2457.43, "word": " ما", "probability": 0.97607421875}, {"start": 2457.43, "end": 2457.99, "word": " كانت،", "probability": 0.7578125}, {"start": 2457.99, "end": 2459.05, "word": " فالأفكار", "probability": 0.9144694010416666}, {"start": 2459.05, "end": 2459.69, "word": " البسيطة", "probability": 0.9890625}, {"start": 2459.69, "end": 2459.83, "word": " اللي", "probability": 0.839111328125}, {"start": 2459.83, "end": 2460.23, "word": " أحيانا", "probability": 0.9763671875}, {"start": 2460.23, "end": 2460.71, "word": " بتمر", "probability": 0.95068359375}, {"start": 2460.71, "end": 2461.41, "word": " عليكم", "probability": 0.97265625}, {"start": 2461.41, "end": 2462.09, "word": " يعني", "probability": 0.73046875}, {"start": 2462.09, "end": 2462.67, "word": " ربما", "probability": 0.98681640625}, {"start": 2462.67, "end": 2463.97, "word": " أول", "probability": 0.9091796875}, {"start": 2463.97, "end": 2464.09, "word": " ما", "probability": 0.97265625}, {"start": 2464.09, "end": 2464.67, "word": " الإنسان", "probability": 0.991943359375}, {"start": 2464.67, "end": 2465.43, "word": " بيشرح", "probability": 0.9759521484375}, {"start": 2465.43, "end": 2466.01, "word": " لما", "probability": 0.8408203125}, {"start": 2466.01, "end": 2466.57, "word": " تشوفوا", "probability": 0.972900390625}, {"start": 2466.57, "end": 2466.99, "word": " كلمة", "probability": 0.98779296875}, {"start": 2466.99, "end": 2468.23, "word": " آسيول", "probability": 0.436767578125}], "temperature": 1.0}, {"id": 106, "seek": 249242, "start": 2471.41, "end": 2492.43, "text": "ثيول يصير داي سالفايد okay فكرة كيميا لكن الجميل دائما بفكرة الكيميا انها بتتحول لفكرة ايش لفكرة تطبيق ولا فكرة حياة بهيك بننهي chapter ال alcohols ان شاء الله المرة القادمة بنبدأ في موضوع ال ethers", "tokens": [12984, 1829, 12610, 7251, 9381, 13546, 11778, 47302, 8608, 6027, 5172, 995, 25708, 1392, 6156, 4117, 25720, 9122, 32640, 25528, 44381, 25724, 2304, 26895, 11778, 16373, 15042, 4724, 5172, 4117, 25720, 33251, 32640, 25528, 16472, 11296, 39894, 2655, 5016, 12610, 5296, 5172, 4117, 25720, 1975, 1829, 8592, 5296, 5172, 4117, 25720, 6055, 9566, 21292, 4587, 49429, 6156, 4117, 25720, 11331, 25528, 3660, 39627, 1829, 4117, 44945, 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"word": " الجميل", "probability": 0.9254557291666666}, {"start": 2476.53, "end": 2476.97, "word": " دائما", "probability": 0.9142252604166666}, {"start": 2476.97, "end": 2477.51, "word": " بفكرة", "probability": 0.93017578125}, {"start": 2477.51, "end": 2478.19, "word": " الكيميا", "probability": 0.8818359375}, {"start": 2478.19, "end": 2478.63, "word": " انها", "probability": 0.7261962890625}, {"start": 2478.63, "end": 2479.17, "word": " بتتحول", "probability": 0.9549560546875}, {"start": 2479.17, "end": 2479.71, "word": " لفكرة", "probability": 0.9229736328125}, {"start": 2479.71, "end": 2480.13, "word": " ايش", "probability": 0.7814127604166666}, {"start": 2480.13, "end": 2481.21, "word": " لفكرة", "probability": 0.8643798828125}, {"start": 2481.21, "end": 2481.87, "word": " تطبيق", "probability": 0.955322265625}, {"start": 2481.87, "end": 2482.03, "word": " ولا", "probability": 0.455810546875}, {"start": 2482.03, "end": 2482.51, "word": " فكرة", "probability": 0.96875}, {"start": 2482.51, "end": 2484.59, "word": " حياة", "probability": 0.96044921875}, {"start": 2484.59, "end": 2485.51, "word": " بهيك", "probability": 0.6063639322916666}, {"start": 2485.51, "end": 2486.33, "word": " بننهي", "probability": 0.916259765625}, {"start": 2486.33, "end": 2486.75, "word": " chapter", "probability": 0.75537109375}, {"start": 2486.75, "end": 2487.39, "word": " ال", "probability": 0.7509765625}, {"start": 2487.39, "end": 2487.97, "word": " alcohols", "probability": 0.380126953125}, {"start": 2487.97, "end": 2488.05, "word": " ان", "probability": 0.87255859375}, {"start": 2488.05, "end": 2488.25, "word": " شاء", "probability": 0.9443359375}, {"start": 2488.25, "end": 2488.29, "word": " الله", "probability": 0.943359375}, {"start": 2488.29, "end": 2488.63, "word": " المرة", "probability": 0.979248046875}, {"start": 2488.63, "end": 2489.15, "word": " القادمة", "probability": 0.9894205729166666}, {"start": 2489.15, "end": 2489.75, "word": " بنبدأ", "probability": 0.7760416666666666}, {"start": 2489.75, "end": 2489.95, "word": " في", "probability": 0.91552734375}, {"start": 2489.95, "end": 2490.59, "word": " موضوع", "probability": 0.9891357421875}, {"start": 2490.59, "end": 2491.89, "word": " ال", "probability": 0.96240234375}, {"start": 2491.89, "end": 2492.43, "word": " ethers", "probability": 0.566162109375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2493.77675, "duration_after_vad": 2409.8581249999934}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA.srt
new file mode 100644
index 0000000000000000000000000000000000000000..9eb629ba5b9e289a7af47d899637a57c9d080d72
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA.srt
@@ -0,0 +1,1491 @@
+1
+00:00:19,760 --> 00:00:25,420
+بسم الله الرحمن الرحيم نستمر اليوم في موضوع ال
+
+2
+00:00:25,420 --> 00:00:29,040
+carboxylic acids and their derivatives ربما المرة
+
+3
+00:00:29,040 --> 00:00:34,360
+الأخيرة اتكلمنا على تحضير ال acid anhydrides
+
+4
+00:00:34,360 --> 00:00:38,900
+وصنفناهم ل symmetrical anhydride و unsymmetrical
+
+5
+00:00:38,900 --> 00:00:45,240
+anhydrideبالنسبة لتفاعلاتهم، لا يخرجوا عن الإطار
+
+6
+00:00:45,240 --> 00:00:48,380
+العام لتفاعلات الأحماض ومشتقاتها، اللي هو
+
+7
+00:00:48,380 --> 00:00:54,060
+substitution reaction، واضح؟ فعلى سبيل المثال، هذا
+
+8
+00:00:54,060 --> 00:01:00,550
+الـ anhydrideلو اجينا نفعله مثلا مع الميه الميه
+
+9
+00:01:00,550 --> 00:01:04,470
+هتكون ال يوكليوفايل ييجي تهاجم هنا و ينكسر من هذا
+
+10
+00:01:04,470 --> 00:01:09,670
+المكان الان هذا الجزء هيصير acid لو فعلنا مع الميه
+
+11
+00:01:09,670 --> 00:01:13,330
+و هذا الجزء ايضا هياخد الاتش يصير acid بناء على
+
+12
+00:01:13,330 --> 00:01:18,450
+ذلك تفاعل الانهيدريد مع الميه بيرجع الى ايش الى
+
+13
+00:01:18,450 --> 00:01:26,440
+حامضين لو اجينا مثلا نفعل كحولهذا الجزء هيجي عليه
+
+14
+00:01:26,440 --> 00:01:34,340
+بدل OH في حالة الكحون OR هيصير Easter وهذا بيطلع
+
+15
+00:01:34,340 --> 00:01:40,220
+على شكل acid لو جينا الفاعل مع ammonia هذا الجزء
+
+16
+00:01:40,220 --> 00:01:45,870
+هيصير amineان اتش تو مثلا او ان اتش ار هيصير امين
+
+17
+00:01:45,870 --> 00:01:50,310
+وهذا بيطلع على شكل حامض فزي ما بتلاحظوا انه دائما
+
+18
+00:01:50,310 --> 00:01:55,650
+في عندى جزء معين بيطلع على شكل حامض وهذا الجزء
+
+19
+00:01:55,650 --> 00:02:00,910
+اللى هجم عليه النيكليوفايل من الميه لنيكليوفايل OH
+
+20
+00:02:00,910 --> 00:02:05,550
+من الكحول لنيكليوفايل OR من الأمونيا لنيكليوفايل
+
+21
+00:02:05,550 --> 00:02:12,930
+NH2 وبالتالي ممكن ارجعلل acid ل ال E star ل الأمد
+
+22
+00:02:12,930 --> 00:02:18,710
+و هكذا هذا مثال تطبيقي اللي موجود عندنا هنا كيف
+
+23
+00:02:18,710 --> 00:02:25,210
+نحضر الأسبيرين واضح؟ كيف نحضر الأسبيرين ربما سبق
+
+24
+00:02:25,210 --> 00:02:29,010
+مار معنا ان احنا بننطلق من ال salicylic acid
+
+25
+00:02:29,750 --> 00:02:34,110
+الساليسليك أسد اللى هو الحامض ال بنزويك أسد اللى
+
+26
+00:02:34,110 --> 00:02:40,950
+على موقع ألفا منه OH فهو على موقع أورثو منه OH فهو
+
+27
+00:02:40,950 --> 00:02:46,430
+أورثو هيدروكسي بنزويك أسد واسمه ساليسليك أسد وزي
+
+28
+00:02:46,430 --> 00:02:50,970
+ما اتفقنا لازم تكونوا عارفينه سواء قولنا أورثو
+
+29
+00:02:50,970 --> 00:02:58,920
+هيدروكسي بنزويك أسدهذا ال name ايوبك الان لو بدكم
+
+30
+00:02:58,920 --> 00:03:03,420
+ال common name تبعه ايش salicylic acid الان هذا
+
+31
+00:03:03,420 --> 00:03:09,140
+فيه OH اللي هي تعتبر الكهور من ناحية المبدأ هذا ال
+
+32
+00:03:09,140 --> 00:03:14,040
+OH لما اتهاجل على ال acid anhydride عادة بيفعله مع
+
+33
+00:03:14,040 --> 00:03:18,900
+ال acetic anhydride فهتكسر
+
+34
+00:03:18,900 --> 00:03:25,570
+من هنا الحامضزي كل الأمثلة السابقة وهذا الجزء
+
+35
+00:03:25,570 --> 00:03:30,610
+هييجي اللي هو ممثلا للكحول فكأنه في النهاية اللي
+
+36
+00:03:30,610 --> 00:03:38,410
+صار عندى Easter حقيقة راحظوا R C double bond O O R
+
+37
+00:03:38,410 --> 00:03:43,270
+or A R هذا Easter هذا هو ال Aspirin الآن ال
+
+38
+00:03:43,270 --> 00:03:47,470
+Aspirin عادة بنسميه احنا لأنه حاطينا في هذا
+
+39
+00:03:47,470 --> 00:03:53,740
+المجموع ال acetinAcetyl Salicylic Acid أو أسيتو
+
+40
+00:03:53,740 --> 00:03:56,740
+سالي سيليك أسد هذا اللي بياخد اسم الشهراء
+
+41
+00:03:56,740 --> 00:04:03,080
+الأسبيرين أسيتل أو أسيتو و جزء السالي سيليك أسد
+
+42
+00:04:03,080 --> 00:04:07,260
+فالأسبيرين أسيتل سالي سيليك أسد فانتوا لما بتقرأوا
+
+43
+00:04:07,260 --> 00:04:12,800
+على علب الأدويةسواء كان بتركيز خمسمية ميلي جرام
+
+44
+00:04:12,800 --> 00:04:17,740
+الحبة أو بتركيز المية اللى بيسموها ال baby aspirin
+
+45
+00:04:17,740 --> 00:04:20,640
+اللى بياخدوها الناس اللى عندهم الجلطات و أحيانا
+
+46
+00:04:20,640 --> 00:04:25,740
+الان صاروا يصنعوا منها اعتمدوا تركيز واحد و تمانين
+
+47
+00:04:25,740 --> 00:04:29,300
+لل baby aspirin يعني بدل ما يعملوا ميت ميلي جرام
+
+48
+00:04:29,300 --> 00:04:32,860
+في ال tablet في الحبة لأ بيعملوها واحد و تمانين
+
+49
+00:04:33,360 --> 00:04:37,580
+تمام هتقرؤوا واحد و تمانين ميلي جرام او ميت ميلي
+
+50
+00:04:37,580 --> 00:04:41,620
+جرام Acetyl Salicylic Acid او Acetosalicylic Acid
+
+51
+00:04:41,620 --> 00:04:46,320
+فمعنى ذلك انه فيها هذا المقدار من دوة الاشه
+
+52
+00:04:46,320 --> 00:04:56,140
+الاسبريل من دوة الاسبريل بفر
+
+53
+00:04:56,140 --> 00:04:58,440
+اسبريل بفر اسبريل
+
+54
+00:05:00,950 --> 00:05:06,170
+لأ هو بس بيحاولوا يخففوا من مشاكل تأثيره على
+
+55
+00:05:06,170 --> 00:05:10,370
+المعدة من خلال أنه بيكون مخلوط بنظام ال buffer هو
+
+56
+00:05:10,370 --> 00:05:17,730
+مشكلة الأسبيرين حقيقة أنه الجزء الفعال فيه اللي هو
+
+57
+00:05:17,730 --> 00:05:22,750
+ال salicylic acid نفسه لكن ال salicylic acid نفسه
+
+58
+00:05:22,750 --> 00:05:28,170
+يعني شديد على المعدةفبناء على ذلك هم بيحولوا ل
+
+59
+00:05:28,170 --> 00:05:32,750
+acid ال salicylic acid فلما يمر في المعدة بيمر على
+
+60
+00:05:32,750 --> 00:05:36,130
+شكل acid ال salicylic acid لما ينزل على القمعة في
+
+61
+00:05:36,130 --> 00:05:40,570
+الوسط القلوي بتروح تكسر هادي و بيرجع ل salicylic
+
+62
+00:05:40,570 --> 00:05:45,550
+acidفكل الفكرة و المشاكل اللي يعني مرتبطة في ال
+
+63
+00:05:45,550 --> 00:05:50,590
+Aspirin هي مشاكل التأثير على المعدة، فلما يعملوا
+
+64
+00:05:50,590 --> 00:05:54,990
+coated بنظام معين ولا buffer Aspirin، كله على أساس
+
+65
+00:05:54,990 --> 00:05:58,570
+يخففوا تأثيره على إيش المعدة، بالذات اللي عندهم
+
+66
+00:05:58,570 --> 00:06:02,780
+يعني قرحة متهيجة، مابقدروش ياخدوا ال Aspirinاللي
+
+67
+00:06:02,780 --> 00:06:07,840
+عندهم قرحة متهيجة وغلبة عندهم إشكالية إنهم ياخدوا
+
+68
+00:06:07,840 --> 00:06:11,760
+ال Aspirin فبيحاولوا عاد يعملوا الجرعات الخفيفة
+
+69
+00:06:11,760 --> 00:06:15,000
+ويعملوه coated مثلا في Aspirin بسموه Aspirin
+
+70
+00:06:15,000 --> 00:06:21,140
+Cartia، buffer Aspirin، كل هذا لتقليل إيش؟ تأثيره
+
+71
+00:06:21,140 --> 00:06:22,080
+على المهدة
+
+72
+00:06:24,930 --> 00:06:30,750
+الجزء الأخير في مشتقات الأحماض ال Amides طبعا سبق
+
+73
+00:06:30,750 --> 00:06:34,250
+أنه إحنا عرفنا ال Amides قولنا ال C double bond O
+
+74
+00:06:34,250 --> 00:06:39,770
+اللي جنبها نيتروجين، الآن بهمش، بدناش نظل نقول
+
+75
+00:06:39,770 --> 00:06:44,660
+اللي جنبها ال H2لأ بدنا نغير كلامنا شوية نقول اللي
+
+76
+00:06:44,660 --> 00:06:51,140
+جنبها nitrogen اللي جنبها nitrogen تمام؟ الآن هذه
+
+77
+00:06:51,140 --> 00:06:56,020
+ال nitrogen غير إن أنا متصلة بصيدة بال bond O عادة
+
+78
+00:06:56,020 --> 00:07:00,940
+كام رابطة بتعمل؟ تلاتة، تلاتة، تلاتة، تلاتة،
+
+79
+00:07:00,940 --> 00:07:02,120
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+80
+00:07:02,120 --> 00:07:02,440
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+81
+00:07:02,440 --> 00:07:05,140
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+82
+00:07:05,140 --> 00:07:05,920
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+83
+00:07:06,140 --> 00:07:10,760
+بناء على ذلك هدولة ممكن يكونوا H وH ونقول جنبها N
+
+84
+00:07:10,760 --> 00:07:16,380
+H2 ممكن يكونوا H وR وممكن يكونوا R وR يعني مايكونش
+
+85
+00:07:16,380 --> 00:07:21,700
+هيدروجين بالمرة فالأمد سيضة بال point O جنبها N ال
+
+86
+00:07:21,700 --> 00:07:30,660
+N ال N حاملة 2 H بصير الأمد حاملة واحدة H واحدة R
+
+87
+00:07:31,670 --> 00:07:39,450
+برضه بيصير الأمد حاملة تنتين R برضه بيصير واضحة
+
+88
+00:07:39,450 --> 00:07:45,510
+الفكرة؟ الآن ضمن هذا المنطق بيصير في عنده تصنيف
+
+89
+00:07:45,510 --> 00:07:50,590
+لأنواع الأمد بيصير عنده تصنيف لأنواع الأمد يعني
+
+90
+00:07:50,590 --> 00:07:54,750
+لاحظوا ال nitrogen هنا متصلة بكم كاربون لما تكون
+
+91
+00:07:54,750 --> 00:08:00,250
+حاملة H وH؟ بكاربون واحدة إذا هذا الأمد الأخضر إيش
+
+92
+00:08:00,250 --> 00:08:04,480
+بنقول عنه؟primary amide متصلة ب one carbon
+
+93
+00:08:04,480 --> 00:08:10,840
+النيتروجين لو صرت متصلة ب H و ب R يعني ب carbon و
+
+94
+00:08:10,840 --> 00:08:16,410
+من هنا ب carbon ايش بده تكون secondaryوالـ
+
+95
+00:08:16,410 --> 00:08:22,870
+Nitrogen لو كانت متصلة بـ R و بـ R .. بـ Carbon و
+
+96
+00:08:22,870 --> 00:08:26,170
+بـ Carbon و هنا الطبيعة الحالي بـ Carbon هتكون
+
+97
+00:08:26,170 --> 00:08:31,670
+ايش؟ Tertiary بناء على ذلك الأمد بيصير تلت أنواع
+
+98
+00:08:32,490 --> 00:08:38,090
+والأمد بيصير تعريفه العام C double bond O متصلة
+
+99
+00:08:38,090 --> 00:08:44,530
+بإيش؟ بنيتروجين هالنيتروجين هذه تكون NH2 primary
+
+100
+00:08:44,530 --> 00:08:51,150
+أمد NHR secondary أمد NR2 tertiary أمد واضح هذه
+
+101
+00:08:51,150 --> 00:08:56,710
+الفكرة؟ الآن هذه الفكرة طالما احنا وقفنا عندها
+
+102
+00:08:56,710 --> 00:09:04,890
+هتجيبنا لنقطة كتير مهمةالعمل ممكن يعمل hydrogen
+
+103
+00:09:04,890 --> 00:09:11,210
+bonding وممكن مايعملش وممكن يعمل بشكل كبير وممكن
+
+104
+00:09:11,210 --> 00:09:13,830
+يعمل بشكل اقل عارفين انتوا ال hydrogen bonding
+
+105
+00:09:13,830 --> 00:09:18,370
+بيصير لما يكون عندى hydrogen متطابط يا بنيتروجين
+
+106
+00:09:18,370 --> 00:09:23,730
+يا باكسوجين يا بفلورين الان لو اجيت على المركب
+
+107
+00:09:23,730 --> 00:09:31,510
+اللى هو ال primary amine فيه MHو تنتين مش واحدة
+
+108
+00:09:31,510 --> 00:09:36,350
+تمام اذا ال primary amide ممكن يعمل hydrogen
+
+109
+00:09:36,350 --> 00:09:40,430
+bonding ولا لأ و ممكن يعمل كام hydrogen bonding
+
+110
+00:09:40,430 --> 00:09:44,730
+طالما فيه تنتين hydrogen ممكن يعمل two hydrogen
+
+111
+00:09:44,730 --> 00:09:52,550
+bonding الان لو اجيت على ال secondary amide في كام
+
+112
+00:09:52,550 --> 00:09:58,690
+هيدروجينةوحدة إذا ممكن يعمل one hydrogen bonding
+
+113
+00:09:58,690 --> 00:10:04,590
+لو إجيت على ال tertiary amide مش فيه hydrogen إذا
+
+114
+00:10:04,590 --> 00:10:09,030
+بيعملش hydrogen bonding واضحة الفكرة إذا لو أنا
+
+115
+00:10:09,030 --> 00:10:11,450
+بدي أجي أشوف ال amides من ناحية ال hydrogen
+
+116
+00:10:11,450 --> 00:10:17,910
+bonding مين أكثر واحد بيعمل hydrogen bonding بعده
+
+117
+00:10:18,450 --> 00:10:23,970
+بعده tertiary ع طول مباشرة ال hydrogen bonding
+
+118
+00:10:23,970 --> 00:10:29,970
+بنعكس على أي خاصية على ال boiling point بناء على
+
+119
+00:10:29,970 --> 00:10:34,330
+ذلك لما انا بدي اجي احكي عن ال boiling point مين
+
+120
+00:10:34,330 --> 00:10:40,870
+هيكون اعلى boiling point ال primary اعلى من ال
+
+121
+00:10:40,870 --> 00:10:47,330
+secondary اعلى من ال tertiaryالان لو قلنا لكوا ليش
+
+122
+00:10:47,330 --> 00:10:51,010
+ال primary أعلى من ال secondary لأن ال primary فيه
+
+123
+00:10:51,010 --> 00:10:54,250
+تنين هيدروجين bonding السكندرية واحدة ليش
+
+124
+00:10:54,250 --> 00:10:57,710
+السكندرية أعلى من ال tertiary السكندرية فيه
+
+125
+00:10:57,710 --> 00:11:01,430
+إمكانية لوان هيدروجين bonding الترتشيري مافيش فيه
+
+126
+00:11:01,430 --> 00:11:05,450
+إمكانية للهيدروجين bonding فالأمر في ال boiling
+
+127
+00:11:05,450 --> 00:11:10,590
+point ما بين ال primary والسكندرية والترتشيريهو
+
+128
+00:11:10,590 --> 00:11:15,310
+إلى إمكانية تكوين الـ hydrogen bonding واضحة هذه
+
+129
+00:11:15,310 --> 00:11:20,410
+الفكرة كتصنيف amides و كنقاط غليان لاحظوا هذه
+
+130
+00:11:20,410 --> 00:11:28,020
+الفكرة نفسها موجودة هنا مثلالو انا اتطلعت على
+
+131
+00:11:28,020 --> 00:11:31,760
+الامد و كلكم اتذكرين انه احنا بالنسبة للامد لما
+
+132
+00:11:31,760 --> 00:11:35,920
+سبق المرة الماضية اتكلمنا عن تسميته قولنا بنيجي
+
+133
+00:11:35,920 --> 00:11:40,380
+بنشوف ايش اسم الحامض الاصلي و بنشيل oic acid و
+
+134
+00:11:40,380 --> 00:11:45,140
+بنكتب بدالها امد يعني هذا الحمض واحد اتنين تلاتة
+
+135
+00:11:45,140 --> 00:11:51,860
+كان بروبانوك اسد بيصير بروبان امد هذا الحمض لما
+
+136
+00:11:51,860 --> 00:11:58,300
+يكون OH بنزوك اسد بيصير بنز امدحمد و هكذا واضح
+
+137
+00:11:58,300 --> 00:12:03,540
+الفكرة؟ الأن لو مثلا اتيت على هذا المركب C double
+
+138
+00:12:03,540 --> 00:12:08,160
+bond O اللي حامل H هذا أبسط حامد في الدنيا لإن لو
+
+139
+00:12:08,160 --> 00:12:13,020
+هذه كانت OH بيكون Formic Acid بناء على ذلك من
+
+140
+00:12:13,020 --> 00:12:18,500
+Formic Acid من Formic Acid لما أعمل حامد Primer شو
+
+141
+00:12:18,500 --> 00:12:25,940
+هسميه؟ Formamideطيب يا ترى لو إجيت شيلت واحدة من
+
+142
+00:12:25,940 --> 00:12:30,820
+الهيدروجينات و بدلتها بمثل يعني عملت هيك C double
+
+143
+00:12:30,820 --> 00:12:38,420
+bond OH و هذه N خليت عليها هيدروجين و الهيدروجين
+
+144
+00:12:38,420 --> 00:12:41,320
+التاني ايه شو خليتها CH3
+
+145
+00:12:46,710 --> 00:12:51,830
+هذا امد جاي من ال form امد لكن هذا form امد صار
+
+146
+00:12:51,830 --> 00:12:58,870
+بيحمل ايش مثل اذا بسمي انا مثل form امد لاحظوا
+
+147
+00:12:58,870 --> 00:13:05,390
+form امد ال primary لان لما حمل مثل واحدة ايش صار
+
+148
+00:13:05,390 --> 00:13:13,610
+مثل form امد اللي هو secondary امدالآن، لو بعدك
+
+149
+00:13:13,610 --> 00:13:18,290
+حملتوا مثل مجموعات، فهي تصبح دائمة في الـ
+
+150
+00:13:18,290 --> 00:13:22,980
+Formamentواضح؟ إذا ممكن يكون form amide بدون ولا
+
+151
+00:13:22,980 --> 00:13:28,160
+مثل بمثل واحدة مثل form amide ب two methyl groups
+
+152
+00:13:28,160 --> 00:13:33,660
+ضاي مثل form amide الان لأن هالمثل بتحمل على ال
+
+153
+00:13:33,660 --> 00:13:39,640
+nitrogen مرات بيضيفوا و مرات لأ الحرف capital N
+
+154
+00:13:39,640 --> 00:13:43,980
+يعني هنا بيكتبوا أن مثل form amide إيش معناها؟
+
+155
+00:13:43,980 --> 00:13:47,880
+معناها أن المثل محمول على ذرة ال nitrogen هاي
+
+156
+00:13:47,880 --> 00:13:53,630
+معناه أنواضح؟ طبعا هذا اللي فيه مجموعتين مثل على
+
+157
+00:13:53,630 --> 00:13:59,210
+ذرة النيتروجين شو هسميه؟ N فاصلة N
+
+158
+00:13:59,210 --> 00:14:03,570
+-dimethylformamide يعني المثل الأولى والمثل
+
+159
+00:14:03,570 --> 00:14:08,010
+التانية محمولات على ذرة إيش؟ النيتروجين الآن
+
+160
+00:14:08,010 --> 00:14:12,170
+لاحظوا كيف التدرج ال primary amyl formamide ال
+
+161
+00:14:12,170 --> 00:14:16,800
+secondary مثلا المثل formamide ال tertiaryالداي
+
+162
+00:14:16,800 --> 00:14:22,500
+مثل فورماميل، مين بنتوقعه أعلى boiling point
+
+163
+00:14:22,500 --> 00:14:28,400
+لبرايماري، لاحظوا ال boiling point تبعته 210، الآن
+
+164
+00:14:28,400 --> 00:14:33,960
+مين أقل boiling point؟ ال boiling point تبعته 153
+
+165
+00:14:35,590 --> 00:14:39,390
+ال secondary where بيجي؟ في النص حيجي حوالي مية و
+
+166
+00:14:39,390 --> 00:14:43,190
+سبعين، مية و تمانين، شغل زي هيك، شفتوا التدرج؟
+
+167
+00:14:43,190 --> 00:14:46,730
+ميتين و عشرة، مية و سبعين، مية و تمانين، مية و
+
+168
+00:14:46,730 --> 00:14:50,290
+تلاتة و خمسين، ال primary؟ بتنين هيدروجين بولنج،
+
+169
+00:14:50,290 --> 00:14:53,570
+ال secondary one؟ تير شر بدون هيدروجين بولنج،
+
+170
+00:14:53,570 --> 00:14:58,000
+واضحة؟نفس الاشي مثلا هذا ال acetamide ال primary
+
+171
+00:14:58,000 --> 00:15:01,540
+ال di-methyl acetamide او ال un-di-methyl
+
+172
+00:15:01,540 --> 00:15:06,300
+acetamide ال tertiary مش رسمي هنا ال secondary هذا
+
+173
+00:15:06,300 --> 00:15:11,020
+ال primary مائتين و اتنين و عشرين الآن ال tertiary
+
+174
+00:15:11,020 --> 00:15:15,060
+
+
+223
+00:19:34,900 --> 00:19:37,600
+ال aldehydes في ال ketones في ال acids في ال E
+
+224
+00:19:37,600 --> 00:19:42,610
+stars very reactive واضح؟والـ Nitrogen لواحدة الـ
+
+225
+00:19:42,610 --> 00:19:48,870
+NH2 و الـ NH3 برضه very reactive و هندرس عليها
+
+226
+00:19:48,870 --> 00:19:55,510
+شبتر 11 فالـ C double bond O very reactive و درسنا
+
+227
+00:19:55,510 --> 00:19:57,990
+عليها شبتر ال aldehydes و ال ketones و ال acids
+
+228
+00:19:57,990 --> 00:20:00,990
+شبتر 9 و 10 كله مع ال C double bond O من كتر مية
+
+229
+00:20:00,990 --> 00:20:06,470
+reactive الـ NH very reactive ندرس عليها شبتر 11
+
+230
+00:20:06,470 --> 00:20:13,290
+ال amines الآن يوم ما بنحطالـ c double bond o ال
+
+231
+00:20:13,290 --> 00:20:19,710
+very reactive مع ال n h ال very reactive بنحصل
+
+232
+00:20:19,710 --> 00:20:24,250
+منهم على very
+
+233
+00:20:24,250 --> 00:20:31,490
+very reactive ولا إيش رأيكم؟ بنحصل منهم على
+
+234
+00:20:31,490 --> 00:20:36,970
+unreactive بنحصل
+
+235
+00:20:36,970 --> 00:20:39,610
+منهم على unreactive
+
+236
+00:20:41,050 --> 00:20:48,450
+الـ A يمكن تستغربه كيف ال reactive و ال reactive
+
+237
+00:20:48,450 --> 00:20:50,130
+بيعطوا
+
+238
+00:20:51,590 --> 00:20:58,010
+unreactive لكن اللي بيفهم الدنيا بيقدر يفهم هذا
+
+239
+00:20:58,010 --> 00:21:01,790
+الأمر جيدا اللي بيفهم الدنيا بيقدر يفهم هذا الأمر
+
+240
+00:21:01,790 --> 00:21:08,590
+جيدا ال reactivity ال reactivity معناها تفاعل مع
+
+241
+00:21:08,590 --> 00:21:14,540
+الخارج ال reactivity تفاعل مع الخارج تماميعني
+
+242
+00:21:14,540 --> 00:21:20,100
+الأمة العربية .. الأمة العربية كان ممكن تكون
+
+243
+00:21:20,100 --> 00:21:27,210
+reactive بس بشرط reactive ضد مينضد أعداءها الأمة
+
+244
+00:21:27,210 --> 00:21:30,730
+العربية ممكن تكون reactive و very reactive ضد
+
+245
+00:21:30,730 --> 00:21:35,810
+أعداءها اليوم لما صارت الأمة العربية في كل دولة
+
+246
+00:21:35,810 --> 00:21:40,390
+فيها و ما بين الدول بعد هيك في كل دولة في شق
+
+247
+00:21:40,390 --> 00:21:45,550
+reactive و شق reactive هدول الشقين طبق تالف بعض
+
+248
+00:21:45,550 --> 00:21:53,710
+كيف صفيه مع الخارج? unreactive يعني في اليمنجدّاش
+
+249
+00:21:53,710 --> 00:21:57,550
+بتجتلوا في بعض هو هذا الاقتلا والجبال الإسرائيل
+
+250
+00:21:57,550 --> 00:22:02,290
+ماجدرتش عليهم بس المشكلة ان ال reactivity مش مع
+
+251
+00:22:02,290 --> 00:22:08,950
+الخارج reactivity ايش داخلية فما بالكوا لما نجيبها
+
+252
+00:22:08,950 --> 00:22:15,410
+ايديك ايش نقول اليمن و السعودية تبقوا معاه هنا في
+
+253
+00:22:15,410 --> 00:22:18,510
+reactivity و هنا في reactivity ايش هت مع بعض دمرت
+
+254
+00:22:18,510 --> 00:22:24,610
+بعض طب مع الخارجضد الأعداء الحقيقيين، إيش بنصفة؟
+
+255
+00:22:24,610 --> 00:22:29,650
+Unreactive ولذلك لما جمعنا هنا ال reactive و ال
+
+256
+00:22:29,650 --> 00:22:35,350
+reactive صاروا إيش؟ يتقاتلوا مع بعض فمع الخارج
+
+257
+00:22:35,350 --> 00:22:41,230
+بطلوا reactive الآن هذا الكلام بدنا نفهمه أكتر من
+
+258
+00:22:41,230 --> 00:22:47,910
+ناحية إيش؟ الكيميا بدنا نقول وين سر قوة شمشوم
+
+259
+00:22:47,910 --> 00:22:53,530
+الجبارعارفينه شمشوم الجباب؟ اللي في الأسطورة بطل
+
+260
+00:22:53,530 --> 00:23:00,670
+غزة اللي كان سر قوته في شعره و لما اكتشفوا سر قوته
+
+261
+00:23:00,670 --> 00:23:06,230
+بيكسر المباني و بيعمل .. حلقوله شعره راح فقد قوته،
+
+262
+00:23:06,230 --> 00:23:10,470
+تمام؟ الآن لو اجينا على ال الديهيد و الكيتون، وين
+
+263
+00:23:10,470 --> 00:23:15,530
+سر قوتهم اللي لنا تلت أسابيع نشتغل عليه؟ الكربون
+
+264
+00:23:15,530 --> 00:23:16,770
+المجاباة
+
+265
+00:23:18,720 --> 00:23:22,220
+الـ Carbon الموجبة مشغول من التفاعلات الـ
+
+266
+00:23:22,220 --> 00:23:25,220
+Eucleophilic Addition أو Substitution، الـ
+
+267
+00:23:25,220 --> 00:23:28,980
+Eucleophile إجراء بيجي وين؟ على الـ Carbon
+
+268
+00:23:28,980 --> 00:23:34,440
+الموجبة، هاي سر قوتهم، وعشان يقم لما ييجي الـ
+
+269
+00:23:34,440 --> 00:23:39,490
+Eucleophile من الخارجيحمل أزواج إلكتروناتي جراي
+
+270
+00:23:39,490 --> 00:23:43,550
+بيجي بتفعل معاهم صاروا reactive معاه ولا لأ؟ صاروا
+
+271
+00:23:43,550 --> 00:23:51,130
+reactive طيب لو أجينا للـ nitrogen وين سر قوتها؟
+
+272
+00:23:51,130 --> 00:23:55,950
+زوج الإلكترونات هنا
+
+273
+00:23:55,950 --> 00:24:02,920
+في عندي على ال nitrogen زوج إلكتروناتهذا سير قوتها
+
+274
+00:24:02,920 --> 00:24:07,940
+أول ما بيلاقي أي موجة بجزئه بروح بتفاعل معاه ولا
+
+275
+00:24:07,940 --> 00:24:12,600
+لأ هاي سير قوة ال nitrogen زوج الإلكترونات يعني
+
+276
+00:24:12,600 --> 00:24:20,480
+مثلا أذكر لما كنا نقول فعله المركبين القاتين RNH2
+
+277
+00:24:20,480 --> 00:24:26,620
+زائد CH3 نكتبها زي هيك
+
+278
+00:24:37,980 --> 00:24:45,440
+النيتروجين عليها زوج إلكتروناتصح و ال carbon و
+
+279
+00:24:45,440 --> 00:24:50,320
+اليود مين فيهم موجب و مين سالب ال carbon الموجبة
+
+280
+00:24:50,320 --> 00:24:55,280
+ال a التفاعل موجب مع سالب إجراء هذا زوج
+
+281
+00:24:55,280 --> 00:24:59,620
+الإلكترونات بييجي بيهاجمها و بيطرد اليود صار سر
+
+282
+00:24:59,620 --> 00:25:05,240
+عندك CH3 NHR
+
+283
+00:25:05,240 --> 00:25:13,880
+مظبوط ولا لأ فهي سر القوةزوج الالكترونات هذا سير
+
+284
+00:25:13,880 --> 00:25:18,200
+قوته الموجب الموجب مع السالب هاي التفاعلات هاي
+
+285
+00:25:18,200 --> 00:25:23,760
+الكيميا موجب وسالب واضح فالان النيتروجين سير قوته
+
+286
+00:25:23,760 --> 00:25:27,860
+السالب او زوج الالكترونات والكربون سير قوته الموجب
+
+287
+00:25:27,860 --> 00:25:35,790
+لما قعدوا في نفس الجزءبدل ما يروحوا يتفاعلوا ال
+
+288
+00:25:35,790 --> 00:25:40,330
+nitrogen برا يكون reactive برا وال carbon برا يكون
+
+289
+00:25:40,330 --> 00:25:45,050
+reactive برا قال انت سالب شو بدك؟ وانت موجب شو
+
+290
+00:25:45,050 --> 00:25:52,320
+بدك؟ طب هيوموجودين جانب بعض بناء على ذلك إجراء هذا
+
+291
+00:25:52,320 --> 00:25:57,760
+السالب إجا قالوا هاي المجاب شو بدك؟ قالوا أنا
+
+292
+00:25:57,760 --> 00:26:03,160
+السالب اتفضل أعطاه الإلكترونات تبعه طبعا معقول إنه
+
+293
+00:26:03,160 --> 00:26:08,160
+هنا يصير في عندي خمس روابط على الكربون على طول هذه
+
+294
+00:26:08,160 --> 00:26:13,740
+إيش هتصير؟ تلوف الإلكترونات تصير O minus صار بهذا
+
+295
+00:26:13,740 --> 00:26:18,830
+الشكل الرزوناسيالان اتطلعوا على هذا الجزء هل
+
+296
+00:26:18,830 --> 00:26:24,250
+ياترال كاربول ضال عليها موجب؟ هل ال نيتروجين ضال
+
+297
+00:26:24,250 --> 00:26:29,250
+عليها زوج إلكترونات؟ راحوا القوتين ولذلك بيصف
+
+298
+00:26:29,250 --> 00:26:34,750
+القامد او ال reactif لأنه اتفاعل مع نفسه يعني زي
+
+299
+00:26:34,750 --> 00:26:38,410
+اللي في داخل الأمة جاتلوا مع بعض قدام الناس إيش
+
+300
+00:26:38,410 --> 00:26:44,710
+بيطلعوا؟ ولا إشيقدام الغروب، شو بيطلعوا؟ ولا إشي،
+
+301
+00:26:44,710 --> 00:26:48,630
+هم خلاص اتفاعلوا مع بعضهم، اتقاتلوا مع بعضهم،
+
+302
+00:26:48,630 --> 00:26:54,070
+واضحة الفكرة؟ ولذلك السبب إن الامد unreactive هو
+
+303
+00:26:54,070 --> 00:26:59,230
+إيش؟ الامد resonance، لا ضال هذا السالب سالب ولا
+
+304
+00:26:59,230 --> 00:27:04,250
+ضال هذا الموجب موجبفسر القوة للتانين انتهى، راحوا،
+
+305
+00:27:04,250 --> 00:27:08,770
+بطلوا، سالب و موجب، الآن خليني أسأل عادي السؤال من
+
+306
+00:27:08,770 --> 00:27:14,910
+زاوية تانية، هل يترى الأمد لما بيكون unreactive؟
+
+307
+00:27:14,910 --> 00:27:20,490
+يعتبر الأمر شيء إيجابي ولا شيء سلبي؟
+
+308
+00:27:22,790 --> 00:27:29,350
+أحنا اتفقنا القامت unreactive هل يعتبر سلبي ولا
+
+309
+00:27:29,350 --> 00:27:36,410
+إيجابي؟ فينا زملائكوا بيقولوا كل شيء زي السكينة
+
+310
+00:27:36,410 --> 00:27:43,570
+ممكن تكون كويسة وممكن تكون مش كويسة حسب الاستخدام
+
+311
+00:27:43,570 --> 00:27:49,430
+زي ال internetممكن يكون مفيد، ممكن يكون إيش، بقى
+
+312
+00:27:49,430 --> 00:27:54,330
+حسب الاستخدام، يعني على سبيل المثال النيلون
+
+313
+00:27:56,280 --> 00:28:01,240
+عبارة عن أمد، هنشوف كيف بتحضر، بس الآن أقل تقدير
+
+314
+00:28:01,240 --> 00:28:06,620
+نعرف إن النيلون إيش أمد، وبناء على ذلك النيلون
+
+315
+00:28:06,620 --> 00:28:11,760
+reactive ولا unreactive؟ النيلون unreactive، الآن
+
+316
+00:28:11,760 --> 00:28:15,260
+كون النيلون unreactive، هذا الأمر يعتبر موجب ولا
+
+317
+00:28:15,260 --> 00:28:22,900
+ثاني؟يحتمل الأمرين، يعني لما النيلون بيكون عبارة
+
+318
+00:28:22,900 --> 00:28:27,900
+عن قمامة و بدنا نتخلص منها لو دفنناها أو ما إلى
+
+319
+00:28:27,900 --> 00:28:33,540
+ذلك، بتتحلل ولا بتظل زي ما هي بالأرض؟ بتظل زي ما
+
+320
+00:28:33,540 --> 00:28:38,320
+هي بالأرض، مابتتحللشخدوا مثلا فضلات النبات غير
+
+321
+00:28:38,320 --> 00:28:41,500
+غيرها، ادفنوها في الأرض، بتتحللوا، بتروح، ادفنوا
+
+322
+00:28:41,500 --> 00:28:45,180
+نيلون في الأرض، بتتحللش، وبناء على ذلك، كونوا
+
+323
+00:28:45,180 --> 00:28:49,040
+الـnylon unreactive من هذه الزاوية، من زاوية
+
+324
+00:28:49,040 --> 00:28:56,590
+كفضلاتيعتبر الأمر غير جيد، يعتبر الأمر سلبي، لكن
+
+325
+00:28:56,590 --> 00:29:01,530
+نفس النيلون هذا، نفس النيلون هذا، لو أنا كنت بدي
+
+326
+00:29:01,530 --> 00:29:06,890
+فعلا يظل في الرمل وما يخربش، يعني على سبيل المثال،
+
+327
+00:29:06,890 --> 00:29:11,910
+الحمامات الزراعية مش بيعملوها بنيلون، النيلون هذا
+
+328
+00:29:11,910 --> 00:29:17,750
+تحت، بطم فوقه رمل ولا لأ؟بعد شهر، شهرين، تلاتة،
+
+329
+00:29:17,750 --> 00:29:22,170
+أربعة، بدوب النيلون ولا بيظله موجود؟ اتخيل لو هذا
+
+330
+00:29:22,170 --> 00:29:29,670
+كان ورق، ورق وحطينا فوقه رمل، رمل وميه، بعد كدهش
+
+331
+00:29:29,670 --> 00:29:36,030
+بنتهي؟ بعد ساعة، النيلون الآن أنا بديه يظلهلما
+
+332
+00:29:36,030 --> 00:29:39,510
+ظلوا بهذا الشكل وكانوا unreactive، كان يعتبر أمر
+
+333
+00:29:39,510 --> 00:29:43,950
+إيش؟ إيجابي بالنسبة لي، ولذلك مثلا لما بيعملوا
+
+334
+00:29:43,950 --> 00:29:49,400
+كوابل الكهربا مدفونة في الأرضبيجوا فوق الكابل بنص
+
+335
+00:29:49,400 --> 00:29:52,880
+متر، يعني افترض الكابل مدفون على عمق متر، فوق
+
+336
+00:29:52,880 --> 00:29:56,860
+الكابل بنص متر، بيجيبوا شريط نايلون و بيحطوه في
+
+337
+00:29:56,860 --> 00:30:01,200
+الأرض، هذا الشريط مكتوب عليه احذر خطر الكهرباء،
+
+338
+00:30:01,200 --> 00:30:05,540
+احذر خطر الكهرباء، ليش؟ لو اجوا ناس يجرفوا، بعد
+
+339
+00:30:05,540 --> 00:30:09,680
+شوية الجرفة تخبط في كابل كهربا مدفون في الأرضبناء
+
+340
+00:30:09,680 --> 00:30:13,620
+على ذلك بيحطولهم نايلون أصفر و مكتوب عليه شريط فوق
+
+341
+00:30:13,620 --> 00:30:17,560
+الكابل احذر على عمق متر فيه عندك قطر كربا هذا
+
+342
+00:30:17,560 --> 00:30:23,210
+بيقعد عشر خمس عشر سنة وأكترالان هذا استعمال إيجابى
+
+343
+00:30:23,210 --> 00:30:27,970
+ولا سلبى لل unreactivity تبعته استعمال إيجابى
+
+344
+00:30:27,970 --> 00:30:32,470
+ففكرة ال unreactivity أو ال reactivity يمكن ان
+
+345
+00:30:32,470 --> 00:30:38,030
+ينظر إليها من زاويتين و كذلك ال nylon لما بقول عنه
+
+346
+00:30:38,030 --> 00:30:42,050
+عبارة عن أمد و unreactive مرات انا بدي اكون
+
+347
+00:30:42,050 --> 00:30:45,850
+unreactive باستفيد من كونه unreactive ان ال nylon
+
+348
+00:30:45,850 --> 00:30:50,450
+مابخربش و بحمل فيه الغرابو عند اللزوم اليوم اللي
+
+349
+00:30:50,450 --> 00:30:55,970
+بيشتريوا الأشتال الصغيرة كلها محطوطة بإيش؟ بكياس
+
+350
+00:30:55,970 --> 00:31:00,650
+نيلون ولا بكياس ورق؟الان هذا استعمال إيجابي ولا
+
+351
+00:31:00,650 --> 00:31:04,670
+سلبي؟ استعمال إيجابي، انه unreactive، انه ماخربش
+
+352
+00:31:04,670 --> 00:31:09,350
+من الميه والحرارة، واضح؟ لكن أنا لما بحط قمامة و
+
+353
+00:31:09,350 --> 00:31:12,690
+بدي أدفنها و بديها تتحول إلى سماد عضوى، و أجي
+
+354
+00:31:12,690 --> 00:31:16,390
+ألاقي النيلول زي ما هو، و أبدأ أضطر أروح أحرجه و
+
+355
+00:31:16,390 --> 00:31:20,970
+أطلع منه مواد ضارة، و أجي تبكي و أروح اتعلق؟السلبي
+
+356
+00:31:20,970 --> 00:31:25,290
+من أن الامد إيش ماله؟ Unreactive فهمنا إذا فكرة ال
+
+357
+00:31:25,290 --> 00:31:29,190
+reactivity of امد في كل الأحوال لما احنا بنقول إشي
+
+358
+00:31:29,190 --> 00:31:34,690
+unreactive مش معناه صيرنا جايبين سيرة النيلون شو
+
+359
+00:31:34,690 --> 00:31:40,110
+هو النيلون؟ النيلون عبارة عن امد بوليمر بسيط جدا
+
+360
+00:31:40,110 --> 00:31:47,680
+بحط هذا المركب اللي فيه C double bond OCLو ست
+
+361
+00:31:47,680 --> 00:31:53,040
+كربونات يعني كربون تنتين تلاتة أربعة خمسة ستة الان
+
+362
+00:31:53,040 --> 00:31:57,840
+هذا أصلا حامض داي أسد من ست كربونات بتذكرين قولنا
+
+363
+00:31:57,840 --> 00:32:02,680
+إيش اسمه اديبك أسد المرة الماضية الحمض اللي هو
+
+364
+00:32:02,680 --> 00:32:07,250
+الدي أسد من ست كربونات لو فعلنا معك لوربدو يصير
+
+365
+00:32:07,250 --> 00:32:10,810
+أديبويل كلورايد زي ما قولنا المرة الماضية
+
+366
+00:32:10,810 --> 00:32:15,010
+بروبانويل كلورايد وكذا كذا كذا الآن هي أديبويل
+
+367
+00:32:15,010 --> 00:32:19,710
+كلورايد يمين و أديبويل كلورايد الشمال بجيب أمين
+
+368
+00:32:19,710 --> 00:32:27,210
+NH2 6 كربونات و كمان NH2 لما أعمل تفاعل بينهم ال
+
+369
+00:32:27,210 --> 00:32:35,210
+nitrogen هذا ايش بدي اعمل احل محلالكلور هيعمل عندى
+
+370
+00:32:35,210 --> 00:32:43,770
+C double bond O and H واضح الفكرة و هكذا و من هنا
+
+371
+00:32:43,770 --> 00:32:47,670
+هيصير عندى كمان C double bond O and H هيصير عندى
+
+372
+00:32:47,670 --> 00:32:50,610
+polymer يعني هى ست كربونات جايين من الادبويل
+
+373
+00:32:50,610 --> 00:32:55,640
+الكلوراي ستة جايين من إيش؟من الداي أمين الأمين من
+
+374
+00:32:55,640 --> 00:32:58,640
+الجهتين والأدي بويل الكلورايد من الجهتين بيظلوا
+
+375
+00:32:58,640 --> 00:33:03,300
+ميشبكوا مع بعض ولا لأ عملوا معي بوليمر الآن هذا
+
+376
+00:33:03,300 --> 00:33:08,620
+البوليمر موصول من وين من خلال رابطة أمد لإن عندي
+
+377
+00:33:08,620 --> 00:33:15,480
+ال C double bond O and H لاحظوا هنا كام كربونا ستة
+
+378
+00:33:16,560 --> 00:33:21,040
+مع ال سيطة بالبوند او التنتين و CH2 الستة و هنا كم
+
+379
+00:33:21,040 --> 00:33:26,500
+كربونا غير ال نيتروجين اذا انا عندى رابطة الامد و
+
+380
+00:33:26,500 --> 00:33:34,960
+ست كربونات و بعدين رابطة امد تانية و ست كربونات و
+
+381
+00:33:34,960 --> 00:33:41,020
+هلما طالما ستة امد ستة امد ستة امد ستة امد هذا
+
+382
+00:33:41,020 --> 00:33:46,610
+النيلون ايش هنسميه في هذه الحالةنيلون بوليمر طبعا
+
+383
+00:33:46,610 --> 00:33:56,050
+بيسموه نيلون 6 6 لأن هنا 6 كربونات أمد و 6 كربونات
+
+384
+00:33:56,050 --> 00:34:01,740
+من الأمينستة من الاديبويل الكلورايت و ستة من
+
+385
+00:34:01,740 --> 00:34:06,540
+الأمين و بينهم رابطة ايش امل فنيلون سيكس سيكس الان
+
+386
+00:34:06,540 --> 00:34:10,180
+بيصير السؤال لو يا ترى استعملوا الأمين ب تمان
+
+387
+00:34:10,180 --> 00:34:17,150
+كربونات ايش هيصير النيلون six eightلأ مش الانتين
+
+388
+00:34:17,150 --> 00:34:22,530
+استعملهم تمانية خلوا هذا ستة و هدول تمانية ممكن
+
+389
+00:34:22,530 --> 00:34:27,470
+نعمل زي هيك و بناء على ذلك النيلون نفسه بيصير مصنف
+
+390
+00:34:27,470 --> 00:34:33,410
+six six ممكن six eight ممكن six ten ممكن واضح؟ و
+
+391
+00:34:33,410 --> 00:34:37,650
+هذا بيعمل اللي هي الأنواع المختلفة في النيلون من
+
+392
+00:34:37,650 --> 00:34:42,310
+ناحية القوام والشكل والصلابة لكن أشهر نيل
+
+445
+00:39:28,290 --> 00:39:33,310
+علب الأدوية باسمين احد دول الاسمين انه انا لو اتيت
+
+446
+00:39:33,310 --> 00:39:35,150
+اطلعت هذه المجموعة ايش
+
+447
+00:39:40,820 --> 00:39:45,280
+فينول وبناء على ذلك ممكن تلاقوه ينكتب تحت عائلة
+
+448
+00:39:45,280 --> 00:39:54,580
+عامة أسيت أمينوفين لاحظوا أسيت أمينوفين من الأسيتل
+
+449
+00:39:54,580 --> 00:40:00,980
+والأمينو والفينول أسيت أمينوفين واضحة أسيت
+
+450
+00:40:00,980 --> 00:40:05,980
+أمينوفين بس اللي منكم اتذكره أكتر دائما على بكية
+
+451
+00:40:05,980 --> 00:40:11,210
+الأكامول بيكون مكتوب خمسمية ملي جرام إشبراسيتامول
+
+452
+00:40:11,210 --> 00:40:20,090
+برا سيتامول الان لو اجينا نطبق ال بارا أسيتامول
+
+453
+00:40:20,090 --> 00:40:28,350
+على نفس شكل الأكامول بارا لأن هدولة جايين بالنسبة
+
+454
+00:40:28,350 --> 00:40:41,230
+لبعضهم بارا صح ولا لأ أسيت لأن هاي الـ Acetamol هى
+
+455
+00:40:41,230 --> 00:40:52,370
+الأمين وهى الأول بارا
+
+456
+00:40:52,370 --> 00:40:57,570
+أسيتامول
+
+457
+00:40:57,570 --> 00:41:03,130
+فبتلاحظوا أن عندكم 500 ميلي جرام براسيتامول بحبة
+
+458
+00:41:03,130 --> 00:41:09,150
+الدواءواضحة الفكرة براستامول الان لو غيروا فيه
+
+459
+00:41:09,150 --> 00:41:13,310
+البراستامول ذرة صغيرة بدل ما دي O H صارت O ethyl
+
+460
+00:41:13,310 --> 00:41:18,610
+بيصير في ناسي تين برضه انا الجسك بيشبه الأكامول
+
+461
+00:41:18,610 --> 00:41:22,330
+لكن المشهور أكثر الأكامول وإن كان التوصي أن
+
+462
+00:41:22,330 --> 00:41:26,710
+الأكامول برضه بيغلب مع الكلية التخلص منه يعني بدون
+
+463
+00:41:26,710 --> 00:41:31,460
+سبب مايكونش كل يوم حبتين أكاموليعني فقط لحالات
+
+464
+00:41:31,460 --> 00:41:35,460
+الصداع و بإشراف طبي ممكن تتعاملوا معاه أما ناس
+
+465
+00:41:35,460 --> 00:41:38,360
+يقولوا و الله كل ما بدنا ندروا الصفحتين بدنا ناخد
+
+466
+00:41:38,360 --> 00:41:42,580
+جماله و نحطين أكامول بيخربوا الكلية تاعتهم واضح؟
+
+467
+00:41:42,580 --> 00:41:47,920
+يعني نفس الأكامول أو البراسيتامول ماتاخدهوش بدون
+
+468
+00:41:47,920 --> 00:41:53,020
+إيش بدون وصفة طبية و بدون لزوم إنما على الحامل على
+
+469
+00:41:53,020 --> 00:41:55,480
+البارد كل ما بدنا ندروا الصفحة نروح ناخدلنا حبة
+
+470
+00:41:55,480 --> 00:42:00,700
+أكامول هذه تعتبر مأساةطبعاً في أشياء تانية فرمونات
+
+471
+00:42:00,700 --> 00:42:04,260
+بنسميها برضه أشياء تطبيقية على ال e-stars و ال
+
+472
+00:42:04,260 --> 00:42:08,220
+emits بهيك بننهي اليوم و ان شاء الله المرة القادمة
+
+473
+00:42:08,220 --> 00:42:12,280
+بنبدأ في chapter ال emits
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE.srt
new file mode 100644
index 0000000000000000000000000000000000000000..dbb14b0d19aa2d031b5b6ea5daa45a2cfeb4bcbd
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE.srt
@@ -0,0 +1,1307 @@
+
+1
+00:00:19,940 --> 00:00:25,100
+بسم الله الرحمن الرحيم اليوم بنبتدأ في الفصل
+
+2
+00:00:25,100 --> 00:00:29,820
+المكمل خلينا نقول للالديهيدس والكيتونز اللي هو ال
+
+3
+00:00:29,820 --> 00:00:33,940
+carboxylic acids and their derivatives طبعا ليش
+
+4
+00:00:33,940 --> 00:00:38,900
+احنا قولنا الفصل المكمل لأن كل هذه المجموعة من
+
+5
+00:00:38,900 --> 00:00:42,240
+المركبات هي ال carbonyl containing compounds
+
+6
+00:00:42,240 --> 00:00:46,980
+المركبات يعني اللي فيها مجموعة السيضة بال bond O
+
+7
+00:00:47,750 --> 00:00:51,810
+صنفنا ال الديهيدز والكيتونز لوحدنا وقلنا هدولة
+
+8
+00:00:51,810 --> 00:00:56,810
+جماعة ال addition او الإضافة الآن بيجي عند
+
+9
+00:00:56,810 --> 00:01:01,330
+الكاربوكسيليك أسدوبنقول عن المراكبات التانية
+
+10
+00:01:01,330 --> 00:01:04,290
+derivatives of carboxylic acids مشتقة من ال
+
+11
+00:01:04,290 --> 00:01:08,770
+carboxylic acids بمعنى تبدل فيها مجموعة ال OH
+
+12
+00:01:08,770 --> 00:01:14,770
+بمجموعة تانية فإذا أبدلت ب OR بيصير Ester إذا
+
+13
+00:01:14,770 --> 00:01:20,190
+أبدلت ب NH2 و لا NHR بيصير Amid إذا أبدلت بCL أو
+
+14
+00:01:20,190 --> 00:01:24,310
+بR بيصير Acid Halide Acid chloride or bromide إذا
+
+15
+00:01:24,310 --> 00:01:27,490
+أبدلت بOC double bond O بيصير Acid anhydride
+
+16
+00:01:27,490 --> 00:01:34,570
+فبنقول إحناCarboxylic Acids and their derivatives
+
+17
+00:01:34,570 --> 00:01:40,630
+و لذلك لو أتينا مثلا سألناكوا السؤال E stars are
+
+18
+00:01:40,630 --> 00:01:45,450
+Carboxylic Acid derivatives صح Acid chlorides are
+
+19
+00:01:45,450 --> 00:01:48,070
+Carboxylic Acid derivatives صح لكن لو مثلا
+
+20
+00:01:48,070 --> 00:01:51,870
+قلنالكوا E stars are Carboxylic Acid derivatives
+
+21
+00:01:51,870 --> 00:01:57,050
+no aldehydes or ketones or alcohol واضح فاللي
+
+22
+00:01:57,050 --> 00:02:04,490
+بنقصده بال derivative كم نوعأربعة أستر أمد أسد
+
+23
+00:02:04,490 --> 00:02:12,370
+كلورايد و أسد أنهايدرايد الأسد
+
+24
+00:02:12,370 --> 00:02:15,950
+أنهايدرايد الأسد أنهايدرايد ماخد الصيغة العامة
+
+25
+00:02:15,950 --> 00:02:18,730
+الاتية R C double bond O
+
+26
+00:02:34,410 --> 00:02:35,810
+وووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو
+
+27
+00:02:50,150 --> 00:02:56,550
+طبعا دائما اول ما بنبدأ بنبدأ باش بتسمية العائلات
+
+28
+00:02:56,550 --> 00:03:01,890
+و احنا اتفقنا ان التسمية في النظام ال IUPAC تسمية
+
+29
+00:03:01,890 --> 00:03:07,630
+سهلة اهم فيها معرفة اطول سلسلة و نعرف ايش العائلة
+
+30
+00:03:07,630 --> 00:03:11,410
+بناء على الترتيبات اللي اتعلمناها سابقا الان لما
+
+31
+00:03:11,410 --> 00:03:17,230
+تكون العائلة الأحماض بنحط النهاية oic acid واضح
+
+32
+00:03:17,230 --> 00:03:22,830
+فالنهاية اللي بدنا نضيفها شو هيoic acid يعني لو
+
+33
+00:03:22,830 --> 00:03:29,270
+كان مع carbon واحدة إيش هنقول المركب مثال oic acid
+
+34
+00:03:29,270 --> 00:03:34,930
+carbon 2 إيثانويك أسد بروبانويك أسد بيوتانويك أسد
+
+35
+00:03:34,930 --> 00:03:39,730
+and so on ولذلك هذا المركب مثلا و العاد دائما
+
+36
+00:03:39,730 --> 00:03:43,730
+بيكون من عند ال acid ال acid دائما موجود على نمرة
+
+37
+00:03:43,730 --> 00:03:48,670
+واحد ولذلك مابنكتبش one oic acid لأ بس acid يعني
+
+38
+00:03:48,670 --> 00:03:54,420
+مثلا هذا المركبواحد، اتنين، تلاتة، اربعة، خمسة،
+
+39
+00:03:54,420 --> 00:03:58,900
+ستة دائما الحاجة اللي مكتوبة بين قسيل معناه انه
+
+40
+00:03:58,900 --> 00:04:03,860
+هذه معلجة واضح؟ يعني لما انا اكون هنا كاتب CH بين
+
+41
+00:04:03,860 --> 00:04:10,990
+قسيل CH3 معناه ذلك هذه ال CH3 معلجة هناواضح ايش
+
+42
+00:04:10,990 --> 00:04:14,050
+تفسيرها لما بكتبها بين قوسين بس لإن انا بكتب على
+
+43
+00:04:14,050 --> 00:04:19,410
+السطر بقدرش ا في برنامج الطباعة اطلع خط زي هيك و
+
+44
+00:04:19,410 --> 00:04:24,430
+ارسم زي هيك فبحط بين قوسين و بكتب CH3 فاللي موجودة
+
+45
+00:04:24,430 --> 00:04:27,910
+في داخل السلسلة بين قوسين يعني معلجة على المجموعة
+
+46
+00:04:27,910 --> 00:04:34,350
+اللي قبلها الان هذا المركب اكيد hexanoic acid على
+
+47
+00:04:34,350 --> 00:04:40,340
+نمرة تلاتة ال hexanoic acid شو بيحمل؟مثل فبصير
+
+48
+00:04:40,340 --> 00:04:44,040
+three methyl hexanoic acid
+
+49
+00:04:49,490 --> 00:04:54,850
+زي ما اتفقنا احنا ان الأحماض بالتدريج هتمشي مثانوك
+
+50
+00:04:54,850 --> 00:04:58,770
+ايثانوك بروبانوك بيوتانوك بنتانوك هكسانوك هبتانوك
+
+51
+00:04:58,770 --> 00:05:05,670
+اكتانوك نونا نوك ديكانوك ديكان يعني عشرة الان هذه
+
+52
+00:05:05,670 --> 00:05:10,910
+الأحماض لها أسماء شهرة هذه الأحماض لها أسماء شهرة
+
+53
+00:05:10,910 --> 00:05:15,890
+أقل تقدير نسمع فيها لمرة و نعرف أبسط اتنين او
+
+54
+00:05:15,890 --> 00:05:21,470
+تلاتة منهاالحمض اللي من كاربون واحدة formic acid
+
+55
+00:05:21,470 --> 00:05:27,310
+واضح؟ اللي من تنتين acidic acid اللي في مجموعة ال
+
+56
+00:05:27,310 --> 00:05:32,390
+acid اللي أخدناها تلاتة probionic بنقولش probionic
+
+57
+00:05:32,390 --> 00:05:38,470
+بروبانوك الاربعة بيوتانوك بيوتاريكبيوتاريك أسد
+
+58
+00:05:38,470 --> 00:05:42,390
+بعدين بيجي الخامسة Valeric و بعدين Caproic,
+
+59
+00:05:42,510 --> 00:05:46,950
+Enanthic, Caprylic, Pelargonic, Capric طبعا مش
+
+60
+00:05:46,950 --> 00:05:50,870
+ضرور نحفظها الأسماء لكن أقل تقدير يكون اسمعناها
+
+61
+00:05:50,870 --> 00:05:54,650
+مرة يعني لو في يوم من الأيام لجينا انه اخلط ال
+
+62
+00:05:54,650 --> 00:05:59,070
+Valeric acidنجي نتذكر شو ال valeric acid نفتح
+
+63
+00:05:59,070 --> 00:06:02,830
+الكتاب أو ال net نتذكر أن ال valeric acid هو ال
+
+64
+00:06:02,830 --> 00:06:06,730
+pentanoic acid واضح؟ بس أكيد أقل تقدير لما نقول
+
+65
+00:06:06,730 --> 00:06:11,850
+ethanoic acid هو ال acetic acid, methanoic acid هو
+
+66
+00:06:11,850 --> 00:06:15,630
+ال formic acid اللي أساسا جاي من وين ال formic
+
+67
+00:06:15,630 --> 00:06:20,930
+acid؟ من ال antsاللي هي باللاتيني formica يعني من
+
+68
+00:06:20,930 --> 00:06:25,770
+النمل هو الحمب اللي النملة لما بتجرس بتحطه بالإيد
+
+69
+00:06:25,770 --> 00:06:31,150
+عشان هيك القرص بيكون مؤلم واضح؟ يعني النملة لما
+
+70
+00:06:31,150 --> 00:06:37,170
+بتعمل قرص للبني آدم بتبخ شوية formic acid هذا اللي
+
+71
+00:06:37,170 --> 00:06:43,630
+بيسبب القلم عند الإنسان واضح؟
+
+72
+00:06:45,960 --> 00:06:49,860
+هذه أمثلة إضافية على تسمية ال assets واضح أنه
+
+73
+00:06:49,860 --> 00:06:53,960
+الأساس البحث عن أطول سلسة و الترقيم من عند ال c
+
+74
+00:06:53,960 --> 00:06:57,640
+double bond o يعني نمرة واحد هي إيش ال c double
+
+75
+00:06:57,640 --> 00:07:03,020
+bond o الآن انتبهوا لخطأ شائع بصره الطلاب جد ما
+
+76
+00:07:03,020 --> 00:07:06,420
+بتعد معهم إنهم يخطئوا فيه إنه أول ما يشوفوا c
+
+77
+00:07:06,420 --> 00:07:11,700
+double bond oبياخدوا هذا الجزء و بيقولوا CWO على
+
+78
+00:07:11,700 --> 00:07:16,040
+الطرف إذا هذا الديهايد و الديهايد على نمر واحد
+
+79
+00:07:16,040 --> 00:07:19,600
+حامل مجموعة هيدروكسي فبيجوا يقولون one
+
+80
+00:07:19,600 --> 00:07:26,660
+hydroxybutanol طبعا إذا التقت ال CWO مع ال OH خلاص
+
+81
+00:07:26,660 --> 00:07:33,030
+أصبحت المجموعة الوظيفية هي هذه كاملةو كلها كاملة
+
+82
+00:07:33,030 --> 00:07:37,170
+بتعطي نهاية ايش اوك اسد لما اجي اقول واحد اتنين
+
+83
+00:07:37,170 --> 00:07:40,250
+تلاتة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+84
+00:07:40,250 --> 00:07:46,130
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+85
+00:07:46,130 --> 00:07:51,210
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+86
+00:07:51,210 --> 00:07:52,450
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+87
+00:07:52,450 --> 00:07:53,030
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+88
+00:07:53,030 --> 00:07:53,550
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+89
+00:07:53,550 --> 00:07:56,910
+اربعة اربعة اربعة اربعة اربعة اربعة اربEthyl to
+
+90
+00:07:56,910 --> 00:08:02,530
+Ethyl butanoic acid هنا مثلا بالزويك أسد حامل
+
+91
+00:08:02,530 --> 00:08:07,890
+الكلور علىال بارا position أو ال four position مر
+
+92
+00:08:07,890 --> 00:08:12,870
+علينا مثل هذا المركب لحظو هنا عندنا مجموعة وظيفية
+
+93
+00:08:12,870 --> 00:08:18,110
+واحدة اللي هي مجموعة الاش ال acid لكن لو انتقل ال
+
+94
+00:08:18,110 --> 00:08:21,430
+acid مع ال الديهايد او ال كيتون او كذا مين اللي
+
+95
+00:08:21,430 --> 00:08:25,630
+الاولوية ال acid اعلى من ال الديهايد اعلى من ال
+
+96
+00:08:25,630 --> 00:08:31,430
+كيتون اعلى من ال alcohol كل شيء هينسبلهالان لو يا
+
+97
+00:08:31,430 --> 00:08:37,270
+ترى كان عندى اكثر من acid لو كان عندى اكثر من acid
+
+98
+00:08:37,270 --> 00:08:41,790
+ممكن على السلسلة على الطرفين يكون على هذا الطرف
+
+99
+00:08:41,790 --> 00:08:46,230
+مجموعة acid وعلى هذا الطرف مجموعة acid واضح؟ ممكن
+
+100
+00:08:46,230 --> 00:08:52,770
+يكون اكثر من مجموعتين كمان اكيد لو كان عندى تفرعات
+
+101
+00:08:52,770 --> 00:08:57,590
+يعني لو كان عندى مثل هذا مثل هذه السلسلة ممكن
+
+102
+00:08:57,590 --> 00:09:04,870
+احطها لمجموعة acidc double bond o o h ممكن احط هنا
+
+103
+00:09:04,870 --> 00:09:11,170
+مجموعة acid ممكن احط هنا مجموعة acid واضح يعني
+
+104
+00:09:11,170 --> 00:09:16,150
+ممكن مجموعة مجموعتين تلاتة اربعة لو صار عندى
+
+105
+00:09:16,150 --> 00:09:20,550
+تفارعات كله وارد طب الآن لما بيصير عندى اكثر من
+
+106
+00:09:20,550 --> 00:09:26,750
+مجموعة ايش بدي اسمه بدل ما بدي اقول awake لما
+
+107
+00:09:26,750 --> 00:09:35,110
+يصيروا تنتين die awakeDioic acid فهنا لما يكونوا
+
+108
+00:09:35,110 --> 00:09:38,510
+carbon 2 هل ممكن ع carbon واحدة نحط two acids
+
+109
+00:09:38,510 --> 00:09:46,230
+مستحيل فأبسط حامض diacid هو اللي ع carbon 2 بيكون
+
+110
+00:09:46,230 --> 00:09:52,250
+اسمه ethanedioic acid ethanedioic acid هذا ماخد
+
+111
+00:09:52,250 --> 00:09:58,230
+اسم الشهرة oxalic acid لو صاروا تلاتةيعني هي ع
+
+112
+00:09:58,230 --> 00:10:03,710
+الطرف وع الطرف مجموعة حامض بيصير إيش بروبان ديويك
+
+113
+00:10:03,710 --> 00:10:08,690
+أسد ماخد اسم شورا مالونك أسد بعدين بيوتان ديويك
+
+114
+00:10:08,690 --> 00:10:14,940
+أسد ساكسينك بنتان هكسان هبتينDioic acid، glutaric،
+
+115
+00:10:14,940 --> 00:10:19,920
+adibic بملك، أسماء شهراء كثيرة موجودة، أقل تقدير
+
+116
+00:10:19,920 --> 00:10:23,980
+خلّينا نعرف ال aiobacnine، ال aiobacnine بستعمل
+
+117
+00:10:23,980 --> 00:10:30,960
+كلمة إيش؟ Dioic acid، بستعمل كلمة Dioic acid، و
+
+118
+00:10:30,960 --> 00:10:35,470
+أبسط Dioic acid زي ما قولنا إيش؟ال oxalic acid ..
+
+119
+00:10:35,470 --> 00:10:40,250
+ال oxalic acid كويس تعرفوه يعني طالما .. طالما
+
+120
+00:10:40,250 --> 00:10:47,010
+انتوا تحاليل طبية لما تبدأوا تدرسوا في ال urine في
+
+121
+00:10:47,010 --> 00:10:52,530
+ال bowl الأملاح وبعد هيك الأملاح هذه بدأت تعمل
+
+122
+00:10:52,530 --> 00:10:58,110
+حصوات في الكيليةهتلاحظوا ان جزء أساسي ان الحصوات
+
+123
+00:10:58,110 --> 00:11:03,550
+اما بده تكون صلبة جدا من ال oxalic acids او من ال
+
+124
+00:11:03,550 --> 00:11:08,850
+oxalic acid salts او من ال phosphates واضح فلما
+
+125
+00:11:08,850 --> 00:11:14,950
+نيجي نقول حصوات من ال oxalic acids او من ال salts
+
+126
+00:11:14,950 --> 00:11:21,180
+طبعا ال salt هيكون O minusالان هذه ال salts جزء من
+
+127
+00:11:21,180 --> 00:11:24,780
+أبيعمال حصواته و لذلك هتصيروا تقولوا oxalic acid
+
+128
+00:11:24,780 --> 00:11:29,760
+salts أملاح ال oxalic acid بتشوفوا بلوراتها تحت
+
+129
+00:11:29,760 --> 00:11:33,320
+الميكروسكوب فلما تكونوا تسمعوا oxalic acid و أنتوا
+
+130
+00:11:33,320 --> 00:11:37,160
+قاعدين بتحلله و بتحددوا شنوع الأملاح اللي عاملة
+
+131
+00:11:37,160 --> 00:11:42,100
+الحصوات و إشي أقل تقدير يضالوا في بالكوا انه مار
+
+132
+00:11:42,100 --> 00:11:49,980
+عليكم ال oxalic acid is a dyeواضح؟ من كم كربون؟ من
+
+133
+00:11:49,980 --> 00:11:56,060
+كربون تاني هنا
+
+134
+00:11:56,060 --> 00:12:01,260
+زى ما قلنا بيوتين ديويك أسد طيب لو صار عندى ال
+
+135
+00:12:01,260 --> 00:12:06,920
+triple bondلاحظوا هنا أصبح أكتر من مجموعة وظيفية
+
+136
+00:12:06,920 --> 00:12:12,120
+اويك أسد فى عندى منه تانين و triple bond اذا هنا
+
+137
+00:12:12,120 --> 00:12:17,640
+هنعد العدد لكل واحد اتنين تلاتة اربعة بيوتاين
+
+138
+00:12:17,640 --> 00:12:21,940
+دايويك أسد لاحظوا ان ال triple bond عبّرت عنها
+
+139
+00:12:21,940 --> 00:12:29,020
+بإيش ب I بيوتاين دايويك أسد طبعا لما بيكون عندى
+
+140
+00:12:29,020 --> 00:12:35,180
+triple bond مافيش عندى قصة إيشالسيس والترانس لانقص
+
+141
+00:12:35,180 --> 00:12:38,780
+السيس والترانس موجودة في ال double bonds او في
+
+142
+00:12:38,780 --> 00:12:44,740
+الحلقات وبناء على ذلك لو اتيت على بيوتين ديويك اسد
+
+143
+00:12:44,740 --> 00:12:50,120
+high carbon تنتين تلاتة اربعة اذا حطيت مجموعتين ال
+
+144
+00:12:50,120 --> 00:12:56,920
+acid على جهة واحدة هذا السيس واحد اتنين تلاتة
+
+145
+00:12:56,920 --> 00:13:02,180
+اربعة اتو بيوتين ديويك اسد ماخد اسم malic acid
+
+146
+00:13:02,830 --> 00:13:07,910
+ماليك لاحظوا ما بنقرأش مالك لأنه الملك أسد حامض
+
+147
+00:13:07,910 --> 00:13:19,010
+تاني بدون ال E ماليك هذه ال E تبعت ال الكيل ماليك
+
+148
+00:13:19,670 --> 00:13:24,190
+الـ E تبعت الالكيد الان لو هذول المجمعتين في ال
+
+149
+00:13:24,190 --> 00:13:28,790
+بيوتينويك أسد اجوا عكس بعض ال trans يعني كان
+
+150
+00:13:28,790 --> 00:13:31,830
+المركب واحد اتنين تلات اربع ال trans to
+
+151
+00:13:31,830 --> 00:13:37,370
+بيوتيندايويك أسد و اجت ايش بنسميه فيوماريك أسد
+
+152
+00:13:37,370 --> 00:13:41,890
+فيوماريك أسد هذه أحماض مشهورة المفروض تحفظوها يعني
+
+153
+00:13:41,890 --> 00:13:46,530
+لو قلنالكم ماليك أسد و فيوماريك أسد المفروض تكونوا
+
+154
+00:13:46,530 --> 00:13:51,620
+عارفين من فيهم السس الماليكمن ال Trans الفيومارك
+
+155
+00:13:51,620 --> 00:13:55,240
+واحد منهم بيجيبوه من التفاح والتاني بيجيبوه من
+
+156
+00:13:55,240 --> 00:14:01,140
+الحيوانات من الأغنام ويمكن عشان هيك لو بتطلعوا على
+
+157
+00:14:01,140 --> 00:14:07,080
+غلاف الكتاب غلاف كتاب heart بتلاحظوا في صورة تفاحة
+
+158
+00:14:07,080 --> 00:14:13,160
+خضرة اذا بعض الناس انتبهوا للغلاف هذا واحد من
+
+159
+00:14:13,160 --> 00:14:16,500
+الأحماض انسيت المليك او الفيومارك من التفاح
+
+160
+00:14:16,500 --> 00:14:22,180
+بتقولوا واضح؟الان لو يا ترى البنزينة كان عليها
+
+161
+00:14:22,180 --> 00:14:26,820
+اكثر من ascent يعني
+
+162
+00:14:26,820 --> 00:14:32,240
+die ascent كام احتمال ممكن يكون ممكن اتنين يكونوا
+
+163
+00:14:32,240 --> 00:14:36,460
+جانب بعض يعني one two die substituted بنزين ممكن
+
+164
+00:14:36,460 --> 00:14:39,820
+يكونوا واحد اتنين تلاتة وممكن يكونوا واحد اتنين
+
+165
+00:14:39,820 --> 00:14:44,200
+تلاتة اربعة اذا المجموعتين حامض على البنزينة ممكن
+
+166
+00:14:44,200 --> 00:14:49,390
+تكون علاقة بينهم one twoاو one three او one four
+
+167
+00:14:49,390 --> 00:14:54,970
+الان كل واحد من هدوله له اسم ال one two بنسميه
+
+168
+00:14:54,970 --> 00:14:59,450
+ifthalic acid و ال one three isophthalic acid و ال
+
+169
+00:14:59,450 --> 00:15:04,470
+one four teraphthalic acid اقل تقدير بدكوا تحفظه
+
+170
+00:15:04,470 --> 00:15:09,790
+لانه يعود يتكرر معنا ال ifthalic acidواضح؟ لأنه
+
+171
+00:15:09,790 --> 00:15:13,250
+منه هنعمل phthalic anhydride المليك أسد منه هنعمل
+
+172
+00:15:13,250 --> 00:15:17,530
+مليك أنهيدريد يعني هيعود مر معنى لما ندرس
+
+173
+00:15:17,530 --> 00:15:21,810
+
+223
+00:19:29,770 --> 00:19:33,710
+اتكلمنا عن ال acidity of acids قلنا بدنا ننظر
+
+224
+00:19:33,710 --> 00:19:39,510
+لثبات الايون السالب ال resonance هنا في resonance
+
+225
+00:19:39,510 --> 00:19:45,620
+مش هذا السالب ممكن يكون هناأه إذا ال acids they
+
+226
+00:19:45,620 --> 00:19:49,820
+are more acidic than alcohols or they have a lower
+
+227
+00:19:49,820 --> 00:19:55,460
+pka because of resonance ال charge in alcohol is
+
+228
+00:19:55,460 --> 00:20:01,940
+ايش وصفناها ثابتة في محلها مابتتنقلش حد يقوللي شو
+
+229
+00:20:01,940 --> 00:20:04,720
+الكلمة اللي استعملناها لهذه الشحنة اللي ثابتة في
+
+230
+00:20:04,720 --> 00:20:09,640
+محلها مابتتنقل لاحظوا اللي مابدرسوش مابحفظوش
+
+231
+00:20:09,640 --> 00:20:15,140
+المصطلحات localized in its location ايش يعني
+
+232
+00:20:15,140 --> 00:20:20,420
+location في موقعها localized يعني ثابتة بموقعها
+
+233
+00:20:20,420 --> 00:20:26,470
+متمركزة localized جاعدة بمحلة الانهاد اللي جاعدة
+
+234
+00:20:26,470 --> 00:20:31,970
+بتتنجل مرة هان و مرة هان و يعملالها resonance إيش
+
+235
+00:20:31,970 --> 00:20:39,450
+بنسميها؟ delocalized مرة هان و مرة هان و مرة هان و
+
+236
+00:20:39,450 --> 00:20:44,570
+مرة هان واضح؟ إذا وين ال charge localized و وين ال
+
+237
+00:20:44,570 --> 00:20:49,330
+delocalized؟ localized في ال alcohols لأن مافيش
+
+238
+00:20:49,330 --> 00:20:53,570
+فيهم resonance delocalized قاعدة بتنقل شمال ويمين
+
+239
+00:20:53,570 --> 00:20:58,350
+في ال carboxylic acids لأن في جنبها C double bond
+
+240
+00:20:58,350 --> 00:21:04,130
+O فممكن يتم انتقال ال bond و الشحنة مرة بتكون هنا
+
+241
+00:21:04,130 --> 00:21:07,890
+و مرة بتكون هنا انا بتقول كل هذا ال resonance سبق
+
+242
+00:21:07,890 --> 00:21:12,130
+ان اوضحناه بشكل كامل لما حكينا ال alcohol بحاجة
+
+243
+00:21:12,130 --> 00:21:17,400
+لإنكم تتبعوه فال resonance هو سببالحمضية الزايدة
+
+244
+00:21:17,400 --> 00:21:22,700
+للاسدس ولذلك الكربوكسليك اسدس الآن بنقدرش نسيبهم
+
+245
+00:21:22,700 --> 00:21:27,920
+ينكبوا على أيدنا يعني الكحولات ال BKA بتاعتهم 15
+
+246
+00:21:27,920 --> 00:21:31,280
+-16 زي الميه مش مشكلة لو اجوا على أيدنا و غسلنا
+
+247
+00:21:31,280 --> 00:21:36,100
+فيهم و بيوتلوا البكتيريا بس ماحدش عمره يجرب يغسل
+
+248
+00:21:36,100 --> 00:21:41,160
+بمحلول حتى كربوكسليك اسدس و لو بنسميها weak يعني في
+
+249
+00:21:41,160 --> 00:21:46,200
+نهاية أحمار ضعيفة بالنسبة لل HCl وبالنسبة لل H2SO4
+
+250
+00:21:46,200 --> 00:21:52,120
+لكن بتظهر أقوى كتير من الكحولات وبتظهر تحرق
+
+251
+00:21:52,120 --> 00:21:57,700
+الإيدين واضح؟ طيب
+
+252
+00:22:04,580 --> 00:22:08,520
+كل موضوع ال acidity و كتاب الثابت ال acidity و ما
+
+253
+00:22:08,520 --> 00:22:12,800
+إلى ذلك اتعلمناه و اننا نتطلع على ال BKA لاحظوا
+
+254
+00:22:12,800 --> 00:22:17,100
+لما نتطلع على ال BKA اتطلعوا مثلا ال formic acid
+
+255
+00:22:17,100 --> 00:22:20,560
+تلاتة و ستة ال acetic acid اربعة و سبعة ال
+
+256
+00:22:20,560 --> 00:22:24,480
+probionic acid اربعة و تمانية زي ما حكينا تقريبا
+
+257
+00:22:24,480 --> 00:22:29,740
+معظم هدول ال acids في منطقة ال ايش التلاتة اربعة
+
+258
+00:22:29,740 --> 00:22:35,390
+خمسة واضح؟ معظم هدول ال acid في 3,4,5 لاحظوا ال
+
+259
+00:22:35,390 --> 00:22:41,950
+alcohol عمل مقارنة هنا هاي كل ال acid تتطلع عليها
+
+260
+00:22:41,950 --> 00:22:49,750
+ال PKA تعتها قليلة 3,4 لكن ال phenol عشرة واخدنا
+
+261
+00:22:49,750 --> 00:22:53,790
+ليش ال phenol كانت ال acidity شوية مرتفعة تبعته
+
+262
+00:22:53,790 --> 00:22:59,460
+بسبب ال resonanceيا ريتنا خلناه في الامتحان
+
+263
+00:22:59,460 --> 00:23:05,440
+chapter 7 سبب ال resonance ال ethanol والميه
+
+264
+00:23:05,440 --> 00:23:14,240
+تقريبا ال BKA تبعهم زي بعض 16 15.5 منخفض الان في
+
+265
+00:23:14,240 --> 00:23:18,820
+جوا الأحماض او في جوا الكحولات لما نيجي نقول حامض
+
+266
+00:23:18,820 --> 00:23:25,950
+اقوى من حامضوقلنا بنفتش على السبب كام سبب طرحناهم
+
+267
+00:23:25,950 --> 00:23:32,650
+تلاتة يا ال resonance يا ال size يا ال inductive
+
+268
+00:23:32,650 --> 00:23:36,030
+effect الان تطلعوا هنا بتلاقوا هاي حامض سبحان الله
+
+269
+00:23:36,030 --> 00:23:42,590
+صار إيش ماله قوى أقوى كتير وهذا مشتاق من ال acetic
+
+270
+00:23:42,590 --> 00:23:50,360
+acid خلينا نرسمه هناسي دبل بوند او اتش اتراي كلور
+
+271
+00:23:50,360 --> 00:23:55,800
+و أسيتك أسل اه هذا أسيتك أسل حامل تلت مجموعات كلور
+
+272
+00:23:55,800 --> 00:23:59,440
+تخيلوا
+
+273
+00:23:59,440 --> 00:24:06,870
+انه لما بيصير ال ionization بتصير هذه O minus ماذا
+
+274
+00:24:06,870 --> 00:24:11,930
+يحدث لدي هنا اي effect؟ Inductive effect ان هذه
+
+275
+00:24:11,930 --> 00:24:16,930
+الكلور تسحب جزء من الشحنة السالبة وهذه تسحب جزء من
+
+276
+00:24:16,930 --> 00:24:18,610
+الشحنة السالبة وهذه تسحب جزء من الشحنة السالبة هذا
+
+277
+00:24:18,610 --> 00:24:23,090
+ال effect Inductive فال Trichloroacetic acid is
+
+278
+00:24:23,090 --> 00:24:28,830
+stronger than اكيد ال Dichloro لاحظوا ال Dichloro
+
+279
+00:24:28,830 --> 00:24:37,560
+في تن تل بيسحبوا ال Trichloro الكلور واحدةالاسيتك
+
+280
+00:24:37,560 --> 00:24:43,220
+أسد مفيش عشان هيك شوفوا التدريج الاسيتك أسد ال PKA
+
+281
+00:24:43,220 --> 00:24:51,480
+74% لو حطينا له وان كلورين صار كداش 82 لو حطينا
+
+282
+00:24:51,480 --> 00:24:56,870
+تنتينواحد و تلاتة من عشرة لو حطينا تلاتة point
+
+283
+00:24:56,870 --> 00:25:01,030
+seven الكلام منطقي ولا لأ inductive effect بيزيد
+
+284
+00:25:01,030 --> 00:25:04,930
+اعلى اشي بيصير لما يكونوا تلاتة اقل لو كانوا تلتين
+
+285
+00:25:04,930 --> 00:25:09,470
+اقل لو كانوا واحدة كل هذا الكلام في تفصيل ال
+
+286
+00:25:09,470 --> 00:25:14,050
+acidity الحقيقة موازي تماما للكلام اللي انا اخدناه
+
+287
+00:25:14,680 --> 00:25:18,540
+في الكحولات موازي تماما للكلام اللي أخدناه في
+
+288
+00:25:18,540 --> 00:25:22,480
+الكحولات ال resonance effect و ال inductive effect
+
+289
+00:25:22,480 --> 00:25:28,800
+و طبعا لأن ال BKA عالية في نهاية الأحماض بتتفاعل
+
+290
+00:25:28,800 --> 00:25:37,130
+مع ال NiOH حمض زي قاعدة ملح زي دماغ واضح؟هي الحامض
+
+291
+00:25:37,130 --> 00:25:41,090
+زاد الاني و اتش ال او اتش مع ال اتش هتعمل H2O و
+
+292
+00:25:41,090 --> 00:25:46,130
+هيصير عندى ملح الحامض و اتعلمنا الاصل كيف بنسميهم
+
+293
+00:25:46,130 --> 00:25:53,310
+يعني لو بدنا ناخد كمثال حقيقي ال acetic acid لو
+
+294
+00:25:53,310 --> 00:25:57,510
+بدنا ناخد كمثال حقيقي اللى عادة بتعملوله titration
+
+295
+00:25:57,510 --> 00:26:06,280
+فى التجارب العملية اللى هوC H 3 C O O H زائد N A O
+
+296
+00:26:06,280 --> 00:26:13,580
+H مين اتنجلنا شو بدي اكتب المعادلة وقتها C H 3 C O
+
+297
+00:26:13,580 --> 00:26:25,460
+O O خلينا نقول هيك N A Plus زائد H 2 O الآن هذا
+
+298
+00:26:25,460 --> 00:26:27,900
+الناتج لما بدي اسميه كيف بسميه
+
+299
+00:26:33,060 --> 00:26:38,000
+صوديوم والمجموع اللى جاى من ال acetic acid اذا من
+
+300
+00:26:38,000 --> 00:26:43,560
+ال formic acid فورميت اذا من ال probionic acid
+
+301
+00:26:43,560 --> 00:26:48,220
+بروبانويت من ال butanoic acid بيوتانويت اذا
+
+302
+00:26:48,220 --> 00:26:52,360
+النهاية ات زى ما كنتوا تقولوا صلفيت و كربونيت و
+
+303
+00:26:52,360 --> 00:26:59,010
+نيتريت نهاية ات هي نهاية ال acid اذا صوديومacetate
+
+304
+00:26:59,010 --> 00:27:05,770
+فانا شيلت ال اك او ال او اك اسد و حطيت بدلها ايش
+
+305
+00:27:05,770 --> 00:27:11,880
+ات فال ات هذهنهاية الايون السالب Sodium Acetate
+
+306
+00:27:11,880 --> 00:27:16,340
+وسبق ان وضحنا لكم ايش معنى ال Acetyl group و ال
+
+307
+00:27:16,340 --> 00:27:20,180
+Acetate group و ال Acetic Acid قولنا لكم ان هذه
+
+308
+00:27:20,180 --> 00:27:25,700
+المجموعة لحالة شو اسمها AC Acetate لو حطينا لل O
+
+309
+00:27:25,700 --> 00:27:32,030
+صارت Acetate لو حطينا لل Hأسيتك أسد فالأسيتك أسد
+
+310
+00:27:32,030 --> 00:27:41,030
+اختصارا a-c-o-h واضح أسيتل أسيتيت مع الأكسجين
+
+311
+00:27:41,030 --> 00:27:42,330
+أسيتك أسد
+
+312
+00:28:02,030 --> 00:28:03,610
+اشمع له الجهاز
+
+313
+00:28:28,050 --> 00:28:34,830
+كيف بنحضر ال carboxylic acids زي ما بتلاحظوا في
+
+314
+00:28:34,830 --> 00:28:40,830
+عندنا مجموعة كبيرة من الطرق لتحضير ال carboxylic
+
+315
+00:28:40,830 --> 00:28:46,910
+acids ممكن نبدأ نستعرض بعضها الحقيقة البعض منها مر
+
+316
+00:28:46,910 --> 00:28:53,000
+علينا البعض منها مر علينا وبعضها عبارة عن أشياء
+
+317
+00:28:53,000 --> 00:28:57,720
+جديدة اليوم احنا بناخد الشغلتين الخفاف اللي مروا
+
+318
+00:28:57,720 --> 00:29:02,000
+علينا و الأشياء الجديدة بنسيبهم للمرة القادمة
+
+319
+00:29:02,000 --> 00:29:06,780
+الشغلتين اللي مروا علينا لما أخدنا أكسدة ال
+
+320
+00:29:06,780 --> 00:29:13,540
+primary alcohols مين تذكرني إياها بجملة بسيطة جدا؟
+
+321
+00:29:13,540 --> 00:29:19,870
+إيش حكينا في أكسدة ال primary alcohols؟ قلنا اكسدت
+
+322
+00:29:19,870 --> 00:29:24,790
+ال primary alcohol بعمل مؤكسد خفيف بتعطيني ال
+
+323
+00:29:24,790 --> 00:29:30,330
+aldehyde واضح شو العمل المؤكسد الخفيف اللي بيحول
+
+324
+00:29:30,330 --> 00:29:36,310
+ال primary alcohol ل aldehyde بي سي سي الان طيب لو
+
+325
+00:29:36,310 --> 00:29:45,200
+ال primary alcohol استعملتله عامل مؤكسد قوي بتحول ل
+
+326
+00:29:45,200 --> 00:29:48,540
+الديهايد و بيضلوا ماشي عدل ل ايش ل carboxylic
+
+327
+00:29:48,540 --> 00:29:52,420
+acids اذا ممكن انا اتحرك من ال primary alcohol ل
+
+328
+00:29:52,420 --> 00:29:57,960
+carboxylic acid باستعمال اي عامل مؤكسد كيامان او
+
+329
+00:29:57,960 --> 00:30:00,300
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+330
+00:30:00,300 --> 00:30:00,880
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+331
+00:30:00,880 --> 00:30:01,180
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+332
+00:30:01,180 --> 00:30:01,660
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+333
+00:30:01,660 --> 00:30:08,120
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+334
+00:30:08,120 --> 00:30:14,380
+فور و كيامان او فور و كيامان ابيصيروا alcohol
+
+335
+00:30:14,380 --> 00:30:18,360
+مباشرة طبعا اكيد مرورا بال الديهيدز الان في شبطر
+
+336
+00:30:18,360 --> 00:30:23,960
+ال الديهيدز و ال ketones اخدنا ان ال الديهيدز ايضا
+
+337
+00:30:23,960 --> 00:30:32,190
+بتأكسد لاش ل acids و ال ketones بتأكسدوش واضح؟
+
+338
+00:30:32,190 --> 00:30:37,030
+لاحظوا الخطأ الشائع بهمش .. خلّي كل العالم يسمع
+
+339
+00:30:37,030 --> 00:30:40,930
+الخطأ الشائع عند الطلاب أنه يوما بلتهيوا بامتحان
+
+340
+00:30:40,930 --> 00:30:44,950
+بنسوا المواد التانية و لذلك بنصير إحنا نحكي معهم و
+
+341
+00:30:44,950 --> 00:30:49,970
+هم خارج ال rhythm تماما يعني أكسدت ال aldehydes ل
+
+342
+00:30:49,970 --> 00:30:53,010
+carboxylic acids في المحاضرة السابقة هذه من
+
+343
+00:30:53,010 --> 00:30:56,110
+الأخطاء الشائعة اللي بيرتكبوها الطلاب أنه بيضالوا
+
+344
+00:30:56,110 --> 00:31:01,240
+يحطوا شغلة بدل شغلة مافيش عندهم اتزان في الدراسة من
+
+345
+00:31:01,240 --> 00:31:06,060
+البداية يعني بيموتوا مادة او مادتيلة مدة اسبوعين و
+
+346
+00:31:06,060 --> 00:31:09,920
+بيغيبوا عن محاضراتها و بيلتهيوا لمادة الامتحان
+
+347
+00:31:09,920 --> 00:31:13,300
+عملوها بيجوا بيلاجوا عندهم مشكلة في المادة التانية
+
+348
+00:31:13,300 --> 00:31:18,720
+و هكذا دائما حافظوا على انه تظلوا متزينين في جميع
+
+349
+00:31:18,720 --> 00:31:22,900
+المواد يعني بيزعل المدرس لما ييجي يحكيلكوا انه
+
+350
+00:31:22,900 --> 00:31:26,080
+اكسدت ال primary alcohols ل acids و اكسدت ال
+
+351
+00:31:26,080 --> 00:31:30,660
+aldehydes ل acids و تعب كتير في الكلام و يلاقي أنكم
+
+352
+00:31:30,660 --> 00:31:35,760
+مش متفاعلين طبعا ليش أنا نوّهت لهذا الكلام لأن
+
+353
+00:31:35,760 --> 00:31:39,720
+انتوا في النهاية لسه سنة أولى طبيعة الحياة أنه
+
+354
+00:31:39,720 --> 00:31:46,960
+هيطلب منكم عشر شغلات في يوم واحد الآن مش ممكن أن
+
+355
+00:31:46,960 --> 00:31:52,430
+البني آدم يعيش و هو بيموت شغلة على حساب شغلة لازم
+
+356
+00:31:52,430 --> 00:31:56,590
+يعمل كل شيء يعني طبيعة الحياة بعد شوية أنه بده
+
+357
+00:31:56,590 --> 00:32:02,630
+يكون عندكم عمل بدكم تعمله طفل بدكم اتربيه بيت بدكم
+
+358
+00:32:02,630 --> 00:32:06,570
+تديروا بالك عليه زوج بدكم تديروا بالك عليه الآن
+
+359
+00:32:06,570 --> 00:32:10,550
+اتخيلوا لو واحدة من هذه الأربعة طغت على التانية
+
+360
+00:32:10,550 --> 00:32:14,370
+فقط فكرتوا بالعمل الولد الصغير بيسخن و بيموت و
+
+361
+00:32:14,370 --> 00:32:18,330
+أنتم مش دارين على حالكم فقط فكرتوا بالولد الصغير
+
+362
+00:32:19,120 --> 00:32:23,340
+الجوز بيبطل عنكوا وانتوا مش دارين عن حالكوا ولذلك
+
+363
+00:32:23,340 --> 00:32:28,320
+لما تكتر الأعمال عند الإنسان من الأخطاء الشائعة
+
+364
+00:32:28,320 --> 00:32:34,910
+جدا انه يقوم بعمل ويهمل تلت أعمال اليوم في الحياة
+
+365
+00:32:34,910 --> 00:32:40,870
+العملية الجواب لأ لازم تجوم بكل الأعمال و تقسم
+
+366
+00:32:40,870 --> 00:32:45,570
+وقتك على كل الأعمال و كذلك انتوا كطلاب لازم تدرسوا
+
+367
+00:32:45,570 --> 00:32:49,730
+لكل المواد مش اذا اجاكوا امتحان اتحدد بعد أسبوعين
+
+368
+00:32:49,730 --> 00:32:53,590
+ع مدى الأسبوعين بندرس للامتحان و بنغيب عن المواد و
+
+369
+00:32:53,590 --> 00:33:00,740
+مابنفتحاش و بتضل ايش يصير عندكم التراكم هذه نصيحة
+
+370
+00:33:00,740 --> 00:33:05,180
+جيد مش بس انتوا تسمعوها وكمان الناس اللي بيحضروا
+
+371
+00:33:05,180 --> 00:33:10,300
+المحاضرات حتى لو كانوا من خارج الجامعة يسمعوا هذا
+
+372
+00:33:10,300 --> 00:33:15,540
+الكلام انه الإنسان أعماله كثيرة لازم يوازن بين
+
+373
+00:33:15,540 --> 00:33:21,600
+أعماله بس مش صح اطلاقا انه يعمل عمل على حساب عمل
+
+374
+00:33:21,600 --> 00:33:27,400
+ابهيك بنكون أخدنا طريقتين لتحضير الاحماد من
+
+375
+00:33:27,400 --> 00:33:30,980
+الكحولات و من ال الدي هايتز في طرق ثانية ان شاء
+
+376
+00:33:30,980 --> 00:33:34,840
+الله المرة القادمة بنكمل فيها و بننهي لحد ذلك
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..f54d72d5ca5f356da783a1e6ae13fbc77fa79d44
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4698, "start": 19.94, "end": 46.98, "text": "بسم الله الرحمن الرحيم اليوم بنبتدأ في الفصل المكمل خلينا نقول للالديهيدس والكيتونز اللي هو ال carboxylic acids and their derivatives طبعا ليش احنا قولنا الفصل المكمل لأن كل هذه المجموعة من المركبات هي ال carbonyl containing compounds المركبات يعني اللي فيها مجموعة السيضة بال bond O", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 44945, 3555, 2655, 3215, 10721, 8978, 27188, 36520, 9673, 24793, 1211, 16490, 20292, 8315, 8717, 39648, 24976, 6027, 16254, 3224, 25708, 3794, 16070, 4117, 36081, 11536, 11622, 13672, 1829, 31439, 2423, 1032, 4995, 88, 1050, 21667, 293, 641, 33733, 23032, 3555, 3615, 995, 32239, 8592, 1975, 5016, 8315, 12174, 12610, 8315, 27188, 36520, 9673, 24793, 1211, 5296, 33456, 28242, 29538, 9673, 7435, 2304, 2407, 27884, 9154, 9673, 2288, 4117, 3555, 9307, 39896, 2423, 12143, 2526, 75, 19273, 21810, 9673, 31747, 3555, 9307, 37495, 22653, 13672, 1829, 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"temperature": 1.0}, {"id": 2, "seek": 5845, "start": 47.75, "end": 58.45, "text": "صنفنا ال الديهيدز والكيتونز لوحدنا وقلنا هدولة جماعة ال addition او الإضافة الآن بيجي عند الكاربوكسيليك أسد", "tokens": [9381, 1863, 5172, 8315, 2423, 2423, 16254, 3224, 25708, 11622, 16070, 4117, 36081, 11536, 11622, 45164, 24401, 8315, 4032, 4587, 1211, 8315, 8032, 3215, 12610, 3660, 10874, 15042, 27884, 2423, 4500, 1975, 2407, 33688, 11242, 31845, 3660, 6024, 48506, 4724, 1829, 7435, 1829, 43242, 33251, 9640, 3555, 2407, 4117, 3794, 1829, 20292, 4117, 5551, 3794, 3215], "avg_logprob": -0.3481359690950628, "compression_ratio": 1.3669064748201438, "no_speech_prob": 0.0, "words": [{"start": 47.75, "end": 48.49, "word": "صنفنا", "probability": 0.70074462890625}, {"start": 48.49, "end": 48.61, "word": " ال", "probability": 0.8134765625}, {"start": 48.61, "end": 49.53, "word": " الديهيدز", "probability": 0.5341552734375}, {"start": 49.53, "end": 50.61, "word": " والكيتونز", "probability": 0.813671875}, 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diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..a5b4d87627fc52698a019e642a0620137daef5fc
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_raw.srt
@@ -0,0 +1,1508 @@
+1
+00:00:19,940 --> 00:00:25,100
+بسم الله الرحمن الرحيم اليوم بنبتدأ في الفصل
+
+2
+00:00:25,100 --> 00:00:29,820
+المكمل خلينا نقول للالديهيدس والكيتونز اللي هو ال
+
+3
+00:00:29,820 --> 00:00:33,940
+carboxylic acids and their derivatives طبعا ليش
+
+4
+00:00:33,940 --> 00:00:38,900
+احنا قولنا الفصل المكمل لأن كل هذه المجموعة من
+
+5
+00:00:38,900 --> 00:00:42,240
+المركبات هي ال carbonyl containing compounds
+
+6
+00:00:42,240 --> 00:00:46,980
+المركبات يعني اللي فيها مجموعة السيضة بال bond O
+
+7
+00:00:47,750 --> 00:00:51,810
+صنفنا ال الديهيدز والكيتونز لوحدنا وقلنا هدولة
+
+8
+00:00:51,810 --> 00:00:56,810
+جماعة ال addition او الإضافة الآن بيجي عند
+
+9
+00:00:56,810 --> 00:01:01,330
+الكاربوكسيليك أسدوبنقول عن المراكبات التانية
+
+10
+00:01:01,330 --> 00:01:04,290
+derivatives of carboxylic acids مشتقة من ال
+
+11
+00:01:04,290 --> 00:01:08,770
+carboxylic acids بمعنى تبدل فيها مجموعة ال OH
+
+12
+00:01:08,770 --> 00:01:14,770
+بمجموعة تانية فإذا أبدلت ب OR بيصير Easter إذا
+
+13
+00:01:14,770 --> 00:01:20,190
+أبدلت ب NH2 و لا NHR بيصير Amid إذا أبدلت بCL أو
+
+14
+00:01:20,190 --> 00:01:24,310
+بR بيصير Acid Halide Acid chloride or bromide إذا
+
+15
+00:01:24,310 --> 00:01:27,490
+أبدلت بOC double bond O بيصير Acid anhydride
+
+16
+00:01:27,490 --> 00:01:34,570
+فبنقول إحناCarboxylic Acids and their derivatives
+
+17
+00:01:34,570 --> 00:01:40,630
+و لذلك لو أتينا مثلا سألناكوا السؤال E stars are
+
+18
+00:01:40,630 --> 00:01:45,450
+Carboxylic Acid derivatives صح Acid chlorides are
+
+19
+00:01:45,450 --> 00:01:48,070
+Carboxylic Acid derivatives صح لكن لو مثلا
+
+20
+00:01:48,070 --> 00:01:51,870
+قلنالكوا E stars are Carboxylic Acid derivatives
+
+21
+00:01:51,870 --> 00:01:57,050
+no aldehydes or ketones or alcohol واضح فاللي
+
+22
+00:01:57,050 --> 00:02:04,490
+بنقصده بال derivative كم نوعأربعة أستر أمد أسد
+
+23
+00:02:04,490 --> 00:02:12,370
+كلورايد و أسد أنهايدرايد الأسد
+
+24
+00:02:12,370 --> 00:02:15,950
+أنهايدرايد الأسد أنهايدرايد ماخد الصيغة العامة
+
+25
+00:02:15,950 --> 00:02:18,730
+الاتية R C double bond O
+
+26
+00:02:34,410 --> 00:02:35,810
+وووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو
+
+27
+00:02:50,150 --> 00:02:56,550
+طبعا دائما اول ما بنبدأ بنبدأ باش بتسمية العائلات
+
+28
+00:02:56,550 --> 00:03:01,890
+و احنا اتفقنا ان التسمية في النظام ال IUPAC تسمية
+
+29
+00:03:01,890 --> 00:03:07,630
+سهلة اهم فيها معرفة اطول سلسلة و نعرف ايش العائلة
+
+30
+00:03:07,630 --> 00:03:11,410
+بناء على الترتيبات اللي اتعلمناها سابقا الان لما
+
+31
+00:03:11,410 --> 00:03:17,230
+تكون العائلة الأحماض بنحط النهاية oic acid واضح
+
+32
+00:03:17,230 --> 00:03:22,830
+فالنهاية اللي بدنا نضيفها شو هيoic acid يعني لو
+
+33
+00:03:22,830 --> 00:03:29,270
+كان مع carbon واحدة إيش هنقول المركب مثال oic acid
+
+34
+00:03:29,270 --> 00:03:34,930
+carbon 2 إيثانويك أسد بروبانويك أسد بيوتانويك أسد
+
+35
+00:03:34,930 --> 00:03:39,730
+and so on ولذلك هذا المركب مثلا و العاد دائما
+
+36
+00:03:39,730 --> 00:03:43,730
+بيكون من عند ال acid ال acid دائما موجود على نمرة
+
+37
+00:03:43,730 --> 00:03:48,670
+واحد ولذلك مابنكتبش one oic acid لأ بس acid يعني
+
+38
+00:03:48,670 --> 00:03:54,420
+مثلا هذا المركبواحد، اتنين، تلاتة، اربعة، خمسة،
+
+39
+00:03:54,420 --> 00:03:58,900
+ستة دائما الحاجة اللي مكتوبة بين قسيل معناه انه
+
+40
+00:03:58,900 --> 00:04:03,860
+هذه معلجة واضح؟ يعني لما انا اكون هنا كاتب CH بين
+
+41
+00:04:03,860 --> 00:04:10,990
+قسيل CH3 معناه ذلك هذه ال CH3 معلجة هناواضح ايش
+
+42
+00:04:10,990 --> 00:04:14,050
+تفسيرها لما بكتبها بين قوسين بس لإن انا بكتب على
+
+43
+00:04:14,050 --> 00:04:19,410
+السطر بقدرش ا في برنامج الطباعة اطلع خط زي هيك و
+
+44
+00:04:19,410 --> 00:04:24,430
+ارسم زي هيك فبحط بين قوسين و بكتب CH3 فاللي موجودة
+
+45
+00:04:24,430 --> 00:04:27,910
+في داخل السلسلة بين قوسين يعني معلجة على المجموعة
+
+46
+00:04:27,910 --> 00:04:34,350
+اللي قبلها الان هذا المركب اكيد hexanoic acid على
+
+47
+00:04:34,350 --> 00:04:40,340
+نمرة تلاتة ال hexanoic acid شو بيحمل؟مثل فبصير
+
+48
+00:04:40,340 --> 00:04:44,040
+three methyl hexanoic acid
+
+49
+00:04:49,490 --> 00:04:54,850
+زي ما اتفقنا احنا ان الأحماض بالتدريج هتمشي مثانوك
+
+50
+00:04:54,850 --> 00:04:58,770
+ايثانوك بروبانوك بيوتانوك بنتانوك هكسانوك هبتانوك
+
+51
+00:04:58,770 --> 00:05:05,670
+اكتانوك نونا نوك ديكانوك ديكان يعني عشرة الان هذه
+
+52
+00:05:05,670 --> 00:05:10,910
+الأحماض لها أسماء شهرة هذه الأحماض لها أسماء شهرة
+
+53
+00:05:10,910 --> 00:05:15,890
+أقل تقدير نسمع فيها لمرة و نعرف أبسط اتنين او
+
+54
+00:05:15,890 --> 00:05:21,470
+تلاتة منهاالحمض اللي من كاربون واحدة formic acid
+
+55
+00:05:21,470 --> 00:05:27,310
+واضح؟ اللي من تنتين acidic acid اللي في مجموعة ال
+
+56
+00:05:27,310 --> 00:05:32,390
+acid اللي أخدناها تلاتة probionic بنقولش probionic
+
+57
+00:05:32,390 --> 00:05:38,470
+بروبانوك الاربعة بيوتانوك بيوتاريكبيوتاريك أسد
+
+58
+00:05:38,470 --> 00:05:42,390
+بعدين بيجي الخامسة Valeric و بعدين Caproic,
+
+59
+00:05:42,510 --> 00:05:46,950
+Enanthic, Caprylic, Pelargonic, Capric طبعا مش
+
+60
+00:05:46,950 --> 00:05:50,870
+ضرور نحفظها الأسماء لكن أقل تقدير يكون اسمعناها
+
+61
+00:05:50,870 --> 00:05:54,650
+مرة يعني لو في يوم من الأيام لجينا انه اخلط ال
+
+62
+00:05:54,650 --> 00:05:59,070
+Valeric acidنجي نتذكر شو ال valeric acid نفتح
+
+63
+00:05:59,070 --> 00:06:02,830
+الكتاب أو ال net نتذكر أن ال valeric acid هو ال
+
+64
+00:06:02,830 --> 00:06:06,730
+pentanoic acid واضح؟ بس أكيد أقل تقدير لما نقول
+
+65
+00:06:06,730 --> 00:06:11,850
+ethanoic acid هو ال acetic acid, methanoic acid هو
+
+66
+00:06:11,850 --> 00:06:15,630
+ال formic acid اللي أساسا جاي من وين ال formic
+
+67
+00:06:15,630 --> 00:06:20,930
+acid؟ من ال antsاللي هي باللاتيني formica يعني من
+
+68
+00:06:20,930 --> 00:06:25,770
+النمل هو الحمب اللي النملة لما بتجرس بتحطه بالإيد
+
+69
+00:06:25,770 --> 00:06:31,150
+عشان هيك القرص بيكون مؤلم واضح؟ يعني النملة لما
+
+70
+00:06:31,150 --> 00:06:37,170
+بتعمل قرص للبني آدم بتبخ شوية formic acid هذا اللي
+
+71
+00:06:37,170 --> 00:06:43,630
+بيسبب القلم عند الإنسان واضح؟
+
+72
+00:06:45,960 --> 00:06:49,860
+هذه أمثلة إضافية على تسمية ال assets واضح أنه
+
+73
+00:06:49,860 --> 00:06:53,960
+الأساس البحث عن أطول سلسة و الترقيم من عند ال c
+
+74
+00:06:53,960 --> 00:06:57,640
+double bond o يعني نمرة واحد هي إيش ال c double
+
+75
+00:06:57,640 --> 00:07:03,020
+bond o الآن انتبهوا لخطأ شائع بصره الطلاب جد ما
+
+76
+00:07:03,020 --> 00:07:06,420
+بتعد معهم إنهم يخطئوا فيه إنه أول ما يشوفوا c
+
+77
+00:07:06,420 --> 00:07:11,700
+double bond oبياخدوا هذا الجزء و بيقولوا CWO على
+
+78
+00:07:11,700 --> 00:07:16,040
+الطرف إذا هذا الديهايد و الديهايد على نمر واحد
+
+79
+00:07:16,040 --> 00:07:19,600
+حامل مجموعة هيدروكسي فبيجوا يقولون one
+
+80
+00:07:19,600 --> 00:07:26,660
+hydroxybutanol طبعا إذا التقت ال CWO مع ال OH خلاص
+
+81
+00:07:26,660 --> 00:07:33,030
+أصبحت المجموعة الوظيفية هي هذه كاملةو كلها كاملة
+
+82
+00:07:33,030 --> 00:07:37,170
+بتعطي نهاية ايش اوك اسد لما اجي اقول واحد اتنين
+
+83
+00:07:37,170 --> 00:07:40,250
+تلاتة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+84
+00:07:40,250 --> 00:07:46,130
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+85
+00:07:46,130 --> 00:07:51,210
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+86
+00:07:51,210 --> 00:07:52,450
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+87
+00:07:52,450 --> 00:07:53,030
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+88
+00:07:53,030 --> 00:07:53,550
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+89
+00:07:53,550 --> 00:07:53,550
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+90
+00:07:53,550 --> 00:07:56,910
+اربعة اربعة اربعة اربعة اربعة اربعة اربEthyl to
+
+91
+00:07:56,910 --> 00:08:02,530
+Ethyl butanoic acid هنا مثلا بالزويك أسد حامل
+
+92
+00:08:02,530 --> 00:08:07,890
+الكلور علىال بارا position أو ال four position مر
+
+93
+00:08:07,890 --> 00:08:12,870
+علينا مثل هذا المركب لحظو هنا عندنا مجموعة وظيفية
+
+94
+00:08:12,870 --> 00:08:18,110
+واحدة اللي هي مجموعة الاش ال acid لكن لو انتقل ال
+
+95
+00:08:18,110 --> 00:08:21,430
+acid مع ال الديهايد او ال كيتون او كذا مين اللي
+
+96
+00:08:21,430 --> 00:08:25,630
+الاولوية ال acid اعلى من ال الديهايد اعلى من ال
+
+97
+00:08:25,630 --> 00:08:31,430
+كيتون اعلى من ال alcohol كل شيء هينسبلهالان لو يا
+
+98
+00:08:31,430 --> 00:08:37,270
+ترى كان عندى اكثر من acid لو كان عندى اكثر من acid
+
+99
+00:08:37,270 --> 00:08:41,790
+ممكن على السلسلة على الطرفين يكون على هذا الطرف
+
+100
+00:08:41,790 --> 00:08:46,230
+مجموعة acid وعلى هذا الطرف مجموعة acid واضح؟ ممكن
+
+101
+00:08:46,230 --> 00:08:52,770
+يكون اكثر من مجموعتين كمان اكيد لو كان عندى تفرعات
+
+102
+00:08:52,770 --> 00:08:57,590
+يعني لو كان عندى مثل هذا مثل هذه السلسلة ممكن
+
+103
+00:08:57,590 --> 00:09:04,870
+احطها لمجموعة acidc double bond o o h ممكن احط هنا
+
+104
+00:09:04,870 --> 00:09:11,170
+مجموعة acid ممكن احط هنا مجموعة acid واضح يعني
+
+105
+00:09:11,170 --> 00:09:16,150
+ممكن مجموعة مجموعتين تلاتة اربعة لو صار عندى
+
+106
+00:09:16,150 --> 00:09:20,550
+تفارعات كله وارد طب الآن لما بيصير عندى اكثر من
+
+107
+00:09:20,550 --> 00:09:26,750
+مجموعة ايش بدي اسمه بدل ما بدي اقول awake لما
+
+108
+00:09:26,750 --> 00:09:35,110
+يصيروا تنتين die awakeDioic acid فهنا لما يكونوا
+
+109
+00:09:35,110 --> 00:09:38,510
+carbon 2 هل ممكن ع carbon واحدة نحط two acids
+
+110
+00:09:38,510 --> 00:09:46,230
+مستحيل فأبسط حامض diacid هو اللي ع carbon 2 بيكون
+
+111
+00:09:46,230 --> 00:09:52,250
+اسمه ethanedioic acid ethanedioic acid هذا ماخد
+
+112
+00:09:52,250 --> 00:09:58,230
+اسم الشهرة oxalic acid لو صاروا تلاتةيعني هي ع
+
+113
+00:09:58,230 --> 00:10:03,710
+الطرف وع الطرف مجموعة حامض بيصير إيش بروبان ديويك
+
+114
+00:10:03,710 --> 00:10:08,690
+أسد ماخد اسم شورا مالونك أسد بعدين بيوتان ديويك
+
+115
+00:10:08,690 --> 00:10:14,940
+أسد ساكسينك بنتان هكسان هبتينDioic acid، glutaric،
+
+116
+00:10:14,940 --> 00:10:19,920
+adibic بملك، أسماء شهراء كثيرة موجودة، أقل تقدير
+
+117
+00:10:19,920 --> 00:10:23,980
+خلّينا نعرف ال aiobacnine، ال aiobacnine بستعمل
+
+118
+00:10:23,980 --> 00:10:30,960
+كلمة إيش؟ Dioic acid، بستعمل كلمة Dioic acid، و
+
+119
+00:10:30,960 --> 00:10:35,470
+أبسط Dioic acid زي ما قولنا إيش؟ال oxalic acid ..
+
+120
+00:10:35,470 --> 00:10:40,250
+ال oxalic acid كويس تعرفوه يعني طالما .. طالما
+
+121
+00:10:40,250 --> 00:10:47,010
+انتوا تحاليل طبية لما تبدأوا تدرسوا في ال urine في
+
+122
+00:10:47,010 --> 00:10:52,530
+ال bowl الأملاح وبعد هيك الأملاح هذه بدأت تعمل
+
+123
+00:10:52,530 --> 00:10:58,110
+حصوات في الكيليةهتلاحظوا ان جزء أساسي ان الحصوات
+
+124
+00:10:58,110 --> 00:11:03,550
+اما بده تكون صلبة جدا من ال oxalic acids او من ال
+
+125
+00:11:03,550 --> 00:11:08,850
+oxalic acid salts او من ال phosphates واضح فلما
+
+126
+00:11:08,850 --> 00:11:14,950
+نيجي نقول حصوات من ال oxalic acids او من ال salts
+
+127
+00:11:14,950 --> 00:11:21,180
+طبعا ال salt هيكون O minusالان هذه ال salts جزء من
+
+128
+00:11:21,180 --> 00:11:24,780
+أبيعمال حصواته و لذلك هتصيروا تقولوا oxalic acid
+
+129
+00:11:24,780 --> 00:11:29,760
+salts أملاح ال oxalic acid بتشوفوا بلوراتها تحت
+
+130
+00:11:29,760 --> 00:11:33,320
+الميكروسكوب فلما تكونوا تسمعوا oxalic acid و أنتوا
+
+131
+00:11:33,320 --> 00:11:37,160
+قاعدين بتحلله و بتحددوا شنوع الأملاح اللي عاملة
+
+132
+00:11:37,160 --> 00:11:42,100
+الحصوات و إشي أقل تقدير يضالوا في بالكوا انه مار
+
+133
+00:11:42,100 --> 00:11:49,980
+عليكم ال oxalic acid is a dyeواضح؟ من كم كربون؟ من
+
+134
+00:11:49,980 --> 00:11:56,060
+كربون تاني هنا
+
+135
+00:11:56,060 --> 00:12:01,260
+زى ما قلنا بيوتين ديويك أسد طيب لو صار عندى ال
+
+136
+00:12:01,260 --> 00:12:06,920
+triple bondلاحظوا هنا أصبح أكتر من مجموعة وظيفية
+
+137
+00:12:06,920 --> 00:12:12,120
+اويك أسد فى عندى منه تانين و triple bond اذا هنا
+
+138
+00:12:12,120 --> 00:12:17,640
+هنعد العدد لكل واحد اتنين تلاتة اربعة بيوتاين
+
+139
+00:12:17,640 --> 00:12:21,940
+دايويك أسد لاحظوا ان ال triple bond عبّرت عنها
+
+140
+00:12:21,940 --> 00:12:29,020
+بإيش ب I بيوتاين دايويك أسد طبعا لما بيكون عندى
+
+141
+00:12:29,020 --> 00:12:35,180
+triple bond مافيش عندى قصة إيشالسيس والترانس لانقص
+
+142
+00:12:35,180 --> 00:12:38,780
+السيس والترانس موجودة في ال double bonds او في
+
+143
+00:12:38,780 --> 00:12:44,740
+الحلقات وبناء على ذلك لو اتيت على بيوتين ديويك اسد
+
+144
+00:12:44,740 --> 00:12:50,120
+high carbon تنتين تلاتة اربعة اذا حطيت مجموعتين ال
+
+145
+00:12:50,120 --> 00:12:56,920
+acid على جهة واحدة هذا السيس واحد اتنين تلاتة
+
+146
+00:12:56,920 --> 00:13:02,180
+اربعة اتو بيوتين ديويك اسد ماخد اسم malic acid
+
+147
+00:13:02,830 --> 00:13:07,910
+ماليك لاحظوا ما بنقرأش مالك لأنه الملك أسد حامض
+
+148
+00:13:07,910 --> 00:13:19,010
+تاني بدون ال E ماليك هذه ال E تبعت ال الكيل ماليك
+
+149
+00:13:19,670 --> 00:13:24,190
+الـ E تبعت الالكيد الان لو هذول المجمعتين في ال
+
+150
+00:13:24,190 --> 00:13:28,790
+بيوتينويك أسد اجوا عكس بعض ال trans يعني كان
+
+151
+00:13:28,790 --> 00:13:31,830
+المركب واحد اتنين تلات اربع ال trans to
+
+152
+00:13:31,830 --> 00:13:37,370
+بيوتيندايويك أسد و اجت ايش بنسميه فيوماريك أسد
+
+153
+00:13:37,370 --> 00:13:41,890
+فيوماريك أسد هذه أحماض مشهورة المفروض تحفظوها يعني
+
+154
+00:13:41,890 --> 00:13:46,530
+لو قلنالكم ماليك أسد و فيوماريك أسد المفروض تكونوا
+
+155
+00:13:46,530 --> 00:13:51,620
+عارفين من فيهم السس الماليكمن ال Trans الفيومارك
+
+156
+00:13:51,620 --> 00:13:55,240
+واحد منهم بيجيبوه من التفاح والتاني بيجيبوه من
+
+157
+00:13:55,240 --> 00:14:01,140
+الحيوانات من الأغنام ويمكن عشان هيك لو بتطلعوا على
+
+158
+00:14:01,140 --> 00:14:07,080
+غلاف الكتاب غلاف كتاب heart بتلاحظوا في صورة تفاحة
+
+159
+00:14:07,080 --> 00:14:13,160
+خضرة اذا بعض الناس انتبهوا للغلاف هذا واحد من
+
+160
+00:14:13,160 --> 00:14:16,500
+الأحماض انسيت المليك او الفيومارك من التفاح
+
+161
+00:14:16,500 --> 00:14:22,180
+بتقولوا واضح؟الان لو يا ترى البنزينة كان عليها
+
+162
+00:14:22,180 --> 00:14:26,820
+اكثر من ascent يعني
+
+163
+00:14:26,820 --> 00:14:32,240
+die ascent كام احتمال ممكن يكون ممكن اتنين يكونوا
+
+164
+00:14:32,240 --> 00:14:36,460
+جانب بعض يعني one two die substituted بنزين ممكن
+
+165
+00:14:36,460 --> 00:14:39,820
+يكونوا واحد اتنين تلاتة وممكن يكونوا واحد اتنين
+
+166
+00:14:39,820 --> 00:14:44,200
+تلاتة اربعة اذا المجموعتين حامض على البنزينة ممكن
+
+167
+00:14:44,200 --> 00:14:49,390
+تكون علاقة بينهم one twoاو one three او one four
+
+168
+00:14:49,390 --> 00:14:54,970
+الان كل واحد من هدوله له اسم ال one two بنسميه
+
+169
+00:14:54,970 --> 00:14:59,450
+ifthalic acid و ال one three isophthalic acid و ال
+
+170
+00:14:59,450 --> 00:15:04,470
+one four teraphthalic acid اقل تقدير بدكوا تحفظه
+
+171
+00:15:04,470 --> 00:15:09,790
+لانه يعود يتكرر معنا ال ifthalic acidواضح؟ لأنه
+
+172
+00:15:09,790 --> 00:15:13,250
+منه هنعمل phthalic anhydride المليك أسد منه هنعمل
+
+173
+00:15:13,250 --> 00:15:17,530
+مليك أنهيدريد يعني هيعود مر معنى لما ندرس
+
+174
+00:15:17,530 --> 00:15:21,810
+الانهيدريد مليك أنهيدريد و phthalic anhydride
+
+175
+00:15:21,810 --> 00:15:26,570
+فالمليك أسد الأربعة اللي فيهم دابل بوند و سيس
+
+176
+00:15:26,570 --> 00:15:32,270
+الفثالك أسد داي أسد على البنزين أورثو جايين
+
+177
+00:15:32,270 --> 00:15:35,630
+المجموعتين to each other يعني العلاقة بينهم one
+
+178
+00:15:35,630 --> 00:15:42,670
+twoالان ال physical properties of carboxylic acids
+
+179
+00:15:42,670 --> 00:15:50,310
+الكلام يشبه الكحولات لكن خلنا نقول يعني في
+
+180
+00:15:50,310 --> 00:15:53,990
+hydrogen bonding في ال acids ال hydrogen bonding
+
+181
+00:15:53,990 --> 00:15:57,990
+في ال acids بيعمل solubility in water لكن بيضل
+
+182
+00:15:57,990 --> 00:16:05,090
+بشكل عام ان الحامض هو عبارة عن R وC double bond O
+
+183
+00:16:06,090 --> 00:16:12,950
+OH بمعنى زي ما كان الكحول ايش كان الكحول خلينا
+
+184
+00:16:12,950 --> 00:16:19,170
+نقول CH2OH الآن في الكحول اتفقنا انه في جزء polar
+
+185
+00:16:19,170 --> 00:16:24,990
+و في جزء non polar الآن الحامض نفس الاشي جزء polar
+
+186
+00:16:24,990 --> 00:16:31,760
+و جزء non polarnon-polar اللي هي ال R و لذلك لو
+
+187
+00:16:31,760 --> 00:16:35,600
+اجيلا نحكي عن ال solubility in water ال solubility
+
+188
+00:16:35,600 --> 00:16:39,160
+in water بنقول ان ال low alcohols are water
+
+189
+00:16:39,160 --> 00:16:43,260
+soluble كل ما ال R كبرت بتقلل ال solubility الان
+
+190
+00:16:43,260 --> 00:16:48,700
+نفس الجملة بنكررها ال low acids are water soluble
+
+191
+00:16:48,700 --> 00:16:51,620
+معناه low acids يعني اللي فيهم ال R صغيرة كربونا
+
+192
+00:16:51,620 --> 00:16:55,380
+تنتين تلاتة هدول بيدوبوا في الميه يعني مثلا ال
+
+193
+00:16:55,380 --> 00:17:00,290
+acetic acid كام كربونا بالمجملتلتين ال .. ال
+
+194
+00:17:00,290 --> 00:17:05,290
+acetic acid الخل بدوب في الميه عمرا واحد عملة مخلل
+
+195
+00:17:05,290 --> 00:17:11,310
+مش بتحطوا شوية خل عليها هو ال acetic acid حتى الخل
+
+196
+00:17:11,310 --> 00:17:14,870
+اللي بتشتريوه من السوق هو عبارة عن ال acetic acid
+
+197
+00:17:14,870 --> 00:17:20,710
+مدوب في الميه بنسبة بسيطة 4-5% واضح؟ فبنقول احنا
+
+198
+00:17:20,710 --> 00:17:25,610
+ان ال acids و ال alcohols both are polarو بناء على
+
+199
+00:17:25,610 --> 00:17:28,770
+ذلك الـ low acids and low alcohols are water
+
+200
+00:17:28,770 --> 00:17:32,850
+soluble كلما ال chain كبرت كلما ال solubility
+
+201
+00:17:32,850 --> 00:17:38,710
+اشمالها بتقل الان وجود ال OH بتعمل hydrogen
+
+202
+00:17:38,710 --> 00:17:43,630
+bonding وبناء على ذلك الأحماض والكحولات بشكل عام
+
+203
+00:17:43,630 --> 00:17:48,630
+نقاط غليانهم اشمالها مرتفعة لأن هان و هان في عنده
+
+204
+00:17:49,330 --> 00:17:53,990
+hydrogen bonding يعني تطلعوا انتوا مثلا ال acetic
+
+205
+00:17:53,990 --> 00:17:59,490
+acid كربونتين ال boiling point تبعته كده؟ مية و
+
+206
+00:17:59,490 --> 00:18:05,030
+تمانتاش عالية جدا ال ethanol كان تمانية و سبعين ال
+
+207
+00:18:05,030 --> 00:18:07,750
+probionic acid مية و واحد و اربعين ال butanoic
+
+208
+00:18:07,750 --> 00:18:11,290
+acid مية و اربعة و ستين بعد هيك الأحماض بتبدأ
+
+209
+00:18:11,290 --> 00:18:17,410
+تقترب تصير solidواضح الفكرة فالارتفاع في ال
+
+210
+00:18:17,410 --> 00:18:21,230
+boiling point النسبي و اكيد في ال melting point هو
+
+211
+00:18:21,230 --> 00:18:28,130
+سببه ال hydrogen bonding الان بتجينا صفة تانية
+
+212
+00:18:28,130 --> 00:18:34,050
+اللي هي ال acidity ال acidity متعلقة بإيش؟بال اتش
+
+213
+00:18:34,050 --> 00:18:38,190
+الموجودة على ال oxygen يعني هذه الاتش انها تفقد
+
+214
+00:18:38,190 --> 00:18:42,150
+ويتكون هنا عندي ايون سالم او تفقد هنا ويتكون عندي
+
+215
+00:18:42,150 --> 00:18:46,350
+هنا ايون سالم قلنا احنا ان ال alcohols they are in
+
+216
+00:18:46,350 --> 00:18:52,150
+general acidic و ال carboxylic acid acidic لكن جدش
+
+217
+00:18:52,150 --> 00:18:56,850
+ال bk ايه لل alcohol اذا انتم متذكرين تقريبا ال
+
+218
+00:18:56,850 --> 00:19:01,970
+alcohols العادية مثانول اثانولكانت خمس طائش، ست
+
+219
+00:19:01,970 --> 00:19:07,790
+طائش، الآن ال carboxylic acids أقوى كتير ال BKA
+
+220
+00:19:07,790 --> 00:19:12,770
+تبعتهم حوالي أربع على خمسة مين أقوى كتير ال
+
+221
+00:19:12,770 --> 00:19:16,430
+carboxylic acids ولا الكحولات المناظرة أو الكحولات
+
+222
+00:19:16,430 --> 00:19:22,410
+بشكل عام؟ ال carboxylic acids، إيش السبب؟ حكيناها
+
+223
+00:19:25,810 --> 00:19:29,770
+الـ H فقدت الله يرحمها، ضال الايون السالب لما
+
+224
+00:19:29,770 --> 00:19:33,710
+اتكلمنا عن ال acidity of acids قلنا بدنا ننظر
+
+225
+00:19:33,710 --> 00:19:39,510
+لثبات الايون السالب ال resonance هنا في resonance
+
+226
+00:19:39,510 --> 00:19:45,620
+مش هذا السالب ممكن يكون هناأه إذا ال acids they
+
+227
+00:19:45,620 --> 00:19:49,820
+are more acidic than alcohols or they have a lower
+
+228
+00:19:49,820 --> 00:19:55,460
+pka because of resonance ال charge in alcohol is
+
+229
+00:19:55,460 --> 00:20:01,940
+ايش وصفناها ثابتة في محلها مابتتنقلش حد يقوللي شو
+
+230
+00:20:01,940 --> 00:20:04,720
+الكلمة اللي استعملناها لهذه الشحنة اللي ثابتة في
+
+231
+00:20:04,720 --> 00:20:09,640
+محلها مابتتنقل لاحظوا اللي مابدرسوش مابحفظوش
+
+232
+00:20:09,640 --> 00:20:15,140
+المصطلحات localizedin its location ايش يعني
+
+233
+00:20:15,140 --> 00:20:20,420
+location في موقعها localized يعني ثابتة بموقعها
+
+234
+00:20:20,420 --> 00:20:26,470
+متمركزة localizedجاعدة بمحلة الانهاد اللي جاعدة
+
+235
+00:20:26,470 --> 00:20:31,970
+بتتنجل مرة هان و مرة هان و يعملالها resonance إيش
+
+236
+00:20:31,970 --> 00:20:39,450
+بنسميها؟ delocalized مرة هان و مرة هان و مرة هان و
+
+237
+00:20:39,450 --> 00:20:44,570
+مرة هان واضح؟ إذا وين ال charge localized و وين ال
+
+238
+00:20:44,570 --> 00:20:49,330
+delocalized؟localized في ال alcohols لأن مافيش
+
+239
+00:20:49,330 --> 00:20:53,570
+فيهم resonance delocalized قاعدة بتنقل شمال ويمين
+
+240
+00:20:53,570 --> 00:20:58,350
+في ال carboxylic acids لأن في جنبها C double bond
+
+241
+00:20:58,350 --> 00:21:04,130
+O فممكن يتم انتقال ال bond و الشحنة مرة بتكون هنا
+
+242
+00:21:04,130 --> 00:21:07,890
+و مرة بتكون هنا انا بتقول كل هذا ال resonance سبق
+
+243
+00:21:07,890 --> 00:21:12,130
+ان اوضحناه بشكل كامل لما حكينا ال alcohol بحاجة
+
+244
+00:21:12,130 --> 00:21:17,400
+لإنكم تتبعوه فال resonance هو سببالحمضية الزايدة
+
+245
+00:21:17,400 --> 00:21:22,700
+للاسدس ولذلك الكربوكسليك اسدس الآن بنقدرش نسيبهم
+
+246
+00:21:22,700 --> 00:21:27,920
+ينكبوا على أيدنا يعني الكحولات ال BKA بتاعتهم 15
+
+247
+00:21:27,920 --> 00:21:31,280
+-16 زي الميه مش مشكلة لو اجوا على أيدنا و غسلنا
+
+248
+00:21:31,280 --> 00:21:36,100
+فيهم و بيوتلوا البكتيريا بس ماحدش عمره يجرب يغسل
+
+249
+00:21:36,100 --> 00:21:41,160
+بمحلول حتى كربوكسليك اسدس و لو بنسميها weakيعني في
+
+250
+00:21:41,160 --> 00:21:46,200
+نهاية أحمار ضعيفة بالنسبة لل HCl وبالنسبة لل H2SO4
+
+251
+00:21:46,200 --> 00:21:52,120
+لكن بتظهر أقوى كتير من الكحولات وبتظهر تحرق
+
+252
+00:21:52,120 --> 00:21:57,700
+الإيدين واضح؟ طيب
+
+253
+00:22:04,580 --> 00:22:08,520
+كل موضوع ال acidity و كتاب الثابت ال acidity و ما
+
+254
+00:22:08,520 --> 00:22:12,800
+إلى ذلك اتعلمناه و اننا نتطلع على ال BKA لاحظوا
+
+255
+00:22:12,800 --> 00:22:17,100
+لما نتطلع على ال BKA اتطلعوا مثلا ال formic acid
+
+256
+00:22:17,100 --> 00:22:20,560
+تلاتة و ستة ال acetic acid اربعة و سبعة ال
+
+257
+00:22:20,560 --> 00:22:24,480
+probionic acid اربعة و تمانية زي ما حكينا تقريبا
+
+258
+00:22:24,480 --> 00:22:29,740
+معظم هدول ال acids في منطقة ال ايش التلاتة اربعة
+
+259
+00:22:29,740 --> 00:22:35,390
+خمسةواضح؟ معظم هدول ال acid في 3,4,5 لاحظوا ال
+
+260
+00:22:35,390 --> 00:22:41,950
+alcohol عمل مقارنة هنا هاي كل ال acid تتطلع عليها
+
+261
+00:22:41,950 --> 00:22:49,750
+ال PKA تعتها قليلة 3,4 لكن ال phenol عشرة واخدنا
+
+262
+00:22:49,750 --> 00:22:53,790
+ليش ال phenol كانت ال acidity شوية مرتفعة تبعته
+
+263
+00:22:53,790 --> 00:22:59,460
+بسبب ال resonanceيا ريتنا خلناه في الامتحان
+
+264
+00:22:59,460 --> 00:23:05,440
+chapter 7 سبب ال resonance ال ethanol والميه
+
+265
+00:23:05,440 --> 00:23:14,240
+تقريبا ال BKA تبعهم زي بعض 16 15.5 منخفض الان في
+
+266
+00:23:14,240 --> 00:23:18,820
+جوا الأحماض او في جوا الكحولات لما نيجي نقول حامض
+
+267
+00:23:18,820 --> 00:23:25,950
+اقوى من حامضوقلنا بنفتش على السبب كام سبب طرحناهم
+
+268
+00:23:25,950 --> 00:23:32,650
+تلاتة يا ال resonance يا ال size يا ال inductive
+
+269
+00:23:32,650 --> 00:23:36,030
+effect الان تطلعوا هنا بتلاقوا هاي حامض سبحان الله
+
+270
+00:23:36,030 --> 00:23:42,590
+صار إيش ماله قوى أقوى كتير وهذا مشتاق من ال acetic
+
+271
+00:23:42,590 --> 00:23:50,360
+acid خلينا نرسمه هناسي دبل بوند او اتش اتراي كلور
+
+272
+00:23:50,360 --> 00:23:55,800
+و أسيتك أسل اه هذا أسيتك أسل حامل تلت مجموعات كلور
+
+273
+00:23:55,800 --> 00:23:59,440
+تخيلوا
+
+274
+00:23:59,440 --> 00:24:06,870
+انه لما بيصير ال ionization بتصير هذه O minusماذا
+
+275
+00:24:06,870 --> 00:24:11,930
+يحدث لدي هنا اي effect؟ Inductive effect ان هذه
+
+276
+00:24:11,930 --> 00:24:16,930
+الكلور تسحب جزء من الشحنة السالبة وهذه تسحب جزء من
+
+277
+00:24:16,930 --> 00:24:18,610
+الشحنة السالبة وهذه تسحب جزء من الشحنة السالبة هذا
+
+278
+00:24:18,610 --> 00:24:23,090
+ال effect Inductive فال Trichloroacetic acid is
+
+279
+00:24:23,090 --> 00:24:28,830
+stronger than اكيد ال Dichloro لاحظوا ال Dichloro
+
+280
+00:24:28,830 --> 00:24:37,560
+في تن تل بيسحبوا ال Trichloro الكلور واحدةالاسيتك
+
+281
+00:24:37,560 --> 00:24:43,220
+أسد مفيش عشان هيك شوفوا التدريج الاسيتك أسد ال PKA
+
+282
+00:24:43,220 --> 00:24:51,480
+74% لو حطينا له وان كلورين صار كداش 82 لو حطينا
+
+283
+00:24:51,480 --> 00:24:56,870
+تنتينواحد و تلاتة من عشرة لو حطينا تلاتة point
+
+284
+00:24:56,870 --> 00:25:01,030
+seven الكلام منطقي ولا لأ inductive effect بيزيد
+
+285
+00:25:01,030 --> 00:25:04,930
+اعلى اشي بيصير لما يكونوا تلاتة اقل لو كانوا تلتين
+
+286
+00:25:04,930 --> 00:25:09,470
+اقل لو كانوا واحدة كل هذا الكلام في تفصيل ال
+
+287
+00:25:09,470 --> 00:25:14,050
+acidity الحقيقة موازي تماما للكلام اللي انا اخدناه
+
+288
+00:25:14,680 --> 00:25:18,540
+في الكحولات موازي تماما للكلام اللي أخدناه في
+
+289
+00:25:18,540 --> 00:25:22,480
+الكحولات ال resonance effect و ال inductive effect
+
+290
+00:25:22,480 --> 00:25:28,800
+و طبعا لأن ال BKA عالية في نهاية الأحماض بتتفاعل
+
+291
+00:25:28,800 --> 00:25:37,130
+مع ال NiOH حمض زي قاعدة ملح زي دماغ واضح؟هي الحامض
+
+292
+00:25:37,130 --> 00:25:41,090
+زاد الاني و اتش ال او اتش مع ال اتش هتعمل H2O و
+
+293
+00:25:41,090 --> 00:25:46,130
+هيصير عندى ملح الحامض و اتعلمنا الاصل كيف بنسميهم
+
+294
+00:25:46,130 --> 00:25:53,310
+يعني لو بدنا ناخد كمثال حقيقي ال acetic acid لو
+
+295
+00:25:53,310 --> 00:25:57,510
+بدنا ناخد كمثال حقيقي اللى عادة بتعملوله titration
+
+296
+00:25:57,510 --> 00:26:06,280
+فى التجارب العملية اللى هوC H 3 C O O H زائد N A O
+
+297
+00:26:06,280 --> 00:26:13,580
+H مين اتنجلنا شو بدي اكتب المعادلة وقتها C H 3 C O
+
+298
+00:26:13,580 --> 00:26:25,460
+O O خلينا نقول هيك N A Plus زائد H 2 O الآن هذا
+
+299
+00:26:25,460 --> 00:26:27,900
+الناتج لما بدي اسميه كيف بسميه
+
+300
+00:26:33,060 --> 00:26:38,000
+صوديوم والمجموع اللى جاى من ال acetic acid اذا من
+
+301
+00:26:38,000 --> 00:26:43,560
+ال formic acid فورميت اذا من ال probionic acid
+
+302
+00:26:43,560 --> 00:26:48,220
+بروبانويت من ال butanoic acid بيوتانويت اذا
+
+303
+00:26:48,220 --> 00:26:52,360
+النهاية ات زى ما كنتوا تقولوا صلفيت و كربونيت و
+
+304
+00:26:52,360 --> 00:26:59,010
+نيتريت نهاية ات هي نهاية ال acid اذا صوديومacetate
+
+305
+00:26:59,010 --> 00:27:05,770
+فانا شيلت ال اك او ال او اك اسد و حطيت بدلها ايش
+
+306
+00:27:05,770 --> 00:27:11,880
+ات فال ات هذهنهاية الايون السالب Sodium Acetate
+
+307
+00:27:11,880 --> 00:27:16,340
+وسبق ان وضحنا لكم ايش معنى ال Acetyl group و ال
+
+308
+00:27:16,340 --> 00:27:20,180
+Acetate group و ال Acetic Acid قولنا لكم ان هذه
+
+309
+00:27:20,180 --> 00:27:25,700
+المجموعة لحالة شو اسمها AC Acetate لو حطينا لل O
+
+310
+00:27:25,700 --> 00:27:32,030
+صارت Acetate لو حطينا لل Hأسيتك أسد فالأسيتك أسد
+
+311
+00:27:32,030 --> 00:27:41,030
+اختصارا a-c-o-h واضح أسيتل أسيتيت مع الأكسجين
+
+312
+00:27:41,030 --> 00:27:42,330
+أسيتك أسد
+
+313
+00:28:02,030 --> 00:28:03,610
+اشمع له الجهاز
+
+314
+00:28:28,050 --> 00:28:34,830
+كيف بنحضر ال carboxylic acids زي ما بتلاحظوا في
+
+315
+00:28:34,830 --> 00:28:40,830
+عندنا مجموعة كبيرة من الطرق لتحضير ال carboxylic
+
+316
+00:28:40,830 --> 00:28:46,910
+acids ممكن نبدأ نستعرض بعضها الحقيقة البعض منها مر
+
+317
+00:28:46,910 --> 00:28:53,000
+علينا البعض منها مر علينا وبعضهاعبارة عن أشياء
+
+318
+00:28:53,000 --> 00:28:57,720
+جديدة اليوم احنا بناخد الشغلتين الخفاف اللي مروا
+
+319
+00:28:57,720 --> 00:29:02,000
+علينا و الأشياء الجديدة بنسيبهم للمرة القادمة
+
+320
+00:29:02,000 --> 00:29:06,780
+الشغلتين اللي مروا علينا لما أخدنا أكسدة ال
+
+321
+00:29:06,780 --> 00:29:13,540
+primary alcohols مين تذكرني إياها بجملة بسيطة جدا؟
+
+322
+00:29:13,540 --> 00:29:19,870
+إيش حكينا في أكسدة ال primary alcohols؟قلنا اكسدت
+
+323
+00:29:19,870 --> 00:29:24,790
+ال primary alcohol بعمل مؤكسد خفيف بتعطيني ال
+
+324
+00:29:24,790 --> 00:29:30,330
+aldehyde واضح شو العمل المؤكسد الخفيف اللي بيحول
+
+325
+00:29:30,330 --> 00:29:36,310
+ال primary alcohol ل aldehyde بي سي سي الان طيب لو
+
+326
+00:29:36,310 --> 00:29:45,200
+ال primary alcohol استعملتله عامل مؤكسد قويبتحول ل
+
+327
+00:29:45,200 --> 00:29:48,540
+الديهايد و بيضلوا ماشي عدل ل ايش ل carboxylic
+
+328
+00:29:48,540 --> 00:29:52,420
+acids اذا ممكن انا اتحرك من ال primary alcohol ل
+
+329
+00:29:52,420 --> 00:29:57,960
+carboxylic acid باستعمال اي عامل مؤكسد كيامان او
+
+330
+00:29:57,960 --> 00:30:00,300
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+331
+00:30:00,300 --> 00:30:00,880
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+332
+00:30:00,880 --> 00:30:01,180
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+333
+00:30:01,180 --> 00:30:01,660
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+334
+00:30:01,660 --> 00:30:08,120
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+335
+00:30:08,120 --> 00:30:14,380
+فور و كيامان او فور و كيامان ابيصيروا alcohol
+
+336
+00:30:14,380 --> 00:30:18,360
+مباشرة طبعا اكيد مرورا بال الديهيدز الان في شبطر
+
+337
+00:30:18,360 --> 00:30:23,960
+ال الديهيدز و ال ketones اخدنا ان ال الديهيدز ايضا
+
+338
+00:30:23,960 --> 00:30:32,190
+بتأكسد لاش ل acids و ال ketones بتأكسدوشواضح؟
+
+339
+00:30:32,190 --> 00:30:37,030
+لاحظوا الخطأ الشائع بهمش .. خلّي كل العالم يسمع
+
+340
+00:30:37,030 --> 00:30:40,930
+الخطأ الشائع عند الطلاب أنه يوما بلتهيوا بامتحان
+
+341
+00:30:40,930 --> 00:30:44,950
+بنسوا المواد التانية و لذلك بنصير إحنا نحكي معهم و
+
+342
+00:30:44,950 --> 00:30:49,970
+هم خارج ال rhythm تماما يعني أكسدت ال aldehydes ل
+
+343
+00:30:49,970 --> 00:30:53,010
+carboxylic acids في المحاضرة السابقة هذه من
+
+344
+00:30:53,010 --> 00:30:56,110
+الأخطاء الشائعة اللي بيرتكبوها الطلاب أنه بيضالوا
+
+345
+00:30:56,110 --> 00:31:01,240
+يحطوا شغلة بدل شغلة مافيش عندهم اتزانفي الدراسة من
+
+346
+00:31:01,240 --> 00:31:06,060
+البداية يعني بيموتوا مادة او مادتيلة مدة اسبوعين و
+
+347
+00:31:06,060 --> 00:31:09,920
+بيغيبوا عن محاضراتها و بيلتهيوا لمادة الامتحان
+
+348
+00:31:09,920 --> 00:31:13,300
+عملوها بيجوا بيلاجوا عندهم مشكلة في المادة التانية
+
+349
+00:31:13,300 --> 00:31:18,720
+و هكذا دائما حافظوا على انه تظلوا متزينين في جميع
+
+350
+00:31:18,720 --> 00:31:22,900
+المواد يعني بيزعل المدرس لما ييجي يحكيلكوا انه
+
+351
+00:31:22,900 --> 00:31:26,080
+اكسدت ال primary alcohols ل acids و اكسدت ال
+
+352
+00:31:26,080 --> 00:31:30,660
+aldehydes ل acidsو تعب كتير في الكلام و يلاقي أنكم
+
+353
+00:31:30,660 --> 00:31:35,760
+مش متفاعلين طبعا ليش أنا نوّهت لهذا الكلام لأن
+
+354
+00:31:35,760 --> 00:31:39,720
+انتوا في النهاية لسه سنة أولى طبيعة الحياة أنه
+
+355
+00:31:39,720 --> 00:31:46,960
+هيطلب منكم عشر شغلات في يوم واحد الآن مش ممكن أن
+
+356
+00:31:46,960 --> 00:31:52,430
+البني آدم يعيش و هو بيموت شغلة على حساب شغلةلازم
+
+357
+00:31:52,430 --> 00:31:56,590
+يعمل كل شيء يعني طبيعة الحياة بعد شوية أنه بده
+
+358
+00:31:56,590 --> 00:32:02,630
+يكون عندكم عمل بدكم تعمله طفل بدكم اتربيه بيت بدكم
+
+359
+00:32:02,630 --> 00:32:06,570
+تديروا بالك عليه زوج بدكم تديروا بالك عليه الآن
+
+360
+00:32:06,570 --> 00:32:10,550
+اتخيلوا لو واحدة من هذه الأربعة طغت على التانية
+
+361
+00:32:10,550 --> 00:32:14,370
+فقط فكرتوا بالعمل الولد الصغير بيسخن و بيموت و
+
+362
+00:32:14,370 --> 00:32:18,330
+أنتم مش دارين على حالكم فقط فكرتوا بالولد الصغير
+
+363
+00:32:19,120 --> 00:32:23,340
+الجوز بيبطل عنكوا وانتوا مش دارين عن حالكوا ولذلك
+
+364
+00:32:23,340 --> 00:32:28,320
+لما تكتر الأعمال عند الإنسان من الأخطاء الشائعة
+
+365
+00:32:28,320 --> 00:32:34,910
+جدا انه يقوم بعمل ويهمل تلت أعمالاليوم في الحياة
+
+366
+00:32:34,910 --> 00:32:40,870
+العملية الجواب لأ لازم تجوم بكل الأعمال و تقسم
+
+367
+00:32:40,870 --> 00:32:45,570
+وقتك على كل الأعمال و كذلك انتوا كطلاب لازم تدرسوا
+
+368
+00:32:45,570 --> 00:32:49,730
+لكل المواد مش اذا اجاكوا امتحان اتحدد بعد أسبوعين
+
+369
+00:32:49,730 --> 00:32:53,590
+ع مدى الأسبوعين بندرس للامتحان و بنغيب عن المواد و
+
+370
+00:32:53,590 --> 00:33:00,740
+مابنفتحاش و بتضل ايشيصير عندكم التراكم هذه نصيحة
+
+371
+00:33:00,740 --> 00:33:05,180
+جيد مش بس انتوا تسمعوها وكمان الناس اللي بيحضروا
+
+372
+00:33:05,180 --> 00:33:10,300
+المحاضرات حتى لو كانوا من خارج الجامعة يسمعوا هذا
+
+373
+00:33:10,300 --> 00:33:15,540
+الكلام انه الإنسان أعماله كثيرة لازم يوازن بين
+
+374
+00:33:15,540 --> 00:33:21,600
+أعماله بس مش صح اطلاقا انه يعمل عمل على حساب عمل
+
+375
+00:33:21,600 --> 00:33:27,400
+ابهيك بنكون أخدنا طريقتين لتحضيرالاحماد من
+
+376
+00:33:27,400 --> 00:33:30,980
+الكحولات و من ال الدي هايتز في طرق ثانية ان شاء
+
+377
+00:33:30,980 --> 00:33:34,840
+الله المرة القادمة بنكمل فيها و بننهي لحد ذلك
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..474ca3ea9c3f22d297621c351792f1bbad6e773d
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU.srt
@@ -0,0 +1,1377 @@
+1
+00:00:18,360 --> 00:00:22,720
+بسم الله الرحمن الرحيم المرة الماضية بدنا نتكلم في
+
+2
+00:00:22,720 --> 00:00:29,780
+موضوع البروتينات وكان الأساس ان نتعرف على الأحماض
+
+3
+00:00:29,780 --> 00:00:34,200
+الأمينية ال amino acids اتعرفنا عليهم و اتعرفنا
+
+4
+00:00:34,200 --> 00:00:38,560
+طبعا كيف بيكونوا بالوسط الحامض أو القاعدى كيف
+
+5
+00:00:38,560 --> 00:00:44,280
+بتتأثر الشحنة تبعتهمبال بي اتش وهذا الكلام بيدى
+
+6
+00:00:44,280 --> 00:00:49,560
+الى طريقة عملية لفصلهم عن بعضهم البعض اعتمادا على
+
+7
+00:00:49,560 --> 00:00:54,380
+اختلاف ال بي اتش اللى هي فكرة ال Electrophoresis
+
+8
+00:00:54,380 --> 00:01:01,420
+الان اذا بنستمر في الموضوع لو اجينا بدنا نتكلم على
+
+9
+00:01:01,420 --> 00:01:07,460
+تفاعلات الأحماض الأمينية طبعا اذا قلنا amino acids
+
+10
+00:01:07,460 --> 00:01:13,680
+كلمتين aminoاللي هي الـ Amines اللي أخدناهم في
+
+11
+00:01:13,680 --> 00:01:20,720
+الفصل شبطر 11 و Assets الأحمد اللي أخدناهم في شبطر
+
+12
+00:01:20,720 --> 00:01:26,640
+10 إذا تفاعلاتهم هي تفاعلات الـ Amines و الأحمد
+
+13
+00:01:26,640 --> 00:01:34,030
+يعني أي تفاعل كنا بناخده للأمينفي السابق في ال
+
+14
+00:01:34,030 --> 00:01:37,850
+organic العادية هيتفاعل ال amino acids فيه من خلال
+
+15
+00:01:37,850 --> 00:01:42,820
+ال amino group أي تفاعل كنا بناخده لل acidهيكون
+
+16
+00:01:42,820 --> 00:01:48,060
+نفس الاشي مع ال amino acids يعني مثلا عندكوا جملة
+
+17
+00:01:48,060 --> 00:01:54,600
+عامة انه acid زائد alcohol ايش بيعطينا Easter بناء
+
+18
+00:01:54,600 --> 00:01:59,420
+على ذلك ال amino acids فيهم acids حتى لو كانوا على
+
+19
+00:01:59,420 --> 00:02:04,180
+شكل ال soul تبعهم بيظلوا acids هذا ال acid لو اجت
+
+20
+00:02:04,180 --> 00:02:09,140
+فعلته مع alcohol هاي جزء ال acid هاي ال alcohol
+
+21
+00:02:10,310 --> 00:02:16,150
+ماذا سيعطيني إيستار سيصبح C double bond O OR أو
+
+22
+00:02:16,150 --> 00:02:22,830
+CO2 R إذا هذا مثال على أنه تفاعل كحامض أسد زائد
+
+23
+00:02:22,830 --> 00:02:28,430
+ألكوهول إيستار ليس هناك شيء جديد كذلك الحالة لو
+
+24
+00:02:28,430 --> 00:02:32,110
+إحنا جينا على ال amino group حتى لو كنا كاتبينها
+
+25
+00:02:32,110 --> 00:02:36,590
+على شكل NH3 بلس إحنا مجرد ما نفعله مع base ترجع
+
+26
+00:02:36,590 --> 00:02:37,710
+نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو
+
+27
+00:02:37,830 --> 00:02:41,930
+عادية لو اتش هنا قولنا هذا في النهاية ان اتش توحت
+
+28
+00:02:41,930 --> 00:02:46,970
+صفة بدنا نفعلها مع acid chloride او مع ايستر او مع
+
+29
+00:02:46,970 --> 00:02:50,330
+acid anhydride كيف كان الأمين يتفاعل مع ال acid
+
+30
+00:02:50,330 --> 00:02:57,310
+chloride بالإبدال بهذا الشكل و يعمل عملية إبدال في
+
+31
+00:02:57,310 --> 00:03:03,030
+هذه الحالة هيعطيني أميدفهذه الحالة هيعطيني amide
+
+32
+00:03:03,030 --> 00:03:09,170
+واضح هاي ال amide N H C double bond O واضح ففكرة
+
+33
+00:03:09,170 --> 00:03:14,510
+التفاعلات ال amino acids هي فكرة بسيطة للي فيهم
+
+34
+00:03:14,510 --> 00:03:18,830
+سابقا تفاعلات ال amines ولي فيهم سابقا تفاعلات ال
+
+35
+00:03:18,830 --> 00:03:24,410
+acids يمكن أخدتوا انتوا ان ammonia او amine زائد
+
+36
+00:03:24,410 --> 00:03:31,370
+acid شو كان بيعطيني بشكل عامأمد تمام وبناء على ذلك
+
+37
+00:03:31,370 --> 00:03:37,690
+هذه الفكرة أيضا ممكن ناخدها لكن من خلال أن الفاعل
+
+38
+00:03:37,690 --> 00:03:44,640
+جزيئين من ال amino acids مع بعض و من بعضجزء ناخد
+
+39
+00:03:44,640 --> 00:03:51,320
+منه جزء ناخد منه مجموعة الـ nitrogen الـ NH2 و جزء
+
+40
+00:03:51,320 --> 00:03:56,860
+ناخد منه جزء ال acid واضح فلما نيجي نقول NH2 زي ال
+
+41
+00:03:56,860 --> 00:04:02,840
+acid اتفاعلوا شو هيعطوني امد اذا two amino acids
+
+42
+00:04:02,840 --> 00:04:08,640
+react with each other to form amides واضح هذا
+
+43
+00:04:08,640 --> 00:04:13,510
+الكلام اللي موجود هنايعني لو أنا اتطلعت على هذا
+
+44
+00:04:13,510 --> 00:04:18,770
+المركب اللي بيطلع عندى هذا أصلا كان NH2 Amino Acid
+
+45
+00:04:18,770 --> 00:04:22,970
+و هذا ال Amino Acid التانى هذا Amino Acid و هذا
+
+46
+00:04:22,970 --> 00:04:28,850
+Amino Acid كان إيش؟ C double bond O OH لما ال NH2
+
+47
+00:04:28,850 --> 00:04:36,760
+إجت اتفاعلت هنا شو عملت؟ طردت؟الـ OH وانخصم من هنا
+
+48
+00:04:36,760 --> 00:04:43,800
+H OH مع H اذا صفينا على هذا الشكل هاي ال two amino
+
+49
+00:04:43,800 --> 00:04:49,500
+acids اتحدوا مع بعض عملوا قمد C double bond O NH
+
+50
+00:04:49,500 --> 00:04:53,520
+وين الرابطة الجديدة اللي اتكونت بين ال two amino
+
+51
+00:04:53,520 --> 00:05:05,080
+acids؟ هذه هذا كان نهاية الجزء الأولان اتش تو وكان
+
+52
+00:05:05,080 --> 00:05:09,220
+هذا الجزء نهايته سيضا بالبوند او او اتش الان اتش
+
+53
+00:05:09,220 --> 00:05:12,220
+اتصلت بالسيضا بالبوند او او اتش اذا هذه الرابطة
+
+54
+00:05:12,220 --> 00:05:16,800
+اللي اتكونت اللي هي الاميد بوند الان لأنه هنا انا
+
+55
+00:05:16,800 --> 00:05:21,820
+بابدأ ادمج amino acids مع بعضهم البعض لتكوين
+
+56
+00:05:21,820 --> 00:05:25,580
+بيبتايد هذه رابطة هنا اتكونت و رابط هنا اتكونت هذه
+
+57
+00:05:25,580 --> 00:05:30,860
+الاميد بوند بنصير احنا نعطيها اسم بيبتايد بوندواضح
+
+58
+00:05:30,860 --> 00:05:36,140
+فلما نقول ال peptide bond هي حقيقة ال amide bond
+
+59
+00:05:36,140 --> 00:05:40,760
+واضح لكن لأنه انا لما بفعل two amino acids او
+
+60
+00:05:40,760 --> 00:05:46,680
+three amino acids بكون ايش؟ peptide و لو كبروا
+
+61
+00:05:46,680 --> 00:05:52,080
+كتير بصيروا ايش؟ protein واضح فال peptides و ال
+
+62
+00:05:52,080 --> 00:05:57,060
+proteins فيهم ال amide bond واضح او بنسميها في هذه
+
+63
+00:05:57,060 --> 00:06:02,470
+الحالة تخصيصاببتايت بوند فلو قلنا مثلا سؤال ببتايت
+
+64
+00:06:02,470 --> 00:06:06,330
+بوند is an amide bond طبعا هي امد see double bond
+
+65
+00:06:06,330 --> 00:06:13,090
+O and H طبعا هيكون فيها كل خواص الامدز انه هتكون
+
+66
+00:06:13,090 --> 00:06:18,490
+هذه المنطقة كامد reactive ولا unreactive
+
+67
+00:06:18,490 --> 00:06:23,850
+unreactive احنا قلنا الكلمة الأساسية المميزة
+
+68
+00:06:23,850 --> 00:06:29,670
+للامدز they are unreactiveو بناء على ذلك حتى ال
+
+69
+00:06:29,670 --> 00:06:34,830
+hydrolysis تبعهم بيكون سهل ولا صعبصعب و لذلك بعد
+
+70
+00:06:34,830 --> 00:06:38,130
+شوية لما تيجوا تاخدوا protein على سبيل المثال
+
+71
+00:06:38,130 --> 00:06:43,290
+امكون من amino acids و اقول بدي احلل هذا ال
+
+72
+00:06:43,290 --> 00:06:49,490
+protein لالمفردات تبعته بيكون الجواب و الله اغليه
+
+73
+00:06:49,490 --> 00:06:56,110
+في وسط حامض مركز مثلا لمدة 24 ساعة و هو يغلي عشان
+
+74
+00:06:56,110 --> 00:07:02,230
+تقدر تكسر ال ايش ال amides bonds هذي شروط سهلة ولا
+
+75
+00:07:02,230 --> 00:07:08,990
+صعبة؟شروط صعبة الان لما احنا بنعمل اتحاد ل two
+
+76
+00:07:08,990 --> 00:07:13,490
+amino acids بنكون ال peptide bond ممكن نحط كمان
+
+77
+00:07:13,490 --> 00:07:18,050
+amino acid ها بالتأكيد ممكن كمان نستمر نجيب مجموعة
+
+78
+00:07:18,050 --> 00:07:24,370
+amino و هكذا الان ال peptide عادة لما احنا بنكونه
+
+79
+00:07:24,370 --> 00:07:32,070
+بنلاحظ انه في شيء مشترك في هيكل عام MCC double
+
+80
+00:07:32,070 --> 00:07:37,540
+bond Oهذا الهيكل العام إيش ماله؟ متكرر يعني هاي في
+
+81
+00:07:37,540 --> 00:07:44,780
+عندى هنا N C C double bond O بعد شو بيجيني كمان
+
+82
+00:07:44,780 --> 00:07:53,670
+مرة؟ NC C double bond O لو عملت كمان شو هيجيني N C
+
+83
+00:07:53,670 --> 00:07:59,630
+C double bond O و هكذا واضحة هذه النقطة فهذا شيء
+
+84
+00:07:59,630 --> 00:08:04,910
+مشترك في ال peptides الان اللي بيكون عادة على
+
+85
+00:08:04,910 --> 00:08:10,890
+الإيد الشمال بالنسبة لكمبنبدأ منه بنقول ان هذا
+
+86
+00:08:10,890 --> 00:08:16,670
+الجزء بيمثل ال unterminal of the peptide يعني
+
+87
+00:08:16,670 --> 00:08:21,290
+الطرف اللي فيه نيتروجين من ال peptide بنرسمه زيكي
+
+88
+00:08:21,290 --> 00:08:27,000
+عشان الكلاش يفهم مع بعضهوهذا الجزء الأخير بيكون اي
+
+89
+00:08:27,000 --> 00:08:33,700
+terminal ال carbon terminal فانا لما بدي اعمل
+
+90
+00:08:33,700 --> 00:08:38,120
+peptide سواء مكون من واحد او اتنين او تلاتة او
+
+91
+00:08:38,120 --> 00:08:44,800
+اربعة او خمسة amino acids سهل جدا عليا بدي اعمل N
+
+92
+00:08:44,800 --> 00:08:50,000
+terminal و بدي اعمل C terminal الان ما الوحدة
+
+93
+00:08:50,000 --> 00:08:59,730
+المتكررةماذا المختلف؟ ال R بناء
+
+94
+00:08:59,730 --> 00:09:04,870
+على ذلك لو انا الان باجي بقولكم والله انا بدي
+
+95
+00:09:04,870 --> 00:09:12,740
+بيبتايد من اربعة amino acids ارسمولياممكن هجيبلكوا
+
+96
+00:09:12,740 --> 00:09:16,520
+سؤال زيك في الامتحان أرسموني ال بيبتايد اللي من
+
+97
+00:09:16,520 --> 00:09:22,560
+أربعة amino acids اللي هم مثلا بهذا الشكل إجليسين
+
+98
+00:09:22,560 --> 00:09:32,270
+ألانين سيستين وفينل ألانينهتيجيوا تقولولا احنا
+
+99
+00:09:32,270 --> 00:09:37,010
+بنكون حافظين هدولة؟ احنا اتفقنا معكم ان الـR group
+
+100
+00:09:37,010 --> 00:09:40,870
+في الـGlycine H بتكون تحفظوها وفي الالانين مثل
+
+101
+00:09:40,870 --> 00:09:46,810
+بتكون تحفظوها وفي الستين CH2SH بتكون تعرفوها بالفن
+
+102
+00:09:46,810 --> 00:09:51,650
+الالانين CH2 فن اللي بعطيكوا بس بعطيكوا الـR الان
+
+103
+00:09:51,650 --> 00:09:57,750
+لو كان الكلام ارسم هذا الـpeptideكيف بدى ارسم هذا
+
+104
+00:09:57,750 --> 00:10:03,090
+البيبتايد؟ بدى اجي احط الهيكل تبع البيبتايد الهيكل
+
+105
+00:10:03,090 --> 00:10:07,270
+تبع البيبتايد اربع وحدات الان هيكونوا بهذا الشكل N
+
+106
+00:10:07,270 --> 00:10:14,270
+C C double bond O هى اول وحدة amino acid بعدين N C
+
+107
+00:10:14,270 --> 00:10:22,920
+C double bond O بعدين N C C double bond O بعدينN C
+
+108
+00:10:22,920 --> 00:10:27,040
+C double bond O الان هى صار عندى أربع وحدات
+
+109
+00:10:27,040 --> 00:10:36,060
+تتخيلوهم هذه وحدة تنتين تلاتة أربعة واضحة الفكرة
+
+110
+00:10:36,060 --> 00:10:43,100
+الان ايش بيظل عند المجموعة ال R اللى بتجينه من ال
+
+111
+00:10:43,100 --> 00:10:48,160
+glycine H و
+
+112
+00:10:48,160 --> 00:10:54,070
+ايش ال R اللى من القلانين مثلو إيش ال R اللي من
+
+113
+00:10:54,070 --> 00:11:01,770
+الستين؟ CH2SH و إيش ال R اللي من الفن الألانين؟
+
+114
+00:11:01,770 --> 00:11:08,730
+CH2 فنل واضح؟ لحظوا إذا أنا مجرد معرفتي الهيكل
+
+115
+00:11:08,730 --> 00:11:13,830
+بكرره بعد هيك أن أستكمل الكلام إنه هذه مثلا NH2،
+
+116
+00:11:13,830 --> 00:11:20,010
+إنه هذه CH إنه هذه NH1، إنه هذه CH، إنه هذه NH،
+
+117
+00:11:20,010 --> 00:11:25,760
+هذه CHعشان يكتمل الشكل العام بتاع الـ OH
+
+118
+00:11:30,660 --> 00:11:35,880
+واضح؟ OH أسد تيرمينال لاحظوا بهذا الشكل بإمكاني
+
+119
+00:11:35,880 --> 00:11:41,740
+أرسم أي بيبتايد فالبيبتايد معروف فيه هيكل كربوني
+
+120
+00:11:41,740 --> 00:11:48,460
+متكرر الهيكل الكربوني مع النيتروجين اللي هو NCCOO
+
+121
+00:11:48,460 --> 00:11:57,450
+NCCOO NCCOO NCCOO الاختلاف وين؟بال R groups طبعا
+
+122
+00:11:57,450 --> 00:12:02,570
+هذا الاختلاف بيخلي ال peptides و ال proteins
+
+123
+00:12:02,570 --> 00:12:09,050
+مايكونوش polymers حقيقيين لابد من معرفة إيش ال
+
+124
+00:12:09,050 --> 00:12:14,070
+sequence لهم لابد من معرفة ال sequence إيش تسلسلهم
+
+125
+00:12:14,070 --> 00:12:18,670
+الآن لو إجيت جبتلكوا سؤال مثلا قلتلكوا والله هذا
+
+126
+00:12:18,670 --> 00:12:24,710
+ال peptide يجلسين قلانين سستين فين القلانين؟مع هذا
+
+127
+00:12:24,710 --> 00:12:31,490
+الـpeptide جلبت أي شيء فيه ألانين إيجليسين سيستين
+
+128
+00:12:31,490 --> 00:12:35,670
+فين الألانين؟ غيرت أي شيء ما العلاقة بينهم؟ they
+
+129
+00:12:35,670 --> 00:12:39,470
+are structural isomers اختلفوا في مواقع الارتباط
+
+130
+00:12:39,470 --> 00:12:44,810
+كانت هنا مثلا اللي فيها المثل أعلى تاني وحدة صارت
+
+131
+00:12:44,810 --> 00:12:46,690
+اللي فيها المثل على الأولى و اللي فيها الأتش على
+
+132
+00:12:46,690 --> 00:12:51,670
+التانيةهذا تغير في الارتباط ولا لأ؟ اذا they are
+
+133
+00:12:51,670 --> 00:12:56,830
+structural isomers واضح؟ they are structural
+
+134
+00:12:56,830 --> 00:13:08,190
+isomers هذه الـ
+
+135
+00:13:08,190 --> 00:13:13,190
+N-terminal وهذه الـ C-terminalكل بيبتايد إله
+
+136
+00:13:13,190 --> 00:13:18,250
+unterminal وإله c-terminal لما ببدأ أكتب بكتب بهذا
+
+137
+00:13:18,250 --> 00:13:23,350
+الشكل واضح؟ إذا ذكرنا بيبتايد بهذا الشكل أي واحدة
+
+138
+00:13:23,350 --> 00:13:26,230
+كان بإمكانها تخلي c-terminal هان وunterminal هان
+
+139
+00:13:26,230 --> 00:13:29,290
+بس مش متعودين نشتغل زي هيك في ال biochemistry عشان
+
+140
+00:13:29,290 --> 00:13:32,210
+الكل يفهم على بعضه
+
+141
+00:13:49,240 --> 00:13:54,780
+لحظوا معاه هذا الكلام بيعمل شغل كتير مهمة لو أنا
+
+142
+00:13:54,780 --> 00:14:00,160
+مثلا جبت بس two amino acids و بدي أخليهم يتحدوا مع
+
+143
+00:14:00,160 --> 00:14:06,160
+بعض يعني glycine و alanine ممكن أخليهم يتحدوا يكون
+
+144
+00:14:06,160 --> 00:14:11,610
+ل glycine في الأولوالألانين بعده ال glycine اللي
+
+145
+00:14:11,610 --> 00:14:16,390
+فيه H والألانين اللي فيه مثل أو أخلي الألانين في
+
+146
+00:14:16,390 --> 00:14:20,790
+الأول وال glycine بعده في هذه الحالة لو أنا بدي
+
+147
+00:14:20,790 --> 00:14:26,450
+أسمي Hannah ببطاي بشكل دقيق بقول الأساس تبعه الجزء
+
+148
+00:14:26,450 --> 00:14:31,630
+الأخر اللي هو الألانين متصل في إيش ال glycine
+
+149
+00:14:31,630 --> 00:14:36,980
+بعتبره على شكل مجموعة بسميه glycineألانين مرات هذه
+
+150
+00:14:36,980 --> 00:14:43,860
+التسمية بنختصرها بنعملها بهذا الشكل إجلاي ألا خلاص
+
+151
+00:14:43,860 --> 00:14:49,040
+بنمشي بنقبلها لكن لو بدنا نحكي بشكل دقيق إجلاي سل
+
+152
+00:14:49,040 --> 00:14:55,020
+ألانين أو إجلاي ألا الآن هذا إيش أول إشي ببدأ فيه
+
+153
+00:14:55,020 --> 00:15:02,930
+ببدأ هيك و بضلني ماشي ألانين إجلاي سلفلو انا بدى
+
+154
+00:15:02,930 --> 00:15:08,690
+اعمل اتحاد بينهم اتنين مختلفين صار عندى مش ببتايد
+
+155
+00:15:08,690 --> 00:15:15,170
+واحد صار عندى اتنين هل يا ترى هذا لجليسي القلانين
+
+156
+00:15:15,170 --> 00:15:23,270
+هو نفسه القلانيل الجليسين اتأملوا فيه هنا مثلا ال
+
+157
+00:15:23,270 --> 00:15:29,270
+CH3 جنب مجموعة الحامضهنا الـ H جنب مجموعة الحامض،
+
+158
+00:15:29,270 --> 00:15:32,570
+هذا اختلاف في ال bonding ولا لا؟ هنا الـ H جنب
+
+159
+00:15:32,570 --> 00:15:37,770
+الأمين، هنا ال CH3 جنب الأمين، إذا هذولا
+
+160
+00:15:37,770 --> 00:15:41,410
+المجموعتين، يعني لو كنا متخيلين أن هذه H، انعكسوا
+
+161
+00:15:41,410 --> 00:15:47,460
+ولا لأ؟أذن هدولة Structural isomers فلو إجينا
+
+162
+00:15:47,460 --> 00:15:47,960
+سئلنا
+
+163
+00:16:13,350 --> 00:16:23,530
+الـ Glycine واضحة هذه النقطة؟ الآن نرجع للقصة
+
+164
+00:16:23,530 --> 00:16:30,750
+القديمة تبعتنا لو يا تورا إجينا و خلطنا
+
+165
+00:16:34,170 --> 00:16:39,470
+الجليسين مع الانين احنا بنخلط جزء واحد ولا عدد
+
+166
+00:16:39,470 --> 00:16:44,070
+كبير من الجزيئات عدد كبير من الجزيئات وقلنا لهم
+
+167
+00:16:44,070 --> 00:16:48,610
+يلا اتفاعلوا مع بعض و اعملولنا peptides كام ناتج
+
+168
+00:16:48,610 --> 00:16:49,810
+بنتوقع؟
+
+169
+00:16:51,890 --> 00:16:56,790
+اتذكروا لما كنا نخلط .. لما كنا نخلط على سبيل
+
+170
+00:16:56,790 --> 00:17:03,670
+المثال Methanol مع Ethanol عشان نحضر ال ether كام
+
+171
+00:17:03,670 --> 00:17:10,390
+ناتج كنا نطلع؟ تلاتة لما كنا نخلط Acetic acid مثلا
+
+172
+00:17:10,390 --> 00:17:15,930
+مع Benzoic acid عشان نطلع ال anhydride كام ناتج
+
+173
+00:17:15,930 --> 00:17:
+
+223
+00:21:12,960 --> 00:21:17,750
+عاملينهمش احنا ميزينهم ال glycine أحمر و ال
+
+224
+00:21:17,750 --> 00:21:22,410
+alanine أزرق هذه جزيئات كتيرة ممكن يتحد عندى
+
+225
+00:21:22,410 --> 00:21:27,290
+glycine مع glycine يعطوني بيبتايد بده يكون إيش هو
+
+226
+00:21:27,290 --> 00:21:35,270
+glycine glycine هذي H هذي H NCC double bond O NCC
+
+227
+00:21:35,270 --> 00:21:39,910
+double bond O وH وH يعني glycine مع glycine ممكن
+
+228
+00:21:39,910 --> 00:21:48,260
+يتحد عندى alanine مع alanineNCCWO NCCWO مثل و مثل
+
+229
+00:21:48,260 --> 00:21:54,040
+واضح هذا يكون أي بيبتايل ألانين ألانين ممكن يتحد
+
+230
+00:21:54,040 --> 00:22:01,180
+الآن إجليسين مع الألانين بهذا الشكل إجليسين ألانين
+
+231
+00:22:01,180 --> 00:22:10,550
+NCCWO NCCWO الهيكلة هذا إجليسين H هذا ألانينالان
+
+232
+00:22:10,550 --> 00:22:13,470
+الاتحاد يتم بطريقة تانية
+
+233
+00:22:20,780 --> 00:22:28,840
+يكون بهذا الشكل NCCWO NCCWO CH3HANA و N HANA هذا
+
+234
+00:22:28,840 --> 00:22:34,860
+إيش بده يكون الانين غلايسين ال بيبتايد الآن اتطلع
+
+235
+00:22:34,860 --> 00:22:40,840
+عليهم بالتأمل هل فيهم أشياء بتشبه بعض طبعا لو
+
+236
+00:22:40,840 --> 00:22:44,760
+سألتكوا ما العلاقة بين غلايسين غلايسين و الانين
+
+237
+00:22:44,760 --> 00:22:50,520
+انا الانينthey are .. استعملولي كلمات كيميائية
+
+238
+00:22:50,520 --> 00:22:56,040
+they are different compounds مراكبات مختلفة، لأن
+
+239
+00:22:56,040 --> 00:22:59,500
+أنا اتش و اتش و انا مثل و مثلها، دي مراكبات مختلفة
+
+240
+00:22:59,500 --> 00:23:03,700
+إجليسين إجليسين و ألانين ألانين they are different
+
+241
+00:23:03,700 --> 00:23:07,620
+compounds لو قلتلكوا ما العلاقة بين إجليسين
+
+242
+00:23:07,620 --> 00:23:11,950
+إجليسين و إجليسين ألانين؟they are different
+
+243
+00:23:11,950 --> 00:23:14,570
+compounds هان اتش و اتش و هان اتش و مثل صيغة
+
+244
+00:23:14,570 --> 00:23:18,850
+مختلفة كذلك الحال لو بدأ اقول الالانين الالانين و
+
+245
+00:23:18,850 --> 00:23:19,950
+الالانين الالانين الالانين الالانين الالانين
+
+246
+00:23:19,950 --> 00:23:20,490
+الالانين الالانين الالانين الالانين الالانين
+
+247
+00:23:20,490 --> 00:23:22,850
+الالانين الالانين الالانين الالانين الالانين
+
+248
+00:23:22,850 --> 00:23:25,270
+الالانين الالانين الالانين الالانين الالانين
+
+249
+00:23:25,270 --> 00:23:29,230
+الالانين الالانين الالانين الالانين الالانين
+
+250
+00:23:29,230 --> 00:23:30,250
+الالانين الالانين الالانين الالانين الالانين
+
+251
+00:23:30,250 --> 00:23:30,610
+الالانين الالانين الالانين الالانين الالانين
+
+252
+00:23:30,610 --> 00:23:36,470
+الالانين الالانين الالانين الالان
+
+253
+00:23:36,500 --> 00:23:40,040
+الذرات تماما يعني لو حسبنا على الكمبيوتر ال
+
+254
+00:23:40,040 --> 00:23:43,420
+molecular weight لهذا و لهذا same number of atoms
+
+255
+00:23:43,420 --> 00:23:46,980
+same molecular weight بس الفكرة الاختلاف ان هنا
+
+256
+00:23:46,980 --> 00:23:49,920
+اجت ال H و هنا ال مثل هنا اجت ال مثل و هنا ال H
+
+257
+00:23:49,920 --> 00:23:54,400
+واضح ان they are different compounds يعني هذه ال H
+
+258
+00:23:54,400 --> 00:23:58,280
+محصورة بين C double bond O و N H 2 و المثل بين
+
+259
+00:23:58,280 --> 00:24:04,700
+acid و N H هنا ال H بين acid و N Hواضح الاختلاف
+
+260
+00:24:04,700 --> 00:24:09,420
+بناء على ذلك لو سألنا ان mixing two amino acids
+
+261
+00:24:09,420 --> 00:24:16,620
+together in fact will produce fourproducts تمام؟
+
+262
+00:24:16,620 --> 00:24:23,300
+هيعطي أربع نواتج طبعا هتصير عندنا مشكلة هتصير
+
+263
+00:24:23,300 --> 00:24:27,640
+عندنا مشكلة يعني لو الناس كانوا بدهم لجليسين
+
+264
+00:24:27,640 --> 00:24:31,660
+جليسين هيسخنوا الجليسين مع نفسه بظروف تفاعل يتفاعل
+
+265
+00:24:31,660 --> 00:24:37,220
+بدي ألانين ألانين نفس الفكرة لكن لو كنت بدي أحضر
+
+266
+00:24:37,220 --> 00:24:44,260
+جليسين ألانينبدي طريقة معينة الان هذه الطريقة مش
+
+267
+00:24:44,260 --> 00:24:48,380
+مقبولة كيميائيا اصدقائك بتقولوا اخلطوهم وافصلوهم
+
+268
+00:24:48,380 --> 00:24:52,460
+اول اش اذا خلطناهم هنطلع مش ناتجين اربعة اربعة
+
+269
+00:24:52,460 --> 00:24:57,660
+الان في كيميائي بيحط حاله يقعد يفصل اربعة
+
+270
+00:24:57,660 --> 00:25:01,240
+compounds عن بعض اللي بيدخل المختبر وبيعرف غلبة
+
+271
+00:25:01,240 --> 00:25:05,420
+الشغل لايمكن يعملها لايمكن يعملها وبناء على ذلك
+
+272
+00:25:05,420 --> 00:25:14,780
+انا فعلا فعلا بدي طريقةفقط اطلع لي ناتج واحد يعني
+
+273
+00:25:14,780 --> 00:25:22,380
+هاي هدول المركباتفكروا معي قداش الكيميا منطقها هو
+
+274
+00:25:22,380 --> 00:25:28,260
+منطق إيش؟ هو منطق حياة .. منطق حياة شايفين؟ هدولة
+
+275
+00:25:28,260 --> 00:25:32,040
+المركبات الأربعة أنا خلطهم و افترضوا أخلط من هذا
+
+276
+00:25:32,040 --> 00:25:35,420
+مليون جزيئة و من هذا مليون جزيئة بدي أفعلهم أي
+
+277
+00:25:35,420 --> 00:25:39,460
+واحد اللي بدكم إياه أنتم يطلع إجلايسين ألانين يعني
+
+278
+00:25:39,460 --> 00:25:45,380
+اللي زي هيك و فقط واضح؟أنا بدي أفرجيكوا كيف بدي
+
+279
+00:25:45,380 --> 00:25:52,120
+أعملها كإنها لعبة برا ما أحكي عن إيش عن الكيميا
+
+280
+00:25:52,120 --> 00:25:56,980
+يعني أنا بدي أتعامل معها كإنها لعبة بدي أعطي لشخص
+
+281
+00:25:56,980 --> 00:26:00,680
+معين هدول أقوله اخلط بحيث أنه لما تيجي تشبكهم في
+
+282
+00:26:00,680 --> 00:26:04,660
+بعض ما يطلعش إلا هذا المركب اللي أنتوا طلبته
+
+283
+00:26:04,660 --> 00:26:09,440
+الأحمر و الأزرق تمام؟ كل هذا الكلام ممكن نعمله
+
+284
+00:26:09,440 --> 00:26:13,600
+بورقة clinics صغيرة إيش رأيكوا؟
+
+285
+00:26:16,190 --> 00:26:21,210
+ورقة كلينكس الصغيرة ايش اللي بدنا نعمله احنا بنيجي
+
+286
+00:26:21,210 --> 00:26:26,590
+هذا بنعمله protection من هنا بنعمله حماية من هنا
+
+287
+00:26:26,590 --> 00:26:30,910
+ممنوع انت تتفعل بدنا ياك تتفعل من ال nitrogen
+
+288
+00:26:30,910 --> 00:26:34,090
+سكرنا مجموعة الحامض عشان مايجيش هذا يتفعل معاه من
+
+289
+00:26:34,090 --> 00:26:39,510
+هنا لاحظوا هذا الغلبان جاي يتفعل معاه راضي يتفعل؟
+
+290
+00:26:39,510 --> 00:26:43,950
+شوفوا قبل ال protection قبل الحماية لو هذا إيجي
+
+291
+00:26:43,950 --> 00:26:50,400
+يتفعلكان بتفاعل، الآن بعد ما عملت الـ protection
+
+292
+00:26:50,400 --> 00:26:57,800
+إجا اتفاعلمش قادر يتفاعل سكرت هذا الجزء إذا بجعل
+
+293
+00:26:57,800 --> 00:27:02,880
+كل هدولة بعمل protection لل acid بإضافة مجموعة
+
+294
+00:27:02,880 --> 00:27:07,460
+كيميائية اتسكر هذا الجزء هذا بطل يتفاعل من هنا
+
+295
+00:27:07,460 --> 00:27:13,820
+ممتاز لسه عندي خوف ان هدول يتفاعلوا مع بعض الان
+
+296
+00:27:13,820 --> 00:27:18,800
+هدول هدين يتفاعلوا مع بعض انا منعت نص المشكلة الان
+
+297
+00:27:18,800 --> 00:27:23,530
+هذا من وين بدي امنعه يتفاعل؟من ال nitrogen باجي
+
+298
+00:27:23,530 --> 00:27:27,350
+بعمله protection من الطرف التاني عشان مايقدرش
+
+299
+00:27:27,350 --> 00:27:35,050
+يتفاعل منها أنا بنعمله شوية protection برضه هاي
+
+300
+00:27:35,050 --> 00:27:40,270
+بأمل أنها تكون عمليتها ال protection هذه زبطت
+
+301
+00:27:40,270 --> 00:27:41,670
+استعمل
+
+302
+00:27:46,120 --> 00:27:51,860
+بهمش انتوا في النهاية تصللكوا الفكرة ان الكيميائي
+
+303
+00:27:51,860 --> 00:27:57,980
+والبني آدم والطبيب لما بده يفكر بحالة مشكلة بده
+
+304
+00:27:57,980 --> 00:28:01,620
+يكون عنده أصول العلم لكن بده يفكر بمنطق الدنيا
+
+305
+00:28:01,620 --> 00:28:06,320
+بمنطق الدنيا يعني إليزاروف إليزاروف لما عمل
+
+306
+00:28:06,320 --> 00:28:11,040
+العملية الجراحية تبعته اللي بطول فيها عظام الساق
+
+307
+00:28:11,040 --> 00:28:15,320
+الناس اللي عندهم ساق أكثر من التانيةاللي فكر فيه
+
+308
+00:28:15,320 --> 00:28:20,420
+انه ايجي على العضمة جشرها و حط حديد هان و هان و
+
+309
+00:28:20,420 --> 00:28:25,040
+صار كل ساعتين اطول نص مل نص مل لانه مقدرش يسحب كل
+
+310
+00:28:25,040 --> 00:28:29,780
+شيء عظامه اعصابه اشي مرة واحدة عمدا أسبوعين بيضلوا
+
+311
+00:28:29,780 --> 00:28:34,020
+يسحب يسحب او بيطول العضمة كده؟ سبعة تمانية سانتي
+
+312
+00:28:34,020 --> 00:28:40,840
+بيعمل مسوافر عملية شهيرة جدا ال الازاروفالان
+
+313
+00:28:40,840 --> 00:28:45,720
+الظروف شاب تبع البسكليتات كيف بيشتغلوا بعمل العجال
+
+314
+00:28:45,720 --> 00:28:51,380
+واخذ منه فكرة كيف يعمل العملية واضحة الفكرة؟ الان
+
+315
+00:28:51,380 --> 00:28:58,120
+هاي انا عملت protection هنا لل acid part وهنا لل
+
+316
+00:28:58,120 --> 00:29:03,320
+amino part انه مش قادر يتفاعل من عند ال nitrogen
+
+317
+00:29:03,320 --> 00:29:09,740
+الان بدي اخلطهم و اقولوا متفاعلوا زي ما بدكمهيجي
+
+318
+00:29:09,740 --> 00:29:14,060
+يتفاعلوا اول اشي هذا هيجي يتفاعل من هنا هيلاجي ايش
+
+319
+00:29:14,060 --> 00:29:18,880
+امسكّر ال nitrogen تبعته من هنا امسكّر ال nitrogen
+
+320
+00:29:18,880 --> 00:29:24,180
+هذا هيجي يتفاعل مع هذا امسكّر ال CO هذا يتفاعل مع
+
+321
+00:29:24,180 --> 00:29:29,620
+هذا امسكّر ال CO لغاية كل هذه التفاعلات الان هذا
+
+322
+00:29:29,620 --> 00:29:36,820
+بيجي يتفاعل مع هذا امسكّر هذا بيجي يتفاعل مع هذا
+
+323
+00:29:38,200 --> 00:29:45,500
+طلعت one product شوف كيف .. هايوة one product هيك
+
+324
+00:29:45,500 --> 00:29:50,500
+ممكن .. الآن هيكمش ممكن اتنين زرق مش ممكن اتنين
+
+325
+00:29:50,500 --> 00:29:55,500
+حمر مش ممكن هذه الفكرة هي اللي عملوها الان كل اللي
+
+326
+00:29:55,500 --> 00:29:59,500
+بدنا نعمله اننا بدنا نكتب في المعادلة حطوا هنا حرف
+
+327
+00:29:59,500 --> 00:30:04,520
+بي بي ايش يعني بي يعني protecting group لما تكونوا
+
+328
+00:30:04,520 --> 00:30:08,000
+اعملوا هذا protected او اعملوا هذا protected لما
+
+329
+00:30:08,000 --> 00:30:12,140
+تشوفوا ال بي يعني من هنا ممنوع تتفاعلمجموعة
+
+330
+00:30:12,140 --> 00:30:16,120
+كيميائية صغيرة بنضيفها بتخلي هذا مثبت مابتفعلش مش
+
+331
+00:30:16,120 --> 00:30:21,980
+هندخل بتفاصيل أكتر من هي وجدها ماعندي إلا هذه
+
+332
+00:30:21,980 --> 00:30:25,780
+الإمكانية تشتغل هذا مش هيقدر يتفعل مع نفسه ولا هذا
+
+333
+00:30:25,780 --> 00:30:29,400
+هيتفعل مع نفسه هذا هيتفعل مع هذا بس one product
+
+334
+00:30:29,400 --> 00:30:37,260
+طلعت ال glycine ألانين واضحة الفكرة وهذا هو اللي
+
+335
+00:30:37,260 --> 00:30:38,220
+موجود يمكن
+
+336
+00:30:40,820 --> 00:30:45,960
+في ال slide يمكن متأخرة عندكم اربع خمسة slides
+
+337
+00:30:45,960 --> 00:30:52,520
+لاحظوا هاي جاب amino acid one سماه وعمل protection
+
+338
+00:30:52,520 --> 00:30:58,740
+لمجموعة معينة و جاب ال amino acid two وعمل
+
+339
+00:30:58,740 --> 00:31:02,620
+protection لمجموعة تانية نفس الفكرة اللي احنا
+
+340
+00:31:02,620 --> 00:31:06,280
+حكيناها الآن هذا بطل يتفعل من هنا هذا بتفعلش من
+
+341
+00:31:06,280 --> 00:31:10,850
+هنا مافيش غير هذا الجزءمع هذا الجزء بده يتفاعل
+
+342
+00:31:10,850 --> 00:31:17,010
+فبدل ما أطلع four different compounds بطلع one
+
+343
+00:31:17,010 --> 00:31:22,230
+طبعا في هذه الحالة هين طلعت بيبتايد الآن بعد ما
+
+344
+00:31:22,230 --> 00:31:26,090
+طلعته بتفاعل كيميائي بسيط بقدر أشيل هذا ال
+
+345
+00:31:26,090 --> 00:31:30,730
+protection أو هذا ال protection الآن تخيلوا لو كنا
+
+346
+00:31:30,730 --> 00:31:35,910
+بدنا نطول ال peptide يعني مش بس اتنين بد من هنا ما
+
+347
+00:31:35,910 --> 00:31:41,370
+يتفاعلشبخلّي هذا الـ protection بدي من هنا يتفاعل
+
+348
+00:31:41,370 --> 00:31:50,370
+بشيل هذا و بجيبله amino acid ال nitrogen تبعته not
+
+349
+00:31:50,370 --> 00:31:53,430
+protected و ال acid protected عشان مايتفعلش مع
+
+350
+00:31:53,430 --> 00:31:58,150
+بعضه اللي جاي جديد بيجي يتفعل هنا واحد اتنين تلاتة
+
+351
+00:31:58,150 --> 00:32:03,270
+اربعة ممكن في الآخر يتحضروا خمسة عشر و عشرين و
+
+352
+00:32:03,270 --> 00:32:09,540
+تلاتين جد ما بدكم و بالترتيببالترتيب بتحضره تمام
+
+353
+00:32:09,540 --> 00:32:13,220
+هذا
+
+354
+00:32:13,220 --> 00:32:20,160
+الكلام كله موجود ثانية أخدها لحظوا
+
+355
+00:32:20,160 --> 00:32:27,460
+على سبيل المثال هاي مركب اتخيلوا هذا عملوله
+
+356
+00:32:27,460 --> 00:32:28,100
+sequencing
+
+357
+00:32:31,070 --> 00:32:35,610
+عرفوا تفاصيله هنشوف طبعا كيف بعد شوية بنحلل المركب
+
+358
+00:32:35,610 --> 00:32:39,050
+نعرف ال amino acids إيجليسين إليوسين فالين
+
+359
+00:32:39,050 --> 00:32:44,870
+إيجلوتاميكاس وهكذا هذا الانسولين هذا الانسولين
+
+360
+00:32:44,870 --> 00:32:51,030
+سلسلتين من ال إيش ال peptides بيحللوه بيعرفوه واحد
+
+361
+00:32:51,030 --> 00:32:58,130
+واحد لاحظوا مابنقدرش زي السكر نعمل إيش شغلة to the
+
+362
+00:32:58,130 --> 00:33:02,700
+end لأ في إيش اسمهسيكوانس في ال .. بيبتايتز و في
+
+363
+00:33:02,700 --> 00:33:08,000
+الأمان هاي هذا مركّب الراجل اللي حضره أخد عليه
+
+364
+00:33:08,000 --> 00:33:13,600
+جائزة نوبل في الكيميا سنة الخمسة و خمسين هذا
+
+365
+00:33:13,600 --> 00:33:22,780
+Vincent de Vignod أخد عليه جائزة نوبل هذا هرمون من
+
+366
+00:33:22,780 --> 00:33:29,310
+تسعةأمينو أسد حضرهم من مرتبين سيستين تايروسين
+
+367
+00:33:29,310 --> 00:33:33,030
+إليوسين كذا أسبرتك أسستين برولين ليوسين إجلايسين
+
+368
+00:33:33,030 --> 00:33:37,750
+أعدهم واحد اتنين تلاتة أربعة خمس ستة سبعة تمانية
+
+369
+00:33:37,750 --> 00:33:42,970
+تسعة هنا في أس و أس ارتبطوا مع بعض مش موضوعنا ناخد
+
+370
+00:33:42,970 --> 00:33:46,630
+الديس الفايدمون بس هدول كام أمينو أسد في المحصلة
+
+371
+00:33:46,630 --> 00:33:52,590
+واحد اتنين تلاتة أربعة خمسة ستة سبعة تمانية تسعة
+
+372
+00:33:52,590 --> 00:33:59,330
+حضرهم من مرتبينبهذه الطريقة واضح؟ هذا عبارة عن
+
+373
+00:33:59,330 --> 00:34:05,790
+هرمون اسمه oxytocin مار عليكم؟ هرمون السعادة الله
+
+374
+00:34:05,790 --> 00:34:11,380
+يسعدكمالناس بيسموه هرمون السعادة فعلا، ليش؟ لأنهم
+
+375
+00:34:11,380 --> 00:34:14,640
+انتبعون علم النفس وغيره، بيقولوا هذا اللي بتتحكم
+
+376
+00:34:14,640 --> 00:34:19,440
+بالانفعالات وقصص السعادة والحب وكل إشي برتوب هذا
+
+377
+00:34:19,440 --> 00:34:24,160
+الهرمون طبعا إله تطبيقات تانية .. إله تطبيقات
+
+378
+00:34:24,160 --> 00:34:28,720
+تانية هو في الأصل بيطلع من ال posterior pituitary
+
+379
+00:34:28,720 --> 00:34:33,060
+gland يمكن بتسموها الغضب الكذرية ولا إيش .. هذا
+
+380
+00:34:33,060 --> 00:34:40,320
+بتحكم في القبضات الرحم في لحظة الولادةit regulates
+
+381
+00:34:40,320 --> 00:34:46,560
+uterine contraction and lactation وفي الرضاعة may
+
+382
+00:34:46,560 --> 00:34:49,360
+be administered .. إيش معنى administered في لغة
+
+383
+00:34:49,360 --> 00:34:54,800
+العلم الطبي؟ يُعطى كعلاج أو يوصف واضح؟ when it is
+
+384
+00:34:54,800 --> 00:34:58,440
+necessary to induce labor at childbirth يعني عشان
+
+385
+00:34:58,440 --> 00:35:03,750
+يزيد الطلجواضح؟ وبنفس الوقت زي ما حكينا إيه له
+
+386
+00:35:03,750 --> 00:35:09,670
+علاقة بالانفعالات الآن لاحظوا بيبتعد وحضر أول إشي
+
+387
+00:35:09,670 --> 00:35:13,570
+قبل ما يحضر إيش كان لازم نفصله من مصدره الطبيعي
+
+388
+00:35:13,570 --> 00:35:19,210
+ونعرف إيش ال sequence تبعته بعد ما نعرف ال
+
+389
+00:35:19,210 --> 00:35:23,230
+sequence ال road نقدر نعملها إذا صار عند أنا في
+
+390
+00:35:23,230 --> 00:35:27,850
+المنطقة شغلتين معرفة ال sequence و التحضير يمكن
+
+391
+00:35:27,850 --> 00:35:32,610
+احنا بدأنا الآنبفكرة التحضير لكن لسه ماحكيناش عن
+
+392
+00:35:32,610 --> 00:35:37,950
+فكرة إيش ال sequence فكرة ال sequence فكرة طويلة و
+
+393
+00:35:37,950 --> 00:35:46,110
+أخدت وقت طبعا من العلماء لكن
+
+394
+00:35:46,110 --> 00:35:50
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d3ba3582aa4461c51174e3aa957adfa003c0e91d
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_raw.srt
@@ -0,0 +1,1740 @@
+1
+00:00:18,360 --> 00:00:22,720
+بسم الله الرحمن الرحيم المرة الماضية بدنا نتكلم في
+
+2
+00:00:22,720 --> 00:00:29,780
+موضوع البروتينات وكان الأساس ان نتعرف على الأحماض
+
+3
+00:00:29,780 --> 00:00:34,200
+الأمينية ال amino acids اتعرفنا عليهم و اتعرفنا
+
+4
+00:00:34,200 --> 00:00:38,560
+طبعا كيف بيكونوا بالوسط الحامض أو القاعدى كيف
+
+5
+00:00:38,560 --> 00:00:44,280
+بتتأثر الشحنة تبعتهمبال بي اتش وهذا الكلام بيدى
+
+6
+00:00:44,280 --> 00:00:49,560
+الى طريقة عملية لفصلهم عن بعضهم البعض اعتمادا على
+
+7
+00:00:49,560 --> 00:00:54,380
+اختلاف ال بي اتش اللى هي فكرة ال Electrophoresis
+
+8
+00:00:54,380 --> 00:01:01,420
+الان اذا بنستمر في الموضوع لو اجينا بدنا نتكلم على
+
+9
+00:01:01,420 --> 00:01:07,460
+تفاعلات الأحماض الأمينية طبعا اذا قلنا amino acids
+
+10
+00:01:07,460 --> 00:01:13,680
+كلمتين aminoاللي هي الـ Amines اللي أخدناهم في
+
+11
+00:01:13,680 --> 00:01:20,720
+الفصل شبطر 11 و Assets الأحمد اللي أخدناهم في شبطر
+
+12
+00:01:20,720 --> 00:01:26,640
+10 إذا تفاعلاتهم هي تفاعلات الـ Amines و الأحمد
+
+13
+00:01:26,640 --> 00:01:34,030
+يعني أي تفاعل كنا بناخده للأمينفي السابق في ال
+
+14
+00:01:34,030 --> 00:01:37,850
+organic العادية هيتفاعل ال amino acids فيه من خلال
+
+15
+00:01:37,850 --> 00:01:42,820
+ال amino group أي تفاعل كنا بناخده لل acidهيكون
+
+16
+00:01:42,820 --> 00:01:48,060
+نفس الاشي مع ال amino acids يعني مثلا عندكوا جملة
+
+17
+00:01:48,060 --> 00:01:54,600
+عامة انه acid زائد alcohol ايش بيعطينا Easter بناء
+
+18
+00:01:54,600 --> 00:01:59,420
+على ذلك ال amino acids فيهم acids حتى لو كانوا على
+
+19
+00:01:59,420 --> 00:02:04,180
+شكل ال soul تبعهم بيظلوا acids هذا ال acid لو اجت
+
+20
+00:02:04,180 --> 00:02:09,140
+فعلته مع alcohol هاي جزء ال acid هاي ال alcohol
+
+21
+00:02:10,310 --> 00:02:16,150
+ماذا سيعطيني إيستار سيصبح C double bond O OR أو
+
+22
+00:02:16,150 --> 00:02:22,830
+CO2 R إذا هذا مثال على أنه تفاعل كحامض أسد زائد
+
+23
+00:02:22,830 --> 00:02:28,430
+ألكوهول إيستار ليس هناك شيء جديد كذلك الحالة لو
+
+24
+00:02:28,430 --> 00:02:32,110
+إحنا جينا على ال amino group حتى لو كنا كاتبينها
+
+25
+00:02:32,110 --> 00:02:36,590
+على شكل NH3 بلس إحنا مجرد ما نفعله مع base ترجع
+
+26
+00:02:36,590 --> 00:02:37,710
+نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو
+
+27
+00:02:37,710 --> 00:02:37,710
+نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو
+
+28
+00:02:37,710 --> 00:02:37,710
+نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نح
+
+29
+00:02:37,830 --> 00:02:41,930
+عادية لو اتش هنا قولنا هذا في النهاية ان اتش توحت
+
+30
+00:02:41,930 --> 00:02:46,970
+صفة بدنا نفعلها مع acid chloride او مع ايستر او مع
+
+31
+00:02:46,970 --> 00:02:50,330
+acid anhydride كيف كان الأمين يتفاعل مع ال acid
+
+32
+00:02:50,330 --> 00:02:57,310
+chloride بالإبدال بهذا الشكل و يعمل عملية إبدال في
+
+33
+00:02:57,310 --> 00:03:03,030
+هذه الحالة هيعطيني أميدفهذه الحالة هيعطيني amide
+
+34
+00:03:03,030 --> 00:03:09,170
+واضح هاي ال amide N H C double bond O واضح ففكرة
+
+35
+00:03:09,170 --> 00:03:14,510
+التفاعلات ال amino acids هي فكرة بسيطة للي فيهم
+
+36
+00:03:14,510 --> 00:03:18,830
+سابقا تفاعلات ال amines ولي فيهم سابقا تفاعلات ال
+
+37
+00:03:18,830 --> 00:03:24,410
+acids يمكن أخدتوا انتوا ان ammonia او amine زائد
+
+38
+00:03:24,410 --> 00:03:31,370
+acid شو كان بيعطيني بشكل عامأمد تمام وبناء على ذلك
+
+39
+00:03:31,370 --> 00:03:37,690
+هذه الفكرة أيضا ممكن ناخدها لكن من خلال أن الفاعل
+
+40
+00:03:37,690 --> 00:03:44,640
+جزيئين من ال amino acids مع بعض و من بعضجزء ناخد
+
+41
+00:03:44,640 --> 00:03:51,320
+منه جزء ناخد منه مجموعة الـ nitrogen الـ NH2 و جزء
+
+42
+00:03:51,320 --> 00:03:56,860
+ناخد منه جزء ال acid واضح فلما نيجي نقول NH2 زي ال
+
+43
+00:03:56,860 --> 00:04:02,840
+acid اتفاعلوا شو هيعطوني امد اذا two amino acids
+
+44
+00:04:02,840 --> 00:04:08,640
+react with each other to form amides واضح هذا
+
+45
+00:04:08,640 --> 00:04:13,510
+الكلام اللي موجود هنايعني لو أنا اتطلعت على هذا
+
+46
+00:04:13,510 --> 00:04:18,770
+المركب اللي بيطلع عندى هذا أصلا كان NH2 Amino Acid
+
+47
+00:04:18,770 --> 00:04:22,970
+و هذا ال Amino Acid التانى هذا Amino Acid و هذا
+
+48
+00:04:22,970 --> 00:04:28,850
+Amino Acid كان إيش؟ C double bond O OH لما ال NH2
+
+49
+00:04:28,850 --> 00:04:36,760
+إجت اتفاعلت هنا شو عملت؟ طردت؟الـ OH وانخصم من هنا
+
+50
+00:04:36,760 --> 00:04:43,800
+H OH مع H اذا صفينا على هذا الشكل هاي ال two amino
+
+51
+00:04:43,800 --> 00:04:49,500
+acids اتحدوا مع بعض عملوا قمد C double bond O NH
+
+52
+00:04:49,500 --> 00:04:53,520
+وين الرابطة الجديدة اللي اتكونت بين ال two amino
+
+53
+00:04:53,520 --> 00:05:05,080
+acids؟ هذه هذا كان نهاية الجزء الأولان اتش تو وكان
+
+54
+00:05:05,080 --> 00:05:09,220
+هذا الجزء نهايته سيضا بالبوند او او اتش الان اتش
+
+55
+00:05:09,220 --> 00:05:12,220
+اتصلت بالسيضا بالبوند او او اتش اذا هذه الرابطة
+
+56
+00:05:12,220 --> 00:05:16,800
+اللي اتكونت اللي هي الاميد بوند الان لأنه هنا انا
+
+57
+00:05:16,800 --> 00:05:21,820
+بابدأ ادمج amino acids مع بعضهم البعض لتكوين
+
+58
+00:05:21,820 --> 00:05:25,580
+بيبتايد هذه رابطة هنا اتكونت و رابط هنا اتكونت هذه
+
+59
+00:05:25,580 --> 00:05:30,860
+الاميد بوند بنصير احنا نعطيها اسم بيبتايد بوندواضح
+
+60
+00:05:30,860 --> 00:05:36,140
+فلما نقول ال peptide bond هي حقيقة ال amide bond
+
+61
+00:05:36,140 --> 00:05:40,760
+واضح لكن لأنه انا لما بفعل two amino acids او
+
+62
+00:05:40,760 --> 00:05:46,680
+three amino acids بكون ايش؟ peptide و لو كبروا
+
+63
+00:05:46,680 --> 00:05:52,080
+كتير بصيروا ايش؟ protein واضح فال peptides و ال
+
+64
+00:05:52,080 --> 00:05:57,060
+proteins فيهم ال amide bond واضح او بنسميها في هذه
+
+65
+00:05:57,060 --> 00:06:02,470
+الحالة تخصيصاببتايت بوند فلو قلنا مثلا سؤال ببتايت
+
+66
+00:06:02,470 --> 00:06:06,330
+بوند is an amide bond طبعا هي امد see double bond
+
+67
+00:06:06,330 --> 00:06:13,090
+O and H طبعا هيكون فيها كل خواص الامدز انه هتكون
+
+68
+00:06:13,090 --> 00:06:18,490
+هذه المنطقة كامد reactive ولا unreactive
+
+69
+00:06:18,490 --> 00:06:23,850
+unreactive احنا قلنا الكلمة الأساسية المميزة
+
+70
+00:06:23,850 --> 00:06:29,670
+للامدز they are unreactiveو بناء على ذلك حتى ال
+
+71
+00:06:29,670 --> 00:06:34,830
+hydrolysis تبعهم بيكون سهل ولا صعبصعب و لذلك بعد
+
+72
+00:06:34,830 --> 00:06:38,130
+شوية لما تيجوا تاخدوا protein على سبيل المثال
+
+73
+00:06:38,130 --> 00:06:43,290
+امكون من amino acids و اقول بدي احلل هذا ال
+
+74
+00:06:43,290 --> 00:06:49,490
+protein لالمفردات تبعته بيكون الجواب و الله اغليه
+
+75
+00:06:49,490 --> 00:06:56,110
+في وسط حامض مركز مثلا لمدة 24 ساعة و هو يغلي عشان
+
+76
+00:06:56,110 --> 00:07:02,230
+تقدر تكسر ال ايش ال amides bonds هذي شروط سهلة ولا
+
+77
+00:07:02,230 --> 00:07:08,990
+صعبة؟شروط صعبة الان لما احنا بنعمل اتحاد ل two
+
+78
+00:07:08,990 --> 00:07:13,490
+amino acids بنكون ال peptide bond ممكن نحط كمان
+
+79
+00:07:13,490 --> 00:07:18,050
+amino acid ها بالتأكيد ممكن كمان نستمر نجيب مجموعة
+
+80
+00:07:18,050 --> 00:07:24,370
+amino و هكذا الان ال peptide عادة لما احنا بنكونه
+
+81
+00:07:24,370 --> 00:07:32,070
+بنلاحظ انه في شيء مشترك في هيكل عام MCC double
+
+82
+00:07:32,070 --> 00:07:37,540
+bond Oهذا الهيكل العام إيش ماله؟ متكرر يعني هاي في
+
+83
+00:07:37,540 --> 00:07:44,780
+عندى هنا N C C double bond O بعد شو بيجيني كمان
+
+84
+00:07:44,780 --> 00:07:53,670
+مرة؟ NC C double bond O لو عملت كمان شو هيجيني N C
+
+85
+00:07:53,670 --> 00:07:59,630
+C double bond O و هكذا واضحة هذه النقطة فهذا شيء
+
+86
+00:07:59,630 --> 00:08:04,910
+مشترك في ال peptides الان اللي بيكون عادة على
+
+87
+00:08:04,910 --> 00:08:10,890
+الإيد الشمال بالنسبة لكمبنبدأ منه بنقول ان هذا
+
+88
+00:08:10,890 --> 00:08:16,670
+الجزء بيمثل ال unterminal of the peptide يعني
+
+89
+00:08:16,670 --> 00:08:21,290
+الطرف اللي فيه نيتروجين من ال peptide بنرسمه زيكي
+
+90
+00:08:21,290 --> 00:08:27,000
+عشان الكلاش يفهم مع بعضهوهذا الجزء الأخير بيكون اي
+
+91
+00:08:27,000 --> 00:08:33,700
+terminal ال carbon terminal فانا لما بدي اعمل
+
+92
+00:08:33,700 --> 00:08:38,120
+peptide سواء مكون من واحد او اتنين او تلاتة او
+
+93
+00:08:38,120 --> 00:08:44,800
+اربعة او خمسة amino acids سهل جدا عليا بدي اعمل N
+
+94
+00:08:44,800 --> 00:08:50,000
+terminal و بدي اعمل C terminal الان ما الوحدة
+
+95
+00:08:50,000 --> 00:08:59,730
+المتكررةماذا المختلف؟ ال R بناء
+
+96
+00:08:59,730 --> 00:09:04,870
+على ذلك لو انا الان باجي بقولكم والله انا بدي
+
+97
+00:09:04,870 --> 00:09:12,740
+بيبتايد من اربعة amino acids ارسمولياممكن هجيبلكوا
+
+98
+00:09:12,740 --> 00:09:16,520
+سؤال زيك في الامتحان أرسموني ال بيبتايد اللي من
+
+99
+00:09:16,520 --> 00:09:22,560
+أربعة amino acids اللي هم مثلا بهذا الشكل إجليسين
+
+100
+00:09:22,560 --> 00:09:32,270
+ألانين سيستين وفينل ألانينهتيجيوا تقولولا احنا
+
+101
+00:09:32,270 --> 00:09:37,010
+بنكون حافظين هدولة؟ احنا اتفقنا معكم ان الـR group
+
+102
+00:09:37,010 --> 00:09:40,870
+في الـGlycine H بتكون تحفظوها وفي الالانين مثل
+
+103
+00:09:40,870 --> 00:09:46,810
+بتكون تحفظوها وفي الستين CH2SH بتكون تعرفوها بالفن
+
+104
+00:09:46,810 --> 00:09:51,650
+الالانين CH2 فن اللي بعطيكوا بس بعطيكوا الـR الان
+
+105
+00:09:51,650 --> 00:09:57,750
+لو كان الكلام ارسم هذا الـpeptideكيف بدى ارسم هذا
+
+106
+00:09:57,750 --> 00:10:03,090
+البيبتايد؟ بدى اجي احط الهيكل تبع البيبتايد الهيكل
+
+107
+00:10:03,090 --> 00:10:07,270
+تبع البيبتايد اربع وحدات الان هيكونوا بهذا الشكل N
+
+108
+00:10:07,270 --> 00:10:14,270
+C C double bond O هى اول وحدة amino acid بعدين N C
+
+109
+00:10:14,270 --> 00:10:22,920
+C double bond O بعدين N C C double bond O بعدينN C
+
+110
+00:10:22,920 --> 00:10:27,040
+C double bond O الان هى صار عندى أربع وحدات
+
+111
+00:10:27,040 --> 00:10:36,060
+تتخيلوهم هذه وحدة تنتين تلاتة أربعة واضحة الفكرة
+
+112
+00:10:36,060 --> 00:10:43,100
+الان ايش بيظل عند المجموعة ال R اللى بتجينه من ال
+
+113
+00:10:43,100 --> 00:10:48,160
+glycine H و
+
+114
+00:10:48,160 --> 00:10:54,070
+ايش ال R اللى من القلانين مثلو إيش ال R اللي من
+
+115
+00:10:54,070 --> 00:11:01,770
+الستين؟ CH2SH و إيش ال R اللي من الفن الألانين؟
+
+116
+00:11:01,770 --> 00:11:08,730
+CH2 فنل واضح؟ لحظوا إذا أنا مجرد معرفتي الهيكل
+
+117
+00:11:08,730 --> 00:11:13,830
+بكرره بعد هيك أن أستكمل الكلام إنه هذه مثلا NH2،
+
+118
+00:11:13,830 --> 00:11:20,010
+إنه هذه CH إنه هذه NH1، إنه هذه CH، إنه هذه NH،
+
+119
+00:11:20,010 --> 00:11:25,760
+هذه CHعشان يكتمل الشكل العام بتاع الـ OH
+
+120
+00:11:30,660 --> 00:11:35,880
+واضح؟ OH أسد تيرمينال لاحظوا بهذا الشكل بإمكاني
+
+121
+00:11:35,880 --> 00:11:41,740
+أرسم أي بيبتايد فالبيبتايد معروف فيه هيكل كربوني
+
+122
+00:11:41,740 --> 00:11:48,460
+متكرر الهيكل الكربوني مع النيتروجين اللي هو NCCOO
+
+123
+00:11:48,460 --> 00:11:57,450
+NCCOO NCCOO NCCOO الاختلاف وين؟بال R groups طبعا
+
+124
+00:11:57,450 --> 00:12:02,570
+هذا الاختلاف بيخلي ال peptides و ال proteins
+
+125
+00:12:02,570 --> 00:12:09,050
+مايكونوش polymers حقيقيين لابد من معرفة إيش ال
+
+126
+00:12:09,050 --> 00:12:14,070
+sequence لهم لابد من معرفة ال sequence إيش تسلسلهم
+
+127
+00:12:14,070 --> 00:12:18,670
+الآن لو إجيت جبتلكوا سؤال مثلا قلتلكوا والله هذا
+
+128
+00:12:18,670 --> 00:12:24,710
+ال peptide يجلسين قلانين سستين فين القلانين؟مع هذا
+
+129
+00:12:24,710 --> 00:12:31,490
+الـpeptide جلبت أي شيء فيه ألانين إيجليسين سيستين
+
+130
+00:12:31,490 --> 00:12:35,670
+فين الألانين؟ غيرت أي شيء ما العلاقة بينهم؟ they
+
+131
+00:12:35,670 --> 00:12:39,470
+are structural isomers اختلفوا في مواقع الارتباط
+
+132
+00:12:39,470 --> 00:12:44,810
+كانت هنا مثلا اللي فيها المثل أعلى تاني وحدة صارت
+
+133
+00:12:44,810 --> 00:12:46,690
+اللي فيها المثل على الأولى و اللي فيها الأتش على
+
+134
+00:12:46,690 --> 00:12:51,670
+التانيةهذا تغير في الارتباط ولا لأ؟ اذا they are
+
+135
+00:12:51,670 --> 00:12:56,830
+structural isomers واضح؟ they are structural
+
+136
+00:12:56,830 --> 00:13:08,190
+isomers هذه الـ
+
+137
+00:13:08,190 --> 00:13:13,190
+N-terminal وهذه الـ C-terminalكل بيبتايد إله
+
+138
+00:13:13,190 --> 00:13:18,250
+unterminal وإله c-terminal لما ببدأ أكتب بكتب بهذا
+
+139
+00:13:18,250 --> 00:13:23,350
+الشكل واضح؟ إذا ذكرنا بيبتايد بهذا الشكل أي واحدة
+
+140
+00:13:23,350 --> 00:13:26,230
+كان بإمكانها تخلي c-terminal هان وunterminal هان
+
+141
+00:13:26,230 --> 00:13:29,290
+بس مش متعودين نشتغل زي هيك في ال biochemistry عشان
+
+142
+00:13:29,290 --> 00:13:32,210
+الكل يفهم على بعضه
+
+143
+00:13:49,240 --> 00:13:54,780
+لحظوا معاه هذا الكلام بيعمل شغل كتير مهمة لو أنا
+
+144
+00:13:54,780 --> 00:14:00,160
+مثلا جبت بس two amino acids و بدي أخليهم يتحدوا مع
+
+145
+00:14:00,160 --> 00:14:06,160
+بعض يعني glycine و alanine ممكن أخليهم يتحدوا يكون
+
+146
+00:14:06,160 --> 00:14:11,610
+ل glycine في الأولوالألانين بعده ال glycine اللي
+
+147
+00:14:11,610 --> 00:14:16,390
+فيه H والألانين اللي فيه مثل أو أخلي الألانين في
+
+148
+00:14:16,390 --> 00:14:20,790
+الأول وال glycine بعده في هذه الحالة لو أنا بدي
+
+149
+00:14:20,790 --> 00:14:26,450
+أسمي Hannah ببطاي بشكل دقيق بقول الأساس تبعه الجزء
+
+150
+00:14:26,450 --> 00:14:31,630
+الأخر اللي هو الألانين متصل في إيش ال glycine
+
+151
+00:14:31,630 --> 00:14:36,980
+بعتبره على شكل مجموعة بسميه glycineألانين مرات هذه
+
+152
+00:14:36,980 --> 00:14:43,860
+التسمية بنختصرها بنعملها بهذا الشكل إجلاي ألا خلاص
+
+153
+00:14:43,860 --> 00:14:49,040
+بنمشي بنقبلها لكن لو بدنا نحكي بشكل دقيق إجلاي سل
+
+154
+00:14:49,040 --> 00:14:55,020
+ألانين أو إجلاي ألا الآن هذا إيش أول إشي ببدأ فيه
+
+155
+00:14:55,020 --> 00:15:02,930
+ببدأ هيك و بضلني ماشي ألانين إجلاي سلفلو انا بدى
+
+156
+00:15:02,930 --> 00:15:08,690
+اعمل اتحاد بينهم اتنين مختلفين صار عندى مش ببتايد
+
+157
+00:15:08,690 --> 00:15:15,170
+واحد صار عندى اتنين هل يا ترى هذا لجليسي القلانين
+
+158
+00:15:15,170 --> 00:15:23,270
+هو نفسه القلانيل الجليسين اتأملوا فيه هنا مثلا ال
+
+159
+00:15:23,270 --> 00:15:29,270
+CH3 جنب مجموعة الحامضهنا الـ H جنب مجموعة الحامض،
+
+160
+00:15:29,270 --> 00:15:32,570
+هذا اختلاف في ال bonding ولا لا؟ هنا الـ H جنب
+
+161
+00:15:32,570 --> 00:15:37,770
+الأمين، هنا ال CH3 جنب الأمين، إذا هذولا
+
+162
+00:15:37,770 --> 00:15:41,410
+المجموعتين، يعني لو كنا متخيلين أن هذه H، انعكسوا
+
+163
+00:15:41,410 --> 00:15:47,460
+ولا لأ؟أذن هدولة Structural isomers فلو إجينا
+
+164
+00:15:47,460 --> 00:15:47,960
+سئلنا
+
+165
+00:16:13,350 --> 00:16:23,530
+الـ Glycine واضحة هذه النقطة؟ الآن نرجع للقصة
+
+166
+00:16:23,530 --> 00:16:30,750
+القديمة تبعتنا لو يا تورا إجينا و خلطنا
+
+167
+00:16:34,170 --> 00:16:39,470
+الجليسين مع الانين احنا بنخلط جزء واحد ولا عدد
+
+168
+00:16:39,470 --> 00:16:44,070
+كبير من الجزيئات عدد كبير من الجزيئات وقلنا لهم
+
+169
+00:16:44,070 --> 00:16:48,610
+يلا اتفاعلوا مع بعض و اعملولنا peptides كام ناتج
+
+170
+00:16:48,610 --> 00:16:49,810
+بنتوقع؟
+
+171
+00:16:51,890 --> 00:16:56,790
+اتذكروا لما كنا نخلط .. لما كنا نخلط على سبيل
+
+172
+00:16:56,790 --> 00:17:03,670
+المثال Methanol مع Ethanol عشان نحضر ال ether كام
+
+173
+00:17:03,670 --> 00:17:10,390
+ناتج كنا نطلع؟ تلاتة لما كنا نخلط Acetic acid مثلا
+
+174
+00:17:10,390 --> 00:17:15,930
+مع Benzoic acid عشان نطلع ال anhydride كام ناتج
+
+175
+00:17:15,930 --> 00:17:22,340
+بنطلع؟ تلاتةتلاتة طيب لما نيجي نخلط ألانين مع
+
+176
+00:17:22,340 --> 00:17:26,960
+إجلايسين و نقولهم اتفاعلوا كام ناتج بنطلع تلاتة ..
