diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/1BnFNPVSqwg_raw.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/1BnFNPVSqwg_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..6914c938be905996dfe971c1b5c304b78a48a886 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/1BnFNPVSqwg_raw.srt @@ -0,0 +1,1828 @@ +1 +00:00:05,400 --> 00:00:07,760 +أعوذ بالله السميع العليه من الشياطان الرديع بسم + +2 +00:00:07,760 --> 00:00:10,600 +الله الرحمن الرحيم الحمد لله و الصلاة والسلام على + +3 +00:00:10,600 --> 00:00:14,800 +رسول الله اللهم صلى على سيدنا محمد وعلى آله وصحبه + +4 +00:00:14,800 --> 00:00:19,580 +وسلم أجمعين عزائي الطلاب قبل ذي بدء أرحبكم جميعا + +5 +00:00:19,580 --> 00:00:23,800 +في بداية محاضرة جديدة وأحييكم بتحية الإسلام العظيم + +6 +00:00:23,800 --> 00:00:29,510 +فالسلام الله عليكم ورحمته وبركاتهوبعد فقد انتهينا + +7 +00:00:29,510 --> 00:00:34,790 +من الفصل التمهيدي واليوم نرحل بصحبتكم إلى الفصل + +8 +00:00:34,790 --> 00:00:39,110 +الثاني وهو نظام العبادة في الإسلام وقد قلنا بأن + +9 +00:00:39,110 --> 00:00:44,190 +الفصل الأول وهو العقيدة غير مطلوب في الامتحانات + +10 +00:00:44,190 --> 00:00:52,810 +لأنهسيقرر عليكم في مساكن مستقل في كلية وصول الدين + +11 +00:00:52,810 --> 00:00:58,130 +شرح وصول العقيدة الإسلامية لزميلنا الدكتور نسيم + +12 +00:00:58,130 --> 00:01:07,560 +شيحدا ياسيم نبدأ على بركة الله فالعبادةسوف نتعرض + +13 +00:01:07,560 --> 00:01:12,300 +لها في مباحثة ثلاثة أولا تعريف العبادة لغة + +14 +00:01:12,300 --> 00:01:18,760 +واصطلاحا و ثانيا غاية العبادة و حكمتها أما ثالثا و + +15 +00:01:18,760 --> 00:01:25,300 +أخيرا خصائص العبادة في الإسلام أما العبادة في + +16 +00:01:25,300 --> 00:01:30,350 +اللغة فهي من الفعل عبدةمن الفعل الثلاثي المجرد + +17 +00:01:30,350 --> 00:01:35,070 +العين والباء والدال وهي في لغة العرب تأتي بمعنى + +18 +00:01:35,070 --> 00:01:44,530 +خضعة وذلة ولذا يقال عند العرب أرض معبدة أرض معبدة + +19 +00:01:44,530 --> 00:01:50,290 +بمعنى ممهدة ومذللة + +20 +00:01:51,370 --> 00:01:57,930 +لعب جاجة فيها وكذلك يقال دابة معبدة بمعنى أيضا + +21 +00:01:57,930 --> 00:02:05,370 +مذللة وخاضعة لصاحبها فلا تعصي أوامرهم وكذلك هي + +22 +00:02:05,370 --> 00:02:10,370 +العبادة في الإسلام التزلل لله والخضوع بين يدي الله + +23 +00:02:10,370 --> 00:02:17,470 +سبحانه وتعالى أما العبادة اصطلاحا فهي فعل مكلف على + +24 +00:02:17,470 --> 00:02:26,170 +خلاف هو نفسهتعظيما لربه مرة ثانية العبادة في + +25 +00:02:26,170 --> 00:02:34,670 +الاصطلاح فعل المكلف على خلاف هو نفسه تعظيما لربه + +26 +00:02:34,670 --> 00:02:43,410 +والمكلف هو المسلم البالغ العاقل لأن غير المكلفلا + +27 +00:02:43,410 --> 00:02:50,050 +تجب عليه عبادة في الإسلام بحديث رفع القلم عن ثلاث + +28 +00:02:50,050 --> 00:02:56,050 +من النائم حتى يستيقظ وعن الصبي حتى يبلغ وعن + +29 +00:02:56,050 --> 00:03:02,370 +المجنون حتى يعقل وإذا أخذ ما أوهب أسقط ما أوجب كما + +30 +00:03:02,370 --> 00:03:09,950 +يقولونفالعبادة فعل مكلف و هو المسلم البالغ العاقل + +31 +00:03:09,950 --> 00:03:18,110 +على خلاف هوى نفسه تعظيما لربه لأن النفس قد تأمر + +32 +00:03:18,110 --> 00:03:26,190 +بالمعصية و قد تأمر بالفحشاء فالعبادة تعني أن يخالف + +33 +00:03:26,190 --> 00:03:33,270 +المسلم هواه و أن يعلم الحرب على نفسه الأمارة + +34 +00:03:33,270 --> 00:03:40,690 +بالسوءفأما من خاف مقام ربه ونهى النفس عن الهوى فإن + +35 +00:03:40,690 --> 00:03:47,310 +الجنة هي المأوى وهذه النفس التي بين جنبيك كما جاء + +36 +00:03:47,310 --> 00:03:53,230 +في الأثر هي أعداء أعدائك أعداء أعدائك نفسك التي + +37 +00:03:53,230 --> 00:04:02,770 +بين جنبيك ولذلك كانت من الأعداء مع مجموعةمن + +38 +00:04:02,770 --> 00:04:09,590 +الأعداء الآخرين كالهوى والشيطان والدنيا وقد قال + +39 +00:04:09,590 --> 00:04:14,870 +الشاعر العربي إن ابتليت بأربع ما صلطوا إلا لشدة + +40 +00:04:14,870 --> 00:04:20,490 +شقوتي وعنائي إبليس والدنيا ونفسي والهوى كيف الخلاص + +41 +00:04:20,490 --> 00:04:28,570 +وكلهم أعداء والنفس في القرآن الكريم ثلاثة نفس + +42 +00:04:28,570 --> 00:04:36,970 +أمارة بالسوءوهي أشقاها كما في قصة يوسفة على لسان + +43 +00:04:36,970 --> 00:04:44,410 +امرأة العزيز وما أبرؤ نفسي إن النفس لأمارة بالسوء + +44 +00:04:44,410 --> 00:04:50,530 +هي النفس التي تأمر بالفحشاء والمنكر والمعصية + +45 +00:04:50,530 --> 00:04:56,950 +والسوء والنفس الثانية هي النفس اللوامة كما في صدر + +46 +00:04:56,950 --> 00:05:04,880 +صورة القيامةلا أقسم بيوم القيامة ولا أقسم بالنفس + +47 +00:05:04,880 --> 00:05:12,380 +اللوامة لماذا سميت النفس لوامة لأمرين لأنها تلوم + +48 +00:05:12,380 --> 00:05:22,300 +صاحبها إذا قصر في الطاعات نعم وتلوم صاحبها إذا فعل + +49 +00:05:22,300 --> 00:05:30,030 +المعصية وهذه نفس المؤمنفالمؤمن ليس ملكا كما أسلفنا + +50 +00:05:30,030 --> 00:05:35,370 +قد يتعرض إلى الطاعة وقد يتعرض إلى المعصي والنبي + +51 +00:05:35,370 --> 00:05:39,110 +عليه الصلاة والسلام قال كل بني آدم خطاء وخير + +52 +00:05:39,110 --> 00:05:45,230 +الخطائين التوبون فنفس المؤمن تلومه إذا قصر في + +53 +00:05:45,230 --> 00:05:54,410 +الطاعات أو فعل الخطيئات أما النفس الثالثة وهي نفسه + +54 +00:05:54,980 --> 00:06:01,700 +المخلصين أو المخلصين الذين أخلصهم الله تبارك + +55 +00:06:01,700 --> 00:06:08,460 +وتعالى لعبادته وهي النفس المطمئنة التي انتصرت على + +56 +00:06:08,460 --> 00:06:14,780 +الهوى وانتصرتعلى الشيطان واطمأنت إلى جنب الله وإلى + +57 +00:06:14,780 --> 00:06:20,120 +ذكر الله يا أيتها النفس المطمئنة ارجعي إلى ربك + +58 +00:06:20,120 --> 00:06:25,640 +راضية مرضية فادخلي في عبادي وادخلي جنتي هذا هو + +59 +00:06:25,640 --> 00:06:31,140 +المصطلح الأول وهو المصطلح المطلوب منه في الامتحان + +60 +00:06:31,140 --> 00:06:35,600 +لأن الامتحان كما ذكرنا أكثر من مرة سيأتي على صور + +61 +00:06:35,600 --> 00:06:45,260 +سلاسة صح أو خطأواختيار متعدد ومصطلح توصيل إذا كان + +62 +00:06:45,260 --> 00:06:50,920 +الامتحان إلكترونيا أو أذكر المصطلح الذي يناسب + +63 +00:06:50,920 --> 00:06:56,320 +العبارات التالية إذا كان الامتحان ورقيا إذا + +64 +00:06:56,320 --> 00:07:03,630 +العبادة كما هي في المصطلح الشرعي هي فعل مكلفعلى + +65 +00:07:03,630 --> 00:07:10,310 +خلاف هوى نفسه تعظيمًا لربه أو كما قال هنا هي حب + +66 +00:07:10,310 --> 00:07:17,950 +الله تبارك وتعالى والخضوع والتزلل له وكما نرى ثمة + 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+كما قال الله تبارك وتعالى في عباده المؤمنين + +79 +00:08:29,740 --> 00:08:36,710 +الصالحين يحبهم ويحبونهمهذا هو تعريف العبادة + +80 +00:08:36,710 --> 00:08:46,190 +الإصطلاحي لكن العبادة في حقيقة معناها ومفهومها لا + +81 +00:08:46,190 --> 00:08:54,150 +تقتصر على أركان الإسلام وهنا أعزائي الطلابلابد أن + +82 +00:08:54,150 --> 00:09:00,150 +نقف قليلا عند هذه العبارة لأن البعض يظن أن العبادة + +83 +00:09:00,150 --> 00:09:06,550 +فقط هي أركع الإسلام الأربعة من صوم وصلاة وحج وذكاء + +84 +00:09:06,550 --> 00:09:14,230 +وما هذه إلا صور من صور العبادة في الإسلام وإلا كيف + +85 +00:09:14,230 --> 00:09:18,030 +يقول الله تبارك وتعالى في أواخر صورة الذريات وما + +86 +00:09:18,030 --> 00:09:25,010 +خلقت الجن والإنس إلا ليعبدونفالعبادة هنا بالمعنى + +87 +00:09:25,010 --> 00:09:32,270 +العام ولا تقتصر العبادة بمعناها ومفهومها العام على + +88 +00:09:32,270 --> 00:09:39,630 +الصلاة والصوم والحج والزكاه إذا العبادة بمعناها + +89 +00:09:39,630 --> 00:09:50,570 +العام كل أمر أو فعل أو شيء يبتغى به وجه الله تبارك + +90 +00:09:50,570 --> 00:09:58,060 +وتعالىفكل ما يبتغى به وجه الله هو عبادة فالجهاد في + +91 +00:09:58,060 --> 00:10:07,240 +سبيل الله عبادة بر الوالدين عبادة حتى التبسم في + +92 +00:10:07,240 --> 00:10:11,720 +وجه أخيك المسلم عبادة ألم نتكلم على ذلك في + +93 +00:10:11,720 --> 00:10:19,180 +المثالية من خصائص النظم الإسلامية وهي الخاصية + +94 +00:10:19,180 --> 00:10:24,830 +السابعةوقد قال عليه الصلاة والسلام تبسمك في وجه + +95 +00:10:24,830 --> 00:10:30,090 +أخيك صدق كما في حديث عائشة أيضا رضي الله عنها لا + +96 +00:10:30,090 --> 00:10:36,070 +تحكرن من المعروف شيئا و لو أنطلق أخاك بوجه طليق + +97 +00:10:36,070 --> 00:10:43,350 +نعم و كذلك إيثار الآخرين عبادة حب الوطن عبادة + +98 +00:10:43,350 --> 00:10:50,570 +اتقان العملوعدم الغش أيضًا باب من أبواب العبادة + +99 +00:10:50,570 --> 00:10:58,200 +وكذلك النفقة على الأقارب ونبذ الأنانية وصلةالأرحام + +100 +00:10:58,200 --> 00:11:05,460 +كل ذلك من ألوان و من صور العبادة في الإسلام و كذلك + +101 +00:11:05,460 --> 00:11:11,120 +إكرام الضيف و إكرام الجار بل إماطة الأذى عن الطريق + +102 +00:11:11,120 --> 00:11:16,620 +و تعلم الصباحة و الرماية و التمرس بفنون الحرب و + +103 +00:11:16,620 --> 00:11:22,420 +القتال كل ذلك يدخل في معنى العبادة بمفهومها الواسع + +104 +00:11:22,420 --> 00:11:29,360 +و معناها العامإذا أعود إلى ذي بدء فأقول بأن + +105 +00:11:29,360 --> 00:11:35,280 +العبادة في الإسلام لها معناه يعني معناه خاص وهذا + +106 +00:11:35,280 --> 00:11:41,880 +غير مطلوب وهو أركان الإسلام الأربعة بعد الشهادتين + +107 +00:11:41,880 --> 00:11:46,640 +الصلاة والصوم والحج والذكاء هذا هو المعنى الخاص + +108 +00:11:46,640 --> 00:11:53,410 +للعبادة أما المطلوب في هذا الفصلهو العبادة + +109 +00:11:53,410 --> 00:11:58,210 +بمفهومها العام لأن البعض يتساءل يقول إذا كانت + +110 +00:11:58,210 --> 00:12:06,490 +العبادة هي أركان الإسلام فمتى نعمل ومتى نتزوج ومتى + +111 +00:12:06,490 --> 00:12:12,410 +نصل الأرحم ومتى نجاهد في صبر الله فنقول إذا كان + +112 +00:12:12,410 --> 00:12:19,780 +ذلك مشفوعا بالنيتيفهو عبادة بل كأجران كما سيأتي + +113 +00:12:19,780 --> 00:12:26,320 +معناه في باب النفقة من حقوق الزوجة عند الحديث عن + +114 +00:12:26,320 --> 00:12:31,700 +الفصل الرابع ان شاء الله نظام الأسرة في الإسلام + +115 +00:12:31,700 --> 00:12:40,300 +فالرجل يعمل و يكسب و يجد و يجتهدويأتي بالمال لينفق + +116 +00:12:40,300 --> 00:12:47,460 +على أهله ليضع اللقمة في فم زوجه وولده وهو يحتسبها + +117 +00:12:47,460 --> 00:12:53,120 +وسنأتي إلى ذكر الحديث ان شاء الله فهي صدقة متقبلة + +118 +00:12:53,120 --> 00:12:57,040 +عند الله ولذلك النبي عليه الصلاة والسلام قال هذا + +119 +00:12:57,040 --> 00:13:03,380 +الذي يعمل ويبتغي وجه الله ويحتسبها صدقة في سبيل + +120 +00:13:03,380 --> 00:13:12,680 +الله له أجرانهنعم كما قال في قصة موسى عليه السلام + +121 +00:13:12,680 --> 00:13:22,140 +كأم موسى ترضع ولدها وتأخذ أجرها نعم كأم موسى هكذا + +122 +00:13:22,140 --> 00:13:26,460 +النبي عليه السلام يشبه هذا الرجل الذي يعمل من أجل + +123 +00:13:26,460 --> 00:13:31,500 +الدنيا ويبتغي وجه الله كأم موسى ترضع ولدها وتأخذ + +124 +00:13:31,500 --> 00:13:39,230 +أجرها ولذلك إذا جاءكمسؤال في الإمتحان إن معنى + +125 +00:13:39,230 --> 00:13:45,010 +العبادة هو الصلاة والصوم والحج والذكاء فالإجابة + +126 +00:13:45,010 --> 00:13:52,390 +خطأ وليست صحيحة لأن العبادة أشمل من ذلك فهي تشمل + +127 +00:13:52,390 --> 00:14:01,070 +كما أسلفنا كل فعلأو كل عمل يبتغى به وجه الله حتى و + +128 +00:14:01,070 --> 00:14:06,790 +لو كان عملا كالكسب و جمع المال و السعي على الأيال + +129 +00:14:06,790 --> 00:14:12,650 +من أجل أن يسطر نفسه و يسطر زوجه ولده و ألا يتكسب + +130 +00:14:12,650 --> 00:14:22,110 +بالسؤال و مد اليد إلى الآخرين و النبي عليه الصلاة + +131 +00:14:22,110 --> 00:14:28,410 +والسلام قال اليد العليا خيرمن اليد الصفلاء نعم + +132 +00:14:28,410 --> 00:14:37,230 +الآن بعد المبحث الأول الذي عرفنا فيه العبادة لغة + +133 +00:14:37,230 --> 00:14:42,910 +واصطلاحا نأتي إلى المبحث الثاني و هو بعنوان غاية + +134 +00:14:42,910 --> 00:14:49,230 +العبادة و حكمتها فالعبادة ليست من أجل الرياضة و من + +135 +00:14:49,230 --> 00:14:55,310 +أجل الحركات أو من أجل القيام و القعود و إنما لها + +136 +00:14:55,940 --> 00:15:04,040 +غاية نعم ولها حكمة نعم أفحسبتم أنما خلقناكم عبسة + +137 +00:15:04,040 --> 00:15:09,480 +وأنكم إلينا لا ترجعون وهنا لابد من التفريق بين + +138 +00:15:09,480 --> 00:15:17,000 +المبحث الثاني الذي هو بعنوان غاية الإبادة وحكمتها + +139 +00:15:17,000 --> 00:15:25,000 +وبين المبحث الثالث الذي هو خصائصهالعبادة في + +140 +00:15:25,000 --> 00:15:30,840 +الإسلام ومزاياها فانتبهوا إلى ذلك عند السؤال وعند + +141 +00:15:30,840 --> 00:15:37,720 +الامتحان لأنه قد يأتي سؤال مثلا تحقيق العبودية لله + +142 +00:15:37,720 --> 00:15:44,400 +وحده عند الإختيار المتعدد هل هذا من الغيات أم هذا + +143 +00:15:44,400 --> 00:15:52,700 +من الخصائص نعم دقيقوافي ذلك وانتبهوا إليه وغاية + +144 +00:15:52,700 --> 00:15:59,240 +العبادة وحكمتها ثلاثة أولها تحقيق العبودية لله + +145 +00:15:59,240 --> 00:16:05,920 +وحده وذلك بمعنى أن تكون العبودية من الإنسان لله + +146 +00:16:05,920 --> 00:16:15,230 +الخالق وحده دون سواهفالله له العبادة وحده لا شريك + +147 +00:16:15,230 --> 00:16:21,750 +له سبحانه وتعالى فلا سجود إلا لله ولا ركوع إلا لله + +148 +00:16:21,750 --> 00:16:28,510 +ولا خضوع إلا لله ولا تذلل إلا بين يدي الله سبحانه + +149 +00:16:28,510 --> 00:16:35,470 +وتعالى ثانيا تغذية الكيان الروحي في الإنسان لأن + +150 +00:16:35,470 --> 00:16:39,150 +الإنسان له كيانان كيان + +151 +00:16:40,400 --> 00:16:54,260 +طيني من التراب وكيان روحي من الله ولكل غذائه فغذاء + +152 +00:16:54,260 --> 00:17:03,560 +الشق الطيني من الأرض من طعام و شراب و نحو ذلك منها + +153 +00:17:03,560 --> 00:17:11,850 +خلقناكموفيها نعيدكم ومنها نخرجكم ترة أخرى أما غذاء + +154 +00:17:11,850 --> 00:17:18,930 +الروح من السماء من عند الله تبارك وتعالى والإنسان + +155 +00:17:18,930 --> 00:17:27,950 +بشقه الروحي وليس بشقه الطيني لو كان الإنسان بالطين + +156 +00:17:27,950 --> 00:17:34,810 +و لو كان الإنسان بالتراب و لو كان الإنسان بالطول + +157 +00:17:35,360 --> 00:17:44,120 +والعرض ونحو ذلك لكانت الحيوانات اعزكم الله اعظم + +158 +00:17:44,120 --> 00:17:51,380 +قدرا من الإنسان انظروا الى الفيلة انظروا الى + +159 +00:17:51,380 --> 00:17:57,780 +الحيتانانظروا إلى الثيران، انظروا إلى الذرفات كم + +160 +00:17:57,780 --> 00:18:03,340 +هي أضخم من هذا الإنسان، ولكن الله سبحانه وتعالى + +161 +00:18:03,340 --> 00:18:11,790 +كرّم الإنسان بروحهلأنها من عند الله لطيفة ربانية + +162 +00:18:11,790 --> 00:18:17,170 +نورانية نفخها الله تبارك وتعالى في هذا الإنسان + +163 +00:18:17,170 --> 00:18:23,890 +أليس الله هو القائل في صورة الإسراء و لقد كرمنا + +164 +00:18:23,890 --> 00:18:28,870 +بني آدمةوحملناهم في البر والبحر ورزقناهم من + +165 +00:18:28,870 --> 00:18:34,770 +الطيبات وفضلناهم على كثير ممن خلقنا تفضيلة نعم + +166 +00:18:34,770 --> 00:18:40,250 +ولذلك قال الشعر العربي يا خادم الجسم كم تشقى + +167 +00:18:40,250 --> 00:18:46,650 +بخدمته أتطلب الربح مما فيه خسرانه؟هتطلب الربح مما + +168 +00:18:46,650 --> 00:18:51,530 +فيه خسرانه؟ انهض إلى الروح واستكمل فضائلها فانت + +169 +00:18:51,530 --> 00:18:57,610 +بالروح لا بالجسم إنسان حقا فانت بالروح لا بالجسم + +170 +00:18:57,610 --> 00:19:04,170 +إنسان لأن الروح لا تفنع وما لهذا الجسد الطيني + +171 +00:19:04,170 --> 00:19:10,210 +الترابي إلا صندوق ليحفظ هذه الروح فإذا انتقلت + +172 +00:19:10,210 --> 00:19:15,530 +الروح إلى بارئهالم يعد لهذا الجسدي مهمة أو فائدة + +173 +00:19:15,530 --> 00:19:24,970 +صرعان ما يفنى و يبلأ و يصبح بلا حركة بل يتحلله و + +174 +00:19:24,970 --> 00:19:31,170 +يعود إلى عناصره الأولى فهو من التراب و إلى التراب + +175 +00:19:31,170 --> 00:19:36,750 +لذا لابد من الالتفات إلى الكيان الروحي في الإنسان + +176 +00:19:36,750 --> 00:19:43,950 +و غذائه من السماء غذائه بقراءة القرآنبذكر الله + +177 +00:19:43,950 --> 00:19:51,050 +بالعبادات التي سبق ذكرها من صلاة و صوم و حج و ذكاء + +178 +00:19:51,050 --> 00:19:57,170 +و نحوها و التسبيحات و الأذكار و الأوراد و + +179 +00:19:57,170 --> 00:20:03,390 +المأثورات كل ذلك غذاء للروح ان شاء الله تعالى أما + +180 +00:20:03,390 --> 00:20:11,330 +ثالثا و أخيرا فمنغاية العبادة وحكمتها تقوية + +181 +00:20:11,330 --> 00:20:19,650 +الإرادة ومساندة الإنسان في معرفة الحياة فالإنسان + +182 +00:20:19,650 --> 00:20:27,810 +ضعيف نعم كما خلقه الله تعالى ضعيفا ولذلك عليه أن + +183 +00:20:27,810 --> 00:20:35,830 +يتقوى بالعبادة وأن يكون بين يدي اللهفإن الله أقرب + +184 +00:20:35,830 --> 00:20:42,450 +إليه من حبل الورد و هناك لا مشاكل إن شاء الله + +185 +00:20:42,450 --> 00:20:48,850 +تبارك وتعالى لأنه في الشدائد يهرع العبد إلى ربه + +186 +00:20:48,850 --> 00:20:56,850 +تبارك وتعالى فتقوى الإرادةبهذه العبادة لأن العبادة + +187 +00:20:56,850 --> 00:21:03,930 +كما سيأتي بعد قليل هي صلة بين العبد وربه فإذا نزلت + +188 +00:21:03,930 --> 00:21:11,810 +بك مصيبةأو حلت بك كارثة فما عليك إلا أن تهرع إلى + +189 +00:21:11,810 --> 00:21:20,230 +الله سبحانه وتعالى فإنه يفرج قربك بكون فيكون نعم + +190 +00:21:20,230 --> 00:21:27,410 +الآن بعد أن انتهينا من المبحث الثاني وهو بعنوان + +191 +00:21:27,410 --> 00:21:36,730 +غاية العبادة وحكمتها وهو منأمور سلاسة أول هذه + +192 +00:21:36,730 --> 00:21:44,330 +الأمور تحقيق العبودية لله تبارك وتعالى ثانيا تغذية + +193 +00:21:44,330 --> 00:21:50,670 +الكيان الروحي في الإنسان ثالثا تقوية الإرادة + +194 +00:21:50,670 --> 00:21:56,410 +ومساندة الإنسان في معرفة الحياة نأتي الآن إلى + +195 +00:21:56,410 --> 00:22:05,380 +المبحث الثالث وهو آخر المباحث في الفصل الثانينظام + +196 +00:22:05,380 --> 00:22:09,820 +العبادة في الإسلام خصائص العبادة في الإسلام هم مش + +197 +00:22:09,820 --> 00:22:15,280 +زيها ولا مانع أن أذكر مترة أخرى فأقول لابد من + +198 +00:22:15,280 --> 00:22:25,500 +التفريق عند الإجابة بين الغايات وبين الخصائصلأن + +199 +00:22:25,500 --> 00:22:32,040 +السؤال قد يختلط عليك فنأتي بالخصائص بدل الغايات او + +200 +00:22:32,040 --> 00:22:38,040 +نأتي بالغايات بدل الخصائص في حال الصح او الخطأ او + +201 +00:22:38,040 --> 00:22:44,320 +في حال الاختيار المتعدد نعم تكلمنا اذا عن غايات + +202 +00:22:44,320 --> 00:22:50,660 +العبادة و حكمة العبادة و انها لم تفرض علينا سدا + +203 +00:22:50,660 --> 00:22:57,790 +ولاعبسا ..الآن نأتي إلى خصائص العبادة في الإسلام + +204 +00:22:57,790 --> 00:23:04,790 +وهي خمسة إن شاء الله تبارك وتعالى أول هذه الخصائص + +205 +00:23:04,790 --> 00:23:11,950 +أن العبادة لا تكون إلا لله وحده وهنا أيضا لابد أن + +206 +00:23:11,950 --> 00:23:21,010 +أقف قليلاوإني لكم ناصح أمين لأنه من الأخطاء التي + +207 +00:23:21,010 --> 00:23:25,150 +مرت علينا في تصحي الامتحانات أنهم لا يفرقون بين ال + +208 +00:23:25,150 --> 00:23:32,310 +band الأول من الغايات وهو تحقيق العبودية للهوبين + +209 +00:23:32,310 --> 00:23:37,290 +البند الأول من الخصائص وهو بعنوان العبادة لا تكون + +210 +00:23:37,290 --> 00:23:42,650 +إلا لله وحده سبحانه وتعالى فانتبهوا إلى ذلك تحقيق + +211 +00:23:42,650 --> 00:23:47,050 +العبودية لله من الغايات العبادة لا تكون إلا لله + +212 +00:23:47,050 --> 00:23:52,170 +وحده من الخصائص بدليل قوله تبارك الله في أواخر + +213 +00:23:52,170 --> 00:23:58,450 +صورة الكهف فمن كان يرجو لقاء ربه فليعمل عملا صالحا + +214 +00:23:58,450 --> 00:24:06,230 +ولا يشركبعبادة ربه أحدى فلابد أن يكون العمل لله + +215 +00:24:06,230 --> 00:24:14,790 +واحدة حتى يكون متقبلا بعيدا عن الشرك الأكبر وهو + +216 +00:24:14,790 --> 00:24:19,210 +عبادة الصنم والوثن وهذا لم يعد له وجود بين + +217 +00:24:19,210 --> 00:24:25,250 +المسلمين وكذلك أن يكون بعيدا عن الشرك الأصغر اللى + +218 +00:24:25,250 --> 00:24:30,900 +هو الرياءكما قال الله في اكثر من موضع في حق + +219 +00:24:30,900 --> 00:24:37,920 +المنافقين مثلا انهم يؤدونالزكاة رياءً يا أيها + +220 +00:24:37,920 --> 00:24:43,700 +الذين آمنوا لا تبطلوا صدقاتكم بالمن والأذى كالذي + +221 +00:24:43,700 --> 00:24:47,920 +ينفق ما له رئاء الناس ولا يؤمن بالله واليوم الآخر + +222 +00:24:47,920 --> 00:24:54,560 +أو حتى يصلي رياءً كما قال الله في حق المنافقين + +223 +00:24:54,560 --> 00:24:59,780 +وإذا قاموا إلى الصلاة قاموا كسالة يراؤون الناس ولا + +224 +00:24:59,780 --> 00:25:05,700 +يذكرون الله إلا قليلاأو كما قال في موضوع آخر فويل + +225 +00:25:05,700 --> 00:25:11,820 +للمصلين الذين هم عن صلاتهم ثاهون الذين هم يراؤون + +226 +00:25:11,820 --> 00:25:19,480 +ويمنعون الماعوننعم، إذا حتى تكون العبارة متقبلة، + +227 +00:25:19,480 --> 00:25:24,420 +لابد أن يبتغى بها وجه الله كما جاء في الحديث + +228 +00:25:24,420 --> 00:25:31,280 +القدسي الجليل أنا أغنى الشركاء عن الشرك، من عمل + +229 +00:25:31,280 --> 00:25:39,180 +عملا أشرك فيه معي غيري، تركته شركةكما قال الله لإن + +230 +00:25:39,180 --> 00:25:44,860 +أشركت ليحبطن عملك فالشرك بنوعيه الأكبر و الأصغر + +231 +00:25:44,860 --> 00:25:53,480 +يحبط العملة وهنا نأتي إلى سؤال حول هذه النقطة أو + +232 +00:25:53,480 --> 00:25:58,540 +حول هذا البند وهو أن العبادة لا تكون إلا لله واحدة + +233 +00:25:58,540 --> 00:26:08,620 +وهي ثمار هذه النقطةماذا يترتب على ذلك من ثمار أو + +234 +00:26:08,620 --> 00:26:18,020 +من نتائج أولاأن العبادة لا تؤدى إلا لله كالركوع + +235 +00:26:18,020 --> 00:26:25,660 +والسجود فلا ركوع إلا لله ولا سجود إلا لله وكذلك + +236 +00:26:25,660 --> 00:26:30,960 +الزبيحة لا تكون إلا باسم الله فإذا زبحت الزبيحة + +237 +00:26:30,960 --> 00:26:37,710 +كما كانت تفعل العرب على النصبوهي حجارة كان يتقرب + +238 +00:26:37,710 --> 00:26:44,830 +بها العرب قبل الإسلام بالذباح إلى الأوسان وإلى + +239 +00:26:44,830 --> 00:26:50,090 +الأصمام وما ذبح على النصب ولا تأكلوا مما لم يذكر + +240 +00:26:50,090 --> 00:26:55,970 +اسم الله عليه فإن كانت الذبيحة باسم غير اسم الله + +241 +00:26:55,970 --> 00:27:07,640 +فهي ميتة لا يحل أكلهاثانيا وهذه نقطة مهمة اعزائنا + +242 +00:27:07,640 --> 00:27:12,720 +الطلاب لابد ان نقف عندها قليلا وهو انه يترتب على + +243 +00:27:12,720 --> 00:27:19,230 +ميزةوعلى خاصية أن العبادة لا تكون إلا لله واحدة + +244 +00:27:19,230 --> 00:27:27,530 +أنه لا مجال فيها للزيادة أو النقصان أو التعديل أو + +245 +00:27:27,530 --> 00:27:32,930 +التغيير وهذا معنى قولنا إن العبادة في الإسلام + +246 +00:27:32,930 --> 00:27:41,090 +توقيفيةومعنى توقفية أي أنه يوقف بها عند الحدود + +247 +00:27:41,090 --> 00:27:46,350 +التي حددها الله تبارك وتعالى وفي حالها النبي صلى + +248 +00:27:46,350 --> 00:27:52,830 +الله عليه وسلم فلا زيادة ولا نقصان ولا تعديل ولا + +249 +00:27:52,830 --> 00:27:59,410 +تغيير فمثلا لا يصح لشخص أن يقول اني استيقظ من + +250 +00:27:59,410 --> 00:28:01,250 +النوم نشطا + +251 +00:28:03,030 --> 00:28:10,970 +فأصلي صلاة الصبح أربعان وصلاة الصبح ركعتين أو مثلا + +252 +00:28:10,970 --> 00:28:18,890 +يقول أعود إلى البيت تعبا من عمل النهار فأريد أن + +253 +00:28:18,890 --> 00:28:26,480 +أصلي صلاة العشاء ركعتينفنقول له لا هذا أمر توقفي + +254 +00:28:26,480 --> 00:28:31,940 +من عند الله تبارك وتعالى لا زيادة ولا نقصان لا + +255 +00:28:31,940 --> 00:28:39,930 +تعديل ولا تبديل ولا تغيير فصلاة الفجر ركعتانمن زاد + +256 +00:28:39,930 --> 00:28:45,050 +أو نقص فقط بطلة صلاته وكذلك صلاته العشائي والظهري + +257 +00:28:45,050 --> 00:28:54,050 +والعصري أربعا أما صلاته المغرب فهي وتر فهي سلاسا + +258 +00:28:54,050 --> 00:29:02,000 +نعم ومن خارج الكتاب أقول حاول بعض الخلفاءفي + +259 +00:29:02,000 --> 00:29:08,680 +التاريخ الإسلامي أن يجعل صلاة العيد كصلاة الجمعة + +260 +00:29:08,680 --> 00:29:16,080 +حتى لا يخرج الناس أراد أن يجعل الخطبة أولا والصلاة + +261 +00:29:16,080 --> 00:29:23,360 +ثانيا حتى لا يخرج الناس من المسجد فقام عليه + +262 +00:29:23,360 --> 00:29:29,600 +العلماء العاملون الأمرون بالمعروف والنهون عن + +263 +00:29:29,600 --> 00:29:36,410 +المنكروقالوا له هذا وقف من عند الله هذا فعل رسول + +264 +00:29:36,410 --> 00:29:41,910 +الله وما ينطق عن الهوى صلى الله عليه وسلم في صلاة + +265 +00:29:41,910 --> 00:29:50,370 +العيد الصلاة أولا والخطبة ثانيا أما في صلاة الجمعة + +266 +00:29:50,370 --> 00:29:58,860 +فالخطبة أولا والصلاة ثانيافلا يصح أي تغيير أو + +267 +00:29:58,860 --> 00:30:08,320 +تبديل أو تعديل ثانيا يترتب على قولنا أن العبادة + +268 +00:30:08,320 --> 00:30:18,540 +توقفية أنها لا تعلّل بعلة لأن العلة خفية فلا يصح + +269 +00:30:18,540 --> 00:30:28,310 +أن يقال إن العلة من فردالوضوء مثلا النظافة أو من + +270 +00:30:28,310 --> 00:30:36,050 +فرض الصلاة الرياضة أو من فرض الصوم الصحى يمكن أن + +271 +00:30:36,050 --> 00:30:43,030 +نقول بأن هذه الأشياء هي فوائد وليست علالة لأن + +272 +00:30:43,030 --> 00:30:50,330 +العلة خفية لا يعلمها إلا الله تبارك وتعالى وما + +273 +00:30:50,330 --> 00:30:57,420 +علينا نحن المسلمينالذين آمنا بالله ربا وبمحمد + +274 +00:30:57,420 --> 00:31:05,640 +رسولا وبالإسلام دينا إلا السمع والطاعة نعم حتى و + +275 +00:31:05,640 --> 00:31:11,660 +لو غابت عن الحكمة أحيانا فإذا مسئولنا عن تحريم + +276 +00:31:11,660 --> 00:31:16,500 +الخمر لماذا حرم الله الخمر هناك من تكلم عن أضراره + +277 +00:31:16,500 --> 00:31:22,650 +ولكنالإجابة لأن الله حرّم علينا الخمر لماذا حرّم + +278 +00:31:22,650 --> 00:31:27,230 +الله الزنا لأن الله قد حرّم علينا الزنا وفيه ما + +279 +00:31:27,230 --> 00:31:33,480 +فيه من الأضرار هذا لا يخفىولماذا حرّم الله علينا + +280 +00:31:33,480 --> 00:31:39,080 +لحمة الخنزير كنا نقول و نحن صغار لأن فيه الدودة + +281 +00:31:39,080 --> 00:31:44,180 +الشريطية فثبتت أنها في البقر لأن الله حرّم علينا + +282 +00:31:44,180 --> 00:31:49,080 +لحمة الخنزير إنما حرّم عليكم الميتة والدم و لحمة + +283 +00:31:49,080 --> 00:31:54,360 +الخنزير وما أهل لغير الله به وحال المؤمنين سمعنا + +284 +00:31:54,360 --> 00:31:59,460 +وأطعنا أفرانك ربنا وإليك المصير وإن غابت عننا + +285 +00:31:59,460 --> 00:32:08,090 +الإلهوإن غابت عنّا الحكمة ويمكن الاستدلال على ذلك + +286 +00:32:08,090 --> 00:32:13,930 +بخصة عمر رضي الله عنه لما كان يطوف يوما حول الكعبة + +287 +00:32:13,930 --> 00:32:19,770 +المشرفة زادها الله تشريفا ولمّا وصل إلى الحجر + +288 +00:32:19,770 --> 00:32:30,820 +الأسود الأسعد ان شاء الله قبله وقال هكذارأيت رسول + +289 +00:32:30,820 --> 00:32:38,360 +الله صلى الله عليه وسلم يقبلك إنك حجر لا تنفع ولا + +290 +00:32:38,360 --> 00:32:45,360 +تضرر ولولا أني رأيت رسول الله يقبلك ما قبلتك هذا + +291 +00:32:45,360 --> 00:32:54,020 +هو الإيمان الخالص بأحكام الله وبشرع الله ولذلك نحن + +292 +00:32:54,020 --> 00:33:00,240 +عندما نطوف حول الكعبة لا نطوف حول حجارةوعندما نقبل + +293 +00:33:00,240 --> 00:33:05,220 +الحجر الأسود لا نقبل حجراً إنما نمتثل أمر الله + +294 +00:33:05,220 --> 00:33:11,020 +لأنه من شعائر الله ومن يعظم شعائر الله فإنها من + +295 +00:33:11,020 --> 00:33:18,940 +تقوى القلوب نعم رأيتم في مناسك الحجر في منا نرجم + +296 +00:33:18,940 --> 00:33:27,230 +حجراً وما هذه الاستوانة التي نرجمها بالحجارةأول + +297 +00:33:27,230 --> 00:33:32,950 +يوم من أيام العيد سبعا وفي اليوم الثاني احدا + +298 +00:33:32,950 --> 00:33:37,310 +وعشرين حصاتا وفي اليوم الثالث كذلك تسعة واربعون + +299 +00:33:37,310 --> 00:33:43,390 +حصاتا ومن تخلف فسبعون حصاتا انما نرجم حجرا بحجر + +300 +00:33:43,390 --> 00:33:50,030 +ايضا هذا امتثال لامر الله لأن أعداء الإسلام قالوا + +301 +00:33:50,030 --> 00:33:56,010 +كيفترجمون الحجر وتقبلون الحجر وتطفون حول الحجر + +302 +00:33:56,010 --> 00:34:02,390 +بينما حرّم الإسلام عبادة الحجر كالأوثان والأصنام + +303 +00:34:02,390 --> 00:34:07,410 +كانت مصنوعة من الحجارة نقول لهم ما نفعله نحن + +304 +00:34:07,410 --> 00:34:14,170 +المسلمين إنما هو امتثال لأمر اللهوما يعظم شعائر + +305 +00:34:14,170 --> 00:34:23,450 +الله فإنها من تقوى القلوب لا مانع أن نستشهد بشعر + +306 +00:34:23,450 --> 00:34:31,930 +إمرئ القهز عندما كان يمر على ديار ليلة ويقبل + +307 +00:34:31,930 --> 00:34:41,120 +الحجارة التي مستها ليلة هل هويمر عليها من أجل + +308 +00:34:41,120 --> 00:34:47,440 +الحجارة أم من أجل أن يشم رائحة ليلة و لذلك قال أمر + +309 +00:34:47,440 --> 00:34:53,340 +.. أمر على ديار ديار ليلة أقبل ذا الجدار و ذا + +310 +00:34:53,340 --> 00:34:58,750 +الجدارةوما حب الديار شغفنا قلبي ولكن حب من سكن + +311 +00:34:58,750 --> 00:35:05,210 +الديارة ولله المثل الأعلى سبحانه وتعالى نعم إذا + +312 +00:35:05,210 --> 00:35:11,370 +هنا نقول في البند الأول أو الخصية الأولى من خصائص + +313 +00:35:11,370 --> 00:35:16,350 +العبادة في الإسلام أن العبادة لا تكون إلا لله + +314 +00:35:16,350 --> 00:35:22,870 +واحدة نقية من الشرك بنوعيه الشرك الأكبر والشرك + +315 +00:35:22,870 --> 00:35:27,680 +الأصغركما قال الله تبارك وتعالى فمن كان يرجو لقاء + +316 +00:35:27,680 --> 00:35:33,940 +ربه فليعمل عملا صالحا ولا يشرك بعبادة ربه أحدا + +317 +00:35:33,940 --> 00:35:39,140 +وكلنا يترتب على ذلك أن العبادة في الإسلام توقفية + +318 +00:35:39,140 --> 00:35:47,170 +نعم ومعنى توقفيةأنها ليست اجتهادية من الرسول عليه + +319 +00:35:47,170 --> 00:35:50,950 +الصلاة والسلام بل من عند الله كما يقال إن صور + +320 +00:35:50,950 --> 00:35:56,130 +القرآن توقفية هذه صورة البقرة وهذه صورة الامران + +321 +00:35:56,130 --> 00:36:04,210 +وهذه صورة النساءالمائدة و هكذا الأعراف و الأنعام و + +322 +00:36:04,210 --> 00:36:09,630 +الأنفال إلى غير ذلك من الصور فهي توقيفية من عند + +323 +00:36:09,630 --> 00:36:16,270 +الله و ليست اجتهادا من عند رسول الله ﷺ و كذلك هنا + +324 +00:36:16,270 --> 00:36:21,210 +نقول إن العبادة توقيفية أي أنها من عند الله و فعل + +325 +00:36:21,210 --> 00:36:26,890 +رسول الله الذي لا ينطق عن الهوى ﷺ و معنى أنها + +326 +00:36:26,890 --> 00:36:35,600 +توقيفية أولاأنه لا زيادة فيها ولا نقصان ولا تعديل + +327 +00:36:35,600 --> 00:36:42,920 +فيها ولا تبديل ثانيا أنها لا تعلل بعلة فلا يقلق + +328 +00:36:42,920 --> 00:36:48,940 +الصلاة من أجل الرياضة وإلا من يلعبالرياضة و يجري + +329 +00:36:48,940 --> 00:36:54,960 +ورا الطابة فهو اللي يصلي، لا ولا نقول أن الوضوء من + +330 +00:36:54,960 --> 00:36:59,940 +أجل النظافة لأن غيرنا من أعداء الإسلام قد يغتسلون + +331 +00:36:59,940 --> 00:37:05,530 +أكثر مننانعم بالسبب روايحهم الخبيثة التي تنجم عن + +332 +00:37:05,530 --> 00:37:10,250 +الأطعم الحرام و عن شرب الخمر و عن العرق المنتن و + +333 +00:37:10,250 --> 00:37:17,890 +كذلك العبادات الأخرى لماذا نغتفل من الجنابة هذا + +334 +00:37:17,890 --> 00:37:24,420 +السؤالكثيرا ما نسأله لماذا نغتسل من الجنابة؟ لماذا + +335 +00:37:24,420 --> 00:37:30,140 +لا نقتفر على غسل الأعضاء التناسلية فقط؟ فنقول هذا + +336 +00:37:30,140 --> 00:37:38,420 +أيضا شرع الله وامتثال لأمر الله نغتسل استجابة لله + +337 +00:37:38,420 --> 00:37:43,140 +وإن غابت عننا الحكمة أو غابت عننا الأله وإن كنتم + +338 +00:37:43,140 --> 00:37:48,740 +جنوبا فاتحروا هكذا قال الله فأهلا وسهلا ومرحبا + +339 +00:37:49,040 --> 00:37:54,720 +بكلام الله و شرع الله سبحانه وتعالى أما الميزة + +340 +00:37:54,720 --> 00:38:00,400 +الثانية أو الخاصية الثانية من خاصية العبادة أنه لا + +341 +00:38:00,400 --> 00:38:06,520 +وساطة فيها بين الله تعالى و بين عباده لأن هذه + +342 +00:38:06,520 --> 00:38:14,890 +العبادة صلة بين العبد و ربه ولا تحتاج إلى وساطةكما + +343 +00:38:14,890 --> 00:38:20,890 +هو الحال اليوم عند اليهود و عند النصارى يتوجهون + +344 +00:38:20,890 --> 00:38:27,010 +إلى الحاخمات أو إلى القصص أو إلى الرهبان و يعترفون + +345 +00:38:27,010 --> 00:38:33,590 +بذنبهم و يدفعون الدولارات و الآلاف من أجل أن + +346 +00:38:33,590 --> 00:38:40,870 +يغفروا لهم و من أجل أن يدخلوهم الجنة فالإسلام لا + +347 +00:38:40,870 --> 00:38:48,710 +يعترف بهذه الصقوقثقوق حرمان وثقوق وفران لأن + +348 +00:38:48,710 --> 00:38:54,670 +العلاقة بين العبد وربه قالوا يا رسول الله أقريب + +349 +00:38:54,670 --> 00:39:01,770 +ربنا فنناديه أم بعيد فنناديه فكان جبريل عليه + +350 +00:39:01,770 --> 00:39:07,420 +السلام أسرع بالجوابفنزل قوله تعالى في صورة البقرة + +351 +00:39:07,420 --> 00:39:15,880 +عقب آيات الصيام وإذا سألك عبادي عني فإني قريب فإني + +352 +00:39:15,880 --> 00:39:22,580 +قريب والفاء هنا حرف عطف كما نعلم يفيد الترتيب + +353 +00:39:22,580 --> 00:39:30,780 +والتعقيد لا وساطة فعلا بين العبد وربه إذا أصبت + +354 +00:39:30,780 --> 00:39:41,550 +خطيئةأو فحشة أو معصية أو تلبست بذنب أو حرام فليس + +355 +00:39:41,550 --> 00:39:48,350 +لك أن تذهب إلى شيخ من أجل أن تعترف بين يديه حتى + +356 +00:39:48,350 --> 00:39:53,730 +يغفر لك أو يدعو لك بالمغفرة والرحمة والرضوان لا + +357 +00:39:53,730 --> 00:40:01,220 +توجه إلى الله وادعو اللهوارفع أكفة ضراعة إلى الله + +358 +00:40:01,220 --> 00:40:07,460 +واذرف الدموع ساخنة على الوجنات قائلا يا رب فإنه + +359 +00:40:07,460 --> 00:40:13,640 +يجيبك على الفور لبيك عبدي لبيك منزل الذي وقف على + +360 +00:40:13,640 --> 00:40:19,280 +بابي واطرته وكيف أطرد أحبابي فالتائب حبيب الرحمن + +361 +00:40:19,280 --> 00:40:26,670 +والتائب من الذنب كمن لا ذنب لهوإذا سألك عبادي عني + +362 +00:40:26,670 --> 00:40:32,710 +فإني قريب حتى إن هذه الآية تختلف عن مثيلاتها من + +363 +00:40:32,710 --> 00:40:42,090 +الآيات الأخرى لأنها قد جاعت بصيغة قل كما في حوالي + +364 +00:40:42,090 --> 00:40:47,230 +أربعة عشر موضعا في القرآن الكريم مثل قول ويسألونك + +365 +00:40:47,230 --> 00:40:54,710 +عن المحيط قل هو أذن قل يا محمد لأنمحمد هو المبلغ + +366 +00:40:54,710 --> 00:41:01,890 +عن الله سبحانه وتعالى ويسألون كماذا ينفقون قل + +367 +00:41:01,890 --> 00:41:10,340 +العفوو يسألونك عن الأنفال قل الأنفال لله و الرسول + +368 +00:41:10,340 --> 00:41:16,520 +و يسألونك عن الأهلة قل هي مواقيته للناس و الحجة + +369 +00:41:16,520 --> 00:41:21,100 +إيه لأ غير ذلك من المواضع أما هنا فجاءت الآية و + +370 +00:41:21,100 --> 00:41:26,200 +إذا سألك عبادي عني لم يقول فقول إنه خير لأن النبي + +371 +00:41:26,200 --> 00:41:32,180 +عليه السلام سيموت إنك ميتوإن هم ميتون قالها أبو + +372 +00:41:32,180 --> 00:41:36,160 +بكر الصديق رضي الله عنه أيها الناس من كان يعبد + +373 +00:41:36,160 --> 00:41:42,980 +محمدا فإن محمدا قد مات ومن كان يعبد الله فإن الله + +374 +00:41:42,980 --> 00:41:52,390 +حي لا يموت نعم وإذا سألك عبادي عني فإني قريبأجيب + +375 +00:41:52,390 --> 00:41:57,290 +دعوة الداعي ذا دعان فليستجيبوا ليه وليؤمنوا بيه + +376 +00:41:57,290 --> 00:42:03,570 +لعلهم يرشدوا سبحانه وتعالى أقربوا إلينا من دقات + +377 +00:42:03,570 --> 00:42:09,450 +قلوبنا وأقربوا إلينا مما يختر في نفوسنا بل أقربوا + +378 +00:42:09,450 --> 00:42:14,430 +إلينا من حبل الوريد كما قال ربنا وقال ربكم دعوني + +379 +00:42:14,430 --> 00:42:20,140 +أستجيب لكمإن الذين يستكبرون عن عبادتي سيدخلون جهنم + +380 +00:42:20,140 --> 00:42:25,800 +داخرين أرأيتم سم الدعاء عبادة إن الذين يستكبرون عن + +381 +00:42:25,800 --> 00:42:30,640 +عبادته ولم يقول عن دعائه بل جاء في الحديث إن + +382 +00:42:30,640 --> 00:42:38,640 +الدعاء هو العبادة بل هو مخ العبادة نعم فما أحوجنا + +383 +00:42:39,460 --> 00:42:46,280 +إلى الله الذي يغفر الزنب ويقبل التوب ويعفو عن كثير + +384 +00:42:46,280 --> 00:42:52,260 +كيف لا وقد جاء في الأثر أنه سبحانه وتعالى ينزل كل + +385 +00:42:52,260 --> 00:42:59,860 +ليلة في الثورة الأخيرة من الليل ينزل طبعا دون + +386 +00:42:59,860 --> 00:43:08,220 +تأويلودون تعطيل ودون تشبيه هذه هي عقيدتنا نحن أهل + +387 +00:43:08,220 --> 00:43:14,420 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النار وفي الحديث + +399 +00:44:29,730 --> 00:44:34,050 +الآخر عن السيدة عائشة رضي الله عنها من أحدث في + +400 +00:44:34,050 --> 00:44:40,370 +أمرنا ما ليس فيه فهو رد والحديث عند مسلم ذكر + +401 +00:44:40,370 --> 00:44:47,450 +النووي في شرح مسلم فهو رد أي مردود على صحبهلأن كل + +402 +00:44:47,450 --> 00:44:53,630 +هذه زيادات من البدع وكل بدعة ضلالة وكل ضلالة في + +403 +00:44:53,630 --> 00:44:59,370 +النار فانتبهوا هنا إلى مصطلح البدعة لأن البدعة كل + +404 +00:44:59,370 --> 00:45:04,170 +ما لم يكن عليه الرسول عليه الصلاة والسلام والخلفاء + +405 +00:45:04,170 --> 00:45:10,850 +والراشدون فهوبدعا من أجل أن تكون العبادة سليمة + +406 +00:45:10,850 --> 00:45:15,490 +وصحيحة لابد أن نكون على طريق رسول الله عليه الصلاة + +407 +00:45:15,490 --> 00:45:19,830 +والسلام قال الله تبارك وتعالى قل إن كنتم تحبون + +408 +00:45:19,830 --> 00:45:25,090 +الله فاتبعوني يحببكم الله ويغفر لكم ذنوبكم والله + +409 +00:45:25,090 --> 00:45:30,210 +غفور ورحيم فالدين كامل لا يقبل الزيادة أو النقصان + +410 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قصر الصلاة في الصفر ومثل الجمع في + +422 +00:46:33,840 --> 00:46:38,540 +حال الخوف وفي حال الصفر وفي حال المرض وكذلك + +423 +00:46:38,540 --> 00:46:42,320 +استعمال الطراب في الطهارة بدل وضوء فلم تجدوا ماء + +424 +00:46:42,320 --> 00:46:47,720 +فتيمموا صعيدا طيبة وهكذا الإسلام والحمد لله كله + +425 +00:46:47,720 --> 00:46:54,490 +يسر وسماحة وقد مر بنا حديثالراحة الثلاثة فماذا قال + +426 +00:46:54,490 --> 00:46:58,530 +لهم عليه الصلاة والسلام إني أتقاكم لله و أخشاكم له + +427 +00:46:58,530 --> 00:47:03,910 +ولكن أصوم و أفطر و أصلي و أرقد و أتسوج النساء فمن + +428 +00:47:03,910 --> 00:47:10,160 +رغب عن سنتي فليس مني عليه الصلاة والسلامأما خامسا + +429 +00:47:10,160 --> 00:47:17,120 +وأخيرا فمن أعظم خصائص العبادة في الإسلام النية + +430 +00:47:17,120 --> 00:47:23,400 +والإخلاص فذلك أساس قبول العبادة ولعلنا تكلمنا عن + +431 +00:47:23,400 --> 00:47:27,330 +الشرك الأكبر وعن الشرك الأصغر اللي هو هوالرياء + +432 +00:47:27,330 --> 00:47:33,290 +وتكلمنا حتى عن الذبيحة إذا لم تذبح باسم الله فهي + 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الثالث وهو + +456 +00:49:34,790 --> 00:49:38,430 +بعنوان نظام الأخلاق في الإسلام وصلى اللهم على + +457 +00:49:38,430 --> 00:49:43,270 +سيدنا محمد والسلام عليكم ورحمة الله وبركاته + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/3RRw81jW3SM.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/3RRw81jW3SM.srt new file mode 100644 index 0000000000000000000000000000000000000000..10210cea4db76da559121eeca029a5fc25ea0638 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/3RRw81jW3SM.srt @@ -0,0 +1,2383 @@ +1 +00:00:05,450 --> 00:00:07,790 +أعوذ بالله السميع العلي من الشياطين الرجيم باسم + +2 +00:00:07,790 --> 00:00:11,250 +الله الرحمن الرحيم الحمد لله والصلاة والسلام على + +3 +00:00:11,250 --> 00:00:15,210 +رسول الله دائما وأبدا نعقد مجالسنا بالصلاة على + +4 +00:00:15,210 --> 00:00:19,210 +الحبيب محمد صلى الله عليه وسلم أعزائي الطلاب قبل + +5 +00:00:19,210 --> 00:00:24,470 +ذِكْرِ بدء أرحبكم جميعا في بداية محاضرة جديدة وأحييكم + +6 +00:00:24,470 --> 00:00:28,570 +بتحية الإسلام العظيم فالسلام الله عليكم ورحمته + +7 +00:00:28,570 --> 00:00:33,870 +وبركاته نحن اليوم على موعد مع المبحث الرابع من + +8 +00:00:33,870 --> 00:00:41,030 +الفصل الرابع وهو بعنوان الطلاق وسوف نفتح هذا + +9 +00:00:41,030 --> 00:00:47,890 +المبحث بالخطوات الوقائية للحد من الطلاق أبغض + +10 +00:00:47,890 --> 00:00:55,930 +الحلال إلى الله الطلاق فالطلاق مباح وقد يكون حلا + +11 +00:00:56,930 --> 00:01:05,190 +لمشكلة اجتماعية يعاني منها الزوجان وبعد الطلاق + +12 +00:01:05,190 --> 00:01:12,310 +يُرزق كل منهما كما قال الله تبارك وتعالى وإن يتفرقا + +13 +00:01:12,310 --> 00:01:19,650 +يُغن الله كلًا من سعْده ولكن الطلاق ليس هو الحل + +14 +00:01:19,650 --> 00:01:29,310 +الأول وإنما آخر الدواء كما يقولون من أجل ذلك شرع الإسلام + +15 +00:01:29,310 --> 00:01:37,810 +الخطوات الوقائية للحد من الطلاق وأول هذه الخطوات + +16 +00:01:37,810 --> 00:01:45,470 +أن يحصن كل من الزوجين اختيار صاحبه وهذا الاختيار + +17 +00:01:45,470 --> 00:01:54,450 +لا يكون بسبب المال أو بسبب الجمال أو بسبب الحسب + +18 +00:01:54,450 --> 00:02:02,150 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أربع + +30 +00:03:18,970 --> 00:03:26,510 +أو اثنتين أو جميعها وقال ما تجتمع لمالها لأنها + +31 +00:03:26,510 --> 00:03:33,830 +غنية أو جمالها لأنها حسناء وضيئة أو حسبها ونسبها + +32 +00:03:33,830 --> 00:03:40,890 +لأنها من قبيلة وعشيرة أو لدينها ثم يوصي الرسول صلى + +33 +00:03:40,890 --> 00:03:46,420 +الله عليه وسلم الخاطب وما يرغب في الزوجة قائلا + +34 +00:03:46,420 --> 00:03:54,860 +فاضفر بذات الدين تربت يداك ومعنى الحديث إن لم تظفر + +35 +00:03:54,860 --> 00:04:02,500 +بذات الدين تربت يداك وتربت يداك يقال في لغة العرب + +36 +00:04:02,500 --> 00:04:12,740 +ويُقْنَع به عن الفقر والعوز والحاجة لأنها دعوة من + +37 +00:04:12,740 --> 00:04:20,520 +الرسول عليه وليست بدعا كما يظن البعض كما قال الله + +38 +00:04:20,520 --> 00:04:28,220 +سبحانه وتعالى أو مسكينا ذاب الطرابة من المسكنة + +39 +00:04:28,220 --> 00:04:37,880 +التسقى بالتراب ومنه قولهم فِكْرٌ مُدْكَعٌ من الدُّقَّاءِ وهي + +40 +00:04:37,880 --> 00:04:45,450 +الأرض ويقول عليه الصلاة والسلام الدنيا متاع وخير + +41 +00:04:45,450 --> 00:04:51,290 +متاعها المرأة الصالحة ما صفاتها يا رسول الله قال + +42 +00:04:51,290 --> 00:04:59,390 +أربع إن نظر إليها سَرَّتْهُ وإن أمرها أطاعته وإن أقسم + +43 +00:04:59,390 --> 00:05:08,290 +عليها أبرَّتْهُ وإن غاب عنها حفظته في ماله وفي أرضه + +44 +00:05:08,290 --> 00:05:13,190 +صلى الله عليه وسلم و محمد صلى الله عليه وسلم إذًا الخطوة + +45 +00:05:13,190 --> 00:05:19,970 +الأولى من خطوات إيقاع الطلاق أو الحد من إيقاع + +46 +00:05:19,970 --> 00:05:27,990 +الطلاق هو أن يحصن كل من الزوجين اختيار صاحبه لأنها + +47 +00:05:27,990 --> 00:05:36,130 +ليست أيامًا أو شهورًا بل هو زواج إلى الأبد وعشرة عمر + +48 +00:05:36,130 --> 00:05:45,390 +ثانيًا دع الإسلام الزوجين أن يشعر كل منهم بمسؤوليته + +49 +00:05:45,390 --> 00:05:54,530 +تجاه الآخر وقد مر بنا عندما تكلمنا في المباحث + +50 +00:05:54,530 --> 00:06:01,550 +السابقة عن حقوق الزوجين فقد تكلمنا عن حقوق الزوج + +51 +00:06:01,550 --> 00:06:08,990 +الرابعة عفوا الخامسة وتكلمنا عن حقوق الزوجة + +52 +00:06:08,990 --> 00:06:14,510 +الرابعة وعن الحقوق المشتركة بين الزوجين وهي أيضًا + +53 +00:06:14,510 --> 00:06:22,070 +أربعة فإذا ما عرف كل من الزوجين ما له وما عليه لم + +54 +00:06:22,070 --> 00:06:29,250 +يعد ثمّ تخالف أو شقاق أو نزاع وقد قال صلى الله عليه + +55 +00:06:29,250 --> 00:06:38,090 +وسلم كلكم راع وكلكم مسئول عن رعيته والرجل راع + +56 +00:06:38,090 --> 00:06:44,430 +في أهله وهو مسئول عن رعيته والمرأة راعية في بيت + +57 +00:06:44,430 --> 00:06:51,680 +زوجها وهي مسئولة عن رعيتها فكلكم راع وكلكم مسئول + +58 +00:06:51,680 --> 00:06:59,520 +عن رعيتِه وهذا أيضًا من الخطوات المهمة في الحد من + +59 +00:06:59,520 --> 00:07:05,940 +وقوع الطلاق ثالثًا من الخطوات الوقائية للحد من وقوع + +60 +00:07:05,940 --> 00:07:12,380 +الطلاق إذا ما ظهرت بادرة خلاف بين الزوجين على + +61 +00:07:12,380 --> 00:07:21,950 +الزوج ألا يتعجّل بإيقاع الطلاق لأنه سيندم في ساعة + +62 +00:07:21,950 --> 00:07:31,030 +غضب أو ثورة بل عليه أن يتروّى وأن يتأنّى وأن يصبر + +63 +00:07:31,030 --> 00:07:37,250 +على أذى زوجته كما مر بنا في حديث رسول الله صلى الله + +64 +00:07:37,250 --> 00:07:44,350 +عليه وسلم لا يفرق بمعنى لا يكره مؤمن مؤمنة إن كره + +65 +00:07:44,350 --> 00:07:50,910 +منها خلقا راضيا غيرها وفي هذا يقول الله تبارك وتعالى + +66 +00:07:50,910 --> 00:07:58,090 +وعاشروهن بالمعروف فإن كرهتموهن أي لا تتعجلوا + +67 +00:07:58,090 --> 00:08:03,730 +بالطلاق فعسى أن تكرهوا شيئا ويجعل الله فيه خيرا + +68 +00:08:03,730 --> 00:08:10,170 +كثيرًا قال علماء التفسير وأهل العلم الخير الكثير أن + +69 +00:08:10,170 --> 00:08:19,330 +يُرزق منها بولد صالح رابعا إذا استمر الخلاف بين + +70 +00:08:19,330 --> 00:08:29,230 +الزوجين وكانت الزوجة هي المشاكسة المعاكسة فللزوج + +71 +00:08:29,230 --> 00:08:35,970 +تأديبها وقد مر بنا من حقوق الزوج الخامسة تأديب + +72 +00:08:35,970 --> 00:08:42,970 +الزوجة المشاكسة ونعيد باختصار ما سبق ذكره هناك أنه + +73 +00:08:42,970 --> 00:08:50,090 +أولا ليس كل امرأة تُؤَدَّبُ إنما المرأة التي تُؤَدَّبُ هي + +74 +00:08:50,090 --> 00:08:56,750 +المرأة الناشزة والناشزة هي التي تترفع على زوجها + +75 +00:08:56,750 --> 00:09:03,850 +ولا تطيع زوجها بطاعة الله تبارك وتعالى لأن الطاعة + +76 +00:09:03,850 --> 00:09:09,810 +هنا مقيدة بطاعة الله فإذا أمر الزوج زوجته بمعصية + +77 +00:09:09,810 --> 00:09:16,290 +الله كأن لا تصلي مثلا أو أن تفطر في شهر رمضان أو أن + +78 +00:09:16,290 --> 00:09:21,990 +تخرج إلى الشارع سافرة متبرجة فليس له عليها من طاعة + +79 +00:09:21,990 --> 00:09:27,150 +لأن الطاعة في الخير ولأن الطاعة في المعروف ولا + +80 +00:09:27,150 --> 00:09:36,390 +طاعة لمخلوق في معصية الخالق ثانيًا لابد أن يكون + +81 +00:09:36,390 --> 00:09:43,880 +التأديب مرتبا بدءا بالموعظة ومرورا بِهَجْرِها في + +82 +00:09:43,880 --> 00:09:50,880 +المضجع وانتهاء بالضرب غير المبرح كما قال الله + +83 +00:09:50,880 --> 00:09:58,280 +تبارك وتعالى والتي تخافون نشوزهن فاعظوهن واهجروهن + +84 +00:09:58,280 --> 00:10:04,740 +في المضاجع واضربونهن فيبدأ بالموعظة بالكلمة الطيبة + +85 +00:10:04,740 --> 00:10:14,130 +وبالتي هي أحسن ويذكرها بمآلات أفعالها وأنه قد يفرق + +86 +00:10:14,130 --> 00:10:24,050 +بينها وبين زوجها وبين ولدها وهذا عواقبه وخيمة + +87 +00:10:24,050 --> 00:10:33,810 +لا تصر أبدا لعلها ترتدع وتنزجر وتعود إلى الجادة + +88 +00:10:33,810 --> 00:10:43,860 +والطريق القويم وإلى طاعة زوجها فإن لم تلتزم ينطلق + +89 +00:10:43,860 --> 00:10:50,200 +إلى المرحلة الثانية وهي الهجران في المضجع والهجران + +90 +00:10:50,200 --> 00:10:56,160 +في المضجع كما سبق أن قلنا في حقوق الزوج هو أن + +91 +00:10:56,160 --> 00:11:05,610 +يُهْجَرُها في سريرها في مخدعها بأن لا يُجامِعها فقط إذًا + +92 +00:11:05,610 --> 00:11:14,410 +الهجران هنا بمعنى عدم الجماع في غرفة نومها لكن لا + +93 +00:11:14,410 --> 00:11:21,370 +يكون الهجر في الصالون مثلا أو في ديوان العائلة أو + +94 +00:11:21,370 --> 00:11:27,550 +عند أحد الجيران أو الأصدقاء فهذا كله لا يجوز شرعًا + +95 +00:11:27,550 --> 00:11:33,250 +إنما الهجران في مخدعها في مبيتِها ومكان نومها بأن + +96 +00:11:33,250 --> 00:11:42,670 +يُدير لها ظهره فقط ولكن يؤكلها ويشربها ويكلمها و + +97 +00:11:42,670 --> 00:11:51,620 +يُحادِثُها لعلهَا تعود فإن لم تعود كانت ضربه + +98 +00:11:51,620 --> 00:11:57,160 +والضرب هنا ليس كما يقول أعداء الإسلام إنما هو + +99 +00:11:57,160 --> 00:12:04,880 +الضرب الخفيف الضرب غير المبرح كما قال ابن عباس + +100 +00:12:04,880 --> 00:12:11,910 +رضي الله عنهما أن يضرب بالسواك السواك الذي يستعمل + +101 +00:12:11,910 --> 00:12:18,430 +في نظافة الأسنان مثل قلم الرصاص لا يؤذي أبدًا + +102 +00:12:18,430 --> 00:12:24,030 +ولذلك اشترط العلماء شروطًا في هذا الضرب أولا أن + +103 +00:12:24,030 --> 00:12:32,590 +لا يُكْسِرُ عظمًا وثانيًا أن لا يخدش جلدًا وثالثًا أن + +104 +00:12:32,590 --> 00:12:38,330 +لا يترك أثرًا أو علامة أو ما يُسمّى اليوم بالكدمات + +105 +00:12:39,880 --> 00:12:46,380 +زرقاء أو سوداد حول الجلد لأن هذا قد يضرها وقد + +106 +00:12:46,380 --> 00:12:53,180 +يؤثر فيها فإذا ما حصل طلاق قد يؤخر طلاقها وألا + +107 +00:12:53,180 --> 00:12:59,480 +يُمسّ الوجه نعم هكذا قال الرسول عليه الصلاة والسلام + +108 +00:12:59,480 --> 00:13:07,210 +ألا يكون التأديب في الوجه لماذا الوجه؟ لأن الوجه + +109 +00:13:07,210 --> 00:13:12,570 +هو جماع محاسن المرأة كل محاسن المرأة في وجهها + +110 +00:13:12,570 --> 00:13:17,950 +ولذلك شرع الإسلام للخاطب أن ينظر إلى مقتوبته إلى + +111 +00:13:17,950 --> 00:13:22,690 +وجهها وكفيها كما قال عليه تصادف أحد الأنصار انظر + +112 +00:13:22,690 --> 00:13:29,350 +إليها فإنه أحرى أن يُؤْدَمَ بينكما بمعنى أن يكون + +113 +00:13:29,350 --> 00:13:38,540 +بينكما أُلفة يعني ألفة ومحبة وألا يشتم وألا يثب + +114 +00:13:38,540 --> 00:13:48,420 +وألا يقبح فما ذنب الأبوين في هذه الحالة نعم ولذلك + +115 +00:13:48,420 --> 00:13:54,160 +قال أهل العلم وعلى رأسهم الشيخ العالم محمد رشيد رضا + +116 +00:13:54,160 --> 00:14:01,020 +في تفسيره الاجتماعي الذي سمي بتفسير المنار بأن + +117 +00:14:01,020 --> 00:14:08,820 +الرجل الكامل لا يضرب امرأته قط لأن ضرب النساء حقيقة + +118 +00:14:08,820 --> 00:14:15,400 +لا يليق بأخلاق الرجال الكامل ولذلك وهذه الآيات قد + +119 +00:14:15,400 --> 00:14:20,920 +نزلت على رسول الله صلى الله عليه وسلم إلا أنه لم + +120 +00:14:20,920 --> 00:14:28,370 +يضرب امرأة قط وإنما كان يضرب بيده مجاهدا في سبيل + +121 +00:14:28,370 --> 00:14:37,010 +الله عز وجل نعم هكذا هم الرجال كما ورد عن شريح بن + +122 +00:14:37,010 --> 00:14:43,270 +هانيء وهو قاض المسلمين في عهد الخلفاء الراشدين + +123 +00:14:43,270 --> 00:14:50,370 +عندما كانت تأتيه المرأة تشكو ضرب زوجها وكانت له + +124 +00:14:50,370 --> 00:14:56,590 +زوجة اسمها زينب فكان يقول رأيت رجالا يضربون نساءهم + +125 +00:14:56,590 --> 00:15:02,690 +فشلًا يميني يوم أضربُ زينبًا نعم هذه هي الخطوات + +126 +00:15:02,690 --> 00:15:09,630 +الثلاثة في تأديب الزوجة فإذا لم ترتدع الزوجة + +127 +00:15:09,630 --> 00:15:17,470 +بالموعظة والهجران والضرب غير المبرح هنا لابد من + +128 +00:15:17,470 --> 00:15:24,730 +إرسال الحكمين حكما من أهله أهل الزوج وهو مختار + +129 +00:15:24,730 --> 00:15:31,590 +العائلة مثلا وحكما من أهلها مختار العائلة ويشترط + +130 +00:15:31,590 --> 00:15:40,570 +في هذين الحكمين أن يكون صالحينه وإن خفتم شقاق + +131 +00:15:40,570 --> 00:15:48,870 +بينهما فابعثوا حكما من أهله وحكما من أهلها الذي + +132 +00:15:48,870 --> 00:15:57,920 +يريد إصلاحا يوفق الله بينهما سبحانه وتعالى وهنا + +133 +00:15:57,920 --> 00:16:05,700 +اختلف علماء التفسير إي يريد إصلاحا إي يريد الصلح + +134 +00:16:05,700 --> 00:16:11,520 +هنا يعود إلى الحكمين أم يعود إلى الزوجين بعضهم قال + +135 +00:16:11,520 --> 00:16:18,300 +إي يريد أي الحكمان وهذا مقبول وبعضهم قال إي يريدان + +136 +00:16:18,300 --> 00:16:23,260 +أي الزوجان الزوج والزوجة وهذا أيضًا مقبول إذا + +137 +00:16:23,260 --> 00:16:30,700 +الآية تحتمل المعنيين إي يريدان إصلاحا يوفق الله + +138 +00:16:30,700 --> 00:16:37,460 +بينهما إن الله كان عليما خبيرا سبحانه وتعالى سادسًا + +139 +00:16:37,460 --> 00:16:45,680 +إذا فشلت كل الخطوات الخمسة السابقة هنا لابد من + +140 +00:16:45,680 --> 00:16:52,840 +وقوع الطلاق وهو كما قال عليه الصلاة والسلام أنه + +141 +00:16:52,840 --> 00:17:00,900 +أخف الضررين وأهون الشرين وأبغض الحلال إلى الله + +142 +00:17:00,900 --> 00:17:08,900 +الطلاق ولكن لابدّ منهُم لعلّ أحدهم يرزق بخير من الآخر + +143 +00:17:08,900 --> 00:17:13,990 +ولكن عندما نتكلم عن الطلاق لا نتكلم عن الطلاق + +144 +00:17:13,990 --> 00:17:20,750 +البدعي كأن مثلا يطلقها في حيض أو في نفاس أو أن + +145 +00:17:20,750 --> 00:17:28,470 +يطلقها سلسًا وإن كان الطلاق في كل ذلك يقع فالطلاق + +146 +00:17:28,470 --> 00:17:35,290 +البدعي يقع وإن خالف السنة والفرق بين الطلاق الصني + +147 +00:17:35,290 --> 00:17:43,070 +والطلاق البدعي أن الطلاق الصني يقع بلا إثم أما + +148 +00:17:43,070 --> 00:17:49,770 +الطلاق البدعي فيقع مع الإثم لأنه على خلاف السنة + +149 +00:17:49,770 --> 00:17:56,590 +فما هو الطلاق الصني كما سماه جمهور العلماء أو أحسن + +150 +00:17:56,590 --> 00:18:02,310 +الطلاق كما سماه الحنفية أن يطلق الرجل المرأة في + +151 +00:18:02,310 --> 00:18:13,240 +طهر لم يمسها فيه يعني لم يجامعها فيه لماذا؟ لأنه لو + +152 +00:18:13,240 --> 00:18:20,340 +جامعها ثم بعد ذلك طلقها قد تحمل وإذا ما حملت في + +153 +00:18:20,340 --> 00:18:29,840 +هذه الحال فإنه يطول زواجها لأن عدة الحامل الوضع + +154 +00:18:29,840 --> 00:18:37,780 +كما قال الله تبارك وتعالى: "وأولات الأحمال أجلهن أن" + +155 +00:18:37,780 --> 00:18:46,130 +يضعن حملهنّ لكن إذا طلقها بعد طهرها من حيض أو نفاس + +156 +00:18:46,130 --> 00:18:52,310 +دون جماع فإنها تتزوج بعد ثلاثة أشهر أو بعد تسعين + +157 +00:18:52,310 --> 00:19:04,250 +يومًا فإذا طلقها في حيض أيضًا أضرّ بها لأن عدة المرأة + +158 +00:19:04,250 --> 00:19:12,500 +لا تحسبوا من الحيض إنما تحسبوا من الطهر يا أيها + +159 +00:19:12,500 --> 00:19:19,060 +النبي "إذا طلقتم النساء فطلقوهن لعدتهنّ" ما معنى قوله + +160 +00:19:19,060 --> 00:19:29,120 +تعالى "فطلقوهن لعدتهنّ" أي في بداية طهرهن أو مستقبلات + +161 +00:19:29,120 --> 00:19:39,100 +عدة هنّ ومتى تستقبل المرأة عدةها بعد طهرها فإذا + +162 +00:19:39,100 --> 00:19:45,640 +طلقها في حيض لم تُحسب مدة الحيض التي أقلها يوم + +163 +00:19:45,640 --> 00:19:55,220 +وليلة وغالبها ست أو سبع وأكثرها عشرة أو خمسة عشر + +164 +00:19:55,220 --> 00:20:00,580 +يومًا على مذهب الإمام الشافعي وإذا طلقها في النفاس + +165 +00:20:00,580 --> 00:20:08,540 +فإن هذه المدة كلها لا تُحسب من عدتها وإنما تُحسب + +166 +00:20:08,540 --> 00:20:15,990 +بعد طهرها من دم النفاس وكما مرّ بنا في مساق الفقه + +167 +00:20:15,990 --> 00:20:23,910 +أو دراسات في الفقه أن النفاس أقلّه لحظة وغالبّه + +168 +00:20:23,910 --> 00:20:33,310 +أربعون أو أكثره أربعون وأكثره ستون عند الإمام + +169 +00:20:33,310 --> 00:20:38,750 +الشافعي فكل هذه الفترة قد تكون أربعين وقد تكون + +170 +00:20:38,750 --> 00:20:46,310 +ستين نعم كلها لا تحسب من عدة المرأة وهذا يضرّ بها + +171 +00:20:46,310 --> 00:20:53,910 +ويؤخرها إذا ما جاءها خاطب كفء يليق بها أولات + +172 +00:20:53,910 --> 00:21:00,690 +الأحمال أجلهنّ أن يضعن حملهنّ فإنه بذلك قد يؤخر + +173 +00:21:00,690 --> 00:21:11,170 +زواجها وقد يفوتها خاطب كفء إذا إذا طلقها في طهر قد + +174 +00:21:11,170 --> 00:21:16,610 +مسّها فيه فإن الطلاق يقع وهو طلاق بدعي لماذا سُمّي + +175 +00:21:16,610 --> 00:21:27,950 +بدعيًا لأنه يؤخر زواجها ويُطيل في عدتها وكذلك الطلاق + +176 +00:21:27,950 --> 00:21:34,290 +البدعي يكون في حيض أو يكون في نفاس لماذا أيضًا؟ + +177 +00:21:34,290 --> 00:21:40,010 +وهذا الكلام الذي أحكيَه ليس في الكتاب عشان كده + +178 +00:21:40,010 --> 00:21:47,970 +انتبهوا إليه جيدًا قلت لكم الأمر مهم جداً أولًا من + +179 +00:21:47,970 --> 00:21:54,940 +ناحية نفسية قد ينفر الزوج من الزوجة أثناء نزول + +180 +00:21:54,940 --> 00:22:00,940 +الدم عليها من حيض أو نفاس فقد لا يرغب الزوج في + +181 +00:22:00,940 --> 00:22:07,820 +زوجته فيتعجل بالطلاق ولكن الزوج عندما تطهر زوجته + +182 +00:22:07,820 --> 00:22:15,620 +فإنه يشتهيها ويقبل عليها ولذلك إذا ما طلق في طهر + +183 +00:22:15,620 --> 00:22:26,700 +لم يمسها فيه يكون قد طلق عن روية وعن قصد وعن إرادة + +184 +00:22:26,700 --> 00:22:33,140 +ولذلك سُمّي طلاقًا صنيًا إذا ما طلق في طهر لم يمسها + +185 +00:22:33,140 --> 00:22:37,780 +فيه لكن إذا طلق في حيض أو نفاس ومع أنه طلاق بدئي + +186 +00:22:37,780 --> 00:22:46,420 +وأنه يقع وقد يكون في حالة نفسية شاذة فهو لا يرغب + +187 +00:22:46,420 --> 00:22:52,440 +فيها ولا يقبل عليها بسبب نزول الدم عليها فيطلقها + +188 +00:22:52,440 --> 00:22:57,320 +هذا من ناحية النفسية أما من ناحية الشرعية فإنه + +189 +00:22:57,320 --> 00:23:03,580 +يُطيل عدتها كيف يُطيل عدتها أيضًا؟ لأن العدة لا تُحسب + +190 +00:23:03,580 --> 00:23:11,420 +في حيض أو نفاس متى تُحسب عدة المطلقة؟ عند بداية + +191 +00:23:11,420 --> 00:23:16,500 +الطهروانتبهوا إلى ذلك وهذا معنى قوله تبارك وتعالى + +192 +00:23:16,500 --> 00:23:22,280 +في صدر سورة الطلاق خطابًا إلى النبي عليه الصلاة + +193 +00:23:22,280 --> 00:23:27,190 +والسلام والخطاب إلى النبي وهذا هو الراجح من أقوال + +194 +00:23:27,190 --> 00:23:33,830 +أهل العلم خطاب إلى أمّته عليه الصلاة والسلام ولكنه + +195 +00:23:33,830 --> 00:23:38,250 +خطاب في شخص النبي عليه الصلاة والسلام كما قالوا: "يا" + +196 +00:23:38,250 --> 00:23:41,950 +أيها النبي اتق الله" والخطاب إلى أمة محمد عليه + +197 +00:23:41,950 --> 00:23:46,590 +الصلاة والسلام نعم وكذلك هنا يا أيها النبي إذا + +198 +00:23:46,590 --> 00:23:55,510 +طلقتم المؤمنات فطلقوهن لعدتهن وأحصلوا عدتهن نعم + +199 +00:23:55,510 --> 00:24:00,150 +فطلقوهن لعدتهن وأحصلوا عدتهنّ ما معنى قوله تعالى + +200 +00:24:00,150 --> 00:24:05,830 +"فطلقوهن لعدتهنّ" أي مستقبلات + +201 +00:24:05,830 --> 00:24:14,670 +عدة هنّ ومتى تستقبل المرأة عدتها في بداية طهرها لا + +202 +00:24:14,670 --> 00:24:20,710 +في حيضها ولا في نفاسها فلو طلقها في حيضها مثلًا فإنه + +203 +00:24:20,710 --> 00:24:27,040 +يُحرمها هذه الأيام لأن الحيض مثلًا على مذهب الإمام + +204 +00:24:27,040 --> 00:24:35,080 +الشافعي أقلّه يوم وليلة وغالبّه ست أو سبع وأكثره + +205 +00:24:35,080 --> 00:24:42,700 +خمسة عشر يومًا وعند غيره أكثره عشرة أيام فهذه المدة + +206 +00:24:44,590 --> 00:24:50,470 +سواء على مذهب الشافعي أو عند الحنفية فإن هذه المدة + +207 +00:24:50,470 --> 00:24:56,290 +تحرم منها الزوجة المطلقة ولا تُحسب في عدتها ناهيك + +208 +00:24:56,290 --> 00:25:01,450 +عن طلاقها في نفاس فعلى مذهب الإمام الشافعي أن أقلّ + +209 +00:25:01,450 --> 00:25:07,830 +النفاس لحظة وتغتسل غسل الجنابة كما ورد وهذه معلومة + +210 +00:25:07,830 --> 00:25:14,800 +نادرة لا يفقهها يعني كثير من الناس ولذلك إذا ما + +211 +00:25:14,800 --> 00:25:21,480 +طهرت بعد الولادة مباشرة فإنها تُعامل معاملة الحيض + +212 +00:25:21,480 --> 00:25:29,500 +وورد ذلك عن السيدة فاطمة بنت الرسول عليه الصلاة + +213 +00:25:29,500 --> 00:25:35,020 +والسلام وزوج علي وأمّ الحسن والحسين ولذلك إذا ما + +214 +00:25:35,020 --> 00:25:41,340 +سُئلتم والجواب علي والجوائز لكم لماذا سُمّيت فاطمة + +215 +00:25:41,340 --> 00:25:46,300 +الزهراء بالزهراء هذا سؤال لا يعرفه كثير من الناس + +216 +00:25:46,300 --> 00:25:52,920 +لأنها كانت تطهر عقب الولادة مباشرة ومن ثم تغتسل + +217 +00:25:52,920 --> 00:25:57,630 +غسل الجنابة وهذا موضوعنا في دراسات في الفقه أو في + +218 +00:25:57,630 --> 00:26:02,370 +الفقه المنهجي على مذهب الإمام الشافعي ولكن لست + +219 +00:26:02,370 --> 00:26:07,190 +بخيلة والشيء بالشيء يذكر قلت على مذهب الإمام + +220 +00:26:07,190 --> 00:26:14,270 +الشافعي أقلّ النفاس لحظة وغالبّه أربعون وغالب النساء + +221 +00:26:14,690 --> 00:26:21,570 +وخاصة في بلادنا الفلسطينية والغزية وأكثره ستون أما + +222 +00:26:21,570 --> 00:26:28,470 +عند غيره فأكثر النفاس أربعون نعم قلت فلو طلقها في + +223 +00:26:28,470 --> 00:26:33,550 +هذه المدة الطويلة فإن هذه المدة كلها لا تُحسب من + +224 +00:26:33,550 --> 00:26:39,170 +العدة إنما تُحسب العدة في بداية طهرها هذا معنى قوله + +225 +00:26:39,170 --> 00:26:44,760 +يا أيها النبي إذا طلقتم من المؤمنات فطلقوهن لعدتهنّ و + +226 +00:26:44,760 --> 00:26:47,180 +أحصلوا عليها فطلقوهن لعدتهنّ + +227 +00:26:49,310 --> 00:26:56,970 +مستقبلات عدة هما قلت ومتى تستقبل المرأة عدةها عند + +228 +00:26:56,970 --> 00:27:04,350 +طهرها من نفاس أو حيض من أجل ذلك سُمّي طلاقه بدعيًا + +229 +00:27:04,350 --> 00:27:09,950 +إذا كان في حيض أو نفاس أو كان في طهر مسّها فيه لأنه + +230 +00:27:09,950 --> 00:27:15,440 +يضرّ بالمرأة إذا ما طلقها ويُحرمها من خاطب كفء نعم + +231 +00:27:15,440 --> 00:27:22,220 +قلت الطلاق السنوي أن يطلق طلقة واحدة رجعية في طهر + +232 +00:27:22,220 --> 00:27:29,800 +لم يمسها فيه لماذا سُمّيت طلقة رجعية؟ لأنّ نصاب + +233 +00:27:29,800 --> 00:27:35,270 +الطلاق ثلاثة كما قال الله تعالى: "الطلاق مرتان أين" + +234 +00:27:35,270 --> 00:27:41,070 +"الثالثة؟ فإما مُسَاكَنَةٌ بمعروف أو تسريح بإحسان" فإما مُسَاكَنَةٌ + +235 +00:27:41,070 --> 00:27:46,110 +بمعروف وحسن الأشر كما قلنا من حقّ الزوج على زوجته + +236 +00:27:46,110 --> 00:27:51,010 +ومن حقّ الزوجة على زوجها أن يحصن كل من الزوجين + +237 +00:27:51,010 --> 00:27:58,370 +معاشرة الآخر أو تسريح بإحسان التسريح هو الطلاق بأن + +238 +00:27:58,370 --> 00:28:06,730 +يُعطي المرأة حقّها وألاّ يحرمها حقّها من المهر من مؤخر + +239 +00:28:06,730 --> 00:28:13,550 +أو عفش بيت ونحن قلنا بأنّ عفش البيت هو سلاح وضعه + +240 +00:28:13,550 --> 00:28:19,270 +الشرع في يد المرأة لها أن تطالب به زوجها متى شاءت + +241 +00:28:19,270 --> 00:28:25,250 +حتى ولو أحسن إليها حتى قلت يومًا بلغتي أنا لو + +242 +00:28:25,250 --> 00:28:31,280 +ألبسها الحرير وهزّ لها السرير أما المؤخر فهو كما + +243 +00:28:31,280 --> 00:28:36,280 +يُكتب في عقد القران أو عقد الزواج أو إذن النعمة + +244 +00:28:36,280 --> 00:28:42,060 +عند أقرب الأجلين الطلاق أو الوفاء فإنه يُخصم من + +245 +00:28:42,060 --> 00:28:49,100 +التركة قبل توزيع التركة لأنه حقّ آدمي وحقّ آدمي + +246 +00:28:49,100 --> 00:28:55,940 +مقدم على حقّ الله كوصية من بعد وصية يُوصى بها أو دين + +247 +00:28:55,940 --> 00:29:04,380 +ولذلك مراحله التركة أربعة: دفن، فدين، فوصية، فميراث + +248 +00:29:04,380 --> 00:29:09,080 +فالدين قبل الوصية وقبل الميراث لأنه من حقوق + +249 +00:29:09,080 --> 00:29:14,780 +الآدميين وحقوق الآدميين مقدمة على حقوق الله تبارك + +250 +00:29:14,780 --> 00:29:22,220 +وتعالى فإذا مطلق طلقة واحدة فثمّة طلقتان أخريان لكن + +251 +00:29:22,220 --> 00:29:29,000 +المشكلة الكبرى التي تُزعج المفتين والقضاء في + +252 +00:29:29,000 --> 00:29:34,100 +المحاكم الشرعية إذا ما طلقها سلسًا وقال لها مثلًا + +253 +00:29:34,100 --> 00:29:39,460 +أنتِ طالق سلسًا دفعة واحدة أو قال أنتِ طالق أنتِ طالق + +254 +00:29:39,460 --> 00:29:45,140 +أنتِ طالق فعلى المذاهب الأربعة يُعتبروا طلاقًا + +255 +00:29:45,140 --> 00:29:50,080 +ثلاثًا وتبين منه الزوجة بينونة كبرى وهذه مصيبة + +256 +00:29:50,080 --> 00:29:56,400 +وهذه كارثة لما فيها من تمسيخ البيوت وخراب الديار + +257 +00:29:56,400 --> 00:30:04,470 +وتشتيت الأطفال ولذلك كان الطلاق الصني أن يطلق طلقة + +258 +00:30:04,470 --> 00:30:13,830 +واحدة رجعية حتى تعود إليه زوجته هنا إذا ما طلق + +259 +00:30:13,830 --> 00:30:20,390 +طلقة واحدة رجعية ولها عدة كما قلنا سلاسة قراءة + +260 +00:30:20,390 --> 00:30:26,910 +سلاسة حيضات أو سلاسة أطهار أو سلاسة أشهر أو تسعين + +261 +00:30:26,910 --> 00:30:34,620 +يومًا بلغة هذا الزمان فله أن يرجعها له حقّ الرجعة + +262 +00:30:34,620 --> 00:30:40,660 +وكيف تكون الرجعة أثناء العدة إما قولًا وإما فعلًا + +263 +00:30:40,660 --> 00:30:46,000 +وإما قولًا وفعلًا كما ذهب الإمام الشافعي حتى لا تشبه + +264 +00:30:46,000 --> 00:30:51,800 +الزنا والقول أن يقول الزوج لزوجته أرجعتك إلى عصمته + +265 +00:30:51,800 --> 00:30:58,040 +حتى ولو لم يكن شهود انظروا إلى عظمة الإسلام من باب + +266 +00:30:58,040 --> 00:31:05,630 +التيسير ومن باب أن تعود المياه إلى مجاريها لا + +267 +00:31:05,630 --> 00:31:13,090 +يُشترط شهود ولا يُشترط خطاب الزوجة لا يُشترط أن + +268 +00:31:13,090 --> 00:31:19,670 +تكون الرجعة مواجهة فلو أرجعها بينها وبين ربها وحلف + +269 +00:31:19,670 --> 00:31:27,480 +بذلك للقاضي فإن القاضي يُصدقه نعم لأن الغاية هي أن + +270 +00:31:27,480 --> 00:31:32,800 +تعود اللحمة وأن تعود الوشائج نعم فإذا قال الزوج + +271 +00:31:32,800 --> 00:31:39,240 +أرجعت زوجتي إلى عصمتي بدون شهود ولا حضور الزوجة أو + +272 +00:31:39,240 --> 00:31:44,060 +خاطبها أرجعتك إلى عصمتي عند المذاهب الأخرى عدا + +273 +00:31:44,060 --> 00:31:50,240 +الإمام الشافعي تُعتبر هذه رجعة وهناك + +274 +00:31:50,240 --> 00:31:57,300 +رجعة فعلية بالجماع إذا ما جامع الزوج زوجته فإنها + +275 +00:31:57,300 --> 00:32:07,440 +ترجع له نعم إذا إما أن يكون رجوع الزوجة قولًا "أرجعتك" + +276 +00:32:07,440 --> 00:32:13,180 +"إلى عصمتي" وإما أن يكون فعلًا بالجماع لكن الإمام + +277 +00:32:13,180 --> 00:32:18,020 +الشافعي قال لابدّ أن يكون قولًا وفعلًا لا يكفي أن + +278 +00:32:18,020 --> 00:32:22,720 +تكون الرجعة فعلًا حتى لا تشبه الزنا ولكن يجوز عند + +279 +00:32:22,720 --> 00:32:29,240 +غيره بالقول وبالفعل وهنا لابدّ أن ألفت الأنظار إلى + +280 +00:32:29,240 --> 00:32:34,600 +خطأ يقع فيه كثير من الناس عندما يكون الزوج غاضبًا و + +281 +00:32:34,600 --> 00:32:41,480 +سائرا ويحلف على زوجته طلقة واحدة رجعية فماذا تصنع + +282 +00:32:41,480 --> 00:32:49,800 +هذه الزوجة الجاهلة إنَّها تلملم ثيابها وتحمل حقيبتها + +283 +00:32:49,800 --> 00:32:56,590 +وتخرج إلى بيت أهلها وهنا تكون الكارثة والمصيبة و + +284 +00:32:56,590 --> 00:33:04,170 +يجتمع النسوة والمحرضون ليفسدوا علاقتها مع زوجها + +285 +00:33:04,170 --> 00:33:10,010 +أقولوا وهذا كلام مهم ودقيق وقلت أكثر من مرة + +286 +00:33:10,010 --> 00:33:18,830 +الكلام مهم نعم على الزوجة إذا ما حلف عليها الزوج + +287 +00:33:18,830 --> 00:33:24,080 +الطلاق الذي تخرج من بيتها أما سمعتم قوله تعالى لا + +288 +00:33:24,080 --> 00:33:30,760 +تخرجوهن من بيوتهن أي في مدة العدة حيث لها حق + +289 +00:33:30,760 --> 00:33:37,760 +السكنى نعم تبقى في بيت الزوج بل أقول لكم كلامًا + +290 +00:33:37,760 --> 00:33:46,440 +غريبًا قد تسمعوه لأول مرة في هذه الحال عليها أن + +291 +00:33:46,440 --> 00:33:54,460 +تتزين لزوجها خرج الزوج غاضبًا وثائرًا وعاد آخر + +292 +00:33:54,460 --> 00:34:04,680 +الليل وإذا بزوجته بثوب زفافها نعم قد تزينت وتجملت + +293 +00:34:04,680 --> 00:34:10,840 +وتعترفت فإذا ما جمعها الزوج عادت المياه إلى مجاريها + +294 +00:34:10,840 --> 00:34:18,280 +هذه هي الرجعة الفعلية كما قلت آنفًا إذا لا تخرج من + +295 +00:34:18,280 --> 00:34:24,270 +بيتِها لأن الخروج من البيت يزيد الطين بِاللّهوداء + +296 +00:34:24,270 --> 00:34:30,770 +علّها بل تبقى في بيتها أثناء عدتها لأن لها حق + +297 +00:34:30,770 --> 00:34:40,430 +السكنى هنا نعود إلى مسألة أخرى إذا لم يرجع الزوج + +298 +00:34:40,430 --> 00:34:46,190 +وزوجته أثناء العدة ومضت العدة دون إرجاع لا بقول + +299 +00:34:46,190 --> 00:34:51,150 +ولا بفعل حتى انتهت العدة ماذا يسمى هنا تكون وقد + +300 +00:34:51,150 --> 00:34:57,570 +بانت منه زوجة بينونة صغرى ما معنى بينونة صغرى + +301 +00:34:57,570 --> 00:35:04,410 +بمعنى أنها تحل لزوجها الأول لكن بمهر وعقد جديدين + +302 +00:35:04,410 --> 00:35:13,780 +ولا تستغربوا فالمهر ليس 3000 دينار أو 5000 دينار + +303 +00:35:13,780 --> 00:35:23,920 +يكفي 100 دينار نعم في هذه الحال تعود الزوجة إلى + +304 +00:35:23,920 --> 00:35:31,080 +زوجها بمهر وعقد جديدين لكن مع ملاحظة بإرادتها + +305 +00:35:31,080 --> 00:35:39,560 +واختيارها هنا الفرق دقيق بين أن تكون الرجعة أثناء + +306 +00:35:39,560 --> 00:35:45,380 +العدة فإنه لا يشترط رضاها انتبهوا إلى هذه المسألة + +307 +00:35:45,380 --> 00:35:50,940 +فإنها مسائل قد تأتي في الامتحانات إذا كان إرجاع + +308 +00:35:50,940 --> 00:35:57,960 +الزوجة أثناء عدتها لا يشترط رضاها ولا يشترط شهود + +309 +00:35:57,960 --> 00:36:05,340 +ولا يشترط مهر وعقد جديدان لكن إذا ما انتهت العدة + +310 +00:36:05,340 --> 00:36:12,220 +من الطلقة الأولى وقد بانت من زوجها بينونة صغرى + +311 +00:36:12,220 --> 00:36:19,540 +فإنها أصبحت حرة أصبحت طليقة بمعنى لها أن تقبل + +312 +00:36:19,540 --> 00:36:25,340 +العودة ولها أن لا تقبل العودة لكن النبي عليه الصلاة + +313 +00:36:25,340 --> 00:36:31,220 +والسلام في بعض الأحاديث رغب أن تعود الزوجة إلى + +314 +00:36:31,220 --> 00:36:39,760 +زوجها وخاصة إذا كان زوجها صالحًا وبينهما صغار أو + +315 +00:36:39,760 --> 00:36:46,640 +أولاد أو ذرية نعم فإن الزوج في حال الغضب قد يفعل + +316 +00:36:46,640 --> 00:36:53,360 +ما يفعل ولكن سرعان ما تهدأ ثورته ويعود إلى عقله + +317 +00:36:53,360 --> 00:36:59,760 +ويعود إلى صوابه وإلى رشده فإذا ما طلق الزوج زوجته + +318 +00:36:59,760 --> 00:37:05,370 +طلقة ثانية فالأحكام هي الأحكام في الطلقة الأولى + +319 +00:37:05,370 --> 00:37:11,570 +عليه إرجاعها أثناء العدة إما قولًا أرجعتك إلى + +320 +00:37:11,570 --> 00:37:17,010 +عصمتي وإما فعلًا بالجماع وفي هذه الحالة أيضًا ليس + +321 +00:37:17,010 --> 00:37:23,710 +لها أن تخرج من البيت لأن الخروج من البيت كما + +322 +00:37:23,710 --> 00:37:32,150 +أسلفنا لا يأتي بخير بل تبقى في بيت زوجيتها نعم + +323 +00:37:32,150 --> 00:37:39,010 +فإذا انتهت العدة ولم يراجعها الزوج بانت منه أيضًا + +324 +00:37:39,010 --> 00:37:46,250 +بينونة صغرى بمعنى أنها تحل له ولكن كما قلت برضاه + +325 +00:37:46,250 --> 00:37:57,810 +برضاه بمهر وعقد جديدين ولا يشترط آلاف من الدنانير + +326 +00:37:58,700 --> 00:38:04,500 +نعم بل إن المهر قد يكون آية من كتاب الله كما جاء + +327 +00:38:04,500 --> 00:38:10,880 +في بعض الروايات حفظهم إياها فذاك مهرها نعم لكن + +328 +00:38:10,880 --> 00:38:19,440 +ثالثة الأثافي وداهية الدواهي إذا ما طلقها الطلقة + +329 +00:38:19,440 --> 00:38:26,300 +الثالثة ففي هذه الحال ليست ثمة رجعة لأنها تسمى + +330 +00:38:27,000 --> 00:38:32,940 +بينونة كبرى ومعنى البينونة الكبرى أن تنكح زوجًا + +331 +00:38:32,940 --> 00:38:37,040 +غيره كما قال الله تبارك وتعالى في حق الزوج الأول + +332 +00:38:37,040 --> 00:38:44,120 +فإن طلقها أي الزوج الأول الطلقة الثالثة وبانت منه + +333 +00:38:44,120 --> 00:38:50,600 +بينونة كبرى فلا تحل له من بعده حتى تنكح زوجًا غيره + +334 +00:38:50,600 --> 00:38:58,240 +وهنا لابد أن نركز على بعض الأحكام أن تنكح زوجًا غيره + +335 +00:38:58,240 --> 00:39:04,680 +نكاحًا حقيقيًا نكاحًا صحيحًا ولا يكون ذلك إلا + +336 +00:39:04,680 --> 00:39:12,220 +بالجماع كما ورد عن بعض الصحابيات أنها طلقت ثلاثًا + +337 +00:39:12,220 --> 00:39:19,500 +وبانت من زوجها بينونة كبرى وكانت تحب زوجها وأرادت + +338 +00:39:19,500 --> 00:39:25,750 +أن تعود إليه قبل الدخول بها فقال النبي عليه الصلاة + +339 +00:39:25,750 --> 00:39:33,450 +والسلام لا حتى يذوق سيلتك وتذوق سيلته قال أهل + +340 +00:39:33,450 --> 00:39:41,510 +العلم هذا كناية عن الجماع وأن يطلقها الزوج الثاني + +341 +00:39:41,510 --> 00:39:51,650 +باختياره ومحض إرادته وإلا والعياذ بالله كان التيس + +342 +00:39:51,650 --> 00:39:59,330 +المستعار كما سماه النبي عليه أفضل الصلاة وأزكى + +343 +00:39:59,330 --> 00:40:04,030 +السلام وهو ملعون واللعن هو الطرد من رحمة الله لعن + +344 +00:40:04,030 --> 00:40:10,350 +الله المحلل والمحللة حتى اعتبرهم عمر بن الخطاب + +345 +00:40:10,350 --> 00:40:19,900 +زانيين لا أوتي بمحلل ومحللة إلا رجمتهما والعياذ بالله + +346 +00:40:19,900 --> 00:40:28,160 +كما يحصل في هذه الأيام أن تكون مؤامرة أو اتفاق + +347 +00:40:28,160 --> 00:40:33,200 +مسبق بين الزوج الأول والزوج الثاني ويقولوا له إياك + +348 +00:40:33,200 --> 00:40:37,880 +أن تقترب منها إياك أن تدخل عليها إياك أن تمسها ولك + +349 +00:40:37,880 --> 00:40:43,460 +مثلًا مائة دينار إذا ما طلقتها هذا كله حرام ولا + +350 +00:40:43,460 --> 00:40:50,060 +يليق ولا ينبغي وقد تكلمنا عن الزواج المؤقت نكاح + +351 +00:40:50,060 --> 00:40:54,320 +المتعة عند الشيعة أما الزواج في الإسلام فإذا ما + +352 +00:40:54,320 --> 00:41:01,720 +تزوجت الزوج الثاني وطلقها الزوج الثاني بإرادته + +353 +00:41:01,720 --> 00:41:07,480 +ومحض اختياره كما أسلفنا دون مؤامرة أو اتفاق مسبق + +354 +00:41:07,480 --> 00:41:12,980 +بين الزوج الأول والثاني أو توفي عنها ففي هذه الحال + +355 +00:41:12,980 --> 00:41:20,810 +تعود إلى زوجها الأول ولكن بعد أن تنقضي عدتها من + +356 +00:41:20,810 --> 00:41:25,850 +الزوج الثاني إن كانت طلاقًا فبعد ثلاثة أشهر أو + +357 +00:41:25,850 --> 00:41:30,650 +تسعين يومًا وإن كانت وفاة فبعد مائة وثلاثين يومًا + +358 +00:41:30,650 --> 00:41:34,670 +أربعة أشهر وعشرة كما تكلمنا في الحقوق الزوجية ومن + +359 +00:41:34,670 --> 00:41:40,690 +حقوق الزوج على زوجته العدة نعم قال الله تبارك + +360 +00:41:40,690 --> 00:41:49,290 +وتعالى فإن طلقها أي الزوج الثاني بإرادته واختياره + +361 +00:41:49,290 --> 00:41:56,410 +فلا جناح عليهم أي تراجعة إن ظن أن يقيم حدود الله + +362 +00:41:56,410 --> 00:42:05,830 +وساعة إذن يبدأان حياة زوجية جديدة وتمحى الطلاقات + +363 +00:42:05,830 --> 00:42:13,600 +الثلاثة طبعًا هذا الموضوع من المواضيع المهمة التي + +364 +00:42:13,600 --> 00:42:17,600 +تدرس بالتفصيل + +365 +00:42:17,600 --> 00:42:23,100 +في كلية الشريعة فعودوا إليه وانتبهوا الآن نأتي + +366 +00:42:23,100 --> 00:42:32,040 +للمبحث الخامس من الفصل الرابع نظام الأسرة في + +367 +00:42:32,040 --> 00:42:36,680 +الإسلام وهو بنوان مكانة المرأة وحقوق الإسلام لكن + +368 +00:42:36,680 --> 00:42:42,200 +نلفت أنظاركم بأن هذا العنوان ينقسم إلى قسمين أولًا وثانيًا + +369 +00:42:42,200 --> 00:42:49,700 +أولًا غير مطلوب في الامتحان فنتخطاه وهو مكانة + +370 +00:42:49,700 --> 00:42:58,400 +المرأة عند غير المسلمين عند اليونان وعند الرومان + +371 +00:42:58,400 --> 00:43:09,190 +وعند اليهود وعند النصارى المسيحيين وعند الهنود و + +372 +00:43:09,190 --> 00:43:13,630 +عند العرب قبل الإسلام فكل هذا ليس مطلوبًا في + +373 +00:43:13,630 --> 00:43:21,070 +الامتحان المطلوب في الامتحان ثانيًا المرأة عند + +374 +00:43:21,070 --> 00:43:26,890 +المسلمين وهذا ما يكفينا هذا ما يكفينا فإن الإسلام + +375 +00:43:26,890 --> 00:43:33,430 +هو الذي كرّم المرأة المرأة لم تكن ذا كرامة عند غير + +376 +00:43:33,430 --> 00:43:41,010 +المسلمين وقد علمتم كيف كان حالها في الهند وغير + +377 +00:43:41,010 --> 00:43:46,690 +الهند فإذا مات الزوج في الهند يحرم على المرأة أن + +378 +00:43:46,690 --> 00:43:55,010 +تبقى على قيد الحياة كانت تُحرق حية مع زوجها هذا في + +379 +00:43:55,010 --> 00:44:02,370 +زمن من أزمان الهند أي نعم وفي الجاهلية كانت تقتل + +380 +00:44:02,370 --> 00:44:07,950 +حية إذا ما كانت أنثى وإذا الموقودة سئلَة بأي ذنب + +381 +00:44:07,950 --> 00:44:15,660 +قُتلت نعم وإذا بُشِّر أحدهم بالأُنثى ظل وجهه مسودًا + +382 +00:44:15,660 --> 00:44:21,040 +وهو كظيم يتوارى من القوم من سوء ما بشر به أيمسكه + +383 +00:44:21,040 --> 00:44:27,520 +على هون أم يدسه في الطراب ألا ساء ما يحكمون فجاء + +384 +00:44:27,520 --> 00:44:33,720 +الإسلام ورفع قدرها ورفع شأنها وأنزل أحكامًا لها + +385 +00:44:33,720 --> 00:44:41,120 +وجعل لها ذمة مالية وأحكامًا شرعية وهناك صورة هي صورة + +386 +00:44:41,120 --> 00:44:47,900 +النساء وقد استمع الله إليها من فوق سبع سماوات في + +387 +00:44:47,900 --> 00:44:53,880 +قصة المجادلة في سورة المجادلة قد سمع الله قول التي + +388 +00:44:53,880 --> 00:44:59,320 +تجادلك في زوجها وتشتكي إلى الله والله يسمع تحاركما + +389 +00:44:59,320 --> 00:45:07,110 +إن الله سميع بصير نعم نأتي الآن إلى مظاهر عناية + +390 +00:45:07,110 --> 00:45:12,930 +الإسلام بالمرأة أولًا مساواة المرأة مع الرجل في + +391 +00:45:12,930 --> 00:45:22,830 +الإنسانية وهنا نقول إن الرجل إنسان والمرأة إنسان + +392 +00:45:23,760 --> 00:45:30,140 +هنا من الأخطاء الشائعة اللغوية يقال الرجل إنسان والمرأة إنسانة + +393 +00:45:30,140 --> 00:45:35,780 +هذا ليس بصحيح الرجل إنسان والمرأة + +394 +00:45:35,780 --> 00:45:46,400 +أيضًا إنسان وصمّى الإنسان إنسانًا إما لنسيانه كما قال + +395 +00:45:46,400 --> 00:45:52,840 +الله تعالى في قصة آدم فنسي ولم نجد له عزمة وإما + +396 +00:45:52,840 --> 00:46:01,120 +لأُنسِه بِرَبِّه لأُنسِه بِرَبِّه كما قال الشعر العربي وما صُممّى + +397 +00:46:01,120 --> 00:46:09,090 +الإنسان إلا لأُنسِه ولا القلب إلا أنه يتقلبوا قال + +398 +00:46:09,090 --> 00:46:13,390 +الله تعالى يا أيها الناس ابتغوا ربكم الذي خلقكم من + +399 +00:46:13,390 --> 00:46:20,920 +نفس واحدة في صدري صورتي النساء يا أيها الناس تطاب + +400 +00:46:20,920 --> 00:46:25,520 +إلى كل الناس من عرب ومن عجم من أبيض ومن أسود من + +401 +00:46:25,520 --> 00:46:29,880 +ذكر ومن أنثى يا أيها الناس ابتغوا ربكم الذي خلقكم + +402 +00:46:29,880 --> 00:46:35,760 +من نفس واحدة فكلكم لآدم وآدم من تراب وحواء خلقت من + +403 +00:46:35,760 --> 00:46:40,780 +ضلع آدم الأيسر ولذلك قال عليه الصلاة والسلام + +404 +00:46:40,780 --> 00:46:48,170 +النساء شقائق الرجال ومعنى هذا الحديث وهذا من باب + +405 +00:46:48,170 --> 00:46:57,550 +التشبيه البليغ كأن المرأة والرجل عصا فشقت المرأة + +406 +00:46:57,550 --> 00:47:04,830 +من الرجل نعم وقال تعالى ولهن مثل الذي عليهن + +407 +00:47:04,830 --> 00:47:11,390 +بالمعروف فمساواة المرأة مع الرجل في الإنسانية أول + +408 +00:47:11,390 --> 00:47:16,610 +مظاهر عناية الإسلام بالمعروف ثانيًا دفع عنها اللعنة + +409 +00:47:16,610 --> 00:47:22,610 +التي أُلصِقَت بها الديانات السابقة من اليهودية + +410 +00:47:22,610 --> 00:47:27,390 +والنصرانية وأقول بأن الكتب التي بين أيدي اليهود + +411 +00:47:27,390 --> 00:47:32,570 +والنصارى ليست هي الكتب التي أنزلها الله فالتوراة + +412 +00:47:32,570 --> 00:47:37,710 +ليست هي التوراة والإنجيل ليس هو الإنجيل إنه هو من + +413 +00:47:37,710 --> 00:47:43,890 +صنعهم ومن كتابة أيديهم كما قال الله تعالى يفضحهم + +414 +00:47:43,890 --> 00:47:48,770 +فويل للذين يكتبون الكتاب بأيديهم ثم يقولون هذا من + +415 +00:47:48,770 --> 00:47:54,480 +عند الله ليشتروا به ثمنًا قليلًا فويلٌ لهم مما كتبت + +416 +00:47:54,480 --> 00:48:03,580 +أيديهم وويلٌ لهم مما يكسبون فزعموا بأن حواء عليها + +417 +00:48:03,580 --> 00:48:09,420 +السلام هي التي أغوت آدم وهي التي أخرجته من الجنة + +418 +00:48:09,420 --> 00:48:14,950 +هذا كلام الغرب الذين يدعون الحرية والديمقراطية + +419 +00:48:14,950 --> 00:48:20,270 +ويتغنون بمكانة المرأة وأن الإسلام قد ظلم المرأة + +420 +00:48:20,270 --> 00:48:29,630 +نقول لهم بأن الإسلام هو الذي دفع عنها اللعنة وبيّن + +421 +00:48:29,630 --> 00:48:38,700 +القرآن الكريم بأن كل من آدم وحواء كانا ضحية لإبليس + +422 +00:48:38,700 --> 00:48:45,660 +والشيطان الرجيم فإبليس هو الذي أضلهما بدليل قوله + +423 +00:48:45,660 --> 00:48:53,320 +فأزلهما الشيطان فالشيطان هو الذي أزلهما وأخرجهما + +424 +00:48:53,320 --> 00:49:01,580 +من الجنة وقال تعالى فوسوس لهما الشيطان فالشيطان هو + +425 +00:49:01,580 --> 00:49:06,800 +الذي وسوس لهما وليس حواء هي التي وسوست لآدم بدليل + +426 +00:49:06,800 --> 00:49:13,320 +أيضا في سورة الأعراف قال ربنا ظلمنا أنفسنا وإن لم + +427 +00:49:13,320 --> 00:49:17,340 +تغفر لنا وترحمنا لنكنن الخاسرين نعم أقول أيضا ما + +428 +00:49:17,340 --> 00:49:23,030 +أحبجنا إلى هذا الدعاء ونحن في شهر رمضان المبارك فكل + +429 +00:49:23,030 --> 00:49:27,550 +بني آدم خطأون وخير الخطائين التوابون وليس العيب في + +430 +00:49:27,550 --> 00:49:31,390 +الخطأ إنما العيب هو الإصرار على الخطأ فأبواب + +431 +00:49:31,390 --> 00:49:35,710 +السماء مفتوحة وأبواب التوبة لا تغلق أبدا يا ليتنا + +432 +00:49:35,710 --> 00:49:41,310 +ندعو الله بهذا الدعاء على لسان آدم وحواء أبوين + +433 +00:49:41,310 --> 00:49:47,090 +عليهما السلام قال ربنا ظلمنا أنفسنا وإن لم تغفر لنا + +434 +00:49:47,090 --> 00:49:53,790 +وترحمنا لنكون من الخاسرين بل إنه في بعض المواضع + +435 +00:49:53,790 --> 00:50:00,970 +حمل الله آدم المسؤولية وأحمَل ذكرى حواء فقال تعالى + +436 +00:50:00,970 --> 00:50:10,330 +وعصى آدم ربه فغوى فكل نفس كما مر بنا قبل قليل في + +437 +00:50:10,330 --> 00:50:15,410 +الحديث كلكم راع وكلكم مسئول عن رعيته كما قال + +438 +00:50:15,410 --> 00:50:23,770 +تعالى كل نفس بما كسبت رهينة أما ثالثا فالمرأة في + +439 +00:50:23,770 --> 00:50:32,130 +الإسلام أهل للمسؤولية الكاملة فهي مكلفة شرعًا وهي + +440 +00:50:32,130 --> 00:50:38,610 +مخاطبة بالخطاب الشرعي كالرجل تمامًا وقد جاء هذا في + +441 +00:50:38,610 --> 00:50:42,230 +أكثر من آية في القرآن مثل قوله تبارك وتعالى ومن + +442 +00:50:42,230 --> 00:50:48,610 +يعمل من الصالحات من ذكر أو أنثى رأيتم من ذكر أو + +443 +00:50:48,610 --> 00:50:55,190 +أنثى وهو مؤمن فأولئك يدخلون الجنة ولا يظلمون نقيرا + +444 +00:50:55,190 --> 00:50:59,930 +وقوله تبارك وتعالى فاستجاب لهم ربهم أني لا أضيع + +445 +00:50:59,930 --> 00:51:06,350 +عمل عامل منكم من ذكر أو أنثى بعضكم من بعض أي بعضكم + +446 +00:51:06,350 --> 00:51:12,610 +من بعض في الثواب والأحكام والنصرة ونحو ذلك قال + +447 +00:51:12,610 --> 00:51:18,790 +الضحاك رجالكم شَكلُ نسائكم في الطاعة ونسائكم شَكلُ + +448 +00:51:18,790 --> 00:51:24,550 +رجالكم في الطاعة ولهن مثل الذي عليهن بالمعروف + +449 +00:51:24,550 --> 00:51:32,590 +فالرجل مسئول والمرأة مسئولة وتبلغ الذروة في مطالبة + +450 +00:51:32,590 --> 00:51:38,310 +المرأة في البيعة فالمرأة مطالبة بالبيعة كما أن + +451 +00:51:38,310 --> 00:51:42,630 +الرجل مطالب بالبيعة لقد رضي الله عن المؤمنين إذ + +452 +00:51:42,630 --> 00:51:48,720 +يبايعونك تحت الشجرة في سورة الفتح وفي قصة صلح + +453 +00:51:48,720 --> 00:51:56,240 +الحديبية نعم التي سماها البخاري غزوة الحديبية و + +454 +00:51:56,240 --> 00:52:02,940 +القصة معروفة عند أسرى أثمان وسميت بيعته الرضوان + +455 +00:52:03,750 --> 00:52:08,850 +لأنهم بايعوا على الموت في سبيل الله لقد رضي الله + +456 +00:52:08,850 --> 00:52:12,750 +عن المؤمنين إذ يبايعونك تحت الشجرة إن الذين + +457 +00:52:12,750 --> 00:52:17,490 +يبايعونك إنما يبايعون الله يضع الله فوق أيديهم + +458 +00:52:17,490 --> 00:52:23,130 +فمن نكث فإنما ينكث على نفسه ومن أوفى بما عاهد عليه + +459 +00:52:23,130 --> 00:52:29,600 +الله رأيتم كيف أن العهد يفخم لم يقل الله ومن أوفى + +460 +00:52:29,600 --> 00:52:34,120 +بما عهد عليه الله بالترقيق كما قال الله في حق + +461 +00:52:34,120 --> 00:52:41,000 +فرعون فرعون مُرَقَّق لأنه يُرَقِّق ولا يُفَخِّم قال أنا ربكم + +462 +00:52:41,000 --> 00:52:45,480 +الأعلى وما علمت لكم من إله أخر أما عهد الله فخّم + +463 +00:52:45,480 --> 00:52:49,820 +لم يقل ومن أوفى بما عهد عليه الله بالترقيق ومن + +464 +00:52:49,820 --> 00:52:55,280 +أوفى بما عهد عليه الله فسوف يتيه أجرا عظيمة وكذلك + +465 +00:52:55,280 --> 00:53:03,570 +المرأة مكلفة بالبيعة وهذا من أعظم الأدلة على أنها + +466 +00:53:03,570 --> 00:53:11,790 +مطالبة بالمسؤولية والتكاليف الشرعية يا أيها النبي + +467 +00:53:11,790 --> 00:53:16,930 +إذا جاءك المؤمنات يبايعنك على أن لا يشريكن بالله + +468 +00:53:16,930 --> 00:53:22,290 +شيئا ولا يسرقن ولا يزنين ولا يقتلن أولادهن ولا + +469 +00:53:22,290 --> 00:53:26,930 +يأتين ببهتان يفترينه بين أيديهن وأرجلهن ولا + +470 +00:53:26,930 --> 00:53:32,750 +يعصينك في معروف فبايعهن واستغفر لهن الله إن الله + +471 +00:53:32,750 --> 00:53:37,700 +غفور ورحيم أما رابعا من مظاهر عناية الإسلام بالمرأة + +472 +00:53:37,700 --> 00:53:45,060 +الترحيب بها منذ ولادتها وهذه كأنها تعني الكفار + +473 +00:53:45,060 --> 00:53:53,600 +الذين كانوا يقتلون المرأة عند ولادتها لأنها كانت + +474 +00:53:53,600 --> 00:54:00,610 +كما يقولون تجلب لهم العار عندما كانت تغير القبائل + +475 +00:54:00,610 --> 00:54:05,930 +القوية على القبائل الضعيفة فهم يحتكمون إلى شريعة + +476 +00:54:05,930 --> 00:54:12,850 +الغاب كالحيتان في البحر القوي منهم يقتلوا الضعيف + +477 +00:54:12,850 --> 00:54:18,870 +فكانت تسلب وكانت تباع ويدلّ عليها في أسواق النخاسة + +478 +00:54:18,870 --> 00:54:26,420 +فكانت فضيحة لأهلها كما ذكرنا من الآيات وهنا يقول + +479 +00:54:26,420 --> 00:54:31,800 +الله تبارك وتعالى لله ملك السماوات والأرض يخلق ما + +480 +00:54:31,800 --> 00:54:38,880 +يشاء يهب لمن يشاء أنوثة رأيتم قدم المرأة في الذكر + +481 +00:54:38,880 --> 00:54:46,140 +ليُلفت الأنظار إلى أهمية المرأة وهذا ما قاله بعضهم + +482 +00:54:46,940 --> 00:54:51,620 +يدافع عن قولهم عندما نسمع بعض المذيعين يخاطبوا + +483 +00:54:51,620 --> 00:54:57,920 +النساء قبل الرجال فماذا يقول سيداتي ساداتي قيل + +484 +00:54:57,920 --> 00:55:03,680 +أخذوا هذا من هذه الآية يهب لمن يشاء إناثا ويهبوا + +485 +00:55:03,680 --> 00:55:13,130 +لمن يشاء الذكور نعم أو يُسَوِّجُهم ذكورا وإناثا ويجعلوا + +486 +00:55:13,130 --> 00:55:19,130 +من يشاء عقيما قال ابن كثير الناس من جهة الأصل أربعة + +487 +00:55:19,130 --> 00:55:24,810 +ومن جهة الفرع أربعة من جهة الأصل أن الله خلق آدم + +488 +00:55:24,810 --> 00:55:33,190 +بدون ذكر ولا أنثى وخلق حواء من ذكر بدون أنثى وخلق + +489 +00:55:33,190 --> 00:55:37,410 +عيسى من أنثى بدون ذكر وخلق كل الناس كما في سورة + +490 +00:55:37,410 --> 00:55:42,310 +الحجرات من ذكر وأنثى ومن جهة الفروع أيضا أربعة + +491 +00:55:42,310 --> 00:55:50,210 +يهب لمن يشاء إناثا ويهب لمن يشاء ذكورا نعم قد + +492 +00:55:50,210 --> 00:55:56,110 +تكون كل خلفته إناث وقد تكون كل خلفته ذكورا أو + +493 +00:55:56,110 --> 00:56:04,830 +يُسَوِّجُهم ذكورا وإنّ أثر نعم ويجعل من يشاء عقيما وهنا + +494 +00:56:04,830 --> 00:56:11,330 +نقف عند قوله ويجعل من يشاء عقيما وهذا ليس معناه أن + +495 +00:56:11,330 --> 00:56:18,310 +لا علاج وأن الذي لا ينجب يستسلم وهنا أرى وهذا + +496 +00:56:18,310 --> 00:56:28,230 +اجتهاد شخصي أن الله قال يخلق ما يشاء ثم قال في عجز + +497 +00:56:28,230 --> 00:56:32,730 +الآية ويجعل من يشاء عقيما لم يقل الله ويخلقوا + +498 +00:56:32,730 --> 00:56:37,490 +ما يشاء عقيما لو قال ويخلقوا ما يشاء عقيما لما + +499 +00:56:37,490 --> 00:56:45,550 +أنجب أحد آه ولكنه قال في صدر الآية يخلق ما يشاء + +500 +00:56:45,550 --> 00:56:53,750 +وقال في عجزها ويجعلوا وكلمة جعله بمعنى صيّر + +501 +00:56:53,750 --> 00:56:58,530 +بمعنى الانتقال من حال إلى حال كما يقال في لغة + +502 +00:56:58,530 --> 00:57:03,530 +العرب جعلت الطين إبريقا يعني صيّرته إبريقا وما + +503 +00:57:03,530 --> 00:57:08,790 +يدريك أن العقيم يصبح منجبا أقول هذا حتى لا ييأس + +504 +00:57:08,790 --> 00:57:13,690 +العقيم الذي لا ينجب فقد ينجب ولا مانع أن يأخذ + +505 +00:57:13,690 --> 00:57:19,490 + بالأسباب والدواء والعلمتقدم وهذا ليس مطلوبا في + +506 +00:57:19,490 --> 00:57:29,310 +الامتحان ولكن الشيء بالشيء يذكر نعم خامسًا أمر + +507 +00:57:29,310 --> 00:57:36,400 +الإسلام بإكرام المرأة بنتًا وزوجة أما إكرامها بنتًا + +508 +00:57:36,400 --> 00:57:41,280 +فقد جاء في ذلك أحاديث كثيرة منها الأحاديث الصحيحة + +509 +00:57:41,280 --> 00:57:45,900 +قوله عليه الصلاة والسلام من ابتلي من البنات بشيء + +510 +00:57:45,900 --> 00:57:52,420 +فأحسن إليهن كن له سطرًا من النار يا فوزك ويا هنائك + +511 +00:57:52,650 --> 00:57:59,010 +من أكرمك الله بالإناث وبالبنات حجاب لك وستر لك + +512 +00:57:59,010 --> 00:58:04,890 +من النار إذا ما أحسنت إليهن وأدبتهن وزوجتهن + +513 +00:58:04,890 --> 00:58:09,310 +للصالحين وقال عليه الصلاة والسلام من على جاريتين + +514 +00:58:09,310 --> 00:58:15,910 +يعني أنثيين حتى تبلغ جاء يوم القيامة أنا وهو وقد + +515 +00:58:15,910 --> 00:58:22,100 +ضم السبابة والوسطى كما في حالة اليتيم أنا وكافل + +516 +00:58:22,100 --> 00:58:29,710 +اليتيم في الجنة كهتين وهكذا من أكرم البنات فهن له + +517 +00:58:29,710 --> 00:58:35,130 +إن شاء الله حجابًا وكذلك إكرامها زوجة وقد مر بنا في + +518 +00:58:35,130 --> 00:58:40,210 +باب الزواج قوله في سورة الروم سبحانه وتعالى ومن + +519 +00:58:40,210 --> 00:58:45,190 +آياته أي ومن دلائل قدرته أن خلق لكم من أنفسكم + +520 +00:58:45,190 --> 00:58:50,650 +أزواجا لتسكنوا إليها وجعل بينكم مودة ورحمة إن في + +521 +00:58:50,650 --> 00:58:56,600 +ذلك لآيات لقوم يتفكرون فهي آية من آيات الله مثل + +522 +00:58:56,600 --> 00:59:02,160 +الأرض والسموات وسائر الآيات التي ذكرها الله في + +523 +00:59:02,160 --> 00:59:06,260 +سورة الروم ويقول عليه الصلاة والسلام الدنيا متاع + +524 +00:59:06,260 --> 00:59:13,430 + وخير متاعها المرأة الصالحة وكأنه قيل ما صفتها يا + +525 +00:59:13,430 --> 00:59:18,330 +رسول الله قال إن نظر إليها اطمأن وإن أمرها أطاعته + +526 +00:59:18,330 --> 00:59:23,130 +وإن أقسم عليها أبرته وإن غاب عنها حفظته في ماله + +527 +00:59:23,130 --> 00:59:28,910 +وفي أرضه صلى الله عليه وسلم وأما إكرامها أما فما + +528 +00:59:28,910 --> 00:59:34,050 +أكثر الأدلة والشواهد من القرآن الكريم والسنة + +529 +00:59:34,050 --> 00:59:38,510 +النبوية فنكتفي بما في الكتاب مثل قوله تعالى + +530 +00:59:38,510 --> 00:59:44,330 +ووصينا الإنسان بوالديه إحسانا حملته أمه كرها + +531 +00:59:44,330 --> 00:59:48,890 +ووضعته كرها وقوله عليه الصلاة والسلام وقوله تبارك + +532 +00:59:48,890 --> 00:59:54,130 +وتعالى ووصينا الإنسان بوالديه حملته أمه وهنا على + +533 +00:59:54,130 --> 00:59:59,230 +وهن وفصاله في عمله أما الأحاديث فكثيرة منها قوله + +534 +00:59:59,230 --> 01:00:04,650 +عليه الصلاة والسلام من أحق الناس بحق صحبتي قال أمك + +535 +01:00:04,650 --> 01:00:11,590 +أمك أمك ثلاثًا لماذا أمك أمك ثلاثًا لأنها التي حملت + +536 +01:00:11,590 --> 01:00:18,130 +وهي التي أرضعت وهي التي ربت كان الله في عون الأم + +537 +01:00:18,130 --> 01:00:27,600 +ومن أعظم الوصية بالأم قصة الرجل الذي جاء من اليمن + +538 +01:00:27,600 --> 01:00:32,020 +فرحًا مسرورًا يريد أن يجاهد في سبيل الله يا رسول + +539 +01:00:32,020 --> 01:00:37,160 +الله تركت أبوي يبكيان نعم من أجل أن يجاهد في سبيل + +540 +01:00:37,160 --> 01:00:43,770 +الله فقال عد إليهما وأضحك هما كما أبكيتهما وكما + +541 +01:00:43,770 --> 01:00:48,030 +نرى في كتابة الكتاب + +542 +01:00:48,030 --> 01:00:54,710 +ففيهما فجاهل والحديث الآخر رغم أنف ثم رغم أنف ثم + +543 +01:00:54,710 --> 01:01:01,910 +رغم أنف وهذه رغم هي مثال عند العرب يُقْنَعُ به عن + +544 +01:01:01,910 --> 01:01:08,050 +الذلة واحتقار هذا الشخص عندما كان يُدَلِّقُ أنفه + +545 +01:01:08,050 --> 01:01:16,330 + بالتراب أن الرغام هو التراب قال من أدرك أبويه عند + +546 +01:01:16,330 --> 01:01:21,910 +الكبر أحداهما أو كلاهما فلم يدخل الجنة نعم + +547 +01:01:21,910 --> 01:01:26,710 +الآيات والأحاديث كما قلنا في ذلك كثيرة فنكتفي بما + +548 +01:01:26,710 --> 01:01:32,010 +في الكتاب سادسًا رغب الإسلام في تعليم المرأة + +549 +01:01:32,010 --> 01:01:39,200 +كالرجل نعم وهنا معنى حديثان الحديث الأول ثلاثة لهم + +550 +01:01:39,200 --> 01:01:43,660 +أجرات والذي يعنينا هو قوله عليه الصلاة والسلام + +551 +01:01:43,660 --> 01:01:50,100 +ورجل كانت عنده أمة فأدبها فأحسن تأديبًا وعلمها فأحسن + +552 +01:01:50,100 --> 01:01:56,100 +تعليمها ثم أعتقها فتزوجا فله أجرًا اللذي يعنينا فقط + +553 +01:01:56,100 --> 01:01:59,220 +من هذا الحديث الطويل هو قوله عليه الصلاة والسلام + +554 +01:01:59,220 --> 01:02:06,040 +وعلمها فأحسن تعليمًا وكذلك الحديث الآخر المحفوظ طلب + +555 +01:02:06,040 --> 01:02:12,020 +العلم فريضة على كل مسلم هنا يخطئ من يقول ومسلمة + +556 +01:02:12,020 --> 01:02:19,040 +لأن مسلم جنس يدخل فيه المسلمة كما يقال مثلًا عدد + +557 +01:02:19,040 --> 01:02:24,720 +طلاب الجامعة الإسلامية أربعة عشر ألف طالب فلا يقال + +558 +01:02:24,720 --> 01:02:31,360 +وطالبة لأن طالب اسمه جنس يشمل كل الطلاب وأنا أرى + +559 +01:02:31,360 --> 01:02:36,380 +أن أحسن معنى لهذا الحديث طلب العلم فريضة على كل + +560 +01:02:36,380 --> 01:02:43,210 +مسلم طلب العلم فريضة على كل من أسلم على كل من أسلم + +561 +01:02:43,210 --> 01:02:50,810 +فيدخل فيه الذكر ويدخل فيه الأنسة نعم سابعًا أعطاها + +562 +01:02:50,810 --> 01:02:56,010 +حقها في الميراث وهذا طبعًا طويل 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"end": 110.25, "text": "من أجل ذلك شرع الإسلام الخطوات الوقائية للحد من الطلاق وأول هذه الخطوات أن يحصن كل من الزوجين اختيار صاحبه وهذا الاختيار لا يكون بسبب المال", "tokens": [27842, 5551, 7435, 1211, 29910, 23275, 13412, 2288, 3615, 33688, 3794, 37440, 33962, 9566, 2407, 9307, 2423, 30543, 16373, 10632, 24976, 24401, 9154, 41950, 15040, 4587, 36725, 12610, 29538, 33962, 9566, 2407, 9307, 14739, 7251, 5016, 9381, 1863, 28242, 9154, 6024, 110, 29245, 9957, 1975, 9778, 31371, 9640, 20328, 39319, 3555, 3224, 37037, 15730, 2423, 47283, 31371, 9640, 20193, 7251, 30544, 4724, 35457, 3555, 9673, 6027], "avg_logprob": -0.05920592484189503, "compression_ratio": 1.7328767123287672, "no_speech_prob": 1.1920928955078125e-06, "words": [{"start": 85.93, "end": 86.19, "word": "من", "probability": 0.94921875}, {"start": 86.19, "end": 86.51, "word": " أجل", "probability": 0.9671223958333334}, {"start": 86.51, "end": 87.05, "word": " ذلك", "probability": 0.99560546875}, {"start": 87.05, "end": 88.67, 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"probability": 0.98486328125}, {"start": 3595.79, "end": 3596.27, "word": " عمله", "probability": 0.605712890625}, {"start": 3596.27, "end": 3596.59, "word": " أما", "probability": 0.899658203125}, {"start": 3596.59, "end": 3597.25, "word": " الأحاديث", "probability": 0.898046875}, {"start": 3597.25, "end": 3598.13, "word": " فكثيرة", "probability": 0.917236328125}, {"start": 3598.13, "end": 3598.81, "word": " منها", "probability": 0.980224609375}, {"start": 3598.81, "end": 3599.23, "word": " قوله", "probability": 0.98486328125}, {"start": 3599.23, "end": 3599.59, "word": " عليه", "probability": 0.9853515625}, {"start": 3599.59, "end": 3599.97, "word": " الصلاة", "probability": 0.9817708333333334}, {"start": 3599.97, "end": 3600.51, "word": " والسلام", "probability": 0.9749348958333334}], "temperature": 1.0}, {"id": 149, "seek": 362541, "start": 3601.21, "end": 3625.41, "text": "من أحق الناس بحسب صحبتي قال أمك أمك أمك ثلاثا لماذا أمك أمك ثلاثا لأنها التي حملت وهي التي أرضعت وهي التي ربت كان الله في عون الأم ومن أعظم الوصية بالأم قصته الرجل الذي جاء", "tokens": [27842, 5551, 5016, 4587, 2423, 8315, 3794, 4724, 5016, 35457, 20328, 5016, 3555, 31371, 50239, 5551, 2304, 4117, 5551, 2304, 4117, 5551, 2304, 4117, 38637, 1211, 5718, 104, 995, 32767, 45636, 995, 5551, 2304, 4117, 5551, 2304, 4117, 38637, 1211, 5718, 104, 995, 5296, 33456, 11296, 38392, 11331, 42213, 2655, 37037, 1829, 38392, 5551, 43042, 34268, 37037, 1829, 38392, 12602, 3555, 2655, 25961, 21984, 8978, 6225, 11536, 16247, 2304, 4032, 27842, 5551, 3615, 19913, 2304, 2423, 2407, 9381, 10632, 20666, 10721, 2304, 12174, 9381, 47395, 34892, 7435, 1211, 43527, 10874, 16606], "avg_logprob": -0.09247622606546982, "compression_ratio": 1.9556962025316456, "no_speech_prob": 6.735324859619141e-06, "words": [{"start": 3601.21, "end": 3601.63, "word": "من", "probability": 0.83740234375}, {"start": 3601.63, "end": 3602.15, "word": " أحق", "probability": 0.9737955729166666}, {"start": 3602.15, "end": 3602.59, "word": " 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أبوي يبكيان نعم من أجل أن يجاهد في سبيل الله فقال عد إليهما وأضحك هما كما أبكيتهما", "tokens": [27842, 45595, 27842, 6156, 2288, 5016, 995, 47524, 2288, 13063, 995, 7251, 16572, 3215, 14739, 7251, 7435, 40294, 3215, 8978, 8608, 21292, 1211, 21984, 35186, 12602, 3794, 12610, 21984, 6055, 31747, 2655, 5551, 3555, 45865, 7251, 3555, 4117, 1829, 7649, 8717, 25957, 9154, 5551, 7435, 1211, 14739, 7251, 7435, 40294, 3215, 8978, 8608, 21292, 1211, 21984, 6156, 4587, 6027, 6225, 3215, 11933, 20292, 3224, 15042, 36725, 11242, 5016, 4117, 8032, 15042, 9122, 15042, 5551, 3555, 4117, 36081, 3224, 15042], "avg_logprob": -0.12138672163709999, "compression_ratio": 1.8732394366197183, "no_speech_prob": 1.2814998626708984e-05, "words": [{"start": 3626.82, "end": 3627.08, "word": "من", "probability": 0.720703125}, {"start": 3627.08, "end": 3627.6, "word": " اليمن", "probability": 0.871826171875}, {"start": 3627.6, "end": 3628.2, "word": " فرحا", "probability": 0.906982421875}, {"start": 3628.2, "end": 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ما زلنا مع الفصل الرابع من فصول + +7 +00:00:31,280 --> 00:00:35,220 +مساق النظام الإسلامية وهو بعنوان نظام الأسرة في + +8 +00:00:35,220 --> 00:00:41,580 +الإسلام ونكمل اليوم الحقوق الزوجية وقد انتهينا من + +9 +00:00:41,580 --> 00:00:47,940 +حقوق الزوج ووصلنا بإذنه تعالى إلى حقوق + +10 +00:00:47,940 --> 00:00:56,160 +الزوجة ونتكلم أيضا عن الحقوق المشتركة بين الزوجين + +11 +00:00:56,160 --> 00:01:06,700 +نقول وبالله التوفيق لقد مر بنا لقد مر بنا حق الزوج + +12 +00:01:07,680 --> 00:01:16,640 +على زوجته ابتداءً بالطاعة ومرورًا بالأمانة وحسن + +13 +00:01:16,640 --> 00:01:24,640 +العشرة والتقديم والإنفاق هذه خمسة هي حقوق الزوج +14 +00:01:24,640 --> 00:01:30,320 +أرجو أن تحفظها لأنه قد يأتيكم أسئلة في الامتحانات + +15 +00:01:30,320 --> 00:01:37,560 +هذا من حقوق الزوج وهذا من حقوق الزوجة وهذا من + +16 +00:01:37,560 --> 00:01:42,280 +الحقوق المشتركة فلابد من التفريق بين حقوق الزوج + +17 +00:01:42,280 --> 00:01:49,800 +الخمسة على حدة وحقوق الزوجة الأربعة على حدة + +18 +00:01:49,800 --> 00:01:56,000 +والحقوق المشتركة الأربعة أيضا على حدة حتى لا يختلط + +19 +00:01:56,000 --> 00:02:04,370 +الأمر عليكم في الامتحان أما حقوق الزوجة على زوجها و + +20 +00:02:04,370 --> 00:02:12,630 +هو القسم الثاني من الحقوق فبدأ بحسن المعاشرة وأنا + +21 +00:02:12,630 --> 00:02:24,030 +أقول قبل أن أبدأ بأن هذا يحتاج إلى ترتيب فقد مر بنا + +22 +00:02:24,030 --> 00:02:33,460 +أن حسن المعاشرة وهو الحق الثالث بعد الطاعة والأمانة + +23 +00:02:33,460 --> 00:02:40,380 +من حقوق الزوج على زوجته والحق الأول من حقوق الزوجة + +24 +00:02:40,380 --> 00:02:46,200 +على زوجها هو حسن المعاشرة فلو كنت مستشارًا في هذا + +25 +00:02:46,200 --> 00:02:56,260 +الترتيب لقلت بأن حسن المعاشرة يجب + +26 +00:02:56,260 --> 00:03:04,950 +أن يكون من الحقوق المشتركة بين الزوجين لأنه إذا + +27 +00:03:04,950 --> 00:03:13,730 +كانت الزوجة مطالبة بأن تحسن عشرة زوجها فالزوج كذلك + +28 +00:03:13,730 --> 00:03:21,150 +بالمثل مطالب بأن يحسن عشرة زوجته وقد قال الله + +29 +00:03:21,150 --> 00:03:25,430 +تعالى وعاشروهن بالمعروف + +30 +00:03:28,840 --> 00:03:34,260 +فحسن المعاشرة أرجو أن يكون في طبعة قادمة من الحقوق + +31 +00:03:34,260 --> 00:03:39,320 +المشتركة بين الزوجين لأنه لو جاء مثلاً سؤال في + +32 +00:03:39,320 --> 00:03:48,280 +الامتحان حقوق الزوج حسن المعاشرة فقد يكون أيضًا من + +33 +00:03:48,280 --> 00:03:56,080 +حقوق الزوجة لأنه قد جاء مكررًا مرة من حقوق الزوج وهو + +34 +00:03:56,080 --> 00:04:01,520 +الحق الثالث وفق ترتيب الكتاب والحق الأول من حقوق + +35 +00:04:01,520 --> 00:04:07,080 +الزوجة على زوجها كما نراه في الكتاب ولذلك إذا ما + +36 +00:04:07,080 --> 00:04:15,600 +جاء سؤال حسن المعاشرة من حقوق الزوج الزوجة الزوج + +37 +00:04:15,600 --> 00:04:23,720 +والزوجة لا شيء مما سبق أو كل ما سبق فيكون الجواب + +38 +00:04:23,720 --> 00:04:32,420 +الثالث جيم هو الجواب الصحيح لأن حسن المعاشرة من + +39 +00:04:32,420 --> 00:04:38,900 +حقوق الزوجين معًا فهو من حق الزوج على + +40 +00:04:38,900 --> 00:04:47,400 +زوجته ومن حق الزوجة على زوجها وحسن المعاشرة + +41 +00:04:47,400 --> 00:04:55,420 +بالنسبة إلى الزوجة يكون باللين والرفق في المعاملة + +42 +00:04:55,420 --> 00:05:04,920 +وأن يؤدي حقها من المهر والنفقة وأن يبتسم في وجهها + +43 +00:05:04,920 --> 00:05:13,150 +وألا يعبس بدون ذنب والأهم من هذا كما قال هنا في + +44 +00:05:13,150 --> 00:05:19,290 +الكتاب وهو ما نقل عن السلف الصالح أن يتجمل لها كما + +45 +00:05:19,290 --> 00:05:27,250 +تتجمل له وهذه نقطة لابد أن نقف عندها قليلاً وقد قال + +46 +00:05:27,250 --> 00:05:34,490 +أحد السلف إني لأتزين لامرأتي كما تتزين لي فالزوج + +47 +00:05:34,490 --> 00:05:45,890 +له زينة من النظافة والطهارة والغسل وإزالة العرق حتى + +48 +00:05:45,890 --> 00:05:53,150 +لو كان في شعره شيب له أن يصبغ إن كان صغيرًا صبغ + +49 +00:05:53,150 --> 00:05:58,070 +باللون الأسود لأنه لا يتعارض مع الفطرة وإن كان + +50 +00:05:58,070 --> 00:06:04,890 +كبيرًا صبغ باللون الأحمر كما ورد لما أسلم أبو قحافة + +51 +00:06:05,650 --> 00:06:10,410 +والد أبي بكر الصديق رضي الله عنهما وجاء به إلى + +52 +00:06:10,410 --> 00:06:17,510 +الرسول صلى الله عليه وسلم وكان شعره قد شاب وبيضّ + +53 +00:06:17,510 --> 00:06:26,270 +فكره الرسول منه ذلك فقال غيروا هذا واجتنبوه السواد + +54 +00:06:26,270 --> 00:06:34,820 +لماذا قال هنا واجتنبوه السواد لأن السواد لا يتناسب مع + +55 +00:06:34,820 --> 00:06:43,320 +سن أبي قحافة لأنه كان شيخًا عجوزًا قد طعن في السن + +56 +00:06:43,320 --> 00:06:51,180 +شاب شعره وبيّض ظهره وبلغ من الكبر عتيه أما إذا + +57 +00:06:51,180 --> 00:06:57,880 +كان أو كانت هي صغيرة أو كانت صغيرة مثلاً فلها أن + +58 +00:06:57,880 --> 00:07:03,460 +تصبغ باللون الأسود وذلك ليس مكروهًا إن شاء الله + +59 +00:07:03,460 --> 00:07:09,560 +لأنه لا يغير الفطرة لأن الصغير شعره أسود وهذا + +60 +00:07:09,560 --> 00:07:17,100 +الشيب قد يكون له أسباب أهمها الوراثة قد يشيب شعر + +61 +00:07:17,100 --> 00:07:25,400 +الصغير لسبب الوراثة وهنا يؤخر زواج البنت فلا مانع + +62 +00:07:25,400 --> 00:07:32,430 +من الصبغة باللون الأسود نعم حتى تكون جميلة أمام + +63 +00:07:32,430 --> 00:07:42,210 +خاطبها أو أمام زوجها نعم وقد يكون بسبب مرض يصيب + +64 +00:07:42,210 --> 00:07:50,370 +بصيلات الشعر فتضعف فتذهب الصبغة التي تلون الشعر + +65 +00:07:50,370 --> 00:07:57,240 +وقد يكون أحيانًا حالة نفسية فيتحول الشعر من اللون + +66 +00:07:57,240 --> 00:08:00,700 +الأسود إلى اللون الأبيض وهذا ما ذكره الله في + +67 +00:08:00,700 --> 00:08:04,520 +القرآن الكريم عن يوم القيامة حيث الخوف والفزع + +68 +00:08:04,520 --> 00:08:12,000 +والرعب يومًا يجعل الولدان شيبًا أردت أن أقول بأن + +69 +00:08:12,000 --> 00:08:19,270 +الزينة محمودة هنا من قبل الزوج لزوجته ومن قبل + +70 +00:08:19,270 --> 00:08:25,130 +الزوجة لزوجها فكما قلنا قد يشتركان في النظافة و + +71 +00:08:25,130 --> 00:08:36,890 +الطهارة وإزالة العرق وهناك زينة خاصة بالمرأة وأريد + +72 +00:08:36,890 --> 00:08:43,550 +أن أقول بأن المرأة تكره من الرجل ما يكره + +73 +00:08:43,550 --> 00:08:53,110 +الرجل من المرأة فإذا كانت المرأة تكره الشيبة في + +74 +00:08:53,110 --> 00:09:00,430 +الرجل فإن الرجل أيضًا يكره الشيبة من المرأة وقد ورد + +75 +00:09:00,430 --> 00:09:08,410 +في قصص العرب أن رجلًا كبيرًا أراد أن يخطب امرأة وكان + +76 +00:09:08,410 --> 00:09:14,570 +قد شاب شعره نعم وصار أبيض + +77 +00:09:16,700 --> 00:09:24,220 +فسألها هل شاب شعرك أم لا؟ فقالت له نعم طبعًا لم + +78 +00:09:24,220 --> 00:09:30,960 +تصدقه القول لم تكن المرأة قد شابت لأن شعرها كان + +79 +00:09:30,960 --> 00:09:40,120 +أسود كالليل البهيم وكانوا يمدحون الشعر الأسود بأنه + +80 +00:09:40,120 --> 00:09:49,670 +كجناحي الغراب تشبيهًا باللون الأسود شديد السواد + +81 +00:09:49,670 --> 00:09:57,670 + فانصرف عنها لما علم أنها قد شابت ثم قالت له يا رجل + +82 +00:09:57,670 --> 00:10:04,630 +والله ما شاب شعري ولكن شاب شعرك أنت وأردت أن أقول + +83 +00:10:04,630 --> 00:10:10,490 +لك بأن المرأة تكره من الرجل ما يكره الرجل من + +84 +00:10:10,490 --> 00:10:19,830 +المرأة إذاً في الكتاب عبارة نعم جميلة وهو أن يتجمل + +85 +00:10:19,830 --> 00:10:26,850 +لها كما تتجمل له وهناك زينة مشتركة ولكل زينة + +86 +00:10:26,850 --> 00:10:34,930 +خاصة وأن يصبر على أذاها وهذا أمر مستحب فهو من + +87 +00:10:34,930 --> 00:10:47,370 +حسن المعاشرة وقد قال ﷺ لا يفرك مؤمن مؤمنة بمعنى لا + +88 +00:10:47,370 --> 00:10:58,370 +يكره يفرك بمعنى يكره لا يفرك مؤمن مؤمنة إن كره + +89 +00:10:58,370 --> 00:11:08,110 +منها خلقًا راضي غيره وهذا كلام في غاية الدقة + +90 +00:11:10,240 --> 00:11:14,260 +والرسول عليه الصلاة والسلام لا ينطق عن الهوى صلى + +91 +00:11:14,260 --> 00:11:20,380 +الله عليه وسلم فالمرأة ليست ملكًا يمشي على الأرض + +92 +00:11:20,380 --> 00:11:27,240 +والمرأة ليست نبياً معصومًا فالمرأة كرجل تمامًا تخطئ + +93 +00:11:27,240 --> 00:11:33,540 +وتصيب والرسول عليه الصلاة والسلام قال كل بني آدم + +94 +00:11:33,540 --> 00:11:39,340 +خطاء وخير الخطائين التوابون نعم + +95 +00:11:41,240 --> 00:11:47,020 +فعلى الزوج إذا ما أخطأت زوجته ألا يتعرض إلى الطلاق + +96 +00:11:47,020 --> 00:11:51,420 +وسنأتي بعد هذه المحاضرة إن شاء الله إلى باب + +97 +00:11:51,420 --> 00:12:00,780 +الطلاق ومعرفة أحكامه قلت ألا يتعجل عند أخطائها + +98 +00:12:00,780 --> 00:12:10,550 +بالطلاق لأن الطلاق جده جد وهزله جد كما جاء في بعض + +99 +00:12:10,550 --> 00:12:15,630 +الآثار عند رسول الله صلى الله عليه وسلم بل أن يصبر + +100 +00:12:15,630 --> 00:12:25,130 +وأن يتحمل فالمرأة تخطئ كما أن الرجل يخطئ وكل بني + +101 +00:12:25,130 --> 00:12:33,070 +آدم خطاء وليس العيب في الخطأ إنما العيب هو الإصرار + +102 +00:12:33,070 --> 00:12:39,690 +على هذا الخطأ ولذلك قال هنا صلى الله عليه وسلم + +103 +00:12:39,690 --> 00:12:48,110 +ناصحًا الأزواج أن يصبرّوا على أذى زوجاتهم لا يفرق + +104 +00:12:48,110 --> 00:12:54,670 +مؤمن مؤمنة لا يكره ولا يبغض مؤمن مؤمنة إن كره منها + +105 +00:12:54,670 --> 00:13:04,640 +خلقًا راضي غيره فعلى الإنسان أن ينظر إلى الحسنات وأن + +106 +00:13:04,640 --> 00:13:11,600 +لا يقتصر على السيئات كما جاء في بعض الآثار يرى + +107 +00:13:11,600 --> 00:13:17,140 +أحدكم القذة في عين أخيه كناية عن الذنب الصغير + +108 +00:13:18,410 --> 00:13:23,710 +والخطأ القليل ولا يرى الجذع في عينه والجذع يقصد + +109 +00:13:23,710 --> 00:13:31,450 +به في لغة العرب عن كثرة العيوب والنقائص فلا تخلو + +110 +00:13:31,450 --> 00:13:37,490 +من عيب ولا تخلو من نقص وكذلك المرأة في الإسلام + +111 +00:13:37,490 --> 00:13:45,370 +ليست ملكًا أو نبياً معصومًا كما أسلفنا نأتي ثانيًا إلى + +112 +00:13:45,370 --> 00:13:52,610 +العدل العدل أيضًا من حقوق الزوجة على زوجها والبعض + +113 +00:13:52,610 --> 00:13:58,410 +هنا يخطئ عندما يظن أن العدل لا يكون إلا مع الزوجات + +114 +00:13:58,410 --> 00:14:07,250 +وعند تعدد الزوجات نقول بأن العدل يكون مع الزوجة + +115 +00:14:07,250 --> 00:14:14,120 +الواحدة أيضًا كما يكون مع تعدد الزوجات كيف يكون + +116 +00:14:14,120 --> 00:14:21,320 +العدل مع الزوجة الواحدة بأن يطعمها مما يطعم وأن + +117 +00:14:21,320 --> 00:14:33,040 +يكسوها مما يلبس وأن يسكنها السكن اللائق بها نعم + +118 +00:14:33,040 --> 00:14:39,580 +هذا معنى حديث رسول الله صلى الله عليه وسلم أن + +119 +00:14:39,580 --> 00:14:48,660 +يطعمها مما يطعم أن تأكل من نفس طعامه لا أن يأكل في + +120 +00:14:48,660 --> 00:14:57,200 +الأسواق أشهى الطعام والشراب ثم يأتيها في آخر + +121 +00:14:57,200 --> 00:15:04,850 +النهار بالخشن من الطعام وأن يلبسها أو يكسوها مما + +122 +00:15:04,850 --> 00:15:11,530 +يلبس حتى وإن كان يلبس العتيق المستعمل فهذا ليس + +123 +00:15:11,530 --> 00:15:17,750 +عيبًا المهم أن يكون طاهرًا وأن يكون نظيفًا حتى ولو + +124 +00:15:17,750 --> 00:15:25,220 +كان عتيقًا أو مستعملًا وأن يسكنها السكن اللائق بها وهذا + +125 +00:15:25,220 --> 00:15:30,380 +سنأتي إليه عند الحديث عن النفقة فإن النفقة + +126 +00:15:30,380 --> 00:15:38,340 +تُعنى المسكن والمأكل والملبس وسنزيد أيضًا + +127 +00:15:38,340 --> 00:15:47,520 +التعليم والتطبيب فالتطبيب والتعليم أيضًا من حقوق + +128 +00:15:47,520 --> 00:15:55,300 +الزوجة على زوجها ومن حقوق الولد على أبيه وسنأتي + +129 +00:15:55,300 --> 00:16:02,500 +إليه إن شاء الله أما المشكلة الأهم والمشكلة الأخطر + +130 +00:16:02,500 --> 00:16:09,440 +كيف يكون العدل مع الزوجات وهنا + +131 +00:16:10,480 --> 00:16:14,920 +لابد أن نقف قليلًا عند هذا الباب لأنه من المواضيع + +132 +00:16:14,920 --> 00:16:23,740 +المهمة في الإسلام فهناك أمور ظاهرة مثل النفقة كما + +133 +00:16:23,740 --> 00:16:30,720 +أسلفنا والمبيت وهناك أمور باطنة مثل المحبة + +134 +00:16:30,720 --> 00:16:39,790 +القلبية فما هو المطلوب هنا المطلوب كما أخبر + +135 +00:16:39,790 --> 00:16:44,890 +القرآن الكريم وكما أخبر النبي المعصوم الذي لا ينطق + +136 +00:16:44,890 --> 00:16:51,230 +عن الهوى صلى الله عليه وسلم أن الواجب على الزوج هو + +137 +00:16:51,230 --> 00:16:58,190 +العدل في الأمور الظاهرة كالنفقة والمبيت وقد تكلمنا + +138 +00:16:58,190 --> 00:17:05,150 +قليلًا عن النفقة من مسكن ومطعم وملبس + +139 +00:17:06,250 --> 00:17:13,430 +هذه أمور لابد أن يشترك بها جميع الزوجات فلا يفرق + +140 +00:17:13,430 --> 00:17:19,590 +بين امرأة وأخرى وكذلك المبيت أن يبيت عند هذه مثلاً + +141 +00:17:19,590 --> 00:17:25,010 +ليلة وعند هذه ليلة أو أن يبيت عند هذه ليلتين وعند + +142 +00:17:25,010 --> 00:17:37,170 +تلك ليلتين حسب الاتفاق بينهما هذا عدل فرض واجب كوجب + +143 +00:17:37,170 --> 00:17:43,750 +أركان الإسلام من صوم وصلاة وحج وذاكر **ة** والزوج آثم + +144 +00:17:43,750 --> 00:17:51,810 +إن لم يعدل بين الزوجات في الأمور الظاهرة أو الأمور + +145 +00:17:51,810 --> 00:17:58,910 +المادية المقدورة عليه وهذه لا عُذْر لأحد أبدا فيها + +146 +00:17:58,910 --> 00:18:07,710 +النفقة والمبيت وهذا والله تعالى أعلى وأعلم معنى + +147 +00:18:07,710 --> 00:18:14,950 +قوله تبارك وتعالى فإن خفتم ألا تعدلوا فواحدة + +148 +00:18:14,950 --> 00:18:21,950 +والمقصود بالعدل هنا هو العدل الظاهر العدل المادي + +149 +00:18:21,950 --> 00:18:27,170 +المقدور عليه من النفقة والمبيت والرسول عليه الصلاة + +150 +00:18:27,170 --> 00:18:36,870 +والسلام كان يفعل ذلك مع أزواجه حتى إنه لما ترك أم + +151 +00:18:36,870 --> 00:18:44,750 +سلمة استشارها في ذلك فأذنت له أن يبيت ليلتها عند + +152 +00:18:44,750 --> 00:18:52,950 +عائشة لأن المبيت حق لها فتنازلت أم سلمة برضاها + +153 +00:18:52,950 --> 00:19:00,810 +ومحض اختيارها عن ليلتها إلى عائشة على أن لا يطلقها + +154 +00:19:01,640 --> 00:19:09,240 +وتبعث يوم القيامة زوجة للرسول في الجنة لأن أزواج + +155 +00:19:09,240 --> 00:19:15,100 +النبي في الدنيا أزواج النبي في الجنة صلى الله عليه + +156 +00:19:15,100 --> 00:19:24,060 +وسلم ورضي الله عن أزواج النبي أجمعين نأتي إلى + +157 +00:19:24,060 --> 00:19:33,470 +العدل الباطن وهو الميل القلبي هذا ليس فرضًا ولا + +158 +00:19:33,470 --> 00:19:41,970 +واجبًا لأن القلب بين أصبعين من أصابع الرحمن يقلبها + +159 +00:19:41,970 --> 00:19:48,950 +كيف شاء وعند قوله تبارك وتعالى في صورة الأنفال + +160 +00:19:48,950 --> 00:19:55,610 +واعلموا أن الله يحول بين المرء وقلبه قال ابن كثير + +161 +00:19:55,610 --> 00:20:00,580 +يحول بمعنى يفصل وكان النبي عليه الصلاة والسلام + +162 +00:20:00,580 --> 00:20:07,260 +عندما يقرأ هذه الآية يكثر من دعاء يا مقلب القلوب + +163 +00:20:07,260 --> 00:20:15,180 +والأبصار ثبت قلبي على دينك ولذلك صُمُّ القلب قلبًا + +164 +00:20:15,180 --> 00:20:23,100 +لأنه لا يثبت على حال فصرعان ما يتقلبوا وقد قال + +165 +00:20:23,100 --> 00:20:30,520 +الشاعر العربي يومًا سمي القلب إلا من تقلبه فاحذر على + +166 +00:20:30,520 --> 00:20:40,760 +القلب من قلب وتحويله نعم هذا هو حقيقة القلب فقد + +167 +00:20:40,760 --> 00:20:49,480 +يميل الزوج إلى بعض نسائه بقلبه وهذا + +168 +00:20:49,480 --> 00:20:56,430 +لا يحاسب عليه الإنسان ولا يأثم فيه إن شاء الله لكن + +169 +00:20:56,430 --> 00:21:02,050 +عليه أن يتقي الله واتقوا الله ما استطعتم كما قال + +170 +00:21:02,050 --> 00:21:07,430 +هنا فلا تميلوا كل الميل لأن ميل القلب إلى واحدة + +171 +00:21:07,430 --> 00:21:15,970 +منهم لا يعني أن يهجر الثانية أو بقية الزوجات إن + +172 +00:21:15,970 --> 00:21:21,470 +كان متزوجا بأكثر من واحدة وهذا والله أعلى وأعلم + +173 +00:21:22,130 --> 00:21:27,790 +معنى قوله تبارك وتعالى ولن تستطيعوا أن تعدلوا بين + +174 +00:21:27,790 --> 00:21:34,390 +النساء ولو حرصتم فلا تميلوا كل الميـل وهنا يأتي + +175 +00:21:34,390 --> 00:21:40,110 +أعداء الإسلام من العلمانيين والشيوعيين + +176 +00:21:40,110 --> 00:21:45,970 +والمستشريقين ويقول بأن في القرآن التناقضا كيف يقول + +177 +00:21:45,970 --> 00:21:51,360 +الله تبارك وتعالى في الآية فإن خفتم أن لا تعدلوا + +178 +00:21:51,360 --> 00:21:56,300 +فواحدة ويقول في الآية الأخرى ولن تستطيعوا أن + +179 +00:21:56,300 --> 00:22:02,540 +تعدلوا بين النساء ولو حرصتم نقول لا تعارض البتة + +180 +00:22:02,540 --> 00:22:09,340 +لأن الكلام هو كلام الله سبحانه وتعالى فالآية + +181 +00:22:09,340 --> 00:22:15,200 +السابقة فإن خفتم أن لا تعدلوا فواحدة إنما تعني + +182 +00:22:15,200 --> 00:22:21,390 +العدل في الأمور الظاهرة كما أسلفنا يعني في الأمور + +183 +00:22:21,390 --> 00:22:31,410 +المادية المقدور عليها أما الآية الأخرى ولن + +184 +00:22:31,410 --> 00:22:37,510 +تستطيعوا أن تعدلوا فهي في الأمور القلبية الأمور + +185 +00:22:37,510 --> 00:22:45,370 +الباطنة التي لا يقدر عليها إلا الله لأن الشخص قد + +186 +00:22:45,370 --> 00:22:52,650 +يميل وأقوله بأن الميل هنا قد لا يكون بسبب جمال + +187 +00:22:52,650 --> 00:22:59,550 +الزوجة كما يظن البعض وأنا قد قرأتُه في بعض الكتب حتى + +188 +00:22:59,550 --> 00:23:05,530 +عند غير المسلمين بأن بعض الملوك كان يميلوا إلى + +189 +00:23:05,530 --> 00:23:14,730 +زوجة صمراء وفرعية من هم أجمل منها بسبب حسن + +190 +00:23:14,730 --> 00:23:23,130 +المعاشرة الذي سبق الحديث عنه فعظوبته اللسان + +191 +00:23:23,130 --> 00:23:26,430 +وابتسامته + +192 +00:23:26,430 --> 00:23:37,430 +نعم فهذا كله من إعداد الطعام وإعداد الحمام إذا كان + +193 +00:23:37,430 --> 00:23:48,340 +قد عاد تعبا مرحقا فلا تقابله بتجهم أو بقلة النفقة + +194 +00:23:48,340 --> 00:23:56,600 +والمصاريف ورسوم المدارس والجامعات وفطورة الماء + +195 +00:23:56,600 --> 00:24:05,440 +والكهرباء إلى غير ذلك نعم إذا هذا يرجع إلى حصن + +196 +00:24:05,440 --> 00:24:12,260 +معاشرة الزوجة لزوجها وأقول أيضا قد يميل الرجل إلى + +197 +00:24:12,260 --> 00:24:22,880 +زوجة أقل جمالا من أختها ودعوني ألا أقول ضرتها لأن + +198 +00:24:22,880 --> 00:24:28,840 +العوام يقولون ضرة وأنا لا أقول هذا إن شاء الله و + +199 +00:24:28,840 --> 00:24:37,300 +لكن كما جاء في بعض الحديث أختها نعم وقد تكون أقل + +200 +00:24:37,300 --> 00:24:46,970 +جمالا منها فيؤثرها على الأكثر جمالا نعم إذا هنا لا + +201 +00:24:46,970 --> 00:24:53,770 +عتبة على الزوج والنبي عليه الصلاة والسلام قد صرح + +202 +00:24:53,770 --> 00:25:02,770 +بذلك عندما قال اللهم هذا قسمي فيما أملك فلا تلومني + +203 +00:25:02,770 --> 00:25:10,570 +فيما أملك ولا أملك وهو القلب أو الحب والمودة + +204 +00:25:12,340 --> 00:25:19,120 +فالنبي عليه الصلاة والسلام كان يصرح بحب عائشة رضي + +205 +00:25:19,120 --> 00:25:25,220 +الله عنها كما جاء في الحديث الصحيحة **الصحيحة** لعلها في + +206 +00:25:25,220 --> 00:25:29,340 +البخاري عندما سؤل عليه الصلاة والسلام عن أحب الناس + +207 +00:25:29,340 --> 00:25:35,760 +إليه فقال أبو بكرن فقال لا نسألك عن الرجال من + +208 +00:25:35,760 --> 00:25:43,480 +النساء قال عائشة فعائشة الصديقة بنت الصديق كانت + +209 +00:25:43,480 --> 00:25:50,860 +أحب النساء إليه وهذا هو معنى قوله اللهم إن هذا + +210 +00:25:50,860 --> 00:25:58,060 +قسمي وقسمي بمعنى + +211 +00:25:58,060 --> 00:26:06,620 +العدل بين الزوجات وليس قسمي لأن القسم بفتح القاف + +212 +00:26:06,620 --> 00:26:15,270 +هو اليمين والجمع أقسام أما القسم هو العدل بين + +213 +00:26:15,270 --> 00:26:23,410 +الزوجات إذا لابد أن نقف هنا وانتبهوا لأن هذا قد + +214 +00:26:23,410 --> 00:26:30,210 +يأتيكم في الامتحانات صح أو خطأ أو اختيار متعدد إذا + +215 +00:26:30,210 --> 00:26:37,400 +الواجب هو العدل في الأمور الظاهرة المادية المقدور + +216 +00:26:37,400 --> 00:26:43,660 +عليها مثل النفقة والمبيت وهذا معنى الآية الكريمة + +217 +00:26:43,660 --> 00:26:52,300 +فإن خبتم ألا تعدلوا فواحدة وكذلك ليس مطلوبا العدل + +218 +00:26:52,300 --> 00:26:57,120 +أو ليس واجبا أو فرضا العدل في الأمور الباطنة + +219 +00:26:57,120 --> 00:27:05,050 +القلبية كالحب والمودة وهذا معنى الآية الأخرى ولن + +220 +00:27:05,050 --> 00:27:10,410 +تستطيعوا أن تعدلوا بين النساء ولو حرصتم ولن + +221 +00:27:10,410 --> 00:27:17,590 +تفيدوا الحاضر والمستقبل لم يقل لم لأنه لو قال + +222 +00:27:17,590 --> 00:27:27,360 +لم محتمل أن يكون ذلك في المستقبل ولكن **هُوَ** لا في + +223 +00:27:27,360 --> 00:27:33,380 +الحاضر ولا في المستقبل فاتقوا الله ولا تميلوا كل + +224 +00:27:33,380 --> 00:27:39,640 +الميل بمعنى إذا ميلتم إلى واحدة منهم فلا تهجروا + +225 +00:27:39,640 --> 00:27:44,440 +الباقيات وهذا ما أكده الرسول عليه الصلاة والسلام + +226 +00:27:44,440 --> 00:27:50,620 +في حديثه اللهم هذا قسمي فيما أملك وهو المبيت + +227 +00:27:50,620 --> 00:27:58,070 +والنفقة فلا تلومني يا رب في ما أملك وهو القلب ولا + +228 +00:27:58,070 --> 00:28:04,810 +أملك أي في الحب والمودة ثالثا من حقوق الزوجة على + +229 +00:28:04,810 --> 00:28:15,480 +زوجها المهر وهذا عرضون محبة كما يقولون وهو واجب على + +230 +00:28:15,480 --> 00:28:21,560 +الزوج وحق من حقوق الزوجة على زوجها قال الله تبارك + +231 +00:28:21,560 --> 00:28:29,440 +وتعالى وآتوا النساء صدقاتهن نحلة صدقات جمع **صدقة** + +232 +00:28:29,440 --> 00:28:37,670 +جمع صدقة عفوا **بضم الدال** صدقة بمعنى المهر + +233 +00:28:37,670 --> 00:28:46,970 +والجمع صدقات أما صدقة بفتح الدال فمعناه **الصدقة** منه + +234 +00:28:46,970 --> 00:28:52,590 +قوله تبارك وتعالى في صورة التوبة إنما الصدقات + +235 +00:28:52,590 --> 00:28:59,570 +للفقراء والمساكين فالصدقات جمع صدقة والصدقات + +236 +00:28:59,570 --> 00:29:06,290 +جمع صدقة بمعنى المهر وآتوا النساء صدقاتهن نحلة + +237 +00:29:06,290 --> 00:29:15,900 +نحلة بمعنى هبة أو عطية أو منحة فإن طبنا لكم عن شيء + +238 +00:29:15,900 --> 00:29:25,800 +منه نفسا فكلوه هنيئا مريئا نعم وهذا لفتة إلى بعض + +239 +00:29:25,800 --> 00:29:31,400 +الإخوة أو بعض الآباء الذين يأخذون شيئا من مهور + +240 +00:29:31,400 --> 00:29:41,480 +أخواتهم أو بناتهم فهذا لا يحل شرعا إن المهر ملك + +241 +00:29:41,480 --> 00:29:49,860 +للزوجة ولها أن تتنازل عن شيء منه لزوجها مثلا أو + +242 +00:29:49,860 --> 00:29:58,840 + لأخيها أو ابنها أو أبيها وآتوا النساء صدقاتهن نحلة + +243 +00:29:58,840 --> 00:30:08,820 +فإن طبن لكم منه شيئا فكلوه هنيئا مريئا فهو أحل + +244 +00:30:08,820 --> 00:30:16,520 +الحلال كما قالوا أحل الحلال ثلاثة أولها مهر + +245 +00:30:16,520 --> 00:30:22,960 +الزوجة إن كان عن طيب منها وثانيا الميراث أيضا + +246 +00:30:22,960 --> 00:30:30,720 +أحل الحلال وثالثا مال الغنيمة نعم فكلوا مما غنمتم + +247 +00:30:30,720 --> 00:30:41,340 +حلالا طيبا وقد ذهب جمهور الفقهاء إلى أنه لا حد + +248 +00:30:41,340 --> 00:30:48,880 + لأكثر المهر حتى ولو وصل إلى قنطار كما قال الله + +249 +00:30:48,880 --> 00:30:55,540 +تبارك وتعالى وإن أردتم استبدال زوج مكان زوج وآتيتم + +250 +00:30:55,540 --> 00:31:02,080 +إحداهن قنطارا فلا تأخذوا منه شيئا أتأخذونه بهتانا + +251 +00:31:02,080 --> 00:31:11,620 +وإثما مبينا لا حد لأكثره وأيضا + +252 +00:31:12,430 --> 00:31:22,010 +لا حد لقليله فإن المهر قد يصل إلى خاتم من حديد + +253 +00:31:22,010 --> 00:31:30,870 +كما جاء في بعض الآثار التمث **الآثار** ولو كان خاتما من حديد + +254 +00:31:30,870 --> 00:31:39,270 +ولو كان خاتما من حديد ومعنى الحديث ولو كان + +255 +00:31:39,270 --> 00:31:45,450 +ملتمسك خاتما من حديد فخاتم **الخبر** كان + +256 +00:31:45,450 --> 00:31:52,090 +المحذوفة واسمها التمس ولو خاتم يعني ولو كان مهرك + +257 +00:31:52,090 --> 00:32:02,090 +خاتم أو ملتمسك خاتم من حديد وقد يكون المهر صورا أو + +258 +00:32:02,090 --> 00:32:08,900 +حتى آيات من القرآن الكريم وهذه بشارة لأبنائنا الذين + +259 +00:32:08,900 --> 00:32:15,220 +يحفظون القرآن الكريم بأن القرآن الكريم يكون مهرا + +260 +00:32:15,220 --> 00:32:23,040 +بل أعظم المهر كما جاء في الأحاديث الصحيحة **الصحيحة** عندما + +261 +00:32:23,040 --> 00:32:26,940 +جاءت امرأة تعرض نفسها على الرسول عليه الصلاة + +262 +00:32:26,940 --> 00:32:34,260 +والسلام وكأنه لم يكن بحاجة إليها فقال أحد الصحابة + +263 +00:32:34,260 --> 00:32:39,820 +زوجني إياها يا رسول الله ولا يملك شيئا فقال له هل + +264 +00:32:39,820 --> 00:32:43,280 +تحفظ شيئا من القرآن قال كذا وكذا يا رسول الله قال + +265 +00:32:43,280 --> 00:32:50,920 +حفظهم إياها فذاك مهرها نعم ولا نحتكر ذلك فإن أعظم + +266 +00:32:50,920 --> 00:33:00,880 +المهور هو كلام الله سبحانه وتعالى هذا هو الحق + +267 +00:33:00,880 --> 00:33:07,960 +الثالث من حقوق الزوجة على زوجها ألا وهو المهر وأما + +268 +00:33:07,960 --> 00:33:14,920 +النفقة فهي أيضا من حق الزوجة على زوجها وسوف نستدل + +269 +00:33:14,920 --> 00:33:19,340 +على ذلك من القرآن ومن السنة فمن القرآن الآية + +270 +00:33:19,340 --> 00:33:25,120 +السابقة في المحاضرة السابقة عندما تكلمنا عن الطاعة + +271 +00:33:25,120 --> 00:33:31,880 +كحق من حقوق الزوج على زوجته وهذه الآية هي قوله + +272 +00:33:31,880 --> 00:33:38,200 +تبارك وتعالى الرجال قوامون على النساء بما فضّل + +273 +00:33:38,200 --> 00:33:46,100 +الله بعضهم على بعض وبما أنفقوا من أموالهم وقوامون + +274 +00:33:46,100 --> 00:33:53,050 +من القوامة وهي حق الطاعة وللرجال عليهن درجة الطاعة + +275 +00:33:53,050 --> 00:33:58,870 +والقوامة كما سبق في الحديث وهي من حقوق الزوج على + +276 +00:33:58,870 --> 00:34:04,270 +زوجته أما نحن هنا فجئنا بالآية من أجل قوله وبما + +277 +00:34:04,270 --> 00:34:10,190 +أنفقوا من أمواله فهذا فضل الله يؤتيه من يشاء والله + +278 +00:34:10,190 --> 00:34:17,730 +واسع عليهم وتكلمنا عن النفقة أنها تشمل أولا السكن + +279 +00:34:17,730 --> 00:34:28,640 +اللائق بها نعم وأن يطعمها مما يطعم وأن يكسوها + +280 +00:34:28,640 --> 00:34:37,280 +الكسوة اللائقة بها أو أن يلبسها مما يلبس كما جاء + +281 +00:34:37,280 --> 00:34:44,880 +في الآثار ونزيد على ذلك وسنأتي إليه إن شاء الله في + +282 +00:34:44,880 --> 00:34:54,570 +موضع آخر عند التفريق بين الرجل والمرأة في الشهادة + +283 +00:34:54,570 --> 00:35:03,010 +وفي الميراث وفي رئاسة الدولة سنتكلم لماذا فرق الله + +284 +00:35:03,010 --> 00:35:06,910 +بين الرجل والمرأة في الميراث يوصيكم الله في + +285 +00:35:06,910 --> 00:35:15,170 +أولادكم للذكر مثل حظ الأنثيين وسنقول يومها بأن + +286 +00:35:15,170 --> 00:35:20,370 +الرجل مطالب بالمهر ومطالب بالنفقة وأن المرأة في + +287 +00:35:20,370 --> 00:35:27,510 +الإسلام لا تكلف بشيء فهي مكفية المؤنة إن كانت + +288 +00:35:27,510 --> 00:35:32,830 +صغيرة فعلى أبيها وإن كانت زوجة فنفقتها على زوجها + +289 +00:35:32,830 --> 00:35:38,950 +حتى ولو كانت أغنى الأغنياء وإن كانت كبيرة فنفقتها + +290 +00:35:38,950 --> 00:35:45,270 +على ولدها وثنأت أيضًا إلى أن التعليم والتطبيب + +291 +00:35:45,270 --> 00:35:52,490 +أيضًا يدخل في نفقة الزوج على أهله وعلى ولده أما من + +292 +00:35:52,490 --> 00:35:58,030 +الصناعة النبوية فالحديث الشريف إذا أنفق المسلم نفقة + +293 +00:35:58,030 --> 00:36:04,650 +على أهله وهو يحتسبها كانت له صدقة والمراد بالأهل + +294 +00:36:04,650 --> 00:36:14,370 +هنا الزوجة والولد وقيل تشمل الأرحام أيضًا من أقارب + +295 +00:36:14,370 --> 00:36:20,490 +الزوج ولعلنا قد تكلمنا عن هذا عند الحديث عن + +296 +00:36:20,490 --> 00:36:26,410 +العبادة وقلنا بأن العبادة بمعناها العام هي كل عمل + +297 +00:36:26,410 --> 00:36:35,850 +أو فعل يبتغى به وجه الله حتى نفقة الزوجة والولد + +298 +00:36:35,850 --> 00:36:41,470 +إذا كانت في سبيل الله وابتغاء مرضاة الله وهذا معنى + +299 +00:36:41,470 --> 00:36:46,730 +الحديث وهو يحتسبها كانت له صدقة والنبي عليه السلام + +300 +00:36:46,730 --> 00:36:54,770 +عندما وصل إلى قصة موسى وام موسى قال إن المؤمن الذي + +301 +00:36:54,770 --> 00:37:00,410 +يعمل العمل يبتغي به وجه الله فهو كأم موسى ترضع + +302 +00:37:00,410 --> 00:37:05,870 +ولدها وتأخذ أجرها لأن النية تجعل العمل الدنيوي + +303 +00:37:05,870 --> 00:37:17,560 +أخرويًا وأعود إلى الوسط لأنه معنى آيتان وحديث أخرت + +304 +00:37:17,560 --> 00:37:23,640 +الآية الوسطى لأنها تتكلم عن مسألة مهمة أردت ألا + +305 +00:37:23,640 --> 00:37:34,760 +أسرع فيها وهي النفقة الزوجية تكون وفق حال الزوج أم + +306 +00:37:34,760 --> 00:37:43,800 +وفق حال الزوجة الجواب أن النفقة تكون وفق حال الزوج + +307 +00:37:45,050 --> 00:37:53,750 +أو كما قال هنا على حسب قدرة الزوج من يسار وإعسار + +308 +00:37:53,750 --> 00:38:00,730 +أو من غنى وفكر وهذا معنى الآية التي أخرتها لأقف + +309 +00:38:00,730 --> 00:38:09,020 +عندها قليلا وهي في صورة الطلاق لينفق ذو سعة من + +310 +00:38:09,020 --> 00:38:15,900 +سعته ومن قدر عليه رزقه فلينفق مما آتاه الله + +311 +00:38:15,900 --> 00:38:23,040 +وبالمثال يتضح المقال لو كان الزوج غنيا وكانت + +312 +00:38:23,040 --> 00:38:32,520 +الزوجة فقيرة فإن القاضي يحكم على الزوج نفقة غني أو + +313 +00:38:32,520 --> 00:38:39,030 +نفقة يسار دون النظر إلى فقر الزوجة والعكس إذا كان + +314 +00:38:39,030 --> 00:38:46,470 +الزوج فقيرا معسرا وكانت الزوجة غنية ثرية فإن + +315 +00:38:46,470 --> 00:38:55,470 +القضاء يحكم على الزوج بنفقة فقير بنفقة معسر دون + +316 +00:38:55,470 --> 00:39:02,220 +النظر إلى حال الزوجة انتبهوا إلى هذه النقطة واقفوا + +317 +00:39:02,220 --> 00:39:08,900 +عندها قليلا وضعوا تحتها خطوطا النفقة الزوجية وفق + +318 +00:39:08,900 --> 00:39:16,600 +حال الزوج من غنى وفكر أو حسب قدرة الزوج من يسار + +319 +00:39:16,600 --> 00:39:26,280 +وإعسار لينفق ذو سعة من سعته والسعة بمعنى الغنى + +320 +00:39:26,280 --> 00:39:36,110 +وهي بالفتح وليس كما يقول الناس على الرحب والسعة هذا + +321 +00:39:36,110 --> 00:39:41,710 +خطأ الأصل أن تقول في لغة العرب على الرحب والسعة + +322 +00:39:41,710 --> 00:39:49,090 +الرحب بضم الراء لأنها بمعنى الواد الفسيح والسعة + +323 +00:39:49,090 --> 00:39:56,710 +بفتح السين بمعنى الجاه أو الغنى ومن قدر عليه رزقه + +324 +00:39:56,710 --> 00:40:02,930 +فلينفق مما آتاه الله من قدر بمعنى من ضيق عليه + +325 +00:40:02,930 --> 00:40:08,470 +رزقه وهذا هو معنى قوله تبارك وتعالى والله أعلى + +326 +00:40:08,470 --> 00:40:16,490 +وأعلم في صورة الأنبياء عند الحديث عن نبي الله يونس + +327 +00:40:16,490 --> 00:40:21,790 +عليه السلام وزنوني وذا بمعنى صاحب يعني وصاحب النون + +328 +00:40:21,790 --> 00:40:28,690 +يعني الحوت وزنوني الذهب مغاضبا فظن ألا نقدر عليه + +329 +00:40:28,690 --> 00:40:36,910 +ومعنى ألا نقدر عليه بمعنى ألا نضيق عليه إذا ومن + +330 +00:40:36,910 --> 00:40:43,310 +قدر عليه رزقه يعني ضيق عليه رزقه بفكر أو عسرفلينفق + +331 +00:40:43,310 --> 00:40:50,230 +مما آتاه الله لا يكلف الله نفسا إلا ما آتاها سيجعل + +332 +00:40:50,230 --> 00:40:59,290 +الله بعد عسر يسرا نعم وصلنا إلى القسم الثالث وهو + +333 +00:40:59,290 --> 00:41:01,510 +الحقوق المشتركة بين الزوجين diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/5kneOaWUqdM_postprocess.