+
+177
+00:17:26,960 --> 00:17:32,040
+تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+178
+00:17:32,040 --> 00:17:36,140
+.. تلاتة
+
+179
+00:17:36,140 --> 00:17:39,780
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+180
+00:17:39,780 --> 00:17:40,140
+تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+181
+00:17:40,140 --> 00:17:40,800
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+182
+00:17:40,800 --> 00:17:40,880
+تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+183
+00:17:40,880 --> 00:17:40,880
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+184
+00:17:40,880 --> 00:17:44,240
+تلاتة .. تلاتة .. تلطبعا هيبدأ يصير عندكوا استغراب
+
+185
+00:17:44,240 --> 00:17:50,520
+ليش .. ليش انا في الميثانول لما عملت ال ether لما
+
+186
+00:17:50,520 --> 00:17:56,040
+عملت ال ether طلع عندى بس تلت أشكال لما خلطت
+
+187
+00:17:56,040 --> 00:18:00,000
+ميثانول و إيثانول و لما خلطت أسيتك أسد مثلا مع
+
+188
+00:18:00,000 --> 00:18:04,060
+بنزويك أسد أعمل الانهيدريد طلع عندى برضه تلت أشكال
+
+189
+00:18:04,060 --> 00:18:10,300
+لكن لو بخلط ألانينمع إجلايسين على سبيل المثال عشان
+
+190
+00:18:10,300 --> 00:18:14,200
+أعمل بيبتايد هيطلع عندى أربع أشكال
+
+191
+00:18:20,420 --> 00:18:25,940
+شوفوا المجموعة الوظيفية المجموعة الوظيفية تبعت ال
+
+192
+00:18:25,940 --> 00:18:30,940
+ether تبعت ال ether و تبعت ال anhydride
+
+193
+00:18:30,940 --> 00:18:35,840
+symmetrical بفرق اش معها تيجي اي مجموعة على اليمين
+
+194
+00:18:35,840 --> 00:18:42,640
+و على الاشمال يعني خلينا نشوف ال ether لو بده احط
+
+195
+00:18:42,640 --> 00:18:49,650
+مثل و اثلأحط مثل يمين و لا مثل الشمال أو العكس
+
+196
+00:18:49,650 --> 00:18:56,570
+مجموعة الاثر عبارة عن إيش O بدا
+
+197
+00:18:56,570 --> 00:19:03,370
+تتحد من الجهتين مجموعة الانهيدريد عبارة عن إيشC O
+
+198
+00:19:03,370 --> 00:19:12,310
+O C O O الآن هدول المجمعتين اللي هم بدو ييجي جنبهم
+
+199
+00:19:12,310 --> 00:19:18,070
+مثل او اثل بفرقش اذا ايجت هنا مثل وهنا اثل او هنا
+
+200
+00:19:18,070 --> 00:19:23,030
+مثل وهنا اثل لان هدول متماثلاتكذلك الحال في ال
+
+201
+00:19:23,030 --> 00:19:26,690
+unhydrate لو حطيت هنا methyl وهنا phenyl يعني
+
+202
+00:19:26,690 --> 00:19:30,730
+acidic بنزوك او حطيت هنا phenyl وهنا methyl نفس
+
+203
+00:19:30,730 --> 00:19:34,270
+الاشي هذه المجموعة متماثلة فأي واحد احط يمين او
+
+204
+00:19:34,270 --> 00:19:40,250
+شمال مابفرقش الان لو اجيت اعتبرت ان انا بدي اشتغل
+
+205
+00:19:40,250 --> 00:19:42,150
+على الامد
+
+206
+00:19:43,880 --> 00:19:49,080
+و اشوف اللي هي ال peptide bond هل يا تورا في عندي
+
+207
+00:19:49,080 --> 00:19:53,380
+تماثل ولا لأ لما باجي بشتغل اتذكروا ان احنا قولنا
+
+208
+00:19:53,380 --> 00:20:02,210
+بنشتغل N C C double bond او و بعدها بنشتغل N CC
+
+209
+00:20:02,210 --> 00:20:06,550
+double bond O لما نضع الاتنين اللي موجودين الان
+
+210
+00:20:06,550 --> 00:20:11,490
+هذا بيصير يفرج ان انا بضع هنا ال H و هنا المثل
+
+211
+00:20:11,490 --> 00:20:16,410
+بتصير هذه ال H قريبة من ايش او هذه ال H بتصير بين
+
+212
+00:20:16,410 --> 00:20:21,950
+C double bond O و N H2 هنا لو اجيت بضع المجموعة
+
+213
+00:20:21,950 --> 00:20:26,210
+التانية بتكون عند C double bond O OH مع N H واحدة
+
+214
+00:20:26,390 --> 00:20:30,150
+فهل هدولة بيكونوا بنفس ال environment لأ لكن انا
+
+215
+00:20:30,150 --> 00:20:34,030
+لو حطيتها مثل و مثل ايش بوصف مثل بقول جانبه و مثل
+
+216
+00:20:34,030 --> 00:20:39,410
+جانبه لو حطيتها مثل و مثل مثل مثل مثل مثل مثل مثل
+
+217
+00:20:39,410 --> 00:20:41,430
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+218
+00:20:41,430 --> 00:20:41,830
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+219
+00:20:41,830 --> 00:20:43,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+220
+00:20:43,950 --> 00:20:43,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+221
+00:20:43,950 --> 00:20:43,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+222
+00:20:43,950 --> 00:20:43,970
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+223
+00:20:43,970 --> 00:20:51,250
+مثل
+
+224
+00:20:51,250 --> 00:20:54,740
+مثل مثلتلاتة products بدوا يطلع عندى أربعة
+
+225
+00:20:54,740 --> 00:20:59,900
+products خلّينا نشوفهم خلّينا نشوفهم هاي ال
+
+226
+00:20:59,900 --> 00:21:06,640
+glycine و ال alanine و خلطناهم مع بعض طبعا افترضوا
+
+227
+00:21:06,640 --> 00:21:12,960
+ال alanine الأزرق و ال glycine الأحمر زى ما احنا
+
+228
+00:21:12,960 --> 00:21:17,750
+عاملينهمش احنا ميزينهم ال glycine أحمر و ال
+
+229
+00:21:17,750 --> 00:21:22,410
+alanine أزرق هذه جزيئات كتيرة ممكن يتحد عندى
+
+230
+00:21:22,410 --> 00:21:27,290
+glycine مع glycine يعطوني بيبتايد بده يكون إيش هو
+
+231
+00:21:27,290 --> 00:21:35,270
+glycine glycine هذي H هذي H NCC double bond O NCC
+
+232
+00:21:35,270 --> 00:21:39,910
+double bond O وH وH يعني glycine مع glycine ممكن
+
+233
+00:21:39,910 --> 00:21:48,260
+يتحد عندى alanine مع alanineNCCWO NCCWO مثل و مثل
+
+234
+00:21:48,260 --> 00:21:54,040
+واضح هذا يكون أي بيبتايل ألانين ألانين ممكن يتحد
+
+235
+00:21:54,040 --> 00:22:01,180
+الآن إجليسين مع الألانين بهذا الشكل إجليسين ألانين
+
+236
+00:22:01,180 --> 00:22:10,550
+NCCWO NCCWO الهيكلة هذا إجليسين H هذا ألانينالان
+
+237
+00:22:10,550 --> 00:22:13,470
+الاتحاد يتم بطريقة تانية
+
+238
+00:22:20,780 --> 00:22:28,840
+يكون بهذا الشكل NCCWO NCCWO CH3HANA و N HANA هذا
+
+239
+00:22:28,840 --> 00:22:34,860
+إيش بده يكون الانين غلايسين ال بيبتايد الآن اتطلع
+
+240
+00:22:34,860 --> 00:22:40,840
+عليهم بالتأمل هل فيهم أشياء بتشبه بعض طبعا لو
+
+241
+00:22:40,840 --> 00:22:44,760
+سألتكوا ما العلاقة بين غلايسين غلايسين و الانين
+
+242
+00:22:44,760 --> 00:22:50,520
+انا الانينthey are .. استعملولي كلمات كيميائية
+
+243
+00:22:50,520 --> 00:22:56,040
+they are different compounds مراكبات مختلفة، لأن
+
+244
+00:22:56,040 --> 00:22:59,500
+أنا اتش و اتش و انا مثل و مثلها، دي مراكبات مختلفة
+
+245
+00:22:59,500 --> 00:23:03,700
+إجليسين إجليسين و ألانين ألانين they are different
+
+246
+00:23:03,700 --> 00:23:07,620
+compounds لو قلتلكوا ما العلاقة بين إجليسين
+
+247
+00:23:07,620 --> 00:23:11,950
+إجليسين و إجليسين ألانين؟they are different
+
+248
+00:23:11,950 --> 00:23:14,570
+compounds هان اتش و اتش و هان اتش و مثل صيغة
+
+249
+00:23:14,570 --> 00:23:18,850
+مختلفة كذلك الحال لو بدأ اقول الالانين الالانين و
+
+250
+00:23:18,850 --> 00:23:19,950
+الالانين الالانين الالانين الالانين الالانين
+
+251
+00:23:19,950 --> 00:23:20,490
+الالانين الالانين الالانين الالانين الالانين
+
+252
+00:23:20,490 --> 00:23:22,850
+الالانين الالانين الالانين الالانين الالانين
+
+253
+00:23:22,850 --> 00:23:25,270
+الالانين الالانين الالانين الالانين الالانين
+
+254
+00:23:25,270 --> 00:23:29,230
+الالانين الالانين الالانين الالانين الالانين
+
+255
+00:23:29,230 --> 00:23:30,250
+الالانين الالانين الالانين الالانين الالانين
+
+256
+00:23:30,250 --> 00:23:30,250
+الالانين الالانين الالانين الالانين الالانين
+
+257
+00:23:30,250 --> 00:23:30,610
+الالانين الالانين الالانين الالانين الالانين
+
+258
+00:23:30,610 --> 00:23:36,470
+الالانين الالانين الالانين الالان
+
+259
+00:23:36,500 --> 00:23:40,040
+الذرات تماما يعني لو حسبنا على الكمبيوتر ال
+
+260
+00:23:40,040 --> 00:23:43,420
+molecular weight لهذا و لهذا same number of atoms
+
+261
+00:23:43,420 --> 00:23:46,980
+same molecular weight بس الفكرة الاختلاف ان هنا
+
+262
+00:23:46,980 --> 00:23:49,920
+اجت ال H و هنا ال مثل هنا اجت ال مثل و هنا ال H
+
+263
+00:23:49,920 --> 00:23:54,400
+واضح ان they are different compounds يعني هذه ال H
+
+264
+00:23:54,400 --> 00:23:58,280
+محصورة بين C double bond O و N H 2 و المثل بين
+
+265
+00:23:58,280 --> 00:24:04,700
+acid و N H هنا ال H بين acid و N Hواضح الاختلاف
+
+266
+00:24:04,700 --> 00:24:09,420
+بناء على ذلك لو سألنا ان mixing two amino acids
+
+267
+00:24:09,420 --> 00:24:16,620
+together in fact will produce fourproducts تمام؟
+
+268
+00:24:16,620 --> 00:24:23,300
+هيعطي أربع نواتج طبعا هتصير عندنا مشكلة هتصير
+
+269
+00:24:23,300 --> 00:24:27,640
+عندنا مشكلة يعني لو الناس كانوا بدهم لجليسين
+
+270
+00:24:27,640 --> 00:24:31,660
+جليسين هيسخنوا الجليسين مع نفسه بظروف تفاعل يتفاعل
+
+271
+00:24:31,660 --> 00:24:37,220
+بدي ألانين ألانين نفس الفكرة لكن لو كنت بدي أحضر
+
+272
+00:24:37,220 --> 00:24:44,260
+جليسين ألانينبدي طريقة معينة الان هذه الطريقة مش
+
+273
+00:24:44,260 --> 00:24:48,380
+مقبولة كيميائيا اصدقائك بتقولوا اخلطوهم وافصلوهم
+
+274
+00:24:48,380 --> 00:24:52,460
+اول اش اذا خلطناهم هنطلع مش ناتجين اربعة اربعة
+
+275
+00:24:52,460 --> 00:24:57,660
+الان في كيميائي بيحط حاله يقعد يفصل اربعة
+
+276
+00:24:57,660 --> 00:25:01,240
+compounds عن بعض اللي بيدخل المختبر وبيعرف غلبة
+
+277
+00:25:01,240 --> 00:25:05,420
+الشغل لايمكن يعملها لايمكن يعملها وبناء على ذلك
+
+278
+00:25:05,420 --> 00:25:14,780
+انا فعلا فعلا بدي طريقةفقط اطلع لي ناتج واحد يعني
+
+279
+00:25:14,780 --> 00:25:22,380
+هاي هدول المركباتفكروا معي قداش الكيميا منطقها هو
+
+280
+00:25:22,380 --> 00:25:28,260
+منطق إيش؟ هو منطق حياة .. منطق حياة شايفين؟ هدولة
+
+281
+00:25:28,260 --> 00:25:32,040
+المركبات الأربعة أنا خلطهم و افترضوا أخلط من هذا
+
+282
+00:25:32,040 --> 00:25:35,420
+مليون جزيئة و من هذا مليون جزيئة بدي أفعلهم أي
+
+283
+00:25:35,420 --> 00:25:39,460
+واحد اللي بدكم إياه أنتم يطلع إجلايسين ألانين يعني
+
+284
+00:25:39,460 --> 00:25:45,380
+اللي زي هيك و فقط واضح؟أنا بدي أفرجيكوا كيف بدي
+
+285
+00:25:45,380 --> 00:25:52,120
+أعملها كإنها لعبة برا ما أحكي عن إيش عن الكيميا
+
+286
+00:25:52,120 --> 00:25:56,980
+يعني أنا بدي أتعامل معها كإنها لعبة بدي أعطي لشخص
+
+287
+00:25:56,980 --> 00:26:00,680
+معين هدول أقوله اخلط بحيث أنه لما تيجي تشبكهم في
+
+288
+00:26:00,680 --> 00:26:04,660
+بعض ما يطلعش إلا هذا المركب اللي أنتوا طلبته
+
+289
+00:26:04,660 --> 00:26:09,440
+الأحمر و الأزرق تمام؟ كل هذا الكلام ممكن نعمله
+
+290
+00:26:09,440 --> 00:26:13,600
+بورقة clinics صغيرة إيش رأيكوا؟
+
+291
+00:26:16,190 --> 00:26:21,210
+ورقة كلينكس الصغيرة ايش اللي بدنا نعمله احنا بنيجي
+
+292
+00:26:21,210 --> 00:26:26,590
+هذا بنعمله protection من هنا بنعمله حماية من هنا
+
+293
+00:26:26,590 --> 00:26:30,910
+ممنوع انت تتفعل بدنا ياك تتفعل من ال nitrogen
+
+294
+00:26:30,910 --> 00:26:34,090
+سكرنا مجموعة الحامض عشان مايجيش هذا يتفعل معاه من
+
+295
+00:26:34,090 --> 00:26:39,510
+هنا لاحظوا هذا الغلبان جاي يتفعل معاه راضي يتفعل؟
+
+296
+00:26:39,510 --> 00:26:43,950
+شوفوا قبل ال protection قبل الحماية لو هذا إيجي
+
+297
+00:26:43,950 --> 00:26:50,400
+يتفعلكان بتفاعل، الآن بعد ما عملت الـ protection
+
+298
+00:26:50,400 --> 00:26:57,800
+إجا اتفاعلمش قادر يتفاعل سكرت هذا الجزء إذا بجعل
+
+299
+00:26:57,800 --> 00:27:02,880
+كل هدولة بعمل protection لل acid بإضافة مجموعة
+
+300
+00:27:02,880 --> 00:27:07,460
+كيميائية اتسكر هذا الجزء هذا بطل يتفاعل من هنا
+
+301
+00:27:07,460 --> 00:27:13,820
+ممتاز لسه عندي خوف ان هدول يتفاعلوا مع بعض الان
+
+302
+00:27:13,820 --> 00:27:18,800
+هدول هدين يتفاعلوا مع بعض انا منعت نص المشكلة الان
+
+303
+00:27:18,800 --> 00:27:23,530
+هذا من وين بدي امنعه يتفاعل؟من ال nitrogen باجي
+
+304
+00:27:23,530 --> 00:27:27,350
+بعمله protection من الطرف التاني عشان مايقدرش
+
+305
+00:27:27,350 --> 00:27:35,050
+يتفاعل منها أنا بنعمله شوية protection برضه هاي
+
+306
+00:27:35,050 --> 00:27:40,270
+بأمل أنها تكون عمليتها ال protection هذه زبطت
+
+307
+00:27:40,270 --> 00:27:41,670
+استعمل
+
+308
+00:27:46,120 --> 00:27:51,860
+بهمش انتوا في النهاية تصللكوا الفكرة ان الكيميائي
+
+309
+00:27:51,860 --> 00:27:57,980
+والبني آدم والطبيب لما بده يفكر بحالة مشكلة بده
+
+310
+00:27:57,980 --> 00:28:01,620
+يكون عنده أصول العلم لكن بده يفكر بمنطق الدنيا
+
+311
+00:28:01,620 --> 00:28:06,320
+بمنطق الدنيا يعني إليزاروف إليزاروف لما عمل
+
+312
+00:28:06,320 --> 00:28:11,040
+العملية الجراحية تبعته اللي بطول فيها عظام الساق
+
+313
+00:28:11,040 --> 00:28:15,320
+الناس اللي عندهم ساق أكثر من التانيةاللي فكر فيه
+
+314
+00:28:15,320 --> 00:28:20,420
+انه ايجي على العضمة جشرها و حط حديد هان و هان و
+
+315
+00:28:20,420 --> 00:28:25,040
+صار كل ساعتين اطول نص مل نص مل لانه مقدرش يسحب كل
+
+316
+00:28:25,040 --> 00:28:29,780
+شيء عظامه اعصابه اشي مرة واحدة عمدا أسبوعين بيضلوا
+
+317
+00:28:29,780 --> 00:28:34,020
+يسحب يسحب او بيطول العضمة كده؟ سبعة تمانية سانتي
+
+318
+00:28:34,020 --> 00:28:40,840
+بيعمل مسوافر عملية شهيرة جدا ال الازاروفالان
+
+319
+00:28:40,840 --> 00:28:45,720
+الظروف شاب تبع البسكليتات كيف بيشتغلوا بعمل العجال
+
+320
+00:28:45,720 --> 00:28:51,380
+واخذ منه فكرة كيف يعمل العملية واضحة الفكرة؟ الان
+
+321
+00:28:51,380 --> 00:28:58,120
+هاي انا عملت protection هنا لل acid part وهنا لل
+
+322
+00:28:58,120 --> 00:29:03,320
+amino part انه مش قادر يتفاعل من عند ال nitrogen
+
+323
+00:29:03,320 --> 00:29:09,740
+الان بدي اخلطهم و اقولوا متفاعلوا زي ما بدكمهيجي
+
+324
+00:29:09,740 --> 00:29:14,060
+يتفاعلوا اول اشي هذا هيجي يتفاعل من هنا هيلاجي ايش
+
+325
+00:29:14,060 --> 00:29:18,880
+امسكّر ال nitrogen تبعته من هنا امسكّر ال nitrogen
+
+326
+00:29:18,880 --> 00:29:24,180
+هذا هيجي يتفاعل مع هذا امسكّر ال CO هذا يتفاعل مع
+
+327
+00:29:24,180 --> 00:29:29,620
+هذا امسكّر ال CO لغاية كل هذه التفاعلات الان هذا
+
+328
+00:29:29,620 --> 00:29:36,820
+بيجي يتفاعل مع هذا امسكّر هذا بيجي يتفاعل مع هذا
+
+329
+00:29:38,200 --> 00:29:45,500
+طلعت one product شوف كيف .. هايوة one product هيك
+
+330
+00:29:45,500 --> 00:29:50,500
+ممكن .. الآن هيكمش ممكن اتنين زرق مش ممكن اتنين
+
+331
+00:29:50,500 --> 00:29:55,500
+حمر مش ممكن هذه الفكرة هي اللي عملوها الان كل اللي
+
+332
+00:29:55,500 --> 00:29:59,500
+بدنا نعمله اننا بدنا نكتب في المعادلة حطوا هنا حرف
+
+333
+00:29:59,500 --> 00:30:04,520
+بي بي ايش يعني بي يعني protecting group لما تكونوا
+
+334
+00:30:04,520 --> 00:30:08,000
+اعملوا هذا protected او اعملوا هذا protected لما
+
+335
+00:30:08,000 --> 00:30:12,140
+تشوفوا ال بي يعني من هنا ممنوع تتفاعلمجموعة
+
+336
+00:30:12,140 --> 00:30:16,120
+كيميائية صغيرة بنضيفها بتخلي هذا مثبت مابتفعلش مش
+
+337
+00:30:16,120 --> 00:30:21,980
+هندخل بتفاصيل أكتر من هي وجدها ماعندي إلا هذه
+
+338
+00:30:21,980 --> 00:30:25,780
+الإمكانية تشتغل هذا مش هيقدر يتفعل مع نفسه ولا هذا
+
+339
+00:30:25,780 --> 00:30:29,400
+هيتفعل مع نفسه هذا هيتفعل مع هذا بس one product
+
+340
+00:30:29,400 --> 00:30:37,260
+طلعت ال glycine ألانين واضحة الفكرة وهذا هو اللي
+
+341
+00:30:37,260 --> 00:30:38,220
+موجود يمكن
+
+342
+00:30:40,820 --> 00:30:45,960
+في ال slide يمكن متأخرة عندكم اربع خمسة slides
+
+343
+00:30:45,960 --> 00:30:52,520
+لاحظوا هاي جاب amino acid one سماه وعمل protection
+
+344
+00:30:52,520 --> 00:30:58,740
+لمجموعة معينة و جاب ال amino acid two وعمل
+
+345
+00:30:58,740 --> 00:31:02,620
+protection لمجموعة تانية نفس الفكرة اللي احنا
+
+346
+00:31:02,620 --> 00:31:06,280
+حكيناها الآن هذا بطل يتفعل من هنا هذا بتفعلش من
+
+347
+00:31:06,280 --> 00:31:10,850
+هنا مافيش غير هذا الجزءمع هذا الجزء بده يتفاعل
+
+348
+00:31:10,850 --> 00:31:17,010
+فبدل ما أطلع four different compounds بطلع one
+
+349
+00:31:17,010 --> 00:31:22,230
+طبعا في هذه الحالة هين طلعت بيبتايد الآن بعد ما
+
+350
+00:31:22,230 --> 00:31:26,090
+طلعته بتفاعل كيميائي بسيط بقدر أشيل هذا ال
+
+351
+00:31:26,090 --> 00:31:30,730
+protection أو هذا ال protection الآن تخيلوا لو كنا
+
+352
+00:31:30,730 --> 00:31:35,910
+بدنا نطول ال peptide يعني مش بس اتنين بد من هنا ما
+
+353
+00:31:35,910 --> 00:31:41,370
+يتفاعلشبخلّي هذا الـ protection بدي من هنا يتفاعل
+
+354
+00:31:41,370 --> 00:31:50,370
+بشيل هذا و بجيبله amino acid ال nitrogen تبعته not
+
+355
+00:31:50,370 --> 00:31:53,430
+protected و ال acid protected عشان مايتفعلش مع
+
+356
+00:31:53,430 --> 00:31:58,150
+بعضه اللي جاي جديد بيجي يتفعل هنا واحد اتنين تلاتة
+
+357
+00:31:58,150 --> 00:32:03,270
+اربعة ممكن في الآخر يتحضروا خمسة عشر و عشرين و
+
+358
+00:32:03,270 --> 00:32:09,540
+تلاتين جد ما بدكم و بالترتيببالترتيب بتحضره تمام
+
+359
+00:32:09,540 --> 00:32:13,220
+هذا
+
+360
+00:32:13,220 --> 00:32:20,160
+الكلام كله موجود ثانية أخدها لحظوا
+
+361
+00:32:20,160 --> 00:32:27,460
+على سبيل المثال هاي مركب اتخيلوا هذا عملوله
+
+362
+00:32:27,460 --> 00:32:28,100
+sequencing
+
+363
+00:32:31,070 --> 00:32:35,610
+عرفوا تفاصيله هنشوف طبعا كيف بعد شوية بنحلل المركب
+
+364
+00:32:35,610 --> 00:32:39,050
+نعرف ال amino acids إيجليسين إليوسين فالين
+
+365
+00:32:39,050 --> 00:32:44,870
+إيجلوتاميكاس وهكذا هذا الانسولين هذا الانسولين
+
+366
+00:32:44,870 --> 00:32:51,030
+سلسلتين من ال إيش ال peptides بيحللوه بيعرفوه واحد
+
+367
+00:32:51,030 --> 00:32:58,130
+واحد لاحظوا مابنقدرش زي السكر نعمل إيش شغلة to the
+
+368
+00:32:58,130 --> 00:33:02,700
+end لأ في إيش اسمهسيكوانس في ال .. بيبتايتز و في
+
+369
+00:33:02,700 --> 00:33:08,000
+الأمان هاي هذا مركّب الراجل اللي حضره أخد عليه
+
+370
+00:33:08,000 --> 00:33:13,600
+جائزة نوبل في الكيميا سنة الخمسة و خمسين هذا
+
+371
+00:33:13,600 --> 00:33:22,780
+Vincent de Vignod أخد عليه جائزة نوبل هذا هرمون من
+
+372
+00:33:22,780 --> 00:33:29,310
+تسعةأمينو أسد حضرهم من مرتبين سيستين تايروسين
+
+373
+00:33:29,310 --> 00:33:33,030
+إليوسين كذا أسبرتك أسستين برولين ليوسين إجلايسين
+
+374
+00:33:33,030 --> 00:33:37,750
+أعدهم واحد اتنين تلاتة أربعة خمس ستة سبعة تمانية
+
+375
+00:33:37,750 --> 00:33:42,970
+تسعة هنا في أس و أس ارتبطوا مع بعض مش موضوعنا ناخد
+
+376
+00:33:42,970 --> 00:33:46,630
+الديس الفايدمون بس هدول كام أمينو أسد في المحصلة
+
+377
+00:33:46,630 --> 00:33:52,590
+واحد اتنين تلاتة أربعة خمسة ستة سبعة تمانية تسعة
+
+378
+00:33:52,590 --> 00:33:59,330
+حضرهم من مرتبينبهذه الطريقة واضح؟ هذا عبارة عن
+
+379
+00:33:59,330 --> 00:34:05,790
+هرمون اسمه oxytocin مار عليكم؟ هرمون السعادة الله
+
+380
+00:34:05,790 --> 00:34:11,380
+يسعدكمالناس بيسموه هرمون السعادة فعلا، ليش؟ لأنهم
+
+381
+00:34:11,380 --> 00:34:14,640
+انتبعون علم النفس وغيره، بيقولوا هذا اللي بتتحكم
+
+382
+00:34:14,640 --> 00:34:19,440
+بالانفعالات وقصص السعادة والحب وكل إشي برتوب هذا
+
+383
+00:34:19,440 --> 00:34:24,160
+الهرمون طبعا إله تطبيقات تانية .. إله تطبيقات
+
+384
+00:34:24,160 --> 00:34:28,720
+تانية هو في الأصل بيطلع من ال posterior pituitary
+
+385
+00:34:28,720 --> 00:34:33,060
+gland يمكن بتسموها الغضب الكذرية ولا إيش .. هذا
+
+386
+00:34:33,060 --> 00:34:40,320
+بتحكم في القبضات الرحم في لحظة الولادةit regulates
+
+387
+00:34:40,320 --> 00:34:46,560
+uterine contraction and lactation وفي الرضاعة may
+
+388
+00:34:46,560 --> 00:34:49,360
+be administered .. إيش معنى administered في لغة
+
+389
+00:34:49,360 --> 00:34:54,800
+العلم الطبي؟ يُعطى كعلاج أو يوصف واضح؟ when it is
+
+390
+00:34:54,800 --> 00:34:58,440
+necessary to induce labor at childbirth يعني عشان
+
+391
+00:34:58,440 --> 00:35:03,750
+يزيد الطلجواضح؟ وبنفس الوقت زي ما حكينا إيه له
+
+392
+00:35:03,750 --> 00:35:09,670
+علاقة بالانفعالات الآن لاحظوا بيبتعد وحضر أول إشي
+
+393
+00:35:09,670 --> 00:35:13,570
+قبل ما يحضر إيش كان لازم نفصله من مصدره الطبيعي
+
+394
+00:35:13,570 --> 00:35:19,210
+ونعرف إيش ال sequence تبعته بعد ما نعرف ال
+
+395
+00:35:19,210 --> 00:35:23,230
+sequence ال road نقدر نعملها إذا صار عند أنا في
+
+396
+00:35:23,230 --> 00:35:27,850
+المنطقة شغلتين معرفة ال sequence و التحضير يمكن
+
+397
+00:35:27,850 --> 00:35:32,610
+احنا بدأنا الآنبفكرة التحضير لكن لسه ماحكيناش عن
+
+398
+00:35:32,610 --> 00:35:37,950
+فكرة إيش ال sequence فكرة ال sequence فكرة طويلة و
+
+399
+00:35:37,950 --> 00:35:46,110
+أخدت وقت طبعا من العلماء لكن
+
+400
+00:35:46,110 --> 00:35:50,170
+خلينا نضل ماشيين مع ال slides شوفنا قصة ال
+
+401
+00:35:50,170 --> 00:35:54,570
+protection خلصنا منها الآن من الروابط اللي
+
+402
+00:35:54,570 --> 00:36:00,840
+بتواجهنافي الـpeptides و بتمسكها مع بعض اللي هي
+
+403
+00:36:00,840 --> 00:36:04,180
+الـdisulfide bonds طبعا في hydrogen bonding أكيد
+
+404
+00:36:04,180 --> 00:36:08,740
+هيمر علينا لكن الـdisulfide bonds and all amino
+
+405
+00:36:08,740 --> 00:36:13,540
+acid اللي فيه الـsulfur ممكن يعمل الـdisulfide
+
+406
+00:36:13,540 --> 00:36:20,870
+bondال سيستين اللي قلتلكوا احفظوه اللي فيه CH2SH
+
+407
+00:36:20,870 --> 00:36:27,970
+فلو التقى سيستين مع سيستين SH وSH أخدنا في الثيول
+
+408
+00:36:27,970 --> 00:36:31,510
+شوفوا كيف العلم مبني على بعضه لما أخدنا الثيول
+
+409
+00:36:31,510 --> 00:36:35,530
+متذكرين قولنا الثيول بال Oxidation بعمل Di
+
+410
+00:36:35,530 --> 00:36:40,030
+-sulphide bond و بال reduction برجع لثيول و كان من
+
+411
+00:36:40,030 --> 00:36:46,770
+أمثلتها الشعر و قرنية العين و غيرهافهدولة لو اجينا
+
+412
+00:36:46,770 --> 00:36:51,650
+مثلا في بيبتايد طويل في طرف معين منه فيه 16 فيه
+
+413
+00:36:51,650 --> 00:36:58,590
+CH2SH و بطرف تاني 16 فيه CH2SH ممكن الـSH مع الـSH
+
+414
+00:36:58,590 --> 00:37:02,410
+يعملوا ايش دايس الفايدبوند هذا الكلام وين توي
+
+415
+00:37:02,410 --> 00:37:07,150
+شوفناه احنا؟ في الـOxytocin
+
+416
+00:37:08,650 --> 00:37:13,970
+تطلعوا معي هاي ال oxytocin ال amino acid نمرا واحد
+
+417
+00:37:13,970 --> 00:37:20,610
+16 يعني CH2SH وال amino acid واحد اتنين تلاتة
+
+418
+00:37:20,610 --> 00:37:27,430
+اربعة خمسة ستة السادس CH2SH
+
+419
+00:37:27,430 --> 00:37:34,110
+الآن ال SH مع ال SH عملوا oxidation عملوا ايش ال
+
+420
+00:37:34,110 --> 00:37:38,470
+di-sulfide bond فصار مبين هذا كأنه في حلقةعشان هيك
+
+421
+00:37:38,470 --> 00:37:40,930
+لما عدينا ال amino acids عديناهم تسعة، واحد،
+
+422
+00:37:40,930 --> 00:37:44,090
+اتنين، تلات، اربع، خمس، ستة، سبعة، تمانية، تسعة بس
+
+423
+00:37:44,090 --> 00:37:50,490
+الأول والسادس فيهم CH2SH CH2SH CH2SH CH2SH CH2SH
+
+424
+00:37:50,490 --> 00:37:50,490
+CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH
+
+425
+00:37:50,490 --> 00:37:51,550
+CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH
+
+426
+00:37:51,550 --> 00:37:51,550
+CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH
+
+427
+00:37:51,550 --> 00:37:52,730
+CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH
+
+428
+00:37:52,730 --> 00:37:54,930
+CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH
+
+429
+00:37:54,930 --> 00:38:03,630
+CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2الان
+
+430
+00:38:03,630 --> 00:38:10,910
+واضح تماما انه صعب في نهاية المحاضرة ان نبدأ نحكي
+
+431
+00:38:10,910 --> 00:38:15,270
+عن ال protein وكيف نعمل ال sequence هيلزمنا ان شاء
+
+432
+00:38:15,270 --> 00:38:20,970
+الله محاضرة إضافية نحكي فيها كيف نتعرف على ال
+
+433
+00:38:20,970 --> 00:38:24,830
+sequence لل amino acids وإذا عرفنا ال sequence
+
+434
+00:38:24,830 --> 00:38:29,250
+شوفنا كيف الآن بنحضرهم بعد هيك أشكال ال protein
+
+435
+00:38:29,250 --> 00:38:31,530
+المختلفة فان شاء الله إلى لقاء
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8cf7712c4f942fec41da6272a8b6bbc92ced999f
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_raw.srt
@@ -0,0 +1,1920 @@
+1
+00:00:20,210 --> 00:00:23,950
+بسم الله الرحمن الرحيم بنبدأ اليوم بالفصل السابع
+
+2
+00:00:23,950 --> 00:00:30,470
+هتلاحظوا أنه يعني هنركز كعائلة أساسية فيه على
+
+3
+00:00:30,470 --> 00:00:35,650
+مركبات ال alcohols اللي بنسميها بالعربي الكحولات
+
+4
+00:00:35,650 --> 00:00:42,850
+الآن بعض الكتب اللي بتدرس باللغة العربية هتلاقوها
+
+5
+00:00:42,850 --> 00:00:49,720
+موجودة باسم الأغوالإذا مرت عليكم هذه الكلمة يعني
+
+6
+00:00:49,720 --> 00:00:52,920
+الناس اللي جاي من السعودية بدهم يدرسوا عن ال
+
+7
+00:00:52,920 --> 00:00:57,020
+alcohols الكحولات بدل ما يقولوا الكحولات بيقولوا
+
+8
+00:00:57,020 --> 00:01:03,200
+إيش الأغوال جامع غول و بيستندوا للنص القرآن لا
+
+9
+00:01:03,200 --> 00:01:08,760
+فيها غولولهم عنها ينزفون واضح الفكرة فإذا قرأتها
+
+10
+00:01:08,760 --> 00:01:14,800
+بكتاب عربي باسم الأغوال فهي الكحولات، الآن ككيميا
+
+11
+00:01:14,800 --> 00:01:23,080
+الكحولات هي المركبات اللي ماخدة صيغة Rواضح الان
+
+12
+00:01:23,080 --> 00:01:30,020
+بيجي معها ال phenols إذا كانت ال OH متصلة بحلقة
+
+13
+00:01:30,020 --> 00:01:35,020
+أروماتية البنزين حالة خاصة بيكون نفس ال phenol لكن
+
+14
+00:01:35,020 --> 00:01:42,920
+المجموعة العامة AR بشكل عام ال AR OH يعني كل
+
+15
+00:01:42,920 --> 00:01:47,580
+المركبات الأروماتية إذا اتصلت ب OH they are
+
+16
+00:01:47,580 --> 00:01:55,420
+phenolsموازي لل alcohols لكن بإبدال ال oxygen هادى
+
+17
+00:01:55,420 --> 00:02:01,200
+ب Sulphur بيصير المركب ثيول بيصير المركب ثيول يعني
+
+18
+00:02:01,200 --> 00:02:08,060
+ماخد الصيغة العامة R RSH ثيولز ماخد الصيغة العامة
+
+19
+00:02:08,060 --> 00:02:15,060
+RSH طبعا اكيد هتقولوا طيب في موازي لل phenol بمعنى
+
+20
+00:02:15,060 --> 00:02:16,580
+اخر ايش بدى يكون ماخد AR
+
+21
+00:02:19,820 --> 00:02:25,320
+SH موجود أيضا بنسميه Theophenol
+
+22
+00:02:27,210 --> 00:02:33,170
+واضح؟ فهذه العائلات اللي طبعا الأساس فيها عائلة
+
+23
+00:02:33,170 --> 00:02:37,390
+الكحولات يعني هيكون التركيز الأكبر على الكحولات
+
+24
+00:02:37,390 --> 00:02:41,030
+اللي هي المركبات اللي ماخدة الصيغة العامة ROH من
+
+25
+00:02:41,030 --> 00:02:47,210
+الطرق بشكل خفيف للphenols للthiols للthiophenols
+
+26
+00:02:47,210 --> 00:02:53,270
+كل هذه الأشياء ان شاء الله بنقشها في هذا الفصل
+
+27
+00:02:56,090 --> 00:03:00,990
+إذا بدأنا بالكحولات .. إذا بدأنا بالكحولات و أول
+
+28
+00:03:00,990 --> 00:03:06,430
+شغلة دايما بنبدأ فيها كيف نسمي المركبات عادة بنسمي
+
+29
+00:03:06,430 --> 00:03:12,190
+الكحولات بإضافة النهاية all لاحظوا أن نظام التسمية
+
+30
+00:03:12,190 --> 00:03:15,910
+.. نظام التسمية في ال organ chemistry للناس اللي
+
+31
+00:03:15,910 --> 00:03:22,120
+بيتقنوه هو نظامبسيط جدا يعني مئات إذا ما قلناش
+
+32
+00:03:22,120 --> 00:03:27,540
+ملايين المراكبات الإنسان بتعلم قواعد بسيطة جدا
+
+33
+00:03:27,540 --> 00:03:32,840
+للتسمية وبيقدر يسيطر عليها الآن المفروض مع هذا
+
+34
+00:03:32,840 --> 00:03:37,440
+الوقت أنه صار نظام التسمية بالنسبة لناواضح في
+
+35
+00:03:37,440 --> 00:03:42,560
+عندنا سلسلة كربونية بدنا ناخد العدد تبعها بالنهاية
+
+36
+00:03:42,560 --> 00:03:48,980
+ميثين إيثين بروبين بيوتين بيوتين هكسين هبتين هدوله
+
+37
+00:03:48,980 --> 00:03:53,300
+صرنا حافظينهم الآن هذا الكلام إذا كانت السلسلة
+
+38
+00:03:53,300 --> 00:03:56,840
+كلها روابط أحدية وقلنا الkins الآن إذا صرنا في
+
+39
+00:03:56,840 --> 00:04:02,900
+الروابط الثنائية بنغير بنحط in بدل ال in في
+
+40
+00:04:02,900 --> 00:04:09,610
+الروابط الثلاثيةI الآن في الكحولات بنحط نهاية all
+
+41
+00:04:09,610 --> 00:04:14,450
+بعد شوية هنتعلم في ال aldehydes بنحط نهاية L في ال
+
+42
+00:04:14,450 --> 00:04:19,430
+ketone بنحط نهاية on في الأحماض الكربوكسيلية بنحط
+
+43
+00:04:19,430 --> 00:04:24,390
+نهاية oic acid بمعنى لو أنا رسمت خمس درات كربون
+
+44
+00:04:24,390 --> 00:04:29,690
+بقدر اقول ان المركبات اللي منهم عند اللزوم مثيل
+
+45
+00:04:30,860 --> 00:04:39,680
+للألكين ميثين اعفوا بنتين I mean بنتين بنتين بنتين
+
+46
+00:04:39,680 --> 00:04:42,860
+طبعا بحدد وين موقع ال double bond ده قصة بسيطة
+
+47
+00:04:42,860 --> 00:04:50,580
+بنتاي بنتانول بنتانال لل الديهايد بنتانون لل كيتون
+
+48
+00:04:50,580 --> 00:04:56,970
+بنتانوك أسد فصارت القصة فقط هي نهايةبتتغير في
+
+49
+00:04:56,970 --> 00:05:01,750
+نهاية الاسم و بنقدر نسمي المراكبات انتبهوا جيدا ان
+
+50
+00:05:01,750 --> 00:05:05,870
+ال all اللي بنستعمله انه نهاية الكحولات مافيش فيها
+
+51
+00:05:05,870 --> 00:05:13,330
+E في الآخر يعني OL بدون E ليش هتوجهنا المراكبات
+
+52
+00:05:13,770 --> 00:05:20,050
+بتنتهي ب OLE هذه مركبات حلقية تحتوي على حلقات
+
+53
+00:05:20,050 --> 00:05:24,430
+خماسية خارج موضوع دراستنا زي لما تسمعوا عن بعض
+
+54
+00:05:24,430 --> 00:05:29,870
+الأدوية مثلا المضادة للفطريات الدكتازول
+
+55
+00:05:29,870 --> 00:05:33,690
+والفلوكانازول الناس اللي عندهم فطريات أحيانا بين
+
+56
+00:05:33,690 --> 00:05:39,560
+أصابع رجليهم بيشتريوامضاد للفطريات دكتازول مشهور
+
+57
+00:05:39,560 --> 00:05:45,040
+كتير في البلد flucanazole هدولة هتلاحظوا اسمهم OLE
+
+58
+00:05:45,040 --> 00:05:50,580
+OLE هذه عائلة ثانية عائلة مركبات بحلقات يشمالها
+
+59
+00:05:50,580 --> 00:05:56,980
+خماسية فالكحولات اللي عندنا نهايتهم all الان لو
+
+60
+00:05:56,980 --> 00:06:03,680
+اجينا بدنا نسمي ب carbon واحد هنقول مثان allو هكذا
+
+61
+00:06:03,680 --> 00:06:08,060
+الان لاحظوا ال common nomenclature و مرات كتير
+
+62
+00:06:08,060 --> 00:06:12,920
+بنقولكوا ايش الاسم الشائع للمركب ايضا لها بشكل عام
+
+63
+00:06:12,920 --> 00:06:19,800
+قاعدة القاعدة تبعتها ذكر المجموعة ال alkyl group و
+
+64
+00:06:19,800 --> 00:06:25,300
+بعدين بنحط نهاية يعني لو كان هذا المركب CH3Cl كنت
+
+65
+00:06:25,300 --> 00:06:28,800
+اقول ال common nomenclature له مثل ال chloride
+
+66
+00:06:28,800 --> 00:06:35,950
+الان لما بيصير CH3OHمثل و ال OH عائلة الألكوهول
+
+67
+00:06:35,950 --> 00:06:40,250
+فبصير مثل ألكوهول و هكذا ف ال common nomenclature
+
+68
+00:06:40,250 --> 00:06:48,750
+بشكل عام بتيجي بذكر المجموعة و بعدها العائلة واضح؟
+
+69
+00:06:48,750 --> 00:06:52,590
+نفس الاشي هتلاحظوا مثلا في ال aldehydes
+
+70
+00:06:52,590 --> 00:07:00,950
+بروبلالديهيد مثلا بروبل المجموعة الديهيدالعائلة و
+
+71
+00:07:00,950 --> 00:07:06,830
+بال كيتون و بال أسد و بال كلورايتس و بالبرومايتس
+
+72
+00:07:08,520 --> 00:07:13,980
+توجه عام الان لو اتيت هنا اتطلعت هذا إيثانول طبعا
+
+73
+00:07:13,980 --> 00:07:19,200
+المجموعة إيثل بناء على ذلك بيكون إيثل ألكول هذا
+
+74
+00:07:19,200 --> 00:07:23,700
+البروبانول الان لاحظوا البروبانول الالكول ممكن
+
+75
+00:07:23,700 --> 00:07:26,580
+تكون ال OH على الكاربون الأولى أو على الكاربون
+
+76
+00:07:26,580 --> 00:07:30,880
+الثانية ولذلك بلزم نوضح بالترقيم فبنقول one
+
+77
+00:07:30,880 --> 00:07:36,890
+probanol و two probanolواضح؟ ال alcohol من
+
+78
+00:07:36,890 --> 00:07:41,470
+المركبات زيها زي ال alkenes اللي مرات كتير لازم
+
+79
+00:07:41,470 --> 00:07:45,870
+نوضح موقع المجموعة الوظيفية باستعمال ايش؟ أرقام
+
+80
+00:07:45,870 --> 00:07:50,290
+طبعا هنا لما قلنا one probanol لو كنا بدنا نسميه
+
+81
+00:07:50,290 --> 00:07:54,070
+بالاسم الشائع ال common name المجموعة هذه probel
+
+82
+00:07:54,070 --> 00:08:00,370
+.. probel alcohol الآن هذا two probanolأيزو برو
+
+83
+00:08:00,370 --> 00:08:01,430
+بالالكهول
+
+84
+00:08:15,670 --> 00:08:19,770
+CH حملة تنتين CH3 و كمان كربونة يعني العدد الكلي
+
+85
+00:08:19,770 --> 00:08:25,310
+أربعة إذا هذا شو بدي أسميه Isobutyl يمكن ال I
+
+86
+00:08:25,310 --> 00:08:30,290
+رايحة Isobutyl alcohol طبعا لو بدي أسميه أيوبكنومي
+
+87
+00:08:30,290 --> 00:08:35,990
+كليتشار بدي أسميه بالترقيم و ال OH بدي أكون ماخدة
+
+88
+00:08:35,990 --> 00:08:40,290
+أقل ترقيم يعني بدي أقول واحد اتنين تلاتة إذا هذا
+
+89
+00:08:40,290 --> 00:08:45,440
+one-probanolوانبروبانول على نمر اتنين شو بيحمل
+
+90
+00:08:45,440 --> 00:08:51,200
+الوانبروبانول مثل هاي أطول سلسلة واحد اتنين تلاتة
+
+91
+00:08:51,200 --> 00:08:57,520
+two مثل وانبروبانول فلازم احدد موقع ال ايش ال OH
+
+92
+00:08:57,520 --> 00:09:02,800
+two مثل وانبروبانوللو بننظر لهذا المركب على سبيل
+
+93
+00:09:02,800 --> 00:09:06,460
+المثال كمجموعة لو كنت بدي ال common nomenclature
+
+94
+00:09:06,460 --> 00:09:11,080
+له كمجموعة معروفة tertiary butyl اذا tertiary
+
+95
+00:09:11,080 --> 00:09:14,640
+butyl alcohol طب لو بدي اسميه بال iubac
+
+96
+00:09:14,640 --> 00:09:18,360
+nomenclature مرة تانية بدي اطول سلسلة خليني افترض
+
+97
+00:09:18,360 --> 00:09:24,700
+هي اطول سلسلة واحد اتنين تلاتة اذا هذا a-probanol
+
+98
+00:09:25,770 --> 00:09:31,010
+تو بروبانول لأن ال OH طالعة من موقع اتنين و على
+
+99
+00:09:31,010 --> 00:09:34,730
+اتنين ايضا ايش في عندكم مثل اذا two methyl two
+
+100
+00:09:34,730 --> 00:09:37,370
+probanol is tertiary butyl alcohol
+
+101
+00:09:45,170 --> 00:09:48,790
+الـ Common Nomenclature هو الـ tertiary butyl
+
+102
+00:09:48,790 --> 00:09:52,950
+alcohol في الـ Common Nomenclature الآن هذا
+
+103
+00:09:52,950 --> 00:09:57,150
+المُركّب لو بدأ أطلع على المجموعة اللي فيه لما
+
+104
+00:09:57,150 --> 00:10:02,690
+درفنا ال الكينز أخدنا مجموعتين أخدنا الفينل والألل
+
+105
+00:10:02,690 --> 00:10:06,870
+قلنا الألل اللي هو البروبين اللي بنخص منه هيدروجين
+
+106
+00:10:06,870 --> 00:10:10,780
+من هذا الموقعكل هذا الكلام السكوت اللي بلاحظه على
+
+107
+00:10:10,780 --> 00:10:15,740
+بعض الوجوه اللي أنا مارجعتش كتير هذه مشكلتها واضح؟
+
+108
+00:10:15,740 --> 00:10:20,700
+بدكوا تكونوا متذاكرين هذه المجموعة أخدناها بهذا
+
+109
+00:10:20,700 --> 00:10:25,380
+الشكل اسمها إيش؟ ألل الآن إذا إجي عليها chlorine
+
+110
+00:10:26,360 --> 00:10:30,580
+ألل كلورايت إذا إتي عليها بروم ألل برومايت إذا إتي
+
+111
+00:10:30,580 --> 00:10:36,960
+عليها OH ألل Alcohol فمن ناحية ال Alcohol اعرفنا
+
+112
+00:10:36,960 --> 00:10:42,520
+الآن لو كنا هذا ال ال alcohol بدنا نسميه بال Iopac
+
+113
+00:10:42,520 --> 00:10:48,840
+Nomenclature هنلاحظ إن في عندنا مجمعتين وظيفيتين
+
+114
+00:10:48,840 --> 00:10:53,280
+بدنا ننتبهالان التقاء المجموعات الوظيفية في
+
+115
+00:10:53,280 --> 00:10:58,520
+المركبات هذه تماما زى التقاء المجموعات الوظيفية
+
+116
+00:10:58,520 --> 00:11:02,660
+لما درسنا ال aromatic compounds متذكرين؟ اه قولنا
+
+117
+00:11:02,660 --> 00:11:07,420
+أبسط إشي ال alkanes بعدين ال alkenes و ال alkynes
+
+118
+00:11:07,420 --> 00:11:13,460
+بعدين مثلا ال OH بعدين ال ketone بعدين ال aldehyde
+
+119
+00:11:13,460 --> 00:11:19,890
+بعدين ال acidOkay فلو أنا بدي أجي أطلع أنه عندي OH
+
+120
+00:11:19,890 --> 00:11:27,370
+وعندي ال keen مين بده تكون العائلة ال OH وبناء على
+
+121
+00:11:27,370 --> 00:11:33,050
+ذلك المركب اللي عنده لازم ياخد النهاية all لأن
+
+122
+00:11:33,050 --> 00:11:37,950
+الشيء بتسمى باسم عائلته بياخد النهاية all طبعا هذا
+
+123
+00:11:37,950 --> 00:11:41,490
+لو بدي أطلع عليه واحد و الترقيم من وين هيكون؟
+
+124
+00:11:41,710 --> 00:11:46,310
+بنعندى الالكول واحد اتنين تلاتة طبعا بينا نسميه
+
+125
+00:11:46,310 --> 00:11:51,950
+بروبان all هو فيه double bond فبدل ال a بروبين
+
+126
+00:11:51,950 --> 00:11:58,050
+بيصير بروبين ال يعني لو مافيش عند انا هذا double
+
+127
+00:11:58,050 --> 00:12:02,910
+bond ايش كنت استعمل حرف ال a الآن صار double bond
+
+128
+00:12:02,910 --> 00:12:10,150
+ال الكن صار الكن صار بروبين all واضح بروبين all
+
+129
+00:12:10,150 --> 00:12:18,000
+لاحظواالعائلة إيش؟ all و هو فيه ألكين، الآن ال all
+
+130
+00:12:18,000 --> 00:12:24,470
+لازم نحدد موقعها و ال ألكين لازم نحدد موقعهابتدخل
+
+131
+00:12:24,470 --> 00:12:29,550
+الأرقام ال all على أي موقع جاية على واحد فبنكتب
+
+132
+00:12:29,550 --> 00:12:34,830
+two prob in one all بمعنى أن ال in موجودة على موقع
+
+133
+00:12:34,830 --> 00:12:39,890
+اتنين وال all على موقع واحد مرات هذا ممكن تشوفوه
+
+134
+00:12:39,890 --> 00:12:45,670
+بطريقة تانية يعني يكتبوه a prob و بعدين in و بعدين
+
+135
+00:12:45,670 --> 00:12:52,100
+all و يحددوا أن ال in على أي موقع اتنينع اتنين و
+
+136
+00:12:52,100 --> 00:12:56,080
+ال all على اي موقع لاحظوا اختلاف بسيط هنا في
+
+137
+00:12:56,080 --> 00:13:00,160
+الكتاب يعني عملنا تقطيع في الاسم حددنا وين ال in و
+
+138
+00:13:00,160 --> 00:13:05,100
+وين ال all هنا نفس الاشي و فهمنا ضمنا ان اتنين
+
+139
+00:13:05,100 --> 00:13:11,180
+اللي كتبت برا هي تعنيموقع ال in و ال all جنبها ف
+
+140
+00:13:11,180 --> 00:13:16,000
+two probine one all او prob two in one all هو نفس
+
+141
+00:13:16,000 --> 00:13:20,560
+الاسم يعني طريقتين لكتابة نفس الاسم في كتير طلاب
+
+142
+00:13:20,560 --> 00:13:25,320
+بيحبوا يقولوا في الأول هذا كله probine all جنب ال
+
+143
+00:13:25,320 --> 00:13:30,140
+in بالظبط بيحطوا الرقم جنب ال all بالظبط بيحطوا
+
+144
+00:13:30,140 --> 00:13:32,140
+الرقم تبعها
+
+145
+00:13:35,230 --> 00:13:39,650
+فهذه الطريقة اللي احنا بنستعملها لما بلتقى عندنا
+
+146
+00:13:39,650 --> 00:13:44,370
+اكثر من مجموعة وظيفية لاحظوا بدي اجي مباشرة على
+
+147
+00:13:44,370 --> 00:13:50,650
+هذا المثال لانه على نفس الفكرة طلع هذا المثال ايش
+
+148
+00:13:50,650 --> 00:13:58,180
+العائلات اللي موجودة فيه؟ال all و ال I ال ال مين
+
+149
+00:13:58,180 --> 00:14:04,120
+أعلى في الأولوية ال all إذا لو عديت العدد لكل واحد
+
+150
+00:14:04,120 --> 00:14:11,880
+اتنين تلاتة أربعة خمسة إيش هيكون كمركب؟ بين two
+
+151
+00:14:11,880 --> 00:14:17,960
+all بين two all هيني ذكرت المجموعتين لما أنا أقول
+
+152
+00:14:17,960 --> 00:14:21,240
+بين I
+
+153
+00:14:22,480 --> 00:14:29,500
+all هذه المجموعتين في I و في all الآن بلزم أن احدد
+
+154
+00:14:29,500 --> 00:14:36,960
+موقعهم ال all على اي موقع و ال I على تلاتة بنت
+
+155
+00:14:36,960 --> 00:14:42,140
+اثري I one all او لو كتبت اثري بنتين بتفهم ان ال
+
+156
+00:14:42,140 --> 00:14:47,160
+three هذي بتحدد موقع ال I اثري بنتين one all او
+
+157
+00:14:47,160 --> 00:14:52,500
+بنت اثري I one all نفس الفكرة تماماواضح؟ نفس
+
+158
+00:14:52,500 --> 00:14:57,360
+المُركّب فهذا الكلام اللي بيصير عندنا لما بلتقي
+
+159
+00:14:57,360 --> 00:15:05,380
+أكثر من مجموعة وظيفية الان ممكن يكون عندي alcohol
+
+160
+00:15:05,380 --> 00:15:13,120
+على حلقات ال alcohol على الحلقة .. الحلقة مش زي
+
+161
+00:15:13,120 --> 00:15:18,620
+السلسلةالحلقة ما لهاش بداية و نهاية يعني لما يكون
+
+162
+00:15:18,620 --> 00:15:24,200
+عندي انا خمس درات كربون كسلسلة باجي بقول بضحوط ال
+
+163
+00:15:24,200 --> 00:15:31,460
+OH هنا بسميه one بنتانول هنا two بنتانول three
+
+164
+00:15:31,460 --> 00:15:35,760
+بنتانول برجع طبعا two بنتانول اذا في عندي في
+
+165
+00:15:35,760 --> 00:15:40,150
+السلسلةone pentanol و two pentanol و three
+
+166
+00:15:40,150 --> 00:15:46,600
+pentanol لكن لو هذه السلسلة صارت حلقة خماسيةالان
+
+167
+00:15:46,600 --> 00:15:50,420
+سواء كتبة ال او اتش هان او هان او هان او هان او
+
+168
+00:15:50,420 --> 00:15:54,220
+هان جميع المواقع متكافئة مافيش فيها موقع واحد يعني
+
+169
+00:15:54,220 --> 00:15:58,800
+مابيقدرش الإنسان الحلقة يقول وين بدايتها ولذلك هذا
+
+170
+00:15:58,800 --> 00:16:04,200
+بتسمى cyclopentanol بدون ما نحطله one أو two لأن
+
+171
+00:16:04,200 --> 00:16:11,240
+كل المواقع واحد واضح؟ cyclopentanol لكن وقتش بيلزم
+
+172
+00:16:11,240 --> 00:16:16,930
+ترقيملو كان عندى اكتر من مجموعة عشان اشوف انه هذه
+
+173
+00:16:16,930 --> 00:16:23,610
+المجموعات انه هذه المجموعات هل يا ترى واحد اتنين
+
+174
+00:16:23,610 --> 00:16:27,250
+ولا واحد تلاتة ايش العلاقة بينها يعني لو كان
+
+175
+00:16:27,250 --> 00:16:31,030
+المركب بهذا الشكل والمجموعتين على جهة واحدة هذا
+
+176
+00:16:31,030 --> 00:16:38,930
+ايش هسميه one two cyclopentane by all all و all
+
+177
+00:16:39,860 --> 00:16:44,680
+Diol واضح؟ one two cycle وبنتين ديول وحنقول إيش
+
+178
+00:16:44,680 --> 00:16:52,140
+مالهم؟ sis طبعا ممكن نتخيل مركب بهذا الشكل لو
+
+179
+00:16:52,140 --> 00:16:58,860
+افترضنا هنا في عندنا OH وهنا في عندنا CL وإيجا
+
+180
+00:16:58,860 --> 00:17:05,680
+بدنا نسميه الآن أكيد ال alcohol أساس أقوى من ال CL
+
+181
+00:17:05,680 --> 00:17:12,110
+إذا المركب إيش هيكون؟cyclopentanol بتخيلوا من وين
+
+182
+00:17:12,110 --> 00:17:17,070
+بيبدأ الترقيم؟ و
+
+183
+00:17:17,070 --> 00:17:23,270
+بناء على ذلك مثل هذا المركب هيصير three .. فيش
+
+184
+00:17:23,270 --> 00:17:31,050
+ميتة ميتة في البنزينة خلصنا منها بس في البنزينة مش
+
+185
+00:17:31,050 --> 00:17:37,190
+في الحلقات إذا هذا three chloro cyclopentanol
+
+186
+00:17:37,370 --> 00:17:44,590
+بنتانول مش بنتين Cyclopentanol خلاص مابنكتبش one
+
+187
+00:17:44,590 --> 00:17:48,150
+لأنه يفهم ضمنا أن الترقيم بدأ من عندها يعني
+
+188
+00:17:48,150 --> 00:17:52,770
+مابنكتبش three chloro cyclopentane one all أو one
+
+189
+00:17:52,770 --> 00:17:57,310
+cyclopentanol لأ three chloro cyclopentanol و هكذا
+
+190
+00:17:57,310 --> 00:17:58,110
+واضح؟
+
+191
+00:18:00,740 --> 00:18:06,080
+الان احيانا بلتقي عندى الجزء ال aliphatic مع ال
+
+192
+00:18:06,080 --> 00:18:10,320
+aromatic وسبق احنا لما أخدنا ال aromatic compounds
+
+193
+00:18:10,320 --> 00:18:16,020
+نوّهنا لهذه النقطة قولنا انه ممكن نسمي المركب بأحد
+
+194
+00:18:16,020 --> 00:18:21,560
+طريقين اما ان نعتبر الأساس بنزين و اكتشف نعتبر
+
+195
+00:18:21,560 --> 00:18:26,600
+الأساس بنزينإذا هذه المجموعة اللي موجودة سهلة ولها
+
+196
+00:18:26,600 --> 00:18:31,460
+اسم بسيط عارفينه طب إذا مش مجموعة سهلة وملاش اسم
+
+197
+00:18:31,460 --> 00:18:39,480
+بسيط بعتبر نفسي بتعامل مع المركب كالكين بتعامل مع
+
+198
+00:18:39,480 --> 00:18:45,620
+المركب كالكين هذا الالكين هيطول سلسلة فيه في نمرة
+
+199
+00:18:45,620 --> 00:18:50,780
+واحد اتنين ويحمل مجموعة ايش اسم هذه المجموعة فنل
+
+200
+00:18:51,570 --> 00:18:56,330
+البنزينة اللى خصمنا منها H كمجموعة شو بنسميها؟ فنل
+
+201
+00:18:56,330 --> 00:18:59,970
+طبعا لاحظوا المركب اللى فيه ذرتين كربون هو اي
+
+202
+00:18:59,970 --> 00:19:06,470
+مركب؟ الاثانول اذا هذا لو كنا بنسميه شو هنسميه؟
+
+203
+00:19:06,470 --> 00:19:08,790
+two phenyl اثانول
+
+204
+00:19:11,950 --> 00:19:16,070
+يفهم على طول مباشرة طالما كتبنا two أن الـ O على
+
+205
+00:19:16,070 --> 00:19:22,430
+واحد و هذا على اتنين لاحظوا لو مثلا جبنا مركب شبيه
+
+206
+00:19:22,430 --> 00:19:29,390
+فيه بهذا الشكل هاي ذارتين كربون و حطينا الـ OH هنا
+
+207
+00:19:29,390 --> 00:19:30,970
+و البنزينة هنا
+
+208
+00:19:35,020 --> 00:19:39,080
+لاحظوا هذا isomer .. structural isomer كربون تنتين
+
+209
+00:19:39,080 --> 00:19:42,140
+كانت ال O H على الكربون الأولى و البنزينة على
+
+210
+00:19:42,140 --> 00:19:45,080
+التانية حطينا ال O H على الأولى و البنزينة على
+
+211
+00:19:45,080 --> 00:19:53,120
+الأولى فلو بدنا نيجي نقول بدنا نسمي هذا one phenyl
+
+212
+00:19:53,120 --> 00:20:00,180
+one ethanol مواد هيك إيثانول
+
+213
+00:20:03,690 --> 00:20:10,650
+عشان نضع رقم وان فينيل وان إيثانول واضح؟ وان فينيل
+
+214
+00:20:10,650 --> 00:20:14,350
+وان إيثانول عشان التوضيح يعني دائما في موضوع
+
+215
+00:20:14,350 --> 00:20:19,430
+الأرقام إذا حسيت أن في شيء confusing لازمة أرقام
+
+216
+00:20:19,430 --> 00:20:25,250
+إضافية نضعها مش لازمة أرقام إضافية مافيش داعي أن
+
+217
+00:20:25,250 --> 00:20:29,470
+نضع الأرقام مايتضح بدون أرقام لا نستعمل له الأرقام
+
+218
+00:20:29,470 --> 00:20:35,310
+يعني هنابتمشي بدون أرقام بيبطل فيه لزوم ان اكتب
+
+219
+00:20:35,310 --> 00:20:39,490
+one على سبيل المثال one cyclopentanol خلاص
+
+220
+00:20:39,490 --> 00:20:45,030
+فالأرقام عندها غرض ايش الغرض تبعها التوضيح لما
+
+221
+00:20:45,030 --> 00:20:49,350
+بيصير في لبس معين بحتاج ان نحط الأرقام عشان نوضح
+
+222
+00:20:49,350 --> 00:20:56,350
+بنستعملها طبعا ال aromatic alcohol انجاز التعبير
+
+223
+00:20:56,350 --> 00:21:03,280
+الأساس فيهمالفينول مر علينا تسميته وقلنا لو ال OH
+
+224
+00:21:03,280 --> 00:21:08,480
+مع ال نيترو مين الأساس الفينول إذا هذا para-nitro
+
+225
+00:21:08,480 --> 00:21:14,260
+أو four-nitroفينول لكن بدكوا تنتبهوا لنقطة أن نفس
+
+226
+00:21:14,260 --> 00:21:21,020
+هذه الفينول لو انوجدت مع مجموعات أعلى منها هترجع
+
+227
+00:21:21,020 --> 00:21:26,620
+لأصلها يعني هذه حامض C double bond O OH acidو
+
+228
+00:21:26,620 --> 00:21:31,380
+Alcohol من الأعلى؟ ال acid ولذلك هذا المُركّب
+
+229
+00:21:31,380 --> 00:21:35,620
+Benzoic acid على موقع Ortho، إيش عندكم؟
+
+230
+00:21:39,360 --> 00:21:44,420
+Orthohydroxy benzoic acid أو two hydroxy benzoic
+
+231
+00:21:44,420 --> 00:21:51,020
+acid طبعا هذا ماخد اسم شهرة salicylic acid ماخد
+
+232
+00:21:51,020 --> 00:21:54,720
+اسم شهرة ايش؟ salicylic acid ال salicylic acid هو
+
+233
+00:21:54,720 --> 00:21:59,760
+الحامض اللي بيطلو عادة من شجر الصفصاف وهو أساس
+
+234
+00:21:59,760 --> 00:22:05,680
+تحضير الأسبيرين هو أساس تحضير الأسبيرينيعني
+
+235
+00:22:05,680 --> 00:22:11,960
+الأسبيرين عادة بيشتقوا من هذا الحامض بيبدلوا ال H
+
+236
+00:22:11,960 --> 00:22:16,400
+اللي موجودة هنا على ال OH شايفين هذه ال OH هذه ال
+
+237
+00:22:16,400 --> 00:22:20,140
+H بنبدلها و بنحط مكانها هذه المجموعة
+
+238
+00:22:23,720 --> 00:22:26,920
+الناس اللي حفظوا معنا هذه المجموعة أخدناها لجامن
+
+239
+00:22:26,920 --> 00:22:32,840
+الـ acetic acid أسيتل فبصير المركب بدل salicylic
+
+240
+00:22:32,840 --> 00:22:35,140
+acid أسيتو
+
+241
+00:22:37,400 --> 00:22:42,540
+acetosalicylic acid هو الاسبيرين واضح فالاسبيرين
+
+242
+00:22:42,540 --> 00:22:47,480
+هو ال salicylic acid لكن انا شيلت منه ال H وحطيت
+
+243
+00:22:47,480 --> 00:22:52,940
+مكانها C double bond O CH3 فبصير الاسم المشهور
+
+244
+00:22:52,940 --> 00:23:00,080
+للاسبيرين ايش acetosalicylic acidacetosalicylic
+
+245
+00:23:00,080 --> 00:23:04,860
+acid المثال الأخير اللي موجود في هذا ال slide هو
+
+246
+00:23:04,860 --> 00:23:10,280
+التقاء الديهايد مع الكهول لحظة متذكرين لما قلنا
+
+247
+00:23:10,280 --> 00:23:16,280
+الكهول الديهايدي ماكتبوش COH CHO وهذا لو كنا
+
+248
+00:23:16,280 --> 00:23:21,960
+بنفسرها بال structure كيف بنفسرها بنفسرها C double
+
+249
+00:23:21,960 --> 00:23:29,730
+bond OHهذه تفاصيلها C double bond OH لما بنكتبها
+
+250
+00:23:29,730 --> 00:23:34,750
+كتابة كيف بنكتبها CHO فهذه مجموعة ال الديهايد الان
+
+251
+00:23:34,750 --> 00:23:39,350
+ال الديهايد أعلى من الألكوهول ولذلك المركب اللي
+
+252
+00:23:39,350 --> 00:23:46,490
+عندي هنا بنز الديهايد على موقع متا هيدروكسي
+
+253
+00:23:46,490 --> 00:23:50,050
+متا هيدروكسي بنز الديهايد
+
+254
+00:23:54,320 --> 00:23:59,120
+هذا بشكل عام بالنسبة لتسمية الكحولات و ال phenols
+
+255
+00:23:59,120 --> 00:24:04,180
+لما نصل لل thyols اللي فيهم SH بناخد تسميتهم بشكل
+
+256
+00:24:04,180 --> 00:24:05,240
+منفصل
+
+257
+00:24:07,650 --> 00:24:14,410
+الان كنا عارفين شغلة ان الكحولات طالما فيهم OH إذا
+
+258
+00:24:14,410 --> 00:24:19,550
+اللي بيعملوا إيش هيدروجين bonding بيعملوا هيدروجين
+
+259
+00:24:19,550 --> 00:24:23,530
+bonding اللي مقصود بالهيدروجين bonding أن ذرة
+
+260
+00:24:23,530 --> 00:24:27,330
+الهيدروجين في الكحولات تحديدا بتكون محصورة بين
+
+261
+00:24:27,330 --> 00:24:32,400
+ذرتين أكسجينوبشكل عام إذا إنتوا متذكرين من المدارس
+
+262
+00:24:32,400 --> 00:24:37,380
+الـ hydrogen bonding بيكون إذا حصرت الهيدروجين بين
+
+263
+00:24:37,380 --> 00:24:43,440
+electronegative atoms محددة تلت ذرات شو هما؟
+
+264
+00:24:43,440 --> 00:24:48,680
+Oxygen و Nitrogen و Fluor سواء كان على اليمين أو
+
+265
+00:24:48,680 --> 00:24:52,360
+الشمال يعني بين تنتين Oxygen، بين تنتين Nitrogen،
+
+266
+00:24:52,360 --> 00:24:55,260
+بين تنتين Fluor، بين Oxygen وNitrogen، Oxygen و
+
+267
+00:24:55,260 --> 00:25:00,810
+Fluor الهيدروجين لما بتحصربين ذرتين
+
+268
+00:25:00,810 --> 00:25:05,130
+electronegative بهذا الشكل بتكون رابطة أساسية
+
+269
+00:25:05,130 --> 00:25:10,270
+رابطة أساسية مع ذرة و رابطة هيدروجينية مع الذرة
+
+270
+00:25:10,270 --> 00:25:15,130
+التانية يعني لو كنا بدنا نوضح بالظبط ال hydrogen
+
+271
+00:25:15,130 --> 00:25:20,670
+bonding في الألكوهول حتى ما نتغلب هيكون بهذا الشكل
+
+272
+00:25:20,670 --> 00:25:23,350
+ال hydrogen bonding في الألكوهول تخيلوا مثلا
+
+273
+00:25:23,350 --> 00:25:27,990
+الميثانول CH3O
+
+274
+00:25:29,040 --> 00:25:34,620
+H هذا الجزء و في كم زوج إلكتروناتها اتنين الان لو
+
+275
+00:25:34,620 --> 00:25:43,280
+بدى اجيب انا جزء كحول تاني CH3 OH وهي كمان زوجين
+
+276
+00:25:43,280 --> 00:25:53,130
+إلكترونات الان هذا جزء و هذاهذه الروابط الـ OH
+
+277
+00:25:53,130 --> 00:25:57,370
+اللي هنا رابطة أصلية Intramolecular bond و الـ OH
+
+278
+00:25:57,370 --> 00:26:01,510
+اللي هنا Intramolecular bond لو أنا إجيت أعملت بين
+
+279
+00:26:01,510 --> 00:26:07,070
+هذه الـ H و هذا زوج الإلكترونات رابطة هذا الرابطة
+
+280
+00:26:07,070 --> 00:26:13,230
+الهيدروجينية هذا الـ hydrogen bondهذا الهيدروجين
+
+281
+00:26:13,230 --> 00:26:18,630
+بوند الان لاحظوا معي ان الهيدروجين بوند ولا بحال
+
+282
+00:26:18,630 --> 00:26:23,090
+من الأحوال قوتها بتصل لقوة هذه الرابطة الأساسية
+
+283
+00:26:23,090 --> 00:26:27,450
+يعني هذه الهيدروجين بوند اللي بين الجزيئين قوتها
+
+284
+00:26:27,450 --> 00:26:32,070
+تقريبا بين خمسة لعشرة في المية من قوة الرابطة
+
+285
+00:26:32,070 --> 00:26:38,900
+الأصلية اللي هنا يعني هذه مقارنة بهذه خمسةالى 10%
+
+286
+00:26:38,900 --> 00:26:43,280
+من قوة الرابط الاصلية لهنا بناء على ذلك لو احنا
+
+287
+00:26:43,280 --> 00:26:49,460
+بدنا نعمل عملية تسخين او غليان نكسر روابط بالطاقة
+
+288
+00:26:49,460 --> 00:26:55,080
+اى رابط اللى بدأت نكسر هادي وبطير هذا الكحول لوحده
+
+289
+00:26:55,080 --> 00:26:59,840
+وبطير بتبخر هذا الكحول لوحدهبس ماحد بيقول اللي
+
+290
+00:26:59,840 --> 00:27:05,680
+بنكسر هذه الرابطة بالغليان، الغليان بيكسر الروابط
+
+291
+00:27:05,680 --> 00:27:10,040
+الـ Intermolecular forces، الروابط بين الجزيئات،
+
+292
+00:27:10,040 --> 00:27:14,080
+هذا جزيء و هذا جزيء بينهم رابطة ضعيفة هي اللي
+
+293
+00:27:14,080 --> 00:27:19,070
+بتتفكك و بتنكسر، بس بالتأكيدمش ال intramolecular
+
+294
+00:27:19,070 --> 00:27:22,330
+force الرابطة الأصلية اللي بتنكسر، لأ ال
+
+295
+00:27:22,330 --> 00:27:26,110
+intermolecular force يعني لو سخننا مثلا و بدنا
+
+296
+00:27:26,110 --> 00:27:30,110
+نعمل غليان أو كان بتبخر حتى مع ارتفاع الحرارة أي
+
+297
+00:27:30,110 --> 00:27:35,190
+رابطة اللي بتنكسر، هذه الرابطة بيصير كل جزء ينفصل
+
+298
+00:27:35,190 --> 00:27:41,000
+لإيش؟ لوحده، واضح؟طبعا انتبهوا معي وجود ال
+
+299
+00:27:41,000 --> 00:27:47,460
+hydrogen bond هادي بتخلي الكحول جزيئاته مترابطة
+
+300
+00:27:47,460 --> 00:27:52,040
+اذا نقطة غليانه نسبيا ايش بتكون عالية يعني هذا
+
+301
+00:27:52,040 --> 00:27:56,580
+الميثانول على سبيل المثال نقطة غليانه 65 درجة
+
+302
+00:27:56,580 --> 00:28:02,190
+مئويةمقارنة بمركبات مش فيها hydrogen bonding زي ال
+
+303
+00:28:02,190 --> 00:28:07,630
+الكنز تعتبر نقطة غليان عالية طيب لو قلنا بدنا
+
+304
+00:28:07,630 --> 00:28:13,610
+نقارن هذا الميثانول بالمية طب ليش؟ مع العلم أن
+
+305
+00:28:13,610 --> 00:28:20,130
+وزنها الجزائي أقل و
+
+306
+00:28:20,130 --> 00:28:24,800
+أنا هيدروجينيةعندى تلتين رابطين زى ما .. الميه
+
+307
+00:28:24,800 --> 00:28:29,020
+عندها الإمكانية بالظبط تعمل رابطتين هيدروجينيتين
+
+308
+00:28:29,020 --> 00:28:34,140
+مش رابط يعني الجزيئات بتترابط بشكل أقوى لما انتوا
+
+309
+00:28:34,140 --> 00:28:40,860
+بدكم تقولوا فى عندكم OHH نفترض الآن هذا الجزيئ لو
+
+310
+00:28:40,860 --> 00:28:47,560
+بدى أجيبله جزيئ تانى بهذا الشكل OHH وهنا كمان OHH
+
+311
+00:28:47,560 --> 00:28:49,740
+هى تلت جزيئات نفترض
+
+312
+00:28:52,840 --> 00:28:57,600
+الان هنا في عندي أزواج إلكترونات بيصير رابطة
+
+313
+00:28:57,600 --> 00:29:02,380
+هيدروجينية من هنا إذا أنا لو هذا بدي أفكه كام
+
+314
+00:29:02,380 --> 00:29:07,300
+رابطة هيدروجينية بدي أكسر؟ تنتين مش واحدة فالمي
+
+315
+00:29:07,300 --> 00:29:14,220
+لأنها H2 بيكون فيها روابط هيدروجينية إيش؟ أكتر من
+
+316
+00:29:14,220 --> 00:29:20,840
+الكحولاتلاحظوا يعني لو الإنسان بده يحكي شوية بمنطق
+
+317
+00:29:20,840 --> 00:29:27,440
+الفلسفة .. بمنطق الفلسفة الميه
+
+318
+00:29:27,440 --> 00:29:36,700
+يمكن مشروب لذيذ و أحل الحلال تمام؟ و الكحولات
+
+319
+00:29:36,700 --> 00:29:43,800
+بعضهاسام وبعضها خمر وبعضها مفيد يعني الكحولات
+
+320
+00:29:43,800 --> 00:29:50,300
+ماحدش يستعمل المصطلح الحديث إنه الكحولات بشكل عام
+
+321
+00:29:50,300 --> 00:29:57,460
+ضارة أو الكحولات محرمة لأ الكحولات عائلة عائلة
+
+322
+00:29:57,460 --> 00:30:04,440
+كبيرة هذه العائلة في منها مواد سامة في منها مواد
+
+323
+00:30:04,440 --> 00:30:11,100
+مسكرة في منها مواد مفيدةواضح؟ في منها مواد سامة
+
+324
+00:30:11,100 --> 00:30:16,420
+وفي مسكر وفي مفيد حسب طبيعة ال ايش ال R أو
+
+325
+00:30:16,420 --> 00:30:21,960
+المجموعة الان لو انا بدأ اتخيل ان الكحولات بنائها
+
+326
+00:30:21,960 --> 00:30:26,460
+الأساسي ال O H و اجي اقول أبسط الكحولات .. أبسط
+
+327
+00:30:26,460 --> 00:30:34,300
+الكحولات يعني هي عندي O H .. O H .. O H الان خليني
+
+328
+00:30:34,300 --> 00:30:43,510
+اجي احط هناقبل ال CH3 H أحط هنا CH3 و أحط هنا CH2
+
+329
+00:30:43,510 --> 00:30:51,780
+CH3لاحظوا أبسط مركّب هيكون الميّه طبعا الميّه ما
+
+330
+00:30:51,780 --> 00:30:55,980
+بنصنفهاش احنا مركّب عضوي لسبب بسيط ان مافيش فيها
+
+331
+00:30:55,980 --> 00:31:00,200
+carbon المركّب العضوي فيه carbon لكن لو الإنسان
+
+332
+00:31:00,200 --> 00:31:06,300
+بتأمل من ناحية الخواص الميّه كتير في خواصها بتشبه
+
+333
+00:31:06,300 --> 00:31:10,450
+الكحولاتكخواص كيميائية يعني لو بدأت أتكلم عن نقطة
+
+334
+00:31:10,450 --> 00:31:14,770
+غليان مرتفعة لو بدأ أتكلم عن تفاعل مع السوديوم لو
+
+335
+00:31:14,770 --> 00:31:19,490
+بدأ أتكلم بعد شوية لما أخد الحامضية هلاحظ أن
+
+336
+00:31:19,490 --> 00:31:24,310
+حامضية الماء زي حامضية الكحولات بالظبط يعني نفس
+
+337
+00:31:24,310 --> 00:31:29,630
+القوة الحامضية عشان هيك بنقول للبني آدم غسل بالمية
+
+338
+00:31:29,630 --> 00:31:34,350
+إيدك بنضره ولا لأ؟ بندرهش كلنا بنغسل بالمية طب
+
+339
+00:31:34,350 --> 00:31:39,160
+الكحولات؟بعد شوية لما تصيروا تعملوا مزارع بكتيريا
+
+340
+00:31:39,160 --> 00:31:41,840
+اللي بتخصصوا تحاليل طبية و إشي بعد ما يشتغلوا
+
+341
+00:31:41,840 --> 00:31:44,860
+بالبكتيريا بدهم يطهروا إيديهم بإيش بيغسلوا
+
+342
+00:31:44,860 --> 00:31:50,960
+بالإيثانول بالإيثانول اللي هو الكحول نفسه تبع
+
+343
+00:31:50,960 --> 00:31:56,420
+الخمر بيغسله فيه واضح؟ الآن لاحظوا أن الماء شراط
+
+344
+00:31:56,420 --> 00:32:04,660
+الميثانول poisonous الإيثانول
+
+345
+00:32:05,860 --> 00:32:10,060
+اللي هو الخمرة الاثانول
+
+346
+00:32:10,060 --> 00:32:13,760
+المكون الأساسي هو اللي بيسبب الاسكار في الخمر
+
+347
+00:32:13,760 --> 00:32:21,200
+والميه اللي هي أبسط مشروب فيهم الميه
+
+348
+00:32:21,200 --> 00:32:27,540
+مشروب جيد وممتاز هيجيكم كمان فكرة طالما ذكرنا هذا
+
+349
+00:32:27,540 --> 00:32:36,600
+الكلام هيجيكم كمان فكرة ان الاثانول في مشكلةإن هو
+
+350
+00:32:36,600 --> 00:32:42,540
+من أفضل المذيبات لإجراء التفاعلات الكيميائية ومطهر
+
+351
+00:32:42,540 --> 00:32:47,280
+يعني أنا بدي إياه يكون متوفر وبسعر رخيص يعني ال
+
+352
+00:32:47,280 --> 00:32:53,180
+letter يكون مثلا بتلاتة أربعة shekel بدولار واضح؟
+
+353
+00:32:58,850 --> 00:33:06,070
+بنغسل الأوان الذجاجية بالإيثانول بالإيثانول
+
+354
+00:33:06,070 --> 00:33:06,070
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+355
+00:33:06,070 --> 00:33:07,350
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+356
+00:33:07,350 --> 00:33:07,350
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+357
+00:33:07,350 --> 00:33:07,350
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+358
+00:33:07,350 --> 00:33:07,510
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+359
+00:33:07,510 --> 00:33:08,990
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+360
+00:33:08,990 --> 00:33:11,110
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+361
+00:33:11,110 --> 00:33:11,110
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+362
+00:33:11,110 --> 00:33:14,620
+بالإيثانول بالإصناعة الخمور هذه بحث ذاتها علم يعني
+
+363
+00:33:14,620 --> 00:33:19,560
+ملايين الفدانات بتكون مزروعة عنب اللي بيعملوا منه
+
+364
+00:33:19,560 --> 00:33:23,440
+الخمر و بدهوا مياه تكون بسعر غالي و زجاجة النبيذ
+
+365
+00:33:23,440 --> 00:33:27,100
+بسعر معين طب هى الاساس اللى فيها اللى بيعمل كل
+
+366
+00:33:27,100 --> 00:33:32,400
+المشاكل مين ال Ethanol اذا ال Ethanol صار مطلوب
+
+367
+00:33:32,400 --> 00:33:36,380
+عند العلماء و عند الكيميائين و عند الصناعة انه
+
+368
+00:33:36,380 --> 00:33:42,680
+ينباع رخيصو ممكن يتحضروا ينباع رخيص ومطلوب عند
+
+369
+00:33:42,680 --> 00:33:49,920
+الناس اللي بيصنعوا الخمر انه ينباع ايش؟ غالب لأنه
+
+370
+00:33:49,920 --> 00:33:54,300
+هذه صناعة في العالم الغربي و بدها تربح طب ايش
+
+371
+00:33:54,300 --> 00:33:57,940
+الحل؟ العالم والكيميائي بيقول بدي ايه ايه ايه ايه
+
+372
+00:33:57,940 --> 00:33:58,840
+ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه
+
+373
+00:33:58,840 --> 00:34:06,690
+ايه ايه ايه ايه ايه ايه ايه ايه ايهجالوا بسيطة
+
+374
+00:34:06,690 --> 00:34:14,050
+للكيميائيين جالولهم بنبيعكم إيثانول رخيص بس بشرط
+
+375
+00:34:14,050 --> 00:34:21,280
+عارفين إيش الشرط انسموا اللي ما تشربوهوشيعني هم
+
+376
+00:34:21,280 --> 00:34:24,220
+بدوا ميثاق أنه اللي بده يشرب إيثانول و اللي بده
+
+377
+00:34:24,220 --> 00:34:28,180
+يشرب خمره بده يدفع كتير طب ييجي بني آدم بده يلحق
+
+378
+00:34:28,180 --> 00:34:32,340
+عليهم بالله بيعوني إيثانول أنا بدي أستعمله للصناعة
+
+379
+00:34:32,340 --> 00:34:38,000
+و يروح يشربه برخيص خسروا الجماعة فقالوا بنبيعكيا
+
+380
+00:34:38,000 --> 00:34:44,900
+للصناعة بس ما تشربوش في ثقة متبادلة أنه يلتزم طب
+
+381
+00:34:44,900 --> 00:34:51,240
+إيش عملوه؟ قالوا بنحط فيه شوية سماللي لو شربته
+
+382
+00:34:51,240 --> 00:34:56,780
+تموت، تبقوا معاه، يعني لو الواحد شرب الاثانول بتاع
+
+383
+00:34:56,780 --> 00:35:03,800
+المختبر، بده يموت، إذا الإنسان شرب اثانول المختبر،
+
+384
+00:35:03,800 --> 00:35:07,240
+شو بده يصير فيه؟ بده يموت، طب إيش السم اللي بدكوا
+
+385
+00:35:07,240 --> 00:35:11,920
+تحطوه في الاثانول؟ جالي شوية ميثانول صغيرة،
+
+386
+00:35:11,920 --> 00:35:18,250
+الميثانول سام، يا بيموت يا بيعمىواضح؟ فال Ethanol
+
+387
+00:35:18,250 --> 00:35:21,330
+اللي في المختبر .. ال Ethanol اللي في المختبر
+
+388
+00:35:21,330 --> 00:35:26,570
+مسموم ممنوع أن البني أدم يشربه مخلوط بشوية إيش؟
+
+389
+00:35:26,570 --> 00:35:31,470
+Methanol. الآن إذا إجا لا سمح الله واحد جاهل بده
+
+390
+00:35:31,470 --> 00:35:35,510
+يحضر خمرة للغلابة و الفجرة و جاب منها ال Ethanol
+
+391
+00:35:35,510 --> 00:35:40,090
+الارخيص و حط في جزايز و باع و يلا اشربه شو بده
+
+392
+00:35:40,090 --> 00:35:48,340
+يصير فيهم؟ بدهم يموتواواضح؟ شو بده يصير فيهم؟ بدهم
+
+393
+00:35:48,340 --> 00:36:00,480
+يموتوا ويعيادوا بالله على أي حال، هذا الحادث مش
+
+394
+00:36:00,480 --> 00:36:06,270
+زمان صارجابل سنتين بس في ال 2013 عملها واحد
+
+395
+00:36:06,270 --> 00:36:10,750
+بالليبيا اول ما الدنيا صارت فوضى هناك راح اعمل هذا
+
+396
+00:36:10,750 --> 00:36:15,830
+الكلام و اقرأ التقرير لان انا بفرجيكوا تقرير من
+
+397
+00:36:15,830 --> 00:36:25,630
+تقرير حديث يعني لو بتطلع التاريخ 13.03.2003 2013
+
+398
+00:36:25,630 --> 00:36:26,950
+بالظبط
+
+399
+00:36:28,750 --> 00:36:34,410
+قدرين تقرأوا العنوان؟ ارتفاع عدد الموتى بسبب الخمر
+
+400
+00:36:34,410 --> 00:36:41,610
+المغشوشة لستين و هذا الكلام بتلت عشر تلاتة تداولته
+
+401
+00:36:41,610 --> 00:36:47,510
+وكلات الأنباء و ليش وصلوا لستين حالة و أكتر من
+
+402
+00:36:47,510 --> 00:36:52,310
+سبعميت حالة تسمم لأنهم
+
+403
+00:36:53,460 --> 00:36:58,040
+التسمم نجب عن مادة نجمة عن مادة مشروب كحول محل
+
+404
+00:36:58,040 --> 00:37:03,500
+الصناع والميثانول الذي يستخدم ايضا كوقود يضاف
+
+405
+00:37:03,500 --> 00:37:05,420
+احيانا بكميات صغيرة
+
+406
+00:37:13,840 --> 00:37:18,100
+يضاف أحيانا بكميات صغيرة في المشروبات الكحولية
+
+407
+00:37:18,100 --> 00:37:23,820
+التي تنتج سرا هو مش لزيادة المفعول يضاف يضاف أساسا
+
+408
+00:37:23,820 --> 00:37:29,800
+كتسميم لإيش لل إيثانول عشان الناس مايشربوش، الآن
+
+409
+00:37:29,800 --> 00:37:34,880
+هذا جاب إيثانول من تبع الكيمويات حطه عم الخمرة
+
+410
+00:37:36,080 --> 00:37:40,080
+ماتوا الناس اللي شربوا بالإضافة للناس اللي اتسمموا
+
+411
+00:37:40,080 --> 00:37:44,540
+و اللي أصيبوا بالإيش؟ بالعمى .. بالعمى و لذلك حتى
+
+412
+00:37:44,540 --> 00:37:48,240
+و أنتم تشتغلوا في المختبر نفترض أنكم كنتوا بتسخنوا
+
+413
+00:37:48,240 --> 00:37:53,060
+شغلة فيها إيثانول ما تعرضوش أنفسكم كتير لبخار
+
+414
+00:37:53,060 --> 00:37:58,680
+الإيثانولاللي تتنفسوا إيثانول يدخل لجسمكم من خلال
+
+415
+00:37:58,680 --> 00:38:03,660
+الجهاز التنفسي و يصل لعينيكم واضح؟ مثل هذه التجارب
+
+416
+00:38:03,660 --> 00:38:08,060
+و الأشياء لازم كيف تنشغل بخزانة أبخرة تشفطها مش
+
+417
+00:38:08,060 --> 00:38:13,300
+بني آدم بيعمل تجربة و بيسخن إيثانول و بيشتغل بدون
+
+418
+00:38:13,300 --> 00:38:17,040
+ما يعرف اللي بيشتغل كيميا هذه الكيميائيات بيتعامل
+
+419
+00:38:17,040 --> 00:38:22,520
+معاها كيف؟بأسلوب ضمن التحذيرات قبل ما بيمسك المادة
+
+420
+00:38:22,520 --> 00:38:27,600
+الإنسان بيكون فهمها و قرأ التحذيرات اللي عليها طيب
+
+421
+00:38:27,600 --> 00:38:33,020
+كيف يأتي السام يعني و بغسك يديه ممكن طبعا يعني؟ هو
+
+422
+00:38:33,020 --> 00:38:38,550
+ما بيأثرش في التغسيلفي التغسيل بأثرش لما يتناول من
+
+423
+00:38:38,550 --> 00:38:42,190
+الفم و يمتص جوا الجسم يعني مابتصيرش نسبة
+
+424
+00:38:42,190 --> 00:38:46,030
+absorption كبيرة اللى يدخل على الجسم بالذات اللى
+
+425
+00:38:46,030 --> 00:38:50,510
+هو بنسبة جليلة لكن لما بيتاخد كمشروب كلها النسبة
+
+426
+00:38:50,510 --> 00:38:55,430
+الجليلة بتيجي بتدخل الجسم طبعا أفضل كتير لو كنا
+
+427
+00:38:55,430 --> 00:39:01,010
+كمان بنغسل بإيثانول ناقي اللى مايصيرشنسبة ال
+
+428
+00:39:01,010 --> 00:39:04,270
+absorption الخفيفة لكن الواقع اللي موجود ان ال
+
+429
+00:39:04,270 --> 00:39:10,730
+ethanol الطبي بالذات ال ethanol المختبرة و عشان
+
+430
+00:39:10,730 --> 00:39:15,550
+هيك لما مرات بيجيبوا ethanol معين لصناعة الأدويات
+
+431
+00:39:16,370 --> 00:39:20,230
+بيكتبوا ان هذا إيثانول بنفع لصناعة الأدوية بيكون
+
+432
+00:39:20,230 --> 00:39:24,630
+مش فيه سموم ممكن يدوبوا فيه أدوية والموضوع خلاف في
+
+433
+00:39:24,630 --> 00:39:28,350
+موضوع انه يجوز استعماله او لا وقدر الإمكان الإنسان
+
+434
+00:39:28,350 --> 00:39:33,330
+لازم يتجنب الدواء اللي مدوب بإيثانول ما لم يكن
+
+435
+00:39:33,330 --> 00:39:39,130
+هناك يعني ضرورة يعني شديدة جدا و البدائل كتيرة في
+
+436
+00:39:39,130 --> 00:39:41,550
+كل الأحوال واضح الفكرة؟
+
+437
+00:39:49,990 --> 00:39:54,530
+الان في موضوع الـ hydrogen bonding قولنا بيخلي
+
+438
+00:39:54,530 --> 00:39:58,250
+نقاط الغليان مرتفعة يعني لو انا بدأ اطلع على
+
+439
+00:39:58,250 --> 00:40:04,330
+الميثانول 65 زادت كربونا الإيثانول بيصير 78
+
+440
+00:40:04,330 --> 00:40:10,030
+البروبانول 97 طبعا هذا كلام منطقي كل ما بتكبر
+
+441
+00:40:10,030 --> 00:40:14,970
+السلسلة شو بيصيرها نقطة الغليان؟بتزيد الان لو
+
+442
+00:40:14,970 --> 00:40:20,210
+اجينا نقارن الموضوع بذائبية هذه المراكبات في الميه
+
+443
+00:40:20,210 --> 00:40:24,690
+هذه المراكبات تمتاز انها مكونا من جزئين الجزء
+
+444
+00:40:24,690 --> 00:40:29,610
+الاول ال O H خلينا نعلمها بالاحمر في كل المراكبات
+
+445
+00:40:29,610 --> 00:40:36,030
+هذا جزء ال O H جزء ايش بنقول عنه احنا polar الان
+
+446
+00:40:36,030 --> 00:40:37,650
+الجزء التاني
+
+447
+00:40:47,350 --> 00:40:52,590
+السلسلة طولت فانجزوا اللي بيزيد قاعد ال non polar
+
+448
+00:40:56,610 --> 00:41:02,210
+ربما نستطيع ان نقول ان هذا الجزء polar يعني الجزء
+
+449
+00:41:02,210 --> 00:41:06,450
+ال polar فيه متغلب لكن لما تكبر السلسلة كتير الجزء
+
+450
+00:41:06,450 --> 00:41:12,330
+بالمجمل شو بنعمله؟ non polar بناء على ذلك الميه ال
+
+451
+00:41:12,330 --> 00:41:19,850
+H2O polar رجاء نقوله polar مش بولر مش بنانا،
+
+452
+00:41:19,850 --> 00:41:22,930
+pencil اه polar
+
+453
+00:41:25,090 --> 00:41:31,840
+لاحظوا القاعدة ايش بتقول Likedissolves like الان
+
+454
+00:41:31,840 --> 00:41:36,080
+هذا اعتبرنا polar بدوب في الميه هذا زيه هذا زيه
+
+455
+00:41:36,080 --> 00:41:41,100
+هذا اعتبرنا ايش non polar بدوب في الميه لأ و بناء
+
+456
+00:41:41,100 --> 00:41:45,280
+على ذلك بنصير قادرين نتخيل ليش ال methanol و ال
+
+457
+00:41:45,280 --> 00:41:48,460
+ethanol و ال probanol اللي هي الكحولات الصغيرة
+
+458
+00:41:48,460 --> 00:41:52,900
+بتدوب في الميه هذه الكحولات اللي في أول السلسلة
+
+459
+00:41:52,900 --> 00:41:58,820
+بنسميها احنا ايش lower alcohol يعني الكحولات الاش
+
+460
+00:41:59,790 --> 00:42:05,010
+لصغيرة و هذه الكحولات اللى تحت شو بنسميها higher
+
+461
+00:42:05,010 --> 00:42:09,750
+alcohols الان مين اللى بيدوبوا في الميه ال lower
+
+462
+00:42:09,750 --> 00:42:13,930
+alcohols ولا ال higher alcohols ال lower alcohols
+
+463
+00:42:13,930 --> 00:42:18,330
+are water soluble because they are considered to
+
+464
+00:42:18,330 --> 00:42:25,460
+be polar however higher alcohols arenon-polar and
+
+465
+00:42:25,460 --> 00:42:30,540
+so they are water insoluble الان بيستعملوا بدل
+
+466
+00:42:30,540 --> 00:42:33,520
+soluble و insoluble كلمة تانية عارفين شو بيسموها
+
+467
+00:42:33,520 --> 00:42:39,120
+missable missable لما نحط سائلين مع بعض و ينخلطوا
+
+468
+00:42:39,120 --> 00:42:44,140
+مع بعض بنستعملها بين السوائلفلما نقول completely
+
+469
+00:42:44,140 --> 00:42:49,780
+miscible يعني زي سائلين نحطهم في بعض و يخلطوا 100%
+
+470
+00:42:49,780 --> 00:42:54,220
+مثلا لو عمنا حطينا الاسيتون مع الميه الاسيتون
+
+471
+00:42:54,220 --> 00:42:57,340
+بيدوب في الميه الاثانول مع الميه الميثانول مع
+
+472
+00:42:57,340 --> 00:43:02,190
+الميه they are miscible لكن لو حطينا ال oilمع
+
+473
+00:43:02,190 --> 00:43:08,190
+الميّه بيكونوا immiscible أو non miscible يعني ما
+
+474
+00:43:08,190 --> 00:43:11,850
+بيدوبوش في بعض ف miscible تستعمل التعبير عن
+
+475
+00:43:11,850 --> 00:43:16,410
+السوائل اللي بتخلق مع بعضها البعض واضح؟ زي
+
+476
+00:43:16,410 --> 00:43:22,650
+soluble, miscibleالـ Hydrogen Bonding حكيناه
+
+477
+00:43:22,650 --> 00:43:25,970
+ووضحناه الآن ال acidity of alcohols الحقيقة موضوع
+
+478
+00:43:25,970 --> 00:43:30,630
+كبير يعني ربما يحتاج محاضرة كاملة بنبدأ فيه المرة
+
+479
+00:43:30,630 --> 00:43:35,090
+القادمة حمضية الكحولات إذا كان بإمكانك تراجعوا
+
+480
+00:43:35,090 --> 00:43:39,530
+مفهوم الحمضية مما تعلمته سابقا بيكون جيد
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..9d2fb105496c2e5f407052827cf5060045d9898c
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_postprocess.srt
@@ -0,0 +1,2132 @@
+1
+00:00:19,470 --> 00:00:24,730
+بسم الله الرحمن الرحيم بدأنا من محاضرة او محاضرتين
+
+2
+00:00:24,730 --> 00:00:28,470
+في موضوع ال الديهيدس والكيتونز اتعرفنا عليهم ليش
+
+3
+00:00:28,470 --> 00:00:34,430
+اتصنفوا مع بعض تسمية ال الديهيدس والكيتونز طرق
+
+4
+00:00:34,430 --> 00:00:38,690
+صناعية لتحضير اشهر ال الديهيدس والكيتونز كان اخر
+
+5
+00:00:38,690 --> 00:00:44,270
+شيء اتكلمنا عنه الان في المختبر الطرق العامة
+
+6
+00:00:44,270 --> 00:00:49,420
+لتحضير ال الديهيدس والكيتونزإذا بنستعرضها مع بعض
+
+7
+00:00:49,420 --> 00:00:53,560
+بنلاحظ أن هذه الأشياء مرت علينا الحقيقة يعني
+
+8
+00:00:53,560 --> 00:00:58,080
+الطريقة الأولى لتحضير ال aldehydes و ال ketones من
+
+9
+00:00:58,080 --> 00:01:03,300
+أجسدة الكحولات لما أخدنا ال alcohols قلنا أن ال
+
+10
+00:01:03,300 --> 00:01:06,880
+alcohols they are either primary, secondary or
+
+11
+00:01:06,880 --> 00:01:13,120
+tertiary وقلنا أن ال primaryبصيروا باستعمال ال BCC
+
+12
+00:01:13,120 --> 00:01:16,960
+الديهيدز و ممكن يمدوا اكتر لو كان العامل مؤاكسد
+
+13
+00:01:16,960 --> 00:01:20,660
+اقوى بصيروا acids هذا مش الموضوع هنا ال secondary
+
+14
+00:01:20,660 --> 00:01:26,500
+alcohol باستعمال كيامانو 4 او كيتو كروميون 2
+
+15
+00:01:27,340 --> 00:01:33,400
+برمجانات البوتاسيوم كيتو كروميوم 207 بوتاسيوم داي
+
+16
+00:01:33,400 --> 00:01:37,940
+كروميت أو كروميك أكسيد بيصيروا كيتون فهذا أكسد
+
+17
+00:01:37,940 --> 00:01:42,720
+بالالكوهولز هي طريقة في انها لتحضير ال الديهايد
+
+18
+00:01:42,720 --> 00:01:45,520
+والكيتون من ال primer بناخد ال الديهايد ومن
+
+19
+00:01:45,520 --> 00:01:50,730
+السكندر بناخدالكيتون هذه طريقة مرت علينا سابقا
+
+20
+00:01:50,730 --> 00:01:58,450
+الاروماتيك كيتون أخدناهم كنا انحضر الاسيتوفينون
+
+21
+00:01:58,450 --> 00:02:06,640
+مثلا من استعمال ال acid halidesR-C-O-C-L هذي C-O
+
+22
+00:02:06,640 --> 00:02:10,700
+معناها C double bond و C-L في وجود ألومنيوم
+
+23
+00:02:10,700 --> 00:02:14,400
+الكلورايد الألومنيوم الكلورايد بيسحب الكلور و
+
+24
+00:02:14,400 --> 00:02:18,280
+بيعمل عندنا الايون الموجب و بيصير Electrophilic
+
+25
+00:02:18,280 --> 00:02:22,920
+Substitution اللي سمناه Friedel Crafts Acylation
+
+26
+00:02:22,920 --> 00:02:26,700
+واضح سمناه Friedel Crafts Acylation أخدنا Friedel
+
+27
+00:02:26,700 --> 00:02:30,720
+Crafts Alkylation و Acylation في شبطر الاروماتيك
+
+28
+00:02:31,490 --> 00:02:38,470
+from alkynes اخدنا احنا ان ال alkynes بيضيفوا مية
+
+29
+00:02:38,470 --> 00:02:42,090
+المية اللى بيضيفوها ممكن تكون حسب قاعدة
+
+30
+00:02:42,090 --> 00:02:46,390
+Markovnikov يضيف HOO يصير اندي double bond او Anti
+
+31
+00:02:46,390 --> 00:02:51,070
+Markovnikov HOH و في كل الأحوال لما يصير اندي in
+
+32
+00:02:51,070 --> 00:02:55,810
+all يعني هذا ال alkyne لو ضفنا عليه HOOH بدو يصير
+
+33
+00:02:55,810 --> 00:03:03,290
+double bondInol أخدنا أن Inol يعمل توتوميريزم
+
+34
+00:03:03,290 --> 00:03:08,550
+لكيتون أو لالديهيد سمناها keto inol توتوميريزم
+
+35
+00:03:08,550 --> 00:03:12,050
+يعني بهذا المثال لما نضيف الميه في وجود الحامض
+
+36
+00:03:12,050 --> 00:03:17,090
+فالإضافة بمرحلتها الأولى Markov-Nikov addition لما
+
+37
+00:03:17,090 --> 00:03:21,850
+نعمل التوتوميريزم ال COH بتصير C double bond O
+
+38
+00:03:21,850 --> 00:03:25,830
+يعني هذا بنرجع في الفصل التالت هذا بنرجع في الفصل
+
+39
+00:03:25,830 --> 00:03:30,800
+الرابع هذا بنرجع في الفصلالسابق كل هذه طرق تحضير
+
+40
+00:03:30,800 --> 00:03:36,580
+الالديهيد والكيتون مرت معناه وهذه الميزة الحقيقة
+
+41
+00:03:36,580 --> 00:03:41,540
+موجودة في ال organ ال chemistry انه انا في اندي شي
+
+42
+00:03:41,540 --> 00:03:45,300
+اسمه functional group interconvergent يعني اتحول
+
+43
+00:03:45,300 --> 00:03:51,180
+من شغلة لشغلة من كحول لالديهيد من كحول الى كيتون
+
+44
+00:03:51,180 --> 00:03:57,130
+من الكاين الى كيتونالان طالما صار عندى مسميين
+
+45
+00:03:57,130 --> 00:04:01,670
+طالما صار عندى مسميين اذا الشغل هتمر عندى مرتين
+
+46
+00:04:01,670 --> 00:04:04,150
+يعني لما انا بقول ان انا عندى كحول بده يصير
+
+47
+00:04:04,150 --> 00:04:07,530
+aldehyde او كيتون هتلاقوا انحنا نذكرها لما بنحكي
+
+48
+00:04:07,530 --> 00:04:10,990
+عن ال alcohol كتفاعل و نذكرها لما بنحكي عن ال
+
+49
+00:04:10,990 --> 00:04:15,290
+aldehydes و ال ketones كطريقة للتحضير بعد شوية
+
+50
+00:04:15,290 --> 00:04:18,690
+هنيجي على ال aldehydes و ال ketones طالما هذه
+
+51
+00:04:18,690 --> 00:04:25,320
+العملية أكسدة طب لو رجعنا فيها رجوعهتصير تفاعل لل
+
+52
+00:04:25,320 --> 00:04:28,060
+الديهيد والكيتون هلاحظ ان ال reduction of
+
+53
+00:04:28,060 --> 00:04:31,700
+aldehydes and ketones produces ايش؟ alcohol
+
+54
+00:04:31,700 --> 00:04:36,960
+فالعملية عملية متعاكسة وعشان كده الكلام بنشوفه
+
+55
+00:04:36,960 --> 00:04:41,820
+باكثر من مكان alcohol صار الديهيد او كيتون بالاكسة
+
+56
+00:04:41,820 --> 00:04:48,000
+ده الآن طب الديهيد او كيتونبالاختصار هيرجع ايش؟
+
+57
+00:04:48,000 --> 00:04:53,740
+هيرجع لالكول وسبق احنا انه وضحنا معنى الأكسادة ان
+
+58
+00:04:53,740 --> 00:05:00,020
+هي في النهاية اما انها زيادة في المحتوى الاكسوجيني
+
+59
+00:05:00,020 --> 00:05:05,940
+او نقص في محتوى الهيدروجينيالان هذه ال aldehydes و
+
+60
+00:05:05,940 --> 00:05:10,920
+ال ketones خلينا نقول في النهاية هي و كل الكيميا
+
+61
+00:05:10,920 --> 00:05:15,680
+لازم نفهمها من منطق التطبيق العملي يعني هي بتبدأ
+
+62
+00:05:15,680 --> 00:05:19,680
+معناه ربوز لكن في النهاية بواقع الحياة بتنتهي انها
+
+63
+00:05:19,680 --> 00:05:25,170
+مركباتالها وجود في الحياة العملية، الها تطبيق على
+
+64
+00:05:25,170 --> 00:05:28,790
+سبيل المثال ال Benzaldehyde هذا Aldehyde
+
+65
+00:05:28,790 --> 00:05:33,670
+Benzaldehyde هذا هو عبارة عن ال oil of almonds هو
+
+66
+00:05:33,670 --> 00:05:39,600
+زيت اللوزواضح؟ في زيت مشهور اسمه زيت اللوز لو
+
+67
+00:05:39,600 --> 00:05:43,740
+أسرنا اللوز بيطلع منه زيت اللي هو ال benz aldehyde
+
+68
+00:05:43,740 --> 00:05:49,140
+هذا ال aldehyde اللي شايفينه C double bond OH مع
+
+69
+00:05:49,140 --> 00:05:54,000
+حلقة بنزين و double bond هذا مركب كامل هذا اسمه
+
+70
+00:05:54,000 --> 00:05:58,880
+cinnamaldehyde cinnamaldehyde جاية من ال cinnamon
+
+71
+00:05:58,880 --> 00:06:05,880
+cinnamon يعني جرفةواضح؟ فهو المركب الأساسي اللي
+
+72
+00:06:05,880 --> 00:06:10,360
+بيعطي الجرفة الريحة تبعتها لأن الجرفة اسمها
+
+73
+00:06:10,360 --> 00:06:16,560
+cinnamon هو سموه إيش؟cinnamaldehyde مثلا بالالماني
+
+74
+00:06:16,560 --> 00:06:22,480
+الجرفة اسمها zimt فبيسموه zimt aldehyde واضح zimt
+
+75
+00:06:22,480 --> 00:06:27,300
+aldehyde هنا cinnamon cinnamaldehyde واضح فهذه
+
+76
+00:06:27,300 --> 00:06:31,620
+الجرفة اللي احنا بنتناولها في النهاية هي aldehyde
+
+77
+00:06:31,620 --> 00:06:36,180
+مر علينا سابقا ان الفانيلة هي عبارة عن aromatic
+
+78
+00:06:36,180 --> 00:06:40,600
+aldehyde عليه مجموعة هيدروكسي وميثوكسي الفانيلين
+
+79
+00:06:41,300 --> 00:06:47,120
+الان كتير ناس بيحبوا زيت النعناع sperminate oil
+
+80
+00:06:47,120 --> 00:06:51,220
+اللى بدخل فى مشتقات كتيرة و لعلاج الزور هذا عبارة
+
+81
+00:06:51,220 --> 00:06:54,680
+عن كيتون هى فيه ال C double bond O اللى بنسميه
+
+82
+00:06:54,680 --> 00:06:59,960
+carbonالمركب الكيميائي carbon لكن هذا ال carbon هو
+
+83
+00:06:59,960 --> 00:07:05,500
+ال sperm in it oil هو زيت النعمة واضح هذا المركب
+
+84
+00:07:05,500 --> 00:07:08,960
+لاحظوا بتلاحظوه مركب كبير لكن انا بهمن المجموعة
+
+85
+00:07:08,960 --> 00:07:12,280
+الوظيفية في نهاية المجموعة الوظيفية ايش فيه C
+
+86
+00:07:12,280 --> 00:07:17,240
+double bond O كيتون finally كيتون هذا ال camphor
+
+87
+00:07:17,240 --> 00:07:21,720
+الكفور واضح اللي بيستعملوه لعلاج الرجلين و ما إلى
+
+88
+00:07:21,720 --> 00:07:28,840
+ذلك الآن مش ضايل عندنا غير مينغير البحتري عاد
+
+89
+00:07:28,840 --> 00:07:34,560
+الربيع الى الدنيا بموقبه فزينت واكتست بالسندس
+
+90
+00:07:34,560 --> 00:07:38,580
+الشجر اه الياسمين الياسمين خلال أسبوعين اللي عندهم
+
+91
+00:07:38,580 --> 00:07:44,570
+ياسمينة هيلاحظوا كل الياسمينة إيش تصيربيضة من إيش؟
+
+92
+00:07:44,570 --> 00:07:50,590
+أه هي الياسمون كيتو واضح؟ ملاحظين مركب معين هذا
+
+93
+00:07:50,590 --> 00:07:56,910
+اللي هو الياسمون من ال oil of ياسمين من زيت
+
+94
+00:07:56,910 --> 00:08:01,190
+الياسمين بنطول هذا المركب الأساسي اللي بيعطيها
+
+95
+00:08:01,190 --> 00:08:04,790
+الريحة الكويسة سواء عملنا منه أطور أو الناس حتى
+
+96
+00:08:04,790 --> 00:08:11,500
+بيشموها و هي على الشجر ريحة جيدةفهذه المراكبات
+
+97
+00:08:11,500 --> 00:08:16,860
+الحقيقة يعني إلها مجال كبير في التطبيق طبعا أكيد
+
+98
+00:08:16,860 --> 00:08:20,060
+إلها مجالات في أشياء كتيرة غير هيك في أدوية في
+
+99
+00:08:20,060 --> 00:08:24,280
+الصناعة ولذلك إحنا بندرسها بعنق و بنتعرف عليها
+
+100
+00:08:24,280 --> 00:08:31,560
+الآن لو بدنا نيجي بعد هيك لتفاعلات ال aldehydes و
+
+101
+00:08:31,560 --> 00:08:38,080
+ال ketones قلنا بشكل عام الأمر مختصر فيهكلمة واحدة
+
+102
+00:08:38,080 --> 00:08:43,900
+اللي هي addition واضح طبعا لو اجينا بدنا ندقق في
+
+103
+00:08:43,900 --> 00:08:48,540
+كلمة ال addition in eucleophilic addition بمعنى
+
+104
+00:08:48,540 --> 00:08:54,820
+المهاجم لازم يكون ايش؟اليوكليوفايل ليش المهاجم
+
+105
+00:08:54,820 --> 00:08:59,660
+لازم يكون اليوكليوفايل لأن الالدهايد والكيتون فيهم
+
+106
+00:08:59,660 --> 00:09:03,060
+السيضة بالبوند او اللي موجودة لو اتطلعنا علي اي
+
+107
+00:09:03,060 --> 00:09:07,040
+مكان ارسمها بشكل اوضح السيضة بالبوند او لو اتطلع
+
+108
+00:09:07,040 --> 00:09:10,420
+السلبية هذا الطرف partially positive هذا partially
+
+109
+00:09:10,420 --> 00:09:16,870
+negative الان اللي بدو يهاجم عادةاليوكليوفايل واضح
+
+110
+00:09:16,870 --> 00:09:21,210
+اللي بيهاجم عادة نيوكليوفايل لما يهاجم هنا زوج
+
+111
+00:09:21,210 --> 00:09:25,430
+الإلكترونات هذا بتتحرك بيصف النتيجة ان هي carbon
+
+112
+00:09:25,430 --> 00:09:33,470
+OH نيوكليوفايل الان في عند اصلا مجموعتين تانين هنا
+
+113
+00:09:33,470 --> 00:09:37,350
+مش رسموهم دولة مافيش عليهم أي تغيير
+
+114
+00:09:38,710 --> 00:09:42,830
+الخلاصة أن التفاعل الأساسي لـ aldehydes و لـ
+
+115
+00:09:42,830 --> 00:09:48,430
+ketones كان هناك double bond و أصبحت تنتين single
+
+116
+00:09:48,430 --> 00:09:53,550
+bond واحدة OH واحدة نيوكليوفايل بكل الأحوال هنا
+
+117
+00:09:53,550 --> 00:09:57,690
+عدد الروابط أربعة و هنا عدد الروابط أربعة فال
+
+118
+00:09:57,690 --> 00:10:04,000
+double bond O تصبحوبصير عنده رابطة جديدة مع ال
+
+119
+00:10:04,000 --> 00:10:09,580
+file واضح الفكرة هذا هو التفاعل اللي هيظل يتكرر
+
+120
+00:10:09,580 --> 00:10:17,260
+بناء على ذلك بصير الان كل هذه المحاضرةهتحكي شغلة
+
+121
+00:10:17,260 --> 00:10:21,260
+واحدة بسيطة اللي بيفهمها بيقدر إذا مستعجل يروح
+
+122
+00:10:21,260 --> 00:10:24,640
+يمشي إنه إيش أنواع الـ nucleophile اللي بتهاجم
+
+123
+00:10:24,640 --> 00:10:28,140
+أعطونا أمثلة بنقول نمروا واحد الميّه، نمروا اتنين
+
+124
+00:10:28,140 --> 00:10:31,260
+الكحول، نمروا تلاتة الـCr، نمروا أربعة الـH-,
+
+125
+00:10:31,260 --> 00:10:36,000
+نمروا خمسة كذا، نمروا ستة كذا فبكل المحاضرة هذه
+
+126
+00:10:36,000 --> 00:10:40,880
+فقط احنا بدنا نحتفظ بهذا ال frame إن هدول
+
+127
+00:10:40,880 --> 00:10:44,200
+المجموعتين في الأساس ماتغيروش الـC double bond O
+
+128
+00:10:44,200 --> 00:10:51,110
+صارت OHانغيّر هذه المجموعة واضحة الفكرة؟ بمعنى لو
+
+129
+00:10:51,110 --> 00:10:55,370
+انا الآن بقولكوا ان النيوكليوفايل كان ميّه ايش
+
+130
+00:10:55,370 --> 00:11:01,110
+هنحط هنا؟ OH بيصير عائلة اسمها الهيدريت اللي فيها
+
+131
+00:11:01,110 --> 00:11:04,010
+كاربون حاملة انت نواتش بحكي بالتفصيل ماتستعجلوش
+
+132
+00:11:04,010 --> 00:11:11,350
+الآن طب لو ضفنا كحول؟ OR بيصير عائلة جديدة اسمها
+
+133
+00:11:11,350 --> 00:11:15,570
+سيانهيدريل شوف كيف البساطة طب لو ضفنا CM؟
+
+134
+00:11:18,510 --> 00:11:26,090
+لحظة لو سمحتوا لو ضفنا OR بيصير عندنا عائلة اسمها
+
+135
+00:11:26,090 --> 00:11:29,570
+hemacetal انا قلت cyanohedrin hemacetal طيب لو
+
+136
+00:11:29,570 --> 00:11:37,070
+ضفنا CN cyanohedrin بيسموها لو ضفنا H minus هذه
+
+137
+00:11:37,070 --> 00:11:46,110
+عملية الاختزال H برجعلك كحول واضح؟ لو ضفنا Amin
+
+138
+00:11:46,860 --> 00:11:53,400
+أمونيا انا H2 متعودين انتوا لنيوترا ليوكليوفايل شو
+
+139
+00:11:53,400 --> 00:12:01,380
+هيصير هيفقد H و هكذا فكل الأمثلة اللي هنحكيها
+
+140
+00:12:01,380 --> 00:12:05,020
+هتكون ماخدة هذا الإطار العام كل الأمثلة اللي
+
+141
+00:12:05,020 --> 00:12:08,700
+هنحكيها هتاخد هذا الإطار العام البسيط
+
+142
+00:12:11,390 --> 00:12:18,850
+بفيد شغلة أن هذا التفاعل بشكل عام بتم له catalysis
+
+143
+00:12:18,850 --> 00:12:23,970
+يعني تسريع بإضافة H plus عشان هيك في معظم الحالات
+
+144
+00:12:23,970 --> 00:12:29,910
+هتلاحظوا على سهم التفاعل موجود عنده في وجود إيشأتش
+
+145
+00:12:29,910 --> 00:12:37,090
+بلس وظيفتها أن تعمل تسريع للتفاعل لاحظوا لو أنا
+
+146
+00:12:37,090 --> 00:12:40,710
+كان عندي الديهيد او كيتون وضفت عليه أتش بلس الأتش
+
+147
+00:12:40,710 --> 00:12:46,140
+بلس وين هتروح على الموجة ولا على الأكسجين السالبع
+
+148
+00:12:46,140 --> 00:12:51,580
+الأكسجل موجب على سالب هتصير بهذا الشكل و لو حركنا
+
+149
+00:12:51,580 --> 00:12:54,860
+زوج الألكترونات تعملنا resonance هلاحظ أنه أنا
+
+150
+00:12:54,860 --> 00:12:59,720
+بصير عند الكاربون موجبة full positive charge الآن
+
+151
+00:12:59,720 --> 00:13:03,880
+قبل شوية لما رسمنا احنا كنا نقول هنا إيش شحنة إيش
+
+152
+00:13:03,880 --> 00:13:11,060
+مالها partial charge ال acidلما اجى اضاف ال H plus
+
+153
+00:13:11,060 --> 00:13:16,060
+هنا خلى هذا ال carbon موجب كامل الان ال
+
+154
+00:13:16,060 --> 00:13:22,200
+nucleophile انه افضل له اهاجم على موجب جزء ولا على
+
+155
+00:13:22,200 --> 00:13:26,900
+موجب كامل اهاجم على موجب كامل التجادب ايش بيكون
+
+156
+00:13:26,900 --> 00:13:31,320
+اقوى والتفاعل اسرع هاي بالظبط اللي بيعملوا ال acid
+
+157
+00:13:31,320 --> 00:13:37,720
+الان الناتج النهائي مافيش فيه خلافالناتج النهائي
+
+158
+00:13:37,720 --> 00:13:42,280
+هو نفس الناتج لكن دائما لما بتقرأوا التفاعل
+
+159
+00:13:42,280 --> 00:13:45,840
+هتلاحظوا انه على السهم في عندكم ايش اتش بلس اتش
+
+160
+00:13:45,840 --> 00:13:50,520
+بلس هذه الاتش بلس عبارة عن catalyst بتسرع ايش
+
+161
+00:13:50,520 --> 00:13:57,040
+التفاعل بالطريقة اللي حكيناها الان لو بدأنا ناخد
+
+162
+00:13:57,040 --> 00:14:01,220
+امثلة هاي هذه ال carbon في ال aldehyde موجبة اجت
+
+163
+00:14:01,220 --> 00:14:07,400
+الميه تهاجمأول الـ Eucalyptus ناخد الميّه الـ C
+
+164
+00:14:07,400 --> 00:14:13,760
+double bond O شو بتصير؟ OH نحطها بالأخضر و الميّه
+
+165
+00:14:13,760 --> 00:14:16,280
+هتضيف
+
+166
+00:14:17,080 --> 00:14:23,100
+OH في النهاية واضح هاي صار عندنا استيظة بال bond O
+
+167
+00:14:23,100 --> 00:14:27,960
+صارت OH والمية كان يوكليوفال بتضيف OH الان هنا
+
+168
+00:14:27,960 --> 00:14:34,580
+اتكون عندى مركب على نفس ذرة الكربون تبعته كام OH؟
+
+169
+00:14:34,580 --> 00:14:40,480
+تلتين هذه المركبات اللى على نفس ذرة الكربون فيها
+
+170
+00:14:40,480 --> 00:14:47,840
+تلتين OH بنعطيها اسم hydratesواضح فال hydrate لو
+
+171
+00:14:47,840 --> 00:14:52,800
+قلتلكوا ارسمولي شكل عام لل hydrate معنى ذلك تحطوا
+
+172
+00:14:52,800 --> 00:14:59,420
+carbon على نفس ال carbon تنتين O H's يمكن انتوا
+
+173
+00:14:59,420 --> 00:15:05,340
+سابقا مر عليكم انه يكون عندى في المركب تنتين O H's
+
+174
+00:15:05,340 --> 00:15:12,440
+على ذرات متجاورة زي هيك هذا المركب لما انا كنت
+
+175
+00:15:12,440 --> 00:15:20,400
+اسميهماذا كنت أسميه؟ داي أول داي أول و لأنه
+
+176
+00:15:20,400 --> 00:15:29,620
+كربونتين اثان داي أولواضح إيثان دايول على نمرة
+
+177
+00:15:29,620 --> 00:15:32,360
+واحد وعن نمرة اتنين ممكن تكتبوا one two إيثان
+
+178
+00:15:32,360 --> 00:15:37,980
+دايول تمام لكن لما يكونوا مجموعتين ال OH على نفس
+
+179
+00:15:37,980 --> 00:15:41,860
+ال carbon بنسمي عائلة جديدة هذه العائلة إيش
+
+180
+00:15:41,860 --> 00:15:47,620
+بنسميها hydrate الان المركب نفسه بنسميه نسبة ال
+
+181
+00:15:47,620 --> 00:15:51,140
+aldehyde الأصلي يعني هذا ال aldehyde الأصلي الآن
+
+182
+00:15:51,140 --> 00:15:55,620
+formaldehydeبتذكروا لما قلنا ال formaldehyde غاز
+
+183
+00:15:55,620 --> 00:16:00,400
+ملدوبه في الميه عملية اذابته في الميه هي ان الميه
+
+184
+00:16:00,400 --> 00:16:04,880
+تتفاعل عليه تعمل هان OH و تخلص سيضا من البند OH
+
+185
+00:16:04,880 --> 00:16:11,560
+هذا ال formaldehyde هيدريت طب لو كان acetaldehyde
+
+186
+00:16:11,560 --> 00:16:16,700
+واحدة من دول ال حزب ده تصير CH3 و هكذا الان لاحظوا
+
+187
+00:16:16,700 --> 00:16:22,380
+معي ان ال hydrate تفاعل تكوينه متفاعل ايش
+
+188
+00:16:23,760 --> 00:16:28,200
+Equilibrium reaction يعني لا يتم بشكل كامل بيكون
+
+189
+00:16:28,200 --> 00:16:34,020
+موجود ال الديهيد مع الميه مع الهيدرين بنسبة معينة
+
+190
+00:16:34,020 --> 00:16:40,200
+الان في حالة ال formaldehyde بيصل لإن هذا يتفاعل
+
+191
+00:16:40,200 --> 00:16:45,550
+بنسبة 37% عشان ايه بيصير لكم الفورمالينهو نفس الـ
+
+192
+00:16:45,550 --> 00:16:48,910
+Formal Dehydrate الـ Formalin اللي أخدنا بنستعمله
+
+193
+00:16:48,910 --> 00:16:53,390
+لحفظ الأنسجة وغيرها هو نفسه ال Formal Dehydrate
+
+194
+00:16:53,390 --> 00:16:56,730
+اللي هو ال Formal Dehydrate اتدوب في الميه عمل هذا
+
+195
+00:16:56,730 --> 00:17:01,790
+الشكل ال Formalin واضح الفكرة؟ وهذا التفاعل زي ما
+
+196
+00:17:01,790 --> 00:17:07,950
+قلنا عنه تفاعل عكسي الآن هل يترا في كل ال ال
+
+197
+00:17:07,950 --> 00:17:12,300
+Dehydrates و ال Ketones ممكن يتكون هيدريتز؟من
+
+198
+00:17:12,300 --> 00:17:17,260
+ناحية نظرية بالورقة والقلم اه يعني انا بقدر
+
+199
+00:17:17,260 --> 00:17:21,260
+اقولكوا اي aldehyde في الدنيا ارسموله hydrate
+
+200
+00:17:21,260 --> 00:17:26,620
+الاصل انكم تعرفوا تعملوا hydrate له مثلا لو اجاكم
+
+201
+00:17:26,620 --> 00:17:32,020
+في الامتحان ارسمولنا benz aldehyde hydrate المنطلق
+
+202
+00:17:32,020 --> 00:17:38,630
+تبعكم لازم تكونوا عارفين ال benz aldehydeهي ال
+
+203
+00:17:38,630 --> 00:17:44,210
+benz aldehyde C double bond O H الان احنا اتفقنا
+
+204
+00:17:44,210 --> 00:17:49,230
+لما بدى يعمل hydrate هدول المجمعتين مافيش فيهم
+
+205
+00:17:49,230 --> 00:17:56,450
+تغيير طب ها شو بدى يصير ال C double bond O بتصير O
+
+206
+00:17:56,450 --> 00:18:05,030
+H والمية بتضيف O H هذا بتصير benz aldehyde hydrate
+
+207
+00:18:05,890 --> 00:18:11,750
+و هكذا يعني بنفس هذه الطريقة ممكن نرسم لأي ألديهيد
+
+208
+00:18:11,750 --> 00:18:15,850
+أو كيتون هيدريت لو قولنا أسيتون هيدريت أسيتالديهيد
+
+209
+00:18:15,850 --> 00:18:21,210
+هيدريت لكن الحقيقة معظم الهيدريت بشكل عام they are
+
+210
+00:18:21,210 --> 00:18:26,930
+unstable يعني في حالة الإتزان اللي بيوجد بشكل أكبر
+
+211
+00:18:26,930 --> 00:18:33,280
+كتير جدا هو الألديهيدو لذلك هذا التفاعل بيصير نوعا
+
+212
+00:18:33,280 --> 00:18:37,200
+ما تفاعل نظري مش تفاعل عملي يعني بيكون هذا ال
+
+213
+00:18:37,200 --> 00:18:42,160
+الديهيد او ال ketone موجود بالنسبة 99.9% و هذا
+
+214
+00:18:42,160 --> 00:18:46,780
+موجود بالنسبة قليلة جدا و لذلك معظم ال الديهيد و
+
+215
+00:18:46,780 --> 00:18:50,820
+ال ketones بيكون ال position of equilibrium اتجاه
+
+216
+00:18:50,820 --> 00:18:54,580
+الاتزان فيها هل هو باتجاه ال hydrate و لا باتجاه
+
+217
+00:18:54,580 --> 00:18:56,040
+ال الديهيد او ال ketone
+
+218
+00:18:58,860 --> 00:19:04,840
+واضح الفكرة؟ لكن نظريا كل شيء له hydrate الان مثلا
+
+219
+00:19:04,840 --> 00:19:10,420
+هذا المركب تطلع عليه carbon حملة تين و H إذا هذا
+
+220
+00:19:10,420 --> 00:19:15,120
+hydrate ولا لأ؟ Hydrate طب الآن لو قلت لواحدة
+
+221
+00:19:15,120 --> 00:19:22,520
+فيكوا هذا ال hydrate من أي الديهيد جاي كيف
+
+222
+00:19:22,520 --> 00:19:28,900
+بدى تعمل؟ بدى تخلي الرابطتين اللي موجودات ال Hو ال
+
+223
+00:19:28,900 --> 00:19:34,800
+C اللي حاملة تلاتة كلور يعني CCLCLCL و تحط هنا
+
+224
+00:19:34,800 --> 00:19:41,420
+double bond O هذا مركب موازل ال acetaldehyde لكن
+
+225
+00:19:41,420 --> 00:19:46,160
+ابدلت تلت ذرات الهيدروجين فيه بكلور فبصير اسمه ايش
+
+226
+00:19:46,160 --> 00:19:53,340
+اكلورال اكلورال لما اعمل من ال اكلورال هيدريت
+
+227
+00:19:53,340 --> 00:20:01,450
+باضافة الميهبيصير ايش اسمه اكلورال هايدريت فانا ال
+
+228
+00:20:01,450 --> 00:20:05,770
+الديهايدي اللي عندي اكلورال لما اعمله اضافة ميه
+
+229
+00:20:05,770 --> 00:20:10,950
+بيصير اكلورال هايدريت واضح لما اعمله اضافة ميه
+
+230
+00:20:10,950 --> 00:20:15,530
+بيصير اكلورال هايدريت هذا ال اكلورال هايدريت مادة
+
+231
+00:20:15,530 --> 00:20:19,650
+تستعمل في التخدير و عادة في التخدير في الطب
+
+232
+00:20:19,650 --> 00:20:24,090
+البيطري يعني لما يعملوا عمليات جراحية للحيوانات
+
+233
+00:20:24,090 --> 00:20:28,860
+الكبيرة الضخمةبيعطوها chloral hydrate كمخدر فيلو
+
+234
+00:20:28,860 --> 00:20:36,660
+ما إلى ذلك واضح؟ فهذا بالنسبة لل hydrate الأن كتير
+
+235
+00:20:36,660 --> 00:20:40,160
+مرات بنيجي بنقول للطالب في الامتحان النهار or some
+
+236
+00:20:40,160 --> 00:20:44,420
+general structure of hydrate بشكل عام شو بده يحط
+
+237
+00:20:44,420 --> 00:20:53,080
+الليه؟ carbon حاملة تنتلؤ أدشز واضح؟طيب لو اتينا ل
+
+238
+00:20:53,080 --> 00:20:59,680
+ال alcohol كيف بتتفاعل برضه إضافة الآن على طول
+
+239
+00:20:59,680 --> 00:21:05,140
+السيباب البندقوس شو هتصير OH و ال nucleophile اللي
+
+240
+00:21:05,140 --> 00:21:12,520
+هيهاجم OR لاحظوا هنا صار عندى ذرة carbon بتحمل مش
+
+241
+00:21:12,520 --> 00:21:21,470
+تنتين OHOH و OR يعني كأن هذا المركب هو عبارة عن
+
+242
+00:21:21,470 --> 00:21:28,230
+كحول و إيثر بنفس الوقت كاربون بتحمل OH هذا ألكوهول
+
+243
+00:21:28,960 --> 00:21:36,180
+و carbon OR هذا ether واضح فهذا المركب كأنه كحول و
+
+244
+00:21:36,180 --> 00:21:40,680
+ether و هذه العملية إضافة ليش إضافة هذه العملية
+
+245
+00:21:40,680 --> 00:21:44,200
+لأن ال double bond صارت single bond هذه الإضافة
+
+246
+00:21:44,200 --> 00:21:47,900
+ببساطة ال double bond single bond إضافة خلصنا الآن
+
+247
+00:21:47,900 --> 00:21:53,240
+هذا اللي فيه ال carbon بتحمل OH و OR بنسميه
+
+248
+00:21:53,240 --> 00:22:00,690
+hemiacetalيعني إيش؟ نص أسيتال مش أسيتال كامل، الآن
+
+249
+00:22:00,690 --> 00:22:06,190
+لما أي شغل نقول هذا نص أسيتال حيصير التفكير عندكم
+
+250
+00:22:06,190 --> 00:22:12,030
+طب هو إيش الأسيتال؟ الكامل، إذا في بالدنيا نص
+
+251
+00:22:12,030 --> 00:22:17,430
+أسيتال، إذا أكيد في الدنيا في إيش؟ أسيتال كامل،
+
+252
+00:22:17,430 --> 00:22:21,750
+hemacetal نص أسيتال، طب وإيش الأسيتال الكامل؟
+
+253
+00:22:24,180 --> 00:22:32,080
+إتنين إيثر لو هذا المركب نفسه الـ hemacetal فعلناه
+
+254
+00:22:32,080 --> 00:22:37,480
+مع زيادة من الكحول فعلناه مع زيادة من الكحول الآن
+
+255
+00:22:37,480 --> 00:22:41,960
+مرة تانية بيجي الكحول في هذه الحالة بيعمل تفاعل
+
+256
+00:22:41,960 --> 00:22:46,800
+تاني بيهاجم على الكربون الموجبة وبيطرد الـ OH الآن
+
+257
+00:22:46,800 --> 00:22:51,180
+هذا التفاعل مجموعة داخلة مجموعة طالعة شو بنسمي
+
+258
+00:22:51,180 --> 00:22:51,920
+احنا substitution
+
+259
+00:22:55,450 --> 00:22:58,630
+substitution هذا التفاعل double bond صارت single
+
+260
+00:22:58,630 --> 00:23:04,590
+bond شو كنا مسمينه addition الان بدلنا ال OH ب OR
+
+261
+00:23:04,590 --> 00:23:11,090
+شو صار موجود عندك على الكربون تنتين
+
+262
+00:23:11,090 --> 00:23:18,370
+OR داي إيثر هذا الأسيتال الكامل واضح هذا هو
+
+263
+00:23:18,370 --> 00:23:25,730
+الأسيتال الكامل اللي هو كربون بتحملTentenor و
+
+264
+00:23:25,730 --> 00:23:31,770
+التفاعل لتكوين الاسيتال يتم من خلال الهيمياسيتال
+
+265
+00:23:31,770 --> 00:23:36,870
+مع مزيد من الكحول فالتفاعل في هذه الحالة
+
+266
+00:23:36,870 --> 00:23:41,850
+substitution لاحظوا انا الان كم عائلة جديدة اتعرفت
+
+267
+00:23:41,850 --> 00:23:47,490
+عليها خدوهم بالتدريج Carbon Carbon Carbon Carbon
+
+268
+00:23:47,490 --> 00:23:48,990
+حاملة Tentenor
+
+269
+00:23:51,050 --> 00:23:57,350
+أه carbon حاملة OH و OR همي أسيتال carbon حاملة OR
+
+270
+00:23:57,350 --> 00:24:06,530
+و OR أسيتال شفتم كيف بالمقارنة hydrate أسيتال وهذا
+
+271
+00:24:06,530 --> 00:24:12,720
+اللي بين بينهيمي أسيتال هيدريت وهذا أسيتال وهذا
+
+272
+00:24:12,720 --> 00:24:18,320
+هيمي أسيتال الآن لو أجينا نسألكم الهيدريت كيف
+
+273
+00:24:18,320 --> 00:24:25,440
+بيتكون من إضافة الماء على ال الديهيد أو الكيتون
+
+274
+00:24:25,440 --> 00:24:29,300
+لحظوا الكلمات اللي باستعملها لما نفجر نسأل هيدريت
+
+275
+00:24:29,300 --> 00:24:30,260
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+276
+00:24:30,260 --> 00:24:31,960
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+277
+00:24:31,960 --> 00:24:32,140
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+278
+00:24:32,140 --> 00:24:34,240
+هيدريت هيدريت هيدريت هيدريت هيدby addition
+
+279
+00:24:34,240 --> 00:24:40,000
+reaction الـ hemacetal is formed also by addition
+
+280
+00:24:40,000 --> 00:24:43,760
+reaction على ال الديهيد والكيتون ال acetal
+
+281
+00:24:43,760 --> 00:24:51,340
+substitution reaction على ال hemacetal واضح ال
+
+282
+00:24:51,340 --> 00:24:55,480
+acetal هو عبارة عن عملية إبدال ال OH اللي موجودة
+
+283
+00:24:55,480 --> 00:25:00,120
+في ال hemacetal واضح هذه التفاعلات والعائلات
+
+284
+00:25:00,120 --> 00:25:01,740
+الجديدة والمسميات
+
+285
+00:25:07,510 --> 00:25:14,790
+الان هذا الحقيقة تفاعل الاسيتال والهيمياسيتال
+
+286
+00:25:14,790 --> 00:25:22,070
+تفاعل مهم جدا ممكن ايضا طالما المكونات تبعته كحول
+
+287
+00:25:22,070 --> 00:25:27,670
+بيهاجم على ايش الديهايد او كيتون الان لو انا
+
+288
+00:25:27,670 --> 00:25:31,150
+اتخيلت هي الديهايد او كيتون كحول هاجم عليه شو
+
+289
+00:25:31,150 --> 00:25:36,710
+الناتج؟Hemiacetal طيب السؤال لو ال الديهايد و ال
+
+290
+00:25:36,710 --> 00:25:40,930
+alcohol بنفس الجزئ يعني تخيلنا هيك جزئ سلسلة على
+
+291
+00:25:40,930 --> 00:25:46,330
+أحد أطرافها الديهايد و على الطرف التاني OH و إجت
+
+292
+00:25:46,330 --> 00:25:52,170
+فاعل هذه هاجمتها و السيطة بالبندق شو صارت OH هذا
+
+293
+00:25:52,170 --> 00:25:56,370
+التفاعل بنسميه Intermolecular ولا Intramolecular
+
+294
+00:25:57,570 --> 00:26:00,950
+Intramolecular شو يعني Intramolecular تفاعل بين
+
+295
+00:26:00,950 --> 00:26:06,430
+جزئين مفصولين تماما هذا جزء و هذا جزء جاء الجزئين
+
+296
+00:26:06,430 --> 00:26:10,150
+المفصولين تماما يتفاعلوا مع بعض هذا Intermolecular
+
+297
+00:26:10,150 --> 00:26:15,510
+بين جزئين مفصولين الان لو هذا الجزء و هذا الجزء
+
+298
+00:26:15,510 --> 00:26:21,430
+ممسكين بنفس السلسلة زي هذا المثال لاحظوا هذه سلسلة
+
+299
+00:26:21,430 --> 00:26:28,570
+واضح على أحد أطرافهاالديهايد وعلى الطرف الثاني
+
+300
+00:26:28,570 --> 00:26:32,790
+كحول فالجزئين اللي بدهم يتفاعلوا موجودين بنفس
+
+301
+00:26:32,790 --> 00:26:36,830
+المركب مش بمركبين مختلفين في هذه الحالة إذا
+
+302
+00:26:36,830 --> 00:26:40,730
+الجزئين اللي بتفاعلوا بنفس المركب على طول التفاعل
+
+303
+00:26:40,730 --> 00:26:47,380
+إيش أنا بأوصفه Intramolecular reactionفالـ
+
+304
+00:26:47,380 --> 00:26:51,120
+Intramolecular معناه ذلك أن الجزئين اللي بتفعلوا
+
+305
+00:26:51,120 --> 00:26:55,860
+بنفس الجزئ لكن الـ Intermolecular لأ جزئين مفصلين
+
+306
+00:26:55,860 --> 00:27:00,780
+و بيجوا يتفعلوا مع بعض واضح؟ هذا الأمر موجود كتير
+
+307
+00:27:00,780 --> 00:27:05,620
+الآن خلّيت الكحول و الالدهايد بنفس الجزئ التفاعل
+
+308
+00:27:05,620 --> 00:27:10,540
+أكيد إضافة الكحول بده يهاجم هنا و هاد السيطة بالـ
+
+309
+00:27:10,540 --> 00:27:16,270
+Bond O شو بده تصيرOH احنا قلنا في كل الأحوال دائما
+
+310
+00:27:16,270 --> 00:27:20,310
+ال C double bond O بتصير OH يمكن في كل الأمثلة
+
+311
+00:27:20,310 --> 00:27:25,690
+السابقة رسمناها بالأخضر و ال nucleophile هاجم بهذا
+
+312
+00:27:25,690 --> 00:27:32,110
+الشكل الآن هذا المركب اللي متكون عنده أيضا
+
+313
+00:27:32,110 --> 00:27:37,370
+hemacetal ولا لأ؟ أكيد لأن high carbon حاملة OH
+
+314
+00:27:41,220 --> 00:27:45,560
+هذا Hemacetal لكن التفاعل بهذه الحالة
+
+315
+00:27:45,560 --> 00:27:52,000
+Intramolecular reaction الان هذا التفاعل جزء من
+
+316
+00:27:52,000 --> 00:27:58,390
+أهميته انه في ال biochemistryإذا عندكم فكرة خفيفة
+
+317
+00:27:58,390 --> 00:28:03,190
+أو هيمر عليكم لما بناخد السكريات ال sugars احنا
+
+318
+00:28:03,190 --> 00:28:08,150
+قولنا ال sugars they are polyhydroxy aldehydes او
+
+319
+00:28:08,150 --> 00:28:12,890
+كيتون هى عبارة عن الديهيد او كيتون مع مجموعات
+
+320
+00:28:12,890 --> 00:28:17,510
+اوقاتش كبيرة الديهيد لحاله بيعملش sugar ومجموعات
+
+321
+00:28:17,510 --> 00:28:21,490
+اوقاتش كتيرة لحالها بتعملش ايش sugar فال sugar
+
+322
+00:28:21,490 --> 00:28:26,130
+عبارة عن ايشموجود فيه يا الديهايد يا كيتون
+
+323
+00:28:26,130 --> 00:28:31,290
+ومجموعات OH's الآن طالما وجد فيه على جهة معينة
+
+324
+00:28:31,290 --> 00:28:34,950
+الديهايد او كيتون هي C double bond او نتخيل هيك وع
+
+325
+00:28:34,950 --> 00:28:40,980
+الجهة التانيةأو أتشز ممكن هذه ال أو أتشز تسكر على
+
+326
+00:28:40,980 --> 00:28:45,600
+ال الديهايد أو ال كيتون أكيد بتعمل في هذه الحالة
+
+327
+00:28:45,600 --> 00:28:49,520
+hemeacetal بس لما تسكر بدل ما ال sugar كان عامل
+
+328
+00:28:49,520 --> 00:28:54,480
+سلسلة بهذا الشكل ال chain بيصير إيش in the cyclic
+
+329
+00:28:54,480 --> 00:28:58,440
+form كل كمار عليكوا أن السكر بيكون في ال chain
+
+330
+00:28:58,440 --> 00:29:06,430
+formكسلسلة و بيكون بـ Cyclic Form كحلقة الآن عملية
+
+331
+00:29:06,430 --> 00:29:12,090
+إغلاق السكر هي عملية تفاعل Hemacetal Formation
+
+332
+00:29:12,090 --> 00:29:17,890
+Hemacetal Formation هاي السكر اللي مسكر الجلوكوز
+
+333
+00:29:17,890 --> 00:29:22,650
+هذا منظر الجلوكوز اللي مسكر لاحظوا هذه ال carbon
+
+334
+00:29:22,650 --> 00:29:32,570
+تحديدا اللي هنا هي فيها OHو OR اللى هو alcohol و
+
+335
+00:29:32,570 --> 00:29:36,910
+ether طب لو قولنا لأى حد اذكرنا كيف هذه كانت قبل
+
+336
+00:29:36,910 --> 00:29:43,250
+التفاعل قبل ما يسكر كانت هذه C double bond O وكانت
+
+337
+00:29:43,250 --> 00:29:52,240
+هذه OH وماكنش فيه رابطةكانت هذه C double bond O L
+
+338
+00:29:52,240 --> 00:29:57,780
+D I و هذه O H فهذه ال O H سكرت هنا و C double bond
+
+339
+00:29:57,780 --> 00:30:05,240
+O صارتOH بهذا الشكل فلو اجينا سألناكوا سؤال
+
+340
+00:30:05,240 --> 00:30:10,260
+وقلنالكم cyclic glucose انتبهوا معايا هاي ال
+
+341
+00:30:10,260 --> 00:30:14,480
+glucose اللي مسكرة تكونوا فاهمين العائلات كويسة
+
+342
+00:30:14,480 --> 00:30:20,420
+cyclic glucose is a hydrate يعني في تنتين OH على
+
+343
+00:30:20,420 --> 00:30:21,140
+الكربون
+
+344
+00:30:25,890 --> 00:30:30,950
+cyclic glucose is a hydrate no cyclic glucose is
+
+345
+00:30:30,950 --> 00:30:38,450
+an acetal في تنتين OR برضه false cyclic glucose is
+
+346
+00:30:38,450 --> 00:30:48,340
+a hemacetal في OH و OR واضحة الفكرةالان ممكن نسأل
+
+347
+00:30:48,340 --> 00:30:54,180
+السؤال بطريقة تانية Cyclic glucose is formed by a
+
+348
+00:30:54,180 --> 00:30:55,960
+substitution reaction
+
+349
+00:30:58,930 --> 00:31:03,610
+by an addition reaction شوف كيف اللي بيفهم شغلة
+
+350
+00:31:03,610 --> 00:31:07,770
+بيحس انه ممكن نسأل عن الشغلة بقالف طريق أنا مش
+
+351
+00:31:07,770 --> 00:31:10,610
+الفكرة ان اخوفكم من الأسئلة و الانتحانات بقدر ما
+
+352
+00:31:10,610 --> 00:31:16,130
+اني بركز المعلومة عندكم ان هذه فعلا كانت C double
+
+353
+00:31:16,130 --> 00:31:20,430
+bond O و هذه فعلا كانت OH هذا alcohol و هذا
+
+354
+00:31:20,430 --> 00:31:23,750
+aldehyde الآن ال alcohol و ال aldehyde بيتفاعلوا
+
+355
+00:31:23,750 --> 00:31:31,560
+تفاعل ايش اضافة بكونه hemiacetalواضح؟ الآن بعد ما
+
+356
+00:31:31,560 --> 00:31:37,160
+اتكون الـ hemacetal هذا وصار هنا في OR و OH ممكن
+
+357
+00:31:37,160 --> 00:31:44,040
+يصير تفاعل تاني تبدل في ال OH ل OR مع كحول تاني
+
+358
+00:31:44,040 --> 00:31:48,260
+خارجي يعني افترضوا ناس جابوا ميثانول وفعلوا مع هذا
+
+359
+00:31:48,260 --> 00:31:55,530
+شو هيعمل الميثانول؟هيشيل ال OH يخليها OR صار عندكم
+
+360
+00:31:55,530 --> 00:32:01,890
+OR OR أسيتال بس ب substitution reaction تاني واضح
+
+361
+00:32:01,890 --> 00:32:06,350
+انما ال cyclic glucose في نص الطريق هو عبارة عن
+
+362
+00:32:06,350 --> 00:32:11,500
+ايش؟Hemiacetal Cyclic Glucose is Hemiacetal ممكن
+
+363
+00:32:11,500 --> 00:32:15,920
+تحويله ل Acetal بالتفاعل مع الكحول أكيد لأن احنا
+
+364
+00:32:15,920 --> 00:32:20,820
+قلنا التفاعل ع مرحلتين إضافة ثم إبدال أنا لما وصلت
+
+365
+00:32:20,820 --> 00:32:24,900
+ل Hemacetal عملت الإضافة الآن إذا الإنسان بيجيب
+
+366
+00:32:24,900 --> 00:32:30,860
+كحول و حامض و بيسخنه ممكن يعمل إيش الإبدال و يحوله
+
+367
+00:32:30,860 --> 00:32:37,360
+إلى Acetal كاملهنا في عندى على هذه النقطة كمان
+
+368
+00:32:37,360 --> 00:32:46,320
+مثال جميل انه انا جبت ال Acetone كيتون مع Ethylene
+
+369
+00:32:46,320 --> 00:32:51,740
+Glycol او اللى سميناه Ethanediol هذا المركب كام OH
+
+370
+00:32:51,740 --> 00:32:58,200
+فيهTintin يعني كأنه هذا Dialcohol الان لما فعلنا
+
+371
+00:32:58,200 --> 00:33:03,200
+اعطانا هذا المركب المغلق يمكن واحدة تقول طب كيف تم
+
+372
+00:33:03,200 --> 00:33:08,600
+هذا التفاعل؟ بنقول بهدوء ممكن نفهم كيف تم الان
+
+373
+00:33:08,600 --> 00:33:13,540
+نتعامل مع هذا كيتون و مع هذا الكهول كيف الكهول
+
+374
+00:33:13,540 --> 00:33:17,700
+بتفاعل على الكيتون او على الديهايد بال addition
+
+375
+00:33:17,700 --> 00:33:24,310
+هذه بتيجي تضيف هنا و هذه بتصيرOH إذا لو قلنا شو
+
+376
+00:33:24,310 --> 00:33:32,770
+الناتج اللي في هذه الحالة بيصير C OH CH3 CH3 هذا
+
+377
+00:33:32,770 --> 00:33:37,590
+الجزء اللي كان أسيتون والجزء التاني هو عبارة عن O
+
+378
+00:33:37,590 --> 00:33:48,890
+CH2 CH2 OH هاي كحول اتفاعل مع كيتون ال C double
+
+379
+00:33:48,890 --> 00:33:54,500
+bond O صارتOH والكحول اتفاعل هنا الان الكحول نفسه
+
+380
+00:33:54,500 --> 00:34:00,220
+في داخله OH تاني يعني كأن الكحول كحولين في بعض في
+
+381
+00:34:00,220 --> 00:34:04,740
+مجموعتين OH هذا المركب اللي هنا carbon حاملة OH و
+
+382
+00:34:04,740 --> 00:34:10,660
+OR شو عبارة عن ايش Himacetal الان ممكن يعمل كمان
+
+383
+00:34:10,660 --> 00:34:16,680
+تفاعل ان هذه تهاجم هنا و تحل محل هذه ابدال
+
+384
+00:34:17,800 --> 00:34:21,920
+و انت بتطلع عندى هذا المركب لحظة هذا المركب carbon
+
+385
+00:34:21,920 --> 00:34:27,680
+حاملة OR و OR اذا هذا عبارة عن ايش
+
+386
+00:34:30,910 --> 00:34:36,990
+Hemiacetal لاحظوا هنا اعملت التفاعل على مرتين لكن
+
+387
+00:34:36,990 --> 00:34:42,970
+مش من كحولين مفصلين لأ الكحولين موجودين بإيش؟ بنفس
+
+388
+00:34:42,970 --> 00:34:47,330
+الجزء نفس الجزء فيه تن تن و اتش يعني كأنه الجزء زي
+
+389
+00:34:47,330 --> 00:34:53,410
+ما بيقولوا اليوم في الدعايات إيش؟ two in oneطالما
+
+390
+00:34:53,410 --> 00:34:58,470
+في اتنين OH اذا صار عبارة عن كحولين في نفس الجزء
+
+391
+00:34:58,470 --> 00:35:03,710
+طالما مجمعتين OH الكحول OH هذا في OH OH صار كحولين
+
+392
+00:35:03,710 --> 00:35:09,650
+اتفاعل في المرة الأولى بالاضافة و في المرة الثانية
+
+393
+00:35:09,650 --> 00:35:15,380
+بالابدالةشوفنا كيف ادول التفاعلين تموا addition
+
+394
+00:35:15,380 --> 00:35:19,640
+followed by substitution الان هذا المركب اتجه من
+
+395
+00:35:19,640 --> 00:35:23,360
+الاسيتون و من الاثيلين جليكول عشان يسموه اسيتون
+
+396
+00:35:23,360 --> 00:35:28,820
+اثيلين جليكول لاحظوا ايش استعمله اسيتال منطق
+
+397
+00:35:28,820 --> 00:35:32,480
+اسيتال لانه OR و OR اسيتال
+
+398
+00:35:42,600 --> 00:35:48,900
+الان من التفاعلات انه نستعمل نيكليوفايل مجموعة ال
+
+399
+00:35:48,900 --> 00:35:52,680
+CNI و بتذكروا احنا لما أخدنا ال CNI تقولنا بتتفاعل
+
+400
+00:35:52,680 --> 00:35:56,460
+من اي طرف من الكربون ولا من ال نيتروجين من الكربون
+
+401
+00:35:56,460 --> 00:36:01,200
+كل اللي مطلوب انه ال CN تهاجم هنا و الصيدة بال
+
+402
+00:36:01,200 --> 00:36:06,580
+bond O تصير OH الان صار عندى عائلة جديدة على
+
+403
+00:36:06,580 --> 00:36:13,040
+الكربون ايش المجمعتين اللي موجودين CNN و OHو OH
+
+404
+00:36:13,040 --> 00:36:20,700
+لاحظوا C و تلتين OH هيدريت OH و OR هيمي أسيتال OR
+
+405
+00:36:20,700 --> 00:36:27,340
+و OR أسيتال الان OH و CNN بسميها سيانو هيدرين
+
+406
+00:36:27,340 --> 00:36:37,760
+بسميها سيانو هيدرين واضح سيانو هيدرين الان
+
+407
+00:36:39,440 --> 00:36:43,880
+لو عملنا التفاعل مع الاسيتالديهيد هذا المركب شو
+
+408
+00:36:43,880 --> 00:36:51,320
+هسميه اسيتالديهيد سيانوهيدرين لو عملت التفاعل مع
+
+409
+00:36:51,320 --> 00:36:57,100
+الاسيتون هذا المركب ايش هسميه اسيتون هاي جزء
+
+410
+00:36:57,100 --> 00:37:05,520
+الاسيتون مش الاسيتون عبارة عن CH3CCH3 بدون ال
+
+411
+00:37:05,520 --> 00:37:10,950
+oxygen اسيتونCyanohedron لو عملتم مع الـ
+
+412
+00:37:10,950 --> 00:37:16,250
+Cyclohexanone هذي الـ C double bond O إيش هتصير؟
+
+413
+00:37:16,250 --> 00:37:21,650
+OH وهي الـ Cl شو هسميه؟ Cyclohexanone
+
+414
+00:37:21,650 --> 00:37:23,470
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+415
+00:37:23,470 --> 00:37:23,530
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+416
+00:37:23,530 --> 00:37:23,810
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+417
+00:37:23,810 --> 00:37:24,510
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+418
+00:37:24,510 --> 00:37:26,930
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+419
+00:37:26,930 --> 00:37:27,010
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+420
+00:37:27,010 --> 00:37:31,690
+Cyclohexanone
+
+421
+00:37:31,690 --> 00:37:37,790
+Cyclohexanone Cyclohexanone
+
+422
+00:37:40,220 --> 00:37:47,620
+الدهايد بنزالدهايد سيانو هيدرل يعني لو قلنا لأي
+
+423
+00:37:47,620 --> 00:37:53,440
+واحدة أرسمينا بنزالدهايد سيانو هيدرل في الامتحان
+
+424
+00:37:53,440 --> 00:37:58,360
+بدا تيجي تفكر تتخيل بسهولة ماتاخدش وقت منكوا
+
+425
+00:37:58,360 --> 00:38:05,530
+ببساطة هاي ال بنزالدهايد صح ولا لألازم في الأصل
+
+426
+00:38:05,530 --> 00:38:09,390
+تكون عارفة الـ Benzaldehyde مجرد ما نقولها سيانو
+
+427
+00:38:09,390 --> 00:38:17,490
+هيدرين الـ C بابل بوند O OH OHIJNQCN مش عملية صعبة
+
+428
+00:38:17,490 --> 00:38:23,090
+Benzaldehyde cyanohydrin واضح الفكرة؟ لاحظوا أنا
+
+429
+00:38:23,090 --> 00:38:27,650
+كاتب له common name نفس
+
+430
+00:38:27,650 --> 00:38:30,830
+الـ Benzaldehyde cyanohydrin له common name
+
+431
+00:38:30,830 --> 00:38:33,330
+Manbilonitride
+
+432
+00:38:34,290 --> 00:38:42,750
+mandilo mandel بالالماني يعني لوز انتوا بتذاكرين
+
+433
+00:38:42,750 --> 00:38:46,750
+قبل شوية لما أخدنا ال benzaldehyde قولنا oil of
+
+434
+00:38:46,750 --> 00:38:54,170
+almond اللوز بالانجليزي بالالماني mandel ومن هنا
+
+435
+00:38:54,170 --> 00:38:58,950
+استعمل mandilo nitral mandel من اللوز يعني كتير من
+
+436
+00:38:58,950 --> 00:39:04,150
+ال common name علاقة في إيشفي أصل المركب من أي
+
+437
+00:39:04,150 --> 00:39:08,130
+منطقة نباتية اشتهر ان هذا المركب انفصل
+
+438
+00:39:08,130 --> 00:39:12,990
+فالمنديلونيترال هو ال benzaldehyde cyanohydrin
+
+439
+00:39:12,990 --> 00:39:14,370
+واضح الفكرة؟
+
+440
+00:39:20,340 --> 00:39:24,120
+اتخيلوا عاد كيف الطالب لما بيبعد عن الكلام احنا
+
+441
+00:39:24,120 --> 00:39:28,320
+مرة جيبناله سؤال في الامتحان ارسم العائلة العامة و
+
+442
+00:39:28,320 --> 00:39:33,940
+كتبناله Hydrate, Hemacetal, Acetal وCyanohydrin
+
+443
+00:39:33,940 --> 00:39:37,420
+انا بدي احط هدوله و هنا يعمل شرط اما يكتبليش اشي
+
+444
+00:39:37,420 --> 00:39:42,240
+يعني في مجبوعتين صعبة ولا سهلة؟ سهلة جدا .. سهلة
+
+445
+00:39:42,240 --> 00:39:45,020
+جدا .. الآن
+
+446
+00:39:46,660 --> 00:39:53,640
+بنجي لنيكليوفايل جديد هذا النيكليوفايل الجديد هو H
+
+447
+00:39:53,640 --> 00:40:01,080
+- متذكرين انتوا انه احنا لما حكينا عن الهيدروجين،
+
+448
+00:40:01,080 --> 00:40:07,580
+قولنا الهيدروجين بيدا تمر علينا بكم شكل؟ تلت أشكال
+
+449
+00:40:07,580 --> 00:40:10,700
+H plus وH
+
+450
+00:40:14,320 --> 00:40:19,580
+و أعطناهم أسماء الـ H بلس شو قلنا عنها البروتون
+
+451
+00:40:19,580 --> 00:40:25,480
+اللي بيفقد الحامض و الـ H هيدروجين أتم الـ H minus
+
+452
+00:40:25,480 --> 00:40:30,880
+هيدرايد أنيون الان مين في هدولة التلاتة
+
+453
+00:40:30,880 --> 00:40:38,080
+نيوكليوفاين الهيدرايد أنيون طيب انتهت الكلام طالما
+
+454
+00:40:38,080 --> 00:40:44,480
+الهيدرايد أنيوناليوكليوفايل لو أخدت الديهيد زي هذا
+
+455
+00:40:44,480 --> 00:40:48,040
+خلّيني أقول ال Acetaldehyde وهي ال H وحملة ال
+
+456
+00:40:48,040 --> 00:40:52,860
+minus وقلتلكوا أكمل المعادلة ال hydride بدو يتفعل
+
+457
+00:40:52,860 --> 00:40:59,320
+مع هذا شو هيعمل ال C double bond O هتصير O H هي
+
+458
+00:40:59,320 --> 00:41:03,480
+باللون الأخضر واليوكليوفايل بهذه الحالة هو عبارة
+
+459
+00:41:03,480 --> 00:41:12,270
+عن إيش ال Hما العائلة الجديدة اللتي تكونت هنا؟كحول
+
+460
+00:41:12,270 --> 00:41:17,650
+هذه عملية الاختزال الار بيصير السؤال هو بالدنيا
+
+461
+00:41:17,650 --> 00:41:23,870
+بينباع H- لحاله؟ لأ بينباع على شكل المراكبات
+
+462
+00:41:23,870 --> 00:41:29,970
+المراكبات اللي بتكون مصدر للhydride anion موجود
+
+463
+00:41:29,970 --> 00:41:33,930
+منها وتستعمل كعوامل مختزلة لحظوا هذه العملية
+
+464
+00:41:33,930 --> 00:41:38,410
+اختزال لأن C double bond O صارت OH واحدة نقص في
+
+465
+00:41:38,410 --> 00:41:44,610
+محتوىالأكسوجين وزيادة في محتوى الهيدروجين أنا زيدت
+
+466
+00:41:44,610 --> 00:41:49,430
+هنا H وزيدت هنا H هايهم تنتين هذا الاختزال بعينه
+
+467
+00:41:49,430 --> 00:41:54,690
+مظبوط ولا لأ الآن العوامل المختزلة عادة بتكون
+
+468
+00:41:54,690 --> 00:41:58,410
+هيدرايد أو ممكن الإنسان يعملها بإضافة الهيدروجين
+
+469
+00:41:58,410 --> 00:42:02,120
+هنا إحنا إيش اللي بنستعمله الهيدرايدلحظوا من
+
+470
+00:42:02,120 --> 00:42:06,320
+الهيدرايتز اللي مشهورة جدا هذا المركّب الليثيام
+
+471
+00:42:06,320 --> 00:42:12,340
+والألمنيوم اللي متصل ب 4H- لحظوا الألمنيوم بوضعه
+
+472
+00:42:12,340 --> 00:42:18,880
+الطبيعي بيكون ايش تلاتة موجة حطوا عليه 4H- كل ال
+
+473
+00:42:18,880 --> 00:42:23,920
+ايون شو هيصفاه minus عشان يطلع الجزية متعادلة
+
+474
+00:42:23,920 --> 00:42:31,420
+بحطله lithium plusهذا بيصير Lithium Tetrahydride
+
+475
+00:42:31,420 --> 00:42:39,180
+Aluminate طبعا الات هي نهاية إيش؟ الايون السالب مش
+
+476
+00:42:39,180 --> 00:42:43,440
+أخدنا احنا الايونات السالبة سولفات، كربونات،
+
+477
+00:42:43,440 --> 00:42:50,230
+نيترات، أسيتات، الآن هنا قولنا إيش؟ Aluminateكل
+
+478
+00:42:50,230 --> 00:42:57,290
+عمره بنقول سلفيت SO4 minus minus نيتريت NO3 minus
+
+479
+00:42:57,290 --> 00:43:03,170
+فال eight نهاية ال ايش ال ايون السالب الان هذا
+
+480
+00:43:03,170 --> 00:43:07,050
+الجزء متعادل لان عندي ليثيام plus والالمنيوم تلاتة
+
+481
+00:43:07,050 --> 00:43:12,770
+plus هاي أربعة موجب وال H أربعة minus صف الجزء كله
+
+482
+00:43:12,770 --> 00:43:18,190
+ايش ليثيام تترا هيدرايدو ألمينيت أو هذا من البورون
+
+483
+00:43:18,950 --> 00:43:26,130
+Sodium Tetrahydride من البرون بوريت مش من البروم
+
+484
+00:43:26,130 --> 00:43:31,350
+البرون لما تمشوا في أول الجدول الدوري العنصر
+
+485
+00:43:31,350 --> 00:43:35,890
+الخامس يعني تطلعوا على عناصر الجدول الدوري H بعدين
+
+486
+00:43:35,890 --> 00:43:41,590
+helium بعدين lithium بعدين beryllium بعدين boron
+
+487
+00:43:41,590 --> 00:43:48,520
+واضح؟ اه ال boronSodium tetrahydride borate الان
+
+488
+00:43:48,520 --> 00:43:52,160
+هذول الحقيقة بياخدوا كمان اسماء تانية لو سمعتهم
+
+489
+00:43:52,160 --> 00:43:55,700
+بأي اسمين هذول من أشهر العوامل المختز ل ال
+
+490
+00:43:55,700 --> 00:44:02,140
+hydrides هم ببساطة مصدر ل إيش ل H minus يعني احنا
+
+491
+00:44:02,140 --> 00:44:06,840
+بنفهمه مصدر ل H minus هذا بيسموه ال lithium
+
+492
+00:44:06,840 --> 00:44:13,460
+tetrahydride aluminate بيسموه lithium aluminum
+
+493
+00:44:13,460 --> 00:44:20,740
+hydrideالومينوم هايدرايد يعني نفسه ممكن تلاقوه تحت
+
+494
+00:44:20,740 --> 00:44:24,840
+اسم ليثيام ألومينوم هايدرايد أو ليثيام تيترا
+
+495
+00:44:24,840 --> 00:44:29,260
+هايدرايد و ألومينيت وهذا بيسموه صوديوم بورو
+
+496
+00:44:29,260 --> 00:44:35,230
+هايدرايد مش بورونBorohydride فإذا سمعتوا Sodium
+
+497
+00:44:35,230 --> 00:44:38,770
+Borohydride أو Sodium Tetrahydride و Borate نفس
+
+498
+00:44:38,770 --> 00:44:43,330
+الاسم Lithium Tetrahydride و Aluminate أو Lithium
+
+499
+00:44:43,330 --> 00:44:47,690
+Aluminum Hydride نفس الاسم و مرات كتير حتى الاسم
+
+500
+00:44:47,690 --> 00:44:52,530
+هذا Sodium Borohydride و عادة مش هيكونوا عاملينه
+
+501
+00:44:52,530 --> 00:44:57,310
+زيك هتلاعظوا على السهم مكتوب عندكم NABH4
+
+502
+00:44:58,940 --> 00:45:05,980
+وهنا هتلاحظوا Lithium Aluminum H4 اذا شفتوا هذا او
+
+503
+00:45:05,980 --> 00:45:09,780
+هذا هذا Sodium Borohydride Lithium Aluminum
+
+504
+00:45:09,780 --> 00:45:16,560
+Hydride شوفوا مثلها Sodium Borohydride Lithium
+
+505
+00:45:16,560 --> 00:45:21,220
+Aluminum Hydride هدوله الشرعوه المختزلة هم في
+
+506
+00:45:21,220 --> 00:45:27,990
+النهاية مصدر لإيش؟لل H- الان ال H- لما هاجم على ال
+
+507
+00:45:27,990 --> 00:45:34,850
+aldehyde عملوا ايش؟ كحول وهذه عملية الاختزال عكس
+
+508
+00:45:34,850 --> 00:45:40,150
+عملية ايش؟ الاكسادة هذه عملية الاختزال عكس عملية
+
+509
+00:45:40,150 --> 00:45:47,190
+الاكسادة هي reducing agents طبعا لو ال H- هاجم على
+
+510
+00:45:47,190 --> 00:45:53,490
+كيتون هيعملوا ايش؟secondary alcohol اذا انتبهوا
+
+511
+00:45:53,490 --> 00:45:59,030
+معي جيدا انه لما الهجوم تم على ال الديهايد عادي
+
+512
+00:45:59,030 --> 00:46:06,550
+اتكول اه اذا هل جيتها بنصير نكتب reduction عشان
+
+513
+00:46:06,550 --> 00:46:11,950
+تكون واضحة الأمور معاكم قبل الديهايدs produces
+
+514
+00:46:11,950 --> 00:46:19,070
+primary alcoholreduction of aldehydes produces
+
+515
+00:46:19,070 --> 00:46:23,950
+primary alcohols الان تحتها هيصير reduction of
+
+516
+00:46:23,950 --> 00:46:28,890
+كيتون ايش
+
+517
+00:46:28,890 --> 00:46:35,050
+produces secondary alcohols هو كل درسنا aldehydes
+
+518
+00:46:35,050 --> 00:46:40,240
+او كيتون ولا في غيرهم؟أذا بدنا نكون عارفين ان ال
+
+519
+00:46:40,240 --> 00:46:45,240
+الديهايد لما بنعمله reduction بالهيدرايد بده يصير
+
+520
+00:46:45,240 --> 00:46:50,080
+عنده primary alcohol و ال ketone لما بنعمله
+
+521
+00:46:50,080 --> 00:46:54,240
+reduction بال الديهايد بده يصير عنده secondary
+
+522
+00:46:54,240 --> 00:46:58,940
+alcohol لاحظوا هذا الكلام بفيدكم سواء بجمل صح و
+
+523
+00:46:58,940 --> 00:47:03,820
+غلط بأكمل معادلة او حتى لو احنا سألناكوا سؤال how
+
+524
+00:47:03,820 --> 00:47:09,210
+can you prepare the following compoundواضح؟ لما
+
+525
+00:47:09,210 --> 00:47:12,610
+تشوفوا أن الناتج اللي عندكم primary alcohol إذا
+
+526
+00:47:12,610 --> 00:47:16,530
+بتقدروا تفكروا أنه ممكن يكون إيجا من وين لما
+
+527
+00:47:16,530 --> 00:47:19,930
+تشوفوا الناتج اللي عندكم secondary alcohol إذا
+
+528
+00:47:19,930 --> 00:47:25,430
+ممكن يكون إيجا من وين من كيتون واضح الفكرة؟ بنقف
+
+529
+00:47:25,430 --> 00:47:29,510
+عند هذه النقطة المرة القادمة إن شاء الله بنحكي عن
+
+530
+00:47:29,510 --> 00:47:34,690
+تفاعل الديهيدس والكيتون مع متفاعل اسمه green yard
+
+531
+00:47:34,690 --> 00:47:39,740
+reagent عمرنا حكينا عنه؟بنعرفه المرة الجاية وبنشوف
+
+532
+00:47:39,740 --> 00:47:44,440
+كيف بتفاعل ال الديهيد والكيتون مع ال green yard
+
+533
+00:47:44,440 --> 00:47:46,220
+reagent شكرا
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b0ab76fbc41eb0eb433ee7322cf3a1d9a5cd0846
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.srt
@@ -0,0 +1,2140 @@
+1
+00:00:19,470 --> 00:00:24,730
+بسم الله الرحمن الرحيم بدأنا من محاضرة او محاضرتين
+
+2
+00:00:24,730 --> 00:00:28,470
+في موضوع ال الديهيدس والكيتونز اتعرفنا عليهم ليش
+
+3
+00:00:28,470 --> 00:00:34,430
+اتصنفوا مع بعض تسمية ال الديهيدس والكيتونز طرق
+
+4
+00:00:34,430 --> 00:00:38,690
+صناعية لتحضير اشهر ال الديهيدس والكيتونز كان اخر
+
+5
+00:00:38,690 --> 00:00:44,270
+شيء اتكلمنا عنه الان في المختبر الطرق العامة
+
+6
+00:00:44,270 --> 00:00:49,420
+لتحضير ال الديهيدس والكيتونزإذا بنستعرضها مع بعض
+
+7
+00:00:49,420 --> 00:00:53,560
+بنلاحظ أن هذه الأشياء مرت علينا الحقيقة يعني
+
+8
+00:00:53,560 --> 00:00:58,080
+الطريقة الأولى لتحضير ال aldehydes و ال ketones من
+
+9
+00:00:58,080 --> 00:01:03,300
+أجسدة الكحولات لما أخدنا ال alcohols قلنا أن ال
+
+10
+00:01:03,300 --> 00:01:06,880
+alcohols they are either primary, secondary or
+
+11
+00:01:06,880 --> 00:01:13,120
+tertiary وقلنا أن ال primaryبصيروا باستعمال ال BCC
+
+12
+00:01:13,120 --> 00:01:16,960
+الديهيدز و ممكن يمدوا اكتر لو كان العامل مؤاكسد
+
+13
+00:01:16,960 --> 00:01:20,660
+اقوى بصيروا acids هذا مش الموضوع هنا ال secondary
+
+14
+00:01:20,660 --> 00:01:26,500
+alcohol باستعمال كيامانو 4 او كيتو كروميون 2
+
+15
+00:01:27,340 --> 00:01:33,400
+برمجانات البوتاسيوم كيتو كروميوم 207 بوتاسيوم داي
+
+16
+00:01:33,400 --> 00:01:37,940
+كروميت أو كروميك أكسيد بيصيروا كيتون فهذا أكسد
+
+17
+00:01:37,940 --> 00:01:42,720
+بالالكوهولز هي طريقة في انها لتحضير ال الديهايد
+
+18
+00:01:42,720 --> 00:01:45,520
+والكيتون من ال primer بناخد ال الديهايد ومن
+
+19
+00:01:45,520 --> 00:01:50,730
+السكندر بناخدالكيتون هذه طريقة مرت علينا سابقا
+
+20
+00:01:50,730 --> 00:01:58,450
+الاروماتيك كيتون أخدناهم كنا انحضر الاسيتوفينون
+
+21
+00:01:58,450 --> 00:02:06,640
+مثلا من استعمال ال acid halidesR-C-O-C-L هذي C-O
+
+22
+00:02:06,640 --> 00:02:10,700
+معناها C double bond و C-L في وجود ألومنيوم
+
+23
+00:02:10,700 --> 00:02:14,400
+الكلورايد الألومنيوم الكلورايد بيسحب الكلور و
+
+24
+00:02:14,400 --> 00:02:18,280
+بيعمل عندنا الايون الموجب و بيصير Electrophilic
+
+25
+00:02:18,280 --> 00:02:22,920
+Substitution اللي سمناه Friedel Crafts Acylation
+
+26
+00:02:22,920 --> 00:02:26,700
+واضح سمناه Friedel Crafts Acylation أخدنا Friedel
+
+27
+00:02:26,700 --> 00:02:30,720
+Crafts Alkylation و Acylation في شبطر الاروماتيك
+
+28
+00:02:31,490 --> 00:02:38,470
+from alkynes اخدنا احنا ان ال alkynes بيضيفوا مية
+
+29
+00:02:38,470 --> 00:02:42,090
+المية اللى بيضيفوها ممكن تكون حسب قاعدة
+
+30
+00:02:42,090 --> 00:02:46,390
+Markovnikov يضيف HOO يصير اندي double bond او Anti
+
+31
+00:02:46,390 --> 00:02:51,070
+Markovnikov HOH و في كل الأحوال لما يصير اندي in
+
+32
+00:02:51,070 --> 00:02:55,810
+all يعني هذا ال alkyne لو ضفنا عليه HOOH بدو يصير
+
+33
+00:02:55,810 --> 00:03:03,290
+double bondInol أخدنا أن Inol يعمل توتوميريزم
+
+34
+00:03:03,290 --> 00:03:08,550
+لكيتون أو لالديهيد سمناها keto inol توتوميريزم
+
+35
+00:03:08,550 --> 00:03:12,050
+يعني بهذا المثال لما نضيف الميه في وجود الحامض
+
+36
+00:03:12,050 --> 00:03:17,090
+فالإضافة بمرحلتها الأولى Markov-Nikov addition لما
+
+37
+00:03:17,090 --> 00:03:21,850
+نعمل التوتوميريزم ال COH بتصير C double bond O
+
+38
+00:03:21,850 --> 00:03:25,830
+يعني هذا بنرجع في الفصل التالت هذا بنرجع في الفصل
+
+39
+00:03:25,830 --> 00:03:30,800
+الرابع هذا بنرجع في الفصلالسابق كل هذه طرق تحضير
+
+40
+00:03:30,800 --> 00:03:36,580
+الالديهيد والكيتون مرت معناه وهذه الميزة الحقيقة
+
+41
+00:03:36,580 --> 00:03:41,540
+موجودة في ال organ ال chemistry انه انا في اندي شي
+
+42
+00:03:41,540 --> 00:03:45,300
+اسمه functional group interconvergent يعني اتحول
+
+43
+00:03:45,300 --> 00:03:51,180
+من شغلة لشغلة من كحول لالديهيد من كحول الى كيتون
+
+44
+00:03:51,180 --> 00:03:57,130
+من الكاين الى كيتونالان طالما صار عندى مسميين
+
+45
+00:03:57,130 --> 00:04:01,670
+طالما صار عندى مسميين اذا الشغل هتمر عندى مرتين
+
+46
+00:04:01,670 --> 00:04:04,150
+يعني لما انا بقول ان انا عندى كحول بده يصير
+
+47
+00:04:04,150 --> 00:04:07,530
+aldehyde او كيتون هتلاقوا انحنا نذكرها لما بنحكي
+
+48
+00:04:07,530 --> 00:04:10,990
+عن ال alcohol كتفاعل و نذكرها لما بنحكي عن ال
+
+49
+00:04:10,990 --> 00:04:15,290
+aldehydes و ال ketones كطريقة للتحضير بعد شوية
+
+50
+00:04:15,290 --> 00:04:18,690
+هنيجي على ال aldehydes و ال ketones طالما هذه
+
+51
+00:04:18,690 --> 00:04:25,320
+العملية أكسدة طب لو رجعنا فيها رجوعهتصير تفاعل لل
+
+52
+00:04:25,320 --> 00:04:28,060
+الديهيد والكيتون هلاحظ ان ال reduction of
+
+53
+00:04:28,060 --> 00:04:31,700
+aldehydes and ketones produces ايش؟ alcohol
+
+54
+00:04:31,700 --> 00:04:36,960
+فالعملية عملية متعاكسة وعشان كده الكلام بنشوفه
+
+55
+00:04:36,960 --> 00:04:41,820
+باكثر من مكان alcohol صار الديهيد او كيتون بالاكسة
+
+56
+00:04:41,820 --> 00:04:48,000
+ده الآن طب الديهيد او كيتونبالاختصار هيرجع ايش؟
+
+57
+00:04:48,000 --> 00:04:53,740
+هيرجع لالكول وسبق احنا انه وضحنا معنى الأكسادة ان
+
+58
+00:04:53,740 --> 00:05:00,020
+هي في النهاية اما انها زيادة في المحتوى الاكسوجيني
+
+59
+00:05:00,020 --> 00:05:05,940
+او نقص في محتوى الهيدروجينيالان هذه ال aldehydes و
+
+60
+00:05:05,940 --> 00:05:10,920
+ال ketones خلينا نقول في النهاية هي و كل الكيميا
+
+61
+00:05:10,920 --> 00:05:15,680
+لازم نفهمها من منطق التطبيق العملي يعني هي بتبدأ
+
+62
+00:05:15,680 --> 00:05:19,680
+معناه ربوز لكن في النهاية بواقع الحياة بتنتهي انها
+
+63
+00:05:19,680 --> 00:05:25,170
+مركباتالها وجود في الحياة العملية، الها تطبيق على
+
+64
+00:05:25,170 --> 00:05:28,790
+سبيل المثال ال Benzaldehyde هذا Aldehyde
+
+65
+00:05:28,790 --> 00:05:33,670
+Benzaldehyde هذا هو عبارة عن ال oil of almonds هو
+
+66
+00:05:33,670 --> 00:05:39,600
+زيت اللوزواضح؟ في زيت مشهور اسمه زيت اللوز لو
+
+67
+00:05:39,600 --> 00:05:43,740
+أسرنا اللوز بيطلع منه زيت اللي هو ال benz aldehyde
+
+68
+00:05:43,740 --> 00:05:49,140
+هذا ال aldehyde اللي شايفينه C double bond OH مع
+
+69
+00:05:49,140 --> 00:05:54,000
+حلقة بنزين و double bond هذا مركب كامل هذا اسمه
+
+70
+00:05:54,000 --> 00:05:58,880
+cinnamaldehyde cinnamaldehyde جاية من ال cinnamon
+
+71
+00:05:58,880 --> 00:06:05,880
+cinnamon يعني جرفةواضح؟ فهو المركب الأساسي اللي
+
+72
+00:06:05,880 --> 00:06:10,360
+بيعطي الجرفة الريحة تبعتها لأن الجرفة اسمها
+
+73
+00:06:10,360 --> 00:06:16,560
+cinnamon هو سموه إيش؟cinnamaldehyde مثلا بالالماني
+
+74
+00:06:16,560 --> 00:06:22,480
+الجرفة اسمها zimt فبيسموه zimt aldehyde واضح zimt
+
+75
+00:06:22,480 --> 00:06:27,300
+aldehyde هنا cinnamon cinnamaldehyde واضح فهذه
+
+76
+00:06:27,300 --> 00:06:31,620
+الجرفة اللي احنا بنتناولها في النهاية هي aldehyde
+
+77
+00:06:31,620 --> 00:06:36,180
+مر علينا سابقا ان الفانيلة هي عبارة عن aromatic
+
+78
+00:06:36,180 --> 00:06:40,600
+aldehyde عليه مجموعة هيدروكسي وميثوكسي الفانيلين
+
+79
+00:06:41,300 --> 00:06:47,120
+الان كتير ناس بيحبوا زيت النعناع sperminate oil
+
+80
+00:06:47,120 --> 00:06:51,220
+اللى بدخل فى مشتقات كتيرة و لعلاج الزور هذا عبارة
+
+81
+00:06:51,220 --> 00:06:54,680
+عن كيتون هى فيه ال C double bond O اللى بنسميه
+
+82
+00:06:54,680 --> 00:06:59,960
+carbonالمركب الكيميائي carbon لكن هذا ال carbon هو
+
+83
+00:06:59,960 --> 00:07:05,500
+ال sperm in it oil هو زيت النعمة واضح هذا المركب
+
+84
+00:07:05,500 --> 00:07:08,960
+لاحظوا بتلاحظوه مركب كبير لكن انا بهمن المجموعة
+
+85
+00:07:08,960 --> 00:07:12,280
+الوظيفية في نهاية المجموعة الوظيفية ايش فيه C
+
+86
+00:07:12,280 --> 00:07:17,240
+double bond O كيتون finally كيتون هذا ال camphor
+
+87
+00:07:17,240 --> 00:07:21,720
+الكفور واضح اللي بيستعملوه لعلاج الرجلين و ما إلى
+
+88
+00:07:21,720 --> 00:07:28,840
+ذلك الآن مش ضايل عندنا غير مينغير البحتري عاد
+
+89
+00:07:28,840 --> 00:07:34,560
+الربيع الى الدنيا بموقبه فزينت واكتست بالسندس
+
+90
+00:07:34,560 --> 00:07:38,580
+الشجر اه الياسمين الياسمين خلال أسبوعين اللي عندهم
+
+91
+00:07:38,580 --> 00:07:44,570
+ياسمينة هيلاحظوا كل الياسمينة إيش تصيربيضة من إيش؟
+
+92
+00:07:44,570 --> 00:07:50,590
+أه هي الياسمون كيتو واضح؟ ملاحظين مركب معين هذا
+
+93
+00:07:50,590 --> 00:07:56,910
+اللي هو الياسمون من ال oil of ياسمين من زيت
+
+94
+00:07:56,910 --> 00:08:01,190
+الياسمين بنطول هذا المركب الأساسي اللي بيعطيها
+
+95
+00:08:01,190 --> 00:08:04,790
+الريحة الكويسة سواء عملنا منه أطور أو الناس حتى
+
+96
+00:08:04,790 --> 00:08:11,500
+بيشموها و هي على الشجر ريحة جيدةفهذه المراكبات
+
+97
+00:08:11,500 --> 00:08:16,860
+الحقيقة يعني إلها مجال كبير في التطبيق طبعا أكيد
+
+98
+00:08:16,860 --> 00:08:20,060
+إلها مجالات في أشياء كتيرة غير هيك في أدوية في
+
+99
+00:08:20,060 --> 00:08:24,280
+الصناعة ولذلك إحنا بندرسها بعنق و بنتعرف عليها
+
+100
+00:08:24,280 --> 00:08:31,560
+الآن لو بدنا نيجي بعد هيك لتفاعلات ال aldehydes و
+
+101
+00:08:31,560 --> 00:08:38,080
+ال ketones قلنا بشكل عام الأمر مختصر فيهكلمة واحدة
+
+102
+00:08:38,080 --> 00:08:43,900
+اللي هي addition واضح طبعا لو اجينا بدنا ندقق في
+
+103
+00:08:43,900 --> 00:08:48,540
+كلمة ال addition in eucleophilic addition بمعنى
+
+104
+00:08:48,540 --> 00:08:54,820
+المهاجم لازم يكون ايش؟اليوكليوفايل ليش المهاجم
+
+105
+00:08:54,820 --> 00:08:59,660
+لازم يكون اليوكليوفايل لأن الالدهايد والكيتون فيهم
+
+106
+00:08:59,660 --> 00:09:03,060
+السيضة بالبوند او اللي موجودة لو اتطلعنا علي اي
+
+107
+00:09:03,060 --> 00:09:07,040
+مكان ارسمها بشكل اوضح السيضة بالبوند او لو اتطلع
+
+108
+00:09:07,040 --> 00:09:10,420
+السلبية هذا الطرف partially positive هذا partially
+
+109
+00:09:10,420 --> 00:09:16,870
+negative الان اللي بدو يهاجم عادةاليوكليوفايل واضح
+
+110
+00:09:16,870 --> 00:09:21,210
+اللي بيهاجم عادة نيوكليوفايل لما يهاجم هنا زوج
+
+111
+00:09:21,210 --> 00:09:25,430
+الإلكترونات هذا بتتحرك بيصف النتيجة ان هي carbon
+
+112
+00:09:25,430 --> 00:09:33,470
+OH نيوكليوفايل الان في عند اصلا مجموعتين تانين هنا
+
+113
+00:09:33,470 --> 00:09:37,350
+مش رسموهم دولة مافيش عليهم أي تغيير
+
+114
+00:09:38,710 --> 00:09:42,830
+الخلاصة أن التفاعل الأساسي لـ aldehydes و لـ
+
+115
+00:09:42,830 --> 00:09:48,430
+ketones كان هناك double bond و أصبحت تنتين single
+
+116
+00:09:48,430 --> 00:09:53,550
+bond واحدة OH واحدة نيوكليوفايل بكل الأحوال هنا
+
+117
+00:09:53,550 --> 00:09:57,690
+عدد الروابط أربعة و هنا عدد الروابط أربعة فال
+
+118
+00:09:57,690 --> 00:10:04,000
+double bond O تصبحوبصير عنده رابطة جديدة مع ال
+
+119
+00:10:04,000 --> 00:10:09,580
+file واضح الفكرة هذا هو التفاعل اللي هيظل يتكرر
+
+120
+00:10:09,580 --> 00:10:17,260
+بناء على ذلك بصير الان كل هذه المحاضرةهتحكي شغلة
+
+121
+00:10:17,260 --> 00:10:21,260
+واحدة بسيطة اللي بيفهمها بيقدر إذا مستعجل يروح
+
+122
+00:10:21,260 --> 00:10:24,640
+يمشي إنه إيش أنواع الـ nucleophile اللي بتهاجم
+
+123
+00:10:24,640 --> 00:10:28,140
+أعطونا أمثلة بنقول نمروا واحد الميّه، نمروا اتنين
+
+124
+00:10:28,140 --> 00:10:31,260
+الكحول، نمروا تلاتة الـCr، نمروا أربعة الـH-,
+
+125
+00:10:31,260 --> 00:10:36,000
+نمروا خمسة كذا، نمروا ستة كذا فبكل المحاضرة هذه
+
+126
+00:10:36,000 --> 00:10:40,880
+فقط احنا بدنا نحتفظ بهذا ال frame إن هدول
+
+127
+00:10:40,880 --> 00:10:44,200
+المجموعتين في الأساس ماتغيروش الـC double bond O
+
+128
+00:10:44,200 --> 00:10:51,110
+صارت OHانغيّر هذه المجموعة واضحة الفكرة؟ بمعنى لو
+
+129
+00:10:51,110 --> 00:10:55,370
+انا الآن بقولكوا ان النيوكليوفايل كان ميّه ايش
+
+130
+00:10:55,370 --> 00:11:01,110
+هنحط هنا؟ OH بيصير عائلة اسمها الهيدريت اللي فيها
+
+131
+00:11:01,110 --> 00:11:04,010
+كاربون حاملة انت نواتش بحكي بالتفصيل ماتستعجلوش
+
+132
+00:11:04,010 --> 00:11:11,350
+الآن طب لو ضفنا كحول؟ OR بيصير عائلة جديدة اسمها
+
+133
+00:11:11,350 --> 00:11:15,570
+سيانهيدريل شوف كيف البساطة طب لو ضفنا CM؟
+
+134
+00:11:18,510 --> 00:11:26,090
+لحظة لو سمحتوا لو ضفنا OR بيصير عندنا عائلة اسمها
+
+135
+00:11:26,090 --> 00:11:29,570
+hemacetal انا قلت cyanohedrin hemacetal طيب لو
+
+136
+00:11:29,570 --> 00:11:37,070
+ضفنا CN cyanohedrin بيسموها لو ضفنا H minus هذه
+
+137
+00:11:37,070 --> 00:11:46,110
+عملية الاختزال H برجعلك كحول واضح؟ لو ضفنا Amin
+
+138
+00:11:46,860 --> 00:11:53,400
+أمونيا انا H2 متعودين انتوا لنيوترا ليوكليوفايل شو
+
+139
+00:11:53,400 --> 00:12:01,380
+هيصير هيفقد H و هكذا فكل الأمثلة اللي هنحكيها
+
+140
+00:12:01,380 --> 00:12:05,020
+هتكون ماخدة هذا الإطار العام كل الأمثلة اللي
+
+141
+00:12:05,020 --> 00:12:08,700
+هنحكيها هتاخد هذا الإطار العام البسيط
+
+142
+00:12:11,390 --> 00:12:18,850
+بفيد شغلة أن هذا التفاعل بشكل عام بتم له catalysis
+
+143
+00:12:18,850 --> 00:12:23,970
+يعني تسريع بإضافة H plus عشان هيك في معظم الحالات
+
+144
+00:12:23,970 --> 00:12:29,910
+هتلاحظوا على سهم التفاعل موجود عنده في وجود إيشأتش
+
+145
+00:12:29,910 --> 00:12:37,090
+بلس وظيفتها أن تعمل تسريع للتفاعل لاحظوا لو أنا
+
+146
+00:12:37,090 --> 00:12:40,710
+كان عندي الديهيد او كيتون وضفت عليه أتش بلس الأتش
+
+147
+00:12:40,710 --> 00:12:46,140
+بلس وين هتروح على الموجة ولا على الأكسجين السالبع
+
+148
+00:12:46,140 --> 00:12:51,580
+الأكسجل موجب على سالب هتصير بهذا الشكل و لو حركنا
+
+149
+00:12:51,580 --> 00:12:54,860
+زوج الألكترونات تعملنا resonance هلاحظ أنه أنا
+
+150
+00:12:54,860 --> 00:12:59,720
+بصير عند الكاربون موجبة full positive charge الآن
+
+151
+00:12:59,720 --> 00:13:03,880
+قبل شوية لما رسمنا احنا كنا نقول هنا إيش شحنة إيش
+
+152
+00:13:03,880 --> 00:13:11,060
+مالها partial charge ال acidلما اجى اضاف ال H plus
+
+153
+00:13:11,060 --> 00:13:16,060
+هنا خلى هذا ال carbon موجب كامل الان ال
+
+154
+00:13:16,060 --> 00:13:22,200
+nucleophile انه افضل له اهاجم على موجب جزء ولا على
+
+155
+00:13:22,200 --> 00:13:26,900
+موجب كامل اهاجم على موجب كامل التجادب ايش بيكون
+
+156
+00:13:26,900 --> 00:13:31,320
+اقوى والتفاعل اسرع هاي بالظبط اللي بيعملوا ال acid
+
+157
+00:13:31,320 --> 00:13:37,720
+الان الناتج النهائي مافيش فيه خلافالناتج النهائي
+
+158
+00:13:37,720 --> 00:13:42,280
+هو نفس الناتج لكن دائما لما بتقرأوا التفاعل
+
+159
+00:13:42,280 --> 00:13:45,840
+هتلاحظوا انه على السهم في عندكم ايش اتش بلس اتش
+
+160
+00:13:45,840 --> 00:13:50,520
+بلس هذه الاتش بلس عبارة عن catalyst بتسرع ايش
+
+161
+00:13:50,520 --> 00:13:57,040
+التفاعل بالطريقة اللي حكيناها الان لو بدأنا ناخد
+
+162
+00:13:57,040 --> 00:14:01,220
+امثلة هاي هذه ال carbon في ال aldehyde موجبة اجت
+
+163
+00:14:01,220 --> 00:14:07,400
+الميه تهاجمأول الـ Eucalyptus ناخد الميّه الـ C
+
+164
+00:14:07,400 --> 00:14:13,760
+double bond O شو بتصير؟ OH نحطها بالأخضر و الميّه
+
+165
+00:14:13,760 --> 00:14:16,280
+هتضيف
+
+166
+00:14:17,080 --> 00:14:23,100
+OH في النهاية واضح هاي صار عندنا استيظة بال bond O
+
+167
+00:14:23,100 --> 00:14:27,960
+صارت OH والمية كان يوكليوفال بتضيف OH الان هنا
+
+168
+00:14:27,960 --> 00:14:34,580
+اتكون عندى مركب على نفس ذرة الكربون تبعته كام OH؟
+
+169
+00:14:34,580 --> 00:14:40,480
+تلتين هذه المركبات اللى على نفس ذرة الكربون فيها
+
+170
+00:14:40,480 --> 00:14:47,840
+تلتين OH بنعطيها اسم hydratesواضح فال hydrate لو
+
+171
+00:14:47,840 --> 00:14:52,800
+قلتلكوا ارسمولي شكل عام لل hydrate معنى ذلك تحطوا
+
+172
+00:14:52,800 --> 00:14:59,420
+carbon على نفس ال carbon تنتين O H's يمكن انتوا
+
+173
+00:14:59,420 --> 00:15:05,340
+سابقا مر عليكم انه يكون عندى في المركب تنتين O H's
+
+174
+00:15:05,340 --> 00:15:12,440
+على ذرات متجاورة زي هيك هذا المركب لما انا كنت
+
+175
+00:15:12,440 --> 00:15:20,400
+اسميهماذا كنت أسميه؟ داي أول داي أول و لأنه
+
+176
+00:15:20,400 --> 00:15:29,620
+كربونتين اثان داي أولواضح إيثان دايول على نمرة
+
+177
+00:15:29,620 --> 00:15:32,360
+واحد وعن نمرة اتنين ممكن تكتبوا one two إيثان
+
+178
+00:15:32,360 --> 00:15:37,980
+دايول تمام لكن لما يكونوا مجموعتين ال OH على نفس
+
+179
+00:15:37,980 --> 00:15:41,860
+ال carbon بنسمي عائلة جديدة هذه العائلة إيش
+
+180
+00:15:41,860 --> 00:15:47,620
+بنسميها hydrate الان المركب نفسه بنسميه نسبة ال
+
+181
+00:15:47,620 --> 00:15:51,140
+aldehyde الأصلي يعني هذا ال aldehyde الأصلي الآن
+
+182
+00:15:51,140 --> 00:15:55,620
+formaldehydeبتذكروا لما قلنا ال formaldehyde غاز
+
+183
+00:15:55,620 --> 00:16:00,400
+ملدوبه في الميه عملية اذابته في الميه هي ان الميه
+
+184
+00:16:00,400 --> 00:16:04,880
+تتفاعل عليه تعمل هان OH و تخلص سيضا من البند OH
+
+185
+00:16:04,880 --> 00:16:11,560
+هذا ال formaldehyde هيدريت طب لو كان acetaldehyde
+
+186
+00:16:11,560 --> 00:16:16,700
+واحدة من دول ال حزب ده تصير CH3 و هكذا الان لاحظوا
+
+187
+00:16:16,700 --> 00:16:22,380
+معي ان ال hydrate تفاعل تكوينه متفاعل ايش
+
+188
+00:16:23,760 --> 00:16:28,200
+Equilibrium reaction يعني لا يتم بشكل كامل بيكون
+
+189
+00:16:28,200 --> 00:16:34,020
+موجود ال الديهيد مع الميه مع الهيدرين بنسبة معينة
+
+190
+00:16:34,020 --> 00:16:40,200
+الان في حالة ال formaldehyde بيصل لإن هذا يتفاعل
+
+191
+00:16:40,200 --> 00:16:45,550
+بنسبة 37% عشان ايه بيصير لكم الفورمالينهو نفس الـ
+
+192
+00:16:45,550 --> 00:16:48,910
+Formal Dehydrate الـ Formalin اللي أخدنا بنستعمله
+
+193
+00:16:48,910 --> 00:16:53,390
+لحفظ الأنسجة وغيرها هو نفسه ال Formal Dehydrate
+
+194
+00:16:53,390 --> 00:16:56,730
+اللي هو ال Formal Dehydrate اتدوب في الميه عمل هذا
+
+195
+00:16:56,730 --> 00:17:01,790
+الشكل ال Formalin واضح الفكرة؟ وهذا التفاعل زي ما
+
+196
+00:17:01,790 --> 00:17:07,950
+قلنا عنه تفاعل عكسي الآن هل يترا في كل ال ال
+
+197
+00:17:07,950 --> 00:17:12,300
+Dehydrates و ال Ketones ممكن يتكون هيدريتز؟من
+
+198
+00:17:12,300 --> 00:17:17,260
+ناحية نظرية بالورقة والقلم اه يعني انا بقدر
+
+199
+00:17:17,260 --> 00:17:21,260
+اقولكوا اي aldehyde في الدنيا ارسموله hydrate
+
+200
+00:17:21,260 --> 00:17:26,620
+الاصل انكم تعرفوا تعملوا hydrate له مثلا لو اجاكم
+
+201
+00:17:26,620 --> 00:17:32,020
+في الامتحان ارسمولنا benz aldehyde hydrate المنطلق
+
+202
+00:17:32,020 --> 00:17:38,630
+تبعكم لازم تكونوا عارفين ال benz aldehydeهي ال
+
+203
+00:17:38,630 --> 00:17:44,210
+benz aldehyde C double bond O H الان احنا اتفقنا
+
+204
+00:17:44,210 --> 00:17:49,230
+لما بدى يعمل hydrate هدول المجمعتين مافيش فيهم
+
+205
+00:17:49,230 --> 00:17:56,450
+تغيير طب ها شو بدى يصير ال C double bond O بتصير O
+
+206
+00:17:56,450 --> 00:18:05,030
+H والمية بتضيف O H هذا بتصير benz aldehyde hydrate
+
+207
+00:18:05,890 --> 00:18:11,750
+و هكذا يعني بنفس هذه الطريقة ممكن نرسم لأي ألديهيد
+
+208
+00:18:11,750 --> 00:18:15,850
+أو كيتون هيدريت لو قولنا أسيتون هيدريت أسيتالديهيد
+
+209
+00:18:15,850 --> 00:18:21,210
+هيدريت لكن الحقيقة معظم الهيدريت بشكل عام they are
+
+210
+00:18:21,210 --> 00:18:26,930
+unstable يعني في حالة الإتزان اللي بيوجد بشكل أكبر
+
+211
+00:18:26,930 --> 00:18:33,280
+كتير جدا هو الألديهيدو لذلك هذا التفاعل بيصير نوعا
+
+212
+00:18:33,280 --> 00:18:37,200
+ما تفاعل نظري مش تفاعل عملي يعني بيكون هذا ال
+
+213
+00:18:37,200 --> 00:18:42,160
+الديهيد او ال ketone موجود بالنسبة 99.9% و هذا
+
+214
+00:18:42,160 --> 00:18:46,780
+موجود بالنسبة قليلة جدا و لذلك معظم ال الديهيد و
+
+215
+00:18:46,780 --> 00:18:50,820
+ال ketones بيكون ال position of equilibrium اتجاه
+
+216
+00:18:50,820 --> 00:18:54,580
+الاتزان فيها هل هو باتجاه ال hydrate و لا باتجاه
+
+217
+00:18:54,580 --> 00:18:56,040
+ال الديهيد او ال ketone
+
+218
+00:18:58,860 --> 00:19:04,840
+واضح الفكرة؟ لكن نظريا كل شيء له hydrate الان مثلا
+
+219
+00:19:04,840 --> 00:19:10,420
+هذا المركب تطلع عليه carbon حملة تين و H إذا هذا
+
+220
+00:19:10,420 --> 00:19:15,120
+hydrate ولا لأ؟ Hydrate طب الآن لو قلت لواحدة
+
+221
+00:19:15,120 --> 00:19:22,520
+فيكوا هذا ال hydrate من أي الديهيد جاي كيف
+
+222
+00:19:22,520 --> 00:19:28,900
+بدى تعمل؟ بدى تخلي الرابطتين اللي موجودات ال Hو ال
+
+223
+00:19:28,900 --> 00:19:34,800
+C اللي حاملة تلاتة كلور يعني CCLCLCL و تحط هنا
+
+224
+00:19:34,800 --> 00:19:41,420
+double bond O هذا مركب موازل ال acetaldehyde لكن
+
+225
+00:19:41,420 --> 00:19:46,160
+ابدلت تلت ذرات الهيدروجين فيه بكلور فبصير اسمه ايش
+
+226
+00:19:46,160 --> 00:19:53,340
+اكلورال اكلورال لما اعمل من ال اكلورال هيدريت
+
+227
+00:19:53,340 --> 00:20:01,450
+باضافة الميهبيصير ايش اسمه اكلورال هايدريت فانا ال
+
+228
+00:20:01,450 --> 00:20:05,770
+الديهايدي اللي عندي اكلورال لما اعمله اضافة ميه
+
+229
+00:20:05,770 --> 00:20:10,950
+بيصير اكلورال هايدريت واضح لما اعمله اضافة ميه
+
+230
+00:20:10,950 --> 00:20:15,530
+بيصير اكلورال هايدريت هذا ال اكلورال هايدريت مادة
+
+231
+00:20:15,530 --> 00:20:19,650
+تستعمل في التخدير و عادة في التخدير في الطب
+
+232
+00:20:19,650 --> 00:20:24,090
+البيطري يعني لما يعملوا عمليات جراحية للحيوانات
+
+233
+00:20:24,090 --> 00:20:28,860
+الكبيرة الضخمةبيعطوها chloral hydrate كمخدر فيلو
+
+234
+00:20:28,860 --> 00:20:36,660
+ما إلى ذلك واضح؟ فهذا بالنسبة لل hydrate الأن كتير
+
+235
+00:20:36,660 --> 00:20:40,160
+مرات بنيجي بنقول للطالب في الامتحان النهار or some
+
+236
+00:20:40,160 --> 00:20:44,420
+general structure of hydrate بشكل عام شو بده يحط
+
+237
+00:20:44,420 --> 00:20:53,080
+الليه؟ carbon حاملة تنتلؤ أدشز واضح؟طيب لو اتينا ل
+
+238
+00:20:53,080 --> 00:20:59,680
+ال alcohol كيف بتتفاعل برضه إضافة الآن على طول
+
+239
+00:20:59,680 --> 00:21:05,140
+السيباب البندقوس شو هتصير OH و ال nucleophile اللي
+
+240
+00:21:05,140 --> 00:21:12,520
+هيهاجم OR لاحظوا هنا صار عندى ذرة carbon بتحمل مش
+
+241
+00:21:12,520 --> 00:21:21,470
+تنتين OHOH و OR يعني كأن هذا المركب هو عبارة عن
+
+242
+00:21:21,470 --> 00:21:28,230
+كحول و إيثر بنفس الوقت كاربون بتحمل OH هذا ألكوهول
+
+243
+00:21:28,960 --> 00:21:36,180
+و carbon OR هذا ether واضح فهذا المركب كأنه كحول و
+
+244
+00:21:36,180 --> 00:21:40,680
+ether و هذه العملية إضافة ليش إضافة هذه العملية
+
+245
+00:21:40,680 --> 00:21:44,200
+لأن ال double bond صارت single bond هذه الإضافة
+
+246
+00:21:44,200 --> 00:21:47,900
+ببساطة ال double bond single bond إضافة خلصنا الآن
+
+247
+00:21:47,900 --> 00:21:53,240
+هذا اللي فيه ال carbon بتحمل OH و OR بنسميه
+
+248
+00:21:53,240 --> 00:22:00,690
+hemiacetalيعني إيش؟ نص أسيتال مش أسيتال كامل، الآن
+
+249
+00:22:00,690 --> 00:22:06,190
+لما أي شغل نقول هذا نص أسيتال حيصير التفكير عندكم
+
+250
+00:22:06,190 --> 00:22:12,030
+طب هو إيش الأسيتال؟ الكامل، إذا في بالدنيا نص
+
+251
+00:22:12,030 --> 00:22:17,430
+أسيتال، إذا أكيد في الدنيا في إيش؟ أسيتال كامل،
+
+252
+00:22:17,430 --> 00:22:21,750
+hemacetal نص أسيتال، طب وإيش الأسيتال الكامل؟
+
+253
+00:22:24,180 --> 00:22:32,080
+إتنين إيثر لو هذا المركب نفسه الـ hemacetal فعلناه
+
+254
+00:22:32,080 --> 00:22:37,480
+مع زيادة من الكحول فعلناه مع زيادة من الكحول الآن
+
+255
+00:22:37,480 --> 00:22:41,960
+مرة تانية بيجي الكحول في هذه الحالة بيعمل تفاعل
+
+256
+00:22:41,960 --> 00:22:46,800
+تاني بيهاجم على الكربون الموجبة وبيطرد الـ OH الآن
+
+257
+00:22:46,800 --> 00:22:51,180
+هذا التفاعل مجموعة داخلة مجموعة طالعة شو بنسمي
+
+258
+00:22:51,180 --> 00:22:51,920
+احنا substitution
+
+259
+00:22:55,450 --> 00:22:58,630
+substitution هذا التفاعل double bond صارت single
+
+260
+00:22:58,630 --> 00:23:04,590
+bond شو كنا مسمينه addition الان بدلنا ال OH ب OR
+
+261
+00:23:04,590 --> 00:23:11,090
+شو صار موجود عندك على الكربون تنتين
+
+262
+00:23:11,090 --> 00:23:18,370
+OR داي إيثر هذا الأسيتال الكامل واضح هذا هو
+
+263
+00:23:18,370 --> 00:23:25,730
+الأسيتال الكامل اللي هو كربون بتحملTentenor و
+
+264
+00:23:25,730 --> 00:23:31,770
+التفاعل لتكوين الاسيتال يتم من خلال الهيمياسيتال
+
+265
+00:23:31,770 --> 00:23:36,870
+مع مزيد من الكحول فالتفاعل في هذه الحالة
+
+266
+00:23:36,870 --> 00:23:41,850
+substitution لاحظوا انا الان كم عائلة جديدة اتعرفت
+
+267
+00:23:41,850 --> 00:23:47,490
+عليها خدوهم بالتدريج Carbon Carbon Carbon Carbon
+
+268
+00:23:47,490 --> 00:23:48,990
+حاملة Tentenor
+
+269
+00:23:51,050 --> 00:23:57,350
+أه carbon حاملة OH و OR همي أسيتال carbon حاملة OR
+
+270
+00:23:57,350 --> 00:24:06,530
+و OR أسيتال شفتم كيف بالمقارنة hydrate أسيتال وهذا
+
+271
+00:24:06,530 --> 00:24:12,720
+اللي بين بينهيمي أسيتال هيدريت وهذا أسيتال وهذا
+
+272
+00:24:12,720 --> 00:24:18,320
+هيمي أسيتال الآن لو أجينا نسألكم الهيدريت كيف
+
+273
+00:24:18,320 --> 00:24:25,440
+بيتكون من إضافة الماء على ال الديهيد أو الكيتون
+
+274
+00:24:25,440 --> 00:24:29,300
+لحظوا الكلمات اللي باستعملها لما نفجر نسأل هيدريت
+
+275
+00:24:29,300 --> 00:24:30,260
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+276
+00:24:30,260 --> 00:24:31,960
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+277
+00:24:31,960 --> 00:24:32,140
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+278
+00:24:32,140 --> 00:24:32,140
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+279
+00:24:32,140 --> 00:24:34,240
+هيدريت هيدريت هيدريت هيدريت هيدby addition
+
+280
+00:24:34,240 --> 00:24:40,000
+reaction الـ hemacetal is formed also by addition
+
+281
+00:24:40,000 --> 00:24:43,760
+reaction على ال الديهيد والكيتون ال acetal
+
+282
+00:24:43,760 --> 00:24:51,340
+substitution reaction على ال hemacetal واضح ال
+
+283
+00:24:51,340 --> 00:24:55,480
+acetal هو عبارة عن عملية إبدال ال OH اللي موجودة
+
+284
+00:24:55,480 --> 00:25:00,120
+في ال hemacetal واضح هذه التفاعلات والعائلات
+
+285
+00:25:00,120 --> 00:25:01,740
+الجديدة والمسميات
+
+286
+00:25:07,510 --> 00:25:14,790
+الان هذا الحقيقة تفاعل الاسيتال والهيمياسيتال
+
+287
+00:25:14,790 --> 00:25:22,070
+تفاعل مهم جدا ممكن ايضا طالما المكونات تبعته كحول
+
+288
+00:25:22,070 --> 00:25:27,670
+بيهاجم على ايش الديهايد او كيتون الان لو انا
+
+289
+00:25:27,670 --> 00:25:31,150
+اتخيلت هي الديهايد او كيتون كحول هاجم عليه شو
+
+290
+00:25:31,150 --> 00:25:36,710
+الناتج؟Hemiacetal طيب السؤال لو ال الديهايد و ال
+
+291
+00:25:36,710 --> 00:25:40,930
+alcohol بنفس الجزئ يعني تخيلنا هيك جزئ سلسلة على
+
+292
+00:25:40,930 --> 00:25:46,330
+أحد أطرافها الديهايد و على الطرف التاني OH و إجت
+
+293
+00:25:46,330 --> 00:25:52,170
+فاعل هذه هاجمتها و السيطة بالبندق شو صارت OH هذا
+
+294
+00:25:52,170 --> 00:25:56,370
+التفاعل بنسميه Intermolecular ولا Intramolecular
+
+295
+00:25:57,570 --> 00:26:00,950
+Intramolecular شو يعني Intramolecular تفاعل بين
+
+296
+00:26:00,950 --> 00:26:06,430
+جزئين مفصولين تماما هذا جزء و هذا جزء جاء الجزئين
+
+297
+00:26:06,430 --> 00:26:10,150
+المفصولين تماما يتفاعلوا مع بعض هذا Intermolecular
+
+298
+00:26:10,150 --> 00:26:15,510
+بين جزئين مفصولين الان لو هذا الجزء و هذا الجزء
+
+299
+00:26:15,510 --> 00:26:21,430
+ممسكين بنفس السلسلة زي هذا المثال لاحظوا هذه سلسلة
+
+300
+00:26:21,430 --> 00:26:28,570
+واضح على أحد أطرافهاالديهايد وعلى الطرف الثاني
+
+301
+00:26:28,570 --> 00:26:32,790
+كحول فالجزئين اللي بدهم يتفاعلوا موجودين بنفس
+
+302
+00:26:32,790 --> 00:26:36,830
+المركب مش بمركبين مختلفين في هذه الحالة إذا
+
+303
+00:26:36,830 --> 00:26:40,730
+الجزئين اللي بتفاعلوا بنفس المركب على طول التفاعل
+
+304
+00:26:40,730 --> 00:26:47,380
+إيش أنا بأوصفه Intramolecular reactionفالـ
+
+305
+00:26:47,380 --> 00:26:51,120
+Intramolecular معناه ذلك أن الجزئين اللي بتفعلوا
+
+306
+00:26:51,120 --> 00:26:55,860
+بنفس الجزئ لكن الـ Intermolecular لأ جزئين مفصلين
+
+307
+00:26:55,860 --> 00:27:00,780
+و بيجوا يتفعلوا مع بعض واضح؟ هذا الأمر موجود كتير
+
+308
+00:27:00,780 --> 00:27:05,620
+الآن خلّيت الكحول و الالدهايد بنفس الجزئ التفاعل
+
+309
+00:27:05,620 --> 00:27:10,540
+أكيد إضافة الكحول بده يهاجم هنا و هاد السيطة بالـ
+
+310
+00:27:10,540 --> 00:27:16,270
+Bond O شو بده تصيرOH احنا قلنا في كل الأحوال دائما
+
+311
+00:27:16,270 --> 00:27:20,310
+ال C double bond O بتصير OH يمكن في كل الأمثلة
+
+312
+00:27:20,310 --> 00:27:25,690
+السابقة رسمناها بالأخضر و ال nucleophile هاجم بهذا
+
+313
+00:27:25,690 --> 00:27:32,110
+الشكل الآن هذا المركب اللي متكون عنده أيضا
+
+314
+00:27:32,110 --> 00:27:37,370
+hemacetal ولا لأ؟ أكيد لأن high carbon حاملة OH
+
+315
+00:27:41,220 --> 00:27:45,560
+هذا Hemacetal لكن التفاعل بهذه الحالة
+
+316
+00:27:45,560 --> 00:27:52,000
+Intramolecular reaction الان هذا التفاعل جزء من
+
+317
+00:27:52,000 --> 00:27:58,390
+أهميته انه في ال biochemistryإذا عندكم فكرة خفيفة
+
+318
+00:27:58,390 --> 00:28:03,190
+أو هيمر عليكم لما بناخد السكريات ال sugars احنا
+
+319
+00:28:03,190 --> 00:28:08,150
+قولنا ال sugars they are polyhydroxy aldehydes او
+
+320
+00:28:08,150 --> 00:28:12,890
+كيتون هى عبارة عن الديهيد او كيتون مع مجموعات
+
+321
+00:28:12,890 --> 00:28:17,510
+اوقاتش كبيرة الديهيد لحاله بيعملش sugar ومجموعات
+
+322
+00:28:17,510 --> 00:28:21,490
+اوقاتش كتيرة لحالها بتعملش ايش sugar فال sugar
+
+323
+00:28:21,490 --> 00:28:26,130
+عبارة عن ايشموجود فيه يا الديهايد يا كيتون
+
+324
+00:28:26,130 --> 00:28:31,290
+ومجموعات OH's الآن طالما وجد فيه على جهة معينة
+
+325
+00:28:31,290 --> 00:28:34,950
+الديهايد او كيتون هي C double bond او نتخيل هيك وع
+
+326
+00:28:34,950 --> 00:28:40,980
+الجهة التانيةأو أتشز ممكن هذه ال أو أتشز تسكر على
+
+327
+00:28:40,980 --> 00:28:45,600
+ال الديهايد أو ال كيتون أكيد بتعمل في هذه الحالة
+
+328
+00:28:45,600 --> 00:28:49,520
+hemeacetal بس لما تسكر بدل ما ال sugar كان عامل
+
+329
+00:28:49,520 --> 00:28:54,480
+سلسلة بهذا الشكل ال chain بيصير إيش in the cyclic
+
+330
+00:28:54,480 --> 00:28:58,440
+form كل كمار عليكوا أن السكر بيكون في ال chain
+
+331
+00:28:58,440 --> 00:29:06,430
+formكسلسلة و بيكون بـ Cyclic Form كحلقة الآن عملية
+
+332
+00:29:06,430 --> 00:29:12,090
+إغلاق السكر هي عملية تفاعل Hemacetal Formation
+
+333
+00:29:12,090 --> 00:29:17,890
+Hemacetal Formation هاي السكر اللي مسكر الجلوكوز
+
+334
+00:29:17,890 --> 00:29:22,650
+هذا منظر الجلوكوز اللي مسكر لاحظوا هذه ال carbon
+
+335
+00:29:22,650 --> 00:29:32,570
+تحديدا اللي هنا هي فيها OHو OR اللى هو alcohol و
+
+336
+00:29:32,570 --> 00:29:36,910
+ether طب لو قولنا لأى حد اذكرنا كيف هذه كانت قبل
+
+337
+00:29:36,910 --> 00:29:43,250
+التفاعل قبل ما يسكر كانت هذه C double bond O وكانت
+
+338
+00:29:43,250 --> 00:29:52,240
+هذه OH وماكنش فيه رابطةكانت هذه C double bond O L
+
+339
+00:29:52,240 --> 00:29:57,780
+D I و هذه O H فهذه ال O H سكرت هنا و C double bond
+
+340
+00:29:57,780 --> 00:30:05,240
+O صارتOH بهذا الشكل فلو اجينا سألناكوا سؤال
+
+341
+00:30:05,240 --> 00:30:10,260
+وقلنالكم cyclic glucose انتبهوا معايا هاي ال
+
+342
+00:30:10,260 --> 00:30:14,480
+glucose اللي مسكرة تكونوا فاهمين العائلات كويسة
+
+343
+00:30:14,480 --> 00:30:20,420
+cyclic glucose is a hydrate يعني في تنتين OH على
+
+344
+00:30:20,420 --> 00:30:21,140
+الكربون
+
+345
+00:30:25,890 --> 00:30:30,950
+cyclic glucose is a hydrate no cyclic glucose is
+
+346
+00:30:30,950 --> 00:30:38,450
+an acetal في تنتين OR برضه false cyclic glucose is
+
+347
+00:30:38,450 --> 00:30:48,340
+a hemacetal في OH و OR واضحة الفكرةالان ممكن نسأل
+
+348
+00:30:48,340 --> 00:30:54,180
+السؤال بطريقة تانية Cyclic glucose is formed by a
+
+349
+00:30:54,180 --> 00:30:55,960
+substitution reaction
+
+350
+00:30:58,930 --> 00:31:03,610
+by an addition reaction شوف كيف اللي بيفهم شغلة
+
+351
+00:31:03,610 --> 00:31:07,770
+بيحس انه ممكن نسأل عن الشغلة بقالف طريق أنا مش
+
+352
+00:31:07,770 --> 00:31:10,610
+الفكرة ان اخوفكم من الأسئلة و الانتحانات بقدر ما
+
+353
+00:31:10,610 --> 00:31:16,130
+اني بركز المعلومة عندكم ان هذه فعلا كانت C double
+
+354
+00:31:16,130 --> 00:31:20,430
+bond O و هذه فعلا كانت OH هذا alcohol و هذا
+
+355
+00:31:20,430 --> 00:31:23,750
+aldehyde الآن ال alcohol و ال aldehyde بيتفاعلوا
+
+356
+00:31:23,750 --> 00:31:31,560
+تفاعل ايش اضافة بكونه hemiacetalواضح؟ الآن بعد ما
+
+357
+00:31:31,560 --> 00:31:37,160
+اتكون الـ hemacetal هذا وصار هنا في OR و OH ممكن
+
+358
+00:31:37,160 --> 00:31:44,040
+يصير تفاعل تاني تبدل في ال OH ل OR مع كحول تاني
+
+359
+00:31:44,040 --> 00:31:48,260
+خارجي يعني افترضوا ناس جابوا ميثانول وفعلوا مع هذا
+
+360
+00:31:48,260 --> 00:31:55,530
+شو هيعمل الميثانول؟هيشيل ال OH يخليها OR صار عندكم
+
+361
+00:31:55,530 --> 00:32:01,890
+OR OR أسيتال بس ب substitution reaction تاني واضح
+
+362
+00:32:01,890 --> 00:32:06,350
+انما ال cyclic glucose في نص الطريق هو عبارة عن
+
+363
+00:32:06,350 --> 00:32:11,500
+ايش؟Hemiacetal Cyclic Glucose is Hemiacetal ممكن
+
+364
+00:32:11,500 --> 00:32:15,920
+تحويله ل Acetal بالتفاعل مع الكحول أكيد لأن احنا
+
+365
+00:32:15,920 --> 00:32:20,820
+قلنا التفاعل ع مرحلتين إضافة ثم إبدال أنا لما وصلت
+
+366
+00:32:20,820 --> 00:32:24,900
+ل Hemacetal عملت الإضافة الآن إذا الإنسان بيجيب
+
+367
+00:32:24,900 --> 00:32:30,860
+كحول و حامض و بيسخنه ممكن يعمل إيش الإبدال و يحوله
+
+368
+00:32:30,860 --> 00:32:37,360
+إلى Acetal كاملهنا في عندى على هذه النقطة كمان
+
+369
+00:32:37,360 --> 00:32:46,320
+مثال جميل انه انا جبت ال Acetone كيتون مع Ethylene
+
+370
+00:32:46,320 --> 00:32:51,740
+Glycol او اللى سميناه Ethanediol هذا المركب كام OH
+
+371
+00:32:51,740 --> 00:32:58,200
+فيهTintin يعني كأنه هذا Dialcohol الان لما فعلنا
+
+372
+00:32:58,200 --> 00:33:03,200
+اعطانا هذا المركب المغلق يمكن واحدة تقول طب كيف تم
+
+373
+00:33:03,200 --> 00:33:08,600
+هذا التفاعل؟ بنقول بهدوء ممكن نفهم كيف تم الان
+
+374
+00:33:08,600 --> 00:33:13,540
+نتعامل مع هذا كيتون و مع هذا الكهول كيف الكهول
+
+375
+00:33:13,540 --> 00:33:17,700
+بتفاعل على الكيتون او على الديهايد بال addition
+
+376
+00:33:17,700 --> 00:33:24,310
+هذه بتيجي تضيف هنا و هذه بتصيرOH إذا لو قلنا شو
+
+377
+00:33:24,310 --> 00:33:32,770
+الناتج اللي في هذه الحالة بيصير C OH CH3 CH3 هذا
+
+378
+00:33:32,770 --> 00:33:37,590
+الجزء اللي كان أسيتون والجزء التاني هو عبارة عن O
+
+379
+00:33:37,590 --> 00:33:48,890
+CH2 CH2 OH هاي كحول اتفاعل مع كيتون ال C double
+
+380
+00:33:48,890 --> 00:33:54,500
+bond O صارتOH والكحول اتفاعل هنا الان الكحول نفسه
+
+381
+00:33:54,500 --> 00:34:00,220
+في داخله OH تاني يعني كأن الكحول كحولين في بعض في
+
+382
+00:34:00,220 --> 00:34:04,740
+مجموعتين OH هذا المركب اللي هنا carbon حاملة OH و
+
+383
+00:34:04,740 --> 00:34:10,660
+OR شو عبارة عن ايش Himacetal الان ممكن يعمل كمان
+
+384
+00:34:10,660 --> 00:34:16,680
+تفاعل ان هذه تهاجم هنا و تحل محل هذه ابدال
+
+385
+00:34:17,800 --> 00:34:21,920
+و انت بتطلع عندى هذا المركب لحظة هذا المركب carbon
+
+386
+00:34:21,920 --> 00:34:27,680
+حاملة OR و OR اذا هذا عبارة عن ايش
+
+387
+00:34:30,910 --> 00:34:36,990
+Hemiacetal لاحظوا هنا اعملت التفاعل على مرتين لكن
+
+388
+00:34:36,990 --> 00:34:42,970
+مش من كحولين مفصلين لأ الكحولين موجودين بإيش؟ بنفس
+
+389
+00:34:42,970 --> 00:34:47,330
+الجزء نفس الجزء فيه تن تن و اتش يعني كأنه الجزء زي
+
+390
+00:34:47,330 --> 00:34:53,410
+ما بيقولوا اليوم في الدعايات إيش؟ two in oneطالما
+
+391
+00:34:53,410 --> 00:34:58,470
+في اتنين OH اذا صار عبارة عن كحولين في نفس الجزء
+
+392
+00:34:58,470 --> 00:35:03,710
+طالما مجمعتين OH الكحول OH هذا في OH OH صار كحولين
+
+393
+00:35:03,710 --> 00:35:09,650
+اتفاعل في المرة الأولى بالاضافة و في المرة الثانية
+
+394
+00:35:09,650 --> 00:35:15,380
+بالابدالةشوفنا كيف ادول التفاعلين تموا addition
+
+395
+00:35:15,380 --> 00:35:19,640
+followed by substitution الان هذا المركب اتجه من
+
+396
+00:35:19,640 --> 00:35:23,360
+الاسيتون و من الاثيلين جليكول عشان يسموه اسيتون
+
+397
+00:35:23,360 --> 00:35:28,820
+اثيلين جليكول لاحظوا ايش استعمله اسيتال منطق
+
+398
+00:35:28,820 --> 00:35:32,480
+اسيتال لانه OR و OR اسيتال
+
+399
+00:35:42,600 --> 00:35:48,900
+الان من التفاعلات انه نستعمل نيكليوفايل مجموعة ال
+
+400
+00:35:48,900 --> 00:35:52,680
+CNI و بتذكروا احنا لما أخدنا ال CNI تقولنا بتتفاعل
+
+401
+00:35:52,680 --> 00:35:56,460
+من اي طرف من الكربون ولا من ال نيتروجين من الكربون
+
+402
+00:35:56,460 --> 00:36:01,200
+كل اللي مطلوب انه ال CN تهاجم هنا و الصيدة بال
+
+403
+00:36:01,200 --> 00:36:06,580
+bond O تصير OH الان صار عندى عائلة جديدة على
+
+404
+00:36:06,580 --> 00:36:13,040
+الكربون ايش المجمعتين اللي موجودين CNN و OHو OH
+
+405
+00:36:13,040 --> 00:36:20,700
+لاحظوا C و تلتين OH هيدريت OH و OR هيمي أسيتال OR
+
+406
+00:36:20,700 --> 00:36:27,340
+و OR أسيتال الان OH و CNN بسميها سيانو هيدرين
+
+407
+00:36:27,340 --> 00:36:37,760
+بسميها سيانو هيدرين واضح سيانو هيدرين الان
+
+408
+00:36:39,440 --> 00:36:43,880
+لو عملنا التفاعل مع الاسيتالديهيد هذا المركب شو
+
+409
+00:36:43,880 --> 00:36:51,320
+هسميه اسيتالديهيد سيانوهيدرين لو عملت التفاعل مع
+
+410
+00:36:51,320 --> 00:36:57,100
+الاسيتون هذا المركب ايش هسميه اسيتون هاي جزء
+
+411
+00:36:57,100 --> 00:37:05,520
+الاسيتون مش الاسيتون عبارة عن CH3CCH3 بدون ال
+
+412
+00:37:05,520 --> 00:37:10,950
+oxygen اسيتونCyanohedron لو عملتم مع الـ
+
+413
+00:37:10,950 --> 00:37:16,250
+Cyclohexanone هذي الـ C double bond O إيش هتصير؟
+
+414
+00:37:16,250 --> 00:37:21,650
+OH وهي الـ Cl شو هسميه؟ Cyclohexanone
+
+415
+00:37:21,650 --> 00:37:23,470
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+416
+00:37:23,470 --> 00:37:23,530
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+417
+00:37:23,530 --> 00:37:23,810
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+418
+00:37:23,810 --> 00:37:24,510
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+419
+00:37:24,510 --> 00:37:26,930
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+420
+00:37:26,930 --> 00:37:26,930
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+421
+00:37:26,930 --> 00:37:27,010
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+422
+00:37:27,010 --> 00:37:31,690
+Cyclohexanone
+
+423
+00:37:31,690 --> 00:37:37,790
+Cyclohexanone Cyclohexanone
+
+424
+00:37:40,220 --> 00:37:47,620
+الدهايد بنزالدهايد سيانو هيدرل يعني لو قلنا لأي
+
+425
+00:37:47,620 --> 00:37:53,440
+واحدة أرسمينا بنزالدهايد سيانو هيدرل في الامتحان
+
+426
+00:37:53,440 --> 00:37:58,360
+بدا تيجي تفكر تتخيل بسهولة ماتاخدش وقت منكوا
+
+427
+00:37:58,360 --> 00:38:05,530
+ببساطة هاي ال بنزالدهايد صح ولا لألازم في الأصل
+
+428
+00:38:05,530 --> 00:38:09,390
+تكون عارفة الـ Benzaldehyde مجرد ما نقولها سيانو
+
+429
+00:38:09,390 --> 00:38:17,490
+هيدرين الـ C بابل بوند O OH OHIJNQCN مش عملية صعبة
+
+430
+00:38:17,490 --> 00:38:23,090
+Benzaldehyde cyanohydrin واضح الفكرة؟ لاحظوا أنا
+
+431
+00:38:23,090 --> 00:38:27,650
+كاتب له common name نفس
+
+432
+00:38:27,650 --> 00:38:30,830
+الـ Benzaldehyde cyanohydrin له common name
+
+433
+00:38:30,830 --> 00:38:33,330
+Manbilonitride
+
+434
+00:38:34,290 --> 00:38:42,750
+mandilo mandel بالالماني يعني لوز انتوا بتذاكرين
+
+435
+00:38:42,750 --> 00:38:46,750
+قبل شوية لما أخدنا ال benzaldehyde قولنا oil of
+
+436
+00:38:46,750 --> 00:38:54,170
+almond اللوز بالانجليزي بالالماني mandel ومن هنا
+
+437
+00:38:54,170 --> 00:38:58,950
+استعمل mandilo nitral mandel من اللوز يعني كتير من
+
+438
+00:38:58,950 --> 00:39:04,150
+ال common name علاقة في إيشفي أصل المركب من أي
+
+439
+00:39:04,150 --> 00:39:08,130
+منطقة نباتية اشتهر ان هذا المركب انفصل
+
+440
+00:39:08,130 --> 00:39:12,990
+فالمنديلونيترال هو ال benzaldehyde cyanohydrin
+
+441
+00:39:12,990 --> 00:39:14,370
+واضح الفكرة؟
+
+442
+00:39:20,340 --> 00:39:24,120
+اتخيلوا عاد كيف الطالب لما بيبعد عن الكلام احنا
+
+443
+00:39:24,120 --> 00:39:28,320
+مرة جيبناله سؤال في الامتحان ارسم العائلة العامة و
+
+444
+00:39:28,320 --> 00:39:33,940
+كتبناله Hydrate, Hemacetal, Acetal وCyanohydrin
+
+445
+00:39:33,940 --> 00:39:37,420
+انا بدي احط هدوله و هنا يعمل شرط اما يكتبليش اشي
+
+446
+00:39:37,420 --> 00:39:42,240
+يعني في مجبوعتين صعبة ولا سهلة؟ سهلة جدا .. سهلة
+
+447
+00:39:42,240 --> 00:39:45,020
+جدا .. الآن
+
+448
+00:39:46,660 --> 00:39:53,640
+بنجي لنيكليوفايل جديد هذا النيكليوفايل الجديد هو H
+
+449
+00:39:53,640 --> 00:40:01,080
+- متذكرين انتوا انه احنا لما حكينا عن الهيدروجين،
+
+450
+00:40:01,080 --> 00:40:07,580
+قولنا الهيدروجين بيدا تمر علينا بكم شكل؟ تلت أشكال
+
+451
+00:40:07,580 --> 00:40:10,700
+H plus وH
+
+452
+00:40:14,320 --> 00:40:19,580
+و أعطناهم أسماء الـ H بلس شو قلنا عنها البروتون
+
+453
+00:40:19,580 --> 00:40:25,480
+اللي بيفقد الحامض و الـ H هيدروجين أتم الـ H minus
+
+454
+00:40:25,480 --> 00:40:30,880
+هيدرايد أنيون الان مين في هدولة التلاتة
+
+455
+00:40:30,880 --> 00:40:38,080
+نيوكليوفاين الهيدرايد أنيون طيب انتهت الكلام طالما
+
+456
+00:40:38,080 --> 00:40:44,480
+الهيدرايد أنيوناليوكليوفايل لو أخدت الديهيد زي هذا
+
+457
+00:40:44,480 --> 00:40:48,040
+خلّيني أقول ال Acetaldehyde وهي ال H وحملة ال
+
+458
+00:40:48,040 --> 00:40:52,860
+minus وقلتلكوا أكمل المعادلة ال hydride بدو يتفعل
+
+459
+00:40:52,860 --> 00:40:59,320
+مع هذا شو هيعمل ال C double bond O هتصير O H هي
+
+460
+00:40:59,320 --> 00:41:03,480
+باللون الأخضر واليوكليوفايل بهذه الحالة هو عبارة
+
+461
+00:41:03,480 --> 00:41:12,270
+عن إيش ال Hما العائلة الجديدة اللتي تكونت هنا؟كحول
+
+462
+00:41:12,270 --> 00:41:17,650
+هذه عملية الاختزال الار بيصير السؤال هو بالدنيا
+
+463
+00:41:17,650 --> 00:41:23,870
+بينباع H- لحاله؟ لأ بينباع على شكل المراكبات
+
+464
+00:41:23,870 --> 00:41:29,970
+المراكبات اللي بتكون مصدر للhydride anion موجود
+
+465
+00:41:29,970 --> 00:41:33,930
+منها وتستعمل كعوامل مختزلة لحظوا هذه العملية
+
+466
+00:41:33,930 --> 00:41:38,410
+اختزال لأن C double bond O صارت OH واحدة نقص في
+
+467
+00:41:38,410 --> 00:41:44,610
+محتوىالأكسوجين وزيادة في محتوى الهيدروجين أنا زيدت
+
+468
+00:41:44,610 --> 00:41:49,430
+هنا H وزيدت هنا H هايهم تنتين هذا الاختزال بعينه
+
+469
+00:41:49,430 --> 00:41:54,690
+مظبوط ولا لأ الآن العوامل المختزلة عادة بتكون
+
+470
+00:41:54,690 --> 00:41:58,410
+هيدرايد أو ممكن الإنسان يعملها بإضافة الهيدروجين
+
+471
+00:41:58,410 --> 00:42:02,120
+هنا إحنا إيش اللي بنستعمله الهيدرايدلحظوا من
+
+472
+00:42:02,120 --> 00:42:06,320
+الهيدرايتز اللي مشهورة جدا هذا المركّب الليثيام
+
+473
+00:42:06,320 --> 00:42:12,340
+والألمنيوم اللي متصل ب 4H- لحظوا الألمنيوم بوضعه
+
+474
+00:42:12,340 --> 00:42:18,880
+الطبيعي بيكون ايش تلاتة موجة حطوا عليه 4H- كل ال
+
+475
+00:42:18,880 --> 00:42:23,920
+ايون شو هيصفاه minus عشان يطلع الجزية متعادلة
+
+476
+00:42:23,920 --> 00:42:31,420
+بحطله lithium plusهذا بيصير Lithium Tetrahydride
+
+477
+00:42:31,420 --> 00:42:39,180
+Aluminate طبعا الات هي نهاية إيش؟ الايون السالب مش
+
+478
+00:42:39,180 --> 00:42:43,440
+أخدنا احنا الايونات السالبة سولفات، كربونات،
+
+479
+00:42:43,440 --> 00:42:50,230
+نيترات، أسيتات، الآن هنا قولنا إيش؟ Aluminateكل
+
+480
+00:42:50,230 --> 00:42:57,290
+عمره بنقول سلفيت SO4 minus minus نيتريت NO3 minus
+
+481
+00:42:57,290 --> 00:43:03,170
+فال eight نهاية ال ايش ال ايون السالب الان هذا
+
+482
+00:43:03,170 --> 00:43:07,050
+الجزء متعادل لان عندي ليثيام plus والالمنيوم تلاتة
+
+483
+00:43:07,050 --> 00:43:12,770
+plus هاي أربعة موجب وال H أربعة minus صف الجزء كله
+
+484
+00:43:12,770 --> 00:43:18,190
+ايش ليثيام تترا هيدرايدو ألمينيت أو هذا من البورون
+
+485
+00:43:18,950 --> 00:43:26,130
+Sodium Tetrahydride من البرون بوريت مش من البروم
+
+486
+00:43:26,130 --> 00:43:31,350
+البرون لما تمشوا في أول الجدول الدوري العنصر
+
+487
+00:43:31,350 --> 00:43:35,890
+الخامس يعني تطلعوا على عناصر الجدول الدوري H بعدين
+
+488
+00:43:35,890 --> 00:43:41,590
+helium بعدين lithium بعدين beryllium بعدين boron
+
+489
+00:43:41,590 --> 00:43:48,520
+واضح؟ اه ال boronSodium tetrahydride borate الان
+
+490
+00:43:48,520 --> 00:43:52,160
+هذول الحقيقة بياخدوا كمان اسماء تانية لو سمعتهم
+
+491
+00:43:52,160 --> 00:43:55,700
+بأي اسمين هذول من أشهر العوامل المختز ل ال
+
+492
+00:43:55,700 --> 00:44:02,140
+hydrides هم ببساطة مصدر ل إيش ل H minus يعني احنا
+
+493
+00:44:02,140 --> 00:44:06,840
+بنفهمه مصدر ل H minus هذا بيسموه ال lithium
+
+494
+00:44:06,840 --> 00:44:13,460
+tetrahydride aluminate بيسموه lithium aluminum
+
+495
+00:44:13,460 --> 00:44:20,740
+hydrideالومينوم هايدرايد يعني نفسه ممكن تلاقوه تحت
+
+496
+00:44:20,740 --> 00:44:24,840
+اسم ليثيام ألومينوم هايدرايد أو ليثيام تيترا
+
+497
+00:44:24,840 --> 00:44:29,260
+هايدرايد و ألومينيت وهذا بيسموه صوديوم بورو
+
+498
+00:44:29,260 --> 00:44:35,230
+هايدرايد مش بورونBorohydride فإذا سمعتوا Sodium
+
+499
+00:44:35,230 --> 00:44:38,770
+Borohydride أو Sodium Tetrahydride و Borate نفس
+
+500
+00:44:38,770 --> 00:44:43,330
+الاسم Lithium Tetrahydride و Aluminate أو Lithium
+
+501
+00:44:43,330 --> 00:44:47,690
+Aluminum Hydride نفس الاسم و مرات كتير حتى الاسم
+
+502
+00:44:47,690 --> 00:44:52,530
+هذا Sodium Borohydride و عادة مش هيكونوا عاملينه
+
+503
+00:44:52,530 --> 00:44:57,310
+زيك هتلاعظوا على السهم مكتوب عندكم NABH4
+
+504
+00:44:58,940 --> 00:45:05,980
+وهنا هتلاحظوا Lithium Aluminum H4 اذا شفتوا هذا او
+
+505
+00:45:05,980 --> 00:45:09,780
+هذا هذا Sodium Borohydride Lithium Aluminum
+
+506
+00:45:09,780 --> 00:45:16,560
+Hydride شوفوا مثلها Sodium Borohydride Lithium
+
+507
+00:45:16,560 --> 00:45:21,220
+Aluminum Hydride هدوله الشرعوه المختزلة هم في
+
+508
+00:45:21,220 --> 00:45:27,990
+النهاية مصدر لإيش؟لل H- الان ال H- لما هاجم على ال
+
+509
+00:45:27,990 --> 00:45:34,850
+aldehyde عملوا ايش؟ كحول وهذه عملية الاختزال عكس
+
+510
+00:45:34,850 --> 00:45:40,150
+عملية ايش؟ الاكسادة هذه عملية الاختزال عكس عملية
+
+511
+00:45:40,150 --> 00:45:47,190
+الاكسادة هي reducing agents طبعا لو ال H- هاجم على
+
+512
+00:45:47,190 --> 00:45:53,490
+كيتون هيعملوا ايش؟secondary alcohol اذا انتبهوا
+
+513
+00:45:53,490 --> 00:45:59,030
+معي جيدا انه لما الهجوم تم على ال الديهايد عادي
+
+514
+00:45:59,030 --> 00:46:06,550
+اتكول اه اذا هل جيتها بنصير نكتب reduction عشان
+
+515
+00:46:06,550 --> 00:46:11,950
+تكون واضحة الأمور معاكم قبل الديهايدs produces
+
+516
+00:46:11,950 --> 00:46:19,070
+primary alcoholreduction of aldehydes produces
+
+517
+00:46:19,070 --> 00:46:23,950
+primary alcohols الان تحتها هيصير reduction of
+
+518
+00:46:23,950 --> 00:46:28,890
+كيتون ايش
+
+519
+00:46:28,890 --> 00:46:35,050
+produces secondary alcohols هو كل درسنا aldehydes
+
+520
+00:46:35,050 --> 00:46:40,240
+او كيتون ولا في غيرهم؟أذا بدنا نكون عارفين ان ال
+
+521
+00:46:40,240 --> 00:46:45,240
+الديهايد لما بنعمله reduction بالهيدرايد بده يصير
+
+522
+00:46:45,240 --> 00:46:50,080
+عنده primary alcohol و ال ketone لما بنعمله
+
+523
+00:46:50,080 --> 00:46:54,240
+reduction بال الديهايد بده يصير عنده secondary
+
+524
+00:46:54,240 --> 00:46:58,940
+alcohol لاحظوا هذا الكلام بفيدكم سواء بجمل صح و
+
+525
+00:46:58,940 --> 00:47:03,820
+غلط بأكمل معادلة او حتى لو احنا سألناكوا سؤال how
+
+526
+00:47:03,820 --> 00:47:09,210
+can you prepare the following compoundواضح؟ لما
+
+527
+00:47:09,210 --> 00:47:12,610
+تشوفوا أن الناتج اللي عندكم primary alcohol إذا
+
+528
+00:47:12,610 --> 00:47:16,530
+بتقدروا تفكروا أنه ممكن يكون إيجا من وين لما
+
+529
+00:47:16,530 --> 00:47:19,930
+تشوفوا الناتج اللي عندكم secondary alcohol إذا
+
+530
+00:47:19,930 --> 00:47:25,430
+ممكن يكون إيجا من وين من كيتون واضح الفكرة؟ بنقف
+
+531
+00:47:25,430 --> 00:47:29,510
+عند هذه النقطة المرة القادمة إن شاء الله بنحكي عن
+
+532
+00:47:29,510 --> 00:47:34,690
+تفاعل الديهيدس والكيتون مع متفاعل اسمه green yard
+
+533
+00:47:34,690 --> 00:47:39,740
+reagent عمرنا حكينا عنه؟بنعرفه المرة الجاية وبنشوف
+
+534
+00:47:39,740 --> 00:47:44,440
+كيف بتفاعل ال الديهيد والكيتون مع ال green yard
+
+535
+00:47:44,440 --> 00:47:46,220
+reagent شكرا
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/di-xbM-HbNU_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/di-xbM-HbNU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..113e6db8580a7a6a78dd7c4cdb91328115f59e55
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/di-xbM-HbNU_raw.srt
@@ -0,0 +1,2096 @@
+1
+00:00:18,700 --> 00:00:22,900
+بسم الله الرحمن الرحيم، اليوم ان شاء الله هنبتدأ
+
+2
+00:00:22,900 --> 00:00:28,300
+الفصل الأخير في ال course اللي بأمل أن نكون يعني
+
+3
+00:00:28,300 --> 00:00:32,740
+استفدنا منه واستمتعنا فيه على مدى ثلاث أو أربع
+
+4
+00:00:32,740 --> 00:00:38,220
+شهور course الكيمياء الأضوية العامة والكيمياء يعني
+
+5
+00:00:38,220 --> 00:00:43,140
+مقدمة في الكيمياء الحيوية العامةالفصل هذا بعنوان
+
+6
+00:00:43,140 --> 00:00:49,360
+amino acids, peptides and proteins، طبعا هو مش تلت
+
+7
+00:00:49,360 --> 00:00:56,860
+عنوين، لأهي ال amino acids الأحماض الأمينية الوحدة
+
+8
+00:00:56,860 --> 00:01:02,640
+البسيطة إذا اتحد عندي عدد قليل من ال amino acids
+
+9
+00:01:02,640 --> 00:01:07,080
+بيعملوا ال peptides يعني أربعة، خمسة، عشرة، خمس،
+
+10
+00:01:07,080 --> 00:01:12,280
+تعش هدولة بيعملوا ال peptides الآن إذا صاروا بال
+
+11
+00:01:12,280 --> 00:01:17,880
+آلاف وأحيانا بعشرات الآلاف بصير الجزء كبير جدا
+
+12
+00:01:17,880 --> 00:01:23,530
+بنسمي إيش ال proteinفالبروتين الان كبير جدا لو بده
+
+13
+00:01:23,530 --> 00:01:28,690
+يتكسر بالعكس هيتكسر لpeptides و ال peptides لو
+
+14
+00:01:28,690 --> 00:01:34,670
+بدها تتكسر هتتكسر ل amino acids فالوحدة الأساسية
+
+15
+00:01:34,670 --> 00:01:42,480
+هتكون ال aminoو لذلك أمر طبيعي جدا ان نبدأ الفصل
+
+16
+00:01:42,480 --> 00:01:47,900
+هذا ان نتعرف على ال amino acids معنى amino acids
+
+17
+00:01:47,900 --> 00:01:54,220
+أحماض عضوية عادية لكن فيها مجموعة الأمين بشكل عام
+
+18
+00:01:54,220 --> 00:02:01,940
+مجموعة ال NH2 الآن من الناحية النظرية البحثة لو
+
+19
+00:02:01,940 --> 00:02:08,870
+انا بحكي عن حامض عضويوفي مجموعة امين معنا ذلك بقدر
+
+20
+00:02:08,870 --> 00:02:14,250
+اتوقع ان يكون عندى عدد لا نهائى من ال amino acids
+
+21
+00:02:14,250 --> 00:02:20,070
+واضح يعني لو بدى اقول قداش العدد النظري المتوقع من
+
+22
+00:02:20,070 --> 00:02:23,910
+ال amino acids لما انا اجي اقول هاي مجموعة الحامض
+
+23
+00:02:23,910 --> 00:02:29,470
+سيضة بال bond O OH و بعدين احط هنا carbons
+
+24
+00:02:31,380 --> 00:02:36,140
+الان حسب ما يكون في عندى و الله اذا في هنا مجموعة
+
+25
+00:02:36,140 --> 00:02:40,920
+amino ممكن يكون هنا مجموعة amino هنا هنا لاحظوا
+
+26
+00:02:40,920 --> 00:02:44,000
+معنى بتيجي نقطة كتير مهمه ان انا لما بحط amino
+
+27
+00:02:44,000 --> 00:02:50,200
+بكون في عندي كمان R groups واضح فنظريا ال amino
+
+28
+00:02:50,200 --> 00:02:56,730
+acids اكترالان بنجيب نتطلع وين مجموعة الأمين
+
+29
+00:02:56,730 --> 00:03:02,030
+مجموعة ال N H2 والله إذا كانت هذه مجموعة الأمين
+
+30
+00:03:02,030 --> 00:03:06,470
+على أول carbon بعد ال C double bond O احنا اتعلمنا
+
+31
+00:03:06,470 --> 00:03:11,090
+ان هذا ال carbon هي ال alpha carbon لكن بالتأكيد
+
+32
+00:03:11,090 --> 00:03:14,410
+ممكن ماتكونش على أول carbon ممكن تكون على ثاني
+
+33
+00:03:14,410 --> 00:03:20,940
+carbonوأجد عن إيش هنحكي؟ Beta Amino Acids على اللي
+
+34
+00:03:20,940 --> 00:03:26,940
+بعدها Gamma Delta فال Amino Acids ال Amino Acids
+
+35
+00:03:26,940 --> 00:03:33,780
+بهذا المنطق اكتار الآن اللي موجودين في البروتينات
+
+36
+00:03:41,580 --> 00:03:45,360
+اللي موجودين في البروتينات تحديدا هم ال alpha
+
+37
+00:03:45,360 --> 00:03:50,400
+amino acids يعني اللي فيهم مجموعة الأمين على ال
+
+38
+00:03:50,400 --> 00:03:54,000
+carbon alpha و احنا سبق عرفنا ال carbon alpha بال
+
+39
+00:03:54,000 --> 00:03:57,220
+acids و بال aldehydes و بال ketones قلنا هي ال
+
+40
+00:03:57,220 --> 00:04:01,400
+carbon المجاورة لل seed of the bond O لو كنا بنعد
+
+41
+00:04:01,400 --> 00:04:05,280
+بال ayobac بتكون ال alpha carbon هي ال carbon رقم
+
+42
+00:04:05,280 --> 00:04:09,320
+اتنين لأن احنا بنعد في ال ayobac من ال seed of the
+
+43
+00:04:09,320 --> 00:04:15,360
+bond Oيعني فال amino group موجودة على ال carbon
+
+44
+00:04:15,360 --> 00:04:19,800
+رقم اتنين او على ال carbon الفة هذا الكلام في وين؟
+
+45
+00:04:19,800 --> 00:04:23,940
+في ال amino acids اللي موجودين في البروتينات لكن
+
+46
+00:04:23,940 --> 00:04:30,660
+لو قلنا لطالب في الامتحان الدروق general structure
+
+47
+00:04:30,660 --> 00:04:37,620
+for a beta amino acidهذا جيبنا سؤال مرة اوكي هي
+
+48
+00:04:37,620 --> 00:04:43,080
+انها C double bond O OH بنمشي بهذا الشكل هي alpha
+
+49
+00:04:43,080 --> 00:04:50,820
+هي beta اذا نحط ال amino group على ال carbon beta
+
+50
+00:04:50,820 --> 00:04:54,740
+هذا beta amino acid لو قلنا لغاها مابدوا يحطوا على
+
+51
+00:04:54,740 --> 00:04:59,400
+اللي بعدها واضح لكن اللي موجودين في البروتينات اي
+
+52
+00:04:59,400 --> 00:05:05,440
+نوع ال alpha amino acidsواضح؟ زي ما حكينا احنا ان
+
+53
+00:05:05,440 --> 00:05:10,080
+ال peptides عدت amino acids مع بعض و ال proteins
+
+54
+00:05:10,080 --> 00:05:16,040
+many amino acids مع بعض الان لما نيجي نكسر ال
+
+55
+00:05:16,040 --> 00:05:18,740
+protein زي ما قلنا ممكن يعطينا peptide و ال
+
+56
+00:05:18,740 --> 00:05:22,720
+peptide ممكن يكسره الوحدات الاولية هنصف بال ايش؟
+
+57
+00:05:22,720 --> 00:05:26,700
+بال amino acids الان هذه ال amino acids ايش
+
+58
+00:05:26,700 --> 00:05:30,960
+مواصفاتها؟ المواصفة الاولى ان كلهم الف amino acids
+
+59
+00:05:31,860 --> 00:05:36,960
+الشغل التاني ان ال amino acids اللي بيطلعوا عندنا
+
+60
+00:05:36,960 --> 00:05:41,840
+they are optically active يعني فيهم chiral center
+
+61
+00:05:41,840 --> 00:05:46,140
+ما عدا واحد بيكونوا فيه المجموعتين زي بعض يعني
+
+62
+00:05:46,140 --> 00:05:50,480
+مافيش فيه أربع مجموعات مختلفة هذا الواحد اللي
+
+63
+00:05:50,480 --> 00:05:54,940
+هنتعرف عليه هو ال glycine فباقي ال amino acids
+
+64
+00:05:54,940 --> 00:05:59,880
+كلهم they areoptically active they contain chiral
+
+65
+00:05:59,880 --> 00:06:05,380
+centers فيهم chiral centers الآن بيجينا شغلة طالما
+
+66
+00:06:05,380 --> 00:06:09,380
+بدنا نقول chiral center متذكرين لما اتكلمنا عن ال
+
+67
+00:06:09,380 --> 00:06:13,620
+sugars واستبدلنا المصطلح يعني في ال biochemistry
+
+68
+00:06:13,620 --> 00:06:19,940
+ال R و ال S ب D و L فلما اتكلمنا عن ال sugars احنا
+
+69
+00:06:19,940 --> 00:06:25,630
+اتفقنا ان نحط اعلى مجموعة للأعلى اللي هي مجموعةالـ
+
+70
+00:06:25,630 --> 00:06:29,650
+aldehyde بعدين ال sugars بيميزها على الكربون اللى
+
+71
+00:06:29,650 --> 00:06:33,630
+باقى ده H و OH و بعدين بنحط rest of the molecule
+
+72
+00:06:33,630 --> 00:06:40,090
+الآن إذا حطينا ال OH على اليمين كنا نقول في عندنا
+
+73
+00:06:40,090 --> 00:06:45,150
+D و إذا حطينا على الشمال كنا نقول في عندنا L الآن
+
+74
+00:06:45,150 --> 00:06:49,450
+بنفس المنطق بنعمل ال amino acids لكن شو المجموعة
+
+75
+00:06:49,450 --> 00:06:55,600
+اللى بنحطها لأعلى؟بدل ال الديهايد مجموعة الحامض
+
+76
+00:06:55,600 --> 00:06:59,860
+يعني ال amino acids في حامض برسم المجموعة الحامض
+
+77
+00:06:59,860 --> 00:07:04,420
+هذه لأعلى الآن بعد مجموعة الحامض ال carbon Alpha
+
+78
+00:07:04,420 --> 00:07:11,080
+متصلة ب H و متصلة ب NH2 و متصلة ب R group تاني
+
+79
+00:07:11,080 --> 00:07:14,960
+يعني هي بتميز و بتخلي عدد ال amino acids infinity
+
+80
+00:07:14,960 --> 00:07:19,780
+ليش أنا بقول العدد infinity يعني هذا الجزء CO2 H
+
+81
+00:07:19,780 --> 00:07:25,700
+ثابتالـ H ثابتة، الآن الـ H2 ثابتة، الآن الـ Amino
+
+82
+00:07:25,700 --> 00:07:30,600
+acid عن التاني بتغيره بإيش؟ بالـ R طالما في عندي
+
+83
+00:07:30,600 --> 00:07:36,110
+متغيّد، الـ R ممكن تكون عدد لا نهائيواضح ال R ممكن
+
+84
+00:07:36,110 --> 00:07:40,210
+تكون عدد لا نهاية الان احنا بنيجي بنرسم بهذا الشكل
+
+85
+00:07:40,210 --> 00:07:44,470
+عشان الكل يفهم على بعضه اذا حطينا ال N H2 على
+
+86
+00:07:44,470 --> 00:07:49,230
+اليمين بنقول هذا D Amino Acid اذا حطينا ال N H2
+
+87
+00:07:49,230 --> 00:07:54,890
+على اليسار بنقول هذا ايش ال Amino Acids الان ال
+
+88
+00:07:54,890 --> 00:07:59,770
+Amino Acids اللي بيطلعوا من ال proteins كلهم L مش
+
+89
+00:07:59,770 --> 00:08:07,980
+D هذا خلق اللههك ربنا خلقهم يعني لاحظوا أنه لما
+
+90
+00:08:07,980 --> 00:08:11,020
+بنيجي الحل للبروتين بنلاحظ أنه كل ال amino acids
+
+91
+00:08:11,020 --> 00:08:14,600
+اللي طلع عندنا Alpha amino acids وكل ال amino
+
+92
+00:08:14,600 --> 00:08:20,080
+acids اللي طلع عندنا ال amino acids واضح؟ الآن
+
+93
+00:08:20,080 --> 00:08:28,500
+بنيجي لنقطة تانية أنه طالما أن هذا ال R متغير
+
+94
+00:08:29,120 --> 00:08:32,920
+ممكن تاخد أي إشي أتش مثل إثالبروبيل إيزوبروبيل و
+
+95
+00:08:32,920 --> 00:08:37,160
+كبرو زي ما بدكم معناه ذلك من الناحية النظرية كده
+
+96
+00:08:37,160 --> 00:08:44,680
+اندي أمينو أسيد حتى ألفةعدد لانهائي لكن بالواقع
+
+97
+00:08:44,680 --> 00:08:48,680
+التجريبي لما بيعملوا hydrolysis ل ال proteins
+
+98
+00:08:48,680 --> 00:08:53,380
+وبيفصلوا ال amino acids اللي نشأت من تميق ال
+
+99
+00:08:53,380 --> 00:08:57,200
+protein و تكسره لوحدته الأولية لاحظوا ان في عندنا
+
+100
+00:08:57,200 --> 00:09:02,620
+عشرين amino acid هذا الكلام بسهل الشغل علينا يعني
+
+101
+00:09:02,620 --> 00:09:06,980
+تخيل لو كانوا الف و كل واحد بده تشخيص مشكلة لكن
+
+102
+00:09:08,010 --> 00:09:13,070
+بشكل عام كل بروتينات ملفة حوالين ال 20 amino acids
+
+103
+00:09:13,070 --> 00:09:20,010
+هدولة اللي بشكل عام موجودين في البروتينات الان من
+
+104
+00:09:20,010 --> 00:09:24,450
+هدولة ال amino acids العشرينعلى خلاف بسيط من
+
+105
+00:09:24,450 --> 00:09:29,330
+العلماء مش مشكلة خلّيني أتزم بالكلام في 12 amino
+
+106
+00:09:29,330 --> 00:09:33,530
+acid ممكن يتحضروا في الجسم يعني الإنسان ممكن
+
+107
+00:09:33,530 --> 00:09:38,390
+يحضرهم من نقطة السفر وفي 8 amino acids الجسم
+
+108
+00:09:38,390 --> 00:09:43,450
+بيحضرهمش طب هدولة اللي بيحضرهمش الجسم لازم ياخدهم
+
+109
+00:09:43,450 --> 00:09:48,890
+جاهزين من برا من وين هياخدهم؟ من الغذابةأنواع من
+
+110
+00:09:48,890 --> 00:09:52,750
+الغذاء فيها هذه ال amino acids الآن هدولة التمانية
+
+111
+00:09:52,750 --> 00:09:56,790
+amino acids that cannot be synthesized in the body
+
+112
+00:09:56,790 --> 00:10:00,610
+they are called essential amino acids الأحماض
+
+113
+00:10:00,610 --> 00:10:05,350
+الأمينية الأساسية فلما نقول إيش معنى essential
+
+114
+00:10:05,350 --> 00:10:09,730
+amino acids the amino acids that cannot be
+
+115
+00:10:09,730 --> 00:10:13,830
+synthesized in the body and must be obtained from
+
+116
+00:10:13,830 --> 00:10:18,390
+the dietin the form of protein لازم ناخدها من
+
+117
+00:10:18,390 --> 00:10:22,290
+الغذاء على شكل البروتينات، الغذاء الحيواني اللي
+
+118
+00:10:22,290 --> 00:10:25,850
+بنتغدأه، والغذاء النباتي، بروتينات حيوانية أو
+
+119
+00:10:25,850 --> 00:10:32,460
+نباتيةهدول ال amino acids العشرين بدنا نتعرف عليهم
+
+120
+00:10:32,460 --> 00:10:37,440
+جيدا، طبعا كل واحد له اسم، و دائما الناس بيحبوا
+
+121
+00:10:37,440 --> 00:10:41,920
+إيش؟ يختصروا الأسماء، يعني هيمروا علينا glycine,
+
+122
+00:10:41,980 --> 00:10:46,880
+alanine, cysteine, tryptophan, saline, valineاكتار
+
+123
+00:10:46,880 --> 00:10:52,960
+واضح؟ الان فى لهم نوعين من الاختصار فى اختصار لهم
+
+124
+00:10:52,960 --> 00:10:58,240
+بتلت حروف وفى اختصار لهم بحرف واحد بنسميه three
+
+125
+00:10:58,240 --> 00:11:03,100
+letter abbreviation اختصار الاسم لتلت حروف وفى
+
+126
+00:11:03,100 --> 00:11:08,140
+اننا نختصره لحرف واحد one letter abbreviation بشكل
+
+127
+00:11:08,140 --> 00:11:13,830
+عام اذا انا كنتربما المحاضرة السابقة قلتلكوا مشكلة
+
+128
+00:11:13,830 --> 00:11:20,310
+البروتينات ان they are not polymers فلازم اعمللهم
+
+129
+00:11:20,310 --> 00:11:24,650
+ايش؟ sequence ترتيب مين جاي اول واحد التاني التالت
+
+130
+00:11:24,650 --> 00:11:30,070
+الرابع الان اذا انا بدي ارسم peptide صغير يعني ال
+
+131
+00:11:30,070 --> 00:11:34,470
+peptide بيكون عادة تمانية تسعة عشرة خمستاشر amino
+
+132
+00:11:34,470 --> 00:11:39,920
+acid بستعمل three letter abbreviation واضح؟وإذا
+
+133
+00:11:39,920 --> 00:11:43,660
+بدى استعمل البروتين لبروتين بالمئات اللي لم يكن
+
+134
+00:11:43,660 --> 00:11:47,460
+بالألاف بستعمل ال one letter abbreviation فاللي
+
+135
+00:11:47,460 --> 00:11:52,320
+بدى يرسم ببتايد عادة بيستعمل اختصار تلت حروف اللي
+
+136
+00:11:52,320 --> 00:11:59,080
+بدى يرسم البروتين بيستخدم اختصار الحرف الواحد الان
+
+137
+00:11:59,080 --> 00:12:05,320
+لو اجينا بدنا نتعرف على هدول ال amino acids لاحظوا
+
+138
+00:12:05,320 --> 00:12:12,100
+ان احنا اتفقنا ان ال amino acidsفيهم أكتر من شيء
+
+139
+00:12:12,100 --> 00:12:16,080
+مشترك يعني مجموعة ال acid مشتركة ال carbon اللي
+
+140
+00:12:16,080 --> 00:12:20,960
+جنبها مشتركة و غالبا بتحمل H و أنا H2 و يمكن معادة
+
+141
+00:12:20,960 --> 00:12:25,420
+أمينو أسد واحد بيظل عندنا الاختلاف وين؟ في ال R
+
+142
+00:12:25,420 --> 00:12:30,100
+group بيظل عندنا الاختلاف في ال R group الآن بنيجي
+
+143
+00:12:30,100 --> 00:12:33,300
+إذا كانت ال R أبسط شيء عندنا في ال organ ال
+
+144
+00:12:33,300 --> 00:12:38,350
+chemistry اللي هي ال Hتمام؟ ال amino acid بيكون هو
+
+145
+00:12:38,350 --> 00:12:44,670
+ال glycine واضح؟ بياخد اختصارين ال gly او ال j
+
+146
+00:12:44,670 --> 00:12:50,930
+واضح؟ الان لاحظوا معي ال glycine تحديدا لو طلعنا
+
+147
+00:12:50,930 --> 00:12:55,110
+على ال carbon اللي هنا هذا ال carbon
+
+148
+00:12:58,040 --> 00:13:03,760
+في H و H مافيش في عليه four different groups عشان
+
+149
+00:13:03,760 --> 00:13:08,020
+هيك ال glycine does not contain a chiral center so
+
+150
+00:13:08,020 --> 00:13:12,620
+it is not a chiral molecule مش chiral optically
+
+151
+00:13:12,620 --> 00:13:20,990
+inactive مع ده ال glycine كلهم هيكونواthey contain
+
+152
+00:13:20,990 --> 00:13:24,670
+chiral centers and they are optically active الآن
+
+153
+00:13:24,670 --> 00:13:30,450
+نمشي بسرعة لو بدنا نشوف الحامض الأميني لبعده اللي
+
+154
+00:13:30,450 --> 00:13:35,850
+في مجموعة المثل أبسط المجموعات المثل بيصير اسمه
+
+155
+00:13:35,850 --> 00:13:38,590
+الانين لاحظوا ما تقولوش أنين
+
+156
+00:13:41,140 --> 00:13:45,340
+حاجة تانية في الـ aromatic compounds الانين الانين
+
+157
+00:13:45,340 --> 00:13:51,120
+بياخد الاختصار ال أو ا في مجموعة المثل لو كان في
+
+158
+00:13:51,120 --> 00:13:56,480
+مجموعة ال isopropyl بيصير اسمه valine لو كان في
+
+159
+00:13:56,480 --> 00:14:01,820
+مجموعة ال isobutyl بيصير اسمه ليوسين طبعا هذا ايه
+
+160
+00:14:01,820 --> 00:14:06,900
+الاختصار value في ال EU إذا كان في مجموعة ال
+
+161
+00:14:06,900 --> 00:14:13,600
+secondary butyl بيصير اسمه isoleucineواضح؟ لاحظوا
+
+162
+00:14:13,600 --> 00:14:17,100
+كل هذه المجموعات in principle they are simple
+
+163
+00:14:17,100 --> 00:14:20,560
+alkyl groups يعني كلها مرت علينا لما أخدنا ال
+
+164
+00:14:20,560 --> 00:14:25,240
+alkyl groups مثل بروبل مثل ايزو بروبل ايزو بيوتل
+
+165
+00:14:25,240 --> 00:14:29,540
+سكندر بيوتل they are simple alkyl groups هذه
+
+166
+00:14:29,540 --> 00:14:34,970
+المجموعة الأولى من ال amino acidsالان بعد هيك في
+
+167
+00:14:34,970 --> 00:14:40,950
+عندي amino acids ال R تبعتهم بتحمل OH يعني غير ال
+
+168
+00:14:40,950 --> 00:14:48,000
+amino و غير ال acid فيهم alcohol واضح؟فيهم ال
+
+169
+00:14:48,000 --> 00:14:52,160
+amino أكيد موجودة وال acid أكيد موجود هذا لا خلاف
+
+170
+00:14:52,160 --> 00:14:56,600
+فيه لكن يضاف اللي هو منه على ال R group في عنده
+
+171
+00:14:56,600 --> 00:15:04,400
+إيش ال alcohol فمنهم السيرين CH2OH ومنهم الثريونين
+
+172
+00:15:04,400 --> 00:15:13,350
+CHOHCH3 تمام؟بعد هيك بيجيني مجموعات فيهم كبريت
+
+173
+00:15:13,350 --> 00:15:21,230
+sulfur فيهم كبريت منهم الستين CH2SH ومنهم
+
+174
+00:15:21,230 --> 00:15:26,570
+الميثيونين CH2CH2SCH3
+
+175
+00:15:26,570 --> 00:15:34,250
+طبعا هتقولوا هدولةاكتار هل يا تورا مطلوب نحفظ كلها
+
+176
+00:15:34,250 --> 00:15:39,850
+ال amino acids؟ لأ لكن انا بقدر اطلب منكم اي amino
+
+177
+00:15:39,850 --> 00:15:42,530
+acid يعني انا ممكن بعديك اجي اقولكوا ارسموا
+
+178
+00:15:42,530 --> 00:15:47,330
+بيبتايد من خمسة amino acids هنكون اتعلمنا انه في
+
+179
+00:15:47,330 --> 00:15:52,940
+هيكل مشترك و ان الاختلاف فقطفي الـ R group فلو
+
+180
+00:15:52,940 --> 00:15:57,740
+أتيت قلتلكوا مثلا الانين بين جثين الـR بتساوي مثل
+
+181
+00:15:57,740 --> 00:16:02,840
+خلاص ان عرف لإن الاختلاف بينهم بس بإيش بالمثل او
+
+182
+00:16:02,840 --> 00:16:09,660
+مثلا فالين R بتساوي isopropyl الأصل أنه يقدر
+
+183
+00:16:09,660 --> 00:16:14,960
+الإنسان يرسمه لكن على أقل تقدير على أقل تقدير بدنا
+
+184
+00:16:14,960 --> 00:16:21,130
+تكونوا بالتأكيد تعرفوا ال glycineالأول H الالانين
+
+185
+00:16:21,130 --> 00:16:31,050
+اللي هو المثل الستينالـ CH2SH الستين بالذات لأنه
+
+186
+00:16:31,050 --> 00:16:35,390
+بعد هيك هنلاحظ أنه له أهمية كبيرة في شكل البروتين
+
+187
+00:16:35,390 --> 00:16:39,610
+بيعمل داي سالفايد بونتز متذاكرين لما أخدنا الثيولز
+
+188
+00:16:39,610 --> 00:16:43,390
+كانوا يعملوا داي سالفايد بونتز الآن اللي مطلوبين
+
+189
+00:16:43,390 --> 00:16:47,530
+يعني ممكن أقولكوا أرسمولي ألانين سستين أو اعملولي
+
+190
+00:16:47,530 --> 00:16:51,290
+بيبتايد من السستين بدون ما أعطيكوا المجموعة خلاص
+
+191
+00:16:51,290 --> 00:16:54,030
+نكون عارفين أن السستين هو اللي فيه مجموعة
+
+192
+00:16:57,230 --> 00:17:05,070
+الألانين في مثل لجليسين في H ما عدا ذلك لو بدنا أي
+
+193
+00:17:05,070 --> 00:17:09,670
+شيء بس بنعطيكوا بين جثين ال R group بتقدروا تكملوا
+
+194
+00:17:09,670 --> 00:17:17,090
+رسم ال amino acidالآن بجينة حامض اسمه إبرولين هذا
+
+195
+00:17:17,090 --> 00:17:23,750
+شوية صغيرة بختلف عنهم انه مافيش فيه NH2 هو CH NH
+
+196
+00:17:23,750 --> 00:17:28,700
+ومسكر على ال NH2 يعني عامل حلقةيعني كل ال amino
+
+197
+00:17:28,700 --> 00:17:34,760
+acids لما ترسموهم هترسم مجموعة الحامض و بعدين CH و
+
+198
+00:17:34,760 --> 00:17:39,960
+NH2 مع ذا هذا البرولين بتكون ال NH مسكرة على باقى
+
+199
+00:17:39,960 --> 00:17:47,580
+الجزء بالشكل اللى موجود الان هذا البرولين ماخد
+
+200
+00:17:47,580 --> 00:17:51,860
+الاختصار برو او بي بجينة الفينلالانين
+
+201
+00:17:53,330 --> 00:17:58,250
+لاحظوا لو هذه كانت CH3، إيش اسم ال amino acid؟
+
+202
+00:17:58,250 --> 00:18:03,070
+الالانين، شيلنا منها H و حطينا فينل، صار فينل
+
+203
+00:18:03,070 --> 00:18:08,230
+الالانين، واضح؟ يعني برضه ال فينل الالانين، لإنه
+
+204
+00:18:08,230 --> 00:18:13,940
+مختصر من الالانين، بصير مطلوب منهانعرفه، ليش؟ لأن
+
+205
+00:18:13,940 --> 00:18:18,720
+اللي عرف الألانين أن الـR تبعته CH3 لما أنا أقول
+
+206
+00:18:18,720 --> 00:18:23,380
+له فنل ألانين، بشيل H و بحط مجموعة الفنل، صار
+
+207
+00:18:23,380 --> 00:18:27,440
+الفنل ألانين، فاللي عرف الألانين وعارف من الكيميا
+
+208
+00:18:27,440 --> 00:18:35,530
+العامة مجموعة الفنل، بقدر يعرف الفنل ألانينبيجينا
+
+209
+00:18:35,530 --> 00:18:39,310
+الـ Tyrosine في هذه المجموعة CH2 في الـ OH لـ
+
+210
+00:18:39,310 --> 00:18:44,950
+tryptophan في حلقة كبيرة بنسميها Endol مع CH2 مش
+
+211
+00:18:44,950 --> 00:18:53,640
+مطموض نحفظهم طبعا، الآن في مجموعة أحماض فيهممجموعة
+
+212
+00:18:53,640 --> 00:18:58,660
+حمب تانية يعني غير ال acid group و ال amino group
+
+213
+00:18:58,660 --> 00:19:02,400
+اللي هم أساسيات هدولة لاحظوا اللي رسمينهم بالأزرق
+
+214
+00:19:02,400 --> 00:19:06,600
+في كل الرسمات يعني هدولة مشتركين بيجي في ال R
+
+215
+00:19:06,600 --> 00:19:11,460
+group نفسها مجموعة حمب تانية يعني غير هذه CO2H
+
+216
+00:19:11,460 --> 00:19:15,080
+تبعت ال amino acid في هنا كمان مجموعة تانية يعني
+
+217
+00:19:15,080 --> 00:19:19,380
+صار CH2COOH فصار في another
+
+218
+00:19:22,610 --> 00:19:28,750
+هدولة منهم الحمض الأول CH2COH اسمه Aspartic Acid و
+
+219
+00:19:28,750 --> 00:19:34,900
+لو كان مجمعتين CH ورا بعض بيصير Glutamic Acidلو
+
+220
+00:19:34,900 --> 00:19:39,280
+كان مشتق من الأحماض تذكروا لما أخدنا الأحماض قولنا
+
+221
+00:19:39,280 --> 00:19:43,580
+assets and their derivatives و منها الأمد و ما إلى
+
+222
+00:19:43,580 --> 00:19:49,060
+ذلك فلو كان بهذا الشكل ماخد شكل الأمد بيكون اسمه
+
+223
+00:19:49,060 --> 00:19:55,460
+أسبارجين و لو كان أمد بزيادة CH2 يعني بيصير
+
+224
+00:19:55,460 --> 00:20:00,700
+glutamine بيصير glutamine لحظةبتقدروا تشوفوا ال
+
+225
+00:20:00,700 --> 00:20:05,160
+glutamic acid كربونتين CH2 CH2 وبعدين حامض ل
+
+226
+00:20:05,160 --> 00:20:10,080
+glutamine CH2 CH2 وبعدين الأمد تبعه لذلك إيش سموه
+
+227
+00:20:10,080 --> 00:20:16,680
+glutamine إله اختصار الآن في أحماض تانية فيهم غير
+
+228
+00:20:16,680 --> 00:20:23,230
+ال NH2 هذه مجموعة NH2 تانية مش أمد أمينلحظوا الـ
+
+229
+00:20:23,230 --> 00:20:27,650
+NH2 الأمد بتخلف عن الأمين يعني هذه أمد وقلنا عنها
+
+230
+00:20:27,650 --> 00:20:33,050
+unreactive group متذكرين لما أخدنا الأمد قلنا انه
+
+231
+00:20:33,050 --> 00:20:38,230
+unreactive لأ في بيكون فيهم أمين عادية NH2 تانية
+
+232
+00:20:38,230 --> 00:20:44,640
+منهم اللايسين بالشكل اللي موجود منهم الارجينينفيه
+
+233
+00:20:44,640 --> 00:20:49,380
+أكثر من NH ومنهم الهستيدين هي أنا بتلاحظوا برضه
+
+234
+00:20:49,380 --> 00:20:58,080
+فيه NH NH NH أو NH2 هذي كلها amino acids فزي ما
+
+235
+00:20:58,080 --> 00:21:02,680
+بتلاحظوا انه بتصنيف ال amino acids التركيز على
+
+236
+00:21:02,680 --> 00:21:06,220
+إيش؟ على ال R group يعني ال R ممكن تكون simple
+
+237
+00:21:06,220 --> 00:21:10,960
+alkyl groupممكن تحتوي على OH ممكن تحتوي على
+
+238
+00:21:10,960 --> 00:21:16,680
+مجموعات aromatic ممكن تحتوي على مجموعة حمضية تانية
+
+239
+00:21:16,680 --> 00:21:22,480
+ممكن تحتوي على مجموعة قاعدية تانية واضح هذا
+
+240
+00:21:22,480 --> 00:21:31,670
+بالنسبة للتعريف بال amino acids بشكل عامالان لو
+
+241
+00:21:31,670 --> 00:21:36,310
+اجينا بدينا في ال acid-base properties لل amino
+
+242
+00:21:36,310 --> 00:21:45,450
+acids ال amino acids هم خليط من حمض و قاعدة ماشي
+
+243
+00:21:45,450 --> 00:21:51,850
+ال amino group is a basic group لما درسناها و أبسط
+
+244
+00:21:51,850 --> 00:21:57,700
+basic group منها ال ammoniaتحمل زوج إلكترونات
+
+245
+00:21:57,700 --> 00:22:05,040
+وجاهز إنها تستقبل إيش بروتون والأحماض acids الآن
+
+246
+00:22:05,040 --> 00:22:12,340
+لو أنا بشكل منفصل إجيت قلتلكم حمض زائد قاعدة يعني
+
+247
+00:22:12,340 --> 00:22:20,860
+HCL زائد أمونيا أو acetic acid زائد أمونياماشي
+
+248
+00:22:20,860 --> 00:22:26,360
+الحمض مع القاعدة بتفاعل وش بيعطوني ملح و ماء ممتاز
+
+249
+00:22:26,360 --> 00:22:32,060
+جدا الان في ال amino acids الحمض و القاعدة نوجدوا
+
+250
+00:22:32,060 --> 00:22:39,960
+في جزء واحد واضح ال amino group basic و ال COOH
+
+251
+00:22:39,960 --> 00:22:48,510
+acidic ال amino group بتحب تكتسببروتون هاي معناه
+
+252
+00:22:48,510 --> 00:22:54,950
+base و COH بتفقد بروتون طب هدول اتنين انحطوا في
+
+253
+00:22:54,950 --> 00:23:02,350
+جزء واحد اذا بالوضع الطبيعي تلقائيا بيعملوا تفاعل
+
+254
+00:23:02,350 --> 00:23:06,870
+داخلي طالما انه انوجد ال acidic group و ال basic
+
+255
+00:23:06,870 --> 00:23:11,110
+group بنفس الجزء بيعملوا التفاعل بينهم و بين بعض
+
+256
+00:23:11,110 --> 00:23:17,010
+المجموعة الحامضية بتفقد ال H و مين بيكتسبهالقاعدة
+
+257
+00:23:17,010 --> 00:23:24,310
+و لذلك بالوضع الطبيعي هذا الحامض بدل ما يكون C
+
+258
+00:23:24,310 --> 00:23:30,930
+double bond O OH بيفقد ال H بيصير CO2 minus يعني C
+
+259
+00:23:30,930 --> 00:23:35,870
+double bond O O minus لأن ال H اللي فقدها هنا مين
+
+260
+00:23:35,870 --> 00:23:42,730
+بده يتسبها القاعدة بدل ما هي NH2 بتصير NH3 plus
+
+261
+00:23:43,440 --> 00:23:49,180
+واضح؟ وبناء على ذلك في الوضع الطبيعي المتعدل ال
+
+262
+00:23:49,180 --> 00:23:56,460
+amino acids ما برسموهش بهذا الشكل يعني RCHC
+
+263
+00:23:56,460 --> 00:24:03,800
+double bond O OH هنا ال N H2بنرسمه مش زيك، بنقول
+
+264
+00:24:03,800 --> 00:24:08,220
+هذا حامض بده يفقد، هذه قاعدة بده تكتسب، وقاعدين
+
+265
+00:24:08,220 --> 00:24:11,920
+جان بعض، شو اللي بيمنعهم يفقدوا ويكتسبوا؟ بناء على
+
+266
+00:24:11,920 --> 00:24:17,380
+ذلك، بيتم إنه هذه بتفقد منها، وبتيجي وين؟ على هذا
+
+267
+00:24:17,380 --> 00:24:21,560
+الوضع، ففي ال neutral form حقيقة ما بنوجدش ال
+
+268
+00:24:21,560 --> 00:24:25,720
+amino acids بهذا الشكل، لأ بنوجد بهذا الشكل، فقد
+
+269
+00:24:25,720 --> 00:24:31,940
+لبروتون منها، واكتسبته إيش؟الـ Base واضح؟ و الآن
+
+270
+00:24:31,940 --> 00:24:37,460
+هذا الشكل بنقول عنه احنا Dipolar Ionic Form يعني
+
+271
+00:24:37,460 --> 00:24:43,820
+شكل فيه قطبين و بياخد اسم تاني جاي من الألماني
+
+272
+00:24:43,820 --> 00:24:47,900
+Zwitter Ionic Zwitter اش يعني Zwitter؟
+
+273
+00:24:51,140 --> 00:24:57,060
+سفيتر ionic form هذا المصطلح بيمر معاكم كتير سفيتر
+
+274
+00:24:57,060 --> 00:25:04,310
+من svay svay بالالماني معناها إيش؟اتنين, zwei يعني
+
+275
+00:25:04,310 --> 00:25:08,630
+اتنين يعني لما احنا بنعد بالعرب ايش بنقول؟ واحد,
+
+276
+00:25:08,690 --> 00:25:12,970
+اتنين, تلاتة, اربعة و بالانجليزي one, two, three,
+
+277
+00:25:13,170 --> 00:25:17,870
+four بالالماني eins, zwei, drei, vier, fünf,
+
+278
+00:25:18,030 --> 00:25:22,690
+sechs, sieben, acht, neun, zehn ف zwei يعني اتنين
+
+279
+00:25:22,690 --> 00:25:29,300
+فمنها ايجاZwitter Ionic لحظة دي بتنقرق Z و هذه ال
+
+280
+00:25:29,300 --> 00:25:37,440
+W V مش Zwitter لأ Zwitter واضح ال W الألمان شو
+
+281
+00:25:37,440 --> 00:25:44,760
+بيقرؤوها V و ال V إيش بيقرؤوها F عشان هيك اللي
+
+282
+00:25:44,760 --> 00:25:47,760
+عندهم السيارة هذه ال Volkswagen
+
+283
+00:25:50,020 --> 00:25:53,000
+إذا بدهم يقرؤوها بلغة الإنجليز بدهم يقرؤوا
+
+284
+00:25:53,000 --> 00:25:59,240
+Volkswagen بس هي باللغة الألمانية Volkswagen ال V
+
+285
+00:25:59,240 --> 00:26:06,880
+تقرأ F و ال W V Volkswagen Volkswagen يعني سيارة و
+
+286
+00:26:06,880 --> 00:26:10,240
+Volkswagen شعب
+
+287
+00:26:10,240 --> 00:26:15,080
+يعني تاكس الشعب سيارة الشعب سيارة البسيطة عارفينهم
+
+288
+00:26:15,080 --> 00:26:19,870
+ال Volkswagen اللي منهم الباصات و ال ..هذه
+
+289
+00:26:19,870 --> 00:26:23,650
+السيارات الكتيرة Volkswagen هذي svitar ionic
+
+290
+00:26:23,650 --> 00:26:30,430
+structure فلو سألناكم ان ال amino acids are better
+
+291
+00:26:30,430 --> 00:26:35,710
+represented by a dipolar ion structure معناه
+
+292
+00:26:35,710 --> 00:26:39,970
+dipolar ion structure svitar ionic structure عرفنا
+
+293
+00:26:39,970 --> 00:26:43,610
+ايش معناه هذا المصطلح؟ بتكرر كتير معكم بالمناسبة
+
+294
+00:26:44,390 --> 00:26:49,590
+تمام هذا الوضع في الـ neutral form طيب لو اجينا ال
+
+295
+00:26:49,590 --> 00:26:54,550
+amino acid احنا حطينا عليه H plus يعني زدناله H
+
+296
+00:26:54,550 --> 00:27:00,050
+plus من الخارج يعني بدون ما نحطله لا H plus ولا OH
+
+297
+00:27:00,050 --> 00:27:05,510
+minus يعني نسيبه زي ما هو هو حل مشكلته لحاله فقد H
+
+298
+00:27:05,510 --> 00:27:10,170
+من جهة و حطه بجهة تانية واضح؟و هذا الكلام كله في
+
+299
+00:27:10,170 --> 00:27:13,190
+الـ neutral form ماضفناش عليه إش بالبرا طب لو ضفنا
+
+300
+00:27:13,190 --> 00:27:19,450
+له H plus إضافية وين هتروح الـ H plus؟ على ال O
+
+301
+00:27:19,450 --> 00:27:24,490
+minus و لذلك لو ضفنا H plus هيصير بهذا الشكل الآن
+
+302
+00:27:24,490 --> 00:27:29,250
+لاحظوا لما أنا ضفت له H plus هذا متعادل ليش؟ لأنه
+
+303
+00:27:29,250 --> 00:27:34,110
+في موجب و سالب جد بعض الآن متعادل زاد H plus
+
+304
+00:27:34,110 --> 00:27:40,700
+متعادل زاد موجبأيش المحصلة موجب فهي لما فعلنا إجت
+
+305
+00:27:40,700 --> 00:27:45,580
+ال H plus اللي ضفناها هنا H plus عدلة ال O minus
+
+306
+00:27:45,580 --> 00:27:51,640
+دلوا موجب فبال acidic form بيكون ال amino acids
+
+307
+00:27:52,780 --> 00:27:57,480
+موجبة إيش شحنتها موجبة لاحظوا هذه الأسئلة اللي
+
+308
+00:27:57,480 --> 00:28:00,980
+بتكونوا تسألوها انتوا بالصح و الغلط in acidic
+
+309
+00:28:00,980 --> 00:28:09,320
+medium the amino acids are positive واضح amino
+
+310
+00:28:09,320 --> 00:28:14,530
+acid at low pH ال low pH معناهاacidic ايش بيكونوا؟
+
+311
+00:28:14,530 --> 00:28:19,170
+positive الان لو افترضنا هذا ال amino acid بعد ما
+
+312
+00:28:19,170 --> 00:28:23,670
+حطينا عليه حامض بزيادة وصار موجب اجينا بدينا بدنا
+
+313
+00:28:23,670 --> 00:28:28,510
+نسحب منه ال Hات كيف بنسحبهم؟ شو اللي بيسحب ال H
+
+314
+00:28:28,510 --> 00:28:33,870
+plus؟ OH minus فلو فعلت أنا مع OH minus هتيجي تسحب
+
+315
+00:28:33,870 --> 00:28:39,950
+هذه اللي اجت OH minus مع ال H؟ هتعطيني H2O و هيرجع
+
+316
+00:28:39,950 --> 00:28:49,700
+للوضع؟المتعادل طب لو زته كمان OH minus هياخد هذه
+
+317
+00:28:50,900 --> 00:28:55,760
+هياخد القدش اللي زي دهانة، شو هيصير؟ سالب فبناء
+
+318
+00:28:55,760 --> 00:29:01,180
+على ذلك بيصير عند أنا قاعدة بسيطة كتير ان ال amino
+
+319
+00:29:01,180 --> 00:29:08,940
+acids في الوسط الحامضي بيكونوا مجابين، في الوسط
+
+320
+00:29:08,940 --> 00:29:17,250
+القاعدي بيكونوا سالبين، واضح؟ سالبو طبعا بدون ما
+
+321
+00:29:17,250 --> 00:29:21,550
+نضيف عليهم من برا لا حمض ولا قاعدة بيكونوا إيش؟
+
+322
+00:29:21,550 --> 00:29:30,150
+neutral بس في zwitterionic form واضح؟ في شكل ثنائي
+
+323
+00:29:30,150 --> 00:29:33,050
+القطبية، هاي معناه zwitterionic form
+
+324
+00:29:38,320 --> 00:29:43,320
+هي هنا كمان مثال تأكيدي تماما للمثال السابق هو
+
+325
+00:29:43,320 --> 00:29:50,620
+أعطاني amino acid موجة طبعا بدناش ننسا احنا شغلة
+
+326
+00:29:50,620 --> 00:29:54,440
+انه فيش اشي في الدنيا .. فيش اشي في الدنيا بنباع
+
+327
+00:29:55,130 --> 00:29:59,910
+موجب أو سالب يعني لما هنا كنا نقولكوا اضيفوا H
+
+328
+00:29:59,910 --> 00:30:04,390
+plus مافيش H plus بتنجب لحالها و بتلبعها عادة لما
+
+329
+00:30:04,390 --> 00:30:08,230
+نقول اضيف H plus من وين بنجيبها؟ من HCL يعني كان
+
+330
+00:30:08,230 --> 00:30:13,210
+في معاه CL minus وبناء على ذلك لما هذه عملة الايون
+
+331
+00:30:13,210 --> 00:30:20,210
+الموجب كل هذا الجزء الموجب كان فيله CL minus مرافق
+
+332
+00:30:21,300 --> 00:30:27,000
+واضح؟ لكن أنا كنت مختصر الـCl- كده لأن أنا مهتم
+
+333
+00:30:27,000 --> 00:30:30,860
+بجزء الـ amino acid مش بالجزء التاني، واضح؟ بس
+
+334
+00:30:30,860 --> 00:30:34,460
+مافيش H بلس في الكون بتلبع لحالها، يعني الـH بلس
+
+335
+00:30:34,460 --> 00:30:38,100
+جاية من وين؟ من acid، خلّيني أقول HCl، فلو كنت
+
+336
+00:30:38,100 --> 00:30:44,560
+أعطي الـHCl، حيكون هذا موجة ومعه Cl ثالث، الآن لو
+
+337
+00:30:44,560 --> 00:30:49,620
+أخدنا مثل، هاي الـ amino acid الالانينفى nh3 plus
+
+338
+00:30:49,620 --> 00:30:54,560
+cl minus لما نيجى نفعله مع ال N A O H شو اللى بدى
+
+339
+00:30:54,560 --> 00:31:03,480
+يصير ال O H minus بدى تاخد ال H شو عملت ليه H 2 O
+
+340
+00:31:03,480 --> 00:31:06,680
+ال N A plus مع ال C L minus
+
+341
+00:31:11,850 --> 00:31:20,330
+الحمض يبقى في وضعه نيوترال وليس جابوسالد الاسفتر
+
+342
+00:31:20,330 --> 00:31:25,170
+ايونيك نيوترال الان هذا نفسه نيوترال لو اجينا كمان
+
+343
+00:31:25,170 --> 00:31:34,480
+مرة زدناله NAOH شو حيصير ال OH- هتاخدوحدة من هدولة
+
+344
+00:31:34,480 --> 00:31:41,100
+ال H's هتعطيني H2O هيصير بناء على ذلك هذي أنا H2
+
+345
+00:31:41,100 --> 00:31:45,860
+متعادلة بس أنا في عندى minus ال minus بالزمعيون
+
+346
+00:31:45,860 --> 00:31:46,620
+مرافق
+
+347
+00:31:50,390 --> 00:31:54,910
+فهذه المعادلات الحقيقة بلزم انكوا تتدربوا عليها
+
+348
+00:31:54,910 --> 00:31:58,710
+كيف ان ال amino acid بيكتسب بروتون كيف بيفقد
+
+349
+00:31:58,710 --> 00:32:02,870
+بروتون من خلال التفاعل مع حامض بيكتسب بروتونات من
+
+350
+00:32:02,870 --> 00:32:07,070
+خلال التفاعل مع القاعدة بيفقد بروتونات ما لم
+
+351
+00:32:07,070 --> 00:32:10,670
+تكتبوا و تتدربوا بهدوء على هذه المعادلات مش
+
+352
+00:32:10,670 --> 00:32:14,830
+هتتقنوا يعني مرات بنجيبلكوا أكمل المعادلات زي هيك
+
+353
+00:32:14,830 --> 00:32:20,270
+حطيلكوا amino acidع شكل Salt يعني كنا ضايفينله
+
+354
+00:32:20,270 --> 00:32:26,030
+أساسا HCL فعلوه مع NUH مرة أو مرتين يعني بنسبة
+
+355
+00:32:26,030 --> 00:32:31,490
+واحد او بنسبة اتنين اول NUH بتواصلنا لهنا تاني
+
+356
+00:32:31,490 --> 00:32:38,510
+فاعل واضح هذا الكلام وظيفة الطالب انه يتدرب عليه
+
+357
+00:32:38,510 --> 00:32:46,720
+الانمن الكلام هذا كله هنيجي لمحصلة مهمة جدا
+
+358
+00:32:46,720 --> 00:32:50,640
+المحصلة المهمة جدا احنا قلنا انه في ال acidic
+
+359
+00:32:50,640 --> 00:32:54,440
+condition
+
+360
+00:32:54,440 --> 00:33:00,560
+يعني في موضع حامض ال amino acid شو بيكون موجب و في
+
+361
+00:33:00,560 --> 00:33:09,680
+basic condition سالب طبعا معنى acidic low pHالان
+
+362
+00:33:09,680 --> 00:33:15,940
+كون ال amino acid صار ممكن يكون موجود
+
+363
+00:33:17,410 --> 00:33:22,230
+متعادل الـ zwitterionic يعني فيه الموجب والسالب أو
+
+364
+00:33:22,230 --> 00:33:28,450
+بس فيه كأمينو أسد الموجب أو بس فيه كأمينو أسد
+
+365
+00:33:28,450 --> 00:33:34,790
+السالب هذا الكلام بيوفرلي تقنية لفصل إيش ال amino
+
+366
+00:33:34,790 --> 00:33:41,670
+acids قبل ما نصل لهذا الكلام خلينا نقول ان ال BH
+
+367
+00:33:45,180 --> 00:33:50,480
+اللي بيكون عندها ال amino acid neutral سبعة ..
+
+368
+00:33:50,480 --> 00:33:54,360
+بنسميها .. لأ مش سبعة مختلفة .. مختلفة لأن ال
+
+369
+00:33:54,360 --> 00:33:59,320
+amino acid نفسه في مجموعات بتخليه acidic و basic
+
+370
+00:33:59,320 --> 00:34:04,060
+إضافية ال BH اللي بيكون عندها neutral ال amino
+
+371
+00:34:04,060 --> 00:34:08,120
+acid خلينا نقول هيك ال BH اللي بيكون عندها ال
+
+372
+00:34:08,120 --> 00:34:13,390
+amino acid إيش؟الـ neutral بتقول عنها الـ
+
+373
+00:34:13,390 --> 00:34:18,830
+isoelectric point واضح فال isoelectric point اللي
+
+374
+00:34:18,830 --> 00:34:24,550
+هي ال pH اللي بيكون عندها ال amino acid متعدل
+
+375
+00:34:24,550 --> 00:34:30,990
+isoelectric point الان كل amino acid له
+
+376
+00:34:30,990 --> 00:34:37,130
+isoelectric point خاصة فيه لكل ال amino acids
+
+377
+00:34:38,900 --> 00:34:43,840
+هتلاحظوا ان الـ isoelectric point تبعتهم موجودة في
+
+378
+00:34:43,840 --> 00:34:50,100
+الجدوة المحطوطة بين جثين يعني اتطلعوا للجليسين وين
+
+379
+00:34:50,100 --> 00:34:54,840
+بيكون ال amino acid متعادل بالسفتر ايونك and BH؟
+
+380
+00:34:54,840 --> 00:35:01,320
+ستة للالانين ستة للفالين ستة للسيرين مثلا خمسة
+
+381
+00:35:01,320 --> 00:35:09,930
+وسبعة للستين خمسةمجيوسة الان لاحظوا لما يكون عند
+
+382
+00:35:09,930 --> 00:35:14,930
+انا بعض ال amino acids فيهم مجموعة حمضية تانية
+
+383
+00:35:14,930 --> 00:35:20,330
+بتصير ال isoelectric point منخفضة بتصير تلاتة يعني
+
+384
+00:35:20,330 --> 00:35:23,550
+بيقاتش تلاتة بيكونوا متعادلين لما يكون فيهم مجموعة
+
+385
+00:35:23,550 --> 00:35:27,350
+قاعدية تانية بتصير ال isoelectric point عقلهم عالي
+
+386
+00:35:27,350 --> 00:35:33,490
+عند تسعة وعند عشرة تقريبا واضح فكل amino acid الان
+
+387
+00:35:34,530 --> 00:35:39,990
+بنفهم ان هو له isoelectric point ال بي اتش اللى
+
+388
+00:35:39,990 --> 00:35:46,430
+بيكون عندها متعادل الان اقل من ال isoelectric
+
+389
+00:35:46,430 --> 00:35:54,210
+point هذه ال بي اتش ايش بيصير موجب اعلى منها سالب
+
+390
+00:35:54,210 --> 00:35:58,810
+يعني صار في عند انا ال isoelectric point لل amino
+
+391
+00:35:58,810 --> 00:36:08,130
+acid ال isoelectric pointالآن هذه neutral أقل منها
+
+392
+00:36:08,130 --> 00:36:17,310
+موجب أعلى منها سالف واضح؟ وبناء على ذلك لو أنا جيت
+
+393
+00:36:17,310 --> 00:36:22,750
+سألت مثلا للستين شو ال isoelectric point قبل شوية
+
+394
+00:36:22,750 --> 00:36:29,560
+حكيناها ستةلسستين ستة الان لو سألتكم و قولتلكم
+
+395
+00:36:29,560 --> 00:36:35,880
+السستين عند بي اتش اربعة شو بيكون موجب السستين عند
+
+396
+00:36:35,880 --> 00:36:41,620
+بي اتش تسعة او تمانية سالب واضحهذه معناه الكلام
+
+397
+00:36:41,620 --> 00:36:49,000
+يعني BH6 الستين ال neutral بيكون
+
+398
+00:36:49,000 --> 00:36:55,120
+موجب ال BH أعلى بيكون H سالب الآن هذا الموضوع أن
+
+399
+00:36:55,120 --> 00:37:00,200
+ال amino acid ممكن نتحكم فيه يعني الستين أنا
+
+400
+00:37:00,200 --> 00:37:05,620
+بتغيير ال BH قاعد بقدر أخليه مرة يكون موجب مرة
+
+401
+00:37:05,620 --> 00:37:10,240
+يكون متعادل مرة يكون سالب ولا لأأنا اللي بتحكم في
+
+402
+00:37:10,240 --> 00:37:13,400
+ال بي أتش كيف الواحد بتحكم في ال بي أتش بيحط حمض
+
+403
+00:37:13,400 --> 00:37:17,540
+أو قاعدة أو بزيدها أو بنجسها يعني قمر سهل عمليا
+
+404
+00:37:17,540 --> 00:37:24,940
+فكأنه ال بي أتش صار إلها إشي تابع إنه يكونموجب أو
+
+405
+00:37:24,940 --> 00:37:29,820
+سالب الآن جثة الموجب والسالب كتير بتفرج معناه ليش؟
+
+406
+00:37:29,820 --> 00:37:35,560
+لأنه أخدوا منها .. من فكرتها تقنية عامة لفصل ال
+
+407
+00:37:35,560 --> 00:37:41,380
+amino acids عن بعضهم البعض الموجبلو حطيته في مجال
+
+408
+00:37:41,380 --> 00:37:45,780
+كهربائي، في موجة بوسالب، هيروح وين؟ على السالب،
+
+409
+00:37:45,780 --> 00:37:51,400
+والسالب هيروح وين؟ على الموجب، وبناء على ذلك هذا
+
+410
+00:37:51,400 --> 00:37:55,500
+الكلام بيصير أساس لطريقة، لفصل
+
+411
+00:37:58,240 --> 00:38:01,600
+الأمينو أسد هي أنا تعريف ال isoelectric point بس
+
+412
+00:38:01,600 --> 00:38:06,220
+عشان تكونوا متذكرينها is the pH at which the amino
+
+413
+00:38:06,220 --> 00:38:09,520
+acid will be dipolar and have in it its charge
+
+414
+00:38:09,520 --> 00:38:14,780
+equal to zero الأن لما يكون ديبولر و شحنته سفر لو
+
+415
+00:38:14,780 --> 00:38:18,920
+حطيته بوسط كهربا يعني حاطيت قطبين كهربا موجب و
+
+416
+00:38:18,920 --> 00:38:23,710
+سالبو ال بي اتش تبعته ع ال isoelectric point يعني
+
+417
+00:38:23,710 --> 00:38:28,710
+هو متعادل بيروح يمين ولا شمال ولا بيقعد مكانه الان
+
+418
+00:38:28,710 --> 00:38:34,550
+لو كانت ال بي اتش قليلة بمعنى كان موجب و وجدت وين
+
+419
+00:38:34,550 --> 00:38:38,830
+هيروح الموجب؟ على السالب على ال cathode و لو كانت
+
+420
+00:38:38,830 --> 00:38:43,990
+ال بي اتش عالية كان سالب وين هيروح السالب؟ على ال
+
+421
+00:38:43,990 --> 00:38:49,960
+anode مش ال anode هو القطبالموجب والكثود هو القطب
+
+422
+00:38:49,960 --> 00:38:55,600
+السالق وبناء على ذلك بتصير هذه طريقة يمكن من
+
+423
+00:38:55,600 --> 00:39:01,120
+خلالها ان نفصل ال amino acids عن بعض بنسميها ال ال
+
+424
+00:39:01,120 --> 00:39:03,260
+Electrophoresis
+
+425
+00:39:04,140 --> 00:39:07,140
+و هذه طريقة أساسية للناس اللي بيشتغلوا في الكيميا
+
+426
+00:39:07,140 --> 00:39:10,780
+في البروتينات و في ال amino acids بفصلوا من خلالها
+
+427
+00:39:10,780 --> 00:39:15,880
+هي فصل ال amino acids و فصل لبروتينات كهربيا
+
+428
+00:39:15,880 --> 00:39:22,080
+اعتمادا على ايش على شحنتهم الان شحنتهم تعتمد على
+
+429
+00:39:22,080 --> 00:39:28,540
+ال BH اذا انا بقدر اقول هو فصل كهربي لل amino
+
+430
+00:39:28,540 --> 00:39:33,400
+acids او لبروتينات اعتمادا على ال BH في المحصلة
+
+431
+00:39:34,600 --> 00:39:38,380
+واضح؟ هو الفصل اعتمادا على الشحنة انه يروح اشمال
+
+432
+00:39:38,380 --> 00:39:47,160
+او يمين، لكن الشحنة معتمدة على الـ BH ناخد مثالهذا
+
+433
+00:39:47,160 --> 00:39:50,120
+اللي سمناه الـ Electrophoresis is a method for
+
+434
+00:39:50,120 --> 00:39:53,620
+separating amino acids and proteins based on their
+
+435
+00:39:53,620 --> 00:39:58,380
+charge differences طبعا الـ isoelectric point عادة
+
+436
+00:39:58,380 --> 00:40:02,980
+بيعتور رمز بي لو قلنا ال isoelectric point
+
+437
+00:40:02,980 --> 00:40:10,460
+للأسبارتك أسد تلاتة تمام؟ الآن دائما جربوا أنتوا
+
+438
+00:40:10,460 --> 00:40:17,020
+ارسموا زي خط الأعدادتمام؟ الآن هذه الـ isoelectric
+
+439
+00:40:17,020 --> 00:40:24,380
+point للأسبارتك أسد اللي تلاتة عند BH تلاتة شو
+
+440
+00:40:24,380 --> 00:40:29,380
+بيكون الأسبارتك أسد؟ neutral بناء على ذلك لو حطينا
+
+441
+00:40:29,380 --> 00:40:35,640
+الأسبارتك أسد على BH3 و في وسطكهربائي كسودوانوت
+
+442
+00:40:35,640 --> 00:40:40,880
+هيتحرك؟ لأ هو الان بيجي بيسألني بيقول يا تورا على
+
+443
+00:40:40,880 --> 00:40:47,360
+BH5 وين هيروح؟ على الموجة الان انتبهوا معاه إيش
+
+444
+00:40:47,360 --> 00:40:51,840
+اللي عملوا قال طيب لو مخلوط عندي حامضين أسبارتك
+
+445
+00:40:51,840 --> 00:40:57,240
+أسد خلينا هيك نقول هذا الأسبارتك أسد ال BH ال
+
+446
+00:40:57,240 --> 00:41:02,900
+isoelectric point تبعته تلاتة مخلوط مع الألانين
+
+447
+00:41:05,540 --> 00:41:09,620
+القلانين عارفينه القلانين؟ قداش للقلانين ال
+
+448
+00:41:09,620 --> 00:41:18,120
+isoelectric point؟ ستة من الجدول ستة واضح؟ شفتوها؟
+
+449
+00:41:19,750 --> 00:41:25,710
+الالانين عند ستة بيكون متعادل، بتفرج على حاله، صح؟
+
+450
+00:41:25,710 --> 00:41:31,530
+والاسبارتك أسد عند تلاتة بيكون متعادل، بتفرج على
+
+451
+00:41:31,530 --> 00:41:36,390
+حاله، الآن لو إجيت قلت أطلع الاسبارتك أسد لوحده،
+
+452
+00:41:36,390 --> 00:41:43,230
+فوق التلاتة، شو بيكون؟ سالد، تحت التلاتة؟ موجب، لو
+
+453
+00:41:43,230 --> 00:41:45,250
+إجيت على الالانين
+
+454
+00:41:49,340 --> 00:41:56,080
+لو إجيت على الأنانين تحت الستة موجب فوق الستة سالب
+
+455
+00:41:56,080 --> 00:42:01,580
+الآن لو إجيت هدول الاتنين بدي أفصلهم عن بعض بضلني
+
+456
+00:42:01,580 --> 00:42:09,040
+أغير ال bh تغيير ذكي خليني أقول وصلت ال bh لخمسة
+
+457
+00:42:09,040 --> 00:42:15,340
+صار كل المحلول ال bh تبعته خمسة الآن قولولي أنتوا
+
+458
+00:42:15,340 --> 00:42:21,310
+عند خمسة شو بده يكون ال aspartic acid؟سالب فوق
+
+459
+00:42:21,310 --> 00:42:29,710
+التلاتة سالب واضح هيك موجب و عند ستة شو بده يكون
+
+460
+00:42:29,710 --> 00:42:34,150
+القلانين متعادل
+
+461
+00:42:34,150 --> 00:42:39,950
+عند ستة أقل من ستة موجب أعلى من ستة سالب الآن لما
+
+462
+00:42:39,950 --> 00:42:47,400
+أجي أقولكوا عند الخمسة هناتطلعوا معي الألانين موجب
+
+463
+00:42:47,400 --> 00:42:52,300
+الأسبارتك أسد سالب بناء على ذلك هذا الخليط لو
+
+464
+00:42:52,300 --> 00:42:56,500
+اتحكمت في ال بي اتش تبعته خليتها خمسة و حطيت له
+
+465
+00:42:56,500 --> 00:43:01,580
+قطبين كهربا وين هيروح الأسبارتك أسد على قطب الموجب
+
+466
+00:43:01,580 --> 00:43:05,700
+وين هيروح الألانين على قطب السالب انفصلوا عن بعض
+
+467
+00:43:05,700 --> 00:43:12,460
+ولا لأبنفصله طالما طلع هنا مختلف إذا بينفصله طيب
+
+468
+00:43:12,460 --> 00:43:17,780
+الآن انتبهوا معي جيدا حتى نفهم الطريقة بالظبط طبعا
+
+469
+00:43:17,780 --> 00:43:20,460
+احنا قولنا ال aspartic acid فوق التلاتة إيه شو بده
+
+470
+00:43:20,460 --> 00:43:26,040
+يكون؟ تلاتة و ال alanine تحت الستة شو بده يكون؟
+
+471
+00:43:26,040 --> 00:43:32,160
+موجة موجة الآن الإنسان اللي مش ذكي و بده يفصل هدول
+
+472
+00:43:32,160 --> 00:43:42,040
+عن بعضبنقوله اخترنا بي اتش مناسبة للفصل اذا حد اجى
+
+473
+00:43:42,040 --> 00:43:46,600
+جال انا والله بدي اخلي ال بي اتش تبعتهم اتنين ايش
+
+474
+00:43:46,600 --> 00:43:51,020
+رأيكوا؟ اتطلعوا
+
+475
+00:43:51,020 --> 00:43:54,780
+عما عند التنين، التنين موجبين، مش هيفصلوا
+
+476
+00:43:57,210 --> 00:44:01,510
+الان لو اجه واحد قال لأ و الله انا بدي افصلهم عند
+
+477
+00:44:01,510 --> 00:44:07,370
+BH تمانية اتنين سالب اذا اللي بده يختار ال BH
+
+478
+00:44:07,370 --> 00:44:12,850
+المناسبة لفصلهم لازم يختارها بين إيش؟ في المنطقة
+
+479
+00:44:12,850 --> 00:44:16,620
+اللي بيختلفوا فيهاشفتوا كيف لما بنفصل two amino
+
+480
+00:44:16,620 --> 00:44:23,400
+acids عن بعض بحط خط الأعداد باجلة الأول بعمل موجب
+
+481
+00:44:23,400 --> 00:44:27,940
+أقل من ال isoelectric point سالب أكتر باجلة التاني
+
+482
+00:44:27,940 --> 00:44:32,700
+نفس الاشي هاي ال isoelectric point أقل منها موجب
+
+483
+00:44:32,700 --> 00:44:38,500
+أكتر منها سالب الآن ال BH اللي بتفصل اللي بيختلفوا
+
+484
+00:44:38,500 --> 00:44:45,010
+فيهايعني أي BH بين التلاتة والستة بيكون فيها هذا
+
+485
+00:44:45,010 --> 00:44:49,890
+سالب وبيكون فيها هذا موجب تصبح للفصل لكن لو قولت
+
+486
+00:44:49,890 --> 00:44:53,550
+أقل من التلاتة التانين موجبين لو قولت أعلى من
+
+487
+00:44:53,550 --> 00:44:59,590
+الستة التانين سالبين ولذلك لما نعطي مثال ونقول
+
+488
+00:44:59,590 --> 00:45:04,470
+choose the appropriate BH for separating this
+
+489
+00:45:04,470 --> 00:45:12,380
+mixtureبدي أرسم خط الأعداد بيصير الأمر سهل جدا،
+
+490
+00:45:12,380 --> 00:45:20,280
+واضح؟ خلّيني أخد مثال تاني، هذا المثال التاني قال
+
+491
+00:45:20,280 --> 00:45:27,840
+بدنا تفصلونا ل glycine و lycine، طبعا أنا أسهل إشي
+
+492
+00:45:27,840 --> 00:45:33,390
+عندىان اعمل خط الاعداد اتخيل اني بدي احط ال
+
+493
+00:45:33,390 --> 00:45:39,210
+glycine مثلا هنا وال glycine هنا الان هيلزمني من
+
+494
+00:45:39,210 --> 00:45:45,830
+الجداول جداش ال isoelectric point لل glycine احنا
+
+495
+00:45:45,830 --> 00:45:54,610
+احفظنا لل glycine 6 ممتاز طب لل glycine مين شفتلنا
+
+496
+00:45:54,610 --> 00:45:56,290
+إياها 9.7
+
+497
+00:46:00,380 --> 00:46:05,780
+هذه تسعة و سبعة واضح؟ ارسموا بهذا الشكل و تحلوا
+
+498
+00:46:05,780 --> 00:46:08,860
+المسألة معاكم سهولة هاي ال glycine له ال
+
+499
+00:46:08,860 --> 00:46:12,480
+isoelectric point ستة ال glycine تسعة و سبعة الآن
+
+500
+00:46:12,480 --> 00:46:18,780
+بعد هيك هذه النقطة اللي بيكون عندها neutral أقل
+
+501
+00:46:18,780 --> 00:46:26,500
+منها أعلى منها سالم واضح؟ الآن بالنسبة لل glycine
+
+502
+00:46:26,500 --> 00:46:30,750
+هذه النقطة اللي بيكون عندها neutralneutral اقل
+
+503
+00:46:30,750 --> 00:46:35,030
+منها موجب
+
+504
+00:46:35,030 --> 00:46:42,010
+اعلى منها سالم الان لما اجي انا اقول لو انا بدي
+
+505
+00:46:42,010 --> 00:46:48,390
+افصلهم اي BH بتنفع معاه السبعة ممتازة التمانية
+
+506
+00:46:48,390 --> 00:46:54,440
+ممتازة بين الستةو التسعة و سبعة بين ال isoelectric
+
+507
+00:46:54,440 --> 00:46:59,160
+points تبعتهم واضح لكن لو أخدت أقل من الستة
+
+508
+00:46:59,160 --> 00:47:03,020
+التانين في موجبين مش هيفصلوا التانين موجب يعني
+
+509
+00:47:03,020 --> 00:47:06,380
+التانين هيروحوا على ال cathode و لو أخدت أكتر من
+
+510
+00:47:06,380 --> 00:47:09,660
+التسعة و سبعة تانين سالم التانين هيروحوا على ال
+
+511
+00:47:09,660 --> 00:47:13,190
+anode مع بعض مش هيفصلوافانا بتطلع وين بيكونوا
+
+512
+00:47:13,190 --> 00:47:17,670
+مختلفين باخد I BH مناسبة عادة بياخدوها ال between
+
+513
+00:47:17,670 --> 00:47:21,850
+الناس اللي بيشتغلوا طبعا بهذه الطريقة ممكن نفصل
+
+514
+00:47:21,850 --> 00:47:26,400
+كمان مش بس اتنيناكتر من اتنين تلاتة او اربعة او
+
+515
+00:47:26,400 --> 00:47:31,740
+خمسة احيانا لما بيعملوا الفصل بيفصلوا واحد بيودوه
+
+516
+00:47:31,740 --> 00:47:34,980
+على السالب و اتنين مع بعض على الموجة بعد ذلك
+
+517
+00:47:34,980 --> 00:47:39,000
+الاتنين اللي ودوه مع الموجة يعيدوا الفصل انا مش
+
+518
+00:47:39,000 --> 00:47:43,120
+هنحول احنا الى ايش الى مختبر يعني احنا بيكفينا
+
+519
+00:47:43,120 --> 00:47:47,860
+الفكرة العامة بتاعة الفكرة العامة صارت واضحة شهو
+
+520
+00:47:47,860 --> 00:47:52,640
+ال ال Electrophoresis هو طريقة لفصل ال amino acids
+
+521
+00:47:52,640 --> 00:47:59,580
+و البروتيناتاعتمادا على ال بي اتش ال بي اتش هي
+
+522
+00:47:59,580 --> 00:48:07,020
+اللي بتغير ايش الشحنات و بتوجه كل واحد باتجاه مجال
+
+523
+00:48:07,020 --> 00:48:12,640
+كهربي محدد ابهيك بننهي المرة اللي جاي بنبدأ في
+
+524
+00:48:12,640 --> 00:48:14,880
+تفاعلات ال amino acids
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6247ab8a90e2d4c0798fb1802df11fcfc6344b16
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs.srt
@@ -0,0 +1,1440 @@
+
+1
+00:00:19,620 --> 00:00:25,000
+بسم الله الرحمن الرحيم ما زلنا احنا بنتكلم في موضوع
+
+2
+00:00:25,000 --> 00:00:28,880
+الأحماض ومشتقاتها المرة الماضية اتكلمنا عن ال E
+
+3
+00:00:28,880 --> 00:00:34,940
+-stars وطرق تحضيرهم وبدأنا في موضوع تفاعلات ال E
+
+4
+00:00:34,940 --> 00:00:40,040
+-stars قولنا أول شيء أن التفاعل الأساسي اللي
+
+5
+00:00:40,040 --> 00:00:44,520
+هيتكرر معنا في كل هذا الفصل للأحماض وجميع مشتقاتها
+
+6
+00:00:44,520 --> 00:00:49,020
+وتفاعل الإجدال فكان أول تفاعل أخدناه عن ال E-stars
+
+7
+00:00:49,020 --> 00:00:54,430
+ال ammonolysis يعني أن نبدل ال OR ب نيتروجين
+
+8
+00:00:54,430 --> 00:01:00,210
+وبالتالي بيطلع عندنا أمد وشوفنا كيف مثلا اتكون ال
+
+9
+00:01:00,210 --> 00:01:03,870
+بنز أمد الأسيتامد ما إلى ذلك في نهاية
+
+10
+00:01:03,870 --> 00:01:09,210
+اليوكليوفيليك substitution الآن من التفاعلات
+
+11
+00:01:09,210 --> 00:01:15,190
+التانية من التفاعلات التانية لل E stars الريدكشن
+
+12
+00:01:15,190 --> 00:01:20,230
+الريدكشن بالليثيوم الومنوم هايدرايد سبق احنا
+
+13
+00:01:20,230 --> 00:01:24,810
+اتعرفنا حقيقة على الليثيوم الومنوم هايدرايد قولنا
+
+14
+00:01:24,810 --> 00:01:30,980
+الاساس اللي فيه الاساس اللي فيه هو ال H-يعني انا
+
+15
+00:01:30,980 --> 00:01:35,320
+اللى بدى استفيده من ال hydride H minus الان
+
+16
+00:01:35,320 --> 00:01:41,260
+بدكوا تتخيلوا ان ال H minus بدها تهاجم على هذا ال
+
+17
+00:01:41,260 --> 00:01:45,120
+Easter بدها تهاجم على هذا ال Easter شو بدها تعمل
+
+18
+00:01:45,120 --> 00:01:51,680
+ابدا مكان ال OR بناء على ذلك الناتج اللى بده يطلع
+
+19
+00:01:51,680 --> 00:01:57,460
+عندكم بالدرجة الأولى R C double bond O H
+
+20
+00:02:00,330 --> 00:02:06,850
+واضح؟ شيلنا ال OR و حطينا ال H طبعا إذا بتلاحظوا
+
+21
+00:02:06,850 --> 00:02:12,330
+هذا ال ناتج اللي اتكون عندى هو عبارة عن ال الديهيد
+
+22
+00:02:12,330 --> 00:02:17,570
+احنا أخدنا في chapter ال الديهيد و ال ketones ان
+
+23
+00:02:17,570 --> 00:02:22,310
+ال الديهيد و ال ketones بيتفاعلوا مع ال hydride
+
+24
+00:02:22,890 --> 00:02:27,170
+الالديهيدز بتعطيني ال primary alcohol و ال ketone
+
+25
+00:02:27,170 --> 00:02:30,890
+ال secondary alcohol بناء على ذلك هذا ال الديهيدز
+
+26
+00:02:30,890 --> 00:02:36,670
+اللي اتكون هنا مرة تانية لو اجت فاعل مع ال H minus
+
+27
+00:02:36,670 --> 00:02:42,290
+الان هذا كان E star ال E star ايش تفاعله المميز
+
+28
+00:02:42,290 --> 00:02:44,250
+Substitution
+
+29
+00:02:46,570 --> 00:02:50,930
+لما عملت substitution صار ال الديهايد ال الديهايد
+
+30
+00:02:50,930 --> 00:02:56,990
+شو تفاعله addition هم الكلمتين تحكوليش غيرهم فقط
+
+31
+00:02:56,990 --> 00:03:01,890
+بسمع هنا substitution وهنا بسمع addition طالما هذا
+
+32
+00:03:01,890 --> 00:03:06,770
+الديهايد addition طبعا هتيجي H و سيضة بال bond O
+
+33
+00:03:06,770 --> 00:03:11,090
+شو تصير O H هذا التفاعل سبق أخدنا الديهايد مع ال
+
+34
+00:03:11,090 --> 00:03:16,990
+hydride بيعمل addition والنتيجة هتكون إيشprimary
+
+35
+00:03:16,990 --> 00:03:22,810
+alcohol إذا لو أنا أخدت التفاعل بالمجمل تفاعل ال
+
+36
+00:03:22,810 --> 00:03:28,750
+eastern مع ال hydride بينتهي في النهاية ب primary
+
+37
+00:03:28,750 --> 00:03:33,090
+alcohol لكن ننتبه أنه مرورا بال aldehyde الآن هذا
+
+38
+00:03:33,090 --> 00:03:38,110
+ال aldehyde لا يفصلواضح؟ يعني بنفعل بتكون ال
+
+39
+00:03:38,110 --> 00:03:41,990
+الديهايد ع طول بلاجة اتش تانية يتفعل معاها بيصفى
+
+40
+00:03:41,990 --> 00:03:46,650
+primary alcohol عشان هيك هذا الكلام حتى نكون
+
+41
+00:03:46,650 --> 00:03:50,910
+فاهمين بالظبط إيش اللي صار معنا لكن بدل المرة ألف
+
+42
+00:03:50,910 --> 00:03:55,410
+بقول لو قلتلكوا أكمل المعادلة أكمل الفراغ بدي
+
+43
+00:03:55,410 --> 00:04:00,640
+Easterمع hydride في النهاية انا بده اشوف ال
+
+44
+00:04:00,640 --> 00:04:03,620
+primary alcohol ربما لهذا السبب انتوا شايفين
+
+45
+00:04:03,620 --> 00:04:07,580
+المعادلة في نهايتها ايش؟ primary alcohol لكن هي في
+
+46
+00:04:07,580 --> 00:04:13,440
+تفصيلها كام خطوة؟ خطوتين هي في تفصيلها خطوتين
+
+47
+00:04:13,440 --> 00:04:18,980
+إبدال كون ال aldehyde و بعدين إضافة كونت ال
+
+48
+00:04:18,980 --> 00:04:25,150
+primary alcohol واضحة الفكرة؟الان زى هذا التفاعل
+
+49
+00:04:25,150 --> 00:04:31,970
+تماما زى هذا التفاعل تماما لو يا تورا اجينا فعلنا
+
+50
+00:04:31,970 --> 00:04:35,890
+و هذا مش مكتوب عندكوا لكن بنضيفه عليكم لو اجينا
+
+51
+00:04:35,890 --> 00:04:42,590
+فعلنا ال Easter مش مع H minus مع R minus طبعا اللى
+
+52
+00:04:42,590 --> 00:04:47,890
+بنقصده في R بهدى الحالة ايش ال green yard reagent
+
+53
+00:04:47,890 --> 00:04:59,080
+ال Rمجي اكس مصدر لل R مينوس مظبوط ولا لأ هيحط R
+
+54
+00:04:59,080 --> 00:05:05,220
+مرتين فى المرة الأولى شو هيحط هنا R كوّن لك
+
+55
+00:05:05,220 --> 00:05:13,140
+الكيتون الان كمان مرة R تانية نشيل هدول ال chain
+
+56
+00:05:13,140 --> 00:05:18,820
+اللى كانوا من ال hydride نحط R وR
+
+57
+00:05:20,670 --> 00:05:26,770
+إذا في هذه الحالة التفاعل مع جرينيارد شو بيعطيني
+
+58
+00:05:26,770 --> 00:05:32,210
+تيرتشاري ألكول لأن R كانت أصلا من ال Easter وتنتين
+
+59
+00:05:32,210 --> 00:05:35,210
+متشابهات اتجوا من الجرينيارد يعني لو افترضنا مثلا
+
+60
+00:05:35,210 --> 00:05:39,990
+أن هذه كانت فنل وفعلت
+
+61
+00:05:39,990 --> 00:05:44,130
+مع إيثل ماجنيسيا مبروماي على مرتين أول مرة هيحق
+
+62
+00:05:44,130 --> 00:05:51,170
+إيثل و تاني مرة كمان إيثل إذا ال Easterفي المحصلة
+
+63
+00:05:51,170 --> 00:05:59,510
+مع الـ Greenyard reagent بدوا يعطيني تيرتشاريه
+
+64
+00:05:59,510 --> 00:06:05,710
+الكهول تماما نفس التفاعل اللي مع الهيدرايد لكن بدل
+
+65
+00:06:05,710 --> 00:06:10,210
+ما كنت بضيف H- مرتين يعني مرة بالإبدال و مرة
+
+66
+00:06:10,210 --> 00:06:21,410
+بالإضافة بحط R- مرتين واضح بحط ال R- مرتينلاحظوا
+
+67
+00:06:21,410 --> 00:06:27,030
+معي للناس اللي بيحاولوا يفهموا الأمور بصورتها
+
+68
+00:06:27,030 --> 00:06:31,730
+الكلية للناس اللي بيحاولوا يفهموا الأمور بصورتها
+
+69
+00:06:31,730 --> 00:06:38,410
+الكلية السهلة مش بالمسميات الضيقة الآن هذا Easter
+
+70
+00:06:38,410 --> 00:06:43,130
+اعملتله انا تفاعلين و اتعمت لما عرفتهم التفاعل
+
+71
+00:06:43,130 --> 00:06:43,670
+الأول
+
+72
+00:06:47,190 --> 00:06:51,550
+الـ Hydrides و أعطاني Primary Alcohols و التفاعل
+
+73
+00:06:51,550 --> 00:06:54,790
+التالي معي Green Yard Reagent و أعطاني Tertiary
+
+74
+00:06:54,790 --> 00:06:59,530
+Alcohol مرورا بالكيتون في هذه الحالة الآن هذه
+
+75
+00:06:59,530 --> 00:07:07,070
+المجموعة الـ OR مجموعة إيه شمالها؟مطرودة طردت جيبت
+
+76
+00:07:07,070 --> 00:07:14,170
+سيرتها لأ طيب يا تورا لو بعد شوية أخدنا ال acid
+
+77
+00:07:14,170 --> 00:07:19,090
+halides بمعنى ماكناش نبدأ ب E star و المجموعة
+
+78
+00:07:19,090 --> 00:07:23,670
+المطرودة OR كان عندنا acid halide كان تادي CL أو
+
+79
+00:07:23,670 --> 00:07:32,570
+PR و إجيت قولت تفاعل ال acid halide مع ال hydrides
+
+80
+00:07:32,570 --> 00:07:40,530
+شو هيعطيلي؟نفس الكلام تماماً لأنه طردت OR أو طردت
+
+81
+00:07:40,530 --> 00:07:45,310
+CL وباقي الناتج زي ما هو ال primary alcohol تفاعل
+
+82
+00:07:45,310 --> 00:07:50,170
+acid halide مع grignard reagent tertiary alcohol
+
+83
+00:07:50,170 --> 00:07:54,890
+واضح؟ شو بديفرق التفاعل إذا كانت المجموعة اللي
+
+84
+00:07:54,890 --> 00:07:59,810
+طردت OR و أخدت H طلعت على شكل alcohol ولا CL minus
+
+85
+00:07:59,810 --> 00:08:06,360
+و أخدت H طلعت على HCLواضح؟ وعشان هيك اللي بيعرف
+
+86
+00:08:06,360 --> 00:08:10,240
+أنه ال Easter بتفاعل مع ال hydrates ومع greenery
+
+87
+00:08:10,240 --> 00:08:15,880
+agent بطريقة معينة بنقوله كمان و ال acid chlorides
+
+88
+00:08:15,880 --> 00:08:21,970
+بتفاعلوا مع ال hydrates ومع greenery agentبنفس
+
+89
+00:08:21,970 --> 00:08:27,090
+الطريقة تماما مافرجش انه يكونش المجموعة المطرودة
+
+90
+00:08:27,090 --> 00:08:31,710
+هي OR ولا CL هذه مجموعة مطرودة لكن الجزء ال
+
+91
+00:08:31,710 --> 00:08:36,870
+organic اللي عندى جزء اشماله ثابت واضح الفكرة
+
+92
+00:08:49,670 --> 00:08:55,890
+الان بننتقل ل ال acid halides ال acid halides قلنا
+
+93
+00:08:55,890 --> 00:09:00,290
+عنهم مشتقات ايضا من الأحماض و لما اتكلمنا عن
+
+94
+00:09:00,290 --> 00:09:06,030
+تفاعلات الأحماض اتكلمنا عن تحضيرهم قلنا اذا أخدنا
+
+95
+00:09:06,030 --> 00:09:10,990
+ال organic acid مع ال phosphorus trichloride او ال
+
+96
+00:09:10,990 --> 00:09:20,920
+SOCl2 يهدي يهدي بيشيل ال OH و بيحطلهCL فال acid
+
+97
+00:09:20,920 --> 00:09:25,480
+بتحول الى acid chlorides طريقة التحضير طريقة ايش
+
+98
+00:09:25,480 --> 00:09:31,600
+سهلة الان لو اجينا للتسمية كيف بنسمي ال acid
+
+99
+00:09:31,600 --> 00:09:39,190
+halides احنا كان هنا في عندنا OECacid الآن بدنا
+
+100
+00:09:39,190 --> 00:09:44,930
+نغير كلمة acid بكلمة halide بدنا نغير كلمة acid
+
+101
+00:09:44,930 --> 00:09:49,790
+بكلمة halide و ال oic بنخليها oil يعني لو أخدنا
+
+102
+00:09:49,790 --> 00:09:56,510
+ethanoic acid اللي هو الحامض اللي من carbon 10 بدو
+
+103
+00:09:56,510 --> 00:10:02,350
+يصير ethanoic chloride لو هنا bromالبروميد لو
+
+104
+00:10:02,350 --> 00:10:07,770
+أخدنا ال common name تبعه acidic acid بس بنشيل ايش
+
+105
+00:10:07,770 --> 00:10:13,490
+كلمة acid و بنحط chloride فهذا المركب ايش بيصير
+
+106
+00:10:13,490 --> 00:10:19,750
+Acetyl لأ بنرجع للمجموعة YL Acetic منها Acetyl
+
+107
+00:10:19,750 --> 00:10:27,400
+واضح لأن هذه اتعرفنا عليها Acetylمتذكرينها؟ أسيتل
+
+108
+00:10:27,400 --> 00:10:33,560
+و بنكتب إيش؟ أكلورايد فالفكرة بدنا نشيل هذا جزء
+
+109
+00:10:33,560 --> 00:10:39,000
+الأسيتل و ننهب وي الهلايد أسيتل أكلورايد و منها
+
+110
+00:10:39,000 --> 00:10:43,380
+كمان سبق إن اتعرفنا على مجموعة ال بنزويل من وين
+
+111
+00:10:43,380 --> 00:10:48,920
+بنجيب ال بنزويل أكلورايد؟ لو أجينا سألناكم بنزويل
+
+112
+00:10:48,920 --> 00:10:54,300
+أكلورايد بدنا نجيبه من؟
+
+113
+00:10:55,720 --> 00:11:03,440
+البنزويك أسد C double bond O OH في ال BCL3 أو أي
+
+114
+00:11:03,440 --> 00:11:07,640
+حاجة C
+
+115
+00:11:07,640 --> 00:11:14,360
+double bond O Cl هذا إيش بده يصير بنزويل لإن هذه
+
+116
+00:11:14,360 --> 00:11:19,900
+مجموعة البنزويل فنل C double bond O بنزويل
+
+117
+00:11:19,900 --> 00:11:29,870
+إكلورايدوالبنزول كمجموعة مرات بتختصر بي زد هيك
+
+118
+00:11:29,870 --> 00:11:35,250
+بنزول إكلورايد فإذا قرأته كلمة بي زد هذا اختصار
+
+119
+00:11:35,250 --> 00:11:40,330
+إيش بنزول بنزول إكلورايد واللي علمكوا ال بنزول
+
+120
+00:11:40,330 --> 00:11:45,230
+جالكوا تذكروا أنه في إلها بنت عم بتشبهها في
+
+121
+00:11:45,230 --> 00:11:49,510
+الكتابة اللي هي بنزل إكلورايد بس ال بنزل إكلورايد
+
+122
+00:11:49,510 --> 00:11:57,190
+عبارة عنفين ال CH2 نفترض CH2 فين ال CH2 هذه مجموعة
+
+123
+00:11:57,190 --> 00:12:06,230
+البنزل مش بنزايل بنزل طبعا لو جيت سألكوا البنزل
+
+124
+00:12:06,230 --> 00:12:11,650
+كلورايد كهيلايد أي نوع من الهيلايد primary
+
+125
+00:12:11,650 --> 00:12:12,890
+alkalihilide
+
+126
+00:12:16,310 --> 00:12:21,030
+الكل واضح ماحدش ييجي يشوف هنا ال aromatic ويقول
+
+127
+00:12:21,030 --> 00:12:24,630
+عنه aromatic halide لأ هو ال aromatic halide لو
+
+128
+00:12:24,630 --> 00:12:29,370
+كانت ال CL متصلة مباشرة بالحلقة لكن طالما ال CL
+
+129
+00:12:29,370 --> 00:12:34,930
+متصلة ب CH2 إذا هذا الكل halide وبناء على ذلك بتيم
+
+130
+00:12:34,930 --> 00:12:37,970
+عليكوا التفاعلات الإبدال اللي درسناها في شبتر 6
+
+131
+00:12:37,970 --> 00:12:42,070
+ولا لأ اه فهذا بنزل chloride
+
+132
+00:12:43,690 --> 00:12:47,390
+فبفرق بنزل الكلورايد عن بنزول الكلورايد وبنزل الى
+
+133
+00:12:47,390 --> 00:12:52,650
+اختصار بيختصرها BN واضح
+
+134
+00:12:52,650 --> 00:13:01,050
+بيختصرها BN بنزل فننتبه لهدول المجموعتين هذا ال
+
+135
+00:13:01,050 --> 00:13:07,150
+بنزول الكلورايد يعني إذا بدنا نوصفه بنقول عنه انه
+
+136
+00:13:07,150 --> 00:13:16,970
+إيش انه لعينليش بنوصف بهذا الوصف القاسي؟ لأن هذا
+
+137
+00:13:16,970 --> 00:13:22,430
+اللي هو عادة يستعمل كغاز مسيل للدموع يعني بتعرفوا
+
+138
+00:13:22,430 --> 00:13:27,630
+الغازات اللي في المظاهرات وغيرها، الغازات المسيلة
+
+139
+00:13:27,630 --> 00:13:34,930
+للدموع، معظمها acid halides، ومن ضمنهاالبنزول
+
+140
+00:13:34,930 --> 00:13:40,230
+الكلورايد من ضمنها البنزول الكلورايد طبعا لو اجينا
+
+141
+00:13:40,230 --> 00:13:45,850
+نقول ايش السبب ايش السبب ان هذا البنزول الكلورايد
+
+142
+00:13:45,850 --> 00:13:53,110
+يستعمل كغاز مسيل للدموع ناخد احنا بشكل عام
+
+143
+00:13:53,110 --> 00:13:58,330
+الكلورايد و تفاعلاتها ناخد بشكل عام الكلورايد و
+
+144
+00:13:58,330 --> 00:14:03,550
+تفاعلاتها طبعا مرتان تفاعلات الكلورايد هي تفاعلات
+
+145
+00:14:05,010 --> 00:14:09,570
+الإبدال يعني ال acid chloride مجرد ما بديه يتعرض
+
+146
+00:14:09,570 --> 00:14:14,410
+للميه مجرد ما بديه يتعرض للميه بديه يفقد ال CL و
+
+147
+00:14:14,410 --> 00:14:21,470
+يحط ال OH رجع لإيش؟ لل carboxylic acid واضح؟من حد
+
+148
+00:14:21,470 --> 00:14:25,590
+ما يتعرض للميه برجع ل acid لو فعلنا مع ال ethanol
+
+149
+00:14:25,590 --> 00:14:32,050
+بدو يشيل ال CL ويحط O-ethyl برجع ل E-star لو فعلنا
+
+150
+00:14:32,050 --> 00:14:37,890
+مع ال ammonia بدو يشيل ال CL ويحط NH2 بصير أمل فزي
+
+151
+00:14:37,890 --> 00:14:41,770
+ما اتفقنا أنه من واحد بنحضر التاني الآن خلينا على
+
+152
+00:14:41,770 --> 00:14:47,480
+المعادلة الأولىخلّينا على المعادلة الأولى و نتخيل
+
+153
+00:14:47,480 --> 00:14:52,020
+مثلا أنه إحنا اللي بدين فيه ال benzoyl chloride
+
+154
+00:14:52,020 --> 00:14:54,920
+اللي هو إيش موجود فيه بدل ال acetyl chloride هنا
+
+155
+00:14:55,790 --> 00:15:00,610
+فنل سيبا بالبوند OCL هذا البيزويل الكلوري
+
+156
+00:15:00,610 --> 00:15:06,190
+بيستعملوه كغاز مصير للدموع الآن السؤال هل هو غاز
+
+157
+00:15:06,190 --> 00:15:13,310
+أصلا لأ هو مادة زيتية يعني مادة
+
+158
+00:15:15,850 --> 00:15:22,150
+بحرارة غليان فوق المية درجة مئوية لكن لما بيرموه
+
+159
+00:15:22,150 --> 00:15:27,130
+في الجو بيطلع على شكل .. بيطلع على شكل رذاذ صغير
+
+160
+00:15:27,130 --> 00:15:31,350
+فبييجي على الناس بيبدو الناس يشموه بييجي على وجههم
+
+161
+00:15:31,350 --> 00:15:37,250
+يعني عملية قذفهفي الجو بيخليه يطلع على شكل إيش؟
+
+162
+00:15:37,250 --> 00:15:42,470
+رذاذ، رذاذ صغير، الآن هذا الرذاذ الصغير اللي طلع
+
+163
+00:15:42,470 --> 00:15:49,750
+لو دخل على جسم الإنسان، هيدخل على الزور، هيجي على
+
+164
+00:15:49,750 --> 00:15:56,450
+العنين، شكل أساسي، الآن الزور و العنين فيهم مياه
+
+165
+00:15:57,990 --> 00:16:03,730
+إذا وجدت أنا هأعمل تفاعل البنزويلي كلوراي مع الميه
+
+166
+00:16:03,730 --> 00:16:09,590
+هطلع بنزويك أسد البنزويك أسد حمضه ضعيف مش منه
+
+167
+00:16:09,590 --> 00:16:16,350
+المشكلة لكن المشكلة أكتر من ال HCL ال HCL هو اللي
+
+168
+00:16:16,350 --> 00:16:22,950
+هيسبب الحرقان في العينين وفي الزور واضح ال HCL
+
+169
+00:16:22,950 --> 00:16:31,010
+الآن هذا نفسه لو إجه على الجلدمافيش منه مشكلة إذا
+
+170
+00:16:31,010 --> 00:16:34,350
+الجلد جافلكن بتعرفوا الناس اللي بيكونوا في
+
+171
+00:16:34,350 --> 00:16:39,010
+المظاهرات مرات بيكونوا عرقانين اه لو اجى معي العرق
+
+172
+00:16:39,010 --> 00:16:43,630
+و اجي اتعمل HCL بيصير الجلد يحرج لو افترضنا ان
+
+173
+00:16:43,630 --> 00:16:49,310
+البني ادم اللي كان في المظ
+
+223
+00:21:21,390 --> 00:21:28,510
+إذا كانت symmetrical ethers و unsymmetrical ethers
+
+224
+00:21:28,510 --> 00:21:33,090
+الـR و الـR زي بعض هذا سمنا إيش؟ symmetrical ether
+
+225
+00:21:33,090 --> 00:21:38,030
+و لذلك لما كنا مثلا بدنا نضاي إيثل إيثر كنا ناخد
+
+226
+00:21:38,030 --> 00:21:42,370
+الكحول مش الحامض في النهاية في OH اللي هو على سبيل
+
+227
+00:21:42,370 --> 00:21:50,450
+المثال لو أخدنا الإيثانول بنسبة 2 مع H plus هو نفس
+
+228
+00:21:50,450 --> 00:21:58,660
+الفكرة تماما إيش كان هذا يعطينا؟ إيثل أو Diethyl
+
+229
+00:21:58,660 --> 00:22:03,100
+ether من
+
+230
+00:22:03,100 --> 00:22:09,660
+الكحول و Diethyl ether is symmetrical ether
+
+231
+00:22:11,320 --> 00:22:14,800
+شوف نقاش ال symmetrical فالكحول بيتفاعل مع نفسه
+
+232
+00:22:14,800 --> 00:22:19,800
+جوزيق بيهاجم على التاني و بيطرده مية و بتفاعله
+
+233
+00:22:19,800 --> 00:22:25,960
+الان الكلام نفسه بتم مع ال unhydrates لكن في هذه
+
+234
+00:22:25,960 --> 00:22:32,280
+الحالة الحامض بيتفاعل مع نفسه واضح؟ في هذه الحالة
+
+235
+00:22:32,280 --> 00:22:36,680
+الحامض يتفاعل مع نفسه يعني احنا اليوم موضوعنا ال
+
+236
+00:22:36,680 --> 00:22:41,000
+unhydrates لو بدأ اركز اكثر عليها بدأ اقول تخيلوا
+
+237
+00:22:41,000 --> 00:22:47,120
+ان هذا جزيق حامض بدأ افعله مع ايش؟ مع جزيق تاني
+
+238
+00:22:47,120 --> 00:22:54,980
+اللي هو OH سيضة بال bond O نفترض CH3 هاي Acetic
+
+239
+00:22:54,980 --> 00:23:00,040
+Acid جزئ و هاي Acetic Acid كمان جزئ هاي الجزئين
+
+240
+00:23:00,040 --> 00:23:04,740
+خلصنا واضح؟ الآن هذا بده ييجي من خلال الـ OH اللي
+
+241
+00:23:04,740 --> 00:23:10,620
+هي الـ nucleophile إهاجمها يطرد الـ OH هذا تفاعل
+
+242
+00:23:10,620 --> 00:23:15,380
+الإبدال ولا لأ؟ هذا تفاعل الإبدال بناء على ذلك لما
+
+243
+00:23:15,380 --> 00:23:18,920
+تطرد الـ OH من هنا مع الـ H هذه
+
+244
+00:23:21,660 --> 00:23:29,940
+الجزء الأول اللي مبين بالأسود هي CH3COO
+
+245
+00:23:29,940 --> 00:23:35,100
+والجزء التاني OCOO
+
+246
+00:23:36,520 --> 00:23:42,080
+CH3 هيتكون عندى الـ Symmetrical Anhydride اتكون
+
+247
+00:23:42,080 --> 00:23:46,840
+عندى الـ Symmetrical Anhydride لاحظوا انه مجموعة
+
+248
+00:23:46,840 --> 00:23:52,840
+الانهيدريد كمجموعة عبارة عن ايش C double bond O O
+
+249
+00:23:52,840 --> 00:23:57,580
+C double bond O يعني لو بدى اقول ال ether كانت O
+
+250
+00:23:57,580 --> 00:24:03,620
+متصلة بتنتين R طيب الانهيدريد هى
+
+251
+00:24:06,590 --> 00:24:13,350
+هذه ثابتة C double bond O O C double bond O هذه
+
+252
+00:24:13,350 --> 00:24:17,670
+مجموعة الانهيدريد الآن لما فعلت الحامض مع نفسه
+
+253
+00:24:17,670 --> 00:24:23,890
+صارت هذه ال R و هذه ال R زي بعض ولذلك سميت هذا
+
+254
+00:24:23,890 --> 00:24:28,530
+symmetrical anhydride الآن السؤال طب لو خلت هذه
+
+255
+00:24:28,530 --> 00:24:33,690
+مثل وهذه اثلبتصير Unsymmetrical لو خلّيت فينيل و
+
+256
+00:24:33,690 --> 00:24:40,130
+إثل Unsymmetrical طبعا بيلزمنا نسمي و نحضر ال
+
+257
+00:24:40,130 --> 00:24:43,210
+symmetrical anhydride و الunsymmetrical anhydride
+
+258
+00:24:43,210 --> 00:24:47,050
+تماما زي ما عملنا مع ال aether احنا قولنا ال
+
+259
+00:24:47,050 --> 00:24:49,870
+aether كان الكحول مع نفسه أعطاني symmetrical
+
+260
+00:24:49,870 --> 00:24:54,350
+aether الآن ال symmetrical anhydride الحامض مع
+
+261
+00:24:54,350 --> 00:24:57,350
+نفسه بنسخنه في وجود حمض
+
+262
+00:25:00,190 --> 00:25:06,170
+بش ان مش واضح بنسخنه في وجود حمض و طبعا بنتخلي
+
+263
+00:25:06,170 --> 00:25:09,610
+شروط التفاعل تسحب الميه للخارج ليش؟ لأن هذا
+
+264
+00:25:09,610 --> 00:25:13,510
+التفاعل ما عدا ذلك عكس بترد الميه تهاجمها و ترجع
+
+265
+00:25:13,510 --> 00:25:17,230
+لحمضين ولذلك اللي بيعمل unhydrate بيكون عنده طريقة
+
+266
+00:25:17,230 --> 00:25:22,160
+يسحب فيها الميه لوينل الخارج يتخلص منها طب الآن
+
+267
+00:25:22,160 --> 00:25:27,640
+هذا كيف بدي أسميه على اسم الحامض بشيل كلمة acid و
+
+268
+00:25:27,640 --> 00:25:32,880
+بكتب unhydrate يعني هذا لو سمناه ethanoic acid ال
+
+269
+00:25:32,880 --> 00:25:37,700
+unhydrate تبعه إيش بدي يصير ethanoic unhydrate طب
+
+270
+00:25:37,700 --> 00:25:43,820
+لو سمناه بال common name acetic acid إيش بدي يتسمى
+
+271
+00:25:44,770 --> 00:25:53,230
+acetic anhydride فالتسمية إن نشيل كلمة
+
+272
+00:25:53,230 --> 00:25:59,850
+acid ونحط anhydride واضح التسمية إن نشيل كلمة acid
+
+273
+00:25:59,850 --> 00:26:04,250
+ونحط إيش anhydride الحامض اللي فيه المثل هو
+
+274
+00:26:04,250 --> 00:26:12,990
+الacetic الان لو اجينا وقلنالكم لو سمحتوا ارسمولنا
+
+275
+00:26:12,990 --> 00:26:20,510
+المركب القاتل بنزوك unhydrate بنزوك
+
+276
+00:26:20,510 --> 00:26:29,870
+unhydrate اول اشي ع طول بدكم تحطولي ايش هي مجموعة
+
+277
+00:26:29,870 --> 00:26:35,670
+ال unhydrate مجموعة ال unhydrate C double bond O O
+
+278
+00:26:37,550 --> 00:26:42,130
+خلّينا نعملها هيك C double bond O تابع هذه مجموعة
+
+279
+00:26:42,130 --> 00:26:47,810
+الانهيدريد الآن إذا كانت بنزوك فنل معناه ذلك سأضع
+
+280
+00:26:47,810 --> 00:26:55,250
+على الجهتين مجموعة الفنل فنل و فنل هذه بنزوك
+
+281
+00:26:55,250 --> 00:27:00,350
+انهيدريد لما نقول أسيتك مثل و مثل المجموعة تبع
+
+282
+00:27:00,350 --> 00:27:02,550
+الأسيتك أسيتك بروبانوك
+
+283
+00:27:07,410 --> 00:27:12,490
+بدوا يكون المجموع تلاتة اه انتبهوا معاك خلصنا من
+
+284
+00:27:12,490 --> 00:27:20,310
+ال benzoic اه اه لو اتيتكن اتكتبلكم بروبانوك لأنه
+
+285
+00:27:20,310 --> 00:27:25,810
+مرات بيغلطوا الطلاب بهذه النقطة بروبانوك unhydrate
+
+286
+00:27:25,810 --> 00:27:33,950
+بدي الكربونات تلاتة هذه واحدة منهمهذه واحدة و لذلك
+
+287
+00:27:33,950 --> 00:27:38,310
+لما كان عند ال E ثانوك كنت بس حاطط ال CH3 المجموع
+
+288
+00:27:38,310 --> 00:27:45,430
+تنتين لما بدل بربانوك بدأ اكتب CH2 CH3 المجموع
+
+289
+00:27:45,430 --> 00:27:54,830
+تلاتة و هنا CH2 CH3 واضح فالمجموع تلاتة بربانوك و
+
+290
+00:27:54,830 --> 00:28:01,830
+مثلها بيوتانوك واضحة طيب الآن يا تورا الكلام شوفوا
+
+291
+00:28:01,830 --> 00:28:08,370
+كيف ما أسهل الكيميا ولا أمتعها بتفهم لحالها لو
+
+292
+00:28:08,370 --> 00:28:19,610
+إجيت و روحت كتبتلكم هنا CH3 و كتبتلكم هنا فنل و
+
+293
+00:28:19,610 --> 00:28:21,810
+قلتلكوا سموا هذا المركب
+
+294
+00:28:27,020 --> 00:28:34,240
+هذا مكون من كام حامض؟ هذا الحامض شو هو؟
+
+295
+00:28:42,280 --> 00:28:47,600
+جيد جيد هذا التردد .. هذا التردد بحل مشكلتك الناس
+
+296
+00:28:47,600 --> 00:28:50,380
+اللي سألوني عن الامتحان لأ في الامتحان مش عامليني
+
+297
+00:28:50,380 --> 00:28:55,120
+كويس لإن مصيرين ما تسمعوش نصيحتي إن إذا في الكيميا
+
+298
+00:28:55,120 --> 00:29:00,400
+ما طبقتوش و ما كتبتوش الجملة ألف مرة لن تتعلموا
+
+299
+00:29:00,400 --> 00:29:05,340
+كيميا تمام؟ لن تتعلموا كيميا هذا اللي فيه تنتين
+
+300
+00:29:05,340 --> 00:29:12,810
+اثانوك و بال common أسيتكمظبوط ولا لأ؟ هذا كحمد
+
+301
+00:29:12,810 --> 00:29:19,010
+CH3C double bond O إيش ماله؟ Acetic و هذا الفنل C
+
+302
+00:29:19,010 --> 00:29:23,430
+double bond O بنزوك و خلّيني أحطهم alphabetical
+
+303
+00:29:23,430 --> 00:29:28,190
+مين بيجي قبل ال Acetic ولا ال بنزوك؟ Acetic بنزوك
+
+304
+00:29:28,190 --> 00:29:29,850
+Unhydrate
+
+305
+00:29:31,620 --> 00:29:35,840
+واضح؟ بذكر اسم الحامضين و بحطه ممرتبين
+
+306
+00:29:35,840 --> 00:29:40,520
+alphabetically فبكون هيك اقدرت اسمي ال
+
+307
+00:29:40,520 --> 00:29:47,620
+unsymmetrical .. unhydrite .. واضح؟ أسيتك بنزوك
+
+308
+00:29:47,620 --> 00:29:51,080
+أنهايدرايد طبعا واحدة ممكن تقول ممكن نسميه إيثانوك
+
+309
+00:29:51,080 --> 00:29:56,060
+ممكن موادة كاربون تنتيل إيثانوك و أجي تبدأ تكتب
+
+310
+00:29:56,060 --> 00:30:01,740
+بنزوك إيثانوك أنهايدرايد عشان تحط ال B قبل ال E
+
+311
+00:30:01,740 --> 00:30:06,920
+alphabetical إذا إعرفنا كيف بنسمي الـ unsymmetrical
+
+312
+00:30:06,920 --> 00:30:12,680
+anhydride بذكر الحامضين alphabetically وإضافة
+
+313
+00:30:12,680 --> 00:30:18,860
+النهاية anhydride الآن إذا هذا الكلام إعرفنا كيف
+
+314
+00:30:18,860 --> 00:30:26,860
+نسميه، ضال كيف؟ انحضروه، ضال كيف انحضروه اللي
+
+315
+00:30:26,860 --> 00:30:34,400
+فاهمين ال ethers، إيش كنا نعمل فيهم؟ نفس الفكرة
+
+316
+00:30:34,400 --> 00:30:39,520
+تماما اللي اتذكره William Sun William Sun's
+
+317
+00:30:39,520 --> 00:30:44,320
+synthesis of ethers هل يا تورا كنت بقدر انا اجي
+
+318
+00:30:44,320 --> 00:30:55,280
+أقول Methanol زائد Ethanol بالحرارة و الحامض هذا
+
+319
+00:30:55,280 --> 00:31:01,790
+كام مركب كام Ether كان يعطيلي كان يعطيني تلاتة مثل
+
+320
+00:31:01,790 --> 00:31:11,130
+او مثل او اثل او اثل او مثل او اثل طب هتقول هذا ال
+
+321
+00:31:11,130 --> 00:31:16,610
+synthesis مقبول ولا لأ مرفوض في ال ethers مرفوض
+
+322
+00:31:16,610 --> 00:31:19,650
+لان انا بدي اطلع تلاتة و اقعد افصلهم طب كيف كنا
+
+323
+00:31:19,650 --> 00:31:24,810
+نعمل كنا نقول خلي واحد منهم يصير مثل او minus
+
+324
+00:31:24,810 --> 00:31:33,920
+التاني يصير اثل CLCH3 CH2 CL نبدل ال OH بCL مثلا
+
+325
+00:31:33,920 --> 00:31:39,000
+من PCL3 و بعدين نفعل هدول التنين مع بعض كانوا
+
+326
+00:31:39,000 --> 00:31:45,980
+بيعطوني بس المثل O Ethan واضح؟
+
+327
+00:31:45,980 --> 00:31:52,720
+واحد نخليه O minus والتاني نخليه CL و نخلطهم هيك
+
+328
+00:31:52,720 --> 00:32:00,300
+بيعطيني فقط ناتج واحد لا غير بضحك الفكرة؟ هذه إيش
+
+329
+00:32:00,300 --> 00:32:06,500
+كان اسمها؟ طريقة William Sun لتحضير ال ether الآن
+
+330
+00:32:06,500 --> 00:32:13,220
+لما بدي أحضر ال un-symmetrical unhydride نفسها
+
+331
+00:32:13,220 --> 00:32:19,520
+تماما 100% لكن بدل ما أنا مبتدئ بكحول في ال
+
+332
+00:32:19,520 --> 00:32:25,140
+unhydride بدي أبتدئ من إيش؟ من الـ Acid خلّيني أقول
+
+333
+00:32:25,140 --> 00:32:29,460
+بدي مثلا الـ Acetic Benzoic Anhydrate إذا إيش
+
+334
+00:32:29,460 --> 00:32:37,300
+الحامضين اللي بدي أبتدأ منهم Acetic Acid هاي CH3C
+
+335
+00:32:37,300 --> 00:32:44,280
+double bond O OH زائد Benzoic Acid Phenyl C double
+
+336
+00:32:44,280 --> 00:32:53,200
+bond O OH الآن لو خلطناهم بـ H Plus و Heat كم ناتج
+
+337
+00:32:53,200 --> 00:32:58,880
+الـ three products بنفع هذا الكلام مقبول اللي بعمل
+
+338
+00:32:58,880 --> 00:33:03,060
+زي هيك ايش بيكون بيشتغل غلط ال three products
+
+339
+00:33:03,060 --> 00:33:07,580
+موازية تماما لفكرة ال ethers الان واحد منهم بدنا
+
+340
+00:33:07,580 --> 00:33:11,220
+نخلي O minus نفترض هذا
+
+341
+00:33:13,840 --> 00:33:19,860
+CH3C double bond O O minus والتاني بدنا نخلي CL
+
+342
+00:33:19,860 --> 00:33:26,220
+فنل C double bond O CL هدولة لما نخلطهم بده يطلع
+
+343
+00:33:26,220 --> 00:33:33,700
+عندنا ناتج واحد فقط نرسمها CH3C double bond O O C
+
+344
+00:33:33,700 --> 00:33:41,680
+double bond O فنل على أساس أن هذه بتهاجمها و بتطرد
+
+345
+00:33:42,840 --> 00:33:48,240
+الـ Cl واضح؟ طبعا ممكن حد يقول كيف هذا بنحول ال
+
+346
+00:33:48,240 --> 00:33:54,840
+acid ال acid ل O minus بالتفاعل مع N A O H حمزاد
+
+347
+00:33:54,840 --> 00:33:55,680
+قاعدة
+
+348
+00:33:59,270 --> 00:34:03,890
+NA قدش كتير عليه دائما مستعمل أقل شغلة مع ال NA
+
+349
+00:34:03,890 --> 00:34:08,170
+هياعمل حريقة هيكون التفاعل violent مع ال NA و لا
+
+350
+00:34:08,170 --> 00:34:14,470
+مع ال NA او ال NA قدش كتير عليه هيعمل حريقة مع ال N
+
+351
+00:34:14,470 --> 00:34:17,470
+A و N A H ماشي الحمض يتفاعل مع ال N A و N A H
+
+352
+00:34:17,470 --> 00:34:21,570
+الكحول هداج زنبه ع جنبه مكانش يتفاعل مع ال N A و N
+
+353
+00:34:21,570 --> 00:34:26,970
+A H ولذلك استعملتله N A و N A H لكن الحمض بتفاعل
+
+354
+00:34:26,970 --> 00:34:31,670
+مع ال N A و N A H ولا لأ بتفاعل و هذا بي سي ال
+
+355
+00:34:31,670 --> 00:34:37,050
+اثنين اذا حامض طبعا واحدة ممكن تسأل انواع نخلي O
+
+356
+00:34:37,050 --> 00:34:42,970
+minus وانواع C L مش فارقفى ال ethers كان فارق ال
+
+357
+00:34:42,970 --> 00:34:48,330
+CL بنا نخليه ال primary هنا مش فارق واحد بخليه O
+
+358
+00:34:48,330 --> 00:34:55,210
+minus والتانى بخليه CL و بعدين بفعلهم هيطلع عندى
+
+359
+00:34:55,210 --> 00:35:01,650
+ال unsymmetrical anhydride
+
+360
+00:35:01,650 --> 00:35:10,810
+واضحة الفكرة وهي طريقة تحضير الـ Acidic Benzoic
+
+361
+00:35:10,810 --> 00:35:16,290
+Anhydride فيه أوضح من هيك؟ مرة جيبناها سؤال هذا
+
+362
+00:35:16,290 --> 00:35:20,230
+المركب، قولنا للطلاب سمي المركب التالي واذكر طريقة
+
+363
+00:35:20,230 --> 00:35:27,250
+تحضيره، ما جوابوش عشرة في المية، بتصدقوا؟ ليش؟ لأنه
+
+364
+00:35:27,250 --> 00:35:31,370
+مابيطبقوش مابيعدوش الكتابة خمس مرات لحد ما إيدهم
+
+365
+00:35:31,370 --> 00:35:36,830
+تتعود على الكيميا ولذلك لو بدكوا تطلعوا على سبيل
+
+366
+00:35:36,830 --> 00:35:42,270
+المثال هذا الكلام جيد إنه الكل يسمعوا حتى الناس
+
+367
+00:35:42,270 --> 00:35:46,470
+اللي بيشاهدوا الفيديو الطالب اللي مابيكتب كيميا
+
+368
+00:35:46,470 --> 00:35:53,090
+كتير ما بيكتب كيميا كتير هذا فن بحاجة إلى تدريب
+
+369
+00:35:53,090 --> 00:36:00,310
+ولذلك قد تستغربوا انه لما جيبنالكم بنزين وقلنا
+
+370
+00:36:00,310 --> 00:36:06,890
+حطوا عليها بس مجموعة إثل زي هيك يعني كتبنا CH3
+
+371
+00:36:06,890 --> 00:36:15,070
+CH2Cl في وجود الـFeCl3 تمام؟
+
+372
+00:36:16,720 --> 00:36:24,060
+الآن بنسبة 70% منكم عندهم فهم ولكن عندهم خطأ في
+
+373
+00:36:24,060 --> 00:36:28,300
+التنفيذ لأنهم ما دربوش إيديهم يكتبوا كان الجواب
+
+374
+00:36:28,300 --> 00:36:40,280
+اللي كتب بهذا الشكل الان
+
+375
+00:36:40,280 --> 00:36:44,720
+انتوا بتحكوا لكن انا عندى إحصائية انا بعمل إحصائية
+
+376
+00:36:44,720 --> 00:36:49,560
+كيف بتكتبوا، 70% منكم كتبوا بهذا الشكل، لا هذه ال
+
+377
+00:36:49,560 --> 00:36:53,780
+carbon أربع روابط ولا هذه أربع روابط ولا محل مكانة
+
+378
+00:36:53,780 --> 00:36:59,280
+ال CL عملوا التفاعل كل هذه الأشياء ليش؟ لأنه مافيش
+
+379
+00:36:59,280 --> 00:37:05,900
+تطبيق، الأصل أنه هنا نكون كاتبين CH2 CH3
+
+380
+00:37:07,280 --> 00:37:14,480
+الان لما جيبنالكم فاعله مع CH3CWOCL الاصل بدكوا
+
+381
+00:37:14,480 --> 00:37:23,960
+تحطه من هنا من محل ال CL يعني تحطه CWOCL
+
+382
+00:37:23,960 --> 00:37:31,560
+ربما خمسين في المية منكم حطوا هنا CWO وحطوا هنا
+
+383
+00:37:31,560 --> 00:37:40,360
+CH3 بهذا الشكل بهذا الشكل لا تحزروا روسكو و إلا
+
+384
+00:37:40,360 --> 00:37:44,380
+بجيب الورق و بفرجيكوا إياه ليش؟ لأنه ما صارش عندكم
+
+385
+00:37:44,380 --> 00:37:49,140
+تطبيق اللي بيدخل على كلية علمية جامعية بده يتعب و
+
+386
+00:37:49,140 --> 00:37:54,980
+هو بيطبق و يكتب كتير و يتعب كتير عشان يشتغل صح لكن
+
+387
+00:37:54,980 --> 00:37:59,020
+هذا الكلام خمسين في المية يمكن كتبوه من الطالبات و
+
+388
+00:37:59,020 --> 00:38:02,440
+هذا الكلام اللي كان تول سبعين في المية من الطالبات
+
+389
+00:38:02,440 --> 00:38:07,760
+كتبوه ليش؟ لأنهم بدهم يقرؤوا ال organic قراءة
+
+390
+00:38:08,820 --> 00:38:14,640
+أدبيات الرافعي الرافعي يقرأ استلقاء و ال organic
+
+391
+00:38:14,640 --> 00:38:28,580
+تقرأ كتابة و تطبيقا واضحة الفكرة هاي
+
+392
+00:38:28,580 --> 00:38:36,210
+ال acid anhydride الان لاحظوا من الأحماض اللي
+
+393
+00:38:36,210 --> 00:38:42,090
+درسناها ال die acids يعني يكون عندى حامضين في نفس
+
+394
+00:3
+
+445
+00:43:52,570 --> 00:43:58,850
+C double bond O و هذا بيصير ايش اسمه أفثالك
+
+446
+00:43:58,850 --> 00:44:01,810
+انهيدريد
+
+447
+00:44:04,120 --> 00:44:12,560
+أفثالك أنهايدرايد واضح طبعا
+
+448
+00:44:12,560 --> 00:44:16,960
+هذه ال mix انهيدرايد حكينا عنها كيف بتتحضر واحد O
+
+449
+00:44:16,960 --> 00:44:20,520
+minus والتاني CL وهي تسميتهم acidic benzoic
+
+450
+00:44:20,520 --> 00:44:22,060
+anhydride حكينا عنه
+
+451
+00:44:29,520 --> 00:44:36,740
+طبعا لو كنا بدنا ندرس تفاعلات الانهيدريد واحدة
+
+452
+00:44:36,740 --> 00:44:40,340
+تختصر تفاعلات الانهيدريد بكلمة شو هتقول عنهم
+
+453
+00:44:40,340 --> 00:44:47,660
+substitution reaction طبعا ال substitution بده يتم
+
+454
+00:44:47,660 --> 00:44:56,020
+هان و نطرد كل هذه المجموعة بتخرج على شكل إيشحمض مع
+
+455
+00:44:56,020 --> 00:45:00,360
+الأموليا بيعطيني أمد مثلا مع الكحول بيعطيني Easter
+
+456
+00:45:00,360 --> 00:45:05,240
+مع الميه بيعطيني ال acid التاني و هكذا من هذه
+
+457
+00:45:05,240 --> 00:45:09,960
+النقطة ان شاء الله المرة القادمة بنبدأ بنأكد عليها
+
+458
+00:45:09,960 --> 00:45:14,960
+بس بتكونوا تدربتوا عليها تفاعلات ال acid
+
+459
+00:45:14,960 --> 00:45:18,000
+anhydrides بال substitution بالإبدال
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6c89219318856cd1f1ce423281afe5f1c923d3f1
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk.srt
@@ -0,0 +1,1459 @@
+
+1
+00:00:21,160 --> 00:00:25,760
+بسم الله الرحمن الرحيم اليوم موضوع درسنا في
+
+2
+00:00:25,760 --> 00:00:30,500
+الكيميا العضوية موضوع درسنا في الكيميا العضوية
+
+3
+00:00:30,500 --> 00:00:36,800
+بعنوان ال alkenes طبعا احنا في الفصل الثاني
+
+4
+00:00:36,800 --> 00:00:40,540
+اتكلمنا على ال alkenes و ال cycloalkenes اللي
+
+5
+00:00:40,540 --> 00:00:45,660
+بيمتازوا بالمجموعة الوظيفية اللي هي كلها single
+
+6
+00:00:45,660 --> 00:00:49,610
+bonds الروابط اللي موجودة فيهم single bonds أخدنا
+
+7
+00:00:49,610 --> 00:00:54,310
+معلومات عامة عنهم طبعا درسنا الأمر ضمن الإطار
+
+8
+00:00:54,310 --> 00:00:59,010
+العام ان ال hydrocarbons they are either saturated
+
+9
+00:00:59,010 --> 00:01:02,950
+contain only single bonds such as alkenes or
+
+10
+00:01:02,950 --> 00:01:06,870
+cycloalkenes الصياغ العامة لهم واضحة or
+
+11
+00:01:06,870 --> 00:01:13,800
+unsaturated ومنهم ال alkenes ربما وضحنا في الوقت
+
+12
+00:01:13,800 --> 00:01:17,360
+اللي شرحنا فيه الصيغة العامة ان ال alkenes
+
+13
+00:01:17,360 --> 00:01:23,140
+بياخدوا الصيغة العامة CNH2N بمعنى لو انا بدي انظر
+
+14
+00:01:23,140 --> 00:01:27,620
+لأبسط alkenes هذا alkenes اللي هو ال Ethlene اللي
+
+15
+00:01:27,620 --> 00:01:33,520
+مكوّن من ذرتين كاربونهو أبسط alkenes ولذلك مرات
+
+16
+00:01:33,520 --> 00:01:39,160
+بيسموه ال parent alkenes parent يعني الأساسي أو
+
+17
+00:01:39,160 --> 00:01:44,200
+الأبسط parent جاية من ال parents العباء parent ال
+
+18
+00:01:44,200 --> 00:01:48,380
+alkenes ال parent alkenes أبسط واحد هو إيش؟ الـ
+
+19
+00:01:48,380 --> 00:01:51,840
+Ethylene اللى انتوا شايفينه بهذا الشكل اكيد لو
+
+20
+00:01:51,840 --> 00:02:00,140
+طلعنا على الصيغة العامة تبعته C2H4 CNH2N لما احنا
+
+21
+00:02:00,140 --> 00:02:04,500
+عملنا ال double bond حذفنا مقابلها ذرتين هيدروجين
+
+22
+00:02:06,320 --> 00:02:11,400
+الان هذا الكلام بيخلنا مرة تانية نذكر ايضا بشيء
+
+23
+00:02:11,400 --> 00:02:16,440
+اخدناه في المقدمة اللي هو انظر متذكرين العلاقة ما
+
+24
+00:02:16,440 --> 00:02:21,400
+بين انواع الروابط bond order وطول الرابط وقوة
+
+25
+00:02:21,400 --> 00:02:26,780
+الرابط قلنا ان الروابط اللي هتمر معنى لل carbon يا
+
+26
+00:02:26,780 --> 00:02:31,260
+اما روابط احدية او ثنائية او ثلاثية هذا بنسميه
+
+27
+00:02:31,260 --> 00:02:36,900
+bond order عدد الروابط نسميه bond order الان لو
+
+28
+00:02:36,900 --> 00:02:41,560
+اجينا نتذكر ال bond angles ال bond angle اللى كانت
+
+29
+00:02:41,560 --> 00:02:47,680
+حول الكربون لما يكونوا كل روابط احدية مية وتسعة و
+
+30
+00:02:47,680 --> 00:02:53,360
+نص بيكون الشكل تتراهيدرال واضح الان لما نيجي نحكي
+
+31
+00:02:53,360 --> 00:02:58,790
+على ال double bond بتكون الزاوية 120 يعني لو انا
+
+32
+00:02:58,790 --> 00:03:06,530
+بدأ اطلع بهذا الشكل 120 120 و 120 المجموع قداشر 360
+
+33
+00:03:06,530 --> 00:03:12,670
+المجموع 360 الان لو بدأ اشوف طيب ايش الشكل حوالين
+
+34
+00:03:12,670 --> 00:03:16,450
+ال double bond الشكل حوالين ال double bond بنسميه
+
+35
+00:03:16,450 --> 00:03:22,910
+Triangular Planar يعني في مستوى واحد لاحظوا الذرات
+
+36
+00:03:23,440 --> 00:03:28,140
+هيدروجين كاربون هيدروجين كاربون هيدروجين كاربون لو
+
+37
+00:03:28,140 --> 00:03:32,960
+حطينا مستوى بهذا الشكل جميع الذرات في مستوى واحد
+
+38
+00:03:32,960 --> 00:03:37,000
+ولذلك الاثيليين جميع ذراته في مستوى واحد بنقول عنه
+
+39
+00:03:37,000 --> 00:03:42,180
+إيش ال planar الان الشكل ال Triangular Planar
+
+40
+00:03:42,180 --> 00:03:49,600
+يعني مقسوم إلى تلات أقسام الزاوية 120 120 120 واضحة
+
+41
+00:03:49,600 --> 00:03:55,540
+هذه النقطة الآن لو اجينا نحكي على ال bond length
+
+42
+00:03:55,540 --> 00:04:01,680
+مقارنة ال carbon carbon single bond مع ال carbon
+
+43
+00:04:01,680 --> 00:04:05,700
+carbon double bond أنها بتكون أقصر الـ carbon
+
+44
+00:04:05,700 --> 00:04:09,700
+carbon double bond كل ما ال bond order بيزيد ال
+
+45
+00:04:09,700 --> 00:04:14,200
+bond بتصير أقصر و ال triple bond بعد شوية هنلاحظ
+
+46
+00:04:14,200 --> 00:04:19,840
+أنها أقصر و موجودة الأطوال عندنا في ال بيكمتر الان
+
+47
+00:04:19,840 --> 00:04:23,140
+الرابطة لما بيزيد فيها ال bond order بيصير فيها
+
+48
+00:04:23,140 --> 00:04:32,070
+أمر كتير مهم هذا الأمر هوزيادة قوة الرابطة بما
+
+49
+00:04:32,070 --> 00:04:36,290
+يمنع الدوران يعني لاحظوا معي لما بيكون عند رابطة
+
+50
+00:04:36,290 --> 00:04:42,170
+أحدية فقط عند دوران ممكن حول الرابطة الأحدية لكن
+
+51
+00:04:42,170 --> 00:04:46,650
+مجرد ما بتصير هذه الرابطة رابطة ثنائية او بالتأكيد
+
+52
+00:04:46,650 --> 00:04:53,550
+ثلاثية بيصير الدوران ممنوع بيصير الدوران ممنوع هذا
+
+53
+00:04:53,550 --> 00:05:02,130
+الكلام له انعكاس مهم جدا في الكيميا انه انا لو
+
+54
+00:05:02,130 --> 00:05:08,230
+رجعت دقيقة للخلف و أخدت مركب فيه روابط أحدية يعني
+
+55
+00:05:08,230 --> 00:05:14,610
+لغيت هذه الرابطة نهائيا و اتخيلت انه عندي ال Ethane مش
+
+56
+00:05:14,610 --> 00:05:20,890
+ال Ethane هو مركب الروابط الأحدية الـ Ethane هو مركّب
+
+57
+00:05:20,890 --> 00:05:24,250
+الهواط الأوحادية الان هنا في عندى اشي بسميه اش
+
+58
+00:05:24,250 --> 00:05:31,270
+free rotation اش بنسميه free rotation دوران حر
+
+59
+00:05:31,270 --> 00:05:34,510
+free rotation
+
+60
+00:05:36,130 --> 00:05:42,090
+طيب هذا الـ free rotation على إيش بيأثر عندى في
+
+61
+00:05:42,090 --> 00:05:48,090
+الأمور الكيميائية هيأثر على أمر مهم جدا جدا لو يا
+
+62
+00:05:48,090 --> 00:05:55,170
+ترى أنا إجيت بدلت من هنا هيدروجين بذرة كلور على
+
+63
+00:05:55,170 --> 00:06:00,890
+موقع واحد وبدلت من هنا هيدروجين تانية على ذرة كلور
+
+64
+00:06:00,890 --> 00:06:06,740
+بموقع واحد وامسكت الجزاء لاحظوا معي الدوران ممكن
+
+65
+00:06:06,740 --> 00:06:10,820
+ألاحظ أن ذرتين الكلور هدولة جايين بمستوى واحد يقبل
+
+66
+00:06:10,820 --> 00:06:17,780
+بعض ممكن يلفوا بدت واحدة تغلط و تقول sis انتبهوا
+
+67
+00:06:17,780 --> 00:06:22,140
+معي ممكن يلفوا صار بينهم زيو معين كمان كمان كمان
+
+68
+00:06:22,140 --> 00:06:25,320
+ممكن بلحظة من اللحظات أثناء الدوران يكونوا بهذا
+
+69
+00:06:25,320 --> 00:06:34,380
+الشكل اذا لو سألت كم هيئة تنتج عن الدوران متوقع
+
+70
+00:06:34,380 --> 00:06:42,620
+لهذا الشكل أكيد عدد لانهائي من الهيئات يعني
+
+71
+00:06:42,620 --> 00:06:47,420
+الزاوية ما بين هدولة دارتين سفر بدت ألف صارت واحد
+
+72
+00:06:47,420 --> 00:06:50,780
+من عشر او اتنين من عشر او تلات من عشر اربع زادت
+
+73
+00:06:50,780 --> 00:06:55,680
+زادت زادت زادت زادت صاروا عكس بعض طول أنا بلوف
+
+74
+00:06:55,680 --> 00:07:01,180
+بطلع هيئات مش أشكال لاحظوا بدي أميز ما بين كلمتين
+
+75
+00:07:01,180 --> 00:07:05,700
+ما بين هيئة و ما بين شكل أصلي يعني البني آدم بني
+
+76
+00:07:05,700 --> 00:07:10,740
+آدم واحد لكن يمكن أن يوجد فيه هيئات مختلفة ولذلك
+
+77
+00:07:10,740 --> 00:07:14,800
+لما بييجي في الطالب الصبح و بيعمل تمرينات الصبح
+
+78
+00:07:14,800 --> 00:07:19,180
+رياضية هيئاتين تين تلاتة أربعة بييجي في محمد و بعد
+
+79
+00:07:19,180 --> 00:07:24,360
+التمرينات بننادي عليه و بنقول عنه برضه محمد بياخد
+
+80
+00:07:24,360 --> 00:07:29,620
+ايقات مختلفة المدرس قال هيك هيك هيك هيك هيك هيك
+
+81
+00:07:29,620 --> 00:07:31,420
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+82
+00:07:31,420 --> 00:07:31,960
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+83
+00:07:31,960 --> 00:07:32,040
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+84
+00:07:32,040 --> 00:07:37,760
+هيك هيك هيك هيك هيك هيك هيك
+
+85
+00:07:37,760 --> 00:07:38,540
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+86
+00:07:38,540 --> 00:07:38,680
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+87
+00:07:38,680 --> 00:07:38,900
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+88
+00:07:38,900 --> 00:07:39,760
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+89
+00:07:39,760 --> 00:07:48,300
+هيك هيك هيك هيك هيك
+
+90
+00:07:48,300 --> 00:07:55,690
+هيك هيك هو واحد بهيئات دورانية مختلفة هيئة بنسميها
+
+91
+00:07:55,690 --> 00:07:58,650
+احنا باللغة الإنجليزية ايش Conformation
+
+92
+00:07:58,650 --> 00:08:02,490
+Conformation
+
+93
+00:08:02,490 --> 00:08:11,230
+هيئة الان مرت علينا هذه الكلمة في ال Cyclohexane
+
+94
+00:08:11,230 --> 00:08:17,190
+اذا ال Conformation او الهيئات تنتج عن شغلتين ال
+
+95
+00:08:17,190 --> 00:08:22,230
+conformations بتنتج عن شغلتين الشغلة الأولى اللى
+
+96
+00:08:22,230 --> 00:08:26,370
+مرت علينا ال flipping يوم كان ال cyclohexane بيجلب
+
+97
+00:08:26,370 --> 00:08:29,770
+بيعمل flipping زى الشمسية اللى بتجلب للامام و
+
+98
+00:08:29,770 --> 00:08:33,930
+للخلف للامام و للخلف لكن بتبقى شمسية إذا ال
+
+99
+00:08:33,930 --> 00:08:39,290
+conformations يمكن أن تنشأ عن ال flipping و نمرة
+
+100
+00:08:39,290 --> 00:08:45,170
+اتنين يمكن أن تنشأ عن ال rotation الدوران فيكون
+
+101
+00:08:45,170 --> 00:08:53,610
+المُركّب مُركّب واحدبشكل واحد وبهيئات كثيرة مختلفة
+
+102
+00:08:53,610 --> 00:08:59,810
+ولذلك ال one two dichloroethane هو مركب واحد فقط
+
+103
+00:08:59,810 --> 00:09:05,030
+بهيئات مختلفة وهو في حالة دوران أبدي يعني ربنا
+
+104
+00:09:05,030 --> 00:09:10,050
+خالقه زي ما بتقول الآية الكريمة وكل في فلك يسبحون
+
+105
+00:09:10,050 --> 00:09:15,740
+بالنسبة لعلم الكيميا هذا دوران لا يتوقف الدوران حول
+
+106
+00:09:15,740 --> 00:09:19,820
+الرابطة الأوحادية تماما زى المروحة اللى بالسجف لما
+
+107
+00:09:19,820 --> 00:09:24,320
+بتلوف بنقولش عنها مروحة كتيرة بتكون بهذا الشكل بعد
+
+108
+00:09:24,320 --> 00:09:28,730
+شوية بتزيد زوايا كمانو هي في حالة دوران أبدي لكنها
+
+109
+00:09:28,730 --> 00:09:33,450
+تبقى مروحة الان هذا الـ dichloroethane في حالة
+
+110
+00:09:33,450 --> 00:09:39,550
+دوران أبدي بهيئات كثيرة ولكنه يبقى مركبا واحد فلو
+
+111
+00:09:39,550 --> 00:09:43,570
+واحدة بدت تشتري dichloroethane هتلاقي انه عندها
+
+112
+00:09:43,570 --> 00:09:51,130
+إيش مركب واحد السبب ال free rotation الان خلينا
+
+113
+00:09:51,130 --> 00:09:53,010
+نحول للالكين
+
+114
+00:09:55,450 --> 00:10:01,850
+في الالكين صار عندي double bond قوية باجى اجرب ان
+
+115
+00:10:01,850 --> 00:10:08,410
+اعمل الدوران مافيش دوران مافيش إمكانية للدوران
+
+116
+00:10:08,410 --> 00:10:14,510
+الرابطة قوية وبناء على ذلك لو بدأ أحول هذا الشكل
+
+117
+00:10:14,510 --> 00:10:19,870
+للشكل التاني إيش بدأ أعمل؟ كسر وتكوين رابط قبل
+
+118
+00:10:19,870 --> 00:10:23,030
+شوية لما كانت الرابط أحدية بدأ أحول هذا للتاني
+
+119
+00:10:23,030 --> 00:10:28,130
+rotation فهذه هيئات وليس تعبير عن مركب جديد لكن
+
+120
+00:10:28,130 --> 00:10:32,070
+الأن أنا أمام ظاهرة جديدة لو بدأ أحول هذا المركب
+
+121
+00:10:32,070 --> 00:10:38,290
+اللي قلنا عنه cis إلى ال Trans بدي أكسر الرابطة
+
+122
+00:10:38,290 --> 00:10:44,790
+وأكسر الرابطة وأعمل المركب لجديد ولذلك هدول صاروا
+
+123
+00:10:44,790 --> 00:10:50,250
+مركبين مختلفين بخواص مختلفة يومها بتروح تشتري one
+
+124
+00:10:50,250 --> 00:10:54,890
+two dichloro ethane اللي في double bond بنهاية إيش
+
+125
+00:10:54,890 --> 00:11:00,790
+in بتشتروا مركب ولا اتنين؟ مركبين واحد اسمه ال
+
+126
+00:11:00,790 --> 00:11:07,980
+Trans one two dichloro ethane و التاني اسمه cis one
+
+127
+00:11:07,980 --> 00:11:13,660
+two dichloro ethane واضح هذه الفكرة فكرة ال cis و
+
+128
+00:11:13,660 --> 00:11:17,680
+ال trans الآن
+
+129
+00:11:17,680 --> 00:11:23,560
+لو يا تورا اجينا نمشي خطوة للامام طيب عندنا ال
+
+130
+00:11:23,560 --> 00:11:29,650
+alkenes بدنا نتعلم كيف نسميهم و ال alkenes مثل ما
+
+131
+00:11:29,650 --> 00:11:35,330
+اتعودنا نسمي في الـ Alkanes بدنا أطول سلسلة لكن
+
+132
+00:11:35,330 --> 00:11:42,530
+هنا نضع شرط أطول سلسلة تحتوي على الرابطة الثنائية
+
+133
+00:11:42,530 --> 00:11:47,150
+او الثلاثية بمعنى ممكن تشوفوا السلسلة طولها سبع
+
+134
+00:11:47,150 --> 00:11:51,610
+كربونات متتالية لكن كلها روابط أحدية والجزء في
+
+135
+00:11:51,610 --> 00:11:54,310
+رابطة ثنائية
+
+136
+00:11:55,990 --> 00:12:02,230
+يجب أن تحتوي أطول سلسلة على رابطة ثنائية ممكن
+
+137
+00:12:02,230 --> 00:12:09,930
+أعطيكم مثال حتى التطبيق يكون واضح ممكن نعطي مثال
+
+138
+00:12:09,930 --> 00:12:14,750
+يعني لو أعطينا فقط نرسم ذرات ال carbon وحاطينا
+
+139
+00:12:14,750 --> 00:12:21,340
+carbon 2 ثلاثة carbon 2 ثلاثة بهذا الشكل الان لو
+
+140
+00:12:21,340 --> 00:12:28,060
+جينا وعطينا هنا كمان carbon نحسب أطول سلسلة ممكن
+
+141
+00:12:28,060 --> 00:12:32,940
+واحدة تيجي تقول واحد، تنين، تلاتة، أربعة، خمسة،
+
+142
+00:12:32,940 --> 00:12:39,040
+ستة، سبعة، تمانية وممكن كمان تقول هنا كمان رابطة
+
+143
+00:12:39,040 --> 00:12:42,880
+تسعة الان لاحظوا هذه السلسلة اللي اخترتها مافيش
+
+144
+00:12:42,880 --> 00:12:46,840
+فيها ال double bond مش هتمشي معاه بدي سلسلة يكون
+
+145
+00:12:46,840 --> 00:12:58,790
+فيها ال double bond 1 2 3 4 5 6 7 او 1 2 3 4 5 6 7
+
+146
+00:12:58,790 --> 00:13:05,950
+ممكن خلهم يختاروا واحدة منهم حسب الاكثر تفرع عن
+
+147
+00:13:05,950 --> 00:13:09,810
+اللي حكينا عليه اذا كان موجود الان اذا ما باخدش
+
+148
+00:13:09,810 --> 00:13:13,620
+السلسلة التسعة اللي مافيش فيها double bond لما ابدأ
+
+149
+00:13:13,620 --> 00:13:18,320
+أسمي لازم السلسلة اللي أخدها يكون فيها double bond
+
+150
+00:13:18,320 --> 00:13:23,980
+وجدت بنهي المركب بنهايك E لو كانت هذه triple bond
+
+151
+00:13:23,980 --> 00:13:30,500
+بنهي المركب بنهايك I إذا التسمية ببساطة أن نختار
+
+152
+00:13:30,500 --> 00:13:36,740
+أطول سلسلة تحتوي على Double أو Triple Point إذا كان
+
+153
+00:13:36,740 --> 00:13:40,360
+Double Point بنهي المركب بالنهاية E وإذا Triple
+
+154
+00:13:40,360 --> 00:13:45,580
+Point بنهي المركب بالنهاية I خلينا نشوف أمثلة من
+
+155
+00:13:45,580 --> 00:13:50,960
+ال slides هاي في عندنا مثال لما نيجي نبحث عن أطول
+
+156
+00:13:50,960 --> 00:13:58,880
+سلسلة واحد، اتنين، تلاتة، أربعة، خمسة هذه اللي
+
+157
+00:13:58,880 --> 00:14:01,240
+فيها Double Point في واحد، اتنين، تلاتة Double
+
+158
+00:14:01,240 --> 00:14:06,750
+Point خارجها، مابديها الان مجرد ما اختارنا أطول
+
+159
+00:14:06,750 --> 00:14:13,510
+سلسلة على طول بدنا نقول إنه في إمكانيتين للترقيم
+
+160
+00:14:13,510 --> 00:14:17,850
+يعني هذه أطول سلسلة ممكن أوضحها أنا باللون الأزرق،
+
+161
+00:14:17,850 --> 00:14:21,850
+هذه أطول سلسلة، الآن بدي أبدأ واحد هان خمسان ولا
+
+162
+00:14:21,850 --> 00:14:26,520
+واحد هان خمسان، هذا سؤال مهم جدا بدي اخلي ال
+
+163
+00:14:26,520 --> 00:14:31,180
+double bond تاخد أقل ترقيم، بداية ال double bond،
+
+164
+00:14:31,180 --> 00:14:35,480
+لاحظوا هنا ال double bond بدايتها وين؟ اتنين، لو
+
+165
+00:14:35,480 --> 00:14:40,680
+برقم من هنا واحد، اتنين، تلاتة، وين ال double bond
+
+166
+00:14:40,680 --> 00:14:46,170
+أقرب للطرف؟ من هام ولذلك برقم واحد اتنين تلاتة
+
+167
+00:14:46,170 --> 00:14:52,210
+اربعة خمسة طالما خمس ذرات carbon إذا المركب Pentene
+
+168
+00:14:52,210 --> 00:14:59,530
+Pentene يلتهي بين في double bond الآن الين هذه اللي
+
+169
+00:14:59,530 --> 00:15:05,160
+هي ال double bond وين بدايتها؟ فالـ carbon 2 هي
+
+170
+00:15:05,160 --> 00:15:10,160
+جاية بين 2 و 3 أنا بذكر فقط نقطة البداية ولذلك
+
+171
+00:15:10,160 --> 00:15:16,840
+هذا بقول عنه two Pentene فال two اللي موجودة هنا هذه
+
+172
+00:15:16,840 --> 00:15:
+
+223
+00:19:59,400 --> 00:20:06,800
+سلسلة شوفوا إيش اسمه فكيف تبدأ التسمية؟ بأطول سلسلة
+
+224
+00:20:06,800 --> 00:20:10,320
+مش أشوف أن هذه مجموعة و هذه مجموعة و التنتين
+
+225
+00:20:10,320 --> 00:20:16,880
+موجودات كجزء من أطول سلسلة واضحة الفكرة؟
+
+226
+00:20:36,770 --> 00:20:43,390
+وعشان هيك لا بأس ان اعطيكم مسألة تانية تفكروا فيها
+
+227
+00:20:43,390 --> 00:20:58,450
+تعملوها homework على هذا الموضوع تحديدا مسألة
+
+228
+00:20:58,450 --> 00:21:04,080
+جميلة جداطبعا اللي حافظين المجموعات يا الله
+
+229
+00:21:04,080 --> 00:21:07,400
+isopropyl و isopropyl ضاي isopropyl واحد اتنين
+
+230
+00:21:07,400 --> 00:21:12,440
+تلاتة اربعة خمسة ستة ضاي isopropylهكسين و كل الاسم
+
+231
+00:21:12,440 --> 00:21:18,220
+غلط بديش الأن أسميه اتعبوا فيه ابحثوا عن أطول
+
+232
+00:21:18,220 --> 00:21:22,200
+سلسلة و ما زاد عنفا و مجموعات مش تيجي تقولوا أن
+
+233
+00:21:22,200 --> 00:21:24,060
+هذه isopropyl و هذه isopropyl
+
+234
+00:21:31,920 --> 00:21:39,760
+تخدوا من بعض لو سمحتوا خلينا نمشي الان انتبهوا معي
+
+235
+00:21:39,760 --> 00:21:46,500
+حكينا احنا عن ظاهرة ال
+
+236
+00:21:46,500 --> 00:21:51,960
+الكينز و ال sis و ال trans الان ازملتكوا ذكرتنا
+
+237
+00:21:51,960 --> 00:21:57,260
+بالمجموعاتبتذكرين لما أخدنا مثيل قولنا منه مجموعة
+
+238
+00:21:57,260 --> 00:22:04,560
+مثل اثل اثل بروبل بروبل و ايزو بروبل طيب يا تورا
+
+239
+00:22:04,560 --> 00:22:10,080
+الالكين لو خصمنا من الالكين هيدروجين في كمان
+
+240
+00:22:10,080 --> 00:22:14,850
+مجموعات؟يعني دول بنحفظنا الأولانيين لو خصمنا
+
+241
+00:22:14,850 --> 00:22:19,690
+الهيدروجين من الالكين في مجموعات الجواب في بعض
+
+242
+00:22:19,690 --> 00:22:24,550
+المجموعات اللي بنتعرف عليها أبسط الكين هو الاثيل
+
+243
+00:22:24,550 --> 00:22:30,190
+أو الاثيلين لو شيلنا منه الهيدروجين هذه بنعمل
+
+244
+00:22:30,190 --> 00:22:36,130
+مجموعة الالكين minus الهيدروجين بنعمل مجموعة
+
+245
+00:22:36,130 --> 00:22:43,540
+بنسميهاإزملتكوا برضه سمعتني كلمة مش مظبوطة جالت
+
+246
+00:22:43,540 --> 00:22:51,460
+فينل أنا بقول فينل في حرف ال V هذه فينل فلو حملت
+
+247
+00:22:51,460 --> 00:22:57,770
+ال chlorine بتصير vinyl chloride ليش رفضنا؟إنها
+
+248
+00:22:57,770 --> 00:23:02,430
+تقول كلمة Fennel لأن ال Fennel مجموعة تانية
+
+249
+00:23:02,430 --> 00:23:08,250
+البنزين لما بتلوجد على يعني لو أخدت هذا المركب
+
+250
+00:23:08,250 --> 00:23:14,550
+بيوتين صح؟ أو هذا المركب بنتين حطوا عليها هنا
+
+251
+00:23:14,550 --> 00:23:22,310
+بنزينة بنزينة مخصوم منها Hydrogen هذه كمجموعة
+
+252
+00:23:22,310 --> 00:23:24,790
+اسمها Fennel
+
+253
+00:23:27,710 --> 00:23:33,290
+الان الفنل مجموعة البنزين الـ C6H6 الخاصة منه
+
+254
+00:23:33,290 --> 00:23:40,590
+هيدروجين صار C6H6H5 وبيشبك من هذا الموقع هذه
+
+255
+00:23:40,590 --> 00:23:47,830
+مجموعة الفينل الان لما اجي اخد الاثيليين اخص منه
+
+256
+00:23:47,830 --> 00:23:55,690
+هيدروجين بيصير C2H3 مجموعة الفينل ولذلك لما بتلفظه
+
+257
+00:23:55,690 --> 00:24:02,390
+ميزه كلمة فينل عن كلمة فينل هذه مجموعة و هذه
+
+258
+00:24:02,390 --> 00:24:08,550
+مجموعة فينل فينلهذه المجموعة الأولى مشتقة من إيش؟
+
+259
+00:24:08,550 --> 00:24:13,550
+من الإيثيلين من خلال أن أحذف منه هيدروجينة طبعا
+
+260
+00:24:13,550 --> 00:24:18,750
+موضوع الإيثيلين موضوع سهل جدا ليش؟ لأنه في
+
+261
+00:24:18,750 --> 00:24:23,790
+الإيثيلين الأربع ذرات هيدروجين زي بعض يعني من وين
+
+262
+00:24:23,790 --> 00:24:27,410
+ما بخسم هذه أو هذه أو هذه أو هذه شيلت هيدروجينة
+
+263
+00:24:27,410 --> 00:24:33,260
+صارت مجموعة ما اسمها؟Vinyl هذه مجموعة Vinyl الان
+
+264
+00:24:33,260 --> 00:24:37,480
+لو اتيت و حطيت Clor هنا ايش في المركب؟ Vinyl
+
+265
+00:24:37,480 --> 00:24:44,120
+Cloride واضح؟ لكن لو يا تورا اتيت على المركب اللي
+
+266
+00:24:44,120 --> 00:24:48,420
+مباشرة بيجي عند بعض ال إيثيلين اللي هو البروبين
+
+267
+00:24:48,420 --> 00:24:55,580
+حطيت كمان Carbon خليني
+
+268
+00:24:55,580 --> 00:24:57,180
+اعمل ال model عشان نفهم
+
+269
+00:25:12,820 --> 00:25:25,430
+الان لاحظوا هذا جزء لبروبين CH2 CH CH3واضح؟
+
+270
+00:25:25,430 --> 00:25:31,270
+إبروبين و لو بتشوفوا الصيغة تبعته C3H6
+
+271
+00:25:31,270 --> 00:25:38,590
+يعني CNH2N واضحة صيغته؟ الآن في أنواع كتيرة من
+
+272
+00:25:38,590 --> 00:25:43,010
+الهيدروجين يعني هدول نوع، هذي نوع، هذي نوع، يمكن
+
+273
+00:25:43,010 --> 00:25:46,130
+هذي نوع، أنواع كتيرة من الهيدروجين طب أنا بقول لو
+
+274
+00:25:46,130 --> 00:25:49,850
+حذفت منه هيدروجين بيطلع مجموعةيا ترى أحذف هذه اللي
+
+275
+00:25:49,850 --> 00:25:52,930
+عند ال double bond ولا أحذف اللي بالوسط ولا أحذف
+
+276
+00:25:52,930 --> 00:25:58,490
+اللي هنا الحقيقة المجموعة الهيدروجين اللي بيحذفوها
+
+277
+00:25:58,490 --> 00:26:04,190
+من ال CH3 هنا واضح؟
+
+278
+00:26:04,190 --> 00:26:08,050
+يمكن أن تحذف الأشياء التانية لكن ليس لها اسم الآن
+
+279
+00:26:08,050 --> 00:26:12,550
+بهذا الشكل صار عند CH2
+
+280
+00:26:13,730 --> 00:26:20,930
+CH وهنا CH2 جاهزة أن تتفاعل مع شيء تاني جاهزة
+
+281
+00:26:20,930 --> 00:26:26,250
+تتفاعل مع شيء تاني هذه المجموعة بنسميها ألل إيش
+
+282
+00:26:26,250 --> 00:26:30,550
+بنسميها؟ ألل فلو حطيتي كلور محل الهيدروجينة هنا
+
+283
+00:26:30,550 --> 00:26:37,110
+تحديدا محل منحفة ال H على CH صار اسم المركب ألل
+
+284
+00:26:37,110 --> 00:26:42,980
+كلورايدواضح؟ فهذا المركب شو بيصير اسمه؟ ألل
+
+285
+00:26:42,980 --> 00:26:46,520
+أكلورايت، بتكون تتضربوا على هالكلام طيب، لو الآن
+
+286
+00:26:46,520 --> 00:26:52,300
+جبتلكوا سؤال في الامتحان وقلتلكم ارسمولي الألل
+
+287
+00:26:52,300 --> 00:26:57,660
+الكهول زي
+
+288
+00:26:57,660 --> 00:27:01,720
+الألل أكلورايت بدل الـCl وH
+
+289
+00:27:11,220 --> 00:27:18,020
+الخلاصة اللي هي مجموعةالألل مجموعة الألل هذه
+
+290
+00:27:18,020 --> 00:27:22,920
+الصحيح مجموعة الألل من الناحية التاريخية من
+
+291
+00:27:22,920 --> 00:27:29,960
+الناحية التاريخية في سبب ليش سموها ألل في سبب ليش
+
+292
+00:27:29,960 --> 00:27:36,160
+سموها ألل هذه مرتبطة بنبات التومتعرفوا الـ Toma؟
+
+293
+00:27:36,160 --> 00:27:41,000
+اه ال Toma الان ال Toma المركب الأساسي اللي فيها
+
+294
+00:27:41,000 --> 00:27:46,540
+اللي هو CH2 double bond CH CH2 الان هذه مجموعة ألل
+
+295
+00:27:46,540 --> 00:27:52,360
+ولا لأ؟ ألل بدأ تشبك من هنا وكمان لو أخدنا CH2
+
+296
+00:27:52,360 --> 00:27:58,910
+double bond CHCH2 هذه مجموعة ألل ولا لأ هدولة لما
+
+297
+00:27:58,910 --> 00:28:05,670
+بيكون بينهم ذرتين كبريت sulfur كمان رابطة sulfur
+
+298
+00:28:05,670 --> 00:28:10,070
+بيصير المركب الأساسي اللي موجود في التومة و اللي
+
+299
+00:28:10,070 --> 00:28:15,070
+بيعطيها طاعمها الآن لو قلنا طيب هذا المركب الأساسي
+
+300
+00:28:15,070 --> 00:28:23,060
+إيش بدنا نسميه هى ألل أو ألل ضاي أللو Sulphur و
+
+301
+00:28:23,060 --> 00:28:28,480
+Sulphur داي Sulphide فالمكوّن الأساسي اللي في
+
+302
+00:28:28,480 --> 00:28:36,540
+التومة داي قلل يعني تنتين قلل داي Sulphide
+
+303
+00:28:37,690 --> 00:28:42,430
+dialyl disulfide الآن هذا المركب طلو من التومة
+
+304
+00:28:42,430 --> 00:28:47,170
+لقوا في هذه المجموعة رجعوا لاسم التومة في علم
+
+305
+00:28:47,170 --> 00:28:51,450
+النبات من أي عيلة التومة في علم النبات العيلة
+
+306
+00:28:51,450 --> 00:28:59,330
+النباتية تاعة التومة اليوم اليوم فنسبة لعيلة
+
+307
+00:28:59,330 --> 00:29:07,470
+التومة قالوا سمي هذه المجموعة الواضح؟ فالأصل جاي
+
+308
+00:29:07,470 --> 00:29:14,330
+من اسم العيلة النباتية تبعت نبات التوم اليوم فإيجى
+
+309
+00:29:14,330 --> 00:29:18,150
+اليل والمكون الأساسي اللي في التومة di-alyl
+
+310
+00:29:18,150 --> 00:29:25,140
+disulfide لاحظوا معنى التومة فيها كبريتالكابريت
+
+311
+00:29:25,140 --> 00:29:30,040
+لما بيعمل تفاعلات مش بيطلع غازات سيئة S O2 H2S
+
+312
+00:29:30,040 --> 00:29:34,080
+ولذلك منهي حتى أن الإنسان ياكل تومة ويروح يصلف
+
+313
+00:29:34,080 --> 00:29:39,300
+الجماعة من وين السبب؟ سبب الرائحة السيئة اللي
+
+314
+00:29:39,300 --> 00:29:46,430
+بتطلع منه التومة الكابريت مركبات الكابريتمراكبات
+
+315
+00:29:46,430 --> 00:29:50,210
+الكابريت مراكبات رائحتها سيئة فالانسان لما بياكل
+
+316
+00:29:50,210 --> 00:29:55,610
+التومة بيصير يطلع رائحة هذه المراكبات، واضح؟
+
+317
+00:29:55,610 --> 00:30:01,010
+فالتوم مراكب موجود فيه الكابريت وهو سبب المشكلة
+
+318
+00:30:01,010 --> 00:30:05,810
+والرائحة السيئة، إذاً هيك بنكون أخدنا مجموعتين،
+
+319
+00:30:05,810 --> 00:30:10,260
+مجموعةالفينيل والأليل بس هدول المجمعتين بدنا
+
+320
+00:30:10,260 --> 00:30:14,100
+ناخدهم لل ألكينز بدنا ناخد لل ألكينز بس هدول
+
+321
+00:30:14,100 --> 00:30:20,100
+المجمعتين الانياطورة لو إجينا قولنا في عندنا تلت
+
+322
+00:30:20,100 --> 00:30:28,020
+ذرات كربون إبروبين بيمشي الحال و بدنا نعمل المركب
+
+323
+00:30:28,020 --> 00:30:31,020
+اللي بعده المركب اللي بعده إيش بدنا نزيد عليه
+
+324
+00:30:31,020 --> 00:30:37,330
+كربون إضافيةفكروا معنى أين ممكن نحط الكربون
+
+325
+00:30:37,330 --> 00:30:44,530
+الإضافية بمعنى كم مركّب الـKey هيكون عنده من أربع
+
+326
+00:30:44,530 --> 00:30:50,890
+ذرّات كربون أنا هنا ماسك التلاتة ممكن واحدة تقول
+
+327
+00:30:50,890 --> 00:30:56,350
+بسيطة حطوا هنا الكربون هنا
+
+328
+00:30:59,320 --> 00:31:03,720
+هي صار عندى اربع ذرات كربون شايفينها؟ وهنا نكملهم
+
+329
+00:31:03,720 --> 00:31:07,800
+الهيدروجينات ولا واضحين؟ واضحين هذا المركب لو بدى
+
+330
+00:31:07,800 --> 00:31:15,460
+اسميه شو هسميه؟ one two three four اذا نبيوتين
+
+331
+00:31:15,460 --> 00:31:20,540
+وبداية ال double bond ع واحد وانا بيوتين اعرفته
+
+332
+00:31:22,860 --> 00:31:28,820
+وانا بيوتين الآن هاجي أسأل يا تورا هذا المُركّب في
+
+333
+00:31:28,820 --> 00:31:33,640
+ظاهرة الـcis والترانس احنا المرة الماضية حكينا شرط
+
+334
+00:31:33,640 --> 00:31:38,220
+ظاهرة الcis والترانس مختلفتان مختلفتان هاي ال
+
+335
+00:31:38,220 --> 00:31:41,220
+double bond هاي الكربونتين تعونها هيدروجين
+
+336
+00:31:41,220 --> 00:31:45,200
+وهيدروجين متشابهتان
+
+337
+00:31:45,200 --> 00:31:50,740
+إذا كل قصة الcis والترانس غير موجودة فيه على طول
+
+338
+00:31:50,740 --> 00:31:56,740
+انتهىمافيش فيه ألوان بيوتين هو مركب واحد فقط مافيش
+
+339
+00:31:56,740 --> 00:32:02,340
+منه cis وtrans الآن ممكن نفكر أن نحط مجموعة
+
+340
+00:32:02,340 --> 00:32:08,180
+الميثالهانة لاحظوا هذه الكربون بتحمل مجمعتين
+
+341
+00:32:08,180 --> 00:32:15,760
+مختفتين هيدروجين و CH3 لما أجي بدي أبدل واحدة من
+
+342
+00:32:15,760 --> 00:32:20,990
+هدول الهيدروجينبيصير سس و تران لاحظوا واحدة هتقول
+
+343
+00:32:20,990 --> 00:32:26,910
+بدل الهيدروجين اللي فوق سير سس اه صاروا هدولة
+
+344
+00:32:26,910 --> 00:32:33,010
+مجمعتين المثل على جهة واحدة واحدة شو بدو يصير
+
+345
+00:32:33,010 --> 00:32:42,110
+المركب اللي عندك؟ سس و لو حطينا بالاتجاه المعاكس
+
+346
+00:32:42,110 --> 00:32:52,120
+اه انتبه معاههذا one two three four two بيوتين لكن
+
+347
+00:32:52,120 --> 00:32:56,600
+المثل والمثل على جهة واحدة فهو sis الظاهرة بينت
+
+348
+00:32:56,600 --> 00:33:01,120
+لأنه مختلفتان مختلفتان الان لو بدى احاول ال sis لل
+
+349
+00:33:01,120 --> 00:33:06,620
+trans one
+
+350
+00:33:06,620 --> 00:33:12,100
+two
+
+351
+00:33:12,100 --> 00:33:18,570
+three fourtrans إذا ال two بيوتين كم مركّب منه؟
+
+352
+00:33:18,570 --> 00:33:19,730
+اتنين
+
+353
+00:33:24,560 --> 00:33:29,100
+الـ two butane كام مُركّب منه؟ الـ cis والترانس
+
+354
+00:33:29,100 --> 00:33:36,660
+الان لسه ما خلصناش نشوف كل المُركّبات الان لاحظوا
+
+355
+00:33:36,660 --> 00:33:40,940
+معناه ايش اللي عملنا احنا تحديدا لما شوفنا أنواع
+
+356
+00:33:40,940 --> 00:33:43,680
+المُركّبات قولنا بنشيل الهيدروجين من هنا وكملنا
+
+357
+00:33:43,680 --> 00:33:49,280
+طلع وانا butane اجينا نشيل هذهأعملنا sis to butyl
+
+358
+00:33:49,280 --> 00:33:53,740
+شيلنا هذه و حطينا مثل أعملنا trans to butyl طب يا
+
+359
+00:33:53,740 --> 00:33:59,200
+تورا لو شيلنا هذه و حطينا مثل هنطلع
+
+360
+00:33:59,200 --> 00:34:06,680
+في المركب المتفرع اتطلع
+
+361
+00:34:06,680 --> 00:34:08,960
+على شكله بدأ يغلبني
+
+362
+00:34:13,200 --> 00:34:16,440
+الثلاثة اللي اتفرع منهم واحد واحد اتنين تلاتة
+
+363
+00:34:16,440 --> 00:34:19,880
+اتفرع لما كان في ال ال كيرز ال double bond سمينا
+
+364
+00:34:19,880 --> 00:34:26,380
+ايزو بيوتين هنا ايش هنسميه ايزو بيوتين ايزو بيوتين
+
+365
+00:34:26,380 --> 00:34:32,000
+طب لو قلت لو واحد اسميه بال ايو باكنيم هايوا قدام
+
+366
+00:34:32,000 --> 00:34:42,200
+عينيكم اطول سلسلة فيهOne Ibropine وعن إمرأتين يحمل
+
+367
+00:34:42,200 --> 00:34:49,720
+مثل إذا ال isobutene اسمه two مثل و one ibropine
+
+368
+00:34:49,720 --> 00:35:00,480
+بناء على ذلك هذه الصيغة العامة C4H8 كم ألكين منها؟
+
+369
+00:35:00,480 --> 00:35:04,480
+C4H8
+
+370
+00:35:04,480 --> 00:35:05,960
+كم ألكين؟
+
+371
+00:35:08,360 --> 00:35:13,840
+عدوهم أربعة أربعة شفتهم يعني لو بدى يكون عندكوا
+
+372
+00:35:13,840 --> 00:35:18,060
+سؤال draw all the possible alkenes that have the
+
+373
+00:35:18,060 --> 00:35:22,820
+formula C4H8 one butane, cistobutane, trans
+
+374
+00:35:22,820 --> 00:35:28,520
+-tobutane, isobutane إذا كام ألكين؟ أربعة الآن
+
+375
+00:35:28,520 --> 00:35:36,460
+انتبهوا معي سؤال دقيق جدالو أنا سألتكم draw all
+
+376
+00:35:36,460 --> 00:35:42,220
+the possible compounds المركبات أنا قولت ال keys
+
+377
+00:35:42,220 --> 00:35:46,600
+انتبهوا جيدا draw all the possible compounds كل
+
+378
+00:35:46,600 --> 00:35:53,320
+المركبات that have the formula C4H8 كيف بدكوا
+
+379
+00:35:53,320 --> 00:35:56,860
+تبدأوا تفكروا تفضلي
+
+380
+00:35:58,830 --> 00:36:04,530
+أه احنا قلنا الصيغة المشبعة C4H10 خصمنا منها اتنين
+
+381
+00:36:04,530 --> 00:36:10,010
+يالا تكوين ال double bond يالا تكوين حلقة المركبات
+
+382
+00:36:10,010 --> 00:36:15,930
+الحلقية أيضا صيغتها العامة CNH2N
+
+383
+00:36:17,500 --> 00:36:22,720
+المُركّبات الحلقية صيغتها العامة أيضًا CNN H2N
+
+384
+00:36:22,720 --> 00:36:25,940
+بناءً على ذلك بدي أشوف كم حلقة بقدر أعمل من أربع
+
+385
+00:36:25,940 --> 00:36:29,680
+كربونات عطولي أعطوني الجواب كم حلقة بيعمل إنسان من
+
+386
+00:36:29,680 --> 00:36:40,800
+أربع كربونات؟ غلط، غلط، برضه غلط أربع
+
+387
+00:36:40,800 --> 00:36:45,840
+كربونات كم حلقة بعمل منهم؟ حرام عليكي تمانية
+
+388
+00:36:53,600 --> 00:37:02,220
+يا باخد الاربعة زي هيك CH2 CH2 CH2 CH2 يا باخد
+
+389
+00:37:02,220 --> 00:37:06,300
+تلاتة و بطلع منهم مجموعة CH3
+
+390
+00:37:11,400 --> 00:37:16,360
+هدولة كمان C4H8 لو بتكملوا ال hydrogens واحد اتنين
+
+391
+00:37:16,360 --> 00:37:20,700
+واحد اتنين واحد اتنين واحد اتنين هاي ال C4H8 تلاتة
+
+392
+00:37:20,700 --> 00:37:25,600
+و اتنين و اتنين و انا واحد تمانية مقم ال hydrogens
+
+393
+00:37:25,600 --> 00:37:31,460
+بيكملوا حالهم صح اذا لو كان سؤالي بدي كل المركبات
+
+394
+00:37:31,460 --> 00:37:39,420
+اللي صيغتها C4H
+
+445
+00:41:48,830 --> 00:41:55,290
+أصح ال lower عشان يك الأسماء هنا موجودة بشكل صحيح
+
+446
+00:41:55,290 --> 00:42:01,670
+five brom one three cyclohexadiene لو تلاتة double
+
+447
+00:42:01,670 --> 00:42:09,130
+bonds تريين تلاتة تريين و بتحطوا الأرقام و
+
+448
+00:42:09,130 --> 00:42:15,730
+بتنتبهولها لو أربعة double bonds تتراين و هكذا
+
+449
+00:42:15,730 --> 00:42:23,190
+واضح؟ لكن هنا يجب أن ننوه لأمر لحظة ال Cyclohexane
+
+450
+00:42:23,190 --> 00:42:34,370
+هذا ايش اسمه؟ Cyclohexane هذا تنتين
+
+451
+00:42:42,130 --> 00:42:47,850
+Cyclohexadiene هيو موجود عندكم الآن ضمن نفس
+
+452
+00:42:47,850 --> 00:42:53,430
+المنطقة لو واحدة بدها تسمي هذا ممكن
+
+453
+00:42:53,430 --> 00:42:57,310
+تفكر تسميه Cyclohexatriene الآن عبر التاريخ هذا
+
+454
+00:42:57,310 --> 00:43:03,290
+أخد اسم بنزين فلا يقبل له اسم Cyclohexatriene لحظوا
+
+455
+00:43:03,290 --> 00:43:07,250
+لو واحدة بدت تعمل اشتقاق كان ممكن تقول واحد اتنين
+
+456
+00:43:07,250 --> 00:43:11,410
+تلاتة اربعة خمسة ستة هاي بداية ال double bond هاي
+
+457
+00:43:11,410 --> 00:43:15,250
+بداية اللي بعدها هاي بداية اللي بعدها و تروح تسميه
+
+458
+00:43:15,250 --> 00:43:23,950
+one three five cyclohexatriene
+
+459
+00:43:23,950 --> 00:43:30,630
+هذا الاسم غير مقبولهذا المركب أخد اسم شهرة عبر
+
+460
+00:43:30,630 --> 00:43:36,390
+التاريخ من ايام ما فصلوا العالم فرده في ال .. يمكن
+
+461
+00:43:36,390 --> 00:43:41,750
+الف وتمنمية ولا اشي زي هيك، خمسة و عشرين زمان، قبل
+
+462
+00:43:41,750 --> 00:43:47,770
+متين سنة، أخد اسم بنزين فما بنسميه إطلاقا
+
+463
+00:43:47,770 --> 00:43:50,970
+Cyclohexatriene
+
+464
+00:43:50,970 --> 00:43:54,250
+ف Cyclohexatriene is not a correct name، شو ال
+
+465
+00:43:54,250 --> 00:43:58,560
+correct name؟ بنزينوبهيك بننهي اليوم ان شاء الله
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8ce15a6b986ca436cb6647e6d21da75ed5443c38
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk_postprocess.srt
@@ -0,0 +1,1860 @@
+1
+00:00:21,160 --> 00:00:25,760
+بسم الله الرحمن الرحيم اليوم موضوع درسنا في
+
+2
+00:00:25,760 --> 00:00:30,500
+الكيميا العضوية موضوع درسنا في الكيميا العضوية
+
+3
+00:00:30,500 --> 00:00:36,800
+بعنوان ال alkenes طبعا احنا في الفصل الثاني
+
+4
+00:00:36,800 --> 00:00:40,540
+اتكلمنا على ال alkenes و ال cycloalkenes اللي
+
+5
+00:00:40,540 --> 00:00:45,660
+بيمتازوا بالمجموعة الوظيفية اللي هي كلها single
+
+6
+00:00:45,660 --> 00:00:49,610
+bondsالروابط اللي موجودة فيهم single bonds أخدنا
+
+7
+00:00:49,610 --> 00:00:54,310
+معلومات عامة عنهم طبعا درسنا الأمر ضمن الإطار
+
+8
+00:00:54,310 --> 00:00:59,010
+العام ان ال hydrocarbons they are either saturated
+
+9
+00:00:59,010 --> 00:01:02,950
+contain only single bonds such as alkenes or
+
+10
+00:01:02,950 --> 00:01:06,870
+cycloalkenes الصياغ العامة لهم واضحة or
+
+11
+00:01:06,870 --> 00:01:13,800
+unsaturated ومنهم ال alkenesربما وضحنا في الوقت
+
+12
+00:01:13,800 --> 00:01:17,360
+اللي شرحنا فيه الصيغة العامة ان ال ال keynes
+
+13
+00:01:17,360 --> 00:01:23,140
+بياخدوا الصيغة العامة CNH2N بمعنى لو انا بدي انظر
+
+14
+00:01:23,140 --> 00:01:27,620
+لأبسط ال keyne هذا ال keyne اللي هو ال إفليل اللي
+
+15
+00:01:27,620 --> 00:01:33,520
+مكوّن من ذرتين كاربونهو أبسط ال keen ولذلك مرات
+
+16
+00:01:33,520 --> 00:01:39,160
+بيسموه ال parent ال keen parent يعني الأساسي أو
+
+17
+00:01:39,160 --> 00:01:44,200
+الأبسط parent جاية من ال parents العباء parent ال
+
+18
+00:01:44,200 --> 00:01:48,380
+keen ال parent ال keen أبسط واحد هو إيش؟الـ
+
+19
+00:01:48,380 --> 00:01:51,840
+Ethylene اللى انتوا شايفينه بهذا الشكل اكيد لو
+
+20
+00:01:51,840 --> 00:02:00,140
+طلعنا على الصيغة العامة تبعته C2H4 CNH2N لما احنا
+
+21
+00:02:00,140 --> 00:02:04,500
+عملنا ال double bond حذفنا مقابلها ذرتين هيدروجين
+
+22
+00:02:06,320 --> 00:02:11,400
+الان هذا الكلام بيخلنا مرة تانية نذكر ايضا بشيء
+
+23
+00:02:11,400 --> 00:02:16,440
+اخدناه في المقدمة اللي هو انظر متذكرين العلاقة ما
+
+24
+00:02:16,440 --> 00:02:21,400
+بين انواع الروابط bond order وطول الرابط وقوة
+
+25
+00:02:21,400 --> 00:02:26,780
+الرابط قلنا ان الروابط اللي هتمر معنى للcarbon يا
+
+26
+00:02:26,780 --> 00:02:31,260
+اما روابط احدية او ثنائية او ثلاثية هذا بنسميه
+
+27
+00:02:31,260 --> 00:02:36,900
+bond orderعدد الروابط نسميه bond order الان لو
+
+28
+00:02:36,900 --> 00:02:41,560
+اجينا نتذكر ال bond angles ال bond angle اللى كانت
+
+29
+00:02:41,560 --> 00:02:47,680
+حول الكربون لما يكونوا كل روابط احدية مية وتسعة و
+
+30
+00:02:47,680 --> 00:02:53,360
+نص بيكون الشكل تتراهيدرال واضح الان لما نيجي نحكي
+
+31
+00:02:53,360 --> 00:02:58,790
+على ال double bond بتكون الزاوية120 يعني لو انا
+
+32
+00:02:58,790 --> 00:03:06,530
+بدأ اطلع بهذا الشكل 120 120 و120 المجموع قداشر 360
+
+33
+00:03:06,530 --> 00:03:12,670
+المجموع 360 الان لو بدأ اشوف طيب ايش الشكل حوالين
+
+34
+00:03:12,670 --> 00:03:16,450
+ال double bond الشكل حوالين ال double bond بنسميه
+
+35
+00:03:16,450 --> 00:03:22,910
+Triangular Planar يعني في مستوى واحد لاحظوا الذرات
+
+36
+00:03:23,440 --> 00:03:28,140
+هيدروجين كاربون هيدروجين كاربون هيدروجين كاربون لو
+
+37
+00:03:28,140 --> 00:03:32,960
+حطينا مستوى بهذا الشكل جميع الذرات في مستوى واحد
+
+38
+00:03:32,960 --> 00:03:37,000
+ولذلك الاثيليين جميع ذراته في مستوى واحد بنقول عنه
+
+39
+00:03:37,000 --> 00:03:42,180
+إيش ال planner الان الشكل ال triangular planner
+
+40
+00:03:42,180 --> 00:03:49,600
+يعني مقسوم إلىتلات أقسام الزاوية 120 120 120 واضحة
+
+41
+00:03:49,600 --> 00:03:55,540
+هذه النقطة الآن لو اجينا نحكي على ال bond length
+
+42
+00:03:55,540 --> 00:04:01,680
+مقارنة ال carbon carbon single bond مع ال carbon
+
+43
+00:04:01,680 --> 00:04:05,700
+carbon double bond أنها بتكون أقصرالـ carbon
+
+44
+00:04:05,700 --> 00:04:09,700
+carbon double bond كل ما ال bond order بيزيد ال
+
+45
+00:04:09,700 --> 00:04:14,200
+bond بتصير أقصر و ال triple bond بعد شوية هنلاحظ
+
+46
+00:04:14,200 --> 00:04:19,840
+أنها أقصر و موجودة الأطوال عندنا في ال بيكمتر الان
+
+47
+00:04:19,840 --> 00:04:23,140
+الرابطة لما بيزيد فيها ال bond order بيصير فيها
+
+48
+00:04:23,140 --> 00:04:32,070
+أمر كتير مهم هذا الأمر هوزيادة قوة الرابطة بما
+
+49
+00:04:32,070 --> 00:04:36,290
+يمنع الدوران يعني لاحظوا معي لما بيكون عند رابطة
+
+50
+00:04:36,290 --> 00:04:42,170
+أحدية فقط عند دوران ممكن حول الرابطة الأحدية لكن
+
+51
+00:04:42,170 --> 00:04:46,650
+مجرد ما بتصير هذه الرابطة رابطة ثنائية أو بالتأكيد
+
+52
+00:04:46,650 --> 00:04:53,550
+ثلاثية بيصير الدوران ممنوعبصير الدوران ممنوع هذا
+
+53
+00:04:53,550 --> 00:05:02,130
+الكلام له انعكاس مهم جدا في الكيميا انه انا لو
+
+54
+00:05:02,130 --> 00:05:08,230
+رجعت دقيقة للخلف و أخدت مركب فيه روابط أحدية يعني
+
+55
+00:05:08,230 --> 00:05:14,610
+لغيت هذه الرابطة نهائيا و اتخيلت انه عندي ال E2 مش
+
+56
+00:05:14,610 --> 00:05:20,890
+ال E2 هو مركب الروابط الأحديةالـ E2 هو مركّب
+
+57
+00:05:20,890 --> 00:05:24,250
+الهواط الأوحادية الان هنا في عندى اشي بسميه اش
+
+58
+00:05:24,250 --> 00:05:31,270
+free rotation اش بنسميه free rotation دوران حر
+
+59
+00:05:31,270 --> 00:05:34,510
+free rotation
+
+60
+00:05:36,130 --> 00:05:42,090
+طيب هذا الـ free rotation على إيش بيأثر عندى في
+
+61
+00:05:42,090 --> 00:05:48,090
+الأمور الكيميائية هيأثر على أمر مهم جدا جدا لو يا
+
+62
+00:05:48,090 --> 00:05:55,170
+ترى أنا إجيت بدلت من هنا هيدروجين بذرة كلور على
+
+63
+00:05:55,170 --> 00:06:00,890
+موقع واحد وبدلت من هنا هيدروجين تانية على ذرة كلور
+
+64
+00:06:00,890 --> 00:06:06,740
+بموقع واحد وامسكت الجزاءلاحظوا معي الدوران ممكن
+
+65
+00:06:06,740 --> 00:06:10,820
+ألاحظ أن ذرتين الكلور هدولة جايين بمستوى واحد يقبل
+
+66
+00:06:10,820 --> 00:06:17,780
+بعض ممكن يلفوا بدت واحدة تغلط و تقول sis انتبهوا
+
+67
+00:06:17,780 --> 00:06:22,140
+معي ممكن يلفوا صار بينهم زيو معين كمان كمان كمان
+
+68
+00:06:22,140 --> 00:06:25,320
+ممكن بلحظة من اللحظات أثناء الدوران يكونوا بهذا
+
+69
+00:06:25,320 --> 00:06:34,380
+الشكلإذا لو سألت كم هيئة تنتج عن الدوران متوقع
+
+70
+00:06:34,380 --> 00:06:42,620
+لهذا الشكل أكيد عدد لانهائي من الهيئات يعني
+
+71
+00:06:42,620 --> 00:06:47,420
+الزاوية ما بين هدولة دارتين سفر بدت ألف صارت واحد
+
+72
+00:06:47,420 --> 00:06:50,780
+من عشر او اتنين من عشر او تلات من عشر اربع زادت
+
+73
+00:06:50,780 --> 00:06:55,680
+زادت زادت زادت زادت صاروا عكس بعضطوله أنا بلوف
+
+74
+00:06:55,680 --> 00:07:01,180
+بطلع هيئات مش أشكال لاحظوا بدي أميز ما بين كلمتين
+
+75
+00:07:01,180 --> 00:07:05,700
+ما بين هيئة و ما بين شكل أصلي يعني البني آدم بني
+
+76
+00:07:05,700 --> 00:07:10,740
+آدم واحد لكن يمكن أن يوجد فيه هيئات مختلفة ولذلك
+
+77
+00:07:10,740 --> 00:07:14,800
+لما بييجي في الطالب الصبح و بيعمل تمرينات الصبح
+
+78
+00:07:14,800 --> 00:07:19,180
+رياضية هيئاتين تين تلاتة أربعة بييجي في محمد و بعد
+
+79
+00:07:19,180 --> 00:07:24,360
+التمرينات بننادي عليه و بنقول عنه برضه محمدبياخد
+
+80
+00:07:24,360 --> 00:07:29,620
+ايقات مختلفة المدرس قال هيك هيك هيك هيك هيك هيك
+
+81
+00:07:29,620 --> 00:07:31,420
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+82
+00:07:31,420 --> 00:07:31,960
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+83
+00:07:31,960 --> 00:07:32,040
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+84
+00:07:32,040 --> 00:07:37,760
+هيك هيك هيك هيك هيك هيك هيك
+
+85
+00:07:37,760 --> 00:07:38,540
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+86
+00:07:38,540 --> 00:07:38,680
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+87
+00:07:38,680 --> 00:07:38,900
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+88
+00:07:38,900 --> 00:07:39,760
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+89
+00:07:39,760 --> 00:07:48,300
+هيك هيك هيك هيك هيك
+
+90
+00:07:48,300 --> 00:07:55,690
+هيك هيكهو واحد بهيئات دورانية مختلفة هيئة بنسميها
+
+91
+00:07:55,690 --> 00:07:58,650
+احنا باللغة الإنجليزية ايش Conformation
+
+92
+00:07:58,650 --> 00:08:02,490
+Conformation
+
+93
+00:08:02,490 --> 00:08:11,230
+هيئة الان مرت علينا هذه الكلمة في ال Cyclohexane
+
+94
+00:08:11,230 --> 00:08:17,190
+اذا ال Conformation او الهيئات تنتج عن شغلتينال
+
+95
+00:08:17,190 --> 00:08:22,230
+conformations بتنتج عن شغلتين الشغلة الأولى اللى
+
+96
+00:08:22,230 --> 00:08:26,370
+مرت علينا ال flipping يوم كان ال cyclohexane بيجلب
+
+97
+00:08:26,370 --> 00:08:29,770
+بيعمل flipping زى الشمسية اللى بتجلب للامام و
+
+98
+00:08:29,770 --> 00:08:33,930
+للخلف للامام و للخلف لكن بتبقى شمسية إذا ال
+
+99
+00:08:33,930 --> 00:08:39,290
+conformations يمكن أن تنشأ عن ال flipping و نمرة
+
+100
+00:08:39,290 --> 00:08:45,170
+اتنين يمكن أن تنشأ عن ال rotation الدورانفيكون
+
+101
+00:08:45,170 --> 00:08:53,610
+المُركّب مُركّب واحدبشكل واحد وبهيئات كثيرة مختلفة
+
+102
+00:08:53,610 --> 00:08:59,810
+ولذلك ال one two dichloroethane هو مركب واحد فقط
+
+103
+00:08:59,810 --> 00:09:05,030
+بهيئات مختلفة وهو في حالة دوران أبدي يعني ربنا
+
+104
+00:09:05,030 --> 00:09:10,050
+خالجه زي ما بتقول الآية الكريمة وكل في فلك يسبحون
+
+105
+00:09:10,050 --> 00:09:15,740
+بالنسبة لعلم الكيميا هذا دوران لا يتوقفالدوران حول
+
+106
+00:09:15,740 --> 00:09:19,820
+الرابطة الأوحادية تماما زى المروحة اللى بالسجف لما
+
+107
+00:09:19,820 --> 00:09:24,320
+بتلوف بنقولش عنها مروحة كتيرة بتكون بهذا الشكل بعد
+
+108
+00:09:24,320 --> 00:09:28,730
+شوية بتزيد زوايا كمانو هي في حالة دوران أبدي لكنها
+
+109
+00:09:28,730 --> 00:09:33,450
+تبقى مروحة الان هذا الـ dichloroethane في حالة
+
+110
+00:09:33,450 --> 00:09:39,550
+دوران أبدي بهيئات كثيرة ولكنه يبقى مركبا واحد فلو
+
+111
+00:09:39,550 --> 00:09:43,570
+واحدة بدت تشتري dichloroethane هتلاقي انه عندها
+
+112
+00:09:43,570 --> 00:09:51,130
+ايش مركب واحد السبب ال free rotation الان خلينا
+
+113
+00:09:51,130 --> 00:09:53,010
+نحول للالكين
+
+114
+00:09:55,450 --> 00:10:01,850
+في الالكين صار عندى double bond قوية باجى اجرب ان
+
+115
+00:10:01,850 --> 00:10:08,410
+اعمل الدوران مافيش دورانمافيش إمكانية للدوران
+
+116
+00:10:08,410 --> 00:10:14,510
+الرابطة قوية وبناء على ذلك لو بدأ أحول هذا الشكل
+
+117
+00:10:14,510 --> 00:10:19,870
+للشكل التاني إيش بدأ أعمل؟ كسر وتكوين رابط قبل
+
+118
+00:10:19,870 --> 00:10:23,030
+شوية لما كانت الرابط أحدية بدأ أحول هذا للتاني
+
+119
+00:10:23,030 --> 00:10:28,130
+rotation فهذه هيئات وليس تعبير عن مركب جديد لكن
+
+120
+00:10:28,130 --> 00:10:32,070
+الأن أنا أمام ظاهرة جديدة لو بدأ أحول هذا المركب
+
+121
+00:10:32,070 --> 00:10:38,290
+اللي قلنا عنه cess إلى ال Transبدي أكسر الرابطة
+
+122
+00:10:38,290 --> 00:10:44,790
+وأكسر الرابطة وأعمل المركب لجديد ولذلك هدول صاروا
+
+123
+00:10:44,790 --> 00:10:50,250
+مركبين مختلفين بخواص مختلفة يومها بتروح تشتري one
+
+124
+00:10:50,250 --> 00:10:54,890
+two dichloro ethane اللي في double bond بنهاية إيش
+
+125
+00:10:54,890 --> 00:11:00,790
+in بتشتروا مركب ولا اتنين؟ مركبين واحد اسمه ال
+
+126
+00:11:00,790 --> 00:11:07,980
+Transone two dichloro ethane و التاني اسمه sis one
+
+127
+00:11:07,980 --> 00:11:13,660
+two dichloro ethane واضح هذه الفكرة فكرة ال sis و
+
+128
+00:11:13,660 --> 00:11:17,680
+ال trans الآن
+
+129
+00:11:17,680 --> 00:11:23,560
+لو يا تورا اجينا نمشي خطوة للامام طيب عندنا ال
+
+130
+00:11:23,560 --> 00:11:29,650
+kings بدنا نتعلم كيف نسميهم و ال kindsمثل ما
+
+131
+00:11:29,650 --> 00:11:35,330
+اتعودنا نسمي في الـ Alkanes بدنا أطول سلسلة لكن
+
+132
+00:11:35,330 --> 00:11:42,530
+هنا نضع شرط أطول سلسلة تحتوي على الرابطة الثنائية
+
+133
+00:11:42,530 --> 00:11:47,150
+أو الثلاثية بمعنى ممكن تشوفوا السلسلة طولها سبع
+
+134
+00:11:47,150 --> 00:11:51,610
+كربونات متتالية لكن كلها روابط أحدية والجزء في
+
+135
+00:11:51,610 --> 00:11:54,310
+رابطة ثنائية
+
+136
+00:11:55,990 --> 00:12:02,230
+يجب أن تحتوي أطول سلسلة على رابطة ثنائية ممكن
+
+137
+00:12:02,230 --> 00:12:09,930
+أعطيكم مثال حتى التطبيق يكون واضح ممكن نعطي مثال
+
+138
+00:12:09,930 --> 00:12:14,750
+يعني لو أعطينا فقط نرسم ذرات ال carbon وحاطينا
+
+139
+00:12:14,750 --> 00:12:21,340
+carbon 2 ثلاثة carbon 2 ثلاثةبهذا الشكل الان لو
+
+140
+00:12:21,340 --> 00:12:28,060
+جينا وعطينا هنا كمان carbon نحسب أطول سلسلة ممكن
+
+141
+00:12:28,060 --> 00:12:32,940
+واحدة تيجي تقول واحد، تنين، تلاتة، أربعة، خمسة،
+
+142
+00:12:32,940 --> 00:12:39,040
+ستة، سبعة، تمانية وممكن كمان تقول هنا كمان رابطة
+
+143
+00:12:39,040 --> 00:12:42,880
+تسعة الان لاحظوا هذه السلسلة اللي اخترتها مافيش
+
+144
+00:12:42,880 --> 00:12:46,840
+فيها ال double bond مش هتمشي معاه بدي سلسلة يكون
+
+145
+00:12:46,840 --> 00:12:58,790
+فيها ال double bond1 2 3 4 5 6 7 او 1 2 3 4 5 6 7
+
+146
+00:12:58,790 --> 00:13:05,950
+ممكن خلهم يختاروا واحدة منهم حسب الاكثر تفرع عن
+
+147
+00:13:05,950 --> 00:13:09,810
+اللي حكينا عليه اذا كان موجود الان اذا ماباخدش
+
+148
+00:13:09,810 --> 00:13:13,620
+السلسلة التسعة اللي مافيش فيها double bondلما ابدأ
+
+149
+00:13:13,620 --> 00:13:18,320
+أسمي لازم السلسلة اللي أخدها يكون فيها double bond
+
+150
+00:13:18,320 --> 00:13:23,980
+وجدت بنهي المركب بنهايك E لو كانت هذه triple bond
+
+151
+00:13:23,980 --> 00:13:30,500
+بنهي المركب بنهايك I إذا التسمية ببساطة أن نختار
+
+152
+00:13:30,500 --> 00:13:36,740
+أطول سلسلة تحتوي علىDouble أو Triple Point إذا كان
+
+153
+00:13:36,740 --> 00:13:40,360
+Double Point بنهي المركب بالنهاية E وإذا Triple
+
+154
+00:13:40,360 --> 00:13:45,580
+Point بنهي المركب بالنهاية I خلّينا نشوف أمثلة من
+
+155
+00:13:45,580 --> 00:13:50,960
+ال slides هاي في عندنا مثال لما نيجي نبحث عن أطول
+
+156
+00:13:50,960 --> 00:13:58,880
+سلسلة واحد، اتنين، تلاتة، أربعة، خمسة هذه اللي
+
+157
+00:13:58,880 --> 00:14:01,240
+فيها Double Point في واحد، اتنين، تلاتة Double
+
+158
+00:14:01,240 --> 00:14:06,750
+Point خارجها، مابديهاالآن مجرد ما اختارنا أطول
+
+159
+00:14:06,750 --> 00:14:13,510
+سلسلة على طول بدنا نقول إنه في إمكانيتين للترقيم
+
+160
+00:14:13,510 --> 00:14:17,850
+يعني هذه أطول سلسلة ممكن أوضحها أنا باللون الأزرق،
+
+161
+00:14:17,850 --> 00:14:21,850
+هذه أطول سلسلة، الآن بدي أبدأ واحد هان خمسان ولا
+
+162
+00:14:21,850 --> 00:14:26,520
+واحد هان خمسان، هذا سؤال مهم جدابدأ أخلّي ال
+
+163
+00:14:26,520 --> 00:14:31,180
+double bond تاخد أقل ترقيم، بداية ال double bond،
+
+164
+00:14:31,180 --> 00:14:35,480
+لاحظوا هنا ال double bond بدايتها وين؟ اتنين، لو
+
+165
+00:14:35,480 --> 00:14:40,680
+برقم من هنا واحد، اتنين، تلاتة، وين ال double bond
+
+166
+00:14:40,680 --> 00:14:46,170
+أقرب للطرف؟من هام و لذلك برقم واحد اتنين تلاتة
+
+167
+00:14:46,170 --> 00:14:52,210
+اربعة خمسة طالما خمس ذرات carbon إذا المركب بنتين
+
+168
+00:14:52,210 --> 00:14:59,530
+بنتين يلتهي بين في double bond الآن الين هذه اللي
+
+169
+00:14:59,530 --> 00:15:05,160
+هي ال double bond وين بدايتها؟فالـ carbon 2 هي
+
+170
+00:15:05,160 --> 00:15:10,160
+جاية بين 2 و 3 أنا بذكر فقط نقطة البداية و لذلك
+
+171
+00:15:10,160 --> 00:15:16,840
+هذا بقول عنه two بنتين فال two اللي موجودة هنا هذه
+
+172
+00:15:16,840 --> 00:15:22,640
+تحدد بداية ال double bond يجب أن احدد بداية ال
+
+173
+00:15:22,640 --> 00:15:31,320
+double bond هذه
+
+174
+00:15:31,320 --> 00:15:37,290
+و هذه زي بعضو هيقدروا لنفس الاسم لو قلت سلسلة واحد
+
+175
+00:15:37,290 --> 00:15:43,210
+اتنين تلاتة اربعة خمسة و لو سميت الآن هذه two مثل
+
+176
+00:15:43,210 --> 00:15:48,330
+و four promo طب لو عديت من هنا two مثل و four
+
+177
+00:15:48,330 --> 00:15:52,110
+promo لو قلت واحد اتنين تلاتة اربعة خمسة two مثل و
+
+178
+00:15:52,110 --> 00:15:57,010
+four promo نفس الأشياء طالما عندك مجموعتين مثل على
+
+179
+00:15:57,010 --> 00:16:00,250
+نفس ال carbon ابدأ من أي واحدة مافيش عندك مشكلة
+
+180
+00:16:01,300 --> 00:16:04,480
+واحدة منهم تكون ضمن السلسلة والثانية تصبح
+
+181
+00:16:04,480 --> 00:16:08,440
+substitute طبعا أكيد هطبق القواعد اللي حكيتها في
+
+182
+00:16:08,440 --> 00:16:12,440
+البداية أنه لو مابدأ أذكر ال promo و ال مثل كيف
+
+183
+00:16:12,440 --> 00:16:16,500
+بدي أذكرهم alphabetically alphabetically بمعنى ال
+
+184
+00:16:16,500 --> 00:16:23,760
+B قبلالان ..الان هاي مركب ثاني موجود عندى لحظة هذا
+
+185
+00:16:23,760 --> 00:16:27,880
+المركب الثاني كان ممكن يوجع البعض في خطأ معين انه
+
+186
+00:16:27,880 --> 00:16:34,020
+يبحث عن أطول سلسلة روابط أحدية لازم ال double bond
+
+187
+00:16:34,020 --> 00:16:38,540
+بترفينها تكون ضمن السلسلة ولذلك هذه السلسلة بهذا
+
+188
+00:16:38,540 --> 00:16:42,400
+الشكل لا يجوز اعتبارهابنعتبر السلسلة اللي مبينة
+
+189
+00:16:42,400 --> 00:16:46,860
+بالأحمر واحد اتنين تلاتة أربعة خمسة ستة طالما ستة
+
+190
+00:16:46,860 --> 00:16:53,340
+إذا المركبة هيكسين الرابط فيه، وين بدايتها؟ إذا
+
+191
+00:16:53,340 --> 00:16:58,620
+هذا one هيكسين، واضح؟ هذا one هيكسين عن امر اتنين،
+
+192
+00:16:58,620 --> 00:17:04,810
+موجود تلت كربونات في هالشكل، احفظ ما اسمهم بروبين2
+
+193
+00:17:04,810 --> 00:17:14,630
+Probel و 1 Hexane لأن
+
+194
+00:17:14,630 --> 00:17:22,010
+انتهانها بترتكب خطأ كبير جدا جدا مافيش اشي اسمه
+
+195
+00:17:22,010 --> 00:17:27,630
+مجموعات افكر فيها قبل ما ابحث عن أطول سلسلة هذا من
+
+196
+00:17:27,630 --> 00:17:33,030
+الأخطاء الشائعةجدا عند الطلاب من الأخطاء الشائعة
+
+197
+00:17:33,030 --> 00:17:38,630
+جدا عند الطلاب السؤال اللي سألته زملتكوا سؤال جيد
+
+198
+00:17:38,630 --> 00:17:43,170
+بيجعوا فيه كتير من الطلاب انه بيحفظوا مجموعة معينة
+
+199
+00:17:43,170 --> 00:17:47,430
+و انبسطوا كتير على حالهم انه حفظوا شكل هالمجموعة
+
+200
+00:17:47,430 --> 00:17:51,670
+بيروحوا بغلطوا في القاعدة الأساسية في التسمية انه
+
+201
+00:17:51,670 --> 00:17:56,810
+يجب ان ابحثعن أطول سلسلة قبل أن أفكر بالمجموعات
+
+202
+00:17:56,810 --> 00:18:00,030
+بعد ما أبحث عنها حكيتلكم ممكن تعلموها بقلم
+
+203
+00:18:00,030 --> 00:18:05,510
+الفوسفور ما تفرع منها فهو مجموعات سأعطي مثال يعني
+
+204
+00:18:05,510 --> 00:18:10,710
+لو عندكم مثلا هاي كاربون تنتين تلاتةأربعة بهذا
+
+205
+00:18:10,710 --> 00:18:16,850
+الشكل فقط أضع ذرات الكاربون ال A لاحظوا طالب درست
+
+206
+00:18:16,850 --> 00:18:22,330
+جيدا ممكن أول ما تشوف هذا المركب تفكر تقول هذه
+
+207
+00:18:22,330 --> 00:18:28,390
+الكاربون اللي حملة تلاتة كاربون تيرتشاري
+
+208
+00:18:28,390 --> 00:18:34,950
+بيوتلتفكر بهذا المنطق وبناء على ذلك تبدأ ترتكب
+
+209
+00:18:34,950 --> 00:18:41,010
+الأخطاء الكتيرة جدا تقول هذا المركب 1,2,3,4 يحمل
+
+210
+00:18:41,010 --> 00:18:47,510
+على موقع تيرتشار بيوتيل و تيجي تسمي هذا المركب two
+
+211
+00:18:47,510 --> 00:18:55,220
+tertiary butyl butaneجابت كيميا كتير، درست كتير،
+
+212
+00:18:55,220 --> 00:18:59,900
+بس مامشيتش بالاتجاه الصحي، ليش؟ لأنه المفروض أطول
+
+213
+00:18:59,900 --> 00:19:04,080
+سلسلة، الآن لما ابدأ أقول أطول سلسلة، أجرب أعد
+
+214
+00:19:04,080 --> 00:19:09,500
+كتير، هعد من هنا في الآخر، واحد، اتنين، تلاتة،
+
+215
+00:19:09,500 --> 00:19:16,330
+اربعة، خمسةاللي كانت تعتبرها سلسلة مجموعة دخلت ضمن
+
+216
+00:19:16,330 --> 00:19:20,810
+السلسلة هاي أطول سلسلة، واحد، اتنين، تلاتة، أربعة،
+
+217
+00:19:20,810 --> 00:19:24,730
+خمسة، هاي أطول سلسلة، بنتين الآن، ماذا تبقى
+
+218
+00:19:24,730 --> 00:19:31,850
+للخارج؟ كل ما تبقى فهو مجموعات أه، اتبقى عندها مثل
+
+219
+00:19:31,850 --> 00:19:37,650
+و مثل، و هذه لو كملناها كمان مثل CH3
+
+220
+00:19:38,900 --> 00:19:45,360
+فالاسم الصحيح لهذا المركب شو هيكون؟ two two three
+
+221
+00:19:45,360 --> 00:19:54,360
+اتراي مثل بنتين واضح؟ فما تفكروا نهائيا بمجموعات
+
+222
+00:19:54,360 --> 00:19:59,400
+قبل ما تحددوا أطول سلسلة و اتعلموها ما زاد عن أطول
+
+223
+00:19:59,400 --> 00:20:06,800
+سلسلة شوفوا إيش اسمه فكيف تبدأ التسمية؟بأطول سلسلة
+
+224
+00:20:06,800 --> 00:20:10,320
+مش أشوف أن هذه مجموعة و هذه مجموعة و التنتين
+
+225
+00:20:10,320 --> 00:20:16,880
+موجودات كجزء من أطول سلسلة واضحة الفكرة؟
+
+226
+00:20:36,770 --> 00:20:43,390
+وعشان هيك لا بأس ان اعطيكم مسألة تانية تفكروا فيها
+
+227
+00:20:43,390 --> 00:20:58,450
+تعملوها homework على هذا الموضوع تحديدا مسألة
+
+228
+00:20:58,450 --> 00:21:04,080
+جميلة جداطبعا اللي حافظين المجموعات يا الله
+
+229
+00:21:04,080 --> 00:21:07,400
+isopropyl و isopropyl ضاي isopropyl واحد اتنين
+
+230
+00:21:07,400 --> 00:21:12,440
+تلاتة اربعة خمسة ستة ضاي isopropylهكسين و كل الاسم
+
+231
+00:21:12,440 --> 00:21:18,220
+غلط بديش الأن أسميه اتعبوا فيه ابحثوا عن أطول
+
+232
+00:21:18,220 --> 00:21:22,200
+سلسلة و ما زاد عنفا و مجموعات مش تيجي تقولوا أن
+
+233
+00:21:22,200 --> 00:21:24,060
+هذه isopropyl و هذه isopropyl
+
+234
+00:21:31,920 --> 00:21:39,760
+تخدوا من بعض لو سمحتوا خلينا نمشي الان انتبهوا معي
+
+235
+00:21:39,760 --> 00:21:46,500
+حكينا احنا عن ظاهرة ال
+
+236
+00:21:46,500 --> 00:21:51,960
+الكينز و ال sis و ال trans الان ازملتكوا ذكرتنا
+
+237
+00:21:51,960 --> 00:21:57,260
+بالمجموعاتبتذكرين لما أخدنا مثيل قولنا منه مجموعة
+
+238
+00:21:57,260 --> 00:22:04,560
+مثل اثل اثل بروبل بروبل و ايزو بروبل طيب يا تورا
+
+239
+00:22:04,560 --> 00:22:10,080
+الالكين لو خصمنا من الالكين هيدروجين في كمان
+
+240
+00:22:10,080 --> 00:22:14,850
+مجموعات؟يعني دول بنحفظنا الأولانيين لو خصمنا
+
+241
+00:22:14,850 --> 00:22:19,690
+الهيدروجين من الالكين في مجموعات الجواب في بعض
+
+242
+00:22:19,690 --> 00:22:24,550
+المجموعات اللي بنتعرف عليها أبسط الكين هو الاثيل
+
+243
+00:22:24,550 --> 00:22:30,190
+أو الاثيلين لو شيلنا منه الهيدروجين هذه بنعمل
+
+244
+00:22:30,190 --> 00:22:36,130
+مجموعة الالكين minus الهيدروجين بنعمل مجموعة
+
+245
+00:22:36,130 --> 00:22:43,540
+بنسميهاإزملتكوا برضه سمعتني كلمة مش مظبوطة جالت
+
+246
+00:22:43,540 --> 00:22:51,460
+فينل أنا بقول فينل في حرف ال V هذه فينل فلو حملت
+
+247
+00:22:51,460 --> 00:22:57,770
+ال chlorine بتصير vinyl chloride ليش رفضنا؟إنها
+
+248
+00:22:57,770 --> 00:23:02,430
+تقول كلمة Fennel لأن ال Fennel مجموعة تانية
+
+249
+00:23:02,430 --> 00:23:08,250
+البنزين لما بتلوجد على يعني لو أخدت هذا المركب
+
+250
+00:23:08,250 --> 00:23:14,550
+بيوتين صح؟ أو هذا المركب بنتين حطوا عليها هنا
+
+251
+00:23:14,550 --> 00:23:22,310
+بنزينة بنزينة مخصوم منها Hydrogen هذه كمجموعة
+
+252
+00:23:22,310 --> 00:23:24,790
+اسمها Fennel
+
+253
+00:23:27,710 --> 00:23:33,290
+الان الفنل مجموعة البنزين الـ C6H6 الخاصة منه
+
+254
+00:23:33,290 --> 00:23:40,590
+هيدروجين صار C6H6H5 وبيشبك من هذا الموقع هذه
+
+255
+00:23:40,590 --> 00:23:47,830
+مجموعة الفينل الان لما اجي اخد الاثيليين اخص منه
+
+256
+00:23:47,830 --> 00:23:55,690
+هيدروجين بيصير C2H3 مجموعة الفينل ولذلك لما بتلفظه
+
+257
+00:23:55,690 --> 00:24:02,390
+ميزه كلمة فينل عن كلمة فينل هذه مجموعة و هذه
+
+258
+00:24:02,390 --> 00:24:08,550
+مجموعة فينل فينلهذه المجموعة الأولى مشتقة من إيش؟
+
+259
+00:24:08,550 --> 00:24:13,550
+من الإيثيلين من خلال أن أحذف منه هيدروجينة طبعا
+
+260
+00:24:13,550 --> 00:24:18,750
+موضوع الإيثيلين موضوع سهل جدا ليش؟ لأنه في
+
+261
+00:24:18,750 --> 00:24:23,790
+الإيثيلين الأربع ذرات هيدروجين زي بعض يعني من وين
+
+262
+00:24:23,790 --> 00:24:27,410
+ما بخسم هذه أو هذه أو هذه أو هذه شيلت هيدروجينة
+
+263
+00:24:27,410 --> 00:24:33,260
+صارت مجموعة ما اسمها؟Vinyl هذه مجموعة Vinyl الان
+
+264
+00:24:33,260 --> 00:24:37,480
+لو اتيت و حطيت Clor هنا ايش في المركب؟ Vinyl
+
+265
+00:24:37,480 --> 00:24:44,120
+Cloride واضح؟ لكن لو يا تورا اتيت على المركب اللي
+
+266
+00:24:44,120 --> 00:24:48,420
+مباشرة بيجي عند بعض ال إيثيلين اللي هو البروبين
+
+267
+00:24:48,420 --> 00:24:55,580
+حطيت كمان Carbon خليني
+
+268
+00:24:55,580 --> 00:24:57,180
+اعمل ال model عشان نفهم
+
+269
+00:25:12,820 --> 00:25:25,430
+الان لاحظوا هذا جزء لبروبين CH2 CH CH3واضح؟
+
+270
+00:25:25,430 --> 00:25:31,270
+إبروبين و لو بتشوفوا الصيغة تبعته C3H6
+
+271
+00:25:31,270 --> 00:25:38,590
+يعني CNH2N واضحة صيغته؟ الآن في أنواع كتيرة من
+
+272
+00:25:38,590 --> 00:25:43,010
+الهيدروجين يعني هدول نوع، هذي نوع، هذي نوع، يمكن
+
+273
+00:25:43,010 --> 00:25:46,130
+هذي نوع، أنواع كتيرة من الهيدروجين طب أنا بقول لو
+
+274
+00:25:46,130 --> 00:25:49,850
+حذفت منه هيدروجين بيطلع مجموعةيا ترى أحذف هذه اللي
+
+275
+00:25:49,850 --> 00:25:52,930
+عند ال double bond ولا أحذف اللي بالوسط ولا أحذف
+
+276
+00:25:52,930 --> 00:25:58,490
+اللي هنا الحقيقة المجموعة الهيدروجين اللي بيحذفوها
+
+277
+00:25:58,490 --> 00:26:04,190
+من ال CH3 هنا واضح؟
+
+278
+00:26:04,190 --> 00:26:08,050
+يمكن أن تحذف الأشياء التانية لكن ليس لها اسم الآن
+
+279
+00:26:08,050 --> 00:26:12,550
+بهذا الشكل صار عند CH2
+
+280
+00:26:13,730 --> 00:26:20,930
+CH وهنا CH2 جاهزة أن تتفاعل مع شيء تاني جاهزة
+
+281
+00:26:20,930 --> 00:26:26,250
+تتفاعل مع شيء تاني هذه المجموعة بنسميها ألل إيش
+
+282
+00:26:26,250 --> 00:26:30,550
+بنسميها؟ ألل فلو حطيتي كلور محل الهيدروجينة هنا
+
+283
+00:26:30,550 --> 00:26:37,110
+تحديدا محل منحفة ال H على CH صار اسم المركب ألل
+
+284
+00:26:37,110 --> 00:26:42,980
+كلورايدواضح؟ فهذا المركب شو بيصير اسمه؟ ألل
+
+285
+00:26:42,980 --> 00:26:46,520
+أكلورايت، بتكون تتضربوا على هالكلام طيب، لو الآن
+
+286
+00:26:46,520 --> 00:26:52,300
+جبتلكوا سؤال في الامتحان وقلتلكم ارسمولي الألل
+
+287
+00:26:52,300 --> 00:26:57,660
+الكهول زي
+
+288
+00:26:57,660 --> 00:27:01,720
+الألل أكلورايت بدل الـCl وH
+
+289
+00:27:11,220 --> 00:27:18,020
+الخلاصة اللي هي مجموعةالألل مجموعة الألل هذه
+
+290
+00:27:18,020 --> 00:27:22,920
+الصحيح مجموعة الألل من الناحية التاريخية من
+
+291
+00:27:22,920 --> 00:27:29,960
+الناحية التاريخية في سبب ليش سموها ألل في سبب ليش
+
+292
+00:27:29,960 --> 00:27:36,160
+سموها ألل هذه مرتبطة بنبات التومتعرفوا الـ Toma؟
+
+293
+00:27:36,160 --> 00:27:41,000
+اه ال Toma الان ال Toma المركب الأساسي اللي فيها
+
+294
+00:27:41,000 --> 00:27:46,540
+اللي هو CH2 double bond CH CH2 الان هذه مجموعة ألل
+
+295
+00:27:46,540 --> 00:27:52,360
+ولا لأ؟ ألل بدأ تشبك من هنا وكمان لو أخدنا CH2
+
+296
+00:27:52,360 --> 00:27:58,910
+double bond CHCH2 هذه مجموعة ألل ولا لأ هدولة لما
+
+297
+00:27:58,910 --> 00:28:05,670
+بيكون بينهم ذرتين كبريت sulfur كمان رابطة sulfur
+
+298
+00:28:05,670 --> 00:28:10,070
+بيصير المركب الأساسي اللي موجود في التومة و اللي
+
+299
+00:28:10,070 --> 00:28:15,070
+بيعطيها طاعمها الآن لو قلنا طيب هذا المركب الأساسي
+
+300
+00:28:15,070 --> 00:28:23,060
+إيش بدنا نسميه هى ألل أو ألل ضاي أللو Sulphur و
+
+301
+00:28:23,060 --> 00:28:28,480
+Sulphur داي Sulphide فالمكوّن الأساسي اللي في
+
+302
+00:28:28,480 --> 00:28:36,540
+التومة داي قلل يعني تنتين قلل داي Sulphide
+
+303
+00:28:37,690 --> 00:28:42,430
+dialyl disulfide الآن هذا المركب طلو من التومة
+
+304
+00:28:42,430 --> 00:28:47,170
+لقوا في هذه المجموعة رجعوا لاسم التومة في علم
+
+305
+00:28:47,170 --> 00:28:51,450
+النبات من أي عيلة التومة في علم النبات العيلة
+
+306
+00:28:51,450 --> 00:28:59,330
+النباتية تاعة التومة اليوم اليوم فنسبة لعيلة
+
+307
+00:28:59,330 --> 00:29:07,470
+التومة قالوا سمي هذه المجموعة الواضح؟ فالأصل جاي
+
+308
+00:29:07,470 --> 00:29:14,330
+من اسم العيلة النباتية تبعت نبات التوم اليوم فإيجى
+
+309
+00:29:14,330 --> 00:29:18,150
+اليل والمكون الأساسي اللي في التومة di-alyl
+
+310
+00:29:18,150 --> 00:29:25,140
+disulfide لاحظوا معنى التومة فيها كبريتالكابريت
+
+311
+00:29:25,140 --> 00:29:30,040
+لما بيعمل تفاعلات مش بيطلع غازات سيئة S O2 H2S
+
+312
+00:29:30,040 --> 00:29:34,080
+ولذلك منهي حتى أن الإنسان ياكل تومة ويروح يصلف
+
+313
+00:29:34,080 --> 00:29:39,300
+الجماعة من وين السبب؟ سبب الرائحة السيئة اللي
+
+314
+00:29:39,300 --> 00:29:46,430
+بتطلع منه التومة الكابريت مركبات الكابريتمراكبات
+
+315
+00:29:46,430 --> 00:29:50,210
+الكابريت مراكبات رائحتها سيئة فالانسان لما بياكل
+
+316
+00:29:50,210 --> 00:29:55,610
+التومة بيصير يطلع رائحة هذه المراكبات، واضح؟
+
+317
+00:29:55,610 --> 00:30:01,010
+فالتوم مراكب موجود فيه الكابريت وهو سبب المشكلة
+
+318
+00:30:01,010 --> 00:30:05,810
+والرائحة السيئة، إذاً هيك بنكون أخدنا مجموعتين،
+
+319
+00:30:05,810 --> 00:30:10,260
+مجموعةالفينيل والأليل بس هدول المجمعتين بدنا
+
+320
+00:30:10,260 --> 00:30:14,100
+ناخدهم لل ألكينز بدنا ناخد لل ألكينز بس هدول
+
+321
+00:30:14,100 --> 00:30:20,100
+المجمعتين الانياطورة لو إجينا قولنا في عندنا تلت
+
+322
+00:30:20,100 --> 00:30:28,020
+ذرات كربون إبروبين بيمشي الحال و بدنا نعمل المركب
+
+323
+00:30:28,020 --> 00:30:31,020
+اللي بعده المركب اللي بعده إيش بدنا نزيد عليه
+
+324
+00:30:31,020 --> 00:30:37,330
+كربون إضافيةفكروا معنى أين ممكن نحط الكربون
+
+325
+00:30:37,330 --> 00:30:44,530
+الإضافية بمعنى كم مركّب الـKey هيكون عنده من أربع
+
+326
+00:30:44,530 --> 00:30:50,890
+ذرّات كربون أنا هنا ماسك التلاتة ممكن واحدة تقول
+
+327
+00:30:50,890 --> 00:30:56,350
+بسيطة حطوا هنا الكربون هنا
+
+328
+00:30:59,320 --> 00:31:03,720
+هي صار عندى اربع ذرات كربون شايفينها؟ وهنا نكملهم
+
+329
+00:31:03,720 --> 00:31:07,800
+الهيدروجينات ولا واضحين؟ واضحين هذا المركب لو بدى
+
+330
+00:31:07,800 --> 00:31:15,460
+اسميه شو هسميه؟ one two three four اذا نبيوتين
+
+331
+00:31:15,460 --> 00:31:20,540
+وبداية ال double bond ع واحد وانا بيوتين اعرفته
+
+332
+00:31:22,860 --> 00:31:28,820
+وانا بيوتين الآن هاجي أسأل يا تورا هذا المُركّب في
+
+333
+00:31:28,820 --> 00:31:33,640
+ظاهرة الـcis والترانس احنا المرة الماضية حكينا شرط
+
+334
+00:31:33,640 --> 00:31:38,220
+ظاهرة الcis والترانس مختلفتان مختلفتان هاي ال
+
+335
+00:31:38,220 --> 00:31:41,220
+double bond هاي الكربونتين تعونها هيدروجين
+
+336
+00:31:41,220 --> 00:31:45,200
+وهيدروجين متشابهتان
+
+337
+00:31:45,200 --> 00:31:50,740
+إذا كل قصة الcis والترانس غير موجودة فيه على طول
+
+338
+00:31:50,740 --> 00:31:56,740
+انتهىمافيش فيه ألوان بيوتين هو مركب واحد فقط مافيش
+
+339
+00:31:56,740 --> 00:32:02,340
+منه cis وtrans الآن ممكن نفكر أن نحط مجموعة
+
+340
+00:32:02,340 --> 00:32:08,180
+الميثالهانة لاحظوا هذه الكربون بتحمل مجمعتين
+
+341
+00:32:08,180 --> 00:32:15,760
+مختفتين هيدروجين و CH3 لما أجي بدي أبدل واحدة من
+
+342
+00:32:15,760 --> 00:32:20,990
+هدول الهيدروجينبيصير سس و تران لاحظوا واحدة هتقول
+
+343
+00:32:20,990 --> 00:32:26,910
+بدل الهيدروجين اللي فوق سير سس اه صاروا هدولة
+
+344
+00:32:26,910 --> 00:32:33,010
+مجمعتين المثل على جهة واحدة واحدة شو بدو يصير
+
+345
+00:32:33,010 --> 00:32:42,110
+المركب اللي عندك؟ سس و لو حطينا بالاتجاه المعاكس
+
+346
+00:32:42,110 --> 00:32:52,120
+اه انتبه معاههذا one two three four two بيوتين لكن
+
+347
+00:32:52,120 --> 00:32:56,600
+المثل والمثل على جهة واحدة فهو sis الظاهرة بينت
+
+348
+00:32:56,600 --> 00:33:01,120
+لأنه مختلفتان مختلفتان الان لو بدى احاول ال sis لل
+
+349
+00:33:01,120 --> 00:33:06,620
+trans one
+
+350
+00:33:06,620 --> 00:33:12,100
+two
+
+351
+00:33:12,100 --> 00:33:18,570
+three fourtrans إذا ال two بيوتين كم مركّب منه؟
+
+352
+00:33:18,570 --> 00:33:19,730
+اتنين
+
+353
+00:33:24,560 --> 00:33:29,100
+الـ two butane كام مُركّب منه؟ الـ cis والترانس
+
+354
+00:33:29,100 --> 00:33:36,660
+الان لسه ما خلصناش نشوف كل المُركّبات الان لاحظوا
+
+355
+00:33:36,660 --> 00:33:40,940
+معناه ايش اللي عملنا احنا تحديدا لما شوفنا أنواع
+
+356
+00:33:40,940 --> 00:33:43,680
+المُركّبات قولنا بنشيل الهيدروجين من هنا وكملنا
+
+357
+00:33:43,680 --> 00:33:49,280
+طلع وانا butane اجينا نشيل هذهأعملنا sis to butyl
+
+358
+00:33:49,280 --> 00:33:53,740
+شيلنا هذه و حطينا مثل أعملنا trans to butyl طب يا
+
+359
+00:33:53,740 --> 00:33:59,200
+تورا لو شيلنا هذه و حطينا مثل هنطلع
+
+360
+00:33:59,200 --> 00:34:06,680
+في المركب المتفرع اتطلع
+
+361
+00:34:06,680 --> 00:34:08,960
+على شكله بدأ يغلبني
+
+362
+00:34:13,200 --> 00:34:16,440
+الثلاثة اللي اتفرع منهم واحد واحد اتنين تلاتة
+
+363
+00:34:16,440 --> 00:34:19,880
+اتفرع لما كان في ال ال كيرز ال double bond سمينا
+
+364
+00:34:19,880 --> 00:34:26,380
+ايزو بيوتين هنا ايش هنسميه ايزو بيوتين ايزو بيوتين
+
+365
+00:34:26,380 --> 00:34:32,000
+طب لو قلت لو واحد اسميه بال ايو باكنيم هايوا قدام
+
+366
+00:34:32,000 --> 00:34:42,200
+عينيكم اطول سلسلة فيهOne Ibropine وعن إمرأتين يحمل
+
+367
+00:34:42,200 --> 00:34:49,720
+مثل إذا ال isobutene اسمه two مثل و one ibropine
+
+368
+00:34:49,720 --> 00:35:00,480
+بناء على ذلك هذه الصيغة العامة C4H8 كم ألكين منها؟
+
+369
+00:35:00,480 --> 00:35:04,480
+C4H8
+
+370
+00:35:04,480 --> 00:35:05,960
+كم ألكين؟
+
+371
+00:35:08,360 --> 00:35:13,840
+عدوهم أربعة أربعة شفتهم يعني لو بدى يكون عندكوا
+
+372
+00:35:13,840 --> 00:35:18,060
+سؤال draw all the possible alkenes that have the
+
+373
+00:35:18,060 --> 00:35:22,820
+formula C4H8 one butane, cistobutane, trans
+
+374
+00:35:22,820 --> 00:35:28,520
+-tobutane, isobutane إذا كام ألكين؟ أربعة الآن
+
+375
+00:35:28,520 --> 00:35:36,460
+انتبهوا معي سؤال دقيق جدالو أنا سألتكم draw all
+
+376
+00:35:36,460 --> 00:35:42,220
+the possible compounds المركبات أنا قولت ال keys
+
+377
+00:35:42,220 --> 00:35:46,600
+انتبهوا جيدا draw all the possible compounds كل
+
+378
+00:35:46,600 --> 00:35:53,320
+المركبات that have the formula C4H8 كيف بدكوا
+
+379
+00:35:53,320 --> 00:35:56,860
+تبدأوا تفكروا تفضلي
+
+380
+00:35:58,830 --> 00:36:04,530
+أه احنا قلنا الصيغة المشبعة C4H10 خصمنا منها اتنين
+
+381
+00:36:04,530 --> 00:36:10,010
+يالا تكوين ال double bond يالا تكوين حلقة المركبات
+
+382
+00:36:10,010 --> 00:36:15,930
+الحلقية أيضا صيغتها العامة CNH2N
+
+383
+00:36:17,500 --> 00:36:22,720
+المُركّبات الحلقية صيغتها العامة أيضًا CNN H2N
+
+384
+00:36:22,720 --> 00:36:25,940
+بناءً على ذلك بدي أشوف كم حلقة بقدر أعمل من أربع
+
+385
+00:36:25,940 --> 00:36:29,680
+كربونات عطولي أعطوني الجواب كم حلقة بيعمل إنسان من
+
+386
+00:36:29,680 --> 00:36:40,800
+أربع كربونات؟ غلط، غلط، برضه غلط أربع
+
+387
+00:36:40,800 --> 00:36:45,840
+كربونات كم حلقة بعمل منهم؟ حرام عليكي تمانية
+
+388
+00:36:53,600 --> 00:37:02,220
+يا باخد الاربعة زي هيك CH2 CH2 CH2 CH2 يا باخد
+
+389
+00:37:02,220 --> 00:37:06,300
+تلاتة و بطلع منهم مجموعة CH3
+
+390
+00:37:11,400 --> 00:37:16,360
+هدولة كمان C4H8 لو بتكملوا ال hydrogens واحد اتنين
+
+391
+00:37:16,360 --> 00:37:20,700
+واحد اتنين واحد اتنين واحد اتنين هاي ال C4H8 تلاتة
+
+392
+00:37:20,700 --> 00:37:25,600
+و اتنين و اتنين و انا واحد تمانية مقم ال hydrogens
+
+393
+00:37:25,600 --> 00:37:31,460
+بيكملوا حالهم صح اذا لو كان سؤالي بدي كل المركبات
+
+394
+00:37:31,460 --> 00:37:39,420
+اللي صيغتها C4H8 حقيقة هيكونوا ستة أربعة الكينزو
+
+395
+00:37:39,420 --> 00:37:43,380
+اتنين Cycle of Alkanes لو قلت بدّي الحلقات اتنين
+
+396
+00:37:43,380 --> 00:37:51,140
+بدّي ال Alkanes اربعة واضحة الصورة و دائما الصيغة
+
+397
+00:37:51,140 --> 00:37:58,740
+المتساوية اللي هي CNN H2N فكروا فيها بالاتجاهين ان
+
+398
+00:37:58,740 --> 00:38:03,020
+هذه الصيغة هي صيغة Alkanes و في ذات الوقت هي صيغة
+
+399
+00:38:03,020 --> 00:38:07,300
+Cycle of Alkanes واضحة الفكرة
+
+400
+00:38:18,050 --> 00:38:22,150
+ناخد أمثلة إضافية على موضوع التسمية لو عندي double
+
+401
+00:38:22,150 --> 00:38:28,290
+bond نهاية المركب إيش؟ in طب لو كنتين double
+
+402
+00:38:28,290 --> 00:38:36,180
+bonds؟ضايقين، لو تلاتة double bonds، اترايقين، لو
+
+403
+00:38:36,180 --> 00:38:44,680
+أربعة double bonds، تتراقين، و هكذا، واضح؟ ضايقين،
+
+404
+00:38:44,680 --> 00:38:46,420
+اتراقين، تتراقين، و هكذا، واضح؟ ضايقين، اتراقين،
+
+405
+00:38:46,420 --> 00:38:46,720
+تتراقين، و هكذا، واضح؟ ضايقين، اتراقين، تتراقين، و
+
+406
+00:38:46,720 --> 00:38:47,240
+هكذا، واضح؟ ضايقين، اتراقين، تتراقين، و هكذا،
+
+407
+00:38:47,240 --> 00:38:47,960
+ضايقين، اتراقين، تتراقين، و هكذا، واضح؟ ضايقين،
+
+408
+00:38:47,960 --> 00:38:52,380
+اتراقين، تتراقين، و هكذا، واضح؟تنتين اذا بده يبين
+
+409
+00:38:52,380 --> 00:38:57,180
+في ضايين هو كله اربع كربونات بيصير اسمه بيوتا
+
+410
+00:38:57,180 --> 00:39:01,800
+ضايين يعني بيوتين في تنتين اين في تنتين double
+
+411
+00:39:01,800 --> 00:39:08,620
+bonds لازم احدد وين مواقعهم نقطة البداية واحد و
+
+412
+00:39:08,620 --> 00:39:13,040
+تلاتة و عن اثري بيوتا ضايين و عن امر اتنين شو
+
+413
+00:39:13,040 --> 00:39:20,600
+بيحمل مثل لاحظوا كان واحدة ممكن تغلطاتسمى من هنا
+
+414
+00:39:20,600 --> 00:39:26,020
+اترقم من هنا واحد اتنين تلاتة هاي one three و هاي
+
+415
+00:39:26,020 --> 00:39:29,920
+one three لاحظوا هذا ال one three يخلى المثل تاخد
+
+416
+00:39:29,920 --> 00:39:35,380
+نمرة اتنين هذا ال one three بيخلى المثل تاخد تلاتة
+
+417
+00:39:35,380 --> 00:39:38,740
+انا عندي قاعدة عامة في الكيميا العضوية lower
+
+418
+00:39:38,740 --> 00:39:40,360
+numbering
+
+419
+00:39:42,150 --> 00:39:45,370
+واضح؟ يعني لما صار من هنا one and three و واحدة
+
+420
+00:39:45,370 --> 00:39:49,730
+تانية اتسمى من هنا بالازرق برضه one and three اخد
+
+421
+00:39:49,730 --> 00:39:52,650
+هذه ال one and three ولا هذه ال one and three ال
+
+422
+00:39:52,650 --> 00:39:55,870
+one and three اللي بالأصمر بتخل المثل على اتنين ال
+
+423
+00:39:55,870 --> 00:39:58,490
+one and three اللي بالازرق بتخل المثل على تلاتة
+
+424
+00:39:58,490 --> 00:40:03,030
+بتدله one number و لذلك هذا two مثل one and three
+
+425
+00:40:03,030 --> 00:40:09,310
+بيتضايين مش three مثل one and three بيتضايين الآن
+
+426
+00:40:09,310 --> 00:40:15,530
+هيعندي حلقةبدل Cyclopentane إذا فيها double bond؟
+
+427
+00:40:15,530 --> 00:40:21,230
+Cyclopentene شفتوا أين التغير؟ إيه؟ Cyclopentene
+
+428
+00:40:21,230 --> 00:40:26,290
+بدل Cyclopentene الآن لازم في الترقيم أمر بالبداية
+
+429
+00:40:26,290 --> 00:40:30,310
+على ال double bonds أسرع ما يمكن لاحظوا واحدة ممكن
+
+430
+00:40:30,310 --> 00:40:33,550
+تفكر تقول واحد، تنين هين مريت على ال double bond
+
+431
+00:40:33,550 --> 00:40:38,130
+من طرفنا واحد، اتنين إجت ال مثل الآن على أكم؟تلاتة
+
+432
+00:40:38,130 --> 00:40:42,870
+لو واحدة رقمت من هنا واحد اتنين هتقول تلاتة اربعة
+
+433
+00:40:42,870 --> 00:40:48,770
+هتخل ال مثل على خمسة ان هو الأصحى اذا من هنا برقم
+
+434
+00:40:48,770 --> 00:40:51,790
+واحد اتنين تلاتة اربعة خمسة ال three مثل
+
+435
+00:40:51,790 --> 00:40:57,930
+Cyclopentane المركب اللي بعدهCyclohexane ولا
+
+436
+00:40:57,930 --> 00:41:04,610
+Cyclohexadiene؟ Cyclohexadiene
+
+437
+00:41:04,610 --> 00:41:08,850
+بدي أقل ترقيب في البداية للـ Double bonds لحظة،
+
+438
+00:41:08,850 --> 00:41:13,970
+واحد، اتنين، تلاتة، أربعة يعني لو خلت هذه واحد
+
+439
+00:41:13,970 --> 00:41:20,050
+بدايتها، هذه بدايتها تلاتة الآن لو خلت هذه واحد،
+
+440
+00:41:20,050 --> 00:41:24,430
+هذه بدايتها أيضا تلاتة لكن هذه التلاتة بتخلي
+
+441
+00:41:24,430 --> 00:41:31,450
+البرومعلى خمسة one two three four five لو واحدة
+
+442
+00:41:31,450 --> 00:41:36,630
+غلطت هي أنا one three أيضا واحد نعمله بالأسود
+
+443
+00:41:36,630 --> 00:41:44,450
+اتنين تلاتة هذا one three و هذا one three لكن هذا
+
+444
+00:41:44,450 --> 00:41:48,830
+ال one three four five six خلال الرمعة ستة هنول
+
+445
+00:41:48,830 --> 00:41:55,290
+أصح ال lowerعشان يك الأسماء هنا موجودة بشكل صحيح
+
+446
+00:41:55,290 --> 00:42:01,670
+five brom one three cyclohexadiene لو تلاتة double
+
+447
+00:42:01,670 --> 00:42:09,130
+bonds تريين تلاتة تريين و بتحطوا الأرقام و
+
+448
+00:42:09,130 --> 00:42:15,730
+بتنتبهولها لو أربعة double bondsتتراين و هكذا
+
+449
+00:42:15,730 --> 00:42:23,190
+واضح؟ لكن هنا يجب أن ننوح لأمر لحظة ال Cyclohexane
+
+450
+00:42:23,190 --> 00:42:34,370
+هذا ايش اسمه؟ Cyclohexane هذا تنتين
+
+451
+00:42:42,130 --> 00:42:47,850
+Cyclohexadiene هيو موجود عندكم الآن ضمن نفس
+
+452
+00:42:47,850 --> 00:42:53,430
+المنطقة لو واحدة بدها تسمي هذا ممكن
+
+453
+00:42:53,430 --> 00:42:57,310
+تفكر تسميه Cyclohexatriene الآن عبر التاريخ هذا
+
+454
+00:42:57,310 --> 00:43:03,290
+أخد اسم بنزين فلا يقبل له اسم Cyclohexatrieneلحظوا
+
+455
+00:43:03,290 --> 00:43:07,250
+لو واحدة بدت تعمل اشتقاق كان ممكن تقول واحد اتنين
+
+456
+00:43:07,250 --> 00:43:11,410
+تلاتة اربعة خمسة ستة هاي بداية ال double bond هاي
+
+457
+00:43:11,410 --> 00:43:15,250
+بداية اللي بعدها هاي بداية اللي بعدها و تروح تسميه
+
+458
+00:43:15,250 --> 00:43:23,950
+one three five cyclohexatriene
+
+459
+00:43:23,950 --> 00:43:30,630
+هذا الاسم غير مقبولهذا المركب أخد اسم شهرة عبر
+
+460
+00:43:30,630 --> 00:43:36,390
+التاريخ من ايام ما فصلوا العالم فرده في ال .. يمكن
+
+461
+00:43:36,390 --> 00:43:41,750
+الف وتمنمية ولا اشي زي هيك، خمسة و عشرين زمان، قبل
+
+462
+00:43:41,750 --> 00:43:47,770
+متين سنة، أخد اسم بنزين فما بنسميه إطلاقا
+
+463
+00:43:47,770 --> 00:43:50,970
+Cyclohexatriene
+
+464
+00:43:50,970 --> 00:43:54,250
+ف Cyclohexatriene is not a correct name، شو ال
+
+465
+00:43:54,250 --> 00:43:58,560
+correct name؟ بنزينوبهيك بننهي اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..861d2cfec39fc28d2483acb10a64f8fe8339f6fc
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/gPDsINexngk_raw.srt
@@ -0,0 +1,1864 @@
+1
+00:00:21,160 --> 00:00:25,760
+بسم الله الرحمن الرحيم اليوم موضوع درسنا في
+
+2
+00:00:25,760 --> 00:00:30,500
+الكيميا العضوية موضوع درسنا في الكيميا العضوية
+
+3
+00:00:30,500 --> 00:00:36,800
+بعنوان ال alkenes طبعا احنا في الفصل الثاني
+
+4
+00:00:36,800 --> 00:00:40,540
+اتكلمنا على ال alkenes و ال cycloalkenes اللي
+
+5
+00:00:40,540 --> 00:00:45,660
+بيمتازوا بالمجموعة الوظيفية اللي هي كلها single
+
+6
+00:00:45,660 --> 00:00:49,610
+bondsالروابط اللي موجودة فيهم single bonds أخدنا
+
+7
+00:00:49,610 --> 00:00:54,310
+معلومات عامة عنهم طبعا درسنا الأمر ضمن الإطار
+
+8
+00:00:54,310 --> 00:00:59,010
+العام ان ال hydrocarbons they are either saturated
+
+9
+00:00:59,010 --> 00:01:02,950
+contain only single bonds such as alkenes or
+
+10
+00:01:02,950 --> 00:01:06,870
+cycloalkenes الصياغ العامة لهم واضحة or
+
+11
+00:01:06,870 --> 00:01:13,800
+unsaturated ومنهم ال alkenesربما وضحنا في الوقت
+
+12
+00:01:13,800 --> 00:01:17,360
+اللي شرحنا فيه الصيغة العامة ان ال ال keynes
+
+13
+00:01:17,360 --> 00:01:23,140
+بياخدوا الصيغة العامة CNH2N بمعنى لو انا بدي انظر
+
+14
+00:01:23,140 --> 00:01:27,620
+لأبسط ال keyne هذا ال keyne اللي هو ال إفليل اللي
+
+15
+00:01:27,620 --> 00:01:33,520
+مكوّن من ذرتين كاربونهو أبسط ال keen ولذلك مرات
+
+16
+00:01:33,520 --> 00:01:39,160
+بيسموه ال parent ال keen parent يعني الأساسي أو
+
+17
+00:01:39,160 --> 00:01:44,200
+الأبسط parent جاية من ال parents العباء parent ال
+
+18
+00:01:44,200 --> 00:01:48,380
+keen ال parent ال keen أبسط واحد هو إيش؟الـ
+
+19
+00:01:48,380 --> 00:01:51,840
+Ethylene اللى انتوا شايفينه بهذا الشكل اكيد لو
+
+20
+00:01:51,840 --> 00:02:00,140
+طلعنا على الصيغة العامة تبعته C2H4 CNH2N لما احنا
+
+21
+00:02:00,140 --> 00:02:04,500
+عملنا ال double bond حذفنا مقابلها ذرتين هيدروجين
+
+22
+00:02:06,320 --> 00:02:11,400
+الان هذا الكلام بيخلنا مرة تانية نذكر ايضا بشيء
+
+23
+00:02:11,400 --> 00:02:16,440
+اخدناه في المقدمة اللي هو انظر متذكرين العلاقة ما
+
+24
+00:02:16,440 --> 00:02:21,400
+بين انواع الروابط bond order وطول الرابط وقوة
+
+25
+00:02:21,400 --> 00:02:26,780
+الرابط قلنا ان الروابط اللي هتمر معنى للcarbon يا
+
+26
+00:02:26,780 --> 00:02:31,260
+اما روابط احدية او ثنائية او ثلاثية هذا بنسميه
+
+27
+00:02:31,260 --> 00:02:36,900
+bond orderعدد الروابط نسميه bond order الان لو
+
+28
+00:02:36,900 --> 00:02:41,560
+اجينا نتذكر ال bond angles ال bond angle اللى كانت
+
+29
+00:02:41,560 --> 00:02:47,680
+حول الكربون لما يكونوا كل روابط احدية مية وتسعة و
+
+30
+00:02:47,680 --> 00:02:53,360
+نص بيكون الشكل تتراهيدرال واضح الان لما نيجي نحكي
+
+31
+00:02:53,360 --> 00:02:58,790
+على ال double bond بتكون الزاوية120 يعني لو انا
+
+32
+00:02:58,790 --> 00:03:06,530
+بدأ اطلع بهذا الشكل 120 120 و120 المجموع قداشر 360
+
+33
+00:03:06,530 --> 00:03:12,670
+المجموع 360 الان لو بدأ اشوف طيب ايش الشكل حوالين
+
+34
+00:03:12,670 --> 00:03:16,450
+ال double bond الشكل حوالين ال double bond بنسميه
+
+35
+00:03:16,450 --> 00:03:22,910
+Triangular Planar يعني في مستوى واحد لاحظوا الذرات
+
+36
+00:03:23,440 --> 00:03:28,140
+هيدروجين كاربون هيدروجين كاربون هيدروجين كاربون لو
+
+37
+00:03:28,140 --> 00:03:32,960
+حطينا مستوى بهذا الشكل جميع الذرات في مستوى واحد
+
+38
+00:03:32,960 --> 00:03:37,000
+ولذلك الاثيليين جميع ذراته في مستوى واحد بنقول عنه
+
+39
+00:03:37,000 --> 00:03:42,180
+إيش ال planner الان الشكل ال triangular planner
+
+40
+00:03:42,180 --> 00:03:49,600
+يعني مقسوم إلىتلات أقسام الزاوية 120 120 120 واضحة
+
+41
+00:03:49,600 --> 00:03:55,540
+هذه النقطة الآن لو اجينا نحكي على ال bond length
+
+42
+00:03:55,540 --> 00:04:01,680
+مقارنة ال carbon carbon single bond مع ال carbon
+
+43
+00:04:01,680 --> 00:04:05,700
+carbon double bond أنها بتكون أقصرالـ carbon
+
+44
+00:04:05,700 --> 00:04:09,700
+carbon double bond كل ما ال bond order بيزيد ال
+
+45
+00:04:09,700 --> 00:04:14,200
+bond بتصير أقصر و ال triple bond بعد شوية هنلاحظ
+
+46
+00:04:14,200 --> 00:04:19,840
+أنها أقصر و موجودة الأطوال عندنا في ال بيكمتر الان
+
+47
+00:04:19,840 --> 00:04:23,140
+الرابطة لما بيزيد فيها ال bond order بيصير فيها
+
+48
+00:04:23,140 --> 00:04:32,070
+أمر كتير مهم هذا الأمر هوزيادة قوة الرابطة بما
+
+49
+00:04:32,070 --> 00:04:36,290
+يمنع الدوران يعني لاحظوا معي لما بيكون عند رابطة
+
+50
+00:04:36,290 --> 00:04:42,170
+أحدية فقط عند دوران ممكن حول الرابطة الأحدية لكن
+
+51
+00:04:42,170 --> 00:04:46,650
+مجرد ما بتصير هذه الرابطة رابطة ثنائية أو بالتأكيد
+
+52
+00:04:46,650 --> 00:04:53,550
+ثلاثية بيصير الدوران ممنوعبصير الدوران ممنوع هذا
+
+53
+00:04:53,550 --> 00:05:02,130
+الكلام له انعكاس مهم جدا في الكيميا انه انا لو
+
+54
+00:05:02,130 --> 00:05:08,230
+رجعت دقيقة للخلف و أخدت مركب فيه روابط أحدية يعني
+
+55
+00:05:08,230 --> 00:05:14,610
+لغيت هذه الرابطة نهائيا و اتخيلت انه عندي ال E2 مش
+
+56
+00:05:14,610 --> 00:05:20,890
+ال E2 هو مركب الروابط الأحديةالـ E2 هو مركّب
+
+57
+00:05:20,890 --> 00:05:24,250
+الهواط الأوحادية الان هنا في عندى اشي بسميه اش
+
+58
+00:05:24,250 --> 00:05:31,270
+free rotation اش بنسميه free rotation دوران حر
+
+59
+00:05:31,270 --> 00:05:34,510
+free rotation
+
+60
+00:05:36,130 --> 00:05:42,090
+طيب هذا الـ free rotation على إيش بيأثر عندى في
+
+61
+00:05:42,090 --> 00:05:48,090
+الأمور الكيميائية هيأثر على أمر مهم جدا جدا لو يا
+
+62
+00:05:48,090 --> 00:05:55,170
+ترى أنا إجيت بدلت من هنا هيدروجين بذرة كلور على
+
+63
+00:05:55,170 --> 00:06:00,890
+موقع واحد وبدلت من هنا هيدروجين تانية على ذرة كلور
+
+64
+00:06:00,890 --> 00:06:06,740
+بموقع واحد وامسكت الجزاءلاحظوا معي الدوران ممكن
+
+65
+00:06:06,740 --> 00:06:10,820
+ألاحظ أن ذرتين الكلور هدولة جايين بمستوى واحد يقبل
+
+66
+00:06:10,820 --> 00:06:17,780
+بعض ممكن يلفوا بدت واحدة تغلط و تقول sis انتبهوا
+
+67
+00:06:17,780 --> 00:06:22,140
+معي ممكن يلفوا صار بينهم زيو معين كمان كمان كمان
+
+68
+00:06:22,140 --> 00:06:25,320
+ممكن بلحظة من اللحظات أثناء الدوران يكونوا بهذا
+
+69
+00:06:25,320 --> 00:06:34,380
+الشكلإذا لو سألت كم هيئة تنتج عن الدوران متوقع
+
+70
+00:06:34,380 --> 00:06:42,620
+لهذا الشكل أكيد عدد لانهائي من الهيئات يعني
+
+71
+00:06:42,620 --> 00:06:47,420
+الزاوية ما بين هدولة دارتين سفر بدت ألف صارت واحد
+
+72
+00:06:47,420 --> 00:06:50,780
+من عشر او اتنين من عشر او تلات من عشر اربع زادت
+
+73
+00:06:50,780 --> 00:06:55,680
+زادت زادت زادت زادت صاروا عكس بعضطوله أنا بلوف
+
+74
+00:06:55,680 --> 00:07:01,180
+بطلع هيئات مش أشكال لاحظوا بدي أميز ما بين كلمتين
+
+75
+00:07:01,180 --> 00:07:05,700
+ما بين هيئة و ما بين شكل أصلي يعني البني آدم بني
+
+76
+00:07:05,700 --> 00:07:10,740
+آدم واحد لكن يمكن أن يوجد فيه هيئات مختلفة ولذلك
+
+77
+00:07:10,740 --> 00:07:14,800
+لما بييجي في الطالب الصبح و بيعمل تمرينات الصبح
+
+78
+00:07:14,800 --> 00:07:19,180
+رياضية هيئاتين تين تلاتة أربعة بييجي في محمد و بعد
+
+79
+00:07:19,180 --> 00:07:24,360
+التمرينات بننادي عليه و بنقول عنه برضه محمدبياخد
+
+80
+00:07:24,360 --> 00:07:29,620
+ايقات مختلفة المدرس قال هيك هيك هيك هيك هيك هيك
+
+81
+00:07:29,620 --> 00:07:31,420
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+82
+00:07:31,420 --> 00:07:31,960
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+83
+00:07:31,960 --> 00:07:32,040
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+84
+00:07:32,040 --> 00:07:37,760
+هيك هيك هيك هيك هيك هيك هيك
+
+85
+00:07:37,760 --> 00:07:38,540
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+86
+00:07:38,540 --> 00:07:38,680
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+87
+00:07:38,680 --> 00:07:38,900
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+88
+00:07:38,900 --> 00:07:39,760
+هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك هيك
+
+89
+00:07:39,760 --> 00:07:48,300
+هيك هيك هيك هيك هيك
+
+90
+00:07:48,300 --> 00:07:55,690
+هيك هيكهو واحد بهيئات دورانية مختلفة هيئة بنسميها
+
+91
+00:07:55,690 --> 00:07:58,650
+احنا باللغة الإنجليزية ايش Conformation
+
+92
+00:07:58,650 --> 00:08:02,490
+Conformation
+
+93
+00:08:02,490 --> 00:08:11,230
+هيئة الان مرت علينا هذه الكلمة في ال Cyclohexane
+
+94
+00:08:11,230 --> 00:08:17,190
+اذا ال Conformation او الهيئات تنتج عن شغلتينال
+
+95
+00:08:17,190 --> 00:08:22,230
+conformations بتنتج عن شغلتين الشغلة الأولى اللى
+
+96
+00:08:22,230 --> 00:08:26,370
+مرت علينا ال flipping يوم كان ال cyclohexane بيجلب
+
+97
+00:08:26,370 --> 00:08:29,770
+بيعمل flipping زى الشمسية اللى بتجلب للامام و
+
+98
+00:08:29,770 --> 00:08:33,930
+للخلف للامام و للخلف لكن بتبقى شمسية إذا ال
+
+99
+00:08:33,930 --> 00:08:39,290
+conformations يمكن أن تنشأ عن ال flipping و نمرة
+
+100
+00:08:39,290 --> 00:08:45,170
+اتنين يمكن أن تنشأ عن ال rotation الدورانفيكون
+
+101
+00:08:45,170 --> 00:08:53,610
+المُركّب مُركّب واحدبشكل واحد وبهيئات كثيرة مختلفة
+
+102
+00:08:53,610 --> 00:08:59,810
+ولذلك ال one two dichloroethane هو مركب واحد فقط
+
+103
+00:08:59,810 --> 00:09:05,030
+بهيئات مختلفة وهو في حالة دوران أبدي يعني ربنا
+
+104
+00:09:05,030 --> 00:09:10,050
+خالجه زي ما بتقول الآية الكريمة وكل في فلك يسبحون
+
+105
+00:09:10,050 --> 00:09:15,740
+بالنسبة لعلم الكيميا هذا دوران لا يتوقفالدوران حول
+
+106
+00:09:15,740 --> 00:09:19,820
+الرابطة الأوحادية تماما زى المروحة اللى بالسجف لما
+
+107
+00:09:19,820 --> 00:09:24,320
+بتلوف بنقولش عنها مروحة كتيرة بتكون بهذا الشكل بعد
+
+108
+00:09:24,320 --> 00:09:28,730
+شوية بتزيد زوايا كمانو هي في حالة دوران أبدي لكنها
+
+109
+00:09:28,730 --> 00:09:33,450
+تبقى مروحة الان هذا الـ dichloroethane في حالة
+
+110
+00:09:33,450 --> 00:09:39,550
+دوران أبدي بهيئات كثيرة ولكنه يبقى مركبا واحد فلو
+
+111
+00:09:39,550 --> 00:09:43,570
+واحدة بدت تشتري dichloroethane هتلاقي انه عندها
+
+112
+00:09:43,570 --> 00:09:51,130
+ايش مركب واحد السبب ال free rotation الان خلينا
+
+113
+00:09:51,130 --> 00:09:53,010
+نحول للالكين
+
+114
+00:09:55,450 --> 00:10:01,850
+في الالكين صار عندى double bond قوية باجى اجرب ان
+
+115
+00:10:01,850 --> 00:10:08,410
+اعمل الدوران مافيش دورانمافيش إمكانية للدوران
+
+116
+00:10:08,410 --> 00:10:14,510
+الرابطة قوية وبناء على ذلك لو بدأ أحول هذا الشكل
+
+117
+00:10:14,510 --> 00:10:19,870
+للشكل التاني إيش بدأ أعمل؟ كسر وتكوين رابط قبل
+
+118
+00:10:19,870 --> 00:10:23,030
+شوية لما كانت الرابط أحدية بدأ أحول هذا للتاني
+
+119
+00:10:23,030 --> 00:10:28,130
+rotation فهذه هيئات وليس تعبير عن مركب جديد لكن
+
+120
+00:10:28,130 --> 00:10:32,070
+الأن أنا أمام ظاهرة جديدة لو بدأ أحول هذا المركب
+
+121
+00:10:32,070 --> 00:10:38,290
+اللي قلنا عنه cess إلى ال Transبدي أكسر الرابطة
+
+122
+00:10:38,290 --> 00:10:44,790
+وأكسر الرابطة وأعمل المركب لجديد ولذلك هدول صاروا
+
+123
+00:10:44,790 --> 00:10:50,250
+مركبين مختلفين بخواص مختلفة يومها بتروح تشتري one
+
+124
+00:10:50,250 --> 00:10:54,890
+two dichloro ethane اللي في double bond بنهاية إيش
+
+125
+00:10:54,890 --> 00:11:00,790
+in بتشتروا مركب ولا اتنين؟ مركبين واحد اسمه ال
+
+126
+00:11:00,790 --> 00:11:07,980
+Transone two dichloro ethane و التاني اسمه sis one
+
+127
+00:11:07,980 --> 00:11:13,660
+two dichloro ethane واضح هذه الفكرة فكرة ال sis و
+
+128
+00:11:13,660 --> 00:11:17,680
+ال trans الآن
+
+129
+00:11:17,680 --> 00:11:23,560
+لو يا تورا اجينا نمشي خطوة للامام طيب عندنا ال
+
+130
+00:11:23,560 --> 00:11:29,650
+kings بدنا نتعلم كيف نسميهم و ال kindsمثل ما
+
+131
+00:11:29,650 --> 00:11:35,330
+اتعودنا نسمي في الـ Alkanes بدنا أطول سلسلة لكن
+
+132
+00:11:35,330 --> 00:11:42,530
+هنا نضع شرط أطول سلسلة تحتوي على الرابطة الثنائية
+
+133
+00:11:42,530 --> 00:11:47,150
+أو الثلاثية بمعنى ممكن تشوفوا السلسلة طولها سبع
+
+134
+00:11:47,150 --> 00:11:51,610
+كربونات متتالية لكن كلها روابط أحدية والجزء في
+
+135
+00:11:51,610 --> 00:11:54,310
+رابطة ثنائية
+
+136
+00:11:55,990 --> 00:12:02,230
+يجب أن تحتوي أطول سلسلة على رابطة ثنائية ممكن
+
+137
+00:12:02,230 --> 00:12:09,930
+أعطيكم مثال حتى التطبيق يكون واضح ممكن نعطي مثال
+
+138
+00:12:09,930 --> 00:12:14,750
+يعني لو أعطينا فقط نرسم ذرات ال carbon وحاطينا
+
+139
+00:12:14,750 --> 00:12:21,340
+carbon 2 ثلاثة carbon 2 ثلاثةبهذا الشكل الان لو
+
+140
+00:12:21,340 --> 00:12:28,060
+جينا وعطينا هنا كمان carbon نحسب أطول سلسلة ممكن
+
+141
+00:12:28,060 --> 00:12:32,940
+واحدة تيجي تقول واحد، تنين، تلاتة، أربعة، خمسة،
+
+142
+00:12:32,940 --> 00:12:39,040
+ستة، سبعة، تمانية وممكن كمان تقول هنا كمان رابطة
+
+143
+00:12:39,040 --> 00:12:42,880
+تسعة الان لاحظوا هذه السلسلة اللي اخترتها مافيش
+
+144
+00:12:42,880 --> 00:12:46,840
+فيها ال double bond مش هتمشي معاه بدي سلسلة يكون
+
+145
+00:12:46,840 --> 00:12:58,790
+فيها ال double bond1 2 3 4 5 6 7 او 1 2 3 4 5 6 7
+
+146
+00:12:58,790 --> 00:13:05,950
+ممكن خلهم يختاروا واحدة منهم حسب الاكثر تفرع عن
+
+147
+00:13:05,950 --> 00:13:09,810
+اللي حكينا عليه اذا كان موجود الان اذا ماباخدش
+
+148
+00:13:09,810 --> 00:13:13,620
+السلسلة التسعة اللي مافيش فيها double bondلما ابدأ
+
+149
+00:13:13,620 --> 00:13:18,320
+أسمي لازم السلسلة اللي أخدها يكون فيها double bond
+
+150
+00:13:18,320 --> 00:13:23,980
+وجدت بنهي المركب بنهايك E لو كانت هذه triple bond
+
+151
+00:13:23,980 --> 00:13:30,500
+بنهي المركب بنهايك I إذا التسمية ببساطة أن نختار
+
+152
+00:13:30,500 --> 00:13:36,740
+أطول سلسلة تحتوي علىDouble أو Triple Point إذا كان
+
+153
+00:13:36,740 --> 00:13:40,360
+Double Point بنهي المركب بالنهاية E وإذا Triple
+
+154
+00:13:40,360 --> 00:13:45,580
+Point بنهي المركب بالنهاية I خلّينا نشوف أمثلة من
+
+155
+00:13:45,580 --> 00:13:50,960
+ال slides هاي في عندنا مثال لما نيجي نبحث عن أطول
+
+156
+00:13:50,960 --> 00:13:58,880
+سلسلة واحد، اتنين، تلاتة، أربعة، خمسة هذه اللي
+
+157
+00:13:58,880 --> 00:14:01,240
+فيها Double Point في واحد، اتنين، تلاتة Double
+
+158
+00:14:01,240 --> 00:14:06,750
+Point خارجها، مابديهاالآن مجرد ما اختارنا أطول
+
+159
+00:14:06,750 --> 00:14:13,510
+سلسلة على طول بدنا نقول إنه في إمكانيتين للترقيم
+
+160
+00:14:13,510 --> 00:14:17,850
+يعني هذه أطول سلسلة ممكن أوضحها أنا باللون الأزرق،
+
+161
+00:14:17,850 --> 00:14:21,850
+هذه أطول سلسلة، الآن بدي أبدأ واحد هان خمسان ولا
+
+162
+00:14:21,850 --> 00:14:26,520
+واحد هان خمسان، هذا سؤال مهم جدابدأ أخلّي ال
+
+163
+00:14:26,520 --> 00:14:31,180
+double bond تاخد أقل ترقيم، بداية ال double bond،
+
+164
+00:14:31,180 --> 00:14:35,480
+لاحظوا هنا ال double bond بدايتها وين؟ اتنين، لو
+
+165
+00:14:35,480 --> 00:14:40,680
+برقم من هنا واحد، اتنين، تلاتة، وين ال double bond
+
+166
+00:14:40,680 --> 00:14:46,170
+أقرب للطرف؟من هام و لذلك برقم واحد اتنين تلاتة
+
+167
+00:14:46,170 --> 00:14:52,210
+اربعة خمسة طالما خمس ذرات carbon إذا المركب بنتين
+
+168
+00:14:52,210 --> 00:14:59,530
+بنتين يلتهي بين في double bond الآن الين هذه اللي
+
+169
+00:14:59,530 --> 00:15:05,160
+هي ال double bond وين بدايتها؟فالـ carbon 2 هي
+
+170
+00:15:05,160 --> 00:15:10,160
+جاية بين 2 و 3 أنا بذكر فقط نقطة البداية و لذلك
+
+171
+00:15:10,160 --> 00:15:16,840
+هذا بقول عنه two بنتين فال two اللي موجودة هنا هذه
+
+172
+00:15:16,840 --> 00:15:22,640
+تحدد بداية ال double bond يجب أن احدد بداية ال
+
+173
+00:15:22,640 --> 00:15:31,320
+double bond هذه
+
+174
+00:15:31,320 --> 00:15:37,290
+و هذه زي بعضو هيقدروا لنفس الاسم لو قلت سلسلة واحد
+
+175
+00:15:37,290 --> 00:15:43,210
+اتنين تلاتة اربعة خمسة و لو سميت الآن هذه two مثل
+
+176
+00:15:43,210 --> 00:15:48,330
+و four promo طب لو عديت من هنا two مثل و four
+
+177
+00:15:48,330 --> 00:15:52,110
+promo لو قلت واحد اتنين تلاتة اربعة خمسة two مثل و
+
+178
+00:15:52,110 --> 00:15:57,010
+four promo نفس الأشياء طالما عندك مجموعتين مثل على
+
+179
+00:15:57,010 --> 00:16:00,250
+نفس ال carbon ابدأ من أي واحدة مافيش عندك مشكلة
+
+180
+00:16:01,300 --> 00:16:04,480
+واحدة منهم تكون ضمن السلسلة والثانية تصبح
+
+181
+00:16:04,480 --> 00:16:08,440
+substitute طبعا أكيد هطبق القواعد اللي حكيتها في
+
+182
+00:16:08,440 --> 00:16:12,440
+البداية أنه لو مابدأ أذكر ال promo و ال مثل كيف
+
+183
+00:16:12,440 --> 00:16:16,500
+بدي أذكرهم alphabetically alphabetically بمعنى ال
+
+184
+00:16:16,500 --> 00:16:23,760
+B قبلالان ..الان هاي مركب ثاني موجود عندى لحظة هذا
+
+185
+00:16:23,760 --> 00:16:27,880
+المركب الثاني كان ممكن يوجع البعض في خطأ معين انه
+
+186
+00:16:27,880 --> 00:16:34,020
+يبحث عن أطول سلسلة روابط أحدية لازم ال double bond
+
+187
+00:16:34,020 --> 00:16:38,540
+بترفينها تكون ضمن السلسلة ولذلك هذه السلسلة بهذا
+
+188
+00:16:38,540 --> 00:16:42,400
+الشكل لا يجوز اعتبارهابنعتبر السلسلة اللي مبينة
+
+189
+00:16:42,400 --> 00:16:46,860
+بالأحمر واحد اتنين تلاتة أربعة خمسة ستة طالما ستة
+
+190
+00:16:46,860 --> 00:16:53,340
+إذا المركبة هيكسين الرابط فيه، وين بدايتها؟ إذا
+
+191
+00:16:53,340 --> 00:16:58,620
+هذا one هيكسين، واضح؟ هذا one هيكسين عن امر اتنين،
+
+192
+00:16:58,620 --> 00:17:04,810
+موجود تلت كربونات في هالشكل، احفظ ما اسمهم بروبين2
+
+193
+00:17:04,810 --> 00:17:14,630
+Probel و 1 Hexane لأن
+
+194
+00:17:14,630 --> 00:17:22,010
+انتهانها بترتكب خطأ كبير جدا جدا مافيش اشي اسمه
+
+195
+00:17:22,010 --> 00:17:27,630
+مجموعات افكر فيها قبل ما ابحث عن أطول سلسلة هذا من
+
+196
+00:17:27,630 --> 00:17:33,030
+الأخطاء الشائعةجدا عند الطلاب من الأخطاء الشائعة
+
+197
+00:17:33,030 --> 00:17:38,630
+جدا عند الطلاب السؤال اللي سألته زملتكوا سؤال جيد
+
+198
+00:17:38,630 --> 00:17:43,170
+بيجعوا فيه كتير من الطلاب انه بيحفظوا مجموعة معينة
+
+199
+00:17:43,170 --> 00:17:47,430
+و انبسطوا كتير على حالهم انه حفظوا شكل هالمجموعة
+
+200
+00:17:47,430 --> 00:17:51,670
+بيروحوا بغلطوا في القاعدة الأساسية في التسمية انه
+
+201
+00:17:51,670 --> 00:17:56,810
+يجب ان ابحثعن أطول سلسلة قبل أن أفكر بالمجموعات
+
+202
+00:17:56,810 --> 00:18:00,030
+بعد ما أبحث عنها حكيتلكم ممكن تعلموها بقلم
+
+203
+00:18:00,030 --> 00:18:05,510
+الفوسفور ما تفرع منها فهو مجموعات سأعطي مثال يعني
+
+204
+00:18:05,510 --> 00:18:10,710
+لو عندكم مثلا هاي كاربون تنتين تلاتةأربعة بهذا
+
+205
+00:18:10,710 --> 00:18:16,850
+الشكل فقط أضع ذرات الكاربون ال A لاحظوا طالب درست
+
+206
+00:18:16,850 --> 00:18:22,330
+جيدا ممكن أول ما تشوف هذا المركب تفكر تقول هذه
+
+207
+00:18:22,330 --> 00:18:28,390
+الكاربون اللي حملة تلاتة كاربون تيرتشاري
+
+208
+00:18:28,390 --> 00:18:34,950
+بيوتلتفكر بهذا المنطق وبناء على ذلك تبدأ ترتكب
+
+209
+00:18:34,950 --> 00:18:41,010
+الأخطاء الكتيرة جدا تقول هذا المركب 1,2,3,4 يحمل
+
+210
+00:18:41,010 --> 00:18:47,510
+على موقع تيرتشار بيوتيل و تيجي تسمي هذا المركب two
+
+211
+00:18:47,510 --> 00:18:55,220
+tertiary butyl butaneجابت كيميا كتير، درست كتير،
+
+212
+00:18:55,220 --> 00:18:59,900
+بس مامشيتش بالاتجاه الصحي، ليش؟ لأنه المفروض أطول
+
+213
+00:18:59,900 --> 00:19:04,080
+سلسلة، الآن لما ابدأ أقول أطول سلسلة، أجرب أعد
+
+214
+00:19:04,080 --> 00:19:09,500
+كتير، هعد من هنا في الآخر، واحد، اتنين، تلاتة،
+
+215
+00:19:09,500 --> 00:19:16,330
+اربعة، خمسةاللي كانت تعتبرها سلسلة مجموعة دخلت ضمن
+
+216
+00:19:16,330 --> 00:19:20,810
+السلسلة هاي أطول سلسلة، واحد، اتنين، تلاتة، أربعة،
+
+217
+00:19:20,810 --> 00:19:24,730
+خمسة، هاي أطول سلسلة، بنتين الآن، ماذا تبقى
+
+218
+00:19:24,730 --> 00:19:31,850
+للخارج؟ كل ما تبقى فهو مجموعات أه، اتبقى عندها مثل
+
+219
+00:19:31,850 --> 00:19:37,650
+و مثل، و هذه لو كملناها كمان مثل CH3
+
+220
+00:19:38,900 --> 00:19:45,360
+فالاسم الصحيح لهذا المركب شو هيكون؟ two two three
+
+221
+00:19:45,360 --> 00:19:54,360
+اتراي مثل بنتين واضح؟ فما تفكروا نهائيا بمجموعات
+
+222
+00:19:54,360 --> 00:19:59,400
+قبل ما تحددوا أطول سلسلة و اتعلموها ما زاد عن أطول
+
+223
+00:19:59,400 --> 00:20:06,800
+سلسلة شوفوا إيش اسمه فكيف تبدأ التسمية؟بأطول سلسلة
+
+224
+00:20:06,800 --> 00:20:10,320
+مش أشوف أن هذه مجموعة و هذه مجموعة و التنتين
+
+225
+00:20:10,320 --> 00:20:16,880
+موجودات كجزء من أطول سلسلة واضحة الفكرة؟
+
+226
+00:20:36,770 --> 00:20:43,390
+وعشان هيك لا بأس ان اعطيكم مسألة تانية تفكروا فيها
+
+227
+00:20:43,390 --> 00:20:58,450
+تعملوها homework على هذا الموضوع تحديدا مسألة
+
+228
+00:20:58,450 --> 00:21:04,080
+جميلة جداطبعا اللي حافظين المجموعات يا الله
+
+229
+00:21:04,080 --> 00:21:07,400
+isopropyl و isopropyl ضاي isopropyl واحد اتنين
+
+230
+00:21:07,400 --> 00:21:12,440
+تلاتة اربعة خمسة ستة ضاي isopropylهكسين و كل الاسم
+
+231
+00:21:12,440 --> 00:21:18,220
+غلط بديش الأن أسميه اتعبوا فيه ابحثوا عن أطول
+
+232
+00:21:18,220 --> 00:21:22,200
+سلسلة و ما زاد عنفا و مجموعات مش تيجي تقولوا أن
+
+233
+00:21:22,200 --> 00:21:24,060
+هذه isopropyl و هذه isopropyl
+
+234
+00:21:31,920 --> 00:21:39,760
+تخدوا من بعض لو سمحتوا خلينا نمشي الان انتبهوا معي
+
+235
+00:21:39,760 --> 00:21:46,500
+حكينا احنا عن ظاهرة ال
+
+236
+00:21:46,500 --> 00:21:51,960
+الكينز و ال sis و ال trans الان ازملتكوا ذكرتنا
+
+237
+00:21:51,960 --> 00:21:57,260
+بالمجموعاتبتذكرين لما أخدنا مثيل قولنا منه مجموعة
+
+238
+00:21:57,260 --> 00:22:04,560
+مثل اثل اثل بروبل بروبل و ايزو بروبل طيب يا تورا
+
+239
+00:22:04,560 --> 00:22:10,080
+الالكين لو خصمنا من الالكين هيدروجين في كمان
+
+240
+00:22:10,080 --> 00:22:14,850
+مجموعات؟يعني دول بنحفظنا الأولانيين لو خصمنا
+
+241
+00:22:14,850 --> 00:22:19,690
+الهيدروجين من الالكين في مجموعات الجواب في بعض
+
+242
+00:22:19,690 --> 00:22:24,550
+المجموعات اللي بنتعرف عليها أبسط الكين هو الاثيل
+
+243
+00:22:24,550 --> 00:22:30,190
+أو الاثيلين لو شيلنا منه الهيدروجين هذه بنعمل
+
+244
+00:22:30,190 --> 00:22:36,130
+مجموعة الالكين minus الهيدروجين بنعمل مجموعة
+
+245
+00:22:36,130 --> 00:22:43,540
+بنسميهاإزملتكوا برضه سمعتني كلمة مش مظبوطة جالت
+
+246
+00:22:43,540 --> 00:22:51,460
+فينل أنا بقول فينل في حرف ال V هذه فينل فلو حملت
+
+247
+00:22:51,460 --> 00:22:57,770
+ال chlorine بتصير vinyl chloride ليش رفضنا؟إنها
+
+248
+00:22:57,770 --> 00:23:02,430
+تقول كلمة Fennel لأن ال Fennel مجموعة تانية
+
+249
+00:23:02,430 --> 00:23:08,250
+البنزين لما بتلوجد على يعني لو أخدت هذا المركب
+
+250
+00:23:08,250 --> 00:23:14,550
+بيوتين صح؟ أو هذا المركب بنتين حطوا عليها هنا
+
+251
+00:23:14,550 --> 00:23:22,310
+بنزينة بنزينة مخصوم منها Hydrogen هذه كمجموعة
+
+252
+00:23:22,310 --> 00:23:24,790
+اسمها Fennel
+
+253
+00:23:27,710 --> 00:23:33,290
+الان الفنل مجموعة البنزين الـ C6H6 الخاصة منه
+
+254
+00:23:33,290 --> 00:23:40,590
+هيدروجين صار C6H6H5 وبيشبك من هذا الموقع هذه
+
+255
+00:23:40,590 --> 00:23:47,830
+مجموعة الفينل الان لما اجي اخد الاثيليين اخص منه
+
+256
+00:23:47,830 --> 00:23:55,690
+هيدروجين بيصير C2H3 مجموعة الفينل ولذلك لما بتلفظه
+
+257
+00:23:55,690 --> 00:24:02,390
+ميزه كلمة فينل عن كلمة فينل هذه مجموعة و هذه
+
+258
+00:24:02,390 --> 00:24:08,550
+مجموعة فينل فينلهذه المجموعة الأولى مشتقة من إيش؟
+
+259
+00:24:08,550 --> 00:24:13,550
+من الإيثيلين من خلال أن أحذف منه هيدروجينة طبعا
+
+260
+00:24:13,550 --> 00:24:18,750
+موضوع الإيثيلين موضوع سهل جدا ليش؟ لأنه في
+
+261
+00:24:18,750 --> 00:24:23,790
+الإيثيلين الأربع ذرات هيدروجين زي بعض يعني من وين
+
+262
+00:24:23,790 --> 00:24:27,410
+ما بخسم هذه أو هذه أو هذه أو هذه شيلت هيدروجينة
+
+263
+00:24:27,410 --> 00:24:33,260
+صارت مجموعة ما اسمها؟Vinyl هذه مجموعة Vinyl الان
+
+264
+00:24:33,260 --> 00:24:37,480
+لو اتيت و حطيت Clor هنا ايش في المركب؟ Vinyl
+
+265
+00:24:37,480 --> 00:24:44,120
+Cloride واضح؟ لكن لو يا تورا اتيت على المركب اللي
+
+266
+00:24:44,120 --> 00:24:48,420
+مباشرة بيجي عند بعض ال إيثيلين اللي هو البروبين
+
+267
+00:24:48,420 --> 00:24:55,580
+حطيت كمان Carbon خليني
+
+268
+00:24:55,580 --> 00:24:57,180
+اعمل ال model عشان نفهم
+
+269
+00:25:12,820 --> 00:25:25,430
+الان لاحظوا هذا جزء لبروبين CH2 CH CH3واضح؟
+
+270
+00:25:25,430 --> 00:25:31,270
+إبروبين و لو بتشوفوا الصيغة تبعته C3H6
+
+271
+00:25:31,270 --> 00:25:38,590
+يعني CNH2N واضحة صيغته؟ الآن في أنواع كتيرة من
+
+272
+00:25:38,590 --> 00:25:43,010
+الهيدروجين يعني هدول نوع، هذي نوع، هذي نوع، يمكن
+
+273
+00:25:43,010 --> 00:25:46,130
+هذي نوع، أنواع كتيرة من الهيدروجين طب أنا بقول لو
+
+274
+00:25:46,130 --> 00:25:49,850
+حذفت منه هيدروجين بيطلع مجموعةيا ترى أحذف هذه اللي
+
+275
+00:25:49,850 --> 00:25:52,930
+عند ال double bond ولا أحذف اللي بالوسط ولا أحذف
+
+276
+00:25:52,930 --> 00:25:58,490
+اللي هنا الحقيقة المجموعة الهيدروجين اللي بيحذفوها
+
+277
+00:25:58,490 --> 00:26:04,190
+من ال CH3 هنا واضح؟
+
+278
+00:26:04,190 --> 00:26:08,050
+يمكن أن تحذف الأشياء التانية لكن ليس لها اسم الآن
+
+279
+00:26:08,050 --> 00:26:12,550
+بهذا الشكل صار عند CH2
+
+280
+00:26:13,730 --> 00:26:20,930
+CH وهنا CH2 جاهزة أن تتفاعل مع شيء تاني جاهزة
+
+281
+00:26:20,930 --> 00:26:26,250
+تتفاعل مع شيء تاني هذه المجموعة بنسميها ألل إيش
+
+282
+00:26:26,250 --> 00:26:30,550
+بنسميها؟ ألل فلو حطيتي كلور محل الهيدروجينة هنا
+
+283
+00:26:30,550 --> 00:26:37,110
+تحديدا محل منحفة ال H على CH صار اسم المركب ألل
+
+284
+00:26:37,110 --> 00:26:42,980
+كلورايدواضح؟ فهذا المركب شو بيصير اسمه؟ ألل
+
+285
+00:26:42,980 --> 00:26:46,520
+أكلورايت، بتكون تتضربوا على هالكلام طيب، لو الآن
+
+286
+00:26:46,520 --> 00:26:52,300
+جبتلكوا سؤال في الامتحان وقلتلكم ارسمولي الألل
+
+287
+00:26:52,300 --> 00:26:57,660
+الكهول زي
+
+288
+00:26:57,660 --> 00:27:01,720
+الألل أكلورايت بدل الـCl وH
+
+289
+00:27:11,220 --> 00:27:18,020
+الخلاصة اللي هي مجموعةالألل مجموعة الألل هذه
+
+290
+00:27:18,020 --> 00:27:22,920
+الصحيح مجموعة الألل من الناحية التاريخية من
+
+291
+00:27:22,920 --> 00:27:29,960
+الناحية التاريخية في سبب ليش سموها ألل في سبب ليش
+
+292
+00:27:29,960 --> 00:27:36,160
+سموها ألل هذه مرتبطة بنبات التومتعرفوا الـ Toma؟
+
+293
+00:27:36,160 --> 00:27:41,000
+اه ال Toma الان ال Toma المركب الأساسي اللي فيها
+
+294
+00:27:41,000 --> 00:27:46,540
+اللي هو CH2 double bond CH CH2 الان هذه مجموعة ألل
+
+295
+00:27:46,540 --> 00:27:52,360
+ولا لأ؟ ألل بدأ تشبك من هنا وكمان لو أخدنا CH2
+
+296
+00:27:52,360 --> 00:27:58,910
+double bond CHCH2 هذه مجموعة ألل ولا لأ هدولة لما
+
+297
+00:27:58,910 --> 00:28:05,670
+بيكون بينهم ذرتين كبريت sulfur كمان رابطة sulfur
+
+298
+00:28:05,670 --> 00:28:10,070
+بيصير المركب الأساسي اللي موجود في التومة و اللي
+
+299
+00:28:10,070 --> 00:28:15,070
+بيعطيها طاعمها الآن لو قلنا طيب هذا المركب الأساسي
+
+300
+00:28:15,070 --> 00:28:23,060
+إيش بدنا نسميه هى ألل أو ألل ضاي أللو Sulphur و
+
+301
+00:28:23,060 --> 00:28:28,480
+Sulphur داي Sulphide فالمكوّن الأساسي اللي في
+
+302
+00:28:28,480 --> 00:28:36,540
+التومة داي قلل يعني تنتين قلل داي Sulphide
+
+303
+00:28:37,690 --> 00:28:42,430
+dialyl disulfide الآن هذا المركب طلو من التومة
+
+304
+00:28:42,430 --> 00:28:47,170
+لقوا في هذه المجموعة رجعوا لاسم التومة في علم
+
+305
+00:28:47,170 --> 00:28:51,450
+النبات من أي عيلة التومة في علم النبات العيلة
+
+306
+00:28:51,450 --> 00:28:59,330
+النباتية تاعة التومة اليوم اليوم فنسبة لعيلة
+
+307
+00:28:59,330 --> 00:29:07,470
+التومة قالوا سمي هذه المجموعة الواضح؟ فالأصل جاي
+
+308
+00:29:07,470 --> 00:29:14,330
+من اسم العيلة النباتية تبعت نبات التوم اليوم فإيجى
+
+309
+00:29:14,330 --> 00:29:18,150
+اليل والمكون الأساسي اللي في التومة di-alyl
+
+310
+00:29:18,150 --> 00:29:25,140
+disulfide لاحظوا معنى التومة فيها كبريتالكابريت
+
+311
+00:29:25,140 --> 00:29:30,040
+لما بيعمل تفاعلات مش بيطلع غازات سيئة S O2 H2S
+
+312
+00:29:30,040 --> 00:29:34,080
+ولذلك منهي حتى أن الإنسان ياكل تومة ويروح يصلف
+
+313
+00:29:34,080 --> 00:29:39,300
+الجماعة من وين السبب؟ سبب الرائحة السيئة اللي
+
+314
+00:29:39,300 --> 00:29:46,430
+بتطلع منه التومة الكابريت مركبات الكابريتمراكبات
+
+315
+00:29:46,430 --> 00:29:50,210
+الكابريت مراكبات رائحتها سيئة فالانسان لما بياكل
+
+316
+00:29:50,210 --> 00:29:55,610
+التومة بيصير يطلع رائحة هذه المراكبات، واضح؟
+
+317
+00:29:55,610 --> 00:30:01,010
+فالتوم مراكب موجود فيه الكابريت وهو سبب المشكلة
+
+318
+00:30:01,010 --> 00:30:05,810
+والرائحة السيئة، إذاً هيك بنكون أخدنا مجموعتين،
+
+319
+00:30:05,810 --> 00:30:10,260
+مجموعةالفينيل والأليل بس هدول المجمعتين بدنا
+
+320
+00:30:10,260 --> 00:30:14,100
+ناخدهم لل ألكينز بدنا ناخد لل ألكينز بس هدول
+
+321
+00:30:14,100 --> 00:30:20,100
+المجمعتين الانياطورة لو إجينا قولنا في عندنا تلت
+
+322
+00:30:20,100 --> 00:30:28,020
+ذرات كربون إبروبين بيمشي الحال و بدنا نعمل المركب
+
+323
+00:30:28,020 --> 00:30:31,020
+اللي بعده المركب اللي بعده إيش بدنا نزيد عليه
+
+324
+00:30:31,020 --> 00:30:37,330
+كربون إضافيةفكروا معنى أين ممكن نحط الكربون
+
+325
+00:30:37,330 --> 00:30:44,530
+الإضافية بمعنى كم مركّب الـKey هيكون عنده من أربع
+
+326
+00:30:44,530 --> 00:30:50,890