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/5kneOaWUqdM_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..78f6cbbd87eb41d6d121b65e14785fdcab55d95a --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/5kneOaWUqdM_postprocess.srt @@ -0,0 +1,1332 @@ +1 +00:00:05,090 --> 00:00:07,750 +أعوذ بالله السماء العليه من الشيطان الرجيم بسم + +2 +00:00:07,750 --> 00:00:11,510 +الله الرحمن الرحيم الحمد لله والصلاة والسلام على + +3 +00:00:11,510 --> 00:00:16,390 +رسول الله اللهم صلي على سيدنا محمد وعلى آله وصحبه + +4 +00:00:16,390 --> 00:00:21,390 +وسلم أجمعين عزيزي الطلاب قبل ذي بدء ورحبكم جميعا + +5 +00:00:21,390 --> 00:00:25,170 +وأحييكم بتحية الإسلام العظيم فسلام الله عليكم + +6 +00:00:25,170 --> 00:00:31,280 +ورحمته وبركته نحن ما زلنا مع الفصل الرابعيمن فصول + +7 +00:00:31,280 --> 00:00:35,220 +مساق النظام الإسلامية وهو بعنوان نظام الأسرة في + +8 +00:00:35,220 --> 00:00:41,580 +الإسلام ونكمل اليومالحقوق الزوجية وقد انتهينا من + +9 +00:00:41,580 --> 00:00:47,940 +حقوق الزوج ووصلنا بإذنه تبارك وتعالى الى حقوق + +10 +00:00:47,940 --> 00:00:56,160 +الزوجة ونتكلم ايضا عن الحقوق المشتركة بين الزوجين + +11 +00:00:56,160 --> 00:01:06,700 +نقول وبالله التوفيق لقد مر بنا لقد مر بنا حق الزوج + +12 +00:01:07,680 --> 00:01:16,640 +على زوجته بدءًا بالطاعة ومرورًا بالأمانة وحسن + +13 +00:01:16,640 --> 00:01:24,640 +العشرة والتقديم والحداد هذه خمسة هي حقوق الزوجة + +14 +00:01:24,640 --> 00:01:30,320 +أرجو أن تحفظها لأنه قد يأتيكم أسئلة في الامتحانات + +15 +00:01:30,320 --> 00:01:37,560 +هذا من حقوق الزوج وهذا من حقوق الزوجةوهذا من + +16 +00:01:37,560 --> 00:01:42,280 +الحقوق المشتركة فلابد من التفريق بين حقوق الزوج + +17 +00:01:42,280 --> 00:01:49,800 +الخمسة على حدة وحقوق الزوجة الأربعة على حدة + +18 +00:01:49,800 --> 00:01:56,000 +والحقوق المشتركة الأربعة أيضا على حدة حتى لا يختلط + +19 +00:01:56,000 --> 00:02:04,370 +الأمر عليكم في الامتحان اما حقوق الزوجة علىزوجها و + +20 +00:02:04,370 --> 00:02:12,630 +هو القسم الثاني من الحقوق فبدأ بحسن المعاشرة و أنا + +21 +00:02:12,630 --> 00:02:24,030 +أقول قبل ذي بدء بأن هذا يحتاج إلى ترتيب فقد مر بنا + +22 +00:02:24,030 --> 00:02:33,460 +أن حسن الأشرة و هو الحق الثالثبعد الطاعة والأمانة + +23 +00:02:33,460 --> 00:02:40,380 +من حقوق الزوج على زوجته والحق الأول من حقوق الزوجة + +24 +00:02:40,380 --> 00:02:46,200 +على زوجه هو حُسن الأشرة فلو كنت مستشارا في هذا + +25 +00:02:46,200 --> 00:02:56,260 +الترتيب قلت بأن حُسن الأشرة أو حُسن المعاشرة يجب + +26 +00:02:56,260 --> 00:03:04,950 +أن يكونمن الحقوق المشتركة بين الزوجين لأنه إذا + +27 +00:03:04,950 --> 00:03:13,730 +كانت الزوجة مطالبة بأن تحصن عشرة زوجها فالزوج كذلك + +28 +00:03:13,730 --> 00:03:21,150 +بالمثل مطالب بأن يحصن عشرة زوجته وقد قال الله + +29 +00:03:21,150 --> 00:03:25,430 +تعالى وعاشرهن بالمعروف + +30 +00:03:28,840 --> 00:03:34,260 +فحصن المعاشرة أرجو أن يكون في طبعة قادمة من الحقوق + +31 +00:03:34,260 --> 00:03:39,320 +المشتركة بين الزوجين لأنه لو جاء مثلا سؤال في + +32 +00:03:39,320 --> 00:03:48,280 +الامتحان حقوق الزوج حصن المعاشرة فقد يكون أيضا من + +33 +00:03:48,280 --> 00:03:56,080 +حقوق الزوجة لأنه قد جاء مكررا مرة من حقوق الزوجوهو + +34 +00:03:56,080 --> 00:04:01,520 +الحق الثالث وفق ترتيب الكتاب والحق الأول من حقوق + +35 +00:04:01,520 --> 00:04:07,080 +الزوجة على زوجها كما نراه في الكتاب ولذلك إذا ما + +36 +00:04:07,080 --> 00:04:15,600 +جاء سؤال حصن المعاشرة من حقوق الزوج الزوجة الزوج + +37 +00:04:15,600 --> 00:04:23,720 +والزوجة لا شيء مما سبق أو كل ما سبق فيكون الجواب + +38 +00:04:23,720 --> 00:04:32,420 +الثالثجيم هو الجواب الصحيح لأن حصن الأشرة أو حصن + +39 +00:04:32,420 --> 00:04:38,900 +المعاشرة من حقوق الزوجين معاه فهو من حق الزوج على + +40 +00:04:38,900 --> 00:04:47,400 +زوجته ومن حق الزوجة على زوجها وحصن المعاشرة + +41 +00:04:47,400 --> 00:04:55,420 +بالنسبةإلى الزوجة يكون باللين والرفق في المعاملة + +42 +00:04:55,420 --> 00:05:04,920 +وأن توفى حقها من المهر والنفقة وأن يبتسم في وجهها + +43 +00:05:04,920 --> 00:05:13,150 +وألا يعبس بدون ذنبوالأهم من هذا كما قال هنا في + +44 +00:05:13,150 --> 00:05:19,290 +الكتاب وهو ما نقل عن السلف الصالح أن يتجمل لها كما + +45 +00:05:19,290 --> 00:05:27,250 +تتجمل له وهذه نقطة لابد أن نقف عندها قليلا وقد قال + +46 +00:05:27,250 --> 00:05:34,490 +أحد السلف إني لأتزين لامرأتي كما تتزين لي فالزوج + +47 +00:05:34,490 --> 00:05:45,890 +له زينةمن النظافة والطهارة والغسل وإزالة العرق حتى + +48 +00:05:45,890 --> 00:05:53,150 +لو كان في شعره شايب له أن يصبغ إن كان صغيرا صبغ + +49 +00:05:53,150 --> 00:05:58,070 +باللون الأسود لأنه لا يتعرض مع الفطرة وإن كان + +50 +00:05:58,070 --> 00:06:04,890 +كبيرا صبغ باللون الأحمر كما ورد لما أسلم أبو قحافة + +51 +00:06:05,650 --> 00:06:10,410 +والد أبي بكر الصديق رضي الله عنهما وجاء به إلى + +52 +00:06:10,410 --> 00:06:17,510 +الرسول صلى الله عليه وسلم وكان شعره قد شابه وبيضه + +53 +00:06:17,510 --> 00:06:26,270 +فكره الرسول منه ذلك فقال غيروا هذا وجنبوه السواد + +54 +00:06:26,270 --> 00:06:34,820 +لماذا قال هنا وجنبوه السواد لأن السواد لا يتناغمو + +55 +00:06:34,820 --> 00:06:43,320 +سن أبي قحافة لأنه كان شيخا عجوزا قد طعن في السن + +56 +00:06:43,320 --> 00:06:51,180 +شاب شعره و حدود بظهره و بلغ من الكبر عتيه اما اذا + +57 +00:06:51,180 --> 00:06:57,880 +كان او كانت هي صغيرا او كانت صغيرة مثلا فلها ان + +58 +00:06:57,880 --> 00:07:03,460 +تصبغ باللون الأسودو ذلك ليس مكروحا ان شاء الله + +59 +00:07:03,460 --> 00:07:09,560 +لأنه لا يغير الفطرة لأن الصغير شعره أسود وهذا + +60 +00:07:09,560 --> 00:07:17,100 +الشيب قد يكون له أسباب أهمها الوراثة قد يشيب شعر + +61 +00:07:17,100 --> 00:07:25,400 +الصغير لسبب الوراثة وهنا يؤخر زواج البنت فلا مانع + +62 +00:07:25,400 --> 00:07:32,430 +من الصباط وباللون الأسودنعم حتى تكون جميلة أمام + +63 +00:07:32,430 --> 00:07:42,210 +خاطبها أو أمام زوجها نعم وقد يكون بسبب مرض يصيب + +64 +00:07:42,210 --> 00:07:50,370 +بصيلات الشعر فتضعف فتذهب الصبغة التي تلون الشعر + +65 +00:07:50,370 --> 00:07:57,240 +وقد يكون أحيانا حالة نفسيةفيتحول الشعر من اللون + +66 +00:07:57,240 --> 00:08:00,700 +الأسود إلى اللون الأبيض وهذا ما ذكره الله في + +67 +00:08:00,700 --> 00:08:04,520 +القرآن الكريم عن يوم القيامة حيث الخوف والفزع + +68 +00:08:04,520 --> 00:08:12,000 +والرعب يوما يجعل الولدان شيبة أردت أن أقول بأن + +69 +00:08:12,000 --> 00:08:19,270 +الزينة محمودة هنا من قبل الزوجزوجته و من قبل + +70 +00:08:19,270 --> 00:08:25,130 +الزوجة لزوجها فكما قلنا قد يشتركان في النظافة و + +71 +00:08:25,130 --> 00:08:36,890 +الطهارة و إزالة العرق و هناك زينة خاصة بالمرأة و + +72 +00:08:36,890 --> 00:08:43,550 +أريد أن أقول بأن المرأة تكره من الرجل ما يكره + +73 +00:08:43,550 --> 00:08:53,110 +الرجل من المرأةفإذا كانت المرأة تكره الشيبة في + +74 +00:08:53,110 --> 00:09:00,430 +الرجل فإن الرجل أيضا يكره الشيبة من المرأة وقد ورد + +75 +00:09:00,430 --> 00:09:08,410 +في قصص العرب أن رجلا كبيرا أراد أن يخطب امرأة وكان + +76 +00:09:08,410 --> 00:09:14,570 +قد شاب شعره نعم وصار أبيض + +77 +00:09:16,700 --> 00:09:24,220 +فسألها هل شاب شعرك أم لا؟ فقالت له نعم طبعا لم + +78 +00:09:24,220 --> 00:09:30,960 +تصدقه القول لم تكن المرأة قد شابت لأن شعرها كان + +79 +00:09:30,960 --> 00:09:40,120 +أسود كالليل البهيم وكانوا يمدحون الشعر الأسود بأنه + +80 +00:09:40,120 --> 00:09:49,670 +كجناحي الغرابتشبيها باللون الأسود شديد السواد + +81 +00:09:49,670 --> 00:09:57,670 +فانصرف عنها لما علم أنها قد شابت ثم قالت له يا رجل + +82 +00:09:57,670 --> 00:10:04,630 +والله ما شاب شعري ولكن شاب شعرك أنت وأردت أن أقول + +83 +00:10:04,630 --> 00:10:10,490 +لك بأن المرأة تكره من الرجل ما يكره الرجل من + +84 +00:10:10,490 --> 00:10:19,830 +المرأة إذا في الكتاب عبارةنعم جميلة و هو أن يتجمل + +85 +00:10:19,830 --> 00:10:26,850 +لها كما تتجمل له و هناك زينة مشتركة و لكل زينة + +86 +00:10:26,850 --> 00:10:34,930 +خاصة و أن يصبر على أذاها و هذا أمر مستحب فهو من + +87 +00:10:34,930 --> 00:10:47,370 +حسن المعاشرة و قد قال ﷺلا يفرك مؤمن مؤمنة بمعنى لا + +88 +00:10:47,370 --> 00:10:58,370 +يكره يفرك بمعنى يكره لا يفرك مؤمن مؤمنة إن كره + +89 +00:10:58,370 --> 00:11:08,110 +منها خلقا راضي غيره وهذا كلام في غاية الدقة + +90 +00:11:10,240 --> 00:11:14,260 +والرسول عليه الصلاة والسلام لا ينطق عن الهوى صلى + +91 +00:11:14,260 --> 00:11:20,380 +الله عليه وسلم فالمرأة ليست ملكا يمشي على الأرض + +92 +00:11:20,380 --> 00:11:27,240 +والمرأة ليست نبيا معصوما فالمرأة كرجل تماما تخطئ + +93 +00:11:27,240 --> 00:11:33,540 +وتصيب والرسول عليه الصلاة والسلام قال كل بني آدم + +94 +00:11:33,540 --> 00:11:39,340 +خطاء وخير الخطائين التوابون نعم + +95 +00:11:41,240 --> 00:11:47,020 +فعلى الزوج إذا ما أخطأت زوجته ألا يتعرض إلى الطلاق + +96 +00:11:47,020 --> 00:11:51,420 +و سنأتي بعد هذه المحاضرة ان شاء الله إلى باب + +97 +00:11:51,420 --> 00:12:00,780 +الطلاق و معرفة أحكامه قلت ألا يتعجل عند أخطائها + +98 +00:12:00,780 --> 00:12:10,550 +بالطلاق لأن الطلاقجده جد و هزله جد كما جاء في بعض + +99 +00:12:10,550 --> 00:12:15,630 +الآثار عند رسول الله صلى الله عليه وسلم بل أن يصبر + +100 +00:12:15,630 --> 00:12:25,130 +و أن يتحمل فالمرأة تخطئ كما أن الرجل يخطئ و كل بني + +101 +00:12:25,130 --> 00:12:33,070 +آدم خطأ و ليس العيب في الخطأإنما العيب هو الإصرار + +102 +00:12:33,070 --> 00:12:39,690 +على هذا الخطأ ولذلك قال هنا صلى الله عليه وسلم + +103 +00:12:39,690 --> 00:12:48,110 +ناصحا الأزواج أن يصبروا على أذا زوجاتهم لا يفرق + +104 +00:12:48,110 --> 00:12:54,670 +مؤمن مؤمنة لا يكره ولا يبغض مؤمن مؤمنة إن كره منها + +105 +00:12:54,670 --> 00:13:04,640 +خلقا رضي غيرهفعلى الإنسان أن ينظر إلى الحسنات وأن + +106 +00:13:04,640 --> 00:13:11,600 +لا يقتصر على السيئات كما جاء في بعض الآثار يرى + +107 +00:13:11,600 --> 00:13:17,140 +أحدكم القذا في عين أخيه كناية عن الذنب الصغير + +108 +00:13:18,410 --> 00:13:23,710 +والخطأ القليل و لا يرى الجذع في عينه والجذع يقنى + +109 +00:13:23,710 --> 00:13:31,450 +به في لغة العرب عن كثرة العيوب و النقائص فلا تخلو + +110 +00:13:31,450 --> 00:13:37,490 +من عيب ولا تخلو من نقص و كذلك المرأة في الإسلام + +111 +00:13:37,490 --> 00:13:45,370 +ليست ملكا او نبيا معصوما كما أسلفنانأتي ثانيا إلى + +112 +00:13:45,370 --> 00:13:52,610 +العدل العدل أيضا من حقوق الزوجة على زوجها والبعض + +113 +00:13:52,610 --> 00:13:58,410 +هنا يخطئ عندما يظن أن العدل لا يكون إلا مع الزوجات + +114 +00:13:58,410 --> 00:14:07,250 +وعند تعدد الزوجات نقول بأن العدل يكون مع الزوجة + +115 +00:14:07,250 --> 00:14:14,120 +الواحدة أيضاكما يكونوا مع تعدد الزوجات كيف يكون + +116 +00:14:14,120 --> 00:14:21,320 +العدل مع الزوجة الواحدة بأن يطعمها مما يطعم وأن + +117 +00:14:21,320 --> 00:14:33,040 +يكسوها مما يلبث وأن يسكنها السكن اللائقة بها نعم + +118 +00:14:33,040 --> 00:14:39,580 +هذا معنى حديث رسول الله صلى الله عليه وسلمأن + +119 +00:14:39,580 --> 00:14:48,660 +يطعمها مما يطعم أن تأكل من نفس طعامه لا أن يأكل في + +120 +00:14:48,660 --> 00:14:57,200 +الأسواق أشهى الطعام والشراب ثم يأتيها في آخر + +121 +00:14:57,200 --> 00:15:04,850 +النهار بالخشن من الطعاموأن يلبسها أو يكسوها مما + +122 +00:15:04,850 --> 00:15:11,530 +يلبس حتى وإن كان يلبسوا العتيقة المستعمل فهذا ليس + +123 +00:15:11,530 --> 00:15:17,750 +عيبا المهم أن يكون طاهرا وأن يكون نظيفا حتى و لو + +124 +00:15:17,750 --> 00:15:25,220 +كان عتيقا أو مستعملاوان يسكنها السكن اللي هيقبها و + +125 +00:15:25,220 --> 00:15:30,380 +هذا سنأتي اليه عند الحديث عن النفقة فإن النفقة + +126 +00:15:30,380 --> 00:15:38,340 +تتعني المسكن و المأكل و الملبس و سنزيد أيضا + +127 +00:15:38,340 --> 00:15:47,520 +التعليم و التطبيبفالتطبيب والتعليم أيضًا من حقوق + +128 +00:15:47,520 --> 00:15:55,300 +الزوجة على زوجها ومن حقوق الولد على أبيه وسنأتي + +129 +00:15:55,300 --> 00:16:02,500 +إليه ان شاء الله أما المشكلة الأهم والمشكلة الأخطر + +130 +00:16:02,500 --> 00:16:09,440 +كيف يكون العدل مع الزوجات وهنا + +131 +00:16:10,480 --> 00:16:14,920 +لابد أن نقف قليلا عند هذا الباب لأنه من المواضيع + +132 +00:16:14,920 --> 00:16:23,740 +المهمة في الإسلام فهناك أمور ظاهرة مثل النفقة كما + +133 +00:16:23,740 --> 00:16:30,720 +أسلفنا و المبيت و هناك أمور باطنة مثل المحبة + +134 +00:16:30,720 --> 00:16:39,790 +القلبية فما هو المطلوب هنا المطلوب هناكما أخبر + +135 +00:16:39,790 --> 00:16:44,890 +القرآن الكريم وكما أخبر النبي المعصوم الذي لا ينطق + +136 +00:16:44,890 --> 00:16:51,230 +عن الهوى صلى الله عليه وسلم أن الواجب على الزوج هو + +137 +00:16:51,230 --> 00:16:58,190 +العدل في الأمور الظاهرة كالنفقة والمبيت وقد تكلمنا + +138 +00:16:58,190 --> 00:17:05,150 +قليلا عن النفقة من مسكن ومطعم وملبس + +139 +00:17:06,250 --> 00:17:13,430 +هذه أمور لابد أن يشترك بها جميع الزوجات فلا يفرق + +140 +00:17:13,430 --> 00:17:19,590 +بين امرأة وأخرى وكذلك المبيت أن يبيت عند هذه مثلا + +141 +00:17:19,590 --> 00:17:25,010 +ليلة وعند هذه ليلة أو أن يبيت عند هذه ليلتين وعند + +142 +00:17:25,010 --> 00:17:37,170 +تلك ليلتين حسب الاتفاق بينهما هذا عدل فرضواجب كوجب + +143 +00:17:37,170 --> 00:17:43,750 +أركان الإسلام من صوم وصلاة وحج وذاكرة والزوج آثم + +144 +00:17:43,750 --> 00:17:51,810 +إن لم يعدل بين الزوجات في الأمور الظاهرة أو الأمور + +145 +00:17:51,810 --> 00:17:58,910 +المادية المقدورة عليه وهذه لا عضلة لأحد أبدا فيها + +146 +00:17:58,910 --> 00:18:07,710 +النفقة والمبيتوهذا والله تعالى أعلى وأعلم معنى + +147 +00:18:07,710 --> 00:18:14,950 +قوله تبارك وتعالى فإن خفتم ألا تحدلوا فواحدة + +148 +00:18:14,950 --> 00:18:21,950 +والمقصود بالعدل هنا هو العدل الظاهر العدل المادي + +149 +00:18:21,950 --> 00:18:27,170 +المقدور عليه من النفقة والمبيت والرسول عليه الصلاة + +150 +00:18:27,170 --> 00:18:36,870 +والسلام كان يفعل ذلك مع أزواجهحتى إنه لما ترك أم + +151 +00:18:36,870 --> 00:18:44,750 +سلمة استشارها في ذلك فأذنت له أن يبيت ليلتها عند + +152 +00:18:44,750 --> 00:18:52,950 +عائشة لأن المبيت حق لها فتنازلت أم سلمة برضاها + +153 +00:18:52,950 --> 00:19:00,810 +ومحض اختيارها عن ليلتها إلى عائشة على أن لا يطلقها + +154 +00:19:01,640 --> 00:19:09,240 +وتبعث يوم القيامة زوجة للرسول في الجنة لأن أزواج + +155 +00:19:09,240 --> 00:19:15,100 +النبي في الدنيا أزواج النبي في الجنة صلى الله عليه + +156 +00:19:15,100 --> 00:19:24,060 +وسلم ورضي الله عن أزواج النبي أجمعين نأتي إلى + +157 +00:19:24,060 --> 00:19:33,470 +العدل الباطن وهو الميل القلبيهذا ليس فرضًا ولا + +158 +00:19:33,470 --> 00:19:41,970 +واجبًا لأن القلب بين أصبعين من أصابع الرحمن يقلبها + +159 +00:19:41,970 --> 00:19:48,950 +كيف شاء وعند قوله تبارك وتعالى في صورة الأنفال + +160 +00:19:48,950 --> 00:19:55,610 +واعلموا أن الله يحول بين المرء وقلبه قال ابن كثير + +161 +00:19:55,610 --> 00:20:00,580 +يحول بمعنى يفصلوكان النبي عليه الصلاة والسلام + +162 +00:20:00,580 --> 00:20:07,260 +عندما يقرأ هذه الآية يكثر من دعاء يا مقلب القلوب + +163 +00:20:07,260 --> 00:20:15,180 +والأبصار ثبت قلبي على دينك ولذلك صمي القلب قلبا + +164 +00:20:15,180 --> 00:20:23,100 +لأنه لا يثبت على حال فصرعان ما يتقلبوا وقد قال + +165 +00:20:23,100 --> 00:20:30,520 +الشاعر العربيوما سمي القلب إلا من تقلبه فاحذر على + +166 +00:20:30,520 --> 00:20:40,760 +القلب من قلب وتحويله نعم هذا هو حقيقة القلب فقد + +167 +00:20:40,760 --> 00:20:49,480 +يميل الزوج إلى بعض نسائه بقلبه وهذا + +168 +00:20:49,480 --> 00:20:56,430 +لا يحاسب عليه الإنسانولا يأثم فيه إن شاء الله لكن + +169 +00:20:56,430 --> 00:21:02,050 +عليه أن يتق الله واتقوا الله ما استطعتم كما قال + +170 +00:21:02,050 --> 00:21:07,430 +هنا فلا تميلوا كل الميل لأن ميل القلب إلى واحدة + +171 +00:21:07,430 --> 00:21:15,970 +منهم لا يعني أن يهجر الثانية أو بقية الزوجات إن + +172 +00:21:15,970 --> 00:21:21,470 +كان متزوجا بأكثر من واحدة وهذا والله أعلى وأعلم + +173 +00:21:22,130 --> 00:21:27,790 +معنى قوله تبارك وتعالى ولن تستطيعوا أن تعدلوا بين + +174 +00:21:27,790 --> 00:21:34,390 +النساء ولو حرفتم فلا تميلوا كل الميت و هنا يأتي + +175 +00:21:34,390 --> 00:21:40,110 +أعداء الإسلام من العلمانيين والشيوعيين + +176 +00:21:40,110 --> 00:21:45,970 +والمستشريقين ويقول بأن في القرآن التناقضا كيف يقول + +177 +00:21:45,970 --> 00:21:51,360 +الله تبارك وتعالى في الآيةفإن خفتم أن لا تعدلوا + +178 +00:21:51,360 --> 00:21:56,300 +فواحدة ويقول في الآية الأخرى و لن تستطيعوا أن + +179 +00:21:56,300 --> 00:22:02,540 +تعدلوا بين النساء ولو حرصتم نقول لا تعارض البتة + +180 +00:22:02,540 --> 00:22:09,340 +لأن الكلام هو كلام الله سبحانه وتعالى فالآية + +181 +00:22:09,340 --> 00:22:15,200 +السابقة فإن خفتم أن لا تعدلوا فواحدة إنما تعني + +182 +00:22:15,200 --> 00:22:21,390 +العدلفي الأمور الظاهرة كما أسلفنا يعني في الأمور + +183 +00:22:21,390 --> 00:22:31,410 +المادية المقدور عليها أما الآية الأخرى و لن + +184 +00:22:31,410 --> 00:22:37,510 +تستطيعوا أن تعدلوا فهي في الأمور القلبية الأمور + +185 +00:22:37,510 --> 00:22:45,370 +الباطنة التي لا يقدر عليها إلا الله لأن الشخص قد + +186 +00:22:45,370 --> 00:22:52,650 +يميلوأقوله بأن الميل هنا قد لا يكون بسبب جمال + +187 +00:22:52,650 --> 00:22:59,550 +الزودة كما يظن البعض وانا قد قرأته بعض الكتب حتى + +188 +00:22:59,550 --> 00:23:05,530 +عند غير المسلمين بأن بعض الملوك كان يميلوا إلى + +189 +00:23:05,530 --> 00:23:14,730 +زوجة صمراء وفرعية من هم أجمل منها بسبب حسن + +190 +00:23:14,730 --> 00:23:23,130 +المعاشرةالذي سبق الحديث عنه فعظوبته اللسان + +191 +00:23:23,130 --> 00:23:26,430 +وابتسامته + +192 +00:23:26,430 --> 00:23:37,430 +نعم فهذا كله من إعداد الطعام وإعداد الحمام إذا كان + +193 +00:23:37,430 --> 00:23:48,340 +قد عاد تعبا مرحقا فلا تقابله بتجهمأو بقلة النفقة + +194 +00:23:48,340 --> 00:23:56,600 +والمصاريف ورسوم المدارس والجامعات وفطورة الماء + +195 +00:23:56,600 --> 00:24:05,440 +والكهرباء إلى غير ذلك نعم إذا هذا يرجع إلى حصن + +196 +00:24:05,440 --> 00:24:12,260 +معاشرة الزوجة لزوجها وأقول أيضا قد يميل الرجل إلى + +197 +00:24:12,260 --> 00:24:22,880 +زوجة أقل جمالامن أختها و دعوني ألا أقول ضرتها لأن + +198 +00:24:22,880 --> 00:24:28,840 +العوام يقولون ضرة و أنا لا أقول هذا إن شاء الله و + +199 +00:24:28,840 --> 00:24:37,300 +لكن كما جاء في بعض الحديث أختها نعم و قد تكون أقل + +200 +00:24:37,300 --> 00:24:46,970 +جمالا منها فيؤثرها على الأكثر جمالا نعمإذا هنا لا + +201 +00:24:46,970 --> 00:24:53,770 +عتبة على الزوج والنبي عليه الصلاة والسلام قد صرح + +202 +00:24:53,770 --> 00:25:02,770 +بذلك عندما قال اللهم هذا قصمي فيما أملك فلا تلومني + +203 +00:25:02,770 --> 00:25:10,570 +فيما تملك ولا أملك وهو القلب أو الحب والمودته + +204 +00:25:12,340 --> 00:25:19,120 +فالنبي عليه الصلاة والسلام كان يصرحه بحب عائشة رضي + +205 +00:25:19,120 --> 00:25:25,220 +الله عنها كما جاء في الحديث الصحيحة لعلها في + +206 +00:25:25,220 --> 00:25:29,340 +البخاري عندما سؤل عليه الصلاة والسلام عن أحب الناس + +207 +00:25:29,340 --> 00:25:35,760 +ليه فقال أبو بكرن فقال لا نسألك عن الرجال من + +208 +00:25:35,760 --> 00:25:43,480 +النساء قال عائشتهفعائشة الصديقة بنت الصديق كانت + +209 +00:25:43,480 --> 00:25:50,860 +أحب النساء إليه وهذا هو معنى قوله اللهم إن هذا + +210 +00:25:50,860 --> 00:25:58,060 +قسمي وقسمي بمعنى + +211 +00:25:58,060 --> 00:26:06,620 +العدل بين الزوجات وليس قسمي لأن القسم بفتح الصين + +212 +00:26:06,620 --> 00:26:15,270 +هو اليمينوالجمع أقسام أما القسم هو العدل بين + +213 +00:26:15,270 --> 00:26:23,410 +الزوجات إذا لابد أن نقف هنا وانتبهوا لأن هذا قد + +214 +00:26:23,410 --> 00:26:30,210 +يأتيكم في الامتحانات صح أو خطأ أو اختيار متعدد إذا + +215 +00:26:30,210 --> 00:26:37,400 +الواجب هو العدلفي الأمور الظاهرة المادية المقدور + +216 +00:26:37,400 --> 00:26:43,660 +عليها مثل النفقة والمبيت وهذا معنى الآية الكريمة + +217 +00:26:43,660 --> 00:26:52,300 +فإن خبتم ألا تعدلوا فوحدة وكذلك ليس مطلوبا العدل + +218 +00:26:52,300 --> 00:26:57,120 +أو ليس واجبا أو فرضا العدل في الأمور الباطنة + +219 +00:26:57,120 --> 00:27:05,050 +القلبيةكالحب و المودة و هذا معنى الآية الأخرى و لن + +220 +00:27:05,050 --> 00:27:10,410 +تستطيعوا أن تعدلوا بين النساء و لو حرصتم و لن + +221 +00:27:10,410 --> 00:27:17,590 +تفيدوا الحاضرة و المستقبل لم يقول لم لأنه لو قال + +222 +00:27:17,590 --> 00:27:27,360 +لم محتمل أن يكون ذلك في المستقبل و لكنهلا في + +223 +00:27:27,360 --> 00:27:33,380 +الحاضر ولا في المستقبل فاتقوا الله ولا تميلوا كل + +224 +00:27:33,380 --> 00:27:39,640 +الميل بمعنى إذا ميلتم إلى واحدة منهم فلا تهجروا + +225 +00:27:39,640 --> 00:27:44,440 +الباقيات وهذا ما أكده الرسول عليه الصلاة والسلام + +226 +00:27:44,440 --> 00:27:50,620 +في حديثه اللهم هذا قصمي فيما أملك وهو المبيت + +227 +00:27:50,620 --> 00:27:58,070 +والنفقة فلا تلومني يا ربفي ما تملك و هو القلب ولا + +228 +00:27:58,070 --> 00:28:04,810 +أملك أي في الحب والمواد ثالثا من حقوق الزوجة على + +229 +00:28:04,810 --> 00:28:15,480 +زوجها المهر وهذا عرضون محبة كما يقولون وهو واجبعلى + +230 +00:28:15,480 --> 00:28:21,560 +الزوج وحق من حقوق الزوجة على زوجها قال الله تبارك + +231 +00:28:21,560 --> 00:28:29,440 +وتعالى واتوا النساء صدقاتهن نحلة صدقات جمعوا صدقة + +232 +00:28:29,440 --> 00:28:37,670 +جمعوا صدقة عفوا صدقةبضم الدال صدقة بمعنى المهر + +233 +00:28:37,670 --> 00:28:46,970 +والجمع صدقات أما صدقة بفتح الدال فمعناه الذكاءومنه + +234 +00:28:46,970 --> 00:28:52,590 +قوله تبارك وتعالى في صورة التوبة إنما الصدقات + +235 +00:28:52,590 --> 00:28:59,570 +للفقراء والمسكين فالصدقات جمعوا صدقة والصدقات + +236 +00:28:59,570 --> 00:29:06,290 +جمعوا صدقة بمعنى المهل وآتوا النساء صدقاتهن نحلة + +237 +00:29:06,290 --> 00:29:15,900 +نحلة بمعنى هبةأو عطية أو منحة فإن طبنا لكم عن شيء + +238 +00:29:15,900 --> 00:29:25,800 +منه نفسا فكلوه هنيئا مريئا نعم وهذا لفته إلى بعض + +239 +00:29:25,800 --> 00:29:31,400 +الإخوة أو بعض الآباء الذين يأخذون شيئا من مهور + +240 +00:29:31,400 --> 00:29:41,480 +أخواتهن أو بناتهن فهذا لا يحل شرعافإن المهر ملك + +241 +00:29:41,480 --> 00:29:49,860 +للزوجته ولها أن تتنازل عن شيء منه لزوجها مثلا أو + +242 +00:29:49,860 --> 00:29:58,840 +لأخيها أو ابنها أو أبيها وآتوا النساء صدقاتهن نحلة + +243 +00:29:58,840 --> 00:30:08,820 +فانطبن لكممنه شيئا فكلوه هنيئا مريئا فهو أحل + +244 +00:30:08,820 --> 00:30:16,520 +الحلال كما قالوا أحل الحلال ثلاثة أولها مهر + +245 +00:30:16,520 --> 00:30:22,960 +الزوجته إن كان عن طيب منها و ثانيا الميراث أيضا + +246 +00:30:22,960 --> 00:30:30,720 +أحل الحلال و ثالثا مال الغنيمة نعمفاكلوا مما غنمتم + +247 +00:30:30,720 --> 00:30:41,340 +حلالا طيبا وقد ذهب جمهور الفقهاء إلى أنه لا حد + +248 +00:30:41,340 --> 00:30:48,880 +لأكثر المهرحتى ولو وصل إلى قنطار كما قال الله + +249 +00:30:48,880 --> 00:30:55,540 +تبارك وتعالى وإن أردتم استبدال زوج مكان زوج وآتيتم + +250 +00:30:55,540 --> 00:31:02,080 +إحداهن قنطارا فلا تأخذوا منه شيئا أتأخذونه بهتانا + +251 +00:31:02,080 --> 00:31:11,620 +وإثما مبينا لا حد لأكثره وأيضا + +252 +00:31:12,430 --> 00:31:22,010 +لا حد لقليله فإن المهرأ قد يصل إلى خاتم من حديد + +253 +00:31:22,010 --> 00:31:30,870 +كما جاء في بعض الآثار التمث و لو كان خاتما من حديد + +254 +00:31:30,870 --> 00:31:39,270 +و لو كان خاتما من حديدومعنى الحديث وَلَوْ كَانَ + +255 +00:31:39,270 --> 00:31:45,450 +مُلْتَمَسُكَ خَاتَمًا مِنْ حَدِيدٍ فخاتم الخبر كان + +256 +00:31:45,450 --> 00:31:52,090 +المحذوفة واسمها التمس و لو خاتم يعني و لو كان مهرك + +257 +00:31:52,090 --> 00:32:02,090 +خاتم أو ملتمسك خاتم من حديد وقد يكون المهر صورا او + +258 +00:32:02,090 --> 00:32:08,900 +حتى آيات من القرآن الكريموهذه بُشرة لأبنائنا الذين + +259 +00:32:08,900 --> 00:32:15,220 +يحفظون القرآن الكريم بأن القرآن الكريم يكون مهرا + +260 +00:32:15,220 --> 00:32:23,040 +بل أعظم المهر كما جاء في الأحاديث الصحاح عندما + +261 +00:32:23,040 --> 00:32:26,940 +جاءت امرأة تعرض نفسها على الرسول عليه الصلاة + +262 +00:32:26,940 --> 00:32:34,260 +والسلام وكأنه لم يكن بحاجة إليهافقال أحد الصحابة + +263 +00:32:34,260 --> 00:32:39,820 +زويني إياها يا رسول الله و لا يملك شيئا فقال له هل + +264 +00:32:39,820 --> 00:32:43,280 +تحفظ شيئا من القرآن قال كذا و كذا يا رسول الله قال + +265 +00:32:43,280 --> 00:32:50,920 +حفظهم إياها فذاك مهرها نعم و لا نحتكر ذلك فإن أعظم + +266 +00:32:50,920 --> 00:33:00,880 +المهور هو كلام الله سبحانه و تعالى هذا هو الحق + +267 +00:33:00,880 --> 00:33:07,960 +الثالثمن حقوق الزوجة على زوجها ألا وهو المهروم أما + +268 +00:33:07,960 --> 00:33:14,920 +النفقة فهي أيضا من حق الزوجة على زوجها وسوف نستدل + +269 +00:33:14,920 --> 00:33:19,340 +على ذلك من القرآن ومن السنة فمن القرآن الآية + +270 +00:33:19,340 --> 00:33:25,120 +السابقة في المحاضرة السابقة عندما تكلمنا عن الطاعة + +271 +00:33:25,120 --> 00:33:31,880 +كحق من حقوق الزوج على زوجتهوهذه الآية هي قوله + +272 +00:33:31,880 --> 00:33:38,200 +تبارك وتعالى الرجال قوامون على النساء بما فضّل + +273 +00:33:38,200 --> 00:33:46,100 +الله بعضهم على بعض وبما أنفقوا من أموالهم وقوامون + +274 +00:33:46,100 --> 00:33:53,050 +من القوامة وهي حق الطاعة وللرجال عليهن درجةالطاعة + +275 +00:33:53,050 --> 00:33:58,870 +والقوامة كما سبق في الحديث وهي من حقوق الزوج على + +276 +00:33:58,870 --> 00:34:04,270 +زوجته أما نحن هنا فجئنا بالآية من أجل قوله وبما + +277 +00:34:04,270 --> 00:34:10,190 +أنفقوا من أمواله فهذا فضل الله يؤتيه من يشاء والله + +278 +00:34:10,190 --> 00:34:17,730 +واسع عليهم وتكلمنا عن النفقة أنها تشمل أولا السكن + +279 +00:34:17,730 --> 00:34:28,640 +اللائق بها نعموأن يطعمها مما يطعم وأن يكسوها + +280 +00:34:28,640 --> 00:34:37,280 +الكسوة اللائقة بها أو أن يلبسها مما يلبس كما جاء + +281 +00:34:37,280 --> 00:34:44,880 +في الآثار ونزيد على ذلك وسنأتي إليه إن شاء الله في + +282 +00:34:44,880 --> 00:34:54,570 +موضع آخر عند التفريقبين الرجل والمرأة في الشهادة + +283 +00:34:54,570 --> 00:35:03,010 +وفي الميراث وفي رئاسة الدولة سنتكلم لماذا فرق الله + +284 +00:35:03,010 --> 00:35:06,910 +بين الرجل والمرأة في الميراث يوصيكم الله في + +285 +00:35:06,910 --> 00:35:15,170 +أولادكم للذاكر مثل حظ الأنسين وسنقول يومهابأن + +286 +00:35:15,170 --> 00:35:20,370 +الرجل مطالب بالمهر ومطالب بالنفقة وأن المرأة في + +287 +00:35:20,370 --> 00:35:27,510 +الإسلام لا تكلف بشيء فهي مكفية المؤنة إن كانت + +288 +00:35:27,510 --> 00:35:32,830 +صغيرة فعلى أبيها وإن كانت زوجة فنفقتها على زوجها + +289 +00:35:32,830 --> 00:35:38,950 +حتى و لو كانت أغنى الأغنيةوإن كانت كبيرة فنفقتها + +290 +00:35:38,950 --> 00:35:45,270 +على ولدها وثنأت أيضًا إلى أن التعليم والتطبيب + +291 +00:35:45,270 --> 00:35:52,490 +أيضًا يدخل في نفقة الزوج على أهله وعلى ولده أما من + +292 +00:35:52,490 --> 00:35:58,030 +الصناة النبوية فالحديث الشريفإذا أنفق المسلم نفقة + +293 +00:35:58,030 --> 00:36:04,650 +على أهله وهو يحتسبها كانت له صدقة والمراد بالأهل + +294 +00:36:04,650 --> 00:36:14,370 +هنا الزوجة والولد وقيل تشمل الأرحام أيضا من أقارب + +295 +00:36:14,370 --> 00:36:20,490 +الزوج ولعلنا قد تكلمنا عن هذا عند الحديث عن + +296 +00:36:20,490 --> 00:36:26,410 +العبادةوقلنا بأن العبادة بمعناها العام هي كل عمل + +297 +00:36:26,410 --> 00:36:35,850 +أو فعل يبتغى به وجه الله حتى نفقة الزوجة والولد + +298 +00:36:35,850 --> 00:36:41,470 +إذا كانت في سبيل الله وابتغاء مرضاة الله وهذا معنى + +299 +00:36:41,470 --> 00:36:46,730 +الحديث وهو يحتسبها كانت له صدقة والنبي عليه السلام + +300 +00:36:46,730 --> 00:36:54,770 +عندما وصل إلى قصةموسى وام موسى قال إن المؤمن الذي + +301 +00:36:54,770 --> 00:37:00,410 +يعمل العمل يبتغي به وجه الله فهو كأم موسى ترضع + +302 +00:37:00,410 --> 00:37:05,870 +ولدها وتأخذ أجرها لأن النية تجعل العمل الدنيوي + +303 +00:37:05,870 --> 00:37:17,560 +أخرويًا وأعود إلى الوسط لأنه معنى آيتان وحديثأخرت + +304 +00:37:17,560 --> 00:37:23,640 +الآية الوسطى لأنها تتكلم عن مسألة مهمة أردت ألا + +305 +00:37:23,640 --> 00:37:34,760 +أسرع فيها وهي النفقة الزوجية تكون وفق حال الزوج أم + +306 +00:37:34,760 --> 00:37:43,800 +وفق حال الزوجة الجواب أن النفقة تكون وفق حال الزوج + +307 +00:37:45,050 --> 00:37:53,750 +أو كما قال هنا على حسب قدرة الزوج من يسار وإعصار + +308 +00:37:53,750 --> 00:38:00,730 +أو من غنا وفكر وهذا معنى الآية التي أخرتها لأقف + +309 +00:38:00,730 --> 00:38:09,020 +عندها قليلا وهي في صورة الطلاق لينفق ذو ساعةمن + +310 +00:38:09,020 --> 00:38:15,900 +سعته ومن قدر عليه رزقه فلينفق مما آتاه الله + +311 +00:38:15,900 --> 00:38:23,040 +وبالمثال يتضح المقال لو كان الزوج غنيا وكانت + +312 +00:38:23,040 --> 00:38:32,520 +الزوجة فقيرة فإن القاضي يحكم على الزوج نفقة غني أو + +313 +00:38:32,520 --> 00:38:39,030 +نفقة يسار دون النظر إلى فقر الزوجةوالعكس إذا كان + +314 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وهذا هو معنى قوله تبارك وتعالى والله أعلى + +326 +00:40:08,470 --> 00:40:16,490 +وأعلم في صورة الأنبياء عند الحديث عننبي الله يونس + +327 +00:40:16,490 --> 00:40:21,790 +عليه السلام وزنوني وذا بمعنى صاحب يعني وصاحب النون + +328 +00:40:21,790 --> 00:40:28,690 +يعني الحوت وزنوني الذهب مغاضبا فظن ألا نقدر عليه + +329 +00:40:28,690 --> 00:40:36,910 +ومعنى ألا نقدر عليه بمعنى ألا نضيق عليه إذا ومن + +330 +00:40:36,910 --> 00:40:43,310 +قدر عليه رزقه يعني ضيق عليه رزقه بفكر أو عسرفلينفق + +331 +00:40:43,310 --> 00:40:50,230 +مما آتاه الله لا يكلف الله نفسا إلا ما آتاها سيجعل + +332 +00:40:50,230 --> 00:40:59,290 +الله بعد عصر يسرا نعم وصلنا إلى القسم الثالث وهو + +333 +00:40:59,290 --> 00:41:01,510 +الحقوق المشتركة بين الزوجين + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/5kneOaWUqdM_raw.json b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/5kneOaWUqdM_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..7f6c86008a518ea4b2e6b33d2778107e2d8e57b0 --- /dev/null +++ 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الزوج من يسار وإعصار أو من غنا وفكر وهذا معنى الآية التي أخرتها لأقف عندها قليلا وهي في صورة الطلاق لينفق ذو ساعة", "tokens": [10721, 2407, 9122, 15042, 50239, 34105, 15844, 11331, 35457, 12174, 3215, 25720, 6024, 110, 29245, 9154, 7251, 3794, 9640, 4032, 28814, 3615, 9381, 9640, 34051, 9154, 32771, 8315, 4032, 5172, 37983, 37037, 15730, 20449, 1863, 7578, 6024, 95, 10632, 38392, 5551, 34740, 2655, 11296, 5296, 10721, 4587, 5172, 43242, 11296, 12174, 20292, 15040, 37037, 1829, 8978, 20328, 13063, 3660, 41950, 15040, 4587, 5296, 9957, 5172, 4587, 29910, 2407, 8608, 995, 27884], "avg_logprob": -0.08051215546826522, "compression_ratio": 1.632258064516129, "no_speech_prob": 2.384185791015625e-06, "words": [{"start": 2265.05, "end": 2265.41, "word": "أو", "probability": 0.95947265625}, {"start": 2265.41, "end": 2265.75, "word": " كما", "probability": 0.965576171875}, {"start": 2265.75, "end": 2266.21, "word": " قال", "probability": 0.91943359375}, {"start": 2266.21, "end": 2267.21, "word": 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b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/BcRDA3L7VZk_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..4bbcd351254f628385c0d33ff5329a62e17620a9 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/BcRDA3L7VZk_postprocess.srt @@ -0,0 +1,1400 @@ +1 +00:00:05,030 --> 00:00:07,710 +أعوذ بالله السماء العليم من الشيطان الرجيم بسم + +2 +00:00:07,710 --> 00:00:11,090 +الله الرحمن الرحيم الحمد لله والصلاة والسلام على + +3 +00:00:11,090 --> 00:00:15,730 +رسول الله اللهم صلى على سيدنا محمد وعلى أهله وصحبه + +4 +00:00:15,730 --> 00:00:21,420 +وسلم أجمعين عزيزي الطلاب قبل ذي بدءورحبكم جميعا و + +5 +00:00:21,420 --> 00:00:25,100 +أحييكم بتحيية الإسلام العظيم فالسلام الله عليكم + +6 +00:00:25,100 --> 00:00:29,600 +ورحمته وبركاته اليوم ان شاء الله نكون على موعد مع + +7 +00:00:29,600 --> 00:00:34,700 +ختام المبحث الثالث من الفصل التمهيدي وهو بانوان + +8 +00:00:34,700 --> 00:00:40,690 +خصائص النظم الإسلاميةوبعدها ننتقل بكم ان شاء الله + +9 +00:00:40,690 --> 00:00:45,270 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بمعنى أنها + +21 +00:02:05,950 --> 00:02:14,770 +الحياة الحقيقية لأنه من مات فقد قامت قيامته و ليس + +22 +00:02:14,770 --> 00:02:22,330 +القبر هو الانهاية فهناك الحساب و هناك الثواب و + +23 +00:02:22,330 --> 00:02:30,680 +العقاب و هناك الجنة و النارو هناك تطاير الصحف إما + +24 +00:02:30,680 --> 00:02:37,520 +بيمينه أو بشماله أو من وراي ظهره و هناك الشفاعة + +25 +00:02:37,520 --> 00:02:53,720 +حيث العرق الذي يصل إلى الأنف و إلى الفم نعم و هناك + +26 +00:02:53,720 --> 00:03:02,300 +الصراطوهو أحد من السيف وأرفع من الشعرته فالمؤمنون + +27 +00:03:02,300 --> 00:03:13,840 +يكونون عليه صراعا كالبرق أو كالخيل أو يمشي هرولة + +28 +00:03:13,840 --> 00:03:22,320 +ومنهم والعياذ بالله من يقع ويتهاوى في النار كما + +29 +00:03:22,320 --> 00:03:28,450 +يتهاوى الفراشوالعياذ بالله وهذا معنى قوله تبارك + +30 +00:03:28,450 --> 00:03:36,090 +تعالى وإن منكم إلا واردها وواردها بمعنى مار عليها + +31 +00:03:36,090 --> 00:03:43,670 +فهناك فرق بين قوله واردها وبين داخلها فالمؤمنون + +32 +00:03:43,670 --> 00:03:49,710 +يمرون عليها إلى الجنة إن شاء الله تبارك وتعالى كما + +33 +00:03:49,710 --> 00:03:54,860 +قال الله في قصة موسى في صورة القصص ولمّا وردماء + +34 +00:03:54,860 --> 00:04:03,840 +مدينة وإن منكم إلا واردها كان على ربك حتما مقضية + +35 +00:04:03,840 --> 00:04:09,100 +ثم ننجي الذين اتقوا ونظر الظالمين فيها جثية + +36 +00:04:09,100 --> 00:04:16,660 +والعياذ بالله وما بعد الصراط من مستعتب فإما إلى + +37 +00:04:16,660 --> 00:04:26,080 +نار حرها شديد وقعرها بعيدومقامعها حديد يقول الله + +38 +00:04:26,080 --> 00:04:32,440 +تبارك وتعالى هل امتلأتي؟ وتقول هل من مزيد؟ وإما + +39 +00:04:32,440 --> 00:04:39,300 +إلى جنات ونهر في مقعد صدق عند مليك مقتدر عرضها + +40 +00:04:39,300 --> 00:04:45,780 +السماوات والأرض أعدت للمتقين كما أخبر المصطفى الذي + +41 +00:04:45,780 --> 00:04:50,490 +لا ينطق عن الهوى محمد بن عبد اللهصلى الله عليه + +42 +00:04:50,490 --> 00:04:57,070 +وسلم فيها ما لا عين رأت ولا أذن سمعت ولا خطر على + +43 +00:04:57,070 --> 00:05:04,910 +قلب بشر فحي على جنات عدن فحي على جنات عدن ألا إن + +44 +00:05:04,910 --> 00:05:11,850 +الجنة عروس ومهرها العمل الصالح فهل من خاطب نعم هذا + +45 +00:05:11,850 --> 00:05:18,440 +هو حال المؤمنينالذين يؤمنون بالقيامة و بالبعث و + +46 +00:05:18,440 --> 00:05:25,720 +النشور أما غير المؤمنين من الكافرين و المشركين و + +47 +00:05:25,720 --> 00:05:37,220 +الملاحدة فشعارهم أرحم تدفع و أرض تبلع لا إله و + +48 +00:05:37,220 --> 00:05:42,040 +الحياة مادة و الدين و أفيون الشعوبتعالى الله عما + +49 +00:05:42,040 --> 00:05:47,220 +يقولون علوًا كبيرة وقد سماهم القرآن الكريم + +50 +00:05:47,220 --> 00:05:55,060 +بالدهريين اليوم الملحدون او الشيوعيون و بالامس + +51 +00:05:55,060 --> 00:06:03,290 +بلغة القرآن الكريم الدهريون نموت و نحياوما يغلقنا + +52 +00:06:03,290 --> 00:06:11,450 +إلا الدهر كما قال شاعر الجاهلية أموت ثم بعث ثم حشر + +53 +00:06:11,450 --> 00:06:18,910 +حديث خرافة يا أم عمر فهم والعياذ بالله يأكلون + +54 +00:06:18,910 --> 00:06:25,110 +ويتمتعونكما وصفهم القرآن الكريم في سورة محمد كما + +55 +00:06:25,110 --> 00:06:31,010 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00:08:13,100 +قال في الكتاب وقد بلغ الأمر في التأكيد على الجزاء + +68 +00:08:13,100 --> 00:08:20,140 +الأخرويأن من قضى له القضاء بشيء وهو يعلم عدم + +69 +00:08:20,140 --> 00:08:27,840 +استحقاقه له فإنما يأخذه حراما ويستحق عليه العقوبة + +70 +00:08:27,840 --> 00:08:35,100 +في الآخرة والدليل على ذلك ما رواه البخاري ومسلم عن + +71 +00:08:35,100 --> 00:08:42,680 +رسول الله عليه الصلاة والسلام إنكم تختصمون إليوكأن + +72 +00:08:42,680 --> 00:08:47,580 +الرسول يقول ذلك بعيدا عن الوحي وبعيدا عن النبوة + +73 +00:08:47,580 --> 00:08:56,540 +وبعتباره قاضيا وهو درس إلى قضاة الأرض إنكم تختصمون + +74 +00:08:56,540 --> 00:09:05,040 +إليا وإنما أنا بشر وعسى أن يكون بعضكم ألحن بحجته + +75 +00:09:05,040 --> 00:09:13,930 +من بعض فقد يكون المحام فصيحاباليغا وقد يكون الخصم + +76 +00:09:13,930 --> 00:09:25,610 +صاحب الحق جاهلا أميا لا يستطيع أن يثبت حقه فأقضي + +77 +00:09:25,610 --> 00:09:32,750 +له على نحو ما أسمع لأن هذا المحامي قد أتى بالشهود + +78 +00:09:32,750 --> 00:09:40,100 +وقد ظور الوثائق والبيناتوالقاضي في هذه الحال معذور + +79 +00:09:40,100 --> 00:09:49,600 +أيضًا لأنه يحكم وفق ما بين يديه من وثائق وبينات ثم + +80 +00:09:49,600 --> 00:09:54,680 +يقول عليه الصلاة والسلام محذرا من حكم له القاضي + +81 +00:09:54,680 --> 00:10:03,000 +بغير حقه فمن قضيت له بشيء من حق أخيهفإنما أقطعوا + +82 +00:10:03,000 --> 00:10:08,880 +له قطعة من النار فليأخذها أو يتركها طبعا هذا + +83 +00:10:08,880 --> 00:10:14,520 +الحديث له قصة في عهد الصحابة و هما أخواني في عهد + +84 +00:10:14,520 --> 00:10:20,080 +الرسول عليه الصلاة والسلام قد اختلفا في مواريثة + +85 +00:10:20,080 --> 00:10:28,180 +دارسة مواريثة قديمة و ليسمع هؤلاء الإخوة ولا أعني + +86 +00:10:28,180 --> 00:10:33,560 +إخوة النسب وإنما أعني إخوة الدين إنما المؤمنون + +87 +00:10:33,560 --> 00:10:38,620 +إخوة فاصلحوا بين أخويكم واتقوا الله لعلكم ترحمون + +88 +00:10:38,620 --> 00:10:47,520 +كل من هذين المسلمين لا يملكوا أوراق تثبت أحقية + +89 +00:10:47,520 --> 00:10:52,280 +الأرض له فقال النبي عليه الصلاة والسلام هذا الحديث + +90 +00:10:52,280 --> 00:11:03,720 +فلمّا سمعبكى وتعانق فقال عليه الصلاة والسلام اقتسم + +91 +00:11:03,720 --> 00:11:11,640 +الأرض بينكما هكذا هي أخلاق الإسلام لأنهم يعلمون أن + +92 +00:11:11,640 --> 00:11:21,140 +الدنيا لا تغنى عن الآخرة وأنها دار ممر والآخرة دار + +93 +00:11:21,140 --> 00:11:27,770 +مقروأن الله يعطي الدنيا ويعطي المال لمن يحب ولمن + +94 +00:11:27,770 --> 00:11:33,490 +لا يحب أما الآخرة فلا يعطيها الله إلا لمن يحب + +95 +00:11:33,490 --> 00:11:41,270 +سبحانه وتعالى نعم الآن أعزائي الطلاب نكون وقد + +96 +00:11:41,270 --> 00:11:48,190 +انتهينا من المبحث الثالث من الفصل التمهيدي وهو كما + +97 +00:11:48,190 --> 00:11:55,770 +أسلفنا بعنوان خصائص النظمالإسلامية بدءا بالربانية + +98 +00:11:55,770 --> 00:12:05,430 +ومرورا بالثبات والمرونة والتكامل والتوازن + +99 +00:12:05,430 --> 00:12:09,890 +والواقعية والمثالية والعالمية + +100 +00:12:11,970 --> 00:12:18,470 +الجزاء الأخروي الآن نرحل بصحبتكم إلى المبحث الرابع + +101 +00:12:18,470 --> 00:12:23,850 +والأخير من المباحث الفصل التمهيدي اذا الفصل + +102 +00:12:23,850 --> 00:12:29,770 +التمهيدي هو عبارة عن مباحث أربعة بدءا بالمبحث + +103 +00:12:29,770 --> 00:12:35,600 +الأول وهو بانوان تعريف النظم لغة واصطلاحاالمبحث + +104 +00:12:35,600 --> 00:12:39,960 +الثاني بعنوان حاجة المجتمعات إلى النظم الإسلامية + +105 +00:12:39,960 --> 00:12:46,660 +المبحث الثالث وهو الأكبر بعنوان خصائص النظم + +106 +00:12:46,660 --> 00:12:54,160 +الإسلامية وهي سمانية كما ذكرناوأخيرا المبحث الرابع + +107 +00:12:54,160 --> 00:13:02,800 +وهو بعنوان مصادر النظم الإسلامية وهنا لنا وقفة قبل + +108 +00:13:02,800 --> 00:13:11,240 +الولوج في المصادر فنقول وبالله التوفيق بأن مصادر + +109 +00:13:11,240 --> 00:13:17,440 +النظم الإسلامية أو مصادر الشريعة الإسلامية أو + +110 +00:13:17,440 --> 00:13:26,240 +مصادرالفقه الإسلامي نوعان مصادر متفق عليها بين أهل + +111 +00:13:26,240 --> 00:13:32,600 +الألم و هي المصادر المطلوبة منكم و هي الأربعة فقط + +112 +00:13:32,600 --> 00:13:40,200 +أولا القرآن الكريم و ثانيا الصنة النبوية الشريفة و + +113 +00:13:40,200 --> 00:13:50,070 +ثالثا الإجماع و رابعا القياسومن أجل العلم نقول بأن + +114 +00:13:50,070 --> 00:13:58,250 +هناك مصادر اختلف فيها الفقهاء وهي ليست مطلوبة منكم + +115 +00:13:58,250 --> 00:14:03,570 +إنما هي مطلوبة من أهل التخصص في كلية الشريعة + +116 +00:14:03,570 --> 00:14:08,430 +والقانون في الجامعة الإسلامية مثل الاستصحاب + +117 +00:14:10,700 --> 00:14:17,960 +وقد أخذ به الشافعية والاستحسان وقد أخذ به الحنفية + +118 +00:14:17,960 --> 00:14:26,760 +ومثل عمل أهل المدينة وقد أخذ به الإمام مالك نعم + +119 +00:14:26,760 --> 00:14:35,000 +وهكذا المصادر الأخرى كالعرف ومذهب + +120 +00:14:35,000 --> 00:14:45,150 +الصحابيوشرع من قبلنا و سد الزراعيات لماذا قلت هذه + +121 +00:14:45,150 --> 00:14:55,130 +المقدمة للإجابة على سؤالين نعم قد تأتي هذه الأسئلة + +122 +00:14:55,130 --> 00:15:01,030 +في الإمتحانات فإذا ما قلنا إن مصادر النظم + +123 +00:15:01,030 --> 00:15:05,670 +الإسلامية أربعة فالإجابة + +124 +00:15:06,520 --> 00:15:15,600 +خطأ وليست صحيحة لأن المصادر ليست أربعة فقط المصادر + +125 +00:15:15,600 --> 00:15:20,920 +المتفق عليها عند أهل العلم هي أربعة فقط الكتاب + +126 +00:15:20,920 --> 00:15:26,460 +والسنة والإجماع والقياس ولكن هناك مصادر أخرى مختلف + +127 +00:15:26,460 --> 00:15:35,430 +عليها فإذا قلنا مثلا يعتبر العرفأحد مصادر النظم + +128 +00:15:35,430 --> 00:15:42,310 +الإسلامية الإجابة صحيحة أو مثلا يُعتبر صد الذرائع + +129 +00:15:42,310 --> 00:15:52,070 +أو يُعتبر قول الصحابي أو مذهب الصحابي أو هكذا من + +130 +00:15:52,070 --> 00:15:59,230 +المصادر المختلف عليها من مصادرأو أحد مصادر النظم + +131 +00:15:59,230 --> 00:16:06,190 +الإسلامية فالإجابة صحيحة بمعنى لا يصح لنا أن نحصر + +132 +00:16:06,190 --> 00:16:13,270 +مصادر النظم في أربعة فقط أو في حسب لأن الأربعة هي + +133 +00:16:13,270 --> 00:16:19,210 +المتفق عليها وهناك مصادر أخرى أخذ بها بعض العلماء + +134 +00:16:19,210 --> 00:16:24,870 +وتركها لبعض الآخر ولكنها تعتبر أيضا من المصادر + +135 +00:16:25,850 --> 00:16:31,090 +نستدل هنا على هذه المصادر بقوله تبارك وتعالى يا + +136 +00:16:31,090 --> 00:16:37,390 +أيها الذين آمنوا أطيعوا الله وأطيعوا الرسول وأقول + +137 +00:16:37,390 --> 00:16:43,680 +الأمر منكم أطيعوا الله أي في كتابهفي القرآن الكريم + +138 +00:16:43,680 --> 00:16:50,840 +و أطيع الرسول أي في صنته الشريفة كما سنأتي إليها + +139 +00:16:50,840 --> 00:17:01,100 +من قول أو فعل أو تقرير صلى الله عليه و سلم نعم و + +140 +00:17:01,100 --> 00:17:09,580 +في الحديث أيضا و هو الحديث عن سيدنا معاذ بن جبللما + +141 +00:17:09,580 --> 00:17:15,640 +أرسله النبي عليه الصلاة والسلام إلى اليمن قاضيا + +142 +00:17:15,640 --> 00:17:24,280 +وواليا وداعية إلى الإسلام أراد النبي عليه الصلاة + +143 +00:17:24,280 --> 00:17:31,480 +والسلام أن يعلمه القضاء فقال يا معاذ بما تحكم إذا + +144 +00:17:31,480 --> 00:17:37,220 +عرض لك قضاء قال يا رسول الله أقضي بكتاب الله عز + +145 +00:17:37,220 --> 00:17:43,910 +وجللماذا بكتاب الله؟ بعتباره المصدر الأولى من + +146 +00:17:43,910 --> 00:17:50,710 +مصادر الإسلام أو النظم الإسلامية فقال عليه الصلاة + +147 +00:17:50,710 --> 00:17:56,730 +والسلام فإن لم تجد بكتاب الله قال فبصنة رسول الله + +148 +00:17:56,730 --> 00:18:05,430 +صلى الله عليه وسلم بعتبارها المصدر الثاني من مصادر + +149 +00:18:05,430 --> 00:18:11,130 +النظم الإسلاميةثم قال عليه الصلاة والسلام إن لم + +150 +00:18:11,130 --> 00:18:15,510 +تجد بسنة رسول الله فقال محيط بن جبل يا رسول الله + +151 +00:18:15,510 --> 00:18:22,590 +اجتهد رأي ولا قاله ما معنى قوله ولا قاله أي لا + +152 +00:18:22,590 --> 00:18:30,990 +أدخر وسعًا أو لا أقصر في اصطنباط الأحكام الشرعية + +153 +00:18:30,990 --> 00:18:38,170 +من أدلتها التفصيليةنعم ماذا نلحظ في هذا الحديث + +154 +00:18:38,170 --> 00:18:45,110 +نلحظ شيئا مهما لأني ذكرت قبل قليل أن المصادر + +155 +00:18:45,110 --> 00:18:52,110 +المتفقة عليها أربعة الكتاب والصناة والإجماع + +156 +00:18:52,110 --> 00:19:01,470 +والقياس وهنا ذكر ثلاثة ذكر القرآنوهو المصدر الأول + +157 +00:19:01,470 --> 00:19:07,890 +وذكر الصنة وهي المصدر الثاني وذكر الاجتهاد وهو + +158 +00:19:07,890 --> 00:19:15,170 +القياس وهو المصدر الرابع فأين المصدر الثالث؟ وهو + +159 +00:19:15,170 --> 00:19:21,710 +الإجماعللإجابة على هذا نقول وهو سؤال مهم قد يأتيكم + +160 +00:19:21,710 --> 00:19:31,190 +في الامتحانات أن الإجماع شرطه وفاة الرسول صلى الله + +161 +00:19:31,190 --> 00:19:37,330 +عليه وسلم نعم لا إجماع في حياة الرسول صلى الله + +162 +00:19:37,330 --> 00:19:45,510 +عليه وسلمو سيأتي معنى تعريف الإجماع بنوعيه الصريح + +163 +00:19:45,510 --> 00:19:55,590 +والسكوتي و سنلحظ ذلك عند قراءة المصطلح الإجماع هو + +164 +00:19:55,590 --> 00:20:02,810 +اتفاق المجتهدين من أمة محمد عليه الصلاة والسلام + +165 +00:20:02,810 --> 00:20:10,210 +بعد وفاة الرسولونضع خطا هنا تحت قولنا بعد وفاة + +166 +00:20:10,210 --> 00:20:15,230 +الرسول عليه الصلاة والسلام في أي عصر من العصور + +167 +00:20:15,230 --> 00:20:21,170 +فالإجماع ماضى إلى يوم القيامة حتى في أيامنا هذه + +168 +00:20:21,170 --> 00:20:26,510 +الإجماع ماضى إلى يوم القيامة نعم + +169 +00:20:28,800 --> 00:20:35,900 +في مسألة أو في واقعة لم يرد فيها نص من كتاب أو سنة + +170 +00:20:35,900 --> 00:20:43,540 +وسنأتي إلى شرح ذلك في محاضرة تالية إذا أحيان الله + +171 +00:20:43,540 --> 00:20:49,760 +وشاء الله تبارك وتعالى إذا اتفق الصحابة في عهد + +172 +00:20:49,760 --> 00:20:57,970 +الرسول على شيء هل هذا يسمىإجماع هذا لا يسمى إجماع + +173 +00:20:57,970 --> 00:21:04,770 +وإنما يُسمى صنة تقريرية فالنبي عليه الصلاة والسلام + +174 +00:21:04,770 --> 00:21:10,270 +رأى خالد ابن الوليد يأكل الضب النبي عليه الصلاة + +175 +00:21:10,270 --> 00:21:18,530 +والسلام لم يأكل الضب ليس لأنه حرام ولكن عافته نفسه + +176 +00:21:19,430 --> 00:21:24,810 +نعم والضب هو عبارة عن حيوان صحراوي موجود حتى الآن + +177 +00:21:24,810 --> 00:21:30,830 +ويُصطاد في شبه الجزيرة العربية وهو أشبه ما يكون + +178 +00:21:30,830 --> 00:21:37,870 +بالتمساح الصغير فهو حلال ويؤكل والنبي عليه الصلاة + +179 +00:21:37,870 --> 00:21:42,370 +والسلام لما رأى خالد بن الوليد يأكل الضب أقره على + +180 +00:21:42,370 --> 00:21:50,440 +ذلك فهذا الحكم لا يسمى إجماعالأنه في حياة الرسول + +181 +00:21:50,440 --> 00:21:56,260 +صلى الله عليه وسلم وإنما يسمى صنة تقريرية وكما + +182 +00:21:56,260 --> 00:22:02,180 +سيأتي بعد قليل أن الصنة أنواع ثلاثة صنة قولية وصنة + +183 +00:22:02,180 --> 00:22:11,610 +فعلية وصنة تقريرية إذا وصلنا الآنبتوفيق الله عز + +184 +00:22:11,610 --> 00:22:20,050 +وجل إلى المصدر الأول من مصادر النظم الإسلامية وهو + +185 +00:22:20,050 --> 00:22:27,070 +القرآن الكريم مصدر المصادر وكليه الشريعة كما تلونا + +186 +00:22:27,070 --> 00:22:32,300 +على حضراتكم من صورة النساءقوله تبارك وتعالى يا + +187 +00:22:32,300 --> 00:22:37,840 +أيها الذين آمنوا أطيع الله و أطيع الرسول و أولي + +188 +00:22:37,840 --> 00:22:46,620 +الأمر منكم أطيع الله في كتابه و هو المصدر الأول و + +189 +00:22:46,620 --> 00:22:51,680 +أطيع الرسول في صنته عليه الصلاة والسلام و هو + +190 +00:22:51,680 --> 00:22:58,700 +المصدر الثاني و أولي الأمر منكم و هم الوالات أو + +191 +00:22:58,700 --> 00:23:07,030 +الحكاموالعلماء لكن هنا ملحوظة مهمة وهي أن طاعة أول + +192 +00:23:07,030 --> 00:23:16,210 +الأمر لا تكون طاعة عمياء في كل ما يأمرون به أو + +193 +00:23:16,210 --> 00:23:23,850 +ينهون عنه لأن طاعتهم مرهونة بطاعة الله تبارك + +194 +00:23:23,850 --> 00:23:30,660 +وتعالى وطاعة رسول الله صلى الله عليه وسلمبدليل أن + +195 +00:23:30,660 --> 00:23:34,340 +الله قال يا أيها الذين آمنوا أطيعوا الله و أطيعوا + +196 +00:23:34,340 --> 00:23:40,100 +الرسول و أولي الأمر منكم منكم يعني من المؤمنين + +197 +00:23:40,100 --> 00:23:46,580 +فإذا كان أولي الأمر من غير المؤمنين كاليهود + +198 +00:23:46,580 --> 00:23:55,780 +والنصارى كما نرى في هذه الأيام فلا تصح ولايتهمنعم + +199 +00:23:55,780 --> 00:24:01,660 +وليه يجعل الله للكافرين على المؤمنين سبيلا لأن + +200 +00:24:01,660 --> 00:24:07,380 +الولاء لهم يعتبر كفرا والعياذ بالله كما قال الله + +201 +00:24:07,380 --> 00:24:14,980 +ومن يتولهم منكم فإنه منهم من اليهود أو من النصارى + +202 +00:24:14,980 --> 00:24:19,740 +والعياذ بالله والدليل على ذلك قوله عقب ذلك مباشرة + +203 +00:24:19,740 --> 00:24:28,910 +فإن تنازعتم في شيء فردوهإلى الله والرسول إن كنتم + +204 +00:24:28,910 --> 00:24:35,630 +تؤمنون بالله واليوم الآخر ذلك خير وأحسن تأويل صدق + +205 +00:24:35,630 --> 00:24:43,010 +الله العظيم أين أول الأمر لم يعد لهم ذكر فعند + +206 +00:24:43,010 --> 00:24:50,800 +خلافنا معقول الأمر نرجع إلى الأصلنرجع إلى الكتاب + +207 +00:24:50,800 --> 00:24:56,800 +وإلى الصنة فإن تنازعتم في شيء فاردوه إلى الله + +208 +00:24:56,800 --> 00:25:05,940 +والرسول ولم يقل وإلى أولي الأمر منكم ما هو القرآن + +209 +00:25:05,940 --> 00:25:16,540 +الكريم القرآن الكريم يمكن تعريفه كما يليه القرآن + +210 +00:25:16,540 --> 00:25:23,620 +الكريمكلام الله عز وجل المنزل باللغة العربية + +211 +00:25:23,620 --> 00:25:31,760 +بوساطة جبريل عليه السلام أمين السماء على محمد بن + +212 +00:25:31,760 --> 00:25:41,620 +عبد الله أمين الأرض والسماء وهو المتعبد بتلاوته + +213 +00:25:41,620 --> 00:25:47,460 +المنقول إلينا بالتواتر + +214 +00:25:49,700 --> 00:26:03,240 +وهو المعجز بأقصر صورة منهم هذا باختصار من خلال هذا + +215 +00:26:03,240 --> 00:26:12,140 +التعريف يمكن أن نستنبط خواص القرآن الكريم من خلال + +216 +00:26:12,140 --> 00:26:18,620 +التعريف ومن خلال هذا المصطلحلتعريف القرآن الكريم + +217 +00:26:18,620 --> 00:26:25,300 +يمكن أن نستنبط خواص القرآن الكريم أول هذه الخواص + +218 +00:26:25,300 --> 00:26:35,420 +أنه من عند الله وليس كما قال الكفار في عهد قريش أن + +219 +00:26:35,420 --> 00:26:42,400 +النبي يعلمه بشر وأن هذا القرآن نزل باللغة العربية + +220 +00:26:44,390 --> 00:26:50,230 +لأن المعجزة إنما تكون من نفس ما نبغى فيه القوم في + +221 +00:26:50,230 --> 00:26:55,950 +عهد موسى عليه السلام نبغى القوم في السحر في عهد + +222 +00:26:55,950 --> 00:27:03,690 +الفراعنة المصريين فكانت المعجزة اليد و العصة التي + +223 +00:27:03,690 --> 00:27:13,580 +أكلت سعابينهم المزيفة وهي ليست سعابين حقيقةوإنما + +224 +00:27:13,580 --> 00:27:20,300 +هي أنبيب كما قيل ملئة بالذئبق و أوقد تحتها النار + +225 +00:27:20,300 --> 00:27:29,780 +فكانت تتلوى فخدعوا الناس و أعين الناس فظنوها + +226 +00:27:29,780 --> 00:27:35,080 +سعابين وما هي بسعابين أما عصى موسى فكان سعبانا + +227 +00:27:35,670 --> 00:27:42,050 +حقيقيًا أكل عصيهم جميعًا وفي عهد عيسى عليه السلام + +228 +00:27:42,050 --> 00:27:47,510 +نبغى القوم في الطب فكان عيسى يحيي الموت بإذن الله + +229 +00:27:47,510 --> 00:27:55,830 +وكان يبرق الأكمه والأبرز والأكمه لا يستطيع أحد + +230 +00:27:55,830 --> 00:28:04,590 +شفاءه ما هو الأكمه؟ الأكمه هو الذي ولد من بطن أمه + +231 +00:28:04,590 --> 00:28:13,500 +أعمىو ثم كفرق بين الأكمه والأعمى فالأعمى قد يولد + +232 +00:28:13,500 --> 00:28:21,400 +مبصرا ثم بعد ذلك يصاب في عينيه فيفقد بصره وهذا قد + +233 +00:28:21,400 --> 00:28:27,080 +يعود إلى الإبصار و قد يكون له علاج أو شفاء أما + +234 +00:28:27,080 --> 00:28:32,840 +الأكمه فلا يكون له شفاء أبدا لأنه ولد من بطن أمه + +235 +00:28:32,840 --> 00:28:40,840 +أعمى فكانسيدنا عيسى عليه السلام يبرئ الأكمه بإذن + +236 +00:28:40,840 --> 00:28:46,460 +الله والأبرص كذلك وفي عهد النبي عليه الصلاة + +237 +00:28:46,460 --> 00:28:53,080 +والسلام وفي عهد قريش والعرب قد نبغوا بالفصاحة + +238 +00:28:53,080 --> 00:29:00,060 +والبلاغة واللسان ولذلك قال الله تبارك وتعالىمثلا + +239 +00:29:00,060 --> 00:29:07,700 +في صدر صورة يوسف إن أنزلناه قرآن عربي لعلكم تعقلون + +240 +00:29:07,700 --> 00:29:15,560 +وفي صورة الزمر كما هي آية الكتاب إن أنزلنا عليك + +241 +00:29:15,560 --> 00:29:22,880 +الكتاب للناس بالحق فمن اهتدى فلنفسه فهو كلام الله + +242 +00:29:22,880 --> 00:29:33,400 +المنزل باللغة العربيةولذلك جاءت صور القرآن مفتتحة + +243 +00:29:33,400 --> 00:29:41,740 +بالحروف مثل ألف لام ميم و مثل كاف ها يا عين صاد و + +244 +00:29:41,740 --> 00:29:48,440 +مثل حاميم و هكذا ما معنى هذه الحروف الرأي الراجح + +245 +00:29:48,440 --> 00:29:54,800 +فيها و الله أعلى و أعلم أن الله يتحداهم و يقول لهم + +246 +00:29:54,800 --> 00:30:02,490 +أيها العربأو يا معشر قريش يا من اشتهرت بالبلاغة + +247 +00:30:02,490 --> 00:30:11,850 +والفساحة وكانت لهم أسواق ليست للبضايع وإنما ينشدون + +248 +00:30:11,850 --> 00:30:18,950 +فيها الشعر مثل عكاز ومجنى وذل مجاز وكانت القصيدة + +249 +00:30:18,950 --> 00:30:26,290 +التي تفوز تعلق على أسطار الكعبةلنفاستها مثل شعري + +250 +00:30:26,290 --> 00:30:31,870 +الخنساء وعنطرة وزهير + +251 +00:30:31,870 --> 00:30:39,090 +بن أبي صلمة وغيرهم من الشعراء فسميت بالمعلقات + +252 +00:30:39,090 --> 00:30:44,810 +السابعة او المعلقات العشرة كما في الأدب العربي + +253 +00:30:44,810 --> 00:30:52,460 +كانت تعلق على أسطار الكعبة فهذا أول معرضللشعر + +254 +00:30:52,460 --> 00:30:58,420 +العربي عرفاه العرب قبل الإسلام لذا نزل القرآن بلغة + +255 +00:30:58,420 --> 00:31:07,260 +العرب ألف لا ميم ان هذا القرآن بلسانكم وبلغتكم فإن + +256 +00:31:07,260 --> 00:31:12,480 +كنتم كما تزعمون أهل فصاحة وبيان وبلاغة ولسان + +257 +00:31:12,480 --> 00:31:20,910 +فاتبوا مثل هذا القرآن طبعا لم يستطيعوا ولنيستطيعوا + +258 +00:31:20,910 --> 00:31:27,770 +لأن القرآن كلام الله وهو معجز نعم قُلْ لأن اجتمعت + +259 +00:31:27,770 --> 00:31:32,010 +الإنس والجن على أن يأتوا بمثل هذا القرآن لا يأتون + +260 +00:31:32,010 --> 00:31:39,790 +بمثله و لو كان بعضهم لبعضٍ ظاهرة ثم تحدهم و نزل + +261 +00:31:39,790 --> 00:31:47,460 +التحدي إلى عشر صور مفتريات من مثلهفلم يأتوا و لن + +262 +00:31:47,460 --> 00:31:54,160 +يأتوا ثم نزل التحدي كما في صدر صورة البقرة في + +263 +00:31:54,160 --> 00:32:00,600 +الربع الأول بصورة من مثله حتى قال الله فإن لم + +264 +00:32:00,600 --> 00:32:05,540 +تفعلوا و لن تفعلوا فاتقوا النار التي وقودها الناس + +265 +00:32:05,540 --> 00:32:12,320 +و الحجارة قعدت للكافرين فالقرآن الكريم هو المعجز + +266 +00:32:12,320 --> 00:32:25,670 +بأقصر صورة منهمولم يقول بأقصر حرف أو بأقصر كلمة + +267 +00:32:25,670 --> 00:32:32,870 +لأنه باستطاعتهم أن يأتوا بكلمة بل أقول لن يستطيعوا + +268 +00:32:32,870 --> 00:32:42,750 +أن يأتوا بآية نعم ما هي أكبر صورة في القرآن إنها + +269 +00:32:42,750 --> 00:32:48,980 +صورة البقرةما هي أصغر صورة في القرآن؟ إنها صورة + +270 +00:32:48,980 --> 00:32:56,820 +الكوثر إن أعطيناك الكوثر ما هي أكبر آية في القرآن؟ + +271 +00:32:56,820 --> 00:33:02,920 +آية البقرة، آية الدين في أواخر صورة البقرة ما هي + +272 +00:33:02,920 --> 00:33:11,930 +أقصر آية في القرآن؟إنها قوله تبارك وتعالى طاها نعم + +273 +00:33:11,930 --> 00:33:17,810 +والإعجاز الذي نزل به القرآن الكريم هو الإعجاز + +274 +00:33:17,810 --> 00:33:24,890 +البياني الإعجاز اللغوي نعم اليوم تطرق العلم الحديث + +275 +00:33:24,890 --> 00:33:30,310 +وهذا لدعوة غير المسلمين إلى الإسلام في أوروبا + +276 +00:33:30,310 --> 00:33:37,510 +وأمريكا وهو الإعجاز العلمي في القرآن الكريمنعم و + +277 +00:33:37,510 --> 00:33:44,170 +هناك الإعجاز الغيبى و هناك الإعجاز العددي و هناك + +278 +00:33:44,170 --> 00:33:48,650 +الإعجاز التشريعى و هناك الإعجاز الاجتماعى ولكن + +279 +00:33:48,650 --> 00:33:56,050 +الإعجاز الذي جاء به القرآن الكريم في عهد النبوة هو + +280 +00:33:56,050 --> 00:34:03,770 +الإعجاز اللغوي نعم الذي عجزت العرب أن تأتي كما + +281 +00:34:03,770 --> 00:34:11,790 +قلنا بمثله ولا بعشرصور من مثله و لا بصورة من مثله + +282 +00:34:11,790 --> 00:34:22,430 +سبحانه وتعالى نثبت أيضا من خلال التعريف أن هذا + +283 +00:34:22,430 --> 00:34:29,470 +القرآن الكريم متعبد بتلاوته بمعنى أنه تصح قراءته + +284 +00:34:29,470 --> 00:34:36,030 +في الصلاة أما الأحاديث القدسية والأحاديث النبوية + +285 +00:34:38,150 --> 00:34:43,670 +فلا يصح قراءتها في الصلاة مع أن الأحاديث القدسية + +286 +00:34:43,670 --> 00:34:49,430 +ما كانت من عند الله معنا و من عند رسول الله مبنا + +287 +00:34:49,430 --> 00:34:55,810 +أو لفظا لأنهم فرقوا بين القرآن و بين الأحاديث + +288 +00:34:55,810 --> 00:35:03,080 +القدسية و الأحاديث النبوية فالأحاديثالقدسية ما + +289 +00:35:03,080 --> 00:35:07,820 +كانت من عند الله معنا و من عند رسول الله لفظا او + +290 +00:35:07,820 --> 00:35:13,360 +مبنا او صياغة و لذلك ليست معجزة اما الأحاديث + +291 +00:35:13,360 --> 00:35:18,660 +النبوية ما كانت من عند الله ما كانت عفوا من عند + +292 +00:35:18,660 --> 00:35:25,040 +رسول الله عليه الصلاة والسلام لفظا و معنا و اقول + +293 +00:35:25,040 --> 00:35:29,780 +كل ما صدر عن رسول الله من عند الله كما قال الله + +294 +00:35:29,780 --> 00:35:36,420 +تعالىوما ينطق عن الهوى إن هو إلا وحي اليوحى علمه + +295 +00:35:36,420 --> 00:35:41,180 +شديد القوة صلى الله عليه وسلم إذا القرآن متعمد + +296 +00:35:41,180 --> 00:35:46,800 +بتلاوة بمعنى أنه يقرأ في الصلاة وكما سيأتي معنى في + +297 +00:35:46,800 --> 00:35:53,420 +مساق الفقه الإسلامي لا تصح الصلاة بغير صورة + +298 +00:35:53,420 --> 00:35:59,010 +الفاتحةكما جاء في الحديث لا صلاة لمن لم يقرأ + +299 +00:35:59,010 --> 00:36:11,250 +بفاتحة الكتاب أو بأم الكتاب كذلك القرآن عند مسه + +300 +00:36:11,250 --> 00:36:19,230 +يحتاج إلى طهارة من الحدثين الأكبر والأصغر وهذا ما + +301 +00:36:19,230 --> 00:36:24,520 +ذهب إليه الشافعيةكما قال الله تبارك وتعالى لا يمسه + +302 +00:36:24,520 --> 00:36:31,080 +إلا المطهرون وكما جاء في الأحاديث النبوية لا يمس + +303 +00:36:31,080 --> 00:36:37,660 +القرآن إلا طاهر والشافعية قال هنا بطهارة الإنسان + +304 +00:36:37,660 --> 00:36:44,400 +من الحدثين الأكبر و الأصغر نعم بمعنى أنه يكون + +305 +00:36:44,400 --> 00:36:52,260 +مغتسلامن جنابة أو احتلام وأن يكون متوضئا بعد الحدث + +306 +00:36:52,260 --> 00:37:01,060 +الأصغر من بول وغائط وريح ونحو ذلك كذلك يمكن أن + +307 +00:37:01,060 --> 00:37:08,020 +نستنبط من التعريف أن ترجمة القرآن الكريم مهما كانت + +308 +00:37:08,020 --> 00:37:18,410 +دقيقة فإنها لا تعتبر قرآناولا تنسحب عليها أحكام + +309 +00:37:18,410 --> 00:37:25,250 +القرآن الكريم ومن ثم لا تصح الصلاة بها ولا تشترط + +310 +00:37:25,250 --> 00:37:33,050 +الطهارة لقراءتها لأنها ليست من كلام الله وإنما هي + +311 +00:37:33,050 --> 00:37:41,170 +من كلام البشر إذا ترجمة القرآن مهما كانت دقيقة + +312 +00:37:43,290 --> 00:37:51,350 +ومهما بلغت دقتها لا تكون قرآنا ولا تعتبر قرآنا ولا + +313 +00:37:51,350 --> 00:37:57,730 +تنسحب عليها ونسأل ما معنى تنسحب عليها أي لا تنطبق + +314 +00:37:57,730 --> 00:38:04,110 +عليها أحكام القرآن فلا يصح قراءة الترجمة في الصلاة + +315 +00:38:04,110 --> 00:38:11,160 +نعم كمالا تحتاج عند قراءتها إلى طهارة كما أسلفنا + +316 +00:38:11,160 --> 00:38:18,620 +في القرآن الكريم من الحدثين الأصغر والأكبر ولذلك + +317 +00:38:18,620 --> 00:38:26,900 +أعجبت بالمصاحف التي ترجمت ماذا قالوا فيهاترجمت + +318 +00:38:26,900 --> 00:38:33,700 +معاني الفاظ القرآن الكريم وهذه عبارة في الحقيقة في + +319 +00:38:33,700 --> 00:38:39,280 +غاية الدقة ترجمت معاني الفاظ القرآن الكريم إذا ليس + +320 +00:38:39,280 --> 00:38:44,680 +المترجم هو القرآن إنما هي المعاني ما معنى المعاني + +321 +00:38:44,680 --> 00:38:49,840 +يعني التفسير التفسير هو المترجم وليس هو القرآن + +322 +00:38:49,840 --> 00:38:56,100 +الكريم لأن القرآنكلام الله تبارك وتعالى كذلك يمكن + +323 +00:38:56,100 --> 00:39:04,480 +أن نستنبط أن القرآن الكريم وصلنا بالتواتر ما معنى + +324 +00:39:04,480 --> 00:39:12,520 +التواتر؟ معنى له جمع عن جمع جماعة عن جماعة بحيث + +325 +00:39:12,520 --> 00:39:21,450 +يستحيل اتفاقهم على الكذب أو تواطؤهم على الكذبوهذا + +326 +00:39:21,450 --> 00:39:26,170 +بخلاف الأحاديث القدسية والنبوية فهي ما وصلت إلينا + +327 +00:39:26,170 --> 00:39:32,190 +عبر خبر الأعحاد وخبر الأعحاد ما رواه فرد عن فرد + +328 +00:39:32,190 --> 00:39:38,190 +شخص عن شخص بخلاف القرآن فقد وصل إلينا عبر التواتر + +329 +00:39:38,190 --> 00:39:44,910 +وهو ما رواه جماعة عن جماعة كذلك يستنبط من التعريف + +330 +00:39:44,910 --> 00:39:53,000 +أيضًا أن القرآن مع أنه معجزإلا أنه سهل فهمه ولا + +331 +00:39:53,000 --> 00:39:59,480 +يصعب حفظه واصطنباط الأحكام منه والدليل على ذلك + +332 +00:39:59,480 --> 00:40:04,500 +قوله تبارك وتعالى في موضع عينيه ولقد يسرنا القرآن + +333 +00:40:04,500 --> 00:40:10,340 +للذكر فهل من مدكر؟ وقوله فإنما يسرناه بلسانك لعلهم + +334 +00:40:10,340 --> 00:40:17,360 +يتذكرون وأخيرانختم بأن هذا القرآن تكفل الله بحفظه + +335 +00:40:17,360 --> 00:40:22,160 +على خلاف التوراة والإنجيل فقد عهد الله إلى بني + +336 +00:40:22,160 --> 00:40:27,140 +إسرائيل بحفظها فغيروا وبدلوا كما قال الله فويل + +337 +00:40:27,140 --> 00:40:31,390 +للذين يكتبون الكتاب بإيدهمثم يقولون هذا من عند + +338 +00:40:31,390 --> 00:40:35,970 +الله ليشتروا به ثمنا قليلة فويل الله مما كتبت + +339 +00:40:35,970 --> 00:40:40,130 +أيديهم وويل أمهم وويل الله مما يكسبون أما القرآن + +340 +00:40:40,130 --> 00:40:45,090 +فهو كلام الله تكفر الله بحفظه إلى يوم يبعثون إلى + +341 +00:40:45,090 --> 00:40:50,070 +أن يرث الله الأرض من عليها كما قال تعالى إنا نحن + +342 +00:40:50,070 --> 00:40:55,800 +نزلنا الذكرى وإنا له الحافظون صدق الله العظيمنكون + +343 +00:40:55,800 --> 00:41:00,540 +إن شاء الله وإن أحيان الله في المحاضرة التالية على + +344 +00:41:00,540 --> 00:41:09,680 +موعد مع المبحث الرابع ثانيا الصنة النبوية وثالثا + +345 +00:41:09,680 --> 00:41:15,800 +الإجماع بنوعيه الصريح والسكوتي ورابعا القياس + +346 +00:41:15,800 --> 00:41:22,240 +وبعدها نرحل إلى الفصل الثاني وهو العبادة ونترك + +347 +00:41:22,670 --> 00:41:28,250 +الفصل الأول وهو العقيدة لأنه غير مطلوب في الامتحان + +348 +00:41:28,250 --> 00:41:34,550 +لأنه سيشرح لكم في كلية أصول الدين في شرح أصول + +349 +00:41:34,550 --> 00:41:38,490 +العقيدة الإسلامية للدكتور ناسيم ياسين وصل اللهم + +350 +00:41:38,490 --> 00:41:43,050 +على سيدنا محمد والسلام عليكم ورحمة الله وبركاته + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/CqZkhoI6MR4.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/CqZkhoI6MR4.srt new file mode 100644 index 0000000000000000000000000000000000000000..30ac494850d14cac0be05e4b9b8ea7dd3cda58e9 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/CqZkhoI6MR4.srt @@ -0,0 +1,1519 @@ +1 +00:00:05,090 --> 00:00:07,550 +أعوذ بالله السميع العليم من الشياطين الرجيم بسم + +2 +00:00:07,550 --> 00:00:11,130 +الله الرحمن الرحيم الحمد لله والصلاة والسلام على + +3 +00:00:11,130 --> 00:00:15,230 +رسول الله اللهم صل على سيدنا محمد وعلى آله وصحبه + +4 +00:00:15,230 --> 00:00:19,890 +وسلم أجمعين أعزائي الطلاب قبل ذي بدء وفي بداية + +5 +00:00:19,890 --> 00:00:23,970 +محاضرة جديدة ونرحب بكم جميعا وأحييكم بتحية + +6 +00:00:23,970 --> 00:00:28,110 +الإسلام العظيم فالسلام عليكم ورحمة الله وبركاته + +7 +00:00:28,110 --> 00:00:32,030 +بعد أن أنهينا من الفصل الثاني وهو بعنوان العبارة في + +8 +00:00:32,030 --> 00:00:37,230 +الإسلام، نرحل بصحبتكم إلى الفصل الثالث وهو بعنوان + +9 +00:00:37,230 --> 00:00:43,470 +نظام الأخلاقي في الإسلام وسوف نتعرض في هذا الفصل + +10 +00:00:43,470 --> 00:00:49,190 +إلى مباحثه ثلاثة على بركة الله، المبحث الأول تعريف + +11 +00:00:49,190 --> 00:00:56,120 +الأخلاق في اللغة والاصطلاح، والمراحل التي يمر بها + +12 +00:00:56,120 --> 00:01:02,600 +توجيه الخلق في النفس الإنسانية إيجابا أو سلبا، أما + +13 +00:01:02,600 --> 00:01:06,380 +المبحث الثاني فهو بعنوان خصائص نظام الأخلاق في + +14 +00:01:06,380 --> 00:01:10,840 +الإسلام، أما المبحث الثالث فهو بعنوان عناية الإسلام + +15 +00:01:10,840 --> 00:01:15,900 +بالأخلاق وأثرها في النفس الإنسانية. + +16 +00:01:19,090 --> 00:01:24,910 +أما المبحث الأول وهو بعنوان تعريف الأخلاق فإن + +17 +00:01:24,910 --> 00:01:32,710 +الأخلاق في اللغة بمعنى السجية أو الطبيعة، أي الخصلة + +18 +00:01:32,710 --> 00:01:39,330 +التي يتصف بها الإنسان، تقول فلان سجيته أو طبيعته + +19 +00:01:39,330 --> 00:01:47,290 +الصدق، أي أن الصدق صفة فيه، وكذلك قد تكون أيضا + +20 +00:01:47,290 --> 00:01:53,460 +سلبية، نحن عندما نتكلم في باب الأخلاق، وهذه ملحوظة + +21 +00:01:53,460 --> 00:01:59,660 +بين يدي الشرح، لا نتكلم عن الأخلاق الإيجابية التي + +22 +00:01:59,660 --> 00:02:05,000 +عناها أمير الشعراء شوقي، إنما الأمم الأخلاق ما بقيت + +23 +00:02:05,000 --> 00:02:10,780 +فإن هم ذهبت أخلاقهم ذهبون، أو الخلق في مدح الرسول + +24 +00:02:10,780 --> 00:02:16,090 +عليه الصلاة والسلام، وإنك لعلا خلق عظيم، لأننا سنتكلم + +25 +00:02:16,090 --> 00:02:21,870 +عن الأخلاق بنوعيه، الأخلاق الإيجابية كالصدق + +26 +00:02:21,870 --> 00:02:27,250 +والأمانة والوفاء والشجاعة ونحو ذلك، وسوف نتكلم إن + +27 +00:02:27,250 --> 00:02:32,910 +شاء الله عن الأخلاق السلبية مثل الكذب والغدر + +28 +00:02:32,910 --> 00:02:42,350 +والخيانة ونحو ذلك من الأخلاق السلبية، فقد يقال أيضا + +29 +00:02:42,350 --> 00:02:49,620 +فلان سجيته الكذب، أي أن الكذب صفة فيه، نعم، إذا + +30 +00:02:49,620 --> 00:02:58,120 +الأخلاق في لغة العرب جمع الخلق وهي تعني السجية أو + +31 +00:02:58,120 --> 00:03:08,020 +الطبيعة، يقال فلان سجيته الصدق أو فلان سجيته الكذب + +32 +00:03:08,020 --> 00:03:13,860 +على نوعي الأخلاق التي سنأتي إلى ذكرها وضرب الأمثلة + +33 +00:03:14,670 --> 00:03:20,290 +عليها، أما الأخلاق في الاصطلاح فهي هيئة راسخة في + +34 +00:03:20,290 --> 00:03:28,690 +النفس، تصدر عنها الأفعال بسهولة ويسر من غير حاجة + +35 +00:03:28,690 --> 00:03:36,150 +إلى فكر أو روية، هذا هو المصطلح المطلوب في الامتحان، + +36 +00:03:36,150 --> 00:03:44,440 +الأخلاق في الاصطلاح هيئة راسخة في النفس تصدر عنها + +37 +00:03:44,440 --> 00:03:53,000 +الأفعال بسهولة ويسر من غير حاجة إلى فكرة أو روية. + +38 +00:03:53,000 --> 00:03:57,740 +نأتي إلى بعض المعاني من خلال هذا التعريف، فالأخلاق + +39 +00:03:57,740 --> 00:04:06,710 +هيئة راسخة، بمعنى أنها مستقرة في النفس البشرية أو + +40 +00:04:06,710 --> 00:04:13,970 +النفس الإنسانية، بمعنى أنها فطرة في هذا الإنسان، و + +41 +00:04:13,970 --> 00:04:20,770 +هذه الأخلاق طبعا قد تكون إيجابية وقد تكون سلبية. + +42 +00:04:20,770 --> 00:04:29,370 +وهنا يترتب على هذا الكلام أمر مهم وهو أنه لا يقال + +43 +00:04:29,370 --> 00:04:38,470 +عن فلان صادق إلا إذا تكرر منه الصدق، فلو صدق مرة أو + +44 +00:04:38,470 --> 00:04:46,330 +مرتين لا يقال عنه صادق، وكذلك لو كذب مرة أو مرتين + +45 +00:04:46,330 --> 00:04:54,050 +لا يقال عنه كاذب، فلا يقال عنه كاذب حتى يتكرر منه + +46 +00:04:54,050 --> 00:05:04,850 +الكذب وتصبح هذه الخصلة جزء من كيانه، فالأخلاق هيئة + +47 +00:05:04,850 --> 00:05:12,130 +راسخة مستقرة في النفس البشرية أو الإنسانية، تصدر + +48 +00:05:12,130 --> 00:05:21,070 +عنها الأفعال بسهولة ويسر، نعم، دون تفكير مسبق ودون + +49 +00:05:21,070 --> 00:05:30,250 +إعداد، فلو زعم الصدق وهو في الحقيقة كاذب، سرعان ما + +50 +00:05:30,250 --> 00:05:42,160 +يظهر عليه ذلك، وكذلك لا يحتاج إلى فكر أو روية، فإن + +51 +00:05:42,160 --> 00:05:49,480 +الخلق إذا احتاج إلى فكر أو روية لا يسمى خلقا. + +52 +00:05:49,480 --> 00:05:57,080 +انتبهوا إلى هذا المعنى، فهذا موضع سؤال في الامتحان. + +53 +00:05:57,080 --> 00:06:08,340 +إذا ما جاءك سؤال في صح أو خطأ، أن الأخطاء نعم التي + +54 +00:06:08,340 --> 00:06:18,140 +يقع فيها الإنسان تحتاج إلى فكر و روية حتى يتجنبها + +55 +00:06:18,140 --> 00:06:26,560 +فهذه لا تسمى أخلاقا، فالأخلاق ما صدرت عن النفس + +56 +00:06:26,560 --> 00:06:37,600 +بسهولة ويصدر من داخله، من كيانه، من أعماقه دون حاجة + +57 +00:06:37,600 --> 00:06:45,600 +إلى فكر أو روية، فإذا تروى أو فكر فإن ذلك لا يكون + +58 +00:06:45,600 --> 00:06:53,040 +خلقا وإنما يكون تمثيلا كما نرى من بعض المنافقين أو + +59 +00:06:53,040 --> 00:06:58,540 +الكاذبين والعياذ بالله الذين يزعمون الصدق + +60 +00:06:58,540 --> 00:07:03,480 +والأمانة والإخلاص والشجاعة وهم في الحقيقة على خلاف + +61 +00:07:03,480 --> 00:07:09,620 +ذلك، إذا نخرج من هذا التعريف بمعلومتين مهمتين. + +62 +00:07:09,620 --> 00:07:18,760 +المعلومة الأولى أنه لا يتصف فلان بخلق ما سواء كان + +63 +00:07:18,760 --> 00:07:26,840 +هذا الخلق إيجابا أو كان سلبا إلا إذا تكرر منه هذا + +64 +00:07:26,840 --> 00:07:34,670 +الخلق، أقول مرة أخرى، فلو أنه صدق مرة أو مرتين فلا + +65 +00:07:34,670 --> 00:07:42,770 +يقال عنه صادق حتى يتكرر منه خلق الصدق، وكذلك + +66 +00:07:42,770 --> 00:07:50,850 +بالنسبة للأخلاق السلبية، فلو أنه كذب مرة أو مرتين + +67 +00:07:50,850 --> 00:07:59,320 +فإنه لا يقال عنه كاذب حتى يتكرر منه هذا الخلق + +68 +00:07:59,320 --> 00:08:07,440 +السلبي، نعم، وأما ثانيا فإن الأخلاق لا تحتاج إلى + +69 +00:08:07,440 --> 00:08:17,840 +فكر أو روية لأنها تصدر من الشخص بكل سهولة ويسر. + +70 +00:08:18,600 --> 00:08:24,820 +نأتي الآن إلى العنوان الثاني وهو يترتب على التعريف + +71 +00:08:24,820 --> 00:08:31,420 +مراحل توجيه الخلق في النفس الإنسانية إيجابا أو + +72 +00:08:31,420 --> 00:08:40,080 +سلبا، فإن هذه المراحل ثلاثة، المرحلة الأولى التأثر + +73 +00:08:40,080 --> 00:08:44,200 +بالخير والشر، المرحلة + +74 +00:08:46,140 --> 00:08:53,520 +الثانية رسوخ هذا الخلق من خير أو شر في النفس + +75 +00:08:53,520 --> 00:09:00,680 +الإنسانية واستقراره فيها، ثالثا انعكاس هذا الخلق + +76 +00:09:00,680 --> 00:09:05,500 +على سلوك الإنسان وتصرفاته. + +77 +00:09:07,090 --> 00:09:13,210 +إذا، المراحل التي يمر بها توجيه الخلق في النفس + +78 +00:09:13,210 --> 00:09:21,670 +الإنسانية أو النفس البشرية، مراحل ثلاثة، وكل مرحلة + +79 +00:09:21,670 --> 00:09:27,490 +من هذه المراحل تعتمد على ما قبلها، إذا لابد أن تحفظ + +80 +00:09:27,490 --> 00:09:36,830 +هذه المراحل مرتبة، فأول هذه المراحل التأثر بالخير أو + +81 +00:09:36,830 --> 00:09:42,350 +الشر، ماذا يترتب على هذه المرحلة؟ المرحلة الثانية + +82 +00:09:42,350 --> 00:09:51,630 +وهي رسوخ هذا الخلق من خير أو شر واستقراره في النفس + +83 +00:09:51,630 --> 00:10:00,170 +الإنسانية، ويترتب على هذا أيضا المرحلة الثالثة وهي + +84 +00:10:00,170 --> 00:10:06,150 +انعكاس هذا الخلق على تصرفات هذا الشخص وعلى + +85 +00:10:06,150 --> 00:10:14,170 +سلوكيته، إذا قلت لابد أن تحفظ هذه المراحل مرتبة لأنه + +86 +00:10:14,170 --> 00:10:19,530 +قد يأتيكم سؤال، مثلا التأثر بالخير أو الشر يعتبر + +87 +00:10:19,530 --> 00:10:24,630 +المرحلة الثانية من مراحل توجيه الخلق في النفس + +88 +00:10:24,630 --> 00:10:30,250 +البشرية وهذا خطأ، أو استقرار هذا الخلق إيجابا أو + +89 +00:10:30,250 --> 00:10:35,960 +سلبا يعتبر المرحلة الثالثة وهو المرحلة الثانية، + +90 +00:10:35,960 --> 00:10:41,760 +فانتبهوا إلى هذه المراحل واحفظوها مرتبة، أما التأثر + +91 +00:10:41,760 --> 00:10:48,720 +بالخير أو الشر وهو المرحلة الأولى فإنما يعود إلى + +92 +00:10:48,720 --> 00:10:56,840 +خلق الإنسان وأنه إنسان ضعيف، وقد جاء القرآن الكريم + +93 +00:10:56,840 --> 00:11:03,450 +بهذه الحقيقة، وخلق الإنسان ضعيف، فهذا الإنسان الضعيف + +94 +00:11:03,450 --> 00:11:12,230 +قد يتأثر بالبيئة التي حوله من خير ومن شر، كما قال + +95 +00:11:12,230 --> 00:11:17,570 +الله تبارك وتعالى: "زين للناس حب الشهوات من النساء + +96 +00:11:17,570 --> 00:11:23,890 +والبنين والقناطير المقنطرة من ذهب وفضة والخيل + +97 +00:11:23,890 --> 00:11:29,170 +المسومة والأنعام والحرث، ذلك متاع الحياة الدنيا، + +98 +00:11:29,170 --> 00:11:36,710 +والله عنده حسن المآب"، فهذه كلها من زينة الحياة + +99 +00:11:36,710 --> 00:11:47,030 +الدنيا من النساء والأموال من ذهب وفضة وخيل مسومة + +100 +00:11:47,030 --> 00:11:52,890 +بمنزلة السيارات والحافلات في هذه الأيام، وكذلك + +101 +00:11:53,690 --> 00:12:01,990 +المزارع من الأنعام والحرث، فهذه كلها سلاح ذو حدين، + +102 +00:12:01,990 --> 00:12:08,650 +إما أن تكون في طاعة الله وإما أن تكون في معصية + +103 +00:12:08,650 --> 00:12:17,090 +الله، فالزوجة سلاح ذو حدين، والأولاد سلاح ذو حدين، إن + +104 +00:12:17,090 --> 00:12:24,130 +من أزواجكم وأولادكم عدوا لكم فاحذروهن، نعم، فالمال و + +105 +00:12:24,130 --> 00:12:30,850 +الذرية زينة الحياة الدنيا، والباقيات الصالحات خير + +106 +00:12:30,850 --> 00:12:38,730 +عند ربك ثوابا وأعظم أجرا، فإياك أن تقع في المعصية + +107 +00:12:38,730 --> 00:12:47,660 +وأنت تستعمل هذه النعم التي قد تكون نقمة في معصية + +108 +00:12:47,660 --> 00:12:53,880 +الله تبارك وتعالى، وكذلك حذرنا الله تبارك وتعالى من + +109 +00:12:53,880 --> 00:13:00,220 +الحياة الدنيا ومن الشيطان الرجيم حتى لا نقع في + +110 +00:13:00,220 --> 00:13:05,580 +حمق الرذيلة، فالله تبارك وتعالى يقول: "فلا تغررنكم + +111 +00:13:05,580 --> 00:13:12,070 +الحياة الدنيا، ولا يغررنكم بالله الغرور"، طبعا هذه هي + +112 +00:13:12,070 --> 00:13:19,330 +الأدلة من القرآن الكريم في الكتاب المقرر، لكن يمكن + +113 +00:13:19,330 --> 00:13:24,710 +أن نخرج عن الكتاب ونأتي بأدلة أخرى عن تأثر هذا + +114 +00:13:24,710 --> 00:13:31,320 +الإنسان بالبيئة التي عيشها والتي يحياها، ولذا عليه + +115 +00:13:31,320 --> 00:13:38,960 +الحذر حتى لا يستهويه الشيطان، وأعني بالشيطان شيطان + +116 +00:13:38,960 --> 00:13:46,080 +الإنس قبل شيطان الجن، لأن شيطان الإنس أخطر من شيطان + +117 +00:13:46,080 --> 00:13:51,700 +الجن، كما قال الله تعالى: "شياطين الإنس والجن يوحي + +118 +00:13:51,700 --> 00:13:56,520 +بعضهم إلى بعض زخرف القول غرورا"، ورسول الله عليه + +119 +00:13:56,520 --> 00:14:01,040 +الصلاة والسلام قال: "كل مولود يولد على الفطرة، يولد + +120 +00:14:01,040 --> 00:14:05,780 +على الفطرة، يولد على التوحيد وعلى العقيدة الإسلامية + +121 +00:14:05,780 --> 00:14:13,320 +فأبواه يهودانه إن كان يعيش في بيئة + +122 +00:14:13,320 --> 00:14:20,720 +يهودية أو ينصرانه إن كان يعيش في بيئة نصرانية، أو + +123 +00:14:20,720 --> 00:14:28,780 +يمجسانه إن كان يعيش في بيئة مجوسية، نعم، فالإنسان + +124 +00:14:28,780 --> 00:14:37,440 +بسبب ضعفه قد يتأثر بالبيئة التي يحيى فيها، وكذلك + +125 +00:14:37,440 --> 00:14:42,680 +حذرنا النبي عليه الصلاة والسلام من صاحب السوق، فمن + +126 +00:14:42,680 --> 00:14:49,350 +قديم قالوا: "الصاحب بالصادق صاحب بالصين، إما إلى طريق + +127 +00:14:49,350 --> 00:14:55,630 +الخير وإما إلى طريق الشر"، وضرب لنا مثال على ذلك، + +128 +00:14:55,630 --> 00:15:05,570 +فالصاحب الخير والجليس الصالح مثل حامل المسك، إما أن + +129 +00:15:05,570 --> 00:15:15,400 +يعطيك وإما أن تشم منه رائحة عطرة عبقة طيبة، أما جليس + +130 +00:15:15,400 --> 00:15:23,840 +السوق الفاسق الفاجر والعياذ بالله، فمثله كمثل نافخ + +131 +00:15:23,840 --> 00:15:29,520 +الكير وهو الحداد، إما أن تطير شرارة فتحرق ثيابك + +132 +00:15:29,520 --> 00:15:36,880 +وإما أن تشم رائحة خبيثة منتنة، فالبيئة التي يعيش + +133 +00:15:36,880 --> 00:15:44,710 +فيها الإنسان فعلا قد يتأثر فيها من خير ومن شر، فعلى + +134 +00:15:44,710 --> 00:15:50,050 +الإنسان المسلم أن يلجأ إلى البيئة الصالحة وإلى + +135 +00:15:50,050 --> 00:15:56,750 +الصحبة الصالحة، إلى بيوت الله من أجل الصلاة ومن + +136 +00:15:56,750 --> 00:16:04,110 +أجل قراءة القرآن، نعم، ومن أجل قراءة الأوراد + +137 +00:16:04,780 --> 00:16:10,460 +والمأثورات حتى يبقى على اتصال بربه تبارك وتعالى. + +138 +00:16:10,460 --> 00:16:16,320 +وأختم بهذا الحديث الصحيح طبعا الذي مر معنا في أكثر + +139 +00:16:16,320 --> 00:16:20,240 +من موضوعات، قد يذكر هذا الحديث عن بني إسرائيل في + +140 +00:16:20,240 --> 00:16:27,220 +باب التوبة وكيف أن الله قد غفر له وقتل مائة نفس. + +141 +00:16:27,220 --> 00:16:36,710 +قتل تسعًا وتسعين نفسًا ثم قتل الراهب كذلك يستدلوا + +142 +00:16:36,710 --> 00:16:41,630 +ويستشهدوا بهذا الحديث أيضًا في باب العلم كما في موضع + +143 +00:16:41,630 --> 00:16:46,650 +آخر فقيه واحد أشد على الشيطان من ألف عبد لكن أنا + +144 +00:16:46,650 --> 00:16:52,730 +اليوم استشهد بهذا الحديث في باب البيئة البيئة + +145 +00:16:52,730 --> 00:16:58,550 +الصالحة والبيئة الفاسدة وملخص هذا الحديث كما + +146 +00:16:58,550 --> 00:17:04,310 +تعلمون أن شخصًا في بني إسرائيل قتل تسعًا وتسعين نفسًا + +147 +00:17:04,310 --> 00:17:09,750 +ثم أراد أن يتوب فسأل راهبًا هل لي من التوبة قال له + +148 +00:17:09,750 --> 00:17:14,130 +ليس لك من التوبة وقد قتلت تسعًا وتسعين نفسًا فقتله + +149 +00:17:14,130 --> 00:17:20,680 +فأكمل بقتله المائة نفسًا ثم سأل عالمًا وهنا نقول + +150 +00:17:20,680 --> 00:17:25,780 +الفرق كبير والبون شاسع بين العالم الفقيه وبين + +151 +00:17:25,780 --> 00:17:33,500 +العابد الجاهل فمن عبد الله على جهل فكأنما عصاه نعم + +152 +00:17:33,500 --> 00:17:38,400 +فسأل هذا العالم فقال له طب إلى الله من يحول بينك + +153 +00:17:38,400 --> 00:17:43,840 +وبين الله فأبواب السماء مفتوحة وأبواب التوبة + +154 +00:17:43,840 --> 00:17:49,980 +لا تُغلق أبدًا وربنا غفور رحيم يغفر الذنب ويقبل + +155 +00:17:49,980 --> 00:17:55,340 +التوبة ويعفو عن كثير المهم أن هذا الرجل تاب إلى + +156 +00:17:55,340 --> 00:18:02,880 +الله و لكن العالم نصحه أن يخرج من هذا البلد لأنها + +157 +00:18:02,880 --> 00:18:08,220 +بيئة سوء هذا هو الشاهد في القصة لأن الإنسان قد + +158 +00:18:08,220 --> 00:18:13,340 +يتأثر بالخير وقد يتأثر بالشر فهذه البيئة كانت + +159 +00:18:13,340 --> 00:18:19,920 +بيئته شر وفساد وفجور ولا عياذ بالله فتحرك الرجل + +160 +00:18:19,920 --> 00:18:25,040 +وقبل أن يصل إلى منتصف الطريق قبضه الله تبارك + +161 +00:18:25,040 --> 00:18:29,960 +وتعالى فنهاية القصة تقول بأن الملائكة قد اختلفوا + +162 +00:18:29,960 --> 00:18:34,730 +فيهم ملكة الرحمة تقول هو في الجنة لأنه جاء تائبًا + +163 +00:18:34,730 --> 00:18:40,250 +وملكة العذاب تقول هو في النار لأنه قتل مائة نفس + +164 +00:18:40,250 --> 00:18:46,470 +فأرسل الله إليهم ملكًا يحكم بينهم قال نقيص المسافة + +165 +00:18:46,470 --> 00:18:51,750 +إن كان إلى أرض الصلاح أقرب فهو إلى الجنة وإن كان + +166 +00:18:51,750 --> 00:18:55,810 +إلى أرض الفساد أقرب فهو إلى النار وهو لم يصل بعد + +167 +00:18:55,810 --> 00:19:02,240 +إلى أرض الصلاح فكان إلى أرض الفساد أقرب فأمر الله + +168 +00:19:02,240 --> 00:19:08,940 +أرض الصلاح أن تقربي وأرض الفساد أن تبعدي فلما + +169 +00:19:08,940 --> 00:19:13,980 +قاسوا المسافة كان إلى أرض الصلاح أقرب فأدخله الله + +170 +00:19:13,980 --> 00:19:18,840 +الجنة القصة طبعًا في صحيح مسلم وهي طويلة تذكر في + +171 +00:19:18,840 --> 00:19:22,720 +أبواب العلم وفي أبواب التوبة وذكرته هنا في باب + +172 +00:19:22,720 --> 00:19:31,240 +البيئة لأن هذا العالم الفقيه أمر هذا القاتل الذي + +173 +00:19:31,240 --> 00:19:38,150 +هداه الله إلى التوبة وشرح صدره أن يخرج من بيئة + +174 +00:19:38,150 --> 00:19:45,970 +الفساد إلى بيئة الصلاح نعم، إذا هذه هي أول المراحل + +175 +00:19:45,970 --> 00:19:51,850 +التي يمر بها توجيه الخلق في النفس الإنسانية وهو + +176 +00:19:51,850 --> 00:19:59,410 +التأثر بالخير أو الشر أما ثانيًا وقلت كلها مرتبة + +177 +00:19:59,410 --> 00:20:07,190 +بعضها على بعض فإن المرحلة الثانية وهي رسوخ الخير أو + +178 +00:20:07,190 --> 00:20:13,290 +الشر لماذا نقول هنا الخير أو الشر لأن الحديث عن + +179 +00:20:13,290 --> 00:20:19,710 +الأخلاق بنوعيها الأخلاق الإيجابية ويرمز لها بالخير + +180 +00:20:21,840 --> 00:20:28,080 +والأخلاق السلبية ويرمز لها بالشر فالإنسان إذا ما + +181 +00:20:28,080 --> 00:20:33,340 +تأثر بالخير أو الشر فإن هذا الخلق من خير أو شر + +182 +00:20:33,340 --> 00:20:42,630 +يرسخ ويستقر في نفس هذا الإنسان نعم والدليل على ذلك + +183 +00:20:42,630 --> 00:20:48,990 +عندنا في الكتاب دليلان من السنة النبوية أما الدليل + +184 +00:20:48,990 --> 00:20:53,450 +الأول فهو قوله عليه الصلاة والسلام مروا أولادكم + +185 +00:20:53,450 --> 00:20:59,930 +بالصلاة لسبع سنين واضربوهم عليها لعشر سنين وفرقوا + +186 +00:20:59,930 --> 00:21:07,770 +بينهم في المضاجع بمعنى أن الإنسان لابد أن يعود + +187 +00:21:07,770 --> 00:21:18,050 +صغاره وأن يعوض أطفاله منذ سبع سنين حتى يدرك لأنه + +188 +00:21:18,050 --> 00:21:24,170 +قبل سبع سنين لا يكون مدركًا لا يفرق بين الطهارة + +189 +00:21:24,170 --> 00:21:30,750 +وبين النجاسة لكن بعد سبع سنين قد يتدرب وهنا نقول + +190 +00:21:30,750 --> 00:21:38,820 +من ناحية الفقهية لا يُطالب الطفل بوجوب الصلاة أو صوم + +191 +00:21:38,820 --> 00:21:48,520 +أو حج قبل البلوغ لأن البلوغ هو شرط التكليف كما جاء + +192 +00:21:48,520 --> 00:21:53,300 +في الحديث الذي سبق ذكره رفع القلم عن ثلاثة من + +193 +00:21:53,300 --> 00:22:00,550 +النائم حتى يستيقظوا عن المجنون حتى يعقل وعن الصبي + +194 +00:22:00,550 --> 00:22:07,030 +حتى يبلغ أو يحتلم ولكن قبل أن يصل إلى سن البلوغ + +195 +00:22:07,030 --> 00:22:16,450 +لابد أن يتدرب وأن يتمرن هذا الطفل على الصلاة وعلى + +196 +00:22:16,450 --> 00:22:24,210 +الصيام فلو صلى صحت صلاته ولو صام صحت صومه ولو حج + +197 +00:22:24,210 --> 00:22:30,710 +حتى ولو لم يبلغ يصح حجه ولكنه لا يُطالب بذلك كما + +198 +00:22:30,710 --> 00:22:36,310 +قلت وجوبًا إنما يستحب ذلك استحبابًا من باب التدريب + +199 +00:22:36,560 --> 00:22:43,660 +ومن باب التمرين كما جاء في الشعر العربي وينشأ ناشئ + +200 +00:22:43,660 --> 00:22:50,640 +الفتيان فينا على ما كان عوده أبوه لأنه يتأثر كما + +201 +00:22:50,640 --> 00:22:55,850 +قلنا في المرحلة الأولى بالبيئة وأول هذه البيئة هي + +202 +00:22:55,850 --> 00:23:01,950 +الأبوان وبعد ذلك الشارع والمجتمع وبعد ذلك + +203 +00:23:01,950 --> 00:23:12,070 +المدرسة أو الكلية والجامعة نعم وإذا كان صغيرًا فإنه + +204 +00:23:12,070 --> 00:23:18,830 +مثل الأقصان الصغيرة صرعان ما تلينه في يديك فإذا ما + +205 +00:23:18,830 --> 00:23:29,310 +يبثت فإنه يصعب تلينها وتمرينها فإنها تكسر كما قال + +206 +00:23:29,310 --> 00:23:35,150 +الشعر العربي إن الغصون إذا قومتها اعتدلت ولن تلين + +207 +00:23:35,150 --> 00:23:41,890 +إذا قومتها الخشب وقد قالوا في وصف عدي بن حاتم وقد + +208 +00:23:41,890 --> 00:23:48,190 +كان أبوه حاتم يضرب به المثل في الجودة وفي الكرم + +209 +00:23:48,190 --> 00:23:55,800 +كما نعلم وقد جاءه يومًا ليلاً ضيوف فلم يجد من البعير + +210 +00:23:55,800 --> 00:24:01,760 +والغنم فذبح لهم فرسه التي كانت بمنزلة سيارة أو + +211 +00:24:01,760 --> 00:24:06,920 +حافلة في هذه الأيام فقال الشعر العربي يمدح عدي بن + +212 +00:24:06,920 --> 00:24:14,410 +حاتم بأبه اقتدى عدي في الكرم ومي شابه أبه فما ظلموا + +213 +00:24:14,410 --> 00:24:20,930 +هذا يتطلب كما قلنا التمرين والتدريب والتعويد منذ + +214 +00:24:20,930 --> 00:24:25,710 +الصغر، لذا قال عليه الصلاة مروا أولادكم بالصلاة + +215 +00:24:25,710 --> 00:24:33,260 +لسبع سنين قبل أن يتأثروا بالأفكار الدخيلة من + +216 +00:24:33,260 --> 00:24:39,120 +علمانية أو شيوعية ونحو ذلك بسبب كبر سنهم و + +217 +00:24:39,120 --> 00:24:45,140 +دخولهم الجامعات واختلاطهم بالناس واضربوهم عليها + +218 +00:24:45,140 --> 00:24:51,160 +إذا بلغوا عشر سنين وفرقوا بينهم في المضاجع لأن + +219 +00:24:51,160 --> 00:24:57,300 +الشهوة قد تدب فيهم بعد عشر سنوات فلابد أن يكون لكل + +220 +00:24:57,300 --> 00:25:03,810 +طفل فرشة ولحاف أو سرير ومعنى هذا الحديث أن لا + +221 +00:25:03,810 --> 00:25:10,350 +يغطى ولدان بلحاف واحد أو بنتان بلحاف واحد فلكل + +222 +00:25:10,350 --> 00:25:17,570 +فرشة ولحاف أو حتى إن كان هناك مال سرير ولحاف + +223 +00:25:17,570 --> 00:25:25,050 +مستقل عن شقيقه عند النوم نعم وكذلك قوله عليه الصلاة + +224 +00:25:25,050 --> 00:25:31,030 +والسلام في الحديث الذي يبين فيه الرسول عليه الصلاة + +225 +00:25:31,030 --> 00:25:38,410 +والسلام نوعين من الخلق الخلق الإيجابي ويتمثل + +226 +00:25:38,410 --> 00:25:47,180 +بالصدق والخلق السلبي ويتمثل بالكذب نعم هكذا يقول + +227 +00:25:47,180 --> 00:25:53,840 +عليه الصلاة والسلام وإن الرجل لا يصدق ويتحرى الصدق + +228 +00:25:53,840 --> 00:26:02,900 +نعم قفوا عند هذه الكلمة لعله في الكتاب خطأ مطبعي + +229 +00:26:02,900 --> 00:26:08,240 +ويتحرى الصدق الصدق ليست موجودة في الكتاب ولكنها + +230 +00:26:08,240 --> 00:26:18,450 +موجودة في الحديث وإن الرجل لا يصدق ويتحرص صدق حتى + +231 +00:26:18,450 --> 00:26:24,890 +يُكتب عند الله صديقًا وصديق على وزن فعيل من صيغ + +232 +00:26:24,890 --> 00:26:32,630 +المبالغة وهذا يؤكد ما ذهبنا إليه عند التعريف ما هو + +233 +00:26:32,630 --> 00:26:39,710 +تعريف الأخلاق هيئة راسخة يعني مستقرة في النفس + +234 +00:26:39,710 --> 00:26:47,510 +البشرية أو الإنسانية تصدر عنها الأفعال بسهولة ويسر + +235 +00:26:47,510 --> 00:26:52,910 +والمقصود بالأفعال هنا الأخلاق إما إيجابية كالصدق + +236 +00:26:54,010 --> 00:27:01,490 +وإما سلبية كالكذب من غير حاجة إلى فكر أو روية فهي + +237 +00:27:01,490 --> 00:27:06,810 +فعلًا كما قالت العرب في تعريف الخلق الطبيعة أو + +238 +00:27:06,810 --> 00:27:13,150 +السجية أو العادة فلو دخل شخص من أهل الصدق فإنه + +239 +00:27:13,150 --> 00:27:17,470 +يشار إليه بالبنان جاء الصادق الأمين وقد قيل ذلك في + +240 +00:27:17,470 --> 00:27:22,700 +حق الرسول عليه السلام قبل البعثة بسنوات خمس عندما + +241 +00:27:22,700 --> 00:27:29,420 +اختلفوا في رفع الحجر الأسود الأسعد نعم عندما رأوه + +242 +00:27:29,420 --> 00:27:32,980 +وقد اشتهر النبي عليه السلام بهذا الجد جاء الصادق + +243 +00:27:32,980 --> 00:27:40,400 +الأمين محمد وقد حكم بينهم ورضي الجميع وحق ندمه صلى + +244 +00:27:40,400 --> 00:27:45,820 +الله عليه وسلم ولو اشتهر شخص بالكذب أيضًا فإن الكذب + +245 +00:27:45,820 --> 00:27:54,450 +يصدر عنه دون فكر أو روية أو تأن أو تفكير بالصدق + +246 +00:27:54,450 --> 00:28:01,110 +كما يقولون نعم هكذا هو الأخلاق تصدر عنها الأفعال + +247 +00:28:01,110 --> 00:28:07,130 +بنوعها الإيجابية والسلبية من غير حاجة إلى فكر أو + +248 +00:28:07,130 --> 00:28:16,170 +روية وقلت أيضًا بأن خلقًا ما لا يُوصف به شخص ما إلا + +249 +00:28:16,170 --> 00:28:23,500 +إذا تكرر منه هذا الخلق فلو صدق مرة أو مرتين لا يُقال + +250 +00:28:23,500 --> 00:28:32,380 +عنه صادق حتى يصبح هذا الخلق فيه سجية أو طبيعة أو + +251 +00:28:32,380 --> 00:28:39,510 +عادة فيه تكلف كما أسلفنا وكذلك لو كذب مرة أو مرتين + +252 +00:28:39,510 --> 00:28:45,930 +لا يُقال عنه كاذب حتى يصبح هذا الخلق سجية فيه أو + +253 +00:28:45,930 --> 00:28:54,210 +طبيعة أو عادة ويتكرر منه وهذا يؤيده الحديث الذي + +254 +00:28:54,210 --> 00:29:02,620 +بين أيدينا إن الرجل لا يصدق ويتحرى ضعوا خطأ تحته + +255 +00:29:02,620 --> 00:29:09,040 +ويتحرى الصدق حتى يُكتب عند الله صديقًا صديق على وزن + +256 +00:29:09,040 --> 00:29:14,280 +فعيل من صير المبالغة أو من أبنية المبالغة كما يقول + +257 +00:29:14,280 --> 00:29:22,590 +أهل اللغة وكذلك في الأخلاق السلبية يتصف شخص بخلق + +258 +00:29:22,590 --> 00:29:27,990 +سلبي كالكذب أو البخل أو الأنانية لغير ذلك التي + +259 +00:29:27,990 --> 00:29:31,730 +سنأتي إليها ضمن مجموعة الأخلاق الإيجابية والسلبية + +260 +00:29:31,730 --> 00:29:38,190 +حتى يتكرر منه هذا الخلق انظر أيضًا للحديث وإن الرجل + +261 +00:29:38,190 --> 00:29:46,540 +لا يكذب ويتحرى الكذب أيضًا ليس فيه هنا الكذب فهو + +262 +00:29:46,540 --> 00:29:53,860 +خطأ مطبعي في الكتاب انتبهوا إليه ويتحرى الكذب حتى + +263 +00:29:53,860 --> 00:30:01,360 +يُكتب عند الله كذابًا كذاب أيضًا على وزن فعال من + +264 +00:30:01,360 --> 00:30:07,960 +صيغ المبالغة نعم هذا ما أردنا أن نلفت الأنظار إليه + +265 +00:30:07,960 --> 00:30:15,640 +أما ثالثًا فكما قلت هذا نتيجة طبيعية للمرحلة الأولى + +266 +00:30:15,640 --> 00:30:21,080 +والمرحلة الثانية إذا المرحلة الأولى من مراحل توجيه + +267 +00:30:21,080 --> 00:30:26,500 +الخلق في النفس الإنسانية هو التأثر بالخير أو الشر + +268 +00:30:26,500 --> 00:30:32,180 +ينجم عن هذا التأثر بالخير أو الشر يعني بالأخلاق + +269 +00:30:32,180 --> 00:30:37,260 +الإيجابية أو بالأخلاق السلبية إن عكاس هذا الخلق + +270 +00:30:37,260 --> 00:30:45,620 +على سلوك الإنسان وتصرفاته بعد أن يستقر ويرسخ في + +271 +00:30:45,620 --> 00:30:55,560 +نفسه وفي أعماقه فلا يُقال عن فلان مثلًا كريم حتى يتصف + +272 +00:30:55,560 --> 00:31:01,880 +بهذا الكرم ولا يُقال أيضًا عن فلان بخيل حتى يتصف + +273 +00:31:01,880 --> 00:31:08,720 +بهذا الخلق إلا وهو المخلوق وهكذا جميع الأخلاق + +274 +00:31:08,720 --> 00:31:18,960 +إذا قلت ملحوظة مهمة جدًا وهي أن هذه المراحل قبل أن + +275 +00:31:18,960 --> 00:31:23,960 +نودعها ونرحل إلى غيرها لابد أن تُحفظ مرتبة + +276 +00:31:23,960 --> 00:31:29,280 +فالمرحلة الأولى التأثر بالخير أو الشر المرحلة + +277 +00:31:29,280 --> 00:31:35,520 +الثانية رسوخ هذا الخلق إيجابًا أو سلبًا واستقراره + +278 +00:31:35,520 --> 00:31:40,640 +في النفس البشرية أو الإنسانية ثالثًا ينجم عن ذلك + +279 +00:31:40,640 --> 00:31:49,780 +انعكاس هذا الخلق من خير ومن شر من صدق ومن كذب من + +280 +00:31:49,780 --> 00:31:57,280 +شجاعة ومن جبن من كرم ومن بخل إلى غير ذلك على + +281 +00:31:57,280 --> 00:32:05,660 +سلوك هذا الشخص و تصرفاته نعم هذا هو المبحث الأول + +282 +00:32:05,660 --> 00:32:13,030 +من مباحث نظام الأخلاق في الإسلام أما المبحث الثاني + +283 +00:32:13,030 --> 00:32:18,990 +فهو بعنوان خصائص نظام الأخلاق في الإسلام وسوف + +284 +00:32:18,990 --> 00:32:25,650 +نتعرض إلى خصائص خمسة أولا التعميم والتفصيل ثانيا + +285 +00:32:25,650 --> 00:32:35,150 +الشمول ثالثا أنها ضابط لسلوك الإنسان و تصرفاته + +286 +00:32:35,150 --> 00:32:41,310 +رابعا السواب و العقاب خامسا تلازمها مع الإيمان + +287 +00:32:41,310 --> 00:32:48,250 +بالله نبدأ اليوم بالتعميم و التفصيل و نأتي إلى + +288 +00:32:48,250 --> 00:32:55,660 +التعريف، التعميم ما هو مصطلح التعميم انتبهوا إلى + +289 +00:32:55,660 --> 00:33:04,320 +ذلك لعله لم يأتي كالعادة تعريف الأخلاق أو تعريف + +290 +00:33:04,320 --> 00:33:10,780 +العبادة أو تعريف النظم كما مر معنا وإنما جاءت ضمن + +291 +00:33:10,780 --> 00:33:17,820 +الكلام فيمكن أن نعرف التعميم في نظام الأخلاق بأنه + +292 +00:33:17,820 --> 00:33:25,770 +ورود الأخلاق على شكل قواعد عامة كلية، نعم هذا هو + +293 +00:33:25,770 --> 00:33:33,370 +تعريف التعميم، ورود الأخلاق على شكل قواعد عامة كلية + +294 +00:33:33,370 --> 00:33:39,990 +و سنأتي بعد قليل إلى ذكر المثال، أما التفصيل فهو + +295 +00:33:39,990 --> 00:33:48,930 +ورود الأخلاق على شكل جزئيات مفصلة، نعم أنا أرى + +296 +00:33:48,930 --> 00:33:55,970 +للأسف أخطاء مطبعية كثيرة، فانتبهوا إليها وأنا أصححها + +297 +00:33:55,970 --> 00:34:01,810 +لكم، فالطبعة الجديدة فيها أخطاء سأقف عندها عند + +298 +00:34:01,810 --> 00:34:07,820 +الوصول إليها، أما أمامي على الشاشة، على شكل جزئيات + +299 +00:34:07,820 --> 00:34:14,300 +منفصلة، هذا خطأ، على شكل جزئيات مفصلة، إذا ما هو + +300 +00:34:14,300 --> 00:34:20,360 +التعريف، إذا جاءكم في الامتحان ورود الأخلاق على شكل + +301 +00:34:20,360 --> 00:34:30,170 +قواعد عامة كلية فقولوا أنه التعميم، من خصائص نظام + +302 +00:34:30,170 --> 00:34:34,730 +الأخلاق في الإسلام، فإذا ما جاءت ورود الأخلاق على + +303 +00:34:34,730 --> 00:34:44,230 +شكل جزئيات مفصلة فقولوا أنها التفصيل، نعم نأتي الآن + +304 +00:34:44,230 --> 00:34:49,670 +إلى ضرب الأمثلة بخصوص القواعد العامة الكلية + +305 +00:34:49,670 --> 00:34:56,210 +ومثالها آيتان في كتاب الله، نقتصر على ما اقتصر عليه + +306 +00:34:56,210 --> 00:35:00,230 +الكتاب، أول هذه الآيات قوله تبارك وتعالى، وتعاونوا + +307 +00:35:00,230 --> 00:35:04,350 +على البر والتقوى ولا تعاونوا على الإثم والعدوان + +308 +00:35:04,350 --> 00:35:12,890 +ففي هذه الآية قواعد عامة كلية، البر والإثم والعدوان + +309 +00:35:12,890 --> 00:35:21,980 +فالبر أيضًا له مصطلح عندنا في الكتاب، اسم جامع لكل + +310 +00:35:21,980 --> 00:35:30,120 +عمل إيجابي يقوم به الإنسان تجاه غيره أو تجاه نفسه + +311 +00:35:30,120 --> 00:35:37,650 +ويندرج تحتهذه القاعدة العامة الكلية وهي البر كل + +312 +00:35:37,650 --> 00:35:43,550 +خلق إيجابي مثل الصدق ومثل الأمانة ومثل الكرم ومثل + +313 +00:35:43,550 --> 00:35:49,330 +الشجاعة ومساعدة الإنسان وبر الوالدين والعطف على + +314 +00:35:49,330 --> 00:35:54,050 +الأقارب وحب الأبناء والحنو عليهم والإنفاق على + +315 +00:35:54,050 --> 00:35:58,530 +الفقراء المصلي إلى غير ذلك من كف الأذى والعمل من أجل + +316 +00:35:58,530 --> 00:36:05,200 +الصالح العام، نعم هذا هو معنى البر، إذا ما هو مصطلح + +317 +00:36:05,200 --> 00:36:08,860 +البر، وهذا أيضًا من المصطلحات التي تأتيكم في + +318 +00:36:08,860 --> 00:36:16,660 +الامتحان، البر قاعدة عامة كلية وهو اسم جامع لكل + +319 +00:36:16,660 --> 00:36:24,560 +عمل إيجابي يقوم به الإنسان إما تجاه نفسه وإما تجاه + +320 +00:36:24,560 --> 00:36:28,340 +غيره، نعم وكذلك + +321 +00:36:30,530 --> 00:36:35,930 +الإثم والعدوان أيضًا قواعد عامة كلية ولكنها سلبية + +322 +00:36:35,930 --> 00:36:45,630 +فالاثم أيضًا هو اسم جامع لكل خلق سلبي يقوم به + +323 +00:36:45,630 --> 00:36:52,410 +الإنسان تجاه نفسه أو تجاه غيره مثل الكذب مثل + +324 +00:36:52,410 --> 00:37:02,390 +الخيانة مثل الغدر مثل الغش مثل الجبن مثل البخل مثل + +325 +00:37:02,390 --> 00:37:07,490 +عقوق الوالدين وأذية الناس إلى غير ذلك من مجموعة + +326 +00:37:07,490 --> 00:37:12,590 +الأخلاق السلبية التي سنأتي إلى ضرب أمثلة لها، و + +327 +00:37:12,590 --> 00:37:20,030 +كذلك العدوان هو قاعدة عامة كلية سلبية، نعم و هي + +328 +00:37:20,030 --> 00:37:27,350 +تشمل كل عدوان، فالعدوان قد يكون على الله و من يتعدى + +329 +00:37:27,350 --> 00:37:34,820 +حدود الله فقد ظلم نفسه بالكفر والشرك والإلحاد أو + +330 +00:37:34,820 --> 00:37:39,400 +بالمعصية والذنب والخطيئة، فهذا عدوان على الله، وقد + +331 +00:37:39,400 --> 00:37:44,600 +يكون العدوان على النفس وذلك بالانتحار، فالانتحار + +332 +00:37:44,600 --> 00:37:52,180 +أيضًا حرام وهو أخطر من قتل الغير لأنك لا تملك نفسك + +333 +00:37:52,180 --> 00:37:58,890 +فالنفس بنيان الله وصنعة الرب تبارك وتعالى فلا يجوز + +334 +00:37:58,890 --> 00:38:05,370 +لك أن تقتل نفسك أو أن تنتحر فهذا عدوان على النفس، و + +335 +00:38:05,370 --> 00:38:09,790 +كذلك العدوان على الآخرين، والعدوان على الآخرين إما + +336 +00:38:09,790 --> 00:38:13,710 +أن يكون بقتلهم + +337 +00:38:13,710 --> 00:38:21,260 +و إزهاق أرواحهم وإراقة دمائهم، أو بتر أعضائهم، وإما + +338 +00:38:21,260 --> 00:38:26,220 +أن يكون عدوانا على المال بغصب أرضهم أو سرقة + +339 +00:38:26,220 --> 00:38:30,080 +أموالهم، إذا هذه الآية الكريمة وتعاونوا على البر + +340 +00:38:30,080 --> 00:38:35,320 +والتقوى ولا تعاونوا على إثم العدوان، جمعت لنا قواعد + +341 +00:38:35,320 --> 00:38:40,000 +عامة كلية، يرمز إلى القاعدة العامة الكلية + +342 +00:38:40,000 --> 00:38:45,220 +الإيجابية بالبر، يرمز هنا إلى القاعدة العامة الكلية + +343 +00:38:45,220 --> 00:38:50,380 +السلبية بالإثم والعدوان، وكذلك ما قيل في الآية + +344 +00:38:50,380 --> 00:38:54,120 +الأولى، يقال في الآية الثانية وهي قوله تبارك وتعالى + +345 +00:38:54,120 --> 00:38:59,180 +يا أيها الذين آمنوا إذا تناجيتم فلا تتناجوا بالإثم + +346 +00:38:59,180 --> 00:39:04,260 +والعدوان ومعصية الرسول، وتناجوا بالبر والتقوى + +347 +00:39:04,260 --> 00:39:10,140 +واتقوا الله الذي إليه تحشرون، صدق الله العظيم، إن + +348 +00:39:10,140 --> 00:39:18,590 +شاء الله، نختم الآن بفوائد التعميم حتى نكون على موعد + +349 +00:39:18,590 --> 00:39:23,650 +في المحاضرة التالية، ما هي فوائد التعميم + +350 +00:39:23,650 --> 00:39:28,070 +التعميم في نظام الأخلاق في الإسلام له فائدة + +351 +00:39:28,070 --> 00:39:36,030 +الفائدة الأولى، وضع تصور عام عن نظام الأخلاق في + +352 +00:39:36,030 --> 00:39:42,610 +التشريع الإسلامي، نعم، وضع تصور عام عن نظام الأخلاق + +353 +00:39:42,610 --> 00:39:46,830 +في التشريع الإسلامي وبالتالي يسهل على المكلف + +354 +00:39:46,830 --> 00:39:55,990 +التعرف على أسس هذا النظام والإلمام به، دون مشقة أو + +355 +00:39:55,990 --> 00:40:01,410 +عناء، وخاصة من غير الإسلاميين الذين لا يريدون + +356 +00:40:01,410 --> 00:40:09,610 +محاضرات طويلة أو لا يريدون فصولاً وأشهرًا مثل فصول + +357 +00:40:09,610 --> 00:40:17,270 +الجامعة الإسلامية مثلا، وإنما يحتاجون إلى تصور عام + +358 +00:40:17,270 --> 00:40:21,310 +عن نظام الأخلاق في الإسلام، والنبي عليه السلام كان + +359 +00:40:21,310 --> 00:40:30,050 +يعلم الأعرابية الإسلام في ساعة واحدة، فيخرجوا داعية + +360 +00:40:30,050 --> 00:40:35,290 +إلى قومه، ومنه الحديث الأعرابي الحديث الصحيح الذي + +361 +00:40:35,290 --> 00:40:41,370 +رواه عمرو بن الخطاب عن سيدنا جبريل، نعم، وهذا الحديث + +362 +00:40:41,370 --> 00:40:50,860 +استغرق مجلدات عند شرحه، نعم، فجبريل يسأل والنبي يجيب + +363 +00:40:50,860 --> 00:40:56,040 +ما الإسلام، قال أن تشهد أن لا إله إلا الله وأن محمد + +364 +00:40:56,040 --> 00:41:01,480 +رسول الله، وأن تقيم الصلاة وأن تؤتي الزكاة وأن تصوم + +365 +00:41:01,480 --> 00:41:06,040 +رمضان وأن تحج البيت إن استطعت إليه سبيل الله، قال + +366 +00:41:06,040 --> 00:41:12,040 +ما الإيمان وأركانه الستة، أن تؤمن بالله وملائكته وكتبه + +367 +00:41:12,040 --> 00:41:17,220 +ورسله واليوم الآخر والقدر خيره وشره من الله، ثم قال + +368 +00:41:17,220 --> 00:41:21,340 +ما الإحسان، قال أن تعبد الله كأنك تراه فإن لم تكن + +369 +00:41:21,340 --> 00:41:25,220 +تراه فإنه يراك، ثم سأله عن الساعة، فقال ما المسئول + +370 +00:41:25,220 --> 00:41:29,500 +عنها بأعلم من السائل، ثم سأله عن أماراتها، فقال أن + +371 +00:41:29,500 --> 00:41:34,780 +تلد الأمة ربها إذا كان المولود ذكرا أو ربتها إن + +372 +00:41:34,780 --> 00:41:40,300 +كانت أنثى، وهنا الرب بمعنى السيد، وأن ترى الحفاة + +373 +00:41:40,300 --> 00:41:44,100 +العراتة العالة، رعاء الشاة، كحال دول الخليج + +374 +00:41:44,100 --> 00:41:48,520 +اليوم، يتطاولون في البنيان، ففي ساعة واحدة كان + +375 +00:41:48,520 --> 00:41:53,420 +الأعرابي يكونوا قد تعلموا الإسلام وخرج داعية إلى + +376 +00:41:53,420 --> 00:41:58,560 +الله تبارك وتعالى، نقف إلى هنا حتى نكمل في محاضرة + +377 +00:41:58,560 --> 00:42:04,810 +تالية إن شاء الله إن أحيانا الله، التفصيل أيضًا من + +378 +00:42:04,810 --> 00:42:09,270 +خصائص نظام الأخلاق في الإسلام، أقول قولي هذا + +379 +00:42:09,270 --> 00:42:13,850 +وأستغفر الله لي ولكم، والسلام عليكم ورحمة الله + +380 +00:42:13,850 --> 00:42:14,430 +وبركاته diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/CqZkhoI6MR4_raw.json b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/CqZkhoI6MR4_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..2c068ff3df18b0824a46088c4e089c579857e14f --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/CqZkhoI6MR4_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 3254, "start": 5.09, "end": 32.55, "text": "أعوذ بالله السميع العليه من الشياطين الرجيم بسم الله الرحمن الرحيم الحمد لله والصلاة 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"word": " إلى", "probability": 0.94775390625}, {"start": 344.54, "end": 345.04, "word": " فكر", "probability": 0.91748046875}, {"start": 345.04, "end": 345.38, "word": " أو", "probability": 0.87109375}, {"start": 345.38, "end": 345.96, "word": " روية", "probability": 0.9786783854166666}, {"start": 345.96, "end": 347.54, "word": " لا", "probability": 0.7255859375}, {"start": 347.54, "end": 348.64, "word": " يسمى", "probability": 0.9208984375}, {"start": 348.64, "end": 349.48, "word": " خلقا", "probability": 0.9454345703125}, {"start": 349.48, "end": 351.2, "word": " انتبهوا", "probability": 0.826708984375}, {"start": 351.2, "end": 351.64, "word": " إلى", "probability": 0.90185546875}, {"start": 351.64, "end": 351.98, "word": " هذا", "probability": 0.978515625}, {"start": 351.98, "end": 352.66, "word": " المعنى", "probability": 0.9945068359375}, {"start": 352.66, "end": 353.4, "word": " فهذا", "probability": 0.9567057291666666}, {"start": 353.4, "end": 354.18, "word": " موضع", 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مراحل توجيه الخلق في النفس الإنسانية إيجابا أو سلبا فإن هذه المراحل ثلاثة المرحلة الأولى التأثر بالخير والشر المرحلة", "tokens": [1863, 10721, 31371, 6024, 48506, 30731, 18863, 1863, 2407, 7649, 6024, 104, 7649, 1829, 37037, 2407, 7251, 2655, 43500, 3555, 15844, 16712, 3615, 16572, 5172, 3714, 23557, 5016, 1211, 6055, 29245, 1829, 3224, 33962, 1211, 4587, 8978, 28239, 36178, 33688, 1863, 3794, 7649, 10632, 11933, 1829, 7435, 16758, 995, 34051, 8608, 46152, 995, 6156, 28814, 1863, 29538, 9673, 23557, 5016, 1211, 38637, 1211, 5718, 104, 3660, 9673, 2288, 5016, 37977, 16247, 12610, 7578, 16712, 10721, 49115, 20666, 9778, 13546, 16070, 46309, 9673, 2288, 5016, 37977], "avg_logprob": -0.06894985560414403, "compression_ratio": 1.8606060606060606, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 498.6, "end": 499.06, "word": "نأتي", "probability": 0.72705078125}, {"start": 499.06, "end": 499.5, "word": " الآن", "probability": 0.744873046875}, {"start": 499.5, "end": 500.24, "word": 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{"start": 538.76, "end": 539.06, "word": " إن", "probability": 0.477783203125}, {"start": 539.06, "end": 539.68, "word": " عكاس", "probability": 0.8859049479166666}, {"start": 539.68, "end": 540.08, "word": " هذا", "probability": 0.9814453125}, {"start": 540.08, "end": 540.68, "word": " الخلق", "probability": 0.9899088541666666}, {"start": 540.68, "end": 541.48, "word": " على", "probability": 0.8974609375}, {"start": 541.48, "end": 542.54, "word": " صلوك", "probability": 0.83740234375}, {"start": 542.54, "end": 543.34, "word": " الإنسان", "probability": 0.995849609375}, {"start": 543.34, "end": 545.5, "word": " وتصرفاته", "probability": 0.8951171875}], "temperature": 1.0}, {"id": 22, "seek": 57513, "start": 547.09, "end": 575.13, "text": "إذا المراحل التي يمر بها توجيه الخلق في النفس الإنسانية أو النفس البشرية مراحل ثلاثة وكل مرحلة من هذه المراحل تعتمد على ما قبلها إذا لابد أن تحفظ هذه المراحل مرتبة فأول هذه المراحل التأثر بالخير", "tokens": [28814, 15730, 9673, 23557, 5016, 1211, 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فإن هذا الخلق من خير أو شر يرسخ ويستقر في نفس هذا الإنسان", "tokens": [2407, 6027, 10721, 9778, 15040, 4587, 21136, 46152, 10632, 4032, 13546, 2304, 11622, 5296, 11296, 20666, 46309, 6156, 6027, 28814, 1863, 3794, 7649, 11933, 15730, 19446, 6055, 10721, 49115, 20666, 9778, 13546, 34051, 25124, 2288, 6156, 28814, 1863, 23758, 33962, 1211, 4587, 9154, 16490, 13546, 34051, 13412, 2288, 7251, 2288, 3794, 9778, 4032, 1829, 14851, 4587, 2288, 8978, 8717, 36178, 23758, 33688, 1863, 3794, 7649], "avg_logprob": -0.05551609746886022, "compression_ratio": 1.78125, "no_speech_prob": 1.621246337890625e-05, "words": [{"start": 1221.84, "end": 1223.12, "word": "والأخلاق", "probability": 0.90283203125}, {"start": 1223.12, "end": 1223.82, "word": " السلبية", "probability": 0.94580078125}, {"start": 1223.82, "end": 1224.82, "word": " ويرمز", "probability": 0.947021484375}, {"start": 1224.82, "end": 1225.22, "word": " لها", "probability": 0.95751953125}, {"start": 1225.22, "end": 1225.96, "word": " 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صل على سيدنا محمد وعلى آله وصحبه + +4 +00:00:16,160 --> 00:00:20,760 +وسلم أجمعين عزيزي الطلاب أرحبكم قبل بدء في + +5 +00:00:20,760 --> 00:00:25,460 +بداية محاضرة جديدة من مساق النظم الإسلامية وأحييكم + +6 +00:00:25,460 --> 00:00:29,140 +بتحية الإسلام العظيم فالسلام عليكم ورحمة + +7 +00:00:29,140 --> 00:00:35,500 +وبركاته، ومازلنا في فصل الأخلاق واليوم إن شاء الله + +8 +00:00:35,500 --> 00:00:41,820 +تعالى ننتهي من الفصل الثالث اللي هو فصل الأخلاق + +9 +00:00:41,820 --> 00:00:46,780 +ونرحل بصحبتكم في محاضرة قادمة إلى الفصل الرابع وهو + +10 +00:00:46,780 --> 00:00:55,180 +بعنوان نظام الأسرة في الإسلام وقد وصلنا في مبحث + +11 +00:00:55,180 --> 00:00:57,540 +أهمية + +12 +00:00:59,160 --> 00:01:04,100 +الأخلاق في الإسلام وأثرها على النفس البشرية + +13 +00:01:04,100 --> 00:01:07,620 +وتكلمنا + +14 +00:01:07,620 --> 00:01:18,660 +عن القيود على القواعد الخلقية وقلنا سنضرب على ذلك + +15 +00:01:18,660 --> 00:01:27,590 +أمثلة ثلاثة: مثال الدين ومثال الطلاق ومثال الملك وقد + +16 +00:01:27,590 --> 00:01:37,590 +تكلمنا باختصار عن القيد الأول للحق وهو عدم حبس + +17 +00:01:37,590 --> 00:01:46,450 +المدين المعسر وضعه خطا أو خطوطا تحت قولنا المدين + +18 +00:01:46,450 --> 00:01:54,160 +المعسر، والمدين بمعنى مديون، فعيل بمعنى مفعول كما + +19 +00:01:54,160 --> 00:02:00,360 +يقال في لغة العرب قتيل بمعنى مقتول، ومبيع بمعنى + +20 +00:02:00,360 --> 00:02:13,200 +مبيوع، فإذا كان المديون فقيرا أو معثرا لا يستطيع + +21 +00:02:13,200 --> 00:02:25,840 +أداء الدين فمن القواعد الخلقية ألا يقوم الدائن وهو + +22 +00:02:25,840 --> 00:02:32,380 +صاحب المال بحبس هذا المدين المعسر لقوله تبارك + +23 +00:02:32,380 --> 00:02:39,480 +وتعالى: وإن كان ذو عُسرَةٍ فَنَظِرَةٌ إِلَىٰ مَيْسَرَةٍ بمعنى أن + +24 +00:02:39,480 --> 00:02:47,160 +يمهله إلى قابل الأيام لعل الله سبحانه وتعالى أن + +25 +00:02:47,160 --> 00:02:55,750 +يرزقه وأن يغنيه وأن يقوم هذا الفقير المسكين بسداد + +26 +00:02:55,750 --> 00:03:02,350 +ما عليه من دين، أما أن يقوم بحبسه والحيلولة بينه + +27 +00:03:02,350 --> 00:03:09,510 +وبين أهله وزوجه وولده فهذا لا يتفق وأخلاق الإسلام + +28 +00:03:09,510 --> 00:03:15,690 +طبعا نلفت الأنظار إلى أن هذا الحكم إنما يتعلق + +29 +00:03:17,730 --> 00:03:24,670 +بالمدين المعسر، أما إذا كان المدين غنيا ويماطل + +30 +00:03:24,670 --> 00:03:31,150 +فلصاحب الدين وصاحب الحق أن يتقدم بشكوى إلى القضاء + +31 +00:03:31,150 --> 00:03:37,010 +من أجل حبسه ومن أجل إكراهه ومن أجل الضغط عليه حتى + +32 +00:03:37,010 --> 00:03:42,790 +يقوم هذا الغني المليء بسداد ما عليه من دين حتى و + +33 +00:03:42,790 --> 00:03:52,130 +لو ببيع أملاكه، وقد جاء في الحديث: "مطلُّ الغني ظلمٌ" مطلُّ + +34 +00:03:52,130 --> 00:03:58,650 +الغني ظلمٌ، أي الغني الذي يماطله في سداد ما عليه من + +35 +00:03:58,650 --> 00:04:08,720 +دين يحل عرضه وشكايته، عرضه بمعنى غيبته، وشكايته بمعنى + +36 +00:04:08,720 --> 00:04:13,820 +إلى القضاء من أجل حبسه أو إكراهه على سداد ما عليه + +37 +00:04:13,820 --> 00:04:20,700 +من دين فإن لم يكن معه نقود فإن أملاكه تباع بما يسمى + +38 +00:04:20,700 --> 00:04:29,020 +اليوم بالمزاد العلني من أجل سداد ما عليه من ديون + +39 +00:04:29,360 --> 00:04:34,560 +هذا هو المثال الأول ودليله من القرآن الكريم: وإن + +40 +00:04:34,560 --> 00:04:42,480 +كان ذو عُسرَةٍ فَنَظِرَةٌ إِلَىٰ مَيْسَرَةٍ، وأما المثال الثاني وهو + +41 +00:04:42,480 --> 00:04:48,020 +مثال الطلاق فنحن نعلم ولا يخفى على حضراتكم أن + +42 +00:04:48,020 --> 00:04:59,020 +الزوجة بيدها حق الطلاق، الزوجة لا تطلق نفسها، لأنها لا + +43 +00:04:59,020 --> 00:05:12,560 +تعقد قرانها فهي توكل وليها كما جاء في الحديث: أي + +44 +00:05:12,560 --> 00:05:19,680 +امرأة نكحت نفسها بمعنى زوجت نفسها، فنكاحها باطل + +45 +00:05:19,680 --> 00:05:25,680 +فنكاحها باطل، فنكاحها باطل وهذا ما عليه جماهير + +46 +00:05:25,680 --> 00:05:34,620 +العلماء خلافًا لأبي حنيفة النعمان: فلا نكاح إلا + +47 +00:05:34,620 --> 00:05:41,100 +بولي وشاهدي عدل، هكذا يقول المصطفى الذي لا ينطق عن + +48 +00:05:41,100 --> 00:05:45,180 +الهوى صلى الله عليه وسلم، لماذا المرأة لا تسوج + +49 +00:05:45,180 --> 00:05:53,820 +نفسها؟ حتى لا تُنسب إلى الوقاحة، لأن المرأة في + +50 +00:05:53,820 --> 00:06:04,640 +الإسلام كنز ثمين أو بيض مكنون، نعم، كلها حياء، نعم، + +51 +00:06:04,640 --> 00:06:12,580 +والنبي عليه السلام وصف بأنه كان أشد حياء من البكر + +52 +00:06:12,580 --> 00:06:22,720 +في خضرها، فالبكر كلها حياء فلا يليق بها أن تتولّى + +53 +00:06:22,720 --> 00:06:29,360 +عقد زواجها بنفسها فيقوم ولي أمرها من أب أو أخ أو + +54 +00:06:29,360 --> 00:06:38,940 +ابن أو عم بولايتها وتزويجها لمن هو كفء لها، ولذلك + +55 +00:06:38,940 --> 00:06:45,540 +إذا كانت المرأة لا تملك تزويج نفسها وعقد قرانها + +56 +00:06:45,540 --> 00:06:52,200 +بنفسها فلا يحل لها أن تطلق نفسها، لذلك كان حق + +57 +00:06:52,200 --> 00:07:00,280 +الطلاق في يد الزوج ومع ذلك يقول الإسلام: "اتقوا الله + +58 +00:07:00,280 --> 00:07:06,680 +أيها الأزواج" وإذا أردتم الطلاق فإن الطلاق في + +59 +00:07:06,680 --> 00:07:14,940 +الإسلام حكمه الإباحة، حكم الطلاق الإباحة، نعم، وهو + +60 +00:07:15,780 --> 00:07:24,120 +أبغض الحلال إلى الله كما جاء في الآثار وقد نسلت + +61 +00:07:24,120 --> 00:07:30,160 +أحكام الطلاق وفي القرآن صورة هي صورة الطلاق + +62 +00:07:30,160 --> 00:07:37,740 +المطلقات يتربصن بأنفسهن ثلاثة قروء يا أيها النبي + +63 +00:07:37,740 --> 00:07:44,880 +إذا طلقتم النساء فطلقوهن لعدتهن وأحصلي عدة الطلاق + +64 +00:07:44,880 --> 00:07:51,420 +مرتان، فإن سكن بمعروف أو تسريح بإحسان، هذه أحكام + +65 +00:07:51,420 --> 00:07:58,460 +الطلاق في القرآن وغيرها كثير، فنقول يا أيها الزوج + +66 +00:07:58,460 --> 00:08:08,420 +إذا أردت أن تطلق الزوجة فاعطها حقها من المهر وعفش + +67 +00:08:08,420 --> 00:08:14,820 +البيت، لأن المهر يقسم في هذا الزمان إلى أقسام + +68 +00:08:14,820 --> 00:08:20,400 +ثلاثة: مقدم ومؤخر + +69 +00:08:20,400 --> 00:08:28,140 +وعفش بيت، أما المقدم فهو قبل الدخول بالمرأة من أجل + +70 +00:08:28,140 --> 00:08:37,220 +تجهيز نفسها من حلي وثياب ونحو ذلك من زينة، وأما عفش + +71 +00:08:37,220 --> 00:08:44,020 +البيت فهو سلاح في يد المرأة تطالب به في أي وقت + +72 +00:08:44,020 --> 00:08:53,280 +شاءت حتى ولو كانت على رضا مع زوجها، حتى ولو ألبسها + +73 +00:08:53,280 --> 00:08:58,560 +الحرير وهذبها السرير لها أن تطالب به ما تشاء، و + +74 +00:08:58,560 --> 00:09:04,340 +أما المؤخر فعند أقرب الأجلين، والمقصود بأقرب + +75 +00:09:04,340 --> 00:09:11,680 +الأجلين إما الطلاق وإما الوفاة فإنه يخصم من رأس + +76 +00:09:11,680 --> 00:09:21,490 +التركة قبل توزيع نصيب المرأة في حال الوفاة، الثمن + +77 +00:09:21,490 --> 00:09:28,870 +عند إنجاب الزوج والربع عند عدم إنجاب الزوج وهذا + +78 +00:09:28,870 --> 00:09:33,690 +سنأتي إليه عند الحديث عن نظام الأسرة في الإسلام في + +79 +00:09:33,690 --> 00:09:38,390 +الفصل الرابع إن أحيانا الله تبارك وتعالى، ولكن + +80 +00:09:38,390 --> 00:09:43,210 +القرآن يَلْفِتُ أَنْظَارَنَا إلى أن هذا الحق إلا وهو حق + +81 +00:09:43,210 --> 00:09:52,770 +الطلاق مقيد بإنصاف المرأة، الطلاق مرتان والثالثة فإمّا + +82 +00:09:52,770 --> 00:09:58,750 +سكن بمعروف أو تسريح بإحسان، إمّا سكن بمعروف بمعنى + +83 +00:09:58,750 --> 00:10:05,890 +أن تعاشر المرأة معاشرة شرعية بمعنى أن تؤدي المرأة + +84 +00:10:05,890 --> 00:10:11,470 +حقها كاملا، وسنأتي في الفصل الرابع إلى حقوق المرأة + +85 +00:10:11,470 --> 00:10:16,690 +من مهر ونفقة + +86 +00:10:20,390 --> 00:10:29,710 +وعدل وحسن إشرة إلى غير ذلك، فإمّا سكن بمعروف أو + +87 +00:10:29,710 --> 00:10:37,170 +تسريح بإحسان والتسريح بالإحسان هو أن يطلق المرأة و + +88 +00:10:37,170 --> 00:10:42,930 +ألا يظلمها، أن يعطيها حقها ومختصر + +89 +00:10:44,560 --> 00:10:50,920 +تقييد الحق في هذا الباب اللي هو باب الأخلاق اللي + +90 +00:10:50,920 --> 00:10:58,020 +يمسك المرأة، فبعض الرجال الظالمين يريدوا أن يطلق + +91 +00:10:58,020 --> 00:11:05,100 +المرأة فيمسكها ويعتزلها + +92 +00:11:05,100 --> 00:11:14,170 +ويهجرها ولا يعاشرها معاشرة الأزواج من أجل أن يضغط + +93 +00:11:14,170 --> 00:11:21,370 +عليها وأن يكرهها على طلب الطلاق حتى ترى نجوم الظهر + +94 +00:11:21,370 --> 00:11:27,050 +نهارا والعياذ بالله، فهذا هو الحرام وهذا هو الظلم + +95 +00:11:27,050 --> 00:11:32,130 +بعينه، فنقول يا أيها الزوج اتق الله إن كان الطلاق + +96 +00:11:32,130 --> 00:11:35,630 +من حقك فإن طلاقك مقيد + +97 +00:11:38,090 --> 00:11:47,530 +بالإحسان إلى المرأة وإعطائها حقها وألا تظلمها وهذا + +98 +00:11:47,530 --> 00:11:54,210 +معنى قوله تبارك وتعالى، والله أعلى وأعلم، ولا تمسكهن + +99 +00:11:54,210 --> 00:12:02,050 +ضرارا لتعتدوا، هو يمسكها ولكنه لا يعاشرها معاشرة + +100 +00:12:02,050 --> 00:12:10,090 +الأزواج وإنما إضرارا بها حتى تتنازل عن حقها بين + +101 +00:12:10,090 --> 00:12:18,490 +يدي القضاء الإسلامي، فإن إمساك الزوجة لإيقاع ضرر + +102 +00:12:18,490 --> 00:12:26,470 +بها يتنافى وأبسط قواعد الأخلاقية والأدبية في + +103 +00:12:26,470 --> 00:12:33,880 +الإسلام، لأن القاعدة التي تحكمنا هي قوله عليه الصلاة + +104 +00:12:33,880 --> 00:12:40,620 +والسلام، وقد مر بنا هذا الحديث أكثر من مرة: "لا ضرر + +105 +00:12:40,620 --> 00:12:47,460 +ولا ضرار"، لا ضرر ولا ضرار في الإسلام، نعم، فالإسلام + +106 +00:12:47,460 --> 00:12:55,400 +لا ضرر فيه بمعنى أنت لا تبدأ الضرر، ولا ضرار في + +107 +00:12:55,400 --> 00:13:02,000 +الإسلام بمعنى أن تقابل الضرر بضرر مثله، فهذا لا يليق + +108 +00:13:02,000 --> 00:13:09,180 +ولا ينبغي بأخلاق المسلمين، نعم، هنا في الكتاب أيها + +109 +00:13:09,180 --> 00:13:17,440 +الطلاب عنوان ثالث وهو الملك ولكنه لم يظهر واضحا + +110 +00:13:17,440 --> 00:13:25,160 +جليًا في طبعة الكتاب، قلت بأننا سنضرب أمثلة ونماذج + +111 +00:13:25,160 --> 00:13:33,500 +على تقييد استخدام الحق ومنع التعس فيه والاعتداء + +112 +00:13:33,500 --> 00:13:40,480 +على حقوق الغير، والأمثلة ثلاثة: قلنا أولا: تقييد حق + +113 +00:13:40,480 --> 00:13:48,280 +الدائن في حبس المدين المعسر، وثانيا: تقييد حق الزوج + +114 +00:13:48,280 --> 00:13:55,520 +في إيقاع الطلاق على الزوجة إضرارا بها حتى يحرمها + +115 +00:13:55,520 --> 00:14:02,420 +مهرها، وقد قال الله تعالى: "وَآتُوا النِّسَاءَ صَدُقَاتِهِنَّ نِحْلَةً" + +116 +00:14:02,420 --> 00:14:09,880 +فَإِنْ طِبْنَ لَكُمْ عَن شَيْءٍ مِنْهُ نَفْسًا فَكُلُوهُ هَنِيئًا مَرِيئًا، نعم، + +117 +00:14:09,880 --> 00:14:19,600 +وأما ثالثا: تقييد حق المالك في ملكه إضرارا بالآخرين، + +118 +00:14:19,600 --> 00:14:28,460 +هذا عنوان ثالث مكانه عند قولنا في الكتاب: "وعلى ذلك" + +119 +00:14:28,460 --> 00:14:34,060 +فالقاعدة العامة في الإسلام أنه لا ضرر ولا ضرار، يا + +120 +00:14:34,060 --> 00:14:41,460 +ليتنا نكتب إلى جهة اليمين: ثالثا أو جيم، ألف: الدين + +121 +00:14:41,460 --> 00:14:50,870 +باء: الطلاق، جيم: الملك، فلا يصح للمالك أن يستخدم حقه + +122 +00:14:50,870 --> 00:15:00,650 +في الملك إضرارا بالآخرين كأن يفتح طاقة في سقف + +123 +00:15:00,650 --> 00:15:11,250 +البيت حتى يكشف من أعلاه أو أن يفتح طاقة جانبية عن + +124 +00:15:11,250 --> 00:15:18,940 +يمين وشمال على جاره، لأن الجدار مثلا ملكه حتى يكشف + +125 +00:15:18,940 --> 00:15:27,160 +عورات جيرانه أو كما قلت في أول محاضرة في هذا الباب + +126 +00:15:27,160 --> 00:15:32,900 +كأن يربط مثلا كلبا أعزكم الله على باب الدار يعوي + +127 +00:15:32,900 --> 00:15:40,620 +وينبح فيؤذي المرأة ويخيف الأطفال، أو مثلا يحفر حفرة + +128 +00:15:40,620 --> 00:15:46,160 +يقع فيها الناس ويقول هذا ملكي وعلى باب داري، أو أن + +129 +00:15:46,160 --> 00:15:53,340 +يفتح المذياع فوق طاقته فالناس قد يتأذون من الصوت + +130 +00:15:53,340 --> 00:16:00,400 +العالي خاصة المرضى والذين ينامون ظهرا أو نهارا بعد + +131 +00:16:00,400 --> 00:16:06,780 +يوم شاق من العمل، وضربت أيضا مثلا عمليا وإن لم تكن + +132 +00:16:06,780 --> 00:16:11,880 +هذه الأمثلة في الكتاب ولكن الشيء بالشيء يذكر، عندنا + +133 +00:16:11,880 --> 00:16:19,430 +مدن سكنية لابد أن تكون نظيفة وأن تكون هادئة، نعم، + +134 +00:16:19,430 --> 00:16:25,350 +فلا يصح لشخص أن يفتح فيها مثلا مزرعة للدواجن أو + +135 +00:16:25,350 --> 00:16:31,510 +للأغنام أو للأبقار فتفوح الروائح الكريهة المنتنة، و + +136 +00:16:31,510 --> 00:16:35,330 +خاصة في فصل الصيف أضرار بالناس، ويقول هذه مزرعة + +137 +00:16:35,790 --> 00:16:41,530 +وهذا ملكي، لا، لابد أن تكون بعيدا هناك في أطراف + +138 +00:16:41,530 --> 00:16:46,090 +البلد كما تسمى اليوم عندنا في فلسطين وفي قطاع غزة + +139 +00:16:46,090 --> 00:16:53,730 +على وجه الخصوص المدن الصناعية، نعم كمدينة بيت حانون + +140 +00:16:53,730 --> 00:16:59,630 +ونحوها من المدن الأخرى في قطاعنا الحبيب حافظه الله + +141 +00:16:59,630 --> 00:17:06,370 +و المنطلق أيضًا هو القاعدة السابقة الذكر أنه لا ضرر + +142 +00:17:06,370 --> 00:17:11,950 +ولا ضرار في الإسلام إياك أن تبدأ بالضرر وإياك أن + +143 +00:17:11,950 --> 00:17:19,450 +تقابل الضرر بضرر مثله نعم هذه هي الأمثلة الثلاثة + +144 +00:17:19,450 --> 00:17:24,610 +على تقييد استخدام الحق ومنع التعاصف فيه نأتي الآن + +145 +00:17:24,610 --> 00:17:29,830 +إلى ثانيًا والعنوان ما زال هو أثر الأخلاق على النفس + +146 +00:17:29,830 --> 00:17:36,470 +البشرية تكلمنا أولًا والآن نأتي إلى ثانيًا المحافظة + +147 +00:17:36,470 --> 00:17:44,000 +على مبدأ التكافل الاجتماعي في الإسلام وهذا يتطلب + +148 +00:17:44,000 --> 00:17:55,520 +عدة أمور أول هذه الأمور هو التعليق بين يدي التكافل + +149 +00:17:55,520 --> 00:18:03,360 +الاجتماعي على قاعدة شرعية عظيمة ألا وهي الضرر + +150 +00:18:03,360 --> 00:18:11,550 +الأشد يزال بالضرر الأخف، الضرر الأشد يزال بالضرر + +151 +00:18:11,550 --> 00:18:19,910 +الأخف أو كما يقولون أخف الضررين أخف الضررين أو + +152 +00:18:19,910 --> 00:18:30,670 +أشدّين فيعمل بأخفهما فإن الضرر الأشد يزال بالضرر + +153 +00:18:30,670 --> 00:18:39,310 +الأخف بمعنى آخر إذا تعارضت المصلحتان، مصلحة الجماعة + +154 +00:18:39,310 --> 00:18:48,150 +ومصلحة الفرد فأي مصلحة نقدم؟ نقدم مصلحة الجماعة على + +155 +00:18:48,150 --> 00:18:56,490 +مصلحة الفرد عملًا بهذه القاعدة الضرر الأشد وهو + +156 +00:18:56,490 --> 00:19:00,530 +المصلحة العامة يزال بالضرر الأخف وهو مصلحة الفرد + +157 +00:19:01,200 --> 00:19:09,560 +أو بعبارة أخرى إذا تعارضت المصلحة العامة وهي مصلحة + +158 +00:19:09,560 --> 00:19:15,720 +مجموع المسلمين مع المصلحة الخاصة وهي مصلحة الفرد + +159 +00:19:15,720 --> 00:19:23,660 +فإنما تقدم المصلحة العامة على مصلحة الفرد ولو أردنا + +160 +00:19:23,660 --> 00:19:29,140 +أن نتوسع قليلًا من خارج الكتاب وكما يقولون بالمثال + +161 +00:19:29,140 --> 00:19:38,980 +يتضح المقال لو أن الشارع كان ضيقًا مثلًا فهنا + +162 +00:19:38,980 --> 00:19:47,420 +لولِي الأمر عملًا بالقاعدة الشرعية تصرّف الإمام على + +163 +00:19:47,420 --> 00:19:54,550 +الرعية منوط بالمصلحة، ما أعظم هذه القاعدة تصرف + +164 +00:19:54,550 --> 00:19:58,610 +الإمام على الرعية منوط بالمصلحة فإن كانت هناك + +165 +00:19:58,610 --> 00:20:07,110 +مصلحة فله أن يتعدى على مصلحة الفرد أو المصلحة + +166 +00:20:07,110 --> 00:20:12,650 +الخاصة لكن بشرط + +167 +00:20:12,650 --> 00:20:22,760 +مهم جدًا وهو التعويض المكافئ المجزي كما قلت + +168 +00:20:22,760 --> 00:20:29,280 +آنفًا لو أراد ولي الأمر الحاكم المسلم أن يوسع + +169 +00:20:29,280 --> 00:20:37,720 +الشارع فله أن يهدم الدور عن جنبيه فهدم الدور في + +170 +00:20:37,720 --> 00:20:44,320 +هذه الحالة ضرر على الفرد أو على الشخص ولكنه مصلحة + +171 +00:20:44,320 --> 00:20:53,450 +عامة فتقدم المصلحة العامة أو مصلحة الجماعة على + +172 +00:20:53,450 --> 00:21:02,590 +مصلحة الفرد، المصلحة الخاصة لكن على ألا يلقيه + +173 +00:21:02,590 --> 00:21:09,430 +في الشارع، نعم إحنا نتكلم عن حكم الإسلام وعن الحاكم + +174 +00:21:09,430 --> 00:21:17,760 +المسلم فبعض الناس يخرجون هؤلاء إلى الشوارع فيموتون + +175 +00:21:17,760 --> 00:21:25,160 +جوعًا وعطشًا وبردًا، لا إذا هدمت داره فنعم ولكن عليك + +176 +00:21:25,160 --> 00:21:28,500 +بالتعويض + +177 +00:21:28,500 --> 00:21:35,860 +المكافئ المجزي بمعنى لو كان المتر يساوي ألف دينار + +178 +00:21:35,860 --> 00:21:41,840 +فتعوّضه ألف دينار أو تعوضه مترًا بمتر بقيمة ألف + +179 +00:21:41,840 --> 00:21:47,900 +دينار أما إذا كان المتر على الشارع العام سمنه ألف + +180 +00:21:47,900 --> 00:21:54,320 +دينار فتعوضه بخمسين دينارًا أو مائة دينار هذا هو + +181 +00:21:54,320 --> 00:21:59,520 +الظلم بعينه ولا يرضاه الإسلام وكذلك نقول وكما فعل + +182 +00:21:59,520 --> 00:22:06,660 +عمرو بن الخطاب رضي الله عنه في عهد الخلافة الراشدة + +183 +00:22:06,660 --> 00:22:13,360 +لما ضاق المسجد النبوي نعم أراد عمر بن الخطاب أن + +184 +00:22:13,360 --> 00:22:19,580 +يوسع المسجد وكان بجوار المسجد دار لعبد الله بن + +185 +00:22:19,580 --> 00:22:25,960 +عبد المطلب عم النبي عليه الصلاة والسلام فطلب منه + +186 +00:22:25,960 --> 00:22:29,360 +عمر بن الخطاب شراء هذه الدار من بيته المسمى فلم + +187 +00:22:29,360 --> 00:22:36,080 +يقبل، طبعًا هو لم يقبل لحكمة وهو أنه لا يريد أن يبعد + +188 +00:22:36,080 --> 00:22:41,900 +عن مسجد الرسول عليه الصلاة والسلام، يريد أن يكون + +189 +00:22:41,900 --> 00:22:48,220 +قريبًا من الرسول الذي أسلم على يديه حتى يشم رائحة + +190 +00:22:48,220 --> 00:22:54,000 +الرسول وإن كنا لسنا مع هذا الكلام نعم كلنا نحب + +191 +00:22:54,000 --> 00:22:57,760 +الرسول عليه الصلاة والسلام ولكن هنا تأتي القاعدة + +192 +00:22:57,760 --> 00:23:04,360 +العامة الضرر الأشد وهو الواقع على مجموع المسلمين + +193 +00:23:04,360 --> 00:23:09,740 +يزال بالضرر الأخف وهو الواقع على فرد من الأفراد + +194 +00:23:10,630 --> 00:23:17,610 +فمصلحة الجماعة مقدمة على مصلحة الفرد فأكرهه وهنا + +195 +00:23:17,610 --> 00:23:23,630 +يجوز الإكراه لأن شرط البيع الرضا إذا كان بين + +196 +00:23:23,630 --> 00:23:30,190 +شخصين إلا أن تكون تجارة عن تراضٍ منكم أو كما نعلم + +197 +00:23:30,190 --> 00:23:33,750 +نحن في كُرة الشريعة في مساقى المعاملات الشرعية + +198 +00:23:33,750 --> 00:23:39,370 +المالية إنما البيع عن تراضٍ كما في الحديث ولكن هنا + +199 +00:23:39,370 --> 00:23:46,050 +يجوز لولي الأمر أن يكره صاحب الملك نعم من أجل + +200 +00:23:46,050 --> 00:23:52,050 +المصلحة العامة وهو هنا توسيع المسجد فهدم عمر بن + +201 +00:23:52,050 --> 00:23:57,930 +الخطاب دار العباس ووضع ثمنها في بيت مال المسلمين + +202 +00:23:57,930 --> 00:24:05,110 +نعم إن شاء أخذها وإن شاء جعلها صدقة على فقراء + +203 +00:24:05,110 --> 00:24:12,170 +المسلمين وكذلك أمثلة كثيرة لكن حتى لا نطيل نختم + +204 +00:24:12,170 --> 00:24:18,910 +بهذا المثال وقد ذكر الإمام الغزالي لعله في كتابه + +205 +00:24:18,910 --> 00:24:26,750 +المستصفى في أصول الفقه أنه إذا تترس الكفار بأسر + +206 +00:24:26,750 --> 00:24:33,730 +المسلمين كان عند الكفار أسر للمسلمين وتترسوا بهم + +207 +00:24:33,730 --> 00:24:39,970 +تترسوا بهم بمعنى جعلوهم ترسًا أخرجوهم من حبوسهم + +208 +00:24:39,970 --> 00:24:47,550 +وجعلوهم في مقدمة الجيش حتى يخشى المسلمون قتلهم لأنهم + +209 +00:24:47,550 --> 00:24:51,910 +لو ضربوا أسلحتهم على الكفار فقد يقتلون إخوانهم + +210 +00:24:51,910 --> 00:24:58,050 +المسلمين انظروا إلى عظمة الفكر الإسلامي وإلى عظمة + +211 +00:24:58,050 --> 00:25:05,060 +الإمام الغزالي رحمه الله ورضي الله عنه وكيف أن + +212 +00:25:05,060 --> 00:25:10,100 +المصلحة العامة تقدم على المصلحة الخاصة أو أن الضرر + +213 +00:25:10,100 --> 00:25:16,820 +الأشد يزال بالضرر الأخف فإذا ما تعرضت المصلحتان + +214 +00:25:16,820 --> 00:25:24,040 +تقدم المصلحة العامة على المصلحة الخاصة فأجاز + +215 +00:25:24,040 --> 00:25:31,650 +الإمام الغزالي رحمه الله قتل أسر المسلمين، لماذا؟ + +216 +00:25:31,650 --> 00:25:39,510 +لأنه لو لم نقتلهم لترتب على ذلك الضرر الأشد وهو + +217 +00:25:39,510 --> 00:25:47,450 +احتلال بلاد المسلمين وإراقة دماء المسلمين وانتهاك + +218 +00:25:47,450 --> 00:25:53,070 +أعراض المسلمين فهذه أمثلة ونماذج ليست عندنا في + +219 +00:25:53,070 --> 00:25:58,890 +الكتاب ولكن ينتفع بها وإن لم تكن داخلة في الامتحان + +220 +00:25:58,890 --> 00:26:06,050 +فنحن نتعلم من أجل العلم كما قال الغزالي نفسه طلبنا + +221 +00:26:06,050 --> 00:26:10,890 +العلم لغير الله فأبى العلم إلا أن يكون خالصًا لله + +222 +00:26:10,890 --> 00:26:20,100 +بعد هذه المقدمة وبعد شرح هذه القاعدة العظيمة نأتي + +223 +00:26:20,100 --> 00:26:26,400 +إلى مصطلح التكافل، ما هو مصطلح التكافل عندنا؟ + +224 +00:26:26,400 --> 00:26:34,240 +مصطلحان لو اكتفينا بأحدهما كالِتعريف الأول أن يكون + +225 +00:26:34,240 --> 00:26:42,400 +الفرد مرتبط بالجماعة التي هو جزء منها بحيث تكون + +226 +00:26:42,400 --> 00:26:52,000 +تصرفاته وسلوكه مرتبطة بمصلحة هذه الجماعة هذا مصطلح + +227 +00:26:52,000 --> 00:26:56,380 +إذا ما جاءكم في الامتحان إن كان الامتحان خطيًا + +228 +00:26:56,380 --> 00:27:02,700 +ورقياً فإنكم تكتبون بين القوسين التكافل اجتماعيًا + +229 +00:27:02,700 --> 00:27:09,620 +وإذا كان إلكترونيًا فما عليكم إلا التوصيل والمصطلح + +230 +00:27:09,620 --> 00:27:18,380 +سيكون بين أيديكم وهذا يُسهّل عليكم تذكّر الجواب + +231 +00:27:18,380 --> 00:27:24,240 +هنا تعريف آخر شعور الجميع بمسؤولية بعضهم عن بعض + +232 +00:27:24,240 --> 00:27:32,910 +وأن كل واحد منهم حامل لتابعات أخيه ومحمول على أخيه + +233 +00:27:32,910 --> 00:27:39,290 +يُسأل عن نفسه ويُسأل عن أخيه نعم ولكن كما أرى أن + +234 +00:27:39,290 --> 00:27:44,570 +المصطلح الأول هو أجمع إذا ما هو التكافل الاجتماعي؟ + +235 +00:27:44,570 --> 00:27:52,690 +أن يكون الفرد مرتبط بالجماعة التي هو جزء منها بحيث + +236 +00:27:52,690 --> 00:28:02,250 +تكون تصرفاته وسلوكياته مرتبطة بمصلحة هذه الجماعة و + +237 +00:28:02,250 --> 00:28:11,250 +من هنا نرى أن التكافل الاجتماعي هو تقاطر وتعاقد وتكاتف + +238 +00:28:11,250 --> 00:28:19,250 +وتكاتف بين أفراد المجتمع الواحد في شتى مجالات + +239 +00:28:19,250 --> 00:28:26,510 +الحياة وعلى أساس أن مصلحتهم جميعًا هي مصلحة واحدة + +240 +00:28:26,970 --> 00:28:33,570 +نأتي الآن بعد المصطلح إلى الأدلة، ما هي أدلة + +241 +00:28:33,570 --> 00:28:42,910 +التكافل الاجتماعي؟ سنأتي إلى دليلين من الكتاب + +242 +00:28:42,910 --> 00:28:50,310 +ودليلين من السنة النبوية أما أدلة الكتاب في آيتين + +243 +00:28:50,310 --> 00:28:55,310 +قوله تبارك وتعالى واعتصموا بحبل الله جميعًا ولا + +244 +00:28:55,310 --> 00:29:01,890 +تفرقوا وقوله تبارك وتعالى في الآية التي سبقًا تكلمنا + +245 +00:29:01,890 --> 00:29:06,230 +عنها في التعميم من خصائص نظام الأخلاق في الإسلام + +246 +00:29:06,230 --> 00:29:12,450 +وتعاونوا على البر والتقوى ولا تعاونوا على الإثم + +247 +00:29:12,450 --> 00:29:17,450 +والعدوان وأما من السنة النبوية فعندكم في الكتاب + +248 +00:29:17,450 --> 00:29:23,490 +حديث واحد ولكن أردت أن أُضِيء بحديث آخر لأن الحديث + +249 +00:29:23,490 --> 00:29:29,610 +الأخر يُعَدّد هذا الحديث أما حديث الكتاب فقوله عليه + +250 +00:29:29,610 --> 00:29:35,610 +الصلاة والسلام المؤمن للمؤمن كالبنيان يشد بعضه + +251 +00:29:35,610 --> 00:29:46,510 +بعضًا هذا هو حقيقة التكافل تآزر وتعاضد نعم وأما + +252 +00:29:46,510 --> 00:29:52,330 +الحديث الآخر فهو الذين أحفظوا وكيف غاب عنهم مثل + +253 +00:29:52,330 --> 00:30:00,750 +المؤمنين في تودّهم وتراحمهم نعم كمثل الجسد إذا + +254 +00:30:00,750 --> 00:30:06,790 +اشتكى منه عضو تداعى له سائر الأعضاء بالحمّى + +255 +00:30:06,790 --> 00:30:12,990 +والصهري أو بالصهري والحمّى بعد هذه الأدلة نأتي + +256 +00:30:12,990 --> 00:30:22,390 +أبناء الطلاب إلى عنوان مهم جدًا هذا العنوان ليس + +257 +00:30:22,390 --> 00:30:29,150 +بارزًا في الكتاب كان الأولى أن يوضع ببنط أكبر نعم + +258 +00:30:31,040 --> 00:30:38,820 +وهي الضوابط الخلقية أثناء القيام بالسلوك الاجتماعي + +259 +00:30:38,820 --> 00:30:47,340 +أي نعم إذا هكذا السؤال ما هي الضوابط الخلقية أثناء + +260 +00:30:47,340 --> 00:30:54,160 +القيام بالسلوك الاجتماعي هذا العنوان إذا قرأتم + +261 +00:30:54,160 --> 00:31:03,340 +الكتاب ضعوا تحته خطّ عند قوله مع ضمان حدّ أدنى من + +262 +00:31:03,340 --> 00:31:09,000 +الضوابط الخلقية أثناء القيام بالسلوك الاجتماعي + +263 +00:31:09,000 --> 00:31:16,140 +وأنا جئت به بعنوان أكبر ما هي الضوابط الخلقية + +264 +00:31:16,140 --> 00:31:24,320 +أثناء القيام بالسلوك الاجتماعي طبعًا عندنا في + +265 +00:31:24,320 --> 00:31:31,110 +الكتاب أربعة ضوابط أول هذه الضوابط أن التشريع + +266 +00:31:31,110 --> 00:31:40,590 +الإسلامي أباح للفرد حرية المعاملة بالمثل في مجالات + +267 +00:31:40,590 --> 00:31:50,330 +الحقوق الفردية والمعاملات ولعلي وعدتكم عند الحديث + +268 +00:31:50,330 --> 00:31:55,410 +عن العدوان في قوله وتعاونوا على البر والتقوى ولا + +269 +00:31:55,410 --> 00:32:02,430 +تعاونوا على الإثم والعدوان وعند الحديث عن مظاهر + +270 +00:32:02,430 --> 00:32:10,250 +اهتمام الإسلام بالأخلاق وقاتلوا في سبيل الله الذين + +271 +00:32:10,250 --> 00:32:16,650 +يقاتلونكم ولا تعتدوا إن الله لا يحب المعتدين وقلنا + +272 +00:32:16,650 --> 00:32:23,520 +يومئذٍ بأن الإسلام لا يعرف العدوان على الآخرين وإنما + +273 +00:32:23,520 --> 00:32:31,240 +يصدّ العدوان كما هنا فمن اعتدى عليكم رأيتم فمن + +274 +00:32:31,240 --> 00:32:36,140 +اعتدى عليكم فنحن لا نبدأ العدوان وإنما نصدّ العدوان + +275 +00:32:36,140 --> 00:32:44,360 +فاعتدوا عليه بمثل ما اعتدى عليكم ولعلكم تقولون كيف + +276 +00:32:45,600 --> 00:32:50,300 +سمّاه القرآن الكريم عدوانًا والحقيقة هو ليس بعدوان + +277 +00:32:50,300 --> 00:32:58,220 +ولكن هذا في بلاغة العرب وعند العرب يُسمّى المشاكلة + +278 +00:32:58,220 --> 00:33:05,820 +والمشاكلة في لغة العرب وفي أبواب البلاغة العربية + +279 +00:33:05,820 --> 00:33:14,490 +إنما تكون في اللفظ دون المعنى فاللفظ متشابه ولكن + +280 +00:33:14,490 --> 00:33:20,570 +المعنى يختلف لو خرجنا عن الكتاب خليلًا مثل قوله + +281 +00:33:20,570 --> 00:33:29,510 +تبارك وتعالى يمكرون ويمكر الله فهذه مشاكلة فمكر + +282 +00:33:29,510 --> 00:33:35,250 +الله غير مكرهم لأنه مكر يليق به سبحانه وتعالى + +283 +00:33:35,250 --> 00:33:42,530 +وقوله تبارك وتعالى إنهم يكيدون كيدا وأكيد كيدافكيد + +284 +00:33:42,530 --> 00:33:49,410 +الله غير كيدهم وقوله تبارك وتعالى يخادعون الله وهو + +285 +00:33:49,410 --> 00:33:54,770 +خادعهم وكذلك + +286 +00:33:54,770 --> 00:34:02,270 +وجزاء سيئة سيئة مثلها فالأولى سيئة أما الثانية فهي + +287 +00:34:02,270 --> 00:34:10,200 +حسنة لأن رد السيئة ليس سيئة إنما حسنة محمودةولكن + +288 +00:34:10,200 --> 00:34:14,240 +لماذا سماها القرآن سيئة هذا كما قلت من باب + +289 +00:34:14,240 --> 00:34:20,980 +المشاكلة والمشاكلة إنما تكون في اللفظ دون المعنى + +290 +00:34:20,980 --> 00:34:27,660 +نعم كما في الحديث فاستحى فاستحيى الله منهم نعم و + +291 +00:34:27,660 --> 00:34:32,840 +هكذا فمن اعتدى عليكم فاعتدوا عليه بمثل ما اعتدى + +292 +00:34:32,840 --> 00:34:39,680 +عليكم وقوله تبارك وتعالى وإن عقبتم فعاقبوا بمثل ما + +293 +00:34:39,680 --> 00:34:47,720 +عقبتم به فهذا النصان ظاهرا في أن للفرد استفاء مثل + +294 +00:34:47,720 --> 00:34:56,780 +حقه دون زيادة عليه وهذا هو ما تقتضيه مكارم الأخلاق + +295 +00:34:56,780 --> 00:35:04,360 +لأنه كما هو عندنا في الكتاب ليس من الخلق أن يستوفي + +296 +00:35:04,360 --> 00:35:14,280 +الإنسان أكثر من حقه لأن في ذلك الظلم و الظلم يؤدي + +297 +00:35:14,280 --> 00:35:21,660 +إلى تفتيت العلاقات الاجتماعية و إضعافها نعم هذا هو + +298 +00:35:21,660 --> 00:35:27,900 +الضابط الأول أثناء القيام بالسلوك الاجتماعي ثانيا + +299 +00:35:30,110 --> 00:35:37,210 +نهى التشريع الإسلامي عن التزيد في حق النفس لك كما + +300 +00:35:37,210 --> 00:35:45,990 +أسلفنا أن تأخذ حقك كاملا غير منقوص أما أن تتزيد في + +301 +00:35:45,990 --> 00:35:53,470 +حق نفسك فلا ولذلك ذم الله المنافقين في صدر صورة + +302 +00:35:53,470 --> 00:35:59,880 +المطففين أنهم إذا اجتالوا على الناس يستوفونيستوفون + +303 +00:35:59,880 --> 00:36:06,180 +حقوقهم كاملة وإذا كالوهم أو وزنهم يخسرون إذا كالوا + +304 +00:36:06,180 --> 00:36:15,180 +غيرهم أو وزنوا لهم فإنهم يخسرون الميزان وهذا ليس + +305 +00:36:15,180 --> 00:36:25,660 +من أخلاق الإسلام نعم كذلك قوله تبارك وتعالى وهذه + +306 +00:36:25,660 --> 00:36:36,440 +الآية سبق ذكرها عند الحديث عن المثالية في المعاملات + +307 +00:36:36,440 --> 00:36:47,560 +تكلمنا عن المثالية في العبادات نعم و كذلك المثالية + +308 +00:36:47,560 --> 00:36:52,480 +في المنهيات و تكلمنا عن الحد الأدنى و الحد الأعلى + +309 +00:36:52,480 --> 00:37:01,140 +فالحد الأدنى في العبادات نعم هو أداء الفرائض + +310 +00:37:01,140 --> 00:37:07,340 +والاقتصار عليها والحد الأعلى في العبادات هو أداء + +311 +00:37:07,340 --> 00:37:15,920 +النوافل والحد الأدنى في المنهيات والمحرمات هو + +312 +00:37:15,920 --> 00:37:22,420 +البعد عن ما حرم الله من ذنا ومن خمر ومن الربا ومن + +313 +00:37:22,420 --> 00:37:30,280 +عقوق للوالدين إلى آخر هذه الكبائر نعم و الحد + +314 +00:37:30,280 --> 00:37:34,860 +الأعلى في المحرمات و المنهيات هو البعد عن الشبهات + +315 +00:37:34,860 --> 00:37:40,920 +و قد ذكرنا هناك حديثا إن الحلال بين و إن الحرام + +316 +00:37:40,920 --> 00:37:46,090 +بين و بينهما أمور مشتبهات فمن اتقى الشبهات فقد + +317 +00:37:46,090 --> 00:37:54,070 +استبرأ لأرضه ودينه إلى آخر الحديث واليوم هذا له + +318 +00:37:54,070 --> 00:38:00,090 +علاقة بالمثالية في المعاملات ومعنى + +319 +00:38:00,090 --> 00:38:06,610 +هذا المثال أنه في حال القتل العمد ونحن نعلم + +320 +00:38:06,610 --> 00:38:16,070 +أعزائنا وأبنائنا وإخواننا جميعا بأن القتل العمد + +321 +00:38:16,070 --> 00:38:22,070 +حكمه القصاص ولكم في القصاص حياة يقول الألباب لعلكم + +322 +00:38:22,070 --> 00:38:31,310 +تتقون فالقاتل يقتل إذا كان مع الترصد وصدق الإصرار + +323 +00:38:31,310 --> 00:38:35,390 +نعم ولكن + +324 +00:38:35,390 --> 00:38:45,500 +من رحمة الله بالمسلمين أنه يجوز لهم لولي الدم أن + +325 +00:38:45,500 --> 00:38:54,940 +يتنازل من الإعدام والقتل أو القصاص لأنه كان يقعد + +326 +00:38:54,940 --> 00:39:02,100 +بحبل من عنقه ويسلم إلى أولياء الدم لهم أن يتنازلوا + +327 +00:39:02,100 --> 00:39:11,340 +إلى قبول دية حتى ولو كانت ديته مضاعفة سنتين أو + +328 +00:39:11,340 --> 00:39:20,820 +ثلاثة حتى نقوم بإرضائهم وهذا معنى قوله تبارك وتعالى + +329 +00:39:20,820 --> 00:39:25,460 +والله أعلى وأعلم يا أيها الذين آمنوا كُتب عليكم + +330 +00:39:25,460 --> 00:39:32,860 +القصاص في القتل الحُر بالحُر والعبد بالعبد والأنثى + +331 +00:39:32,860 --> 00:39:41,710 +بالأنثى فمن عُفّله من أخيه شيء بمعنى تنازلة من + +332 +00:39:41,710 --> 00:39:48,370 +القتل إلى قبول الدية فمن عفى له من أخيه شيء فاتباع + +333 +00:39:48,370 --> 00:39:55,370 +بالمعروف وأداء إليه بإحسان ذلك تخفيف من ربكم ورحمة + +334 +00:39:55,370 --> 00:40:01,550 +فمن اعتدى بعد ذلك فله عذاب أليم بمعنى إذا تنازل + +335 +00:40:01,550 --> 00:40:07,990 +أولياء الدم وقبلوا الدية فعلى القاتل أن يقوم بدفع + +336 +00:40:07,990 --> 00:40:16,200 +الدية كاملة إلى أولياء الدم وعلى أولياء الدم بعد + +337 +00:40:16,200 --> 00:40:23,080 +قبول هذه الدية اللي يعودوا إلى قتل القاتلين أقولها + +338 +00:40:23,080 --> 00:40:29,380 +بكل أسف وقلم ومرارة حصلت في قطاع غزة أن القوم قد + +339 +00:40:29,380 --> 00:40:37,540 +قبلوا الدية واصطلحوا على ذلك وبعد فترة قام + +340 +00:40:38,570 --> 00:40:45,050 +النمامون والمفسدون بإغراء صدورهم تجاه أقرب الناس + +341 +00:40:45,050 --> 00:40:51,710 +إليهم كأعمامهم أو أخوالهم أو من جيرانهم وقاموا + +342 +00:40:51,710 --> 00:40:58,390 +بقتل القاتل فهؤلاء يقتلون قصاصا لأنك مخير بين + +343 +00:40:58,390 --> 00:41:05,910 +أمرين إما أن تقتل والقتل حق لك وإما أن تقبل الدية + +344 +00:41:05,910 --> 00:41:11,860 +وإما حتى أن تعفونعم فالعفو من أخلاق الإسلام ولذلك + +345 +00:41:11,860 --> 00:41:19,240 +من بلاغة القرآن أنه يعني رغبنا في ذلك فقال فمن + +346 +00:41:19,240 --> 00:41:27,360 +عفى له من أخيه وكلمة من أخيه هذه ترغيب في قبول + +347 +00:41:27,360 --> 00:41:36,130 +الدين لأن القاتل وإن قتل يبقى أخا للمقتول نعم هذا + +348 +00:41:36,130 --> 00:41:39,810 +من عظمة القرآن الكريم فمن عُفي له من أخيه شيء + +349 +00:41:39,810 --> 00:41:46,650 +تنازل من القتل والقصاص إلى قبول الدية فاتباع + +350 +00:41:46,650 --> 00:41:52,850 +بالمعروف وأداء إليه بإحسان ذلك تخفيف من ربكم ورحمة + +351 +00:41:52,850 --> 00:41:57,750 +بمعنى أن هذا ليس عند اليهود ولا عند النصارى في بني + +352 +00:41:57,750 --> 00:42:03,680 +إسرائيل لأنه ليس عندهم إلا القتل نعم العين بالعين + +353 +00:42:03,680 --> 00:42:09,000 +والسن بالسن والجروح كصاص هذا هو عند بني إسرائيل + +354 +00:42:09,000 --> 00:42:17,340 +وفي قصة البقرة لما قتل الرجل عمه ليريثه ويتزوج + +355 +00:42:17,340 --> 00:42:24,460 +ابنته وقد أحياه الله وقال إن الذي قتلني هو ابن أخي + +356 +00:42:24,460 --> 00:42:35,780 +فقتلوه قصاصا لا دية ولا عفوة في هذه المسألة ثم توعد + +357 +00:42:35,780 --> 00:42:43,500 +القرآن الكريم من قام بقتل القاتل الذي اصطلحوا معه + +358 +00:42:43,500 --> 00:42:51,000 +على قبول الدية فمن اعتدى بعد ذلك فله عذاب أليم + +359 +00:42:51,000 --> 00:42:56,660 +فعلى أولياء الدم اللي لا يزيدوا في حقهم بعد قبول + +360 +00:42:56,660 --> 00:43:05,140 +الدية ثالثا رغب التشريع الإسلامي في الزيادة في + +361 +00:43:05,140 --> 00:43:11,500 +حق الغير وهنا لابد أن نلتفت إلى النونين النون + +362 +00:43:11,500 --> 00:43:18,360 +الثاني نهى التشريع الإسلامي عن التزيد في حق النفس + +363 +00:43:20,280 --> 00:43:25,240 +ولكن العنوان الثالث رغب التشريع الإسلامي في + +364 +00:43:25,240 --> 00:43:31,980 +الزيادة في حق الغير فانتبهوا إلى هذين العنوانين + +365 +00:43:31,980 --> 00:43:40,200 +فالزيادة في حق الغير والنهي عن التزيد في حق النفس + +366 +00:43:40,200 --> 00:43:45,890 +وقد ذكر الله ذلك في القرآن الكريم في قوله تبارك + +367 +00:43:45,890 --> 00:43:50,810 +الله في سورة الحشر ويؤثرون على أنفسهم ولو كان بهم + +368 +00:43:50,810 --> 00:43:57,110 +خصاصة وهذه الآية لها قصة في تفسير ابن كثير لمن + +369 +00:43:57,110 --> 00:44:04,290 +أراد أن يرجع إليها كيف أن هذا الأنصاري آثر أخاه + +370 +00:44:04,290 --> 00:44:13,280 +المهاجر الذي طرك ماله وبيته وأهله في مكة حبا في + +371 +00:44:13,280 --> 00:44:18,840 +رسول الله صلى الله عليه وسلم وهاجر إلى المدينة + +372 +00:44:18,840 --> 00:44:26,100 +المنورة فأطعمه عشاء صبيته وباتوا تلك الليلة هو + +373 +00:44:26,100 --> 00:44:32,260 +وزوجه وولده جوعًا فاستحقوا هذا الثناء من الله + +374 +00:44:32,260 --> 00:44:40,720 +ويؤثرون على أنفسهم ولو كان بهم خصاصة نعم هذا من + +375 +00:44:40,720 --> 00:44:45,140 +أعظم القواعد الخلقية تأثيرا في مبدأ التكافل + +376 +00:44:45,140 --> 00:44:50,460 +الاجتماعي لأنه يحافظ على تماسك المجتمع وتقوية + +377 +00:44:50,460 --> 00:44:56,320 +الأواصر بين أفراده وتمتين العلاقات الاجتماعية وأما + +378 +00:44:56,320 --> 00:45:01,740 +من السنة النبوية ما روى أن الرسول صلى الله عليه + +379 +00:45:01,740 --> 00:45:08,090 +وسلم أتاه رجل يتقاضاه بعيرا ولعله هذا البعير كان + +380 +00:45:08,090 --> 00:45:15,750 +نحيفا نعم أو أصغر سنا فقال الرسول عليه الصلاة + +381 +00:45:15,750 --> 00:45:22,550 +والسلام أعطوه فقالوا يا رسول الله ما نجد إلا سنا + +382 +00:45:22,550 --> 00:45:28,440 +أفضل من سنه بمعنى لا نجد إلا بعيرا أفضل من بعيره + +383 +00:45:28,440 --> 00:45:34,740 +لحما أو أكبر سنا فقال عليه الصلاة والسلام أعطوه + +384 +00:45:34,740 --> 00:45:43,080 +فإن خياركم أحسنكم قضاء أعطوه فإن خياركم أحسنكم + +385 +00:45:43,080 --> 00:45:52,140 +قضاء فهذه دعوة إلى الزيادة في حق الغير نعم وهناك + +386 +00:45:52,140 --> 00:46:01,780 +مثال من السنة النبوية أيضًا وهو يبين مدى المثالية + +387 +00:46:01,780 --> 00:46:09,780 +في أخلاق الصحابة كما روى الإمام مسلم في صحيحه قال + +388 +00:46:09,780 --> 00:46:16,440 +عبد الله بن كعب بن مالك نعم وقد سأل ابن أبي حضرة + +389 +00:46:16,440 --> 00:46:23,840 +دينًا ابن أبي حضرد وهذا يعيدنا إلى الوراء قليلا + +390 +00:46:23,840 --> 00:46:32,160 +عندما تكلمنا عن أمثلة ونماذج لتقييد الحق فابن أبي + +391 +00:46:32,160 --> 00:46:39,080 +حضرد قد اخترض مالا فهو مدين للصحابي + +392 +00:46:39,080 --> 00:46:47,460 +الجليل كعب بن مالك وعبد الله يروي هذه القصة عن أبيه + +393 +00:46:47,460 --> 00:46:56,820 +نعم وما أن رأاه في المسجد حتى قال يابن أبي حضران + +394 +00:46:56,820 --> 00:47:05,900 +سدني ديني ولعله لم يكن معه إلا شطر المالي أو نصفه + +395 +00:47:05,900 --> 00:47:12,520 +فارتفعت أصواتهما وهذا لا يليق ولا ينبغي في مسجد + +396 +00:47:12,520 --> 00:47:17,540 +الرسول عليه الصلاة والسلام أقول ليس في حياته أيضًا + +397 +00:47:17,540 --> 00:47:23,540 +بل أيضًا بعد وفاته عليه الصلاة والسلام لا ينبغي + +398 +00:47:23,540 --> 00:47:30,340 +ولا يحل رفع الأصوات في المسجد النبوي تكريما لرسول + +399 +00:47:30,340 --> 00:47:39,580 +الله صلى الله عليه وسلم نعم فخرج النبي من حجرته + +400 +00:47:39,580 --> 00:47:51,520 +وأشار إلى كعب ابن مالك هكذا بمعنى ضع الشطر ضع + +401 +00:47:51,520 --> 00:47:59,010 +الشطر يا كعب نعم فقال لبيك يا رسول الله فأشار بيده + +402 +00:47:59,010 --> 00:48:06,510 +أن ضع الشطرة من دينك يعني النصف فقال كعب قد فعلت يا + +403 +00:48:06,510 --> 00:48:12,530 +رسول الله فقال رسول الله لابن أبي حضرة قم فقده + +404 +00:48:12,530 --> 00:48:22,790 +فهذه دعوة إلى التنازل عن بعض الحق وإن لم تكن فرضا + +405 +00:48:22,790 --> 00:48:30,100 +أو واجبا عليك ولكنها من المثالية ولكنها من أخلاق + +406 +00:48:30,100 --> 00:48:36,820 +الإسلام العظيم ولذلك القرآن الكريم عدد لنا المراحل + +407 +00:48:36,820 --> 00:48:43,920 +ثلاثة في مسألة الدين المرحلة الأولى أن تعطيه دينا + +408 +00:48:43,920 --> 00:48:55,960 +لأن أجر الدين بثمانية عشر الصدقة بعشر أمثالها أما + +409 +00:48:55,960 --> 00:49:01,940 +القرض بثمانية عشرة لماذا؟ لأن الذي يأخذ الصدقة قد + +410 +00:49:01,940 --> 00:49:06,800 +لا يكون محتاجا إليها أما الذي يطلب القرض والدين + +411 +00:49:06,800 --> 00:49:13,000 +فلا محالة أنه محتاج إليه إذا كان الثواب بثمانية + +412 +00:49:13,000 --> 00:49:20,600 +عشرة نعم فالله يقول تبارك وتعالى وإن كان ذو عشرة + +413 +00:49:20,600 --> 00:49:27,350 +فنظرة إلى ميصرة وهي المرحلة الثانية بمعنى أن تنظره + +414 +00:49:27,350 --> 00:49:33,310 +أو أن تؤجل ثداد ما عليهم من الدين هذه هي المرحلة + +415 +00:49:33,310 --> 00:49:39,850 +الثانية والمرحلة الثانية وهي أعظم وأرقى وأسمى هذه + +416 +00:49:39,850 --> 00:49:45,670 +الدرجات إن كان فقيرا محتاجا هو أن تعافوا عنه وإن + +417 +00:49:45,670 --> 00:49:56,140 +كان ذو عصرة فنظرة إلى ميصرة وأن تصدقوا خير لكم نعم + +418 +00:49:56,140 --> 00:50:04,960 +وأن تصدقوا خير لكم فالصدقة هنا من أعظم الدرجات + +419 +00:50:04,960 --> 00:50:09,040 +فالنبي عليه السلام أشار إلى كعب الملك أن ضع الشطرة + +420 +00:50:09,040 --> 00:50:17,360 +يعني النصف من دينك وهذا من باب ترغيب الإسلام في + +421 +00:50:17,360 --> 00:50:24,920 +زيادة حق الغير أما رابعا وأخيرا من الضوابط أثناء + +422 +00:50:24,920 --> 00:50:31,160 +القيام بالسلوك الاجتماعي هو مقابلة الإساءة + +423 +00:50:31,160 --> 00:50:37,160 +بالإحسان وخلق الإحسان كما مر معناه في مجموعة + +424 +00:50:37,160 --> 00:50:40,020 +الأخلاق الإيجابية + +425 +00:50:41,480 --> 00:50:47,280 +إن الله يأمر بالعدل والإحسان وإيتاء القربة وقد جاء + +426 +00:50:47,280 --> 00:50:53,900 +في الحديث أيضًا إن الله كتب الإحسان على كل شيء + +427 +00:50:53,900 --> 00:51:00,100 +فإذا قتلتم فأحصنوا القتلة وإذا ذبحتم فأحصنوا + +428 +00:51:00,100 --> 00:51:04,820 +الذبحة حتى الإحسان إلى الحيوان فكيف بالإحسان إلى + +429 +00:51:04,820 --> 00:51:13,830 +الإنسان؟ وليحدّ أحدكم شفرته وليريح ذبيحته نعم + +430 +00:51:13,830 --> 00:51:21,370 +فالإحسان من أعظم أخلاق الإنسان لأنك لا تشبر الناس + +431 +00:51:21,370 --> 00:51:32,770 +على محبتك وإنما بالإحسان إليهم يحبوك كما ورد عن + +432 +00:51:32,770 --> 00:51:39,950 +الإمام علي أو عن غيره عجبت لمن يشتري العبيد بماله + +433 +00:51:39,950 --> 00:51:47,550 +ولم يشتري الأحرار بحسن فعاله إنها كلمة عظيمة وحكمة + +434 +00:51:47,550 --> 00:51:53,930 +جليلة عجبت لمن يشتري العبيد بماله ولم يشتري + +435 +00:51:53,930 --> 00:51:59,760 +الأحرار بحسن فعاله وقد قال الشعر العربي أحسن إلى + +436 +00:51:59,760 --> 00:52:06,880 +الناس تستعبد قلوبهم فطالما استعبد الإنسان إحسانه + +437 +00:52:06,880 --> 00:52:16,220 +نعم فمن أخلاق الإسلام مقابلة الإساءة بالإحسان + +438 +00:52:16,220 --> 00:52:19,700 +والكلام حول هذا يطول ولكن + +439 +00:52:22,340 --> 00:52:28,440 +المصنفين ضربوا لنا مثلا وهو في حديث الإفك حيث + +440 +00:52:28,440 --> 00:52:36,780 +اتهمت عائشة الرزينة الصديقة بنت الصديق أبي بكر + +441 +00:52:36,780 --> 00:52:41,780 +رضي الله عنه بالزنا من صحابي جليل صفوان بن المعطل + +442 +00:52:41,780 --> 00:52:47,540 +ظلما وعدوانا وقد قام بإشاعة هذا الخبر رأس + +443 +00:52:47,540 --> 00:52:53,650 +المنافقين عبد الله بن أبي بن سلول ولكن للأسف قام + +444 +00:52:53,650 --> 00:53:00,510 +بعض المسلمين بترويج هذه الإشاعة نحن لا نعجب من + +445 +00:53:00,510 --> 00:53:08,930 +منافق عدو الإسلام يروّج هذه الإشاعات أما أن يغتر + +446 +00:53:08,930 --> 00:53:15,930 +بعض المسلمين وأن يخدعوا كما نرى اليوم في مواقع + +447 +00:53:15,930 --> 00:53:21,090 +الفيسبوك و التواصل الاجتماعي هناك أخبار كاذبة عن + +448 +00:53:21,090 --> 00:53:27,350 +فلان وعن فلان ومن أهل الشهامة والمروءة والأخلاق + +449 +00:53:27,350 --> 00:53:35,550 +الحسنة فإذا ببعض المسلمين وكأن هذه المواقع قرآن + +450 +00:53:35,550 --> 00:53:43,090 +يتلى أو سنة صحيحة في البخاري ومسلم لا الله يقول إن + +451 +00:53:43,090 --> 00:53:49,780 +جاءكم فثقوا بنبأ فتبينوا وفي قراءة فتثبته أن تصيب + +452 +00:53:49,780 --> 00:53:55,600 +قوما بجهالة فتصبحوا على ما فعلتم نادمين من قرأ + +453 +00:53:55,600 --> 00:54:01,780 +بالترويج للأسف ثلاثة من الصحابة شاعر الإسلام حسان + +454 +00:54:01,780 --> 00:54:10,500 +بن ثابت نعم وقد تاب إلى الله وحسنت توبته ومدح + +455 +00:54:10,500 --> 00:54:17,650 +عائشة بقصيدة طويلة في صدرها عائشة الرزينة لا تذن بريبة + +456 +00:54:17,650 --> 00:54:25,370 +يعني لا تتهم بريبة وكذلك حمنة بنت تجحش وهي أخت زينب + +457 +00:54:25,370 --> 00:54:30,650 +بنت تجحش زوج النبي عليه السلام زينب بنت تجحش عصمها + +458 +00:54:30,650 --> 00:54:38,490 +الله وهي التي كانت تنافس عائشة فعائشة البكر + +459 +00:54:38,490 --> 00:54:42,130 +الحميراء + +460 +00:54:42,130 --> 00:54:51,700 +نعم وكانت تقول نزلت براءتي من السماء في عشر آيات في + +461 +00:54:51,700 --> 00:54:58,820 +صدر سورة النور برأني الله من السماء فكانت تقول + +462 +00:54:58,820 --> 00:55:05,460 +زينب وأنا التي زوجني الله في السماء فلمّا قضى زيد + +463 +00:55:05,460 --> 00:55:14,250 +منها وطلقها زوجناكها ومع ذلك عصم الله زينب ولكن وقعت + +464 +00:55:14,250 --> 00:55:25,510 +في الخطيئة أختها حمنة بنت تجحش نعم وكذلك مصطح بن أثاثة + +465 +00:55:25,510 --> 00:55:31,950 +من أصله وكان من آل أبي بكر رضي الله عنه وكان مصطح + +466 +00:55:31,950 --> 00:55:36,790 +رجلا فقيرا معدما قد جعل له أبو بكر وكان من التجار + +467 +00:55:36,790 --> 00:55:42,030 +أغنيا نفقة ومع ذلك أساء + +468 +00:55:43,000 --> 00:55:50,620 +إلى أبي بكر وإلى ابنته عائشة فكان يروّج الإشاعة + +469 +00:55:50,620 --> 00:55:56,660 +مع المروّجين وأبو بكر بعتباره بشرا قد غضبه وقال + +470 +00:55:56,660 --> 00:56:04,700 +والله لن أنفق عليه أبدا عقوبة لهم ولكن أين أنت يا + +471 +00:56:04,700 --> 00:56:09,770 +أبا بكر من المثالية وأنت منهم وأنت الوزير الأول + +472 +00:56:09,770 --> 00:56:14,790 +للرسول عليه الصلاة والسلام ألمد أن تلقى إلى مستوى + +473 +00:56:14,790 --> 00:56:20,630 +المثالية نعم فنزل القرآن الكريم ولا يقتلق ولا + +474 +00:56:20,630 --> 00:56:27,650 +يقتلق يعني لا يحلف لأن الإله هو الحلف نعم ولا + +475 +00:56:27,650 --> 00:56:32,370 +يقتلؤل الفضل منكم والسعى وهو أبو بكر رضي الله عنه + +476 +00:56:33,050 --> 00:56:38,450 +أي يؤتوا للقربة والمساكين والمهاجرين في سبيل الله + +477 +00:56:38,450 --> 00:56:43,070 +والمقصود هنا بالاتفاق العلماء مصطح بن أثاثة + +478 +00:56:43,070 --> 00:56:48,870 +وليُعفوا وليصفحوا هذه أخلاق الإسلام ألا تحبون أن + +479 +00:56:48,870 --> 00:56:55,430 +يغفر الله لكم والله غفور ورحيم فيما نزلت هذه الآية + +480 +00:56:55,430 --> 00:57:03,550 +قال أبو بكر بلى يا رب أحب أن تغفر لي وأعاد إليه + +481 +00:57:03,550 --> 00:57:15,620 +صدقة وقال والله لا أنزعها منه أبدا نعم هذه هي + +482 +00:57:15,620 --> 00:57:24,780 +أخلاق الإسلام والمسلمين اليوم نكتفي إلى هنا وهنا + +483 +00:57:24,780 --> 00:57:31,180 +نكون قد انتهينا من الفصل الثالث وهو فصل نظام + +484 +00:57:31,180 --> 00:57:36,710 +الأخلاق في الإسلام حتى نرحل بصحبتكم إن شاء الله إلى + +485 +00:57:36,710 --> 00:57:43,890 +الفصل الرابع وهو بعنوان نظام الأسرة في الإسلام وهو + +486 +00:57:43,890 --> 00:57:51,190 +من خمسة مباحث ألقاكم على خير وأستغفر الله لي ولكم + +487 +00:57:51,190 --> 00:57:54,750 +والسلام عليكم ورحمة الله وبركة الله diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/IXZ2cpoWhzo.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/IXZ2cpoWhzo.srt new file mode 100644 index 0000000000000000000000000000000000000000..dacf6ccc1a40cd67e074c78d362e3a06aa831559 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/IXZ2cpoWhzo.srt @@ -0,0 +1,1631 @@ +1 +00:00:04,980 --> 00:00:07,740 +أعوذ بالله السميع العلي من الشيطان الرجيم بسم الله + +2 +00:00:07,740 --> 00:00:10,900 +الرحمن الرحيم الحمد لله والصلاة والسلام على رسول + +3 +00:00:10,900 --> 00:00:16,200 +الله دائما وأبدا اللهم صلى على سيدنا محمد وعلى آله + +4 +00:00:16,200 --> 00:00:21,560 +وصحبه وسلم أجمعين أعزاء الطلاب قبل ذي بدء أرحبكم + +5 +00:00:21,560 --> 00:00:25,940 +في محاضرة جديدة وأحييكم بتحية الإسلام العظيم فسلام + +6 +00:00:25,940 --> 00:00:32,500 +الله عليكم ورحمته وبركاته ما زلنا مع الفصل الرابع + +7 +00:00:32,500 --> 00:00:38,200 +وهو نظام الأسرة في الإسلام واليوم نكمل معا وسويا + +8 +00:00:38,200 --> 00:00:49,000 +إن شاء الله المبحث الثالث وهو بعنوان الزواج وقد + +9 +00:00:49,000 --> 00:00:58,640 +وصلنا إلى حكمة مشروعية الزواج وهنا وقبل البدء في + +10 +00:00:58,640 --> 00:01:02,940 +الحديث عن حكم مشروعية الزواج لابد من أن ألفت + +11 +00:01:02,940 --> 00:01:11,580 +الأنظار إلى حكم وحكم لعلها لم تأتِ مشكلة ولكن + +12 +00:01:11,580 --> 00:01:19,240 +نحاول أن نشكلها في الامتحان فهناك حكمة وهي مفرد + +13 +00:01:19,240 --> 00:01:32,460 +حكم بكسر الحاء وفتح الكاف حكم والمفرد حكم وسيأتي + +14 +00:01:32,460 --> 00:01:39,160 +بعد قليل حكم والجمع أحكام وهي بضم الحاء وإسكان + +15 +00:01:39,160 --> 00:01:46,940 +الكاف و يجب التنويه إلى الفرق بين حكم وبين حكم التي + +16 +00:01:46,940 --> 00:01:53,360 +لم تأتِ مشكلة في السؤال نعود إلى حكمة مشروعية + +17 +00:01:53,360 --> 00:02:02,000 +الزواج وأول هذه الحكمة الاستجابة لنداء الفطرة + +18 +00:02:02,000 --> 00:02:11,410 +وتلبية الحاجة الغريزية ولكل شخص سوي معتد للفطرة + +19 +00:02:11,410 --> 00:02:23,070 +شهوة وغريزة والذي لا يشعر بها يحتاج إلى استشارة + +20 +00:02:23,070 --> 00:02:33,310 +الطبيب وهذه الشهوة لها قنوات شرعية ففي الإسلام + +21 +00:02:33,310 --> 00:02:46,260 +لكل شهوة قنوات شرعية نعم فشهوة المال مصدرها العمل + +22 +00:02:46,260 --> 00:02:56,040 +والكسب والبيع أو التجارة نعم وشهوة الرئاسة مثلا + +23 +00:02:56,040 --> 00:03:01,900 +الانتخابات والوصول + +24 +00:03:01,900 --> 00:03:08,850 +عبر الشورى والديمقراطية بعيدا عن الانقلابات وسفك + +25 +00:03:08,850 --> 00:03:17,670 +الدماء وأما شهوة الفرد فقنعتها الشرعية الحلال هي + +26 +00:03:17,670 --> 00:03:29,250 +الزواج ولذا كانت الشهوة من أجل أمرين الأمر الأول + +27 +00:03:29,250 --> 00:03:39,260 +هو اللفة بالحلال عبر القناة الشرعية ولا قناة شرعية + +28 +00:03:39,260 --> 00:03:46,960 +لتفريغ هذه الشهوة سواء الزواج والذين هم لفروجهم + +29 +00:03:46,960 --> 00:03:53,180 +حافظون إلا على أزواجهم أو ما ملكت أيمانهم فإنهم + +30 +00:03:53,180 --> 00:03:59,200 +غير ملومين فمن ابتغى وراء ذلك فأولئك هم العدون + +31 +00:04:00,200 --> 00:04:10,540 +والأمر الثاني هو ابتغاء الولد والذرية الصالحة نعم + +32 +00:04:10,540 --> 00:04:15,020 +فالرسول عليه الصلاة والسلام يقول إذا مات ابن آدم + +33 +00:04:15,020 --> 00:04:21,520 +أو إذا مات الإنسان انقطع عمله إلا من ثلاث وذكر + +34 +00:04:21,520 --> 00:04:32,710 +منها ولد صالح يدعو له هذا من حكمة الزواج التي أفعل + +35 +00:04:32,710 --> 00:04:35,030 +بالزوجة الصالحة + +36 +00:04:37,500 --> 00:04:43,620 +والذرية الصالحة والولد الصالح إن شاء الله تبارك + +37 +00:04:43,620 --> 00:04:48,780 +وتعالى وقد طلب الأنبياء الولد الصالح على لسان + +38 +00:04:48,780 --> 00:04:54,180 +الخليل عليه السلام ربي هب لي من الصالحين وعلى لسان + +39 +00:04:54,180 --> 00:04:58,100 +زكريا عليه السلام ربي لا تذرني فردا وأنت خير + +40 +00:04:58,100 --> 00:05:06,750 +الوارثين بل إن هذا اللقاء العاطفي بين الزوجين إن + +41 +00:05:06,750 --> 00:05:17,690 +كان بقصد العفة وبقصد الولد فهو ليس مجرد متعة فقط + +42 +00:05:17,690 --> 00:05:26,870 +وإنما هي صداقة أيضا لقوله صلى الله عليه وسلم كما + +43 +00:05:26,870 --> 00:05:35,740 +في الحديث الشريف وفي بضع أحدكم صداقة والبضع هنا هو + +44 +00:05:35,740 --> 00:05:42,820 +الفرج ويقنى به عن الجماع أو الاتصال الحلال بين + +45 +00:05:42,820 --> 00:05:50,360 +الزوجين فالبدع بضم الباء هو الفرج من كلا الزوجين + +46 +00:05:50,360 --> 00:05:59,330 +وأما البضع بالكسر فهو من ثلاثة إلى سبعة دون العشرة + +47 +00:05:59,330 --> 00:06:04,730 +كما في قول الله تعالى في سورة يوسف فلبث في السجن + +48 +00:06:04,730 --> 00:06:12,750 +بضعة سنين وفي بضع أحدكم صداقة فعجب الصحابة من ذلك + +49 +00:06:12,750 --> 00:06:19,790 +وقالوا يا رسول الله أيأتي أحدنا شهوته ويكون له أجر + +50 +00:06:20,990 --> 00:06:26,590 +قال نعم أرأيتم لو وضعها في حرام أيكون عليه وزر + +51 +00:06:26,590 --> 00:06:34,970 +كذلك لو وضعها في حلال يكون له أجر فهذه الشهوة إذا + +52 +00:06:34,970 --> 00:06:41,450 +كانت في حلال وفي موضع حلال عبر الزواج كما أسلفنا + +53 +00:06:41,450 --> 00:06:44,630 +فهي أجر وصدقة + +54 +00:06:46,150 --> 00:06:51,470 +وإن كانت في فرج حرام كالذنب إنه كانت فحشة وساء + +55 +00:06:51,470 --> 00:06:57,770 +سبيله والعياذ بالله كانت معصية وكانت إثما مبينا + +56 +00:06:57,770 --> 00:07:03,950 +والرسول عليه الصلاة والسلام قد أقر هذه الحقيقة في + +57 +00:07:03,950 --> 00:07:10,330 +الحديث الصحيح الذي رواه البخاري عن أنس بن مالك رضي + +58 +00:07:10,330 --> 00:07:16,880 +الله عنه أنه جاء ثلاثة رهط إلى بيوت أزواج النبي صلى + +59 +00:07:16,880 --> 00:07:24,480 +الله عليه وسلم يسألون عن عبادته فلمّا أخبروا كأنهم + +60 +00:07:24,480 --> 00:07:33,500 +تقالوها بمعنى أنهم عدوها قليلة لأن هذه هي عظمة + +61 +00:07:33,500 --> 00:07:38,220 +الإسلام يسر وسماحة + +62 +00:07:39,540 --> 00:07:48,160 +لا حرج فيه ما جعل الله عليكم في الدين من حرج هذه + +63 +00:07:48,160 --> 00:07:53,780 +هي عظمة الإسلام وحقيقة هذا الدين يريد الله بكم + +64 +00:07:53,780 --> 00:08:02,540 +اليسر ولا يريد بكم الحسر لا تنطع ولا تشدد أبدا + +65 +00:08:02,540 --> 00:08:08,180 +برحمة وصدق الله ربنا العظيم وما أرسلناك إلا رحمة + +66 +00:08:09,150 --> 00:08:15,590 +للعالمين صلى الله عليه وسلم ثم قالوا وأين نحن من + +67 +00:08:15,590 --> 00:08:21,210 +النبي صلى الله عليه وسلم وقد غفر الله له ما تقدم + +68 +00:08:21,210 --> 00:08:29,550 +من ذنبه وما تأخر فقال أحدهم أما أنا أصلي الليلة لا + +69 +00:08:29,550 --> 00:08:36,930 +أرقد أبدا بمعنى لا أنام أبدا وقال الآخر أما أنا + +70 +00:08:36,930 --> 00:08:43,510 +فأصوم النهارة لا أفطر أبدا وقال الثالث أما أنا + +71 +00:08:43,510 --> 00:08:51,870 +فأعتزل النساء لا أتزوج أبدا ظن هؤلاء أنهم بهذا + +72 +00:08:51,870 --> 00:08:58,990 +يخدمون الإسلام وأنهم يطيعون الله ويكونون أقرب إلى + +73 +00:08:58,990 --> 00:09:06,800 +شريعة الإسلام ولكنهم خالفوا بذلك ما جاء به الرسول + +74 +00:09:06,800 --> 00:09:14,740 +صلى الله عليه وسلم من السماحة واليسر إن هذا الدين + +75 +00:09:14,740 --> 00:09:21,330 +يسر ولا شد الدين أحد إلا غلبه فلما سمع بهم النبي + +76 +00:09:21,330 --> 00:09:27,990 +صلى الله عليه وسلم دعاهم وقال لهم أنتم النفر الذين + +77 +00:09:27,990 --> 00:09:32,490 +قلتم كذا وكذا قالوا نعم يا رسول الله وما أردنا إلا + +78 +00:09:32,490 --> 00:09:40,570 +خيرا وهذا هو الجهل أنهم يحيدون عن الإسلام بحب + +79 +00:09:40,570 --> 00:09:41,230 +الإسلام + +80 +00:09:43,760 --> 00:09:48,720 +فعلمهم النبي عليه الصلاة والسلام حقيقة هذا الدين + +81 +00:09:48,720 --> 00:09:55,180 +وأن ما جاءوا به ليس من الدين قال لهم والله إني + +82 +00:09:55,180 --> 00:10:03,530 +لأخشاكم لله وأتقاكم له ولكنني أصوم وأفطر وأصلي و + +83 +00:10:03,530 --> 00:10:11,130 +أرقد وأتزوج النساء فما الرغبة عن سنتي فليس مني صلى + +84 +00:10:11,130 --> 00:10:18,550 +الله عليه وسلم صلى الله عليه وسلم نعم هذه هي + +85 +00:10:18,550 --> 00:10:23,910 +الحكمة الأولى من حكم مشروعية الزواج الاستجابة + +86 +00:10:23,910 --> 00:10:26,350 +لنداء الفطرة + +87 +00:10:27,730 --> 00:10:38,510 +ثانيا إيجاد الراحة النفسية فالزواج فعلا راحة نفسية + +88 +00:10:38,510 --> 00:10:47,550 +لكلا الزوجين حتى ولو كنت في الجنة أليس آدم في + +89 +00:10:47,550 --> 00:10:53,090 +الجنة وقد قال عليه الصلاة والسلام فيها ما لا عين + +90 +00:10:53,090 --> 00:11:02,140 +رأت ولا أذن سمعت ولا خطرة على قلب البشر ومع ذلك خلق + +91 +00:11:02,140 --> 00:11:11,760 +الله لآدم حواء حتى يسكن إليها فالزوجة فعلا وبكل ما + +92 +00:11:11,760 --> 00:11:21,280 +تحمل الكلمة من معنى سكن للزوج ولذا الرجل يحتاج إلى + +93 +00:11:21,280 --> 00:11:28,380 +المرأة والمرأة تحتاج إلى الرجل ولذا فطر الله + +94 +00:11:28,380 --> 00:11:34,660 +المرأة على حب الرجل وفطر الله الرجل على حب المرأة + +95 +00:11:34,660 --> 00:11:44,540 +بل هي من جنس الرجل ومن آياته أن خلق لكم من أنفسكم + +96 +00:11:44,540 --> 00:11:53,960 +يعني من جنسكم وليست غريبة عليكم ومن آياته أن خلق + +97 +00:11:53,960 --> 00:12:01,220 +لكم من أنفسكم أزواجا لتسكنوا إليها وجعل بينكم مودة + +98 +00:12:01,220 --> 00:12:05,940 +ورحمة كما نرى أن هذه الآية تكررت معنا في أكثر من + +99 +00:12:05,940 --> 00:12:12,600 +موضع عندما تكلمنا عن أسس الأسرة المسلمة تكلمنا عن + +100 +00:12:12,600 --> 00:12:17,780 +المودة والرحمة واستشهدنا بهذه الآية من سورة الروم + +101 +00:12:18,600 --> 00:12:23,080 +وعندما تكلمنا عن مشروعية الزواج من القرآن الكريم + +102 +00:12:23,080 --> 00:12:28,540 +استشهدنا بهذه الآية وها نحن أولاء نأتي إليها طورا + +103 +00:12:28,540 --> 00:12:37,730 +آخر عند الحديث عن حكم الزواج نعم وهو إيجاد الراحة + +104 +00:12:37,730 --> 00:12:44,030 +النفسية لقوله تعالى في الآية الكريمة لتسكنوا إليها + +105 +00:12:44,030 --> 00:12:51,110 +وثنأتي إليها أيضا عند الحديث أن التعارف أيضا بين + +106 +00:12:51,110 --> 00:13:00,750 +الناس يكون أيضا من حكم الزواج ثالثا حفظ النوع + +107 +00:13:00,750 --> 00:13:09,400 +الإنساني من الزوال والانقراض وهذا أبناء الطلاب لا + +108 +00:13:09,400 --> 00:13:16,620 +يكونوا إلا بالزواج فالزواج كما قلنا سبيل إلى الولد + +109 +00:13:16,620 --> 00:13:25,540 +وسبيل إلى الذرية الصالحة فالولد شافع ونافع نافع في + +110 +00:13:25,540 --> 00:13:31,520 +الدنيا وشافع في الآخرة كما مر معنا في الحديث + +111 +00:13:31,520 --> 00:13:36,140 +الصحيح إذا مات الإنسان انقطع عمله إلا من ثلاث + +112 +00:13:36,140 --> 00:13:43,390 +وذَكر النبي ولد صالح يدعو له وقد قال الله تبارك + +113 +00:13:43,390 --> 00:13:48,310 +وتعالى في القرآن الكريم والله جعل لكم من أنفسكم + +114 +00:13:48,310 --> 00:13:55,870 +أزواجا وجعل لكم من أزواجكم بنين وحفدة ورزقكم من + +115 +00:13:55,870 --> 00:14:02,370 +الطيبات ومن السنة النبوية للدلالة على مشروعية طلب + +116 +00:14:02,370 --> 00:14:09,000 +الولد ففي الحديث عن معقل بن يسار رضي الله عنه قال + +117 +00:14:09,000 --> 00:14:13,940 +جاء رجل إلى رسول الله صلى الله عليه وسلم فقال يا + +118 +00:14:13,940 --> 00:14:21,500 +رسول الله إني أصبت امرأة ذات حسب ومنصب ومال إلا + +119 +00:14:21,500 --> 00:14:27,950 +أنها لا تلد فأُتزوج بها فنهاه الرسول صلى الله عليه + +120 +00:14:27,950 --> 00:14:34,250 +وسلم ثم أتاه في الثانية وقال له مثل ذلك فنهاه ثم + +121 +00:14:34,250 --> 00:14:38,510 +أتاه الثالثة فقال له مثل ذلك ثم قال صلى الله عليه + +122 +00:14:38,510 --> 00:14:45,340 +وسلم وهذا هو الشاهد في الحديث وعند السؤال يكتفى + +123 +00:14:45,340 --> 00:14:51,560 +بهذا الشاهد قال عليه الصلاة والسلام تزوجوا الولود + +124 +00:14:51,560 --> 00:14:59,980 +الودود فإني مكاثر بكم أو في رواية فإني مباهن بكم + +125 +00:14:59,980 --> 00:15:08,910 +يعني الأمم يوم القيامة فقوله تبارك وتعالى وجعل لكم + +126 +00:15:08,910 --> 00:15:13,690 +من أزواجكم بنين وحفدة دليل من القرآن على مشروعية + +127 +00:15:13,690 --> 00:15:20,850 +طلب الولد والذرية الصالحة وليس بدعا فقد طلب ذلك + +128 +00:15:20,850 --> 00:15:26,470 +الأنبياء من قبلنا ومن السنة قول النبي صلى الله عليه وسلم + +129 +00:15:26,470 --> 00:15:33,910 +تزوجوا الولود الودودة فإني مكاثر بكم أو مباهن بكم + +130 +00:15:33,910 --> 00:15:41,130 +رابعا من حكم مشروعية الزواج تهذيب النفس وإعفاف + +131 +00:15:41,130 --> 00:15:46,950 +المرء نفسه وزوجه من الوقوع في الحرام ونحن تكلمنا + +132 +00:15:46,950 --> 00:15:50,310 +في البند الأول من حكم الزواج عن + +133 +00:15:52,710 --> 00:15:58,610 +الاستجابة لنداء الفطرة إذا كان بنية العفة فهو أجر + +134 +00:15:58,610 --> 00:16:03,970 +وهو صدقة يتقرب بها إلى الله تبارك وتعالى وقد برر + +135 +00:16:03,970 --> 00:16:10,330 +بنا في مشروعية الزواج من السنة النبوية قوله خطابا + +136 +00:16:10,330 --> 00:16:15,390 +للشباب صلى الله عليه وسلم يا معشر الشباب من استطاع + +137 +00:16:15,390 --> 00:16:22,760 +منكم الباءة فليتزوجوا والباقة هنا لا تقتصر على + +138 +00:16:22,760 --> 00:16:34,300 +الباقة المادية من المال فقط وإنما تشمل أيضا صحة + +139 +00:16:34,300 --> 00:16:42,480 +البدن وتشمل أيضا الصحة النفسية فالباقة هنا تشمل + +140 +00:16:42,480 --> 00:16:54,430 +المال وتشمل البدن وتشمل الراحة النفسية أن يكون + +141 +00:16:54,430 --> 00:17:01,770 +سليما معافا من الأمراض البدنية ومن الأمراض النفسية + +142 +00:17:01,770 --> 00:17:06,410 +أقول هذا الكلام لأن البعض يفهم الباقة هنا بالمهر + +143 +00:17:06,930 --> 00:17:15,430 +وما أيسر المغر وما بعده أشد وأختر يا معشر الشباب + +144 +00:17:15,430 --> 00:17:25,170 +من استطاع منكم البائة فليتزوج فإنه أي الزواج أغض + +145 +00:17:25,170 --> 00:17:31,890 +للبصر وأحصن للفرج ومن لم يستطع فعليه بالصوم فإنه + +146 +00:17:31,890 --> 00:17:40,350 +له جَاء أي وقاية وجاء بمعنى قطعة في لغة العرب فهو له + +147 +00:17:40,350 --> 00:17:49,450 +جائي قاطع للشهوة وليستعفف الذين لا يجدون نكاحا حتى + +148 +00:17:49,450 --> 00:17:53,650 +يغنيهم الله فضله ولا عفة تكون أولا بتقوى الله ثم + +149 +00:17:53,650 --> 00:18:03,250 +بالصوم ثم بالرياضة ونحو ذلك من الأمور خامسا من حكم + +150 +00:18:03,250 --> 00:18:10,090 +الزواج التعاون بين الزوجين وتحمل أعباء الحياة + +151 +00:18:10,090 --> 00:18:17,450 +الزوجية ومن ثم تقوية روابط الأسر على تربية الأولاد + +152 +00:18:17,450 --> 00:18:26,470 +تربية سليمة وبه يتم الاستعانة على المصالح أما سادسا + +153 +00:18:26,470 --> 00:18:33,450 +فالمحافظة على الروابط الاجتماعية وتقويتها فالزواج + +154 +00:18:33,450 --> 00:18:41,220 +وسيلة من وسائل ترابط المجتمع وتقويته قوله تبارك + +155 +00:18:41,220 --> 00:18:46,040 +وتعالى كما مرت بنا هذه الآية في أكثر من موضع وهي + +156 +00:18:46,040 --> 00:18:50,500 +في صورة الحجرات يا أيها الناس إن خلقناكم من ذكر + +157 +00:18:50,500 --> 00:18:56,360 +وأنثى وجعلناكم شعوبا وقبائلا لتعارفوا إن أكرمكم + +158 +00:18:56,360 --> 00:19:01,700 +عند الله أتقاكم إن الله عليم خبير صدق الله العظيم + +159 +00:19:01,700 --> 00:19:10,840 +هذه إذن هي حكم الزواجنأتي إلى حكم الزواج إذا حكم + +160 +00:19:10,840 --> 00:19:21,940 +بكسر الحاء بكسر الحاء وفتح الكاف حكم الزواج نعم + +161 +00:19:21,940 --> 00:19:28,380 +جمع حكمة أما حكم الزواج بضم الحاء وإسكان الكاف + +162 +00:19:28,380 --> 00:19:37,140 +والجمع أحكام وهنا يعترض زواجة الأحكام التكليفية + +163 +00:19:37,140 --> 00:19:43,460 +التالية حيث يختلف حكمه اتبعا لحال الشخص الذي يريد + +164 +00:19:43,460 --> 00:19:53,480 +الزواج فالزواج قد يكون فرضا وقد يكون حراما وقد + +165 +00:19:53,480 --> 00:20:00,600 +يكون مكروها وقد يكون سنة مؤكدة في حال اعتدال + +166 +00:20:00,600 --> 00:20:04,220 +الشهوة وهذا ما عليه الجماهير + +167 +00:20:06,570 --> 00:20:14,430 +والأكثرون من أهل العلم متى يكون الزواج فرضا إذا ما + +168 +00:20:14,430 --> 00:20:21,190 +توفر شرطا الشرط الأول إذا تيقن الشخص من وقوعه في + +169 +00:20:21,190 --> 00:20:30,610 +الفاحشة أي الزنا إذا لم يتزوج وهنا لابد أن نضع خطا + +170 +00:20:30,610 --> 00:20:37,970 +أو نخفف قليلا عند قولنا إذا تيقن لأن اليقين هو العلم + +171 +00:20:37,970 --> 00:20:44,990 +مائة بالمائة ومن باب الفائدة ومن باب العلم بالشيء + +172 +00:20:44,990 --> 00:20:52,990 +ولا الجهل به أقول بأن العلم يمر بمراتب أربعة + +173 +00:20:52,990 --> 00:20:59,270 +المرتبة الأولى وهي مرتبة الشك وهي تساوي الطرفين + +174 +00:20:59,270 --> 00:21:06,010 +خمسين في المائة نعم وخمسين في المائة لا المرحلة + +175 +00:21:06,010 --> 00:21:13,290 +الثانية وهي الأعلى رتبة من الشك وهي الظن فالظن قد + +176 +00:21:13,290 --> 00:21:18,750 +يصل إلى ستين أو خمسة وستين في المائة نعم والباقي + +177 +00:21:18,750 --> 00:21:27,910 +لا والمرحلة الثالثة هي غلبة الظن قد تصل إلى سبعين + +178 +00:21:27,910 --> 00:21:34,430 +أو خمسة وسبعين أو حتى ثمانين في المائة نعم والباقي + +179 +00:21:34,430 --> 00:21:41,570 +لا وأما المرحلة الرابعة والأخيرة ألا وهي مرحلة + +180 +00:21:41,570 --> 00:21:50,370 +اليقين واليقين هو الوصول بالعلم إلى مئة بالمئة إذا + +181 +00:21:50,370 --> 00:22:00,010 +مراتب العلم أربعة الشك والظن وغلبة الظن واليقين + +182 +00:22:02,690 --> 00:22:08,750 +متى يكون الزواج فرضًا إذا تيقن الشخص من الوقوع في + +183 +00:22:08,750 --> 00:22:16,290 +الزنا إن لم يتزوج وكذلك الشرط الثاني أن يكون قادرا + +184 +00:22:16,290 --> 00:22:23,010 +على القيام بأعباء الزواج ومسؤوليته من المهر و + +185 +00:22:23,010 --> 00:22:33,330 +النفقات وما يترتب على ذلك من حقوق وواجبات نعم + +186 +00:22:36,980 --> 00:22:42,640 +ثانياً ويكون الزواج حراما متى يكون الزواج حراما + +187 +00:22:42,640 --> 00:22:49,200 +أيضا أقول إذا تيقن الشخص وقلت ضعوا خطا تحت قولنا + +188 +00:22:49,200 --> 00:22:57,220 +إذا تيقن الشخص بمعنى إذا وصل إلى درجة اليقين 100% + +189 +00:22:57,220 --> 00:23:06,320 +أنه إذا تزوج لا محالة 100% سيظلم الزوجة بعدم العدل + +190 +00:23:07,480 --> 00:23:16,680 +وكذلك بعدم القيام بواجباته ومسؤولياته تجاه الزوجة + +191 +00:23:16,680 --> 00:23:23,620 +وهي الحقوق والواجبات الناشئة عن عقد الزواج + +192 +00:23:23,620 --> 00:23:32,600 +كالإنفاق عليها لأن الظلم حرام وإذا كان الزواج + +193 +00:23:32,600 --> 00:23:41,090 +سيؤدي إلى الظلم فما أدى إلى الحرام فهو حرام إذا متى + +194 +00:23:41,090 --> 00:23:47,210 +يكون الزواج فرضًا؟ إذا توافر شرطان إذا تيقن الزوج + +195 +00:23:47,210 --> 00:23:56,360 +أنه بعدم الزواج سيقع في الفاحشة وهو في نفس الوقت + +196 +00:23:56,360 --> 00:24:03,100 +قادر على القيام بالأعباء الزوجية من المهر والنفقة + +197 +00:24:03,100 --> 00:24:09,160 +ونحو ذلك من الحقوق والواجبات ومتى يكون الزواج + +198 +00:24:09,160 --> 00:24:17,780 +حرامًا إذا تيقن أيضًا أنه بزواجه سيظلم الزوجة بعدم + +199 +00:24:17,780 --> 00:24:20,320 +العدل نعم + +200 +00:24:21,580 --> 00:24:31,040 +وكذلك هو غير قادر على القيام بمسؤوليات الزواج من + +201 +00:24:31,040 --> 00:24:37,480 +الإنفاق عليها والنفقة ستأتي من حقوق الزوجة من + +202 +00:24:37,480 --> 00:24:48,840 +المهر والنفقة والعدل ونحو ذلك من حقوق الزوجة في + +203 +00:24:48,840 --> 00:24:55,650 +الإسلام ثالثاً ومتى يكون حرامًا عفواً متى يكون مكروها + +204 +00:24:55,650 --> 00:25:02,210 +إذا انتفى اليقين من الحالة السابقة هو لم يتيقن من + +205 +00:25:02,210 --> 00:25:09,970 +ظلم زوجته ولكنه يخشى الوقوع في ظلم زوجته إذا + +206 +00:25:09,970 --> 00:25:18,690 +انضعوا خطا تحت قوله ولكنه يخشى الوقوع في الظلم إن + +207 +00:25:18,690 --> 00:25:24,970 +تزوجها إذا يكون الزواج حرامًا إذا تيقن الزوج من + +208 +00:25:24,970 --> 00:25:33,570 +الوقوع في الظلم ويكون مكروها إذا انتفى اليقين من + +209 +00:25:33,570 --> 00:25:41,920 +الحالة السابقة ولكنه يخشى الوقوع في الظلم في حال + +210 +00:25:41,920 --> 00:25:48,900 +الزواج وما أدى إلى المكروه فهو مكروه والمكروه كما + +211 +00:25:48,900 --> 00:25:55,500 +نعلم هو دون الحرام أما الحالة الرابعة وهي كون + +212 +00:25:55,500 --> 00:26:05,280 +الشخص معتدل الشهوة وهو ما عليه عظم الناس والأكثرون + +213 +00:26:05,280 --> 00:26:16,540 +من الناس ففي هذه الحال حكم الزواج سنة مؤكدة بحيث + +214 +00:26:16,540 --> 00:26:23,260 +يقوى على ضبط نفسه ولا يخاف ارتكاب المعصية ولا + +215 +00:26:23,260 --> 00:26:29,480 +يخشى ظلم زوجته وهو في نفس الوقت قادر على القيام + +216 +00:26:29,480 --> 00:26:36,590 +بأعباء الزواج ومسؤوليته ففي هذه الحال كما أسلفنا + +217 +00:26:36,590 --> 00:26:44,830 +يكون الزواج سنة مؤكدة وما عليه الجماهير من الفقهاء + +218 +00:26:44,830 --> 00:26:51,270 +ويستدل على ذلك بأحاديث منها قوله صلى الله عليه + +219 +00:26:51,270 --> 00:26:57,990 +وسلم من أحب فطرتي فليستن بصنتي وإن من صنتي نكاح + +220 +00:26:58,530 --> 00:27:04,270 +هذا دليل على سنة النكاح في حال اعتدال الشهوة + +221 +00:27:04,270 --> 00:27:14,350 +وقوله صلى الله عليه وسلم ثلاثة حق على الله عونهم + +222 +00:27:14,350 --> 00:27:21,470 +المجاهد في سبيل الله والمكاتب الذي يريد الأداء + +223 +00:27:22,120 --> 00:27:30,980 +والناكح الذي يريد العفاف صلى الله عليه وسلم ويمكن + +224 +00:27:30,980 --> 00:27:39,320 +الاستشهاد أيضًا بأحاديث أخرى قد مرت بنا في مشروعية + +225 +00:27:39,320 --> 00:27:44,820 +الزواج وغيره مثل قوله صلى الله عليه وسلم يا معشر + +226 +00:27:44,820 --> 00:27:51,520 +الشباب من استطاع منكم البائة فليتزوج فإنه أي + +227 +00:27:51,520 --> 00:27:59,060 +الزواج أغض للبصر وأحصن للفرج ومن لم يستطع فعليه + +228 +00:27:59,060 --> 00:28:06,080 +بالصوم فإنه له جَاء صلى الله عليه وسلم فهذه + +229 +00:28:06,080 --> 00:28:12,830 +الأحاديث الثلاثة وغيرها كثير كلها تدل على سنة + +230 +00:28:12,830 --> 00:28:22,150 +الزواج وأنه سنة مؤكدة في حال اعتدال الشهوة نعم + +231 +00:28:22,150 --> 00:28:31,370 +خامساً من مباحث المبحث الثالث وهو الزواج الحقوق + +232 +00:28:31,370 --> 00:28:40,230 +الزوجية والحقوق الزوجية تنقسم إلى أقسام ثلاثة القسم + +233 +00:28:40,230 --> 00:28:49,910 +الأول حقوق خاصة بالزوج على زوجته والقسم الثاني + +234 +00:28:49,910 --> 00:28:57,910 +حقوق خاصة بالزوجة على زوجها والقسم الثالث حقوق + +235 +00:28:57,910 --> 00:29:05,070 +مشتركة نبدأ بالقسم الأول وهو حقوق الزوج على الزوجة + +236 +00:29:05,070 --> 00:29:15,410 +ابتداءً بالطاعة فإن طاعة الزوجة واجبة فإن طاعة الزوج + +237 +00:29:15,410 --> 00:29:25,190 +واجبة على زوجته نعم ولكن الطاعة هنا ونخفف قليلا عند + +238 +00:29:25,190 --> 00:29:33,850 +هذه الكلمة ليست مطلقة أقول ليست مطلقة فإن طاعة + +239 +00:29:33,850 --> 00:29:41,670 +الزوج واجبة في طاعة الله فإذا ما أمر الزوج بمعصية + +240 +00:29:41,670 --> 00:29:48,850 +الله كأن لا تصلي مثلاً أو أن تفطر في شهر رمضان أو + +241 +00:29:48,850 --> 00:29:54,620 +أن تخرج سافرة متبرجة أو أن تخالط الرجال الأجانب + +242 +00:29:54,620 --> 00:30:01,820 +فمعصية الزوج في هذه الحال واجبة لأنه لا طاعة + +243 +00:30:01,820 --> 00:30:08,260 +لمخلوق في معصية الخالق إذا طاعة الزوج ليست مطلقة + +244 +00:30:08,260 --> 00:30:14,600 +في كل ما يأمر به الزوج وإنما طاعته واجبة في حدود + +245 +00:30:14,600 --> 00:30:23,010 +الشرعية فإذا أمر بمعصية الله فلا طاعة له إطلاقا + +246 +00:30:23,010 --> 00:30:33,450 +والطاعة هنا أيضًا ليست استبدادًا أو تسلطًا أو إكراها + +247 +00:30:33,450 --> 00:30:45,750 +وظلمًا للزوجة وإنما هي الرحمة والمودة والمشورة + +248 +00:30:45,750 --> 00:30:53,920 +أيضاً بل كما قال ابن عباس هي أيضًا الإيثار بمعنى أن + +249 +00:30:53,920 --> 00:31:02,020 +يؤثر الزوج وأهله على نفسه قد يجوع الزوج من أجل + +250 +00:31:02,020 --> 00:31:12,100 +شبع الزوجة والولد وقد لا ينام يبقى طيلة الليل + +251 +00:31:12,100 --> 00:31:20,560 +مستيقظًا من أجل راحة أهله وقد يلبسوا العتيقة من + +252 +00:31:20,560 --> 00:31:27,660 +الثياب من أجل زوجته وولده وهذا معنى قوله تبارك + +253 +00:31:27,660 --> 00:31:33,260 +وتعالى الرجال قوامون على النساء بما فضل الله بعضهم + +254 +00:31:33,260 --> 00:31:43,040 +على بعض وبما أنفقوا من أموالهم نعم هذه هي الدرجة + +255 +00:31:43,040 --> 00:31:53,570 +وللرجال عليهن درجة هي الطاعة أو القوامة إذا طاعة + +256 +00:31:53,570 --> 00:32:02,010 +الزوجة لزوجها أول حقوق الرجل على المرأة ثانيًا + +257 +00:32:02,010 --> 00:32:09,760 +الأمانة والمقصود بالأمانة هنا أن الزوجة تكون مؤتمنة + +258 +00:32:09,760 --> 00:32:19,880 +على نفسها في غياب زوجها وفي حضوره فالزوجة + +259 +00:32:19,880 --> 00:32:28,660 +سر بينها وبين زوجها لا يطلع على سر زوجها وأخذنا منكم + +260 +00:32:28,660 --> 00:32:35,670 +مثاقًا خليظًا وقد أفضى بعضكم إلى بعض + +261 +00:32:35,670 --> 00:32:42,710 +وكذلك هي مؤتمنة على مال زوجها فليس لها إلا النفقة + +262 +00:32:42,710 --> 00:32:51,460 +فليس لها أن تتصدق حتى في سبيل الله من مال زوجها إلا + +263 +00:32:51,460 --> 00:32:57,260 +بإذن زوجها أما إن كان لها مال فلها أن تتبرع به كيف + +264 +00:32:57,260 --> 00:33:01,460 +شاءت لأنه كما سيأتي معنا عند الحديث عن ما كانت + +265 +00:33:01,460 --> 00:33:06,140 +المرأة في الإسلام أن المرأة لها ذمة مالية في + +266 +00:33:06,140 --> 00:33:12,000 +الإسلام نعم أما من مال زوجها فليس لها إلا النفقة من + +267 +00:33:12,000 --> 00:33:21,940 +السكن ومن الطعام ومن الكسوة نعم وكذلك هي مؤتمنة + +268 +00:33:21,940 --> 00:33:30,020 +على تربية أولادها ومنذ الصغر تربيه على الأخلاق وعلى + +269 +00:33:30,020 --> 00:33:39,370 +الأداب السامية الرفيعة بعيدا عن أهل السوء و + +270 +00:33:39,370 --> 00:33:47,390 +الفجور فتذهب به إلى المسجد من أجل الصلاة ومن أجل + +271 +00:33:47,390 --> 00:33:54,570 +حفظ القرآن الكريم وخاصة يتمرن كما مر بنا في مراحل + +272 +00:33:54,570 --> 00:33:58,930 +توجيه الخلق في النفس البشرية بعد السابعة مروا + +273 +00:33:58,930 --> 00:34:03,150 +أولادكم بالصلاة لسبع سنين وا ضربوهم عليها إذا بلغوا + +274 +00:34:03,150 --> 00:34:11,470 +عشر سنين وفرقوا بينهم في المضاجع نعم والله تبارك + +275 +00:34:11,470 --> 00:34:17,830 +وتعالى يقول فالصالحات قانتات حافظات للغيب بما حفظ + +276 +00:34:17,830 --> 00:34:23,530 +الله وفي الحديث الشريف يقول صلى الله عليه وسلم + +277 +00:34:23,530 --> 00:34:32,330 +كلكم راعٍ وكلكم مسئول عن رعيته والأمير راعٍ والرجل + +278 +00:34:32,330 --> 00:34:38,290 +راعٍ على أهل بيته والمرأة راعية على بيت زوجها + +279 +00:34:38,290 --> 00:34:45,450 +وولده فكلكم راعٍ وكلكم مسئول عن رعيته فعلى الزوجة + +280 +00:34:45,450 --> 00:34:51,370 +أن تحصن تربية أولادها وفق الدين والفضيلة وأن تصون + +281 +00:34:51,370 --> 00:34:59,240 +نفسها عما يدنّس شرفها وشرف زوجها وأن تحافظ عليها + +282 +00:34:59,240 --> 00:35:06,260 +ماله نعم هذه أخلاق المرأة الصالحة وصدق الرسول عليه + +283 +00:35:06,260 --> 00:35:10,860 +الصلاة والسلام الدنيا متاع وخير متاعها المرأة + +284 +00:35:10,860 --> 00:35:15,880 +الصالحة التي وصفها بقوله صلى الله عليه وسلم إن نظر + +285 +00:35:15,880 --> 00:35:22,030 +إليها صرته وإن أمرها أطاعته وإن أقسم عليها أبرته + +286 +00:35:22,030 --> 00:35:29,130 +وإن غاب عنها حافظته في ماله وفي أرضها بأبي أنت + +287 +00:35:29,130 --> 00:35:34,390 +وأمي يا رسول الله صلى الله عليه وسلم ثالثا حسن + +288 +00:35:34,390 --> 00:35:42,480 +المعاشرةأيضا من حق الزوج على زوجته فيجب على الزوجة + +289 +00:35:42,480 --> 00:35:51,560 +معاشرة زوجها بالمعروف و ذلك بكف الأذى وغيره فلا + +290 +00:35:51,560 --> 00:35:59,700 +تؤذيه ولا تشق عليه كما عليه معاشرتها بالمعروف + +291 +00:35:59,700 --> 00:36:07,800 +لقوله صلى الله عليه وسلم أي امرأة ماتت وزوجها راضٍ + +292 +00:36:07,800 --> 00:36:17,740 +عنها دخلت الجنة فالزوج فعلا هو جنتها ونارها إذا + +293 +00:36:17,740 --> 00:36:25,240 +أطاعته فلها الجنة وإذا عصته فهي في النار وبئس + +294 +00:36:25,240 --> 00:36:30,140 +القرار والعياذ بالله احفظوا هذا الحديث أي امرأة + +295 +00:36:30,140 --> 00:36:36,080 +ماتت وزوجها راض عنها دخلت الجنة كيف أن طاعة الزوج + +296 +00:36:36,080 --> 00:36:46,440 +ورضا الزوج والإحسان إلى الزوج باب من أبواب الجنة إن + +297 +00:36:46,440 --> 00:36:53,040 +شاء الله ورابعا من حق الزوج على زوجته أيضا + +298 +00:36:53,040 --> 00:37:04,980 +التأديب وهنا لنا وقفات أما أولا هل كل زوجة تؤدب؟ + +299 +00:37:04,980 --> 00:37:09,620 +ليس كل زوجة تؤدب افهموا هذا + +300 +00:37:12,410 --> 00:37:20,150 +نعم الزوجة التي تؤدب هي الزوجة العاصية الزوجة + +301 +00:37:20,150 --> 00:37:32,630 +الناشزة التي لا تطيع زوجها في شرع الله وكما أمر + +302 +00:37:32,630 --> 00:37:38,220 +الله تبارك وتعالى كما قلنا الطاعة في الخير والطاعة + +303 +00:37:38,220 --> 00:37:44,080 +في المعروف أما إذا عصت الزوجة زوجها في معصية الله + +304 +00:37:44,080 --> 00:37:50,920 +لأنه أمرها بما يخالف شرع الله فليست ناشزة ولا + +305 +00:37:50,920 --> 00:37:59,840 +تستحق التأديب إذا هذه واحدة ليس كل زوجة تؤدب إنما + +306 +00:37:59,840 --> 00:38:05,620 +الزوجة التي تؤدب هي الزوجة التي لا تطيع زوجها فيما + +307 +00:38:05,620 --> 00:38:12,140 +أمر ربها سبحانه وتعالى وهذا معنى قوله تبارك وتعالى + +308 +00:38:12,140 --> 00:38:19,380 +والله أعلى وأعلم والتي تخافون نشوزهن أي عصيانهن + +309 +00:38:19,380 --> 00:38:30,620 +وترفعن عن طاعتكم معاشر الأزواج ثانيا تأديب الزوجة + +310 +00:38:31,470 --> 00:38:41,530 +يكون على مراحل ثلاث مرتبة وهنا أراني أعود إلى + +311 +00:38:41,530 --> 00:38:46,930 +الوراء قليلا عندما تكلمت عن مراحل توجيه الخلق في + +312 +00:38:46,930 --> 00:38:55,170 +النفس البشرية في فصل الأخلاق في الفصل الثالث وقلنا + +313 +00:38:55,170 --> 00:39:03,070 +هذه المراحل لابد أن تخفض مرتبة لأن كل مرحلة ترتبط + +314 +00:39:03,070 --> 00:39:14,150 +بما قبلها فقلت أولا التأثر بالخير أو الشر وثانيا + +315 +00:39:14,150 --> 00:39:22,330 +استقرار هذا الخلق إيجابا أو سلبا ورسوخه في النفس + +316 +00:39:22,330 --> 00:39:28,810 +البشرية يترتب على ذلك إنعكاس هذا الخلق إيجابا أو + +317 +00:39:28,810 --> 00:39:35,810 +سلبا على تصرفات الشخص وسلوكيته والآن أراني مضطرا + +318 +00:39:35,810 --> 00:39:44,610 +إلى التذكير لأن هذا موضع أسئلة فالمراحل ثلاثة + +319 +00:39:44,610 --> 00:39:54,240 +المرحلة الأولى مرحلة الوعظ بالكلمة الطيبة وأن يقوم + +320 +00:39:54,240 --> 00:39:59,480 +الزوج بتذكير الزوجة بمستقبلها + +321 +00:39:59,480 --> 00:40:07,700 +في حال الطلاق إذا لم تعد إلى الجادة وإلى الرشاد + +322 +00:40:07,700 --> 00:40:16,480 +وإلى الصواب وإلى طاعة الزوج نعم فإن لم ينفع الوعظة + +323 +00:40:17,680 --> 00:40:24,900 +فهجران في المضجع وما المقصود بالمضجع هنا هو فراش + +324 +00:40:24,900 --> 00:40:33,940 +الزوجية بمعنى السرير الذي ينام عليه الزوجان فلا + +325 +00:40:33,940 --> 00:40:43,520 +يصح الهجران في مكان آخر بعيدا عن غرفة النوم بأن + +326 +00:40:43,520 --> 00:40:52,090 +يدير لها ظهره ولكن لا يعني الهجران أن لا يكلمها أو + +327 +00:40:52,090 --> 00:40:59,810 +أن لا يأكل طعامها يفعل كل شيء ما عدا الجماعة بأن + +328 +00:40:59,810 --> 00:41:09,650 +لا يجامعها لعلها تعود إلى رشدها وإلى صوابها هذا هو + +329 +00:41:09,650 --> 00:41:16,550 +معنى الهجران في المضجع فإن لم ينفع يرحلوا + +330 +00:41:17,550 --> 00:41:26,270 +إلى المرتبة الثالثة وهي الضرب وأي ضرب ليس الضرب + +331 +00:41:26,270 --> 00:41:32,870 +مطلقا أيضا وإنما كما فسره ابن عباس رضي الله + +332 +00:41:32,870 --> 00:41:40,530 +عنهما الضرب غير المبرح كما قال الضرب بالسواك لأن + +333 +00:41:40,530 --> 00:41:48,170 +الضرب حقيقة لا يليق بالرجال الكامل إنما هو من أخلاق + +334 +00:41:48,170 --> 00:41:55,330 +عامة الناس والرسول صلى الله عليه وسلم وقد نزلت + +335 +00:41:55,330 --> 00:42:04,690 +عليه هذه الآيات والتي تخافون نشوزهن أولا فعظوهن + +336 +00:42:04,690 --> 00:42:11,810 +فإن لم ينفع وهجروهن في المضاجع فإن لم ينفع + +337 +00:42:11,810 --> 00:42:17,130 +واضربوهن فإن أطعنكم فلا تبغوا + +338 +00:42:17,130 --> 00:42:20,330 +عليهن سبيلا إن الله كان عليا + +339 +00:42:20,330 --> 00:42:28,810 +كبيرا النبي ﷺ الذي نزل عليه هذه الآيات لم يضرب + +340 +00:42:28,810 --> 00:42:36,310 +امرأة قط إنما ضرب بيده في سبيل الله إذا انتهكت + +341 +00:42:36,310 --> 00:42:40,550 +حرمات الله ولذلك + +342 +00:42:40,550 --> 00:42:52,280 +لا يكرمهن إلا كريم ولا يسيء إليهن إلا لئيم والعياذ + +343 +00:42:52,280 --> 00:42:56,420 +بالله بل قال عليه الصلاة والسلام رفقا بالقوارير + +344 +00:42:56,420 --> 00:43:03,980 +والقوارير جمع قارورة وهي الزجاجة التي سرعان ما + +345 +00:43:03,980 --> 00:43:12,600 +تكسر ولذلك فسر العلماء الضرب غير المبرح أولا بأنه + +346 +00:43:13,380 --> 00:43:22,840 +الذي لا يكسر عظما ولا يخدش جلدا ولا يترك أثرا أو + +347 +00:43:22,840 --> 00:43:33,380 +علامة تشوه بدنها ولا يقبح بمعنى لا يصب ولا يشتم + +348 +00:43:33,380 --> 00:43:45,000 +كما نرى من بعض الناس الجهلاء والعياذ بالله وأن يتقى + +349 +00:43:45,000 --> 00:43:54,220 +الوجه وهذا أهم شيء في الضرب أن يتقى الوجه لماذا + +350 +00:43:54,220 --> 00:44:01,560 +يتقى الوجه فلا يمثل وجه ولا يقترب منه لأن وجه + +351 +00:44:01,560 --> 00:44:08,240 +المرأة هو جماع محاسنها ولذلك المرأة في الإسلام + +352 +00:44:08,240 --> 00:44:17,260 +عندما تخطب تكشف عن وجهها وعندما خطب أحد المهاجرين + +353 +00:44:17,260 --> 00:44:21,360 +امرأة من الأنصار قال هل نظرت إليها قال لأ قال انظر + +354 +00:44:21,360 --> 00:44:28,700 +إليها فإن في أعين الأنصار شيئا قيل ضيقا في الأعين + +355 +00:44:28,700 --> 00:44:32,220 +فإنه + +356 +00:44:32,220 --> 00:44:38,100 +كما في الحديث أحرى أن يُدم بينكما بمعنى أن يكون + +357 +00:44:38,100 --> 00:44:44,840 +بينكما أُلفة والألفة هي الألفة والمحبة فالصنة عند + +358 +00:44:44,840 --> 00:44:51,740 +الخطبة أن تكشف المرأة وجهها نعم فإذا ما ضربها + +359 +00:44:51,740 --> 00:44:59,560 +وشوها وجهها كأن يفقأ عينها أو يجدع أنفها أو يقط + +360 +00:44:59,560 --> 00:45:05,060 +أذنها أو أن يكسر أسنانها فقد شوهها وضربها إذا ما + +361 +00:45:05,060 --> 00:45:10,920 +طلقها وهذا يؤخر زواجها بعد طلاقها ولذا النبي عليه + +362 +00:45:10,920 --> 00:45:16,860 +الصلاة والسلام قال اتقى الوجه نعم وهذا أخلاق + +363 +00:45:16,860 --> 00:45:28,720 +أعظماء من الرجال كما ورد عن القاضي شريح وقد كانت + +364 +00:45:28,720 --> 00:45:36,450 +لهم أمة واسمها زينب وتأتي النساء يشتكين إلى + +365 +00:45:36,450 --> 00:45:43,410 +القاضي أزواجهن من ضربهن فكان + +366 +00:45:43,410 --> 00:45:54,230 +ينعى هذه الأخلاق وقال رأيت رجالًا يضربون نساءهم فشلت + +367 +00:45:54,230 --> 00:46:00,870 +يميني يوم أضرب زينب نعم هذه أخلاق الرجال الرجال + +368 +00:46:01,580 --> 00:46:08,120 +العظماء الكامل رأيت رجالًا يضربون نساءهم فشلت يميني + +369 +00:46:08,120 --> 00:46:14,200 +يوم أضرب زينب وكأني بهذه الكلمات أرد على أعداء + +370 +00:46:14,200 --> 00:46:19,660 +الإسلام الذين قالوا بأن الإسلام يضرب المرأة نقول + +371 +00:46:19,660 --> 00:46:26,170 +لا الضرب غير المبرح كالسواك يعني كقلم الرصاص + +372 +00:46:26,170 --> 00:46:34,870 +بالوسادة نعم هكذا ضرب دلع وليس ضرب تكثير نعم + +373 +00:46:34,870 --> 00:46:43,630 +هذا ما أردت قوله خامسا وأخيرا في حق الزوج نكتفي + +374 +00:46:43,630 --> 00:46:50,710 +هنا الحداد على الزوج وهذا من باب الوفاء للزوج إذا + +375 +00:46:50,710 --> 00:46:57,720 +مات الزوج يجب على الزوجة الحداد بأن تظهر الحزن + +376 +00:46:57,720 --> 00:47:05,020 +والأسى على فراقه أربعة أشهر وعشرة أيام ومئة وثلاثون + +377 +00:47:05,020 --> 00:47:12,240 +يوما اعترافا بالفضل والجميل وذلك بتجنب الطيب + +378 +00:47:12,240 --> 00:47:20,110 +والزينة وأن تلزم بيت الزوجية فلا تبارحه إلا + +379 +00:47:20,110 --> 00:47:26,570 +للضرورة كعلاج أو سوق لشراء طعام أو شراب لأولادها + +380 +00:47:26,570 --> 00:47:32,290 +أو كأن تذهب إلى مصلحة كالبنك أو البريد لأجل راتب + +381 +00:47:32,290 --> 00:47:39,750 +أو نحو ذلك وفي هذه الحالة أيضا نلفت الأنظار إلى حكم + +382 +00:47:39,750 --> 00:47:45,910 +شرعي تكلم عنه الكتاب مختصرا ولكن لا مانع أن نشرحه + +383 +00:47:45,910 --> 00:47:53,110 +لأنه يتعلق بالأبواب الفقهية لا يحل خطبة المعتدة من + +384 +00:47:53,110 --> 00:48:06,050 +وفاة صراحة نعم ولكن يصح خطبتها تعريضا نعم لا جناح + +385 +00:48:06,050 --> 00:48:13,710 +عليكم فيما عرضتم به من خطبة النساء والخطبة كما + +386 +00:48:13,710 --> 00:48:20,830 +ترون بكسر الخاء أما الخطبة بالضم فهي خطبة الجمعة + +387 +00:48:20,830 --> 00:48:26,890 +أي نعم أما دليل العدة قوله تبارك وتعالى والذين + +388 +00:48:26,890 --> 00:48:33,780 +يتوفون منكم ويتركون أزواجا يتربصن بأنفسهن أربعة + +389 +00:48:33,780 --> 00:48:39,520 +أشهر وعشرة فإذا بلغنا أجلهن بمعنى إذا انتهت العدة + +390 +00:48:39,520 --> 00:48:44,340 +الشرعية وهي مئة وثلاثون يوما أو أربعة أشهر وعشر + +391 +00:48:44,340 --> 00:48:50,140 +فلا جناح عليكم فيما فعلن في أنفسهن بالمعروف + +392 +00:48:50,140 --> 00:48:55,780 +يعني إذا ما تزوجن فلا تحولوا بينهن وبين الزواج + +393 +00:48:55,780 --> 00:49:03,550 +والله بما تعملون خبير وهنا لابد من أن أذكر بعدة + +394 +00:49:03,550 --> 00:49:08,190 +الطلاق وسنأتي إلى الطلاق ومن خلال الأسئلة و + +395 +00:49:08,190 --> 00:49:13,950 +تصحيح الإجابات وجدت أن بعض الطلاب يخلطون بين عدة + +396 +00:49:13,950 --> 00:49:19,350 +المطلقة وبين عدة المتوفى عنها زوجها فعدة المطلقة + +397 +00:49:19,350 --> 00:49:25,510 +تسعون يوما ثلاثة أشهر نعم والمطلقات يتربصن + +398 +00:49:25,510 --> 00:49:33,330 +بأنفسهن ثلاثة قراء والقراء جمع قرء وهو بمعنى الحيض + +399 +00:49:33,330 --> 00:49:40,510 +عند الحنفية وبمعنى الطهر عند الشافعية تحيد ثلاثة + +400 +00:49:40,510 --> 00:49:50,010 +حيدات أو تطهر ثلاثة أطهار واليوم القاضي من باب عدم + +401 +00:49:50,010 --> 00:49:55,150 +إحراج المرأة يحسبون في المحاكم الشرعية تسعين يوما + +402 +00:49:55,150 --> 00:50:03,200 +من يوم طلاقها فانتبهوا إلى ذلك ثلاثة أشهر عدة + +403 +00:50:03,200 --> 00:50:09,360 +المطلقة وأربعة أشهر وعشرة عدة المتوفى عنها زوجها + +404 +00:50:09,360 --> 00:50:13,920 +أقول قولي هذا وأستغفر الله لكم والسلام عليكم + +405 +00:50:13,920 --> 00:50:18,000 +ورحمة الله وبركاته نكون على موعد إن أحيانا الله + +406 +00:50:18,000 --> 00:50:23,700 +وكنا من أهل الدنيا مع القسم الثاني حقوق الزوجة على + +407 +00:50:23,700 --> 00:50:29,480 +زوجها والقسم الثالث الحقوق المشتركة والسلام عليكم + +408 +00:50:29,480 --> 00:50:30,920 +ورحمة الله وبركاته diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/IXZ2cpoWhzo_postprocess.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/IXZ2cpoWhzo_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..5f8c3575958c9b852b65d9f850dabcfea6f9ac92 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/IXZ2cpoWhzo_postprocess.srt @@ -0,0 +1,1632 @@ +1 +00:00:04,980 --> 00:00:07,740 +أعوذ بالله السميع العلي من الشيطان الرجيم بسم الله + +2 +00:00:07,740 --> 00:00:10,900 +الرحمن الرحيم الحمد لله والصلاة والسلام على رسول + +3 +00:00:10,900 --> 00:00:16,200 +الله دائما وأبدا اللهم صلى على سيدنا محمد وعلى آله + +4 +00:00:16,200 --> 00:00:21,560 +وصحبه وسلم أجمعين أعزاء الطلاب قبل ذي بدء أرحبكم + +5 +00:00:21,560 --> 00:00:25,940 +في محاضرة جديدة وأحييكم بتحية الإسلام العظيم فسلام + +6 +00:00:25,940 --> 00:00:32,500 +الله عليكمورحمته وبركاته ما زلنا مع الفصل الرابعي + +7 +00:00:32,500 --> 00:00:38,200 +وهو نظام الأسرة في الإسلام واليوم نكمل معا وسويا + +8 +00:00:38,200 --> 00:00:49,000 +ان شاء الله المبحث الثالث وهو بعنوان الزواج وقد + +9 +00:00:49,000 --> 00:00:58,640 +وصلنا إلى حكمة مشروعية الزواجوهنا وقبل البدء في + +10 +00:00:58,640 --> 00:01:02,940 +الحديث عن حكم مشروعية الزواج لابد من أن ألفط + +11 +00:01:02,940 --> 00:01:11,580 +الأنظار إلى حكم وحكم لعلها لم تأتي مشكلة ولكن + +12 +00:01:11,580 --> 00:01:19,240 +نحاولأن نشكلها في الامتحان فهناك حكمة و هي مفرد + +13 +00:01:19,240 --> 00:01:32,460 +حكم بكسر الحق و فتح الكاف حكم و المفرد حكم و سيأتي + +14 +00:01:32,460 --> 00:01:39,160 +بعد قليل حكم و الجمع أحكام و هي بضم الحق و إسكان + +15 +00:01:39,160 --> 00:01:46,940 +الكافوجب التنويه إلى الفرق بين حكم وبين حكم اللي + +16 +00:01:46,940 --> 00:01:53,360 +لم تأتي مشكلة في السؤال نعود إلى حكمة مشروعية + +17 +00:01:53,360 --> 00:02:02,000 +الزواج وأول هذه الحكم الاستجابة لنداء الفطرة + +18 +00:02:02,000 --> 00:02:11,410 +وتلبية الحاجة الغريزية ولكل شخصسوي معتد للفطرة + +19 +00:02:11,410 --> 00:02:23,070 +شهوة و غريزة والذي لا يشعر بها فيحتاج إلى استشارة + +20 +00:02:23,070 --> 00:02:33,310 +الطبيب و هذه الشهوة لها قنوات شرعية ففي الإسلام + +21 +00:02:33,310 --> 00:02:46,260 +لكل شهوةقنوات شرعية نعم فشهوة المال مصدرها العمل + +22 +00:02:46,260 --> 00:02:56,040 +والكسب والبيع أو التجارة نعم وشهوة الرئاسة مثلا + +23 +00:02:56,040 --> 00:03:01,900 +الانتخابات والوصول + +24 +00:03:01,900 --> 00:03:08,850 +عبر الشورى والديمقراطيةبعيدا عن الإنقلابات و سفك + +25 +00:03:08,850 --> 00:03:17,670 +الدماء و أما شهوته الفرد فقنعتها الشرعية الحلال هي + +26 +00:03:17,670 --> 00:03:29,250 +الزواج و لذا كانت الشهوة من أجل أمرين الأمر الأول + +27 +00:03:29,250 --> 00:03:39,260 +هو اللأفةبالحلال عبر القناة الشرعية ولا قناة شرعية + +28 +00:03:39,260 --> 00:03:46,960 +لتفريغ هذه الشهوة سواء الزواج والذين هم لفروجهم + +29 +00:03:46,960 --> 00:03:53,180 +حافظون إلا على أزواجهم أو ما ملكت أيمانهم فإنهم + +30 +00:03:53,180 --> 00:03:59,200 +غير ملومين فمن ابتغى وراء ذلك فأولئك هم العدون + +31 +00:04:00,200 --> 00:04:10,540 +والأمر الثاني هو ابتغاء الولد والذرية الصالحة نعم + +32 +00:04:10,540 --> 00:04:15,020 +فالرسول عليه الصلاة والسلام يقول إذا مات ابن آدم + +33 +00:04:15,020 --> 00:04:21,520 +أو إذا مات الإنسان إنقطع عمله إلا من ثلاث وذكر + +34 +00:04:21,520 --> 00:04:32,710 +منها ولد صالح يدعو له هذا من حكمالزواج اللي افته + +35 +00:04:32,710 --> 00:04:35,030 +بالزوجة الصالحة + +36 +00:04:37,500 --> 00:04:43,620 +والذرية الصالحة والولد الصالح إن شاء الله تبارك + +37 +00:04:43,620 --> 00:04:48,780 +وتعالى وقد طلب الأنبياء الولد الصالح على لسان + +38 +00:04:48,780 --> 00:04:54,180 +الخليل عليه السلام ربي هبلي من الصالحين وعلى لسان + +39 +00:04:54,180 --> 00:04:58,100 +زكريا عليه السلام ربي لا تذرني فردا وأنت خير + +40 +00:04:58,100 --> 00:05:06,750 +الوارثين بل إن هذا اللقاء العاطفيبين الزوجين إن + +41 +00:05:06,750 --> 00:05:17,690 +كان بقصد العفة وبقصد الولد فهو ليس مجرد متعة فقط + +42 +00:05:17,690 --> 00:05:26,870 +وإنما هي صداقة أيضا لقوله صلى الله عليه وسلم كما + +43 +00:05:26,870 --> 00:05:35,740 +في الحديث الشريف وفي بضع أحدكم صداقة والبضعهنا هو + +44 +00:05:35,740 --> 00:05:42,820 +الفرج ويُقنى به عن الجماع أو الاتصال الحلال بين + +45 +00:05:42,820 --> 00:05:50,360 +الزوجين فالبدع بضم البا هو الفرج من كلا الزوجين + +46 +00:05:50,360 --> 00:05:59,330 +وأما البضع بالكثر فهو من ثلاثة إلىسبعة دون العشرة + +47 +00:05:59,330 --> 00:06:04,730 +كما في قول الله تعالى في صورة يوسف فلبس في السجن + +48 +00:06:04,730 --> 00:06:12,750 +بضعة سنين وفي بضعة أحدكم صداقة فعجب الصحابة من ذلك + +49 +00:06:12,750 --> 00:06:19,790 +وقالوا يا رسول الله أيأتي أحدنا شهوته ويكون له أجر + +50 +00:06:20,990 --> 00:06:26,590 +قال نعم أرأيتم لو وضعها في حرام أيكون عليه وزر + +51 +00:06:26,590 --> 00:06:34,970 +كذلك لو وضعها في حلال يكون له أجر فهذه الشهوة إذا + +52 +00:06:34,970 --> 00:06:41,450 +كانت في حلال وفي موضع حلال عبر الزواج كما أسلفنا + +53 +00:06:41,450 --> 00:06:44,630 +فهي أجر وصدقة + +54 +00:06:46,150 --> 00:06:51,470 +وإن كانت في فرج حرام كالذنب إنه كان فحشة وساء + +55 +00:06:51,470 --> 00:06:57,770 +سبيله والعياذ بالله كانت معصية وكانت إثما مبينا + +56 +00:06:57,770 --> 00:07:03,950 +والرسول عليه الصلاة والسلام قد أقر هذه الحقيقة في + +57 +00:07:03,950 --> 00:07:10,330 +الحديث الصحيح الذي رواه البخاري عن أنس بن مالك رضي + +58 +00:07:10,330 --> 00:07:16,880 +الله عنهأنه جاء ثلاثة رهط إلى بيوت أزواج النبي صلى + +59 +00:07:16,880 --> 00:07:24,480 +الله عليه وسلم يسألون عن عبادته فلمّا أخبروا كأنهم + +60 +00:07:24,480 --> 00:07:33,500 +تقالوها بمعنى أنهم عدوها قليلة لأن هذه هي عظمة + +61 +00:07:33,500 --> 00:07:38,220 +الإسلام يسر وسماحة + +62 +00:07:39,540 --> 00:07:48,160 +لا حرج فيه ما جعل الله عليكم في الدين من حرج هذه + +63 +00:07:48,160 --> 00:07:53,780 +هي عظمة الإسلام وحقيقة هذا الدين يريد الله بكم + +64 +00:07:53,780 --> 00:08:02,540 +اليسر ولا يريد بكم الحسر لا تنطع ولا تشدد أبدا + +65 +00:08:02,540 --> 00:08:08,180 +برحمة وصدق الله ربنا العظيم وما أرسلناك إلا رحمة + +66 +00:08:09,150 --> 00:08:15,590 +للعالمين صلى الله عليه وسلم ثم قالوا وأين نحن من + +67 +00:08:15,590 --> 00:08:21,210 +النبي صلى الله عليه وسلم وقد غفر الله له ما تقدم + +68 +00:08:21,210 --> 00:08:29,550 +من ذنبه وما تأخر فقال أحدهم أما أنا أصلي الليلة لا + +69 +00:08:29,550 --> 00:08:36,930 +أرقد أبدا بمعنى لا أنام أبداوقال الآخر أما أنا + +70 +00:08:36,930 --> 00:08:43,510 +فأصوم النهارة لا أفطر أبدا وقال الثالث أما أنا + +71 +00:08:43,510 --> 00:08:51,870 +فأعتزل النساء لا أتزوج أبدا ظن هؤلاء أنهم بهذا + +72 +00:08:51,870 --> 00:08:58,990 +يخدمون الإسلام وأنهم يطيعون الله ويكونون أقرب إلى + +73 +00:08:58,990 --> 00:09:06,800 +شريعة الإسلامولكنهم خالفوا بذلك ما جاء به الرسول + +74 +00:09:06,800 --> 00:09:14,740 +صلى الله عليه وسلم من السماحة و اليسر إن هذا الدين + +75 +00:09:14,740 --> 00:09:21,330 +يسرولي شد الدين أحد إلا غلبه فلما سمع بيهم النبي + +76 +00:09:21,330 --> 00:09:27,990 +صلى الله عليه وسلم دعاهم وقال لهم أنتم النفر الذين + +77 +00:09:27,990 --> 00:09:32,490 +قلتم كذا وكذا قالوا نعم يا رسول الله وما أردنا إلا + +78 +00:09:32,490 --> 00:09:40,570 +خيرا وهذا هو الجهل أنهم يحيدون عن الإسلام بحب + +79 +00:09:40,570 --> 00:09:41,230 +الإسلام + +80 +00:09:43,760 --> 00:09:48,720 +فعلمهم النبي عليه الصلاة والسلام حقيقة هذا الدين + +81 +00:09:48,720 --> 00:09:55,180 +وأن ما جاءوا به ليس من الدين قال لهم والله إني + +82 +00:09:55,180 --> 00:10:03,530 +لأخشاكم لله وأتقاكم لهولكني أصوم و أفطر و أصلي و + +83 +00:10:03,530 --> 00:10:11,130 +أرقد و أتزوج النساء فما الرغب عن سنتي فليس مني صلى + +84 +00:10:11,130 --> 00:10:18,550 +الله عليه و سلم صلى الله عليه و سلم نعم هذه هي + +85 +00:10:18,550 --> 00:10:23,910 +الحكمة الأولى من حكم مشروعية الزواج الاستجابة + +86 +00:10:23,910 --> 00:10:26,350 +لنداء الفطرة + +87 +00:10:27,730 --> 00:10:38,510 +ثانيا إيجاد الراحة النفسية فالزواج فعلا راحة نفسية + +88 +00:10:38,510 --> 00:10:47,550 +لكلا الزوجين حتى و لو كنت في الجنة أليس آدم في + +89 +00:10:47,550 --> 00:10:53,090 +الجنة و قد قال عليه الصلاة والسلام فيها ما لا عين + +90 +00:10:53,090 --> 00:11:02,140 +رأتولا أذن سمعت ولا خطرة علي قلب البشر ومع ذلك خلق + +91 +00:11:02,140 --> 00:11:11,760 +الله لآدم حواء حتى يسكن إليها فالزوجة فعلا وبكل ما + +92 +00:11:11,760 --> 00:11:21,280 +تحمل الكلمة من معنى سكن للزوج ولذا الرجل يحتاج إلى + +93 +00:11:21,280 --> 00:11:28,380 +المرأتهوالمرأة تحتاج إلى الرجل ولذا فطر الله + +94 +00:11:28,380 --> 00:11:34,660 +المرأة على حب الرجل وفطر الله الرجل على حب المرأة + +95 +00:11:34,660 --> 00:11:44,540 +بل هي من جنس الرجل ومن آياته أن خلق لكم من أنفسكم + +96 +00:11:44,540 --> 00:11:53,960 +يعني من جنسكم وليست غريبة عليكمومن آياته أن خلق + +97 +00:11:53,960 --> 00:12:01,220 +لكم من أنفسكم أزواجا لتسكنوا إليها وجعل بينكم مودة + +98 +00:12:01,220 --> 00:12:05,940 +ورحمة كما نرى أن هذه الآية تكررت معنا في أكثر من + +99 +00:12:05,940 --> 00:12:12,600 +موضع عندما تكلمنا عن أسس الأسرة المسلمة تكلمنا عن + +100 +00:12:12,600 --> 00:12:17,780 +المودة و الرحمة واستشهدنا بهذه الآية من صورة الروم + +101 +00:12:18,600 --> 00:12:23,080 +وعندما تكلمنا عن مشروعية الزواج من القرآن الكريم + +102 +00:12:23,080 --> 00:12:28,540 +استشهدنا بهذه الآية وها نحن أولاء نأتي اليها طارة + +103 +00:12:28,540 --> 00:12:37,730 +أخرى عند الحديث عن حكم الزواج نعموهو إيجاد الراحة + +104 +00:12:37,730 --> 00:12:44,030 +النفسية لقوله تعالى في الآية الكريمة لتسكنوا إليها + +105 +00:12:44,030 --> 00:12:51,110 +وثنأتي إليها أيضا عند الحديث أن التعارف أيضا بين + +106 +00:12:51,110 --> 00:13:00,750 +الناس يكون أيضا من حكم الزواج ثالثا حفظ النوع + +107 +00:13:00,750 --> 00:13:09,400 +الإنسانيمن الزوال والانقراض وهذا ابناء الطلاب لا + +108 +00:13:09,400 --> 00:13:16,620 +يكونوا الا بالزواجفالزواج كما قلنا سبيل إلى الولد + +109 +00:13:16,620 --> 00:13:25,540 +وسبيل إلى الذرية الصالحة فالولد شافع ونافع نافع في + +110 +00:13:25,540 --> 00:13:31,520 +الدنيا وشافع في الآخرته كما مر معناه في الحديث + +111 +00:13:31,520 --> 00:13:36,140 +الصحيح إذا مات الإنسان إنقطع عمله إلا من ثلاث + +112 +00:13:36,140 --> 00:13:43,390 +وذاكر النبي ولد صالح يدعو لهوقد قال الله تبارك + +113 +00:13:43,390 --> 00:13:48,310 +وتعالى في القرآن الكريم والله جعل لكم من أنفسكم + +114 +00:13:48,310 --> 00:13:55,870 +أزواجا وجعل لكم من أزواجكم بنين وحفدة ورزقكم من + +115 +00:13:55,870 --> 00:14:02,370 +الطيبات ومن السنة النبوية للدلالة على مشروعية طلب + +116 +00:14:02,370 --> 00:14:09,000 +الولد ففي الحديث عن معقل بن يصاررضي الله عنه قال + +117 +00:14:09,000 --> 00:14:13,940 +جاء رجل إلى رسول الله صلى الله عليه وسلم فقال يا + +118 +00:14:13,940 --> 00:14:21,500 +رسول الله إني أصبت امرأة ذات حسب ومنصب ومال إلا + +119 +00:14:21,500 --> 00:14:27,950 +أنها لا تلدأفأتزوج بها فنهاه الرسول صلى الله عليه + +120 +00:14:27,950 --> 00:14:34,250 +وسلم ثم أتاه في الثانية و قال له مثل ذلك فنهاه ثم + +121 +00:14:34,250 --> 00:14:38,510 +أتاه الثالثة فقال له مثل ذلك ثم قال صلى الله عليه + +122 +00:14:38,510 --> 00:14:45,340 +وسلم وهذا هو الشاهد في الحديثوعند السؤال يكتفى + +123 +00:14:45,340 --> 00:14:51,560 +بهذا الشاهد قال عليه الصلاة والسلام تزوجوا الولود + +124 +00:14:51,560 --> 00:14:59,980 +الودود فإني مكاثر بكم أو في رواية فإني مباهن بكم + +125 +00:14:59,980 --> 00:15:08,910 +يعني الأمم يوم القيامة فقوله تبارك وتعالىو جعل لكم + +126 +00:15:08,910 --> 00:15:13,690 +من أزوادكم بنين و حفدة دليل من القرآن على مشروعية + +127 +00:15:13,690 --> 00:15:20,850 +طلب الولد و الذرية الصالحة و ليس بدعا فقد طلب ذلك + +128 +00:15:20,850 --> 00:15:26,470 +الأنبياء من قبلناومن الصنة خوله صلى الله عليه وسلم + +129 +00:15:26,470 --> 00:15:33,910 +تزوجوا الولود الودودة فإني مكاثر بكم أو مباهن بكم + +130 +00:15:33,910 --> 00:15:41,130 +رابعا من حكم مشروعية الزواج تهذيب النفس وإعفاف + +131 +00:15:41,130 --> 00:15:46,950 +المرء نفسه وزوجه من الوقوع في الحرام ونحن تكلمنا + +132 +00:15:46,950 --> 00:15:50,310 +في البند الأول من حكم الزواج عن + +133 +00:15:52,710 --> 00:15:58,610 +الاستجابة لنداء الفطرة إذا كان بنية الأفة فهو أجر + +134 +00:15:58,610 --> 00:16:03,970 +وهو صدقة يتقرب بها إلى الله تبارك وتعالى وقد برّ + +135 +00:16:03,970 --> 00:16:10,330 +بنا في مشروعية الزواج من الصنة النبوية قوله خطابا + +136 +00:16:10,330 --> 00:16:15,390 +للشباب صلى الله عليه وسلم يا معشر الشباب من استطاع + +137 +00:16:15,390 --> 00:16:22,760 +منكم الباءة فليتزوجواوالباقة هنا لا تقتصر على + +138 +00:16:22,760 --> 00:16:34,300 +الباقة المادية من المال فقط وإنما تشمل أيضًا صحة + +139 +00:16:34,300 --> 00:16:42,480 +البدن وتشمل أيضًا الصحة النفسية فالباقة هنا تشمل + +140 +00:16:42,480 --> 00:16:54,430 +المال وتشمل البدنوتشمل الراحة النفسية أن يكون + +141 +00:16:54,430 --> 00:17:01,770 +سليما معافا من الأمراض البدنية ومن الأمراض النفسية + +142 +00:17:01,770 --> 00:17:06,410 +أقول هذا الكلام لأن البعض يفهم الباقة هنا بالمهر + +143 +00:17:06,930 --> 00:17:15,430 +وما أيصر المغر وما بعده أشد وأختر يا معشر الشباب + +144 +00:17:15,430 --> 00:17:25,170 +من استطاع منكم البائة فليتزوج فإنه أي الزواج أغض + +145 +00:17:25,170 --> 00:17:31,890 +للبصر وأحصن للفرج ومن لم يستطع فعليه بالصوم فإنه + +146 +00:17:31,890 --> 00:17:40,350 +له جاء أي وقايةووجأ بمعنى قطعة في لغة العرب فهو له + +147 +00:17:40,350 --> 00:17:49,450 +جائي قاطع للشهوة وليستعفف الذين لا يجدون نكاحا حتى + +148 +00:17:49,450 --> 00:17:53,650 +يغنيهم الله فضله ولا إفة تكون أولا بتقوى الله ثم + +149 +00:17:53,650 --> 00:18:03,250 +بالصوم ثم بالرياضة ونحو ذلك من الأمورخامسا من حكم + +150 +00:18:03,250 --> 00:18:10,090 +الزواج التعاون بين الزوجين وتحمل أعباء الحياة + +151 +00:18:10,090 --> 00:18:17,450 +الزوجية ومن ثم تقوية روابط الأسر على تربية الأولاد + +152 +00:18:17,450 --> 00:18:26,470 +تربية سليمة وبهيتم الاستعانة على المصالح أما سادسا + +153 +00:18:26,470 --> 00:18:33,450 +فالمحافظة على الروابط الاجتماعية وتقويتها فالزواج + +154 +00:18:33,450 --> 00:18:41,220 +وسيلة من وسائل ترابط المجتمع وتقويتهلقوله تبارك + +155 +00:18:41,220 --> 00:18:46,040 +وتعالى كما مرت بنا هذه الآية في أكثر من موضع وهي + +156 +00:18:46,040 --> 00:18:50,500 +في صورة الحجرات يا أيها الناس إن خلقناكم من ذكر + +157 +00:18:50,500 --> 00:18:56,360 +وأنثى وجعلناكم شعوبا وقبائلا لتعارفوا إن أكرمكم + +158 +00:18:56,360 --> 00:19:01,700 +عند الله أتقاكم إن الله عليم خبير صدق الله العظيم + +159 +00:19:01,700 --> 00:19:10,840 +هذه إذن هي حكم الزواجنأتي إلى حكم الزواج إذا حكم + +160 +00:19:10,840 --> 00:19:21,940 +بكسر الحاء بكسر الحاء وفتح الكاف حكم الزواج نعم + +161 +00:19:21,940 --> 00:19:28,380 +جمع حكمة أما حكم الزواج بضم الحائق وإسكان الكاف + +162 +00:19:28,380 --> 00:19:37,140 +والجمع أخكم وهنا يعترز زواجةالأحكام التكليفية + +163 +00:19:37,140 --> 00:19:43,460 +التالية حيث يختلف حكمه اتبعا لحال الشخص الذي يريد + +164 +00:19:43,460 --> 00:19:53,480 +الزواج فالزواج قد يكون فرضا وقد يكون حراما وقد + +165 +00:19:53,480 --> 00:20:00,600 +يكون مكروها وقد يكون صنة مؤكدة في حال اعتدال + +166 +00:20:00,600 --> 00:20:04,220 +الشهوة وهذا ما عليه الجماهير + +167 +00:20:06,570 --> 00:20:14,430 +والأكثرون من أهل الألم متى يكون الزواج فرضا إذا ما + +168 +00:20:14,430 --> 00:20:21,190 +توفر شرطا الشرط الأول إذا تيقن الشخص من وقوعه في + +169 +00:20:21,190 --> 00:20:30,610 +الفاحشة أي الزنا إذا لم يتزوج وهنا لابد أن نضع خطة + +170 +00:20:30,610 --> 00:20:37,970 +أو نخف قليلا عند قولنا إذا تيقنلأن اليقين هو العلم + +171 +00:20:37,970 --> 00:20:44,990 +مائة بالمائة ومن باب الفائدة ومن باب العلم بالشيء + +172 +00:20:44,990 --> 00:20:52,990 +ولا الجهل به أقول بأن العلم يمر بمراتب أربعة + +173 +00:20:52,990 --> 00:20:59,270 +المرتبة الأولى وهي مرتبة الشك وهي تساوي الطرفين + +174 +00:20:59,270 --> 00:21:06,010 +خمسونة في المائة نعم وخمسونة في المائة لاالمرحلة + +175 +00:21:06,010 --> 00:21:13,290 +الثانية وهي الأعلى رتبة من الشك وهي الظن فالظن قد + +176 +00:21:13,290 --> 00:21:18,750 +يصل إلى ستين أو خمسة وستين في المائة نعم والباقي + +177 +00:21:18,750 --> 00:21:27,910 +لا والمرحلة الثالثة هي غلبة الظن قد تصل إلى سبعين + +178 +00:21:27,910 --> 00:21:34,430 +أو خمسة وسبعين أو حتى ثمانين في المائة نعم والباقي + +179 +00:21:34,430 --> 00:21:41,570 +لاوأما المرحلة الرابعة والأخيرة ألا وهي مرحلة + +180 +00:21:41,570 --> 00:21:50,370 +اليقين واليقين هو الوصول بالعلم إلى مئة بالمئة إذا + +181 +00:21:50,370 --> 00:22:00,010 +مراتب العلم أربعة الشك والظن وغلبة الظن واليقين + +182 +00:22:02,690 --> 00:22:08,750 +متى يكون الزواج فرضًا إذا تيقن الشخص من الوقوع في + +183 +00:22:08,750 --> 00:22:16,290 +الزنا إن لم يتزوجوكذلك الشرط الثاني أن يكون قادرا + +184 +00:22:16,290 --> 00:22:23,010 +على القيام بأعباء الزواج ومسؤوليته من المهر و + +185 +00:22:23,010 --> 00:22:33,330 +النفقته وما يترتب على ذلك من حقوق وواجبات نعم + +186 +00:22:36,980 --> 00:22:42,640 +ثانيا و يكون الزواج حراما متى يكون الزواج حراما + +187 +00:22:42,640 --> 00:22:49,200 +أيضا أقول إذا تيقن الشخص و قلت ضعوا خطا تحت قولنا + +188 +00:22:49,200 --> 00:22:57,220 +إذا تيقن الشخص بمعنى إذا وصل إلى درجة اليقين 100% + +189 +00:22:57,220 --> 00:23:06,320 +أنه إذا تزوج لا محالة 100% سيظلم الزوجة بعدم العدل + +190 +00:23:07,480 --> 00:23:16,680 +وكذلك بعدم القيام بواجباته ومسؤولياته تجاه الزوجة + +191 +00:23:16,680 --> 00:23:23,620 +وهي الحقوق والواجبات الناشئة عن عقد الزواج + +192 +00:23:23,620 --> 00:23:32,600 +كالانفاق عليها لأن الظلم حرام وإذا كان الزواج + +193 +00:23:32,600 --> 00:23:41,090 +سيؤدي إلى الظلمفما أدى إلى الحرام فهو حرام إذا متى + +194 +00:23:41,090 --> 00:23:47,210 +يكون الزواج فرضًا؟ إذا توافر شرطان إذا تيقن الزوج + +195 +00:23:47,210 --> 00:23:56,360 +أنه بعدم الزواج سيقع في الفاحشةوهو في نفس الوقت + +196 +00:23:56,360 --> 00:24:03,100 +قادر على القيام بالأعباء الزوجية من المهر والنفقة + +197 +00:24:03,100 --> 00:24:09,160 +ونحو ذلك من الحقوق والواجبات ومتى يكون الزواج + +198 +00:24:09,160 --> 00:24:17,780 +حراما إذا تيقن أيضا أنه بزواجه سيظلم الزوجة بعدم + +199 +00:24:17,780 --> 00:24:20,320 +العدل نعم + +200 +00:24:21,580 --> 00:24:31,040 +و كذلك هو غير قادر على القيام بمسئوليات الزواج من + +201 +00:24:31,040 --> 00:24:37,480 +الإدفاق عليها و النفقة ستأتي من حقوق الزوجة من + +202 +00:24:37,480 --> 00:24:48,840 +المهر و النفقة و العدل و نحو ذلك من حقوق الزوجة في + +203 +00:24:48,840 --> 00:24:55,650 +الإسلامثالثا ومتى يكون حراما عفوا ومتى يكون مكروها + +204 +00:24:55,650 --> 00:25:02,210 +إذا انتفى اليقين من الحالة السابقة هو لم يتيقن من + +205 +00:25:02,210 --> 00:25:09,970 +ظلم الزوجته ولكنه يخشى الوقوع في ظلم الزوجته إذا + +206 +00:25:09,970 --> 00:25:18,690 +انضعوا خطاتحت قوله و لكنه يخشى الوقوع في الظلم إن + +207 +00:25:18,690 --> 00:25:24,970 +تزوجه إذا يكون الزواج حراما إذا تيقن الزوج من + +208 +00:25:24,970 --> 00:25:33,570 +الوقوع في الظلم و يكون مكروها إذا انتفى اليقين من + +209 +00:25:33,570 --> 00:25:41,920 +الحالة السابقةولكنه يخشى الوقوع في الظلم في حال + +210 +00:25:41,920 --> 00:25:48,900 +الزواج وما أدى إلى المكروه فهو مكروه والمكروه كما + +211 +00:25:48,900 --> 00:25:55,500 +نعلم هو دون الحرام أما الحالة الرابعة وهي كون + +212 +00:25:55,500 --> 00:26:05,280 +الشخص معتد للشهوة وهو ما عليهمعظم الناس والأكثرون + +213 +00:26:05,280 --> 00:26:16,540 +من الناس ففي هذه الحال حكم الزواج صنة مؤكدة بحيث + +214 +00:26:16,540 --> 00:26:23,260 +يقوى على ضبط نفسه ولا يخاف ارتكاب المعصية ولا + +215 +00:26:23,260 --> 00:26:29,480 +يخشظظلم زوجته وهو في نفس الوقت قادر على القيام + +216 +00:26:29,480 --> 00:26:36,590 +بأعباء الزواجومسؤوليته ففي هذه الحال كما أسلفنا + +217 +00:26:36,590 --> 00:26:44,830 +يكون الزواج صنة مؤكدة وما عليه الجماهير من الفقهاء + +218 +00:26:44,830 --> 00:26:51,270 +ويستدل على ذلك بإحاديث منها قوله صلى الله عليه + +219 +00:26:51,270 --> 00:26:57,990 +وسلم من أحب فطرتي فليستن بصنتي وإن من صنتي اندكاه + +220 +00:26:58,530 --> 00:27:04,270 +هذا دليل على ثنية النكاح في حال اعتدال الشهوة + +221 +00:27:04,270 --> 00:27:14,350 +وقوله صلى الله عليه وسلم ثلاثة حق على الله عونهم + +222 +00:27:14,350 --> 00:27:21,470 +المجاهد في سبيل الله والمكاتب الذي يريد الأداء + +223 +00:27:22,120 --> 00:27:30,980 +والناكح الذي يريد العفاف صلى الله عليه وسلم ويمكن + +224 +00:27:30,980 --> 00:27:39,320 +الاستشهاد ايضا باحديث اخرى خد مرت بنافي مشروعية + +225 +00:27:39,320 --> 00:27:44,820 +الزواج وغيره مثل قوله صلى الله عليه وسلم يا معشر + +226 +00:27:44,820 --> 00:27:51,520 +الشباب من استطاع منكم الباءة فليتزوج فإنه أي + +227 +00:27:51,520 --> 00:27:59,060 +الزواج أغض للبصر وأحصن للفرج ومن لم يستطع فعليه + +228 +00:27:59,060 --> 00:28:06,080 +بالصوم فإنه له جاء صلى الله عليه و سلم فهذه + +229 +00:28:06,080 --> 00:28:12,830 +الأحاديث الثلاثةوغيرها كثير كلها تدل على صنية + +230 +00:28:12,830 --> 00:28:22,150 +الزواد وأنه صنة مؤكدة في حال اعتدال الشهوة نعم + +231 +00:28:22,150 --> 00:28:31,370 +خامسا من مباحث المبحث الثالث وهو الزواد الحقوق + +232 +00:28:31,370 --> 00:28:40,230 +الزوجيةوالحقوق الزوجية تنقسم إلى أقسام ثلاثة القسم + +233 +00:28:40,230 --> 00:28:49,910 +الأول حقوق خاصة بالزوج على زوجته والقسم الثاني + +234 +00:28:49,910 --> 00:28:57,910 +حقوق خاصة بالزوجة على زوجهاوالقسم الثالث حقوق + +235 +00:28:57,910 --> 00:29:05,070 +مشتركة نبدأ بالقسم الأول وهو حقوق الزوج على الزوجة + +236 +00:29:05,070 --> 00:29:15,410 +بدءا بالطاعته فإن طاعة الزوجة واجبة فإن طاعة الزوج + +237 +00:29:15,410 --> 00:29:25,190 +واجبة على زوجته نعم ولكن الطاعة هناونخف قليلا عند + +238 +00:29:25,190 --> 00:29:33,850 +هذه الكلمة ليست مطلقة أقول ليست مطلقة فإن طاعة + +239 +00:29:33,850 --> 00:29:41,670 +الزوج واجبة في طاعة الله فإذا ما أمر الزوج بمعصية + +240 +00:29:41,670 --> 00:29:48,850 +الله كأن لا تصلي مثلا أو أن تفتر في شهر رمضان أو + +241 +00:29:48,850 --> 00:29:54,620 +أن تخرج سافرة متبرجةأو أن تخالط الرجال الأجانب + +242 +00:29:54,620 --> 00:30:01,820 +فمعصية الزوج في هذه الحال واجبة لأنه لا طاعة + +243 +00:30:01,820 --> 00:30:08,260 +لمخلوق في معصية الخالق إذا طاعة الزوج ليست مطلقة + +244 +00:30:08,260 --> 00:30:14,600 +في كل ما يأمر به الزوج وإنما طاعته واجبة في حدود + +245 +00:30:14,600 --> 00:30:23,010 +الشرعية فإذا أمر بمعصية الله فلا طاعة لهالبتة + +246 +00:30:23,010 --> 00:30:33,450 +والطاعة هنا أيضًا ليست استبدادًا أو تسلطًا أو كهرا + +247 +00:30:33,450 --> 00:30:45,750 +وظلمًا للزوجته وإنما هي الرحمة والمودة والمشورة + +248 +00:30:45,750 --> 00:30:53,920 +أيضًابل كما قال ابن عباسن هي أيضا الإيثار بمعنى أن + +249 +00:30:53,920 --> 00:31:02,020 +يؤثر الزوج و أهله على نفسه قد يجوع الزوج من أجل + +250 +00:31:02,020 --> 00:31:12,100 +شبع الزوجة و الولد و قد لا ينام يبقى طيلة الليل + +251 +00:31:12,100 --> 00:31:20,560 +مستيخظا من أجل راحة أهلهوقد يلبسوا العتيقة من + +252 +00:31:20,560 --> 00:31:27,660 +الثياب من أجل زوجه وولده وهذا معنى قوله تبارك + +253 +00:31:27,660 --> 00:31:33,260 +وتعالى الرجال قومون على النساء بما فضل الله بعضهم + +254 +00:31:33,260 --> 00:31:43,040 +على بعض وبما أنفقوا من أموالهم نعم هذه هي الدرجة + +255 +00:31:43,040 --> 00:31:53,570 +وللرجال عليهن درجةهي الطاعة أو القوامة إذا طاعة + +256 +00:31:53,570 --> 00:32:02,010 +الزوجة لزوجها أول حقوق الرجل على المرأة ثانيا + +257 +00:32:02,010 --> 00:32:09,760 +الأمانة والمقصود بالأمانة هنا أن الزوجة تكونمؤتمنة + +258 +00:32:09,760 --> 00:32:19,880 +على نفسها في غياب زوجها وفي حضوره فالزوجة + +259 +00:32:19,880 --> 00:32:28,660 +سر بينها وبين زوجها لا يطلع على سوء سوء زوجه + +260 +00:32:28,660 --> 00:32:35,670 +وأخذنا منكم مثاقا خليظا وقد أفضى بعضكم إلى بعضو + +261 +00:32:35,670 --> 00:32:42,710 +كذلك هي مؤتمنة على مال زوجها فليس لها إلا النفقة + +262 +00:32:42,710 --> 00:32:51,460 +فليس لها أن تتصدقحتى في سبيل الله من مال زوجها إلا + +263 +00:32:51,460 --> 00:32:57,260 +بإذن زوجها أما إن كان لها مال فلها أن تتبرع به كيف + +264 +00:32:57,260 --> 00:33:01,460 +شاءت لأنه كما سيأتي معنى عند الحديث عن ما كانت + +265 +00:33:01,460 --> 00:33:06,140 +المرأة في الإسلام أن المرأة لها ذمة مالية في + +266 +00:33:06,140 --> 00:33:12,000 +الإسلامنعم أما من مال زوجها فليس لها إلا النفقة من + +267 +00:33:12,000 --> 00:33:21,940 +السكن و من الطعام و من الكسوة نعم و كذلك هي مؤتمنة + +268 +00:33:21,940 --> 00:33:30,020 +على تربية ولاده و منذ الصغر تربيه على الأخلاق و + +269 +00:33:30,020 --> 00:33:39,370 +على الأداب الساميةالرفيعة بعيدا عن أهل السوء و + +270 +00:33:39,370 --> 00:33:47,390 +الفجور فتذهب به إلى المسجد من أجل الصلاة و من أجل + +271 +00:33:47,390 --> 00:33:54,570 +حفظ القرآن الكريم و خاصة يتمرن كما مر بنا في مراحل + +272 +00:33:54,570 --> 00:33:58,930 +توجيه الخلق في النفس البشرية بعد السابعة مروا + +273 +00:33:58,930 --> 00:34:03,150 +أولادكم بالصلاة لسبع سنينواضربوهم عليها إذا بلغوا + +274 +00:34:03,150 --> 00:34:11,470 +عشر سنين وفرقوا بينهم في المضاجع نعم والله تبارك + +275 +00:34:11,470 --> 00:34:17,830 +وتعالى يقول فالصالحات قانتات حافظات للغيب بما حفظ + +276 +00:34:17,830 --> 00:34:23,530 +الله وفي الحديث الشريف يقول صلى الله عليه وسلم + +277 +00:34:23,530 --> 00:34:32,330 +كلكم راعن وكلكم مسئول عن رعيته والأمير راعنوالرجل + +278 +00:34:32,330 --> 00:34:38,290 +راعٍ على أهل بيته والمرأة راعية على بيت زوجها + +279 +00:34:38,290 --> 00:34:45,450 +وولده فكلكم راعٍ وكلكم مسئول عن رعيته فعلى الزوجة + +280 +00:34:45,450 --> 00:34:51,370 +أن تحصن تربية أولادها وفق الدين والفضيلة وأن تصون + +281 +00:34:51,370 --> 00:34:59,240 +نفسها عما يدنص شرفها وشرف زوجها وأن تحافظهاعلى + +282 +00:34:59,240 --> 00:35:06,260 +ماله نعم هذه أخلاق المرأة الصالحة وصدق الرسول عليه + +283 +00:35:06,260 --> 00:35:10,860 +الصلاة والسلام الدنيا متاع وخير متاعها المرأة + +284 +00:35:10,860 --> 00:35:15,880 +الصالحة التي وصفها بقوله صلى الله عليه وسلم إن نظر + +285 +00:35:15,880 --> 00:35:22,030 +إليها صرته وإن أمرها أطاعتهموإن أقسم عليها أبرته + +286 +00:35:22,030 --> 00:35:29,130 +وإن غاب عنها حافظته في ماله وفي أرضها بأبي أنت + +287 +00:35:29,130 --> 00:35:34,390 +وامي يا رسول الله صلى الله عليه وسلم ثالثا حُسن + +288 +00:35:34,390 --> 00:35:42,480 +الإشرةأيضا من حق الزوج على زوجته فيجب على الزوجة + +289 +00:35:42,480 --> 00:35:51,560 +معاشرة زوجها بالمعروف و ذلك بكف الأذىوغيره فلا + +290 +00:35:51,560 --> 00:35:59,700 +تؤذيه ولا تشق عليه كما عليه معاشرتها بالمعروف + +291 +00:35:59,700 --> 00:36:07,800 +لقوله صلى الله عليه وسلم أي ممرأة ماتت وزوجها راض + +292 +00:36:07,800 --> 00:36:17,740 +عنها دخلت الجنة فالزوج فعلا هو جنتها ونارهاإذا + +293 +00:36:17,740 --> 00:36:25,240 +أطاعته فلها الجنة وإذا عصته فهي في النار وبئس + +294 +00:36:25,240 --> 00:36:30,140 +القرار والعياذ بالله احفظوا هذا الحديث أيوم امرأة + +295 +00:36:30,140 --> 00:36:36,080 +ماتت وزوجها راض عنها دخلت الجنة كيف أن طاعة الزوج + +296 +00:36:36,080 --> 00:36:46,440 +ورض الزوج والإحسان إلى الزوج باب من أبوابيالجنة ان + +297 +00:36:46,440 --> 00:36:53,040 +شاء الله ورابعا من حق الزوج على الزوجة أيضا + +298 +00:36:53,040 --> 00:37:04,980 +التأديب وهنا لنا وقفات أما أولا هل كل زوجة تؤدب؟ + +299 +00:37:04,980 --> 00:37:09,620 +ليس كل زوجة تؤدب افهموا هذا + +300 +00:37:12,410 --> 00:37:20,150 +نعم الزوجة التي تؤدب هي الزوجة العاصية الزوجة + +301 +00:37:20,150 --> 00:37:32,630 +الناشظة التي لا تطيع زوجها في شرع الله وكما أمر + +302 +00:37:32,630 --> 00:37:38,220 +اللهتبارك وتعالى كما قلنا الطاعة في الخير و الطاعة + +303 +00:37:38,220 --> 00:37:44,080 +في المعروف أما إذا عصت الزوجة زوجها في معصية الله + +304 +00:37:44,080 --> 00:37:50,920 +لأنه أمرها بما يخالف شرع الله فليست ناشزة ولا + +305 +00:37:50,920 --> 00:37:59,840 +تستحق التأدب إذا هذه واحدة ليس كل زوجة تؤدب إنما + +306 +00:37:59,840 --> 00:38:05,620 +الزوجة التي تؤدبهي الزوجة التي لا تطيع زوجها فيما + +307 +00:38:05,620 --> 00:38:12,140 +أمر ربها سبحانه وتعالى وهذا معنى قوله تبارك وتعالى + +308 +00:38:12,140 --> 00:38:19,380 +والله أعلى وأعلم والتي تخافون نشوزهن أي أسيانهن + +309 +00:38:19,380 --> 00:38:30,620 +وترفعهن عن طاعتكم معاشر الأزواج ثانيا تأديب الزوجة + +310 +00:38:31,470 --> 00:38:41,530 +يكونوا على مراحل ثلاثة مرتبة وهنا أراني أعوده إلى + +311 +00:38:41,530 --> 00:38:46,930 +الوراء قليلا عندما تكلمت عن مراحل توجيه الخلق في + +312 +00:38:46,930 --> 00:38:55,170 +النفس البشرية في فصلالأخلاق في الفصل الثالث وقلنا + +313 +00:38:55,170 --> 00:39:03,070 +هذه المراحل لابد أن تخفض مرتبة لأن كل مرحلة ترتبط + +314 +00:39:03,070 --> 00:39:14,150 +بما قبلها فقلت أولا التأثر بالخير أو الشر وثانيا + +315 +00:39:14,150 --> 00:39:22,330 +استقرار هذا الخلق إيجابا أو سلبا ورسوخهفي النفس + +316 +00:39:22,330 --> 00:39:28,810 +البشرية يترتب على ذلك إن عكاس هذا الخلق إيجابا أو + +317 +00:39:28,810 --> 00:39:35,810 +سلبا على تصرفات الشخص وسلوكيته والآن أراني مضطرا + +318 +00:39:35,810 --> 00:39:44,610 +إلى التذكير لأن هذا موضع أسئلة فالمراحل ثلاثة + +319 +00:39:44,610 --> 00:39:54,240 +المرحلة الأولى مرحلة الوعظبالكلمة الطيبة وأن يقوم + +320 +00:39:54,240 --> 00:39:59,480 +الزوج بتذكير الزوجة بمستقبلها + +321 +00:39:59,480 --> 00:40:07,700 +في حال الطلاق إذا لم تعد إلى الجادة وإلى الرشاد + +322 +00:40:07,700 --> 00:40:16,480 +وإلى الصواب وإلى طاعة الزوج نعم فإن لم ينفع الوعظة + +323 +00:40:17,680 --> 00:40:24,900 +فالهجران في المطجع وما المقصود بالمطجع هنا هو فراش + +324 +00:40:24,900 --> 00:40:33,940 +الزوجية بمعنى السرير الذي ينام عليه الزوجان فلا + +325 +00:40:33,940 --> 00:40:43,520 +يصح الهجران في مكان آخر بعيدا عن غرفة النوم بأن + +326 +00:40:43,520 --> 00:40:52,090 +يدير لها ظهرهولكن لا يعني الهجران أن لا يكلمها أو + +327 +00:40:52,090 --> 00:40:59,810 +أن لا يأكل طعامها يفعل كل شيء ما عدا الجماعة بأن + +328 +00:40:59,810 --> 00:41:09,650 +لا يجامعها لعلها تعود إلى رشدها وإلى صوابها هذا هو + +329 +00:41:09,650 --> 00:41:16,550 +معنى الهجران في المجتمع فإن لم يلفع يرحلوا + +330 +00:41:17,550 --> 00:41:26,270 +الى المرتبة الثالثة و هي الدرب و أي درب ليس الدرب + +331 +00:41:26,270 --> 00:41:32,870 +مطلقا ايضا و انما كما فسره ابن عباسل رضي الله + +332 +00:41:32,870 --> 00:41:40,530 +عنهما الدرب غير المبرح كما قال الدرب بالسواك لأن + +333 +00:41:40,530 --> 00:41:48,170 +الدرب حقيقة لا يليق بالرجال الكملإنما هو من أخلاق + +334 +00:41:48,170 --> 00:41:55,330 +عامة الناس والرسول صلى الله عليه وسلم وقد نزلت + +335 +00:41:55,330 --> 00:42:04,690 +عليه هذه الآيات والتي تخافون نشوسهن أولا فعظوهن + +336 +00:42:04,690 --> 00:42:11,810 +فإن لم ينفع وهجروهن في المضاجع فإن لم ينفع + +337 +00:42:11,810 --> 00:42:17,130 +واضربوهنفَإِنْ أَطَعْنَكُمْ فَلَا تَبْغُوا + +338 +00:42:17,130 --> 00:42:20,330 +عَلَيْهِنَّ سَبِيلًا إِنَّ اللَّهَ كَانَ عَلِيًّا + +339 +00:42:20,330 --> 00:42:28,810 +كَبِيرًا النبي ﷺ الذي نزل عليه هذه الأيات لم يضرب + +340 +00:42:28,810 --> 00:42:36,310 +امرأة قط إنما ضرب بيده في سبيل الله إذا انتهكت + +341 +00:42:36,310 --> 00:42:40,550 +حرمات الله ولذلك + +342 +00:42:40,550 --> 00:42:52,280 +لا يكرمهن إلا كريمولا يسيئ إليهن إلا لئيم والعياذ + +343 +00:42:52,280 --> 00:42:56,420 +بالله بل قال عليه الصلاة والسلام رفقا بالقوارير + +344 +00:42:56,420 --> 00:43:03,980 +والقوارير جمع قارورة وهي الزجاجة التي سرعان ما + +345 +00:43:03,980 --> 00:43:12,600 +تكسر ولذلك فسر العلماء الضرب غير المبرح أولا بأنه + +346 +00:43:13,380 --> 00:43:22,840 +الذي لا يكسر عظما ولا يخدش جلدا ولا يترك أثرا أو + +347 +00:43:22,840 --> 00:43:33,380 +علامة تشوه بدنها ولا يقبح بمعنى لا يصب ولا يشتم + +348 +00:43:33,380 --> 00:43:45,000 +كما نرى من بعض الناس الجهلاء والعياذ باللهوأن يتقى + +349 +00:43:45,000 --> 00:43:54,220 +الوجه وهذا أهم شيء في الضرب أن يتقى الوجه لماذا + +350 +00:43:54,220 --> 00:44:01,560 +يتقى الوجه فلا يمثل وجه ولا يقترب منه لأن وجه + +351 +00:44:01,560 --> 00:44:08,240 +المرأة هو جماع محاسنها ولذلك المرأة في الإسلام + +352 +00:44:08,240 --> 00:44:17,260 +عندما تخطبتكشف عن وجهها وعندما خطب أحده المهاجرين + +353 +00:44:17,260 --> 00:44:21,360 +امرأة من الأنصار قال هل نظرت إليها قال لأ قال انظر + +354 +00:44:21,360 --> 00:44:28,700 +إليها فإن في أعين الأنصار شيئا قيل ضيقا في الأعين + +355 +00:44:28,700 --> 00:44:32,220 +فإنه + +356 +00:44:32,220 --> 00:44:38,100 +كما في الحديث أحرى أن يُدم بينكما بمعنى أن يكون + +357 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يضربون نساءهم فشلت يميني + +369 +00:46:08,120 --> 00:46:14,200 +يوم أضرب زينبا وكأني بهذه الكلمات أرد على أعداء + +370 +00:46:14,200 --> 00:46:19,660 +الإسلام الذين قالوا بأن الإسلام يضرب المرأة نقول + +371 +00:46:19,660 --> 00:46:26,170 +لاالضرب غير المبرح كالسواك يعني كقلم الرصاص + +372 +00:46:26,170 --> 00:46:34,870 +بالوسادة نعم هكذا ضربوا دلع وليس ضربوا تكثير نعم + +373 +00:46:34,870 --> 00:46:43,630 +هذا ما أردته قوله خامسا وأخيرا في حق الزوجونكتفي + +374 +00:46:43,630 --> 00:46:50,710 +هنا الحداد على الزوج وهذا من باب الوفاء للزوج إذا + +375 +00:46:50,710 --> 00:46:57,720 +مات الزوجيجب على الزوجة الحداد بأن تظهر الحزن + +376 +00:46:57,720 --> 00:47:05,020 +والأسى على فراقه أربعة أشهر وعشرة مائة وثلاثون + +377 +00:47:05,020 --> 00:47:12,240 +يوما اعترافا بالفضل والجميل وذلك بتجنب الطيب + +378 +00:47:12,240 --> 00:47:20,110 +والزينا وأن تلزم بيت الزوجيتهفلا تبارحه إلا + +379 +00:47:20,110 --> 00:47:26,570 +للضرورة كعلاج أو سوق لشراء طعام أو شراب لأولادها + +380 +00:47:26,570 --> 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{"start": 674.78, "end": 676.52, "word": " للزوج", "probability": 0.8779296875}, {"start": 676.52, "end": 677.94, "word": " ولذا", "probability": 0.5946044921875}, {"start": 677.94, "end": 679.56, "word": " الرجل", "probability": 0.9444986979166666}, {"start": 679.56, "end": 681.08, "word": " يحتاج", "probability": 0.99560546875}, {"start": 681.08, "end": 681.28, "word": " إلى", "probability": 0.943359375}, {"start": 681.28, "end": 681.86, "word": " المرأته", "probability": 0.8009033203125}], "temperature": 1.0}, {"id": 28, "seek": 71034, "start": 682.96, "end": 710.34, "text": "والمرأة تحتاج إلى الرجل ولذا فطر الله المرأة على حب الرجل وفطر الله الرجل على حب المرأة بل هي من جنس الرجل ومن آياته أن خلق لكم من أنفسكم يعني من جنسكم وليست غريبة عليكم", "tokens": [2407, 45340, 2288, 10721, 3660, 6055, 33753, 26108, 30731, 34892, 7435, 1211, 35525, 15730, 6156, 9566, 2288, 21984, 9673, 2288, 10721, 3660, 15844, 11331, 3555, 34892, 7435, 1211, 4032, 5172, 9566, 2288, 21984, 34892, 7435, 1211, 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أنها لا تلد", "tokens": [43042, 1829, 21984, 18871, 3224, 50239, 10874, 16606, 12602, 7435, 1211, 30731, 12602, 3794, 12610, 21984, 20328, 23942, 21984, 47356, 46952, 19528, 6156, 4587, 6027, 35186, 12602, 3794, 12610, 21984, 11933, 22653, 5551, 9381, 3555, 2655, 1975, 29973, 10721, 3660, 29910, 9307, 11331, 35457, 4032, 27842, 9381, 3555, 4032, 2304, 6027, 11933, 15040, 14739, 11296, 20193, 6055, 1211, 3215], "avg_logprob": -0.07363280976812045, "compression_ratio": 1.6766917293233083, "no_speech_prob": 2.5033950805664062e-05, "words": [{"start": 847.24, "end": 847.68, "word": "رضي", "probability": 0.6868896484375}, {"start": 847.68, "end": 847.84, "word": " الله", "probability": 0.97412109375}, {"start": 847.84, "end": 848.5, "word": " عنه", "probability": 0.99267578125}, {"start": 848.5, "end": 849.0, "word": " قال", "probability": 0.78515625}, {"start": 849.0, "end": 849.66, "word": " جاء", "probability": 0.97509765625}, {"start": 849.66, "end": 850.1, "word": " رجل", "probability": 0.9920247395833334}, {"start": 850.1, "end": 850.4, "word": " إلى", "probability": 0.8984375}, {"start": 850.4, "end": 850.96, "word": " رسول", "probability": 0.9939778645833334}, {"start": 850.96, "end": 851.46, "word": " الله", "probability": 0.95947265625}, {"start": 851.46, "end": 852.2, "word": " صلى", "probability": 0.901611328125}, {"start": 852.2, "end": 852.48, "word": " الله", "probability": 0.95849609375}, {"start": 852.48, "end": 852.82, "word": " عليه", "probability": 0.95849609375}, {"start": 852.82, "end": 853.32, "word": " وسلم", "probability": 0.9248046875}, {"start": 853.32, "end": 853.76, "word": " فقال", "probability": 0.97412109375}, {"start": 853.76, "end": 853.94, "word": " يا", "probability": 0.89990234375}, {"start": 853.94, "end": 854.36, "word": " رسول", "probability": 0.9938151041666666}, {"start": 854.36, "end": 854.74, "word": " الله", "probability": 0.91552734375}, {"start": 854.74, "end": 855.64, "word": " إني", "probability": 0.7374267578125}, {"start": 855.64, "end": 856.24, "word": " أصبت", "probability": 0.970458984375}, {"start": 856.24, "end": 857.02, "word": " امرأة", "probability": 0.957275390625}, {"start": 857.02, "end": 858.0, "word": " ذات", "probability": 0.991455078125}, {"start": 858.0, "end": 858.5, "word": " حسب", "probability": 0.9970703125}, {"start": 858.5, "end": 859.98, "word": " ومنصب", "probability": 0.886962890625}, {"start": 859.98, "end": 861.08, "word": " ومال", "probability": 0.9270833333333334}, {"start": 861.08, "end": 861.5, "word": " إلا", "probability": 0.915771484375}, {"start": 861.5, "end": 862.12, "word": " أنها", "probability": 0.978271484375}, {"start": 862.12, "end": 862.32, "word": " لا", "probability": 0.8818359375}, {"start": 862.32, "end": 862.8, "word": " تلد", "probability": 0.99462890625}], "temperature": 1.0}, {"id": 36, "seek": 88191, "start": 863.47, "end": 881.91, "text": "أفأتزوج بها فنهاه الرسول صلى الله عليه وسلم ثم أتاه في الثانية و قال له مثل ذلك فنهاه ثم أتاه الثالثة فقال له مثل ذلك ثم قال صلى الله عليه وسلم وهذا هو الشاهد في الحديث", "tokens": [10721, 5172, 10721, 2655, 11622, 29245, 4724, 11296, 6156, 1863, 3224, 40294, 34892, 3794, 12610, 20328, 23942, 21984, 47356, 46952, 19528, 38637, 2304, 5551, 2655, 40294, 8978, 6024, 104, 7649, 10632, 4032, 50239, 46740, 50113, 1211, 29910, 23275, 6156, 1863, 3224, 40294, 38637, 2304, 5551, 2655, 40294, 6024, 104, 6027, 12984, 3660, 6156, 4587, 6027, 46740, 50113, 1211, 29910, 23275, 38637, 2304, 50239, 20328, 23942, 21984, 47356, 46952, 19528, 37037, 15730, 31439, 25124, 40294, 3215, 8978, 21542, 16254, 12984], "avg_logprob": -0.08862304771319032, "compression_ratio": 2.0476190476190474, "no_speech_prob": 4.827976226806641e-06, "words": [{"start": 863.47, "end": 864.49, "word": "أفأتزوج", "probability": 0.921142578125}, {"start": 864.49, "end": 864.89, "word": " بها", "probability": 0.968505859375}, {"start": 864.89, "end": 865.95, "word": " فنهاه", "probability": 0.830322265625}, {"start": 865.95, "end": 866.53, "word": " الرسول", "probability": 0.9903971354166666}, {"start": 866.53, "end": 867.35, "word": " صلى", "probability": 0.958251953125}, {"start": 867.35, "end": 867.57, "word": " الله", "probability": 0.96826171875}, {"start": 867.57, "end": 867.95, "word": " عليه", "probability": 0.96533203125}, {"start": 867.95, "end": 868.57, "word": " وسلم", "probability": 0.879638671875}, {"start": 868.57, "end": 869.33, "word": " ثم", "probability": 0.975341796875}, {"start": 869.33, "end": 869.77, "word": " أتاه", "probability": 0.8590494791666666}, {"start": 869.77, "end": 869.93, "word": " في", "probability": 0.8603515625}, {"start": 869.93, "end": 870.55, "word": " الثانية", "probability": 0.93408203125}, {"start": 870.55, "end": 871.21, "word": " و", "probability": 0.9775390625}, {"start": 871.21, "end": 871.57, "word": " قال", "probability": 0.61376953125}, {"start": 871.57, "end": 871.87, "word": " له", "probability": 0.70751953125}, {"start": 871.87, "end": 872.29, "word": " مثل", "probability": 0.965087890625}, {"start": 872.29, "end": 872.69, "word": " ذلك", "probability": 0.989013671875}, {"start": 872.69, "end": 873.25, "word": " فنهاه", "probability": 0.9334716796875}, {"start": 873.25, "end": 874.25, "word": " ثم", "probability": 0.7127685546875}, {"start": 874.25, "end": 874.79, "word": " أتاه", "probability": 0.9366861979166666}, {"start": 874.79, "end": 875.53, "word": " الثالثة", "probability": 0.8875}, {"start": 875.53, "end": 875.95, "word": " فقال", "probability": 0.9861653645833334}, {"start": 875.95, "end": 876.15, "word": " له", "probability": 0.783203125}, {"start": 876.15, "end": 876.37, "word": " مثل", "probability": 0.984375}, {"start": 876.37, "end": 876.69, "word": " ذلك", "probability": 0.984130859375}, {"start": 876.69, "end": 877.35, "word": " ثم", "probability": 0.981201171875}, {"start": 877.35, "end": 877.69, "word": " قال", "probability": 0.98828125}, {"start": 877.69, "end": 878.03, "word": " صلى", "probability": 0.974609375}, {"start": 878.03, "end": 878.25, "word": " الله", "probability": 0.962890625}, {"start": 878.25, "end": 878.51, "word": " عليه", "probability": 0.939453125}, {"start": 878.51, "end": 878.83, "word": " وسلم", "probability": 0.95458984375}, {"start": 878.83, "end": 880.07, "word": " وهذا", "probability": 0.807861328125}, {"start": 880.07, "end": 880.59, "word": " هو", "probability": 0.9912109375}, {"start": 880.59, "end": 881.31, "word": " الشاهد", "probability": 0.97705078125}, {"start": 881.31, "end": 881.45, "word": " في", "probability": 0.9716796875}, {"start": 881.45, "end": 881.91, "word": " الحديث", "probability": 0.9944661458333334}], "temperature": 1.0}, {"id": 37, "seek": 90610, "start": 883.22, "end": 906.1, "text": "وعند السؤال يكتفى بهذا الشاهد قال عليه الصلاة والسلام تزوجوا الولود الودود فإني مكاثر بكم أو في رواية فإني مباهن بكم يعني الأمم يوم القيامة فقوله تبارك وتعالى", "tokens": [45367, 41260, 21136, 33604, 6027, 7251, 4117, 2655, 5172, 7578, 39627, 15730, 25124, 40294, 3215, 50239, 47356, 31767, 15040, 3660, 16070, 3794, 37440, 6055, 11622, 29245, 14407, 2423, 12610, 23328, 2423, 23328, 23328, 6156, 28814, 22653, 3714, 4117, 5718, 104, 2288, 4724, 24793, 34051, 8978, 12602, 14407, 10632, 6156, 28814, 22653, 3714, 3555, 40294, 1863, 4724, 24793, 37495, 22653, 16247, 2304, 2304, 7251, 20498, 25062, 1829, 10943, 3660, 6156, 39648, 3224, 6055, 3555, 9640, 4117, 34683, 3615, 6027, 7578], "avg_logprob": -0.07045898661017418, "compression_ratio": 1.7730061349693251, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 883.22, "end": 883.82, "word": "وعند", "probability": 0.763671875}, {"start": 883.82, "end": 884.4, "word": " السؤال", "probability": 0.98291015625}, {"start": 884.4, "end": 885.34, "word": " يكتفى", "probability": 0.9072265625}, {"start": 885.34, "end": 886.0, "word": " بهذا", "probability": 0.955322265625}, {"start": 886.0, "end": 887.24, "word": " الشاهد", "probability": 0.9762369791666666}, {"start": 887.24, "end": 887.92, "word": " قال", "probability": 0.9248046875}, {"start": 887.92, "end": 888.3, "word": " عليه", "probability": 0.8701171875}, {"start": 888.3, "end": 888.7, "word": " الصلاة", "probability": 0.9806315104166666}, {"start": 888.7, "end": 889.38, "word": " والسلام", "probability": 0.9537760416666666}, {"start": 889.38, "end": 890.86, "word": " تزوجوا", "probability": 0.916015625}, {"start": 890.86, "end": 891.56, "word": " الولود", "probability": 0.9775390625}, {"start": 891.56, "end": 892.34, "word": " الودود", "probability": 0.9640299479166666}, {"start": 892.34, "end": 893.26, "word": " فإني", "probability": 0.8761393229166666}, {"start": 893.26, "end": 894.1, "word": " مكاثر", "probability": 0.93544921875}, {"start": 894.1, "end": 895.46, "word": " بكم", "probability": 0.897216796875}, {"start": 895.46, "end": 896.3, "word": " أو", "probability": 0.70068359375}, {"start": 896.3, "end": 896.52, "word": " في", "probability": 0.9580078125}, {"start": 896.52, "end": 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أزوادكم بنين و حفدة دليل من القرآن على مشروعية طلب الولد و الذرية الصالحة و ليس بدعا فقد طلب ذلك الأنبياء من قبلنا", "tokens": [2407, 10874, 30241, 5296, 24793, 9154, 5551, 11622, 2407, 18513, 24793, 44945, 9957, 4032, 11331, 5172, 41891, 11778, 20292, 1211, 9154, 25062, 2288, 148, 48506, 15844, 37893, 32887, 3615, 10632, 23032, 46152, 2423, 12610, 3215, 4032, 32545, 2288, 10632, 31767, 6027, 5016, 3660, 4032, 32239, 3794, 47525, 3615, 995, 6156, 28543, 23032, 46152, 29910, 23275, 16247, 1863, 21292, 16606, 9154, 12174, 36150, 8315], "avg_logprob": -0.11267090134788305, "compression_ratio": 1.6056338028169015, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 907.77, "end": 908.03, "word": "و", "probability": 0.76806640625}, {"start": 908.03, "end": 908.47, "word": " جعل", "probability": 0.827880859375}, {"start": 908.47, "end": 908.91, "word": " لكم", "probability": 0.949951171875}, {"start": 908.91, "end": 909.13, "word": " من", "probability": 0.99267578125}, {"start": 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إلا للضرورة كعلاج أو سوق لشراء طعام أو شراب لأولادها أو كأن تذهب إلى مصلحة كالبنك أو البريد لأجل راتب أو نحو ذلك", "tokens": [5172, 15040, 6055, 3555, 9640, 5016, 3224, 11933, 15040, 24976, 11242, 2288, 13063, 3660, 9122, 30241, 26108, 34051, 8608, 30543, 5296, 46309, 16606, 23032, 3615, 10943, 34051, 13412, 2288, 16758, 5296, 10721, 12610, 18513, 11296, 34051, 9122, 33456, 6055, 24192, 3555, 30731, 3714, 36520, 5016, 3660, 9122, 6027, 3555, 1863, 4117, 34051, 29739, 16572, 3215, 5296, 10721, 7435, 1211, 12602, 9307, 3555, 34051, 8717, 5016, 2407, 29910, 23275], "avg_logprob": -0.07121829710144928, "compression_ratio": 1.5857142857142856, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2837.95, "end": 2838.37, "word": "فلا", "probability": 0.95263671875}, {"start": 2838.37, "end": 2839.29, "word": " تبارحه", "probability": 0.94892578125}, {"start": 2839.29, "end": 2840.11, "word": " إلا", "probability": 0.791748046875}, {"start": 2840.11, "end": 2841.01, "word": " 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الإسلامية تكلمنا في + +4 +00:00:20,530 --> 00:00:26,190 +المحاضرة السابقة عن المبحث الأول وهو بعنوان تعريف + +5 +00:00:26,190 --> 00:00:32,620 +النظم لغة واصطلاحا وتكلمنا عن المبحث الثاني وهو + +6 +00:00:32,620 --> 00:00:38,120 +بعنوان حاجة المجتمعات إلى النظم الإسلامية ونحن + +7 +00:00:38,120 --> 00:00:43,040 +اليوم على موعد إن شاء الله مع المبحث الثالث وهو من + +8 +00:00:43,040 --> 00:00:48,360 +أكبر مباحث الفصل التمهيدي الأربعة وهو بعنوان خصائص + +9 +00:00:48,360 --> 00:00:54,460 +النظم الإسلامية وهي ثمانية بدءًا بالربانية ومرورا + +10 +00:00:54,460 --> 00:00:59,920 +بالثبات والمرونة والشمول والتوازن والعموم و + +11 +00:00:59,920 --> 00:01:05,360 +العالمية والتكافل والرباط والواقعية والمثالية + +12 +00:01:05,360 --> 00:01:11,980 +والأخلاق وثامنا وأخيرًا الجزاء الأخروي الخاصية + +13 +00:01:11,980 --> 00:01:21,220 +الأولى وهي أهم الخصائص بل هي أم الخصائص وهي + +14 +00:01:21,220 --> 00:01:27,940 +الربانية والربانية مشتقة من الرب تبارك وتعالى + +15 +00:01:28,460 --> 00:01:34,300 +فيقال ربانيون يُنسبون إلى الرب تبارك وتعالى + +16 +00:01:34,300 --> 00:01:43,440 +والربانية هنا نوعان: ربانية المصدر وربانية الغاية + +17 +00:01:43,440 --> 00:01:51,600 +وهما مصطلحان لابد أن يُفرّق بينهما أما ربانية + +18 +00:01:51,600 --> 00:02:00,790 +المصدر فهو أن أصول أحكامها و أسس تشريعتها مأخوذة من + +19 +00:02:00,790 --> 00:02:05,650 +كتاب الله عز وجل ومن سنة رسول الله صلى الله عليه + +20 +00:02:05,650 --> 00:02:12,550 +وسلم وهذا ما سبق ذكره عند الحديث عن الفرق بين + +21 +00:02:12,550 --> 00:02:18,310 +النظم عند المسلمين وعند غير المسلمين فالنظم عند + +22 +00:02:18,310 --> 00:02:23,810 +المسلمين مصدرها الله تبارك وتعالى ويتمثل ذلك في + +23 +00:02:23,810 --> 00:02:30,240 +كتابه القرآن الكريم سبحانه وتعالى وكذلك في سنة نبيه + +24 +00:02:30,240 --> 00:02:35,120 +محمد صلى الله عليه وسلم عملًا بقوله تعالى: يا أيها + +25 +00:02:35,120 --> 00:02:39,820 +الذين آمنوا أطيعوا الله وأطيعوا الرسول أطيعوا الله + +26 +00:02:39,820 --> 00:02:46,140 +أي في كتابه وأطيعوا الرسول أي في سنته صلى الله عليه + +27 +00:02:46,140 --> 00:02:53,160 +وسلم أما القوانين الوضعية البشرية الأدمية فهي من + +28 +00:02:53,160 --> 00:02:58,300 +وضع الناس أو كما أسلفنا في تعريف النظم عند غير + +29 +00:02:58,300 --> 00:03:02,960 +المسلمين أنها من وضع الشعوب ومن وضع المجتمعات أو + +30 +00:03:02,960 --> 00:03:13,570 +من وضع البرلمان المنتخب من الشعب ومعنى كونه ربانية + +31 +00:03:13,570 --> 00:03:20,850 +الغاية أن هدف هذه النظم الأولى والأسمى هو ربط + +32 +00:03:20,850 --> 00:03:28,010 +الناس بربهم سبحانه وتعالى في كل تصرف وفي كل فعل + +33 +00:03:28,010 --> 00:03:34,750 +يصدر عنهم بل في كل فكرة أو في كل خاطرة تراودهم وأن + +34 +00:03:34,750 --> 00:03:41,010 +يكون كل ذلك من أجل الله وطمعًا في رضاه سبحانه + +35 +00:03:41,010 --> 00:03:50,450 +وتعالى نأتي الآن إلى جملة من النتائج والأثار التي + +36 +00:03:50,450 --> 00:03:58,410 +تنبثق عن خاصية الربانية فنقول ما هي النتائج + +37 +00:03:58,410 --> 00:04:09,440 +والثمار أو الآثار التي تنجم أو تنبثق عن خاصية + +38 +00:04:09,440 --> 00:04:15,240 +الربانية أول هذه النتائج والآثار خلو هذه النظم من + +39 +00:04:15,240 --> 00:04:21,860 +معاني النقص والجهل والهوى والظلم لماذا؟ لأن هذه + +40 +00:04:21,860 --> 00:04:29,570 +النظم هي من عند الله تعالى الله عن هذه النقائص فإن + +41 +00:04:29,570 --> 00:04:37,370 +النقص والجهل والهوى والظلم من صفات البشر من صفات + +42 +00:04:37,370 --> 00:04:42,990 +المخلوقين وليست من صفات الله تبارك وتعالى وصدق + +43 +00:04:42,990 --> 00:04:48,550 +الله ربنا العظيم ليس كمثله شيء وهو السميع العليم + +44 +00:04:48,550 --> 00:04:55,100 +سبحانه وتعالى ثانيًا من النتائج والآثار التي تنبثق + +45 +00:04:55,100 --> 00:05:01,700 +عن خاصية الربانية الثقة بهذه النظم والتسليم بصحة + +46 +00:05:01,700 --> 00:05:07,460 +ما جاء فيها وصلاحيتها ذلك لأنها أيضًا من عند الله + +47 +00:05:07,460 --> 00:05:14,840 +سبحانه وتعالى الذي خلق البشر الله الذي خلق البشر + +48 +00:05:14,840 --> 00:05:24,520 +يعلم ما يصلحهم وما ينفعهم في دنياهم وآخراتهم كما قال + +49 +00:05:24,520 --> 00:05:30,960 +الله تبارك وتعالى: فإما يأتينكم مني هدا فمن اتبع + +50 +00:05:30,960 --> 00:05:36,460 +هدايا فلا يضل ولا يشقى ومن أعرض عن ذكري فإن له + +51 +00:05:36,460 --> 00:05:42,800 +معيشة ضنك ونحشره يوم القيامة أعمى قال: رب لما + +52 +00:05:42,800 --> 00:05:47,340 +حشرتني أعمى وقد كنت بصيرًا قال: كذلك أتتك آياتنا + +53 +00:05:47,340 --> 00:05:55,420 +فنسيتها وكذلك اليوم تنسى فالجزاء من جنس العمل وكما + +54 +00:05:55,420 --> 00:06:04,280 +تدين تدان والنتائج وفق المقدمات من خير ومن شر فمن + +55 +00:06:04,280 --> 00:06:10,640 +يعمل مثقال ذرة خير يره ومن يعمل مثقال ذرة شر يره + +56 +00:06:10,640 --> 00:06:16,920 +ولذلك قالوا من قديم الزمان كل صانع أدرى بصناعته + +57 +00:06:16,920 --> 00:06:26,470 +فمن صنع جهازًا كتب معه ما يُطلَق عليه في هذه الأيام + +58 +00:06:26,470 --> 00:06:35,250 +بالـ Catalogue من أجل أن ينتفع به الخبير فإذا ما + +59 +00:06:35,250 --> 00:06:42,190 +خالف هذا الخبير تعليمات الصانع أو تعليمات ال + +60 +00:06:42,190 --> 00:06:49,950 +Catalogue فإن الآلة تبقى فاسدة ولا تصلح أبدًا ولله + +61 +00:06:49,950 --> 00:06:56,030 +المثل الأعلى فالإنسان صنعة الله تبارك وتعالى صنعة + +62 +00:06:56,030 --> 00:07:00,790 +الله ومن أحسن من الله صنعة صبغة الله ومن أحسن من + +63 +00:07:00,790 --> 00:07:06,810 +الله صبغة الإنسان بنيان الرب سبحانه وتعالى خلقه + +64 +00:07:06,810 --> 00:07:13,910 +الله وهو أدرى بما يصلحه وبما يفسده فأنزل له هذه + +65 +00:07:13,910 --> 00:07:21,430 +النظم أو تلك التشريعات من حلال ومن حرام من أجل + +66 +00:07:21,430 --> 00:07:28,190 +خيره في الدنيا والآخرة وذلك هو الفوز العظيم أما + +67 +00:07:28,190 --> 00:07:34,770 +ثالثًا من النتائج والآثار التي تنبثق عن خاصية + +68 +00:07:35,720 --> 00:07:41,960 +الربانية أنها تتمتع بقدر كبير من الهيبة والتقديس + +69 +00:07:41,960 --> 00:07:48,280 +والحب والاحترام في نفوس المؤمنين لأن الإيمان بالله + +70 +00:07:48,280 --> 00:07:55,580 +لا يكون بالقوة ولا يكون بالسلطان ولا يكونوا + +71 +00:07:55,580 --> 00:08:03,800 +بالإكراه إنما يكونوا بالحب وبالمودة + +72 +00:08:03,800 --> 00:08:09,520 +كما سلف شرحه في المحاضرة السابقة كما قال الله + +73 +00:08:09,520 --> 00:08:14,080 +تبارك وتعالى لا إكراه في الدين قد تبين الرشد من + +74 +00:08:14,080 --> 00:08:19,260 +الغيب أفأنت تكره الناس حتى يكونوا مؤمنين فإن + +75 +00:08:19,260 --> 00:08:27,300 +الإيمان إذا كان عن خشية من حاكم أو من سلطان سرعان + +76 +00:08:27,300 --> 00:08:33,880 +ما يرتد صاحبه أما الإيمان بالله والتسليم بأحكام + +77 +00:08:33,880 --> 00:08:41,240 +الله إذا كان عن حب وعن رضا وعن عقيدة فإنه يخالط + +78 +00:08:41,240 --> 00:08:52,120 +بشاشة القلوب فيثبت ويستقر نعم أما رابعًا وهذه من + +79 +00:08:52,120 --> 00:09:02,440 +الثمار المهمة الناجمة عن خاصية الربانية أنها تدفع + +80 +00:09:02,440 --> 00:09:08,760 +المؤمنين إلى المصارعة في التوبة باستشعار الندم عند + +81 +00:09:08,760 --> 00:09:16,960 +اختراق ما يخالف أحكامها فالإنسان ليس ملكًا يمشي على + +82 +00:09:16,960 --> 00:09:24,800 +الأرض والإنسان ليس نبيًا معصومًا من الخطأ والزلل، + +83 +00:09:24,800 --> 00:09:34,710 +الإنسان فيه من الملائكية وفيه من المعصية فبالطاعة + +84 +00:09:34,710 --> 00:09:40,390 +يكون ملكًا يمشي على الأرض بل أفضل عند الله من + +85 +00:09:40,390 --> 00:09:46,890 +الملائكة كما أسجد الله الملائكة لآدم عليه السلام + +86 +00:09:46,890 --> 00:09:53,030 +وإذ قلنا للملائكة اسجدوا لآدم فسجدوا إلا إبليس أبى + +87 +00:09:53,030 --> 00:10:01,250 +واستكبر وكان من الكافرين وبالمعصية يهبط الإنسان من + +88 +00:10:01,250 --> 00:10:09,910 +سمائه ومن عليائه إلى الأرض السابعة يتمرغ في الأوحال + +89 +00:10:09,910 --> 00:10:19,990 +والمستنقعات مع الأبالسة والشياطين بل أشد منهم + +90 +00:10:19,990 --> 00:10:25,870 +معصية لله عز وجل كما قال الله تبارك وتعالى: شياطين + +91 +00:10:25,870 --> 00:10:33,630 +الإنس والجني ويحي بعضهم إلى بعض زخرف القول غرورًا + +92 +00:10:33,630 --> 00:10:38,970 +فهنا قدم الله شياطين الإنس على شياطين الجن + +93 +00:10:38,970 --> 00:10:42,270 +لخطورتهم + +94 +00:10:42,270 --> 00:10:52,060 +بالإفساد نعم بل إن شياطين الجن قد تتعلم من شياطين + +95 +00:10:52,060 --> 00:10:57,700 +الإنس كما قال الشاعر قديمًا: وكنت امرأة من جندي إبليس + +96 +00:10:57,700 --> 00:11:03,920 +فارتقى بي الحال حتى صار إبليس من جندي فلو مات قبلي + +97 +00:11:03,920 --> 00:11:11,580 +كنت أحصن بعده طرائق فسق ليس يحصنها بعدي أعود إلى + +98 +00:11:11,580 --> 00:11:20,720 +ذي بدء فأقول إن الإنسان معرض للخطأ لأنه ليس ملكًا + +99 +00:11:20,720 --> 00:11:24,040 +مفطورًا + +100 +00:11:24,040 --> 00:11:31,680 +على طاعته وفي نفس الوقت ليس نبيًا معصومًا من الزلل + +101 +00:11:31,680 --> 00:11:41,560 +فماذا يفعل عليه أن يرجع إلى الله وأن يأوب إلى الله + +102 +00:11:41,560 --> 00:11:51,430 +وأن يتوب إليه سبحانه وتعالى ولا ييأس ولا يقنط لأن + +103 +00:11:51,430 --> 00:11:57,270 +اليأس والقنوط من صفات الكافرين كما في قصة يوسف على + +104 +00:11:57,270 --> 00:12:02,120 +لسان يعقوب عليه السلام: يا بني اذهبوا فتحسسوا من + +105 +00:12:02,120 --> 00:12:07,500 +يوسف وأخيه ولا تيأسوا من روح الله إنه لا ييأس من + +106 +00:12:07,500 --> 00:12:13,660 +روح الله إلا القوم الكافرون فاليأس والإيمان خطان + +107 +00:12:13,660 --> 00:12:20,780 +متوازيان لا يلتقيان ولا يجتمعان فما على الإنسان + +108 +00:12:20,780 --> 00:12:27,820 +المسلم إذا مرتكب معصية أو فحشة أو خطيئة في حال + +109 +00:12:27,820 --> 00:12:37,670 +غفلة أو نسيان عليه أن يتوب إلى الله فإن أبواب + +110 +00:12:37,670 --> 00:12:46,390 +السماء مفتوحة وإن أبواب التوبة لا تغلق أبدًا وقد قال + +111 +00:12:46,390 --> 00:12:51,430 +الله تبارك وتعالى وهذه آية في سورة الزمر كان رسول + +112 +00:12:51,430 --> 00:12:56,730 +الله يحبها صلى الله عليه وسلم لأنها تفتح أبواب + +113 +00:12:56,730 --> 00:13:02,710 +التوبة إلى العصاة قل يا عبادي الذين أسرفوا على + +114 +00:13:02,710 --> 00:13:08,830 +أنفسهم لا تقنطوا من رحمة الله إن الله يغفر الذنوب + +115 +00:13:08,830 --> 00:13:16,590 +جميعًا إنه هو الغفور الرحيم سبحانه وتعالى وإن سألت + +116 +00:13:16,590 --> 00:13:25,870 +عن شروط التوبة فإن شروط التوبة النصوح كما قال الله + +117 +00:13:25,870 --> 00:13:30,290 +تعالى يا أيها الذين آمنوا توبوا إلى الله توبة + +118 +00:13:30,290 --> 00:13:37,670 +نصوحًا قلت هي أربعة ثلاثة إذا كان الذنب بين العبد + +119 +00:13:37,670 --> 00:13:42,070 +وربه وواحدة + +120 +00:13:42,820 --> 00:13:47,960 +وهي الرابعة إذا كان الذنب بين الإنسان وأخيه + +121 +00:13:47,960 --> 00:13:54,640 +الإنسان أما الثلاثة الأول فأولًا الإقلاع عن المعصية + +122 +00:13:54,640 --> 00:14:07,920 +وثانيًا الندم والندم في القلب وثالثًا العزم على + +123 +00:14:07,920 --> 00:14:15,030 +عدم العودة إلى المعصية وإلا كان استهتارًا بالله + +124 +00:14:15,030 --> 00:14:21,570 +سبحانه وتعالى إذا ما عصى وتاب ثم عاد إلى المعصية + +125 +00:14:21,570 --> 00:14:32,070 +وهكذا ورابعًا وهذه كما قالت العرب ثالثة الأثافر + +126 +00:14:32,070 --> 00:14:41,190 +لأن الناس قد يغفلون عنها إذا كان الذنب أو إذا كان + +127 +00:14:41,190 --> 00:14:48,230 +الحق بين المسلم وأخيه المسلم فهذه لا يغفرها الله + +128 +00:14:48,230 --> 00:14:57,450 +سبحانه وتعالى لابد أن تعود الحقوق إلى أصحابها وأن + +129 +00:14:57,450 --> 00:15:06,290 +تؤدى الأمانات إلى أهلها وإلا كان يوم القيامة وإذا + +130 +00:15:06,290 --> 00:15:15,480 +كان يوم القيامة فلا دراهم ولا دنانير ولا شواكل + +131 +00:15:15,480 --> 00:15:25,820 +بلغة العصر إنما المقاصة يوم القيامة والحساب يكون + +132 +00:15:25,820 --> 00:15:32,560 +بالحسنات والسيئات كما جاء في السنة النبوية الشريفة + +133 +00:15:32,560 --> 00:15:38,100 +أن الله يجمع الظالم والمظلوم يوم القيامة فيقول الله + +134 +00:15:38,100 --> 00:15:45,640 +تعالى للظالم: أعطي أخاك حقه فيقول: يا رب ما معي + +135 +00:15:45,640 --> 00:15:51,920 +دراهم ما معي دنانير أو شواكل فيقول الله تعالى + +136 +00:15:51,920 --> 00:15:59,160 +أعطيه من حسناتك وما أحوج العبد يوم القيامة ما أحوجك + +137 +00:15:59,160 --> 00:16:06,760 +يا مسكين إلى حسنات تسقل بها موازينك يوم القيامة + +138 +00:16:06,760 --> 00:16:15,340 +فيأخذ من حسناتي الظالم وتغطى للمظلوم فإذا ما فنت + +139 +00:16:15,340 --> 00:16:21,880 +حسنات الظالم أخذ من سيئات المظلوم فطرحت على الظالم + +140 +00:16:21,880 --> 00:16:34,130 +فطرح في النار وبئس القرار قلت هذه الثمرة الرابعة + +141 +00:16:34,130 --> 00:16:39,070 +من الثمار أو النتائج والآثار الناجمة + +142 +00:16:40,640 --> 00:16:50,100 +عن خاصية الربانية من أعظم هذه الخصائص أنك لا تقنط + +143 +00:16:50,100 --> 00:16:55,200 +من رحمة الله فإذا ما شعرت بمعصية أو خطيئة أو ذنب + +144 +00:16:55,200 --> 00:17:00,270 +أو تقصير ما عليك إلا أن تهرع إلى الله تائبًا + +145 +00:17:00,270 --> 00:17:08,210 +ونادمًا وتذرف الدموع ساخنة على الوجنات فالله غفور + +146 +00:17:08,210 --> 00:17:14,910 +والله عفو والله رحيم يقبل التوبة عن عباده ويعفو عن + +147 +00:17:14,910 --> 00:17:22,810 +كثير سبحانه وتعالى أما خامسًا فمن النتائج والأثار + +148 +00:17:22,810 --> 00:17:27,790 +التي تنبثق عن خاصية الربانية وكما قلنا هي أم + +149 +00:17:27,790 --> 00:17:35,690 +الخصائص أن الجميع في كنف هذه النظم سواء وهذه إن + +150 +00:17:35,690 --> 00:17:40,670 +شاء الله سنأتي إليها بشيء من التفصيل عند الوصول + +151 +00:17:40,670 --> 00:17:47,610 +إلى الفصل السادس عند الحديث عن قواعد النظام + +152 +00:17:47,610 --> 00:17:53,460 +السياسي الأربعة بدءًا بالحاكمية ومروراً بالعدل + +153 +00:17:53,460 --> 00:18:00,780 +والمساواة والشورى والطاعة سنتكلم عن هذا طويلاً عندما + +154 +00:18:00,780 --> 00:18:09,780 +نصل إلى الخاصية الثانية نعم أو القاعدة الثانية من + +155 +00:18:09,780 --> 00:18:14,240 +قواعد النظام الإسلامي ألا وهي العدل والمساواة + +156 +00:18:14,240 --> 00:18:20,540 +فالناس في نظر الشريعة الإسلامية سواسية كأسنان + +157 +00:18:20,540 --> 00:18:29,700 +المشط لا فرق بين كبير وصغير أو ذكر وأنثى أو بيضاء + +158 +00:18:29,700 --> 00:18:36,600 +وسوداء أو أحمر وأصفر بل لا فرق بين حاكم ومحكوم أو + +159 +00:18:36,600 --> 00:18:45,660 +رئيس ومرؤوس أو قوي وضعيف أو غني وفقير فالميزان + +160 +00:18:45,660 --> 00:18:55,030 +الثابت الذي نحتكم إليه بل شعارنا الخالد إلى يوم + +161 +00:18:55,030 --> 00:19:01,210 +القيامة إلى أن يرث الله الأرض ومن عليها قوله تبارك + +162 +00:19:01,210 --> 00:19:06,030 +وتعالى في سورة الحجرات وسنأتي إلى هذه الآية إن شاء + +163 +00:19:06,030 --> 00:19:11,090 +الله يا أيها الناس إن خلقناكم من ذكر وأنثى + +164 +00:19:11,090 --> 00:19:16,430 +وجعلناكم شعوبًا وقبائل لتعرفوا إن أكرمكم عند الله + +165 +00:19:16,430 --> 00:19:23,460 +اتقاكم إن الله عليم خبير صدق الله العظيم أما ثالثًا + +166 +00:19:23,460 --> 00:19:33,180 +وقد سبق أن قلت إن خصائص النظم الإسلامية التي ستأتي + +167 +00:19:33,180 --> 00:19:43,120 +بعد قليل من الثبات والمرونة ومن الشمول والتوازن + +168 +00:19:43,120 --> 00:19:51,320 +ومن التكامل والترابط ومن الواقعية والمثالية + +169 +00:19:51,320 --> 00:20:01,160 +والعالمية والجزاء الأخروي كذلك إنما هي تنبثق عن + +170 +00:20:01,160 --> 00:20:08,960 +خاصية الربانية أو هي ثمار أو نتائجه متولدة أو + +171 +00:20:08,960 --> 00:20:17,140 +متفرعة عن خاصية الربانية ولذا تعجلت فقلت إن خاصية + +172 +00:20:17,140 --> 00:20:26,020 +الربانية هي أم الخصائص بحق نعم الآن بعد أن انتهينا + +173 +00:20:26,020 --> 00:20:32,370 +من الخاصية الكبرى وهي أم الخصائص نأتي إلى الخاصية + +174 +00:20:32,370 --> 00:20:37,630 +الثانية من خصائص النظم الإسلامية ألا وهي الثبات + +175 +00:20:37,630 --> 00:20:48,570 +والمرونة وهنا نقف قليلًا لأن البعض ظاهريًا وللوهلة + +176 +00:20:48,570 --> 00:20:54,280 +الأولى قد يظن أن ثمة تناقضًا بين الثبات والمرونة + +177 +00:20:54,280 --> 00:20:58,840 +فيقول كيف تتصف النظم الإسلامية أو الشريعة + +178 +00:20:58,840 --> 00:21:06,400 +الإسلامية مرة بالثبات ومرة بالمرونة فنقول لا + +179 +00:21:06,400 --> 00:21:15,200 +تناقض البتة لأن الثبات في أمور ولأن المرونة في + +180 +00:21:15,200 --> 00:21:25,990 +أمور أما الثبات فإنما يكون في القواعد والأسس + +181 +00:21:25,990 --> 00:21:36,350 +والأصول أما المرونة فإنما تكون في الوسائل والفروع + +182 +00:21:36,350 --> 00:21:47,330 +أو كما سيأتي بعد قليل بالأعراف والعادات والتقاليد + +183 +00:21:47,330 --> 00:21:49,370 +نعم + +184 +00:21:53,780 --> 00:21:58,580 +لو أردنا أن نضرب مثلًا للقواعد + +185 +00:21:58,580 --> 00:22:05,760 +والأصول التي لا تتغير ولا تتبدل إلى يوم القيامة + +186 +00:22:05,760 --> 00:22:14,840 +أرى أن نقتصر على ثلاثة وهذا ليس في الكتاب ولكن من + +187 +00:22:14,840 --> 00:22:20,240 +أجل أن يتضح الموضوع نقول الثبات إنما يكون أولاً في + +188 +00:22:20,240 --> 00:22:26,420 +العقيدة فالعقيدة أو التي عبر عنها القرآن الكريم + +189 +00:22:26,420 --> 00:22:32,580 +الإيمان بالله وبرسوله وبالكتب وباليوم الآخر و + +190 +00:22:32,580 --> 00:22:37,600 +القضاء والقدر خيره وشره من الله تبارك وتعالى + +191 +00:22:37,600 --> 00:22:46,460 +فهذه أركان الإيمان أو أصول العقيدة ثابتة لا تتغير + +192 +00:22:46,460 --> 00:22:54,140 +ولا تتبدل إلى يوم القيامة إلى أن يرث الله الأرض ومن + +193 +00:22:54,140 --> 00:23:06,480 +عليها وكذلك الحديث عن نظام الأسرة كذلك نظام الأسرة + +194 +00:23:06,480 --> 00:23:17,220 +لا يتغير ولا يتبدل بمعنى أن المحرمات هن المحرمات + +195 +00:23:17,220 --> 00:23:26,720 +إلى يوم القيامته فلن يأتي يوم مثلًا تحل فيه الأم أو + +196 +00:23:26,720 --> 00:23:33,780 +الجدّة أو البنت أو الأخت فهؤلاء من المحرمات + +197 +00:23:33,780 --> 00:23:44,490 +مؤبدًا إلى يوم القيامته نعم لكن هناك محرمات مؤقتة + +198 +00:23:44,490 --> 00:23:51,470 +فالمحرمات المؤقتة مثل أخت الزوجة مثل عمّة الزوجة + +199 +00:23:51,470 --> 00:23:59,070 +مثل خالة الزوجة لا يجمع بينهما البتة كما قال الله + +200 +00:23:59,070 --> 00:24:03,830 +وأن تجمعوا بين الأختين فلا يصح أن يجمع بين الأختين + +201 +00:24:03,830 --> 00:24:12,370 +وكما جاء في السنة لا يجمع بين البنت وعمتها أو بين + +202 +00:24:12,370 --> 00:24:20,650 +البنت وخالتها لأنكم إن فعلتم ذلك فقد قطعتم أرحامكم + +203 +00:24:20,650 --> 00:24:27,110 +من تصل المرأة إذا لم تصل أختها وخالتها وعمتها + +204 +00:24:27,110 --> 00:24:34,370 +وجمعتهم في بيت واحد لكن إذا ماتت الأخت فللزوج أن + +205 +00:24:34,370 --> 00:24:41,070 +يتزوج أختها حتى لو طلقها في حياة أختها ولم تعد + +206 +00:24:41,990 --> 00:24:48,050 +الأخت على ذمته له أن يتزوج أختها المهم أن لا يجمع + +207 +00:24:48,050 --> 00:24:54,990 +بين الأختين وكذلك لو ماتت البنت فتزوج عمّتها أو + +208 +00:24:54,990 --> 00:25:04,610 +تزوج خالتها فله ذلك أيضًا فهؤلاء من المحرمات مؤبدًا + +209 +00:25:05,370 --> 00:25:10,810 +وهذا هو الحكم إلى يوم القيامة فهذا هو السبب أما + +210 +00:25:10,810 --> 00:25:15,990 +ثالثًا وأردت الاختصار فهو الحدود الحدود أيضًا من + +211 +00:25:15,990 --> 00:25:21,630 +الأحكام الثابتة التي لا يعتريها تغيير ولا تبديل + +212 +00:25:21,630 --> 00:25:27,610 +قلت هذا من عندي وليس من الكتاب فحد الزنا مثلًا إذا + +213 +00:25:27,610 --> 00:25:35,010 +كان الزاني محصنًا يعني متزوجًا حتى ولو طلق ... المهم + +214 +00:25:35,010 --> 00:25:42,330 +أنه سبق له أن تزوج ودخل بأهله وزنى فإن حكمه + +215 +00:25:42,330 --> 00:25:48,010 +الرجم إلى يوم القيامة وهذا ثابت في السنة الصحيحة + +216 +00:25:48,010 --> 00:25:54,330 +عند مسلم عن عمرو بن الخطاب نزلت الآية تلونها و + +217 +00:25:54,330 --> 00:25:59,710 +لكنها منسوخة التلاوة باقية الحكم الشيخ والشيخة إذا + +218 +00:25:59,710 --> 00:26:06,750 +زنيا فارجموهم البتة نكالًا من الله والله عزيز حكيم + +219 +00:26:06,750 --> 00:26:11,810 +حتى قال عمر أخش أن يأتي يوم يقول الناس لا نجد + +220 +00:26:11,810 --> 00:26:16,710 +الرجم في كتاب الله وقد رجمنا وقد جاء في السنة + +221 +00:26:16,710 --> 00:26:21,070 +الصحيحة عند البخاري وعند مسلم رجموا ماعز وال + +222 +00:26:21,070 --> 00:26:28,150 +غامدية وقال اغضوا يا أنيس المرأة هذا فإن اعترفت + +223 +00:26:28,150 --> 00:26:36,590 +فارجمها وأما الجلد فهو لذانِ العذَب بمعنى غير المحصن + +224 +00:26:36,590 --> 00:26:42,890 +الذي لم يتزوج بعد وهذا ثابت في سورة النور الزانية + +225 +00:26:42,890 --> 00:26:50,090 +والزاني فاجلدوا كل واحد منهما مائة جلدة نعم وكذلك + +226 +00:26:50,090 --> 00:26:58,330 +حدّ السارقة هو قطع اليد وهذا ثابت أيضًا في القرآن + +227 +00:26:58,330 --> 00:27:04,090 +الكريم في سورة المائدة السارق والسارقة فاقطعوا + +228 +00:27:04,090 --> 00:27:10,030 +أيديهما جزاء بما كسبوا نكالًا من الله والله عزيز حكيم + +229 +00:27:10,030 --> 00:27:15,880 +وكذلك الخمر وقد أجمع المسلمون كما سيأتي في المصدر + +230 +00:27:15,880 --> 00:27:20,600 +الثالث من مصادر النظم الإسلامية بعد القرآن والسنة + +231 +00:27:20,600 --> 00:27:25,580 +يأتي الإجماع أن المسلمين قد أجمعوا في عهد عمر بن + +232 +00:27:25,580 --> 00:27:31,640 +الخطاب رضي الله عنه على جلد شارب الخمر ثمانين جلدة + +233 +00:27:31,640 --> 00:27:38,360 +وهكذا قاطعوا الطريق كما في سورة المائدة إنما جزاء + +234 +00:27:38,360 --> 00:27:43,490 +الذين يحاربون الله ورسوله ويصدعون أن يقتلوا أو + +235 +00:27:43,490 --> 00:27:47,770 +يصلبوا أو تقطع أيديهم وأرجلهم من خلاف أو ينفى + +236 +00:27:47,770 --> 00:27:53,550 +مرض إلى آخر الآية إذا قلت إن الثبات لا يكون مطلقًا + +237 +00:27:53,550 --> 00:27:59,190 +في كل شيء إنما يكون الثبات في أمور وقد ذكرت منها + +238 +00:27:59,190 --> 00:28:05,530 +ثلاثة أولاً العقيدة وثانيًا النظام الاجتماعي يعني + +239 +00:28:05,530 --> 00:28:12,790 +المحرمات من النساء أبدًا وكذلك المحرمات مؤقتًا و + +240 +00:28:12,790 --> 00:28:19,270 +ثالثًا الحدود فهي ثابتة أما بالنسبة إلى المرونة فإن + +241 +00:28:19,270 --> 00:28:27,470 +المرونة إنما تكون في الوسائل والفروع وهذه تتغير + +242 +00:28:27,470 --> 00:28:38,310 +وفق الأعراف والتقاليد والعادات حتى قيل إن الأحكام + +243 +00:28:38,310 --> 00:28:49,340 +تتغيّر بزمن ومكان وأشخاص هذا هو معنى المرونة + +244 +00:28:49,340 --> 00:28:54,380 +فالفتوى في زمن قد لا تكون هي نفسها في زمن آخر + +245 +00:28:54,380 --> 00:29:00,480 +والفتوى في مكان قد لا تكون هي في مكان آخر وقد + +246 +00:29:00,480 --> 00:29:06,630 +تختلف الفتوى من شخص إلى شخص آخر وهذا كله ليس في + +247 +00:29:06,630 --> 00:29:11,970 +الكتاب ولكن يحتاج إلى شيء من التوضيح لطلابنا + +248 +00:29:11,970 --> 00:29:21,750 +الأعزاء فقد ورد أن رجلًا سأل ابن عباس هل القاتل + +249 +00:29:21,750 --> 00:29:31,720 +عمدًا توبة فقال له لا فجاء بعده شخص آخر وسأل نفس + +250 +00:29:31,720 --> 00:29:36,540 +السؤال يا ابن عباس يا ابن عم رسول الله صلى الله + +251 +00:29:36,540 --> 00:29:42,740 +عليه وسلم هل القاتل عمدًا توبة؟ قال نعم فعجب القوم + +252 +00:29:42,740 --> 00:29:49,780 +قالوا يا حبر هذه الأمة يا ابن عم رسول الله سأل + +253 +00:29:49,780 --> 00:29:58,670 +شخصان سؤالًا واحدًا هل القاتل عمدًا توبة؟ فقلت للأول + +254 +00:29:58,670 --> 00:30:05,310 +لا وقلت للثاني نعم فقال أما الأول قلت له لا لأنه + +255 +00:30:05,310 --> 00:30:12,730 +أراد أن يقتل أما رأيتم انتفاخ أوداجه واحمرار عينيْه + +256 +00:30:12,730 --> 00:30:20,230 +ولذلك قالوا لابد للمفتي أن يكون على علم بحال + +257 +00:30:20,230 --> 00:30:29,440 +المستفتي نعم أما الثاني فأراد أن يتفكّأ والرأي + +258 +00:30:29,440 --> 00:30:34,800 +الراجح في هذه المثل والذي عليه أكثر العلماء أن + +259 +00:30:34,800 --> 00:30:42,000 +للقاتل عمدًا توبة بأدلة من الكتاب ومن السنة نقولها + +260 +00:30:42,000 --> 00:30:47,260 +باختصار منها قوله تبارك وتعالى إن الله لا يغفر أي + +261 +00:30:47,260 --> 00:30:54,500 +يشرك به ويغفر ما دون ذلك لمن يشاء وفي وصف عباد + +262 +00:30:54,500 --> 00:30:58,600 +الرحمن في سورة الفرقان والذين لا يدعون مع الله + +263 +00:30:58,600 --> 00:31:04,320 +إلهًا آخر ولا يقتلون النفس التي حرم الله إلا بالحق + +264 +00:31:04,320 --> 00:31:10,180 +ولا يزنون ومن يفعل ذلك يلقى أثامه يضاعف له العذاب + +265 +00:31:10,180 --> 00:31:16,560 +يوم القيامة ويخلد فيه مهانة إلا من تاب وآمن وعمل + +266 +00:31:16,560 --> 00:31:22,200 +عملًا صالحًا فأولئك يبدل الله سيئاتهم حسنات وكان الله + +267 +00:31:22,200 --> 00:31:26,360 +غفورًا رحيمًا والآية التي تلونها في سورة الزمر قل يا + +268 +00:31:26,360 --> 00:31:30,340 +عبادي الذين أسرفوا على أنفسهم لا تقنطوا من رحمة + +269 +00:31:30,340 --> 00:31:34,600 +الله إن الله يغفر الذنوب جميعًا إنه هو الغفور + +270 +00:31:34,600 --> 00:31:41,260 +الرحيم نعم آيات كثيرة تفتح أبواب التوبة صدق الله + +271 +00:31:41,260 --> 00:31:47,860 +العظيم ومن الأحاديث الكثيرة نختصر على حديث صحيح + +272 +00:31:47,860 --> 00:31:54,400 +عند مسلم عن بني إسرائيل الذي قتل تسعة وتسعين نفسًا + +273 +00:31:55,280 --> 00:32:04,760 +ثم قتل الراهب المئة ثم سأل العالم الفقيه ولذلك + +274 +00:32:04,760 --> 00:32:12,640 +قيل كما في الحديث النبوي الشريف لفقيه واحد أشد على + +275 +00:32:12,640 --> 00:32:20,640 +الشيطان من ألف عابد نعم قال له ومن يحول بينك وبين + +276 +00:32:20,640 --> 00:32:27,570 +الله تب إلى الله نعم فإن الله يغفر الذنوب جميعًا و + +277 +00:32:27,570 --> 00:32:33,850 +تاب إلى الله وصلح حاله وحسنت توبته وغفر الله له + +278 +00:32:33,850 --> 00:32:41,390 +وأدخله الجنة رأيت كيف تغيرت الفتوى من شخص إلى شخص + +279 +00:32:41,390 --> 00:32:50,540 +وقد سأل نفس السؤال وكذلك من مكان إلى مكان وفتاوى + +280 +00:32:50,540 --> 00:33:00,700 +التقاليد والأعراف والعادات فقد جاء شخص إلى الإمام + +281 +00:33:00,700 --> 00:33:07,920 +مالك ولا يفتي ومالك في المدينة مفتي المدينة في عصره + +282 +00:33:07,920 --> 00:33:18,780 +رضي الله عنه وسأله سؤالا يا إمام قلت لزوجي أنت طالق + +283 +00:33:18,780 --> 00:33:27,320 +إن أكلت سمكا فلو أكلت لحما هل تطلق زوجتي؟ فقال له + +284 +00:33:27,320 --> 00:33:31,720 +الإمام مالك: نعم، قال: هل من دليل من القرآن؟ قال: نعم + +285 +00:33:32,290 --> 00:33:37,970 +قال: إن الله سمى السمكة في القرآن الكريم لحما طريا + +286 +00:33:37,970 --> 00:33:44,490 +نعم، فنحن كما ذكر الله: تستخرجون حلية تلبسونها + +287 +00:33:44,490 --> 00:33:50,690 +وتأكلون لحما طريا، فاللحم الطري هو السمك في القرآن + +288 +00:33:50,690 --> 00:33:56,490 +الكريم، إذا الإمام مالك أفتى له بطلاق زوجته وأهله + +289 +00:33:56,490 --> 00:34:03,800 +لأن الله سمى السمكة لحما طريا، ولكن هذا يختلف في بلد + +290 +00:34:03,800 --> 00:34:11,400 +آخر، ولعل الرجل كان يحب زوجته ولا يريد طلاقها + +291 +00:34:11,400 --> 00:34:19,050 +فانقطع صهوة جواده حتى وصل إلى بغداد إلى الكوفة + +292 +00:34:19,050 --> 00:34:26,610 +والبصرة بلد العلم والعلماء حيث الإمام أبو حنيفة + +293 +00:34:26,610 --> 00:34:31,850 +وأبو حنيفة أن عمار بن ثابت هو شيخ الأئمة، قال له: يا + +294 +00:34:31,850 --> 00:34:38,390 +أبا حنيفة، قلت لزوجي: أنت طالق إن أكلت سمكة، فلو أكلت + +295 +00:34:38,390 --> 00:34:44,010 +لحمة هل تطلق زوجتي؟ قال له: لا، قال: إن الإمام مالكا + +296 +00:34:44,010 --> 00:34:49,170 +أفتاني من القرآن، فأين هذا في القرآن؟ قرأ رأيت لو أن + +297 +00:34:49,170 --> 00:34:55,750 +رجلا قال لزوجه: أنت طالق لو جلست على بساطة، فلو جلس + +298 +00:34:55,750 --> 00:35:01,330 +على الأرض هل تطلق زوجته؟ قال: لا، قال: فإن الله يقول + +299 +00:35:01,330 --> 00:35:08,950 +والأرض بساطة، إذا المرونة إنما تكون في الفروع + +300 +00:35:08,950 --> 00:35:15,620 +والوسائل أو كما قال هنا في الكتاب في الأعراف و + +301 +00:35:15,620 --> 00:35:23,080 +العادات المنتشرة بل في البيئات والظروف المتغيرة + +302 +00:35:23,080 --> 00:35:31,080 +فنحن في غزة مثلا لو قال أبو لابنه: اشتري لنا لحمة + +303 +00:35:31,080 --> 00:35:36,880 +لا يشتري له سمكة ولا يشتري له فراخة، على الرغم أن + +304 +00:35:36,880 --> 00:35:43,260 +السمك لحم وأن الفراخ لحم، ولكن يشتري له لحمة، لحمة + +305 +00:35:43,260 --> 00:35:49,340 +عجل أو لحمة خروف مثلا، ولذلك من قال هنا في قطاع + +306 +00:35:49,340 --> 00:35:55,910 +غزة لزوجه: أنت طالق إن أكلت سمكا، فلو أكل لحما + +307 +00:35:55,910 --> 00:36:02,870 +لا تطلق زوجته، وهكذا تتغير الفتوى بتغير الزمان + +308 +00:36:02,870 --> 00:36:10,330 +والمكان وحتى الأشخاص، ومن أراد أن يرجع فليرجع إلى + +309 +00:36:10,330 --> 00:36:18,850 +مصنفات العلامة ابن قيم الجوزية وعلى رأسها الكتاب + +310 +00:36:18,850 --> 00:36:26,430 +العظيم إعلام الموقعين عن رب العالمين، نعم، وقالوا + +311 +00:36:26,430 --> 00:36:33,520 +إعلام الموقعين عن رب العالمين، إعلام جمع علم، والذي + +312 +00:36:33,520 --> 00:36:38,740 +أراه راجحا هو المصدر إعلام، إعلما، إعلام الموقعين + +313 +00:36:38,740 --> 00:36:43,940 +عن رب العالمين، ففيه الكثير من مثل هذه الأمثلة + +314 +00:36:43,940 --> 00:36:53,930 +والنماذج، إذا نختصر هذه الخاصية فنقول: السباتو + +315 +00:36:53,930 --> 00:37:01,850 +المرونة ليست في شيء واحد أو ليست في أمر واحد + +316 +00:37:01,850 --> 00:37:07,470 +فالثبات إنما يكون في أمور كما ذكرنا في العقيدة و + +317 +00:37:07,470 --> 00:37:15,230 +الأسرة والحدود، والمرونة إنما تكون في الفروع و + +318 +00:37:15,230 --> 00:37:22,500 +الوسائل ألا فاحفظوها أو في العادات والتقاليد نعم + +319 +00:37:22,500 --> 00:37:28,440 +والبيئات المختلفة، أما ثالثا من خصائص النظم + +320 +00:37:28,440 --> 00:37:35,020 +الإسلامية الشمول والتوازن، وكنت أتمنى أن يكون ثالثا + +321 +00:37:35,020 --> 00:37:42,840 +الشمول ورابعا التوازن، فالشمول خاصية مستقلة من + +322 +00:37:42,840 --> 00:37:50,460 +خصائص النظم الإسلامية وكذلك التوازن، فلا يصح أن نعرف + +323 +00:37:50,460 --> 00:37:59,540 +الشمول والتوازن تعريفا واحدا، فلكل تعريف، ونبدأ أولا + +324 +00:37:59,540 --> 00:38:08,480 +بالشمول، ما هو مصطلح الشمول؟ الشمول بمعنى أنها نظم + +325 +00:38:08,480 --> 00:38:17,650 +تعالج جوانب الحياة كلها، نظم تعالج جوانب الحياة كلها + +326 +00:38:17,650 --> 00:38:27,570 +من عقيدة وعبادة ومعاملة وأخلاق وسياسة وحكم + +327 +00:38:27,570 --> 00:38:34,500 +إلى غير ذلك، بل الشمول أيضا الذي يراعي مراحِل حياة + +328 +00:38:34,500 --> 00:38:42,940 +الفرد كلها، طفلا وصبيا وشابا وشيخا، والشمول الذي + +329 +00:38:42,940 --> 00:38:49,820 +يمتد لمعالجة شؤون الدنيا والآخرة وشؤون الفرد و + +330 +00:38:49,820 --> 00:38:58,700 +المجتمع، نأتي بعد هذا المصطلح إلى الأدلة، إذا قلنا + +331 +00:38:58,700 --> 00:39:07,480 +بأن الشمول أنها نظم تعالج جوانب الحياة كلها، ما هي + +332 +00:39:07,480 --> 00:39:17,340 +الأدلة على ذلك؟ نقتصر على أدلة ثلاثة في الكتاب + +333 +00:39:17,340 --> 00:39:23,360 +المقرر وهي كافية إن شاء الله، أول هذه الأدلة على + +334 +00:39:23,360 --> 00:39:30,260 +شمول النظم الإسلامية قوله تبارك وتعالى: وكل شيء + +335 +00:39:30,260 --> 00:39:37,080 +أحصيناه في إمام مبين، وقوله تبارك وتعالى: ونزلنا + +336 +00:39:37,080 --> 00:39:43,200 +عليك الكتاب تبيانا لكل شيء، وقوله تبارك وتعالى: ما + +337 +00:39:43,200 --> 00:39:49,070 +فرطنا في الكتاب من شيء، إذا هذه ثلاثة أدلة من الكتاب + +338 +00:39:49,070 --> 00:39:55,730 +أي من القرآن الكريم على مدى شمولية النظم الإسلامية + +339 +00:39:55,730 --> 00:40:02,650 +للدنيا والآخرة، للعقيدة والعبادة والمعاملة والأخلاق + +340 +00:40:02,650 --> 00:40:08,900 +والسياسة والحكم إلى غير ذلك، وليس معنا إلا حديث واحد + +341 +00:40:08,900 --> 00:40:17,200 +من السنة النبوية، فنكتفي به للدلالة على مدى شمولية + +342 +00:40:17,200 --> 00:40:26,360 +النظم الإسلامية، وهذا الحديث مفهومه ومعناه أن يهوديا + +343 +00:40:26,360 --> 00:40:33,740 +قال لسلمان الفارسي: يا سلمان لقد علمكم نبيكم كل شيء + +344 +00:40:33,740 --> 00:40:40,660 +حتى قضاء الحاجة، يعني ونحن في مساق دراسات + +345 +00:40:42,330 --> 00:40:47,910 +فقهية من كتاب الفقه المنهجي على مذهب الإمام + +346 +00:40:47,910 --> 00:40:55,610 +الشافعي ندرس الاستنجاء أو آداب الخلاء، عندما ندخل + +347 +00:40:55,610 --> 00:41:02,410 +بالشمال ونقول: بسم الله أعوذ بك من الخبث والخبائث + +348 +00:41:03,240 --> 00:41:09,300 +ونخرج باليمين خلافا للمسجد ونقول: اللهم غفرانك، و + +349 +00:41:09,300 --> 00:41:15,640 +الأحكام ستدرس لكم في مساق دراسات فقهية إن شاء الله + +350 +00:41:15,640 --> 00:41:22,540 +تبارك وتعالى، المهم أن هذا اليهودي قد عرف حقيقة هذا + +351 +00:41:22,540 --> 00:41:28,040 +الدين، يا سلمان لقد علمكم نبيكم كل شيء حتى قضاء + +352 +00:41:28,760 --> 00:41:37,580 +يعني حتى قضاء الحاجة، نعم هذا هو الشمول، نأتي الآن + +353 +00:41:37,580 --> 00:41:45,800 +إلى خاصية أخرى وقد ارتبطت هنا بالشمول، لما بين الشمول + +354 +00:41:45,800 --> 00:41:56,440 +والتوازن من ترابط نعم، واتّسار فمعنى + +355 +00:41:57,770 --> 00:42:07,670 +التوازن أنها متناسقة، أنها مترابطة، أنها متكاملة + +356 +00:42:07,670 --> 00:42:16,890 +ولعل هذا يعود بنا إلى تعريف النظم لغة، عندما قلنا + +357 +00:42:16,890 --> 00:42:24,450 +أن النظام أصله اللغوي من الفعل نظم، من الفعل + +358 +00:42:24,450 --> 00:42:34,610 +الثلاثي المجرد النون والظاء والميم، بمعنى ألفة + +359 +00:42:34,610 --> 00:42:46,050 +وبمعنى ربطة، وبمعنى جمعة، فيكون معنى النظم لغة ضم + +360 +00:42:46,050 --> 00:42:52,630 +الأشياء بعضها إلى بعض بتنسيق وترتيب وتناغم + +361 +00:42:52,630 --> 00:42:59,060 +واستقامة أو تكامل وترابط، وقلت في المحاضرة الأولى + +362 +00:42:59,060 --> 00:43:05,780 +إذا ما كانت هذه الأشياء كحبات العقد مثلا أو الصبحية + +363 +00:43:05,780 --> 00:43:15,340 +وقد انفرطت وتباعدت وصار كل حبة في واد مهلهلة + +364 +00:43:15,340 --> 00:43:23,140 +مبعثرة، فإنه لا يطلق عليها نظام ولا تسمى منظومة، و + +365 +00:43:23,140 --> 00:43:29,640 +كذلك أرى هنا ترابطا بين التوازن وبين المعنى اللغوي + +366 +00:43:29,640 --> 00:43:40,690 +للنظم، فإن معنى توازن هذه النظم كما أسلفنا متناسقة + +367 +00:43:40,690 --> 00:43:49,590 +مترابطة، متكاملة، مثل حبات العقد، لا اختلاف بين + +368 +00:43:49,590 --> 00:43:59,330 +حباتها بحيث لا يطغى فيها جانب على جانب، بل هي تنظم + +369 +00:43:59,330 --> 00:44:08,630 +كل جوانب هذا الكون بلا زيغ أو ميل أو إفراط أو تفريط + +370 +00:44:08,630 --> 00:44:16,810 +هذا هو معنى التوازن، لا إفراط بمعنى زيادة ولا تفريط + +371 +00:44:16,810 --> 00:44:27,850 +بمعنى نقص، نعم، هنا جاء لنا بأمثلة بعضها + +372 +00:44:27,850 --> 00:44:35,700 +ذكر أدلتها وبعضها لم يذكر أدلتها، وحتى لا نطيل عليكم + +373 +00:44:35,700 --> 00:44:44,180 +نكتفي بأمثلة الكتاب أولا، توازن بين حياة الفرد + +374 +00:44:44,180 --> 00:44:49,320 +وحياة المجتمع، وهذه ليس فيها دليل بمعنى أنكم في + +375 +00:44:49,320 --> 00:44:55,370 +الامتحان لا تطالبون بذكر الدليل، وكذلك النظم + +376 +00:44:55,370 --> 00:45:02,630 +الإسلامية توازن بين متطلبات الروح ورغبات الجسد، و + +377 +00:45:02,630 --> 00:45:07,630 +أما ثالثا سنأتي إلى ذلك بالتفصيل عند الحديث عن + +378 +00:45:07,630 --> 00:45:13,410 +التوازن بين الواقعية والمثالية، أما الأمثلة + +379 +00:45:13,410 --> 00:45:23,180 +الثلاثة الآتية فإن لها أدلة تطالبون بها في الامتحان + +380 +00:45:23,180 --> 00:45:31,020 +وهي لا تحفظ، لأن الامتحان قد يكون إلكترونيا، أعمال + +381 +00:45:31,020 --> 00:45:37,980 +الفصل من أربعين درجة والنهائي من ستين، فتلك مائة + +382 +00:45:37,980 --> 00:45:44,660 +كاملة، إذا النظم الإسلامية توازن بين الاهتمام بشؤون + +383 +00:45:44,660 --> 00:45:48,680 +الدنيا وشؤون الآخرة، ما هو الدليل على هذا التوازن + +384 +00:45:48,680 --> 00:45:52,900 +بين شؤون الدنيا وشؤون الآخرة؟ نكتفي بقول تعالى في + +385 +00:45:52,900 --> 00:46:01,320 +سورة القصص في قصة قارون الذي بغى وطغى وكفر بالله + +386 +00:46:02,400 --> 00:46:07,340 +ولم يشكر الله على نعمة الله، بل اغتر بعلمه وقال + +387 +00:46:07,340 --> 00:46:12,680 +إنما أوتيته على علم عندي، فخصف الله به وبقومه + +388 +00:46:12,680 --> 00:46:18,320 +الأرض، ماذا قال الله تبارك وتعالى؟ وابتغي فيما آتاك + +389 +00:46:18,320 --> 00:46:24,620 +الله دار الآخرة ولا تنس نصيبك من الدنيا، فالاهتمام + +390 +00:46:24,620 --> 00:46:35,080 +بالدنيا على حساب الآخرة هذا لا يصح، وكذلك الاهتمام + +391 +00:46:35,080 --> 00:46:41,180 +في الآخرة على حساب الدنيا لا يصح، فلابد من التوازن + +392 +00:46:41,180 --> 00:46:46,920 +بين الدنيا وبين الآخرة، أن تعطي الدنيا حقها وأن + +393 +00:46:46,920 --> 00:46:54,420 +تعطي الآخرة حقها، بحيث لا يطغى جانب على جانب، وكذلك + +394 +00:46:54,420 --> 00:47:00,660 +الاهتمام والتوازن بين + +395 +00:47:03,120 --> 00:47:12,120 +الإسراف والتقتير، فالاسراف رذيلة والتقتير أيضا + +396 +00:47:12,120 --> 00:47:19,980 +رذيلة، وبينهما فضيلة وهي الاقتصاد وترشيد الاستهلاك + +397 +00:47:19,980 --> 00:47:28,160 +هنا جاء لنا آية في سورة الإسراء وهي قوله تبارك + +398 +00:47:28,160 --> 00:47:33,880 +وتعالى: ولا تجعل يدك مغلولة إلى عنقك ولا تبسطها كل + +399 +00:47:33,880 --> 00:47:40,560 +البصر فتقعد ملوما محصورا، نعم، هذه آية مناسبة، ولكن + +400 +00:47:40,560 --> 00:47:47,330 +كنت أتمنى لو جاء المؤلف بآية أقرب إلى العنوان، لأن + +401 +00:47:47,330 --> 00:47:52,750 +العنوان التوازن بين الإسراف والتقتير في وصف عباد + +402 +00:47:52,750 --> 00:47:58,830 +الرحمن في سورة الفرقان والذين إذا أنفقوا لم يسرفوا + +403 +00:47:58,830 --> 00:48:05,490 +ولم يقتروا وكان بين ذلك قوامة، فكل ذلك صحيح إن شاء + +404 +00:48:05,490 --> 00:48:14,390 +الله، وهنا نرى أن الفرق كبير وأن البون شاسع بين + +405 +00:48:14,390 --> 00:48:21,150 +الإسراف وبين التبذير، فلا يصح أن نستشهد بآية + +406 +00:48:21,150 --> 00:48:27,010 +التبذير هنا في قوله تبارك وتعالى: ولا تبذر تبذيرا + +407 +00:48:27,010 --> 00:48:32,200 +إن المبذرين كانوا إخوان الشياطين، وكان الشيطان لربه + +408 +00:48:32,200 --> 00:48:36,940 +كفورا، لأن التبذير إنما يكون في المحرمات، أما + +409 +00:48:36,940 --> 00:48:43,280 +الإسراف فإنما يكون في المباحات، حتى ولو كان مباحا + +410 +00:48:43,280 --> 00:48:51,700 +من طعام وشراب ولباس، ليس لك الإسراف، نعم، وهذا معنى + +411 +00:48:51,700 --> 00:48:57,980 +الآيات التي تلينا عرضته أن ألفت الأنظار حتى لو + +412 +00:48:57,980 --> 00:49:05,860 +سئلنا لا نستشهد بآية الإسراف الأخرى ولا تبذر + +413 +00:49:05,860 --> 00:49:10,480 +تبذيرا، لأن التبذير يكون فيما حرم الله، أما الإسراف + +414 +00:49:10,480 --> 00:49:21,790 +فقد يكون في حق المؤمنين، نعم، أما أخيرا فالتوازن بين + +415 +00:49:21,790 --> 00:49:28,730 +حقوق الله وحقوق النفس، وهذا الحديث سيأتي معنا كثيرا + +416 +00:49:28,730 --> 00:49:35,930 +وله قصة طويلة صحيحة عند البخاري وعند غيره، عندما جاء + +417 +00:49:35,930 --> 00:49:42,290 +ثلاثة رجال يسألون أزواج النبي عليه الصلاة والسلام + +418 +00:49:42,290 --> 00:49:46,470 +ورضي الله عنهم عن عبادات النبي عليه الصلاة والسلام + +419 +00:49:46,470 --> 00:49:54,310 +أي نعم، فلما أخبروا كأنهم تقالوها بمعنى أنهم عدوها + +420 +00:49:54,310 --> 00:49:59,490 +قليلة ثم قالوا وأينا مثل رسول الله لقد غفر له ما + +421 +00:49:59,490 --> 00:50:05,410 +تقدم و ما تأخر من ذنبه وما علموا أن هذا الدين يسر + +422 +00:50:05,410 --> 00:50:17,110 +و سماحة لا حرج فيه ولا تطرف فيه ولا غلو فيه فقال + +423 +00:50:17,110 --> 00:50:25,130 +أحدهم أما أنا فأعتزل النساء لا أتزوج أبدا وقال + +424 +00:50:25,130 --> 00:50:31,510 +الآخر أما أنا فأقوم الليلة لا أرقد أبدا وقال + +425 +00:50:31,510 --> 00:50:37,170 +الثالث أما أنا فأصوم النهار لا أفطر أبدا ظنوا أنهم + +426 +00:50:37,170 --> 00:50:42,770 +يفعلون الخير ولكن الرسول عليه الصلاة والسلام لما + +427 +00:50:42,770 --> 00:50:49,770 +سمع بهم عن فهمهم و أخبارهم أن هذا هو التطرف أو أن + +428 +00:50:49,770 --> 00:50:55,130 +هذا هو الغلو هذا لم يأتي به النبي عليه الصلاة + +429 +00:50:55,130 --> 00:51:00,450 +والسلام وسنأتي في الفصل الثاني إن شاء الله عند + +430 +00:51:00,450 --> 00:51:07,010 +الحديث عن خصائص العبادة أنه من خصائص العبادة اليسر + +431 +00:51:07,010 --> 00:51:12,070 +ورفع الحرج وثناؤه إلى آيات وإلى أمثلة ونماذج مثل + +432 +00:51:12,070 --> 00:51:16,710 +قول تعالى يريد الله بكم اليسر ولا يريد بكم العسر + +433 +00:51:16,710 --> 00:51:21,770 +ومثل قول تعالى فمن كان منكم مريضا أو على سفر فعدة + +434 +00:51:21,770 --> 00:51:28,160 +من أيام أخر وكذلك قصر الصلاة للمسافر وكذلك الجمع + +435 +00:51:28,160 --> 00:51:32,660 +في الخوف والمطر + +436 +00:51:32,660 --> 00:51:38,620 +نعم و ثناؤه المسح على الجوارب إلى غير ذلك من + +437 +00:51:38,620 --> 00:51:43,220 +الأمثلة التي تدل على سماحة هذا الدين ويُسر هذه + +438 +00:51:43,220 --> 00:51:49,030 +الشريعة فالنبي عليه السلام لم يعطهم الأوسمة ولم + +439 +00:51:49,030 --> 00:51:55,190 +يعلق الناشين على صدورهم بل قال أما والله إني + +440 +00:51:55,190 --> 00:52:02,030 +لأخشاكم لله وأتقاكم له ولكن أصوم وأفطر وأصلي و + +441 +00:52:02,030 --> 00:52:07,770 +أرقد وأتزوج النساء فمن رغب عن سنتي فليس مني صدق + +442 +00:52:07,770 --> 00:52:11,850 +رسول الله صلى الله عليه وسلم نتوقف إلى هنا إن شاء + +443 +00:52:11,850 --> 00:52:18,570 +الله ونكون في المحاضرة التالية على موعد مع الخاصية + +444 +00:52:18,570 --> 00:52:24,750 +الرابعة العمومية والعالمية من خصائص النظم الإسلامية + +445 +00:52:24,750 --> 00:52:29,510 +وصل اللهم على سيدنا محمد والسلام عليكم ورحمة الله + +446 +00:52:29,510 --> 00:52:30,470 +وبركاته diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/_H4hsoULCPk_raw.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/_H4hsoULCPk_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..11241364de9d80a7656f169498f6c244c95df770 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/_H4hsoULCPk_raw.srt @@ -0,0 +1,1784 @@ +1 +00:00:05,010 --> 00:00:07,470 +أعوذ بالله السمعي العلي من الشياطين الردي بسم الله + +2 +00:00:07,470 --> 00:00:14,150 +الرحمن الرحيم أعزائي الطلاب ما زلنا مع الفصل + +3 +00:00:14,150 --> 00:00:20,530 +التمهيدي من مساق النظم الإسلامية اتكلمنا في + +4 +00:00:20,530 --> 00:00:26,190 +المحاضرة السابقة عن المبحث الأول وهو بعنوان تعريف + +5 +00:00:26,190 --> 00:00:32,620 +النظم لغة وصطلاحاوتكلمنا عن المبحث الثاني وهو + +6 +00:00:32,620 --> 00:00:38,120 +بعنوان حاجة المجتمعات إلى النظم الإسلامية ونحن + +7 +00:00:38,120 --> 00:00:43,040 +اليوم على موعد ان شاء الله مع المبحث الثالث وهو من + +8 +00:00:43,040 --> 00:00:48,360 +أكبر مباحث الفصل التمهيد الأربعة وهو بعنوان خصائص + +9 +00:00:48,360 --> 00:00:54,460 +النظم الإسلامية وهي ثمانية بدء بالربانية ومرورا + +10 +00:00:54,460 --> 00:00:59,920 +بالثبات والمرونة والشمول والتوازنوالعموم و + +11 +00:00:59,920 --> 00:01:05,360 +العالمية و التكافل و الترابط و الواقعية و المثالية + +12 +00:01:05,360 --> 00:01:11,980 +و الأخلاق و ثامنا و أخيرا الجزاء الأخروي الخاصية + +13 +00:01:11,980 --> 00:01:21,220 +الأولى و هي أهم الخصائص بل هي أم الخصائص على و هي + +14 +00:01:21,220 --> 00:01:27,940 +الربانية و الربانية مشتقة من الرب تبارك وتعالى + +15 +00:01:28,460 --> 00:01:34,300 +فيقال ربانيون يُنسبون إلى الرب تبارك وتعالى + +16 +00:01:34,300 --> 00:01:43,440 +والربانية هنا نوعان ربانية المصدر وربانية الغاية + +17 +00:01:43,440 --> 00:01:51,600 +وهم مصطلحان لابد أن يُفرّق بينهما أما ربانية + +18 +00:01:51,600 --> 00:02:00,790 +المصدر فهو أن أصول أحكامهاوأسس تشريعتها مأخوذة من + +19 +00:02:00,790 --> 00:02:05,650 +كتاب الله عز و دل ومن سنة رسول الله صلى الله عليه + +20 +00:02:05,650 --> 00:02:12,550 +وسلم وهذا ما سبق ذكره عند الحديث عن الفرق بين + +21 +00:02:12,550 --> 00:02:18,310 +النظم عند المسلمين وعند غير المسلمين فالنظم عند + +22 +00:02:18,310 --> 00:02:23,810 +المسلمين مصدرها الله تبارك وتعالى ويتمثل ذلك في + +23 +00:02:23,810 --> 00:02:30,240 +كتابهالقرآن الكريم سبحانه وتعالى وكذلك في سنة نبيه + +24 +00:02:30,240 --> 00:02:35,120 +محمد صلى الله عليه وسلم عملا بقوله تعالى يا أيها + +25 +00:02:35,120 --> 00:02:39,820 +الذين آمنوا أطيعوا الله وأطيعوا الرسول أطيعوا الله + +26 +00:02:39,820 --> 00:02:46,140 +أي في كتابهوأطيع الرسولة أي في صناته صلى الله عليه + +27 +00:02:46,140 --> 00:02:53,160 +وسلم أما القوانين الوضعية البشرية الأدمية فهي من + +28 +00:02:53,160 --> 00:02:58,300 +وضع الناس أو كما أسلفنا في تعريف النظم عند غير + +29 +00:02:58,300 --> 00:03:02,960 +المسلمين أنها من وضع الشعوب ومن وضع المجتمعات أو + +30 +00:03:02,960 --> 00:03:13,570 +من وضع البرلمان المنتخب من الشعب ومعنى كونهاربانية + +31 +00:03:13,570 --> 00:03:20,850 +الغاية أن هدف هذه النظم الأولى والأسمى هو ربط + +32 +00:03:20,850 --> 00:03:28,010 +الناس بربهم سبحانه وتعالى في كل تصرف وفي كل فعل + +33 +00:03:28,010 --> 00:03:34,750 +يصدر عنهم بل في كل فكرة أو في كل خاطرة تراودهم وأن + +34 +00:03:34,750 --> 00:03:41,010 +يكون كل ذلك من أجل الله وطمعا في رضاه سبحانه + +35 +00:03:41,010 --> 00:03:50,450 +وتعالىنأتي الآن إلى جملة من النتائج والأثار التي + +36 +00:03:50,450 --> 00:03:58,410 +تنبثق عن خاصية الربانية فنقول ما هي النتائج + +37 +00:03:58,410 --> 00:04:09,440 +والثمار أو الأثارالتي تنجم أو تنبثق عن خاصية + +38 +00:04:09,440 --> 00:04:15,240 +الربانية أول هذه النتائج والأثار خلوة هذه النظم من + +39 +00:04:15,240 --> 00:04:21,860 +معاني النقص والجهل والهوى والظلم لماذا؟ لأن هذه + +40 +00:04:21,860 --> 00:04:29,570 +النظمهي من عند الله وتعالى الله عن هذه النقاس فإن + +41 +00:04:29,570 --> 00:04:37,370 +النقص والجهل والهوى والظلم من صفات البشر من صفات + +42 +00:04:37,370 --> 00:04:42,990 +المخلوقين وليست من صفات الله تبارك وتعالى وصدق + +43 +00:04:42,990 --> 00:04:48,550 +الله ربنا العظيم ليس كمثله شيء وهو السميع العليم + +44 +00:04:48,550 --> 00:04:55,100 +سبحانه وتعالى ثانيامن النتائج والأثار التي تنبثق + +45 +00:04:55,100 --> 00:05:01,700 +عن خاصية الربانية الثقة بهذه النظم والتسليم بصحة + +46 +00:05:01,700 --> 00:05:07,460 +ما جاء فيها وصلاحيتها ذلك لأنها أيضا من عند الله + +47 +00:05:07,460 --> 00:05:14,840 +سبحانه وتعالى الذي خلق البشر الله الذي خلق البشر + +48 +00:05:14,840 --> 00:05:24,520 +يعلم ما يصلحهموما ينفعهم في دنياهم واخراهم كما قال + +49 +00:05:24,520 --> 00:05:30,960 +الله تبارك وتعالى فإما يأتينكم مني هدا فمن اتبع + +50 +00:05:30,960 --> 00:05:36,460 +هدايا فلا يضل ولا يشقى ومن أعرض عن ذكري فإن له + +51 +00:05:36,460 --> 00:05:42,800 +معيشة ضنكة ونحشره يوم القيامة أعمىقال رب لما + +52 +00:05:42,800 --> 00:05:47,340 +حشرتني أعمى وقد كنت بصيرة قال كذلك أتتك آياتنا + +53 +00:05:47,340 --> 00:05:55,420 +فنسيتها وكذلك اليوم تنسى فالجزاء من جنس العملوكما + +54 +00:05:55,420 --> 00:06:04,280 +تدين تدان والنتائج وفق المقدمات من خير ومن شر فمن + +55 +00:06:04,280 --> 00:06:10,640 +يعمل مسقالة ذرة خير يره ومن يعمل مسقالة ذرة شر يره + +56 +00:06:10,640 --> 00:06:16,920 +ولذلك قالوا من قديم الزمان كل صانع أدرى بصناعته + +57 +00:06:16,920 --> 00:06:26,470 +فمن صنع جهازا كتب معاهما يُطلَق عليه في هذه الأيام + +58 +00:06:26,470 --> 00:06:35,250 +بالـ Catalogue من أجل أن ينتفع به الخبير فإذا ما + +59 +00:06:35,250 --> 00:06:42,190 +خالف هذا الخبير تعليمات الصانع أو تعليمات ال + +60 +00:06:42,190 --> 00:06:49,950 +Catalogue فإن الآلة تبقى فاسدة ولا تصلح أبدًا ولله + +61 +00:06:49,950 --> 00:06:56,030 +المثل الأعلى فالإنسانصنعة الله تبارك وتعالى صنعة + +62 +00:06:56,030 --> 00:07:00,790 +الله ومن أحسن من الله صنعة صبغة الله ومن أحسن من + +63 +00:07:00,790 --> 00:07:06,810 +الله صبغة الإنسان بنيان الرب سبحانه وتعالى خلقه + +64 +00:07:06,810 --> 00:07:13,910 +الله وهو أدرا بما يصلحه وبما يفسده فأنزل له هذه + +65 +00:07:13,910 --> 00:07:21,430 +النظم أو تلكالتشريعات من حلال و من حرام من أجل + +66 +00:07:21,430 --> 00:07:28,190 +خيره في الدنيا و الآخرة و ذلك هو الفوز العظيم أما + +67 +00:07:28,190 --> 00:07:34,770 +ثالثا من النتائج و الأثار التي تنبثق عن خاصية + +68 +00:07:35,720 --> 00:07:41,960 +الربانية أنها تتمتع بقدر كبير من الهيبة والتقديس + +69 +00:07:41,960 --> 00:07:48,280 +والحب والاحترام في نفوس المؤمنين لأن الإيمان بالله + +70 +00:07:48,280 --> 00:07:55,580 +لا يكون بالقوة ولا يكون بالسلطانولا يكونوا + +71 +00:07:55,580 --> 00:08:03,800 +بالإكراه إنما يكونوا بالحب وبالمودة + +72 +00:08:03,800 --> 00:08:09,520 +كما سلف أنت لونه في المحاضرة السابقة كما قال الله + +73 +00:08:09,520 --> 00:08:14,080 +تبارك وتعالى لا إكراه في الدين قد تبين الرشد من + +74 +00:08:14,080 --> 00:08:19,260 +الغيب أفأنت تكره الناس حتى يكونوا مؤمنين فإن + +75 +00:08:19,260 --> 00:08:27,300 +الإيمان إذا كان عن خشية من حاكمأو من سلطان صرعان + +76 +00:08:27,300 --> 00:08:33,880 +ما يرتد صاحبهم أما الإيمان بالله والتسليم بأحكام + +77 +00:08:33,880 --> 00:08:41,240 +الله إذا كان عن حب وعن رضا وعن عقيدة فإنه يخالط + +78 +00:08:41,240 --> 00:08:52,120 +بشاشة القلوب فيثبت ويفتكر نعم أما رابعاو هذه من + +79 +00:08:52,120 --> 00:09:02,440 +الثمار المهمة الناجمة عن خاصية الربانية أنها تدفع + +80 +00:09:02,440 --> 00:09:08,760 +المؤمنين إلى المصارعة في التوبة باستشعار الندم عند + +81 +00:09:08,760 --> 00:09:16,960 +اختراف ما يخالف أحكامها فالإنسان ليس ملكا يمشي على + +82 +00:09:16,960 --> 00:09:24,800 +الأرضوالإنسان ليس نبيا معصوما من الخطأ والزلل، + +83 +00:09:24,800 --> 00:09:34,710 +الإنسان فيه من الملائكية وفيه من المعصيتهفبالطاعة + +84 +00:09:34,710 --> 00:09:40,390 +يكون ملكا يمشي على الأرض بل أفضل عند الله من + +85 +00:09:40,390 --> 00:09:46,890 +الملائكة كما أسجد الله الملائكة لآدم عليه السلام + +86 +00:09:46,890 --> 00:09:53,030 +وإذ قلنا للملائكة أسجدوا لآدم فسجدوا إلا إبليس أبى + +87 +00:09:53,030 --> 00:10:01,250 +واستكبر وكان من الكافرين وبالمعصية يهبط الإنسان من + +88 +00:10:01,250 --> 00:10:09,910 +سمائهومن عليائه إلى الأرض السابعة يتمرغ في الأوحال + +89 +00:10:09,910 --> 00:10:19,990 +والمستنقعات مع الأبالسة والشياطين بل أشد منهم + +90 +00:10:19,990 --> 00:10:25,870 +معصية لله عز وجل كما قال الله تبارك وتعالى شياطين + +91 +00:10:25,870 --> 00:10:33,630 +الإنس والجنيوحي بعضهم إلى بعض زخرف القول غرورة + +92 +00:10:33,630 --> 00:10:38,970 +فهنا قدم الله شياطين الإنس على شياطين الجن + +93 +00:10:38,970 --> 00:10:42,270 +لخطورتهم + +94 +00:10:42,270 --> 00:10:52,060 +بالإفساد نعم بل إن شياطين الجن قد تتعلموامن شياطين + +95 +00:10:52,060 --> 00:10:57,700 +الإنس كما قال الشاعر قديما وكنت مرأة من جندي إبليس + +96 +00:10:57,700 --> 00:11:03,920 +فارتقى بي الحال حتى صار إبليس من جندي فلو مات قبلي + +97 +00:11:03,920 --> 00:11:11,580 +كنت أحصن بعده طرائق فسخ ليس يحصنها بعدي أعود إلى + +98 +00:11:11,580 --> 00:11:20,720 +ذي بدء فأقول إن الإنسان معرض للخطألأنه ليس ملكا + +99 +00:11:20,720 --> 00:11:24,040 +مفطورا + +100 +00:11:24,040 --> 00:11:31,680 +على اضطاعته وفي نفس الوقت ليس نبيا معصوما من الزمن + +101 +00:11:31,680 --> 00:11:41,560 +فماذا يفعل عليه أن يرجع إلى الله وأن يأوب إلى الله + +102 +00:11:41,560 --> 00:11:51,430 +وأن يتوب إليه سبحانه وتعالىولا ييأس ولا يقنط لأن + +103 +00:11:51,430 --> 00:11:57,270 +اليأس والقنوط من صفات الكافرين كما في قصة يوسف على + +104 +00:11:57,270 --> 00:12:02,120 +لسان يعقوب عليه السلاميا بني يذهبوا فتحسسوا من + +105 +00:12:02,120 --> 00:12:07,500 +يوسف وأخيه ولا تيأسوا من روح الله إنه لا ييأس من + +106 +00:12:07,500 --> 00:12:13,660 +روح الله إلا القوم الكافرون فاليأس والإيمان خطان + +107 +00:12:13,660 --> 00:12:20,780 +متوازيان لا يلتقيان ولا يجتمعان فما على الإنسان + +108 +00:12:20,780 --> 00:12:27,820 +المسلم إذا مرتكب معصية أو فحجة أو خطيئة في حال + +109 +00:12:27,820 --> 00:12:37,670 +غفلةأو نسيان عليه أن يتوب إلى الله فإن أبواب + +110 +00:12:37,670 --> 00:12:46,390 +السماء مفتحة وإن أبواب التوبة لا تغلق أبدا وقد قال + +111 +00:12:46,390 --> 00:12:51,430 +الله تبارك وتعالى وهذه آية في صورة الظمركان رسول + +112 +00:12:51,430 --> 00:12:56,730 +الله يحبها صلى الله عليه وسلم لأنها تفتح أبواب + +113 +00:12:56,730 --> 00:13:02,710 +التوبة إلى العصات قل يا عبادي الذين أصرفوا على + +114 +00:13:02,710 --> 00:13:08,830 +أنفسهم لا تقنطوا من رحمة الله إن الله يغفر الذنوب + +115 +00:13:08,830 --> 00:13:16,590 +جميعا إنه هو الغفور الرحيم سبحانه وتعالى وإن سألت + +116 +00:13:16,590 --> 00:13:25,870 +عن شروط التوبةفإن شروط التوبة النصوح كما قال الله + +117 +00:13:25,870 --> 00:13:30,290 +تعالى يا أيها الذين آمنوا توبوا إلى الله توبة + +118 +00:13:30,290 --> 00:13:37,670 +نصوحا قلت هي أربعة ثلاثة إذا كان الذنب بين العبد + +119 +00:13:37,670 --> 00:13:42,070 +وربه وواحدة + +120 +00:13:42,820 --> 00:13:47,960 +وهي الرابعة إذا كان الذنب بين الإنسان و أخيه + +121 +00:13:47,960 --> 00:13:54,640 +الإنسان أما الثلاثة الأول فأولا الإقلاع عن المعصية + +122 +00:13:54,640 --> 00:14:07,920 +و ثانيا الندم و الندم في القلب و ثالثا العزم على + +123 +00:14:07,920 --> 00:14:15,030 +عدم العودة إلى المعصيةوإلا كان استهتارا بالله + +124 +00:14:15,030 --> 00:14:21,570 +سبحانه وتعالى إذا ما عصى و تاب ثم عاد إلى المعصية + +125 +00:14:21,570 --> 00:14:32,070 +و هكذا و رابعا و هذه كما قالت العرب ثالثة الأثافر + +126 +00:14:32,070 --> 00:14:41,190 +لأن الناس قد يغفلون عنها إذا كان الذنبأو إذا كان + +127 +00:14:41,190 --> 00:14:48,230 +الحق بين المسلم وأخيه المسلم فهذه لا يغفرها الله + +128 +00:14:48,230 --> 00:14:57,450 +سبحانه وتعالى لابد أن تعود الحقوق إلى أصحابها وأن + +129 +00:14:57,450 --> 00:15:06,290 +تؤدى الأمانات إلى أهلها وإلا كان يوم القيامة وإذا + +130 +00:15:06,290 --> 00:15:15,480 +كان يوم القيامة فلا دراهمةولا دنانير ولا شواكلة + +131 +00:15:15,480 --> 00:15:25,820 +بلغة العصر إنما المقاصة يوم القيامة والحساب يكون + +132 +00:15:25,820 --> 00:15:32,560 +بالحسنات والسيئات كما جاء في الصنة النبوية الشريفة + +133 +00:15:32,560 --> 00:15:38,100 +أن الله يجمع الظالم والمظلوم يوم القيامةفيقول الله + +134 +00:15:38,100 --> 00:15:45,640 +تعالى للظالم أعطي أخاك حقه فيقول يا رب ما معي + +135 +00:15:45,640 --> 00:15:51,920 +دراهم ما معي دنانير أو شواكل فيقول الله تعالى + +136 +00:15:51,920 --> 00:15:59,160 +أعطيه من حسناتك وما أحوج العبد يوم القيامةما أحوجك + +137 +00:15:59,160 --> 00:16:06,760 +يا مسكين إلى حسنات تسقل بها موازينك يوم القيامة + +138 +00:16:06,760 --> 00:16:15,340 +فيأخذ من حسناتي الظالم و تغطى للمظلوم فإذا ما فنت + +139 +00:16:15,340 --> 00:16:21,880 +حسنات الظالم أخذ من سيئات المظلوم فطرحت على الظالم + +140 +00:16:21,880 --> 00:16:34,130 +فطرح في النار وبئس القرارقلت هذه الثمرة الرابعة + +141 +00:16:34,130 --> 00:16:39,070 +من الثمار أو النتائج و الآثار الناجمة + +142 +00:16:40,640 --> 00:16:50,100 +عن خاصية الربانية من اعظم هذه الخصائص انك لا تقنط + +143 +00:16:50,100 --> 00:16:55,200 +من رحمة الله فاذا ما شعرت بمعصية او خطيئة او ذنب + +144 +00:16:55,200 --> 00:17:00,270 +او تقصير ما عليك الا ان تهرعإلى الله تائبًا + +145 +00:17:00,270 --> 00:17:08,210 +ونادمًا وتذرف الدموع ساخنة على الوجنات فالله غفور + +146 +00:17:08,210 --> 00:17:14,910 +والله عفو والله رحيم يقبل التوبة عن عباده ويعفو عن + +147 +00:17:14,910 --> 00:17:22,810 +كثير سبحانه وتعالى أما خامسًا فمن النتائج والأثار + +148 +00:17:22,810 --> 00:17:27,790 +التي تنبثق عن خاصية الربانيةو كما قلنا هي أم + +149 +00:17:27,790 --> 00:17:35,690 +الخصائص أن الجميع في كنف هذه النظم سواء و هذه ان + +150 +00:17:35,690 --> 00:17:40,670 +شاء الله سنأتي اليها بشيء من التفصيل عند الوصول + +151 +00:17:40,670 --> 00:17:47,610 +إلى الفصل السادس عند الحديث عن قواعد النظام + +152 +00:17:47,610 --> 00:17:53,460 +السياسي الأربعة بدءا بالحاكميةومرورا بالعدل + +153 +00:17:53,460 --> 00:18:00,780 +والمثاوات والشورى والطاعة سنتكلم عن هذا طويلاعندما + +154 +00:18:00,780 --> 00:18:09,780 +نصل الى الخاصية الثانية نعم او القاعدة الثانية من + +155 +00:18:09,780 --> 00:18:14,240 +قواعد النظام الإسلامي الا وهي العدل والمساواة + +156 +00:18:14,240 --> 00:18:20,540 +فالناس في نظر الشريعة الإسلامية سواسية كأسنان + +157 +00:18:20,540 --> 00:18:29,700 +المشتلا فرق بين كبير وصغير أو ذكر وأنسة أو أبيضة + +158 +00:18:29,700 --> 00:18:36,600 +وأسودة أو أحمر وأصفر بل لا فرق بين حاكم ومحكوم أو + +159 +00:18:36,600 --> 00:18:45,660 +رئيس ومرؤوس أو قوي وضعيف أو غني وفقير فالميزان + +160 +00:18:45,660 --> 00:18:55,030 +الثابت الذي نحتكم إليهبل شعارنا الخالد إلى يوم + +161 +00:18:55,030 --> 00:19:01,210 +القيامة إلى أن يرث الله الأرض ومن عليها قوله تبارك + +162 +00:19:01,210 --> 00:19:06,030 +وتعالى في صورة الحجرات وسنأتي إلى هذه الآية إن شاء + +163 +00:19:06,030 --> 00:19:11,090 +الله يا أيها الناس إن خلقناكم من ذكر وأنثى + +164 +00:19:11,090 --> 00:19:16,430 +وجعلناكم شعوب وقبائل لتعرفوا إن أكرمكم عند الله + +165 +00:19:16,430 --> 00:19:23,460 +أتقاكمإن الله عليم خبير صدق الله العظيم أما ثادثا + +166 +00:19:23,460 --> 00:19:33,180 +وقد سبق أن قلت إن خصائص النظم الإسلامية التي ستأتي + +167 +00:19:33,180 --> 00:19:43,120 +بعد قليل من الثبات والمرونة ومن الشمول والتوازن + +168 +00:19:43,120 --> 00:19:51,320 +ومن التكامل والترابطومن الواقعية والمثالية + +169 +00:19:51,320 --> 00:20:01,160 +والعالمية والجزاء الأخروي كذلك انما هي تنبثق عن + +170 +00:20:01,160 --> 00:20:08,960 +خاصية الربانية او هيثمار او نتائجه متولدة او + +171 +00:20:08,960 --> 00:20:17,140 +متفرعة عن خاصية الربانية ولذا تعجلت فقلت ان خاصية + +172 +00:20:17,140 --> 00:20:26,020 +الربانية هي أم الخصائص بحق نعم الآن بعد ان انتهينا + +173 +00:20:26,020 --> 00:20:32,370 +من الخاصية الكبرىوهي أم الخصائص نأتي إلى الخاصية + +174 +00:20:32,370 --> 00:20:37,630 +الثانية من خصائص النظم الإسلامية على وهي الثبات + +175 +00:20:37,630 --> 00:20:48,570 +والمرونة وهنا نقف قليلا لأن البعض ظاهرا وللوهلة + +176 +00:20:48,570 --> 00:20:54,280 +الأولى قد يظن أن ثمة تناقضابين الثبات و المرونة + +177 +00:20:54,280 --> 00:20:58,840 +فيقول كيف تتصف النظم الإسلامية أو الشريعة + +178 +00:20:58,840 --> 00:21:06,400 +الإسلامية مرة بالثبات و مرة بالمرونة فنقول لا + +179 +00:21:06,400 --> 00:21:15,200 +تناقض البتة لأن الثبات في أمور و لأن المرونة في + +180 +00:21:15,200 --> 00:21:25,990 +أمور أما الثبات فإنما يكونفي القواعد والأسس + +181 +00:21:25,990 --> 00:21:36,350 +والأصول أما المرونة فإنما تكون في الوسائل والفروق + +182 +00:21:36,350 --> 00:21:47,330 +أو كما سيأتي بعد قليل بالأعراف والعادات والتقاليد + +183 +00:21:47,330 --> 00:21:49,370 +نعم + +184 +00:21:53,780 --> 00:21:58,580 +لو أردنا أن نضرب مثلا للقواعد + +185 +00:21:58,580 --> 00:22:05,760 +والأصول التي لا تتغير ولا تتبدل إلى يوم القيامة + +186 +00:22:05,760 --> 00:22:14,840 +أرى أن نقتصر على ثلاثة وهذا ليس في الكتاب ولكن من + +187 +00:22:14,840 --> 00:22:20,240 +أجل أن يتضح الموضوع نقول السبات إنما يكون أولا في + +188 +00:22:20,240 --> 00:22:26,420 +العقيدة فالعقيدةأو التي عبّر عنها القرآن الكريم + +189 +00:22:26,420 --> 00:22:32,580 +الإيمان بالله و برسوله و بالكتب و باليوم الآخر و + +190 +00:22:32,580 --> 00:22:37,600 +القضاء و القدر خيره و شره من الله تبارك وتعالى + +191 +00:22:37,600 --> 00:22:46,460 +فهذه أركان الإيمان أو أصول العقيدة ثابتة لا تتغير + +192 +00:22:46,460 --> 00:22:54,140 +ولا تتبدلإلى يوم القيامة إلى أن يرث الله الأرض ومن + +193 +00:22:54,140 --> 00:23:06,480 +عليها وكذلك الحديث عن نظام الأسرة كذلك نظام الأسرة + +194 +00:23:06,480 --> 00:23:17,220 +لا يتغير ولا يتبدل بمعنى أن المحرماتهن المحرمات + +195 +00:23:17,220 --> 00:23:26,720 +إلى يوم القيامته فلن يأتي يوم مثلا تحل فيه الأم أو + +196 +00:23:26,720 --> 00:23:33,780 +الجدته أو البنته أو الأخته فهؤلاء من المحرمات + +197 +00:23:33,780 --> 00:23:44,490 +مؤبدا إلى يوم القيامته نعم لكن هناك محرماتمؤقتا + +198 +00:23:44,490 --> 00:23:51,470 +فالمحرمات المؤقتة مثل أخت الزوجة مثل عامة الزوجة + +199 +00:23:51,470 --> 00:23:59,070 +مثل خالة الزوجة لا يجمع بينهما البتة كما قال الله + +200 +00:23:59,070 --> 00:24:03,830 +وأن تجمعوا بين الأختين فلا يصح أن يجمع بين الأختين + +201 +00:24:03,830 --> 00:24:12,370 +وكما جاء في الصنة لا يجمع بين البنت وعمتهاأو بين + +202 +00:24:12,370 --> 00:24:20,650 +البنت وخالتها لأنكم إن فعلتم ذلك فقد قطعتم أرحمكم + +203 +00:24:20,650 --> 00:24:27,110 +من تصل المرأة إذا لم تصل أختها وخالتها وعمتها + +204 +00:24:27,110 --> 00:24:34,370 +وجمعتهم في بيت واحد لكن إذا ماتت الأخت فللزوج أن + +205 +00:24:34,370 --> 00:24:41,070 +يتزوج أختها حتى لو طلقها في حياة أختها ولم تعد + +206 +00:24:41,990 --> 00:24:48,050 +الاخته على ذمته له ان يتزوج اختها المهم ان لا يجمع + +207 +00:24:48,050 --> 00:24:54,990 +بين الأختين و كذلك لو ماتت البنت فتزوج عامتها او + +208 +00:24:54,990 --> 00:25:04,610 +تزوج خالتها فله ذلك ايضا فهؤلاء من المحرمات مؤكدا + +209 +00:25:05,370 --> 00:25:10,810 +وهذا هو الحكم إلى يوم القيامة فهذا هو السبب أما + +210 +00:25:10,810 --> 00:25:15,990 +ثالثا وأردت الإختصار فهو الحدود الحدود أيضا من + +211 +00:25:15,990 --> 00:25:21,630 +الأحكام الثابتة التي لا يعتريها تغيير ولا تبديل + +212 +00:25:21,630 --> 00:25:27,610 +قلت هذا من عندي وليس من الكتاب فحد الزنا مثلا إذا + +213 +00:25:27,610 --> 00:25:35,010 +كان الزني محصنا يعني متزوداحتى و لو طلق .. المهم + +214 +00:25:35,010 --> 00:25:42,330 +أنه سبق له أن تزوج و دخل بأهله و زنى فإن حكمه + +215 +00:25:42,330 --> 00:25:48,010 +الرجم إلى يوم القيامة و هذا ثابت في الصنة الصحيحة + +216 +00:25:48,010 --> 00:25:54,330 +عند مسلم عن عمرو بن الخطابنزلت الآية تلونها و + +217 +00:25:54,330 --> 00:25:59,710 +لكنها منسوخة التلاوة باقية الحكم الشيخ والشيخة إذا + +218 +00:25:59,710 --> 00:26:06,750 +زنيا فارجموهم البتة نكالا من الله والله عزيز حكيم + +219 +00:26:06,750 --> 00:26:11,810 +حتى قال عمر أخش أن يأتي يوم يقول الناس لا نجد + +220 +00:26:11,810 --> 00:26:16,710 +الرجمة في كتاب اللهوقد رجمنا وقد جيأ في الصناة + +221 +00:26:16,710 --> 00:26:21,070 +الصحيحة عند البخاري وعند مسلم رجموا ماعز و + +222 +00:26:21,070 --> 00:26:28,150 +الغامدية وقال اغضوا يا أنيس الأمرأة هذا فانعترفت + +223 +00:26:28,150 --> 00:26:36,590 +فارجمها وأما الجلد فهو لذان العذببمعنى غير المحصن + +224 +00:26:36,590 --> 00:26:42,890 +الذي لم يتزود بعد وهذا ثابت في صورة النور الزانية + +225 +00:26:42,890 --> 00:26:50,090 +والزاني فاجلدوا كل واحد منهما مائة جلدة نعم وكذلك + +226 +00:26:50,090 --> 00:26:58,330 +حدهالسارقة هو قطع اليد وهذا ثابت أيضا في القرآن + +227 +00:26:58,330 --> 00:27:04,090 +الكريم في صورة المادة السارق والسارقة فقطعوا + +228 +00:27:04,090 --> 00:27:10,030 +أيديهما جزاء بما كسب نكلا من الله والله عزيز حكيم + +229 +00:27:10,030 --> 00:27:15,880 +وكذلك الخمر وقد أجمع المسلمون كما سيأتيفي المصدر + +230 +00:27:15,880 --> 00:27:20,600 +الثالث من مصادر النظم الإسلامية بعد القرآن والسنة + +231 +00:27:20,600 --> 00:27:25,580 +يأتي الإجماع أن المسلمين قد أجمعوا في عهد عمر بن + +232 +00:27:25,580 --> 00:27:31,640 +الخطاب رضي الله عنه على جلد شارب الخمر سمانين جلدة + +233 +00:27:31,640 --> 00:27:38,360 +وهكذا قاطعوا الطريق كما في صورة المائدة إنما جزاء + +234 +00:27:38,360 --> 00:27:43,490 +الذين يحاربون الله ورسوله ويصعون أن يقتلواأو + +235 +00:27:43,490 --> 00:27:47,770 +يصلبوا أو تقطع أيديهم و أرجولهم من خلاف أو ينفى + +236 +00:27:47,770 --> 00:27:53,550 +مرض إلى آخر الآية إذا قلت إن السبات لا يكون مطلقا + +237 +00:27:53,550 --> 00:27:59,190 +في كل شيء إنما يكون السبات في أمور و قد ذكرت منها + +238 +00:27:59,190 --> 00:28:05,530 +ثلاثة أولا العقيدة و ثانيا النظام الاجتماعي يعني + +239 +00:28:05,530 --> 00:28:12,790 +المحرمات من النساء أبدا و كذلكالمحرمات مؤقتا و + +240 +00:28:12,790 --> 00:28:19,270 +ثالثا الحدود فهي ثابتة أما بالنسبة إلى المرونة فإن + +241 +00:28:19,270 --> 00:28:27,470 +المرونة انما تكون في الوسائل و الفروع وهذه تتغير + +242 +00:28:27,470 --> 00:28:38,310 +وفق الأعراف و التقاليد و العداد حتى قيل إن الأحكام + +243 +00:28:38,310 --> 00:28:49,340 +تتغيروازمانا و مكانا و أشخاصا هذا هو معنى المرونة + +244 +00:28:49,340 --> 00:28:54,380 +فالفتوى في زمن قد لا تكون هي نفسها في زمن آخر + +245 +00:28:54,380 --> 00:29:00,480 +والفتوى في مكان قد لا تكون هي في مكان آخر وقد + +246 +00:29:00,480 --> 00:29:06,630 +تختلف الفتوى من شخص إلى شخص آخرو هذا كله ليس في + +247 +00:29:06,630 --> 00:29:11,970 +الكتاب ولكن يحتاج إلى شيء من التوضيح لطلابنا + +248 +00:29:11,970 --> 00:29:21,750 +الأعزاء فقد ورد أن رجلا سأل ابن عباس هل القاتل + +249 +00:29:21,750 --> 00:29:31,720 +عمدا توبة فقال له لافجاءه بعده شخص آخر و سأل نفس + +250 +00:29:31,720 --> 00:29:36,540 +السؤال يا ابن عباس يا ابن عم رسول الله صلى الله + +251 +00:29:36,540 --> 00:29:42,740 +عليه وسلم هل القاتل عمدا توبة؟ قال نعم فعجب القوم + +252 +00:29:42,740 --> 00:29:49,780 +قالوا يا حبر هذه الأمة يا ابن عم رسول الله سأل + +253 +00:29:49,780 --> 00:29:58,670 +شخصان سؤالا واحدا هل القاتل عمدا توبة؟فقلت للأول + +254 +00:29:58,670 --> 00:30:05,310 +لا و قلت للأول نعم فقال أما الأول قلت له لا لأنه + +255 +00:30:05,310 --> 00:30:12,730 +أراد أن يقتل أما رأيتم انتفاخ أوداده و إحمر أرى + +256 +00:30:12,730 --> 00:30:20,230 +عينيه ولذلك قالوا لابد للمفته أن يكون على علم بحال + +257 +00:30:20,230 --> 00:30:29,440 +المستفتي نعمأما الثاني فأراد أن يتفكّى والرأي + +258 +00:30:29,440 --> 00:30:34,800 +الراجح في هذه المثلةوالذي عليه أكثر العلماء أن + +259 +00:30:34,800 --> 00:30:42,000 +للقاتل عمدا توبة بأدلة من الكتاب ومن الصنة نقولها + +260 +00:30:42,000 --> 00:30:47,260 +باختصار منها قوله تبارك وتعالى إن الله لا يغفر أي + +261 +00:30:47,260 --> 00:30:54,500 +يشرك به ويغفر ما دون ذلك لمن يشاء وفي وصف عباد + +262 +00:30:54,500 --> 00:30:58,600 +الرحمن في صورة الفرقان والذين لا يدعون مع الله + +263 +00:30:58,600 --> 00:31:04,320 +إلها آخرولا يقتلون النفس التي حرم الله إلا بالحق + +264 +00:31:04,320 --> 00:31:10,180 +ولا يذنون ومن يفعل ذلك يلقى أثامة يضاعف له العذاب + +265 +00:31:10,180 --> 00:31:16,560 +يوم القيامة ويخلط فيه مهانة إلا من تاب و آمن وعمل + +266 +00:31:16,560 --> 00:31:22,200 +عملا صالحة فأولئك يبدل الله سيادهم حسنات وكان الله + +267 +00:31:22,200 --> 00:31:26,360 +غفورا رحيما والآية التي تلونها في سورة الظمر قل يا + +268 +00:31:26,360 --> 00:31:30,340 +عبادي الذين أسرفوا على أنفسهملا تقنطوا من رحمة + +269 +00:31:30,340 --> 00:31:34,600 +الله إن الله يغفر الذنوب جميعا إنه هو الغفور + +270 +00:31:34,600 --> 00:31:41,260 +الرحيم نعم آيات كثيرة تفتح أبواب التوبة صدق الله + +271 +00:31:41,260 --> 00:31:47,860 +العظيم ومن الأحاديث الكثيرة نختصر على حديث صحيح + +272 +00:31:47,860 --> 00:31:54,400 +عند مسلم عن بني إسرائيل الذي قتل تسعة وتسعين نفسا + +273 +00:31:55,280 --> 00:32:04,760 +ثم قتل الراهبة المئة ثم سأل العالم الفقيه ولذلك + +274 +00:32:04,760 --> 00:32:12,640 +قيل كما في الحديث النبوي الشريف لفقيه واحد أشد على + +275 +00:32:12,640 --> 00:32:20,640 +الشيطان من ألف عابد نعم قال له ومن يحول بينك وبين + +276 +00:32:20,640 --> 00:32:27,570 +الله تب إلى اللهنعم فإن الله يغفر الذنوب جميعا و + +277 +00:32:27,570 --> 00:32:33,850 +تاب إلى الله و صلح حاله و حسنت توبته و غفر الله له + +278 +00:32:33,850 --> 00:32:41,390 +و أدخله الجنة رأيت كيف تغيرت الفتوى من شخص إلى شخص + +279 +00:32:41,390 --> 00:32:50,540 +و قد سأل نفس السؤال و كذلك من مكانإلى مكان وفتع + +280 +00:32:50,540 --> 00:33:00,700 +التقاليد والأعراف والعادات فقد جاء شخص إلى الإمام + +281 +00:33:00,700 --> 00:33:07,920 +مالك ولا يفتع ومالك في المدينة مفت المدينة في عصره + +282 +00:33:07,920 --> 00:33:18,780 +رضي الله عنه وسأله سؤالا يا إمام قلت لزوجيأنت طالق + +283 +00:33:18,780 --> 00:33:27,320 +إن أكلت سمكا فلو أكلت لحما هل تطلق زوجتي فقال له + +284 +00:33:27,320 --> 00:33:31,720 +الإمام مالك نعم قال هل من دليل من القرآن قال نعم + +285 +00:33:32,290 --> 00:33:37,970 +قال إن الله سم السمكة في القرآن الكريم لحما طريا + +286 +00:33:37,970 --> 00:33:44,490 +نعم فنحن كما ذكر الله تستخرجون حلية تلبسونها + +287 +00:33:44,490 --> 00:33:50,690 +وتأكلون لحما طريا فاللحم الطري هو السمك في القرآن + +288 +00:33:50,690 --> 00:33:56,490 +الكريم إذا الإمام مالك أفتى له بطلاق زوجه و أهله + +289 +00:33:56,490 --> 00:34:03,800 +لأن الله سم السمكة لحما طرياولكن هذا يختلف في بلد + +290 +00:34:03,800 --> 00:34:11,400 +آخر ولعل الرجل كان يحب زوجته ولا يريد طلاقها + +291 +00:34:11,400 --> 00:34:19,050 +فانقطع صهوة جوادهحتى وصل إلى بغداد إلى الكوفة + +292 +00:34:19,050 --> 00:34:26,610 +والبصرة بلد العلم والعلماء حيث الإمام أبو حنيفة + +293 +00:34:26,610 --> 00:34:31,850 +وأبو حنيفة أن عمار بن ثابت هو شيخ الأئمة قال له يا + +294 +00:34:31,850 --> 00:34:38,390 +أبو حنيفة قلت لزوجي أنت طالق إن أكلت سمكة فلو أكلت + +295 +00:34:38,390 --> 00:34:44,010 +لحمة هل تطلق زوجتي قال له لاقال إن الإمام مالكا + +296 +00:34:44,010 --> 00:34:49,170 +أفتاني من القرآن فأين هذا في القرآن قرأ رأيت لو أن + +297 +00:34:49,170 --> 00:34:55,750 +رجلا قال لزوجه أنت طالق لو جلست على بساطة فلو جلس + +298 +00:34:55,750 --> 00:35:01,330 +على الأرضهل تطلق زوجه؟ قال لأ قال فإن الله يقول + +299 +00:35:01,330 --> 00:35:08,950 +والأرض بساطة إذا المرونة إنما تكون في الفروع + +300 +00:35:08,950 --> 00:35:15,620 +والوسائل أو كما قال هنا في الكتابفي الأعراف و + +301 +00:35:15,620 --> 00:35:23,080 +العادات المنتشرة بل في البيئات و الظروف المتغيرة + +302 +00:35:23,080 --> 00:35:31,080 +فنحن في غزة مثلا لو قال أبو لابنه اشتري لنا لحمة + +303 +00:35:31,080 --> 00:35:36,880 +لا اشتري له سمكةو لا يشتري له فراخة على الرغم أن + +304 +00:35:36,880 --> 00:35:43,260 +السمك لحم و أن الفراخ لحم ولكن يشتري له لحمة لحمة + +305 +00:35:43,260 --> 00:35:49,340 +عجل أو لحمة خروف مثلا و لذلك من قال هنا في قطاع + +306 +00:35:49,340 --> 00:35:55,910 +غزة لزوجه أنت طالق إن أكلتهسمكا فلو أكل لحما + +307 +00:35:55,910 --> 00:36:02,870 +لاتطلق زوجته وهكذا تتغير الفتوى بتغير الزمان + +308 +00:36:02,870 --> 00:36:10,330 +والمكان وحتى الأشخاص ومن أراد أن يرجع فليرجع الى + +309 +00:36:10,330 --> 00:36:18,850 +مصنفات العلامة ابن قيم الجوزية وعلى رأسها الكتاب + +310 +00:36:18,850 --> 00:36:26,430 +العظيم إعلام الموكعينعن رب العالمين نعم و قالوا + +311 +00:36:26,430 --> 00:36:33,520 +أعلام الموقعينعن رب العالمين اعلام جمع علم والذي + +312 +00:36:33,520 --> 00:36:38,740 +اراه راجحا هو المصدر اعلام اعلاما اعلام الموقعين + +313 +00:36:38,740 --> 00:36:43,940 +عن رب العالمين ففيه الكثير من مثل هذه الأمثلة + +314 +00:36:43,940 --> 00:36:53,930 +والنماذج اذا نختصر هذه الخاصية فنقول السباتو + +315 +00:36:53,930 --> 00:37:01,850 +المرونة ليست في شيء واحد أو ليست في أمر واحد + +316 +00:37:01,850 --> 00:37:07,470 +فالثبات إنما يكون فيه أمور كما ذكرنا في العقيدة و + +317 +00:37:07,470 --> 00:37:15,230 +الأسرة و الحدود و المرونة إنما تكون في الفروع و + +318 +00:37:15,230 --> 00:37:22,500 +الوسائل ألا فاحفظوها أو في العادات و التقاليدنعم + +319 +00:37:22,500 --> 00:37:28,440 +والبيئات المختلفة أما ثالثا من خصائص النظم + +320 +00:37:28,440 --> 00:37:35,020 +الإسلامية الشمول والتوازن وكنت أتمنى أن يكون ثالثا + +321 +00:37:35,020 --> 00:37:42,840 +الشمول ورابعا التوازن فالشمول خاصية مستقلة من + +322 +00:37:42,840 --> 00:37:50,460 +خصائص النظم الإسلامية وكذلك التوازن فلا يصحأن نعرف + +323 +00:37:50,460 --> 00:37:59,540 +الشمول والتوازن تعريفا واحدا فلكل تعريف ونبدأ أولا + +324 +00:37:59,540 --> 00:38:08,480 +بالشمول ما هو مصطلح الشمول الشمول بمعنى أنها نظم + +325 +00:38:08,480 --> 00:38:17,650 +تعالج جوانب الحياة كلهانظم تعالج جوانب الحياة كلها + +326 +00:38:17,650 --> 00:38:27,570 +من عقيدة و عبادة و معاملة و أخلاق و سياسة و حكم + +327 +00:38:27,570 --> 00:38:34,500 +إلى غير ذلك بل الشمول أيضا الذي يراعي مراحلحياة + +328 +00:38:34,500 --> 00:38:42,940 +الفرد كلها طفلا و صبيا و شابا و شيخا و الشمول الذي + +329 +00:38:42,940 --> 00:38:49,820 +يمتد لمعالجة شؤون الدنيا و الآخرة و شؤون الفرد و + +330 +00:38:49,820 --> 00:38:58,700 +المجتمع نأتي بعد هذا المصطلح إلى الأدلة إذا قلنا + +331 +00:38:58,700 --> 00:39:07,480 +بأن الشمولأنها نظم تعالج جوانب الحياة كلها ما هي + +332 +00:39:07,480 --> 00:39:17,340 +الأدلة على ذلك نقتصر على أدلة ثلاثةفي الكتاب + +333 +00:39:17,340 --> 00:39:23,360 +المقرر و هي كافية ان شاء الله أول هذه الأدلة على + +334 +00:39:23,360 --> 00:39:30,260 +شمول النظم الإسلامية قوله تبارك وتعالى و كل شيء + +335 +00:39:30,260 --> 00:39:37,080 +أحصيناه في إمام مبين و قوله تبارك وتعالى و نزلنا + +336 +00:39:37,080 --> 00:39:43,200 +عليك الكتاب تبيانا لكل شيء و قوله تبارك وتعالى ما + +337 +00:39:43,200 --> 00:39:49,070 +فرطنا في الكتاب من شيءإذا هذه ثلاثة أدلة من الكتاب + +338 +00:39:49,070 --> 00:39:55,730 +أي من القرآن الكريم على مدى شمولية النظم الإسلامية + +339 +00:39:55,730 --> 00:40:02,650 +للدنيا والآخرة للعقيدة والعبادة والمعاملة والأخلاق + +340 +00:40:02,650 --> 00:40:08,900 +والسياسة والحكم إلى غير ذلك وليس معناإلا حديث واحد + +341 +00:40:08,900 --> 00:40:17,200 +من الصناة النبوية فنكتفي به للدلالة على مدى شمولية + +342 +00:40:17,200 --> 00:40:26,360 +النظم الإسلامية وهذا الحديث مفهومه ومعناهان يهوديا + +343 +00:40:26,360 --> 00:40:33,740 +قال لسلمان الفارسى يا سلمان لقد علمكم نبيكم كل شيء + +344 +00:40:33,740 --> 00:40:40,660 +حتى قضاء الحاجة يعني و نحن في مساقى دراسات + +345 +00:40:42,330 --> 00:40:47,910 +فقهية من كتاب الفقه المنهجي على مذهب الإمام + +346 +00:40:47,910 --> 00:40:55,610 +الشافعي ندرس الاستنجاب او آداب الخلاء عندما ندخل + +347 +00:40:55,610 --> 00:41:02,410 +بالشمال و نقول بسم الله اعوذ بك من الخبث و الخبائث + +348 +00:41:03,240 --> 00:41:09,300 +و نخرج باليمين خلافا للمسجد و نقول اللهم غفرانك و + +349 +00:41:09,300 --> 00:41:15,640 +الأحكام ستدرسلكم في مساق دراسات فقهية ان شاء الله + +350 +00:41:15,640 --> 00:41:22,540 +تبارك وتعالى المهم أن هذا اليهودي قد عرف حقيقة هذا + +351 +00:41:22,540 --> 00:41:28,040 +الدين يا سلمان لقد علمكم نبيكم كل شيء حتى القراءة + +352 +00:41:28,760 --> 00:41:37,580 +يعني حتى قضاء الحاجة نعم هذا هو الشمول نأتي الآن + +353 +00:41:37,580 --> 00:41:45,800 +إلى خاصية أخرى وقدرتبطت هنا بالشمول لما بين الشمول + +354 +00:41:45,800 --> 00:41:56,440 +والتوازن من ترابط نعم واتثار فمعنى + +355 +00:41:57,770 --> 00:42:07,670 +التوازن أنها متناسقة أنها مترابطة أنها متكاملة + +356 +00:42:07,670 --> 00:42:16,890 +ولعل هذا يعود بنا إلى تعريف النظم لغة عندما قلنا + +357 +00:42:16,890 --> 00:42:24,450 +أن النظام أصله اللغوي من الفعل نظمة من الفعل + +358 +00:42:24,450 --> 00:42:34,610 +الثلاثي المجردالنون والظاء والميم بمعنى ألفة + +359 +00:42:34,610 --> 00:42:46,050 +وبمعنى ربطة وبمعنى جمعة فيكون معنى النظم لغة ضم + +360 +00:42:46,050 --> 00:42:52,630 +الأشياء بعضها إلى بعض بتنسيق وترتيب وتناهم + +361 +00:42:52,630 --> 00:42:59,060 +واستقامة أو تكامل وترابطوقلت في المحاضرة الأولى + +362 +00:42:59,060 --> 00:43:05,780 +إذا ما كانت هذه الأشياء كحبات العقد مثلا أو الصبحة + +363 +00:43:05,780 --> 00:43:15,340 +وقد انفرتت وتباعدت وصار كل حبة في واد مهلهلة + +364 +00:43:15,340 --> 00:43:23,140 +مبعثرة فإنه لا يطلق عليها نظام ولا تسمى منظومةو + +365 +00:43:23,140 --> 00:43:29,640 +كذلك ارا هنا ترابطا بين التوازن وبين المعنى اللغوي + +366 +00:43:29,640 --> 00:43:40,690 +للنظم فإن معنى توازن هذه النظمكما أسلفنا متناسقة + +367 +00:43:40,690 --> 00:43:49,590 +مترابطة متكاملة مثل حبات العقد لا اختلاف بين + +368 +00:43:49,590 --> 00:43:59,330 +حباتها بحيث لا يطغى فيها جانب على جانب بل هي تنظم + +369 +00:43:59,330 --> 00:44:08,630 +كل جوانب هذا الكونبلا زيغ أو ميل أو إفراط أو تفريط + +370 +00:44:08,630 --> 00:44:16,810 +هذا هو معنى التوازن لا إفراط بمعنى زيادة ولا تفريط + +371 +00:44:16,810 --> 00:44:27,850 +بمعنى نقص نعم هنا جاء لنا بأمثلة بعضها + +372 +00:44:27,850 --> 00:44:35,700 +ذكر أدلتها وبعضها لم يذكر أدلتهاوحتى لا نطيل عليكم + +373 +00:44:35,700 --> 00:44:44,180 +نكتفي بأمثلة الكتاب أولا توازن بين حياة الفرض + +374 +00:44:44,180 --> 00:44:49,320 +وحياة المجتمع وهذه ليس فيها دليل بمعنى أنكم في + +375 +00:44:49,320 --> 00:44:55,370 +الامتحان لا تطالبون بذكر الدليلو كذلك النظم + +376 +00:44:55,370 --> 00:45:02,630 +الإسلامية توازن بين متطلبات الروح و رغبات الجسد و + +377 +00:45:02,630 --> 00:45:07,630 +أما ثالثا سنأتي إلى ذلك بالتبصيل عند الحديث عن + +378 +00:45:07,630 --> 00:45:13,410 +التوازن بين الواقعية و المثالية أما الأمثلة + +379 +00:45:13,410 --> 00:45:23,180 +الثلاثة الآتية فإن لها أدلة تطالبون بهافي الامتحان + +380 +00:45:23,180 --> 00:45:31,020 +وهي لا تحفظ لأن الامتحان قد يكون إلكترونيا أعمال + +381 +00:45:31,020 --> 00:45:37,980 +الفصل من أربعين درجة والنهائي من ستين فتلك مائة + +382 +00:45:37,980 --> 00:45:44,660 +كاملة إذا النظم الإسلامية توازن بين الاهتمام بشؤون + +383 +00:45:44,660 --> 00:45:48,680 +الدنيا وشؤون الآخرةما هو الدليل على هذا التوازن + +384 +00:45:48,680 --> 00:45:52,900 +بين شؤون الدنيا وشؤون الآخرة نكتفي بقول تعالى في + +385 +00:45:52,900 --> 00:46:01,320 +صورة الخصص في قصة قارون الذي بغى وطغى وكفر بالله + +386 +00:46:02,400 --> 00:46:07,340 +ولم يشكر الله على علم الله بل اغتر بعلمه و قال + +387 +00:46:07,340 --> 00:46:12,680 +انما أوتيته على علم عندي فخصف الله به و بقومه + +388 +00:46:12,680 --> 00:46:18,320 +الأرض ماذا قال الله تبارك وتعالى و ابتغي فيما آتاك + +389 +00:46:18,320 --> 00:46:24,620 +الله دار الآخرة ولا تنس نصيبك من الدنيا فالاهتمام + +390 +00:46:24,620 --> 00:46:35,080 +بالدنيا على حساب الآخرة هذا لا يصحو كذلك الاهتمام + +391 +00:46:35,080 --> 00:46:41,180 +في الآخرة على حساب الدنيا لا يصح فلابد من التوازن + +392 +00:46:41,180 --> 00:46:46,920 +بين الدنيا و بين الآخرة أن تعطي الدنيا حقها و أن + +393 +00:46:46,920 --> 00:46:54,420 +تعطي الآخرة حقها بحيث لا يضغج جانب على جانب و كذلك + +394 +00:46:54,420 --> 00:47:00,660 +الاهتمام و التوازن بين + +395 +00:47:03,120 --> 00:47:12,120 +الاسراف والتقطير فالاسراف رذيلة والتقطير أيضا + +396 +00:47:12,120 --> 00:47:19,980 +رذيلة وبينهما فضيلة وهي الاقتصاد وترشيد الاستهلاك + +397 +00:47:19,980 --> 00:47:28,160 +هنا جاء لنا آية في صورة الاسراءوهي قوله تبارك + +398 +00:47:28,160 --> 00:47:33,880 +وتعالى و لا تجعل يدك مغلولة إلى عنقك ولا تبسطها كل + +399 +00:47:33,880 --> 00:47:40,560 +البصر فتقعد ملوما محصورا نعم هذه آية المناسبة ولكن + +400 +00:47:40,560 --> 00:47:47,330 +كنت أتمنى لو جاء المؤلف بآية أقرب إلى العنوانلأن + +401 +00:47:47,330 --> 00:47:52,750 +العنوان التوازن بين الإسراف والتقطير في وصف عباد + +402 +00:47:52,750 --> 00:47:58,830 +الرحمن في صورة الفرقان والذين إذا أنفقوا لم يسرفوا + +403 +00:47:58,830 --> 00:48:05,490 +ولم يقطروا وكان بين ذلك قوامة فكل ذلك صحيح إن شاء + +404 +00:48:05,490 --> 00:48:14,390 +الله وهنا نرى أن الفرق كبيروأن البون شاسع بين + +405 +00:48:14,390 --> 00:48:21,150 +الإصراف وبين التبزير فلا يصح أن نستشهد بآية + +406 +00:48:21,150 --> 00:48:27,010 +التبزير هنا في قوله تبارك وتعالى و لا تبذر تبزيرة + +407 +00:48:27,010 --> 00:48:32,200 +إن المبذرين كانوا إخوان الشياطينوكان الشيطان لربه + +408 +00:48:32,200 --> 00:48:36,940 +كفورة لأن التبذير إنما يكون في المحرمات أما + +409 +00:48:36,940 --> 00:48:43,280 +الإصراف فإنما يكون في المباحات حتى و لو كان مباحا + +410 +00:48:43,280 --> 00:48:51,700 +من طعام و شراب و ثيابليس لك الإصراف نعم و هذا معنى + +411 +00:48:51,700 --> 00:48:57,980 +الآيات التي تلونا عرضته أن ألفت الأنظار حتى لو + +412 +00:48:57,980 --> 00:49:05,860 +سؤلنا لا نستشهد بآية الإصراف الأخرى ولا تبذر + +413 +00:49:05,860 --> 00:49:10,480 +تبذيرة لأن التبذير يكون فيما حرم الله أما الإصراف + +414 +00:49:10,480 --> 00:49:21,790 +فقد يكون في حق المؤمنين نعمأما أخيرا فالتوازن بين + +415 +00:49:21,790 --> 00:49:28,730 +حقوق الله وحقوق النفس وهذا الحديث سيأتي معنا كثيرا + +416 +00:49:28,730 --> 00:49:35,930 +وله قصة طويلة صحيحة عند البخاري وعند غيرهعندما جاء + +417 +00:49:35,930 --> 00:49:42,290 +ثلاثة ربط يسألون أزواج النبي عليه الصلاة والسلام + +418 +00:49:42,290 --> 00:49:46,470 +ورضي الله عنهم عن عبادة النبي عليه الصلاة والسلام + +419 +00:49:46,470 --> 00:49:54,310 +أي نعم فلمّا أخبروا كأنهم تقالوها بمعنى أنهم عدوها + +420 +00:49:54,310 --> 00:49:59,490 +قليلةثم قالوا و أينا مثل رسول الله لقد غفر له ما + +421 +00:49:59,490 --> 00:50:05,410 +تقدم و ما تأخر من ذنبه وما علموا أن هذا الدين يسر + +422 +00:50:05,410 --> 00:50:17,110 +و سماح لا حرج فيه ولا تطرف فيه ولا غلو فيهفقال + +423 +00:50:17,110 --> 00:50:25,130 +أحدهم أما أنا فأعتزل النساء لا أتزوج أبدا و قال + +424 +00:50:25,130 --> 00:50:31,510 +الآخر أما أنا فأقوم الليلة لا أرقد أبدا و قال + +425 +00:50:31,510 --> 00:50:37,170 +الثالث أما أنا فأصوم النهار لا أفطر أبدا ظنوا أنهم + +426 +00:50:37,170 --> 00:50:42,770 +يفعلون الخيرولكن الرسول عليه الصلاة والسلام لما + +427 +00:50:42,770 --> 00:50:49,770 +سمع بهم عن نفهم و أخبارهم أن هذا هو التطرف أو أن + +428 +00:50:49,770 --> 00:50:55,130 +هذا هو الغلو هذا لم يأتي به النبي عليه الصلاة + +429 +00:50:55,130 --> 00:51:00,450 +والسلام و سنأتي في الفصل الثاني ان شاء الله عند + +430 +00:51:00,450 --> 00:51:07,010 +الحديث عن خصائص العبادةأنه من خصائص العبادة اليسر + +431 +00:51:07,010 --> 00:51:12,070 +ورفع الحرج وثنائة إلى آيات وإلى أمثلة ونماذج مثل + +432 +00:51:12,070 --> 00:51:16,710 +قول تعالى يريد الله بكم اليسر ولا يريد بكم العصر + +433 +00:51:16,710 --> 00:51:21,770 +ومثل قول تعالى فمن كان منكم مريضا أو على سفر فعدة + +434 +00:51:21,770 --> 00:51:28,160 +من أيام أخر وكذلك قصر الصلاة للمسافرو كذلك الجمع + +435 +00:51:28,160 --> 00:51:32,660 +في الخوف و المطر + +436 +00:51:32,660 --> 00:51:38,620 +نعم و ثنأتي المسح على الجوارب إلى غير ذلك من + +437 +00:51:38,620 --> 00:51:43,220 +الأمثلة التي تدل على سماحة هذا الدين و يُصر هذه + +438 +00:51:43,220 --> 00:51:49,030 +الشريعة فالنبي عليه السلاملم يعطهم الأوسمة ولم + +439 +00:51:49,030 --> 00:51:55,190 +يعلق الناشين على صدورهم بل قال أما والله إني + +440 +00:51:55,190 --> 00:52:02,030 +لأخشاكم لله و أتقاكم له و لكن أصوم و أفطر و أصلي و + +441 +00:52:02,030 --> 00:52:07,770 +أرقد و أتزوج النساء فمن رغب عن سنتي فليس مني صدق + +442 +00:52:07,770 --> 00:52:11,850 +رسول الله صلى الله عليه وسلم نتوقف إلى هنا إن شاء + +443 +00:52:11,850 --> 00:52:18,570 +اللهونكون في المحاضرة التالية على موعد مع الخاصية + +444 +00:52:18,570 --> 00:52:24,750 +الرابعة العموم والعالمية من خصائص النظم الإسلامية + +445 +00:52:24,750 --> 00:52:29,510 +وصل اللهم على سيدنا محمد والسلام عليكم ورحمة الله + +446 +00:52:29,510 --> 00:52:30,470 +وبركاته + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/_c7knQ2e7HI_raw.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/_c7knQ2e7HI_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..6ac502152e3ab274ab7d0ce0e11fa7e529eb416a --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/_c7knQ2e7HI_raw.srt @@ -0,0 +1,1824 @@ +1 +00:00:05,030 --> 00:00:07,570 +أعوذ بالله السميع العلي من الشياطين الرجيم بسم + +2 +00:00:07,570 --> 00:00:11,230 +الله الرحمن الرحيم الحمد لله والصلاة والسلام على + +3 +00:00:11,230 --> 00:00:15,630 +رسول الله اللهم صلى على سيدنا محمد وعلى آله وصحبه + +4 +00:00:15,630 --> 00:00:19,850 +وسلم أجمعين قبل ذي بدء أرحب بكم أعزائي الطلاب + +5 +00:00:20,130 --> 00:00:23,610 +وأحييكم جميعا بتحية الإسلام العظيم فالسلام الله + +6 +00:00:23,610 --> 00:00:31,070 +عليكم ورحمته وبركته ما زلنا مع الفصل الثالث مع + +7 +00:00:31,070 --> 00:00:38,750 +نظام الأخلاق في الإسلام وقد تكلمنا عن التعريف وعن + +8 +00:00:38,750 --> 00:00:44,350 +مراحل توجيه الخلق في النفس البشرية واليوم نكمل ان + +9 +00:00:44,350 --> 00:00:51,600 +شاء الله خصائصنظام الأخلاق في الإسلام فعلى بركة + +10 +00:00:51,600 --> 00:00:58,120 +الله نعم كما أسلفتوا تكلمنا عن تعريف نظام الأخلاق + +11 +00:00:58,120 --> 00:01:04,300 +في الإسلام وقلتوا إن الأخلاق جمع قلقوالخلق هو + +12 +00:01:04,300 --> 00:01:14,260 +الطبيعة أو السجية يقال فلان سجيته الصدق أي خلقه + +13 +00:01:14,260 --> 00:01:22,660 +الصدق وفلان سجيته الكذب أي خلقه الكذب ونحن نتكلم + +14 +00:01:22,660 --> 00:01:29,550 +في هذا الفصل عن الأخلاق بنوعيها كما أسلفناالأخلاق + +15 +00:01:29,550 --> 00:01:36,090 +الإيجابية كالصدق والأمانة ونحوهما والأخلاق السلبية + +16 +00:01:36,090 --> 00:01:44,070 +كالكذب والخيانة ونحوهما إذا نحن لا نقتصر في هذا + +17 +00:01:45,110 --> 00:01:51,690 +الفصل على الأخلاق الإيجابية في حسب إنما نتكلم عن + +18 +00:01:51,690 --> 00:01:58,570 +الأخلاق بنوعها لأن الأخلاق إذا ذُكرت مطلقة فإنها + +19 +00:01:58,570 --> 00:02:03,890 +تعني الأخلاقالإيجابية كما قال الله تعالى في مدح + +20 +00:02:03,890 --> 00:02:08,910 +رسول الله عليه الصلاة والسلام وإنك لعلى خلق عظيم + +21 +00:02:08,910 --> 00:02:16,930 +وكذلك نحن نردد منذ الصغر مع أمير الشعراء أحمد شوقي + +22 +00:02:16,930 --> 00:02:22,990 +إنما الأمم الأخلاق ما بقيت فإن هم ذهبت أخلاقهم + +23 +00:02:22,990 --> 00:02:30,800 +ذهبوا نعم وأما الأخلاقاصطلاحا وهذا هو المطلوب في + +24 +00:02:30,800 --> 00:02:36,480 +الامتحان هيئة راسخة في النفس تصدر عنها الأفعال + +25 +00:02:36,480 --> 00:02:42,060 +بسهولة ويسر من غير فكرة أو روية هذه هي حقيقة + +26 +00:02:42,060 --> 00:02:51,280 +الأخلاق أنها فطرة في الإنسان أنهاخصلة أو صفة راسخة + +27 +00:02:51,280 --> 00:02:58,720 +مستقرة في كيان هذا الإنسان و أعماقه و كذلك هي تخرج + +28 +00:02:58,720 --> 00:03:07,140 +بسهولة و يسرا من غير تمثيل أو من غير تفكير مسبق + +29 +00:03:07,140 --> 00:03:14,430 +وإلا لم يكن خلقالأن هذه الأخلاق لا تعتبر حقيقة + +30 +00:03:14,430 --> 00:03:20,710 +وإنما تعتبر من أبواب الكذب أو من أبواب النفاق + +31 +00:03:20,710 --> 00:03:27,810 +والعياذ بالله نعم وقد تكلمنا عن مراحل توجيه الخلق + +32 +00:03:27,810 --> 00:03:33,990 +في النفس البشرية وهي ثلاثة وقلت لكم لابد أن تحفظ + +33 +00:03:33,990 --> 00:03:42,020 +هذه المراحلالثلاثة مرتبة لأن كل واحدة منها تعتمد + +34 +00:03:42,020 --> 00:03:48,040 +على ما قبلها فالمرحلة الأولى التأثر بالخير أو الشر + +35 +00:03:48,040 --> 00:03:53,120 +وهذا يعود كما أسلفنا إلى ضعف الإنسان وقد قال الله + +36 +00:03:53,120 --> 00:03:58,600 +تبارك وتعالى وخُلِق الإنسان ضعيفا وما يحيط به من + +37 +00:03:58,600 --> 00:04:07,540 +شهوات هذه الشهوات إنما هي صلاح زوحة دينهكالنساء + +38 +00:04:07,540 --> 00:04:13,760 +والأولاد والأموال والقناطير المخنطرة من الذهب + +39 +00:04:13,760 --> 00:04:18,460 +والفضة كما قال الله تبارك وتعالى زين للناس حب + +40 +00:04:18,460 --> 00:04:23,020 +الشهوات من النساء والبنين والقناطير المخنطرة من + +41 +00:04:23,020 --> 00:04:28,460 +الذهب والفضة والخيل المسومة والأنعام والحرث فهذه + +42 +00:04:28,460 --> 00:04:34,590 +الشهوات إما أن تصرف في طاعة اللهوإما أن تصرف في + +43 +00:04:34,590 --> 00:04:40,810 +معصية الله فاحرص أن تكون هذه الشهوات أو تلك النعم + +44 +00:04:40,810 --> 00:04:48,470 +في طاعة الله وعونا على التقرب إلى الله تبارك + +45 +00:04:48,470 --> 00:04:56,550 +وتعالى وإلا كانت سلاحا ضدك يدخلكالنار والعياذة + +46 +00:04:56,550 --> 00:05:02,530 +بالله وبئس القرار كما حذرنا القرآن الكريم إن من + +47 +00:05:02,530 --> 00:05:09,330 +أزوادكم وأولادكم عدوا لكم فاحذروهم فالمال والبنون + +48 +00:05:09,330 --> 00:05:14,610 +زينة هذه الحياة الدنيا بل فتنة كما قال الله تبارك + +49 +00:05:14,610 --> 00:05:19,430 +وتعالى في أكثر من موضع في القرآن الكريم وكذلك + +50 +00:05:19,430 --> 00:05:25,470 +حذرنا من الدنيا ومن غرور الشيطانالرجيم فلا تغرنكم + +51 +00:05:25,470 --> 00:05:31,190 +الحياة الدنيا ولا يغرنكم بالله الغرور ويترتب على + +52 +00:05:31,190 --> 00:05:37,510 +هذه المرحلة التأثر بالخير أو الشر بمعنى التأثر + +53 +00:05:37,510 --> 00:05:45,820 +بالأخلاق الإيجابية إن كان في بيئة إيجابية صالحةأو + +54 +00:05:45,820 --> 00:05:52,820 +التأثر بالأخلاق السلبية إن كان في بيئة سلبية فاسدة + +55 +00:05:52,820 --> 00:06:01,620 +والعياذ بالله يترتب على ذلك رصوخ هذا الخلق إيجابا + +56 +00:06:01,620 --> 00:06:10,720 +أو سلبا، خيرا أو شراواستقراره في النفس البشرية + +57 +00:06:10,720 --> 00:06:16,260 +واستشهدنا على ذلك بحديثين الحديث الأول يقول فيه + +58 +00:06:16,260 --> 00:06:22,240 +صلى الله عليه وسلم في تمرين الأطفال وتعويدهم على + +59 +00:06:22,240 --> 00:06:27,460 +الصلاة ومثل الصلاة طبعا الصيام والحج وأركان + +60 +00:06:27,460 --> 00:06:33,430 +الإسلام مروا أولادكم بالصلاة لسبع سنينواضربوهم + +61 +00:06:33,430 --> 00:06:39,190 +عليها إذا بلغوا عشر سنين وفرقوا بينهم في المضاجعين + +62 +00:06:39,190 --> 00:06:45,210 +وهذا يؤكد ما ذهبنا إليه من أن الخلق لا يُنسب إلى + +63 +00:06:45,210 --> 00:06:54,230 +شخص ما إلا إذا تكرر منه هذا الخلق فلو مثلاصدق مرة + +64 +00:06:54,230 --> 00:07:00,530 +او مرتين لا يقال عنه صادق حتى يصبح الصدق سجية فيه + +65 +00:07:00,530 --> 00:07:07,250 +او طبيعة فيه او عادة فيه او حتى يتكرر منه هذا + +66 +00:07:07,250 --> 00:07:13,010 +الخلق مرات و مرات و كذلك الأخلاق السلبية فلا يقال + +67 +00:07:13,010 --> 00:07:18,860 +عن فلان كاذبإذا ما كذب مرة أو مرتين حتى يتكرر منه + +68 +00:07:18,860 --> 00:07:27,020 +هذا الخلق فإن الخلق لا يستقر ولا يرسخ في أعماق + +69 +00:07:27,020 --> 00:07:33,420 +الإنسان وكيانه إلا إذا أصبح جزء منه وتكرر منه ولذا + +70 +00:07:33,420 --> 00:07:38,000 +أمرنا الرسول عليه الصلاة والسلام ورغبنا في تعويض + +71 +00:07:38,000 --> 00:07:44,180 +الصغار قبل أن يبلغواالسنة البلوغ وقبل أن يتأثروا + +72 +00:07:44,180 --> 00:07:52,580 +بما حولهم ومن حولهم من بيئات مرو أولادكم بالصلاة + +73 +00:07:52,580 --> 00:07:57,960 +لسبع سنين إلى آخر الحدث كذلك قوله صلى الله عليه + +74 +00:07:57,960 --> 00:08:03,960 +وسلم وقد ضرب لنا مثالين مثالا للأخلاق الإيجابية + +75 +00:08:03,960 --> 00:08:11,090 +وقد تمثل ذلك بخلق الصدقوضرب لنا مثالا للأخلاق + +76 +00:08:11,090 --> 00:08:18,090 +السلبية وقد تمثل ذلك بخلق الكذب فقال عليه الصلاة + +77 +00:08:18,090 --> 00:08:27,810 +والسلام إن البر يهدي إلى الجنة نعم وإن الرجل لا + +78 +00:08:27,810 --> 00:08:33,970 +يصدق هذا هو الشاهد في الحديث هذا هو المطلوب في + +79 +00:08:33,970 --> 00:08:41,680 +الامتحان وإن الرجل لا يصدقويتحرص صدق حتى يُكتب عند + +80 +00:08:41,680 --> 00:08:48,100 +الله صديقة وهنا لابد أن نقف عند كلمتين يتحرص صدق + +81 +00:08:48,100 --> 00:08:54,980 +بمعنى أنه تعود على الصدق وهذا يؤكد أيضًا ما ذهبنا + +82 +00:08:54,980 --> 00:09:04,140 +إليه عند شرحتعريف الخلق هيئة راصخة يعني مستقرة في + +83 +00:09:04,140 --> 00:09:12,800 +النفس البشرية نعم و كذلك حتى يُكتب عند الله صديقة + +84 +00:09:12,800 --> 00:09:19,260 +فالصديق على وزن فعيل من صيغ المبالغة بمعنى أنه + +85 +00:09:19,260 --> 00:09:28,610 +كثير الصدقبحيث صار رمزا له وعلامة عليه وقد ضربت + +86 +00:09:28,610 --> 00:09:32,950 +لكم الأمثال في قصة الرسول عليه السلام يوم رفع + +87 +00:09:32,950 --> 00:09:37,410 +الحجر الأسود فماذا قال القوم جاء الصادق الأمين + +88 +00:09:37,410 --> 00:09:41,830 +لأنه قد اشتهر في الجاهلية قبل الإسلام بالصدق و + +89 +00:09:41,830 --> 00:09:50,100 +الأمانة و كذلك مثالالكذب والحديث طويل ويكفين ما في + +90 +00:09:50,100 --> 00:09:58,480 +الكتاب وإن الكذب يهدي إلى الفجور وإن الرجل ليجذب + +91 +00:09:58,480 --> 00:10:05,900 +ويتحر الكذب حتى يكتب عند الله كذابة نعم أيضا هنا + +92 +00:10:05,900 --> 00:10:12,280 +نقول ما قلته في الصدق قوله ويتحر الكذب بمعنى أنه + +93 +00:10:12,280 --> 00:10:19,160 +صار الكذب عادة فيهورمزا له علامة عليه فهو لم يجذب + +94 +00:10:19,160 --> 00:10:23,180 +مرة او مرتين حتى يشار اليه بالبنان ويقول هذا هو + +95 +00:10:23,180 --> 00:10:29,160 +الكاذب لأ صار كثيرا الكذب بدليل حتى يكتب عند الله + +96 +00:10:29,160 --> 00:10:37,640 +كذابة وكذاب على وزن فعال ايضا من صيغ المبالغة نعم + +97 +00:10:37,640 --> 00:10:45,820 +اما المرحلة الثالثةفهي مترتبة على المرحلة الثانية + +98 +00:10:45,820 --> 00:10:55,040 +والمرحلة الأولى وهو انعكاس هذا الخلق على تصرفات + +99 +00:10:55,040 --> 00:10:58,860 +الشخص وسلوكياته + +100 +00:10:58,860 --> 00:11:02,040 +نعم فالكريم + +101 +00:11:03,080 --> 00:11:11,100 +معروف بكرمه واطعامه فهو في عيد الأضحى مثلا يضحي + +102 +00:11:11,100 --> 00:11:22,360 +اذا رزق بولد يعق عنه كما هي الصنة اذا ما تزوج احد + +103 +00:11:22,360 --> 00:11:27,750 +اولاده فانه يولمفالاضحية في العيد والعقيقة للولد + +104 +00:11:27,750 --> 00:11:34,270 +والاضحية في عيد الأضحى المبارك وهكذا هو ينفق على + +105 +00:11:34,270 --> 00:11:41,390 +أهله وعلى أولاده وعلى أقاربه وعلى الناس أجمعين فلا + +106 +00:11:41,390 --> 00:11:48,240 +يقال عن البخيل كريمفالكريم معروف بكرمه و كذلك + +107 +00:11:48,240 --> 00:11:54,040 +البخيل معروف ببخله و نحن هنا كما أسلفنا نتكلم عن + +108 +00:11:54,040 --> 00:11:59,040 +الأخلاق بنوعية الأخلاق الإيجابية كالكرم مثلا و + +109 +00:11:59,040 --> 00:12:05,860 +الأخلاق السلبية كالبخل مثلا فالكريم كريم و معروف + +110 +00:12:05,860 --> 00:12:11,740 +بكرمه و البخيل بخيل و معروف ببخله و كذلك الشجاع + +111 +00:12:11,740 --> 00:12:18,950 +شجاععند المعارك و في الحروب و عند العدوان يمططي + +112 +00:12:18,950 --> 00:12:24,250 +صهوة جواده و يحملوا صلاحه و يواجهوا العدوان اما + +113 +00:12:24,250 --> 00:12:29,490 +الجبان و الرعديد اللذي يكون مع القواعد من النساء + +114 +00:12:29,490 --> 00:12:37,610 +فهو كذلك اذا اعود الى Z بدءفأقول إن المراحل التي + +115 +00:12:37,610 --> 00:12:42,290 +يمر بها توجيه الخلق في النفس البشرية أو النفس + +116 +00:12:42,290 --> 00:12:48,330 +الإنسانية مراحل ثلاثة لابد أن تحفظ مرتبة قلت لكم + +117 +00:12:48,330 --> 00:12:54,010 +لأن هذا من ضمن أسئلة الامتحانات أولا التأثر بالخير + +118 +00:12:54,010 --> 00:13:00,030 +أو الشريترتب على هذه المرحلة المرحلة الثانية وهي + +119 +00:13:00,030 --> 00:13:06,090 +رسوخ هذا الخلق واستقراره في النفس البشرية أما + +120 +00:13:06,090 --> 00:13:12,730 +ثالثا فيترتب على المرحلة الثانية إن عكاس هذا الخلق + +121 +00:13:12,730 --> 00:13:20,140 +إيجابا أو سلبا خيرا أو شرا صدقا أو كذباشجاعة أو + +122 +00:13:20,140 --> 00:13:25,380 +جبنا كرما أو بخلا إلى غير ذلك على تصرفات هذا الشخص + +123 +00:13:25,380 --> 00:13:36,470 +وثلوكيته نعمتكلمنا عن هذا و تكلمنا أيضا عن بداية + +124 +00:13:36,470 --> 00:13:43,330 +المبحث الثاني و هو مبحث طويل و هو بعنوان خصائص + +125 +00:13:43,330 --> 00:13:49,050 +نظام الأخلاق في الإسلام و بدأنا بالتعميم و التفصيل + +126 +00:13:49,050 --> 00:13:57,630 +و عرفنا التعميم و قلت المصطلحات هنا كثيرة لابد من + +127 +00:13:57,630 --> 00:14:04,310 +أن تنتبه إليهافالتعميم هو ورود الأخلاق على شكل + +128 +00:14:04,310 --> 00:14:11,390 +قواعد عامة كلية وضربنا لكم الأمثال على ذلك مثل + +129 +00:14:11,390 --> 00:14:16,150 +قوله تبارك وتعالى وتعاونوا على البر والتقوى ولا + +130 +00:14:16,150 --> 00:14:20,470 +تعاونوا على الإسم والعدوان ومثلها تماما قوله تبارك + +131 +00:14:20,470 --> 00:14:24,810 +وتعالى يا أيها الذين أمنوا إذا تناجيتم فلا تتناجوا + +132 +00:14:24,810 --> 00:14:30,200 +بالاسم والعدوان ومعصية الرسول وتناجوا بالبروالتقوى + +133 +00:14:30,200 --> 00:14:36,180 +واتقوا الله الذي إليه تحشرون نعم وقولنا بأن البره + +134 +00:14:36,180 --> 00:14:46,660 +هو اسم جامع لكل خلق إيجابييقوم به الإنسان تجاه + +135 +00:14:46,660 --> 00:14:54,340 +نفسه أو تجاه غيره فالبر هو قاعدة عامة كلية إيجابية + +136 +00:14:54,340 --> 00:14:58,080 +ويندرج تحتها مجموعة من الأخلاق الإيجابية + +137 +00:15:13,100 --> 00:15:22,360 +وأما الإثم فهو خلق سلبي وهو قاعدة عامة كلية يندرج + +138 +00:15:22,360 --> 00:15:32,020 +تحتها كل خلق سلبي فهو اسم لكل خلق سلبييقوم به + +139 +00:15:32,020 --> 00:15:38,300 +الإنسان تجاه نفسه أو تجاه غيره كما أسلفنا من + +140 +00:15:38,300 --> 00:15:43,560 +مجموعة الأخلاق السلبية مثل الكذب ومثل الخيانة + +141 +00:15:43,560 --> 00:15:49,770 +والغدر والغش وعقوق الوالدين والإساءةإلى الجار + +142 +00:15:49,770 --> 00:15:56,310 +والتولي يوم الزحف والغيبة والنميمة والسحر وصناعتي + +143 +00:15:56,310 --> 00:16:01,730 +إلى هذه المجموعة السلبية مستدلين بآيات من الكتاب + +144 +00:16:01,730 --> 00:16:09,410 +وبأحاديث من الصنة النبوية الشريفة إذا مر معنا أربع + +145 +00:16:09,410 --> 00:16:17,590 +مصطلحات في هذه النقطة بالذات مصطلح التعميم ومصطلح + +146 +00:16:18,900 --> 00:16:28,380 +التفصيل وهو ورود الأخلاق على شكل جزئيات مفصلة نعم + +147 +00:16:28,380 --> 00:16:35,800 +وكذلك البر اسم جامع لكل عمل إيجابي يقوم به الإنسان + +148 +00:16:35,800 --> 00:16:43,790 +تجاه غيره أو تجاه نفسه وكذلك الإثمخلق سلبي وهو + +149 +00:16:43,790 --> 00:16:51,590 +قاعدة عامة وهو اسم لكل خلق سلبي يقوم به الإنسان + +150 +00:16:51,590 --> 00:16:59,430 +تجاه نفسه أو تجاه غيره نعم وكذلك العدوان هو قاعدة + +151 +00:16:59,430 --> 00:17:03,810 +عامة كلية لكل عدوان سواء كانت عدوانا على الله + +152 +00:17:04,290 --> 00:17:11,250 +بالكفر و الجحودي و الشرك بالله و تعدي حدود الله و + +153 +00:17:11,250 --> 00:17:15,550 +العدوان على النفس بالانتحار لأن الإنسان لا يملك + +154 +00:17:15,550 --> 00:17:21,030 +نفسه إنما هي ملك الله فالإنسان خلق الله و صنعت + +155 +00:17:21,030 --> 00:17:27,070 +الله و بنيانه الرب تبارك وتعالى و كذلك العدوان على + +156 +00:17:27,070 --> 00:17:33,560 +الآخرين إما بالعدوان على أنفسهمبقتلهم وإزهاق + +157 +00:17:33,560 --> 00:17:41,200 +أرواحهم أو بقطع أطرافهم ونحو ذلك أو الاعتداع على + +158 +00:17:41,200 --> 00:17:47,480 +أموالهم مثل اقتصاب أرضهم أو صالقة أموالهم فهذه + +159 +00:17:47,480 --> 00:17:53,180 +كلها قواعد عامة كلية سواء كانت إيجابية كما ضرب لنا + +160 +00:17:53,180 --> 00:17:59,400 +القرآن الكريم بالبرء أو سلبية كالإثم والعدوان ثم + +161 +00:17:59,400 --> 00:18:07,160 +وصلنا إلىنقطة مهمة جدا وهي فوائد التعميم والتعميم + +162 +00:18:07,160 --> 00:18:13,320 +له فائدتان الفائدة الأولى وضع تصور عام عن نظام + +163 +00:18:13,320 --> 00:18:19,900 +الأخلاق في الإسلام وخاصة من غير المسلمين الذين + +164 +00:18:19,900 --> 00:18:26,460 +يريدون أن يفهموا الإسلامفي ساعة او في ساعتين بعيدا + +165 +00:18:26,460 --> 00:18:33,860 +عن الدراسات وبعيدا عن الكليات والجامعات وقد ضربنا + +166 +00:18:33,860 --> 00:18:37,720 +لكم مثلا كيف ان الرسول عليه الصلاة والسلام كان + +167 +00:18:37,720 --> 00:18:43,160 +يعلم الأعرابية الإسلام في ساعة واحدةفيعود إلى قومه + +168 +00:18:43,160 --> 00:18:49,020 +واعظا وداعية إلى الله ورسوله كما في الحديث الصحيح + +169 +00:18:49,020 --> 00:18:54,460 +عن سيدنا عمرو بن الخطاب رضي الله عنه وفي قصة جبريل + +170 +00:18:54,460 --> 00:19:00,620 +فجبريله يسأل والنبي يجيب ما الإسلام وما الإيمان + +171 +00:19:00,620 --> 00:19:07,400 +وما الإحسان وما الساعة ومتى الساعة وما علامتها + +172 +00:19:07,400 --> 00:19:17,240 +وشروطها نعمهذا هو حقيقة الإسلام كله يسر وسماحة + +173 +00:19:17,240 --> 00:19:25,810 +ولذا لابد ان يشرحالى هؤلاء الأجانب غير المسلمين + +174 +00:19:25,810 --> 00:19:32,510 +بالتعميم بعيدا عن التفصيل وبعد ذلك يكون لهم المجال + +175 +00:19:32,510 --> 00:19:36,590 +أوسع اذا اولا من فوائد تعميم نظام الأخلاق في + +176 +00:19:36,590 --> 00:19:42,690 +الإسلام وضع تصور عام عن نظام الأخلاق في الإسلام + +177 +00:19:42,690 --> 00:19:47,470 +بحيث يسهلواعلى المكلف وعلى غير المكلف من غير + +178 +00:19:47,470 --> 00:19:53,910 +المسلمين الذين يريدون التعرفة على الإسلام ثانيا من + +179 +00:19:53,910 --> 00:20:04,020 +فوائد التعميم في قواعد الأخلاق فهو دفع المكلفالى + +180 +00:20:04,020 --> 00:20:09,240 +البحث في ثانية تشريع عن تفصيلات هذه القواعد + +181 +00:20:09,240 --> 00:20:15,440 +والتعرف على جزئيتها حتى يتسنى له العمل بها + +182 +00:20:15,440 --> 00:20:22,620 +وامتثالها الان نأتي الى التفصيل وقد سبق ان عرفنا + +183 +00:20:22,620 --> 00:20:31,320 +التفصيل بأنه ورود الأخلاق على شكل جزئيات مفصلة + +184 +00:20:32,310 --> 00:20:40,530 +ويمكن أن تقسم الأخلاق إلى مجموعتين مجموعة الأخلاق + +185 +00:20:40,530 --> 00:20:45,590 +الإيجابية ومجموعة الأخلاق السلبية وهنا معنا أيضا + +186 +00:20:45,590 --> 00:20:54,540 +مصطلحات رأيتم كيف أن المصطلحات كثرت فيباب الأخلاق + +187 +00:20:54,540 --> 00:20:59,560 +ونحن لا نطالبكم بحفظها غيبا لأنها ستأتيكم في + +188 +00:20:59,560 --> 00:21:05,100 +الامتحانات كما هي وما عليكم إلا ذكروا المصفلح إذا + +189 +00:21:05,100 --> 00:21:10,060 +كان الامتحان ورقيا خطيا أما إذا كان الامتحان + +190 +00:21:10,060 --> 00:21:18,870 +إلكترونيا فهناكالمصطلح وجوابه ويكون السؤال على شكل + +191 +00:21:18,870 --> 00:21:25,290 +توصيل نعم فالأخلاق الإيجابية هي التي وردت على شكل + +192 +00:21:25,290 --> 00:21:32,330 +أوامر أو في معرض المدح نعم فإذا ما جاء هذا المصطلح + +193 +00:21:32,330 --> 00:21:39,120 +يكتب بين يديه الأخلاق الإيجابيةولا يصح أن يُكتب + +194 +00:21:39,120 --> 00:21:45,340 +الأخلاق هكذا لابد أن يُكتب الأخلاق الإيجابية لأن + +195 +00:21:45,340 --> 00:21:51,320 +هناك أيضًا أخلاقًا سلبية فما الأخلاق الإيجابية هي + +196 +00:21:51,320 --> 00:21:57,820 +التي وردت على شكل أوامر أو في معرض المدح قبل أن + +197 +00:21:57,820 --> 00:22:03,580 +نأتي إلى المجموعة مفصلة نأتي بأمثلة مثل قوله تبارك + +198 +00:22:03,580 --> 00:22:08,780 +وتعالى يا أيها الذين آمنوا اتقوا اللهوكونوا مع + +199 +00:22:08,780 --> 00:22:15,100 +الصادقين هذا خلق إيجابي لأنه جاء على شكل أمر اتقوا + +200 +00:22:15,100 --> 00:22:22,100 +الله وكونوا مع الصادقين ومثله كثير قوله تعالى يا + +201 +00:22:22,100 --> 00:22:26,640 +أيها الذين آمنوا استعينوا بالصبر والصلاة إن الله + +202 +00:22:26,640 --> 00:22:31,420 +مع الصابرين يا أيها الذين آمنوافي أواخر أهل + +203 +00:22:31,420 --> 00:22:34,940 +الإمران اصبروا وصابروا ورابطوا واتقوا الله لعلكم + +204 +00:22:34,940 --> 00:22:41,860 +تفلحون فكل هذه ومثيلاتها أخلاق إيجابية لأنها جاءت + +205 +00:22:41,860 --> 00:22:47,740 +على شكل أوامر أو في معرض المدح لأن الله تبارك + +206 +00:22:47,740 --> 00:22:55,820 +وتعالى لا يمدحوا إلا الأخلاق الإيجابية نعمولا + +207 +00:22:55,820 --> 00:23:01,020 +يذموا إلا الأخلاق السلبية فالأخلاق الإيجابية مدحها + +208 +00:23:01,020 --> 00:23:05,420 +الله تبارك وتعالى والأخلاق السلبية ذمها الله تبارك + +209 +00:23:05,420 --> 00:23:11,880 +وتعالى كما نقرأ في صورة النحل إن الله يأمر بالعدل + +210 +00:23:11,880 --> 00:23:16,420 +والإحسان وإيتاء ذو القربة وينهى عن الفحشاء والمنكر + +211 +00:23:16,420 --> 00:23:22,220 +والبغي يعذبكم لعلكم تذكرونإذا الأخلاق الإيجابية هي + +212 +00:23:22,220 --> 00:23:26,580 +التي وردت على شكر أوامر أو في معرض المدح مثل قوله + +213 +00:23:26,580 --> 00:23:32,040 +من المؤمنين رجال صدقوا ما عاهدوا الله عليه فمنهم + +214 +00:23:32,040 --> 00:23:38,020 +من قضى نحبه ومنهم من ينتظر وما بدلوا تبديله وكذلك + +215 +00:23:38,020 --> 00:23:42,520 +قوله تبارك وتعالى في معرض المدح إنما يوفى الصابرون + +216 +00:23:42,520 --> 00:23:48,390 +أجرهم بغير حسابأما الأخلاق السلبية فهي التي وردت + +217 +00:23:48,390 --> 00:23:55,730 +على شكل نواهن أو في معرض الزمن على شكل نواهن مثل + +218 +00:23:55,730 --> 00:24:00,410 +قوله تبارك وتعالى و لا تقرب الزنا إنه كان فحشة + +219 +00:24:00,410 --> 00:24:05,570 +وساء سبيلة و مثل قوله تبارك وتعالى لا يغتب بعضكم + +220 +00:24:05,570 --> 00:24:14,580 +بعضةلا تلمسوا أنفسكم لا تجسسوا إلى غير ذلك من + +221 +00:24:14,580 --> 00:24:19,380 +الآيات التي صنعتي إلى ذكرها ضمن مجموعة الأخلاق + +222 +00:24:19,380 --> 00:24:27,330 +السلبية أو في معرض الذنب مثل قوله تبارك وتعالىإن + +223 +00:24:27,330 --> 00:24:32,450 +الذين يأكلون أموال اليتام ظلمًا إنما يأكلون في + +224 +00:24:32,450 --> 00:24:46,350 +بطونهم نارًا و سيصلون سعيرًا والعياذ + +225 +00:24:46,350 --> 00:24:51,450 +بالله فالأخلاق السلبية هي التي وردت على شكل نواهن + +226 +00:24:51,450 --> 00:24:56,170 +أو في معرض الزمن نعم الآن نأتي إلى + +227 +00:24:58,950 --> 00:25:09,350 +ضرب الأمثلة سريعا فنبدأ بمجموعة الأخلاق الإيجابية + +228 +00:25:09,350 --> 00:25:16,830 +و كما سنرى أنها جاءت على شكل أوامر أو في معرض + +229 +00:25:16,830 --> 00:25:22,830 +المدحنبدأ بخلق الصبر فالله تبارك وتعالى يقول يا + +230 +00:25:22,830 --> 00:25:27,350 +أيها الذين آمنوا اصبروا وصابروا ورابطوا واتقوا + +231 +00:25:27,350 --> 00:25:34,210 +الله لعلكم تفلحون فالصبر خلق إيجابي لماذا لأنه جاء + +232 +00:25:34,210 --> 00:25:38,710 +بصيغة الأمر يا أيها الذين آمنوا اصبروا وصابروا + +233 +00:25:38,710 --> 00:25:43,970 +ورابطوا واتقوا الله لعلكم تفلحون وكذلك قوله تعالى + +234 +00:25:43,970 --> 00:25:50,240 +واصبروافقوله واصبر أمر والأمر كما قلنا خلق إيجابي + +235 +00:25:50,240 --> 00:25:54,640 +لأن الله لا يأمر إلا بالأخلاق الإيجابية فإن الله + +236 +00:25:54,640 --> 00:26:00,720 +لا يضيع أجر المحصنين وقوله تعالى فاصبر إن وعد الله + +237 +00:26:00,720 --> 00:26:08,300 +حق ثانيا الوفاء كذلك من مجموعة الأخلاقالإيجابية + +238 +00:26:08,300 --> 00:26:13,780 +قوله تبارك وتعالى وأوفوا بالعهد إن العهد كان مسئول + +239 +00:26:13,780 --> 00:26:19,040 +فهذه الآية مثال للأخلاق الإيجابية لأنها جاءت على + +240 +00:26:19,040 --> 00:26:23,920 +صيغة الأمر وأوفوا بالعهد نعم وأما قوله تبارك + +241 +00:26:23,920 --> 00:26:28,720 +وتعالى والموفون بعهدهم إذا عاهدوا فقد جاءت في معرض + +242 +00:26:28,720 --> 00:26:35,870 +المدح فهي خلقإيجابي و أما الصدق هو ما أدراك ما + +243 +00:26:35,870 --> 00:26:41,950 +الصدق فهو قمة الأخلاق الإيجابية لأن النبي عليه + +244 +00:26:41,950 --> 00:26:46,330 +الصلاة والسلام سؤل في أكثر من موضوع أ يكون المؤمن + +245 +00:26:48,640 --> 00:26:53,160 +جبانا قال نعم قد يجب خوفا على نفسه او خوفا على + +246 +00:26:53,160 --> 00:26:59,780 +ماله وولده ايكون المؤمن بخيلا قال نعم فقيل ايكون + +247 +00:26:59,780 --> 00:27:09,010 +المؤمن كذابا قال لا فالمؤمن صادقلأن الكذب و هو ضد + +248 +00:27:09,010 --> 00:27:16,290 +الصدق من الأخلاق السلبية من أخلاق الكافرين و من + +249 +00:27:16,290 --> 00:27:22,990 +أخلاق المنافقين فالمنافق إذا حدث كذبوإذا وعد أخلف + +250 +00:27:22,990 --> 00:27:27,870 +وإذا أتمنى خال أما المؤمن إذا حدث صدق وإذا وعد + +251 +00:27:27,870 --> 00:27:35,010 +أوفى وإذا أتمنى أدى فالصدق مثال الأخلاق الإيجابية + +252 +00:27:35,010 --> 00:27:38,510 +قال الله تبارك وتعالى يا أيها الذين أمنوا اتقوا + +253 +00:27:38,510 --> 00:27:44,630 +الله وكونوا مع الصادقين فقوله تبارك وتعالى وكونوا + +254 +00:27:44,630 --> 00:27:53,320 +مع الصادقين هذا أمر وكما قلنامن تعريف الأخلاق + +255 +00:27:53,320 --> 00:27:57,940 +الإيجابية أنها جاءت على شكل أوامر وقوله تبارك + +256 +00:27:57,940 --> 00:28:03,020 +وتعالى وقل رب أدخلني مدخل صدق وأخرجني مخرج صدق + +257 +00:28:03,020 --> 00:28:09,980 +واجعل لي من لدنك سلطانا نصيرا هذا هو خلق الصدق وقد + +258 +00:28:09,980 --> 00:28:15,160 +مر بنا قبل قليل في المرحلة الثانية من مراحل توجيه + +259 +00:28:15,160 --> 00:28:23,440 +الخلق في النفس البشرية كيف أن الصدقطريق إلى الجنة + +260 +00:28:23,440 --> 00:28:31,540 +نعم إن البر يهدي إلى الجنة وإن الصدق يهدي إلى + +261 +00:28:31,540 --> 00:28:36,960 +الجنة وإن الرجل ليصدق ويتحرص صدق حتى يُكتب عند + +262 +00:28:36,960 --> 00:28:44,860 +الله صديقة نعم أما الأمانة فهي كذلك مثال من أمثلة + +263 +00:28:44,860 --> 00:28:48,920 +الأخلاق الإيجابية لقوله تبارك وتعالى إن الله + +264 +00:28:48,920 --> 00:28:56,780 +يأمركمأمر وقلنا الأمر هنا من تعريف الأخلاق + +265 +00:28:56,780 --> 00:29:01,440 +الإيجابية إن الله يأمركم أن تؤدوا الأمانات إلى + +266 +00:29:01,440 --> 00:29:06,920 +أهلها وقوله صلى الله عليه وسلم أد الأمانة إلى من + +267 +00:29:06,920 --> 00:29:12,830 +اقتمنكفالأمانة أيضًا خلق إيجابي بنص هذا الحديث + +268 +00:29:12,830 --> 00:29:18,090 +لأنها جاءت على شكل أمر أدّي الأمانة إلى من اقتمنك + +269 +00:29:18,090 --> 00:29:23,410 +وكذلك العدل من مجموعة الأخلاق الإيجابية لقوله + +270 +00:29:23,410 --> 00:29:30,290 +تبارك وتعالى إن الله يأمر بالعدل والإحسان وإيتاء + +271 +00:29:30,290 --> 00:29:37,200 +ذي القربة ويقول عز وجل ولا يجري منكمشنقان قوم على + +272 +00:29:37,200 --> 00:29:41,160 +أن لا تعدلوا اعدله وأقربوا للتقوى وهذه الآية + +273 +00:29:41,160 --> 00:29:46,780 +الكريمة من صدر صورة المائدة سنعود إليها عند الوصول + +274 +00:29:46,780 --> 00:29:51,540 +إلى الفصل السادس إن أحيان الله مع القاعدة الثانية + +275 +00:29:51,540 --> 00:29:59,050 +من قواعد النظام السياسي العدل والمساواةو سنأتي إلى + +276 +00:29:59,050 --> 00:30:05,350 +هذا العنوان المهم وهو أن العدل في الإسلام لا يتأثر + +277 +00:30:05,350 --> 00:30:11,750 +بالهواء فلابد أن تحكم بالعدل حتى و لو كان الخصم + +278 +00:30:11,750 --> 00:30:21,090 +ولادك أو أباك أو أخاك أو زوجك أو أقرب الناس إليك + +279 +00:30:21,090 --> 00:30:26,890 +ستأتي معنا هذه الآية وهي الآية السامنة من صدر صورة + +280 +00:30:26,890 --> 00:30:30,640 +المائدةوَلَا يَجْرِمَنَّكُمْ شَنَآنُ قَوْمٍ أَي + +281 +00:30:30,640 --> 00:30:34,680 +مُغْضُ قَوْمٍ عَلَى أَلَّا تَعْدِلُ إِعْدِلُ هو + +282 +00:30:34,680 --> 00:30:41,900 +أقرب للتقوى والآية أيضًا 135 من صورة النساء يا + +283 +00:30:41,900 --> 00:30:47,680 +أيها الذين أمنوا كونوا قوامين بالقصة شهداء لله ولو + +284 +00:30:47,680 --> 00:30:52,880 +على أنفسكم أو الوالدين والأقربين إلى آخري الآية + +285 +00:30:52,880 --> 00:30:58,500 +ونحن هنا نتكلم عن العدل كخلق إيجابييقول صلى الله + +286 +00:30:58,500 --> 00:31:03,000 +عليه وسلم فاتقوا الله واعدلوا بين أولادكم أيضًا + +287 +00:31:03,000 --> 00:31:09,980 +كما نرى أن صيغة أمر وصيغة الأمر دلالة على أن الخلق + +288 +00:31:09,980 --> 00:31:14,240 +إيجابي لأن الله لا يأمر كما أسلفنا إلا بالأخلاق + +289 +00:31:14,240 --> 00:31:19,220 +الإيجابية ولا ينهى إلا عن الأخلاق السلبية فاتقوا + +290 +00:31:19,220 --> 00:31:23,800 +الله واعدلوا بين أولادكم هذه دعوة إلى أولياء + +291 +00:31:23,800 --> 00:31:29,230 +الأموروإلى الآباء أن يعدلوا بين أولادهم وأن لا + +292 +00:31:29,230 --> 00:31:35,870 +يفرقوا بينهم بأن يكتب إلى هذا شيئا وأن يحرم هذا أو + +293 +00:31:35,870 --> 00:31:41,890 +أن يفرق بين الزوجتين الأولى والثانية فيخصوا + +294 +00:31:41,890 --> 00:31:47,360 +الثانيةبشيء بينما يحرم الزوجة الأولى وأولادها + +295 +00:31:47,360 --> 00:31:52,700 +وهكذا دعوة من الرسول إلى تقوى الله وإلى العدل بين + +296 +00:31:52,700 --> 00:31:59,660 +الأولاد والكلام ليس هنا محله وسيأتي في مواضع أخرى + +297 +00:31:59,660 --> 00:32:06,620 +من أبواب الفقه الإسلامي الإحسان كذلك وقد مرت بنا + +298 +00:32:06,620 --> 00:32:11,200 +نفس الآية من صورة النحل كما أسلفنا إن الله يأمر + +299 +00:32:11,200 --> 00:32:18,290 +بالعدلوالإحساني وإيتاء ذي القربة رأيتم أن الآية + +300 +00:32:18,290 --> 00:32:25,110 +نفسها يمكن أن يستشهد بها في أكثر من موضع في + +301 +00:32:25,110 --> 00:32:30,450 +الأسئلة فهذه الآية دليل على خلق العدلوهو خلق + +302 +00:32:30,450 --> 00:32:35,230 +إيجابي وهي دليل على خلق الإحسان وهو خلق إيجابي إن + +303 +00:32:35,230 --> 00:32:41,310 +الله يأمر بالعدل والإحسان وإيتاء ذي القربة وقوله + +304 +00:32:41,310 --> 00:32:47,470 +تبارك وتعالى وأحسن أمر إن الله يحب المحسنين مدحك + +305 +00:32:47,470 --> 00:32:52,670 +رأيتم هنا هذه الآية الكريمة جمعت التعريف كله + +306 +00:32:52,670 --> 00:32:58,960 +فالأخلاق الإيجابية هي التي وردت على شكل أوامروهنا + +307 +00:32:58,960 --> 00:33:07,930 +وأحصن أمر فالإحسان خلق إيجابيأو جاءت في معرض المدح + +308 +00:33:07,930 --> 00:33:14,010 +ان الله يحب المحسنين جاءت في معرض المدح وفي الحديث + +309 +00:33:14,010 --> 00:33:22,550 +أيضا و هذا الحديث سنأتي اليه أيضا عند الكلام عن + +310 +00:33:22,550 --> 00:33:28,070 +خصائص الأخلاق بعد قليل عند الحديث عن خاصية الشمول + +311 +00:33:28,070 --> 00:33:36,410 +عند الحديث عن شمول الأخلاقللتعامل مع الكائنات + +312 +00:33:36,410 --> 00:33:43,970 +الأخرى كالحيوان والطير والنبات وغير ذلك فانتبهوا + +313 +00:33:43,970 --> 00:33:48,210 +إلى هذا الحديث لأنه من الحديث المهمة التي ستسألون + +314 +00:33:48,210 --> 00:33:54,250 +عنها قوله عليه الصلاة والسلام عن شداد ابن أوسإن + +315 +00:33:54,250 --> 00:34:00,150 +الله كتب الإحسان على كل شيء فإذا قتلتم فاحصنوا + +316 +00:34:00,150 --> 00:34:06,490 +القتلة وإذا ذبحتم فاحصنوا الذبحة وليحد أحدكم شفرة + +317 +00:34:06,490 --> 00:34:13,990 +وليريح ذبيحته نعم فهذا هو خلقهالإحسان وهو خلق + +318 +00:34:13,990 --> 00:34:21,270 +إيجابي جاء الأمر به وجاء المدح به في كلام الله وفي + +319 +00:34:21,270 --> 00:34:25,990 +كلام رسول الله صلى الله عليه وسلم كذلك العفو من + +320 +00:34:25,990 --> 00:34:32,680 +أخلاق المؤمنين ومن أخلاقالصالحين فقد قال الله + +321 +00:34:32,680 --> 00:34:38,660 +تبارك وتعالى والعافينا عن الناس نعم خذ العفوة وأمر + +322 +00:34:38,660 --> 00:34:44,820 +بالعرفي وأعرض عن الجاهلين خذ العفوة وجاءت أمر + +323 +00:34:44,820 --> 00:34:49,320 +والعافينا عن الناس مدح وقوله تبارك وتعالى وأن + +324 +00:34:49,320 --> 00:34:56,400 +تعفوا أقربوا للتقوى فهذا فعلا من أخلاق الصالحين بل + +325 +00:34:56,400 --> 00:35:03,400 +من أخلاق الأنبياءوالمرسلين رأيتم بعد أن فتح الله + +326 +00:35:03,400 --> 00:35:07,480 +مكة على رسول الله صلى الله عليه وسلم وقد اجتمع + +327 +00:35:07,480 --> 00:35:13,870 +القوم حولهما تظنون أني فاعل بكم قالوا خير أخ كريم + +328 +00:35:13,870 --> 00:35:18,150 +وابن أخ كريم وبإمكانه عليه الصلاة والسلام أن يسأر + +329 +00:35:18,150 --> 00:35:26,970 +وأن ينتقم كيف لا وقد آذوه وقد أخرجوه من مكة وطنه + +330 +00:35:26,970 --> 00:35:32,030 +ومسقط رأسه ولكنه عليه الصلاة والسلام أراد أن يعلم + +331 +00:35:32,030 --> 00:35:39,090 +البشرية جمعه درثا في السماحة و العفو عند المقدرةما + +332 +00:35:39,090 --> 00:35:44,170 +تظنون أني فاعل بكم؟ قالوا خير أخ كريم وابن أخ كريم + +333 +00:35:44,170 --> 00:35:50,830 +قال إن مثلي ومثلكم كمثل يوسف مع إخوته قال لا تثريب + +334 +00:35:50,830 --> 00:35:55,950 +عليكم اليوم الله يغفر لكم وهو أرحم الراحمين اذهبوا + +335 +00:35:55,950 --> 00:36:00,190 +فانتم الطلقاء هذه الأخلاق السامية و هذه الأداب + +336 +00:36:00,190 --> 00:36:06,590 +الرفيعة جعلت من هؤلاء الأعراب جلاف الطباع قصات + +337 +00:36:06,590 --> 00:36:12,720 +القلوبيدخلون في دين الله أفواجاونزل قوله تبارك + +338 +00:36:12,720 --> 00:36:16,480 +وتعالى باسم الله الرحمن الرحيم إذا جاء نصر الله + +339 +00:36:16,480 --> 00:36:21,420 +والفتح ورأيت أنها سيدخلون في دين الله أفواجا فسبح + +340 +00:36:21,420 --> 00:36:28,420 +بحمد ربك واستغفر إنه كان توابا نعم هذه أمثلة + +341 +00:36:28,420 --> 00:36:36,520 +ونمازج لمجموعة الأخلاق الإيجابية نقتصر عليها كما + +342 +00:36:36,520 --> 00:36:42,930 +اقتصر الكتاب المقرر وفيها كفايةوغنية إن شاء الله + +343 +00:36:42,930 --> 00:36:46,870 +وطبعا وطبعا وكما رأينا إما أن تكون على شكل أوامر + +344 +00:36:46,870 --> 00:36:52,970 +وإما أن تكون في معرض المدى أما ثانيا مجموعة + +345 +00:36:52,970 --> 00:37:00,310 +الأخلاق السلبية التي ذمها الله في القرآن الكريم أو + +346 +00:37:00,310 --> 00:37:07,550 +جاءت على شكل نواهن وأول هذه الأخلاق السلبية الظلم + +347 +00:37:08,480 --> 00:37:11,520 +فقد قال الله تبارك وتعالى وَسَيَعْلَمُ الَّذِينَ + +348 +00:37:11,520 --> 00:37:15,200 +ظَلَمُ أَيَّ مُنْقَلَبٍ يَنْقَلِبُونَ فهنا جاءت + +349 +00:37:15,200 --> 00:37:22,400 +الآية في معرض الزمن لأن الله زم الظلم توعدهم + +350 +00:37:22,400 --> 00:37:28,880 +سبحانه وتعالى وقوله إنه لا يفلح الظالمون كذلك جاءت + +351 +00:37:28,880 --> 00:37:35,160 +في معرض الزمن وقوله تبارك وتعالى وما للظالمين + +352 +00:37:35,160 --> 00:37:41,790 +بالأنصار هذه الآيات الثلاثكلها جاءت في معرض الذنب + +353 +00:37:41,790 --> 00:37:48,570 +فدل على أن الظلمة من الأخلاق هي السلبية ويتأكد هذا + +354 +00:37:48,570 --> 00:37:53,070 +بقوله عليه الصلاة والسلام المسلم أخ المسلم لا + +355 +00:37:53,070 --> 00:38:03,710 +يظلمه ولا يسلمه لأنها جاءت في معرض النهيوفي معرض + +356 +00:38:03,710 --> 00:38:10,690 +الذنب كما نرى وقوله لا يسلمه يعني لا يخذله فلا يحل + +357 +00:38:10,690 --> 00:38:16,870 +للمسلم أن يظلم أخاه أو أن يخذل أخاهه إذا كان بحاجة + +358 +00:38:16,870 --> 00:38:23,050 +إلى النصرة والكذب ولا عياذ بالله وقد تكلمنا أن + +359 +00:38:23,050 --> 00:38:28,310 +الكذب من أخلاق الكافرينوإنما يفتر الكذب الذين لا + +360 +00:38:28,310 --> 00:38:32,430 +يؤمنون بآية الله فالقولت إن الكذب من أخلاق + +361 +00:38:32,430 --> 00:38:37,910 +المنافقين إذا حدث كذب والمؤمن كما جاء في الحديث قد + +362 +00:38:37,910 --> 00:38:44,760 +يشبن أحيانا خوفا على نفسهفي خوض المعارك والحروب و + +363 +00:38:44,760 --> 00:38:50,700 +أحيانا قد يبخل بماله فلا ينفق أما أن يكون كذابا + +364 +00:38:50,700 --> 00:38:57,700 +فلا نعم قال الله تبارك وتعالى في ذنب خلق الكذب فمن + +365 +00:38:57,700 --> 00:39:03,700 +أظلم من من كذب على الله وكذب بالصدق إذ جاءه وقوله + +366 +00:39:03,700 --> 00:39:09,420 +تبارك وتعالى ويوم القيامة هذه في معرض الذنبويوم + +367 +00:39:09,420 --> 00:39:14,640 +القيامة ترى الذين كذبوا على الله وجوههم مسودة نسأل + +368 +00:39:14,640 --> 00:39:20,400 +الله السلامة والعافية وفي الحديث الذي تكلمنا عنه + +369 +00:39:20,400 --> 00:39:26,000 +عند المرحلة الثانية من مراحل توجيه الخلق في النفس + +370 +00:39:26,000 --> 00:39:32,120 +البشرية عندما تكلمنا عن استقرار الخلق ورسوخه في + +371 +00:39:32,120 --> 00:39:37,740 +النفس البشرية فقد تكلمنا عن الصدق في مجموعة + +372 +00:39:37,740 --> 00:39:42,670 +الأخلاقالإيجابية والآن نتكلم عن الكذب في مجموعة + +373 +00:39:42,670 --> 00:39:47,190 +الأخلاق السلبية فالرسول ينهانا عن الكذب اياكم + +374 +00:39:47,190 --> 00:39:52,730 +والكذبة فإن الكذبة يهدي إلى الفجور وإن الفجور يهدي + +375 +00:39:52,730 --> 00:40:00,080 +إلى الناروما يزال الرجل يكذب ويتحرى الكاذبة حتى + +376 +00:40:00,080 --> 00:40:05,440 +يُكتب عند الله كذابا صيغة مبالغة والعياذ بالله + +377 +00:40:05,440 --> 00:40:12,980 +كذاب على وزن فعال فالكذب فعلاكما قال هنا في الكتاب + +378 +00:40:12,980 --> 00:40:19,980 +مضيعة للحقوق وتزيف للحقائق بل غش وخيانة والعياذ + +379 +00:40:19,980 --> 00:40:26,990 +بالله أما الخيانة أيضا فهي من الأخلاقالسلبية وقد + +380 +00:40:26,990 --> 00:40:31,330 +نهان الله تبارك وتعالى عن هذا الخلق الزميم فقال + +381 +00:40:31,330 --> 00:40:36,110 +كما في صورة الأنفال يا أيها الذين آمنوا لا تخونوا + +382 +00:40:36,110 --> 00:40:42,330 +الله والرسول وتخونوا أماناتكم وأنتم تعلمون وقول هو + +383 +00:40:42,330 --> 00:40:46,770 +عليه الصلاة والسلام أدل أمانة إلى من اتمنك أدل + +384 +00:40:46,770 --> 00:40:52,530 +أمانة خلق إيجابي لأنها جاءت على شكل أوامر ولا تخن + +385 +00:40:52,530 --> 00:41:04,020 +من خانكخلق سلبي لأنها جاءت على شكل نواهن نعم وكذلك + +386 +00:41:04,020 --> 00:41:11,200 +النهي عن الصخرية والاستهزاء بالاخرين وهذه مجموعة + +387 +00:41:11,200 --> 00:41:15,980 +من الأخلاق السلبية جاءت في صورة الحجرات وصورة + +388 +00:41:15,980 --> 00:41:23,570 +الحجرات تسمى عند المفسرين بصورة الأدابلما فيها من + +389 +00:41:23,570 --> 00:41:31,510 +الأخلاق الإيجابية التي أمرت بها هذه الآيات + +390 +00:41:31,510 --> 00:41:35,590 +الكريمات ولما فيها من الأخلاق السلبية التي نهت + +391 +00:41:35,590 --> 00:41:39,970 +عنها هذه الآيات نعم فالله تبارك وتعالى يقول يا + +392 +00:41:39,970 --> 00:41:45,350 +أيها الذين آمنوا لا يسخر قوم من قومعسى أن يكونوا + +393 +00:41:45,350 --> 00:41:51,030 +خيرا منهم ولا نساء من نساء عسى أن يكون خيرا منهم + +394 +00:41:51,030 --> 00:41:56,550 +ولا تلمزوا أنفسكم ولا تنابزوا بالألقاب بئس اسم + +395 +00:41:56,550 --> 00:42:01,250 +الفصوخ بعد الإيمان ومن لم يتب فأولئك هم الظالمون + +396 +00:42:01,250 --> 00:42:06,810 +فهذه الآيات تنهى عن الصخرية والاستهزاء تنهى عن + +397 +00:42:06,810 --> 00:42:14,580 +الغمز واللمز والطعن في أعراض الناسوانتقاص قدرهم + +398 +00:42:14,580 --> 00:42:22,060 +وكذلك الآيات التي نهت عن سوء الظن بالمؤمنين وعن + +399 +00:42:22,060 --> 00:42:26,640 +التجسس كما قال الله تبارك وتعالى في صورة نفسها بعد + +400 +00:42:26,640 --> 00:42:31,360 +هذه الآية يا أيها الذين آمنوا اجتنبوا كثيرا من + +401 +00:42:31,360 --> 00:42:37,240 +الظن إن بعض الظن إذن ولا تجسسوا ولا يغتب بعضكم + +402 +00:42:37,240 --> 00:42:43,120 +بعضا أي حب أحدكم أن يأكل لحم أخيه ميتا فكرتهواتقوا + +403 +00:42:43,120 --> 00:42:50,780 +الله إن الله تواب رحيم صدق الله العظيم نعم إذا + +404 +00:42:50,780 --> 00:42:58,160 +الأن نكون قد انتهينا من الخاصية الأولى من خصائص + +405 +00:42:58,160 --> 00:43:07,400 +نظام الأخلاق في الإسلام ألا وهو خلقنعم التعميم + +406 +00:43:07,400 --> 00:43:17,920 +والتفصيل ثانيا الشمول أما الشمول فمعنى ذلك أن + +407 +00:43:17,920 --> 00:43:26,710 +الأخلاق شاملة لعلاقة الإنسان مع ربهوشاملة لعلاقة + +408 +00:43:26,710 --> 00:43:33,630 +الإنسان مع نفسه وشاملة لعلاقة الإنسان مع غيره + +409 +00:43:33,630 --> 00:43:41,490 +وشاملة لعلاقة الإنسان مع الدول أو ما يسمى + +410 +00:43:41,490 --> 00:43:50,990 +بالعلاقات الخارجية و كذلك في حال السلم و في حال + +411 +00:43:50,990 --> 00:43:59,030 +الحربألفت الأنظار هنا بأن خاصية الشمول هي خاصية من + +412 +00:43:59,030 --> 00:44:08,710 +خصائص النظم بوجه عام تكلمنا عن خاصية النظم وهي + +413 +00:44:08,710 --> 00:44:16,510 +الشمول بوجه عام والآن نأتي إلى خاصية الشمول وهي + +414 +00:44:16,510 --> 00:44:23,060 +خاصية من خصائص نظام الأخلاق بوجه خاصفإذا ما جاء + +415 +00:44:23,060 --> 00:44:31,660 +سؤال مثلا في الإختيار المتعدد تعتبر خاصية الشمول + +416 +00:44:31,660 --> 00:44:42,300 +من خصائص ألف نظام الأخلاق في الإسلام بوجه عام نعم + +417 +00:44:42,300 --> 00:44:47,020 +وخصائص نظام الأخلاق + +418 +00:44:47,930 --> 00:44:55,810 +نعم فتكون شاملة لخصائص الأخلاق وتكون شاملة لخصائص + +419 +00:44:55,810 --> 00:45:03,900 +النظم الإسلامية بوجه عامهنا في الكتاب لم يضرب + +420 +00:45:03,900 --> 00:45:09,380 +مثالًا لعلاقة الإنسان مع الله تبارك وتعالى أو مع + +421 +00:45:09,380 --> 00:45:17,880 +خالقه وما أكثرها فالصلاة تربط العبد بربه وكذلك + +422 +00:45:17,880 --> 00:45:24,440 +أركان الإسلام من حج و ذكاء و صوم و نحو ذلك أما + +423 +00:45:26,340 --> 00:45:31,540 +أن شمول الأخلاق لعلاقة الإنسان مع نفسه فقد ضرب لنا + +424 +00:45:31,540 --> 00:45:36,300 +مثالين المثال الأول الصبر واصبر فإن الله لا يضيع + +425 +00:45:36,300 --> 00:45:42,940 +أجر المحسنين وكذلك في الإصراف وكلوا واشربوا ولا + +426 +00:45:42,940 --> 00:45:51,660 +تصرفوا فنرى أن نظام الأخلاقيربط الإنسان بنفسه + +427 +00:45:51,660 --> 00:46:00,000 +وكذلك عن شمول نظام الأخلاق لعلاقة المسلم مع أخيه + +428 +00:46:00,000 --> 00:46:06,680 +المسلم مع أفراد المجتمع الواحد ومثله كل ما ذكرنا + +429 +00:46:06,680 --> 00:46:12,270 +في صورة الحجراتمن قوله يا أيها الذين آمنوا لا يسخر + +430 +00:46:12,270 --> 00:46:16,550 +قوم من قوم إلى قوله يا أيها الذين آمنوا اجتنبوا + +431 +00:46:16,550 --> 00:46:21,310 +كثيرا من الظن ولا نقتصر على التجسس وإن كان في + +432 +00:46:21,310 --> 00:46:26,690 +الكتاب قد ذكر مثلا ولا تجسسه لكن يصلح مثلا أيضا لا + +433 +00:46:26,690 --> 00:46:34,330 +يسخر لا تلمسوا أنفسكم اجتنبوا كثيرا من الظن واما + +434 +00:46:35,580 --> 00:46:40,220 +شمول الأخلاقي لتصرفات الإنسان مع غيرهم من الكائنات + +435 +00:46:40,220 --> 00:46:46,640 +الأخرىوهذه لابد أن نقف عندها قليلا لأن الكل يسأل + +436 +00:46:46,640 --> 00:46:51,640 +ما المقصود بالكائنات الأخرى أقول الكائنات الأخرى + +437 +00:46:51,640 --> 00:46:58,460 +ما عدا الإنسان من حيوان وطير ونبات وقد أشرت إلى + +438 +00:46:58,460 --> 00:47:02,780 +هذا الحديث لما تكلمت عن مجموعة الأخلاق الإيجابية + +439 +00:47:02,780 --> 00:47:07,820 +عن الإحسان ودليله هنا قوله عليه الصلاة والسلام إن + +440 +00:47:07,820 --> 00:47:13,320 +الله كتب الإحسان على كل شيءفإذا قتلتم فاحصنوا + +441 +00:47:13,320 --> 00:47:18,320 +القتلة وإذا ذبحتم فاحصنوا الذبحة وليحد أحدكم شفرة + +442 +00:47:18,320 --> 00:47:25,360 +وليريح ذبيحته فهذا دليل على علافة الإنسان حتى مع + +443 +00:47:25,360 --> 00:47:29,420 +غير الإنسان من الحيوانات والطيور ويمكن أن نستدل + +444 +00:47:29,420 --> 00:47:34,800 +بادلة أخرى مثل قوله عليه الصلاة والسلام أنرجلًا + +445 +00:47:34,800 --> 00:47:39,820 +أدخله الله الجنة بكلب سقاه وأن امرأة أدخلها الله + +446 +00:47:39,820 --> 00:47:45,540 +النار بهرة حبستها فلا هي أطعمتها ولا هي تركتها + +447 +00:47:45,540 --> 00:47:52,530 +تأكل من خشاش الأرض وكذلكالأخلاق تأتي شاملة لعلاقة + +448 +00:47:52,530 --> 00:47:57,930 +الإنسان مع الدول والجماعات هذا يدرس في كلية + +449 +00:47:57,930 --> 00:48:01,790 +الشريعة والقانون في الجامعة الإسلامية تحت عنوان + +450 +00:48:01,790 --> 00:48:07,750 +العلاقات الدولية أو العلاقات الخارجية في حال السلم + +451 +00:48:07,750 --> 00:48:12,430 +وفي حال الحرب وفي حال العهود التي تكون بين الدول + +452 +00:48:12,430 --> 00:48:17,610 +غير المسلمة المجاورة للدولة الإسلامية ومثاله هو + +453 +00:48:17,610 --> 00:48:25,340 +اوفوا بالعهدإن العهد كان مسئولا نقف إلى هنا إن شاء + +454 +00:48:25,340 --> 00:48:31,860 +الله تبارك وتعالى عند ثالثا من خصائص نظام الأخلاق + +455 +00:48:31,860 --> 00:48:38,500 +في الإسلام فالأخلاق ضابطة لسلوك الإنسان وتصرفاته + +456 +00:48:38,500 --> 00:48:43,060 +والسلام عليكم ورحمة الله وبركاته + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/bOshnldAHLg_postprocess.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/bOshnldAHLg_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..84715f44a3e769e8c246b5653aacbd656078fafb --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/bOshnldAHLg_postprocess.srt @@ -0,0 +1,1360 @@ +1 +00:00:05,010 --> 00:00:07,350 +أعوذ بالله السماء العليا من الشياطين الردين باسم + +2 +00:00:07,350 --> 00:00:10,550 +الله الرحمن الرحيم الحمد لله والصلاة والسلام على + +3 +00:00:10,550 --> 00:00:16,330 +رسول الله دائما و أبدا نعطر مجالسنا ونبدأ محاضرتنا + +4 +00:00:16,330 --> 00:00:20,930 +بالصلاة على الحبيب محمد صلى الله عليه وسلمقبل ذي + +5 +00:00:20,930 --> 00:00:25,750 +بدء أعزائي وأبناء الطلاب في مساقة النظم الإسلامية + +6 +00:00:25,750 --> 00:00:29,950 +أرحب بكم جميعا وأحييكم بتحية الإسلام العظيم + +7 +00:00:29,950 --> 00:00:34,570 +فالسلام الله عليكم ورحمته وبركته بعد أن انتهينا من + +8 +00:00:34,570 --> 00:00:38,850 +الفصل الثالث وكان بانواع نظام الأخلاق في الإسلام + +9 +00:00:38,850 --> 00:00:46,180 +اليوم نرحل بصحبتكم بمشيئة اللهإلى الفصل الرابع وهو + +10 +00:00:46,180 --> 00:00:53,700 +بعنوان نظام الأسرة في الإسلام وهو يجتمن على خمسة + +11 +00:00:53,700 --> 00:00:58,820 +مباحث أول + +12 +00:00:58,820 --> 00:01:05,640 +هذه المباحث تعريف الأسرة في الإسلام لغة واصطلاحا + +13 +00:01:05,640 --> 00:01:12,060 +المبحث الثاني الأسس التي يقوم عليها نظام الأسرة في + +14 +00:01:12,060 --> 00:01:19,370 +الإسلامأما المبحث الثالث فهو بانوان الزواج أما + +15 +00:01:19,370 --> 00:01:22,950 +المبحث الرابع فهو بانوان الطلاق والمبحث الخامس + +16 +00:01:22,950 --> 00:01:31,730 +والأخير بانوان مكانة المرأة وحقوقها في الإسلام أما + +17 +00:01:31,730 --> 00:01:39,250 +المبحث الأول وهو تعريف الأسرة فالأسرة في لغة العرب + +18 +00:01:39,250 --> 00:01:50,890 +بمعنى الدرع الحصينةالدرع الحصينة لأن الرجل إنما + +19 +00:01:50,890 --> 00:02:00,910 +يتقوى بأسرته مثل الفارس أو المحارب في أرض المعركة + +20 +00:02:00,910 --> 00:02:08,410 +الذي يتقوى بدرعه الحصينة والأسرة هم أهل الرجل + +21 +00:02:08,410 --> 00:02:15,180 +وعشيرتهوتطلق أيضًا على الجماعة التي يربطها أمر + +22 +00:02:15,180 --> 00:02:21,820 +مشترك فالمسلمون اليوم في مشارق الأرض ومغاربها إنما + +23 +00:02:21,820 --> 00:02:28,740 +هم أسرة واحدة بل أمة واحدة كما ذكر القرآن الكريم + +24 +00:02:28,740 --> 00:02:36,800 +في موضعيني وإن هذه أمتكم أمة واحدة وأنا ربكم + +25 +00:02:36,800 --> 00:02:47,250 +فاعبدون وأنا ربكم فاتقونأما الأسرة شرعا فهي الخلية + +26 +00:02:47,250 --> 00:02:54,250 +الاجتماعية الأولى التي تنشأ عن ارتباط رجل بامرأة + +27 +00:02:54,250 --> 00:03:03,450 +بعقد شرعي هو عقد النكاح ونحن منذ الصغر تعلمنا أن + +28 +00:03:03,450 --> 00:03:10,400 +الأسرة هي الخلية الاجتماعية الأولىوالتي تكون من + +29 +00:03:10,400 --> 00:03:18,220 +رجل وامرأة بعقد شرعي هو عقد النكاح وأن هذه الأسرة + +30 +00:03:18,220 --> 00:03:26,320 +هي أساس المجتمع فإذا ما صلحت صلح المجتمع وإذا ما + +31 +00:03:26,320 --> 00:03:34,720 +فسدت فسد المجتمع نرى هنا ملحوظة مهمة جدا أن كل + +32 +00:03:34,720 --> 00:03:45,040 +ارتباط بين رجل وامرأةبغير عقد شرعي فهو زنا بل + +33 +00:03:45,040 --> 00:03:53,440 +فاحشة كما ذكر القرآن الكريم وساء سبيلا فلابد أن + +34 +00:03:53,440 --> 00:04:03,280 +تكون الأسرة منذ الخطوة الأولى أسرة شرعية على كتاب + +35 +00:04:03,280 --> 00:04:09,620 +اللهوعلى سنة رسول الله صلى الله عليه وسلم عبر + +36 +00:04:09,620 --> 00:04:19,600 +أبواب المحاكم الشرعية وبوساطة المأذون الشرعي + +37 +00:04:19,600 --> 00:04:29,720 +المكلف بعقد الزواج من قبل القضاء الشرعي نعم إذا + +38 +00:04:29,720 --> 00:04:38,650 +الأسرة في لغة العربهي الدرع الحصينة و هم أهل الرجل + +39 +00:04:38,650 --> 00:04:47,390 +و عشيرته لأنه يتقوى بهم و تطلق على الجماعة اللتي + +40 +00:04:47,390 --> 00:04:56,750 +يربطهم أمر مشترك و الأسرة شرعا و عندما أقول شرعا + +41 +00:04:56,750 --> 00:04:59,390 +يعني في الشرع + +42 +00:05:02,090 --> 00:05:10,170 +وهي من أجل الفائدة أقول منصوبة على نزع الخافض وهذا + +43 +00:05:10,170 --> 00:05:16,750 +ما يجهله كثير من أبنائنا الطلاب عندما نقول مثلا + +44 +00:05:16,750 --> 00:05:25,970 +الأسرة لغة الأسرة شرعا أو اصطلاحا ومعنى هذا الكلام + +45 +00:05:25,970 --> 00:05:33,390 +الأسرة في لغتهوالأسرة في الشرعي أو في الاصطلاحي + +46 +00:05:33,390 --> 00:05:39,750 +وهذه في لغة العرب إعرابها منصوبة على نزل الخافض ما + +47 +00:05:39,750 --> 00:05:49,210 +هو الخافض حرف الجر وهو في في هذا المثال كما يقال + +48 +00:05:49,210 --> 00:05:55,500 +في لغة العرب فلان يبيع الناسفقد يظن البعض أن + +49 +00:05:55,500 --> 00:06:04,560 +الناسة مفعول بيه لأ الناس هنا منصوبة بنزأ الخافض و + +50 +00:06:04,560 --> 00:06:11,520 +هو اللام و أصل الكلمة فلان يبيع للناس لأن عصر + +51 +00:06:11,520 --> 00:06:18,320 +العبيد و الرقير لم يعد له وجود و الناس لا يباعونه + +52 +00:06:18,320 --> 00:06:27,550 +نعمإذا الأسرة في الشرعي الحنيف هي الخلية + +53 +00:06:27,550 --> 00:06:36,510 +الاجتماعية الأولى التي تنشأ عن ارتباط رجل بامرأة + +54 +00:06:36,510 --> 00:06:48,260 +بزوج وزوجة بعقد شرعي من إيجاب وقبولهو عقد النكاح + +55 +00:06:48,260 --> 00:06:55,420 +الشراب أما المبحث الثاني فهي الأسس أو القواعد التي + +56 +00:06:55,420 --> 00:07:02,340 +يقوم عليها نظام الأسرة في الإسلام وهي أربعة كما + +57 +00:07:02,340 --> 00:07:09,580 +سنرها أول هذه الأسس أو تلك القواعد التي يقوم عليها + +58 +00:07:09,580 --> 00:07:16,120 +نظام الأسرة في الإسلام هو وحدة الأصل والمنشأةفكلكم + +59 +00:07:16,120 --> 00:07:26,380 +لآدم و آدم من تراب فالرجل والمرأة أو الزوج والزوجة + +60 +00:07:26,380 --> 00:07:34,290 +من أصل واحد كما قال الله تبارك وتعالىفي أكثر من + +61 +00:07:34,290 --> 00:07:39,250 +موضع في القرآن الكريم ومن هذه الآيات في صدر صورة + +62 +00:07:39,250 --> 00:07:44,990 +النساء يا أيها الناس اتقوا ربكم الذي خلقكم من نفس + +63 +00:07:44,990 --> 00:07:53,130 +واحدة وخلق منها زوجها وبث منهما رجال كشيرا ونساء + +64 +00:07:53,130 --> 00:07:58,990 +واتقوا الله الذي تساءلون به والأرحمة إن الله كان + +65 +00:07:58,990 --> 00:08:10,480 +عليكم رخيبا صدق الله العظيمفالناس أبوهم آدم وأمهم + +66 +00:08:10,480 --> 00:08:17,360 +حواء عليهم السلام ويقول الله تبارك وتعالى وهو الذي + +67 +00:08:17,360 --> 00:08:25,800 +أنشأكم من نفس واحدة فالناس جميعا يجمعهم نسب واحد + +68 +00:08:25,800 --> 00:08:35,780 +ويرجعون إلى أصل واحد وهم إخوة في الإنسانيةبدليل + +69 +00:08:35,780 --> 00:08:43,980 +قوله يا أيها الناس ومثلها في صورة الحجرات يا أيها + +70 +00:08:43,980 --> 00:08:50,340 +الناس إن خلقناكم من ذكر وأنثى وجعلناكم شعوب وقبائل + +71 +00:08:50,340 --> 00:08:56,600 +لتعارفوا إن أكرمكم عند الله أتخاكم إن الله عليم + +72 +00:08:56,600 --> 00:09:05,540 +خبير ومن هنا على القويأي يعتف على الضعيف وعلى + +73 +00:09:05,540 --> 00:09:11,940 +الغنيف أن يساعد الفقير حتى يتم بنيان المجتمع + +74 +00:09:11,940 --> 00:09:17,520 +الإنساني وإذا كان الناس جميعا من أصل واحد فليس + +75 +00:09:17,520 --> 00:09:27,400 +لأحد أن يفخر على أحد فلا يصح لشخص أن يفخر على أخيه + +76 +00:09:27,400 --> 00:09:38,900 +الإنسان بمال أو جمالأو عدد أو عدة لأن الآية بينت + +77 +00:09:38,900 --> 00:09:45,880 +الميزان الدقيق الذي هو أدقو عند الله من ميزان + +78 +00:09:45,880 --> 00:09:50,860 +الذهب والفضة ألا وهو التقوى يا أيها الناس إن + +79 +00:09:50,860 --> 00:09:56,640 +خلقناكم من ذكر وأنثى وجعلناكم شعوب وقبائل لتعرفوا + +80 +00:09:56,640 --> 00:10:08,410 +وهنا لتعرفوااللام في لغة العرب تعليلية بمعنى كي + +81 +00:10:08,410 --> 00:10:15,510 +تتعارفوا ويبقى شعارنا الخالد إن أكرمكم عند الله + +82 +00:10:15,510 --> 00:10:21,690 +أتقاكم حتى و لو كان أقل مالا أو جمالا أو حسبا أو + +83 +00:10:21,690 --> 00:10:30,510 +نسبا ثانيا من الأسس التيتقوم عليها الأسرة في + +84 +00:10:30,510 --> 00:10:36,190 +الإسلام المودة والرحمة وهذه الآية الكريمة من صورة + +85 +00:10:36,190 --> 00:10:43,630 +الروم سنرجع اليها في أكثر من موضع عند الحديث أيضًا + +86 +00:10:43,630 --> 00:10:52,330 +عن الزواج وحكم الزواج ومشروعية الزواج فالله تبارك + +87 +00:10:52,330 --> 00:11:00,260 +وتعالى يقول ومن آياته أي ومن دلائل قدرتهلأنه تكلم + +88 +00:11:00,260 --> 00:11:06,540 +في آيات الروم عن السماوات و عن الأرض و عن اختلاف + +89 +00:11:06,540 --> 00:11:15,820 +الألسن و البشرة من أبيضة و أسودة و من عرب و من عجم + +90 +00:11:15,820 --> 00:11:23,360 +و لكن يبقى الذي يجمعناهو تقوى الله تبارك تعالى + +91 +00:11:23,360 --> 00:11:29,800 +وأننا إخوة جميعا في الإنسانيته لأن الآيات بدأت بيا + +92 +00:11:29,800 --> 00:11:35,940 +أيها الناس يا أيها الناس يعني يا كل الناس ومن + +93 +00:11:35,940 --> 00:11:42,720 +آياته أي أن الزواج آية من آيات الله وهذا دليل على + +94 +00:11:42,720 --> 00:11:49,860 +عظم الزواج وخطورة أمر الزواجكيف لا وقد قال الله + +95 +00:11:49,860 --> 00:11:56,020 +وقد أفضأ بعضكم إلى بعض وأخذنا منكم ميثاقا غليظة + +96 +00:11:56,020 --> 00:12:02,180 +ومن آياته ومن دلائل قدرته أن خلق لكم من أنفسكم + +97 +00:12:02,180 --> 00:12:12,040 +أزواجا لتسكنوا إليها وجعل بينكم مودة ورحمة فكل من + +98 +00:12:12,040 --> 00:12:20,370 +الزوجين من أصل واحدكما أسلفنا في البندي الأول + +99 +00:12:20,370 --> 00:12:30,230 +فزوجته ليست من جنس آخر ليست غريبة عن هذا الزوج بل + +100 +00:12:30,230 --> 00:12:38,280 +من جنس الزوج من الطين والتراب وكما مر معنافي + +101 +00:12:38,280 --> 00:12:44,720 +الحديث كلكم لآدم و آدم من تراب ولذلك النبي عليه + +102 +00:12:44,720 --> 00:12:51,700 +الصلاة والسلام قال إنما النساء شقائق الرجال ومعنى + +103 +00:12:51,700 --> 00:13:01,120 +شقائق أنها شقة من الرجل فالمرأة شقة من الرجل فكأن + +104 +00:13:01,120 --> 00:13:08,800 +الرجل والمرأة شيء واحد في الأصلالرسول عليه الصلاة + +105 +00:13:08,800 --> 00:13:17,620 +والسلام شبههم بالعصة التي شُقت فصارت زوجا ومن كل + +106 +00:13:17,620 --> 00:13:25,840 +شيء خلقنا زوجين لعلكم تذكرون إنما النساء شقائق + +107 +00:13:25,840 --> 00:13:34,460 +الرجال وإنما المرأة خُلقت من ضلع الرجل + +108 +00:13:36,430 --> 00:13:44,170 +وإن أعلاه لأعوج إن ذهبت تقيمه كسرته وإن تركته لم + +109 +00:13:44,170 --> 00:13:50,810 +يزل أعوج نعم فاستوصوا بالنساء خيرا أو كما قال عليه + +110 +00:13:50,810 --> 00:13:56,470 +الصلاة والسلام رفقا بالقوارير شبه الزوجة بالقارورة + +111 +00:13:56,470 --> 00:14:06,460 +وهي الزجاجة التي صرعان ما تكسر وإذا كسرت فلاتجبر + +112 +00:14:06,460 --> 00:14:15,220 +نعم ومن آياته أن خلق لكم من أنفسكم أزواجا لتسكنوا + +113 +00:14:15,220 --> 00:14:21,900 +إليها وجعل بينكم مودة ورحمة كما سيأتي بعد قليل من + +114 +00:14:21,900 --> 00:14:31,380 +حكم الزواج ليس الشهوة وقضاء الوطر فقط وإنما السكن + +115 +00:14:31,380 --> 00:14:38,680 +الراحة النفسيةومن أسس الأسرة المودة والرحمة + +116 +00:14:38,680 --> 00:14:47,940 +والمودة هنا بمعنى الحب والحب هو أعلى درجة والمودة + +117 +00:14:47,940 --> 00:14:55,520 +أعلى درجات الحب نعم إن الذين آمنوا وعملوا الصالحات + +118 +00:14:55,520 --> 00:15:04,120 +سيجعل لهم الرحمن ودًا فالمودة هي المحبةوالمودة + +119 +00:15:04,120 --> 00:15:12,320 +أعلى درجات الحب وأما الرحمة هنا بمعنى الرأفة + +120 +00:15:12,320 --> 00:15:21,740 +فالرجل قد يمسك المرأة إما محبة لها وإما رحمة بها + +121 +00:15:21,740 --> 00:15:30,080 +كأن يكون له منها ولد أو أن تحتاجه في الإنفاق عليها + +122 +00:15:31,160 --> 00:15:39,320 +أو للألفة بينهما إلى غير ذلك ثالثا من قواعد هذه + +123 +00:15:39,320 --> 00:15:44,540 +الأسرة ومن الأسس التي تبنى عليها الأسرة في الإسلام + +124 +00:15:44,540 --> 00:15:52,680 +العدل والمساواء وسنأتي إلى هذه النقطة بالتفصيل عند + +125 +00:15:52,680 --> 00:15:58,850 +الوصول ان شاء الله إلى الحقوق الزوجيةلأن الحقوق + +126 +00:15:58,850 --> 00:16:07,950 +الزوجية على أمور ثلاثة أولا حق الزوج خالصا و ثانيا + +127 +00:16:07,950 --> 00:16:14,510 +حق الزوجة خالصا و ثالثا الحقوق المشتركة بين + +128 +00:16:14,510 --> 00:16:21,450 +الزوجين فلكل حق فإذا + +129 +00:16:21,450 --> 00:16:30,410 +ما عرف الزوجان ما لهماوما عليهم فليس ثمة ان شاء + +130 +00:16:30,410 --> 00:16:40,730 +الله من خصام او نزاع او شقاق فالمرأة لها حقوق و + +131 +00:16:40,730 --> 00:16:47,730 +عليها واجبات و كذلك الرجل الزوج له حقوق و عليه + +132 +00:16:47,730 --> 00:16:55,740 +واجبات فحقوق الزوج انما هي واجبات على الزوجةوحقوق + +133 +00:16:55,740 --> 00:17:03,780 +الزوجة إنما هي واجبات على الرجل أو على الزوج قال + +134 +00:17:03,780 --> 00:17:07,240 +الله تبارك وتعالى وَلَهُنَّ مِثْلُ اللَّذِي + +135 +00:17:07,240 --> 00:17:13,320 +عَلَيْهِنَّ بِالْمَعْرُوفِوللرجال عليهن درجة سنأتي + +136 +00:17:13,320 --> 00:17:17,620 +إلى هذه الدرجة الى وهي الخوامة عند الحديث عن + +137 +00:17:17,620 --> 00:17:26,240 +الطاعة وهو الحق الأول من حقوق الزوج على زوجه ومعنى + +138 +00:17:26,240 --> 00:17:33,200 +الآية أي ولاهن على الرجال من الحق ما للرجال عليهن + +139 +00:17:33,910 --> 00:17:39,810 +إذا فليؤد كل واحد منهما إلى الآخر ما يجب عليه + +140 +00:17:39,810 --> 00:17:48,130 +بالمعروف قال الله تبارك وتعالى من عمل صالحا من ذكر + +141 +00:17:48,130 --> 00:17:58,470 +أو أنسى من عمل صالحا من ذكر أو أنسى والعمل الصالح + +142 +00:17:58,470 --> 00:18:05,270 +إنما يكون هنابالعمل بكتاب الله وسنة رسول الله صلى + +143 +00:18:05,270 --> 00:18:10,010 +الله عليه وسلم يا أيها الذين آمنوا اطيعوا الله + +144 +00:18:10,010 --> 00:18:15,770 +واطيعوا الرسولة اطيعوا الله في كتابه واطيعوا + +145 +00:18:15,770 --> 00:18:21,710 +الرسولة في سنته صلى الله عليه وسلم لأن الإيمان + +146 +00:18:21,710 --> 00:18:31,250 +وحده غير كافٍ فلا يقبل العمل بدون إيمانولا يقبل + +147 +00:18:31,250 --> 00:18:40,730 +الإيمان بدون عمل فلا يكمل العمل إلا بالإيمان ولا + +148 +00:18:40,730 --> 00:18:45,430 +يكمل الإيمان إلا بالعمل وهذا في كل آيات القرآن + +149 +00:18:45,430 --> 00:18:51,110 +الكريمبسم الله الرحمن الرحيم والعصر إن الإنسان لفي + +150 +00:18:51,110 --> 00:18:57,190 +خُصر إلا الذين آمنوا وعملوا الصالحات وتواصوا بالحق + +151 +00:18:57,190 --> 00:19:03,710 +وتواصوا بالصبر لذا هنا ربق الله تبارك وتعالى بين + +152 +00:19:03,710 --> 00:19:12,710 +العمل وبين الإيمان من عمل صالحامن ذكر أو أنسة ربط + +153 +00:19:12,710 --> 00:19:17,910 +بين الذكر وبين الأنسة وصناعتي إلى هذا عند الحديث + +154 +00:19:17,910 --> 00:19:23,050 +عن المبحث الخامس والأخير في هذا الفصل وهو مكانة + +155 +00:19:23,050 --> 00:19:30,230 +المرأة في الإسلام فإن الله كلف المرأته وجعلها + +156 +00:19:30,230 --> 00:19:36,170 +مسئولة كالرجل تماما وصناعتي إلى هذه الآية وإلى + +157 +00:19:36,170 --> 00:19:44,020 +آيتين أخرينهمنها آية آل عمران في أواخرها فاستجاب + +158 +00:19:44,020 --> 00:19:51,480 +لهم ربهم أني لا أضيع عمل عامل منكم من ذكر أو أنسى + +159 +00:19:51,480 --> 00:19:59,680 +فكل من الرجل والمرأة عامل ومكلف ومسئول في الإسلام + +160 +00:19:59,680 --> 00:20:05,600 +له ما له وعليه ما عليه وثنأتي إلى + +161 +00:20:07,780 --> 00:20:13,580 +آيته البيعته يا أيها النبي إذا جاءك المؤمنات + +162 +00:20:13,580 --> 00:20:18,520 +يبايعنك على أن لا يشركن بالله شيئا ولا يصرخن ولا + +163 +00:20:18,520 --> 00:20:24,620 +يصدقن والآية طويلة إلى قوله فبايعهن واستغفر لهن + +164 +00:20:24,620 --> 00:20:30,680 +الله فإذا كانت المرأة مكلفة ومطالبة ببيعة الخليفة + +165 +00:20:30,680 --> 00:20:36,580 +أو الإمام كالرجل تماماسنأتي إليها عند الوصول إليها + +166 +00:20:36,580 --> 00:20:42,160 +إن شاء الله من عمل صالحا من ذكر أو أنثى وهو مؤمن + +167 +00:20:42,160 --> 00:20:52,280 +فلنحيينه حياة طيبة و لنجزينهم أجرهم بأحسن ما كانوا + +168 +00:20:52,280 --> 00:20:58,580 +يعملون وهو مؤمن بالله ورسول الله صلى الله عليه + +169 +00:20:58,580 --> 00:21:09,240 +وسلم فالله يحييهمحياتا طيبة في الدنيا و لهم الجزاء + +170 +00:21:09,240 --> 00:21:15,300 +الأوفى و الجنة ان شاء الله في الآخرة و ذلك هو + +171 +00:21:15,300 --> 00:21:23,140 +الفوز العظيم أما رابعا فهو التكافل الاجتماعيوقد + +172 +00:21:23,140 --> 00:21:28,860 +تكلمنا عند الحديث عن باب الأخلاق عن تعريف التكافل + +173 +00:21:28,860 --> 00:21:36,560 +وعن أدلته ونأتي هنا إلى التكافل اجتماعي كركن من + +174 +00:21:36,560 --> 00:21:42,420 +أركان الأسرة في الإسلام نعم يقول الله تعالى وخفض + +175 +00:21:42,420 --> 00:21:48,020 +لهم جناح الذل من الرحمة وقول رب رحمهما كما ربياني + +176 +00:21:48,020 --> 00:21:50,220 +صغيرة نعم + +177 +00:21:52,030 --> 00:21:57,990 +صدق الله العظيم صناعتي إلى هذه الآيات ان شاء الله + +178 +00:21:57,990 --> 00:22:04,750 +عند الحديث عن مكانة المرأة في الإسلام أما وعن + +179 +00:22:04,750 --> 00:22:11,070 +مكانة الأم في الإسلام وصناعتي بالآيات والأحاديث + +180 +00:22:11,070 --> 00:22:20,090 +التي تدلل على ذلك ونحن في مثل هذه الأياموالناس + +181 +00:22:20,090 --> 00:22:24,650 +يحتفلون بعيد الأم نقول لهم إن الاحتفال بعيد الأم + +182 +00:22:24,650 --> 00:22:33,590 +هو إساءة إلى الأم لأن الأمة في الإسلام لها في كل + +183 +00:22:33,590 --> 00:22:42,930 +يوم عيد إنما هذا من بداع الغرب فهم لا يبرون آباءهم + +184 +00:22:42,930 --> 00:22:50,170 +ولا أمهاتهمإنما يضعوهم في دور العجزة والمسنين ولا + +185 +00:22:50,170 --> 00:22:57,970 +يزوروهم ولا يتعرفون عليهم إلا في 21 مارس والعياذ + +186 +00:22:57,970 --> 00:23:08,030 +بالله وقد لا يزوروهم ولا يأتون بهم إلى بيوتهم كما + +187 +00:23:08,030 --> 00:23:12,590 +قرأنا عن بعضهم أن أمها طلبت منه سيارة في عيد الأم + +188 +00:23:12,590 --> 00:23:19,050 +في بلاد الغربفقال لها يا أماه ليس في البيت إلا + +189 +00:23:19,050 --> 00:23:27,130 +غرفتان غرفة لي و لزوجتي و غرفة للكلب أعزكم الله و + +190 +00:23:27,130 --> 00:23:32,410 +قد يرسل لها باقة من الورود عبر الوريد عبر البريد + +191 +00:23:32,410 --> 00:23:40,850 +عبر البريد و أين هذا و قد جعل الله الجنة تحت أقدام + +192 +00:23:40,850 --> 00:23:46,140 +الأمهاتوفي هذه الآية الكريمة واخفض لهم جناح الذل + +193 +00:23:46,140 --> 00:23:53,460 +من الرحمة وقل رب رحمهم كما ربياني صغيرة لفتة كريمة + +194 +00:23:53,460 --> 00:24:03,240 +جدا أن الإسلام في الأصل لا يؤمن بالذلة فالله وصف + +195 +00:24:03,240 --> 00:24:14,860 +المؤمنين بأنهم أشداء على الكفارأعز على الكفار ولله + +196 +00:24:14,860 --> 00:24:20,040 +الأعزة ولرسوله وللمؤمنين ولكن المنافقين لا يعلمون + +197 +00:24:20,040 --> 00:24:27,380 +نعم ولكن الله مدح الذلة للمؤمنين في موضعين اثنين + +198 +00:24:27,380 --> 00:24:35,620 +فقط لا ثالث لهم هذا هو احد الموضعين الذلة للأبوين + +199 +00:24:35,620 --> 00:24:45,570 +واخفض لهم جناح الذلمن الرحمته فالذلة او الذل محمود + +200 +00:24:45,570 --> 00:24:55,770 +بين يدي الأبوين وفي موضع اخرى في وصف المؤمنين اعزة + +201 +00:24:55,770 --> 00:25:03,760 +على الكافرين اذلةعلى المؤمنين فالمؤمن يذل لأخيه + +202 +00:25:03,760 --> 00:25:12,100 +المؤمن ولكنه عزيز على الكافرين إذا هذه هي الأسس + +203 +00:25:12,100 --> 00:25:17,700 +الأربعة التي تبنى عليها الأسرة في الإسلام أولا + +204 +00:25:17,700 --> 00:25:25,790 +وحدة الأصل والمنشأ ثانيا المودة والرحمةثالثا العدل + +205 +00:25:25,790 --> 00:25:31,170 +والمساواة رابعا التكافل الاجتماعي وهنا ألفط + +206 +00:25:31,170 --> 00:25:38,150 +الأنظار إلى أنه لابد من حفظها ووضعها في مكانها + +207 +00:25:38,150 --> 00:25:45,830 +لأنه سيأتي معنا بعد قليل أيضا حكم الزواج وستأتي + +208 +00:25:45,830 --> 00:25:53,790 +معنا بعد ذلك الحقوق الزوجيةنعم حق الزوج و حق + +209 +00:25:53,790 --> 00:25:59,050 +الزوجة و الحقوق المشتركة فقد يختلط الأمر عليكم + +210 +00:25:59,050 --> 00:26:07,990 +فلابد من وضع كل بند في موضعه فهذه هي الأسس و تلك + +211 +00:26:07,990 --> 00:26:13,670 +الحكم و بعدها الحقوق فالتفتوا إلى ذلك و انتبهوا + +212 +00:26:13,670 --> 00:26:17,030 +إليه أما المبحث + +213 +00:26:18,170 --> 00:26:26,650 +الثالث فهو الزواج نأتي في هذا المبحث إلى تعريف + +214 +00:26:26,650 --> 00:26:35,570 +الزواج لغة واصطلاحا اما الزواج في اللغة فاصله من + +215 +00:26:35,570 --> 00:26:45,670 +الفعل زوجة والمصدر زواجا وتزويجا يقال في لغة العرب + +216 +00:26:45,670 --> 00:26:59,580 +زوجةزواجا وتزويجا مثل سلم سلاما وتسليما ومثل كلم + +217 +00:26:59,580 --> 00:27:07,440 +كلاما وكلم الله موسى تكليما ومعنى زوج في لغة العرب + +218 +00:27:07,440 --> 00:27:17,170 +بمعنى قرن الأشياء بعضها ببعضومنه قوله تبارك وتعالى + +219 +00:27:17,170 --> 00:27:25,350 +وزوجناهم بحور عين زوجناهم بحور عين بمعنى قرنناهم + +220 +00:27:25,350 --> 00:27:31,210 +بحور عين وقوله تبارك وتعالى أحشر الذين ظلموا + +221 +00:27:31,210 --> 00:27:38,690 +وأزوادهم وما كانوا يعبدون وهنا وأزوادهم + +222 +00:27:40,080 --> 00:27:49,160 +ليست بمعنى الأزواج الشرعيين بمعنى النساء أو المرأة + +223 +00:27:49,160 --> 00:27:57,440 +لأن المرأة قد تكون مؤمنة ويكون زوجها كافر مثل آسيا + +224 +00:27:57,440 --> 00:28:03,800 +زوج شرعويففرعون كافر في النار و لا عياذ بالله فكيف + +225 +00:28:03,800 --> 00:28:10,180 +تحشر معه زوجه آسية التي آمنت بموسى عليه السلام إذا + +226 +00:28:10,180 --> 00:28:18,540 +هنا و أزواجهم بمعنى أمثالهم و أشباههم أو قرنائهم + +227 +00:28:18,540 --> 00:28:26,940 +من أهل السوء أحشروا الذين ظلموا و أزواجهم بمعنى ما + +228 +00:28:26,940 --> 00:28:33,960 +ذكرتهخرناءهم أو أشباههم و أمثالهم من أهل السوق و + +229 +00:28:33,960 --> 00:28:39,740 +من أهل الكفر ولا عياذ بالله و الزواج كما سنرى أيضا + +230 +00:28:39,740 --> 00:28:47,280 +يطلق على النكاح فإذا قيل تعريف النكاح أو تعريف + +231 +00:28:47,280 --> 00:28:58,490 +الزواج فكلاهما بمعنى واحد فلا يختلط عليكم الأمرهذا + +232 +00:28:58,490 --> 00:29:05,290 +في لغة العرب أما في الاصطلاح الشرعي فنكتفي هنا + +233 +00:29:05,290 --> 00:29:14,390 +بتعريف للشافعية وهو أن الزواج عقد يتضمن إباحة وطء + +234 +00:29:14,390 --> 00:29:22,310 +بلفظ إنكاح أو تزويد أو ترجمته طبعا هنا لا يصح عقد + +235 +00:29:22,310 --> 00:29:29,540 +النكاحبالإيجاب والقبول إلا بهذه الألفاظ زوجتك أو + +236 +00:29:29,540 --> 00:29:37,100 +أنكحتك وكما أسلفنا المرأة لا تتولى زواج نفسها + +237 +00:29:37,100 --> 00:29:43,380 +فالمرأة كتلة من الحياة وحتى لا تُنسب إلى الوقاحة + +238 +00:29:43,380 --> 00:29:51,640 +فإنما يتولى أمر زواجها وليهاأبوها أو من عاش من + +239 +00:29:51,640 --> 00:30:03,240 +أوليائها فيمسكوا بيد الخاطب ويقولوا له مرددا خلف + +240 +00:30:03,240 --> 00:30:11,060 +المأذون الشرعي زوجتك أو أنكحتك ابنتي فلانة موكلة + +241 +00:30:13,230 --> 00:30:18,750 +على كتاب الله وعلى سنة رسول الله وعلى المهر المتفق + +242 +00:30:18,750 --> 00:30:25,530 +عليه بيننا ويردد كذلك الزوج خلف المأذون قبلته + +243 +00:30:25,530 --> 00:30:33,610 +زوادي أو نكاحي من ابنتك موكلتك فلانة على كتاب الله + +244 +00:30:33,610 --> 00:30:39,590 +وسنة رسول الله وعلى المهر المتفق عليه بيننا فلا + +245 +00:30:39,590 --> 00:30:48,680 +يصحواأن يكون عقد الزواج بلفظ الأجر مثلا لماذا؟ لأن + +246 +00:30:48,680 --> 00:30:59,080 +الزواج عقد مؤبد لأن الزواج عقد مؤبد نعم وأما + +247 +00:30:59,080 --> 00:31:06,480 +الأجرة فهي عقد مؤقت قد يستأجر بيتا او دكانة إلى + +248 +00:31:06,480 --> 00:31:14,910 +سنة او سنتين و نحو ذلكثم بعد ذلك يفسخ العقد نعم + +249 +00:31:14,910 --> 00:31:23,830 +ولكن الزواج هو عقد مؤبد ولذلك نحن نقول هنا ولعلنا + +250 +00:31:23,830 --> 00:31:32,630 +نأتي اليه وهو نكاح المتعة فنكاح المتعة باطل عند + +251 +00:31:32,630 --> 00:31:39,580 +أهل الصنة وقد أجازه الشيعة أخذاهم اللهفيعتبرونه من + +252 +00:31:39,580 --> 00:31:45,660 +أركان دينهم والذي لا يتمتع عند شيعة قد يشك في + +253 +00:31:45,660 --> 00:31:55,360 +عقيدته نعم عقيدة الشيعة الباطلة نعم ولذلك نحن أهل + +254 +00:31:55,360 --> 00:32:01,660 +الصنة نقول بأن نكاح المتعة باطل وهو لون من ألوان + +255 +00:32:01,660 --> 00:32:11,580 +الزنا والأياذ بالله لأنه نكاح مؤقتولذلك النكاح ليس + +256 +00:32:11,580 --> 00:32:19,160 +القصد منه فقط هو الشهوة والجنس وقضاء الوطر كما + +257 +00:32:19,160 --> 00:32:23,440 +سنأتي بعد قليل في حكم الزواج، نعم من حكم الزواج + +258 +00:32:23,440 --> 00:32:31,410 +الاستجابة للداء الفطرةنعم لأن الإنسان فيه من + +259 +00:32:31,410 --> 00:32:36,450 +الشهوات والغرائز ما فيه لكن ليس هذا فقط وإنما كما + +260 +00:32:36,450 --> 00:32:41,570 +أسلفنا من حكم الزواج السكن ومن أركان الأسر المسلمة + +261 +00:32:41,570 --> 00:32:46,450 +المودة والرحمة + +262 +00:32:46,450 --> 00:32:55,650 +فعقد الزواج عقد مؤبد إلى أن يفسخ بالموت أو بالطلاق + +263 +00:32:56,500 --> 00:33:04,260 +نعم و لكن يصح أن يطلق على المهري أجرة نعم كما في + +264 +00:33:04,260 --> 00:33:12,340 +قصة موسى عليه السلام مع الرجل الصالح إني أريد أن + +265 +00:33:12,340 --> 00:33:18,640 +أنكحك إحدى ابنتيا هاتيني على أن تأجرني ثمانية حجاج + +266 +00:33:18,640 --> 00:33:25,060 +فإن أتممت عشرا فمن عندك و في أكثر من موضع و آتوهم + +267 +00:33:25,060 --> 00:33:32,530 +أجورهموالأجور هنا هي المهور أما الاستمتاع الذي + +268 +00:33:32,530 --> 00:33:37,990 +استشهد به الشيعة على أنه نكاح المتعة فهو الزواج + +269 +00:33:37,990 --> 00:33:47,190 +فما استمتعتم به منهن فآتوهن أجورهن نعم فالاستمتاع + +270 +00:33:47,190 --> 00:33:55,090 +هنا بمعنى عقد الزواج وليس نكاحالمتعة وهو نكاحه + +271 +00:33:55,090 --> 00:34:01,410 +المؤقت من أجل الشهوة ومن أجل قضاء الوطر وهذه ليست + +272 +00:34:01,410 --> 00:34:07,450 +أخلاق المسلمين لأنه عبر الزنا و الحرام يمكنأن يقضي + +273 +00:34:07,450 --> 00:34:12,770 +شهوته وأن يعطي المرأة أجراً هذا لا يليق ولا ينبغي + +274 +00:34:12,770 --> 00:34:18,590 +بأخلاق المسلمين نعم إذا الزواج عقد وقولنا هذا + +275 +00:34:18,590 --> 00:34:23,870 +العقد لابد أن يكون عبر القضاء الشرعي وعبر المأذون + +276 +00:34:23,870 --> 00:34:34,390 +الشرعي يتضمن إباحة بطءوهو الاتصال بين الجنسين بلفظ + +277 +00:34:34,390 --> 00:34:40,890 +إنكاح أو تزويج لخطورة الأمر أو ترجمته إن لم يكون + +278 +00:34:40,890 --> 00:34:50,190 +عربيين فترجمت النكاح والزواج نعم دليل مشروعية + +279 +00:34:50,190 --> 00:34:57,170 +الزواج الزواج طبعا كما سنرى بعد قليل أنهليس فرضًا + +280 +00:34:57,170 --> 00:35:04,890 +أو واجبًا وإنما هو صنّة مؤكدة في حال اعتدال الشهوة + +281 +00:35:04,890 --> 00:35:11,470 +فالله تبارك وتعالى يقول فانكحوا مع طاب لكم من + +282 +00:35:11,470 --> 00:35:17,550 +النساء مثنى وثلاث وربع هذا دليل من القرآن الكريم + +283 +00:35:17,550 --> 00:35:25,380 +على مشروعية النكاح أو مشروعية الزواجوقوله تبارك + +284 +00:35:25,380 --> 00:35:33,200 +وتعالى وأنكحوا الأيام منكم والأيام جمع أيم والأيم + +285 +00:35:33,200 --> 00:35:39,920 +كل ما لا زوج له من الرجال أو النساء فالرجل ليس له + +286 +00:35:39,920 --> 00:35:49,140 +زوجة أيم والمرأة ليس لها زوج أيم فهي دعوة إلى + +287 +00:35:49,140 --> 00:35:56,910 +أولياء الأمور وقيل إلى الأزواجوالأصح أن الخطابة + +288 +00:35:56,910 --> 00:36:03,130 +إلى كليهما إلى أولياء الأمور وإلى الأزواج فالمعنى + +289 +00:36:03,130 --> 00:36:08,730 +يحتمل ذلك كلهم وأنكحوا الأيام منكم والصالحين من + +290 +00:36:08,730 --> 00:36:14,810 +عبادكم وإمائكم إن يكونوا فقراء يغنهم الله من فضله + +291 +00:36:14,810 --> 00:36:22,350 +وهذه دعوة إلى الزواد حتى ولو كان فقيرا يا أيها + +292 +00:36:22,350 --> 00:36:29,420 +الأولياءزوجوا الفقراء من بناتكم حتى وإن كانوا أقل + +293 +00:36:29,420 --> 00:36:34,580 +مالا منكم كما جاء في أكثر من موضعا في القرآن + +294 +00:36:34,580 --> 00:36:45,080 +الكريم إذا جاءكم وكذلك في عفوا السنة النبوية ففي + +295 +00:36:45,080 --> 00:36:50,480 +القرآن الكريم إن أكرمكم عند الله أدخاكم وفي السنة + +296 +00:36:50,480 --> 00:36:56,570 +النبوية إذا جاءكم أو قال إذا أتاكممن ترضون دينه + +297 +00:36:56,570 --> 00:37:01,910 +وخلقه فسوجوه انظروا هكذا يتفاضل الناس بالدين + +298 +00:37:01,910 --> 00:37:09,730 +والخلق قبل أن نسأل عن ماله وعن جماله وعن حسبه + +299 +00:37:09,730 --> 00:37:14,870 +ونسبه لابد من السؤال عن الدين والخلق اذا جاءكم او + +300 +00:37:14,870 --> 00:37:23,220 +قال اذا اتاكم من ترضون دينه وخلقه فسوجوهإلا تفعلوا + +301 +00:37:23,220 --> 00:37:30,940 +يعني إن طلبتموه لفقره وسوء حاله تكون فتنة في الأرض + +302 +00:37:30,940 --> 00:37:39,590 +وفساد عريضأو قال في رواة وفساد كبير هكذا والمرأة + +303 +00:37:39,590 --> 00:37:44,930 +كذلك عندما تُخطب لا تُخطب لجمالها فقط أو مالها فقط + +304 +00:37:44,930 --> 00:37:51,070 +أو حسبها فقط وإنما أيضًا لدينها تُنكح المرأة لأربع + +305 +00:37:51,070 --> 00:37:59,110 +لمالها وجمالها وحسبها ودينها فاضفر بذات الدين تربط + +306 +00:37:59,110 --> 00:38:08,720 +يدك وتربط يدكمعناها لثقت يداك في التراب وهذه دعوة + +307 +00:38:08,720 --> 00:38:15,860 +من الرسول عليه بالفكر والحاجة والعوز لأن العرب + +308 +00:38:15,860 --> 00:38:23,330 +كانت تطلق الترابوأنه يملكوا ثروة من التراب على + +309 +00:38:23,330 --> 00:38:28,030 +الفقراء والمساكين والمحتاجين كما قال الله تبارك + +310 +00:38:28,030 --> 00:38:32,390 +وتعالى فلاكتح ما العقبة وما أدراك ما العقبة فاكوا + +311 +00:38:32,390 --> 00:38:38,010 +رقبة أو اطعاموا مسكين في يوم زي مصغبة او اطعام في + +312 +00:38:38,010 --> 00:38:43,910 +يوم زي مصغبة او مسكينا زا مطربةأو مسكينا زى مطربة + +313 +00:38:43,910 --> 00:38:52,630 +بمعنى زى تراب فمن فقره ومسكنته التثق بالتراب ومعنى + +314 +00:38:54,690 --> 00:39:00,570 +الحديث إن لم تظفر بذات الدين لسقت يداك بالتراب + +315 +00:39:00,570 --> 00:39:07,070 +بمعنى أصبحت فقيرا ذا حاجة ومسكنة حتى كان سيدنا + +316 +00:39:07,070 --> 00:39:13,390 +عمرو يقول ويقسم على ذلك بأن الزواج باب من أبواب + +317 +00:39:13,390 --> 00:39:19,710 +الغناء نعم فلا تخشى الفقر فالخالق هو الله والرازق + +318 +00:39:19,710 --> 00:39:25,070 +هو اللهوقد قال الله تعالى يكونوا فقراء يغنهم الله + +319 +00:39:25,070 --> 00:39:32,570 +من فضله وسيأتي معنى عند الحديث عن حكم الزواج وأنه + +320 +00:39:32,570 --> 00:39:37,490 +صنة مؤكدة في حال اعتدال الشهوة قوله عليه الصلاة + +321 +00:39:37,490 --> 00:39:43,550 +والسلام ثلاثة الله في عونهم وذكر المجاهد في سبيل + +322 +00:39:43,550 --> 00:39:51,580 +الله والعبد المكاتب وذكر الناكح يريد العفاففالله + +323 +00:39:51,580 --> 00:39:57,420 +يغنيه من فضله ان شاء الله تعالى والآية الكريمة + +324 +00:39:57,420 --> 00:40:03,100 +التي مرت بنا في مشروعية الزواج في صورة الروم من + +325 +00:40:03,100 --> 00:40:08,400 +آياته أن خلق لكم من أنفسكم أزواجا لتسكنوا إليها + +326 +00:40:08,400 --> 00:40:15,940 +وجعل بينكم مودة ورحمة إن في ذلك لآيات لقوم يتفكرون + +327 +00:40:15,940 --> 00:40:23,980 +فكل هذه الآيات تدل علىمشروعية الزواج ونختم بأدلة + +328 +00:40:23,980 --> 00:40:27,680 +من الصناة النبوية للدلالة على مشروعية الزواج وما + +329 +00:40:27,680 --> 00:40:32,000 +أكثرها وقد ذكرت طوا حديثين من غير الكتاب ومنها + +330 +00:40:32,000 --> 00:40:36,500 +قوله عليه الصلاة والسلام وثنأتي إلى هذا الحديث عند + +331 +00:40:36,500 --> 00:40:43,840 +الكلام عن حكم الزواج وأنه إعفاف للزوجين يقول عليه + +332 +00:40:43,840 --> 00:40:48,440 +الصلاة والسلام يا معشر الشبابمن استطاع منكم الباءة + +333 +00:40:48,440 --> 00:40:55,580 +فليتزوج فإنه أي الزواج أغض للبصري و أحسن للفرج ومن + +334 +00:40:55,580 --> 00:41:03,340 +لم يستطع فعليه بالصوم فإنه له وجاء وجاء بمعنى قاطع + +335 +00:41:03,920 --> 00:41:10,560 +لأن وجأ في لغة العرب بمعنى قاطعة فإنه أي قاطع + +336 +00:41:10,560 --> 00:41:19,080 +للشهوة أو مهذب للنفس واليستعف + +337 +00:41:19,080 --> 00:41:23,560 +في الذين لا يدون نكاحا حتى يغنيهم الله من فضله + +338 +00:41:23,560 --> 00:41:29,080 +نكون ان شاء الله في المحاضرة التالية على موعد مع + +339 +00:41:29,870 --> 00:41:37,070 +حكمة مشروعية الزواج والسلام عليكم ورحمة الله + +340 +00:41:37,070 --> 00:41:38,010 +وبركاته + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/bOshnldAHLg_raw.json b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/bOshnldAHLg_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..90f17ef4dfc880794e36e1f71b0a2965b847096f --- /dev/null +++ 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{"start": 2134.26, "end": 2134.54, "word": " ما", "probability": 0.427490234375}, {"start": 2134.54, "end": 2134.92, "word": " لا", "probability": 0.73095703125}, {"start": 2134.92, "end": 2135.36, "word": " زوج", "probability": 0.9912109375}, {"start": 2135.36, "end": 2135.72, "word": " له", "probability": 0.8125}, {"start": 2135.72, "end": 2136.4, "word": " من", "probability": 0.994140625}, {"start": 2136.4, "end": 2137.1, "word": " الرجال", "probability": 0.9876302083333334}, {"start": 2137.1, "end": 2138.16, "word": " أو", "probability": 0.93310546875}, {"start": 2138.16, "end": 2138.68, "word": " النساء", "probability": 0.97119140625}, {"start": 2138.68, "end": 2139.34, "word": " فالرجل", "probability": 0.9703369140625}, {"start": 2139.34, "end": 2139.68, "word": " ليس", "probability": 0.987060546875}, {"start": 2139.68, "end": 2139.92, "word": " له", "probability": 0.9619140625}, {"start": 2139.92, "end": 2140.76, "word": " زوجة", "probability": 0.89892578125}, {"start": 2140.76, 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رسول + +3 +00:00:11,130 --> 00:00:16,350 +الله اللهم صلي وسلم على سيدنا محمد وعلى آله وصحبه + +4 +00:00:16,350 --> 00:00:23,630 +وسلم أجمعين، أعزاء الطلاب، في مساق النظم الإسلامية + +5 +00:00:23,630 --> 00:00:30,050 +قبل ذي بدء، وأرحبوا بكم جميعا في بداية فصل دراسي + +6 +00:00:30,050 --> 00:00:36,130 +جديد، وأحييكم بتحية الإسلام العظيم، فسلام الله عليكم + +7 +00:00:36,130 --> 00:00:42,930 +ورحمته وبركاته، سائلا المولى عز وجل لكم النجاح + +8 +00:00:42,930 --> 00:00:50,850 +والتوفيق والسلامة والعافية من كل داء ووباء، اللهم + +9 +00:00:50,850 --> 00:01:00,130 +آمين، النظم الإسلامية، المساق المطلوب من هذا الفصل + +10 +00:01:01,170 --> 00:01:07,230 +صنفه ثلاثة من زملائنا في كلية الشريعة والقانون في + +11 +00:01:07,230 --> 00:01:14,630 +الجامعة الإسلامية بغزة، وهم: أولا، المرحوم بإذنه + +12 +00:01:14,630 --> 00:01:20,470 +تبارك وتعالى الدكتور أحمد إدياب، إشوذح نسأل الله + +13 +00:01:20,470 --> 00:01:25,130 +تبارك وتعالى أن يغفر له وأن يرحمه وأن يسكنه فسيح + +14 +00:01:25,130 --> 00:01:30,970 +جنانه، اللهم آمين، ثانيا، الدكتور ماهر أحمد السوسي + +15 +00:01:30,970 --> 00:01:37,990 +حفظاه الله، وثالثا، الدكتور زياد إبراهيم مقداد، حفظاه + +16 +00:01:37,990 --> 00:01:49,310 +الله، وكتاب النظم الإسلامية عبارة عن فصل تمهيدي وستة + +17 +00:01:49,310 --> 00:01:57,990 +فصول دراسية، وليست كلها مطلوبة في الامتحان، فالمقرر + +18 +00:01:57,990 --> 00:02:06,470 +منها: أولا، الفصل التمهيدي كاملا، وثانيا، الفصل + +19 +00:02:06,470 --> 00:02:12,310 +الثاني مطلوب كاملا، وهو بعنوان العبادة في الإسلام + +20 +00:02:12,310 --> 00:02:21,570 +وكذلك الفصل الثالث، وهو بعنوان نظام الأخلاق في + +21 +00:02:21,570 --> 00:02:27,290 +الإسلام، وهو مطلوب كاملا، والفصل الرابع أيضا مطلوب + +22 +00:02:27,290 --> 00:02:34,050 +كاملا، وهو بعنوان نظام الأسرة في الإسلام، أما الفصل + +23 +00:02:34,050 --> 00:02:43,430 +السادس فهو عبارة عن مباحث خمسة، ليست كلها مطلوبة + +24 +00:02:43,430 --> 00:02:52,310 +المطلوب فقط هو المبحثان الأول والثاني، تعريف النظام + +25 +00:02:52,310 --> 00:02:57,570 +السياسي في الإسلام، والقواعد الأربعة التي يقوم + +26 +00:02:57,570 --> 00:03:02,990 +عليها النظام السياسي في الإسلام، هذه هي الفصول + +27 +00:03:02,990 --> 00:03:10,020 +المطلوبة والمقررة في الامتحان، أما غير المطلوب فهو + +28 +00:03:10,020 --> 00:03:16,220 +أولا، الفصل الأول كاملا، وهو بعنوان العقيدة، لأنه + +29 +00:03:16,220 --> 00:03:23,700 +سيدرس لكم في كلية أصول الدين في مساق مستقل، إذا + +30 +00:03:23,700 --> 00:03:30,190 +الفصل الأول وهو بعنوان العقيدة ليس مطلوبا في هذا + +31 +00:03:30,190 --> 00:03:36,370 +الفصل، وكذلك الفصل الخامس، وهو بعنوان الاقتصاد + +32 +00:03:36,370 --> 00:03:43,720 +الإسلامي، ليس مطلوبا أيضا، لأنه سيدرس لكم في كلية + +33 +00:03:43,720 --> 00:03:53,100 +التجارة في مساق مستقل أيضا، وكذلك كما أشرت في الفصل + +34 +00:03:53,100 --> 00:03:57,840 +السادس، النظام السياسي في الإسلام، ليس مطلوبا + +35 +00:03:57,840 --> 00:04:04,940 +المباحث الثلاثة من المباحث الخامسة التي يجتمل + +36 +00:04:04,940 --> 00:04:12,850 +عليها الفصل السادس، وهم المبحث الثالث والمبحث الرابع + +37 +00:04:12,850 --> 00:04:17,670 +والمبحث الخامس، فالمطلوب في الفصل السادس فقط + +38 +00:04:17,670 --> 00:04:25,390 +المبحثان الأول والثاني، وإذا مررنا بأشياء ليست + +39 +00:04:25,390 --> 00:04:29,930 +مطلوبة في الامتحان، سنأتي إلى ذكرها عند الوصول + +40 +00:04:29,930 --> 00:04:35,260 +إليها إن شاء الله، الآن إن شاء الله، وعلى بركة الله + +41 +00:04:35,260 --> 00:04:43,340 +نبدأ في الفصل التمهيدي، والفصل التمهيدي، أهمية دراسة + +42 +00:04:43,340 --> 00:04:50,860 +النظم الإسلامية، عبارة عن أربعة مباحث، أما المبحث + +43 +00:04:50,860 --> 00:04:57,160 +الأول فهو بعنوان تعريف النظم الإسلامية، أما المبحث + +44 +00:04:57,160 --> 00:05:01,680 +الثاني فهو بعنوان حاجة المجتمعات إلى النظم + +45 +00:05:01,680 --> 00:05:06,760 +الإسلامية، أما المبحث الثالث فهو بعنوان خصائص النظم + +46 +00:05:06,760 --> 00:05:15,540 +الإسلامية، وهذا المبحث هو أكبر المباحث وأهم المباحث + +47 +00:05:15,540 --> 00:05:20,280 +في الفصل التمهيدي، أما المبحث الرابع والأخير من + +48 +00:05:20,280 --> 00:05:24,880 +الفصل التمهيدي فهو بعنوان مصادر النظم الإسلامية + +49 +00:05:24,880 --> 00:05:32,640 +حيث نتكلم عن المصادر بنوعيها، والمطلوب فقط في هذا + +50 +00:05:32,640 --> 00:05:41,300 +المبحث هو المصادر الأربعة المتفق عليها، وهي الكتاب + +51 +00:05:41,300 --> 00:05:48,780 +والسنة والإجماع والقياس، وهناك مصادر مختلف عليها + +52 +00:05:48,780 --> 00:05:54,560 +ليست مطلوبة، ولكن نشير إليها إشارة عند الوصول إليها + +53 +00:05:54,560 --> 00:06:04,660 +مثل العرف والمصالح المرسلة وسد الذريعة ومذهب الصحابي + +54 +00:06:04,660 --> 00:06:11,820 +وشرع من قبلنا والاستصلاح ونحو ذلك من المصادر + +55 +00:06:11,820 --> 00:06:21,120 +التي تدرس لطلبة كلية الشريعة والقانون، نعم، أما + +56 +00:06:21,120 --> 00:06:28,820 +المبحث الأول وهو تعريف النظم الإسلامية، نأتي في هذا + +57 +00:06:28,820 --> 00:06:35,040 +المبحث إلى تعريف النظم الإسلامية لغة واصطلاحا، بدءا + +58 +00:06:35,040 --> 00:06:43,060 +بتعريف النظم، أما النظم عزيزي الطلاب فهي جمع نظام + +59 +00:06:44,100 --> 00:06:52,980 +وكلمة نظام تجمع على صيغتين ثلاثة: نظم، وهو عنوان + +60 +00:06:52,980 --> 00:07:02,300 +الكتاب، كما تجمع على أنظمة وعلى أنظيم، كما ذكر في + +61 +00:07:02,300 --> 00:07:10,560 +لسان العرب ابن منظور الإفريقي، ولكن الأشهر نظم + +62 +00:07:10,560 --> 00:07:21,900 +وأنظمة، نظم إسلامية ونظم عربية، نعم، هكذا يقولون، أما + +63 +00:07:21,900 --> 00:07:30,240 +أنظيم فهي الأقل شهرة، وكلمة نظام أصلها اللغوي من + +64 +00:07:30,240 --> 00:07:37,960 +فعل نظمة من الفعل الثلاثي المجرد النون والظاء + +65 +00:07:37,960 --> 00:07:46,910 +والميم، وكلمة نظمة تأتي في لغة العرب بمعانٍ متقاربة + +66 +00:07:46,910 --> 00:07:56,410 +مثل ضم وجمع وألف، كما قال الله تبارك وتعالى، وَأَلَّفَ بَيْنَ قُلُوبِهِمْ، بمعنى جمع وضّم، ونظّمه بين قلوبهم، و + +67 +00:07:56,410 --> 00:08:07,230 +النظم هنا هو نظم معنوي، لأنه كما سيأتي بعد قليل، كلمة + +68 +00:08:07,230 --> 00:08:15,440 +نظمة تأتي للأشياء المادية كالـعقد، كما تأتي للأشياء + +69 +00:08:15,440 --> 00:08:24,540 +المعنوية كالقوانين والشعر ونحو ذلك، وكما جاء في + +70 +00:08:24,540 --> 00:08:35,760 +الحديث، "الأرواح جنود مجندة، ما تعارف منها اتلف، وما تناكر منها اختلف"، ما تعارف منها اتلف، بمعنى انتظم، هذا + +71 +00:08:35,760 --> 00:08:43,180 +أيضًا من المعاني المعنوية للفعل نظّمة، إذا الفعل + +72 +00:08:43,180 --> 00:08:50,680 +نظّمة في لغة العرب يأتي بمعنى الضم وبمعنى الجمع و + +73 +00:08:50,680 --> 00:08:57,760 +بمعنى التأليف، ولكن ضمّ الأشياء بعضها إلى بعض بترتيب + +74 +00:09:04,040 --> 00:09:14,660 +واستقامة، هذا هو المعنى اللغوي للفعل نظّمة، إذا لو + +75 +00:09:14,660 --> 00:09:23,650 +كانت الأشياء مهلهلة أو كانت مبعثرة على غير استقامة + +76 +00:09:23,650 --> 00:09:32,050 +أو ترتيب لا يقال لها نظام في لغة العرب، إذا ألف وجمع + +77 +00:09:32,050 --> 00:09:39,840 +وضم الأشياء بعضها إلى بعض في تنسيق واستقامة + +78 +00:09:39,840 --> 00:09:46,800 +هو معنى الفعل نظّما، ولذلك سُمّي العقد نظاما، وهذا هو + +79 +00:09:46,800 --> 00:09:56,280 +المعنى المادي للفعل نظّما، والعقد بكسر العين لأن + +80 +00:09:56,280 --> 00:10:05,720 +العقد على خلاف ذلك، وهو الخرز الذي يتدلى على صدر + +81 +00:10:05,720 --> 00:10:15,420 +المرأة، ومنه كتاب العقد الفريد لابن عبدربه + +82 +00:10:15,420 --> 00:10:21,800 +الاندلوسي، نعم، لأن حبات العقد ضمّ بعضها إلى بعض في + +83 +00:10:21,800 --> 00:10:29,880 +ترتيب واستقامة، أو كما سيأتي معنا في خصائص النظم + +84 +00:10:29,880 --> 00:10:37,040 +الإسلامية في تكامل وفي ترابط، وعليه تأتي كلمة نظام + +85 +00:10:37,040 --> 00:10:45,140 +على كل ما يجمع من أشياء مادية كما أشرنا إلى ذلك في + +86 +00:10:45,140 --> 00:10:54,800 +العقد، وكذلك الصبح، فالصبحة أيضا تعتبر نظاما أو + +87 +00:10:54,800 --> 00:11:04,120 +منظومة، لماذا؟ لأن الخرز قد ضمّ بعضه إلى بعض بترتيب + +88 +00:11:04,120 --> 00:11:11,820 +واستقامة، فإذا انفرط الأخضر وتناثر الحبات، وصارت كل + +89 +00:11:11,820 --> 00:11:19,520 +حبة في واد، فلا يطلق على ذلك نظام، نعم، وكذلك + +90 +00:11:19,520 --> 00:11:27,460 +النظم المعنوي كالأنظمة + +91 +00:11:29,190 --> 00:11:34,670 +والقوانين والشعر، لماذا سمّي الشعر أيضا منظومة، لأنه + +92 +00:11:34,670 --> 00:11:43,030 +ينتهي بالوزن والقافية، فالشعر الذي لا ينتهي بالوزن + +93 +00:11:43,030 --> 00:11:49,130 +والقافية لا يسمى شعرا، نعم، أما الإسلام + +94 +00:11:59,850 --> 00:12:11,730 +فهو أصله اللغوي من معانٍ متقاربة وهي ثلاثة، أول هذه + +95 +00:12:11,730 --> 00:12:19,110 +المعاني هو الخلوص والتجرد، فمعنى + +96 +00:12:20,050 --> 00:12:28,810 +أسلم يعني سلم له الشيء أي خالص له ولم ينازعه فيه + +97 +00:12:28,810 --> 00:12:36,010 +أحد، وهذا أيضا من معاني الإسلام العظيم، فلابد أن + +98 +00:12:36,010 --> 00:12:42,170 +تكون العبادة خالصة لله سبحانه وتعالى، فمن كان يرجو + +99 +00:12:42,170 --> 00:12:49,010 +لقاء ربه فليعمل عملا صالحا ولا يشرك بعبادة ربه + +100 +00:12:49,010 --> 00:12:56,130 +أحدا، وكذلك من معاني الإسلام اللغوية الإذعان وطاعته + +101 +00:12:56,130 --> 00:13:02,770 +ومنه قوله تبارك وتعالى وَلَهُ أَسْلَمَ مَن فِي السَّمَاوَاتِ + +102 +00:13:02,770 --> 00:13:09,590 +وَالأَرْضِ، أسلم بمعنى أذعن، وكذلك في قصة إبراهيم + +103 +00:13:09,590 --> 00:13:17,350 +وإسماعيل عليهما السلام، فلما أسلم بمعنى استسلم + +104 +00:13:17,350 --> 00:13:26,350 +وامتثل أمر الله عز وجل، أما المعنى الثالث فهو الأمن + +105 +00:13:26,350 --> 00:13:33,830 +والمصالحة، تقول سالم فلان فلان، إذا تصالح وأمن + +106 +00:13:33,830 --> 00:13:39,770 +بعضهما الآخر، وهذا أيضا سيأتي من خصائص النظم + +107 +00:13:39,770 --> 00:13:46,990 +الإسلامية، فإن الأمن والأمان لا يتحققان إلا في + +108 +00:13:46,990 --> 00:13:54,800 +الإسلام، الَّذِينَ آمَنُوا وَطَمْئَنَّتْ قُلُوبُهُمْ بِذِكْرِ اللَّهِ، أَلَا بِذِكْرِ اللَّهِ تَطْمَئِنُّ الْقُلُوبُ، نعم، أشرنا وقلنا كل هذه + +109 +00:13:54,800 --> 00:14:01,740 +المعاني اللغوية تتمثل في الإسلام كدين، أما في + +110 +00:14:01,740 --> 00:14:09,860 +الإصطلاح فإنّ النظم + +111 +00:14:09,860 --> 00:14:13,180 +تعرف عند الإسلاميين وعند غير الإسلاميين، نبدأ + +112 +00:14:14,750 --> 00:14:21,370 +بتعريف النظم عند غير الإسلاميين، فقولنا في الكتاب + +113 +00:14:21,370 --> 00:14:28,950 +ومن هنا عرفت النظم في الإصطلاح، للفت الأنظار إلى + +114 +00:14:28,950 --> 00:14:34,290 +أن هذا المصطلح عند غير المسلمين بمعنى القوانين + +115 +00:14:34,290 --> 00:14:41,820 +الوضعية غير الإسلامية، فإذا ما سئلتم عن تعريف النظم + +116 +00:14:41,820 --> 00:14:48,340 +غير الإسلامية أو النظم الوضعية، فهذا هو التعريف + +117 +00:14:48,340 --> 00:14:55,420 +وهنا نلحظ من التعريفين الآتين كلمة المجتمع وكلمة + +118 +00:14:55,420 --> 00:15:04,180 +الشعب، بمعنى أن الذي جاء بهذه القوانين ليس هو الله، + +119 +00:15:04,180 --> 00:15:12,280 +ليست من عند الله، وليست من عند رسول الله صلى الله + +120 +00:15:12,280 --> 00:15:18,880 +عليه وسلم، كما سيأتي في مصادر النظام الكتاب والسنة + +121 +00:15:18,880 --> 00:15:25,260 +والإجماع والقياس، فالشعب أو المجتمع هو الذي وضع هذه + +122 +00:15:25,260 --> 00:15:35,080 +القوانين، ومن هنا أحلوا لهم ما حرم الله حتى في غير + +123 +00:15:35,080 --> 00:15:42,420 +القرآن، حتى في التوراة والإنجيل والكتب السماوية + +124 +00:15:42,420 --> 00:15:47,600 +التي أنزلها الله على الأنبياء من قبل، فأحلوا الزنا + +125 +00:15:47,600 --> 00:15:53,740 +وأحلوا الربا، نعم، وأحلوا الخمر، وهذه كلها من + +126 +00:15:53,740 --> 00:16:03,360 +الكليات التي اتفقت الرسل على تحريمها، نعم، من هنا نرى + +127 +00:16:03,360 --> 00:16:11,810 +أنّ النظم عند غير المسلمين مصطلح عليه المجتمع، قلت لابد أن نضع خطا + +128 +00:16:11,810 --> 00:16:19,730 +عند قولنا المجتمع بمعنى أن الذي + +129 +00:16:19,730 --> 00:16:24,550 +وضع هذه النظم ليس هو الإسلام، ليس هو الله ورسوله + +130 +00:16:24,550 --> 00:16:30,230 +كما قال الله يا أَيُّهَا الَّذِينَ آمَنُوا أَطِيعُوا اللَّهَ وَأَطِيعُوا + +131 +00:16:30,230 --> 00:16:34,970 +الرَّسُولَ، بل الذي وضعها هو المجتمع، أو ما يسمى اليوم + +132 +00:16:34,970 --> 00:16:41,690 +بالبرلمان، أو ما يسمى عندنا بالمجلس التشريعي، أو ما + +133 +00:16:41,690 --> 00:16:49,030 +يسمى عند غيرنا بمجلس الشعب أو مجلس الأمة أو ال + +134 +00:16:49,030 --> 00:16:55,970 +Congress أو الKremlin ونحو ذلك، وفي الأصل هو الشورى + +135 +00:16:55,970 --> 00:17:01,920 +مصطلح عليه المجتمع، من أوضاع لتنظيم ما يسود الأفراد + +136 +00:17:01,920 --> 00:17:08,280 +من علاقات في شتى شؤون حياتهم، التزاماً بها وخضوعا + +137 +00:17:08,280 --> 00:17:14,580 +لها، والتعريف الثاني لا يبتعد كثيرا عن التعريف الأول + + + +141 +00:17:19,660 --> 00:17:24,560 +فالنظم عند غير المسلمين مجموعة من الأحكام اصطلح + +142 +00:17:24,560 --> 00:17:31,460 +شعب ما أيضا قلت نضع خطأ عند قولنا شعب ما فالذي وضع + +143 +00:17:31,460 --> 00:17:40,150 +هذه النظم هو الشعب نعم الذي انتخب البرلمان فمن أجل + +144 +00:17:40,150 --> 00:17:45,690 +إرضائهم أحلوا لهم ما حرم الله مجموعة من الأحكام + +145 +00:17:45,690 --> 00:17:52,890 +اصطلح شعب ما على أنها واجبة الاحترام وواجبة + +146 +00:17:52,890 --> 00:17:59,710 +التنفيذ لتنظيم الحياة المشتركة في مجتمع هذا الشعب + +147 +00:18:01,100 --> 00:18:11,400 +أما النظم الإسلامية فكما نرى هنا تعريفات ثلاثة نقف + +148 +00:18:11,400 --> 00:18:16,760 +عندها قليلا أول هذه التعريفات القواعد والمبادئ + +149 +00:18:16,760 --> 00:18:22,280 +والعادات التي تقوم عليها الحياة في ظل الإسلام + +150 +00:18:22,280 --> 00:18:31,250 +عقيدة وشريعة وخلق، والتي تحدد للإنسان حركة نشاطه في + +151 +00:18:31,250 --> 00:18:38,090 +كافة المجالات كما نرى أن كلمة الإسلام في هذا + +152 +00:18:38,090 --> 00:18:46,510 +التعريف واضحة فالنظم الإسلامية هي التي تقوم عليها + +153 +00:18:46,510 --> 00:18:54,430 +الحياة في ظل الإسلام عقيدة وشريعة وخلقا وكذلك + +154 +00:18:54,430 --> 00:19:00,130 +تعريف آخر، التعريف الثاني من تعريفات النظم + +155 +00:19:00,130 --> 00:19:04,430 +الإسلامية ما تفيده مجموعة القواعد والمبادئ التي + +156 +00:19:04,430 --> 00:19:10,230 +جاء بها الإسلام لتحديد النشاط البشري في الحياة على + +157 +00:19:10,230 --> 00:19:17,260 +مستوى الأفراد والجماعات داخل إطارها، وكما نرى أيضًا + +158 +00:19:17,260 --> 00:19:20,940 +أن كلمة الإسلام واضحة في هذا التعريف، أما التعريف + +159 +00:19:20,940 --> 00:19:27,800 +الثالث وكما نرى كلها قريبة ومتشابهة المناهج التي + +160 +00:19:27,800 --> 00:19:33,540 +رسمها الإسلام لسلوك المسلم وسلوك الجماعة المسلمة + +161 +00:19:33,540 --> 00:19:41,940 +ليستقيم أمر المجتمع، هكذا نرى أن ثمة تشابه + +162 +00:19:44,100 --> 00:19:50,940 +واختلافا بين النظم الإسلامية والنظم غير الإسلامية + +163 +00:19:50,940 --> 00:19:57,630 +أما وجه الشبه بين النظم الإسلامية وغير الإسلامية أن + +164 +00:19:57,630 --> 00:20:04,310 +كلًا منها شكل من أشكال النظم بوجه عام، من حيث إنها + +165 +00:20:04,310 --> 00:20:11,130 +تُطَبِّط وتنظم سلوك ومعاملات أفراد المجتمع الذي آمن + +166 +00:20:11,130 --> 00:20:19,510 +بها أو خضع وانقض لأحكامها وقوانينها، ولكنها تختلف من + +167 +00:20:19,510 --> 00:20:27,010 +جهات ثلاثة: أولا في المصدر، و ثانيا في الهدف، و ثالثا + +168 +00:20:27,010 --> 00:20:35,990 +في الخصائص، فمصدر النظم الإسلامية هو القرآن و السنة + +169 +00:20:36,610 --> 00:20:42,590 +أما مصدر النظم الوضعية البشر أو كما مر معنا في + +170 +00:20:42,590 --> 00:20:51,110 +المصطلحات الشعب والمجتمع الذين وضعوا هذه اللوائح + +171 +00:20:51,110 --> 00:20:59,810 +والتنظيمات، وأما من جهة الهدف فهدف النظم الإسلامية + +172 +00:21:00,310 --> 00:21:07,590 +إرضاء الله تبارك وتعالى وربط الناس بخالقهم، وأما + +173 +00:21:07,590 --> 00:21:12,790 +النظم الوطنية فالغاية منها والهدف هو إرضاء الشعوب + +174 +00:21:12,790 --> 00:21:17,230 +و إرضاء الناس الذين انتخبوهم + +175 +00:21:19,370 --> 00:21:28,530 +وجعلوهم في صدة الحكم، أما الخصائص فهي ثمانية وصنعتي + +176 +00:21:28,530 --> 00:21:34,370 +إليها في المبحث الثالث إن شاء الله تبارك وتعالى + +177 +00:21:34,370 --> 00:21:42,100 +الآن بعد أن تكلمنا عن تعريف النظم لغة واصطلاحا عند + +178 +00:21:42,100 --> 00:21:47,260 +المسلمين وعند غير المسلمين نأتي إلى المبحث الثاني + +179 +00:21:47,260 --> 00:21:54,320 +وهو بعنوان حاجة المجتمعات إلى النظم الإسلامية، نعم + +180 +00:21:54,320 --> 00:22:00,880 +ونحن نرى أن العالم قد جرب النظم الوضعية، جرب + +181 +00:22:00,880 --> 00:22:09,120 +الرأسمالية الغربية وجرب الشيوعية الشرقية، وشيوعيته + +182 +00:22:09,120 --> 00:22:17,150 +قد سقطت في مهدها في عقر دارها وتهوى صنم لينين في + +183 +00:22:17,150 --> 00:22:23,030 +الساحة الحمراء بموسكو، والرأسمالية الغربية في + +184 +00:22:23,030 --> 00:22:29,830 +طريقها إلى السقوط، ولا يبقى إلا الإسلام الدين الذي + +185 +00:22:29,830 --> 00:22:36,170 +أنزله الله للعالمين، وما أرسلناك إلا رحمة للعالمين + +186 +00:22:36,850 --> 00:22:43,590 +الآن ما هي الوجوه والاعتبارات التي تؤكد لنا حاجة + +187 +00:22:43,590 --> 00:22:51,950 +البشرية إلى النظم الإسلامية بعد أن سقطت كل الأقنعة + +188 +00:22:51,950 --> 00:23:00,110 +وكل اللوائح وكل التنظيمات البشرية والوضعية، ولم يبق + +189 +00:23:00,110 --> 00:23:07,290 +إلا الإسلام، نقول ما هي الوجوه والاعتبارات التي تدلل + +190 +00:23:07,290 --> 00:23:13,410 +على كلامنا هذا والتي تؤكد حاجة البشرية للنظم + +191 +00:23:13,410 --> 00:23:19,450 +الإسلامية، أولا إن النظم الإسلامية من وضعه خالق + +192 +00:23:19,450 --> 00:23:24,230 +البشر سبحانه وتعالى، فالله تبارك وتعالى هو الخالق + +193 +00:23:24,230 --> 00:23:32,190 +والخالق أدرى بخلقه، أدرى بما ينفعهم وأدرى بما + +194 +00:23:32,190 --> 00:23:34,190 +يصلحهم + +195 +00:23:35,250 --> 00:23:41,910 +كما قالوا كل صانع أضرب صنعته، والإنسان هو صنعة الله + +196 +00:23:41,910 --> 00:23:48,930 +تبارك وتعالى، وبنيان الرب عز وجل، قال الله تبارك + +197 +00:23:48,930 --> 00:23:55,910 +وتعالى ألا يعلم من خلقه وهو اللطيف الخبير، ثانيا، و + +198 +00:23:55,910 --> 00:24:01,750 +لأنها النظم التي يمكن أن تنال ثقة البشر واحترامهم + +199 +00:24:01,750 --> 00:24:11,890 +لها وإيمانهم بنزاهتها وعدالتها، ومن ثمار ذلك أنهم + +200 +00:24:11,890 --> 00:24:21,250 +يطبقوها في السر والعلن، لأنهم لم يؤمنوا بالقوة ولم + +201 +00:24:21,250 --> 00:24:29,240 +يؤمنوا بالإكراه وإنما آمنوا بالحب والود + +202 +00:24:29,240 --> 00:24:40,120 +فالعلاقة بين المسلم وبين ربه هي الحب والود، يحبهم + +203 +00:24:40,120 --> 00:24:47,640 +ويحبونه، إن الذين آمنوا وعملوا الصالحات سيجعل لهم + +204 +00:24:47,640 --> 00:24:54,840 +الرحمن ودا، ولذلك قال الله تبارك وتعالى لا إكراه في + +205 +00:24:54,840 --> 00:25:01,540 +الدين، قد تبين الرشد من الغيب، أفأنت تكره الناس حتى + +206 +00:25:01,540 --> 00:25:07,160 +يكونوا مؤمنين، وفي صورة الكهف من شاء فليؤمن ومن شاء + +207 +00:25:07,160 --> 00:25:15,440 +فليكفر، صدق الله العظيم، أما ثالثا لماذا + +208 +00:25:15,440 --> 00:25:22,200 +يحتاج الناس إلى النظم الإسلامية؟ لأنها النظم التي + +209 +00:25:22,200 --> 00:25:28,300 +تملِكُ إشاعة الأمن وتعميم الطمأنينة في نفوس + +210 +00:25:28,300 --> 00:25:33,940 +الملتزمين بها والمطبقين لأحكامها، طمأنينة مطلقة + +211 +00:25:33,940 --> 00:25:40,880 +خالية من شوائب القلق والإضطراب، وهذا لا يكون إلا + +212 +00:25:40,880 --> 00:25:45,500 +في الإسلام العظيم، فنحن نرى عند غير المسلمين + +213 +00:25:45,500 --> 00:25:56,570 +الانتحار لا عن فقر، وقد يكونوا أغنى الناس ويملكون + +214 +00:25:56,570 --> 00:26:04,230 +الملايين من الأموال، ولكن ينتحرون ويقتلون أنفسهم + +215 +00:26:04,230 --> 00:26:10,850 +لأنهم لا يشعرون بهذه الطمأنينة وبهذا الأمان وبهذه + +216 +00:26:10,850 --> 00:26:17,170 +السعادة التي يشعر بها المسلمون، فلا أمانة إلا + +217 +00:26:17,170 --> 00:26:22,790 +بالإيمان ولا سلامة إلا بالإسلام، وصدق الله العظيم + +218 +00:26:22,790 --> 00:26:30,870 +الذين آمنوا وتطمأن قلوبهم بذكر الله، ألا بذكر الله + +219 +00:26:30,870 --> 00:26:40,120 +تطمأن القلوب، أما رابعا من الوجوه والاعتبارات التي + +220 +00:26:40,120 --> 00:26:48,100 +تؤكد حاجة البشرية إلى النظم الإسلامية أنها لا تقف + +221 +00:26:48,100 --> 00:26:52,740 +في معالجتها للحياة البشرية على الجانب الحقوقي + +222 +00:26:52,740 --> 00:27:00,640 +المجرد أو على الماديات فحسب، فهي لا تقتصر على + +223 +00:27:00,640 --> 00:27:09,340 +الحدود ولا تقتصر على العقوبات وإنما تتعامل مع النفس + +224 +00:27:09,340 --> 00:27:17,780 +والضمير فتهذب النفس وتطهرها وترتقي بها إلى درجات + +225 +00:27:17,780 --> 00:27:28,340 +من الشفافية والرقة، ولذلك يعلم المسلم أن الله معه + +226 +00:27:28,340 --> 00:27:37,830 +رقيب وأن الله معه حسيب، يعد أنفاسنا سبحانه وتعالى + +227 +00:27:37,830 --> 00:27:46,690 +ويحصي خطواتنا، فالله معنا أينما ذهبنا وحيثما حللنا + +228 +00:27:46,690 --> 00:27:52,930 +ما يكون من نجوا ثلاثة إلا هو رابعهم ولا خمسة إلا + +229 +00:27:52,930 --> 00:27:59,490 +هو سادسهم، وسيأتي معنا حديث الإحسان أن تعبد الله + +230 +00:27:59,490 --> 00:28:04,950 +كأنك تراه، فإن لم تكن تراه فإنه يراك سبحانه وتعالى + +231 +00:28:04,950 --> 00:28:14,040 +نأتي هنا ببعض الأدلة من الكتاب ومن السنة على ذلك + +232 +00:28:14,040 --> 00:28:19,440 +فمن الآيات أيضًا قوله تبارك وتعالى قل إن تخفوا ما + +233 +00:28:19,440 --> 00:28:24,880 +في صدوركم أو تبدوه يعلمه الله، وقوله تبارك وتعالى + +234 +00:28:24,880 --> 00:28:31,130 +والله يعلم ما تسرون وما تعلنون، ويقول عز وجل والله + +235 +00:28:31,130 --> 00:28:36,850 +يعلم ما في قلوبكم، وكان الله عليما حليما، ويقول + +236 +00:28:36,850 --> 00:28:41,950 +سبحانه وتعالى يعلم خائنة الأعين وما تخفي الصدور + +237 +00:28:41,950 --> 00:28:47,590 +أما الأحاديث فكثيرة، نقتصر منها على ما في الكتاب + +238 +00:28:47,590 --> 00:28:53,930 +قوله صلى الله عليه وسلم إن الله لا ينظر إلى صوركم + +239 +00:28:53,930 --> 00:29:01,770 +ولا إلى أموالكم، ولكن ينظر إلى قلوبكم وأعمالكم، وكما + +240 +00:29:01,770 --> 00:29:06,930 +جاء في الحديث أيضا الإثم ما حاك في الصدر وكره + +241 +00:29:06,930 --> 00:29:13,250 +أن يطلع عليه الناس، فاستفت قلبك وإن أفتاك الناس + +242 +00:29:13,250 --> 00:29:22,740 +وأفتوك، نعم، إن لم يرك البشر فلا تستطيع أن تهرب من + +243 +00:29:22,740 --> 00:29:28,640 +الله سبحانه وتعالى، هكذا نرى أن النظام الإسلامية لا + +244 +00:29:28,640 --> 00:29:36,060 +تقتصر على القوانين وعلى اللوائح وعلى الماديات في + +245 +00:29:36,060 --> 00:29:43,100 +حسب، وإنما تربط العبد بربه وهو تقوى الله سبحانه + +246 +00:29:43,100 --> 00:29:53,160 +وتعالى في السر والعلن، وقد سمعنا عن قصة حصلت في بعض + +247 +00:29:53,160 --> 00:29:58,260 +الولايات الأمريكية أن التيار الكهربائي قد انقطع + +248 +00:29:58,260 --> 00:30:07,490 +لدقائق معدودة فارتكبت آلاف من الجرائم من السرقات + +249 +00:30:07,490 --> 00:30:14,230 +ومن الاغتصاب لأنه لم يعود عليهم رقيب أو حسيب من + +250 +00:30:14,230 --> 00:30:21,830 +الشرطة أو من الأجهزة الأمنية ونحو ذلك، أما خامسا + +251 +00:30:23,310 --> 00:30:28,670 +أيضا من الوجوه والاعتبارات التي تؤكد حاجة البشرية + +252 +00:30:28,670 --> 00:30:34,010 +إلى النظم الإسلامية أنها النظم التي أثبت الواقع + +253 +00:30:34,010 --> 00:30:41,900 +وشهدت تاريخه بصلاحيتها للتطبيق في حياة البشر وصلاح + +254 +00:30:41,900 --> 00:30:47,920 +أمرهم بها وانسجامها مع طبائعهم وفطرتهم، ولذلك + +255 +00:30:47,920 --> 00:30:53,940 +نستطيع أن نقول إن الشريعة الإسلامية صالحة للتطبيق + +256 +00:30:53,940 --> 00:31:03,660 +في كل مكان وزمان وعلى مر العصور والأزمنة والدهور + +257 +00:31:03,660 --> 00:31:12,740 +لأن الذي أنزلها هو الله سبحانه وتعالى، أما سادسا + +258 +00:31:12,740 --> 00:31:21,970 +لأنها النظم التي حصرت كل غايات البشر في غاية واحدة + +259 +00:31:21,970 --> 00:31:27,950 +وهي إرضاء الله تبارك وتعالى، كما حصرت كل أهداف + +260 +00:31:27,950 --> 00:31:33,030 +الناس في هدف واحد وهو تحقيق العبودية له سبحانه + +261 +00:31:33,030 --> 00:31:37,230 +وتعالى، وسنأتي في الفصل الثاني إلى الحديث عن + +262 +00:31:37,230 --> 00:31:43,310 +العبادة في الإسلام عن تعريفها لغة واصطلاحا وعن + +263 +00:31:43,310 --> 00:31:50,310 +مميزاتها وسماتها وغاياتها وعن خصائصها عند الوصول + +264 +00:31:50,310 --> 00:31:57,810 +إليها إن شاء الله تبارك وتعالى، أما سابعا وأخيرا + +265 +00:31:57,810 --> 00:32:06,930 +فتحتاج المجتمعات والشعوب إلى النظم الإسلامية لأنها + +266 +00:32:06,930 --> 00:32:15,510 +النظم التي تتميز بخصائص تجعل منها النظم الأوفق + +267 +00:32:15,510 --> 00:32:24,890 +والأولى والأسماء والأولى والأعلى والأوجب والالزم + +268 +00:32:24,890 --> 00:32:30,670 +وإن شاء الله في المبحث الثالث سوف نتناول هذه + +269 +00:32:30,670 --> 00:32:34,710 +الخصائص بشيء من التفصيل diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/bTQq402Vg8E_postprocess.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/bTQq402Vg8E_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..1ff084ef7bb39c1e27b4735e4eec4eadd7747abf --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/bTQq402Vg8E_postprocess.srt @@ -0,0 +1,1076 @@ +1 +00:00:04,990 --> 00:00:07,630 +أعوذ بالله السماء العلي من الشيطان الرجيم بسم الله + +2 +00:00:07,630 --> 00:00:11,130 +الرحمن الرحيم الحمد لله والصلاة والسلام على رسول + +3 +00:00:11,130 --> 00:00:16,350 +الله اللهم صلي وسلم على سيدنا محمد وعلى آله وصحبه + +4 +00:00:16,350 --> 00:00:23,630 +وسلم أجمعين أعزاء الطلابفي مساق النظم الإسلامية + +5 +00:00:23,630 --> 00:00:30,050 +قبل ذي بدء وارحبوا بكم جميعا في بداية فصل دراسي + +6 +00:00:30,050 --> 00:00:36,130 +جديد وأحييكم بتحية الإسلام العظيم فسلام الله عليكم + +7 +00:00:36,130 --> 00:00:42,930 +ورحمته وبركاتهسائلا المولى عز وجل لكم النجاحة + +8 +00:00:42,930 --> 00:00:50,850 +والتوفيق والسلامة والعافية من كل داء ووباء اللهم + +9 +00:00:50,850 --> 00:01:00,130 +آمين النظم الإسلامية المساق المطلوب من هذا الفصل + +10 +00:01:01,170 --> 00:01:07,230 +صنفه ثلاثة من زملائنا في كلية الشريعة والقانون في + +11 +00:01:07,230 --> 00:01:14,630 +الجامعة الإسلامية بغزة وهم أولا المرحوم بإذنه + +12 +00:01:14,630 --> 00:01:20,470 +تبارك وتعالى الدكتور أحمد إدياب إشوذح نسأل الله + +13 +00:01:20,470 --> 00:01:25,130 +تبارك وتعالى أن يغفر له وأن يرحمه وأن يسكنه فسيح + +14 +00:01:25,130 --> 00:01:30,970 +جنانه اللهم أمين ثانياالدكتور ماهر أحمد السوسي + +15 +00:01:30,970 --> 00:01:37,990 +حفظاه الله وثالثا الدكتور زياد إبراهيم مقداد حفظاه + +16 +00:01:37,990 --> 00:01:49,310 +الله وكتاب النظم الإسلامية عبارة عن فصل تمهدي وستة + +17 +00:01:49,310 --> 00:01:57,990 +فصول دراسية وليست كلها مطلوبة في الامتحانفالمقرر + +18 +00:01:57,990 --> 00:02:06,470 +منها أولا الفصل التمهيدي كاملا و ثانيا الفصل + +19 +00:02:06,470 --> 00:02:12,310 +الثاني مطلوب كاملا و هو بعنوان العبادة في الإسلام + +20 +00:02:12,310 --> 00:02:21,570 +و كذلك الفصل الثالث و هو بعنوان نظام الأخلاق في + +21 +00:02:21,570 --> 00:02:27,290 +الإسلام و هو مطلوب كاملا و الفصل الرابع أيضامطلوب + +22 +00:02:27,290 --> 00:02:34,050 +كاملا وهو بعنوان نظام الأسرة في الإسلام أما الفصل + +23 +00:02:34,050 --> 00:02:43,430 +السادس فهو عبارة عن مباحثة خمسة ليست كلها مطلوبة + +24 +00:02:43,430 --> 00:02:52,310 +المطلوب فقط هو المبحثان الأول والثاني تعريفالنظام + +25 +00:02:52,310 --> 00:02:57,570 +السياسي في الإسلام والقواعد الأربعة التي يقوم + +26 +00:02:57,570 --> 00:03:02,990 +عليها النظام السياسي في الإسلام هذه هي الفصول + +27 +00:03:02,990 --> 00:03:10,020 +المطلوبة والمقررة في الامتحان أما غير المطلوبفهو + +28 +00:03:10,020 --> 00:03:16,220 +أولا الفصل الأول كاملا وهو بعنوان العقيدة لأنه + +29 +00:03:16,220 --> 00:03:23,700 +سيدرس لكم في كلية أصول الدين في مساكن مستقل اذا + +30 +00:03:23,700 --> 00:03:30,190 +الفصل الأول وهو بعنوان العقيدة ليس مطلوبافي هذا + +31 +00:03:30,190 --> 00:03:36,370 +الفصل وكذلك الفصل الخامس وهو بعنوان الاقتصاد + +32 +00:03:36,370 --> 00:03:43,720 +الإسلامي ليس مطلوبا أيضا لأنه سيدرس لكمفي كلية + +33 +00:03:43,720 --> 00:03:53,100 +التجارة في مساق مستقل أيضا وكذلك كما أشرت في الفصل + +34 +00:03:53,100 --> 00:03:57,840 +السادس النظام السياسي في الإسلام ليس مطلوبا + +35 +00:03:57,840 --> 00:04:04,940 +المباحث الثلاثة من المباحث الخامسة التي يجتمل + +36 +00:04:04,940 --> 00:04:12,850 +عليها الفصل السادسوهم المبحث الثالث والمبحث الرابع + +37 +00:04:12,850 --> 00:04:17,670 +والمبحث الخامس فالمطلوب في الفصل السادس فقط + +38 +00:04:17,670 --> 00:04:25,390 +المبحثان الأول والثاني وإذا مررنا بأشياء ليست + +39 +00:04:25,390 --> 00:04:29,930 +مطلوبة في الامتحان سنأتي إلى ذكرها عند الوصول + +40 +00:04:29,930 --> 00:04:35,260 +إليها ان شاء اللهالان ان شاء الله وعلى بركة الله + +41 +00:04:35,260 --> 00:04:43,340 +نبدأ في الفصل التمهيدى والفصل التمهيدى أهمية دراسة + +42 +00:04:43,340 --> 00:04:50,860 +النظم الإسلامية عبارة عن أربعة مباحث أما المبحث + +43 +00:04:50,860 --> 00:04:57,160 +الأول فهو بعنوان تعريف النظم الإسلاميةأما المبحث + +44 +00:04:57,160 --> 00:05:01,680 +الثاني فهو بعنوان حاجة المجتمعات إلى النظم + +45 +00:05:01,680 --> 00:05:06,760 +الإسلامية أما المبحث الثالث فهو بعنوان خصائص النظم + +46 +00:05:06,760 --> 00:05:15,540 +الإسلامية وهذا المبحث هو أكبرالمباحث وأهم المباحث + +47 +00:05:15,540 --> 00:05:20,280 +في الفصل التمهيدي أما المبحث الرابع والأخير من + +48 +00:05:20,280 --> 00:05:24,880 +الفصل التمهيدي فهو بعنوان مصادر النظم الإسلامية + +49 +00:05:24,880 --> 00:05:32,640 +حيث نتكلم عن المصادر بنوعيها والمطلوب فقط في هذا + +50 +00:05:32,640 --> 00:05:41,300 +المبحث هوالمصادر الأربعة المتفق عليها وهي الكتاب + +51 +00:05:41,300 --> 00:05:48,780 +والصنة والإجماع والقياس وهناك مصادر مختلف عليها + +52 +00:05:48,780 --> 00:05:54,560 +ليست مطلوبة ولكن نشير اليها إشارة عند الوصول إليها + +53 +00:05:54,560 --> 00:06:04,660 +مثل العرف والمصالح المرسلة وسد الذراع ومذهبالصحابي + +54 +00:06:04,660 --> 00:06:11,820 +وشرعوا من قبلنا والاستصلاح ونحو ذلك من المصادر + +55 +00:06:11,820 --> 00:06:21,120 +التي تدرسلطلبتي كلية الشريعة و القانون نعم أما + +56 +00:06:21,120 --> 00:06:28,820 +المبحث الأول وهو تعريف النظم الإسلامية نأتي في هذا + +57 +00:06:28,820 --> 00:06:35,040 +المبحث إلى تعريف النظم الإسلامية لغة واصطلاحا بدءا + +58 +00:06:35,040 --> 00:06:43,060 +بتعريف النظم أما النظم عزيزي الطلاب فهي جمع نظام + +59 +00:06:44,100 --> 00:06:52,980 +وكلمة نظام تجمع على صيغن ثلاثة نظم وهو عنوان + +60 +00:06:52,980 --> 00:07:02,300 +الكتاب كما تجمع على أنظمة وعلى أنظيم كما ذكر في + +61 +00:07:02,300 --> 00:07:10,560 +لسان العرب ابن منظور الإفريقي ولكن الأشهر نظم + +62 +00:07:10,560 --> 00:07:21,900 +وأنظمةنظم اسلامية ونظم عربية نعم هكذا يقولون أما + +63 +00:07:21,900 --> 00:07:30,240 +أنظيم فهي الأقل شهرة وكلمة نظام أصلها اللغوي من + +64 +00:07:30,240 --> 00:07:37,960 +الفعل نظمة من الفعل الثلاثي المجرد النون والظاء + +65 +00:07:37,960 --> 00:07:46,910 +والميموكلمة نظمة تأتي في لغة العرب بمعانين متقاربة + +66 +00:07:46,910 --> 00:07:56,410 +مثل ضم و جمع و ألف كما قال الله تبارك و تعالى و + +67 +00:07:56,410 --> 00:08:07,230 +ألف بين قلوبهم بمعنى جمع و ضم و نظمة بين قلوبهم و + +68 +00:08:07,230 --> 00:08:15,440 +النظم هناهو نظم معنوي لأنه كما سيأتي بعد قليل كلمة + +69 +00:08:15,440 --> 00:08:24,540 +نظمة تأتي للاشياء الماديةكالعقد كما تأتي للأشياء + +70 +00:08:24,540 --> 00:08:35,760 +المعنوية كالقوانين والشعر ونحو ذلك وكما جاء في + +71 +00:08:35,760 --> 00:08:43,180 +الحديث الأرواح جنود مجندة ما تعرف منها اتلف وما + +72 +00:08:43,180 --> 00:08:50,680 +تناكر منها اختلف ما تعرف منها اتلف بمعنى انتظموهذا + +73 +00:08:50,680 --> 00:08:57,760 +أيضًا من المعاني المعنوية للفعل نظمة إذا الفعل + +74 +00:08:57,760 --> 00:09:04,040 +نظمة في لغة العرب يأتي بمعنى الضم و بمعنى الجمع و + +75 +00:09:04,040 --> 00:09:14,660 +بمعنى التأليف ولكن ضم الأشياء بعضها إلى بعض بترتيب + +76 +00:09:14,660 --> 00:09:23,650 +و استقامةهذا هو المعنى اللغوي للفعل نظمة إذا لو + +77 +00:09:23,650 --> 00:09:32,050 +كانت الأشياء مهلهلة أو كانت مبعثرة على غير استقامة + +78 +00:09:32,050 --> 00:09:39,840 +أو ترتيب لا يقال لها نظام في لغة العربإذا ألف و + +79 +00:09:39,840 --> 00:09:46,800 +جمع و ضم الأشياء بعضها إلى بعض في تنسيق و استقامة + +80 +00:09:46,800 --> 00:09:56,280 +هو معنى الفعل نظاما ولذلك صمي العقد نظاما وهذا هو + +81 +00:09:56,280 --> 00:10:05,720 +المعنى المادي للفعل نظاما والعقدبكسر العين لأن + +82 +00:10:05,720 --> 00:10:15,420 +العقد على خلاف ذلك وهو الخرز الذي يتدلى على صدر + +83 +00:10:15,420 --> 00:10:21,800 +المرأة ومنه كتاب العقد الفريد لابن عبدربه + +84 +00:10:21,800 --> 00:10:29,880 +الاندلوسيتي نعم لأن حبات العقد ضم بعضها إلى بعض في + +85 +00:10:29,880 --> 00:10:37,040 +ترتيبوإستقامة أو كما سيأتي معنا في خصائص النظم + +86 +00:10:37,040 --> 00:10:45,140 +الإسلامية في تكامل وفي ترابط وعليه تأتي كلمة نظام + +87 +00:10:45,140 --> 00:10:54,800 +على كل ما يجمع من أشياء مادية كما أشرنا إلى ذلك في + +88 +00:10:54,800 --> 00:11:04,120 +العقد وكذلك الصبح فالصبحة أيضاتعتبر نظاما أو + +89 +00:11:04,120 --> 00:11:11,820 +منظومة لماذا؟ لأن الخرز قد ضم بعضه إلى بعض بترتيب + +90 +00:11:11,820 --> 00:11:19,520 +واستقامة فإذا انفرط الأخضر وتناثر الحبات وصارت كل + +91 +00:11:19,520 --> 00:11:27,460 +حبة في واد فلا يطلق على ذلك نظام نعم وكذلك + +92 +00:11:29,190 --> 00:11:34,670 +النظم المعنوي كالأنظمة + +93 +00:11:34,670 --> 00:11:43,030 +والقوانين والشعر لماذا سمى الشعر أيضا منظومة لأنه + +94 +00:11:43,030 --> 00:11:49,130 +ينتهي بالوزن والقافلة فالشعر الذي لا ينتهي بالوزن + +95 +00:11:49,130 --> 00:11:57,970 +والقافلة لا يسمى شعرا نعم أما الإسلام + +96 +00:11:59,850 --> 00:12:11,730 +فهو أصله اللغوي من معاني متقاربة وهي ثلاثة أول هذه + +97 +00:12:11,730 --> 00:12:19,110 +المعاني هو الخلوص والتجرد فمعنى + +98 +00:12:20,050 --> 00:12:28,810 +أسلم يعني سلم له الشيء أي خالص له ولم ينازح فيه + +99 +00:12:28,810 --> 00:12:36,010 +أحد وهذا أيضًا من معاني الإسلام العظيم فلابد أن + +100 +00:12:36,010 --> 00:12:42,170 +تكون العبادة خالصة لله سبحانه وتعالىفمن كان يرجو + +101 +00:12:42,170 --> 00:12:49,010 +لقاء ربه فليعمل عملا صالحا ولا يشرك بعبادة ربه + +102 +00:12:49,010 --> 00:12:56,130 +أحدا وكذلك من معاني الإسلام اللغوية الاذعانواطاعته + +103 +00:12:56,130 --> 00:13:02,770 +ومنه قوله تبارك وتعالى وله أسلم من في السماوات + +104 +00:13:02,770 --> 00:13:09,590 +والأرض أسلم بمعنى أزعنه وكذلك في قصة إبراهيم + +105 +00:13:09,590 --> 00:13:17,350 +وإسماعيل عليهم السلام فلمّا أسلم بمعنى استسلم + +106 +00:13:17,350 --> 00:13:26,350 +وامتثل أمر الله عز وجلأما المعنى الثالث فهو الأمن + +107 +00:13:26,350 --> 00:13:33,830 +والمصالحة تقول سالم فلان فلان إذا تصالح وأمن + +108 +00:13:33,830 --> 00:13:39,770 +بعضهما الآخر وهذا أيضًا سيأتي من خصائص النظم + +109 +00:13:39,770 --> 00:13:46,990 +الإسلامية فإن الأمن والأمان لا يتحققان إلا في + +110 +00:13:46,990 --> 00:13:54,800 +الإسلامالذين آمنوا و تطمأنوا قلوبهم بذكر الله ألا + +111 +00:13:54,800 --> 00:14:01,740 +بذكر الله تطمأنه القلوب نعم أشرنا و قلنا كل هذه + +112 +00:14:01,740 --> 00:14:09,860 +المعاني اللغوية تتمثل في الإسلام كدين أما في + +113 +00:14:09,860 --> 00:14:13,180 +الإصطلاح فأنظم + +114 +00:14:14,750 --> 00:14:21,370 +تُعرّف عند الإسلاميين وعند غير الإسلاميين نبدأ + +115 +00:14:21,370 --> 00:14:28,950 +بتعريف النظم عند غير الإسلاميين فقولنا في الكتاب + +116 +00:14:28,950 --> 00:14:34,290 +ومن هنا عُرفت النظم في الإصطلاح للفتو الأنظار إلى + +117 +00:14:34,290 --> 00:14:41,820 +أن هذا المصطلح عند غير المسلمينبمعنى القوانين + +118 +00:14:41,820 --> 00:14:48,340 +الوضعية غير الإسلامية فإذا ما سئلتم عن تعريف النظم + +119 +00:14:48,340 --> 00:14:55,420 +غير الإسلامية أو النظم الوضعية فهذا هو التعريف + +120 +00:14:55,420 --> 00:15:04,180 +وهنا نلحظ من التعريفين الآتين كلمة المجتمع وكلمة + +121 +00:15:04,180 --> 00:15:12,280 +الشعب بمعنى أن الذي جاءبهذه القوانين ليس هو الله + +122 +00:15:12,280 --> 00:15:18,880 +ليست من عند الله وليست من عند رسول الله صلى الله + +123 +00:15:18,880 --> 00:15:25,260 +عليه وسلم كما سيأتي في مصادر النظام الكتاب والصنة + +124 +00:15:25,260 --> 00:15:35,080 +والإجماع والقياس فالشعب أو المجتمع هو الذي وضع هذه + +125 +00:15:35,080 --> 00:15:42,420 +القوانينو من هنا أحلوا لهم ما حرم الله حتى في غير + +126 +00:15:42,420 --> 00:15:47,600 +القرآن حتى في التوراة و الإنجيل و الكتب السماوية + +127 +00:15:47,600 --> 00:15:53,740 +اللتي أنزلها الله على الأنبياء من قبل فأحلوا الزنا + +128 +00:15:53,740 --> 00:16:03,360 +و أحلوا الربا نعم و أحلوا الخمر و هذه كلها من + +129 +00:16:03,360 --> 00:16:11,810 +الكلياتالتي اتفقت الرسل على تحريمها نعم من هنا نرى + +130 +00:16:11,810 --> 00:16:19,730 +أن النظم عند غير المسلمين مصطلح عليه المجتمع قلت + +131 +00:16:19,730 --> 00:16:24,550 +لابد أن نضع خطا عند قولنا المجتمع بمعنى أن الذي + +132 +00:16:24,550 --> 00:16:30,230 +وضع هذه النظم ليس هو الإسلام ليس هو الله ورسوله + +133 +00:16:30,230 --> 00:16:34,970 +كما قال الله يا أيها الذين آمنوا اطيعوا اللهوأطيع + +134 +00:16:34,970 --> 00:16:41,690 +الرسولة بل الذي مضعها هو المجتمع او ما يسمى اليوم + +135 +00:16:41,690 --> 00:16:49,030 +بالبرلمان او ما يسمى عندنا بالمجلس التشريعي او ما + +136 +00:16:49,030 --> 00:16:55,970 +يسمى عند غيرنا بمجلس الشعب او مجلس الأمة او ال + +137 +00:16:55,970 --> 00:17:01,920 +congress او ال kremlin ونحو ذلك وفي الأصل هوالشورة + +138 +00:17:01,920 --> 00:17:08,280 +مصطلح عليه المجتمع من أوضاع لتنظيم ما يسود الأفراد + +139 +00:17:08,280 --> 00:17:14,580 +من علائقة في شتى شؤون حياتهم التثامن بها وخضوعا + +140 +00:17:14,580 --> 00:17:19,660 +لهاوالتعريف الثاني لا يبتعد كثيرا عن التعريف الأول + +141 +00:17:19,660 --> 00:17:24,560 +فالنظم عند غير المسلمين مجموعة من الأحكام اصطلح + +142 +00:17:24,560 --> 00:17:31,460 +شعب ما أيضا قلت نضع خطا عند قولنا شعب ما فالذي وضع + +143 +00:17:31,460 --> 00:17:40,150 +هذه النظم هو الشعب نعم الذي انتخبالبرلمان فمن أجل + +144 +00:17:40,150 --> 00:17:45,690 +إرضائهم أحلوا لهم ما حرم الله مجموعة من الأحكام + +145 +00:17:45,690 --> 00:17:52,890 +اصطلح شعب ما على أنها واجبة الاحترام وواجبة + +146 +00:17:52,890 --> 00:17:59,710 +التنفيذ لتنظيم الحياة المشتركة في مجتمع هذا الشعب + +147 +00:18:01,100 --> 00:18:11,400 +أما النظم الإسلامية فكما نرى هنا تعريفات ثلاثة نقف + +148 +00:18:11,400 --> 00:18:16,760 +عندها قليلا أول هذه التعريفات القواعد والمبادئ + +149 +00:18:16,760 --> 00:18:22,280 +والعادات التي تقوم عليها الحياة في ظل الإسلام + +150 +00:18:22,280 --> 00:18:31,250 +عقيدة وشريعة وخلقاوالتي تحدد للإنسان حركة نشاطه في + +151 +00:18:31,250 --> 00:18:38,090 +كافة المجالات كما نرى أن كلمة الإسلام في هذا + +152 +00:18:38,090 --> 00:18:46,510 +التعريف واضحة فالنظم الإسلامية هي التي تقومعليها + +153 +00:18:46,510 --> 00:18:54,430 +الحياة في ظل الإسلام عقيدة وشريعة وخلقا وكذلك + +154 +00:18:54,430 --> 00:19:00,130 +تعريف آخر التعريف الثاني من تعريفات النظم + +155 +00:19:00,130 --> 00:19:04,430 +الإسلامية ما تفيده مجموعة القواعد والمبادئ التي + +156 +00:19:04,430 --> 00:19:10,230 +جاء بها الإسلام لتحديد النشاط البشري في الحياة على + +157 +00:19:10,230 --> 00:19:17,260 +مستوى الأفراد والجماعات داخل إطارهاوكما نرى أيضًا + +158 +00:19:17,260 --> 00:19:20,940 +أن كلمة الإسلام واضحة في هذا التعريف أما التعريف + +159 +00:19:20,940 --> 00:19:27,800 +الثالث وكما نرى كلها قريبة ومتشابهة المناهج التي + +160 +00:19:27,800 --> 00:19:33,540 +رسمها الإسلام لسلوك المسلم وسلوك الجماعة المسلمة + +161 +00:19:33,540 --> 00:19:41,940 +ليستقيم أمر المجتمع هكذا نرى أن ثمة تشابه + +162 +00:19:44,100 --> 00:19:50,940 +واختلافا بين النظم الإسلامية والنظم غير الإسلامية + +163 +00:19:50,940 --> 00:19:57,630 +أما وجه الشبه بين النظم الإسلامية وغير الإسلاميةأن + +164 +00:19:57,630 --> 00:20:04,310 +كلًا منها شكل من أشكال النظم بوجه عام، من حيث إنها + +165 +00:20:04,310 --> 00:20:11,130 +تطبط وتنظم صلوك ومعاملات أفراد المجتمع الذي آمن + +166 +00:20:11,130 --> 00:20:19,510 +بها أو خضع وانقض لأحكامها وقوانينهاولكنها تختلف من + +167 +00:20:19,510 --> 00:20:27,010 +جهات ثلاثة أولا في المصدر و ثانيا في الهدف و ثالثا + +168 +00:20:27,010 --> 00:20:35,990 +في الخصائص فمصدر النظم الإسلامية هو القرآن و الصنة + +169 +00:20:36,610 --> 00:20:42,590 +أما مصدر النظم الوضعية البشر أو كما مر معنا في + +170 +00:20:42,590 --> 00:20:51,110 +المصطلحات الشعب والمجتمع الذين وضعوا هذه اللوائح + +171 +00:20:51,110 --> 00:20:59,810 +والتنظيمات وأما من جهة الهدف فهدف النظم الإسلامية + +172 +00:21:00,310 --> 00:21:07,590 +إرضاء الله تبارك وتعالى وربط الناس بخالقهم وأما + +173 +00:21:07,590 --> 00:21:12,790 +النظم الوطنية فالغاية منها و الهدف هو إرضاء الشعوب + +174 +00:21:12,790 --> 00:21:17,230 +و إرضاء الناس الذين انتخبوهم + +175 +00:21:19,370 --> 00:21:28,530 +وجعلوهم في صدة الحكم اما الخصائص فهي ثمانية وصنعتي + +176 +00:21:28,530 --> 00:21:34,370 +اليها في المبحث الثالث ان شاء الله تبارك وتعالى + +177 +00:21:34,370 --> 00:21:42,100 +الآن بعد ان تكلمنا عن تعريف النظملغة واصطلاحا عند + +178 +00:21:42,100 --> 00:21:47,260 +المسلمين وعند غير المسلمين نأتي إلى المبحث الثاني + +179 +00:21:47,260 --> 00:21:54,320 +وهو بعنوان حاجة المجتمعاتإلى النظم الإسلامية نعم + +180 +00:21:54,320 --> 00:22:00,880 +ونحن نرى أن العالم قد جرب النظم الوضعية جرب + +181 +00:22:00,880 --> 00:22:09,120 +الرأسمالية الغربية وجرب الشيوعية الشرقية وشيوعيته + +182 +00:22:09,120 --> 00:22:17,150 +قد سقطت في مهدهافي عقر دارها وتهوى صنم لينين في + +183 +00:22:17,150 --> 00:22:23,030 +الساحة الحمراء بموسكو والرأسمالية الغربية في + +184 +00:22:23,030 --> 00:22:29,830 +طريقها إلى السقوط ولا يبقى إلا الإسلام الدين الذي + +185 +00:22:29,830 --> 00:22:36,170 +أنزله الله للعالمين وما أرسلناك إلا رحمة للعالمين + +186 +00:22:36,850 --> 00:22:43,590 +الآن ما هي الوجوه والاعتبارات التي تؤكد لنا حاجة + +187 +00:22:43,590 --> 00:22:51,950 +البشرية إلى النظم الإسلامية بعد أن سقطت كل الأقنعة + +188 +00:22:51,950 --> 00:23:00,110 +وكل اللوائح وكل التنظيمات البشرية والوضعية ولم يبق + +189 +00:23:00,110 --> 00:23:07,290 +إلا الإسلام نقول ما هي الوجوه والاعتباراتالتي تدلل + +190 +00:23:07,290 --> 00:23:13,410 +على كلامنا هذا والتي تؤكد حاجة البشرية للنظم + +191 +00:23:13,410 --> 00:23:19,450 +الإسلامية أولا إن النظم الإسلامية من وضعه خالق + +192 +00:23:19,450 --> 00:23:24,230 +البشر سبحانه وتعالى فالله تبارك وتعالى هو الخالق + +193 +00:23:24,230 --> 00:23:32,190 +والخالق أدرى بخلقه أدرى بما ينفعهم وأدرى بما + +194 +00:23:32,190 --> 00:23:34,190 +يصلحهم + +195 +00:23:35,250 --> 00:23:41,910 +كما قالوا كل صانع أضرب صنعته والإنسان هو صنعة الله + +196 +00:23:41,910 --> 00:23:48,930 +تبارك وتعالى وبنيان الرب عز وجل قال الله تبارك + +197 +00:23:48,930 --> 00:23:55,910 +وتعالى ألا يعلم من خلقه وهو اللطيف الخبيرثانيا و + +198 +00:23:55,910 --> 00:24:01,750 +لأنها النظم التي يمكن أن تنال ثقة البشر واحترامهم + +199 +00:24:01,750 --> 00:24:11,890 +لها و إيمانهم بنزاعتها وعدالتها و من ثمار ذلك أنهم + +200 +00:24:11,890 --> 00:24:21,250 +يطبقوها في السر و العلن لأنهم لم يؤمنوا بالقوة و + +201 +00:24:21,250 --> 00:24:29,240 +لم يؤمنوا بالإكراروإنما آمنوا بالحب و الود + +202 +00:24:29,240 --> 00:24:40,120 +فالعلاقة بين المسلم وبين ربه هي الحب و الود يحبهم + +203 +00:24:40,120 --> 00:24:47,640 +و يحبونه إن الذين آمنوا و عملوا الصالحات سيجعل لهم + +204 +00:24:47,640 --> 00:24:54,840 +الرحمن ودا ولذلكقال الله تبارك وتعالى لا إكراه في + +205 +00:24:54,840 --> 00:25:01,540 +الدين قد تبين الرشد من الغيب أفأنت تكره الناس حتى + +206 +00:25:01,540 --> 00:25:07,160 +يكونوا مؤمنين وفي صورة الكهف من شاء فليؤمن ومن شاء + +207 +00:25:07,160 --> 00:25:15,440 +فليكفر صدق الله العظيم أما ثالثا لماذا + +208 +00:25:15,440 --> 00:25:22,200 +يحتاج الناس إلى النظم الإسلاميةلأنها النظم التي + +209 +00:25:22,200 --> 00:25:28,300 +تملكوا إشاعة الأمن و تعميم الطمأنينة في نفوس + +210 +00:25:28,300 --> 00:25:33,940 +الملتزمين بها و المطبقين لأحكامها طمأنينة مطلقة + +211 +00:25:33,940 --> 00:25:40,880 +خالية من شوائب القلق و الإضطراب وهذا لا يكون إلا + +212 +00:25:40,880 --> 00:25:45,500 +في الإسلام العظيم فنحن نرى عند غير المسلمين + +213 +00:25:45,500 --> 00:25:56,570 +الانتحارلا عن فقر وقد يكونوا أغنى الناس ويملكون + +214 +00:25:56,570 --> 00:26:04,230 +الملايين من الأموال ولكن ينتحرون ويقتلون أنفسهم + +215 +00:26:04,230 --> 00:26:10,850 +لأنهم لا يشعرونبهذه الطمأنينة وبهذا الأمان وبهذه + +216 +00:26:10,850 --> 00:26:17,170 +السعادة التي يشعر بها المسلمون فلا أمانة إلا + +217 +00:26:17,170 --> 00:26:22,790 +بالإيمان ولا سلامة إلا بالإسلام وصدق الله العظيم + +218 +00:26:22,790 --> 00:26:30,870 +الذين آمنوا وتطمأن قلوبهم بذكر الله ألا بذكر الله + +219 +00:26:30,870 --> 00:26:40,120 +تطمأن القلوب أما رابعامن الوجوه والاعتبارات التي + +220 +00:26:40,120 --> 00:26:48,100 +تؤكد حاجة البشرية إلى النظم الإسلامية أنها لا تقف + +221 +00:26:48,100 --> 00:26:52,740 +في معالجتها للحياة البشرية على الجانب الحقوقي + +222 +00:26:52,740 --> 00:27:00,640 +المجرد أو على الماديات فحسب فهي لا تقتصر على + +223 +00:27:00,640 --> 00:27:09,340 +الحدود ولا تقتصر على العقوباتوإنما تتعامل مع النفس + +224 +00:27:09,340 --> 00:27:17,780 +والضمير فتهذب النفس وتطهرها وترتقي بها إلى درجات + +225 +00:27:17,780 --> 00:27:28,340 +من الشفافية والرقة ولذلك يعلم المسلم أن الله معه + +226 +00:27:28,340 --> 00:27:37,830 +رقيب وأن الله معه حسيب يعد أنفاسنا سبحانه وتعالى + +227 +00:27:37,830 --> 00:27:46,690 +ويحصي خطواتنا فالله معنا أينما ذهبنا وحيثما حللنا + +228 +00:27:46,690 --> 00:27:52,930 +ما يكون من نجوا ثلاثة إلا هو رابعهم ولا خمسة إلا + +229 +00:27:52,930 --> 00:27:59,490 +هو سادسهم وسيأتي معنا حديث الإحسان أن تعبد الله + +230 +00:27:59,490 --> 00:28:04,950 +كأنك تراه فإن لم تكن تراه فإنه يراك سبحانه وتعالى + +231 +00:28:04,950 --> 00:28:14,040 +نأتي هنالبعض الأدلة من الكتاب ومن السنة على ذلك + +232 +00:28:14,040 --> 00:28:19,440 +فمن الآيات أيضًا قوله تبارك وتعالى قل إن تخفوا ما + +233 +00:28:19,440 --> 00:28:24,880 +في صدوركم أو تبدوه يعلمه الله وقوله تبارك وتعالى + +234 +00:28:24,880 --> 00:28:31,130 +والله يعلم ما تسرون وما تعلنونويقول عز وجل والله + +235 +00:28:31,130 --> 00:28:36,850 +يعلم ما في قلوبكم وكان الله عليما حليما ويقول + +236 +00:28:36,850 --> 00:28:41,950 +سبحانه وتعالى يعلم خائنة الأعين وما تخفي الصدور + +237 +00:28:41,950 --> 00:28:47,590 +أما الأحاديث فكثيرة نقتصر منها على ما في الكتاب + +238 +00:28:47,590 --> 00:28:53,930 +قوله صلى الله عليه وسلم إن الله لا ينظر إلى صوركم + +239 +00:28:53,930 --> 00:29:01,770 +ولا إلى أموالكم ولكن ينظر إلى قلوبكموأعمالكم وكما + +240 +00:29:01,770 --> 00:29:06,930 +جاء في الحديث أيضا الاثم ما حاك في الصدر وكره تأي + +241 +00:29:06,930 --> 00:29:13,250 +يطلع عليه الناس فاستفت قلبك وإن أفتاك الناس و + +242 +00:29:13,250 --> 00:29:22,740 +أفتوك نعم إن لم يرك البشرفلا تستطيع أن تهرب من + +243 +00:29:22,740 --> 00:29:28,640 +الله سبحانه وتعالى هكذا نرى أن النظام الإسلامية لا + +244 +00:29:28,640 --> 00:29:36,060 +تقتصر على القوانين وعلى اللوائحوعلى الماديات في + +245 +00:29:36,060 --> 00:29:43,100 +حسب وإنما تربط العبد بربه وهو تقوى الله سبحانه + +246 +00:29:43,100 --> 00:29:53,160 +وتعالى في السر والعلن وقد سمعنا عن قصة حصلت في بعض + +247 +00:29:53,160 --> 00:29:58,260 +الولايات الأمريكية أن التيار الكهربائي قد انقطع + +248 +00:29:58,260 --> 00:30:07,490 +لدقائق معدودةفارتكبت آلاف من الجرائم من السرقات + +249 +00:30:07,490 --> 00:30:14,230 +ومن الإغتصاب لأنه لم يعود عليهم رقيب أو حسيب من + +250 +00:30:14,230 --> 00:30:21,830 +الشرطة أو من الأجهزة الأمنية ونحو ذلك أما خامسا + +251 +00:30:23,310 --> 00:30:28,670 +أيضًا من الوجوه والاعتبارات التي تؤكد حاجة البشرية + +252 +00:30:28,670 --> 00:30:34,010 +إلى النظم الإسلامية أنها النظم التي أثبت الواقع + +253 +00:30:34,010 --> 00:30:41,900 +وشهدت تاريخه بصلاحيتها للتطبيق في حياة البشروصلاح + +254 +00:30:41,900 --> 00:30:47,920 +أمرهم بها وانسجامها مع طبائعهم وفطرتهم ولذلك + +255 +00:30:47,920 --> 00:30:53,940 +نستطيع أن نقول إن الشريعة الإسلامية صالحة للتطبيق + +256 +00:30:53,940 --> 00:31:03,660 +في كل مكان وزمان وعلى مر العصور والأزمنة والدهور + +257 +00:31:03,660 --> 00:31:12,740 +لأن الذي أنزلها هو الله سبحانه وتعالىأما ثالثاً + +258 +00:31:12,740 --> 00:31:21,970 +لأنها النظم التي حصرت كل غايات البشرفي غاية واحدة + +259 +00:31:21,970 --> 00:31:27,950 +وهي إرضاء الله تبارك وتعالى كما حصرت كل أهداف + +260 +00:31:27,950 --> 00:31:33,030 +الناس في هدف واحد وهو تحقيق العبودية له سبحانه + +261 +00:31:33,030 --> 00:31:37,230 +وتعالى وسنأتي في الفصل الثاني إلى الحديث عن + +262 +00:31:37,230 --> 00:31:43,310 +العبادة في الإسلام عن تعريفها لغة واصطلاحاوعن + +263 +00:31:43,310 --> 00:31:50,310 +مميزاتها وسماتها وغاياتها وعن خصائصها عند الوصول + +264 +00:31:50,310 --> 00:31:57,810 +إليها إن شاء الله تبارك وتعالى أما سابعا وأخيرا + +265 +00:31:57,810 --> 00:32:06,930 +فتحتاج المجتمعات والشعوب إلى النظم الإسلامية لأنها + +266 +00:32:06,930 --> 00:32:15,510 +النظم التي تتميزبخصائص تجعل منها النظم الأوفق + +267 +00:32:15,510 --> 00:32:24,890 +والأولى والأسماء والأولى والأعلى والأوجب والالزم + +268 +00:32:24,890 --> 00:32:30,670 +وإن شاء الله في المبحث الثالث سوف نتناول هذه + +269 +00:32:30,670 --> 00:32:34,710 +الخصائص بشيء من التفصيل + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/djMgXUXQZ5g_postprocess.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/djMgXUXQZ5g_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..cf64f3c81b2d99a923001fd2761b9c6c4ebce422 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/djMgXUXQZ5g_postprocess.srt @@ -0,0 +1,1840 @@ +1 +00:00:05,010 --> 00:00:07,490 +أعوذ بالله السماء العليا من الشيطان الرجيم بسم + +2 +00:00:07,490 --> 00:00:11,390 +الله الرحمن الرحيم الحمد لله والصلاة والسلام على + +3 +00:00:11,390 --> 00:00:15,890 +رسول الله اللهم صلى على سيدنا محمد وعلى آله وصحبه + +4 +00:00:15,890 --> 00:00:20,430 +وسلم أجمعين أعزاء الطلاب قبل ذي بدء ورحبوا بكم في + +5 +00:00:20,430 --> 00:00:25,230 +محاضرة جديدة وأحييكم بتحية الإسلام فالسلام الله + +6 +00:00:25,230 --> 00:00:29,390 +عليكم ورحمته وبركاته نحن اليوم على موعد ان شاء + +7 +00:00:29,390 --> 00:00:35,980 +اللهمع تكملة المبحث الرابع من مباحث الفصل التمهيدي + +8 +00:00:35,980 --> 00:00:41,440 +وهو بعنوان مصادر النظم الإسلامية وسبق أن تكلمنا عن + +9 +00:00:41,440 --> 00:00:47,500 +المصدر الأول وهو كلي الشريعة ومصدر المصادر اللى هو + +10 +00:00:47,500 --> 00:00:53,080 +القرآن الكريم وتكلمنا عن تعريفه واصطنبطنا من + +11 +00:00:53,080 --> 00:00:58,760 +التعريفالخواص واليوم ان شاء الله نكمل بقية المصادر + +12 +00:00:58,760 --> 00:01:06,380 +بدء بالصنة النبوية ومرورا بالاجماع و القيادة أما + +13 +00:01:06,380 --> 00:01:13,760 +الصنة النبوية وهي المصدر الثاني من مصادر النظم + +14 +00:01:13,760 --> 00:01:15,840 +الإسلامية + +15 +00:01:17,070 --> 00:01:22,910 +فتعريفها ما نقل عن النبي صلى الله عليه وسلم من قول + +16 +00:01:22,910 --> 00:01:31,770 +أو فعل أو تقرير فالصنة إما أن تكون قولية وإما أن + +17 +00:01:31,770 --> 00:01:40,400 +تكونفعلية و إما أن تكون تقريرية أما الصنة القولية + +18 +00:01:40,400 --> 00:01:44,680 +فكل الأحاديث التي وردت عن النبي عليه الصلاة + +19 +00:01:44,680 --> 00:01:52,200 +والسلام في كتب الصنة الصحيحة وأهمهاالصحيحان + +20 +00:01:52,200 --> 00:02:00,960 +البخاري ومسلم ثم الصنان الأربعة الترمذي وابو داود + +21 +00:02:00,960 --> 00:02:07,160 +والنسائي وابن ماجة وكذلك مُسند الإمام أحمد وموطأ + +22 +00:02:07,160 --> 00:02:14,080 +مالك إلى غير ذلك من الموسوعات الحدثية فكل هذهتصلح + +23 +00:02:14,080 --> 00:02:20,580 +أمثلة ونماذج للصنة القولية مثل قوله عليه الصلاة + +24 +00:02:20,580 --> 00:02:27,400 +والسلام إنما الأعمال بالنيان أما الصنة الفعلية فهي + +25 +00:02:27,400 --> 00:02:32,120 +ما ورد عن النبي صلى الله عليه وسلم في كيفية صلاته + +26 +00:02:32,120 --> 00:02:40,350 +وصومه وحجه وزكاته وجهاده وسلمهوحربه وزواجه وطلاقه + +27 +00:02:40,350 --> 00:02:46,590 +ونومه واصطيقاضه صلى الله عليه وسلم وسيأتي معنا بعد + +28 +00:02:46,590 --> 00:02:52,430 +قليل قوله صلى الله عليه وسلم صلوا كما رأيتموني + +29 +00:02:52,430 --> 00:02:58,370 +أصلي وقوله صلى الله عليه وسلم في الحج خذوا عني + +30 +00:02:58,370 --> 00:03:06,040 +مناسككم أما الصنة التقريريةفهي ما أقره الرسول صلى + +31 +00:03:06,040 --> 00:03:13,800 +الله عليه وسلم للصحابة الكرام إذا رأهم يفعلون شيئا + +32 +00:03:13,800 --> 00:03:20,660 +أو يقومون بعمل ولم يعترض عليه وسكت عنه وأقراهم + +33 +00:03:20,660 --> 00:03:28,750 +عليه فهو الصنة التقريرية وقد تكلمنا عنخالد بن + +34 +00:03:28,750 --> 00:03:33,350 +الوليد رضي الله عنه في محاضرة سابقة لما رأاه النبي + +35 +00:03:33,350 --> 00:03:39,230 +عليه الصلاة والسلام يأكل الضب فأقراه على أكل الضب + +36 +00:03:39,230 --> 00:03:44,790 +والنبي عليه الصلاة والسلام لم يأكل الضب وإنما أقرا + +37 +00:03:44,790 --> 00:03:50,410 +خالدا على أكل الضب فدل ذلك على مشروعية أكل الضب + +38 +00:03:50,410 --> 00:03:58,580 +فهذا مثال لصنة التقريرية وعند دراسة مساقدراسات في + +39 +00:03:58,580 --> 00:04:04,540 +الفقه أو الفقه المنهج على مذهب الإمام الشافعي + +40 +00:04:04,540 --> 00:04:10,460 +سنتعرض إلى أمثلة أخرى فالنبي عليه الصلاة والسلام + +41 +00:04:10,460 --> 00:04:19,300 +قد أقر الرجل الذي قضى صلاة الصنة القبلية بعد الفجر + +42 +00:04:19,300 --> 00:04:27,310 +على الرغم أن الصلاةبعد الفجر أي بعد صلاة الفجر + +43 +00:04:27,310 --> 00:04:35,630 +مكروهة كراهة تحريمية ولكن هذا الرجل صلى ركعتين بعد + +44 +00:04:35,630 --> 00:04:41,230 +أن صلى الفجر فلمّا سأله النبي عن هتين الركعتين صلى + +45 +00:04:41,230 --> 00:04:46,690 +الله عليه وسلم قال إن هما ركعتا الفجر القبلية يا + +46 +00:04:46,690 --> 00:04:53,680 +رسول اللهفأقره الرسول على ذلك وهذه مسألة سنتعرض + +47 +00:04:53,680 --> 00:05:00,700 +لها في أبواب الفقه عند الحديث عن الأوقات التي تكره + +48 +00:05:00,700 --> 00:05:05,500 +فيها الصلاة لأن الأوقات التي تكره فيها الصلاة خمسة + +49 +00:05:05,500 --> 00:05:11,500 +بعد الفجر وبعد العصر وعند طلوع الشمس وعند غروبها + +50 +00:05:11,500 --> 00:05:17,340 +وقبيل الظهروهو وقت الاستواء عندما تكون الشمس + +51 +00:05:17,340 --> 00:05:25,240 +عمودية على خط الاستواء ولكن الكراهة هنا ليست مطلقة + +52 +00:05:25,240 --> 00:05:32,890 +لكل صلاةإنما الكراهة هنا فقط لصلاة النفل المطلق + +53 +00:05:32,890 --> 00:05:41,050 +أما إذا كانت الصلاة لها سبب مثل القضاء فتصلى في أي + +54 +00:05:41,050 --> 00:05:46,630 +وقت حتى في أوقات الكراهة فلو استيقظ شخص مع طلوع + +55 +00:05:46,630 --> 00:05:54,470 +الشمس أو مع غروب الشمس فإنه يصلى لحديث من نسي صلاة + +56 +00:05:54,470 --> 00:06:02,320 +أو نام عنهافليصليها متى ذكرها، لا كفارة إلا ذلك + +57 +00:06:02,320 --> 00:06:10,380 +وكذلك صلاة الجنازة وصلاة الكسوف والخصوف وكذلك صنة + +58 +00:06:10,380 --> 00:06:17,080 +الوضوء وتحية المسجد إذا دخل أحدكم المسجد فلا يقعد + +59 +00:06:17,080 --> 00:06:22,840 +حتى يصلي ركعتين لأن تحية المسجد من الصناة المؤكدة + +60 +00:06:22,840 --> 00:06:30,730 +وهي صلاة لها سببو كذلك سيأتي معنى في باب التيمم في + +61 +00:06:30,730 --> 00:06:38,190 +مساق الفقه الإسلامي أن من صلى بالتيمم ثم بعد ذلك + +62 +00:06:38,190 --> 00:06:44,590 +وجد الماء لا يعيد صلاته فالصحابة قد فعلوا ذلك + +63 +00:06:44,590 --> 00:06:50,550 +والنبي عليه الصلاة والسلام قد أقرهم على ذلك فهذه + +64 +00:06:50,550 --> 00:06:58,330 +أمثلة قليلة للصنة التقريريةونأتي إلى التفصيل في + +65 +00:06:58,330 --> 00:07:03,830 +أبوابها ان شاء الله تبارك وتعالى بعد تعريف السنة + +66 +00:07:03,830 --> 00:07:09,970 +النبوية وكما قلنا قبل قليل هي ما ورد أو ما نقل عن + +67 +00:07:09,970 --> 00:07:15,370 +النبي عليه الصلاة والسلام من قول أو فعل أو تقرير + +68 +00:07:15,370 --> 00:07:22,130 +فالسنة إما قولية وإما فعلية وإما تقريرية أقر النبي + +69 +00:07:22,130 --> 00:07:29,340 +الصحابة عليها نأتي إلى عنوانعلاقة أحكام الصنة + +70 +00:07:29,340 --> 00:07:38,900 +بالقرآن الكريم والعلاقة هنا تكون على ثلاثة أضربأو + +71 +00:07:38,900 --> 00:07:45,940 +على ثلاثة أوجه الوجه الأول سهل وميصور وهو أن الصنة + +72 +00:07:45,940 --> 00:07:52,120 +النبوية تأتي مؤكدة لكل ما جاء في القرآن الكريم أو + +73 +00:07:52,120 --> 00:07:58,180 +كما قال هنا في الكتاب تأتي موافقة لكل ما جاء في + +74 +00:07:58,180 --> 00:08:05,190 +القرآن الكريم نعم فهناك في القرآنآياته الصلاة + +75 +00:08:05,190 --> 00:08:11,670 +والصوم والحج والزكاة والجهاد في سبيل الله وبر + +76 +00:08:11,670 --> 00:08:16,610 +الوالدين والإحسان إلى الجار إلى غير ذلك من الأحكام + +77 +00:08:16,610 --> 00:08:23,870 +الشرعية وكل هذه الأحكام في الصنة النبوية فما من + +78 +00:08:23,870 --> 00:08:33,710 +آية إلا وقد وافقها وأكدهاحديث نبوي شريف ولا يتفع + +79 +00:08:33,710 --> 00:08:41,490 +المقام لضرب الأمثلة نأتي إلى الأهم من هذه الأضرب + +80 +00:08:41,490 --> 00:08:48,050 +أو تلك الأوجه الثلاثة وهو أن الصنة النبوية إنما + +81 +00:08:48,050 --> 00:08:57,910 +تأتي بيانا لما أريد بالقرآن الكريم نعم وهذاأشبه ما + +82 +00:08:57,910 --> 00:09:04,710 +يكون بالقوانين الوضعية فالقوانين الوضعية لها + +83 +00:09:04,710 --> 00:09:11,800 +مذكراتلكل قانون وضعي مذاكرة تسمى بالمذاكرة + +84 +00:09:11,800 --> 00:09:18,000 +الإيضاحية أو المذاكرة التفسيرية وكذلك أقول هنا + +85 +00:09:18,000 --> 00:09:23,360 +ولله المثل الأعلى مع فارق التشبيه أن الصنة النبوية + +86 +00:09:23,360 --> 00:09:28,680 +إنما هي المذاكرة الإيضاحية أو المذاكرة التفسيرية + +87 +00:09:28,680 --> 00:09:36,560 +لكتاب الله تبارك وتعالى وذلك يكون على صور ثلاثةأما + +88 +00:09:36,560 --> 00:09:43,280 +الصورة الأولى فهي تفصيل المجمل وأما الصورة الثانية + +89 +00:09:43,280 --> 00:09:52,260 +فهي تخصيص العام وأما الصورة الثالثة فهي تقييد + +90 +00:09:52,260 --> 00:10:00,980 +المطلق هذا هو الموجز وإليكم التفصيل أما تفصيل + +91 +00:10:00,980 --> 00:10:10,730 +المجمليفقد سبق أن ذكرت في مثال الصنة الفعلية قوله + +92 +00:10:10,730 --> 00:10:16,530 +عليه الصلاة والسلام صلوا كما رأيتموني أصلي وكذلك + +93 +00:10:16,530 --> 00:10:22,070 +حديث خذوا عني مناسككم لأن الله قال أقيموا الصلاة و + +94 +00:10:22,070 --> 00:10:27,010 +آتوا الذكاء و لأن الله قال و لله على الناس حجوا + +95 +00:10:27,010 --> 00:10:32,310 +البيتولأن الله قال يا أيها الذين أمنوا كُتب عليكم + +96 +00:10:32,310 --> 00:10:40,530 +الصيام نعم فهذه أركانه الإسلامي جاءت مجملة ولكن + +97 +00:10:40,530 --> 00:10:47,430 +الصنة النبوية هي التي فسّرت ووضحت وفسّلت الأركان + +98 +00:10:47,430 --> 00:10:56,690 +والصنن والمكرهات والمبطلات من أجل ذلك كان من مهمة + +99 +00:10:57,530 --> 00:11:04,430 +الصنة النبوية أنها تفصل المجملة في كتاب الله تبارك + +100 +00:11:04,430 --> 00:11:10,110 +وتعالى أما تخصيص العام فمثل قوله صلى الله عليه + +101 +00:11:10,110 --> 00:11:18,200 +وسلم لا يرث القاتل شيئاخصّفت قوله تبارك وتعالى + +102 +00:11:18,200 --> 00:11:26,940 +يوصيكم الله في أولادكم للذاكر مثل حظ الأنسيين فإن + +103 +00:11:26,940 --> 00:11:33,300 +قوله تبارك وتعالى للذاكر مثل حظ الأنسيين يثبت + +104 +00:11:33,300 --> 00:11:43,060 +الميراث لكل ولد سواء كان قاتلاأم غير قاتل فجاءت + +105 +00:11:43,060 --> 00:11:51,120 +الصنة النبوية وحرمت قاتل أبيه من الميراثفقاتل أبيه + +106 +00:11:51,120 --> 00:11:59,040 +لا يرث بدليل هذا النص النبوي الشريف لا يرث القاتل + +107 +00:11:59,040 --> 00:12:05,900 +شيئا لأنه كما قيل في القواعد الشرعية من استعجل + +108 +00:12:05,900 --> 00:12:15,160 +الشيء قبل أوانه يعاقب بحرمانه كما من يقطف الثمرة + +109 +00:12:15,160 --> 00:12:26,390 +قبل نضوجهافمن قطف فاكهة قبل نضوجها فإنه يحرم من + +110 +00:12:26,390 --> 00:12:34,670 +أكلها يحرم منها وهكذا هنا من قتل أباه من أجل أن + +111 +00:12:34,670 --> 00:12:44,110 +يتعجل بميراثه فإنه يعاقببصوق نيته فيحرم من الميراث + +112 +00:12:44,110 --> 00:12:49,250 +وصدق رسول الله صلى الله عليه وسلم لا يرث القاتل + +113 +00:12:49,250 --> 00:12:56,830 +شيئًا أما الصورة الثالثة فهي تقييد المطلق ويستدل + +114 +00:12:56,830 --> 00:13:03,830 +على ذلك بقوله صلى الله عليه وسلم الثلث والثلث كثير + +115 +00:13:04,600 --> 00:13:11,180 +وهذا الحديث يقيد قوله تبارك وتعالى من بعد وصية + +116 +00:13:11,180 --> 00:13:19,720 +يوصي بها أو دين فإن هذه الآية جاءت مطلقة حتى + +117 +00:13:19,720 --> 00:13:26,600 +ظاهرها يدل على أنه لو أوص الشخص بكل ماله فإنها + +118 +00:13:26,600 --> 00:13:34,420 +تنفذ بعد وفاته فجاءت الصنة النبوية الشريفةوقيدت + +119 +00:13:34,420 --> 00:13:42,860 +إطلاق الآية بالثلث فإذا قال أوصيت بكل مالي للفقراء + +120 +00:13:42,860 --> 00:13:47,700 +والمساكين أو للأيتام والأرامل أو لبناء المساجد + +121 +00:13:47,700 --> 00:13:54,340 +والأعمال الخيرية فإنه لا ينفذ منها سواء الثلث + +122 +00:13:54,340 --> 00:14:02,650 +ويعود الباقي إلى الورسته وهذا الحديثالصحيح طبعا له + +123 +00:14:02,650 --> 00:14:09,350 +قصة وصاحب القصة هو سعد بن أبي وقاس خال رسول الله + +124 +00:14:09,350 --> 00:14:16,990 +صلى الله عليه وسلم ورضي الله عن سعد مرض يوما مرضا + +125 +00:14:16,990 --> 00:14:23,690 +شديدا ولم يكن له إلا ابنة واحدة فقال يا رسول الله + +126 +00:14:23,690 --> 00:14:32,010 +لعلي أموت ظن أنه يحتضر بسبب شدة المرضوليس لي إلا + +127 +00:14:32,010 --> 00:14:39,050 +ابنة واحدة أوصي بكل مالي فقال النبي لا فقال أوصي + +128 +00:14:39,050 --> 00:14:44,530 +بنصفه قال لا قال أوصي بالثلث فقال صلى الله عليه + +129 +00:14:44,530 --> 00:14:53,230 +وسلم الثلث والثلث كثير إنك انتظر ورثتك أغنياء خير + +130 +00:14:53,230 --> 00:14:59,970 +من أن تظرهم عالة يتكففوف الناس يعني يسألون الناس + +131 +00:15:01,070 --> 00:15:09,750 +يشحزون ويتسولون لأن السؤال انما يكون بمد الكف خير + +132 +00:15:09,750 --> 00:15:16,490 +من أن تظرهم عالة يعني فقراء يتكففون الناس يسألون + +133 +00:15:16,490 --> 00:15:24,780 +الناس يعني مدينة أقفهم يطلبونالصدقة وهذه دعوة إلى + +134 +00:15:24,780 --> 00:15:29,880 +أولياء الأمور بل إن النبي عليه الصلاة والسلام أوصى + +135 +00:15:29,880 --> 00:15:37,630 +بأقل من الثلثبدليل هذا النص الشريف الثلث والثلث + +136 +00:15:37,630 --> 00:15:43,470 +كثير استنبط أهل العلم من هذه الصناة النبوية أن + +137 +00:15:43,470 --> 00:15:49,510 +الوصية بأقل من الثلث كأن يوصي بالربع أو يوصي + +138 +00:15:49,510 --> 00:15:57,310 +بالخمس خير من أن يوصي بالثلث لأن الأقربين أولى + +139 +00:15:57,310 --> 00:16:04,080 +بالمعروف نعم إذا هذه نقف عندها قليلاونطلب منكم + +140 +00:16:04,080 --> 00:16:11,240 +أيها الطلاب لأنها موضع أسئلة أن تقفوا عندها و أن + +141 +00:16:11,240 --> 00:16:17,520 +تفرقوا بينها لأن الصورة الأولى سهلة وميصورة ولا + +142 +00:16:17,520 --> 00:16:24,280 +تخفى على أحد ألا وهي تفصيل المجمل تفصيل الصلاة + +143 +00:16:24,280 --> 00:16:34,080 +تفصيل الذكاء الحج والصوم و هكذا لكنالملاحظة في + +144 +00:16:34,080 --> 00:16:43,120 +إجابات الطلاب أنهم يخلطون بين تخصيص العام وبين + +145 +00:16:43,120 --> 00:16:49,340 +تقييد المطلق فانتبهوا + +146 +00:16:49,340 --> 00:17:00,520 +إلى ذلك جيدا فتخصيص العام مثله لا يرث القاتل شيئا + +147 +00:17:01,260 --> 00:17:10,740 +وتقييد المطلق مثاله السلس والسلس كثير نعم أما + +148 +00:17:10,740 --> 00:17:19,000 +الوجه الثالث من علاقة أحكام الصنة بأحكام القرآن + +149 +00:17:19,000 --> 00:17:27,890 +الكريم فهي أن تكون الصنة منشئةلأحكام سكت عنها + +150 +00:17:27,890 --> 00:17:34,370 +القرآن الكريم إذا علاقة أحكام الصنة بأحكام القرآن + +151 +00:17:34,370 --> 00:17:41,430 +ثلاثة الوجه الأول أن تكون موافقة أو مؤكدة لكل ما + +152 +00:17:41,430 --> 00:17:47,710 +جاء في القرآن الكريم من كل وجه ثانيا أن تأتي الصنة + +153 +00:17:47,710 --> 00:17:56,310 +النبوية بياناوتفسيرا أو مذكرة توضيحية بلغة رجال + +154 +00:17:56,310 --> 00:18:03,150 +القانون لكل ما جاء في القرآن الكريم وهو على صور + +155 +00:18:03,150 --> 00:18:09,270 +ثلاثة كما قلنا الصورة الأولى تفصيل المجمل الصورة + +156 +00:18:09,270 --> 00:18:15,620 +الثانية تخصيص العامالصورة الثالثة تقييد المطلق أما + +157 +00:18:15,620 --> 00:18:20,900 +ثالثا من أوجه علاقة الصنة بالقرآن الكريم أن تكون + +158 +00:18:20,900 --> 00:18:27,740 +الصنة أو أن تأتي الصنة منشئة لأحكام قد سكت عنها + +159 +00:18:27,740 --> 00:18:33,060 +القرآن الكريم وقد ضرب لناالكتاب المقرر والزملاء + +160 +00:18:33,060 --> 00:18:37,640 +مصنفوه الكتاب مثالا واحدا وهو قوله عليه الصلاة + +161 +00:18:37,640 --> 00:18:47,840 +والسلام يحرم بالرضاع ما يحرم بالنسب وهكذا لأن الله + +162 +00:18:47,840 --> 00:18:54,140 +تكلم عن القرآن الكريم مثل حرمة الأم ومثل حرمة + +163 +00:18:54,140 --> 00:18:58,240 +الأخت وهكذا لكن + +164 +00:19:00,040 --> 00:19:07,060 +كل ما يحرم بالرضاع يحرم بالنسب وكل ما يحرم بالنسب + +165 +00:19:07,060 --> 00:19:14,700 +يحرم بالرضاع فأمك في الرضاع محرمة عليك و أختك في + +166 +00:19:14,700 --> 00:19:19,620 +الرضاع محرمة عليك كما قال الله تعالى وأمهاتكم + +167 +00:19:19,620 --> 00:19:26,380 +اللتي أرضعنكم وأخواتكم من الرضاعةهذا ما نُص عليه + +168 +00:19:26,380 --> 00:19:32,120 +في القرآن الكريم لكن عمتك في الرضاعة أيضًا محرمة + +169 +00:19:32,120 --> 00:19:40,160 +كعمتك في النسب وخالتك في الرضاعة محرمة كخالتك في + +170 +00:19:40,160 --> 00:19:49,000 +النسب وجدتك في الرضاعة محرمة مثل جدتك في النسب فلو + +171 +00:19:49,000 --> 00:19:57,970 +مثلًا أن أحمدرضعة من فاطمة فإن فاطمة تصبح أما + +172 +00:19:57,970 --> 00:20:07,070 +لأحمد في الرضاعة ومن ثم يصبح سوجها أبا لأحمد في + +173 +00:20:07,070 --> 00:20:14,370 +الرضاعة ويترتب على ذلك أحكام أن كل بنات فاطمة تحرم + +174 +00:20:14,370 --> 00:20:20,830 +على أحمد لأن هما أخواته في الرضاعة وليس كما يقول + +175 +00:20:20,830 --> 00:20:27,570 +العواممن الناس أن التي تحرم عليه فقط هي التي رضعت + +176 +00:20:27,570 --> 00:20:38,870 +معاه هذا كلام خاطئ فكل بنات فاطمة سواء كنا قبل + +177 +00:20:38,870 --> 00:20:44,530 +التي رضع معاها أو بعد التي رضع معاها محرمات على + +178 +00:20:44,530 --> 00:20:51,270 +أحمده نعم وكذلك تعتبر + +179 +00:20:52,170 --> 00:21:05,210 +أخته زوج فاطمة عامة له نعم هكذا وأمه جدة له فكل ما + +180 +00:21:05,210 --> 00:21:12,730 +يحرم بالرضاعي يحرم بالنسبيه هذا مثال في الكتاب + +181 +00:21:12,730 --> 00:21:17,870 +ويمكن أن نظر بأمثلة أخرى جاءت بها الصنة النبوية + +182 +00:21:17,870 --> 00:21:26,350 +ولم تأتي في القرآن الكريم مثل تحريمالحلي الذهب و + +183 +00:21:26,350 --> 00:21:33,150 +كذلك الحرير على الرجال دون النساء فتحريم الذهب و + +184 +00:21:33,150 --> 00:21:38,310 +الحرير على الرجال دون النساء هذا ما جاءت به السنة + +185 +00:21:38,310 --> 00:21:46,470 +النبوية الشريفة و كذلك تحريم الحمر الأهلية الحمر + +186 +00:21:46,470 --> 00:21:53,510 +الإنسية و الحمر جمع حماروالحمار يجمع جمعة تكسير + +187 +00:21:53,510 --> 00:21:59,630 +على حمير وعلى حمر الحميرة والبغالة كأنهم حمر + +188 +00:21:59,630 --> 00:22:07,530 +مستنفرة فرت من قصورة وهذا بخلاف الحمار الوحشي الذي + +189 +00:22:07,530 --> 00:22:13,590 +يكون في الغاب فهو حلال مثل الخيل ومثل البقر الوحشي + +190 +00:22:13,590 --> 00:22:18,510 +ومثل الغزال والأنب أما الحديث هنا عن الحمار الأهلي + +191 +00:22:19,100 --> 00:22:24,440 +أو الحمار الإنسي الذي يعيش بيننا ويستعمل الركوب + +192 +00:22:24,440 --> 00:22:29,540 +والحراسة ونحو ذلك فقد قال عليه الصلاة والسلام + +193 +00:22:29,540 --> 00:22:32,940 +أنهاكم + +194 +00:22:32,940 --> 00:22:41,540 +عن أكل لحوم الحمر الأهليةنعم فهذا نص من الرسول + +195 +00:22:41,540 --> 00:22:46,700 +الذي لا ينطق عن الهوى صلى الله عليه وسلم في تحريم + +196 +00:22:46,700 --> 00:22:53,740 +أكل لحوم الحمر الأهلية وكان ذلك في غزوة خيبر في + +197 +00:22:53,740 --> 00:23:00,540 +العام السادس من الهجرة النبوية كذلك يحرم الجمع بين + +198 +00:23:00,540 --> 00:23:06,010 +البنت وعمتهاوبين البنت وخالتها أيضًا هذا حكم لم + +199 +00:23:06,010 --> 00:23:10,530 +يرد في القرآن الكريم وإنما جاءت به الصنة النبوية + +200 +00:23:10,530 --> 00:23:19,370 +والعلّة في ذلك أنكم إن فعلتم ذلك فقد قطعتم أرحمكم + +201 +00:23:19,370 --> 00:23:27,150 +نعم إذا جمعت الأخت والأم وقد حرمت في القرآن الكريم + +202 +00:23:27,150 --> 00:23:34,490 +وكذلك العامة والخالة في بيت واحدفإنها تقطع الأرحم + +203 +00:23:34,490 --> 00:23:41,370 +فالجمع بين البنت و عمتها وبين البنت و خالتها يحرمه + +204 +00:23:41,370 --> 00:23:49,290 +لكن إذا ماتت البنت أو طلقت البنت له أن يتزوج + +205 +00:23:49,290 --> 00:23:56,310 +بخالتها أو أن يتزوج بعمتها كما قلنا في الأختين و + +206 +00:23:56,310 --> 00:24:01,020 +أن تجمعوا بين الأختين هذا في القرآن الكريملكن إذا + +207 +00:24:01,020 --> 00:24:06,960 +ماتت الأخت أو طلقت الأخت له أن يتسوج بأختها لأن + +208 +00:24:06,960 --> 00:24:13,520 +التحريم ليس تحريما مطلقا مؤبدا وإنما هو تحريم مؤكد + +209 +00:24:13,520 --> 00:24:22,320 +وكذلك نكاح المتعة الذي أحلته الشيعة وهذا نكاح + +210 +00:24:22,320 --> 00:24:31,020 +المتعة عندنا نحن أهل الصنة حرام شرعالأنه نكاح مؤقت + +211 +00:24:31,020 --> 00:24:42,720 +وعقد الزواج عقد مؤبد أما نكاح المتعة فهو نكاح مؤقت + +212 +00:24:42,720 --> 00:24:48,460 +حرام شرعا حرمه النبي عليه الصلاة والسلام وعلى ذلك + +213 +00:24:48,460 --> 00:24:56,590 +جماهير الفقهاء من أهل الصنةخلافا للشيعة وكان ذلك + +214 +00:24:56,590 --> 00:25:02,770 +في غزوة خيبر في العام السادس من الهجرة النبوية + +215 +00:25:02,770 --> 00:25:06,790 +هكذا أعزائي الطلاب نكون وقد انتهينا من المصدر + +216 +00:25:06,790 --> 00:25:15,110 +الثاني من مصادر النظم الإسلامية وهي الصنة النبوية + +217 +00:25:15,110 --> 00:25:21,980 +بعدالقرآن الكريم أما ثالثا الإجماع الإجماع أيضا + +218 +00:25:21,980 --> 00:25:29,820 +يعتبر من المصادر الأربعة المتفق عليها ما هو مصطلح + +219 +00:25:29,820 --> 00:25:36,500 +الإجماع اتفاق المجتهدين من المسلمين أو من أمة محمد + +220 +00:25:36,500 --> 00:25:45,000 +صلى الله عليه وسلم في أي عصر من العصور بعد وفاة + +221 +00:25:45,000 --> 00:25:52,220 +الرسولبعد وفاة الرسول صلى الله عليه وسلم على حكم + +222 +00:25:52,220 --> 00:26:02,000 +شرعي في قضية لم يرد بحكمها نص من كتاب أو صنة إذا + +223 +00:26:02,000 --> 00:26:09,780 +نحن هنا على موعد مع تعريفات ثلاثة وليس مع تعريف + +224 +00:26:09,780 --> 00:26:17,880 +واحد فقط فالتعريف الأول هو التعريف العامإذا ما جاء + +225 +00:26:17,880 --> 00:26:25,220 +في الامتحان و ستكون المصطلحات من ضمن الامتحانات + +226 +00:26:25,220 --> 00:26:33,220 +والسؤال على شكل توصيل إذا كان الامتحان إلكترونيا + +227 +00:26:33,220 --> 00:26:39,880 +أما إذا كان ورقيا فصيغته السؤال اذكر المصطلح الذي + +228 +00:26:39,880 --> 00:26:46,540 +يناسب الإبارات التالية ولعله بسببجائحة كورونا عفنا + +229 +00:26:46,540 --> 00:26:51,380 +الله وإياكم ونسأل الله السلامة لنا ولكم ولجميع + +230 +00:26:51,380 --> 00:26:56,280 +المسلمين أن يكون الامتحان ألكترونيا يقتصر على + +231 +00:26:56,280 --> 00:27:04,520 +أسئلة ثلاثة السؤال الأول صح أو خطأ والسؤال الثاني + +232 +00:27:04,520 --> 00:27:11,160 +اختيار متعدد والسؤال الثالث مصطلح توصيل لماذا وقفت + +233 +00:27:11,160 --> 00:27:18,440 +هنا قليلالأن الطلب عندما يجيبون على مصطلح الإجماع + +234 +00:27:18,440 --> 00:27:25,460 +لا يفرقون بين المصطلح العام الذي سبق أن ذكرته وهو + +235 +00:27:25,460 --> 00:27:32,000 +اتفاق المجتهدين من أمة محمد عليه الصلاة والسلام في + +236 +00:27:32,000 --> 00:27:40,370 +أي عصر من العصور بعد وفاة الرسولعلى حادثة أو واقعة + +237 +00:27:40,370 --> 00:27:49,210 +لم يرد فيها نص من كتاب او صناة اقف قليلا بعد هذه + +238 +00:27:49,210 --> 00:27:57,510 +المقدمة بعد وفاة الرسول لأنه سبق ان قلت في حديث + +239 +00:27:57,510 --> 00:28:02,750 +محاذ بن جبل ان النبي عليه الصلاة والسلام ذكر له + +240 +00:28:02,750 --> 00:28:09,310 +محاذالمصادر الثلاثة الكتاب والصنة والاجتهاد أو + +241 +00:28:09,310 --> 00:28:16,630 +القياس وقلت لماذا لم يذكر الإجماع لأنه لا إجماع في + +242 +00:28:16,630 --> 00:28:22,270 +حياة الرسول وما اتفق عليه الصحابة في حياة الرسول + +243 +00:28:22,270 --> 00:28:30,580 +لا يسمى إجماعاوإنما يسمى سنة تقريرية وقد ذكرت + +244 +00:28:30,580 --> 00:28:38,100 +أمثلة على ذلك قبل قليل لذلك نضع خط باللون الأحمر + +245 +00:28:38,100 --> 00:28:44,240 +تحت قوله بعد وفاة الرسول فإذا ما جاءكم سؤال مثلا + +246 +00:28:44,240 --> 00:28:50,970 +يعتبر الإجماع أحد مصادرالنظم الإسلامية في العهد + +247 +00:28:50,970 --> 00:28:57,290 +النبوي الإجابة خطأ وليست صحيحة لأن الإجماع كما + +248 +00:28:57,290 --> 00:29:02,230 +رأيتم في التعريف بعد وفاة الرسول عليه الصلاة + +249 +00:29:02,230 --> 00:29:09,870 +والسلام ثم قال هنا في قضية أو في مسألة أو حادثةأو + +250 +00:29:09,870 --> 00:29:15,070 +واقعة لم يرد فيها نص من كتاب أو صنة لأن الإجماعة + +251 +00:29:15,070 --> 00:29:21,350 +يعتبر المصدر الثالثة بعد الكتاب والصنة من مصادر + +252 +00:29:21,350 --> 00:29:25,290 +النظم الإسلامية فلو كان في المسئلة فتوة + +253 +00:29:27,740 --> 00:29:32,860 +آية أو حديث لمّا لجأنا إلى الإجماع لأننا عندما + +254 +00:29:32,860 --> 00:29:38,460 +نسأل سؤالا أو نستفت في فتوة نبحث عنها في كتاب الله + +255 +00:29:38,460 --> 00:29:43,780 +فإن لم نجد فبصنّط رسول الله كما في حديث معاذ سابق + +256 +00:29:43,780 --> 00:29:50,480 +الذكرفإن لم نجد فالإجماع وإلا فالاجهاد والقياس كما + +257 +00:29:50,480 --> 00:29:58,020 +قال معاذ أجتهد رأي ولا آله أي لا أقصر أو أجتهد في + +258 +00:29:58,020 --> 00:30:03,320 +استنباط الأحكام الشرعية من أدلتها التفصيلية من + +259 +00:30:03,320 --> 00:30:12,100 +خلال هذا التعريف يمكن أن نستنبط أركان الإجماع وهي + +260 +00:30:12,100 --> 00:30:19,920 +ثلاثةأولا وجود عدد من المجتهدين عند وقوع الحادثة + +261 +00:30:19,920 --> 00:30:26,320 +اذ لا عبرة بوجود غيرهم لأن فاقد الشيء لا يعطيه + +262 +00:30:26,320 --> 00:30:33,860 +ونحن لا يتسع المقام لذكر أوصاف المجتهدين لأن + +263 +00:30:33,860 --> 00:30:41,040 +الاجتهاد باب طويليدرّس في أصول الفقه لأولادنا في + +264 +00:30:41,040 --> 00:30:45,920 +كلية الشريعة والقانون من أهل التخصص في كتاب + +265 +00:30:45,920 --> 00:30:49,180 +الإحكام + +266 +00:30:49,180 --> 00:30:55,960 +للأمدي نعم و هناك التفسير ولكن أقل ما يقال عن + +267 +00:30:55,960 --> 00:31:02,600 +المجتهدين أنهم يحفظون كتاب الله ولا يحفظونه غيبا + +268 +00:31:02,600 --> 00:31:04,020 +فقط + +269 +00:31:05,950 --> 00:31:12,810 +وإنما يحفظونه مع معرفة الأحكام الشرعية ولذلك هناك + +270 +00:31:12,810 --> 00:31:20,410 +تفاسير اختصت بأحكام القرآن مثل الجامع لأحكام + +271 +00:31:20,410 --> 00:31:25,010 +القرآن للقرطبي ومثل أحكام القرآن لابن العرب + +272 +00:31:25,010 --> 00:31:31,530 +المالكي وكلاهما مالكي القرطبي وابن العرب كلاهما + +273 +00:31:31,530 --> 00:31:39,260 +مالكيوكذلك أحكام القرآن للجصاص وهو حنفي وأحكام + +274 +00:31:39,260 --> 00:31:45,740 +القرآن للكيا الغراسي وهو شافعي وزاد المسير في علم + +275 +00:31:45,740 --> 00:31:52,700 +التفسير لابن الجوزي وهو حنبلي وهنا نفرق بين ابن + +276 +00:31:52,700 --> 00:32:00,110 +الجوزي وابن قيم الجوزيةفابن قيم الجوزية التلميذ + +277 +00:32:00,110 --> 00:32:06,850 +النجيب لشيخ الإسلام ابن تيمية صاحب المؤلفات التي + +278 +00:32:06,850 --> 00:32:16,250 +كثرت وأما ابن الجوزي ابن العراق ومغداد فهو حنبلي + +279 +00:32:16,250 --> 00:32:24,390 +أيضا ولذلك يقال زاد المسير وما أكثر مؤلفاته لابن + +280 +00:32:24,390 --> 00:32:32,360 +الجوزيأما ابن القيم الشامى فيقول ابن القيم هذه + +281 +00:32:32,360 --> 00:32:39,240 +معلومة للدراسات العليا فائدة لا نبخل عليكم بها أو + +282 +00:32:39,240 --> 00:32:44,920 +ابن قيم الجوزية الجوزية كانت مدرسة في بلاد الشام + +283 +00:32:44,920 --> 00:32:50,860 +والقيم بمنزلة المديرالمشرف على هذه المدرسة فيقال + +284 +00:32:50,860 --> 00:32:56,360 +ابن القيم هكذا او ابن قيم الجوزية ويخطئ بعض الطلاب + +285 +00:32:56,360 --> 00:33:01,960 +الماجستير او الدكتوراه عندما يكتبون في الهامش ابن + +286 +00:33:01,960 --> 00:33:08,100 +القيم الجوزيةهذا من الأخطاء وليس مطلوب ولكن أردت + +287 +00:33:08,100 --> 00:33:15,160 +أن لا أبخلى عليكم وكذلك الصنة النبوية وأحكامها + +288 +00:33:15,160 --> 00:33:20,560 +والصنة لها شروح مثل فتح الباري في شرح الصحيح + +289 +00:33:20,560 --> 00:33:28,440 +البخاري وعرضة الأحواذيللمبارك فوري في شرح الترمذي + +290 +00:33:28,440 --> 00:33:34,420 +ومعالم الصنن للخطابي ونيل الأوطار للشوكاني وصوب + +291 +00:33:34,420 --> 00:33:43,880 +السلام للصنعاني الكحلاني وهكذا هي الصنة النبوية + +292 +00:33:43,880 --> 00:33:51,960 +وشرحها وكذلك يشترط في المجتهدو هذا شرط مهم جدا أن + +293 +00:33:51,960 --> 00:33:59,520 +يكون عالما ضليعا باللغة العربيةلأن القرآن الكريم + +294 +00:33:59,520 --> 00:34:04,060 +باللغة العربية و كذلك الصنة النبوية باللغة العربية + +295 +00:34:04,060 --> 00:34:08,760 +فإذا لم يكن فقيها باللغة العربية لا يصلح أن يكون + +296 +00:34:08,760 --> 00:34:15,780 +عالما لا يصلح أن يكون مفسرا أو مجتهدا و هكذا عليه + +297 +00:34:15,780 --> 00:34:22,140 +أن يكون على علم أيضا بإجماع الصحابة و إجتهادات + +298 +00:34:22,140 --> 00:34:29,800 +التابعين هذا هو الرقم الأولمن أركان الإجماع وجود + +299 +00:34:29,800 --> 00:34:35,740 +عدد من المجتهدين لأن الله قال فاسألوا أهل الذكر إن + +300 +00:34:35,740 --> 00:34:42,020 +كنتم لاتعلمون ومن أهل الذكر هم أهل التخصص والجاهل + +301 +00:34:42,020 --> 00:34:50,360 +لا يسأله ولا يستفتى إذ لا عبرةبوجود غير المجتهدين + +302 +00:34:50,360 --> 00:34:56,480 +ثانيا من أركان الإجماع اتفاق المجتهدين على الحكم + +303 +00:34:56,480 --> 00:35:05,700 +وقت حدوث الواقعة بحيث لا يخالف في الحكم أحد منهم + +304 +00:35:05,700 --> 00:35:13,040 +أو يرجع عنه وإلا فلا ينعقد الإجماع اتفاق المجتهدين + +305 +00:35:13,040 --> 00:35:19,460 +على الحكموقت حدوث الواقعة هذا هو الركن الثاني من + +306 +00:35:19,460 --> 00:35:25,440 +أركان الإجماع بحيث لا يخالف في الحكم أحد منهم أو + +307 +00:35:25,440 --> 00:35:36,300 +يرجع عنهم وإلا فلا ينعقدوا الإجماع أما ثالثا أن + +308 +00:35:36,300 --> 00:35:41,920 +يكون الاتفاق بعد وفاة الرسول صلى الله عليه وسلم + +309 +00:35:42,570 --> 00:35:51,810 +ولذلك قلت لكم ضعوا خطة أحمر أو خطوط تحت هذه الكلمة + +310 +00:35:51,810 --> 00:35:54,350 +لأنه من خلال تصحيحي + +311 +00:35:57,510 --> 00:36:05,430 +لآلاف الأسئلة و خاصة في متطلبات الجامعة حيث ندرس + +312 +00:36:05,430 --> 00:36:10,730 +في كل فصل ال آلاف و ليس العشرات أو المئات كما هو + +313 +00:36:10,730 --> 00:36:17,030 +في التخصص وجدت أنهم يخطئونلذا ألفطوا أنظركم إلى + +314 +00:36:17,030 --> 00:36:22,290 +الانتباه بأن الإجماعة إنما يكون بعد وفاة الرسول + +315 +00:36:22,290 --> 00:36:30,350 +صلى الله عليه وسلم نعم في واقعة لا نص في حكمها لا + +316 +00:36:30,350 --> 00:36:36,590 +من القرآن الكريمولا من الصنة النبوية لأنه لو كان + +317 +00:36:36,590 --> 00:36:41,490 +هناك نص من القرآن أو من الصنة لما لجأنا إلى + +318 +00:36:41,490 --> 00:36:47,130 +الإجماع فالقرآن الكريم هو المصدر الأول كما أسميناه + +319 +00:36:47,130 --> 00:36:52,950 +بمصدر المصادر أو كلي الشريعة والصنة النبوية هي + +320 +00:36:52,950 --> 00:36:56,730 +المصدر الثاني كما قال الله تعالى يا أيها الذين + +321 +00:36:56,730 --> 00:37:02,060 +أمنوا أطيعوا الله وأطيعوا الرسولأي في كتابه وفي + +322 +00:37:02,060 --> 00:37:08,940 +سنته وأما ثالثًا فالإجماع يُعتبر المصدر الثالثة + +323 +00:37:08,940 --> 00:37:14,540 +إذا لم نجد في المسألة فتوة من كتاب أو سنة نأتي + +324 +00:37:14,540 --> 00:37:21,520 +الآن إلى أنواع الإجماع والإجماع نوعًا إجماع صريح + +325 +00:37:21,520 --> 00:37:27,180 +وإجماع سقطت لذا قلت لكم في أول المحاضرة لابد من + +326 +00:37:27,180 --> 00:37:34,660 +التفريقبين مصطلح الإجماع بمعناه العام وبين مصطلحي + +327 +00:37:34,660 --> 00:37:41,160 +الصريح والسكوتي لأني رأيت بعض الطلاب يكتبون + +328 +00:37:41,160 --> 00:37:46,620 +الإجماع هذا غير صحيح الإجماع إنما يكون للمصطلح + +329 +00:37:46,620 --> 00:37:52,450 +الأول للإجماع بمعناه العامأما إذا كان الإجماع + +330 +00:37:52,450 --> 00:37:59,610 +صريحا أو كان ثقوتيا فلابد أن يكتب الطالب الإجماع + +331 +00:37:59,610 --> 00:38:07,850 +الصريح أو الإجماع الثقوتى ما هو مصطلح الإجماع + +332 +00:38:07,850 --> 00:38:14,590 +الصريح هو ما اتفق فيه جميع مجتهدي عصر من العصور + +333 +00:38:14,590 --> 00:38:22,390 +أيضا بعد وفاة الرسول صلى الله عليه وسلمعلى حكم + +334 +00:38:22,390 --> 00:38:29,950 +واقعة بإبداء كل واحد منهم رأيه صراحة بفتوى أو قضاء + +335 +00:38:29,950 --> 00:38:37,270 +وهو حجة قاطعة لا يحكم في واقعة بخلافه ومثال ذلك + +336 +00:38:37,270 --> 00:38:44,530 +الإجماع على حد شارب الخمر ثمانين جلدة ماذا نلحظ + +337 +00:38:44,530 --> 00:38:49,950 +هنا نلحظ هنا أن الإجماع الصريح هو اتفاق جميع + +338 +00:38:49,950 --> 00:38:58,730 +المجتهدينولذا أطلب منكم عند النظر في هذا المسجل أو + +339 +00:38:58,730 --> 00:39:05,170 +المصور أو حتى القراءة في الكتاب أن تضعوا خطة أو + +340 +00:39:05,170 --> 00:39:15,090 +خطوط تحت قولنا جميعلأن كلمة جميع هي التي تفرق بين + +341 +00:39:15,090 --> 00:39:19,570 +الإجماع الصريح وبين الإجماع السقوطي كما سيأتي بعد + +342 +00:39:19,570 --> 00:39:25,290 +قليل ان شاء الله فالإجماع الصريح هو اتفاق جميع + +343 +00:39:25,290 --> 00:39:31,470 +المجتهدين من المسلمين من أمة محمد في أي عصر من + +344 +00:39:31,470 --> 00:39:38,090 +العصور بعد وفاة الرسول أيضاعلى واقعة أو حادثة أو + +345 +00:39:38,090 --> 00:39:45,470 +مسألة لم يرد فيها نص من كتاب أو صنعة نعم ما حكم + +346 +00:39:45,470 --> 00:39:55,370 +الإجماع الصحي وجوب العمل به وجوب العمل به إذا + +347 +00:39:55,370 --> 00:40:03,330 +الإجماع الصريح يجب العمل به لأنه حجة قاطعةوما معنى + +348 +00:40:03,330 --> 00:40:08,750 +وجوب العمل به وهو حجة القطعة بمعنى لا يجوز مخالفته + +349 +00:40:08,750 --> 00:40:18,890 +بل يجب الأخذ به وأما ما لم يأخذ به فما حكمه آثم + +350 +00:40:18,890 --> 00:40:28,920 +وعاص لله تبارك وتعالى وضرب لنا مثالاوهو في عهد + +351 +00:40:28,920 --> 00:40:33,360 +عمرو بن الخطاب رضي الله عنه إجماع الصحابة في عهد + +352 +00:40:33,360 --> 00:40:40,500 +عمرو على جلد شارب الخمر ثمانين جلدة فكان إجماعا + +353 +00:40:40,500 --> 00:40:48,980 +صريحا لا غموض فيه ولا خلافة ولا لبسة أما النوع + +354 +00:40:48,980 --> 00:40:56,790 +الثاني من أنواع الإجماع فهو الإجماع السكوتيوهنا + +355 +00:40:56,790 --> 00:41:05,450 +نقول الإجماع السكوتي هو ما يقرره بعض المجتهدين في + +356 +00:41:05,450 --> 00:41:11,510 +عصر من العصور حول حادثة ما ويمتنع الآخرون عن + +357 +00:41:11,510 --> 00:41:17,730 +الموافقة أو المخالفة بدون عذر ومخالفة هذا الإجماع + +358 +00:41:17,730 --> 00:41:26,430 +غير محرمة نظرا لعدم وجوب مانع يمنع الساكتين عنهإذا + +359 +00:41:26,430 --> 00:41:33,890 +كما قلت لكم ضعوا خطة تحت جميع في الإجماع الصريح + +360 +00:41:33,890 --> 00:41:39,830 +ضعوا خطة أو خطوط أخرى تحت بعض هذا هو الذي يفرق + +361 +00:41:39,830 --> 00:41:47,850 +الإجماع الصريح عن الإجماع السكوتي فالإجماع الصريح + +362 +00:41:47,850 --> 00:41:56,380 +هو اتفاق جميع المجتهدين نعموالإجماع السكوتى هو + +363 +00:41:56,380 --> 00:42:04,680 +اتفاق بعض المجتهدين بينما سكوت البعض الآخر دون عذر + +364 +00:42:04,680 --> 00:42:14,540 +يمنعهم من الإدلاء بفتواهم نعم لكن ما حكم الإجماع + +365 +00:42:14,540 --> 00:42:20,140 +الصريح أنه ليس حجة قاطعة + +366 +00:42:22,250 --> 00:42:33,090 +ولذلك المسلم لا يجب عليه الأخذ به بل هو مخير بين + +367 +00:42:33,090 --> 00:42:40,950 +الأخذ وبين التركه ولا يأثم تركه إذا أيضا نعيد + +368 +00:42:40,950 --> 00:42:45,910 +لأهمية هذه النقطة الإجماع الصريح هو اتفاق جميع + +369 +00:42:45,910 --> 00:42:54,950 +المجتهدين وهو حجة قاطعةلا يحكم بخلافه و يأثم تاركه + +370 +00:42:54,950 --> 00:43:05,950 +لاتفاق جميع المجتهدين أما الإجماع السكوتي فهو ليس + +371 +00:43:05,950 --> 00:43:13,850 +حجة قاطعة و المسلم مخير بين الأخذ و الترك و لا + +372 +00:43:13,850 --> 00:43:22,010 +يأثم تاركه طبعا هنا الكتابلم يضرب لنا مثالا لأن + +373 +00:43:22,010 --> 00:43:29,570 +المثال انما هو في كتب المعاملات كما يدرس في التخصص + +374 +00:43:29,570 --> 00:43:35,170 +في متطلب الكلية في كلية الشريعة في الجامعة + +375 +00:43:35,170 --> 00:43:42,630 +الإسلامية يدرس باب البيوعو هنا يستدلون على ذلك + +376 +00:43:42,630 --> 00:43:48,250 +بمثال نأتي به من أجل الفائدة و ليس مطلوبا في + +377 +00:43:48,250 --> 00:43:53,170 +الامتحان لأنه ليس موجودا في الكتاب و الامتحان + +378 +00:43:53,170 --> 00:44:02,130 +المقرر هو فقط في الكتاب و يستثنى ما شطبناه عنكم + +379 +00:44:02,890 --> 00:44:09,370 +لأنكم ستدرسونه في مساقات أخرى كالعقيدة والاقتصاد + +380 +00:44:09,370 --> 00:44:18,110 +الإسلامي قالوا بأن بيع الشيء قبل نقله يعتبر من + +381 +00:44:18,110 --> 00:44:27,170 +الإجماع السكوتى إذا ما اشترى شخص سلعة مثلا كسيارة + +382 +00:44:27,170 --> 00:44:36,130 +في مستودع لا يجوز لهان يبيعها حتى تخرج من المستودع + +383 +00:44:36,130 --> 00:44:41,490 +او مثلا اشتراها في سوق ليس له ان يبيعها في السوق + +384 +00:44:41,490 --> 00:44:48,830 +حتى ينقلها الى مكان اخر والعلّة في ذلك انهم قالوا + +385 +00:44:48,830 --> 00:44:56,110 +انها تشبه الربا لكن انا اقول بخلاف ذلك وافتي بجواز + +386 +00:44:56,110 --> 00:45:04,160 +الاخذ مع ان المكلفة المسلمةشرعا كما قلنا هو مخيّر + +387 +00:45:04,160 --> 00:45:10,520 +بين أن يأخذ بهذا وبين أن لا يأخذ بهذا فالذين ذهبوا + +388 +00:45:10,520 --> 00:45:18,020 +إلى الورق والبعد عن الشبهات قالوا بحرمة هذا البيع + +389 +00:45:18,020 --> 00:45:25,440 +إذا بيعت السلعة بعد شرائها ولم تنقل إلى مكان آخر + +390 +00:45:25,440 --> 00:45:31,310 +لأنها أشبه ما تكون في هذه الحالة بالربالكن البون + +391 +00:45:31,310 --> 00:45:37,770 +شاسع والفرق كبير لأن الربا بيع نقد بنقد أن تبيع + +392 +00:45:37,770 --> 00:45:43,930 +ألف دينار مثلا أو ألف شكل بألف وعشرة هذا هو الربا، + +393 +00:45:43,930 --> 00:45:51,720 +لكن هنا بيع صلة بصلةواليوم في ظل العصر الحديث لا + +394 +00:45:51,720 --> 00:45:59,180 +ينبغي الفتوى بهذا فالفتوى صارت عبر الأنموذج وصارت + +395 +00:45:59,180 --> 00:46:08,220 +عبر الإلكترونيات والأجهزة الحديثة من facts ونحو + +396 +00:46:08,220 --> 00:46:16,080 +ذلك مما لا يخفىإذا بيعت السلعة في محلها بعد شرائها + +397 +00:46:16,080 --> 00:46:26,120 +فليست محرمة ولا يأثم فاعلها لأنه كما قلت إجماع غير + +398 +00:46:26,120 --> 00:46:35,600 +صريح إجماع سكوتي بمعنى اتفق فيه البعض وسكت فيه + +399 +00:46:35,600 --> 00:46:42,170 +البعضولذا أنت أيها المسلم مخير بين أن تأخذ به وبين + +400 +00:46:42,170 --> 00:46:46,270 +أن لا تأخذ به أردت بهذا المثال بعيدا عن الكتاب + +401 +00:46:46,270 --> 00:46:52,930 +نختم الآن ان شاء الله تعالى المبحث الرابع وهو + +402 +00:46:52,930 --> 00:47:00,510 +مصادر النظم الإسلامية بالمصدر الرابع وهوالقياس + +403 +00:47:00,510 --> 00:47:07,630 +والقياس يعتبر من أهم أبواب الفقه الإسلامي حتى سماه + +404 +00:47:07,630 --> 00:47:14,990 +البعض بالاجتهاد لأن الأمور تتغير في كل مكان وفي كل + +405 +00:47:14,990 --> 00:47:20,070 +زمان والنبي عليه الصلاة والسلام ذكر في حديث الربا + +406 +00:47:20,070 --> 00:47:26,400 +ستةفي الحديث الصحيح عند البخاري وغيره عن أبي سعيد + +407 +00:47:26,400 --> 00:47:34,240 +الخدري عندما قال الذهب بالذهب والفضة بالفضة والبر + +408 +00:47:34,240 --> 00:47:38,640 +بالبر يعني القمح بالقمح والشعير بالشعير والملح + +409 +00:47:38,640 --> 00:47:45,170 +بالملح والتمر بالتمر طب فأين الأرز؟و أين العدس؟ و + +410 +00:47:45,170 --> 00:47:53,230 +أين الحمص؟ نعم بالفصحى حمص أما أنتم فقولوا حمص أما + +411 +00:47:53,230 --> 00:48:01,190 +إذا أردتم الفصحى فالحمص بكسر الحق و ليس بالضم و + +412 +00:48:01,190 --> 00:48:05,070 +أين المجروش؟ + +413 +00:48:05,740 --> 00:48:17,880 +وغير ذلك من مثلا الفاكهة المجففة غير التمر كالقطين + +414 +00:48:17,880 --> 00:48:28,620 +مثلا مجفف التين وكذبيب مجفف العنب أين هذه الأشياء؟ + +415 +00:48:28,620 --> 00:48:35,340 +ليست في الحديثولذلك لابد هنا وهذا من أخطر الأبواب + +416 +00:48:35,340 --> 00:48:42,060 +بل من أهمها لابد من البحث عن العلة فنقول لماذا + +417 +00:48:42,060 --> 00:48:47,080 +حرمت هذه الأشياء فالعلة في الذهب والفضة هي + +418 +00:48:47,080 --> 00:48:54,030 +الثمانيةأو النقدية وهذا سيدرّس لكم في الفقه + +419 +00:48:54,030 --> 00:48:59,630 +الإسلامي قسم المعاملات في الفقه المنهجي على مذهب + +420 +00:48:59,630 --> 00:49:04,430 +الإمام الشافعي فالنقدية أو الثمانية هي لا إلا + +421 +00:49:04,430 --> 00:49:11,890 +وعليه يحرم بيع العملات الورقية بالزيادة + +422 +00:49:11,890 --> 00:49:19,590 +أو النقصان لأنها ربن مثل الدينار والدولاروالشيكل + +423 +00:49:19,590 --> 00:49:25,630 +وال يورو ونحو ذلك من المارك الألماني الفرنكي + +424 +00:49:25,630 --> 00:49:30,870 +الفرنسي أو الجنيه المصري أو السترليني أو الليرة + +425 +00:49:30,870 --> 00:49:36,990 +التركية إلى غير ذلك من أنواع العملات فكما يحرم بيع + +426 +00:49:36,990 --> 00:49:41,730 +ألف دينار من الذهب أو الف دينار من الفضة بألف + +427 +00:49:41,730 --> 00:49:50,320 +وعشرة كذلك يحرم بيع ألف دينار من الورقالذى يسمى + +428 +00:49:50,320 --> 00:49:57,040 +الدنار الأردني او الدولار بالألف وعشرة ونحو ذلك + +429 +00:49:57,040 --> 00:50:03,920 +إلى غير ذلك من الأبواب وكذلك هنا تحرم البيرة قياسا + +430 +00:50:03,920 --> 00:50:09,260 +على الخمرة لأن العلة في الخمرة هي الإسكار والبيرة + +431 +00:50:09,260 --> 00:50:16,260 +مسكرة فتحرم فكل مسكر خمر وكل خمر حرام وإن لم يكن + +432 +00:50:16,260 --> 00:50:24,660 +من العنابأما مصطلح القياس فهو إلحاق واقعة لم يرد + +433 +00:50:24,660 --> 00:50:30,680 +نص شرعي على حكمها بواقعة ورد نص شرعي بحكمها + 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بأمثلة أخرى جاءت بها الصنة النبوية ولم تأتي في القرآن الكريم مثل تحريم", "tokens": [10721, 46456, 3224, 30767, 29245, 6156, 41193, 46007, 6225, 10943, 3660, 46740, 8717, 25957, 8032, 4117, 15730, 36725, 2304, 3224, 10874, 3215, 3660, 46740, 6156, 28820, 19446, 7251, 5016, 2288, 2304, 20666, 43042, 45761, 1829, 7251, 5016, 2288, 2304, 20666, 1863, 35457, 1829, 3224, 23758, 50113, 6027, 8978, 33251, 2655, 16758, 4032, 32640, 19452, 14739, 8717, 19913, 2288, 4724, 10721, 2304, 12984, 37977, 5551, 34740, 7578, 10874, 16606, 2655, 4724, 11296, 31767, 1863, 3660, 28239, 3555, 2407, 10632, 4032, 19528, 6055, 10721, 31371, 8978, 25062, 2288, 148, 48506, 33251, 16572, 2304, 50113, 1211, 6055, 5016, 16572, 2304], "avg_logprob": -0.1283482173267676, "compression_ratio": 1.7675675675675675, "no_speech_prob": 1.1920928955078125e-06, "words": [{"start": 1252.17, "end": 1252.99, "word": "أخته", "probability": 0.6822916666666666}, {"start": 1252.99, "end": 1254.39, "word": " زوج", "probability": 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الحرير على الرجال دون النساء فتحريم الذهب و الحرير على الرجال دون النساء هذا ما جاءت به السنة النبوية الشريفة و كذلك تحريم الحمر الأهلية الحمر الإنسية و الحمر جمع حمار", "tokens": [6027, 5016, 20292, 2423, 24192, 3555, 4032, 9122, 8848, 23275, 21542, 2288, 13546, 15844, 34892, 7435, 6027, 11778, 11536, 28239, 3794, 16606, 6156, 2655, 5016, 16572, 2304, 32545, 3224, 3555, 4032, 21542, 2288, 13546, 15844, 34892, 7435, 6027, 11778, 11536, 28239, 3794, 16606, 23758, 19446, 10874, 16606, 2655, 39627, 21136, 1863, 3660, 28239, 3555, 2407, 10632, 25124, 16572, 5172, 3660, 4032, 9122, 8848, 23275, 6055, 5016, 16572, 2304, 21542, 29973, 16247, 3224, 1211, 10632, 21542, 29973, 33688, 1863, 3794, 10632, 4032, 21542, 29973, 10874, 2304, 3615, 11331, 2304, 9640], "avg_logprob": -0.09869791708058781, "compression_ratio": 2.2533333333333334, "no_speech_prob": 1.138448715209961e-05, "words": [{"start": 1282.31, "end": 1283.05, "word": "الحلي", "probability": 0.809326171875}, {"start": 1283.05, "end": 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الله عنه إجماع الصحابة في عهد عمرو على جلد شارب الخمر ثمانين جلدة فكان إجماعا صريحا لا غموض فيه ولا خلافة ولا لبسة أما النوع الثاني من أنواع الإجماع فهو الإجماع السكوتي", "tokens": [2407, 3224, 2407, 8978, 6225, 3224, 3215, 6225, 29973, 2407, 44945, 33962, 9566, 16758, 12602, 11242, 1829, 21984, 18871, 3224, 11933, 7435, 15042, 3615, 31767, 5016, 16758, 3660, 8978, 6225, 3224, 3215, 6225, 29973, 2407, 15844, 10874, 1211, 3215, 13412, 9640, 3555, 33962, 29973, 38637, 2304, 7649, 9957, 10874, 1211, 41891, 6156, 41361, 11933, 7435, 15042, 3615, 995, 20328, 16572, 5016, 995, 20193, 32771, 2304, 2407, 11242, 8978, 3224, 49429, 16490, 15040, 5172, 3660, 49429, 5296, 3555, 3794, 3660, 5551, 15042, 28239, 45367, 6024, 104, 7649, 1829, 9154, 14739, 14407, 3615, 33688, 7435, 15042, 3615, 6156, 3224, 2407, 33688, 7435, 15042, 3615, 21136, 4117, 2407, 31371], "avg_logprob": -0.06757447764138196, "compression_ratio": 1.988888888888889, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 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الصلاة لأن الأوقات التي تكره فيها الصلاة خمسة + +49 +00:05:05,500 --> 00:05:11,500 +بعد الفجر وبعد العصر وعند طلوع الشمس وعند غروبها + +50 +00:05:11,500 --> 00:05:17,340 +وقبيل الظهروهو وقت الاستواء عندما تكون الشمس + +51 +00:05:17,340 --> 00:05:25,240 +عمودية على خط الاستواء ولكن الكراهة هنا ليست مطلقة + +52 +00:05:25,240 --> 00:05:32,890 +لكل صلاةإنما الكراهة هنا فقط لصلاة النفل المطلق + +53 +00:05:32,890 --> 00:05:41,050 +أما إذا كانت الصلاة لها سبب مثل القضاء فتصلى في أي + +54 +00:05:41,050 --> 00:05:46,630 +وقت حتى في أوقات الكراهة فلو استيقظ شخص مع طلوع + +55 +00:05:46,630 --> 00:05:54,470 +الشمس أو مع غروب الشمس فإنه يصلى لحديث من نسي صلاة + +56 +00:05:54,470 --> 00:06:02,320 +أو نام عنهافليصليها متى ذكرها، لا كفارة إلا ذلك + +57 +00:06:02,320 --> 00:06:10,380 +وكذلك صلاة الجنازة وصلاة الكسوف والخصوف وكذلك صنة + +58 +00:06:10,380 --> 00:06:17,080 +الوضوء وتحية المسجد إذا دخل أحدكم المسجد فلا يقعد + +59 +00:06:17,080 --> 00:06:22,840 +حتى يصلي ركعتين لأن تحية المسجد من الصناة المؤكدة + +60 +00:06:22,840 --> 00:06:30,730 +وهي صلاة لها سببو كذلك سيأتي معنى في باب التيمم في + +61 +00:06:30,730 --> 00:06:38,190 +مساق الفقه الإسلامي أن من صلى بالتيمم ثم بعد ذلك + +62 +00:06:38,190 --> 00:06:44,590 +وجد الماء لا يعيد صلاته فالصحابة قد فعلوا ذلك + +63 +00:06:44,590 --> 00:06:50,550 +والنبي عليه الصلاة والسلام قد أقرهم على ذلك فهذه + +64 +00:06:50,550 --> 00:06:58,330 +أمثلة قليلة للصنة التقريريةونأتي إلى التفصيل في + +65 +00:06:58,330 --> 00:07:03,830 +أبوابها ان شاء الله تبارك وتعالى بعد تعريف السنة + +66 +00:07:03,830 --> 00:07:09,970 +النبوية وكما قلنا قبل قليل هي ما ورد أو ما نقل عن + +67 +00:07:09,970 --> 00:07:15,370 +النبي عليه الصلاة والسلام من قول أو فعل أو تقرير + +68 +00:07:15,370 --> 00:07:22,130 +فالسنة إما قولية وإما فعلية وإما تقريرية أقر النبي + +69 +00:07:22,130 --> 00:07:29,340 +الصحابة عليها نأتي إلى عنوانعلاقة أحكام الصنة + +70 +00:07:29,340 --> 00:07:38,900 +بالقرآن الكريم والعلاقة هنا تكون على ثلاثة أضربأو + +71 +00:07:38,900 --> 00:07:45,940 +على ثلاثة أوجه الوجه الأول سهل وميصور وهو أن الصنة + +72 +00:07:45,940 --> 00:07:52,120 +النبوية تأتي مؤكدة لكل ما جاء في القرآن الكريم أو + +73 +00:07:52,120 --> 00:07:58,180 +كما قال هنا في الكتاب تأتي موافقة لكل ما جاء في + +74 +00:07:58,180 --> 00:08:05,190 +القرآن الكريم نعم فهناك في القرآنآياته الصلاة + +75 +00:08:05,190 --> 00:08:11,670 +والصوم والحج والزكاة والجهاد في سبيل الله وبر + +76 +00:08:11,670 --> 00:08:16,610 +الوالدين والإحسان إلى الجار إلى غير ذلك من الأحكام + +77 +00:08:16,610 --> 00:08:23,870 +الشرعية وكل هذه الأحكام في الصنة النبوية فما من + +78 +00:08:23,870 --> 00:08:33,710 +آية إلا وقد وافقها وأكدهاحديث نبوي شريف ولا يتفع + +79 +00:08:33,710 --> 00:08:41,490 +المقام لضرب الأمثلة نأتي إلى الأهم من هذه الأضرب + +80 +00:08:41,490 --> 00:08:48,050 +أو تلك الأوجه الثلاثة وهو أن الصنة النبوية إنما + +81 +00:08:48,050 --> 00:08:57,910 +تأتي بيانا لما أريد بالقرآن الكريم نعم وهذاأشبه ما + +82 +00:08:57,910 --> 00:09:04,710 +يكون بالقوانين الوضعية فالقوانين الوضعية لها + +83 +00:09:04,710 --> 00:09:11,800 +مذكراتلكل قانون وضعي مذاكرة تسمى بالمذاكرة + +84 +00:09:11,800 --> 00:09:18,000 +الإيضاحية أو المذاكرة التفسيرية وكذلك أقول هنا + +85 +00:09:18,000 --> 00:09:23,360 +ولله المثل الأعلى مع فارق التشبيه أن الصنة النبوية + +86 +00:09:23,360 --> 00:09:28,680 +إنما هي المذاكرة الإيضاحية أو المذاكرة التفسيرية + +87 +00:09:28,680 --> 00:09:36,560 +لكتاب الله تبارك وتعالى وذلك يكون على صور ثلاثةأما + +88 +00:09:36,560 --> 00:09:43,280 +الصورة الأولى فهي تفصيل المجمل وأما الصورة الثانية + +89 +00:09:43,280 --> 00:09:52,260 +فهي تخصيص العام وأما الصورة الثالثة فهي تقييد + +90 +00:09:52,260 --> 00:10:00,980 +المطلق هذا هو الموجز وإليكم التفصيل أما تفصيل + +91 +00:10:00,980 --> 00:10:10,730 +المجمليفقد سبق أن ذكرت في مثال الصنة الفعلية قوله + +92 +00:10:10,730 --> 00:10:16,530 +عليه الصلاة والسلام صلوا كما رأيتموني أصلي وكذلك + +93 +00:10:16,530 --> 00:10:22,070 +حديث خذوا عني مناسككم لأن الله قال أقيموا الصلاة و + +94 +00:10:22,070 --> 00:10:27,010 +آتوا الذكاء و لأن الله قال و لله على الناس حجوا + +95 +00:10:27,010 --> 00:10:32,310 +البيتولأن الله قال يا أيها الذين أمنوا كُتب عليكم + +96 +00:10:32,310 --> 00:10:40,530 +الصيام نعم فهذه أركانه الإسلامي جاءت مجملة ولكن + +97 +00:10:40,530 --> 00:10:47,430 +الصنة النبوية هي التي فسّرت ووضحت وفسّلت الأركان + +98 +00:10:47,430 --> 00:10:56,690 +والصنن والمكرهات والمبطلات من أجل ذلك كان من مهمة + +99 +00:10:57,530 --> 00:11:04,430 +الصنة النبوية أنها تفصل المجملة في كتاب الله تبارك + +100 +00:11:04,430 --> 00:11:10,110 +وتعالى أما تخصيص العام فمثل قوله صلى الله عليه + +101 +00:11:10,110 --> 00:11:18,200 +وسلم لا يرث القاتل شيئاخصّفت قوله تبارك وتعالى + +102 +00:11:18,200 --> 00:11:26,940 +يوصيكم الله في أولادكم للذاكر مثل حظ الأنسيين فإن + +103 +00:11:26,940 --> 00:11:33,300 +قوله تبارك وتعالى للذاكر مثل حظ الأنسيين يثبت + +104 +00:11:33,300 --> 00:11:43,060 +الميراث لكل ولد سواء كان قاتلاأم غير قاتل فجاءت + +105 +00:11:43,060 --> 00:11:51,120 +الصنة النبوية وحرمت قاتل أبيه من الميراثفقاتل أبيه + +106 +00:11:51,120 --> 00:11:59,040 +لا يرث بدليل هذا النص النبوي الشريف لا يرث القاتل + +107 +00:11:59,040 --> 00:12:05,900 +شيئا لأنه كما قيل في القواعد الشرعية من استعجل + +108 +00:12:05,900 --> 00:12:15,160 +الشيء قبل أوانه يعاقب بحرمانه كما من يقطف الثمرة + +109 +00:12:15,160 --> 00:12:26,390 +قبل نضوجهافمن قطف فاكهة قبل نضوجها فإنه يحرم من + +110 +00:12:26,390 --> 00:12:34,670 +أكلها يحرم منها وهكذا هنا من قتل أباه من أجل أن + +111 +00:12:34,670 --> 00:12:44,110 +يتعجل بميراثه فإنه يعاقببصوق نيته فيحرم من الميراث + +112 +00:12:44,110 --> 00:12:49,250 +وصدق رسول الله صلى الله عليه وسلم لا يرث القاتل + +113 +00:12:49,250 --> 00:12:56,830 +شيئًا أما الصورة الثالثة فهي تقييد المطلق ويستدل + +114 +00:12:56,830 --> 00:13:03,830 +على ذلك بقوله صلى الله عليه وسلم الثلث والثلث كثير + +115 +00:13:04,600 --> 00:13:11,180 +وهذا الحديث يقيد قوله تبارك وتعالى من بعد وصية + +116 +00:13:11,180 --> 00:13:19,720 +يوصي بها أو دين فإن هذه الآية جاءت مطلقة حتى + +117 +00:13:19,720 --> 00:13:26,600 +ظاهرها يدل على أنه لو أوص الشخص بكل ماله فإنها + +118 +00:13:26,600 --> 00:13:34,420 +تنفذ بعد وفاته فجاءت الصنة النبوية الشريفةوقيدت + +119 +00:13:34,420 --> 00:13:42,860 +إطلاق الآية بالثلث فإذا قال أوصيت بكل مالي للفقراء + +120 +00:13:42,860 --> 00:13:47,700 +والمساكين أو للأيتام والأرامل أو لبناء المساجد + +121 +00:13:47,700 --> 00:13:54,340 +والأعمال الخيرية فإنه لا ينفذ منها سواء الثلث + +122 +00:13:54,340 --> 00:14:02,650 +ويعود الباقي إلى الورسته وهذا الحديثالصحيح طبعا له + +123 +00:14:02,650 --> 00:14:09,350 +قصة وصاحب القصة هو سعد بن أبي وقاس خال رسول الله + +124 +00:14:09,350 --> 00:14:16,990 +صلى الله عليه وسلم ورضي الله عن سعد مرض يوما مرضا + +125 +00:14:16,990 --> 00:14:23,690 +شديدا ولم يكن له إلا ابنة واحدة فقال يا رسول الله + +126 +00:14:23,690 --> 00:14:32,010 +لعلي أموت ظن أنه يحتضر بسبب شدة المرضوليس لي إلا + +127 +00:14:32,010 --> 00:14:39,050 +ابنة واحدة أوصي بكل مالي فقال النبي لا فقال أوصي + +128 +00:14:39,050 --> 00:14:44,530 +بنصفه قال لا قال أوصي بالثلث فقال صلى الله عليه + +129 +00:14:44,530 --> 00:14:53,230 +وسلم الثلث والثلث كثير إنك انتظر ورثتك أغنياء خير + +130 +00:14:53,230 --> 00:14:59,970 +من أن تظرهم عالة يتكففوف الناس يعني يسألون الناس + +131 +00:15:01,070 --> 00:15:09,750 +يشحزون ويتسولون لأن السؤال انما يكون بمد الكف خير + +132 +00:15:09,750 --> 00:15:16,490 +من أن تظرهم عالة يعني فقراء يتكففون الناس يسألون + +133 +00:15:16,490 --> 00:15:24,780 +الناس يعني مدينة أقفهم يطلبونالصدقة وهذه دعوة إلى + +134 +00:15:24,780 --> 00:15:29,880 +أولياء الأمور بل إن النبي عليه الصلاة والسلام أوصى + +135 +00:15:29,880 --> 00:15:37,630 +بأقل من الثلثبدليل هذا النص الشريف الثلث والثلث + +136 +00:15:37,630 --> 00:15:43,470 +كثير استنبط أهل العلم من هذه الصناة النبوية أن + +137 +00:15:43,470 --> 00:15:49,510 +الوصية بأقل من الثلث كأن يوصي بالربع أو يوصي + +138 +00:15:49,510 --> 00:15:57,310 +بالخمس خير من أن يوصي بالثلث لأن الأقربين أولى + +139 +00:15:57,310 --> 00:16:04,080 +بالمعروف نعم إذا هذه نقف عندها قليلاونطلب منكم + +140 +00:16:04,080 --> 00:16:11,240 +أيها الطلاب لأنها موضع أسئلة أن تقفوا عندها و أن + +141 +00:16:11,240 --> 00:16:17,520 +تفرقوا بينها لأن الصورة الأولى سهلة وميصورة ولا + +142 +00:16:17,520 --> 00:16:24,280 +تخفى على أحد ألا وهي تفصيل المجمل تفصيل الصلاة + +143 +00:16:24,280 --> 00:16:34,080 +تفصيل الذكاء الحج والصوم و هكذا لكنالملاحظة في + +144 +00:16:34,080 --> 00:16:43,120 +إجابات الطلاب أنهم يخلطون بين تخصيص العام وبين + +145 +00:16:43,120 --> 00:16:49,340 +تقييد المطلق فانتبهوا + +146 +00:16:49,340 --> 00:17:00,520 +إلى ذلك جيدا فتخصيص العام مثله لا يرث القاتل شيئا + +147 +00:17:01,260 --> 00:17:10,740 +وتقييد المطلق مثاله السلس والسلس كثير نعم أما + +148 +00:17:10,740 --> 00:17:19,000 +الوجه الثالث من علاقة أحكام الصنة بأحكام القرآن + +149 +00:17:19,000 --> 00:17:27,890 +الكريم فهي أن تكون الصنة منشئةلأحكام سكت عنها + +150 +00:17:27,890 --> 00:17:34,370 +القرآن الكريم إذا علاقة أحكام الصنة بأحكام القرآن + +151 +00:17:34,370 --> 00:17:41,430 +ثلاثة الوجه الأول أن تكون موافقة أو مؤكدة لكل ما + +152 +00:17:41,430 --> 00:17:47,710 +جاء في القرآن الكريم من كل وجه ثانيا أن تأتي الصنة + +153 +00:17:47,710 --> 00:17:56,310 +النبوية بياناوتفسيرا أو مذكرة توضيحية بلغة رجال + +154 +00:17:56,310 --> 00:18:03,150 +القانون لكل ما جاء في القرآن الكريم وهو على صور + +155 +00:18:03,150 --> 00:18:09,270 +ثلاثة كما قلنا الصورة الأولى تفصيل المجمل الصورة + +156 +00:18:09,270 --> 00:18:15,620 +الثانية تخصيص العامالصورة الثالثة تقييد المطلق أما + +157 +00:18:15,620 --> 00:18:20,900 +ثالثا من أوجه علاقة الصنة بالقرآن الكريم أن تكون + +158 +00:18:20,900 --> 00:18:27,740 +الصنة أو أن تأتي الصنة منشئة لأحكام قد سكت عنها + +159 +00:18:27,740 --> 00:18:33,060 +القرآن الكريم وقد ضرب لناالكتاب المقرر والزملاء + +160 +00:18:33,060 --> 00:18:37,640 +مصنفوه الكتاب مثالا واحدا وهو قوله عليه الصلاة + +161 +00:18:37,640 --> 00:18:47,840 +والسلام يحرم بالرضاع ما يحرم بالنسب وهكذا لأن الله + +162 +00:18:47,840 --> 00:18:54,140 +تكلم عن القرآن الكريم مثل حرمة الأم ومثل حرمة + +163 +00:18:54,140 --> 00:18:58,240 +الأخت وهكذا لكن + +164 +00:19:00,040 --> 00:19:07,060 +كل ما يحرم بالرضاع يحرم بالنسب وكل ما يحرم بالنسب + +165 +00:19:07,060 --> 00:19:14,700 +يحرم بالرضاع فأمك في الرضاع محرمة عليك و أختك في + +166 +00:19:14,700 --> 00:19:19,620 +الرضاع محرمة عليك كما قال الله تعالى وأمهاتكم + +167 +00:19:19,620 --> 00:19:26,380 +اللتي أرضعنكم وأخواتكم من الرضاعةهذا ما نُص عليه + +168 +00:19:26,380 --> 00:19:32,120 +في القرآن الكريم لكن عمتك في الرضاعة أيضًا محرمة + +169 +00:19:32,120 --> 00:19:40,160 +كعمتك في النسب وخالتك في الرضاعة محرمة كخالتك في + +170 +00:19:40,160 --> 00:19:49,000 +النسب وجدتك في الرضاعة محرمة مثل جدتك في النسب فلو + +171 +00:19:49,000 --> 00:19:57,970 +مثلًا أن أحمدرضعة من فاطمة فإن فاطمة تصبح أما + +172 +00:19:57,970 --> 00:20:07,070 +لأحمد في الرضاعة ومن ثم يصبح سوجها أبا لأحمد في + +173 +00:20:07,070 --> 00:20:14,370 +الرضاعة ويترتب على ذلك أحكام أن كل بنات فاطمة تحرم + +174 +00:20:14,370 --> 00:20:20,830 +على أحمد لأن هما أخواته في الرضاعة وليس كما يقول + +175 +00:20:20,830 --> 00:20:27,570 +العواممن الناس أن التي تحرم عليه فقط هي التي رضعت + +176 +00:20:27,570 --> 00:20:38,870 +معاه هذا كلام خاطئ فكل بنات فاطمة سواء كنا قبل + +177 +00:20:38,870 --> 00:20:44,530 +التي رضع معاها أو بعد التي رضع معاها محرمات على + +178 +00:20:44,530 --> 00:20:51,270 +أحمده نعم وكذلك تعتبر + +179 +00:20:52,170 --> 00:21:05,210 +أخته زوج فاطمة عامة له نعم هكذا وأمه جدة له فكل ما + +180 +00:21:05,210 --> 00:21:12,730 +يحرم بالرضاعي يحرم بالنسبيه هذا مثال في الكتاب + +181 +00:21:12,730 --> 00:21:17,870 +ويمكن أن نظر بأمثلة أخرى جاءت بها الصنة النبوية + +182 +00:21:17,870 --> 00:21:26,350 +ولم تأتي في القرآن الكريم مثل تحريمالحلي الذهب و + +183 +00:21:26,350 --> 00:21:33,150 +كذلك الحرير على الرجال دون النساء فتحريم الذهب و + +184 +00:21:33,150 --> 00:21:38,310 +الحرير على الرجال دون النساء هذا ما جاءت به السنة + +185 +00:21:38,310 --> 00:21:46,470 +النبوية الشريفة و كذلك تحريم الحمر الأهلية الحمر + +186 +00:21:46,470 --> 00:21:53,510 +الإنسية و الحمر جمع حماروالحمار يجمع جمعة تكسير + +187 +00:21:53,510 --> 00:21:59,630 +على حمير وعلى حمر الحميرة والبغالة كأنهم حمر + +188 +00:21:59,630 --> 00:22:07,530 +مستنفرة فرت من قصورة وهذا بخلاف الحمار الوحشي الذي + +189 +00:22:07,530 --> 00:22:13,590 +يكون في الغاب فهو حلال مثل الخيل ومثل البقر الوحشي + +190 +00:22:13,590 --> 00:22:18,510 +ومثل الغزال والأنب أما الحديث هنا عن الحمار الأهلي + +191 +00:22:19,100 --> 00:22:24,440 +أو الحمار الإنسي الذي يعيش بيننا ويستعمل الركوب + +192 +00:22:24,440 --> 00:22:29,540 +والحراسة ونحو ذلك فقد قال عليه الصلاة والسلام + +193 +00:22:29,540 --> 00:22:32,940 +أنهاكم + +194 +00:22:32,940 --> 00:22:41,540 +عن أكل لحوم الحمر الأهليةنعم فهذا نص من الرسول + +195 +00:22:41,540 --> 00:22:46,700 +الذي لا ينطق عن الهوى صلى الله عليه وسلم في تحريم + +196 +00:22:46,700 --> 00:22:53,740 +أكل لحوم الحمر الأهلية وكان ذلك في غزوة خيبر في + +197 +00:22:53,740 --> 00:23:00,540 +العام السادس من الهجرة النبوية كذلك يحرم الجمع بين + +198 +00:23:00,540 --> 00:23:06,010 +البنت وعمتهاوبين البنت وخالتها أيضًا هذا حكم لم + +199 +00:23:06,010 --> 00:23:10,530 +يرد في القرآن الكريم وإنما جاءت به الصنة النبوية + +200 +00:23:10,530 --> 00:23:19,370 +والعلّة في ذلك أنكم إن فعلتم ذلك فقد قطعتم أرحمكم + +201 +00:23:19,370 --> 00:23:27,150 +نعم إذا جمعت الأخت والأم وقد حرمت في القرآن الكريم + +202 +00:23:27,150 --> 00:23:34,490 +وكذلك العامة والخالة في بيت واحدفإنها تقطع الأرحم + +203 +00:23:34,490 --> 00:23:41,370 +فالجمع بين البنت و عمتها وبين البنت و خالتها يحرمه + +204 +00:23:41,370 --> 00:23:49,290 +لكن إذا ماتت البنت أو طلقت البنت له أن يتزوج + +205 +00:23:49,290 --> 00:23:56,310 +بخالتها أو أن يتزوج بعمتها كما قلنا في الأختين و + +206 +00:23:56,310 --> 00:24:01,020 +أن تجمعوا بين الأختين هذا في القرآن الكريملكن إذا + +207 +00:24:01,020 --> 00:24:06,960 +ماتت الأخت أو طلقت الأخت له أن يتسوج بأختها لأن + +208 +00:24:06,960 --> 00:24:13,520 +التحريم ليس تحريما مطلقا مؤبدا وإنما هو تحريم مؤكد + +209 +00:24:13,520 --> 00:24:22,320 +وكذلك نكاح المتعة الذي أحلته الشيعة وهذا نكاح + +210 +00:24:22,320 --> 00:24:31,020 +المتعة عندنا نحن أهل الصنة حرام شرعالأنه نكاح مؤقت + +211 +00:24:31,020 --> 00:24:42,720 +وعقد الزواج عقد مؤبد أما نكاح المتعة فهو نكاح مؤقت + +212 +00:24:42,720 --> 00:24:48,460 +حرام شرعا حرمه النبي عليه الصلاة والسلام وعلى ذلك + +213 +00:24:48,460 --> 00:24:56,590 +جماهير الفقهاء من أهل الصنةخلافا للشيعة وكان ذلك + +214 +00:24:56,590 --> 00:25:02,770 +في غزوة خيبر في العام السادس من الهجرة النبوية + +215 +00:25:02,770 --> 00:25:06,790 +هكذا أعزائي الطلاب نكون وقد انتهينا من المصدر + +216 +00:25:06,790 --> 00:25:15,110 +الثاني من مصادر النظم الإسلامية وهي الصنة النبوية + +217 +00:25:15,110 --> 00:25:21,980 +بعدالقرآن الكريم أما ثالثا الإجماع الإجماع أيضا + +218 +00:25:21,980 --> 00:25:29,820 +يعتبر من المصادر الأربعة المتفق عليها ما هو مصطلح + +219 +00:25:29,820 --> 00:25:36,500 +الإجماع اتفاق المجتهدين من المسلمين أو من أمة محمد + +220 +00:25:36,500 --> 00:25:45,000 +صلى الله عليه وسلم في أي عصر من العصور بعد وفاة + +221 +00:25:45,000 --> 00:25:52,220 +الرسولبعد وفاة الرسول صلى الله عليه وسلم على حكم + +222 +00:25:52,220 --> 00:26:02,000 +شرعي في قضية لم يرد بحكمها نص من كتاب أو صنة إذا + +223 +00:26:02,000 --> 00:26:09,780 +نحن هنا على موعد مع تعريفات ثلاثة وليس مع تعريف + +224 +00:26:09,780 --> 00:26:17,880 +واحد فقط فالتعريف الأول هو التعريف العامإذا ما جاء + +225 +00:26:17,880 --> 00:26:25,220 +في الامتحان و ستكون المصطلحات من ضمن الامتحانات + +226 +00:26:25,220 --> 00:26:33,220 +والسؤال على شكل توصيل إذا كان الامتحان إلكترونيا + +227 +00:26:33,220 --> 00:26:39,880 +أما إذا كان ورقيا فصيغته السؤال اذكر المصطلح الذي + +228 +00:26:39,880 --> 00:26:46,540 +يناسب الإبارات التالية ولعله بسببجائحة كورونا عفنا + +229 +00:26:46,540 --> 00:26:51,380 +الله وإياكم ونسأل الله السلامة لنا ولكم ولجميع + +230 +00:26:51,380 --> 00:26:56,280 +المسلمين أن يكون الامتحان ألكترونيا يقتصر على + +231 +00:26:56,280 --> 00:27:04,520 +أسئلة ثلاثة السؤال الأول صح أو خطأ والسؤال الثاني + +232 +00:27:04,520 --> 00:27:11,160 +اختيار متعدد والسؤال الثالث مصطلح توصيل لماذا وقفت + +233 +00:27:11,160 --> 00:27:18,440 +هنا قليلالأن الطلب عندما يجيبون على مصطلح الإجماع + +234 +00:27:18,440 --> 00:27:25,460 +لا يفرقون بين المصطلح العام الذي سبق أن ذكرته وهو + +235 +00:27:25,460 --> 00:27:32,000 +اتفاق المجتهدين من أمة محمد عليه الصلاة والسلام في + +236 +00:27:32,000 --> 00:27:40,370 +أي عصر من العصور بعد وفاة الرسولعلى حادثة أو واقعة + +237 +00:27:40,370 --> 00:27:49,210 +لم يرد فيها نص من كتاب او صناة اقف قليلا بعد هذه + +238 +00:27:49,210 --> 00:27:57,510 +المقدمة بعد وفاة الرسول لأنه سبق ان قلت في حديث + +239 +00:27:57,510 --> 00:28:02,750 +محاذ بن جبل ان النبي عليه الصلاة والسلام ذكر له + +240 +00:28:02,750 --> 00:28:09,310 +محاذالمصادر الثلاثة الكتاب والصنة والاجتهاد أو + +241 +00:28:09,310 --> 00:28:16,630 +القياس وقلت لماذا لم يذكر الإجماع لأنه لا إجماع في + +242 +00:28:16,630 --> 00:28:22,270 +حياة الرسول وما اتفق عليه الصحابة في حياة الرسول + +243 +00:28:22,270 --> 00:28:30,580 +لا يسمى إجماعاوإنما يسمى سنة تقريرية وقد ذكرت + +244 +00:28:30,580 --> 00:28:38,100 +أمثلة على ذلك قبل قليل لذلك نضع خط باللون الأحمر + +245 +00:28:38,100 --> 00:28:44,240 +تحت قوله بعد وفاة الرسول فإذا ما جاءكم سؤال مثلا + +246 +00:28:44,240 --> 00:28:50,970 +يعتبر الإجماع أحد مصادرالنظم الإسلامية في العهد + +247 +00:28:50,970 --> 00:28:57,290 +النبوي الإجابة خطأ وليست صحيحة لأن الإجماع كما + +248 +00:28:57,290 --> 00:29:02,230 +رأيتم في التعريف بعد وفاة الرسول عليه الصلاة + +249 +00:29:02,230 --> 00:29:09,870 +والسلام ثم قال هنا في قضية أو في مسألة أو حادثةأو + +250 +00:29:09,870 --> 00:29:15,070 +واقعة لم يرد فيها نص من كتاب أو صنة لأن الإجماعة + +251 +00:29:15,070 --> 00:29:21,350 +يعتبر المصدر الثالثة بعد الكتاب والصنة من مصادر + +252 +00:29:21,350 --> 00:29:25,290 +النظم الإسلامية فلو كان في المسئلة فتوة + +253 +00:29:27,740 --> 00:29:32,860 +آية أو حديث لمّا لجأنا إلى الإجماع لأننا عندما + +254 +00:29:32,860 --> 00:29:38,460 +نسأل سؤالا أو نستفت في فتوة نبحث عنها في كتاب الله + +255 +00:29:38,460 --> 00:29:43,780 +فإن لم نجد فبصنّط رسول الله كما في حديث معاذ سابق + +256 +00:29:43,780 --> 00:29:50,480 +الذكرفإن لم نجد فالإجماع وإلا فالاجهاد والقياس كما + +257 +00:29:50,480 --> 00:29:58,020 +قال معاذ أجتهد رأي ولا آله أي لا أقصر أو أجتهد في + +258 +00:29:58,020 --> 00:30:03,320 +استنباط الأحكام الشرعية من أدلتها التفصيلية من + +259 +00:30:03,320 --> 00:30:12,100 +خلال هذا التعريف يمكن أن نستنبط أركان الإجماع وهي + +260 +00:30:12,100 --> 00:30:19,920 +ثلاثةأولا وجود عدد من المجتهدين عند وقوع الحادثة + +261 +00:30:19,920 --> 00:30:26,320 +اذ لا عبرة بوجود غيرهم لأن فاقد الشيء لا يعطيه + +262 +00:30:26,320 --> 00:30:33,860 +ونحن لا يتسع المقام لذكر أوصاف المجتهدين لأن + +263 +00:30:33,860 --> 00:30:41,040 +الاجتهاد باب طويليدرّس في أصول الفقه لأولادنا في + +264 +00:30:41,040 --> 00:30:45,920 +كلية الشريعة والقانون من أهل التخصص في كتاب + +265 +00:30:45,920 --> 00:30:49,180 +الإحكام + +266 +00:30:49,180 --> 00:30:55,960 +للأمدي نعم و هناك التفسير ولكن أقل ما يقال عن + +267 +00:30:55,960 --> 00:31:02,600 +المجتهدين أنهم يحفظون كتاب الله ولا يحفظونه غيبا + +268 +00:31:02,600 --> 00:31:04,020 +فقط + +269 +00:31:05,950 --> 00:31:12,810 +وإنما يحفظونه مع معرفة الأحكام الشرعية ولذلك هناك + +270 +00:31:12,810 --> 00:31:20,410 +تفاسير اختصت بأحكام القرآن مثل الجامع لأحكام + +271 +00:31:20,410 --> 00:31:25,010 +القرآن للقرطبي ومثل أحكام القرآن لابن العرب + +272 +00:31:25,010 --> 00:31:31,530 +المالكي وكلاهما مالكي القرطبي وابن العرب كلاهما + +273 +00:31:31,530 --> 00:31:39,260 +مالكيوكذلك أحكام القرآن للجصاص وهو حنفي وأحكام + +274 +00:31:39,260 --> 00:31:45,740 +القرآن للكيا الغراسي وهو شافعي وزاد المسير في علم + +275 +00:31:45,740 --> 00:31:52,700 +التفسير لابن الجوزي وهو حنبلي وهنا نفرق بين ابن + +276 +00:31:52,700 --> 00:32:00,110 +الجوزي وابن قيم الجوزيةفابن قيم الجوزية التلميذ + +277 +00:32:00,110 --> 00:32:06,850 +النجيب لشيخ الإسلام ابن تيمية صاحب المؤلفات التي + +278 +00:32:06,850 --> 00:32:16,250 +كثرت وأما ابن الجوزي ابن العراق ومغداد فهو حنبلي + +279 +00:32:16,250 --> 00:32:24,390 +أيضا ولذلك يقال زاد المسير وما أكثر مؤلفاته لابن + +280 +00:32:24,390 --> 00:32:32,360 +الجوزيأما ابن القيم الشامى فيقول ابن القيم هذه + +281 +00:32:32,360 --> 00:32:39,240 +معلومة للدراسات العليا فائدة لا نبخل عليكم بها أو + +282 +00:32:39,240 --> 00:32:44,920 +ابن قيم الجوزية الجوزية كانت مدرسة في بلاد الشام + +283 +00:32:44,920 --> 00:32:50,860 +والقيم بمنزلة المديرالمشرف على هذه المدرسة فيقال + +284 +00:32:50,860 --> 00:32:56,360 +ابن القيم هكذا او ابن قيم الجوزية ويخطئ بعض الطلاب + +285 +00:32:56,360 --> 00:33:01,960 +الماجستير او الدكتوراه عندما يكتبون في الهامش ابن + +286 +00:33:01,960 --> 00:33:08,100 +القيم الجوزيةهذا من الأخطاء وليس مطلوب ولكن أردت + +287 +00:33:08,100 --> 00:33:15,160 +أن لا أبخلى عليكم وكذلك الصنة النبوية وأحكامها + +288 +00:33:15,160 --> 00:33:20,560 +والصنة لها شروح مثل فتح الباري في شرح الصحيح + +289 +00:33:20,560 --> 00:33:28,440 +البخاري وعرضة الأحواذيللمبارك فوري في شرح الترمذي + +290 +00:33:28,440 --> 00:33:34,420 +ومعالم الصنن للخطابي ونيل الأوطار للشوكاني وصوب + +291 +00:33:34,420 --> 00:33:43,880 +السلام للصنعاني الكحلاني وهكذا هي الصنة النبوية + +292 +00:33:43,880 --> 00:33:51,960 +وشرحها وكذلك يشترط في المجتهدو هذا شرط مهم جدا أن + +293 +00:33:51,960 --> 00:33:59,520 +يكون عالما ضليعا باللغة العربيةلأن القرآن الكريم + +294 +00:33:59,520 --> 00:34:04,060 +باللغة العربية و كذلك الصنة النبوية باللغة العربية + +295 +00:34:04,060 --> 00:34:08,760 +فإذا لم يكن فقيها باللغة العربية لا يصلح أن يكون + +296 +00:34:08,760 --> 00:34:15,780 +عالما لا يصلح أن يكون مفسرا أو مجتهدا و هكذا عليه + +297 +00:34:15,780 --> 00:34:22,140 +أن يكون على علم أيضا بإجماع الصحابة و إجتهادات + +298 +00:34:22,140 --> 00:34:29,800 +التابعين هذا هو الرقم الأولمن أركان الإجماع وجود + +299 +00:34:29,800 --> 00:34:35,740 +عدد من المجتهدين لأن الله قال فاسألوا أهل الذكر إن + +300 +00:34:35,740 --> 00:34:42,020 +كنتم لاتعلمون ومن أهل الذكر هم أهل التخصص والجاهل + +301 +00:34:42,020 --> 00:34:50,360 +لا يسأله ولا يستفتى إذ لا عبرةبوجود غير المجتهدين + +302 +00:34:50,360 --> 00:34:56,480 +ثانيا من أركان الإجماع اتفاق المجتهدين على الحكم + +303 +00:34:56,480 --> 00:35:05,700 +وقت حدوث الواقعة بحيث لا يخالف في الحكم أحد منهم + +304 +00:35:05,700 --> 00:35:13,040 +أو يرجع عنه وإلا فلا ينعقد الإجماع اتفاق المجتهدين + +305 +00:35:13,040 --> 00:35:19,460 +على الحكموقت حدوث الواقعة هذا هو الركن الثاني من + +306 +00:35:19,460 --> 00:35:25,440 +أركان الإجماع بحيث لا يخالف في الحكم أحد منهم أو + +307 +00:35:25,440 --> 00:35:36,300 +يرجع عنهم وإلا فلا ينعقدوا الإجماع أما ثالثا أن + +308 +00:35:36,300 --> 00:35:41,920 +يكون الاتفاق بعد وفاة الرسول صلى الله عليه وسلم + +309 +00:35:42,570 --> 00:35:51,810 +ولذلك قلت لكم ضعوا خطة أحمر أو خطوط تحت هذه الكلمة + +310 +00:35:51,810 --> 00:35:54,350 +لأنه من خلال تصحيحي + +311 +00:35:57,510 --> 00:36:05,430 +لآلاف الأسئلة و خاصة في متطلبات الجامعة حيث ندرس + +312 +00:36:05,430 --> 00:36:10,730 +في كل فصل ال آلاف و ليس العشرات أو المئات كما هو + +313 +00:36:10,730 --> 00:36:17,030 +في التخصص وجدت أنهم يخطئونلذا ألفطوا أنظركم إلى + +314 +00:36:17,030 --> 00:36:22,290 +الانتباه بأن الإجماعة إنما يكون بعد وفاة الرسول + +315 +00:36:22,290 --> 00:36:30,350 +صلى الله عليه وسلم نعم في واقعة لا نص في حكمها لا + +316 +00:36:30,350 --> 00:36:36,590 +من القرآن الكريمولا من الصنة النبوية لأنه لو كان + +317 +00:36:36,590 --> 00:36:41,490 +هناك نص من القرآن أو من الصنة لما لجأنا إلى + +318 +00:36:41,490 --> 00:36:47,130 +الإجماع فالقرآن الكريم هو المصدر الأول كما أسميناه + +319 +00:36:47,130 --> 00:36:52,950 +بمصدر المصادر أو كلي الشريعة والصنة النبوية هي + +320 +00:36:52,950 --> 00:36:56,730 +المصدر الثاني كما قال الله تعالى يا أيها الذين + +321 +00:36:56,730 --> 00:37:02,060 +أمنوا أطيعوا الله وأطيعوا الرسولأي في كتابه وفي + +322 +00:37:02,060 --> 00:37:08,940 +سنته وأما ثالثًا فالإجماع يُعتبر المصدر الثالثة + +323 +00:37:08,940 --> 00:37:14,540 +إذا لم نجد في المسألة فتوة من كتاب أو سنة نأتي + +324 +00:37:14,540 --> 00:37:21,520 +الآن إلى أنواع الإجماع والإجماع نوعًا إجماع صريح + +325 +00:37:21,520 --> 00:37:27,180 +وإجماع سقطت لذا قلت لكم في أول المحاضرة لابد من + +326 +00:37:27,180 --> 00:37:34,660 +التفريقبين مصطلح الإجماع بمعناه العام وبين مصطلحي + +327 +00:37:34,660 --> 00:37:41,160 +الصريح والسكوتي لأني رأيت بعض الطلاب يكتبون + +328 +00:37:41,160 --> 00:37:46,620 +الإجماع هذا غير صحيح الإجماع إنما يكون للمصطلح + +329 +00:37:46,620 --> 00:37:52,450 +الأول للإجماع بمعناه العامأما إذا كان الإجماع + +330 +00:37:52,450 --> 00:37:59,610 +صريحا أو كان ثقوتيا فلابد أن يكتب الطالب الإجماع + +331 +00:37:59,610 --> 00:38:07,850 +الصريح أو الإجماع الثقوتى ما هو مصطلح الإجماع + +332 +00:38:07,850 --> 00:38:14,590 +الصريح هو ما اتفق فيه جميع مجتهدي عصر من العصور + +333 +00:38:14,590 --> 00:38:22,390 +أيضا بعد وفاة الرسول صلى الله عليه وسلمعلى حكم + +334 +00:38:22,390 --> 00:38:29,950 +واقعة بإبداء كل واحد منهم رأيه صراحة بفتوى أو قضاء + +335 +00:38:29,950 --> 00:38:37,270 +وهو حجة قاطعة لا يحكم في واقعة بخلافه ومثال ذلك + +336 +00:38:37,270 --> 00:38:44,530 +الإجماع على حد شارب الخمر ثمانين جلدة ماذا نلحظ + +337 +00:38:44,530 --> 00:38:49,950 +هنا نلحظ هنا أن الإجماع الصريح هو اتفاق جميع + +338 +00:38:49,950 --> 00:38:58,730 +المجتهدينولذا أطلب منكم عند النظر في هذا المسجل أو + +339 +00:38:58,730 --> 00:39:05,170 +المصور أو حتى القراءة في الكتاب أن تضعوا خطة أو + +340 +00:39:05,170 --> 00:39:15,090 +خطوط تحت قولنا جميعلأن كلمة جميع هي التي تفرق بين + +341 +00:39:15,090 --> 00:39:19,570 +الإجماع الصريح وبين الإجماع السقوطي كما سيأتي بعد + +342 +00:39:19,570 --> 00:39:25,290 +قليل ان شاء الله فالإجماع الصريح هو اتفاق جميع + +343 +00:39:25,290 --> 00:39:31,470 +المجتهدين من المسلمين من أمة محمد في أي عصر من + +344 +00:39:31,470 --> 00:39:38,090 +العصور بعد وفاة الرسول أيضاعلى واقعة أو حادثة أو + +345 +00:39:38,090 --> 00:39:45,470 +مسألة لم يرد فيها نص من كتاب أو صنعة نعم ما حكم + +346 +00:39:45,470 --> 00:39:55,370 +الإجماع الصحي وجوب العمل به وجوب العمل به إذا + +347 +00:39:55,370 --> 00:40:03,330 +الإجماع الصريح يجب العمل به لأنه حجة قاطعةوما معنى + +348 +00:40:03,330 --> 00:40:08,750 +وجوب العمل به وهو حجة القطعة بمعنى لا يجوز مخالفته + +349 +00:40:08,750 --> 00:40:18,890 +بل يجب الأخذ به وأما ما لم يأخذ به فما حكمه آثم + +350 +00:40:18,890 --> 00:40:28,920 +وعاص لله تبارك وتعالى وضرب لنا مثالاوهو في عهد + +351 +00:40:28,920 --> 00:40:33,360 +عمرو بن الخطاب رضي الله عنه إجماع الصحابة في عهد + +352 +00:40:33,360 --> 00:40:40,500 +عمرو على جلد شارب الخمر ثمانين جلدة فكان إجماعا + +353 +00:40:40,500 --> 00:40:48,980 +صريحا لا غموض فيه ولا خلافة ولا لبسة أما النوع + +354 +00:40:48,980 --> 00:40:56,790 +الثاني من أنواع الإجماع فهو الإجماع السكوتيوهنا + +355 +00:40:56,790 --> 00:41:05,450 +نقول الإجماع السكوتي هو ما يقرره بعض المجتهدين في + +356 +00:41:05,450 --> 00:41:11,510 +عصر من العصور حول حادثة ما ويمتنع الآخرون عن + +357 +00:41:11,510 --> 00:41:17,730 +الموافقة أو المخالفة بدون عذر ومخالفة هذا الإجماع + +358 +00:41:17,730 --> 00:41:26,430 +غير محرمة نظرا لعدم وجوب مانع يمنع الساكتين عنهإذا + +359 +00:41:26,430 --> 00:41:33,890 +كما قلت لكم ضعوا خطة تحت جميع في الإجماع الصريح + +360 +00:41:33,890 --> 00:41:39,830 +ضعوا خطة أو خطوط أخرى تحت بعض هذا هو الذي يفرق + +361 +00:41:39,830 --> 00:41:47,850 +الإجماع الصريح عن الإجماع السكوتي فالإجماع الصريح + +362 +00:41:47,850 --> 00:41:56,380 +هو اتفاق جميع المجتهدين نعموالإجماع السكوتى هو + +363 +00:41:56,380 --> 00:42:04,680 +اتفاق بعض المجتهدين بينما سكوت البعض الآخر دون عذر + +364 +00:42:04,680 --> 00:42:14,540 +يمنعهم من الإدلاء بفتواهم نعم لكن ما حكم الإجماع + +365 +00:42:14,540 --> 00:42:20,140 +الصريح أنه ليس حجة قاطعة + +366 +00:42:22,250 --> 00:42:33,090 +ولذلك المسلم لا يجب عليه الأخذ به بل هو مخير بين + +367 +00:42:33,090 --> 00:42:40,950 +الأخذ وبين التركه ولا يأثم تركه إذا أيضا نعيد + +368 +00:42:40,950 --> 00:42:45,910 +لأهمية هذه النقطة الإجماع الصريح هو اتفاق جميع + +369 +00:42:45,910 --> 00:42:54,950 +المجتهدين وهو حجة قاطعةلا يحكم بخلافه و يأثم تاركه + +370 +00:42:54,950 --> 00:43:05,950 +لاتفاق جميع المجتهدين أما الإجماع السكوتي فهو ليس + +371 +00:43:05,950 --> 00:43:13,850 +حجة قاطعة و المسلم مخير بين الأخذ و الترك و لا + +372 +00:43:13,850 --> 00:43:22,010 +يأثم تاركه طبعا هنا الكتابلم يضرب لنا مثالا لأن + +373 +00:43:22,010 --> 00:43:29,570 +المثال انما هو في كتب المعاملات كما يدرس في التخصص + +374 +00:43:29,570 --> 00:43:35,170 +في متطلب الكلية في كلية الشريعة في الجامعة + +375 +00:43:35,170 --> 00:43:42,630 +الإسلامية يدرس باب البيوعو هنا يستدلون على ذلك + +376 +00:43:42,630 --> 00:43:48,250 +بمثال نأتي به من أجل الفائدة و ليس مطلوبا في + +377 +00:43:48,250 --> 00:43:53,170 +الامتحان لأنه ليس موجودا في الكتاب و الامتحان + +378 +00:43:53,170 --> 00:44:02,130 +المقرر هو فقط في الكتاب و يستثنى ما شطبناه عنكم + +379 +00:44:02,890 --> 00:44:09,370 +لأنكم ستدرسونه في مساقات أخرى كالعقيدة والاقتصاد + +380 +00:44:09,370 --> 00:44:18,110 +الإسلامي قالوا بأن بيع الشيء قبل نقله يعتبر من + +381 +00:44:18,110 --> 00:44:27,170 +الإجماع السكوتى إذا ما اشترى شخص سلعة مثلا كسيارة + +382 +00:44:27,170 --> 00:44:36,130 +في مستودع لا يجوز لهان يبيعها حتى تخرج من المستودع + +383 +00:44:36,130 --> 00:44:41,490 +او مثلا اشتراها في سوق ليس له ان يبيعها في السوق + +384 +00:44:41,490 --> 00:44:48,830 +حتى ينقلها الى مكان اخر والعلّة في ذلك انهم قالوا + +385 +00:44:48,830 --> 00:44:56,110 +انها تشبه الربا لكن انا اقول بخلاف ذلك وافتي بجواز + +386 +00:44:56,110 --> 00:45:04,160 +الاخذ مع ان المكلفة المسلمةشرعا كما قلنا هو مخيّر + +387 +00:45:04,160 --> 00:45:10,520 +بين أن يأخذ بهذا وبين أن لا يأخذ بهذا فالذين ذهبوا + +388 +00:45:10,520 --> 00:45:18,020 +إلى الورق والبعد عن الشبهات قالوا بحرمة هذا البيع + +389 +00:45:18,020 --> 00:45:25,440 +إذا بيعت السلعة بعد شرائها ولم تنقل إلى مكان آخر + +390 +00:45:25,440 --> 00:45:31,310 +لأنها أشبه ما تكون في هذه الحالة بالربالكن البون + +391 +00:45:31,310 --> 00:45:37,770 +شاسع والفرق كبير لأن الربا بيع نقد بنقد أن تبيع + +392 +00:45:37,770 --> 00:45:43,930 +ألف دينار مثلا أو ألف شكل بألف وعشرة هذا هو الربا، + +393 +00:45:43,930 --> 00:45:51,720 +لكن هنا بيع صلة بصلةواليوم في ظل العصر الحديث لا + +394 +00:45:51,720 --> 00:45:59,180 +ينبغي الفتوى بهذا فالفتوى صارت عبر الأنموذج وصارت + +395 +00:45:59,180 --> 00:46:08,220 +عبر الإلكترونيات والأجهزة الحديثة من facts ونحو + +396 +00:46:08,220 --> 00:46:16,080 +ذلك مما لا يخفىإذا بيعت السلعة في محلها بعد شرائها + +397 +00:46:16,080 --> 00:46:26,120 +فليست محرمة ولا يأثم فاعلها لأنه كما قلت إجماع غير + +398 +00:46:26,120 --> 00:46:35,600 +صريح إجماع سكوتي بمعنى اتفق فيه البعض وسكت فيه + +399 +00:46:35,600 --> 00:46:42,170 +البعضولذا أنت أيها المسلم مخير بين أن تأخذ به وبين + +400 +00:46:42,170 --> 00:46:46,270 +أن لا تأخذ به أردت بهذا المثال بعيدا عن الكتاب + +401 +00:46:46,270 --> 00:46:52,930 +نختم الآن ان شاء الله تعالى المبحث الرابع وهو + +402 +00:46:52,930 --> 00:47:00,510 +مصادر النظم الإسلامية بالمصدر الرابع وهوالقياس + +403 +00:47:00,510 --> 00:47:07,630 +والقياس يعتبر من أهم أبواب الفقه الإسلامي حتى سماه + +404 +00:47:07,630 --> 00:47:14,990 +البعض بالاجتهاد لأن الأمور تتغير في كل مكان وفي كل + +405 +00:47:14,990 --> 00:47:20,070 +زمان والنبي عليه الصلاة والسلام ذكر في حديث الربا + +406 +00:47:20,070 --> 00:47:26,400 +ستةفي الحديث الصحيح عند البخاري وغيره عن أبي سعيد + +407 +00:47:26,400 --> 00:47:34,240 +الخدري عندما قال الذهب بالذهب والفضة بالفضة والبر + +408 +00:47:34,240 --> 00:47:38,640 +بالبر يعني القمح بالقمح والشعير بالشعير والملح + +409 +00:47:38,640 --> 00:47:45,170 +بالملح والتمر بالتمر طب فأين الأرز؟و أين العدس؟ و + +410 +00:47:45,170 --> 00:47:53,230 +أين الحمص؟ نعم بالفصحى حمص أما أنتم فقولوا حمص أما + +411 +00:47:53,230 --> 00:48:01,190 +إذا أردتم الفصحى فالحمص بكسر الحق و ليس بالضم و + +412 +00:48:01,190 --> 00:48:05,070 +أين المجروش؟ + +413 +00:48:05,740 --> 00:48:17,880 +وغير ذلك من مثلا الفاكهة المجففة غير التمر كالقطين + +414 +00:48:17,880 --> 00:48:28,620 +مثلا مجفف التين وكذبيب مجفف العنب أين هذه الأشياء؟ + +415 +00:48:28,620 --> 00:48:35,340 +ليست في الحديثولذلك لابد هنا وهذا من أخطر الأبواب + +416 +00:48:35,340 --> 00:48:42,060 +بل من أهمها لابد من البحث عن العلة فنقول لماذا + +417 +00:48:42,060 --> 00:48:47,080 +حرمت هذه الأشياء فالعلة في الذهب والفضة هي + +418 +00:48:47,080 --> 00:48:54,030 +الثمانيةأو النقدية وهذا سيدرّس لكم في الفقه + +419 +00:48:54,030 --> 00:48:59,630 +الإسلامي قسم المعاملات في الفقه المنهجي على مذهب + +420 +00:48:59,630 --> 00:49:04,430 +الإمام الشافعي فالنقدية أو الثمانية هي لا إلا + +421 +00:49:04,430 --> 00:49:11,890 +وعليه يحرم بيع العملات الورقية بالزيادة + +422 +00:49:11,890 --> 00:49:19,590 +أو النقصان لأنها ربن مثل الدينار والدولاروالشيكل + +423 +00:49:19,590 --> 00:49:25,630 +وال يورو ونحو ذلك من المارك الألماني الفرنكي + +424 +00:49:25,630 --> 00:49:30,870 +الفرنسي أو الجنيه المصري أو السترليني أو الليرة + +425 +00:49:30,870 --> 00:49:36,990 +التركية إلى غير ذلك من أنواع العملات فكما يحرم بيع + +426 +00:49:36,990 --> 00:49:41,730 +ألف دينار من الذهب أو الف دينار من الفضة بألف + +427 +00:49:41,730 --> 00:49:50,320 +وعشرة كذلك يحرم بيع ألف دينار من الورقالذى يسمى + +428 +00:49:50,320 --> 00:49:57,040 +الدنار الأردني او الدولار بالألف وعشرة ونحو ذلك + +429 +00:49:57,040 --> 00:50:03,920 +إلى غير ذلك من الأبواب وكذلك هنا تحرم البيرة قياسا + +430 +00:50:03,920 --> 00:50:09,260 +على الخمرة لأن العلة في الخمرة هي الإسكار والبيرة + +431 +00:50:09,260 --> 00:50:16,260 +مسكرة فتحرم فكل مسكر خمر وكل خمر حرام وإن لم يكن + +432 +00:50:16,260 --> 00:50:24,660 +من العنابأما مصطلح القياس فهو إلحاق واقعة لم يرد + +433 +00:50:24,660 --> 00:50:30,680 +نص شرعي على حكمها بواقعة ورد نص شرعي بحكمها + +434 +00:50:30,680 --> 00:50:36,440 +لإشتراك الواقعتين في علّة هذا الحكم استطيع أن أقول + +435 +00:50:36,440 --> 00:50:44,920 +بصيغة أخرى القياس إلحاق فرعغير منصوص على حكمه بأصل + +436 +00:50:44,920 --> 00:50:51,500 +منصوص على حكمه لإشتراكهما في علة واحدة كما قلنا في + +437 +00:50:51,500 --> 00:50:57,320 +الخمر فالخمر هو عصير العنب الذي غلى وقذف بالزبد + +438 +00:50:57,320 --> 00:51:02,980 +والعلة فيه الإسكا فيحرم البيرة والعرق والويسكي + +439 +00:51:02,980 --> 00:51:07,940 +وغير ذلك من الأسماء نسأل الله أن يعافينا + +440 +00:51:07,940 --> 00:51:13,380 +لإشتراكهما في العلةفنسقط حكم الخمرة و هو الحرمة + +441 +00:51:13,380 --> 00:51:18,000 +على الفرق و من خلال التعريف يمكن أن نستنبط الأركان + +442 +00:51:18,000 --> 00:51:24,420 +الأربعة فأركان القياسي أربعة أصل و فرع و حكم الأصل + +443 +00:51:24,420 --> 00:51:30,610 +و العلةوإياك أن تخطأ فتقول حكم الفرع لا حكم الأصل + +444 +00:51:30,610 --> 00:51:37,170 +فالأصل هو المقيس عليه كما ضربنا بالذهب و الفضة و + +445 +00:51:37,170 --> 00:51:44,230 +الخمرة وهو ما ورد بحكمه نص و يسمى المقيس عليه لأن + +446 +00:51:44,230 --> 00:51:49,010 +الفروع التي لم يرد فيها نص تخاسه عليه أما الفرع + +447 +00:51:49,010 --> 00:51:56,470 +وهو المقيس فهو الشيء الذي لم يرد بحكمه نصويراد + +448 +00:51:56,470 --> 00:52:02,770 +تسويته بالاصل في حكمه أي معرفة حكمه أما حكم الأصل + +449 +00:52:02,770 --> 00:52:08,050 +فهو الحكم الشرعي الذي ورد به النص في الأصل من الحل + +450 +00:52:08,050 --> 00:52:13,330 +أو من الحرمة ويراد أن يكون مثله في الفرق أما العلة + +451 +00:52:13,330 --> 00:52:19,990 +فهي الوصف أو السبب الذي بني عليه حكم الأصل لوجوده + +452 +00:52:20,500 --> 00:52:25,120 +في الفرعي هقول قولي هذا و أستغفر الله ليه لكم و + +453 +00:52:25,120 --> 00:52:29,060 +السلام عليكم و رحمة الله نكون ان شاء الله في + +454 +00:52:29,060 --> 00:52:35,180 +المحاضرة التالية على موعد مع الفصل الثاني و ليس مع + +455 +00:52:35,180 --> 00:52:40,700 +الفصل الأول لأن الفصل الأول و هو العقيدة غير مقرر + +456 +00:52:40,700 --> 00:52:47,370 +في الامتحان و غير مطلوب منكم لأنه سيدرس لكمفي كلية + +457 +00:52:47,370 --> 00:52:51,990 +أصول الدين تحت عنوان شرح أصول العقيدة الإسلامية + +458 +00:52:51,990 --> 00:52:58,190 +لزميلنا الدكتور ناسيم شيخ ده ياسين فنكون على موعد + +459 +00:52:58,190 --> 00:53:03,390 +مع الفصل الثاني وهو بعنوان نظام العبادة في الإسلام + +460 +00:53:03,390 --> 00:53:07,450 +والسلام عليكم ورحمة الله وبركاته + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/f0tiPvvYPLw.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/f0tiPvvYPLw.srt new file mode 100644 index 0000000000000000000000000000000000000000..67b7b757a834beafe8545ce21804d4fed36ee116 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/f0tiPvvYPLw.srt @@ -0,0 +1,2027 @@ +1 +00:00:04,940 --> 00:00:07,860 +أعوذ بالله السميع العلي من الشيطان الرجيم بسم الله + +2 +00:00:07,860 --> 00:00:11,180 +الرحمن الرحيم الحمد لله والصلاة والسلام على رسول + +3 +00:00:11,180 --> 00:00:15,460 +الله دائما وأبدا نعطر مجالسنا بالصلاة على الحبيب + +4 +00:00:15,460 --> 00:00:20,040 +محمد صلى الله عليه وسلم عزيزي الطلاب قبل ذِي بدء + +5 +00:00:20,040 --> 00:00:25,040 +أرحب بكم جميعا وأحييكم بتحية الإسلام العظيم فسلام + +6 +00:00:25,040 --> 00:00:30,980 +الله عليكم ورحمته وبركاته وقبل ذِي بدء الحمد لله + +7 +00:00:30,980 --> 00:00:37,050 +على سلامتكم بعد أن نجان الله من القوم الظالمين ومن + +8 +00:00:37,050 --> 00:00:42,030 +علينا بالنصر المبين وصدق الله العظيم فلم تقتلوهم + +9 +00:00:42,030 --> 00:00:46,890 +ولكن الله قتلهم وما رميت إذا رميت ولكن الله رمى + +10 +00:00:46,890 --> 00:00:55,110 +نحن اليوم على موعد مع تتمة الفصل الرابع وعلى موعد + +11 +00:00:55,110 --> 00:01:03,270 +مع المبحث الخامس ثالثا المجالات التي فرق فيها + +12 +00:01:03,270 --> 00:01:08,370 +الإسلام بين الرجل والمرأة وسوف نقتصر على ثلاثة كما + +13 +00:01:08,370 --> 00:01:15,510 +في الكتاب أولا الشهادة وثانيا الميراث وثالثا رئاسة + +14 +00:01:15,510 --> 00:01:23,000 +الدولة إذا نحن إن شاء الله على موعد مع المجالات + +15 +00:01:23,000 --> 00:01:28,640 +التي فرق فيها الإسلام بين الرجل وبين المرأة بدءا + +16 +00:01:28,640 --> 00:01:34,960 +بالشهادة حيث سعم أعداء الإسلام بأن الإسلام قد ظلم + +17 +00:01:34,960 --> 00:01:42,400 +المرأة وجعلها على نصف من شهادة الرجل مستدلين بقوله + +18 +00:01:42,400 --> 00:01:47,140 +تبارك وتعالى واستشهدوا شهيدين من رجالكم فإن لم + +19 +00:01:47,140 --> 00:01:54,270 +يكون رجلين فرجل وامرأتان ممن ترضون من الشهداء أن تضل + +20 +00:01:54,270 --> 00:02:00,750 +إحداهما فتذكر إحداهما الأخرى ونحن قبل الحديث عن + +21 +00:02:00,750 --> 00:02:11,530 +هذه الآية أرى أن نبدأ بالبند الثالث والبند الثاني + +22 +00:02:11,530 --> 00:02:18,290 +وبعد ذلك نعود إلى البند الأول الذي فيه الآية ونقول + +23 +00:02:18,290 --> 00:02:28,160 +لهم أنتم تنظرون بعين واحدة ولا تنظرون بعينين سنتين + +24 +00:02:28,160 --> 00:02:35,900 +أين أنتم من قضايا أخرى لا تقبل فيها شهادة الرجال + +25 +00:02:35,900 --> 00:02:46,260 +أبدا وإنما تقبل فيها شهادة النساء وحدهن مثل إثبات + +26 +00:02:46,260 --> 00:02:55,090 +الولادة لأن المرأة هي التي كانت تقوم بتوليد المرأة + +27 +00:02:55,090 --> 00:03:03,230 +وهي القابلة فهي قادرة بنسب هذا الطفل وكذلك الثيوبة + +28 +00:03:03,230 --> 00:03:11,930 +والبكارة في حال جريمة الزنا مثلا إذا متهمت امرأة + +29 +00:03:11,930 --> 00:03:20,090 +مثلا بكر بالزنا كيف يُعرف أنها بكر أم ثيب إلا عبر + +30 +00:03:20,090 --> 00:03:26,450 +شهادة النساء وكذلك العيوب الجلدية الداخلية والعيوب + +31 +00:03:26,450 --> 00:03:36,080 +الجنسية فكل هذه القضايا التي لم تجري العادة بالطلاع + +32 +00:03:36,080 --> 00:03:43,320 +الرجال عليها لا يصح فيها شهادة الرجال وإنما تقبل + +33 +00:03:43,320 --> 00:03:50,600 +فيها شهادة المرأة وحدها كما أسلفنا كإثبات الولادة + +34 +00:03:50,600 --> 00:03:59,240 +أو النسب وكذلك هل المرأة ثيب أم بكر وكذلك العيوب + +35 +00:03:59,240 --> 00:04:05,660 +الداخلية من العيوب الجلدية والعيوب الجنسية فهل + +36 +00:04:05,660 --> 00:04:10,760 +للرجال أن يغضبوا وأن يصوروا وأن يقولوا لماذا لم + +37 +00:04:10,760 --> 00:04:17,720 +تقبل شهادتنا في هذه المسائل لماذا لم تلتفتوا إلى + +38 +00:04:17,720 --> 00:04:25,160 +هذا والتفتتم هناك فقط نعم سنأتي إلى ذلك إن شاء + +39 +00:04:25,160 --> 00:04:31,370 +الله ولن نفر منه ولكن نبدأ بهذه الحقائق أما البند + +40 +00:04:31,370 --> 00:04:40,390 +الثاني لماذا غفلتم أيضا عن أن شهادة المرأة كشهادة + +41 +00:04:40,390 --> 00:04:48,030 +الرجل في أيمان اللعان التي سماها القرآن الكريم + +42 +00:04:48,030 --> 00:04:54,290 +بالشهادات لأن الشهادة في الصناعة تحتاج إلى أربعة + +43 +00:04:54,290 --> 00:05:04,010 +شهود فكان كل يمين بمنزلة شهادة واللعان كما هو عندكم + +44 +00:05:04,010 --> 00:05:10,370 +في الهامش وهذا التفتوا إليه جيدا لأن البعض الذي + +45 +00:05:10,370 --> 00:05:16,110 +لم يحضر المحاضرات يغفل عن هذا المصطلح لأن + +46 +00:05:16,110 --> 00:05:24,410 +المصطلحات غالبا تكون فوق الهامش في صدر الصفحة أما + +47 +00:05:24,410 --> 00:05:30,890 +هذا المصطلح فهو في الهامشة واللعان كما عندكم في + +48 +00:05:30,890 --> 00:05:38,210 +الهامشة كلمات معلومة جعلت حجة للمضطر إلى قذف ملطخ + +49 +00:05:38,210 --> 00:05:47,470 +فراشه وألحق العار به أو إلى نفي الولد نعم وصمت + +50 +00:05:47,470 --> 00:05:54,050 +هذه الكلمات لعانا لقول الرجل عليه لعنة الله إن كان + +51 +00:05:54,050 --> 00:06:01,830 +من الكاذبين أو عليها لعنة الله إن كان من الصادقين + +52 +00:06:01,830 --> 00:06:09,510 +نعم إذا في شهادات اللعان تساوت شهادات الرجال + +53 +00:06:09,510 --> 00:06:18,490 +وشهادات النساء فالرجل يشهد أربع شهادات بالله إنه + +54 +00:06:18,490 --> 00:06:25,030 +لمن الصادقين والخامسة أن لعنة الله عليه إن كان من + +55 +00:06:25,030 --> 00:06:30,760 +الكاذبين فإذا اعترفت المرأة بالجريمة أقيم عليها حد + +56 +00:06:30,760 --> 00:06:38,900 +الزنا وهو الرجم وإذا لم تعترف ويدرأ عنها العذاب أن + +57 +00:06:38,900 --> 00:06:44,720 +تشهد أربع شهادات بالله إنه لمن الكاذبين هكذا كما + +58 +00:06:44,720 --> 00:06:51,740 +ترون تساوت شهادة المرأة مع شهادة الرجل بأن تشهد + +59 +00:06:51,740 --> 00:06:58,520 +أربع شهادات بالله إنه لمن الكاذبين فيما رماها به من + +60 +00:06:58,520 --> 00:07:05,100 +الفاحشة أو جريمة الزنا والخامسة أن غضب الله عليها + +61 +00:07:05,100 --> 00:07:10,760 +إن كان من الصادقين فنقول أين أنتم من هذا؟ في + +62 +00:07:10,760 --> 00:07:17,980 +المسألة الأولى هناك مسائل لا تقبل فيها إلا شهادة + +63 +00:07:17,980 --> 00:07:26,030 +النساء كما أسلفنا من إثبات النسب أو الولادة لأن + +64 +00:07:26,030 --> 00:07:33,010 +المرأة القابلة هي التي كانت تتولى توليد المرأة و + +65 +00:07:33,010 --> 00:07:43,030 +كذلك العيوب الجنسية والعيوب الجلدية وهل هي ثيب + +66 +00:07:43,030 --> 00:07:49,470 +أم بكر وأين أنتم من هذه المسألة الثانية لما تساوت + +67 +00:07:49,470 --> 00:07:55,560 +شهادة الرجال وشهادة النساء في أيمان اللعن أو في + +68 +00:07:55,560 --> 00:08:03,060 +شهادات اللعن وقد قلت إن هذه الايمان صمت شهادات لأن + +69 +00:08:03,800 --> 00:08:10,840 +نصاب الشهود في جريمة الزنا أربع شهادات لخطورة هذه + +70 +00:08:10,840 --> 00:08:17,860 +الجريمة ولذلك كانت أربعا أما الآن فنأتي إلى الآية + +71 +00:08:17,860 --> 00:08:23,640 +حيث زعم أعداء الإسلام الذين ينظرون بعين واحدة بأن + +72 +00:08:23,640 --> 00:08:28,780 +الإسلام قد ظلم المرأة وجعلها على النصف من شهادة + +73 +00:08:29,910 --> 00:08:35,610 +الرجل في قوله تبارك وتعالى في سورة البقرة + +74 +00:08:35,610 --> 00:08:43,070 +واستشهدوا شهيدين من رجالكم فإن لم يكون رجلين فرجل + +75 +00:08:43,070 --> 00:08:50,730 +وامرأتان ممن ترضون من الشهداء أن تضل إحداهما فتذكر + +76 +00:08:50,730 --> 00:08:55,550 +إحداهما الأخرى أولا نقول وبالله التوفيق بأن هذه + +77 +00:08:55,550 --> 00:09:03,600 +الآية الكريمة لا علاقة لها بالجنس بمعنى لا علاقة + +78 +00:09:03,600 --> 00:09:12,460 +لها بكون الشخص ذكرا أم أنثى ثانيا أن هذه الآية + +79 +00:09:12,460 --> 00:09:22,630 +تتكلم عن أحكام المعاملات من بيع وشراء وتجارة و + +80 +00:09:22,630 --> 00:09:30,310 +دين وقرض ونحو ذلك وهذه الأمور إنما تكون غالبا + +81 +00:09:30,310 --> 00:09:38,850 +في حضرة الرجال ولا تكون في حضرة النساء فالمرأة + +82 +00:09:38,850 --> 00:09:46,420 +بسبب طبيعتها البيولوجية أو الفيزيولوجية بمعنى + +83 +00:09:46,420 --> 00:09:56,240 +وظائف الأعضاء قد تنسى وخاصة أنها تمر بالحمل وبعد + +84 +00:09:56,240 --> 00:10:02,280 +الحمل الوضع وبعد الوضع الرضاعة فهذا قد يؤثر على + +85 +00:10:02,280 --> 00:10:11,530 +شهادتها فتنسى فالقضية ليست احتقارا وليست امتهانا + +86 +00:10:11,530 --> 00:10:20,990 +وليست انتقاصا من كرامة المرأة وإنما حفاظا على حقوق + +87 +00:10:20,990 --> 00:10:28,830 +الناس لأننا لا نتكلم عن دراهم معدودة عن فلوس وقد + +88 +00:10:28,830 --> 00:10:32,930 +يكون العقد بملايين + +89 +00:10:32,930 --> 00:10:39,500 +مثلا الدنانير أو الدولارات وقد يكون عنارة كبيرة أو + +90 +00:10:39,500 --> 00:10:49,280 +يكون عقارا أو نحو ذلك فأراد الإسلام أن يتثبت من + +91 +00:10:49,280 --> 00:10:55,100 +أجل حقوق الناس والمرأة قد تنسى فيضم إليها أختها + +92 +00:10:55,100 --> 00:11:01,700 +يضم إليها امرأة أخرى من أجل أن تتذكر والضلال هنا + +93 +00:11:01,700 --> 00:11:09,980 +ليس بمعنى الضلال الديني الذي هو البعد عن شرع الله + +94 +00:11:09,980 --> 00:11:16,840 +إنما هو الضلال الدنيوي بمعنى النسيان وهذا معنى + +95 +00:11:16,840 --> 00:11:22,460 +قوله تبارك وتعالى أن تضل إحداهما بمعنى أن تنسى + +96 +00:11:22,460 --> 00:11:28,660 +إحداهما فتذكر إحداهما الأخرى فقد جاء الضلال مقابلة + +97 +00:11:28,660 --> 00:11:35,060 +التذكرفدل على أن الضلال هنا بمعنى النسيان وهذا + +98 +00:11:35,060 --> 00:11:42,340 +ثابت في لغة العرب إذا هكذا يرد على أعداء الإسلام + +99 +00:11:42,340 --> 00:11:52,320 +فقد خاب فألهم وطاش سهمهم نعم هذه من جهة الشهادة + +100 +00:11:52,320 --> 00:12:03,480 +أما من جهة الميراث فأيضا أبدأ كما بدأت في موضوع + +101 +00:12:03,480 --> 00:12:12,560 +الشهادات أبدأ بضرب أمثلة على أن الإسلام قد ساوى + +102 +00:12:12,560 --> 00:12:20,360 +بين الرجل والمرأة حتى في الميراث لأنه ليس في كل + +103 +00:12:20,360 --> 00:12:29,440 +الأحيان يكون الرجل على الضعف من المرأة بل قد تكون + +104 +00:12:29,440 --> 00:12:37,080 +المرأة أحيانا أوفر نصيبا من الرجل وهذا الموضوع نحن + +105 +00:12:37,080 --> 00:12:44,420 +في كلية الشريعة يحتاج منا إلى فصل كامل إلى شهور + +106 +00:12:44,420 --> 00:12:52,040 +أربعة والكتاب ضرب لنا مثالين اثنين نختصر عليهما + +107 +00:12:52,040 --> 00:12:58,320 + وإلا فالأمر يحتاج إلى فصل كامل في كلية الشريعة + +108 +00:12:58,320 --> 00:13:06,140 +والقانون في الجامعة الإسلامية فمثلا الإخوة لأم + +109 +00:13:06,140 --> 00:13:14,760 +وهذا هو معنى الآية وإن كان رجل يورث كلالة أو امرأة + +110 +00:13:14,760 --> 00:13:23,750 +وليس له أخ أو أخت وإن كان رجل يورث كلالة أو امرأة + +111 +00:13:23,750 --> 00:13:31,270 +وله أخ أو أخت فلكل واحد منهما السدس فإن كانوا أكثر + +112 +00:13:31,270 --> 00:13:37,130 +من ذلك فهم شركاء في السدس إذا نحن نتكلم في هذه + +113 +00:13:37,130 --> 00:13:44,170 +المسألة عن الإخوة لأم لأن الإخوة على أنواع ثلاثة + +114 +00:13:44,170 --> 00:13:51,120 +إما أن يكونوا إخوة أشقاء من أبوين وإما أن يكونوا + +115 +00:13:51,120 --> 00:14:01,700 +إخوة لأب ومن أم وإما أن يكونوا إخوة لأم نعم ففي + +116 +00:14:01,700 --> 00:14:08,820 +هذه الحال إذا مات شخص كلالة وما معنى الكلالة + +117 +00:14:08,820 --> 00:14:19,430 +الكلالة هي الشخص الذي ليس له أصل ولا فرع نعم ليس له + +118 +00:14:19,430 --> 00:14:29,750 +أصل ولا فرع ليس له أبوان وليس له فرع وارث كالأولاد + +119 +00:14:29,750 --> 00:14:39,230 +ففي هذه الحالة ورثه إخوته لأم فإن كان أخ وأخت فقط + +120 +00:14:39,230 --> 00:14:49,590 +فنصيبهما الثلث بمعنى أن يقتسم الثلث عليهما فيتساوى + +121 +00:14:49,590 --> 00:14:57,510 +الأخ والأخت يكون نصيب الأخ الثلث ونصيب الأخت الثلث + +122 +00:14:57,510 --> 00:15:06,490 +فإن كانوا أكثر من اثنين من أخ وأخت فإنهم يتقاسمون + +123 +00:15:06,490 --> 00:15:15,820 +الثلث بالسوية للذكر مثل حظ الأنثى هذا هو معنى + +124 +00:15:15,820 --> 00:15:21,600 +قوله تبارك وتعالى وإن كان رجل يورث كلالة أو امرأة + +125 +00:15:21,600 --> 00:15:31,200 +وله أخ أو أخت يعني فقط فهما يتقسمان الثلث فلكل + +126 +00:15:31,200 --> 00:15:35,980 +واحد منهما السدس نصف الثلث + +127 +00:15:38,720 --> 00:15:45,360 +فإن كانوا أكثر من ذلك فهم شركاء في الثلث والشركة + +128 +00:15:45,360 --> 00:15:53,880 +تفيد المساواة بمعنى أنهم يتقاسمون الثلث للذكر مثل + +129 +00:15:53,880 --> 00:15:59,120 +حظ الأنثى فنقول لهؤلاء الذين يزعمون بأن الإسلام قد + +130 +00:15:59,120 --> 00:16:03,000 +ظلم المرأة أين أنتم من هذه الآيات؟ لماذا لم + +131 +00:16:03,000 --> 00:16:09,010 +تستشدوها؟ واختصرتهم فقط على قوله تبارك وتعالى في + +132 +00:16:09,010 --> 00:16:15,010 +صدر هذا الباب يوصيكم الله في أولادكم للذكر مثل حظ + +133 +00:16:15,010 --> 00:16:20,190 +الأنثى هذه القاعدة العامة ولكن ليست في كل مسألة + +134 +00:16:20,190 --> 00:16:25,950 +المسألة الثانية في مساواة الرجل مع المرأة إذا مات + +135 +00:16:25,950 --> 00:16:35,110 +شخص وله أبوان وفرع وارث سواء من الذكور فقط أو من + +136 +00:16:35,110 --> 00:16:42,670 +الذكور والإناث فيكون نصيب الأبوين أيضًا الثلث + +137 +00:16:42,670 --> 00:16:50,450 +بالتساوي بينهما الأب يكون له الثلث والأم يكون لها + +138 +00:16:50,450 --> 00:16:57,570 +الثلث وهذا معنى قوله تبارك وتعالى ولأبويه لكل واحد + +139 +00:16:57,570 --> 00:17:03,610 +منهما السدس مما ترك إن كان له ولد يعني إن كان له + +140 +00:17:03,610 --> 00:17:14,750 +فرع وارث نعم إذا هذان مثالان يبيّنان أن المرأة + +141 +00:17:14,750 --> 00:17:20,470 +تساوت مع الرجل في الميراث وأما المثال الأول فهو + +142 +00:17:20,470 --> 00:17:28,570 +الإخوة لأم إذا ورثوا أخاهم الكلالة يعني الذي لم + +143 +00:17:28,570 --> 00:17:36,170 +ينجب وليس له أبوان على قيد الحياة وكذلك الأبو + +144 +00:17:36,170 --> 00:17:43,790 +والأم إذا مات لابنه وكان له فرع وارث فلكل واحد + +145 +00:17:43,790 --> 00:17:51,660 +منهما الثلث نعود إلى الآية الأولى وهي قوله تبارك + +146 +00:17:51,660 --> 00:17:57,760 +وتعالى يوصيكم الله في أولادكم للذكر مثل حظ + +147 +00:17:57,760 --> 00:18:07,840 +الأنثيين فنقول إن هذا هو قمة العدل لماذا؟ لأن + +148 +00:18:07,840 --> 00:18:16,920 +الرجل هو الذي يكلف بالنفقة ودفع المهر نحن تكلمنا + +149 +00:18:16,920 --> 00:18:25,080 +في مبحث سابق عن الحقوق الزوجية وتكلمنا عن حقوق + +150 +00:18:25,080 --> 00:18:35,400 +الزوجة الأربعة ومنها المهر والنفقة فالمهر يقوم + +151 +00:18:35,400 --> 00:18:43,520 +الزوج بدفعه للزوجة كاملا غير منقوص كما مر بنا قول + +152 +00:18:43,520 --> 00:18:50,220 +الله تبارك وتعالى وآتوا النساء صدقاتهن نحلة أي هبة + +153 +00:18:50,220 --> 00:18:56,140 +وعطية فإن طبن لكم عن شيء منه نفسا فكلوه هنيئا + +154 +00:18:56,140 --> 00:19:03,620 +مريئا وكذلك النفقته هي حق للزوجة على زوجها وقد مر + +155 +00:19:03,620 --> 00:19:08,690 +بنا قول الله تبارك وتعالى الرجال قوامون على النساء + +156 +00:19:08,690 --> 00:19:14,190 +بما فضّل الله بعضهم على بعض وبما أنفقوا من أموالهم + +157 +00:19:14,190 --> 00:19:19,190 +وقول الله تبارك وتعالى في سورة الطلاق لينفق ذو + +158 +00:19:19,190 --> 00:19:27,150 +سعة من ساعته وكذلك الأحاديث الشريفة التي بينت أن + +159 +00:19:27,150 --> 00:19:36,380 +النفقـة حق للزوجة على زوجها فإذا كان الزوج أو الأخ + +160 +00:19:36,380 --> 00:19:46,440 +مثلا مكلفا بدفع المهر وبالإنفاق على الزوجة والنفقة + +161 +00:19:46,440 --> 00:19:55,820 +كما تعلمون تشمل أمورا خمسة المسكن والملبس والمأكل + +162 +00:19:55,820 --> 00:20:02,810 +والتعليم والتطبيب علاج الزوجة والأولاد حتى قال + +163 +00:20:02,810 --> 00:20:10,650 +الفقهاء إن ولادة المرأة تدخل في النفقة أيضًا فنفقة + +164 +00:20:10,650 --> 00:20:16,750 +الولادة أيضًا على الزوج إذا أقول إذا كان ذلك كذلك + +165 +00:20:16,750 --> 00:20:23,130 +فوالله إنه لمن العدل ومن الإنصاف أن يكون الرجل على + +166 +00:20:23,130 --> 00:20:28,770 +الضعف من المرأة أو أن يكون الأخ على الضعف من أخته + +167 +00:20:30,490 --> 00:20:39,270 +والشيخ الصابوني رحمه الله في كتابه المواريث يضرب + +168 +00:20:39,270 --> 00:20:46,550 +لنا مثالا فيقول لو أن التركة كانت مثلا ثلاثة + +169 +00:20:46,550 --> 00:20:54,830 +آلاف دينار فماذا يكون نصيب الأخ؟ يكون نصيب الأخ + +170 +00:20:54,830 --> 00:20:59,490 +الألفين ويكون نصيب أخته الألف + +171 +00:21:02,500 --> 00:21:10,240 +فماذا تصنع هذه الأخت بالألف؟ إنها تحتفظ بها ولا + +172 +00:21:10,240 --> 00:21:18,160 +تطالب بشيء إلا إذا كانت هذه الألف نصابا للزكاة ومر + +173 +00:21:18,160 --> 00:21:28,200 +عليها الحول فتطالب بالزكاة أما هي فلا تطالب بشيء + +174 +00:21:28,200 --> 00:21:36,950 +مكفية المؤنة إن كانت صغيرة فنفقتها على أبيها وإن + +175 +00:21:36,950 --> 00:21:43,290 +كانت زوجة فنفقتها على زوجها وإن كانت أم فنفقتها + +176 +00:21:43,290 --> 00:21:52,530 +على ولدها أما أخوها الذي سيتزوج فإنه ماذا سيصنع؟ + +177 +00:21:52,530 --> 00:21:59,640 +أول ما يدفع إلا الألفين مهرا وهذا أضعف الإيمان اللي + +178 +00:21:59,640 --> 00:22:04,840 +لم يكن في هذه الأيام ثلاثة آلاف أو أربعة آلاف أو + +179 +00:22:04,840 --> 00:22:14,030 +حتى خمسة آلاف نعم إذا الزوجة احتفظت بالألف أو لو + +180 +00:22:14,030 --> 00:22:21,190 +جاءها مهر ألفان فصار الزوج مفلسا بلا شيء وأصبح + +181 +00:22:21,190 --> 00:22:28,990 +ثروة الزوجة 3000 دينار لكن الذين يقولون هذا إنما + +182 +00:22:28,990 --> 00:22:34,250 +هم من العلمانيين أو من المستشريقين أعداء الإسلام + +183 +00:22:34,250 --> 00:22:41,070 +والمسلمين الحاقدين الذين يقلدون الغرب تقليدا أعمى + +184 +00:22:41,710 --> 00:22:46,850 +فهناك الرجل في الغرب إذا مات عارف على المرأة قد + +185 +00:22:46,850 --> 00:22:51,650 +يدخل بها وقد ينجب حتى أطفالا دون أن يتوجه إلى + +186 +00:22:51,650 --> 00:22:58,730 +الكنيسة لعقد قرانه وبعد ذلك يتبنّاهم ولو بعد + +187 +00:22:58,730 --> 00:23:06,450 +خمسين عاما هذا ليس في الإسلام وبلا مهر وبلا نفقة + +188 +00:23:07,060 --> 00:23:13,980 +فالمرأة تعمل وتأكل وتلبس وتنفق على نفسها دون حاجة + +189 +00:23:13,980 --> 00:23:20,180 +إلى الزوج أما الإسلام فقد كلف الرجل واعتبر ذلك حقا + +190 +00:23:20,180 --> 00:23:27,540 +من حقوق الزوجة بأن يدفع عليها مهرا وأن ينفق عليها + +191 +00:23:27,540 --> 00:23:36,120 +فإن الزوجة لو كانت مليونيرة نعم كانت تملك الملايين + +192 +00:23:36,120 --> 00:23:44,600 +وتملك العقارات والعمارات وزوجها فقير لا يملك شيئا + +193 +00:23:44,600 --> 00:23:50,500 +لا تطالب الزوجة في هذه الحال بأن تنفق على زوجها + +194 +00:23:50,500 --> 00:23:59,660 +إلا ندبا واستحبابا أما المكلف بالإنفاق على الزوجة + +195 +00:23:59,660 --> 00:24:05,830 +وعلى الولد وعلى البيت هو الزوج حتى وإن كان فقيرا + +196 +00:24:05,830 --> 00:24:10,550 +وقد مرت بنا هذه المسألة عند الآية السابعة في سورة + +197 +00:24:10,550 --> 00:24:16,430 +الطلاق لينفق ذو سعة من ساعته وترتب على ذلك سؤال + +198 +00:24:16,430 --> 00:24:24,210 +مهم قد لا يخل منه امتحان وهو هل النفقة وفق حال + +199 +00:24:24,210 --> 00:24:30,610 +الزوج أم وفق حال الزوجة طبعا كان الجواب هناك أن + +200 +00:24:30,610 --> 00:24:38,790 +النفقة وفق حال الزوج يسرا وعسرا وهذا معنى قوله + +201 +00:24:38,790 --> 00:24:45,110 +تبارك وتعالى لينفق ذو سعة من ساعته ومن قدر عليه + +202 +00:24:45,110 --> 00:24:50,710 +رزقه فلينفق من ما أتاه الله لا يكلف الله نفسه إلا + +203 +00:24:50,710 --> 00:24:58,290 +ما أتاه سيجعل الله بعد عسر يسرا الصابوني هنا جاء + +204 +00:24:58,290 --> 00:25:08,590 +الحقيقة بأمور خمسة يا ليتنا نقرأها ونعود إليها في + +205 +00:25:08,590 --> 00:25:16,670 +الكتاب فهي انتصار للإسلام وأن المرأة لم تظلم بعد + +206 +00:25:16,670 --> 00:25:23,180 +وأن الإسلام لما جعل أخذها على ضعفها في الميراث + +207 +00:25:23,180 --> 00:25:29,360 +إنما هو قمة العدل والإنصاف وإليكم هذه الأمور + +208 +00:25:29,360 --> 00:25:36,300 +الخمسة أولا المرأة مكفية المؤنة والحاجة فنفقتها + +209 +00:25:36,300 --> 00:25:40,820 +واجبة على أبيها أو أخيها أو زوجها أو ابنها أو + +210 +00:25:40,820 --> 00:25:46,640 +غيرهم من الأقارب نعم صدق أن ذكرت ذلك ولكن الشيء + +211 +00:25:46,640 --> 00:25:53,970 +بالشيء يذكر ثانيا المرأة لا تكلف بالإنفاق على أحد + +212 +00:25:53,970 --> 00:25:59,310 +كما أسلفنا بخلاف الرجل فإنه مكلف بالإنفاق على + +213 +00:25:59,310 --> 00:26:08,170 +الأهل والأقرباء وغيرهم ممن تجب عليه نفقتهم ثالثا + +214 +00:26:08,170 --> 00:26:13,690 +نفقات الرجل أكثر وتصرفاته المالية أضخم فحاجته + +215 +00:26:13,690 --> 00:26:20,190 +إلى المال أكبر من حاجة المرأة أما رابعا فإن الرجل + +216 +00:26:20,190 --> 00:26:26,270 +أو الزوج يدفع مهرا للزوجة ويكلف بنفقة السكنى + +217 +00:26:26,270 --> 00:26:32,310 +والمطعم والملبس للزوجة والأولاد خامسا وأخيرا + +218 +00:26:32,310 --> 00:26:39,410 +أجور التعليم كذلك للأولاد وتكاليف العلاج والدواء + +219 +00:26:39,410 --> 00:26:45,250 +للزوجة والأولاد يدفعها الرجل دون المرأة حتى قلت كما + +220 +00:26:45,250 --> 00:26:52,110 +ذكر الفقهاء إن أجرة الولادة للقابلة تدخل في النفقة + +221 +00:26:52,740 --> 00:27:00,380 +ويكلف بها الزوج نعم بعد ذلك لم يبقى لهؤلاء دليل قل + +222 +00:27:00,380 --> 00:27:06,180 +هاتوا برهانكم إن كنتم صادقين ولكن أعمى الله بصرهم + +223 +00:27:06,180 --> 00:27:11,120 +وبصيرتهم وصدق الله العظيم فإنها لا تعمى الأبصار + +224 +00:27:11,120 --> 00:27:17,440 +ولكن تعمى القلوب التي في صدقهم وثالثا زعموا وبئس + +225 +00:27:17,440 --> 00:27:24,940 +ما زعموا بأن الإسلام قد ظلم المرأة ثالثا بأن حرمها + +226 +00:27:24,940 --> 00:27:31,200 +من الرئاسة ونحن نقول بأن هذا المنصب لا يليق + +227 +00:27:31,200 --> 00:27:40,300 +بالمرأة لأن هذا المنصب وهو منصب الرئاسة ليس كرسيا + +228 +00:27:40,300 --> 00:27:49,500 +تجلس عليه المرأة فقط وليس صورة للزينة وتوقيع + +229 +00:27:49,500 --> 00:27:59,050 +العهود والمواثيق وإنما الرئاسة قيادة المجتمع ورأسه + +230 +00:27:59,050 --> 00:28:05,050 +المفكر ووجهه البارز ولسانه الناطق وله صلاحيات + +231 +00:28:05,050 --> 00:28:12,290 +واسعة خطيرة الآثار والنتائج خاصة في حالة الحروب + +232 +00:28:12,290 --> 00:28:21,230 +والقتال ويترتب على ذلك إراقة الدماء أو قتل الرجال + +233 +00:28:21,230 --> 00:28:29,650 +والنساء والأطفال والمرأة عاطفية بطبعها فهذا يحتاج + +234 +00:28:29,650 --> 00:28:34,590 +إلى الرجال دون النساء والنبي عليه الصلاة والسلام + +235 +00:28:34,590 --> 00:28:42,390 +وهذا هو الدليل لما علم بموت كسرى وأن الفرصة قد + +236 +00:28:42,390 --> 00:28:48,910 +ولوا ابنته بعد موته قال عليه الصلاة والسلام في + +237 +00:28:48,910 --> 00:28:54,680 +الحديث الصحيح طبعا الذي رواه البخاري لن يفلح قوم + +238 +00:28:54,680 --> 00:29:04,500 +ولّو أمرهم امرأة فهذا هو الدليل على أن المرأة لا + +239 +00:29:04,500 --> 00:29:10,880 +تتولى رئاسة الدولة ولا ينبغي لها ولكن ليس هذا أن + +240 +00:29:10,880 --> 00:29:16,060 +تكون المرأة محرومة من الولاية إنما حديثنا عن + +241 +00:29:16,060 --> 00:29:22,260 +الولاية العظمى أو عن الخلافة أو رئاسة الدولة فقد + +242 +00:29:22,260 --> 00:29:32,220 +تكون ولية على صغارها بتصريف أموالهم وقد تكون شهادة + +243 +00:29:32,220 --> 00:29:38,820 +والشهادة ولاية كما نص الفقهاء على ذلك كما يجوز أن + +244 +00:29:38,820 --> 00:29:45,340 +تكون قاضية في الأموال كما ذهب فريق من أهل العلم + +245 +00:29:45,340 --> 00:29:50,800 +فهي ليست محرومة من جميع الولايات إنما هي محرومة من + +246 +00:29:50,800 --> 00:29:58,890 +الولاية العظمى من رئاسة الدولة بقى أن نذكر شيئا + +247 +00:29:58,890 --> 00:30:07,130 +لعلنا قد غفلنا عنه في باب الشهادات أنه كما قلنا + +248 +00:30:07,130 --> 00:30:13,970 +بأن شهادة الرجال لا تقبل فيما يخص النساء مثل + +249 +00:30:13,970 --> 00:30:19,990 +الولادة والنسب والثيوب والبكارة والأمراض + +250 +00:30:19,990 --> 00:30:27,050 +الداخلية كالجلدية مثلا وعيوب الجنسية وقولنا هذا من + +251 +00:30:27,050 --> 00:30:32,570 +اختصاص النساء دون الرجال كذلك نقول وهذه معلومة قد + +252 +00:30:32,570 --> 00:30:38,150 +مرت بها وتذكرتها الآن وهي أن شهادة النساء لا تقبل + +253 +00:30:38,150 --> 00:30:44,690 +في الحدود والعقوبات إنما تقبل فيها شهادة الرجال + +254 +00:30:44,690 --> 00:30:51,890 +فقط لأن هذه العقوبات كجريمة القتل أو مثلا جريمة + +255 +00:30:51,890 --> 00:30:58,560 +الزنا أو شرب الخمر أو السرقة غالبا لا تحضروها + +256 +00:30:58,560 --> 00:31:05,100 +النساء إنما يحضروها الرجال فلا تقبل فيها شهادة + +257 +00:31:05,100 --> 00:31:13,220 +النساء نعم أردت أن أذكر بذلك فاحفظوهم نعم بعد هذا + +258 +00:31:13,220 --> 00:31:17,940 +ننتقل إلى خامس من + +259 +00:31:22,620 --> 00:31:29,380 +أو قبل خامسا إلى رابعا من المبحث الخامس وهو عمل + +260 +00:31:29,380 --> 00:31:37,080 +المرأة ومثل عمل المرأة الاختلاط رابعا عمل المرأة + +261 +00:31:37,080 --> 00:31:45,140 +وخامسا الاختلاط وبهذا نكون بعد هذه العنوانين قد + +262 +00:31:45,140 --> 00:31:49,360 +انتهينا من الفصل الرابع وهو نظام الأسرة في + +263 +00:31:49,360 --> 00:31:56,600 +الإسلام نسأل أولا هذا السؤال ما حكم عمل المرأة هل + +264 +00:31:56,600 --> 00:32:08,720 +هو مباح بإطلاق أم هو حرام بإطلاق أم هو مباح بقيود + +265 +00:32:08,720 --> 00:32:14,120 +قبل ذي بدء نقول أن الجواب على هذا السؤال أن عمل + +266 +00:32:14,120 --> 00:32:23,950 +المرأة مباح بقيود وضوابط نعم، إذًا عمل المرأة ليس + +267 +00:32:23,950 --> 00:32:30,150 +حرامًا مطلقا وليس مباحا مطلقا إنما هو مباح + +268 +00:32:30,150 --> 00:32:37,950 +بظوابط وقيود والمرأة أحيانا قد تضطر إلى العمل + +269 +00:32:37,950 --> 00:32:43,950 +خارج البيت والأصل في المرأة أن تكون في بيتها وقرن + +270 +00:32:43,950 --> 00:32:49,970 +في بيوتنا ولا تبرجن تبرج الجاهلية الأولى لأن + +271 +00:32:49,970 --> 00:32:56,270 +المرأة تتعامل مع الرجال تتعامل مع البشر والآدمين + +272 +00:32:56,270 --> 00:33:03,730 +والمرأة خارج البيت تتعامل مع الآلة تتعامل مع + +273 +00:33:03,730 --> 00:33:12,910 +الماكينات والحديد فهو شاق عليها ومع ذلك أجاز لها + +274 +00:33:12,910 --> 00:33:19,860 +الإسلام أن تعمل عملا يليق بأنوثتها ويليق + +275 +00:33:19,860 --> 00:33:26,100 +بطبيعتها كأن تعمل طبيبة أو ممرضة أو قابلة أو معلمة + +276 +00:33:26,100 --> 00:33:35,300 +أو مربية أو حاضنة أطفال ففي هذه السن يفضلوا في سن + +277 +00:33:35,300 --> 00:33:40,500 +الحضانة أو البستان ونحو ذلك أن يكون المربي امرأة + +278 +00:33:40,970 --> 00:33:47,030 +هذه كلها أعمال ووظائف تليق بالمرأة وعلمت أنه في + +279 +00:33:47,030 --> 00:33:55,870 +الغرب المرأة تعمل أعمال شاقة كالصياغة والبناء وحتى + +280 +00:33:55,870 --> 00:34:01,320 +في روسيا علمت أنها تعمل في إزالة الثلوج كما أخبرني + +281 +00:34:01,320 --> 00:34:06,540 +الطلاب الدارسون هناك من الشوارع والطرقات وهذا كله + +282 +00:34:06,540 --> 00:34:13,740 +عمل خشن لا يليق بما فطر الله به عليه المرأة ولكنها + +283 +00:34:13,740 --> 00:34:19,160 +قد تعمل وقد تكون مضطرة لخدمة أطفالها مثلا إن كانت + +284 +00:34:19,160 --> 00:34:24,200 +أرملة لزوجها لها أو كان لها مثلا أبوان شيخان + +285 +00:34:24,200 --> 00:34:31,400 +كبيران كما في قصة موسى مع بنتي الرجل الصالح في + +286 +00:34:31,400 --> 00:34:38,420 +صورة القصص وفي مدينة كما قال الله تبارك وتعالى + +287 +00:34:38,420 --> 00:34:43,260 +ولمّا ورد ماء مدينة وجد عليه أمة من الناس يسكنون + +288 +00:34:43,260 --> 00:34:49,120 +ووجد من دونهم امرأتين تسقيان قال ما خطبكما قالت لا + +289 +00:34:49,120 --> 00:34:55,540 +نسقي حتى يُسقى الرعاء وأبونا شيخ كبير فشيخوخة الأب + +290 +00:34:55,540 --> 00:35:04,530 +وكبر سنه جعلت هتين البنتين أن تخرجا من أجل رعي + +291 +00:35:04,530 --> 00:35:12,350 +الأغنام ورعاية الأغنام لكن إذا قلنا بأن عمل المرأة + +292 +00:35:12,350 --> 00:35:19,890 +مباح بقيود وضوابط ما هذه الضوابط؟ هذه الضوابط ثلاثة + +293 +00:35:19,890 --> 00:35:27,800 +أولها أن يكون العمل في حد ذاته مشروعاً حلالاً قد + +294 +00:35:27,800 --> 00:35:34,410 +أقره الله وقد أقره رسول الله صلى الله عليه وسلم كما + +295 +00:35:34,410 --> 00:35:42,590 +ضربنا أمثلة لا تتعارض مع القرآن والسنة والشريعة + +296 +00:35:42,590 --> 00:35:47,910 +الإسلامية كأن تعمل طبيبة أو ممرضة أو قابلة أو تعمل + +297 +00:35:47,910 --> 00:35:56,210 +معلمة نعم للبنات أو في الحضانة والروضة ونحو ذلك + +298 +00:35:56,210 --> 00:36:02,910 +كما نرى في مراحل التعليم أما إذا كان العمل حراماً + +299 +00:36:03,780 --> 00:36:11,780 +فهذا لا يجوز لها العمل به أبداً كالتي تعمل خادمة + +300 +00:36:11,780 --> 00:36:18,580 +لرجل أعزب أو سكرتيرة خاصة لمدير تقتضي وظيفتها أن + +301 +00:36:18,580 --> 00:36:24,240 +يخلو بها وتخلو به وهذا سنأتي إليه عند الحديث عن + +302 +00:36:24,240 --> 00:36:28,960 +الاختلاط لا يخلون رجل بامرأة إلا وكان الشيطان + +303 +00:36:28,960 --> 00:36:35,990 +ثالثاً أو تعمل راقصة تُثير الشهوات والغرائز أو + +304 +00:36:35,990 --> 00:36:42,630 +عاملة في بار تقدم الخمور والمسكرات أو مضيفة في + +305 +00:36:42,630 --> 00:36:48,750 +طائرة يجب عليها عملها تقديم المسكرات والسفر البعيد + +306 +00:36:48,750 --> 00:36:55,330 +بغير محرم بما يلزمه من المبيت وحدها في بلاد أو في + +307 +00:36:55,330 --> 00:37:01,760 +بلاد الغربة أو غير ذلك من الأعمال أول هذه الضوابط + +308 +00:37:01,760 --> 00:37:07,890 +والقيود التي تبيح عمل المرأة أن يكون العمل في حد + +309 +00:37:07,890 --> 00:37:13,970 +ذاته مشروعاً فإن كان حراماً فلا يصح لها أن تعمل + +310 +00:37:13,970 --> 00:37:20,190 +ثانياً أن تلتزم آداب المرأة المسلمة التي قررتها + +311 +00:37:20,190 --> 00:37:25,150 +الشريعة الإسلامية وسنأتي بعد ذلك بعد قليل عند + +312 +00:37:25,150 --> 00:37:31,530 +الحديث عن الاختلاط إلى هذا بشيء من التفصيل من جهة + +313 +00:37:31,530 --> 00:37:38,080 +النظر ومن جهة اللباس ومن جهة الكلام ومن جهة + +314 +00:37:38,080 --> 00:37:43,720 +المشي كله سنأتي إليه بعد قليل وسنأتي بالآيات إن + +315 +00:37:43,720 --> 00:37:47,820 +شاء الله تبارك وتعالى أما ثالثاً من الضوابط و + +316 +00:37:47,820 --> 00:37:53,180 +القيود التي تجعل عمل المرأة مباحاً أن لا يكون عملها + +317 +00:37:53,180 --> 00:38:00,200 +على حساب واجبات أخرى لا يجوز لها إهمالها لأننا قد + +318 +00:38:00,200 --> 00:38:05,780 +تكلمنا أن مهمة المرأة الأصلية هو أن تقرّ في بيتها + +319 +00:38:05,780 --> 00:38:14,590 +لتربية أطفالها وتنشئتهم التنشئة الصحيحة وخدمة زوجها + +320 +00:38:14,590 --> 00:38:21,690 +نعم ولكن لها أن تعمل إذا كان عملها لا يتعارض مع + +321 +00:38:21,690 --> 00:38:28,170 +واجبات أخرى كواجباتها نحو زوجها وأولادها وهو + +322 +00:38:28,170 --> 00:38:34,710 +واجبها الأول وعملها الأساسي كما أسلفنا وكما تلاونا + +323 +00:38:34,710 --> 00:38:39,710 +قول الله تبارك وتعالى وقرن في بيوتكن ولا تبرجن + +324 +00:38:39,710 --> 00:38:45,330 +تبرج الجاهلية الآن خامساً من المبحث الخامس من الفصل + +325 +00:38:45,330 --> 00:38:53,090 +الرابع نظام الأسرة في الإسلام وهذا آخر مبحث في + +326 +00:38:53,090 --> 00:38:59,460 +نظام الأسرة في الإسلام وبعدها ننتقل إلى الفصل + +327 +00:38:59,460 --> 00:39:04,960 +السادس النظام السياسي ولنا عنده وقفة ما المطلوب + +328 +00:39:04,960 --> 00:39:09,840 +وغير المطلوب في الامتحان طبعاً نحن انتقلنا من الفصل + +329 +00:39:09,840 --> 00:39:15,140 +الرابع إلى الفصل السادس فأين الفصل الخامس وهو + +330 +00:39:15,140 --> 00:39:19,560 +النظام الاقتصادي؟ لقد تكلمنا أكثر من مرة لمن لم + +331 +00:39:19,560 --> 00:39:27,240 +يحضر أو لم يقرأ الـmodel أن هناك فصلين نعم مُشتَمَلٌ + +332 +00:39:27,240 --> 00:39:32,040 +بيني من المنهج بالكلية الفصل الأول وهو العقيدة + +333 +00:39:32,040 --> 00:39:40,700 +لأنه سيُدرس لكم في مساقٍ مستقل شرح أصول العقيدة + +334 +00:39:40,700 --> 00:39:46,780 +للدكتور نسيم شحدة ياسين وأما الفصل الخامس وهو + +335 +00:39:46,780 --> 00:39:54,880 +نظام الاقتصاد نعم سيُدرس لكم في مساقٍ مستقل النظام + +336 +00:39:54,880 --> 00:40:01,200 +الاقتصادي في الإسلام نعم للأخوين الشقيقين محمد + +337 +00:40:01,200 --> 00:40:07,120 +إبراهيم مقداد وأخيه الدكتور زياد إبراهيم مقداد + +338 +00:40:07,120 --> 00:40:12,940 +فليس مطلوبا في هذا الفصل أما خامساً المرأة والاختلاط + +339 +00:40:12,940 --> 00:40:19,640 +فكما قلنا في عمل المرأة نقول في الاختلاط فما حكم + +340 +00:40:19,640 --> 00:40:25,920 +الاختلاط؟ هل هو محرم بالكلية؟ هل هو مباح بالكلية؟ + +341 +00:40:25,920 --> 00:40:30,760 +لا هذا ولا ذاك الاختلاط مثل عمل المرأة تماماً مباح + +342 +00:40:30,760 --> 00:40:39,840 +ولكن كما قلنا بشروط أو بقيود وضوابط ما هذه القيود + +343 +00:40:39,840 --> 00:40:44,200 +والضوابط؟ إنها ستة أولاً + +344 +00:40:46,740 --> 00:40:55,500 +الالتزام بغض البصر من الجنسين فلا ينظر إلى عورة + +345 +00:40:55,500 --> 00:41:03,060 +ولا ينظر بشهوة ولا يطيل النظر في غير حاجة قال الله + +346 +00:41:03,060 --> 00:41:08,220 +تبارك وتعالى قل للمؤمنين يغضوا من أبصارهم ويحفظوا + +347 +00:41:08,220 --> 00:41:14,850 +فروجهم ذلك أزكى لهم إن الله خبير بما يصنعون وكل + +348 +00:41:14,850 --> 00:41:22,170 +المؤمنات يغضضن من أبصارهم ويحفظن فروجهم إذا غضّوا + +349 +00:41:22,170 --> 00:41:30,290 +النظر والبصر من الطرفين أول هذه القيود ماذا نلحظ في + +350 +00:41:30,290 --> 00:41:35,430 +هذه الآية؟ نلحظ في هذه الآية أن الله قدّم غضّ + +351 +00:41:35,430 --> 00:41:40,390 +البصري على حفظ الفرج قل للمؤمنين يغضوا من أبصارهم + +352 +00:41:40,390 --> 00:41:45,450 +ويحفظوا فروجهم وكل المؤمنات يغضضن من أبصارهم + +353 +00:41:45,450 --> 00:41:53,690 +ويحفظن فروجهم لماذا؟ لأن النظر هو بريد الشيطان + +354 +00:41:53,690 --> 00:42:03,560 +إلى الذنوب هو سفير الحرام فلولا النظر ولولا إنعام + +355 +00:42:03,560 --> 00:42:11,200 +البصر في العورات والثياب لما كانت الفاحشة وما + +356 +00:42:11,200 --> 00:42:18,320 +كانت جريمة الذنب حتى قال الشاعر قديماً كل الحوادث + +357 +00:42:18,320 --> 00:42:27,310 +مبدأها من النظر ومعظم النار من مستصغر الشرّ كم من + +358 +00:42:27,310 --> 00:42:32,910 +نظرة فتكت في قلب صاحبها فتك السهام بلا قوس ولا وتر + +359 +00:42:32,910 --> 00:42:38,910 +والمرء مادام ذا عينين يقلبها في أعين الغيد موقوف على + +360 +00:42:38,910 --> 00:42:46,130 +الخطر نعم موقوف على الخطر والشاعر حديثاً وهو أحمد + +361 +00:42:46,130 --> 00:42:51,710 +شوقي أمير الشعراء قال نظرة فابتسامة فسلام فكلام + +362 +00:42:51,710 --> 00:42:59,370 +فموعد فلقاء فهذا دليل على خطورة إنعام النظر أو + +363 +00:42:59,370 --> 00:43:06,530 +النظر بشهوة إلى عورة المرأة ثانياً من الضوابط + +364 +00:43:06,530 --> 00:43:12,410 +والقيود التزام المرأة باللباس الشرعي وهو اللباس + +365 +00:43:12,410 --> 00:43:18,990 +المحتشم الذي يغطي البدن ما عدا الوجه والكفين على + +366 +00:43:18,990 --> 00:43:26,900 +مذهب الجمهور خلافا للإمام أحمد ولا يشف ولا يصف قال + +367 +00:43:26,900 --> 00:43:29,940 +تعالى ولا يُبدين زينتهن إلا ما + +368 +00:43:29,940 --> 00:43:33,420 +ظهر منها إلا ما ظهر منها على مذهب + +369 +00:43:33,420 --> 00:43:40,140 +الجمهور على الحنابلة الوجه والكفان وليضربن بخمرهن + +370 +00:43:40,140 --> 00:43:48,000 +على جيوبهن الخمر جمع خمار وهو غطاء الرأس والجيوب + +371 +00:43:48,000 --> 00:43:56,170 +جمع جيب وهو فتحة الصدر وليست الجيب التي توضع فيها + +372 +00:43:56,170 --> 00:44:01,970 +الفلوس كما هو في أيامنا هذه إنما الجيب هو فتحة + +373 +00:44:01,970 --> 00:44:10,270 +الصدر فلابد أن يتدل الحجاب على صدر المرأة حتى + +374 +00:44:10,270 --> 00:44:17,710 +يُغطي فتحة الرقبة وليضربن بخمرهن على جيوبهن + +375 +00:44:17,710 --> 00:44:27,310 +والخمار من الفعل خَمَرَ بمعنى ستر ومنه صميت الخمرة + +376 +00:44:27,310 --> 00:44:34,790 +خمرة لأنها تستر العقل وكذلك صمي الخمار خماراً لأنه + +377 +00:44:34,790 --> 00:44:42,610 +يستر الرأس أو يغطي الرأس وفتحة الصدر هذا معنى قوله + +378 +00:44:42,610 --> 00:44:49,640 +تبارك الله تعالى أعلى وأعلى وأعلم وليضربن بخمرهن على + +379 +00:44:49,640 --> 00:44:56,520 +جيوبهن وكذلك الجلباب الطويل الذي يغطي البدن حتى + +380 +00:44:56,520 --> 00:45:01,780 +القدمين أي نعم يا أيها النبي قل لأزواجك وبنتك ونساء + +381 +00:45:01,780 --> 00:45:07,180 +المؤمنين يدنين عليهن من جلابيبهن ذلك أدنى أي + +382 +00:45:07,180 --> 00:45:14,900 +عرفنا فلا يُؤذين نعم لأن الذي يفرق المرأة العفيفة + +383 +00:45:14,900 --> 00:45:22,730 +من المرأة السافرة هو الجلباب فالمرأة السافرة هي + +384 +00:45:22,730 --> 00:45:29,530 +التي تتعرض للمشاكسة والمعاكسة من الساقطين على + +385 +00:45:29,530 --> 00:45:35,010 +قارعة الطريق أما العفيفة المحجبة المجلببة فلا + +386 +00:45:35,010 --> 00:45:40,970 +يستطيع أحد أن يؤذيها أو أن يتعرض لها بكلام ونحو + +387 +00:45:40,970 --> 00:45:49,720 +ذلك ثالثاً الالتزام بأدب المسلمة في كل شيء وخصوصا في + +388 +00:45:49,720 --> 00:45:56,180 +التعامل مع الرجال لأن المؤسسات الحكومية كالوزارات + +389 +00:45:56,180 --> 00:46:01,880 +ونحو ذلك لا تخلو منها النساء فقد يكون الرجال + +390 +00:46:01,880 --> 00:46:09,240 +والنساء في صالة واحدة فلابد هنا أن تلتزم آداب + +391 +00:46:09,240 --> 00:46:16,800 +الإسلام أولاً في كلامها بحيث يكون بعيدا عن الإغراء + +392 +00:46:16,800 --> 00:46:24,120 +والإثارة فقد قال تعالى فلا تخضعن بالقول فيطمع الذي + +393 +00:46:24,120 --> 00:46:29,680 +في قلبه مرض وقولنا قولا معروفاً وهنا نقول هل صوت + +394 +00:46:29,680 --> 00:46:35,760 +المرأة عورة؟ طبعاً ليس صوت المرأة عورة وهذا ما عليه + +395 +00:46:35,760 --> 00:46:44,600 +الأكثرون من أهل العلم الصوت المرأة ليس بعورة إلا إذا + +396 +00:46:44,600 --> 00:46:53,740 +كان فيه شهوة أو إغراء وإثارة ولذلك تمنع المرأة من + +397 +00:46:53,740 --> 00:47:00,990 +الأذان لما فيه من إثارة الرجال ولكن المرأة لا + +398 +00:47:00,990 --> 00:47:08,310 +تستغني عن الكلام أبداً ولكن كلاماً عادياً دون تصنع + +399 +00:47:08,310 --> 00:47:15,030 +أبداً فهي تتكلم مع الطبيب وتصف ألمها أو وجعها تتكلم + +400 +00:47:15,030 --> 00:47:24,770 +مع المفتي أو القاضي أو المعلم في الفصل من أجل مسألة + +401 +00:47:24,770 --> 00:47:35,210 +أو شيء جهلته وتتكلم في السوق نعم من أجل الشراء أو + +402 +00:47:35,210 --> 00:47:40,770 +حتى من أجل البيع لأن المرأة لها ذمة مالية في + +403 +00:47:40,770 --> 00:47:46,940 +الإسلام نعم وهكذا لا نستطيع أن نقول بأن صوت المرأة + +404 +00:47:46,940 --> 00:47:52,880 +عورة ولكن العورة هو ما سبق أن ذكرناه لما فيه من + +405 +00:47:52,880 --> 00:47:57,980 +الإغراء والإثارة ولذلك قال الله تعالى فلا تخضعن + +406 +00:47:57,980 --> 00:48:04,300 +بالقول إذاً الممنوع هو الخضوع بالقول فقط وليس مجرد + +407 +00:48:04,300 --> 00:48:09,790 +الكلام كذلك في المشي كما قال الله تبارك وتعالى + +408 +00:48:09,790 --> 00:48:13,390 +ولا يضربن بأرجلهن ليُعلم ما + +409 +00:48:13,390 --> 00:48:17,870 +يُخفين من زينتهن لأن المرأة كانت تلبس + +410 +00:48:17,870 --> 00:48:27,030 +خلخالا وتضرب الأرض برجلها فيجري الفساق خلفها نعم + +411 +00:48:27,030 --> 00:48:35,080 +وكذلك اليوم الكعب الذي فيه حديد ونحن نقول يا ليت + +412 +00:48:35,080 --> 00:48:40,740 +أحذية النساء تكون بعيدة عن هذا الحديد الذي يحدث + +413 +00:48:40,740 --> 00:48:45,800 +صوتاً عند المشي على البلاط أو الإسفلت ونحو ذلك فهو + +414 +00:48:45,800 --> 00:48:51,580 +أيضاً لفت للأنظار وإثارة للرجال ولعلنا تكلمنا قبل + +415 +00:48:51,580 --> 00:48:58,070 +قليل عن قصة ابنتي الرجل الصالح ولا أقول ابنتي شعيب + +416 +00:48:58,070 --> 00:49:01,690 +لأنه لم يثبت أن هذا الرجل الصالح في عهد موسى هو + +417 +00:49:01,690 --> 00:49:06,690 +النبي شعيب وإن كان شعيب في مدينة كان يوماً من + +418 +00:49:06,690 --> 00:49:12,270 +الأيام وإلى مدينة أخاهم شعيب ولكن لم يثبت أن صاحب + +419 +00:49:12,270 --> 00:49:16,490 +موسى هو شعيب عليه السلام ولذلك نقول ابنتي الرجل + +420 +00:49:16,490 --> 00:49:25,070 +الصالح كيف جاءته بأدب وحياء كما وصف القرآن الكريم + +421 +00:49:25,070 --> 00:49:30,330 +فجاءته إحداهن تمشي على استحياء قالت هذا هو الأدب + +422 +00:49:30,330 --> 00:49:38,920 +المرأة وكذلك في الحركة فلا تتكثّر ولا تتميل ولا يصدر + +423 +00:49:38,920 --> 00:49:43,600 +عنها ما يجعلها من صنف المتبرّجات تبرج الجاهلية + +424 +00:49:43,600 --> 00:49:51,540 +الأولى أو حتى الأخيرة وهذا ما نبه عليه صلى الله + +425 +00:49:51,540 --> 00:50:01,180 +عليه وسلم في آخر الزمان نساء متبرّجات سافرات عاريات + +426 +00:50:01,180 --> 00:50:08,760 +مائلات مميلات لقلوب الشباب نعم هذا كله لا يليق ولا + +427 +00:50:08,760 --> 00:50:13,720 +ينبغي بأخلاق المرأة المسلمة بل تمشي مشيًا عاديًا دون + +428 +00:50:13,720 --> 00:50:21,360 +تكثّر ودون تمايل ودون ما يصدر عنها مما يَلفت أنظار + +429 +00:50:21,360 --> 00:50:27,730 +الرجال إليها رابعًا أن تتجنب كل ما شأنه أن يثير + +430 +00:50:27,730 --> 00:50:33,050 +ويغري من الروائح العطرية وألوان الزينة التي ينبغي + +431 +00:50:33,050 --> 00:50:37,750 +أن تكون للبيت لا للطريق ولا للقاء مع الرجال + +432 +00:50:37,750 --> 00:50:44,290 +فالمرأة تتعطر وتتزين وتلبس أجمل ما عندها ولكن في + +433 +00:50:44,290 --> 00:50:50,810 +بيتها لزوجها أما إذا ذهبت إلى السوق وإلى المشفى + +434 +00:50:50,810 --> 00:50:58,450 +وإلى الشارع فلا يليق هذا بل إن الملائكة تلعنها فإن + +435 +00:50:58,450 --> 00:51:03,850 +الشيطان يستشرفها إذا خرجت كما جاء في الأثر المرأة + +436 +00:51:03,850 --> 00:51:10,870 +متزينة متعطرة فإنها زانية وكل عين تنظر إليها زانية + +437 +00:51:10,870 --> 00:51:15,130 +بل أمرها أبو غريرة رضي الله عنه أن تعود إلى البيت + +438 +00:51:15,130 --> 00:51:22,850 +وأن تغتسل غسلة الجنابة نعم أما خامسًا من الضوابط + +439 +00:51:22,850 --> 00:51:29,870 +والقيود لإباحة الاختلاط احذروا من أن يختلي الرجل + +440 +00:51:29,870 --> 00:51:37,550 +بامرأة وليس معهما محرم نعم حتى إذا ذهبت إلى الطبيب + +441 +00:51:37,550 --> 00:51:43,660 +لا يجوز للمرأة أن تذهب إلى الطبيب وحدها وأن تخلو به + +442 +00:51:43,660 --> 00:51:48,800 +وأن يخلو بها فلابد أن يكون محرم كزوج أو أب أو ابن + +443 +00:51:48,800 --> 00:51:58,140 +أو أم أو أخت أو بنت ونحو ذلك نعم ما خلى رجل بامرأة + +444 +00:51:58,140 --> 00:52:04,340 +إلا وكان الشيطان ثالثهما هكذا يقول المعصوم صلى + +445 +00:52:04,340 --> 00:52:08,580 +الله عليه وسلم الذي لا ينطق عن الهوى ويقول عليه + +446 +00:52:08,580 --> 00:52:13,860 +الصلاة والسلام إياكم والدخول على النساء قالوا يا + +447 +00:52:13,860 --> 00:52:19,190 +رسول الله رأيت الحمو؟ الحمو هو قريب الزوجة ابن عمها + +448 +00:52:19,190 --> 00:52:23,770 +ابن خالها يأتي في غياب الزوج هل موجود أبو محمد + +449 +00:52:23,770 --> 00:52:28,890 +فتقول له لا إنه في العمل ولكن أدخل حتى يأتي وقد + +450 +00:52:28,890 --> 00:52:35,310 +يطول غياب الزوج فتصنع له القهوة والشاي والطعام وما + +451 +00:52:35,310 --> 00:52:41,410 +هو عمل الشيطان إلا الوسوسة فتكون المعصية وقد يأتي + +452 +00:52:41,410 --> 00:52:45,810 +الزوج وهذا الرجل في حال مشبوه + +453 +00:52:47,710 --> 00:52:53,770 +فتصور حميته وغيرته فيحمل السلاح ويقتل هذا الرجل + +454 +00:52:53,770 --> 00:52:59,130 +وتكون الدماء ليس بين شخصين بل بين قبيلتين أو + +455 +00:52:59,130 --> 00:53:03,670 +عائلتين كبيرتين هذا معنى قوله عليه الصلاة والسلام + +456 +00:53:03,670 --> 00:53:10,590 +أعلى وأعلم قالوا أرأيت الحمو؟ قال الحمو الموت أو هو + +457 +00:53:10,590 --> 00:53:16,290 +سبب الهلاك لأنه قد يجلس نعم ويطيل الجلوس وفي هذا + +458 +00:53:16,290 --> 00:53:23,110 +خطر شديد ومقالة إلى المعصية أو الفحشة فالحذر من + +459 +00:53:23,110 --> 00:53:28,070 +خلوة الرجل بالمرأة كأن تكون سكرتيرة مثلًا وليس + +460 +00:53:28,070 --> 00:53:34,470 +معهما محرم أما سادسًا وأخيرًا من الضوابط الستة التي + +461 +00:53:34,470 --> 00:53:38,810 +تبيح الاختلاط بين الرجال والنساء أن يكون اللقاء في + +462 +00:53:38,810 --> 00:53:45,710 +حدود ما تفرضه الحاجة وما يقتضيه العمل المشترك دون + +463 +00:53:45,710 --> 00:53:52,630 +إسراف أو توسع يخرج المرأة عن فطرتها الأنثوية أو أن + +464 +00:53:52,630 --> 00:53:58,550 +يعرضها للقيل والقال أو يعطلها عن واجبها المقدس في + +465 +00:53:58,550 --> 00:54:05,760 +رعاية البيت وتربيته الأجوان نعم أن يكون الحديث + +466 +00:54:05,760 --> 00:54:14,060 +مقتصرًا على العمل وليس في مواضيع أخرى كأن يشكو لها + +467 +00:54:14,060 --> 00:54:20,260 +خلق زوجته أو تشكو له خلق زوجها هذا كله لا يليق ولا + +468 +00:54:20,260 --> 00:54:25,160 +ينبغي ونحن عندنا من القصص والأمثلة ليس لنا أن + +469 +00:54:25,160 --> 00:54:30,890 +نذكرها في هذه المحاضرات ولكن أقول نجم عن التوسع في + +470 +00:54:30,890 --> 00:54:38,890 +الحديث الطلاق هو يطلق زوجته وهي تطلق زوجها وتعطيَه + +471 +00:54:38,890 --> 00:54:44,570 +المال الكثير وأقول هذا زواج فاشل وجنين ميت نعم + +472 +00:54:44,570 --> 00:54:50,770 +بقى لنا أخيرًا إجازة الإسلام للمرأة أن تجتمع مع + +473 +00:54:50,770 --> 00:54:58,030 +الرجال في أمور أربعة أولاً العبادة فلها أن تصلي + +474 +00:54:58,030 --> 00:55:05,410 +جماعة في المسجد واليوم النساء لهن مكان خاص كبدروم + +475 +00:55:05,410 --> 00:55:13,590 +أسفل المسجد أو مثلًا في صدة المسجد ولكن في عهد + +476 +00:55:13,590 --> 00:55:17,430 +النبي عليه السلام كانت المرأة تصلي خلف الرجال + +477 +00:55:17,430 --> 00:55:23,140 +مباشرة ولذلك قال عليه الصلاة والسلام خير صفوف + +478 +00:55:23,140 --> 00:55:28,760 +النساء آخرها لماذا لبعدها عن الرجال وشر صفوف + +479 +00:55:28,760 --> 00:55:35,280 +النساء أولها لماذا لقربها من الرجال ولكن لا يجوز + +480 +00:55:35,280 --> 00:55:39,400 +لنا أبدًا أن نمنع المرأة من الصلاة في المسجد وقد + +481 +00:55:39,400 --> 00:55:43,740 +قال عليه الصلاة والسلام لا تمنعوا إماء الله مساجد + +482 +00:55:43,740 --> 00:55:50,150 +الله ثانيًا العلم وقد تكلمنا عن مكانة المرأة في + +483 +00:55:50,150 --> 00:55:55,810 +الإسلام وأن الإسلام دعا إلى تعليمها ورجل كانت عنده + +484 +00:55:55,810 --> 00:56:05,930 +أمة فأعتقها وعلمها وتزوجها والعلم فريضة على كل مسلم + +485 +00:56:05,930 --> 00:56:11,670 +بمعنى على كل من أسلم من الرجال والنساء ويمكن هنا + +486 +00:56:11,670 --> 00:56:18,760 +أن يضاف هذا الحديث ثالثًا للدلالة على مشروعية تعليم + +487 +00:56:18,760 --> 00:56:24,120 +المرأة فقد جاءت المرأة إلى الرسول عليه الصلاة + +488 +00:56:24,120 --> 00:56:30,320 +والسلام وقالت يا رسول الله غلبنا عليك الرجال اجعل + +489 +00:56:30,320 --> 00:56:36,940 +لنا يومًا من نفسك فوعدهن يومًا لقيهن فيه فوعدهن + +490 +00:56:36,940 --> 00:56:43,990 +وأمرهن فكان في مقال له إن ما من كل امرأة تقدم ثلاثة + +491 +00:56:43,990 --> 00:56:49,170 +من ولدها يعني يموتون في حياتها إلا كان لها حجاب من + +492 +00:56:49,170 --> 00:56:54,890 +النار فقال ثلاثة واثنين فقال واثنين فهذا الحديث + +493 +00:56:54,890 --> 00:57:03,200 +دليل على مشروعية تعليم المرأة في الإسلام ثالثًا ميدان + +494 +00:57:03,200 --> 00:57:09,360 +الجهاد فالمرأة أيضًا تجاهد إما بنفسها وإما بعلمها + +495 +00:57:09,360 --> 00:57:15,950 +كأن تكون طبيبة وعندنا في غزوة أحد كانت رفايدة + +496 +00:57:15,950 --> 00:57:21,530 +الأسلمية أول ممرضة في الإسلام تعالج الرجال وأم + +497 +00:57:21,530 --> 00:57:27,630 +سلمة في غزوة أحد قتلت مشركًا بعمود الخيمة وأم + +498 +00:57:27,630 --> 00:57:37,820 +عمرة نعم قاتلت وجاهدت وانتصرت ونزل فيها وفي + +499 +00:57:37,820 --> 00:57:42,320 +المسلمين من المؤمنين رجال صدقوا ما عاهدوا الله + +500 +00:57:42,320 --> 00:57:47,360 +عليه فمنهم من قضى نحبه ومنهم من ينتظر وما بدلوا + +501 +00:57:47,360 --> 00:57:54,040 +تبديلاً والرجال في هذه الآية ليس بمعنى الذكورة 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"probability": 0.903076171875}, {"start": 1525.45, "end": 1525.89, "word": " والعياذ", "probability": 0.7950439453125}, {"start": 1525.89, "end": 1526.29, "word": " بالله", "probability": 0.979736328125}, {"start": 1526.29, "end": 1527.63, "word": " فهذه", "probability": 0.9130859375}, {"start": 1527.63, "end": 1528.01, "word": " الآية", "probability": 0.9010416666666666}, {"start": 1528.01, "end": 1528.49, "word": " تصلح", "probability": 0.97607421875}, {"start": 1528.49, "end": 1528.97, "word": " مثالا", "probability": 0.7845052083333334}, {"start": 1528.97, "end": 1529.59, "word": " هناك", "probability": 0.962158203125}, {"start": 1529.59, "end": 1530.11, "word": " إن", "probability": 0.460693359375}, {"start": 1530.11, "end": 1530.93, "word": " المنافقين", "probability": 0.98837890625}, {"start": 1530.93, "end": 1531.09, "word": " في", "probability": 0.97607421875}, {"start": 1531.09, "end": 1531.45, "word": " الدرك", "probability": 0.7801106770833334}, {"start": 1531.45, "end": 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1546.51, "end": 1547.79, "word": " وسوف", "probability": 0.74365234375}, {"start": 1547.79, "end": 1548.33, "word": " يؤتي", "probability": 0.7197265625}, {"start": 1548.33, "end": 1548.77, "word": " الله", "probability": 0.9541015625}, {"start": 1548.77, "end": 1549.41, "word": " المؤمنين", "probability": 0.9879150390625}, {"start": 1549.41, "end": 1549.83, "word": " أجرا", "probability": 0.9783528645833334}, {"start": 1549.83, "end": 1550.77, "word": " عظيمة", "probability": 0.833984375}, {"start": 1550.77, "end": 1551.65, "word": " رأيتم", "probability": 0.8927001953125}, {"start": 1551.65, "end": 1552.11, "word": " كيف", "probability": 0.9814453125}, {"start": 1552.11, "end": 1553.17, "word": " تلازمة", "probability": 0.8497314453125}], "temperature": 1.0}, {"id": 69, "seek": 157739, "start": 1554.83, "end": 1577.39, "text": "الإيمان بالله مع الأخلاق الإيجابية فالتوبة والإصلاح و الاعتصام بالله والإخلاص لله كل هذه الأخلاق تعتبر أخلاق إيجابية قد ارتبطت وتلازمت مع الإيمان فأولئك مع المؤمنين", "tokens": [6027, 28814, 32640, 7649, 20666, 43761, 20449, 16247, 9778, 15040, 4587, 33688, 1829, 7435, 16758, 10632, 6156, 6027, 2655, 37746, 3660, 16070, 28814, 9381, 15040, 5016, 4032, 42963, 34268, 9381, 10943, 20666, 43761, 16070, 28814, 9778, 1211, 33546, 24976, 3224, 28242, 29538, 16247, 9778, 15040, 4587, 6055, 34268, 26890, 5551, 9778, 15040, 4587, 11933, 1829, 7435, 16758, 10632, 12174, 3215, 1975, 43500, 3555, 9566, 2655, 34683, 1211, 31377, 2304, 2655, 20449, 33688, 32640, 7649, 6156, 10721, 12610, 19986, 4117, 20449, 9673, 33604, 27842, 9957], "avg_logprob": -0.08083639425389907, "compression_ratio": 1.993421052631579, "no_speech_prob": 3.5762786865234375e-06, "words": [{"start": 1554.83, "end": 1555.49, "word": "الإيمان", "probability": 0.92236328125}, {"start": 1555.49, "end": 1555.93, "word": " بالله", "probability": 0.982421875}, {"start": 1555.93, "end": 1556.73, "word": " مع", "probability": 0.96044921875}, {"start": 1556.73, "end": 1557.41, "word": " الأخلاق", "probability": 0.97265625}, {"start": 1557.41, "end": 1559.01, "word": " الإيجابية", "probability": 0.95908203125}, {"start": 1559.01, "end": 1560.11, "word": " فالتوبة", "probability": 0.9533203125}, {"start": 1560.11, "end": 1562.33, "word": " والإصلاح", "probability": 0.8814453125}, {"start": 1562.33, "end": 1563.19, "word": " و", "probability": 0.53271484375}, {"start": 1563.19, "end": 1563.97, "word": " الاعتصام", "probability": 0.860595703125}, {"start": 1563.97, "end": 1564.65, "word": " بالله", "probability": 0.982177734375}, {"start": 1564.65, "end": 1566.41, "word": " والإخلاص", "probability": 0.83583984375}, {"start": 1566.41, "end": 1567.63, "word": " لله", "probability": 0.858154296875}, {"start": 1567.63, "end": 1568.29, "word": " كل", "probability": 0.7724609375}, {"start": 1568.29, "end": 1568.71, "word": " هذه", "probability": 0.98193359375}, {"start": 1568.71, "end": 1569.23, "word": " الأخلاق", "probability": 0.9920654296875}, {"start": 1569.23, "end": 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سوف يؤتي الله المؤمنين أجرا عظيمة و نختم قبل أن نرحل إلى المبحث الثالث بحديث الرسول عليه الصلاة والسلام وهذا من الأحاديث", "tokens": [2407, 8608, 38688, 7251, 33604, 31371, 21984, 9673, 33604, 27842, 9957, 5551, 7435, 23557, 6225, 19913, 32640, 3660, 4032, 8717, 9778, 39237, 12174, 36150, 14739, 8717, 2288, 5016, 1211, 30731, 9673, 49628, 12984, 6024, 104, 6027, 12984, 4724, 5016, 16254, 12984, 34892, 3794, 12610, 47356, 31767, 15040, 3660, 16070, 3794, 37440, 37037, 15730, 9154, 16247, 5016, 995, 16254, 12984], "avg_logprob": -0.11249999975164732, "compression_ratio": 1.6444444444444444, "no_speech_prob": 3.039836883544922e-06, "words": [{"start": 1578.05, "end": 1578.29, "word": "و", "probability": 0.62353515625}, {"start": 1578.29, "end": 1578.71, "word": " سوف", "probability": 0.838623046875}, {"start": 1578.71, "end": 1579.27, "word": " يؤتي", "probability": 0.7897135416666666}, {"start": 1579.27, "end": 1579.63, "word": " الله", "probability": 0.96044921875}, {"start": 1579.63, 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-0,0 +1,1528 @@ +1 +00:00:05,060 --> 00:00:07,420 +أعوذ بالله السماء العليا من الشاطر الرجيم بسم الله + +2 +00:00:07,420 --> 00:00:10,900 +الرحمن الرحيم الحمد لله والصلاة والسلام على رسول + +3 +00:00:10,900 --> 00:00:15,200 +الله اللهم صلي على سيدنا محمد وعلى آله وصحبه وسلم + +4 +00:00:15,200 --> 00:00:20,540 +أجمعين عزيزي الطلاب قبل ذي بدء ورحبكم جميعا + +5 +00:00:20,540 --> 00:00:23,800 +وأحييكم بتحية الإسلام فالسلام الله عليكم ورحمته + +6 +00:00:23,800 --> 00:00:28,650 +وبركاتهما زلنا مع الفصل التمهيدي من مساق النظم + +7 +00:00:28,650 --> 00:00:34,790 +الإسلامية واليوم نحن على موعد مع تكملة المبحث + +8 +00:00:34,790 --> 00:00:41,810 +الثالث وهو بعنوان خصائص النظم الإسلامية بدءا من + +9 +00:00:41,810 --> 00:00:49,070 +العموم والعالميةوالعموم والعالمية من خصائص النظم + +10 +00:00:49,070 --> 00:00:55,430 +الإسلامية ومعنى العموم والعالمية أي أن هذه النظم + +11 +00:00:56,160 --> 00:01:02,780 +وأن هذه الشريعة الإسلامية لم تأتي إلى قوم دون قوم + +12 +00:01:02,780 --> 00:01:12,580 +أو جنس دون جنس ولم تختص بإقليم دون إقليم أو بلون + +13 +00:01:12,580 --> 00:01:21,860 +دون لون بل هي عالمية فقد كان كل قوم يبعث إلى قومه + +14 +00:01:21,860 --> 00:01:29,580 +خاصةفموسى وعيسى مثلا إلى بني إسرائيل وصالح إلى + +15 +00:01:29,580 --> 00:01:35,640 +ثمود وخود إلى عاد وهكذا إبراهيم ونوح وسائر + +16 +00:01:35,640 --> 00:01:41,280 +الأنبياء عليهم وعلى نبينا محمد أفضل الصلاة وأزكى + +17 +00:01:41,280 --> 00:01:46,800 +السلام أما محمد عليه أفضل الصلاة وأزكى السلام فقد + +18 +00:01:46,800 --> 00:01:53,510 +بُعث إلى العالمين ونحن الآن على موعدمع الأدلة على + +19 +00:01:53,510 --> 00:01:58,630 +ذلك من الكتاب والسنة النبوية أما من الكتاب فمعنى + +20 +00:01:58,630 --> 00:02:05,070 +خمس آيات من القرآن الكريم أولها قوله تبارك وتعالى + +21 +00:02:05,070 --> 00:02:12,110 +وما أرسلناك إلا رحمة للعالمينوقوله تبارك وتعالى في + +22 +00:02:12,110 --> 00:02:18,630 +صدر صورة الفرقان تبارك الذي نزل الفرقان على عبده + +23 +00:02:18,630 --> 00:02:24,870 +ليكون للعالمين نذيرا وفي صورة سبأ قوله تبارك + +24 +00:02:24,870 --> 00:02:31,870 +وتعالى وما أرسلناك إلا كافة للناس بشيرا ونذيرا + +25 +00:02:31,870 --> 00:02:38,230 +ولكن أكثر الناس لا يعلمون وقوله تبارك وتعالى في + +26 +00:02:38,230 --> 00:02:45,320 +موضعينبدأت بالخطاب بـ يا أيها الناس يا أيها الناس + +27 +00:02:45,320 --> 00:02:52,840 +خطاب إلى كل الناس من عرب و من عجم من أبيض و من + +28 +00:02:52,840 --> 00:02:58,980 +أسود و من أحمر و من أصفر الآية الأولى في صدر صورة + +29 +00:02:58,980 --> 00:03:04,120 +النساء و هي قوله تبارك وتعالى يا أيها الناس اتقوا + +30 +00:03:04,120 --> 00:03:09,990 +ربكم الذي خلقكم من نفس واحدةوخلق منها زوجها وبث + +31 +00:03:09,990 --> 00:03:14,810 +منهما رجالًا كثيرًا ونساء واتقوا الله الذي تسألون + +32 +00:03:14,810 --> 00:03:20,630 +به والأرحمة إن الله كان عليكم رقيبة وقوله تبارك + +33 +00:03:20,630 --> 00:03:28,670 +وتعالىفي صورة الحجرات وهي أيضًا خطاب إلى كل الناس + +34 +00:03:28,670 --> 00:03:34,370 +يا أيها الناس إن خلقناكم من زكري و أنسى وجعلناكم + +35 +00:03:34,370 --> 00:03:39,710 +شعوبا و قبائلا لتعارفوا إن أكرمكم عند الله أتقاكم + +36 +00:03:40,100 --> 00:03:44,060 +إِنَّ اللَّهَ عَلِيمٌ خَبِيرٌ صدق الله العظيم من + +37 +00:03:44,060 --> 00:03:50,600 +مجموع هذه الآيات يتبين لنا أن هذه النظم ليست خاصة + +38 +00:03:50,600 --> 00:03:57,360 +بأمة العرب فقط أو بأمة محمد عليه الصلاة والسلام + +39 +00:03:57,360 --> 00:04:02,680 +وإنما جاءت رحمة للعالمين هكذا كانوا في عهد النبي + +40 +00:04:02,680 --> 00:04:10,190 +صلى الله عليه وسلم فهذا بلال الحبشيوهذا صحيب + +41 +00:04:10,190 --> 00:04:16,430 +الرومي وهذا سلمان الفارسي وهذا أبو بكر العربي + +42 +00:04:16,430 --> 00:04:21,950 +تظلهم راية واحدة هي راية الإسلام العظيم راية + +43 +00:04:21,950 --> 00:04:28,750 +القرآن الكريم راية العقيدة الإسلامية وشعارهم + +44 +00:04:28,750 --> 00:04:34,010 +الخالد كما تلونا في صورة الحجرات إن أكرمكم عند + +45 +00:04:34,010 --> 00:04:41,420 +الله أتقاكمحتى و لو كانوا أقل مالا أو أقل جمالا أو + +46 +00:04:41,420 --> 00:04:48,400 +أقل حسبا و نسبا هكذا هم الناس في كتاب الله و في + +47 +00:04:48,400 --> 00:04:52,620 +سنة رسول الله صلى الله عليه و سلم فراية الإسلام + +48 +00:04:52,620 --> 00:04:58,320 +تظلهم جميعا كما قال رسول الله صلى الله عليه و سلم + +49 +00:04:58,320 --> 00:05:03,960 +و هذا هو الحديث الأوحدمن أدلتنا في العموم + +50 +00:05:03,960 --> 00:05:10,020 +والعالمية وهو قوله صلى الله عليه وسلم أعطيت خمسا + +51 +00:05:10,020 --> 00:05:16,340 +لم يعطهن أحد من الأنبياء قبله نصرت بالرعب مسيرة + +52 +00:05:16,340 --> 00:05:22,680 +شهر وجعلت لي الأرض مسجدا وطهورا وأحلت لي الغنائم + +53 +00:05:22,680 --> 00:05:30,630 +ولم تحل لأحد قبلي وأعطيت الشفاعةوالذي يعنينا في + +54 +00:05:30,630 --> 00:05:35,850 +هذا الحديث الطويل هو الشطرة الأخيرة وكان النبي + +55 +00:05:35,850 --> 00:05:43,670 +يبعث إلى قومه خاصة وبعثته إلى الناس كافة وهذا + +56 +00:05:43,670 --> 00:05:49,170 +يتناغم مع قوله تبارك وتعالى وما أرسلناك إلا كافة + +57 +00:05:49,170 --> 00:05:56,650 +للناس إذا بعد هذه الأدلة من الكتاب والصنعةمقرر بأن + +58 +00:05:56,650 --> 00:06:04,190 +النظم الإسلامية جاءت عامة لكل الناس لكل العالمين + +59 +00:06:04,190 --> 00:06:11,530 +لا تختص بقوم دون قوم ولا بجنس دون جنس وأن الإسلام + +60 +00:06:11,530 --> 00:06:18,630 +هو دستور ومنهج حياة يحتكم إليه الناس جميعا الان + +61 +00:06:18,630 --> 00:06:26,840 +نأتي إلى الفرق بينالعولمة والعالمية قلنا من خصائص + +62 +00:06:26,840 --> 00:06:35,620 +النظم الإسلامية أنها عامة وأنها عالمية لكل الناس + +63 +00:06:35,620 --> 00:06:45,440 +أما العولمة فهي أن نكون عبيدا للنظام الأمريكي أو + +64 +00:06:45,440 --> 00:06:53,690 +العمسام كما يقولونأما الإسلام فلا إكراهة في الدين + +65 +00:06:53,690 --> 00:06:58,910 +كما قال الله تبارك وتعالى أفأنت تكره الناس حتى + +66 +00:06:58,910 --> 00:07:04,590 +يكونوا مؤمنين وفي موضع آخر فمن شاء فليؤمن ومن شاء + +67 +00:07:04,590 --> 00:07:10,840 +فليقفل هذا هو الإسلام العظيم كله رحمةوكله سماحة + +68 +00:07:10,840 --> 00:07:16,800 +حتى من غير المسلمين كما في التاريخ الإسلامي + +69 +00:07:16,800 --> 00:07:25,560 +كاليهودي والنصارى عاشوا بيننا نعم أهله ذمة أما + +70 +00:07:25,560 --> 00:07:31,880 +العولمة فهو أن نكون تحت الراية الأمريكية اقتصادا + +71 +00:07:31,880 --> 00:07:42,330 +وأخلاقاوديانة وقومية ووطنية بمعنى كما عندنا في + +72 +00:07:42,330 --> 00:07:48,850 +المصطلح إزالة الفوارق الدينية والقومية والوطنية في + +73 +00:07:48,850 --> 00:07:53,830 +إطار تدويل النظام الرأسي مال الحديث وفق الرؤية + +74 +00:07:53,830 --> 00:08:00,910 +الأمريكية المهيمة أمريكا التي تزعم أنها سيدة الكون + +75 +00:08:00,910 --> 00:08:08,220 +وحامية النظام العالميالجديد بمعنى أن العولمة هي + +76 +00:08:08,220 --> 00:08:15,860 +الفرعونيته كما قال الله في قصة فرعون مع بني + +77 +00:08:15,860 --> 00:08:21,600 +إسرائيل أنا ربكم الأعلى وما علمت لكم من إله غيري + +78 +00:08:21,600 --> 00:08:29,530 +هذا هوالخاصية الرابعة من خصائص النظم الإسلامية + +79 +00:08:29,530 --> 00:08:35,470 +العموم والعالمية ننتقل الآن إلى الخاصية الخامسة + +80 +00:08:35,470 --> 00:08:39,570 +اللى وهي التكامل والترابط وهذا يعود بنا إلى الوراء + +81 +00:08:39,570 --> 00:08:48,020 +قليلا عندما قمنا بتعريف النظم لغة وقلناالنظم لغة + +82 +00:08:48,020 --> 00:08:54,180 +هي ضم الأشياء بعضها إلى بعض بترتيب و استقامة أو + +83 +00:08:54,180 --> 00:09:01,740 +تناغم وتكامل وتوازن وترابط فيما بينهاوهنا نرى + +84 +00:09:01,740 --> 00:09:07,160 +تناغما بين المعنيين اللغوي والاصطلاحي هكذا هي + +85 +00:09:07,160 --> 00:09:13,620 +الشريعة الإسلامية وهكذا هي النظم الإسلامية فهي كل + +86 +00:09:13,620 --> 00:09:23,160 +عقده بين لآلئه وبين حباته تكامل وترابط لا يصح أن + +87 +00:09:23,160 --> 00:09:30,930 +ينفرط هذا العقد فقبل الحديث مثلاعن الميراث كما + +88 +00:09:30,930 --> 00:09:35,790 +يقول أعداء الإسلام اليوم إن الإسلام قد ظلم المرأة + +89 +00:09:35,790 --> 00:09:41,270 +وجعلها على النصف الميراث من الرجل فنقول لهم على + +90 +00:09:41,270 --> 00:09:46,850 +رسلكم قبل الحديث عن نظام الميراث الحديث عن + +91 +00:09:46,850 --> 00:09:56,690 +المواريث وعن المهور وعن النفقات فكلها لآلؤ متكاملة + +92 +00:09:57,440 --> 00:10:07,460 +لآلؤ متناغمة لآلؤ متوازنة متناسقة بين حباتها تكامل + +93 +00:10:07,460 --> 00:10:14,740 +فإذا علمنا أن الرجل هو المكلف في الإسلام بدفع + +94 +00:10:14,740 --> 00:10:22,150 +المهر و النفقة على الزوجةوالزوجة في الإسلام ليست + +95 +00:10:22,150 --> 00:10:28,450 +مكلفة بشيء حتى و لو كانت من أغنى الأغنياء فهي + +96 +00:10:28,450 --> 00:10:35,350 +مكفولة المؤنىمنذ أن تولد إلى أن تلقى الله عز وجل + +97 +00:10:35,350 --> 00:10:41,390 +فإذا كانت طفلة فنفقة المرأة على أبيها وإن كانت + +98 +00:10:41,390 --> 00:10:47,830 +زوجة فنفقتها على زوجها وإن كانت أم فعلى أولادها + +99 +00:10:47,830 --> 00:10:53,430 +هكذا هي المرأة في الإسلام وهذا هو عين الرشاد + +100 +00:10:53,700 --> 00:10:59,300 +والصواب بل عين العدل و الإنصاف في الشريعة + +101 +00:10:59,300 --> 00:11:05,140 +الإسلامية فالمرأة لا تكلف بشيء و لذا تأخذ نصف + +102 +00:11:05,140 --> 00:11:10,680 +الرجل في الميراث أما النفقة و المهر فعلى الرجلي + +103 +00:11:10,680 --> 00:11:19,840 +نعم و من هنا جاءت الأدلة للدلالة على مدى تكامل + +104 +00:11:20,920 --> 00:11:27,100 +النظم الإسلامية وترابطها وسوف نعيش مع الكتاب + +105 +00:11:27,100 --> 00:11:34,960 +والصنة والأثر أما الكتاب فمعنا خمس أدلة من القرآن + +106 +00:11:34,960 --> 00:11:40,140 +الكريم أولها قول الله تبارك وتعالى يا أيها الذين + +107 +00:11:40,140 --> 00:11:47,440 +آمنوا ادخلوا في السلم كافةومعنى السلم في هذه الآية + +108 +00:11:47,440 --> 00:11:52,860 +هو الإسلام ومعنى ادخل في السلم كافة أي خذوا + +109 +00:11:52,860 --> 00:12:01,920 +الإسلام جميعا كلا لا يتبعد وجسما لا يتجزأ فالإسلام + +110 +00:12:03,500 --> 00:12:13,020 +عقيدة و عبادة و أخلاق و معاملات و سياسة و حكم و + +111 +00:12:13,020 --> 00:12:21,520 +دولة و مصحف و سيف نعم كل ذلك هو الإسلام العظيم و + +112 +00:12:21,520 --> 00:12:30,580 +النظم الإسلامية بل إن اتباع بعض الإسلام و ترك بعضه + +113 +00:12:31,640 --> 00:12:37,260 +صوره القرآن الكريم بأنه اتباع لخطوات الشيطان + +114 +00:12:37,260 --> 00:12:42,400 +الرجيم والعياذ بالله كما قال الله عقب هذه مباشرة + +115 +00:12:42,400 --> 00:12:50,790 +ولا تتبع خطوات الشيطان إنه لكم عدومبين ومن الأدلة + +116 +00:12:50,790 --> 00:12:54,850 +أيضًا على مدى تكامل و ترابط النظمة الإسلامية قوله + +117 +00:12:54,850 --> 00:13:00,830 +تبارك وتعالى وحذرهم أي يفتنوك عن بعض ما أنزل الله + +118 +00:13:00,830 --> 00:13:06,470 +إليه وقوله تبارك وتعالى أفحكم الجاهلية يبغون ومن + +119 +00:13:06,470 --> 00:13:13,930 +أحسن من الله حكمًا لقوم يوقنون وقد بلغ الوعيد أشده + +120 +00:13:13,930 --> 00:13:15,370 +وقد بلغ الوعيد + +121 +00:13:18,150 --> 00:13:24,330 +زغوته في قوله تبارك وتعالى في صورة البقرة في آيات + +122 +00:13:24,330 --> 00:13:28,550 +الربا يا أيها الذين آمنوا اتقوا الله واذروا ما بقي + +123 +00:13:28,550 --> 00:13:34,570 +من الربا إن كنتم مؤمنين فإن لم تفعلوا فأذنوا بحرب + +124 +00:13:34,570 --> 00:13:40,130 +من الله ورسوله لم يتوعد الله تبارك وتعالى الزانية + +125 +00:13:40,130 --> 00:13:48,190 +ولا القاتلةبحرب من الله ورسوله إلا آكل الربا فهذا + +126 +00:13:48,190 --> 00:13:54,310 +دليل على خطورة هذه الجريمة اللى وهي جريمة الربا + +127 +00:13:54,310 --> 00:13:59,270 +نعم كل هذه الأدلة من القرآن تدل على مدى تكامل و + +128 +00:13:59,270 --> 00:14:04,850 +ترابط النظم الإسلامية فلا يصح أن نأخذ بالعبادات + +129 +00:14:04,850 --> 00:14:07,530 +دون المعاملة + +130 +00:14:09,670 --> 00:14:15,530 +أو أن نأخذ بالأخلاق دون الحكم والسياسة هكذا هو + +131 +00:14:15,530 --> 00:14:23,230 +الإسلام كل لا يتبعد وجسم لا يتجزى ومن الأدلة من + +132 +00:14:23,230 --> 00:14:28,250 +السنة النبوية والسيرة النبوية أيضا يوم جاء + +133 +00:14:28,250 --> 00:14:33,550 +المشركون إلى رسول الله صلى الله عليه وسلم يعرضون + +134 +00:14:33,550 --> 00:14:41,930 +عليه عروضا وقالوا له يا محمدإذا أردت الملكة ملكناك + +135 +00:14:41,930 --> 00:14:48,490 +علينا وإذا أردت المال جعلناك أغنانا وإذا أردت + +136 +00:14:48,490 --> 00:14:54,130 +النساء زوجناك أجمل نسائنا والنبي عليه السلام لم + +137 +00:14:54,130 --> 00:15:01,330 +يبعث إلى هذا وإنما بُعث من أجل هداية الناس أجمعين + +138 +00:15:01,330 --> 00:15:09,880 +وكان معهم عمه أبو طالبفقال له والله يا عم لو وضع + +139 +00:15:09,880 --> 00:15:14,720 +الشمس في يميني والقمر في يساري على أن أترك هذا + +140 +00:15:14,720 --> 00:15:23,400 +الأمر ما تركته حتى يظهره الله أو أهلك دونه نعمهذا + +141 +00:15:23,400 --> 00:15:31,220 +هو السبات على المبدأ أما من الأثر فقصته أبي بكر في + +142 +00:15:31,220 --> 00:15:36,040 +حروب الردة بعد وفاة الرسول عليه الصلاة والسلام + +143 +00:15:36,040 --> 00:15:43,960 +ارتدت العرب وكانت الردة على نوعين الردة الأولى في + +144 +00:15:43,960 --> 00:15:51,480 +بني حنيفة وكان يقودها مسلمة الكذاب الذي زعم أنه + +145 +00:15:51,480 --> 00:16:02,970 +نبيوكانت نهايته في خلافة أبي بكر نعم وقتل في معركة + +146 +00:16:02,970 --> 00:16:10,180 +اليمامةوأما قلة من المسلمين ومن الأعراب قالوا لقد + +147 +00:16:10,180 --> 00:16:16,520 +مات رسول الله فلا ندفع الزكاة لخليفته أبي بكر رضي + +148 +00:16:16,520 --> 00:16:22,000 +الله عنه وأبو بكر خليفة رسول الله الذي فقه تكامل + +149 +00:16:22,000 --> 00:16:28,660 +وترابط هذا الدين العظيم علم أن الصلاة والزكاة + +150 +00:16:28,660 --> 00:16:36,000 +توأمان لا تقبل إحداهما بدون الأخرىففي كل آيات + +151 +00:16:36,000 --> 00:16:41,260 +القرآن الكريم أقيموا الصلاة و آتوا الزكاة الذين + +152 +00:16:41,260 --> 00:16:47,440 +يقيمون الصلاة و مما رزقناهم ينفقون فالزكاة هي + +153 +00:16:47,440 --> 00:16:54,620 +شقيقة الصلاة و لذلك سل سيفه في سبيل الله و أعلن + +154 +00:16:54,620 --> 00:17:00,940 +الحرب على المرتدين و قال و الله لأقاتلن من فرق بين + +155 +00:17:00,940 --> 00:17:07,930 +الصلاة و بين الزكاةنعم هذه هي أدلة ثلاثة أدلة من + +156 +00:17:07,930 --> 00:17:13,450 +الكتاب و أدلة من السنة و أدلة من الأثر في حروب + +157 +00:17:13,450 --> 00:17:19,370 +الردة في عهد أبي بكر رضي الله عنه ننتقل الآن إلى + +158 +00:17:19,370 --> 00:17:26,370 +الخاصية السادسة أو إلى الخاصية السادسة من خصائص + +159 +00:17:26,370 --> 00:17:34,000 +النظم الإسلامية على و هي الواقعيةومعنى الواقعية أن + +160 +00:17:34,000 --> 00:17:41,620 +هذا الإسلام مطبق على أرض الواقع بمعنى أنه لا يطبق + +161 +00:17:41,620 --> 00:17:49,160 +في الأحلام أو في السماء أو في المريخ مثلا وإنما + +162 +00:17:49,160 --> 00:17:55,580 +كان كما وصف النبي صلى الله عليه وسلم لقد كان قرآنا + +163 +00:17:55,580 --> 00:18:01,730 +يمشي على الأرضكان صلى الله عليه وسلم مصحفا يتحرك + +164 +00:18:01,730 --> 00:18:10,270 +كان يجسد الإسلام في كل نواحي حياته صلى الله عليه + +165 +00:18:10,270 --> 00:18:18,850 +وسلم في كلامه و في صمته في طعامه و في شرابهفي نومه + +166 +00:18:18,850 --> 00:18:26,270 +واصطيخاذه في زواده وفي طلاقه في حربه وفي سلمه صلى + +167 +00:18:26,270 --> 00:18:34,370 +الله عليه وسلم فهي خصية تجعل من النظم نظاما بعيدا + +168 +00:18:34,370 --> 00:18:39,490 +عن الإفراط في طلب المثالية بما يتناقض مع واقع + +169 +00:18:39,490 --> 00:18:46,250 +البشرية وفطرتها أو التفريط في جانبمن جوانب الأخلاق + +170 +00:18:46,250 --> 00:18:52,950 +والقيم لتصبح حياة البشرية أشبه بحياة الوحوش في + +171 +00:18:52,950 --> 00:18:59,890 +غاباتها ولذلك سقطت جميع النظريات التي نادت + +172 +00:18:59,890 --> 00:19:06,790 +بالملائكية في عالم البشر كما صنع أفلاطون في + +173 +00:19:06,790 --> 00:19:14,920 +جمهوريته والفرابي في مدينته والشيوعيةأخيرا حيث لا + +174 +00:19:14,920 --> 00:19:22,960 +فوارقة وتزول الملكية ولا دولة ولا قضاء ولا شرطة + +175 +00:19:22,960 --> 00:19:30,850 +ولا سجون لأن الإنسان يبقى إنساناوالبشر بشرا فيهم + +176 +00:19:30,850 --> 00:19:36,870 +من الطاعة ما فيهم وفيهم من الملائكية ما فيهم وفيهم + +177 +00:19:36,870 --> 00:19:41,210 +من المعصية ما فيهم لأن الله لم يخلق هذا الإنسان + +178 +00:19:41,210 --> 00:19:46,630 +ملكا ولم يخلق هذا الإنسان نبيا وإنما خلقه بشرا + +179 +00:19:46,630 --> 00:19:56,210 +يخطئ ويصيب نعم الآن نأتي إلى مظاهر واقعية النظم + +180 +00:19:56,210 --> 00:20:04,320 +الإسلاميةنحن تكلمنا إذا أن هذه النظم واقعية ولا + +181 +00:20:04,320 --> 00:20:11,640 +تطبق في عالم الخيال أو في عالم الأوهام وإنما تطبق + +182 +00:20:11,640 --> 00:20:17,580 +على أرض الواقع ما هي الأدلة على ذلك نأتي الآن إلى + +183 +00:20:17,580 --> 00:20:26,900 +مظاهر الواقعية وهي ستة بدءا بأحكام هذه النظمالتي + +184 +00:20:26,900 --> 00:20:35,280 +هي أحكام سهلة وميسرة ومقدور عليها لا حرج فيها ولا + +185 +00:20:35,280 --> 00:20:39,800 +مشقة كما قال الله تبارك وتعالى في أكثر من موضع في + +186 +00:20:39,800 --> 00:20:45,940 +القرآن الكريم لا يكلف الله نفسا إلا وسعها لها ما + +187 +00:20:45,940 --> 00:20:51,630 +كسبتوعليها ما اكتسبت وكما قال عز وجل يريد الله بكم + +188 +00:20:51,630 --> 00:20:56,370 +اليسر ولا يريد بكم العصر وكما قال الله تبارك + +189 +00:20:56,370 --> 00:21:03,790 +وتعالى ما يريد الله ليجعل عليكم من حرجنعم هذا هو + +190 +00:21:03,790 --> 00:21:11,510 +الإسلام العظيم كله رحمة وتيسير وتخفيف عن الناس كما + +191 +00:21:11,510 --> 00:21:17,150 +قال الله تبارك وتعالى يريد الله أن يخفف عنكم وخلق + +192 +00:21:17,150 --> 00:21:21,850 +الإنسان ضعيفة أما من الصناة النبوية فقوله صلى الله + +193 +00:21:21,850 --> 00:21:32,180 +عليه وسلم بعثت بحنيفية سمحة فلا غلوة ولا تطرفةفي + +194 +00:21:32,180 --> 00:21:38,360 +هذا الدين العظيم ثانيا انها نظم تراعي في أحكامها + +195 +00:21:38,360 --> 00:21:45,480 +الحالات الاستثنائية وأصحاب الأعذار ليس على المريض + +196 +00:21:45,480 --> 00:21:50,910 +حرج ليس على الأعمى حرجليس على الأعراض حرج كما قال + +197 +00:21:50,910 --> 00:21:54,950 +الله تبارك وتعالى في موضع آخر فمن اضطر غير باغ ولا + +198 +00:21:54,950 --> 00:22:00,470 +عاد فلا إثم عليه إن الله غفور ورحيم وكما قال الله + +199 +00:22:00,470 --> 00:22:07,600 +تبارك وتعالى مثلا في عبادة الصومفي حال المرض و في + +200 +00:22:07,600 --> 00:22:12,840 +حال المسافر فمن كان منكم مريضا او على سفر فعدة من + +201 +00:22:12,840 --> 00:22:18,620 +ايام اخر و في حال السفر تقصر الصلاة لا جناح عليكم + +202 +00:22:18,620 --> 00:22:23,260 +ان تقصروا من الصلاة و كذا في حال المرض و في حال + +203 +00:22:23,260 --> 00:22:31,360 +السفر عند فقد الماءللمسلمين أن يتيمموا فإن لم + +204 +00:22:31,360 --> 00:22:39,760 +تجدوا ماء فتيمموا صعيدا طيبا أما ثالثا من مظاهر + +205 +00:22:39,760 --> 00:22:46,440 +واقعية هذه النظم أنها تحقق في مجمل أحكامها المصلحة + +206 +00:22:46,440 --> 00:22:55,550 +وتدفع المفسدة هذا هومعنى الدين العظيم فإذا سؤلتم + +207 +00:22:55,550 --> 00:23:02,170 +ما هو الإسلام فقولوا الإسلام كلمتان جلب المصلحة + +208 +00:23:02,170 --> 00:23:09,470 +ودفع المفسدة فالإسلام ما جاء إلا بالمصلحة ما جاء + +209 +00:23:09,470 --> 00:23:14,910 +إلا بالخير ما أمرنا الله إلا بكل خير وما نهان الله + +210 +00:23:14,910 --> 00:23:20,410 +إلا عن كل شر كيف لا وقد قال الله تبارك وتعالىوما + +211 +00:23:20,410 --> 00:23:25,750 +أرسلناك إلا رحمة للعالمين وكما قال صلى الله عليه + +212 +00:23:25,750 --> 00:23:33,270 +وسلم لا ضرر ولا درار نعم لا ضرر ولا درار في + +213 +00:23:33,270 --> 00:23:40,090 +الإسلام ولا في هذا الدين العظيم ومعنى لا ضرر أي لا + +214 +00:23:40,090 --> 00:23:47,090 +تبدأ أنت بالضرر ولا درار أي لا تقابل الضرر بضرر + +215 +00:23:47,090 --> 00:23:54,910 +مثلهفلو حرق لك شخص مثلا سيارة او بيت لا تحرق انت + +216 +00:23:54,910 --> 00:24:01,930 +سيارته او بيته لانه اتلاف واضاعة للمال ماعليك الا + +217 +00:24:01,930 --> 00:24:09,830 +ان ترفع شكوى الى القضاء وان تأخذ تعويض سيارتك او + +218 +00:24:09,830 --> 00:24:16,310 +تعويض بيتكأما رابعا من مظاهر واقعية النظم + +219 +00:24:16,310 --> 00:24:23,250 +الإسلامية مراعتها لصنة التدرج في التشريع لأن العرب + +220 +00:24:23,250 --> 00:24:32,130 +كانوا يرتكبون الفواحش كانوا يأكلون الربا كانوا + +221 +00:24:32,130 --> 00:24:37,520 +مدمنين على شرب الخمروكما قالت السيدة عائشة رضي + +222 +00:24:37,520 --> 00:24:43,640 +الله عنها لو كان أول ما نزل من القرآن تحريم الخمر + +223 +00:24:43,640 --> 00:24:52,660 +وتحريم الذنب لم أسلم أحد ولكن جاء تحريم الخمر على + +224 +00:24:52,660 --> 00:24:59,080 +أربعة مراحل وكذا جاء تحريم الربا على أربعة مراحل + +225 +00:24:59,080 --> 00:25:05,940 +وهكذا الحدودالعقوبات وفي الأثر عن السيدة عائشة رضي + +226 +00:25:05,940 --> 00:25:11,480 +الله عنها أنها قالت أن الصلاة أول ما فرضت كانت + +227 +00:25:11,480 --> 00:25:19,580 +ركعتين صباحا و ركعتين مساء وهذا دليل من الأثر على + +228 +00:25:19,580 --> 00:25:28,080 +صنة التدرج في التشريع ومن مظاهر واقعية هذه النظام + +229 +00:25:28,540 --> 00:25:34,120 +أنها لم تكتفي بالعمل على تطبيقها بالوازع الديني + +230 +00:25:34,120 --> 00:25:41,120 +والأخلاقي فالنظم الإسلامية لم تقتصر على العقوبات + +231 +00:25:41,120 --> 00:25:47,660 +وعلى الحجود في حسب وكذلك لم تقتصر على الوازع + +232 +00:25:47,660 --> 00:25:53,760 +الديني والإيماني أو ما يسمى اليوم بالضمير في حسب + +233 +00:25:54,810 --> 00:26:04,290 +وإنما جمعت بين الجناحين فالعقوبات والحدود والوازع + +234 +00:26:04,290 --> 00:26:11,870 +الديني والإيمانيجناحان يطير بهم الإنسان إلى عالم + +235 +00:26:11,870 --> 00:26:17,890 +الفضيلة والجنان ان شاء الله تبارك وتعالى أما سادسا + +236 +00:26:17,890 --> 00:26:24,490 +فإن من مظاهر واقعية هذه النظم اقرارها لفريضة + +237 +00:26:24,490 --> 00:26:30,620 +الجهاد في سبيل اللهوالجهاد في سبيل الله من أجل + +238 +00:26:30,620 --> 00:26:38,980 +تحرير البلاد و العباد كما قال الفقهاء إذا احتل شبر + +239 +00:26:38,980 --> 00:26:46,000 +من أرض الإسلام كان الجهاد فرض عين على كل مسلم و + +240 +00:26:46,000 --> 00:26:55,340 +مسلمة يخرج الولد دون إذن أبويه و المدين دون إذن + +241 +00:26:55,340 --> 00:27:02,310 +دائنهوحتى العبد ايام العبيد والامى دون اذن سيده + +242 +00:27:02,310 --> 00:27:08,530 +فاليوم اصبح الجهاد فرض عين كيف لا وقد احتلت فلسطين + +243 +00:27:09,030 --> 00:27:16,550 +و القدس زهرة المدائن فحرب اليهود في فلسطين يتناغم + +244 +00:27:16,550 --> 00:27:23,850 +مع مظاهر واقعية هذه المظمم لأننا لسنا إرهابيين كما + +245 +00:27:23,850 --> 00:27:30,460 +يقول أعداء الإسلام والمسلمين فالجهاد لم يفردمن أجل + +246 +00:27:30,460 --> 00:27:36,120 +الاعتداء على الناس وإنما يكونوا أولا من أجل رد + +247 +00:27:36,120 --> 00:27:40,760 +العدوان كما سيأتي معنى قوله تبارك وتعالى فمن اعتد + +248 +00:27:40,760 --> 00:27:49,640 +عليكم فاعتدوا عليه بمثل ما اعتد عليكم وهنا العدوان + +249 +00:27:49,640 --> 00:27:57,960 +يكون من باب المشاكلة لأن العدوان الأول هو العدوان + +250 +00:27:57,960 --> 00:28:02,980 +الحقيقيعدوان أعداء المسلمين على المسلمين أما + +251 +00:28:02,980 --> 00:28:10,880 +العدوان الثاني فليس حقيقة عدوانا وإنما هو صد أو رد + +252 +00:28:10,880 --> 00:28:16,560 +للعدوان وهذا في علم البلاغة يسمى بالمشاكلة + +253 +00:28:16,560 --> 00:28:22,480 +والمشاكلة إنما تكون في اللفظ دون المعنى كما قال + +254 +00:28:22,480 --> 00:28:28,040 +الله تعالى في أكثر من موضع وجزاء سيئة سيئة مثلها + +255 +00:28:28,690 --> 00:28:34,010 +فالأولى سيئة أما الثانية فليست سيئة بل هي حسنة + +256 +00:28:34,010 --> 00:28:42,320 +لأنها رد للسيئة و كذلك يمكرون و يمكر اللهإنهم + +257 +00:28:42,320 --> 00:28:47,600 +يكيدون كيدا و أكيدوا كيدا يخادعون الله و هو خادعهم + +258 +00:28:47,600 --> 00:28:56,600 +فهذا كله نص الله فنسيهم من باب المشاكلة و المشاكلة + +259 +00:28:56,600 --> 00:29:01,600 +كما قلت في اللفظ دون المعنى إذا الجهاد في سبيل + +260 +00:29:01,600 --> 00:29:08,340 +الله أولا ليرد العدوان و نحن لا نبدأ العدوان أبدا + +261 +00:29:08,340 --> 00:29:14,890 +فمن اعتدى عليكمفاعتدوا عليه بمثل ما اعتدا عليكم + +262 +00:29:14,890 --> 00:29:22,610 +وإن عاقبتم فعاقبوا بمثل ما عقبتم به و ثانيا يفرض + +263 +00:29:22,610 --> 00:29:26,570 +الجهاد في سبيل الله لنصرة المستضعفين في الأرض + +264 +00:29:26,570 --> 00:29:32,750 +الذين يفتنون في دينهم و يحالوا بينهم و بين عقيدتهم + +265 +00:29:32,750 --> 00:29:37,780 +و بينعبادتهم كما قال الله في موضعين في القرآن + +266 +00:29:37,780 --> 00:29:43,400 +الكريم في صورة البقرة و قاتلوهم حتى لا تكون فتنة و + +267 +00:29:43,400 --> 00:29:49,640 +يكون الدين لله و في صورة الأنفال و قاتلوهم حتى لا + +268 +00:29:49,640 --> 00:29:57,260 +تكون فتنة و يكون الدين كله لله أما ثابعا فمن مظاهر + +269 +00:29:57,260 --> 00:30:05,080 +واقعية النظم الإسلامية المثالية والأخلاقوهنا أيضًا + +270 +00:30:05,080 --> 00:30:13,140 +أقول لا تعارض بين المثالية وبين الواقعية كما أسلفت + +271 +00:30:13,140 --> 00:30:19,000 +في محاضرة سابقة وقلت لا تعارض بين الثبات وبين + +272 +00:30:19,000 --> 00:30:24,420 +المرونة لأن الثبات إنما يكون في القواعد والأصول + +273 +00:30:24,420 --> 00:30:29,600 +والأسسأما المرونة فتكون في الفروع والوسائل أو في + +274 +00:30:29,600 --> 00:30:35,320 +الأعراف والتقاليد والعداد وكذلك أقول هنا لا تعارض + +275 +00:30:35,320 --> 00:30:42,860 +بين الواقعية وبين المثالية البتة لأن لا نقصد + +276 +00:30:42,860 --> 00:30:53,240 +بالمثالية أن نخرج عن البشرية أو عن الإنسانية وإنما + +277 +00:30:53,240 --> 00:31:05,290 +أن نبلغما نستطيع من الأخلاق والمثالية والكمال ولكن + +278 +00:31:05,290 --> 00:31:13,270 +الكمال المطلقليس إلا لله تبارك وتعالى والعصمة ليست + +279 +00:31:13,270 --> 00:31:18,850 +إلا لرسول الله الذي يوحى إليه صلى الله عليه وسلم + +280 +00:31:18,850 --> 00:31:25,070 +أما نحن ومع المثالية والأخلاق لا نخرج عن كوننا + +281 +00:31:25,070 --> 00:31:33,770 +بشرا أو إنسانا ولذلك جاء التعريف عظيماعندما عرفوا + +282 +00:31:33,770 --> 00:31:42,030 +المثالية فهي نظم تهدف إلى الوصول بالإنسان إلى أرفع + +283 +00:31:42,030 --> 00:31:49,970 +مستوى له وأكمل نموذج يمكن أن تصل إليه البشرية أو + +284 +00:31:49,970 --> 00:31:55,970 +ترتقي إليه لو دققنا النظر في هذا التعريف لو وجدنا + +285 +00:31:55,970 --> 00:32:02,950 +أن المثالية لا تخرجنا عن كونناانسانا او عن كوننا + +286 +00:32:02,950 --> 00:32:10,330 +بشرا فقد تكررت هذه مرتين نظم تهدف الى الوصول + +287 +00:32:10,330 --> 00:32:17,330 +بالانسان فانت تبقى انسانامع المثالية أيضًا وكذلك + +288 +00:32:17,330 --> 00:32:25,990 +قوله وأكمل نموذج يمكن أن تصل إليه البشرية ولكن + +289 +00:32:25,990 --> 00:32:32,050 +اتقوا الله ما استطعتم أو ما يسمى اليوم بلغة العصر + +290 +00:32:32,050 --> 00:32:37,990 +علو الهمة فمن المثالية مثلًا + +291 +00:32:39,780 --> 00:32:44,280 +الابتسامة وقد قال عليه صلى الله عليه وسلم تبسمك في + +292 +00:32:44,280 --> 00:32:49,520 +وجه أخيك صداقة هذه صورة من صور المثالية وكذلك في + +293 +00:32:49,520 --> 00:32:53,420 +حديث السيدة عايشة رضي الله عنها لا تحكرن من + +294 +00:32:53,420 --> 00:33:02,060 +المعروف شيئا و لو أن تلقى أخاك بوجه تليق نعم حتى + +295 +00:33:02,060 --> 00:33:07,820 +في القرآن الكريموهذا أقوله من خارج الكتاب نزل + +296 +00:33:07,820 --> 00:33:14,120 +عتابا لرسول الله صلى الله عليه وسلم وهي قصته + +297 +00:33:14,120 --> 00:33:19,960 +الأعمى عبدالله ابن أم مكتوم وهذه الآيات دليل على + +298 +00:33:19,960 --> 00:33:25,230 +أن القرآن لم ينقص منه شيءفلو أراد النبي أن يخفي + +299 +00:33:25,230 --> 00:33:31,470 +آية لأخفى هذه الآيات عبث وتولى أنجاءه الأعمى وما + +300 +00:33:31,470 --> 00:33:36,390 +يدريك لعله يزكى نعم والنبي عليه الصلاة والسلام + +301 +00:33:36,390 --> 00:33:44,060 +معذور كان يدعو الملأأو علية القوم لأنهم كما يقولون + +302 +00:33:44,060 --> 00:33:50,300 +الناس على دين ملوكهم وعلى مذاهب علمائهم فلو هدى + +303 +00:33:50,300 --> 00:33:55,860 +الله هؤلاء الكبار لهدى الصغار وهدى العبيد والإماء + +304 +00:33:55,860 --> 00:34:02,760 +الذين يتبعهم نعم فالنبي عليه السلام لم يقول كلمة + +305 +00:34:02,760 --> 00:34:09,080 +ولم ينبس ببنت شفا وإنما عبس في وجه هذا الأعمق أو + +306 +00:34:09,080 --> 00:34:15,830 +قطبةجبينه وكأنه يقول له أما تراني مشغولا بدعوة + +307 +00:34:15,830 --> 00:34:21,530 +القوم فنزل القرآن الكريم والقرآن الكريم لا يبارك + +308 +00:34:21,530 --> 00:34:27,550 +فكان النبي عليه الصلاة والسلام إذا ما رأاه يفرش له + +309 +00:34:27,550 --> 00:34:34,830 +عباءته ويجلسه عليها ويقول له أهلا بمن عاتبني به + +310 +00:34:34,830 --> 00:34:40,830 +ربي صلى الله عليه وسلموهنا نأتي إلى مصطلحين في + +311 +00:34:40,830 --> 00:34:50,970 +الكتاب ولكن لم يتوسع فيهما الكتاب وهم مصطلح مجرد + +312 +00:34:50,970 --> 00:34:59,790 +الأداء ومصطلح المثالية في الأداء نعم نريد أن نضرب + +313 +00:34:59,790 --> 00:35:07,570 +مثلا على ذلك في إحدى المصالح الحكومية مثل + +314 +00:35:09,490 --> 00:35:17,510 +بريد أو وزارة من الوزارات أو مثلا بلدية من + +315 +00:35:17,510 --> 00:35:27,230 +البلديات وهكذا من المصالح الحكومية وكان على شباك + +316 +00:35:27,230 --> 00:35:37,600 +الجمهور موظفان وكلاهما مخلص في عملهويؤدي خدمة + +317 +00:35:37,600 --> 00:35:43,460 +الجمهور على أكمل وجه لكن ما الفرق بينهما الأول + +318 +00:35:43,460 --> 00:35:52,820 +منهم يؤدي واجبه كما قلنا بإخلاص وصدق وأمانة ولكنه + +319 +00:35:52,820 --> 00:36:03,770 +مكفهر الوجه مقطب الجبين عابسفي وجه المراجعين + +320 +00:36:03,770 --> 00:36:09,310 +والجمهور ماذا يطلق على هذا يطلق على هذا مجرد + +321 +00:36:09,310 --> 00:36:17,350 +الأداء أما الثاني وهو زميله والقريب منه إلى جانب + +322 +00:36:17,350 --> 00:36:22,430 +ما يقوم به من عمل في خدمة المراجعين والجمهور وكما + +323 +00:36:22,430 --> 00:36:29,730 +قلنا بصدق وأمانة وإخلاص ولكنه منفرج الأسارير + +324 +00:36:30,930 --> 00:36:40,230 +ضحوك السن يقابل الناس بابتسامة عريضة وكلمة عذبة + +325 +00:36:40,230 --> 00:36:45,710 +رقيقة هذا هو المقصود في حديثنا فيطلق على الثاني + +326 +00:36:45,710 --> 00:36:51,870 +المثالية في الأداء أما الأول فيطلق عليه مجرد + +327 +00:36:51,870 --> 00:36:59,330 +الأداء فنحن مطالبون بأن نصل إلى مستوى المثالية في + +328 +00:36:59,330 --> 00:37:07,480 +الأداءنعم هنا نأتي إلى أمثلة للحد الأدنى والحد + +329 +00:37:07,480 --> 00:37:17,060 +الأعلى للمثالية بدءا بالطاعات فالحد الأدنى في + +330 +00:37:17,060 --> 00:37:23,350 +الطاعات هو أداء الفرائضبمعنى أركان الإسلام من صوم + +331 +00:37:23,350 --> 00:37:35,140 +وصلاة وحج وذكاء وأما الحد الأعلى في الطاعاتهو أداء + +332 +00:37:35,140 --> 00:37:45,060 +النوافل كما جاء في الحديث من عاد لي وليا فقد آذنته + +333 +00:37:45,060 --> 00:37:50,900 +بالحرب وهذا الحديث القدسي عند مسلم عن أبي هريرة من + +334 +00:37:50,900 --> 00:37:59,380 +خارج الكتاب ولكنه مثال لأداء النوافليقول صلى الله + +335 +00:37:59,380 --> 00:38:04,540 +عليه وسلم قال الله تبارك وتعالى من عاد لي وليا فقد + +336 +00:38:04,540 --> 00:38:11,580 +أذنته بالحرب وما تقرب إلي عبدي بشيء أحب إليه مما + +337 +00:38:11,580 --> 00:38:17,180 +افترضته عليه هذا هو الواجب هذا هو الفرض في الطاعات + +338 +00:38:17,180 --> 00:38:21,980 +و العبادات و هو الحد الأدنى للمثالية أما الحد + +339 +00:38:21,980 --> 00:38:29,180 +الأعلى فيتمثل في النوافل والرواتبمثل الصنع قبل + +340 +00:38:29,180 --> 00:38:38,000 +الصلاة وبعدها مثل الصوم في غير رمضان كالاثنين + +341 +00:38:38,000 --> 00:38:48,420 +والخميس وعرفة وست من شوال وأيامالبيض الثالث عشر + +342 +00:38:48,420 --> 00:38:53,860 +والرابع عشر والخامس عشر من كل شهر قمري وسميت + +343 +00:38:53,860 --> 00:38:58,940 +بالأيام البيض لأن القمر أبيض ما يكون في هذه الأيام + +344 +00:38:58,940 --> 00:39:06,340 +أما الست من شوال بعد رمضان فلا تسمى بأيام البيض + +345 +00:39:06,340 --> 00:39:11,320 +كما يقول العوام وإنما هي ست من شوال كما جاء في + +346 +00:39:11,320 --> 00:39:19,630 +حديثي رمضان نعمولا يزال عبدي يتقرب إلي بالنوافل + +347 +00:39:19,630 --> 00:39:26,250 +حتى أحبهفإذا أحببته كنت سمعه الذي يسمع به وبصره + +348 +00:39:26,250 --> 00:39:31,050 +الذي يبصر به ويده التي يبطش بها ولئن سألني + +349 +00:39:31,050 --> 00:39:38,970 +لأعطيناه ولئن استعاذني لأعيدناه ومعنا أيضا حديث + +350 +00:39:38,970 --> 00:39:43,330 +يوم جاء الأعرابي وسأل الرسول عليه الصلاة والسلام + +351 +00:39:43,330 --> 00:39:50,000 +أرايت إذا صليت الصلاوات المكتوبات وصمت رمضانبمعنى + +352 +00:39:50,000 --> 00:39:55,400 +أنه اقتصر على الفرض دون أداء الصنام والناوافلة + +353 +00:39:55,400 --> 00:40:00,940 +وأحللت الحلال وحرمت الحرام ولم أزد على ذلك شيئا + +354 +00:40:00,940 --> 00:40:07,560 +أدخل الجنة فقال عليه الصلاة والسلام نعم وفي رواية + +355 +00:40:07,560 --> 00:40:13,370 +أفلح الأعرابي إن صدقفقال الأعرابي والله لا أزيد + +356 +00:40:13,370 --> 00:40:20,870 +على ذلك شيئا 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"text": "عن الميراث كما يقول أعداء الإسلام اليوم إن الإسلام قد ظلم المرأة وجعلها على النصف الميراث من الرجل فنقول لهم على رسلكم قبل الحديث عن نظام الميراث الحديث عن المواريث وعن المهور وعن النفقات فكلها لآلؤ متكاملة", "tokens": [3615, 1863, 9673, 13546, 5718, 104, 9122, 15042, 7251, 39648, 5551, 22488, 16606, 33688, 3794, 37440, 45595, 20498, 36145, 33688, 3794, 37440, 12174, 3215, 1357, 116, 19528, 9673, 2288, 10721, 3660, 49610, 30241, 11296, 15844, 28239, 9381, 5172, 9673, 13546, 5718, 104, 9154, 34892, 7435, 1211, 6156, 1863, 39648, 5296, 16095, 15844, 12602, 3794, 23275, 2304, 12174, 36150, 21542, 16254, 12984, 18871, 8717, 19913, 10943, 9673, 13546, 5718, 104, 21542, 16254, 12984, 18871, 9673, 2407, 9640, 1829, 12984, 4032, 3615, 1863, 9673, 3224, 13063, 4032, 3615, 1863, 28239, 5172, 4587, 9307, 6156, 28820, 11296, 5296, 148, 95, 1211, 33604, 44650, 4117, 10943, 37977], "avg_logprob": -0.05603966170635361, "compression_ratio": 2.0546448087431695, "no_speech_prob": 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"text": "إذا أردت الملكة ملكناك علينا وإذا أردت المال جعلناك أغنانا وإذا أردت النساء زوجناك أجمل نسائنا والنبي عليه السلام لم يبعث إلى هذا وإنما بُعث من أجل هداية الناس أجمعين وكان معهم عمه أبو طالب", "tokens": [28814, 15730, 5551, 2288, 3215, 2655, 9673, 23275, 3660, 3714, 23275, 8315, 4117, 25894, 8315, 4032, 28814, 15730, 5551, 2288, 3215, 2655, 9673, 6027, 10874, 30241, 8315, 4117, 5551, 17082, 1863, 7649, 995, 4032, 28814, 15730, 5551, 2288, 3215, 2655, 28239, 3794, 16606, 30767, 29245, 8315, 4117, 5551, 7435, 42213, 8717, 3794, 16373, 8315, 4032, 6027, 1863, 21292, 47356, 21136, 37440, 32767, 7251, 3555, 3615, 12984, 30731, 23758, 4032, 28814, 1863, 15042, 4724, 10859, 3615, 12984, 9154, 5551, 7435, 1211, 8032, 28259, 10632, 2423, 8315, 3794, 5551, 7435, 2304, 3615, 9957, 4032, 41361, 20449, 16095, 6225, 2304, 3224, 5551, 3555, 2407, 23032, 6027, 3555], "avg_logprob": -0.05829613010088603, "compression_ratio": 1.9770114942528736, "no_speech_prob": 1.1324882507324219e-06, "words": 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1546.88, "word": " على", "probability": 0.94921875}, {"start": 1546.88, "end": 1547.66, "word": " الوازع", "probability": 0.9560546875}, {"start": 1547.66, "end": 1549.1, "word": " الديني", "probability": 0.9469401041666666}, {"start": 1549.1, "end": 1550.84, "word": " والإيماني", "probability": 0.9123046875}, {"start": 1550.84, "end": 1551.08, "word": " أو", "probability": 0.775390625}, {"start": 1551.08, "end": 1551.2, "word": " ما", "probability": 0.9638671875}, {"start": 1551.2, "end": 1551.72, "word": " يسمى", "probability": 0.9557291666666666}, {"start": 1551.72, "end": 1552.02, "word": " اليوم", "probability": 0.986328125}, {"start": 1552.02, "end": 1552.9, "word": " بالضمير", "probability": 0.944091796875}, {"start": 1552.9, "end": 1553.46, "word": " في", "probability": 0.921875}, {"start": 1553.46, "end": 1553.76, "word": " حسب", "probability": 0.994873046875}], "temperature": 1.0}, {"id": 66, "seek": 156637, "start": 1554.81, "end": 1566.37, "text": "وإنما جمعت بين الجناحين فالعقوبات والحدود والوازع الديني والإيماني", "tokens": [2407, 28814, 1863, 15042, 10874, 2304, 34268, 49374, 25724, 8315, 5016, 9957, 6156, 6027, 3615, 4587, 37746, 9307, 16070, 24401, 23328, 16070, 2407, 31377, 3615, 32748, 9957, 1829, 16070, 28814, 32640, 7649, 1829], "avg_logprob": -0.10345817729830742, "compression_ratio": 1.4090909090909092, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1554.81, "end": 1555.71, "word": "وإنما", "probability": 0.8232421875}, {"start": 1555.71, "end": 1556.89, "word": " جمعت", "probability": 0.9890950520833334}, {"start": 1556.89, "end": 1557.47, "word": " بين", "probability": 0.9912109375}, {"start": 1557.47, "end": 1558.63, "word": " الجناحين", "probability": 0.97314453125}, {"start": 1558.63, "end": 1560.43, "word": " فالعقوبات", "probability": 0.9669596354166666}, {"start": 1560.43, "end": 1562.03, "word": " والحدود", "probability": 0.9095052083333334}, {"start": 1562.03, "end": 1564.29, "word": " والوازع", "probability": 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الطلاب قبل ذي بدء ورحبكم جميعا + +5 +00:00:20,540 --> 00:00:23,800 +وأحييكم بتحية الإسلام فالسلام الله عليكم ورحمته + +6 +00:00:23,800 --> 00:00:28,650 +وبركاتهما زلنا مع الفصل التمهيدي من مساق النظم + +7 +00:00:28,650 --> 00:00:34,790 +الإسلامية واليوم نحن على موعد مع تكملة المبحث + +8 +00:00:34,790 --> 00:00:41,810 +الثالث وهو بعنوان خصائص النظم الإسلامية بدءا من + +9 +00:00:41,810 --> 00:00:49,070 +العموم والعالميةوالعموم والعالمية من خصائص النظم + +10 +00:00:49,070 --> 00:00:55,430 +الإسلامية ومعنى العموم والعالمية أي أن هذه النظم + +11 +00:00:56,160 --> 00:01:02,780 +وأن هذه الشريعة الإسلامية لم تأتي إلى قوم دون قوم + +12 +00:01:02,780 --> 00:01:12,580 +أو جنس دون جنس ولم تختص بإقليم دون إقليم أو بلون + +13 +00:01:12,580 --> 00:01:21,860 +دون لون بل هي عالمية فقد كان كل قوم يبعث إلى قومه + +14 +00:01:21,860 --> 00:01:29,580 +خاصةفموسى وعيسى مثلا إلى بني إسرائيل وصالح إلى + +15 +00:01:29,580 --> 00:01:35,640 +ثمود وخود إلى عاد وهكذا إبراهيم ونوح وسائر + +16 +00:01:35,640 --> 00:01:41,280 +الأنبياء عليهم وعلى نبينا محمد أفضل الصلاة وأزكى + +17 +00:01:41,280 --> 00:01:46,800 +السلام أما محمد عليه أفضل الصلاة وأزكى السلام فقد + +18 +00:01:46,800 --> 00:01:53,510 +بُعث إلى العالمين ونحن الآن على موعدمع الأدلة على + +19 +00:01:53,510 --> 00:01:58,630 +ذلك من الكتاب والسنة النبوية أما من الكتاب فمعنى + +20 +00:01:58,630 --> 00:02:05,070 +خمس آيات من القرآن الكريم أولها قوله تبارك وتعالى + +21 +00:02:05,070 --> 00:02:12,110 +وما أرسلناك إلا رحمة للعالمينوقوله تبارك وتعالى في + +22 +00:02:12,110 --> 00:02:18,630 +صدر صورة الفرقان تبارك الذي نزل الفرقان على عبده + +23 +00:02:18,630 --> 00:02:24,870 +ليكون للعالمين نذيرا وفي صورة سبأ قوله تبارك + +24 +00:02:24,870 --> 00:02:31,870 +وتعالى وما أرسلناك إلا كافة للناس بشيرا ونذيرا + +25 +00:02:31,870 --> 00:02:38,230 +ولكن أكثر الناس لا يعلمون وقوله تبارك وتعالى في + +26 +00:02:38,230 --> 00:02:45,320 +موضعينبدأت بالخطاب بـ يا أيها الناس يا أيها الناس + +27 +00:02:45,320 --> 00:02:52,840 +خطاب إلى كل الناس من عرب و من عجم من أبيض و من + +28 +00:02:52,840 --> 00:02:58,980 +أسود و من أحمر و من أصفر الآية الأولى في صدر صورة + +29 +00:02:58,980 --> 00:03:04,120 +النساء و هي قوله تبارك وتعالى يا أيها الناس اتقوا + +30 +00:03:04,120 --> 00:03:09,990 +ربكم الذي خلقكم من نفس واحدةوخلق منها زوجها وبث + +31 +00:03:09,990 --> 00:03:14,810 +منهما رجالًا كثيرًا ونساء واتقوا الله الذي تسألون + +32 +00:03:14,810 --> 00:03:20,630 +به والأرحمة إن الله كان عليكم رقيبة وقوله تبارك + +33 +00:03:20,630 --> 00:03:28,670 +وتعالىفي صورة الحجرات وهي أيضًا خطاب إلى كل الناس + +34 +00:03:28,670 --> 00:03:34,370 +يا أيها الناس إن خلقناكم من زكري و أنسى وجعلناكم + +35 +00:03:34,370 --> 00:03:39,710 +شعوبا و قبائلا لتعارفوا إن أكرمكم عند الله أتقاكم + +36 +00:03:40,100 --> 00:03:44,060 +إِنَّ اللَّهَ عَلِيمٌ خَبِيرٌ صدق الله العظيم من + +37 +00:03:44,060 --> 00:03:50,600 +مجموع هذه الآيات يتبين لنا أن هذه النظم ليست خاصة + +38 +00:03:50,600 --> 00:03:57,360 +بأمة العرب فقط أو بأمة محمد عليه الصلاة والسلام + +39 +00:03:57,360 --> 00:04:02,680 +وإنما جاءت رحمة للعالمين هكذا كانوا في عهد النبي + +40 +00:04:02,680 --> 00:04:10,190 +صلى الله عليه وسلم فهذا بلال الحبشيوهذا صحيب + +41 +00:04:10,190 --> 00:04:16,430 +الرومي وهذا سلمان الفارسي وهذا أبو بكر العربي + +42 +00:04:16,430 --> 00:04:21,950 +تظلهم راية واحدة هي راية الإسلام العظيم راية + +43 +00:04:21,950 --> 00:04:28,750 +القرآن الكريم راية العقيدة الإسلامية وشعارهم + +44 +00:04:28,750 --> 00:04:34,010 +الخالد كما تلونا في صورة الحجرات إن أكرمكم عند + +45 +00:04:34,010 --> 00:04:41,420 +الله أتقاكمحتى و لو كانوا أقل مالا أو أقل جمالا أو + +46 +00:04:41,420 --> 00:04:48,400 +أقل حسبا و نسبا هكذا هم الناس في كتاب الله و في + +47 +00:04:48,400 --> 00:04:52,620 +سنة رسول الله صلى الله عليه و سلم فراية الإسلام + +48 +00:04:52,620 --> 00:04:58,320 +تظلهم جميعا كما قال رسول الله صلى الله عليه و سلم + +49 +00:04:58,320 --> 00:05:03,960 +و هذا هو الحديث الأوحدمن أدلتنا في العموم + +50 +00:05:03,960 --> 00:05:10,020 +والعالمية وهو قوله صلى الله عليه وسلم أعطيت خمسا + +51 +00:05:10,020 --> 00:05:16,340 +لم يعطهن أحد من الأنبياء قبله نصرت بالرعب مسيرة + +52 +00:05:16,340 --> 00:05:22,680 +شهر وجعلت لي الأرض مسجدا وطهورا وأحلت لي الغنائم + +53 +00:05:22,680 --> 00:05:30,630 +ولم تحل لأحد قبلي وأعطيت الشفاعةوالذي يعنينا في + +54 +00:05:30,630 --> 00:05:35,850 +هذا الحديث الطويل هو الشطرة الأخيرة وكان النبي + +55 +00:05:35,850 --> 00:05:43,670 +يبعث إلى قومه خاصة وبعثته إلى الناس كافة وهذا + +56 +00:05:43,670 --> 00:05:49,170 +يتناغم مع قوله تبارك وتعالى وما أرسلناك إلا كافة + +57 +00:05:49,170 --> 00:05:56,650 +للناس إذا بعد هذه الأدلة من الكتاب والصنعةمقرر بأن + +58 +00:05:56,650 --> 00:06:04,190 +النظم الإسلامية جاءت عامة لكل الناس لكل العالمين + +59 +00:06:04,190 --> 00:06:11,530 +لا تختص بقوم دون قوم ولا بجنس دون جنس وأن الإسلام + +60 +00:06:11,530 --> 00:06:18,630 +هو دستور ومنهج حياة يحتكم إليه الناس جميعا الان + +61 +00:06:18,630 --> 00:06:26,840 +نأتي إلى الفرق بينالعولمة والعالمية قلنا من خصائص + +62 +00:06:26,840 --> 00:06:35,620 +النظم الإسلامية أنها عامة وأنها عالمية لكل الناس + +63 +00:06:35,620 --> 00:06:45,440 +أما العولمة فهي أن نكون عبيدا للنظام الأمريكي أو + +64 +00:06:45,440 --> 00:06:53,690 +العمسام كما يقولونأما الإسلام فلا إكراهة في الدين + +65 +00:06:53,690 --> 00:06:58,910 +كما قال الله تبارك وتعالى أفأنت تكره الناس حتى + +66 +00:06:58,910 --> 00:07:04,590 +يكونوا مؤمنين وفي موضع آخر فمن شاء فليؤمن ومن شاء + +67 +00:07:04,590 --> 00:07:10,840 +فليقفل هذا هو الإسلام العظيم كله رحمةوكله سماحة + +68 +00:07:10,840 --> 00:07:16,800 +حتى من غير المسلمين كما في التاريخ الإسلامي + +69 +00:07:16,800 --> 00:07:25,560 +كاليهودي والنصارى عاشوا بيننا نعم أهله ذمة أما + +70 +00:07:25,560 --> 00:07:31,880 +العولمة فهو أن نكون تحت الراية الأمريكية اقتصادا + +71 +00:07:31,880 --> 00:07:42,330 +وأخلاقاوديانة وقومية ووطنية بمعنى كما عندنا في + +72 +00:07:42,330 --> 00:07:48,850 +المصطلح إزالة الفوارق الدينية والقومية والوطنية في + +73 +00:07:48,850 --> 00:07:53,830 +إطار تدويل النظام الرأسي مال الحديث وفق الرؤية + +74 +00:07:53,830 --> 00:08:00,910 +الأمريكية المهيمة أمريكا التي تزعم أنها سيدة الكون + +75 +00:08:00,910 --> 00:08:08,220 +وحامية النظام العالميالجديد بمعنى أن العولمة هي + +76 +00:08:08,220 --> 00:08:15,860 +الفرعونيته كما قال الله في قصة فرعون مع بني + +77 +00:08:15,860 --> 00:08:21,600 +إسرائيل أنا ربكم الأعلى وما علمت لكم من إله غيري + +78 +00:08:21,600 --> 00:08:29,530 +هذا هوالخاصية الرابعة من خصائص النظم الإسلامية + +79 +00:08:29,530 --> 00:08:35,470 +العموم والعالمية ننتقل الآن إلى الخاصية الخامسة + +80 +00:08:35,470 --> 00:08:39,570 +اللى وهي التكامل والترابط وهذا يعود بنا إلى الوراء + +81 +00:08:39,570 --> 00:08:48,020 +قليلا عندما قمنا بتعريف النظم لغة وقلناالنظم لغة + +82 +00:08:48,020 --> 00:08:54,180 +هي ضم الأشياء بعضها إلى بعض بترتيب و استقامة أو + +83 +00:08:54,180 --> 00:09:01,740 +تناغم وتكامل وتوازن وترابط فيما بينهاوهنا نرى + +84 +00:09:01,740 --> 00:09:07,160 +تناغما بين المعنيين اللغوي والاصطلاحي هكذا هي + +85 +00:09:07,160 --> 00:09:13,620 +الشريعة الإسلامية وهكذا هي النظم الإسلامية فهي كل + +86 +00:09:13,620 --> 00:09:23,160 +عقده بين لآلئه وبين حباته تكامل وترابط لا يصح أن + +87 +00:09:23,160 --> 00:09:30,930 +ينفرط هذا العقد فقبل الحديث مثلاعن الميراث كما + +88 +00:09:30,930 --> 00:09:35,790 +يقول أعداء الإسلام اليوم إن الإسلام قد ظلم المرأة + +89 +00:09:35,790 --> 00:09:41,270 +وجعلها على النصف الميراث من الرجل فنقول لهم على + +90 +00:09:41,270 --> 00:09:46,850 +رسلكم قبل الحديث عن نظام الميراث الحديث عن + +91 +00:09:46,850 --> 00:09:56,690 +المواريث وعن المهور وعن النفقات فكلها لآلؤ متكاملة + +92 +00:09:57,440 --> 00:10:07,460 +لآلؤ متناغمة لآلؤ متوازنة متناسقة بين حباتها تكامل + +93 +00:10:07,460 --> 00:10:14,740 +فإذا علمنا أن الرجل هو المكلف في الإسلام بدفع + +94 +00:10:14,740 --> 00:10:22,150 +المهر و النفقة على الزوجةوالزوجة في الإسلام ليست + +95 +00:10:22,150 --> 00:10:28,450 +مكلفة بشيء حتى و لو كانت من أغنى الأغنياء فهي + +96 +00:10:28,450 --> 00:10:35,350 +مكفولة المؤنىمنذ أن تولد إلى أن تلقى الله عز وجل + +97 +00:10:35,350 --> 00:10:41,390 +فإذا كانت طفلة فنفقة المرأة على أبيها وإن كانت + +98 +00:10:41,390 --> 00:10:47,830 +زوجة فنفقتها على زوجها وإن كانت أم فعلى أولادها + +99 +00:10:47,830 --> 00:10:53,430 +هكذا هي المرأة في الإسلام وهذا هو عين الرشاد + +100 +00:10:53,700 --> 00:10:59,300 +والصواب بل عين العدل و الإنصاف في الشريعة + +101 +00:10:59,300 --> 00:11:05,140 +الإسلامية فالمرأة لا تكلف بشيء و لذا تأخذ نصف + +102 +00:11:05,140 --> 00:11:10,680 +الرجل في الميراث أما النفقة و المهر فعلى الرجلي + +103 +00:11:10,680 --> 00:11:19,840 +نعم و من هنا جاءت الأدلة للدلالة على مدى تكامل + +104 +00:11:20,920 --> 00:11:27,100 +النظم الإسلامية وترابطها وسوف نعيش مع الكتاب + +105 +00:11:27,100 --> 00:11:34,960 +والصنة والأثر أما الكتاب فمعنا خمس أدلة من القرآن + +106 +00:11:34,960 --> 00:11:40,140 +الكريم أولها قول الله تبارك وتعالى يا أيها الذين + +107 +00:11:40,140 --> 00:11:47,440 +آمنوا ادخلوا في السلم كافةومعنى السلم في هذه الآية + +108 +00:11:47,440 --> 00:11:52,860 +هو الإسلام ومعنى ادخل في السلم كافة أي خذوا + +109 +00:11:52,860 --> 00:12:01,920 +الإسلام جميعا كلا لا يتبعد وجسما لا يتجزأ فالإسلام + +110 +00:12:03,500 --> 00:12:13,020 +عقيدة و عبادة و أخلاق و معاملات و سياسة و حكم و + +111 +00:12:13,020 --> 00:12:21,520 +دولة و مصحف و سيف نعم كل ذلك هو الإسلام العظيم و + +112 +00:12:21,520 --> 00:12:30,580 +النظم الإسلامية بل إن اتباع بعض الإسلام و ترك بعضه + +113 +00:12:31,640 --> 00:12:37,260 +صوره القرآن الكريم بأنه اتباع لخطوات الشيطان + +114 +00:12:37,260 --> 00:12:42,400 +الرجيم والعياذ بالله كما قال الله عقب هذه مباشرة + +115 +00:12:42,400 --> 00:12:50,790 +ولا تتبع خطوات الشيطان إنه لكم عدومبين ومن الأدلة + +116 +00:12:50,790 --> 00:12:54,850 +أيضًا على مدى تكامل و ترابط النظمة الإسلامية قوله + +117 +00:12:54,850 --> 00:13:00,830 +تبارك وتعالى وحذرهم أي يفتنوك عن بعض ما أنزل الله + +118 +00:13:00,830 --> 00:13:06,470 +إليه وقوله تبارك وتعالى أفحكم الجاهلية يبغون ومن + +119 +00:13:06,470 --> 00:13:13,930 +أحسن من الله حكمًا لقوم يوقنون وقد بلغ الوعيد أشده + +120 +00:13:13,930 --> 00:13:15,370 +وقد بلغ الوعيد + +121 +00:13:18,150 --> 00:13:24,330 +زغوته في قوله تبارك وتعالى في صورة البقرة في آيات + +122 +00:13:24,330 --> 