+ذرّات كربون أنا هنا ماسك التلاتة ممكن واحدة تقول
+
+327
+00:30:50,890 --> 00:30:56,350
+بسيطة حطوا هنا الكربون هنا
+
+328
+00:30:59,320 --> 00:31:03,720
+هي صار عندى اربع ذرات كربون شايفينها؟ وهنا نكملهم
+
+329
+00:31:03,720 --> 00:31:07,800
+الهيدروجينات ولا واضحين؟ واضحين هذا المركب لو بدى
+
+330
+00:31:07,800 --> 00:31:15,460
+اسميه شو هسميه؟ one two three four اذا نبيوتين
+
+331
+00:31:15,460 --> 00:31:20,540
+وبداية ال double bond ع واحد وانا بيوتين اعرفته
+
+332
+00:31:22,860 --> 00:31:28,820
+وانا بيوتين الآن هاجي أسأل يا تورا هذا المُركّب في
+
+333
+00:31:28,820 --> 00:31:33,640
+ظاهرة الـcis والترانس احنا المرة الماضية حكينا شرط
+
+334
+00:31:33,640 --> 00:31:38,220
+ظاهرة الcis والترانس مختلفتان مختلفتان هاي ال
+
+335
+00:31:38,220 --> 00:31:41,220
+double bond هاي الكربونتين تعونها هيدروجين
+
+336
+00:31:41,220 --> 00:31:45,200
+وهيدروجين متشابهتان
+
+337
+00:31:45,200 --> 00:31:50,740
+إذا كل قصة الcis والترانس غير موجودة فيه على طول
+
+338
+00:31:50,740 --> 00:31:56,740
+انتهىمافيش فيه ألوان بيوتين هو مركب واحد فقط مافيش
+
+339
+00:31:56,740 --> 00:32:02,340
+منه cis وtrans الآن ممكن نفكر أن نحط مجموعة
+
+340
+00:32:02,340 --> 00:32:08,180
+الميثالهانة لاحظوا هذه الكربون بتحمل مجمعتين
+
+341
+00:32:08,180 --> 00:32:15,760
+مختفتين هيدروجين و CH3 لما أجي بدي أبدل واحدة من
+
+342
+00:32:15,760 --> 00:32:20,990
+هدول الهيدروجينبيصير سس و تران لاحظوا واحدة هتقول
+
+343
+00:32:20,990 --> 00:32:26,910
+بدل الهيدروجين اللي فوق سير سس اه صاروا هدولة
+
+344
+00:32:26,910 --> 00:32:33,010
+مجمعتين المثل على جهة واحدة واحدة شو بدو يصير
+
+345
+00:32:33,010 --> 00:32:42,110
+المركب اللي عندك؟ سس و لو حطينا بالاتجاه المعاكس
+
+346
+00:32:42,110 --> 00:32:52,120
+اه انتبه معاههذا one two three four two بيوتين لكن
+
+347
+00:32:52,120 --> 00:32:56,600
+المثل والمثل على جهة واحدة فهو sis الظاهرة بينت
+
+348
+00:32:56,600 --> 00:33:01,120
+لأنه مختلفتان مختلفتان الان لو بدى احاول ال sis لل
+
+349
+00:33:01,120 --> 00:33:06,620
+trans one
+
+350
+00:33:06,620 --> 00:33:12,100
+two
+
+351
+00:33:12,100 --> 00:33:18,570
+three fourtrans إذا ال two بيوتين كم مركّب منه؟
+
+352
+00:33:18,570 --> 00:33:19,730
+اتنين
+
+353
+00:33:24,560 --> 00:33:29,100
+الـ two butane كام مُركّب منه؟ الـ cis والترانس
+
+354
+00:33:29,100 --> 00:33:36,660
+الان لسه ما خلصناش نشوف كل المُركّبات الان لاحظوا
+
+355
+00:33:36,660 --> 00:33:40,940
+معناه ايش اللي عملنا احنا تحديدا لما شوفنا أنواع
+
+356
+00:33:40,940 --> 00:33:43,680
+المُركّبات قولنا بنشيل الهيدروجين من هنا وكملنا
+
+357
+00:33:43,680 --> 00:33:49,280
+طلع وانا butane اجينا نشيل هذهأعملنا sis to butyl
+
+358
+00:33:49,280 --> 00:33:53,740
+شيلنا هذه و حطينا مثل أعملنا trans to butyl طب يا
+
+359
+00:33:53,740 --> 00:33:59,200
+تورا لو شيلنا هذه و حطينا مثل هنطلع
+
+360
+00:33:59,200 --> 00:34:06,680
+في المركب المتفرع اتطلع
+
+361
+00:34:06,680 --> 00:34:08,960
+على شكله بدأ يغلبني
+
+362
+00:34:13,200 --> 00:34:16,440
+الثلاثة اللي اتفرع منهم واحد واحد اتنين تلاتة
+
+363
+00:34:16,440 --> 00:34:19,880
+اتفرع لما كان في ال ال كيرز ال double bond سمينا
+
+364
+00:34:19,880 --> 00:34:26,380
+ايزو بيوتين هنا ايش هنسميه ايزو بيوتين ايزو بيوتين
+
+365
+00:34:26,380 --> 00:34:32,000
+طب لو قلت لو واحد اسميه بال ايو باكنيم هايوا قدام
+
+366
+00:34:32,000 --> 00:34:42,200
+عينيكم اطول سلسلة فيهOne Ibropine وعن إمرأتين يحمل
+
+367
+00:34:42,200 --> 00:34:49,720
+مثل إذا ال isobutene اسمه two مثل و one ibropine
+
+368
+00:34:49,720 --> 00:35:00,480
+بناء على ذلك هذه الصيغة العامة C4H8 كم ألكين منها؟
+
+369
+00:35:00,480 --> 00:35:04,480
+C4H8
+
+370
+00:35:04,480 --> 00:35:05,960
+كم ألكين؟
+
+371
+00:35:08,360 --> 00:35:13,840
+عدوهم أربعة أربعة شفتهم يعني لو بدى يكون عندكوا
+
+372
+00:35:13,840 --> 00:35:18,060
+سؤال draw all the possible alkenes that have the
+
+373
+00:35:18,060 --> 00:35:22,820
+formula C4H8 one butane, cistobutane, trans
+
+374
+00:35:22,820 --> 00:35:28,520
+-tobutane, isobutane إذا كام ألكين؟ أربعة الآن
+
+375
+00:35:28,520 --> 00:35:36,460
+انتبهوا معي سؤال دقيق جدالو أنا سألتكم draw all
+
+376
+00:35:36,460 --> 00:35:42,220
+the possible compounds المركبات أنا قولت ال keys
+
+377
+00:35:42,220 --> 00:35:46,600
+انتبهوا جيدا draw all the possible compounds كل
+
+378
+00:35:46,600 --> 00:35:53,320
+المركبات that have the formula C4H8 كيف بدكوا
+
+379
+00:35:53,320 --> 00:35:56,860
+تبدأوا تفكروا تفضلي
+
+380
+00:35:58,830 --> 00:36:04,530
+أه احنا قلنا الصيغة المشبعة C4H10 خصمنا منها اتنين
+
+381
+00:36:04,530 --> 00:36:10,010
+يالا تكوين ال double bond يالا تكوين حلقة المركبات
+
+382
+00:36:10,010 --> 00:36:15,930
+الحلقية أيضا صيغتها العامة CNH2N
+
+383
+00:36:17,500 --> 00:36:22,720
+المُركّبات الحلقية صيغتها العامة أيضًا CNN H2N
+
+384
+00:36:22,720 --> 00:36:25,940
+بناءً على ذلك بدي أشوف كم حلقة بقدر أعمل من أربع
+
+385
+00:36:25,940 --> 00:36:29,680
+كربونات عطولي أعطوني الجواب كم حلقة بيعمل إنسان من
+
+386
+00:36:29,680 --> 00:36:40,800
+أربع كربونات؟ غلط، غلط، برضه غلط أربع
+
+387
+00:36:40,800 --> 00:36:45,840
+كربونات كم حلقة بعمل منهم؟ حرام عليكي تمانية
+
+388
+00:36:53,600 --> 00:37:02,220
+يا باخد الاربعة زي هيك CH2 CH2 CH2 CH2 يا باخد
+
+389
+00:37:02,220 --> 00:37:06,300
+تلاتة و بطلع منهم مجموعة CH3
+
+390
+00:37:11,400 --> 00:37:16,360
+هدولة كمان C4H8 لو بتكملوا ال hydrogens واحد اتنين
+
+391
+00:37:16,360 --> 00:37:20,700
+واحد اتنين واحد اتنين واحد اتنين هاي ال C4H8 تلاتة
+
+392
+00:37:20,700 --> 00:37:25,600
+و اتنين و اتنين و انا واحد تمانية مقم ال hydrogens
+
+393
+00:37:25,600 --> 00:37:31,460
+بيكملوا حالهم صح اذا لو كان سؤالي بدي كل المركبات
+
+394
+00:37:31,460 --> 00:37:39,420
+اللي صيغتها C4H8 حقيقة هيكونوا ستة أربعة الكينزو
+
+395
+00:37:39,420 --> 00:37:43,380
+اتنين Cycle of Alkanes لو قلت بدّي الحلقات اتنين
+
+396
+00:37:43,380 --> 00:37:51,140
+بدّي ال Alkanes اربعة واضحة الصورة و دائما الصيغة
+
+397
+00:37:51,140 --> 00:37:58,740
+المتساوية اللي هي CNN H2N فكروا فيها بالاتجاهين ان
+
+398
+00:37:58,740 --> 00:38:03,020
+هذه الصيغة هي صيغة Alkanes و في ذات الوقت هي صيغة
+
+399
+00:38:03,020 --> 00:38:07,300
+Cycle of Alkanes واضحة الفكرة
+
+400
+00:38:18,050 --> 00:38:22,150
+ناخد أمثلة إضافية على موضوع التسمية لو عندي double
+
+401
+00:38:22,150 --> 00:38:28,290
+bond نهاية المركب إيش؟ in طب لو كنتين double
+
+402
+00:38:28,290 --> 00:38:36,180
+bonds؟ضايقين، لو تلاتة double bonds، اترايقين، لو
+
+403
+00:38:36,180 --> 00:38:44,680
+أربعة double bonds، تتراقين، و هكذا، واضح؟ ضايقين،
+
+404
+00:38:44,680 --> 00:38:46,420
+اتراقين، تتراقين، و هكذا، واضح؟ ضايقين، اتراقين،
+
+405
+00:38:46,420 --> 00:38:46,720
+تتراقين، و هكذا، واضح؟ ضايقين، اتراقين، تتراقين، و
+
+406
+00:38:46,720 --> 00:38:47,240
+هكذا، واضح؟ ضايقين، اتراقين، تتراقين، و هكذا،
+
+407
+00:38:47,240 --> 00:38:47,240
+واضح؟ ضايقين، اتراقين، تتراقين، و هكذا، واضح؟
+
+408
+00:38:47,240 --> 00:38:47,960
+ضايقين، اتراقين، تتراقين، و هكذا، واضح؟ ضايقين،
+
+409
+00:38:47,960 --> 00:38:52,380
+اتراقين، تتراقين، و هكذا، واضح؟تنتين اذا بده يبين
+
+410
+00:38:52,380 --> 00:38:57,180
+في ضايين هو كله اربع كربونات بيصير اسمه بيوتا
+
+411
+00:38:57,180 --> 00:39:01,800
+ضايين يعني بيوتين في تنتين اين في تنتين double
+
+412
+00:39:01,800 --> 00:39:08,620
+bonds لازم احدد وين مواقعهم نقطة البداية واحد و
+
+413
+00:39:08,620 --> 00:39:13,040
+تلاتة و عن اثري بيوتا ضايين و عن امر اتنين شو
+
+414
+00:39:13,040 --> 00:39:20,600
+بيحمل مثل لاحظوا كان واحدة ممكن تغلطاتسمى من هنا
+
+415
+00:39:20,600 --> 00:39:26,020
+اترقم من هنا واحد اتنين تلاتة هاي one three و هاي
+
+416
+00:39:26,020 --> 00:39:29,920
+one three لاحظوا هذا ال one three يخلى المثل تاخد
+
+417
+00:39:29,920 --> 00:39:35,380
+نمرة اتنين هذا ال one three بيخلى المثل تاخد تلاتة
+
+418
+00:39:35,380 --> 00:39:38,740
+انا عندي قاعدة عامة في الكيميا العضوية lower
+
+419
+00:39:38,740 --> 00:39:40,360
+numbering
+
+420
+00:39:42,150 --> 00:39:45,370
+واضح؟ يعني لما صار من هنا one and three و واحدة
+
+421
+00:39:45,370 --> 00:39:49,730
+تانية اتسمى من هنا بالازرق برضه one and three اخد
+
+422
+00:39:49,730 --> 00:39:52,650
+هذه ال one and three ولا هذه ال one and three ال
+
+423
+00:39:52,650 --> 00:39:55,870
+one and three اللي بالأصمر بتخل المثل على اتنين ال
+
+424
+00:39:55,870 --> 00:39:58,490
+one and three اللي بالازرق بتخل المثل على تلاتة
+
+425
+00:39:58,490 --> 00:40:03,030
+بتدله one number و لذلك هذا two مثل one and three
+
+426
+00:40:03,030 --> 00:40:09,310
+بيتضايين مش three مثل one and three بيتضايين الآن
+
+427
+00:40:09,310 --> 00:40:15,530
+هيعندي حلقةبدل Cyclopentane إذا فيها double bond؟
+
+428
+00:40:15,530 --> 00:40:21,230
+Cyclopentene شفتوا أين التغير؟ إيه؟ Cyclopentene
+
+429
+00:40:21,230 --> 00:40:26,290
+بدل Cyclopentene الآن لازم في الترقيم أمر بالبداية
+
+430
+00:40:26,290 --> 00:40:30,310
+على ال double bonds أسرع ما يمكن لاحظوا واحدة ممكن
+
+431
+00:40:30,310 --> 00:40:33,550
+تفكر تقول واحد، تنين هين مريت على ال double bond
+
+432
+00:40:33,550 --> 00:40:38,130
+من طرفنا واحد، اتنين إجت ال مثل الآن على أكم؟تلاتة
+
+433
+00:40:38,130 --> 00:40:42,870
+لو واحدة رقمت من هنا واحد اتنين هتقول تلاتة اربعة
+
+434
+00:40:42,870 --> 00:40:48,770
+هتخل ال مثل على خمسة ان هو الأصحى اذا من هنا برقم
+
+435
+00:40:48,770 --> 00:40:51,790
+واحد اتنين تلاتة اربعة خمسة ال three مثل
+
+436
+00:40:51,790 --> 00:40:57,930
+Cyclopentane المركب اللي بعدهCyclohexane ولا
+
+437
+00:40:57,930 --> 00:41:04,610
+Cyclohexadiene؟ Cyclohexadiene
+
+438
+00:41:04,610 --> 00:41:08,850
+بدي أقل ترقيب في البداية للـ Double bonds لحظة،
+
+439
+00:41:08,850 --> 00:41:13,970
+واحد، اتنين، تلاتة، أربعة يعني لو خلت هذه واحد
+
+440
+00:41:13,970 --> 00:41:20,050
+بدايتها، هذه بدايتها تلاتة الآن لو خلت هذه واحد،
+
+441
+00:41:20,050 --> 00:41:24,430
+هذه بدايتها أيضا تلاتة لكن هذه التلاتة بتخلي
+
+442
+00:41:24,430 --> 00:41:31,450
+البرومعلى خمسة one two three four five لو واحدة
+
+443
+00:41:31,450 --> 00:41:36,630
+غلطت هي أنا one three أيضا واحد نعمله بالأسود
+
+444
+00:41:36,630 --> 00:41:44,450
+اتنين تلاتة هذا one three و هذا one three لكن هذا
+
+445
+00:41:44,450 --> 00:41:48,830
+ال one three four five six خلال الرمعة ستة هنول
+
+446
+00:41:48,830 --> 00:41:55,290
+أصح ال lowerعشان يك الأسماء هنا موجودة بشكل صحيح
+
+447
+00:41:55,290 --> 00:42:01,670
+five brom one three cyclohexadiene لو تلاتة double
+
+448
+00:42:01,670 --> 00:42:09,130
+bonds تريين تلاتة تريين و بتحطوا الأرقام و
+
+449
+00:42:09,130 --> 00:42:15,730
+بتنتبهولها لو أربعة double bondsتتراين و هكذا
+
+450
+00:42:15,730 --> 00:42:23,190
+واضح؟ لكن هنا يجب أن ننوح لأمر لحظة ال Cyclohexane
+
+451
+00:42:23,190 --> 00:42:34,370
+هذا ايش اسمه؟ Cyclohexane هذا تنتين
+
+452
+00:42:42,130 --> 00:42:47,850
+Cyclohexadiene هيو موجود عندكم الآن ضمن نفس
+
+453
+00:42:47,850 --> 00:42:53,430
+المنطقة لو واحدة بدها تسمي هذا ممكن
+
+454
+00:42:53,430 --> 00:42:57,310
+تفكر تسميه Cyclohexatriene الآن عبر التاريخ هذا
+
+455
+00:42:57,310 --> 00:43:03,290
+أخد اسم بنزين فلا يقبل له اسم Cyclohexatrieneلحظوا
+
+456
+00:43:03,290 --> 00:43:07,250
+لو واحدة بدت تعمل اشتقاق كان ممكن تقول واحد اتنين
+
+457
+00:43:07,250 --> 00:43:11,410
+تلاتة اربعة خمسة ستة هاي بداية ال double bond هاي
+
+458
+00:43:11,410 --> 00:43:15,250
+بداية اللي بعدها هاي بداية اللي بعدها و تروح تسميه
+
+459
+00:43:15,250 --> 00:43:23,950
+one three five cyclohexatriene
+
+460
+00:43:23,950 --> 00:43:30,630
+هذا الاسم غير مقبولهذا المركب أخد اسم شهرة عبر
+
+461
+00:43:30,630 --> 00:43:36,390
+التاريخ من ايام ما فصلوا العالم فرده في ال .. يمكن
+
+462
+00:43:36,390 --> 00:43:41,750
+الف وتمنمية ولا اشي زي هيك، خمسة و عشرين زمان، قبل
+
+463
+00:43:41,750 --> 00:43:47,770
+متين سنة، أخد اسم بنزين فما بنسميه إطلاقا
+
+464
+00:43:47,770 --> 00:43:50,970
+Cyclohexatriene
+
+465
+00:43:50,970 --> 00:43:54,250
+ف Cyclohexatriene is not a correct name، شو ال
+
+466
+00:43:54,250 --> 00:43:58,560
+correct name؟ بنزينوبهيك بننهي اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk.srt
new file mode 100644
index 0000000000000000000000000000000000000000..0fbcb00a4f2ebc3d8e0379c120f3b215cc5a1a8a
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk.srt
@@ -0,0 +1,1495 @@
+
+1
+00:00:20,180 --> 00:00:26,240
+بسم الله الرحمن الرحيم الفصل التاسع موضوعه ال
+
+2
+00:00:26,240 --> 00:00:31,480
+aldehydes and ketones طبعا ال aldehydes and
+
+3
+00:00:31,480 --> 00:00:36,420
+ketones ربما انتوا اتلاحظوا انه عائلتين مش عائلة
+
+4
+00:00:36,420 --> 00:00:41,000
+واحدة لو اطلعنا هنلاقي ان ال aldehydes و ال
+
+5
+00:00:41,000 --> 00:00:47,000
+ketones هم جزء من عائلة اكبر جزء من عائلة اكبر
+
+6
+00:00:47,000 --> 00:00:53,230
+اسمهاالكربونيل containing compounds يعني المركبات
+
+7
+00:00:53,230 --> 00:00:56,870
+اللى بتحتوي على مجموعة الكربونيل الان ايش مجموعة
+
+8
+00:00:56,870 --> 00:01:02,490
+الكربونيل مجموعة الكربونيل هي ال C double bond O
+
+9
+00:01:02,490 --> 00:01:08,130
+واضح ال C double bond O هي المجموعة اللى اسمها ايش
+
+10
+00:01:08,130 --> 00:01:15,110
+كربونيلالان كتير في مراكبات .. كتير في مراكبات
+
+11
+00:01:15,110 --> 00:01:19,530
+فيهم هذه المجموعة الـ C double bond O يعني من هدول
+
+12
+00:01:19,530 --> 00:01:23,910
+المراكبات الـ aldehydes لما يكون عند الـ C double
+
+13
+00:01:23,910 --> 00:01:28,970
+bond O مجموعة R وH على الجهة التانية منهم الـ
+
+14
+00:01:28,970 --> 00:01:32,110
+ketones لما تكون الـ C double bond O محشورة بين
+
+15
+00:01:32,110 --> 00:01:36,990
+مجمعتين Rمنهم الـ Carboxylic Acids الـ C double
+
+16
+00:01:36,990 --> 00:01:41,750
+bond O متصلة بـ OH الان المراكبات اللي ضايلة
+
+17
+00:01:41,750 --> 00:01:46,030
+بنسميها مشتقات من الـ Carboxylic Acids منها الـ E
+
+18
+00:01:46,030 --> 00:01:49,970
+star C double bond O OR منها الامد C double bond O
+
+19
+00:01:49,970 --> 00:01:57,970
+NH2 منها ال Acid C double bond OCL وفي كمان مركب
+
+20
+00:01:57,970 --> 00:02:03,030
+أيضا موجود ومشهور ولو مش مكتوب هنا R C double bond
+
+21
+00:02:03,030 --> 00:02:09,150
+O O C double bond O R تانية هذا بنسميه acid
+
+22
+00:02:09,150 --> 00:02:15,610
+anhydride بنسميه acid anhydride
+
+23
+00:02:17,770 --> 00:02:23,130
+الان اللى بتطلع على هذه العائلة الكبيرة كتير خلينا
+
+24
+00:02:23,130 --> 00:02:27,630
+نسميه عائلة ال carbonyl compounds هيلحظ انه احنا
+
+25
+00:02:27,630 --> 00:02:31,890
+صارنا بنحكي عن عائلات فرعية موجودة فيها واحد اتنين
+
+26
+00:02:31,890 --> 00:02:38,890
+تلاتة اربع خمسة ستةسبعة يعني عدد كبير من العائلات
+
+27
+00:02:38,890 --> 00:02:42,710
+الفرعية جوا العائلة العاملة هي عائلة الاش ال
+
+28
+00:02:42,710 --> 00:02:46,390
+carbonyl compounds المركبات اللي بتحتوي على مجموعة
+
+29
+00:02:46,390 --> 00:02:53,690
+ال C double bond O لحسن الحظ ان هدول العائلات
+
+30
+00:02:54,350 --> 00:03:01,030
+يقسموا أو يجمعوا إلى عائلتين ال الديهيدس والكيتونز
+
+31
+00:03:01,030 --> 00:03:04,790
+في كل كتب الكيميا العضوية بتلاقوهم محطوطين مع بعض
+
+32
+00:03:04,790 --> 00:03:11,170
+في شبتر واحد والأحماض ومشتقاتها بنسميها assets and
+
+33
+00:03:11,170 --> 00:03:15,710
+their derivatives ال acid derivatives يعني هدولة
+
+34
+00:03:15,710 --> 00:03:19,290
+derivatives لل acid مشتقات derivative يعني إيش؟
+
+35
+00:03:19,970 --> 00:03:25,510
+الاسد ديريفاتيف لو قلنا لكم شو هم الاستر الامد
+
+36
+00:03:25,510 --> 00:03:32,190
+الاسد هيلايد والاسد انهيدريد هدولة الخمسة بنحط
+
+37
+00:03:32,190 --> 00:03:38,330
+بعيلة واحدةلاحظوا صار عندى تقسيم بدل ما هو ل سبع
+
+38
+00:03:38,330 --> 00:03:43,370
+عائلات كلها مختلفة حاطناهم بإيش؟ بعائلتين فقط
+
+39
+00:03:43,370 --> 00:03:48,850
+الهيتز و الفيتون عائلة الاسيتز و مصادرهم كلهم دول
+
+40
+00:03:48,850 --> 00:03:53,290
+عائلة و لذلك عادة في الكيميا العضوية في غالب الكتب
+
+41
+00:03:53,290 --> 00:03:56,630
+هتلاقي انه بنعمل عن كل هذه المركبات chapter يعني
+
+42
+00:03:56,630 --> 00:04:01,490
+فاصلين هدول بنحطه بفصل لحالهم و هدول بنحطه بفصل
+
+43
+00:04:01,490 --> 00:04:02,710
+لحالهم
+
+44
+00:04:05,560 --> 00:04:10,240
+لسه بإمكاننا نبسط الموضوع بإمكاننا نبسط الموضوع
+
+45
+00:04:10,240 --> 00:04:16,230
+أكثر كثير من هيكنقول ليش هذه التقسيمة و كيف أنا
+
+46
+00:04:16,230 --> 00:04:20,450
+الاشي الكتير بدي أسهل التعامل معه بنقول هذه
+
+47
+00:04:20,450 --> 00:04:26,050
+التقسيمة قائمة على كلمتين فقط كلمتين اللي بيفهم
+
+48
+00:04:26,050 --> 00:04:31,150
+دول الكلمتين بنقدر نقول عنه أنه فيهم ست إلى سبع
+
+49
+00:04:31,150 --> 00:04:36,090
+محاضرات للأمام هنضلنا نعيد و نزيد فيهم بنفس
+
+50
+00:04:36,090 --> 00:04:42,790
+الكلمتينواضح؟ صعب على البني آدم يفهم كلمتين كان
+
+51
+00:04:42,790 --> 00:04:48,130
+زمان برنامج بالتلفزيون بالإذاعة اسمه كلمتين و بس
+
+52
+00:04:48,130 --> 00:04:52,630
+خلوه و ميرك معاكم مين اللي كان يقدم هذا البرنامج
+
+53
+00:04:52,630 --> 00:04:58,330
+زمان اسأله الآباء والأجداد المهم ايش الكلمتين
+
+54
+00:04:58,330 --> 00:05:06,290
+المرتبطات بكل هذه العائلات الكلمة الأولىخاصة بأهم
+
+55
+00:05:06,290 --> 00:05:12,070
+تفاعل أساسي لهدول المركبات اللي هم ال aldehydes و
+
+56
+00:05:12,070 --> 00:05:19,630
+ال ketones بيتفاعلوا تفاعل ال addition الإضافة ال
+
+57
+00:05:19,630 --> 00:05:24,730
+addition و الكلمة التانية لهدول الخمسة اللي ضايقين
+
+58
+00:05:24,730 --> 00:05:29,750
+معهم ال unhydrate اللي شطبناه بتفاعلوا تفاعل ال
+
+59
+00:05:29,750 --> 00:05:32,930
+substitution الإبدال تمام؟
+
+60
+00:05:37,060 --> 00:05:43,120
+إذن سبب تقسيم هدول السبع مركبات إلى عائلات يعني
+
+61
+00:05:43,120 --> 00:05:46,440
+أحيانا الإنسان كان ممكن يسأل إذا السبعة بدنا
+
+62
+00:05:46,440 --> 00:05:50,180
+نعملهم عيلتين أو شبترين كان خلينا أربعة في شبتر
+
+63
+00:05:50,180 --> 00:05:56,620
+وتلاتة في شبتر تاني ليش خلينا اتنين وخمسة تمام؟ لأ
+
+64
+00:05:56,620 --> 00:06:03,470
+التقسيم مش تقسيم عددي التقسيم تقسيم وظيفي بمعنىإيش
+
+65
+00:06:03,470 --> 00:06:10,370
+التفاعل الأساسي لهذه العائلة هو تفاعل الإضافة؟ إيش
+
+66
+00:06:10,370 --> 00:06:16,450
+التفاعل الأساسي لهذه العائلة هو تفاعل الإبدال؟
+
+67
+00:06:16,450 --> 00:06:21,310
+ولذلك لو أي طالب organic chemistry بده يدخل مقابل
+
+68
+00:06:21,310 --> 00:06:25,510
+التوظيف، مانعش يمسك ورق و جلم و يكتب، لكن أبسط
+
+69
+00:06:25,510 --> 00:06:29,510
+سؤال بده يسأله ببساطة إيش التفاعل الأساسي
+
+70
+00:06:29,510 --> 00:06:33,660
+للالدهايتز والكيتونز؟ماعرفش يجاوب ايش التفاعل
+
+71
+00:06:33,660 --> 00:06:38,720
+الأساسي لل assets ومش رقاتها ماعرفش يجاوب نراكم في
+
+72
+00:06:38,720 --> 00:06:43,750
+السنة القادمةبالزمش يكون دراسة organic واضح اهتموا
+
+73
+00:06:43,750 --> 00:06:48,950
+كتير بهدول الكلمتين اللي بيفهموهم جيدا بيكونوا
+
+74
+00:06:48,950 --> 00:06:53,530
+فاهموا سبع عائلات اللي بيفهموا دول الكلمتين جيدا
+
+75
+00:06:53,530 --> 00:06:58,350
+بيكونوا فاهموا ايش سبع عائلات ولذلك خلينا نتعمق
+
+76
+00:06:58,350 --> 00:07:03,070
+اكتر بفهم هدول الكلمتين خلينا نتعمق اكتر بفهم هدول
+
+77
+00:07:03,070 --> 00:07:07,280
+الكلمتين الان احنا قولنا ايش ال carbonyl groupالـ
+
+78
+00:07:07,280 --> 00:07:11,960
+C double bond O طب لو كتبنا تحت الكربونيل C double
+
+79
+00:07:11,960 --> 00:07:17,120
+bond O ورجعنا للكلام اللي بنعرفه بخصوص السالبية
+
+80
+00:07:17,120 --> 00:07:22,640
+مين أكثر سالبية؟ ال oxygen مين أقل سالبية؟ ال
+
+81
+00:07:22,640 --> 00:07:26,880
+carbon إذا هذه ال carbon partially positive و هذه
+
+82
+00:07:26,880 --> 00:07:32,180
+ال oxygen partially negative واضح؟ الآن المحور
+
+83
+00:07:32,180 --> 00:07:36,410
+الأساسيفي فهم الكيميا كاملة تبعتي السبع عائلات
+
+84
+00:07:36,410 --> 00:07:43,210
+هدولة بينطلق من انه ال carbon موجبة يعني يمكن أهم
+
+85
+00:07:43,210 --> 00:07:49,530
+كلمة في فهم هذه العائلات السبعة كلها مجتمعة يعني
+
+86
+00:07:49,530 --> 00:07:54,250
+في فهم ال two chapters ان نقول ان هذا ال carbon
+
+87
+00:07:54,250 --> 00:07:59,030
+هاي بدنا نعلمها فيهم كلهم باللون الأحمر اشمالها
+
+88
+00:07:59,030 --> 00:08:07,920
+موجبةالان من باب تحصيل الحاصل الموجب لما يتفاعل ..
+
+89
+00:08:07,920 --> 00:08:14,280
+بنفتح بس على واحدة منهم الموجب لما يتفاعل ايش بده؟
+
+90
+00:08:14,280 --> 00:08:20,460
+بلغة الكيميا ال يوكليوفالالموجب لما يتفاعل بده
+
+91
+00:08:20,460 --> 00:08:24,980
+سالب بده نيوكليوفايل بناء على ذلك طالما جميعهم
+
+92
+00:08:24,980 --> 00:08:29,260
+عندهم ال carbon الموجبة إذا جميعهم تفاعلهم الأساسي
+
+93
+00:08:29,260 --> 00:08:33,580
+بيستنوا نيوكليوفايل واضح؟ يعني بدي أجيب ان
+
+94
+00:08:33,580 --> 00:08:40,360
+نيوكليوفايل و هذا عليه زوجمن الالكترونات زي ما
+
+95
+00:08:40,360 --> 00:08:43,500
+انتوا عارفين سواء كان مشحون او متعادل مش موضوعنا
+
+96
+00:08:43,500 --> 00:08:47,480
+.. وين بده يروح يجري يهاجم ال nucleophile على ال
+
+97
+00:08:47,480 --> 00:08:52,420
+carbon نفس ال nucleophile .. نفس ال nucleophile
+
+98
+00:08:52,420 --> 00:08:59,670
+على ال carbonالان هذا الـ nucleophile لما بيهاجم
+
+99
+00:08:59,670 --> 00:09:04,370
+على الكربون مرة هيعمل تفاعل إضافة في الحالتين
+
+100
+00:09:04,370 --> 00:09:08,870
+الأولانيات و في باقى الحالات هيعمل تفاعل إبدال إذا
+
+101
+00:09:08,870 --> 00:09:13,530
+لو جينا سألناكم قولنا لكم ال aldehydes بيعملوا
+
+102
+00:09:13,530 --> 00:09:19,150
+addition بتقولوا صحو ال acids و المشتقاتة بيعملوا
+
+103
+00:09:19,150 --> 00:09:24,510
+substitution صح لو سألنا هل يا ترى ال eucleophilic
+
+104
+00:09:24,510 --> 00:09:27,850
+addition و ال eucleophilic substitution ولا ال
+
+105
+00:09:27,850 --> 00:09:30,630
+electrophilic addition و ال electrophilic
+
+106
+00:09:30,630 --> 00:09:35,440
+substitution؟ ال eucleophilicإذن الآن بنقدر نزيد
+
+107
+00:09:35,440 --> 00:09:40,440
+كلمة إن ال الديهايدز تفاعلهم الأساسي اللي بديها
+
+108
+00:09:40,440 --> 00:09:45,340
+بالظبط الـ Eucleophilic addition وفهمنا ليش؟ ال
+
+109
+00:09:45,340 --> 00:09:50,460
+Eucleophilic addition و الأحماض و مشتقاتها تفاعلهم
+
+110
+00:09:50,460 --> 00:09:56,390
+الأساسي ال Eucleophilic substitution واضح؟لحد الآن
+
+111
+00:09:56,390 --> 00:10:02,230
+تمام الان بيصير ايش الناتج اللى بده يتكون عندى ايش
+
+112
+00:10:02,230 --> 00:10:06,510
+الناتج اللى بده يتكون في حالة ما كنا بنحكي عن ال
+
+113
+00:10:06,510 --> 00:10:10,870
+aldehydes و ال ketones addition معناه ان ال C
+
+114
+00:10:10,870 --> 00:10:15,070
+double bond O او ال double bond تصير single bondمش
+
+115
+00:10:15,070 --> 00:10:18,050
+هيك احنا قولنا ال addition يعني مجرد ماذا ال
+
+116
+00:10:18,050 --> 00:10:21,830
+nucleophile يهاجم هنا ويعمل رابطة هل معقول يصير
+
+117
+00:10:21,830 --> 00:10:26,290
+عندي خمس روابط؟ لأ، إذا هذه الرابطة بتتحرك تصبح O
+
+118
+00:10:26,290 --> 00:10:31,470
+minus بتصفح OH بتاخد H من اللي ال nucleophile أو
+
+119
+00:10:31,470 --> 00:10:36,310
+من ال solvent إذا الناتج اللي هيصير عندي ناتج ال
+
+120
+00:10:36,310 --> 00:10:40,310
+addition ببساطة إنه سيضة بال bond O تبعت ال ketone
+
+121
+00:10:40,310 --> 00:10:43,830
+أو تبعت ال aldehyde شو بده تصير؟ OH
+
+122
+00:10:46,820 --> 00:10:50,500
+شوفت وين ال addition هنا تم ال addition double
+
+123
+00:10:50,500 --> 00:10:56,980
+single إضافة شو هو ال addition تحويل ال double
+
+124
+00:10:56,980 --> 00:11:00,520
+bond إلى single bond إذا في ال aldehydes و ال
+
+125
+00:11:00,520 --> 00:11:05,060
+ketones ال C double bond O هتصير OH طبّاق
+
+126
+00:11:05,060 --> 00:11:12,240
+المجموعات R زي ما هي H أو R زي ما هي و اللي إجه
+
+127
+00:11:12,240 --> 00:11:14,900
+هنا ال nucleophile
+
+128
+00:11:17,240 --> 00:11:20,840
+مشهور الـ nucleophile اللي هاجمه عام الرابط إذا
+
+129
+00:11:20,840 --> 00:11:26,440
+هذا الشكل العام تبع نتيجة تفاعل ال الديهيد أو ال
+
+130
+00:11:26,440 --> 00:11:30,400
+ketones يعني لو إجينا قولنا مثلا لل nucleophile
+
+131
+00:11:30,400 --> 00:11:32,900
+H2O
+
+132
+00:11:35,400 --> 00:11:39,820
+ماذا سيحصل؟ هذه في كل الأحوال ستصبح OH مع كل أنواع
+
+133
+00:11:39,820 --> 00:11:44,040
+الـ nucleophiles لكن الـ H2O ماذا تضع هنا؟ OH
+
+134
+00:11:44,040 --> 00:11:48,140
+دائما الـ nucleophile المتعدد سنخصه من OH ولو قلنا
+
+135
+00:11:48,140 --> 00:11:53,420
+لـ nucleophile OH-, سيضع أيضًا OH و بعد ذلك نضع
+
+136
+00:11:53,420 --> 00:11:57,880
+acid ستصبح هذه OH إذا لو لـ nucleophile H2O أو H-,
+
+137
+00:11:57,880 --> 00:12:02,700
+سيصبح عندكم على الكربون OH من الألديهيد الأصلي و
+
+138
+00:12:02,700 --> 00:12:10,190
+OHالمهاجمة لو النيوكليوفايل الكهول شوف دي جهانة OR
+
+139
+00:12:10,190 --> 00:12:17,210
+هذه OH لا خلافة فيها ثابتة هذه ثابتة اللي هي ال C
+
+140
+00:12:17,210 --> 00:12:20,290
+double bond O لكن أنا بقول النيوكليوفايل الميا
+
+141
+00:12:20,290 --> 00:12:29,950
+بتحط OH الكحول بيحط OR ال HCl بيحط Cl و هكذا واضحة
+
+142
+00:12:29,950 --> 00:12:36,010
+الفكرة؟هي هذا الشكل العام تبع تفاعل إضافة وهو الذي
+
+143
+00:12:36,010 --> 00:12:41,130
+يميز جميع تفاعلات ال device و ال ketones و هناخد
+
+144
+00:12:41,130 --> 00:12:46,210
+أمثلة تصير كلها تكرار نضل نعيد يقول بيعمل إضافة و
+
+145
+00:12:46,210 --> 00:12:52,290
+بس في كل الأمثلة اللي بناخدها إيش بتصير القصة؟هنا
+
+146
+00:12:52,290 --> 00:12:55,470
+نقول ايه شو هو لليوكليوفايل؟ اذا كان ليوكليوفايل
+
+147
+00:12:55,470 --> 00:12:58,450
+ماء فهذه كذا، اذا كان الكول هذه كذا، اذا كان
+
+148
+00:12:58,450 --> 00:13:02,870
+سياناد كذا، اذا كان هايدرايد هذه كذا، يعني فقط هذا
+
+149
+00:13:02,870 --> 00:13:07,450
+المتغير الوحيد حيصفى عندكم شو هو ليوكليوفايل؟
+
+150
+00:13:07,450 --> 00:13:13,950
+واضح؟ الان لو اجينا وقلنا نفس ليوكليوفايل بده
+
+151
+00:13:13,950 --> 00:13:20,770
+يهاجم علىالكيتون على الكربون الحمراء عفوا على
+
+152
+00:13:20,770 --> 00:13:24,870
+الاسد لأ ما هو الكيتون زي الألدياد خلصنا منه على
+
+153
+00:13:24,870 --> 00:13:31,630
+الاسد أو مشتقاته إيش بيكون التفاعل؟ هذا بيجي هنا و
+
+154
+00:13:31,630 --> 00:13:38,020
+يطرد المجموعة هذهواضح؟ طبعا O H minus لما تترد
+
+155
+00:13:38,020 --> 00:13:43,920
+تاخد H من برا شو هتصير؟ O R minus لما تترد تاخد H
+
+156
+00:13:43,920 --> 00:13:51,460
+R O H كحول N H 2 لما تترد N H 3 C L minus لما يترد
+
+157
+00:13:51,460 --> 00:13:57,140
+C L اذا صار عندى هذه المجموعة هي اللتي تستبدل اللى
+
+158
+00:13:57,140 --> 00:14:03,380
+جنب ايش اللى جنب الصيغة بال bond O بناء على ذلك
+
+159
+00:14:03,380 --> 00:14:09,940
+الناتج ايش هيكون؟R C double bond O هذه ما زالت زي
+
+160
+00:14:09,940 --> 00:14:15,140
+ما هي لكن بدل ال OH او ال OR او ال NH2 whatever
+
+161
+00:14:15,140 --> 00:14:21,120
+whatever صار إبدال enucleophile نيو ن أيه صوديوم
+
+162
+00:14:21,120 --> 00:14:25,480
+نيوكليوفايل واضح يعني شيلنا هذه المجموعة و حطينا
+
+163
+00:14:25,480 --> 00:14:29,880
+مكانها إيش نيوكليوفايل هذا substitution ولا لأ
+
+164
+00:14:29,880 --> 00:14:35,430
+مجموعة جاية مجموعة طالعةواضحك الفكرة و الجزء اللي
+
+165
+00:14:35,430 --> 00:14:39,390
+طلع بياخد H بطلع على شكل ماء على شكل أمونيا على
+
+166
+00:14:39,390 --> 00:14:45,380
+شكل كحول على شكل HClهذا الكلام بتلاقوه بتكرر في كل
+
+167
+00:14:45,380 --> 00:14:50,660
+عائلات الأحماض ومشتقاتها إذا لو احنا كنا حتى
+
+168
+00:14:50,660 --> 00:14:55,280
+chapter 9 هذا اللي بدنا نبدأ فيه بدنا نعطيه عنوان
+
+169
+00:14:55,280 --> 00:14:59,820
+جديد ال dehydes and ketones بين قصين إيش بدنا نكتب
+
+170
+00:14:59,820 --> 00:15:04,300
+ال eucleophilic addition لو كنا في chapter 10 بدنا
+
+171
+00:15:04,300 --> 00:15:08,460
+نقول acids and their derivatives بين قصين ال
+
+172
+00:15:08,460 --> 00:15:12,910
+eucleophilic substitutionاللي فهموا هدولا الكلمتين
+
+173
+00:15:12,910 --> 00:15:19,430
+جيدا واتدربوا عليهم بيقدروا يتريحوا أربع أو خمس
+
+174
+00:15:19,430 --> 00:15:24,370
+محاضرات جاية خلاص بيصيروا بس بتذكروا الكلام اللي
+
+175
+0
+
+223
+00:19:41,970 --> 00:19:46,350
+مرتبطة بالقطبية بس هذه القيم خليني أقول تقريبية
+
+224
+00:19:46,350 --> 00:19:51,190
+ممكن مرة تانية نجيب القيم الدقيقة واضحة الفكرة
+
+225
+00:19:51,190 --> 00:19:57,930
+ال polarity أطول إلى انعكاس على القطبيه الان طيب
+
+226
+00:19:57,930 --> 00:20:03,370
+الان عكس على شغل تاني البولاريكي شو هي الذائبية و
+
+227
+00:20:03,370 --> 00:20:09,470
+القاعدة العامة في الموضوع ايش like dissolves like
+
+228
+00:20:09,470 --> 00:20:15,950
+الان اكتر حاجة فيها قطبية ايش الكحولات اللي فيها O
+
+229
+00:20:15,950 --> 00:20:20,190
+H's و بتذكروا حتى لما قلنا عن الكحولات قلنا
+
+230
+00:20:20,190 --> 00:20:26,280
+مابدناش ننسى ان الكحول في المجمعتين في الجزء القطبي
+
+231
+00:20:26,280 --> 00:20:33,200
+ال R والجزء القطبي ال OH والجزء غير القطبي ال R
+
+232
+00:20:33,200 --> 00:20:37,020
+وبناء على ذلك ال lower alcohols كانت water soluble
+
+233
+00:20:37,020 --> 00:20:42,000
+وال higher alcohols كانت water soluble تذكرين هذه
+
+234
+00:20:42,000 --> 00:20:46,180
+المعلومة؟ الكلام نفسه بتكرر وين؟ في ال ketones
+
+235
+00:20:46,180 --> 00:20:50,400
+برضه ال ketones فيهم جزء قطبة ال C double bond O و
+
+236
+00:20:50,400 --> 00:20:54,780
+فيهم ال R لما تصير ال R هذه كبيرة بيبطلوا يدوبوا
+
+237
+00:20:54,780 --> 00:20:57,840
+في الميه بس R صغيرة يعني مثل و مثل بيصير ال
+
+238
+00:20:57,840 --> 00:21:03,660
+acetone ال acetone بدوب في الميه لكن خلوها إثل و
+
+239
+00:21:03,660 --> 00:21:07,760
+إثل، إبروبل و إبروبل، فينل و إثل، كبرت، بتبطل
+
+240
+00:21:07,760 --> 00:21:12,140
+الدوب في المياه، واضح؟ فال lower molecular weight
+
+241
+00:21:12,140 --> 00:21:14,540
+species، يعني الأشياء اللي ال molecular weight
+
+242
+00:21:14,540 --> 00:21:18,560
+فيها إجليل في الأذيهات والكيتونز، بتكون إيش؟ water
+
+243
+00:21:18,560 --> 00:21:23,320
+soluble، كل ما ال R كبرت، بتبطل، يعني زي زي إيش؟
+
+244
+00:21:23,320 --> 00:21:27,720
+الكحولات فمن ال الديهيدس اللي بيدوبوا في الميا بشكل
+
+245
+00:21:27,720 --> 00:21:30,600
+عام ال formaldehyde بيدوب في الميا بيعطي ال
+
+246
+00:21:30,600 --> 00:21:34,340
+formalin ال acetaldehyde نسبيا بيدوب بعد هيك بيبطل
+
+247
+00:21:34,340 --> 00:21:38,000
+يدوب من ال ketones ال acetone بيدوب في الميا بعد
+
+248
+00:21:38,000 --> 00:21:43,270
+هيكلما يكبروا ببطله يدوبوا واضح فال low molecular
+
+249
+00:21:43,270 --> 00:21:45,830
+weight species are soluble in water and the
+
+250
+00:21:45,830 --> 00:21:50,270
+solubility decreases بتنقص as the R chain gets
+
+251
+00:21:50,270 --> 00:21:54,570
+longer كل ما كبرت ال R كل ما قلت التأبية وهذا
+
+252
+00:21:54,570 --> 00:21:58,710
+الكلام أيضا في الكحولات لاحظنا واضح الفكرة هذا
+
+253
+00:21:58,710 --> 00:22:02,710
+الكلام أيضا لاحظنا في الكحولات
+
+254
+00:22:06,830 --> 00:22:09,910
+طيب كيف بنسمي ال الديهايد و ال ketones؟ احنا قولنا
+
+255
+00:22:09,910 --> 00:22:14,510
+أساسا كل نظام التسمية في الكيميا العضوية نظام سهل
+
+256
+00:22:14,510 --> 00:22:20,230
+ليش سهل؟ لأنه مبني على ذكر طول السلسلة منتهي برمز
+
+257
+00:22:20,230 --> 00:22:28,770
+للمجموعة الوظيفية ال ال K نهايته L E I O للكحول ال
+
+258
+00:22:28,770 --> 00:22:35,330
+L ل ال الديهايد L و ل ال ketone O والذلك ال الديهيد
+
+259
+00:22:35,330 --> 00:22:40,670
+اللي متكون من كربونة واحدة بنقول مثانال مثانال
+
+260
+00:22:40,670 --> 00:22:45,130
+ماخد common name formaldehyde الان لو صاروا
+
+261
+00:22:45,130 --> 00:22:51,120
+كربونتينإيه ثانال؟ أسيتالديهيد الكمونومتينام لو
+
+262
+00:22:51,120 --> 00:22:56,400
+صاروا تلاتة بروبانال بروبيونالديهيد لو صاروا أربعة
+
+263
+00:22:56,400 --> 00:23:01,860
+بيوتانال بيوتيرالديهيد بيوتيرالديهيد الآن لاحظوا
+
+264
+00:23:01,860 --> 00:23:07,320
+هتلاحظوا الفرقبين ال aldehydes و الكحولات يعني في
+
+265
+00:23:07,320 --> 00:23:11,520
+الكحول كنا نقول ethanol, methanol, ethanol,
+
+266
+00:23:11,620 --> 00:23:15,320
+propanol, butanol وهنا بنقول methanol, ethanol,
+
+267
+00:23:15,440 --> 00:23:20,740
+propanol, butanol وين الفرق؟ لأ في فرق تاني أنا
+
+268
+00:23:20,740 --> 00:23:24,760
+عارف ال all و ال al هذه الفرق لكن في فرق تاني
+
+269
+00:23:24,760 --> 00:23:32,360
+الاسم كامل هنافي الكحولات لما أجي أقول بروبانول
+
+270
+00:23:32,360 --> 00:23:36,440
+بكفي؟
+
+271
+00:23:36,440 --> 00:23:42,640
+آه الكحول تلت ذرات كربون الآن هل يتر الأو اتش فيه
+
+272
+00:23:42,640 --> 00:23:47,480
+على واحد؟ one probanol و لا على اتنين؟ two
+
+273
+00:23:47,480 --> 00:23:52,360
+probanol واضح؟ إذا البروبانول في الكحولات منه
+
+274
+00:23:52,360 --> 00:23:59,290
+اتنين و البيوتانول كمان لو صار هذه اربع كربونات هل
+
+275
+00:23:59,290 --> 00:24:05,490
+الكحول هنا one بيوتانول
+
+276
+00:24:05,490 --> 00:24:10,050
+ولا two بيوتانول ولا two بيوتانول من هنا مش تلاتة
+
+277
+00:24:10,050 --> 00:24:18,590
+ال بيوتانول منه كم الكحول واضح؟ لتشين المتسلسل
+
+278
+00:24:18,590 --> 00:24:23,430
+يعني لو اجاكوا سؤال في الامتحان انه لتشين بيوتانول
+
+279
+00:24:23,430 --> 00:24:30,280
+اللي زي هيك كم كحول بالمجمل منه اتنينهك هتكون
+
+280
+00:24:30,280 --> 00:24:34,660
+جوابته غلط واضح؟
+
+281
+00:24:34,660 --> 00:24:41,060
+ليش؟ مين تقول لي ليش الغلط؟
+
+282
+00:24:41,060 --> 00:24:47,860
+لحظة أنا قلت المتسلسل، بعرف أنه في ISO و في
+
+283
+00:24:47,860 --> 00:24:53,750
+tertiary، هذه قصة تانية ما بدكوا تظلوا تعودوا اه ال
+
+284
+00:24:53,750 --> 00:24:55,910
+chiral center مش ال cis و ال trans ال cis و ال
+
+285
+00:24:55,910 --> 00:24:58,910
+trans كل ما يلي علاقة بالضبط بالبونس و بالحلقات ال
+
+286
+00:24:58,910 --> 00:25:03,870
+chiral center لما بيصير هذا هنا و بحط O H و H ع
+
+287
+00:25:03,870 --> 00:25:08,510
+طول صار عندى ROS من ال two butanol ال two butanol
+
+288
+00:25:08,510 --> 00:25:12,390
+منه ROS ال one butanol مافيش فيه chiral center one
+
+289
+00:25:12,390 --> 00:25:18,170
+butanol واضح؟ طبعا ما بننساش أنه فيه isobutanol و
+
+290
+00:25:18,170 --> 00:25:22,790
+tertiarybutanol كل هدول الأشياء لازم تكونوا
+
+291
+00:25:22,790 --> 00:25:27,470
+عارفينها الان ال aldehydes اللي جابنا للكلام ال
+
+292
+00:25:27,470 --> 00:25:32,190
+aldehydes لأ مافيش منها واحد و اتنين لأن مجموعة ال
+
+293
+00:25:32,190 --> 00:25:36,730
+aldehydes لا تكون الا على نمرة واحد و لانها لا
+
+294
+00:25:36,730 --> 00:25:41,310
+تكون الا على نمرة واحد بنحط ال hash رقم يعني ما
+
+295
+00:25:41,310 --> 00:25:46,110
+إجيناش كتبنا إيثان وان قالب روبان وان قالب يوتان
+
+296
+00:25:46,110 --> 00:25:49,510
+وان قالب لأنها لا تكون إلا على واحد فالاشي اللي
+
+297
+00:25:49,510 --> 00:25:54,830
+معروف ضلنا بلزم نكتبه واضح؟ ومثل ال الديهايد
+
+298
+00:25:54,830 --> 00:25:59,210
+بالمناسبة اللي ما بيكونش إلا على نمرة واحد وفقط
+
+299
+00:25:59,210 --> 00:26:07,770
+على واحد ال acid الحامض الحامض ما بيكون إلا على
+
+300
+00:26:07,770 --> 00:26:09,370
+الطرف
+
+301
+00:26:11,040 --> 00:26:15,620
+هيو زي هيو ولا ممكن يكون c double bond o o h في
+
+302
+00:26:15,620 --> 00:26:21,440
+النص مستحيل طب الحامض لو اجيت رقمت من هنا واحد
+
+303
+00:26:21,440 --> 00:26:25,500
+اتنين تلاتة اربعة و بدي اسميه طبعا هقول اكيد
+
+304
+00:26:25,500 --> 00:26:30,580
+بيوتان مافيش فيها لقاش هتقولي اللي هو الحامض ايش
+
+305
+00:26:30,580 --> 00:26:39,300
+نهايته اوك اسد اوك أسد بيوتانووك أسد الان هل يا ترى
+
+306
+00:26:39,300 --> 00:26:44,360
+بنحط بيوتان وان أوك أسد لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+307
+00:26:44,360 --> 00:26:45,200
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+308
+00:26:45,200 --> 00:26:46,700
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+309
+00:26:46,700 --> 00:26:47,880
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+310
+00:26:47,880 --> 00:26:48,340
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+311
+00:26:48,340 --> 00:26:52,440
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ ل
+
+312
+00:26:55,860 --> 00:27:00,100
+لأ ممكن يكون على موقع اتنين او تلاتة او اكتر يعني
+
+313
+00:27:00,100 --> 00:27:03,900
+في ال ketone بعد شوية هتلاحظوا لو كان عندنا خمس
+
+314
+00:27:03,900 --> 00:27:11,720
+ذرات كربون او ستة كم ذرة اللي رسمناهم واحد
+
+315
+00:27:11,720 --> 00:27:17,200
+اتنين تلاتة اربعة خمسة ستة سبعة و اجينا قولنا من
+
+316
+00:27:17,200 --> 00:27:24,440
+هذا المركب كسلسلة كم ketone بقدر اطلعلو قولت كام
+
+317
+00:27:24,440 --> 00:27:29,620
+الديهايد بقدر أعمل منه؟ واحد اسمه Heptanal و الـ C
+
+318
+00:27:29,620 --> 00:27:33,140
+double bond هو Hannah و Jamal لو قولت كام Acid
+
+319
+00:27:33,140 --> 00:27:39,020
+بقدر أطلع؟ Acid، واحد Heptanoic Acid لو قولت كام
+
+320
+00:27:39,020 --> 00:27:43,500
+كيتون؟ إذا إجت Hannah، two Heptanon وإذا إجت
+
+321
+00:27:43,500 --> 00:27:47,880
+Hannah، three Heptanon وإذا إجت Hannah، four
+
+322
+00:27:47,880 --> 00:27:56,330
+Heptanon one, twotwo عفوا واحد اتنين تلات عفوا two
+
+323
+00:27:56,330 --> 00:28:01,070
+و three و four اذا صار عندى two هبتانون و three
+
+324
+00:28:01,070 --> 00:28:05,490
+هبتانون و four هبتانون الا لو اجت هنا بتصير three
+
+325
+00:28:05,490 --> 00:28:08,470
+هبتانون من الجهة التانية او لو اجت هنا two هبتانون
+
+326
+00:28:08,470 --> 00:28:12,490
+من الجهة التانية اذا من هذا صار عندى اكتر من كيتون
+
+327
+00:28:12,490 --> 00:28:16,930
+فالكيتون يحتاج الى ترقيم لما بيلزم بينما ال
+
+328
+00:28:16,930 --> 00:28:22,270
+الديهايد لا يكون الا على موقع واحد و بعد الفكرة
+
+329
+00:28:22,270 --> 00:28:27,970
+ومثل الديهيد ال acid ومثل ال ketone ال alcohol إذا
+
+330
+00:28:27,970 --> 00:28:32,990
+الأشياء اللي احنا بنسمي بلزم نحطلها أرقام اللي أنا
+
+331
+00:28:32,990 --> 00:28:35,750
+خدوها كلها مين يذكرنا في الأشياء اللي بلزمها
+
+332
+00:28:35,750 --> 00:28:42,450
+أرقامه الأشياء اللي مابلزمها ال alkene يلزموا أرقام
+
+333
+00:28:42,450 --> 00:28:47,310
+انتبهوا معايا هاي سبع كاربونات لو كنت بعمل الكيل
+
+334
+00:28:47,310 --> 00:28:52,670
+ممكن يكون هنا او هنا او هنا اذا ال الكيل بيلزموا
+
+335
+00:28:52,670 --> 00:28:59,370
+أرقام ال الكاين one-heptane, two-heptane, three
+
+336
+00:28:59,370 --> 00:29:05,030
+-heptane يلزموا أرقام ال alcohol one-heptanol, two
+
+337
+00:29:05,030 --> 00:29:08,690
+-heptanol, three-heptanol, four-heptanol يلزموا
+
+338
+00:29:08,690 --> 00:29:14,920
+أرقام الكيتون two-heptanone، three-heptanone، four
+
+339
+00:29:14,920 --> 00:29:20,340
+-heptanone يلزم أرقام، إذا الالكيل والالكايد
+
+340
+00:29:20,340 --> 00:29:25,760
+والالكول والكيتون هدولة بلزمهم أرقام، لكن لو كنت
+
+341
+00:29:25,760 --> 00:29:30,960
+بحكي عن الديهيد، لأ، هبتنال فقط عن إمرأة واحدة
+
+342
+00:29:31,450 --> 00:29:36,250
+acid, heptanoic acid فالالدهاد والاسد ما بيكونوا
+
+343
+00:29:36,250 --> 00:29:54,710
+غير على موقع واحد واضحة تاني الفكرة حابين
+
+344
+00:29:54,710 --> 00:30:02,640
+تسمعوا الجوابلا بأس السؤال اللي سألته زملتكم أنه
+
+345
+00:30:02,640 --> 00:30:07,460
+لو كان في عندها رابطة ثلاثية و رابطة ثنائية كيف
+
+346
+00:30:07,460 --> 00:30:12,600
+بدي أسم المركب؟ تمام؟ لو عندي رابطة ثلاثية و رابطة
+
+347
+00:30:12,600 --> 00:30:16,800
+ثنائية كيف بدي أسم المركب؟ المركب بدي يكون في ال
+
+348
+00:30:16,800 --> 00:30:23,190
+keen و ال kind، الآن alphabetical ال E قبل ال I،
+
+349
+00:30:23,190 --> 00:30:26,570
+يعني لو كان بسبع ذرات، في double bond و triple
+
+350
+00:30:26,570 --> 00:30:32,170
+bond، إيش هيتسمى؟ هبتين I، يعني بتكونوا تتخيلوه،
+
+351
+00:30:32,170 --> 00:30:37,410
+سبع ذرات بهذا الشكل، بتأكدوا حيكون لإنه سبعة جاب
+
+352
+00:30:37,410 --> 00:30:43,720
+كلمة إيش؟ هبت سبع ذرات إيش هيجيبه؟ Hept لما يكون في
+
+353
+00:30:43,720 --> 00:30:48,960
+double bond ال double bond إيش هيجيبه؟ En لما يكون
+
+354
+00:30:48,960 --> 00:30:56,120
+في triple bond ل triple bond إيش هيجيبه؟ Ein زي
+
+355
+00:30:56,120 --> 00:31:01,490
+هيك لازم اسمه يبين حاجة بتعبر عن العدد بعدين عن
+
+356
+00:31:01,490 --> 00:31:05,650
+الألكين بعدين عن الألكاين هذا الكلام هذا الكلام
+
+357
+00:31:05,650 --> 00:31:12,530
+ككتابة اسم و كذكر مجموعات لكن بيجي سؤال لما بدي
+
+358
+00:31:12,530 --> 00:31:19,920
+أرقم أحدد وين موقع ال E وين موقع ال I هذه لها جثة
+
+359
+00:31:19,920 --> 00:31:25,080
+تانية و الموقع ال ال و الموقع ال I هذه لها جثة
+
+360
+00:31:25,080 --> 00:31:28,680
+تانية الآن القصة بتقول القات يعني خليني أعمل سبعة
+
+361
+00:31:28,680 --> 00:31:35,560
+واحد اتنين تلاتة اربع خمسة ستة سبعة و حطيت هذه زي
+
+362
+00:31:35,560 --> 00:31:37,300
+هيك و حطيت هنا triple bond
+
+363
+00:31:40,170 --> 00:31:44,050
+هذا heaped in I الان من وان بده ارقمه من هنا ولا
+
+364
+00:31:44,050 --> 00:31:50,230
+من هناك بنقول بنرقمه من الأقرب لأحد الأطراف يعني
+
+365
+00:31:50,230 --> 00:31:53,430
+تكون سواء double او triple اقرب يعني هنا لو عديت
+
+366
+00:31:53,430 --> 00:31:56,130
+واحد اتنين اول multiple point بتقابلني هنا عن
+
+367
+00:31:56,130 --> 00:31:59,930
+امرأة كم؟ تلاتة اول واحدة بتقابلني عن امرأة ايش؟
+
+368
+00:31:59,930 --> 00:32:04,110
+واحد وبناء على ذلك هرقم واحد اتنين تلاتة اربعة
+
+369
+00:32:04,110 --> 00:32:14,600
+خمسة ستة سبعة فهذا هيكون heapedone in أربعة I هبت
+
+370
+00:32:14,600 --> 00:32:23,520
+one in four I واضح طبعا لو انعكس سجلوا هذا الشغل ب
+
+371
+00:32:23,520 --> 00:32:31,160
+ثانية بقول برقم من الأقرب لأحد الأطراف الأقرب
+
+372
+00:32:31,160 --> 00:32:35,760
+بشتغل عليه تمام يعني هذا المركب .. بصوا بري ثانية
+
+373
+00:32:35,760 --> 00:32:41,500
+يا هودا يعني هذا المركب نفسه الآن لو كان زي هيك ايش
+
+374
+00:32:41,500 --> 00:32:45,740
+رأيكم؟ هيظلوا على نفس الترقيم؟ اه .. اه .. اه ..
+
+375
+00:32:45,740 --> 00:32:45,840
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+376
+00:32:45,840 --> 00:32:46,020
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+377
+00:32:46,020 --> 00:32:47,260
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+378
+00:32:47,260 --> 00:32:47,540
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+379
+00:32:47,540 --> 00:32:48,040
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+380
+00:32:48,040 --> 00:32:48,460
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+381
+00:32:48,460 --> 00:32:52,340
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. ا
+
+382
+00:32:53,210 --> 00:32:58,710
+يعني مافيش تسمية نهائية تكون I'm in هذه ضد ال
+
+383
+00:32:58,710 --> 00:33:01,910
+alphabetical دائما الاتقاء ال double و ال triple
+
+384
+00:33:01,910 --> 00:33:06,210
+bond يجب أن تكون إيش؟ in I'm مافيش إشي في الكون
+
+385
+00:33:06,210 --> 00:33:11,990
+اسمه I'm in ضد ال alphabetical واضح؟ الآن الترقيم
+
+386
+00:33:11,990 --> 00:33:16,190
+هلجيته؟ هذي جاي ع نمره واحد لو بتعد من هنا بتجي ع
+
+387
+00:33:16,190 --> 00:33:19,770
+نمره واحد اتنين تلاتة إذا هذا الترقيم الصح وجدت
+
+388
+00:33:19,770 --> 00:33:22,470
+هذا المركب لما بده يتسمى مرة تانية
+
+389
+00:33:26,270 --> 00:33:34,090
+لاحظوا in و i عشان يتقارنوا المركبين الان هذا ال
+
+390
+00:33:34,090 --> 00:33:40,250
+in تبع وين اربعة و ال i تبع واحد خلصنا من المركب
+
+391
+00:33:40,250 --> 00:33:46,310
+اللي قبله ماناش فيه هذا بيصير
+
+445
+00:38:53,320 --> 00:38:57,620
+هذي بإيش؟ ب Carbon ولذلك هذا لما بدنا نسميه
+
+446
+00:38:57,620 --> 00:39:02,560
+Cyclopentanol
+
+447
+00:39:02,560 --> 00:39:08,340
+تان و بنضيف النهاية تبعته All Cyclopentanol خلصنا
+
+448
+00:39:08,340 --> 00:39:16,050
+هذا لما بدنا نسميه نفس الفكرة Cycloبنتان وبنحطله
+
+449
+00:39:16,050 --> 00:39:23,250
+نهاية ال ketone بنتانون وخلصنا هذا لما بدي اسميه
+
+450
+00:39:23,250 --> 00:39:30,330
+.. لأ بسميهوش cycle بالتنالليش؟ لأنه إجي عليه
+
+451
+00:39:30,330 --> 00:39:33,690
+مجموعة كاملة خارجية، إجي عليه كمان carbon، C
+
+452
+00:39:33,690 --> 00:39:39,350
+double bond OH، بنسميه Cyclopenten-carb-aldehyde
+
+453
+00:39:39,350 --> 00:39:43,410
+لأنه إجت carbon زيادة عن اللي جابله، ولذلك هذا إيش
+
+454
+00:39:43,410 --> 00:39:50,910
+بده يتسمى؟ Cyclopenten-carb-aldehyde
+
+455
+00:39:53,820 --> 00:39:58,780
+ملاحظين الفرق بينهم؟ أنه أنا مابقدرش أشبك أكسوجين
+
+456
+00:39:58,780 --> 00:40:02,560
+الالديهايد مباشرة بالحلقة إلا من خلال ذرة كربون
+
+457
+00:40:02,560 --> 00:40:07,620
+ولذلك بنسميه Cyclopentane Carbaldehyde شفتوا الفرق
+
+458
+00:40:07,620 --> 00:40:11,500
+بين الكحول والكيتون والالديهايد لو يجي على حلقة؟
+
+459
+00:40:12,310 --> 00:40:16,630
+الان لو واحدة فيكم شاطرة بعد ما نختم المحاضرة بذكر
+
+460
+00:40:16,630 --> 00:40:20,210
+الله اتقولي كمان اخر مثال عشان نسكر هذه النقطة
+
+461
+00:40:20,210 --> 00:40:26,510
+المفروض يلحق هدولة كلهم ايش هيكون ال acid ال acid
+
+462
+00:40:26,510 --> 00:40:32,070
+لو بده ييجي على الحلقة كيف بده ييجي زي ال aldehyde
+
+463
+00:40:32,070 --> 00:40:37,150
+ال acid لو بده ييجي على الحلقة بده ييجي كله معلج
+
+464
+00:40:37,150 --> 00:40:38,010
+على الحلقة
+
+465
+00:40:42,740 --> 00:40:46,200
+ماقدرش أحطه على نفس الحلقة الأكسجينة المتصلة ولذلك
+
+466
+00:40:46,200 --> 00:40:49,820
+لما بدي أسميه بدي أسميه بشكل موازن لنظام ال
+
+467
+00:40:49,820 --> 00:40:57,680
+الديهايد إيش وجدت حاجة أقول عنه؟ Cyclo .. بنتين ..
+
+468
+00:40:57,680 --> 00:41:03,300
+Carboxylic acid كمان Carboxylic acid
+
+469
+00:41:05,250 --> 00:41:09,150
+شوفتوا كيف مقارنة الأمور بتيجي الكحول والكيتون
+
+470
+00:41:09,150 --> 00:41:11,750
+بيجيوا مباشرة على الحلقة فبنقول cyclopentanol
+
+471
+00:41:11,750 --> 00:41:16,090
+وcyclopentanol ال aldehyde لأ cyclopentane وcarb
+
+472
+00:41:16,090 --> 00:41:20,670
+aldehyde ال acid cyclopentane وcarboxylic acid
+
+473
+00:41:20,670 --> 00:41:26,650
+واضحة الفكرة وبهيك بننهي المحاضرة اليوم المرة اللي
+
+474
+00:41:26,650 --> 00:41:29,970
+جاي بنستمر في موضوع التسمية وموضوع ال aldehydes
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8b65882cd124d32b1eb0a42dba8ab91a2aba78db
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E.srt
@@ -0,0 +1,1498 @@
+
+1
+00:00:20,790 --> 00:00:24,970
+بسم الله الرحمن الرحيم اليوم إن شاء الله في
+
+2
+00:00:24,970 --> 00:00:30,390
+المحاضرة الأخيرة بدنا نحاول نراجع بعض الامتحانات
+
+3
+00:00:30,390 --> 00:00:35,430
+نشوف كيف بتيجي الصورة الكلية في الامتحانات على هذه
+
+4
+00:00:35,430 --> 00:00:39,630
+المادة في عندنا هذا الامتحان هذا الامتحان كان في
+
+5
+00:00:39,630 --> 00:00:45,330
+الفصل الأول الماضي لطلاب السنة الأولى في كلية الطب
+
+6
+00:00:45,910 --> 00:00:50,190
+نحاول مع بعض نمر عليه، بنلاحظ أن الأسئلة طبعًا
+
+7
+00:00:50,190 --> 00:00:55,750
+منوعة، في أسئلة صح و غلط، أكمل الفراغ، سم المركب،
+
+8
+00:00:55,750 --> 00:01:01,760
+كيف تحضر مركب، أكمل المعادلة، كل هذه الأشياء نشوف
+
+9
+00:01:01,760 --> 00:01:07,800
+الأشياء بالترتيب في أسئلة الصح والغلط بيسألنا سؤال
+
+10
+00:01:07,800 --> 00:01:13,160
+بيقولنا الـpeptide لجليسين ألانين ألانين و
+
+11
+00:01:13,160 --> 00:01:16,380
+الـpeptide ألانين جليسين جليسين are structural
+
+12
+00:01:16,380 --> 00:01:20,920
+isomers إيش رأيكم؟ they are not isomers لأن ال
+
+13
+00:01:20,920 --> 00:01:26,140
+isomers لازم يكونوا مكونين من نفس الأشياء يعني هذا
+
+14
+00:01:26,140 --> 00:01:29,120
+اتنين ألانين واحد جليسين هذا اتنين جليسين واحد
+
+15
+00:01:29,120 --> 00:01:32,700
+ألانين they are not isomers they are different
+
+16
+00:01:32,700 --> 00:01:43,140
+compounds a glucofuranose is an aldopentose واضح؟
+
+17
+00:01:43,140 --> 00:01:49,340
+إيش رأيكم؟
+
+18
+00:01:49,340 --> 00:01:54,760
+الفيورانوز خمسة
+
+19
+00:01:54,760 --> 00:02:01,200
+لكن الجلوكوز ستة الجلوكوز
+
+20
+00:02:04,860 --> 00:02:11,080
+لأ لما نقول جولوكوز، الجولوكوز مر علينا وين؟ في
+
+21
+00:02:11,080 --> 00:02:16,500
+الالدوهيكسوزز؟
+
+22
+00:02:16,500 --> 00:02:17,700
+لأ هذا world
+
+23
+00:02:29,910 --> 00:02:36,410
+الجلوكوز نفسه ست كربونات ولا خمسة؟ ستة، الآن لما
+
+24
+00:02:36,410 --> 00:02:41,470
+أنا هنا بقول خمسة، إذا هذا الكلام صح ولا غلط؟ غلط،
+
+25
+00:02:41,470 --> 00:02:46,810
+لأنه الجلوكوز ستة مش خمسة، واضحة الفكرة؟ الجلوكوز
+
+26
+00:02:46,810 --> 00:02:50,910
+ستة ذرات كربون، مش خمسة The peptide bond is longer
+
+27
+00:02:50,910 --> 00:02:57,830
+than normal C double bond N أو C N double bond،
+
+28
+00:02:57,830 --> 00:03:03,110
+إيش رأيكوا؟ هل الـpeptide أطول من الـC double bond
+
+29
+00:03:03,110 --> 00:03:06,190
+N؟ طبعًا انتوا بتكونوا تتذكروا ان الـamide bond
+
+30
+00:03:06,190 --> 00:03:11,990
+الـamide bond اللي هي الـCN كأنها رابطة و نص مع
+
+31
+00:03:11,990 --> 00:03:15,850
+الـresonance ليش؟ لأنه أنا في الـamide bond عندي C
+
+32
+00:03:15,850 --> 00:03:20,590
+double bond ON هذه single bond في الوضع الطبيعي
+
+33
+00:03:20,590 --> 00:03:27,510
+الآن لو صارت هنا C double bond N وهنا الـO minus
+
+34
+00:03:27,510 --> 00:03:28,530
+صارت
+
+35
+00:03:30,900 --> 00:03:35,480
+Double bond فهل ال peptide أو الأمد double ولا
+
+36
+00:03:35,480 --> 00:03:42,220
+single؟ لأ هي واحد و نص في النهاية مش احنا حكينا في
+
+37
+00:03:42,220 --> 00:03:46,880
+عندنا أمد resonance الامد بيعمل resonance معنى
+
+38
+00:03:46,880 --> 00:03:51,580
+resonance هذه اللي بتكون مرة double single bond في
+
+39
+00:03:51,580 --> 00:03:54,800
+المرة التانية شو بتكون double bond شو متوسط ال
+
+40
+00:03:54,800 --> 00:03:58,640
+double و ال single واحد و نص الآن الواحد و نص
+
+41
+00:03:58,640 --> 00:04:03,600
+كرابطة الواحد و نص كرابطة مقارنة بالواحد أيه اطول
+
+42
+00:04:03,600 --> 00:04:09,920
+رابطة الـ single أقصر الـ double ال and ال
+
+43
+00:04:09,920 --> 00:04:16,160
+واحد و نص بينهم فهي أقصر من الـ single و أطول من ال
+
+44
+00:04:16,160 --> 00:04:21,140
+double واضح الـ رابطة لما تكون ب resonance يعني
+
+45
+00:04:21,140 --> 00:04:24,240
+كأنها واحد و نص هي أقصر من الـ single bond و أطول
+
+46
+00:04:24,240 --> 00:04:29,460
+من الـ double bond احنا ايش كاتبين is longer than c
+
+47
+00:04:29,460 --> 00:04:35,250
+double bond and إذا هذه الجملة صح واضحة الفكرة؟ هذه
+
+48
+00:04:35,250 --> 00:04:38,630
+بتعتمد على فهمكم للأمد resonance .. بتعتمد على
+
+49
+00:04:38,630 --> 00:04:42,130
+فهمكم للأمد resonance Hydrolysis of starch
+
+50
+00:04:42,130 --> 00:04:49,350
+produces only beta-glucopyranosis الـ starch من أي
+
+51
+00:04:49,350 --> 00:04:53,110
+سكة؟
+
+52
+00:04:53,110 --> 00:05:00,710
+من؟ كويس من أي ديساكراي؟ ملتوز .. الملتوز من إيش؟
+
+53
+00:05:02,010 --> 00:05:08,890
+أي جولوكوز ألف وأو بيتا ألف وأو بيتا الآن هنا إيش
+
+54
+00:05:08,890 --> 00:05:16,130
+كاتبين إحنا only بيتا لأن الملتوز ألف وأو بيتا
+
+55
+00:05:16,130 --> 00:05:19,950
+ملتوز ألف وأو بيتا the OH of the anomeric carbon
+
+56
+00:05:19,950 --> 00:05:23,690
+of beta-glucobyranose is found in the equatorial
+
+57
+00:05:23,690 --> 00:05:29,870
+position هذه أخدناها صحيحة
+
+58
+00:05:31,370 --> 00:05:36,890
+مشقولنا انه ليش بيكون ال beta نسبته أعلى من ال
+
+59
+00:05:36,890 --> 00:05:40,270
+alpha لأنه ال beta في ال equatorial position مافيش
+
+60
+00:05:40,270 --> 00:05:45,650
+عليها steric hindrance داي تيربين are composed of
+
+61
+00:05:45,650 --> 00:05:52,710
+twenty carbon atoms الآن ال mono terbin كم إيزو
+
+62
+00:05:52,710 --> 00:05:57,110
+برين unit؟ اثنتين الـداي تيربين كم إيزو برين unit
+
+63
+00:05:57,110 --> 00:05:58,910
+أربع أربع في خمسة
+
+64
+00:06:02,460 --> 00:06:09,860
+hydrogenation of oils is a saponification reaction
+
+65
+00:06:09,860 --> 00:06:12,880
+هدرجة
+
+66
+00:06:12,880 --> 00:06:18,280
+الزيوت بتحول ال double bond إلى single bond بتحول
+
+67
+00:06:18,280 --> 00:06:22,820
+ال oil إلى fat ال saponification reaction بيعمل
+
+68
+00:06:22,820 --> 00:06:29,770
+hydrolysis فهدرجة الزيوت مش تفاعل سابونفكاشن
+
+69
+00:06:29,770 --> 00:06:34,250
+السابونفكاشن إن أخد الـ triglyceride أحوله الى
+
+70
+00:06:34,250 --> 00:06:41,190
+soap إلى salt of the fatty acid واضح ان احول الزيت
+
+71
+00:06:41,190 --> 00:06:45,690
+إلى سابون إن أعمل hydrolysis الآن هل ال
+
+72
+00:06:45,690 --> 00:06:48,970
+hydrogenation عمل hydrolysis ولا تحويل double bond
+
+73
+00:06:48,970 --> 00:06:52,610
+لـ single bond؟ اه اذا ال hydrogenation is
+
+74
+00:06:52,610 --> 00:06:58,270
+سابونفكاشن reaction غلط الهيدروجينيشن تحويل بابل
+
+75
+00:06:58,270 --> 00:07:03,710
+بوند لـ single bond مش تحويل إيستر لملح The polar R
+
+76
+00:07:03,710 --> 00:07:08,990
+groups in hair proteins طبعًا الـ hair fibrous
+
+77
+00:07:08,990 --> 00:07:15,750
+protein are located outside الفيبرس
+
+78
+00:07:15,750 --> 00:07:22,450
+وين موجودة ال R groups تبعتهم؟ جوا مش برا الـ fibers
+
+79
+00:07:22,450 --> 00:07:27,350
+الـ proteins الـ R groups تبعتهم موجودة للداخل ولذلك
+
+80
+00:07:27,350 --> 00:07:34,390
+هذه الجملة غلط واضحة الآن complete the following
+
+81
+00:07:34,390 --> 00:07:38,450
+statements نرفع شوية
+
+82
+00:07:45,750 --> 00:07:49,630
+الدياستيريوم الذين يختلفون فقط في مركز واحد كيرال
+
+83
+00:07:49,630 --> 00:08:02,610
+يسمون ابيمارز ابيمارز اسم الكيميائي لاسبيرين أسيتل
+
+84
+00:08:02,610 --> 00:08:07,130
+ساليسينك
+
+85
+00:08:07,130 --> 00:08:12,830
+أسد باراسيتامول
+
+86
+00:08:12,830 --> 00:08:14,170
+أيضًا يسمون
+
+87
+00:08:18,000 --> 00:08:24,020
+أسيتامينوفين متذاكرين هالكلام؟ أسيتامينوفين
+
+88
+00:08:24,020 --> 00:08:30,000
+دايسالفايد بونتز ان البروتينز ريزولت من أكسيدشن أي
+
+89
+00:08:30,000 --> 00:08:35,520
+امينواسد اللي بيعمل دايسالفايد بونت؟ سيستين
+
+90
+00:08:44,950 --> 00:08:49,250
+أكسيدات الجولوكوز باستخدام نيترك أسد تنتج
+
+91
+00:08:49,250 --> 00:08:58,410
+إجلوكاريك إجلوكاريك أسد اللي هو يعني فيه مجموعتين
+
+92
+00:08:58,410 --> 00:09:08,350
+حامض إجلوكاريك أسد إجلوكاريك أسد التغيير
+
+93
+00:09:08,350 --> 00:09:11,870
+في حركة العيون بسبب التعاون بين الحيوانات
+
+94
+00:09:11,870 --> 00:09:18,880
+والمواصلة ميوتا روتيشن
+
+95
+00:09:18,880 --> 00:09:24,080
+البروجيستيرون
+
+96
+00:09:24,080 --> 00:09:33,800
+هم 6 هرمون مع مصادر استيرويدال استيرويدال
+
+97
+00:09:33,800 --> 00:09:38,360
+مصادر استيرويدال تقوم بالتقليل من الشغر
+
+98
+00:09:43,220 --> 00:09:49,820
+السكريات المختزلة بيصيرلها oxidation reactions
+
+99
+00:09:49,820 --> 00:09:59,420
+واضح؟ oxidation لأنه هي الـ ديهايد بيصيرلها أكسدة
+
+100
+00:09:59,420 --> 00:10:05,540
+واضح؟ reducing sugars undergo oxidation reactions
+
+101
+00:10:13,590 --> 00:10:19,570
+name the following compounds اول مركب ايش شايفين
+
+102
+00:10:19,570 --> 00:10:25,010
+فيه مجموعات وظيفية الديهايد و كيتون و double bond
+
+103
+00:10:25,010 --> 00:10:29,530
+شو لازم يصير الديهايد اعلى او لو يالا الديهايد
+
+104
+00:10:29,530 --> 00:10:34,630
+واحد اثنين تلاتة اربعة خمسة إذا هذا هيكون
+
+105
+00:10:56,440 --> 00:10:59,240
+توبنتينال توبنتينال
+
+106
+00:11:02,160 --> 00:11:06,800
+واضح؟ الآن تطلع على المركب اللي بعده أهم شغل تعرفه
+
+107
+00:11:06,800 --> 00:11:13,440
+المجموعة الوظيفية تبعت المركب الـ acid الـ acid ال
+
+108
+00:11:13,440 --> 00:11:21,160
+acid إذا هقول انا واحد اثنين تلاتة أربعة هاي الجزء
+
+109
+00:11:21,160 --> 00:11:27,620
+الأساسي في المركب الآن هذا الجزء شو اسمه بيوتانويك
+
+110
+00:11:27,620 --> 00:11:30,660
+بيوتانويك
+
+111
+00:11:31,760 --> 00:11:40,640
+acid إيش بيحمل على نمرة تلاتة؟ three cyclopentyl
+
+112
+00:11:40,640 --> 00:11:50,520
+وشو بيحمل على نمرة أربعة؟ four dimethylamino
+
+113
+00:11:50,520 --> 00:11:55,560
+three cyclopentyl
+
+114
+00:11:55,560 --> 00:12:00,380
+four dimethylamino butanoic acid واضح؟
+
+115
+00:12:02,250 --> 00:12:07,430
+3-cyclopentel-4-dimethylamino-butanoic acid اخر
+
+116
+00:12:07,430 --> 00:12:14,490
+مركب شو مجموعته الوظيفية؟ أمد من
+
+117
+00:12:14,490 --> 00:12:22,450
+كم كربونة مكوّن بالأساس يعني جاي من أي حامض من ال
+
+118
+00:12:22,450 --> 00:12:31,330
+acetic acid اذا هذا اسيت امد او لو قولنا اثانوك
+
+119
+00:12:31,330 --> 00:12:31,810
+اسد
+
+120
+00:12:35,670 --> 00:12:43,650
+الآن ايش بيحمل هذا على نمرة اثنين؟ فنل فنل فنل فنل
+
+121
+00:12:43,650 --> 00:12:48,190
+فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل
+
+122
+00:12:48,190 --> 00:12:48,470
+فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل
+
+123
+00:12:48,470 --> 00:12:51,550
+فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل
+
+124
+00:12:51,550 --> 00:12:51,670
+فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل
+
+125
+00:12:51,670 --> 00:13:02,030
+فنل فنل فنل فنل
+
+126
+00:13:02,030 --> 00:13:02,570
+فن
+
+127
+00:13:08,520 --> 00:13:13,160
+الآن هانا بدنا ياكوا ترسمون لبعض المركبات بأشكالها
+
+128
+00:13:13,160 --> 00:13:17,340
+العامة لو قولنا أسيتوفينون مين ما بتعرفش
+
+129
+00:13:17,340 --> 00:13:21,440
+الأسيتوفينون CH3
+
+130
+00:13:21,440 --> 00:13:29,480
+فينيل C double bond O الآن لما بدي هيدرازون بدو
+
+131
+00:13:29,480 --> 00:13:34,110
+يصير C double bond N NH احنا إيش حاطين على
+
+132
+00:13:34,110 --> 00:13:39,890
+الهيدرازون أسيتل لو كانت مثل بنحط مثل فينال فينال
+
+133
+00:13:39,890 --> 00:13:44,950
+أسيتل C
+
+134
+00:13:44,950 --> 00:13:53,750
+double bond O CH3 أسيتوفينون هيدرازون أسيتل
+
+135
+00:13:53,750 --> 00:13:57,960
+هيدرازون أسيتوفينون لو فينيل كان قولنا فينيل
+
+136
+00:13:57,960 --> 00:14:01,600
+هيدرازون مثل مثل هيدرازون اثل هيدرازون أسيت
+
+137
+00:14:01,600 --> 00:14:08,860
+الهيدرازون الـ glyceraldehyde الـ glyceraldehyde في
+
+138
+00:14:08,860 --> 00:14:18,560
+هنا الديهايد و بعدين كايرال سنتر واحد شوفي هنا
+
+139
+00:14:18,560 --> 00:14:19,740
+الكايرال سنتر
+
+140
+00:14:22,340 --> 00:14:31,660
+H و OH و أنا هاي
+
+141
+00:14:31,660 --> 00:14:39,620
+الـ glycerol دي و لو كان دي ناقص بنزل to بيوتاي
+
+142
+00:14:39,620 --> 00:14:45,160
+نويت بنخلص
+
+143
+00:14:45,160 --> 00:14:47,020
+هدول خلصناهم
+
+144
+00:14:49,020 --> 00:14:54,540
+الآن طبعًا بنبدأ الرسم من الآخر معناه ا و ات يعني
+
+145
+00:14:54,540 --> 00:15:00,480
+عندي P stop يعني عندي C double bond O O الآن شو
+
+146
+00:15:00,480 --> 00:15:09,180
+الجزء الـ alcohol اللي هنا بنزل شو البنزل CH2
+
+147
+00:15:09,180 --> 00:15:15,960
+فنل CH2 فنل هي البنزل بنزل بيوتين و ات هي كربونة
+
+148
+00:15:15,960 --> 00:15:17,340
+كم كربون بيضل عندي
+
+149
+00:15:26,230 --> 00:15:32,970
+أربعة الآن في عندي ال triple bond على نمرة اتنين
+
+150
+00:15:32,970 --> 00:15:42,690
+إذا واحد اثنين تلاتة وهدى شو بيخليها CH3 وهدى
+
+151
+00:15:42,690 --> 00:15:51,050
+رقم واحد يعني لحظة بنزل فنل CH2 بنزل الـ Easter C W
+
+152
+00:15:51,050 --> 00:15:55,870
+bond O O R واضح بيوتين واحة اثنين تلاتة أربعة two
+
+153
+00:15:55,870 --> 00:16:02,170
+بيوتين و اثنين هذا المركب بهدوء بنمشي فيه خطوة
+
+154
+00:16:02,170 --> 00:16:07,330
+خطوة بنرسمه Cyclopentane كيف الـ Cyclopentane؟ في
+
+155
+00:16:07,330 --> 00:16:14,590
+حد بعرفهش؟ بدنا نعمل فيه الديهيد سايكلوبنتين
+
+156
+00:16:14,590 --> 00:16:21,070
+كربلديهيد كيف الكربلديهيد؟ C double bond O H هاي
+
+157
+00:16:21,070 --> 00:16:26,090
+السايكلوبنتين كربلديهيد هذا السايكلوبنتين
+
+158
+00:16:26,090 --> 00:16:30,910
+كربلديهيد الآن لما بتعمل أكزيم بدي أشيل الـ O
+
+159
+00:16:30,910 --> 00:16:35,670
+أخليها N OH
+
+160
+00:16:38,800 --> 00:16:43,560
+حولت الالديهيد إلى أكزيم سايكلوبنتين كربالديهيد
+
+161
+00:16:43,560 --> 00:16:49,820
+أكزيم Beta
+
+162
+00:16:49,820 --> 00:16:57,100
+to deoxifuranose متذكرين الفيورانوز؟ بده general
+
+163
+00:16:57,100 --> 00:17:05,120
+structure له أهم شيء انه على موقع اتنين في عنده
+
+164
+00:17:07,970 --> 00:17:14,750
+بهمنيش ال O H بهمني الـ two دي أوكزي هنا في oxygen
+
+165
+00:17:14,750 --> 00:17:25,410
+و الموقع اتنين هنا هذا
+
+166
+00:17:25,410 --> 00:17:29,550
+الموقع واضح مار عليكوا ولا نفرجيكوا معاه
+
+167
+00:17:40,850 --> 00:17:47,390
+نذكركوا فيه لو سمحتوا في ال .. في ال
+
+168
+00:17:47,390 --> 00:17:54,990
+carbohydrates، هذا ال carbohydrates؟ لأ
+
+169
+00:18:08,950 --> 00:18:12,190
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+170
+00:18:12,190 --> 00:18:18,910
+Clothes Clothes
+
+171
+00:18:18,910 --> 00:18:19,190
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+172
+00:18:19,190 --> 00:18:19,210
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+173
+00:18:19,210 --> 00:18:19,390
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+174
+00:18:19,390 --> 00:18:19,510
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+175
+00:18:19,510 --> 00:18:19,830
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+176
+00:18:19,830 --> 00:18:20,630
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+177
+00:18:20,630 --> 00:18:20,750
+Clothes Clothes
+
+178
+00:18:33,500 --> 00:18:36,800
+oxygen ديش هيكوا تحفظوا الـ watchs لوين بس أهم إشي
+
+179
+00:18:36,800 --> 00:18:43,460
+تنتبهوه لإنه موقع اتنين دي oxy sugar واضحة موقع
+
+180
+00:18:43,460 --> 00:18:50,040
+اتنين دي oxy sugar مافيش عليه إيش؟ watchs موقع اثنين
+
+181
+00:18:50,040 --> 00:18:58,580
+مافيش عليه watchs ماليك انهيدريد متذكرين الماليك
+
+182
+00:18:58,580 --> 00:19:08,650
+انهيدريد؟ سيبقى بالـ بنت او اوC double bond O ماليك
+
+183
+00:19
+
+223
+00:23:18,550 --> 00:23:24,890
+الكلام الفكرة خلصت الان كحول مع الديهايد hemacetal
+
+224
+00:23:24,890 --> 00:23:31,410
+الديهايد بالاختزال كحول الديهايد بالأكسدة حم حم
+
+225
+00:23:31,410 --> 00:23:37,710
+زاد قاعدة ملح حم زاد ثيونيلي كلورايد أسد كلورايد
+
+226
+00:23:37,710 --> 00:23:43,790
+الديهايد مع السيانو هدرين الديايد مع الاتلينيج
+
+227
+00:23:43,790 --> 00:23:49,110
+لايكول أسيتال وبعدين بيصير انه جديش الإنسان متدرب
+
+228
+00:23:49,110 --> 00:23:51,430
+يكتب ويطبق هذا الكلام
+
+229
+00:24:07,890 --> 00:24:14,030
+الآن هى فى عندنا سؤال تانى إيش المنطلق اللى عندنا
+
+230
+00:24:14,030 --> 00:24:17,970
+فيه أسد كلورايد أسد كلورايد بتكون تتذكروا كيمية
+
+231
+00:24:17,970 --> 00:24:24,910
+الأسد كلورايد أسد كلورايد مع كحول أستر أستر كل إشي
+
+232
+00:24:24,910 --> 00:24:29,610
+بخليه زى ما هو و بحطها نقوه أسلف أستر ممتاز أسد
+
+233
+00:24:29,610 --> 00:24:36,730
+كلورايد مع أمين أمد أمد unatched
+
+234
+00:24:36,730 --> 00:24:46,530
+twoالان acid chloride مع Greenyard reagent تير
+
+235
+00:24:46,530 --> 00:24:52,510
+تشيري ألكول هاي ال C هادي هادي هادي بتصير OH يجيني
+
+236
+00:24:54,100 --> 00:24:58,100
+مجمعتين فنل على مرتين هيتفاعل أول اشي بيعطيني ال
+
+237
+00:24:58,100 --> 00:25:01,800
+ketone أول ما تاجم الفنل هنا محل ال CL بيعطيني ال
+
+238
+00:25:01,800 --> 00:25:06,480
+ketone و بكمل ل tertiary alcohol أخدنا ال Easter و
+
+239
+00:25:06,480 --> 00:25:10,580
+ال acid chloride مع Greenyard شو بيعطوني؟ tertiary
+
+240
+00:25:10,580 --> 00:25:16,200
+alcohol و بال reduction؟ primary alcohol الان
+
+241
+00:25:21,250 --> 00:25:25,850
+هذا الـ Acid chloride مع Sodium Benzoyate بدنا
+
+242
+00:25:25,850 --> 00:25:31,190
+واحدة شاطرة تقولنا كيف شكل Sodium Benzoyate فنل C
+
+243
+00:25:31,190 --> 00:25:38,410
+double bond O O minus N A plus لاحظوا هنا لما قلت
+
+244
+00:25:38,410 --> 00:25:44,730
+O minus و هذا Acid chloride صار تحضير ايش الـ
+
+245
+00:25:44,730 --> 00:25:49,930
+Unsymmetrical anhydride ان هذه تهاجمهاهذا
+
+246
+00:25:49,930 --> 00:25:55,350
+نيوكليوفايل يترد الـCl إيه هاجمانه يترد الـCl
+
+247
+00:25:55,350 --> 00:25:58,810
+عشانك هيصير هذا تحضير الـ Unsymmetrical Unhydrate
+
+248
+00:25:58,810 --> 00:26:05,670
+هاي هذا الجزء والجزء التاني O C double bond O
+
+249
+00:26:05,670 --> 00:26:11,170
+Phenyl فعلا هذا Unhydrate ولا لأ؟ C double bond O
+
+250
+00:26:11,170 --> 00:26:18,440
+O C double bond O Unhydrate هاي احناأخدنا أربع
+
+251
+00:26:18,440 --> 00:26:22,780
+تفاعلات للـ Acid Chloride باختصار Acid Chloride مع
+
+252
+00:26:22,780 --> 00:26:27,300
+كحول Easter Acid Chloride مع أمونيا Amid Acid
+
+253
+00:26:27,300 --> 00:26:31,000
+Chloride مع Greenyard Tertiary Alcohol Acid
+
+254
+00:26:31,000 --> 00:26:37,160
+Chloride مع أنيون Unhydrate Unsymmetrical
+
+255
+00:26:37,160 --> 00:26:40,020
+Unhydrate طريقة تحضير الـ Unsymmetrical Unhydrate
+
+256
+00:26:40,020 --> 00:26:44,560
+الأن دول خلصناهم صار في عندي Easter بدي أخد لل
+
+257
+00:26:44,560 --> 00:26:49,240
+Easter كام تفاعل؟تفاعلين وصار في اندي أمد بتاخد
+
+258
+00:26:49,240 --> 00:26:53,420
+للأمد كام تفاعل؟ تفاعلين هو احنا كل اللي اتعلمناهم
+
+259
+00:26:53,420 --> 00:27:01,100
+للأمد كام تفاعل؟ يا هيدروليسز يعني هذا يصير acid
+
+260
+00:27:01,100 --> 00:27:13,240
+بهذا الشكل يا اما reduction ان هذا يصير CH2
+
+261
+00:27:14,120 --> 00:27:22,280
+ان اتش امد امد امد امد امد امد امد امد امد امد امد
+
+262
+00:27:22,280 --> 00:27:25,100
+امد امد امد امد امد امد امد امد امد امد امد امد
+
+263
+00:27:25,100 --> 00:27:25,980
+امد امد امد امد امد امد امد امد امد امد امد امد
+
+264
+00:27:25,980 --> 00:27:30,000
+امد امد امد امد امد امد امد امد امد امد امد امد
+
+265
+00:27:30,000 --> 00:27:31,420
+امد امد امد امد امد امد امد امد امد امد امد امد
+
+266
+00:27:31,420 --> 00:27:31,460
+امد امد امد امد امد امد امد امد امد امد امد امد
+
+267
+00:27:31,460 --> 00:27:39,960
+امد امد ا
+
+268
+00:27:43,000 --> 00:27:47,720
+الإيستار بالريدكشن الاسد الكلورايد والإيستار
+
+269
+00:27:47,720 --> 00:27:51,240
+بالريدكشن شو بيصيروا ال primary alcohol يعني هذه
+
+270
+00:27:51,240 --> 00:27:56,400
+بيصير CH2OH
+
+271
+00:27:56,400 --> 00:28:04,700
+والجزء هذا نفسه طيب الإيستار مع الهيدرازين يمكن
+
+272
+00:28:04,700 --> 00:28:10,790
+مامرش عليكم هذا التفاعلكتفاعل خاص لكن لما تقولوا
+
+273
+00:28:10,790 --> 00:28:16,190
+الهيدرازين نيوكليوفايل شو بده يعمل؟ بده يهاجم هنا
+
+274
+00:28:16,190 --> 00:28:22,410
+و يطرد ال O-ethyl، حطوا الناتج بهذا الشكل، إذا
+
+275
+00:28:22,410 --> 00:28:30,510
+حاسين عندكم؟ C double bond O وهنا إيش بده يصير؟ NH
+
+276
+00:28:30,510 --> 00:28:35,630
+NH2 هيدرازايد
+
+277
+00:28:35,630 --> 00:28:42,800
+بيسموهزي تفاعل الأمد، زي لو كنتوا بفعلينه مع ناتشي
+
+278
+00:28:42,800 --> 00:28:48,460
+ثري، مش كان تيجي ناتشي ثري تحل محل هادى، واضح؟ نفس
+
+279
+00:28:48,460 --> 00:28:53,900
+الفكرة تماما،
+
+280
+00:28:53,900 --> 00:28:54,620
+واضحة؟
+
+281
+00:29:13,900 --> 00:29:19,260
+لاحظوا بسؤال بسيط راجعنا كام كيميا ال acid halides
+
+282
+00:29:19,260 --> 00:29:25,720
+و ال e stars و ال amides و ال acids هذا
+
+283
+00:29:25,720 --> 00:29:34,430
+الجزء في عندكممجموعة النيترو ومجموعة ال سيانو على
+
+284
+00:29:34,430 --> 00:29:43,070
+بنزين الان النيترو بال reduction شو بتصير ان
+
+285
+00:29:43,070 --> 00:29:47,670
+اتشتو ان اتشتو امين مشقول ان هذه طريقة تحضير
+
+286
+00:29:47,670 --> 00:29:53,970
+الانيلين يعني هذه تصير ان اتشتو هنا سيان
+
+287
+00:29:56,170 --> 00:30:02,250
+Reduction بيشتغل الـ Nitro تصير NH2 الآن السيانو
+
+288
+00:30:02,250 --> 00:30:06,470
+أخدنا بالهيدروليسيز في تحضير الأحمار، شو بتصير؟
+
+289
+00:30:06,470 --> 00:30:12,030
+أسد، أذن هنا، بدي أسيبني من الـNitro زي ما هي،
+
+290
+00:30:12,030 --> 00:30:20,810
+وهذه إيش تصير؟ C double bond O تفاعل
+
+291
+00:30:20,810 --> 00:30:26,980
+السيانو لأسد، مر معنا ولا لأ؟وتفاعل الـ Nitro هي
+
+292
+00:30:26,980 --> 00:30:32,060
+مصدر الانيلين مرمعنا ولا لأ افتح دي للأمين؟ بس هم
+
+293
+00:30:32,060 --> 00:30:38,640
+راحون دخلوش في بعض في هنا الـNa الـO2 بتحولها إلى
+
+294
+00:30:38,640 --> 00:30:45,260
+الـOX اه هنا اول فكرة الـH2 بهمش انتبع شوية الـH2
+
+295
+00:30:45,260 --> 00:30:49,640
+مع البلاتينام بيعطيني الانيلين الآن اذا بعد هيك
+
+296
+00:30:49,640 --> 00:30:54,880
+فعلناها مع Sodium Nitrite وH3O Plus بيصير ايش؟
+
+297
+00:30:55,940 --> 00:31:00,660
+الفينول مر علينا طريقة تحضير الفينول يعني أنا كان
+
+298
+00:31:00,660 --> 00:31:06,060
+جوابي بس للجزء الأول إذا بعدك فعلته مع الصوديوم
+
+299
+00:31:06,060 --> 00:31:08,640
+نايترايت حامل دايزونيوم سولت ماعدش three of plus
+
+300
+00:31:08,640 --> 00:31:15,280
+بصير فينول يعني لو أجينا بس لحدها أنيلين
+
+301
+00:31:15,280 --> 00:31:22,520
+لو كملناالانهيلين بنحوله إلى فينول حسب ما يجي
+
+302
+00:31:22,520 --> 00:31:25,980
+السؤال يعني لحد ال reduction انهيلين زدنا عن ال
+
+303
+00:31:25,980 --> 00:31:33,480
+reduction فينول ممتازة
+
+304
+00:31:33,480 --> 00:31:34,020
+الان
+
+305
+00:31:45,510 --> 00:31:50,110
+جينا سؤال كيف بدنا نحضر ال Acetic Acid بتعرفوا ال
+
+306
+00:31:50,110 --> 00:31:56,750
+Acetic Acid؟ CH3COOH
+
+307
+00:31:56,750 --> 00:32:02,870
+من إيش بدنا نحضره؟ من التوبيوتانون واحد اتنين هاي
+
+308
+00:32:02,870 --> 00:32:07,530
+توبيوتانون طبعا
+
+309
+00:32:07,530 --> 00:32:14,580
+الكلام يبدوشوية غريب جدا لكن لو اي حد بيفكر شوية
+
+310
+00:32:14,580 --> 00:32:20,720
+بعمق بيفكر شوية بعمق ال acetic acid كاربونتين وال
+
+311
+00:32:20,720 --> 00:32:30,460
+two-butanone اربعة يعني الأربعة لو كسروا لو كسروا
+
+312
+00:32:30,460 --> 00:32:34,360
+بيصيروا اتنين و اتنين اذا انا لو كنت بدي اجي برجوع
+
+313
+00:32:34,360 --> 00:32:36,540
+من ورا هذا ايش ممكن يكون
+
+314
+00:32:39,320 --> 00:32:47,400
+الالكين هذا نمرة واحد O3 نمرة اتنين H2O2 كان
+
+315
+00:32:47,400 --> 00:32:53,300
+بيعطيني زي هيك ولا لأ؟
+
+316
+00:32:53,300 --> 00:32:58,660
+أنا كملت بالأكسدة الإضافية أوزون وبعدين أكسدة
+
+317
+00:32:58,660 --> 00:33:07,580
+بيصير حامض أوزون وبعدين أكسدة بيصير حامضواضح؟ الآن
+
+318
+00:33:07,580 --> 00:33:13,140
+هذا من إيش ممكن ييجي؟ من كحول يعني خلّينا هيك
+
+319
+00:33:13,140 --> 00:33:19,540
+نتخيل هي OH الآن أنا ماعنديش كحول عشان أعمل حدث
+
+320
+00:33:19,540 --> 00:33:24,380
+باستعمال ال KOH بيعطينا Alkene بس أنا ماعنديش كحول
+
+321
+00:33:24,380 --> 00:33:33,360
+أنا عنده Ketone ال Ketone يختزل آه
+
+322
+00:33:33,960 --> 00:33:41,740
+اذا كيتون كحول الكين و اوزونوليس اتبع اكسيداشيا او
+
+323
+00:33:41,740 --> 00:33:46,960
+ممكن تستعمل كمان او فور برضه اتش بلس بتعمل نفس
+
+324
+00:33:46,960 --> 00:33:52,700
+الشي واضح هذا في طريقة تحضير الأحمار لما قولنا كيف
+
+325
+00:33:52,700 --> 00:33:57,200
+بنكسر ال double bond او ال triple bond كمان ممكن
+
+326
+00:33:57,200 --> 00:34:00,700
+نكسرها و اش تعطينا حامض
+
+327
+00:34:02,030 --> 00:34:06,050
+طبعا لأن هنا في عندي H وهنا H أول ما بيكسر زي ما
+
+328
+00:34:06,050 --> 00:34:09,470
+حكت زميلتكوا فعلا ل 12-dihydes ال 12-dihydes
+
+329
+00:34:09,470 --> 00:34:17,010
+بتأكسدوا لإيش لacetic acid 12-dihydes بتأكسدوا
+
+330
+00:34:17,010 --> 00:34:24,610
+لacetic acid أخر
+
+331
+00:34:24,610 --> 00:34:29,770
+سؤال كان draw the structure of the peptide alanine
+
+332
+00:34:29,770 --> 00:34:35,490
+cysteineالان بدي قلانين الستين هو ال بيبتايد ايش
+
+333
+00:34:35,490 --> 00:34:44,710
+NCCO وكمان NCCO الان هاي بيبتايد من شغلتين
+
+334
+00:34:44,710 --> 00:34:49,910
+القلانين شو المجموعة اللي هنا CH3 وهي ال amino
+
+335
+00:34:49,910 --> 00:34:55,650
+terminal وهنا بدو يكون عندكم NH الستين شو المجموعة
+
+336
+00:34:55,650 --> 00:34:59,930
+CH2SH
+
+337
+00:34:59,930 --> 00:35:05,970
+وهنا بدو يكونالـ Acid Terminal فلاحظوا الـ peptide
+
+338
+00:35:05,970 --> 00:35:10,190
+لما بدي أرسم بدي أبدأ بالهيكل تبعه N C C double
+
+339
+00:35:10,190 --> 00:35:14,770
+bond O و N C C double bond O الآن إذا بحكي عن
+
+340
+00:35:14,770 --> 00:35:22,150
+الانين بدي أحط مثل بحكي عن سيستين بدي أحط CH2SH
+
+341
+00:35:23,240 --> 00:35:26,540
+واضح الفكرة؟ هى صار عند ال بيبتايد و amino
+
+342
+00:35:26,540 --> 00:35:32,260
+terminal و acid terminal الآن بدنا نيجي بعد هيك
+
+343
+00:35:32,260 --> 00:35:40,180
+نقول هذا ال بيبتايد خلينا نفعله مع ال methanol و H
+
+344
+00:35:40,180 --> 00:35:44,220
+plus لاحظوا
+
+345
+00:35:44,220 --> 00:35:49,980
+ال بيبتايد إله acid terminal ولا لأ؟ acid .. acid
+
+346
+00:35:49,980 --> 00:35:51,320
+زاد alcohol
+
+347
+00:35:53,810 --> 00:35:59,050
+أسد زائد ألكوهول إيستر إذا أنا بدي أجيب كل هذا
+
+348
+00:35:59,050 --> 00:36:02,970
+بلاش نقعد نوضح فيه و نقول C double bond O و من
+
+349
+00:36:02,970 --> 00:36:09,110
+الميثانول شو هيحط اوميثيل كل ال بيبتايد زي ما هو
+
+350
+00:36:09,110 --> 00:36:12,530
+كاملة C double bond O اوميثيل
+
+351
+00:36:18,040 --> 00:36:22,160
+الان ال بيبتايد مع ال two four داينيترو فلورو
+
+352
+00:36:22,160 --> 00:36:29,680
+بنزين هذا اللي أخدناه وسمناه ايش floor zanger
+
+353
+00:36:29,680 --> 00:36:39,340
+method وان او اتو وان اتو ايش بيعمل بالتحت مكان ال
+
+354
+00:36:39,340 --> 00:36:45,360
+floor اذا انا هيكون عندى ان اتش و ال بيبتايد كله و
+
+355
+00:36:45,360 --> 00:36:56,410
+بعدين هنابنزينة بنيترو و نيترو كل ال بيبتايد يتحد
+
+356
+00:36:56,410 --> 00:37:05,110
+من عند ال N الان
+
+357
+00:37:05,110 --> 00:37:12,030
+لو اجينا فعلنا هذا مع ال etheracetate OH- ال
+
+358
+00:37:12,030 --> 00:37:19,040
+etheracetate يستر بنقدر نرسمهCH3C double bond O O
+
+359
+00:37:19,040 --> 00:37:26,040
+-ethyl ايش اللي بنتوقع ميثل بيبتايد موجود ال amino
+
+360
+00:37:26,040 --> 00:37:33,640
+group النيكليوفايل وين ممكن يتهاجم تطرد
+
+361
+00:37:33,640 --> 00:37:41,160
+ال O-ethyl اذا هيكون الناتج اللي عندى ال N-H مع كل
+
+362
+00:37:41,160 --> 00:37:50,600
+ال بيبتايد و ايش هيحط عندى هناC double bond O CH3
+
+363
+00:37:50,600 --> 00:37:56,320
+الأمين
+
+364
+00:37:56,320 --> 00:38:00,080
+بتفاعل مع ال Easter مش الأسد بتفاعل مع ال Easter
+
+365
+00:38:00,080 --> 00:38:11,130
+أمين زائد Easter أمد أمين زائد Easterامد مش هذه
+
+366
+00:38:11,130 --> 00:38:18,410
+المعادلة العامة هذي امين وهذا اي ستار امين زائد اي
+
+367
+00:38:18,410 --> 00:38:28,950
+ستار بيعطينا ايش امد الان طب ال HCL بدو يتحلل اه
+
+368
+00:38:28,950 --> 00:38:32,930
+بالاساس مش بنعمل هيدرونيسز احنا لل بيبتايدز يعني
+
+369
+00:38:32,930 --> 00:38:43,130
+بدو يعطينا NH CHC double bond O OHزائد طبعا nh2
+
+370
+00:38:43,130 --> 00:38:50,470
+كمان nh2 CH16 CH2SH مشغولا بيعملوا hydrolysis ال
+
+371
+00:38:50,470 --> 00:38:58,230
+peptides واضح؟ hydrolysis peptide hydrolysis بدو
+
+372
+00:38:58,230 --> 00:39:02,530
+يتكسر ضايق الاشياء؟
+
+373
+00:39:22,160 --> 00:39:25,980
+نشوف الامتحان التاني حاولوا تشوفون اللي بدوبوها لو
+
+374
+00:39:25,980 --> 00:39:26,600
+سمحتوا
+
+375
+00:39:55,080 --> 00:40:10,380
+هذا الامتحان التاني اللي عندكم بمش
+
+376
+00:40:10,380 --> 00:40:15,860
+نمشي فيه أسرع شوية نمشي
+
+377
+00:40:15,860 --> 00:40:20,280
+فيه أسرع شوية يعني الحل بدون شرح و بتقلق الآن ال
+
+378
+00:40:20,280 --> 00:40:23,220
+carboxylic acids نكبر هذه بس
+
+379
+00:40:27,990 --> 00:40:32,070
+خلّيكم معايا Carboxylic acids react with aniline
+
+380
+00:40:32,070 --> 00:40:36,070
+producing amides حمض زائد أمين أمد هذي الجملة صح
+
+381
+00:40:36,070 --> 00:40:43,210
+اجليسرال ترايستيريت is a simple triglyceride صح
+
+382
+00:40:45,730 --> 00:40:50,250
+A large percentage of unsaturated acids غلط of
+
+383
+00:40:50,250 --> 00:40:54,630
+saturated reaction of hemacetals with alcohol is a
+
+384
+00:40:54,630 --> 00:40:58,290
+substitution reaction Hemacetal مع الالكول
+
+385
+00:40:58,290 --> 00:41:02,870
+substitution صحيحة Ibomars are enantiomars that
+
+386
+00:41:02,870 --> 00:41:06,230
+differ only in one chiral center لأ ال Ibomars are
+
+387
+00:41:06,230 --> 00:41:10,600
+diastereomarsالغلط إيجا من كلمة enantiomers الـ
+
+388
+00:41:10,600 --> 00:41:16,360
+epimers are the stereomers ال acid halides are
+
+389
+00:41:16,360 --> 00:41:22,450
+reduced to primary alcohols صح؟Aniline can be
+
+390
+00:41:22,450 --> 00:41:25,770
+prepared from the reaction of benzene with ammonia
+
+391
+00:41:25,770 --> 00:41:29,910
+هذا قلنا لأ من ال nitrobenzene بنحضر ال aniline
+
+392
+00:41:29,910 --> 00:41:34,290
+متذكرين؟ ال aniline من إيش بنحضره؟ Nitrobenzene
+
+393
+00:41:34,290 --> 00:41:37,790
+heating acidic acid with benzoic acid in presence
+
+394
+00:41:37,790 --> 00:41:42,570
+of H plus produces three possible products اللي هي
+
+395
+00:41:42,570 --> 00:41:45,750
+ال anhydrides مش four possible anhydrides، three
+
+396
+00:41:45,750 --> 00:41:57,500
+هذا بالنسبة لجزءالصح والغلط الآن
+
+397
+00
+
+445
+00:47:09,280 --> 00:47:13,420
+سم المركبات التالية هذا إيش مجموعته الوظيفية إيه
+
+446
+00:47:13,420 --> 00:47:19,180
+إيه استر إذا لازم أحط في الأول إثل و في الآخر واحد
+
+447
+00:47:19,180 --> 00:47:28,360
+اتنين تلاتة أربعة خمسة بنتين و ويت ال E وين موقعها
+
+448
+00:47:28,360 --> 00:47:34,700
+إثل توبنتين و ويت إيش ده الحامل هذا المركب four
+
+449
+00:47:34,700 --> 00:47:35,120
+hydroxy
+
+450
+00:47:37,970 --> 00:47:44,350
+اذا هذا صار اثل فور هيدروكسي توبنتينويت اثل فور
+
+451
+00:47:44,350 --> 00:47:51,350
+هيدروكسي توبنتينويت واضح؟ نسمي اخر اتنين ونخلص بعد
+
+452
+00:47:51,350 --> 00:47:56,750
+عشر ثواني هذا المركب اللي شايفينه عبارة عن ايش؟
+
+453
+00:47:56,750 --> 00:48:03,810
+كيتون واحد اتنين تلاتة أربعة خمسة ستة اذا هذا
+
+454
+00:48:03,810 --> 00:48:10,520
+عبارة عن threeهكسانون شو بيحمل ال three hexanone
+
+455
+00:48:10,520 --> 00:48:17,940
+مثل و دايمثل بيحط مواقعهم يعني two مثل و six
+
+456
+00:48:17,940 --> 00:48:23,020
+daimethylamino هذي إيش اسمها الآن مثل مثل six
+
+457
+00:48:23,020 --> 00:48:28,140
+daimethylamino المركب الأخير هذا مر علينا في ال
+
+458
+00:48:28,140 --> 00:48:36,240
+unhydrate افتلك unhydrate
+
+459
+00:48:37,520 --> 00:48:42,140
+على اي حال بيكفي لهذا الجزء الباقي عبارة عن
+
+460
+00:48:42,140 --> 00:48:46,860
+معادلات شبيهة بالامثلة التانية، بننهي الآن و
+
+461
+00:48:46,860 --> 00:48:48,720
+بنتمنى لكم التوفيق
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..923a15123444b2c8f031deafe7bfd3ce1eb1b3c9
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_postprocess.srt
@@ -0,0 +1,1892 @@
+1
+00:00:21,450 --> 00:00:26,690
+بسم الله الرحمن الرحيم طبعا سعاداء ان احنا نلتقي
+
+2
+00:00:26,690 --> 00:00:31,710
+فيكم في المحاضرة الأولى في هذا المساق هذا مساق
+
+3
+00:00:31,710 --> 00:00:38,510
+كيميا عضوية أو كيميا عضوية و حيوية يدرس عادةبأرقام
+
+4
+00:00:38,510 --> 00:00:43,510
+مختلفة في الجامعة لأكثر من تخصص يعني لطلبة العلوم
+
+5
+00:00:43,510 --> 00:00:49,690
+الصحية احنا بندرسه بالرقم Bioc 1301 لطلبة كلية
+
+6
+00:00:49,690 --> 00:00:55,770
+الطب بندرسه بالرقم Medic 1310 ولطلبة العلوم
+
+7
+00:00:55,770 --> 00:00:59,390
+الحياتية البيولوجيا والبيئة وما إلى ذلك برضه
+
+8
+00:00:59,390 --> 00:01:07,060
+بندرسه برقم Chem 2311 فكل هؤلاء الطلبةبنشاء الله
+
+9
+00:01:07,060 --> 00:01:10,700
+بيستطيعوا أنهم يستفيدوا من هذا المساق و اللي يعني
+
+10
+00:01:10,700 --> 00:01:15,900
+ان شاء الله سيكون مسجل حتى يعني يمكنكم تدارك أي
+
+11
+00:01:15,900 --> 00:01:19,760
+معلومات نقصت عليكم أثناء يعني سماع المحاضرة
+
+12
+00:01:19,760 --> 00:01:24,960
+الأصلية، مسموح طبعا أنه يكون في نقاش علمي هادق و
+
+13
+00:01:24,960 --> 00:01:29,280
+بيظهر في التصويرانتوا كلكم كمان واضحين أمام
+
+14
+00:01:29,280 --> 00:01:35,120
+الكاميرات ومناقشاتكوا هتكون يعني مثرية لتدريس هذا
+
+15
+00:01:35,120 --> 00:01:40,020
+المسابق ان شاء الله الكتاب
+
+16
+00:01:40,020 --> 00:01:45,600
+المقرر هو كتاب مشهور جدا في مجاله كتاب organic
+
+17
+00:01:45,600 --> 00:01:50,540
+chemistry للمؤلف heart and heart هذا الكتاب طبعا
+
+18
+00:01:50,540 --> 00:01:55,700
+مع المحتويات الإلكترونية كلها موفرة لكم ان شاء
+
+19
+00:01:55,700 --> 00:02:01,560
+اللهالجزء الأول من المساقى اللى هندرسه مقدمة في
+
+20
+00:02:01,560 --> 00:02:06,220
+الكيمياء العضوية بنتعرف جيد على المجموعات الوظيفية
+
+21
+00:02:06,220 --> 00:02:10,420
+على أنواع المركبات العضوية هذه المقدمة في الكيمياء
+
+22
+00:02:10,420 --> 00:02:16,400
+العضوية حوالى 11 فاصل لما تصير موجودة عندنا بشكل
+
+23
+00:02:16,400 --> 00:02:21,960
+جيد بصير بإمكاننا أنه نعطي بعدها مقدمة في الكيمياء
+
+24
+00:02:21,960 --> 00:02:28,080
+الحيوية باربع فصولان شاء الله بهيك بيكون يعني ال
+
+25
+00:02:28,080 --> 00:02:32,660
+course اكتملت مكوناته مقدمة في الكيمياع العضوية و
+
+26
+00:02:32,660 --> 00:02:36,220
+بعد هيك الجزء الثاني من ال course مقدمة في
+
+27
+00:02:36,220 --> 00:02:43,110
+الكيمياع الحيويةطبعا بدنا نبدأ مباشرة مابضيقش وقت
+
+28
+00:02:43,110 --> 00:02:47,830
+الفصل الأول في المقدمة في الكيمياء الأضوية مفاهيم
+
+29
+00:02:47,830 --> 00:02:51,750
+عامة بالذات أنه يعني أنتوا أخدتوا شغلتين أخدتوا
+
+30
+00:02:51,750 --> 00:02:56,730
+كيمياء عامة في الجامعة و أخدتوا أشياء مختلفة من
+
+31
+00:02:56,730 --> 00:03:02,090
+الكيمياء في المدارس بعضها أحيانا أو جزء خفيف في
+
+32
+00:03:02,090 --> 00:03:06,830
+الكيمياء الأضويةهذه الاساسية المبادئ الأساسية
+
+33
+00:03:06,830 --> 00:03:11,710
+بتساعدكم في انكم تتعاملوا مع مساق الكيميا الأضوية
+
+34
+00:03:11,710 --> 00:03:19,130
+هذا الفصل اللي في المقدمة هنتكلم فيه عن الارتباط
+
+35
+00:03:19,130 --> 00:03:22,990
+والتشكل bonding and isomerism يعني طالما انه احنا
+
+36
+00:03:22,990 --> 00:03:28,650
+بنحكي عن مركبات في الكيميا الأضوية اكيد ذرات معينة
+
+37
+00:03:28,650 --> 00:03:34,950
+هترتبط تعطيمركب bonding الان هذه الذرات اللى
+
+38
+00:03:34,950 --> 00:03:40,550
+بترتبط يمكن ان ترتبط بطرق مختلفة وبالتالي يمكن ان
+
+39
+00:03:40,550 --> 00:03:46,910
+تعطي اكثر من مركب اكثر من شكل او متشكل تماما زى ما
+
+40
+00:03:46,910 --> 00:03:51,360
+انا هتعامل مع هذه الاقلامهنا بقدر اعمل ارتباط
+
+41
+00:03:51,360 --> 00:03:54,920
+بينهم كإني عملت مُركّب يعني لو تخيلتوا ان هدولة
+
+42
+00:03:54,920 --> 00:03:58,840
+تلت ذرات مثلا Carbon, Hydrogen, Oxygen عملوا
+
+43
+00:03:58,840 --> 00:04:03,820
+مُركّب بطريقة معينة الآن لو غيرت ترتيب هدول الذرات
+
+44
+00:04:04,600 --> 00:04:10,560
+بكون عملت بكون عملت مركب تاني واضح لو غيرت هدول
+
+45
+00:04:10,560 --> 00:04:14,760
+الذرات بكون عملت مركب تاني الآن المركب الأول و
+
+46
+00:04:14,760 --> 00:04:19,540
+المركب الثاني ما العلاقة بينهم هدول المركبين
+
+47
+00:04:19,540 --> 00:04:25,180
+بنسميهم ايش احنا isomers يعني لما بنقول المركب A و
+
+48
+00:04:25,180 --> 00:04:31,360
+المركب B they are isomers متشكلاتالآن الظاهرة كلها
+
+49
+00:04:31,360 --> 00:04:37,980
+إيش بنسميها isomerism، ظاهرة التشكل، و هنتعمق في
+
+50
+00:04:37,980 --> 00:04:43,280
+هذا الموضوع بالتأكيد أثناء دراستنا، نتعمق في هذا
+
+51
+00:04:43,280 --> 00:04:48,510
+الموضوع أثناءدراستنا الآن إذا بدنا نبدأ في موضوع
+
+52
+00:04:48,510 --> 00:04:53,950
+ال bonding طبعا مر عليكم أنواع الروابط مر عليكم
+
+53
+00:04:53,950 --> 00:04:57,770
+أنواع الروابط اللي بتكون في داخل الجزيئة ارجو
+
+54
+00:04:57,770 --> 00:05:01,390
+انكوا تنتبهوا اللي بقصده انا في ال bonding اللي
+
+55
+00:05:01,390 --> 00:05:06,270
+بقصده في ال bonding مش الروابط بين الجزيئات اللي
+
+56
+00:05:06,270 --> 00:05:11,070
+اسمها intermolecular forces لأ الروابط في داخل
+
+57
+00:05:11,070 --> 00:05:16,720
+الجزيئةالروابط في داخل الجزيئ يعني في روابط بين
+
+58
+00:05:16,720 --> 00:05:22,520
+الجزيئات مش هي المقصودة هنا يعني افترضوا مثلا جزيئ
+
+59
+00:05:22,520 --> 00:05:31,420
+الميّه H2O الان هذا جزيئ هذه جزيئ ميّه تاني HOO
+
+60
+00:05:33,470 --> 00:05:38,730
+الان هذه الروابط اللى فى داخل الجزئ هي اللى انا
+
+61
+00:05:38,730 --> 00:05:44,650
+بقصدها فى الكيميا بنعطيها اسم بنقول عنها intra
+
+62
+00:05:44,650 --> 00:05:49,650
+molecular bonds يعنى روابط within the molecule جوا
+
+63
+00:05:49,650 --> 00:05:54,030
+الجزئ يعنى هذه الروابط شو بيقول عنها intra
+
+64
+00:05:56,090 --> 00:06:01,750
+موليكيولار بوندي انترا يعني روابط جوه الجزيه الان
+
+65
+00:06:01,750 --> 00:06:04,550
+اذا اجيت بعد هيك بقول مثلا في عندى روابط
+
+66
+00:06:04,550 --> 00:06:09,620
+هيدروجينية بين ال اكسجون و الهيدروجينهذه روابط بين
+
+67
+00:06:09,620 --> 00:06:15,160
+الجزيئات Intermolecular forces فميزوا الكلمتين
+
+68
+00:06:15,160 --> 00:06:20,940
+Intramolecular اللي هي الروابط الأصلية القوية اللي
+
+69
+00:06:20,940 --> 00:06:25,720
+في داخل الجزيئ بينما الروابط بين الجزيئات between
+
+70
+00:06:25,720 --> 00:06:31,070
+molecules شو بسميها أنا؟Intermolecular forces
+
+71
+00:06:31,070 --> 00:06:37,790
+الأقوى نوع في الـ Intermolecular forces هذه قوته
+
+72
+00:06:37,790 --> 00:06:42,230
+مابتيجيش خمسة لعشرة في المية من قوة هذه الروابط
+
+73
+00:06:42,230 --> 00:06:47,250
+بمعنى لو أنا بدي أكسر الروابط من اللي سهل أني
+
+74
+00:06:47,250 --> 00:06:53,210
+أكسره ال Intermolecular forces تماما زي ما نتخيل
+
+75
+00:06:53,210 --> 00:06:59,070
+اتنين بيجوا بيسلموا على بعضفي رابطة أصلية .. رابطة
+
+76
+00:06:59,070 --> 00:07:04,750
+هذا الكف مع الجسم .. هذي Intramolecular وفي رابطة
+
+77
+00:07:04,750 --> 00:07:08,010
+بين التنين اللي بيسلموا مع بعض .. هذي
+
+78
+00:07:08,010 --> 00:07:13,110
+Intermolecular الأن لو ولدين صغار سلموا مع بعض و
+
+79
+00:07:13,110 --> 00:07:16,550
+الام كل واحدة بدها تسحب ابنها و تمشي في طريقها ..
+
+80
+00:07:16,550 --> 00:07:22,030
+بيسحبوا الولد أن هي اللي بتنكسر .. هذي الرابطة ولا
+
+81
+00:07:22,030 --> 00:07:26,400
+هذي الرابطة؟هذه الرابطة الـ Intermolecular Forces
+
+82
+00:07:26,400 --> 00:07:29,500
+فالـ Intermolecular Forces اللي منها الـ London
+
+83
+00:07:29,500 --> 00:07:32,740
+Forces و الـ Dipole-Dipole Attractions و الـ
+
+84
+00:07:32,740 --> 00:07:37,780
+Hydrogen Bonding هذه روابط ضعيفة بين الجزيئات
+
+85
+00:07:37,780 --> 00:07:41,500
+بتأثر بشكل كبير على الخواص الفيزيائية لكن لما انا
+
+86
+00:07:41,500 --> 00:07:46,600
+بدأ ادرس تفاعلات و اقول ان التفاعل الكيميائي بعد
+
+87
+00:07:46,600 --> 00:07:52,500
+شوية كسر وتكوين روابط انا لا اتكلم اطلاقا عن هذه
+
+88
+00:07:52,500 --> 00:07:57,340
+الروابطأنا بتكلم عن الروابط within the molecule
+
+89
+00:07:57,340 --> 00:08:02,640
+الـ Intramolecular forces و لما الآن بنصنف أنواع
+
+90
+00:08:02,640 --> 00:08:07,860
+هذه الروابط و بنحكي ionic bonds و covalent bonds و
+
+91
+00:08:07,860 --> 00:08:11,680
+coordinate covalent bonds بنكون بنحكي عن الروابط
+
+92
+00:08:11,680 --> 00:08:18,580
+اللي في جوة الجزء الـ Intramolecularواضح؟ اللي
+
+93
+00:08:18,580 --> 00:08:24,020
+بتكون الجزء نفسه الان من هذه الروابط زي ما سبق
+
+94
+00:08:24,020 --> 00:08:27,540
+انكم اتعلمتوا من هذه الروابط زي ما سبق انكم
+
+95
+00:08:27,540 --> 00:08:33,020
+اتعلمتوا ال ionic bonds ال ionic bonds بتنشأ لما
+
+96
+00:08:33,020 --> 00:08:37,680
+بيتكون عند أيونات في عناصر معينة عندها إلكترونات
+
+97
+00:08:37,680 --> 00:08:42,080
+زيادة عادة بتكون موجودة في أول الجدول الدوري على
+
+98
+00:08:42,080 --> 00:08:47,840
+اليساربنسميها electropositive atoms زي الصوديوم
+
+99
+00:08:47,840 --> 00:08:51,240
+على سبيل المثال وكلكوا عارفين تركيبه الإلكتروني
+
+100
+00:08:51,240 --> 00:08:57,780
+1s2 2s2 2b6 3s1 لإن عنده إلكتروني زيادة لو فقدوا
+
+101
+00:08:57,780 --> 00:09:02,600
+بيصل ال octet structure واضح لكن لما بيفقدوا هيصير
+
+102
+00:09:02,600 --> 00:09:08,580
+عبارة عن ايونموجة في عند ذرات بنقول عنها electro
+
+103
+00:09:08,580 --> 00:09:13,000
+negative atoms هدولة نقصهم إلكترون عشان يصلوا لل
+
+104
+00:09:13,000 --> 00:09:18,480
+octet structures هدولة لو اكتسبوا لو اكتسبوا هذا
+
+105
+00:09:18,480 --> 00:09:25,500
+الإلكترون بيصيروا ايوناتسالبة زي الكلور مثلا 1s2
+
+106
+00:09:25,500 --> 00:09:32,320
+2s2 2b6 بعدين بيصير عندي 3s2 3b5 هذا ال 3b5 ما زال
+
+107
+00:09:32,320 --> 00:09:37,660
+عنده وسع لإيش لإلكترون واحد لو اكتسب هذا الإلكترون
+
+108
+00:09:37,660 --> 00:09:42,890
+طبعا هيكتسب أي إلكترون اللي فقط الصوديومهيصير كلور
+
+109
+00:09:42,890 --> 00:09:47,990
+سالب اذا هنا صار في عندك صوديوم موجب و صار عندك
+
+110
+00:09:47,990 --> 00:09:51,490
+كلور سالب هدول ال ايونات لما بيعملوا ال attraction
+
+111
+00:09:51,490 --> 00:09:57,690
+مع بعض بيكونوا ليه ال ionic bond واضح طبعا ممكن
+
+112
+00:09:57,690 --> 00:10:02,250
+بعض العناصر اللي في المجموعة الثانية يفقدوا
+
+113
+00:10:02,250 --> 00:10:07,880
+إلكترونين و بيكونواIon موجب اتنين ممكن يفقدوا
+
+114
+00:10:07,880 --> 00:10:11,240
+تلاتة مثلا زي الالمنيون موجب تلاتة كل هذا الكلام
+
+115
+00:10:11,240 --> 00:10:16,360
+بتاعي اللي عرفته وكيف نكتب صيغة مركب ايوني هذا
+
+116
+00:10:16,360 --> 00:10:20,720
+الكلام كله بيمور وين عندنا في الكيمياء العامة
+
+117
+00:10:20,720 --> 00:10:29,460
+بالنسبة ل ال covalent compounds بيفرقوا بشغلة انه
+
+118
+00:10:30,790 --> 00:10:35,610
+الروابط اللي بتتكون تتكون نتيجة مشاركة في
+
+119
+00:10:35,610 --> 00:10:39,210
+الإلكترونات يعني هذه عندها إلكترونات معينة هذه
+
+120
+00:10:39,210 --> 00:10:43,990
+عندها إلكترونات بيعملوا sharing للإلكترون فكل ذرة
+
+121
+00:10:43,990 --> 00:10:48,370
+بتصل للتركيب اللي هو المستقر إذا كنا بنحكي عن
+
+122
+00:10:48,370 --> 00:10:51,710
+هيدروجين كل ذرة بتصير اتنين و اتنين زي مثلا ما
+
+123
+00:10:51,710 --> 00:10:56,330
+نتخيل هيدروجين فيه إلكترونهذا مش يبين وهيدروجين
+
+124
+00:10:56,330 --> 00:11:00,050
+فيه إلكترون هيعملوا جزء الهيدروجين كأنه الآن كل
+
+125
+00:11:00,050 --> 00:11:03,590
+ذرة هيدروجين عندها كام إلكترون اتنين هذا التركيب
+
+126
+00:11:03,590 --> 00:11:09,840
+ثابت أو الكلور مثلا مداره الأخيرفي سبع إلكترونات
+
+127
+00:11:09,840 --> 00:11:14,460
+الـ valence shell اللى موجود فيه الآن لما أنا بحكي
+
+128
+00:11:14,460 --> 00:11:18,940
+عن سبع إلكترونات لو صار مشاركة في هدول الإلكترونات
+
+129
+00:11:18,940 --> 00:11:23,780
+صارت كل ذرّة كلور كام إلكترون حولها تمانية إذا
+
+130
+00:11:23,780 --> 00:11:29,240
+عملنا covalent compound كذلك لو بدى أخد H مع CL
+
+131
+00:11:29,240 --> 00:11:36,830
+برضه الرابط أيش بتكون covalent bondالـ bonds هذه
+
+132
+00:11:36,830 --> 00:11:42,130
+الـ bonds هذه في إلها إشي بنسميه bond energy هذا
+
+133
+00:11:42,130 --> 00:11:47,530
+تعبير عن قوة الروابط ال bond energy هو الطاقة
+
+134
+00:11:47,530 --> 00:11:54,570
+اللازمة لكسر روابط واحد مول من الروابط الواحد مول
+
+135
+00:11:54,570 --> 00:11:59,410
+عرفينه عدد مضاعف عدد ال 26 من الف في عشر أقصى
+
+136
+00:11:59,410 --> 00:12:04,030
+تلاتة وعشرينالان عشان اكسر هذه الروابط .. هاي
+
+137
+00:12:04,030 --> 00:12:08,590
+رابطة .. لما اقول بدي اكسر الرابطة .. ايش بدي؟بدي
+
+138
+00:12:08,590 --> 00:12:14,870
+طاقة دايما معروف عندنا انه كسر الرابطة عملية بحاجة
+
+139
+00:12:14,870 --> 00:12:21,590
+الى طاقة بقول عنها endothermic process بينما تكوين
+
+140
+00:12:21,590 --> 00:12:26,810
+الرابطة عملية طاردة للطاقة بقول عنها exothermic
+
+141
+00:12:26,810 --> 00:12:31,930
+process فال bond energy هي الطاقة اللي لازم الكسر
+
+142
+00:12:31,930 --> 00:12:36,170
+روابط او واحد مول من الروابط من ال covalent bonds
+
+143
+00:12:36,170 --> 00:12:41,180
+كذلكفي عندى إيش اسمه ال bond length ال bond length
+
+144
+00:12:41,180 --> 00:12:48,660
+هو المسافة المتوسطة ما بين ذرتين ليش مسافة متوسطة
+
+145
+00:12:48,660 --> 00:12:54,420
+لأنه الرابطة هي عبارة عن مسافة بالفراغ ليست ثابتة
+
+146
+00:12:54,420 --> 00:12:58,260
+يعني ذرتين بينهم مسافة معينة في الفراغ بنقول هدول
+
+147
+00:12:58,260 --> 00:13:03,240
+الذرتين بينهم إيش رابطة الآن هذه المسافة تزيد
+
+148
+00:13:03,240 --> 00:13:08,500
+وتقصرليست ثابتة تماما و لذلك احنا بناخد المسافة
+
+149
+00:13:08,500 --> 00:13:12,000
+المتوسطة بيصير عندنا ال bond length الآن ال bond
+
+150
+00:13:12,000 --> 00:13:17,660
+length يقاس عادة بال angstrom اللي هو واحد في عشر
+
+151
+00:13:17,660 --> 00:13:22,300
+أقص ناقص عشرة من المتر او بنقيسه في ال picometer
+
+152
+00:13:22,300 --> 00:13:28,140
+اللي هو واحد في عشر أقص ناقص اتنائش من المتر واضح
+
+153
+00:13:28,140 --> 00:13:34,010
+طبعا لما انقيس ال bond lengthبال بيكميتر هتطلع
+
+154
+00:13:34,010 --> 00:13:39,330
+أطوال الروابط عندنا سهلة الملاحظة وسهلة الحفظ يعني
+
+155
+00:13:39,330 --> 00:13:44,630
+خليني أفرجيكم كيف هي أنا بعطيكم مقارنة بين الرابطة
+
+156
+00:13:44,630 --> 00:13:49,590
+الأحادية هذه الرابطة اللي أنا بقصدها الأحادية
+
+157
+00:13:49,590 --> 00:13:52,890
+والثنائية والرابطة
+
+158
+00:13:54,550 --> 00:14:01,830
+الثلاثية الان لاحظوا ان عدد الروابط بيزيد احدية
+
+159
+00:14:01,830 --> 00:14:07,970
+ثنائية ثلاثية هذا احنا بنسميه ال bond order ايش ال
+
+160
+00:14:07,970 --> 00:14:11,490
+bond order ال bond order is the number of chemical
+
+161
+00:14:11,490 --> 00:14:15,850
+bonds between a pair of atoms عدد الروابط ما بين
+
+162
+00:14:15,850 --> 00:14:22,270
+ذرتين هل يترى هدول الروابط منها ذرتين احديةثنائية
+
+163
+00:14:22,270 --> 00:14:28,490
+ثلاثية ايش بسمي انا ال bond order الان انتبهوا معي
+
+164
+00:14:28,490 --> 00:14:31,970
+as the bond order increases يعني كل ما بزيد من
+
+165
+00:14:31,970 --> 00:14:36,150
+الرابط احدية لا ثنائية لا ثلاثية بقول the bond
+
+166
+00:14:36,150 --> 00:14:43,810
+will be stronger and shorter بتصير اقوى و اقصر
+
+167
+00:14:43,810 --> 00:14:48,270
+ليش؟ لان الرابط الاحدية هي عبارة عن sigma bond
+
+168
+00:14:49,600 --> 00:14:56,440
+الرابطة الثلاثية هي عبارة عن سيجما و باي و لذلك
+
+169
+00:14:56,440 --> 00:14:57,900
+أصبحت أقوى
+
+170
+00:15:06,370 --> 00:15:10,150
+بتخيلوها الأيام بتصير سهلة الفهم، هذه sigma bond
+
+171
+00:15:10,150 --> 00:15:15,350
+فقط، هذه sigma و by bond، هذه sigma و by و by، مين
+
+172
+00:15:15,350 --> 00:15:20,730
+أكتر واحدة فيها قوة؟ الرابطة الثلاثية، هذا الكلام
+
+173
+00:15:20,730 --> 00:15:25,930
+بنعكس وين؟ بنعكس على أمركتير مهم في الكيميا قوة
+
+174
+00:15:25,930 --> 00:15:31,430
+الرابط لان الرابط الثلاثية قوية اللى هى هل يترى
+
+175
+00:15:31,430 --> 00:15:36,950
+يمكن ان يصير دوران حول الرابط ولا لأ ولذلك اذا
+
+176
+00:15:36,950 --> 00:15:41,950
+احنا بدنا نيجي نتخيل انه باستعمال ال models نتخيل
+
+177
+00:15:41,950 --> 00:15:49,350
+انه احنا باستعمال ال models بدنا نعملروابط معينة
+
+178
+00:15:49,350 --> 00:15:54,030
+نعمل رابطة أحادية هاي رابطة أحادية لو بتطلع علي
+
+179
+00:15:54,030 --> 00:15:59,270
+هدولة في عندى إمكانية للدوران حول الرابطة الأحادية
+
+180
+00:15:59,270 --> 00:16:03,990
+رابطة ضعيفة ممكن الأشياء اللى موجودة هنا يكون فيها
+
+181
+00:16:03,990 --> 00:16:10,710
+دوران الان لو خلتها رابطة ثنائية بهذا الشكل وجربت
+
+182
+00:16:10,710 --> 00:16:16,490
+أني بدي ألف بيصير عندى ال rotationRestricted
+
+183
+00:16:16,490 --> 00:16:28,370
+rotation رابطة
+
+184
+00:16:28,370 --> 00:16:36,390
+ضعيفة رابطة ثنائية Restricted
+
+185
+00:16:36,390 --> 00:16:42,650
+rotationيعني دوران ممنوع forbidden rotation الان
+
+186
+00:16:42,650 --> 00:16:51,790
+لو خلتها رابطة ثلاثية بدت تصير اقوى و اقوى اطلاقا
+
+187
+00:16:51,790 --> 00:16:57,150
+مش ممكن يصير فيه دوران حول الرابطة الثلاثية او
+
+188
+00:16:57,150 --> 00:17:01,690
+ثنائية صعب جدا واضح هى اللى احنا بدنا نستفيده ان
+
+189
+00:17:01,690 --> 00:17:07,690
+الرابطة كل ما البند order تبعها زاد بتصير ايش اقوى
+
+190
+00:17:08,210 --> 00:17:13,710
+وبنفس الوقت الرابطة القوية بتكون رابطة أكثر الذرات
+
+191
+00:17:13,710 --> 00:17:17,690
+بيصيروا جراب من بعض فلو احنا بدنا نشوف طول الرابطة
+
+192
+00:17:17,690 --> 00:17:23,190
+في ال بيكوميتر لاحظوا الرابطة الأحدية 154 بيكوميتر
+
+193
+00:17:23,190 --> 00:17:31,270
+لما بتصير ثنائية 134 بيكوميتر لما بتصير أحدية 121
+
+194
+00:17:31,270 --> 00:17:39,100
+بيكوميتر فمين أكثر رابطة الرابطةالتلافية واضحة هذه
+
+195
+00:17:39,100 --> 00:17:44,440
+النقطة فهذا الكلام بناخده كقاعدة as the bond order
+
+196
+00:17:44,440 --> 00:17:50,000
+increases the bond will be stronger and shorter
+
+197
+00:17:50,000 --> 00:17:53,120
+بتصير الرابطة أقوى وأقصى
+
+198
+00:17:56,880 --> 00:18:01,980
+الان احنا بنعمل روابط بين ذرات مختلفة لعناصر
+
+199
+00:18:01,980 --> 00:18:06,240
+مختلفة في الكيميا العضوية في الكيميا العضوية ربما
+
+200
+00:18:06,240 --> 00:18:11,140
+اهم العناصر اللى بيعملوا عندنا الروابط ال carbon و
+
+201
+00:18:11,140 --> 00:18:14,940
+ال hydrogen ال oxygen ال nitrogen و ال halogens
+
+202
+00:18:16,050 --> 00:18:20,890
+واضح؟ الان يا ترى كل عنصر من هدول العناصر كام
+
+203
+00:18:20,890 --> 00:18:25,810
+رابطة بيعمل عندنا لازم نكون عارفين و هذا الكلام
+
+204
+00:18:25,810 --> 00:18:29,210
+هتلاحظوا يعني لو فتحتوا كتاب الكيميا العضوية من
+
+205
+00:18:29,210 --> 00:18:35,190
+أول صفحة لآخر صفحة هتلاقوا ان الكربون بيعمل أربع
+
+206
+00:18:35,190 --> 00:18:42,350
+روابط مش هتلاقوا ولا مركب ولا مركب في الكربون بخمس
+
+207
+00:18:42,350 --> 00:18:49,240
+روابط واضح النقطة؟مافيش في كل علم الكيميا العضوية
+
+208
+00:18:49,240 --> 00:18:53,600
+على طوله و عرضه مش هتلاقيه مركب الكربون فيه بخمس
+
+209
+00:18:53,600 --> 00:18:56,880
+روابط أثناء التفاعل بيكون قاعد بفقد رابطة بيعمل
+
+210
+00:18:56,880 --> 00:19:01,420
+رابطة هذه حالات أثناء التفاعل بتكون ناشطة و بترجع
+
+211
+00:19:01,420 --> 00:19:05,620
+للإيش للاربع اللي بيدرسم شكل مركب بيدرسم الكربون
+
+212
+00:19:05,620 --> 00:19:12,310
+بكام رابطة؟ باربع الأن في ورقة الامتحانحدث ولا حرج
+
+213
+00:19:12,310 --> 00:19:16,810
+بتعملوا على ال carbon خمس روابط و ست روابط و عشر
+
+214
+00:19:16,810 --> 00:19:25,420
+روابط كله ايش؟كله غلط مش كله ماشي اربع روابط الآن
+
+215
+00:19:25,420 --> 00:19:29,820
+خلّينا نطلع على هذه العناصر الأساسية الهيدروجين
+
+216
+00:19:29,820 --> 00:19:35,340
+عادة بيعمل رابطة واحدة فقط الكاربون بيعمل اربع
+
+217
+00:19:35,340 --> 00:19:42,090
+روابط النيتروجين بيعمل تلت روابط وبيبقى عليهزوج من
+
+218
+00:19:42,090 --> 00:19:45,270
+الإلكترونات يعني بيظل على ال nitrogen غير التلات
+
+219
+00:19:45,270 --> 00:19:50,250
+روابط زوج من الإلكترونات ال oxygen مشهور بنقول عنه
+
+220
+00:19:50,250 --> 00:19:55,870
+بيعمل رابطتين و يبقى عليه زوجان من الإلكترونات ال
+
+221
+00:19:55,870 --> 00:19:59,510
+halogens اللي هي الفلور و الكلور و البروم و اليود
+
+222
+00:19:59,510 --> 00:20:03,330
+اللي هم المجموعة السابعة في الجدول الدوري هدولة
+
+223
+00:20:03,330 --> 00:20:07,890
+بيعملوا رابطة واحدة و بيبقى عليهم كام زوج من
+
+224
+00:20:07,890 --> 00:20:13,190
+الإلكتروناتثلاث أزواج، واضح؟ الآن هي أنا راسم
+
+225
+00:20:13,190 --> 00:20:20,730
+مركّب كبيرلو بتتطلع عليه، كل رأس في هذا المركب
+
+226
+00:20:20,730 --> 00:20:25,770
+يمثل ذرة كربون إذا لاقيتوا إشي ناقص في أعداد
+
+227
+00:20:25,770 --> 00:20:30,270
+الروابط، معناه ذلك هذا الشيء اللي ناقص هو عبارة عن
+
+228
+00:20:30,270 --> 00:20:34,910
+هيدروجين اختصر في الكتابة لأنه إحنا عندنا شيء
+
+229
+00:20:34,910 --> 00:20:38,530
+بنسميه abbreviated structure اللي هو شكل مختصر
+
+230
+00:20:38,530 --> 00:20:43,590
+يعني اللي بينفهم ضمنه مرات مابنكتبهشواضح؟ اللي
+
+231
+00:20:43,590 --> 00:20:47,930
+بينفهم ضمنها مرات مابنكتبوش فلاحظوا مثلا هاي ذرات
+
+232
+00:20:47,930 --> 00:20:53,830
+ال carbon هذه carbon هذه carbon carbon كل هذه
+
+233
+00:20:53,830 --> 00:20:59,630
+الذرات كل رأس هنا في الرسم يعتبر ذرة carbon و هاي
+
+234
+00:20:59,630 --> 00:21:04,470
+كمان carbon لو بنطلع عليهم كلهم كلهم عليهم أربع
+
+235
+00:21:04,470 --> 00:21:08,610
+روابط إذا في إشي مبين أقل معنا ذلك هذا فيه
+
+236
+00:21:08,610 --> 00:21:15,600
+هيدروجين اختصراكتابة يعني هذه CH3EC مبينين أربع
+
+237
+00:21:15,600 --> 00:21:19,720
+روابط هنا يمكن تطلع كربون متصلة بكربون و كربون إذا
+
+238
+00:21:19,720 --> 00:21:24,240
+ما المختصر هنا ذرتين هيدروجين بتكون تفهموهم يعني
+
+239
+00:21:24,240 --> 00:21:27,600
+لما نقول إقرأوا إيش فيه هنا بتقولوا هذه عبارة عن
+
+240
+00:21:27,600 --> 00:21:33,180
+CH2مختصر من hydrogen و hydrogen كتابة هذه من بين
+
+241
+00:21:33,180 --> 00:21:37,380
+أربع روابط هذه من بين أربعة هذه carbon رابطة تنتين
+
+242
+00:21:37,380 --> 00:21:41,480
+و تنتين مع ال oxygen سليمة ال oxygen كم رابطة
+
+243
+00:21:41,480 --> 00:21:48,000
+تنتين ال oxygen هنا بطريقة تانيةرابطتين بمعنى انه
+
+244
+00:21:48,000 --> 00:21:51,600
+ممكن يكونوا رابطة ثنائية في نهاية العدد تنتين او
+
+245
+00:21:51,600 --> 00:21:56,540
+رابطتين احديتين مافيش مشكلة كذلك مع ال carbon ممكن
+
+246
+00:21:56,540 --> 00:22:01,580
+يكونوا اربع روابط احدية ممكن يكون رابطة ثنائية و
+
+247
+00:22:01,580 --> 00:22:07,200
+رابطتين احديات ممكن تلت روابط يعني رابطة ثلاثية و
+
+248
+00:22:07,200 --> 00:22:10,360
+رابطة احدية المهم المجموع يكون في النهاية ايش
+
+249
+00:22:10,360 --> 00:22:13,900
+اربعة المهم المجموع يكون في النهاية اربعة لاحظوا
+
+250
+00:22:13,900 --> 00:22:19,500
+ال halogen هنارابطة واحدة بيكون أكيد عليه أزواج
+
+251
+00:22:19,500 --> 00:22:23,580
+إلكترونات لو كنا محتاجين إيه لفهم تفاعل بنكتبها مش
+
+252
+00:22:23,580 --> 00:22:28,240
+محتاجين عادة مابنكتبهاش يعني لو كنت بدي أكمل أزواج
+
+253
+00:22:28,240 --> 00:22:33,000
+الإلكترونات هنا أكيد ال oxygen عليه زوجين أكيد ال
+
+254
+00:22:33,000 --> 00:22:36,100
+nitrogen عليه زوج أكيد ال halogen عليه تلاتة
+
+255
+00:22:36,100 --> 00:22:42,740
+بالمناسبةبالنسبة لموضوع الروابط رسم الأشكال زي ما
+
+256
+00:22:42,740 --> 00:22:47,440
+هتلاحظوا ربما بعد two or three slides انه احنا
+
+257
+00:22:47,440 --> 00:22:54,900
+بنرسم الأشكال بأكثر من طريقة بمعنى ممكن احنا نرسم
+
+258
+00:22:54,900 --> 00:23:01,620
+شكل مركب بتفصيل كامل يعني نبيّن فيهكل ذرة من
+
+259
+00:23:01,620 --> 00:23:05,500
+الذرات ممكن نبين في المراكب كل ذرة من الذرات زي ما
+
+260
+00:23:05,500 --> 00:23:14,600
+احنا رسمين هنا CH3 CH2 CH2 OH هذا قواعد الروابط
+
+261
+00:23:14,600 --> 00:23:18,740
+كلها بتنطبق عليه سليم الان لو هذا كنت بدي اكتبه
+
+262
+00:23:18,740 --> 00:23:26,880
+بطريقة الكتابة العادية هاكتبهCH3 CH2 CH2 OH لو بدى
+
+263
+00:23:26,880 --> 00:23:32,540
+اختصره باستعمال برامج الرسم هارسمه بهذا الشكل واحد
+
+264
+00:23:32,540 --> 00:23:36,860
+اتنين تلاتة الان هدوله اش يفهموا كرر رأس يفهم
+
+265
+00:23:37,630 --> 00:23:44,750
+carbon كرر اس يفهم carbon فانا لو شفت هذا المركب و
+
+266
+00:23:44,750 --> 00:23:51,110
+قلت لطالب اقرأ هذا الشكل المفروض هي تقرأه CH3 CH2
+
+267
+00:23:51,110 --> 00:23:58,260
+CH2 OH او مثلا لو شفت مركب زي هذاكل رأس carbon
+
+268
+00:23:58,260 --> 00:24:03,060
+يعني كم carbon عندى في هذا المركب خمس ذرات carbon
+
+269
+00:24:03,060 --> 00:24:09,500
+فيقرأ CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+270
+00:24:09,500 --> 00:24:09,800
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+271
+00:24:09,800 --> 00:24:10,480
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+272
+00:24:10,480 --> 00:24:10,520
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+273
+00:24:10,520 --> 00:24:14,220
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+274
+00:24:14,220 --> 00:24:14,280
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+275
+00:24:14,280 --> 00:24:15,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+276
+00:24:15,020 --> 00:24:21,380
+CH2 CH2 CH2بدنا نكون متعودين على معرفة الصيغة
+
+277
+00:24:21,380 --> 00:24:27,240
+الجزائية للمراكبات و حسابها و الروابط المختصرة على
+
+278
+00:24:27,240 --> 00:24:33,120
+طول احنا بمخنا ايش نعمل نجيبها و نحطها خليني
+
+279
+00:24:33,120 --> 00:24:40,450
+اعطيكمخليني أعطيكم مثال إضافي أعطيكم مثال إضافي
+
+280
+00:24:40,450 --> 00:24:49,190
+يعني لو على السريع جربنا مثلا أنه نرسم جزئ زي هيك
+
+281
+00:24:49,190 --> 00:25:02,150
+و هذا الجزئ عملنا فيه ناخد
+
+282
+00:25:02,150 --> 00:25:03,990
+ثانية في الرسم مش مشكلة
+
+283
+00:25:25,060 --> 00:25:30,720
+الان يا تورا هى عندكم جزيق و خلينا نكبره عشان
+
+284
+00:25:30,720 --> 00:25:36,720
+انتوا كلكم تشوفوه لو سألنا هذا الجزيق اللى موجود
+
+285
+00:25:36,720 --> 00:25:41,380
+قدامكم ايش صيغته الجزيقية؟ ايش اللى مبينه؟ ايش
+
+286
+00:25:41,380 --> 00:25:46,250
+اللى مختصر فيه؟واحدة تقولنا إيه صيغته الجزائية،
+
+287
+00:25:46,250 --> 00:25:54,630
+يعني كام carbon يوجد عندى في هذا الجزء؟ carbon؟
+
+288
+00:25:54,630 --> 00:25:57,270
+كل رأس بالنسبة ليه carbon؟
+
+289
+00:26:00,180 --> 00:26:05,660
+هذا اللي هنا Carbon، إذاً هذا صيرته الجزائية C5،
+
+290
+00:26:05,660 --> 00:26:12,800
+الان الأصعب شوية كم هيدروجين عندى في هذا الجزء
+
+291
+00:26:16,380 --> 00:26:21,680
+كل شي بتكون تكمله حسب ما اتفقنا الكربون لأربع
+
+292
+00:26:21,680 --> 00:26:28,320
+روابط النيتروجين لثلاثة الأكسجل لرابطتين كل ما هو
+
+293
+00:26:28,320 --> 00:26:36,020
+محدوث عبارة عن هيدروجين يعني هنا موجود عندي
+
+294
+00:26:36,020 --> 00:26:43,670
+هيدروجين هنا هيدروجين هنا هيدروجين هناتنتين
+
+295
+00:26:43,670 --> 00:26:47,530
+هيدروجين هنا عشان يصير الكاربون أربع هذه
+
+296
+00:26:47,530 --> 00:26:52,010
+النيتروجين كام رابط مابين عليها تنتين تنتين اذا
+
+297
+00:26:52,010 --> 00:27:04,070
+ينقصها عشان تصير تلت روابط هذه كاربون عدوهم
+
+298
+00:27:04,070 --> 00:27:10,460
+واحد اتنينأنا أكيد بقول الناس اللي بيقولوا رقم
+
+299
+00:27:10,460 --> 00:27:15,700
+مفرد هم الكلام الصح و قدوا انتوا اربع ستة تمانية
+
+300
+00:27:15,700 --> 00:27:26,900
+عشرة احداشر اذا ن ا واضحهي عدد الروابط و بالمناسبة
+
+301
+00:27:26,900 --> 00:27:30,920
+برنامج الرسم بإمكانه يحسب إن الصيغة تبعت هذا
+
+302
+00:27:30,920 --> 00:27:34,780
+المركب يعني لو علمناه كيميستر كالكوليت موليكيلار
+
+303
+00:27:34,780 --> 00:27:39,460
+فاليوز و كالكوليت و قلنا له لزجلنا إياهم هاي
+
+304
+00:27:39,460 --> 00:27:46,920
+الصيغة إيش حسبها البرنامج اقرأوا C5H11NO
+
+305
+00:27:46,920 --> 00:27:52,010
+زي ما احنا كتبناها ولا لأ زي ما احنا كتبناهاواضح؟
+
+306
+00:27:52,010 --> 00:27:57,110
+فعندكم انتوا برنامج الرسم موجود بإمكانكوا ترسموا
+
+307
+00:27:57,110 --> 00:28:02,770
+جزيئات زي ما بدكم بإمكانكوا ترسموا جزيئات زي ما
+
+308
+00:28:02,770 --> 00:28:08,110
+بدكم والبرنامج بحسبها وبالتالي بتقدروا تراجعوا
+
+309
+00:28:08,110 --> 00:28:12,110
+لنفسكم يعني حتى لو اجت طالبة قالت انا بدي بدل ما
+
+310
+00:28:12,110 --> 00:28:16,690
+هذه هيدروجين تكون زي هيك الان هذه ايش تصبح؟ carbon
+
+311
+00:28:20,260 --> 00:28:25,990
+هذا الآن تصبح carbon، كل رأس اسمه carbonهذه من
+
+312
+00:28:25,990 --> 00:28:29,530
+الأخطاء الشائعة جدا راجعنا نتبهولها ان احنا لما
+
+313
+00:28:29,530 --> 00:28:32,550
+بنحط رأس زي هيك زي هذا او زي هذا بتيجي الطالب
+
+314
+00:28:32,550 --> 00:28:36,630
+بتكتب عليه hydrogen لأ هذا الرأس يفهم على انه
+
+315
+00:28:36,630 --> 00:28:41,370
+carbon مش hydrogen و بالمناسبة لو بدكم تغلطوا
+
+316
+00:28:41,370 --> 00:28:46,570
+برامج الرسم عادة شاطرة و بتفهمكم يعني لو اجيتوا
+
+317
+00:28:46,570 --> 00:28:49,470
+تحطوا هنا على ال oxygen رابطة ثالثة يعني هذه
+
+318
+00:28:49,470 --> 00:28:54,070
+الرابطة نعص و نحط كمان رابطةلاحظوا إيش كتبلكوا
+
+319
+00:28:54,070 --> 00:28:59,650
+جملة؟ Valence exceeded on atoms زاد الإرتباط على
+
+320
+00:28:59,650 --> 00:29:04,390
+الذرّار، ليش؟ لأنه أنا قاعد بدأ أحط رابطتين هنا و
+
+321
+00:29:04,390 --> 00:29:09,690
+رابطة، قداش المجموع بيصير على ال oxygen، تلاتة
+
+322
+00:29:10,240 --> 00:29:15,300
+بالفعل ولذلك اعطاني اشارة تنبيه انه عدد الارتباط
+
+323
+00:29:15,300 --> 00:29:19,960
+زاد فانتوا في البيت اتعودوا ان عندكم برامج رسم
+
+324
+00:29:19,960 --> 00:29:24,480
+معينة او هذا البرنامج ايضا موجود عندكم بترسموا فيه
+
+325
+00:29:24,480 --> 00:29:28,700
+بتتدربوا كل ما رسمتوا اكتر اتعبتوا اكتربتتدربوا
+
+326
+00:29:28,700 --> 00:29:33,600
+أكتر على إنكوا تفهموا الأشكال بالشكل السليم، وهذه
+
+327
+00:29:33,600 --> 00:29:38,460
+مشكلة للمن مابتدربش وبيتعب من البداية، بيتغلب
+
+328
+00:29:38,460 --> 00:29:41,020
+أثناء دراسته للمسار
+
+329
+00:29:50,540 --> 00:29:55,560
+هذا بالنسبة للأشكال و كيف نرسمها بأكثر من طريقة و
+
+330
+00:29:55,560 --> 00:30:00,800
+احنا دائما في الكيميا بنفضل اي طرق الطريقة
+
+331
+00:30:00,800 --> 00:30:08,170
+المختصرة و انتوا بتكملوا الحساب في اللي هينكمالان
+
+332
+00:30:08,170 --> 00:30:14,050
+بيجينا برضه من المراجعات شيء متعلق في قطبية
+
+333
+00:30:14,050 --> 00:30:19,890
+الروابط متى تكون الرابطة قطبية و متى يكون الجزء
+
+334
+00:30:19,890 --> 00:30:25,870
+قطبيا، الرابطة بتكون قطبية يعني لها قطب موجب و قطب
+
+335
+00:30:25,870 --> 00:30:31,210
+سالبإذا اختلفت السالبية الـ electronegativity بين
+
+336
+00:30:31,210 --> 00:30:36,450
+الذرتين تعون الرابطة طبعا الذرة الأكثر سالبية تصبح
+
+337
+00:30:36,450 --> 00:30:42,290
+كأنها طرف سالب والأقل سالبية تصبح كأنها طرف موجب
+
+338
+00:30:42,290 --> 00:30:48,770
+وبنعبر عن هذا الكلام بوضع إشارة الشحنةالجزائية
+
+339
+00:30:48,770 --> 00:30:52,930
+بالحق partial positive أو partial negative في
+
+340
+00:30:52,930 --> 00:30:57,110
+عندنا احنا جدول للسالبية اعلى السالبيات اللي هي
+
+341
+00:30:57,110 --> 00:31:02,290
+سالبية الفلورين اربعة فمثلا لو كان عندكوا رابطة
+
+342
+00:31:02,290 --> 00:31:08,530
+بين الكاربون والفلورين بهذا الشكل هي كاربون الفلور
+
+343
+00:31:09,820 --> 00:31:14,040
+مين اللي سالبيتها أعلى؟ الـFloor الـFloor، إذا أي
+
+344
+00:31:14,040 --> 00:31:17,760
+طرف هيكون سالب؟ الـFloor أي طرف هيكون موجب؟
+
+345
+00:31:17,760 --> 00:31:23,060
+الـCarbon وقتها بنحط إشارة القطبية إما بهذا الشكل
+
+346
+00:31:23,060 --> 00:31:28,140
+يفهم إن هذا هو الطرف السالب وهذا هو الطرف الموجب
+
+347
+00:31:28,140 --> 00:31:33,820
+أو بنحطها بإشارة إن الـFloor بنقول عنه partially
+
+348
+00:31:33,820 --> 00:31:40,020
+negative والـCarbon partially positiveهذا بالنسبة
+
+349
+00:31:40,020 --> 00:31:43,820
+لقطبية الروابط الـ polarity of bonds it depends on
+
+350
+00:31:43,820 --> 00:31:46,820
+the electronegativity difference of the atoms
+
+351
+00:31:46,820 --> 00:31:52,560
+forming this bond بيعتمدوا على فرق السلبية لكن لو
+
+352
+00:31:52,560 --> 00:32:00,860
+مثلا قلنا جزء مثل البرومهل يا ترى هذا الجزء .. هذا
+
+353
+00:32:00,860 --> 00:32:05,900
+الرابط عفوا بين البروم و البروم بتكون قطبية؟ ليش؟
+
+354
+00:32:05,900 --> 00:32:09,780
+لأن هذه السلبية زي هذه السلبية فما بيكون في عنده
+
+355
+00:32:09,780 --> 00:32:17,650
+قطبية بين ذرتين مثل بعضهم تماماو هاي أمثلة كتير
+
+356
+00:32:17,650 --> 00:32:22,010
+بين الهيدروجين والكلور قطبية تعبر عنها بهذا الشكل
+
+357
+00:32:22,010 --> 00:32:25,250
+أو بهذا أو بهذا ال carbon و ال nitrogen ال carbon
+
+358
+00:32:25,250 --> 00:32:29,370
+و ال oxygen كل هذه أمثلة بإمكانكوا ترجعوها واضح أن
+
+359
+00:32:29,370 --> 00:32:34,630
+الذرتين لمكونات للرابطة مختلفات واحدة سلبيتها أكثر
+
+360
+00:32:34,630 --> 00:32:38,490
+هتكون هي الطرف السالب والتانية أقل هتكون هي الطرف
+
+361
+00:32:38,490 --> 00:32:44,270
+الموجبهذا الكلام بينقلنا لقطبية الجزائي الجزائي
+
+362
+00:32:44,270 --> 00:32:49,310
+يتكون من عدة روابط هل الجزائي بمجمله يكون قطبي ولا
+
+363
+00:32:49,310 --> 00:32:55,030
+لأ هذا الكلام بيعتمد على إن نجد المحاصلة لهذه
+
+364
+00:32:55,030 --> 00:33:01,210
+الروابط طبعا أي إنسان بده يوجد محاصلة لازم يفهم
+
+365
+00:33:01,210 --> 00:33:05,950
+الشكل يعني لو أنا قلتلكم هذه الطاولة بيأثر عليها
+
+366
+00:33:05,950 --> 00:33:12,210
+قوتين ما المحاصلة؟هتقولولي مباشرة احكيلنا كيف شكل
+
+367
+00:33:12,210 --> 00:33:15,610
+القوتين، والله إذا القوتين كانوا من هذه الجهة
+
+368
+00:33:15,610 --> 00:33:20,690
+بيدغطوا، الطاولة هتمشي، هتنجمع القوة الأولى مع
+
+369
+00:33:20,690 --> 00:33:24,150
+القوة التانية، لو القوتين واحدة بهذا الشكل، واحدة
+
+370
+00:33:24,150 --> 00:33:29,930
+من اتجاه المعاكسهيسطبوا بعض إذا لكي أعرف المحصلة
+
+371
+00:33:29,930 --> 00:33:34,130
+لابد إلا أن أعرف الشكل الهندسي والأصل إن هذا موضوع
+
+372
+00:33:34,130 --> 00:33:38,530
+بتتعلموه في الكيميا العامة مش مجالنا الآن إننا
+
+373
+00:33:38,530 --> 00:33:42,350
+ناخد ال geometrical structures لكن خلّيني أخد عدة
+
+374
+00:33:42,350 --> 00:33:46,990
+أمثلة مثلا درسنا إحنا إن الشكل الهندسي لثاني أكسيد
+
+375
+00:33:46,990 --> 00:33:51,810
+الكربون ليليا الآن الأكسجين عندها قطبية أكتر من
+
+376
+00:33:51,810 --> 00:33:56,260
+الكربونبناء ع ذلك لو بدأ احكي عن carbon oxygen
+
+377
+00:33:56,260 --> 00:34:01,840
+bond لها قطبية بهذا الشكلوهذه كمان القطمية بهذا
+
+378
+00:34:01,840 --> 00:34:05,800
+الشكل ايش بتلاعبوا في القطميتين؟ شطبوا بعض فالجزء
+
+379
+00:34:05,800 --> 00:34:09,860
+صار non-polar ال carbon dioxide لايه non-polar
+
+380
+00:34:09,860 --> 00:34:14,460
+بينما لو اجيت للميه، الميه الشكل تبعها ايش ماله؟ V
+
+381
+00:34:14,460 --> 00:34:19,120
+-shaped او bent، منثني الآن، فيه اندهانة قطمية
+
+382
+00:34:19,120 --> 00:34:23,900
+بهذا الشكل وبهذا الشكل هدول قوتين جايين بزاوية
+
+383
+00:34:23,900 --> 00:34:31,010
+المحصلة بتاعتهم وين بتكون؟ بينهمزي هيك هيصف محصلة
+
+384
+00:34:31,010 --> 00:34:39,000
+الجزاء فجزاء الماء يصبح جزاء قطبة واضح؟لو أخدنا
+
+385
+00:34:39,000 --> 00:34:43,200
+جزء الميثين اللي مكوّن من أربع روابط و هناخد تفصيل
+
+386
+00:34:43,200 --> 00:34:47,420
+الشكل تبعه اللي هو tetrahedral structure بإمكاننا
+
+387
+00:34:47,420 --> 00:34:55,480
+الآن على السريع نعمل شكل لجزء الميثين حتى نتأكد أن
+
+388
+00:34:55,480 --> 00:35:01,380
+هذا الجزء يترى قطبي ولا غير قطبي هاي عندنا جزء
+
+389
+00:35:01,380 --> 00:35:09,510
+الميثين بالشكل ال tetrahedral رباع الأوجهو هدولة
+
+390
+00:35:09,510 --> 00:35:13,690
+اللونهم بوردجاني اللي هم كأنهم بيمثلوا إيش ال
+
+391
+00:35:13,690 --> 00:35:19,570
+hydrogens الآن بهذا الشكل يكون جزء الميثين لو أنا
+
+392
+00:35:19,570 --> 00:35:24,550
+إجيت اطلعت كل الروابط قطبية يعني هذا الجزء في أربع
+
+393
+00:35:24,550 --> 00:35:29,250
+روابط قطبية لكن هذه و هذه لو بدي أعمل له محاصلة
+
+394
+00:35:29,250 --> 00:35:35,310
+هندسية هذه محاصلتهم الهندسية واضح؟ إذا كأن أنا إيش
+
+395
+00:35:35,310 --> 00:35:40,170
+عملت لغيت هدولة التنتينوهي المحصلة تبعتهم
+
+396
+00:35:40,170 --> 00:35:44,110
+الهندسية، طيب في عندي كمان تنتين لورا، وين
+
+397
+00:35:44,110 --> 00:35:48,250
+محصلتهم؟ بينهم، هي حاطيت محصلة
+
+398
+00:35:51,050 --> 00:35:55,790
+صار عندى محاصيلتين عكس بعض فجزء الميثين في هذه
+
+399
+00:35:55,790 --> 00:36:00,070
+الحالة بيكون polar او non-polar؟ non-polar وكذلك
+
+400
+00:36:00,070 --> 00:36:05,550
+لو كان مثلا carbon tetrachloride يعني carbon متصل
+
+401
+00:36:05,550 --> 00:36:10,310
+بكمكلور يعني لو بدل هدول ال hydrogen كانوا كلهم
+
+402
+00:36:10,310 --> 00:36:16,160
+كلورينأربع روابط قطبية أه لكن محصلتها سفر هذا
+
+403
+00:36:16,160 --> 00:36:19,480
+الأمر مش مستغرب يعني لو انتوا اتيتوا مثلا على هذه
+
+404
+00:36:19,480 --> 00:36:23,660
+الطاولة جيبتوا أربع رجال أشداء كل واحد عنده قوة
+
+405
+00:36:23,660 --> 00:36:27,400
+واحد بيضغط بهذا الشكل واحد بهذا الشكل واحد بهذا
+
+406
+00:36:27,400 --> 00:36:32,400
+الشكل واحد بهذا الشكل هل ستتحرك الطاولة؟ في عندى
+
+407
+00:36:32,400 --> 00:36:38,280
+أربع قوة لكن محصلتها إيش؟ سفرواضح هذه الفكرة، إذا
+
+408
+00:36:38,280 --> 00:36:45,540
+قطبية الجزيئات تعتمد على شكلها الهندسي، على محصلة
+
+409
+00:36:45,540 --> 00:36:47,500
+قطبية الروابط
+
+410
+00:36:50,510 --> 00:36:55,770
+ما فهمنا احنا الآن ظاهرة ال isomerism او تكون ال
+
+411
+00:36:55,770 --> 00:37:00,550
+isomers سبق انه احنا قلنا ان ال isomers يمكن هذه
+
+412
+00:37:00,550 --> 00:37:05,510
+ال slide شوية صغيرة خليني انا اعمل نسخة اكبر منها
+
+413
+00:37:05,510 --> 00:37:09,730
+شوية ال isomers they are different compounds that
+
+414
+00:37:09,730 --> 00:37:14,130
+have the same molecular formula اكثر من مركب لهم
+
+415
+00:37:14,130 --> 00:37:17,750
+نفس الصيغة الجزائية زي ما عملنا في البداية هاي
+
+416
+00:37:17,750 --> 00:37:22,700
+مثلا مركب بصيغة جزائيةأسود أزرق أحمر هاي مركب
+
+417
+00:37:22,700 --> 00:37:28,060
+بصيغة جزائية تانية الان المركب الأول و المركب
+
+418
+00:37:28,060 --> 00:37:32,640
+الثاني شو أنا بسميهم isomers فال isomers they are
+
+419
+00:37:32,640 --> 00:37:35,840
+different compounds that have the same molecular
+
+420
+00:37:35,840 --> 00:37:40,320
+formula الان طالما the same molecular formula لو
+
+421
+00:37:40,320 --> 00:37:44,780
+ناس قالوا the same number of atoms ما هي ال
+
+422
+00:37:44,780 --> 00:37:49,740
+molecular formulaعدد ذرات لو ناس قالوا the same
+
+423
+00:37:49,740 --> 00:37:54,700
+molecular weightكله تعبير عن نفس الفكرة طالما نفس
+
+424
+00:37:54,700 --> 00:38:01,700
+العدد من الذرات إذا نفس الوزن فكل من هذه التعريف
+
+425
+00:38:01,700 --> 00:38:04,380
+يجوز لنا الناس تعمله different compounds that have
+
+426
+00:38:04,380 --> 00:38:07,260
+the same molecular formula the same number of
+
+427
+00:38:07,260 --> 00:38:11,040
+atoms the same molecular weight كل هذا الكلام
+
+428
+00:38:11,040 --> 00:38:16,240
+بيمشي كتعريف لل isomers الآن ال isomers بشكل عام
+
+429
+00:38:16,240 --> 00:38:22,710
+تقسم إلى نوعيننوع بنسميه constitutional isomers
+
+430
+00:38:22,710 --> 00:38:29,010
+وبياخد اسم تاني structural isomersStructural يعني
+
+431
+00:38:29,010 --> 00:38:34,490
+بنائي و نوع بنسميه stereo isomers فراغي إذا في
+
+432
+00:38:34,490 --> 00:38:42,170
+عندى متشكلات بنائية و متشكلات فراغية المتشكلات
+
+433
+00:38:42,170 --> 00:38:45,690
+البنائية ال structural أو ال constitutional
+
+434
+00:38:45,690 --> 00:38:50,910
+isomers بتكون الذرات نفسها مرتبطة مع بعض البعض
+
+435
+00:38:50,910 --> 00:38:56,760
+بطرق مختلفةيعني لو افترضت عندى تلت ذرات تنتين
+
+436
+00:38:56,760 --> 00:39:01,940
+Carbon و واحدة Oxygen هل يا ترى هدولة مربوطين
+
+437
+00:39:01,940 --> 00:39:07,760
+Carbon Carbon Oxygen ولا Carbon Oxygen Carbon و
+
+438
+00:39:07,760 --> 00:39:13,180
+بعدين نكمل الهيدروجينات هنا عندى different bonding
+
+439
+00:39:14,310 --> 00:39:19,050
+واضح؟ carbon carbon oxygen غير عن carbon oxygen
+
+440
+00:39:19,050 --> 00:39:23,590
+carbon فلو انا اجيت كملت المراكبات هاي المراكبة ده
+
+441
+00:39:23,590 --> 00:39:29,110
+carbon carbon oxygen CH3 CH2 OH صار عندي مراكب
+
+442
+00:39:29,110 --> 00:39:38,470
+اسمه الاثانون لو اجيت قولت CH3 OCH3 صار عندي مراكب
+
+443
+00:39:38,470 --> 00:39:47,340
+تاني اسمه dye مثل etherثنائي مثل ال ether فهذا
+
+444
+00:39:47,340 --> 00:39:50,760
+اللي بيميز ال structural isomers they have
+
+445
+00:39:50,760 --> 00:39:55,840
+different bonding different names طالما الارتباط
+
+446
+00:39:55,840 --> 00:40:01,060
+اختلف اذا كمان الاسماء هتصير ايش مختلفة فاول ما
+
+447
+00:40:01,060 --> 00:40:05,800
+بنقول احنا structural isomers بدنا نتذكر ان هدولة
+
+448
+00:40:05,800 --> 00:40:11,850
+فيهم ارتباط مختلف ولهم اسماء مختلفةالنوع التاني من
+
+449
+00:40:11,850 --> 00:40:17,450
+ال isomers نوع أصعب شوية ولذلك بندرسه احنا ب
+
+450
+00:40:17,450 --> 00:40:21,730
+chapter منفصل اللي هو الفصل الخامس من المادة هذه
+
+451
+00:40:21,730 --> 00:40:27,130
+بنسميه stereo isomers ال stereo isomers الذرات
+
+452
+00:40:27,130 --> 00:40:31,790
+بتكون لها نفس الارتباط يعني هنا أنا قولت same
+
+453
+00:40:31,790 --> 00:40:35,270
+different bonding في ال stereo isomers على طول
+
+454
+00:40:35,270 --> 00:40:40,850
+بقول sameconstitution أو same bonding نفس الارتباط
+
+455
+00:40:40,850 --> 00:40:46,410
+طب نفس الارتباط هوين بيختلفوا؟ بالشكل بالفراغ ممكن
+
+456
+00:40:46,410 --> 00:40:51,410
+أشياء يكون لها نفس الارتباط وتختلف بالشكل بالفراغ
+
+457
+00:40:51,410 --> 00:40:55,690
+الجواب أه بدي أعطيكم مثال من برا الكيميا لما
+
+458
+00:40:55,690 --> 00:41:00,430
+الطلاب في المدرسة بيجفوا بطابور الصبح هي إيد وجسمه
+
+459
+00:41:00,430 --> 00:41:06,270
+إيد هذا الارتباط إيش هو؟إيد وجسم وإيد، طب لو عملوا
+
+460
+00:41:06,270 --> 00:41:12,350
+هيك، هذا الشكل، لو عملوا هيك، هذا الشكل، الآن هل
+
+461
+00:41:12,350 --> 00:41:16,630
+تغير شيء في الإرتباط؟ إيد وجسم إيد
+
+462
+00:41:19,410 --> 00:41:22,950
+لو عملوا هيك، طب هدول الأشكال التلاتة، لو أخدت
+
+463
+00:41:22,950 --> 00:41:27,910
+تلات صور و حاطيتهم قدام الطالب وسألته ما العلاقة
+
+464
+00:41:27,910 --> 00:41:31,990
+بين هدول التلات صور، هيقول لي ال same bonding،
+
+465
+00:41:31,990 --> 00:41:36,150
+مافكتش ولا إيد من إيدين البني آدم، نفس الإرتباط،
+
+466
+00:41:36,150 --> 00:41:40,720
+طب أين الاختلاف؟بالشكل الفراغي إذا اللي بيميز ال
+
+467
+00:41:40,720 --> 00:41:45,060
+stereo isomers ال atoms have the same bonding the
+
+468
+00:41:45,060 --> 00:41:48,400
+same constitution بط different arrangement in
+
+469
+00:41:48,400 --> 00:41:52,320
+space لكن شكلهم بالفراغ بختلف طبعا هنتوسع فيهم
+
+470
+00:41:52,320 --> 00:41:56,220
+نلاحظ أنه في منهم نوع اسمه اناشو مارس و نوع اسمه
+
+471
+00:41:56,220 --> 00:42:01,340
+استيريو مارس كل هذا التوسع بيكون بفصل كامل اللي هو
+
+472
+00:42:01,340 --> 00:42:07,570
+الفصلالخامس ابهيك ابننهي اليوم و إلى لقاء آخر ان
+
+473
+00:42:07,570 --> 00:42:07,950
+شاء الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..0e3d8e5f43868413d26c7b3c2f7385222fcbea5f
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_raw.json
@@ -0,0 +1 @@
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قوة هذه الروابط بمعنى لو أنا بدي أكسر الروابط من اللي سهل أني أكسره ال Intermolecular forces تماما زي ما نتخيل اتنين بيجوا بيسلموا على بعض", "tokens": [4575, 7039, 4812, 17792, 5874, 16247, 4587, 2407, 7578, 8717, 45367, 8978, 2423, 39184, 5751, 3280, 306, 17792, 5874, 29538, 12174, 35473, 3224, 3714, 16758, 31371, 7435, 1829, 8592, 16490, 2304, 3794, 3660, 5296, 3615, 8592, 25720, 8978, 9673, 10632, 9154, 12174, 2407, 3660, 29538, 34892, 14407, 3555, 9566, 4724, 2304, 3615, 1863, 7578, 45164, 41850, 4724, 16254, 5551, 4117, 3794, 2288, 34892, 14407, 3555, 9566, 9154, 13672, 1829, 8608, 3224, 1211, 14739, 1829, 5551, 4117, 3794, 2288, 3224, 2423, 5751, 3280, 306, 17792, 5874, 46811, 10943, 995, 30767, 1829, 19446, 8717, 2655, 9778, 26895, 1975, 2655, 1863, 9957, 4724, 1829, 7435, 14407, 4724, 1829, 3794, 19528, 14407, 15844, 45030, 11242], "avg_logprob": -0.20507812460086175, "compression_ratio": 1.8405797101449275, "no_speech_prob": 0.0, "words": [{"start": 388.83, "end": 390.27, 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للطاقة بقول عنها exothermic process فال bond energy هي الطاقة اللي لازم الكسر روابط او واحد مول من الروابط من ال covalent bonds كذلك", "tokens": [3555, 16254, 23032, 995, 28671, 11778, 47302, 15042, 20449, 32887, 5172, 43242, 8315, 16472, 3224, 9122, 3794, 2288, 34892, 16758, 9566, 3660, 6225, 42213, 10632, 4724, 5016, 26108, 3660, 2423, 7578, 23032, 995, 28671, 4724, 39648, 18871, 11296, 917, 802, 13195, 1399, 49374, 15042, 6055, 4117, 2407, 9957, 34892, 16758, 9566, 3660, 6225, 42213, 10632, 23032, 9640, 41891, 24976, 9566, 995, 28671, 4724, 39648, 18871, 11296, 454, 802, 13195, 1399, 6156, 6027, 6086, 2281, 39896, 41950, 995, 28671, 13672, 1829, 5296, 31377, 2304, 33251, 3794, 2288, 12602, 14407, 3555, 9566, 1975, 2407, 36764, 24401, 3714, 12610, 9154, 34892, 14407, 3555, 9566, 9154, 2423, 598, 3337, 317, 14713, 9122, 8848, 23275], "avg_logprob": -0.1352055182865074, "compression_ratio": 1.8818181818181818, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 728.21, "end": 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الذرتين بينهم إيش رابطة الآن هذه المسافة تزيد وتقصر", "tokens": [41185, 43242, 7578, 11933, 1829, 8592, 24525, 2304, 3224, 2423, 6086, 4641, 2423, 6086, 4641, 31439, 9673, 3794, 31845, 3660, 9673, 2655, 41779, 9566, 3660, 19446, 49374, 29910, 43500, 9957, 32239, 8592, 47524, 31845, 3660, 44650, 41779, 9566, 3660, 5296, 33456, 3224, 34892, 16758, 9566, 3660, 39896, 6225, 3555, 9640, 3660, 18871, 47524, 31845, 3660, 20666, 5172, 2288, 5718, 118, 32239, 14851, 38637, 16758, 2655, 3660, 37495, 22653, 29910, 43500, 9957, 49374, 16095, 47524, 31845, 3660, 20449, 9957, 3660, 8978, 27188, 2288, 5718, 118, 44945, 39648, 8032, 3215, 12610, 32545, 43500, 9957, 49374, 16095, 11933, 1829, 8592, 12602, 16758, 9566, 3660, 6024, 48506, 29538, 9673, 3794, 31845, 3660, 6055, 11622, 25708, 34683, 4587, 9381, 2288], "avg_logprob": -0.11099137943880312, "compression_ratio": 2.052380952380952, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 757.92, "end": 758.22, "word": "في", "probability": 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هو واحد في عشر أقص ناقص اتنائش من المتر واضح طبعا لما انقيس ال bond length", "tokens": [20292, 14851, 38637, 16758, 2655, 3660, 46811, 10943, 995, 4032, 5296, 8848, 23275, 1975, 5016, 8315, 44945, 47283, 3215, 9673, 3794, 31845, 3660, 9673, 2655, 41779, 9566, 3660, 4724, 1829, 9381, 13546, 43242, 8315, 2423, 6086, 4641, 6024, 48506, 2423, 6086, 4641, 7251, 4587, 32277, 6225, 18513, 3660, 20666, 2562, 38673, 13672, 1829, 31439, 36764, 24401, 8978, 6225, 46309, 5551, 4587, 9381, 8717, 995, 4587, 9381, 6225, 8592, 25720, 9154, 9673, 2655, 2288, 1975, 2407, 44945, 38436, 3794, 3224, 8978, 2423, 13363, 13606, 13672, 1829, 31439, 36764, 24401, 8978, 6225, 46309, 5551, 4587, 9381, 8717, 995, 4587, 9381, 1975, 2655, 1863, 16373, 8592, 9154, 9673, 2655, 2288, 4032, 46958, 5016, 23032, 3555, 3615, 995, 5296, 15042, 16472, 38436, 3794, 2423, 6086, 4641], "avg_logprob": -0.20871442411004043, "compression_ratio": 1.9642857142857142, "no_speech_prob": 0.0, "words": [{"start": 784.84, "end": 785.48, 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{"start": 802.3, "end": 803.14, "word": " اللي", "probability": 0.9814453125}, {"start": 803.14, "end": 803.32, "word": " هو", "probability": 0.9833984375}, {"start": 803.32, "end": 803.74, "word": " واحد", "probability": 0.969482421875}, {"start": 803.74, "end": 803.88, "word": " في", "probability": 0.97705078125}, {"start": 803.88, "end": 804.2, "word": " عشر", "probability": 0.881591796875}, {"start": 804.2, "end": 804.48, "word": " أقص", "probability": 0.9767252604166666}, {"start": 804.48, "end": 805.08, "word": " ناقص", "probability": 0.9788818359375}, {"start": 805.08, "end": 806.28, "word": " اتنائش", "probability": 0.744384765625}, {"start": 806.28, "end": 806.76, "word": " من", "probability": 0.994140625}, {"start": 806.76, "end": 807.4, "word": " المتر", "probability": 0.9534505208333334}, {"start": 807.4, "end": 808.14, "word": " واضح", "probability": 0.8228352864583334}, {"start": 808.14, "end": 809.08, "word": " طبعا", "probability": 0.92431640625}, {"start": 809.08, "end": 809.56, "word": " لما", "probability": 0.868896484375}, {"start": 809.56, "end": 810.34, "word": " انقيس", "probability": 0.6807454427083334}, {"start": 810.34, "end": 810.66, "word": " ال", "probability": 0.8896484375}, {"start": 810.66, "end": 810.94, "word": " bond", "probability": 0.97216796875}, {"start": 810.94, "end": 811.4, "word": " length", "probability": 0.833984375}], "temperature": 1.0}, {"id": 36, "seek": 83289, "start": 811.95, "end": 832.89, "text": "بال بيكميتر هتطلع أطوال الروابط عندنا سهلة الملاحظة وسهلة الحفظ يعني خليني أفرجيكم كيف هي أنا بعطيكم مقارنة بين الرابطة الأحادية هذه الرابطة اللي أنا بقصدها الأحادية والثنائية والرابطة", "tokens": [3555, 6027, 4724, 1829, 24793, 36081, 2288, 8032, 2655, 9566, 1211, 3615, 5551, 9566, 2407, 6027, 34892, 14407, 3555, 9566, 43242, 8315, 8608, 3224, 37977, 9673, 15040, 5016, 19913, 3660, 46952, 3224, 37977, 21542, 5172, 19913, 37495, 22653, 16490, 1211, 9957, 1829, 5551, 5172, 47341, 1829, 24793, 9122, 33911, 39896, 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bond order ايش ال bond order ال bond order is the number of chemical bonds between a pair of atoms عدد الروابط ما بين ذرتين هل يترى هدول الروابط منها ذرتين احدية", "tokens": [6027, 12984, 1211, 5718, 104, 10632, 2423, 7649, 20193, 5016, 19913, 14407, 16472, 6225, 3215, 3215, 34892, 14407, 3555, 9566, 4724, 1829, 11622, 25708, 1975, 24401, 10632, 38637, 1863, 16373, 10632, 38637, 1211, 5718, 104, 10632, 23758, 1975, 5016, 8315, 44945, 38251, 1829, 3224, 2423, 6086, 1668, 1975, 1829, 8592, 2423, 6086, 1668, 2423, 6086, 1668, 307, 264, 1230, 295, 7313, 14713, 1296, 257, 6119, 295, 16871, 6225, 3215, 3215, 34892, 14407, 3555, 9566, 19446, 49374, 29910, 43500, 9957, 8032, 1211, 7251, 2655, 2288, 7578, 8032, 3215, 12610, 34892, 14407, 3555, 9566, 9154, 11296, 29910, 43500, 9957, 1975, 24401, 10632], "avg_logprob": -0.23994431047156306, "compression_ratio": 1.8535353535353536, "no_speech_prob": 0.0, "words": [{"start": 834.55, "end": 835.39, "word": "الثلاثية", "probability": 0.9072265625}, 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"probability": 0.7845865885416666}, {"start": 1266.33, "end": 1266.91, "word": " أقل", "probability": 0.96923828125}, {"start": 1266.91, "end": 1267.79, "word": " معنا", "probability": 0.816650390625}, {"start": 1267.79, "end": 1268.13, "word": " ذلك", "probability": 0.809326171875}, {"start": 1268.13, "end": 1268.35, "word": " هذا", "probability": 0.76416015625}, {"start": 1268.35, "end": 1268.61, "word": " فيه", "probability": 0.93115234375}, {"start": 1268.61, "end": 1269.33, "word": " هيدروجين", "probability": 0.90302734375}, {"start": 1269.33, "end": 1270.21, "word": " اختصرا", "probability": 0.776611328125}], "temperature": 1.0}, {"id": 56, "seek": 128854, "start": 1271.02, "end": 1288.54, "text": "كتابة يعني هذه CH3EC مبينين أربع روابط هنا يمكن تطلع كربون متصلة بكربون و كربون إذا ما المختصر هنا ذرتين هيدروجين بتكون تفهموهم يعني لما نقول إقرأوا إيش فيه هنا بتقولوا هذه عبارة عن CH2", "tokens": [4117, 2655, 16758, 3660, 37495, 22653, 29538, 5995, 18, 8140, 3714, 3555, 9957, 9957, 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إنسان بده يوجد محاصلة لازم يفهم الشكل يعني لو أنا قلتلكم هذه الطاولة بيأثر عليها قوتين ما المحاصلة؟", "tokens": [3224, 15730, 2423, 28820, 10943, 4724, 1829, 1863, 4587, 1211, 8315, 5296, 47432, 3555, 10632, 25724, 11622, 16373, 1829, 25724, 11622, 16373, 1829, 7251, 2655, 30544, 9154, 6225, 41891, 12602, 14407, 3555, 9566, 8032, 1211, 25724, 11622, 16373, 1829, 4724, 2304, 7435, 42213, 3224, 7251, 30544, 12174, 9566, 21292, 49429, 5296, 10721, 23758, 2423, 28820, 10943, 4724, 1829, 34268, 2304, 3215, 15844, 36145, 8717, 7435, 3215, 9673, 5016, 33546, 37977, 46740, 24192, 34892, 14407, 3555, 9566, 23032, 3555, 3615, 995, 36632, 36145, 3794, 7649, 47525, 3224, 7251, 29245, 3215, 3714, 5016, 33546, 37977, 5296, 31377, 2304, 7251, 5172, 16095, 25124, 28820, 37495, 22653, 45164, 41850, 12174, 1211, 2655, 23275, 2304, 29538, 41950, 995, 12610, 3660, 4724, 1829, 10721, 49115, 25894, 11296, 12174, 35473, 9957, 19446, 9673, 5016, 33546, 37977, 22807], "avg_logprob": -0.15255248614849934, 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isomers على طول بقول same", "tokens": [6027, 1863, 45367, 16712, 7649, 1829, 9154, 2423, 307, 298, 433, 8717, 45367, 5551, 9381, 3615, 3555, 13412, 2407, 10632, 35525, 8848, 23275, 44945, 3215, 2288, 3794, 3224, 1975, 5016, 8315, 4724, 7187, 9154, 5172, 36520, 13672, 1829, 31439, 27188, 36520, 33962, 10943, 3794, 9154, 9673, 18513, 3660, 29538, 44945, 38251, 1829, 3224, 29029, 307, 298, 433, 2423, 29029, 307, 298, 433, 32545, 2288, 9307, 39894, 30544, 5296, 11296, 8717, 36178, 2423, 9640, 2655, 3555, 41193, 37495, 22653, 34105, 41850, 12174, 12610, 2655, 912, 819, 28824, 8978, 2423, 29029, 307, 298, 433, 15844, 23032, 12610, 4724, 39648, 912], "avg_logprob": -0.14772727603864189, "compression_ratio": 1.747787610619469, "no_speech_prob": 0.0, "words": [{"start": 2410.71, "end": 2411.17, "word": "النوع", "probability": 0.9615885416666666}, {"start": 2411.17, "end": 2411.65, "word": " التاني", "probability": 0.9391276041666666}, {"start": 2411.65, "end": 2411.85, "word": " من", 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2432.59, "end": 2433.25, "word": " bonding", "probability": 0.9140625}, {"start": 2433.25, "end": 2433.65, "word": " في", "probability": 0.7880859375}, {"start": 2433.65, "end": 2433.79, "word": " ال", "probability": 0.9482421875}, {"start": 2433.79, "end": 2434.15, "word": " stereo", "probability": 0.9560546875}, {"start": 2434.15, "end": 2434.89, "word": " isomers", "probability": 0.9850260416666666}, {"start": 2434.89, "end": 2435.07, "word": " على", "probability": 0.341064453125}, {"start": 2435.07, "end": 2435.27, "word": " طول", "probability": 0.989013671875}, {"start": 2435.27, "end": 2435.65, "word": " بقول", "probability": 0.973876953125}, {"start": 2435.65, "end": 2436.25, "word": " same", "probability": 0.849609375}], "temperature": 1.0}, {"id": 110, "seek": 246309, "start": 2436.97, "end": 2463.09, "text": "constitution أو same bonding نفس الارتباط طب نفس الارتباط هوين بيختلفوا؟ بالشكل بالفراغ ممكن أشياء يكون لها نفس الارتباط وتختلف بالشكل بالفراغ الجواب أه بدي أعطيكم مثال من برا الكيميا لما الطلاب في المدرسة بيجفوا بطابور الصبح هي إيد وجسمه إيد هذا الارتباط إيش هو؟", "tokens": [25279, 6518, 34051, 912, 28824, 8717, 36178, 2423, 9640, 2655, 3555, 41193, 23032, 3555, 8717, 36178, 2423, 9640, 2655, 3555, 41193, 31439, 9957, 4724, 1829, 46456, 46538, 14407, 22807, 20666, 8592, 28820, 20666, 5172, 2288, 5718, 118, 3714, 43020, 5551, 8592, 1829, 16606, 7251, 30544, 5296, 11296, 8717, 36178, 2423, 9640, 2655, 3555, 41193, 34683, 46456, 46538, 20666, 8592, 28820, 20666, 5172, 2288, 5718, 118, 25724, 14407, 3555, 5551, 3224, 4724, 16254, 5551, 3615, 9566, 1829, 24793, 50113, 6027, 9154, 4724, 23557, 33251, 32640, 25528, 5296, 15042, 41950, 15040, 3555, 8978, 9673, 3215, 2288, 3794, 3660, 4724, 1829, 7435, 5172, 14407, 4724, 9566, 16758, 13063, 31767, 49628, 39896, 11933, 25708, 49610, 38251, 3224, 11933, 25708, 23758, 2423, 9640, 2655, 3555, 41193, 11933, 1829, 8592, 31439, 22807], "avg_logprob": -0.15661908838692612, "compression_ratio": 1.896694214876033, 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2444.09, "end": 2445.11, "word": " بالشكل", "probability": 0.9431966145833334}, {"start": 2445.11, "end": 2445.77, "word": " بالفراغ", "probability": 0.9283203125}, {"start": 2445.77, "end": 2446.41, "word": " ممكن", "probability": 0.921630859375}, {"start": 2446.41, "end": 2446.99, "word": " أشياء", "probability": 0.9683837890625}, {"start": 2446.99, "end": 2447.29, "word": " يكون", "probability": 0.9638671875}, {"start": 2447.29, "end": 2447.71, "word": " لها", "probability": 0.6920166015625}, {"start": 2447.71, "end": 2448.39, "word": " نفس", "probability": 0.99755859375}, {"start": 2448.39, "end": 2449.41, "word": " الارتباط", "probability": 0.98486328125}, {"start": 2449.41, "end": 2450.35, "word": " وتختلف", "probability": 0.8605143229166666}, {"start": 2450.35, "end": 2450.79, "word": " بالشكل", "probability": 0.9635416666666666}, {"start": 2450.79, "end": 2451.41, "word": " بالفراغ", "probability": 0.97744140625}, {"start": 2451.41, "end": 2452.11, "word": " الجواب", "probability": 0.8899739583333334}, {"start": 2452.11, "end": 2452.47, "word": " أه", "probability": 0.6595458984375}, {"start": 2452.47, "end": 2452.99, "word": " بدي", "probability": 0.482421875}, {"start": 2452.99, "end": 2453.31, "word": " أعطيكم", "probability": 0.836572265625}, {"start": 2453.31, "end": 2453.69, "word": " مثال", "probability": 0.94921875}, {"start": 2453.69, "end": 2453.87, "word": " من", "probability": 0.9892578125}, {"start": 2453.87, "end": 2454.17, "word": " برا", "probability": 0.916259765625}, {"start": 2454.17, "end": 2455.19, "word": " الكيميا", "probability": 0.84765625}, {"start": 2455.19, "end": 2455.69, "word": " لما", "probability": 0.921142578125}, {"start": 2455.69, "end": 2456.27, "word": " الطلاب", "probability": 0.9544270833333334}, {"start": 2456.27, "end": 2456.39, "word": " في", "probability": 0.9755859375}, {"start": 2456.39, "end": 2456.97, "word": " المدرسة", "probability": 0.9923828125}, {"start": 2456.97, "end": 2457.41, "word": " بيجفوا", "probability": 0.8982421875}, {"start": 2457.41, "end": 2457.89, "word": " بطابور", "probability": 0.8123779296875}, {"start": 2457.89, "end": 2458.47, "word": " الصبح", "probability": 0.90283203125}, {"start": 2458.47, "end": 2459.03, "word": " هي", "probability": 0.650390625}, {"start": 2459.03, "end": 2459.63, "word": " إيد", "probability": 0.716796875}, {"start": 2459.63, "end": 2460.43, "word": " وجسمه", "probability": 0.6949869791666666}, {"start": 2460.43, "end": 2460.81, "word": " إيد", "probability": 0.9619140625}, {"start": 2460.81, "end": 2461.53, "word": " هذا", "probability": 0.87890625}, {"start": 2461.53, "end": 2462.25, "word": " الارتباط", "probability": 0.976953125}, {"start": 2462.25, "end": 2462.59, "word": " إيش", "probability": 0.7689615885416666}, {"start": 2462.59, "end": 2463.09, "word": " هو؟", "probability": 0.95703125}], "temperature": 1.0}, {"id": 111, "seek": 247663, "start": 2463.75, "end": 2476.63, "text": "إيد وجسم وإيد، طب لو عملوا هيك، هذا الشكل، لو عملوا هيك، هذا الشكل، الآن هل تغير شيء في الإرتباط؟ إيد وجسم إيد", "tokens": [28814, 25708, 49610, 38251, 4032, 28814, 25708, 12399, 23032, 3555, 45164, 6225, 42213, 14407, 39896, 4117, 12399, 23758, 25124, 28820, 12399, 45164, 6225, 42213, 14407, 39896, 4117, 12399, 23758, 25124, 28820, 12399, 6024, 48506, 8032, 1211, 6055, 17082, 13546, 44049, 38207, 8978, 33688, 43500, 3555, 41193, 22807, 11933, 25708, 49610, 38251, 11933, 25708], "avg_logprob": -0.2109374983443154, "compression_ratio": 1.7678571428571428, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 2463.75, "end": 2464.25, "word": "إيد", "probability": 0.7406005859375}, {"start": 2464.25, "end": 2464.89, "word": " وجسم", "probability": 0.863525390625}, {"start": 2464.89, "end": 2465.43, "word": " وإيد،", "probability": 0.6529541015625}, {"start": 2465.43, "end": 2465.75, "word": " طب", "probability": 0.86181640625}, {"start": 2465.75, "end": 2465.91, "word": " لو", "probability": 0.98486328125}, {"start": 2465.91, "end": 2466.27, "word": " عملوا", "probability": 0.9405924479166666}, {"start": 2466.27, "end": 2467.77, "word": " هيك،", "probability": 0.6680501302083334}, {"start": 2467.77, "end": 2467.99, "word": " هذا", "probability": 0.90673828125}, {"start": 2467.99, "end": 2468.71, "word": " الشكل،", "probability": 0.8533528645833334}, {"start": 2468.71, "end": 2469.51, "word": " لو", "probability": 0.740234375}, {"start": 2469.51, "end": 2469.89, "word": " عملوا", "probability": 0.9773763020833334}, {"start": 2469.89, "end": 2470.79, "word": " هيك،", "probability": 0.9205729166666666}, {"start": 2470.79, "end": 2470.99, "word": " هذا", "probability": 0.919921875}, {"start": 2470.99, "end": 2471.77, "word": " الشكل،", "probability": 0.9537760416666666}, {"start": 2471.77, "end": 2472.09, "word": " الآن", "probability": 0.792724609375}, {"start": 2472.09, "end": 2472.35, "word": " هل", "probability": 0.978759765625}, {"start": 2472.35, "end": 2472.89, "word": " تغير", "probability": 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"end": 2481.05, "word": " هدول", "probability": 0.9290364583333334}, {"start": 2481.05, "end": 2481.59, "word": " الأشكال", "probability": 0.900390625}, {"start": 2481.59, "end": 2482.37, "word": " التلاتة،", "probability": 0.85546875}, {"start": 2482.37, "end": 2482.51, "word": " لو", "probability": 0.95458984375}, {"start": 2482.51, "end": 2482.95, "word": " أخدت", "probability": 0.9442138671875}, {"start": 2482.95, "end": 2483.27, "word": " تلات", "probability": 0.8203125}, {"start": 2483.27, "end": 2483.69, "word": " صور", "probability": 0.9912109375}, {"start": 2483.69, "end": 2484.05, "word": " و", "probability": 0.8876953125}, {"start": 2484.05, "end": 2485.09, "word": " حاطيتهم", "probability": 0.806884765625}, {"start": 2485.09, "end": 2485.73, "word": " قدام", "probability": 0.9632161458333334}, {"start": 2485.73, "end": 2486.17, "word": " الطالب", "probability": 0.9918619791666666}, {"start": 2486.17, "end": 2486.87, "word": " وسألته", "probability": 0.8509521484375}, 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252190, "start": 2498.02, "end": 2521.9, "text": "بالشكل الفراغي إذا اللي بيميز ال stereo isomers ال atoms have the same bonding the same constitution بط different arrangement in space لكن شكلهم بالفراغ بختلف طبعا هنتوسع فيهم نلاحظ أنه في منهم نوع اسمه اناشو مارس و نوع اسمه استيريو مارس كل هذا التوسع بيكون بفصل كامل اللي هو الفصل", "tokens": [3555, 6027, 8592, 28820, 27188, 2288, 5718, 118, 1829, 11933, 15730, 13672, 1829, 4724, 32640, 1829, 11622, 2423, 29029, 307, 298, 433, 2423, 16871, 362, 264, 912, 28824, 264, 912, 11937, 4724, 9566, 819, 17620, 294, 1901, 44381, 13412, 28820, 16095, 20666, 5172, 2288, 5718, 118, 4724, 46456, 46538, 23032, 3555, 3615, 995, 8032, 29399, 41779, 3615, 8978, 16095, 8717, 15040, 5016, 19913, 14739, 3224, 8978, 9154, 16095, 8717, 45367, 24525, 2304, 3224, 16472, 33599, 2407, 3714, 9640, 3794, 4032, 8717, 45367, 24525, 2304, 3224, 44713, 13546, 1829, 2407, 3714, 9640, 3794, 28242, 23758, 16712, 41779, 3615, 4724, 1829, 30544, 4724, 5172, 36520, 9122, 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\ No newline at end of file
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new file mode 100644
index 0000000000000000000000000000000000000000..43833ac798b205762d287a5321a52381a9fa029b
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_raw.srt
@@ -0,0 +1,1896 @@
+1
+00:00:21,450 --> 00:00:26,690
+بسم الله الرحمن الرحيم طبعا سعاداء ان احنا نلتقي
+
+2
+00:00:26,690 --> 00:00:31,710
+فيكم في المحاضرة الأولى في هذا المساق هذا مساق
+
+3
+00:00:31,710 --> 00:00:38,510
+كيميا عضوية أو كيميا عضوية و حيوية يدرس عادةبأرقام
+
+4
+00:00:38,510 --> 00:00:43,510
+مختلفة في الجامعة لأكثر من تخصص يعني لطلبة العلوم
+
+5
+00:00:43,510 --> 00:00:49,690
+الصحية احنا بندرسه بالرقم Bioc 1301 لطلبة كلية
+
+6
+00:00:49,690 --> 00:00:55,770
+الطب بندرسه بالرقم Medic 1310 ولطلبة العلوم
+
+7
+00:00:55,770 --> 00:00:59,390
+الحياتية البيولوجيا والبيئة وما إلى ذلك برضه
+
+8
+00:00:59,390 --> 00:01:07,060
+بندرسه برقم Chem 2311 فكل هؤلاء الطلبةبنشاء الله
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+9
+00:01:07,060 --> 00:01:10,700
+بيستطيعوا أنهم يستفيدوا من هذا المساق و اللي يعني
+
+10
+00:01:10,700 --> 00:01:15,900
+ان شاء الله سيكون مسجل حتى يعني يمكنكم تدارك أي
+
+11
+00:01:15,900 --> 00:01:19,760
+معلومات نقصت عليكم أثناء يعني سماع المحاضرة
+
+12
+00:01:19,760 --> 00:01:24,960
+الأصلية، مسموح طبعا أنه يكون في نقاش علمي هادق و
+
+13
+00:01:24,960 --> 00:01:29,280
+بيظهر في التصويرانتوا كلكم كمان واضحين أمام
+
+14
+00:01:29,280 --> 00:01:35,120
+الكاميرات ومناقشاتكوا هتكون يعني مثرية لتدريس هذا
+
+15
+00:01:35,120 --> 00:01:40,020
+المسابق ان شاء الله الكتاب
+
+16
+00:01:40,020 --> 00:01:45,600
+المقرر هو كتاب مشهور جدا في مجاله كتاب organic
+
+17
+00:01:45,600 --> 00:01:50,540
+chemistry للمؤلف heart and heart هذا الكتاب طبعا
+
+18
+00:01:50,540 --> 00:01:55,700
+مع المحتويات الإلكترونية كلها موفرة لكم ان شاء
+
+19
+00:01:55,700 --> 00:02:01,560
+اللهالجزء الأول من المساقى اللى هندرسه مقدمة في
+
+20
+00:02:01,560 --> 00:02:06,220
+الكيمياء العضوية بنتعرف جيد على المجموعات الوظيفية
+
+21
+00:02:06,220 --> 00:02:10,420
+على أنواع المركبات العضوية هذه المقدمة في الكيمياء
+
+22
+00:02:10,420 --> 00:02:16,400
+العضوية حوالى 11 فاصل لما تصير موجودة عندنا بشكل
+
+23
+00:02:16,400 --> 00:02:21,960
+جيد بصير بإمكاننا أنه نعطي بعدها مقدمة في الكيمياء
+
+24
+00:02:21,960 --> 00:02:28,080
+الحيوية باربع فصولان شاء الله بهيك بيكون يعني ال
+
+25
+00:02:28,080 --> 00:02:32,660
+course اكتملت مكوناته مقدمة في الكيمياع العضوية و
+
+26
+00:02:32,660 --> 00:02:36,220
+بعد هيك الجزء الثاني من ال course مقدمة في
+
+27
+00:02:36,220 --> 00:02:43,110
+الكيمياع الحيويةطبعا بدنا نبدأ مباشرة مابضيقش وقت
+
+28
+00:02:43,110 --> 00:02:47,830
+الفصل الأول في المقدمة في الكيمياء الأضوية مفاهيم
+
+29
+00:02:47,830 --> 00:02:51,750
+عامة بالذات أنه يعني أنتوا أخدتوا شغلتين أخدتوا
+
+30
+00:02:51,750 --> 00:02:56,730
+كيمياء عامة في الجامعة و أخدتوا أشياء مختلفة من
+
+31
+00:02:56,730 --> 00:03:02,090
+الكيمياء في المدارس بعضها أحيانا أو جزء خفيف في
+
+32
+00:03:02,090 --> 00:03:06,830
+الكيمياء الأضويةهذه الاساسية المبادئ الأساسية
+
+33
+00:03:06,830 --> 00:03:11,710
+بتساعدكم في انكم تتعاملوا مع مساق الكيميا الأضوية
+
+34
+00:03:11,710 --> 00:03:19,130
+هذا الفصل اللي في المقدمة هنتكلم فيه عن الارتباط
+
+35
+00:03:19,130 --> 00:03:22,990
+والتشكل bonding and isomerism يعني طالما انه احنا
+
+36
+00:03:22,990 --> 00:03:28,650
+بنحكي عن مركبات في الكيميا الأضوية اكيد ذرات معينة
+
+37
+00:03:28,650 --> 00:03:34,950
+هترتبط تعطيمركب bonding الان هذه الذرات اللى
+
+38
+00:03:34,950 --> 00:03:40,550
+بترتبط يمكن ان ترتبط بطرق مختلفة وبالتالي يمكن ان
+
+39
+00:03:40,550 --> 00:03:46,910
+تعطي اكثر من مركب اكثر من شكل او متشكل تماما زى ما
+
+40
+00:03:46,910 --> 00:03:51,360
+انا هتعامل مع هذه الاقلامهنا بقدر اعمل ارتباط
+
+41
+00:03:51,360 --> 00:03:54,920
+بينهم كإني عملت مُركّب يعني لو تخيلتوا ان هدولة
+
+42
+00:03:54,920 --> 00:03:58,840
+تلت ذرات مثلا Carbon, Hydrogen, Oxygen عملوا
+
+43
+00:03:58,840 --> 00:04:03,820
+مُركّب بطريقة معينة الآن لو غيرت ترتيب هدول الذرات
+
+44
+00:04:04,600 --> 00:04:10,560
+بكون عملت بكون عملت مركب تاني واضح لو غيرت هدول
+
+45
+00:04:10,560 --> 00:04:14,760
+الذرات بكون عملت مركب تاني الآن المركب الأول و
+
+46
+00:04:14,760 --> 00:04:19,540
+المركب الثاني ما العلاقة بينهم هدول المركبين
+
+47
+00:04:19,540 --> 00:04:25,180
+بنسميهم ايش احنا isomers يعني لما بنقول المركب A و
+
+48
+00:04:25,180 --> 00:04:31,360
+المركب B they are isomers متشكلاتالآن الظاهرة كلها
+
+49
+00:04:31,360 --> 00:04:37,980
+إيش بنسميها isomerism، ظاهرة التشكل، و هنتعمق في
+
+50
+00:04:37,980 --> 00:04:43,280
+هذا الموضوع بالتأكيد أثناء دراستنا، نتعمق في هذا
+
+51
+00:04:43,280 --> 00:04:48,510
+الموضوع أثناءدراستنا الآن إذا بدنا نبدأ في موضوع
+
+52
+00:04:48,510 --> 00:04:53,950
+ال bonding طبعا مر عليكم أنواع الروابط مر عليكم
+
+53
+00:04:53,950 --> 00:04:57,770
+أنواع الروابط اللي بتكون في داخل الجزيئة ارجو
+
+54
+00:04:57,770 --> 00:05:01,390
+انكوا تنتبهوا اللي بقصده انا في ال bonding اللي
+
+55
+00:05:01,390 --> 00:05:06,270
+بقصده في ال bonding مش الروابط بين الجزيئات اللي
+
+56
+00:05:06,270 --> 00:05:11,070
+اسمها intermolecular forces لأ الروابط في داخل
+
+57
+00:05:11,070 --> 00:05:16,720
+الجزيئةالروابط في داخل الجزيئ يعني في روابط بين
+
+58
+00:05:16,720 --> 00:05:22,520
+الجزيئات مش هي المقصودة هنا يعني افترضوا مثلا جزيئ
+
+59
+00:05:22,520 --> 00:05:31,420
+الميّه H2O الان هذا جزيئ هذه جزيئ ميّه تاني HOO
+
+60
+00:05:33,470 --> 00:05:38,730
+الان هذه الروابط اللى فى داخل الجزئ هي اللى انا
+
+61
+00:05:38,730 --> 00:05:44,650
+بقصدها فى الكيميا بنعطيها اسم بنقول عنها intra
+
+62
+00:05:44,650 --> 00:05:49,650
+molecular bonds يعنى روابط within the molecule جوا
+
+63
+00:05:49,650 --> 00:05:54,030
+الجزئ يعنى هذه الروابط شو بيقول عنها intra
+
+64
+00:05:56,090 --> 00:06:01,750
+موليكيولار بوندي انترا يعني روابط جوه الجزيه الان
+
+65
+00:06:01,750 --> 00:06:04,550
+اذا اجيت بعد هيك بقول مثلا في عندى روابط
+
+66
+00:06:04,550 --> 00:06:09,620
+هيدروجينية بين ال اكسجون و الهيدروجينهذه روابط بين
+
+67
+00:06:09,620 --> 00:06:15,160
+الجزيئات Intermolecular forces فميزوا الكلمتين
+
+68
+00:06:15,160 --> 00:06:20,940
+Intramolecular اللي هي الروابط الأصلية القوية اللي
+
+69
+00:06:20,940 --> 00:06:25,720
+في داخل الجزيئ بينما الروابط بين الجزيئات between
+
+70
+00:06:25,720 --> 00:06:31,070
+molecules شو بسميها أنا؟Intermolecular forces
+
+71
+00:06:31,070 --> 00:06:37,790
+الأقوى نوع في الـ Intermolecular forces هذه قوته
+
+72
+00:06:37,790 --> 00:06:42,230
+مابتيجيش خمسة لعشرة في المية من قوة هذه الروابط
+
+73
+00:06:42,230 --> 00:06:47,250
+بمعنى لو أنا بدي أكسر الروابط من اللي سهل أني
+
+74
+00:06:47,250 --> 00:06:53,210
+أكسره ال Intermolecular forces تماما زي ما نتخيل
+
+75
+00:06:53,210 --> 00:06:59,070
+اتنين بيجوا بيسلموا على بعضفي رابطة أصلية .. رابطة
+
+76
+00:06:59,070 --> 00:07:04,750
+هذا الكف مع الجسم .. هذي Intramolecular وفي رابطة
+
+77
+00:07:04,750 --> 00:07:08,010
+بين التنين اللي بيسلموا مع بعض .. هذي
+
+78
+00:07:08,010 --> 00:07:13,110
+Intermolecular الأن لو ولدين صغار سلموا مع بعض و
+
+79
+00:07:13,110 --> 00:07:16,550
+الام كل واحدة بدها تسحب ابنها و تمشي في طريقها ..
+
+80
+00:07:16,550 --> 00:07:22,030
+بيسحبوا الولد أن هي اللي بتنكسر .. هذي الرابطة ولا
+
+81
+00:07:22,030 --> 00:07:26,400
+هذي الرابطة؟هذه الرابطة الـ Intermolecular Forces
+
+82
+00:07:26,400 --> 00:07:29,500
+فالـ Intermolecular Forces اللي منها الـ London
+
+83
+00:07:29,500 --> 00:07:32,740
+Forces و الـ Dipole-Dipole Attractions و الـ
+
+84
+00:07:32,740 --> 00:07:37,780
+Hydrogen Bonding هذه روابط ضعيفة بين الجزيئات
+
+85
+00:07:37,780 --> 00:07:41,500
+بتأثر بشكل كبير على الخواص الفيزيائية لكن لما انا
+
+86
+00:07:41,500 --> 00:07:46,600
+بدأ ادرس تفاعلات و اقول ان التفاعل الكيميائي بعد
+
+87
+00:07:46,600 --> 00:07:52,500
+شوية كسر وتكوين روابط انا لا اتكلم اطلاقا عن هذه
+
+88
+00:07:52,500 --> 00:07:57,340
+الروابطأنا بتكلم عن الروابط within the molecule
+
+89
+00:07:57,340 --> 00:08:02,640
+الـ Intramolecular forces و لما الآن بنصنف أنواع
+
+90
+00:08:02,640 --> 00:08:07,860
+هذه الروابط و بنحكي ionic bonds و covalent bonds و
+
+91
+00:08:07,860 --> 00:08:11,680
+coordinate covalent bonds بنكون بنحكي عن الروابط
+
+92
+00:08:11,680 --> 00:08:18,580
+اللي في جوة الجزء الـ Intramolecularواضح؟ اللي
+
+93
+00:08:18,580 --> 00:08:24,020
+بتكون الجزء نفسه الان من هذه الروابط زي ما سبق
+
+94
+00:08:24,020 --> 00:08:27,540
+انكم اتعلمتوا من هذه الروابط زي ما سبق انكم
+
+95
+00:08:27,540 --> 00:08:33,020
+اتعلمتوا ال ionic bonds ال ionic bonds بتنشأ لما
+
+96
+00:08:33,020 --> 00:08:37,680
+بيتكون عند أيونات في عناصر معينة عندها إلكترونات
+
+97
+00:08:37,680 --> 00:08:42,080
+زيادة عادة بتكون موجودة في أول الجدول الدوري على
+
+98
+00:08:42,080 --> 00:08:47,840
+اليساربنسميها electropositive atoms زي الصوديوم
+
+99
+00:08:47,840 --> 00:08:51,240
+على سبيل المثال وكلكوا عارفين تركيبه الإلكتروني
+
+100
+00:08:51,240 --> 00:08:57,780
+1s2 2s2 2b6 3s1 لإن عنده إلكتروني زيادة لو فقدوا
+
+101
+00:08:57,780 --> 00:09:02,600
+بيصل ال octet structure واضح لكن لما بيفقدوا هيصير
+
+102
+00:09:02,600 --> 00:09:08,580
+عبارة عن ايونموجة في عند ذرات بنقول عنها electro
+
+103
+00:09:08,580 --> 00:09:13,000
+negative atoms هدولة نقصهم إلكترون عشان يصلوا لل
+
+104
+00:09:13,000 --> 00:09:18,480
+octet structures هدولة لو اكتسبوا لو اكتسبوا هذا
+
+105
+00:09:18,480 --> 00:09:25,500
+الإلكترون بيصيروا ايوناتسالبة زي الكلور مثلا 1s2
+
+106
+00:09:25,500 --> 00:09:32,320
+2s2 2b6 بعدين بيصير عندي 3s2 3b5 هذا ال 3b5 ما زال
+
+107
+00:09:32,320 --> 00:09:37,660
+عنده وسع لإيش لإلكترون واحد لو اكتسب هذا الإلكترون
+
+108
+00:09:37,660 --> 00:09:42,890
+طبعا هيكتسب أي إلكترون اللي فقط الصوديومهيصير كلور
+
+109
+00:09:42,890 --> 00:09:47,990
+سالب اذا هنا صار في عندك صوديوم موجب و صار عندك
+
+110
+00:09:47,990 --> 00:09:51,490
+كلور سالب هدول ال ايونات لما بيعملوا ال attraction
+
+111
+00:09:51,490 --> 00:09:57,690
+مع بعض بيكونوا ليه ال ionic bond واضح طبعا ممكن
+
+112
+00:09:57,690 --> 00:10:02,250
+بعض العناصر اللي في المجموعة الثانية يفقدوا
+
+113
+00:10:02,250 --> 00:10:07,880
+إلكترونين و بيكونواIon موجب اتنين ممكن يفقدوا
+
+114
+00:10:07,880 --> 00:10:11,240
+تلاتة مثلا زي الالمنيون موجب تلاتة كل هذا الكلام
+
+115
+00:10:11,240 --> 00:10:16,360
+بتاعي اللي عرفته وكيف نكتب صيغة مركب ايوني هذا
+
+116
+00:10:16,360 --> 00:10:20,720
+الكلام كله بيمور وين عندنا في الكيمياء العامة
+
+117
+00:10:20,720 --> 00:10:29,460
+بالنسبة ل ال covalent compounds بيفرقوا بشغلة انه
+
+118
+00:10:30,790 --> 00:10:35,610
+الروابط اللي بتتكون تتكون نتيجة مشاركة في
+
+119
+00:10:35,610 --> 00:10:39,210
+الإلكترونات يعني هذه عندها إلكترونات معينة هذه
+
+120
+00:10:39,210 --> 00:10:43,990
+عندها إلكترونات بيعملوا sharing للإلكترون فكل ذرة
+
+121
+00:10:43,990 --> 00:10:48,370
+بتصل للتركيب اللي هو المستقر إذا كنا بنحكي عن
+
+122
+00:10:48,370 --> 00:10:51,710
+هيدروجين كل ذرة بتصير اتنين و اتنين زي مثلا ما
+
+123
+00:10:51,710 --> 00:10:56,330
+نتخيل هيدروجين فيه إلكترونهذا مش يبين وهيدروجين
+
+124
+00:10:56,330 --> 00:11:00,050
+فيه إلكترون هيعملوا جزء الهيدروجين كأنه الآن كل
+
+125
+00:11:00,050 --> 00:11:03,590
+ذرة هيدروجين عندها كام إلكترون اتنين هذا التركيب
+
+126
+00:11:03,590 --> 00:11:09,840
+ثابت أو الكلور مثلا مداره الأخيرفي سبع إلكترونات
+
+127
+00:11:09,840 --> 00:11:14,460
+الـ valence shell اللى موجود فيه الآن لما أنا بحكي
+
+128
+00:11:14,460 --> 00:11:18,940
+عن سبع إلكترونات لو صار مشاركة في هدول الإلكترونات
+
+129
+00:11:18,940 --> 00:11:23,780
+صارت كل ذرّة كلور كام إلكترون حولها تمانية إذا
+
+130
+00:11:23,780 --> 00:11:29,240
+عملنا covalent compound كذلك لو بدى أخد H مع CL
+
+131
+00:11:29,240 --> 00:11:36,830
+برضه الرابط أيش بتكون covalent bondالـ bonds هذه
+
+132
+00:11:36,830 --> 00:11:42,130
+الـ bonds هذه في إلها إشي بنسميه bond energy هذا
+
+133
+00:11:42,130 --> 00:11:47,530
+تعبير عن قوة الروابط ال bond energy هو الطاقة
+
+134
+00:11:47,530 --> 00:11:54,570
+اللازمة لكسر روابط واحد مول من الروابط الواحد مول
+
+135
+00:11:54,570 --> 00:11:59,410
+عرفينه عدد مضاعف عدد ال 26 من الف في عشر أقصى
+
+136
+00:11:59,410 --> 00:12:04,030
+تلاتة وعشرينالان عشان اكسر هذه الروابط .. هاي
+
+137
+00:12:04,030 --> 00:12:08,590
+رابطة .. لما اقول بدي اكسر الرابطة .. ايش بدي؟بدي
+
+138
+00:12:08,590 --> 00:12:14,870
+طاقة دايما معروف عندنا انه كسر الرابطة عملية بحاجة
+
+139
+00:12:14,870 --> 00:12:21,590
+الى طاقة بقول عنها endothermic process بينما تكوين
+
+140
+00:12:21,590 --> 00:12:26,810
+الرابطة عملية طاردة للطاقة بقول عنها exothermic
+
+141
+00:12:26,810 --> 00:12:31,930
+process فال bond energy هي الطاقة اللي لازم الكسر
+
+142
+00:12:31,930 --> 00:12:36,170
+روابط او واحد مول من الروابط من ال covalent bonds
+
+143
+00:12:36,170 --> 00:12:41,180
+كذلكفي عندى إيش اسمه ال bond length ال bond length
+
+144
+00:12:41,180 --> 00:12:48,660
+هو المسافة المتوسطة ما بين ذرتين ليش مسافة متوسطة
+
+145
+00:12:48,660 --> 00:12:54,420
+لأنه الرابطة هي عبارة عن مسافة بالفراغ ليست ثابتة
+
+146
+00:12:54,420 --> 00:12:58,260
+يعني ذرتين بينهم مسافة معينة في الفراغ بنقول هدول
+
+147
+00:12:58,260 --> 00:13:03,240
+الذرتين بينهم إيش رابطة الآن هذه المسافة تزيد
+
+148
+00:13:03,240 --> 00:13:08,500
+وتقصرليست ثابتة تماما و لذلك احنا بناخد المسافة
+
+149
+00:13:08,500 --> 00:13:12,000
+المتوسطة بيصير عندنا ال bond length الآن ال bond
+
+150
+00:13:12,000 --> 00:13:17,660
+length يقاس عادة بال angstrom اللي هو واحد في عشر
+
+151
+00:13:17,660 --> 00:13:22,300
+أقص ناقص عشرة من المتر او بنقيسه في ال picometer
+
+152
+00:13:22,300 --> 00:13:28,140
+اللي هو واحد في عشر أقص ناقص اتنائش من المتر واضح
+
+153
+00:13:28,140 --> 00:13:34,010
+طبعا لما انقيس ال bond lengthبال بيكميتر هتطلع
+
+154
+00:13:34,010 --> 00:13:39,330
+أطوال الروابط عندنا سهلة الملاحظة وسهلة الحفظ يعني
+
+155
+00:13:39,330 --> 00:13:44,630
+خليني أفرجيكم كيف هي أنا بعطيكم مقارنة بين الرابطة
+
+156
+00:13:44,630 --> 00:13:49,590
+الأحادية هذه الرابطة اللي أنا بقصدها الأحادية
+
+157
+00:13:49,590 --> 00:13:52,890
+والثنائية والرابطة
+
+158
+00:13:54,550 --> 00:14:01,830
+الثلاثية الان لاحظوا ان عدد الروابط بيزيد احدية
+
+159
+00:14:01,830 --> 00:14:07,970
+ثنائية ثلاثية هذا احنا بنسميه ال bond order ايش ال
+
+160
+00:14:07,970 --> 00:14:11,490
+bond order ال bond order is the number of chemical
+
+161
+00:14:11,490 --> 00:14:15,850
+bonds between a pair of atoms عدد الروابط ما بين
+
+162
+00:14:15,850 --> 00:14:22,270
+ذرتين هل يترى هدول الروابط منها ذرتين احديةثنائية
+
+163
+00:14:22,270 --> 00:14:28,490
+ثلاثية ايش بسمي انا ال bond order الان انتبهوا معي
+
+164
+00:14:28,490 --> 00:14:31,970
+as the bond order increases يعني كل ما بزيد من
+
+165
+00:14:31,970 --> 00:14:36,150
+الرابط احدية لا ثنائية لا ثلاثية بقول the bond
+
+166
+00:14:36,150 --> 00:14:43,810
+will be stronger and shorter بتصير اقوى و اقصر
+
+167
+00:14:43,810 --> 00:14:48,270
+ليش؟ لان الرابط الاحدية هي عبارة عن sigma bond
+
+168
+00:14:49,600 --> 00:14:56,440
+الرابطة الثلاثية هي عبارة عن سيجما و باي و لذلك
+
+169
+00:14:56,440 --> 00:14:57,900
+أصبحت أقوى
+
+170
+00:15:06,370 --> 00:15:10,150
+بتخيلوها الأيام بتصير سهلة الفهم، هذه sigma bond
+
+171
+00:15:10,150 --> 00:15:15,350
+فقط، هذه sigma و by bond، هذه sigma و by و by، مين
+
+172
+00:15:15,350 --> 00:15:20,730
+أكتر واحدة فيها قوة؟ الرابطة الثلاثية، هذا الكلام
+
+173
+00:15:20,730 --> 00:15:25,930
+بنعكس وين؟ بنعكس على أمركتير مهم في الكيميا قوة
+
+174
+00:15:25,930 --> 00:15:31,430
+الرابط لان الرابط الثلاثية قوية اللى هى هل يترى
+
+175
+00:15:31,430 --> 00:15:36,950
+يمكن ان يصير دوران حول الرابط ولا لأ ولذلك اذا
+
+176
+00:15:36,950 --> 00:15:41,950
+احنا بدنا نيجي نتخيل انه باستعمال ال models نتخيل
+
+177
+00:15:41,950 --> 00:15:49,350
+انه احنا باستعمال ال models بدنا نعملروابط معينة
+
+178
+00:15:49,350 --> 00:15:54,030
+نعمل رابطة أحادية هاي رابطة أحادية لو بتطلع علي
+
+179
+00:15:54,030 --> 00:15:59,270
+هدولة في عندى إمكانية للدوران حول الرابطة الأحادية
+
+180
+00:15:59,270 --> 00:16:03,990
+رابطة ضعيفة ممكن الأشياء اللى موجودة هنا يكون فيها
+
+181
+00:16:03,990 --> 00:16:10,710
+دوران الان لو خلتها رابطة ثنائية بهذا الشكل وجربت
+
+182
+00:16:10,710 --> 00:16:16,490
+أني بدي ألف بيصير عندى ال rotationRestricted
+
+183
+00:16:16,490 --> 00:16:28,370
+rotation رابطة
+
+184
+00:16:28,370 --> 00:16:36,390
+ضعيفة رابطة ثنائية Restricted
+
+185
+00:16:36,390 --> 00:16:42,650
+rotationيعني دوران ممنوع forbidden rotation الان
+
+186
+00:16:42,650 --> 00:16:51,790
+لو خلتها رابطة ثلاثية بدت تصير اقوى و اقوى اطلاقا
+
+187
+00:16:51,790 --> 00:16:57,150
+مش ممكن يصير فيه دوران حول الرابطة الثلاثية او
+
+188
+00:16:57,150 --> 00:17:01,690
+ثنائية صعب جدا واضح هى اللى احنا بدنا نستفيده ان
+
+189
+00:17:01,690 --> 00:17:07,690
+الرابطة كل ما البند order تبعها زاد بتصير ايش اقوى
+
+190
+00:17:08,210 --> 00:17:13,710
+وبنفس الوقت الرابطة القوية بتكون رابطة أكثر الذرات
+
+191
+00:17:13,710 --> 00:17:17,690
+بيصيروا جراب من بعض فلو احنا بدنا نشوف طول الرابطة
+
+192
+00:17:17,690 --> 00:17:23,190
+في ال بيكوميتر لاحظوا الرابطة الأحدية 154 بيكوميتر
+
+193
+00:17:23,190 --> 00:17:31,270
+لما بتصير ثنائية 134 بيكوميتر لما بتصير أحدية 121
+
+194
+00:17:31,270 --> 00:17:39,100
+بيكوميتر فمين أكثر رابطة الرابطةالتلافية واضحة هذه
+
+195
+00:17:39,100 --> 00:17:44,440
+النقطة فهذا الكلام بناخده كقاعدة as the bond order
+
+196
+00:17:44,440 --> 00:17:50,000
+increases the bond will be stronger and shorter
+
+197
+00:17:50,000 --> 00:17:53,120
+بتصير الرابطة أقوى وأقصى
+
+198
+00:17:56,880 --> 00:18:01,980
+الان احنا بنعمل روابط بين ذرات مختلفة لعناصر
+
+199
+00:18:01,980 --> 00:18:06,240
+مختلفة في الكيميا العضوية في الكيميا العضوية ربما
+
+200
+00:18:06,240 --> 00:18:11,140
+اهم العناصر اللى بيعملوا عندنا الروابط ال carbon و
+
+201
+00:18:11,140 --> 00:18:14,940
+ال hydrogen ال oxygen ال nitrogen و ال halogens
+
+202
+00:18:16,050 --> 00:18:20,890
+واضح؟ الان يا ترى كل عنصر من هدول العناصر كام
+
+203
+00:18:20,890 --> 00:18:25,810
+رابطة بيعمل عندنا لازم نكون عارفين و هذا الكلام
+
+204
+00:18:25,810 --> 00:18:29,210
+هتلاحظوا يعني لو فتحتوا كتاب الكيميا العضوية من
+
+205
+00:18:29,210 --> 00:18:35,190
+أول صفحة لآخر صفحة هتلاقوا ان الكربون بيعمل أربع
+
+206
+00:18:35,190 --> 00:18:42,350
+روابط مش هتلاقوا ولا مركب ولا مركب في الكربون بخمس
+
+207
+00:18:42,350 --> 00:18:49,240
+روابط واضح النقطة؟مافيش في كل علم الكيميا العضوية
+
+208
+00:18:49,240 --> 00:18:53,600
+على طوله و عرضه مش هتلاقيه مركب الكربون فيه بخمس
+
+209
+00:18:53,600 --> 00:18:56,880
+روابط أثناء التفاعل بيكون قاعد بفقد رابطة بيعمل
+
+210
+00:18:56,880 --> 00:19:01,420
+رابطة هذه حالات أثناء التفاعل بتكون ناشطة و بترجع
+
+211
+00:19:01,420 --> 00:19:05,620
+للإيش للاربع اللي بيدرسم شكل مركب بيدرسم الكربون
+
+212
+00:19:05,620 --> 00:19:12,310
+بكام رابطة؟ باربع الأن في ورقة الامتحانحدث ولا حرج
+
+213
+00:19:12,310 --> 00:19:16,810
+بتعملوا على ال carbon خمس روابط و ست روابط و عشر
+
+214
+00:19:16,810 --> 00:19:25,420
+روابط كله ايش؟كله غلط مش كله ماشي اربع روابط الآن
+
+215
+00:19:25,420 --> 00:19:29,820
+خلّينا نطلع على هذه العناصر الأساسية الهيدروجين
+
+216
+00:19:29,820 --> 00:19:35,340
+عادة بيعمل رابطة واحدة فقط الكاربون بيعمل اربع
+
+217
+00:19:35,340 --> 00:19:42,090
+روابط النيتروجين بيعمل تلت روابط وبيبقى عليهزوج من
+
+218
+00:19:42,090 --> 00:19:45,270
+الإلكترونات يعني بيظل على ال nitrogen غير التلات
+
+219
+00:19:45,270 --> 00:19:50,250
+روابط زوج من الإلكترونات ال oxygen مشهور بنقول عنه
+
+220
+00:19:50,250 --> 00:19:55,870
+بيعمل رابطتين و يبقى عليه زوجان من الإلكترونات ال
+
+221
+00:19:55,870 --> 00:19:59,510
+halogens اللي هي الفلور و الكلور و البروم و اليود
+
+222
+00:19:59,510 --> 00:20:03,330
+اللي هم المجموعة السابعة في الجدول الدوري هدولة
+
+223
+00:20:03,330 --> 00:20:07,890
+بيعملوا رابطة واحدة و بيبقى عليهم كام زوج من
+
+224
+00:20:07,890 --> 00:20:13,190
+الإلكتروناتثلاث أزواج، واضح؟ الآن هي أنا راسم
+
+225
+00:20:13,190 --> 00:20:20,730
+مركّب كبيرلو بتتطلع عليه، كل رأس في هذا المركب
+
+226
+00:20:20,730 --> 00:20:25,770
+يمثل ذرة كربون إذا لاقيتوا إشي ناقص في أعداد
+
+227
+00:20:25,770 --> 00:20:30,270
+الروابط، معناه ذلك هذا الشيء اللي ناقص هو عبارة عن
+
+228
+00:20:30,270 --> 00:20:34,910
+هيدروجين اختصر في الكتابة لأنه إحنا عندنا شيء
+
+229
+00:20:34,910 --> 00:20:38,530
+بنسميه abbreviated structure اللي هو شكل مختصر
+
+230
+00:20:38,530 --> 00:20:43,590
+يعني اللي بينفهم ضمنه مرات مابنكتبهشواضح؟ اللي
+
+231
+00:20:43,590 --> 00:20:47,930
+بينفهم ضمنها مرات مابنكتبوش فلاحظوا مثلا هاي ذرات
+
+232
+00:20:47,930 --> 00:20:53,830
+ال carbon هذه carbon هذه carbon carbon كل هذه
+
+233
+00:20:53,830 --> 00:20:59,630
+الذرات كل رأس هنا في الرسم يعتبر ذرة carbon و هاي
+
+234
+00:20:59,630 --> 00:21:04,470
+كمان carbon لو بنطلع عليهم كلهم كلهم عليهم أربع
+
+235
+00:21:04,470 --> 00:21:08,610
+روابط إذا في إشي مبين أقل معنا ذلك هذا فيه
+
+236
+00:21:08,610 --> 00:21:15,600
+هيدروجين اختصراكتابة يعني هذه CH3EC مبينين أربع
+
+237
+00:21:15,600 --> 00:21:19,720
+روابط هنا يمكن تطلع كربون متصلة بكربون و كربون إذا
+
+238
+00:21:19,720 --> 00:21:24,240
+ما المختصر هنا ذرتين هيدروجين بتكون تفهموهم يعني
+
+239
+00:21:24,240 --> 00:21:27,600
+لما نقول إقرأوا إيش فيه هنا بتقولوا هذه عبارة عن
+
+240
+00:21:27,600 --> 00:21:33,180
+CH2مختصر من hydrogen و hydrogen كتابة هذه من بين
+
+241
+00:21:33,180 --> 00:21:37,380
+أربع روابط هذه من بين أربعة هذه carbon رابطة تنتين
+
+242
+00:21:37,380 --> 00:21:41,480
+و تنتين مع ال oxygen سليمة ال oxygen كم رابطة
+
+243
+00:21:41,480 --> 00:21:48,000
+تنتين ال oxygen هنا بطريقة تانيةرابطتين بمعنى انه
+
+244
+00:21:48,000 --> 00:21:51,600
+ممكن يكونوا رابطة ثنائية في نهاية العدد تنتين او
+
+245
+00:21:51,600 --> 00:21:56,540
+رابطتين احديتين مافيش مشكلة كذلك مع ال carbon ممكن
+
+246
+00:21:56,540 --> 00:22:01,580
+يكونوا اربع روابط احدية ممكن يكون رابطة ثنائية و
+
+247
+00:22:01,580 --> 00:22:07,200
+رابطتين احديات ممكن تلت روابط يعني رابطة ثلاثية و
+
+248
+00:22:07,200 --> 00:22:10,360
+رابطة احدية المهم المجموع يكون في النهاية ايش
+
+249
+00:22:10,360 --> 00:22:13,900
+اربعة المهم المجموع يكون في النهاية اربعة لاحظوا
+
+250
+00:22:13,900 --> 00:22:19,500
+ال halogen هنارابطة واحدة بيكون أكيد عليه أزواج
+
+251
+00:22:19,500 --> 00:22:23,580
+إلكترونات لو كنا محتاجين إيه لفهم تفاعل بنكتبها مش
+
+252
+00:22:23,580 --> 00:22:28,240
+محتاجين عادة مابنكتبهاش يعني لو كنت بدي أكمل أزواج
+
+253
+00:22:28,240 --> 00:22:33,000
+الإلكترونات هنا أكيد ال oxygen عليه زوجين أكيد ال
+
+254
+00:22:33,000 --> 00:22:36,100
+nitrogen عليه زوج أكيد ال halogen عليه تلاتة
+
+255
+00:22:36,100 --> 00:22:42,740
+بالمناسبةبالنسبة لموضوع الروابط رسم الأشكال زي ما
+
+256
+00:22:42,740 --> 00:22:47,440
+هتلاحظوا ربما بعد two or three slides انه احنا
+
+257
+00:22:47,440 --> 00:22:54,900
+بنرسم الأشكال بأكثر من طريقة بمعنى ممكن احنا نرسم
+
+258
+00:22:54,900 --> 00:23:01,620
+شكل مركب بتفصيل كامل يعني نبيّن فيهكل ذرة من
+
+259
+00:23:01,620 --> 00:23:05,500
+الذرات ممكن نبين في المراكب كل ذرة من الذرات زي ما
+
+260
+00:23:05,500 --> 00:23:14,600
+احنا رسمين هنا CH3 CH2 CH2 OH هذا قواعد الروابط
+
+261
+00:23:14,600 --> 00:23:18,740
+كلها بتنطبق عليه سليم الان لو هذا كنت بدي اكتبه
+
+262
+00:23:18,740 --> 00:23:26,880
+بطريقة الكتابة العادية هاكتبهCH3 CH2 CH2 OH لو بدى
+
+263
+00:23:26,880 --> 00:23:32,540
+اختصره باستعمال برامج الرسم هارسمه بهذا الشكل واحد
+
+264
+00:23:32,540 --> 00:23:36,860
+اتنين تلاتة الان هدوله اش يفهموا كرر رأس يفهم
+
+265
+00:23:37,630 --> 00:23:44,750
+carbon كرر اس يفهم carbon فانا لو شفت هذا المركب و
+
+266
+00:23:44,750 --> 00:23:51,110
+قلت لطالب اقرأ هذا الشكل المفروض هي تقرأه CH3 CH2
+
+267
+00:23:51,110 --> 00:23:58,260
+CH2 OH او مثلا لو شفت مركب زي هذاكل رأس carbon
+
+268
+00:23:58,260 --> 00:24:03,060
+يعني كم carbon عندى في هذا المركب خمس ذرات carbon
+
+269
+00:24:03,060 --> 00:24:09,500
+فيقرأ CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+270
+00:24:09,500 --> 00:24:09,800
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+271
+00:24:09,800 --> 00:24:10,480
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+272
+00:24:10,480 --> 00:24:10,480
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+273
+00:24:10,480 --> 00:24:10,520
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+274
+00:24:10,520 --> 00:24:14,220
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+275
+00:24:14,220 --> 00:24:14,280
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+276
+00:24:14,280 --> 00:24:15,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+277
+00:24:15,020 --> 00:24:21,380
+CH2 CH2 CH2بدنا نكون متعودين على معرفة الصيغة
+
+278
+00:24:21,380 --> 00:24:27,240
+الجزائية للمراكبات و حسابها و الروابط المختصرة على
+
+279
+00:24:27,240 --> 00:24:33,120
+طول احنا بمخنا ايش نعمل نجيبها و نحطها خليني
+
+280
+00:24:33,120 --> 00:24:40,450
+اعطيكمخليني أعطيكم مثال إضافي أعطيكم مثال إضافي
+
+281
+00:24:40,450 --> 00:24:49,190
+يعني لو على السريع جربنا مثلا أنه نرسم جزئ زي هيك
+
+282
+00:24:49,190 --> 00:25:02,150
+و هذا الجزئ عملنا فيه ناخد
+
+283
+00:25:02,150 --> 00:25:03,990
+ثانية في الرسم مش مشكلة
+
+284
+00:25:25,060 --> 00:25:30,720
+الان يا تورا هى عندكم جزيق و خلينا نكبره عشان
+
+285
+00:25:30,720 --> 00:25:36,720
+انتوا كلكم تشوفوه لو سألنا هذا الجزيق اللى موجود
+
+286
+00:25:36,720 --> 00:25:41,380
+قدامكم ايش صيغته الجزيقية؟ ايش اللى مبينه؟ ايش
+
+287
+00:25:41,380 --> 00:25:46,250
+اللى مختصر فيه؟واحدة تقولنا إيه صيغته الجزائية،
+
+288
+00:25:46,250 --> 00:25:54,630
+يعني كام carbon يوجد عندى في هذا الجزء؟ carbon؟
+
+289
+00:25:54,630 --> 00:25:57,270
+كل رأس بالنسبة ليه carbon؟
+
+290
+00:26:00,180 --> 00:26:05,660
+هذا اللي هنا Carbon، إذاً هذا صيرته الجزائية C5،
+
+291
+00:26:05,660 --> 00:26:12,800
+الان الأصعب شوية كم هيدروجين عندى في هذا الجزء
+
+292
+00:26:16,380 --> 00:26:21,680
+كل شي بتكون تكمله حسب ما اتفقنا الكربون لأربع
+
+293
+00:26:21,680 --> 00:26:28,320
+روابط النيتروجين لثلاثة الأكسجل لرابطتين كل ما هو
+
+294
+00:26:28,320 --> 00:26:36,020
+محدوث عبارة عن هيدروجين يعني هنا موجود عندي
+
+295
+00:26:36,020 --> 00:26:43,670
+هيدروجين هنا هيدروجين هنا هيدروجين هناتنتين
+
+296
+00:26:43,670 --> 00:26:47,530
+هيدروجين هنا عشان يصير الكاربون أربع هذه
+
+297
+00:26:47,530 --> 00:26:52,010
+النيتروجين كام رابط مابين عليها تنتين تنتين اذا
+
+298
+00:26:52,010 --> 00:27:04,070
+ينقصها عشان تصير تلت روابط هذه كاربون عدوهم
+
+299
+00:27:04,070 --> 00:27:10,460
+واحد اتنينأنا أكيد بقول الناس اللي بيقولوا رقم
+
+300
+00:27:10,460 --> 00:27:15,700
+مفرد هم الكلام الصح و قدوا انتوا اربع ستة تمانية
+
+301
+00:27:15,700 --> 00:27:26,900
+عشرة احداشر اذا ن ا واضحهي عدد الروابط و بالمناسبة
+
+302
+00:27:26,900 --> 00:27:30,920
+برنامج الرسم بإمكانه يحسب إن الصيغة تبعت هذا
+
+303
+00:27:30,920 --> 00:27:34,780
+المركب يعني لو علمناه كيميستر كالكوليت موليكيلار
+
+304
+00:27:34,780 --> 00:27:39,460
+فاليوز و كالكوليت و قلنا له لزجلنا إياهم هاي
+
+305
+00:27:39,460 --> 00:27:46,920
+الصيغة إيش حسبها البرنامج اقرأوا C5H11NO
+
+306
+00:27:46,920 --> 00:27:52,010
+زي ما احنا كتبناها ولا لأ زي ما احنا كتبناهاواضح؟
+
+307
+00:27:52,010 --> 00:27:57,110
+فعندكم انتوا برنامج الرسم موجود بإمكانكوا ترسموا
+
+308
+00:27:57,110 --> 00:28:02,770
+جزيئات زي ما بدكم بإمكانكوا ترسموا جزيئات زي ما
+
+309
+00:28:02,770 --> 00:28:08,110
+بدكم والبرنامج بحسبها وبالتالي بتقدروا تراجعوا
+
+310
+00:28:08,110 --> 00:28:12,110
+لنفسكم يعني حتى لو اجت طالبة قالت انا بدي بدل ما
+
+311
+00:28:12,110 --> 00:28:16,690
+هذه هيدروجين تكون زي هيك الان هذه ايش تصبح؟ carbon
+
+312
+00:28:20,260 --> 00:28:25,990
+هذا الآن تصبح carbon، كل رأس اسمه carbonهذه من
+
+313
+00:28:25,990 --> 00:28:29,530
+الأخطاء الشائعة جدا راجعنا نتبهولها ان احنا لما
+
+314
+00:28:29,530 --> 00:28:32,550
+بنحط رأس زي هيك زي هذا او زي هذا بتيجي الطالب
+
+315
+00:28:32,550 --> 00:28:36,630
+بتكتب عليه hydrogen لأ هذا الرأس يفهم على انه
+
+316
+00:28:36,630 --> 00:28:41,370
+carbon مش hydrogen و بالمناسبة لو بدكم تغلطوا
+
+317
+00:28:41,370 --> 00:28:46,570
+برامج الرسم عادة شاطرة و بتفهمكم يعني لو اجيتوا
+
+318
+00:28:46,570 --> 00:28:49,470
+تحطوا هنا على ال oxygen رابطة ثالثة يعني هذه
+
+319
+00:28:49,470 --> 00:28:54,070
+الرابطة نعص و نحط كمان رابطةلاحظوا إيش كتبلكوا
+
+320
+00:28:54,070 --> 00:28:59,650
+جملة؟ Valence exceeded on atoms زاد الإرتباط على
+
+321
+00:28:59,650 --> 00:29:04,390
+الذرّار، ليش؟ لأنه أنا قاعد بدأ أحط رابطتين هنا و
+
+322
+00:29:04,390 --> 00:29:09,690
+رابطة، قداش المجموع بيصير على ال oxygen، تلاتة
+
+323
+00:29:10,240 --> 00:29:15,300
+بالفعل ولذلك اعطاني اشارة تنبيه انه عدد الارتباط
+
+324
+00:29:15,300 --> 00:29:19,960
+زاد فانتوا في البيت اتعودوا ان عندكم برامج رسم
+
+325
+00:29:19,960 --> 00:29:24,480
+معينة او هذا البرنامج ايضا موجود عندكم بترسموا فيه
+
+326
+00:29:24,480 --> 00:29:28,700
+بتتدربوا كل ما رسمتوا اكتر اتعبتوا اكتربتتدربوا
+
+327
+00:29:28,700 --> 00:29:33,600
+أكتر على إنكوا تفهموا الأشكال بالشكل السليم، وهذه
+
+328
+00:29:33,600 --> 00:29:38,460
+مشكلة للمن مابتدربش وبيتعب من البداية، بيتغلب
+
+329
+00:29:38,460 --> 00:29:41,020
+أثناء دراسته للمسار
+
+330
+00:29:50,540 --> 00:29:55,560
+هذا بالنسبة للأشكال و كيف نرسمها بأكثر من طريقة و
+
+331
+00:29:55,560 --> 00:30:00,800
+احنا دائما في الكيميا بنفضل اي طرق الطريقة
+
+332
+00:30:00,800 --> 00:30:08,170
+المختصرة و انتوا بتكملوا الحساب في اللي هينكمالان
+
+333
+00:30:08,170 --> 00:30:14,050
+بيجينا برضه من المراجعات شيء متعلق في قطبية
+
+334
+00:30:14,050 --> 00:30:19,890
+الروابط متى تكون الرابطة قطبية و متى يكون الجزء
+
+335
+00:30:19,890 --> 00:30:25,870
+قطبيا، الرابطة بتكون قطبية يعني لها قطب موجب و قطب
+
+336
+00:30:25,870 --> 00:30:31,210
+سالبإذا اختلفت السالبية الـ electronegativity بين
+
+337
+00:30:31,210 --> 00:30:36,450
+الذرتين تعون الرابطة طبعا الذرة الأكثر سالبية تصبح
+
+338
+00:30:36,450 --> 00:30:42,290
+كأنها طرف سالب والأقل سالبية تصبح كأنها طرف موجب
+
+339
+00:30:42,290 --> 00:30:48,770
+وبنعبر عن هذا الكلام بوضع إشارة الشحنةالجزائية
+
+340
+00:30:48,770 --> 00:30:52,930
+بالحق partial positive أو partial negative في
+
+341
+00:30:52,930 --> 00:30:57,110
+عندنا احنا جدول للسالبية اعلى السالبيات اللي هي
+
+342
+00:30:57,110 --> 00:31:02,290
+سالبية الفلورين اربعة فمثلا لو كان عندكوا رابطة
+
+343
+00:31:02,290 --> 00:31:08,530
+بين الكاربون والفلورين بهذا الشكل هي كاربون الفلور
+
+344
+00:31:09,820 --> 00:31:14,040
+مين اللي سالبيتها أعلى؟ الـFloor الـFloor، إذا أي
+
+345
+00:31:14,040 --> 00:31:17,760
+طرف هيكون سالب؟ الـFloor أي طرف هيكون موجب؟
+
+346
+00:31:17,760 --> 00:31:23,060
+الـCarbon وقتها بنحط إشارة القطبية إما بهذا الشكل
+
+347
+00:31:23,060 --> 00:31:28,140
+يفهم إن هذا هو الطرف السالب وهذا هو الطرف الموجب
+
+348
+00:31:28,140 --> 00:31:33,820
+أو بنحطها بإشارة إن الـFloor بنقول عنه partially
+
+349
+00:31:33,820 --> 00:31:40,020
+negative والـCarbon partially positiveهذا بالنسبة
+
+350
+00:31:40,020 --> 00:31:43,820
+لقطبية الروابط الـ polarity of bonds it depends on
+
+351
+00:31:43,820 --> 00:31:46,820
+the electronegativity difference of the atoms
+
+352
+00:31:46,820 --> 00:31:52,560
+forming this bond بيعتمدوا على فرق السلبية لكن لو
+
+353
+00:31:52,560 --> 00:32:00,860
+مثلا قلنا جزء مثل البرومهل يا ترى هذا الجزء .. هذا
+
+354
+00:32:00,860 --> 00:32:05,900
+الرابط عفوا بين البروم و البروم بتكون قطبية؟ ليش؟
+
+355
+00:32:05,900 --> 00:32:09,780
+لأن هذه السلبية زي هذه السلبية فما بيكون في عنده
+
+356
+00:32:09,780 --> 00:32:17,650
+قطبية بين ذرتين مثل بعضهم تماماو هاي أمثلة كتير
+
+357
+00:32:17,650 --> 00:32:22,010
+بين الهيدروجين والكلور قطبية تعبر عنها بهذا الشكل
+
+358
+00:32:22,010 --> 00:32:25,250
+أو بهذا أو بهذا ال carbon و ال nitrogen ال carbon
+
+359
+00:32:25,250 --> 00:32:29,370
+و ال oxygen كل هذه أمثلة بإمكانكوا ترجعوها واضح أن
+
+360
+00:32:29,370 --> 00:32:34,630
+الذرتين لمكونات للرابطة مختلفات واحدة سلبيتها أكثر
+
+361
+00:32:34,630 --> 00:32:38,490
+هتكون هي الطرف السالب والتانية أقل هتكون هي الطرف
+
+362
+00:32:38,490 --> 00:32:44,270
+الموجبهذا الكلام بينقلنا لقطبية الجزائي الجزائي
+
+363
+00:32:44,270 --> 00:32:49,310
+يتكون من عدة روابط هل الجزائي بمجمله يكون قطبي ولا
+
+364
+00:32:49,310 --> 00:32:55,030
+لأ هذا الكلام بيعتمد على إن نجد المحاصلة لهذه
+
+365
+00:32:55,030 --> 00:33:01,210
+الروابط طبعا أي إنسان بده يوجد محاصلة لازم يفهم
+
+366
+00:33:01,210 --> 00:33:05,950
+الشكل يعني لو أنا قلتلكم هذه الطاولة بيأثر عليها
+
+367
+00:33:05,950 --> 00:33:12,210
+قوتين ما المحاصلة؟هتقولولي مباشرة احكيلنا كيف شكل
+
+368
+00:33:12,210 --> 00:33:15,610
+القوتين، والله إذا القوتين كانوا من هذه الجهة
+
+369
+00:33:15,610 --> 00:33:20,690
+بيدغطوا، الطاولة هتمشي، هتنجمع القوة الأولى مع
+
+370
+00:33:20,690 --> 00:33:24,150
+القوة التانية، لو القوتين واحدة بهذا الشكل، واحدة
+
+371
+00:33:24,150 --> 00:33:29,930
+من اتجاه المعاكسهيسطبوا بعض إذا لكي أعرف المحصلة
+
+372
+00:33:29,930 --> 00:33:34,130
+لابد إلا أن أعرف الشكل الهندسي والأصل إن هذا موضوع
+
+373
+00:33:34,130 --> 00:33:38,530
+بتتعلموه في الكيميا العامة مش مجالنا الآن إننا
+
+374
+00:33:38,530 --> 00:33:42,350
+ناخد ال geometrical structures لكن خلّيني أخد عدة
+
+375
+00:33:42,350 --> 00:33:46,990
+أمثلة مثلا درسنا إحنا إن الشكل الهندسي لثاني أكسيد
+
+376
+00:33:46,990 --> 00:33:51,810
+الكربون ليليا الآن الأكسجين عندها قطبية أكتر من
+
+377
+00:33:51,810 --> 00:33:56,260
+الكربونبناء ع ذلك لو بدأ احكي عن carbon oxygen
+
+378
+00:33:56,260 --> 00:34:01,840
+bond لها قطبية بهذا الشكلوهذه كمان القطمية بهذا
+
+379
+00:34:01,840 --> 00:34:05,800
+الشكل ايش بتلاعبوا في القطميتين؟ شطبوا بعض فالجزء
+
+380
+00:34:05,800 --> 00:34:09,860
+صار non-polar ال carbon dioxide لايه non-polar
+
+381
+00:34:09,860 --> 00:34:14,460
+بينما لو اجيت للميه، الميه الشكل تبعها ايش ماله؟ V
+
+382
+00:34:14,460 --> 00:34:19,120
+-shaped او bent، منثني الآن، فيه اندهانة قطمية
+
+383
+00:34:19,120 --> 00:34:23,900
+بهذا الشكل وبهذا الشكل هدول قوتين جايين بزاوية
+
+384
+00:34:23,900 --> 00:34:31,010
+المحصلة بتاعتهم وين بتكون؟ بينهمزي هيك هيصف محصلة
+
+385
+00:34:31,010 --> 00:34:39,000
+الجزاء فجزاء الماء يصبح جزاء قطبة واضح؟لو أخدنا
+
+386
+00:34:39,000 --> 00:34:43,200
+جزء الميثين اللي مكوّن من أربع روابط و هناخد تفصيل
+
+387
+00:34:43,200 --> 00:34:47,420
+الشكل تبعه اللي هو tetrahedral structure بإمكاننا
+
+388
+00:34:47,420 --> 00:34:55,480
+الآن على السريع نعمل شكل لجزء الميثين حتى نتأكد أن
+
+389
+00:34:55,480 --> 00:35:01,380
+هذا الجزء يترى قطبي ولا غير قطبي هاي عندنا جزء
+
+390
+00:35:01,380 --> 00:35:09,510
+الميثين بالشكل ال tetrahedral رباع الأوجهو هدولة
+
+391
+00:35:09,510 --> 00:35:13,690
+اللونهم بوردجاني اللي هم كأنهم بيمثلوا إيش ال
+
+392
+00:35:13,690 --> 00:35:19,570
+hydrogens الآن بهذا الشكل يكون جزء الميثين لو أنا
+
+393
+00:35:19,570 --> 00:35:24,550
+إجيت اطلعت كل الروابط قطبية يعني هذا الجزء في أربع
+
+394
+00:35:24,550 --> 00:35:29,250
+روابط قطبية لكن هذه و هذه لو بدي أعمل له محاصلة
+
+395
+00:35:29,250 --> 00:35:35,310
+هندسية هذه محاصلتهم الهندسية واضح؟ إذا كأن أنا إيش
+
+396
+00:35:35,310 --> 00:35:40,170
+عملت لغيت هدولة التنتينوهي المحصلة تبعتهم
+
+397
+00:35:40,170 --> 00:35:44,110
+الهندسية، طيب في عندي كمان تنتين لورا، وين
+
+398
+00:35:44,110 --> 00:35:48,250
+محصلتهم؟ بينهم، هي حاطيت محصلة
+
+399
+00:35:51,050 --> 00:35:55,790
+صار عندى محاصيلتين عكس بعض فجزء الميثين في هذه
+
+400
+00:35:55,790 --> 00:36:00,070
+الحالة بيكون polar او non-polar؟ non-polar وكذلك
+
+401
+00:36:00,070 --> 00:36:05,550
+لو كان مثلا carbon tetrachloride يعني carbon متصل
+
+402
+00:36:05,550 --> 00:36:10,310
+بكمكلور يعني لو بدل هدول ال hydrogen كانوا كلهم
+
+403
+00:36:10,310 --> 00:36:16,160
+كلورينأربع روابط قطبية أه لكن محصلتها سفر هذا
+
+404
+00:36:16,160 --> 00:36:19,480
+الأمر مش مستغرب يعني لو انتوا اتيتوا مثلا على هذه
+
+405
+00:36:19,480 --> 00:36:23,660
+الطاولة جيبتوا أربع رجال أشداء كل واحد عنده قوة
+
+406
+00:36:23,660 --> 00:36:27,400
+واحد بيضغط بهذا الشكل واحد بهذا الشكل واحد بهذا
+
+407
+00:36:27,400 --> 00:36:32,400
+الشكل واحد بهذا الشكل هل ستتحرك الطاولة؟ في عندى
+
+408
+00:36:32,400 --> 00:36:38,280
+أربع قوة لكن محصلتها إيش؟ سفرواضح هذه الفكرة، إذا
+
+409
+00:36:38,280 --> 00:36:45,540
+قطبية الجزيئات تعتمد على شكلها الهندسي، على محصلة
+
+410
+00:36:45,540 --> 00:36:47,500
+قطبية الروابط
+
+411
+00:36:50,510 --> 00:36:55,770
+ما فهمنا احنا الآن ظاهرة ال isomerism او تكون ال
+
+412
+00:36:55,770 --> 00:37:00,550
+isomers سبق انه احنا قلنا ان ال isomers يمكن هذه
+
+413
+00:37:00,550 --> 00:37:05,510
+ال slide شوية صغيرة خليني انا اعمل نسخة اكبر منها
+
+414
+00:37:05,510 --> 00:37:09,730
+شوية ال isomers they are different compounds that
+
+415
+00:37:09,730 --> 00:37:14,130
+have the same molecular formula اكثر من مركب لهم
+
+416
+00:37:14,130 --> 00:37:17,750
+نفس الصيغة الجزائية زي ما عملنا في البداية هاي
+
+417
+00:37:17,750 --> 00:37:22,700
+مثلا مركب بصيغة جزائيةأسود أزرق أحمر هاي مركب
+
+418
+00:37:22,700 --> 00:37:28,060
+بصيغة جزائية تانية الان المركب الأول و المركب
+
+419
+00:37:28,060 --> 00:37:32,640
+الثاني شو أنا بسميهم isomers فال isomers they are
+
+420
+00:37:32,640 --> 00:37:35,840
+different compounds that have the same molecular
+
+421
+00:37:35,840 --> 00:37:40,320
+formula الان طالما the same molecular formula لو
+
+422
+00:37:40,320 --> 00:37:44,780
+ناس قالوا the same number of atoms ما هي ال
+
+423
+00:37:44,780 --> 00:37:49,740
+molecular formulaعدد ذرات لو ناس قالوا the same
+
+424
+00:37:49,740 --> 00:37:54,700
+molecular weightكله تعبير عن نفس الفكرة طالما نفس
+
+425
+00:37:54,700 --> 00:38:01,700
+العدد من الذرات إذا نفس الوزن فكل من هذه التعريف
+
+426
+00:38:01,700 --> 00:38:04,380
+يجوز لنا الناس تعمله different compounds that have
+
+427
+00:38:04,380 --> 00:38:07,260
+the same molecular formula the same number of
+
+428
+00:38:07,260 --> 00:38:11,040
+atoms the same molecular weight كل هذا الكلام
+
+429
+00:38:11,040 --> 00:38:16,240
+بيمشي كتعريف لل isomers الآن ال isomers بشكل عام
+
+430
+00:38:16,240 --> 00:38:22,710
+تقسم إلى نوعيننوع بنسميه constitutional isomers
+
+431
+00:38:22,710 --> 00:38:29,010
+وبياخد اسم تاني structural isomersStructural يعني
+
+432
+00:38:29,010 --> 00:38:34,490
+بنائي و نوع بنسميه stereo isomers فراغي إذا في
+
+433
+00:38:34,490 --> 00:38:42,170
+عندى متشكلات بنائية و متشكلات فراغية المتشكلات
+
+434
+00:38:42,170 --> 00:38:45,690
+البنائية ال structural أو ال constitutional
+
+435
+00:38:45,690 --> 00:38:50,910
+isomers بتكون الذرات نفسها مرتبطة مع بعض البعض
+
+436
+00:38:50,910 --> 00:38:56,760
+بطرق مختلفةيعني لو افترضت عندى تلت ذرات تنتين
+
+437
+00:38:56,760 --> 00:39:01,940
+Carbon و واحدة Oxygen هل يا ترى هدولة مربوطين
+
+438
+00:39:01,940 --> 00:39:07,760
+Carbon Carbon Oxygen ولا Carbon Oxygen Carbon و
+
+439
+00:39:07,760 --> 00:39:13,180
+بعدين نكمل الهيدروجينات هنا عندى different bonding
+
+440
+00:39:14,310 --> 00:39:19,050
+واضح؟ carbon carbon oxygen غير عن carbon oxygen
+
+441
+00:39:19,050 --> 00:39:23,590
+carbon فلو انا اجيت كملت المراكبات هاي المراكبة ده
+
+442
+00:39:23,590 --> 00:39:29,110
+carbon carbon oxygen CH3 CH2 OH صار عندي مراكب
+
+443
+00:39:29,110 --> 00:39:38,470
+اسمه الاثانون لو اجيت قولت CH3 OCH3 صار عندي مراكب
+
+444
+00:39:38,470 --> 00:39:47,340
+تاني اسمه dye مثل etherثنائي مثل ال ether فهذا
+
+445
+00:39:47,340 --> 00:39:50,760
+اللي بيميز ال structural isomers they have
+
+446
+00:39:50,760 --> 00:39:55,840
+different bonding different names طالما الارتباط
+
+447
+00:39:55,840 --> 00:40:01,060
+اختلف اذا كمان الاسماء هتصير ايش مختلفة فاول ما
+
+448
+00:40:01,060 --> 00:40:05,800
+بنقول احنا structural isomers بدنا نتذكر ان هدولة
+
+449
+00:40:05,800 --> 00:40:11,850
+فيهم ارتباط مختلف ولهم اسماء مختلفةالنوع التاني من
+
+450
+00:40:11,850 --> 00:40:17,450
+ال isomers نوع أصعب شوية ولذلك بندرسه احنا ب
+
+451
+00:40:17,450 --> 00:40:21,730
+chapter منفصل اللي هو الفصل الخامس من المادة هذه
+
+452
+00:40:21,730 --> 00:40:27,130
+بنسميه stereo isomers ال stereo isomers الذرات
+
+453
+00:40:27,130 --> 00:40:31,790
+بتكون لها نفس الارتباط يعني هنا أنا قولت same
+
+454
+00:40:31,790 --> 00:40:35,270
+different bonding في ال stereo isomers على طول
+
+455
+00:40:35,270 --> 00:40:40,850
+بقول sameconstitution أو same bonding نفس الارتباط
+
+456
+00:40:40,850 --> 00:40:46,410
+طب نفس الارتباط هوين بيختلفوا؟ بالشكل بالفراغ ممكن
+
+457
+00:40:46,410 --> 00:40:51,410
+أشياء يكون لها نفس الارتباط وتختلف بالشكل بالفراغ
+
+458
+00:40:51,410 --> 00:40:55,690
+الجواب أه بدي أعطيكم مثال من برا الكيميا لما
+
+459
+00:40:55,690 --> 00:41:00,430
+الطلاب في المدرسة بيجفوا بطابور الصبح هي إيد وجسمه
+
+460
+00:41:00,430 --> 00:41:06,270
+إيد هذا الارتباط إيش هو؟إيد وجسم وإيد، طب لو عملوا
+
+461
+00:41:06,270 --> 00:41:12,350
+هيك، هذا الشكل، لو عملوا هيك، هذا الشكل، الآن هل
+
+462
+00:41:12,350 --> 00:41:16,630
+تغير شيء في الإرتباط؟ إيد وجسم إيد
+
+463
+00:41:19,410 --> 00:41:22,950
+لو عملوا هيك، طب هدول الأشكال التلاتة، لو أخدت
+
+464
+00:41:22,950 --> 00:41:27,910
+تلات صور و حاطيتهم قدام الطالب وسألته ما العلاقة
+
+465
+00:41:27,910 --> 00:41:31,990
+بين هدول التلات صور، هيقول لي ال same bonding،
+
+466
+00:41:31,990 --> 00:41:36,150
+مافكتش ولا إيد من إيدين البني آدم، نفس الإرتباط،
+
+467
+00:41:36,150 --> 00:41:40,720
+طب أين الاختلاف؟بالشكل الفراغي إذا اللي بيميز ال
+
+468
+00:41:40,720 --> 00:41:45,060
+stereo isomers ال atoms have the same bonding the
+
+469
+00:41:45,060 --> 00:41:48,400
+same constitution بط different arrangement in
+
+470
+00:41:48,400 --> 00:41:52,320
+space لكن شكلهم بالفراغ بختلف طبعا هنتوسع فيهم
+
+471
+00:41:52,320 --> 00:41:56,220
+نلاحظ أنه في منهم نوع اسمه اناشو مارس و نوع اسمه
+
+472
+00:41:56,220 --> 00:42:01,340
+استيريو مارس كل هذا التوسع بيكون بفصل كامل اللي هو
+
+473
+00:42:01,340 --> 00:42:07,570
+الفصلالخامس ابهيك ابننهي اليوم و إلى لقاء آخر ان
+
+474
+00:42:07,570 --> 00:42:07,950
+شاء الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c8c4d934a7f4dc8383bcc7c8870547450df2cb4a
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.srt
@@ -0,0 +1,2212 @@
+1
+00:00:20,770 --> 00:00:26,070
+بسم الله الرحمن الرحيم المرة الماضية بدأنا معكم في
+
+2
+00:00:26,070 --> 00:00:30,810
+الفصل الثاني بونوان ال alkanes and cycloalkanes
+
+3
+00:00:30,810 --> 00:00:37,130
+ربما حكينا فكرة في البداية عن تصنيفات ال alkanes
+
+4
+00:00:37,130 --> 00:00:41,350
+أو ال hydrocarbons ل saturated alkanes بقولنا
+
+5
+00:00:41,350 --> 00:00:46,350
+هدولة نوعين اللي همالالكينز والسايكلوالكينز و
+
+6
+00:00:46,350 --> 00:00:50,110
+unsaturated hydrocarbons اللي منها المراكبات اللي
+
+7
+00:00:50,110 --> 00:00:52,470
+فيها double bond و triple bond في الالكينز
+
+8
+00:00:52,470 --> 00:00:59,290
+والالكاينز بدنا نتعرف على الالكينز وقلنا هذه سلاسل
+
+9
+00:00:59,290 --> 00:01:05,200
+وممكن أن تكون مراكباتمتفرعة وهذا يؤدي الى تكون عدد
+
+10
+00:01:05,200 --> 00:01:11,340
+كبير جدا من ال isomers او المتشكلات ال isomers زى
+
+11
+00:01:11,340 --> 00:01:16,780
+ما اتفقنا فى ال alkanes بتبدأ تظهر وقتاش لما بنصل
+
+12
+00:01:16,780 --> 00:01:20,080
+لاربع ذرات كربون يعنى لو عندنا ذرة كربون واحدة
+
+13
+00:01:20,080 --> 00:01:24,480
+عندنا مركب واحد فقط ميثين بعدين ايثين بروبين هذا
+
+14
+00:01:24,480 --> 00:01:28,900
+منه مركب واحد لكن لما ابدي اجى احط اربع ذرات كربون
+
+15
+00:01:28,900 --> 00:01:34,130
+ارتبهمصار في عنده احتمالين لترتيبهم اما ان يرتبوا
+
+16
+00:01:34,130 --> 00:01:39,850
+بشكل متسلسل chain structure و بيكون اسم المركب
+
+17
+00:01:39,850 --> 00:01:45,210
+بيوتين او بشكل branch و بيكون اسم المركب ايزو
+
+18
+00:01:45,210 --> 00:01:48,770
+بيوتين و اتكلمنا بعد هيك عن البنتين انه بيكون
+
+19
+00:01:48,770 --> 00:01:53,930
+تلاتة isomers و بعد ذلك اعطيناكم واجب انكوا تجربوا
+
+20
+00:01:53,930 --> 00:02:00,170
+انتوا تتعبوا و ترسموا الخمسةstructures of hexane
+
+21
+00:02:00,170 --> 00:02:06,010
+والمفروض يكون الأمر بالنسبة لكم مش صعب كثير انه
+
+22
+00:02:06,010 --> 00:02:10,830
+تجيبوا 6 ذرات كربون تجربوا ما لم تعملوا هذا الأمر
+
+23
+00:02:10,830 --> 00:02:14,230
+بالإيد و بالجلم لرصاص و بالورق و تتعبوا فيه كثير
+
+24
+00:02:14,230 --> 00:02:20,770
+مابفيدش ان انا اعمله بكل الأحوال هذه وجفنا
+
+25
+00:02:20,770 --> 00:02:26,630
+اخر شي عند ال structure ofميثين وقولنا ان الميثين
+
+26
+00:02:26,630 --> 00:02:32,290
+ماخد الـ tetrahedral structure اللي له أربعة أوجه
+
+27
+00:02:32,290 --> 00:02:38,390
+وهذا أفضل شئ نتعامل معه نرسمه بسهولة اننا نعمله
+
+28
+00:02:38,390 --> 00:02:41,810
+بالشكل اللي موجود بين اديكم تخيل انه عندنا مستويين
+
+29
+00:02:41,960 --> 00:02:48,200
+مستوى أفقي للأمام ومستوى متعامد عليه للخلف هذا
+
+30
+00:02:48,200 --> 00:02:51,960
+المستوى الأفقي للأمام بيكون فيه ذارتين هيدروجين في
+
+31
+00:02:51,960 --> 00:02:56,880
+زاوية 109.5 والمستوى الخلفي أيضا في ذارتين
+
+32
+00:02:56,880 --> 00:03:02,320
+هيدروجينبزاوية 109.5، الآن باقي الزاوية أيضًا 109
+
+33
+00:03:02,320 --> 00:03:05,940
+.5، يعني لو واحد .. لو واحدة بدأ تاخد بين هذه
+
+34
+00:03:05,940 --> 00:03:08,260
+الهيدروجين اللي في المستوى الأمامي و اللي في
+
+35
+00:03:08,260 --> 00:03:14,100
+المستوى الخلفي و انقيس الزاوية 109.5اللي اتوقفنا
+
+36
+00:03:14,100 --> 00:03:19,020
+عنده كيف يرسم هذا الشكل بالفراغ كيف يرسم هذا الشكل
+
+37
+00:03:19,020 --> 00:03:23,860
+بالفراغ قولنا أفضل شيء أنه نرسمه بهذه الطريقة
+
+38
+00:03:23,860 --> 00:03:29,920
+نستعمل ال wedges أو الأسافير بحيث أنه الأشياء اللي
+
+39
+00:03:29,920 --> 00:03:34,400
+للأمام عادة بنعملها ب solid wedge و الأشياء اللي
+
+40
+00:03:34,400 --> 00:03:39,360
+للخلف عادة بنعملها ب dashed wedgeواضح؟ وهذا اللي
+
+41
+00:03:39,360 --> 00:03:43,860
+موجود عندنا الان اذا احنا بندقيق شوية في هذا الشكل
+
+42
+00:03:43,860 --> 00:03:49,360
+هنلاحظ ان الوجه له رأس head و له base قاعدة
+
+43
+00:03:49,360 --> 00:03:56,250
+القاعدة اللي هي عريضة زي هذه و الرأساللي بيكون
+
+44
+00:03:56,250 --> 00:04:02,030
+رفيع هل يا ترى هناك معنى لما انا اجي ارسم مثلا هذا
+
+45
+00:04:02,030 --> 00:04:07,370
+solid wedge تكون القاعدة فيه على جهة الهيدروجين و
+
+46
+00:04:07,370 --> 00:04:11,650
+الرأس على جهة الكاربون لما اجي ارسم ورا ال dashed
+
+47
+00:04:11,650 --> 00:04:16,690
+wedge تكون القاعدة على جهة الكاربون و الرأس على
+
+48
+00:04:16,690 --> 00:04:22,210
+جهة الهيدروجين هذا الكلام بالتأكيد له معنى شو
+
+49
+00:04:22,210 --> 00:04:27,730
+معنى؟ هذا تعبير عنالرسم في الفراغ دائما احنا
+
+50
+00:04:27,730 --> 00:04:32,070
+متعودين .. دائما احنا متعودين ان الشغلة اللى بتكون
+
+51
+00:04:32,070 --> 00:04:37,590
+قريبة علينا كبيرة بتبين كل ما بعدت عننا بتبين ايش
+
+52
+00:04:37,590 --> 00:04:41,150
+صغيرة يعني الناس اللى بيشوفوا الطائرة في المطار
+
+53
+00:04:41,150 --> 00:04:46,710
+طيارة كبيرة بتاخد خمسمية راكب واضح؟ لما بتبعد كتير
+
+54
+00:04:46,710 --> 00:04:53,610
+في السماء بتشوفوا الطائرة نقطة فكل شيء قريب علينا
+
+55
+00:04:54,670 --> 00:05:00,010
+كبير كلما بقعد صغر حتى لو انتوا بترسموا شارع مثلا
+
+56
+00:05:00,010 --> 00:05:02,950
+متعودين انكوا تقولوا هاي الإنسان هنا اللي بترسم
+
+57
+00:05:02,950 --> 00:05:09,970
+الشارع يبدأ الشارع عريض و كل ما بيبعد بيصير إيش؟
+
+58
+00:05:10,790 --> 00:05:16,210
+يصغر الان هذه الأشياء أيضا تعبير عن هذا الأمر يعني
+
+59
+00:05:16,210 --> 00:05:20,590
+لو انا امسكت هذا الشكل زي هيك هاي اللي موجودين في
+
+60
+00:05:20,590 --> 00:05:25,670
+المستوى الأفقي الان ايش القريب عليكم ذرات
+
+61
+00:05:25,670 --> 00:05:31,710
+الهيدروجين و كل ما بتروحوا على الكاربون بتبتعدوا
+
+62
+00:05:32,390 --> 00:05:38,870
+واضح و لذلك الوجه لما رسمناه خلناه عريض من عند
+
+63
+00:05:38,870 --> 00:05:43,430
+الهيدروجين و كل ما راح الكربون بيبعد بيصير ماخد
+
+64
+00:05:43,430 --> 00:05:49,690
+ايش؟ رأس المثلث فلاحظوا قريب و بيبعد عشان هيك
+
+65
+00:05:49,690 --> 00:05:55,830
+رسمناه عريض و بيصغر لو اجيت على الهيدروجين اللي في
+
+66
+00:05:55,830 --> 00:06:01,480
+الخلفأيش القريب عليكم اكثر ال carbon ولا ال
+
+67
+00:06:01,480 --> 00:06:05,580
+hydrogen؟ ال carbon و كل ما بتروحوا باتجاه ال
+
+68
+00:06:05,580 --> 00:06:12,000
+hydrogen بتبعدوا و لذلك هذا قريب بيبتعد، اذا ال
+
+69
+00:06:12,000 --> 00:06:18,780
+wedge تبعه سيبدأ كبيرامن عند الكربون و يصغر فلو
+
+70
+00:06:18,780 --> 00:06:23,900
+رسمت هذا بشكل معاكس بتكونوا بتعملوا غلط وهذا بيصير
+
+71
+00:06:23,900 --> 00:06:28,120
+جزء لما بترسموا أشكال دائما الشيء القريب عليكم
+
+72
+00:06:28,120 --> 00:06:32,280
+اعملوا الوجه تبعه قاعدته باتجاهكم و كل ما بيبعد
+
+73
+00:06:32,280 --> 00:06:39,000
+بيصغر واضح هذه الفكرة فهذا أمر يجب ان ينتبه له شكل
+
+74
+00:06:39,000 --> 00:06:44,200
+الوجه اللي للأمام و اللي للخلف الان ابتيجي نقطة
+
+75
+00:06:44,200 --> 00:06:50,590
+كثير مهمةلما احنا اضطرنا اضطرارا نرسم الشكل بهذه
+
+76
+00:06:50,590 --> 00:06:55,830
+الطريقة ليش؟ لأنه في اللوح مافيش إمكانية لشيء
+
+77
+00:06:55,830 --> 00:07:00,490
+الفراغي يعني مافيش عندي إمكانية أطلع هدول للأمام و
+
+78
+00:07:00,490 --> 00:07:06,090
+أرجع هدول للخلف فهذه الرسمة غير حقيقية الآن لما
+
+79
+00:07:06,090 --> 00:07:10,310
+باجي بقولكوا بدي أقيس الزوايا مابتكونش تقيسوا
+
+80
+00:07:10,310 --> 00:07:15,560
+الزوايا على أساس الشكلاللي مبين عندكم تقيسوها على
+
+81
+00:07:15,560 --> 00:07:20,120
+أساس الشكل الفراغي اللي موجود في ذهنكم ولذلك لما
+
+82
+00:07:20,120 --> 00:07:25,420
+أقول الزاوية بين الهيدروجين والكاربون والهيدروجين
+
+83
+00:07:25,420 --> 00:07:36,470
+على الرسمة مبينة 180180 لكن هي حقيقة جديش 109.5
+
+84
+00:07:36,470 --> 00:07:40,990
+كذلك الحال لو جيت قلتلكوا بدي الزاوية بين
+
+85
+00:07:40,990 --> 00:07:46,430
+الهيدروجين والكاربون والهيدروجين الآن على الرسمة
+
+86
+00:07:47,810 --> 00:07:54,230
+الزاوية كانت 180 لكنها حقيقة 109.5 فلو كنت معلم
+
+87
+00:07:54,230 --> 00:07:59,870
+بالأزرق و قلت له اكتبوا الزاوية ستكتبوها 109.5 مش
+
+88
+00:07:59,870 --> 00:08:06,040
+180 مابناش نخلط هذه الغلطةلو تخيلنا القاعدة ايضا
+
+89
+00:08:06,040 --> 00:08:11,680
+لو انا اجيت قلتلكم بدي الزاوية بين هذه الهيدروجين
+
+90
+00:08:11,680 --> 00:08:15,440
+اللي في المستوى الأفقي وهذه الهيدروجين الخلفية
+
+91
+00:08:15,440 --> 00:08:22,980
+الان هدولة هنا انبينين تسعين لكن هم حقيقة مية
+
+92
+00:08:22,980 --> 00:08:28,000
+وتسعة و نص ايضا واضح؟
+
+93
+00:08:29,450 --> 00:08:35,470
+فيجب الانتباه لهذا الأمر أن هذا الشكل ليس في مستوى
+
+94
+00:08:35,470 --> 00:08:40,630
+واحد وانما شكل في الفراغ وعندما تحدد الزوايا تبعته
+
+95
+00:08:40,630 --> 00:08:44,790
+يجب أن تحدد من الذهن تبعكه اللي اتعلم ان جميع
+
+96
+00:08:44,790 --> 00:08:50,970
+زوايا الـ tetrahedral structure قيمتها 109.5 كل
+
+97
+00:08:50,970 --> 00:08:55,970
+ذرة بعيدة عن التانيةمن خلال الكربون بزاوية 109.5
+
+98
+00:08:55,970 --> 00:09:03,410
+لا في زاوية شكل الميثين 90 ولا في زاوية 180 جميع
+
+99
+00:09:03,410 --> 00:09:07,510
+زاوية هيدروجين كربون هيدروجين من أي جهة بتاخدوها
+
+100
+00:09:07,510 --> 00:09:15,430
+قيمتها 109.5 هذا
+
+101
+00:09:15,430 --> 00:09:22,950
+بالنسبة لشكل الميثينإذا رجعنا لهذه ال slide اللي
+
+102
+00:09:22,950 --> 00:09:26,150
+اتكلمنا فيها عن ال الكانز بالتفصيل المميل قلنا
+
+103
+00:09:26,150 --> 00:09:30,690
+عندنا ميثين إيثين بروبين لحد البيوتين صار في عندنا
+
+104
+00:09:30,690 --> 00:09:36,330
+كام مركب اتنين الآن هدول بنسميهم الكانز من ال
+
+105
+00:09:36,330 --> 00:09:41,350
+الكانز بنطلع شغلة بنقولها ال kilogram لو يا ترى
+
+106
+00:09:41,350 --> 00:09:45,730
+احنا في نيتنا أنه بدنا نعمل تفاعل لما بدنا نعمل
+
+107
+00:09:45,730 --> 00:09:51,350
+التفاعل أول شيء أول شيء بدنا نعملهإنه بدنا نشيل
+
+108
+00:09:51,350 --> 00:09:58,870
+ذرة هيدروجين مثلا عشان نحط مكانها ذرة كلور الآن
+
+109
+00:09:58,870 --> 00:10:02,990
+لما أنا بشيل هيدروجين من الألكان يعني بدل ما
+
+110
+00:10:02,990 --> 00:10:12,030
+الميثين مثلا CH4 شو بده يصير CH3 وفي مكان سترتبط
+
+111
+00:10:12,030 --> 00:10:15,670
+به الذرة الجديدة نفترض اللي هي ذرة الكلور ممكن
+
+112
+00:10:15,670 --> 00:10:21,400
+نتخيل أنه لونها أخضرالان الالكين ناقص الهيدروجين
+
+113
+00:10:21,400 --> 00:10:27,180
+بسميه الكل جروب دائما الالكين ناقص الهيدروجين الكل
+
+114
+00:10:27,180 --> 00:10:32,520
+جروب فمن الميثين بطول مجموعة بسميها ايش مثل يعني
+
+115
+00:10:32,520 --> 00:10:40,940
+بستبدل ال N ب Y L بدل مثل N بصير مثل جروب دائما كل
+
+116
+00:10:41,530 --> 00:10:46,570
+نهاية اسم او شغلة فيها ال YL فانا بحكي عن الكلجروب
+
+117
+00:10:46,570 --> 00:10:52,330
+يعني ال cane مخصوم منه ذرة هيدروجين واضح؟ الان
+
+118
+00:10:52,330 --> 00:10:57,450
+لاحظوا لو هذه الذرة اتيت اعمل مركب طبعا المثل
+
+119
+00:10:57,450 --> 00:11:02,730
+مجموعة لكن لا تكون مركب يعني انا لما اخص منها
+
+120
+00:11:02,730 --> 00:11:07,290
+هيدروجينمباشرة مكانها الهيدروجين شو هتيجي تحط
+
+121
+00:11:07,290 --> 00:11:12,550
+اكلور نفترض الان لو كونت هذا المركب و بدي اعطيه
+
+122
+00:11:12,550 --> 00:11:19,010
+اسم باجي بسأل هذه المجموعة شو اسمها مثل وفي عند
+
+123
+00:11:19,010 --> 00:11:24,910
+اكلور فبقول المركب مثل اكلورايدبصير في ال common
+
+124
+00:11:24,910 --> 00:11:29,510
+nomenclature يعني التسمية المشهورة انه انا لو هنا
+
+125
+00:11:29,510 --> 00:11:34,110
+شيلت hydrogen و افترض و حطيت chlorine ايش هاسم
+
+126
+00:11:34,110 --> 00:11:41,070
+المركب اللي عندى مثل chloride هذه التسميةبنقول
+
+127
+00:11:41,070 --> 00:11:44,890
+عنها احنا ايش common nomenclature، ايش يعني
+
+128
+00:11:44,890 --> 00:11:49,350
+common؟ تسمية مشهورة، مش تسمية حسب القواعد، هناخد
+
+129
+00:11:49,350 --> 00:11:52,890
+نوعين من التسمية، في تسمية بنسميها IUPAC
+
+130
+00:11:52,890 --> 00:11:56,820
+Nomenclatureالتسمية لحسب القواعد اللي بنتعلمها
+
+131
+00:11:56,820 --> 00:12:00,620
+الآن وفيكم ال nomenclature التسمية المشهورة الان
+
+132
+00:12:00,620 --> 00:12:05,620
+التسمية المشهورة في مثل هذه المراكبات كيف بتتم من
+
+133
+00:12:05,620 --> 00:12:11,140
+خلال ذكر اسم المجموعة و بعد هيك بذكر اسم الهالوجين
+
+134
+00:12:11,140 --> 00:12:15,480
+فمن ال مثل لما شيلت هيدروجين صارت مثل حطيت بدلها
+
+135
+00:12:15,480 --> 00:12:20,380
+كلوه بيصير المراكب مثل كلورايد لو حطيت بدلها بروم
+
+136
+00:12:21,110 --> 00:12:27,190
+مثل البروميد و هكذا واضح؟ الان بنفس المنطق لو اجيت
+
+137
+00:12:27,190 --> 00:12:32,770
+على الاثين كام هيدروجين في الاثين بالمجمل؟ ستة
+
+138
+00:12:32,770 --> 00:12:37,170
+لاحظوا الست ذرات هيدروجين اللي في الاثين كلهم زي
+
+139
+00:12:37,170 --> 00:12:40,990
+بعض متكافئات يعني لو شيلت اي واحدة منهم هعمل
+
+140
+00:12:40,990 --> 00:12:47,670
+مجموعة شو هسميها؟ اثل زي ما انا شيلت من الميثين من
+
+141
+00:12:47,670 --> 00:12:53,840
+الأربع المتكافئات هدولةهيدروجينة وسميت المجموعة
+
+142
+00:12:53,840 --> 00:12:58,860
+مثل بقدر انا من ال اثين ايضا اشيل هيدروجينة الست
+
+143
+00:12:58,860 --> 00:13:01,880
+هيدروجينات زي بعض اي واحدة بنشيلها بتعطينا نفس
+
+144
+00:13:01,880 --> 00:13:07,080
+المجموعة هنكون مجموعة اثل لو افترضنا هذه المجموعة
+
+145
+00:13:07,080 --> 00:13:10,740
+مكان الهيدروجين اللي شيلناها حطينا كلور شو هيصير
+
+146
+00:13:10,740 --> 00:13:18,440
+مثلا مركبة اثل كلورايد و هكذا طيب لو اجينا بعد هيك
+
+147
+00:13:18,440 --> 00:13:24,620
+للبروبينوقلنا من مركب البروبين بدنا نشيل هيدروجين
+
+148
+00:13:24,620 --> 00:13:32,000
+ونعمل مجموعة بروبين مثل مثل اثان اثل بروبين بروبين
+
+149
+00:13:32,000 --> 00:13:39,000
+بيوتين بيوتل هتلاحظوا انه هيبدأ يصير عندى مشكلة
+
+150
+00:13:39,000 --> 00:13:46,610
+صغيرة انهالبروبين في كام هيدروجين؟ تمانية هي تلاتة
+
+151
+00:13:46,610 --> 00:13:50,870
+و تلاتة زي بعض وفي هنا الهيدروجينتين اللي اتفقنا
+
+152
+00:13:50,870 --> 00:13:56,470
+انه اختصرناهم في الكتابة اذا شكله العام CH3 CH2
+
+153
+00:13:56,470 --> 00:14:02,830
+CH3 تمان هيدروجينات هذولة تمان هيدروجينات كام نوع؟
+
+154
+00:14:04,020 --> 00:14:07,900
+عبارة عن نوعين التلاتة هذول والتلاتة هذول اللي على
+
+155
+00:14:07,900 --> 00:14:12,400
+الطرف زي بعض وهذه اللي موجودين في النص زي بعض فال
+
+156
+00:14:12,400 --> 00:14:16,960
+تمان هيدروجينات تعون لبروبين نوعين ستة زي بعض
+
+157
+00:14:16,960 --> 00:14:21,800
+وتنتين زي بعض لو شيلت أي واحدة من هان او من هان
+
+158
+00:14:21,800 --> 00:14:26,640
+هعمل مجموعة ولو شيلت واحدة من هان هعمل مجموعة
+
+159
+00:14:26,640 --> 00:14:30,880
+ولذلك بتلاحظوا انه لما باجي بشيل هيدروجين من
+
+160
+00:14:30,880 --> 00:14:35,460
+البروبين بعمل مجموعتيناذا شيلت من الطرف وهي جاهز
+
+161
+00:14:35,460 --> 00:14:39,420
+انه يشبك من هنا من هنا خصمة الهيدروجين هذه معناه
+
+162
+00:14:39,420 --> 00:14:44,140
+الكلام هذا بسميها مجموعة البروبيل ولو بدي اشيل من
+
+163
+00:14:44,140 --> 00:14:50,220
+النص بدي تصير ايزو بروبيل فلاحظوا معي لو بعد هيك
+
+164
+00:14:50,220 --> 00:14:56,360
+اجينا نعمل مركب نضيف كلور ممكن ناس يقولوا حطلي
+
+165
+00:14:56,360 --> 00:15:02,420
+كلور هانأو محل الهيدروجين اللي شلتها في الحالة
+
+166
+00:15:02,420 --> 00:15:06,600
+الأولى شو هيصير اسم المُركّب؟ Isopropyl chloride
+
+167
+00:15:06,600 --> 00:15:11,240
+في الحالة التانية إيش هيصير اسم المُركّب؟
+
+168
+00:15:11,240 --> 00:15:13,020
+Isopropyl chloride
+
+169
+00:15:15,840 --> 00:15:20,340
+واضح؟ و لذلك بدكوا تكونوا منتبهين أن التلات
+
+170
+00:15:20,340 --> 00:15:27,720
+كربونات كم ألكين منهم؟ واحد .. كم ألكين؟ واحد اسمه
+
+171
+00:15:27,720 --> 00:15:33,900
+بروبيل .. كم ألكي لجروب؟ تنتين .. اسمهم بروبيل و
+
+172
+00:15:33,900 --> 00:15:38,660
+ايزو بروبيل .. واضح؟هذا الكلام أكيد بحاجة إلى
+
+173
+00:15:38,660 --> 00:15:44,120
+تدريب وحفظ بعد شوية بنجي على أربع ذرات كربون هنقول
+
+174
+00:15:44,120 --> 00:15:50,960
+الأربع ذرات كربون أساسا منهم كم مركب اتنين بيوتين
+
+175
+00:15:50,960 --> 00:15:57,500
+و ايزو بيوتين طب كم الكل جروب منهم؟ بدي أجي أطلع
+
+176
+00:15:57,500 --> 00:16:05,510
+هنا كم هيدروجين عندى؟في البيوتين العادى عشرة تلاتة
+
+177
+00:16:05,510 --> 00:16:10,950
+و اتنين و اتنين و تلاتة الان هدولة المختصرين لو
+
+178
+00:16:10,950 --> 00:16:18,270
+بيناهم بالاحمر وسألنا العشرة هيدروجين هدولة كام
+
+179
+00:16:18,270 --> 00:16:27,350
+نوع كام نوع هدول العشر هيدروجين نوعين كام نوع كداش
+
+180
+00:16:27,350 --> 00:16:34,450
+و كداشستة زي بعض اللي على الطرف والاربعة هدول زي
+
+181
+00:16:34,450 --> 00:16:38,410
+بعض يعني لو شيلت hydrogen من هان او هان او هان او
+
+182
+00:16:38,410 --> 00:16:44,130
+هدول نفس الاشي هيعطيني مجموعة اش اسمها الـbutyl
+
+183
+00:16:44,130 --> 00:16:48,190
+ولو شيلت اي واحدة من هدول الاربعة هادي او هادي او
+
+184
+00:16:48,190 --> 00:16:52,030
+هادي او هادي كأن بكون شيلت عن موقع اتنين يعني من
+
+185
+00:16:52,030 --> 00:16:55,490
+هان او من هان بشيل عن موقع واحد من هان او من هان
+
+186
+00:16:55,490 --> 00:17:02,320
+بشيل عن موقع اتنينصار عندى من نفس البيوتين العادى
+
+187
+00:17:02,320 --> 00:17:08,340
+كام مجموعة؟ تنتين واحدة بسميها butyl واحدة بسميها
+
+188
+00:17:08,340 --> 00:17:12,060
+secondary butyl secondary اللى احنا شيلنا فيها
+
+189
+00:17:12,060 --> 00:17:16,410
+الهيدروجين من carbon 2الـ Butyl اللي شيلنا فيها
+
+190
+00:17:16,410 --> 00:17:21,910
+الهيدروجين من Carbon-1 مرات كتيرة هتلاحظوا إضافة و
+
+191
+00:17:21,910 --> 00:17:26,270
+ممكن تقرؤوها في بعض الكتب أن هذا الـ Butane بيروح
+
+192
+00:17:26,270 --> 00:17:32,850
+و بيحطه قدام حرف الـ N معناه بيوتين عادي المتسلسل
+
+193
+00:17:32,850 --> 00:17:37,530
+فالـ N هذي جاية من كلمة إيش؟ Normal لـ Butane
+
+194
+00:17:37,530 --> 00:17:41,270
+العادي و المجموعة تبعته هتلاحظوا مرات بيحطوا
+
+195
+00:17:41,270 --> 00:17:46,390
+قدامها حرف الـ Nفإذا قرأنا بيوتين هو نفسه
+
+196
+00:17:46,390 --> 00:17:51,270
+الانبيوتين المتسلسل وإذا قرأنا المجموعة بيوتين هي
+
+197
+00:17:51,270 --> 00:17:55,770
+نفسها الانبيوتين يعني البيوتين العادية اللي من نمر
+
+198
+00:17:55,770 --> 00:18:01,690
+واحد منها شيلنا ذرة إيش الهيدروجين الآن لو حطينا
+
+199
+00:18:01,690 --> 00:18:06,300
+هنا كلور شو هتسمي المركب؟Butylic chloride طب لو
+
+200
+00:18:06,300 --> 00:18:11,440
+حطينا هنا secondary butylic chloride الان لو اجينا
+
+201
+00:18:11,440 --> 00:18:15,120
+على ال isomers التانى اللى من اربع كربونات اللى
+
+202
+00:18:15,120 --> 00:18:21,640
+اسمه ايش ايزو بيوتين و سألنا كام هيدروجين فيه اكيد
+
+203
+00:18:21,640 --> 00:18:27,900
+عشرة لأنه التنين C4H10 طيب اللى مبينين تسعة وين
+
+204
+00:18:27,900 --> 00:18:34,190
+العاشرةالمختصرة هنا عشان يكتمل الشكل الان هدول
+
+205
+00:18:34,190 --> 00:18:41,090
+العشر هيدروجينات كام نوع؟ إذا بتطلع عليهم ممتازة
+
+206
+00:18:41,090 --> 00:18:49,180
+نوعين التسعة هدول زي بعضوهذا الهيدروجين نوع تاني
+
+207
+00:18:49,180 --> 00:18:52,680
+لأن هذا على الطرف وهذا على الطرف وهذا على الطرف
+
+208
+00:18:52,680 --> 00:18:57,020
+وهذا جاء في قلب الجزء فهذه نوع و هذول التسعة زي
+
+209
+00:18:57,020 --> 00:19:01,440
+بعض بناء على ذلك لو شيلنا أي واحدة من هذول هنعمل
+
+210
+00:19:01,440 --> 00:19:09,160
+مجموعةماذا نسمي المجموعة؟ انظروا معي هنا CH3 CH
+
+211
+00:19:09,160 --> 00:19:12,920
+CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+212
+00:19:12,920 --> 00:19:12,920
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+213
+00:19:12,920 --> 00:19:13,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+214
+00:19:13,020 --> 00:19:13,200
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+215
+00:19:13,200 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+216
+00:19:13,560 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+217
+00:19:13,560 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+218
+00:19:13,560 --> 00:19:15,980
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+219
+00:19:15,980 --> 00:19:20,860
+CH2 CH2 CH2 CH2 CH2والعدد كله أربعة إذا هذه
+
+220
+00:19:20,860 --> 00:19:27,200
+المجموعة إيش اسمها Isobutyl هذه المجموعة اسمها
+
+221
+00:19:27,200 --> 00:19:30,680
+Isobutyl اللي شيلنا فيها هيدروجين سواء من هنا أو
+
+222
+00:19:30,680 --> 00:19:36,160
+من هنا أو من هنا هي Iso هذا الشكل بيعني Iso هذا
+
+223
+00:19:36,160 --> 00:19:40,120
+التفرع كاربون طالع منها مجموعتين مثل Iso لاحظوا
+
+224
+00:19:40,120 --> 00:19:46,290
+هنا كان عندكم تقريبا نفس الاشي انتبهوا معيcarbon
+
+225
+00:19:46,290 --> 00:19:50,190
+منها مجموعتين مثل شو قلنا ايزو العدد الكلي لل
+
+226
+00:19:50,190 --> 00:19:56,810
+carbons كم كان تلاتة ولذلك سمناها ايزو بروبل الان
+
+227
+00:19:56,810 --> 00:20:01,790
+carbon طالع منها مجموعتين مثل ايزو و العدد الكلي
+
+228
+00:20:01,790 --> 00:20:08,630
+اربعة اذا صارت ايزوبيوتل لو الان بدى اقولها واحدة
+
+229
+00:20:08,630 --> 00:20:13,050
+طيب ال ISO pentel مثلا او ال ISO hexel بتقدر
+
+230
+00:20:13,050 --> 00:20:21,410
+ترسمها اه ع طول بقول هي ال ISO CH3 CH3
+
+231
+00:20:21,410 --> 00:20:26,290
+CH3 الان هكذا صار عندى ISO لو قولت ISO pentel جداش
+
+232
+00:20:26,290 --> 00:20:33,220
+بدى يكون عندى خمسة خمسة اذا بدي كمان هنا CH2CH2 و
+
+233
+00:20:33,220 --> 00:20:37,100
+من هنا شيلت الهيدروجين خليني هادي مثلا لو حطيت
+
+234
+00:20:37,100 --> 00:20:41,720
+كلور هنا كل
+
+235
+00:20:41,720 --> 00:20:51,680
+المركب ايش حيصير ايزو اربعة خمسة بنتل اكلورايد لو
+
+236
+00:20:51,680 --> 00:20:59,960
+حطيت الكلور هنا ايزو بيتل اكلورايد واضح بهذا الشكل
+
+237
+00:20:59,960 --> 00:21:00,300
+بيكون
+
+238
+00:21:03,730 --> 00:21:08,510
+جزء ال ISO التلاتة هدول، الآن إذا بس صفيت عليهم
+
+239
+00:21:08,510 --> 00:21:13,470
+بقول ISO Propyl، زيدت Carbon؟ ISO Butyl، زيدت
+
+240
+00:21:13,470 --> 00:21:17,810
+Carbon؟ ISO Bentyl، الآن هنا بدكوا تنتبهوا، إذا
+
+241
+00:21:17,810 --> 00:21:23,250
+كان عندي شئ بينتهي بالنهاية YL، بحكي عن مجموعة،
+
+242
+00:21:23,250 --> 00:21:28,110
+إذا كان عندي شئ بينتهي بالنهاية N؟بحكي عن ال cane
+
+243
+00:21:28,110 --> 00:21:34,110
+يعني مثلا لو قلنا لطالبة بدنا رسمة ال ISO أكتين
+
+244
+00:21:34,110 --> 00:21:42,950
+اتخيلوا أجاكوا في الامتحان بدي ISO أكتين بتغلبش
+
+245
+00:21:42,950 --> 00:21:49,970
+مباشرة ال ISO كيف شكلها CH3 CH3
+
+246
+00:21:50,800 --> 00:21:56,600
+الان هى صار عندى جزء ال ISO بدي اكمل ل ألكين كم
+
+247
+00:21:56,600 --> 00:22:01,280
+carbon بدى يصير المجموع الكله تمانية اذا هى تلاتة
+
+248
+00:22:01,280 --> 00:22:09,160
+اربعة خمسة ستة سبعة تمانية وهنا بكتب ايش CH3 مش
+
+249
+00:22:09,160 --> 00:22:15,190
+شايل ولا هيدروجينه منه ليش لأنه نهاية N الكينلكن
+
+250
+00:22:15,190 --> 00:22:19,130
+لو كنت بدي الـ iso-octal group من وين هشيل
+
+251
+00:22:19,130 --> 00:22:25,890
+الهيدروجينة؟ من هذه الأخيرة واضح؟ الآن إذا هاي تسع
+
+252
+00:22:25,890 --> 00:22:28,410
+هيدروجينات زي بعض لو شيلت منهم هيدروجينة بطلّق
+
+253
+00:22:28,410 --> 00:22:33,370
+مجموعة isobutyl طب لو شيلت هيدروجين من النص بطلّق
+
+254
+00:22:33,370 --> 00:22:38,270
+مجموعة فيها ذرة الكاربون هذه متصلة بتلت مجموعات
+
+255
+00:22:38,270 --> 00:22:46,250
+CH3 بنسميها tertiarybutylTertiarybutyl مرات
+
+256
+00:22:46,250 --> 00:22:51,210
+بيكتبوا ترت اختصارا و مرات بيحطوا T يعني ممكن
+
+257
+00:22:51,210 --> 00:22:59,700
+تلاقوا Tبيوتل أو تيرت بيوتل تيرتشار بيوتل في كل
+
+258
+00:22:59,700 --> 00:23:04,080
+الأحوال لما نحتاج نشوف هذه الأشياء من ناحية
+
+259
+00:23:04,080 --> 00:23:08,680
+alphabetical أي حرف اللي بنعتمده لأنه بعد شوية لما
+
+260
+00:23:08,680 --> 00:23:13,500
+نسمي المراكبات يلزمنا الترتيب ال alphabetical
+
+261
+00:23:13,500 --> 00:23:19,200
+لبيوتل حتى لو كنتي بتاعة بيوتل هي حرف إيشالـ
+
+262
+00:23:19,200 --> 00:23:23,400
+secondary butyl حرف بيه، ال tertiary butyl حرف
+
+263
+00:23:23,400 --> 00:23:30,960
+بيه، ال isobutyl حرف I، ال isobutyl حرف I مش حرف
+
+264
+00:23:30,960 --> 00:23:36,520
+بيهواضح ال isobutyl لو قلتلكوا alphabetically ايش
+
+265
+00:23:36,520 --> 00:23:40,760
+اول اشي باعتمدوا فيها I لكن tertiary butyl باهمل
+
+266
+00:23:40,760 --> 00:23:45,340
+ال T وتعامل على انه حرف الأول B من ناحية
+
+267
+00:23:45,340 --> 00:23:50,720
+alphabetical و لو حطينا هنا Chlor في شغلات مرات مش
+
+268
+00:23:50,720 --> 00:23:55,780
+بحاجة لفهم بحاجة انكم تحفظوها زي هيك تمام يعني مش
+
+269
+00:23:55,780 --> 00:23:58,600
+قصة tertiary butyl alphabetically
+
+270
+00:24:00,680 --> 00:24:09,180
+B Isobutyl خلصنا واضح؟
+
+271
+00:24:09,180 --> 00:24:13,220
+مرات كتير في التسمية في ناس بصروا على ان بعض
+
+272
+00:24:13,220 --> 00:24:17,180
+الأشياء بدهم يفهموها مش كل شيء في التسمية مش كل
+
+273
+00:24:17,180 --> 00:24:22,020
+شيء في التسمية بيفهم يعني لما اجي اقول والله انت
+
+274
+00:24:22,020 --> 00:24:29,660
+اسمك هدا ليش سموكي هدا خلاص هدا خلاصواحدة تيجي
+
+275
+00:24:29,660 --> 00:24:36,640
+تقولي طب ليش سموه بروبين؟ كان سموه نوبا كلين، ليش
+
+276
+00:24:36,640 --> 00:24:43,120
+سموه بروبين؟مش كل شيء في التسمية بالذات أحيانا
+
+277
+00:24:43,120 --> 00:24:46,900
+بتلاقوا إله منطق وقاعدة زي ما أنتوا أهلكوا سموكم
+
+278
+00:24:46,900 --> 00:24:52,280
+واضح؟ زي ما أهلكوا سموكم كان في شيء معين خلهم
+
+279
+00:24:52,280 --> 00:24:58,620
+يسموا مركب معين بنزين كان في شيء معين حادث صديق
+
+280
+00:24:58,620 --> 00:25:04,780
+اللي بيرجع لتاريخ العلوم أحيانا ممكن بلحظة من
+
+281
+00:25:04,780 --> 00:25:11,700
+اللحظات يلاقي هذا الأصلواللي بيرجع لتاريخ الأسماء
+
+282
+00:25:11,700 --> 00:25:16,280
+اللي بيرجع لتاريخ الأسماء ممكن يلاقي أصل لأسماءكم
+
+283
+00:25:16,280 --> 00:25:22,460
+حتى لو أنتم مش عارفينه يعني ممكن لمن ولدتوا كان
+
+284
+00:25:22,460 --> 00:25:26,860
+متوفي عامة إلكم اسمها هودا إكراما إليها سموكوا
+
+285
+00:25:26,860 --> 00:25:30,940
+هودا الآن أنا بالنسبة إيه هذه المعلومة؟ مابعرفاش
+
+286
+00:25:30,940 --> 00:25:35,220
+ولذلك خدوا تسمية العناصر مرة بتلاقي العنصر بيقوله
+
+287
+00:25:35,220 --> 00:25:41,090
+مسمى على اسم مدينةمر على اسم بني آدم اللي اكتشفه،
+
+288
+00:25:41,090 --> 00:25:46,550
+مر على اسم كذا، فأصل الاسم قد لا نعرفه، قد يكون له
+
+289
+00:25:46,550 --> 00:25:52,930
+أصل، لكن احنا ايش؟ ما بنعرفوش، الأن بالنسبة لنا
+
+290
+00:25:52,930 --> 00:25:58,990
+هذه سيارة مرسيدس، اسم، لكن يا تورا لو أعطيتكوا
+
+291
+00:25:58,990 --> 00:26:02,170
+واجب، ليش سموا ال مرسيدس مرسيدس؟
+
+292
+00:26:05,190 --> 00:26:10,310
+فتشوا عليه و هتقولي الجواب المرة الجاية هتلاحظوا
+
+293
+00:26:10,310 --> 00:26:15,530
+إنه إله اسم ومسمى على اسم واحدة وكذا إله أصل بس مش
+
+294
+00:26:15,530 --> 00:26:18,150
+كتير بهمن الأصل في لحظة من لحظات بلاش نضيع وقت
+
+295
+00:26:18,150 --> 00:26:24,610
+كتير الآن هذه المجموعات يجب أن تتدربوا عليها يجب
+
+296
+00:26:24,610 --> 00:26:29,810
+أنكم تحفظوها بشكل جيد هذا الكلام كيف بيجي بالتدريب
+
+297
+00:26:29,810 --> 00:26:33,490
+كيف بيجي بالتدريب الآن
+
+298
+00:26:34,940 --> 00:26:39,940
+بعد ما أخدنا ال الكانز البسيطة و ال alkyl groups
+
+299
+00:26:39,940 --> 00:26:45,120
+البسيطة بدنا ناخد تسمية ال الكانز بال IUPAC system
+
+300
+00:26:45,120 --> 00:26:50,360
+حتى لو كبرت و صارت متفرعة واضح؟ يعني تسمية ال
+
+301
+00:26:50,360 --> 00:26:54,340
+الكانز الكبيرة اللي مامرتش علينا بال IUPAC system
+
+302
+00:26:54,730 --> 00:27:00,050
+ال ايوبك سيستم بيعتمد على ان نبحث عن اطول سلسلة
+
+303
+00:27:00,050 --> 00:27:05,330
+كربونية و اسم عليها يعني لو اطول سلسلة تلاتة نهاية
+
+304
+00:27:05,330 --> 00:27:11,110
+الاسم عندى ابروبين لو اربعة بيوتين تمانية اكتيل
+
+305
+00:27:12,590 --> 00:27:17,830
+فالشيء الأول بيقولنا choose the largest continuous
+
+306
+00:27:17,830 --> 00:27:23,090
+chain الان رجاء ماحدش يفهم السلسلة أن انتوا
+
+307
+00:27:23,090 --> 00:27:28,550
+بتكونوا تشوفوها مرسومة عدل بشكل أفقي أو بشكل عمودي
+
+308
+00:27:28,550 --> 00:27:33,350
+هذا الشيء ليس له معنى أنها تكون أفقي أو عمودي أو
+
+309
+00:27:33,350 --> 00:27:38,740
+مائلة معنى سلسلةذرات كربون ورا بعض بأي طريقة انا
+
+310
+00:27:38,740 --> 00:27:43,180
+ارسمهم هذا الكلام لا معنى له كله ممكن يعني لو بدأ
+
+311
+00:27:43,180 --> 00:27:48,920
+احكي مثلا عن خمسة لو بدأ احكي عن خمسة هذه سلسلة من
+
+312
+00:27:48,920 --> 00:27:59,380
+خمسة تمام وهذه سلسلة من خمسة وممكن ناخد كمان هذه
+
+313
+00:27:59,380 --> 00:28:05,360
+بهذا الشكلسلسلة من الخمسة و ممكن نرسمها بطريقة
+
+314
+00:28:05,360 --> 00:28:12,440
+تانيةسلسلة من خمسة فمعنى سلسلة ذرات متتالية وليس
+
+315
+00:28:12,440 --> 00:28:15,740
+الطريقة المرسومة بعض الناس بيقول سلسلة يعني بيشوفه
+
+316
+00:28:15,740 --> 00:28:21,800
+هيك حسب نظره أفقي أو عمودي لأ لأ معنى سلسلة كام
+
+317
+00:28:21,800 --> 00:28:25,360
+ذرة كربون متتالية فاهمنا إيش معنى سلسلة فلو قولت
+
+318
+00:28:25,360 --> 00:28:29,220
+هنا أما أطول سلسلة واحد اتنين تلاتة أربعة خمسة
+
+319
+00:28:29,220 --> 00:28:33,060
+واحد اتنين تلاتة أربعة خمسة واحد اتنين تلاتة أربعة
+
+320
+00:28:33,060 --> 00:28:36,580
+خمسة واحد اتنين تلاتة أربعة خمسة ابلاحظين مرسومين
+
+321
+00:28:36,580 --> 00:28:43,470
+بطرقمختلفة لكن بالنسبة لي معنى أطول سلسلة أطول عدد
+
+322
+00:28:43,470 --> 00:28:47,870
+متتالي من ذرات الكربون كيف يرتسموا مش مشكلة واضح و
+
+323
+00:28:47,870 --> 00:28:52,010
+لذلك بعد شوية اشوفوا مثلا هذا المركب هين اتكلمت عن
+
+324
+00:28:52,010 --> 00:28:58,190
+سلسلة اللي ماعطيها اللون الأحمر ولو مش مبينة بشكل
+
+325
+00:28:58,190 --> 00:29:04,370
+مستقيم بالنسبة لكم هذا شيء ما لهش معنى الآنحسب
+
+326
+00:29:04,370 --> 00:29:08,130
+أطول سلسلة بيكون اسم المُركّب لو كان عندنا تلاتة
+
+327
+00:29:08,130 --> 00:29:13,050
+نهاية المُركّب ابرو بين خمسة بينتين و هكذا طيب لما
+
+328
+00:29:13,050 --> 00:29:17,370
+بيصير في عندي سلسلة هذه السلسلة أكيد بيتفرع منها
+
+329
+00:29:17,370 --> 00:29:23,010
+شغلات هذه بسميها أنا الأشياء المتفرعة من السلسلة
+
+330
+00:29:23,010 --> 00:29:26,870
+اللي طالعة من أطول سلسلة carbon بقول عنها
+
+331
+00:29:26,870 --> 00:29:31,980
+substituent هذه كلمة هتصير اتمر عليكمكثير
+
+332
+00:29:31,980 --> 00:29:38,040
+Substituents اللي هي الأشياء المبدلة الان كام
+
+333
+00:29:38,040 --> 00:29:43,460
+Substituents على هذا المركب متفرع منه؟ اتنين هدولة
+
+334
+00:29:43,460 --> 00:29:48,920
+ال Substituents لازم انا اوضحهم او اوضح من اي نقطة
+
+335
+00:29:48,920 --> 00:29:53,060
+تفرعوا من اي مكان تفرعوا طب لما هذي بدي اعطيها اسم
+
+336
+00:29:53,060 --> 00:29:57,820
+هعطيها Chloro لما هذي بدي اعطيها اسم هعطيها Abromo
+
+337
+00:29:57,820 --> 00:30:02,830
+بعدين بدي اقول لك Chloro من وين اتفرعت؟من أي موقع
+
+338
+00:30:02,830 --> 00:30:08,690
+لبرومو من وين اتفرعت اذا بالزمن ترقيم لهالسلسلة
+
+339
+00:30:08,690 --> 00:30:12,950
+طالما بحكي سلسلة إذا عندي احتمالين ترقيم ممكن أبدأ
+
+340
+00:30:12,950 --> 00:30:17,770
+من هنا واحد اتنين تلاتة أربعة خمسة أو من هنا واحد
+
+341
+00:30:17,770 --> 00:30:23,130
+اتنين تلاتة أربعة خمسة من أي جهة بدي أبدأ الجهة
+
+342
+00:30:23,130 --> 00:30:26,910
+اللي بتخلي ال substituents أرقامهم أقل ما يمكن
+
+343
+00:30:26,910 --> 00:30:30,230
+يعني لو بدأت من هنا زي ما احنا عاملين ال chlorine
+
+344
+00:30:30,230 --> 00:30:34,280
+على اتنين و ال brom على تلاتة اتنين و تلاتةخمسة لو
+
+345
+00:30:34,280 --> 00:30:38,600
+بدأت منها ان واحد اتنين تلاتة اربعة صارت هذه على
+
+346
+00:30:38,600 --> 00:30:43,840
+تلاتة وهذه على اربعة تلاتة واربعة اذا ماهو اقل
+
+347
+00:30:43,840 --> 00:30:50,900
+ترقيم هذا ولذلك لما بدي ارقم دائما عند احتمالين
+
+348
+00:30:50,900 --> 00:30:56,220
+الاحتمال اللي بدي اختارهالـ lowest possible
+
+349
+00:30:56,220 --> 00:31:00,780
+numbering أقل احتمال بيعطي الـ substituents أرقام
+
+350
+00:31:00,780 --> 00:31:05,640
+طب اعرفنا الأرقام و اعرفنا الآن انه صار عندنا على
+
+351
+00:31:05,640 --> 00:31:13,800
+موقع اتنين ذرة اكلورو مظبوط ولا لأ اكلورو وع موقع
+
+352
+00:31:13,800 --> 00:31:20,410
+تلاتة ذرة ابروموبدي اكتب الاسم كامل الاسم عادة
+
+353
+00:31:20,410 --> 00:31:26,130
+بنبدأ في كتابته من الخلف للامام اول كلمة في الاسم
+
+354
+00:31:26,130 --> 00:31:30,970
+انه عندي خمسة اذا مركبه بنتين يعني اول شي بدي ابدأ
+
+355
+00:31:30,970 --> 00:31:36,070
+اكتبه بنتين هذا البنتين الان بيحمل برومو و كلورو
+
+356
+00:31:36,070 --> 00:31:41,630
+مين بدي اذكره في الاول ال alphabetical اللي بيظهر
+
+357
+00:31:41,630 --> 00:31:47,510
+اولا مين بيجي قبل ال B ولا ال Cالـ B A B C D
+
+358
+00:31:47,510 --> 00:31:51,090
+شوفتوا قبل شوية ليش أنا نبهت كل ال alphabetical في
+
+359
+00:31:51,090 --> 00:31:58,010
+المجموعات أه إذا هذا هيكون three bromo two
+
+360
+00:31:58,010 --> 00:32:03,430
+chlorobentain واضح؟ لأن أنا عندي كام substituent؟
+
+361
+00:32:03,430 --> 00:32:10,670
+هذه و هذه كيف بأذكرهم؟list substituents
+
+362
+00:32:10,670 --> 00:32:15,830
+alphabetically أذكرهم alphabetically أذكر ال B قبل
+
+363
+00:32:15,830 --> 00:32:22,650
+ال C قبل ال D قبل ال E و هكذا طبعا هنا اجتمل الاسم
+
+364
+00:32:22,650 --> 00:32:26,930
+بضيف معلومة أنه لو من مجموعة معينة كان في عندي
+
+365
+00:32:26,930 --> 00:32:33,400
+تنتينبدي أستعمل لمضاي، لو كان في عندي تلاتة ا try،
+
+366
+00:32:33,400 --> 00:32:38,700
+لو عندي أربعة تترى، و هكذا، واضح؟ انشوف أمثلة
+
+367
+00:32:38,700 --> 00:32:46,820
+إضافية، انشوفأمثلة إضافية مثلا هاي مثال أصعب شغلة
+
+368
+00:32:46,820 --> 00:32:52,220
+أنه فعلا طول أطول سلسلة يعني لو إجيت بدي أطول
+
+369
+00:32:52,220 --> 00:32:57,460
+سلسلة ممكن أعد واحد اتنين تلاتة واحد اتنين تلاتة
+
+370
+00:32:57,460 --> 00:33:03,340
+أربعة خمسة واحد اتنين تلاتة أربعة خمسة احتمالات
+
+371
+00:33:03,340 --> 00:33:07,780
+كتيرة بدي أضلني أجرب لحد ما فعلا ألاقي أطول سلسلة
+
+372
+00:33:07,780 --> 00:33:14,930
+واحد اتنين تلاتة أربعة خمسة ستة سبعةإذا مركّب إيش؟
+
+373
+00:33:14,930 --> 00:33:15,730
+هبتين
+
+374
+00:33:23,230 --> 00:33:37,450
+مثل مثل مثل مثل مثل مثل مثل مثل
+
+375
+00:33:46,950 --> 00:33:51,550
+إذا من هنا لازم أرقم فالمثلز اللي عندي وين موجودين
+
+376
+00:33:51,550 --> 00:33:57,350
+على اتنين واربعة هيصير مركبة two four dimethyl
+
+377
+00:33:57,350 --> 00:34:02,850
+heptane two four dimethyl heptane الان هاي مركب
+
+378
+00:34:02,850 --> 00:34:10,610
+تاني بتجارب كتير هتكتشف ان هاي أطول سلسلة سبعة ايش
+
+379
+00:34:10,610 --> 00:34:11,750
+بيتفرع منها
+
+380
+00:34:14,510 --> 00:34:24,070
+هذه المجموعة اللي مرت علينا ايزو بروبل و مثل الان
+
+381
+00:34:24,070 --> 00:34:30,410
+ايزو بروبل حرف I و المثل حرف M و المركب هبتين و I
+
+382
+00:34:30,410 --> 00:34:36,870
+قبل ال M اذا حيصير اسم المركب for aizobrobel انها
+
+383
+00:34:36,870 --> 00:34:38,530
+موجودة على موقع اربعة
+
+384
+00:34:41,630 --> 00:34:46,510
+لاحظوا في كل التسمية لو تطبعوا على الكمبيوتر في أي
+
+385
+00:34:46,510 --> 00:34:54,490
+فراغولا فراغ دائما قبل الرقم وبعد الرقم بتحطه شرطة
+
+386
+00:34:54,490 --> 00:34:58,330
+ما عدا إذا كنا بنحط في أول الإسم بتكون الشرطة فقط
+
+387
+00:34:58,330 --> 00:35:04,170
+بعد الرقم بدون أي فراغات يعني هذا كله متصل بعض
+
+388
+00:35:04,170 --> 00:35:08,830
+كتابة من هنا لهنا مافيش عندي فراغات لو بكتب اسم
+
+389
+00:35:08,830 --> 00:35:14,550
+هذا المركب على الكمبيوتر قبل الرقم شرطة وبعده شرطة
+
+390
+00:35:14,550 --> 00:35:21,380
+ما لم يكن الرقمفي الأول فبس بيكون فيه بعده شرطة
+
+391
+00:35:22,430 --> 00:35:27,630
+الان في عندكم امثلة كتير بإمكانكوا تتدربوا عليها
+
+392
+00:35:27,630 --> 00:35:31,250
+ماعطيكوا انا في الواجبات بالذات في الامتحانات
+
+393
+00:35:31,250 --> 00:35:35,270
+السابقة اللي موجودة عندكم كل امتحان بتلاقي عليه
+
+394
+00:35:35,270 --> 00:35:40,310
+اربع خمس مركبات كيف تسموهم مالم تتدربوا على حفظ
+
+395
+00:35:40,310 --> 00:35:44,890
+أسماء ال الkins على حفظ المجموعات على كيف تسموا
+
+396
+00:35:44,890 --> 00:35:48,970
+مركب مش هتقدروا تطبقوا يعني لازم لو واحد كنتوا
+
+397
+00:35:48,970 --> 00:35:50,210
+تدرسوا و تتدربوا أكثر
+
+398
+00:35:54,510 --> 00:35:58,250
+لأ لأ اعتمدي على اللي احنا بنشرحه بشكل اكبر
+
+399
+00:35:58,250 --> 00:36:02,370
+واعتمدي على الامتحانات الكتيرة اللي موجودة عندكم
+
+400
+00:36:02,370 --> 00:36:08,470
+بتعطيكي اسئلة وافية في الموضوع الآن بنيجي لنقطة
+
+401
+00:36:08,470 --> 00:36:14,350
+خاصة صغيرة بنضيفها في هذا الموضوع أحيانا بنيجي
+
+402
+00:36:14,350 --> 00:36:20,410
+نبحث عن أطول سلسلة بنلاحظ أنه بيطلع عندنا احتمالين
+
+403
+00:36:20,410 --> 00:36:27,520
+مش احتمال واحدمثلا هذا المركب هو نفسه هذا المركب
+
+404
+00:36:27,520 --> 00:36:31,440
+تماما لو بتتطلع عليه يعني احنا رسمنا المركب هذا
+
+405
+00:36:31,440 --> 00:36:36,460
+عملنا له نسخ و لاصق هنا لما نيجي نبحث عن أطول
+
+406
+00:36:36,460 --> 00:36:41,680
+سلسلة عدنا كتير هيقولنا واحد اتنين تلاتة اربعة
+
+407
+00:36:41,680 --> 00:36:47,800
+خمسة ستة سبعة اجت طالبة تانية عدت من هنا واحد
+
+408
+00:36:47,800 --> 00:36:55,600
+اتنين تلاتة اربعة خمسة ستة سبعةطب يا تورا بدي
+
+409
+00:36:55,600 --> 00:37:00,820
+أختار هذه السلسلة و لا بدي أختار هذه السلسلة طلع
+
+410
+00:37:00,820 --> 00:37:05,780
+عندك أكتر من سلسلة سبعة في عندنا قاعدة بتقول if
+
+411
+00:37:05,780 --> 00:37:09,760
+there are two equal along continuous chains يعني
+
+412
+00:37:09,760 --> 00:37:13,180
+لو في عندكوا سلسلتين متساويات في الطول في
+
+413
+00:37:13,180 --> 00:37:16,780
+الاحتمالات ا choose the one with most branches
+
+414
+00:37:16,780 --> 00:37:21,820
+اختار السلسلة اللي فيها تفرعات أكتريعني لو اتطلعت
+
+415
+00:37:21,820 --> 00:37:28,340
+على السلسلة هذه، كم تفرع طالع منها؟ اتنين، شغلتين
+
+416
+00:37:28,340 --> 00:37:31,540
+طالعين منها، لو اتطلعت على السلسلة هذه، كم تفرع
+
+417
+00:37:31,540 --> 00:37:37,980
+طالع منها؟ مجموعة واحدة، واضح؟ هذه طالع منها فقط
+
+418
+00:37:37,980 --> 00:37:42,240
+تفرع واحد، هيو، هنا طالع تفرعين، ابن اختار اللي
+
+419
+00:37:42,240 --> 00:37:47,000
+فيهاتفرعين طبعا لما نختار او ناخد ال lower
+
+420
+00:37:47,000 --> 00:37:51,640
+numbering على نمرة تلاتة في عندي مجموعة CH2 CH3
+
+421
+00:37:51,640 --> 00:37:55,600
+هذه اللي بيقول عنها إثل وعن نمرة اتنين المثل three
+
+422
+00:37:55,600 --> 00:38:00,300
+ethyl two methyl heptane بينما لو واحدة اختارت هذه
+
+423
+00:38:00,300 --> 00:38:04,220
+هتقول heptane على نمرة تلاتة هذه المجموعة
+
+424
+00:38:04,220 --> 00:38:09,520
+isopropyl فهذا الاسم three isopropyl heptane is
+
+425
+00:38:09,520 --> 00:38:14,650
+not a correct nameممكن واحدة في الامتحان تعمله،
+
+426
+00:38:14,650 --> 00:38:18,230
+تعتقد أنها عملت جيدا، في الآخر تتفاجأ أنه غلط
+
+427
+00:38:18,230 --> 00:38:22,670
+بالكامل، ليش؟ لأنها مانتبهتش أنه عندها سلسلتين،
+
+428
+00:38:22,670 --> 00:38:26,690
+ممكن يكونوا سبعة، وأنه لو أخدت من هنا، اللي هي هذه
+
+429
+00:38:26,690 --> 00:38:30,130
+السلسلة، هذه فيها ال most branches، فيها التفرعات
+
+430
+00:38:30,130 --> 00:38:34,390
+الأكثرولذلك اللي بده يشتغل في التسمية بده يكون
+
+431
+00:38:34,390 --> 00:38:39,610
+منتبه أنه فعلا لجأ أطول سلسلة واتأكد أنه مافيش
+
+432
+00:38:39,610 --> 00:38:45,150
+غيرها، لو لجأت إنتين بنفس الطول، بده يختار الأكثر
+
+433
+00:38:45,150 --> 00:38:52,310
+تفرعا، بده يختار السلسلة الأكثر تفرعا، واضح هذا
+
+434
+00:38:52,310 --> 00:39:00,220
+الكلام؟ ممكن نجرب ما أعطيكممثال حتى نشوف انكم
+
+435
+00:39:00,220 --> 00:39:18,060
+أتقنتوا هذا الكلام ولا لا هذا
+
+436
+00:39:18,060 --> 00:39:23,040
+مركب ابدأوا
+
+437
+00:39:23,040 --> 00:39:24,780
+فاكروا فيه وشوفوا
+
+438
+00:39:27,090 --> 00:39:33,530
+أيش أطول سلسلة موجودة فيه و
+
+439
+00:39:33,530 --> 00:39:38,610
+أول ما نعملها بأنصح اكون معاكم قلم فوسفور اتعلموا
+
+440
+00:39:38,610 --> 00:39:44,350
+عليها عشان تقدروا تشوفوا كل ما يتفرع منها واضح؟
+
+441
+00:39:44,350 --> 00:39:49,650
+الآن أكيد هتبدو تعدوا أنتوا واحد تنين تلاتة أربعة
+
+442
+00:39:49,650 --> 00:39:53,310
+أكيد لو قلتوا تلاتة تلاتة أربعة تلاتة أربعة نفس
+
+443
+00:39:53,310 --> 00:40:02,770
+الأشي أوواحد اتنين تلاتة او واحد اتنين تلاتة اربعة
+
+444
+00:40:02,770 --> 00:40:11,370
+خمسة ستة ايش رأيكوا او اي واحدة من هدول هادي زي
+
+445
+00:40:11,370 --> 00:40:14,650
+هادي زي هادي ماهم تلات اطراف واحد اتنين واحد اتنين
+
+446
+00:40:14,650 --> 00:40:22,090
+واحد اتنين اي واحدة بتاخدوها مافيش فيه مشكلة منها
+
+447
+00:40:23,210 --> 00:40:27,150
+أي واحدة من هدولة بيمشي تكون المرة واحدة لأنها
+
+448
+00:40:27,150 --> 00:40:33,650
+وادي وادي زي بعض واحد تانين تلاتة أربعة خمسة ستة
+
+449
+00:40:33,650 --> 00:40:39,630
+سبعة اه الآن هي أطول سلسلة خليني أعلمها و بأنصحكوا
+
+450
+00:40:39,630 --> 00:40:44,630
+لو عندكم طلم فسفور أسفر اتعلموها هي أطول سلسلة
+
+451
+00:40:44,630 --> 00:40:51,050
+عشان نقدر نشوف كام تفرع طالع منها هذه السلسلةاربع
+
+452
+00:40:51,050 --> 00:41:01,330
+انا مع الكلور هذه CH3 وهذه CH3 وهذه CH3 وهنا
+
+453
+00:41:01,330 --> 00:41:06,010
+الكلور اربع تفرعات طالع منها طب لو بدى اعطيها اقل
+
+454
+00:41:06,010 --> 00:41:16,080
+ترقيم من فضل من فضل اكيد واحدتلاتة اربعة خمسة ستة
+
+455
+00:41:16,080 --> 00:41:21,160
+سبعة الان لو بدنا نكتب الاسم كاملا كيف بدنا نبدأ
+
+456
+00:41:21,160 --> 00:41:27,880
+نكتب الاسم؟ من الخلف للامام ايش مركب طالما سبعة؟
+
+457
+00:41:27,880 --> 00:41:35,360
+هبتين الان هذا الهبتين كم نوع من المجموعات يحمل؟
+
+458
+00:41:35,360 --> 00:41:44,910
+نوعين اكلوروومثل ومثل ومثل اتراي مثل اذا هذا حقيقة
+
+459
+00:41:44,910 --> 00:41:54,550
+الـ C في الأول الكلورو اتراي مثل الان الكلورو وين
+
+460
+00:41:54,550 --> 00:42:01,870
+موقعها على نمرة أربعة four شرطة كلورو ال اتراي مثل
+
+461
+00:42:01,870 --> 00:42:10,930
+وين موجودين على اتنينو اتنين و تلاتة لازم احدد
+
+462
+00:42:10,930 --> 00:42:15,330
+تلات ارقام طالما try مثل لازم التلات ارقام بينه
+
+463
+00:42:15,330 --> 00:42:21,090
+اذا هنا فعلا بدي اكتب شرطة اتنين اتنين تلاتة هدف
+
+464
+00:42:21,090 --> 00:42:27,650
+هذا الموقع ان انا اكتبها صح هتكون اتنين اتنين
+
+465
+00:42:27,650 --> 00:42:32,090
+تلاتة try مثل
+
+466
+00:42:37,340 --> 00:42:47,340
+4-chloro-2-2-3-trimethylheptane
+
+467
+00:42:52,160 --> 00:42:56,040
+ماحدش يغلط .. مرات كتير بعض الناس اللي بيحفظوا
+
+468
+00:42:56,040 --> 00:42:59,400
+مجموعات شو الغلط اللي بيجعوا فيه، مابيبحثوش عن
+
+469
+00:42:59,400 --> 00:43:02,480
+أطول سلسلة، بيجوا و بيقولوا اه هذه ال carbon اللي
+
+470
+00:43:02,480 --> 00:43:06,300
+حملة تلت مجموعات tertiary-butyl وهذه السلسلة
+
+471
+00:43:07,580 --> 00:43:11,460
+وبالتالي بيسموه hexane وحمل على نمرة 2 tertiary
+
+472
+00:43:11,460 --> 00:43:16,920
+butyl بالفعش أنا مابخدش أسماء المجموعات إلا بعد ما
+
+473
+00:43:16,920 --> 00:43:23,700
+أحدد أطول سلسلة دائما نمرة واحد حدده أطول سلسلة
+
+474
+00:43:23,700 --> 00:43:28,340
+بعض الناس بيغلط بيجي بيقول لأ هذه تعتبر مجموعة في
+
+475
+00:43:28,340 --> 00:43:32,830
+البداية يعني لو أنا هنا كنت كاتب CH3بروح و بقول
+
+476
+00:43:32,830 --> 00:43:36,210
+ادي مجموعة مثل لأ دي جزء من السلسلة بنفعش اسميها
+
+477
+00:43:36,210 --> 00:43:41,110
+مجموعة هذه من الأخطاء الشائع لبعض الناس بيجي بعمل
+
+478
+00:43:41,110 --> 00:43:44,650
+الترقيم من هان و بعدين بيقول على نمر واحد في عندي
+
+479
+00:43:44,650 --> 00:43:50,950
+try مثل .. لأ مش هيك تأخذه لازم أفتش عليه أطول
+
+480
+00:43:50,950 --> 00:43:54,630
+سلسلة و بعدين أشوف إيش في عندي مجموعات حسب ما
+
+481
+00:43:54,630 --> 00:43:59,010
+اتعلمت بأعمل التسمية تبعي
+
+482
+00:44:04,700 --> 00:44:10,980
+هذه تقريبا فكرة عن ال الكنز بشكل عام لو اتكلمنا عن
+
+483
+00:44:10,980 --> 00:44:15,960
+ال physical properties of الكنز هنلاحظ القاتل اول
+
+484
+00:44:15,960 --> 00:44:23,940
+شئ ال الكنز هم water insoluble ليش؟ لان دائما ال
+
+485
+00:44:23,940 --> 00:44:31,440
+الكنز تتذكر انهم non polar والمية polar حسب قاعدة
+
+486
+00:44:31,440 --> 00:44:36,250
+like dissolves likeالالكينز لا يدوبون في المياه
+
+487
+00:44:36,250 --> 00:44:40,590
+ولذلك من هؤلاء الالكينز على سبيل المثال البنزين
+
+488
+00:44:40,590 --> 00:44:44,890
+اللي هو أقود السيارات واضح هل يا تورا هذا بيدوب في
+
+489
+00:44:44,890 --> 00:44:49,090
+المياه ولا بيعمل طبقة تانية بيعمل طبقة تانية هنا
+
+490
+00:44:49,090 --> 00:44:54,810
+خليني أنبه لنقطة خطأ شائعلأنه احنا باللغة العربية
+
+491
+00:44:54,810 --> 00:44:59,330
+بنستعمل كلمة بنزين لما بنعب السيارة بنقول بنزين
+
+492
+00:44:59,330 --> 00:45:05,310
+فناس كتير بيخطئوا و بيفكروا انه احنا بنعب السيارة
+
+493
+00:45:05,310 --> 00:45:09,150
+البنزين هذا اللي مار عليكم اللي هو البنزين العطري
+
+494
+00:45:09,150 --> 00:45:16,230
+هذا الكلام خطأ طب ايش اسم هو بالانجليزي وقود
+
+495
+00:45:16,230 --> 00:45:23,650
+السيارات ال fuel اسمه جازولينأحنا بالعربي هذا
+
+496
+00:45:23,650 --> 00:45:29,390
+الجازولين بنقول عنه بنزين لكن هو حقيقة خليط من
+
+497
+00:45:29,390 --> 00:45:35,870
+الالكينز بشكل أساسي مركبين من الالكينز هو خليط من
+
+498
+00:45:35,870 --> 00:45:40,190
+الهيبتين والايزو
+
+499
+00:45:40,190 --> 00:45:40,710
+أكتين
+
+500
+00:45:43,660 --> 00:45:48,340
+فالجازولين اللي هو وقود السيارات اللي احنا بنعبيه
+
+501
+00:45:48,340 --> 00:45:52,180
+باللغة العربية متعودين نقول عنه بنزين مالوش هذا ال
+
+502
+00:45:52,180 --> 00:45:56,020
+structure ولا له علاقة بهذا ال structure لأ
+
+503
+00:45:56,020 --> 00:46:02,000
+gasoline is a mixture of alkanes الجازولين وقود
+
+504
+00:46:02,000 --> 00:46:05,780
+السيارات اللي بنعبيه هو خليط من ال alkanes شو ما
+
+505
+00:46:05,780 --> 00:46:10,480
+دول ال alkanes؟الهبتين وال ايزو اكتين و بتهيألي
+
+506
+00:46:10,480 --> 00:46:15,020
+اليوم احنا رسمنا شكل الهبتين سبع كربونات و رسمنا
+
+507
+00:46:15,020 --> 00:46:18,900
+شكل ال ايزو اكتين اللي فيه مجموعة ال ايزو و بنكمل
+
+508
+00:46:18,900 --> 00:46:24,500
+لكم كربونات تمانية الان هدولة الكنز لو أخدنا هذا
+
+509
+00:46:24,500 --> 00:46:29,880
+الجازولين وقود السيارات و حطناه فوق ميهبيخلط
+
+510
+00:46:29,880 --> 00:46:34,640
+معاها، بيدوب فيها؟ لأ، فإذا الالكينز they are
+
+511
+00:46:34,640 --> 00:46:39,880
+water insoluble، ليش؟ لأن هدول المركبات، القوة
+
+512
+00:46:39,880 --> 00:46:46,010
+اللي فيهم، London forces، بينما الميهالهيدروجين
+
+513
+00:46:46,010 --> 00:46:52,810
+بوندنج فيها الميّه بولر والالكينز نان بولر فالبولر
+
+514
+00:46:52,810 --> 00:46:57,370
+والنان بولر بخلطوش مع بعض are water insoluble طبعا
+
+515
+00:46:57,370 --> 00:47:02,000
+كونوا القوة اللي موجودة فيهم ضعيفةاللي هي أضعف نوع
+
+516
+00:47:02,000 --> 00:47:05,440
+من القوة الـ London Forces معناه ذلك الجزيئات
+
+517
+00:47:05,440 --> 00:47:10,880
+بتاعتهم ممسوقة ببعضها بقوة ولا بقوة ضعيفة؟ بقوة
+
+518
+00:47:10,880 --> 00:47:16,160
+ضعيفة، هذا بيقدر إلى إنها بتتبخر بشكل سريع وإلى أن
+
+519
+00:47:16,160 --> 00:47:22,000
+نقطة الغليان تبعتها أيضا منخفضة جدا ولذلك لو أنا
+
+520
+00:47:22,000 --> 00:47:25,380
+إجيت اتطلعت على ال canes اللي في الجدول هلاحظ ال
+
+521
+00:47:25,380 --> 00:47:32,540
+methane غازالإيثين غاز، البروبين غاز، البيوتين
+
+522
+00:47:32,540 --> 00:47:36,600
+غاز، اللي هو الغاز المنزلي، غاز الطهي المنزلي، هو
+
+523
+00:47:36,600 --> 00:47:41,740
+البيوتين البنتين بيبدأ يصير سائل بنقطة غليان حوالي
+
+524
+00:47:41,740 --> 00:47:46,500
+36 درجة مؤوية، نقطة غليان منخفضة البنزين نفسه نقطة
+
+525
+00:47:46,500 --> 00:47:49,920
+غليانه منخفضة، ولذلك بيتبقر بسرعة وبيعمل حرائق
+
+526
+00:47:49,920 --> 00:47:56,570
+بسرعةواضح؟ كل هذا الكلام لأن القوة الترابط اللي
+
+527
+00:47:56,570 --> 00:48:01,070
+موجودة فيه هي ال London forces اللي هي أضعف أنواع
+
+528
+00:48:01,070 --> 00:48:05,550
+قوة الترابط فالجزيئات غير مترابطة بقوة و من هنا
+
+529
+00:48:05,550 --> 00:48:10,910
+بيكون ال alkanes لهم low boiling points بالتأكيد
+
+530
+00:48:10,910 --> 00:48:15,720
+ال cane من ذرةنقطة غليانه اقل من ذرتين اقل من
+
+531
+00:48:15,720 --> 00:48:20,460
+تلاتة وكل ما يبدو يزيدوا عدد ذرات الالكين ايش
+
+532
+00:48:20,460 --> 00:48:26,020
+بيصيلا نقطة الغليان بتزيد واضح؟أخر نقطة اليوم
+
+533
+00:48:26,020 --> 00:48:31,560
+بنحكيها أن الالكينز لنفس المركب يعني لنفس العدد
+
+534
+00:48:31,560 --> 00:48:36,580
+الخمسة مثلا ممكن تكون chain متسلسلة و ممكن تكون
+
+535
+00:48:36,580 --> 00:48:39,900
+branched معناة chain مرة تانية أن الخمسة ورا بعض
+
+536
+00:48:39,900 --> 00:48:44,020
+branched هي عندي واحد اتنين تلاتة مثلا في البنتين
+
+537
+00:48:44,020 --> 00:48:49,800
+و من موقع اتنين اعملت تفرعينهنا خمس ذرات وهنا خمس
+
+538
+00:48:49,800 --> 00:48:53,560
+ذرات الخمس هذول جايين إيش؟ ورا بعض بقول عنهم chain
+
+539
+00:48:53,560 --> 00:49:00,140
+compounds هذول برانش دائما بنقول برانش الكنز have
+
+540
+00:49:00,140 --> 00:49:02,840
+lower boiling points than the corresponding long
+
+541
+00:49:02,840 --> 00:49:10,620
+chain of kens يعني هذا و هذا له نفس الصيغة C5H12
+
+542
+00:49:10,620 --> 00:49:17,970
+لكن مين له نقطة غليان أعلى؟الـ Chain أقل ال branch
+
+543
+00:49:17,970 --> 00:49:23,330
+ليش؟ لأن ال branch بيكون عامل زي الكورة الآن
+
+544
+00:49:23,330 --> 00:49:27,990
+تخيلوا لو حطيتوا أنتوا نفسكم تلت كورات هيك فوق بعض
+
+545
+00:49:27,990 --> 00:49:33,130
+بهذا الشكل هل يتورا بينهم مسافات ارتباط قوية كتير؟
+
+546
+00:49:33,130 --> 00:49:37,620
+هاي بس سطح الارتباطواضحة الفكرة؟ فالجزء اللي
+
+547
+00:49:37,620 --> 00:49:42,220
+branched بصير أعمل زي الكورة، الآن الكورات بحطها
+
+548
+00:49:42,220 --> 00:49:45,880
+بشكل تستقر فوق بعض، يعني أنا بقدر أحطها دولة تلاتة
+
+549
+00:49:45,880 --> 00:49:51,610
+فوق بعض ويثبتوا؟ لأليش؟ لأنه مافيش سطح التقاء كبير
+
+550
+00:49:51,610 --> 00:49:55,730
+بينهم ولذلك الـbranched alkanes they have lower
+
+551
+00:49:55,730 --> 00:49:59,170
+boiling points than the corresponding long chain
+
+552
+00:49:59,170 --> 00:50:03,210
+alkanes هذه مبادئ عامة بال physical properties
+
+553
+00:50:03,210 --> 00:50:06,090
+للالكنز وبهيك بننهي اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..14e63a092d27f7f869641d58d03fe8277da43831
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4389, "start": 19.57, "end": 43.89, "text": "بسم الله الرحمن الرحيم اليوم ضيلنا أشياء بسيطة في موضوع ال amines قبل ما ننتقل لجزء ال biochemistry طبعا اتفقنا المرة الماضية أن ال amines هم مراكبات ال nitrogen من أهم الأشياء اللي بتميزهم هو وجود إيش", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 48812, 26895, 8315, 5551, 8592, 1829, 16606, 4724, 3794, 1829, 9566, 3660, 8978, 3714, 2407, 11242, 45367, 2423, 669, 1652, 12174, 36150, 19446, 8717, 29399, 4587, 1211, 5296, 7435, 11622, 38207, 2423, 12198, 48353, 23032, 3555, 3615, 995, 1975, 2655, 5172, 4587, 8315, 9673, 25720, 9673, 46958, 10632, 14739, 2423, 669, 1652, 8032, 2304, 3714, 23557, 4117, 3555, 9307, 2423, 17903, 9154, 5551, 16095, 16247, 8592, 1829, 16606, 13672, 1829, 39894, 2304, 1829, 11622, 16095, 31439, 49610, 23328, 11933, 1829, 8592], "avg_logprob": -0.07627688011815471, "compression_ratio": 1.6372549019607843, "no_speech_prob": 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الحالة لو دوبنا ال ammonia مثلا في ال HCl ال ammonia هتاخد H من هنا هصير عندى ammonium ion مع ال Cl minus ammonium chloride يمكن هذا ما معاكم في المدرسة انه بإمكاننا احنا نجيب نقطة", "tokens": [4117, 8848, 23275, 21542, 6027, 3660, 45164, 11778, 37746, 8315, 2423, 46833, 50113, 15040, 8978, 2423, 389, 9966, 2423, 46833, 8032, 2655, 47283, 3215, 389, 9154, 34105, 8032, 9381, 13546, 43242, 7578, 36431, 2197, 17437, 20449, 2423, 2033, 3175, 36431, 2197, 35434, 7251, 43020, 23758, 19446, 20449, 995, 24793, 8978, 9673, 3215, 2288, 3794, 3660, 16472, 3224, 4724, 28814, 2304, 41361, 8315, 1975, 5016, 8315, 8717, 7435, 1829, 3555, 8717, 47432, 3660], "avg_logprob": -0.2669092498413504, "compression_ratio": 1.540983606557377, "no_speech_prob": 0.0, "words": [{"start": 321.55, "end": 322.09, "word": "كذلك", "probability": 0.7384440104166666}, {"start": 322.09, "end": 322.51, "word": " الحالة", "probability": 0.569091796875}, {"start": 322.51, "end": 322.59, "word": " لو", "probability": 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HCl لما يلتجوا مع بعض ال ammonia مع ال HCl شو هيعملوا؟ ammonium chloride ال ammonium chloride إيش لونه؟ تذكروا شغل المدرسة؟", "tokens": [27842, 2423, 46833, 9154, 3714, 5016, 1211, 12610, 2423, 46833, 8717, 5016, 9566, 11296, 34105, 8717, 47432, 3660, 9154, 2423, 389, 9966, 8717, 5016, 9566, 3224, 34105, 4032, 8717, 3794, 1829, 3555, 16095, 10874, 7649, 3555, 45030, 11242, 39894, 2655, 3555, 34740, 4386, 39894, 2655, 3555, 34740, 2423, 46833, 39894, 2655, 3555, 34740, 2423, 389, 9966, 5296, 15042, 7251, 1211, 2655, 7435, 14407, 20449, 45030, 11242, 2423, 46833, 20449, 2423, 389, 9966, 13412, 2407, 39896, 25957, 1211, 14407, 22807, 36431, 2197, 35434, 2423, 36431, 2197, 35434, 11933, 1829, 8592, 5296, 11536, 3224, 22807, 6055, 8848, 37983, 14407, 13412, 17082, 1211, 9673, 3215, 2288, 3794, 3660, 22807], "avg_logprob": -0.14398364123897017, "compression_ratio": 1.8522167487684729, "no_speech_prob": 0.0, "words": [{"start": 340.4, "end": 340.74, "word": "من", "probability": 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"probability": 0.99169921875}, {"start": 352.1, "end": 352.6, "word": " HCl", "probability": 0.893310546875}, {"start": 352.6, "end": 353.18, "word": " لما", "probability": 0.935302734375}, {"start": 353.18, "end": 353.68, "word": " يلتجوا", "probability": 0.9455078125}, {"start": 353.68, "end": 353.86, "word": " مع", "probability": 0.99609375}, {"start": 353.86, "end": 354.28, "word": " بعض", "probability": 0.997802734375}, {"start": 354.28, "end": 354.42, "word": " ال", "probability": 0.9736328125}, {"start": 354.42, "end": 354.76, "word": " ammonia", "probability": 0.986328125}, {"start": 354.76, "end": 354.92, "word": " مع", "probability": 0.8896484375}, {"start": 354.92, "end": 355.06, "word": " ال", "probability": 0.9951171875}, {"start": 355.06, "end": 355.54, "word": " HCl", "probability": 0.911865234375}, {"start": 355.54, "end": 355.74, "word": " شو", "probability": 0.929931640625}, {"start": 355.74, "end": 357.08, "word": " هيعملوا؟", "probability": 0.7958984375}, {"start": 357.08, "end": 357.62, "word": " ammonium", "probability": 0.6268310546875}, {"start": 357.62, "end": 358.18, "word": " chloride", "probability": 0.89013671875}, {"start": 358.18, "end": 358.38, "word": " ال", "probability": 0.68603515625}, {"start": 358.38, "end": 358.76, "word": " ammonium", "probability": 0.98779296875}, {"start": 358.76, "end": 359.26, "word": " chloride", "probability": 0.9931640625}, {"start": 359.26, "end": 359.56, "word": " إيش", "probability": 0.7685546875}, {"start": 359.56, "end": 362.66, "word": " لونه؟", "probability": 0.9503173828125}, {"start": 362.66, "end": 363.28, "word": " تذكروا", "probability": 0.8291015625}, {"start": 363.28, "end": 363.56, "word": " شغل", "probability": 0.9930013020833334}, {"start": 363.56, "end": 364.58, "word": " المدرسة؟", "probability": 0.978759765625}], "temperature": 1.0}, {"id": 16, "seek": 37647, "start": 365.19, "end": 376.47, "text": "أبيض و لذلك كنا نقول أنه ال ammonia مع ال HCl بيعطوا سحب بيضاء من ال ammonium chloride بهذا النص مرت عليكم في المدرسة ولا لأ؟", "tokens": [10721, 21292, 11242, 4032, 5296, 8848, 23275, 9122, 8315, 8717, 39648, 14739, 3224, 2423, 46833, 20449, 2423, 389, 9966, 4724, 40228, 9566, 14407, 8608, 5016, 3555, 4724, 1829, 11242, 16606, 9154, 2423, 36431, 2197, 35434, 39627, 15730, 28239, 9381, 3714, 43500, 25894, 24793, 8978, 9673, 3215, 2288, 3794, 3660, 49429, 5296, 10721, 22807], "avg_logprob": -0.20037616347825085, "compression_ratio": 1.3178807947019868, "no_speech_prob": 0.0, "words": [{"start": 365.19, "end": 365.93, "word": "أبيض", "probability": 0.8761393229166666}, {"start": 365.93, "end": 366.43, "word": " و", "probability": 0.3427734375}, {"start": 366.43, "end": 366.89, "word": " لذلك", "probability": 0.91650390625}, {"start": 366.89, "end": 367.13, "word": " كنا", "probability": 0.97021484375}, {"start": 367.13, "end": 367.45, "word": " نقول", "probability": 0.90771484375}, {"start": 367.45, "end": 367.79, "word": " أنه", "probability": 0.52978515625}, 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"word": " اتنين", "probability": 0.88916015625}, {"start": 578.57, "end": 579.35, "word": " بالعشرة", "probability": 0.9630126953125}, {"start": 579.35, "end": 580.41, "word": " الان", "probability": 0.6466064453125}, {"start": 580.41, "end": 581.33, "word": " لاحظوا", "probability": 0.9603271484375}, {"start": 581.33, "end": 581.63, "word": " ع", "probability": 0.29931640625}, {"start": 581.63, "end": 581.93, "word": " طول", "probability": 0.8466796875}, {"start": 581.93, "end": 582.93, "word": " ملاحظة", "probability": 0.98837890625}, {"start": 582.93, "end": 583.83, "word": " الأمينز", "probability": 0.80572509765625}, {"start": 583.83, "end": 583.97, "word": " اللي", "probability": 0.802978515625}, {"start": 583.97, "end": 584.09, "word": " في", "probability": 0.85498046875}, {"start": 584.09, "end": 584.63, "word": " الأول", "probability": 0.92431640625}, {"start": 584.63, "end": 585.41, "word": " مثل", "probability": 0.97900390625}, {"start": 585.41, "end": 586.01, "word": " أمين", "probability": 0.9059244791666666}, {"start": 586.01, "end": 586.31, "word": " ضاي", "probability": 0.41021728515625}, {"start": 586.31, "end": 586.71, "word": " مثل", "probability": 0.989013671875}, {"start": 586.71, "end": 587.21, "word": " أمين", "probability": 0.9833984375}, {"start": 587.21, "end": 587.65, "word": " و", "probability": 0.68359375}, {"start": 587.65, "end": 588.09, "word": " لحد", "probability": 0.97900390625}, {"start": 588.09, "end": 589.07, "word": " الأللين", "probability": 0.9385986328125}, {"start": 589.07, "end": 589.53, "word": " هنا", "probability": 0.92333984375}, {"start": 589.53, "end": 590.55, "word": " صار", "probability": 0.93896484375}, {"start": 590.55, "end": 590.89, "word": " عندى", "probability": 0.775634765625}, {"start": 590.89, "end": 591.37, "word": " تغير", "probability": 0.97216796875}, {"start": 591.37, "end": 591.89, "word": " كتير", "probability": 0.98876953125}, {"start": 591.89, "end": 592.15, "word": " يعني", "probability": 0.845458984375}, {"start": 592.15, "end": 592.57, "word": " لحد", "probability": 0.97705078125}, {"start": 592.57, "end": 593.13, "word": " هدولة", "probability": 0.930908203125}, {"start": 593.13, "end": 593.69, "word": " كلهم", "probability": 0.98876953125}], "temperature": 1.0}, {"id": 27, "seek": 61741, "start": 594.83, "end": 617.41, "text": "كانت ال بي كي بي قليلة تلاتة تلاتة أربعة لما صرت فيه الانليل و التوابع صرت تسعة الان هدول ايش بيفرقوا عن بعض لحد هذا الخط هدول اللي فوق aliphatic amines اللي تحت aromatic amines واضح؟ اذا هذه منطقات", "tokens": [41361, 2655, 2423, 4724, 1829, 9122, 1829, 4724, 1829, 12174, 20292, 37977, 6055, 1211, 9307, 3660, 6055, 1211, 9307, 3660, 5551, 25513, 27884, 5296, 15042, 20328, 43500, 8978, 3224, 2423, 7649, 20292, 1211, 4032, 16712, 14407, 3555, 3615, 20328, 43500, 6055, 3794, 27884, 2423, 7649, 8032, 3215, 12610, 1975, 1829, 8592, 4724, 33911, 2288, 4587, 14407, 18871, 45030, 11242, 5296, 24401, 23758, 33962, 9566, 8032, 3215, 12610, 13672, 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0.8250325520833334}, {"start": 598.81, "end": 599.83, "word": " لما", "probability": 0.9033203125}, {"start": 599.83, "end": 600.21, "word": " صرت", "probability": 0.911376953125}, {"start": 600.21, "end": 600.73, "word": " فيه", "probability": 0.763671875}, {"start": 600.73, "end": 601.59, "word": " الانليل", "probability": 0.6300048828125}, {"start": 601.59, "end": 601.71, "word": " و", "probability": 0.3125}, {"start": 601.71, "end": 602.21, "word": " التوابع", "probability": 0.9188232421875}, {"start": 602.21, "end": 602.55, "word": " صرت", "probability": 0.873291015625}, {"start": 602.55, "end": 603.13, "word": " تسعة", "probability": 0.9744466145833334}, {"start": 603.13, "end": 603.73, "word": " الان", "probability": 0.625}, {"start": 603.73, "end": 604.07, "word": " هدول", "probability": 0.8678385416666666}, {"start": 604.07, "end": 604.39, "word": " ايش", "probability": 0.585205078125}, {"start": 604.39, "end": 605.03, "word": " بيفرقوا", "probability": 0.84619140625}, {"start": 605.03, "end": 605.21, "word": " عن", "probability": 0.9833984375}, {"start": 605.21, "end": 605.79, "word": " بعض", "probability": 0.994384765625}, {"start": 605.79, "end": 607.25, "word": " لحد", "probability": 0.898681640625}, {"start": 607.25, "end": 607.55, "word": " هذا", "probability": 0.89599609375}, {"start": 607.55, "end": 608.05, "word": " الخط", "probability": 0.9833984375}, {"start": 608.05, "end": 609.03, "word": " هدول", "probability": 0.9462890625}, {"start": 609.03, "end": 609.23, "word": " اللي", "probability": 0.90625}, {"start": 609.23, "end": 609.67, "word": " فوق", "probability": 0.990478515625}, {"start": 609.67, "end": 610.61, "word": " aliphatic", "probability": 0.5916341145833334}, {"start": 610.61, "end": 611.35, "word": " amines", "probability": 0.81640625}, {"start": 611.35, "end": 611.97, "word": " اللي", "probability": 0.944580078125}, {"start": 611.97, "end": 612.45, "word": " تحت", "probability": 0.98046875}, {"start": 612.45, "end": 613.67, "word": " aromatic", "probability": 0.84814453125}, {"start": 613.67, "end": 614.51, "word": " amines", "probability": 0.917724609375}, {"start": 614.51, "end": 615.43, "word": " واضح؟", "probability": 0.79620361328125}, {"start": 615.43, "end": 616.05, "word": " اذا", "probability": 0.73193359375}, {"start": 616.05, "end": 616.65, "word": " هذه", "probability": 0.82958984375}, {"start": 616.65, "end": 617.41, "word": " منطقات", "probability": 0.7760009765625}], "temperature": 1.0}, {"id": 28, "seek": 63491, "start": 618.35, "end": 634.91, "text": "الالفاتك أمين هذي منطقة ال aromatic amines لو إجينا سألنا مين بيكونوا ك basis أقوى الالفاتك أمين ولا ال aromatic amines؟ الالفاتك أمين", "tokens": [6027, 6027, 5172, 9307, 4117, 5551, 2304, 9957, 8032, 8848, 1829, 9154, 9566, 28671, 2423, 45831, 669, 1652, 45164, 11933, 7435, 1829, 8315, 8608, 10721, 1211, 8315, 3714, 9957, 4724, 1829, 30544, 14407, 9122, 5143, 5551, 4587, 2407, 7578, 2423, 6027, 5172, 9307, 4117, 5551, 2304, 9957, 49429, 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"probability": 0.9012451171875}, {"start": 625.25, "end": 626.05, "word": " مين", "probability": 0.96826171875}, {"start": 626.05, "end": 626.89, "word": " بيكونوا", "probability": 0.96240234375}, {"start": 626.89, "end": 627.17, "word": " ك", "probability": 0.92041015625}, {"start": 627.17, "end": 627.87, "word": " basis", "probability": 0.4580078125}, {"start": 627.87, "end": 629.13, "word": " أقوى", "probability": 0.9732666015625}, {"start": 629.13, "end": 630.27, "word": " الالفاتك", "probability": 0.7444580078125}, {"start": 630.27, "end": 630.85, "word": " أمين", "probability": 0.939453125}, {"start": 630.85, "end": 631.47, "word": " ولا", "probability": 0.7685546875}, {"start": 631.47, "end": 631.69, "word": " ال", "probability": 0.93408203125}, {"start": 631.69, "end": 632.23, "word": " aromatic", "probability": 0.9541015625}, {"start": 632.23, "end": 633.43, "word": " amines؟", "probability": 0.78271484375}, {"start": 633.43, "end": 634.47, "word": " الالفاتك", "probability": 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"word": " ممكن", "probability": 0.83642578125}, {"start": 663.94, "end": 664.84, "word": " نكمل", "probability": 0.91748046875}, {"start": 664.84, "end": 665.12, "word": " لكم،", "probability": 0.5358072916666666}, {"start": 665.12, "end": 665.66, "word": " نقولكم", "probability": 0.8494466145833334}, {"start": 665.66, "end": 666.08, "word": " إيش", "probability": 0.776611328125}, {"start": 666.08, "end": 666.84, "word": " ال", "probability": 0.50146484375}, {"start": 666.84, "end": 667.18, "word": " due", "probability": 0.51953125}, {"start": 667.18, "end": 667.82, "word": " to", "probability": 0.2734375}, {"start": 667.82, "end": 668.72, "word": " بسبب", "probability": 0.9713541666666666}, {"start": 668.72, "end": 669.34, "word": " إيش؟", "probability": 0.9056396484375}, {"start": 669.34, "end": 670.54, "word": " ليش", "probability": 0.8935546875}, {"start": 670.54, "end": 672.08, "word": " بدنا", "probability": 0.6165771484375}, {"start": 672.08, "end": 672.58, "word": " نحكي", 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الضعف اللي بين لضعاف أساساً بسبب إيش؟ ال inductive effect", "tokens": [9566, 3555, 3615, 995, 14111, 4724, 8592, 28820, 6225, 10943, 28242, 16095, 7251, 34268, 26890, 14407, 48812, 3615, 31845, 12399, 32239, 8592, 22807, 5296, 33456, 28242, 16095, 8978, 16095, 30944, 12399, 28242, 16095, 7251, 34268, 26890, 14407, 9122, 5143, 48812, 3615, 31845, 12399, 44381, 36764, 24401, 5551, 11242, 3615, 5172, 9154, 16712, 7649, 1829, 5551, 11242, 3615, 5172, 9154, 16712, 6027, 2655, 12399, 16247, 1863, 6156, 2288, 4587, 6024, 114, 3615, 5172, 13672, 1829, 49374, 5296, 11242, 3615, 31845, 5551, 3794, 32277, 995, 14111, 4724, 35457, 3555, 11933, 1829, 8592, 22807, 2423, 31612, 488, 1802], "avg_logprob": -0.15315754882370433, "compression_ratio": 1.7837837837837838, "no_speech_prob": 0.0, "words": [{"start": 1207.81, "end": 1208.39, "word": "طبعاً", "probability": 0.788671875}, {"start": 1208.39, "end": 1209.01, "word": " بشكل", "probability": 0.9324544270833334}, {"start": 1209.01, "end": 1209.51, 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1223.25, "word": " الضعف", "probability": 0.947998046875}, {"start": 1223.25, "end": 1223.61, "word": " اللي", "probability": 0.938720703125}, {"start": 1223.61, "end": 1223.85, "word": " بين", "probability": 0.99560546875}, {"start": 1223.85, "end": 1224.79, "word": " لضعاف", "probability": 0.754364013671875}, {"start": 1224.79, "end": 1226.61, "word": " أساساً", "probability": 0.86328125}, {"start": 1226.61, "end": 1227.31, "word": " بسبب", "probability": 0.9254557291666666}, {"start": 1227.31, "end": 1228.43, "word": " إيش؟", "probability": 0.8580322265625}, {"start": 1228.43, "end": 1228.55, "word": " ال", "probability": 0.9033203125}, {"start": 1228.55, "end": 1229.21, "word": " inductive", "probability": 0.888671875}, {"start": 1229.21, "end": 1229.71, "word": " effect", "probability": 0.95068359375}], "temperature": 1.0}, {"id": 52, "seek": 124415, "start": 1230.49, "end": 1244.15, "text": "لكن لو أنا باجي بسألكم والله بشكل عام ال nitroaniline is a weak base، ليش؟ هتقولولي ال resonance مصيبة؟", "tokens": [1211, 19452, 45164, 41850, 4724, 26108, 1829, 4724, 3794, 10721, 23275, 2304, 16070, 43761, 4724, 8592, 28820, 6225, 10943, 2423, 10900, 340, 282, 388, 533, 307, 257, 5336, 3096, 12399, 32239, 8592, 22807, 8032, 2655, 39648, 12610, 1829, 2423, 30944, 3714, 9381, 1829, 49401, 22807], "avg_logprob": -0.1842730945867041, "compression_ratio": 1.2, "no_speech_prob": 0.0, "words": [{"start": 1230.49, "end": 1230.91, "word": "لكن", "probability": 0.8544921875}, {"start": 1230.91, "end": 1231.09, "word": " لو", "probability": 0.966796875}, {"start": 1231.09, "end": 1231.33, "word": " أنا", "probability": 0.58935546875}, {"start": 1231.33, "end": 1231.67, "word": " باجي", "probability": 0.9404296875}, {"start": 1231.67, "end": 1232.45, "word": " بسألكم", "probability": 0.8916015625}, {"start": 1232.45, "end": 1233.13, "word": " والله", "probability": 0.75}, {"start": 1233.13, "end": 1233.77, "word": " بشكل", "probability": 0.9752604166666666}, {"start": 1233.77, 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1.0}, {"id": 53, "seek": 126994, "start": 1244.88, "end": 1269.94, "text": "و الحاجات هم صيبة تانية ال nitro يعني صار سبب ضعفه شغل فيه ال resonance و ال inductive effect لكن لو كنت بدأ اقارنه مثلا مع ال methyl aniline لأ بقول ما هو ال resonance و ال resonance هم عامل مشترك بطل هو اللي مفرج صار إيش اللي مفرج؟ شكل أساسي ال inductive effect واضحة الفكرة؟", "tokens": [2407, 21542, 26108, 9307, 8032, 2304, 20328, 1829, 49401, 6055, 7649, 10632, 2423, 10900, 340, 37495, 22653, 20328, 9640, 8608, 3555, 3555, 48812, 3615, 5172, 3224, 13412, 17082, 1211, 8978, 3224, 2423, 30944, 4032, 2423, 31612, 488, 1802, 44381, 45164, 9122, 29399, 47525, 10721, 1975, 4587, 9640, 1863, 3224, 50113, 15040, 20449, 2423, 48441, 364, 388, 533, 5296, 10721, 4724, 39648, 19446, 31439, 2423, 30944, 4032, 2423, 30944, 8032, 2304, 6225, 10943, 1211, 37893, 2655, 31747, 4724, 9566, 1211, 31439, 13672, 1829, 3714, 5172, 47341, 20328, 9640, 11933, 1829, 8592, 13672, 1829, 3714, 5172, 47341, 22807, 13412, 28820, 5551, 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"probability": 0.9775390625}, {"start": 1258.5, "end": 1259.02, "word": " resonance", "probability": 0.982421875}, {"start": 1259.02, "end": 1259.24, "word": " و", "probability": 0.837890625}, {"start": 1259.24, "end": 1259.34, "word": " ال", "probability": 0.953125}, {"start": 1259.34, "end": 1259.7, "word": " resonance", "probability": 0.978515625}, {"start": 1259.7, "end": 1260.06, "word": " هم", "probability": 0.5208740234375}, {"start": 1260.06, "end": 1260.38, "word": " عامل", "probability": 0.9934895833333334}, {"start": 1260.38, "end": 1260.9, "word": " مشترك", "probability": 0.96630859375}, {"start": 1260.9, "end": 1261.34, "word": " بطل", "probability": 0.9083658854166666}, {"start": 1261.34, "end": 1261.5, "word": " هو", "probability": 0.978515625}, {"start": 1261.5, "end": 1261.72, "word": " اللي", "probability": 0.9306640625}, {"start": 1261.72, "end": 1262.22, "word": " مفرج", "probability": 0.826171875}, {"start": 1262.22, "end": 1262.98, "word": " صار", "probability": 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{"start": 1554.02, "end": 1554.44, "word": " مع", "probability": 0.89404296875}, {"start": 1554.44, "end": 1554.66, "word": " ال", "probability": 0.8984375}, {"start": 1554.66, "end": 1555.36, "word": " amines", "probability": 0.5557861328125}, {"start": 1555.36, "end": 1555.64, "word": " لما", "probability": 0.789794921875}, {"start": 1555.64, "end": 1555.98, "word": " تكون", "probability": 0.987548828125}, {"start": 1555.98, "end": 1556.14, "word": " ال", "probability": 0.93603515625}, {"start": 1556.14, "end": 1556.38, "word": " H", "probability": 0.75244140625}, {"start": 1556.38, "end": 1556.54, "word": " و", "probability": 0.77099609375}, {"start": 1556.54, "end": 1556.66, "word": " ال", "probability": 0.5771484375}, {"start": 1556.66, "end": 1557.06, "word": " OH", "probability": 0.83544921875}, {"start": 1557.06, "end": 1557.6, "word": " جانب", "probability": 0.8758138020833334}, {"start": 1557.6, "end": 1557.96, "word": " بعض،", "probability": 0.7942708333333334}, {"start": 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"قولنا احنا كل N H2 مع C double bond O ماصيرها النهائي C double bond O الديهيد او كيتون تصير C double bond N CH2 CH3 بصير ال shift basis وقولنا ان التفاعل بهذه الحالة ايش بنقول عنه addition elimination", "tokens": [39648, 8315, 1975, 5016, 8315, 28242, 426, 389, 17, 20449, 383, 3834, 6086, 422, 19446, 9381, 13546, 11296, 28239, 3224, 16373, 1829, 383, 3834, 6086, 422, 2423, 16254, 3224, 25708, 1975, 2407, 9122, 36081, 11536, 6055, 9381, 13546, 383, 3834, 6086, 426, 5995, 17, 5995, 18, 4724, 9381, 13546, 2423, 5513, 5143, 4032, 39648, 8315, 16472, 16712, 5172, 995, 30241, 39627, 24192, 21542, 6027, 3660, 1975, 1829, 8592, 44945, 39648, 18871, 3224, 4500, 29224], "avg_logprob": -0.32937499205271403, "compression_ratio": 1.559782608695652, "no_speech_prob": 0.0, "words": [{"start": 1568.45, "end": 1568.93, "word": "قولنا", "probability": 0.53009033203125}, {"start": 1568.93, "end": 1569.19, "word": " احنا", "probability": 0.7599283854166666}, {"start": 1569.19, "end": 1569.47, "word": " 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"probability": 0.96484375}, {"start": 1573.61, "end": 1573.79, "word": " O", "probability": 0.9501953125}, {"start": 1573.79, "end": 1574.35, "word": " الديهيد", "probability": 0.70416259765625}, {"start": 1574.35, "end": 1574.59, "word": " او", "probability": 0.897216796875}, {"start": 1574.59, "end": 1575.07, "word": " كيتون", "probability": 0.8253580729166666}, {"start": 1575.07, "end": 1576.31, "word": " تصير", "probability": 0.88623046875}, {"start": 1576.31, "end": 1577.13, "word": " C", "probability": 0.791015625}, {"start": 1577.13, "end": 1577.45, "word": " double", "probability": 0.9033203125}, {"start": 1577.45, "end": 1577.99, "word": " bond", "probability": 0.974609375}, {"start": 1577.99, "end": 1578.65, "word": " N", "probability": 0.974609375}, {"start": 1578.65, "end": 1580.41, "word": " CH2", "probability": 0.780517578125}, {"start": 1580.41, "end": 1581.23, "word": " CH3", "probability": 0.908203125}, {"start": 1581.23, "end": 1581.63, "word": " بصير", "probability": 0.67626953125}, {"start": 1581.63, "end": 1581.81, "word": " ال", "probability": 0.1715087890625}, {"start": 1581.81, "end": 1582.13, "word": " shift", "probability": 0.37890625}, {"start": 1582.13, "end": 1582.75, "word": " basis", "probability": 0.5732421875}, {"start": 1582.75, "end": 1583.79, "word": " وقولنا", "probability": 0.8548177083333334}, {"start": 1583.79, "end": 1583.93, "word": " ان", "probability": 0.76171875}, {"start": 1583.93, "end": 1584.59, "word": " التفاعل", "probability": 0.924072265625}, {"start": 1584.59, "end": 1584.95, "word": " بهذه", "probability": 0.571044921875}, {"start": 1584.95, "end": 1585.37, "word": " الحالة", "probability": 0.95654296875}, {"start": 1585.37, "end": 1585.57, "word": " ايش", "probability": 0.818359375}, {"start": 1585.57, "end": 1586.01, "word": " بنقول", "probability": 0.847412109375}, {"start": 1586.01, "end": 1586.51, "word": " عنه", "probability": 0.970703125}, {"start": 1586.51, "end": 1587.59, "word": " addition", "probability": 0.72607421875}, {"start": 1587.59, "end": 1590.37, "word": " elimination", "probability": 0.45068359375}], "temperature": 1.0}, {"id": 66, "seek": 160815, "start": 1591.67, "end": 1608.15, "text": "نسيته تفاعل تكوين الأكزينز والهيدرازونز والسمي كربازونز كل ال N-H2 مع ال C double bond O الديهيدوكيتون كانت تعمل C double bond N على خطوتين لكن في الأساس أن الأمين تفاعل كإيش؟", "tokens": [1863, 3794, 36081, 3224, 6055, 5172, 995, 30241, 6055, 4117, 2407, 9957, 16247, 4117, 11622, 9957, 11622, 16070, 3224, 25708, 2288, 31377, 11536, 11622, 16070, 38251, 1829, 9122, 25513, 31377, 11536, 11622, 28242, 2423, 426, 12, 39, 17, 20449, 2423, 383, 3834, 6086, 422, 2423, 16254, 3224, 25708, 2407, 4117, 36081, 11536, 25961, 2655, 6055, 25957, 1211, 383, 3834, 6086, 426, 15844, 16490, 9566, 35473, 9957, 44381, 8978, 16247, 3794, 32277, 14739, 16247, 2304, 9957, 6055, 5172, 995, 30241, 9122, 28814, 1829, 8592, 22807], "avg_logprob": -0.2680147142971263, "compression_ratio": 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{"start": 1598.03, "end": 1598.31, "word": " مع", "probability": 0.97119140625}, {"start": 1598.31, "end": 1598.53, "word": " ال", "probability": 0.82666015625}, {"start": 1598.53, "end": 1598.67, "word": " C", "probability": 0.28955078125}, {"start": 1598.67, "end": 1598.85, "word": " double", "probability": 0.446533203125}, {"start": 1598.85, "end": 1599.25, "word": " bond", "probability": 0.93896484375}, {"start": 1599.25, "end": 1599.57, "word": " O", "probability": 0.95263671875}, {"start": 1599.57, "end": 1600.69, "word": " الديهيدوكيتون", "probability": 0.676910400390625}, {"start": 1600.69, "end": 1601.27, "word": " كانت", "probability": 0.937255859375}, {"start": 1601.27, "end": 1601.59, "word": " تعمل", "probability": 0.9816080729166666}, {"start": 1601.59, "end": 1601.81, "word": " C", "probability": 0.76806640625}, {"start": 1601.81, "end": 1601.99, "word": " double", "probability": 0.91455078125}, {"start": 1601.99, "end": 1602.37, "word": " bond", "probability": 0.97119140625}, {"start": 1602.37, "end": 1602.53, "word": " N", "probability": 0.96337890625}, {"start": 1602.53, "end": 1602.73, "word": " على", "probability": 0.8720703125}, {"start": 1602.73, "end": 1603.41, "word": " خطوتين", "probability": 0.85845947265625}, {"start": 1603.41, "end": 1604.19, "word": " لكن", "probability": 0.82177734375}, {"start": 1604.19, "end": 1604.45, "word": " في", "probability": 0.91943359375}, {"start": 1604.45, "end": 1605.45, "word": " الأساس", "probability": 0.9401041666666666}, {"start": 1605.45, "end": 1606.13, "word": " أن", "probability": 0.591796875}, {"start": 1606.13, "end": 1606.79, "word": " الأمين", "probability": 0.8118489583333334}, {"start": 1606.79, "end": 1607.41, "word": " تفاعل", "probability": 0.9718017578125}, {"start": 1607.41, "end": 1608.15, "word": " كإيش؟", "probability": 0.85517578125}], "temperature": 1.0}, {"id": 67, "seek": 163448, "start": 1608.98, "end": 1634.48, "text": "كان uqlu5 وعمل addition الان بعد هيك ان ال addition اتبع ال elimination هذا امر ايش تاني هذا المحصلة النهائية لكن ال addition ادشن و ال uqlu5 ال uqlu5 فال amines تفاعلهم الأساسي بنقول هو ايش they react as uqlu5 as uqlu5 واضح؟", "tokens": [41361, 344, 80, 2781, 20, 4032, 25957, 1211, 4500, 2423, 7649, 39182, 39896, 4117, 16472, 2423, 4500, 1975, 2655, 3555, 3615, 2423, 29224, 23758, 1975, 29973, 1975, 1829, 8592, 6055, 7649, 1829, 23758, 9673, 5016, 36520, 3660, 28239, 3224, 16373, 10632, 44381, 2423, 4500, 1975, 3215, 8592, 1863, 4032, 2423, 344, 80, 2781, 20, 2423, 344, 80, 2781, 20, 6156, 6027, 669, 1652, 6055, 5172, 995, 30241, 16095, 16247, 3794, 32277, 1829, 44945, 39648, 31439, 1975, 1829, 8592, 436, 4515, 382, 344, 80, 2781, 20, 382, 344, 80, 2781, 20, 4032, 46958, 5016, 22807], "avg_logprob": -0.2791118521439402, "compression_ratio": 1.6785714285714286, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1608.98, "end": 1609.28, "word": "كان", "probability": 0.80810546875}, {"start": 1609.28, "end": 1610.44, "word": " 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"probability": 0.437744140625}, {"start": 1620.98, "end": 1621.72, "word": " uqlu5", "probability": 0.9527587890625}, {"start": 1621.72, "end": 1621.88, "word": " ال", "probability": 0.705078125}, {"start": 1621.88, "end": 1622.78, "word": " uqlu5", "probability": 0.9798583984375}, {"start": 1622.78, "end": 1623.48, "word": " فال", "probability": 0.868408203125}, {"start": 1623.48, "end": 1624.1, "word": " amines", "probability": 0.5814208984375}, {"start": 1624.1, "end": 1624.84, "word": " تفاعلهم", "probability": 0.8880859375}, {"start": 1624.84, "end": 1625.52, "word": " الأساسي", "probability": 0.81939697265625}, {"start": 1625.52, "end": 1625.8, "word": " بنقول", "probability": 0.789794921875}, {"start": 1625.8, "end": 1625.98, "word": " هو", "probability": 0.82421875}, {"start": 1625.98, "end": 1627.3, "word": " ايش", "probability": 0.8304036458333334}, {"start": 1627.3, "end": 1627.58, "word": " they", "probability": 0.52392578125}, {"start": 1627.58, "end": 1628.46, "word": " react", "probability": 0.92041015625}, {"start": 1628.46, "end": 1629.24, "word": " as", "probability": 0.97802734375}, {"start": 1629.24, "end": 1630.84, "word": " uqlu5", "probability": 0.82696533203125}, {"start": 1630.84, "end": 1632.24, "word": " as", "probability": 0.55859375}, {"start": 1632.24, "end": 1633.2, "word": " uqlu5", "probability": 0.968017578125}, {"start": 1633.2, "end": 1634.48, "word": " واضح؟", "probability": 0.8817138671875}], "temperature": 1.0}, {"id": 68, "seek": 166584, "start": 1636.42, "end": 1665.84, "text": "لكن لو جينا سألناكم ال reaction of amines with aldehydes and ketones is a nucleophilic addition in a brain cell واضح؟ انه بعدك followed by elimination على أنه الرأس مرة تبسيط واضح؟ with acids and their derivatives a nucleophilic substitution with alkyl halides برضه nucleophilic substitution", "tokens": [1211, 19452, 45164, 10874, 1829, 8315, 8608, 10721, 1211, 8315, 24793, 2423, 5480, 295, 669, 1652, 365, 16798, 68, 3495, 14792, 293, 14979, 2213, 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2170.46, "end": 2170.94, "word": "يعني", "probability": 0.9501953125}, {"start": 2170.94, "end": 2171.66, "word": " بتكون", "probability": 0.9150390625}, {"start": 2171.66, "end": 2172.12, "word": " عشر", "probability": 0.93359375}, {"start": 2172.12, "end": 2174.08, "word": " كربونات،", "probability": 0.7752482096354166}, {"start": 2174.08, "end": 2174.82, "word": " اتنائش،", "probability": 0.833740234375}, {"start": 2174.82, "end": 2175.12, "word": " اربعة", "probability": 0.6787109375}, {"start": 2175.12, "end": 2175.5, "word": " عاشر،", "probability": 0.717529296875}, {"start": 2175.5, "end": 2175.76, "word": " ستة", "probability": 0.84619140625}, {"start": 2175.76, "end": 2176.0, "word": " عاشر،", "probability": 0.9342041015625}, {"start": 2176.0, "end": 2176.32, "word": " تمانة", "probability": 0.6844889322916666}, {"start": 2176.32, "end": 2176.7, "word": " عاشر،", "probability": 0.969970703125}, {"start": 2176.7, "end": 2177.22, "word": " اشرين", "probability": 0.714599609375}, 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"end": 2183.76, "word": " هذه", "probability": 0.73193359375}, {"start": 2183.76, "end": 2184.58, "word": " المركبات", "probability": 0.84661865234375}, {"start": 2184.58, "end": 2185.62, "word": " التمتاز", "probability": 0.94384765625}, {"start": 2185.62, "end": 2186.14, "word": " ان", "probability": 0.69140625}, {"start": 2186.14, "end": 2186.58, "word": " فيها", "probability": 0.916259765625}, {"start": 2186.58, "end": 2187.18, "word": " طرف", "probability": 0.996337890625}, {"start": 2187.18, "end": 2189.48, "word": " polar", "probability": 0.91796875}, {"start": 2189.48, "end": 2191.8, "word": " و", "probability": 0.94189453125}, {"start": 2191.8, "end": 2192.3, "word": " طرف", "probability": 0.8984375}, {"start": 2192.3, "end": 2193.5, "word": " non", "probability": 0.97119140625}, {"start": 2193.5, "end": 2193.98, "word": " polar", "probability": 0.51318359375}], "temperature": 1.0}, {"id": 91, "seek": 220282, "start": 2195.86, "end": 2202.82, "text": "الـ R في الـ fatty acids الـ non-polar الكبير، خلّينا نقول من عشرة و فوق", "tokens": [6027, 39184, 497, 8978, 2423, 39184, 24898, 21667, 2423, 39184, 2107, 12, 12892, 289, 33251, 3555, 13546, 12399, 16490, 1211, 11703, 9957, 995, 8717, 39648, 9154, 6225, 8592, 25720, 4032, 6156, 30543], "avg_logprob": -0.27296401515151514, "compression_ratio": 1.0679611650485437, "no_speech_prob": 0.0, "words": [{"start": 2195.86, "end": 2196.3, "word": "الـ", "probability": 0.703857421875}, {"start": 2196.3, "end": 2196.62, "word": " R", "probability": 0.64453125}, {"start": 2196.62, "end": 2197.52, "word": " في", "probability": 0.8154296875}, {"start": 2197.52, "end": 2197.76, "word": " الـ", "probability": 0.5850830078125}, {"start": 2197.76, "end": 2198.04, "word": " fatty", "probability": 0.344482421875}, {"start": 2198.04, "end": 2198.72, "word": " acids", "probability": 0.6494140625}, {"start": 2198.72, "end": 2199.26, "word": " الـ", "probability": 0.7666015625}, {"start": 2199.26, "end": 2199.4, "word": " non", "probability": 0.64794921875}, {"start": 2199.4, "end": 2199.8, "word": "-polar", "probability": 0.8408203125}, {"start": 2199.8, "end": 2200.82, "word": " الكبير،", "probability": 0.8463134765625}, {"start": 2200.82, "end": 2201.48, "word": " خلّينا", "probability": 0.80966796875}, {"start": 2201.48, "end": 2201.68, "word": " نقول", "probability": 0.994140625}, {"start": 2201.68, "end": 2201.84, "word": " من", "probability": 0.9462890625}, {"start": 2201.84, "end": 2202.28, "word": " عشرة", "probability": 0.87451171875}, {"start": 2202.28, "end": 2202.42, "word": " و", "probability": 0.97021484375}, {"start": 2202.42, "end": 2202.82, "word": " فوق", "probability": 0.6522216796875}], "temperature": 1.0}, {"id": 92, "seek": 222888, "start": 2204.38, "end": 2228.88, "text": "وبناء على ذلك الجزيء بمجمله يغلب عليه الـ non-polar part فبصير water soluble ولا insoluble؟ بصير non-polar طالما صار non-polar صار water insoluble بصير دوب في ال organic solvent إذا هذه الجزيئات اللي فيها القاري الكبيرة هي اللي بنسميها الـ fatty acids", "tokens": [37746, 1863, 16606, 15844, 29910, 23275, 25724, 11622, 1829, 38207, 4724, 2304, 7435, 42213, 3224, 7251, 17082, 46152, 47356, 2423, 39184, 2107, 12, 12892, 289, 644, 6156, 3555, 9381, 13546, 1281, 24807, 638, 49429, 1028, 39754, 638, 22807, 4724, 9381, 13546, 2107, 12, 12892, 289, 23032, 6027, 15042, 20328, 9640, 2107, 12, 12892, 289, 20328, 9640, 1281, 1028, 39754, 638, 4724, 9381, 13546, 11778, 37746, 8978, 2423, 10220, 33575, 11933, 15730, 29538, 25724, 11622, 1829, 19986, 9307, 13672, 1829, 8978, 11296, 25062, 9640, 1829, 33251, 3555, 48923, 39896, 13672, 1829, 44945, 38251, 1829, 11296, 2423, 39184, 24898, 21667], "avg_logprob": -0.2788825865947839, "compression_ratio": 1.6415929203539823, "no_speech_prob": 0.0, "words": [{"start": 2204.38, "end": 2205.06, "word": "وبناء", "probability": 0.794921875}, {"start": 2205.06, "end": 2205.48, "word": " على", "probability": 0.751953125}, {"start": 2205.48, "end": 2206.18, "word": " 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"end": 2221.2, "word": " بصير", "probability": 0.7610677083333334}, {"start": 2221.2, "end": 2221.42, "word": " دوب", "probability": 0.78857421875}, {"start": 2221.42, "end": 2221.58, "word": " في", "probability": 0.92333984375}, {"start": 2221.58, "end": 2221.68, "word": " ال", "probability": 0.71728515625}, {"start": 2221.68, "end": 2222.16, "word": " organic", "probability": 0.83154296875}, {"start": 2222.16, "end": 2222.8, "word": " solvent", "probability": 0.763671875}, {"start": 2222.8, "end": 2223.48, "word": " إذا", "probability": 0.600341796875}, {"start": 2223.48, "end": 2224.54, "word": " هذه", "probability": 0.84130859375}, {"start": 2224.54, "end": 2225.54, "word": " الجزيئات", "probability": 0.95869140625}, {"start": 2225.54, "end": 2225.74, "word": " اللي", "probability": 0.784423828125}, {"start": 2225.74, "end": 2226.12, "word": " فيها", "probability": 0.979248046875}, {"start": 2226.12, "end": 2226.64, "word": " القاري", "probability": 0.6139322916666666}, {"start": 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التفاعل، الآن هاي كحول في الجليسرين و هاي حمض، خليهم يتفاعلوا", "tokens": [2407, 46958, 5016, 22807, 8032, 2304, 4724, 3555, 3794, 41193, 3660, 9122, 25513, 2407, 4117, 3794, 26895, 4117, 5551, 3794, 1863, 3794, 9122, 3555, 9640, 12399, 6024, 48506, 45164, 5551, 7435, 1829, 8315, 4032, 12174, 12610, 8315, 9122, 5016, 12610, 30767, 16373, 3215, 11331, 2304, 11242, 12399, 13412, 2407, 4724, 40228, 9566, 1829, 22653, 22807, 11933, 1829, 14851, 2288, 12399, 45164, 5551, 9778, 3215, 8315, 36632, 9122, 5016, 12610, 30767, 16373, 3215, 11331, 2304, 11242, 12399, 11933, 1829, 14851, 2288, 12399, 23758, 5551, 9778, 3215, 8315, 16712, 5172, 995, 30241, 12399, 6024, 48506, 8032, 47302, 9122, 5016, 12610, 8978, 25724, 20292, 3794, 2288, 9957, 4032, 8032, 47302, 11331, 2304, 11242, 12399, 16490, 20292, 16095, 7251, 2655, 5172, 995, 30241, 14407], "avg_logprob": -0.21410123868422073, "compression_ratio": 1.9565217391304348, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2266.07, 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خلال", "probability": 0.9952799479166666}, {"start": 2986.39, "end": 2986.61, "word": " أنه", "probability": 0.4925537109375}, {"start": 2986.61, "end": 2986.71, "word": " أنا", "probability": 0.716796875}, {"start": 2986.71, "end": 2987.27, "word": " بستفيد", "probability": 0.8802490234375}, {"start": 2987.27, "end": 2987.45, "word": " من", "probability": 0.98828125}, {"start": 2987.45, "end": 2988.09, "word": " التفاعل", "probability": 0.9146728515625}, {"start": 2988.09, "end": 2988.67, "word": " الأصلي", "probability": 0.7545572916666666}, {"start": 2988.67, "end": 2988.75, "word": " اللي", "probability": 0.96435546875}, {"start": 2988.75, "end": 2989.13, "word": " أخدته", "probability": 0.94873046875}, {"start": 2989.13, "end": 2989.21, "word": " في", "probability": 0.904296875}, {"start": 2989.21, "end": 2989.59, "word": " شبتر", "probability": 0.78741455078125}, {"start": 2989.59, "end": 2990.11, "word": " واحد", "probability": 0.93017578125}, {"start": 2990.11, "end": 2990.65, "word": " أنه", "probability": 0.676025390625}, {"start": 2990.65, "end": 2991.25, "word": " الألكيز", "probability": 0.63677978515625}, {"start": 2991.25, "end": 2991.73, "word": " بتحض", "probability": 0.5010986328125}, {"start": 2991.73, "end": 2991.89, "word": " مع", "probability": 0.80517578125}, {"start": 2991.89, "end": 2992.13, "word": " ال", "probability": 0.63916015625}, {"start": 2992.13, "end": 2993.95, "word": " oxygen", "probability": 0.2073974609375}, {"start": 2993.95, "end": 2994.31, "word": " و", "probability": 0.56884765625}, {"start": 2994.31, "end": 2994.47, "word": " ال", "probability": 0.52294921875}, {"start": 2994.47, "end": 2995.35, "word": " combustion", "probability": 0.87158203125}, {"start": 2995.35, "end": 2996.67, "word": " طلعوا", "probability": 0.8939208984375}, {"start": 2996.67, "end": 2996.91, "word": " ثانو", "probability": 0.8336588541666666}, {"start": 2996.91, "end": 2997.11, "word": " أكسيد", "probability": 0.848388671875}, {"start": 2997.11, "end": 2997.53, "word": " كربون", "probability": 0.9375}, {"start": 2997.53, "end": 2997.65, "word": " و", "probability": 0.98876953125}, {"start": 2997.65, "end": 2997.97, "word": " ميه", "probability": 0.71630859375}, {"start": 2997.97, "end": 2998.15, "word": " و", "probability": 0.9931640625}, {"start": 2998.15, "end": 2998.63, "word": " حرارة", "probability": 0.980712890625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2999.693, "duration_after_vad": 2875.9274999999875}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/rNQZEu2DPCw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/rNQZEu2DPCw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..655cf1e61ea0edf0a1b742f5d3344f520646cba4
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/rNQZEu2DPCw.srt
@@ -0,0 +1,1759 @@
+
+1
+00:00:20,750 --> 00:00:25,750
+بسم الله الرحمن الرحيم بنستغنف اليوم في موضوع ما
+
+2
+00:00:25,750 --> 00:00:30,570
+ساقنا في الكيميا العضوية و الحيوية اعطينا احنا او
+
+3
+00:00:30,570 --> 00:00:35,850
+بدأنا في فصل مقدمة ذكر بمبادئ أساسية بتخدمنا في
+
+4
+00:00:35,850 --> 00:00:41,360
+مجال الكيميا العضويةكان عنوان الفصل اللى احنا
+
+5
+00:00:41,360 --> 00:00:44,700
+بدأنا فيه bonding and isomerism يعني بدنا نتكلم عن
+
+6
+00:00:44,700 --> 00:00:47,600
+أنواع الروابط اتكلمنا عنها ionic compounds,
+
+7
+00:00:47,740 --> 00:00:52,040
+covalent compounds فكرة عن الروابط الأحدية
+
+8
+00:00:52,040 --> 00:00:57,100
+الثنائية الثلاثية قوة الرابطة طول الرابطة كل هذا
+
+9
+00:00:57,100 --> 00:01:01,740
+الكلام اتكلمنا عنه ال valency التكافؤ كل عنصر من
+
+10
+00:01:01,740 --> 00:01:05,800
+العناص الأساسية اللى عندنا كام رابطة بيعمل عادة
+
+11
+00:01:05,800 --> 00:01:10,740
+لما احنا بدنا نكون جزء عضوىالـ polarity of bonds و
+
+12
+00:01:10,740 --> 00:01:15,860
+polarity of compounds اتكلمنا ايضا عنها جزء ثاني
+
+13
+00:01:15,860 --> 00:01:21,480
+المتشكلات لان الكيميا العضوية فكرة اساسية جدا فيها
+
+14
+00:01:21,480 --> 00:01:26,460
+انه مجموعة قليلة من الذرات لكن بتعمل عدد كبير جدا
+
+15
+00:01:26,460 --> 00:01:30,820
+من المركبات يعني اليوم نتكلم عن حوالي عشرين مليون
+
+16
+00:01:30,820 --> 00:01:36,740
+مركب عضوي معروف ومشخصلما نفكر هدول عشرين مليون فقط
+
+17
+00:01:36,740 --> 00:01:41,680
+من الكاربون الهيدروجين النيتروجين الاكسوجين معنى
+
+18
+00:01:41,680 --> 00:01:47,100
+ذلك ان هدول نتجوا نتيجة التشكل هل الكاربون اجت في
+
+19
+00:01:47,100 --> 00:01:50,300
+الاول الاكسوجين في الاول الكلور اجت على الموقع
+
+20
+00:01:50,300 --> 00:01:53,140
+واحد على الموقع اتنين على الموقع تلاتة بتصير أشكال
+
+21
+00:01:53,140 --> 00:01:57,820
+مختلفة بيصير عندنا ظاهرة ال isomers طبعا ال
+
+22
+00:01:57,820 --> 00:02:02,080
+isomers قلنا في منها نوع سهلهو الـ Structural
+
+23
+00:02:02,080 --> 00:02:06,000
+Isomers اللي الذرات بتختلف في ارتباطها والجزيات
+
+24
+00:02:06,000 --> 00:02:10,700
+بتختلف في تسميتها وفي نوع تاني بنفرضله فاصل كامل
+
+25
+00:02:10,700 --> 00:02:16,780
+أثناء شرحنا الـ Stereoisomersكذلك كيف نكتب الصياغ
+
+26
+00:02:16,780 --> 00:02:21,020
+في الكيميا العضوية اتكلمنا عنه وقولنا انه احنا في
+
+27
+00:02:21,020 --> 00:02:25,520
+الكيميا العضوية صح بإمكاننا نكتب الصياغ مفصلة
+
+28
+00:02:25,520 --> 00:02:29,160
+بأعداد الروابط اللي اتفقنا عليها اللي هي لل carbon
+
+29
+00:02:29,160 --> 00:02:32,480
+أربع روابط ال nitrogen تلاتة ال oxygen اتنين ال
+
+30
+00:02:32,480 --> 00:02:37,540
+hydrogen وال halogens واحد لكن بإمكاننا نكتب صياغ
+
+31
+00:02:37,540 --> 00:02:42,720
+مختصرة جدامثل الصياغ اللى أمامكم وناقشناها في
+
+32
+00:02:42,720 --> 00:02:49,640
+المرة الماضية وكل رأس اذا لم يكتب عليه شيء ويجب ان
+
+33
+00:02:49,640 --> 00:02:55,350
+يكمل الى اربع روابط في المجملالان بنجي لنقطة
+
+34
+00:02:55,350 --> 00:02:59,990
+إضافية بتلزمنا أثناء شرحنا في الكيميا العضوية و
+
+35
+00:02:59,990 --> 00:03:02,850
+يفترض أن الناس بيتعلموها أيضا في ال general
+
+36
+00:03:02,850 --> 00:03:07,110
+chemistry اللي هي ال formal charges أو أحيانا
+
+37
+00:03:07,110 --> 00:03:12,700
+بترجموها الشحنات ربما الظاهريةالـ formal charges
+
+38
+00:03:12,700 --> 00:03:18,080
+لو احنا رسمنا جزيء حتى لو كان هذا الجزيء covalent
+
+39
+00:03:18,080 --> 00:03:21,900
+او molecular molecule يعني الروابط اللي فيها
+
+40
+00:03:21,900 --> 00:03:27,540
+covalent bonds وجزيء متعادل بيقول على الذرات اللي
+
+41
+00:03:27,540 --> 00:03:32,900
+موجودة في داخل هذا الجزيء يوجد شحنات بنسميها ايش
+
+42
+00:03:32,900 --> 00:03:39,480
+احنا ال formal charges الان يفترض انه الجزيء ككل
+
+43
+00:03:40,150 --> 00:03:44,310
+يكون عليه شحنة لو كان متعادل معنى ذلك مجموعة
+
+44
+00:03:44,310 --> 00:03:48,190
+الشحنات هذه كلها بساوي سفر يعني لو انا مثلا بدأ
+
+45
+00:03:48,190 --> 00:03:52,090
+احكي عن جزيء زي ال carbon tetrachloride يعني
+
+46
+00:03:52,090 --> 00:03:56,970
+carbon و 4 ذرات كلور المفروض انه كل ذرة من هذه
+
+47
+00:03:56,970 --> 00:04:02,070
+الذرات عليها شحنة انا بسميها formal charge الان
+
+48
+00:04:02,070 --> 00:04:08,130
+الجزء بالمجملبكون مجموعة الشحنات يعني لو أنا قلت
+
+49
+00:04:08,130 --> 00:04:14,270
+CCl4 ذرة كربون وأربع ذرات كلور انبين هنا أي شحنة؟
+
+50
+00:04:14,270 --> 00:04:18,810
+لأ، إذا المفروض يكون عندي شحنات على الكربون شحنات
+
+51
+00:04:18,810 --> 00:04:24,230
+على الكلور ومجموعة هذه الشحنات يساوي إيش؟ سفر لكن
+
+52
+00:04:24,230 --> 00:04:30,570
+لو مثلا أنا حكيت عن ايون زي ما أحكي مثلا CO3 minus
+
+53
+00:04:30,570 --> 00:04:32,290
+minus ايون الكربونين
+
+54
+00:04:36,100 --> 00:04:40,680
+الشحنات المفروضة على الكربون والأكسجين شحنات
+
+55
+00:04:40,680 --> 00:04:44,260
+ومجموعة من هذه الشحنات يسوى ما يعني؟ مايعني مايعني
+
+56
+00:04:44,260 --> 00:04:44,980
+مايعني مايعني مايعني مايعني مايعني مايعني مايعني
+
+57
+00:04:44,980 --> 00:04:46,580
+مايعني مايعني مايعني مايعني مايعني مايعني مايعني
+
+58
+00:04:46,580 --> 00:04:47,380
+مايعني مايعني مايعني مايعني مايعني مايعني مايعني
+
+59
+00:04:47,380 --> 00:04:47,460
+مايعني مايعني مايعني مايعني مايعني مايعني مايعني
+
+60
+00:04:47,460 --> 00:04:47,720
+مايعني مايعني مايعني مايعني مايعني مايعني مايعني
+
+61
+00:04:47,720 --> 00:04:47,760
+مايعني مايعني مايعني مايعني مايعني مايعني مايعني
+
+62
+00:04:47,760 --> 00:04:53,390
+مايعني مايعنيبالنسبة لأ الشحنة اللي بتكون هنا هي
+
+63
+00:04:53,390 --> 00:04:57,650
+مجموع ال formal charges واضح يعني لما واحدة بتعمل
+
+64
+00:04:57,650 --> 00:05:01,270
+حسابة تقول احسب جداش فيه charge على الكاربون جداش
+
+65
+00:05:01,270 --> 00:05:04,730
+فيه على الأكسجين عملت جمعة ايه سوى شحنة لها جزء
+
+66
+00:05:04,730 --> 00:05:10,630
+متعادل هصير مجموعهمجزء مشحون مجموعهم الشحناء اللي
+
+67
+00:05:10,630 --> 00:05:15,270
+موجودة هنا الان كيف احنا بنحسب ال formality charge
+
+68
+00:05:15,270 --> 00:05:19,430
+ال formality charge بتساوي ال valence electrons
+
+69
+00:05:19,430 --> 00:05:23,160
+اللي هي الإلكترونات في المداري الأخيرممكن البعض
+
+70
+00:05:23,160 --> 00:05:27,460
+يقول طب و أنا بدأ أعمل توزيع إلكتروني عشان أعرف ال
+
+71
+00:05:27,460 --> 00:05:32,260
+Valence Electrons؟ بنقول لأ، بده يتذكر الإنسان إن
+
+72
+00:05:32,260 --> 00:05:36,960
+ال Valence Electrons بيساوي رقم المجموعة في الجدول
+
+73
+00:05:36,960 --> 00:05:42,120
+الدوري طبعا هيجي تساؤل تاني عندكم، هل يا ترى بدنا
+
+74
+00:05:42,120 --> 00:05:49,040
+نكون حافظين الجدول الدوري؟الجواب في منطقة معينة اه
+
+75
+00:05:49,040 --> 00:05:52,960
+بدنا نكون حافظين الجدول الدوري يعني يوم اتي احكي
+
+76
+00:05:52,960 --> 00:05:57,220
+مثلا على الهيدروجين بدنا نكون عارفين تماما ان
+
+77
+00:05:57,220 --> 00:06:02,380
+الهيدروجين في المجموعة الاولى يوم بحكي عن الذرات
+
+78
+00:06:02,380 --> 00:06:05,480
+الأساسية عندى في ال organ الchemistry اللى هى
+
+79
+00:06:05,480 --> 00:06:09,120
+تحديدا ال carbon بعد ال nitrogen ال oxygen ال
+
+80
+00:06:09,120 --> 00:06:14,110
+floorو تحت ال floor بيجوني ال halogens ال chlorine
+
+81
+00:06:14,110 --> 00:06:18,710
+البروم ال يولي تحت ال oxygen ال sulfur تقريبا هذه
+
+82
+00:06:18,710 --> 00:06:22,470
+هي ذرات الكيميا العضوية اللى بتمر عليها اكثر ما
+
+83
+00:06:22,470 --> 00:06:27,250
+يمكن الان بدي اكون عارف تماما ان ال carbon في
+
+84
+00:06:27,250 --> 00:06:29,930
+المجموعة الرابعة ال nitrogen في الخامسة ال oxygen
+
+85
+00:06:29,930 --> 00:06:33,790
+في السادسة ال floor في السابعةإذا الـ valence
+
+86
+00:06:33,790 --> 00:06:36,890
+electrons أو الإلكترونات الخارجية لأي ذرّة من
+
+87
+00:06:36,890 --> 00:06:42,370
+هدول، كم لمتهم؟ للأكسجون والسلفر، للنيتروجين،
+
+88
+00:06:42,370 --> 00:06:47,910
+خمسة، للكاربون، أربعة، واضح؟ هذا شيء يجب أن نعرفه
+
+89
+00:06:48,730 --> 00:06:51,570
+الأن الـ Formal Charge بتساوي الـ Valence
+
+90
+00:06:51,570 --> 00:06:56,690
+Electrons ناقص عدد الروابط اللي على الذرة المعينة
+
+91
+00:06:56,690 --> 00:07:01,990
+اللي أنا بحسبها ناقص أي عدد من الإلكترونات و غالبا
+
+92
+00:07:01,990 --> 00:07:05,790
+أزواج الإلكترونات موجودة على هذه الذرة مثلا لو
+
+93
+00:07:05,790 --> 00:07:10,290
+نظرت أنا لإيون الكربونات لو نظرت لإيون الكربونات
+
+94
+00:07:10,290 --> 00:07:13,850
+اعملتله Lewis Structure هذا الـ Lewis Structure
+
+95
+00:07:13,850 --> 00:07:19,490
+تبعه تماماالان لو جيت باسأل طب هذه ال carbon كام
+
+96
+00:07:19,490 --> 00:07:23,830
+شحنة عليها formal charge هقول ال valence electrons
+
+97
+00:07:23,830 --> 00:07:30,250
+بتاعونها أربعة ناقص الروابط اللي عاملهم أربعة ناقص
+
+98
+00:07:30,250 --> 00:07:35,230
+هل يظهر عليها أزواج إلكترونات لأ إذا ال formal
+
+99
+00:07:35,230 --> 00:07:41,850
+charge على هذه ال carbon سفر طب لو جيت لل oxygen
+
+100
+00:07:41,850 --> 00:07:49,310
+اللي جنبهاهأقول ال oxygen ستة ناقص كام رابطة ناقص
+
+101
+00:07:49,310 --> 00:07:55,370
+رابطتين ناقص كام إلكترون أربعة ستة ناقص اتنين ناقص
+
+102
+00:07:55,370 --> 00:08:01,440
+أربعةأيضا صفر طب لو جيت على ال oxygen هذي و هذي
+
+103
+00:08:01,440 --> 00:08:06,180
+زيها ست إلكترونات ال feelings electrons ناقص كام
+
+104
+00:08:06,180 --> 00:08:11,820
+رابطة واحد ناقص كام إلكترون نين أربعة ستة إذا هذي
+
+105
+00:08:11,820 --> 00:08:17,320
+minus one و هذي زيها minus one الآن هذي أربع ذرات
+
+106
+00:08:17,320 --> 00:08:21,270
+مكونين لهذا الايون كل واحدة لها شحنةالى formal
+
+107
+00:08:21,270 --> 00:08:26,470
+charge طب مجموع هذه الشحنات جديش minus اتنين احنا
+
+108
+00:08:26,470 --> 00:08:32,330
+طبعا عارفين ان ال CO3 two minus ايش فادتني ال
+
+109
+00:08:32,330 --> 00:08:36,430
+formal charge ايش فادتني ال formal charge فادتني
+
+110
+00:08:36,430 --> 00:08:42,390
+ان انا بقول هذا الايون المكون من اربع ذرات عليه
+
+111
+00:08:42,390 --> 00:08:46,950
+شحنتين سالبات طب لو سألنا السؤال where بالظبط
+
+112
+00:08:46,950 --> 00:08:52,560
+الشحنتين السالبات هدول اربع ذراتالـ CO3 أربع ذرات
+
+113
+00:08:53,330 --> 00:08:57,110
+شحنته العامة minus minus طب وين موجودين هدول
+
+114
+00:08:57,110 --> 00:09:01,850
+الشحنتين السالبات الان هذا الحساب اعطاني فكرة
+
+115
+00:09:01,850 --> 00:09:07,890
+موجودين على هذا ال oxygen و على هذا ال oxygen لو
+
+116
+00:09:07,890 --> 00:09:12,350
+الان انا بدي اجي اعمل تفاعل معين اجيب شيء موجب
+
+117
+00:09:12,350 --> 00:09:17,130
+يتفاعل وين بده يجي الموجب؟ تحديدا على هذه و هذه
+
+118
+00:09:17,130 --> 00:09:24,440
+يعني مثلا لو هذا ال ion بدي اجي افعله مع H plusوين
+
+119
+00:09:24,440 --> 00:09:28,120
+بدو ييجي ال H plus؟ الموجب بدو ييجي على السالب
+
+120
+00:09:28,120 --> 00:09:32,320
+عشان هيك الشكل اللي هيطلع عندك C ضب البند O، O
+
+121
+00:09:32,320 --> 00:09:37,940
+هتتفعل مع H، O هتتفعل مع H، هى الموجب اتفعل مع
+
+122
+00:09:37,940 --> 00:09:44,520
+السالب صار عند المركب H2CO3 اللى هو ال carbonic
+
+123
+00:09:44,520 --> 00:09:50,230
+acidواضح؟ اللي أنا عارفه، فهذه من فوائد ال formal
+
+124
+00:09:50,230 --> 00:09:56,090
+it charges إنها بتحدد لبالظبط لو في شحنات وين
+
+125
+00:09:56,090 --> 00:10:00,190
+موجودين، لو في شحنات بمجمل ال ion وين موجودين،
+
+126
+00:10:00,190 --> 00:10:07,570
+كذلكلو كان عندى الجزء متعادل يعنى بين شحنته سفر
+
+127
+00:10:07,570 --> 00:10:13,250
+ايضا كل ذرة فيه بتحمل شحنة يعنى مثلا لو أخدنا هذا
+
+128
+00:10:13,250 --> 00:10:20,430
+ال carbon tetrachloride CClClClCl
+
+129
+00:10:20,430 --> 00:10:27,410
+و توزيعه الإلكترونى بهذا الشكل و قلنا بدنا نجرب
+
+130
+00:10:27,410 --> 00:10:31,720
+نحسبله formal chargeالحالي يجي نقول ال carbon
+
+131
+00:10:31,720 --> 00:10:38,280
+أربعة ناقص أربع روابط مافيش أزواج إلكترونات إذا
+
+132
+00:10:38,280 --> 00:10:43,040
+هذه zero لو جيت ال chlorine كلهم يبينوا زي بعض ال
+
+133
+00:10:43,040 --> 00:10:51,520
+chlorine سبعة ناقص رابطة ناقص ستة
+
+134
+00:10:55,460 --> 00:11:04,560
+و المجموع تبعه صفر واضح؟ و المجموع تبعه صفر مرات
+
+135
+00:11:04,560 --> 00:11:09,540
+بيكون في عندكم على بعض الذرات موجب و سالب و
+
+136
+00:11:09,540 --> 00:11:12,760
+المجموع أيضا صفر يعني ممكن تلاقوا في حالة تانية
+
+137
+00:11:12,760 --> 00:11:20,610
+plus one و minus one و المجموع صفر الآنطالما عندي
+
+138
+00:11:20,610 --> 00:11:26,150
+أزواج إلكترونات و روابط بإمكاني أنا أحرك أزواج
+
+139
+00:11:26,150 --> 00:11:31,110
+الإلكترونات من مكانها و أعمل تغيير في الروابط يعني
+
+140
+00:11:31,110 --> 00:11:35,350
+مثلا لو إحنا إجينا و قولنا بدنا نحرك هذا زوج
+
+141
+00:11:35,350 --> 00:11:40,130
+الإلكترونات نجيبه على هذا الموقع بيصير؟ بنقدر
+
+142
+00:11:40,130 --> 00:11:43,050
+نجيبه لكن يا تورة هل معقول اللي كاربون تصير خمس
+
+143
+00:11:43,050 --> 00:11:47,370
+روابط؟ لأ وجدت هأ بدأت طار أحرك رابطة ما هي
+
+144
+00:11:47,370 --> 00:11:53,040
+الرابطة إلكترونيةوهذا إلكترونين وقت بدأ الطر أحرك
+
+145
+00:11:53,040 --> 00:11:58,240
+هذه الرابطة تيجي على ال oxygen هنا واضح؟ صار عندي
+
+146
+00:11:58,240 --> 00:12:02,500
+شكل جديد إيش الإختلاف بين الشكل الأول والشكل
+
+147
+00:12:02,500 --> 00:12:09,180
+التاني؟ تطلع عليهمفقط في مواقع الإلكترونات بمعنى
+
+148
+00:12:09,180 --> 00:12:13,380
+الذرات Carbon Oxygen Oxygen Oxygen Carbon Oxygen
+
+149
+00:12:13,380 --> 00:12:18,680
+Oxygen Oxygen لكن الإلكترونات تغير شكلها واضح
+
+150
+00:12:18,680 --> 00:12:22,940
+بإمكان أعمل كمان تغيير مثلا ممكن أجيب هذا زوج
+
+151
+00:12:22,940 --> 00:12:27,200
+الإلكترونات هان أخليها دي جهان صار عندي شكل جديد
+
+152
+00:12:27,200 --> 00:12:31,640
+الآن الشكل الأول التاني التالت شو بسميهم أنا
+
+153
+00:12:32,080 --> 00:12:36,300
+Resonance structures يعني أشكال رانيل بنقولها
+
+154
+00:12:36,300 --> 00:12:41,460
+بالعربي فال resonance كفكرة arises whenever we can
+
+155
+00:12:41,460 --> 00:12:44,320
+write two or more structures for a molecule with
+
+156
+00:12:44,320 --> 00:12:48,540
+different arrangement of electrons but identical
+
+157
+00:12:48,540 --> 00:12:52,020
+arrangement of atoms لاحظوا هذا بيجيبلنا مفهوم
+
+158
+00:12:52,020 --> 00:12:56,940
+كتير مهم عندنا أنه أنا ممكن أغير في الإلكترونات
+
+159
+00:12:56,940 --> 00:13:01,960
+بدون ما أغير الذراتهذه العملية اللى بغير فيها فقط
+
+160
+00:13:01,960 --> 00:13:09,300
+إلكترونات arrangement of إلكترون بدون ما أقترب من
+
+161
+00:13:09,300 --> 00:13:14,840
+الذرات شو بسميها أنا resonance structures الان ال
+
+162
+00:13:14,840 --> 00:13:18,840
+resonance structures بين شكل و التاني بنستعمل لهم
+
+163
+00:13:18,840 --> 00:13:23,500
+سهم زى ما انتوا شايفينهDouble Headed Arrow عشان
+
+164
+00:13:23,500 --> 00:13:29,800
+نقول ان هذا وهذا فقط يختلفوا في طريقة رسمنا
+
+165
+00:13:29,800 --> 00:13:35,200
+للإلكترونات بين الذرات ولكننا لم نغير في ايش في
+
+166
+00:13:35,200 --> 00:13:39,580
+مواقع الذرات يمكن مر عليكم هذا الكلام لما أخدت
+
+167
+00:13:39,580 --> 00:13:44,260
+أشكال البنزين متذكرين لما كنتوا تاخدوا البنزين
+
+168
+00:13:46,670 --> 00:13:51,890
+بهذا الشكل و كنتوا تقولوا ممكن يكون غيرنا الأشكال
+
+169
+00:13:51,890 --> 00:13:57,350
+بهذا الشكل الآن هذولا الشكلين تبعون البنزين عبارة
+
+170
+00:13:57,350 --> 00:14:01,530
+عن ايش resonance structures مرة أنا كان عندي رابطة
+
+171
+00:14:01,530 --> 00:14:05,130
+يعني إلكترونين مرة أنا رابطة زوجية يعني كأنها أربع
+
+172
+00:14:05,130 --> 00:14:09,090
+إلكترونات فأنا قاعد فقط بغير إلكترونات لكن هل
+
+173
+00:14:09,090 --> 00:14:14,070
+تغيرت الذراتولذلك هدول الشكلين بنستعملله ماذا
+
+174
+00:14:14,070 --> 00:14:21,210
+السهم اللي بعبر عن إيش ال resonance هذا الكلام
+
+175
+00:14:21,210 -->
+
+223
+00:18:19,100 --> 00:18:27,000
+الإلكترونات؟ إيش عملنا؟ high curved أقول لما قلنا
+
+224
+00:18:27,000 --> 00:18:30,300
+بدنا نحرك الرابط، طب ما هي الرابط أيضا إلكترونين،
+
+225
+00:18:30,300 --> 00:18:35,330
+نجيب إلكترونات هنا، كيف استعملنا؟Curved Arrow فالـ
+
+226
+00:18:35,330 --> 00:18:41,170
+Curved Arrow is used to indicate the movement of a
+
+227
+00:18:41,170 --> 00:18:45,290
+pair of electrons، two electrons، واضح؟
+
+228
+00:18:50,240 --> 00:18:57,060
+أحيانا بنحرك بس إلكترون واحد مش إلكترونين وجدها
+
+229
+00:18:57,060 --> 00:19:03,620
+بنستعمل الـ curved arrow هذا لكن برأس واحد يعني زي
+
+230
+00:19:03,620 --> 00:19:09,620
+هيك، هيك صار واضح لكم؟ الآن هذا بيشبه إيش؟ السنارة
+
+231
+00:19:09,620 --> 00:19:14,610
+تبعت الصياد صيدين السمك اللي بيصيدوا السمك زي هيك
+
+232
+00:19:14,610 --> 00:19:19,810
+شكل السنارة ولذلك هذا السهم بنسميه احنا ايش fish
+
+233
+00:19:19,810 --> 00:19:24,790
+hook يعني سهم السنارة fish hook arrow ف الـ fish
+
+234
+00:19:24,790 --> 00:19:31,290
+hook arrow is used to indicate the movement of one
+
+235
+00:19:31,290 --> 00:19:36,520
+electron لاحظوا اللي كان two electrons كان له رأسين
+
+236
+00:19:36,520 --> 00:19:41,500
+اللي كان one electron له رأس واحد مثلا لو افترضنا
+
+237
+00:19:41,500 --> 00:19:46,780
+هذا جزء فيه رابطة، الرابطة كام electron؟ اتنين،
+
+238
+00:19:46,780 --> 00:19:51,120
+هاي في عندي electron ين، الان انا بدي اكسر الرابطة
+
+239
+00:19:51,120 --> 00:19:56,240
+كسر متجانس اكسرها من النص، electron هان ييجي و
+
+240
+00:19:56,240 --> 00:20:00,640
+electron هان ييجي اي سهم بدي استعمل؟ الـ fish hook
+
+241
+00:20:00,640 --> 00:20:06,660
+لو عملت زي هيك هيأجى هذا الإلكترون على CH3 صار CH3
+
+242
+00:20:06,660 --> 00:20:14,860
+تحمل إلكترون واحد وهذا نفس الشيء واضح؟ اتخيلوا لو
+
+243
+00:20:14,860 --> 00:20:21,320
+مثلا في هذا الجزء نفسه كنت بدي أخلي الإلكترونين
+
+244
+00:20:21,320 --> 00:20:25,740
+يروحوا مع CH3 والتانية بدون إلكترونات أي سهم بدي
+
+245
+00:20:25,740 --> 00:20:32,470
+أستعمل السهم السابق وجدت لو بستعمل هذا السهم الـ
+
+246
+00:20:32,470 --> 00:20:39,970
+Curved Arrow هينتج عندي من هنا CH3 تحمل زوج
+
+247
+00:20:39,970 --> 00:20:46,930
+الإلكترونات كله والتانية CH3
+
+248
+00:20:46,930 --> 00:20:51,970
+لا تحمل شيئا طبعا لو حسبته الـ Formal Charge لهدول
+
+249
+00:20:51,970 --> 00:20:58,470
+القطعتين اللي طلعوا اتذكروا الكربون أربعة ناقص تلت
+
+250
+00:20:58,470 --> 00:21:05,890
+روابط ناقص إلكترونيل شو هتكون minus ال carbon أربع
+
+251
+00:21:05,890 --> 00:21:14,590
+ناقص تلت روابط بس plus كأنه قسمت الجزء إلى قطعتين
+
+252
+00:21:14,590 --> 00:21:19,330
+إلى أيون سالب و أيون موجب لكن أنا قسمت إلى قطعتين
+
+253
+00:21:19,330 --> 00:21:24,610
+متعادلات فكل هذا الكلام إيش اللي بساعدني عليه أن
+
+254
+00:21:24,610 --> 00:21:30,460
+أكون فاهم معنى الأسهم اللي أنا بستعملها و هذا
+
+255
+00:21:30,460 --> 00:21:34,680
+الكلام ما لم يتضرر بالطالب انه يحط السهم و يرسمه
+
+256
+00:21:34,680 --> 00:21:39,720
+بإيده و يكتب معناه بإيده بعد فترة هتلاقوه ايش نسيه
+
+257
+00:21:39,720 --> 00:21:43,480
+احنا دائما و ابدا مافيش امتحان الا بنسألكوا فيه عن
+
+258
+00:21:43,480 --> 00:21:49,180
+ايش الأسهم لابد الا يجيكم سؤال ايش معنى هذا السهم
+
+259
+00:21:49,180 --> 00:21:55,520
+لإيش يستعمل هذا السهم أخر
+
+260
+00:21:55,520 --> 00:22:02,160
+شغلة في هذا الفصل الكيميا العضوية قبل قليل خفتوا و
+
+261
+00:22:02,160 --> 00:22:08,460
+الآن نقطع الخوف و ننزل الخوف لماذا خفنا من الكيميا
+
+262
+00:22:08,460 --> 00:22:15,240
+العضوية لأن الكيميا العضوية عشرين مليون مركب أو
+
+263
+00:22:15,240 --> 00:22:19,560
+أكتر معروفين هدولة غير اللي مش معروفين طيب لما
+
+264
+00:22:19,560 --> 00:22:24,420
+الإنسان بتعامل مع عدد كبير من الأشياء و بده يقدر
+
+265
+00:22:24,420 --> 00:22:30,080
+يسيطر عليه كيف بيسيطر عليه؟ من خلال أنه يصنفوا إلى
+
+266
+00:22:30,080 --> 00:22:35,090
+مجموعات معينة يعمل classification يعني حتى البشرية
+
+267
+00:22:35,090 --> 00:22:39,030
+الناس البشر اللي عايشين اليوم احنا بنعمللهم تصنفات
+
+268
+00:22:39,030 --> 00:22:43,210
+بتسهل علينا نتعامل معهم يعني بنقول والله ها السبعة
+
+269
+00:22:43,210 --> 00:22:46,810
+أو تمانية مليار بني آدم اللي موجودين ممكن نصنفهم
+
+270
+00:22:46,810 --> 00:22:54,270
+من زاوية انه ذكور واناث ممكن نصنفهم من زاوية انه
+
+271
+00:22:54,270 --> 00:23:01,170
+في منهم أغنياء ومتوسطي الحال وفقراء واضح؟ ممكن
+
+272
+00:23:01,170 --> 00:23:04,170
+نصورهم من زاوية ان في منهم اجسار و في منهم ..
+
+273
+00:23:04,760 --> 00:23:09,020
+إطوال، ممكن نصنفهم من زاوية الدين، نقول والله فيها
+
+274
+00:23:09,020 --> 00:23:12,680
+الجد نصارى، فيها الجد مسلمين، فيها الجد .. واضحة
+
+275
+00:23:12,680 --> 00:23:17,020
+الفكرة؟ كذلك الحالة لما أنا بتكلم عن عشرين مليون
+
+276
+00:23:17,020 --> 00:23:21,560
+مركب وبدأ أدرس organ الـ chemistry و أفهم شيء عن كل
+
+277
+00:23:21,560 --> 00:23:26,060
+شيء فيهم، لابد أن أعمل تصنيف التصنيف اللي احنا
+
+278
+00:23:26,060 --> 00:23:31,680
+بنعمله .. فيه تصنيفات كتيرة يعني ممكن مراكبات
+
+279
+00:23:31,680 --> 00:23:36,420
+أصنفها حسب مصدرها، يعني منتجات طبيعية ولا منتجات
+
+280
+00:23:36,420 --> 00:23:41,680
+صناعية، ممكن حسب ريحتها، ممكن حسب طعمها، ممكن حسب
+
+281
+00:23:41,680 --> 00:23:47,040
+كيمياء حيوية، ممكن .. تصنيفات كتيرة، لكن جوا
+
+282
+00:23:47,040 --> 00:23:50,720
+الكيميا العضوية العادية عشان أسيطر على معظم
+
+283
+00:23:50,720 --> 00:23:54,980
+الأشياء الأساسية بنصنف حسب شيء بنسميه المجموعة
+
+284
+00:23:54,980 --> 00:24:01,830
+الوظيفية شيء مميز في داخل مجموعة من المركبات بنسميه
+
+285
+00:24:01,830 --> 00:24:06,370
+functional group فالـ classification of organic
+
+286
+00:24:06,370 --> 00:24:09,450
+compounds بيكون according to functional groups
+
+287
+00:24:09,450 --> 00:24:15,250
+مثلا المركبات اللي كلها روابط أحادية بسميها
+
+288
+00:24:15,250 --> 00:24:19,690
+alkanes لو صار في عندى بين الـ carbon و الـ carbon
+
+289
+00:24:19,690 --> 00:24:25,190
+رابطة ثنائية بقول هذه عائلة الـ alkenes لو صار
+
+290
+00:24:25,190 --> 00:24:31,070
+رابطة ثلاثية عائلة الـ alkynes لو صار حلقة بروابط
+
+291
+00:24:31,070 --> 00:24:35,570
+زوجية بقول هدولة الـ aromatic compounds لو صار
+
+292
+00:24:35,570 --> 00:24:41,400
+مركبات في مجموعة الـ OH الكحولات وبيشتغ منها
+
+293
+00:24:41,400 --> 00:24:47,180
+الثيولات زي الكحولات بس بدل OH S H لو كان اكسوجين
+
+294
+00:24:47,180 --> 00:24:52,790
+بالكربونتين بقول الـ Ethers سلفر بين كربونتين ثيو
+
+295
+00:24:52,790 --> 00:24:57,570
+إيثرز الـ C double bond O في منها مجموعات كتيرة
+
+296
+00:24:57,570 --> 00:25:02,250
+الـ C double bond O اللي جنبها H و R بقول عنها
+
+297
+00:25:02,250 --> 00:25:06,290
+الديهيد لو كانت الـ C double bond O بين كربونتين
+
+298
+00:25:06,290 --> 00:25:12,080
+كيتون بين كربون و OH acid بين carbon و ore استر
+
+299
+00:25:12,080 --> 00:25:17,980
+وهكذا الان كل هذه المجموعات هنتعرف عليها في الجزء
+
+300
+00:25:17,980 --> 00:25:20,600
+الاول من هذا المساق اللي هو جزء الـ organic
+
+301
+00:25:20,600 --> 00:25:25,280
+chemistry يعني كل ما تراونه امامكم على السبورة
+
+302
+00:25:25,280 --> 00:25:33,880
+هناخده بشكل مفصل و مختصر طبعا واضح ان اي انسان بده
+
+303
+00:25:33,880 --> 00:25:40,560
+يبتدئ هيبتدئ بأي جزء الالكينز اللي هي المركبات اللي
+
+304
+00:25:40,560 --> 00:25:46,460
+بتحتوي على روابط أحادية هذا بيكون بداية الفصل
+
+305
+00:25:46,460 --> 00:25:56,560
+التاني اللي احنا هنبدأ فيه مباشرة واضح؟
+
+306
+00:25:58,420 --> 00:26:03,420
+الفصل الثاني اللى هنبدأ فيه بنسميه الـ canes and
+
+307
+00:26:03,420 --> 00:26:09,740
+cycloalcanes يعني يمكن أن تكون هذه المركبات مركبات
+
+308
+00:26:09,740 --> 00:26:17,600
+متسلسلة و ممكن تكون سكرة على شكل حلقة لكن القاسم
+
+309
+00:26:17,600 --> 00:26:22,180
+المشترك في الـ canes و الـ cycloalcanes و الحقيقة
+
+310
+00:26:22,180 --> 00:26:28,070
+اللى بيعبر عنه هو هذا الحرف الـ a اللى هنا هو
+
+311
+00:26:28,070 --> 00:26:34,050
+الروابط الأحادية لو كانت الـ الـ Keynes الـ A صارت E
+
+312
+00:26:34,050 --> 00:26:38,130
+بدا أبدأ أحكي عن روابط ثنائية و لو بدا أحكي
+
+313
+00:26:38,130 --> 00:26:41,790
+Cycloalkynes هيصير فيها روابط ثنائية لو كانت فيها
+
+314
+00:26:41,790 --> 00:26:47,530
+Y الروابط الثلاثية فالـ Keynes و الـ Cycloalkynes
+
+315
+00:26:47,530 --> 00:26:52,310
+فيهم شئ مشترك أن كل الروابط اللي موجودة في الجزء
+
+316
+00:26:52,310 --> 00:26:54,830
+هي روابط أحادية
+
+317
+00:26:57,320 --> 00:27:04,960
+الان هذا الكلام بيجيبنا لتصنيف للاشياء الأساسية في
+
+318
+00:27:04,960 --> 00:27:07,260
+الـ organ الـ chemistry اللي أنا بسميها الـ
+
+319
+00:27:07,260 --> 00:27:10,900
+hydrocarbons اللي بقصده بالـ hydrocarbons أبسط
+
+320
+00:27:10,900 --> 00:27:16,440
+المراكبات العضوية اللي فقط بتحتوي hydrogen و
+
+321
+00:27:16,440 --> 00:27:20,000
+carbon هاي معناه hydrocarbon hydrocarbons they
+
+322
+00:27:20,000 --> 00:27:23,980
+contain only carbon and hydrogen الان هدول
+
+323
+00:27:23,980 --> 00:27:30,000
+المراكبات بصنفهم لصنفين اما بيقول saturated او
+
+324
+00:27:30,000 --> 00:27:36,000
+unsaturated، saturated مشبع معناه مشبع جميع روابط
+
+325
+00:27:36,000 --> 00:27:41,360
+أحدية unsaturated في multiple bonds، يعني يا في
+
+326
+00:27:41,360 --> 00:27:46,710
+double bond يا في الـ triple bonds الان المراكبات
+
+327
+00:27:46,710 --> 00:27:54,370
+اللى جميع روابطها أحدية هى الـ الكينز والساكلو
+
+328
+00:27:54,370 --> 00:27:59,150
+الكينز هدول saturated اللى فيهم روابط ثنائية او
+
+329
+00:27:59,150 --> 00:28:02,830
+ثلاثية او اكتر الـ الكينز اللى فيهم الـ double bonds
+
+330
+00:28:02,830 --> 00:28:05,990
+الـ الكينز اللى فيهم الـ triple bonds و الـ aromatic
+
+331
+00:28:05,990 --> 00:28:09,050
+compounds اللى هم المراكبات اللى بيشبهوا البنزين
+
+332
+00:28:09,050 --> 00:28:16,690
+فيهم حلقة زاد روابط زوجية فيهم حلقة زاد روابط زوجية
+
+333
+00:28:16,690 --> 00:28:22,630
+double bonds طبعا لما نيجي نتكلم عن الـ alkanes
+
+334
+00:28:22,630 --> 00:28:28,650
+بنبدأ بمركب فيه carbon واحدة بعد هيك two carbons
+
+335
+00:28:28,650 --> 00:28:33,910
+three carbons four carbons و هكذا و بنكمل دائما و
+
+336
+00:28:33,910 --> 00:28:41,070
+أبدا لإيش لأقصى عدد بتحتمل ذرة الـ carbon في هذه
+
+337
+00:28:41,070 --> 00:28:46,870
+الحالة هنكمل بهيدروجينات هنكمل بهيدروجينات يعني
+
+338
+00:28:46,870 --> 00:28:52,310
+مثلا لو كنا بدنا ناخد الجزء الأبسط اللي هو جزء
+
+339
+00:28:52,310 --> 00:28:58,630
+الميثين هتلاحظوا انه فيه
+
+340
+00:28:58,630 --> 00:29:07,110
+اربع روابط وكل رابطة فيها هيدروجين اربع روابط وهي
+
+341
+00:29:07,110 --> 00:29:12,750
+مثلا الهيدروجين باللون نوعا ما الـ orange هذا اللي
+
+342
+00:29:12,750 --> 00:29:19,310
+هو جزيء الـ Methane الصيغة تبعته إيش بتكون CH4
+
+343
+00:29:19,310 --> 00:29:24,170
+بنسميه Methane الآن من Carbon واحدة بقدر أعمل غير
+
+344
+00:29:24,170 --> 00:29:29,750
+هذا الجزيء؟ لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ،
+
+345
+00:29:29,750 --> 00:29:30,490
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ،
+
+346
+00:29:30,490 --> 00:29:31,510
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ،
+
+347
+00:29:31,510 --> 00:29:33,410
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، ل
+
+348
+00:29:35,840 --> 00:29:40,560
+هيصير عنده جزء الـ E2 طب ذرتين الكربون هما اللي
+
+349
+00:29:40,560 --> 00:29:47,120
+هيشبكوا بعض في احتمالات كتيرة ممكن اعملها ايش هما
+
+350
+00:29:47,120 --> 00:29:54,040
+خليني استعمل روابط اقصر و اوضح اللون الأصفر هذا
+
+351
+00:29:54,040 --> 00:30:02,640
+هاي الجزء التاني و ربما تلاحظوا انه الكلام بياخدله
+
+352
+00:30:02,640 --> 00:30:05,520
+دقيقة واجت لكن لا بأس بذلك
+
+353
+00:30:09,830 --> 00:30:16,010
+هي هدول بلاش نحط الـ hydrogens يفهموا ضمنها CH3 CH3
+
+354
+00:30:16,010 --> 00:30:22,270
+دارتين كربون عندي إمكانية أعمل غير هذا الشكل لأ إذا
+
+355
+00:30:22,270 --> 00:30:27,550
+كام isomer عندى من الـ E2 ايضا isomer واحد مش قادر
+
+356
+00:30:27,550 --> 00:30:32,890
+اعمل غيره طيب الان ناس جابوا ذرة كربون جديدة ها
+
+357
+00:30:32,890 --> 00:30:36,630
+يوم مسكينها بدهم يضيفوها على هذا الجزء اكيد بدنا
+
+358
+00:30:36,630 --> 00:30:41,370
+نشيلها هيدروجين و نحط كربون يا بنحطها هنا او
+
+359
+00:30:41,370 --> 00:30:45,390
+بالجهات التانية نفس الاشي كام احتمال عندى عشان احط
+
+360
+00:30:45,390 --> 00:30:49,050
+ذرة الكربون الجديدة أبدا
+
+361
+00:30:50,460 --> 00:30:58,460
+فارجوني احتمال تاني و بنكمل هذه الذرة .. بنكمل هذه
+
+362
+00:30:58,460 --> 00:31:04,540
+الذرة هاي الجزء اللي من تلت كربونات ممكن تلت
+
+363
+00:31:04,540 --> 00:31:08,990
+كربونات احطه من غير هذا الاحتمال؟ فكروا معي، لا
+
+364
+00:31:08,990 --> 00:31:13,930
+يمكن، إذا هذا الجزء اللي من تلات كربونات البروبين
+
+365
+00:31:13,930 --> 00:31:22,890
+اللي صيغته CH3 CH2 CH3 لا يوجد منه إلا شكل واحد،
+
+366
+00:31:22,890 --> 00:31:28,930
+متشكل واحد فقط لا غيرو واضح؟ لحظة أنا بحط عدد ذرات
+
+367
+00:31:28,930 --> 00:31:34,110
+الكربون والـ number of structural isomers فالميثان
+
+368
+00:31:34,110 --> 00:31:39,250
+والإيثان والبروبين لا يوجد منهم غير متشكل واحد
+
+369
+00:31:39,250 --> 00:31:43,490
+خلّيني أجيب في نص دقيقة الآن لو جينا واطلعنا على
+
+370
+00:31:43,490 --> 00:31:50,860
+الصيغ وقلنا إن الميثان CH4 والإيثان CH6لبروبين
+
+371
+00:31:50,860 --> 00:31:56,900
+C3H8 هذا الكلام هيرجعنا خطوة للوراء ان صيغة العامة
+
+372
+00:31:56,900 --> 00:32:05,180
+لالكينز CN H2N Plus 2 يعني لما تكون C1 تكون H 2X1
+
+373
+00:32:05,180 --> 00:32:12,280
+اتنين زي اتنين اربعة لو كانت الـ C3 اتنين في اتنين
+
+374
+00:32:14,820 --> 00:32:18,920
+إتنين في تلاتة ستة زاد اتنين تمانية شايفين
+
+375
+00:32:18,920 --> 00:32:23,760
+التمانية ولا لأ هايهم تلاتة و اتنين و تلاتة و هكذا
+
+376
+00:32:23,760 --> 00:32:28,820
+الآن لو بدنا نيجي على الـ C4 المركب اللي من أربع
+
+377
+00:32:28,820 --> 00:32:35,480
+ذرات كربون طالما قلنا C4 إذا كم هيدروجينة هيكون
+
+378
+00:32:35,480 --> 00:32:40,380
+فيه حسب القاعدة أربعة في اتنين تمانية تمانية زاد
+
+379
+00:32:40,380 --> 00:32:52,020
+اتنين عشرة طيب خلينان حمل معنى ذرة كربون رباعية هاي
+
+380
+00:32:52,020 --> 00:32:58,160
+ذرة كربون و بدنا نضيف على هذا الجزء انتبهوا معي
+
+381
+00:32:58,160 --> 00:33:02,180
+الان بإمكاني اضيفها على الطرف يعني اعمل سلسلة
+
+382
+00:33:02,180 --> 00:33:07,140
+طويلة لو ضيفتها على هذه الـ carbon صار مركب جديد
+
+383
+00:33:07,140 --> 00:33:11,980
+اربع ذرات متسلسلة لو ضيفتها هنا نفس الاشي اربع
+
+384
+00:33:11,980 --> 00:33:17,100
+ذرات متسلسلة لكن لو ضيفتها هنا هيصير عندى مركب
+
+385
+00:33:17,100 --> 00:33:24,980
+متشعب branched molecule اذا لما بصل للاربعة بتبدأ
+
+386
+00:33:24,980 --> 00:33:32,080
+عند ظاهرة التشكل هنا بإمكانى ان احصل على مركبين
+
+387
+00:33:32,080 --> 00:33:39,240
+مركب بهذا الشكل مركب بهذا الشكل ونكمل هنا بالتأكيد
+
+388
+00:33:39,240 --> 00:33:42,840
+الهيدروجينات التلاتة
+
+389
+00:33:48,630 --> 00:33:54,350
+شايفينوا كيف؟ حيصير صيغته CH3 CH2 CH2 CH3 هذا
+
+390
+00:33:54,350 --> 00:33:57,790
+بتسميه بيوتين عادي، الآن هذا موجود عندنا بعد هيك
+
+391
+00:33:57,790 --> 00:34:03,090
+في الجدول لاحظوا بكربون واحدة قولت اندي م
+
+445
+00:39:05,750 --> 00:39:11,640
+بينتين طب لو الآن قلت لو واحدة ايزو هكسين بدي أخلّي
+
+446
+00:39:11,640 --> 00:39:19,900
+هذه تنتين أزيد واحدة ايزو هبتين هذا الجزء بيقول لي
+
+447
+00:39:19,900 --> 00:39:25,260
+كلمة ايزو و العدد الكلي بيحدد اللي موجود عنده الآن
+
+448
+00:39:25,260 --> 00:39:32,040
+هاي هذا الجزء موجود هنا هاي ايزو واحد اتنين تلاتة
+
+449
+00:39:32,040 --> 00:39:37,260
+أكملت أربعة خمسة اذا إيش صار عندك ايزو بنتين و هذا
+
+450
+00:39:37,260 --> 00:39:43,140
+نفسه ايزو بنتين مُركّبات البنتين هي البنتين والأيزو
+
+451
+00:39:43,140 --> 00:39:48,180
+بنتين وهذا المُركّب الأخير كاربون متفرع منها أربع
+
+452
+00:39:48,180 --> 00:39:51,660
+مجموعات مثل اسم الـ New بنتين
+
+453
+00:39:57,160 --> 00:40:00,800
+الـ isomers بتاعون البنتين، الخمسة isomers، لاحظوا
+
+454
+00:40:00,800 --> 00:40:06,980
+أنا قولت البنتين، خمس درات، عفوا الثلاث isomers،
+
+455
+00:40:06,980 --> 00:40:15,390
+كم isomers؟ إيش أسميهم؟ بنتين، iso-بنتين؟ و نيو
+
+456
+00:40:15,390 --> 00:40:20,290
+بنتين بنتين ايزو بنتين نيو بنتين الآن لو واحدة بدت
+
+457
+00:40:20,290 --> 00:40:25,170
+تعمل الستة بدت تجيب ورقة و جلم ارصاص وتجرب تاخد
+
+458
+00:40:25,170 --> 00:40:29,030
+لها ربع ساعة ثلت ساعة من وين نقطة الانطلاق تبعها
+
+459
+00:40:29,030 --> 00:40:34,870
+بدكون من هذوله التلاتة تعون البنتين وتصير تزيد
+
+460
+00:40:34,870 --> 00:40:41,070
+عليهم carbon واضح؟ لأن هذوله الخمس كربونات هي
+
+461
+00:40:41,070 --> 00:40:43,830
+أشكالهم، يا هذا، يا هذا، يا هذا، الآن بدي أزيد
+
+462
+00:40:43,830 --> 00:40:47,490
+عليهم كربون، بجرب كل احتمالاتهان، كل احتمالاتهان،
+
+463
+00:40:47,490 --> 00:40:51,590
+كل احتمالاتهان، و بشوف الأشكال المشتركة، و بطلع
+
+464
+00:40:51,590 --> 00:40:57,610
+الجواب، في النهاية، هلاحظ أن ال six كربونات، كم
+
+465
+00:40:57,610 --> 00:41:05,030
+مركب لهم؟ خمسة isomers، السبع كربونات تسعة isomers
+
+466
+00:41:05,030 --> 00:41:10,670
+و هكذا طيب لو يا تورا سألنا سؤال و هذا أرجو أنكوا
+
+467
+00:41:10,670 --> 00:41:18,130
+تنتبهوا له هل هناك قاعدة عامة بتيجي بتقولي إذا
+
+468
+00:41:18,130 --> 00:41:21,950
+عندك هذا العدد من ال carbons معنى ذلك عندك هذا
+
+469
+00:41:21,950 --> 00:41:26,950
+العدد من ال isomers قاعدة رياضية حسابية بسيطة في
+
+470
+00:41:26,950 --> 00:41:33,420
+قاعدة بس لأول عشر مركبات الحقيقة مافيش قاعدة مافيش
+
+471
+00:41:33,420 --> 00:41:38,260
+قاعدة هذا كان أحيانا في أحد الكتب المدرسية محطوط
+
+472
+00:41:38,260 --> 00:41:42,580
+سؤال على الجانب هل توجد قاعدة وكثير من المدرسين
+
+473
+00:41:42,580 --> 00:41:48,140
+كانوا بيعملوا فيه اجتهادات كثيرة مافيش قاعدة إذا
+
+474
+00:41:48,140 --> 00:41:52,060
+أنا .. هذا الكلام كله بالتجريب بتم .. إذا أنا كان
+
+475
+00:41:52,060 --> 00:41:56,840
+في عندي .. إذا أنا كان في عندي عدد ال carbons إن
+
+476
+00:41:56,840 --> 00:42:00,320
+أقدر أعرف منها عدد ال isomers هذا الكلام بتم ..
+
+477
+00:42:00,320 --> 00:42:03,520
+بإيش؟ بالتجريب لكن لاحظوا كيف الكيميا العضوية
+
+478
+00:42:03,520 --> 00:42:09,710
+بتكبر كتير يعني مثلا لما نصل ل .. الـ 6 هكسين، 7
+
+479
+00:42:09,710 --> 00:42:14,090
+هبتين، 8 أكتين، 9 نونين، 10 ديكين، 10 كربونات
+
+480
+00:42:14,090 --> 00:42:22,110
+بلاحظ أن العشر كربونات هذوله منهم 75 مركّب 75
+
+481
+00:42:22,110 --> 00:42:29,610
+isomers يعني الصيغة C10H22 لأن عشرة في اتنين عشرين
+
+482
+00:42:29,610 --> 00:42:33,930
+زاد اتنين اتنين وعشرين في بدها خمسة وسبعين مُركّب،
+
+483
+00:42:33,930 --> 00:42:37,690
+بهيك بنقدر نصير فاهمين ليش الكيميا العضوية كبيرة
+
+484
+00:42:37,690 --> 00:42:43,030
+في عدد مُركّباتها، إنه من نفس العدد من الذرات عمال
+
+485
+00:42:43,030 --> 00:42:50,670
+بنعمل احنا عدد كبير جدا من المتشكلات، بنعمل عدد
+
+486
+00:42:50,670 --> 00:42:53,750
+كبير جدا من المتشكلات
+
+487
+00:42:55,530 --> 00:43:02,290
+هذا بالنسبة للألكنز الأساسية ومتشكلات هذه الألكنز
+
+488
+00:43:02,290 --> 00:43:07,590
+الأساسية المرة الماضية ونأكد عليك آخر شيء بدنا
+
+489
+00:43:07,590 --> 00:43:13,790
+نحكيه اتكلمنا عن جزء الميثين اللي هو الجزء الأول
+
+490
+00:43:13,790 --> 00:43:19,590
+و قلنا كيف شكله الميثين تتراهيدرال
+
+491
+00:43:19,590 --> 00:43:25,180
+CH4 و معنى tetrahedral أنه أبقله أربع وجوه يعني لو
+
+492
+00:43:25,180 --> 00:43:29,420
+أنا جيبت مثلث أو ممكن نستعمل الروابط الكبيرة عشان
+
+493
+00:43:29,420 --> 00:43:36,700
+نوضح الأمر خلال تلت دقائق تقريبا المتبقية هاي جزاء
+
+494
+00:43:36,700 --> 00:43:43,420
+الميثين هذا قولنا عنه إيش الشكل تبعه تتراهيدرال
+
+495
+00:43:43,420 --> 00:43:49,800
+رباعي الأوجه اللي بنقصده إحنا برباعي الأوجه أنه
+
+496
+00:43:49,800 --> 00:43:56,940
+أنا لو جيبتمثلث وجه زي هذا المثلث اللي موجود عندي
+
+497
+00:43:56,940 --> 00:44:04,100
+و سكرت هنا هى إيش عندى وجه طب لو عملت هنا وجهين لو
+
+498
+00:44:04,100 --> 00:44:09,740
+عملت هنا ثلت أوجه لو عملت هنا سكر الشكل شفتوا ليش
+
+499
+00:44:09,740 --> 00:44:14,600
+رباعي الأوجه يعني لو أنا هذا بدي أسكره على شكل معين
+
+500
+00:44:14,600 --> 00:44:20,550
+بدي كام مثلث زي هذا أربعة أربعة أوجه هي وجهوهي
+
+501
+00:44:20,550 --> 00:44:28,910
+كمان وجه سكرت هنا وهي كمان وجه معين سكرت هذه وهي
+
+502
+00:44:28,910 --> 00:44:33,870
+كمان الوجه الرابع سكرت هذه ولذلك إيش بنسمي الشكل
+
+503
+00:44:33,870 --> 00:44:40,390
+تبع الميثين تتراهيدرال واضح إن هذا الشكل في مستوى
+
+504
+00:44:40,390 --> 00:44:44,310
+واحد ولا بالفراغ يعني planner ولا three
+
+505
+00:44:44,310 --> 00:44:49,050
+dimensional بنسميه three dimensional بالفراغ الآن
+
+506
+00:44:49,050 --> 00:44:53,330
+لما بدى اعبر عن هذا الشكل كيف باعبر عنه افضل الطرق
+
+507
+00:44:53,330 --> 00:44:58,670
+للتعبير عنه إن أنا امسكه بهذه الطريقة اتخيل إن
+
+508
+00:44:58,670 --> 00:45:04,050
+هذوله التنتين جايين في مستوى أفقي للأمام لاحظوا
+
+509
+00:45:04,050 --> 00:45:08,050
+هاي المستوى هذا مستوى أفقي ولا لأ و بينهم زاوية
+
+510
+00:45:08,050 --> 00:45:11,930
+مية وتسعة و نصف و هذوله جايين في مستوى متعامد على
+
+511
+00:45:11,930 --> 00:45:16,610
+المستوى الأفقي للخلف إذا الجزء أفضل طريقة لرسمه
+
+512
+00:45:16,610 --> 00:45:21,830
+اتخيله بهذا الشكلهي مستوى أفقي للأمام عمودي عليهم
+
+513
+00:45:21,830 --> 00:45:29,650
+تنتين في مستوى أفقي لوين؟ للخلف واضح؟ مستويين هي
+
+514
+00:45:29,650 --> 00:45:34,830
+مستوى أفقي ومستوى عمودي عليه الأفقي تنتين للأمام و
+
+515
+00:45:34,830 --> 00:45:40,010
+العمودي عليه تنتين للخلف طب هذا الكلام سهل إن
+
+516
+00:45:40,010 --> 00:45:44,750
+نشرحه لكن لو قلنا يا تورا بدنا نرسمه دائما الاشي
+
+517
+00:45:44,750 --> 00:45:50,670
+للخلف كيف برسمه أنا؟ مُنَقَط أو شرطات dashes واللي
+
+518
+00:45:50,670 --> 00:45:56,030
+للأمام solid مسكّر واضح؟ أفضل الطرق اللي ممكن
+
+519
+00:45:56,030 --> 00:46:01,010
+نستعملها لرسم هذا الجزء هي هذه الطريقة إن اخلي
+
+520
+00:46:01,010 --> 00:46:06,870
+هدول ال hydrogens للأمام وبستعمل هذا المثلث أو
+
+521
+00:46:06,870 --> 00:46:13,850
+بنسمي إحنا إيش wedge عارفين إيش يعني wedge؟ هذا
+
+522
+00:46:13,850 --> 00:46:22,930
+اللي زي هيك بنقول عنه wedge وتحديدا solid wedge ولو
+
+523
+00:46:22,930 --> 00:46:30,850
+كان للخلف التانية دولة للخلف بنعمله dashed wedge
+
+524
+00:46:30,850 --> 00:46:38,170
+wedge تترجم باللغة العربية بمعنى أسفيل الأسفيل
+
+525
+00:46:38,170 --> 00:46:42,930
+شغلة زي هذه شايفين هذه الخشبة؟ هذه إحنا إيش
+
+526
+00:46:42,930 --> 00:46:49,470
+بنسميها؟ أسفين ما رو عليكم هذا الاسم؟ حتى .. حتى
+
+527
+00:46:49,470 --> 00:46:53,890
+في اللغة .. حتى في اللغة الأدبية والإنسانية كلمة
+
+528
+00:46:53,890 --> 00:46:59,270
+أسفين بتمر معنى كتير اللي بيكون بيفرج اتنين أصدقاء
+
+529
+00:46:59,270 --> 00:47:04,440
+عن بعض إيش بنستعمله إحنا باللغة الأدبية؟ بنقول و
+
+530
+00:47:04,440 --> 00:47:10,000
+جاء فلان و دق اسفيناً بين الإخوة، فرجهم مع بعض،
+
+531
+00:47:10,000 --> 00:47:13,560
+يعني تخيلوا أنتوا، هاي هذه وهذه إخوة، الآن باجي
+
+532
+00:47:13,560 --> 00:47:16,840
+أنا بهذا الإسفين، بحطه، بصير بدوجي بهذا الشكل،
+
+533
+00:47:16,840 --> 00:47:22,390
+بهذا الشكل، شو بعمل؟ ببعدهم عن بعض فكلمة دقة اسفينا
+
+534
+00:47:22,390 --> 00:47:27,190
+باللغة العربية والقصصية معناها بعادهم عن بعض هذا
+
+535
+00:47:27,190 --> 00:47:32,150
+اللي أنا بستعمله إيش بسميه أنا اسفين اللي للأمام
+
+536
+00:47:32,150 --> 00:47:37,610
+لازم يكون solid و اللي للخلف لازم يكون dash المرة
+
+537
+00:47:37,610 --> 00:47:41,910
+الجاية بنبدأ إن شاء الله من هذه النقطة وبنركز عليها
+
+538
+00:47:41,910 --> 00:47:47,150
+أكتر حتى نفهم هذا الشكل شكل الميثين بشكل جيد لأن
+
+539
+00:47:47,150 --> 00:47:55,930
+هو أساس فاهمنا لل organ ال chemistry المرة
+
+540
+00:47:55,930 --> 00:47:57,970
+الجاية كتير هفصل في الموضوع
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4.srt
new file mode 100644
index 0000000000000000000000000000000000000000..db2e01df2a6128046d13c7844b0bd9049f3b6f7e
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4.srt
@@ -0,0 +1,1374 @@
+
+1
+00:00:19,470 --> 00:00:24,710
+بسم الله الرحمن الرحيم بنكمل اليوم في موضوع ال
+
+2
+00:00:24,710 --> 00:00:30,170
+aldehydes و ال ketones و ربما كلكم الذاكرين أنه
+
+3
+00:00:30,170 --> 00:00:34,130
+التفاعل الأساسي لل aldehydes و ال ketones كان
+
+4
+00:00:34,910 --> 00:00:40,890
+Nucleophilic Addition أخدنا
+
+5
+00:00:40,890 --> 00:00:47,150
+عدة أمثلة ع الموضوع إضافة الماء الكحول ال cyanide
+
+6
+00:00:47,150 --> 00:00:53,200
+مثلا ال H- لعملية ال reduction و اليوم هناخد بشكل
+
+7
+00:00:53,200 --> 00:00:58,440
+أساسي كمان مثلين على هذا الموضوع يعني للناس اللي
+
+8
+00:00:58,440 --> 00:01:03,180
+بيحبوا الصور الكلية و بيفهموا الموضوع بالصورة
+
+9
+00:01:03,180 --> 00:01:06,980
+الكلية مش بالصورة الجزائية أو الجزئية خلينا نقول
+
+10
+00:01:06,980 --> 00:01:13,120
+كأنه كل تفاعلات الكحولات لو بدكم تسجلوها إضافة ما
+
+11
+00:01:14,130 --> 00:01:21,730
+بحط OH كحول بحط Oethyl أو OR in general فعلا ال
+
+12
+00:01:21,730 --> 00:01:27,870
+cyanide بحط CN minus ال hydride بحط H ماينوس الان
+
+13
+00:01:27,870 --> 00:01:33,370
+في عندنا اضافتين واحدة من هذول الاضافتين التفاعل
+
+14
+00:01:33,370 --> 00:01:39,450
+مع Grignard reagent واضح عادة هذا المتفاعل يمكن
+
+15
+00:01:39,450 --> 00:01:43,270
+ماعندكم مش خبرة عنه بنتعرف عليه شو هو Grignard
+
+16
+00:01:43,270 --> 00:01:47,020
+reagent إذا بتلاحظوا reaction of aldehydes and
+
+17
+00:01:47,020 --> 00:01:51,340
+ketones with Grignard reagent ربما تقرأوا الكلمة
+
+18
+00:01:51,340 --> 00:01:57,260
+كأنها Grignard لكن عادة احنا بنقولها ايش Grignard
+
+19
+00:01:57,260 --> 00:02:06,290
+reagent هذا متفاعل اللي عمله لأنه مهم كتيراخد عليه
+
+20
+00:02:06,290 --> 00:02:13,430
+جائزة نوبل في الكيميا عشانك جربه ممكن تفهمه جيدا و
+
+21
+00:02:13,430 --> 00:02:19,730
+الكلام مش جديد يعني في ال 1911 تقريبا قبل أكثر من
+
+22
+00:02:20,620 --> 00:02:25,320
+ميت سنة بتعرف جائزة نوبل بدت من ال 1900 تقريبا
+
+23
+00:02:25,320 --> 00:02:31,620
+فبال 1911 أخد عليه جائزة نوبل ايش هو ال Grignard
+
+24
+00:02:31,620 --> 00:02:38,120
+reagent بالظبط الان لو أخدنا احنا اي مركب متصل
+
+25
+00:02:38,120 --> 00:02:45,980
+بهالوجل RX او ARX بتحبوا تاخدوهم بالصيغة العامة
+
+26
+00:02:45,980 --> 00:02:54,100
+بمشي الحال يعني بقول RX او ARX بتحبوا تاخدوهم بمثال
+
+27
+00:02:54,100 --> 00:03:00,600
+بيمشي الحال برضه يعني مثلا نقول CH3CH2CL
+
+28
+00:03:00,600 --> 00:03:06,580
+هايه بمثال واضح CH3CH2Br
+
+29
+00:03:06,580 --> 00:03:13,120
+هذا RX ولا لأ؟ RX ولو بدي انا ARX مثلا اخد فنل
+
+30
+00:03:13,120 --> 00:03:24,730
+بنزينة فنل Br أو فنل CL الآن لو أخدنا RX او ARX
+
+31
+00:03:24,730 --> 00:03:29,590
+وفعلناهم مع بودرة المغنيسيوم في ظروف جافة في
+
+32
+00:03:29,590 --> 00:03:33,810
+solvent ال ether يعني هدولا بنافعلهم مع ايش؟
+
+33
+00:03:33,810 --> 00:03:40,970
+مغنيسيوم MG و عادة بستعملوا solvent ether والاصل
+
+34
+00:03:40,970 --> 00:03:47,370
+يكون dry ether واضح؟ الآن هذا بيتفعل بيعطينا الشكل
+
+35
+00:03:47,370 --> 00:03:59,110
+القاتل بيعطينا CH3 CH2 MgBr
+
+36
+00:03:59,110 --> 00:03:59,410
+CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH3 CH3 CH3 CH3
+
+37
+00:03:59,410 --> 00:04:00,690
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+38
+00:04:00,690 --> 00:04:02,730
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+39
+00:04:02,730 --> 00:04:03,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+40
+00:04:03,130 --> 00:04:07,610
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+41
+00:04:07,610 --> 00:04:11,670
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+42
+00:04:11,670 --> 00:04:16,080
+CH3 CH3 Grignard reagent الآن لو كنت بدى اسميه
+
+43
+00:04:16,080 --> 00:04:20,860
+بمشي فيه من الشمال لليمين هذه المجموعة شو هي ايه
+
+44
+00:04:20,860 --> 00:04:29,040
+فينيل ماجنيسيوم برومايو هذا فنيل ماجنيسيوم برومايو
+
+45
+00:04:29,040 --> 00:04:35,000
+و مثلها مثيل وبروبيل وايزوبروبيل وهكذا هذا هو ال
+
+46
+00:04:35,000 --> 00:04:39,320
+Grignard reagent عرفنا بالظبط شو هو الآن هذا ال
+
+47
+00:04:39,320 --> 00:04:45,030
+Grignard reagent ماذا هو الفائدة التي جعل الناس
+
+48
+00:04:45,030 --> 00:04:52,270
+يعطوه جائزة نوبل في الكيميا للعالم هذا؟ ال
+
+49
+00:04:52,270 --> 00:04:57,070
+Grignard agent هو عبارة عن carbon nucleophile يعني
+
+50
+00:04:57,070 --> 00:05:02,450
+أنا لما بدي اتعامل معه بدي أخده بهذا الشكل أنسى ال
+
+51
+00:05:02,450 --> 00:05:03,230
+MgBr
+
+52
+00:05:05,600 --> 00:05:09,900
+بدي أخده بهذا الشكل الآن هو بهذا الشكل صار بيمثل
+
+53
+00:05:09,900 --> 00:05:17,120
+لي CH3 CH2 و زوج إلكترونات على الكاربون فهو carbon
+
+54
+00:05:17,120 --> 00:05:22,140
+nucleophile أو أخده بهذا الشكليعني هو صح موجود
+
+55
+00:05:22,140 --> 00:05:26,820
+كمركب لكن في لحظة التفاعل يعني تخيلوا بالظبط a
+
+56
+00:05:26,820 --> 00:05:31,400
+Grignard reagent كأنه هذا القلم الآن هذا الجزء
+
+57
+00:05:31,400 --> 00:05:35,360
+اللي فيه ال nucleophile هو اللي بيجي يتفاعل و يعمل
+
+58
+00:05:35,360 --> 00:05:41,160
+addition و ال MgBr ما إنه ملها واضح؟ فكأنه يمثل هذا
+
+59
+00:05:41,160 --> 00:05:43,900
+القلم مع الغطاية، الآن أنا مهتم بالغطاية ولا
+
+60
+00:05:43,900 --> 00:05:48,020
+بالقلم؟ الآن أنا من ال Grignard agent بإيش
+
+61
+00:05:48,020 --> 00:05:53,820
+مهتم؟ بال R مع إلكتروناتها أو بال AR مع
+
+62
+00:05:53,820 --> 00:05:59,420
+إلكتروناتهاواضحة الفكرة؟ الآن لما بدي اجي اقول ان
+
+63
+00:05:59,420 --> 00:06:05,240
+هذا ال R مع إلكتروناتها او ال AR مع إلكتروناتها
+
+64
+00:06:05,240 --> 00:06:08,960
+بدها تيجي تتفاعل مع الديهيد او الكيتون هي أصبحت
+
+65
+00:06:08,960 --> 00:06:14,800
+نيوكليوفايل الآن كيف بتيجي و اين بتيجي تهاجم؟ هاي
+
+66
+00:06:14,800 --> 00:06:22,590
+ال R بدها تهاجم هنا وهذه ايش بدها تصير؟ OH في
+
+67
+00:06:22,590 --> 00:06:26,770
+النهاية طبعا هو هنا كتبلكوا التفاعل بالتفصيل ان
+
+68
+00:06:26,770 --> 00:06:31,290
+أول ما بتهاجم هنا بتصير OMGPR بعدين بنضيف عليه
+
+69
+00:06:31,290 --> 00:06:35,990
+نقطة ميه و حامض فبتصفى OH الآن هي نتيجة نهائية
+
+70
+00:06:35,990 --> 00:06:40,130
+يعني هذه الشغل تفصيل جوا التفاعل احنا مش مهتمين
+
+71
+00:06:40,130 --> 00:06:43,410
+فيها بدنا في النهاية نتيجة نهائية متذكرين المرة
+
+72
+00:06:43,410 --> 00:06:48,810
+الماضية لما كنا نقولكم كل CW bond O ايش بتصير وكنا
+
+73
+00:06:48,810 --> 00:06:56,310
+نحطها بمربع أخضر و النيوكليوفايل بيهاجم هاي
+
+74
+00:06:56,310 --> 00:07:01,330
+نيوكليوفايل و السيطة بالبنط O صارت OH الآن ال R و
+
+75
+00:07:01,330 --> 00:07:08,210
+ال R' ما تدخلوش احنا كل اللي عملناه الحقيقة في
+
+76
+00:07:08,210 --> 00:07:11,930
+التفاعلات كل اللي عملناه في التفاعلات تبع ال
+
+77
+00:07:11,930 --> 00:07:16,690
+aldehydes و ال ketones هو فقط تغيير اللي هان يعني
+
+78
+00:07:16,690 --> 00:07:20,310
+كل اللي درسنا قولنا لما تكون هذه مياه بده يكون هنا
+
+79
+00:07:22,430 --> 00:07:27,930
+OH لما يكون كحول OR لما يكون cyanide CN لما يكون
+
+80
+00:07:27,930 --> 00:07:32,970
+hydride H الآن لما يكون Grignard R
+
+81
+00:07:36,320 --> 00:07:40,660
+و بعد شوية هنجيب نيتروجين نيوكليوفايل يتحد هنا
+
+82
+00:07:40,660 --> 00:07:45,980
+بنكون خلصنا الشطر الألديهيد و الكيتونز فكل شغلنا
+
+83
+00:07:45,980 --> 00:07:52,340
+الحقيقة هو عبارة عن أمثلة لنفس التفاعل أمثلة لنفس
+
+84
+00:07:52,340 --> 00:07:56,820
+التفاعل فقط تغيير النيوكليوفايل في كل الأحوال عندي
+
+85
+00:07:56,820 --> 00:08:00,500
+addition و ال C double bond O بتصير OH هذا عام
+
+86
+00:08:00,500 --> 00:08:05,030
+مشترك لكن النيوكليوفايل مارا يكون كذا كذا كذا اليوم
+
+87
+00:08:05,030 --> 00:08:09,050
+ايش لنيو كليو فايل تبعنا ل Grignard reagent
+
+88
+00:08:09,050 --> 00:08:15,630
+اللي هو R مع إلكتروناتها او AR مع إلكتروناتها و
+
+89
+00:08:15,630 --> 00:08:19,850
+عرفنا كيف بتحضر يعني لو كنا بديني ب RX كتبنا مع ال
+
+90
+00:08:19,850 --> 00:08:25,790
+MG بنكتب RMGX بعدين لما بنفعله ايش بناخد منه بس ال
+
+91
+00:08:25,790 --> 00:08:34,190
+R ال RMGX مش موضوعنا الآن هذا التفاعل حقيقةمهم
+
+92
+00:08:34,190 --> 00:08:40,270
+كتير ليش؟ خلّينا نجرب نفس ال Grignard reagent على
+
+93
+00:08:40,270 --> 00:08:44,770
+أنواع مختلفة من الالديهيدس و الكيتونز نقول
+
+94
+00:08:44,770 --> 00:08:48,410
+ال Grignard reagent تبعنا إثيل ال RgBr يعني إثيل
+
+95
+00:08:48,410 --> 00:08:52,430
+مجليسيامبروميدل الآن هذا إيش هيحُك اليوكليوفاين؟
+
+96
+00:08:53,400 --> 00:08:59,020
+مجموعة ال aethyl لو فعلنا مع ال formaldehyde اللي
+
+97
+00:08:59,020 --> 00:09:05,580
+هو أبسط ال dehyde هذه بدها تصير OH و بده يحط عندها
+
+98
+00:09:05,580 --> 00:09:13,060
+مجموعة ال aethyl هاي مجموعة ال aethyl شايفينها و
+
+99
+00:09:13,060 --> 00:09:20,200
+هنا CH2 OH هذه ثابتةواضح؟ إذا هو حط مجموعة ال
+
+100
+00:09:20,200 --> 00:09:22,660
+ethylene لاحظوا الآن ال Grignard مع ال
+
+101
+00:09:22,660 --> 00:09:28,120
+formaldehyde كوالي كحول إيش نوع هذا الكحول؟
+
+102
+00:09:28,120 --> 00:09:32,880
+primary alcohol طيب خليني أفعل ال Grignard مع أي
+
+103
+00:09:32,880 --> 00:09:40,060
+aldehyde تاني غير ال formaldehyde يعني
+
+104
+00:09:40,060 --> 00:09:44,360
+acetaldehyde هذا, ibropenaldehyde, benzaldehyde
+
+105
+00:09:44,360 --> 00:09:51,840
+طبعا هيحط برضه مجموعة الإثيل وهي جزء ال الديهايد
+
+106
+00:09:51,840 --> 00:09:56,320
+كانت كاربون متصل فيها H و CH3 وصارت OH الآن إيش
+
+107
+00:09:56,320 --> 00:10:02,760
+كوّل لها سكندري الكحول طب خلّيه يتفاعل مع ال كيتون
+
+108
+00:10:02,760 --> 00:10:10,200
+مع هذا الاسيتون شو هيحط مجموعة ال إثيل تيرتشاري
+
+109
+00:10:10,200 --> 00:10:17,710
+الكحول واضح؟ إذن الآن صرنا فاهمين ليش Grignard
+
+110
+00:10:17,710 --> 00:10:21,810
+agent موضوع مهم لأن هو بالنسبة لنا بيمثل طريقة
+
+111
+00:10:21,810 --> 00:10:26,910
+لتحضير كل أنواع الكحولات يعني لو بدى primary
+
+112
+00:10:26,910 --> 00:10:32,610
+alcohol بدى أنطلق من ال formaldehyde تمام؟ لو بدى
+
+113
+00:10:32,610 --> 00:10:39,150
+secondary alcohol بدى أنطلق من أي aldehyde تاني
+
+114
+00:10:39,150 --> 00:10:44,410
+غير غير ال formaldehyde لأن ال formaldehyde بيعطي
+
+115
+00:10:44,410 --> 00:10:47,710
+ال alcohol برايمر كل ال aldehydes التانية بيعطيه
+
+116
+00:10:48,170 --> 00:10:53,850
+secondary لو بدى tertiary alcohol بدى كيت بيعطينى
+
+117
+00:10:53,850 --> 00:10:58,830
+بدى اتفاعل مع أو بدى تم التفاعل مع الكيتون و بناء
+
+118
+00:10:58,830 --> 00:11:03,810
+على ذلك لو قلنالكوا اكمل المعادلة او مثلا كيف تحضر
+
+119
+00:11:03,810 --> 00:11:10,910
+كحول معين كيف بدى يكون الجواب تبعنا باستعمال طريقة
+
+120
+00:11:10,910 --> 00:11:15,710
+Grignard باستعمال طريقة Grignard خلينا ناخد
+
+121
+00:11:17,360 --> 00:11:23,800
+مثال او اكتر على هذا الموضوع حتى انرسخ هذا الكلام
+
+122
+00:11:23,800 --> 00:11:32,360
+يعني لو اجينا سألناكم عندكم هذا الكحول فينيل CH2OH
+
+123
+00:11:32,360 --> 00:11:39,860
+how can you prepare this alcohol فكرولي ان انتوا
+
+124
+00:11:39,860 --> 00:11:44,080
+بتكونوا تحضروا هذا الكحول بطريقة السيد الجرين يعني
+
+125
+00:11:45,470 --> 00:11:51,690
+ماشي اللي هنقوله ايش
+
+126
+00:11:51,690 --> 00:12:00,310
+نوع هذا الكحول ال primary اذا انا لازمني ال CH2 و
+
+127
+00:12:00,310 --> 00:12:04,990
+ال double bond all formaldehyde و بدي افعله مع اي
+
+128
+00:12:04,990 --> 00:12:11,970
+Grignard agent مع فنل MgBr
+
+129
+00:12:14,230 --> 00:12:17,290
+فنل مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر
+
+130
+00:12:17,290 --> 00:12:19,310
+مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر
+
+131
+00:12:19,310 --> 00:12:20,190
+مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر
+
+132
+00:12:20,190 --> 00:12:25,610
+مجدر مجدر مجدر
+
+133
+00:12:25,610 --> 00:12:26,890
+مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر
+
+134
+00:12:26,890 --> 00:12:32,990
+مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر
+
+135
+00:12:32,990 --> 00:12:35,270
+مجدر
+
+136
+00:12:43,630 --> 00:12:49,690
+وكان السؤال بالشكل القاتى how can you prepare this
+
+137
+00:12:49,690 --> 00:12:57,390
+alcohol from two different compounds يعني بده يعمل
+
+138
+00:12:57,390 --> 00:13:01,010
+مركبين والمركبين معروفين جيدا بالنسبة إلينا كيف
+
+139
+00:13:01,010 --> 00:13:05,930
+بنحضر هذا الكحول من مركبين مختلفين two different
+
+140
+00:13:05,930 --> 00:13:12,390
+ketones الان
+
+141
+00:13:13,490 --> 00:13:17,790
+وحدة قالت ممكن نستعمل هذا ال C double bond O حاملة
+
+142
+00:13:17,790 --> 00:13:24,550
+تنتهي CH3 وحدة حاملة CH3 وحدة فنل C double bond O
+
+143
+00:13:24,550 --> 00:13:33,870
+CH3 و هذه فنل هذا المركب شو اسمه؟ خلينا في اللي
+
+144
+00:13:33,870 --> 00:13:34,630
+بنعرفه
+
+145
+00:13:37,180 --> 00:13:42,240
+اسيتون اسيتون ماحد بيقول عنه provenone واضح؟
+
+146
+00:13:42,240 --> 00:13:47,860
+اسيتون و هذا يلا
+
+147
+00:13:47,860 --> 00:13:53,600
+بتحكوا بعد يومين فين ال C-double bond OCH3؟
+
+148
+00:13:53,600 --> 00:13:58,740
+أسيتوفينون أبشر بطولى سلامة اليوم الرابعه
+
+149
+00:13:58,740 --> 00:14:05,060
+أسيتوفينون إذا هذا أسيتون هذا أسيتوفينون الآن
+
+150
+00:14:05,060 --> 00:14:09,500
+هدولة لما أنا بدي أفعلهم هذه إيش ناقصها مجموعة إيش
+
+151
+00:14:09,500 --> 00:14:19,380
+إذا هاخد فين ال .. MgBr MgBr و هذه إيش ناقصها هاخد
+
+152
+00:14:19,380 --> 00:14:24,600
+CH3 MgBr
+
+153
+00:14:27,780 --> 00:14:32,200
+واضح؟ مجمعتين بدهم يكونوا على الكيتون و التالتة بدي
+
+154
+00:14:32,200 --> 00:14:35,580
+اجيبها من ال Grignard و اعملوا اي خلطة انتوا
+
+155
+00:14:35,580 --> 00:14:42,930
+بتكونوا معاها واضحة في هذه النقطة؟ إذا مش صعب ان
+
+156
+00:14:42,930 --> 00:14:47,610
+نحضر primary او secondary او tertiary alcohol قطعة
+
+157
+00:14:47,610 --> 00:14:51,670
+من القطع هنجيبها من وين؟ من ال Grignard و الباقي
+
+158
+00:14:51,670 --> 00:14:57,730
+بيكون جزء ال aldehyde او ال ketone اللي هيكون
+
+159
+00:14:57,730 --> 00:14:59,830
+موجود عندنا و نبدأ فيه
+
+160
+00:15:09,860 --> 00:15:14,140
+الآن بنجي لنقطة جديدة لكن مرت علينا مش هناخد فيها
+
+161
+00:15:14,140 --> 00:15:18,580
+كتير Oxidation of aldehydes and ketones مر علينا
+
+162
+00:15:18,580 --> 00:15:23,500
+احنا ان ال primary alcohol كانت تتأكسد لإيش
+
+163
+00:15:23,500 --> 00:15:26,760
+لالدهيد
+
+164
+00:15:26,760 --> 00:15:30,620
+و اذا استعملنا عامل مؤكسد قوي الالدهيد شو بيصير؟
+
+165
+00:15:30,620 --> 00:15:34,980
+acid خلاص اذا الجزء اللى بدنا يهو ال الديهيد كان
+
+166
+00:15:34,980 --> 00:15:40,260
+بي oxidizeto acids مرت علينا في جزء ال alcohol ولا
+
+167
+00:15:40,260 --> 00:15:44,230
+لأ؟ أه كنا نقول الكحول بيصير ال الديهيد و ال
+
+168
+00:15:44,230 --> 00:15:48,050
+الديهيد أسد ال الديهيد أسد هو تفاعل لل الديهيد و
+
+169
+00:15:48,050 --> 00:15:51,610
+الكيتون صارنا عارفينه طيب ال secondary alcohol
+
+170
+00:15:51,610 --> 00:15:56,510
+كانوا يتأكسدوا لإيش لكيتون ال كيتون بتتأكسد أكسدة
+
+171
+00:15:56,510 --> 00:16:00,970
+إضافية لأ إذا هاي الموضوع أكسدت ال الديهيد و
+
+172
+00:16:00,970 --> 00:16:05,130
+الكيتون ان ال الديهيد بيصيروا أسد و الكيتون
+
+173
+00:16:05,130 --> 00:16:11,700
+بتأكسدوش خلصناواضح؟ و كل هذه الفكرة مرت علينا في أي
+
+174
+00:16:11,700 --> 00:16:18,260
+منطقة؟ في منطقة الكحولات كل هذه الفكرة مرت علينا
+
+17
+
+223
+00:20:54,930 --> 00:21:00,380
+عشان نكتب الجواب الصح، بدنا نقعد نتخيل الحالة
+
+224
+00:21:00,380 --> 00:21:04,520
+الوسيطة ونقول تمت الإضافة ونرسم الناتج وبعدين بتتم
+
+225
+00:21:04,520 --> 00:21:08,980
+الحدف، وتاخدوا خمس دقائق وانتوا تكتبوا الجواب لأ
+
+226
+00:21:08,980 --> 00:21:13,960
+بإمكاننا من ناحية تطبيقية نعمل الأمر بطريقة سهلة
+
+227
+00:21:13,960 --> 00:21:19,080
+جدا، الأمر بطريقة سهلة جدا اللي بيشمل العمليتين أنه
+
+228
+00:21:19,080 --> 00:21:23,600
+دائما تخيلوا C double bond O والان H2 جايين بهذا
+
+229
+00:21:23,600 --> 00:21:27,980
+الشكل الان خلوها تصير C double bond N لاحظوا ايش
+
+230
+00:21:27,980 --> 00:21:37,060
+أنا حدفت H2O، فخلو بدل ما مكتوب عندكم C double bond
+
+231
+00:21:37,060 --> 00:21:43,480
+O خلوها C double bond N والان متصلة ب X. إذا هذا
+
+232
+00:21:43,480 --> 00:21:49,020
+التفاعل صار أسهل تفاعل فيهم نتيجته النهائية أنه في
+
+233
+00:21:49,020 --> 00:21:54,000
+التفاعل مع ال N H2، بدل ما كان عنده C double bond O
+
+234
+00:21:54,000 --> 00:22:02,360
+بتصير C double bond N واضحة الفكرة و ال N بأي X
+
+235
+00:22:02,360 --> 00:22:07,580
+متصلة يعتبر موضوع بسيط، بس كنتيجة أنه C double bond
+
+236
+00:22:07,580 --> 00:22:15,640
+O بتصير C double bond N أبتدت أن نكون كفكرة إلتهينا
+
+237
+00:22:15,640 --> 00:22:22,020
+من هذه التفاعلات، ولكن الآن نريد أن نعرف أسماء
+
+238
+00:22:22,020 --> 00:22:27,970
+الأشياء التي تتفاعل عادة أو بمعنى آخر خلّينا نقول
+
+239
+00:22:27,970 --> 00:22:32,710
+نعطي أمثلة على ال X. إيش ممكن تكون ال X؟ واضحة
+
+240
+00:22:32,710 --> 00:22:37,950
+الفكرة؟ إيش ممكن تكون ال X؟ الآن هذه عندي دائما و
+
+241
+00:22:37,950 --> 00:22:42,270
+أبدا unatched two نتفق ال unatched two نحطها وين؟
+
+242
+00:22:44,150 --> 00:22:48,970
+بمربع أخضر. هذه اللي فاهمين هي ال N H 2 ال N متصلة
+
+243
+00:22:48,970 --> 00:22:55,090
+ب X ال X في هذا المثال شو هي؟ N H 2 تانية ال N هذي
+
+244
+00:22:55,090 --> 00:22:58,950
+ال N H 2 اللي متصلة ب N H 2 تانية، المركب بسميه
+
+245
+00:22:58,950 --> 00:23:06,810
+هيدرازين. okay. هيدرازين طيب لو ال N H 2 تانية كانت
+
+246
+00:23:06,810 --> 00:23:14,290
+متصلة ب N H phenyl يعني ال X عبارة عن إيش؟ ان اتش
+
+247
+00:23:14,290 --> 00:23:20,770
+فينيل هذي ال X كلها واضح بيصير اسمه فينيل هيدرازيل
+
+248
+00:23:22,460 --> 00:23:26,180
+أكيد هدول فيش نقاش انه كل اشي اللي أنا بدي احكيه
+
+249
+00:23:26,180 --> 00:23:32,400
+بده ينحفظ بالظبط فينل هيدرازين. طيب هذه ال N-H2
+
+250
+00:23:32,400 --> 00:23:37,320
+نفسها لو اتصلت ب N-H حاملة فينل وعالفينل على نمره
+
+251
+00:23:37,320 --> 00:23:42,120
+واحد اتنين تلاتة اربعة نيترو نايترو شو هنيجي
+
+252
+00:23:42,120 --> 00:23:51,480
+نسميه؟ two four dinitro فينل هيدرازين واضح؟
+
+253
+00:23:53,580 --> 00:23:58,160
+Two for dinitrophin الهيدرازين، الان لو جيبنا لأي
+
+254
+00:23:58,160 --> 00:24:02,760
+واحد من هدول هذا أو هذا أو هذا كيتون C double bond
+
+255
+00:24:02,760 --> 00:24:06,480
+O وقلنا بدنا نكمل المعادلة احنا واحنا مغمضين
+
+256
+00:24:06,480 --> 00:24:12,720
+متعودين ان هال C double bond O تصير C double bond
+
+257
+00:24:12,720 --> 00:24:18,210
+N خلص الجواب الـ C double bond O بتصير C double
+
+258
+00:24:18,210 --> 00:24:22,370
+bond N و بنحدث الـ H طولها. طيب الآن لما اتكون هذا
+
+259
+00:24:22,370 --> 00:24:30,250
+المركب عندى هذا نتج من تفاعل الديهيد او كيتون
+
+260
+00:24:30,250 --> 00:24:39,130
+الديهيد او كيتون، يعني أنا حاطينهم بصيغة ايش؟ R، يعني
+
+261
+00:24:39,130 --> 00:24:43,470
+ممكن تكون H و H، H و مثل، مثل و مثل، اثل و اثل
+
+262
+00:24:44,950 --> 00:24:50,250
+اتشوفينيل، مثلوفينيل، كل احتمالات واردة الان المركب
+
+263
+00:24:50,250 --> 00:24:53,070
+اللي بيلتج عندى اللي فيه ال c double bond أو الان
+
+264
+00:24:53,070 --> 00:24:57,330
+ايش بدي اسميه؟ بسمي اسم ال الديهايد او ال كيتون
+
+265
+00:24:57,330 --> 00:25:03,870
+اللي كوّنه، و بحط النهاية اسم هذا، لكن بدل ما اقول
+
+266
+00:25:03,870 --> 00:25:09,970
+in بقول on يعني لو كان متفاعل مع NH2 و NH2 بسميه
+
+267
+00:25:09,970 --> 00:25:13,510
+الديهايد او كيتون هيدرازون
+
+268
+00:25:14,360 --> 00:25:20,800
+لو مع هذا فينيل هيدرازون، لو مع هذا two four
+
+269
+00:25:20,800 --> 00:25:26,220
+dinitrophenylheidrazone، فالنتج مااخد نفس الاسم لكن
+
+270
+00:25:26,220 --> 00:25:36,360
+بنهاية on بدل نهاية in خلينا الان نشوفه بامثلة
+
+271
+00:25:36,360 --> 00:25:41,450
+أكتر يعني بدون ال R وال R بأمثلة اقصوا بريد جيجا
+
+272
+00:25:41,450 --> 00:25:45,090
+اقصوا بريد جيجا الأمثلة بتوضح حالها لحالها اقصوا
+
+273
+00:25:45,090 --> 00:25:49,110
+بريد جيجا إن الله يحبه الصابرين والصابرات كمان
+
+274
+00:25:49,110 --> 00:25:59,990
+ربنا بيحبهم يعني
+
+275
+00:25:59,990 --> 00:26:09,310
+لو اجينا هنا حقينا هذه CH3 CH3 هذا المركب شو اسمه
+
+276
+00:26:12,370 --> 00:26:19,830
+اسيتون وهذا هيدرازين
+
+277
+00:26:19,830 --> 00:26:27,190
+الان المركب اللي نشأ منهم شو بدي اسميه؟ اسيتون
+
+278
+00:26:27,190 --> 00:26:35,630
+هيدرازون، مش هيدرازين، بيصيروا التانين مع بعض اسيتون
+
+279
+00:26:35,630 --> 00:26:39,510
+هيدرازون
+
+280
+00:26:40,980 --> 00:26:47,800
+وبناء على ذلك بنقدر نستنتج استنتاج بسيط جدا ان ال
+
+281
+00:26:47,800 --> 00:26:53,480
+hydrazines بيصيروا hydrazones طب ناخد مثال تاني
+
+282
+00:26:53,480 --> 00:26:58,960
+خلينا نحط هنا H ونحط هنا phenyl، في الناتج ايش
+
+283
+00:26:58,960 --> 00:27:07,380
+هيكون عندي هنا H و phenyl، لو قولنا لواحدة سمي ال
+
+284
+00:27:07,380 --> 00:27:14,520
+الديهيد او ال كيتون سمي هذا سمي الناتج، واضحة
+
+285
+00:27:14,520 --> 00:27:18,560
+الفكرة؟ اتفضلي ايش هذا بنسميه؟ فينيل C double bond
+
+286
+00:27:18,560 --> 00:27:23,940
+OH فينيل
+
+287
+00:27:23,940 --> 00:27:29,200
+C double bond OH ايش اسمه؟ الاسيتوفينون اللي فيه
+
+288
+00:27:29,200 --> 00:27:30,080
+CH3
+
+289
+00:27:42,220 --> 00:27:48,360
+بنزالدهيد بنزالدهيد بنزالدهيد
+
+290
+00:27:48,360 --> 00:27:56,880
+ممتازة، الآن هذا إيش اسمه؟
+
+291
+00:27:56,880 --> 00:28:02,180
+أخدناله اسم قبل شوية فنل هيدرازين
+
+292
+00:28:04,140 --> 00:28:13,040
+فنل هيدرازين فنل هيدرازين، الآن الناتج اللي ناتج من
+
+293
+00:28:13,040 --> 00:28:18,680
+التنين ايش هيكون اسمه؟ بنز الديهيد فنل هيدرازون بنز
+
+294
+00:28:18,680 --> 00:28:24,920
+الديهيد فنل هيدرازون، هاي جزء بنز الديهيد وفنل
+
+295
+00:28:24,920 --> 00:28:31,840
+هيدرازون، بنز الديهيد فنل
+
+296
+00:28:33,320 --> 00:28:38,180
+هيدرازون بدل ما كان الاسم عندى oen بدو يصير ايش
+
+297
+00:28:38,180 --> 00:28:42,300
+بنزالديهيدفينالهيدرازون
+
+298
+00:28:42,300 --> 00:28:45,860
+بنزالديهيدفينالهيدرازون
+
+299
+00:28:45,860 --> 00:28:47,920
+الان
+
+300
+00:29:00,620 --> 00:29:06,560
+لو مثلا اجينا وقلنالكوا، لو سمحتوا نختبركوا شطرين
+
+301
+00:29:06,560 --> 00:29:12,280
+ولا لا؟ ارسمولنا Cyclohexanone 2,4
+
+302
+00:29:12,280 --> 00:29:22,440
+-dinitrophenylhydrazone هيك ايجاكم Cyclohexanone
+
+303
+00:29:22,440 --> 00:29:29,520
+2,4-dinitrophenyl
+
+304
+00:29:33,300 --> 00:29:39,480
+هيدرازون كل هذا اسم بني آدم مؤدب بدنا نور اسمه
+
+305
+00:29:39,480 --> 00:29:46,380
+السياسة العامة، cut and conquer فرق تسد، جزقوها ال
+
+306
+00:29:46,380 --> 00:29:52,100
+Cyclohexanone أصلا
+
+307
+00:29:52,100 --> 00:29:58,980
+كان زي هيك CWO بس احنا عرفنا بعد العقلة ال CWO إيش
+
+308
+00:29:58,980 --> 00:30:05,270
+بتصير؟ C double bond N، هاي حطينا ال N، لما نكمل ال 2
+
+309
+00:30:05,270 --> 00:30:12,250
+,4-dinitrophenylhydrazone بدنا نحط N H حاملة فنل
+
+310
+00:30:12,250 --> 00:30:23,190
+وعلى موقع 2 بالفنل N O 2 و N O 2 طبعا اللي بتدرب
+
+311
+00:30:23,190 --> 00:30:27,710
+عليهم بيتقنهم هاي Cyclohexanone 2,4
+
+312
+00:30:27,710 --> 00:30:29,830
+-dinitrophenylhydrazone
+
+313
+00:30:34,850 --> 00:30:58,890
+واضحة الفكرة، طيب
+
+314
+00:30:58,890 --> 00:31:05,400
+لو كان السؤالعشان تشوفوا العلم مبني على بعضه
+
+315
+00:31:05,400 --> 00:31:14,440
+ارسموا Cyclohexane Carb Aldehyde Hydrazol، خلصنا
+
+316
+00:31:14,440 --> 00:31:23,540
+من هذا؟ Cyclohexane
+
+317
+00:31:23,540 --> 00:31:31,800
+Carb Aldehyde Cyclohexane Carb Aldehyde
+
+318
+00:31:36,170 --> 00:31:41,950
+Hydrazone كلمة واحدة
+
+319
+00:31:41,950 --> 00:31:47,490
+طبعا اللي بتعرفش ال Cyclohexane لحاله ولو بتعرفش
+
+320
+00:31:47,490 --> 00:31:51,370
+ال Hydrazone لحاله مش هترسم طبعا، هذا Cyclohexane
+
+321
+00:31:51,370 --> 00:31:55,950
+إيش؟ Carb Aldehyde، كلكوا لازم تكونوا متذكرين أنه
+
+322
+00:31:55,950 --> 00:32:00,410
+احنا لما حكينا عن ال aldehydes مع الحلقة قلنا ال
+
+323
+00:32:00,410 --> 00:32:07,610
+aldehyde بيكون معلق تعليج على الحلقة، يعني الـ
+
+324
+00:32:07,610 --> 00:32:11,010
+Cyclohexane كربلديهيد لو قلب لحاله زي هيك وهذه C
+
+325
+00:32:11,010 --> 00:32:16,750
+double bond O، الأن لما تصير Hydrazone هتصير C
+
+326
+00:32:16,750 --> 00:32:21,530
+double bond N ولما يكون.. بس كلمة Hydrazone لحاله
+
+327
+00:32:21,530 --> 00:32:27,890
+بدون ولا إشي تاني N H 2 لو كانت فين ال Hydrazone؟
+
+328
+00:32:27,890 --> 00:32:33,940
+بدي أحط فين ال.. طب لو قلتلكوا مثل Hydrazone هتمثل
+
+329
+00:32:33,940 --> 00:32:39,440
+لو قولت اتل هيدرازون، اتل لو قولت أسيتل هيدرازون
+
+330
+00:32:39,440 --> 00:32:46,480
+أسيتل، حد مايعرفش الأسيتل C double bond O CH3، Form
+
+331
+00:32:46,480 --> 00:32:53,940
+الهيدرازون، C double bond O H3 وهكذا، واضحة الفكرة
+
+332
+00:32:53,940 --> 00:33:00,930
+يعني اتعمقنا كتير كتير زيادة في الموضوع، الآن
+
+333
+00:33:00,930 --> 00:33:06,650
+ناخد مشتقة تانية ناخد مشتقة تانية لو يا تورا
+
+334
+00:33:06,650 --> 00:33:12,430
+ما كانش عندى مع ال N H2، N H2 تانية، لو كان عندى O H
+
+335
+00:33:12,430 --> 00:33:19,710
+لاحظوا هي عندي ال N H2 بس ايش ال X اللي هنا O H
+
+336
+00:33:19,710 --> 00:33:23,330
+هذا بنسميه Hydroxylamine
+
+337
+00:33:24,660 --> 00:33:30,340
+ماذا نسميه؟ هيدروكسل أمين، هي الهيدروكسل وهي الأمين
+
+338
+00:33:30,340 --> 00:33:33,420
+لما بده يتفاعل ال C double bond اوه بتحصل في
+
+339
+00:33:33,420 --> 00:33:39,280
+النهاية C double bond L، لما بدنا نسمي المركب بدنا
+
+340
+00:33:39,280 --> 00:33:45,300
+نقول ال الديهيد او ال كيتون، والان
+
+341
+00:33:45,300 --> 00:33:49,460
+على هذا الجزء بنكتب كلمة واحدة أكزيم
+
+342
+00:33:51,630 --> 00:33:56,990
+يعني ال c double volt n o h، إيش بنسميها؟ أكزيم
+
+343
+00:33:56,990 --> 00:34:01,850
+اكزيم، الان
+
+344
+00:34:01,850 --> 00:34:12,490
+واحدة
+
+345
+00:34:12,490 --> 00:34:19,470
+تقول أي، جانا هذا في الامتحان، رسمه أسيتوفينون اكزيم
+
+346
+00:34:20,940 --> 00:34:27,060
+اللي بدي يرسم، بدي يقول هاي ال Acetophenon فينل، و
+
+347
+00:34:27,060 --> 00:34:34,200
+CH3 و متصل بـ C double bond O أصلا عشان يكون
+
+348
+00:34:34,200 --> 00:34:41,680
+Acetophenon، الأهم لما يصير أكزيم، NOH، و مثل، و
+
+349
+00:34:41,680 --> 00:34:44,420
+Cyclohexanone أكزيم، و Cyclopentanone أكزيم، و كل
+
+350
+00:34:44,420 --> 00:34:51,160
+الأكزيمات إذا العملية سهلة ولا مش سهلة، هنا أخدنا
+
+351
+00:34:51,160 --> 00:35:01,640
+مشتقة الهيدرازون ومشتقة الأكزيم، طب
+
+352
+00:35:01,640 --> 00:35:07,560
+لو كانت هذه R، يعني مثل ولا إثل؟ إيش بدي يكون
+
+353
+00:35:07,560 --> 00:35:13,000
+الجواب؟ R مثل أو إثل كعائلة بيسموها shift base
+
+354
+00:35:13,000 --> 00:35:20,500
+نتغلب أكتر بالاسماء تبعتها، الآن بيضل عندى كل هدولة
+
+355
+00:35:20,500 --> 00:35:25,040
+موجودين يمكن ضلت عندي شغلة واحدة أخرى لو كانت هذه
+
+356
+00:35:25,040 --> 00:35:36,420
+unh2 unh c double bond o unh2، هذا مركب شوية إيش
+
+357
+00:35:36,420 --> 00:35:41,840
+ماله كبير لكن أنا المهم عندي فيه ان هذه ال unh2، كل
+
+358
+00:35:41,840 --> 00:35:46,700
+هدولة يعتبروا x واحدة، هتقول في تلتين unh2 في واحدة
+
+359
+00:35:46,700 --> 00:35:51,420
+هنا اقريبة على c double bond o، واحدة بعيدة، مين اللي
+
+360
+00:35:51,420 --> 00:35:55,140
+بتتفعل مع الالدهاد أو الـ Ketone؟ هذه البعيدة
+
+361
+00:35:55,140 --> 00:35:58,060
+وبناء على ذلك، لو هذا قلتلكوا فعلومة عن
+
+362
+00:35:58,060 --> 00:36:05,700
+الـcyclobentanone، كيف هنكتب الجواب؟ زي ما اتعودنا
+
+363
+00:36:05,700 --> 00:36:09,960
+تماما، نحط الـcyclobentane
+
+364
+00:36:09,960 --> 00:36:17,540
+والسيضة بالبند أو تصير سيضة بالبند and ونكمل
+
+365
+00:36:19,990 --> 00:36:26,670
+MHCW.O NH2 بيصير .. طب إيش اسم هذا، و إيش اسم هذا
+
+366
+00:36:26,670 --> 00:36:37,450
+هذا اسمه سيمي كربازايد، سيمي كربازايد، طب و الناتج
+
+367
+00:36:37,450 --> 00:36:43,690
+اللي بتطلع من السيمي كربازايد Semi-carbazone زي
+
+368
+00:36:43,690 --> 00:36:49,210
+هيدرازين هيدرازون Carbazide Carbazone، إذا هذا
+
+369
+00:36:49,210 --> 00:36:54,610
+المركب كاملا الان لو بدنا نسميه شو هنسميه؟
+
+370
+00:36:54,610 --> 00:37:00,450
+Cyclobentanone
+
+371
+00:37:00,450 --> 00:37:05,110
+Semi-carbazone
+
+372
+00:37:07,490 --> 00:37:17,290
+cyclobentanone-semicarbazone هذا
+
+373
+00:37:17,290 --> 00:37:29,310
+هو
+
+374
+00:37:29,310 --> 00:37:30,930
+ال slide الأخير
+
+375
+00:37:34,700 --> 00:37:41,500
+بتلخص لي كل الدارس انه ال amine اللي هو متصل في ال
+
+376
+00:37:41,500 --> 00:37:47,980
+NH2R بيعطي كعائلة عامة امين، ال hydroxylamine بيعطي
+
+377
+00:37:47,980 --> 00:37:54,160
+oxime ال semi carbazide بيعطي semi carbazone ال
+
+378
+00:37:54,160 --> 00:38:00,880
+hydrazines بيعطي hydrazones، واضح؟ مرة تانية نعيدهم
+
+379
+00:38:00,880 --> 00:38:08,150
+مع بعض ال hydrazine، والهيدروكس الأمين أكزيم، والسمي
+
+380
+00:38:08,150 --> 00:38:13,650
+كربازايد سيمي كربازون، والأمين اللي هي متصلة بR
+
+381
+00:38:13,650 --> 00:38:22,570
+امين امين، بس، واضح؟ لو نعطي مثال، ولا نقول الله
+
+382
+00:38:22,570 --> 00:38:27,630
+يعطيكوا العافية، بنعطي مثلين، بنعطي مثلين، و بنخلص
+
+383
+00:38:27,630 --> 00:38:33,870
+اليوم، إجاكم سؤال، أرسموا إيثانال أكزيم
+
+384
+00:38:35,520 --> 00:38:48,140
+وإجانا السؤال ارسمه داي إثل كيتون، فين الهيدرازون
+
+385
+00:38:48,140 --> 00:38:54,420
+يلا
+
+386
+00:38:54,420 --> 00:39:06,030
+نجلوني إيثانال، عارفين الإيثانال؟ اللي هو CHCH3
+
+387
+00:39:06,030 --> 00:39:11,410
+اللي هو ال Acetaldehyde، وهذه كانت C double bond O
+
+388
+00:39:11,410 --> 00:39:16,310
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+389
+00:39:16,310 --> 00:39:16,790
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+390
+00:39:16,790 --> 00:39:16,810
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+391
+00:39:16,810 --> 00:39:18,510
+ان او اتش ان او اتش ان او اتش ان او اتش
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..daad7ff8cbc5da3d47e2e9ddb2670ea5b55c11f3
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3413, "start": 19.47, "end": 34.13, "text": "بسم الله الرحمن الرحيم بنكمل اليوم في موضوع ال aldehydes و ال ketones و ربما كلكم الذاكرين أنه التفاعل الأساسي لل aldehydes و ال ketones كان", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 4724, 1863, 24793, 1211, 45595, 20498, 8978, 3714, 2407, 11242, 45367, 2423, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 4032, 12602, 3555, 15042, 28242, 24793, 32545, 995, 37983, 9957, 14739, 3224, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 24976, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 25961], "avg_logprob": -0.1489583266278108, "compression_ratio": 1.60431654676259, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 19.47, "end": 19.71, "word": "بسم", "probability": 0.919677734375}, {"start": 19.71, "end": 19.89, "word": " الله", "probability": 0.95703125}, {"start": 19.89, "end": 20.25, "word": " الرحمن", "probability": 0.9500325520833334}, {"start": 20.25, 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"probability": 0.854248046875}, {"start": 28.67, "end": 29.47, "word": " الذاكرين", "probability": 0.906982421875}, {"start": 29.47, "end": 30.17, "word": " أنه", "probability": 0.5709228515625}, {"start": 30.17, "end": 31.07, "word": " التفاعل", "probability": 0.9403076171875}, {"start": 31.07, "end": 32.05, "word": " الأساسي", "probability": 0.9530029296875}, {"start": 32.05, "end": 32.39, "word": " لل", "probability": 0.66357421875}, {"start": 32.39, "end": 32.95, "word": " aldehydes", "probability": 0.9410400390625}, {"start": 32.95, "end": 33.09, "word": " و", "probability": 0.982421875}, {"start": 33.09, "end": 33.17, "word": " ال", "probability": 0.72509765625}, {"start": 33.17, "end": 33.71, "word": " ketones", "probability": 0.929931640625}, {"start": 33.71, "end": 34.13, "word": " كان", "probability": 0.9931640625}], "temperature": 1.0}, {"id": 2, "seek": 4993, "start": 34.91, "end": 49.93, "text": "Heniocleophilic Addition أخدنا عدة أمثلة ع الموضوع إضافة الماء الكحول ال cyanide مثلا ال H- لعملية ال reduction", "tokens": [39, 268, 1004, 2160, 5317, 388, 299, 5349, 849, 5551, 9778, 3215, 8315, 6225, 41891, 5551, 2304, 12984, 37977, 6225, 9673, 2407, 11242, 45367, 11933, 11242, 31845, 3660, 9673, 16606, 33251, 5016, 12610, 2423, 47463, 482, 50113, 15040, 2423, 389, 12, 5296, 25957, 1211, 10632, 2423, 11004], "avg_logprob": -0.3164062487582366, "compression_ratio": 1.2058823529411764, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 34.91, "end": 36.15, "word": "Heniocleophilic", "probability": 0.6049630301339286}, {"start": 36.15, "end": 36.69, "word": " Addition", "probability": 0.6605224609375}, {"start": 36.69, "end": 40.89, "word": " أخدنا", "probability": 0.702850341796875}, {"start": 40.89, "end": 41.21, "word": " عدة", "probability": 0.91259765625}, {"start": 41.21, "end": 42.01, "word": " أمثلة", "probability": 0.9473876953125}, {"start": 42.01, "end": 42.75, "word": " ع", "probability": 0.1900634765625}, {"start": 42.75, "end": 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"text": "أتش ماينوس الان في عندنا اضافتين واحدة من هذول الاضافتين التفاعل مع green yard reagent واضح عادة هذا المتفاعل يمكن ماعندكم مش خبرة عنه بنتعرف عليه شو هو green yard reagent", "tokens": [10721, 2655, 8592, 19446, 9957, 41779, 2423, 7649, 8978, 43242, 8315, 1975, 11242, 31845, 2655, 9957, 36764, 24401, 3660, 9154, 8032, 8848, 12610, 2423, 46958, 31845, 2655, 9957, 16712, 5172, 995, 30241, 20449, 3092, 11682, 26949, 317, 4032, 46958, 5016, 6225, 18513, 3660, 23758, 9673, 2655, 5172, 995, 30241, 7251, 43020, 19446, 3615, 41260, 24793, 37893, 16490, 3555, 25720, 18871, 3224, 44945, 2655, 3615, 28480, 47356, 13412, 2407, 31439, 3092, 11682, 26949, 317], "avg_logprob": -0.33086993444610285, "compression_ratio": 1.6184971098265897, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 85.91, "end": 86.43, "word": "أتش", "probability": 0.5946451822916666}, {"start": 86.43, "end": 87.01, "word": " ماينوس", "probability": 0.7781575520833334}, {"start": 87.01, "end": 87.87, "word": 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green yard مع ال formaldehyde كوالي كحول إيش نوع هذا الكحول؟ primary alcohol طيب خليني أفعل ال green yard مع أي aldehyde تاني غير ال formaldehyde يعني acetaldehyde هذا, ibropenaldehyde, benzaldehyde طبعا هيحط برضه مجموعة", "tokens": [2407, 46958, 5016, 22807, 11933, 15730, 31439, 11331, 9566, 3714, 7435, 2304, 2407, 27884, 2423, 39184, 1030, 3495, 21323, 5296, 39319, 19913, 14407, 6024, 48506, 2423, 3092, 11682, 20449, 2423, 9860, 1479, 3495, 1479, 9122, 2407, 6027, 1829, 9122, 5016, 12610, 11933, 1829, 8592, 8717, 45367, 23758, 33251, 5016, 12610, 22807, 6194, 7658, 23032, 1829, 3555, 16490, 1211, 9957, 1829, 5551, 5172, 30241, 2423, 3092, 11682, 20449, 36632, 16798, 68, 3495, 1479, 6055, 7649, 1829, 32771, 13546, 2423, 9860, 1479, 3495, 1479, 37495, 22653, 37848, 304, 1479, 3495, 1479, 23758, 11, 39073, 1513, 268, 304, 1479, 3495, 1479, 11, 44335, 304, 1479, 3495, 1479, 23032, 3555, 3615, 995, 39896, 5016, 9566, 4724, 43042, 3224, 3714, 7435, 2304, 2407, 27884], "avg_logprob": 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{"start": 569.32, "end": 570.16, "word": " طيب", "probability": 0.8743489583333334}, {"start": 570.16, "end": 570.78, "word": " خليني", "probability": 0.82421875}, {"start": 570.78, "end": 571.28, "word": " أفعل", "probability": 0.923828125}, {"start": 571.28, "end": 571.5, "word": " ال", "probability": 0.8916015625}, {"start": 571.5, "end": 571.78, "word": " green", "probability": 0.9072265625}, {"start": 571.78, "end": 572.2, "word": " yard", "probability": 0.8857421875}, {"start": 572.2, "end": 572.66, "word": " مع", "probability": 0.978515625}, {"start": 572.66, "end": 572.88, "word": " أي", "probability": 0.9716796875}, {"start": 572.88, "end": 573.96, "word": " aldehyde", "probability": 0.754791259765625}, {"start": 573.96, "end": 574.82, "word": " تاني", "probability": 0.9798177083333334}, {"start": 574.82, "end": 576.32, "word": " غير", "probability": 0.83203125}, {"start": 576.32, "end": 576.74, "word": " ال", "probability": 0.90625}, {"start": 576.74, "end": 578.0, "word": " 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بالنسبة لنا بيمثل طريقة لتحضير كل أنواع الكحولات يعني لو بدى primary alcohol بدى أنطلق من ال formaldehyde تمام؟ لو بدى secondary alcohol بدى أنطلق من أي aldehyde تاني غير", "tokens": [28814, 8848, 1863, 6024, 48506, 20328, 2288, 8315, 6156, 995, 16095, 9957, 32239, 8592, 3092, 2109, 9461, 3714, 2407, 11242, 45367, 3714, 16095, 5296, 33456, 31439, 20666, 1863, 35457, 3660, 5296, 8315, 4724, 32640, 12984, 1211, 23032, 16572, 28671, 5296, 2655, 5016, 11242, 13546, 28242, 14739, 14407, 3615, 33251, 5016, 12610, 9307, 37495, 22653, 45164, 47525, 7578, 6194, 7658, 47525, 7578, 14739, 9566, 1211, 4587, 9154, 2423, 9860, 1479, 3495, 1479, 46811, 10943, 22807, 45164, 47525, 7578, 11396, 7658, 47525, 7578, 14739, 9566, 1211, 4587, 9154, 36632, 16798, 68, 3495, 1479, 6055, 7649, 1829, 32771, 13546], "avg_logprob": -0.18411726804123713, "compression_ratio": 1.6325581395348838, "no_speech_prob": 0.0, "words": [{"start": 612.83, "end": 613.45, "word": "إذن", "probability": 0.5449625651041666}, 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"probability": 0.258544921875}, {"start": 852.84, "end": 853.96, "word": " MgBr", "probability": 0.512939453125}, {"start": 853.96, "end": 855.62, "word": " MgBr", "probability": 0.8255208333333334}, {"start": 855.62, "end": 856.76, "word": " و", "probability": 0.56689453125}, {"start": 856.76, "end": 857.04, "word": " هذه", "probability": 0.55908203125}, {"start": 857.04, "end": 857.24, "word": " إيش", "probability": 0.9749348958333334}, {"start": 857.24, "end": 857.82, "word": " ناقصها", "probability": 0.99541015625}, {"start": 857.82, "end": 859.38, "word": " هاخد", "probability": 0.6034342447916666}, {"start": 859.38, "end": 861.94, "word": " CH3", "probability": 0.7017822265625}, {"start": 861.94, "end": 864.6, "word": " MgBr", "probability": 0.9519856770833334}], "temperature": 1.0}, {"id": 37, "seek": 87956, "start": 867.78, "end": 879.56, "text": "واضح؟ مجمعتين بدهم يكونوا على الكيتون والتالتة بدي اجيبها من ال green yard و اعملوا اي خلطة انتوا بتكونوا معاها واضحة في هذه النقطة؟", "tokens": [2407, 46958, 5016, 22807, 3714, 7435, 2304, 34268, 9957, 47525, 16095, 7251, 30544, 14407, 15844, 33251, 36081, 11536, 16070, 2655, 6027, 2655, 3660, 4724, 16254, 1975, 7435, 1829, 3555, 11296, 9154, 2423, 3092, 11682, 4032, 1975, 25957, 1211, 14407, 1975, 1829, 16490, 1211, 9566, 3660, 16472, 2655, 14407, 39894, 30544, 14407, 20449, 995, 11296, 4032, 46958, 5016, 3660, 8978, 29538, 28239, 47432, 3660, 22807], "avg_logprob": -0.2966346153846154, "compression_ratio": 1.5364238410596027, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 867.7800000000001, "end": 868.5600000000001, "word": "واضح؟", "probability": 0.812255859375}, {"start": 868.5600000000001, "end": 869.34, "word": " مجمعتين", "probability": 0.86484375}, {"start": 869.34, "end": 870.28, "word": " بدهم", "probability": 0.5537109375}, {"start": 870.28, "end": 870.66, "word": " يكونوا", "probability": 0.9716796875}, {"start": 870.66, "end": 870.88, "word": " على", "probability": 0.8388671875}, {"start": 870.88, "end": 871.46, "word": " الكيتون", "probability": 0.6914876302083334}, {"start": 871.46, "end": 872.0, "word": " والتالتة", "probability": 0.8630859375}, {"start": 872.0, "end": 872.2, "word": " بدي", "probability": 0.46087646484375}, {"start": 872.2, "end": 872.6, "word": " اجيبها", "probability": 0.87783203125}, {"start": 872.6, "end": 872.76, "word": " من", "probability": 0.98779296875}, {"start": 872.76, "end": 872.88, "word": " ال", "probability": 0.8203125}, {"start": 872.88, "end": 873.12, "word": " green", "probability": 0.34619140625}, {"start": 873.12, "end": 873.46, "word": " yard", "probability": 0.77685546875}, {"start": 873.46, "end": 873.9, "word": " و", "probability": 0.484619140625}, {"start": 873.9, "end": 874.38, "word": " اعملوا", "probability": 0.9228515625}, {"start": 874.38, "end": 874.68, "word": " اي", "probability": 0.751220703125}, {"start": 874.68, "end": 875.38, "word": " خلطة", "probability": 0.9901123046875}, {"start": 875.38, "end": 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"probability": 0.75244140625}, {"start": 890.55, "end": 890.75, "word": " grill", "probability": 0.37939453125}, {"start": 890.75, "end": 891.03, "word": " yard", "probability": 0.362060546875}, {"start": 891.03, "end": 891.15, "word": " و", "probability": 0.4931640625}, {"start": 891.15, "end": 891.67, "word": " الباقي", "probability": 0.85009765625}, {"start": 891.67, "end": 892.51, "word": " بيكون", "probability": 0.6810709635416666}, {"start": 892.51, "end": 893.91, "word": " جزء", "probability": 0.8180338541666666}, {"start": 893.91, "end": 894.47, "word": " ال", "probability": 0.80810546875}, {"start": 894.47, "end": 895.23, "word": " aldehyde", "probability": 0.75018310546875}, {"start": 895.23, "end": 895.43, "word": " او", "probability": 0.86376953125}, {"start": 895.43, "end": 895.61, "word": " ال", "probability": 0.81884765625}, {"start": 895.61, "end": 896.19, "word": " ketone", "probability": 0.847900390625}, {"start": 896.19, "end": 896.87, "word": " اللي", "probability": 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"probability": 0.74072265625}, {"start": 927.2, "end": 927.32, "word": " اذا", "probability": 0.7349853515625}, {"start": 927.32, "end": 927.92, "word": " استعملنا", "probability": 0.955078125}, {"start": 927.92, "end": 928.22, "word": " عامل", "probability": 0.9895833333333334}, {"start": 928.22, "end": 928.72, "word": " مؤكسد", "probability": 0.88056640625}, {"start": 928.72, "end": 928.96, "word": " قوي", "probability": 0.9111328125}, {"start": 928.96, "end": 929.5, "word": " الالدهيد", "probability": 0.672314453125}, {"start": 929.5, "end": 929.68, "word": " شو", "probability": 0.9033203125}, {"start": 929.68, "end": 930.62, "word": " بيصير؟", "probability": 0.834814453125}, {"start": 930.62, "end": 931.06, "word": " acid", "probability": 0.57763671875}, {"start": 931.06, "end": 931.8, "word": " خلاص", "probability": 0.9510091145833334}, {"start": 931.8, "end": 932.26, "word": " اذا", "probability": 0.69091796875}, {"start": 932.26, "end": 933.2, "word": " الجزء", "probability": 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"no_speech_prob": 0.0, "words": [{"start": 936.76, "end": 936.96, "word": "to", "probability": 0.2442626953125}, {"start": 936.96, "end": 937.52, "word": " acids", "probability": 0.705078125}, {"start": 937.52, "end": 938.74, "word": " مرت", "probability": 0.782958984375}, {"start": 938.74, "end": 939.08, "word": " علينا", "probability": 0.951904296875}, {"start": 939.08, "end": 939.18, "word": " في", "probability": 0.84326171875}, {"start": 939.18, "end": 939.44, "word": " جزء", "probability": 0.9754231770833334}, {"start": 939.44, "end": 939.54, "word": " ال", "probability": 0.80517578125}, {"start": 939.54, "end": 939.88, "word": " alcohol", "probability": 0.54931640625}, {"start": 939.88, "end": 940.26, "word": " ولا", "probability": 0.6669921875}, {"start": 940.26, "end": 940.82, "word": " لأ؟", "probability": 0.8396809895833334}], "temperature": 1.0}, {"id": 41, "seek": 96721, "start": 941.59, "end": 967.21, "text": "أه كنا نقول الكحول بيصير ال الديهيد و ال الديهيد أسد ال الديهيد أسد هو تفاعل لل الديهيد و الكيتون صارنا عارفينه طيب ال secondary alcohol كانوا يتأكسدوا لإيش لكيتون ال كيتون بتتأكسد أكسدة إضافية لأ إذا هاي الموضوع أكسدت ال الديهيد و الكيتون ان ال الديهيد بيصيروا أسد و الكيتون بتأكسدوش خلصنا", "tokens": [10721, 3224, 9122, 8315, 8717, 39648, 33251, 5016, 12610, 4724, 1829, 9381, 13546, 2423, 2423, 16254, 3224, 25708, 4032, 2423, 2423, 16254, 3224, 25708, 5551, 3794, 3215, 2423, 2423, 16254, 3224, 25708, 5551, 3794, 3215, 31439, 6055, 5172, 995, 30241, 24976, 2423, 16254, 3224, 25708, 4032, 33251, 36081, 11536, 20328, 9640, 8315, 6225, 9640, 5172, 9957, 3224, 23032, 1829, 3555, 2423, 11396, 7658, 25961, 14407, 7251, 2655, 10721, 4117, 3794, 3215, 14407, 5296, 28814, 1829, 8592, 5296, 4117, 36081, 11536, 2423, 9122, 36081, 11536, 39894, 2655, 10721, 4117, 3794, 3215, 5551, 4117, 3794, 41891, 11933, 11242, 31845, 10632, 5296, 10721, 11933, 15730, 8032, 47302, 9673, 2407, 11242, 45367, 5551, 4117, 3794, 3215, 2655, 2423, 2423, 16254, 3224, 25708, 4032, 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Cyclobentanone Semi-carbazone", "tokens": [50, 13372, 12, 6166, 65, 921, 546, 30767, 1829, 8032, 25708, 2288, 31377, 9957, 8032, 25708, 2288, 31377, 11536, 2741, 65, 921, 482, 2741, 65, 921, 546, 11933, 15730, 23758, 9673, 31747, 3555, 9122, 10943, 15040, 16247, 1863, 45164, 47525, 8315, 8717, 38251, 1829, 3224, 13412, 2407, 8032, 1863, 38251, 1829, 3224, 22807, 10295, 66, 752, 65, 317, 282, 546, 318, 13372, 12, 6166, 65, 921, 546], "avg_logprob": -0.2879135994350209, "compression_ratio": 1.3732394366197183, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2200.31, "end": 2200.91, "word": "Semi", "probability": 0.57586669921875}, {"start": 2200.91, "end": 2202.59, "word": "-carbazone", "probability": 0.643505859375}, {"start": 2202.59, "end": 2203.69, "word": " زي", "probability": 0.892822265625}, {"start": 2203.69, "end": 2204.73, "word": " هيدرازين", "probability": 0.86787109375}, {"start": 2204.73, "end": 2206.19, "word": " هيدرازون", "probability": 0.9013671875}, {"start": 2206.19, "end": 2207.45, "word": " Carbazide", "probability": 0.72418212890625}, {"start": 2207.45, "end": 2208.29, "word": " Carbazone", "probability": 0.83819580078125}, {"start": 2208.29, "end": 2208.83, "word": " إذا", "probability": 0.692626953125}, {"start": 2208.83, "end": 2209.21, "word": " هذا", "probability": 0.95458984375}, {"start": 2209.21, "end": 2209.95, "word": " المركب", "probability": 0.9093424479166666}, {"start": 2209.95, "end": 2210.65, "word": " كاملا", "probability": 0.8904622395833334}, {"start": 2210.65, "end": 2211.13, "word": " الأن", "probability": 0.60015869140625}, {"start": 2211.13, "end": 2211.29, "word": " لو", "probability": 0.9677734375}, {"start": 2211.29, "end": 2211.57, "word": " بدنا", "probability": 0.974365234375}, {"start": 2211.57, "end": 2212.09, "word": " نسميه", "probability": 0.990966796875}, {"start": 2212.09, "end": 2212.25, "word": " شو", "probability": 0.767333984375}, {"start": 2212.25, "end": 2214.61, "word": " هنسميه؟", "probability": 0.8191731770833334}, {"start": 2214.61, "end": 2220.45, "word": " Cyclobentanone", "probability": 0.6683872767857143}, {"start": 2220.45, "end": 2222.51, "word": " Semi", "probability": 0.56036376953125}, {"start": 2222.51, "end": 2225.11, "word": "-carbazone", "probability": 0.90556640625}], "temperature": 1.0}, {"id": 90, "seek": 225092, "start": 2227.49, "end": 2250.93, "text": "cyclobentanone-semicarbazone هذا هو ال slide الأخير", "tokens": [1344, 3474, 996, 317, 282, 546, 12, 19872, 7953, 65, 921, 546, 23758, 31439, 2423, 4137, 16247, 9778, 13546], "avg_logprob": -0.4980468720197678, "compression_ratio": 0.9411764705882353, "no_speech_prob": 0.0, "words": [{"start": 2227.49, "end": 2228.89, "word": "cyclobentanone", "probability": 0.6944986979166666}, {"start": 2228.89, "end": 2230.29, "word": "-semicarbazone", "probability": 0.7027180989583334}, {"start": 2230.29, "end": 2237.29, "word": " هذا", "probability": 0.2391357421875}, {"start": 2237.29, "end": 2249.31, 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{"start": 2267.98, "end": 2268.96, "word": " oxime", "probability": 0.4710693359375}, {"start": 2268.96, "end": 2269.58, "word": " ال", "probability": 0.6298828125}, {"start": 2269.58, "end": 2270.44, "word": " semi", "probability": 0.6416015625}, {"start": 2270.44, "end": 2271.26, "word": " carbazide", "probability": 0.7403971354166666}, {"start": 2271.26, "end": 2271.8, "word": " بيعطي", "probability": 0.982666015625}, {"start": 2271.8, "end": 2272.24, "word": " semi", "probability": 0.8251953125}, {"start": 2272.24, "end": 2273.76, "word": " carbazone", "probability": 0.8551432291666666}, {"start": 2273.76, "end": 2274.16, "word": " ال", "probability": 0.98095703125}, {"start": 2274.16, "end": 2275.1, "word": " hydrazines", "probability": 0.6344401041666666}, {"start": 2275.1, "end": 2276.28, "word": " بيعطي", "probability": 0.949462890625}, {"start": 2276.28, "end": 2278.22, "word": " hydrazones", "probability": 0.7740885416666666}, {"start": 2278.22, "end": 2279.8, "word": " واضح؟", "probability": 0.77960205078125}, {"start": 2279.8, "end": 2280.2, "word": " مرة", "probability": 0.961669921875}, {"start": 2280.2, "end": 2280.5, "word": " تانية", "probability": 0.951171875}, {"start": 2280.5, "end": 2280.88, "word": " نعيدهم", "probability": 0.816650390625}, {"start": 2280.88, "end": 2281.04, "word": " مع", "probability": 0.99169921875}, {"start": 2281.04, "end": 2281.48, "word": " بعض", "probability": 0.99365234375}, {"start": 2281.48, "end": 2282.16, "word": " ال", "probability": 0.96533203125}, {"start": 2282.16, "end": 2283.02, "word": " hydrazine", "probability": 0.7677408854166666}], "temperature": 1.0}, {"id": 92, "seek": 231387, "start": 2284.69, "end": 2313.87, "text": "والهيدروكس الأمين أكزيم والسمي كربازايد سيمي كربازون والأمين اللي هي متصلة بR امين امين بس واضح لو نعطي مثال ولا نقول الله يعطيكوا العافية بنعطي مثلين بنعطي مثلين و بنخلص اليوم إجاكم سؤال أرسموا إيثانال أكزيم", "tokens": [2407, 6027, 3224, 25708, 2288, 2407, 4117, 3794, 16247, 2304, 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إثل كيتون فين الهيدرازون يلا نجلوني إيثانال عارفين الإيثانال؟", "tokens": [2407, 28814, 7435, 7649, 995, 21136, 33604, 6027, 1975, 2288, 38251, 3224, 11778, 47302, 11933, 12984, 1211, 9122, 36081, 11536, 8978, 1863, 2423, 3224, 25708, 2288, 31377, 11536, 7251, 15040, 8717, 7435, 1211, 11536, 1829, 11933, 1829, 12984, 7649, 6027, 6225, 9640, 5172, 9957, 33688, 1829, 12984, 7649, 6027, 22807], "avg_logprob": -0.3069853081422694, "compression_ratio": 1.5339805825242718, "no_speech_prob": 0.0, "words": [{"start": 2315.52, "end": 2316.38, "word": "وإجانا", "probability": 0.556640625}, {"start": 2316.38, "end": 2316.9, "word": " السؤال", "probability": 0.9187825520833334}, {"start": 2316.9, "end": 2318.24, "word": " ارسمه", "probability": 0.8052978515625}, {"start": 2318.24, "end": 2321.22, "word": " داي", "probability": 0.383575439453125}, {"start": 2321.22, "end": 2321.92, "word": " إثل", "probability": 0.6016438802083334}, {"start": 2321.92, "end": 2324.44, "word": " كيتون", 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"end": 2416.11, "word": " بهيك", "probability": 0.6512858072916666}, {"start": 2416.11, "end": 2417.39, "word": " بننتهي", "probability": 0.9332275390625}, {"start": 2417.39, "end": 2417.79, "word": " من", "probability": 0.990234375}, {"start": 2417.79, "end": 2418.35, "word": " درس", "probability": 0.9884440104166666}, {"start": 2418.35, "end": 2418.55, "word": " ال", "probability": 0.94970703125}, {"start": 2418.55, "end": 2419.41, "word": " aldehydes", "probability": 0.7137451171875}, {"start": 2419.41, "end": 2419.87, "word": " و", "probability": 0.88916015625}, {"start": 2419.87, "end": 2420.01, "word": " ال", "probability": 0.87353515625}, {"start": 2420.01, "end": 2420.55, "word": " ketones", "probability": 0.823974609375}, {"start": 2420.55, "end": 2420.69, "word": " و", "probability": 0.95556640625}, {"start": 2420.69, "end": 2420.79, "word": " ان", "probability": 0.82373046875}, {"start": 2420.79, "end": 2421.01, "word": " شاء", "probability": 0.990478515625}, {"start": 2421.01, "end": 2421.33, "word": " الله", "probability": 0.9560546875}, {"start": 2421.33, "end": 2422.19, "word": " يوم", "probability": 0.993408203125}, {"start": 2422.19, "end": 2422.93, "word": " السبت", "probability": 0.9558919270833334}], "temperature": 1.0}, {"id": 97, "seek": 244798, "start": 2423.74, "end": 2447.98, "text": "في عندنا مراجعة للامتحانات النصفية كونوا مجاهزينها او ساحبينها ع ورق و حلينها احنا بنحلها انا قدامكم و بنناقش اي مشكلة فيها و بعد هيك ان شاء الله بنبدأ في موضوع الأحماض و مستقبلها و الامتحان لنهاية الفصل السادس حكينا بوضوح الامتحان لنهاية الفصل السادس اذا سمحت", "tokens": [41185, 43242, 8315, 3714, 2288, 26108, 27884, 24976, 10943, 2655, 5016, 7649, 9307, 28239, 9381, 5172, 10632, 9122, 11536, 14407, 3714, 7435, 40294, 11622, 9957, 11296, 1975, 2407, 8608, 39319, 3555, 9957, 11296, 6225, 4032, 2288, 4587, 4032, 11331, 1211, 9957, 11296, 1975, 5016, 8315, 44945, 5016, 1211, 11296, 1975, 8315, 12174, 3215, 10943, 24793, 4032, 44945, 8315, 4587, 8592, 1975, 1829, 37893, 28820, 3660, 8978, 11296, 4032, 39182, 39896, 4117, 16472, 13412, 16606, 21984, 44945, 44510, 10721, 8978, 3714, 2407, 11242, 45367, 16247, 35571, 46958, 4032, 3714, 14851, 4587, 36150, 11296, 4032, 2423, 10943, 2655, 5016, 7649, 5296, 1863, 11296, 10632, 27188, 36520, 21136, 18513, 3794, 11331, 4117, 1829, 8315, 4724, 2407, 11242, 2407, 5016, 2423, 10943, 2655, 5016, 7649, 5296, 1863, 11296, 10632, 27188, 36520, 21136, 18513, 3794, 1975, 15730, 8608, 2304, 33753], "avg_logprob": -0.13740809360409484, "compression_ratio": 2.0973451327433628, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 2423.74, "end": 2423.98, "word": "في", "probability": 0.67724609375}, {"start": 2423.98, "end": 2424.38, "word": " عندنا", "probability": 0.982666015625}, {"start": 2424.38, "end": 2425.24, "word": " مراجعة", "probability": 0.960205078125}, {"start": 2425.24, "end": 2426.46, "word": " للامتحانات", "probability": 0.8868408203125}, {"start": 2426.46, "end": 2427.06, "word": " النصفية", "probability": 0.975341796875}, {"start": 2427.06, "end": 2427.46, "word": " كونوا", "probability": 0.80224609375}, {"start": 2427.46, "end": 2428.46, "word": " مجاهزينها", "probability": 0.8374837239583334}, {"start": 2428.46, "end": 2428.72, "word": " او", "probability": 0.708984375}, {"start": 2428.72, "end": 2429.36, "word": " ساحبينها", "probability": 0.844921875}, {"start": 2429.36, "end": 2429.46, "word": " ع", "probability": 0.8564453125}, {"start": 2429.46, "end": 2429.84, "word": " ورق", "probability": 0.8876953125}, {"start": 2429.84, "end": 2429.96, "word": " و", "probability": 0.9794921875}, {"start": 2429.96, "end": 2430.68, "word": " حلينها", "probability": 0.7738037109375}, {"start": 2430.68, "end": 2431.42, "word": " احنا", "probability": 0.9305013020833334}, {"start": 2431.42, "end": 2431.88, "word": " بنحلها", "probability": 0.9656982421875}, {"start": 2431.88, "end": 2432.14, "word": " انا", "probability": 0.65966796875}, {"start": 2432.14, "end": 2432.82, "word": " قدامكم", "probability": 0.976318359375}, {"start": 2432.82, "end": 2432.98, "word": " و", "probability": 0.90380859375}, {"start": 2432.98, "end": 2433.52, "word": " بنناقش", "probability": 0.96630859375}, {"start": 2433.52, "end": 2433.74, "word": " اي", "probability": 0.918212890625}, {"start": 2433.74, "end": 2434.22, "word": " مشكلة", "probability": 0.97802734375}, {"start": 2434.22, "end": 2434.62, "word": " فيها", "probability": 0.98974609375}, {"start": 2434.62, "end": 2435.4, "word": " و", "probability": 0.73388671875}, {"start": 2435.4, "end": 2435.7, "word": " بعد", "probability": 0.92236328125}, {"start": 2435.7, "end": 2436.0, "word": " هيك", "probability": 0.692626953125}, {"start": 2436.0, "end": 2436.14, "word": " ان", "probability": 0.861328125}, {"start": 2436.14, "end": 2436.36, "word": " شاء", "probability": 0.979248046875}, {"start": 2436.36, "end": 2436.48, "word": " الله", "probability": 0.94580078125}, {"start": 2436.48, "end": 2436.98, "word": " بنبدأ", "probability": 0.9777018229166666}, {"start": 2436.98, "end": 2437.14, "word": " في", "probability": 0.900390625}, {"start": 2437.14, "end": 2437.52, "word": " موضوع", "probability": 0.9945068359375}, {"start": 2437.52, "end": 2438.16, "word": " الأحماض", "probability": 0.7822265625}, {"start": 2438.16, "end": 2438.3, "word": " و", "probability": 0.994140625}, {"start": 2438.3, "end": 2439.22, "word": " مستقبلها", "probability": 0.62216796875}, {"start": 2439.22, "end": 2439.38, "word": " و", "probability": 0.5419921875}, {"start": 2439.38, "end": 2440.12, "word": " الامتحان", "probability": 0.9578125}, {"start": 2440.12, "end": 2440.8, "word": " لنهاية", "probability": 0.957763671875}, {"start": 2440.8, "end": 2441.3, "word": " الفصل", "probability": 0.940673828125}, {"start": 2441.3, "end": 2442.02, "word": " السادس", "probability": 0.9599609375}, {"start": 2442.02, "end": 2442.52, "word": " حكينا", "probability": 0.95458984375}, {"start": 2442.52, "end": 2443.16, "word": " بوضوح", "probability": 0.971484375}, {"start": 2443.16, "end": 2445.26, "word": " الامتحان", "probability": 0.9583984375}, {"start": 2445.26, "end": 2445.88, "word": " لنهاية", "probability": 0.971923828125}, {"start": 2445.88, "end": 2446.44, "word": " الفصل", "probability": 0.98681640625}, {"start": 2446.44, "end": 2447.28, "word": " السادس", "probability": 0.9807942708333334}, {"start": 2447.28, "end": 2447.56, "word": " اذا", "probability": 0.693115234375}, {"start": 2447.56, "end": 2447.98, "word": " سمحت", "probability": 0.9532877604166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2449.61225, "duration_after_vad": 2332.394374999992}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4adc0e525ea98578e86ba889562aaaf66dd92f29
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.srt
@@ -0,0 +1,1652 @@
+1
+00:00:19,470 --> 00:00:24,710
+بسم الله الرحمن الرحيم بنكمل اليوم في موضوع ال
+
+2
+00:00:24,710 --> 00:00:30,170
+aldehydes و ال ketones و ربما كلكم الذاكرين أنه
+
+3
+00:00:30,170 --> 00:00:34,130
+التفاعل الأساسي لل aldehydes و ال ketones كان
+
+4
+00:00:34,910 --> 00:00:40,890
+Heniocleophilic Addition أخدنا
+
+5
+00:00:40,890 --> 00:00:47,150
+عدة أمثلة ع الموضوع إضافة الماء الكحول ال cyanide
+
+6
+00:00:47,150 --> 00:00:53,200
+مثلا ال H- لعملية ال reductionواليوم هناخد بشكل
+
+7
+00:00:53,200 --> 00:00:58,440
+أساسي كمان مثلين على هذا الموضوع يعني للناس اللي
+
+8
+00:00:58,440 --> 00:01:03,180
+بيحبوا الصور الكلية وبيفهموا الموضوع بالصورة
+
+9
+00:01:03,180 --> 00:01:06,980
+الكلية مش بالصورة الجزائية أو الجزئية خلينا نقول
+
+10
+00:01:06,980 --> 00:01:13,120
+كأنه كل تفاعلات الكحولات لو بدكم تسجلوها إضافة ما
+
+11
+00:01:14,130 --> 00:01:21,730
+بحط OH كحول بحط Oethyl أو OR in general فعلا ال
+
+12
+00:01:21,730 --> 00:01:27,870
+cyanide بحط CN minus ال hydride بحطأتش ماينوس الان
+
+13
+00:01:27,870 --> 00:01:33,370
+في عندنا اضافتين واحدة من هذول الاضافتين التفاعل
+
+14
+00:01:33,370 --> 00:01:39,450
+مع green yard reagent واضح عادة هذا المتفاعل يمكن
+
+15
+00:01:39,450 --> 00:01:43,270
+ماعندكم مش خبرة عنه بنتعرف عليه شو هو green yard
+
+16
+00:01:43,270 --> 00:01:47,020
+reagentإذا بتلاحظوا reaction of aldehydes and
+
+17
+00:01:47,020 --> 00:01:51,340
+ketones with Grignard reagent ربما تقرأوا الكلمة
+
+18
+00:01:51,340 --> 00:01:57,260
+كأنها Grignard لكن عادة احنا بنقولها ايش Grignard
+
+19
+00:01:57,260 --> 00:02:06,290
+reagent هذا متفاعل اللي عمله لأنه مهم كتيراخد عليه
+
+20
+00:02:06,290 --> 00:02:13,430
+جائزة نوبل في الكيميا عشانك جربه ممكن تفهمه جيدا و
+
+21
+00:02:13,430 --> 00:02:19,730
+الكلام مش جديد يعني في ال 1911 تقريبا قبل أكثر من
+
+22
+00:02:20,620 --> 00:02:25,320
+ميت سنة بتعرف جائزة نوبل بدت من ال 1900 تقريبا
+
+23
+00:02:25,320 --> 00:02:31,620
+فبال 1911 أخد عليه جائزة نوبل ايش هو ال green yard
+
+24
+00:02:31,620 --> 00:02:38,120
+reagent بالظبط الان لو أخدنا احنا اي مركب متصل
+
+25
+00:02:38,120 --> 00:02:45,980
+بهالوجل RX او ARX بتحبوا تاخدوهم بالصيغة العامة
+
+26
+00:02:45,980 --> 00:02:54,100
+بمشي الحال يعني بقول RX اوARX بتحبوا تاخدوهم بمثال
+
+27
+00:02:54,100 --> 00:03:00,600
+بيمشي الحال برضه يعني مثلا نقول CH3CH2CL
+
+28
+00:03:00,600 --> 00:03:06,580
+هايه بمثال واضح CH3CH2PR
+
+29
+00:03:06,580 --> 00:03:13,120
+هذا RX ولا لأ؟ RX ولو بدي انا ARX مثلا اخد فنل
+
+30
+00:03:13,120 --> 00:03:24,730
+بنزينة فنل PR او فنل CLالان لو اخدنا RX او ARX
+
+31
+00:03:24,730 --> 00:03:29,590
+وفعلناهم مع بودرة المغنيسيوم في ظروف جافة في
+
+32
+00:03:29,590 --> 00:03:33,810
+solvent ال ether يعني هدولا بنافعلهم مع ايش؟
+
+33
+00:03:33,810 --> 00:03:40,970
+مغنيسيوم MG و عادة بستعملوا solvent ether والاصل
+
+34
+00:03:40,970 --> 00:03:47,370
+يكون dry ether واضح؟ الان هذا بيتفعل بيعطينا الشكل
+
+35
+00:03:47,370 --> 00:03:59,110
+القاتل بيعطيناCH3 CH2 CH3
+
+36
+00:03:59,110 --> 00:03:59,410
+CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH3 CH3 CH3 CH3
+
+37
+00:03:59,410 --> 00:04:00,690
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+38
+00:04:00,690 --> 00:04:02,730
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+39
+00:04:02,730 --> 00:04:03,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+40
+00:04:03,130 --> 00:04:03,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+41
+00:04:03,130 --> 00:04:03,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+42
+00:04:03,130 --> 00:04:03,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+43
+00:04:03,130 --> 00:04:07,610
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+44
+00:04:07,610 --> 00:04:11,670
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+45
+00:04:11,670 --> 00:04:16,080
+CH3 CH3greenyard reagent الان لو كنت بدى اسميه
+
+46
+00:04:16,080 --> 00:04:20,860
+بمشي فيه من الشمال لليمين هذه المجموعة شو هي ايه
+
+47
+00:04:20,860 --> 00:04:29,040
+فين ماجنيسيوم برومايو هذا فنل ماجنيسيوم برومايو
+
+48
+00:04:29,040 --> 00:04:35,000
+ومثلها مثيل وبروبيل وايزوبروبيل وهكذا هذا هو ال
+
+49
+00:04:35,000 --> 00:04:39,320
+greenyard reagent عرفنا بالظبط شو هو الان هذا ال
+
+50
+00:04:39,320 --> 00:04:45,030
+greenyard reagentماذا هو الفائدة التي جعل الناس
+
+51
+00:04:45,030 --> 00:04:52,270
+يعطوه جائزة نوبل في الكيميا للعالم هذا؟ ال
+
+52
+00:04:52,270 --> 00:04:57,070
+greenery agent هو عبارة عن carbon nucleophile يعني
+
+53
+00:04:57,070 --> 00:05:02,450
+انا لما بدي اتعامل معه بدي اخده بهذا الشكل أنسى ال
+
+54
+00:05:02,450 --> 00:05:03,230
+MgBr
+
+55
+00:05:05,600 --> 00:05:09,900
+بدي أخده بهذا الشكل الان هو بهذا الشكل صار بيمثل
+
+56
+00:05:09,900 --> 00:05:17,120
+لي CH3 CH2 وزوج إلكترونات على الكاربون فهو carbon
+
+57
+00:05:17,120 --> 00:05:22,140
+nucleophile أو أخده بهذا الشكليعني هو صح موجود
+
+58
+00:05:22,140 --> 00:05:26,820
+كمركب لكن في لحظة التفاعل يعني تخيلوا بالظبط a
+
+59
+00:05:26,820 --> 00:05:31,400
+green yard reagent كأنه هذا القلم الآن هذا الجزء
+
+60
+00:05:31,400 --> 00:05:35,360
+اللي فيه ال nucleophile هو اللي بيجي يتفاعل و يعمل
+
+61
+00:05:35,360 --> 00:05:41,160
+addition و ال MgBr ما انه ملها واضح؟فكأنه يمثل هذا
+
+62
+00:05:41,160 --> 00:05:43,900
+القلم مع الغطاية، الان انا مهتم بالغطاية ولا
+
+63
+00:05:43,900 --> 00:05:48,020
+بالقلم؟ الان انا من ال green yardary agent بإيش
+
+64
+00:05:48,020 --> 00:05:53,820
+مهتم؟ بال R مع إلكتروناتها أو بال AR مع
+
+65
+00:05:53,820 --> 00:05:59,420
+إلكتروناتهاواضحة الفكرة؟ الان لما بدي اجي اقول ان
+
+66
+00:05:59,420 --> 00:06:05,240
+هذا ال R مع إلكتروناتها او ال AR مع إلكتروناتها
+
+67
+00:06:05,240 --> 00:06:08,960
+بدها تيجي تتفاعل مع الديهيد او الكيتون هي أصبحت
+
+68
+00:06:08,960 --> 00:06:14,800
+نيوكليوفاين الان كيف بتيجي و اين بتيجي تهاجم؟ هاي
+
+69
+00:06:14,800 --> 00:06:22,590
+ال R بدها تهاجم هنا وهذه ايش بدها تصير؟OH في
+
+70
+00:06:22,590 --> 00:06:26,770
+النهاية طبعا هو هنا كتبلكوا التفاعل بالتفصيل ان
+
+71
+00:06:26,770 --> 00:06:31,290
+اول ما بتهاجم هنا بتصير OMGPR بعدين بنضيف عليه
+
+72
+00:06:31,290 --> 00:06:35,990
+نقطة ميه و حامض فبتصفى OH الان هي نتيجة نهائية
+
+73
+00:06:35,990 --> 00:06:40,130
+يعني هذه الشغل تفصيل جوا التفاعل احنا مش مهتمين
+
+74
+00:06:40,130 --> 00:06:43,410
+فيها بدنا في النهاية نتيجة نهائية متذكرين المرة
+
+75
+00:06:43,410 --> 00:06:48,810
+الماضية لما كنا نقولكم كل CW bond O ايش بتصير وكنا
+
+76
+00:06:48,810 --> 00:06:56,310
+نحطها بمربع أخضرو النيوكليوفايل بيهاجم هاي
+
+77
+00:06:56,310 --> 00:07:01,330
+نيوكليوفايل و السيطة بالبنط O صارت OH الآن ال R و
+
+78
+00:07:01,330 --> 00:07:08,210
+ال R' ما تدخلوش احنا كل اللي عملناه الحقيقة في
+
+79
+00:07:08,210 --> 00:07:11,930
+التفاعلات كل اللي عملناه في التفاعلات تبع ال
+
+80
+00:07:11,930 --> 00:07:16,690
+aldehydes و ال ketones هو فقط تغيير اللي هان يعني
+
+81
+00:07:16,690 --> 00:07:20,310
+كل اللي درسنا قولنا لما تكون هذه مياه بده يكون هنا
+
+82
+00:07:22,430 --> 00:07:27,930
+OH لما يكون كحول OR لما يكون cyanide CN لما يكون
+
+83
+00:07:27,930 --> 00:07:32,970
+hydride H الان لما يكون green yard R
+
+84
+00:07:36,320 --> 00:07:40,660
+وبعد شوية هنجيب نيتروجين نيوكليوفايل يتحد هنا
+
+85
+00:07:40,660 --> 00:07:45,980
+بنكون خلصنا الشطر الألديهيد والكيتونز فكل شغلنا
+
+86
+00:07:45,980 --> 00:07:52,340
+الحقيقة هو عبارة عن أمثلة لنفس التفاعل أمثلة لنفس
+
+87
+00:07:52,340 --> 00:07:56,820
+التفاعل فقط تغيير النيوكليوفايل في كل الأحوال عندي
+
+88
+00:07:56,820 --> 00:08:00,500
+addition و ال C double bond O بتصير OH هذا عام
+
+89
+00:08:00,500 --> 00:08:05,030
+مشترك لكن النيوكليوفايل مارا يكون كذا كذا كذااليوم
+
+90
+00:08:05,030 --> 00:08:09,050
+ايش لنيو كليو فايل تبعنا ل green yard ray agent
+
+91
+00:08:09,050 --> 00:08:15,630
+اللي هو R مع إلكتروناتها او AR مع إلكتروناتها و
+
+92
+00:08:15,630 --> 00:08:19,850
+عرفنا كيف بتحضر يعني لو كنا بديني ب RX كتبنا مع ال
+
+93
+00:08:19,850 --> 00:08:25,790
+MG بنكتب RMGX بعدين لما بنفعله ايش بناخد منه بس ال
+
+94
+00:08:25,790 --> 00:08:34,190
+R ال RMGX مش موضوعنا الآن هذا التفاعل حقيقةمهم
+
+95
+00:08:34,190 --> 00:08:40,270
+كتير ليش؟ خلّينا نجرب نفس الـgreenyard reagent على
+
+96
+00:08:40,270 --> 00:08:44,770
+أنواع مختلفة من الالديهيدس والكيتونز نقول
+
+97
+00:08:44,770 --> 00:08:48,410
+الـgreenyard reagent تبعنا إثل الـRGBR يعني إثل
+
+98
+00:08:48,410 --> 00:08:52,430
+مجليسيامبروميدل الآن هذا إيش هيحُك اليوكليوفاين؟
+
+99
+00:08:53,400 --> 00:08:59,020
+مجموعة ال aethyl لو فعلنا مع ال formaldehyde اللي
+
+100
+00:08:59,020 --> 00:09:05,580
+هو أبسط ال dehyde هذه بدها تصير OH و بده يحط عندها
+
+101
+00:09:05,580 --> 00:09:13,060
+مجموعة ال aethyl هاي مجموعة ال aethyl شايفينها و
+
+102
+00:09:13,060 --> 00:09:20,200
+هنا CH2 OH هذه ثابتةواضح؟ إذا هو حط مجموعة الـ
+
+103
+00:09:20,200 --> 00:09:22,660
+ethylene لاحظوا الآن ال green yard مع ال
+
+104
+00:09:22,660 --> 00:09:28,120
+formaldehyde كوالي كحول إيش نوع هذا الكحول؟
+
+105
+00:09:28,120 --> 00:09:32,880
+primary alcohol طيب خليني أفعل ال green yard مع أي
+
+106
+00:09:32,880 --> 00:09:40,060
+aldehyde تاني غير ال formaldehyde يعني
+
+107
+00:09:40,060 --> 00:09:44,360
+acetaldehyde هذا, ibropenaldehyde, benzaldehyde
+
+108
+00:09:44,360 --> 00:09:51,840
+طبعا هيحط برضه مجموعةالإثل وهي جزء ال الديهايد
+
+109
+00:09:51,840 --> 00:09:56,320
+كانت كاربون متصل فيها H وCH3 وصارت OH الآن إيش
+
+110
+00:09:56,320 --> 00:10:02,760
+كوّل لها سكندري الكحول طب خلّيه يتفاعل مع ال كيتون
+
+111
+00:10:02,760 --> 00:10:10,200
+مع هذا الاسيتون شو هيحط مجموعة ال إثل تيرتشاري
+
+112
+00:10:10,200 --> 00:10:17,710
+الكحول واضح؟إذن الآن صرنا فاهمين ليش greenery
+
+113
+00:10:17,710 --> 00:10:21,810
+agent موضوع مهم لأن هو بالنسبة لنا بيمثل طريقة
+
+114
+00:10:21,810 --> 00:10:26,910
+لتحضير كل أنواع الكحولات يعني لو بدى primary
+
+115
+00:10:26,910 --> 00:10:32,610
+alcohol بدى أنطلق من ال formaldehyde تمام؟ لو بدى
+
+116
+00:10:32,610 --> 00:10:39,150
+secondary alcohol بدى أنطلق من أي aldehyde تاني
+
+117
+00:10:39,150 --> 00:10:44,410
+غيرغير ال formaldehyde لأن ال formaldehyde بيعطي
+
+118
+00:10:44,410 --> 00:10:47,710
+ال alcohol برايمر كل ال aldehydes التانية بيعطيه
+
+119
+00:10:48,170 --> 00:10:53,850
+secondary لو بدى tertiary alcohol بدى كيت بيعطينى
+
+120
+00:10:53,850 --> 00:10:58,830
+بدى اتفاعل مع او بدى تم التفاعل مع الكيتون وبناء
+
+121
+00:10:58,830 --> 00:11:03,810
+على ذلك لو قلنالكوا اكمل المعادلة او مثلا كيف تحضر
+
+122
+00:11:03,810 --> 00:11:10,910
+كحول معين كيف بدى يكون الجواب تبعنا باستعمال طريقة
+
+123
+00:11:10,910 --> 00:11:15,710
+ingredient باستعمال طريقة ingredient خلينا ناخد
+
+124
+00:11:17,360 --> 00:11:23,800
+مثال او اكتر على هذا الموضوع حتى انرسخ هذا الكلام
+
+125
+00:11:23,800 --> 00:11:32,360
+يعني لو اجينا سألناكم عندكم هذا الكحول فينيل CH2OH
+
+126
+00:11:32,360 --> 00:11:39,860
+how can you prepare this alcohol فكرولي ان انتوا
+
+127
+00:11:39,860 --> 00:11:44,080
+بتكونوا تحضروا هذا الكحول بطريقة السيد الجرين يعني
+
+128
+00:11:45,470 --> 00:11:51,690
+ماشي اللي هنقوله ايش
+
+129
+00:11:51,690 --> 00:12:00,310
+نوع هذا الكحول ال primary اذا انا لازمني ال CH2 و
+
+130
+00:12:00,310 --> 00:12:04,990
+ال double bond all formaldehyde و بدي افعله مع اي
+
+131
+00:12:04,990 --> 00:12:11,970
+green yardary agent مع فنل MgBr
+
+132
+00:12:14,230 --> 00:12:17,290
+فنل مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر
+
+133
+00:12:17,290 --> 00:12:19,310
+مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر
+
+134
+00:12:19,310 --> 00:12:20,190
+مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر
+
+135
+00:12:20,190 --> 00:12:20,190
+مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجدر مجدر
+
+136
+00:12:20,190 --> 00:12:25,610
+مجدر مجدر مجدر
+
+137
+00:12:25,610 --> 00:12:26,890
+مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر
+
+138
+00:12:26,890 --> 00:12:32,990
+مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر
+
+139
+00:12:32,990 --> 00:12:35,270
+مجدر
+
+140
+00:12:43,630 --> 00:12:49,690
+وكان السؤال بالشكل القاتى how can you prepare this
+
+141
+00:12:49,690 --> 00:12:57,390
+alcohol from two different compounds يعني بده يعمل
+
+142
+00:12:57,390 --> 00:13:01,010
+مركبين والمركبين معروفين جيدا بالنسبة إلينا كيف
+
+143
+00:13:01,010 --> 00:13:05,930
+بنحضر هذا الكحول من مركبين مختلفين two different
+
+144
+00:13:05,930 --> 00:13:12,390
+ketones الان
+
+145
+00:13:13,490 --> 00:13:17,790
+وحدة قالت ممكن نستعمل هذا ال C double bond O حاملة
+
+146
+00:13:17,790 --> 00:13:24,550
+تنتهي CH3 وحدة حاملة CH3 وحدة فنل C double bond O
+
+147
+00:13:24,550 --> 00:13:33,870
+CH3 و هذه فنل هذا المركب شو اسمه؟ خلينا في اللي
+
+148
+00:13:33,870 --> 00:13:34,630
+بنعرفه
+
+149
+00:13:37,180 --> 00:13:42,240
+اسيتون اسيتون ماحد بيقول عنه provenone واضح؟
+
+150
+00:13:42,240 --> 00:13:47,860
+اسيتون و هذا يلا
+
+151
+00:13:47,860 --> 00:13:53,600
+بتحكوا بعد يومين فين ال C-double bond OCH3؟
+
+152
+00:13:53,600 --> 00:13:58,740
+أسيتوفينونأبشر بطولى سلامة اليوم الرابعه
+
+153
+00:13:58,740 --> 00:14:05,060
+أسيتوفينون إذا هذا أسيتون هذا أسيتوفينون الآن
+
+154
+00:14:05,060 --> 00:14:09,500
+هدولة لما أنا بدي أفعلهم هذه إيش ناقصها مجموعة إيش
+
+155
+00:14:09,500 --> 00:14:19,380
+إذا هاخد فين ال .. MgBr MgBr و هذه إيش ناقصها هاخد
+
+156
+00:14:19,380 --> 00:14:24,600
+CH3 MgBr
+
+157
+00:14:27,780 --> 00:14:32,200
+واضح؟ مجمعتين بدهم يكونوا على الكيتون والتالتة بدي
+
+158
+00:14:32,200 --> 00:14:35,580
+اجيبها من ال green yard و اعملوا اي خلطة انتوا
+
+159
+00:14:35,580 --> 00:14:42,930
+بتكونوا معاها واضحة في هذه النقطة؟إذا مش صعب ان
+
+160
+00:14:42,930 --> 00:14:47,610
+نحضر primary او secondary او tertiary alcohol قطعة
+
+161
+00:14:47,610 --> 00:14:51,670
+من القطع هنجيبها من وين؟ من ال grill yard و الباقي
+
+162
+00:14:51,670 --> 00:14:57,730
+بيكون جزء ال aldehyde او ال ketone اللي هيكون
+
+163
+00:14:57,730 --> 00:14:59,830
+موجود عندنا و نبدأ فيه
+
+164
+00:15:09,860 --> 00:15:14,140
+الان بنجي لنقطة جديدة لكن مرت علينا مش هناخد فيها
+
+165
+00:15:14,140 --> 00:15:18,580
+كتير Oxidation of aldehydes and ketones مر علينا
+
+166
+00:15:18,580 --> 00:15:23,500
+احنا ان ال primary alcohol كانت تتأكسد لايش
+
+167
+00:15:23,500 --> 00:15:26,760
+لالدهيد
+
+168
+00:15:26,760 --> 00:15:30,620
+و اذا استعملنا عامل مؤكسد قوي الالدهيد شو بيصير؟
+
+169
+00:15:30,620 --> 00:15:34,980
+acid خلاص اذا الجزء اللى بدنا يهو ال الديهيد كان
+
+170
+00:15:34,980 --> 00:15:40,260
+بي oxidizeto acids مرت علينا في جزء ال alcohol ولا
+
+171
+00:15:40,260 --> 00:15:44,230
+لأ؟أه كنا نقول الكحول بيصير ال الديهيد و ال
+
+172
+00:15:44,230 --> 00:15:48,050
+الديهيد أسد ال الديهيد أسد هو تفاعل لل الديهيد و
+
+173
+00:15:48,050 --> 00:15:51,610
+الكيتون صارنا عارفينه طيب ال secondary alcohol
+
+174
+00:15:51,610 --> 00:15:56,510
+كانوا يتأكسدوا لإيش لكيتون ال كيتون بتتأكسد أكسدة
+
+175
+00:15:56,510 --> 00:16:00,970
+إضافية لأ إذا هاي الموضوع أكسدت ال الديهيد و
+
+176
+00:16:00,970 --> 00:16:05,130
+الكيتون ان ال الديهيد بيصيروا أسد و الكيتون
+
+177
+00:16:05,130 --> 00:16:11,700
+بتأكسدوش خلصناواضح؟ وكل هذه الفكرة مرت علينا في أي
+
+178
+00:16:11,700 --> 00:16:18,260
+منطقة؟ في منطقة الكحولات كل هذه الفكرة مرت علينا
+
+179
+00:16:18,260 --> 00:16:21,080
+في منطقة الكحولات ليش؟ لأننا كنا نقول primary
+
+180
+00:16:21,080 --> 00:16:25,980
+alcohol، aldehyde acid secondary alcohol، ketone،
+
+181
+00:16:25,980 --> 00:16:31,140
+stop tertiary alcohol من الأساس مافيش أكسة ده،
+
+182
+00:16:31,140 --> 00:16:37,560
+واضح؟الان بنجي الى التفاعل الأخير لل ال الديهايتز
+
+183
+00:16:37,560 --> 00:16:43,200
+والكيتونز اللى هو التفاعل مع مركبات ال نيتروجين مع
+
+184
+00:16:43,200 --> 00:16:48,120
+ال نيتروجين ال يوكليوفايلز طبعا أشهر المركبات اللى
+
+185
+00:16:48,120 --> 00:16:54,760
+هتمر علينا غير الأمونيا الامونيا NH3 تمام؟ الان
+
+186
+00:16:54,760 --> 00:16:58,940
+انا لو أخدت من الأمونيا derivative لو أخدت من
+
+187
+00:16:58,940 --> 00:17:04,990
+الأمونيا derivative هخلى NH2و محل ال H التالتة احط
+
+188
+00:17:04,990 --> 00:17:09,350
+اشي معين خليني اسمي X يعني تطلعوا هذه احدى مشتقات
+
+189
+00:17:09,350 --> 00:17:16,030
+الأمونيا NH2 متصلة بإيش؟ ب X في الأمونيا ال X إيش
+
+190
+00:17:16,030 --> 00:17:23,510
+بتكون؟ Hydrogen الان ممكن ال X تكون مثل إثل ممكن
+
+191
+00:17:23,510 --> 00:17:29,270
+تكون NH2 تانية ممكن تكون R ممكن تكون OH ممكن تكون
+
+192
+00:17:29,270 --> 00:17:36,430
+ARاعتبروها X وكل اشي فيها ال X ممكن بيصير التفاعل
+
+193
+00:17:36,430 --> 00:17:40,830
+تبعنا للناس اللي بدهم يفهموه يقولوا ال X بتضلها
+
+194
+00:17:40,830 --> 00:17:46,970
+إيش؟ X مالنا و مالها كيف ال N H2 بتتفاعل مع ال C
+
+195
+00:17:46,970 --> 00:17:54,610
+double bond O واضح الكلام؟ كيف ال N H2 بتتفاعل مع
+
+196
+00:17:54,610 --> 00:18:00,470
+ال C double bond O الآن ال nitrogen هذاIn UQ5
+
+197
+00:18:00,470 --> 00:18:05,670
+بيحمل زوج إلكترونات وبناء على ذلك لما بنفعله مع C
+
+198
+00:18:05,670 --> 00:18:09,770
+double bond O بده يهاجم عليها هنا و ال C double
+
+199
+00:18:09,770 --> 00:18:16,730
+bond O تصير OH فاللي هيتكون عنده حقيقة بنص الطريق
+
+200
+00:18:16,730 --> 00:18:23,860
+هو المركب القاتل اللي هيكون فيه عنده C Oأتش هنا
+
+201
+00:18:23,860 --> 00:18:33,840
+إيش موجود عندى OH وهنا خلّينا نقول N H متصلة بال X
+
+202
+00:18:33,840 --> 00:18:40,660
+وهنا المجموعتين اللى عندى واضح هذا ال N H المتصلة
+
+203
+00:18:40,660 --> 00:18:45,800
+بال X والمجموعتين اللى عندى واضح ولا لأ ولا أرسمه
+
+204
+00:18:45,800 --> 00:18:50,440
+بالطريقة اللى أنتم متعودين عليهاهذه الكربون متصل
+
+205
+00:18:50,440 --> 00:18:58,320
+فيها مجموعتين هذه شو صارت OH وهنا NHX
+
+206
+00:18:58,320 --> 00:19:06,500
+واضح؟ وهذه كنا نحطها بالأخضر وهذا لليوكليوفايل
+
+207
+00:19:06,500 --> 00:19:12,160
+اللي تم الهجوم عليه الآن هذا التفاعل شو نوعه؟
+
+208
+00:19:13,370 --> 00:19:17,590
+addition reaction هذا تفاعل addition هذا
+
+209
+00:19:17,590 --> 00:19:24,050
+النيوكليوفايل واضح الفكرة ماجيبناش إش جديد الآن في
+
+210
+00:19:24,050 --> 00:19:29,330
+حالة ال nitrogen نيوكليوفايل والان H2 بعد ما بتم
+
+211
+00:19:29,330 --> 00:19:35,610
+هذا ال addition عادة وبشكل تلقائي بتم تفاعل تاني
+
+212
+00:19:35,970 --> 00:19:38,950
+ولذلك الناتج ما بيقفش عند ال addition يعني لو
+
+213
+00:19:38,950 --> 00:19:43,430
+الناتج بيقف عند ال addition الأمر بصير بتم تفاعل
+
+214
+00:19:43,430 --> 00:19:48,390
+تاني تلقائي هذا التفاعل التاني التلقائي في عندكم
+
+215
+00:19:48,390 --> 00:19:53,590
+هنا OH وفي عندنا هنا جنبها على الذرة المجاورة هدول
+
+216
+00:19:53,590 --> 00:19:57,890
+ذرتين متجاورتين carbon و nitrogen صح؟ على ال
+
+217
+00:19:57,890 --> 00:20:04,150
+carbon عندكم OH وعلى ال nitrogen H الآن بتم حذفال
+
+218
+00:20:04,150 --> 00:20:11,990
+OH مع ال H على شكل جزيء ماء هاي ال OH هذه مع ال H
+
+219
+00:20:11,990 --> 00:20:14,910
+اللي هنا ع شكل جزيء ماء لما بدوا ينحفوا شو بدوا
+
+220
+00:20:14,910 --> 00:20:21,430
+يصير مكانهم double bond هاني شلتم شلتم شلتم ايش
+
+221
+00:20:21,430 --> 00:20:28,990
+بده احط مكانهم double bondواضح؟ إذا بعد ال
+
+222
+00:20:28,990 --> 00:20:34,170
+addition صار عندي تفاعل elimination وعشان هيك
+
+223
+00:20:34,170 --> 00:20:38,690
+العنوان اللي عندكم كان إيش addition elimination
+
+224
+00:20:38,690 --> 00:20:42,510
+reactions of aldehydes and ketones هذه مع أي
+
+225
+00:20:42,510 --> 00:20:49,330
+مركبات بتصير؟مع الان H2 اللى متصل فيها أي X كانت
+
+226
+00:20:49,330 --> 00:20:54,930
+الان بيجي السؤال من ناحية السهولة هل يا ترى كل مرة
+
+227
+00:20:54,930 --> 00:21:00,380
+عشان نكتب الجواب الصحبدنا نقعد نتخيل الحالة
+
+228
+00:21:00,380 --> 00:21:04,520
+الوسيطة ونقول تمت الإضافة ونرسم الناتج وبعدين بتم
+
+229
+00:21:04,520 --> 00:21:08,980
+الحدف و تاخدوا خمس دقائق وانتوا تكتبوا الجواب لأ
+
+230
+00:21:08,980 --> 00:21:13,960
+بإمكاننا من ناحية تطبيقية نعمل الأمر بطريقة سهلة
+
+231
+00:21:13,960 --> 00:21:19,080
+جداالأمر بطريقة سهلة جدا اللي بيشمل العمليتين انه
+
+232
+00:21:19,080 --> 00:21:23,600
+دائما تخيلوا C double bond O والان H2 جايين بهذا
+
+233
+00:21:23,600 --> 00:21:27,980
+الشكل الان خلوها تصير C double bond N لاحظوا ايش
+
+234
+00:21:27,980 --> 00:21:37,060
+انا حدفت H2O فخلو بدل ما مكتوب عندكم C double bond
+
+235
+00:21:37,060 --> 00:21:43,480
+O خلوها C double bond N والان متصلة ب Xإذا هذا
+
+236
+00:21:43,480 --> 00:21:49,020
+التفاعل صار أسهل تفاعل فيهم نتيجته النهائية أنه في
+
+237
+00:21:49,020 --> 00:21:54,000
+التفاعل مع ال N H2 بدل ما كان عنده C double bond O
+
+238
+00:21:54,000 --> 00:22:02,360
+بتصير C double bond N واضحة الفكرة و ال N بأي X
+
+239
+00:22:02,360 --> 00:22:07,580
+متصلة يعتبر موضوع بسيط بس كنتيجة أنه C double bond
+
+240
+00:22:07,580 --> 00:22:15,640
+O بتصير C double bond Nأبتدت أن نكون كفكرة إلتهينا
+
+241
+00:22:15,640 --> 00:22:22,020
+من هذه التفاعلات ولكن الآن نريد أن نعرف أسماء
+
+242
+00:22:22,020 --> 00:22:27,970
+الأشياء التي تتفاعل عادةأو بمعنى آخر خلّينا نقول
+
+243
+00:22:27,970 --> 00:22:32,710
+نعطي أمثلة على ال X إيش ممكن تكون ال X واضحة
+
+244
+00:22:32,710 --> 00:22:37,950
+الفكرة؟ إيش ممكن تكون ال X؟ الآن هذه عندي دائما و
+
+245
+00:22:37,950 --> 00:22:42,270
+أبدا unatched two نتفق ال unatched two نحطها وين؟
+
+246
+00:22:44,150 --> 00:22:48,970
+بمربع أخضر هذه اللي فاهمين هي ال N H 2 ال N متصلة
+
+247
+00:22:48,970 --> 00:22:55,090
+ب X ال X في هذا المثال شو هي N H 2 تانية ال N هذي
+
+248
+00:22:55,090 --> 00:22:58,950
+ال N H 2 اللي متصلة ب N H 2 تانية المركب بسميه
+
+249
+00:22:58,950 --> 00:23:06,810
+هيدرازين okay هيدرازين طيب لو ال N H 2 تانية كانت
+
+250
+00:23:06,810 --> 00:23:14,290
+متصلة ب N H phenyl يعني ال X عبارة عن إيش؟ان اتش
+
+251
+00:23:14,290 --> 00:23:20,770
+فينيل هذي ال X كلها واضح بيصير اسمه فينيل هيدرازيل
+
+252
+00:23:22,460 --> 00:23:26,180
+أكيد هدول فيش نقاش انه كل اشي اللي انا بدي احكيه
+
+253
+00:23:26,180 --> 00:23:32,400
+بده ينحفظ بالظبط فينل هيدرازين طيب هذه ال N-H2
+
+254
+00:23:32,400 --> 00:23:37,320
+نفسها لو اتصلت ب N-H حاملة فينل وعالفينل على نمره
+
+255
+00:23:37,320 --> 00:23:42,120
+واحد اتنين تلاتة اربعة نيترو نايترو شو هنيجي
+
+256
+00:23:42,120 --> 00:23:51,480
+نسميه؟ two four dinitro فينل هيدرازين واضح؟
+
+257
+00:23:53,580 --> 00:23:58,160
+Two for dinitrophin الهيدرازين الان لو جيبنا لأي
+
+258
+00:23:58,160 --> 00:24:02,760
+واحد من هدول هذا او هذا او هذا كيتون C double bond
+
+259
+00:24:02,760 --> 00:24:06,480
+O وقلنا بدنا نكمل المعادلة احنا و احنا مغمضين
+
+260
+00:24:06,480 --> 00:24:12,720
+متعودين ان هال C double bond O تصير C double bond
+
+261
+00:24:12,720 --> 00:24:18,210
+N خلص الجوابالـ C double bond O بتصير C double
+
+262
+00:24:18,210 --> 00:24:22,370
+bond N و بنحدث الـ H طوله طيب الآن لما اتكون هذا
+
+263
+00:24:22,370 --> 00:24:30,250
+المركب عندى هذا نتج من تفاعل الديهيد او كيتون
+
+264
+00:24:30,250 --> 00:24:39,130
+الديهيد او كيتون يعني انا حاطينهم بصيغة ايش R يعني
+
+265
+00:24:39,130 --> 00:24:43,470
+ممكن تكون H و H H و مثل مثل و مثل اثل و اثل
+
+266
+00:24:44,950 --> 00:24:50,250
+أتشوفينيل مثلوفينيل كل احتمالات واردة الان المركب
+
+267
+00:24:50,250 --> 00:24:53,070
+اللى بيلتج عندى اللى فيه ال c double bond او الان
+
+268
+00:24:53,070 --> 00:24:57,330
+ايش بدي اسميه بسمي اسم ال الديهايد او ال كيتون
+
+269
+00:24:57,330 --> 00:25:03,870
+اللى كوّنه و بحط النهاية اسم هذا لكن بدل ما اقول
+
+270
+00:25:03,870 --> 00:25:09,970
+in بقول on يعني لو كان متفاعل مع NH2 و NH2 بسميه
+
+271
+00:25:09,970 --> 00:25:13,510
+الديهايد او كيتون هيدرازون
+
+272
+00:25:14,360 --> 00:25:20,800
+لو مع هذا فينيل هيدرازون لو مع هذا two four
+
+273
+00:25:20,800 --> 00:25:26,220
+dinitrophenylheidrazone فالنتج مااخد نفس الاسم لكن
+
+274
+00:25:26,220 --> 00:25:36,360
+بنهاية on بدل نهاية in خلينا الان نشوفه بامثلة
+
+275
+00:25:36,360 --> 00:25:41,450
+اكتر يعني بدون ال R و ال Rبأمثلة اقصوا بريد جيجا
+
+276
+00:25:41,450 --> 00:25:45,090
+اقصوا بريد جيجا الأمثلة بتوضح حالها لحالها اقصوا
+
+277
+00:25:45,090 --> 00:25:49,110
+بريد جيجا ان الله يحبه الصابرين والصابرات كمان
+
+278
+00:25:49,110 --> 00:25:59,990
+ربنا بيحبهم يعني
+
+279
+00:25:59,990 --> 00:26:09,310
+لو اجينا هنا حقينا هذه CH3 CH3 هذا المركب شو اسمه
+
+280
+00:26:12,370 --> 00:26:19,830
+اسيتون وهذا هيدرازين
+
+281
+00:26:19,830 --> 00:26:27,190
+الان المركب اللي نشأ منهم شو بدي اسميه اسيتون
+
+282
+00:26:27,190 --> 00:26:35,630
+هيدرازون مش هيدرازين بيصيروا التانين مع بعض اسيتون
+
+283
+00:26:35,630 --> 00:26:39,510
+هيدرازون
+
+284
+00:26:40,980 --> 00:26:47,800
+و بناء على ذلك بنقدر نستنتج استنتاج بسيط جدا ان ال
+
+285
+00:26:47,800 --> 00:26:53,480
+hydrazines بيصيروا hydrazones طب ناخد مثال تاني
+
+286
+00:26:53,480 --> 00:26:58,960
+خلينا نحط هنا H ونحط هنا phenyl في الناتج ايش
+
+287
+00:26:58,960 --> 00:27:07,380
+هيكون عندي هنا H و phenylلو قولنا لواحدة سمينا ال
+
+288
+00:27:07,380 --> 00:27:14,520
+الديهيد او ال كيتون سمي هذا سمي الناتج واضحة
+
+289
+00:27:14,520 --> 00:27:18,560
+الفكرة؟ اتفضلي ايش هذا بنسميه؟ فينيل C double bond
+
+290
+00:27:18,560 --> 00:27:23,940
+OH فينيل
+
+291
+00:27:23,940 --> 00:27:29,200
+C double bond OH ايش اسمه؟ الاسيتوفينون اللي فيه
+
+292
+00:27:29,200 --> 00:27:30,080
+CH3
+
+293
+00:27:42,220 --> 00:27:48,360
+بنزالدهيد بنزالدهيد بنزالدهيد
+
+294
+00:27:48,360 --> 00:27:56,880
+ممتازة الآن هذا إيش اسمه؟
+
+295
+00:27:56,880 --> 00:28:02,180
+أخدناله اسم قبل شوية فنل هيدرازين
+
+296
+00:28:04,140 --> 00:28:13,040
+فنل هيدرازين فنل هيدرازين الآن الناتج اللي ناتج من
+
+297
+00:28:13,040 --> 00:28:18,680
+التنين ايش هيكون اسمه بنز الديهيد فنل هيدرازون بنز
+
+298
+00:28:18,680 --> 00:28:24,920
+الديهيد فنل هيدرازون هاي جزء بنز الديهيد وفنل
+
+299
+00:28:24,920 --> 00:28:31,840
+هيدرازون بنز الديهيد فنل
+
+300
+00:28:33,320 --> 00:28:38,180
+هيدرازون بدل ما كان الاسم عندى oen بدو يصير ايش
+
+301
+00:28:38,180 --> 00:28:42,300
+بنزالديهيدفينالهيدرازون
+
+302
+00:28:42,300 --> 00:28:45,860
+بنزالديهيدفينالهيدرازون
+
+303
+00:28:45,860 --> 00:28:47,920
+الان
+
+304
+00:29:00,620 --> 00:29:06,560
+لو مثلا اجينا وقلنالكوا لو سمحتوا نختبركوا شطرين
+
+305
+00:29:06,560 --> 00:29:12,280
+ولا لا ارسمولنا Cyclohexanone 2,4
+
+306
+00:29:12,280 --> 00:29:22,440
+-dinitrophenylhydrazone هيك ايجاكم Cyclohexanone
+
+307
+00:29:22,440 --> 00:29:29,520
+2,4-dinitrophenyl
+
+308
+00:29:33,300 --> 00:29:39,480
+هيدرازون كل هذا اسم بني آدم مؤدب بدنا نور اسمه
+
+309
+00:29:39,480 --> 00:29:46,380
+السياسة العامة cut and conquer فرق تسد جزقوها ال
+
+310
+00:29:46,380 --> 00:29:52,100
+Cyclohexanone أصلا
+
+311
+00:29:52,100 --> 00:29:58,980
+كان زي هيك CWO بس احنا عرفنا بعد العقلة ال CWO إيش
+
+312
+00:29:58,980 --> 00:30:05,270
+بتصير؟C double bond N هاي حطينا ال N لما نكمل ال 2
+
+313
+00:30:05,270 --> 00:30:12,250
+,4-dinitrophenylhydrazone بدنا نحط N H حاملة فنل
+
+314
+00:30:12,250 --> 00:30:23,190
+وعلى موقع 2 بالفنل N O 2 و N O 2 طبعا اللي بتدرب
+
+315
+00:30:23,190 --> 00:30:27,710
+عليهم بيتقنهم هاي Cyclohexanone 2,4
+
+316
+00:30:27,710 --> 00:30:29,830
+-dinitrophenylhydrazone
+
+317
+00:30:34,850 --> 00:30:58,890
+واضحة الفكرة طيب
+
+318
+00:30:58,890 --> 00:31:05,400
+لو كان السؤالعشان تشوفوا العلم مبني على بعضه
+
+319
+00:31:05,400 --> 00:31:14,440
+ارسموا Cyclohexane Carb Aldehyde Hydrazol خلصنا
+
+320
+00:31:14,440 --> 00:31:23,540
+من هذا؟ Cyclohexane
+
+321
+00:31:23,540 --> 00:31:31,800
+Carb Aldehyde Cyclohexane Carb Aldehyde
+
+322
+00:31:36,170 --> 00:31:41,950
+Hydrazone كلمة واحدة
+
+323
+00:31:41,950 --> 00:31:47,490
+طبعا اللي بتعرفش ال Cyclohexane لحاله ولو بتعرفش
+
+324
+00:31:47,490 --> 00:31:51,370
+ال Hydrazone لحاله مش هترسم طبعا هذا Cyclohexane
+
+325
+00:31:51,370 --> 00:31:55,950
+إيش؟ Carb Aldehyde كلكوا لازم تكونوا متذكرين أنه
+
+326
+00:31:55,950 --> 00:32:00,410
+إحنا لما حكينا عن ال aldehydes مع الحلقة قلنا ال
+
+327
+00:32:00,410 --> 00:32:07,610
+aldehyde بيكون معلق تعليج على الحلقةيعني الـ
+
+328
+00:32:07,610 --> 00:32:11,010
+Cyclohexane كربلديهيد لو قلب لحاله زي هيك وهذه C
+
+329
+00:32:11,010 --> 00:32:16,750
+double bond O الأن لما تصير Hydrazone هتصير C
+
+330
+00:32:16,750 --> 00:32:21,530
+double bond N ولما يكون .. بس كلمة Hydrazone لحاله
+
+331
+00:32:21,530 --> 00:32:27,890
+بدون ولا إشي تاني N H 2 لو كانت فين ال Hydrazone؟
+
+332
+00:32:27,890 --> 00:32:33,940
+بدي أحط فين ال .. طب لو قلتلكوا مثل Hydrazoneهتمثل
+
+333
+00:32:33,940 --> 00:32:39,440
+لو قولت اتل هيدرازون اتل لو قولت أسيتل هيدرازون
+
+334
+00:32:39,440 --> 00:32:46,480
+أسيتل حد مايعرفش الأسيتل C double bond O CH3 Form
+
+335
+00:32:46,480 --> 00:32:53,940
+الهيدرازون C double bond O H3 و هكذا واضحة الفكرة
+
+336
+00:32:53,940 --> 00:33:00,930
+يعني اتعمقنا كتير كتير زيادة في الموضوع الآنطيب
+
+337
+00:33:00,930 --> 00:33:06,650
+ناخد مشتقة تانية ناخد مشتقة تانية لو يا تورا
+
+338
+00:33:06,650 --> 00:33:12,430
+ماكانش عندى مع ال N H2 N H2 تانية لو كان عندى O H
+
+339
+00:33:12,430 --> 00:33:19,710
+لاحظوا هى عندى ال N H2 بس ايش ال X اللى هنا O H
+
+340
+00:33:19,710 --> 00:33:23,330
+هذا بنسمي Hydroxylamine
+
+341
+00:33:24,660 --> 00:33:30,340
+ماذا نسميه؟ هيدروكسل أمين هي الهيدروكسل وهي الأمين
+
+342
+00:33:30,340 --> 00:33:33,420
+لما بده يتفاعل ال C double bond اوه بتحصل في
+
+343
+00:33:33,420 --> 00:33:39,280
+النهاية C double bond L لما بدنا نسمي المركب بدنا
+
+344
+00:33:39,280 --> 00:33:45,300
+نقول ال الديهيد او ال كيتون والان
+
+345
+00:33:45,300 --> 00:33:49,460
+على هذا الجزء بنكتب كلمة واحدة أكزيم
+
+346
+00:33:51,630 --> 00:33:56,990
+يعني ال c double volt n o h ايش بنسميها اكزيم
+
+347
+00:33:56,990 --> 00:34:01,850
+اكزيم الان
+
+348
+00:34:01,850 --> 00:34:12,490
+واحدة
+
+349
+00:34:12,490 --> 00:34:19,470
+تقول اي جانا هذا في الامتحان رسمه أسيتوفينون اكزيم
+
+350
+00:34:20,940 --> 00:34:27,060
+اللي بدي يرسم بدي يقول هاي ال Acetophenon فينل و
+
+351
+00:34:27,060 --> 00:34:34,200
+CH3 و متصل بـ C double bond O أصلا عشان يكون
+
+352
+00:34:34,200 --> 00:34:41,680
+Acetophenon الأهم لما يصير أكزيم NOH و مثل و
+
+353
+00:34:41,680 --> 00:34:44,420
+Cyclohexanone أكزيم و Cyclopentanone أكزيم و كل
+
+354
+00:34:44,420 --> 00:34:51,160
+الأكزيمات إذا العملية سهلة ولا مش سهلةهنا أخدنا
+
+355
+00:34:51,160 --> 00:35:01,640
+مشتقة الهيدرازون ومشتقة الأكزيم طب
+
+356
+00:35:01,640 --> 00:35:07,560
+لو كانت هذه R يعني مثل ولا إثل؟ ايش بدي يكون
+
+357
+00:35:07,560 --> 00:35:13,000
+الجواب؟ R مثل أو إثل كعائلة بيسموها shift base
+
+358
+00:35:13,000 --> 00:35:20,500
+نتغلب أكتر بالاسماء تبعتها الآن بيضل عندىكل هدولة
+
+359
+00:35:20,500 --> 00:35:25,040
+موجودين يمكن ضلت عندي شغلة واحدة اخرى لو كانت هذه
+
+360
+00:35:25,040 --> 00:35:36,420
+unh2 unh c double bond o unh2 هذا مركب شوية ايش
+
+361
+00:35:36,420 --> 00:35:41,840
+ماله كبير لكن انا المهم عندي فيه ان هذه ال unh2 كل
+
+362
+00:35:41,840 --> 00:35:46,700
+هدولة يعتبروا x واحدة هتقول في تلتين unh2 في واحدة
+
+363
+00:35:46,700 --> 00:35:51,420
+هنا اقريبة على c double bond o واحدةبعيدة مين اللي
+
+364
+00:35:51,420 --> 00:35:55,140
+بتتفعل مع الالدهاد او الـ Ketone؟ هذه البعيدة
+
+365
+00:35:55,140 --> 00:35:58,060
+وبناء على ذلك لو هذا قلتلكوا فعلومة عن
+
+366
+00:35:58,060 --> 00:36:05,700
+الـcyclobentanone كيف هنكتب الجواب؟ زي ما اتعودنا
+
+367
+00:36:05,700 --> 00:36:09,960
+تماما، نحط الـcyclobentane
+
+368
+00:36:09,960 --> 00:36:17,540
+والسيضة بالبند او تصير سيضة بالبند and ونكمل
+
+369
+00:36:19,990 --> 00:36:26,670
+MHCW.O NH2 بيصير .. طب إيش اسم هذا و إيش اسم هذا
+
+370
+00:36:26,670 --> 00:36:37,450
+هذا اسمه سيمي كربازايد سيمي كربازايد طب و الناتج
+
+371
+00:36:37,450 --> 00:36:43,690
+اللي بتطلع من السيمي كربازايدSemi-carbazone زي
+
+372
+00:36:43,690 --> 00:36:49,210
+هيدرازين هيدرازون Carbazide Carbazone إذا هذا
+
+373
+00:36:49,210 --> 00:36:54,610
+المركب كاملا الأن لو بدنا نسميه شو هنسميه؟
+
+374
+00:36:54,610 --> 00:37:00,450
+Cyclobentanone
+
+375
+00:37:00,450 --> 00:37:05,110
+Semi-carbazone
+
+376
+00:37:07,490 --> 00:37:17,290
+cyclobentanone-semicarbazone هذا
+
+377
+00:37:17,290 --> 00:37:29,310
+هو
+
+378
+00:37:29,310 --> 00:37:30,930
+ال slide الأخير
+
+379
+00:37:34,700 --> 00:37:41,500
+بتلخص لي كل الدارس انه ال amine اللي هو متصل في ال
+
+380
+00:37:41,500 --> 00:37:47,980
+NH2R بيعطي كعائلة عامة امين ال hydroxylamine بيعطي
+
+381
+00:37:47,980 --> 00:37:54,160
+oxime ال semi carbazide بيعطي semi carbazone ال
+
+382
+00:37:54,160 --> 00:38:00,880
+hydrazines بيعطي hydrazones واضح؟ مرة تانية نعيدهم
+
+383
+00:38:00,880 --> 00:38:08,150
+مع بعض ال hydrazineوالهيدروكس الأمين أكزيم والسمي
+
+384
+00:38:08,150 --> 00:38:13,650
+كربازايد سيمي كربازون والأمين اللي هي متصلة بR
+
+385
+00:38:13,650 --> 00:38:22,570
+امين امين بس واضح لو نعطي مثال ولا نقول الله
+
+386
+00:38:22,570 --> 00:38:27,630
+يعطيكوا العافية بنعطي مثلين بنعطي مثلين و بنخلص
+
+387
+00:38:27,630 --> 00:38:33,870
+اليوم إجاكم سؤال أرسموا إيثانال أكزيم
+
+388
+00:38:35,520 --> 00:38:48,140
+وإجانا السؤال ارسمه داي إثل كيتون فين الهيدرازون
+
+389
+00:38:48,140 --> 00:38:54,420
+يلا
+
+390
+00:38:54,420 --> 00:39:06,030
+نجلوني إيثانال عارفين الإيثانال؟اللي هو CHCH3
+
+391
+00:39:06,030 --> 00:39:11,410
+اللي هو ال Acetaldehyde وهذه كانت C double bond O
+
+392
+00:39:11,410 --> 00:39:16,310
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+393
+00:39:16,310 --> 00:39:16,790
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+394
+00:39:16,790 --> 00:39:16,810
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+395
+00:39:16,810 --> 00:39:18,510
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+396
+00:39:18,510 --> 00:39:18,890
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+397
+00:39:18,890 --> 00:39:18,890
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+398
+00:39:18,890 --> 00:39:26,070
+ان او اتش ان او اتش ان او اتش ان
+
+399
+00:39:26,070 --> 00:39:30,520
+اهو الـ 3-bentanone هو داي إثل كيتون إيش بده أحط؟
+
+400
+00:39:30,520 --> 00:39:35,700
+هاي الـ ketone C double bond O وهي مجموعة إثل وهي
+
+401
+00:39:35,700 --> 00:39:41,940
+مجموعة إثل مش CH2 CH3 إثل CH2 CH3 إثل داي إثل
+
+402
+00:39:41,940 --> 00:39:48,960
+كيتون الآن بده منه فين
+
+403
+00:39:48,960 --> 00:39:53,100
+الهيدرازون؟ أكيد هيكون
+
+404
+00:40:03,390 --> 00:40:07,770
+طبعا أنا بتوقعش ان كل إشي هتكون أتقنطوه لان لكن في
+
+405
+00:40:07,770 --> 00:40:11,290
+المحاضرة اللي جاية لما تتدربوا و ال organic تدريب
+
+406
+00:40:11,290 --> 00:40:16,110
+و كتابة أكيد ان شاء الله كل شيء بتتقنوه بهيك
+
+407
+00:40:16,110 --> 00:40:21,010
+بننتهي من درس ال aldehydes و ال ketones و ان شاء
+
+408
+00:40:21,010 --> 00:40:27,060
+الله يوم السبتفي عندنا مراجعة للامتحانات النصفية
+
+409
+00:40:27,060 --> 00:40:31,420
+كونوا مجاهزينها او ساحبينها ع ورق و حلينها احنا
+
+410
+00:40:31,420 --> 00:40:36,000
+بنحلها انا قدامكم و بنناقش اي مشكلة فيها و بعد هيك
+
+411
+00:40:36,000 --> 00:40:39,380
+ان شاء الله بنبدأ في موضوع الأحماض و مستقبلها و
+
+412
+00:40:39,380 --> 00:40:45,260
+الامتحان لنهاية الفصل السادس حكينا بوضوح الامتحان
+
+413
+00:40:45,260 --> 00:40:47,980
+لنهاية الفصل السادس اذا سمحت
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..46be9d08e376177afdebeb77ac68b54d02e6d08b
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU.srt
@@ -0,0 +1,1671 @@
+
+1
+00:00:20,690 --> 00:00:23,670
+بسم الله الرحمن الرحيم، في موضوع الـ
+
+2
+00:00:23,670 --> 00:00:27,290
+Stereochemistry، آخر شغلة أتكلمنا عنها
+
+3
+00:00:30,440 --> 00:00:36,360
+كانت موضوع الخواص الفيزيائية ربما لل enantiomers
+
+4
+00:00:36,360 --> 00:00:41,000
+وقولنا ان ال enantiomers بيشتركوا في كل الخواص
+
+5
+00:00:41,000 --> 00:00:47,360
+الفيزيائية ما عدا خاصية ال rotation of polarized
+
+6
+00:00:47,360 --> 00:00:53,460
+light تدوير الضوء المستوى طبعا شرحنا
+
+7
+00:00:54,200 --> 00:00:59,300
+بشكل مبسط جهاز ال بولاريميتر وقلنا لو في عندنا two
+
+8
+00:00:59,300 --> 00:01:03,760
+انان شمارز حاطناهم في مسار الضوء تبع ال بولاريميتر
+
+9
+00:01:03,760 --> 00:01:09,780
+نفس الكمية واحد هيلف الضوء لليمين هيكون المركب
+
+10
+00:01:09,780 --> 00:01:14,630
+dextrorotatory أو positive التاني هيلف للشمال عشان
+
+11
+00:01:14,630 --> 00:01:18,610
+نتخلص من فكرة اننا نضل نقول حطينا نفس الكمية
+
+12
+00:01:18,610 --> 00:01:23,630
+اعرفنا شئ سمناه الدوران النوعى او ال specific
+
+13
+00:01:23,630 --> 00:01:27,770
+rotation ال specific rotation بمنطق الخواص بمنطق
+
+14
+00:01:27,770 --> 00:01:31,890
+الخواص هو عبارة عن intensive probability بمنطق
+
+15
+00:01:31,890 --> 00:01:34,750
+الخواص هو عبارة عن intensive probability يعني
+
+16
+00:01:34,750 --> 00:01:40,660
+المركب الواحد له specific rotation واحد ولذلك ربما
+
+17
+00:01:40,660 --> 00:01:46,980
+اعطيناكم homework وقلنا لكم شوفوا لنا مثلا ال R2
+
+18
+00:01:46,980 --> 00:01:53,240
+butanol قداش الزاوية تبعته هذه الزاوية بتكون عبارة
+
+19
+00:01:53,240 --> 00:01:57,840
+عن شئ تجريبي ماعرفش في ناس جدروا يصلوا لهذه
+
+20
+00:01:57,840 --> 00:01:58,380
+الزاوية
+
+21
+00:02:00,890 --> 00:02:10,130
+الان تلتعش وتسعة سالب ولا موجب الان
+
+22
+00:02:10,130 --> 00:02:15,490
+وضحتلكم انا لاحظوا يعني بكل وضوح قلتلكم اللي
+
+23
+00:02:15,490 --> 00:02:21,770
+بيعرف اللي بيعرف زاوية بيعرف التانية يعني اذا انا
+
+24
+00:02:21,770 --> 00:02:29,220
+كنت معطيكم في الواجب زاوية المُركّب الـR فتحته النت
+
+25
+00:02:29,220 --> 00:02:35,360
+وجدت الـS-13 وكذا إذا الـR هتكون الـPlus العكس
+
+26
+00:02:35,360 --> 00:02:42,380
+واضح؟ وانتهى على
+
+27
+00:02:42,380 --> 00:02:52,800
+أي حال فتش ربما بشكل أداء ليش؟
+
+28
+00:02:54,350 --> 00:02:59,050
+معنى ذلك اتقانكم لعملية البحث .. اتقانكم لعملية
+
+29
+00:02:59,050 --> 00:03:03,930
+البحث ضعيف يعني انا بهمني ان انتوا تتعبوا انا
+
+30
+00:03:03,930 --> 00:03:08,750
+بهمني في النهاية ان انتوا .. ان انتوا تتعبوا يعني
+
+31
+00:03:08,750 --> 00:03:13,270
+ان اقولكوا specific rotation ل ال tube eutanol و
+
+32
+00:03:13,270 --> 00:03:19,170
+تقولوا اتغلبنا معنى ذلك ما تقلتوش ممكن في عصر
+
+33
+00:03:19,170 --> 00:03:23,210
+المعلومات ناس ما يقدروش يطولوا ل specific rotation
+
+34
+00:03:23,210 --> 00:03:28,090
+لتو بيوتانول او لتو كلورو بيوتانول هذه معلومة
+
+35
+00:03:28,090 --> 00:03:32,690
+ثابتة زي ما اجي اقولكم تماما ايش نقطة الغليان ايش
+
+36
+00:03:32,690 --> 00:03:36,410
+نقطة الانصهار ايش نقطة كده كل هذه المعلومات
+
+37
+00:03:36,410 --> 00:03:41,970
+معلومات متوفرة وموجودة على ال net مش ممكن الا انكم
+
+38
+00:03:41,970 --> 00:03:49,720
+تطولوها تمام بكل الأحوال لما اللاجئ لأيزومر معين ل
+
+39
+00:03:49,720 --> 00:03:53,920
+specific rotation كأنه انا عندى لأيزومر التاني
+
+40
+00:03:53,920 --> 00:03:58,760
+مباشرة يعني لما يكون واحد موجب بمقدار معين التاني
+
+41
+00:03:58,760 --> 00:04:05,060
+بيكون سالب بنفس المقدار الان لاحظوا معايا لو حطينا
+
+42
+00:04:05,060 --> 00:04:10,150
+المركب الموجب او أحد ال enantiomers في البولاريميتر
+
+43
+00:04:10,150 --> 00:04:15,350
+بلوف ايش؟ الضوء هذا الجزء اللي بلوف الضوء الآن
+
+44
+00:04:15,350 --> 00:04:21,830
+بنقول عنه مصطلح chiral molecule هنا كنت بنتبه ان
+
+45
+00:04:21,830 --> 00:04:26,970
+انا استعمل كلمة chiral مرتين مرة لما انا حكيت عن
+
+46
+00:04:26,970 --> 00:04:31,330
+chiral carbon الكايرال كاربون هي الكاربون اللي
+
+47
+00:04:31,330 --> 00:04:36,170
+عليها أربع مجموعات مختلفة لما بحكي عن كايرال
+
+48
+00:04:36,170 --> 00:04:41,230
+موليكيول الكايرال موليكيول هو الجزير اللي بيعمل
+
+49
+00:04:41,230 --> 00:04:45,750
+دوران للضوء اذا هو أحد ال enantiomers لما بيوجد
+
+50
+00:04:45,750 --> 00:04:50,890
+لحاله نحط احنا احد المركبات في مسار الضوء يعمل
+
+51
+00:04:50,890 --> 00:04:55,530
+دوران للضوء بنقول هذا المركب كايرال موليكيول
+
+52
+00:04:55,530 --> 00:04:58,750
+فالكايرال موليكيول هو اللي بيعمل دوران للضوء الآن
+
+53
+00:04:58,750 --> 00:05:02,370
+طالما انه دخل الضوء فيه وعمله دوران بنقول عنه
+
+54
+00:05:02,370 --> 00:05:06,610
+optically active يعني بدل ما نستعمل مصطلح بيعمل
+
+55
+00:05:06,610 --> 00:05:10,390
+دوران للضوء بنقول optically active فمعنى كلمة
+
+56
+00:05:10,390 --> 00:05:19,400
+optically active it rotates light هو بيلف ايش؟ بيلف
+
+57
+00:05:19,400 --> 00:05:23,320
+في الضوء سواء لف الضوء شمال او لف الضوء يمين هو
+
+58
+00:05:23,320 --> 00:05:27,020
+بيكون ايش؟ optically active لاحظوا معي ايش
+
+59
+00:05:27,020 --> 00:05:31,700
+المركبات اللي بتكون optically inactive المركبات
+
+60
+00:05:31,700 --> 00:05:35,720
+اللي مافيش فيها كل هذه الظاهرة مابديش انا انسى ان
+
+61
+00:05:35,720 --> 00:05:38,980
+بداية ظاهرة ال enantiomers كانت بتتطلب كايرال
+
+62
+00:05:38,980 --> 00:05:44,880
+كاربون عشان يصير من المركب اتنين ROS و بعدين واحد
+
+63
+00:05:44,880 --> 00:05:49,040
+منهم موجب واحد سالب كان بتطلب كيرال كاربون طب لو
+
+64
+00:05:49,040 --> 00:05:52,980
+انا حاطيت مركب زي على سبيل المثال ال carbon
+
+65
+00:05:52,980 --> 00:05:54,040
+tetrachloride
+
+66
+00:05:56,090 --> 00:06:01,350
+هل هذا يا ترى باربع ذرات متشابهة في كايرال كاربون؟
+
+67
+00:06:01,350 --> 00:06:05,850
+في منه اتنين؟ مافيش منه غير واحد، اذا هذا لو انا
+
+68
+00:06:05,850 --> 00:06:09,350
+حاطيته بمسار الضوء، بيكون optically active ولا
+
+69
+00:06:09,350 --> 00:06:14,170
+inactive؟ inactive، لو انا حاطيت ميه في مسار الضوء
+
+70
+00:06:15,320 --> 00:06:19,260
+بكون optically active ولا inactive؟ inactive لو
+
+71
+00:06:19,260 --> 00:06:25,280
+انا حطيت مثلا Dichloromethane CH2 Cl2 بكون
+
+72
+00:06:25,280 --> 00:06:29,960
+optically active ولا inactive؟ inactive لأنه عشان
+
+73
+00:06:29,960 --> 00:06:33,920
+يبدأ يصير أحد ال enantiomers في وجود chiral center
+
+74
+00:06:33,920 --> 00:06:37,960
+واحد المفروض يكون عندى أربع مجموعات مختلفة فخلينا
+
+75
+00:06:37,960 --> 00:06:43,840
+نقول انه نسبة كبيرة جدا من المراكبات العضوية أساسا
+
+76
+00:06:44,940 --> 00:06:50,300
+بتكون achiral لاحظوا معاه هنا بنيجي لنقطة كتير
+
+77
+00:06:50,300 --> 00:06:55,220
+مهمة لما وصفنا مركب انه chiral بمعنى هو أحد
+
+78
+00:06:56,430 --> 00:07:01,010
+الإنانشومارز يعني كلمة chiral بتكون لما بيكون عندى
+
+79
+00:07:01,010 --> 00:07:05,730
+two enanchomars هذا المركب لو حاطيته لحاله بقول
+
+80
+00:07:05,730 --> 00:07:10,650
+عنه chiral بلف الضوء بزاوية معينة الآن ال
+
+81
+00:07:10,650 --> 00:07:14,530
+enanchomar التاني لو حاطيته في ال polarimeter برضه
+
+82
+00:07:14,530 --> 00:07:20,900
+chiral بنسميه بلف الضوء ولكن باتجاه معاكس إذا صار
+
+83
+00:07:20,900 --> 00:07:24,840
+عندى مركب chiral و مركب chiral طيب لو حطيت مركب من
+
+84
+00:07:24,840 --> 00:07:28,660
+الأساس مافيه chiral center بلفش الضوء وجدت ايش بدى
+
+85
+00:07:28,660 --> 00:07:34,840
+أسمي هذا المركب achiral هنا ال a بتصير أداة نفي
+
+86
+00:07:34,840 --> 00:07:38,840
+لاحظوا معناه .. لاحظوا معناه بتكونوا فاهمين شوية
+
+87
+00:07:38,840 --> 00:07:44,420
+باللغة الإنجليزية أدوات النكرة و أدوات المعرفة
+
+88
+00:07:44,420 --> 00:07:50,840
+يعني المركب هنا .. المركب هناكايرال ال a اللي
+
+89
+00:07:50,840 --> 00:07:56,260
+موجودة فيه هي أداة نكرة ولذلك إذا أنا مثلا بدي أجي
+
+90
+00:07:56,260 --> 00:08:00,340
+أحكي باللغة الإنقليزية أقول this is a chiral
+
+91
+00:08:00,340 --> 00:08:05,900
+compound معناه ذلك هذا مركب بلف الضوء ال a أداة
+
+92
+00:08:05,900 --> 00:08:09,880
+نكرة زي ما بنيجي نقول this is a table this is a
+
+93
+00:08:09,880 --> 00:08:14,220
+pen واضح الفكرة؟ الآن لو كنت بدي أحكي عن مركب زي
+
+94
+00:08:14,220 --> 00:08:20,470
+هذا شو بدي أقول عنه؟ أكايرل، الآن هنا أكايرل كلمة
+
+95
+00:08:20,470 --> 00:08:24,470
+واحدة لما بدي استعمل إلها أذات نكرة بالإنقليزي بدي
+
+96
+00:08:24,470 --> 00:08:31,670
+أحفظ قدامها أن صارت هذه الكلمة كلمة واحدة أكايرل
+
+97
+00:08:32,460 --> 00:08:35,220
+فالكلمة اللى عندى للمركب اللى بيكون optically
+
+98
+00:08:35,220 --> 00:08:40,180
+active كايران ال optically inactive أكايرة الكلمة
+
+99
+00:08:40,180 --> 00:08:43,580
+واحدة الآن حسب قواعد اللغة الإنجليزية ان هنا بتدخل
+
+100
+00:08:43,580 --> 00:08:49,040
+أداة ناكرة ال a و هنا بتدخل أداة ناكرة ال m فإذا
+
+101
+00:08:49,040 --> 00:08:53,180
+كنتوا بتسمعوا أو بتقرؤوا بتكونوا منتبهين لهذا
+
+102
+00:08:53,180 --> 00:09:00,100
+الكلام ال m طيب يا تورا لو أنا حطيت من ال two
+
+103
+00:09:00,100 --> 00:09:05,500
+enantiomers خليط متساوي يعني جبت كمية من ال
+
+104
+00:09:05,500 --> 00:09:08,700
+enantiomer الأول و كمية من ال enantiomer التاني و
+
+105
+00:09:08,700 --> 00:09:12,300
+حطيتهم مع بعض في ال polarimeter عملت منهم mixture
+
+106
+00:09:12,300 --> 00:09:18,120
+هذا الخليط المتساوي بيسموه racemic mixture فمعنى
+
+107
+00:09:18,120 --> 00:09:22,180
+racemic mixture او racemic modification هو خليط
+
+108
+00:09:22,180 --> 00:09:26,400
+متساوي من ال two enantiomers هل يا ترى هذا الخليط
+
+109
+00:09:26,400 --> 00:09:30,580
+المتساوي بكون optically active ولا optically
+
+110
+00:09:30,580 --> 00:09:37,700
+inactive؟ optically inactive، ليش؟ لأن واحد بيلف
+
+111
+00:09:37,700 --> 00:09:41,880
+الضوء يمين، التاني بيلف الضوء شمال، المحص لزفر
+
+112
+00:09:43,230 --> 00:09:48,550
+واضح؟ زي تماما ما بنيجي بنقول واحد بيبني واحد
+
+113
+00:09:48,550 --> 00:09:54,410
+بيهدم ايش في نهاية المحصلة؟ صفر متى يبلغ البنيانو؟
+
+114
+00:09:54,410 --> 00:10:00,630
+تماما هو أنت تبني وغيرك يهدم واضح الفكرة؟ ولذلك
+
+115
+00:10:00,630 --> 00:10:04,650
+إذا كان عندى خليط متساوي .. إذا كان عندى خليط
+
+116
+00:10:04,650 --> 00:10:11,560
+متساوي من ال two enansomers بتكون إيش؟ الخليط
+
+117
+00:10:11,560 --> 00:10:16,780
+chiral ولا achiral كله optically active ولا
+
+118
+00:10:16,780 --> 00:10:20,480
+optically inactive؟ optically inactive طبعا هنا
+
+119
+00:10:20,480 --> 00:10:26,740
+ممكن يجيني السؤال طب يا تورا لو كان عندي خليط بنسب
+
+120
+00:10:26,740 --> 00:10:28,300
+غير متساوية
+
+121
+00:10:30,330 --> 00:10:36,830
+يعني مثلا خلطت من ال isomer الموجب نسبة 70% من ال
+
+122
+00:10:36,830 --> 00:10:42,110
+isomer السالب نسبة 30% هذا الخليط
+
+123
+00:10:44,420 --> 00:10:50,400
+هيكون optically active هذا الخليط هيكون optically
+
+124
+00:10:50,400 --> 00:10:57,780
+active ولكن بشكل ايش؟ جزئي بشكل جزئي تماما زي ما
+
+125
+00:10:57,780 --> 00:11:01,460
+بنيجي نقول مثلا بني ادم الله ربح سبعين كذا خسر
+
+126
+00:11:01,460 --> 00:11:07,660
+تلاتين كده ش في النهاية؟ المربح 40 ولذلك هنا نسبة
+
+127
+00:11:07,660 --> 00:11:13,120
+الزيادة 40% موجب بنضربها في الزاوية الأصلية يعني
+
+128
+00:11:13,120 --> 00:11:18,780
+لو افترضت مثلا المركب النقي زاويته 20 هذه العشرين
+
+129
+00:11:18,780 --> 00:11:24,300
+للمركب الاش النقي لو وضعته زي ما هو وضعت أحد
+
+130
+00:11:24,300 --> 00:11:28,980
+الانانشومارز زاويته زائد عشرين الانانشومارز التاني
+
+131
+00:11:28,980 --> 00:11:34,690
+وضعته زاويته نقص عشرين طب لو عملت خليط من التنين
+
+132
+00:11:34,690 --> 00:11:38,430
+سبعين في المية موجب تلاتين في المية سالب هذا
+
+133
+00:11:38,430 --> 00:11:44,120
+الخليط كده هتكون الزاوية تبعته؟ لاحظوا انا في عندي
+
+134
+00:11:44,120 --> 00:11:49,360
+فرق اربعين في المية موجب هقول اربعين على مية ضرب
+
+135
+00:11:49,360 --> 00:11:53,360
+العشرين فالزاوية هتكون اقل من عشرين بالتأكيد
+
+136
+00:11:53,360 --> 00:11:59,540
+العشرين لأ النقي تماما لان انا عندي جزء من هذا جزء
+
+137
+00:11:59,540 --> 00:12:02,700
+اربعين في المية بس موجب فالاربعين في المية من
+
+138
+00:12:02,700 --> 00:12:09,990
+العشرين كده هتطلع نضربها تمانية فهذا الخليط زاوية و
+
+139
+00:12:09,990 --> 00:12:14,570
+هتكون تمانية الان موجب ولا سالب؟ بالتأكيد هتتبع
+
+140
+00:12:14,570 --> 00:12:18,170
+الأعلى يعني لو حطيت كمية كبيرة من الموجب و قليلة
+
+141
+00:12:18,170 --> 00:12:21,730
+من السالب فالخليط موجب يعني الإشارة على طول بنحطها
+
+142
+00:12:21,730 --> 00:12:26,650
+مابدهاش حساب واحد ربح كتير و خسر أقل فهو رابح واحد
+
+143
+00:12:26,650 --> 00:12:31,410
+خسر كتير و ربح أقل فهو خاسر الآن بتطلع أنا أعلى
+
+144
+00:12:31,410 --> 00:12:35,310
+الموجب ولا السالب؟ إذا الخليط اللي عندي موجب لكن
+
+145
+00:12:35,310 --> 00:12:40,060
+مش هيصل للموجب النقل مش هيصل لعشرين واضح؟ أنا بقول
+
+146
+00:12:40,060 --> 00:12:44,920
+هنا في عندي تلاتين سالبات بتشطبك بقالها تلاتين
+
+147
+00:12:44,920 --> 00:12:49,460
+موجبة بقى هدولة شطبوا بعض يعني كأنه في عندي تلاتين
+
+148
+00:12:49,460 --> 00:12:52,180
+في المية بيلفوا باتجاه و التلاتين باتجاه تاني
+
+149
+00:12:52,180 --> 00:12:55,220
+هدولة شطبوا بعض لما نشطب التلاتين السالبة مع
+
+150
+00:12:55,220 --> 00:12:59,180
+تلاتين قبالها موجبة جداش ضال عندي اربعين من
+
+151
+00:12:59,180 --> 00:13:03,540
+الموجبة اربعين على مية ضارب عشرين بنقدر نحسب كمان
+
+152
+00:13:03,540 --> 00:13:09,780
+زاوية الخليط اذا دائما و ابدا زاوية الخليط اقل ولا
+
+153
+00:13:09,780 --> 00:13:14,380
+اكثر من الزاوية النقية اقل لاحظوا معي لو هالخليط
+
+154
+00:13:14,380 --> 00:13:22,640
+وصل خمسين و خمسين عندما تصبح زاويته صفر رسمك
+
+155
+00:13:22,640 --> 00:13:28,760
+ميكس شرف او رسمك موديفيكشن الخمسين وخمسين شطبوا بعض
+
+156
+00:13:28,760 --> 00:13:35,220
+تماما زي إنسان ربح خمسين دينار الصبح وخسر خمسين
+
+157
+00:13:35,220 --> 00:13:40,620
+دينار آخر النهار، إيش بيروح؟ صفر، لفنا خمسين موجب
+
+158
+00:13:40,620 --> 00:13:43,820
+و بعدين خمسين سلم، بنينا خمسين حجر و هدينا خمسين
+
+159
+00:13:43,820 --> 00:13:50,950
+حجر، شو المحصلة؟ صفر، واضح؟ هذا بالنسبة لمعنى
+
+160
+00:13:50,950 --> 00:13:54,770
+كايرال موليكيول و أكايرال موليكيول و راسيمك ميكشر
+
+161
+00:13:54,770 --> 00:13:58,570
+ولذلك يجب أن تكونوا مميزين أن كلمة كايرال مرت معنى
+
+162
+00:13:58,570 --> 00:14:03,450
+في كام اتجاه كايرال كاربون معناها أربع مجموعات
+
+163
+00:14:03,450 --> 00:14:09,230
+مختلفة كايرال موليكيول معناه بلوف الضوء معناه بلوف
+
+164
+00:14:09,230 --> 00:14:15,950
+الضوء هذا الكلام كله متعلق بقصة ال rotation وهو
+
+165
+00:14:15,950 --> 00:14:19,970
+خاصية فيزيائية بالمناسبة معنى خاصية فيزيائية ان
+
+166
+00:14:19,970 --> 00:14:22,810
+انا لو بعد ما خدتها المركب وحطيته في ال
+
+167
+00:14:22,810 --> 00:14:26,690
+polarimeter وعملت كل القياسات باسترده زي ما هو ولا
+
+168
+00:14:26,690 --> 00:14:31,610
+لأ انا ماعملت عليه تفاعل هذا الكلام بيقودنا مباشرة
+
+169
+00:14:31,610 --> 00:14:36,770
+لشغلتانية ال enantiomersiatura من ناحية الخواص
+
+170
+00:14:36,770 --> 00:14:43,360
+الكيميائية هل بيختلفوا ولا لأ يعني ال chemical
+
+171
+00:14:43,360 --> 00:14:48,580
+properties of enantiomers الخواص الكيميائية لل
+
+172
+00:14:48,580 --> 00:14:54,020
+enantiomers أسهل شيء ممكن نفهم من خلاله الموضوع
+
+173
+00:14:54,020 --> 00:14:59,560
+أسهل شيء ممكن نفهم من خلاله الموضوع عارفين شو هو؟
+
+174
+00:14:59,560 --> 00
+
+223
+00:18:51,250 --> 00:18:55,700
+ال R في مركب رابع ال S حسب طبيعة إيش الدواء الآن
+
+224
+00:18:55,700 --> 00:18:59,480
+بيصير السؤال طيب إذا هذا هو المركب الفعال اللى
+
+225
+00:18:59,480 --> 00:19:04,420
+يستخدم كعلاج المركب الثاني شو بده يكون؟ ممكن يكون
+
+226
+00:19:04,420 --> 00:19:09,780
+عديم الفائدة يعني حضوره زي غيابه لا يؤذي ولا يضر و
+
+227
+00:19:09,780 --> 00:19:15,480
+ممكن يكون مؤذى و مضر و يعمل مشاكل الآن تعون
+
+228
+00:19:15,480 --> 00:19:21,060
+الكيميا بيشتغلوا بالشكل القاتل إذا مركب منهم دواء و
+
+229
+00:19:21,060 --> 00:19:24,980
+التاني لا يضر بدل ما يفصلوهم انتوا لاحظوا لما حض
+
+230
+00:19:24,980 --> 00:19:28,870
+المركب طلعوا عندي خليط من الاثنين نتعلم انه لما
+
+231
+00:19:28,870 --> 00:19:32,970
+نحضر الدواء بيطلع الثاني خليط عملية الفصل عملية
+
+232
+00:19:32,970 --> 00:19:37,570
+صعبة و مكلفة ماديا كتير الآن من هدولة مين المفيد
+
+233
+00:19:37,570 --> 00:19:42,550
+خلينا نفترض هذا enantiomer التاني إذا كان مابضرش
+
+234
+00:19:42,550 --> 00:19:47,110
+سيبه معه بيأكلوا البني آدم و بيخرجوا من البني آدم
+
+235
+00:19:47,110 --> 00:19:52,640
+بدون ما يؤدي لأي ضرر بيعطوا الدواء وبيعطوا الثاني،
+
+236
+00:19:52,640 --> 00:19:56,700
+هم عارفين ان هذا الثاني مش هيضر .. ان هذا الثاني
+
+237
+00:19:56,700 --> 00:20:00,820
+مش هيضر هذا الكلام بالمناسبة مثلا بيعملوه في دواء
+
+238
+00:20:00,820 --> 00:20:06,020
+زي الابوبروفين ربما انتوا لما مر علينا جزء
+
+239
+00:20:06,020 --> 00:20:10,380
+الابوبروفين متذكرينه؟ و انا هفرجيكوا إياه في ال
+
+240
+00:20:10,380 --> 00:20:14,540
+aromatic compounds ارجعولهلو اتطلعتوا على
+
+241
+00:20:14,540 --> 00:20:18,000
+الابوبروفن او الاتروفن هتلاقوا فيه chiral center
+
+242
+00:20:18,000 --> 00:20:22,340
+فيه منه اتنين لان واحد منهم مفيد و بضيع الصداع
+
+243
+00:20:22,340 --> 00:20:28,000
+الثاني مالوش تأثير واضح بيسيبوه مع بعض و بيعطوا
+
+244
+00:20:28,000 --> 00:20:31,400
+البني ادم اللي هو يستفيد من المفيد و يخرج الآخر
+
+245
+00:20:31,400 --> 00:20:36,630
+لمصيبة الكبيرة وين بتصير؟ لو كان واحد منهم مفيد
+
+246
+00:20:36,630 --> 00:20:43,010
+والتاني ضار يجب حينها أن يفصل فصلا كاملا الضار
+
+247
+00:20:43,010 --> 00:20:48,730
+ويعطى الإنسان المفيد واضحة الفكرة؟ إذا أغلطنا بهذه
+
+248
+00:20:48,730 --> 00:20:53,210
+الشغلة، إيش حيصير فينا؟ حيصير فينا المقاس التالية
+
+249
+00:20:53,210 --> 00:20:57,750
+هذا مقال كتباه
+
+250
+00:21:03,190 --> 00:21:10,030
+دكتورة عن عقار هذا العقار ربما موجود هنا اسمه
+
+251
+00:21:10,030 --> 00:21:19,430
+الثاليدو أميد هذا قصته في الكيميا قصة مشهورة
+
+252
+00:21:19,430 --> 00:21:26,750
+كتير هذا هو العقار الثاليدو أميد الآن هذا الثاليدو
+
+253
+00:21:26,750 --> 00:21:32,540
+أميد في Cairo Center هنا واحدة يعني لما نطلع في
+
+254
+00:21:32,540 --> 00:21:37,140
+الشكل تبعه فيه chiral center واحدة إذا صار فيه منه
+
+255
+00:21:37,140 --> 00:21:46,100
+مركب R وصار منه مركب S الآن المركب R مفيد ولمين
+
+256
+00:21:46,100 --> 00:21:50,300
+المركب R مفيد تقريبا اخترع هذا الدواء في سنة 1953
+
+257
+00:21:50,300 --> 00:21:56,940
+للنساء الحوامل بضيع عندهم الصداع المصاحب للحمل نزل
+
+258
+00:21:56,940 --> 00:22:01,600
+السوق بدون ما تستكمل الدراسات الكاملة عليه في آخر
+
+259
+00:22:01,600 --> 00:22:07,920
+الخمسينات طلعت المصيبة أن المركب التاني الـ S هذا
+
+260
+00:22:07,920 --> 00:22:12,300
+بيخترق المشيمة و بيأثر على الأجنة اللي في بطون
+
+261
+00:22:12,300 --> 00:22:17,190
+الأمهات لأنهم بياخدوا الأمهات الحوامل عشان الصداع
+
+262
+00:22:17,190 --> 00:22:21,750
+ما انتبهوش ما استكملوش الدراسات تبع الدواء فطلع
+
+263
+00:22:21,750 --> 00:22:26,350
+المركب الثاني بأثر على الأجنة، الآن عدد كبير من
+
+264
+00:22:26,350 --> 00:22:31,350
+النساء استعملوا بدأت أوروبا تتواجه بالأجنة
+
+265
+00:22:31,350 --> 00:22:36,920
+المشوهين تقريبا سنة و نص سنتين ستين و واحد و ستين
+
+266
+00:22:36,920 --> 00:22:41,000
+نهاية التسعة و خمسين مباشرة من أول ما انتبهولها مع
+
+267
+00:22:41,000 --> 00:22:45,360
+الواحد و ستين أوقفوا استعمال الدواء على طول لكن
+
+268
+00:22:45,360 --> 00:22:49,960
+بعد ما طلع عندهم جيل كامل من الأطفال المشواهين
+
+269
+00:22:49,960 --> 00:22:54,520
+ملمش أيديهم فقط لغلطة زي هيك انه كانوا يعطوا
+
+270
+00:22:54,520 --> 00:23:00,400
+الدواء و معاه enantiomer .. enantiomer إيش
+
+271
+00:23:00,400 --> 00:23:06,980
+اتضارت و ربما لو الصورة واضحة عندكم في أسماء
+
+272
+00:23:06,980 --> 00:23:12,780
+مشهورة في هذا المجال يعني هذا الإنسان يمكن مش واضح
+
+273
+00:23:12,780 --> 00:23:17,480
+كده بس اتطلعوا الأيدين بتاعونه بصار جدا الأيدين
+
+274
+00:23:17,480 --> 00:23:23,060
+بتاعونه اتطلعوا عليه بالصور بالنت بتنبسطوا، بتلاقوا
+
+275
+00:23:23,060 --> 00:23:28,240
+كتير، ليش؟ لأن هذا مذيع مشهور جدا، مذيع مشهور جدا
+
+276
+00:23:28,240 --> 00:23:34,420
+في ال BBC ومحرر أخبار في النهاية اسمه Adams Spank
+
+277
+00:23:34,420 --> 00:23:38,780
+Adams Spank اللي بدهم يقرأوا عن قصته Adams Spank
+
+278
+00:23:38,780 --> 00:23:44,790
+موليد ال 61يعني الحامل صار في الستين الأم أخدت
+
+279
+00:23:44,790 --> 00:23:49,150
+الدواء هو موليد الواحد والستين بدون إيدين وبعين
+
+280
+00:23:49,150 --> 00:23:55,430
+يعني فيها إيش عوى كذلك الحال لو بدأ أطلع على أسماء
+
+281
+00:23:55,430 --> 00:24:00,790
+تانية هاي Adams Smug شايفين العين هنا شوية ما فيش
+
+282
+00:24:00,790 --> 00:24:09,710
+إيدين هذا بني آدم مش بدخل سيجارة هذا برسم الريشة
+
+283
+00:24:09,710 --> 00:24:15,170
+في تمه لأنه ما لوش إيدين رسم شهير ويله معارض شهيرة
+
+284
+00:24:15,170 --> 00:24:19,670
+برضه موليد ال واحد و ستين من غلطة زي هذه برضه
+
+285
+00:24:19,670 --> 00:24:23,650
+موليد ال واحد و ستين و هي المعرض الفني تبعه و هذا
+
+286
+00:24:23,650 --> 00:24:28,950
+بامالي الكوجادرين اللي تشوفوه هذا بيعزف ع الجثار
+
+287
+00:24:28,950 --> 00:24:36,790
+برجله ليش؟ برضه لأنه ما لوش أطراف ما لوش إيدين إيدين
+
+288
+00:24:36,790 --> 00:24:43,050
+و غير الإيدين كمان إيدين و عينينو جوزي أنتونيو
+
+289
+00:24:43,050 --> 00:24:47,130
+عازف شهير جدا من نيكاراجوا و ربما البعض سمع له
+
+290
+00:24:47,130 --> 00:24:52,480
+موسيقى عازف مشهور هدولة كلهم عايشين ولذلك من سنين
+
+291
+00:24:52,480 --> 00:24:56,640
+بسيطة الألمان عملوا فيلم عن هذا الموضوع واحتجوا
+
+292
+00:24:56,640 --> 00:25:01,980
+الشعب الألماني ليش؟ لأنه ذكروهم بالمقساة اللي مرت
+
+293
+00:25:01,980 --> 00:25:06,160
+في عام واحد وستين اتنين وستين مقسات الأجنة
+
+294
+00:25:06,160 --> 00:25:10,340
+المشوهين كل هذا الكلام لأن استعملنا الدواء الغلط
+
+295
+00:25:10,340 --> 00:25:16,090
+الفكرة ببساطة مرة ثانية تشبه قصة المفتاح والذرفيل
+
+296
+00:25:16,090 --> 00:25:20,990
+الذرفيل كايرة الفراغي بيده مفتاح معين يتطابق معاه
+
+297
+00:25:20,990 --> 00:25:27,670
+نجيب المفتاح التاني مابفتحش مستفدناش اشي و لذلك في
+
+298
+00:25:27,670 --> 00:25:34,970
+الخواص الكيميائية enantiomers لهم نفس الخواص
+
+299
+00:25:34,970 --> 00:25:40,840
+الكيميائية ما عدا إذا اتفعلوا مع مركبات فراغية زيهم
+
+300
+00:25:40,840 --> 00:25:45,680
+يعني لما بتفعل chiral مع chiral شيء ماخد
+
+301
+00:25:45,680 --> 00:25:49,000
+اتجاه فراغي شمال او يمين مع شيء ماخد اتجاه فراغي
+
+302
+00:25:49,000 --> 00:25:52,880
+شمال او يمين بيصير الاختلاف زي الذرفيل بتاع الباب
+
+303
+00:25:52,880 --> 00:25:57,820
+في شمال ويمين جوا والمفتاح في شمال ويمين بيصير
+
+304
+00:25:57,820 --> 00:26:04,160
+مفتاح معين لذرفيل معين واحد تاني مابظبطش او بايدي
+
+305
+00:26:04,160 --> 00:26:08,340
+الى مشاكل ولذلك في الخواص الكيميائية المحاصلة اللي
+
+306
+00:26:08,340 --> 00:26:12,500
+بنقولها ان enantiomers they have the same
+
+307
+00:26:12,500 --> 00:26:16,780
+chemical the same chemical properties except when
+
+308
+00:26:16,780 --> 00:26:19,880
+they react with other chiral molecules لما يصير
+
+309
+00:26:19,880 --> 00:26:24,630
+التفاعل بين chiral و chiral وجعت المشكلة واضحة
+
+310
+00:26:24,630 --> 00:26:31,030
+الفكرة؟ هذا كلام عام جدا لكن بحياتكوا .. يعني بأمل
+
+311
+00:26:31,030 --> 00:26:34,990
+أنه هتصيروا تشوفوا كتير هذه المسميات هتصيروا
+
+312
+00:26:34,990 --> 00:26:38,730
+تقرأوا كتير على الأدوية مكتوب عليها R و بين جثين
+
+313
+00:26:38,730 --> 00:26:42,330
+موجة بقى أو سالب و S و بين جثين موجة بقى أو سالب
+
+314
+00:26:42,330 --> 00:26:52,230
+فنكون عارفين كل هذه المصطلحات فليدو أمد فليدو
+
+315
+00:26:56,400 --> 00:27:03,260
+ثليده أمن لو قرأته قصة الثليده أمن قصة كبيرة جدا
+
+316
+00:27:03,260 --> 00:27:09,540
+بلاش ممكن نروح على شغلة ثانية بسيطة جدا ربما مرت
+
+317
+00:27:09,540 --> 00:27:19,740
+عليكم كتير مر عليكم هذا اللي موجود هنا في الصورة
+
+318
+00:27:19,740 --> 00:27:27,120
+قادرين تشوفوه الفطر الفطر تبع البيتزا، الان متعودين
+
+319
+00:27:27,120 --> 00:27:31,500
+تقولوا ان الفطر في منه كويس و في منه سام، مظبوط؟
+
+320
+00:27:31,500 --> 00:27:37,820
+الان الكويس والسام فيهم نفس المركب، نفس المركب،
+
+321
+00:27:37,820 --> 00:27:42,880
+تحديدا من ناحية كيميائية هذا هو المركب، واضح؟ من
+
+322
+00:27:42,880 --> 00:27:44,040
+ناحية كيميائية
+
+323
+00:27:47,540 --> 00:27:52,000
+هذا هو المركب، شايفينه؟ هاي المركب، الآن هذا
+
+324
+00:27:52,000 --> 00:27:59,860
+المركب في chiral center واحد، هذا واحد
+
+325
+00:27:59,860 --> 00:28:08,010
+منهم بيكون كويس والتاني بيكون poisonous، سام فقط
+
+326
+00:28:08,010 --> 00:28:12,330
+بيختلفوا بال chiral center يعني نفس الجزء هذا اللي
+
+327
+00:28:12,330 --> 00:28:17,110
+بنسميه one octane three all ال R منه اللي كويس و
+
+328
+00:28:17,110 --> 00:28:22,590
+التاني ال S و انتوا دائما كانوا يحذروكوا في دراسة
+
+329
+00:28:22,590 --> 00:28:27,330
+النبات و انه احذروا الفطر اللي بيكون عادة شكله زي
+
+330
+00:28:27,330 --> 00:28:32,650
+المثلث يعني الفطر العادي هذا ال okay هذا عامل
+
+331
+00:28:32,650 --> 00:28:37,240
+مشكلة الآن هذولا فيهم نفس ال هوركنفس المركب اللي
+
+332
+00:28:37,240 --> 00:28:41,080
+خله مركب كويس ومركب سام انه هذا enantiomer وهذا
+
+333
+00:28:41,080 --> 00:28:45,660
+enantiomer ثاني شوفوا هذا الفرق البسيط جدا اللي
+
+334
+00:28:45,660 --> 00:28:49,740
+بمرهانة قعد يؤثر على الأدوية ويؤثر على حياة الناس
+
+335
+00:28:49,740 --> 00:28:54,120
+هو فرق أساسي في فهم الكيمياء ولذلك يعني ال stereo
+
+336
+00:28:54,120 --> 00:28:59,980
+chemistry مش قصة يعني قصة شيء أحيانا صعب أو شيء
+
+337
+00:28:59,980 --> 00:29:05,490
+ممتع على جانب لإن فيه صميم فهم الكيمياء و في صميم
+
+338
+00:29:05,490 --> 00:29:11,470
+فهم الأدوية ان نكون فاهمين هذه الأمور المتعلقة بال
+
+339
+00:29:11,470 --> 00:29:18,890
+stereo chemistry طبعا الانسان كل ما بيتعب من شغلة
+
+340
+00:29:18,890 --> 00:29:24,270
+بيقول واجتاش بدنا نخلص من الشغلة اول ما بيحس انه
+
+341
+00:29:24,270 --> 00:29:30,310
+بده يخلص من الشغلة بيكتشف نقطة بسيطة جدا ان هو لسه
+
+342
+00:29:30,310 --> 00:29:36,330
+ماخدش من الموضوع نقطة اول ما بيحس أنه جربنا نخلص من
+
+343
+00:29:36,330 --> 00:29:40,950
+هالشغلة هو ما أخدش من الموضوع نقطة، ليش؟ لأنه أنا
+
+344
+00:29:40,950 --> 00:29:47,670
+تكلمت عن جزء في chiral centers واحد، قولت بيقدّي
+
+345
+00:29:47,670 --> 00:29:52,990
+لكم enantiomer؟ إتنين، طيب يا تورة الآن لو أجيت و
+
+346
+00:29:52,990 --> 00:29:58,350
+أتكلمت عن chiral centers ال chiral centers
+
+347
+00:29:58,350 --> 00:30:02,190
+وال enantiomer
+
+348
+00:30:02,190 --> 00:30:12,790
+او ال products ال stereo isomers لما
+
+349
+00:30:12,790 --> 00:30:17,690
+كان في عندي one chiral center كم واحد كانوا؟ طب يا
+
+350
+00:30:17,690 --> 00:30:19,910
+تورا لو صاروا اتنين، لو صاروا تلاتة، لو صاروا
+
+351
+00:30:19,910 --> 00:30:23,490
+أربعة، لو صاروا خمسة، لو صاروا ستة، كده بده يصير
+
+352
+00:30:23,490 --> 00:30:28,180
+عندي؟ يعني جزء فيه تلاتة اربعة خمسة chiral centers
+
+353
+00:30:28,180 --> 00:30:33,060
+في عندي علاقة بتقوللي ال maximum possible number
+
+354
+00:30:33,060 --> 00:30:40,680
+of stereoisomers two to the N بحيث انه هذي إيش ال
+
+355
+00:30:40,680 --> 00:30:51,790
+N اتنين اقصى واحد اتنين اقصى اتنين اربعة 2-3 8 2-4 16
+
+356
+00:30:51,790 --> 00:30:59,050
+2-5 32 لما يبدأ يجينا مركب في خمسة chiral centers
+
+357
+00:30:59,050 --> 00:31:06,510
+هنكتشف أنه في منه 32 isomers هذول 32 isomers ممكن
+
+358
+00:31:06,510 --> 00:31:10,990
+واحد منهم يكون مفيد و بنستفيد منه والواحد و
+
+359
+00:31:10,990 --> 00:31:15,200
+التلاتين التانين بقابله لاحظوا قداش الكلام بيصير
+
+360
+00:31:15,200 --> 00:31:20,440
+مرهق وهذا الكلام هيمر معكم على سبيل المثال الخامسة
+
+361
+00:31:20,440 --> 00:31:27,400
+لما ندرس ال biochemistry السكر اللي مكون من ست
+
+362
+00:31:27,400 --> 00:31:32,500
+درات كربون لما يكون في الشكل الحلقي في خمسة chiral
+
+363
+00:31:32,500 --> 00:31:39,340
+centers في منه اتنين و تلاتين isomers تخيلوا أنه
+
+364
+00:31:39,340 --> 00:31:44,700
+بدنا نتعلم لما نيجي ناخد السكر السداسي الماخد
+
+365
+00:31:44,700 --> 00:31:52,800
+الصيغة العامة C6H12O6 بدنا نرسم مش مركب واحد اتنين
+
+366
+00:31:52,800 --> 00:31:58,220
+و تلاتين مركب و نعرفهم و نميزهم بالاسم الان لما
+
+367
+00:31:58,220 --> 00:32:01,420
+المريض بيروح على المستشفى لما المريض بيروح على
+
+368
+00:32:01,420 --> 00:32:04,760
+المستشفى و بيقولوا بدنا نعطيه محلول سكر بتعرفوا
+
+369
+00:32:04,760 --> 00:32:10,490
+بيعطيه واحد من الاتنين و تلاتين واحد من ال 32 هدولة
+
+370
+00:32:10,490 --> 00:32:16,370
+واضح و الباقي مش هم اللي بيعطيها فالموضوع بيصير
+
+371
+00:32:16,370 --> 00:32:21,790
+بهذا الشكل كبير طبعا اللي بده يتدرج في الكلام يبدأ
+
+372
+00:32:21,790 --> 00:32:26,190
+يعطي مثال على اتنين chiral centers الآن انا هنا
+
+373
+00:32:26,190 --> 00:32:31,390
+مابقولش ان هذا عدد ال isomers بقول هذا ال maximum
+
+374
+00:32:31,390 --> 00:32:38,340
+possible يعني هذا أعلى ما يمكن من ال isomers بس
+
+375
+00:32:38,340 --> 00:32:44,130
+ممكن يكون أقل منه يعني لما بيكون فيه اتنين chiral
+
+376
+00:32:44,130 --> 00:32:48,710
+centers ممكن يكون عنده العدد الأقصى أربعة و مرات
+
+377
+00:32:48,710 --> 00:32:53,490
+بيكونوا تلاتة و هكذا ممكن يقولوا واحد ما بدناش
+
+378
+00:32:53,490 --> 00:32:58,790
+نتجاوز بس التلين يعني بدنا نشرح مثالين مثال لما
+
+379
+00:32:58,790 --> 00:33:02,790
+يكون عنده two chiral centers و عنده أربعة isomers
+
+380
+00:33:02,790 --> 00:33:07,230
+و مثال لما بيكون عنده two chiral centers بس ال
+
+381
+00:33:07,230 --> 00:33:11,430
+isomers تلاتة يعني بيطلع منهم في هذه الحالة اتنين
+
+382
+00:33:11,430 --> 00:33:16,710
+طلعوا شبه بعض نفس الأشياء واضحة فبيصير الدارس تبعنا
+
+383
+00:33:16,710 --> 00:33:23,630
+المركبات اللي فيها أكتر من chiral centers والمثال
+
+384
+00:33:23,630 --> 00:33:26,770
+اللي بدنا نبدأ فيه لما يكون عندي two chiral
+
+385
+00:33:26,770 --> 00:33:32,650
+centers او centers لاحظوا ان هذا الكلام بيجيبنا
+
+386
+00:33:32,650 --> 00:33:41,000
+لنقطة ان انتوا لما بتتعلموا العلم بتتعلموا كيف بنوع
+
+387
+00:33:41,000 --> 00:33:46,340
+من البساطة بتتعلموا بنوع من البساطة في الأول يعني
+
+388
+00:33:46,340 --> 00:33:52,420
+بنعطيكوا جزء من العلم وبنخبي عنكم أجزاء بنعطيكوا
+
+389
+00:33:52,420 --> 00:33:57,340
+جزء وبنخبي عنكم أجزاء يعني لو جيبت سؤال احنا
+
+390
+00:33:57,340 --> 00:34:00,680
+اتعودنا ان نجاوبه وممكن اعطيتكوا ياهو ميركو سلمته
+
+391
+00:
+
+445
+00:38:14,080 --> 00:38:17,660
+تحطوا هنا و هنا تخيلوا لما تحطوا هنا CL ما زال
+
+446
+00:38:17,660 --> 00:38:24,300
+عندكم CH2 مش chiral و CH2 و CH2 و CH2 و هنا CH2CL
+
+447
+00:38:24,300 --> 00:38:29,860
+مش chiral اذا لو انا جبتلكوا سؤال ال one five
+
+448
+00:38:29,860 --> 00:38:36,100
+dichlorobentane has two stereoisomers طلعوا معاه
+
+449
+00:38:36,100 --> 00:38:41,170
+هي كلور هي كلورشوفوا هنا كم كايرال سنتر فيه
+
+450
+00:38:41,170 --> 00:38:45,250
+CH2H2H2H2
+
+451
+00:38:45,250 --> 00:38:49,210
+ولا كايرال سنتر إذا ال 1,5 ده يكلوره بين 2 فيه
+
+452
+00:38:49,210 --> 00:38:53,710
+مركب واحد لكن لو أنا كنت مثلا باجي بسألكم ال 1,2
+
+453
+00:38:53,710 --> 00:39:03,210
+هيكلور أكيد هنا H هنا CL هتكون مكملة H2 HH صح ولا
+
+454
+00:39:03,210 --> 00:39:10,610
+لأ هذا كم مركب منه 2لأ و هذا مش chiral هذا بس one
+
+455
+00:39:10,610 --> 00:39:19,370
+chiral center فيه هذا مش chiral هذا CH2 و هذه H2 و
+
+456
+00:39:19,370 --> 00:39:23,590
+هذه H2 و هذه H3 one chiral center إذا ال one two
+
+457
+00:39:23,590 --> 00:39:29,710
+dichloro بينتين في منه كام مركب اتنين ارقص الآن لو
+
+458
+00:39:29,710 --> 00:39:34,070
+إجيت لواحد من هدول المجموعة و اتأملوا جيدا
+
+459
+00:39:36,880 --> 00:39:44,160
+وقلنا لكوا سمونا المركب التالي هذا
+
+460
+00:39:44,160 --> 00:39:48,040
+اتنين
+
+461
+00:39:48,040 --> 00:39:49,540
+ثلاثة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+462
+00:39:49,540 --> 00:39:49,620
+تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+463
+00:39:49,620 --> 00:39:50,060
+تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+464
+00:39:50,060 --> 00:39:50,980
+تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+465
+00:39:50,980 --> 00:39:56,440
+تلاتة اتنين تلاتة
+
+466
+00:39:56,440 --> 00:39:56,780
+اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة
+
+467
+00:39:56,780 --> 00:40:01,900
+اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين ت
+
+468
+00:40:05,330 --> 00:40:10,730
+هذه حملة مثل و H و CL و مجموعة كبيرة إذا هذه كايرا
+
+469
+00:40:10,730 --> 00:40:16,690
+و هذه حملة كلور و H و CH2 و CH3 و CHCL و CH3 أربع
+
+470
+00:40:16,690 --> 00:40:21,990
+مجموعات كايرا two chiral centers maximum بنتوقع
+
+471
+00:40:21,990 --> 00:40:26,650
+أربعة و حقيقة هنكتشف إن هدولة أربع مركبات
+
+472
+00:40:30,150 --> 00:40:34,470
+اللي كنا بنفكره و بنكتب ان هو مراكب واحد ال two
+
+473
+00:40:34,470 --> 00:40:38,330
+three dichlorobentain هتلاحظوا انه اربع مراكبات
+
+474
+00:40:38,330 --> 00:40:41,250
+يعني لو روحتوا على الدكانة تشتريوا two three
+
+475
+00:40:41,250 --> 00:40:43,570
+dichlorobentain لو سمحت بيعلى two three
+
+476
+00:40:43,570 --> 00:40:47,270
+dichlorobentain بيفتش مابلاقيش مراكب في الكون هيك
+
+477
+00:40:47,270 --> 00:40:51,250
+لو واحده اسمه two three dichlorobentain هيلاقيهم
+
+478
+00:40:51,250 --> 00:40:58,190
+اسمهم ROR SOS ROS SOR هتقولوا كيف هدولة ابن اتعلم
+
+479
+00:41:03,030 --> 00:41:07,570
+نرسمهم الان متشوقين انكوا تشوفوا شو مع الاربع
+
+480
+00:41:07,570 --> 00:41:13,150
+مركبات العملية بسيطة اتطلعوا مع هاي البنتين carbon
+
+481
+00:41:13,150 --> 00:41:20,730
+CH3 CH حملة CL CH حملة CL و إثل يعني CH2 CH3 ع
+
+482
+00:41:20,730 --> 00:41:24,960
+موقع اتنين وع موقع تلتة عندكم كلور ولا لأهي على
+
+483
+00:41:24,960 --> 00:41:29,560
+اتنين كلور و على تلاتة كلور الان حطوهم عكس بعض و
+
+484
+00:41:29,560 --> 00:41:34,100
+اعملوا صورتهم في المرايا صار هذا مركب و هذا مركب
+
+485
+00:41:34,100 --> 00:41:40,800
+غير متطابقين على بعض و حطوهم جنب بعض الكلور شايفين
+
+486
+00:41:40,800 --> 00:41:46,080
+الكلور عكس بعض و صورتهم في المرايا جنب بعض و
+
+487
+00:41:46,080 --> 00:41:52,520
+صورتهم في المراياكام مراكب صاروا؟ أربعة، الآن كل
+
+488
+00:41:52,520 --> 00:41:55,240
+اللي موجود عند الأربع مراكبات اسمهم two three
+
+489
+00:41:55,240 --> 00:41:59,000
+dichlorobentane باجي بسمي من هنا واحد اتنين تلاتة
+
+490
+00:41:59,000 --> 00:42:05,760
+اربعة لما بدي اقول هذا اتنين بدي احددها R ولا S و
+
+491
+00:42:05,760 --> 00:42:11,360
+تلاتة بدي احددها R ولا Sبسأل نفسي وين أقل مجموعة
+
+492
+00:42:11,360 --> 00:42:16,680
+على اتنين انا امركز الان على اتنين ال H شطبناها
+
+493
+00:42:16,680 --> 00:42:23,420
+قول انا على الجانب هنعكس الان عندكم Cl و Carbon و
+
+494
+00:42:23,420 --> 00:42:27,740
+CH3 طبعا هذه ال Carbon حملة Cl و هذه الحملة H اذا
+
+495
+00:42:27,740 --> 00:42:47,970
+كيف همشيأس أس أس أس أس أس أس أس أس أس أس
+
+496
+00:42:47,970 --> 00:42:54,580
+أس أس أس أس أس أس أس أس أس أس أس أسالـ H و الأعلى
+
+497
+00:42:54,580 --> 00:43:02,700
+مجموعة الـ Cl بعدها الكربون اللي حمله Cl بعدها هذه
+
+498
+00:43:02,700 --> 00:43:08,840
+الـ Ethyl CH2 CH3 أنا أعلى كربون بتحمل Cl ولا
+
+499
+00:43:08,840 --> 00:43:13,200
+كربون بتحمل H و H و C كربون بتحمل Cl مش فيها نقاش
+
+500
+00:43:13,200 --> 00:43:18,790
+الآن هاي واحد هذه كلها كمجموعة اتنينهذه تلات
+
+501
+00:43:18,790 --> 00:43:24,710
+مجموعات هذي واحد هذي اتنين هذي تلاتة ال R لما نمشي
+
+502
+00:43:24,710 --> 00:43:30,870
+بهذا الشكل واحد اتنين تلاتة شو مبينه بكتب 3R هذول
+
+503
+00:43:30,870 --> 00:43:36,090
+عكسهم هتلاقوهم 2S 3S بإمكانكوا في البيت الأن
+
+504
+00:43:36,090 --> 00:43:43,020
+تروحوا تحددوا كل هذه المواقعاعملوهم بهدوء هتلاحظوا
+
+505
+00:43:43,020 --> 00:43:47,080
+ان الأربع مركبات اللي موجودة هنا الاربع مركبات
+
+506
+00:43:47,080 --> 00:43:50,600
+اللي موجودة هنا two R ثري R وصورته في المرايا two
+
+507
+00:43:50,600 --> 00:43:55,060
+S ثري S دابن الصورة في المرايا أشمالها عكس يعني ال
+
+508
+00:43:55,060 --> 00:43:59,740
+R أقبالها S و ال R أقبالها S و بعدين ال two R ثري
+
+509
+00:43:59,740 --> 00:44:04,340
+S و أقبالها two S three R يعني ال two R two S و ال
+
+510
+00:44:04,340 --> 00:44:09,760
+three S three R مش أنا قولت كل نقطةعكس التانية في
+
+511
+00:44:09,760 --> 00:44:14,620
+المراية هل يترفيب هذه الرموز أي رمزين متشابهين؟
+
+512
+00:44:14,620 --> 00:44:20,680
+إذا هدولة كام مركبة؟ أربع مركبات اتخيلوا عاد لو
+
+513
+00:44:20,680 --> 00:44:24,960
+واحد من هدولة الدوة و الباقين بضره أنه أنا اللي
+
+514
+00:44:24,960 --> 00:44:29,060
+بدي استعمله، هنفترض أن الدوة كان 2S 3S، بس هذا
+
+515
+00:44:29,060 --> 00:44:33,530
+اللي بدي استعمله، هذا لأ، هذا لأ، هذا لأواضحة
+
+516
+00:44:33,530 --> 00:44:36,830
+الفكرة شوما الأربع مركبات المرة الجاية ان شاء الله
+
+517
+00:44:36,830 --> 00:44:41,450
+انطلاقا من هذه النقطة بشرط تكونوا اتدربتوا على
+
+518
+00:44:41,450 --> 00:44:45,570
+تسمية المركبات وعلى تحديد ال chiral centers بشكل
+
+519
+00:44:45,570 --> 00:44:48,950
+أكبر بنستمر انطلاقا من هذه النقطة
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..96706e81a5bccd271205b0808ba9abc29ebba8e0
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_raw.srt
@@ -0,0 +1,2084 @@
+1
+00:00:20,690 --> 00:00:23,670
+بسم الله الرحمن الرحيم، في موضوع الـ
+
+2
+00:00:23,670 --> 00:00:27,290
+Stereochemistry، آخر شغلة أتكلمنا عنها
+
+3
+00:00:30,440 --> 00:00:36,360
+كانت موضوع الخواص الفيزيائية ربما لل enantiomers
+
+4
+00:00:36,360 --> 00:00:41,000
+وقولنا ان ال enantiomers بيشتركوا في كل الخواص
+
+5
+00:00:41,000 --> 00:00:47,360
+الفيزيائية ما عدا خاصية ال rotation of polarized
+
+6
+00:00:47,360 --> 00:00:53,460
+light تدوير الضوء المستخدم في المستوى طبعا شرحنا
+
+7
+00:00:54,200 --> 00:00:59,300
+بشكل مبسط جهاز ال بولاريميتر وقلنا لو في عندنا two
+
+8
+00:00:59,300 --> 00:01:03,760
+انان شمارز حاطناهم في مسار الضوء تبع ال بولاريميتر
+
+9
+00:01:03,760 --> 00:01:09,780
+نفس الكمية واحد هيلف الضوء لليمين هيكون المركب
+
+10
+00:01:09,780 --> 00:01:14,630
+dextrorotatory أو positive التاني هيلف للشمالعشان
+
+11
+00:01:14,630 --> 00:01:18,610
+نتخلص من فكرة اننا نضل نقول حطينا نفس الكمية
+
+12
+00:01:18,610 --> 00:01:23,630
+اعرفنا شئ سمناه الدوران النوعى او ال specific
+
+13
+00:01:23,630 --> 00:01:27,770
+rotation ال specific rotation بمنطق الخواص بمنطق
+
+14
+00:01:27,770 --> 00:01:31,890
+الخواص هو عبارة عن intensive probability بمنطق
+
+15
+00:01:31,890 --> 00:01:34,750
+الخواص هو عبارة عن intensive probability يعني
+
+16
+00:01:34,750 --> 00:01:40,660
+المركب الواحد لهspecific rotation واحد ولذلك ربما
+
+17
+00:01:40,660 --> 00:01:46,980
+اعطناكوا homework وقلنا لكم شوفولنا مثلا ال R2
+
+18
+00:01:46,980 --> 00:01:53,240
+butanol قداش الزاوية تبعته هذه الزاوية بتكون عبارة
+
+19
+00:01:53,240 --> 00:01:57,840
+عن شئ تجريبي ماعرفش في ناس جدروا يصلوا لهذه
+
+20
+00:01:57,840 --> 00:01:58,380
+الزاوية
+
+21
+00:02:00,890 --> 00:02:10,130
+الان تلتعش وتسعة سالب ولا موجب الان
+
+22
+00:02:10,130 --> 00:02:15,490
+وضحتلكوا انا لاحظوا يعني بكل وضوح قلتلكم اللي
+
+23
+00:02:15,490 --> 00:02:21,770
+بيعرف اللي بيعرف زاوية بيعرف التانية يعني اذا انا
+
+24
+00:02:21,770 --> 00:02:29,220
+كنت معطيكم في الواجبزاوية المُركّب الـR فتحته النت
+
+25
+00:02:29,220 --> 00:02:35,360
+وجدت الـS-13 وكذا إذا الـR هتكون الـPlus العكس
+
+26
+00:02:35,360 --> 00:02:42,380
+واضح؟ وانتهى على
+
+27
+00:02:42,380 --> 00:02:52,800
+أي حال فتش ربما بشكل أداء ليش؟
+
+28
+00:02:54,350 --> 00:02:59,050
+معنى ذلك اتقانكوا لعملية البحث .. اتقانكوا لعملية
+
+29
+00:02:59,050 --> 00:03:03,930
+البحث ضعيف يعني انا بهمني ان انتوا تتعبوا انا
+
+30
+00:03:03,930 --> 00:03:08,750
+بهمني في النهاية ان انتوا .. ان انتوا تتعبوا يعني
+
+31
+00:03:08,750 --> 00:03:13,270
+ان اقولكوا specific rotation ل ال tube eutanol و
+
+32
+00:03:13,270 --> 00:03:19,170
+تقولوا اتغلبنا معنى ذلك ما تقلتوشممكن في عصر
+
+33
+00:03:19,170 --> 00:03:23,210
+المعلومات ناس مايقدروش يطولوا ل specific rotation
+
+34
+00:03:23,210 --> 00:03:28,090
+لتو بيوتانول او لتو كلورو بيوتانول هذه معلومة
+
+35
+00:03:28,090 --> 00:03:32,690
+ثابتة زي ما اجي اقولكم تماما ايش نقطة الغليان ايش
+
+36
+00:03:32,690 --> 00:03:36,410
+نقطة الانصحار ايش نقطة كده كل هذه المعلومات
+
+37
+00:03:36,410 --> 00:03:41,970
+معلومات متوفرة وموجودة على ال net مش ممكن الا انكم
+
+38
+00:03:41,970 --> 00:03:49,720
+تطولوها تمام بكل الأحوال لما اللاجئلأيزومر معين ل
+
+39
+00:03:49,720 --> 00:03:53,920
+specific rotation كأنه انا عندى لأيزومر التانى
+
+40
+00:03:53,920 --> 00:03:58,760
+مباشرة يعني لما يكون واحد موجب بمقدار معين التانى
+
+41
+00:03:58,760 --> 00:04:05,060
+بيكون سالب بنفس المقدار الان لاحظوا معايا لو حطينا
+
+42
+00:04:05,060 --> 00:04:10,150
+المركب الموجبأو أحد ال enantiomers في البولاريميتر
+
+43
+00:04:10,150 --> 00:04:15,350
+بلوف ايش؟ الضوء هذا الجزء اللي بلوف الضوء الآن
+
+44
+00:04:15,350 --> 00:04:21,830
+بنقول عنه مصطلح chiral molecule هنا كنت بنتبه ان
+
+45
+00:04:21,830 --> 00:04:26,970
+انا استعمل كلمة chiral مرتين مرة لما انا حكيت عن
+
+46
+00:04:26,970 --> 00:04:31,330
+chiral carbonالكايرال كاربون هي الكاربون اللي
+
+47
+00:04:31,330 --> 00:04:36,170
+عليها أربع مجموعات مختلفة لما بحكي عن كايرال
+
+48
+00:04:36,170 --> 00:04:41,230
+موليكيول الكايرال موليكيول هو الجزير اللي بيعمل
+
+49
+00:04:41,230 --> 00:04:45,750
+دوران للضوء إذا هو أحد ال enantiomersلما بيوجد
+
+50
+00:04:45,750 --> 00:04:50,890
+لحاله نحط احنا احد المركبات في مسار الضوء يعمل
+
+51
+00:04:50,890 --> 00:04:55,530
+دوران للضوء بنقول هذا المركب كايرال موليكيول
+
+52
+00:04:55,530 --> 00:04:58,750
+فالكايرال موليكيول هو اللي بيعمل دوران للضوء الآن
+
+53
+00:04:58,750 --> 00:05:02,370
+طالما انه دخل الضوء فيه وعمله دوران بنقول عنه
+
+54
+00:05:02,370 --> 00:05:06,610
+optically active يعني بدل ما نستعمل مصطلح بيعمل
+
+55
+00:05:06,610 --> 00:05:10,390
+دوران للضوء بنقول optically active فمعنى كلمة
+
+56
+00:05:10,390 --> 00:05:19,400
+optically active it rotateslight هو بيلف ايش؟ بيلف
+
+57
+00:05:19,400 --> 00:05:23,320
+في الضوء سواء لف الضوء شمال او لف الضوء يمين هو
+
+58
+00:05:23,320 --> 00:05:27,020
+بيكون ايش؟ optically active لاحظوا معي ايش
+
+59
+00:05:27,020 --> 00:05:31,700
+المركبات اللي بتكون optically inactive المركبات
+
+60
+00:05:31,700 --> 00:05:35,720
+اللي مافيش فيها كل هذه الظاهرة مابديش انا انسى ان
+
+61
+00:05:35,720 --> 00:05:38,980
+بداية ظاهرة ال enantiomers كانت بتتطلب كايرال
+
+62
+00:05:38,980 --> 00:05:44,880
+كاربونعشان يصير من المركب اتنين ROS و بعدين واحد
+
+63
+00:05:44,880 --> 00:05:49,040
+منهم موجب واحد سالب كان بتطلب كيرال كاربون طب لو
+
+64
+00:05:49,040 --> 00:05:52,980
+انا حاطيت مركب زي على سبيل المثال ال carbon
+
+65
+00:05:52,980 --> 00:05:54,040
+tetrachloride
+
+66
+00:05:56,090 --> 00:06:01,350
+هل هذا يا ترى باربع ذرات متشابهة في كايرال كاربون؟
+
+67
+00:06:01,350 --> 00:06:05,850
+في منه اتنين؟ مافيش منه غير واحد، اذا هذا لو انا
+
+68
+00:06:05,850 --> 00:06:09,350
+حاطيته بمسار الضوء، بيكون optically active ولا
+
+69
+00:06:09,350 --> 00:06:14,170
+inactive؟ inactive، لو انا حاطيت ميه في مسار الضوء
+
+70
+00:06:15,320 --> 00:06:19,260
+بكون Optically Active ولا Inactive؟ Inactive لو
+
+71
+00:06:19,260 --> 00:06:25,280
+انا حطيت مثلا Dichloromethane CH2 Cl2 بكون
+
+72
+00:06:25,280 --> 00:06:29,960
+Optically Active ولا Inactive؟ Inactive لأنه عشان
+
+73
+00:06:29,960 --> 00:06:33,920
+يبدأ يصير أحد ال enantiomers في وجود chiral center
+
+74
+00:06:33,920 --> 00:06:37,960
+واحد المفروض يكون عندى أربع مجموعات مختلفة فخلينا
+
+75
+00:06:37,960 --> 00:06:43,840
+نقول انه نسبة كبيرة جدا من المراكبات العضوية أساسا
+
+76
+00:06:44,940 --> 00:06:50,300
+بتكون A chiral لاحظوا معاه هنا بنيجي لنقطة كتير
+
+77
+00:06:50,300 --> 00:06:55,220
+مهمة لما وصفنا مركب انه chiral بمعنى هو أحد
+
+78
+00:06:56,430 --> 00:07:01,010
+الإنانشومارز يعني كلمة chiral بتكون لما بيكون عندى
+
+79
+00:07:01,010 --> 00:07:05,730
+two enanchomars هذا المركب لو حاطيته لحاله بقول
+
+80
+00:07:05,730 --> 00:07:10,650
+عنه chiral بلف الضوء بزاوية معينة الآن ال
+
+81
+00:07:10,650 --> 00:07:14,530
+enanchomar التاني لو حاطيته في ال polarimeter برضه
+
+82
+00:07:14,530 --> 00:07:20,900
+chiral بنسميه بلف الضوء ولكن باتجاهمعاكس إذا صار
+
+83
+00:07:20,900 --> 00:07:24,840
+عندى مركب chiral و مركب chiral طيب لو حطيت مركب من
+
+84
+00:07:24,840 --> 00:07:28,660
+الأساس مافيه chiral center بلفش الضوء وجدت إيش بدى
+
+85
+00:07:28,660 --> 00:07:34,840
+أسمي هذا المركب A chiral هنا ال A بتصير أداة نفي
+
+86
+00:07:34,840 --> 00:07:38,840
+لاحظوا معناه .. لاحظوا معناه بتكونوا فاهمين شوية
+
+87
+00:07:38,840 --> 00:07:44,420
+باللغة الإنجليزية أدوات النكرة و أدوات المعرفة
+
+88
+00:07:44,420 --> 00:07:50,840
+يعني المركب هنا .. المركب هناكايرال ال a اللي
+
+89
+00:07:50,840 --> 00:07:56,260
+موجودة فيه هي أداة نكرة ولذلك إذا أنا مثلا بدي أجي
+
+90
+00:07:56,260 --> 00:08:00,340
+أحكي باللغة الإنقليزية أقول this is a chiral
+
+91
+00:08:00,340 --> 00:08:05,900
+compound معناه ذلك هذا مركب بلف الضوء ال a أداة
+
+92
+00:08:05,900 --> 00:08:09,880
+نكرة زي ما بنيجي نقول this is a table this is a
+
+93
+00:08:09,880 --> 00:08:14,220
+pen واضح الفكرة؟ الآن لو كنت بدي أحكي عن مركب زي
+
+94
+00:08:14,220 --> 00:08:20,470
+هذا شو بدي أقول عنه؟أكايرل، الآن هنا أكايرل كلمة
+
+95
+00:08:20,470 --> 00:08:24,470
+واحدة لما بدي استعمل إلها أذات نكرة بالإنقليزي بدي
+
+96
+00:08:24,470 --> 00:08:31,670
+أحفظ قدامها أن صارت هذه الكلمة كلمة واحدة أكايرل
+
+97
+00:08:32,460 --> 00:08:35,220
+فالكلمة اللى عندى للمركب اللى بيكون optically
+
+98
+00:08:35,220 --> 00:08:40,180
+active كايران ال optically inactive أكايرة الكلمة
+
+99
+00:08:40,180 --> 00:08:43,580
+واحدة الآن حسب قواعد اللغة الإنجليزية ان هنا بتدخل
+
+100
+00:08:43,580 --> 00:08:49,040
+أداة ناكرة ال a و هنا بتدخل أداة ناكرة ال m فإذا
+
+101
+00:08:49,040 --> 00:08:53,180
+كنتوا بتسمعوا أو بتقرؤوا بتكونوا منتبهين لهذا
+
+102
+00:08:53,180 --> 00:09:00,100
+الكلام ال m طيب يا تورا لو أنا حطيتمن ال two
+
+103
+00:09:00,100 --> 00:09:05,500
+enantiomers خليط متساوي يعني جبت كمية من ال
+
+104
+00:09:05,500 --> 00:09:08,700
+enantiomer الأول و كمية من ال enantiomer التاني و
+
+105
+00:09:08,700 --> 00:09:12,300
+حطيتهم مع بعض في ال polarimeter عملت منهم mixture
+
+106
+00:09:12,300 --> 00:09:18,120
+هذا الخليط المتساوي بيسموه racemic mixture فمعنى
+
+107
+00:09:18,120 --> 00:09:22,180
+racemic mixture او racemic modification هو خليط
+
+108
+00:09:22,180 --> 00:09:26,400
+متساوي من ال two enantiomers هل يا ترى هذا الخليط
+
+109
+00:09:26,400 --> 00:09:30,580
+المتساويبكون optically active ولا optically
+
+110
+00:09:30,580 --> 00:09:37,700
+inactive؟ optically inactive، ليش؟ لأن واحد بيلف
+
+111
+00:09:37,700 --> 00:09:41,880
+الضوء يمين، التاني بيلف الضوء شمال، المحص لزفر
+
+112
+00:09:43,230 --> 00:09:48,550
+واضح؟ زي تماما ما بنيجي بنقول واحد بيبني واحد
+
+113
+00:09:48,550 --> 00:09:54,410
+بيهدم ايش في نهاية المحصلة؟ صفر متى يبلغ البنيانو؟
+
+114
+00:09:54,410 --> 00:10:00,630
+تماما هو أنت تبني وغيرك يهدم واضح الفكرة؟ ولذلك
+
+115
+00:10:00,630 --> 00:10:04,650
+إذا كان عندى خليط متساوي .. إذا كان عندى خليط
+
+116
+00:10:04,650 --> 00:10:11,560
+متساوي من ال two enansomers بتكون إيش؟الخليط
+
+117
+00:10:11,560 --> 00:10:16,780
+chiral ولا achiral كله optically active ولا
+
+118
+00:10:16,780 --> 00:10:20,480
+optically inactive؟ optically inactive طبعا هنا
+
+119
+00:10:20,480 --> 00:10:26,740
+ممكن يجيني السؤال طب يا تورا لو كان عندي خليط بنسب
+
+120
+00:10:26,740 --> 00:10:28,300
+غير متساوية
+
+121
+00:10:30,330 --> 00:10:36,830
+يعني مثلا خلطت من ال isomer الموجب نسبة 70% من ال
+
+122
+00:10:36,830 --> 00:10:42,110
+isomer السالب نسبة 30% هذا الخليط
+
+123
+00:10:44,420 --> 00:10:50,400
+هيكون optically active هذا الخليط هيكون optically
+
+124
+00:10:50,400 --> 00:10:57,780
+active ولكن بشكل ايش؟ جزئي بشكل جزئي تماما زي ما
+
+125
+00:10:57,780 --> 00:11:01,460
+بنيجي نقول مثلا بني ادم الله ربح سبعين كذا خسر
+
+126
+00:11:01,460 --> 00:11:07,660
+تلاتين كدهش في النهاية؟المربح 40 ولذلك هنا نسبة
+
+127
+00:11:07,660 --> 00:11:13,120
+الزيادة 40% موجب بنضربها في الزاوية الأصلية يعني
+
+128
+00:11:13,120 --> 00:11:18,780
+لو افترضت مثلا المركب النقي زاويته 20 هذه العشرين
+
+129
+00:11:18,780 --> 00:11:24,300
+للمركب الاش النقي لو وضعته زي ما هو وضعت أحد
+
+130
+00:11:24,300 --> 00:11:28,980
+الانانشومارز زاويته زائد عشرين الانانشومارز التاني
+
+131
+00:11:28,980 --> 00:11:34,690
+وضعته زاويتهنقص عشرين طب لو عملت خليط من التنين
+
+132
+00:11:34,690 --> 00:11:38,430
+سبعين في المية موجب تلاتين في المية سالب هذا
+
+133
+00:11:38,430 --> 00:11:44,120
+الخليط كده هتكون الزاوية تبعته؟لاحظوا انا في عندي
+
+134
+00:11:44,120 --> 00:11:49,360
+فرق اربعين في المية موجب هقول اربعين على مية ضرب
+
+135
+00:11:49,360 --> 00:11:53,360
+العشرين فالزاوية هتكون اقل من عشرين بالتأكيد
+
+136
+00:11:53,360 --> 00:11:59,540
+العشرين لأ النقي تماما لان انا عندي جزء من هذا جزء
+
+137
+00:11:59,540 --> 00:12:02,700
+اربعين في المية بس موجب فالاربعين في المية من
+
+138
+00:12:02,700 --> 00:12:09,990
+العشرين كده هتطلع نضربها تمانيةفهذا الخليط زاوية و
+
+139
+00:12:09,990 --> 00:12:14,570
+هتكون تمانية الان موجب ولا سالب؟ بالتأكيد هتتبع
+
+140
+00:12:14,570 --> 00:12:18,170
+الأعلى يعني لو حطيت كمية كبيرة من الموجب و قليلة
+
+141
+00:12:18,170 --> 00:12:21,730
+من السالب فالخليط موجب يعني الإشارة على طول بنحطها
+
+142
+00:12:21,730 --> 00:12:26,650
+مابدهاش حساب واحد ربح كتير و خسر أقل فهو رابح واحد
+
+143
+00:12:26,650 --> 00:12:31,410
+خسر كتير و ربح أقل فهو خاسر الآن بتطلع أنا أعلى
+
+144
+00:12:31,410 --> 00:12:35,310
+الموجب ولا السالب؟ إذا الخليط اللي عندي موجب لكن
+
+145
+00:12:35,310 --> 00:12:40,060
+مش هيصل للموجب النقل مش هيصل لعشرينواضح؟ أنا بقول
+
+146
+00:12:40,060 --> 00:12:44,920
+هنا في عندي تلاتين سالبات بتشطبك بقالها تلاتين
+
+147
+00:12:44,920 --> 00:12:49,460
+موجة بقىهدولة شطبوا بعض يعني كأنه في عندي تلاتين
+
+148
+00:12:49,460 --> 00:12:52,180
+في المية بيلفوا باتجاه و التلاتين باتجاه تاني
+
+149
+00:12:52,180 --> 00:12:55,220
+هدولة شطبوا بعض لما نشطب التلاتين السالبة مع
+
+150
+00:12:55,220 --> 00:12:59,180
+تلاتين اقبالها موجبة جداش ضال عندي اربعين من
+
+151
+00:12:59,180 --> 00:13:03,540
+الموجبة اربعين على مية ضارب عشرين بنقدر نحسب كمان
+
+152
+00:13:03,540 --> 00:13:09,780
+زاوية الخليط اذا دائما و ابدا زاوية الخليط اقل ولا
+
+153
+00:13:09,780 --> 00:13:14,380
+اكثر من الزاوية النقية اقل لاحظوا معي لو هالخليط
+
+154
+00:13:14,380 --> 00:13:22,640
+وصل خمسين و خمسينعندما تصبح زاويته صفر رسمك
+
+155
+00:13:22,640 --> 00:13:28,760
+ميكس شرف او رسمك موديفيكشنالخمسين وخمسين شطبوا بعض
+
+156
+00:13:28,760 --> 00:13:35,220
+تماما زي إنسان ربح خمسين دينار الصبح وخسر خمسين
+
+157
+00:13:35,220 --> 00:13:40,620
+دينار آخر النهار، إيش بيروح؟ صفر، لفنا خمسين موجب
+
+158
+00:13:40,620 --> 00:13:43,820
+و بعدين خمسين سلم، بنينا خمسين حجر و هدينا خمسين
+
+159
+00:13:43,820 --> 00:13:50,950
+حجر، شو المحصلة؟ صفر، واضح؟هذا بالنسبة لمعنى
+
+160
+00:13:50,950 --> 00:13:54,770
+كايرال موليكيول و أكايرال موليكيول و راسيمك ميكشر
+
+161
+00:13:54,770 --> 00:13:58,570
+ولذلك يجب أن تكونوا مميزين أن كلمة كايرال مرت معنى
+
+162
+00:13:58,570 --> 00:14:03,450
+في كام اتجاه كايرال كاربون معناها أربع مجموعات
+
+163
+00:14:03,450 --> 00:14:09,230
+مختلفة كايرال موليكيول معناه بلوف الضوء معناه بلوف
+
+164
+00:14:09,230 --> 00:14:15,950
+الضوء هذا الكلام كله متعلق بقصة ال rotationوهو
+
+165
+00:14:15,950 --> 00:14:19,970
+خاصية فيزيائية بالمناسبة معنى خاصية فيزيائية ان
+
+166
+00:14:19,970 --> 00:14:22,810
+انا لو بعد ما خدتها المركب وحطيته في ال
+
+167
+00:14:22,810 --> 00:14:26,690
+polarimeter وعملت كل القياسات باسترده زي ما هو ولا
+
+168
+00:14:26,690 --> 00:14:31,610
+لأ انا ماعملت عليه تفاعل هذا الكلام بيقودنا مباشرة
+
+169
+00:14:31,610 --> 00:14:36,770
+لشغلتانية ال enantiomersiatura من ناحية الخواص
+
+170
+00:14:36,770 --> 00:14:43,360
+الكيميائية هل بيختلفوا ولا لأيعني ال chemical
+
+171
+00:14:43,360 --> 00:14:48,580
+properties of enantiomers الخواص الكيميائية لل
+
+172
+00:14:48,580 --> 00:14:54,020
+enantiomers أسهل شيء ممكن نفهم من خلاله الموضوع
+
+173
+00:14:54,020 --> 00:14:59,560
+أسهل شيء ممكن نفهم من خلاله الموضوع عارفين شو هو؟
+
+174
+00:14:59,560 --> 00:15:04,300
+هعطيكم مثال أو مثلين من الحياة مثال أو مثلين من
+
+175
+00:15:04,300 --> 00:15:10,730
+الحياةمرات بيكون عندنا عدسات للنضارات عدسات محدبة
+
+176
+00:15:10,730 --> 00:15:14,470
+ممكن نستعملها نجمع الأشعة أو ممكن بعض الأطفال
+
+177
+00:15:14,470 --> 00:15:19,230
+الصغار يجمعوا الأشعة أو يحرجوا ورقة بالعدسة بيصير
+
+178
+00:15:19,230 --> 00:15:20,210
+ولا لأ؟
+
+179
+00:15:36,480 --> 00:15:39,820
+ولا صورتها غير المتطابقة في المرآة الإنانش
+
+180
+00:15:39,820 --> 00:15:44,700
+ومرتبعها؟ مابفرقش يعني لو فكنا العدستين من
+
+181
+00:15:44,700 --> 00:15:48,840
+النظارات وقولنا للطلاب يتعلموا ويركزوا أشعة الشمس
+
+182
+00:15:48,840 --> 00:15:52,780
+على البقرة استعملوها العدسة الاتنين هيحرجوا الورقة
+
+183
+00:15:52,780 --> 00:15:58,260
+إذا هنا اتنين اختلفوا ولا لأ؟ مااختلفوش طيب كويس
+
+184
+00:15:58,260 --> 00:16:03,860
+لو افترضنا على سبيل المثال إنه إنسان بيشتري أبواب
+
+185
+00:16:03,860 --> 00:16:08,950
+سياراتقديمة، بيشتريها بالكيلو، الباب وزنه عشرين
+
+186
+00:16:08,950 --> 00:16:14,090
+كيلو، يا ترى لو جيبناله الباب الأمامي اليمين أو
+
+187
+00:16:14,090 --> 00:16:19,950
+الباب الأمامي الشمال، بيفرق عنده؟ هو بيشتريهم حديد
+
+188
+00:16:19,950 --> 00:16:25,990
+خردو في النهاية؟بدوا يسارهم وانتهى افرج انه يشتري
+
+189
+00:16:25,990 --> 00:16:29,970
+باب يمين ولا باب شمال؟ مايفرقش، اذا ممكن مايفرقوش
+
+190
+00:16:29,970 --> 00:16:34,790
+طب وين بيفرق معه انه يشتري باب سيارة يمين او شمال؟
+
+191
+00:16:34,790 --> 00:16:39,030
+لما يكون في عنده السيارة الكايرة اللي فيها ايضا
+
+192
+00:16:39,030 --> 00:16:45,150
+الفتحات مصممة يمين وشمال واجتها بيصيربيفرق عنده
+
+193
+00:16:45,150 --> 00:16:48,710
+لهذه الجهة بدي الباب اليمين لهذه الجهة بدي الباب
+
+194
+00:16:48,710 --> 00:16:53,710
+الشمال إذا كأنه الفتحات تبعون بواب السيارة كايرال
+
+195
+00:16:53,710 --> 00:17:00,110
+والبواب كايرال الان كل إشي بدي أحطه في مكانه وقتها
+
+196
+00:17:00,110 --> 00:17:04,650
+بيصير عند الفرق تماما زي ما أجي أنا أتكلم يعني
+
+197
+00:17:04,650 --> 00:17:13,120
+عفوا عن أقدام الأحذية الأحذية كايرالواضحة؟ و
+
+198
+00:17:13,120 --> 00:17:15,760
+الأقدام كايرل .. كايرل .. كايرل .. كايرل .. كايرل
+
+199
+00:17:15,760 --> 00:17:16,780
+.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل ..
+
+200
+00:17:16,780 --> 00:17:19,380
+كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. كايرل
+
+201
+00:17:19,380 --> 00:17:22,580
+.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل ..
+
+202
+00:17:22,580 --> 00:17:22,820
+كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. كايرل
+
+203
+00:17:22,820 --> 00:17:22,820
+.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل ..
+
+204
+00:17:22,820 --> 00:17:22,820
+كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. كايرل
+
+205
+00:17:22,820 --> 00:17:25,660
+.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل ..
+
+206
+00:17:25,710 --> 00:17:30,490
+طيب، هذا الكلام وين أكتر ما بيوجد؟ بيوجد في ال
+
+207
+00:17:30,490 --> 00:17:34,030
+biological systems، في النظم البيولوجية أنه في
+
+208
+00:17:34,030 --> 00:17:38,490
+النظم البيولوجية ال enzymes و ال receptors في
+
+209
+00:17:38,490 --> 00:17:42,330
+أحيان كثيرة كايرا يعني افترضوا مثلا عندي أنا
+
+210
+00:17:42,330 --> 00:17:47,590
+receptor موجب هذا ال receptor الموجب من خواصه أنه
+
+211
+00:17:47,590 --> 00:17:53,470
+بتفاعل مع دوة ال drugبتفعل مع دوة drug ال drug
+
+212
+00:17:53,470 --> 00:17:59,310
+ممكن يكون موجب ممكن يكون ثالث فيه منه اتنين الان
+
+213
+00:17:59,310 --> 00:18:04,740
+خلينا نفترض ان هذا ال receptor الموجببتفاعل مع
+
+214
+00:18:04,740 --> 00:18:08,900
+الدوى الموجب فلو جبتله الدوى الموجب بتفاعل معه
+
+215
+00:18:08,900 --> 00:18:12,320
+وبيؤدي لتأثيره بطيب البني آدم لو جبتله الدوى
+
+216
+00:18:12,320 --> 00:18:15,980
+السالم واحد
+
+217
+00:18:15,980 --> 00:18:20,180
+من اتنين ممكن يكون مافيش تفاعل بالمرة ومافيش أثر
+
+218
+00:18:20,180 --> 00:18:24,160
+بالمرة وممكن يتفاعل معه بطريقة معاتسة ويؤدي إلى
+
+219
+00:18:24,160 --> 00:18:30,950
+ضرر واضح؟حسب طبيعة الأدوية وحسب الـ Receptor
+
+220
+00:18:30,950 --> 00:18:34,370
+المعني ولذلك هذه النقطة أكثر ما بتواجهنا في
+
+221
+00:18:34,370 --> 00:18:39,810
+الكيميا وفي الأدوية أنه بيجوا بيدرسوا كل مركب من
+
+222
+00:18:39,810 --> 00:18:44,190
+التنين أنه فيهم اللي له الفاعلية ولذلك كثير من
+
+223
+00:18:44,190 --> 00:18:47,230
+الأدوية لما بتيجوا بتقرأوا الدوة الفعال بتلاقوا ال
+
+224
+00:18:47,230 --> 00:18:51,250
+R مثلا في مركب تاني الدوة الفعال ال S في مركب تالت
+
+225
+00:18:51,250 --> 00:18:55,700
+ال R في مركب رابع ال S حسب طبيعة إيش الدوةالان
+
+226
+00:18:55,700 --> 00:18:59,480
+بيصير السؤال طيب إذا هذا هو المركب الفعال اللى
+
+227
+00:18:59,480 --> 00:19:04,420
+يستخدم كعلاج المركب التانى شو بده يكون؟ممكن يكون
+
+228
+00:19:04,420 --> 00:19:09,780
+عديم الفائدة يعني حضوره زي غيابه لا يؤذي ولا يضر و
+
+229
+00:19:09,780 --> 00:19:15,480
+ممكن يكون مؤذى و مضر و يعمل مشاكل الآن تعون
+
+230
+00:19:15,480 --> 00:19:21,060
+الكيميا بيشتغلوا بالشكل القاتل إذا مركب منهم دوة و
+
+231
+00:19:21,060 --> 00:19:24,980
+التاني لا يضر بدل ما يفصلوهم انتوا لاحظوا لما حض
+
+232
+00:19:24,980 --> 00:19:28,870
+المركب طلعوا عندي خليط من التنينهنتعلم انه لما
+
+233
+00:19:28,870 --> 00:19:32,970
+نحضر الدواء بيطلع التانين خليط عملية الفصل عملية
+
+234
+00:19:32,970 --> 00:19:37,570
+صعبة و مكلفة ماديا كتير الان من هدولة مين المفيد
+
+235
+00:19:37,570 --> 00:19:42,550
+خلينا نفترض هذا الانانشومر التاني إذا كان مابضرش
+
+236
+00:19:42,550 --> 00:19:47,110
+سيبه معه بيأكلوا البني آدم و بيخرجوا من البني آدم
+
+237
+00:19:47,110 --> 00:19:52,640
+بدون ما يؤدي لأي ضرربيعطوا الدواء وبيعطوا التاني،
+
+238
+00:19:52,640 --> 00:19:56,700
+هم عارفين ان هذا التاني مش هيضر .. ان هذا التاني
+
+239
+00:19:56,700 --> 00:20:00,820
+مش هيضر هذا الكلام بالمناسبة مثلا بيعملوه في دواء
+
+240
+00:20:00,820 --> 00:20:06,020
+زي الابوبروفين ربما انتوا لما مار علينا جزء
+
+241
+00:20:06,020 --> 00:20:10,380
+الابوبروفين متذكرينه؟ و انا هفرجيكواياه في ال
+
+242
+00:20:10,380 --> 00:20:14,540
+aromatic compounds ارجعولهلو اتطلعتوا على
+
+243
+00:20:14,540 --> 00:20:18,000
+الابوبروفن او الاتروفن هتلاقوا فيه chiral center
+
+244
+00:20:18,000 --> 00:20:22,340
+فيه منه اتنين لان واحد منهم مفيد و بضيع الصداع
+
+245
+00:20:22,340 --> 00:20:28,000
+التاني مالوش تأثير واضح بيسيبوه مع بعض و بيعطوا
+
+246
+00:20:28,000 --> 00:20:31,400
+البني ادم اللي هو يستفيد من المفيد و يخرج الآخر
+
+247
+00:20:31,400 --> 00:20:36,630
+لمصيبة الكبيرة وين بتصير؟لو كان واحد منهم مفيد
+
+248
+00:20:36,630 --> 00:20:43,010
+والتاني ضار يجب حينها أن يفصل فصلا كاملا الضار
+
+249
+00:20:43,010 --> 00:20:48,730
+ويعطى الإنسان المفيد واضحة الفكرة؟ إذا أغلطنا بهذه
+
+250
+00:20:48,730 --> 00:20:53,210
+الشغلة، إيش حيصير فينا؟ حيصير فينا المقاس التالية
+
+251
+00:20:53,210 --> 00:20:57,750
+هذا مقال كتباه
+
+252
+00:21:03,190 --> 00:21:10,030
+دكتورة عن عقار هذا العقار ربما موجود هنا اسمه
+
+253
+00:21:10,030 --> 00:21:19,430
+الثاليدو أميد هذا قصته في الكيميا قصة مشهورة
+
+254
+00:21:19,430 --> 00:21:26,750
+كتير هذا هو العقار الثاليدو أميد الآن هذا الثاليدو
+
+255
+00:21:26,750 --> 00:21:32,540
+أميد في Cairo Center هنا واحدةيعني لما نطلع في
+
+256
+00:21:32,540 --> 00:21:37,140
+الشكل تبعه فيه chiral center واحدة إذا صار فيه منه
+
+257
+00:21:37,140 --> 00:21:46,100
+مركب R وصار منه مركب S الآن المركب R مفيد ولمين
+
+258
+00:21:46,100 --> 00:21:50,300
+المركب R مفيد تقريبا اخترع هذا الدواء في سنة 1953
+
+259
+00:21:50,300 --> 00:21:56,940
+للنساء الحوامل بضيع عندهم الصداع المصاحب للحملنزل
+
+260
+00:21:56,940 --> 00:22:01,600
+السوق بدون ما تستكمل الدراسات الكاملة عليه في آخر
+
+261
+00:22:01,600 --> 00:22:07,920
+الخمسينات طلعت المصيبة أن المركب التاني الـ S هذا
+
+262
+00:22:07,920 --> 00:22:12,300
+بيخترق المشيمة و بيأثر على الأجنة اللي في بطون
+
+263
+00:22:12,300 --> 00:22:17,190
+الأمهات لأنهم بياخدوا الأمهات الحواملعشان الصداع
+
+264
+00:22:17,190 --> 00:22:21,750
+ما انتبهوش ما استكملوش الدراسات تبع الدواء فطلع
+
+265
+00:22:21,750 --> 00:22:26,350
+المركب الثاني بأثر على الأجنة، الآن عدد كبير من
+
+266
+00:22:26,350 --> 00:22:31,350
+النساء استعملوا بدأت أوروبا تتواجه بالأجنة
+
+267
+00:22:31,350 --> 00:22:36,920
+المشوهينتقريبا سنة و نص سنتين ستين و واحد و ستين
+
+268
+00:22:36,920 --> 00:22:41,000
+نهاية التسعة و خمسين مباشرة من أول ما انتبهولها مع
+
+269
+00:22:41,000 --> 00:22:45,360
+الواحد و ستين أوقفوا استعمال الدواء على طول لكن
+
+270
+00:22:45,360 --> 00:22:49,960
+بعد ما طلع عندهم جيل كامل من الأطفال المشواهين
+
+271
+00:22:49,960 --> 00:22:54,520
+ملمش أيديهم فقط لغلطة زي هيك انه كانوا يعطوا
+
+272
+00:22:54,520 --> 00:23:00,400
+الدواء و معاهالإينان شمار .. الإينان شمار إيش
+
+273
+00:23:00,400 --> 00:23:06,980
+اتضارت و ربما لو الصورة واضحة عندكم في أسماء
+
+274
+00:23:06,980 --> 00:23:12,780
+مشهورة في هذا المجال يعني هذا الإنسان يمكن مش واضح
+
+275
+00:23:12,780 --> 00:23:17,480
+كده بس اتطلعوا الإيدين بتاعونه بصار جدا الإيدين
+
+276
+00:23:17,480 --> 00:23:23,060
+بتاعونه اتطلعوا عليه بالصور بالنتبتنبسطوا، بتلاقوا
+
+277
+00:23:23,060 --> 00:23:28,240
+كتير، ليش؟ لأن هذا مذيع مشهور جدا، مذيع مشهور جدا
+
+278
+00:23:28,240 --> 00:23:34,420
+في ال BBC ومحرر أخبار في النهاية اسمه Adams Spank
+
+279
+00:23:34,420 --> 00:23:38,780
+Adams Spank اللي بدهم يقرأوا عن قصته Adams Spank
+
+280
+00:23:38,780 --> 00:23:44,790
+موليد ال 61يعني الحامل صار في الستين الام أخدت
+
+281
+00:23:44,790 --> 00:23:49,150
+الدواء هو موليد الواحد والستين بدون إيدين وبعين
+
+282
+00:23:49,150 --> 00:23:55,430
+يعني فيها إيش عوى كذلك الحال لو بدأ أطلع على أسماء
+
+283
+00:23:55,430 --> 00:24:00,790
+تانية هاي Adams Smug شايفين العين هنا شوية مافيش
+
+284
+00:24:00,790 --> 00:24:09,710
+إيدين هذا بني آدم مش بدخل سيجارة هذا برسم الريشة
+
+285
+00:24:09,710 --> 00:24:15,170
+في تمه لأنه مالوش إيدينرسام شهير ويله معارض شهيرة
+
+286
+00:24:15,170 --> 00:24:19,670
+برضه موليد ال واحد و ستين من غلطة زي هذه برضه
+
+287
+00:24:19,670 --> 00:24:23,650
+موليد ال واحد و ستين و هي المعرض الفني تبعه و هذا
+
+288
+00:24:23,650 --> 00:24:28,950
+بامالي الكوجادرين اللي تشوفوه هذا بيعزف ع الجثار
+
+289
+00:24:28,950 --> 00:24:36,790
+برجله ليش؟ برضه لأنه مالوش أطراف مالوش إيدين إيدين
+
+290
+00:24:36,790 --> 00:24:43,050
+و غير الإيدين كمان إيدين و عينينو جوزي أنتونيو
+
+291
+00:24:43,050 --> 00:24:47,130
+عازف شهير جدا من نيكاراجوا و ربما البعض سمع له
+
+292
+00:24:47,130 --> 00:24:52,480
+موسيقىعازف مشهور هدولة كلهم عايشين ولذلك من سنين
+
+293
+00:24:52,480 --> 00:24:56,640
+بسيطة الألمان عملوا فيلم عن هذا الموضوع واحتجوا
+
+294
+00:24:56,640 --> 00:25:01,980
+الشعب الألماني ليش؟ لأنه ذكروهم بالمقساة اللي مرت
+
+295
+00:25:01,980 --> 00:25:06,160
+في عام واحد وستين اتنين وستين مقسات الأجنة
+
+296
+00:25:06,160 --> 00:25:10,340
+المشوهين كل هذا الكلام لأن استعملنا الدوة الغلط
+
+297
+00:25:10,340 --> 00:25:16,090
+الفكرة ببساطةمرة تانية تشبه قصة المفتاح والذرفيل
+
+298
+00:25:16,090 --> 00:25:20,990
+الذرفيل كايرة الفراغي بيده مفتاح معين يتطابق معاه
+
+299
+00:25:20,990 --> 00:25:27,670
+نجيب المفتاح التاني مابفتحش مستفدناش اشي و لذلك في
+
+300
+00:25:27,670 --> 00:25:34,970
+الخواص الكيميائية ال enantiomers لهم نفس الخواص
+
+301
+00:25:34,970 --> 00:25:40,840
+الكيميائية ما عدااذا اتفعلوا مع مركبات فراغية زيهم
+
+302
+00:25:40,840 --> 00:25:45,680
+يعني لما بتفعل ال chiral مع ال chiral اشي ماخد
+
+303
+00:25:45,680 --> 00:25:49,000
+اتجاه فراغي شمال او يمين مع اشي ماخد اتجاه فراغي
+
+304
+00:25:49,000 --> 00:25:52,880
+شمال او يمين بيصير الاختلاف زي الزرفيل بتاع الباب
+
+305
+00:25:52,880 --> 00:25:57,820
+في شمال ويمين جوا والمفتاح في شمال ويمين بيصير
+
+306
+00:25:57,820 --> 00:26:04,160
+مفتاح معينلذرفي المعين واحد تاني مابظبطش او بادى
+
+307
+00:26:04,160 --> 00:26:08,340
+الى مشاكل ولذلك في الخواص الكيميائى المحاصلة اللى
+
+308
+00:26:08,340 --> 00:26:12,500
+بنقولها ان ال enantiomers they have the same
+
+309
+00:26:12,500 --> 00:26:16,780
+chemical the same chemical properties except when
+
+310
+00:26:16,780 --> 00:26:19,880
+they react with other chiral molecules لما يصير
+
+311
+00:26:19,880 --> 00:26:24,630
+التفاعل بين chiral و chiral وجعت المشكلةواضح
+
+312
+00:26:24,630 --> 00:26:31,030
+الفكرة؟ هذا كلام عام جدا لكن بحياتكوا .. يعني بأمل
+
+313
+00:26:31,030 --> 00:26:34,990
+أنه هتصيروا تشوفوا كتير هذه المسميات هتصيروا
+
+314
+00:26:34,990 --> 00:26:38,730
+تقرأوا كتير على الأدوية مكتوب عليها R و بين جثين
+
+315
+00:26:38,730 --> 00:26:42,330
+موجة بقى أو سالب و S و بين جثين موجة بقى أو سالب
+
+316
+00:26:42,330 --> 00:26:52,230
+فنكون عارفين كل هذه المصطلحات فليدو أمد فليدو
+
+317
+00:26:56,400 --> 00:27:03,260
+ثليده أمن لو قرأته قصة الثليده أمن قصة كبيرة جدا
+
+318
+00:27:03,260 --> 00:27:09,540
+بلاش ممكن نروح على شغلة تانية بسيطة جدا ربما مرت
+
+319
+00:27:09,540 --> 00:27:19,740
+عليكم كتير مر عليكم هذا اللي موجود هنا في الصورة
+
+320
+00:27:19,740 --> 00:27:27,120
+قادرين تشوفوه الفطرالفطر تبع البيتزا، الان متعودين
+
+321
+00:27:27,120 --> 00:27:31,500
+تقولوا ان الفطر في منه كويس و في منه سام، مظبوط؟
+
+322
+00:27:31,500 --> 00:27:37,820
+الان الكويس والسام فيهم نفس المركب، نفس المركب،
+
+323
+00:27:37,820 --> 00:27:42,880
+تحديدا من ناحية كيميائية هذا هو المركب، واضح؟ من
+
+324
+00:27:42,880 --> 00:27:44,040
+ناحية كيميائية
+
+325
+00:27:47,540 --> 00:27:52,000
+هذا هو المركب، شايفينه؟ هاي المركب، الآن هذا
+
+326
+00:27:52,000 --> 00:27:59,860
+المركب في chiral center واحد، هذا واحد
+
+327
+00:27:59,860 --> 00:28:08,010
+منهم بيكون اكويس والتاني بيكون poisonous، سابفقط
+
+328
+00:28:08,010 --> 00:28:12,330
+بيختلفوا بال chiral center يعني نفس الجزء هذا اللي
+
+329
+00:28:12,330 --> 00:28:17,110
+بنسميه one octane three all ال R منه اللي كويس و
+
+330
+00:28:17,110 --> 00:28:22,590
+التاني ال 7 و انتوا دائما كانوا يحذروكوا في دراسة
+
+331
+00:28:22,590 --> 00:28:27,330
+النبات و انه احذروا الفطر اللي بيكون عادة شكله زي
+
+332
+00:28:27,330 --> 00:28:32,650
+المثلث يعني الفطر العادي هذا ال okay هذا العامل
+
+333
+00:28:32,650 --> 00:28:37,240
+مشكلة الآن هذولا فيهم نفس الهوركبنفس المُركّب اللي
+
+334
+00:28:37,240 --> 00:28:41,080
+خلّه مُركّب كويس ومُركّب سام انه هذا انانشومر وهذا
+
+335
+00:28:41,080 --> 00:28:45,660
+انانشومر تاني شوفوا هذا الفرق البسيط جدا اللي
+
+336
+00:28:45,660 --> 00:28:49,740
+بمرهانة قعد يؤثر على الأدوية ويؤثر على حياة الناس
+
+337
+00:28:49,740 --> 00:28:54,120
+هو فرق أساسي في فهم الكيمياء ولذلك يعني ال stereo
+
+338
+00:28:54,120 --> 00:28:59,980
+chemistry مش قصة يعني قصة شيء أحيانا صعب أو شيء
+
+339
+00:28:59,980 --> 00:29:05,490
+ممتع على جانب لإن فيه صميمفهم الكيمياء و في صميم
+
+340
+00:29:05,490 --> 00:29:11,470
+فهم الأدوية ان نكون فاهمين هذه الأمور المتعلقة بال
+
+341
+00:29:11,470 --> 00:29:18,890
+stereo chemistry طبعا الانسان كل ما بيتعب من شغلة
+
+342
+00:29:18,890 --> 00:29:24,270
+بيقول واجتاش بدنا نخلص من الشغلة اول ما بيحس انه
+
+343
+00:29:24,270 --> 00:29:30,310
+بده يخلص من الشغلة بيكتشف نقطة بسيطة جدا ان هو لسه
+
+344
+00:29:30,310 --> 00:29:36,330
+ماخدش من الموضوع نقطةأول ما بيحس أنه جربنا نخلص من
+
+345
+00:29:36,330 --> 00:29:40,950
+هالشغلة هو ما أخدش من الموضوع نقطة، ليش؟ لأنه أنا
+
+346
+00:29:40,950 --> 00:29:47,670
+تكلمت عن جزء في chiral centers واحد، قولت بيقدّي
+
+347
+00:29:47,670 --> 00:29:52,990
+لكم إينان شمار؟ إتنين، طيب يا تورة الآن لو أجيت و
+
+348
+00:29:52,990 --> 00:29:58,350
+أتكلمت عن ال chiral centers ال chiral centers
+
+349
+00:29:58,350 --> 00:30:02,190
+والإينان
+
+350
+00:30:02,190 --> 00:30:12,790
+شمارأو ال products ال stereo isomers لما
+
+351
+00:30:12,790 --> 00:30:17,690
+كان في عندى one chiral center كم واحد كانوا؟ طب يا
+
+352
+00:30:17,690 --> 00:30:19,910
+تورا لو صاروا اتنين، لو صاروا تلاتة، لو صاروا
+
+353
+00:30:19,910 --> 00:30:23,490
+أربعة، لو صاروا خمسة، لو صاروا ستة، كده بده يصير
+
+354
+00:30:23,490 --> 00:30:28,180
+عندى؟يعني جزء فيه تلاتة اربعة خمسة chiral centers
+
+355
+00:30:28,180 --> 00:30:33,060
+في عندى علاقة بتقوللي ال maximum possible number
+
+356
+00:30:33,060 --> 00:30:40,680
+of stereoisomers two to the N بحيث انه هذي ايش ال
+
+357
+00:30:40,680 --> 00:30:51,790
+N اتنين اقص واحد اتنين اقص اتنين اربعة2-3 8 2-4 16
+
+358
+00:30:51,790 --> 00:30:59,050
+2-5 32 لما يبدأ يجينا مركب في خمسة chiral centers
+
+359
+00:30:59,050 --> 00:31:06,510
+هنكتشف أنه في منه 32 isomers هذول 32 isomers ممكن
+
+360
+00:31:06,510 --> 00:31:10,990
+واحد منهم يكون مفيد و بنستفيد منه والواحد و
+
+361
+00:31:10,990 --> 00:31:15,200
+التلاتين التانين بقابلهلاحظوا قداش الكلام بيصير
+
+362
+00:31:15,200 --> 00:31:20,440
+مرهق وهذا الكلام هيمر معكم على سبيل المثال الخامسة
+
+363
+00:31:20,440 --> 00:31:27,400
+لما ندرس ال biochemistry السكر اللي مكوّن من ست
+
+364
+00:31:27,400 --> 00:31:32,500
+درات كربون لما يكون في الشكل الحلقي في خمسة chiral
+
+365
+00:31:32,500 --> 00:31:39,340
+centers في منه اتنين و تلاتين isomersتخيلوا أنه
+
+366
+00:31:39,340 --> 00:31:44,700
+بدنا نتعلم لما نيجي ناخد السكر السداسي الماخد
+
+367
+00:31:44,700 --> 00:31:52,800
+الصيغة العامة C6H12O6 بدنا نرسم مش مركب واحد اتنين
+
+368
+00:31:52,800 --> 00:31:58,220
+و تلاتين مركب و نعرفهم و نميزهم بالاسم الان لما
+
+369
+00:31:58,220 --> 00:32:01,420
+المريض بيروح على المستشفى لما المريض بيروح على
+
+370
+00:32:01,420 --> 00:32:04,760
+المستشفى و بيقولوا بدنا نعطيه محلول سكر بتعرفوا
+
+371
+00:32:04,760 --> 00:32:10,490
+بيعطيه واحد من الاتنين و تلاتينواحد من ال 32 هدولة
+
+372
+00:32:10,490 --> 00:32:16,370
+واضح و الباقي مش هم اللي بيعطيها فالموضوع بيصير
+
+373
+00:32:16,370 --> 00:32:21,790
+بهذا الشكل كبير طبعا اللي بده يتدرج في الكلام يبدأ
+
+374
+00:32:21,790 --> 00:32:26,190
+يعطي مثال على اتنين chiral centers الان انا هنا
+
+375
+00:32:26,190 --> 00:32:31,390
+مابقولش ان هذا عدد ال isomers بقول هذا ال maximum
+
+376
+00:32:31,390 --> 00:32:38,340
+possible يعني هذاأعلى ما يمكن من ال isomers بس
+
+377
+00:32:38,340 --> 00:32:44,130
+ممكن يكون أقل منهيعني لما بيكون فيه اتنين chiral
+
+378
+00:32:44,130 --> 00:32:48,710
+centers ممكن يكون عنده العدد الأقصى أربعة و مرات
+
+379
+00:32:48,710 --> 00:32:53,490
+بيكونوا تلاتة و هكذا ممكن يقولوا واحد مابدناش
+
+380
+00:32:53,490 --> 00:32:58,790
+نتجاوز بس التلين يعني بدنا نشرح مثالين مثال لما
+
+381
+00:32:58,790 --> 00:33:02,790
+يكون عنده two chiral centers و عنده أربعة isomers
+
+382
+00:33:02,790 --> 00:33:07,230
+و مثال لما بيكون عنده two chiral centers بس ال
+
+383
+00:33:07,230 --> 00:33:11,430
+isomersتلاتة يعني بيطلع منهم في هذه الحالة اتنين
+
+384
+00:33:11,430 --> 00:33:16,710
+طلعوا شبه بعض نفس الاشياء واضح فبصير الدارس تبعنا
+
+385
+00:33:16,710 --> 00:33:23,630
+المركبات اللي فيهاأكتر من chiral centers والمثال
+
+386
+00:33:23,630 --> 00:33:26,770
+اللى بدنا نبدأ فيه لما يكون عندى two chiral
+
+387
+00:33:26,770 --> 00:33:32,650
+centers او centers لاحظوا ان هذا الكلام بيجيبنا
+
+388
+00:33:32,650 --> 00:33:41,000
+لنقطة ان انتوا لما بتتعلموا العلم بتتعلموا كيفبنوع
+
+389
+00:33:41,000 --> 00:33:46,340
+من البساطة بتتعلموا بنوع من البساطة في الأول يعني
+
+390
+00:33:46,340 --> 00:33:52,420
+بنعطيكوا جزء من العلم وبنخبي عنكم أجزاء بنعطيكوا
+
+391
+00:33:52,420 --> 00:33:57,340
+جزء وبنخبي عنكم أجزاء يعني لو جيبت سؤال احنا
+
+392
+00:33:57,340 --> 00:34:00,680
+اتعودنا ان نجاوبه وممكن اعطيتكوا ياهو ميركو سلمته
+
+393
+00:34:00,680 --> 00:34:05,960
+وقلتلكوا مركب البنتين لو عملتله monochlorination
+
+394
+00:34:07,760 --> 00:34:12,900
+هي واحد، اتنين، تلاتة، اربعة، خمسة كام ناتج عندي
+
+395
+00:34:12,900 --> 00:34:17,980
+من الـ monoclonation؟ اعملتوا؟ تلاتة واحدة ما زالت
+
+396
+00:34:17,980 --> 00:34:23,480
+بتقول تلاتة إذا حطيت هنا كلور، مُركّب وإذا حطيت
+
+397
+00:34:23,480 --> 00:34:27,600
+هنا مُركّب وإذا حطيت هنا مُركّب وسمناهم one
+
+398
+00:34:27,600 --> 00:34:33,360
+chloro, two chloro, three chloro الآن لاحظوا معي
+
+399
+00:34:33,360 --> 00:34:36,300
+لو هذا الكلام أنا إجيته طبقته
+
+400
+00:34:40,720 --> 00:34:44,160
+هذا مُركّب البنتين و افترض ان انا بعمل الكلور هاي
+
+401
+00:34:44,160 --> 00:34:47,080
+الكلور عن إمرأة واحد، هاي الكلور عن إمرأة اتنين،
+
+402
+00:34:47,080 --> 00:34:52,280
+هاي الكلور عن إمرأة تلاتة بتقصيروا الآن، بتقولوا،
+
+403
+00:34:52,280 --> 00:35:02,440
+في عندي chiral centers ولا لأ؟ هنا CH2 CH2 CH2 CH2
+
+404
+00:35:02,440 --> 00:35:06,180
+CH3 إذا مافيش ولا chiral center، إذا هذا فعلا
+
+405
+00:35:06,180 --> 00:35:12,290
+مُركّب واحد، الواحد كلوره بينتينالان هنا حطوا
+
+406
+00:35:12,290 --> 00:35:18,170
+القدش لناقصة في Cairo Center إذا هذا مركبين في من
+
+407
+00:35:18,170 --> 00:35:22,430
+واحد R و واحد S يعني لو روحتوا تشتريوا مركب اسمه
+
+408
+00:35:22,430 --> 00:35:28,130
+two chlorobentain هتلاقوا مركبين البياح هيقولكم في
+
+409
+00:35:28,130 --> 00:35:31,070
+مركب اسمه R two chlorobentain و S two
+
+410
+00:35:31,070 --> 00:35:34,170
+chlorobentain بس فيش مركب اسم two chlorobentain
+
+411
+00:35:34,970 --> 00:35:38,470
+واضح؟ يا بدي يكون R يا بدي يكون S لأنه في كايرال
+
+412
+00:35:38,470 --> 00:35:44,770
+سنتر طيب هذا المركب لأ لأنه اثل او اثل CH2 CH3
+
+413
+00:35:44,770 --> 00:35:47,210
+اللي هي مجموعة ايش الاثل
+
+414
+00:35:49,150 --> 00:35:53,910
+و هذه إثل فحامل HUC قالوا إثل و إثل إذا هذا فيش
+
+415
+00:35:53,910 --> 00:35:59,650
+منه غير مركّب الآن لو أنا إجيت سألتكم عادة أن الـ
+
+416
+00:35:59,650 --> 00:36:03,750
+monochlorination للوان بنتين بيعطيني
+
+417
+00:36:03,750 --> 00:36:09,450
+chemistructural isomers4 أربع لأ تلاتة لاحظوا
+
+418
+00:36:09,450 --> 00:36:14,010
+معايا ال structural isomers اللي بيختلفوا في ترتيب
+
+419
+00:36:14,010 --> 00:36:18,590
+مواقع الذرات من ناحية ال structure لكلور يا ع واحد
+
+420
+00:36:18,590 --> 00:36:23,170
+يا ع اتنين يا ع تلاتة هذا المركب هيكون اسمته two
+
+421
+00:36:23,170 --> 00:36:27,190
+chlorobentain والتاني two chlorobentain الآن ال R
+
+422
+00:36:27,190 --> 00:36:32,930
+و ال S stereo isomersولذلك، بدكم تنتبه لو أنا
+
+423
+00:36:32,930 --> 00:36:36,530
+بقولكوا بيعطيني كام structural isomers، ثلاثة، لكن
+
+424
+00:36:36,530 --> 00:36:41,250
+لو قلتلكم ال total number of isomers، أربعة، ال
+
+425
+00:36:41,250 --> 00:36:44,630
+total number of isomers، أربعة، لأن هذا واحد، هذا
+
+426
+00:36:44,630 --> 00:36:52,380
+في منه تنين، Rs، وهذا واحد، واضح الفكرة؟الان لو
+
+427
+00:36:52,380 --> 00:36:57,480
+اتينا احنا بدنا نزيد خطوة بدنا نقول it's two
+
+428
+00:36:57,480 --> 00:37:03,900
+chlorobentains بس نعمله dichlorination مش
+
+429
+00:37:03,900 --> 00:37:09,900
+monochlorination ربما ان انتوا حليتوا السؤال لكن
+
+430
+00:37:09,900 --> 00:37:17,070
+بدون ماشيبدون ما تاخدوا الاستيريو كيميستر بعين
+
+431
+00:37:17,070 --> 00:37:20,970
+الاعتبار يعني ممكن تفكروا تحطوا تنتين كلور هنا او
+
+432
+00:37:20,970 --> 00:37:24,650
+تنتين هنا او تنتين هنا او واحدة و واحدة واحدة
+
+433
+00:37:24,650 --> 00:37:27,450
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+434
+00:37:27,450 --> 00:37:27,730
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+435
+00:37:27,730 --> 00:37:27,990
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+436
+00:37:27,990 --> 00:37:29,050
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+437
+00:37:29,050 --> 00:37:31,090
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+438
+00:37:31,090 --> 00:37:37,070
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+439
+00:37:37,070 --> 00:37:41,490
+واحدة واحدة واحدة واحدة واحدةهذا مش هيكون في منه
+
+440
+00:37:41,490 --> 00:37:46,650
+إلى واحد او التنتين هان او التنتين هان طبعا هان زي
+
+441
+00:37:46,650 --> 00:37:49,910
+هان و هان زي هان بعدين ممكن تحطوا كلور ع واحد و ع
+
+442
+00:37:49,910 --> 00:37:54,510
+اتنين بيصير عندى one chiral center اللى هنا وجد
+
+443
+00:37:54,510 --> 00:37:57,850
+هذا المركب اللى فيه هنا كلور هنا كلور كم مركب منه
+
+444
+00:37:57,850 --> 00:38:03,810
+اتنين ممكن تحطه هان و هان بيصير برضه عندكم one
+
+445
+00:38:03,810 --> 00:38:08,690
+chiral center في منه جديش اتنين ممكن تحطه هان و
+
+446
+00:38:08,690 --> 00:38:14,080
+هانبرضه عندكم one chiral center فى منه اتنين ممكن
+
+447
+00:38:14,080 --> 00:38:17,660
+تحطوا هنا و هنا تخيلوا لما تحطوا هنا CL ما زال
+
+448
+00:38:17,660 --> 00:38:24,300
+عندكم CH2 مش chiral و CH2 و CH2 و CH2 و هنا CH2CL
+
+449
+00:38:24,300 --> 00:38:29,860
+مش chiral اذا لو انا جبتلكوا سؤال ال one five
+
+450
+00:38:29,860 --> 00:38:36,100
+dichlorobentane has two stereoisomers طلعوا معاه
+
+451
+00:38:36,100 --> 00:38:41,170
+هي كلور هي كلورشوفوا هنا كم كايرال سنتر فيه
+
+452
+00:38:41,170 --> 00:38:45,250
+CH2H2H2H2
+
+453
+00:38:45,250 --> 00:38:49,210
+ولا كايرال سنتر إذا ال 1,5 ده يكلوره بين 2 فيه
+
+454
+00:38:49,210 --> 00:38:53,710
+مركب واحد لكن لو أنا كنت مثلا باجي بسألكم ال 1,2
+
+455
+00:38:53,710 --> 00:39:03,210
+هيكلور أكيد هنا H هنا CL هتكون مكملة H2 HH صح ولا
+
+456
+00:39:03,210 --> 00:39:10,610
+لأ هذا كم مركب منه 2لأ و هذا مش chiral هذا بس one
+
+457
+00:39:10,610 --> 00:39:19,370
+chiral center فيه هذا مش chiral هذا CH2 و هذه H2 و
+
+458
+00:39:19,370 --> 00:39:23,590
+هذه H2 و هذه H3 one chiral center إذا ال one two
+
+459
+00:39:23,590 --> 00:39:29,710
+dichloro بينتين في منه كام مركب اتنين ارقص الآن لو
+
+460
+00:39:29,710 --> 00:39:34,070
+إجيت لواحد من هدول المجموعة و اتأملوا جيدا
+
+461
+00:39:36,880 --> 00:39:44,160
+وقلنا لكوا سمونا المركب التالي هذا
+
+462
+00:39:44,160 --> 00:39:48,040
+اتنين
+
+463
+00:39:48,040 --> 00:39:49,540
+ثلاثة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+464
+00:39:49,540 --> 00:39:49,620
+تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+465
+00:39:49,620 --> 00:39:50,060
+تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+466
+00:39:50,060 --> 00:39:50,980
+تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+467
+00:39:50,980 --> 00:39:56,440
+تلاتة اتنين تلاتة
+
+468
+00:39:56,440 --> 00:39:56,780
+اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة
+
+469
+00:39:56,780 --> 00:40:01,900
+اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين ت
+
+470
+00:40:05,330 --> 00:40:10,730
+هذه حملة مثل و H و CL و مجموعة كبيرة إذا هذه كايرا
+
+471
+00:40:10,730 --> 00:40:16,690
+و هذه حملة كلور و H و CH2 و CH3 و CHCL و CH3 أربع
+
+472
+00:40:16,690 --> 00:40:21,990
+مجموعات كايرا two chiral centers maximum بنتوقع
+
+473
+00:40:21,990 --> 00:40:26,650
+أربعة و حقيقة هنكتشف إن هدولة أربع مركبات
+
+474
+00:40:30,150 --> 00:40:34,470
+اللي كنا بنفكره و بنكتب ان هو مراكب واحد ال two
+
+475
+00:40:34,470 --> 00:40:38,330
+three dichlorobentain هتلاحظوا انه اربع مراكبات
+
+476
+00:40:38,330 --> 00:40:41,250
+يعني لو روحتوا على الدكانة تشتريوا two three
+
+477
+00:40:41,250 --> 00:40:43,570
+dichlorobentain لو سمحت بيعلى two three
+
+478
+00:40:43,570 --> 00:40:47,270
+dichlorobentain بيفتش مابلاقيش مراكب في الكون هيك
+
+479
+00:40:47,270 --> 00:40:51,250
+لو واحده اسمه two three dichlorobentain هيلاقيهم
+
+480
+00:40:51,250 --> 00:40:58,190
+اسمهم ROR SOS ROS SOR هتقولوا كيف هدولة ابن اتعلم
+
+481
+00:41:03,030 --> 00:41:07,570
+نرسمهم الان متشوقين انكوا تشوفوا شو مع الاربع
+
+482
+00:41:07,570 --> 00:41:13,150
+مركبات العملية بسيطة اتطلعوا مع هاي البنتين carbon
+
+483
+00:41:13,150 --> 00:41:20,730
+CH3 CH حملة CL CH حملة CL و إثل يعني CH2 CH3 ع
+
+484
+00:41:20,730 --> 00:41:24,960
+موقع اتنين وع موقع تلتة عندكم كلور ولا لأهي على
+
+485
+00:41:24,960 --> 00:41:29,560
+اتنين كلور و على تلاتة كلور الان حطوهم عكس بعض و
+
+486
+00:41:29,560 --> 00:41:34,100
+اعملوا صورتهم في المرايا صار هذا مركب و هذا مركب
+
+487
+00:41:34,100 --> 00:41:40,800
+غير متطابقين على بعض و حطوهم جنب بعض الكلور شايفين
+
+488
+00:41:40,800 --> 00:41:46,080
+الكلور عكس بعض و صورتهم في المرايا جنب بعض و
+
+489
+00:41:46,080 --> 00:41:52,520
+صورتهم في المراياكام مراكب صاروا؟ أربعة، الآن كل
+
+490
+00:41:52,520 --> 00:41:55,240
+اللي موجود عند الأربع مراكبات اسمهم two three
+
+491
+00:41:55,240 --> 00:41:59,000
+dichlorobentane باجي بسمي من هنا واحد اتنين تلاتة
+
+492
+00:41:59,000 --> 00:42:05,760
+اربعة لما بدي اقول هذا اتنين بدي احددها R ولا S و
+
+493
+00:42:05,760 --> 00:42:11,360
+تلاتة بدي احددها R ولا Sبسأل نفسي وين أقل مجموعة
+
+494
+00:42:11,360 --> 00:42:16,680
+على اتنين انا امركز الان على اتنين ال H شطبناها
+
+495
+00:42:16,680 --> 00:42:23,420
+قول انا على الجانب هنعكس الان عندكم Cl و Carbon و
+
+496
+00:42:23,420 --> 00:42:27,740
+CH3 طبعا هذه ال Carbon حملة Cl و هذه الحملة H اذا
+
+497
+00:42:27,740 --> 00:42:47,970
+كيف همشيأس أس أس أس أس أس أس أس أس أس أس
+
+498
+00:42:47,970 --> 00:42:54,580
+أس أس أس أس أس أس أس أس أس أس أس أسالـ H و الأعلى
+
+499
+00:42:54,580 --> 00:43:02,700
+مجموعة الـ Cl بعدها الكربون اللي حمله Cl بعدها هذه
+
+500
+00:43:02,700 --> 00:43:08,840
+الـ Ethyl CH2 CH3 أنا أعلى كربون بتحمل Cl ولا
+
+501
+00:43:08,840 --> 00:43:13,200
+كربون بتحمل H و H و C كربون بتحمل Cl مش فيها نقاش
+
+502
+00:43:13,200 --> 00:43:18,790
+الآن هاي واحد هذه كلها كمجموعة اتنينهذه تلات
+
+503
+00:43:18,790 --> 00:43:24,710
+مجموعات هذي واحد هذي اتنين هذي تلاتة ال R لما نمشي
+
+504
+00:43:24,710 --> 00:43:30,870
+بهذا الشكل واحد اتنين تلاتة شو مبينه بكتب 3R هذول
+
+505
+00:43:30,870 --> 00:43:36,090
+عكسهم هتلاقوهم 2S 3S بإمكانكوا في البيت الأن
+
+506
+00:43:36,090 --> 00:43:43,020
+تروحوا تحددوا كل هذه المواقعاعملوهم بهدوء هتلاحظوا
+
+507
+00:43:43,020 --> 00:43:47,080
+ان الأربع مركبات اللي موجودة هنا الاربع مركبات
+
+508
+00:43:47,080 --> 00:43:50,600
+اللي موجودة هنا two R ثري R وصورته في المرايا two
+
+509
+00:43:50,600 --> 00:43:55,060
+S ثري S دابن الصورة في المرايا أشمالها عكس يعني ال
+
+510
+00:43:55,060 --> 00:43:59,740
+R أقبالها S و ال R أقبالها S و بعدين ال two R ثري
+
+511
+00:43:59,740 --> 00:44:04,340
+S و أقبالها two S three R يعني ال two R two S و ال
+
+512
+00:44:04,340 --> 00:44:09,760
+three S three R مش أنا قولت كل نقطةعكس التانية في
+
+513
+00:44:09,760 --> 00:44:14,620
+المراية هل يترفيب هذه الرموز أي رمزين متشابهين؟
+
+514
+00:44:14,620 --> 00:44:20,680
+إذا هدولة كام مركبة؟ أربع مركبات اتخيلوا عاد لو
+
+515
+00:44:20,680 --> 00:44:24,960
+واحد من هدولة الدوة و الباقين بضره أنه أنا اللي
+
+516
+00:44:24,960 --> 00:44:29,060
+بدي استعمله، هنفترض أن الدوة كان 2S 3S، بس هذا
+
+517
+00:44:29,060 --> 00:44:33,530
+اللي بدي استعمله، هذا لأ، هذا لأ، هذا لأواضحة
+
+518
+00:44:33,530 --> 00:44:36,830
+الفكرة شوما الأربع مركبات المرة الجاية ان شاء الله
+
+519
+00:44:36,830 --> 00:44:41,450
+انطلاقا من هذه النقطة بشرط تكونوا اتدربتوا على
+
+520
+00:44:41,450 --> 00:44:45,570
+تسمية المركبات وعلى تحديد ال chiral centers بشكل
+
+521
+00:44:45,570 --> 00:44:48,950
+أكبر بنستمر انطلاقا من هذه النقطة
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA.srt
new file mode 100644
index 0000000000000000000000000000000000000000..58300ca766eba2bfdb8b1168da621a9c23ffa74c
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA.srt
@@ -0,0 +1,1502 @@
+
+1
+00:00:21,400 --> 00:00:26,380
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry
+
+2
+00:00:26,380 --> 00:00:31,980
+اللى بدأنا فيه المرة الماضية المرة الماضية اتكلمنا
+
+3
+00:00:31,980 --> 00:00:36,300
+طبعا على تصنيف ال isomers ايش معنى structural
+
+4
+00:00:36,300 --> 00:00:39,980
+isomers و stereo isomers وقولنا ان ال stereo
+
+5
+00:00:39,980 --> 00:00:44,850
+isomers نوعانانشو مارس ودياستيريو مارس
+
+6
+00:00:44,850 --> 00:00:48,070
+الدياستيريو مارس كنا اتكلمنا عنهم سابق و نعطينا
+
+7
+00:00:48,070 --> 00:00:52,510
+عنهم امثلة من ال CC trans compounds و ما إلى ذلك
+
+8
+00:00:52,510 --> 00:00:57,130
+عرفنا بالظبط ايش بنعنى بانانشو مارس طبعا جزء من
+
+9
+00:00:57,130 --> 00:01:02,290
+الموضوع ان نكون فاهمين علاقة المركبات بعضها بعض من
+
+10
+00:01:02,290 --> 00:01:08,040
+خلال المرأة فإذا كانت المركبات زي ما حكينا non
+
+11
+00:01:08,040 --> 00:01:11,540
+-sober imposible mirror image stereo isomers هذوله
+
+12
+00:01:11,540 --> 00:01:16,280
+سمناهم إيش Inertiomers و بتكلمنا عن إنه هذه
+
+13
+00:01:16,280 --> 00:01:20,020
+الإمكانية ممكن تكون موجودة لما يكون عند كايرال
+
+14
+00:01:20,020 --> 00:01:26,080
+سنتر معنى كايرال سنتر هي ذرة كربون تحمل أربع
+
+15
+00:01:26,080 --> 00:01:30,780
+مجموعات مختلفة هي مثلا عندنا الآن أربع مجموعات
+
+16
+00:01:30,780 --> 00:01:34,440
+مختلفة يعني إذا بتلاحظوا هذا الكربون عادة الكايرال
+
+17
+00:01:34,440 --> 00:01:40,410
+سنتر بنحطلها نجمةهذا الكربون بتحمل مجموعة و بتحمل
+
+18
+00:01:40,410 --> 00:01:44,090
+كربون متصلة بالدوبل بوند و بتحمل CH2 و بتحمل H
+
+19
+00:01:44,090 --> 00:01:49,850
+هذول أربع مجموعات مختلفة مع ذلك لو اتطلعنا في كل
+
+20
+00:01:49,850 --> 00:01:54,690
+الجزيء مافيش غير هذا الكربون هذا المثال أيضا لو
+
+21
+00:01:54,690 --> 00:01:58,610
+بتطلع الكربون اللي هنا Cl, Methyl, CH2, CH2,
+
+22
+00:01:58,650 --> 00:02:02,950
+Potassium و H أربع مجموعات مختلفة فهذا في منه
+
+23
+00:02:02,950 --> 00:02:09,370
+مركبين ROSهذا في منه مركبين R وS اي مركب مافيش فيه
+
+24
+00:02:09,370 --> 00:02:13,050
+اربع مجموعات مختلفة حوالين carbon هيكون منه ايش
+
+25
+00:02:13,050 --> 00:02:20,370
+مركب مركب واحد فقط الان كان ضروري جدا نقدر نميز
+
+26
+00:02:20,370 --> 00:02:25,490
+المركبين وقلنا ان التمييز بينهم من خلال ال
+
+27
+00:02:25,490 --> 00:02:32,090
+configuration ال configuration احدد 1R 1S الطريقة
+
+28
+00:02:32,610 --> 00:02:36,170
+انه انا امسك المركب .. انه انا امسك المركب اخلى
+
+29
+00:02:36,170 --> 00:02:41,270
+المجموعة الأقل للخلف و اتحرك حسب الأولويات اللى
+
+30
+00:02:41,270 --> 00:02:45,410
+اتعلمناها اللى كان انجلد برولوج رولز إذا بتحرك مع
+
+31
+00:02:45,410 --> 00:02:50,390
+عقاري بالساعة المركب بعطي وصف R وإذا بتحرك عكس
+
+32
+00:02:50,390 --> 00:02:55,000
+عقاري بالساعة بعطي المركب الوصفS هذا الكلام إذا
+
+33
+00:02:55,000 --> 00:02:59,880
+فيه معنى model إذا مافيش معنى model إذا مافيش معنى
+
+34
+00:02:59,880 --> 00:03:05,080
+model بدنا نتذكر إنه إحنا بنرسم المركب بهذا الشكل
+
+35
+00:03:05,080 --> 00:03:10,240
+واتفقنا إنه مش planner المركب يعني لما نرسمه زي
+
+36
+00:03:10,240 --> 00:03:15,040
+هيك هو حقيقة شكل فراغي بهذا الشكل في مجمعتين
+
+37
+00:03:15,040 --> 00:03:21,470
+للأمام وفي مجمعتين للخلففخلّينا نضل مركزين كتير
+
+38
+00:03:21,470 --> 00:03:25,410
+على هذه النقطة أن هذه المجموعة اللي موجودة هنا أو
+
+39
+00:03:25,410 --> 00:03:31,070
+هنا هي للأمام و المجموعة اللي موجودة هنا هي للخلف
+
+40
+00:03:31,070 --> 00:03:37,580
+بناء على ذلك لو أقل مجموعة وجدت على هذا المحورفهي
+
+41
+00:03:37,580 --> 00:03:42,180
+للخلف بتحرك في التلت مجموعات التانين الأعلى فالأقل
+
+42
+00:03:42,180 --> 00:03:46,080
+فالأقل وبكتب ال configuration مباشرة الآن لو أقل
+
+43
+00:03:46,080 --> 00:03:50,760
+مجموعة وجدت على الجنبين فهي للأمام يعني نتيجتها
+
+44
+00:03:50,760 --> 00:03:56,200
+هتطلع معكوسة وبناء على ذلك هتحرك في التلت مجموعات
+
+45
+00:03:56,200 --> 00:04:01,500
+التانين و أكتب عكس اللي بيطلع معاه عشان أصحح أن
+
+46
+00:04:01,500 --> 00:04:06,850
+هذه المجموعة أساسا مرسومة للأماملو افترضنا نعمل
+
+47
+00:04:06,850 --> 00:04:10,810
+مثال ان أكد فيه هذه الفكرة خلّينا نبدأ مثلا
+
+48
+00:04:10,810 --> 00:04:16,790
+بمجموعة اقل مجموعة تكون هنا يعني لو قولنا HPRCH3
+
+49
+00:04:16,790 --> 00:04:19,670
+مثلا floor okay
+
+50
+00:04:21,380 --> 00:04:25,520
+لحظوا هذا المركب لو بهذا الشكل إجيانا في الامتحان
+
+51
+00:04:25,520 --> 00:04:29,640
+name the following compound سمى المركب هذا طبعا
+
+52
+00:04:29,640 --> 00:04:34,320
+أول شي بدنا نسميه الكيميا العادية اللي هي تحديد
+
+53
+00:04:34,320 --> 00:04:40,140
+الذرات و أطول سلسلة و مواقع الذرات هذا انكون من
+
+54
+00:04:40,140 --> 00:04:46,780
+كام carbon؟ واحد اتنين على نمرة واحد عندى بروم و
+
+55
+00:04:46,780 --> 00:04:57,470
+floor إذا هذا كمركب وانبرومهوان فلورو اثان
+
+56
+00:04:57,470 --> 00:05:05,390
+واضح هاي carbon one وcarbon two وان برومو وان
+
+57
+00:05:05,390 --> 00:05:11,470
+فلورو اثان الآن بعد هيك بتطلع هل هذا ال carbon في
+
+58
+00:05:11,470 --> 00:05:17,350
+chiral center ولا لأ بمعنى ان في carbon تحمل اربع
+
+59
+00:05:17,350 --> 00:05:22,810
+مجموعات مختلفةمباشرة بنحط عليها نجمة إذا هذا
+
+60
+00:05:22,810 --> 00:05:28,690
+المركب هيكون واحد من اتنين يا R يا S باجي بتطلع أن
+
+61
+00:05:28,690 --> 00:05:33,290
+هي أقل مجموعة متصلة مباشرة بالcarbon ال H ال PR ال
+
+62
+00:05:33,290 --> 00:05:38,650
+floor ال CH3 واضح إنها ال H أقل مجموعة already
+
+63
+00:05:38,650 --> 00:05:43,650
+موجودة للخلف برتب المجموعات التلاتة التانين الأعلى
+
+64
+00:05:43,650 --> 00:05:50,460
+فالأقل فالأقلطبعا الأعلى لبروم بعدها لفلور بعدها
+
+65
+00:05:50,460 --> 00:05:56,960
+الكاربون إذا هاي واحد هاي تانين هاي تلاتة و بتحرك
+
+66
+00:05:56,960 --> 00:06:04,200
+واحد اتنين تلاتة كيف أنا ماشي؟ عكس عقارب الساعة
+
+67
+00:06:04,200 --> 00:06:10,880
+إذا هذا المركب S هيك بيصير الاسم تبعه كامل هذا
+
+68
+00:06:10,880 --> 00:06:18,070
+المركب S one bromo one floro E2واضح الفكرة؟ خلينا
+
+69
+00:06:18,070 --> 00:06:24,330
+ناخد مثال او مثلين ان اكد على هذه النقطة بيهمني
+
+70
+00:06:24,330 --> 00:06:29,770
+يصير انكم اتقان لهذه النقطة تحديدا لو افترضنا اننا
+
+71
+00:06:29,770 --> 00:06:32,410
+رسمنا مركب بهذا الشكل
+
+72
+00:06:48,630 --> 00:07:00,430
+وإجانة هذا المركب وسم المركب تسمية كاملة لحظوا
+
+73
+00:07:00,430 --> 00:07:04,830
+الناس المستعجلة قاعدة بتعطي إجابات غلط الكيميا
+
+74
+00:07:04,830 --> 00:07:09,870
+علم، systematic، بدنا نمشي فيه خطوة خطوة بدنا نقول
+
+75
+00:07:09,870 --> 00:07:16,690
+في الأول ما نوع المركبالكيل في double point إذا
+
+76
+00:07:16,690 --> 00:07:20,690
+يجب البحث عن أطول سلسلة تحتوي على ال double point
+
+77
+00:07:20,690 --> 00:07:23,770
+واحد،
+
+78
+00:07:23,770 --> 00:07:29,450
+اتنين، تلاتة، أربعة، خمسة إذا المركب اللي عندي
+
+79
+00:07:29,450 --> 00:07:35,870
+حقيقة بنتين هي أطول سلسلة أي بنتين؟
+
+80
+00:07:38,710 --> 00:07:42,690
+one بنتين يعني ال double bond اللي فيه على موقع
+
+81
+00:07:42,690 --> 00:07:50,690
+واحد اذا هذا one بنتين من وين الترقيم بالتأكيد
+
+82
+00:07:50,690 --> 00:07:56,650
+واحد اتنين تلاتة اربعة خمسة الان هذا عليه
+
+83
+00:07:56,650 --> 00:08:04,560
+substituentsعلى موقع تلاتة اكلور وعلى موقع تلاتة
+
+84
+00:08:04,560 --> 00:08:09,480
+مثل اذا ايش اسمه كمركب بيصير تلاتة اكلور تلاتة مثل
+
+85
+00:08:09,480 --> 00:08:14,860
+تلاتة اكلور تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+86
+00:08:14,860 --> 00:08:18,840
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+87
+00:08:18,840 --> 00:08:21,280
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+88
+00:08:21,280 --> 00:08:22,140
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+89
+00:08:22,140 --> 00:08:23,100
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+90
+00:08:23,100 --> 00:08:28,440
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تل
+
+91
+00:08:29,570 --> 00:08:35,150
+مافيش غيرها نهائيًا، مافيش غيرها نهائيًا، الآن بدي
+
+92
+00:08:35,150 --> 00:08:38,410
+أطلع على المجموعات الأربعة اللي على هذا ال carbon
+
+93
+00:08:38,410 --> 00:08:44,430
+أنهي أقل مجموعة، عندي halogenو carbon و carbon و
+
+94
+00:08:44,430 --> 00:08:49,810
+carbon أكيد ال halogen هي المجموعة الأعلى نمرة
+
+95
+00:08:49,810 --> 00:08:54,650
+واحد خلصت من ال halogen الآن ال carbons carbon
+
+96
+00:08:54,650 --> 00:08:58,210
+متصلة ب اتنين carbons ولا carbon متصلة ب carbon
+
+97
+00:08:58,210 --> 00:09:04,710
+ولا carbon متصلة ب etches المتصلة بال carbon مرتين
+
+98
+00:09:04,710 --> 00:09:13,160
+هي نمرة اتنين هذه اللي بيبين ك ethylنمرة 3 هذه
+
+99
+00:09:13,160 --> 00:09:22,700
+نمرة 2 هذه نمرة 4 الألوان أصغر مجموعة ال CH3 في
+
+100
+00:09:22,700 --> 00:09:28,500
+هذه الحالة أصغر مجموعة ال CH3 لاحظوا اكتبوا جنبه
+
+101
+00:09:28,500 --> 00:09:33,340
+عشان ما تغلطوش موجودة للأمام إذا اللي بيطلع عندكم
+
+102
+00:09:33,340 --> 00:09:36,500
+بس تكتبوا عكسه عشان تطلعوا ال configuration الصح
+
+103
+00:09:37,530 --> 00:09:45,610
+واضح؟ فلما انا بمشي واحد اتنين تلاتة R اذا S هذا
+
+104
+00:09:45,610 --> 00:09:59,190
+المركب زيه اللي هيكون اسمه الكلام
+
+105
+00:09:59,190 --> 00:10:07,570
+جميل وكمان مثال بضر ولا ما بضر؟كمان مثال مابضرش
+
+106
+00:10:07,570 --> 00:10:16,830
+خلنا ناخد كمان مثال أي سؤال على السريع ايه
+
+107
+00:10:16,830 --> 00:10:24,390
+السؤال؟ السبق
+
+108
+00:10:24,390 --> 00:10:29,130
+اتفقنا العلم كامل و هذا الكلام مش موضوع ان نسأل
+
+109
+00:10:29,130 --> 00:10:34,710
+عنه ايش اعمل في الامتحان و كيف اسلحالجواب زي هيك
+
+110
+00:10:34,710 --> 00:10:39,990
+كامل، الآن ما عدا هيك العشرة بتصير تمانية و سبعة و
+
+111
+00:10:39,990 --> 00:10:45,690
+ستة، هذا بيبطل موضوعكم أستاذ ليش رقمت هناك اتنين و
+
+112
+00:10:45,690 --> 00:10:50,920
+هالتلاتة؟ الأجين و الأتلاتة عايشون؟هذا الكلام سبق
+
+113
+00:10:50,920 --> 00:10:55,620
+أننا أخدناه لما كنا بنحكي عن كان English Dibrelog
+
+114
+00:10:55,620 --> 00:11:01,360
+Rules والأصل أن الطالب يكون متذكره من هذه المنطقة،
+
+115
+00:11:01,360 --> 00:11:06,720
+يكون مراجع ومتذكر كويس، الآن هذه carbon تتصل
+
+116
+00:11:06,720 --> 00:11:14,560
+بماذا؟ بH و بcarbonو ب carbon هذه ال carbon تتصل
+
+117
+00:11:14,560 --> 00:11:20,040
+بماذا؟ ب H و ب carbon لاحظوا الطالب اللي مابيرجعش
+
+118
+00:11:20,040 --> 00:11:27,730
+كويس بيجي يسأل في نقطةقديمة الكيميا مبنية على بعض
+
+119
+00:11:27,730 --> 00:11:32,910
+يعني في هذا المثال جيبنا طول السلسلة من chapter ال
+
+120
+00:11:32,910 --> 00:11:35,490
+alkanes جيبنا ال double bond و مكانها من chapter
+
+121
+00:11:35,490 --> 00:11:38,830
+ال alkanes جيبنا ترتيب الأولويات من chapter ال
+
+122
+00:11:38,830 --> 00:11:42,970
+alkanes جيبنا ال R و ال S من chapter خمسةالان
+
+123
+00:11:42,970 --> 00:11:47,870
+مابنقدرش احنا ننسى الكلام السابق اللى اتعلمناه
+
+124
+00:11:47,870 --> 00:11:52,490
+واضح هذه النقطة خلينا نعطى مثال تانى لو مثلا اجينا
+
+125
+00:11:52,490 --> 00:12:02,610
+كتبنا carbon C triple bond C CH3 وحطينا كمان هنا
+
+126
+00:12:02,610 --> 00:12:12,350
+CH3 وحطينا كمان هنا على سبيل المثالخليها دي double
+
+127
+00:12:12,350 --> 00:12:18,050
+bond زي
+
+128
+00:12:18,050 --> 00:12:21,050
+هيك و حطينا هنا chlorine
+
+129
+00:12:26,900 --> 00:12:31,620
+لاحظوا هذا مركّب بتكون تعرفوا في الأول تتأملوا
+
+130
+00:12:31,620 --> 00:12:36,920
+بشكل عام على أي تسمية بتكون تسموها البعض هيفكر أنه
+
+131
+00:12:36,920 --> 00:12:41,460
+فيه بنزين لكن صعب أن نلاقي اسم لهذه المجموعة لذلك
+
+132
+00:12:41,460 --> 00:12:47,240
+ما بنسميه كمشتقة بنزين بنبحث عنه كمركب متسلسل
+
+133
+00:12:47,240 --> 00:12:52,880
+كمركب متسلسل هذاإتنين بنتين .. إتنين بنتين ..
+
+134
+00:12:52,880 --> 00:13:01,300
+إتنين بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين
+
+135
+00:13:01,300 --> 00:13:01,720
+بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين بنتين
+
+136
+00:13:01,720 --> 00:13:02,400
+.. إتنين بنتين .. إتنين بنتين .. إتنين بنتين ..
+
+137
+00:13:02,400 --> 00:13:02,520
+إتنين بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين
+
+138
+00:13:02,520 --> 00:13:02,960
+بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين بنتين
+
+139
+00:13:02,960 --> 00:13:03,100
+.. إتنين بنتين .. إتنين بنتين .. إتنين بنتين ..
+
+140
+00:13:03,100 --> 00:13:05,820
+إتنين بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين
+
+141
+00:13:05,820 --> 00:13:11,200
+بنتين .. إتنين بنتين .. إتنين بنتين ..يكون مبين في
+
+142
+00:13:11,200 --> 00:13:15,860
+الـ S والـ Trans والـ Z والـ E مثلا بهذا الشكل هاي
+
+143
+00:13:15,860 --> 00:13:21,360
+carbon ممكن تلاقوه بهذا الشكل تجمع كل الكلام اللي
+
+144
+00:13:21,360 --> 00:13:26,540
+انتوا اتعلمتهوا
+
+145
+00:13:26,540 --> 00:13:33,020
+الان
+
+146
+00:13:33,020 --> 00:13:40,390
+لاحظوا هذا المركب ايش موجود فيه ال keenوالألكين في
+
+147
+00:13:40,390 --> 00:13:44,110
+مجموعتين مختلفات و مجموعتين مختلفات إذا حتبدوا
+
+148
+00:13:44,110 --> 00:13:49,550
+تفكروا بالـ Cis و Trans أو Z و E في chiral center
+
+149
+00:13:49,550 --> 00:13:56,250
+كمان يعني في شغلتين ال stereo chemistry واضح؟ مش
+
+150
+00:13:56,250 --> 00:14:01,580
+ال cis و ال trans بيعطيني ال diastereomers ال Zو
+
+151
+00:14:01,580 --> 00:14:04,280
+ال E أو ال cis و ال trans و ال chiral center
+
+152
+00:14:04,280 --> 00:14:09,460
+بيعطيني R و S لان هذا في bubble bond و في ال
+
+153
+00:14:09,460 --> 00:14:13,500
+chiral center موجودة هنا قبل ما نتوقف في ال stereo
+
+154
+00:14:13,500 --> 00:14:18,220
+chemistry خلينا نشوف السلسلة المركبة كسلسلة ايش
+
+155
+00:14:18,220 --> 00:14:24,670
+بده اسمي انابدي أطول سلسلة مزال بسمع كلمات بنتين
+
+156
+00:14:24,670 --> 00:14:31,450
+واحد اتنين تلاتة اربعة خمسة هي أطول سلسلة و العد
+
+157
+00:14:31,450 --> 00:14:37,690
+من هنا عشان نخليها ايش two بنتين اذا هنا كلمة two
+
+158
+00:14:37,690 --> 00:14:45,810
+بنتين سليمة الان هذه أطول سلسلة ايش بتحمل بإمكانك
+
+159
+00:14:45,810 --> 00:14:54,360
+تطلع نهاية كسلسلةهذه كلها السلسلة على موقع اربعة
+
+160
+00:14:54,360 --> 00:15:01,540
+عندى فيها four chloro four
+
+161
+00:15:01,540 --> 00:15:09,440
+phenyl four chloro four phenyl two pentene الان
+
+162
+00:15:09,440 --> 00:15:15,990
+خلصت المواقع دل عندى جزءالاستيريو كيميسترا جزء
+
+163
+00:15:15,990 --> 00:15:21,990
+الاستيريو كيميسترا كيف شكل المجموعات هنا هنجي نقول
+
+164
+00:15:21,990 --> 00:15:29,530
+اكش ولا مثل؟ مين اعلى؟ مثل واضحة اذا هذه المجموعة
+
+165
+00:15:29,530 --> 00:15:33,330
+خلينا نقول الاعلى الكاربون هذا اكش ولا كاربون؟
+
+166
+00:15:33,330 --> 00:15:37,530
+كاربون هذا الاعلى الان الاعلى على جهة واحدة ولا
+
+167
+00:15:37,530 --> 00:15:43,640
+على جهتين متعاكستين؟على جهتين متعاكستين هاي هذه
+
+168
+00:15:43,640 --> 00:15:50,000
+على جهة وهذه على الجهة التانية إذا المركب هذا E او
+
+169
+00:15:50,000 --> 00:15:55,480
+Trans احنا قولنا إذا المركب فيه شوية تعمل E الآن
+
+170
+00:15:55,480 --> 00:16:02,220
+ضال عندى حوالين ال chiral center هالمركب هذا R ولا
+
+171
+00:16:02,220 --> 00:16:09,240
+Sواضح؟ بدي أجي أطلع على هذه الـ carbon و أقول وين
+
+172
+00:16:09,240 --> 00:16:13,960
+أقل مجموعة و وين أعلى مجموعة الان الهالوجين كاربون
+
+173
+00:16:13,960 --> 00:16:22,040
+كاربون كاربون إذا نمرة واحد الهالوجين بعد هيك
+
+174
+00:16:22,040 --> 00:16:28,160
+خلّينا نتذكر إنه في البنزينة الكاربون ما بنشتغل
+
+175
+00:
+
+223
+00:20:51,910 --> 00:20:56,790
+الفيزيائية و من ناحية الخواص الكيميائية يمكن هذا
+
+224
+00:20:56,790 --> 00:21:02,770
+ال slide موجودة شوية للامام هتلاحظوا بس احنا بدنا
+
+225
+00:21:02,770 --> 00:21:08,160
+نشوف ال enantiomers دولةمن ناحية خواص فيزيائية و
+
+226
+00:21:08,160 --> 00:21:11,740
+من ناحية خواص كيميائية بإيش بيختلفوا و بعد ذلك
+
+227
+00:21:11,740 --> 00:21:15,440
+برضه بدي أشوف ال diastereomers من ناحية خواص
+
+228
+00:21:15,440 --> 00:21:20,980
+فيزيائية و من ناحية خواص كيميائية بإيش بيختلفوا
+
+229
+00:21:20,980 --> 00:21:29,640
+واضح؟ الآن طبعا ع السريع بتكونوا عارفين إيش معنى
+
+230
+00:21:29,640 --> 00:21:35,010
+خواص فيزيائية و إيش معنى خواص كيميائيةاحنا بنقول
+
+231
+00:21:35,010 --> 00:21:40,290
+الخواص الفيزيائية هي الخواص التي يمكن أن نقيسها
+
+232
+00:21:40,290 --> 00:21:45,310
+دون أن نغير في تركيب المادة يعني المادة بتضال زي
+
+233
+00:21:45,310 --> 00:21:51,190
+ما هي على سبيل المثال عندي ماءبدي أقيسله الحجم،
+
+234
+00:21:51,190 --> 00:21:55,170
+قست الحجم بعد ما قسته، الماء ما زال زي ما هو ولا
+
+235
+00:21:55,170 --> 00:22:00,770
+لأ؟ بدي أقيسله الكتلة، قست الكتلة، الماء ما زال زي
+
+236
+00:22:00,770 --> 00:22:05,310
+ما هو ولا لأ؟ بدي أقيسله الكثافة، قسمت الكتلة على
+
+237
+00:22:05,310 --> 00:22:11,190
+الحجم، والماء ما زالة؟موجودا بدا قص معامل الانكسار
+
+238
+00:22:11,190 --> 00:22:17,530
+جبت الماء و حطيته في وعاء و أسقطت عليه الضوء و قصت
+
+239
+00:22:17,530 --> 00:22:21,910
+زاوية الانكسار او معامل الانكسار بعد هيك لو بد
+
+240
+00:22:21,910 --> 00:22:26,310
+الماء الماء ما زال موجودا اذا كل القياسات عملتها
+
+241
+00:22:26,310 --> 00:22:30,850
+من غير ما اغير في تركيب الماء بهذا الشكل تكون
+
+242
+00:22:30,850 --> 00:22:35,790
+الخاصيةفيزيائية إذا ال physical probity is a
+
+243
+00:22:35,790 --> 00:22:39,350
+probity that can be measured without changing the
+
+244
+00:22:39,350 --> 00:22:42,790
+chemical makeup of the substance لكن لو كنت أقول
+
+245
+00:22:42,790 --> 00:22:46,010
+إيش يعني chemical probity ال chemical probity
+
+246
+00:22:46,010 --> 00:22:50,530
+تفاعل والتفاعل يغير المادة أبسط تعريف لل chemical
+
+247
+00:22:50,530 --> 00:22:54,930
+probity هي تفاعل يعني لو مثلا إجيت قولت الماء مع
+
+248
+00:22:54,930 --> 00:22:59,300
+الصوديومبقول والله خلّينا نحط صوديوم على ميّه
+
+249
+00:22:59,300 --> 00:23:03,300
+حطينا صوديوم على كمية ميّه صغيرة بحذر لأنه التفاعل
+
+250
+00:23:03,300 --> 00:23:08,160
+خطير لاحظنا أنه بينطلق غاز هيدروجين وممكن كمان
+
+251
+00:23:08,160 --> 00:23:12,180
+يشتعل مع حرارة التفاعل ويعمل عندنا فرقعة وبتكون
+
+252
+00:23:12,180 --> 00:23:16,000
+هيدروكسيد الصوديوم وما إلى ذلك الآن بعد ما خلصنا
+
+253
+00:23:16,000 --> 00:23:21,940
+هالكلام اجينا قلنالكم لو سمحتوا راجعولنا الميّهأي
+
+254
+00:23:21,940 --> 00:23:26,860
+مية؟ المية اتفعلت المية صارت هيدروكسيد السوديوم
+
+255
+00:23:26,860 --> 00:23:31,080
+إذا أنا لما درست الخاصية الكيميائية فعلت المية ف
+
+256
+00:23:32,350 --> 00:23:37,010
+خلصت الميه، اتغيرت تركيبها، لكن لما جابلي شوية جسد
+
+257
+00:23:37,010 --> 00:23:41,810
+خمس، ست خواص فيزيائية كتلة وحجم ومعامل انكسار وما
+
+258
+00:23:41,810 --> 00:23:46,470
+إلى ذلك، الميه غيرت فيها إشي، إذا نفهمنا إيش الفرق
+
+259
+00:23:46,470 --> 00:23:50,290
+بين الخواص الفيزيائي والكيميائي، الآن لو إجينا
+
+260
+00:23:50,290 --> 00:23:55,240
+بنتكلم على الانانش ومرز و الخواص الفيزيائيبنقول
+
+261
+00:23:55,240 --> 00:23:59,280
+احنا الانانشو مارز they have the same physical
+
+262
+00:23:59,280 --> 00:24:03,020
+properties except for direction of rotation of a
+
+263
+00:24:03,020 --> 00:24:08,200
+plane polarized light يعني هناك عدد كبير من الخواص
+
+264
+00:24:08,200 --> 00:24:12,140
+الفيزيائية، قولوا خمسين خصية ما إلى ذلك مايفرجش
+
+265
+00:24:12,140 --> 00:24:16,060
+عندنا ال two enansho marz اللي هما هيكونوا واحد
+
+266
+00:24:16,060 --> 00:24:23,640
+منهم R والتاني S يشتركوا في جميع الخواص الفيزيائية
+
+267
+00:24:23,890 --> 00:24:31,990
+مثل الكثافة مثل نقطة الغليان مثل نقطة الانصحار مثل
+
+268
+00:24:31,990 --> 00:24:37,850
+معامل الانكسار كلهم لو اتيت against لهم يشتركوافي
+
+269
+00:24:37,850 --> 00:24:44,710
+جميع الخواص الفيزيائية ما عدا خاصية واحدة فقط هذه
+
+270
+00:24:44,710 --> 00:24:49,450
+الخاصية احنا ممكن نقول عنها بالعربي خاصية اللي
+
+271
+00:24:49,450 --> 00:24:54,470
+علاقة بالفيزيا خاصية تدوير الضوء المستقطب في مستوى
+
+272
+00:24:54,470 --> 00:25:01,350
+واحدخاصية ضوئية بندرسها احنا بالفيزيا الان بدنا
+
+273
+00:25:01,350 --> 00:25:07,210
+نفهم ايش معناه ببساطة طبعا هذه الخاصية الفيزيائية
+
+274
+00:25:07,210 --> 00:25:14,020
+هذه الخاصية الفيزيائية الحقيقة احنا بنقيسهامن خلال
+
+275
+00:25:14,020 --> 00:25:18,880
+جهاز .. جهاز تدوير الضوء او بنسميه احنا البولاري
+
+276
+00:25:18,880 --> 00:25:24,840
+ميتر اش بنسميه الجهاز اللي بنقيس فيه البولاري ميتر
+
+277
+00:25:24,840 --> 00:25:31,480
+جهاز تدوير الضوء ببساطة هذا الجهاز بنجيب فيه ضوء
+
+278
+00:25:32,210 --> 00:25:36,810
+والضوء بنمرره على مستقطب بيصير ال vibration تبعه
+
+279
+00:25:36,810 --> 00:25:40,090
+باتجاه واحد، يعني تخيلوا أن هذا اللي موجود بإيدي
+
+280
+00:25:40,090 --> 00:25:44,530
+هو شعاع الضوء، الآن شعاع الضوء بيمشي للأمام، و
+
+281
+00:25:44,530 --> 00:25:50,790
+شعاع الضوء موجة كهرومغناطيسية، و الموجة إلها إيش؟
+
+282
+00:25:50,790 --> 00:25:55,590
+اهتزاز أو تردد، الآن أول ما بيطلع شعاع الضوء بيكون
+
+283
+00:25:55,590 --> 00:26:00,790
+يهتز بجميع الاتجاهاتيعني بهذا الشكل وبهذا الشكل
+
+284
+00:26:00,790 --> 00:26:06,070
+وبهذا الشكل وبهذا الشكل بنمرره على جهاز في الضوء
+
+285
+00:26:06,070 --> 00:26:10,470
+اسمه Polarimeter ال Polarimeter أسهل شيء ممكن
+
+286
+00:26:10,470 --> 00:26:18,110
+تتخيلوا فيه أنه مثل شيء معين فيه فتحة في النص يعني
+
+287
+00:26:18,110 --> 00:26:23,630
+زي هيك شايفين هذه الورقة؟الان هى فيها فتحة او slit
+
+288
+00:26:23,630 --> 00:26:28,590
+الان لو انا عند الضوء هنا يهتز بجميع الاتجاهات
+
+289
+00:26:28,590 --> 00:26:34,990
+بهذا الشكل واضح مررته على البولاريمتر فى فتحة اى
+
+290
+00:26:34,990 --> 00:26:37,910
+اهتزاز اللى بده يطلع من هذه الفتحة
+
+291
+00:26:40,630 --> 00:26:46,970
+فقط اهتزاز واحد الباقي كله ايش هينحجز بناء على ذلك
+
+292
+00:26:46,970 --> 00:26:50,770
+الضوء قبل ما يمر على ال polarimeter بنسميه
+
+293
+00:26:50,770 --> 00:26:54,850
+unpolarized light يعني اول ما بيطلع هنا بيكون عند
+
+294
+00:26:54,850 --> 00:27:01,050
+ال light unpolarized يهتز في جميع الاتجاهات مررتوا
+
+295
+00:27:01,050 --> 00:27:05,500
+على ال polarimeter اللي فيهمفتحة طبعا بيكون من
+
+296
+00:27:05,500 --> 00:27:09,600
+خلال بلورات بس ناخد الفكرة البساطة صار يهتز الضوء
+
+297
+00:27:09,600 --> 00:27:16,140
+في اتجاه واحد فبنسميه polarized light اذا صار عنده
+
+298
+00:27:16,140 --> 00:27:22,640
+الضوء polarized يهتز في اتجاه واحد unpolarized
+
+299
+00:27:22,640 --> 00:27:30,200
+يهتز في اتجاهفي جميع الاتجاهات الان هذا الضوء اللي
+
+300
+00:27:30,200 --> 00:27:35,320
+بيقول polarized بمرره على المركب تبعي مش انا اتفقت
+
+301
+00:27:35,320 --> 00:27:41,630
+ان عندي مركبينواحد R واحد S بجيب المركب بدوبه
+
+302
+00:27:41,630 --> 00:27:46,170
+بمحلول بحطه في أنبوبة زجاجية عادة زي هذا الجلم
+
+303
+00:27:46,170 --> 00:27:50,650
+يعني الأنبوبة طولها عادة عشرة سنتيمتر لغطاية زي
+
+304
+00:27:50,650 --> 00:27:55,750
+هيك بندوب المركب absorbent بنحطه و بنسكر عليه
+
+305
+00:27:55,750 --> 00:27:59,810
+بالغطاية بنحطه في مسار الضوء الآن تخيلوا الضوء كيف
+
+306
+00:27:59,810 --> 00:28:05,400
+قاعد بحتزفى مستوى واحد لما يمر فى أحد هدولة
+
+307
+00:28:05,400 --> 00:28:12,160
+الانانشو مارز بيروح بلوف طلعوا معاه كان يهتز بهذا
+
+308
+00:28:12,160 --> 00:28:18,460
+الاتجاه مر بيطلع يهتز باتجاه مختلف ملاحظين؟ طيب
+
+309
+00:28:18,460 --> 00:28:23,060
+السؤال لو ياتورا مر بمركب مافيش منه R.O.S يعني
+
+310
+00:28:23,060 --> 00:28:25,760
+بمية بيظله
+
+311
+00:28:26,790 --> 00:28:31,170
+بهذا الشكل بمر الميه بيتأثرش عليه بيطلع احتزازه
+
+312
+00:28:31,170 --> 00:28:38,430
+بنفس الشكل لكن لو ماربل ار بيلوف بيصيله عملية ايش
+
+313
+00:28:38,430 --> 00:28:45,430
+روتيشن الان احنا بنقدر نستقبل الشعاع الضوءي ونشوف
+
+314
+00:28:45,430 --> 00:28:51,370
+كده زاويةالدوران اللى لفها يعني هيه بهذا الشكل
+
+315
+00:28:51,370 --> 00:28:55,950
+لفها القدر عشرين درجة تلاتين اربعين بنقدر هذا
+
+316
+00:28:55,950 --> 00:28:59,870
+الكلام نعمله تطبيقيا من خلال جهاز ال polarimeter
+
+317
+00:28:59,870 --> 00:29:05,130
+اللى بنلاحظه القاتلإنه لو واحد من هدولة
+
+318
+00:29:05,130 --> 00:29:10,390
+الانانشومارز كان بيلف الضوء باتجاه معين وبزاوية
+
+319
+00:29:10,390 --> 00:29:15,370
+معينة نفترض بيلف الضوء باتجاه اليمين بزاوية تلاتين
+
+320
+00:29:15,370 --> 00:29:22,010
+درجة المركب التاني نفس الكمية منه بتلف الضوء
+
+321
+00:29:22,010 --> 00:29:28,390
+بالاتجاه المعاكس بنفس المقدار إذا الاختلاف الآن
+
+322
+00:29:28,390 --> 00:29:33,490
+بمقدار الدوران بين المركبين ال R و ال Sلأ إذا
+
+323
+00:29:33,490 --> 00:29:39,870
+استعملت نفس الكمية فقط الاختلاف يكون بماذا؟ باتجاه
+
+324
+00:29:39,870 --> 00:29:45,830
+الدوران فواحد منهم بلف الضوء باتجاه اليمين وواحد
+
+325
+00:29:45,830 --> 00:29:48,410
+منهم بلف الضوء يعني لو أنا اتخيلت أنه عندي زي
+
+326
+00:29:48,410 --> 00:29:53,030
+مانجلة أو ما إلى ذلك إذا واحد منهم لف الضوء بهذا
+
+327
+00:29:53,030 --> 00:29:57,770
+الاتجاه تلاتين درجة التاني بلف الضوء بهذا الاتجاه
+
+328
+00:29:57,770 --> 00:30:05,350
+ناقص تلاتينطبعا الشرط ان انا استعمل نفس الكمية من
+
+329
+00:30:05,350 --> 00:30:09,690
+المركبين واضح؟ الشرط ان انا استعمل نفس الكمية من
+
+330
+00:30:09,690 --> 00:30:14,410
+المركبين ولذلك لو انتوا انتبهتوا لما انا حكيت عن
+
+331
+00:30:14,410 --> 00:30:18,230
+الخاصية الفيزيائية الجولية بيختلفوا بال direction
+
+332
+00:30:18,230 --> 00:30:24,730
+of rotation اتجاه التدوير ماقلتش بال amount of
+
+333
+00:30:24,730 --> 00:30:31,140
+rotationنفس الكمية من ال R و نفس الكمية من ال S
+
+334
+00:30:31,140 --> 00:30:36,240
+بيختلفوا بس بالاتجاه واحدة بتلفه على اليمين
+
+335
+00:30:36,240 --> 00:30:43,220
+والتانية بتلفه لليسار لكن ما بيختلفوا بالمقدار هذا
+
+336
+00:30:43,220 --> 00:30:47,100
+هو الاختلاف ما بين ال enantiomers بال physical
+
+337
+00:30:47,100 --> 00:30:50,700
+Proparities واحد بيلف على اليمين و واحد بيلف على
+
+338
+00:30:50,700 --> 00:30:59,490
+اليسارالان إذا هذه الفكرة وهي الأساس أصبحت واضحة
+
+339
+00:30:59,490 --> 00:31:04,210
+خلّينا الآن نضيف عليها شوية أفكار بسيطة لما
+
+340
+00:31:04,210 --> 00:31:10,170
+اتكلمنا على الكمية مش احنا قلنا بندوّببندوّب كمية
+
+341
+00:31:10,170 --> 00:31:12,910
+من المُركّب وبنحطها في الأنبوبة تبع
+
+342
+00:31:12,910 --> 00:31:18,270
+الـPolarimeter؟ طيب، أنا ممكن أدوّب كمية صغيرة؟
+
+343
+00:31:18,270 --> 00:31:22,090
+ممكن أكتر؟ ممكن أكتر؟ ممكن أكتر؟ يعني ممكن أعمل
+
+344
+00:31:22,090 --> 00:31:28,190
+عدد كبير من التركيز؟ أكيد، خلّيني أقول مثلا، لو
+
+345
+00:31:28,190 --> 00:31:30,610
+أعمل التركيز واحد، concentration one,
+
+346
+00:31:30,730 --> 00:31:32,910
+concentration two, concentration three,
+
+347
+00:31:33,250 --> 00:31:37,480
+concentration fourبقدر اعمل اكتر من التركيز و
+
+348
+00:31:37,480 --> 00:31:42,020
+خلّيني افترض ان التركيز بتزيد بهذا الشكل و انا
+
+349
+00:31:42,020 --> 00:31:45,720
+بجيس الزاوية للمركب اللي عملت منه اكتر من التركيز
+
+350
+00:31:45,720 --> 00:31:51,030
+الزاوية اللي بقيسها بعطيها رمز Alphaتمام ل
+
+351
+00:31:51,030 --> 00:31:56,750
+Concentration 1 بقيس زاوية Alpha 1 ل Concentration
+
+352
+00:31:56,750 --> 00:32:01,270
+2 Alpha 2 ل Concentration 3 Alpha 3 ل
+
+353
+00:32:01,270 --> 00:32:05,770
+Concentration 4 Alpha 4 يعني صار عندى اكتر من
+
+354
+00:32:05,770 --> 00:32:10,270
+زاوية الدوران هذه ال Alpha بقول عنها Observed
+
+355
+00:32:10,270 --> 00:32:15,090
+Rotation اللى هو Observed
+
+356
+00:32:15,850 --> 00:32:20,130
+rotation اللى هو الدوران اللى انا لاحظته بالجهاز
+
+357
+00:32:20,130 --> 00:32:26,410
+هل معقول يا تورا انه يكون عندى لكل تركيز اكثر
+
+358
+00:32:26,410 --> 00:32:32,090
+زاوية لكل تركيز معين زاوية معينة الجواب اه وبسيط
+
+359
+00:32:32,090 --> 00:32:37,430
+جدا اتخيلوا واتذكروا معايا لو كان عندكم على سبيل
+
+360
+00:32:37,430 --> 00:32:45,590
+المثال خمس أحجام من الميهكباية، شاف، طنجرة، كل
+
+361
+00:32:45,590 --> 00:32:52,350
+واحدة فيها ميّه الحجم الأول له كتلة أولى الحجم
+
+362
+00:32:52,350 --> 00:32:58,190
+التاني له كتلة تانية الحجم التالت له كتلة تالتة
+
+363
+00:32:58,190 --> 00:33:01,370
+مظبوط ولا لأ الكتلة و الحجم بيعتمدوا على كمية
+
+364
+00:33:01,370 --> 00:33:09,390
+المادة، مقدارها الآن إذا لكل حجم كتلة لكل تركيز
+
+365
+00:33:10,220 --> 00:33:15,400
+زاوية الآن الحجم والكتلة عمري ما أخدتهم أنا كخاصية
+
+366
+00:33:15,400 --> 00:33:21,140
+أعرف من خلالهم المية لماذا؟ لأن الماء له عدد لا
+
+367
+00:33:21,140 --> 00:33:27,540
+نهائي من الكتل وله عدد لا نهائي من الأحجام واضح؟
+
+368
+00:33:27,540 --> 00:33:31,440
+طب هايش الخاصية اللي في منها بس قيمة واحدة للمية
+
+369
+00:33:31,440 --> 00:33:39,400
+لا تعتمد على المقدار ال density الكثافة لو جبت أنا
+
+370
+00:33:40,220 --> 00:33:45,140
+كل كتلة قِستة يعني لو عملت 100 حجم و قِستلهم 100
+
+371
+00:33:45,140 --> 00:33:47,740
+كتلة كل مرة الكتلة على الحجم الكتلة على الحجم
+
+372
+00:33:47,740 --> 00:33:51,220
+الكتلة على الحجم الكتلة على الحجم نفس المقدار
+
+373
+00:33:51,220 --> 00:33:55,520
+تماما ال density إذا الكتلة و الحجم يعتمدوا على
+
+374
+00:33:55,520 --> 00:33:59,400
+المقدار منهم عدد لنهائي موجود لأي مادة لكن ال
+
+375
+00:33:59,400 --> 00:34:03,780
+density للميه لو سألتكم عند الحرارة العادية كم
+
+376
+00:34:03,780 --> 00:34:08,550
+كثافة الماء1 جرام لكل سنتمتر مكعب
+
+377
+00:34:12,120 --> 00:34:17,440
+فقط لغير هو اللي بنسجله كخاصية للمق في الكتب الأن
+
+378
+00:34:17,440 --> 00:34:23,700
+نفس الكلام تماما لكل تركيز زاوية دوران طيب يا تورا
+
+379
+00:34:23,700 --> 00:34:29,380
+لو أنا بعد هيك بدي مقدار واحد للمركب أنا صار عند
+
+380
+00:34:29,380 --> 00:34:34,160
+ألف واحد ألف اتنين ألف تلات ألف أربعة باجي بعرف
+
+381
+00:34:34,160 --> 00:34:41,730
+كمية بسميها ل specific rotation الدوران النوعيالان
+
+382
+00:34:41,730 --> 00:34:45,410
+الـ specific rotation بيساوي الـ observed rotation
+
+383
+00:34:45,410 --> 00:34:51,490
+الألفة مقسوم على طول الأنبوبة بالديسميتر بتعرف
+
+384
+00:34:51,490 --> 00:34:55,530
+الديسميتر كام سانتي؟ عشرة سانتي يعني واحد في عشر
+
+385
+00:34:55,530 --> 00:34:59,810
+أقصى ناقص واحد من المتر وإحنا عادة الأنبوبة
+
+386
+00:34:59,810 --> 00:35:04,600
+عاملينها ديسميتر يعني بتكون القيمة جديش؟وحد ديسمتر
+
+387
+00:35:04,600 --> 00:35:09,660
+على التركيز للمادة بالإجرام لكل ملل، لاحظوا قسمة
+
+388
+00:35:09,660 --> 00:35:14,500
+الالف على التركيز كعلمي الف واحد على C واحد، الف
+
+389
+00:35:14,500 --> 00:35:17,020
+اتنين على C اتنين، الف تلاتة على C تلاتة، الف
+
+390
+00:35:17,020 --> 00:35:22,320
+أربعة على C أربعة، خلّيت طول الأنبوبة نفس الشيء،
+
+391
+00
+
+445
+00:39:40,690 --> 00:39:45,930
+homework ادخلوا على الكمبيوتر و اكتبوا اسم مركبين
+
+446
+00:39:45,930 --> 00:39:51,290
+هذول المركبين كايرال هذول المركبين لو كان عندكم
+
+447
+00:39:51,290 --> 00:39:55,830
+carbon تنتين تلاتة أربعة وهي carbon تنتين تلاتة
+
+448
+00:39:55,830 --> 00:40:02,490
+أربعة لو حطيت هنا chlorine افترض OH وحطيت هنا OH و
+
+449
+00:40:02,490 --> 00:40:07,310
+هنا H وكملوا
+
+450
+00:40:07,310 --> 00:40:17,370
+المركب يعني CH3 CH2 CH3 و هذا CH3 CH2 CH3 الآن
+
+451
+00:40:17,370 --> 00:40:24,370
+هذولا المركبين chiral ولا لأ؟ chiral الآن هذا
+
+452
+00:40:24,370 --> 00:40:30,080
+المركب اسمه two-chlorobutane بتقدر تحددوله ROS
+
+453
+00:40:30,080 --> 00:40:34,640
+بالقواعد اللي اتعلمتوهم؟ حددوا ايه له ROS؟ وهذا
+
+454
+00:40:34,640 --> 00:40:41,320
+اسمه Top-Butanol بنقدر نحددله ROS؟ بنقدر، اذا ان
+
+455
+00:40:41,320 --> 00:40:47,150
+انا احدد للمركب ROS من وين بجيبهم؟من المجموعات
+
+456
+00:40:47,150 --> 00:40:51,870
+والأولويات الآن بعد هيك لما تحددوا نفترض هذا طلع R
+
+457
+00:40:51,870 --> 00:40:57,430
+روحوا شوفولي ال R-2-chlorobutane بالكتالوجي من
+
+458
+00:40:57,430 --> 00:41:02,890
+الكمبيوتر قدش قيمة ال alpha تبعته وبعدها نفترض هذا
+
+459
+00:41:02,890 --> 00:41:08,490
+طلع S or whatever 2-butanol شوفولي من الكتالوجي
+
+460
+00:41:08,490 --> 00:41:12,790
+اضربه على ال google search نفترض كام S-2-butanol
+
+461
+00:41:12,790 --> 00:41:20,040
+او R-2-butanol شوفوليجداش الزاوية تبعته واضح؟ الان
+
+462
+00:41:20,040 --> 00:41:24,740
+خليكم معاه لو افترضنا هذا المركب او ممكن نعمله
+
+463
+00:41:24,740 --> 00:41:29,540
+بسهولة ايه موجود هذه هنا واحد اتنين تلاتة هذا R
+
+464
+00:41:29,540 --> 00:41:35,340
+راحت واحدة فتشت في الكمبيوتر لجت ان ال S2 كلورو
+
+465
+00:41:35,340 --> 00:41:41,240
+بيوتين ناقص عشرين مالجتش ال R بتحل ال .. بتحل ال
+
+466
+00:41:41,240 --> 00:41:48,650
+homework ولا لأ؟إذا عرف واحد التاني عكسهواضح؟ يعني
+
+467
+00:41:48,650 --> 00:41:52,510
+لو واحدة فتشت على الكمبيوتر و بتفتش ايش زاوية مركب
+
+468
+00:41:52,510 --> 00:41:57,510
+ال R لجت زاوية ال S تبقى لها ساعتين تفتش على مركب
+
+469
+00:41:57,510 --> 00:42:03,410
+ال R قد ايش زاويته اذا لجت ال R ال S عكسها و اذا
+
+470
+00:42:03,410 --> 00:42:09,450
+لجت ال S ال R عكسها لاحظوا لا يختلفوا في القيمة
+
+471
+00:42:09,450 --> 00:42:15,350
+ولكن يختلفوا في الاتجاه جربوا وشوفوا كيف هذه
+
+472
+00:42:15,350 --> 00:42:19,750
+المراكبات بتنكتب هدولا خاصيتين لازم يكونوا معروفين
+
+473
+00:42:19,750 --> 00:42:25,730
+عن المراكب ال configuration يحدد من الأولويات و ال
+
+474
+00:42:25,730 --> 00:42:31,590
+rotation يحدد بال إيش بالتجربة باستعمال جهاز
+
+475
+00:42:31,590 --> 00:42:36,290
+البولاري ميتر وبهيك بننهي اليوم ان شاء الله و
+
+476
+00:42:36,290 --> 00:42:36,730
+بنكمل
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..4e5643e2f5e21775c49780820dec063cd21b9776
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.json
@@ -0,0 +1 @@
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207.67, "end": 208.19, "word": " المجموعة", "probability": 0.90380859375}, {"start": 208.19, "end": 208.35, "word": " اللي", "probability": 0.983154296875}, {"start": 208.35, "end": 208.85, "word": " موجودة", "probability": 0.9930419921875}, {"start": 208.85, "end": 209.23, "word": " هنا", "probability": 0.99072265625}, {"start": 209.23, "end": 210.35, "word": " هي", "probability": 0.88232421875}, {"start": 210.35, "end": 211.07, "word": " للخلف", "probability": 0.9169921875}, {"start": 211.07, "end": 212.09, "word": " بناء", "probability": 0.804931640625}, {"start": 212.09, "end": 212.33, "word": " على", "probability": 0.5185546875}, {"start": 212.33, "end": 212.75, "word": " ذلك", "probability": 0.995361328125}, {"start": 212.75, "end": 212.99, "word": " لو", "probability": 0.83740234375}, {"start": 212.99, "end": 213.49, "word": " أقل", "probability": 0.9889322916666666}, {"start": 213.49, "end": 214.25, "word": " مجموعة", "probability": 0.9728515625}, {"start": 214.25, "end": 215.05, "word": " وجدت", "probability": 0.9122721354166666}, {"start": 215.05, "end": 215.35, "word": " على", "probability": 0.9306640625}, {"start": 215.35, "end": 215.77, "word": " هذا", "probability": 0.97265625}, {"start": 215.77, "end": 216.45, "word": " المحور", "probability": 0.9912109375}], "temperature": 1.0}, {"id": 9, "seek": 24444, "start": 217.16, "end": 244.44, "text": "فهي للخلف بتحرك في التلت مجموعات التانين الأعلى فالأقل فالأقل وبكتب ال configuration مباشرة الآن لو أقل مجموعة وجدت على الجنبين فهي للأمام يعني نتيجتها هتطلع معكوسة وبناء على ذلك هتحرك في التلت مجموعات التانين و أكتب عكس اللي بيطلع معاه عشان أصحح أن هذه المجموعة أساسا مرسومة للأمام", "tokens": [5172, 3224, 1829, 24976, 9778, 46538, 39894, 5016, 31747, 8978, 16712, 1211, 2655, 3714, 7435, 2304, 45367, 9307, 16712, 7649, 9957, 16247, 3615, 23942, 6156, 6027, 10721, 4587, 1211, 6156, 6027, 10721, 4587, 1211, 46599, 4117, 2655, 3555, 2423, 11694, 3714, 3555, 33599, 25720, 6024, 48506, 45164, 5551, 4587, 1211, 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الآن", "probability": 0.56365966796875}, {"start": 225.34, "end": 225.72, "word": " لو", "probability": 0.818359375}, {"start": 225.72, "end": 226.08, "word": " أقل", "probability": 0.9705403645833334}, {"start": 226.08, "end": 226.6, "word": " مجموعة", "probability": 0.93408203125}, {"start": 226.6, "end": 227.16, "word": " وجدت", "probability": 0.8968098958333334}, {"start": 227.16, "end": 227.3, "word": " على", "probability": 0.7744140625}, {"start": 227.3, "end": 227.98, "word": " الجنبين", "probability": 0.82208251953125}, {"start": 227.98, "end": 228.5, "word": " فهي", "probability": 0.9798177083333334}, {"start": 228.5, "end": 229.2, "word": " للأمام", "probability": 0.926513671875}, {"start": 229.2, "end": 230.14, "word": " يعني", "probability": 0.913330078125}, {"start": 230.14, "end": 230.76, "word": " نتيجتها", "probability": 0.94560546875}, {"start": 230.76, "end": 231.4, "word": " هتطلع", "probability": 0.95244140625}, {"start": 231.4, "end": 232.66, "word": " معكوسة", 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0.94091796875}, {"start": 239.12, "end": 239.62, "word": " بيطلع", "probability": 0.98046875}, {"start": 239.62, "end": 240.0, "word": " معاه", "probability": 0.77880859375}, {"start": 240.0, "end": 240.58, "word": " عشان", "probability": 0.9816080729166666}, {"start": 240.58, "end": 241.28, "word": " أصحح", "probability": 0.899658203125}, {"start": 241.28, "end": 241.5, "word": " أن", "probability": 0.4423828125}, {"start": 241.5, "end": 241.8, "word": " هذه", "probability": 0.82763671875}, {"start": 241.8, "end": 242.42, "word": " المجموعة", "probability": 0.92392578125}, {"start": 242.42, "end": 243.12, "word": " أساسا", "probability": 0.9443359375}, {"start": 243.12, "end": 243.94, "word": " مرسومة", "probability": 0.9408203125}, {"start": 243.94, "end": 244.44, "word": " للأمام", "probability": 0.956298828125}], "temperature": 1.0}, {"id": 10, "seek": 25967, "start": 244.95, "end": 259.67, "text": "لو افترضنا نعمل مثال ان أكد فيه هذه الفكرة خلّينا نبدأ مثلا بمجموعة اقل مجموعة تكون هنا يعني لو قولنا HPRCH3 مثلا floor okay", "tokens": [1211, 2407, 1975, 5172, 2655, 43042, 8315, 8717, 25957, 1211, 50113, 6027, 16472, 5551, 4117, 3215, 8978, 3224, 29538, 27188, 4117, 25720, 16490, 1211, 11703, 9957, 995, 8717, 44510, 10721, 50113, 15040, 4724, 2304, 7435, 2304, 2407, 27884, 1975, 4587, 1211, 3714, 7435, 2304, 2407, 27884, 6055, 30544, 34105, 37495, 22653, 45164, 12174, 12610, 8315, 389, 15958, 5462, 18, 50113, 15040, 4123, 1392], "avg_logprob": -0.2365722726099193, "compression_ratio": 1.3548387096774193, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 244.95, "end": 245.45, "word": "لو", "probability": 0.7061767578125}, {"start": 245.45, "end": 246.25, "word": " افترضنا", "probability": 0.91923828125}, {"start": 246.25, "end": 246.85, "word": " نعمل", "probability": 0.873046875}, {"start": 246.85, "end": 247.47, "word": " مثال", "probability": 0.982177734375}, {"start": 247.47, "end": 247.71, "word": " ان", "probability": 0.2152099609375}, {"start": 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الذرات", "probability": 0.8728841145833334}, {"start": 275.2, "end": 275.32, "word": " و", "probability": 0.5986328125}, {"start": 275.32, "end": 275.68, "word": " أطول", "probability": 0.9119466145833334}, {"start": 275.68, "end": 276.52, "word": " سلسلة", "probability": 0.971923828125}, {"start": 276.52, "end": 276.76, "word": " و", "probability": 0.97265625}, {"start": 276.76, "end": 278.44, "word": " مواقع", "probability": 0.82037353515625}, {"start": 278.44, "end": 279.16, "word": " الذرات", "probability": 0.9669596354166666}, {"start": 279.16, "end": 279.58, "word": " هذا", "probability": 0.87109375}, {"start": 279.58, "end": 279.98, "word": " انكون", "probability": 0.462890625}, {"start": 279.98, "end": 280.14, "word": " من", "probability": 0.98974609375}, {"start": 280.14, "end": 280.4, "word": " كام", "probability": 0.893310546875}, {"start": 280.4, "end": 281.14, "word": " carbon؟", "probability": 0.65087890625}, {"start": 281.14, "end": 282.44, "word": " واحد", 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هذول المركبين كايرال هذول المركبين لو كان عندكم carbon تنتين تلاتة أربعة وهي carbon تنتين تلاتة أربعة لو حطيت هنا chlorine", "tokens": [2304, 4117, 2655, 37746, 43242, 24793, 497, 4032, 7435, 1863, 3555, 11296, 8717, 5172, 2655, 43042, 1804, 2217, 3714, 43020, 7251, 30544, 497, 3175, 2217, 6024, 48506, 8608, 2407, 25528, 1975, 8315, 1975, 3615, 9566, 1829, 24793, 14578, 1975, 3215, 9778, 1211, 14407, 15844, 2423, 24793, 21292, 35473, 2288, 4032, 1975, 4117, 2655, 3555, 14407, 24525, 2304, 3714, 31747, 3555, 9957, 8032, 8848, 12610, 9673, 31747, 3555, 9957, 9122, 995, 13546, 6027, 8032, 8848, 12610, 9673, 31747, 3555, 9957, 45164, 25961, 43242, 24793, 5954, 6055, 29399, 9957, 6055, 1211, 9307, 3660, 5551, 25513, 27884, 37037, 1829, 5954, 6055, 29399, 9957, 6055, 1211, 9307, 3660, 5551, 25513, 27884, 45164, 11331, 9566, 36081, 34105, 39888], "avg_logprob": -0.19380482233930052, "compression_ratio": 1.771551724137931, "no_speech_prob": 0.0, "words": [{"start": 2369.91, "end": 2370.45, 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2548.49, "end": 2550.07, "word": " بالتجربة", "probability": 0.901953125}, {"start": 2550.07, "end": 2550.89, "word": " باستعمال", "probability": 0.96494140625}, {"start": 2550.89, "end": 2551.59, "word": " جهاز", "probability": 0.9752604166666666}, {"start": 2551.59, "end": 2552.85, "word": " البولاري", "probability": 0.7064208984375}, {"start": 2552.85, "end": 2553.27, "word": " ميتر", "probability": 0.7228190104166666}, {"start": 2553.27, "end": 2554.67, "word": " وبهيك", "probability": 0.8487548828125}, {"start": 2554.67, "end": 2555.43, "word": " بننهي", "probability": 0.912353515625}, {"start": 2555.43, "end": 2555.79, "word": " اليوم", "probability": 0.962890625}, {"start": 2555.79, "end": 2555.93, "word": " ان", "probability": 0.224365234375}, {"start": 2555.93, "end": 2556.13, "word": " شاء", "probability": 0.966064453125}, {"start": 2556.13, "end": 2556.19, "word": " الله", "probability": 0.955078125}, {"start": 2556.19, "end": 2556.29, "word": " و", "probability": 0.74853515625}, {"start": 2556.29, "end": 2556.73, "word": " بنكمل", "probability": 0.8419596354166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2557.562, "duration_after_vad": 2469.1349999999925}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..50788cd22a88b80dd510c57a69d3fc6fc2612d61
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.srt
@@ -0,0 +1,1912 @@
+1
+00:00:21,400 --> 00:00:26,380
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry
+
+2
+00:00:26,380 --> 00:00:31,980
+اللى بدأنا فيه المرة الماضية المرة الماضية اتكلمنا
+
+3
+00:00:31,980 --> 00:00:36,300
+طبعا على تصنيف ال isomers ايش معنى structural
+
+4
+00:00:36,300 --> 00:00:39,980
+isomers و stereo isomers وقولنا ان ال stereo
+
+5
+00:00:39,980 --> 00:00:44,850
+isomers نوعينانانشو مارس ودياستيريو مارس
+
+6
+00:00:44,850 --> 00:00:48,070
+الدياستيريو مارس كنا اتكلمنا عنهم سابق و نعطينا
+
+7
+00:00:48,070 --> 00:00:52,510
+عنهم امثلة من ال CC trans compounds و ما إلى ذلك
+
+8
+00:00:52,510 --> 00:00:57,130
+عرفنا بالظبط ايش بنعنى بانانشو مارس طبعا جزء من
+
+9
+00:00:57,130 --> 00:01:02,290
+الموضوع ان نكون فاهمين علاقة المركبات بعضها بعض من
+
+10
+00:01:02,290 --> 00:01:08,040
+خلال المرأة فإذا كانت المركبات زي ما حكيناnon
+
+11
+00:01:08,040 --> 00:01:11,540
+-sober imposible mirror image stereo isomers هذوله
+
+12
+00:01:11,540 --> 00:01:16,280
+سمناهم إيش Inertiomers و بتكلمنا عن إنه هذه
+
+13
+00:01:16,280 --> 00:01:20,020
+الإمكانية ممكن تكون موجودة لما يكون عند كايرال
+
+14
+00:01:20,020 --> 00:01:26,080
+سنتر معنى كايرال سنتر هي ذرة كربون تحمل أربع
+
+15
+00:01:26,080 --> 00:01:30,780
+مجموعات مختلفة هي مثلا عندنا الآن أربع مجموعات
+
+16
+00:01:30,780 --> 00:01:34,440
+مختلفة يعني إذا بتلاحظوا هذا الكربون عادة الكايرال
+
+17
+00:01:34,440 --> 00:01:40,410
+سنتر بنحطلها نجمةهذا الكربون بتحمل مجموعة و بتحمل
+
+18
+00:01:40,410 --> 00:01:44,090
+كربون متصلة بالدوبل بوند و بتحمل CH2 و بتحمل H
+
+19
+00:01:44,090 --> 00:01:49,850
+هذول أربع مجموعات مختلفة مع ذلك لو اتطلعنا في كل
+
+20
+00:01:49,850 --> 00:01:54,690
+الجزيء مافيش غير هذا الكربون هذا المثال أيضا لو
+
+21
+00:01:54,690 --> 00:01:58,610
+بتطلع الكربون اللي هنا Cl, Methyl, CH2, CH2,
+
+22
+00:01:58,650 --> 00:02:02,950
+Potassium و H أربع مجموعات مختلفة فهذا في منه
+
+23
+00:02:02,950 --> 00:02:09,370
+مركبين ROSهذا في منه مركبين R وS اي مركب مافيش فيه
+
+24
+00:02:09,370 --> 00:02:13,050
+اربع مجموعات مختلفة حوالين carbon هيكون منه ايش
+
+25
+00:02:13,050 --> 00:02:20,370
+مركب مركب واحد فقط الان كان ضروري جدا نقدر نميز
+
+26
+00:02:20,370 --> 00:02:25,490
+المركبين وقلنا ان التمييز بينهم من خلال ال
+
+27
+00:02:25,490 --> 00:02:32,090
+configuration ال configuration احدد 1R 1S الطريقة
+
+28
+00:02:32,610 --> 00:02:36,170
+انه انا امسك المركب .. انه انا امسك المركب اخلى
+
+29
+00:02:36,170 --> 00:02:41,270
+المجموعة الأقل للخلف و اتحرك حسب الأولويات اللى
+
+30
+00:02:41,270 --> 00:02:45,410
+اتعلمناها اللى كان انجلد برولوج رولز إذا بتحرك مع
+
+31
+00:02:45,410 --> 00:02:50,390
+عقاري بالساعة المركب بعطي وصف R وإذا بتحرك عكس
+
+32
+00:02:50,390 --> 00:02:55,000
+عقاري بالساعة بعطي المركب الوصفS هذا الكلام إذا
+
+33
+00:02:55,000 --> 00:02:59,880
+فيه معنى model إذا مافيش معنى model إذا مافيش معنى
+
+34
+00:02:59,880 --> 00:03:05,080
+model بدنا نتذكر إنه إحنا بنرسم المركب بهذا الشكل
+
+35
+00:03:05,080 --> 00:03:10,240
+واتفقنا إنه مش planner المركب يعني لما نرسمه زي
+
+36
+00:03:10,240 --> 00:03:15,040
+هيك هو حقيقة شكل فراغي بهذا الشكل في مجمعتين
+
+37
+00:03:15,040 --> 00:03:21,470
+للأمام وفي مجمعتين للخلففخلّينا نضل مركزين كتير
+
+38
+00:03:21,470 --> 00:03:25,410
+على هذه النقطة أن هذه المجموعة اللي موجودة هنا أو
+
+39
+00:03:25,410 --> 00:03:31,070
+هنا هي للأمام و المجموعة اللي موجودة هنا هي للخلف
+
+40
+00:03:31,070 --> 00:03:37,580
+بناء على ذلك لو أقل مجموعة وجدت على هذا المحورفهي
+
+41
+00:03:37,580 --> 00:03:42,180
+للخلف بتحرك في التلت مجموعات التانين الأعلى فالأقل
+
+42
+00:03:42,180 --> 00:03:46,080
+فالأقل وبكتب ال configuration مباشرة الآن لو أقل
+
+43
+00:03:46,080 --> 00:03:50,760
+مجموعة وجدت على الجنبين فهي للأمام يعني نتيجتها
+
+44
+00:03:50,760 --> 00:03:56,200
+هتطلع معكوسة وبناء على ذلك هتحرك في التلت مجموعات
+
+45
+00:03:56,200 --> 00:04:01,500
+التانين و أكتب عكس اللي بيطلع معاه عشان أصحح أن
+
+46
+00:04:01,500 --> 00:04:06,850
+هذه المجموعة أساسا مرسومة للأماملو افترضنا نعمل
+
+47
+00:04:06,850 --> 00:04:10,810
+مثال ان أكد فيه هذه الفكرة خلّينا نبدأ مثلا
+
+48
+00:04:10,810 --> 00:04:16,790
+بمجموعة اقل مجموعة تكون هنا يعني لو قولنا HPRCH3
+
+49
+00:04:16,790 --> 00:04:19,670
+مثلا floor okay
+
+50
+00:04:21,380 --> 00:04:25,520
+لحظوا هذا المركب لو بهذا الشكل إجيانا في الامتحان
+
+51
+00:04:25,520 --> 00:04:29,640
+name the following compound سمى المركب هذا طبعا
+
+52
+00:04:29,640 --> 00:04:34,320
+أول شي بدنا نسميه الكيميا العادية اللي هي تحديد
+
+53
+00:04:34,320 --> 00:04:40,140
+الذرات و أطول سلسلة و مواقع الذرات هذا انكون من
+
+54
+00:04:40,140 --> 00:04:46,780
+كام carbon؟ واحد اتنين على نمرة واحد عندى بروم و
+
+55
+00:04:46,780 --> 00:04:57,470
+floor إذا هذا كمركب وانبرومهوان فلورو اثان
+
+56
+00:04:57,470 --> 00:05:05,390
+واضح هاي carbon one وcarbon two وان برومو وان
+
+57
+00:05:05,390 --> 00:05:11,470
+فلورو اثان الآن بعد هيك بتطلع هل هذا ال carbon في
+
+58
+00:05:11,470 --> 00:05:17,350
+chiral center ولا لأ بمعنى ان في carbon تحمل اربع
+
+59
+00:05:17,350 --> 00:05:22,810
+مجموعات مختلفةمباشرة بنحط عليها نجمة إذا هذا
+
+60
+00:05:22,810 --> 00:05:28,690
+المركب هيكون واحد من اتنين يا R يا S باجي بتطلع أن
+
+61
+00:05:28,690 --> 00:05:33,290
+هي أقل مجموعة متصلة مباشرة بالcarbon ال H ال PR ال
+
+62
+00:05:33,290 --> 00:05:38,650
+floor ال CH3 واضح إنها ال H أقل مجموعة already
+
+63
+00:05:38,650 --> 00:05:43,650
+موجودة للخلف برتب المجموعات التلاتة التانين الأعلى
+
+64
+00:05:43,650 --> 00:05:50,460
+فالأقل فالأقلطبعا الأعلى لبروم بعدها لفلور بعدها
+
+65
+00:05:50,460 --> 00:05:56,960
+الكاربون إذا هاي واحد هاي تانين هاي تلاتة و بتحرك
+
+66
+00:05:56,960 --> 00:06:04,200
+واحد اتنين تلاتة كيف أنا ماشي؟ عكس عقارب الساعة
+
+67
+00:06:04,200 --> 00:06:10,880
+إذا هذا المركب S هيك بيصير الاسم تبعه كامل هذا
+
+68
+00:06:10,880 --> 00:06:18,070
+المركب S one bromo one floro E2واضح الفكرة؟ خلينا
+
+69
+00:06:18,070 --> 00:06:24,330
+ناخد مثال او مثلين ان اكد على هذه النقطة بيهمني
+
+70
+00:06:24,330 --> 00:06:29,770
+يصير انكم اتقان لهذه النقطة تحديدا لو افترضنا اننا
+
+71
+00:06:29,770 --> 00:06:32,410
+رسمنا مركب بهذا الشكل
+
+72
+00:06:48,630 --> 00:07:00,430
+وإجانة هذا المركب وسم المركب تسمية كاملة لحظوا
+
+73
+00:07:00,430 --> 00:07:04,830
+الناس المستعجلة قاعدة بتعطي إجابات غلط الكيميا
+
+74
+00:07:04,830 --> 00:07:09,870
+علم، systematic، بدنا نمشي فيه خطوة خطوة بدنا نقول
+
+75
+00:07:09,870 --> 00:07:16,690
+في الأول ما نوع المركبالكيل في double point إذا
+
+76
+00:07:16,690 --> 00:07:20,690
+يجب البحث عن أطول سلسلة تحتوي على ال double point
+
+77
+00:07:20,690 --> 00:07:23,770
+واحد،
+
+78
+00:07:23,770 --> 00:07:29,450
+اتنين، تلاتة، أربعة، خمسة إذا المركب اللي عندي
+
+79
+00:07:29,450 --> 00:07:35,870
+حقيقة بنتين هي أطول سلسلة أي بنتين؟
+
+80
+00:07:38,710 --> 00:07:42,690
+one بنتين يعني ال double bond اللي فيه على موقع
+
+81
+00:07:42,690 --> 00:07:50,690
+واحد اذا هذا one بنتين من وين الترقيم بالتأكيد
+
+82
+00:07:50,690 --> 00:07:56,650
+واحد اتنين تلاتة اربعة خمسة الان هذا عليه
+
+83
+00:07:56,650 --> 00:08:04,560
+substituentsعلى موقع تلاتة اكلور وعلى موقع تلاتة
+
+84
+00:08:04,560 --> 00:08:09,480
+مثل اذا ايش اسمه كمركب بيصير تلاتة اكلور تلاتة مثل
+
+85
+00:08:09,480 --> 00:08:14,860
+تلاتة اكلور تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+86
+00:08:14,860 --> 00:08:18,840
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+87
+00:08:18,840 --> 00:08:21,280
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+88
+00:08:21,280 --> 00:08:22,140
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+89
+00:08:22,140 --> 00:08:23,100
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+90
+00:08:23,100 --> 00:08:28,440
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تل
+
+91
+00:08:29,570 --> 00:08:35,150
+مافيش غيرها نهائيًا، مافيش غيرها نهائيًا، الآن بدي
+
+92
+00:08:35,150 --> 00:08:38,410
+أطلع على المجموعات الأربعة اللي على هذا ال carbon
+
+93
+00:08:38,410 --> 00:08:44,430
+أنهي أقل مجموعة، عندي halogenو carbon و carbon و
+
+94
+00:08:44,430 --> 00:08:49,810
+carbon أكيد ال halogen هي المجموعة الأعلى نمرة
+
+95
+00:08:49,810 --> 00:08:54,650
+واحد خلصت من ال halogen الآن ال carbons carbon
+
+96
+00:08:54,650 --> 00:08:58,210
+متصلة ب اتنين carbons ولا carbon متصلة ب carbon
+
+97
+00:08:58,210 --> 00:09:04,710
+ولا carbon متصلة ب etches المتصلة بال carbon مرتين
+
+98
+00:09:04,710 --> 00:09:13,160
+هي نمرة اتنين هذه اللي بيبين ك ethylنمرة 3 هذه
+
+99
+00:09:13,160 --> 00:09:22,700
+نمرة 2 هذه نمرة 4 الألوان أصغر مجموعة ال CH3 في
+
+100
+00:09:22,700 --> 00:09:28,500
+هذه الحالة أصغر مجموعة ال CH3 لاحظوا اكتبوا جنبه
+
+101
+00:09:28,500 --> 00:09:33,340
+عشان ما تغلطوش موجودة للأمام إذا اللي بيطلع عندكم
+
+102
+00:09:33,340 --> 00:09:36,500
+بس تكتبوا عكسه عشان تطلعوا ال configuration الصح
+
+103
+00:09:37,530 --> 00:09:45,610
+واضح؟ فلما انا بمشي واحد اتنين تلاتة R اذا S هذا
+
+104
+00:09:45,610 --> 00:09:59,190
+المركب زيه اللي هيكون اسمه الكلام
+
+105
+00:09:59,190 --> 00:10:07,570
+جميل وكمان مثال بضر ولا ما بضر؟كمان مثال مابضرش
+
+106
+00:10:07,570 --> 00:10:16,830
+خلنا ناخد كمان مثال أي سؤال على السريع ايه
+
+107
+00:10:16,830 --> 00:10:24,390
+السؤال؟ السبق
+
+108
+00:10:24,390 --> 00:10:29,130
+اتفقنا العلم كامل و هذا الكلام مش موضوع ان نسأل
+
+109
+00:10:29,130 --> 00:10:34,710
+عنه ايش اعمل في الامتحان و كيف اسلحالجواب زي هيك
+
+110
+00:10:34,710 --> 00:10:39,990
+كامل، الآن ما عدا هيك العشرة بتصير تمانية و سبعة و
+
+111
+00:10:39,990 --> 00:10:45,690
+ستة، هذا بيبطل موضوعكم أستاذ ليش رقمت هناك اتنين و
+
+112
+00:10:45,690 --> 00:10:50,920
+هالتلاتة؟ الأجين و الأتلاتة عايشون؟هذا الكلام سبق
+
+113
+00:10:50,920 --> 00:10:55,620
+أننا أخدناه لما كنا بنحكي عن كان English Dibrelog
+
+114
+00:10:55,620 --> 00:11:01,360
+Rules والأصل أن الطالب يكون متذكره من هذه المنطقة،
+
+115
+00:11:01,360 --> 00:11:06,720
+يكون مراجع ومتذكر كويس، الآن هذه carbon تتصل
+
+116
+00:11:06,720 --> 00:11:14,560
+بماذا؟ بH و بcarbonو ب carbon هذه ال carbon تتصل
+
+117
+00:11:14,560 --> 00:11:20,040
+بماذا؟ ب H و ب carbon لاحظوا الطالب اللي مابيرجعش
+
+118
+00:11:20,040 --> 00:11:27,730
+كويس بيجي يسأل في نقطةقديمة الكيميا مبنية على بعض
+
+119
+00:11:27,730 --> 00:11:32,910
+يعني في هذا المثال جيبنا طول السلسلة من chapter ال
+
+120
+00:11:32,910 --> 00:11:35,490
+alkanes جيبنا ال double bond و مكانها من chapter
+
+121
+00:11:35,490 --> 00:11:38,830
+ال alkanes جيبنا ترتيب الأولويات من chapter ال
+
+122
+00:11:38,830 --> 00:11:42,970
+alkanes جيبنا ال R و ال S من chapter خمسةالان
+
+123
+00:11:42,970 --> 00:11:47,870
+مابنقدرش احنا ننسى الكلام السابق اللى اتعلمناه
+
+124
+00:11:47,870 --> 00:11:52,490
+واضح هذه النقطة خلينا نعطى مثال تانى لو مثلا اجينا
+
+125
+00:11:52,490 --> 00:12:02,610
+كتبنا carbon C triple bond C CH3 وحطينا كمان هنا
+
+126
+00:12:02,610 --> 00:12:12,350
+CH3 وحطينا كمان هنا على سبيل المثالخليها دي double
+
+127
+00:12:12,350 --> 00:12:18,050
+bond زي
+
+128
+00:12:18,050 --> 00:12:21,050
+هيك و حطينا هنا chlorine
+
+129
+00:12:26,900 --> 00:12:31,620
+لاحظوا هذا مركّب بتكون تعرفوا في الأول تتأملوا
+
+130
+00:12:31,620 --> 00:12:36,920
+بشكل عام على أي تسمية بتكون تسموها البعض هيفكر أنه
+
+131
+00:12:36,920 --> 00:12:41,460
+فيه بنزين لكن صعب أن نلاقي اسم لهذه المجموعة لذلك
+
+132
+00:12:41,460 --> 00:12:47,240
+ما بنسميه كمشتقة بنزين بنبحث عنه كمركب متسلسل
+
+133
+00:12:47,240 --> 00:12:52,880
+كمركب متسلسل هذاإتنين بنتين .. إتنين بنتين ..
+
+134
+00:12:52,880 --> 00:13:01,300
+إتنين بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين
+
+135
+00:13:01,300 --> 00:13:01,720
+بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين بنتين
+
+136
+00:13:01,720 --> 00:13:02,400
+.. إتنين بنتين .. إتنين بنتين .. إتنين بنتين ..
+
+137
+00:13:02,400 --> 00:13:02,520
+إتنين بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين
+
+138
+00:13:02,520 --> 00:13:02,960
+بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين بنتين
+
+139
+00:13:02,960 --> 00:13:03,100
+.. إتنين بنتين .. إتنين بنتين .. إتنين بنتين ..
+
+140
+00:13:03,100 --> 00:13:05,820
+إتنين بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين
+
+141
+00:13:05,820 --> 00:13:11,200
+بنتين .. إتنين بنتين .. إتنين بنتين ..يكون مبين في
+
+142
+00:13:11,200 --> 00:13:15,860
+الـ S والـ Trans والـ Z والـ E مثلا بهذا الشكل هاي
+
+143
+00:13:15,860 --> 00:13:21,360
+carbon ممكن تلاقوه بهذا الشكل تجمع كل الكلام اللي
+
+144
+00:13:21,360 --> 00:13:26,540
+انتوا اتعلمتهوا
+
+145
+00:13:26,540 --> 00:13:33,020
+الان
+
+146
+00:13:33,020 --> 00:13:40,390
+لاحظوا هذا المركب ايش موجود فيه ال keenوالألكين في
+
+147
+00:13:40,390 --> 00:13:44,110
+مجموعتين مختلفات و مجموعتين مختلفات إذا حتبدوا
+
+148
+00:13:44,110 --> 00:13:49,550
+تفكروا بالـ Cis و Trans أو Z و E في chiral center
+
+149
+00:13:49,550 --> 00:13:56,250
+كمان يعني في شغلتين ال stereo chemistry واضح؟ مش
+
+150
+00:13:56,250 --> 00:14:01,580
+ال cis و ال trans بيعطيني ال diastereomers ال Zو
+
+151
+00:14:01,580 --> 00:14:04,280
+ال E أو ال cis و ال trans و ال chiral center
+
+152
+00:14:04,280 --> 00:14:09,460
+بيعطيني R و S لان هذا في bubble bond و في ال
+
+153
+00:14:09,460 --> 00:14:13,500
+chiral center موجودة هنا قبل ما نتوقف في ال stereo
+
+154
+00:14:13,500 --> 00:14:18,220
+chemistry خلينا نشوف السلسلة المركبة كسلسلة ايش
+
+155
+00:14:18,220 --> 00:14:24,670
+بده اسمي انابدي أطول سلسلة مزال بسمع كلمات بنتين
+
+156
+00:14:24,670 --> 00:14:31,450
+واحد اتنين تلاتة اربعة خمسة هي أطول سلسلة و العد
+
+157
+00:14:31,450 --> 00:14:37,690
+من هنا عشان نخليها ايش two بنتين اذا هنا كلمة two
+
+158
+00:14:37,690 --> 00:14:45,810
+بنتين سليمة الان هذه أطول سلسلة ايش بتحمل بإمكانك
+
+159
+00:14:45,810 --> 00:14:54,360
+تطلع نهاية كسلسلةهذه كلها السلسلة على موقع اربعة
+
+160
+00:14:54,360 --> 00:15:01,540
+عندى فيها four chloro four
+
+161
+00:15:01,540 --> 00:15:09,440
+phenyl four chloro four phenyl two pentene الان
+
+162
+00:15:09,440 --> 00:15:15,990
+خلصت المواقع دل عندى جزءالاستيريو كيميسترا جزء
+
+163
+00:15:15,990 --> 00:15:21,990
+الاستيريو كيميسترا كيف شكل المجموعات هنا هنجي نقول
+
+164
+00:15:21,990 --> 00:15:29,530
+اكش ولا مثل؟ مين اعلى؟ مثل واضحة اذا هذه المجموعة
+
+165
+00:15:29,530 --> 00:15:33,330
+خلينا نقول الاعلى الكاربون هذا اكش ولا كاربون؟
+
+166
+00:15:33,330 --> 00:15:37,530
+كاربون هذا الاعلى الان الاعلى على جهة واحدة ولا
+
+167
+00:15:37,530 --> 00:15:43,640
+على جهتين متعاكستين؟على جهتين متعاكستين هاي هذه
+
+168
+00:15:43,640 --> 00:15:50,000
+على جهة وهذه على الجهة التانية إذا المركب هذا E او
+
+169
+00:15:50,000 --> 00:15:55,480
+Trans احنا قولنا إذا المركب فيه شوية تعمل E الآن
+
+170
+00:15:55,480 --> 00:16:02,220
+ضال عندى حوالين ال chiral center هالمركب هذا R ولا
+
+171
+00:16:02,220 --> 00:16:09,240
+Sواضح؟ بدي أجي أطلع على هذه الـ carbon و أقول وين
+
+172
+00:16:09,240 --> 00:16:13,960
+أقل مجموعة و وين أعلى مجموعة الان الهالوجين كاربون
+
+173
+00:16:13,960 --> 00:16:22,040
+كاربون كاربون إذا نمرة واحد الهالوجين بعد هيك
+
+174
+00:16:22,040 --> 00:16:28,160
+خلّينا نتذكر إنه في البنزينة الكاربون ما بنشتغل
+
+175
+00:16:28,160 --> 00:16:32,060
+على مجموع إطلاقا للناس اللي بدوا يقولوا C6H6 بدوا
+
+176
+00:16:32,060 --> 00:16:36,930
+يمشوا بالاتجاه الغلطلأ لأ أنا بشوفها متصلة بإيش
+
+177
+00:16:36,930 --> 00:16:41,970
+الآن هذه ال carbon واحدة تقول يا متصلة بكم ذرة
+
+178
+00:16:41,970 --> 00:16:46,830
+متصلة ب carbon و ب carbon تانية من خلال ال double
+
+179
+00:16:46,830 --> 00:16:51,250
+bond و ب carbon تالتة هي ال carbon هذه متصلة ب
+
+180
+00:16:51,250 --> 00:16:55,550
+carbon كمان carbon ال double bond هيك منفسرة كمان
+
+181
+00:16:55,550 --> 00:16:59,670
+carbon متصلة تلت مرات بال carbon طب هذه ال carbon
+
+182
+00:16:59,670 --> 00:17:06,550
+ب carbonوب carbon وب H إذا مين أعلى لمتصلة بتلاتة
+
+183
+00:17:06,550 --> 00:17:10,950
+carbon ولا لمتصلة بتنين carbon اه هذه متصلة carbon
+
+184
+00:17:10,950 --> 00:17:16,030
+اتنين تلاتة انا واحد اتنين هذه متصلة بتلاتة H إذا
+
+185
+00:17:16,030 --> 00:17:21,590
+هذه أقل المجموعات مين أعلى مجموعة هتكون في التلاتة
+
+186
+00:17:21,590 --> 00:17:29,610
+اللي ضاله البنزينة هتاخد نمرة اتنين بعدها هذه
+
+187
+00:17:29,610 --> 00:17:38,780
+المجموعة كلهاهتاخد نمرة تلاتة بعدها هذه المجموعة
+
+188
+00:17:38,780 --> 00:17:47,680
+نمرة أربعة الآن أي مجموعة الأصغر موجودة للخالق إذا
+
+189
+00:17:47,680 --> 00:17:52,300
+بدي أمشي واحد اتنين تلاتة أشوف أنا مع أقارب الساعة
+
+190
+00:17:52,300 --> 00:17:58,240
+ولا ضد أقارب الساعة واحد اتنين تلاتة هاي واحد كيف
+
+191
+00:17:58,240 --> 00:18:00,960
+بمشي على اتنين اتنين
+
+192
+00:18:02,730 --> 00:18:11,410
+تلاتة واحد اثنين تلاتة اذا المركب اللي عنده S واضح
+
+193
+00:18:11,410 --> 00:18:14,610
+S
+
+194
+00:18:14,610 --> 00:18:25,070
+و E جيبت كل ال stereo chemistry تبعته ال
+
+195
+00:18:25,070 --> 00:18:31,250
+A درس في chapter تلاتة بترجعي في chapter تلاتةلأنه
+
+196
+00:18:31,250 --> 00:18:36,190
+برضه الناس بتفرج علينا على ال video لازم يكون واضح
+
+197
+00:18:36,190 --> 00:18:41,690
+للناس حتى اللي بيسمعوني بالخارج أنه الشيء السابق
+
+198
+00:18:41,690 --> 00:18:47,730
+ما كان فهمه أن يراجع سابقا و لذلك نعلم احنا في
+
+199
+00:18:47,730 --> 00:18:53,020
+التربية و نتعلم أن نعلم الطلابأي معلومة الطالب
+
+200
+00:18:53,020 --> 00:18:57,700
+مابفهمهاش وانا بشرحها، إذا عنده مشكلة في المعلومة
+
+201
+00:18:57,700 --> 00:19:02,780
+السابقة، الآن المعلومة السابقة طبيعة الجامعة أن
+
+202
+00:19:02,780 --> 00:19:07,420
+المدرس لا يعيد المعلومة السابقةفي دارس موجود الآن
+
+203
+00:19:07,420 --> 00:19:13,120
+يعني إذا كان المدرس درسكم معنى الديمقراطية سابقا و
+
+204
+00:19:13,120 --> 00:19:17,500
+بدأ الآن يحكي عن علاقة الديمقراطية بالرأسمالية مش
+
+205
+00:19:17,500 --> 00:19:20,600
+معقول أنه يروح يفتح محاضرة جديدة بعنوان
+
+206
+00:19:20,600 --> 00:19:24,380
+الديمقراطية و هو بده يشرح علاقة الديمقراطية
+
+207
+00:19:24,380 --> 00:19:30,630
+بالرأسماليةفارجو أن ننتبه لهذا الأمر جيدا، بظل
+
+208
+00:19:30,630 --> 00:19:34,650
+دائما عند الطالب أسئلة بيرجع لوحده في البيت
+
+209
+00:19:34,650 --> 00:19:39,370
+بيجاوبها أو بيمر على أستاذ بخارج وقت الحصة، ليس من
+
+210
+00:19:39,370 --> 00:19:44,990
+الضروري أن يفهم كل شيء في هذه اللحظة، بالذات إذا
+
+211
+00:19:44,990 --> 00:19:51,100
+الأمر تعلق بمجموعة .. بمعلومة سابقة هو نسيهاهيك
+
+212
+00:19:51,100 --> 00:19:56,020
+الجامعة وهيك الدنيا وفي كل الأحوال انتوا بتكونوا
+
+213
+00:19:56,020 --> 00:20:00,420
+تتعودوا على نظام الجامعة لأنكوا طلاب جدود سنة أولى
+
+214
+00:20:00,420 --> 00:20:07,870
+بس المدرس مش لازم يرجع فيكم لنظام المدرسةأمر طبيعي
+
+215
+00:20:07,870 --> 00:20:11,870
+في الجامعة انه بتسمعوا بتحسوا ان خانتكوا معلومة
+
+216
+00:20:11,870 --> 00:20:17,270
+معلومتين موجود عندكم مراجعة بهدوء لها المعلومة
+
+217
+00:20:17,270 --> 00:20:21,670
+السابقة او في اسوأ الاحتمالات ماحصلش بتروحوا على
+
+218
+00:20:21,670 --> 00:20:25,850
+المكتب عند المدرس تفهم المعلومة السابقة فارجو ان
+
+219
+00:20:25,850 --> 00:20:33,470
+ننتبه لهذا الأمر جيدا الان اتفقنا احنا ان في عندنا
+
+220
+00:20:33,470 --> 00:20:39,650
+مركباتROS يعني لو عندي chiral center كام مركب عندى
+
+221
+00:20:39,650 --> 00:20:45,070
+اتنين هدولة كل عنهم enantiomers الان بتهمنا شغلة
+
+222
+00:20:45,070 --> 00:20:51,910
+ايش العلاقة بين ال enantiomers من ناحية الخواص
+
+223
+00:20:51,910 --> 00:20:56,790
+الفيزيائية و من ناحية الخواص الكيميائية يمكن هذا
+
+224
+00:20:56,790 --> 00:21:02,770
+ال slide موجودة شوية للامام هتلاحظوا بس احنا بدنا
+
+225
+00:21:02,770 --> 00:21:08,160
+نشوف ال enantiomers دولةمن ناحية خواص فيزيائية و
+
+226
+00:21:08,160 --> 00:21:11,740
+من ناحية خواص كيميائية بإيش بيختلفوا و بعد ذلك
+
+227
+00:21:11,740 --> 00:21:15,440
+برضه بدي أشوف ال diastereomers من ناحية خواص
+
+228
+00:21:15,440 --> 00:21:20,980
+فيزيائية و من ناحية خواص كيميائية بإيش بيختلفوا
+
+229
+00:21:20,980 --> 00:21:29,640
+واضح؟ الآن طبعا ع السريع بتكونوا عارفين إيش معنى
+
+230
+00:21:29,640 --> 00:21:35,010
+خواص فيزيائية و إيش معنى خواص كيميائيةاحنا بنقول
+
+231
+00:21:35,010 --> 00:21:40,290
+الخواص الفيزيائية هي الخواص التي يمكن أن نقيسها
+
+232
+00:21:40,290 --> 00:21:45,310
+دون أن نغير في تركيب المادة يعني المادة بتضال زي
+
+233
+00:21:45,310 --> 00:21:51,190
+ما هي على سبيل المثال عندي ماءبدي أقيسله الحجم،
+
+234
+00:21:51,190 --> 00:21:55,170
+قست الحجم بعد ما قسته، الماء ما زال زي ما هو ولا
+
+235
+00:21:55,170 --> 00:22:00,770
+لأ؟ بدي أقيسله الكتلة، قست الكتلة، الماء ما زال زي
+
+236
+00:22:00,770 --> 00:22:05,310
+ما هو ولا لأ؟ بدي أقيسله الكثافة، قسمت الكتلة على
+
+237
+00:22:05,310 --> 00:22:11,190
+الحجم، والماء ما زالة؟موجودا بدا قص معامل الانكسار
+
+238
+00:22:11,190 --> 00:22:17,530
+جبت الماء و حطيته في وعاء و أسقطت عليه الضوء و قصت
+
+239
+00:22:17,530 --> 00:22:21,910
+زاوية الانكسار او معامل الانكسار بعد هيك لو بد
+
+240
+00:22:21,910 --> 00:22:26,310
+الماء الماء ما زال موجودا اذا كل القياسات عملتها
+
+241
+00:22:26,310 --> 00:22:30,850
+من غير ما اغير في تركيب الماء بهذا الشكل تكون
+
+242
+00:22:30,850 --> 00:22:35,790
+الخاصيةفيزيائية إذا ال physical probity is a
+
+243
+00:22:35,790 --> 00:22:39,350
+probity that can be measured without changing the
+
+244
+00:22:39,350 --> 00:22:42,790
+chemical makeup of the substance لكن لو كنت أقول
+
+245
+00:22:42,790 --> 00:22:46,010
+إيش يعني chemical probity ال chemical probity
+
+246
+00:22:46,010 --> 00:22:50,530
+تفاعل والتفاعل يغير المادة أبسط تعريف لل chemical
+
+247
+00:22:50,530 --> 00:22:54,930
+probity هي تفاعل يعني لو مثلا إجيت قولت الماء مع
+
+248
+00:22:54,930 --> 00:22:59,300
+الصوديومبقول والله خلّينا نحط صوديوم على ميّه
+
+249
+00:22:59,300 --> 00:23:03,300
+حطينا صوديوم على كمية ميّه صغيرة بحذر لأنه التفاعل
+
+250
+00:23:03,300 --> 00:23:08,160
+خطير لاحظنا أنه بينطلق غاز هيدروجين وممكن كمان
+
+251
+00:23:08,160 --> 00:23:12,180
+يشتعل مع حرارة التفاعل ويعمل عندنا فرقعة وبتكون
+
+252
+00:23:12,180 --> 00:23:16,000
+هيدروكسيد الصوديوم وما إلى ذلك الآن بعد ما خلصنا
+
+253
+00:23:16,000 --> 00:23:21,940
+هالكلام اجينا قلنالكم لو سمحتوا راجعولنا الميّهأي
+
+254
+00:23:21,940 --> 00:23:26,860
+مية؟ المية اتفعلت المية صارت هيدروكسيد السوديوم
+
+255
+00:23:26,860 --> 00:23:31,080
+إذا أنا لما درست الخاصية الكيميائية فعلت المية ف
+
+256
+00:23:32,350 --> 00:23:37,010
+خلصت الميه، اتغيرت تركيبها، لكن لما جابلي شوية جسد
+
+257
+00:23:37,010 --> 00:23:41,810
+خمس، ست خواص فيزيائية كتلة وحجم ومعامل انكسار وما
+
+258
+00:23:41,810 --> 00:23:46,470
+إلى ذلك، الميه غيرت فيها إشي، إذا نفهمنا إيش الفرق
+
+259
+00:23:46,470 --> 00:23:50,290
+بين الخواص الفيزيائي والكيميائي، الآن لو إجينا
+
+260
+00:23:50,290 --> 00:23:55,240
+بنتكلم على الانانش ومرز و الخواص الفيزيائيبنقول
+
+261
+00:23:55,240 --> 00:23:59,280
+احنا الانانشو مارز they have the same physical
+
+262
+00:23:59,280 --> 00:24:03,020
+properties except for direction of rotation of a
+
+263
+00:24:03,020 --> 00:24:08,200
+plane polarized light يعني هناك عدد كبير من الخواص
+
+264
+00:24:08,200 --> 00:24:12,140
+الفيزيائية، قولوا خمسين خصية ما إلى ذلك مايفرجش
+
+265
+00:24:12,140 --> 00:24:16,060
+عندنا ال two enansho marz اللي هما هيكونوا واحد
+
+266
+00:24:16,060 --> 00:24:23,640
+منهم R والتاني S يشتركوا في جميع الخواص الفيزيائية
+
+267
+00:24:23,890 --> 00:24:31,990
+مثل الكثافة مثل نقطة الغليان مثل نقطة الانصحار مثل
+
+268
+00:24:31,990 --> 00:24:37,850
+معامل الانكسار كلهم لو اتيت against لهم يشتركوافي
+
+269
+00:24:37,850 --> 00:24:44,710
+جميع الخواص الفيزيائية ما عدا خاصية واحدة فقط هذه
+
+270
+00:24:44,710 --> 00:24:49,450
+الخاصية احنا ممكن نقول عنها بالعربي خاصية اللي
+
+271
+00:24:49,450 --> 00:24:54,470
+علاقة بالفيزيا خاصية تدوير الضوء المستقطب في مستوى
+
+272
+00:24:54,470 --> 00:25:01,350
+واحدخاصية ضوئية بندرسها احنا بالفيزيا الان بدنا
+
+273
+00:25:01,350 --> 00:25:07,210
+نفهم ايش معناه ببساطة طبعا هذه الخاصية الفيزيائية
+
+274
+00:25:07,210 --> 00:25:14,020
+هذه الخاصية الفيزيائية الحقيقة احنا بنقيسهامن خلال
+
+275
+00:25:14,020 --> 00:25:18,880
+جهاز .. جهاز تدوير الضوء او بنسميه احنا البولاري
+
+276
+00:25:18,880 --> 00:25:24,840
+ميتر اش بنسميه الجهاز اللي بنقيس فيه البولاري ميتر
+
+277
+00:25:24,840 --> 00:25:31,480
+جهاز تدوير الضوء ببساطة هذا الجهاز بنجيب فيه ضوء
+
+278
+00:25:32,210 --> 00:25:36,810
+والضوء بنمرره على مستقطب بيصير ال vibration تبعه
+
+279
+00:25:36,810 --> 00:25:40,090
+باتجاه واحد، يعني تخيلوا أن هذا اللي موجود بإيدي
+
+280
+00:25:40,090 --> 00:25:44,530
+هو شعاع الضوء، الآن شعاع الضوء بيمشي للأمام، و
+
+281
+00:25:44,530 --> 00:25:50,790
+شعاع الضوء موجة كهرومغناطيسية، و الموجة إلها إيش؟
+
+282
+00:25:50,790 --> 00:25:55,590
+اهتزاز أو تردد، الآن أول ما بيطلع شعاع الضوء بيكون
+
+283
+00:25:55,590 --> 00:26:00,790
+يهتز بجميع الاتجاهاتيعني بهذا الشكل وبهذا الشكل
+
+284
+00:26:00,790 --> 00:26:06,070
+وبهذا الشكل وبهذا الشكل بنمرره على جهاز في الضوء
+
+285
+00:26:06,070 --> 00:26:10,470
+اسمه Polarimeter ال Polarimeter أسهل شيء ممكن
+
+286
+00:26:10,470 --> 00:26:18,110
+تتخيلوا فيه أنه مثل شيء معين فيه فتحة في النص يعني
+
+287
+00:26:18,110 --> 00:26:23,630
+زي هيك شايفين هذه الورقة؟الان هى فيها فتحة او slit
+
+288
+00:26:23,630 --> 00:26:28,590
+الان لو انا عند الضوء هنا يهتز بجميع الاتجاهات
+
+289
+00:26:28,590 --> 00:26:34,990
+بهذا الشكل واضح مررته على البولاريمتر فى فتحة اى
+
+290
+00:26:34,990 --> 00:26:37,910
+اهتزاز اللى بده يطلع من هذه الفتحة
+
+291
+00:26:40,630 --> 00:26:46,970
+فقط اهتزاز واحد الباقي كله ايش هينحجز بناء على ذلك
+
+292
+00:26:46,970 --> 00:26:50,770
+الضوء قبل ما يمر على ال polarimeter بنسميه
+
+293
+00:26:50,770 --> 00:26:54,850
+unpolarized light يعني اول ما بيطلع هنا بيكون عند
+
+294
+00:26:54,850 --> 00:27:01,050
+ال light unpolarized يهتز في جميع الاتجاهات مررتوا
+
+295
+00:27:01,050 --> 00:27:05,500
+على ال polarimeter اللي فيهمفتحة طبعا بيكون من
+
+296
+00:27:05,500 --> 00:27:09,600
+خلال بلورات بس ناخد الفكرة البساطة صار يهتز الضوء
+
+297
+00:27:09,600 --> 00:27:16,140
+في اتجاه واحد فبنسميه polarized light اذا صار عنده
+
+298
+00:27:16,140 --> 00:27:22,640
+الضوء polarized يهتز في اتجاه واحد unpolarized
+
+299
+00:27:22,640 --> 00:27:30,200
+يهتز في اتجاهفي جميع الاتجاهات الان هذا الضوء اللي
+
+300
+00:27:30,200 --> 00:27:35,320
+بيقول polarized بمرره على المركب تبعي مش انا اتفقت
+
+301
+00:27:35,320 --> 00:27:41,630
+ان عندي مركبينواحد R واحد S بجيب المركب بدوبه
+
+302
+00:27:41,630 --> 00:27:46,170
+بمحلول بحطه في أنبوبة زجاجية عادة زي هذا الجلم
+
+303
+00:27:46,170 --> 00:27:50,650
+يعني الأنبوبة طولها عادة عشرة سنتيمتر لغطاية زي
+
+304
+00:27:50,650 --> 00:27:55,750
+هيك بندوب المركب absorbent بنحطه و بنسكر عليه
+
+305
+00:27:55,750 --> 00:27:59,810
+بالغطاية بنحطه في مسار الضوء الآن تخيلوا الضوء كيف
+
+306
+00:27:59,810 --> 00:28:05,400
+قاعد بحتزفى مستوى واحد لما يمر فى أحد هدولة
+
+307
+00:28:05,400 --> 00:28:12,160
+الانانشو مارز بيروح بلوف طلعوا معاه كان يهتز بهذا
+
+308
+00:28:12,160 --> 00:28:18,460
+الاتجاه مر بيطلع يهتز باتجاه مختلف ملاحظين؟ طيب
+
+309
+00:28:18,460 --> 00:28:23,060
+السؤال لو ياتورا مر بمركب مافيش منه R.O.S يعني
+
+310
+00:28:23,060 --> 00:28:25,760
+بمية بيظله
+
+311
+00:28:26,790 --> 00:28:31,170
+بهذا الشكل بمر الميه بيتأثرش عليه بيطلع احتزازه
+
+312
+00:28:31,170 --> 00:28:38,430
+بنفس الشكل لكن لو ماربل ار بيلوف بيصيله عملية ايش
+
+313
+00:28:38,430 --> 00:28:45,430
+روتيشن الان احنا بنقدر نستقبل الشعاع الضوءي ونشوف
+
+314
+00:28:45,430 --> 00:28:51,370
+كده زاويةالدوران اللى لفها يعني هيه بهذا الشكل
+
+315
+00:28:51,370 --> 00:28:55,950
+لفها القدر عشرين درجة تلاتين اربعين بنقدر هذا
+
+316
+00:28:55,950 --> 00:28:59,870
+الكلام نعمله تطبيقيا من خلال جهاز ال polarimeter
+
+317
+00:28:59,870 --> 00:29:05,130
+اللى بنلاحظه القاتلإنه لو واحد من هدولة
+
+318
+00:29:05,130 --> 00:29:10,390
+الانانشومارز كان بيلف الضوء باتجاه معين وبزاوية
+
+319
+00:29:10,390 --> 00:29:15,370
+معينة نفترض بيلف الضوء باتجاه اليمين بزاوية تلاتين
+
+320
+00:29:15,370 --> 00:29:22,010
+درجة المركب التاني نفس الكمية منه بتلف الضوء
+
+321
+00:29:22,010 --> 00:29:28,390
+بالاتجاه المعاكس بنفس المقدار إذا الاختلاف الآن
+
+322
+00:29:28,390 --> 00:29:33,490
+بمقدار الدوران بين المركبين ال R و ال Sلأ إذا
+
+323
+00:29:33,490 --> 00:29:39,870
+استعملت نفس الكمية فقط الاختلاف يكون بماذا؟ باتجاه
+
+324
+00:29:39,870 --> 00:29:45,830
+الدوران فواحد منهم بلف الضوء باتجاه اليمين وواحد
+
+325
+00:29:45,830 --> 00:29:48,410
+منهم بلف الضوء يعني لو أنا اتخيلت أنه عندي زي
+
+326
+00:29:48,410 --> 00:29:53,030
+مانجلة أو ما إلى ذلك إذا واحد منهم لف الضوء بهذا
+
+327
+00:29:53,030 --> 00:29:57,770
+الاتجاه تلاتين درجة التاني بلف الضوء بهذا الاتجاه
+
+328
+00:29:57,770 --> 00:30:05,350
+ناقص تلاتينطبعا الشرط ان انا استعمل نفس الكمية من
+
+329
+00:30:05,350 --> 00:30:09,690
+المركبين واضح؟ الشرط ان انا استعمل نفس الكمية من
+
+330
+00:30:09,690 --> 00:30:14,410
+المركبين ولذلك لو انتوا انتبهتوا لما انا حكيت عن
+
+331
+00:30:14,410 --> 00:30:18,230
+الخاصية الفيزيائية الجولية بيختلفوا بال direction
+
+332
+00:30:18,230 --> 00:30:24,730
+of rotation اتجاه التدوير ماقلتش بال amount of
+
+333
+00:30:24,730 --> 00:30:31,140
+rotationنفس الكمية من ال R و نفس الكمية من ال S
+
+334
+00:30:31,140 --> 00:30:36,240
+بيختلفوا بس بالاتجاه واحدة بتلفه على اليمين
+
+335
+00:30:36,240 --> 00:30:43,220
+والتانية بتلفه لليسار لكن ما بيختلفوا بالمقدار هذا
+
+336
+00:30:43,220 --> 00:30:47,100
+هو الاختلاف ما بين ال enantiomers بال physical
+
+337
+00:30:47,100 --> 00:30:50,700
+Proparities واحد بيلف على اليمين و واحد بيلف على
+
+338
+00:30:50,700 --> 00:30:59,490
+اليسارالان إذا هذه الفكرة وهي الأساس أصبحت واضحة
+
+339
+00:30:59,490 --> 00:31:04,210
+خلّينا الآن نضيف عليها شوية أفكار بسيطة لما
+
+340
+00:31:04,210 --> 00:31:10,170
+اتكلمنا على الكمية مش احنا قلنا بندوّببندوّب كمية
+
+341
+00:31:10,170 --> 00:31:12,910
+من المُركّب وبنحطها في الأنبوبة تبع
+
+342
+00:31:12,910 --> 00:31:18,270
+الـPolarimeter؟ طيب، أنا ممكن أدوّب كمية صغيرة؟
+
+343
+00:31:18,270 --> 00:31:22,090
+ممكن أكتر؟ ممكن أكتر؟ ممكن أكتر؟ يعني ممكن أعمل
+
+344
+00:31:22,090 --> 00:31:28,190
+عدد كبير من التركيز؟ أكيد، خلّيني أقول مثلا، لو
+
+345
+00:31:28,190 --> 00:31:30,610
+أعمل التركيز واحد، concentration one,
+
+346
+00:31:30,730 --> 00:31:32,910
+concentration two, concentration three,
+
+347
+00:31:33,250 --> 00:31:37,480
+concentration fourبقدر اعمل اكتر من التركيز و
+
+348
+00:31:37,480 --> 00:31:42,020
+خلّيني افترض ان التركيز بتزيد بهذا الشكل و انا
+
+349
+00:31:42,020 --> 00:31:45,720
+بجيس الزاوية للمركب اللي عملت منه اكتر من التركيز
+
+350
+00:31:45,720 --> 00:31:51,030
+الزاوية اللي بقيسها بعطيها رمز Alphaتمام ل
+
+351
+00:31:51,030 --> 00:31:56,750
+Concentration 1 بقيس زاوية Alpha 1 ل Concentration
+
+352
+00:31:56,750 --> 00:32:01,270
+2 Alpha 2 ل Concentration 3 Alpha 3 ل
+
+353
+00:32:01,270 --> 00:32:05,770
+Concentration 4 Alpha 4 يعني صار عندى اكتر من
+
+354
+00:32:05,770 --> 00:32:10,270
+زاوية الدوران هذه ال Alpha بقول عنها Observed
+
+355
+00:32:10,270 --> 00:32:15,090
+Rotation اللى هو Observed
+
+356
+00:32:15,850 --> 00:32:20,130
+rotation اللى هو الدوران اللى انا لاحظته بالجهاز
+
+357
+00:32:20,130 --> 00:32:26,410
+هل معقول يا تورا انه يكون عندى لكل تركيز اكثر
+
+358
+00:32:26,410 --> 00:32:32,090
+زاوية لكل تركيز معين زاوية معينة الجواب اه وبسيط
+
+359
+00:32:32,090 --> 00:32:37,430
+جدا اتخيلوا واتذكروا معايا لو كان عندكم على سبيل
+
+360
+00:32:37,430 --> 00:32:45,590
+المثال خمس أحجام من الميهكباية، شاف، طنجرة، كل
+
+361
+00:32:45,590 --> 00:32:52,350
+واحدة فيها ميّه الحجم الأول له كتلة أولى الحجم
+
+362
+00:32:52,350 --> 00:32:58,190
+التاني له كتلة تانية الحجم التالت له كتلة تالتة
+
+363
+00:32:58,190 --> 00:33:01,370
+مظبوط ولا لأ الكتلة و الحجم بيعتمدوا على كمية
+
+364
+00:33:01,370 --> 00:33:09,390
+المادة، مقدارها الآن إذا لكل حجم كتلة لكل تركيز
+
+365
+00:33:10,220 --> 00:33:15,400
+زاوية الآن الحجم والكتلة عمري ما أخدتهم أنا كخاصية
+
+366
+00:33:15,400 --> 00:33:21,140
+أعرف من خلالهم المية لماذا؟ لأن الماء له عدد لا
+
+367
+00:33:21,140 --> 00:33:27,540
+نهائي من الكتل وله عدد لا نهائي من الأحجام واضح؟
+
+368
+00:33:27,540 --> 00:33:31,440
+طب هايش الخاصية اللي في منها بس قيمة واحدة للمية
+
+369
+00:33:31,440 --> 00:33:39,400
+لا تعتمد على المقدار ال density الكثافة لو جبت أنا
+
+370
+00:33:40,220 --> 00:33:45,140
+كل كتلة قِستة يعني لو عملت 100 حجم و قِستلهم 100
+
+371
+00:33:45,140 --> 00:33:47,740
+كتلة كل مرة الكتلة على الحجم الكتلة على الحجم
+
+372
+00:33:47,740 --> 00:33:51,220
+الكتلة على الحجم الكتلة على الحجم نفس المقدار
+
+373
+00:33:51,220 --> 00:33:55,520
+تماما ال density إذا الكتلة و الحجم يعتمدوا على
+
+374
+00:33:55,520 --> 00:33:59,400
+المقدار منهم عدد لنهائي موجود لأي مادة لكن ال
+
+375
+00:33:59,400 --> 00:34:03,780
+density للميه لو سألتكم عند الحرارة العادية كم
+
+376
+00:34:03,780 --> 00:34:08,550
+كثافة الماء1 جرام لكل سنتمتر مكعب
+
+377
+00:34:12,120 --> 00:34:17,440
+فقط لغير هو اللي بنسجله كخاصية للمق في الكتب الأن
+
+378
+00:34:17,440 --> 00:34:23,700
+نفس الكلام تماما لكل تركيز زاوية دوران طيب يا تورا
+
+379
+00:34:23,700 --> 00:34:29,380
+لو أنا بعد هيك بدي مقدار واحد للمركب أنا صار عند
+
+380
+00:34:29,380 --> 00:34:34,160
+ألف واحد ألف اتنين ألف تلات ألف أربعة باجي بعرف
+
+381
+00:34:34,160 --> 00:34:41,730
+كمية بسميها ل specific rotation الدوران النوعيالان
+
+382
+00:34:41,730 --> 00:34:45,410
+الـ specific rotation بيساوي الـ observed rotation
+
+383
+00:34:45,410 --> 00:34:51,490
+الألفة مقسوم على طول الأنبوبة بالديسميتر بتعرف
+
+384
+00:34:51,490 --> 00:34:55,530
+الديسميتر كام سانتي؟ عشرة سانتي يعني واحد في عشر
+
+385
+00:34:55,530 --> 00:34:59,810
+أقصى ناقص واحد من المتر وإحنا عادة الأنبوبة
+
+386
+00:34:59,810 --> 00:35:04,600
+عاملينها ديسميتر يعني بتكون القيمة جديش؟وحد ديسمتر
+
+387
+00:35:04,600 --> 00:35:09,660
+على التركيز للمادة بالإجرام لكل ملل، لاحظوا قسمة
+
+388
+00:35:09,660 --> 00:35:14,500
+الالف على التركيز كعلمي الف واحد على C واحد، الف
+
+389
+00:35:14,500 --> 00:35:17,020
+اتنين على C اتنين، الف تلاتة على C تلاتة، الف
+
+390
+00:35:17,020 --> 00:35:22,320
+أربعة على C أربعة، خلّيت طول الأنبوبة نفس الشيء،
+
+391
+00:35:22,320 --> 00:35:28,000
+الآن بيطلع عندSpecific rotation الان هذه بتطلع نفس
+
+392
+00:35:28,000 --> 00:35:31,340
+القيمة نفس القيمة نفس القيمة نفس القيمة تماما زي
+
+393
+00:35:31,340 --> 00:35:36,050
+ما كان عندكم كتل كتير و حجام كتيرDensity واحدة
+
+394
+00:35:36,050 --> 00:35:41,430
+الان تركيزي كتيرة Alpha كتيرة لكن لما اقسم ال
+
+395
+00:35:41,430 --> 00:35:44,810
+alpha على ال concentration مضروب في طول الأنبوبة و
+
+396
+00:35:44,810 --> 00:35:48,390
+احنا موحدينه عشان نريح حالنا بطلع عندى بس زاوية
+
+397
+00:35:48,390 --> 00:35:53,070
+واحدة اسمها ال specific rotation الان هذه الزاوية
+
+398
+00:35:53,070 --> 00:35:56,830
+بتصير جزء من خواص المركب يعني يوم ما اقول ان في
+
+399
+00:35:56,830 --> 00:36:03,770
+عندى مركبكايرال بقول زاويتها لجد، الآن بدا تكون يا
+
+400
+00:36:03,770 --> 00:36:09,330
+موجبة، يا إيش؟ سالبة، إذا كانت دوران على اليمين،
+
+401
+00:36:09,330 --> 00:36:15,010
+إبناعته، plus ووقتها المركب اللي بلوف على اليمين
+
+402
+00:36:17,190 --> 00:36:20,570
+المُركّب مش احنا يقول إن واحد بده يلف على اليمين
+
+403
+00:36:20,570 --> 00:36:26,270
+والتاني على الشمال الآن ما هي الزاوية المتساوية
+
+404
+00:36:26,270 --> 00:36:31,130
+للتانين ال alpha ولا ال specific rotation ال
+
+405
+00:36:31,130 --> 00:36:35,030
+specific rotation اللي هي ال alpha اللي بين جثين
+
+406
+00:36:35,030 --> 00:36:40,570
+الآن هدولة المُركّبين لو واحد كان منهم زائد تلاتين
+
+407
+00:36:40,570 --> 00:36:47,310
+هيلف على اليمين التاني منهم ناقص تلاتينالان المركب
+
+408
+00:36:47,310 --> 00:36:50,970
+اللى بلوف على اليمين بنعطيه إشارة موجب بنصير نكتب
+
+409
+00:36:50,970 --> 00:36:54,910
+قدامه موجب ومقدار الزاوية وبنعطيه وصف
+
+410
+00:36:54,910 --> 00:36:58,930
+Dextrorotatory إيش يعني Dextrorotatory
+
+411
+00:36:58,930 --> 00:37:07,520
+Dextrorotatory يعني يقولبلف الضوع اليمين والمركب
+
+412
+00:37:07,520 --> 00:37:12,720
+التاني ال minus بنعطيه اسم Levo Rotatory إذا
+
+413
+00:37:12,720 --> 00:37:17,500
+المركبات صاروا نوعين واحد بيلف يمين بيعطيه إشارة
+
+414
+00:37:17,500 --> 00:37:22,040
+الموجبة واحد بيلف إشمال بيعطيه إشارة السلبة واحد
+
+415
+00:37:22,040 --> 00:37:28,850
+منهم موجب والتاني منهمسالب واضح الموجب بقول عنه
+
+416
+00:37:28,850 --> 00:37:33,550
+Dextrorotatory السالب بقول عنه Levorotatory الأن
+
+417
+00:37:33,550 --> 00:37:40,250
+انتبهوا معاه عشان نعمل هذا الكلام احنا جاعدين في
+
+418
+00:37:40,250 --> 00:37:45,070
+المختبر و لا لأ و عندنا جهاز يعني كيف جيس اتلا
+
+419
+00:37:45,070 --> 00:37:50,910
+مركب انه كان plus 30 او minus 30 في المختبر اذا
+
+420
+00:37:50,910 --> 00:37:56,980
+هذه النتيجة تعتبر نتيجةتجريبية طب لما انا كنت احدد
+
+421
+00:37:56,980 --> 00:38:03,060
+المركب انه R ولا S ايش كنت اعمل اشوف المجموعات
+
+422
+00:38:03,060 --> 00:38:08,800
+والوفهم لصغيرة لخالف الأعلى فالاقل فالاقل ولذلك
+
+423
+00:38:08,800 --> 00:38:14,260
+هنا بيجيني سؤال كتير مهم هل يا ترى هناك علاقة ما
+
+424
+00:38:14,260 --> 00:38:22,540
+بين ان المركب يكون R او S ويطلع موجب او سالبالجواب
+
+425
+00:38:22,540 --> 00:38:27,720
+بالتأكيد لأ يعني المُركّب أن R و S هذه أولوية
+
+426
+00:38:27,720 --> 00:38:32,460
+المجموعات أن موجب و سالب هذا قياس في مختبر ففي
+
+427
+00:38:32,460 --> 00:38:38,640
+مُركّبات R و موجبة و في مُركّبات R و سالبة و في
+
+428
+00:38:38,640 --> 00:38:44,620
+مُركّبات S و موجبة و في مُركّبات S و سالبة ولذلك
+
+429
+00:38:44,620 --> 00:38:50,060
+لو أنا بدي أصيغها بجملة بقول there is no relation
+
+430
+00:38:52,390 --> 00:38:59,730
+مافيش علاقة مافيش
+
+431
+00:38:59,730 --> 00:39:01,170
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+432
+00:39:01,170 --> 00:39:01,450
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+433
+00:39:01,450 --> 00:39:01,550
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+434
+00:39:01,550 --> 00:39:01,550
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+435
+00:39:01,550 --> 00:39:01,550
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+436
+00:39:01,550 --> 00:39:01,710
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+437
+00:39:01,710 --> 00:39:02,050
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+438
+00:39:02,050 --> 00:39:02,470
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+439
+00:39:02,470 --> 00:39:03,060
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيمش
+
+440
+00:39:03,060 --> 00:39:07,280
+الزام ان ال R تكون موجب او ال S سالب لأ هذا موضوع
+
+441
+00:39:07,280 --> 00:39:12,100
+و هذا موضوع الموجب و السالب بقيسه بالجهاز ال R و
+
+442
+00:39:12,100 --> 00:39:18,820
+ال S بحددهم بإيش بالأولويات و لذلك بتلاحظوا انه لو
+
+443
+00:39:18,820 --> 00:39:24,120
+بتفتشوا على مركب معين في كتالوج كيمويات مركب معين
+
+444
+00:39:24,120 --> 00:39:27,100
+في كتالوج كيمويات ممكن على ال computer تكتبوه
+
+445
+00:39:27,100 --> 00:39:34,650
+حيصير معرفي بشغلتينمكتوب عندكم R وجنبها نفترض plus
+
+446
+00:39:34,650 --> 00:39:40,690
+30 ممكن يكون R minus 30 الآن سويا انا اعطيكم
+
+447
+00:39:40,690 --> 00:39:45,930
+homework ادخلوا على الكمبيوتر و اكتبوا اسم مركبين
+
+448
+00:39:45,930 --> 00:39:51,290
+هذول المركبين كايرال هذول المركبين لو كان عندكم
+
+449
+00:39:51,290 --> 00:39:55,830
+carbon تنتين تلاتة أربعة وهي carbon تنتين تلاتة
+
+450
+00:39:55,830 --> 00:40:02,490
+أربعة لو حطيت هنا chlorineافترض OH وحطيت هنا OH و
+
+451
+00:40:02,490 --> 00:40:07,310
+هنا H وكملوا
+
+452
+00:40:07,310 --> 00:40:17,370
+المركب يعني CH3 CH2 CH3 و هذا CH3 CH2 CH3 الآن
+
+453
+00:40:17,370 --> 00:40:24,370
+هذولا المركبين chiral ولا لأ؟ chiral الآن هذا
+
+454
+00:40:24,370 --> 00:40:30,080
+المركب اسمه two-chlorobutaneبتقدر تحددوله ROS
+
+455
+00:40:30,080 --> 00:40:34,640
+بالقواعد اللي اتعلمتوهم؟ حددوا ايه له ROS؟ وهذا
+
+456
+00:40:34,640 --> 00:40:41,320
+اسمه Top-Butanol بنقدر نحددله ROS؟ بنقدر، اذا ان
+
+457
+00:40:41,320 --> 00:40:47,150
+انا احدد للمركب ROS من وين بجيبهم؟من المجموعات
+
+458
+00:40:47,150 --> 00:40:51,870
+والأولويات الآن بعد هيك لما تحددوا نفترض هذا طلع R
+
+459
+00:40:51,870 --> 00:40:57,430
+روحوا شوفولي ال R-2-chlorobutane بالكتالوجي من
+
+460
+00:40:57,430 --> 00:41:02,890
+الكمبيوتر قدش قيمة ال alpha تبعته وبعدها نفترض هذا
+
+461
+00:41:02,890 --> 00:41:08,490
+طلع S or whatever 2-butanol شوفولي من الكتالوجي
+
+462
+00:41:08,490 --> 00:41:12,790
+اضربه على ال google search نفترض كام S-2-butanol
+
+463
+00:41:12,790 --> 00:41:20,040
+او R-2-butanol شوفوليجداش الزاوية تبعته واضح؟ الان
+
+464
+00:41:20,040 --> 00:41:24,740
+خليكم معاه لو افترضنا هذا المركب او ممكن نعمله
+
+465
+00:41:24,740 --> 00:41:29,540
+بسهولة ايه موجود هذه هنا واحد اتنين تلاتة هذا R
+
+466
+00:41:29,540 --> 00:41:35,340
+راحت واحدة فتشت في الكمبيوتر لجت ان ال S2 كلورو
+
+467
+00:41:35,340 --> 00:41:41,240
+بيوتين ناقص عشرين مالجتش ال R بتحل ال .. بتحل ال
+
+468
+00:41:41,240 --> 00:41:48,650
+homework ولا لأ؟إذا عرف واحد التاني عكسهواضح؟ يعني
+
+469
+00:41:48,650 --> 00:41:52,510
+لو واحدة فتشت على الكمبيوتر و بتفتش ايش زاوية مركب
+
+470
+00:41:52,510 --> 00:41:57,510
+ال R لجت زاوية ال S تبقى لها ساعتين تفتش على مركب
+
+471
+00:41:57,510 --> 00:42:03,410
+ال R قد ايش زاويته اذا لجت ال R ال S عكسها و اذا
+
+472
+00:42:03,410 --> 00:42:09,450
+لجت ال S ال R عكسها لاحظوا لا يختلفوا في القيمة
+
+473
+00:42:09,450 --> 00:42:15,350
+ولكن يختلفوا في الاتجاهجربوا وشوفوا كيف هذه
+
+474
+00:42:15,350 --> 00:42:19,750
+المراكبات بتنكتب هدولا خاصيتين لازم يكونوا معروفين
+
+475
+00:42:19,750 --> 00:42:25,730
+عن المراكب ال configuration يحدد من الأولويات و ال
+
+476
+00:42:25,730 --> 00:42:31,590
+rotation يحدد بال إيش بالتجربة باستعمال جهاز
+
+477
+00:42:31,590 --> 00:42:36,290
+البولاري ميتر وبهيك بننهي اليوم ان شاء الله و
+
+478
+00:42:36,290 --> 00:42:36,730
+بنكمل
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tov4h-a7-Pc_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tov4h-a7-Pc_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..49fb3801714f5bcfa88e6a66293f732a1bc79df1
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tov4h-a7-Pc_postprocess.srt
@@ -0,0 +1,2364 @@
+1
+00:00:20,810 --> 00:00:27,390
+بسم الله الرحمن الرحيم بعد ما اتعرفنا في المرات
+
+2
+00:00:27,390 --> 00:00:37,590
+الماضية على الأحماض الأمينية و تفاعلاتها اليوم
+
+3
+00:00:37,590 --> 00:00:43,210
+ان شاء الله هنتعرف كيف هذه الأحماض الأمينية طبعا
+
+4
+00:00:43,210 --> 00:00:49,650
+بتتحد مع بعضها البعضبشكل متتابع لتكوين ال peptides
+
+5
+00:00:49,650 --> 00:00:56,850
+وأكبر منهم طبعا بيكونوا إيش ال proteins بالنسبة ل
+
+6
+00:00:56,850 --> 00:01:02,130
+ال proteins زي ما انتوا عارفين اللهم أهمية
+
+7
+00:01:02,130 --> 00:01:07,510
+بيولوجية جزيئات أساسيةمثلا في الأشياء اللي بنسميها
+
+8
+00:01:07,510 --> 00:01:12,150
+structural tissues، الأنسجة البنائية الأساسية،
+
+9
+00:01:12,150 --> 00:01:17,390
+العضلات، ال muscles، ال skin، الجلد، ال nails،
+
+10
+00:01:17,390 --> 00:01:23,070
+الأضافر، ال hair، الشعر، كل هذا يصنفوا على أنه
+
+11
+00:01:23,070 --> 00:01:27,150
+إيش؟ ال proteins and they are structural tissuesفي
+
+12
+00:01:27,150 --> 00:01:31,850
+عندنا transport molecules الجزيئات الناقلة من
+
+13
+00:01:31,850 --> 00:01:37,130
+أمثلتها مثلا ال hemoglobin في عندنا ال enzymes
+
+14
+00:01:37,130 --> 00:01:42,010
+اللي هي ال biological catalyst أيضا هذه ال
+
+15
+00:01:42,010 --> 00:01:47,970
+proteins الآن لما بنيجي نتكلم عن ال protein بشكل
+
+16
+00:01:47,970 --> 00:01:54,270
+عام بنتكلم الحقيقة عن أربع أشكال لل protein يعني
+
+17
+00:01:54,270 --> 00:01:58,560
+هيمروا معاكم مصطلحاتprimary structure of protein
+
+18
+00:01:58,560 --> 00:02:02,520
+secondary structure of protein tertiary structure
+
+19
+00:02:02,520 --> 00:02:06,000
+of protein and quaternary structure of protein
+
+20
+00:02:06,000 --> 00:02:11,740
+والمفروض فينا ان نفهم ايش معنى هذه الأشكال وهذا
+
+21
+00:02:11,740 --> 00:02:17,520
+تقريبا هيكون محور الدرس اليوم ايش معنى اللي هي
+
+22
+00:02:17,520 --> 00:02:20,940
+أشكال البروتين ال primary structure شو معنى ال
+
+23
+00:02:20,940 --> 00:02:27,410
+secondary tertiary quaternary الان لو بدنا نبدأأول
+
+24
+00:02:27,410 --> 00:02:32,070
+شيء في ال primary structure of proteins المقصود
+
+25
+00:02:32,070 --> 00:02:38,350
+فيه ال amino acid sequence يعني كيف الأحماض
+
+26
+00:02:38,350 --> 00:02:42,950
+الأمينية مرتبة في هذا ال protein أو في الأصغر منه
+
+27
+00:02:42,950 --> 00:02:48,010
+اللي هو إيش ال peptide طبعا إحنا اتفقنا سابقا إن
+
+28
+00:02:48,010 --> 00:02:52,510
+ال amino acid إلهtwo abbreviations three letter
+
+29
+00:02:52,510 --> 00:02:57,590
+abbreviation عادة بنستعمله للتعبير عن الـpeptide و
+
+30
+00:02:57,590 --> 00:03:00,530
+one letter abbreviation عادة بنستعمله للتعبير عن
+
+31
+00:03:00,530 --> 00:03:05,110
+البروتين طبعا
+
+32
+00:03:05,110 --> 00:03:11,490
+كيف بيحددوا ال primary structure of بروتين يعني
+
+33
+00:03:11,490 --> 00:03:19,010
+نفترض بروتين في الف amino acid الف وحدةقبعا هدولة
+
+34
+00:03:19,010 --> 00:03:25,790
+الألف واحدة هتلاحظوا ان هما في النهاية من عشرين
+
+35
+00:03:25,790 --> 00:03:31,770
+amino acid مش هيك احنا اتفقنا بمعنى انه مثلا amino
+
+36
+00:03:31,770 --> 00:03:37,590
+acid glycine نفترض فيه منه خمسين مرة متكررواضح؟
+
+37
+00:03:37,590 --> 00:03:42,230
+أمينو أسد ليسين افترض تلاتين مرة أمينو أسد
+
+38
+00:03:42,230 --> 00:03:48,330
+تريبتوفان ممكن نقول ستين مرة الآن هدولة في النهاية
+
+39
+00:03:48,330 --> 00:03:54,470
+بيجمعوا ايش؟ بيجمعوا البروتين اللي مكون من الف
+
+40
+00:03:54,470 --> 00:03:59,850
+أمينو أسد واضح الفكرة؟ يعني لو انا يمكن اتعودنا
+
+41
+00:03:59,850 --> 00:04:03,850
+احنا ان نتخيل انه بهذا الشكل كأننا بنعمل ايش؟
+
+42
+00:04:05,160 --> 00:04:11,400
+ببتايد او بروتين الان لو جيبت انا عشرين نوع من هذه
+
+43
+00:04:11,400 --> 00:04:15,560
+الاجلام من نوع اربعين من نوع خمسين من نوع سبعين من
+
+44
+00:04:15,560 --> 00:04:22,040
+نوع تمانين لحد ما كان المجموع الكل قداش الف وطلبت
+
+45
+00:04:22,040 --> 00:04:28,220
+من اي شخص انه تعالى يعمل اليهم سلسلة بروتين هل
+
+46
+00:04:28,220 --> 00:04:33,760
+عقلا بتتوقعوا انه ممكن اتنين يعملوا نفس الشيء
+
+47
+00:04:35,760 --> 00:04:40,900
+مستحيل، يعني هذه تعتبر صدفة مستحيلة، ليش؟ لأن كل
+
+48
+00:04:40,900 --> 00:04:46,400
+واحد بيحطهم بشكل معين، بيعمل sequence معينة، الآن
+
+49
+00:04:46,400 --> 00:04:51,220
+تخيلوا إنه في الدنياهذه الـ sequence لبروتين محدد
+
+50
+00:04:51,220 --> 00:04:55,780
+هي sequence ثابتة او لإنزايم محدد هي sequence
+
+51
+00:04:55,780 --> 00:05:00,160
+ثابتة يعني مانفعش نيجي نقول والله الانسولين و
+
+52
+00:05:00,160 --> 00:05:04,520
+بعدين كل انسولين مختلف عن التاني لأ لما نقول
+
+53
+00:05:04,520 --> 00:05:09,740
+انسولين هيكون له sequence ثابت الآن هذه ال
+
+54
+00:05:09,740 --> 00:05:15,530
+sequence الثابتة لازم يتعرفوا عليهابالمرحلة الأولى
+
+55
+00:05:15,530 --> 00:05:20,670
+و بعد هيك إذا و الله لازمهم انهم يقدروا يجمعوا ال
+
+56
+00:05:20,670 --> 00:05:24,290
+amino acids و يحضروها كان بها إذا حسوا ان القمر
+
+57
+00:05:24,290 --> 00:05:28,590
+فيه غلبة كتير و في عنده مصدر طبيعي ممكن يعطينا
+
+58
+00:05:28,590 --> 00:05:32,130
+انسليل زي الأبقار و ما إلى ذلك بروحوا بيجيبوه
+
+59
+00:05:32,130 --> 00:05:37,630
+المصدر الطبيعي محضر و جاهز فبتصير من أصعب الشغلات
+
+60
+00:05:37,630 --> 00:05:44,030
+في موضوعHow to determine the primary structure of
+
+61
+00:05:44,030 --> 00:05:49,890
+a protein يعني كيف انا بدي طرق اني احدد هذا الشكل
+
+62
+00:05:49,890 --> 00:05:56,430
+الان المرحلة الاولى لو انا حطيت ال protein بحمض
+
+63
+00:05:56,430 --> 00:06:03,110
+محرارة كسرتهلأ الأحماض اللي متكون منها طبعا مش
+
+64
+00:06:03,110 --> 00:06:06,610
+ضروري ال protein او ال peptide يكون من ال 20 amino
+
+65
+00:06:06,610 --> 00:06:13,050
+acid ممكن من اقل ممكن من 14 من 8 من 15 حسب نوعه
+
+66
+00:06:13,050 --> 00:06:17,930
+تمام؟ في هذه الحالة بدون حطوا ال protein يغلو مع
+
+67
+00:06:17,930 --> 00:06:25,290
+الحامض لمدة حوالي 24 ساعة بتتكسركل ايش؟ كل ال
+
+68
+00:06:25,290 --> 00:06:28,430
+peptide bonds و لاحظوا متذاكرين احنا لما أخدنا ال
+
+69
+00:06:28,430 --> 00:06:31,550
+amide bond قولنا ال amide bond بالتسخين الطويل
+
+70
+00:06:31,550 --> 00:06:35,750
+تتكسر و ال peptide bond is an amide bond في
+
+71
+00:06:35,750 --> 00:06:40,370
+النهاية اذا هيني انا كسرته طلع عندى من الأخضر مثلا
+
+72
+00:06:40,370 --> 00:06:45,050
+اتنين من الأسود تلاتة من الأحمر glycine واضح بعد
+
+73
+00:06:45,050 --> 00:06:52,770
+هيك ابقى جهزة معينةسهلة أجهزة كروماتوغرافي نمرر و
+
+74
+00:06:52,770 --> 00:06:56,590
+نعرف كم نوع amino acid عندك بقى لكل نوع amino acid
+
+75
+00:06:56,590 --> 00:06:57,470
+اللي بيعطي نبيك
+
+76
+00:07:02,690 --> 00:07:09,270
+الأطياف 1,2,3,4,5,6,7,8 يعني هذا بيبتايد مكون من
+
+77
+00:07:09,270 --> 00:07:13,930
+كام نوع من ال amino acids من تمانية الآن حسب كوبر
+
+78
+00:07:13,930 --> 00:07:18,470
+هذه بتكون هذه التعبير عن جداش عندي أعداد يعني
+
+79
+00:07:18,470 --> 00:07:23,080
+نفترضهذه بتمثل أربعة، وهذه بتمثل ستة، وهذه تمثل
+
+80
+00:07:23,080 --> 00:07:28,560
+تمانية، بجمعه حسب العدد الكلي، فالان صرنا عارفين
+
+81
+00:07:28,560 --> 00:07:33,560
+المكونات الفردية، يعني المكونات الفردية انها تنعرف
+
+82
+00:07:33,560 --> 00:07:40,420
+ليستأمرا صعبا بالنسبة للكيميا ايه واضح اطلاقا مش
+
+83
+00:07:40,420 --> 00:07:45,580
+امر صعب يعني انا بدي اسهل عليكم لو عملتلكم على
+
+84
+00:07:45,580 --> 00:07:54,480
+سبيل المثال هذا ال ال بروتيل او ال peptide واضح؟
+
+85
+00:07:54,480 --> 00:08:00,310
+الآن و اجيت عملتله ال hydrolysis كسرتهو بعد هي
+
+86
+00:08:00,310 --> 00:08:04,270
+قلتلكوا اعملولي المكونات الفردية تبعته هتقولولي في
+
+87
+00:08:04,270 --> 00:08:08,290
+اتنين Glycine في واحد Alanine في واحد Tyrosine في
+
+88
+00:08:08,290 --> 00:08:15,070
+واحد Valine اربع انواع واضح؟ لكن السؤال الصعب لو
+
+89
+00:08:15,070 --> 00:08:20,330
+انا الآن بقولكم كيف كانوا هدولة مرتبين ولا حد فيكم
+
+90
+00:08:20,330 --> 00:08:25,020
+اتطلع و متأكد كيف كانوا مرتبين ولا حتى انايمكن في
+
+91
+00:08:25,020 --> 00:08:29,060
+عندنا الكاميرا لو كنا بنرجع بالتسجيل بنقدر نشوف
+
+92
+00:08:29,060 --> 00:08:33,420
+كيف كانوا مرتبين لكن ماحد فينا عارف واضح ماحد فينا
+
+93
+00:08:33,420 --> 00:08:37,520
+عارف كيف كانوا مرتبين ففكرة ان اكسرهم و اعرفهم
+
+94
+00:08:37,520 --> 00:08:41,740
+بالظبط جديش العدد الكلي تباعهم و العدد الكلي مكون
+
+95
+00:08:41,740 --> 00:08:47,080
+من اي amino acids هذه الفكرةممكن أو بسيطة
+
+96
+00:08:47,080 --> 00:08:53,760
+كيميائيا، لكن الفكرة الأصعب، الـ sequence تبعتهم
+
+97
+00:08:53,760 --> 00:08:57,720
+اللي كانت موجودة، هذه الفكرة الأصعب
+
+98
+00:08:59,850 --> 00:09:05,370
+اللي أخدت تجارب لحد ما قدروا يحددوا الـ sequences
+
+99
+00:09:05,370 --> 00:09:11,410
+من التجارب هذه من التجارب الأولية اللي بدأوا
+
+100
+00:09:11,410 --> 00:09:15,950
+يستعملوها لتحديد الـ sequences كان في عنده طريقة
+
+101
+00:09:15,950 --> 00:09:19,050
+سيد زانجر method زانجر method
+
+102
+00:09:21,560 --> 00:09:27,080
+اتذكروا معنا شغلة انه احنا لما اتكلمنا عن ال
+
+103
+00:09:27,080 --> 00:09:33,080
+بيبتايد اذا بتذكروا قلنا انه ال بيبتايد له
+
+104
+00:09:36,520 --> 00:09:42,560
+terminal و C terminal مظبوط ولا لا الآن ال method
+
+105
+00:09:42,560 --> 00:09:50,960
+زانجر ماعملتش شغل كتير لنا عملت شغلة بسيطة جدا بس
+
+106
+00:09:50,960 --> 00:09:57,260
+قال انا بقدر اساعدكم اقولكم مين اول amino acid and
+
+107
+00:09:57,260 --> 00:10:01,900
+terminal يعني بس بيقولي ان ال and terminal هو مثلا
+
+108
+00:10:01,900 --> 00:10:08,110
+نجليسين او tryptophan و بعد هيكبيعجز، الآن كيف
+
+109
+00:10:08,110 --> 00:10:13,270
+ممكن زانجر يعمل هذه الطريقة، يحدد لأي واحد، يعني
+
+110
+00:10:13,270 --> 00:10:17,510
+هم لما يتكسروا، بتقولوا هدولة خمسة، لكن مين كان
+
+111
+00:10:17,510 --> 00:10:24,470
+فيهم الـand terminal؟ مش عارفين، واضح؟ الآن method
+
+112
+00:10:24,470 --> 00:10:30,390
+زانجر بتعرف النيةواضح فزانجر method فقط بتقدر
+
+113
+00:10:30,390 --> 00:10:36,130
+تقولنا من ال N terminal ال N كفكرة بعيدا عن
+
+114
+00:10:36,130 --> 00:10:40,490
+المعادلات الكيميائية ايش اللي بيعمله زانجر زانجر
+
+115
+00:10:40,490 --> 00:10:46,130
+بيجي بيجيب مادة خارجية بتتفاعل مع ال N H2 ال N في
+
+116
+00:10:46,130 --> 00:10:52,330
+كل هذا الجزء وين موجود N H2في الـ Unterminal اللي
+
+117
+00:10:52,330 --> 00:10:56,810
+هنا Unetched Unreactive هذه Unetched هذه Unetched
+
+118
+00:10:56,810 --> 00:11:02,990
+هذه Unetched صارت Unreactive في فقط Unetched واحدة
+
+119
+00:11:02,990 --> 00:11:08,990
+الان بيجيب مادة كيميائية غريبة و بيعمل تفاعل لهذه
+
+120
+00:11:08,990 --> 00:11:14,070
+المادة مع ال Unetched بيصير ولا لأ هيجيب المادة و
+
+121
+00:11:14,070 --> 00:11:20,560
+هيعمللها تفاعل شبكهامع ال N H2 لاحظوا ال N
+
+122
+00:11:20,560 --> 00:11:24,720
+Terminal صار مشبوك فيه مادة و لا لأ مادة معينة ال
+
+123
+00:11:24,720 --> 00:11:32,060
+N بعد هيك بكسر ال protein كسرنا واحد اتنين تلاتة
+
+124
+00:11:33,070 --> 00:11:38,010
+وبيجي بيفحص الان هيلاجي هذا amino acid معروف عند
+
+125
+00:11:38,010 --> 00:11:42,390
+هذا amino acid صفات هذا هذا الان هيلاجي فيهم واحد
+
+126
+00:11:42,390 --> 00:11:47,710
+مرتبط بالمادة اللي عملت تفاعل معها اللي مرتبط
+
+127
+00:11:47,710 --> 00:11:51,830
+بالمادة هذه هو مين بيكون ال unterminal واضح
+
+128
+00:11:51,830 --> 00:11:56,410
+الفكرة؟بيظل اذا احنا هذا الكلام اللي عملناه بدون
+
+129
+00:11:56,410 --> 00:12:00,610
+ما نحكي اسماء مواد ان نعرف شو هي المادة اللي
+
+130
+00:12:00,610 --> 00:12:04,890
+بتتفاعل مع ال N-H2 بترتبط معها و لما يتكسر بيظلوا
+
+131
+00:12:04,890 --> 00:12:11,050
+مشابكين التنتين مع بعض، واضح الفكرة؟هذه المادة هي
+
+132
+00:12:11,050 --> 00:12:16,650
+2,4-dinitrofluorobenzene يعني لو انا طلعت على هذا
+
+133
+00:12:16,650 --> 00:12:20,850
+المركب الفلورو بنزين واحد اتنين تلاتة اربعة على
+
+134
+00:12:20,850 --> 00:12:25,490
+نمرة اتنين واربعة في عندى dinitrofluorobenzene لما
+
+135
+00:12:25,490 --> 00:12:31,720
+اجى افعله مع ال aminoترمينال لأنه مع الأشياء
+
+136
+00:12:31,720 --> 00:12:35,980
+التانية بتفعلش بتصل مكان ل floor بيحل محل ل floor
+
+137
+00:12:35,980 --> 00:12:41,820
+فلاحظوا هاي ال ال anterminal amino acid صار متصل
+
+138
+00:12:41,820 --> 00:12:48,880
+مع إيش؟ مع المادة الغريبة اللي جيبناها من برا هذه
+
+139
+00:12:48,880 --> 00:12:54,360
+المادة بنسميها Zangari agentهو الـ reagent اللي
+
+140
+00:12:54,360 --> 00:12:58,840
+استعملوه زنجاب الان لما بنيجي بنعمل عملية التكسر
+
+141
+00:12:58,840 --> 00:13:03,940
+كل ال amino acids بيطلعوا على شكل amino acids
+
+142
+00:13:03,940 --> 00:13:11,420
+عادية ما عدت ال unterminal بيطلع ملتصق في ال 2,4
+
+143
+00:13:11,420 --> 00:13:16,740
+-dinitrobenzene فالملتصق بال 2,4-dinitrobenzene ع
+
+144
+00:13:16,740 --> 00:13:21,500
+طول بنقول هذا كان ال unterminal طبعا انتوا تخيلوا
+
+145
+00:13:23,180 --> 00:13:28,660
+إنه لو في عنده ميت أمينو أسد في بيبتايد و لا ألف
+
+146
+00:13:28,660 --> 00:13:33,920
+أمينو أسد في بروتين لناس بدوا يدرجوا في العلم إنه
+
+147
+00:13:33,920 --> 00:13:37,560
+بس يعرفوا مين أول واحد و بعد هيك اتكسر و خلاص
+
+148
+00:13:37,560 --> 00:13:43,020
+بطلنا جادرين نعرف لكن هذا بحد ذاته كان إنجاز في
+
+149
+00:13:43,020 --> 00:13:49,560
+وقته لكن مابكفيش يعني مابحنش الشكلواضح الشكل أني
+
+150
+00:13:49,560 --> 00:13:56,200
+بدي أعرف الألف مرتبين مش بس أعرف مين أول واحد فيهم
+
+151
+00:13:56,200 --> 00:14:03,680
+ولذلك إجت طريقة هذه المعادلة بتهيألي بشكل واضح هاي
+
+152
+00:14:03,680 --> 00:14:06,820
+اللي هو الـ 2,4-dinitrobenzene اللي هو الـ Zangar
+
+153
+00:14:06,820 --> 00:14:16,730
+reagent خلينا هيك نسميه ال Zangar reagentلما احنا
+
+154
+00:14:16,730 --> 00:14:21,650
+فعلنا مع البروتين فقط يتفاعل مع الـ unatched الـ
+
+155
+00:14:21,650 --> 00:14:26,670
+unterminal بيعطينا ده الشكل لما نكسر زي ما اتفقنا
+
+156
+00:14:26,670 --> 00:14:30,390
+فقط الـ unterminal ال amino acid بيكون متحد معاه
+
+157
+00:14:30,390 --> 00:14:36,860
+والباقي بيطلعوا amino acids اديينهذا الكلام بعد
+
+158
+00:14:36,860 --> 00:14:42,980
+ذلك اتطور بطريقة افضل كثير من خلال العالم Edman
+
+159
+00:14:42,980 --> 00:14:49,980
+عمل Edman's reagent الآن ال Edman's reagent الشغل
+
+160
+00:14:49,980 --> 00:14:55,140
+اللي اشتغله اجمل كثير يمكن ايش اللي اشتغله جاب
+
+161
+00:14:55,140 --> 00:15:01,720
+reagent بيجي يتفاعل ايضا مع ال unterminal amino
+
+162
+00:15:01,720 --> 00:15:07,120
+acidتمام خلّينا نفترض هذا ال reagent مرة تانية
+
+163
+00:15:07,120 --> 00:15:15,660
+اللي جابه السيد مين ادمان هيه اتفاعل وصار شابك مع
+
+164
+00:15:15,660 --> 00:15:23,080
+ال unterminal amino acid بعد هيك هذا ال reagent
+
+165
+00:15:23,080 --> 00:15:30,620
+تبعه بيكسر فقط هو ال unterminal amino acidو بيظل
+
+166
+00:15:30,620 --> 00:15:35,960
+باقي ال protein ممسوك، مابتكسرش كله واضح؟ إذ
+
+167
+00:15:35,960 --> 00:15:40,180
+هايدرولز خفيف بس بيكسر هذا مع هذا و بيطلع هذا على
+
+168
+00:15:40,180 --> 00:15:44,540
+شكل إيش حلقة، هنشوف كيف التفاصيل، الآن هذا اللي
+
+169
+00:15:44,540 --> 00:15:49,240
+طلع بنقدر ناخده و نحلله لحاله و نعرفه؟ أه، الآن
+
+170
+00:15:49,240 --> 00:15:55,290
+بنعيد التفاعلبنجيب الـ Edmund's reagent مرة تانية،
+
+171
+00:15:55,290 --> 00:15:59,570
+اذا احنا عرفنا أول واحد، بنعود الفعل الجزء المتبقى
+
+172
+00:15:59,570 --> 00:16:05,950
+مع Edmund's reagent، هيتحد معاه وكسربس ال
+
+173
+00:16:05,950 --> 00:16:10,450
+unterminal اللي عرفنا نمرة اتنين بعد هيك كمان مرة
+
+174
+00:16:10,450 --> 00:16:16,070
+بنعرف نمرة تلاتة لاحظوا تعريف Edman's reagent is a
+
+175
+00:16:16,070 --> 00:16:21,610
+reagent that clips off يعني بيقطع واضح؟ that clips
+
+176
+00:16:21,610 --> 00:16:26,350
+off just one amino acid at a time يعني في كل مرة
+
+177
+00:16:26,350 --> 00:16:31,170
+بتفاعل مع ال amino acid الطرفاني و بيقصه بس بيخلي
+
+178
+00:16:31,170 --> 00:16:35,650
+ايش ال protein مرة تانية تالتة رابعةفي النهاية
+
+179
+00:16:35,650 --> 00:16:43,470
+بنقدر ايش؟ بنعرف الترتيب تبعهم الان بالنسبة لفكرة
+
+180
+00:16:43,470 --> 00:16:49,390
+التفاعل الكيميائي هي في المحصلة فكرة كيميائية مش
+
+181
+00:16:49,390 --> 00:16:53,890
+صعبة كتير ال reagents اللي هو ال Edmans reagent
+
+182
+00:16:53,890 --> 00:17:01,330
+اسمه هين رسمينه بالأحمرفنل ايزو سيانيت ايش اسمه
+
+183
+00:17:01,330 --> 00:17:07,770
+فنل ايزو سيانيت ايش اللي بيميز الفنل ايزو سيانيت
+
+184
+00:17:07,770 --> 00:17:13,610
+هذا لاحظوا هذا الفنل ايزو سيانيت الكاربون تبعته
+
+185
+00:17:13,610 --> 00:17:21,050
+موجود بين ذرتين electronegative كبريتونيتروجين
+
+186
+00:17:21,050 --> 00:17:26,550
+عشان هيك هذه الكاربون is a highly positive carbon
+
+187
+00:17:28,170 --> 00:17:30,550
+هذا الكربون موجبة الكربون الكربون الكربون الكربون
+
+188
+00:17:30,550 --> 00:17:32,070
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+189
+00:17:32,070 --> 00:17:32,150
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+190
+00:17:32,150 --> 00:17:34,610
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+191
+00:17:34,610 --> 00:17:35,090
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+192
+00:17:35,090 --> 00:17:37,050
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+193
+00:17:37,050 --> 00:17:38,850
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+194
+00:17:38,850 --> 00:17:39,070
+الكربون الكربون الكربون الكربون كربون كربون كربون
+
+195
+00:17:39,070 --> 00:17:53,490
+كربون كربون كربون كربون كربون كربون كربون
+
+196
+00:17:54,430 --> 00:17:59,630
+في زوج الالكترونات والكربون بصفتها محصورة بين
+
+197
+00:17:59,630 --> 00:18:05,030
+ذرتين سالبات إذا هي موجبة فلما هذا التفاعل بده يتم
+
+198
+00:18:05,030 --> 00:18:10,730
+بتقدروا تخيلوها إيه هذه هاجمت إجت وين؟ على الكربون
+
+199
+00:18:10,730 --> 00:18:14,890
+اللي هنا هذا زوج الالكترونات بتتحرك بيجي على الان
+
+200
+00:18:14,890 --> 00:18:20,730
+بتصير on minus هذا بتفقد H الان بتكتسبها واضح؟
+
+201
+00:18:20,730 --> 00:18:26,190
+فبصير عند هذا الجزءلاحظوا التفاعل منطقي يعني لو
+
+202
+00:18:26,190 --> 00:18:32,810
+اتطلعتوا كان عندى phenyl NCS وكانت هذه NH2 نقيت
+
+203
+00:18:32,810 --> 00:18:38,010
+التفاعل هذه صارت NH و الـH انتقلت هنا في ذرات
+
+204
+00:18:38,010 --> 00:18:43,530
+اختفت كانت هذه NH2 وكانت هذه phenyl NCS هيوم
+
+205
+00:18:43,530 --> 00:18:50,190
+اتفاعلوا بهذا الشكل الان هذا لو فعلته مع HCl ومية
+
+206
+00:18:52,270 --> 00:19:00,010
+بيكسر بشكل معين ان هذا ال نيتروجين عليها
+
+207
+00:19:00,010 --> 00:19:03,470
+زوج إلكترونات بتهاجم على هذا ال C double bond و
+
+208
+00:19:03,470 --> 00:19:09,290
+بتعمل حلقة و بتكسرالجزء الأول بتطلع ع شكل حلقة الـ
+
+209
+00:19:09,290 --> 00:19:13,410
+C double bond O موجة بسيه وهذا النيتروجين عليه زوج
+
+210
+00:19:13,410 --> 00:19:16,770
+الإلكترونات فبتكسر و بتطلع هذا ع شكل حلقة لاحظوا
+
+211
+00:19:16,770 --> 00:19:22,550
+هنا إيش موجود عندى ال amino acid الأزرق الأول متحد
+
+212
+00:19:22,550 --> 00:19:29,130
+مع ال Edmans reagent الفينيليايزوسيانات وباقى
+
+213
+00:19:29,130 --> 00:19:36,850
+لبروتين زي ما هو فانا لما بفصل هذا بعرفأيش ال
+
+214
+00:19:36,850 --> 00:19:40,330
+amino acid طالما فصلته لحاله مش عملية صعبة الان
+
+215
+00:19:40,330 --> 00:19:44,730
+بعيد الكلام هيفصل ال amino acid اللي بعده مع انفنل
+
+216
+00:19:44,730 --> 00:19:52,940
+NCO كمان مرة كمان مرة بهيك بنقدر ايش نعملنعرف كل
+
+217
+00:19:52,940 --> 00:19:57,580
+ال sequence، بنقدر نعرف كل ال sequence، واضحة
+
+218
+00:19:57,580 --> 00:20:01,340
+الفكرة؟ من خلال ال Edmund's reagent لأنه بياخدهم
+
+219
+00:20:01,340 --> 00:20:05,300
+واحد واحد، الآن طبعا بإمكانكوا تتخيلوا أنتوا أن
+
+220
+00:20:05,300 --> 00:20:08,840
+هذا الكلام بده شخص في المختبر يقعد ويفصل ويشتغل
+
+221
+00:20:08,840 --> 00:20:11,780
+ويفصل ويعود ويعيد التفاعل ويفصل، كل هذا الكلام
+
+222
+00:20:11,780 --> 00:20:16,380
+الآن على أجهزة بنعمل automaticيعني بنحط ل protein
+
+223
+00:20:16,380 --> 00:20:21,320
+و عندنا أجهزة sequencing نفسها automatic بتضيف ال
+
+224
+00:20:21,320 --> 00:20:24,680
+reagent و بتعمل و بتفصل و بتتعرف على الأول بعدين
+
+225
+00:20:24,680 --> 00:20:27,360
+على التاني بعدين على التالت طبعا الدنيا كتير
+
+226
+00:20:27,360 --> 00:20:31,420
+متطورة في هذا المجال واضح؟ يعني مش شغل في المختبر
+
+227
+00:20:31,420 --> 00:20:36,780
+و أقعد فيه أشهر و سنين لأ كل شغل بنشغل automatic
+
+228
+00:20:36,780 --> 00:20:43,990
+بس هذه الفكرة الأساسية تبعته الآن هناما بنقدرش
+
+229
+00:20:43,990 --> 00:20:51,190
+نترك هذه الفكرة إلا نحكي عن نقطة يمكن كثير مهمة
+
+230
+00:20:51,190 --> 00:20:56,750
+مالهاش علاقة في موضوع البروتينات أو يمكن أقول لأ
+
+231
+00:20:56,750 --> 00:21:02,390
+إلها علاقة في موضوع البروتينات ابن عمه بس ابن عمه
+
+232
+00:21:02,390 --> 00:21:09,880
+الصغيرللفنل ايزو ثيو سيانات فنل ايزو ثيو سيانات
+
+233
+00:21:09,880 --> 00:21:14,280
+اللي هو ابن عم صغير ايش هذا ابن عم الصغير مين هو
+
+234
+00:21:14,280 --> 00:21:24,020
+CH3MCOO
+
+235
+00:21:24,020 --> 00:21:31,070
+هد مين بطلع؟ابن عمه الصغير طب لو بدنا نسميه هذه
+
+236
+00:21:31,070 --> 00:21:36,010
+ايزو سيانات هذه ايزو ثايو سيانات اللي فيها اكسجين
+
+237
+00:21:36,010 --> 00:21:41,090
+ايزو سيانات اللي فيها كبريت ايزو ثايو سيانات ثنل
+
+238
+00:21:41,090 --> 00:21:46,570
+ايزو ثايو سيانات مثل ايزو سيانات تعرفنا هذا ايش
+
+239
+00:21:46,570 --> 00:21:58,470
+اسمه مثل ايزو سيانات اذا المثل ايزو سياناتبكون ابن
+
+240
+00:21:58,470 --> 00:22:05,070
+عمه الصغير لمين؟ للفنل ايزوثيو سيانيت لأن جزء
+
+241
+00:22:05,070 --> 00:22:11,350
+الصغير لأن جزء الصغير المثل ايزو سيانيت بكون عبارة
+
+242
+00:22:11,350 --> 00:22:18,310
+عن غاز بكون عبارة عن غاز بتطير
+
+243
+00:22:20,680 --> 00:22:26,440
+هذا الغاز بيستعمله في مصانع المبيدات بيستعمله في
+
+244
+00:22:26,440 --> 00:22:31,880
+مصانع المبيدات الحشرية وغيرها وغيراتها طبعا
+
+245
+00:22:31,880 --> 00:22:40,060
+اتخيلوا لو هذا الغاز اجا على بروتين زي كل الأشياء
+
+246
+00:22:40,060 --> 00:22:44,780
+اللي موجودة في جسم الإنسان وين مصدر قوته لهذا
+
+247
+00:22:44,780 --> 00:22:53,220
+الغاز ال carbon ال carbonالموجبة والبروتينات اللي
+
+248
+00:22:53,220 --> 00:22:58,280
+في جسم الإنسان والجزيئات اللي في الجسم كلها فيها
+
+249
+00:22:58,280 --> 00:23:02,600
+نيتروجين إيش حيصير؟ هتتفاعل هالجزيئات هذه اللي في
+
+250
+00:23:02,600 --> 00:23:07,440
+جسم الإنسان مع هذا على الكاربون الموجبة هي فيها
+
+251
+00:23:07,440 --> 00:23:10,520
+نيتروجين سالبة على الكاربون الموجبة نفس الفكرة
+
+252
+00:23:10,520 --> 00:23:13,800
+نيتروجين سالبة على الكاربون الموجبة مش هذا بروتين
+
+253
+00:23:14,940 --> 00:23:18,640
+صح ولا لا؟ طب و البني آدم مافيش فيه بروتينات؟ فلو
+
+254
+00:23:18,640 --> 00:23:25,780
+بني آدم شم هذا الغاز إيش هيصير؟ هتيجي البروتينات
+
+255
+00:23:25,780 --> 00:23:28,780
+تتفاعل مع هذا، الآن البروتينات عشان البني آدم
+
+256
+00:23:28,780 --> 00:23:32,260
+يستفيد منها لازم تكون بصورتها الطبيعية، بنفع تكون
+
+257
+00:23:32,260 --> 00:23:36,220
+متفاعلة مع أشياء تانية، شو هيصير في البني آدم؟
+
+258
+00:23:38,260 --> 00:23:43,840
+هيموت، هيتسمم، هيتسمم ويموت هذا اللي صار، هذا
+
+259
+00:23:43,840 --> 00:23:50,960
+الكلام بالظبط اللي صار في أكبر كارثة كيميائية تصنف
+
+260
+00:23:50,960 --> 00:23:56,740
+في التاريخ يعني خلال ساعات قليلة، ساعتين، تلاتة
+
+261
+00:23:56,740 --> 00:23:59,160
+قتلت عشرين ألف واحد
+
+262
+00:24:02,240 --> 00:24:10,120
+إنه مصنع للأسف الشديد في الهند حطوه قريب من السكان
+
+263
+00:24:10,120 --> 00:24:16,620
+في منطقة سكانية مزدحمة و المصنع مبيدات حشرية قريب
+
+264
+00:24:16,620 --> 00:24:21,320
+من السكان حطوه جنب أي مدينة في الهند جنب مدينة
+
+265
+00:24:21,320 --> 00:24:22,940
+بوبالي
+
+266
+00:24:24,330 --> 00:24:29,210
+حطوه جنب مدينة بوبال، بوبال مدينة وين موجودة؟ في
+
+267
+00:24:29,210 --> 00:24:37,330
+الهند وصهريش قديمة متآكلة انفجر صهريش، نفس غاز على
+
+268
+00:24:37,330 --> 00:24:38,050
+السكان
+
+269
+00:24:40,620 --> 00:24:45,840
+مات عشرين ألف غير الناس اللي أصيبوا بالعمى و
+
+270
+00:24:45,840 --> 00:24:53,060
+العهات و الأشياء الكثيرة هذا الكلام في يوم تلاتة
+
+271
+00:24:53,060 --> 00:25:00,060
+لأربعة ليلة تلاتة أربعة اتناشر الف تسعمية و تلاتة
+
+272
+00:25:00,060 --> 00:25:07,390
+و تمانية واضح؟ هذه كانت أكبر كارثة كيميائيةولذلك
+
+273
+00:25:07,390 --> 00:25:12,250
+لما بتتطلعوا على الناس الخضر تعون البيئة بيطلعوا
+
+274
+00:25:12,250 --> 00:25:17,810
+بمظاهرات بتلاقوهم دايما حاملين لافتات على أكبر
+
+275
+00:25:17,810 --> 00:25:25,030
+الكوارث اللي حصلت، الكوارث البيئية، تلت لافتات
+
+276
+00:25:25,030 --> 00:25:27,790
+أساسية بتنحمل، شو هي؟
+
+277
+00:25:31,070 --> 00:25:34,890
+لافتة بتلاقي و مكتوب عليها بوبال شو معنى بوبال
+
+278
+00:25:34,890 --> 00:25:42,530
+نفهم لافتة تانية مكتوب عنها Chernobyl المفاعل اللي
+
+279
+00:25:42,530 --> 00:25:47,570
+عمل الكارثة البيئية في أوكرانيا واللافتة التالتة
+
+280
+00:25:47,570 --> 00:25:53,710
+مكتوب عليها نجازاكي وهيروشيما اه مين اللي عمل
+
+281
+00:25:53,710 --> 00:25:58,390
+نجازاكي وهيروشيما remember it
+
+282
+00:26:01,560 --> 00:26:08,900
+واضح؟ هذه أشهر الكوارث البيئية نجزاكي
+
+283
+00:26:08,900 --> 00:26:15,560
+وهيروشيما هذه كارثة صناعة متعمدة كارثة صناعة
+
+284
+00:26:15,560 --> 00:26:24,180
+متعمدة إبادة مدن كاملة يعني يمكن بوبال و تشيرنوبل
+
+285
+00:26:24,180 --> 00:26:30,340
+يصنفوا عليها كوارث إحمادلكن نجازاكي و هيروشيما هي
+
+286
+00:26:30,340 --> 00:26:37,100
+جرائم حرب جرائم حرب كاملة شوفتوا الجزيئات الصغيرة
+
+287
+00:26:37,100 --> 00:26:41,940
+كيف بتعملوا الأفكار العلمية كيف متصلة ببعض هالبعض
+
+288
+00:26:41,940 --> 00:26:48,000
+زي ما البروتين بتتحد على الكربونة تبعت الفينل ايزو
+
+289
+00:26:48,000 --> 00:26:52,960
+سيانيت البروتين تبع البني آدم اتحد على كربونة
+
+290
+00:26:52,960 --> 00:26:56,280
+الميثل ايزو سيانيت بس المشكلة ان الميثل ايزو
+
+291
+00:26:56,280 --> 00:27:05,970
+سيانيتغاز انتشر في الأجواء بسهولة ولذلك آذى ناس
+
+292
+00:27:05,970 --> 00:27:11,950
+كتير الفينال ايزوسيانيت سائل يعني بيضل فى منطقة
+
+293
+00:27:11,950 --> 00:27:16,430
+المختبر فى خزانة أبخرة بعمل التفاعل بتحكم فيه لكن
+
+294
+00:27:16,430 --> 00:27:22,270
+الميثل ايزوسيانيت غاز والغاز ايش بيعمل؟ بنتشر
+
+295
+00:27:22,270 --> 00:27:24,810
+بنتشر فى كل المختبر
+
+296
+00:27:26,680 --> 00:27:34,540
+الان بيجينا كمان شغلة مساعدة .. شغلة مساعدة لتحديد
+
+297
+00:27:34,540 --> 00:27:38,360
+ال sequence هذه الشغلة Eclavage of Selected
+
+298
+00:27:38,360 --> 00:27:43,100
+Peptide Bonds انه انا لما يكون عندى بروتيل كبير
+
+299
+00:27:43,100 --> 00:27:48,860
+ممكن البروتيل الكبير هذا اجسمه لاربع خمس قطع وكل
+
+300
+00:27:48,860 --> 00:27:53,960
+قطعة اقعد احلي لو بعدين بجمع المجموع تبعهم واضح؟
+
+301
+00:27:54,420 --> 00:27:59,940
+يعني اتخيلوا مرة تانية ان هاي عندى نفترض بيبتايد
+
+302
+00:27:59,940 --> 00:28:04,980
+كبير لو انا اعملت القاتل اجيت اعملته مثلا قطعتين
+
+303
+00:28:04,980 --> 00:28:11,840
+وعرفتهم كسرتهم من مكان معين واضح؟ الآن بعد هيك
+
+304
+00:28:11,840 --> 00:28:15,020
+بحدد هذه ال sequence الأولى بحدد ال sequence
+
+305
+00:28:15,020 --> 00:28:19,760
+التانية بجمعهم بطلع إيش كل ال بيبتايد الفكرة بصير
+
+306
+00:28:19,760 --> 00:28:24,460
+أنه بدي أنزين معين يكسروا من مكان معينفي عند
+
+307
+00:28:24,460 --> 00:28:27,720
+انزيمات كل واحد فيها متخصص يكسر من مكان معين
+
+308
+00:28:27,720 --> 00:28:32,120
+هيتخيلوا انه في انزيم بيكون بيكسر من عند الأزراج
+
+309
+00:28:32,120 --> 00:28:38,200
+مع الأسود في هذه الحالة وين في أزراج مع أسود بس
+
+310
+00:28:38,200 --> 00:28:42,840
+هان بيكسروا من هان واضح؟ كذلك الحال في الانزيمات
+
+311
+00:28:42,840 --> 00:28:49,950
+اللي في الجسم يعني مثلا لتربسين لتربسينبيكسر من
+
+312
+00:28:49,950 --> 00:28:54,750
+عند الـ Carboxyl side of Lysine and Arginine من
+
+313
+00:28:54,750 --> 00:28:58,510
+عند الـ Carboxyl side يعني السيطرة بالـ Bond O تبع
+
+314
+00:28:58,510 --> 00:29:03,750
+الـ Lysine و الـ Arginine الـ Chemotrypsin بيكسر
+
+315
+00:29:03,750 --> 00:29:07,050
+من الـ Carboxyl side للفنلالانين والتيروسين
+
+316
+00:29:07,050 --> 00:29:09,270
+والتريبتوفان
+
+317
+00:29:10,090 --> 00:29:13,830
+السيانوجين برومايد بيكسر من الكربوكس الصيد
+
+318
+00:29:13,830 --> 00:29:19,350
+للميثيونين الكربوكس بيبتدز بيكسر من ال C-terminal
+
+319
+00:29:19,350 --> 00:29:25,930
+بيكسر ال C-terminal amino acid يعني بيطلع له آخر
+
+320
+00:29:25,930 --> 00:29:33,210
+واحد واضح؟ وبناء على ذلك لو احنا مثلا بدنا نيجي
+
+321
+00:29:33,210 --> 00:29:40,220
+نطلع هنا على مثال هاي في عندناببتايد مكوّن من عدة
+
+322
+00:29:40,220 --> 00:29:44,260
+amino acid طبعا دائما بتكون تتخيلوا أنه في ال
+
+323
+00:29:44,260 --> 00:29:49,360
+amino acid هذا الأن terminal وهنا ال C terminal
+
+324
+00:29:51,060 --> 00:29:56,400
+واضح؟ يعني كل amino acid مش بيبين الجزء تبعه N H C
+
+325
+00:29:56,400 --> 00:30:03,680
+H A C double bond O و متحد اذا هذا اللي على الشمال
+
+326
+00:30:03,680 --> 00:30:10,750
+ال N terminal هذا اللي على اليمينالـ C Terminal و
+
+327
+00:30:10,750 --> 00:30:13,930
+هكذا الـ Amino Acid اللي بعده و اللي بعده فلو احنا
+
+328
+00:30:13,930 --> 00:30:18,750
+اتينا و اتطلعنا على هذا ال Amino Acid Alanine,
+
+329
+00:30:18,830 --> 00:30:22,410
+Glycine, Tyrosine, Tryptophan, Serine, Glycine إلى
+
+330
+00:30:22,410 --> 00:30:26,630
+اخرها و اتينا و قلنا بدنا نشوف كيف تكسر مثلا مع
+
+331
+00:30:26,630 --> 00:30:31,130
+الـ Trypsin مع الـ Chemotrypsin مع الـ Cyanogen
+
+332
+00:30:31,130 --> 00:30:41,560
+Bromideيمكن المدى طيب لو اجينا ل .. لتربسيل من وين
+
+333
+00:30:41,560 --> 00:30:49,020
+بيكسل ال lycine نكتبهم هنا و ال arginine lycine و
+
+334
+00:30:49,020 --> 00:30:55,360
+arginine من عند ..الكاربوكسل سايد فانا الآن لو
+
+335
+00:30:55,360 --> 00:30:59,200
+اجيت اطلعت وين في عندي ليسين و وين في عندي أرغنين
+
+336
+00:30:59,200 --> 00:31:03,320
+الانينيجليسين تايروسين تريبتوفانسيرين ليسين هي
+
+337
+00:31:03,320 --> 00:31:12,520
+ليسين الان ايش له ليسين N و C هو بيكسر من وين اذا
+
+338
+00:31:12,520 --> 00:31:19,120
+هى ناتج تكسر له هيجيب لهذه القطة على وحدها وهذه
+
+339
+00:31:19,120 --> 00:31:24,460
+القطة على وحدهاواضح؟ فهتشوفوا الجزء الأول اللي هو
+
+340
+00:31:24,460 --> 00:31:27,520
+لحد اللايسين والجزء التاني اللايسين اليوسين
+
+341
+00:31:27,520 --> 00:31:33,480
+ميثيون، واضحة الفكرة؟ طيب ليش بيتنا مكسرة من
+
+342
+00:31:33,480 --> 00:31:37,450
+البروتين؟ يعني إيش الناس؟الان هذا التفصيل مش
+
+343
+00:31:37,450 --> 00:31:42,390
+موضوعنا يعني هذه انزيمات ربنا خلقها specific لغرض
+
+344
+00:31:42,390 --> 00:31:46,990
+معين انا ماعنديش فكرة اكثر انه ليش هذه الانتقائية
+
+345
+00:31:46,990 --> 00:31:52,650
+سؤالي تحديدا ليش هذه الانتقائية تمام ترجع ايش هو
+
+346
+00:31:52,650 --> 00:31:56,910
+شكل الانزيم وكيف الروابط بتكون متناسبة مع بعض انها
+
+347
+00:31:56,910 --> 00:32:00,990
+تكسر مش هي الموضوع احنا بناخد نتيجة الان كنتيجة
+
+348
+00:32:02,350 --> 00:32:08,230
+مثبتة لـ Trypsin من وين بيكسر من هذه النقطة الان
+
+349
+00:32:08,230 --> 00:32:11,290
+احنا
+
+350
+00:32:11,290 --> 00:32:16,070
+متفقين معاكم متفقين معاكم و احنا بنحكي ما تسألونيش
+
+351
+00:32:16,070 --> 00:32:22,290
+شو تحفظه للامتحان واضح؟ افهمتوا الفكرة العامة هان؟
+
+352
+00:32:22,290 --> 00:32:27,360
+هي فكرة تجزئة للمساعدة في عمل إيش؟الـ sequence
+
+353
+00:32:27,360 --> 00:32:31,260
+الان في النهاية صرنا جادرين نقرا في ال sequences
+
+354
+00:32:31,260 --> 00:32:36,340
+ولا لأ بالتأكيد الان الناس اللي عملوا زي هيك جدروا
+
+355
+00:32:36,340 --> 00:32:42,460
+انهم يحددوا بعض الأشكال يعني على سبيل المثال هذا
+
+356
+00:32:42,460 --> 00:32:49,400
+الانسولين حددوا الشكل تبعه هو عبارة عن سلسلتين
+
+357
+00:32:49,400 --> 00:32:52,980
+هيوم متحدين و في مناطق معينة لما بيجي
+
+358
+00:32:56,210 --> 00:33:01,570
+60×60 سواء بيشبكوا السلسلتين ببعض أو بيعملوا حتى
+
+359
+00:33:01,570 --> 00:33:06,210
+ارتباط داخل يعني لاحظوا هذا 60×60 في نفس السلسلة
+
+360
+00:33:06,210 --> 00:33:12,830
+هذه عملوا die sulfide bond او او لو اجت 60×60 ببعض
+
+361
+00:33:12,830 --> 00:33:17,150
+برضه بيعملوا die sulfide bond الان هذا بيصير
+
+362
+00:33:17,150 --> 00:33:20,930
+السلسلتين اللي من 20 امينواسد و من 30 امينواسد
+
+363
+00:33:20,930 --> 00:33:24,370
+الشكل تبع ايش الانسونات
+
+364
+00:33:25,780 --> 00:33:32,000
+هذا اتكلمنا عنه المرة الماضية شكل الأوكزي توسين كل
+
+365
+00:33:32,000 --> 00:33:36,240
+هذا الكلام نتيجة تطور بهالعلم مابدناش ننسى شغله ان
+
+366
+00:33:36,240 --> 00:33:41,600
+انتوا الآن بتاخدوا مقدمة بسيطة جدا اللي بده بعد
+
+367
+00:33:41,600 --> 00:33:45,920
+هيك يشتغل بهذا الكلام بده ياخد biochemistry one و
+
+368
+00:33:45,920 --> 00:33:49,040
+two و three و analytical methods يتخصص
+
+369
+00:33:49,040 --> 00:33:55,090
+biochemistry ممكن البعض فيكمالان يبدأ يحب هذه
+
+370
+00:33:55,090 --> 00:34:00,330
+المنطقة و بالتالي يطلب انه يتخصص biochemistry و ال
+
+371
+00:34:00,330 --> 00:34:07,930
+biochemistry بالمناسبة من التخصصات العجيبة ليش؟
+
+372
+00:34:07,930 --> 00:34:12,930
+انتبهوا معي لأن ال biochemistry ابتبنى على عدة
+
+373
+00:34:12,930 --> 00:34:15,990
+تخصصات يعني عادة ال chemistry اللى بده يعمل
+
+374
+00:34:15,990 --> 00:34:20,730
+ماجستير و دكتوراه في الكيميا لازم يكون مخلص كيميا
+
+375
+00:34:21,740 --> 00:34:25,080
+بيعمل ماجستير ودكتوراه في الكيميا الآن ال
+
+376
+00:34:25,080 --> 00:34:31,360
+biochemistry لأ خريج biology بيكمل biochemistry
+
+377
+00:34:31,360 --> 00:34:36,740
+خريج زراعة بيكمل biochemistry خريج تحاليل طبية
+
+378
+00:34:36,740 --> 00:34:39,800
+بيكمل biochemistry وفي جزء في التحاليل الطبية
+
+379
+00:34:39,800 --> 00:34:44,620
+biochemistry طبيب بيكمل biochemistry وفي جزء في
+
+380
+00:34:44,620 --> 00:34:49,810
+الطب biochemistry واضح؟كل هدولة ممكن انهم يكملوا
+
+381
+00:34:49,810 --> 00:34:52,770
+biochemistry عشانك حتى لو بتتطلعوا على الدكاترة
+
+382
+00:34:52,770 --> 00:34:55,610
+اللي عندهم biochemistry نفترض في الجامعة او في
+
+383
+00:34:55,610 --> 00:34:59,350
+الجامعات بشكل عام هتلاقوا ان فلان اصلا طبيب فلان
+
+384
+00:34:59,350 --> 00:35:04,170
+زراعة فلان تحاليل طبية الآن خلينا نقول ربع اللي
+
+385
+00:35:04,170 --> 00:35:09,260
+بيعملوا masterتحاليل طبية هم حقيقة بيكملوا
+
+386
+00:35:09,260 --> 00:35:13,060
+biochemistry جزء تاني بيروح بيكمل hematology او
+
+387
+00:35:13,060 --> 00:35:18,040
+microbiology واضح الفكرة فال biochemistry بتبنى
+
+388
+00:35:18,040 --> 00:35:23,560
+على اكتر من تخصص biology chemistry biochemistry
+
+389
+00:35:23,560 --> 00:35:30,200
+biotechnologyزراعة طب طب بيطري كله بيكمل ال
+
+390
+00:35:30,200 --> 00:35:34,780
+biochemistry و كلهم يعني بيشتغلوا في مجالات اللي
+
+391
+00:35:34,780 --> 00:35:37,900
+لها علاقة في ال biochemistry لأن هو في النهاية علم
+
+392
+00:35:37,900 --> 00:35:44,480
+واسع يعني علم إيش علم الحياة الآن بنيجي لل
+
+393
+00:35:44,480 --> 00:35:48,440
+secondary structure of proteins احنا الآن عرفنا ال
+
+394
+00:35:48,440 --> 00:35:54,760
+sequence ال sequence شو هي amino acidsمختلفة
+
+395
+00:35:54,760 --> 00:36:01,520
+متتالية لازم نعرفها هاي عملنا sequence
+
+396
+00:36:01,520 --> 00:36:07,440
+هذا peptideبتطلع عليه اعمله له sequence إجليسين
+
+397
+00:36:07,440 --> 00:36:12,160
+ألانين تيروسين كذا كذا كذا اعمله و خلصنا معرفة
+
+398
+00:36:12,160 --> 00:36:15,980
+الترتيب هو اللي بنسمي احنا ايش ال primary
+
+399
+00:36:15,980 --> 00:36:19,400
+structure اذا ال primary structure هو معرفة ال
+
+400
+00:36:19,400 --> 00:36:24,120
+sequence خلصنا منه الآن بعد هيك هذا كيف بده يصير
+
+401
+00:36:24,120 --> 00:36:28,180
+في الدنيا بده يظله على شكل خط ولا بده ياخد أشكال
+
+402
+00:36:28,180 --> 00:36:35,920
+تانيةهذا بيعمل نفسه بأشكال تانية منها ال secondary
+
+403
+00:36:35,920 --> 00:36:40,760
+structure of proteins في ال secondary structure of
+
+404
+00:36:40,760 --> 00:36:47,580
+protein هذا ممكن ياخد شكل ال helix و ممكن ياخد شكل
+
+405
+00:36:47,580 --> 00:36:52,920
+ال bladed sheath زي الدرج يا بيعمل حاله زي ال
+
+406
+00:36:52,920 --> 00:36:57,690
+helix تطلعوا كيف ال helix هيك بده يلف حالهHelix أو
+
+407
+00:36:57,690 --> 00:37:02,950
+زي الدرج يعني هيك طالع نازل طالع نازل واضح؟ هي
+
+408
+00:37:02,950 --> 00:37:07,630
+كأنه هي القاعدة هيك زي الدرج واضح؟ بنسميه إيش؟
+
+409
+00:37:07,630 --> 00:37:14,610
+Ablated Sheet الآن ال helix نوعان إيش ماله ال
+
+410
+00:37:14,610 --> 00:37:19,410
+helix؟ نقوة ولا نوعين؟ Alpha و Beta مروا عليكم
+
+411
+00:37:19,410 --> 00:37:24,430
+وين؟في الأحياء تعرفوا تعملوهم في البيت لو قلنا
+
+412
+00:37:24,430 --> 00:37:30,850
+لكوا يعملوا Alpha و Beta كيف؟
+
+413
+00:37:30,850 --> 00:37:37,030
+الآن هاي هدولة ال helixات لو أعطيتكوا إياهم مين
+
+414
+00:37:37,030 --> 00:37:41,770
+بده يعرف لمين ال Alpha ومين ال Beta اللي الدوران
+
+415
+00:37:41,770 --> 00:37:45,870
+تبعه إذا مشيت فيه مع أقارب الساعة بنسميه Alpha
+
+416
+00:37:45,870 --> 00:37:50,390
+helix اتطلعوا معاه هيك اتطلعوا كيف أنا بمشي
+
+417
+00:37:53,580 --> 00:37:59,700
+لاحظين كيف الدوران مع أقارب الساعة طبعا لو جلبته
+
+418
+00:37:59,700 --> 00:38:05,100
+برضه هيظل مع أقارب الساعة من أي شكل الآن لو مسكت
+
+419
+00:38:05,100 --> 00:38:13,620
+ال helix التاني طلعوا عكس أقارب الساعة هذا اللي مع
+
+420
+00:38:13,620 --> 00:38:18,380
+أقارب الساعة Alpha helix العكس أقارب الساعة Beta
+
+421
+00:38:18,380 --> 00:38:25,100
+helix واضح؟ الآن كيف بيكونوا موجودينالـ Amino
+
+422
+00:38:25,100 --> 00:38:31,280
+Acids لما بيلفوا على شكل Alpha Helix واضح؟ طبعا
+
+423
+00:38:31,280 --> 00:38:37,280
+أول ما بنقول Alpha Helix هنتواجه بمشكلة تقولولي
+
+424
+00:38:37,280 --> 00:38:42,420
+هاي زي حبل هالتليفون هذا واضح؟ فهذا شكله إيش حبل
+
+425
+00:38:42,420 --> 00:38:48,100
+التليفون Beta Helix المهم الآن ليش؟ لأنه انا لو
+
+426
+00:38:48,100 --> 00:38:52,240
+مسكت هاي ال Primary Structure وإجيت بدي أعمل و
+
+427
+00:38:52,240 --> 00:38:57,850
+ألفه Alpha Helixلاحظوا إيش اللي قاعد يصير؟ كل ما
+
+428
+00:38:57,850 --> 00:39:03,410
+بعمله بيوجع فوق بعضه جادر أنا الأن أعمله Alpha
+
+429
+00:39:03,410 --> 00:39:08,350
+Helix؟ طب إيش اللي بيثبته أنه يصير على شكل Alpha
+
+430
+00:39:08,350 --> 00:39:15,230
+Helix؟ أنه هنا بتيجي بين هذه و هذه و هذه و هذه و
+
+431
+00:39:15,230 --> 00:39:19,910
+هذه روابط هيدروجينية و disulfide bonds لو هذه
+
+432
+00:39:19,910 --> 00:39:25,120
+اتكسرت كله بيجي على بعضهواضح الفكرة؟ إذا اللي
+
+433
+00:39:25,120 --> 00:39:30,980
+بيثبت .. اللي بيثبت الشكل على شكل الـ Alpha Helix
+
+434
+00:39:30,980 --> 00:39:35,580
+هي حقيقة الروابط الهيدروجينية و الـ disulfide
+
+435
+00:39:35,580 --> 00:39:39,560
+bonds هتقولولي من وين الروابط الهيدروجينية؟ سهل مش
+
+436
+00:39:39,560 --> 00:39:44,420
+انتوا في عندكوا أماكن فيها C double bond O و أماكن
+
+437
+00:39:44,420 --> 00:39:51,600
+فيها N H في اللفات الآن لما هدولة بينوجدواالـ N H
+
+438
+00:39:51,600 --> 00:39:55,840
+مع الـ C double bond O شو بيعمله؟ الـ hydrogen
+
+439
+00:39:55,840 --> 00:40:00,460
+bonding فالـ hydrogen bonding هو حقيقة المثبت الـ
+
+440
+00:40:00,460 --> 00:40:05,260
+alpha helix واضح؟ هاي مثلا هنا إذا بتيجوا بتطلعوا
+
+441
+00:40:05,260 --> 00:40:08,720
+هاي C double bond O إحنا متعودين دائما اتفقنا
+
+442
+00:40:08,720 --> 00:40:13,140
+معاكم في الكيميا حتى عشان يفهموا الناس ع بعض إيش
+
+443
+00:40:13,140 --> 00:40:20,310
+بيعملوا؟ لما بيرسموا الـ Oxygen بيرسموه أحمرفي
+
+444
+00:40:20,310 --> 00:40:23,470
+الرسمات في ال molecular structures صار standard
+
+445
+00:40:23,470 --> 00:40:27,830
+يفهموا الكيميائين على بعض ال nitrogen ال oxygen
+
+446
+00:40:27,830 --> 00:40:34,330
+أحمر و ال nitrogen أزرق يعني لما تشوفوا ذره زرقه
+
+447
+00:40:34,330 --> 00:40:41,910
+قولوا هذه إيش نيتروجين و حمرة هذه oxygen الآن اللي
+
+448
+00:40:41,910 --> 00:40:45,770
+بتكون نوعا ما grey هيك سكنه و صغيرة هذه ال
+
+449
+00:40:45,770 --> 00:40:51,210
+hydrogen هي أنا فيه hydrogen إذاالخلاصة هي الشكل
+
+450
+00:40:51,210 --> 00:40:57,510
+هي Oxygen وهي نيتروجين وهي بينهم إيش ال hydrogen
+
+451
+00:40:57,510 --> 00:41:03,550
+bonding هي بينهم ال hydrogen bonding اللي هي بتكون
+
+452
+00:41:03,550 --> 00:41:12,070
+عادة ما بين ال Oxygen وهذه اللي ضعيفة هذه رابط
+
+453
+00:41:12,070 --> 00:41:17,240
+أصلية اللي مع ال nitrogen لأنه أساسا هي N Hفالـ
+
+454
+00:41:17,240 --> 00:41:25,640
+hydrogen bonding وينها؟ OH هذه الروابط بالاضافة لـ
+
+455
+00:41:25,640 --> 00:41:31,380
+disulfide bonds هم اللي بيعملولي إيش؟ الشكل الـ
+
+456
+00:41:31,380 --> 00:41:34,480
+alpha helix الآن لاحظوا هذا ال alpha helix درسينه
+
+457
+00:41:34,480 --> 00:41:39,200
+كويس يعني كل turn فيه عارفين إيش يعني turn؟ يعني
+
+458
+00:41:39,200 --> 00:41:44,250
+لو جيت من هذه النقطة لهذه النقطة لفة كاملةاسمها
+
+459
+00:41:44,250 --> 00:41:49,170
+ايش تيرن كل تيرن فيها تلاتة وستة من عشرة amino
+
+460
+00:41:49,170 --> 00:41:54,390
+acids يمكن البعض يقول طب ما هم ال amino acids مش
+
+461
+00:41:54,390 --> 00:41:59,610
+متساويات كيف بالظبط كل تيرن جد التانية مية في
+
+462
+00:41:59,610 --> 00:42:08,410
+المية مين تعطيني تفسير لأ
+
+463
+00:42:08,410 --> 00:42:11,410
+ليش كل تيرن جد التانية
+
+464
+00:42:14,220 --> 00:42:19,640
+رغم انه انا مابحكيش .. انا مابحكيش عن amino acid
+
+465
+00:42:19,640 --> 00:42:26,400
+واحد polymer عامل to the N واضحة الفكرة؟ انا بحكي
+
+466
+00:42:26,400 --> 00:42:29,420
+عن different .. different amino acids يعني هدولة
+
+467
+00:42:29,420 --> 00:42:33,340
+التلاتة وستة من عشرة ممكن يكونوا alanine، glycine،
+
+468
+00:42:33,340 --> 00:42:37,440
+tryptophan التلاتة وستة مع جزء من اللي بعده ممكن
+
+469
+00:42:37,440 --> 00:42:43,340
+يكونوا valine، كذا كذا لكن كل turn جدت تانية، ليش؟
+
+470
+00:42:57,750 --> 00:43:03,530
+أه اتفقنا احنا انه لما بنكون ال peptide في عندى
+
+471
+00:43:03,530 --> 00:43:11,450
+جزء ثابت الجزء الثابت الجزء الثابت اللي هو ايش N C
+
+472
+00:43:11,450 --> 00:43:19,700
+C double bond Oوكمان N C C double bond O ال R هذه
+
+473
+00:43:19,700 --> 00:43:25,540
+انها تكون مثلا H انها تكون CH3 طال على برا فهذا
+
+474
+00:43:25,540 --> 00:43:30,940
+الجزء الثابت في الهيكل ثابت N C C double bond O
+
+475
+00:43:30,940 --> 00:43:35,020
+فكأنه عندي تلاتة وستة من عشرة N C C double bond O
+
+476
+00:43:35,020 --> 00:43:42,480
+ال R طال على برا مش داخلة في السلسلة واضح ال R
+
+477
+00:43:43,570 --> 00:43:49,610
+طالعة للخارج لكن المتكرر تلاتة و ستة من عشرة من
+
+478
+00:43:49,610 --> 00:43:55,370
+وحدة ال NCC double bond واضح الفكرة؟ و هدولة
+
+479
+00:43:55,370 --> 00:43:59,890
+معروفة طولهم كمان خمسة و أربعة من عشرة أنجستروم
+
+480
+00:43:59,890 --> 00:44:04,450
+بير تيرن يعني كل لفة خمسة و أربعة من عشرة أنجستروم
+
+481
+00:44:04,450 --> 00:44:10,170
+زي ما انتوا ملاحظين انه يعني ال alpha helix محدد
+
+482
+00:44:10,170 --> 00:44:16,780
+تماما و واضحعند الناس اللي بيشتغلوا فيه الان
+
+483
+00:44:16,780 --> 00:44:22,400
+الاحتمال التاني انه ممكن يكونوا ايش بـlated sheet
+
+484
+00:44:22,400 --> 00:44:28,260
+زي الدرج بهذا الشكل و ايضا محددين و بتمسكوا
+
+485
+00:44:28,260 --> 00:44:33,100
+بـhydrogen bonding و لاحظوا لما بيكونوا زي الدرج
+
+486
+00:44:33,100 --> 00:44:38,640
+بيكونوا سلسلتين اقبال بعض و بيشبكوا بـhydrogen
+
+487
+00:44:38,640 --> 00:44:44,690
+bonding اذا ال secondary structure لبروتينيا إما
+
+488
+00:44:44,690 --> 00:44:50,230
+Alpha Helix أو Pleated Sheet الآن اعرفنا ال
+
+489
+00:44:50,230 --> 00:44:54,250
+secondary structure نيجي على ال tertiary structure
+
+490
+00:44:54,250 --> 00:44:57,990
+قولنا Alpha Helix هي Alpha Helix يا ترها ال Alpha
+
+491
+00:44:57,990 --> 00:45:04,190
+Helix هذا كيف بيكون موجود هي هيك Alpha Helix ولا
+
+492
+00:45:04,190 --> 00:45:12,310
+لأ طب و هيك Alpha Helix ولا لأ يعني ببساطة اتخيلوا
+
+493
+00:45:12,310 --> 00:45:20,630
+الحياةعارفين الحياة؟ الصعبان الصعبان لما بيكون هيك
+
+494
+00:45:20,630 --> 00:45:28,490
+عدل بتخافوا منه ولا لأ طب و لما يكون ملف في حاله و
+
+495
+00:45:28,490 --> 00:45:34,190
+مكور هذا صعبان وهذا صعبان و في الحالتين بتخافوا
+
+496
+00:45:34,190 --> 00:45:38,530
+منه الآن ال alpha helix نفس الفكرة يا إما بيكون
+
+497
+00:45:38,530 --> 00:45:46,080
+مكور حاله بنقول عنه globular كراويأو بيكون بهذا
+
+498
+00:45:46,080 --> 00:45:52,640
+الشكل بنقول عنه fibrous خيطي واضح؟ فبعد ما انا
+
+499
+00:45:52,640 --> 00:45:56,220
+عملت ال alpha helix هل يا ترى ال alpha helix بيكون
+
+500
+00:45:56,220 --> 00:46:03,520
+زي الحيا العدلة ولا اللي في الشتاء امكورة حالها؟
+
+501
+00:46:03,520 --> 00:46:07,360
+اذا بيصير عندى ال tertiary structure ان بعد ما انا
+
+502
+00:46:07,360 --> 00:46:13,960
+عرفت ال sequence ال primary اعملت helixsecondary
+
+503
+00:46:13,960 --> 00:46:20,040
+الان هذا ال helix يكون كراوي ولا خيطي هذا ايش بقول
+
+504
+00:46:20,040 --> 00:46:24,040
+عنه ال tertiary structure فعيصير عند ال tertiary
+
+505
+00:46:24,040 --> 00:46:28,920
+structure لل proteins is either fibrous or
+
+506
+00:46:28,920 --> 00:46:34,140
+globular نفس ال alpha helix بعد ما صار alpha helix
+
+507
+00:46:34,140 --> 00:46:38,620
+تخيلوه ببساطة زي حبل التليفون مكور على بعض ولا زي
+
+508
+00:46:38,620 --> 00:46:45,800
+الخيطfibrous or globular طبعا حسب نوع البروتينات
+
+509
+00:46:45,800 --> 00:46:51,920
+لاحظوا الفيبروس بيكونه water insoluble هي
+
+510
+00:46:51,920 --> 00:46:56,820
+البروتينات اللتي لا تدوب في الماء من أمثلتها
+
+511
+00:46:56,820 --> 00:47:03,620
+الكريتينز اللي هي ال protective tissues ال hair ال
+
+512
+00:47:03,620 --> 00:47:08,190
+nailsالـ Collagens اللي هي الـ connective tissues
+
+513
+00:47:08,190 --> 00:47:12,130
+لـ blood vessels الأوعية الدموية لاحظوا سبحان الله
+
+514
+00:47:12,130 --> 00:47:16,790
+كيف الـ Hemoglobin بروتين و الوعاء الدموي بروتين
+
+515
+00:47:16,790 --> 00:47:21,830
+الآن و بيمشي فيهم ميه ال Hemoglobin بدوب في الميه
+
+516
+00:47:21,830 --> 00:47:26,710
+الوعاء الدموي من يوم الإنسان ينولد لحد ما يموت و
+
+517
+00:47:26,710 --> 00:47:34,130
+الميه ماشية في قلبه و بيدوبش ماشي الدموسط ماء؟ من
+
+518
+00:47:34,130 --> 00:47:37,830
+يوم ما الإنسان ينولد لحد ما الإنسان يموت والدم
+
+519
+00:47:37,830 --> 00:47:42,510
+ماشي وهو الوعاء الدموي مش عماله إيش يدوب إذا
+
+520
+00:47:42,510 --> 00:47:46,030
+الوعاء الدموي ال blood vessel water soluble ولا
+
+521
+00:47:46,030 --> 00:47:52,150
+insoluble هذا من نوع إيش ال fibrous proteins بينما
+
+522
+00:47:52,150 --> 00:47:57,510
+ال hemoglobin مثلا globular protein water soluble
+
+523
+00:47:57,510 --> 00:48:03,230
+بيمشي مع ال إيش؟ مع الدمزي ال enzymes ال hormones
+
+524
+00:48:03,230 --> 00:48:07,770
+ل transport proteins storage proteins الآن هدول
+
+525
+00:48:07,770 --> 00:48:13,550
+ايش اللي بيميزهم في انه في الشكل الكراوي هذا بتكون
+
+526
+00:48:13,550 --> 00:48:17,790
+ال polar are groups outside يعني هذا لما بيعمل كرة
+
+527
+00:48:17,790 --> 00:48:23,490
+تمام مش في انا عندي are groups في ال globular هذي
+
+528
+00:48:23,490 --> 00:48:28,390
+ال are groups ال polar للخارج فلما تيجي مية polar
+
+529
+00:48:30,110 --> 00:48:34,570
+والميّه بولر Like Dissolve، Dissolves Like، اذا
+
+530
+00:48:34,570 --> 00:48:37,730
+صاروا بيدوبوا في الميّه، صاروا ايش بيعملوا؟
+
+531
+00:48:37,730 --> 00:48:42,270
+بيدوبوا في الميّه، بينما في ال fibrous ال water ..
+
+532
+00:48:42,270 --> 00:48:47,070
+ال boiler للداخل،
+
+533
+00:48:47,070 --> 00:48:51,850
+بناء على ذلك هييجي الشكل العام يلاقي ميّه بولر لكن
+
+534
+00:48:51,850 --> 00:48:58,050
+هيتواجه ال non-polar groupsالان لاحظوا كيف جثة ال
+
+535
+00:48:58,050 --> 00:49:03,470
+polarity بتفرج لل texture بتخلي واحد كروي و يدوب
+
+536
+00:49:03,470 --> 00:49:10,130
+في الميه و يمشي و التاني يكون fibrous و water
+
+537
+00:49:10,130 --> 00:49:13,790
+insoluble فال hemoglobin بروتيل و الوعاء الدوموي
+
+538
+00:49:13,790 --> 00:49:18,630
+بروتيل ال hemoglobin دايم و الوعاء الدوموي مش دايم
+
+539
+00:49:18,630 --> 00:49:25,730
+الشعر و الأضافر و الجلدما بدوبوش ولا كان البني آدم
+
+540
+00:49:25,730 --> 00:49:34,650
+كل ما بتغسل بتلاشى اه ملاحظين هذا اذا احنا اللي
+
+541
+00:49:34,650 --> 00:49:38,630
+بنسمي ال tertiary structure of proteins is either
+
+542
+00:49:38,630 --> 00:49:45,650
+globular or fibrous بيجينا اخر شغلةطبعا و انا ما
+
+543
+00:49:45,650 --> 00:49:50,150
+اعطيكم نقطة بسيطة انه لو اتطلعتوا انتوا حتى على
+
+544
+00:49:50,150 --> 00:49:53,650
+الحبل اللي معي عشان هذا يصير يعمل كرة عشان هذا
+
+545
+00:49:53,650 --> 00:49:58,850
+يصير يعمل كرة بدوا يتن من اماكن معينة اتطلعوا هاي
+
+546
+00:49:58,850 --> 00:50:03,230
+من هذا المكان بيعمل turn من هذا المكان بيعمل turn
+
+547
+00:50:03,230 --> 00:50:08,290
+تاني من هنا بيعمل turn ثالث من اي نقطة تحديدا بيتن
+
+548
+00:50:09,810 --> 00:50:13,410
+واضح؟ مش هذا لما بيعمل الشكل ال globular قاعد
+
+549
+00:50:13,410 --> 00:50:17,910
+بيتنه؟ طلعوا شايفينه كيف؟ تلقاه بيتنه من هنا من أي
+
+550
+00:50:17,910 --> 00:50:23,450
+نقطة بيتنه؟ بيتنه من عند ال amino acid لبرولين
+
+551
+00:50:23,450 --> 00:50:31,150
+البرولين الوحيد اللي قلنا انه مافيش فيه NH2 فيه NH
+
+552
+00:50:32,660 --> 00:50:37,340
+و بناء على ذلك كل ال amino acids اللي فيها أساسا
+
+553
+00:50:37,340 --> 00:50:41,920
+un-H2 و في الوحيد البرولين فيه un-H هدول لما
+
+554
+00:50:41,920 --> 00:50:47,940
+بيعملوا ال peptide هيخسروا H، شو حيظل عنده هنا؟ un
+
+555
+00:50:47,940 --> 00:50:52,600
+-H هذا لما يعمل شو حيظل؟ من عند البرولين مفيش
+
+556
+00:50:52,600 --> 00:50:58,940
+hydrogen bonding هنا في hydrogen bonding مازال في
+
+557
+00:50:58,940 --> 00:51:03,770
+H، لحظة هي عند البرولينهذا الـ Peptide bond اللي
+
+558
+00:51:03,770 --> 00:51:10,210
+عند البرولين فيه un-etched؟ إذا لم يكن تاني، فهي
+
+559
+00:51:10,210 --> 00:51:15,970
+Amino Acid تاني، فهي un-etched؟ فهي un-etched،
+
+560
+00:51:15,970 --> 00:51:20,980
+كانت un-etched تمو، ضال، un-etched، هذا كانأنا
+
+561
+00:51:20,980 --> 00:51:25,360
+أكتر أنا فعند البرولين مافيش hydrogen bonding وين
+
+562
+00:51:25,360 --> 00:51:28,080
+مافيش hydrogen bonding الجثيات بتتنيه مش احنا
+
+563
+00:51:28,080 --> 00:51:31,860
+قولنا لماسك ال helix ال hydrogen bonding الآن عند
+
+564
+00:51:31,860 --> 00:51:36,200
+البرولين مافيش hydrogen bonding من عنده بيصير إيش
+
+565
+00:51:36,200 --> 00:51:40,580
+التانية عارفين الحديث اللي بيقول أو المقولة اللي
+
+566
+00:51:40,580 --> 00:51:46,940
+بتقول من هناتأتي إيش؟ الهزيمة مقولة صلاح الدين لما
+
+567
+00:51:46,940 --> 00:51:49,980
+لجى الخيمة اللى بتجرهاش القرآن الكريم قال من هنا
+
+568
+00:51:49,980 --> 00:51:54,720
+تأتي الهزيمة ومن أين يأتي الانثناء في ال globular؟
+
+569
+00:51:54,720 --> 00:52:00,000
+من عند البرولين بسبب عدم وجود ال hydrogen bonding
+
+570
+00:52:00,000 --> 00:52:05,830
+أخر شغلةأخر slide، في عندنا شيء بنسميه
+
+571
+00:52:05,830 --> 00:52:09,910
+الـquaternary structure of proteins الـquaternary
+
+572
+00:52:09,910 --> 00:52:14,790
+structure of proteins هو عبارة عن aggregate تجمع
+
+573
+00:52:14,790 --> 00:52:22,150
+لعدة أشكال، يعني مثلا من أمثلته في ال .. ال
+
+574
+00:52:22,150 --> 00:52:26,170
+hemoglobin في ال hemoglobin، هين عملت أنا كرة،
+
+575
+00:52:26,170 --> 00:52:32,270
+globular structure تمام؟الـ Hemoglobin حقيقة عبارة
+
+576
+00:52:32,270 --> 00:52:33,770
+عن نوعين
+
+577
+00:52:35,830 --> 00:52:40,690
+نوعين من الكورات خلينا نتخيله بهذا الشكل طبعا فيهم
+
+578
+00:52:40,690 --> 00:52:44,850
+سلاسل amino acids واحدة بنسميها alpha unit فيها
+
+579
+00:52:44,850 --> 00:52:50,730
+141 amino acid وعملة كورة معينة والتانية ال beta
+
+580
+00:52:50,730 --> 00:52:57,690
+unit 146 amino acid فلاحظوا ال 141 عملالها كورة و
+
+581
+00:52:57,690 --> 00:53:02,010
+ال 146 عمل كورة واحدة سمينها alpha والتانية beta
+
+582
+00:53:02,010 --> 00:53:07,530
+الآن ال hemoglobin بالمجمل هو عبارة عن إيش؟سلسلتين
+
+583
+00:53:07,530 --> 00:53:13,930
+Alpha مع سلسلتين Beta موجودين على شكل tetrahedral
+
+584
+00:53:13,930 --> 00:53:20,850
+arrangement متذكرين التتراهيدرال اللي اتعلمناه زي
+
+585
+00:53:20,850 --> 00:53:28,010
+هيك هاي كرة تنتين نفترض Alpha و Alpha زي هيك يعني
+
+586
+00:53:28,010 --> 00:53:30,310
+ال Hemoglobin تنتين Alpha
+
+587
+00:53:38,910 --> 00:53:45,880
+الشيء الجميل ان احنا بدأنا ال courseفي المحاضرة
+
+588
+00:53:45,880 --> 00:53:51,220
+الأولى بال tetrahedral structure والان ننهي ال
+
+589
+00:53:51,220 --> 00:53:56,280
+course بال tetrahedral arrangement اللى موجودة في
+
+590
+00:53:56,280 --> 00:53:59,700
+ال hemoglobin الدرس القادم ان شاء الله بيكون
+
+591
+00:53:59,700 --> 00:54:01,560
+مراجعة وحل امتحانات
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tov4h-a7-Pc_raw.json b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tov4h-a7-Pc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..46bf2e019ea22fa2da83fdf187c0d4269afdd5d9
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tov4h-a7-Pc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4519, "start": 20.81, "end": 45.19, "text": "بسم الله الرحمن الرحيم بعد ما اتعرفنا في المرات الماضية على الأحماض الأمينية و تفاعلاتها اليوم ان شاء الله هنتعرف كيف هذه الأحماض الأمينية طبعا بتتحد مع بعضها البعض", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 39182, 19446, 1975, 2655, 3615, 28480, 8315, 8978, 9673, 2288, 9307, 9673, 46958, 10632, 15844, 16247, 35571, 46958, 16247, 2304, 9957, 10632, 4032, 6055, 5172, 995, 30241, 9307, 11296, 45595, 20498, 16472, 13412, 16606, 21984, 8032, 29399, 3615, 28480, 9122, 33911, 29538, 16247, 35571, 46958, 16247, 2304, 9957, 10632, 23032, 3555, 3615, 995, 39894, 2655, 24401, 20449, 45030, 11242, 11296, 29739, 3615, 11242], "avg_logprob": -0.09193064905192753, "compression_ratio": 1.9736842105263157, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 20.81, "end": 21.31, "word": "بسم", "probability": 0.919921875}, {"start": 21.31, "end": 21.51, "word": " الله", "probability": 0.9765625}, {"start": 21.51, "end": 21.89, "word": " الرحمن", "probability": 0.9728190104166666}, {"start": 21.89, "end": 22.37, "word": " الرحيم", "probability": 0.9954427083333334}, {"start": 22.37, "end": 25.33, "word": " بعد", "probability": 0.83154296875}, {"start": 25.33, "end": 25.71, "word": " ما", "probability": 0.888671875}, {"start": 25.71, "end": 26.71, "word": " اتعرفنا", "probability": 0.94609375}, {"start": 26.71, "end": 26.87, "word": " في", "probability": 0.953125}, {"start": 26.87, "end": 27.39, "word": " المرات", "probability": 0.94482421875}, {"start": 27.39, "end": 28.21, "word": " الماضية", "probability": 0.99658203125}, {"start": 28.21, "end": 29.27, "word": " على", "probability": 0.87939453125}, {"start": 29.27, "end": 30.09, "word": " الأحماض", "probability": 0.9430338541666666}, {"start": 30.09, "end": 30.93, "word": " الأمينية", "probability": 0.91015625}, {"start": 30.93, "end": 31.27, "word": " و", "probability": 0.55712890625}, {"start": 31.27, "end": 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sequence يعني كيف الأحماض الأمينية مرتبة في هذا ال protein أو في الأصغر منه اللي هو إيش ال peptide طبعا إحنا اتفقنا سابقا إن ال amino acid إله", "tokens": [10721, 12610, 44049, 38207, 8978, 2423, 6194, 3877, 295, 15577, 9673, 4587, 9381, 23328, 8978, 3224, 2423, 24674, 8258, 8310, 37495, 22653, 9122, 33911, 16247, 35571, 46958, 16247, 2304, 9957, 10632, 3714, 43500, 49401, 8978, 23758, 2423, 7944, 34051, 8978, 16247, 9381, 17082, 2288, 9154, 3224, 13672, 1829, 31439, 11933, 1829, 8592, 2423, 41781, 482, 23032, 3555, 3615, 995, 11933, 5016, 8315, 1975, 2655, 5172, 4587, 8315, 8608, 16758, 4587, 995, 36145, 2423, 24674, 8258, 11933, 43761], "avg_logprob": -0.1667668286424417, "compression_ratio": 1.5588235294117647, "no_speech_prob": 0.0, "words": [{"start": 146.95, "end": 147.41, "word": "أول", "probability": 0.926513671875}, {"start": 147.41, "end": 148.11, "word": " شيء", "probability": 0.73779296875}, {"start": 148.11, "end": 148.41, "word": " في", "probability": 0.859375}, {"start": 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بالنسبة للكيميا ايه واضح اطلاقا مش امر صعب يعني انا بدي اسهل عليكم لو عملتلكم على سبيل المثال هذا ال ال بروتيل او ال peptide واضح؟ الآن و اجيت عملتله ال hydrolysis كسرته", "tokens": [10721, 2304, 23557, 20328, 3615, 3555, 995, 20666, 1863, 35457, 3660, 5296, 23275, 32640, 25528, 1975, 1829, 3224, 4032, 46958, 5016, 1975, 9566, 15040, 4587, 995, 37893, 1975, 29973, 20328, 3615, 3555, 37495, 22653, 1975, 8315, 4724, 16254, 24525, 3224, 1211, 25894, 24793, 45164, 6225, 42213, 2655, 23275, 2304, 15844, 8608, 21292, 1211, 9673, 12984, 6027, 23758, 2423, 2423, 4724, 32887, 31371, 1211, 1975, 2407, 2423, 41781, 482, 4032, 46958, 5016, 22807, 6024, 48506, 4032, 1975, 7435, 36081, 6225, 42213, 2655, 43761, 2423, 15435, 356, 17122, 9122, 3794, 43500, 3224], "avg_logprob": -0.20758928669677987, "compression_ratio": 1.641711229946524, "no_speech_prob": 0.0, "words": [{"start": 455.84, "end": 456.34, "word": "أمرا", "probability": 0.6642252604166666}, {"start": 456.34, "end": 456.84, "word": " 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فينا عارف واضح ماحد فينا عارف كيف كانوا مرتبين ففكرة ان اكسرهم و اعرفهم بالظبط جديش العدد الكلي تباعهم و العدد الكلي مكون من اي amino acids هذه الفكرة", "tokens": [32640, 19452, 8978, 43242, 8315, 33251, 10943, 13546, 995, 45164, 9122, 8315, 44945, 47341, 3615, 20666, 2655, 3794, 7435, 26895, 44945, 28543, 2288, 8717, 8592, 38688, 9122, 33911, 25961, 14407, 3714, 43500, 3555, 9957, 44381, 19446, 24401, 8978, 8315, 6225, 9640, 5172, 4032, 46958, 5016, 19446, 24401, 8978, 8315, 6225, 9640, 5172, 9122, 33911, 25961, 14407, 3714, 43500, 3555, 9957, 6156, 5172, 4117, 25720, 16472, 1975, 4117, 3794, 2288, 16095, 4032, 1975, 3615, 28480, 16095, 20666, 19913, 3555, 9566, 10874, 16254, 8592, 18863, 3215, 3215, 33251, 20292, 6055, 3555, 45761, 16095, 4032, 18863, 3215, 3215, 33251, 20292, 3714, 30544, 9154, 1975, 1829, 24674, 21667, 29538, 27188, 4117, 25720], "avg_logprob": -0.1393348623853211, "compression_ratio": 1.947867298578199, "no_speech_prob": 0.0, "words": [{"start": 504.46, "end": 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"probability": 0.9639892578125}, {"start": 515.3, "end": 515.5, "word": " ان", "probability": 0.44384765625}, {"start": 515.5, "end": 516.46, "word": " اكسرهم", "probability": 0.88076171875}, {"start": 516.46, "end": 516.94, "word": " و", "probability": 0.703125}, {"start": 516.94, "end": 517.52, "word": " اعرفهم", "probability": 0.9290771484375}, {"start": 517.52, "end": 518.26, "word": " بالظبط", "probability": 0.9962158203125}, {"start": 518.26, "end": 518.9, "word": " جديش", "probability": 0.7237141927083334}, {"start": 518.9, "end": 519.34, "word": " العدد", "probability": 0.9464518229166666}, {"start": 519.34, "end": 519.88, "word": " الكلي", "probability": 0.6849365234375}, {"start": 519.88, "end": 520.5, "word": " تباعهم", "probability": 0.84918212890625}, {"start": 520.5, "end": 520.62, "word": " و", "probability": 0.60400390625}, {"start": 520.62, "end": 521.02, "word": " العدد", "probability": 0.9532877604166666}, {"start": 521.02, "end": 521.36, "word": " الكلي", "probability": 0.892822265625}, {"start": 521.36, "end": 521.74, "word": " مكون", "probability": 0.7353515625}, {"start": 521.74, "end": 521.98, "word": " من", "probability": 0.98828125}, {"start": 521.98, "end": 522.82, "word": " اي", "probability": 0.88330078125}, {"start": 522.82, "end": 523.26, "word": " amino", "probability": 0.85791015625}, {"start": 523.26, "end": 523.82, "word": " acids", "probability": 0.6884765625}, {"start": 523.82, "end": 524.38, "word": " هذه", "probability": 0.6318359375}, {"start": 524.38, "end": 524.96, "word": " الفكرة", "probability": 0.9939778645833334}], "temperature": 1.0}, {"id": 23, "seek": 53772, "start": 525.82, "end": 537.72, "text": "ممكن أو بسيطة كيميائيا، لكن الفكرة الأصعب، الـ sequence تبعتهم اللي كانت موجودة، هذه الفكرة الأصعب", "tokens": [2304, 43020, 34051, 4724, 3794, 1829, 9566, 3660, 9122, 32640, 1829, 16373, 25528, 12399, 44381, 27188, 4117, 25720, 16247, 9381, 3615, 3555, 12399, 2423, 39184, 8310, 6055, 3555, 34268, 16095, 13672, 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"end": 533.76, "word": " تبعتهم", "probability": 0.8492431640625}, {"start": 533.76, "end": 534.12, "word": " اللي", "probability": 0.646240234375}, {"start": 534.12, "end": 534.52, "word": " كانت", "probability": 0.97216796875}, {"start": 534.52, "end": 535.42, "word": " موجودة،", "probability": 0.93359375}, {"start": 535.42, "end": 535.64, "word": " هذه", "probability": 0.689453125}, {"start": 535.64, "end": 536.2, "word": " الفكرة", "probability": 0.9684244791666666}, {"start": 536.2, "end": 537.72, "word": " الأصعب", "probability": 0.9002685546875}], "temperature": 1.0}, {"id": 24, "seek": 55904, "start": 539.85, "end": 559.05, "text": "اللي أخدت تجارب لحد ما قدروا يحددوا الـ sequences من التجارب هذه من التجارب الأولية اللي بدأوا يستعملوها لتحديد الـ sequences كان في عنده طريقة سيد زانجر method زانجر method", "tokens": [6027, 20292, 5551, 9778, 3215, 2655, 6055, 7435, 9640, 3555, 5296, 24401, 19446, 12174, 3215, 2288, 14407, 7251, 24401, 3215, 14407, 2423, 39184, 22978, 9154, 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{"start": 552.53, "end": 552.69, "word": " الـ", "probability": 0.68310546875}, {"start": 552.69, "end": 553.33, "word": " sequences", "probability": 0.88818359375}, {"start": 553.33, "end": 554.31, "word": " كان", "probability": 0.95556640625}, {"start": 554.31, "end": 554.53, "word": " في", "probability": 0.841796875}, {"start": 554.53, "end": 555.11, "word": " عنده", "probability": 0.58935546875}, {"start": 555.11, "end": 555.95, "word": " طريقة", "probability": 0.9853515625}, {"start": 555.95, "end": 556.99, "word": " سيد", "probability": 0.76123046875}, {"start": 556.99, "end": 557.61, "word": " زانجر", "probability": 0.72021484375}, {"start": 557.61, "end": 558.05, "word": " method", "probability": 0.7900390625}, {"start": 558.05, "end": 558.53, "word": " زانجر", "probability": 0.889892578125}, {"start": 558.53, "end": 559.05, "word": " method", "probability": 0.70849609375}], "temperature": 1.0}, {"id": 25, "seek": 57308, "start": 561.56, "end": 573.08, "text": "اتذكروا معنا شغلة انه احنا لما اتكلمنا عن ال بيبتايد اذا بتذكروا قلنا انه ال بيبتايد له", "tokens": [9307, 8848, 37983, 14407, 20449, 8315, 13412, 17082, 37977, 16472, 3224, 1975, 5016, 8315, 5296, 15042, 1975, 2655, 4117, 19528, 8315, 18871, 2423, 4724, 1829, 3555, 2655, 995, 25708, 1975, 15730, 39894, 8848, 37983, 14407, 12174, 1211, 8315, 16472, 3224, 2423, 4724, 1829, 3555, 2655, 995, 25708, 46740], "avg_logprob": -0.272321418840058, "compression_ratio": 1.6458333333333333, "no_speech_prob": 0.0, "words": [{"start": 561.56, "end": 562.3, "word": "اتذكروا", "probability": 0.760589599609375}, {"start": 562.3, "end": 562.7, "word": " معنا", "probability": 0.95751953125}, {"start": 562.7, "end": 564.1, "word": " شغلة", "probability": 0.7996419270833334}, {"start": 564.1, "end": 565.2, "word": " انه", "probability": 0.5296630859375}, {"start": 565.2, "end": 565.52, "word": " احنا", "probability": 0.9606119791666666}, {"start": 565.52, "end": 565.76, "word": " لما", "probability": 0.957275390625}, 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و C terminal مظبوط ولا لا الآن ال method زانجر ماعملتش شغل كتير لنا عملت شغلة بسيطة جدا بس قال انا بقدر اساعدكم اقولكم مين اول amino acid and terminal يعني بس بيقولي ان ال and terminal هو مثلا نجليسين او tryptophan و بعد هيك", "tokens": [7039, 2071, 4032, 383, 14709, 3714, 19913, 3555, 2407, 9566, 49429, 20193, 6024, 48506, 2423, 3170, 30767, 7649, 7435, 2288, 19446, 25957, 1211, 2655, 8592, 13412, 17082, 1211, 9122, 2655, 13546, 5296, 8315, 6225, 42213, 2655, 13412, 17082, 37977, 4724, 3794, 1829, 9566, 3660, 10874, 28259, 4724, 3794, 50239, 1975, 8315, 4724, 28543, 2288, 24525, 995, 22488, 24793, 1975, 39648, 24793, 3714, 9957, 1975, 12610, 24674, 8258, 293, 14709, 37495, 22653, 4724, 3794, 4724, 1829, 39648, 1829, 16472, 2423, 293, 14709, 31439, 50113, 15040, 8717, 7435, 20292, 3794, 9957, 1975, 2407, 853, 662, 404, 3451, 4032, 39182, 39896, 4117], "avg_logprob": -0.26265624046325686, "compression_ratio": 1.6682242990654206, "no_speech_prob": 0.0, "words": [{"start": 576.52, "end": 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sequence", "probability": 0.97705078125}, {"start": 2149.0, "end": 2149.5, "word": " ال", "probability": 0.76171875}, {"start": 2149.5, "end": 2149.94, "word": " sequence", "probability": 0.98828125}, {"start": 2149.94, "end": 2150.22, "word": " شو", "probability": 0.950439453125}, {"start": 2150.22, "end": 2150.52, "word": " هي", "probability": 0.90380859375}, {"start": 2150.52, "end": 2152.4, "word": " amino", "probability": 0.382568359375}, {"start": 2152.4, "end": 2153.04, "word": " acids", "probability": 0.7392578125}], "temperature": 1.0}, {"id": 91, "seek": 216267, "start": 2153.92, "end": 2162.68, "text": "مختلفة متتالية لازم نعرفها هاي عملنا sequence هذا peptide", "tokens": [2304, 46456, 46538, 3660, 44650, 2655, 6027, 10632, 5296, 31377, 2304, 8717, 3615, 28480, 11296, 8032, 47302, 6225, 42213, 8315, 8310, 23758, 41781, 482], "avg_logprob": -0.19328125476837157, "compression_ratio": 1.0459770114942528, "no_speech_prob": 0.0, "words": [{"start": 2153.92, "end": 2154.76, "word": "مختلفة", "probability": 0.917724609375}, {"start": 2154.76, "end": 2155.44, "word": " متتالية", "probability": 0.9061279296875}, {"start": 2155.44, "end": 2155.82, "word": " لازم", "probability": 0.9783528645833334}, {"start": 2155.82, "end": 2156.44, "word": " نعرفها", "probability": 0.986328125}, {"start": 2156.44, "end": 2157.06, "word": " هاي", "probability": 0.514404296875}, {"start": 2157.06, "end": 2157.76, "word": " عملنا", "probability": 0.97314453125}, {"start": 2157.76, "end": 2161.52, "word": " sequence", "probability": 0.3916015625}, {"start": 2161.52, "end": 2161.98, "word": " هذا", "probability": 0.7373046875}, {"start": 2161.98, "end": 2162.68, "word": " peptide", "probability": 0.6527099609375}], "temperature": 1.0}, {"id": 92, "seek": 218892, "start": 2164.08, "end": 2188.92, "text": "بتطلع عليه اعمله له sequence إجليسين ألانين تيروسين كذا كذا كذا اعمله و خلصنا معرفة الترتيب هو اللي بنسمي احنا ايش ال primary structure اذا ال primary structure هو معرفة ال sequence خلصنا منه الآن بعد هيك هذا كيف بده يصير في الدنيا بده يظله على شكل خط ولا بده ياخد أشكال تانية", "tokens": [3555, 2655, 9566, 1211, 3615, 47356, 1975, 25957, 43761, 46740, 8310, 11933, 7435, 20292, 3794, 9957, 5551, 1211, 7649, 9957, 6055, 13546, 41779, 9957, 9122, 15730, 9122, 15730, 9122, 15730, 1975, 25957, 43761, 4032, 16490, 1211, 9381, 8315, 20449, 28480, 3660, 16712, 2288, 31371, 3555, 31439, 13672, 1829, 44945, 38251, 1829, 1975, 5016, 8315, 1975, 1829, 8592, 2423, 6194, 3877, 1975, 15730, 2423, 6194, 3877, 31439, 20449, 28480, 3660, 2423, 8310, 16490, 1211, 9381, 8315, 9154, 3224, 6024, 48506, 39182, 39896, 4117, 23758, 9122, 33911, 47525, 3224, 7251, 9381, 13546, 8978, 32748, 22653, 995, 47525, 3224, 7251, 19913, 43761, 15844, 13412, 28820, 16490, 9566, 49429, 47525, 3224, 7251, 47283, 3215, 5551, 8592, 4117, 6027, 6055, 7649, 10632], "avg_logprob": -0.1910752069394467, "compression_ratio": 1.8991596638655461, "no_speech_prob": 5.960464477539063e-08, "words": 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"probability": 0.91943359375}, {"start": 2176.8, "end": 2177.48, "word": " اذا", "probability": 0.6793212890625}, {"start": 2177.48, "end": 2177.68, "word": " ال", "probability": 0.9609375}, {"start": 2177.68, "end": 2178.06, "word": " primary", "probability": 0.96533203125}, {"start": 2178.06, "end": 2178.58, "word": " structure", "probability": 0.9150390625}, {"start": 2178.58, "end": 2178.76, "word": " هو", "probability": 0.98291015625}, {"start": 2178.76, "end": 2179.26, "word": " معرفة", "probability": 0.9947916666666666}, {"start": 2179.26, "end": 2179.4, "word": " ال", "probability": 0.9619140625}, {"start": 2179.4, "end": 2179.88, "word": " sequence", "probability": 0.986328125}, {"start": 2179.88, "end": 2180.72, "word": " خلصنا", "probability": 0.98046875}, {"start": 2180.72, "end": 2181.14, "word": " منه", "probability": 0.9873046875}, {"start": 2181.14, "end": 2181.92, "word": " الآن", "probability": 0.68896484375}, {"start": 2181.92, "end": 2182.26, "word": " بعد", 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كيف أنا بمشي", "tokens": [41185, 16247, 5016, 1829, 16606, 6055, 3615, 28480, 14407, 6055, 25957, 1211, 2407, 16095, 8978, 2423, 21292, 2655, 45164, 12174, 1211, 8315, 5296, 4117, 14407, 7251, 25957, 1211, 14407, 20588, 4032, 33286, 9122, 33911, 22807, 6024, 48506, 8032, 47302, 8032, 3215, 12610, 3660, 2423, 801, 970, 9307, 45164, 5551, 3615, 9566, 36081, 4117, 14407, 11933, 25528, 16095, 3714, 9957, 47525, 3224, 37495, 28480, 32767, 9957, 2423, 20588, 4032, 2304, 9957, 2423, 33286, 13672, 1829, 32748, 13063, 7649, 6055, 3555, 3615, 3224, 11933, 15730, 3714, 8592, 36081, 8978, 3224, 20449, 5551, 4587, 9640, 3555, 21136, 995, 27884, 44945, 38251, 1829, 3224, 20588, 801, 970, 1975, 2655, 9566, 1211, 3615, 14407, 20449, 40294, 39896, 4117, 1975, 2655, 9566, 1211, 3615, 14407, 9122, 33911, 41850, 4724, 2304, 8592, 1829], "avg_logprob": -0.20620078435094338, "compression_ratio": 1.8099173553719008, "no_speech_prob": 0.0, "words": [{"start": 2241.05, "end": 2241.27, "word": "في", 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"probability": 0.501220703125}, {"start": 2647.09, "end": 2648.15, "word": " يعني", "probability": 0.869384765625}, {"start": 2648.15, "end": 2648.41, "word": " ال", "probability": 0.94482421875}, {"start": 2648.41, "end": 2648.75, "word": " alpha", "probability": 0.419677734375}, {"start": 2648.75, "end": 2649.33, "word": " helix", "probability": 0.9580078125}, {"start": 2649.33, "end": 2650.17, "word": " محدد", "probability": 0.9488932291666666}, {"start": 2650.17, "end": 2651.03, "word": " تماما", "probability": 0.9869791666666666}, {"start": 2651.03, "end": 2651.79, "word": " و", "probability": 0.9912109375}, {"start": 2651.79, "end": 2652.39, "word": " واضح", "probability": 0.9285481770833334}], "temperature": 1.0}, {"id": 109, "seek": 268288, "start": 2653.78, "end": 2682.88, "text": "عند الناس اللي بيشتغلوا فيه الان الاحتمال التاني انه ممكن يكونوا ايش بـlated sheet زي الدرج بهذا الشكل و ايضا محددين و بتمسكوا بـhydrogen bonding و لاحظوا لما بيكونوا زي الدرج بيكونوا سلسلتين اقبال بعض و بيشبكوا بـhydrogen bonding اذا ال secondary structure لبروتين", "tokens": [3615, 41260, 2423, 8315, 3794, 13672, 1829, 4724, 1829, 8592, 2655, 17082, 1211, 14407, 8978, 3224, 2423, 7649, 42963, 33753, 2304, 6027, 16712, 7649, 1829, 16472, 3224, 3714, 43020, 7251, 30544, 14407, 1975, 1829, 8592, 4724, 39184, 38539, 8193, 30767, 1829, 32748, 47341, 39627, 15730, 25124, 28820, 4032, 1975, 1829, 11242, 995, 3714, 24401, 3215, 9957, 4032, 39894, 2304, 3794, 4117, 14407, 4724, 39184, 21591, 7747, 28824, 4032, 20193, 5016, 19913, 14407, 5296, 15042, 4724, 1829, 30544, 14407, 30767, 1829, 32748, 47341, 4724, 1829, 30544, 14407, 8608, 1211, 3794, 1211, 2655, 9957, 1975, 4587, 3555, 6027, 45030, 11242, 4032, 4724, 1829, 8592, 3555, 4117, 14407, 4724, 39184, 21591, 7747, 28824, 1975, 15730, 2423, 11396, 3877, 5296, 26890, 35473, 9957], "avg_logprob": -0.20729166169961294, "compression_ratio": 1.8177966101694916, "no_speech_prob": 0.0, "words": [{"start": 2653.78, "end": 2654.12, "word": 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"end": 2670.46, "word": " bonding", "probability": 0.9228515625}, {"start": 2670.46, "end": 2671.38, "word": " و", "probability": 0.3876953125}, {"start": 2671.38, "end": 2671.82, "word": " لاحظوا", "probability": 0.9189453125}, {"start": 2671.82, "end": 2672.04, "word": " لما", "probability": 0.893310546875}, {"start": 2672.04, "end": 2672.44, "word": " بيكونوا", "probability": 0.8515625}, {"start": 2672.44, "end": 2672.62, "word": " زي", "probability": 0.9853515625}, {"start": 2672.62, "end": 2673.1, "word": " الدرج", "probability": 0.98876953125}, {"start": 2673.1, "end": 2673.6, "word": " بيكونوا", "probability": 0.9573974609375}, {"start": 2673.6, "end": 2674.4, "word": " سلسلتين", "probability": 0.9833170572916666}, {"start": 2674.4, "end": 2674.8, "word": " اقبال", "probability": 0.70233154296875}, {"start": 2674.8, "end": 2675.32, "word": " بعض", "probability": 0.99658203125}, {"start": 2675.32, "end": 2675.98, "word": " و", "probability": 0.7578125}, {"start": 2675.98, "end": 2676.76, "word": " بيشبكوا", "probability": 0.93359375}, {"start": 2676.76, "end": 2678.64, "word": " بـhydrogen", "probability": 0.9091796875}, {"start": 2678.64, "end": 2679.04, "word": " bonding", "probability": 0.97705078125}, {"start": 2679.04, "end": 2679.66, "word": " اذا", "probability": 0.7939453125}, {"start": 2679.66, "end": 2680.0, "word": " ال", "probability": 0.85595703125}, {"start": 2680.0, "end": 2680.56, "word": " secondary", "probability": 0.88916015625}, {"start": 2680.56, "end": 2681.38, "word": " structure", "probability": 0.8935546875}, {"start": 2681.38, "end": 2682.88, "word": " لبروتين", "probability": 0.75244140625}], "temperature": 1.0}, {"id": 110, "seek": 271319, "start": 2684.27, "end": 2713.19, "text": "يا إما Alpha Helix أو Pleated Sheet الآن اعرفنا ال secondary structure نيجي على ال tertiary structure قولنا Alpha Helix هي Alpha Helix يا ترها ال Alpha Helix هذا كيف بيكون موجود هي هيك Alpha Helix ولا لأ طب و هيك Alpha Helix ولا لأ يعني ببساطة اتخيلوا الحياة", "tokens": [25528, 11933, 15042, 20588, 6128, 970, 34051, 25658, 770, 1240, 302, 6024, 48506, 1975, 3615, 28480, 8315, 2423, 11396, 3877, 8717, 1829, 7435, 1829, 15844, 2423, 38726, 29104, 3877, 12174, 12610, 8315, 20588, 6128, 970, 39896, 20588, 6128, 970, 35186, 6055, 2288, 11296, 2423, 20588, 6128, 970, 23758, 9122, 33911, 4724, 1829, 30544, 3714, 29245, 23328, 39896, 39896, 4117, 20588, 6128, 970, 49429, 5296, 10721, 23032, 3555, 4032, 39896, 4117, 20588, 6128, 970, 49429, 5296, 10721, 37495, 22653, 4724, 3555, 3794, 41193, 3660, 1975, 2655, 9778, 26895, 14407, 21542, 25528, 3660], "avg_logprob": -0.2953464654476746, "compression_ratio": 1.6948356807511737, "no_speech_prob": 0.0, "words": [{"start": 2684.27, "end": 2684.53, "word": "يا", "probability": 0.39013671875}, {"start": 2684.53, "end": 2684.69, "word": " إما", "probability": 0.6822509765625}, {"start": 2684.69, "end": 2685.37, "word": " Alpha", "probability": 0.392822265625}, {"start": 2685.37, "end": 2686.01, 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"end": 2698.59, "word": " Helix", "probability": 0.963623046875}, {"start": 2698.59, "end": 2699.05, "word": " هذا", "probability": 0.6865234375}, {"start": 2699.05, "end": 2700.95, "word": " كيف", "probability": 0.92822265625}, {"start": 2700.95, "end": 2701.43, "word": " بيكون", "probability": 0.7001139322916666}, {"start": 2701.43, "end": 2702.11, "word": " موجود", "probability": 0.9786783854166666}, {"start": 2702.11, "end": 2702.71, "word": " هي", "probability": 0.44189453125}, {"start": 2702.71, "end": 2703.17, "word": " هيك", "probability": 0.7587890625}, {"start": 2703.17, "end": 2703.57, "word": " Alpha", "probability": 0.908203125}, {"start": 2703.57, "end": 2703.97, "word": " Helix", "probability": 0.96142578125}, {"start": 2703.97, "end": 2704.19, "word": " ولا", "probability": 0.9033203125}, {"start": 2704.19, "end": 2704.61, "word": " لأ", "probability": 0.900634765625}, {"start": 2704.61, "end": 2706.33, "word": " طب", "probability": 0.635986328125}, {"start": 2706.33, "end": 2706.43, "word": " و", "probability": 0.7587890625}, {"start": 2706.43, "end": 2706.89, "word": " هيك", "probability": 0.984375}, {"start": 2706.89, "end": 2708.15, "word": " Alpha", "probability": 0.95166015625}, {"start": 2708.15, "end": 2708.59, "word": " Helix", "probability": 0.974365234375}, {"start": 2708.59, "end": 2708.85, "word": " ولا", "probability": 0.9462890625}, {"start": 2708.85, "end": 2709.31, "word": " لأ", "probability": 0.994384765625}, {"start": 2709.31, "end": 2710.21, "word": " يعني", "probability": 0.927734375}, {"start": 2710.21, "end": 2711.21, "word": " ببساطة", "probability": 0.91083984375}, {"start": 2711.21, "end": 2712.31, "word": " اتخيلوا", "probability": 0.9130859375}, {"start": 2712.31, "end": 2713.19, "word": " الحياة", "probability": 0.78076171875}], "temperature": 1.0}, {"id": 111, "seek": 274239, "start": 2713.97, "end": 2742.39, "text": "عارفين الحياة؟ الصعبان الصعبان لما بيكون هيك عدل بتخافوا منه ولا لأ طب و لما يكون ملف في حاله و مكور هذا صعبان وهذا صعبان و في الحالتين بتخافوا منه الآن ال alpha helix نفس الفكرة يا إما بيكون مكور حاله بنقول عنه globular كراوي", "tokens": [3615, 9640, 5172, 9957, 21542, 25528, 3660, 22807, 31767, 3615, 3555, 7649, 31767, 3615, 3555, 7649, 5296, 15042, 4724, 1829, 30544, 39896, 4117, 6225, 3215, 1211, 39894, 9778, 31845, 14407, 9154, 3224, 49429, 5296, 10721, 23032, 3555, 4032, 5296, 15042, 7251, 30544, 3714, 46538, 8978, 11331, 6027, 3224, 4032, 3714, 4117, 13063, 23758, 20328, 3615, 3555, 7649, 37037, 15730, 20328, 3615, 3555, 7649, 4032, 8978, 21542, 6027, 2655, 9957, 39894, 9778, 31845, 14407, 9154, 3224, 6024, 48506, 2423, 8961, 801, 970, 8717, 36178, 27188, 4117, 25720, 35186, 11933, 15042, 4724, 1829, 30544, 3714, 4117, 13063, 11331, 6027, 3224, 44945, 39648, 18871, 3224, 16125, 1040, 9122, 23557, 45865], "avg_logprob": -0.163773146768411, "compression_ratio": 1.9306930693069306, "no_speech_prob": 0.0, "words": [{"start": 2713.97, "end": 2714.45, "word": "عارفين", "probability": 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"probability": 0.54736328125}, {"start": 2726.79, "end": 2726.87, "word": " و", "probability": 0.953125}, {"start": 2726.87, "end": 2727.07, "word": " لما", "probability": 0.884521484375}, {"start": 2727.07, "end": 2727.43, "word": " يكون", "probability": 0.98046875}, {"start": 2727.43, "end": 2727.85, "word": " ملف", "probability": 0.922607421875}, {"start": 2727.85, "end": 2728.03, "word": " في", "probability": 0.74951171875}, {"start": 2728.03, "end": 2728.39, "word": " حاله", "probability": 0.9817708333333334}, {"start": 2728.39, "end": 2728.49, "word": " و", "probability": 0.966796875}, {"start": 2728.49, "end": 2729.05, "word": " مكور", "probability": 0.8675130208333334}, {"start": 2729.05, "end": 2730.19, "word": " هذا", "probability": 0.8134765625}, {"start": 2730.19, "end": 2731.33, "word": " صعبان", "probability": 0.9952392578125}, {"start": 2731.33, "end": 2732.01, "word": " وهذا", "probability": 0.76904296875}, {"start": 2732.01, "end": 2732.67, "word": " صعبان", 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"probability": 0.9396158854166666}, {"start": 3003.75, "end": 3004.19, "word": " من", "probability": 0.8896484375}, {"start": 3004.19, "end": 3004.33, "word": " هنا", "probability": 0.451416015625}, {"start": 3004.33, "end": 3004.75, "word": " بيعمل", "probability": 0.9835205078125}, {"start": 3004.75, "end": 3005.03, "word": " turn", "probability": 0.8642578125}, {"start": 3005.03, "end": 3005.43, "word": " ثالث", "probability": 0.8795572916666666}, {"start": 3005.43, "end": 3005.89, "word": " من", "probability": 0.95751953125}, {"start": 3005.89, "end": 3006.17, "word": " اي", "probability": 0.838134765625}, {"start": 3006.17, "end": 3006.85, "word": " نقطة", "probability": 0.9895833333333334}, {"start": 3006.85, "end": 3007.65, "word": " تحديدا", "probability": 0.908447265625}, {"start": 3007.65, "end": 3008.29, "word": " بيتن", "probability": 0.9386393229166666}], "temperature": 1.0}, {"id": 122, "seek": 303115, "start": 3009.81, "end": 3031.15, "text": "واضح؟ مش هذا لما بيعمل الشكل ال globular قاعد بيتنه؟ طلعوا شايفينه كيف؟ تلقاه بيتنه من هنا من أي نقطة بيتنه؟ بيتنه من عند ال amino acid لبرولين البرولين الوحيد اللي قلنا انه مافيش فيه NH2 فيه NH", "tokens": [2407, 46958, 5016, 22807, 37893, 23758, 5296, 15042, 4724, 1829, 25957, 1211, 25124, 28820, 2423, 16125, 1040, 12174, 995, 22488, 4724, 36081, 1863, 3224, 22807, 23032, 1211, 3615, 14407, 13412, 995, 33911, 9957, 3224, 9122, 33911, 22807, 6055, 1211, 4587, 40294, 4724, 36081, 1863, 3224, 9154, 34105, 9154, 36632, 8717, 47432, 3660, 4724, 36081, 1863, 3224, 22807, 4724, 36081, 1863, 3224, 9154, 43242, 2423, 24674, 8258, 5296, 26890, 12610, 9957, 2423, 26890, 12610, 9957, 2423, 2407, 5016, 25708, 13672, 1829, 12174, 1211, 8315, 16472, 3224, 19446, 41185, 8592, 8978, 3224, 31118, 17, 8978, 3224, 31118], "avg_logprob": -0.21402994248395166, "compression_ratio": 1.6785714285714286, "no_speech_prob": 0.0, "words": [{"start": 3009.81, "end": 3010.47, "word": "واضح؟", "probability": 0.82373046875}, {"start": 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{"start": 3015.79, "end": 3016.21, "word": " تلقاه", "probability": 0.9425048828125}, {"start": 3016.21, "end": 3016.59, "word": " بيتنه", "probability": 0.8702392578125}, {"start": 3016.59, "end": 3016.69, "word": " من", "probability": 0.98681640625}, {"start": 3016.69, "end": 3016.97, "word": " هنا", "probability": 0.72998046875}, {"start": 3016.97, "end": 3017.69, "word": " من", "probability": 0.45556640625}, {"start": 3017.69, "end": 3017.91, "word": " أي", "probability": 0.77587890625}, {"start": 3017.91, "end": 3018.37, "word": " نقطة", "probability": 0.9820963541666666}, {"start": 3018.37, "end": 3019.35, "word": " بيتنه؟", "probability": 0.96416015625}, {"start": 3019.35, "end": 3020.07, "word": " بيتنه", "probability": 0.9681396484375}, {"start": 3020.07, "end": 3020.29, "word": " من", "probability": 0.98291015625}, {"start": 3020.29, "end": 3020.79, "word": " عند", "probability": 0.982421875}, {"start": 3020.79, "end": 3021.17, "word": " ال", "probability": 0.98388671875}, {"start": 3021.17, "end": 3021.61, "word": " amino", "probability": 0.62158203125}, {"start": 3021.61, "end": 3022.23, "word": " acid", "probability": 0.9609375}, {"start": 3022.23, "end": 3023.45, "word": " لبرولين", "probability": 0.83892822265625}, {"start": 3023.45, "end": 3025.19, "word": " البرولين", "probability": 0.8128662109375}, {"start": 3025.19, "end": 3026.05, "word": " الوحيد", "probability": 0.9866943359375}, {"start": 3026.05, "end": 3026.85, "word": " اللي", "probability": 0.945068359375}, {"start": 3026.85, "end": 3027.35, "word": " قلنا", "probability": 0.7810872395833334}, {"start": 3027.35, "end": 3027.85, "word": " انه", "probability": 0.6260986328125}, {"start": 3027.85, "end": 3028.23, "word": " مافيش", "probability": 0.9342447916666666}, {"start": 3028.23, "end": 3028.47, "word": " فيه", "probability": 0.860107421875}, {"start": 3028.47, "end": 3029.35, "word": " NH2", "probability": 0.698974609375}, {"start": 3029.35, "end": 3030.81, "word": " فيه", "probability": 0.653564453125}, {"start": 3030.81, "end": 3031.15, "word": " NH", "probability": 0.430908203125}], "temperature": 1.0}, {"id": 123, "seek": 306106, "start": 3032.66, "end": 3061.06, "text": "و بناء على ذلك كل ال amino acids اللي فيها أساسا un-H2 و في الوحيد البرولين فيه un-H هدول لما بيعملوا ال peptide هيخسروا H، شو حيظل عنده هنا؟ un-H هذا لما يعمل شو حيظل؟ من عند البرولين مفيش hydrogen bonding هنا في hydrogen bonding مازال في H، لحظة هي عند البرولين", "tokens": [2407, 44945, 16606, 15844, 29910, 23275, 28242, 2423, 24674, 21667, 13672, 1829, 8978, 11296, 5551, 3794, 32277, 995, 517, 12, 39, 17, 4032, 8978, 2423, 2407, 5016, 25708, 2423, 26890, 12610, 9957, 8978, 3224, 517, 12, 39, 8032, 3215, 12610, 5296, 15042, 4724, 1829, 25957, 1211, 14407, 2423, 41781, 482, 8032, 1829, 9778, 3794, 2288, 14407, 389, 12399, 13412, 2407, 11331, 1829, 19913, 1211, 43242, 3224, 34105, 22807, 517, 12, 39, 23758, 5296, 15042, 7251, 25957, 1211, 13412, 2407, 11331, 1829, 19913, 1211, 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"word": "-H", "probability": 0.943603515625}, {"start": 3048.22, "end": 3048.68, "word": " هذا", "probability": 0.274169921875}, {"start": 3048.68, "end": 3048.92, "word": " لما", "probability": 0.974853515625}, {"start": 3048.92, "end": 3049.3, "word": " يعمل", "probability": 0.9832356770833334}, {"start": 3049.3, "end": 3049.46, "word": " شو", "probability": 0.83642578125}, {"start": 3049.46, "end": 3049.98, "word": " حيظل؟", "probability": 0.90078125}, {"start": 3049.98, "end": 3051.58, "word": " من", "probability": 0.85302734375}, {"start": 3051.58, "end": 3051.82, "word": " عند", "probability": 0.986328125}, {"start": 3051.82, "end": 3052.32, "word": " البرولين", "probability": 0.966552734375}, {"start": 3052.32, "end": 3052.6, "word": " مفيش", "probability": 0.6481526692708334}, {"start": 3052.6, "end": 3052.98, "word": " hydrogen", "probability": 0.47900390625}, {"start": 3052.98, "end": 3053.7, "word": " bonding", "probability": 0.943359375}, {"start": 3053.7, "end": 3055.7, "word": " هنا", "probability": 0.91943359375}, {"start": 3055.7, "end": 3057.22, "word": " في", "probability": 0.62353515625}, {"start": 3057.22, "end": 3057.74, "word": " hydrogen", "probability": 0.73876953125}, {"start": 3057.74, "end": 3058.26, "word": " bonding", "probability": 0.96240234375}, {"start": 3058.26, "end": 3058.72, "word": " مازال", "probability": 0.6433919270833334}, {"start": 3058.72, "end": 3058.94, "word": " في", "probability": 0.95703125}, {"start": 3058.94, "end": 3059.74, "word": " H،", "probability": 0.578369140625}, {"start": 3059.74, "end": 3060.1, "word": " لحظة", "probability": 0.9200439453125}, {"start": 3060.1, "end": 3060.22, "word": " هي", "probability": 0.309814453125}, {"start": 3060.22, "end": 3060.44, "word": " عند", "probability": 0.96337890625}, {"start": 3060.44, "end": 3061.06, "word": " البرولين", "probability": 0.9813232421875}], "temperature": 1.0}, {"id": 124, "seek": 307945, "start": 3062.41, "end": 3079.45, "text": "هذا الـ Peptide bond اللي عند البرولين فيه un-etched؟ إذا لم يكن تاني، فهي Amino Acid تاني، فهي un-etched؟ فهي un-etched، كانت un-etched تمو، ضال، un-etched، هذا كان", "tokens": [3224, 15730, 2423, 39184, 430, 5250, 482, 6086, 13672, 1829, 43242, 2423, 26890, 12610, 9957, 8978, 3224, 517, 12, 302, 19318, 22807, 11933, 15730, 32767, 7251, 19452, 6055, 7649, 1829, 12399, 6156, 3224, 1829, 2012, 2982, 5097, 327, 6055, 7649, 1829, 12399, 6156, 3224, 1829, 517, 12, 302, 19318, 22807, 6156, 3224, 1829, 517, 12, 302, 19318, 12399, 25961, 2655, 517, 12, 302, 19318, 6055, 2304, 2407, 12399, 48812, 6027, 12399, 517, 12, 302, 19318, 12399, 23758, 25961], "avg_logprob": -0.5340189647070969, "compression_ratio": 1.576158940397351, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3062.41, "end": 3062.73, "word": "هذا", "probability": 0.5958251953125}, {"start": 3062.73, "end": 3062.83, "word": " الـ", "probability": 0.5255126953125}, {"start": 3062.83, "end": 3063.31, "word": " Peptide", "probability": 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"probability": 0.4486490885416667}, {"start": 3070.21, "end": 3070.61, "word": " Amino", "probability": 0.50634765625}, {"start": 3070.61, "end": 3070.97, "word": " Acid", "probability": 0.658935546875}, {"start": 3070.97, "end": 3072.27, "word": " تاني،", "probability": 0.81927490234375}, {"start": 3072.27, "end": 3072.75, "word": " فهي", "probability": 0.7692057291666666}, {"start": 3072.75, "end": 3072.93, "word": " un", "probability": 0.451904296875}, {"start": 3072.93, "end": 3074.11, "word": "-etched؟", "probability": 0.8111572265625}, {"start": 3074.11, "end": 3075.35, "word": " فهي", "probability": 0.6853841145833334}, {"start": 3075.35, "end": 3075.51, "word": " un", "probability": 0.75634765625}, {"start": 3075.51, "end": 3075.97, "word": "-etched،", "probability": 0.7667236328125}, {"start": 3075.97, "end": 3076.43, "word": " كانت", "probability": 0.713623046875}, {"start": 3076.43, "end": 3076.57, "word": " un", "probability": 0.8408203125}, {"start": 3076.57, "end": 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نوعين", "tokens": [6027, 39184, 18568, 45841, 13496, 11331, 38436, 28671, 6225, 3555, 9640, 3660, 18871, 8717, 45367, 9957], "avg_logprob": -0.1064453125, "compression_ratio": 0.9016393442622951, "no_speech_prob": 0.0, "words": [{"start": 3149.97, "end": 3150.31, "word": "الـ", "probability": 0.781982421875}, {"start": 3150.31, "end": 3150.87, "word": " Hemoglobin", "probability": 0.8458658854166666}, {"start": 3150.87, "end": 3151.59, "word": " حقيقة", "probability": 0.8408203125}, {"start": 3151.59, "end": 3152.27, "word": " عبارة", "probability": 0.97412109375}, {"start": 3152.27, "end": 3152.61, "word": " عن", "probability": 0.99658203125}, {"start": 3152.61, "end": 3153.77, "word": " نوعين", "probability": 0.97705078125}], "temperature": 1.0}, {"id": 129, "seek": 318557, "start": 3155.83, "end": 3185.57, "text": "نوعين من الكورات خلينا نتخيله بهذا الشكل طبعا فيهم سلاسل amino acids واحدة بنسميها alpha unit فيها 141 amino acid وعملة كورة معينة والتانية ال beta unit 146 amino acid 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" acids", "probability": 0.759765625}, {"start": 3162.23, "end": 3162.61, "word": " واحدة", "probability": 0.9332682291666666}, {"start": 3162.61, "end": 3163.27, "word": " بنسميها", "probability": 0.9447021484375}, {"start": 3163.27, "end": 3164.01, "word": " alpha", "probability": 0.4033203125}, {"start": 3164.01, "end": 3164.51, "word": " unit", "probability": 0.83544921875}, {"start": 3164.51, "end": 3164.85, "word": " فيها", "probability": 0.9482421875}, {"start": 3164.85, "end": 3165.93, "word": " 141", "probability": 0.8466796875}, {"start": 3165.93, "end": 3166.37, "word": " amino", "probability": 0.95654296875}, {"start": 3166.37, "end": 3166.77, "word": " acid", "probability": 0.92724609375}, {"start": 3166.77, "end": 3167.21, "word": " وعملة", "probability": 0.7734375}, {"start": 3167.21, "end": 3167.53, "word": " كورة", "probability": 0.97412109375}, {"start": 3167.53, "end": 3168.17, "word": " معينة", "probability": 0.9772135416666666}, {"start": 3168.17, "end": 3169.05, "word": " والتانية", "probability": 0.85589599609375}, {"start": 3169.05, "end": 3170.33, "word": " ال", "probability": 0.94677734375}, {"start": 3170.33, "end": 3170.73, "word": " beta", "probability": 0.83740234375}, {"start": 3170.73, "end": 3172.23, "word": " unit", "probability": 0.9775390625}, {"start": 3172.23, "end": 3173.53, "word": " 146", "probability": 0.962890625}, {"start": 3173.53, "end": 3173.97, "word": " amino", "probability": 0.982421875}, {"start": 3173.97, "end": 3174.41, "word": " acid", "probability": 0.95654296875}, {"start": 3174.41, "end": 3175.07, "word": " فلاحظوا", "probability": 0.93076171875}, {"start": 3175.07, "end": 3175.17, "word": " ال", "probability": 0.822265625}, {"start": 3175.17, "end": 3176.15, "word": " 141", "probability": 0.941650390625}, {"start": 3176.15, "end": 3176.81, "word": " عملالها", "probability": 0.7869873046875}, {"start": 3176.81, "end": 3177.41, "word": " كورة", "probability": 0.9676106770833334}, {"start": 3177.41, "end": 3177.69, "word": " و", "probability": 0.73388671875}, {"start": 3177.69, "end": 3177.77, "word": " ال", "probability": 0.36669921875}, {"start": 3177.77, "end": 3178.77, "word": " 146", "probability": 0.972412109375}, {"start": 3178.77, "end": 3179.15, "word": " عمل", "probability": 0.904052734375}, {"start": 3179.15, "end": 3179.53, "word": " كورة", "probability": 0.7207438151041666}, {"start": 3179.53, "end": 3179.95, "word": " واحدة", "probability": 0.9736328125}, {"start": 3179.95, "end": 3180.25, "word": " سمينها", "probability": 0.68353271484375}, {"start": 3180.25, "end": 3180.67, "word": " alpha", "probability": 0.65771484375}, {"start": 3180.67, "end": 3181.65, "word": " والتانية", "probability": 0.954833984375}, {"start": 3181.65, "end": 3182.01, "word": " beta", "probability": 0.73974609375}, {"start": 3182.01, "end": 3182.59, "word": " الآن", "probability": 0.6915283203125}, {"start": 3182.59, "end": 3182.75, "word": " ال", "probability": 0.98486328125}, {"start": 3182.75, "end": 3183.37, "word": " hemoglobin", "probability": 0.7643229166666666}, {"start": 3183.37, "end": 3184.09, "word": " بالمجمل", "probability": 0.8861083984375}, {"start": 3184.09, "end": 3184.51, "word": " هو", "probability": 0.984375}, {"start": 3184.51, "end": 3184.85, "word": " عبارة", "probability": 0.996337890625}, {"start": 3184.85, "end": 3185.07, "word": " عن", "probability": 0.99462890625}, {"start": 3185.07, "end": 3185.57, "word": " إيش؟", "probability": 0.8250732421875}], "temperature": 1.0}, {"id": 130, "seek": 321031, "start": 3186.39, "end": 3210.31, "text": "سلسلتين Alpha مع سلسلتين Beta موجودين على شكل tetrahedral arrangement متذكرين التتراهيدرال اللي اتعلمناه زي هيك هاي كرة تنتين نفترض Alpha و Alpha زي هيك يعني ال Hemoglobin تنتين Alpha", "tokens": [3794, 1211, 3794, 1211, 2655, 9957, 20588, 20449, 8608, 1211, 3794, 1211, 2655, 9957, 33286, 3714, 29245, 23328, 9957, 15844, 13412, 28820, 23319, 15688, 24764, 17620, 44650, 8848, 37983, 9957, 16712, 2655, 23557, 3224, 25708, 2288, 6027, 13672, 1829, 1975, 2655, 3615, 19528, 8315, 3224, 30767, 1829, 39896, 4117, 8032, 47302, 9122, 25720, 6055, 29399, 9957, 8717, 5172, 2655, 43042, 20588, 4032, 20588, 30767, 1829, 39896, 4117, 37495, 22653, 2423, 18568, 45841, 13496, 6055, 29399, 9957, 20588], "avg_logprob": -0.18479567021131516, "compression_ratio": 1.5875706214689265, "no_speech_prob": 0.0, "words": [{"start": 3186.39, "end": 3187.53, "word": "سلسلتين", "probability": 0.8677571614583334}, {"start": 3187.53, "end": 3187.99, "word": " Alpha", "probability": 0.6044921875}, {"start": 3187.99, "end": 3189.09, "word": " مع", "probability": 0.7861328125}, {"start": 3189.09, "end": 3190.15, "word": " سلسلتين", "probability": 0.9939778645833334}, {"start": 3190.15, "end": 3191.05, "word": " Beta", "probability": 0.86767578125}, {"start": 3191.05, "end": 3192.01, "word": " موجودين", "probability": 0.9586181640625}, {"start": 3192.01, "end": 3192.21, "word": " على", "probability": 0.9580078125}, {"start": 3192.21, "end": 3192.69, "word": " شكل", "probability": 0.97607421875}, {"start": 3192.69, "end": 3193.93, "word": " tetrahedral", "probability": 0.726806640625}, {"start": 3193.93, "end": 3194.81, "word": " arrangement", "probability": 0.80078125}, {"start": 3194.81, "end": 3195.99, "word": " متذكرين", "probability": 0.79736328125}, {"start": 3195.99, "end": 3196.89, "word": " التتراهيدرال", "probability": 0.8578752790178571}, {"start": 3196.89, "end": 3197.05, "word": " اللي", "probability": 0.841796875}, {"start": 3197.05, "end": 3197.93, "word": " اتعلمناه", "probability": 0.8777669270833334}, {"start": 3197.93, "end": 3200.85, "word": " زي", "probability": 0.67822265625}, {"start": 3200.85, "end": 3201.21, "word": " هيك", "probability": 0.882568359375}, {"start": 3201.21, "end": 3202.73, "word": " هاي", "probability": 0.5665283203125}, {"start": 3202.73, "end": 3203.13, "word": " كرة", "probability": 0.919677734375}, {"start": 3203.13, "end": 3204.01, "word": " تنتين", "probability": 0.8484700520833334}, {"start": 3204.01, "end": 3205.13, "word": " نفترض", "probability": 0.94384765625}, {"start": 3205.13, "end": 3205.43, "word": " Alpha", "probability": 0.845703125}, {"start": 3205.43, "end": 3205.57, "word": " و", "probability": 0.9169921875}, {"start": 3205.57, "end": 3205.97, "word": " Alpha", "probability": 0.60205078125}, {"start": 3205.97, "end": 3207.71, "word": " زي", "probability": 0.939453125}, {"start": 3207.71, "end": 3207.85, "word": " هيك", "probability": 0.925537109375}, {"start": 3207.85, "end": 3208.01, "word": " يعني", "probability": 0.9072265625}, {"start": 3208.01, "end": 3208.13, "word": " ال", "probability": 0.9775390625}, {"start": 3208.13, "end": 3208.77, "word": " Hemoglobin", "probability": 0.7051188151041666}, {"start": 3208.77, "end": 3209.91, "word": " تنتين", "probability": 0.97021484375}, {"start": 3209.91, "end": 3210.31, "word": " Alpha", "probability": 0.92626953125}], "temperature": 1.0}, {"id": 131, "seek": 322375, "start": 3218.91, "end": 3223.75, "text": "الشيء الجميل ان احنا بدأنا ال course", "tokens": [6027, 8592, 1829, 38207, 25724, 2304, 26895, 16472, 1975, 5016, 8315, 47525, 10721, 8315, 2423, 1164], "avg_logprob": -0.4420955882352941, "compression_ratio": 1.0, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3218.9100000000003, "end": 3220.07, "word": "الشيء", "probability": 0.6621475219726562}, {"start": 3220.07, "end": 3220.63, "word": " الجميل", "probability": 0.9923502604166666}, {"start": 3220.63, "end": 3221.13, "word": " ان", "probability": 0.4365234375}, {"start": 3221.13, "end": 3221.83, "word": " احنا", "probability": 0.8017578125}, {"start": 3221.83, "end": 3222.95, "word": " بدأنا", "probability": 0.7715657552083334}, {"start": 3222.95, "end": 3223.17, "word": " ال", "probability": 0.493408203125}, {"start": 3223.17, "end": 3223.75, "word": " course", "probability": 0.91796875}], "temperature": 1.0}, {"id": 132, "seek": 324156, "start": 3224.9, "end": 3241.56, "text": "في المحاضرة الأولى بال tetrahedral structure والان ننهي ال course بال tetrahedral arrangement اللى موجودة في ال hemoglobin الدرس القادم ان شاء الله بيكون مراجعة وحل امتحانات", "tokens": [41185, 9673, 5016, 46958, 25720, 16247, 12610, 7578, 20666, 23319, 15688, 24764, 3877, 16070, 7649, 8717, 1863, 3224, 1829, 2423, 1164, 20666, 23319, 15688, 24764, 17620, 13672, 7578, 3714, 29245, 23328, 3660, 8978, 2423, 8636, 45841, 13496, 32748, 2288, 3794, 25062, 18513, 2304, 16472, 13412, 16606, 21984, 4724, 1829, 30544, 3714, 2288, 26108, 27884, 4032, 5016, 1211, 1975, 2304, 2655, 5016, 7649, 9307], "avg_logprob": -0.15930175152607262, "compression_ratio": 1.4636871508379887, "no_speech_prob": 0.0, "words": [{"start": 3224.9, "end": 3225.12, "word": "في", "probability": 0.705078125}, {"start": 3225.12, "end": 3225.88, "word": " المحاضرة", "probability": 0.977783203125}, {"start": 3225.88, "end": 3226.68, "word": " الأولى", "probability": 0.974609375}, {"start": 3226.68, "end": 3226.98, "word": " بال", "probability": 0.8740234375}, {"start": 3226.98, "end": 3228.2, "word": " tetrahedral", "probability": 0.8068033854166666}, {"start": 3228.2, "end": 3229.6, "word": " structure", "probability": 0.84326171875}, {"start": 3229.6, "end": 3230.52, "word": " والان", "probability": 0.5167236328125}, {"start": 3230.52, "end": 3231.14, "word": " ننهي", "probability": 0.8387451171875}, {"start": 3231.14, "end": 3231.22, "word": " ال", "probability": 0.5576171875}, {"start": 3231.22, "end": 3231.76, "word": " course", "probability": 0.8974609375}, {"start": 3231.76, "end": 3232.62, "word": " بال", "probability": 0.9267578125}, {"start": 3232.62, "end": 3233.44, "word": " tetrahedral", "probability": 0.9474283854166666}, {"start": 3233.44, "end": 3234.32, "word": " arrangement", "probability": 0.8046875}, {"start": 3234.32, "end": 3234.84, "word": " اللى", "probability": 0.736328125}, {"start": 3234.84, "end": 3235.6, "word": " موجودة", "probability": 0.9583740234375}, {"start": 3235.6, "end": 3236.28, "word": " في", "probability": 0.69091796875}, {"start": 3236.28, "end": 3236.56, "word": " ال", "probability": 0.982421875}, {"start": 3236.56, "end": 3237.38, "word": " hemoglobin", "probability": 0.765869140625}, {"start": 3237.38, "end": 3238.1, "word": " الدرس", "probability": 0.9464518229166666}, {"start": 3238.1, "end": 3238.58, "word": " القادم", "probability": 0.99169921875}, {"start": 3238.58, "end": 3238.68, "word": " ان", "probability": 0.81298828125}, {"start": 3238.68, "end": 3238.9, "word": " شاء", "probability": 0.98779296875}, {"start": 3238.9, "end": 3239.04, "word": " الله", "probability": 0.953125}, {"start": 3239.04, "end": 3239.7, "word": " بيكون", "probability": 0.833984375}, {"start": 3239.7, "end": 3240.42, "word": " مراجعة", "probability": 0.9697265625}, {"start": 3240.42, "end": 3240.86, "word": " وحل", "probability": 0.8312174479166666}, {"start": 3240.86, "end": 3241.56, "word": " امتحانات", "probability": 0.8741861979166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3242.272, "duration_after_vad": 3125.6937499999885}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_postprocess.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f630731c4dd49839f50b244f11f58dfe8e210c07
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_postprocess.srt
@@ -0,0 +1,1844 @@
+1
+00:00:20,990 --> 00:00:24,950
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:24,950 --> 00:00:29,290
+تفاعلات ال alkenes وقلنا اللى بينظر للموضوع نظرة
+
+3
+00:00:29,290 --> 00:00:34,610
+كلية الموضوع بسيط الموضوع انه double bond هيوم
+
+4
+00:00:34,610 --> 00:00:40,230
+رابطتين بالاضافة بتصير single bond هذه العملية شو
+
+5
+00:00:40,230 --> 00:00:46,110
+بنسميها عملية addition عملية addition واتفقنا ان
+
+6
+00:00:46,110 --> 00:00:48,810
+في ال addition فى عندنا مكونات لل addition فى
+
+7
+00:00:48,810 --> 00:00:52,730
+عندنا ال alkeneو في عندنا ال reagent وهذا ممكن
+
+8
+00:00:52,730 --> 00:00:56,610
+يكون symmetric و لا unsymmetric وهذا نفس الشيء و
+
+9
+00:00:56,610 --> 00:00:59,610
+دائما قلنا بدنا ننتبه لو كان في عندنا
+
+10
+00:00:59,610 --> 00:01:03,550
+unsymmetrical alkene مع unsymmetrical reagent
+
+11
+00:01:03,550 --> 00:01:09,070
+بنتوقع انه بيكون عندنا two products الآن هنبدأ
+
+12
+00:01:09,070 --> 00:01:13,510
+ناخد أمثلة على هذا الموضوع تحديدا لو بدنا نتكلم
+
+13
+00:01:13,510 --> 00:01:18,580
+على إضافة الماءإضافة الماء، الماء بيضيف جزء إيه؟
+
+14
+00:01:18,580 --> 00:01:25,940
+بيضيف H و O H هذه العملية بنسميها hydration لاحظوا
+
+15
+00:01:25,940 --> 00:01:30,780
+أنه عمليات الإضافة حسب ال reagent يعني المرة
+
+16
+00:01:30,780 --> 00:01:35,840
+الماضية إحنا لما إضفنا ال hydrogen عملية إضافة ال
+
+17
+00:01:35,840 --> 00:01:42,940
+hydrogen hydrogenation اسمها واضح؟عملية إضافة
+
+18
+00:01:42,940 --> 00:01:49,120
+الهيدروجين الان ممكن نضيف الهالوجين بشكل عام
+
+19
+00:01:49,120 --> 00:01:57,020
+بنسميها الهالوجيناشن طبعا بشكل خاص إكلوريناشن
+
+20
+00:01:57,020 --> 00:02:05,100
+بروميناشن و هكذا ممكن نضيف الميه بنسميها هيدريشن
+
+21
+00:02:05,100 --> 00:02:14,210
+إضافة الميهHydration واضح؟ ممكن نضيف HX خلّينا
+
+22
+00:02:14,210 --> 00:02:22,530
+نقول HBR و لا HCL على الطرفين الرابطة HX بنسميها
+
+23
+00:02:22,530 --> 00:02:27,530
+Hydro لأن فيها Hydrogen Hydro وHalogen
+
+24
+00:02:27,530 --> 00:02:34,730
+Halogenation Hydro Halogenation كل هذه العمليات هي
+
+25
+00:02:34,730 --> 00:02:40,670
+عمليات إيش؟إضافة إذا إليها أسماء hydrogenation,
+
+26
+00:02:40,750 --> 00:02:44,430
+halogenation, hydration, hydrohalogenation
+
+27
+00:02:44,430 --> 00:02:49,010
+ابتفاعلات تانية هنتعلمها بعدين و هتلاحظوا إنه في
+
+28
+00:02:49,010 --> 00:02:53,430
+الكيميا العضوية دائما عندكم الشغلات المتعاكسة
+
+29
+00:02:53,430 --> 00:02:57,770
+بمعنىان ال double bond لما اضيف عليها reagent
+
+30
+00:02:57,770 --> 00:03:01,370
+بتصير single bond يعني لو افترضنا ان هاي double
+
+31
+00:03:01,370 --> 00:03:06,030
+bond اضفت عليها reagent الناتج single bond الان لو
+
+32
+00:03:06,030 --> 00:03:11,470
+هذه ال single bond ابتفاعل تاني رفعت منها شغلتين
+
+33
+00:03:11,470 --> 00:03:16,510
+هتصير double bond اذا انا ممكن اعمل اضافة و ممكن
+
+34
+00:03:16,510 --> 00:03:22,760
+اعمل حذفواضح ال elimination بسميه فزي ما في عند ا
+
+35
+00:03:22,760 --> 00:03:28,840
+addition في عند كمان عكسه elimination هذه عمليات
+
+36
+00:03:28,840 --> 00:03:34,860
+ال elimination أيضا لها أسماء بمعنى لو كنا بنحذف
+
+37
+00:03:34,860 --> 00:03:39,240
+ذرتين هيدروجين و بنعمل double bond تاني هنسمي
+
+38
+00:03:39,240 --> 00:03:44,880
+العملية dehydrogenation هستخدم ل prefix دي هذا
+
+39
+00:03:44,880 --> 00:03:51,360
+للنفيD فحقول dehydrogenation لو كنت برفع زرتين
+
+40
+00:03:51,360 --> 00:03:58,300
+كلور او بروم Dehydrogenation لو كنت برفع HOH
+
+41
+00:03:58,300 --> 00:04:03,900
+Dehydration هذه الكلمة الشهيرة نزع الماء
+
+42
+00:04:03,900 --> 00:04:07,520
+Dehydration
+
+43
+00:04:08,520 --> 00:04:12,700
+لو كنا بنرفع ال .. ال hydrogen وال halogen
+
+44
+00:04:12,700 --> 00:04:17,120
+dehydrohalogenation واضح؟ dehydrohalogenation
+
+45
+00:04:17,120 --> 00:04:21,640
+ولذلك بتلاقوا هذه الكلمة انتبهولها جيدا واحفظوها
+
+46
+00:04:21,640 --> 00:04:26,460
+انتوا في المستقبل بتصيروا أمهات dehydration لما
+
+47
+00:04:26,460 --> 00:04:30,620
+الأطفال الصغار بيمرضوا بتروح فيهم على المستشفيات
+
+48
+00:04:30,620 --> 00:04:35,630
+بيكون ..عندهم جفاف فالطبيب ايش بيقول عنه عنده
+
+49
+00:04:35,630 --> 00:04:40,070
+dehydration يعني فقد الماء اللي عنده صار عنده جفاف
+
+50
+00:04:40,070 --> 00:04:44,350
+فبيسموها بالانجليزي ايش الجفاف dehydration يعني
+
+51
+00:04:44,350 --> 00:04:48,370
+ايه تسمعوا عن الطفل عنده dehydration لازم تعطوه
+
+52
+00:04:48,370 --> 00:04:53,830
+ايش محليل الان اول شئ بدنا نبدأ فيه ال hydration
+
+53
+00:04:53,830 --> 00:04:57,750
+اضافة الماء الان اضافة الماء على طرفين الرابط
+
+54
+00:04:57,750 --> 00:05:05,860
+الزوجية شو هيحط عندهH و OH واضح القصة طبعا في كل
+
+55
+00:05:05,860 --> 00:05:09,920
+شيء في تفاصيل كثيرة لكن احنا احيانا بنتجوزها في ال
+
+56
+00:05:09,920 --> 00:05:12,880
+course العام يعني كيف بنضافه مش مشكلة المهم ان ال
+
+57
+00:05:12,880 --> 00:05:17,600
+double bond راحت ال bi bond ألغيت صارت two new
+
+58
+00:05:17,600 --> 00:05:24,160
+sigma bonds واحدة H واحدة OH هذا التفاعل بشكل عام
+
+59
+00:05:24,160 --> 00:05:31,000
+الان لو اتيت للتفاعل بحالة خاصةأتطلعت على هذا الـ
+
+60
+00:05:31,000 --> 00:05:35,620
+Alkene اللي هو الـ Isobutyl الان لو اتطلعت على هذا
+
+61
+00:05:35,620 --> 00:05:40,380
+ال Isobutyl هتلاحظوا انه Unsymmetrical الكين بمعنى
+
+62
+00:05:40,380 --> 00:05:43,860
+لو اتيت في نص ال bubble bond اتخيلت اني بدأ اجسم
+
+63
+00:05:43,860 --> 00:05:50,680
+نصين هلعنى C ايش بتحمل؟H و H مختصرات وهنا C بتحمل
+
+64
+00:05:50,680 --> 00:05:57,620
+CH3 و CH3 طيب لما أنا بدي أضيف الميه نتخيل الميه
+
+65
+00:05:57,620 --> 00:06:02,560
+هدول الجزئين الأزرق و الأحمر بدي أضيف الميه هل يا
+
+66
+00:06:02,560 --> 00:06:07,620
+تورا ال H نعتبرها الزرقه نعتبر ال H الزرقه و ال OH
+
+67
+00:06:07,620 --> 00:06:12,980
+الحمره هل يا تورا بدي أحط هنا ال H و هنا ال OH ولا
+
+68
+00:06:12,980 --> 00:06:15,200
+هنا ال H و هنا ال OH
+
+69
+00:06:19,900 --> 00:06:24,640
+من الناحية النظرية البحتة، من ناحية النظرية
+
+70
+00:06:24,640 --> 00:06:29,560
+البحتة، لو احنا بنقول لطفل صغير تعال شيل هادي وحق
+
+71
+00:06:29,560 --> 00:06:36,060
+التنتين، ممكن يعمل هيك و ممكن يعمل هيك، من ناحية
+
+72
+00:06:36,060 --> 00:06:41,000
+النظرية البحتة، الأمرين ممكنين، مافيش فيهم ولا
+
+73
+00:06:41,000 --> 00:06:47,280
+مشكلةالان هدولة الأمرين احنا اعطيناهم اسماء قولنا
+
+74
+00:06:47,280 --> 00:06:53,500
+اذا بنضيف الهيدروجين على الكربون اللى بتحمل
+
+75
+00:06:53,500 --> 00:06:57,520
+هيدروجين اكثر هذه الان لو فصلناها بشكل كامل هي
+
+76
+00:06:57,520 --> 00:07:03,850
+عبارة عن C بتحمل H وHتمام؟ هذه C لا تحمل اش ولا
+
+77
+00:07:03,850 --> 00:07:08,950
+اتش لو ضفنا الهيدروجين على الكاربون اللي حامل
+
+78
+00:07:08,950 --> 00:07:13,630
+هيدروجين اكثر بنقول هذه الإضافة حسب قواعد
+
+79
+00:07:13,630 --> 00:07:17,650
+Markovnikov أو حسب قاعدة Markovnikov وقتها بروح
+
+80
+00:07:17,650 --> 00:07:22,190
+بحط ال H هنا نفترض باللون الأزرق و ال O أتش هنا و
+
+81
+00:07:22,190 --> 00:07:28,710
+بطلع عندى ناتج واضح؟ ان جرب نعمل الجواب لو جربنا
+
+82
+00:07:28,710 --> 00:07:36,900
+هنحط CCH3 CH3 وهذه ستصبح single bond CH2 هذا ما
+
+83
+00:07:36,900 --> 00:07:46,540
+كان موجود أصلا كله ما جاء عليه H و OH الأن بهذا
+
+84
+00:07:46,540 --> 00:07:50,560
+الشكل الهيدروجين جاء على أي كربون على اللي حملة
+
+85
+00:07:50,560 --> 00:07:56,940
+هيدروجين أكتر وهذه الإضافة بنسميها إضافة حسب قاعدة
+
+86
+00:07:56,940 --> 00:07:58,140
+Markov-Nikov
+
+87
+00:08:05,760 --> 00:08:11,760
+ماركوف نيكوفز اديشن اضافة ماركوف نيكوفز اضافة
+
+88
+00:08:11,760 --> 00:08:12,480
+ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف
+
+89
+00:08:12,480 --> 00:08:14,080
+نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز
+
+90
+00:08:14,080 --> 00:08:14,240
+اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة
+
+91
+00:08:14,240 --> 00:08:14,300
+ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف
+
+92
+00:08:14,300 --> 00:08:15,260
+نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز
+
+93
+00:08:15,260 --> 00:08:19,420
+اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة
+
+94
+00:08:19,420 --> 00:08:26,320
+ماركوف نيكوفز اضافCH3 CH3 وهخلّي هذه single bond
+
+95
+00:08:26,320 --> 00:08:31,380
+CH2 هاي الألكين الأصلي و أحطهم بالعكس يعني ال H
+
+96
+00:08:31,380 --> 00:08:41,120
+هنا و ال OH هنا إيش
+
+97
+00:08:41,120 --> 00:08:49,170
+المانع؟مش مانع هاي إضافة مية وهي إضافة مية هذه
+
+98
+00:08:49,170 --> 00:08:54,330
+الإضافة بنعطيها اسم بنقولها Anti-Markovnikov
+
+99
+00:08:54,330 --> 00:08:58,650
+addition إضافة عكس قاعدة Markovnikov
+
+100
+00:09:03,760 --> 00:09:07,420
+Nikov's addition إذا يمكن أن تكون الإضافة زيك
+
+101
+00:09:07,420 --> 00:09:10,380
+ويمكن أن تكون زيك هتقولوا طب وإحنا شو بده يعرفنا
+
+102
+00:09:10,380 --> 00:09:16,380
+كيف نعمل الإضافة بنقول أه حسب ال reagent المستعمل
+
+103
+00:09:16,380 --> 00:09:22,200
+الماء يمكن أن يضيف بهذا الشكل وينتج المركب اللي
+
+104
+00:09:22,200 --> 00:09:25,960
+أمامنا هنا على الجهة اليامين ويمكن أنه يضيف بالشكل
+
+105
+00:09:25,960 --> 00:09:31,500
+التاني وينتج مركب تانيممكن يعطي ناتج إضافة حسب
+
+106
+00:09:31,500 --> 00:09:35,480
+قاعدة Markovnikov وممكن يعطي عكسها هتقولولنا طب
+
+107
+00:09:35,480 --> 00:09:39,440
+وقت إيش بيعمل هيك ووقت إيش بيعمل هيك الجواب بسيط
+
+108
+00:09:39,440 --> 00:09:42,680
+لأ وإحنا بنحكي الصورة الكلية اللي تفهم من خلالها
+
+109
+00:09:42,680 --> 00:09:46,440
+إذا كانت إضافة الماء يعني هنا على السهم كتبنا
+
+110
+00:09:46,440 --> 00:09:51,980
+الماء في وجود الحامض H plus فإنه يضيف حسب قاعدة
+
+111
+00:09:51,980 --> 00:09:57,190
+Markovnikovإذا عرفنا ما الشرط الذي من خلاله تتم
+
+112
+00:09:57,190 --> 00:10:02,570
+الإضافة حسب قاعدة Markov Nikov أن نضيف الماء في
+
+113
+00:10:02,570 --> 00:10:08,950
+وجود كمية قليلة من الحامض وجدها بنضيف حسب قاعدة
+
+114
+00:10:08,950 --> 00:10:17,600
+Markov Nikovالان طب كيف بضيف عكس قاعدة Markovnikov
+
+115
+00:10:17,600 --> 00:10:21,200
+إذا
+
+116
+00:10:21,200 --> 00:10:28,020
+ضفنا الماء باستعمال reagent مختلف طبعا ظروف كاملة
+
+117
+00:10:28,020 --> 00:10:34,520
+مختلفة باستعمال مركب ال borane اللي بنقوله BH3طبعا
+
+118
+00:10:34,520 --> 00:10:39,660
+بعد هيكذا البرين بنحط عليه H2O2 هيدروجين بيروكسايد
+
+119
+00:10:39,660 --> 00:10:46,180
+لو ضفنا في وجود هذه المتفاعلات بضيف عكس قاعدة
+
+120
+00:10:46,180 --> 00:10:52,160
+ماركوف نيكوفطبعا ربما الآن بدت الصورة تتضح لكم
+
+121
+00:10:52,160 --> 00:10:56,980
+لأنه انا حاسس الصمت عندكم لأن انتوا اتعلمتوا نص
+
+122
+00:10:56,980 --> 00:11:01,180
+المعلومة بالثانوية انه الإضافة فقط حسب قاعدة
+
+123
+00:11:01,180 --> 00:11:05,560
+Markovnikov حسب قاعدة Markovnikov ضمن هذا الشرط
+
+124
+00:11:05,560 --> 00:11:11,480
+غير الشرط تحصل على إضافة عكس قاعدة Markovnikov إذا
+
+125
+00:11:11,480 --> 00:11:17,710
+الأمرين ممكنين واضح؟ اللي اتعلمتوا بالثانويةنص
+
+126
+00:11:17,710 --> 00:11:23,030
+القصة مش كل القصة، واضح؟ اللي اتعلمته بالثانوية
+
+127
+00:11:23,030 --> 00:11:29,390
+نصف هذه القصة مش كلها فقط، الآن احنا استكملنا
+
+128
+00:11:29,390 --> 00:11:32,850
+القصة لكم، اننا نقولكم لأ والله يا المية بتضيف
+
+129
+00:11:34,860 --> 00:11:39,160
+الميّه بتضيف بالطريقتين هذا الكلام بعد شوية
+
+130
+00:11:39,160 --> 00:11:43,520
+هتلاحظوه مش بسمع الميّه هذا الكلام بعد شوية
+
+131
+00:11:43,520 --> 00:11:49,200
+هتلاحظوه مش بسمع الميّه هتلاحظوه حتى مع ال HPR على
+
+132
+00:11:49,200 --> 00:11:52,920
+سبيل المثال يعني لو أخذنا نفس ال ال keen اللي كان
+
+133
+00:11:52,920 --> 00:11:56,820
+عندنا هان عارفينه ال C double bond C
+
+134
+00:11:59,940 --> 00:12:08,040
+CH3 و CH3 و قلنا بدنا نكمله باتجاهين مع الـHBr و
+
+135
+00:12:08,040 --> 00:12:13,520
+هنا كمان كتبنا HBr لو قلنا بدنا نكمل التفاعل مع
+
+136
+00:12:13,520 --> 00:12:20,460
+HBr في وجود H Plus سيضيف حسب قاعدة Markov Nikov و
+
+137
+00:12:20,460 --> 00:12:24,520
+لو قلنا بدنا نكمل التفاعل مع الـHBr في وجود
+
+138
+00:12:24,520 --> 00:12:30,160
+بيروكسايد سيضيف عكس قاعدة Markov Nikovالناتج
+
+139
+00:12:30,160 --> 00:12:33,340
+ببساطة نفس اللي موجود عندكم بدل كلمة OH اللي
+
+140
+00:12:33,340 --> 00:12:34,660
+بالأحمر شو بتحطه
+
+141
+00:12:41,060 --> 00:12:46,580
+إذا إضافة الماء أو إضافة الـ HPR يمكن أن تتم
+
+142
+00:12:46,580 --> 00:12:51,360
+بطريقة ولا بطريقتين وهنا بيصير مهم عندي جدا أن
+
+143
+00:12:51,360 --> 00:12:55,460
+أنتبه لل reactant للمتفاعل يعني لو احنا مرات بدنا
+
+144
+00:12:55,460 --> 00:12:59,840
+نسألكوا عن هذا الموضوع ممكن نجيبلكوا ال reactant
+
+145
+00:12:59,840 --> 00:13:03,100
+مع هذا نقولكوا اكتبوا النتيجة ممكن نجيب هذا ال
+
+146
+00:13:03,100 --> 00:13:06,300
+reactant و ال product و نقولكوا شو اللي استعملته
+
+147
+00:13:06,300 --> 00:13:11,620
+كمتفاعل كتبولي ال reactant اللي على السهلواضحك
+
+148
+00:13:11,620 --> 00:13:16,680
+الصورة؟ طبعا لو إجينا سألنا هذه النواتج ال
+
+149
+00:13:16,680 --> 00:13:20,100
+markovnikov product هذا بيسموه markovnikov product
+
+150
+00:13:20,100 --> 00:13:26,020
+و ال antimarkovnikov product ما العلاقة بينهما؟
+
+151
+00:13:26,020 --> 00:13:30,000
+isomers
+
+152
+00:13:30,000 --> 00:13:32,540
+أي نوع من ال isomers هذا اللي بقصدي
+
+153
+00:13:36,070 --> 00:13:40,470
+الـ Markovnikov's product والـ Antimarkovnikov's
+
+154
+00:13:40,470 --> 00:13:45,250
+product They are isomers ليش؟ لأنه نفس الذرات
+
+155
+00:13:45,250 --> 00:13:50,610
+وحطيت H و OH حطيت ال H و OH بنفس المواقع ولا
+
+156
+00:13:50,610 --> 00:13:57,670
+بمواقع مختلفة طالما مواقع مختلفة Different bonding
+
+157
+00:13:57,670 --> 00:14:04,290
+عطول الجواب Structural isomers They are structural
+
+158
+00:14:04,290 --> 00:14:09,910
+isomersمش فيها نقاش مش ارتبطوا الذرات من مواقع
+
+159
+00:14:09,910 --> 00:14:13,210
+مختلفة هنا الهيدروجين على الأولى و ال OH على
+
+160
+00:14:13,210 --> 00:14:17,470
+التانية هنا ال OH على الأولى و ال H على التانية صح
+
+161
+00:14:17,470 --> 00:14:20,570
+ولا لأ different bonding different names
+
+162
+00:14:20,570 --> 00:14:27,490
+structural isomers واضح إذا فكرة إضافة ال
+
+163
+00:14:27,490 --> 00:14:33,850
+unsymmetrical agents ممكن تضيفطريقتين ماركوف نيكوف
+
+164
+00:14:33,850 --> 00:14:37,450
+وانتي ماركوف نيكوف حسب ظروف التفاعل شو الأمثلة
+
+165
+00:14:37,450 --> 00:14:43,840
+المطلوب من ان اعرفها الماءو ال HVR بدون تفاصيل
+
+166
+00:14:43,840 --> 00:14:47,600
+الميكانيزم اللي أحيانا ممكن تلاقوها موجودة عندكم
+
+167
+00:14:47,600 --> 00:14:50,920
+يعني أنا في النهاية ال course general organic
+
+168
+00:14:50,920 --> 00:14:56,340
+course بهمني تصلوا فيه للنتيجة بشكل عام ولذلك على
+
+169
+00:14:56,340 --> 00:14:59,960
+طول الآن ممكن ناخد أمثلة إضافية و تشوفوا كيف
+
+170
+00:14:59,960 --> 00:15:04,520
+الأمثلة الإضافية بنكملها بدون ما ندخل بتفاصيل كيف
+
+171
+00:15:04,520 --> 00:15:08,260
+تمت العملية المهم عنده النتج
+
+172
+00:15:19,100 --> 00:15:22,820
+الشرط اللي بتتم فيه الإضافة عكس قاعدة Markovnikov
+
+173
+00:15:22,820 --> 00:15:27,160
+موجود في هذا ال slide لاحظوا لأنه بضيف مركب اسمه
+
+174
+00:15:27,160 --> 00:15:32,960
+BH3 ال بي بورون مش بروم انتبه بورون ال بورون لما
+
+175
+00:15:32,960 --> 00:15:36,760
+تيجي على الجدول الدوري في أوله اللي هو العنصر
+
+176
+00:15:36,760 --> 00:15:43,920
+الخامس هيدروجين هيليوم ليثيوم بيريليوم بورونBoron
+
+177
+00:15:43,920 --> 00:15:50,200
+الأنصار الخامس تمام لما يكون BH3 بنسميه borane هذا
+
+178
+00:15:50,200 --> 00:15:52,500
+بنسميه بورين
+
+179
+00:15:55,140 --> 00:16:01,340
+الان هذا ال borane في وجود solvent THF اسمه تترا
+
+180
+00:16:01,340 --> 00:16:04,640
+هيدرو فيوران solvent مش مشكلة بالنسبالي ان كل
+
+181
+00:16:04,640 --> 00:16:11,000
+تفاعل بتم في وجود مضيب بنضيف ال borane مع ال THF
+
+182
+00:16:11,000 --> 00:16:15,240
+في خطوة أولى بنحركهم لفترة معينة و بعدين على نفس
+
+183
+00:16:15,240 --> 00:16:23,390
+التفاعل بنضيف H2O2 hydrogen peroxideماء الأكسجين
+
+184
+00:16:23,390 --> 00:16:26,050
+اللي بيستعملوها بتثبيت الشعر وغيرها في basic
+
+185
+00:16:26,050 --> 00:16:32,110
+medium في وجود OH- الان انا دائما بهمني تفهمين
+
+186
+00:16:32,110 --> 00:16:36,450
+الفكرة الرئيسية يعني ماتوهوش كتير في التفاصيل
+
+187
+00:16:36,450 --> 00:16:39,530
+ولذلك لما انا بكون بدي افهم الفكرة الرئيسية لو
+
+188
+00:16:39,530 --> 00:16:43,730
+واحدة فكرت كل هدول وقعدت بتحفظهم بتوه لأ انا بهمني
+
+189
+00:16:43,730 --> 00:16:47,850
+ببساطة في الأول الفكرة الأساسية ان الماء يضيف
+
+190
+00:16:47,850 --> 00:16:52,800
+بطريقتين واضحة ولا لأيضيف Markovnikov في وجود H+,
+
+191
+00:16:52,800 --> 00:16:57,700
+واضح ولا لأ؟ وبقول ببساطة يضيف Anti-Markovnikov
+
+192
+00:16:57,700 --> 00:17:01,480
+بطريقة البرون، الآن أنا اللي بسميها طريقة البرون،
+
+193
+00:17:01,480 --> 00:17:05,660
+لأن طريقة البرون مجموعة من الأشياء موجودة في الكتب
+
+194
+00:17:05,660 --> 00:17:08,560
+وما إلى ذلك، وبنكتوب الكتابة على السهم، مابديش
+
+195
+00:17:08,560 --> 00:17:13,450
+أتقوه إن أقعد أحفظ هدولة بدون ما أكون فهمت؟الشئ
+
+196
+00:17:13,450 --> 00:17:17,570
+الرئيسي كذلك الحالة لبروم ال HPR عفوا بيضيف
+
+197
+00:17:17,570 --> 00:17:22,810
+بطريقتين في وجود H plus ماركوفنيكوف في وجود مواد
+
+198
+00:17:22,810 --> 00:17:27,350
+بيسميها البروكسايد فوق الأكسد انتي ماركوفنيكوف
+
+199
+00:17:27,350 --> 00:17:31,570
+يعني هتلاحظوا ان عندكم HPR و مكتوب لك بيروكسايد
+
+200
+00:17:31,570 --> 00:17:39,330
+اذا وجدتها التنفيذ انتي ماركوفنيكوفسابقا كان عندى
+
+201
+00:17:39,330 --> 00:17:43,290
+ناس ممتازين اللى بيحاولوا يفهموا الأمور في الأول
+
+202
+00:17:43,290 --> 00:17:46,110
+بالصورة الكلية قبل ما يخوضوا بالتفاصيل بعض منكم
+
+203
+00:17:46,110 --> 00:17:49,370
+بيتعب لإنه بيصير يخوض بالتفاصيل و الأشياء قبل ما
+
+204
+00:17:49,370 --> 00:17:53,770
+يفهم الصورة الكلية هدولة الناس الممتازين طلبت منهم
+
+205
+00:17:53,770 --> 00:17:57,570
+كان شعراء انه يلخصوا ال organ ال chemistry شعرا
+
+206
+00:17:58,290 --> 00:18:03,030
+بلغة بسيطة وهذا اللي بنصحكم يوم الامتحان تدرسوه ما
+
+207
+00:18:03,030 --> 00:18:06,610
+تقعدوش بس تكتبوا الأشياء دي و تفهموا لا افهموا
+
+208
+00:18:06,610 --> 00:18:11,170
+الأفكار الرئيسية الأفكار الرئيسية ببساطة اللي قلنا
+
+209
+00:18:11,170 --> 00:18:16,490
+ساعتين فيها تفهم بدقيقتين ال double bond تفعلها
+
+210
+00:18:16,490 --> 00:18:22,100
+الأساس إضافةالهيدروجين يضيف بشكل متماثل من جهة
+
+211
+00:18:22,100 --> 00:18:27,760
+واحدة البرومين يضيف من جهتين الأشياء زي الـH2O و
+
+212
+00:18:27,760 --> 00:18:31,900
+الـHBr ممكن تضيف مع قاعدة ماركوف نيكوف عكس قاعدة
+
+213
+00:18:31,900 --> 00:18:35,180
+ماركوف نيكوف تضيف مع قاعدة ماركوف نيكوف في وجود
+
+214
+00:18:35,180 --> 00:18:40,120
+الحامض تضيف عكس قاعدة ماركوف نيكوف الماء في وجود
+
+215
+00:18:40,120 --> 00:18:43,480
+البرون و الـHBr في وجود البروكسايد
+
+216
+00:18:45,830 --> 00:18:49,310
+هذا كل الكلام اللي احنا حكيناه ماحكيناش ولا كلمة
+
+217
+00:18:49,310 --> 00:18:53,170
+غيره بهذا الشكل بتصير ال organic عندكم سهلة و
+
+218
+00:18:53,170 --> 00:18:58,870
+ممتعة هعندي HPR طبعا ال HPR في نهاية بده يحط H و
+
+219
+00:18:58,870 --> 00:19:03,970
+PR ع دابل بوند هذه كانت CH2 صارت CH3 و انا PR هذا
+
+220
+00:19:03,970 --> 00:19:12,370
+مثال عام لكن لو اجينا على مثال متخصص زي هذا المثال
+
+221
+00:19:12,370 --> 00:19:21,590
+هذا الكربون كام هيدروجين عليهامباشر هذه واحدة
+
+222
+00:19:21,590 --> 00:19:24,070
+طلع هذه متصلة ب carbon
+
+223
+00:19:27,380 --> 00:19:33,680
+بعد انا بحكي عن الاتصال المباشر مش موراء ما بعد
+
+224
+00:19:33,680 --> 00:19:38,460
+بعد حيفا شو مالي و ماله هذا اه هنا هيدروجين تان
+
+225
+00:19:38,460 --> 00:19:42,400
+مباشر هنا هيدروجين و كرمون مين عليها هيدروجين اكثر
+
+226
+00:19:42,400 --> 00:19:48,780
+هذه بناء على ذلك لما انا بقول بدي اضيف HPR في وجود
+
+227
+00:19:48,780 --> 00:19:53,320
+H Plus وين اجت الهيدروجين؟ بهذا الشكل وين اجت ال
+
+228
+00:19:53,320 --> 00:20:02,760
+PR؟ بهذا الشكل واضح؟هي اللي بديها دلوقت بتجي
+
+229
+00:20:02,760 --> 00:20:09,060
+بالجهتين، من فوق و من تحت، قليلا بس شويه هذه
+
+230
+00:20:09,060 --> 00:20:14,000
+الفكرة متطورة اكثر من ان ابيع فيها بقى بتيجي من
+
+231
+00:20:14,000 --> 00:20:17,260
+فوق و من تحت يعنى، بس مش موضوعنا لإنه علاقة
+
+232
+00:20:17,260 --> 00:20:22,410
+بالستيل و كيميسترا، الآن هاي مركب تانيهي عندكم
+
+233
+00:20:22,410 --> 00:20:27,170
+double bond وين الطرفين ال double bond؟ هدى و هدى،
+
+234
+00:20:27,170 --> 00:20:33,570
+الآن هنا في شيء مش مرسوم ولا لأ؟ أكيد ال H الأكيد
+
+235
+00:20:33,570 --> 00:20:35,150
+ال H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال
+
+236
+00:20:35,150 --> 00:20:35,390
+H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+237
+00:20:35,390 --> 00:20:35,870
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+238
+00:20:35,870 --> 00:20:35,890
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+239
+00:20:35,890 --> 00:20:36,110
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+240
+00:20:36,110 --> 00:20:36,610
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+241
+00:20:36,610 --> 00:20:39,010
+الأكيد ال H ال أكيد ال H ال أكيد ال H ال أكيد ال H
+
+242
+00:20:39,010 --> 00:20:44,980
+ال أكيد ال H ال أكيد ال H الإذا لو أنا كنت بدى
+
+243
+00:20:44,980 --> 00:20:51,000
+أكمل HPR في وجود H Plus كيف سأكتب الناتج؟ يعني لو
+
+244
+00:20:51,000 --> 00:20:57,060
+أنه أكمل المعادلة HPR H Plus بدى أحط الهيدروجين ع
+
+245
+00:20:57,060 --> 00:21:02,360
+اللي حاملة هيدروجين أكتر يعني بدى أحطها ناسيه H3
+
+246
+00:21:02,360 --> 00:21:12,340
+وH هدولة اللي كانوا أصلا وجدت بدى أحط ال H تحتو ال
+
+247
+00:21:12,340 --> 00:21:18,800
+PR على هذا الكربون هذه إضافة ماركوفنيكوف الان لما
+
+248
+00:21:18,800 --> 00:21:24,560
+نيجي نعطيكم كملوا المعادلة HPR في وجود البروكسايد
+
+249
+00:21:24,560 --> 00:21:29,300
+بدي أحط بالعكس بدي أحط بالعكس ولذلك لو بتيجي
+
+250
+00:21:29,300 --> 00:21:33,080
+تتطلعوا هنا وين ال PR موجودة على أي كربون
+
+251
+00:21:35,850 --> 00:21:39,270
+هيها طبعا هو ورا السماء مرة لتحت و مرة لفوق هذا
+
+252
+00:21:39,270 --> 00:21:43,710
+السؤال الذكي اللي سألته زملتكوا بس بدناش نطول فيه
+
+253
+00:21:43,710 --> 00:21:46,830
+بيجعل
+
+254
+00:21:46,830 --> 00:21:51,550
+جهتين مش فيها مشكلة بس في كل الأحوال على أي carbon
+
+255
+00:21:51,550 --> 00:21:56,560
+إجت ال PRعلى حملة الهيدروجين على أي كاربون إجت
+
+256
+00:21:56,560 --> 00:22:00,840
+الهيدروجين على اللي أقل هذي Markov Nikov ولا أنت
+
+257
+00:22:00,840 --> 00:22:05,680
+Markov Nikov؟ أنا مابديش ياكلتوه في الشكل فوق و
+
+258
+00:22:05,680 --> 00:22:11,140
+تحت، حطوهم بس بالموقع الصح و غلط و مكفي، واضح؟
+
+259
+00:22:11,140 --> 00:22:15,140
+يعني لما بنكمل هذه المعادلة، ببساطة إيش يكون
+
+260
+00:22:15,140 --> 00:22:24,560
+الجواب؟ هنا ال H وهنا ال PRهك النتج بدون يصفر اكتر
+
+261
+00:22:24,560 --> 00:22:29,580
+من هيك تفصيل مابلزمنيش هذه مع ولا عكس Markovnikov
+
+262
+00:22:29,580 --> 00:22:33,700
+لما يكون هيك جوابه لغير ال double bond عكس
+
+263
+00:22:33,700 --> 00:22:38,500
+Markovnikov هنا ال H هنا ال PR مع Markovnikov
+
+264
+00:22:38,500 --> 00:22:39,200
+فاهمنا؟
+
+265
+00:22:50,600 --> 00:22:58,020
+بيجينا بعد هذه الإضافة إضافة جديدة هذه الإضافة
+
+266
+00:22:58,020 --> 00:22:59,980
+الجديدة
+
+267
+00:23:01,170 --> 00:23:07,110
+ان برضه احنا بنلغي فيها ال double bond و بنعمل two
+
+268
+00:23:07,110 --> 00:23:11,010
+new sigma bonds لكن هدول ال two new sigma bonds
+
+269
+00:23:11,010 --> 00:23:15,450
+بيكونوا على نفس ذرة ال oxygen ولذلك بيعطوني حلقة
+
+270
+00:23:15,450 --> 00:23:19,250
+ثلاثية لاحظوا هذا الكلام كيف هي عندكم carbon
+
+271
+00:23:19,250 --> 00:23:24,450
+carbon double bond صح ولا لأ الان لو فعلناها مع
+
+272
+00:23:24,450 --> 00:23:31,330
+bare acidBear بادئة معناها فوق يعني فيه ازيادة
+
+273
+00:23:31,330 --> 00:23:40,170
+الحامض العضوي كام أكسوجين فيه عادة ال acid؟ تنتيل
+
+274
+00:23:40,170 --> 00:23:44,570
+تلت روابط مع الأكسوجين يعني ال acid شكله العام
+
+275
+00:23:44,570 --> 00:23:55,300
+بهذا الشكل R C double bond O OH مشاكل الحامض؟RCOH
+
+276
+00:23:55,300 --> 00:23:59,640
+لو كانت هذه CH3 بيكون الاسيتك أسد لو كانت فنل
+
+277
+00:23:59,640 --> 00:24:05,260
+بيكون ال بنزويك أسد الان لو اجينا جنب ال COH
+
+278
+00:24:05,260 --> 00:24:12,400
+هتضيفنا كمان O يعني خلينا COOH زي هذا المركب اللي
+
+279
+00:24:12,400 --> 00:24:17,700
+هنا RCOOH
+
+280
+00:24:17,700 --> 00:24:24,640
+هذا زاد عندى بإيش؟بأكسوجينة صار فيه تلت أكسوجينات
+
+281
+00:24:24,640 --> 00:24:28,640
+هذا كام أكسوجينة في تنتين الآن هذا المركب اللي
+
+282
+00:24:28,640 --> 00:24:34,920
+صيرته العامة R C double bond O O O H بنسميه pear
+
+283
+00:24:34,920 --> 00:24:41,230
+acid فوق حامضيعني زاد فيه ال oxygen بمقدار ضرر
+
+284
+00:24:41,230 --> 00:24:46,310
+يعرفنا إيش معنى pear acid و لما نسميه بنسميه على
+
+285
+00:24:46,310 --> 00:24:49,570
+اسم الحامض الأصلي اللي كان موجود يعني لو افترضنا
+
+286
+00:24:49,570 --> 00:24:54,810
+الحامض الأصلي acidic acidبصير اللي فيه أكسجينة
+
+287
+00:24:54,810 --> 00:25:01,350
+زيادة بير أسيتك أسد، بنزويك أسد، بير بنزويك أسد،
+
+288
+00:25:01,350 --> 00:25:06,930
+يعني نفس الحامض تماما بس بنزيد عليه إيش؟ بير، يمكن
+
+289
+00:25:06,930 --> 00:25:12,590
+مرت عليكم لما أخدتوا أحماض الكلور مع الأكسجين لما
+
+290
+00:25:12,590 --> 00:25:18,510
+أخدتوا ال بيريكلوريك أسدمش كان عندكوا ClO3 لكلوريك
+
+291
+00:25:18,510 --> 00:25:25,530
+أسد لما صار ClO4 زاد أكسوجينة بيريكلوريك أسد واضح
+
+292
+00:25:25,530 --> 00:25:31,230
+فبير هنا بمعنى إيش الزيادة لو فعلنا الالكين مع
+
+293
+00:25:31,230 --> 00:25:36,480
+البر أسدمرة تانية بتنكسر ال double bond و بتعمل
+
+294
+00:25:36,480 --> 00:25:40,900
+رابطتين sigma لكن مع نفس ذرة ال oxygen اذا هذه
+
+295
+00:25:40,900 --> 00:25:48,220
+العملية ايضا عملية ايش اضافة تحويل ال by bond الى
+
+296
+00:25:48,220 --> 00:25:54,080
+two new sigma bonds اضافة ولا مش اضافة اضافة لكن
+
+297
+00:25:54,080 --> 00:25:56,880
+الان ال two new sigma bonds على نفس ال oxygen
+
+298
+00:25:56,880 --> 00:26:04,040
+فالناتج حلقة ثلاثيةالناتج حلقة ثلاثية هذه الحلقة
+
+299
+00:26:04,040 --> 00:26:10,460
+الثلاثية من ذرتين كربون و من أكسوجينة حلقة ثلاثية
+
+300
+00:26:10,460 --> 00:26:14,560
+ذرتين كربون و أكسوجينة هذه الثلاث ذرات تعونها الآن
+
+301
+00:26:14,560 --> 00:26:21,140
+هذه الحلقة الثلاثية كعائلة بيسموها ابوكسايد يعني
+
+302
+00:26:21,140 --> 00:26:25,380
+لو قلتلكم ما هي عائلة الابوكسايد لاحظوا family في
+
+303
+00:26:25,380 --> 00:26:29,660
+عندنا family و في عندنا في جوا ال family ايش أفراد
+
+304
+00:26:30,500 --> 00:26:33,720
+هك بتكون تفهموا الكيميا ان في العائلة العامة زي ال
+
+305
+00:26:33,720 --> 00:26:40,800
+ketones ال ketone family عائلة الآن جواتها acetone
+
+306
+00:26:40,800 --> 00:26:46,740
+وcyclohexanone وكذا وكذا ال alkenes عائلة جواتها
+
+307
+00:26:46,740 --> 00:26:53,910
+methane إيثين بروبين الآن ال epoxidesعائلة أيضا مش
+
+308
+00:26:53,910 --> 00:26:59,130
+اسم مركّب الابوكسايد عائلة الان طب ايش في جوات هذه
+
+309
+00:26:59,130 --> 00:27:05,730
+العائلة مركّبات؟ carbon تانو اكسوجينة وين بدو يصير
+
+310
+00:27:05,730 --> 00:27:10,630
+الخلاف؟ بدو يصير الخلاف في هدول المجموعات هل هدول
+
+311
+00:27:10,630 --> 00:27:14,130
+الأربعة هيدروجينز؟ هل واحدة فيهم مثل؟ هل تنتين
+
+312
+00:27:14,130 --> 00:27:16,910
+مثل؟ هل التلاتة مثل؟ هل الأربعة مثل؟ هل واحدة إثل؟
+
+313
+00:27:16,910 --> 00:27:23,540
+هل واحدة بروبل؟وجدتها بيصير لكل مركب اسم طب كيف
+
+314
+00:27:23,540 --> 00:27:28,760
+بنسمي كل مركب؟ العملية سهلة بنيجي بنسأل نفسنا إيش
+
+315
+00:27:28,760 --> 00:27:36,160
+اسم الألكين الأصلي تبعه اللي كونه؟والناتج لما
+
+316
+00:27:36,160 --> 00:27:39,900
+نعمله بنسميه باسم الالكين بنضيف عليه oxide يعني
+
+317
+00:27:39,900 --> 00:27:46,200
+مثلا لو كان الالكين اللي عندكم CH2 double bond CH2
+
+318
+00:27:46,200 --> 00:27:53,580
+هين حددنا مركب محدد هذا إيش اسمه اثيلين او اثيل
+
+319
+00:27:53,580 --> 00:27:59,300
+اثيلين الآن فعلنا مع ال bare acid هذا اللي موجود
+
+320
+00:27:59,300 --> 00:28:05,840
+عندناهتلتغي هذه الـ bi-bond وتعطيني أكسوجينة صار
+
+321
+00:28:05,840 --> 00:28:11,480
+عندى CH2 خلّيني نخلي الهيدروجين يخلع برا مرسومين
+
+322
+00:28:11,480 --> 00:28:14,620
+CH2
+
+323
+00:28:14,620 --> 00:28:23,280
+CH2 و هنا أكسوجين الآن هذا من أي مركب نتاج من
+
+324
+00:28:23,280 --> 00:28:30,910
+الإثالين شو بدي أسميه إثالين أكسيد نسبة للأصلإذا
+
+325
+00:28:30,910 --> 00:28:35,970
+تسمية هذه المراكبات تسمية هذه المراكبات كل فرد
+
+326
+00:28:35,970 --> 00:28:42,350
+منها كيف بسميه باسم القلقين الأصلي مضاف إليه كلمة
+
+327
+00:28:42,350 --> 00:28:49,350
+أكسايد أثالين أكسايد واضحة الفكرة ولا لأ ماشي
+
+328
+00:28:49,350 --> 00:28:53,410
+أتأكد أنها واضحة ولا لأ الآن لو اني جيبت هذا
+
+329
+00:28:53,410 --> 00:28:58,310
+المراكب في الامتحان وقلتلك لو سمحته سمولي هذا
+
+330
+00:28:58,310 --> 00:29:04,760
+المراكبزي هيك هذا جايكوا في الامتحان و أنا قلتلكوا
+
+331
+00:29:04,760 --> 00:29:11,860
+صموه واحدة
+
+332
+00:29:11,860 --> 00:29:15,960
+بس Cyclohexane
+
+333
+00:29:15,960 --> 00:29:22,210
+Oxide بتكون تقولوا هذا إيش كان أصلاهي اللي شيلت
+
+334
+00:29:22,210 --> 00:29:26,990
+هذه .. هذا أصلا كان هيك لما ضيفت عليه شيلت ال
+
+335
+00:29:26,990 --> 00:29:30,910
+double bond و حطيت ال oxygen طب زي هيك إيش اسمه؟
+
+336
+00:29:30,910 --> 00:29:41,120
+Cyclohexane شيلنا هذه صار Cyclohexane oxideواضح؟
+
+337
+00:29:41,120 --> 00:29:48,940
+إذا هذه المركبات كأفراد تسمى باسم القلقين الأصلي
+
+338
+00:29:48,940 --> 00:29:55,160
+باسم القلقين الأصلي مضاف إلى كلمة Oxide واضحة ولا
+
+339
+00:29:55,160 --> 00:30:04,340
+ما واضحت؟ واضحة تماما، الآن إلها تسمية تانية كتير
+
+340
+00:30:04,340 --> 00:30:10,260
+في ناس بياخدوا أكتر من اسم، إلها تسمية تانيةأبسط
+
+341
+00:30:10,260 --> 00:30:15,340
+مُركّب في هذه العائلة كلها أي واحد الـ ethylene
+
+342
+00:30:15,340 --> 00:30:22,620
+oxide ليش؟ لأنه هنا O CH H H H H هذا المُركّب
+
+343
+00:30:22,620 --> 00:30:27,980
+الأبسط فيهم هذا المُركّب الأبسط ماخد اسم اسمه
+
+344
+00:30:27,980 --> 00:30:37,990
+Oxirane Oxirane تمام؟Oxirane بنحفظه ايه كويس الان
+
+345
+00:30:37,990 --> 00:30:43,270
+هذا ال Oxirane بنتخيله تلت مواقع بنبدأ ترقيمه من
+
+346
+00:30:43,270 --> 00:30:50,170
+ال Oxygen بنقول واحد اتنين تلاتةبنسميه ال parent
+
+347
+00:30:50,170 --> 00:30:55,410
+compound عمرنا قولنا كلمة parent المركب الأبسط
+
+348
+00:30:55,410 --> 00:30:59,310
+دائما بنقول عنه ال parent compound الآن هذا ال
+
+349
+00:30:59,310 --> 00:31:02,610
+parent compound لو يا ترى شيلنا من هدول ال
+
+350
+00:31:02,610 --> 00:31:10,870
+hydrogen ال hydrogen واحدة وحطينا بدلها CH3 واحدة
+
+351
+00:31:10,870 --> 00:31:12,610
+تقولي ايش بدها تسمي وجتها
+
+352
+00:31:15,250 --> 00:31:20,130
+أوكز إيرين المركب الأصلي على موقع اتنين إيش إجاله
+
+353
+00:31:20,130 --> 00:31:30,210
+مثل إذا هذا بيصير two مثل أوكز إيرين أنا اعتبرت ال
+
+354
+00:31:30,210 --> 00:31:34,990
+أوكز إيرين اللي فيه أربعة هيدروجين شلت منه واحدة
+
+355
+00:31:34,990 --> 00:31:39,630
+محل ما شلت بكتب اسم المجموعة لو كان كلور two chlor
+
+356
+00:31:39,630 --> 00:31:44,780
+أوكز إيرين لو كانت إثلتوقث ال Oxirane تعرفنا كيف
+
+357
+00:31:44,780 --> 00:31:49,800
+هذا سمنها؟ الآن هي تسمية هذا المركب اللي أمامكم
+
+358
+00:31:49,800 --> 00:31:54,360
+بطريقة ال Oxirane طب لو واحدة بدأت تسميه بطريقة ال
+
+359
+00:31:54,360 --> 00:32:02,200
+Alkyl Oxide، شو هتسميه؟ بروبين أكسيد، بروبين
+
+360
+00:32:02,200 --> 00:32:04,780
+أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد،
+
+361
+00:32:04,780 --> 00:32:05,560
+بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين
+
+362
+00:32:05,560 --> 00:32:06,080
+أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد،
+
+363
+00:32:06,080 --> 00:32:08,440
+بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين
+
+364
+00:32:08,440 --> 00:32:16,320
+أكسيد، بروبين أكسما هذا الالكين؟ واحد CH2 double
+
+365
+00:32:16,320 --> 00:32:22,300
+bond CH CH3 هذا الابروبيل و لذلك بيصير ابروبيل
+
+366
+00:32:22,300 --> 00:32:27,900
+أكسيد فلو جيبنالكم مثلا سؤال ابروبيل أكسيد is also
+
+367
+00:32:27,900 --> 00:32:32,780
+called وقتها بتقولوا 2-methyl oxirane 2-methyl
+
+368
+00:32:32,780 --> 00:32:38,900
+oxirane is also calledPropyl Oxide طبعا ال Oxirans
+
+369
+00:32:38,900 --> 00:32:42,760
+هذه في الكيميا الحلقية غير المتجانسة بنستعملها
+
+370
+00:32:42,760 --> 00:32:46,480
+أكتر في الكيميا العادية المشهورة أكتر يكون تسموها
+
+371
+00:32:46,480 --> 00:32:54,720
+نسبة للالكيم و تحطو إيش Oxide الإسمين بتلاقوهم إذا
+
+372
+00:32:54,720 --> 00:33:01,620
+شفنا هذه المراكبات كيف بنحضرها و كيفبنسميها كيف
+
+373
+00:33:01,620 --> 00:33:05,560
+بنحضرها و كيف بنسميها عساريا مينندسيا هل هذه
+
+374
+00:33:05,560 --> 00:33:08,800
+التسمية بتسميها ايوباك ولا ايوباك؟ لأ لأ هي
+
+375
+00:33:08,800 --> 00:33:14,240
+التسمية اللي هي ال auxirene نظام تسمي بسموه Hans
+
+376
+00:33:14,240 --> 00:33:18,550
+Wiedemann system of nomenclatureيستعمل عن طلاب
+
+377
+00:33:18,550 --> 00:33:23,570
+الكيميا للـ heterocyclic compounds واضح؟ hence
+
+378
+00:33:23,570 --> 00:33:26,570
+Vedman system of nomenclature الآن خلينا ناخد
+
+379
+00:33:26,570 --> 00:33:32,050
+أمثلة انسهل الموضوع هي كذا مثال جيبنا أكمل مع pear
+
+380
+00:33:32,050 --> 00:33:36,950
+acid شو عرفني pear acid؟ تلت أكسوجينات في كل
+
+381
+00:33:36,950 --> 00:33:42,370
+الأحوال شو اللي بدى أعمله؟ أشيل ال double bond؟أحط
+
+382
+00:33:42,370 --> 00:33:48,510
+مكانها أكسجين أشيل ال double bond أحط أكسجين أشيل
+
+383
+00:33:48,510 --> 00:33:52,630
+ال double bond أحط أكسجين إذا الأمر سهل و بسيط ولا
+
+384
+00:33:52,630 --> 00:33:57,110
+لأ الالكيل مع ال bear acid أشيل ال double bond أحط
+
+385
+00:33:57,110 --> 00:34:02,350
+أكسجين في حلقة ثلاثية كل هذه لو إجا شخص من برة و
+
+386
+00:34:02,350 --> 00:34:07,070
+يتطلع على السبورة ويقول له شو هذه المركبات؟ شو بدي
+
+387
+00:34:07,070 --> 00:34:14,200
+يجاوبنا؟Epoxides مش العائلة ابوكسايدز فلو يوم من
+
+388
+00:34:14,200 --> 00:34:19,140
+الأيام جريتوا مثلا عائلة الابوكسايدز افبالكم بلغة
+
+389
+00:34:19,140 --> 00:34:24,740
+بسيطة الحلقات الثلاثية التي تحتوي على ذرة أكسجين
+
+390
+00:34:24,740 --> 00:34:32,280
+واحدة هي عائلة الابوكسايدز واضحة؟ الآن بنلاحظ شغلة
+
+391
+00:34:32,280 --> 00:34:36,790
+في عائلة الابوكسايدزهذه الحلقة الثلاثية حتى لو
+
+392
+00:34:36,790 --> 00:34:41,950
+عملناها باستعمال ال model هنلاحظ فيها شغل يعني لو
+
+393
+00:34:41,950 --> 00:34:47,310
+جيبنا ذرة الأكسجين هذه اللي لونها أزرق شوية مش هي
+
+394
+00:34:47,310 --> 00:34:52,470
+زرق الأكسجين وجيبنا ذرتين carbon وجربنا نعمل
+
+395
+00:34:52,470 --> 00:34:58,350
+الحلقة الثلاثية باستعمال
+
+396
+00:34:59,200 --> 00:35:04,140
+الـ Models هتلاحظوا فيها ملاحظة اتطلعوا معاه قبل
+
+397
+00:35:04,140 --> 00:35:09,600
+ما اتسكر الحلقة شوفوا كيف مترايحة الروابط فيها و
+
+398
+00:35:09,600 --> 00:35:13,960
+انا بسكر ايش قاعد بعمل؟ بضغط .. بضغط .. بضغط ..
+
+399
+00:35:13,960 --> 00:35:18,720
+بضغط .. الآن غصب عن هذه ال carbon قاعد بعمل فيها
+
+400
+00:35:18,720 --> 00:35:24,240
+زاوية لو تتخيلوا جداش مقدارها؟ ستين .. ستين ..
+
+401
+00:35:24,240 --> 00:35:28,880
+ستين .. ستين .. مية و تمانينزوايا المثلث 180 طب
+
+402
+00:35:28,880 --> 00:35:32,420
+الزاوية المترايحة خليني أفلتها شوية أسيب ال carbon
+
+403
+00:35:32,420 --> 00:35:36,320
+تترايح جداش زاوية ال carbon هذه المترايحة لها مش
+
+404
+00:35:36,320 --> 00:35:43,020
+90 انسيتوا ال tetrahedral 109.5 هذه الزاوية 109.5
+
+405
+00:35:43,020 --> 00:35:49,440
+مش هدول بكملهم اتش اتش بيكونوا .. 109.5 الزاوية
+
+406
+00:35:49,440 --> 00:35:55,990
+المترايحةهذه الـ CH2 وهذه بتكون زيها كمان CH2،
+
+407
+00:35:55,990 --> 00:36:01,750
+واضح؟ فالزاوية المتريحة 109.5، الآن أنا عشان أعمل
+
+408
+00:36:01,750 --> 00:36:05,330
+الحلقة الثلاثية، انزلت فيها لا جداش، انزلت فيها لا
+
+409
+00:36:05,330 --> 00:36:10,550
+ستين، إذا هذا ضغط شديد على الحلقة ولا لأ؟ بسميه
+
+410
+00:36:10,550 --> 00:36:14,650
+strain زي الزنبارك لما بتعصوه، strain بتصير
+
+411
+00:36:14,650 --> 00:36:20,890
+الحلقة، هذه الحلقة الـstrain لو بدت تعمل تفاعلوحد
+
+412
+00:36:20,890 --> 00:36:26,070
+مضغوط ايش التفاعل اللي بده يعمله؟
+
+413
+00:36:26,070 --> 00:36:33,450
+Ring Opening لأنها Strained لما قادش أفعلها مع
+
+414
+00:36:33,450 --> 00:36:37,190
+أشياء التفاعل اللي بتعمله Ring Opening بتحب تفتح
+
+415
+00:36:37,190 --> 00:36:41,890
+بتحب مش يظلها مسكرة فبدنا نفهم احنا ان الحلقة
+
+416
+00:36:41,890 --> 00:36:46,290
+الثلاثية هذه Strained ايش يعني Strained؟ مضغوطة
+
+417
+00:36:46,290 --> 00:36:49,030
+بتحب تعمل Ring
+
+418
+00:36:51,710 --> 00:36:56,190
+Ring Opening بتفتح، بتريح الزوايا تبعتها زي أي بني
+
+419
+00:36:56,190 --> 00:37:01,090
+آدم مضغوط برتاح للزوايا الطبيعية، الزوايا الطبيعية
+
+420
+00:37:01,090 --> 00:37:08,120
+109.5، هي الآن هنا موجودة في جداشالان بيصير السؤال
+
+421
+00:37:08,120 --> 00:37:11,980
+يا تورا ايش الشيء اللى بده يعمل ال herring opening
+
+422
+00:37:11,980 --> 00:37:16,580
+و يتفاعل معها؟ لو اطلعتوا انتوا هنا، هاي الحلقة،
+
+423
+00:37:16,580 --> 00:37:22,800
+هذا أكسوجين سلبيته عالية، هذه كربون سلبيتها أقل،
+
+424
+00:37:22,800 --> 00:37:26,540
+اذا كأنه هذا الأكسوجين سالب و الكربون و الكربون
+
+425
+00:37:26,540 --> 00:37:31,880
+هذه ايش مالهم؟ موجباتهذه نقطة كتير مهمة اذا انا
+
+426
+00:37:31,880 --> 00:37:37,560
+بقدر اتخيل الان هذه ان هذه سالبة و انا عندي على ال
+
+427
+00:37:37,560 --> 00:37:42,660
+carbon موجب و على ال carbon موجب بناء على ذلك لو
+
+428
+00:37:42,660 --> 00:37:48,460
+جبت من برا اش سالب يتفاعل وين هيروح يهجم على ال
+
+429
+00:37:48,460 --> 00:37:52,160
+carbon هذا الاش السالب اللي انا بجيبه و بسميه ال
+
+430
+00:37:52,160 --> 00:37:56,020
+eucleophile اكيد شيء عليه أزواج الإلكترونات هي سبب
+
+431
+00:37:56,020 --> 00:38:02,090
+السالبإيش بسميه الـ Eucleophile يمكن هالكلمة هذه
+
+432
+00:38:02,090 --> 00:38:08,910
+ما مرتش معاكم قبل هيك ال Eucleophile لو فصلنا شوية
+
+433
+00:38:08,910 --> 00:38:13,370
+بكلمة ال Eucleophile file من اللاتيني معناه محب
+
+434
+00:38:13,370 --> 00:38:20,300
+محب يحبو نيوكليو من نيوكلياس النواة معناه
+
+435
+00:38:20,300 --> 00:38:24,700
+نيوكليوفايل يحب النواة طب النواة اللي في قلبها
+
+436
+00:38:24,700 --> 00:38:29,780
+موجب ولا سالب؟ موجب إذا بتصير معناة كلمة
+
+437
+00:38:29,780 --> 00:38:36,260
+نيوكليوفايل يحب الموجب ما الذي يحب الموجب؟ السالب
+
+438
+00:38:36,260 --> 00:38:40,020
+أو اللي بيحمل أزواج إلكترونات فهمتوا؟ إذا
+
+439
+00:38:40,020 --> 00:38:46,310
+النيوكليوفايل ببساطة شيء سالبأو شيء بيحمل أزواج
+
+440
+00:38:46,310 --> 00:38:49,970
+إلكترونات لأنه سالب أو بيحمل أزواج إلكترونات فهو
+
+441
+00:38:49,970 --> 00:38:54,970
+يحب ال إيش؟ الموجب الآن هذه ال carbon موجبة تحب
+
+442
+00:38:54,970 --> 00:38:58,990
+إيش؟ سالب سالب لو بدي أعطيها اسم بنفس منطق ال
+
+443
+00:38:58,990 --> 00:39:04,350
+nucleophile إيش هقول؟ أكس آن أكس آن file file هذه
+
+444
+00:39:04,350 --> 00:39:09,790
+يحب ال electrophile ال electrophile فال
+
+445
+00:39:09,790 --> 00:39:16,470
+electrophile شيء موجبيحب السالب لأن يوكليوفي شئ
+
+446
+00:39:16,470 --> 00:39:20,350
+سالب يحب الموجب هدول شغلتين بتفاعلوا مع بعض يعني
+
+447
+00:39:20,350 --> 00:39:24,090
+كأنه ببساطة ممكن واحدة اللي مش كتير حابه
+
+448
+00:39:24,090 --> 00:39:28,050
+هالمصطلحين لأول واحدة تقول يعني موجب وسالب أه
+
+449
+00:39:28,050 --> 00:39:32,110
+ببساطة يعني موجب وسالب لكن احنا من اليوم وطالع في
+
+450
+00:39:32,110 --> 00:39:34,750
+ال organ ال chemistry الموجب ايش هنسميه؟
+
+451
+00:39:35,390 --> 00:39:40,390
+Electrophile والسالب ايش هنسميه النيوكليوفايل الان
+
+452
+00:39:40,390 --> 00:39:47,510
+هنقول انه النيوكليوفايل بيهاجم على ال Electrophile
+
+453
+00:39:47,510 --> 00:39:52,390
+بيعمل رابطة ممكن النيوكليوفايل يكون OH جاية من
+
+454
+00:39:52,390 --> 00:39:56,030
+الميه او تيجي من الميه فلما ييجي هذا ال OH
+
+455
+00:39:56,030 --> 00:40:00,470
+هنهيهاجم معقول يصيروا خمس روابط ولا هتكسر هذه
+
+456
+00:40:00,470 --> 00:40:10,140
+الرابطة تكسر وتفتح هتتحول ال O هذهالى OH الان بهذه
+
+457
+00:40:10,140 --> 00:40:13,220
+المنطقة راجعوا المرة اللى جايب ال road نبدأ من عند
+
+458
+00:40:13,220 --> 00:40:16,400
+هذه النقطة لكن بتكونوا اتدربتوا اكتر و بنشرح كل
+
+459
+00:40:16,400 --> 00:40:20,940
+الأمثلة ايش معنى Electrophile ايش معنى Nucleophile
+
+460
+00:40:20,940 --> 00:40:24,680
+هات بتتدربوا عليها بنشوف كيف ال ring opening بيصير
+
+461
+00:40:24,680 --> 00:40:26,600
+باكثر من مثل
+
diff --git a/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.srt b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8f1fe0fce9342c67c52a03da635410dcc4b62926
--- /dev/null
+++ b/PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.srt
@@ -0,0 +1,1848 @@
+1
+00:00:20,990 --> 00:00:24,950
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:24,950 --> 00:00:29,290
+تفاعلات ال alkenes وقلنا اللى بينظر للموضوع نظرة
+
+3
+00:00:29,290 --> 00:00:34,610
+كلية الموضوع بسيط الموضوع انه double bond هيوم
+
+4
+00:00:34,610 --> 00:00:40,230
+رابطتين بالاضافة بتصير single bond هذه العملية شو
+
+5
+00:00:40,230 --> 00:00:46,110
+بنسميها عملية addition عملية addition واتفقنا ان
+
+6
+00:00:46,110 --> 00:00:48,810
+في ال addition فى عندنا مكونات لل addition فى
+
+7
+00:00:48,810 --> 00:00:52,730
+عندنا ال alkeneو في عندنا ال reagent وهذا ممكن
+
+8
+00:00:52,730 --> 00:00:56,610
+يكون symmetric و لا unsymmetric وهذا نفس الشيء و
+
+9
+00:00:56,610 --> 00:00:59,610
+دائما قلنا بدنا ننتبه لو كان في عندنا
+
+10
+00:00:59,610 --> 00:01:03,550
+unsymmetrical alkene مع unsymmetrical reagent
+
+11
+00:01:03,550 --> 00:01:09,070
+بنتوقع انه بيكون عندنا two products الآن هنبدأ
+
+12
+00:01:09,070 --> 00:01:13,510
+ناخد أمثلة على هذا الموضوع تحديدا لو بدنا نتكلم
+
+13
+00:01:13,510 --> 00:01:18,580
+على إضافة الماءإضافة الماء، الماء بيضيف جزء إيه؟
+
+14
+00:01:18,580 --> 00:01:25,940
+بيضيف H و O H هذه العملية بنسميها hydration لاحظوا
+
+15
+00:01:25,940 --> 00:01:30,780
+أنه عمليات الإضافة حسب ال reagent يعني المرة
+
+16
+00:01:30,780 --> 00:01:35,840
+الماضية إحنا لما إضفنا ال hydrogen عملية إضافة ال
+
+17
+00:01:35,840 --> 00:01:42,940
+hydrogen hydrogenation اسمها واضح؟عملية إضافة
+
+18
+00:01:42,940 --> 00:01:49,120
+الهيدروجين الان ممكن نضيف الهالوجين بشكل عام
+
+19
+00:01:49,120 --> 00:01:57,020
+بنسميها الهالوجيناشن طبعا بشكل خاص إكلوريناشن
+
+20
+00:01:57,020 --> 00:02:05,100
+بروميناشن و هكذا ممكن نضيف الميه بنسميها هيدريشن
+
+21
+00:02:05,100 --> 00:02:14,210
+إضافة الميهHydration واضح؟ ممكن نضيف HX خلّينا
+
+22
+00:02:14,210 --> 00:02:22,530
+نقول HBR و لا HCL على الطرفين الرابطة HX بنسميها
+
+23
+00:02:22,530 --> 00:02:27,530
+Hydro لأن فيها Hydrogen Hydro وHalogen
+
+24
+00:02:27,530 --> 00:02:34,730
+Halogenation Hydro Halogenation كل هذه العمليات هي
+
+25
+00:02:34,730 --> 00:02:40,670
+عمليات إيش؟إضافة إذا إليها أسماء hydrogenation,
+
+26
+00:02:40,750 --> 00:02:44,430
+halogenation, hydration, hydrohalogenation
+
+27
+00:02:44,430 --> 00:02:49,010
+ابتفاعلات تانية هنتعلمها بعدين و هتلاحظوا إنه في
+
+28
+00:02:49,010 --> 00:02:53,430
+الكيميا العضوية دائما عندكم الشغلات المتعاكسة
+
+29
+00:02:53,430 --> 00:02:57,770
+بمعنىان ال double bond لما اضيف عليها reagent
+
+30
+00:02:57,770 --> 00:03:01,370
+بتصير single bond يعني لو افترضنا ان هاي double
+
+31
+00:03:01,370 --> 00:03:06,030
+bond اضفت عليها reagent الناتج single bond الان لو
+
+32
+00:03:06,030 --> 00:03:11,470
+هذه ال single bond ابتفاعل تاني رفعت منها شغلتين
+
+33
+00:03:11,470 --> 00:03:16,510
+هتصير double bond اذا انا ممكن اعمل اضافة و ممكن
+
+34
+00:03:16,510 --> 00:03:22,760
+اعمل حذفواضح ال elimination بسميه فزي ما في عند ا
+
+35
+00:03:22,760 --> 00:03:28,840
+addition في عند كمان عكسه elimination هذه عمليات
+
+36
+00:03:28,840 --> 00:03:34,860
+ال elimination أيضا لها أسماء بمعنى لو كنا بنحذف
+
+37
+00:03:34,860 --> 00:03:39,240
+ذرتين هيدروجين و بنعمل double bond تاني هنسمي
+
+38
+00:03:39,240 --> 00:03:44,880
+العملية dehydrogenation هستخدم ل prefix دي هذا
+
+39
+00:03:44,880 --> 00:03:51,360
+للنفيD فحقول dehydrogenation لو كنت برفع زرتين
+
+40
+00:03:51,360 --> 00:03:58,300
+كلور او بروم Dehydrogenation لو كنت برفع HOH
+
+41
+00:03:58,300 --> 00:04:03,900
+Dehydration هذه الكلمة الشهيرة نزع الماء
+
+42
+00:04:03,900 --> 00:04:07,520
+Dehydration
+
+43
+00:04:08,520 --> 00:04:12,700
+لو كنا بنرفع ال .. ال hydrogen وال halogen
+
+44
+00:04:12,700 --> 00:04:17,120
+dehydrohalogenation واضح؟ dehydrohalogenation
+
+45
+00:04:17,120 --> 00:04:21,640
+ولذلك بتلاقوا هذه الكلمة انتبهولها جيدا واحفظوها
+
+46
+00:04:21,640 --> 00:04:26,460
+انتوا في المستقبل بتصيروا أمهات dehydration لما
+
+47
+00:04:26,460 --> 00:04:30,620
+الأطفال الصغار بيمرضوا بتروح فيهم على المستشفيات
+
+48
+00:04:30,620 --> 00:04:35,630
+بيكون ..عندهم جفاف فالطبيب ايش بيقول عنه عنده
+
+49
+00:04:35,630 --> 00:04:40,070
+dehydration يعني فقد الماء اللي عنده صار عنده جفاف
+
+50
+00:04:40,070 --> 00:04:44,350
+فبيسموها بالانجليزي ايش الجفاف dehydration يعني
+
+51
+00:04:44,350 --> 00:04:48,370
+ايه تسمعوا عن الطفل عنده dehydration لازم تعطوه
+
+52
+00:04:48,370 --> 00:04:53,830
+ايش محليل الان اول شئ بدنا نبدأ فيه ال hydration
+
+53
+00:04:53,830 --> 00:04:57,750
+اضافة الماء الان اضافة الماء على طرفين الرابط
+
+54
+00:04:57,750 --> 00:05:05,860
+الزوجية شو هيحط عندهH و OH واضح القصة طبعا في كل
+
+55
+00:05:05,860 --> 00:05:09,920
+شيء في تفاصيل كثيرة لكن احنا احيانا بنتجوزها في ال
+
+56
+00:05:09,920 --> 00:05:12,880
+course العام يعني كيف بنضافه مش مشكلة المهم ان ال
+
+57
+00:05:12,880 --> 00:05:17,600
+double bond راحت ال bi bond ألغيت صارت two new
+
+58
+00:05:17,600 --> 00:05:24,160
+sigma bonds واحدة H واحدة OH هذا التفاعل بشكل عام
+
+59
+00:05:24,160 --> 00:05:31,000
+الان لو اتيت للتفاعل بحالة خاصةأتطلعت على هذا الـ
+
+60
+00:05:31,000 --> 00:05:35,620
+Alkene اللي هو الـ Isobutyl الان لو اتطلعت على هذا
+
+61
+00:05:35,620 --> 00:05:40,380
+ال Isobutyl هتلاحظوا انه Unsymmetrical الكين بمعنى
+
+62
+00:05:40,380 --> 00:05:43,860
+لو اتيت في نص ال bubble bond اتخيلت اني بدأ اجسم
+
+63
+00:05:43,860 --> 00:05:50,680
+نصين هلعنى C ايش بتحمل؟H و H مختصرات وهنا C بتحمل
+
+64
+00:05:50,680 --> 00:05:57,620
+CH3 و CH3 طيب لما أنا بدي أضيف الميه نتخيل الميه
+
+65
+00:05:57,620 --> 00:06:02,560
+هدول الجزئين الأزرق و الأحمر بدي أضيف الميه هل يا
+
+66
+00:06:02,560 --> 00:06:07,620
+تورا ال H نعتبرها الزرقه نعتبر ال H الزرقه و ال OH
+
+67
+00:06:07,620 --> 00:06:12,980
+الحمره هل يا تورا بدي أحط هنا ال H و هنا ال OH ولا
+
+68
+00:06:12,980 --> 00:06:15,200
+هنا ال H و هنا ال OH
+
+69
+00:06:19,900 --> 00:06:24,640
+من الناحية النظرية البحتة، من ناحية النظرية
+
+70
+00:06:24,640 --> 00:06:29,560
+البحتة، لو احنا بنقول لطفل صغير تعال شيل هادي وحق
+
+71
+00:06:29,560 --> 00:06:36,060
+التنتين، ممكن يعمل هيك و ممكن يعمل هيك، من ناحية
+
+72
+00:06:36,060 --> 00:06:41,000
+النظرية البحتة، الأمرين ممكنين، مافيش فيهم ولا
+
+73
+00:06:41,000 --> 00:06:47,280
+مشكلةالان هدولة الأمرين احنا اعطيناهم اسماء قولنا
+
+74
+00:06:47,280 --> 00:06:53,500
+اذا بنضيف الهيدروجين على الكربون اللى بتحمل
+
+75
+00:06:53,500 --> 00:06:57,520
+هيدروجين اكثر هذه الان لو فصلناها بشكل كامل هي
+
+76
+00:06:57,520 --> 00:07:03,850
+عبارة عن C بتحمل H وHتمام؟ هذه C لا تحمل اش ولا
+
+77
+00:07:03,850 --> 00:07:08,950
+اتش لو ضفنا الهيدروجين على الكاربون اللي حامل
+
+78
+00:07:08,950 --> 00:07:13,630
+هيدروجين اكثر بنقول هذه الإضافة حسب قواعد
+
+79
+00:07:13,630 --> 00:07:17,650
+Markovnikov أو حسب قاعدة Markovnikov وقتها بروح
+
+80
+00:07:17,650 --> 00:07:22,190
+بحط ال H هنا نفترض باللون الأزرق و ال O أتش هنا و
+
+81
+00:07:22,190 --> 00:07:28,710
+بطلع عندى ناتج واضح؟ ان جرب نعمل الجواب لو جربنا
+
+82
+00:07:28,710 --> 00:07:36,900
+هنحط CCH3 CH3 وهذه ستصبح single bond CH2 هذا ما
+
+83
+00:07:36,900 --> 00:07:46,540
+كان موجود أصلا كله ما جاء عليه H و OH الأن بهذا
+
+84
+00:07:46,540 --> 00:07:50,560
+الشكل الهيدروجين جاء على أي كربون على اللي حملة
+
+85
+00:07:50,560 --> 00:07:56,940
+هيدروجين أكتر وهذه الإضافة بنسميها إضافة حسب قاعدة
+
+86
+00:07:56,940 --> 00:07:58,140
+Markov-Nikov
+
+87
+00:08:05,760 --> 00:08:11,760
+ماركوف نيكوفز اديشن اضافة ماركوف نيكوفز اضافة
+
+88
+00:08:11,760 --> 00:08:12,480
+ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف
+
+89
+00:08:12,480 --> 00:08:14,080
+نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز
+
+90
+00:08:14,080 --> 00:08:14,240
+اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة
+
+91
+00:08:14,240 --> 00:08:14,300
+ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف
+
+92
+00:08:14,300 --> 00:08:15,260
+نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز
+
+93
+00:08:15,260 --> 00:08:19,420
+اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة
+
+94
+00:08:19,420 --> 00:08:26,320
+ماركوف نيكوفز اضافCH3 CH3 وهخلّي هذه single bond
+
+95
+00:08:26,320 --> 00:08:31,380
+CH2 هاي الألكين الأصلي و أحطهم بالعكس يعني ال H
+
+96
+00:08:31,380 --> 00:08:41,120
+هنا و ال OH هنا إيش
+
+97
+00:08:41,120 --> 00:08:49,170
+المانع؟مش مانع هاي إضافة مية وهي إضافة مية هذه
+
+98
+00:08:49,170 --> 00:08:54,330
+الإضافة بنعطيها اسم بنقولها Anti-Markovnikov
+
+99
+00:08:54,330 --> 00:08:58,650
+addition إضافة عكس قاعدة Markovnikov
+
+100
+00:09:03,760 --> 00:09:07,420
+Nikov's addition إذا يمكن أن تكون الإضافة زيك
+
+101
+00:09:07,420 --> 00:09:10,380
+ويمكن أن تكون زيك هتقولوا طب وإحنا شو بده يعرفنا
+
+102
+00:09:10,380 --> 00:09:16,380
+كيف نعمل الإضافة بنقول أه حسب ال reagent المستعمل
+
+103
+00:09:16,380 --> 00:09:22,200
+الماء يمكن أن يضيف بهذا الشكل وينتج المركب اللي
+
+104
+00:09:22,200 --> 00:09:25,960
+أمامنا هنا على الجهة اليامين ويمكن أنه يضيف بالشكل
+
+105
+00:09:25,960 --> 00:09:31,500
+التاني وينتج مركب تانيممكن يعطي ناتج إضافة حسب
+
+106
+00:09:31,500 --> 00:09:35,480
+قاعدة Markovnikov وممكن يعطي عكسها هتقولولنا طب
+
+107
+00:09:35,480 --> 00:09:39,440
+وقت إيش بيعمل هيك ووقت إيش بيعمل هيك الجواب بسيط
+
+108
+00:09:39,440 --> 00:09:42,680
+لأ وإحنا بنحكي الصورة الكلية اللي تفهم من خلالها
+
+109
+00:09:42,680 --> 00:09:46,440
+إذا كانت إضافة الماء يعني هنا على السهم كتبنا
+
+110
+00:09:46,440 --> 00:09:51,980
+الماء في وجود الحامض H plus فإنه يضيف حسب قاعدة
+
+111
+00:09:51,980 --> 00:09:57,190
+Markovnikovإذا عرفنا ما الشرط الذي من خلاله تتم
+
+112
+00:09:57,190 --> 00:10:02,570
+الإضافة حسب قاعدة Markov Nikov أن نضيف الماء في
+
+113
+00:10:02,570 --> 00:10:08,950
+وجود كمية قليلة من الحامض وجدها بنضيف حسب قاعدة
+
+114
+00:10:08,950 --> 00:10:17,600
+Markov Nikovالان طب كيف بضيف عكس قاعدة Markovnikov
+
+115
+00:10:17,600 --> 00:10:21,200
+إذا
+
+116
+00:10:21,200 --> 00:10:28,020
+ضفنا الماء باستعمال reagent مختلف طبعا ظروف كاملة
+
+117
+00:10:28,020 --> 00:10:34,520
+مختلفة باستعمال مركب ال borane اللي بنقوله BH3طبعا
+
+118
+00:10:34,520 --> 00:10:39,660
+بعد هيكذا البرين بنحط عليه H2O2 هيدروجين بيروكسايد
+
+119
+00:10:39,660 --> 00:10:46,180
+لو ضفنا في وجود هذه المتفاعلات بضيف عكس قاعدة
+
+120
+00:10:46,180 --> 00:10:52,160
+ماركوف نيكوفطبعا ربما الآن بدت الصورة تتضح لكم
+
+121
+00:10:52,160 --> 00:10:56,980
+لأنه انا حاسس الصمت عندكم لأن انتوا اتعلمتوا نص
+
+122
+00:10:56,980 --> 00:11:01,180
+المعلومة بالثانوية انه الإضافة فقط حسب قاعدة
+
+123
+00:11:01,180 --> 00:11:05,560
+Markovnikov حسب قاعدة Markovnikov ضمن هذا الشرط
+
+124
+00:11:05,560 --> 00:11:11,480
+غير الشرط تحصل على إضافة عكس قاعدة Markovnikov إذا
+
+125
+00:11:11,480 --> 00:11:17,710
+الأمرين ممكنين واضح؟ اللي اتعلمتوا بالثانويةنص
+
+126
+00:11:17,710 --> 00:11:23,030
+القصة مش كل القصة، واضح؟ اللي اتعلمته بالثانوية
+
+127
+00:11:23,030 --> 00:11:29,390
+نصف هذه القصة مش كلها فقط، الآن احنا استكملنا
+
+128
+00:11:29,390 --> 00:11:32,850
+القصة لكم، اننا نقولكم لأ والله يا المية بتضيف
+
+129
+00:11:34,860 --> 00:11:39,160
+الميّه بتضيف بالطريقتين هذا الكلام بعد شوية
+
+130
+00:11:39,160 --> 00:11:43,520
+هتلاحظوه مش بسمع الميّه هذا الكلام بعد شوية
+
+131
+00:11:43,520 --> 00:11:49,200
+هتلاحظوه مش بسمع الميّه هتلاحظوه حتى مع ال HPR على
+
+132
+00:11:49,200 --> 00:11:52,920
+سبيل المثال يعني لو أخذنا نفس ال ال keen اللي كان
+
+133
+00:11:52,920 --> 00:11:56,820
+عندنا هان عارفينه ال C double bond C
+
+134
+00:11:59,940 --> 00:12:08,040
+CH3 و CH3 و قلنا بدنا نكمله باتجاهين مع الـHBr و
+
+135
+00:12:08,040 --> 00:12:13,520
+هنا كمان كتبنا HBr لو قلنا بدنا نكمل التفاعل مع
+
+136
+00:12:13,520 --> 00:12:20,460
+HBr في وجود H Plus سيضيف حسب قاعدة Markov Nikov و
+
+137
+00:12:20,460 --> 00:12:24,520
+لو قلنا بدنا نكمل التفاعل مع الـHBr في وجود
+
+138
+00:12:24,520 --> 00:12:30,160
+بيروكسايد سيضيف عكس قاعدة Markov Nikovالناتج
+
+139
+00:12:30,160 --> 00:12:33,340
+ببساطة نفس اللي موجود عندكم بدل كلمة OH اللي
+
+140
+00:12:33,340 --> 00:12:34,660
+بالأحمر شو بتحطه
+
+141
+00:12:41,060 --> 00:12:46,580
+إذا إضافة الماء أو إضافة الـ HPR يمكن أن تتم
+
+142
+00:12:46,580 --> 00:12:51,360
+بطريقة ولا بطريقتين وهنا بيصير مهم عندي جدا أن
+
+143
+00:12:51,360 --> 00:12:55,460
+أنتبه لل reactant للمتفاعل يعني لو احنا مرات بدنا
+
+144
+00:12:55,460 --> 00:12:59,840
+نسألكوا عن هذا الموضوع ممكن نجيبلكوا ال reactant
+
+145
+00:12:59,840 --> 00:13:03,100
+مع هذا نقولكوا اكتبوا النتيجة ممكن نجيب هذا ال
+
+146
+00:13:03,100 --> 00:13:06,300
+reactant و ال product و نقولكوا شو اللي استعملته
+
+147
+00:13:06,300 --> 00:13:11,620
+كمتفاعل كتبولي ال reactant اللي على السهلواضحك
+
+148
+00:13:11,620 --> 00:13:16,680
+الصورة؟ طبعا لو إجينا سألنا هذه النواتج ال
+
+149
+00:13:16,680 --> 00:13:20,100
+markovnikov product هذا بيسموه markovnikov product
+
+150
+00:13:20,100 --> 00:13:26,020
+و ال antimarkovnikov product ما العلاقة بينهما؟
+
+151
+00:13:26,020 --> 00:13:30,000
+isomers
+
+152
+00:13:30,000 --> 00:13:32,540
+أي نوع من ال isomers هذا اللي بقصدي
+
+153
+00:13:36,070 --> 00:13:40,470
+الـ Markovnikov's product والـ Antimarkovnikov's
+
+154
+00:13:40,470 --> 00:13:45,250
+product They are isomers ليش؟ لأنه نفس الذرات
+
+155
+00:13:45,250 --> 00:13:50,610
+وحطيت H و OH حطيت ال H و OH بنفس المواقع ولا
+
+156
+00:13:50,610 --> 00:13:57,670
+بمواقع مختلفة طالما مواقع مختلفة Different bonding
+
+157
+00:13:57,670 --> 00:14:04,290
+عطول الجواب Structural isomers They are structural
+
+158
+00:14:04,290 --> 00:14:09,910
+isomersمش فيها نقاش مش ارتبطوا الذرات من مواقع
+
+159
+00:14:09,910 --> 00:14:13,210
+مختلفة هنا الهيدروجين على الأولى و ال OH على
+
+160
+00:14:13,210 --> 00:14:17,470
+التانية هنا ال OH على الأولى و ال H على التانية صح
+
+161
+00:14:17,470 --> 00:14:20,570
+ولا لأ different bonding different names
+
+162
+00:14:20,570 --> 00:14:27,490
+structural isomers واضح إذا فكرة إضافة ال
+
+163
+00:14:27,490 --> 00:14:33,850
+unsymmetrical agents ممكن تضيفطريقتين ماركوف نيكوف
+
+164
+00:14:33,850 --> 00:14:37,450
+وانتي ماركوف نيكوف حسب ظروف التفاعل شو الأمثلة
+
+165
+00:14:37,450 --> 00:14:43,840
+المطلوب من ان اعرفها الماءو ال HVR بدون تفاصيل
+
+166
+00:14:43,840 --> 00:14:47,600
+الميكانيزم اللي أحيانا ممكن تلاقوها موجودة عندكم
+
+167
+00:14:47,600 --> 00:14:50,920
+يعني أنا في النهاية ال course general organic
+
+168
+00:14:50,920 --> 00:14:56,340
+course بهمني تصلوا فيه للنتيجة بشكل عام ولذلك على
+
+169
+00:14:56,340 --> 00:14:59,960
+طول الآن ممكن ناخد أمثلة إضافية و تشوفوا كيف
+
+170
+00:14:59,960 --> 00:15:04,520
+الأمثلة الإضافية بنكملها بدون ما ندخل بتفاصيل كيف
+
+171
+00:15:04,520 --> 00:15:08,260
+تمت العملية المهم عنده النتج
+
+172
+00:15:19,100 --> 00:15:22,820
+الشرط اللي بتتم فيه الإضافة عكس قاعدة Markovnikov
+
+173
+00:15:22,820 --> 00:15:27,160
+موجود في هذا ال slide لاحظوا لأنه بضيف مركب اسمه
+
+174
+00:15:27,160 --> 00:15:32,960
+BH3 ال بي بورون مش بروم انتبه بورون ال بورون لما
+
+175
+00:15:32,960 --> 00:15:36,760
+تيجي على الجدول الدوري في أوله اللي هو العنصر
+
+176
+00:15:36,760 --> 00:15:43,920
+الخامس هيدروجين هيليوم ليثيوم بيريليوم بورونBoron
+
+177
+00:15:43,920 --> 00:15:50,200
+الأنصار الخامس تمام لما يكون BH3 بنسميه borane هذا
+
+178
+00:15:50,200 --> 00:15:52,500
+بنسميه بورين
+
+179
+00:15:55,140 --> 00:16:01,340
+الان هذا ال borane في وجود solvent THF اسمه تترا
+
+180
+00:16:01,340 --> 00:16:04,640
+هيدرو فيوران solvent مش مشكلة بالنسبالي ان كل
+
+181
+00:16:04,640 --> 00:16:11,000
+تفاعل بتم في وجود مضيب بنضيف ال borane مع ال THF
+
+182
+00:16:11,000 --> 00:16:15,240
+في خطوة أولى بنحركهم لفترة معينة و بعدين على نفس
+
+183
+00:16:15,240 --> 00:16:23,390
+التفاعل بنضيف H2O2 hydrogen peroxideماء الأكسجين
+
+184
+00:16:23,390 --> 00:16:26,050
+اللي بيستعملوها بتثبيت الشعر وغيرها في basic
+
+185
+00:16:26,050 --> 00:16:32,110
+medium في وجود OH- الان انا دائما بهمني تفهمين
+
+186
+00:16:32,110 --> 00:16:36,450
+الفكرة الرئيسية يعني ماتوهوش كتير في التفاصيل
+
+187
+00:16:36,450 --> 00:16:39,530
+ولذلك لما انا بكون بدي افهم الفكرة الرئيسية لو
+
+188
+00:16:39,530 --> 00:16:43,730
+واحدة فكرت كل هدول وقعدت بتحفظهم بتوه لأ انا بهمني
+
+189
+00:16:43,730 --> 00:16:47,850
+ببساطة في الأول الفكرة الأساسية ان الماء يضيف
+
+190
+00:16:47,850 --> 00:16:52,800
+بطريقتين واضحة ولا لأيضيف Markovnikov في وجود H+,
+
+191
+00:16:52,800 --> 00:16:57,700
+واضح ولا لأ؟ وبقول ببساطة يضيف Anti-Markovnikov
+
+192
+00:16:57,700 --> 00:17:01,480
+بطريقة البرون، الآن أنا اللي بسميها طريقة البرون،
+
+193
+00:17:01,480 --> 00:17:05,660
+لأن طريقة البرون مجموعة من الأشياء موجودة في الكتب
+
+194
+00:17:05,660 --> 00:17:08,560
+وما إلى ذلك، وبنكتوب الكتابة على السهم، مابديش
+
+195
+00:17:08,560 --> 00:17:13,450
+أتقوه إن أقعد أحفظ هدولة بدون ما أكون فهمت؟الشئ
+
+196
+00:17:13,450 --> 00:17:17,570
+الرئيسي كذلك الحالة لبروم ال HPR عفوا بيضيف
+
+197
+00:17:17,570 --> 00:17:22,810
+بطريقتين في وجود H plus ماركوفنيكوف في وجود مواد
+
+198
+00:17:22,810 --> 00:17:27,350
+بيسميها البروكسايد فوق الأكسد انتي ماركوفنيكوف
+
+199
+00:17:27,350 --> 00:17:31,570
+يعني هتلاحظوا ان عندكم HPR و مكتوب لك بيروكسايد
+
+200
+00:17:31,570 --> 00:17:39,330
+اذا وجدتها التنفيذ انتي ماركوفنيكوفسابقا كان عندى
+
+201
+00:17:39,330 --> 00:17:43,290
+ناس ممتازين اللى بيحاولوا يفهموا الأمور في الأول
+
+202
+00:17:43,290 --> 00:17:46,110
+بالصورة الكلية قبل ما يخوضوا بالتفاصيل بعض منكم
+
+203
+00:17:46,110 --> 00:17:49,370
+بيتعب لإنه بيصير يخوض بالتفاصيل و الأشياء قبل ما
+
+204
+00:17:49,370 --> 00:17:53,770
+يفهم الصورة الكلية هدولة الناس الممتازين طلبت منهم
+
+205
+00:17:53,770 --> 00:17:57,570
+كان شعراء انه يلخصوا ال organ ال chemistry شعرا
+
+206
+00:17:58,290 --> 00:18:03,030
+بلغة بسيطة وهذا اللي بنصحكم يوم الامتحان تدرسوه ما
+
+207
+00:18:03,030 --> 00:18:06,610
+تقعدوش بس تكتبوا الأشياء دي و تفهموا لا افهموا
+
+208
+00:18:06,610 --> 00:18:11,170
+الأفكار الرئيسية الأفكار الرئيسية ببساطة اللي قلنا
+
+209
+00:18:11,170 --> 00:18:16,490
+ساعتين فيها تفهم بدقيقتين ال double bond تفعلها
+
+210
+00:18:16,490 --> 00:18:22,100
+الأساس إضافةالهيدروجين يضيف بشكل متماثل من جهة
+
+211
+00:18:22,100 --> 00:18:27,760
+واحدة البرومين يضيف من جهتين الأشياء زي الـH2O و
+
+212
+00:18:27,760 --> 00:18:31,900
+الـHBr ممكن تضيف مع قاعدة ماركوف نيكوف عكس قاعدة
+
+213
+00:18:31,900 --> 00:18:35,180
+ماركوف نيكوف تضيف مع قاعدة ماركوف نيكوف في وجود
+
+214
+00:18:35,180 --> 00:18:40,120
+الحامض تضيف عكس قاعدة ماركوف نيكوف الماء في وجود
+
+215
+00:18:40,120 --> 00:18:43,480
+البرون و الـHBr في وجود البروكسايد
+
+216
+00:18:45,830 --> 00:18:49,310
+هذا كل الكلام اللي احنا حكيناه ماحكيناش ولا كلمة
+
+217
+00:18:49,310 --> 00:18:53,170
+غيره بهذا الشكل بتصير ال organic عندكم سهلة و
+
+218
+00:18:53,170 --> 00:18:58,870
+ممتعة هعندي HPR طبعا ال HPR في نهاية بده يحط H و
+
+219
+00:18:58,870 --> 00:19:03,970
+PR ع دابل بوند هذه كانت CH2 صارت CH3 و انا PR هذا
+
+220
+00:19:03,970 --> 00:19:12,370
+مثال عام لكن لو اجينا على مثال متخصص زي هذا المثال
+
+221
+00:19:12,370 --> 00:19:21,590
+هذا الكربون كام هيدروجين عليهامباشر هذه واحدة
+
+222
+00:19:21,590 --> 00:19:24,070
+طلع هذه متصلة ب carbon
+
+223
+00:19:27,380 --> 00:19:33,680
+بعد انا بحكي عن الاتصال المباشر مش موراء ما بعد
+
+224
+00:19:33,680 --> 00:19:38,460
+بعد حيفا شو مالي و ماله هذا اه هنا هيدروجين تان
+
+225
+00:19:38,460 --> 00:19:42,400
+مباشر هنا هيدروجين و كرمون مين عليها هيدروجين اكثر
+
+226
+00:19:42,400 --> 00:19:48,780
+هذه بناء على ذلك لما انا بقول بدي اضيف HPR في وجود
+
+227
+00:19:48,780 --> 00:19:53,320
+H Plus وين اجت الهيدروجين؟ بهذا الشكل وين اجت ال
+
+228
+00:19:53,320 --> 00:20:02,760
+PR؟ بهذا الشكل واضح؟هي اللي بديها دلوقت بتجي
+
+229
+00:20:02,760 --> 00:20:09,060
+بالجهتين، من فوق و من تحت، قليلا بس شويه هذه
+
+230
+00:20:09,060 --> 00:20:14,000
+الفكرة متطورة اكثر من ان ابيع فيها بقى بتيجي من
+
+231
+00:20:14,000 --> 00:20:17,260
+فوق و من تحت يعنى، بس مش موضوعنا لإنه علاقة
+
+232
+00:20:17,260 --> 00:20:22,410
+بالستيل و كيميسترا، الآن هاي مركب تانيهي عندكم
+
+233
+00:20:22,410 --> 00:20:27,170
+double bond وين الطرفين ال double bond؟ هدى و هدى،
+
+234
+00:20:27,170 --> 00:20:33,570
+الآن هنا في شيء مش مرسوم ولا لأ؟ أكيد ال H الأكيد
+
+235
+00:20:33,570 --> 00:20:35,150
+ال H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال
+
+236
+00:20:35,150 --> 00:20:35,390
+H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+237
+00:20:35,390 --> 00:20:35,870
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+238
+00:20:35,870 --> 00:20:35,890
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+239
+00:20:35,890 --> 00:20:36,110
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+240
+00:20:36,110 --> 00:20:36,610
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+241
+00:20:36,610 --> 00:20:36,610
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+242
+00:20:36,610 --> 00:20:39,010
+الأكيد ال H ال أكيد ال H ال أكيد ال H ال أكيد ال H
+
+243
+00:20:39,010 --> 00:20:44,980
+ال أكيد ال H ال أكيد ال H الإذا لو أنا كنت بدى
+
+244
+00:20:44,980 --> 00:20:51,000
+أكمل HPR في وجود H Plus كيف سأكتب الناتج؟ يعني لو
+
+245
+00:20:51,000 --> 00:20:57,060
+أنه أكمل المعادلة HPR H Plus بدى أحط الهيدروجين ع
+
+246
+00:20:57,060 --> 00:21:02,360
+اللي حاملة هيدروجين أكتر يعني بدى أحطها ناسيه H3
+
+247
+00:21:02,360 --> 00:21:12,340
+وH هدولة اللي كانوا أصلا وجدت بدى أحط ال H تحتو ال
+
+248
+00:21:12,340 --> 00:21:18,800
+PR على هذا الكربون هذه إضافة ماركوفنيكوف الان لما
+
+249
+00:21:18,800 --> 00:21:24,560
+نيجي نعطيكم كملوا المعادلة HPR في وجود البروكسايد
+
+250
+00:21:24,560 --> 00:21:29,300
+بدي أحط بالعكس بدي أحط بالعكس ولذلك لو بتيجي
+
+251
+00:21:29,300 --> 00:21:33,080
+تتطلعوا هنا وين ال PR موجودة على أي كربون
+
+252
+00:21:35,850 --> 00:21:39,270
+هيها طبعا هو ورا السماء مرة لتحت و مرة لفوق هذا
+
+253
+00:21:39,270 --> 00:21:43,710
+السؤال الذكي اللي سألته زملتكوا بس بدناش نطول فيه
+
+254
+00:21:43,710 --> 00:21:46,830
+بيجعل
+
+255
+00:21:46,830 --> 00:21:51,550
+جهتين مش فيها مشكلة بس في كل الأحوال على أي carbon
+
+256
+00:21:51,550 --> 00:21:56,560
+إجت ال PRعلى حملة الهيدروجين على أي كاربون إجت
+
+257
+00:21:56,560 --> 00:22:00,840
+الهيدروجين على اللي أقل هذي Markov Nikov ولا أنت
+
+258
+00:22:00,840 --> 00:22:05,680
+Markov Nikov؟ أنا مابديش ياكلتوه في الشكل فوق و
+
+259
+00:22:05,680 --> 00:22:11,140
+تحت، حطوهم بس بالموقع الصح و غلط و مكفي، واضح؟
+
+260
+00:22:11,140 --> 00:22:15,140
+يعني لما بنكمل هذه المعادلة، ببساطة إيش يكون
+
+261
+00:22:15,140 --> 00:22:24,560
+الجواب؟ هنا ال H وهنا ال PRهك النتج بدون يصفر اكتر
+
+262
+00:22:24,560 --> 00:22:29,580
+من هيك تفصيل مابلزمنيش هذه مع ولا عكس Markovnikov
+
+263
+00:22:29,580 --> 00:22:33,700
+لما يكون هيك جوابه لغير ال double bond عكس
+
+264
+00:22:33,700 --> 00:22:38,500
+Markovnikov هنا ال H هنا ال PR مع Markovnikov
+
+265
+00:22:38,500 --> 00:22:39,200
+فاهمنا؟
+
+266
+00:22:50,600 --> 00:22:58,020
+بيجينا بعد هذه الإضافة إضافة جديدة هذه الإضافة
+
+267
+00:22:58,020 --> 00:22:59,980
+الجديدة
+
+268
+00:23:01,170 --> 00:23:07,110
+ان برضه احنا بنلغي فيها ال double bond و بنعمل two
+
+269
+00:23:07,110 --> 00:23:11,010
+new sigma bonds لكن هدول ال two new sigma bonds
+
+270
+00:23:11,010 --> 00:23:15,450
+بيكونوا على نفس ذرة ال oxygen ولذلك بيعطوني حلقة
+
+271
+00:23:15,450 --> 00:23:19,250
+ثلاثية لاحظوا هذا الكلام كيف هي عندكم carbon
+
+272
+00:23:19,250 --> 00:23:24,450
+carbon double bond صح ولا لأ الان لو فعلناها مع
+
+273
+00:23:24,450 --> 00:23:31,330
+bare acidBear بادئة معناها فوق يعني فيه ازيادة
+
+274
+00:23:31,330 --> 00:23:40,170
+الحامض العضوي كام أكسوجين فيه عادة ال acid؟ تنتيل
+
+275
+00:23:40,170 --> 00:23:44,570
+تلت روابط مع الأكسوجين يعني ال acid شكله العام
+
+276
+00:23:44,570 --> 00:23:55,300
+بهذا الشكل R C double bond O OH مشاكل الحامض؟RCOH
+
+277
+00:23:55,300 --> 00:23:59,640
+لو كانت هذه CH3 بيكون الاسيتك أسد لو كانت فنل
+
+278
+00:23:59,640 --> 00:24:05,260
+بيكون ال بنزويك أسد الان لو اجينا جنب ال COH
+
+279
+00:24:05,260 --> 00:24:12,400
+هتضيفنا كمان O يعني خلينا COOH زي هذا المركب اللي
+
+280
+00:24:12,400 --> 00:24:17,700
+هنا RCOOH
+
+281
+00:24:17,700 --> 00:24:24,640
+هذا زاد عندى بإيش؟بأكسوجينة صار فيه تلت أكسوجينات
+
+282
+00:24:24,640 --> 00:24:28,640
+هذا كام أكسوجينة في تنتين الآن هذا المركب اللي
+
+283
+00:24:28,640 --> 00:24:34,920
+صيرته العامة R C double bond O O O H بنسميه pear
+
+284
+00:24:34,920 --> 00:24:41,230
+acid فوق حامضيعني زاد فيه ال oxygen بمقدار ضرر
+
+285
+00:24:41,230 --> 00:24:46,310
+يعرفنا إيش معنى pear acid و لما نسميه بنسميه على
+
+286
+00:24:46,310 --> 00:24:49,570
+اسم الحامض الأصلي اللي كان موجود يعني لو افترضنا
+
+287
+00:24:49,570 --> 00:24:54,810
+الحامض الأصلي acidic acidبصير اللي فيه أكسجينة
+
+288
+00:24:54,810 --> 00:25:01,350
+زيادة بير أسيتك أسد، بنزويك أسد، بير بنزويك أسد،
+
+289
+00:25:01,350 --> 00:25:06,930
+يعني نفس الحامض تماما بس بنزيد عليه إيش؟ بير، يمكن
+
+290
+00:25:06,930 --> 00:25:12,590
+مرت عليكم لما أخدتوا أحماض الكلور مع الأكسجين لما
+
+291
+00:25:12,590 --> 00:25:18,510
+أخدتوا ال بيريكلوريك أسدمش كان عندكوا ClO3 لكلوريك
+
+292
+00:25:18,510 --> 00:25:25,530
+أسد لما صار ClO4 زاد أكسوجينة بيريكلوريك أسد واضح
+
+293
+00:25:25,530 --> 00:25:31,230
+فبير هنا بمعنى إيش الزيادة لو فعلنا الالكين مع
+
+294
+00:25:31,230 --> 00:25:36,480
+البر أسدمرة تانية بتنكسر ال double bond و بتعمل
+
+295
+00:25:36,480 --> 00:25:40,900
+رابطتين sigma لكن مع نفس ذرة ال oxygen اذا هذه
+
+296
+00:25:40,900 --> 00:25:48,220
+العملية ايضا عملية ايش اضافة تحويل ال by bond الى
+
+297
+00:25:48,220 --> 00:25:54,080
+two new sigma bonds اضافة ولا مش اضافة اضافة لكن
+
+298
+00:25:54,080 --> 00:25:56,880
+الان ال two new sigma bonds على نفس ال oxygen
+
+299
+00:25:56,880 --> 00:26:04,040
+فالناتج حلقة ثلاثيةالناتج حلقة ثلاثية هذه الحلقة
+
+300
+00:26:04,040 --> 00:26:10,460
+الثلاثية من ذرتين كربون و من أكسوجينة حلقة ثلاثية
+
+301
+00:26:10,460 --> 00:26:14,560
+ذرتين كربون و أكسوجينة هذه الثلاث ذرات تعونها الآن
+
+302
+00:26:14,560 --> 00:26:21,140
+هذه الحلقة الثلاثية كعائلة بيسموها ابوكسايد يعني
+
+303
+00:26:21,140 --> 00:26:25,380
+لو قلتلكم ما هي عائلة الابوكسايد لاحظوا family في
+
+304
+00:26:25,380 --> 00:26:29,660
+عندنا family و في عندنا في جوا ال family ايش أفراد
+
+305
+00:26:30,500 --> 00:26:33,720
+هك بتكون تفهموا الكيميا ان في العائلة العامة زي ال
+
+306
+00:26:33,720 --> 00:26:40,800
+ketones ال ketone family عائلة الآن جواتها acetone
+
+307
+00:26:40,800 --> 00:26:46,740
+وcyclohexanone وكذا وكذا ال alkenes عائلة جواتها
+
+308
+00:26:46,740 --> 00:26:53,910
+methane إيثين بروبين الآن ال epoxidesعائلة أيضا مش
+
+309
+00:26:53,910 --> 00:26:59,130
+اسم مركّب الابوكسايد عائلة الان طب ايش في جوات هذه
+
+310
+00:26:59,130 --> 00:27:05,730
+العائلة مركّبات؟ carbon تانو اكسوجينة وين بدو يصير
+
+311
+00:27:05,730 --> 00:27:10,630
+الخلاف؟ بدو يصير الخلاف في هدول المجموعات هل هدول
+
+312
+00:27:10,630 --> 00:27:14,130
+الأربعة هيدروجينز؟ هل واحدة فيهم مثل؟ هل تنتين
+
+313
+00:27:14,130 --> 00:27:16,910
+مثل؟ هل التلاتة مثل؟ هل الأربعة مثل؟ هل واحدة إثل؟
+
+314
+00:27:16,910 --> 00:27:23,540
+هل واحدة بروبل؟وجدتها بيصير لكل مركب اسم طب كيف
+
+315
+00:27:23,540 --> 00:27:28,760
+بنسمي كل مركب؟ العملية سهلة بنيجي بنسأل نفسنا إيش
+
+316
+00:27:28,760 --> 00:27:36,160
+اسم الألكين الأصلي تبعه اللي كونه؟والناتج لما
+
+317
+00:27:36,160 --> 00:27:39,900
+نعمله بنسميه باسم الالكين بنضيف عليه oxide يعني
+
+318
+00:27:39,900 --> 00:27:46,200
+مثلا لو كان الالكين اللي عندكم CH2 double bond CH2
+
+319
+00:27:46,200 --> 00:27:53,580
+هين حددنا مركب محدد هذا إيش اسمه اثيلين او اثيل
+
+320
+00:27:53,580 --> 00:27:59,300
+اثيلين الآن فعلنا مع ال bare acid هذا اللي موجود
+
+321
+00:27:59,300 --> 00:28:05,840
+عندناهتلتغي هذه الـ bi-bond وتعطيني أكسوجينة صار
+
+322
+00:28:05,840 --> 00:28:11,480
+عندى CH2 خلّيني نخلي الهيدروجين يخلع برا مرسومين
+
+323
+00:28:11,480 --> 00:28:14,620
+CH2
+
+324
+00:28:14,620 --> 00:28:23,280
+CH2 و هنا أكسوجين الآن هذا من أي مركب نتاج من
+
+325
+00:28:23,280 --> 00:28:30,910
+الإثالين شو بدي أسميه إثالين أكسيد نسبة للأصلإذا
+
+326
+00:28:30,910 --> 00:28:35,970
+تسمية هذه المراكبات تسمية هذه المراكبات كل فرد
+
+327
+00:28:35,970 --> 00:28:42,350
+منها كيف بسميه باسم القلقين الأصلي مضاف إليه كلمة
+
+328
+00:28:42,350 --> 00:28:49,350
+أكسايد أثالين أكسايد واضحة الفكرة ولا لأ ماشي
+
+329
+00:28:49,350 --> 00:28:53,410
+أتأكد أنها واضحة ولا لأ الآن لو اني جيبت هذا
+
+330
+00:28:53,410 --> 00:28:58,310
+المراكب في الامتحان وقلتلك لو سمحته سمولي هذا
+
+331
+00:28:58,310 --> 00:29:04,760
+المراكبزي هيك هذا جايكوا في الامتحان و أنا قلتلكوا
+
+332
+00:29:04,760 --> 00:29:11,860
+صموه واحدة
+
+333
+00:29:11,860 --> 00:29:15,960
+بس Cyclohexane
+
+334
+00:29:15,960 --> 00:29:22,210
+Oxide بتكون تقولوا هذا إيش كان أصلاهي اللي شيلت
+
+335
+00:29:22,210 --> 00:29:26,990
+هذه .. هذا أصلا كان هيك لما ضيفت عليه شيلت ال
+
+336
+00:29:26,990 --> 00:29:30,910
+double bond و حطيت ال oxygen طب زي هيك إيش اسمه؟
+
+337
+00:29:30,910 --> 00:29:41,120
+Cyclohexane شيلنا هذه صار Cyclohexane oxideواضح؟
+
+338
+00:29:41,120 --> 00:29:48,940
+إذا هذه المركبات كأفراد تسمى باسم القلقين الأصلي
+
+339
+00:29:48,940 --> 00:29:55,160
+باسم القلقين الأصلي مضاف إلى كلمة Oxide واضحة ولا
+
+340
+00:29:55,160 --> 00:30:04,340
+ما واضحت؟ واضحة تماما، الآن إلها تسمية تانية كتير
+
+341
+00:30:04,340 --> 00:30:10,260
+في ناس بياخدوا أكتر من اسم، إلها تسمية تانيةأبسط
+
+342
+00:30:10,260 --> 00:30:15,340
+مُركّب في هذه العائلة كلها أي واحد الـ ethylene
+
+343
+00:30:15,340 --> 00:30:22,620
+oxide ليش؟ لأنه هنا O CH H H H H هذا المُركّب
+
+344
+00:30:22,620 --> 00:30:27,980
+الأبسط فيهم هذا المُركّب الأبسط ماخد اسم اسمه
+
+345
+00:30:27,980 --> 00:30:37,990
+Oxirane Oxirane تمام؟Oxirane بنحفظه ايه كويس الان
+
+346
+00:30:37,990 --> 00:30:43,270
+هذا ال Oxirane بنتخيله تلت مواقع بنبدأ ترقيمه من
+
+347
+00:30:43,270 --> 00:30:50,170
+ال Oxygen بنقول واحد اتنين تلاتةبنسميه ال parent
+
+348
+00:30:50,170 --> 00:30:55,410
+compound عمرنا قولنا كلمة parent المركب الأبسط
+
+349
+00:30:55,410 --> 00:30:59,310
+دائما بنقول عنه ال parent compound الآن هذا ال
+
+350
+00:30:59,310 --> 00:31:02,610
+parent compound لو يا ترى شيلنا من هدول ال
+
+351
+00:31:02,610 --> 00:31:10,870
+hydrogen ال hydrogen واحدة وحطينا بدلها CH3 واحدة
+
+352
+00:31:10,870 --> 00:31:12,610
+تقولي ايش بدها تسمي وجتها
+
+353
+00:31:15,250 --> 00:31:20,130
+أوكز إيرين المركب الأصلي على موقع اتنين إيش إجاله
+
+354
+00:31:20,130 --> 00:31:30,210
+مثل إذا هذا بيصير two مثل أوكز إيرين أنا اعتبرت ال
+
+355
+00:31:30,210 --> 00:31:34,990
+أوكز إيرين اللي فيه أربعة هيدروجين شلت منه واحدة
+
+356
+00:31:34,990 --> 00:31:39,630
+محل ما شلت بكتب اسم المجموعة لو كان كلور two chlor
+
+357
+00:31:39,630 --> 00:31:44,780
+أوكز إيرين لو كانت إثلتوقث ال Oxirane تعرفنا كيف
+
+358
+00:31:44,780 --> 00:31:49,800
+هذا سمنها؟ الآن هي تسمية هذا المركب اللي أمامكم
+
+359
+00:31:49,800 --> 00:31:54,360
+بطريقة ال Oxirane طب لو واحدة بدأت تسميه بطريقة ال
+
+360
+00:31:54,360 --> 00:32:02,200
+Alkyl Oxide، شو هتسميه؟ بروبين أكسيد، بروبين
+
+361
+00:32:02,200 --> 00:32:04,780
+أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد،
+
+362
+00:32:04,780 --> 00:32:05,560
+بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين
+
+363
+00:32:05,560 --> 00:32:06,080
+أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد،
+
+364
+00:32:06,080 --> 00:32:08,440
+بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين
+
+365
+00:32:08,440 --> 00:32:16,320
+أكسيد، بروبين أكسما هذا الالكين؟ واحد CH2 double
+
+366
+00:32:16,320 --> 00:32:22,300
+bond CH CH3 هذا الابروبيل و لذلك بيصير ابروبيل
+
+367
+00:32:22,300 --> 00:32:27,900
+أكسيد فلو جيبنالكم مثلا سؤال ابروبيل أكسيد is also
+
+368
+00:32:27,900 --> 00:32:32,780
+called وقتها بتقولوا 2-methyl oxirane 2-methyl
+
+369
+00:32:32,780 --> 00:32:38,900
+oxirane is also calledPropyl Oxide طبعا ال Oxirans
+
+370
+00:32:38,900 --> 00:32:42,760
+هذه في الكيميا الحلقية غير المتجانسة بنستعملها
+
+371
+00:32:42,760 --> 00:32:46,480
+أكتر في الكيميا العادية المشهورة أكتر يكون تسموها
+
+372
+00:32:46,480 --> 00:32:54,720
+نسبة للالكيم و تحطو إيش Oxide الإسمين بتلاقوهم إذا
+
+373
+00:32:54,720 --> 00:33:01,620
+شفنا هذه المراكبات كيف بنحضرها و كيفبنسميها كيف
+
+374
+00:33:01,620 --> 00:33:05,560
+بنحضرها و كيف بنسميها عساريا مينندسيا هل هذه
+
+375
+00:33:05,560 --> 00:33:08,800
+التسمية بتسميها ايوباك ولا ايوباك؟ لأ لأ هي
+
+376
+00:33:08,800 --> 00:33:14,240
+التسمية اللي هي ال auxirene نظام تسمي بسموه Hans
+
+377
+00:33:14,240 --> 00:33:18,550
+Wiedemann system of nomenclatureيستعمل عن طلاب
+
+378