00:13:28,550 +الربا يا أيها الذين آمنوا اتقوا الله واذروا ما بقي + +123 +00:13:28,550 --> 00:13:34,570 +من الربا إن كنتم مؤمنين فإن لم تفعلوا فأذنوا بحرب + +124 +00:13:34,570 --> 00:13:40,130 +من الله ورسوله لم يتوعد الله تبارك وتعالى الزانية + +125 +00:13:40,130 --> 00:13:48,190 +ولا القاتلةبحرب من الله ورسوله إلا آكل الربا فهذا + +126 +00:13:48,190 --> 00:13:54,310 +دليل على خطورة هذه الجريمة اللى وهي جريمة الربا + +127 +00:13:54,310 --> 00:13:59,270 +نعم كل هذه الأدلة من القرآن تدل على مدى تكامل و + +128 +00:13:59,270 --> 00:14:04,850 +ترابط النظم الإسلامية فلا يصح أن نأخذ بالعبادات + +129 +00:14:04,850 --> 00:14:07,530 +دون المعاملة + +130 +00:14:09,670 --> 00:14:15,530 +أو أن نأخذ بالأخلاق دون الحكم والسياسة هكذا هو + +131 +00:14:15,530 --> 00:14:23,230 +الإسلام كل لا يتبعد وجسم لا يتجزى ومن الأدلة من + +132 +00:14:23,230 --> 00:14:28,250 +السنة النبوية والسيرة النبوية أيضا يوم جاء + +133 +00:14:28,250 --> 00:14:33,550 +المشركون إلى رسول الله صلى الله عليه وسلم يعرضون + +134 +00:14:33,550 --> 00:14:41,930 +عليه عروضا وقالوا له يا محمدإذا أردت الملكة ملكناك + +135 +00:14:41,930 --> 00:14:48,490 +علينا وإذا أردت المال جعلناك أغنانا وإذا أردت + +136 +00:14:48,490 --> 00:14:54,130 +النساء زوجناك أجمل نسائنا والنبي عليه السلام لم + +137 +00:14:54,130 --> 00:15:01,330 +يبعث إلى هذا وإنما بُعث من أجل هداية الناس أجمعين + +138 +00:15:01,330 --> 00:15:09,880 +وكان معهم عمه أبو طالبفقال له والله يا عم لو وضع + +139 +00:15:09,880 --> 00:15:14,720 +الشمس في يميني والقمر في يساري على أن أترك هذا + +140 +00:15:14,720 --> 00:15:23,400 +الأمر ما تركته حتى يظهره الله أو أهلك دونه نعمهذا + +141 +00:15:23,400 --> 00:15:31,220 +هو السبات على المبدأ أما من الأثر فقصته أبي بكر في + +142 +00:15:31,220 --> 00:15:36,040 +حروب الردة بعد وفاة الرسول عليه الصلاة والسلام + +143 +00:15:36,040 --> 00:15:43,960 +ارتدت العرب وكانت الردة على نوعين الردة الأولى في + +144 +00:15:43,960 --> 00:15:51,480 +بني حنيفة وكان يقودها مسلمة الكذاب الذي زعم أنه + +145 +00:15:51,480 --> 00:16:02,970 +نبيوكانت نهايته في خلافة أبي بكر نعم وقتل في معركة + +146 +00:16:02,970 --> 00:16:10,180 +اليمامةوأما قلة من المسلمين ومن الأعراب قالوا لقد + +147 +00:16:10,180 --> 00:16:16,520 +مات رسول الله فلا ندفع الزكاة لخليفته أبي بكر رضي + +148 +00:16:16,520 --> 00:16:22,000 +الله عنه وأبو بكر خليفة رسول الله الذي فقه تكامل + +149 +00:16:22,000 --> 00:16:28,660 +وترابط هذا الدين العظيم علم أن الصلاة والزكاة + +150 +00:16:28,660 --> 00:16:36,000 +توأمان لا تقبل إحداهما بدون الأخرىففي كل آيات + +151 +00:16:36,000 --> 00:16:41,260 +القرآن الكريم أقيموا الصلاة و آتوا الزكاة الذين + +152 +00:16:41,260 --> 00:16:47,440 +يقيمون الصلاة و مما رزقناهم ينفقون فالزكاة هي + +153 +00:16:47,440 --> 00:16:54,620 +شقيقة الصلاة و لذلك سل سيفه في سبيل الله و أعلن + +154 +00:16:54,620 --> 00:17:00,940 +الحرب على المرتدين و قال و الله لأقاتلن من فرق بين + +155 +00:17:00,940 --> 00:17:07,930 +الصلاة و بين الزكاةنعم هذه هي أدلة ثلاثة أدلة من + +156 +00:17:07,930 --> 00:17:13,450 +الكتاب و أدلة من السنة و أدلة من الأثر في حروب + +157 +00:17:13,450 --> 00:17:19,370 +الردة في عهد أبي بكر رضي الله عنه ننتقل الآن إلى + +158 +00:17:19,370 --> 00:17:26,370 +الخاصية السادسة أو إلى الخاصية السادسة من خصائص + +159 +00:17:26,370 --> 00:17:34,000 +النظم الإسلامية على و هي الواقعيةومعنى الواقعية أن + +160 +00:17:34,000 --> 00:17:41,620 +هذا الإسلام مطبق على أرض الواقع بمعنى أنه لا يطبق + +161 +00:17:41,620 --> 00:17:49,160 +في الأحلام أو في السماء أو في المريخ مثلا وإنما + +162 +00:17:49,160 --> 00:17:55,580 +كان كما وصف النبي صلى الله عليه وسلم لقد كان قرآنا + +163 +00:17:55,580 --> 00:18:01,730 +يمشي على الأرضكان صلى الله عليه وسلم مصحفا يتحرك + +164 +00:18:01,730 --> 00:18:10,270 +كان يجسد الإسلام في كل نواحي حياته صلى الله عليه + +165 +00:18:10,270 --> 00:18:18,850 +وسلم في كلامه و في صمته في طعامه و في شرابهفي نومه + +166 +00:18:18,850 --> 00:18:26,270 +واصطيخاذه في زواده وفي طلاقه في حربه وفي سلمه صلى + +167 +00:18:26,270 --> 00:18:34,370 +الله عليه وسلم فهي خصية تجعل من النظم نظاما بعيدا + +168 +00:18:34,370 --> 00:18:39,490 +عن الإفراط في طلب المثالية بما يتناقض مع واقع + +169 +00:18:39,490 --> 00:18:46,250 +البشرية وفطرتها أو التفريط في جانبمن جوانب الأخلاق + +170 +00:18:46,250 --> 00:18:52,950 +والقيم لتصبح حياة البشرية أشبه بحياة الوحوش في + +171 +00:18:52,950 --> 00:18:59,890 +غاباتها ولذلك سقطت جميع النظريات التي نادت + +172 +00:18:59,890 --> 00:19:06,790 +بالملائكية في عالم البشر كما صنع أفلاطون في + +173 +00:19:06,790 --> 00:19:14,920 +جمهوريته والفرابي في مدينته والشيوعيةأخيرا حيث لا + +174 +00:19:14,920 --> 00:19:22,960 +فوارقة وتزول الملكية ولا دولة ولا قضاء ولا شرطة + +175 +00:19:22,960 --> 00:19:30,850 +ولا سجون لأن الإنسان يبقى إنساناوالبشر بشرا فيهم + +176 +00:19:30,850 --> 00:19:36,870 +من الطاعة ما فيهم وفيهم من الملائكية ما فيهم وفيهم + +177 +00:19:36,870 --> 00:19:41,210 +من المعصية ما فيهم لأن الله لم يخلق هذا الإنسان + +178 +00:19:41,210 --> 00:19:46,630 +ملكا ولم يخلق هذا الإنسان نبيا وإنما خلقه بشرا + +179 +00:19:46,630 --> 00:19:56,210 +يخطئ ويصيب نعم الآن نأتي إلى مظاهر واقعية النظم + +180 +00:19:56,210 --> 00:20:04,320 +الإسلاميةنحن تكلمنا إذا أن هذه النظم واقعية ولا + +181 +00:20:04,320 --> 00:20:11,640 +تطبق في عالم الخيال أو في عالم الأوهام وإنما تطبق + +182 +00:20:11,640 --> 00:20:17,580 +على أرض الواقع ما هي الأدلة على ذلك نأتي الآن إلى + +183 +00:20:17,580 --> 00:20:26,900 +مظاهر الواقعية وهي ستة بدءا بأحكام هذه النظمالتي + +184 +00:20:26,900 --> 00:20:35,280 +هي أحكام سهلة وميسرة ومقدور عليها لا حرج فيها ولا + +185 +00:20:35,280 --> 00:20:39,800 +مشقة كما قال الله تبارك وتعالى في أكثر من موضع في + +186 +00:20:39,800 --> 00:20:45,940 +القرآن الكريم لا يكلف الله نفسا إلا وسعها لها ما + +187 +00:20:45,940 --> 00:20:51,630 +كسبتوعليها ما اكتسبت وكما قال عز وجل يريد الله بكم + +188 +00:20:51,630 --> 00:20:56,370 +اليسر ولا يريد بكم العصر وكما قال الله تبارك + +189 +00:20:56,370 --> 00:21:03,790 +وتعالى ما يريد الله ليجعل عليكم من حرجنعم هذا هو + +190 +00:21:03,790 --> 00:21:11,510 +الإسلام العظيم كله رحمة وتيسير وتخفيف عن الناس كما + +191 +00:21:11,510 --> 00:21:17,150 +قال الله تبارك وتعالى يريد الله أن يخفف عنكم وخلق + +192 +00:21:17,150 --> 00:21:21,850 +الإنسان ضعيفة أما من الصناة النبوية فقوله صلى الله + +193 +00:21:21,850 --> 00:21:32,180 +عليه وسلم بعثت بحنيفية سمحة فلا غلوة ولا تطرفةفي + +194 +00:21:32,180 --> 00:21:38,360 +هذا الدين العظيم ثانيا انها نظم تراعي في أحكامها + +195 +00:21:38,360 --> 00:21:45,480 +الحالات الاستثنائية وأصحاب الأعذار ليس على المريض + +196 +00:21:45,480 --> 00:21:50,910 +حرج ليس على الأعمى حرجليس على الأعراض حرج كما قال + +197 +00:21:50,910 --> 00:21:54,950 +الله تبارك وتعالى في موضع آخر فمن اضطر غير باغ ولا + +198 +00:21:54,950 --> 00:22:00,470 +عاد فلا إثم عليه إن الله غفور ورحيم وكما قال الله + +199 +00:22:00,470 --> 00:22:07,600 +تبارك وتعالى مثلا في عبادة الصومفي حال المرض و في + +200 +00:22:07,600 --> 00:22:12,840 +حال المسافر فمن كان منكم مريضا او على سفر فعدة من + +201 +00:22:12,840 --> 00:22:18,620 +ايام اخر و في حال السفر تقصر الصلاة لا جناح عليكم + +202 +00:22:18,620 --> 00:22:23,260 +ان تقصروا من الصلاة و كذا في حال المرض و في حال + +203 +00:22:23,260 --> 00:22:31,360 +السفر عند فقد الماءللمسلمين أن يتيمموا فإن لم + +204 +00:22:31,360 --> 00:22:39,760 +تجدوا ماء فتيمموا صعيدا طيبا أما ثالثا من مظاهر + +205 +00:22:39,760 --> 00:22:46,440 +واقعية هذه النظم أنها تحقق في مجمل أحكامها المصلحة + +206 +00:22:46,440 --> 00:22:55,550 +وتدفع المفسدة هذا هومعنى الدين العظيم فإذا سؤلتم + +207 +00:22:55,550 --> 00:23:02,170 +ما هو الإسلام فقولوا الإسلام كلمتان جلب المصلحة + +208 +00:23:02,170 --> 00:23:09,470 +ودفع المفسدة فالإسلام ما جاء إلا بالمصلحة ما جاء + +209 +00:23:09,470 --> 00:23:14,910 +إلا بالخير ما أمرنا الله إلا بكل خير وما نهان الله + +210 +00:23:14,910 --> 00:23:20,410 +إلا عن كل شر كيف لا وقد قال الله تبارك وتعالىوما + +211 +00:23:20,410 --> 00:23:25,750 +أرسلناك إلا رحمة للعالمين وكما قال صلى الله عليه + +212 +00:23:25,750 --> 00:23:33,270 +وسلم لا ضرر ولا درار نعم لا ضرر ولا درار في + +213 +00:23:33,270 --> 00:23:40,090 +الإسلام ولا في هذا الدين العظيم ومعنى لا ضرر أي لا + +214 +00:23:40,090 --> 00:23:47,090 +تبدأ أنت بالضرر ولا درار أي لا تقابل الضرر بضرر + +215 +00:23:47,090 --> 00:23:54,910 +مثلهفلو حرق لك شخص مثلا سيارة او بيت لا تحرق انت + +216 +00:23:54,910 --> 00:24:01,930 +سيارته او بيته لانه اتلاف واضاعة للمال ماعليك الا + +217 +00:24:01,930 --> 00:24:09,830 +ان ترفع شكوى الى القضاء وان تأخذ تعويض سيارتك او + +218 +00:24:09,830 --> 00:24:16,310 +تعويض بيتكأما رابعا من مظاهر واقعية النظم + +219 +00:24:16,310 --> 00:24:23,250 +الإسلامية مراعتها لصنة التدرج في التشريع لأن العرب + +220 +00:24:23,250 --> 00:24:32,130 +كانوا يرتكبون الفواحش كانوا يأكلون الربا كانوا + +221 +00:24:32,130 --> 00:24:37,520 +مدمنين على شرب الخمروكما قالت السيدة عائشة رضي + +222 +00:24:37,520 --> 00:24:43,640 +الله عنها لو كان أول ما نزل من القرآن تحريم الخمر + +223 +00:24:43,640 --> 00:24:52,660 +وتحريم الذنب لم أسلم أحد ولكن جاء تحريم الخمر على + +224 +00:24:52,660 --> 00:24:59,080 +أربعة مراحل وكذا جاء تحريم الربا على أربعة مراحل + +225 +00:24:59,080 --> 00:25:05,940 +وهكذا الحدودالعقوبات وفي الأثر عن السيدة عائشة رضي + +226 +00:25:05,940 --> 00:25:11,480 +الله عنها أنها قالت أن الصلاة أول ما فرضت كانت + +227 +00:25:11,480 --> 00:25:19,580 +ركعتين صباحا و ركعتين مساء وهذا دليل من الأثر على + +228 +00:25:19,580 --> 00:25:28,080 +صنة التدرج في التشريع ومن مظاهر واقعية هذه النظام + +229 +00:25:28,540 --> 00:25:34,120 +أنها لم تكتفي بالعمل على تطبيقها بالوازع الديني + +230 +00:25:34,120 --> 00:25:41,120 +والأخلاقي فالنظم الإسلامية لم تقتصر على العقوبات + +231 +00:25:41,120 --> 00:25:47,660 +وعلى الحجود في حسب وكذلك لم تقتصر على الوازع + +232 +00:25:47,660 --> 00:25:53,760 +الديني والإيماني أو ما يسمى اليوم بالضمير في حسب + +233 +00:25:54,810 --> 00:26:04,290 +وإنما جمعت بين الجناحين فالعقوبات والحدود والوازع + +234 +00:26:04,290 --> 00:26:11,870 +الديني والإيمانيجناحان يطير بهم الإنسان إلى عالم + +235 +00:26:11,870 --> 00:26:17,890 +الفضيلة والجنان ان شاء الله تبارك وتعالى أما سادسا + +236 +00:26:17,890 --> 00:26:24,490 +فإن من مظاهر واقعية هذه النظم اقرارها لفريضة + +237 +00:26:24,490 --> 00:26:30,620 +الجهاد في سبيل اللهوالجهاد في سبيل الله من أجل + +238 +00:26:30,620 --> 00:26:38,980 +تحرير البلاد و العباد كما قال الفقهاء إذا احتل شبر + +239 +00:26:38,980 --> 00:26:46,000 +من أرض الإسلام كان الجهاد فرض عين على كل مسلم و + +240 +00:26:46,000 --> 00:26:55,340 +مسلمة يخرج الولد دون إذن أبويه و المدين دون إذن + +241 +00:26:55,340 --> 00:27:02,310 +دائنهوحتى العبد ايام العبيد والامى دون اذن سيده + +242 +00:27:02,310 --> 00:27:08,530 +فاليوم اصبح الجهاد فرض عين كيف لا وقد احتلت فلسطين + +243 +00:27:09,030 --> 00:27:16,550 +و القدس زهرة المدائن فحرب اليهود في فلسطين يتناغم + +244 +00:27:16,550 --> 00:27:23,850 +مع مظاهر واقعية هذه المظمم لأننا لسنا إرهابيين كما + +245 +00:27:23,850 --> 00:27:30,460 +يقول أعداء الإسلام والمسلمين فالجهاد لم يفردمن أجل + +246 +00:27:30,460 --> 00:27:36,120 +الاعتداء على الناس وإنما يكونوا أولا من أجل رد + +247 +00:27:36,120 --> 00:27:40,760 +العدوان كما سيأتي معنى قوله تبارك وتعالى فمن اعتد + +248 +00:27:40,760 --> 00:27:49,640 +عليكم فاعتدوا عليه بمثل ما اعتد عليكم وهنا العدوان + +249 +00:27:49,640 --> 00:27:57,960 +يكون من باب المشاكلة لأن العدوان الأول هو العدوان + +250 +00:27:57,960 --> 00:28:02,980 +الحقيقيعدوان أعداء المسلمين على المسلمين أما + +251 +00:28:02,980 --> 00:28:10,880 +العدوان الثاني فليس حقيقة عدوانا وإنما هو صد أو رد + +252 +00:28:10,880 --> 00:28:16,560 +للعدوان وهذا في علم البلاغة يسمى بالمشاكلة + +253 +00:28:16,560 --> 00:28:22,480 +والمشاكلة إنما تكون في اللفظ دون المعنى كما قال + +254 +00:28:22,480 --> 00:28:28,040 +الله تعالى في أكثر من موضع وجزاء سيئة سيئة مثلها + +255 +00:28:28,690 --> 00:28:34,010 +فالأولى سيئة أما الثانية فليست سيئة بل هي حسنة + +256 +00:28:34,010 --> 00:28:42,320 +لأنها رد للسيئة و كذلك يمكرون و يمكر اللهإنهم + +257 +00:28:42,320 --> 00:28:47,600 +يكيدون كيدا و أكيدوا كيدا يخادعون الله و هو خادعهم + +258 +00:28:47,600 --> 00:28:56,600 +فهذا كله نص الله فنسيهم من باب المشاكلة و المشاكلة + +259 +00:28:56,600 --> 00:29:01,600 +كما قلت في اللفظ دون المعنى إذا الجهاد في سبيل + +260 +00:29:01,600 --> 00:29:08,340 +الله أولا ليرد العدوان و نحن لا نبدأ العدوان أبدا + +261 +00:29:08,340 --> 00:29:14,890 +فمن اعتدى عليكمفاعتدوا عليه بمثل ما اعتدا عليكم + +262 +00:29:14,890 --> 00:29:22,610 +وإن عاقبتم فعاقبوا بمثل ما عقبتم به و ثانيا يفرض + +263 +00:29:22,610 --> 00:29:26,570 +الجهاد في سبيل الله لنصرة المستضعفين في الأرض + +264 +00:29:26,570 --> 00:29:32,750 +الذين يفتنون في دينهم و يحالوا بينهم و بين عقيدتهم + +265 +00:29:32,750 --> 00:29:37,780 +و بينعبادتهم كما قال الله في موضعين في القرآن + +266 +00:29:37,780 --> 00:29:43,400 +الكريم في صورة البقرة و قاتلوهم حتى لا تكون فتنة و + +267 +00:29:43,400 --> 00:29:49,640 +يكون الدين لله و في صورة الأنفال و قاتلوهم حتى لا + +268 +00:29:49,640 --> 00:29:57,260 +تكون فتنة و يكون الدين كله لله أما ثابعا فمن مظاهر + +269 +00:29:57,260 --> 00:30:05,080 +واقعية النظم الإسلامية المثالية والأخلاقوهنا أيضًا + +270 +00:30:05,080 --> 00:30:13,140 +أقول لا تعارض بين المثالية وبين الواقعية كما أسلفت + +271 +00:30:13,140 --> 00:30:19,000 +في محاضرة سابقة وقلت لا تعارض بين الثبات وبين + +272 +00:30:19,000 --> 00:30:24,420 +المرونة لأن الثبات إنما يكون في القواعد والأصول + +273 +00:30:24,420 --> 00:30:29,600 +والأسسأما المرونة فتكون في الفروع والوسائل أو في + +274 +00:30:29,600 --> 00:30:35,320 +الأعراف والتقاليد والعداد وكذلك أقول هنا لا تعارض + +275 +00:30:35,320 --> 00:30:42,860 +بين الواقعية وبين المثالية البتة لأن لا نقصد + +276 +00:30:42,860 --> 00:30:53,240 +بالمثالية أن نخرج عن البشرية أو عن الإنسانية وإنما + +277 +00:30:53,240 --> 00:31:05,290 +أن نبلغما نستطيع من الأخلاق والمثالية والكمال ولكن + +278 +00:31:05,290 --> 00:31:13,270 +الكمال المطلقليس إلا لله تبارك وتعالى والعصمة ليست + +279 +00:31:13,270 --> 00:31:18,850 +إلا لرسول الله الذي يوحى إليه صلى الله عليه وسلم + +280 +00:31:18,850 --> 00:31:25,070 +أما نحن ومع المثالية والأخلاق لا نخرج عن كوننا + +281 +00:31:25,070 --> 00:31:33,770 +بشرا أو إنسانا ولذلك جاء التعريف عظيماعندما عرفوا + +282 +00:31:33,770 --> 00:31:42,030 +المثالية فهي نظم تهدف إلى الوصول بالإنسان إلى أرفع + +283 +00:31:42,030 --> 00:31:49,970 +مستوى له وأكمل نموذج يمكن أن تصل إليه البشرية أو + +284 +00:31:49,970 --> 00:31:55,970 +ترتقي إليه لو دققنا النظر في هذا التعريف لو وجدنا + +285 +00:31:55,970 --> 00:32:02,950 +أن المثالية لا تخرجنا عن كونناانسانا او عن كوننا + +286 +00:32:02,950 --> 00:32:10,330 +بشرا فقد تكررت هذه مرتين نظم تهدف الى الوصول + +287 +00:32:10,330 --> 00:32:17,330 +بالانسان فانت تبقى انسانامع المثالية أيضًا وكذلك + +288 +00:32:17,330 --> 00:32:25,990 +قوله وأكمل نموذج يمكن أن تصل إليه البشرية ولكن + +289 +00:32:25,990 --> 00:32:32,050 +اتقوا الله ما استطعتم أو ما يسمى اليوم بلغة العصر + +290 +00:32:32,050 --> 00:32:37,990 +علو الهمة فمن المثالية مثلًا + +291 +00:32:39,780 --> 00:32:44,280 +الابتسامة وقد قال عليه صلى الله عليه وسلم تبسمك في + +292 +00:32:44,280 --> 00:32:49,520 +وجه أخيك صداقة هذه صورة من صور المثالية وكذلك في + +293 +00:32:49,520 --> 00:32:53,420 +حديث السيدة عايشة رضي الله عنها لا تحكرن من + +294 +00:32:53,420 --> 00:33:02,060 +المعروف شيئا و لو أن تلقى أخاك بوجه تليق نعم حتى + +295 +00:33:02,060 --> 00:33:07,820 +في القرآن الكريموهذا أقوله من خارج الكتاب نزل + +296 +00:33:07,820 --> 00:33:14,120 +عتابا لرسول الله صلى الله عليه وسلم وهي قصته + +297 +00:33:14,120 --> 00:33:19,960 +الأعمى عبدالله ابن أم مكتوم وهذه الآيات دليل على + +298 +00:33:19,960 --> 00:33:25,230 +أن القرآن لم ينقص منه شيءفلو أراد النبي أن يخفي + +299 +00:33:25,230 --> 00:33:31,470 +آية لأخفى هذه الآيات عبث وتولى أنجاءه الأعمى وما + +300 +00:33:31,470 --> 00:33:36,390 +يدريك لعله يزكى نعم والنبي عليه الصلاة والسلام + +301 +00:33:36,390 --> 00:33:44,060 +معذور كان يدعو الملأأو علية القوم لأنهم كما يقولون + +302 +00:33:44,060 --> 00:33:50,300 +الناس على دين ملوكهم وعلى مذاهب علمائهم فلو هدى + +303 +00:33:50,300 --> 00:33:55,860 +الله هؤلاء الكبار لهدى الصغار وهدى العبيد والإماء + +304 +00:33:55,860 --> 00:34:02,760 +الذين يتبعهم نعم فالنبي عليه السلام لم يقول كلمة + +305 +00:34:02,760 --> 00:34:09,080 +ولم ينبس ببنت شفا وإنما عبس في وجه هذا الأعمق أو + +306 +00:34:09,080 --> 00:34:15,830 +قطبةجبينه وكأنه يقول له أما تراني مشغولا بدعوة + +307 +00:34:15,830 --> 00:34:21,530 +القوم فنزل القرآن الكريم والقرآن الكريم لا يبارك + +308 +00:34:21,530 --> 00:34:27,550 +فكان النبي عليه الصلاة والسلام إذا ما رأاه يفرش له + +309 +00:34:27,550 --> 00:34:34,830 +عباءته ويجلسه عليها ويقول له أهلا بمن عاتبني به + +310 +00:34:34,830 --> 00:34:40,830 +ربي صلى الله عليه وسلموهنا نأتي إلى مصطلحين في + +311 +00:34:40,830 --> 00:34:50,970 +الكتاب ولكن لم يتوسع فيهما الكتاب وهم مصطلح مجرد + +312 +00:34:50,970 --> 00:34:59,790 +الأداء ومصطلح المثالية في الأداء نعم نريد أن نضرب + +313 +00:34:59,790 --> 00:35:07,570 +مثلا على ذلك في إحدى المصالح الحكومية مثل + +314 +00:35:09,490 --> 00:35:17,510 +بريد أو وزارة من الوزارات أو مثلا بلدية من + +315 +00:35:17,510 --> 00:35:27,230 +البلديات وهكذا من المصالح الحكومية وكان على شباك + +316 +00:35:27,230 --> 00:35:37,600 +الجمهور موظفان وكلاهما مخلص في عملهويؤدي خدمة + +317 +00:35:37,600 --> 00:35:43,460 +الجمهور على أكمل وجه لكن ما الفرق بينهما الأول + +318 +00:35:43,460 --> 00:35:52,820 +منهم يؤدي واجبه كما قلنا بإخلاص وصدق وأمانة ولكنه + +319 +00:35:52,820 --> 00:36:03,770 +مكفهر الوجه مقطب الجبين عابسفي وجه المراجعين + +320 +00:36:03,770 --> 00:36:09,310 +والجمهور ماذا يطلق على هذا يطلق على هذا مجرد + +321 +00:36:09,310 --> 00:36:17,350 +الأداء أما الثاني وهو زميله والقريب منه إلى جانب + +322 +00:36:17,350 --> 00:36:22,430 +ما يقوم به من عمل في خدمة المراجعين والجمهور وكما + +323 +00:36:22,430 --> 00:36:29,730 +قلنا بصدق وأمانة وإخلاص ولكنه منفرج الأسارير + +324 +00:36:30,930 --> 00:36:40,230 +ضحوك السن يقابل الناس بابتسامة عريضة وكلمة عذبة + +325 +00:36:40,230 --> 00:36:45,710 +رقيقة هذا هو المقصود في حديثنا فيطلق على الثاني + +326 +00:36:45,710 --> 00:36:51,870 +المثالية في الأداء أما الأول فيطلق عليه مجرد + +327 +00:36:51,870 --> 00:36:59,330 +الأداء فنحن مطالبون بأن نصل إلى مستوى المثالية في + +328 +00:36:59,330 --> 00:37:07,480 +الأداءنعم هنا نأتي إلى أمثلة للحد الأدنى والحد + +329 +00:37:07,480 --> 00:37:17,060 +الأعلى للمثالية بدءا بالطاعات فالحد الأدنى في + +330 +00:37:17,060 --> 00:37:23,350 +الطاعات هو أداء الفرائضبمعنى أركان الإسلام من صوم + +331 +00:37:23,350 --> 00:37:35,140 +وصلاة وحج وذكاء وأما الحد الأعلى في الطاعاتهو أداء + +332 +00:37:35,140 --> 00:37:45,060 +النوافل كما جاء في الحديث من عاد لي وليا فقد آذنته + +333 +00:37:45,060 --> 00:37:50,900 +بالحرب وهذا الحديث القدسي عند مسلم عن أبي هريرة من + +334 +00:37:50,900 --> 00:37:59,380 +خارج الكتاب ولكنه مثال لأداء النوافليقول صلى الله + +335 +00:37:59,380 --> 00:38:04,540 +عليه وسلم قال الله تبارك وتعالى من عاد لي وليا فقد + +336 +00:38:04,540 --> 00:38:11,580 +أذنته بالحرب وما تقرب إلي عبدي بشيء أحب إليه مما + +337 +00:38:11,580 --> 00:38:17,180 +افترضته عليه هذا هو الواجب هذا هو الفرض في الطاعات + +338 +00:38:17,180 --> 00:38:21,980 +و العبادات و هو الحد الأدنى للمثالية أما الحد + +339 +00:38:21,980 --> 00:38:29,180 +الأعلى فيتمثل في النوافل والرواتبمثل الصنع قبل + +340 +00:38:29,180 --> 00:38:38,000 +الصلاة وبعدها مثل الصوم في غير رمضان كالاثنين + +341 +00:38:38,000 --> 00:38:48,420 +والخميس وعرفة وست من شوال وأيامالبيض الثالث عشر + +342 +00:38:48,420 --> 00:38:53,860 +والرابع عشر والخامس عشر من كل شهر قمري وسميت + +343 +00:38:53,860 --> 00:38:58,940 +بالأيام البيض لأن القمر أبيض ما يكون في هذه الأيام + +344 +00:38:58,940 --> 00:39:06,340 +أما الست من شوال بعد رمضان فلا تسمى بأيام البيض + +345 +00:39:06,340 --> 00:39:11,320 +كما يقول العوام وإنما هي ست من شوال كما جاء في + +346 +00:39:11,320 --> 00:39:19,630 +حديثي رمضان نعمولا يزال عبدي يتقرب إلي بالنوافل + +347 +00:39:19,630 --> 00:39:26,250 +حتى أحبهفإذا أحببته كنت سمعه الذي يسمع به وبصره + +348 +00:39:26,250 --> 00:39:31,050 +الذي يبصر به ويده التي يبطش بها ولئن سألني + +349 +00:39:31,050 --> 00:39:38,970 +لأعطيناه ولئن استعاذني لأعيدناه ومعنا أيضا حديث + +350 +00:39:38,970 --> 00:39:43,330 +يوم جاء الأعرابي وسأل الرسول عليه الصلاة والسلام + +351 +00:39:43,330 --> 00:39:50,000 +أرايت إذا صليت الصلاوات المكتوبات وصمت رمضانبمعنى + +352 +00:39:50,000 --> 00:39:55,400 +أنه اقتصر على الفرض دون أداء الصنام والناوافلة + +353 +00:39:55,400 --> 00:40:00,940 +وأحللت الحلال وحرمت الحرام ولم أزد على ذلك شيئا + +354 +00:40:00,940 --> 00:40:07,560 +أدخل الجنة فقال عليه الصلاة والسلام نعم وفي رواية + +355 +00:40:07,560 --> 00:40:13,370 +أفلح الأعرابي إن صدقفقال الأعرابي والله لا أزيد + +356 +00:40:13,370 --> 00:40:20,870 +على ذلك شيئا فهذا الحديث قد جمع بين طياته الحد + +357 +00:40:20,870 --> 00:40:27,790 +الأدنى للمثالية في العبادات و الطاعات و تمثل ذلك + +358 +00:40:27,790 --> 00:40:32,570 +بالصلاوات و الصلاة و المرمضان و مثله الحج و الذكاء + +359 +00:40:32,570 --> 00:40:38,950 +دون الصداقات و دون العمراء و النوافل الأخرى و كذلك + +360 +00:40:39,680 --> 00:40:46,740 +تكلم عن الحد الأدنى في المحرمات وهو أحللت الحلال و + +361 +00:40:46,740 --> 00:40:52,840 +حرمت الحرام ولكن هناك الحد الأعلى للمثالية في + +362 +00:40:52,840 --> 00:40:59,370 +المحرمات وهو اجتناب أيضا الشبهاتحيث جاء في الحديث + +363 +00:40:59,370 --> 00:41:05,010 +إن الحلال بيّن وإن الحرام بيّن وبينهما أمور + +364 +00:41:05,010 --> 00:41:10,790 +مشتبهات أو في روايات متشابهات لا يعلمهن كثير من + +365 +00:41:10,790 --> 00:41:16,290 +الناس فمن اتقى الشبهات استبرأ لدينه وارضه ومن وقع + +366 +00:41:16,290 --> 00:41:20,880 +في الشبهات وقع في الحرامكالراعي يرعى حول الحمى + +367 +00:41:20,880 --> 00:41:27,800 +يوشك أن يرتع فيه ألا وإن لكل ملك حمى ألا وإن حمى + +368 +00:41:27,800 --> 00:41:32,440 +الله محارمه إلى آخر الحديث كذلك في حديث عمر بن + +369 +00:41:32,440 --> 00:41:38,400 +الخطاب رضي الله عنهالصحيح الذي رواه البخاري و مسلم + +370 +00:41:38,400 --> 00:41:44,320 +في حديث الأعرابي الذي سأل عن الإيمان و الإسلام و + +371 +00:41:44,320 --> 00:41:50,200 +الإحسان فالإيمان و الإسلام يمثلان الحد الأدنى من + +372 +00:41:50,200 --> 00:41:56,180 +الدين و الإحسان يمثلوا الحدالأعلى من الدين + +373 +00:41:56,180 --> 00:42:01,980 +فالإسلام و أركانه الشهادتان و الصلاة و الصوم و + +374 +00:42:01,980 --> 00:42:05,580 +الحج و الذكاء و الإيمان و أركانه الستة أن تؤمن + +375 +00:42:05,580 --> 00:42:10,420 +بالله و ملائكته و كتبه و رسوله و اليوم الآخر و + +376 +00:42:10,420 --> 00:42:15,770 +القدر الخير و شره من الله عز وجل و أما الإحسانفهو + +377 +00:42:15,770 --> 00:42:20,270 +النموذج الأعلى للشريعة الإسلامية وهو أن تعبد الله + +378 +00:42:20,270 --> 00:42:24,930 +كأنك تراه إن لم تكن تراه فإنه يراك صدق رسول الله + +379 +00:42:24,930 --> 00:42:29,170 +نكون على موعد ان شاء الله في المحاضرة التالية مع + +380 +00:42:29,170 --> 00:42:33,670 +الخاصية الثامنة والاخيرة وهي الجزاء الأخروي من + +381 +00:42:33,670 --> 00:42:40,050 +خصائص النظم الإسلامية والسلام عليكم ورحمة الله + +382 +00:42:40,050 --> 00:42:40,850 +وبركاته + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/nEocub7RWbU.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/nEocub7RWbU.srt new file mode 100644 index 0000000000000000000000000000000000000000..1726f7665d88d0d0faf7e50b07251b776b31ce63 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/nEocub7RWbU.srt @@ -0,0 +1,2055 @@ +1 +00:00:04,980 --> 00:00:07,700 +أعوذ بالله من الشيطان الرجيم بسم الله + +2 +00:00:07,700 --> 00:00:10,880 +الرحمن الرحيم الحمد لله والصلاة والسلام على رسول + +3 +00:00:10,880 --> 00:00:14,720 +الله دائما وأبدا نعطر مجالسنا بالصلاة على الحبيب + +4 +00:00:14,720 --> 00:00:20,140 +محمد صلى الله عليه وسلم أما بعد قبل ذي بدء أعزائي + +5 +00:00:20,140 --> 00:00:23,960 +الطلاب أرحب بكم جميعا وأحييكم بتحية الإسلام + +6 +00:00:23,960 --> 00:00:28,820 +العظيم فسلام الله عليكم ورحمته وبركاته. اليوم إن شاء + +7 +00:00:28,820 --> 00:00:33,960 +الله وبعون الله وبمدد من عند الله نكون على موعد مع + +8 +00:00:33,960 --> 00:00:38,820 +الفصل الأخير من فصول مساق النظم الإسلامية وهو + +9 +00:00:38,820 --> 00:00:45,420 +بعنوان النظام السياسي في الإسلام وهو عبارة عن خمسة + +10 +00:00:45,420 --> 00:00:54,050 +مباحث بأن هذا الفصل ليس مطلوبا كله. المطلوب فقط هو + +11 +00:00:54,050 --> 00:01:00,490 +مبحثين من خمسة. المبحث الأول والثاني. المبحث الأول + +12 +00:01:00,490 --> 00:01:06,390 +بعنوان تعريف النظم طبعا عند المسلمين وعند غير + +13 +00:01:06,390 --> 00:01:15,570 +المسلمين والفروق بينهما. والمبحث الثاني وهو مهم جدا + +14 +00:01:15,570 --> 00:01:24,980 +وهو طويل وهو عبارة عن أربعة قواعد. القواعد الأربعة + +15 +00:01:24,980 --> 00:01:30,000 +التي يقوم عليها النظام السياسي في الإسلام بدءا + +16 +00:01:30,000 --> 00:01:34,220 +بالحاكمية ومرورًا بالعدل والمساواة والشورى + +17 +00:01:34,220 --> 00:01:41,620 +وانتهاءً بالطاعة. نبدأ بالمبحث الأول على بركة الله. + +18 +00:01:41,620 --> 00:01:50,000 +السياسة في اللغة. أولا قبل النالجة في الكتاب أصل + +19 +00:01:50,000 --> 00:01:57,040 +السياسة في لغة العرب من سياسة الخيل بمعنى ترويضها + +20 +00:01:57,040 --> 00:02:04,940 +وسحب الأمر من سياسة الخيل بمعنى ترويضها إلى سياسة + +21 +00:02:04,940 --> 00:02:12,880 +الآدمين. والسياسة في لغة العرب من الفعل ساس الأمر + +22 +00:02:12,880 --> 00:02:20,360 +إذا قام به. وهي القيام على الشيء بما يصلحه كما جاء + +23 +00:02:20,360 --> 00:02:26,620 +في الحديث الشريف كان بني إسرائيل يسوسهم أنبياءهم + +24 +00:02:26,620 --> 00:02:30,100 +فأنبياء + +25 +00:02:30,100 --> 00:02:39,100 +بني إسرائيل في الكثرة بمنزلة علمائنا نحن أمة + +26 +00:02:39,100 --> 00:02:45,940 +الإسلام. وهذه ملحوظة قد يجهلها كثير من الناس عندما + +27 +00:02:45,940 --> 00:02:52,580 +يظنون أن كثرة أنبياء بني إسرائيل هي مدح لبني + +28 +00:02:52,580 --> 00:02:59,080 +إسرائيل. والجواب على العكس تماما إن كثرة أنبيائهم + +29 +00:02:59,080 --> 00:03:07,680 +دليل على ذنبهم لأن كثرة الأمراض تحتاج إلى كثرة + +30 +00:03:07,680 --> 00:03:15,870 +الأطباء. كلما كثرت الأمراض والأوبئة في بلد إنما تكثر + +31 +00:03:15,870 --> 00:03:24,870 +الأطباء. لكن إذا قلت الأوبئة والأمراض فيكفي البلدة + +32 +00:03:24,870 --> 00:03:33,450 +طبيب واحد. ولما كثرت مفاسد بني إسرائيل كثرت + +33 +00:03:33,450 --> 00:03:41,000 +أنبياءهم. فأنبياء بني إسرائيل في الكثرة كعلماء أمة + +34 +00:03:41,000 --> 00:03:46,420 +محمد صلى الله عليه وسلم الذين هم بعد الله وبعد + +35 +00:03:46,420 --> 00:03:53,600 +الملائكة. شهد الله أنه لا إله إلا هو والملائكة + +36 +00:03:53,600 --> 00:04:00,860 +وأولو العلم قائما بالقصد. بدأ الله بنفسه، وثنى + +37 +00:04:00,860 --> 00:04:08,540 +بملائكته وختم بأولي العلم الذين رفعهم الله درجات + +38 +00:04:08,540 --> 00:04:12,320 +يرفع الله الذين آمنوا منكم والذين أوتوا العلم + +39 +00:04:12,320 --> 00:04:18,620 +درجات. فالعلماء في أمة الإسلام ورثة الأنبياء. نعود + +40 +00:04:18,620 --> 00:04:24,100 +إلى هذا الحديث كان بنوا إسرائيل يسوسهم أنبياءهم + +41 +00:04:24,100 --> 00:04:34,030 +بمعنى يصلحون شؤونهم ويتولون أمورهم ويتدبرونها. فهم + +42 +00:04:34,030 --> 00:04:42,810 +بمنزلة العلماء. والسياسة في الاصطلاح لها تعريفات + +43 +00:04:42,810 --> 00:04:46,070 +ثلاثة + +44 +00:04:46,070 --> 00:04:56,070 +عند المسلمين وتعريفات ثلاثة عند غير المسلمين. أما + +45 +00:04:56,070 --> 00:05:04,130 +عند المسلمين فالتعريف الأول وهو أحسنها وأجمعها وهو + +46 +00:05:04,130 --> 00:05:09,680 +تعريف ابن عقيل الحنبلي كما ذكره ابن قيم الجوزية في + +47 +00:05:09,680 --> 00:05:16,560 +السياسة الشرعية. السياسة ما كان فعلا يكون معاه + +48 +00:05:16,560 --> 00:05:22,060 +الناس أقرب إلى الصلاح وأبعد عن الفساد وإن لم يضعه + +49 +00:05:22,060 --> 00:05:27,920 +الرسول صلى الله عليه وسلم ولا نزل به وحي. هذا هو + +50 +00:05:27,920 --> 00:05:37,830 +معنى السياسة بمعنى أنه لا يشترط في كل حكم أن يكون + +51 +00:05:37,830 --> 00:05:46,610 +فيه قرآن أو سنة. فلو لي الأمر أن يجتهد وكما تقول + +52 +00:05:46,610 --> 00:05:52,530 +القاعدة الشرعية تصرف الإمام على الرعية منوط + +53 +00:05:52,530 --> 00:06:00,070 +بالمصلحة ولكل زمان ومكان وأشخاص كما مر بنا في + +54 +00:06:00,070 --> 00:06:08,100 +السبات والمرونة. فتوة نعم. فالأحكام تتغير بتغير + +55 +00:06:08,100 --> 00:06:15,860 +الزمان والمكان والأشخاص وفق الأعراف والتقاليد + +56 +00:06:15,860 --> 00:06:23,660 +والعادات. ولعلنا قد أشرنا إلى ذلك سريعا عندما + +57 +00:06:23,660 --> 00:06:28,580 +تكلمنا عن مصادر النظم الإسلامية وقلنا يومها + +58 +00:06:28,580 --> 00:06:35,330 +المصادر نوعان مصادر متفق عليها وهي المقصودة في + +59 +00:06:35,330 --> 00:06:39,790 +المثاق وهي المطلوبة في الامتحان وهي أربعة. القرآن + +60 +00:06:39,790 --> 00:06:48,070 +والسنة والإجماع والقياس. ولكن قلنا هناك مصادر مختلف + +61 +00:06:48,070 --> 00:06:54,730 +عليها بمعنى أخذ بها بعض الأئمة وتركها بعض الأئمة + +62 +00:06:54,730 --> 00:07:02,830 +فمثلا الحنفية أخذوا بالاستحسان والشافعية أخذوا + +63 +00:07:02,830 --> 00:07:10,390 +بالاستصحاب والمالكية أخذوا بعمل + +64 +00:07:10,390 --> 00:07:16,710 +أهل المدينة. فعمل أهل المدينة يعتبر مصدرا من مصادر + +65 +00:07:16,710 --> 00:07:24,330 +التشريع عند الإمام مالك. وهناك أيضا من المصادر + +66 +00:07:24,330 --> 00:07:30,720 +المختلف عليها المصالح المرسلة. والمرسلة بمعنى + +67 +00:07:30,720 --> 00:07:39,200 +المطلقة أي التي لم يتنزل فيها وحي ولم يضعه الرسول + +68 +00:07:39,200 --> 00:07:44,880 +صلى الله عليه وسلم وما أكثر المسائلة في هذا الزمان + +69 +00:07:44,880 --> 00:07:56,080 +حيث يتطور ولكل دولة ولكل عصر دولة ورجال. هذا + +70 +00:07:56,080 --> 00:08:03,200 +باختصار معنى الحديث. فلو قال أحدهم هاتي بدليل على + +71 +00:08:03,200 --> 00:08:09,830 +مشروعية السيارة فهذه السيارة كان مثلها الدواب أعزكم + +72 +00:08:09,830 --> 00:08:14,810 +الله. نعم. فهذا من باب السياسة الشرعية أو من باب + +73 +00:08:14,810 --> 00:08:19,370 +المصالح المرسلة ومثلها السكك الحديدية والقطارات + +74 +00:08:19,370 --> 00:08:24,550 +والإشارات الضوئية والتكنولوجيا الحديثة التي لا تضر + +75 +00:08:24,550 --> 00:08:30,090 +بالإسلام ولا تتعارض ومصالح المسلمين. إذا التعريف + +76 +00:08:30,090 --> 00:08:36,230 +الأول وأنتم لا تطلبون بحفظه غيبا لأنه سيأتيكم في + +77 +00:08:36,230 --> 00:08:43,480 +الامتحان عشر مصطلحات فقط إن شاء الله من ستين + +78 +00:08:43,480 --> 00:08:55,740 +ثلاثين صح أو خطأ وعشرين اختيار متعدد وعشرة مصطلح + +79 +00:08:55,740 --> 00:09:01,470 +توصيل وهذا من التيثير عليكم إن شاء الله سيأتيكم + +80 +00:09:01,470 --> 00:09:07,150 +المصطلح وتنقلون الرقم إلى الجهة الأخرى فقط. نعم. + +81 +00:09:07,150 --> 00:09:14,850 +فهذا أيصر عليكم إنما تطالبون بفهم المصطلح وليس + +82 +00:09:14,850 --> 00:09:20,530 +بحفظه غيبا. وقد يأتيكم واحد من هذه المصطلحات + +83 +00:09:20,530 --> 00:09:25,890 +الثلاثة. إذا السياسة الشرعية عند المسلمين ما كان + +84 +00:09:25,890 --> 00:09:31,550 +فعلا يكون معاه الناس وأقرب إلى الصلاح وأبعد عن + +85 +00:09:31,550 --> 00:09:35,690 +الفساد وإن لم يضعه الرسول عليه الصلاة والسلام ولا + +86 +00:09:35,690 --> 00:09:40,030 +نزل به وحي. انطلاقا من القاعدة الشرعية التي سبق + +87 +00:09:40,030 --> 00:09:45,170 +ذكرها تصرف الإمام على الرعية منوط بالمصلحة. هنا + +88 +00:09:45,170 --> 00:09:52,430 +أيضا مصطلح ثاني. السياسة الشرعية استصلاح الخلق + +89 +00:09:52,430 --> 00:09:59,580 +بإرشادهم إلى الطريق المنجي في العاجل والآجل. وهنا + +90 +00:09:59,580 --> 00:10:03,960 +ألفت نظركم إلى خطأ كبير كنت أتمنى في الطبعة + +91 +00:10:03,960 --> 00:10:13,700 +الجديدة أن يتلافى ولكنه للأسف جاء كما هو. هذا + +92 +00:10:13,700 --> 00:10:21,780 +التعريف يجعل السياسة الشرعية سياسة دنيوية بكلمة أو + +93 +00:10:22,700 --> 00:10:28,940 +فلابد من رفع الألف فيكون التعريف الصحيح أقول + +94 +00:10:28,940 --> 00:10:34,640 +انتبهوا إلى هذا استصلاح الخلق بإرشادهم إلى الطريق + +95 +00:10:34,640 --> 00:10:39,960 +المنجي في العاجل والآجل. وهذا كما سيأتي قليل في + +96 +00:10:39,960 --> 00:10:45,890 +الفروق بين السياسة الشرعية والسياسة غير الشرعية عند + +97 +00:10:45,890 --> 00:10:51,630 +غير المسلمين لأن السياسة الشرعية تحقيق مصالح الأمة + +98 +00:10:51,630 --> 00:11:00,290 +في العاجل والآجل. فكلمة أو هنا خطأ كبير ولا أريد أن + +99 +00:11:00,290 --> 00:11:07,490 +أتعجل بسؤال في الامتحان قد يأتيكم في الصح غلط. نعم. + +100 +00:11:08,770 --> 00:11:13,610 +السياسة الشرعية عند المسلمين استصلاح الخلق + +101 +00:11:13,610 --> 00:11:18,010 +بإرشادهم إلى الطريق المنجّف العاجل أو الآجل. فالذي + +102 +00:11:18,010 --> 00:11:23,530 +لم يحضر مثل هذه الدروس قد يضع صح. لماذا يضع صح + +103 +00:11:23,530 --> 00:11:29,090 +لأنها للأسف في الكتاب خطأ مطبعي فانتبهوا إلى ذلك + +104 +00:11:29,090 --> 00:11:35,530 +وصححوها. الإجابة الصحيحة استصلاح الخلق بإرشادهم إلى + +105 +00:11:35,530 --> 00:11:42,550 +الطريق المناد في العاجل والآجل وليس كلمة أو. اللهم + +106 +00:11:42,550 --> 00:11:48,590 +فاشهد أني بلغت. ثالثا وهي صحيحة ليس فيها أخطاء + +107 +00:11:48,590 --> 00:11:55,510 +مطبعية. حملوا الكافة والكافة هم الناس. حملوا الكافة + +108 +00:11:55,510 --> 00:12:00,670 +على مقتضى النظر الشرعي في مصالحهم الأخروية + +109 +00:12:00,670 --> 00:12:09,370 +والدنيوية الراجعة إليها. رأيتم؟ نعم هنا قاموا + +110 +00:12:09,370 --> 00:12:14,710 +بتصحيح الخطأ في التعريف الثاني. + +111 +00:12:16,490 --> 00:12:21,150 +الأخروية والدنيوية. إذا السياسة الشرعية باختصار + +112 +00:12:21,150 --> 00:12:27,090 +تحقيق مصالح الأمة أو مصالح الخلق أو مصالح الكافة + +113 +00:12:27,090 --> 00:12:32,910 +أو الناس في الدنيا والآخرة عبر عنها في التعريف + +114 +00:12:32,910 --> 00:12:36,390 +الثاني في العاجل والآجل. في العاجل يعني في الدنيا + +115 +00:12:36,390 --> 00:12:43,810 +والآجل يعني في الآخرة. الآن بعد أن عرفنا السياسة عند + +116 +00:12:43,810 --> 00:12:48,010 +المسلمين نأتي إلى سياسة عند غير مسلمين وهي في + +117 +00:12:48,010 --> 00:12:57,010 +الحقيقة تعريفات مبطورة ولكنها رحمة بكم. نعم فأول + +118 +00:12:57,010 --> 00:13:03,370 +هذه التعريفات وهي أجمعها إن كان سيأتيكم سؤال فهو + +119 +00:13:03,370 --> 00:13:11,770 +هذا التعريف. فن حكم المجتمعات الإنسانية والتعريف + +120 +00:13:11,770 --> 00:13:20,560 +الثاني فن الحكم والتعريف الثالث علم الدولة. هذه هي + +121 +00:13:20,560 --> 00:13:26,280 +السياسة عند غير المسلمين. تعريفات كما ترون قصيرة و + +122 +00:13:26,280 --> 00:13:32,340 +مبتورة وكان الأولى أن تستبدل بغيرها من مصطلحات + +123 +00:13:32,340 --> 00:13:39,780 +أخرى. ماذا نرى هنا فأن حكم المجتمعات الإنسانية في + +124 +00:13:39,780 --> 00:13:46,070 +العاجل دون الآجل بمعنى في الدنيا دون الآخرة لأن + +125 +00:13:46,070 --> 00:13:52,910 +هؤلاء الكفار لا يؤمنون بالآخرة إنما همهم هو إشباع + +126 +00:13:52,910 --> 00:14:02,630 +بطونهم وشهواتهم وغرائزهم وإرضاء شعوبهم الذين + +127 +00:14:02,630 --> 00:14:08,150 +انتخبوهم ورفعوهم إلى سدة الحكم. حتى في التوراة + +128 +00:14:08,150 --> 00:14:13,590 +والإنجيل وليس في القرآن فقط حرم الله الزنا وحرم + +129 +00:14:13,590 --> 00:14:20,370 +الله الخمرة وحرم الله الربا. ومع ذلك أحل الزنا وما + +130 +00:14:20,370 --> 00:14:25,790 +هو أخطر من الزنا الشذوذ أن ينكح الرجل الرجل + +131 +00:14:25,790 --> 00:14:35,030 +والمرأة المرأة بل هناك عقود رسمية في المحاكم وفي + +132 +00:14:35,030 --> 00:14:42,690 +الكنائس عندهم يقرون أن يتزوج زواجا حلالا أو شرعيا + +133 +00:14:42,690 --> 00:14:48,490 +بلُغتهم الرجل الرجل والمرأة المرأة وهذا كله مخالف + +134 +00:14:48,490 --> 00:14:52,490 +لا أقول لما جاء في القرآن بل لما جاء في التوراة و + +135 +00:14:52,490 --> 00:14:57,470 +الإنجيل. فهي من الكليات الخمس. حفظوا العقل وحفظوا + +136 +00:14:57,470 --> 00:15:06,390 +النسل والفرج والمال. فحافظ الله العقل + +137 +00:15:06,390 --> 00:15:14,950 +بتحريم الخمر وحفظ النسل بتحريم الزنا وحفظ المال + +138 +00:15:14,950 --> 00:15:22,190 +بتحريم الربا. نعم فإذا ما جاءكم سؤال السياسة عند + +139 +00:15:22,190 --> 00:15:27,430 +غير المسلمين فأن حكم المجتمعات الإنسانية بالعاجل + +140 +00:15:27,430 --> 00:15:34,790 +والآجل الإجابة خطأ وإذا جاءكم سؤال السياسة عند + +141 +00:15:34,790 --> 00:15:41,250 +المسلمين فإن حكم المجتمعات الإنسانية في العاجل والآجل دون + +142 +00:15:41,250 --> 00:15:48,790 +الآجل أو في العاجل أو الآجل فالإجابة أيضا خطأ هكذا + +143 +00:15:48,790 --> 00:15:56,110 +نجد أن هناك تشابه بين السياسة عند المسلمين وعند + +144 +00:15:56,110 --> 00:16:02,630 +غير المسلمين ووجه التشابه أن علماء المسلمين وغيرهم + +145 +00:16:02,630 --> 00:16:09,810 +يرون أن السياسة هي تدبير شؤون البلاد والعباد ولكن + +146 +00:16:09,810 --> 00:16:16,410 +على اختلاف بينهم في كافية ذلك ولعله قد مر بنا في + +147 +00:16:16,410 --> 00:16:21,530 +صدر الكتاب عندما تكلمنا عن تعريف النظم عند + +148 +00:16:21,530 --> 00:16:31,140 +المسلمين وعند غير المسلمين وقلنا هناك تشابها أيضا + +149 +00:16:31,140 --> 00:16:36,280 +في حياة واحدة وهي أن النظم الإسلامية شكل من أشكال + +150 +00:16:36,280 --> 00:16:43,360 +النظم بوجه عام من حيث إنها تُطَبِّق و تنظم سلوك + +151 +00:16:43,360 --> 00:16:48,520 +ومعاملات أفراد المجتمع الذي آمن بها أو خضع وانقاد + +152 +00:16:48,520 --> 00:16:55,140 +لإحكامها وقوانينها هكذا تتفق النظم الإسلامية مع + +153 +00:16:55,140 --> 00:17:02,620 +غير الإسلامية وهنا أيضا تتفق السياسة الشرعية وغير + +154 +00:17:02,620 --> 00:17:13,740 +الشرعية من أن كل منهم تدبير شؤون البلاد والعباد + +155 +00:17:14,910 --> 00:17:20,630 +خلّنا هناك اختلاف من جهة المصدر ومن جهة الغاية أو + +156 +00:17:20,630 --> 00:17:25,550 +الهدف أما من جهة المصدر فكما سبق ذكرنا في النظم + +157 +00:17:25,550 --> 00:17:29,970 +الإسلامية أن مصدر النظم الإسلامية ومن ثم مصدر + +158 +00:17:29,970 --> 00:17:35,870 +السياسة الإسلامية هو الإسلام أو شرع الله أو القرآن + +159 +00:17:35,870 --> 00:17:43,470 +الكريم وكذلك السنة النبوية عن رسول الله صلى الله + +160 +00:17:43,470 --> 00:17:47,870 +عليه وسلم أما بالنسبة إلى غير المسلمين فهم لا + +161 +00:17:47,870 --> 00:17:54,070 +يؤمنون بأي كتاب سماوي حتى القرآن والإنجيل الكتب + +162 +00:17:54,070 --> 00:17:59,090 +السماوية عفوا التوراة والإنجيل الكتب السماوية التي + +163 +00:17:59,090 --> 00:18:03,290 +نزلت عليهم فعند غير المسلمين الحاكم هو القانون + +164 +00:18:03,290 --> 00:18:11,760 +الذي يضعه رجال السياسة أنفسهم أما من حيث الهدف فقد + +165 +00:18:11,760 --> 00:18:18,600 +سبق أن تكلمنا عن ذلك عند المصطلحات فهدف النظم + +166 +00:18:18,600 --> 00:18:24,040 +الإسلامية أو السياسة الإسلامية تحقيق مصالح الأمة + +167 +00:18:24,040 --> 00:18:30,680 +في العاجل والآجل رأيتم هنا قد صححوا الخطأ الأول في + +168 +00:18:30,680 --> 00:18:41,170 +العاجل والآجل هذا هو الأصح وليس أو الآجل نكرر هذا + +169 +00:18:41,170 --> 00:18:46,230 +للأهمية لأنه موضع سؤال ويخطف فيه كثير من الطلاب + +170 +00:18:46,230 --> 00:18:50,410 +الذين يقرؤون الكتاب بعيدا عن توجيهات الدكتور + +171 +00:18:50,410 --> 00:18:57,170 +المحاضر نعم تحقيق مصالح الأمة في العاجل والآجل أي + +172 +00:18:57,170 --> 00:19:02,470 +في الدنيا والآخرة حسب تعاليم الإسلام ونظمه أما عند + +173 +00:19:02,470 --> 00:19:06,970 +غير المسلمين فكما أسلفنا فالهدف ليس واحدا عند كل + +174 +00:19:06,970 --> 00:19:12,190 +الجماعات وإنما هو بحسب ما تراه كل جماعة على حدة أو + +175 +00:19:12,190 --> 00:19:19,330 +بحسب ما يراه رجال السياسة فيها لذلك أحلوا ما حرّم + +176 +00:19:19,330 --> 00:19:30,650 +الله هذا هو باختصار المبحث الأول وهو صغير وقصير + +177 +00:19:30,650 --> 00:19:36,330 +كما ترون تعريف النظم عند المسلمين وعند غير + +178 +00:19:36,330 --> 00:19:44,260 +المسلمين وقد رأينا أن هناك توافقا بين التعريفين من + +179 +00:19:44,260 --> 00:19:51,360 +جهة أن كل منها تدبير شؤون البلاد والعباد ولكن + +180 +00:19:51,360 --> 00:19:58,410 +الخلاف من جهة المصدر ومن جهة الغاية أو الهدف من جهة + +181 +00:19:58,410 --> 00:20:02,230 +المصدر قلنا بأن مصدر النظم الإسلامية أو السياسة + +182 +00:20:02,230 --> 00:20:08,170 +الإسلامية هو القرآن والسنة أما عند غير المسلمين + +183 +00:20:08,170 --> 00:20:13,970 +فهو رجال السياسة أو رجال القانون الذين ليس لهم إلا + +184 +00:20:13,970 --> 00:20:20,180 +إرضاء شعوبهم ومجتمعاتهم الذين انتخبوهم وجعلوهم في + +185 +00:20:20,180 --> 00:20:25,200 +الحكم من أجل ذلك أحلوا ما حرّم الله في القرآن + +186 +00:20:25,200 --> 00:20:30,660 +والتوراة والإنجيل أما الغاية فالنظم الإسلامية + +187 +00:20:30,660 --> 00:20:37,040 +والسياسة الشرعية هدفها تحقيق مصالح الأمة الإسلامية + +188 +00:20:37,040 --> 00:20:44,470 +في العاجل والآجل في أمور الدنياوية والأخروية أما + +189 +00:20:44,470 --> 00:20:50,870 +عند غيرهم فعلى العكس من ذلك تماما ليس لهم هدف إلا + +190 +00:20:50,870 --> 00:20:57,050 +تحقيق شهواتهم ونزواتهم الدنيوية فقط دون الأخروية + +191 +00:20:57,050 --> 00:21:02,890 +لعلهم حتى لا يؤمنون بالآخرة كما وصفهم الله إنما هي + +192 +00:21:02,890 --> 00:21:08,730 +حياتنا الدنيا نموت ونحيا وما يهلكنا إلا الدهر هنا + +193 +00:21:08,730 --> 00:21:14,140 +ننطلق للمبحث الثاني وأريد أن ألفت أنظركم إلى مصطلح + +194 +00:21:14,140 --> 00:21:21,380 +لم يلتفت إليه كثير من الطلاب لأننا تعودنا أن يكون + +195 +00:21:21,380 --> 00:21:28,360 +المصطلح بين قوسين كما مر بنا قبل قليل النظم عند + +196 +00:21:28,360 --> 00:21:32,880 +المسلمين وعند غير المسلمين وكما مر بنا في تعريفات + +197 +00:21:32,880 --> 00:21:39,780 +أخرى مثل تعريف السياسة وتعريف الإجماع وتعريف + +198 +00:21:39,780 --> 00:21:45,800 +الأسرة وتعريف الزواج وتعريفات أخرى كثيرة + +199 +00:21:45,800 --> 00:21:55,600 +كالربانية نعم والثبات والمرونة ولكن هناك تعريفات + +200 +00:21:55,600 --> 00:22:03,820 +لم يفطن إليها الطلاب ولما تكلمت عن مجالات فرّق + +201 +00:22:03,820 --> 00:22:06,400 +فيها الإسلام بين الرجل والمرأة قلت لكم هناك + +202 +00:22:06,400 --> 00:22:14,400 +تعريف اللعان نعم أكرر من أجل مصلحة الطالب لأنه + +203 +00:22:14,400 --> 00:22:18,960 +يوما جاء هذا المصطلح مصطلح اللعان قد يأتي في + +204 +00:22:18,960 --> 00:22:24,380 +الامتحانات وهو ليس في أعلى الصفحة فجاء الطالب و + +205 +00:22:24,380 --> 00:22:28,900 +يسأل أين يا دكتور هذا المصطلح فقلت له لو حضرت + +206 +00:22:28,900 --> 00:22:35,690 +المحاضرات لعرفت أنه في الهامش فمصطلح اللعان في + +207 +00:22:35,690 --> 00:22:44,070 +الهامش وهنا أقول لكم هنا مصطلح اسمه قواعد النظام + +208 +00:22:44,070 --> 00:22:50,210 +السياسي في الإسلام لكنه ليس له عنوان بارز ولم يوضع + +209 +00:22:50,210 --> 00:22:54,270 +بين قوسين ولذا غاب عن كثير من الطلاب ما هذا + +210 +00:22:54,270 --> 00:23:03,840 +المصطلح المبادئ والثوابت الأساسية التي بنى عليها + +211 +00:23:03,840 --> 00:23:10,540 +الإسلام دولته ويستلهم منها النظام السياسي للحكم + +212 +00:23:10,540 --> 00:23:15,380 +إذا ما هو تعريف قواعد النظام السياسي في الإسلام + +213 +00:23:15,380 --> 00:23:22,900 +المبادئ والثوابت الأساسية التي بنى عليها الإسلام + +214 +00:23:22,900 --> 00:23:31,810 +دولته إذا ما جاء هذا وطبعا لن يأتيكم حفظا عن ظهر + +215 +00:23:31,810 --> 00:23:37,150 +القلب وإنما سيأتيكم وتضعون رقمه في الجهة الأخرى + +216 +00:23:37,150 --> 00:23:43,610 +يعني مصطلح توصيل وهذا من كرم الله عليكم أسهل وأيسر + +217 +00:23:43,610 --> 00:23:49,470 +إذا هذه الملحوظة الأولى طبعا قواعد النظام السياسي + +218 +00:23:49,470 --> 00:23:54,830 +كثيرة عُدّت ستة وعُدّت أكثر وعُدّت أقل ولكن نحن + +219 +00:23:54,830 --> 00:24:03,960 +الحقيقة ملتزمون بالكتاب وسوف نقتصر إن شاء الله على + +220 +00:24:03,960 --> 00:24:09,880 +القواعد الأربعة فقواعد النظام السياسي في الإسلام + +221 +00:24:09,880 --> 00:24:17,080 +أربعة كما هي عندنا في الكتاب وهي آخر المقرر في + +222 +00:24:17,080 --> 00:24:24,100 +مساق النظم الإسلامية والأسئلة هنا كثيرة وهي مهمة + +223 +00:24:24,100 --> 00:24:31,130 +جدا أولا الحاكمية لله ثانيا العدل والمساواة وثالثا + +224 +00:24:31,130 --> 00:24:38,890 +الشورى ورابعا الطاعة وهكذا في المحاضرة التالية إن + +225 +00:24:38,890 --> 00:24:44,630 +شاء الله نكون قد انتهينا من المقرر بالكلية نبدأ + +226 +00:24:44,630 --> 00:24:49,570 +الآن بالقاعدة الأولى وهي الحاكمية لله ما هو تعريف + +227 +00:24:49,570 --> 00:24:58,290 +الحاكمية الحاكمية لغة مصدر من الفعل حكم وحكم في + +228 +00:24:58,290 --> 00:25:05,030 +لغة العرب بمعنى قضى ومنه قولهم حكم بالأمر حكما أي + +229 +00:25:05,030 --> 00:25:13,830 +قضى به ويقال حكم له وحكم عليه وحكم فيه وهذا طبعا + +230 +00:25:13,830 --> 00:25:18,870 +لا يعنينا كثيرا لأن المعاني اللغوية لن تأتي في + +231 +00:25:18,870 --> 00:25:23,510 +الامتحان الذي يأتيكم في الامتحان فقط هو المصطلحات + +232 +00:25:23,510 --> 00:25:26,130 +الشرعية نعم + +233 +00:25:28,150 --> 00:25:34,270 +وعلى هذا فمعنى كون الحاكمية لله أي أنه سبحانه + +234 +00:25:34,270 --> 00:25:40,210 +وتعالى بيده القضاء في شؤون عباده وأنه صاحب الحكم + +235 +00:25:40,210 --> 00:25:47,410 +فيهم وله حق التشريع لهم وهو مصدر التشريع والتقنين + +236 +00:25:47,410 --> 00:25:53,070 +سبحانه وتعالى ولا يحق لهم ولا لأحد منهم أن يشرّع + +237 +00:25:53,070 --> 00:26:00,410 +غير شرعه سبحانه وتعالى أو أن يأمر أحد بالاتباع شرع + +238 +00:26:00,410 --> 00:26:06,430 +غير شرع الله تبارك وتعالى أو يأتمر هو بشرع غير شرع + +239 +00:26:06,430 --> 00:26:13,430 +الله سبحانه وتعالى فالحاكمية لله بمعنى أن الذي + +240 +00:26:13,430 --> 00:26:21,410 +يشرع أو أن الذي يُقنّنه للناس + +241 +00:26:21,410 --> 00:26:29,670 +هو الله تبارك وتعالى وأي تشريع وأي قانون يخالف ما + +242 +00:26:29,670 --> 00:26:36,770 +شرع الله فهو كفر والعياذ بالله كما سيأتي يخرجه عن + +243 +00:26:36,770 --> 00:26:43,670 +الملة وسنأتي الآن إلى الأدلة على ذلك ما هي الأدلة؟ + +244 +00:26:44,220 --> 00:26:50,440 +على أن الحاكمية لله وهنا ألفت أنظركم إلى شيء مهم + +245 +00:26:50,440 --> 00:26:55,340 +قد وقع فيه الطلاب من قبل أنهم في المصطلحات لا + +246 +00:26:55,340 --> 00:27:01,720 +يفرقون بين الحاكمية لله وبين الربانية لله الربانية + +247 +00:27:01,720 --> 00:27:11,840 +كما أسلفنا أولى خصائص النظم الإسلامية والربانية كما + +248 +00:27:11,840 --> 00:27:18,500 +قلنا إما ربانية المصدر وإما ربانية الغاية فعودوا + +249 +00:27:18,500 --> 00:27:25,220 +إلى ربانية المصدر وتعريفها أن أصول أحكامها ووصف + +250 +00:27:25,220 --> 00:27:31,180 +تشريعاتها مأخوذة من كتاب الله ومن سنة رسول الله + +251 +00:27:31,180 --> 00:27:37,120 +عليه الصلاة والسلام فبعض الطلاب يخلط فيضع مصطلح + +252 +00:27:37,120 --> 00:27:42,390 +الربانية محل الحاكمية ومصطلح الحاكمية محل + +253 +00:27:42,390 --> 00:27:49,510 +الربانية فخذوا حذركم ولا تقعوا فيما وقع فيه من + +254 +00:27:49,510 --> 00:27:56,070 +سبقكم فنحن نتكلم عن الحاكمية لله بمعنى أن المشرع + +255 +00:27:56,070 --> 00:28:01,830 +هو الله وأن الواضع للقوانين هو الله وليس سواه + +256 +00:28:01,830 --> 00:28:08,140 +سبحانه وتعالى أول هذه الأدلة وهي خمسة قوله تبارك + +257 +00:28:08,140 --> 00:28:13,720 +وتعالى إن الحكم إلا لله في صورة يوسف عليه السلام + +258 +00:28:13,720 --> 00:28:21,560 +إن الحكم إلا لله فلا حاكم إلا الله ولا مشرع إلا + +259 +00:28:21,560 --> 00:28:26,800 +الله سبحانه وتعالى ثانيا في صورة النساء قوله تبارك + +260 +00:28:26,800 --> 00:28:32,020 +وتعالى يريدون أن يتحكموا إلى الطاغوت وقد أمروا أن + +261 +00:28:32,020 --> 00:28:37,470 +يكفروا به يريد الشيطان أن يضلهم ضلالا بعيدا + +262 +00:28:37,470 --> 00:28:43,250 +فالتحاكم إلى الله وليس إلى الطاغوت والطاغوت و + +263 +00:28:43,250 --> 00:28:53,330 +الطواغيت كل طاغية لم يحكم بشرع الله كل حاكم أو + +264 +00:28:53,330 --> 00:29:01,550 +رئيس دولة لم يحكم بما شرع الله أو رسول الله في + +265 +00:29:01,550 --> 00:29:08,100 +الكتاب والسنة نعم وكلمة الطاغية والطواغيت أصلها + +266 +00:29:08,100 --> 00:29:13,260 +اللغوي من الفعل طغى وطغى في اللغة بمعنى تجاوز الحد + +267 +00:29:13,260 --> 00:29:18,320 +ومن قولهم تعالى في قصة نوح عليه السلام إِنَّا + +268 +00:29:18,320 --> 00:29:21,180 +لَمَّا طَغَى الْمَاءُ حَمَلْنَاكُمْ فِي + +269 +00:29:21,180 --> 00:29:26,600 +الْجَارِيَةِ إذا الطاغوت كل من تجاوز حدود الله + +270 +00:29:26,600 --> 00:29:34,270 +تبارك وتعالى ثالثا أيضا في صورة النساء وهذه الآية + +271 +00:29:34,270 --> 00:29:39,910 +لابد أن نقف عندها قليلا لأننا سنأتي إليها في آخر + +272 +00:29:39,910 --> 00:29:43,410 +المبحث + +273 +00:29:43,410 --> 00:29:52,250 +ولها قصة ذكرها العلامة المحدث ابن كثير في تفسيره + +274 +00:29:52,250 --> 00:29:53,850 +العظيم + +275 +00:29:55,600 --> 00:30:02,060 +ولكن لا نتعجل لأن هذه الآية ستأتي إجابة على سؤال + +276 +00:30:02,060 --> 00:30:10,860 +ما حكم من تحاكم إلى شرع غير شرع الله برضا وطواعية + +277 +00:30:10,860 --> 00:30:18,160 +نقول حكمه الكفر أولا والقتل لأنه مرتد عن شريعة + +278 +00:30:18,160 --> 00:30:25,480 +الإسلام وهذه هي الآية وسنأتي إليها تارة أخرى إن + +279 +00:30:25,480 --> 00:30:31,780 +شاء الله تبارك وتعالى فلا وربك رأيتم كيف جاء القسم + +280 +00:30:31,780 --> 00:30:37,840 +والقسم في لغة العرب عندما يأتي للدلالة على أهمية + +281 +00:30:37,840 --> 00:30:44,840 +وعظم وخطر الشيء المقسم به فالقسم لا يكون بأمر تافه + +282 +00:30:44,840 --> 00:30:51,480 +أو حقير أو صغير إنما يكون بشيء خطير أو عظيم فلا + +283 +00:30:51,480 --> 00:30:57,480 +وربك يعني يا محمد لا يؤمنون حتى يحكموك فيما شجر + +284 +00:30:57,480 --> 00:31:04,820 +بينهم ثم لا يجدوا في أنفسهم حرجا مما قضيت ويسلموا + +285 +00:31:04,820 --> 00:31:11,480 +تسليما نعم حتى لا يكفي الرضا + +286 +00:31:11,480 --> 00:31:20,060 +بالقضاء لأنه قد يرضى كارهًا إنما لابد من التسليم + +287 +00:31:20,060 --> 00:31:29,920 +ويسلموا تسليمة بمعنى الرضاء التام بشرع الله وبحكم + +288 +00:31:29,920 --> 00:31:36,100 +الله تبارك وتعالى وإلا لا يكون مؤمنًا يكون مرتدًا + +289 +00:31:36,100 --> 00:31:40,980 +قد خرج عن ملة الإسلام والعياذ بالله أما الدليل + +290 +00:31:40,980 --> 00:31:50,690 +الرابع فإن العقل السليم يقره أن الحاكمية لله سبحانه + +291 +00:31:50,690 --> 00:31:57,830 +وتعالى وكيف ذلك من خلال حقيقتين + +292 +00:31:57,830 --> 00:32:07,870 +ونخرج بالثالثة وهذه على طريقة علم المنطق أن نأتي + +293 +00:32:07,870 --> 00:32:15,820 +بقاعدتين وأن نخرج بقاعدة ثالثة أو بحقيقتين وأن + +294 +00:32:15,820 --> 00:32:24,040 +نأتي بحقيقة ثالثة ونحن نستعمل ذلك في الشريعة + +295 +00:32:24,040 --> 00:32:36,420 +الإسلامية أيضًا عندما نقول مثلًا الصلاة فرض كيف + +296 +00:32:36,420 --> 00:32:41,460 +عرفنا أن الصلاة فرض الله تبارك وتعالى يقول أقيم + +297 +00:32:41,460 --> 00:32:52,050 +الصلاة فأقيموا فعلوا أمر والأمر يفيد الوجوب فدل على + +298 +00:32:52,050 --> 00:33:00,130 +أن الصلاة واجبة وكذلك قوله تبارك وتعالى وآتوا + +299 +00:33:00,130 --> 00:33:06,810 +الزكاة آتوا أمر والأمر يفيد الوجوب فالزكاة واجبة + +300 +00:33:06,810 --> 00:33:15,280 +وكذلك مثلًا في الناهية ولا تقربوا الزنى لا تقربوا + +301 +00:33:15,280 --> 00:33:23,300 +نهي والنهي يفيد التحريم فالزنا حرام ولا تقتلوا + +302 +00:33:23,300 --> 00:33:28,160 +النفس ولا تأكلوا أموالكم بينكم بالباطل إلى غير ذلك + +303 +00:33:28,160 --> 00:33:35,480 +وكذلك هنا نقول هناك حقيقتين الحقيقة الأولى أن + +304 +00:33:35,480 --> 00:33:43,970 +الله هو الخالق وما أكثر الآيات على ذلك نقتصر + +305 +00:33:43,970 --> 00:33:49,370 +ببعضها مثل قوله تبارك وتعالى خلق كل شيء فقدره + +306 +00:33:49,370 --> 00:33:55,370 +تقديرًا والآيات عندكم في الكتاب والحقيقة الثانية أن + +307 +00:33:55,370 --> 00:34:01,470 +الله هو الرازق وما أكثر الآيات ومنها قوله تبارك + +308 +00:34:01,470 --> 00:34:07,810 +وتعالى وفي السماء رزقكم وما توعدون هنا نقول إذا + +309 +00:34:07,810 --> 00:34:13,560 +كان الله هو الخالق وإذا كان الله هو الرازق فإن الله + +310 +00:34:13,560 --> 00:34:19,940 +هو المالك فالمالك هو الحقيقة الثالثة أو الثمرة + +311 +00:34:19,940 --> 00:34:26,040 +التي نجمت عن الحقيقتين الأولى والثانية مرة ثانية + +312 +00:34:26,040 --> 00:34:31,370 +نقول إذا كان الله هو الخالق وإذا كان الله هو الرازق + +313 +00:34:31,370 --> 00:34:37,510 +فإن الله هو المالك ومعنى المالك أي أنه سبحانه + +314 +00:34:37,510 --> 00:34:43,650 +وتعالى هو المتصرف في ملكه كيف يشاء فأنت أيها + +315 +00:34:43,650 --> 00:34:51,030 +المخلوق لو كنت تملك مثلًا بيتًا فأنت حر التصرف فيه + +316 +00:34:51,030 --> 00:35:00,960 +لك مثلًا أن تبيعه ولك أن تنتفع به بالسكنى ولك أن + +317 +00:35:00,960 --> 00:35:10,580 +تؤجره ولك أن تهبه هبةً بدون مقابل ولك أيضًا أن تصدق + +318 +00:35:10,580 --> 00:35:15,700 +به أو أن توقفه إذا أنت أيها المخلوق الصغير من خلق + +319 +00:35:15,700 --> 00:35:21,440 +الله إذا كنت تملك شيئًا فأنت حر التصرف فيه ما بين + +320 +00:35:21,440 --> 00:35:29,460 +بيع وسكنى وإيجارة وهبة ووقف وصدقة إلى غير ذلك + +321 +00:35:29,460 --> 00:35:33,720 +ولله المثل الأعلى إذا كان الله هو المالك فهو + +322 +00:35:33,720 --> 00:35:39,460 +المتصرف في ملكه وفي خلقه كيف شاء لأنه الذي خلقهم + +323 +00:35:39,460 --> 00:35:46,580 +فالإنسان خلق الله وصنعة الله وبنيان الرب تبارك + +324 +00:35:46,580 --> 00:35:52,680 +وتعالى وهو أدرى بهم كما مثلنا في بداية المساق + +325 +00:35:52,680 --> 00:35:59,520 +عندما تكلمنا عن النظم الإسلامية وقلنا بأن مصدرها + +326 +00:35:59,520 --> 00:36:05,780 +هو الله تبارك وتعالى ومثلنا بذلك في صانع الآلة + +327 +00:36:05,780 --> 00:36:13,010 +والكتالوج فالـ Catalogue فيه ما يصلح الآلة والصانع + +328 +00:36:13,010 --> 00:36:19,290 +الذي صنع الآلة هو أدرى بما يصلحها إذا فسدت ولله + +329 +00:36:19,290 --> 00:36:23,390 +المثل الأعلى خلق هذا الإنسان وأنزل معه ال + +330 +00:36:23,390 --> 00:36:30,410 +كتالوج إيه هو الـ Catalogue؟ القرآن الكريم فإما + +331 +00:36:30,410 --> 00:36:38,170 +يأتينكم مني هدا فمن اتبع هدايا فلا يضل ولا يشقى ومن + +332 +00:36:38,170 --> 00:36:43,750 +أعرض عن ذكري فإن له معيشة ضنكة ونحشره يوم القيامة + +333 +00:36:43,750 --> 00:36:48,870 +أعمى قال رب ليه محشرتني أعمى وقد كنت بصيرًا قال + +334 +00:36:48,870 --> 00:36:54,510 +كذلك أتتك آيتنا فنسيتها وكذلك اليوم تنسى الآية في + +335 +00:36:54,510 --> 00:37:04,290 +صورة طه نعم إذا الدليل الرابع على أن الحاكمية + +336 +00:37:04,290 --> 00:37:12,580 +لله من خلال حقيقتينِه الحقيقة الأولى أن الخالق هو + +337 +00:37:12,580 --> 00:37:18,860 +الله والحقيقة الثانية أن الرازق هو الله فنقول وفق + +338 +00:37:18,860 --> 00:37:24,660 +علم المنطق إذا كان الله هو الخالق وإذا كان الله هو + +339 +00:37:24,660 --> 00:37:29,420 +الرازق نخرج من ذلك بحقيقة ثالثة أن الله هو المالك + +340 +00:37:29,420 --> 00:37:38,200 +بمعنى المتصرف سبحانه وتعالى في خلقه وفي عباده فهو + +341 +00:37:38,200 --> 00:37:45,980 +أدرى بما يصلحهم سبحانه وتعالى ولذلك له أن يشرع + +342 +00:37:45,980 --> 00:37:52,400 +لهم ما يشاء عز وجل أما خامسًا لا إله إلا الله تقرر + +343 +00:37:52,400 --> 00:38:02,060 +أن الحاكمية لله لا إله إلا الله أولًا هي عبارة عن + +344 +00:38:02,060 --> 00:38:13,000 +شقينِ الشق الأول نفي مطلق لا إله والشق الثاني إثبات + +345 +00:38:13,000 --> 00:38:21,300 +مطلق إلا الله لا إله نفي مطلق نفت كل إله إلا الله + +346 +00:38:21,300 --> 00:38:30,830 +إثبات مطلق أثبتت الألوهية لله وأن الحاكمية لله + +347 +00:38:30,830 --> 00:38:37,470 +ومعنى لا إله إلا الله لا معبود بحق في الوجود سواء + +348 +00:38:37,470 --> 00:38:44,870 +كان الله سبحانه وتعالى ومن ثم الحاكمية لله عز وجل + +349 +00:38:44,870 --> 00:38:53,030 +وكذلك نقول هنا لابد من التفريق بين كلمة إله وبين + +350 +00:38:53,030 --> 00:39:00,410 +كلمة الله فكلمة الله هي لا تُطلق إلا على الله + +351 +00:39:00,410 --> 00:39:06,250 +سبحانه وتعالى ولذلك لابد أن تُكتب باللغة الأجنبية + +352 +00:39:06,250 --> 00:39:16,350 +الله وهذا للأسف ما أخطأ فيه الذين ترجموا معاني + +353 +00:39:16,350 --> 00:39:21,490 +القرآن الكريم ولا أقول القرآن الكريم لأننا لما + +354 +00:39:21,490 --> 00:39:25,110 +تكلمنا عن المصدر الأول من مصادر النظم الإسلامية + +355 +00:39:25,110 --> 00:39:33,070 +القرآن الكريم تكلمنا عن خصائصه أنه لا يترجم حتى ولو + +356 +00:39:33,070 --> 00:39:39,280 +كانت الترجمة دقيقة جدًا لأن الترجمة من كلام البشر + +357 +00:39:39,280 --> 00:39:45,800 +والقرآن كلام الله المعجز المتعبد بتلاوته سبحانه + +358 +00:39:45,800 --> 00:39:53,440 +وتعالى من أجل ذلك قال الفصحاء والبلغاء ترجمت معاني + +359 +00:39:53,440 --> 00:39:58,600 +لفظ القرآن الكريم وهذا من أدق لكن عندما ننظر إلى + +360 +00:39:58,600 --> 00:40:04,820 +الشاشة ونحن نستمع إلى القرآن من خلال التلفاز نقرأ + +361 +00:40:04,820 --> 00:40:16,180 +كلمة الله بمعنى إله يعني جد وهذا خطأ فلابد أن تُكتب + +362 +00:40:16,180 --> 00:40:23,320 +الله الله هكذا باللغة الأجنبية وكلمة إله بمعنى جد + +363 +00:40:23,320 --> 00:40:31,160 +لأن كلمة إله تشمل كل إله حتى ولو كان من البشر مثل + +364 +00:40:31,160 --> 00:40:39,650 +فرعون أو كان من الحجر والشجر مثل أصنام قريش هبل و + +365 +00:40:39,650 --> 00:40:45,070 +العزة ومناة وغيرها حتى الهوى كما سيأتي في القرآن + +366 +00:40:45,070 --> 00:40:50,810 +يكونوا إلهًا فرأيت من اتخذ إلهًا هو هو إذا لابد من + +367 +00:40:50,810 --> 00:40:56,230 +التفريق بين كلمة إله وبين كلمة الله الله لا يطلق + +368 +00:40:56,230 --> 00:41:02,400 +إلا على الله ولذلك قلنا لا إله إلا الله نفد كل إله + +369 +00:41:02,400 --> 00:41:09,480 +من البشر ومن الشجر ومن الحجر حتى القوانين والأنظمة + +370 +00:41:09,480 --> 00:41:15,180 +الوضعية هي أيضًا آلهة إذا ما طبقت عُبِدَت من دون + +371 +00:41:15,180 --> 00:41:20,920 +الله عز وجل لا إله إلا الله لا مشرع إلا الله لا + +372 +00:41:20,920 --> 00:41:28,440 +حاكم إلا الله سبحانه وتعالى نأتي إلى الكتاب كلمة + +373 +00:41:28,440 --> 00:41:34,060 +الصنم يُطلق عليه إله كما في قصة إبراهيم وإذ قال + +374 +00:41:34,060 --> 00:41:40,160 +إبراهيم لأبيه آزر أتتخذ أصنامًا آلهة فالأصنام قد + +375 +00:41:40,160 --> 00:41:46,100 +تكون آلهة من دون الله وهو الإنسان أفرأيت من اتخذ + +376 +00:41:46,100 --> 00:41:53,180 +إلهه هوَ والبشر كما في قصة فرعون ما علمت لكم من إله + +377 +00:41:53,180 --> 00:42:02,090 +غيره هكذا لا إله إلا الله فعلم أنه لا إله إلا الله + +378 +00:42:02,090 --> 00:42:10,690 +فكلمة الله لا تطلق إلا على الله الخالق الرازق وحده + +379 +00:42:10,690 --> 00:42:16,810 +سبحانه وتعالى وعليه فعندما نقول لا إله نفي المطلق + +380 +00:42:16,810 --> 00:42:22,010 +نكون قد نفينا الألوهية عن كل معبود على الإطلاق سوى + +381 +00:42:22,010 --> 00:42:27,340 +الله وعندما نقول إلا الله إثبات المطلق نكون قد + +382 +00:42:27,340 --> 00:42:33,360 +أثبتنا الألوهية لله وحده وعز وجل وحصرناها فيه دون + +383 +00:42:33,360 --> 00:42:43,280 +غيره سبحانه وتعالى نعم إذا كل هذه الأدلة دليل على + +384 +00:42:43,280 --> 00:42:51,860 +أن الحاكمية لله طب أعداء الإسلام وموقفهم من + +385 +00:42:51,860 --> 00:43:00,440 +الحاكمية المشكلة أن هؤلاء المشركون يؤمنون بالله + +386 +00:43:00,440 --> 00:43:10,240 +ولكن يكفرون بأن الحاكمية لله ولذلك سمي هؤلاء + +387 +00:43:10,240 --> 00:43:15,280 +بالمشركين لأنهم يؤمنون بالله ويعبدون مع الله آلهة + +388 +00:43:15,280 --> 00:43:21,240 +أخرى وعندما سؤلوا قالوا إنما نعبدهم ليقربون إلى + +389 +00:43:21,240 --> 00:43:28,880 +الله ذلفة يعبدون آلهة الأرض من أوثان وأصنام + +390 +00:43:28,880 --> 00:43:36,000 +صنعوها بأيديهم حتى من العجوة كما كانوا يفعلون كما + +391 +00:43:36,000 --> 00:43:39,460 +فعل سيدنا عمرو لما ضحك يومًا وسُئل لماذا ضحكت يا + +392 +00:43:39,460 --> 00:43:43,780 +أمير المؤمنين قال أهدى لي خالي في الجاهلية صنمًا من + +393 +00:43:43,780 --> 00:43:51,110 +عجوة فلما جعت أكلته هكذا كانت آلهة أهل الجاهلية + +394 +00:43:51,110 --> 00:44:00,710 +تؤكل وتكسر ويصنع غيرها من الحجر ومن الشجر و + +395 +00:44:00,710 --> 00:44:05,170 +لذلك كانوا يؤمنون بأن الله هو الخالق وبأن الله هو + +396 +00:44:05,170 --> 00:44:10,810 +الرازق وبأن الله هو القادر سبحانه وتعالى و + +397 +00:44:10,810 --> 00:44:16,470 +المتصرف كما مثلًا في هذه الآية قل من يرزقكم من + +398 +00:44:16,470 --> 00:44:21,350 +السماء والأرض أما يملك السمع والأبصار ومن يخرج + +399 +00:44:21,350 --> 00:44:26,110 +الحي من الميت ويخرج الميت من الحي ومن يدبر أمره + +400 +00:44:26,110 --> 00:44:31,950 +فسيقولون الله فقل أفلا تتقون هذا هو حال المشركين + +401 +00:44:31,950 --> 00:44:41,610 +في الجاهلية بل إن أبا جهل في غزوة بدر يعتقد أن الله + +402 +00:44:41,610 --> 00:44:47,430 +هو الناصر والمعين حيث طلب العون والنصرة من الله + +403 +00:44:47,430 --> 00:44:52,790 +سبحانه وتعالى وهو القائل الله منصر أعلى الجندين + +404 +00:44:52,790 --> 00:44:58,790 +وأكرم القبيلتين فاستجاب الله له فكان محمد عليه + +405 +00:44:58,790 --> 00:45:04,310 +الصلاة والسلام هو أعلى الجندين وأكرم القبيلتين + +406 +00:45:04,310 --> 00:45:09,170 +وهذا معنى قوله تعالى في صورة الأنفال إن تستفتحوا + +407 +00:45:09,170 --> 00:45:15,710 +فقد جاءكم الفتح وإن تنتهوا فهو خير لكم وإن تعودوا + +408 +00:45:15,710 --> 00:45:22,810 +نعود فلن تغني عنكم فئتكم شيء ولو كثرت وأن الله مع + +409 +00:45:22,810 --> 00:45:30,750 +المؤمنين وهو الشعر العربي صهير بن أبي سلم يقول فلا + +410 +00:45:30,750 --> 00:45:36,350 +تكتمن الله ما في نفوسكم ليخفى ومهما يكتم الله + +411 +00:45:36,350 --> 00:45:44,000 +يعلم فهو يؤمن بأن الله عالم بالصرائر والخفايا و + +412 +00:45:44,000 --> 00:45:49,240 +أنه يعلم ما في نفوسهم بل إن عنترة بن شداد وهو + +413 +00:45:49,240 --> 00:45:57,220 +الشاعر الجاهلي يخاطب محبوبته عبلة ويقول يا عبل + +414 +00:45:57,220 --> 00:46:02,900 +أين من المنية مهرب إن كان ربي في السماء خضها فكل + +415 +00:46:02,900 --> 00:46:08,070 +هذا وذاك يدل على أنهم كانوا يؤمنون بالله وبأنه + +416 +00:46:08,070 --> 00:46:14,230 +الخالق وبأنه الرازق وبأنه العالم بنفوسهم وأسرارهم + +417 +00:46:14,230 --> 00:46:20,310 +وخفاياهم ولكنهم كانوا يعبدون الأصنام يتقربون إلى + +418 +00:46:20,310 --> 00:46:25,130 +الله حتى تشفى عليهم هذا معنى قوله تعالى والله أعلى + +419 +00:46:25,130 --> 00:46:30,710 +وأعلم ما نعبدهم إلا ليقربون إلى الله ذلفة وقوله + +420 +00:46:30,710 --> 00:46:38,560 +هؤلاء شفعاؤنا عند الله سبحانه وتعالى أما موقف + +421 +00:46:38,560 --> 00:46:43,780 +المؤمنين من الحاكمية لله فهو كما وصفهم الله في + +422 +00:46:43,780 --> 00:46:50,960 +أكثر من موضع سمعنا وأطعنا غفرانك ربنا وإليك المصير + +423 +00:46:50,960 --> 00:46:57,680 +نعم أو كما قال الله هنا في قوله تبارك وتعالى إنما + +424 +00:46:57,680 --> 00:47:02,690 +كان قول المؤمنين إذا دعوا إلى الله ورسوله ليحكم + +425 +00:47:02,690 --> 00:47:09,070 +بينهم أن يقولوا سمعنا وأطعنا وأولئك هم المفلحون + +426 +00:47:09,070 --> 00:47:14,910 +فالمؤمن إذا سمع الله يقول يا أيها الذين أمنوا سواء + +427 +00:47:14,910 --> 00:47:21,230 +في الأمر يمتثل أو في النهي يجتنب حال لسانه يقول + +428 +00:47:21,230 --> 00:47:27,870 +سمعنا وأطعنا فالله ورسوله أحب إليه من + +429 +00:47:31,810 --> 00:47:38,810 +أبائه وأمه وولده والناس أجمعين كما جاء في الحديث + +430 +00:47:38,810 --> 00:47:44,670 +في غير هذا الكتاب لا يؤمن أحدكم حتى أكون أحب إليه + +431 +00:47:44,670 --> 00:47:51,290 +من والده وولده والناس أجمعين نأتي الآن إلى حكم من + +432 +00:47:51,290 --> 00:47:58,040 +أخطر الأحكام حكم من لم يرضى بحكم الله تبارك وتعالى + +433 +00:47:58,040 --> 00:48:05,100 +هنا أولا والعياذ بالله الكفر لأنها جاءت في آيات + +434 +00:48:05,100 --> 00:48:11,520 +متواليات في صورة المائدة ومن لم يحكم بما أنزل الله + +435 +00:48:11,520 --> 00:48:16,560 +فأولئك هم الكافرون ومن لم يحكم بما أنزل الله + +436 +00:48:16,560 --> 00:48:20,700 +فأولئك هم الظالمون ومن لم يحكم بما أنزل الله + +437 +00:48:20,700 --> 00:48:29,250 +فأولئك هم الفاسقون فهم كافرون وظالمون وفاسقون فالذي + +438 +00:48:29,250 --> 00:48:38,110 +يرفض أن يحكم بما أنزل الله كافر ظالم فاسق والعياذ + +439 +00:48:38,110 --> 00:48:43,710 +بالله فهو كافر قد خرج عن ملة الإسلام + +440 +00:48:47,710 --> 00:48:52,670 +ما هي نتائج الحكم بغير ما أنزل الله؟ طبعا ما نراه + +441 +00:48:52,670 --> 00:49:00,530 +اليوم من سيطرة الكفار على المسلمين فأصبحت أمريكا + +442 +00:49:00,530 --> 00:49:07,810 +هي فرعون هذا العصر الأمر أناهي وكأنها تقول ما علمت + +443 +00:49:07,810 --> 00:49:14,740 +لكم من إله غيري؟ نعم هذا هو حال فرعون العصر التي + +444 +00:49:14,740 --> 00:49:20,980 +تكلمنا عنها العولمة أن نكون نحن المسلمون وفق + +445 +00:49:20,980 --> 00:49:27,340 +الرؤية الصهيو أمريكية أو أن نكون تحت إبط اليهود + +446 +00:49:27,340 --> 00:49:35,560 +والأمريكان والعم سام فالعزة والكرامة للمسلمين إنما + +447 +00:49:35,560 --> 00:49:41,150 +تكون بالإسلام كما قال سيدنا عمرو بن الخطاب اللي أبي + +448 +00:49:41,150 --> 00:49:46,190 +عبيدة بن الجراح لقد كنا أذلاء في الجاهلية فأعزنا + +449 +00:49:46,190 --> 00:49:51,850 +الله بالإسلام ومن يبتغي العزة من غير الإسلام أذله + +450 +00:49:51,850 --> 00:49:56,850 +الله تبارك الله وما حل بالمسلمين من ذلة وهوان كما + +451 +00:49:56,850 --> 00:50:01,590 +نرى في هذه الأيام إلا بسبب بعضهم عن مصدر عزتهم + +452 +00:50:01,590 --> 00:50:06,350 +ومنبع كرامتهم الكتاب والسنة وكما قال الإمام مالك + +453 +00:50:07,210 --> 00:50:11,930 +رضي الله عنه ورحمة الله عليه لن يصلح آخر هذه الأمة + +454 +00:50:11,930 --> 00:50:20,650 +إلا بما صلح به أولها هل صلح أولها بالشيوعية أو + +455 +00:50:20,650 --> 00:50:25,730 +بالقومية أو الوطنية أو العلمانية؟ لا، ولا + +456 +00:50:25,730 --> 00:50:30,970 +بالرأسمالية أيضا صلح أولها بالإسلام ولن يصلح + +457 +00:50:30,970 --> 00:50:35,730 +آخرها إلا بالإسلام فعمر بن الخطاب فتح فلسطين + +458 +00:50:35,730 --> 00:50:40,150 +بالإسلام وصلاح الدين الأيوبي حرر فلسطين بالإسلام + +459 +00:50:40,150 --> 00:50:45,930 +وهو ليس عربيا بل من أكراد العراق في الشمال هناك + +460 +00:50:45,930 --> 00:50:57,030 +على مقربة من تركيا نعم هكذا هو الإسلام العظيم مصدر + +461 +00:50:57,030 --> 00:51:00,450 +عزتنا وكرامتنا إن شاء الله نأتي الآن إلى السؤال + +462 +00:51:00,450 --> 00:51:04,730 +الأخير عقوبة التحاكم إلى غير شرع الله قلت لكم + +463 +00:51:04,730 --> 00:51:11,650 +سنعود إلى هذه الآية الجريمة آية 65 فافهموها ولا + +464 +00:51:11,650 --> 00:51:20,020 +أقول فاحفظوها جيدا فلا وربك لا يؤمنون نفتي الإيمان + +465 +00:51:20,020 --> 00:51:26,140 +عن كل من لم يحتكم إلى شرع الله أو يرضى بشرع الله + +466 +00:51:26,140 --> 00:51:32,900 +عز وجل فلا وربك لا يؤمنون هكذا بصيغة القسم برب + +467 +00:51:32,900 --> 00:51:37,000 +محمد عليه الصلاة والسلام حتى يحكموك يا محمد في + +468 +00:51:37,000 --> 00:51:41,680 +مشاجر بينهم فيما اختلفوا فيه ثم لا يجدوا في أنفسهم + +469 +00:51:41,680 --> 00:51:50,020 +حرجا مما قضيت ويسلموا تسليمة ونريد هنا أن نذكر سبب + +470 +00:51:50,020 --> 00:51:56,620 +النزول كما ذكره ابن كثير في التفسير وملخص هذه + +471 +00:51:56,620 --> 00:52:03,860 +القصة أن مسلما والحقيقة أنه تبين لم يكن من + +472 +00:52:03,860 --> 00:52:10,000 +المسلمين المنافق المدسوس في صفوف المسلمين والعياذ + +473 +00:52:10,000 --> 00:52:15,740 +بالله وآخرين من دونهم لا تعلمونهم الله يعلمهم لا + +474 +00:52:15,740 --> 00:52:21,140 +إله هؤلاء ولا إله هؤلاء إلى هؤلاء بوجه وإلى هؤلاء + +475 +00:52:21,140 --> 00:52:25,500 +بوجه والعياذ بالله وإذا لقوا الذين آمنوا قالوا + +476 +00:52:25,500 --> 00:52:30,180 +آمنا وإذا خلوا إلى شياطينهم قالوا إنا معكم إنما + +477 +00:52:30,180 --> 00:52:38,580 +نحن مستهزئون فهذا المسلم اختلف مع يهودي فأراد + +478 +00:52:38,580 --> 00:52:46,360 +المسلم أن يحتكم إلى أحبار اليهود لأن الحبر اليهودي + +479 +00:52:46,360 --> 00:52:52,910 +يرتشهويحكم بغير الحق وأراد هذا اليهودي أن يحتكم + +480 +00:52:52,910 --> 00:52:57,170 +إلى محمد بن عبد الله إلى رسول الله عليه الصلاة + +481 +00:52:57,170 --> 00:53:02,590 +والسلام لأن رسول الله يحكم بالعدل لا يفرق بين مصمم + +482 +00:53:02,590 --> 00:53:08,590 +والكافر وقد مر بنا وسيأتي عند الكلام عن القاعدة + +483 +00:53:08,590 --> 00:53:13,270 +الثانية العدل والمساواة كيف أن العدل في الإسلام + +484 +00:53:13,270 --> 00:53:19,680 +مطلق لا يتأثر بالهوى ولا يتأثر بالدين كما سنأتي + +485 +00:53:19,680 --> 00:53:28,080 +إلى آيتين أي 135 من سورة النساء وآية تمانية من + +486 +00:53:28,080 --> 00:53:32,540 +سورة المائدة ولا يجرمنكم شنآن قوم على أن لا + +487 +00:53:32,540 --> 00:53:36,740 +تعدلوا اعدلوا واقربوا للتقوى حتى ولو كان يهوديا + +488 +00:53:36,740 --> 00:53:43,860 +أو مصريا أو مجوسيا أو كافرا نعم فهنا انطلق هذا + +489 +00:53:43,860 --> 00:53:49,160 +المسلم المنافق واليهودي إلى الرسول فحكم الرسول + +490 +00:53:49,160 --> 00:53:54,850 +لليهودي لأن الحق كان مع اليهودي فغضب هذا المسلم و + +491 +00:53:54,850 --> 00:54:01,930 +قال لنحتكم إلى أبي بكر فحكم أبو بكر لليهودي كما + +492 +00:54:01,930 --> 00:54:07,850 +حكم رسول الله لأن الحق مع اليهودي وكانت نهاية هذا + +493 +00:54:07,850 --> 00:54:12,330 +المنافق على يد عمرو بن الخطاب جبار الجاهلية و + +494 +00:54:12,330 --> 00:54:17,550 +الإسلام فقال هذا المنافق نحتكم إلى عمرو بن الخطاب + +495 +00:54:17,550 --> 00:54:26,380 +فقال هل حكم رسول الله؟ قال له نعم وحكم لأبي بكر + +496 +00:54:26,380 --> 00:54:33,320 +حكم ليه؟ فقال نعم أحكم بينكما بكتاب الله وسنة رسول + +497 +00:54:33,320 --> 00:54:38,040 +الله صلى الله عليه وسلم فعاد إلى بيته وسل سيفه + +498 +00:54:38,040 --> 00:54:44,780 +وقطع رأس هذا المنافق فالنبي عليه السلام قال باء + +499 +00:54:44,780 --> 00:54:52,270 +عمرو بدم الرجل بقي عمر بدم الرجل يحسبه مسلمًا فنزلت + +500 +00:54:52,270 --> 00:54:57,390 +الآيات تذكر لرسول الله أن هذا المسلم ليس بمسلم بل + +501 +00:54:57,390 --> 00:55:04,910 +منافق وهو مرتد وحكمه ضربة بالسيف ولياز بالله وأن + +502 +00:55:04,910 --> 00:55:09,850 +يقتل لأنه لم يمتثل لحكم الله ونزلت هذه الآية + +503 +00:55:09,850 --> 00:55:15,350 +الكريمة 65 من سورة النساء فلا وربك لا + +504 +00:55:15,350 --> 00:55:21,450 +يؤمنون حتى يحكموك فيما شجر بينهم ثم لا يجدوا في + +505 +00:55:21,450 --> 00:55:27,230 +أنفسهم حرجا مما قضيت ويسلموا تسليما ختامها مسك + +506 +00:55:27,230 --> 00:55:31,730 +قول الله تبارك وتعالى وصل اللهم علي سيدنا محمد + +507 +00:55:31,730 --> 00:55:35,750 +أقول قولي هذا وأستغفر الله لكم والسلام عليكم + +508 +00:55:35,750 --> 00:55:39,730 +ورحمة الله وبركاته إن شاء الله المحاضرة التالية + +509 +00:55:39,730 --> 00:55:46,850 +الأخيرة تكون في الثلاثة البقية الأربعة العدل والمثوى + +510 +00:55:46,850 --> 00:55:53,570 +والشورى والطاعة وبهذا نكون قد ختمنا المقرر أما + +511 +00:55:53,570 --> 00:55:57,750 +المباحث الثلاثة الأخرى الدولة وما بعدها من الفصل + +512 +00:55:57,750 --> 00:56:03,230 +السادس فليست مقررة عليكم ولا مطلوبة في الامتحان + +513 +00:56:03,230 --> 00:56:09,270 +وإلى لقاء ولا أقول وداعا بل السلام عليكم ورحمة + +514 +00:56:09,270 --> 00:56:10,390 +الله وبركاته diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/nEocub7RWbU_postprocess.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/nEocub7RWbU_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..40dd7e9d18b950f8e907a97147344814d78bb2eb --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/nEocub7RWbU_postprocess.srt @@ -0,0 +1,2056 @@ +1 +00:00:04,980 --> 00:00:07,700 +أعوذ بالله السماء العلي من الشيطان الرجيم بسم الله + +2 +00:00:07,700 --> 00:00:10,880 +الرحمن الرحيم الحمد لله والصلاة والسلام على رسول + +3 +00:00:10,880 --> 00:00:14,720 +الله دائما و أبدا نعطر مجالسنا بالصلاة على الحبيب + +4 +00:00:14,720 --> 00:00:20,140 +محمد صلى الله عليه وسلم أما بعد قبل ذي بدء أعزائي + +5 +00:00:20,140 --> 00:00:23,960 +الطلاب أرحب بكم جميعا و أحييكم بتحية الإسلام + +6 +00:00:23,960 --> 00:00:28,820 +العظيم فسلام الله عليكم ورحمته وبركاتهاليوم ان شاء + +7 +00:00:28,820 --> 00:00:33,960 +الله وبعون الله وبمدد من عند الله نكون على موعد مع + +8 +00:00:33,960 --> 00:00:38,820 +الفصل الأخير من فصول مساق النظم الإسلامية وهو + +9 +00:00:38,820 --> 00:00:45,420 +بعنوان النظام السياسي في الإسلام وهو عبارة عن خمسة + +10 +00:00:45,420 --> 00:00:54,050 +مباحث بأن هذا الفصل ليس مطلوبا كلهالمطلوب فقط هو + +11 +00:00:54,050 --> 00:01:00,490 +مبحثاني من خمسة المبحث الأول والثاني المبحث الأول + +12 +00:01:00,490 --> 00:01:06,390 +بعنوان تعريف النظم طبعا عند المسلمين وعند غير + +13 +00:01:06,390 --> 00:01:15,570 +المسلمين والفروق بينهما والمبحث الثاني وهو مهم جدا + +14 +00:01:15,570 --> 00:01:24,980 +وهو طويلوهو عبارة عن أربعة قواعد القواعد الأربعة + +15 +00:01:24,980 --> 00:01:30,000 +التي يقوم عليها النظام السياسي في الإسلام بدءًا + +16 +00:01:30,000 --> 00:01:34,220 +بالحاكمية ومرورًا بالعدل والمثاوات والشورى + +17 +00:01:34,220 --> 00:01:41,620 +وانتهاءًا بالطاعة نبدأ بالمبحث الأول على بركة الله + +18 +00:01:41,620 --> 00:01:50,000 +سياسة في اللغةأولا قبل النالجة في الكتاب أصل + +19 +00:01:50,000 --> 00:01:57,040 +السياسة في لغة العرب من سياسة الخيل بمعنى ترويضها + +20 +00:01:57,040 --> 00:02:04,940 +وسحب الأمر من سياسة الخيل بمعنى ترويضها إلى سياسة + +21 +00:02:04,940 --> 00:02:12,880 +الآدمين والسياسة في لغة العرب من الفعل ساس الأمر + +22 +00:02:12,880 --> 00:02:20,360 +إذا قام بهوهي القيام على الشيء بما يصلحه كما جاء + +23 +00:02:20,360 --> 00:02:26,620 +في الحديث الشريف كان بني إسرائيل يسوسهم أنبياءهم + +24 +00:02:26,620 --> 00:02:30,100 +فأنبياء + +25 +00:02:30,100 --> 00:02:39,100 +بني إسرائيل في الكثرة بمنزلة علمائنا نحن أمة + +26 +00:02:39,100 --> 00:02:45,940 +الإسلاموهذه ملحوظة قد يجهلها كثير من الناس عندما + +27 +00:02:45,940 --> 00:02:52,580 +يظنون أن كثرة أنبياء بني إسرائيل هي مدح لبني + +28 +00:02:52,580 --> 00:02:59,080 +إسرائيل والجواب على العكس تماما إن كثرة أنبيائهم + +29 +00:02:59,080 --> 00:03:07,680 +دليل على ذنبهم لأن كثرة الأمراض تحتاج إلى كثرة + +30 +00:03:07,680 --> 00:03:15,870 +الأطباءكلما كثرت الأمراض والأوبئة في بلد انما تكثر + +31 +00:03:15,870 --> 00:03:24,870 +الأطباء لكن إذا قلت الأوبئة والأمراض فيكفي البلدة + +32 +00:03:24,870 --> 00:03:33,450 +طبيب واحد ولمّا كثرت مفاسد بني إسرائيل كثرت + +33 +00:03:33,450 --> 00:03:41,000 +أنبياءهم فأنبياء بني إسرائيل في الكثرةكعلماء أمة + +34 +00:03:41,000 --> 00:03:46,420 +محمد صلى الله عليه وسلم الذين هم بعد الله وبعد + +35 +00:03:46,420 --> 00:03:53,600 +الملائكة شهد الله أنه لا إله إلا هو والملائكة + +36 +00:03:53,600 --> 00:04:00,860 +وأولو العلم قائما بالقصد بدأ الله بنفسهو ثنى + +37 +00:04:00,860 --> 00:04:08,540 +بملائكته و ختم بأولي العلم الذين رفعهم الله درجات + +38 +00:04:08,540 --> 00:04:12,320 +يرفع الله الذين آمنوا منكم و الذين أوتوا العلم + +39 +00:04:12,320 --> 00:04:18,620 +درجات فالعلماء في أمة الإسلام ورثته الأنبياء نعود + +40 +00:04:18,620 --> 00:04:24,100 +إلى هذا الحديث كان بنوا إسرائيل يسوسهم أنبياءهم + +41 +00:04:24,100 --> 00:04:34,030 +بمعنى يصلحون شؤونهمويتولون أمورهم ويتدبرونها فهم + +42 +00:04:34,030 --> 00:04:42,810 +بمنزلة العلماء والسياسة في الاصطلاح لها تعريفات + +43 +00:04:42,810 --> 00:04:46,070 +ثلاثة + +44 +00:04:46,070 --> 00:04:56,070 +عند المسلمين وتعريفات ثلاثة عند غير المسلمين أما + +45 +00:04:56,070 --> 00:05:04,130 +عند المسلمينفالتعريف الأول وهو أحسنها وأجمعها وهو + +46 +00:05:04,130 --> 00:05:09,680 +تعريف ابن عقيل الحنباليكما ذكره ابن قيم الجوزية في + +47 +00:05:09,680 --> 00:05:16,560 +السياسة الشرعية السياسة ما كان فعلا يكون معاه + +48 +00:05:16,560 --> 00:05:22,060 +الناس أقرب إلى الصلاح وأبعد عن الفساد وإن لم يضاعه + +49 +00:05:22,060 --> 00:05:27,920 +الرسول صلى الله عليه وسلم ولا نزل به وحي هذا هو + +50 +00:05:27,920 --> 00:05:37,830 +معنى السياسة بمعنى أنه لا يشترط في كل حكمأن يكون + +51 +00:05:37,830 --> 00:05:46,610 +فيه قرآن أو سنة فلولي الأمر أن يجتهد وكما تقول + +52 +00:05:46,610 --> 00:05:52,530 +القاعدة الشرعية تصرف الإمام على الرعية منوط + +53 +00:05:52,530 --> 00:06:00,070 +بالمصلحة و لكل زمان و مكان و أشخاص كما مر بنا في + +54 +00:06:00,070 --> 00:06:08,100 +السبات والمرونة فتوة نعم فالأحكامتتغير بتغير + +55 +00:06:08,100 --> 00:06:15,860 +الزمان والمكان والأشخاص وفق الأعراف والتقاليد + +56 +00:06:15,860 --> 00:06:23,660 +والعادات ولعلنا قد أشرنا إلى ذلك سريعا عندما + +57 +00:06:23,660 --> 00:06:28,580 +تكلمنا عن مصادر النظم الإسلامية وقلنا يومها + +58 +00:06:28,580 --> 00:06:35,330 +المصادر نوعان مصادر متفق عليها وهي المقصودةفي + +59 +00:06:35,330 --> 00:06:39,790 +المثاق وهي المطلوبة في الامتحان وهي أربعة القرآن + +60 +00:06:39,790 --> 00:06:48,070 +والسنة والإجماع والقياس ولكن قلنا هناك مصادر مختلف + +61 +00:06:48,070 --> 00:06:54,730 +عليها بمعنى أخذ بها بعض الأئمة وتركها بعض الأئمة + +62 +00:06:54,730 --> 00:07:02,830 +فمثلا الحنفية أخذوا بالاستحسان والشافعية أخذوا + +63 +00:07:02,830 --> 00:07:10,390 +بالاستصحابوالمالكيته أخذه بعمل + +64 +00:07:10,390 --> 00:07:16,710 +أهل المدينة فعمل أهل المدينة يعتبر مصدرا من مصادر + +65 +00:07:16,710 --> 00:07:24,330 +التشريه عند الإمام مالكين وهناك أيضا من المصادر + +66 +00:07:24,330 --> 00:07:30,720 +المختلف عليها المصالح المرسلةوالمرسلة بمعنى + +67 +00:07:30,720 --> 00:07:39,200 +المطلقة أي التي لم يتنزل فيها وحي ولم يضعه الرسول + +68 +00:07:39,200 --> 00:07:44,880 +صلى الله عليه وسلم وما أكثر المسائلة في هذا الزمان + +69 +00:07:44,880 --> 00:07:56,080 +حيث يتطور و لكل دولة و لكل عصر دولة ورجال هذا + +70 +00:07:56,080 --> 00:08:03,200 +باختصار معنىالحديث فلو قال أحدهم هاتي بدليل على + +71 +00:08:03,200 --> 00:08:09,830 +مشروعية السيارة فهذه السيارة كان مثلها الدوابأعزكم + +72 +00:08:09,830 --> 00:08:14,810 +الله نعم فهذا من باب السياسة الشرعية أو من باب + +73 +00:08:14,810 --> 00:08:19,370 +المصالح المرسلة ومثلها السكك الحديدية والقطارات + +74 +00:08:19,370 --> 00:08:24,550 +والإشارات الضوئية والتكنولوجيا الحديثة التي لا تضر + +75 +00:08:24,550 --> 00:08:30,090 +بالإسلام ولا تتعارض ومصالح المسلمين إذا التعريف + +76 +00:08:30,090 --> 00:08:36,230 +الأول وانتم لا تطلبون بحفظه غيبا لأنه سيأتيكم في + +77 +00:08:36,230 --> 00:08:43,480 +الامتحانعشرة مصطلحات فقط ان شاء الله من ستين + +78 +00:08:43,480 --> 00:08:55,740 +سلاثون صح او خطأ وعشرون اختيار متعدد وعشرة مصطلح + +79 +00:08:55,740 --> 00:09:01,470 +توصيلو هذا من التيثير عليكم ان شاء الله سيأتيكم + +80 +00:09:01,470 --> 00:09:07,150 +المصطلح وتنقلون الرقم إلى الجهة الأخرى فقط نعم + +81 +00:09:07,150 --> 00:09:14,850 +فهذا أيصر عليكم انما تطالبون بفهمالمصطلح وليس + +82 +00:09:14,850 --> 00:09:20,530 +بحفظه غيبا وقد يأتيكم واحد من هذه المصطلحات + +83 +00:09:20,530 --> 00:09:25,890 +الثلاثة إذا السياسة الشرعية عند المسلمين ما كان + +84 +00:09:25,890 --> 00:09:31,550 +فعلا يكون معاه الناس وأقرب إلى الصلاحيوأبعد عن + +85 +00:09:31,550 --> 00:09:35,690 +الفساد وإن لم يضعه الرسول عليه الصلاة والسلام ولا + +86 +00:09:35,690 --> 00:09:40,030 +نزل به وحي انطلاقا من القاعدة الشرعية التي سبق + +87 +00:09:40,030 --> 00:09:45,170 +ذكرها تصرف الإمام على الرعية مانوتون بالمصلحة هنا + +88 +00:09:45,170 --> 00:09:52,430 +أيضا مصطلح ثاني السياسة الشرعية استصلاح الخلق + +89 +00:09:52,430 --> 00:09:59,580 +بإرشادهم إلى الطريق المنجي في العاجل والآجلوهنا + +90 +00:09:59,580 --> 00:10:03,960 +ألفط أنظركم إلى خطأ كبير كنت أتمنى في الطبعة + +91 +00:10:03,960 --> 00:10:13,700 +الجديدة أن يتلافى ولكنه للأسف جاء كما هو هذا + +92 +00:10:13,700 --> 00:10:21,780 +التعريف يجعل السياسة الشرعية سياسة دنيوية بكلمة أو + +93 +00:10:22,700 --> 00:10:28,940 +فلابد من رفع الألف فيكون التعريف الصحيح أقول + +94 +00:10:28,940 --> 00:10:34,640 +انتبهوا إلى هذا استصلاح الخلق بإرشادهم إلى الطريق + +95 +00:10:34,640 --> 00:10:39,960 +المنجي في العاجلي والآجلي وهذا كما سيأتي قليل في + +96 +00:10:39,960 --> 00:10:45,890 +الفروقبين السياسة الشرعية والسياسة غير الشرعية عند + +97 +00:10:45,890 --> 00:10:51,630 +غير المسلمين لأن السياسة الشرعية تحقيق مصالح الأمة + +98 +00:10:51,630 --> 00:11:00,290 +في العاجل والاجل فكلمة أو هنا خطأ كبير ولا أريد أن + +99 +00:11:00,290 --> 00:11:07,490 +أتعجل بسؤال في الامتحان قد يأتيكم في الصح غلط نعم + +100 +00:11:08,770 --> 00:11:13,610 +السياسة الشرعية عند المسلمين استصلاح الخلق + +101 +00:11:13,610 --> 00:11:18,010 +بإرشادهم إلى الطريق المنجّف العادل أو الآدل فالذي + +102 +00:11:18,010 --> 00:11:23,530 +لم يحضر مثل هذه الدروس قد يضع صح لماذا يضع صح + +103 +00:11:23,530 --> 00:11:29,090 +لأنها للأسف في الكتاب خطأ مطبعيفانتبهوا إلى ذلك + +104 +00:11:29,090 --> 00:11:35,530 +وصححوها الإجابة الصحيحة استصلاح الخلق بإرشادهم إلى + +105 +00:11:35,530 --> 00:11:42,550 +الطريق المناد في العاجل والآجل وليس كلمة أو اللهم + +106 +00:11:42,550 --> 00:11:48,590 +فاشهد أني بلغت ثالثا وهي صحيحة ليس فيها أخطاء + +107 +00:11:48,590 --> 00:11:55,510 +مطبعية حملوا الكافة والكافة هم الناسحملوا الكافة + +108 +00:11:55,510 --> 00:12:00,670 +على مقتضى النظر الشرعي في مصالحهم الأخروية + +109 +00:12:00,670 --> 00:12:09,370 +والدنيوية الراجعة إليها رأيتم؟ نعم هنا قاموا + +110 +00:12:09,370 --> 00:12:14,710 +بتصحيح الخطأ في التعريف الثاني + +111 +00:12:16,490 --> 00:12:21,150 +الاخراوية والدنياوية إذا السياسة الشرعية باختصار + +112 +00:12:21,150 --> 00:12:27,090 +تحقيق مصالح الأمة أو مصالح الخلق أو مصالح الكافة + +113 +00:12:27,090 --> 00:12:32,910 +أو الناس في الدنيا والآخرة عبر عنها في التعريف + +114 +00:12:32,910 --> 00:12:36,390 +الثاني في العاجل والآجل في العاجل يعني في الدنيا + +115 +00:12:36,390 --> 00:12:43,810 +والآجل يعني في الآخر الآن بعد أن عرفنا السياسة عند + +116 +00:12:43,810 --> 00:12:48,010 +المسلميننأتي إلى سياسة عند غير مسلمين وهي في + +117 +00:12:48,010 --> 00:12:57,010 +الحقيقة تعريفات مبطورة ولكنها رحمة بكم نعم فأول + +118 +00:12:57,010 --> 00:13:03,370 +هذه التعريفات وهي أجمعها إن كان سيأتيكم سؤال فهو + +119 +00:13:03,370 --> 00:13:11,770 +هذا التعريف فن حكم المجتمعات الإنسانية والتعريف + +120 +00:13:11,770 --> 00:13:20,560 +الثاني فن الحكموالتعريف الثالث علم الدولة هذه هي + +121 +00:13:20,560 --> 00:13:26,280 +السياسة عند غير المسلمين تعريفات كما ترون قصيرة و + +122 +00:13:26,280 --> 00:13:32,340 +مبتورة وكان الأولى أن تستبدل بغيرها من مصطلحات + +123 +00:13:32,340 --> 00:13:39,780 +أخرى ماذا نرى هنا فأن حكم المجتمعات الإنسانية في + +124 +00:13:39,780 --> 00:13:46,070 +العاجل دون الآجلبمعنى في الدنيا دون الآخرة لأن + +125 +00:13:46,070 --> 00:13:52,910 +هؤلاء الكفار لا يؤمنون بالآخرة إنما همهم هو إشباع + +126 +00:13:52,910 --> 00:14:02,630 +بطونهم وشهواتهم وغرائصهم وإرضاء شعوبهم الذين + +127 +00:14:02,630 --> 00:14:08,150 +انتخبوهم ورفعوهم إلى سدة الحكم حتى في الطورات + +128 +00:14:08,150 --> 00:14:13,590 +والإنجيل وليس في القرآن فقط حرّم الله الزناوحرّم + +129 +00:14:13,590 --> 00:14:20,370 +الله الخمرة وحرّم الله الربا ومع ذلك أحل الزنا وما + +130 +00:14:20,370 --> 00:14:25,790 +هو أخطر من الزنا الشذوذ أن ينكح الرجل الرجل + +131 +00:14:25,790 --> 00:14:35,030 +والمرأة المرأة بل هناك عقود رسمية في المحاكم وفي + +132 +00:14:35,030 --> 00:14:42,690 +الكنائس عندهم يقرون أن يتثوج زواجا حلالاأو شرعيا + +133 +00:14:42,690 --> 00:14:48,490 +بلغتهم الرجل الرجل و المرأة المرأة وهذا كله مخالف + +134 +00:14:48,490 --> 00:14:52,490 +لا أقول لما جاء في القرآن بل لما جاء في التوراتي و + +135 +00:14:52,490 --> 00:14:57,470 +الانديل فهي من الكليات الخامس حفظوا العقل و حفظوا + +136 +00:14:57,470 --> 00:15:06,390 +النسل و الفرج و حفظوا المال فحافظ الله العقل + +137 +00:15:06,390 --> 00:15:14,950 +بتحريم الخمروحفظ النسل بتحريم الزنا وحفظ المال + +138 +00:15:14,950 --> 00:15:22,190 +بتحريم الربا نعم فإذا ما جاءكم سؤال السياسة عند + +139 +00:15:22,190 --> 00:15:27,430 +غير المسلمين فأن حكم المجتمعات الإنسانية بالعادل + +140 +00:15:27,430 --> 00:15:34,790 +والآدل الإجابة خطأ وإذا جاءكم سؤالالسياسة عند + +141 +00:15:34,790 --> 00:15:41,250 +المسلمين فان حكم المجتمعات الإنسانية في العاجل دون + +142 +00:15:41,250 --> 00:15:48,790 +الآجل أو في العاجل أو الآجل فالإجابة أيضا خطأ هكذا + +143 +00:15:48,790 --> 00:15:56,110 +نجد أن هناك تشابه بين السياسة عند المسلمين وعند + +144 +00:15:56,110 --> 00:16:02,630 +غير المسلمين ووجه التشابهأن علماء المسلمين وغيرهم + +145 +00:16:02,630 --> 00:16:09,810 +يرون أن السياسة هي تدبير شؤون البلاد والعباد ولكن + +146 +00:16:09,810 --> 00:16:16,410 +على اختلاف بينهم في كافية ذلك ولعله قد مر بنا في + +147 +00:16:16,410 --> 00:16:21,530 +صدر الكتاب عندما تكلمنا عن تعريف النظم عند + +148 +00:16:21,530 --> 00:16:31,140 +المسلمين وعند غير المسلمين وقلنا هناكتشابها أيضا + +149 +00:16:31,140 --> 00:16:36,280 +في حياة واحدة وهي أن النظم الإسلامية شكل من أشكال + +150 +00:16:36,280 --> 00:16:43,360 +النظم بوجه عام من حيث إنها تطبط و تنظم صلوك + +151 +00:16:43,360 --> 00:16:48,520 +ومعاملات أفراد المجتمع الذي آمن بها أو خضع وانقاد + +152 +00:16:48,520 --> 00:16:55,140 +لإحكامها وقوانينها هكذا تتفق النظم الإسلامية مع + +153 +00:16:55,140 --> 00:17:02,620 +غير الإسلاميةوهنا أيضا تتفق السياسة الشرعية وغير + +154 +00:17:02,620 --> 00:17:13,740 +الشرعية من أن كل منهم تدبير شؤون البلاد والعباد + +155 +00:17:14,910 --> 00:17:20,630 +خلّنا هناك اختلاف من جهة المصدر ومن جهة الغاية أو + +156 +00:17:20,630 --> 00:17:25,550 +الهدف أما من جهة المصدر فكما سبقا ذكرنا في النظم + +157 +00:17:25,550 --> 00:17:29,970 +الإسلامية أن مصدر النظم الإسلامية ومن ثم مصدر + +158 +00:17:29,970 --> 00:17:35,870 +السياسة الإسلامية هو الإسلام أو شرع الله أو القرآن + +159 +00:17:35,870 --> 00:17:43,470 +الكريم وكذلك السنة النبويةعن رسول الله صلى الله + +160 +00:17:43,470 --> 00:17:47,870 +عليه وسلم أما بالنسبة إلى غير المسلمين فهم لا + +161 +00:17:47,870 --> 00:17:54,070 +يؤمنون بأي كتاب سماوي حتى القرآن والإنجيل الكتب + +162 +00:17:54,070 --> 00:17:59,090 +السماوية عفوا التورات والإنجيل الكتب السماوية التي + +163 +00:17:59,090 --> 00:18:03,290 +نزلت عليهم فعند غير المسلمين الحاكم هو القانون + +164 +00:18:03,290 --> 00:18:11,760 +الذي يضعه رجال السياسة أنفسهم أما من حيث الهدففقد + +165 +00:18:11,760 --> 00:18:18,600 +سبق أن تكلمنا عن ذلك عند المصطلحات فهدف النظم + +166 +00:18:18,600 --> 00:18:24,040 +الإسلامية أو السياسة الإسلامية تحقيق مصالح الأمة + +167 +00:18:24,040 --> 00:18:30,680 +في العادل والآجل رأيتم هنا قد صححوا الخطأ الأول في + +168 +00:18:30,680 --> 00:18:41,170 +العاجل والآجل هذا هو الأصح وليس أو الآجلنكرر هذا + +169 +00:18:41,170 --> 00:18:46,230 +للأهمية لأنه موضع سؤال ويخطف فيه كثير من الطلاب + +170 +00:18:46,230 --> 00:18:50,410 +الذين يقرؤون الكتاب بعيدا عن توجيهاتالدكتور + +171 +00:18:50,410 --> 00:18:57,170 +المحاضر نعم تحقيق مصارح الأمة في العاجل والاجل أي + +172 +00:18:57,170 --> 00:19:02,470 +في الدنيا والاخرة حسب تعاليم الإسلام ونظمه أما عند + +173 +00:19:02,470 --> 00:19:06,970 +غير المسلمين فكما أسلفنا فالهدف ليس واحدا عند كل + +174 +00:19:06,970 --> 00:19:12,190 +الجماعات وإنما هو بحسب ما تراه كل جماعة على حدة أو + +175 +00:19:12,190 --> 00:19:19,330 +بحسب ما يراه رجال سياسة فيها لذلك أحلواما حرّم + +176 +00:19:19,330 --> 00:19:30,650 +الله هذا هو باختصار المبحث الأول وهو صغير وقصير + +177 +00:19:30,650 --> 00:19:36,330 +كما ترون تعريف النظم عند المسلمين وعند غير + +178 +00:19:36,330 --> 00:19:44,260 +المسلمين وقد رأينا أن هناك توافقابين التعريفين من + +179 +00:19:44,260 --> 00:19:51,360 +جهة أن كل منها تدبير شؤون البلاد والعباد ولكن + +180 +00:19:51,360 --> 00:19:58,410 +الخلاف من جهة المصدر ومن جهةالغاية أو الهدف من جهة + +181 +00:19:58,410 --> 00:20:02,230 +المصدر قلنا بأن مصدر النظم الإسلامي أو السياسة + +182 +00:20:02,230 --> 00:20:08,170 +الإسلامية هو القرآن والسنة أما عند غير المسلمين + +183 +00:20:08,170 --> 00:20:13,970 +فهو رجال السياسة أو رجال القانون الذين ليس لهم إلا + +184 +00:20:13,970 --> 00:20:20,180 +إرضاء شعوبهمومجتمعاتهم الذين انتخبوهم وجعلوهم في + +185 +00:20:20,180 --> 00:20:25,200 +الحكم من أجل ذلك أحلوا ما حرّم الله في القرآن + +186 +00:20:25,200 --> 00:20:30,660 +والتوراة والإنجيل أما الغاية فالنظم الإسلامية + +187 +00:20:30,660 --> 00:20:37,040 +والسياسة الشرعية هدفها تحقيق مصالح الأمة الإسلامية + +188 +00:20:37,040 --> 00:20:44,470 +في العاجل والآجل في أمور الدنياوية والأخرويةأما + +189 +00:20:44,470 --> 00:20:50,870 +عند غيرهم فعلى العكس من ذلك تماما ليس لهم هدف إلا + +190 +00:20:50,870 --> 00:20:57,050 +تحقيق شهواتهم ونزواتهم الدنيوية فقط دون الأخروية + +191 +00:20:57,050 --> 00:21:02,890 +لعلهم حتى لا يؤمنون بالآخرة كما وصفهم الله إنما هي + +192 +00:21:02,890 --> 00:21:08,730 +حياتنا الدنيا نموت ونحيا وما يهلكنا إلا الدهر هنا + +193 +00:21:08,730 --> 00:21:14,140 +ننطق المبحث الثانيوأريد أن ألفط أنظركم إلى مصطلح + +194 +00:21:14,140 --> 00:21:21,380 +لم يلتفت إليه كثير من الطلاب لأننا تعودنا أن يكون + +195 +00:21:21,380 --> 00:21:28,360 +المصطلح بين قوسين كما مر بنا قبل قليل النظم عند + +196 +00:21:28,360 --> 00:21:32,880 +المسلمين وعند غير المسلمين وكما مر بنا في تعريفات + +197 +00:21:32,880 --> 00:21:39,780 +أخرى مثل تعريف السياسةو تعريف الإجماع و تعريف + +198 +00:21:39,780 --> 00:21:45,800 +الأسرة و تعريف الزواج و تعريفات أخرى كثيرة + +199 +00:21:45,800 --> 00:21:55,600 +كالربانية نعم و الثبات و المرونة ولكن هناك تعريفات + +200 +00:21:55,600 --> 00:22:03,820 +لم يفطن إليها الطلاب و لما تكلمتعن مجالات فرّق + +201 +00:22:03,820 --> 00:22:06,400 +فيها الإسلام بين الراجل و المرأة قلت لكم هناك + +202 +00:22:06,400 --> 00:22:14,400 +تعريف اللعان نعم أكرر من أجل مصلحة الطالب لأنه + +203 +00:22:14,400 --> 00:22:18,960 +يوما جاء هذا المصطلح مصطلح اللعان قد يأتي في + +204 +00:22:18,960 --> 00:22:24,380 +الامتحانات وهو ليس في أعلى الصفحة فجاء الطالب و + +205 +00:22:24,380 --> 00:22:28,900 +يشكر أين يا دكتور هذا المصطلح فقلت له لو حضرت + +206 +00:22:28,900 --> 00:22:35,690 +المحاضراتلعرفت أنه في الهامش فمصطلح اللعان في + +207 +00:22:35,690 --> 00:22:44,070 +الهامش وهنا أقول لكم هنا مصطلح اسمه قواعد النظام + +208 +00:22:44,070 --> 00:22:50,210 +السياسي في الإسلام لكنه ليس له عنوان بارز ولم يوضع + +209 +00:22:50,210 --> 00:22:54,270 +بين قوسين ولذا غاب عن كثير من الطلاب ما هذا + +210 +00:22:54,270 --> 00:23:03,840 +المصطلح المبادئوالثوابت الأساسية التي بنى عليها + +211 +00:23:03,840 --> 00:23:10,540 +الإسلام دولته ويستلهم منها النظام السياسي للحكم + +212 +00:23:10,540 --> 00:23:15,380 +إذا ما هو تعريف قواعد النظام السياسي في الإسلام + +213 +00:23:15,380 --> 00:23:22,900 +المبادئ والثوابت الأساسية التي بنى عليها الإسلام + +214 +00:23:22,900 --> 00:23:31,810 +دولته إذا ما جاء هذا وطبعالن يأتيكم حفظا عن ظهر + +215 +00:23:31,810 --> 00:23:37,150 +القلب وإنما سيأتيكم وتضعون رقمه في الجهة الأخرى + +216 +00:23:37,150 --> 00:23:43,610 +يعني مصطلح توصيل وهذا من كرم الله عليكم أسهل وأيسر + +217 +00:23:43,610 --> 00:23:49,470 +إذا هذه الملحوظة الأولى طبعا قواعد النظام السياسي + +218 +00:23:49,470 --> 00:23:54,830 +كثيرة عدوها ستة وعدوها أكثر وعدوها أقل ولكن نحن + +219 +00:23:54,830 --> 00:24:03,960 +الحقيقة ملتزمونبالكتاب وسوف نقتصر ان شاء الله على + +220 +00:24:03,960 --> 00:24:09,880 +القواعد الأربعة فقواعد النظام السياسي في الإسلام + +221 +00:24:09,880 --> 00:24:17,080 +أربعة كما هي عندنا في الكتاب وهي آخر المقرر في + +222 +00:24:17,080 --> 00:24:24,100 +مساق النظم الإسلامية والأسئلة هنا كثيرة وهي مهمة + +223 +00:24:24,100 --> 00:24:31,130 +جدا أولا الحاكمية للهثانياً العدل والمساواة وثالثا + +224 +00:24:31,130 --> 00:24:38,890 +الشورى ورابعا الطاعة وهكذا في المحاضرة التالية ان + +225 +00:24:38,890 --> 00:24:44,630 +شاء الله نكون قد انتهينا من المقرر بالكلية نبدأ + +226 +00:24:44,630 --> 00:24:49,570 +الآن بالقاعدة الأولى وهي الحاكمية لله ما هو تعريف + +227 +00:24:49,570 --> 00:24:58,290 +الحاكمية الحاكمية لغة مصدر من الفعل حكمةوحكم في + +228 +00:24:58,290 --> 00:25:05,030 +لغة العرب بمعنى قضى ومنه قولهم حكم بالأمر حكما أي + +229 +00:25:05,030 --> 00:25:13,830 +قضى به ويقال حكم له وحكم عليه وحكم فيه وهذا طبعا + +230 +00:25:13,830 --> 00:25:18,870 +لا يعنينا كثيرا لأن المعاني اللغوية لن تأتي في + +231 +00:25:18,870 --> 00:25:23,510 +الامتحان الذي يأتيكم في الامتحان فقط هو المصطلحات + +232 +00:25:23,510 --> 00:25:26,130 +الشرعية نعم + +233 +00:25:28,150 --> 00:25:34,270 +وعلى هذا فمعنى كون الحاكمية لله أي أنه سبحانه + +234 +00:25:34,270 --> 00:25:40,210 +وتعالى بيده القضاء في شؤون عباده وأنه صاحب الحكم + +235 +00:25:40,210 --> 00:25:47,410 +فيهم وله حق التشريع لهم وهو مصدر التشريعوالتقنين + +236 +00:25:47,410 --> 00:25:53,070 +سبحانه وتعالى ولا يحق لهم ولا لأحد منهم أن يشرّع + +237 +00:25:53,070 --> 00:26:00,410 +غير شرعه سبحانه وتعالى أو أن يأمر أحد بالاتباع شرع + +238 +00:26:00,410 --> 00:26:06,430 +غير شرع الله تبارك وتعالى أو يأتمر هو بشرع غير شرع + +239 +00:26:06,430 --> 00:26:13,430 +الله سبحانه وتعالى فالحاكمية لله بمعنى أن الذي + +240 +00:26:13,430 --> 00:26:21,410 +يشرعوأن الذي يُقنّنه للناس + +241 +00:26:21,410 --> 00:26:29,670 +هو الله تبارك وتعالى وأي تشريع وأي قانون يخالف ما + +242 +00:26:29,670 --> 00:26:36,770 +شرع الله فهو كفر والعياذ بالله كما سيأتي يخرجه عن + +243 +00:26:36,770 --> 00:26:43,670 +الملة وسنأتي الآن إلى الأدلة على ذلك ما هي الأدلة؟ + +244 +00:26:44,220 --> 00:26:50,440 +على أن الحاكمية لله وهنا ألفط أنظركم إلى شيء مهم + +245 +00:26:50,440 --> 00:26:55,340 +قد وقع فيه الطلاب من قبل أنهم في المصطلحات لا + +246 +00:26:55,340 --> 00:27:01,720 +يفرقون بين الحاكمية لله وبين الربانية لله الربانية + +247 +00:27:01,720 --> 00:27:11,840 +كما أسلفنا أولى خصائص النظم الإسلاميةوالربانية كما + +248 +00:27:11,840 --> 00:27:18,500 +قلنا إما ربانية المصدر وإما ربانية الغاية فعودوا + +249 +00:27:18,500 --> 00:27:25,220 +إلى ربانية المصدر وتعريفها أن أصول أحكامها ووصف + +250 +00:27:25,220 --> 00:27:31,180 +تشريعاتها مأخوذة من كتاب الله ومن سنة رسول الله + +251 +00:27:31,180 --> 00:27:37,120 +عليه الصلاة والسلام فبعض الطلاب يخلط فيضع مصطلح + +252 +00:27:37,120 --> 00:27:42,390 +الربانيةمحلة الحاكمية ومصطلح الحاكمية محلة + +253 +00:27:42,390 --> 00:27:49,510 +الربانية فخذوا حذركم ولا تقعوا فيما وقع فيه من + +254 +00:27:49,510 --> 00:27:56,070 +سبقكم فنحن نتكلم عن الحاكمية لله بمعنى أن المشرع + +255 +00:27:56,070 --> 00:28:01,830 +هو الله وأن الواضع للقوانين هو الله وليس سواه + +256 +00:28:01,830 --> 00:28:08,140 +سبحانه وتعالىأول هذه الأدلة وهي خمسة قوله تبارك + +257 +00:28:08,140 --> 00:28:13,720 +وتعالى إن الحكم إلا لله في صورة يوسف عليه السلام + +258 +00:28:13,720 --> 00:28:21,560 +إن الحكم إلا لله فلا حاكم إلا الله ولا مشرع إلا + +259 +00:28:21,560 --> 00:28:26,800 +الله سبحانه وتعالى ثانيا في صورة النساء قوله تبارك + +260 +00:28:26,800 --> 00:28:32,020 +وتعالى يريدون أن يتحكموا إلى الطاغوت وقد أمروا أن + +261 +00:28:32,020 --> 00:28:37,470 +يكفروا بهو يريد الشيطان أن يضلهم ضلالا بعيدا + +262 +00:28:37,470 --> 00:28:43,250 +فالتحاكم إلى الله و ليس إلى الطاغوت و الطاغوت و + +263 +00:28:43,250 --> 00:28:53,330 +الطواغيت كل طاغية لم يحكم بشرع الله كل حاكم او + +264 +00:28:53,330 --> 00:29:01,550 +رئيس دولة لم يحكم بما شرع الله او رسول الله في + +265 +00:29:01,550 --> 00:29:08,100 +الكتاب و السنةنعم وكلمة الطاغية والطوغيط أصلها + +266 +00:29:08,100 --> 00:29:13,260 +اللغوي من الفعل طغى وطغى في اللغة بمعنى تجاوز الحد + +267 +00:29:13,260 --> 00:29:18,320 +ومنه قوله تعالى في قصة نوح عليه السلام إِنَّا + +268 +00:29:18,320 --> 00:29:21,180 +لَمَّا طَغَى الْمَاءُ حَمَلْنَاكُمْ فِي + +269 +00:29:21,180 --> 00:29:26,600 +الْجَارِيَةِ إذا الطاغوت كل من تجاوز حدود الله + +270 +00:29:26,600 --> 00:29:34,270 +تبارك وتعالى ثالثا أيضافي صورة أندساء وهذه الآية + +271 +00:29:34,270 --> 00:29:39,910 +لابد أن نقف عندها قليلا لأننا سنأتي اليها في آخر + +272 +00:29:39,910 --> 00:29:43,410 +المبحث + +273 +00:29:43,410 --> 00:29:52,250 +ولها قصة ذكرها العلامة المحدث ابن كثير في تفسيره + +274 +00:29:52,250 --> 00:29:53,850 +العظيم + +275 +00:29:55,600 --> 00:30:02,060 +ولكن لا نتعجل لأن هذه الآية ستأتي إجابة على سؤال + +276 +00:30:02,060 --> 00:30:10,860 +ما حكم من تحاكم إلى شرع غير شرع الله برضا وطواعية + +277 +00:30:10,860 --> 00:30:18,160 +نقول حكمه الكفر أولا و القتل لأنه مرتد عن شريعة + +278 +00:30:18,160 --> 00:30:25,480 +الإسلامو هذه هي الآية و سنأتي إليها تارة أخرى إن + +279 +00:30:25,480 --> 00:30:31,780 +شاء الله تبارك وتعالى فلا وربك رأيتم كيف جاء القسم + +280 +00:30:31,780 --> 00:30:37,840 +والقسم في لغة العرب عندما يأتي للدلالة على أهمية + +281 +00:30:37,840 --> 00:30:44,840 +وعظم وخطر الشيء المقسم به فالقسم لا يكون بأمر تافه + +282 +00:30:44,840 --> 00:30:51,480 +أو حقير أو صغير إنما يكون بشيءخطير أو عظيم فلا + +283 +00:30:51,480 --> 00:30:57,480 +وربك يعني يا محمد لا يؤمنون حتى يحكموك فيما شجر + +284 +00:30:57,480 --> 00:31:04,820 +بينهم ثم لا يجدوا في أنفسهم حرجا مما قضيت ويسلموا + +285 +00:31:04,820 --> 00:31:11,480 +تسليما نعم حتى لا يكفي الرضا + +286 +00:31:11,480 --> 00:31:20,060 +بالقضاء لأنه قد يرضى كارها انما لابدمدل التسليم + +287 +00:31:20,060 --> 00:31:29,920 +ويسلموا تسليمة بمعنى الرضاء التام بشرع الله وبحكم + +288 +00:31:29,920 --> 00:31:36,100 +الله تبارك وتعالى وإلا لا يكون مؤمنًا يكون مرتدًا + +289 +00:31:36,100 --> 00:31:40,980 +قد خرج عن ملة الإسلام والعياذ بالله أما الدليل + +290 +00:31:40,980 --> 00:31:50,690 +الرابع فإن العقل السليم يقرهأن الحاكمية لله سبحانه + +291 +00:31:50,690 --> 00:31:57,830 +وتعالى وكيف ذلك من خلال حقيقتين + +292 +00:31:57,830 --> 00:32:07,870 +ونخرج بالثالثة وهذه على طريقة علم المنطق أن نأتي + +293 +00:32:07,870 --> 00:32:15,820 +بقاعدتين وأن نخرج بقاعدة ثالثةأو بحقيقتين و أن + +294 +00:32:15,820 --> 00:32:24,040 +نأتي بحقيقة ثالثة و نحن نستعمل ذلك في الشريعة + +295 +00:32:24,040 --> 00:32:36,420 +الإسلامية أيضا عندما نقول مثلا الصلاة فرض كيف + +296 +00:32:36,420 --> 00:32:41,460 +عرفنا أن الصلاة فرض الله تبارك وتعالى يقول أقيم + +297 +00:32:41,460 --> 00:32:52,050 +الصلاةفأقيموا فعلوا أمر والأمر يفيد الوجوب فدل على + +298 +00:32:52,050 --> 00:33:00,130 +أن الصلاة واجبة وكذلك قوله تبارك وتعالى وآتوا + +299 +00:33:00,130 --> 00:33:06,810 +الذكاء آتوا أمر والأمر يفيد الوجوب فالذكاء واجبة + +300 +00:33:06,810 --> 00:33:15,280 +وكذلك مثلا في الناهية ولا تقربوا الزنالا تقربوا + +301 +00:33:15,280 --> 00:33:23,300 +نهي و النهي يفيد التحريم فالزنا حرام ولا تقتلوا + +302 +00:33:23,300 --> 00:33:28,160 +النفس ولا تأكلوا أموالكم بينكم بالباطل إلى غير ذلك + +303 +00:33:28,160 --> 00:33:35,480 +و كذلك هنا نقول هناك حقيقتين الحقيقة الأولى أن + +304 +00:33:35,480 --> 00:33:43,970 +الله هو الخالق و ما أكثر الآيات على ذلكنقتصر + +305 +00:33:43,970 --> 00:33:49,370 +ببعضها مثل قوله تبارك وتعالى خلق كل شيء فقدره + +306 +00:33:49,370 --> 00:33:55,370 +تقديرا والآيات عندكم في الكتاب والحقيقة الثانية أن + +307 +00:33:55,370 --> 00:34:01,470 +الله هو الرازق وما أكثر الآيات ومنها قوله تبارك + +308 +00:34:01,470 --> 00:34:07,810 +وتعالى وفي السماء رزقكم وما توعدون هنا نقول إذا + +309 +00:34:07,810 --> 00:34:13,560 +كان الله هو الخالقوإذا كان الله هو الرازق فإن الله + +310 +00:34:13,560 --> 00:34:19,940 +هو المالك فالمالك هو الحقيقة الثالثة أو الثمرة + +311 +00:34:19,940 --> 00:34:26,040 +التي نجمت عن الحقيقتين الأولى والثانية مرة ثانية + +312 +00:34:26,040 --> 00:34:31,370 +نقول إذا كان الله هو الخالقوإذا كان الله هو الرازق + +313 +00:34:31,370 --> 00:34:37,510 +فإن الله هو المالك ومعنى المالك أي أنه سبحانه + +314 +00:34:37,510 --> 00:34:43,650 +وتعالى هو المتصرف في ملكه كيف يشاء فأنت أيها + +315 +00:34:43,650 --> 00:34:51,030 +المخلوق لو كنت تملك مثلا بيتا فأنت حر التصرف فيه + +316 +00:34:51,030 --> 00:35:00,960 +لك مثلا أن تبيعهولك أن تنتفع به بالسكنة ولك أن + +317 +00:35:00,960 --> 00:35:10,580 +تؤجره ولك أن تهبه هبطا بدون مقابل ولك أيضا أنتتصدق + +318 +00:35:10,580 --> 00:35:15,700 +به أو أن توقفه إذا أنت أيها المخلوق الصغير من خلق + +319 +00:35:15,700 --> 00:35:21,440 +الله إذا كنت تملك شيئا فانت حر التصرف فيه ما بين + +320 +00:35:21,440 --> 00:35:29,460 +بيع و سكنة و إيجارة و هبة و وقف و صدقة إلى غير ذلك + +321 +00:35:29,460 --> 00:35:33,720 +ولله المثل الأعلى إذا كان الله هو المالك فهو + +322 +00:35:33,720 --> 00:35:39,460 +المتصرف في ملكه و في خلقه كيف شاءلأنه الذي خلقهم + +323 +00:35:39,460 --> 00:35:46,580 +فالإنسان خلق الله وصنعة الله وبنيان الرب تبارك + +324 +00:35:46,580 --> 00:35:52,680 +وتعالى وهو أدرى بهم كما مثلنا في بداية المساق + +325 +00:35:52,680 --> 00:35:59,520 +عندما تكلمنا عن النظم الإسلامية وقلنا بأن مصدرها + +326 +00:35:59,520 --> 00:36:05,780 +هو الله تبارك وتعالى ومثلنا بذلك في صانع الآلة + +327 +00:36:05,780 --> 00:36:13,010 +والكتلوجفالـ Catalogue فيه ما يصلح الآلة والصانع + +328 +00:36:13,010 --> 00:36:19,290 +الذي صنع الآلة هو أدرى بما يصلحها إذا فسدت ولله + +329 +00:36:19,290 --> 00:36:23,390 +المثل الأعلى خلق هذا الإنسان وأنزل معه ال + +330 +00:36:23,390 --> 00:36:30,410 +Catalogue إيه هو ال Catalogue؟ القرآن الكريم فإما + +331 +00:36:30,410 --> 00:36:38,170 +يأتينكم مني هدا فمن اتبع هدايا فلا يضل ولا يشقهومن + +332 +00:36:38,170 --> 00:36:43,750 +أعرض عن ذكري فإن له معيشة ضنكة ونحشره يوم القيامة + +333 +00:36:43,750 --> 00:36:48,870 +أعمى قال رب ليه محشرتني أعمى وقد كنت بصيرة قال + +334 +00:36:48,870 --> 00:36:54,510 +كذلك أتتك آيتنا فنسيتها وكذلك اليوم تنسى الآية في + +335 +00:36:54,510 --> 00:37:04,290 +صورة طه نعم إذا الدليل الرابع على أن الحاكمية + +336 +00:37:04,290 --> 00:37:12,580 +لله من خلالحقيقتينه الحقيقة الأولى أن الخالق هو + +337 +00:37:12,580 --> 00:37:18,860 +الله والحقيقة الثانية أن الرازق هو الله فنقول وفق + +338 +00:37:18,860 --> 00:37:24,660 +علم المنطق إذا كان الله هو الخالق وإذا كان الله هو + +339 +00:37:24,660 --> 00:37:29,420 +الرازق نخرج من ذلك بحقيقة ثالثة أن الله هو المالك + +340 +00:37:29,420 --> 00:37:38,200 +بمعنى المتصرف سبحانه وتعالىفي خلقه وفي عباده فهو + +341 +00:37:38,200 --> 00:37:45,980 +أدرى بما يصلحهم سبحانه وتعالى ولذلك له أن يشرّع + +342 +00:37:45,980 --> 00:37:52,400 +لهم ما يشاء عز وجل أما خامسا لا إله إلا الله تقرر + +343 +00:37:52,400 --> 00:38:02,060 +أن الحاكمية لله لا إله إلا الله أولا هي عبارة عن + +344 +00:38:02,060 --> 00:38:13,000 +شقينهالشق الأول نفي مطلق لا إله والشق الثاني إثبات + +345 +00:38:13,000 --> 00:38:21,300 +مطلق إلا الله لا إله نفي مطلق نفت كل إله إلا الله + +346 +00:38:21,300 --> 00:38:30,830 +إثبات مطلق أثبتت الألوهية للهوأن الحاكمية لله + +347 +00:38:30,830 --> 00:38:37,470 +ومعنى لا إله إلا الله لا معبود بحق في الوجود سواء + +348 +00:38:37,470 --> 00:38:44,870 +الله سبحانه وتعالى ومن ثم الحاكمية لله عز وجل + +349 +00:38:44,870 --> 00:38:53,030 +وكذلك نقول هنا لابد من التفريق بين كلمة إله وبين + +350 +00:38:53,030 --> 00:39:00,410 +كلمة الله فكلمة الله هيلا تُطلَق إلا على الله + +351 +00:39:00,410 --> 00:39:06,250 +سبحانه وتعالى ولذلك لابد أن تُكتب باللغة الأجنبية + +352 +00:39:06,250 --> 00:39:16,350 +اللهوهذا للأسف ما أخطأ فيه الذين ترجموا معاني + +353 +00:39:16,350 --> 00:39:21,490 +القرآن الكريم ولا أقول القرآن الكريم لأننا لما + +354 +00:39:21,490 --> 00:39:25,110 +تكلمنا عن المصدر الأول من مصادر النظم الإسلامية + +355 +00:39:25,110 --> 00:39:33,070 +القرآن الكريم تكلمنا من خصائصه أنه لا يترجم حتى و + +356 +00:39:33,070 --> 00:39:39,280 +لو كانت الترجمة دقيقة جدالأن الترجمة من كلام البشر + +357 +00:39:39,280 --> 00:39:45,800 +والقرآن كلام الله المعجز المتعبد بتلاوته سبحانه + +358 +00:39:45,800 --> 00:39:53,440 +وتعالى من أجل ذلك قال الفصحاء والبلغاء ترجمت معاني + +359 +00:39:53,440 --> 00:39:58,600 +الفاظ القرآن الكريم وهذا من أدق لكن عندما ننظر إلى + +360 +00:39:58,600 --> 00:40:04,820 +الشاشة ونحن نستمع إلى القرآن من خلال التلفاز نقرأ + +361 +00:40:04,820 --> 00:40:16,180 +كلمة اللهبمعنى إله يعني جد وهذا خطأ فلابد أن تُكتب + +362 +00:40:16,180 --> 00:40:23,320 +الله الله هكذا باللغة الأجنبية وكلمة إله بمعنى جد + +363 +00:40:23,320 --> 00:40:31,160 +لأن كلمة إله تشمل كل إله حتى و لو كان من البشر مثل + +364 +00:40:31,160 --> 00:40:39,650 +فرعونأو كان من الحجر و الشجر مثل أصنام قريش هبل و + +365 +00:40:39,650 --> 00:40:45,070 +العزة و منات و غيرها حتى الهوى كما سيأتي في القرآن + +366 +00:40:45,070 --> 00:40:50,810 +يكونوا إلها فرأيت من اتخذ إلهة هو هو إذا لابد من + +367 +00:40:50,810 --> 00:40:56,230 +التفريق بين كلمة إله وبين كلمة الله الله لا يطلق + +368 +00:40:56,230 --> 00:41:02,400 +إلا على الله ولذلك قلنا لا إله إلا اللهنفد كل إله + +369 +00:41:02,400 --> 00:41:09,480 +من البشر ومن الشجر ومن الحجر حتى القوانين والأنظمة + +370 +00:41:09,480 --> 00:41:15,180 +الوضعية هي أيضًا آلهة إذا ما طُبّقت تعبدوا من دون + +371 +00:41:15,180 --> 00:41:20,920 +الله عز وجل لا إله إلا الله لا مشرع إلا الله لا + +372 +00:41:20,920 --> 00:41:28,440 +حاكم إلا الله سبحانه وتعالىنأتي إلى الكتاب كلمة + +373 +00:41:28,440 --> 00:41:34,060 +الصنام يُطلَق عليه إله كما في قصة إبراهيم وإذ قال + +374 +00:41:34,060 --> 00:41:40,160 +إبراهيم لأبيه آذر أتتخذ أصناما آلهة فالأصنام قد + +375 +00:41:40,160 --> 00:41:46,100 +تكون آلهة من دون الله وهو الإنسان أفرأيت من اتخذ + +376 +00:41:46,100 --> 00:41:53,180 +إلهه هو والبشر كما في قصة فرعون ما علمت لكم من إله + +377 +00:41:53,180 --> 00:42:02,090 +غيرهوهكذا لا إله إلا الله فعلم أنه لا إله إلا الله + +378 +00:42:02,090 --> 00:42:10,690 +فكلمة الله لا تطلق إلا على الله الخالق الرازق وحده + +379 +00:42:10,690 --> 00:42:16,810 +سبحانه وتعالى وعليه فعندما نقول لا إله نفي المطلق + +380 +00:42:16,810 --> 00:42:22,010 +نكون قد نفينا الألوهية عن كل معبود على الإطلاق صوى + +381 +00:42:22,010 --> 00:42:27,340 +الله وعندما نقول إلا اللهإثبات المطلق نكون قد + +382 +00:42:27,340 --> 00:42:33,360 +أثبتنا الألوهية لله وحده وعز وجل وحصرناها فيه دون + +383 +00:42:33,360 --> 00:42:43,280 +غيره سبحانه وتعالى نعم إذا كل هذه الأدلة دليل على + +384 +00:42:43,280 --> 00:42:51,860 +أن الحاكمية لله طب أعداء الإسلام وموقفهممن + +385 +00:42:51,860 --> 00:43:00,440 +الحاكمية المشكلة ان هؤلاء المشركون يؤمنون بالله + +386 +00:43:00,440 --> 00:43:10,240 +ولكن يكفرون بأن الحاكمية لله ولذلك صمي هؤلاء + +387 +00:43:10,240 --> 00:43:15,280 +بالمشركين لأنهم يؤمنون بالله ويعبدون مع الله آلهة + +388 +00:43:15,280 --> 00:43:21,240 +أخرى وعندما سُولي قالوا انما نعبدهمليقربون إلى + +389 +00:43:21,240 --> 00:43:28,880 +الله ذلفة يعبدون ألهة الأرض من أوثان و أصنام + +390 +00:43:28,880 --> 00:43:36,000 +صنعوها بأيديهم حتى من العجوة كما كانوا يفعلون كما + +391 +00:43:36,000 --> 00:43:39,460 +فعل سيدنا عمرو لما ضحك يوما وسؤل لماذا ضحكت يا + +392 +00:43:39,460 --> 00:43:43,780 +أمير المؤمنين قال أهدا لي خالي في الجاهلية صنما من + +393 +00:43:43,780 --> 00:43:51,110 +عجوة فلمّا جعت أكلتههكذا كانت آلهة أهل الجاهلية + +394 +00:43:51,110 --> 00:44:00,710 +تؤكل و تكسر و يصنع غيرها من الحجر و من الشجر و + +395 +00:44:00,710 --> 00:44:05,170 +لذلك كانوا يؤمنون بأن الله هو الخالق و بأن الله هو + +396 +00:44:05,170 --> 00:44:10,810 +الرازق و بأن الله هو القادر سبحانه وتعالى و + +397 +00:44:10,810 --> 00:44:16,470 +المتصرفكما مثلا في هذه الآية قُل من يرفقكم من + +398 +00:44:16,470 --> 00:44:21,350 +السماء والأرض أما يملك السمع والأبصار ومن يخرج + +399 +00:44:21,350 --> 00:44:26,110 +الحي من الميت ويخرج الميت من الحي ومن يدبر أمره + +400 +00:44:26,110 --> 00:44:31,950 +فسيقولون الله فقول أفلا تتقون هذا هو حاله المشركين + +401 +00:44:31,950 --> 00:44:41,610 +في الجاهلية بل إن أبا جهل في غزوةبدر يعتقد أن الله + +402 +00:44:41,610 --> 00:44:47,430 +هو الناصروالمعين حيث طلب العون والنصرة من الله + +403 +00:44:47,430 --> 00:44:52,790 +سبحانه وتعالى وهو القائل الله منصر أعلى الجندين + +404 +00:44:52,790 --> 00:44:58,790 +وأكرم القبيلتين فاستجاب الله له فكان محمد عليه + +405 +00:44:58,790 --> 00:45:04,310 +الصلاة والسلام هو أعلى الجندين وأكرم القبيلتين + +406 +00:45:04,310 --> 00:45:09,170 +وهذا معنى قوله تعالى في صورة الأنفال إن تستفتحوا + +407 +00:45:09,170 --> 00:45:15,710 +فقد جاءكم الفتحوإن تنتهوا فهو خير لكم وإن تعودوا + +408 +00:45:15,710 --> 00:45:22,810 +نعود ولن تغني عنكم فئتكم شيء و لو كثرت وأن الله مع + +409 +00:45:22,810 --> 00:45:30,750 +المؤمنين وهو الشعر العربي صهير بن أبي سلم يقول فلا + +410 +00:45:30,750 --> 00:45:36,350 +تكتمن الله ما في نفوسكم ليخفى ومهما يكتم الله + +411 +00:45:36,350 --> 00:45:44,000 +يعلميفهو يؤمن بأن الله عالم بالصرائر و الخفاية و + +412 +00:45:44,000 --> 00:45:49,240 +أنه يعلم ما في نفره .. بل إن عنطرة ابن شداد و هو + +413 +00:45:49,240 --> 00:45:57,220 +الشاعر الجاهلي يخاطب محبوبته عبلة و يقول يا عبل + +414 +00:45:57,220 --> 00:46:02,900 +أين من المنية مهرب إن كان ربي في السماء خضها فكل + +415 +00:46:02,900 --> 00:46:08,070 +هذا و ذاك يدل على أنهم كانوا يؤمنون باللهوبأنه + +416 +00:46:08,070 --> 00:46:14,230 +الخالق وبأنه الرازق وبأنه العالم بنفوسهم وأسرارهم + +417 +00:46:14,230 --> 00:46:20,310 +وخفاياهم ولكنهم كانوا يعبدون الأصنام يتقربون إلى + +418 +00:46:20,310 --> 00:46:25,130 +الله حتى تشفى عليهم هذا معنى قوله تعالى والله أعلى + +419 +00:46:25,130 --> 00:46:30,710 +وأعلم ما نعبدهم إلا ليقربون إلى الله ذلفة وقوله + +420 +00:46:30,710 --> 00:46:38,560 +هؤلاء شفعاؤنا عند اللهسبحانه وتعالى أما موقف + +421 +00:46:38,560 --> 00:46:43,780 +المؤمنين من الحاكمية لله فهو كما وصفهم الله في + +422 +00:46:43,780 --> 00:46:50,960 +أكثر من موضع سمعنا وأطعنا غفرانك ربنا وإليك المصير + +423 +00:46:50,960 --> 00:46:57,680 +نعم أو كما قال الله هنا في قوله تبارك وتعالى إنما + +424 +00:46:57,680 --> 00:47:02,690 +كان قول المؤمنينإذا دعوا إلى الله ورسوله ليحكم + +425 +00:47:02,690 --> 00:47:09,070 +بينهم أن يقولوا سمعنا وأطعنا وأولئك هم المفلحون + +426 +00:47:09,070 --> 00:47:14,910 +فالمؤمن إذا سمع الله يقول يا أيها الذين أمنوا سواء + +427 +00:47:14,910 --> 00:47:21,230 +في الأمر يمتثل أو في النهي يجتنب حاله لسانه يقول + +428 +00:47:21,230 --> 00:47:27,870 +سمعنا وأطعنا فالله ورسوله أحب إليه من + +429 +00:47:31,810 --> 00:47:38,810 +أبائه وأمه وولده والناس أجمعين كما جاء في الحديث + +430 +00:47:38,810 --> 00:47:44,670 +في غير هذا الكتاب لا يؤمن أحدكم حتى أكون أحب إليه + +431 +00:47:44,670 --> 00:47:51,290 +من والده وولده والناس أجمعين نأتي الآن إلى حكم من + +432 +00:47:51,290 --> 00:47:58,040 +أخطر الأحكام حكم من لم يرضى بحكم اللهتبارك وتعالى + +433 +00:47:58,040 --> 00:48:05,100 +هنا أولا والعياذ بالله الكفر لأنها جاءت في آيات + +434 +00:48:05,100 --> 00:48:11,520 +متواليات في صورة المائدة ومن لم يحكم بما أنزل الله + +435 +00:48:11,520 --> 00:48:16,560 +فأولئك هم الكافرون ومن لم يحكم بما أنزل الله + +436 +00:48:16,560 --> 00:48:20,700 +فأولئك هم الظالمون ومن لم يحكم بما أنزل الله + +437 +00:48:20,700 --> 00:48:29,250 +فأولئك همالفاسقون فهم كافرون وظالمون وفاسقون فالذي + +438 +00:48:29,250 --> 00:48:38,110 +يرفض ان يحكم بما أنزل الله كافر ظالم فاسق والعياذ + +439 +00:48:38,110 --> 00:48:43,710 +بالله فهو كافر قد خرج عن ملة الإسلام + +440 +00:48:47,710 --> 00:48:52,670 +ما هي نتائج الحكم بغير ما أنذر الله طبعا ما نراه + +441 +00:48:52,670 --> 00:49:00,530 +اليوم من سيطرة الكفار على المسلمين فأصبحت أمريكا + +442 +00:49:00,530 --> 00:49:07,810 +هي فرعون هذا العصر الامر أناهي وكأنها تقول ما علمت + +443 +00:49:07,810 --> 00:49:14,740 +لكم من إله غيري نعم هذا هو حال فرعونالعصر التي + +444 +00:49:14,740 --> 00:49:20,980 +تكلمنا عنها العولمة أن نكون نحن المسلمين وفق + +445 +00:49:20,980 --> 00:49:27,340 +الرؤية الصهيو أمريكية أو أن نكون تحت إبط اليهود + +446 +00:49:27,340 --> 00:49:35,560 +والأمريكان والعم سام فالعزة والكرامة للمسلمين انما + +447 +00:49:35,560 --> 00:49:41,150 +تكون بالإسلام كما قال سيدنا عمرو بن الخطاباللي أبي + +448 +00:49:41,150 --> 00:49:46,190 +عبيدة بن الجراح لقد كنا أذلاء في الجاهلية فأعزنا + +449 +00:49:46,190 --> 00:49:51,850 +الله بالإسلام ومن يبتغي العزة من غير الإسلام أذله + +450 +00:49:51,850 --> 00:49:56,850 +الله تبارك الله وما حل بالمسلمين من ذلة وهوان كما + +451 +00:49:56,850 --> 00:50:01,590 +نرى في هذه الأيام إلا بسبب بعضهم عن مصدر عزتهم + +452 +00:50:01,590 --> 00:50:06,350 +ومنبع كرامتهم الكتاب والصنة وكما قال الإمام مالك + +453 +00:50:07,210 --> 00:50:11,930 +رضي الله عنه ورحمة الله عليه لن يصلح آخر هذه الأمة + +454 +00:50:11,930 --> 00:50:20,650 +إلا بما صلح به أولها هل صلح أولها بالشيوعية أو + +455 +00:50:20,650 --> 00:50:25,730 +بالقومية أو الوطنية أو العلمانية؟ لاولا + +456 +00:50:25,730 --> 00:50:30,970 +بالرأسمالجة أيضا صلح أولها بالإسلام و لن يصلح + +457 +00:50:30,970 --> 00:50:35,730 +آخرها إلا بالإسلام فعمر بن الخطاب فتح فلسطين + +458 +00:50:35,730 --> 00:50:40,150 +بالإسلام و صلاح الدين الأيوبي حرر فلسطين بالإسلام + +459 +00:50:40,150 --> 00:50:45,930 +و هو ليس عربيا بل من أكراد العراق في الشمال هناك + +460 +00:50:45,930 --> 00:50:57,030 +على مقربة من تركيا نعم هكذا هو الإسلام العظيممصدر + +461 +00:50:57,030 --> 00:51:00,450 +عزتنا وكرامتنا ان شاء الله نأتي الآن إلى السؤال + +462 +00:51:00,450 --> 00:51:04,730 +الأخير عقوبة التحاكم إلى غير شرع الله قلت لكم + +463 +00:51:04,730 --> 00:51:11,650 +سنعود إلى هذه الآية الجريمة آية 65 فافهموها ولا + +464 +00:51:11,650 --> 00:51:20,020 +أقول فاحفظوها جيدا فلا وربك لا يؤمنون نفتالإيمان + +465 +00:51:20,020 --> 00:51:26,140 +عن كل من لم يحتكم إلى شرع الله أو يرضى بشرع الله + +466 +00:51:26,140 --> 00:51:32,900 +عز وجل فلا وربك لا يؤمنون هكذا بصيغة القسم برب + +467 +00:51:32,900 --> 00:51:37,000 +محمد عليه الصلاة والسلام حتى يحكموك يا محمد في + +468 +00:51:37,000 --> 00:51:41,680 +مشاجر بينهم فيما اختلفوا فيه ثم لا يجدوا في أنفسهم + +469 +00:51:41,680 --> 00:51:50,020 +حرجا مما قضيت ويسلموا تسليمة ونريد هناأن نذكر سبب + +470 +00:51:50,020 --> 00:51:56,620 +النزول كما ذكره ابن كثير في التفسير وملخص هذه + +471 +00:51:56,620 --> 00:52:03,860 +القصة أن مسلما والحقيقة أنه تبين لم يكن من + +472 +00:52:03,860 --> 00:52:10,000 +المسلمين المنافق المدسوس في صفوف المسلمين والعياذ + +473 +00:52:10,000 --> 00:52:15,740 +بالله وآخرين من دونهم لا تعلمونهم الله يعلمهم لا + +474 +00:52:15,740 --> 00:52:21,140 +إله هؤلاء ولا إله هؤلاءإلى هؤلاء بوجه وإلى هؤلاء + +475 +00:52:21,140 --> 00:52:25,500 +بوجه والعياذ بالله وإذا لقوا الذين آمنوا قالوا + +476 +00:52:25,500 --> 00:52:30,180 +آمنا وإذا خلوا إلى شياطينهم قالوا إنا معكم إنما + +477 +00:52:30,180 --> 00:52:38,580 +نحن مستهزئون فهذا المسلم اختلف مع يهودي فأراد + +478 +00:52:38,580 --> 00:52:46,360 +المسلم أن يحتكم إلى أحبار اليهود لأن الحبر اليهودي + +479 +00:52:46,360 --> 00:52:52,910 +يرتشهويحكم بغير الحق وأراد هذا اليهودي أن يحتكم + +480 +00:52:52,910 --> 00:52:57,170 +إلى محمد بن عبد الله إلى رسول الله عليه الصلاة + +481 +00:52:57,170 --> 00:53:02,590 +والسلام لأن رسول الله يحكم بالعدل لا يفرق بين مصمم + +482 +00:53:02,590 --> 00:53:08,590 +والكافر وقد مر بنا وسيأتي عند الكلام عن القاعدة + +483 +00:53:08,590 --> 00:53:13,270 +الثانية العدل والمساواة كيف أن العدل في الإسلام + +484 +00:53:13,270 --> 00:53:19,680 +مطلق لا يتأثر بالهواةولا يتأثر بالدين كما سنأتي + +485 +00:53:19,680 --> 00:53:28,080 +إلى أيتين أي 135 من صورةالنساء و آية تمانية من + +486 +00:53:28,080 --> 00:53:32,540 +صورة المائدة و لا يجرمنكم شنقان قوم على أن لا + +487 +00:53:32,540 --> 00:53:36,740 +تعدلوا اعدله و اقربوا للتقوى حتى و لو كان يهوديا + +488 +00:53:36,740 --> 00:53:43,860 +او مصرانيا او مجوسيا او كافرا نعم فهنا انطلق هذا + +489 +00:53:43,860 --> 00:53:49,160 +المسلم المنافق واليهودي الى الرسول فحكم الرسول + +490 +00:53:49,160 --> 00:53:54,850 +لليهوديلأن الحق كان مع اليهودي فغضب هذا المسلم و + +491 +00:53:54,850 --> 00:54:01,930 +قال لأ نحتكم إلى أبي بكر فحكم أبو بكر لليهودي كما + +492 +00:54:01,930 --> 00:54:07,850 +حكم رسول الله لأن الحق مع اليهودي و كانت نهاية هذا + +493 +00:54:07,850 --> 00:54:12,330 +المنافق على يد عمرو بن الخطاب جبار الجاهلية و + +494 +00:54:12,330 --> 00:54:17,550 +الإسلام فقال هذا المنافق نحتكم إلى عمرو بن الخطاب + +495 +00:54:17,550 --> 00:54:26,380 +فقالهل حكم رسول الله؟ قال له نعم وحكم ليه أو بكر + +496 +00:54:26,380 --> 00:54:33,320 +حكم ليه فقال نعم أحكم بينكما بكتاب الله وثنة رسول + +497 +00:54:33,320 --> 00:54:38,040 +الله صلى الله عليه وسلم فعاد إلى بيته وسل سيفه + +498 +00:54:38,040 --> 00:54:44,780 +وقطع رأس هذا المنافق فالنبي عليه السلام قال باء + +499 +00:54:44,780 --> 00:54:52,270 +عمرو بدم الرجلبقى عمر بدم الرجل يحسبه مسلمًا فنزلت + +500 +00:54:52,270 --> 00:54:57,390 +الآيات تذكر لرسول الله أن هذا المسلم ليس بمسلم بل + +501 +00:54:57,390 --> 00:55:04,910 +منافق وهو مرتد وحكمه ضربة بالسيف ولياز بالله وأن + +502 +00:55:04,910 --> 00:55:09,850 +يقتل لأنه لم يمتثل لحكم اللهونزلت هذه الآية + +503 +00:55:09,850 --> 00:55:15,350 +الكريمة خمسة وستين من صورة النساء فلا وربك لا + +504 +00:55:15,350 --> 00:55:21,450 +يؤمنون حتى يحكموك فيما شجر بينهمثم لا يجدوا في + +505 +00:55:21,450 --> 00:55:27,230 +أنفسهم حرجا مما قضيته ويسلموا تسليمه ختامها مِسْك + +506 +00:55:27,230 --> 00:55:31,730 +قول الله تبارك وتعالى وصل اللهم علي سيدنا محمد + +507 +00:55:31,730 --> 00:55:35,750 +أقول قولي هذا وأستغفر الله عليكم والسلام عليكم + +508 +00:55:35,750 --> 00:55:39,730 +ورحمة الله وبركاته ان شاء الله المحاضرة التالية + +509 +00:55:39,730 --> 00:55:46,850 +الأخيرة تكون في الثلاثةبقية الأربعة العدل والمثوى + +510 +00:55:46,850 --> 00:55:53,570 +والشورى والطاعة وبهذا نكون قد ختمنا المقرر أما + +511 +00:55:53,570 --> 00:55:57,750 +المباحث الثلاثة الأخرى الدولة وما بعدها من الفصل + +512 +00:55:57,750 --> 00:56:03,230 +السادس فليست مقررة عليكم ولا مطلوبة في الامتحان + +513 +00:56:03,230 --> 00:56:09,270 +وإلى لقاء ولا أقول وداعا بل السلام عليكم ورحمة + +514 +00:56:09,270 --> 00:56:10,390 +الله وبركاته + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/nEocub7RWbU_raw.json 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"temperature": 1.0}, {"id": 21, "seek": 53638, "start": 518.48, "end": 536.38, "text": "عشرة مصطلحات فقط ان شاء الله من ستين سلاثون صح او خطأ وعشرون اختيار متعدد وعشرة مصطلح توصيل", "tokens": [3615, 8592, 25720, 3714, 9381, 9566, 1211, 5016, 9307, 6156, 47432, 16472, 13412, 16606, 21984, 9154, 8608, 2655, 9957, 8608, 1211, 5718, 104, 11536, 20328, 5016, 1975, 2407, 16490, 9566, 10721, 4032, 3615, 46309, 11536, 1975, 9778, 31371, 9640, 44650, 22488, 3215, 4032, 3615, 8592, 25720, 3714, 9381, 9566, 1211, 5016, 33427, 9381, 26895], "avg_logprob": -0.08146306465972554, "compression_ratio": 1.4732142857142858, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 518.48, "end": 519.14, "word": "عشرة", "probability": 0.9640299479166666}, {"start": 519.14, "end": 520.08, "word": " مصطلحات", "probability": 0.987060546875}, {"start": 520.08, "end": 521.6, "word": " فقط", "probability": 0.982666015625}, {"start": 521.6, "end": 521.8, "word": " ان", "probability": 0.7451171875}, {"start": 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إلى ذلك سريعا عندما + +57 +00:06:23,660 --> 00:06:28,580 +تكلمنا عن مصادر النظم الإسلامية وقلنا يومها + +58 +00:06:28,580 --> 00:06:35,330 +المصادر نوعان مصادر متفق عليها وهي المقصودةفي + +59 +00:06:35,330 --> 00:06:39,790 +المثاق وهي المطلوبة في الامتحان وهي أربعة القرآن + +60 +00:06:39,790 --> 00:06:48,070 +والسنة والإجماع والقياس ولكن قلنا هناك مصادر مختلف + +61 +00:06:48,070 --> 00:06:54,730 +عليها بمعنى أخذ بها بعض الأئمة وتركها بعض الأئمة + +62 +00:06:54,730 --> 00:07:02,830 +فمثلا الحنفية أخذوا بالاستحسان والشافعية أخذوا + +63 +00:07:02,830 --> 00:07:10,390 +بالاستصحابوالمالكيته أخذه بعمل + +64 +00:07:10,390 --> 00:07:16,710 +أهل المدينة فعمل أهل المدينة يعتبر مصدرا من مصادر + +65 +00:07:16,710 --> 00:07:24,330 +التشريه عند الإمام مالكين وهناك أيضا من المصادر + +66 +00:07:24,330 --> 00:07:30,720 +المختلف عليها المصالح المرسلةوالمرسلة بمعنى + +67 +00:07:30,720 --> 00:07:39,200 +المطلقة أي التي لم يتنزل فيها وحي ولم يضعه الرسول + +68 +00:07:39,200 --> 00:07:44,880 +صلى الله عليه وسلم وما أكثر المسائلة في هذا الزمان + +69 +00:07:44,880 --> 00:07:56,080 +حيث يتطور و لكل دولة و لكل عصر دولة ورجال هذا + +70 +00:07:56,080 --> 00:08:03,200 +باختصار معنىالحديث فلو قال أحدهم هاتي بدليل على + +71 +00:08:03,200 --> 00:08:09,830 +مشروعية السيارة فهذه السيارة كان مثلها الدوابأعزكم + +72 +00:08:09,830 --> 00:08:14,810 +الله نعم فهذا من باب السياسة الشرعية أو من باب + +73 +00:08:14,810 --> 00:08:19,370 +المصالح المرسلة ومثلها السكك الحديدية والقطارات + +74 +00:08:19,370 --> 00:08:24,550 +والإشارات الضوئية والتكنولوجيا الحديثة التي لا تضر + +75 +00:08:24,550 --> 00:08:30,090 +بالإسلام ولا تتعارض ومصالح المسلمين إذا التعريف + +76 +00:08:30,090 --> 00:08:36,230 +الأول وانتم لا تطلبون بحفظه غيبا لأنه سيأتيكم في + +77 +00:08:36,230 --> 00:08:43,480 +الامتحانعشرة مصطلحات فقط ان شاء الله من ستين + +78 +00:08:43,480 --> 00:08:55,740 +سلاثون صح او خطأ وعشرون اختيار متعدد وعشرة مصطلح + +79 +00:08:55,740 --> 00:09:01,470 +توصيلو هذا من التيثير عليكم ان شاء الله سيأتيكم + +80 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جاء كما هو هذا + +92 +00:10:13,700 --> 00:10:21,780 +التعريف يجعل السياسة الشرعية سياسة دنيوية بكلمة أو + +93 +00:10:22,700 --> 00:10:28,940 +فلابد من رفع الألف فيكون التعريف الصحيح أقول + +94 +00:10:28,940 --> 00:10:34,640 +انتبهوا إلى هذا استصلاح الخلق بإرشادهم إلى الطريق + +95 +00:10:34,640 --> 00:10:39,960 +المنجي في العاجلي والآجلي وهذا كما سيأتي قليل في + +96 +00:10:39,960 --> 00:10:45,890 +الفروقبين السياسة الشرعية والسياسة غير الشرعية عند + +97 +00:10:45,890 --> 00:10:51,630 +غير المسلمين لأن السياسة الشرعية تحقيق مصالح الأمة + +98 +00:10:51,630 --> 00:11:00,290 +في العاجل والاجل فكلمة أو هنا خطأ كبير ولا أريد أن + +99 +00:11:00,290 --> 00:11:07,490 +أتعجل بسؤال في الامتحان قد يأتيكم في الصح غلط نعم + +100 +00:11:08,770 --> 00:11:13,610 +السياسة الشرعية عند المسلمين استصلاح الخلق + +101 +00:11:13,610 --> 00:11:18,010 +بإرشادهم إلى الطريق المنجّف العادل أو الآدل فالذي + +102 +00:11:18,010 --> 00:11:23,530 +لم يحضر مثل هذه الدروس قد يضع صح لماذا يضع صح + +103 +00:11:23,530 --> 00:11:29,090 +لأنها للأسف في الكتاب خطأ مطبعيفانتبهوا إلى ذلك + +104 +00:11:29,090 --> 00:11:35,530 +وصححوها الإجابة الصحيحة استصلاح الخلق بإرشادهم إلى + +105 +00:11:35,530 --> 00:11:42,550 +الطريق المناد في العاجل والآجل وليس كلمة أو اللهم + +106 +00:11:42,550 --> 00:11:48,590 +فاشهد أني بلغت ثالثا وهي صحيحة ليس فيها أخطاء + +107 +00:11:48,590 --> 00:11:55,510 +مطبعية حملوا الكافة والكافة هم الناسحملوا الكافة + +108 +00:11:55,510 --> 00:12:00,670 +على مقتضى النظر الشرعي في مصالحهم الأخروية + +109 +00:12:00,670 --> 00:12:09,370 +والدنيوية الراجعة إليها رأيتم؟ نعم هنا قاموا + +110 +00:12:09,370 --> 00:12:14,710 +بتصحيح الخطأ في التعريف الثاني + +111 +00:12:16,490 --> 00:12:21,150 +الاخراوية والدنياوية إذا السياسة الشرعية باختصار + +112 +00:12:21,150 --> 00:12:27,090 +تحقيق مصالح الأمة أو مصالح الخلق أو مصالح الكافة + +113 +00:12:27,090 --> 00:12:32,910 +أو الناس في الدنيا والآخرة عبر عنها في التعريف + +114 +00:12:32,910 --> 00:12:36,390 +الثاني في العاجل والآجل في العاجل يعني في الدنيا + +115 +00:12:36,390 --> 00:12:43,810 +والآجل يعني في الآخر الآن بعد أن عرفنا السياسة عند + +116 +00:12:43,810 --> 00:12:48,010 +المسلميننأتي إلى سياسة عند غير مسلمين وهي في + +117 +00:12:48,010 --> 00:12:57,010 +الحقيقة تعريفات مبطورة ولكنها رحمة بكم نعم فأول + +118 +00:12:57,010 --> 00:13:03,370 +هذه التعريفات وهي أجمعها إن كان سيأتيكم سؤال فهو + +119 +00:13:03,370 --> 00:13:11,770 +هذا التعريف فن حكم المجتمعات الإنسانية والتعريف + +120 +00:13:11,770 --> 00:13:20,560 +الثاني فن الحكموالتعريف الثالث علم الدولة هذه هي + +121 +00:13:20,560 --> 00:13:26,280 +السياسة عند غير المسلمين تعريفات كما ترون قصيرة و + +122 +00:13:26,280 --> 00:13:32,340 +مبتورة وكان الأولى أن تستبدل بغيرها من مصطلحات + +123 +00:13:32,340 --> 00:13:39,780 +أخرى ماذا نرى هنا فأن حكم المجتمعات الإنسانية في + +124 +00:13:39,780 --> 00:13:46,070 +العاجل دون الآجلبمعنى في الدنيا دون الآخرة لأن + +125 +00:13:46,070 --> 00:13:52,910 +هؤلاء الكفار لا يؤمنون بالآخرة إنما همهم هو إشباع + +126 +00:13:52,910 --> 00:14:02,630 +بطونهم وشهواتهم وغرائصهم وإرضاء شعوبهم الذين + +127 +00:14:02,630 --> 00:14:08,150 +انتخبوهم ورفعوهم إلى سدة الحكم حتى في الطورات + +128 +00:14:08,150 --> 00:14:13,590 +والإنجيل وليس في القرآن فقط حرّم الله الزناوحرّم + +129 +00:14:13,590 --> 00:14:20,370 +الله الخمرة وحرّم الله الربا ومع ذلك أحل الزنا وما + +130 +00:14:20,370 --> 00:14:25,790 +هو أخطر من الزنا الشذوذ أن ينكح الرجل الرجل + +131 +00:14:25,790 --> 00:14:35,030 +والمرأة المرأة بل هناك عقود رسمية في المحاكم وفي + +132 +00:14:35,030 --> 00:14:42,690 +الكنائس عندهم يقرون أن يتثوج زواجا حلالاأو شرعيا + +133 +00:14:42,690 --> 00:14:48,490 +بلغتهم الرجل الرجل و المرأة المرأة وهذا كله مخالف + +134 +00:14:48,490 --> 00:14:52,490 +لا أقول لما جاء في القرآن بل لما جاء في التوراتي و + +135 +00:14:52,490 --> 00:14:57,470 +الانديل فهي من الكليات الخامس حفظوا العقل و حفظوا + +136 +00:14:57,470 --> 00:15:06,390 +النسل و الفرج و حفظوا المال فحافظ الله العقل + +137 +00:15:06,390 --> 00:15:14,950 +بتحريم الخمروحفظ النسل بتحريم الزنا وحفظ المال + +138 +00:15:14,950 --> 00:15:22,190 +بتحريم الربا نعم فإذا ما جاءكم سؤال السياسة عند + +139 +00:15:22,190 --> 00:15:27,430 +غير المسلمين فأن حكم المجتمعات الإنسانية بالعادل + +140 +00:15:27,430 --> 00:15:34,790 +والآدل الإجابة خطأ وإذا جاءكم سؤالالسياسة عند + +141 +00:15:34,790 --> 00:15:41,250 +المسلمين فان حكم المجتمعات الإنسانية في العاجل دون + +142 +00:15:41,250 --> 00:15:48,790 +الآجل أو في العاجل أو الآجل فالإجابة أيضا خطأ هكذا + +143 +00:15:48,790 --> 00:15:56,110 +نجد أن هناك تشابه بين السياسة عند المسلمين وعند + +144 +00:15:56,110 --> 00:16:02,630 +غير المسلمين ووجه التشابهأن علماء المسلمين وغيرهم + +145 +00:16:02,630 --> 00:16:09,810 +يرون أن السياسة هي تدبير شؤون البلاد والعباد ولكن + +146 +00:16:09,810 --> 00:16:16,410 +على اختلاف بينهم في كافية ذلك ولعله قد مر بنا في + +147 +00:16:16,410 --> 00:16:21,530 +صدر الكتاب عندما تكلمنا عن تعريف النظم عند + +148 +00:16:21,530 --> 00:16:31,140 +المسلمين وعند غير المسلمين وقلنا هناكتشابها أيضا + +149 +00:16:31,140 --> 00:16:36,280 +في حياة واحدة وهي أن النظم الإسلامية شكل من أشكال + +150 +00:16:36,280 --> 00:16:43,360 +النظم بوجه عام من حيث إنها تطبط و تنظم صلوك + +151 +00:16:43,360 --> 00:16:48,520 +ومعاملات أفراد المجتمع الذي آمن بها أو خضع وانقاد + +152 +00:16:48,520 --> 00:16:55,140 +لإحكامها وقوانينها هكذا تتفق النظم الإسلامية مع + +153 +00:16:55,140 --> 00:17:02,620 +غير الإسلاميةوهنا أيضا تتفق السياسة الشرعية وغير + +154 +00:17:02,620 --> 00:17:13,740 +الشرعية من أن كل منهم تدبير شؤون البلاد والعباد + +155 +00:17:14,910 --> 00:17:20,630 +خلّنا هناك اختلاف من جهة المصدر ومن جهة الغاية أو + +156 +00:17:20,630 --> 00:17:25,550 +الهدف أما من جهة المصدر فكما سبقا ذكرنا في النظم + +157 +00:17:25,550 --> 00:17:29,970 +الإسلامية أن مصدر النظم الإسلامية ومن ثم مصدر + +158 +00:17:29,970 --> 00:17:35,870 +السياسة الإسلامية هو الإسلام أو شرع الله أو القرآن + +159 +00:17:35,870 --> 00:17:43,470 +الكريم وكذلك السنة النبويةعن رسول الله صلى الله + +160 +00:17:43,470 --> 00:17:47,870 +عليه وسلم أما بالنسبة إلى غير المسلمين فهم لا + +161 +00:17:47,870 --> 00:17:54,070 +يؤمنون بأي كتاب سماوي حتى القرآن والإنجيل الكتب + +162 +00:17:54,070 --> 00:17:59,090 +السماوية عفوا التورات والإنجيل الكتب السماوية التي + +163 +00:17:59,090 --> 00:18:03,290 +نزلت عليهم فعند غير المسلمين الحاكم هو القانون + +164 +00:18:03,290 --> 00:18:11,760 +الذي يضعه رجال السياسة أنفسهم أما من حيث الهدففقد + +165 +00:18:11,760 --> 00:18:18,600 +سبق أن تكلمنا عن ذلك عند المصطلحات فهدف النظم + +166 +00:18:18,600 --> 00:18:24,040 +الإسلامية أو السياسة الإسلامية تحقيق مصالح الأمة + +167 +00:18:24,040 --> 00:18:30,680 +في العادل والآجل رأيتم هنا قد صححوا الخطأ الأول في + +168 +00:18:30,680 --> 00:18:41,170 +العاجل والآجل هذا هو الأصح وليس أو الآجلنكرر هذا + +169 +00:18:41,170 --> 00:18:46,230 +للأهمية لأنه موضع سؤال ويخطف فيه كثير من الطلاب + +170 +00:18:46,230 --> 00:18:50,410 +الذين يقرؤون الكتاب بعيدا عن توجيهاتالدكتور + +171 +00:18:50,410 --> 00:18:57,170 +المحاضر نعم تحقيق مصارح الأمة في العاجل والاجل أي + +172 +00:18:57,170 --> 00:19:02,470 +في الدنيا والاخرة حسب تعاليم الإسلام ونظمه أما عند + +173 +00:19:02,470 --> 00:19:06,970 +غير المسلمين فكما أسلفنا فالهدف ليس واحدا عند كل + +174 +00:19:06,970 --> 00:19:12,190 +الجماعات وإنما هو بحسب ما تراه كل جماعة على حدة أو + +175 +00:19:12,190 --> 00:19:19,330 +بحسب ما يراه رجال سياسة فيها لذلك أحلواما حرّم + +176 +00:19:19,330 --> 00:19:30,650 +الله هذا هو باختصار المبحث الأول وهو صغير وقصير + +177 +00:19:30,650 --> 00:19:36,330 +كما ترون تعريف النظم عند المسلمين وعند غير + +178 +00:19:36,330 --> 00:19:44,260 +المسلمين وقد رأينا أن هناك توافقابين التعريفين من + +179 +00:19:44,260 --> 00:19:51,360 +جهة أن كل منها تدبير شؤون البلاد والعباد ولكن + +180 +00:19:51,360 --> 00:19:58,410 +الخلاف من جهة المصدر ومن جهةالغاية أو الهدف من جهة + +181 +00:19:58,410 --> 00:20:02,230 +المصدر قلنا بأن مصدر النظم الإسلامي أو السياسة + +182 +00:20:02,230 --> 00:20:08,170 +الإسلامية هو القرآن والسنة أما عند غير المسلمين + +183 +00:20:08,170 --> 00:20:13,970 +فهو رجال السياسة أو رجال القانون الذين ليس لهم إلا + +184 +00:20:13,970 --> 00:20:20,180 +إرضاء شعوبهمومجتمعاتهم الذين انتخبوهم وجعلوهم في + +185 +00:20:20,180 --> 00:20:25,200 +الحكم من أجل ذلك أحلوا ما حرّم الله في القرآن + +186 +00:20:25,200 --> 00:20:30,660 +والتوراة والإنجيل أما الغاية فالنظم الإسلامية + +187 +00:20:30,660 --> 00:20:37,040 +والسياسة الشرعية هدفها تحقيق مصالح الأمة الإسلامية + +188 +00:20:37,040 --> 00:20:44,470 +في العاجل والآجل في أمور الدنياوية والأخرويةأما + +189 +00:20:44,470 --> 00:20:50,870 +عند غيرهم فعلى العكس من ذلك تماما ليس لهم هدف إلا + +190 +00:20:50,870 --> 00:20:57,050 +تحقيق شهواتهم ونزواتهم الدنيوية فقط دون الأخروية + +191 +00:20:57,050 --> 00:21:02,890 +لعلهم حتى لا يؤمنون بالآخرة كما وصفهم الله إنما هي + +192 +00:21:02,890 --> 00:21:08,730 +حياتنا الدنيا نموت ونحيا وما يهلكنا إلا الدهر هنا + +193 +00:21:08,730 --> 00:21:14,140 +ننطق المبحث الثانيوأريد أن ألفط أنظركم إلى مصطلح + +194 +00:21:14,140 --> 00:21:21,380 +لم يلتفت إليه كثير من الطلاب لأننا تعودنا أن يكون + +195 +00:21:21,380 --> 00:21:28,360 +المصطلح بين قوسين كما مر بنا قبل قليل النظم عند + +196 +00:21:28,360 --> 00:21:32,880 +المسلمين وعند غير المسلمين وكما مر بنا في تعريفات + +197 +00:21:32,880 --> 00:21:39,780 +أخرى مثل تعريف السياسةو تعريف الإجماع و تعريف + +198 +00:21:39,780 --> 00:21:45,800 +الأسرة و تعريف الزواج و تعريفات أخرى كثيرة + +199 +00:21:45,800 --> 00:21:55,600 +كالربانية نعم و الثبات و المرونة ولكن هناك تعريفات + +200 +00:21:55,600 --> 00:22:03,820 +لم يفطن إليها الطلاب و لما تكلمتعن مجالات فرّق + +201 +00:22:03,820 --> 00:22:06,400 +فيها الإسلام بين الراجل و المرأة قلت لكم هناك + +202 +00:22:06,400 --> 00:22:14,400 +تعريف اللعان نعم أكرر من أجل مصلحة الطالب لأنه + +203 +00:22:14,400 --> 00:22:18,960 +يوما جاء هذا المصطلح مصطلح اللعان قد يأتي في + +204 +00:22:18,960 --> 00:22:24,380 +الامتحانات وهو ليس في أعلى الصفحة فجاء الطالب و + +205 +00:22:24,380 --> 00:22:28,900 +يشكر أين يا دكتور هذا المصطلح فقلت له لو حضرت + +206 +00:22:28,900 --> 00:22:35,690 +المحاضراتلعرفت أنه في الهامش فمصطلح اللعان في + +207 +00:22:35,690 --> 00:22:44,070 +الهامش وهنا أقول لكم هنا مصطلح اسمه قواعد النظام + +208 +00:22:44,070 --> 00:22:50,210 +السياسي في الإسلام لكنه ليس له عنوان بارز ولم يوضع + +209 +00:22:50,210 --> 00:22:54,270 +بين قوسين ولذا غاب عن كثير من الطلاب ما هذا + +210 +00:22:54,270 --> 00:23:03,840 +المصطلح المبادئوالثوابت الأساسية التي بنى عليها + +211 +00:23:03,840 --> 00:23:10,540 +الإسلام دولته ويستلهم منها النظام السياسي للحكم + +212 +00:23:10,540 --> 00:23:15,380 +إذا ما هو تعريف قواعد النظام السياسي في الإسلام + +213 +00:23:15,380 --> 00:23:22,900 +المبادئ والثوابت الأساسية التي بنى عليها الإسلام + +214 +00:23:22,900 --> 00:23:31,810 +دولته إذا ما جاء هذا وطبعالن يأتيكم حفظا عن ظهر + +215 +00:23:31,810 --> 00:23:37,150 +القلب وإنما سيأتيكم وتضعون رقمه في الجهة الأخرى + +216 +00:23:37,150 --> 00:23:43,610 +يعني مصطلح توصيل وهذا من كرم الله عليكم أسهل وأيسر + +217 +00:23:43,610 --> 00:23:49,470 +إذا هذه الملحوظة الأولى طبعا قواعد النظام السياسي + +218 +00:23:49,470 --> 00:23:54,830 +كثيرة عدوها ستة وعدوها أكثر وعدوها أقل ولكن نحن + +219 +00:23:54,830 --> 00:24:03,960 +الحقيقة ملتزمونبالكتاب وسوف نقتصر ان شاء الله على + +220 +00:24:03,960 --> 00:24:09,880 +القواعد الأربعة فقواعد النظام السياسي في الإسلام + +221 +00:24:09,880 --> 00:24:17,080 +أربعة كما هي عندنا في الكتاب وهي آخر المقرر في + +222 +00:24:17,080 --> 00:24:24,100 +مساق النظم الإسلامية والأسئلة هنا كثيرة وهي مهمة + +223 +00:24:24,100 --> 00:24:31,130 +جدا أولا الحاكمية للهثانياً العدل والمساواة وثالثا + +224 +00:24:31,130 --> 00:24:38,890 +الشورى ورابعا الطاعة وهكذا في المحاضرة التالية ان + +225 +00:24:38,890 --> 00:24:44,630 +شاء الله نكون قد انتهينا من المقرر بالكلية نبدأ + +226 +00:24:44,630 --> 00:24:49,570 +الآن بالقاعدة الأولى وهي الحاكمية لله ما هو تعريف + +227 +00:24:49,570 --> 00:24:58,290 +الحاكمية الحاكمية لغة مصدر من الفعل حكمةوحكم في + +228 +00:24:58,290 --> 00:25:05,030 +لغة العرب بمعنى قضى ومنه قولهم حكم بالأمر حكما أي + +229 +00:25:05,030 --> 00:25:13,830 +قضى به ويقال حكم له وحكم عليه وحكم فيه وهذا طبعا + +230 +00:25:13,830 --> 00:25:18,870 +لا يعنينا كثيرا لأن المعاني اللغوية لن تأتي في + +231 +00:25:18,870 --> 00:25:23,510 +الامتحان الذي يأتيكم في الامتحان فقط هو المصطلحات + +232 +00:25:23,510 --> 00:25:26,130 +الشرعية نعم + +233 +00:25:28,150 --> 00:25:34,270 +وعلى هذا فمعنى كون الحاكمية لله أي أنه سبحانه + +234 +00:25:34,270 --> 00:25:40,210 +وتعالى بيده القضاء في شؤون عباده وأنه صاحب الحكم + +235 +00:25:40,210 --> 00:25:47,410 +فيهم وله حق التشريع لهم وهو مصدر التشريعوالتقنين + +236 +00:25:47,410 --> 00:25:53,070 +سبحانه وتعالى ولا يحق لهم ولا لأحد منهم أن يشرّع + +237 +00:25:53,070 --> 00:26:00,410 +غير شرعه سبحانه وتعالى أو أن يأمر أحد بالاتباع شرع + +238 +00:26:00,410 --> 00:26:06,430 +غير شرع الله تبارك وتعالى أو يأتمر هو بشرع غير شرع + +239 +00:26:06,430 --> 00:26:13,430 +الله سبحانه وتعالى فالحاكمية لله بمعنى أن الذي + +240 +00:26:13,430 --> 00:26:21,410 +يشرعوأن الذي يُقنّنه للناس + +241 +00:26:21,410 --> 00:26:29,670 +هو الله تبارك وتعالى وأي تشريع وأي قانون يخالف ما + +242 +00:26:29,670 --> 00:26:36,770 +شرع الله فهو كفر والعياذ بالله كما سيأتي يخرجه عن + +243 +00:26:36,770 --> 00:26:43,670 +الملة وسنأتي الآن إلى الأدلة على ذلك ما هي الأدلة؟ + +244 +00:26:44,220 --> 00:26:50,440 +على أن الحاكمية لله وهنا ألفط أنظركم إلى شيء مهم + +245 +00:26:50,440 --> 00:26:55,340 +قد وقع فيه الطلاب من قبل أنهم في المصطلحات لا + +246 +00:26:55,340 --> 00:27:01,720 +يفرقون بين الحاكمية لله وبين الربانية لله الربانية + +247 +00:27:01,720 --> 00:27:11,840 +كما أسلفنا أولى خصائص النظم الإسلاميةوالربانية كما + +248 +00:27:11,840 --> 00:27:18,500 +قلنا إما ربانية المصدر وإما ربانية الغاية فعودوا + +249 +00:27:18,500 --> 00:27:25,220 +إلى ربانية المصدر وتعريفها أن أصول أحكامها ووصف + +250 +00:27:25,220 --> 00:27:31,180 +تشريعاتها مأخوذة من كتاب الله ومن سنة رسول الله + +251 +00:27:31,180 --> 00:27:37,120 +عليه الصلاة والسلام فبعض الطلاب يخلط فيضع مصطلح + +252 +00:27:37,120 --> 00:27:42,390 +الربانيةمحلة الحاكمية ومصطلح الحاكمية محلة + +253 +00:27:42,390 --> 00:27:49,510 +الربانية فخذوا حذركم ولا تقعوا فيما وقع فيه من + +254 +00:27:49,510 --> 00:27:56,070 +سبقكم فنحن نتكلم عن الحاكمية لله بمعنى أن المشرع + +255 +00:27:56,070 --> 00:28:01,830 +هو الله وأن الواضع للقوانين هو الله وليس سواه + +256 +00:28:01,830 --> 00:28:08,140 +سبحانه وتعالىأول هذه الأدلة وهي خمسة قوله تبارك + +257 +00:28:08,140 --> 00:28:13,720 +وتعالى إن الحكم إلا لله في صورة يوسف عليه السلام + +258 +00:28:13,720 --> 00:28:21,560 +إن الحكم إلا لله فلا حاكم إلا الله ولا مشرع إلا + +259 +00:28:21,560 --> 00:28:26,800 +الله سبحانه وتعالى ثانيا في صورة النساء قوله تبارك + +260 +00:28:26,800 --> 00:28:32,020 +وتعالى يريدون أن يتحكموا إلى الطاغوت وقد أمروا أن + +261 +00:28:32,020 --> 00:28:37,470 +يكفروا بهو يريد الشيطان أن يضلهم ضلالا بعيدا + +262 +00:28:37,470 --> 00:28:43,250 +فالتحاكم إلى الله و ليس إلى الطاغوت و الطاغوت و + +263 +00:28:43,250 --> 00:28:53,330 +الطواغيت كل طاغية لم يحكم بشرع الله كل حاكم او + +264 +00:28:53,330 --> 00:29:01,550 +رئيس دولة لم يحكم بما شرع الله او رسول الله في + +265 +00:29:01,550 --> 00:29:08,100 +الكتاب و السنةنعم وكلمة الطاغية والطوغيط أصلها + +266 +00:29:08,100 --> 00:29:13,260 +اللغوي من الفعل طغى وطغى في اللغة بمعنى تجاوز الحد + +267 +00:29:13,260 --> 00:29:18,320 +ومنه قوله تعالى في قصة نوح عليه السلام إِنَّا + +268 +00:29:18,320 --> 00:29:21,180 +لَمَّا طَغَى الْمَاءُ حَمَلْنَاكُمْ فِي + +269 +00:29:21,180 --> 00:29:26,600 +الْجَارِيَةِ إذا الطاغوت كل من تجاوز حدود الله + +270 +00:29:26,600 --> 00:29:34,270 +تبارك وتعالى ثالثا أيضافي صورة أندساء وهذه الآية + +271 +00:29:34,270 --> 00:29:39,910 +لابد أن نقف عندها قليلا لأننا سنأتي اليها في آخر + +272 +00:29:39,910 --> 00:29:43,410 +المبحث + +273 +00:29:43,410 --> 00:29:52,250 +ولها قصة ذكرها العلامة المحدث ابن كثير في تفسيره + +274 +00:29:52,250 --> 00:29:53,850 +العظيم + +275 +00:29:55,600 --> 00:30:02,060 +ولكن لا نتعجل لأن هذه الآية ستأتي إجابة على سؤال + +276 +00:30:02,060 --> 00:30:10,860 +ما حكم من تحاكم إلى شرع غير شرع الله برضا وطواعية + +277 +00:30:10,860 --> 00:30:18,160 +نقول حكمه الكفر أولا و القتل لأنه مرتد عن شريعة + +278 +00:30:18,160 --> 00:30:25,480 +الإسلامو هذه هي الآية و سنأتي إليها تارة أخرى إن + +279 +00:30:25,480 --> 00:30:31,780 +شاء الله تبارك وتعالى فلا وربك رأيتم كيف جاء القسم + +280 +00:30:31,780 --> 00:30:37,840 +والقسم في لغة العرب عندما يأتي للدلالة على أهمية + +281 +00:30:37,840 --> 00:30:44,840 +وعظم وخطر الشيء المقسم به فالقسم لا يكون بأمر تافه + +282 +00:30:44,840 --> 00:30:51,480 +أو حقير أو صغير إنما يكون بشيءخطير أو عظيم فلا + +283 +00:30:51,480 --> 00:30:57,480 +وربك يعني يا محمد لا يؤمنون حتى يحكموك فيما شجر + +284 +00:30:57,480 --> 00:31:04,820 +بينهم ثم لا يجدوا في أنفسهم حرجا مما قضيت ويسلموا + +285 +00:31:04,820 --> 00:31:11,480 +تسليما نعم حتى لا يكفي الرضا + +286 +00:31:11,480 --> 00:31:20,060 +بالقضاء لأنه قد يرضى كارها انما لابدمدل التسليم + +287 +00:31:20,060 --> 00:31:29,920 +ويسلموا تسليمة بمعنى الرضاء التام بشرع الله وبحكم + +288 +00:31:29,920 --> 00:31:36,100 +الله تبارك وتعالى وإلا لا يكون مؤمنًا يكون مرتدًا + +289 +00:31:36,100 --> 00:31:40,980 +قد خرج عن ملة الإسلام والعياذ بالله أما الدليل + +290 +00:31:40,980 --> 00:31:50,690 +الرابع فإن العقل السليم يقرهأن الحاكمية لله سبحانه + +291 +00:31:50,690 --> 00:31:57,830 +وتعالى وكيف ذلك من خلال حقيقتين + +292 +00:31:57,830 --> 00:32:07,870 +ونخرج بالثالثة وهذه على طريقة علم المنطق أن نأتي + +293 +00:32:07,870 --> 00:32:15,820 +بقاعدتين وأن نخرج بقاعدة ثالثةأو بحقيقتين و أن + +294 +00:32:15,820 --> 00:32:24,040 +نأتي بحقيقة ثالثة و نحن نستعمل ذلك في الشريعة + +295 +00:32:24,040 --> 00:32:36,420 +الإسلامية أيضا عندما نقول مثلا الصلاة فرض كيف + +296 +00:32:36,420 --> 00:32:41,460 +عرفنا أن الصلاة فرض الله تبارك وتعالى يقول أقيم + +297 +00:32:41,460 --> 00:32:52,050 +الصلاةفأقيموا فعلوا أمر والأمر يفيد الوجوب فدل على + +298 +00:32:52,050 --> 00:33:00,130 +أن الصلاة واجبة وكذلك قوله تبارك وتعالى وآتوا + +299 +00:33:00,130 --> 00:33:06,810 +الذكاء آتوا أمر والأمر يفيد الوجوب فالذكاء واجبة + +300 +00:33:06,810 --> 00:33:15,280 +وكذلك مثلا في الناهية ولا تقربوا الزنالا تقربوا + +301 +00:33:15,280 --> 00:33:23,300 +نهي و النهي يفيد التحريم فالزنا حرام ولا تقتلوا + +302 +00:33:23,300 --> 00:33:28,160 +النفس ولا تأكلوا أموالكم بينكم بالباطل إلى غير ذلك + +303 +00:33:28,160 --> 00:33:35,480 +و كذلك هنا نقول هناك حقيقتين الحقيقة الأولى أن + +304 +00:33:35,480 --> 00:33:43,970 +الله هو الخالق و ما أكثر الآيات على ذلكنقتصر + +305 +00:33:43,970 --> 00:33:49,370 +ببعضها مثل قوله تبارك وتعالى خلق كل شيء فقدره + +306 +00:33:49,370 --> 00:33:55,370 +تقديرا والآيات عندكم في الكتاب والحقيقة الثانية أن + +307 +00:33:55,370 --> 00:34:01,470 +الله هو الرازق وما أكثر الآيات ومنها قوله تبارك + +308 +00:34:01,470 --> 00:34:07,810 +وتعالى وفي السماء رزقكم وما توعدون هنا نقول إذا + +309 +00:34:07,810 --> 00:34:13,560 +كان الله هو الخالقوإذا كان الله هو الرازق فإن الله + +310 +00:34:13,560 --> 00:34:19,940 +هو المالك فالمالك هو الحقيقة الثالثة أو الثمرة + +311 +00:34:19,940 --> 00:34:26,040 +التي نجمت عن الحقيقتين الأولى والثانية مرة ثانية + +312 +00:34:26,040 --> 00:34:31,370 +نقول إذا كان الله هو الخالقوإذا كان الله هو الرازق + +313 +00:34:31,370 --> 00:34:37,510 +فإن الله هو المالك ومعنى المالك أي أنه سبحانه + +314 +00:34:37,510 --> 00:34:43,650 +وتعالى هو المتصرف في ملكه كيف يشاء فأنت أيها + +315 +00:34:43,650 --> 00:34:51,030 +المخلوق لو كنت تملك مثلا بيتا فأنت حر التصرف فيه + +316 +00:34:51,030 --> 00:35:00,960 +لك مثلا أن تبيعهولك أن تنتفع به بالسكنة ولك أن + +317 +00:35:00,960 --> 00:35:10,580 +تؤجره ولك أن تهبه هبطا بدون مقابل ولك أيضا أنتتصدق + +318 +00:35:10,580 --> 00:35:15,700 +به أو أن توقفه إذا أنت أيها المخلوق الصغير من خلق + +319 +00:35:15,700 --> 00:35:21,440 +الله إذا كنت تملك شيئا فانت حر التصرف فيه ما بين + +320 +00:35:21,440 --> 00:35:29,460 +بيع و سكنة و إيجارة و هبة و وقف و صدقة إلى غير ذلك + +321 +00:35:29,460 --> 00:35:33,720 +ولله المثل الأعلى إذا كان الله هو المالك فهو + +322 +00:35:33,720 --> 00:35:39,460 +المتصرف في ملكه و في خلقه كيف شاءلأنه الذي خلقهم + +323 +00:35:39,460 --> 00:35:46,580 +فالإنسان خلق الله وصنعة الله وبنيان الرب تبارك + +324 +00:35:46,580 --> 00:35:52,680 +وتعالى وهو أدرى بهم كما مثلنا في بداية المساق + +325 +00:35:52,680 --> 00:35:59,520 +عندما تكلمنا عن النظم الإسلامية وقلنا بأن مصدرها + +326 +00:35:59,520 --> 00:36:05,780 +هو الله تبارك وتعالى ومثلنا بذلك في صانع الآلة + +327 +00:36:05,780 --> 00:36:13,010 +والكتلوجفالـ Catalogue فيه ما يصلح الآلة والصانع + +328 +00:36:13,010 --> 00:36:19,290 +الذي صنع الآلة هو أدرى بما يصلحها إذا فسدت ولله + +329 +00:36:19,290 --> 00:36:23,390 +المثل الأعلى خلق هذا الإنسان وأنزل معه ال + +330 +00:36:23,390 --> 00:36:30,410 +Catalogue إيه هو ال Catalogue؟ القرآن الكريم فإما + +331 +00:36:30,410 --> 00:36:38,170 +يأتينكم مني هدا فمن اتبع هدايا فلا يضل ولا يشقهومن + +332 +00:36:38,170 --> 00:36:43,750 +أعرض عن ذكري فإن له معيشة ضنكة ونحشره يوم القيامة + +333 +00:36:43,750 --> 00:36:48,870 +أعمى قال رب ليه محشرتني أعمى وقد كنت بصيرة قال + +334 +00:36:48,870 --> 00:36:54,510 +كذلك أتتك آيتنا فنسيتها وكذلك اليوم تنسى الآية في + +335 +00:36:54,510 --> 00:37:04,290 +صورة طه نعم إذا الدليل الرابع على أن الحاكمية + +336 +00:37:04,290 --> 00:37:12,580 +لله من خلالحقيقتينه الحقيقة الأولى أن الخالق هو + +337 +00:37:12,580 --> 00:37:18,860 +الله والحقيقة الثانية أن الرازق هو الله فنقول وفق + +338 +00:37:18,860 --> 00:37:24,660 +علم المنطق إذا كان الله هو الخالق وإذا كان الله هو + +339 +00:37:24,660 --> 00:37:29,420 +الرازق نخرج من ذلك بحقيقة ثالثة أن الله هو المالك + +340 +00:37:29,420 --> 00:37:38,200 +بمعنى المتصرف سبحانه وتعالىفي خلقه وفي عباده فهو + +341 +00:37:38,200 --> 00:37:45,980 +أدرى بما يصلحهم سبحانه وتعالى ولذلك له أن يشرّع + +342 +00:37:45,980 --> 00:37:52,400 +لهم ما يشاء عز وجل أما خامسا لا إله إلا الله تقرر + +343 +00:37:52,400 --> 00:38:02,060 +أن الحاكمية لله لا إله إلا الله أولا هي عبارة عن + +344 +00:38:02,060 --> 00:38:13,000 +شقينهالشق الأول نفي مطلق لا إله والشق الثاني إثبات + +345 +00:38:13,000 --> 00:38:21,300 +مطلق إلا الله لا إله نفي مطلق نفت كل إله إلا الله + +346 +00:38:21,300 --> 00:38:30,830 +إثبات مطلق أثبتت الألوهية للهوأن الحاكمية لله + +347 +00:38:30,830 --> 00:38:37,470 +ومعنى لا إله إلا الله لا معبود بحق في الوجود سواء + +348 +00:38:37,470 --> 00:38:44,870 +الله سبحانه وتعالى ومن ثم الحاكمية لله عز وجل + +349 +00:38:44,870 --> 00:38:53,030 +وكذلك نقول هنا لابد من التفريق بين كلمة إله وبين + +350 +00:38:53,030 --> 00:39:00,410 +كلمة الله فكلمة الله هيلا تُطلَق إلا على الله + +351 +00:39:00,410 --> 00:39:06,250 +سبحانه وتعالى ولذلك لابد أن تُكتب باللغة الأجنبية + +352 +00:39:06,250 --> 00:39:16,350 +اللهوهذا للأسف ما أخطأ فيه الذين ترجموا معاني + +353 +00:39:16,350 --> 00:39:21,490 +القرآن الكريم ولا أقول القرآن الكريم لأننا لما + +354 +00:39:21,490 --> 00:39:25,110 +تكلمنا عن المصدر الأول من مصادر النظم الإسلامية + +355 +00:39:25,110 --> 00:39:33,070 +القرآن الكريم تكلمنا من خصائصه أنه لا يترجم حتى و + +356 +00:39:33,070 --> 00:39:39,280 +لو كانت الترجمة دقيقة جدالأن الترجمة من كلام البشر + +357 +00:39:39,280 --> 00:39:45,800 +والقرآن كلام الله المعجز المتعبد بتلاوته سبحانه + +358 +00:39:45,800 --> 00:39:53,440 +وتعالى من أجل ذلك قال الفصحاء والبلغاء ترجمت معاني + +359 +00:39:53,440 --> 00:39:58,600 +الفاظ القرآن الكريم وهذا من أدق لكن عندما ننظر إلى + +360 +00:39:58,600 --> 00:40:04,820 +الشاشة ونحن نستمع إلى القرآن من خلال التلفاز نقرأ + +361 +00:40:04,820 --> 00:40:16,180 +كلمة اللهبمعنى إله يعني جد وهذا خطأ فلابد أن تُكتب + +362 +00:40:16,180 --> 00:40:23,320 +الله الله هكذا باللغة الأجنبية وكلمة إله بمعنى جد + +363 +00:40:23,320 --> 00:40:31,160 +لأن كلمة إله تشمل كل إله حتى و لو كان من البشر مثل + +364 +00:40:31,160 --> 00:40:39,650 +فرعونأو كان من الحجر و الشجر مثل أصنام قريش هبل و + +365 +00:40:39,650 --> 00:40:45,070 +العزة و منات و غيرها حتى الهوى كما سيأتي في القرآن + +366 +00:40:45,070 --> 00:40:50,810 +يكونوا إلها فرأيت من اتخذ إلهة هو هو إذا لابد من + +367 +00:40:50,810 --> 00:40:56,230 +التفريق بين كلمة إله وبين كلمة الله الله لا يطلق + +368 +00:40:56,230 --> 00:41:02,400 +إلا على الله ولذلك قلنا لا إله إلا اللهنفد كل إله + +369 +00:41:02,400 --> 00:41:09,480 +من البشر ومن الشجر ومن الحجر حتى القوانين والأنظمة + +370 +00:41:09,480 --> 00:41:15,180 +الوضعية هي أيضًا آلهة إذا ما طُبّقت تعبدوا من دون + +371 +00:41:15,180 --> 00:41:20,920 +الله عز وجل لا إله إلا الله لا مشرع إلا الله لا + +372 +00:41:20,920 --> 00:41:28,440 +حاكم إلا الله سبحانه وتعالىنأتي إلى الكتاب كلمة + +373 +00:41:28,440 --> 00:41:34,060 +الصنام يُطلَق عليه إله كما في قصة إبراهيم وإذ قال + +374 +00:41:34,060 --> 00:41:40,160 +إبراهيم لأبيه آذر أتتخذ أصناما آلهة فالأصنام قد + +375 +00:41:40,160 --> 00:41:46,100 +تكون آلهة من دون الله وهو الإنسان أفرأيت من اتخذ + +376 +00:41:46,100 --> 00:41:53,180 +إلهه هو والبشر كما في قصة فرعون ما علمت لكم من إله + +377 +00:41:53,180 --> 00:42:02,090 +غيرهوهكذا لا إله إلا الله فعلم أنه لا إله إلا الله + +378 +00:42:02,090 --> 00:42:10,690 +فكلمة الله لا تطلق إلا على الله الخالق الرازق وحده + +379 +00:42:10,690 --> 00:42:16,810 +سبحانه وتعالى وعليه فعندما نقول لا إله نفي المطلق + +380 +00:42:16,810 --> 00:42:22,010 +نكون قد نفينا الألوهية عن كل معبود على الإطلاق صوى + +381 +00:42:22,010 --> 00:42:27,340 +الله وعندما نقول إلا اللهإثبات المطلق نكون قد + +382 +00:42:27,340 --> 00:42:33,360 +أثبتنا الألوهية لله وحده وعز وجل وحصرناها فيه دون + +383 +00:42:33,360 --> 00:42:43,280 +غيره سبحانه وتعالى نعم إذا كل هذه الأدلة دليل على + +384 +00:42:43,280 --> 00:42:51,860 +أن الحاكمية لله طب أعداء الإسلام وموقفهممن + +385 +00:42:51,860 --> 00:43:00,440 +الحاكمية المشكلة ان هؤلاء المشركون يؤمنون بالله + +386 +00:43:00,440 --> 00:43:10,240 +ولكن يكفرون بأن الحاكمية لله ولذلك صمي هؤلاء + +387 +00:43:10,240 --> 00:43:15,280 +بالمشركين لأنهم يؤمنون بالله ويعبدون مع الله آلهة + +388 +00:43:15,280 --> 00:43:21,240 +أخرى وعندما سُولي قالوا انما نعبدهمليقربون إلى + +389 +00:43:21,240 --> 00:43:28,880 +الله ذلفة يعبدون ألهة الأرض من أوثان و أصنام + +390 +00:43:28,880 --> 00:43:36,000 +صنعوها بأيديهم حتى من العجوة كما كانوا يفعلون كما + +391 +00:43:36,000 --> 00:43:39,460 +فعل سيدنا عمرو لما ضحك يوما وسؤل لماذا ضحكت يا + +392 +00:43:39,460 --> 00:43:43,780 +أمير المؤمنين قال أهدا لي خالي في الجاهلية صنما من + +393 +00:43:43,780 --> 00:43:51,110 +عجوة فلمّا جعت أكلتههكذا كانت آلهة أهل الجاهلية + +394 +00:43:51,110 --> 00:44:00,710 +تؤكل و تكسر و يصنع غيرها من الحجر و من الشجر و + +395 +00:44:00,710 --> 00:44:05,170 +لذلك كانوا يؤمنون بأن الله هو الخالق و بأن الله هو + +396 +00:44:05,170 --> 00:44:10,810 +الرازق و بأن الله هو القادر سبحانه وتعالى و + +397 +00:44:10,810 --> 00:44:16,470 +المتصرفكما مثلا في هذه الآية قُل من يرفقكم من + +398 +00:44:16,470 --> 00:44:21,350 +السماء والأرض أما يملك السمع والأبصار ومن يخرج + +399 +00:44:21,350 --> 00:44:26,110 +الحي من الميت ويخرج الميت من الحي ومن يدبر أمره + +400 +00:44:26,110 --> 00:44:31,950 +فسيقولون الله فقول أفلا تتقون هذا هو حاله المشركين + +401 +00:44:31,950 --> 00:44:41,610 +في الجاهلية بل إن أبا جهل في غزوةبدر يعتقد أن الله + +402 +00:44:41,610 --> 00:44:47,430 +هو الناصروالمعين حيث طلب العون والنصرة من الله + +403 +00:44:47,430 --> 00:44:52,790 +سبحانه وتعالى وهو القائل الله منصر أعلى الجندين + +404 +00:44:52,790 --> 00:44:58,790 +وأكرم القبيلتين فاستجاب الله له فكان محمد عليه + +405 +00:44:58,790 --> 00:45:04,310 +الصلاة والسلام هو أعلى الجندين وأكرم القبيلتين + +406 +00:45:04,310 --> 00:45:09,170 +وهذا معنى قوله تعالى في صورة الأنفال إن تستفتحوا + +407 +00:45:09,170 --> 00:45:15,710 +فقد جاءكم الفتحوإن تنتهوا فهو خير لكم وإن تعودوا + +408 +00:45:15,710 --> 00:45:22,810 +نعود ولن تغني عنكم فئتكم شيء و لو كثرت وأن الله مع + +409 +00:45:22,810 --> 00:45:30,750 +المؤمنين وهو الشعر العربي صهير بن أبي سلم يقول فلا + +410 +00:45:30,750 --> 00:45:36,350 +تكتمن الله ما في نفوسكم ليخفى ومهما يكتم الله + +411 +00:45:36,350 --> 00:45:44,000 +يعلميفهو يؤمن بأن الله عالم بالصرائر و الخفاية و + +412 +00:45:44,000 --> 00:45:49,240 +أنه يعلم ما في نفره .. بل إن عنطرة ابن شداد و هو + +413 +00:45:49,240 --> 00:45:57,220 +الشاعر الجاهلي يخاطب محبوبته عبلة و يقول يا عبل + +414 +00:45:57,220 --> 00:46:02,900 +أين من المنية مهرب إن كان ربي في السماء خضها فكل + +415 +00:46:02,900 --> 00:46:08,070 +هذا و ذاك يدل على أنهم كانوا يؤمنون باللهوبأنه + +416 +00:46:08,070 --> 00:46:14,230 +الخالق وبأنه الرازق وبأنه العالم بنفوسهم وأسرارهم + +417 +00:46:14,230 --> 00:46:20,310 +وخفاياهم ولكنهم كانوا يعبدون الأصنام يتقربون إلى + +418 +00:46:20,310 --> 00:46:25,130 +الله حتى تشفى عليهم هذا معنى قوله تعالى والله أعلى + +419 +00:46:25,130 --> 00:46:30,710 +وأعلم ما نعبدهم إلا ليقربون إلى الله ذلفة وقوله + +420 +00:46:30,710 --> 00:46:38,560 +هؤلاء شفعاؤنا عند اللهسبحانه وتعالى أما موقف + +421 +00:46:38,560 --> 00:46:43,780 +المؤمنين من الحاكمية لله فهو كما وصفهم الله في + +422 +00:46:43,780 --> 00:46:50,960 +أكثر من موضع سمعنا وأطعنا غفرانك ربنا وإليك المصير + +423 +00:46:50,960 --> 00:46:57,680 +نعم أو كما قال الله هنا في قوله تبارك وتعالى إنما + +424 +00:46:57,680 --> 00:47:02,690 +كان قول المؤمنينإذا دعوا إلى الله ورسوله ليحكم + +425 +00:47:02,690 --> 00:47:09,070 +بينهم أن يقولوا سمعنا وأطعنا وأولئك هم المفلحون + +426 +00:47:09,070 --> 00:47:14,910 +فالمؤمن إذا سمع الله يقول يا أيها الذين أمنوا سواء + +427 +00:47:14,910 --> 00:47:21,230 +في الأمر يمتثل أو في النهي يجتنب حاله لسانه يقول + +428 +00:47:21,230 --> 00:47:27,870 +سمعنا وأطعنا فالله ورسوله أحب إليه من + +429 +00:47:31,810 --> 00:47:38,810 +أبائه وأمه وولده والناس أجمعين كما جاء في الحديث + +430 +00:47:38,810 --> 00:47:44,670 +في غير هذا الكتاب لا يؤمن أحدكم حتى أكون أحب إليه + +431 +00:47:44,670 --> 00:47:51,290 +من والده وولده والناس أجمعين نأتي الآن إلى حكم من + +432 +00:47:51,290 --> 00:47:58,040 +أخطر الأحكام حكم من لم يرضى بحكم اللهتبارك وتعالى + +433 +00:47:58,040 --> 00:48:05,100 +هنا أولا والعياذ بالله الكفر لأنها جاءت في آيات + +434 +00:48:05,100 --> 00:48:11,520 +متواليات في صورة المائدة ومن لم يحكم بما أنزل الله + +435 +00:48:11,520 --> 00:48:16,560 +فأولئك هم الكافرون ومن لم يحكم بما أنزل الله + +436 +00:48:16,560 --> 00:48:20,700 +فأولئك هم الظالمون ومن لم يحكم بما أنزل الله + +437 +00:48:20,700 --> 00:48:29,250 +فأولئك همالفاسقون فهم كافرون وظالمون وفاسقون فالذي + +438 +00:48:29,250 --> 00:48:38,110 +يرفض ان يحكم بما أنزل الله كافر ظالم فاسق والعياذ + +439 +00:48:38,110 --> 00:48:43,710 +بالله فهو كافر قد خرج عن ملة الإسلام + +440 +00:48:47,710 --> 00:48:52,670 +ما هي نتائج الحكم بغير ما أنذر الله طبعا ما نراه + +441 +00:48:52,670 --> 00:49:00,530 +اليوم من سيطرة الكفار على المسلمين فأصبحت أمريكا + +442 +00:49:00,530 --> 00:49:07,810 +هي فرعون هذا العصر الامر أناهي وكأنها تقول ما علمت + +443 +00:49:07,810 --> 00:49:14,740 +لكم من إله غيري نعم هذا هو حال فرعونالعصر التي + +444 +00:49:14,740 --> 00:49:20,980 +تكلمنا عنها العولمة أن نكون نحن المسلمين وفق + +445 +00:49:20,980 --> 00:49:27,340 +الرؤية الصهيو أمريكية أو أن نكون تحت إبط اليهود + +446 +00:49:27,340 --> 00:49:35,560 +والأمريكان والعم سام فالعزة والكرامة للمسلمين انما + +447 +00:49:35,560 --> 00:49:41,150 +تكون بالإسلام كما قال سيدنا عمرو بن الخطاباللي أبي + +448 +00:49:41,150 --> 00:49:46,190 +عبيدة بن الجراح لقد كنا أذلاء في الجاهلية فأعزنا + +449 +00:49:46,190 --> 00:49:51,850 +الله بالإسلام ومن يبتغي العزة من غير الإسلام أذله + +450 +00:49:51,850 --> 00:49:56,850 +الله تبارك الله وما حل بالمسلمين من ذلة وهوان كما + +451 +00:49:56,850 --> 00:50:01,590 +نرى في هذه الأيام إلا بسبب بعضهم عن مصدر عزتهم + +452 +00:50:01,590 --> 00:50:06,350 +ومنبع كرامتهم الكتاب والصنة وكما قال الإمام مالك + +453 +00:50:07,210 --> 00:50:11,930 +رضي الله عنه ورحمة الله عليه لن يصلح آخر هذه الأمة + +454 +00:50:11,930 --> 00:50:20,650 +إلا بما صلح به أولها هل صلح أولها بالشيوعية أو + +455 +00:50:20,650 --> 00:50:25,730 +بالقومية أو الوطنية أو العلمانية؟ لاولا + +456 +00:50:25,730 --> 00:50:30,970 +بالرأسمالجة أيضا صلح أولها بالإسلام و لن يصلح + +457 +00:50:30,970 --> 00:50:35,730 +آخرها إلا بالإسلام فعمر بن الخطاب فتح فلسطين + +458 +00:50:35,730 --> 00:50:40,150 +بالإسلام و صلاح الدين الأيوبي حرر فلسطين بالإسلام + +459 +00:50:40,150 --> 00:50:45,930 +و هو ليس عربيا بل من أكراد العراق في الشمال هناك + +460 +00:50:45,930 --> 00:50:57,030 +على مقربة من تركيا نعم هكذا هو الإسلام العظيممصدر + +461 +00:50:57,030 --> 00:51:00,450 +عزتنا وكرامتنا ان شاء الله نأتي الآن إلى السؤال + +462 +00:51:00,450 --> 00:51:04,730 +الأخير عقوبة التحاكم إلى غير شرع الله قلت لكم + +463 +00:51:04,730 --> 00:51:11,650 +سنعود إلى هذه الآية الجريمة آية 65 فافهموها ولا + +464 +00:51:11,650 --> 00:51:20,020 +أقول فاحفظوها جيدا فلا وربك لا يؤمنون نفتالإيمان + +465 +00:51:20,020 --> 00:51:26,140 +عن كل من لم يحتكم إلى شرع الله أو يرضى بشرع الله + +466 +00:51:26,140 --> 00:51:32,900 +عز وجل فلا وربك لا يؤمنون هكذا بصيغة القسم برب + +467 +00:51:32,900 --> 00:51:37,000 +محمد عليه الصلاة والسلام حتى يحكموك يا محمد في + +468 +00:51:37,000 --> 00:51:41,680 +مشاجر بينهم فيما اختلفوا فيه ثم لا يجدوا في أنفسهم + +469 +00:51:41,680 --> 00:51:50,020 +حرجا مما قضيت ويسلموا تسليمة ونريد هناأن نذكر سبب + +470 +00:51:50,020 --> 00:51:56,620 +النزول كما ذكره ابن كثير في التفسير وملخص هذه + +471 +00:51:56,620 --> 00:52:03,860 +القصة أن مسلما والحقيقة أنه تبين لم يكن من + +472 +00:52:03,860 --> 00:52:10,000 +المسلمين المنافق المدسوس في صفوف المسلمين والعياذ + +473 +00:52:10,000 --> 00:52:15,740 +بالله وآخرين من دونهم لا تعلمونهم الله يعلمهم لا + +474 +00:52:15,740 --> 00:52:21,140 +إله هؤلاء ولا إله هؤلاءإلى هؤلاء بوجه وإلى هؤلاء + +475 +00:52:21,140 --> 00:52:25,500 +بوجه والعياذ بالله وإذا لقوا الذين آمنوا قالوا + +476 +00:52:25,500 --> 00:52:30,180 +آمنا وإذا خلوا إلى شياطينهم قالوا إنا معكم إنما + +477 +00:52:30,180 --> 00:52:38,580 +نحن مستهزئون فهذا المسلم اختلف مع يهودي فأراد + +478 +00:52:38,580 --> 00:52:46,360 +المسلم أن يحتكم إلى أحبار اليهود لأن الحبر اليهودي + +479 +00:52:46,360 --> 00:52:52,910 +يرتشهويحكم بغير الحق وأراد هذا اليهودي أن يحتكم + +480 +00:52:52,910 --> 00:52:57,170 +إلى محمد بن عبد الله إلى رسول الله عليه الصلاة + +481 +00:52:57,170 --> 00:53:02,590 +والسلام لأن رسول الله يحكم بالعدل لا يفرق بين مصمم + +482 +00:53:02,590 --> 00:53:08,590 +والكافر وقد مر بنا وسيأتي عند الكلام عن القاعدة + +483 +00:53:08,590 --> 00:53:13,270 +الثانية العدل والمساواة كيف أن العدل في الإسلام + +484 +00:53:13,270 --> 00:53:19,680 +مطلق لا يتأثر بالهواةولا يتأثر بالدين كما سنأتي + +485 +00:53:19,680 --> 00:53:28,080 +إلى أيتين أي 135 من صورةالنساء و آية تمانية من + +486 +00:53:28,080 --> 00:53:32,540 +صورة المائدة و لا يجرمنكم شنقان قوم على أن لا + +487 +00:53:32,540 --> 00:53:36,740 +تعدلوا اعدله و اقربوا للتقوى حتى و لو كان يهوديا + +488 +00:53:36,740 --> 00:53:43,860 +او مصرانيا او مجوسيا او كافرا نعم فهنا انطلق هذا + +489 +00:53:43,860 --> 00:53:49,160 +المسلم المنافق واليهودي الى الرسول فحكم الرسول + +490 +00:53:49,160 --> 00:53:54,850 +لليهوديلأن الحق كان مع اليهودي فغضب هذا المسلم و + +491 +00:53:54,850 --> 00:54:01,930 +قال لأ نحتكم إلى أبي بكر فحكم أبو بكر لليهودي كما + +492 +00:54:01,930 --> 00:54:07,850 +حكم رسول الله لأن الحق مع اليهودي و كانت نهاية هذا + +493 +00:54:07,850 --> 00:54:12,330 +المنافق على يد عمرو بن الخطاب جبار الجاهلية و + +494 +00:54:12,330 --> 00:54:17,550 +الإسلام فقال هذا المنافق نحتكم إلى عمرو بن الخطاب + +495 +00:54:17,550 --> 00:54:26,380 +فقالهل حكم رسول الله؟ قال له نعم وحكم ليه أو بكر + +496 +00:54:26,380 --> 00:54:33,320 +حكم ليه فقال نعم أحكم بينكما بكتاب الله وثنة رسول + +497 +00:54:33,320 --> 00:54:38,040 +الله صلى الله عليه وسلم فعاد إلى بيته وسل سيفه + +498 +00:54:38,040 --> 00:54:44,780 +وقطع رأس هذا المنافق فالنبي عليه السلام قال باء + +499 +00:54:44,780 --> 00:54:52,270 +عمرو بدم الرجلبقى عمر بدم الرجل يحسبه مسلمًا فنزلت + +500 +00:54:52,270 --> 00:54:57,390 +الآيات تذكر لرسول الله أن هذا المسلم ليس بمسلم بل + +501 +00:54:57,390 --> 00:55:04,910 +منافق وهو مرتد وحكمه ضربة بالسيف ولياز بالله وأن + +502 +00:55:04,910 --> 00:55:09,850 +يقتل لأنه لم يمتثل لحكم اللهونزلت هذه الآية + +503 +00:55:09,850 --> 00:55:15,350 +الكريمة خمسة وستين من صورة النساء فلا وربك لا + +504 +00:55:15,350 --> 00:55:21,450 +يؤمنون حتى يحكموك فيما شجر بينهمثم لا يجدوا في + +505 +00:55:21,450 --> 00:55:27,230 +أنفسهم حرجا مما قضيته ويسلموا تسليمه ختامها مِسْك + +506 +00:55:27,230 --> 00:55:31,730 +قول الله تبارك وتعالى وصل اللهم علي سيدنا محمد + +507 +00:55:31,730 --> 00:55:35,750 +أقول قولي هذا وأستغفر الله عليكم والسلام عليكم + +508 +00:55:35,750 --> 00:55:39,730 +ورحمة الله وبركاته ان شاء الله المحاضرة التالية + +509 +00:55:39,730 --> 00:55:46,850 +الأخيرة تكون في الثلاثةبقية الأربعة العدل والمثوى + +510 +00:55:46,850 --> 00:55:53,570 +والشورى والطاعة وبهذا نكون قد ختمنا المقرر أما + +511 +00:55:53,570 --> 00:55:57,750 +المباحث الثلاثة الأخرى الدولة وما بعدها من الفصل + +512 +00:55:57,750 --> 00:56:03,230 +السادس فليست مقررة عليكم ولا مطلوبة في الامتحان + +513 +00:56:03,230 --> 00:56:09,270 +وإلى لقاء ولا أقول وداعا بل السلام عليكم ورحمة + +514 +00:56:09,270 --> 00:56:10,390 +الله وبركاته + diff --git a/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/zj2-E5j1LaU.srt b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/zj2-E5j1LaU.srt new file mode 100644 index 0000000000000000000000000000000000000000..04f73d25ae50d619dbd40816642b869ad660f846 --- /dev/null +++ b/PL9fwy3NUQKwYDVehtFpV9OlrzbElYsCBI/zj2-E5j1LaU.srt @@ -0,0 +1,1406 @@ +1 +00:00:04,930 --> 00:00:07,750 +عوض سميع الله من الشيطان الرجيم بسم الله الرحمن + +2 +00:00:07,750 --> 00:00:11,630 +الرحيم الحمد لله والصلاة والسلام على رسول الله + +3 +00:00:11,630 --> 00:00:16,050 +دائما و أبدا معطر مجالسنا بالصلاة على الحبيب محمد + +4 +00:00:16,050 --> 00:00:21,730 +صلى الله عليه وسلم بلغ العلا بكماله كشف الدجا + +5 +00:00:21,730 --> 00:00:28,530 +بجماله حصنت جميع خصاله صلوا عليه وآله أعزائي + +6 +00:00:28,530 --> 00:00:32,890 +الطلاب قبل ذي بدء وأرحب بكم جميعا وأحييكم بتحية + +7 +00:00:32,890 --> 00:00:37,150 +الإسلام فالسلام عليكم ورحمته وبركاته و + +8 +00:00:37,150 --> 00:00:43,310 +اليوم ما زلنا مع الفصل الرابع نظام الأسرة في + +9 +00:00:43,310 --> 00:00:50,000 +الإسلام ومع تكملة المبحث الثالث الزواج ونكون على + +10 +00:00:50,000 --> 00:00:56,200 +موعد إن شاء الله مع القسم الثالث من أقسام الحقوق + +11 +00:00:56,200 --> 00:01:02,380 +الزوجية وسبق الحديث عن القسم الأول وهو حقوق الزوج + +12 +00:01:03,360 --> 00:01:09,040 +وتكلمنا عن القسم الثاني وهو حقوق الزوجة واليوم إن + +13 +00:01:09,040 --> 00:01:14,160 +شاء الله وبعون الله نكون على موعد مع الحقوق + +14 +00:01:14,160 --> 00:01:20,020 +المشتركة بين الزوجين وأول هذه الحقوق إباحة + +15 +00:01:20,020 --> 00:01:26,620 +المعاشرة الزوجية وقد تكلمنا عن ذلك عند الحديث عن + +16 +00:01:26,620 --> 00:01:34,200 +حكم الزواج فهذه شهوة في كل الزوجين لابد أن تخرج + +17 +00:01:34,200 --> 00:01:43,980 +ولكنها لا تخرج إلا عبر قنوات شرعية ولا قناة شرعية + +18 +00:01:43,980 --> 00:01:51,440 +تفرغ فيها الشهوة إلا عبر الزواج كما قال الله تبارك + +19 +00:01:51,440 --> 00:01:56,980 +وتعالى والذين هم لفروجهم حافظون إلا على أزواجهم أو + +20 +00:01:56,980 --> 00:02:02,440 +ما ملكت أيمانهم فإنهم غير ملومين فمن ابتغى وراء + +21 +00:02:02,440 --> 00:02:08,360 +ذلك فأولئك هم العادون صدق الله العظيم وقد سبق + +22 +00:02:08,360 --> 00:02:14,800 +الحديث عن قصة الرهبان الثلاثة الذين جاءوا بيوت أزواج + +23 +00:02:14,800 --> 00:02:21,140 +النبي صلى الله عليه وسلم يسألون عن عبادته فلما + +24 +00:02:21,140 --> 00:02:27,580 +أخبروا كأنهم تقالوها أي عدوها قليلة فقال أحدهم أما + +25 +00:02:27,580 --> 00:02:32,560 +أنا فأصوم النهار لا أفطر أبدا وقال الثاني أقوم + +26 +00:02:32,560 --> 00:02:37,220 +الليل لا أرقد أبدا وقال الثالث اعتزل النساء فلا + +27 +00:02:37,220 --> 00:02:43,840 +أتزوج أبدا وهذا ليس من الإسلام فالإسلام كله يسر + +28 +00:02:43,840 --> 00:02:52,180 +وسماحة ورحمة لا تشدد ولا تنطع في هذا الدين الحنيف + +29 +00:02:52,180 --> 00:02:57,610 +كما قال المصطفى صلى الله عليه وسلم هلك المتنطعون، + +30 +00:02:57,610 --> 00:03:03,310 +هلك المتنطعون، هلك المتنطعون، قالها ثلاثا إن + +31 +00:03:03,310 --> 00:03:08,130 +المنبت لا زهرا أبقى ولا أرضا قطع يريد الله بكم + +32 +00:03:08,130 --> 00:03:12,850 +اليسر ولا يريد بكم العسر فلما علم بهم رسول الله + +33 +00:03:12,850 --> 00:03:20,030 +صلى الله عليه وسلم دعاهم وعلمهم يسر الإسلام وسماحة + +34 +00:03:20,030 --> 00:03:27,870 +الإسلام ووساطة هذا الدين العظيم وأنه لا حرج فيه + +35 +00:03:27,870 --> 00:03:33,870 +ولا مشقة إن هذا الدين يسر وليه شد الدين أحد إلا + +36 +00:03:33,870 --> 00:03:39,330 +غلبه وقال صلى الله عليه وسلم كما مر معنا في الحديث + +37 +00:03:39,330 --> 00:03:45,170 +إني أخشاكم لله وأتقى لكم له ولكنّي أصوم وأفطر و + +38 +00:03:45,170 --> 00:03:50,670 +أصلي وأرقد وأتزوج النساء فمن رغب عن سنتي فليس + +39 +00:03:50,670 --> 00:03:57,190 +مني وقد مر بنا في أحكام الزواج أن الرأي الراجح و + +40 +00:03:57,190 --> 00:04:02,900 +الذي عليه الأكثرون من أهل العلم وجمع الفقهاء أن + +41 +00:04:02,900 --> 00:04:07,380 +الزواج في حال اعتدال الشهوة وهو ما عليه عامة الناس + +42 +00:04:07,380 --> 00:04:15,880 +سنة مؤكدة وقد مرت بنا حديث الأربعة فليرجع إليها أما + +43 +00:04:15,880 --> 00:04:22,700 +ثانيا من الحقوق المشتركة بين الزوجين حرمة المصاهرة + +44 +00:04:22,700 --> 00:04:29,640 +وهنا لابد أن نقف عند قاعدة شرعية وهي + +45 +00:04:31,210 --> 00:04:38,190 +الدخول في الأمهات يحرم البنات والعقد على البنات + +46 +00:04:38,190 --> 00:04:44,670 +يحرم الأمهات هذه كلمة انتبهوا إليها ووقفوا عندها + +47 +00:04:44,670 --> 00:04:51,730 +قليلا فإنها تحتاج إلى شرح وتفصيل معنى هذه القاعدة + +48 +00:04:51,730 --> 00:04:58,130 +العظيمة وهي آية في كتاب الله سنأتي إليها بعد قليل + +49 +00:04:58,130 --> 00:05:10,830 +إذا عقد شخص على امرأة ولم يدخل بها ثم طلقها قبل + +50 +00:05:10,830 --> 00:05:19,270 +الدخول بها فإنه يحل له أن يتزوج ابنتها هذا معنى + +51 +00:05:19,270 --> 00:05:26,730 +قولنا الدخول في الأمهات يحرم البنات إذا مرة ثانية + +52 +00:05:26,730 --> 00:05:36,900 +إذا عقد شخص قرانه على امرأة ولم يدخل بها ثم طلقها + +53 +00:05:36,900 --> 00:05:43,800 +قبل أن يدخل بها فله أن يتزوج ابنتها أما إذا دخل + +54 +00:05:43,800 --> 00:05:50,740 +بها فإنه يحرم عليه الزواج بابنتها والعكس في البنت + +55 +00:05:50,740 --> 00:05:57,740 +إذا عقد شخص قرانه على البنت وطلقها قبل أن يدخل بها + +56 +00:05:57,740 --> 00:06:06,350 +فإنه يحرم عليه أمها نعم وهذا معنى قولنا العقد على + +57 +00:06:06,350 --> 00:06:12,630 +البنات يحرم الأمهات إذا القاعدة الشرعية مرة ثانية + +58 +00:06:12,630 --> 00:06:20,620 +وثالثة الدخول في الأمهات يحرم البنات والعقد على + +59 +00:06:20,620 --> 00:06:27,080 +البنات يحرم الأمهات قلت وبالمثال يتضح المقال + +60 +00:06:27,080 --> 00:06:34,500 +لأهمية هذه القاعدة نعيد للمرأة الثانية والثالثة لو + +61 +00:06:34,500 --> 00:06:41,840 +أن شخصا عقد قرانه على امرأة وطلقها قبل أن يدخل بها + +62 +00:06:41,840 --> 00:06:49,930 +فإنه تحل له ابنتها وإذا دخل بها فإنه يحرم عليه + +63 +00:06:49,930 --> 00:06:55,770 +الزواج بابنتها والعكس في البنت إذا ما عقد قرانه + +64 +00:06:55,770 --> 00:07:02,450 +على البنت إيجابا وقبولا وبحضور الولي والشهود ولم + +65 +00:07:02,450 --> 00:07:10,330 +يدخل بها ثم طلقها فإنه يحرم عليه أمها وإن لم يدخل + +66 +00:07:10,330 --> 00:07:17,150 +بها هذا معنى قول الفقهاء العقد على البنات وإن لم + +67 +00:07:17,150 --> 00:07:23,410 +يدخل بهن يحرم الأمهات أما العقد على البنات أما + +68 +00:07:23,410 --> 00:07:29,990 +العقد على الأمهات فلا يحرم البنات إنما الدخول في + +69 +00:07:29,990 --> 00:07:35,810 +الأمهات يحرم البنات وهذا معنى قوله تبارك وتعالى + +70 +00:07:35,810 --> 00:07:46,510 +والله أعلى وأعلم و .. ربائبكم ربائبكم الربائب جمع + +71 +00:07:46,510 --> 00:07:58,190 +ربيبة وربيبة هنا فعيل بمعنى مفعول مثل قتيل بمعنى + +72 +00:07:58,190 --> 00:08:06,040 +مقتول مفتول بمعنى مفتول ومبيع بمعنى مبيوع وهنا + +73 +00:08:06,040 --> 00:08:12,800 +أيضا خطيبة بمعنى مخطوبة وربيبة بمعنى مربوبة أي + +74 +00:08:12,800 --> 00:08:20,660 +أنها ربيت في بيت الزوج الجديد وهذه الآية تحكي قصة + +75 +00:08:20,660 --> 00:08:26,120 +امرأة لعلها أرملة تركت + +76 +00:08:29,390 --> 00:08:37,490 +نعم بيتها وانتقلت إلى بيت زوجها الجديد وكان الناس + +77 +00:08:37,490 --> 00:08:42,810 +في عهد السلف الصالح أحسن منها حالا في هذه الأيام + +78 +00:08:42,810 --> 00:08:49,350 +في هذه الأيام وأقولها بكل أسف وألم ومرارة إذا ما + +79 +00:08:49,350 --> 00:08:56,370 +تزوجت زوجة الشهيد أو المرأة الأرملة التي توفي + +80 +00:08:56,370 --> 00:09:03,070 +زوجها وترك لها بنت أو بنات فإن الزوج الجديد يشترط + +81 +00:09:03,070 --> 00:09:11,250 +عليها أن يحال بينها وبين ابنتها وهنا قد تتشتت + +82 +00:09:11,250 --> 00:09:17,810 +الأسرة لأنها قد تربى في حضن الجد أو في حضن الجدة + +83 +00:09:17,810 --> 00:09:26,540 +والبنت أو الابن حقيقة لا يربى إلا في حضن أمه في + +84 +00:09:26,540 --> 00:09:31,240 +قديم الزمان في عهد سلفنا الصالح رضوان الله عليهم + +85 +00:09:31,240 --> 00:09:36,640 +أجمعين كانوا عندما يتزوجون بالأم الأرملة كانوا + +86 +00:09:36,640 --> 00:09:45,800 +يأتون بأيتامها فيربون في بيت الزوج الجديد ولذلك + +87 +00:09:45,800 --> 00:09:54,130 +صمّت ربيبة بمعنى أنها تربى في بيت زوج أمها في هذه + +88 +00:09:54,130 --> 00:10:02,470 +الحال كما أسلفنا إذا ما دخل الزوج الجديد بالأم فإن + +89 +00:10:02,470 --> 00:10:11,770 +هذه الربيبة تصبح في حكم بناته تحرم عليه حرمة مؤبدة + +90 +00:10:11,770 --> 00:10:20,170 +إذا ما دخل بأمها لأن هذه الآيات من صورة النساء + +91 +00:10:20,170 --> 00:10:28,110 +إنما تتكلم عن المحرمات من النساء والمحرمات مؤبدا + +92 +00:10:28,740 --> 00:10:35,320 +لكن نضيف من أجل الفائدة العلمية لو أن هذا الزوج + +93 +00:10:35,320 --> 00:10:43,360 +الجديد كان له ابن فيحل له أن يتزوج بابنة زوجته، + +94 +00:10:43,360 --> 00:10:49,990 +إذا هذا الزوج يتزوج بالمرأة وابنه يتزوج بابنتها + +95 +00:10:49,990 --> 00:10:55,610 +التي سماها القرآن الكريم الربيبة هذا معنى قوله + +96 +00:10:55,610 --> 00:11:00,530 +تبارك وتعالى والله أعلم أعلم وربائبكم التي في + +97 +00:11:00,530 --> 00:11:07,270 +حجوركم باعتبار الغالب طب إن لم تكن في حجره وإن لم + +98 +00:11:07,270 --> 00:11:12,230 +تربى في بيته كما أسلفت في هذه الأيام تكون البنت + +99 +00:11:12,230 --> 00:11:18,850 +اليتيمة بعيدة عن بيت زوج أمها أيضا تحرم عليه ولكن + +100 +00:11:18,850 --> 00:11:25,370 +هذا باعتبار الواقع وباعتبار الغالب المعاش في عهد + +101 +00:11:25,370 --> 00:11:32,760 +المسلمين الأوائل وربائبكم التي في حجوركم من نسائكم + +102 +00:11:32,760 --> 00:11:39,340 +التي دخلتم بهن هذا يشرح لنا القاعدة بمعنى إذا دخل + +103 +00:11:39,340 --> 00:11:44,820 +في الأم حرمت عليه البنت وإذا لم يدخل بالأم بمعنى + +104 +00:11:44,820 --> 00:11:50,800 +أنه طلقها قبل الدخول بها فله أن يتزوج بالربيبة أو + +105 +00:11:50,800 --> 00:11:56,920 +بالبنت كما ذكر القرآن الكريم فإن لم تكونوا دخلتم + +106 +00:11:56,920 --> 00:12:05,990 +بهن فلا جناح عليكم بمعنى أن تتزوجوا بالبنات هذا أهم + +107 +00:12:05,990 --> 00:12:12,410 +شيء في الآية وذكر وأمهاتكم اللاتي أرضعنكم + +108 +00:12:12,410 --> 00:12:17,610 +وأخواتكم من الرضاعة لأنه يحرم من الرضاعة ما يحرم + +109 +00:12:17,610 --> 00:12:25,410 +بالنسب وأمهات نسائكم حماتك أم زوجك أيضا كما قلنا + +110 +00:12:25,410 --> 00:12:34,850 +تحرم عليك إذا ما عقدت القرانة على البنت وإن لم تدخل + +111 +00:12:34,850 --> 00:12:42,510 +بالبنت فإن أمها تحرم عليك بمجرد عقد القرانة وحلائل + +112 +00:12:42,510 --> 00:12:51,700 +وأبنائكم كذلك زوجة ابنك والحلائل جمع حليلة بمعنى + +113 +00:12:51,700 --> 00:12:59,160 +الزوجة الذين من أصلابكم نعم لكن الأهم في هذه الآية + +114 +00:12:59,160 --> 00:13:03,640 +هو فهم القاعدة + +115 +00:13:03,640 --> 00:13:10,980 +العقد على البنات يحرم الأمهات وإن لم يتم الدخول في + +116 +00:13:10,980 --> 00:13:16,720 +البنات لو طلقها بعد عقد القران أما الدخول في + +117 +00:13:16,720 --> 00:13:21,600 +الأمهات هو الذي يحرم البنات فلو طلقها بعد العقد و + +118 +00:13:21,600 --> 00:13:26,340 +قبل الدخول فإنه يحل له أن يتزوج مثلا وقد يأتي + +119 +00:13:26,340 --> 00:13:34,740 +السؤال بطريقة أخرى إذا دخل في الأصل حرم عليه الفرع + +120 +00:13:34,740 --> 00:13:42,670 +لأن الأصل هو الأم و أما الفرع هو البنت وإن نزل + +121 +00:13:42,670 --> 00:13:48,170 +وإذا عقد قرانه على الفرع وطلق قبل الدخول فإنه + +122 +00:13:48,170 --> 00:13:56,730 +يحرم عليه الأصل فانتبهوا إلى ذلك نعم ثالثا حق + +123 +00:13:56,730 --> 00:14:07,500 +التوارث فإن الزواجة الصحيحة من ثمارها التوارث بين + +124 +00:14:07,500 --> 00:14:15,300 +الزوجين بمجرد العقد حتى وإن لم يدخل بها فأيهما مات + +125 +00:14:15,300 --> 00:14:21,440 +قبل الآخر والعقد قائم ثبت للموجود في الإرث من تركة + +126 +00:14:21,440 --> 00:14:28,050 +الآخر نصيبا مفروضا وأنا قبل أن أقرأ الآيات وهنا + +127 +00:14:28,050 --> 00:14:33,230 +نحن لا نطالب بحفظ الآيات إنما نطالب بفهم الآيات + +128 +00:14:33,230 --> 00:14:38,990 +وهذا قد يأتينا في الامتحان إما على شكل صح أو خطأ + +129 +00:14:38,990 --> 00:14:50,110 +أو اختيار متعدد نقول وبالله التوفيق إذا ماتت + +130 +00:14:50,110 --> 00:14:51,570 +زوجته + +131 +00:14:53,930 --> 00:15:01,550 +عن غير ولد وهنا بلغة القرآن الكريم عن غير ولد وجمع + +132 +00:15:01,550 --> 00:15:10,050 +الولد أولاد أو ولدان ويطوف عليهم ولدان مخلدون + +133 +00:15:10,050 --> 00:15:18,210 +وأيضا ولد كما في القراءة ويطوف عليهم ولد مخلدون + +134 +00:15:18,210 --> 00:15:24,450 +بكؤوس وأباريق وكأس من معين المهم أن البعض من الناس + +135 +00:15:24,450 --> 00:15:30,310 +يخطئ وقد خطب أحد المشايخ خطبة تكلم فيها عن تربية + +136 +00:15:30,310 --> 00:15:35,170 +الأولاد وإذا برجل يأتيني ويسألني لماذا تكلم عن + +137 +00:15:35,170 --> 00:15:40,510 +الأولاد ولم يتكلم عن البنات وهذا جهل في هذا السائل + +138 +00:15:40,510 --> 00:15:46,570 +في لغة العرب لأن كلمة الولد وهنا نلفت الأنظار إليها + +139 +00:15:46,570 --> 00:15:51,910 +لماذا وقفت هنا حتى لا نقع فيما وقع فيه هذا السائل + +140 +00:15:51,910 --> 00:15:57,750 +الذي يجهل لغة العرب فكلمة ولد إنما تشمل الذكر + +141 +00:15:57,750 --> 00:16:07,210 +والأنثى تشمل الإبن والبنت فالبنت والجمع بنات أما + +142 +00:16:07,210 --> 00:16:15,910 +الإبن فهو جمعه يعامل معاملة المذكر السالم بنون كما + +143 +00:16:15,910 --> 00:16:19,830 +تُلْوَن عند الحديث عن مراحل توجيه الخلق في النفس + +144 +00:16:19,830 --> 00:16:28,230 +البشرية المال والبنون زينة الحياة الدنيا وقد يكون + +145 +00:16:28,230 --> 00:16:34,810 +بنين إذا كانت في حالة النصب أو في حالة الجرّ أي + +146 +00:16:34,810 --> 00:16:45,300 +نعم ف.. ابن يجمع على بنون أو على بنين يُعاملون + +147 +00:16:45,300 --> 00:16:50,280 +معاملة جمع المذكر السالم نعم وقد يُجمع جمع تكسير + +148 +00:16:50,280 --> 00:16:57,700 +فيقول ابن أبناء وأما بنت فتجمع على بنات إذا كلمة + +149 +00:16:57,700 --> 00:17:04,220 +الولد إنما تُطلق على البن الذكر والبنت الأنثى إذا + +150 +00:17:04,220 --> 00:17:14,850 +لو ماتت الزوجة في حياة زوجها وتركت ولداً ولداً + +151 +00:17:14,850 --> 00:17:23,610 +بمعنى فرعا وارثا سواء كان ذكرا أو أنثى ابنا أو + +152 +00:17:23,610 --> 00:17:31,850 +بنتا فإن الزوج يُحجب من النصف إلى الربع فإن الزوجة + +153 +00:17:31,850 --> 00:17:38,730 +يُحجب من النصف إلى الربع لوجود الفرع الوارث فإذا + +154 +00:17:38,730 --> 00:17:44,150 +ماتت الزوجة عن غير ولد وأيضاً هنا أقول معلومة أخرى + +155 +00:17:44,150 --> 00:17:47,990 +عن غير ولد لا يشترط أن يكون الإنجاب من الزوج + +156 +00:17:47,990 --> 00:17:53,410 +الجديد فقد تكون مطلقة مثلاً أو أرملة وقد أنجبت من + +157 +00:17:53,410 --> 00:17:59,160 +الزوج الأول المهم أن يكون لها ولد أو أن لا يكون لها + +158 +00:17:59,160 --> 00:18:04,280 +ولد سواء من الزوج الأول أو من الزوج الثاني فهنا + +159 +00:18:04,280 --> 00:18:12,260 +يكون نصيب الزوج هو النصف وهذا معنى قوله تبارك + +160 +00:18:12,260 --> 00:18:18,020 +وتعالى والله أعلى وأعلم ولكم نصف ما ترك أزواجكم إن + +161 +00:18:18,020 --> 00:18:24,640 +لم يكن لهن ولد إذا عرفنا ما معنى ولد بمعنى فرع + +162 +00:18:24,640 --> 00:18:32,110 +وارث ذكر أو أنثى ابن أو بنت لكم نصف ما ترك أزواجكم + +163 +00:18:32,110 --> 00:18:36,930 +إن لم يكن لهن ولد سواء من الزوج الأول أو من الزوج + +164 +00:18:36,930 --> 00:18:44,170 +الثاني فإن كان لهن ولد فلكم الربع مما تركنا من بعد + +165 +00:18:44,170 --> 00:18:54,130 +وصية يوصين بها أو دين لأن التركة تمر بمراحل أربعة + +166 +00:18:54,130 --> 00:19:05,850 +كما قال الفقهاء دفن فدين فوصية فميراث الدفن أولاً + +167 +00:19:05,850 --> 00:19:15,010 +وهذا يُحسم من رأس المال ثم بعد ذلك تُصَدّى الديون + +168 +00:19:15,010 --> 00:19:22,580 +وديون العباد مقدمة على ديون الله سبحانه وتعالى وبعد + +169 +00:19:22,580 --> 00:19:28,060 +ذلك تُنفذ الوصية ويُفترض في الوصية أن تكون دون + +170 +00:19:28,060 --> 00:19:34,640 +الثلث كما مر معنا في قصة سعد بن أبي وقاص قال الثلث + +171 +00:19:34,640 --> 00:19:42,120 +والثلث كثير إنك انتظر ورثتك أغنياء خير من أن تُظهرهم + +172 +00:19:42,120 --> 00:19:49,400 +عالة يتكففون يعني يشحذون ويسألون الناس أعطوهم أو + +173 +00:19:49,400 --> 00:19:56,770 +منعوهم نعم وبعد ذلك يكون الميراث كما قال الله + +174 +00:19:56,770 --> 00:20:01,090 +تعالى يُوصيكم الله في أولادكم للذكر مثل حظ الأنثيين + +175 +00:20:01,090 --> 00:20:07,190 +والحديث هنا يُختصر فقط على نصيب كل من الزوجين من + +176 +00:20:07,190 --> 00:20:19,710 +الآخر نعم ولهُ هنا الربع مما تركتم هنا نأتي إلى نصيب + +177 +00:20:20,450 --> 00:20:26,950 +الزوجة من ميراث زوجها إذا ما توفي في حياتها فإذا + +178 +00:20:26,950 --> 00:20:32,170 +ما كان للزوج ولد أقول أيضاً الولد هنا يشمل الذكر + +179 +00:20:32,170 --> 00:20:38,930 +والأنثى الإبن والبنت سواء منها أو من زوجة أخرى + +180 +00:20:38,930 --> 00:20:47,730 +المهم أن له ولد أن له فرعاً وارثاً نعم فيكون نصيبها + +181 +00:20:47,730 --> 00:20:53,370 +إن كان له ولد منها أو من غيرها يكون نصيبها الثمن + +182 +00:20:53,370 --> 00:21:01,350 +فإن لم يُنجب كأن كان عقيماً كما قال الله تعالى يهب + +183 +00:21:01,350 --> 00:21:06,290 +لمن يشاء إناثاً ويهب لمن يشاء الذكور أو يُثوجهم + +184 +00:21:06,290 --> 00:21:10,250 +ذكراً وإناثاً ويجعل من يشاء عقيماً أسأل الله في + +185 +00:21:10,250 --> 00:21:14,450 +هذه الساعة المباركة أن يُرزق كل العطاشين الذرية + +186 +00:21:14,450 --> 00:21:19,450 +الصالحة من أمة محمد أجمعين قولوا آمين اللهم آمين + +187 +00:21:19,450 --> 00:21:25,310 +نعم فيكون حقها عند عدم إنجاب الزوج من غيرها الثمن + +188 +00:21:25,310 --> 00:21:35,010 +وهذا يتماشى ويتناغم مع القاعدة العامة للذكر مثل حظ + +189 +00:21:35,010 --> 00:21:44,790 +الأنثيين وهذا معنى ما ذكره الفقهاء رحمهم الله عليهم + +190 +00:21:44,790 --> 00:21:53,310 +أجمعين عندما قالوا في أنصبة الزوجين النصف ونصفه و + +191 +00:21:53,310 --> 00:22:02,090 +نصف نصفه النصف ونصفه الربع ونصف نصفه الثمن إذا + +192 +00:22:02,090 --> 00:22:08,170 +نعود باختصار فنقول وبالله التوفيق بأن الزوجة إذا + +193 +00:22:08,170 --> 00:22:16,320 +ماتت في حياة زوجها وكان لها ولد فإن نصيب الزوج يكون + +194 +00:22:16,320 --> 00:22:24,300 +الربع بسبب الفرع الوارث فإنهم لا يُحجبان حجباً كلياً + +195 +00:22:24,300 --> 00:22:28,820 +هذه قاعدة عامة في علم الميراث الزوجان لا يُحجبان + +196 +00:22:28,820 --> 00:22:35,290 +حجباً كلياً وإنما يُحجبان حجب نقصان فإذا ماتت عن غير + +197 +00:22:35,290 --> 00:22:43,870 +ولد لا منه ولا من غيره فإنه يكون له نصف تركة زوجة + +198 +00:22:43,870 --> 00:22:51,330 +أو زوجته وعلى نصف من الرجل تماماً أو من الزوج تماماً + +199 +00:22:51,330 --> 00:22:57,710 +إذا مات الزوج عن ولد فإن الزوجة يكون نصيبها الثمن + +200 +00:22:57,710 --> 00:23:02,620 +فإن لم يكن له ولد لا منها ولا من غيرها يكون لها + +201 +00:23:02,620 --> 00:23:09,180 +الربع فالربع هو نصف النصف والثمن هو نصف الربع والله + +202 +00:23:09,180 --> 00:23:17,360 +تبارك وتعالى يقول سبحانه وتعالى ولكم نصف ما ترك + +203 +00:23:17,360 --> 00:23:24,130 +أزواجكم إن لم يكن لهن ولد فإن كان لهن ولد فلكم + +204 +00:23:24,130 --> 00:23:29,070 +الربع مما تركنا من بعد وصية يوصين بها أو دين + +205 +00:23:29,070 --> 00:23:37,740 +ولهُن الربع مما تركتم عند عدم الإنجاب إن لم يكن لكم + +206 +00:23:37,740 --> 00:23:44,160 +ولد فإن كان لكم ولد يعني منها أو من غيرها فلهُن + +207 +00:23:44,160 --> 00:23:52,620 +الثمن مما تركتم من بعض وصية يوصين بها أو دين نعم + +208 +00:23:52,620 --> 00:24:01,080 +صدق الله العظيم إذا ننتبه إلى هذا وسيأتي في + +209 +00:24:01,080 --> 00:24:07,810 +الامتحان هذه الأرقام قد تكون صحيحة فتُوضع علامة صح و + +210 +00:24:07,810 --> 00:24:13,050 +قد تكون خطأ فيُكتب علامة خطأ وهكذا في الاختيار + +211 +00:24:13,050 --> 00:24:20,270 +المتعدد رابعاً + +212 +00:24:20,270 --> 00:24:23,510 +انتساب + +213 +00:24:23,510 --> 00:24:31,340 +الأولاد إليهما وحقهما في رعايتهم لأن التناسل والولد + +214 +00:24:31,340 --> 00:24:37,780 +من أغراض الزواج بل من حكم الزواج كما مر بنا في + +215 +00:24:37,780 --> 00:24:44,380 +حديث تزوجوا الولود الودود فإني مكاثر بكم أو مباهي + +216 +00:24:44,380 --> 00:24:50,460 +بكم الأمم يوم القيامة وذلك حفظاً للبقاء واستمرار + +217 +00:24:50,460 --> 00:25:01,700 +للنوع حتى يعمر هذا الكون بالتكاثر وعليه لا يصح أن + +218 +00:25:01,700 --> 00:25:10,520 +يُنسب إلى الزوج من ليس من صلبه كأن تأتي به زنى + +219 +00:25:10,520 --> 00:25:18,470 +بعيداً عن الزوج فهذا والعياذ بالله بن زنا أو لقيط + +220 +00:25:18,470 --> 00:25:23,310 +لا يُنسب إلى أبيه وكذلك يُحرم على الزوج أن يُنكر + +221 +00:25:23,310 --> 00:25:28,970 +ولداً من صلبه ونختم بهذا الحديث الذي جاء به الكتاب + +222 +00:25:28,970 --> 00:25:33,930 +يقول صلى الله عليه وسلم والحديث طبعاً لا يخلو من ضعف + +223 +00:25:33,930 --> 00:25:41,510 +أي امرأة أدخلت على قوم ما ليس منهم فلست من الله + +224 +00:25:41,510 --> 00:25:50,190 +في شيء سبحانه وتعالى رأيتم ولن يدخلها الله جنته + +225 +00:25:50,190 --> 00:25:58,330 +كأني أرى في الطبعة أخطاء مطبعية وأي ما رجل جحد ولده + +226 +00:25:58,330 --> 00:26:05,510 +وهو ينظر إليه احتجب الله منه وفضحه به على رؤوس + +227 +00:26:05,510 --> 00:26:12,350 +الخلائق بين الأولين وبين الآخرين إذا الآن نكون قد + +228 +00:26:12,350 --> 00:26:20,690 +انتهينا من المبحث الثالث وقد تكلمنا فيه عن الزواج + +229 +00:26:20,690 --> 00:26:28,550 +وعن تعريف الزواج لغة واصطلاحاً وعن أدلة مشروعية + +230 +00:26:28,550 --> 00:26:34,830 +الزواج من الكتاب والسنة وعن حكم الزواج وعن حكم + +231 +00:26:34,830 --> 00:26:43,470 +الزواج وعن الحقوق الزوجية بداية بحق الزوج وهي خمسة + +232 +00:26:43,470 --> 00:26:48,910 +وحق الزوجة وهي أربعة والحقوق المشتركة وهي أربعة + +233 +00:26:48,910 --> 00:26:54,390 +الآن إن شاء الله نختم بالمبحث الرابع وهو الطلاق + +234 +00:26:54,390 --> 00:27:01,530 +ونسأل الله السلامة والعافية ولعلنا قد تكلمنا عند + +235 +00:27:01,530 --> 00:27:09,880 +ذكر نكاح المتعة عندما تكلمنا عن وظيفة السنة النبوية + +236 +00:27:09,880 --> 00:27:17,740 +وقلت إنها وظائف ثلاثة أولاً أنها تأتي مؤكدة لكل ما + +237 +00:27:17,740 --> 00:27:26,930 +جاء في القرآن الكريم وثانياً أنها تأتي بيانا من جهة + +238 +00:27:26,930 --> 00:27:35,530 +تفصيل المجمل ومن جهة تخصيص العام ومن جهة تقييد + +239 +00:27:35,530 --> 00:27:42,170 +المطلق وقد ضربنا لكم الأمثال ثم قلت ثالثاً أن + +240 +00:27:42,170 --> 00:27:49,360 +السنة تأتي منشئة لأحكام قد سكت عنها القرآن الكريم + +241 +00:27:49,360 --> 00:27:58,140 +منها نكاح المتعة الذي أحله الشيعة استدلالاً بقوله + +242 +00:27:58,140 --> 00:28:02,440 +تعالى ظلمًا وعدوانًا فما استمتعتم به منهن فآتوهن + +243 +00:28:02,440 --> 00:28:09,980 +أجورهن والاستمتاع هنا هو الزواج الشرعي والعقد + +244 +00:28:09,980 --> 00:28:16,700 +المؤبد فإن قفص الزوجية + +245 +00:28:17,660 --> 00:28:25,360 +سجن مؤبد ولكنه ليس قفصًا من حديد ولكن قفصًا من ذهب + +246 +00:28:25,360 --> 00:28:29,440 +نعم أما نكاح المتعة أو النكاح المؤقت فهو محرم + +247 +00:28:29,440 --> 00:28:35,000 +عندنا نحن أهل السنة مثل كما سيئة معنا في أبواب + +248 +00:28:35,000 --> 00:28:35,580 +الطلاق + +249 +00:28:38,310 --> 00:28:44,130 +التحليل الذي يُحلّ المرأة ليلة أو ليلتين ثم يُطلقها + +250 +00:28:44,130 --> 00:28:48,810 +فهذا يُعتبر بابًا من أبواب الزنا والعياذ بالله و + +251 +00:28:48,810 --> 00:28:55,090 +نسأل الله السلامة والعافية فعقد الزواج عقد مؤبد + +252 +00:28:55,090 --> 00:29:03,270 +من أجل العفة ومن أجل الذرية وإعمار هذا الكون فلو + +253 +00:29:03,270 --> 00:29:10,990 +كانت الحكمة فقط هي المتعة أو الشهوة الجنسية لكانت + +254 +00:29:10,990 --> 00:29:16,430 +بيوت الدعارة مباحة لأن الهدف منها قضاء الوطر ثم + +255 +00:29:16,430 --> 00:29:22,550 +يُعطيها ما تيسر من المال وهذا هو ما حرّمه الإسلام + +256 +00:29:22,550 --> 00:29:32,550 +وَجَعَل عقد الزواج عقدًا مؤبدًا ولذلك عقد دائماً لا ينفك + +257 +00:29:32,550 --> 00:29:37,410 +أو ينتهي إلا بأحد الطريقين الطريق الأولى لا ينجو + +258 +00:29:37,410 --> 00:29:44,670 +منها أحد وهو الموت إما موت الزوجة أو موت الزوج أو + +259 +00:29:44,670 --> 00:29:51,470 +حتى موتهم معاً كما حصل في بعض الأحيان نعم إذا الأول + +260 +00:29:51,470 --> 00:29:57,130 +حتمي لا سبيل إلى تفاديه وهو وفاة أحد الزوجين وهذا + +261 +00:29:57,130 --> 00:30:02,330 +قدر الله كل من عليها فان ويبقى وجه ربك ذو الجلال + +262 +00:30:02,330 --> 00:30:09,430 +والإكرام كل نفس ذائقة الموت كل شيء هالك إلا وجهه + +263 +00:30:09,570 --> 00:30:14,930 +وصدق القائل من لم يمت بالسيف مات بغيره تنوعت + +264 +00:30:14,930 --> 00:30:21,090 +الأسباب والموت واحد أما الثاني وهو عنوان حديثنا + +265 +00:30:21,090 --> 00:30:32,950 +هو الطلاق فإن الطلاق ينهي العلاقة الزوجية وهو ليس + +266 +00:30:32,950 --> 00:30:42,390 +حراماً طبعاً ولكنه مكروه ولا يستحب ولكنه أحد حقائق + +267 +00:30:42,390 --> 00:30:49,910 +الحياة أباحه الإسلام ولكن كما جاء في بعض الآثار أيضاً + +268 +00:30:49,910 --> 00:30:55,590 +لا تخلو من ضعف أبغض الحلال إلى الله فالطلاق مباح + +269 +00:30:55,930 --> 00:31:01,450 +ولكنه أبغض الحلال إلى الله ولكنه أحياناً قد يكون + +270 +00:31:01,450 --> 00:31:07,930 +رحمة للزوجين عندما لا يطيق الزوج زوجته أو لا تطيق + +271 +00:31:07,930 --> 00:31:13,770 +الزوجة زوجها فلا يكون هنا إلا الطلاق ولذلك شرع له + +272 +00:31:13,770 --> 00:31:20,590 +الإسلام أحكامًا وفي صور القرآن الكريم صورة اسمها + +273 +00:31:20,590 --> 00:31:26,470 +صورة الطلاق يا أيها النبي إذا طلقتم النساء فطلقوهن + +274 +00:31:26,470 --> 00:31:32,870 +لعدتهن وأحصوا العدة وجاءت الأحكام والمطلقات + +275 +00:31:32,870 --> 00:31:40,670 +يَتَرَبّصْن بأنفسهن ثلاثة قروء وقوله الطلاق مرتان فإن + +276 +00:31:40,670 --> 00:31:45,590 +قيل أين الثالثة فإمساككم بمعروف أو تسريح بإحسان + +277 +00:31:48,540 --> 00:31:55,760 +ولكن سنأتي بعد ذلك إلى الطلاق وقد تكلمنا عن ذلك + +278 +00:31:55,760 --> 00:32:02,280 +أيضاً عند الحديث عن باب الأخلاق تكلمنا عن تقييد + +279 +00:32:02,280 --> 00:32:07,780 +استعمال الحق وقلت يومها بأن الطلاق من حق الرجل + +280 +00:32:07,780 --> 00:32:14,440 +ولكن إياك أيها الرجل أن تظلم الزوجة فإما أن تمسك + +281 +00:32:14,440 --> 00:32:20,530 +بمعروف، وإما أن تطلق بإحسان، والطلاق بإحسان أن تعطي + +282 +00:32:20,530 --> 00:32:26,750 +المرأة حقوقها كما في لغة العصر، هناك ما يسمى بعفش + +283 +00:32:26,750 --> 00:32:31,890 +البيت، وهو كما قلنا سلاحًا في يد الزوجة تطالب به + +284 +00:32:31,890 --> 00:32:37,590 +زوجها متى شاءت، حتى لو ألبسها الحرير وهزلها السرير + +285 +00:32:38,120 --> 00:32:45,060 +وأما المؤخر فهو عند أقرب الأجلين بلغة الفقه، إما + +286 +00:32:45,060 --> 00:32:54,480 +الطلاق وإما الموت، وقلت في حال الموت يحسم حق المرأة + +287 +00:32:54,480 --> 00:32:59,420 +3000 دينار أو 4000 دينار أو ما يتفقان عليه في عقد + +288 +00:32:59,420 --> 00:33:04,730 +الزواج قبل تقسيم التركة، فهو من الديون التي تكلمنا + +289 +00:33:04,730 --> 00:33:09,730 +عليه، وقد ذكرته قبل قليل أن التركة تمر بمراحل + +290 +00:33:09,730 --> 00:33:17,370 +أربعة: دفن، فدين، فوصية، فميراث، فقبل الميراث يخصم حق + +291 +00:33:17,370 --> 00:33:23,950 +زوجته، وهو عفش البيت الذي لم يدفع لها في حياته أو + +292 +00:33:23,950 --> 00:33:31,190 +المؤخر عند الوفاة قبل أن نحسب لها نصيبها الربع عند + +293 +00:33:31,190 --> 00:33:38,270 +عدم الإنجاب أو الثمن عند الولد، نعم، فإذا أردت أن + +294 +00:33:38,270 --> 00:33:46,710 +تطلق، فكن رجلًا وأعطي المرأة حقها، نعم، كما مرّ بنا + +295 +00:33:46,710 --> 00:33:53,650 +قول الله: "ولا تمسكوهن ضرارًا لتعتدوا"، أنت لا تحبها، و + +296 +00:33:53,650 --> 00:34:00,770 +أنت تبغضها ولا تريدها، ولكنك تضغط عليها حتى ترى + +297 +00:34:00,770 --> 00:34:04,490 +نجوم الظهر في رابعة النهار، وأنت في هذه الحالة + +298 +00:34:04,490 --> 00:34:12,150 +ظالم، من أجل أن تبرئك بين يدي القضاء، ومن أجل أن + +299 +00:34:12,150 --> 00:34:20,940 +تتنازل عن حقها من المؤخر ومن عفش البيت، وربما كانت + +300 +00:34:20,940 --> 00:34:28,400 +عليك ديون، كأن تعطي الزوجة مثلًا حليها لزوجها حتى + +301 +00:34:28,400 --> 00:34:38,000 +يبيعه فيكون دينًا في ذمته، نعم، وهنا يضغط عليها، وقد + +302 +00:34:38,000 --> 00:34:44,820 +لا يعاشرها معاشرة الأزواج، أو يهجرها من أجل أن يتزوج + +303 +00:34:44,820 --> 00:34:50,660 +بغيرها حتى تتنازل عن حقوقها، وهذا هو الظلم بعينه + +304 +00:34:50,660 --> 00:34:55,920 +فلا تمسكوا، ولا تمسكوهن ضرارًا أي إضرارًا، فاتقوا + +305 +00:34:55,920 --> 00:35:03,880 +الله في الزوجة وفي حق الزوجة، لأن مهرها حق لها وقد + +306 +00:35:03,880 --> 00:35:09,340 +تكلمنا من حقوق الزوجة الأربعة: المهر، وآتوا النساء + +307 +00:35:11,170 --> 00:35:17,650 +صدقاتهن نحلة، فإن طبن لكم عن شيء منه نفسًا فكلوه + +308 +00:35:17,650 --> 00:35:22,550 +هنيئًا مليئًا، حتى ولو كان قنطارًا، وإن أردتم استبدال + +309 +00:35:22,550 --> 00:35:28,170 +زوج مكان زوج، وآتيتم إحداهن قنطارًا فلا تأخذوا منه + +310 +00:35:28,170 --> 00:35:34,950 +شيئًا، أتأخذونه بهتانًا وإثمًا مبينًا، نعم، ومع ذلك، و + +311 +00:35:34,950 --> 00:35:42,590 +مع أن الإسلام قد أباح الطلاق، نعم، هنا نتخطى الطلاق + +312 +00:35:42,590 --> 00:35:46,270 +عند اليهودية وعند النصرانية، فهذا ليس مطلوبًا في + +313 +00:35:46,270 --> 00:35:53,910 +الامتحان، دعونا نتكلم عن الأهم، هنا نقول مع أن + +314 +00:35:53,910 --> 00:36:01,650 +الإسلام قد شرع الطلاق، ولكنه حد من وقوع الطلاق، وهذا + +315 +00:36:01,650 --> 00:36:07,990 +عنوان مهم: ما هي الخطوات الوقائية للحد من وقوع + +316 +00:36:07,990 --> 00:36:14,860 +الطلاق، وكيف عالج الإسلام الخلافة العائلية، نبدأ من + +317 +00:36:14,860 --> 00:36:21,640 +البداية عند الخطبة، والخطبة كما قلنا بكثرة الخاء + +318 +00:36:21,640 --> 00:36:29,980 +خلافًا للخطبة، وهي الموعظة من البداية، إذا أراد الشخص + +319 +00:36:29,980 --> 00:36:37,440 +أن يخطب امرأة فعليه أن لا يسأل قبل كل شيء عن + +320 +00:36:37,440 --> 00:36:42,500 +الجمال وعن المال وعن الحسب والنسب، وإن كان ذلك لا + +321 +00:36:42,500 --> 00:36:50,510 +يتعارض مع الإسلام، ولكن يسأل عن الدين وعن الخلق، لأن + +322 +00:36:50,510 --> 00:36:55,770 +شعار هذه الأمة الخالد سيبقى إلى أن يرث الله الأرض + +323 +00:36:55,770 --> 00:37:02,710 +ومن عليها كما تلاّنا في سورة الحجرات: "إن أكرمكم عند + +324 +00:37:02,710 --> 00:37:08,990 +الله أتقاكم"، حتى ولو كان أو كانت أقل مالًا أو جمالًا + +325 +00:37:08,990 --> 00:37:19,880 +أو أضعف قبيلة أو عشيرة، فإن الدين يجبر ذلك، كلهم، وقد + +326 +00:37:19,880 --> 00:37:25,260 +جاء في الحديث: "تنكح المرأة لأربعين"، أي أن الرجال قد + +327 +00:37:25,260 --> 00:37:33,320 +يرغبون في النساء لأربع أو لواحدة من أربع أو لسنتين + +328 +00:37:33,320 --> 00:37:43,990 +وقال: "لما تجتمع هذه الأربع؟"، لما لها من جمالها أو + +329 +00:37:43,990 --> 00:37:48,710 +حسبها ونسبها أو دينها، ثم أوصى الرسول عليه الصلاة + +330 +00:37:48,710 --> 00:37:55,450 +والسلام الجيل قائلًا: "فاذفر بذات الدين تربت يداك"، نعم + +331 +00:37:55,450 --> 00:38:00,470 +والنبي عليه الصلاة والسلام يقول: "الدنيا متاع وخير + +332 +00:38:00,470 --> 00:38:05,770 +متاعها المرأة الصالحة"، وكأنه قيل: "ما صفتها يا رسول + +333 +00:38:05,770 --> 00:38:13,110 +الله؟" قال: "النظر إليها صرّته"، وإن أمرها أطاعته، وإن أقسم + +334 +00:38:13,110 --> 00:38:20,570 +عليها أبرته، وإن غاب عنها حفظته في ماله وفي عرضها + +335 +00:38:20,570 --> 00:38:24,690 +وهذا ما تكلمنا عنه من حقوق الزوج بعد الطاعة + +336 +00:38:24,690 --> 00:38:30,870 +الأمانة: أن تكون مؤتمنًا على ولده وعلى ماله وعلى عرضها + +337 +00:38:30,870 --> 00:38:37,370 +فعرضها سر بينها وبين زوجها لا يفشى لأحد ولا يطلع + +338 +00:38:37,370 --> 00:38:41,330 +عليه أحد كما تلاّنا إلا على أزواجهم أو ما ملكت + +339 +00:38:41,330 --> 00:38:47,930 +أيمانهم، فإنهم غير ملومين، وكذلك نقول الزوجة قبل أن + +340 +00:38:47,930 --> 00:38:54,170 +تنظر إلى وسامة الخاطب أو ما يملك من سيارات أو + +341 +00:38:54,170 --> 00:39:03,250 +عقارات، ينظر إلى الدين وإلى الخلق، فقد جاء في الحديث + +342 +00:39:03,250 --> 00:39:08,310 +خطابًا لأولياء الأمور: "إذا جاءكم" أو قال في رواية: "إذا + +343 +00:39:08,310 --> 00:39:14,610 +أتاكم من ترضون دينه وخلقه فزوجوه"، وانظروا دينه + +344 +00:39:14,610 --> 00:39:20,210 +وخلقه، هكذا يتفاضل الناس، وهذا هو ميزان الإسلام في + +345 +00:39:20,210 --> 00:39:26,190 +الرجال: "إذا جاءكم" أو "إذا أتاكم يا أولياء الأمور من + +346 +00:39:26,190 --> 00:39:30,930 +ترضون دينه وخلقه فزوجوه إلا تفعلوا تكون فتنة في + +347 +00:39:30,930 --> 00:39:38,730 +الأرض وفساد كبير"، وفي رواية " وفساد عريض"، نقف هنا، و + +348 +00:39:38,730 --> 00:39:43,090 +نأتي في المحاضرة التالية إن شاء الله إلى الإكمال + +349 +00:39:43,090 --> 00:39:48,130 +وما زلنا مع الخطوات الوقائية للحد من وقوع الطلاق + +350 +00:39:48,130 --> 00:39:54,590 +من المبحث الرابع من الفصل الرابع، نظام الأسرة في + +351 +00:39:54,590 --> 00:39:59,010 +الإسلام، والسلام عليكم ورحمة الله وبركاته + + + diff --git a/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/944ntkglc5w_postprocess.srt b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/944ntkglc5w_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..46280f03da4c2a7cc53d7fc9322cb3f153ca1366 --- /dev/null +++ b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/944ntkglc5w_postprocess.srt @@ -0,0 +1,1872 @@ +1 +00:00:20,920 --> 00:00:24,480 +الحمد لله يا رب العالمين الصلاة والسلام على أشرف + +2 +00:00:24,480 --> 00:00:29,340 +الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحبه + +3 +00:00:29,340 --> 00:00:33,740 +أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت + +4 +00:00:33,740 --> 00:00:38,840 +العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما + +5 +00:00:38,840 --> 00:00:43,160 +علمتنا وازيدنا علمة آمين يا رب العالمين أما بعد + +6 +00:00:43,160 --> 00:00:47,940 +كنا بدأنا الحديث يا أخوات في المحاضرة الماضية حول + +7 +00:00:47,940 --> 00:00:55,000 +قضايا المرأةالتي أثارها دعاء تحرير المرأة حول حقوق + +8 +00:00:55,000 --> 00:01:00,320 +المرأة في الإسلام وادعوا وزعموا أن الإسلام قد ظلم + +9 +00:01:00,320 --> 00:01:06,780 +المرأة بها أو فيها وانتقص من حقوقها وقضايا ثمانية + +10 +00:01:06,780 --> 00:01:13,700 +كما قلنا نقشنا منها أربع قضايا على الترتيب القضية + +11 +00:01:13,700 --> 00:01:19,240 +الأولى منذ ذكرنا ماذا كانتقضية الميراث، قضية + +12 +00:01:19,240 --> 00:01:27,000 +الثانية الديا، ثالثة القوامة، الرابعة الطلاق، + +13 +00:01:27,000 --> 00:01:30,280 +قضايا الأربعة واليوم ان شاء الله نكمل وحسب ما + +14 +00:01:30,280 --> 00:01:35,000 +يتيسر لنا من الوقت والموضوع ربما يستغرق وقتا طويلا + +15 +00:01:35,000 --> 00:01:40,180 +نتحدث عن قضيتينإذا أسعفنا الوقت القضية الأولى وهي + +16 +00:01:40,180 --> 00:01:44,540 +الخامسة من القضايا المطروحة حول المرأة قضية تعدد + +17 +00:01:44,540 --> 00:01:48,980 +الزوجات والقضية الثانية وهي السادسة من قضايا + +18 +00:01:48,980 --> 00:01:55,300 +المرأة عمل المرأة خارج البيت هتان القضيتان أثرهما + +19 +00:01:55,300 --> 00:02:00,200 +دعاء تحرير المرأة من المستشرقين وغيرهم فادعوا أن + +20 +00:02:00,200 --> 00:02:04,400 +الإسلام قد ظلم المرأة في همام ظلمها حينما أباح + +21 +00:02:04,400 --> 00:02:11,430 +للرجل بأن يعددعلى زوجاته أن يكون له زوجة أخ ثانية + +22 +00:02:11,430 --> 00:02:16,330 +أو ثالثة أو رابع هذا ظلم للمرأة وتأبغى كل مرأة + +23 +00:02:16,330 --> 00:02:22,770 +وترفضه ولا ترضاه هذا ظلم له كذلك العمل خارج البيت + +24 +00:02:22,770 --> 00:02:28,160 +الإسلام هكذا يدعونحرم المرأة ومنع المرأة من الخروج + +25 +00:02:28,160 --> 00:02:33,500 +خارج البيت للعمل وأرادها محبوسة سجينة داخل البيت + +26 +00:02:33,500 --> 00:02:38,460 +طبعا كل ذلك زعم وادعاء باطل سنقوم بالرد عليه + +27 +00:02:38,460 --> 00:02:45,610 +فالقضية الأولى المطروحة الأمامنا هيتعدد الزوجات + +28 +00:02:45,610 --> 00:02:50,550 +وزعم وادعاء أعداء الإسلام بأن المرأة .. بأن + +29 +00:02:50,550 --> 00:02:56,750 +الإسلام قد ظلم المرأة في هذه القضية فكيف نرد على + +30 +00:02:56,750 --> 00:03:00,890 +هؤلاء؟ كيف نرد على من اتهم الإسلام أنه ظلم المرأة + +31 +00:03:00,890 --> 00:03:06,230 +في هذا الحكم الشرعي؟ اللي خاطب قبل أن نبدأ بس مجرد + +32 +00:03:06,230 --> 00:03:13,490 +استفتاء بدنا نشوف مين معالتعدد أو مين ضد التعدد + +33 +00:03:13,490 --> 00:03:18,830 +ليس كحكم شرعي فهذا أمر مفروغ منه، لا يجوز لصفته + +34 +00:03:18,830 --> 00:03:23,770 +عليه أو إعطاء رأي فيه، هذا حكم الله تعالى ومتفق + +35 +00:03:23,770 --> 00:03:29,130 +عليه عندنا كمسلمين، من تقبل أو ترضى أو تسوق أو + +36 +00:03:29,130 --> 00:03:33,270 +تقول هذا أمر يعني تفرضه ضرورة أو كذا أو يسمح للرجل + +37 +00:03:33,270 --> 00:03:38,720 +أو ليس فيه حرج أو مانع أو ..ربما الحديث مين مع + +38 +00:03:38,720 --> 00:03:46,860 +يعني يكون محرج شوية مين ضد .. مين ليس مع .. اه طيب + +39 +00:03:46,860 --> 00:03:51,740 +نشوف ال .. ال .. ال .. العدد و النسبة قبل الحديث + +40 +00:03:51,740 --> 00:03:56,340 +عن الموضوع و نرجع مرة أخرى للاستفتاء بعد الحديث عن + +41 +00:03:56,340 --> 00:03:59,940 +التعدد هنرجع ناخد نسبة تان .. بدنا نعدد كام واحدة + +42 +00:03:59,940 --> 00:04:04,490 +.. ترفع عصابيهم كمان مرة .. اي واحدةاللي ضد .. 1 + +43 +00:04:04,490 --> 00:04:09,210 +.. 2 .. 3 .. 4 .. 5 .. 6 .. يا أخوات قبل ما نكمل، + +44 +00:04:09,210 --> 00:04:14,270 +ليس شرط يعني أن أنت ترضيه لنفسك، بصورة عامة، تضد + +45 +00:04:14,270 --> 00:04:18,590 +ولا مع؟ الآن بنرضح كمان أكتر، ليس شرط إليك، ولا + +46 +00:04:18,590 --> 00:04:21,750 +واحدة بترضي عليه، هذا مفتفق برضه عليا، أه، بس هل + +47 +00:04:21,750 --> 00:04:26,980 +ترضين في الواقع أن يكون هناك تعدد وكذا وكذا؟ولا + +48 +00:04:26,980 --> 00:04:31,860 +انت ضد ان يكون التعدد بسرعة عامة بالنسبة الان بدأت + +49 +00:04:31,860 --> 00:04:35,700 +تخفق اقل ليس السؤال شخصيا يعني اي واحد اتنين تلاتة + +50 +00:04:35,700 --> 00:04:40,260 +اربع شايفه استاذ السماء بدل عدد اجل ستة سبعة طيب + +51 +00:04:40,260 --> 00:04:43,680 +كويس ان شاء الله بعد كده مش هلاجي ولا واحدة انت + +52 +00:04:43,680 --> 00:04:46,780 +معه ولا ضده هو هذا اللي ضد ولا معه هذا اللي ضد + +53 +00:04:46,780 --> 00:04:54,030 +فالاقلية ضد والاغلبية معها كده يفهمأحنا لسنا نعلق + +54 +00:04:54,030 --> 00:04:57,730 +.. لأن بحث .. لأننا لن نقمر أن نناقب عامة في + +55 +00:04:57,730 --> 00:05:02,130 +القلوب والبطون طيب يا أخوات القضية بس دعابة ومقدمة + +56 +00:05:02,130 --> 00:05:06,610 +لكي نعرف حكمة الله تعالى من وراء هذا الحكم الشركي + +57 +00:05:06,610 --> 00:05:11,870 +فإن الله تعالى له في كل ..أمر من أوامره ونهي من + +58 +00:05:11,870 --> 00:05:17,170 +نواهيه وحكم من أحكام له حكمة وحكمة عظيمة قد نعلمها + +59 +00:05:17,170 --> 00:05:21,630 +وقد لا نعلمها فإذا ما علمنا الحكمة يعني استيقظنا + +60 +00:05:21,630 --> 00:05:26,390 +أكثر بهذا الحكم الشرعي من الله تعالى واطمئننا + +61 +00:05:26,390 --> 00:05:30,710 +القلوبنا أكثرفكيف نرد نرجع إلى السؤال وبعد الرد + +62 +00:05:30,710 --> 00:05:33,670 +والانتهاء منه نرجع إلى الاستفتاء مرة أخرى لنرى كم + +63 +00:05:33,670 --> 00:05:51,290 +هي حكمة الله عظيمة في هذا التعدد واحد فضلوا برك + +64 +00:05:51,290 --> 00:05:55,560 +الله فيك ما مغزى هذه النقطة في الردإن الإسلام ما + +65 +00:05:55,560 --> 00:06:00,740 +له؟ لم يكن هو من جاء بهذه أو بهذا الحكم أو بهذه + +66 +00:06:00,740 --> 00:06:04,840 +القضية ليس هو أول من ابتدعها أو قالها أو جاء بيه + +67 +00:06:04,840 --> 00:06:09,080 +بل كانت الأمم قبل الإسلام عندها التعدد أمرا عادي + +68 +00:06:09,080 --> 00:06:13,950 +كانعند اليابانين والصينيين والهنود والبابليين وكل + +69 +00:06:13,950 --> 00:06:18,070 +الحضارات القديمة والاشوريين والمصريين يعني فجاء + +70 +00:06:18,070 --> 00:06:24,270 +الإسلام ووجد أن ناسا تعدد فيعني أبقى على هذا الحكم + +71 +00:06:24,270 --> 00:06:30,250 +الذي اعتد عليه أو اعتدت عليه الأمم لكن طبعا بتنظيم + +72 +00:06:30,250 --> 00:06:36,080 +وتهذيب له كما سيأتي بعد قليل نقطة ثانية اتفضلأن + +73 +00:06:36,080 --> 00:06:39,440 +ديانة اليهودية كانت تبيح التعدد و بدون حد و أنبياء + +74 +00:06:39,440 --> 00:06:42,700 +بني إسرائيل كلهم كانت هم زوجات كثيرة و ليس في + +75 +00:06:42,700 --> 00:06:46,440 +أنجيب ديانة نصرانية ما يمنع التعدد و إنما يبقى + +76 +00:06:46,440 --> 00:06:49,740 +هناك ما يفيد جوازه بارك الله فيك و أحسن إذا في + +77 +00:06:49,740 --> 00:06:54,340 +اليهودية و في النصرانية و هم ديانتان عند أهلهم و + +78 +00:06:54,340 --> 00:06:58,020 +أصحابهم ديانات لكنها طبعا ليست ديانة حقيقية لأن + +79 +00:06:58,020 --> 00:07:03,720 +الدين عند الله الإسلام ففي مفهومأصحابهما دين، لكم + +80 +00:07:03,720 --> 00:07:06,680 +دينكم والذين هذا دين، الذين يدينون به + +81 +00:07:32,050 --> 00:07:37,790 +واضطرت النصراني في بعض البلدان الى الاعتراف + +82 +00:07:37,790 --> 00:07:44,090 +بالتعدد رغم عدم تشريعه كقانون لما وجدوا ان في + +83 +00:07:44,090 --> 00:07:49,320 +الأفريقيا السوداء الناس معتادة على التعددفلكي + +84 +00:07:49,320 --> 00:07:53,160 +يستقطبوهم و يستميلوهم أباحوا لهم التعدد إذا كان + +85 +00:07:53,160 --> 00:07:56,780 +هذا عقبة ضد التنصير فاجدوا إن الناس بدأت تقبل على + +86 +00:07:56,780 --> 00:07:59,900 +النصرانية بس لكن معتقدة على التعدد و بدأت تعدد + +87 +00:07:59,900 --> 00:08:02,800 +فإذا بدك تمنعنا من التعدد ما بديش أدخل فيها الدين + +88 +00:08:02,800 --> 00:08:08,200 +النصراني في بعض المناطق فأباحوا لهم ذلك رضوخا + +89 +00:08:08,200 --> 00:08:16,250 +للواقعفي نقطة ثالثة ترد على هؤلاء الذين يدعون أن + +90 +00:08:16,250 --> 00:08:20,730 +الإسلام ظلم المرأة في التعدد آه يا أخوات اللي هنا + +91 +00:08:20,730 --> 00:08:24,350 +حاولوا إحنا ننوح في الجهات مين من هنا من الأخوات + +92 +00:08:24,350 --> 00:08:28,930 +بتحب ترد في النقطة الثالثة نرجع تفضل اللي في الأخر + +93 +00:08:28,930 --> 00:08:34,450 +سنة 1948 أدرس مضمن للشباب عقد عقدة الميلخ في + +94 +00:08:34,450 --> 00:08:38,150 +ألمانيا فوضوح زيادة النساء في القرب بسبب الحرب + +95 +00:08:38,150 --> 00:08:40,070 +العلمانية العالمية + +96 +00:08:42,290 --> 00:08:46,210 +كان من نتائج هذا المؤتمر إقرار توصية من المؤتمر + +97 +00:08:46,210 --> 00:08:50,270 +بإباحة تعادل الزوجات بناء على اقتراح من بعض دراسي + +98 +00:08:50,270 --> 00:08:54,530 +الأفاني السوريين بارك الله فيكبعد الحرب العالمية + +99 +00:08:54,530 --> 00:08:56,990 +الأولى يا أخوات و الحرب العالمية الثانية و بعد كل + +100 +00:08:56,990 --> 00:09:03,330 +حرب طاحنة هناك شهداء في العالم الإسلامي و قتلة و + +101 +00:09:03,330 --> 00:09:07,570 +موتة في العالم الآخر يعني احنا بيسمي قتلانا + +102 +00:09:07,570 --> 00:09:12,430 +شهداءهم قتلة و أموات و ضحايا كثر أحيانا بالألاف و + +103 +00:09:12,430 --> 00:09:15,050 +أحيانا بالملايين كما حدثت في الحرب العالمية الأولى + +104 +00:09:15,050 --> 00:09:20,750 +و الثانية فأصبح هناك مشكلةمشكلة اجتماعية ان عدد + +105 +00:09:20,750 --> 00:09:25,190 +النساء اصبح في تلك المجتمعات والبلدان اكثر من عدد + +106 +00:09:25,190 --> 00:09:30,710 +الرجال يعني ما بيصحش لكل امرأة رجل يعني مش هيصحين + +107 +00:09:30,710 --> 00:09:37,190 +لأن رجال عدموا وقتلوا وكذا وكذا فقاموا في مؤتمر + +108 +00:09:37,190 --> 00:09:41,270 +عقد بالمانيا وكان في احد توصياتي من بعض ابناء + +109 +00:09:41,270 --> 00:09:44,470 +المسلمين ان تكون او يكون الحل لهذه المشكلة + +110 +00:09:44,470 --> 00:09:50,620 +والمعضلة ان يسمحوا بالتعددحتى يقضوا على ظاهرة عدد + +111 +00:09:50,620 --> 00:09:54,920 +النساء الأكبر من عدد الرجال وأذكر بعد الحرب + +112 +00:09:54,920 --> 00:10:00,200 +العراقية الأولى مع إيران كان هناك في العراق حوالي + +113 +00:10:00,200 --> 00:10:04,940 +مليون شهيد عراقيا أستاذ أسامة الكلام للجميع وكان + +114 +00:10:04,940 --> 00:10:10,600 +الرئيس الراحل صدام حسين وحزبه ونظامه يمنعون التعدد + +115 +00:10:10,600 --> 00:10:15,980 +كنظام تبناه حزب البعثةفبعد هذه المشكلة مليون إراقي + +116 +00:10:15,980 --> 00:10:20,200 +شهيد رجل طبعا فيه مشكلة أرامل صاروا زوجات شهداء + +117 +00:10:20,200 --> 00:10:24,900 +وكذا كيف سنعالج ذلك فالغ هذا القانون و هذا القرار + +118 +00:10:24,900 --> 00:10:29,780 +وشجع على التعدد وسمح بالتعدد بل أعطى إغراءات على + +119 +00:10:29,780 --> 00:10:36,240 +ذلك قال كل من يتزوج زوجة شهيد له عشرة آلاف دينار و + +120 +00:10:36,240 --> 00:10:42,820 +سيارة و شقهذه الإغراءة رجع إلى حكمة الله سبحانه + +121 +00:10:42,820 --> 00:10:47,300 +وتعالى وحكم الله تعالى في أن في حالات يضطر الناس + +122 +00:10:47,300 --> 00:10:52,940 +إلى هذا الأمر من سيحل هذه المشكلة الإجتماعية التي + +123 +00:10:52,940 --> 00:10:57,250 +تعقب الحرب وانت هنا في قطاع غزة مشكلةالأرامل + +124 +00:10:57,250 --> 00:11:01,570 +وزوجات الشهداء يعني هذه مشكلة ومعضلة لابد من علاجة + +125 +00:11:01,570 --> 00:11:06,050 +فهل سيقبل على الدوام أو دائما شاب مقبل على الزواج + +126 +00:11:06,050 --> 00:11:10,290 +أن يتزوج إمرأة أو معها أولاده طبعا من سيقبلها؟ رجل + +127 +00:11:10,290 --> 00:11:16,430 +متزوج فيضيف فيها زوجة يعني ثانية يجيلك تعقيب يا + +128 +00:11:16,430 --> 00:11:25,160 +أستاذ وسامة على ذلك اه تفتربسمع يعني يا أخاني + +129 +00:11:25,160 --> 00:11:37,100 +الأستاذ أسامة في مداخلة قلب + +130 +00:11:37,100 --> 00:11:43,320 +من قلب المرأة اسمعوا يا أخوات يا لا ملكون تبينوا + +131 +00:11:43,320 --> 00:11:48,240 +الانتلاق انتلاك الشيء وعدم المشاركة فيه ويعتبر + +132 +00:11:48,240 --> 00:11:54,350 +الزوج هو جنة الزوجةوهو كل شيء في حياة الزوجة لأن + +133 +00:11:54,350 --> 00:11:59,370 +الزوجات هذا شعارها أن اللي أحلى من أجل زوجها + +134 +00:11:59,370 --> 00:12:04,190 +ولتالي عندما يأتي مناقة مشاركة لها فهذا لن تقبله + +135 +00:12:04,190 --> 00:12:08,930 +قطر ستكون منافسة لها في ذلك و سيرفضه القطر لأ + +136 +00:12:08,930 --> 00:12:12,430 +واقعه فطر هو موجود يعني لأن هذا شيء لا يكادر فيه + +137 +00:12:12,430 --> 00:12:17,930 +أحد من النساء لكن المسألة لابد من أن تكون مطرقة من + +138 +00:12:17,930 --> 00:12:18,910 +باب الدين + +139 +00:12:37,190 --> 00:12:45,230 +وأقول فتتصور أخت نفسها بعد ما استشهد زوجها لا تجد + +140 +00:12:45,230 --> 00:12:51,940 +من يتزوجهاوتبقى في حياتها لوحدها، فإن وصلت إلى + +141 +00:12:51,940 --> 00:12:59,000 +الخمسين أو الستين، لا تجد لها أحد المعينة فتصوري + +142 +00:12:59,000 --> 00:13:05,560 +نفسك في هذا المقام، هل ترضينا لنفسك؟ وأمامنا كثير + +143 +00:13:05,560 --> 00:13:11,030 +من الحالات التي كمرك فيها الأخراج دون زواجوصار + +144 +00:13:11,030 --> 00:13:17,570 +يتأفف منها كل أقربائها ولا يصبرون على حملها أو + +145 +00:13:17,570 --> 00:13:22,870 +تحمل أعدائها أو ما تحتاجوا من مساعدة في كبر سنها + +146 +00:13:22,870 --> 00:13:27,930 +إضافة إلى حالتها النفسية الشخصية التي تمر بها فهل + +147 +00:13:27,930 --> 00:13:33,990 +واحدة من النساء ترضى لنفسها أن تكون على ذلك فإن لم + +148 +00:13:33,990 --> 00:13:39,950 +ترضى يقول النبي صلى الله عليه وسلمأحبكم حتى وحبني + +149 +00:13:39,950 --> 00:13:46,050 +أخي و أحب نفسك و لابد أخدق و لابد من أن نحرك القلب + +150 +00:13:46,050 --> 00:13:52,210 +حب الله تعالى لأن الهوى يميلوا بعكس ما يريده الله + +151 +00:13:52,210 --> 00:13:56,790 +تعالى في هذا الجانب الخاص و لذلك قال النبي صلى + +152 +00:13:56,790 --> 00:13:59,930 +الله عليه و سلم ثلاثة من من كنا في الليل وجد حلاوة + +153 +00:13:59,930 --> 00:14:05,410 +الإيمان أي أن نجد بالإيمان حلاوة أن يكون الله و + +154 +00:14:05,410 --> 00:14:10,800 +رسوله حق إليه مماسواهما فحب الله لا يكون الا + +155 +00:14:10,800 --> 00:14:16,180 +بطاعته و الالتزام بطاعته و من طاعة الله تعالى أن + +156 +00:14:16,180 --> 00:14:22,570 +أحب لغيري كما أحب الناسنشكر الأستاذ أسامة أبو حمزة + +157 +00:14:22,570 --> 00:14:26,750 +على هذه المداخلة الطيبة المباركة وليه خاطر هنا قبل + +158 +00:14:26,750 --> 00:14:30,390 +أن ننهي هذا الموضوع لأن أنا في نصفه الآن أن نجري + +159 +00:14:30,390 --> 00:14:34,330 +استفتاء مرة أخرى بعد هذا الكلام الذي استمعنا إليه + +160 +00:14:34,330 --> 00:14:39,870 +و هذه الحيثيات و هذه المداخلة الطيبة من ضد من ضقي + +161 +00:14:39,870 --> 00:14:43,970 +ضد كانوا سبعة يا أستاذ أسامة لأن في واحدة اتنتين + +162 +00:14:45,520 --> 00:14:49,700 +تلاتة اخص واربع طيب نشوف بعدها في نهاية الكلام + +163 +00:14:49,700 --> 00:14:53,100 +ماداش بتصير النسبة و العدل و لكم الحق في ذلك هذه + +164 +00:14:53,100 --> 00:14:57,840 +قناعات يعني واقعية و مرة أخرى نؤكد على أن الكلام + +165 +00:14:57,840 --> 00:15:01,980 +على قناعات الأخت و يعني رضاها و قبولها و ليس هو + +166 +00:15:01,980 --> 00:15:05,820 +على الحكم الشرعي كحكم من الله و نحن نعلم حتى + +167 +00:15:05,820 --> 00:15:10,040 +الأخوات المعارضة لا تعرض الحكمكحكم لكن لا تقبله + +168 +00:15:10,040 --> 00:15:15,680 +ولا ترضاه تعتقد أن الأفضل والدائم هو الواحدة ولا + +169 +00:15:15,680 --> 00:15:21,360 +شيء سواه طيب أيضا من الرد على أعداء الإسلام بوصفهم + +170 +00:15:21,360 --> 00:15:25,580 +الإسلام كان ظلم المرأة في هذه القضية اتفضل يا أختك + +171 +00:15:25,580 --> 00:15:28,120 +النقطة الرابعة اللي قصد في زواج في الإسلام + +172 +00:15:28,120 --> 00:15:31,400 +الاكتفاء بالزوجة واحدة هو أباحث تعادل في حال انه + +173 +00:15:31,400 --> 00:15:36,230 +يستطيع العدل العدل غير مضمون وهذا العدل مانهغير + +174 +00:15:36,230 --> 00:15:39,530 +مضمون التحقيق .. اه يا اخوان .. برك الله فيك .. ده + +175 +00:15:39,530 --> 00:15:41,990 +نقطة رابعة كمان .. نقطة مهمة يا اخوان .. وهذا اللي + +176 +00:15:41,990 --> 00:15:46,410 +احنا بدنا نعيه جيدا .. الإسلام في دعوته إلى التعدد + +177 +00:15:46,410 --> 00:15:50,590 +أو في إباحته .. عفواً .. ليه؟ التعدد لم يأمر به + +178 +00:15:50,590 --> 00:15:55,650 +أمرا .. ما جعله أمرولا ندب إليه كسنة ومؤكدة + +179 +00:15:55,650 --> 00:16:00,670 +وأفضلية ودعا إليه كالمندوبات الأخرى والسنة المؤكدة + +180 +00:16:00,670 --> 00:16:06,150 +وكذا بل جعله مباحا جائزا إذا أراد الإنسان أن + +181 +00:16:06,150 --> 00:16:11,330 +يستخدم هذا الحكم هذا الحق هذا المباح لضرورات لظروف + +182 +00:16:11,860 --> 00:16:16,000 +مهما تكون هذه الظروف لكن اراد لنفسه ذلك فله ذلك + +183 +00:16:16,000 --> 00:16:21,540 +فهو في اطار حكم الايه الواجب ولا المندوب اليه ولا + +184 +00:16:21,540 --> 00:16:25,760 +المباح لو اجى سؤال في الاختيار ايش بيكون مباح وليس + +185 +00:16:25,760 --> 00:16:30,920 +هو واجبا او فرض وهذا المباح وهذا الحق وهذا الحكم + +186 +00:16:30,920 --> 00:16:38,310 +مشروط بشرط ماهو هذا الشرط العادلفانكحوا ما طاب لكم + +187 +00:16:38,310 --> 00:16:41,970 +من النساء مثلا و ثلاثة و رباع، يجوز لك أن تتزوج + +188 +00:16:41,970 --> 00:16:46,030 +أيها المسلم واحدة، اتنين، تلاتة، اربع فقط ولا يجوز + +189 +00:16:46,030 --> 00:16:50,570 +الزيادة على ذلك، فانخفتم ألا تعدلوا بين هذه + +190 +00:16:50,570 --> 00:16:57,000 +الزوجاتفواحدة وبالتالي الإنسان كما يقول حكيم نفس + +191 +00:16:57,000 --> 00:17:02,320 +وبال الإنسان على نفسه بصيرة فانت تعلموا من نفسك + +192 +00:17:02,320 --> 00:17:07,940 +أيها المقبل على التعدد هل ستعدل بين زوجيك أو + +193 +00:17:07,940 --> 00:17:11,540 +زوجاتك إذا كانوا أكثر من تنتين فإذا كان عندك + +194 +00:17:11,540 --> 00:17:15,560 +الإمكانية و القدرة على العادل فيجوز لكلا تستطيع + +195 +00:17:15,560 --> 00:17:20,040 +الإنفاق على واحدة فلا يحق لك أن تتزوج ثانية مقصر + +196 +00:17:20,040 --> 00:17:25,480 +في حق واحدة و أبناءك لا يجوز لك أن تأتي بثانية و + +197 +00:17:25,480 --> 00:17:29,860 +أنت تعلم من نفسك أنك لا تستطيع العدل فالعدل مطلوب + +198 +00:17:29,860 --> 00:17:34,420 +في الإنفاق نفقائك و متيسر حاله فينفق على الثانية + +199 +00:17:34,420 --> 00:17:38,930 +مثل ما ينفق على الأولى و هكذاوفي المبيت عند هذه و + +200 +00:17:38,930 --> 00:17:43,030 +تلك ويعطي هذه مثل ما يُعرف إذا كان مقتدرا وميصور + +201 +00:17:43,030 --> 00:17:46,830 +الحال ويستطيع أن يفتح بيتين في ظروف صعبة كظروفنا + +202 +00:17:46,830 --> 00:17:50,830 +اليوم وعنده المقدرة و القدرة على ذلك فهذا جائز في + +203 +00:17:50,830 --> 00:17:57,070 +حقه ولا شيء على إن لم يكن فإن لم تعدلوا فواحد فإن + +204 +00:17:57,070 --> 00:18:01,750 +خفتم عفوا فإن خفتم ألا تعدلوا فواحدوالمسألة طبعا + +205 +00:18:01,750 --> 00:18:05,990 +للحق والموضوعية في إطار الخلاف عند العلماء هل + +206 +00:18:05,990 --> 00:18:11,490 +الأصل التعدد ولا الأصل واحدة هنا كمان قال الأصل + +207 +00:18:11,490 --> 00:18:15,030 +التعدد حسب الآية فانكحوا ما طاب لكم من النساء مثنى + +208 +00:18:15,030 --> 00:18:18,790 +و ثلاثة و رباع يعني هذا الأصل فإن خفتم ألا تعدلوا + +209 +00:18:18,790 --> 00:18:23,330 +فيكفيكم معاه أخذ يعني و بنى على ظهر الآية ولكن بعض + +210 +00:18:23,330 --> 00:18:27,950 +يعني فهم أمرا أخر ومنصوص هذا الكلام في كتب الفقه + +211 +00:18:27,950 --> 00:18:34,070 +لأ الأصل واحدةفإذا كان عنده العدل فيجوز لو أن يعدد + +212 +00:18:34,070 --> 00:18:38,670 +والمسألة مطروحة في كتب الفقه في هذا الأمر تفضل يا + +213 +00:18:38,670 --> 00:18:43,110 +أستاذ الأستاذ و هناك رد قوي علمي يقول إن الإسلام + +214 +00:18:43,110 --> 00:18:48,630 +قد ضلم الغرب في موضوع عدو الزوجات نقول له لقد + +215 +00:18:48,630 --> 00:18:54,170 +فانطقك الحق على لسانك ليه لأنه اضطق كإيام فلو لا + +216 +00:18:54,170 --> 00:19:01,080 +الإسلاملم يهتم بأنه يكون للرجل أكتر من إمرأة لكي + +217 +00:19:01,080 --> 00:19:06,000 +يبقى في المجتمع من العوارس فإن بقى من ال .. فلو + +218 +00:19:06,000 --> 00:19:12,280 +ترك الإسلام العوارس دون أمن يحث الرجال على زواجهن + +219 +00:19:12,280 --> 00:19:18,280 +والتعدد لكي تنهر كل إمرأته في هذه الدنيا رجلا لكان + +220 +00:19:18,280 --> 00:19:22,790 +هو عيوبالله يفتح عليك وده جانب مهم جدا يعني يضاف + +221 +00:19:22,790 --> 00:19:26,810 +إلى ما ذكرناه ربما ليس مذكورا هنا وده من باب + +222 +00:19:26,810 --> 00:19:31,050 +الإضافة الجميل لماذا ينظر دائما إلى نصف الكوب زي + +223 +00:19:31,050 --> 00:19:37,250 +كما يقول كوبة كامل ننظر إليه بعين كاملة متكاملة طب + +224 +00:19:37,250 --> 00:19:40,590 +هذه المرأة اللتي أنت قلبك عليها أيها الإنسان أو + +225 +00:19:40,590 --> 00:19:44,750 +تدعينا طب وين المرأة الأخرى؟ أين النصف الآخر؟ أين + +226 +00:19:44,750 --> 00:19:49,880 +العوانس؟ أين الأرامل؟ أين زوجات الشهداء؟يعني الذي + +227 +00:19:49,880 --> 00:19:54,020 +ينظر الامثلة ينبغي أن ينظر لها بمنظور متكامل وهذا + +228 +00:19:54,020 --> 00:19:59,880 +يعني ما يتميز به الله تعالى عن البشر أن علمه كامل، + +229 +00:19:59,880 --> 00:20:03,860 +حكمته كاملة، حكمته تام، لا ينظر إلى الأمور يعني + +230 +00:20:03,860 --> 00:20:07,560 +كما ننظر إليه نحن من زاوية ومن ذار وجزء فربنا + +231 +00:20:07,560 --> 00:20:11,940 +سبحانه وتعالى علمه شامل وعلمه كامل وحكمته شاملة + +232 +00:20:11,940 --> 00:20:17,620 +وكاملة فهو يراعيالجميع لأن الجميع خلقه سبحانه و + +233 +00:20:17,620 --> 00:20:22,880 +تعالى وهو رب العالمين وهو رب الناس ليس رب فئة من + +234 +00:20:22,880 --> 00:20:27,500 +الناس هنا أو هناك هو رب الناس و رب العالمين ينظر + +235 +00:20:27,500 --> 00:20:33,360 +إلى مصلحتهم جميعا و يحكم بها طيب عشان في موضوع + +236 +00:20:33,360 --> 00:20:39,670 +يعني آخر فنحاول نسير في موضوعناالنقطة الخامسة التي + +237 +00:20:39,670 --> 00:20:46,250 +يمكن ان نرد فيها او بها على هؤلاء تفضلي اخت شرع + +238 +00:20:46,250 --> 00:20:49,270 +الله تعالى التعدد مراعاة للفترة و حلل المشكلات + +239 +00:20:49,270 --> 00:20:52,130 +الاجتماعية و فيها مصلحة للرجل و المرأة بارك الله + +240 +00:20:52,130 --> 00:20:56,190 +فيك يعني هذا كلام عام يحتاج إلى تفصيل ان هذا + +241 +00:20:56,190 --> 00:21:04,020 +التشريع و هذا الحكمفي إباحة التعدد له مصالح مش + +242 +00:21:04,020 --> 00:21:08,060 +مصلحة مصالح متعددة فيها مصلحة للمرأة فيها مصلحة + +243 +00:21:08,060 --> 00:21:13,640 +للرجل فيها مصلحة للمجتمع يمكن أن نتبينها في النقاط + +244 +00:21:13,640 --> 00:21:18,000 +التالية ربما بعض النقاط مكررة لكن الآن يعني مذكورة + +245 +00:21:18,000 --> 00:21:23,220 +ضمن هذا التفصيل من هذه النقاط اللي فيها مصلحة + +246 +00:21:23,220 --> 00:21:28,990 +للمرأة مصلحة للرجل مصلحة للمجتمع واحد فضل أختكعادة + +247 +00:21:28,990 --> 00:21:32,990 +الرجال بسبب الحروب قضيت على بوابين المدنان عن + +248 +00:21:32,990 --> 00:21:36,490 +الدنيا؟ وهذه المشكلة تكلمنا عنها بسبب الحروب + +249 +00:21:36,490 --> 00:21:39,650 +وانتهينا منها وشوفنا كيف في ألمانيا كانوا يدعون + +250 +00:21:39,650 --> 00:21:46,770 +إلى التعدد حتى اني قرأت في بعض المقالات قديما انه + +251 +00:21:46,770 --> 00:21:52,470 +صارت هناك مسيرة في ألمانيا من النساء كنا يطالبنا + +252 +00:21:52,470 --> 00:21:56,290 +بالتعدد بعد الحرب العالمية الأولىيعني هم أنفسهم + +253 +00:21:56,290 --> 00:22:00,230 +النساء الألمانيات خرجوا بمسيرة ربما لها علاقة + +254 +00:22:00,230 --> 00:22:04,630 +بالمؤتمر اللي اتكلمنا عنه او ما بعده يعني لأ أذكر + +255 +00:22:04,630 --> 00:22:10,070 +ذلك جيدا النقطة الثانية مين من الأخوات ماسمعناهم؟ + +256 +00:22:10,070 --> 00:22:13,390 +اتفضل الأخرى إذا كانت المرأة عقيمة لاتنجف والزوج + +257 +00:22:13,390 --> 00:22:18,370 +متلاحظ فعلها ولد نعم، إيش في هذه الحالة؟ آه يا + +258 +00:22:18,370 --> 00:22:21,170 +أستاذ وسامة، قولوا خليك معايا ان شاء الله عشرين + +259 +00:22:21,170 --> 00:22:27,920 +سنة واتحملنامش مش مش احنا اللي بتسأل ترفع أصبعها + +260 +00:22:27,920 --> 00:22:31,040 +اه احنا الآن في هذه القضية و بعدها بنكمل احنا في + +261 +00:22:31,040 --> 00:22:36,000 +هذه المسألة اذا كانت الزوجة عقيمة ولا تنجب فمين + +262 +00:22:36,000 --> 00:22:42,080 +أفضل يطلقهالأنه يريد الولد ام يتزوج امرأ اخرى و + +263 +00:22:42,080 --> 00:22:46,120 +تبقى على ذمته و يبقى لها الحب و الحنان و الاحترام + +264 +00:22:46,120 --> 00:22:49,980 +و التقدير و العشرة الزوجية .. هذه من ضمن الحكم .. + +265 +00:22:49,980 --> 00:22:52,980 +لأن اذا تطرح الحكم من ذلك .. فقد تكون المقرفة + +266 +00:22:52,980 --> 00:22:57,720 +يحتاج الراجل .. فافضل ما ان يتزوج عليها لأن من حقه + +267 +00:22:57,720 --> 00:23:00,520 +الولد و الإنجاب اذا كان الله تعالى قد ابتلاها .. + +268 +00:23:00,520 --> 00:23:04,850 +هتبتلأ من الله .. ليس هي بيدهفأفضل لو إذا كان هناك + +269 +00:23:04,850 --> 00:23:09,930 +بعض الأزواج و أنا أعلموا بعضهم يعني خلاص مابدوش + +270 +00:23:09,930 --> 00:23:14,590 +يلقلف مش حابب و ربما لعيب من زوجتي و يريد أن يبقى + +271 +00:23:14,590 --> 00:23:17,930 +معها و لا يريد أن يعدد هذا حر قلنا قبل قليل هذا + +272 +00:23:17,930 --> 00:23:23,130 +ليس واجب ولا يعني فضل لكن إذا كان في نفسه هل سنجد + +273 +00:23:23,130 --> 00:23:26,950 +من يمنعه أو يقول لأ و ليس من حقك من سيقول له لأ + +274 +00:23:26,950 --> 00:23:30,830 +أحد يملك ذلك فهو من حقه أن يكون له نعم إيش السؤال + +275 +00:23:30,830 --> 00:23:35,250 +فترةيعني الرجال هو اللي .. اللي مثلا عنده المشكلة؟ + +276 +00:23:35,250 --> 00:23:38,270 +ايش حال الإسلام في هذه الشركة؟ ربما يعني ترفع + +277 +00:23:38,270 --> 00:23:42,650 +المرأة إذا أرادت ذلك ومن حقها أمرها إلى القاضي إذا + +278 +00:23:42,650 --> 00:23:47,550 +هو لا يريد يعني تطليقها وكذا و تطلب التفريق بينه + +279 +00:23:47,550 --> 00:23:51,990 +وبينه وبرضاهمافإن أراد فصالة عن تراضي منهم أو + +280 +00:23:51,990 --> 00:23:55,550 +تشاورهم فلا جناح عليها فهي بتروح و إذا كان هو بدوش + +281 +00:23:55,550 --> 00:23:59,530 +يطلق و هي بدها فلا جناح عليهم في ما افتدت به + +282 +00:23:59,530 --> 00:24:02,190 +ساعتها هي بتتفرج و تقول انا ابدع فيك من المهر و + +283 +00:24:02,190 --> 00:24:05,290 +المتأخر و بديش حاجة منك و كده و كده تصير نوع من + +284 +00:24:05,290 --> 00:24:09,430 +الخلوع لكن الخلوع ده يعني محدود و في إطار ضيق مش + +285 +00:24:09,430 --> 00:24:12,890 +تشريع نروح نشرع زي ما هو في بعض البلدان و صارت كل + +286 +00:24:12,890 --> 00:24:16,430 +واحدة إمرأة بدهاش زوجها أو في مشاكل بسيطة تروح + +287 +00:24:16,430 --> 00:24:20,860 +إياهتخلع .. لما نخلع المصمار .. اه .. فده مشكلة .. + +288 +00:24:20,860 --> 00:24:24,560 +لما نقطع هذا الحق و نشرع و نوسع في القضية و نفتح + +289 +00:24:24,560 --> 00:24:28,160 +هذا الباب .. فده باب فتنة .. هذا في حدود ضيقة .. + +290 +00:24:28,160 --> 00:24:31,320 +يعني يدرس القاضي فيها الحالة فإذا اقتنع بها .. + +291 +00:24:31,320 --> 00:24:34,580 +يعني يمكن أن يسمع منها .. لما لم يقتنع .. ممكن أن + +292 +00:24:34,580 --> 00:24:37,780 +يوفق بينهما .. كذا .. كذا .. إلى آخر ذلك .. بيكون + +293 +00:24:37,780 --> 00:24:41,850 +في نطاقها السليماصعيأما هي من حقها من حقها لو + +294 +00:24:41,850 --> 00:24:47,070 +أرادت وصار هناك تشاور وتراضي فمسموح لها في ذلك إذا + +295 +00:24:47,070 --> 00:24:51,010 +كان منصوص في القانون أو في المحاكم الشرعية على مثل + +296 +00:24:51,010 --> 00:24:56,470 +هذه الحالات وأعتقد إنها منصوصة في محاكمنا طيب في + +297 +00:24:56,470 --> 00:25:01,190 +نقطة جيم أيضا قريبة من عقم المرأة إذا كانت المرأة + +298 +00:25:01,190 --> 00:25:02,030 +مالة يا أخوات + +299 +00:25:11,040 --> 00:25:15,200 +بارك الله فيك يعني إذا لم تستطع المرأة تعطي الزوج + +300 +00:25:15,200 --> 00:25:19,160 +حقه الشرعي من المعاشرة الزوجية و هذا أمر يعني + +301 +00:25:19,160 --> 00:25:23,900 +موجود كلكم أخوات لنا و ربما كثير منكم نساء و زوجات + +302 +00:25:23,900 --> 00:25:28,100 +و تعلم هذا الأمر فإذا أيضا الله ابتلى بمرض بكذا + +303 +00:25:28,100 --> 00:25:32,940 +يمنعها من هذا الحق لزوجها هل أيضا ليس من حقي في + +304 +00:25:32,940 --> 00:25:38,220 +هذه الحالةان يعني يكون او يتزوج بالحلال والمباح + +305 +00:25:38,220 --> 00:25:43,680 +ويقضي شهوته اللتي شرعها الله تعالى له بالمباح او + +306 +00:25:43,680 --> 00:25:48,040 +الحلال افضل ما يقضيها بالحرام وينظر الى الحرام هنا + +307 +00:25:48,040 --> 00:25:54,400 +و هناك و تبقى زوجاله وافضل ان يطلقها فتبقى زوجة + +308 +00:25:54,400 --> 00:25:59,950 +يعني اولى ويتزوج عليها لهذا السبب في نقطة قديكون + +309 +00:25:59,950 --> 00:26:04,890 +ربما الحساسية الخلام تمنع بعض الأخوات من الحديث + +310 +00:26:04,890 --> 00:26:10,630 +عنها احنا يعني بنقرب الموضوع فيها ربما هناك بعض + +311 +00:26:10,630 --> 00:26:16,170 +الرجال الله تعالى وضع فيهم قوةيعني لا يكتفي في من + +312 +00:26:16,170 --> 00:26:20,390 +خلالها بزوجة واحدة هكذا خلقه الله و هكذا يعني كما + +313 +00:26:20,390 --> 00:26:26,070 +يقال في علم النفس في سيولوجيته و تكوينه الجسدي و + +314 +00:26:26,070 --> 00:26:32,630 +النفسي و عنده طاقةأكبر من أن يكتفي بواحدة فبدل أن + +315 +00:26:32,630 --> 00:26:35,390 +يلجأ إلى الحرام أو إلى الزنا أو كذا ولا تحتمل + +316 +00:26:35,390 --> 00:26:39,730 +المرأة تلك الطاقة فيمكن أن يكون الحال في هذه + +317 +00:26:39,730 --> 00:26:44,050 +الحالة زوجة ثانية أو ربما ثالثة إذا كان من هذه + +318 +00:26:44,050 --> 00:26:48,090 +النوعيات وهذه فطرة الله التي فطر الناس عليها + +319 +00:26:48,090 --> 00:26:51,890 +لتبديل لخلق الله هيك ربنا خلقه هيك ربنا فطره وان + +320 +00:26:51,890 --> 00:26:58,070 +اعلن بعض الأزواج من هذا النوع وليس بياته هذا الأمر + +321 +00:26:59,950 --> 00:27:05,050 +نقطة يعني الخامسة ربما يقع فيها البعض ويكون حلها + +322 +00:27:05,050 --> 00:27:12,390 +وعلاجها هو التعددأن يقع الراجل في خطأ مع امرأة + +323 +00:27:12,390 --> 00:27:16,950 +فيرتكب معها الفاحشة ويكونوا متزوج ولم يصل الأمر + +324 +00:27:16,950 --> 00:27:20,790 +إلى الحاكم ولا أقيم عليهم حد ولا كده فالأفضل أن + +325 +00:27:20,790 --> 00:27:26,550 +يصحح خطأه بالزواج منها مدام أنت فعلت هذه الفاحشة + +326 +00:27:26,550 --> 00:27:30,410 +فالعجزلك أن تتركها او تهملها او تفعل او او او و + +327 +00:27:30,410 --> 00:27:35,450 +هذا ذنبيحاسب عليه إلا أن يراجع ويتوب ويندم وكذا + +328 +00:27:35,450 --> 00:27:42,030 +ويصلح هذا الخطأ يعني بالزواج منها لو وقع هذا الأمر + +329 +00:27:42,030 --> 00:27:48,110 +من بعض أو من أحد الرجال المتزوجين فيكون الحل الستر + +330 +00:27:48,110 --> 00:27:52,450 +عليها بهذه الطريقة وقد حدث في التاريخ الإسلامي بعض + +331 +00:27:52,450 --> 00:28:00,630 +الحوادث مثل هذا الأمر أيضا في حالةالاخيرة المذكورة + +332 +00:28:00,630 --> 00:28:03,850 +عندنا هنا تفضل يا عزيزي إذا استحكمت الخلافات بين + +333 +00:28:03,850 --> 00:28:07,990 +زوجين مفنن الأفضل الفلس هو أفضل ان يتم طلاق المرأة + +334 +00:28:07,990 --> 00:28:11,530 +و تشتت الأولاد فيكون الحال بزواج متاني مع بطائق + +335 +00:28:11,530 --> 00:28:16,050 +بارك الله فيك ممكن في خلافات دائما مستمرطب هو يظل + +336 +00:28:16,050 --> 00:28:19,130 +عايش على هالخلافات أو هي عايش على هالخلافات ممكن + +337 +00:28:19,130 --> 00:28:23,210 +أن تبقى زوجة له سواء في بيتي أو تسكن في بيت آخر هي + +338 +00:28:23,210 --> 00:28:27,230 +أولاد أو تبقى زوجة له وكذا وكذا و بالاتفاق معاه + +339 +00:28:27,230 --> 00:28:32,630 +بأي شكل من أشكال التراضيوأن امرأة خافت من بعلها + +340 +00:28:32,630 --> 00:28:38,950 +نشوزا او اعراضا فلا جناح عليهم ان يصلحا بينهما + +341 +00:28:38,950 --> 00:28:43,410 +صلحا يعني ان يتفقا بينهم على اي شكل ممكن هي تقوله + +342 +00:28:43,410 --> 00:28:46,850 +انا مابديش حق الشرع روح كده شوف حياتك انا اولادي + +343 +00:28:46,850 --> 00:28:50,430 +اعيش لحالي ممكن كده ممكن انت تنازل عن بعض حقوقك في + +344 +00:28:50,430 --> 00:28:54,050 +المبيت في كده في الانفاق احيانا اذا امرها متيسر + +345 +00:28:54,050 --> 00:29:00,500 +وتبقى زوجة له والقرآن يقولوإن امرأته انخافت من + +346 +00:29:00,500 --> 00:29:03,800 +بعدها نجوزا او إعراضا فلا جناح عليهم أن يصلحا + +347 +00:29:03,800 --> 00:29:09,140 +بينهما صلحا يعني يتفقوا والصلح خير هذه الآية اللي + +348 +00:29:09,140 --> 00:29:12,900 +كنا بنستخدمها في غير موضوعها أحيانا جاية في إطار + +349 +00:29:12,900 --> 00:29:17,540 +علاقة الراجل بالمرأة والصلح خير يعني اتفاق الراجل + +350 +00:29:17,540 --> 00:29:23,440 +مع المرأة بهذا الشكل خير له أو لها من أن يطلقها + +351 +00:29:23,440 --> 00:29:30,420 +افضلإلها أو إله من أن يطلقها ويتزوج غيرها أفضل أن + +352 +00:29:30,420 --> 00:29:34,380 +تبقى زوجة له تعيش مع أولادها تأخذ بعض حقوقها إذا + +353 +00:29:34,380 --> 00:29:38,840 +أرادت أن تتنازل برضاها هي دون أن يشترط هو عليه أو + +354 +00:29:38,840 --> 00:29:42,120 +يفرق وإن امرأته انخافت يعني هي خايفة من زوجها + +355 +00:29:42,120 --> 00:29:46,660 +يتزوج تاني أو يظلمها أو يفعل أو أو فتبقى زوجة أفضل + +356 +00:29:46,660 --> 00:29:52,040 +وخير من أن تتطلق لأن الإسلام حريص برضه على الأولى + +357 +00:29:52,040 --> 00:29:58,910 +كما هو حريص على الزوجهذه بعض الحكم ربما غابت عنا + +358 +00:29:58,910 --> 00:30:04,810 +حكم كثيرة أستاذنا والأخ و السامة يعني أضاف إلينا + +359 +00:30:04,810 --> 00:30:08,030 +بعض الحكم ربما بعض الأخوات ونترك المجال في دقيقة + +360 +00:30:08,030 --> 00:30:11,410 +أو دقيقتين إذا في بعض النقاط ممكن أغفلناها أو لم + +361 +00:30:11,410 --> 00:30:15,490 +نذكرها في الحكم من التعدد ممكن بعض الأخوات يعني + +362 +00:30:15,490 --> 00:30:20,610 +اتفيدنا فيها أو إذا انتبهت إليها آه يا أخوات قبل + +363 +00:30:20,610 --> 00:30:23,070 +ما نعمل استفتاء الأخير + +364 +00:30:24,860 --> 00:30:28,580 +قبل و في النص و بعد .. هنعملناها قبل .. هنعملناها + +365 +00:30:28,580 --> 00:30:32,280 +في النص و الآن في الختام .. إيه إيش رأيكوا الآن؟ + +366 +00:30:32,280 --> 00:30:37,000 +مين ضلت معارضة؟ بدون حرج .. أه .. واحدة تين .. + +367 +00:30:37,000 --> 00:30:39,600 +واحدة يعني اللي جالب .. طيب يعني هي كانت نسبة + +368 +00:30:39,600 --> 00:30:44,440 +مطمنةكمان مرة اخرى ليس شرطا ان المرأة يعني انه + +369 +00:30:44,440 --> 00:30:48,500 +راضى او قابلة على نفسها او على غيرها هذه لا احد من + +370 +00:30:48,500 --> 00:30:53,600 +النساء يعني نفسيا تقبله برضه كامل قد تقبله بعض + +371 +00:30:53,600 --> 00:30:58,120 +النساء وانا اعلم بعضهم هي من زوجت زوجها وهي من + +372 +00:30:58,120 --> 00:31:03,100 +خطبت له وهي من ذهبت لغروف فيهلظروف عندها يعني حاسة + +373 +00:31:03,100 --> 00:31:07,080 +نفسها مقصرة هي كذا هي كذا و حاسة الزوجة أنه ملح + +374 +00:31:07,080 --> 00:31:10,700 +على هذا الأمر فبداش تحرمه من ذلك وتوقعه في الحرام + +375 +00:31:10,700 --> 00:31:14,960 +لإن ظروف أحد هذه الظروف مثلا فذهبت معاه و راحت يا + +376 +00:31:14,960 --> 00:31:18,960 +عم احنا مثلا تطمن أهل الزوجة الثانية انه انا مش + +377 +00:31:18,960 --> 00:31:22,900 +غصب عني او كذا انا يعني ظروف زوجي و انا راضي و انا + +378 +00:31:22,900 --> 00:31:29,190 +و تعيش الاثنتين او الاثنتان في بيت واحدوانا يعني + +379 +00:31:29,190 --> 00:31:33,450 +قريب من بعض البيوت اللي بهذه الصورة ولا أحد يعلم + +380 +00:31:33,450 --> 00:31:38,470 +أن فلانة ضرت فلانة من كثرة خروجهن معا واجتماعهن + +381 +00:31:38,470 --> 00:31:45,130 +معا وتفاهمهما معا وسنوات طويلة لم تحدث بينهما + +382 +00:31:45,130 --> 00:31:49,150 +مشكلة واحدة وده قلة ربما من النساء معا لكن في + +383 +00:31:49,150 --> 00:31:53,190 +موجود وفي المجتمع وانا على الطلاع بذلك من بعض + +384 +00:31:53,190 --> 00:31:58,150 +الأقرباء أو القريبات منه فهذا قد يكونولكن نسبته + +385 +00:31:58,150 --> 00:32:02,430 +حسب اعتقاده واعتقاده قليلة صحيح لكن موجود في البعض + +386 +00:32:02,430 --> 00:32:06,150 +لكن الغالب يعظم هو النسبة الأخبار المرأة لا تقبله + +387 +00:32:06,150 --> 00:32:11,470 +لنفسها بكل رضا تام وكامل إلا منظر أما الظروف + +388 +00:32:11,470 --> 00:32:16,010 +والحكم والأحوال هي التي تفرض وهذه تبقى حكمة الله + +389 +00:32:16,010 --> 00:32:20,410 +تعالى ويبقى حكم الله تعالى وحكمه سبحانه وتعالى فيه + +390 +00:32:20,410 --> 00:32:24,930 +المصلحة دائما في كل المجالات ليس في هذا المجال + +391 +00:32:24,930 --> 00:32:30,710 +فحسبوالله تعالى ألا يعلم من خلق و هو اللطيف الخبير + +392 +00:32:30,710 --> 00:32:35,490 +هو خلق الخلق و يعلم أحوالهم و مصالحهم فحينما يشرع + +393 +00:32:35,490 --> 00:32:41,610 +لمصلحة الناس ليس في ذلك ظلم لأحد حاشة لله سبحانه + +394 +00:32:41,610 --> 00:32:47,770 +وتعالى أو تحيز لأحد أو كده هو يعطي الأحكام للجميع + +395 +00:32:47,770 --> 00:32:54,310 +سبحانه وتعالى العليم القدير اللطيف الخبير فضل يا + +396 +00:32:54,310 --> 00:33:03,350 +وسلسلالمرأة الجنة تزوّد على زوجه العقيم يعني عقله + +397 +00:33:03,350 --> 00:33:08,370 +كانت أولاده الجن منذ التلافين عام و بعد التلافين + +398 +00:33:08,370 --> 00:33:14,310 +عام تزوّد و كان برضاه فأنجب من الجديد فالأولاد + +399 +00:33:14,310 --> 00:33:19,190 +الجن لا يقولون لأمهم يا أمي لقدر ما يناديوها + +400 +00:33:19,190 --> 00:33:24,370 +خالتهم بيومي لأنها محتضنة لهم احتضانهم شديدة و + +401 +00:33:24,370 --> 00:33:30,240 +قوية و لا يعزمعوضوها عن النقص التي كانت تشعر به من + +402 +00:33:30,240 --> 00:33:38,260 +عدم الأولاد سيقوم هؤلاء الأبناء .. أبناؤها وسيقفون + +403 +00:33:38,260 --> 00:33:43,980 +معاها في وقت شدتها فتلك اللي انتشتنيت بهذا الباء + +404 +00:33:43,980 --> 00:33:50,100 +الاقتلاء لابد من أن تكون باحثة لزوجها عن امرأة + +405 +00:33:50,100 --> 00:33:54,620 +تنجب لكي تحافظ على نفسها في آخر حياتها منهابارك + +406 +00:33:54,620 --> 00:33:58,060 +الله فيك و جزاك الله خيرا في النهاية اخوات و مرة + +407 +00:33:58,060 --> 00:34:02,640 +اخرى و احنا لم ننتهي بعد لا يعني ذلك اننا نشجع على + +408 +00:34:02,640 --> 00:34:06,720 +التعد و نأمر الناس به الاصل واحد و الاصل انسان + +409 +00:34:06,720 --> 00:34:11,000 +المكتفي بواحدة و ليس عنده ظروفا او تتعويل الاصل و + +410 +00:34:11,000 --> 00:34:15,040 +ليس حكم مننا يعنيالاصل ان اعيش مع زوجتي امر يعني + +411 +00:34:15,040 --> 00:34:18,080 +وضع انطباعي لكن احتاج الى شيء من هذا اراد هو من + +412 +00:34:18,080 --> 00:34:21,840 +نفسي فليس هناك ما يمنع وليس يعني هو تشجيع على + +413 +00:34:21,840 --> 00:34:26,540 +التعدد من المبدأ الا اذا حكمت ظروف او كانت هناك + +414 +00:34:26,540 --> 00:34:29,740 +ظروف في بعض المجتمعات او بعض الكذا فيكون هناك + +415 +00:34:29,740 --> 00:34:37,550 +التوجيه والتشجيع حسب الظروف اللي بتفرض نفسهاالغرب + +416 +00:34:37,550 --> 00:34:45,590 +بيمّع التعدد و يحرّب التعدد و يعتب على المسلمين أو + +417 +00:34:45,590 --> 00:34:51,410 +ينتقد المسلمين و الإسلام كحكم شرعي أنه عدد و هو في + +418 +00:34:51,410 --> 00:34:58,730 +ذات الوقت ماله يعدد بصورة أكثر مما جاء في الإسلام + +419 +00:35:00,420 --> 00:35:07,760 +ويناقضوا نفسه عنده تعدد الخليلات و العشيقات و في + +420 +00:35:07,760 --> 00:35:12,760 +المصطلح ال boy friend و boy friend ده اللي فيه .. + +421 +00:35:12,760 --> 00:35:15,560 +اللي عشان اسمها girl friendيعني اللي عنده + +422 +00:35:15,560 --> 00:35:19,300 +boyfriend و girlfriend و هذا تطلع معاه و تروح معاه + +423 +00:35:19,300 --> 00:35:23,460 +و ال bodyguard و مش عارف مين و اللي بتخلوا في + +424 +00:35:23,460 --> 00:35:26,380 +بيوتهم و المصاحبين يعني الصلاحات أجنبية و غربية + +425 +00:35:26,380 --> 00:35:30,940 +ممكن أي حد يطلع مع أي حد و حتى يكون متزوج هو او هي + +426 +00:35:30,940 --> 00:35:35,740 +متزوجة و هذا صاحب العائلة او مش عارف ايش بيسموه في + +427 +00:35:35,740 --> 00:35:39,680 +الغرب يعني اللي بيدخل و بطلع و بروح و بيجي و يعني + +428 +00:35:39,680 --> 00:35:45,680 +سداح مداح و الحرية المطلقة فنجي بتعددفي ذلك لكنه + +429 +00:35:45,680 --> 00:35:50,140 +تعدد غير مشروع تعدد بالحرام يمكن يخرج معاها + +430 +00:35:50,140 --> 00:35:54,900 +وينفردوا ويختلطوا ويختلوا ويفعلوا ما يشاءون تحت + +431 +00:35:54,900 --> 00:35:59,440 +شعار الحرية المطلقة أو الحرية الشخصية أو كذا أليس + +432 +00:35:59,440 --> 00:36:08,370 +هذا تعدد؟لكنه تعدد محرم تعدد حرام غير جائع أما في + +433 +00:36:08,370 --> 00:36:13,690 +إطار الإسلام فالتعدد مقنن ومضبوط وفي شروط وضوابط + +434 +00:36:13,690 --> 00:36:18,070 +ومباح وحلال وبشرط العدل وبشرط الإنفاق وتحمل + +435 +00:36:18,070 --> 00:36:21,550 +مسئولية هناك وعدد بلا مسئولية هو ليس مسئول عن هذه + +436 +00:36:21,550 --> 00:36:26,090 +التي اتخذها خليلة أو عشيقة أوو يستمتع بها و فقط و + +437 +00:36:26,090 --> 00:36:31,550 +بعدها يسأل عنها في كذا و حتى لو لأ قدروا أن حملت + +438 +00:36:31,550 --> 00:36:35,450 +منه بطريق الحرام و الخطأ تتخلص منه بالاجهاد و + +439 +00:36:35,450 --> 00:36:42,750 +الأمر عندهم سهل و ممكن هناك تصبح ظاهرة اللقطاء و + +440 +00:36:42,750 --> 00:36:47,310 +دور اللقطاء المنتشرة في الغرب + +441 +00:36:52,130 --> 00:36:55,670 +ربما الوقت كده يعني أدركنا و قمنا نود الحديث عن + +442 +00:36:55,670 --> 00:37:01,710 +العمل خارج البيت لكنه موضوع ياخد وقتا و ربما + +443 +00:37:01,710 --> 00:37:07,750 +الحديث عن تعادل الزوجات يعني كان له إثارة و + +444 +00:37:07,750 --> 00:37:13,730 +مداخلات كثيرة من الجميع فنقف عند العمل خارج البيت + 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دراسي مفيد + +457 +00:38:12,760 --> 00:38:17,540 +بعنوان الحكم بما أنزل الله مسألة أو قضية بيسأل + +458 +00:38:17,540 --> 00:38:23,880 +عنها الكل حكمهوضوابطه وموانعه والناس بتسأل كثيرا + +459 +00:38:23,880 --> 00:38:29,120 +عن هذه القضية في تساؤلاته لماذا تأخر تطبيق الشريعة + +460 +00:38:29,120 --> 00:38:32,720 +في قطاع غزة ولماذا لا يتطبق كل هذه الأسئلة وغيرها + +461 +00:38:32,720 --> 00:38:37,280 +سيكون الجواب عليها أو عنها في اليوم الدراسي سيبدأ + +462 +00:38:37,280 --> 00:38:41,260 +يوم السبت الساعة التاسعة صباحا حتى الثانية ظهرافي + +463 +00:38:41,260 --> 00:38:45,720 +مبنى طيبة فانتوا مدعوات للحضور و لو كان في إمكانية + +464 +00:38:45,720 --> 00:38:48,880 +أو طريقة أو وسيلة نسجل فيها حضور ممكن نعمل على + +465 +00:38:48,880 --> 00:38:53,780 +الحضور و المشاركة يعني درجات لكن صعب الإثبات مني + +466 +00:38:53,780 --> 00:38:57,940 +لكن على الأقل احنا كنا ثقة فيكم بدل ما تيجوا في + +467 +00:38:57,940 --> 00:39:01,340 +هذا المكان أو قبله ممكن أن تتوجهوا إلى هذا المكان + +468 +00:39:01,340 --> 00:39:04,580 +و تستفيدوا منه ان شاء الله تعالى و برك الله فيكم + diff --git a/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/944ntkglc5w_raw.json b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/944ntkglc5w_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..f38d72adbe7ef0362630a34e90faf1d30e9fa44c --- /dev/null +++ b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/944ntkglc5w_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4960, "start": 20.92, "end": 49.6, "text": "الحمد لله يا رب العالمين الصلاة والسلام على أشرف الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحبه أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما علمتنا وازيدنا علمة آمين يا رب العالمين أما بعد كنا بدأنا الحديث يا أخوات في المحاضرة الماضية حول قضايا المرأة", "tokens": [6027, 35571, 3215, 24976, 3224, 35186, 12602, 3555, 18863, 45340, 9957, 31767, 15040, 3660, 16070, 3794, 37440, 15844, 5551, 8592, 28480, 33962, 1211, 4587, 46952, 25708, 9673, 2288, 3794, 1211, 9957, 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+00:00:38,650 --> 00:00:44,850 +علمتنا وازيدنا علم أمين رب العالمين أما بعدكان + +6 +00:00:44,850 --> 00:00:47,630 +الحديث يا أخوات في المحاضرة الماضية حول وسائل + +7 +00:00:47,630 --> 00:00:53,790 +التغريب و هي وسائل أربع نذكرنا فيها يا أخوات فضل + +8 +00:00:53,790 --> 00:01:01,590 +العلمانية و القومية و المرأة و العولة ثم بدأنا + +9 +00:01:01,590 --> 00:01:07,730 +الحديث عنأول وسائل التغريب وهي العلمانية عرفنا + +10 +00:01:07,730 --> 00:01:13,490 +فيها معنى العلمانية لغة واصلاح وأساس واصل هذه + +11 +00:01:13,490 --> 00:01:18,490 +الكلمة عند أصحابها وأهلها الذين قالوا ونادوا بها + +12 +00:01:18,490 --> 00:01:25,190 +وهم الغرب وخلصنا إلى خلاصة مفادها أن العلمانية + +13 +00:01:25,190 --> 00:01:33,200 +كلمة علمانية ترجمة غير دقيقة لال secularism هذا + +14 +00:01:33,200 --> 00:01:37,700 +المصطلح الأجنبي الغربي لها secularism فلما نأتي + +15 +00:01:37,700 --> 00:01:41,740 +نترجم ال secularism إلى العلمانية بتكون ترجمة غير + +16 +00:01:41,740 --> 00:01:46,700 +دقيقة وانما الترجمة الدقيقة والصحيحة والاصلية لهذه + +17 +00:01:46,700 --> 00:01:52,660 +الكلمة secularism هي إيه؟ اللادينية وليس العلمانية + +18 +00:01:52,660 --> 00:01:58,700 +ولكن لماذا ركزوا على كلمة العلمانية بل العلمانية + +19 +00:01:58,700 --> 00:02:05,980 +بالكثر؟ليش ركزوا عليها قولنا؟ عشان إيش؟ لأ لنسأل + +20 +00:02:05,980 --> 00:02:10,720 +عن أصلها في اللغة، ليش هم تعمدوا وقصدوا أن يترجموا + +21 +00:02:10,720 --> 00:02:17,100 +ال secularism بدل لا دينية إلى علمانية؟ ليش؟ أول + +22 +00:02:17,100 --> 00:02:19,760 +شيء حتى يرغبوا الناس بيها وحتى لا تكون بمعنى .. + +23 +00:02:19,760 --> 00:02:22,660 +المعنى اللا ديني وفيبقى يبتعد الناس عنهبارك الله + +24 +00:02:22,660 --> 00:02:25,580 +.. لأن كلمة اللادينية بتصادم مشاعر المسلمين فبدو + +25 +00:02:25,580 --> 00:02:28,740 +مش هذا المصادم .. بدو المسلمين يستسيقوها و + +26 +00:02:28,740 --> 00:02:33,980 +يستمرقوها و يتقبلوها فلجوا أنسبش إلى العلمانية و + +27 +00:02:33,980 --> 00:02:38,160 +كأنهم بيوهموا المسلمين أنها من العلم أو اتجاه علم + +28 +00:02:38,160 --> 00:02:45,680 +لكن رأينا العلاقة العلمانية بالعلمو هي يعني + +29 +00:02:45,680 --> 00:02:50,800 +العلمية و ليس العلمانية لو أردنا النسبة و هي وجهة + +30 +00:02:50,800 --> 00:03:00,620 +نظر و منهج علمىيأتي بالتجارب والخبرات والبحث + +31 +00:03:00,620 --> 00:03:04,340 +والاستقرار هذا هو العلم ومنهج العلم لكن العلمانية + +32 +00:03:04,340 --> 00:03:12,260 +اللي ترجموها لل secularism التجاه مش علمي لا DNA + +33 +00:03:12,260 --> 00:03:17,800 +كما عرفنا في المصطلحات المختلفة وسنرى بعد قليل + +34 +00:03:17,800 --> 00:03:23,460 +الآنبعد الحديث عن التعريفات اللغوية والاصطلاحية + +35 +00:03:23,460 --> 00:03:28,600 +علاقة العلمانية بالدين وسيظهر لنا يعني ذلك + +36 +00:03:28,600 --> 00:03:34,940 +بالتفصيل شكل هذه العلاقة بين العلمانية والدين ومن + +37 +00:03:34,940 --> 00:03:40,160 +خلال التعرف على علاقة العلمانية بالعلم بدنا نشوف + +38 +00:03:40,160 --> 00:03:44,680 +هل في علاقة أو في نسبة ولا مافيشوكذلك علاقة + +39 +00:03:44,680 --> 00:03:49,280 +العلمانية بالأخلاق هذه التلت موضوعات المرتبطة + +40 +00:03:49,280 --> 00:03:53,220 +بالعلمانية شوف علاقة العلمانية بكل واحدة منهم + +41 +00:03:53,220 --> 00:03:57,480 +علاقة العلمانية بالدين بالعلم بالأخلاق ثم بعد ذلك + +42 +00:03:57,480 --> 00:04:04,140 +ننتقل إلى الحديث عن نشأة العلمانية في أوروبا حيكون + +43 +00:04:04,140 --> 00:04:09,240 +التركيز يعني عليها ومن ثم بعد ذلك نتعرف على نشأتها + +44 +00:04:09,240 --> 00:04:16,000 +في العالم الإسلامي لكن البدايةبالحديث عن النشأة في + +45 +00:04:16,000 --> 00:04:23,000 +أوروبا والعالم الغربى أول + +46 +00:04:23,000 --> 00:04:27,100 +موضوع في علاقة العلمانية بالأمور الثلاثة التي + +47 +00:04:27,100 --> 00:04:32,280 +ذكرناها علاقة العلمانية بالدين وموقف العلمانية من + +48 +00:04:32,280 --> 00:04:35,580 +الدين ممكن أن نقول علاقة وممكن أن نقول موقف شوف + +49 +00:04:35,580 --> 00:04:40,770 +شكل هذه العلاقة أو شكل هذا الموقف وقد عرفنامن + +50 +00:04:40,770 --> 00:04:45,730 +المحاضرة الماضية وقبل قليل في المراجعة السريعة + +51 +00:04:45,730 --> 00:04:50,510 +والملخص للمحاضرة الماضية ان كلمة علمانية او + +52 +00:04:50,510 --> 00:04:55,150 +العلمانية ترجمة خبيثة مقصودة لأنها غير دقيقة ولا + +53 +00:04:55,150 --> 00:05:00,450 +صحيحة لاتجاه ال secularism الغربي يعني هيك مصطلحة + +54 +00:05:00,450 --> 00:05:08,610 +في الغرب التي معناها الحقيقي لا دينية او ما ليس + +55 +00:05:08,610 --> 00:05:14,750 +بدينيلكن لماذا اختيرت كلمة علمانى كما قلنا ايضا + +56 +00:05:14,750 --> 00:05:19,070 +يعني مكرر الكلام بس بيطبط لنا شكل هذه العلاقة + +57 +00:05:19,070 --> 00:05:22,370 +لماذا اختاروا كلمة لا دينية لأنها + +58 +00:05:25,450 --> 00:05:29,830 +لأن أقل إثارة غير ما يقولوا إحنا لا دينيين وكأننا + +59 +00:05:29,830 --> 00:05:32,630 +جايين يخرجوا الناس من دينهم ومين بيقبل؟ واحد يقول + +60 +00:05:32,630 --> 00:05:36,290 +أنا بدي أخرجك من دينك حتى لو في النهاية استجاب، بس + +61 +00:05:36,290 --> 00:05:39,690 +بيستجيبش بطريقة الاستفزاز والإثارة، واحد يقول لأني + +62 +00:05:39,690 --> 00:05:44,550 +بدي أخرجك من .. طب مش خالي، لو بتخرج، بيبطل عنادا، + +63 +00:05:44,550 --> 00:05:49,610 +لكن في وسائل وفي طرق وفي أساليب يعني خبيثة وتزيين + +64 +00:05:49,610 --> 00:05:56,420 +لهذه المبادئكما رأينا في ملامح خطة التغريب تقوم + +65 +00:05:56,420 --> 00:05:58,880 +على تزيين هذه العبارات المدنية والتطور + +66 +00:05:58,880 --> 00:06:04,220 +والتكنولوجيا والحضارة وغير ذلك ومنها هذه الكلمة + +67 +00:06:04,220 --> 00:06:08,680 +العلمانية وكأنه اتجاههم علمي بدل كلمة اللادينية + +68 +00:06:08,680 --> 00:06:13,520 +معناها الحقيقة اذا على ماذا تقوم علاقة العلمانية + +69 +00:06:13,520 --> 00:06:19,480 +بالدين؟ هل هي علاقة الانسجام والتوافق ولا علاقة + +70 +00:06:19,480 --> 00:06:27,210 +ايش؟ تفضلعلمانية ولا علمانية؟ علمانية صح الألفار + +71 +00:06:28,240 --> 00:06:31,200 +بمعنى أنها لا دينية، يعني تقوم بنفي الدين عن + +72 +00:06:31,200 --> 00:06:34,240 +الدولة، بمعنى أنك تستطيع أيها المسلم أن تقوم + +73 +00:06:34,240 --> 00:06:37,520 +باسقرار داخل المسجد، أن تقيم الشعائر الدينية، ولكن + +74 +00:06:37,520 --> 00:06:42,320 +لا تقوم بتطبيق هذه الشعائر داخل الدولة، لأن نظرم + +75 +00:06:42,320 --> 00:06:45,400 +الدين الإسلامي أو .. وقصوص الدين الإسلامي لا + +76 +00:06:45,400 --> 00:06:49,440 +يتوافق ولا يتطابق مع التكنولوجيا والعصور المتقدمة + +77 +00:06:49,440 --> 00:06:52,540 +التي نعيش فيها، بإمكانك أن تصلي في المسجد، ولكن لا + +78 +00:06:52,540 --> 00:06:56,060 +تبقى دينك بالحياة السياسية والفكرية والاقتصادية + +79 +00:06:56,060 --> 00:06:59,830 +وغيرها.بارك الله فيك يعني كأنه بده من المسلم أو من + +80 +00:06:59,830 --> 00:07:05,430 +ينتسب إلى الدين أي أن كان أن يحصر نفسه في المزيد + +81 +00:07:05,430 --> 00:07:09,870 +في الصومعة في الكنيسة في كده لأنه أصلا ماتجاه غربي + +82 +00:07:09,870 --> 00:07:13,170 +حتى في الغرب هذا الاتجاه يفصل الدين عن الحياة عن + +83 +00:07:13,170 --> 00:07:16,370 +الدولة عن السياسة عن الحكم وبالتالي موقفها من + +84 +00:07:16,370 --> 00:07:21,450 +الدين هو موقف النفيلهم يعني تقوم على اساس نفي + +85 +00:07:21,450 --> 00:07:26,790 +الدين اقصاء الدين عزل الدين نفي اقصاء عزل حصر حصر + +86 +00:07:26,790 --> 00:07:30,430 +هذا الدين انه محصور في داخل هذه الأماكن اللي + +87 +00:07:30,430 --> 00:07:34,750 +ذكرناها ولا علاقة له بالحياة وما يتعلق بيها + +88 +00:07:34,750 --> 00:07:38,450 +السياسية والاقتصادية والاجتماعية وحتى الخلقية زي + +89 +00:07:38,450 --> 00:07:42,230 +ما هنشوف بعد قليلفي موقف أو علاقة العلمانية + +90 +00:07:42,230 --> 00:07:46,410 +بالأخلاق كمان حتى في الأخلاق مش كل الأخلاق المسموح + +91 +00:07:46,410 --> 00:07:50,550 +فيها في هذا الاتجاه و هذا المجال وإن سمح عليها + +92 +00:07:50,550 --> 00:07:57,450 +فبالحرية الفردية أو الشخصية لا على أن تكون طابع + +93 +00:07:57,450 --> 00:08:02,450 +عام في المجتمع إذا الخلاصة اللي بنعيد و بنزيد فيها + +94 +00:08:02,450 --> 00:08:08,240 +و بنكررها و بنأكد عليهاهي أن اللادينية هي أقرب + +95 +00:08:08,240 --> 00:08:14,440 +ترجمة لsecularism من كلمات العلمانية وإنما + +96 +00:08:14,440 --> 00:08:19,660 +استخدموها يعني استخدامهم لا يدل على خبث مقصود طب + +97 +00:08:19,660 --> 00:08:26,530 +نتقل الآن إلى العلاقة الأخرىعلاقة العلمانية بالعلم + +98 +00:08:26,530 --> 00:08:30,070 +علاقة العلمانية بالعلم علاقة العلم بالعلم علاقة + +99 +00:08:30,070 --> 00:08:40,530 +العلم بالعلم علاقة العلم + +100 +00:08:40,530 --> 00:08:49,690 +بالعلمفلم نجد صلة ولا علاقة ولا رابط بين العلمانية + +101 +00:08:49,690 --> 00:08:54,530 +ولا حتى العلمانية اللي سموها والعلم ولا علاقة لها + +102 +00:08:54,530 --> 00:08:57,390 +ولا تتحدث عن العلم ولا هي مختصة بشؤون العلم ولا + +103 +00:08:57,390 --> 00:09:02,430 +يوجد نظر علمية ولا شيء لا في اللغة ولا في الترجمات + +104 +00:09:02,430 --> 00:09:06,470 +المختلفة في المعاجم الغربية المختلفة ولكن + +105 +00:09:06,470 --> 00:09:09,070 +العلمانيين + +106 +00:09:09,740 --> 00:09:13,760 +اللي احنا بنصفهم بالعلمانيين أو العلمانيين يعني + +107 +00:09:13,760 --> 00:09:18,600 +على الخلاف دائما بنذكر هذه وهذه بيحاولوا يجهدوا + +108 +00:09:18,600 --> 00:09:22,340 +أنفسهم في إيجاد صلة بين هذين اللفظة لا يا عم احنا + +109 +00:09:22,340 --> 00:09:26,200 +علميين و اتجاه علمي و مش زي ما انتوا بتفكروا و + +110 +00:09:26,200 --> 00:09:29,380 +بتقولوا احنا ضد الدين احنا مش ضد الدين احنا نطرح + +111 +00:09:29,380 --> 00:09:33,180 +وجهة نظر علميةيعني ممكن أن تقبلها او لا تقبلها دي + +112 +00:09:33,180 --> 00:09:38,740 +وجهة نظر يعني ناسنا معارضين للدين او محاربين للدين + +113 +00:09:38,740 --> 00:09:43,040 +هكذا يسويقوا أنفسهم وبيطرحوا أنفسهم وبيحاولوا + +114 +00:09:43,040 --> 00:09:50,900 +يلصقوا وينسبوا أنفسهم إلى العلم وطبعا + +115 +00:09:50,900 --> 00:09:58,300 +بالبحث الموضوعي والاطلاع على إيه المعنيينليه + +116 +00:09:58,300 --> 00:10:02,080 +العلمانية او العلمانية و العلمية بالاصل اذا كانوا + +117 +00:10:02,080 --> 00:10:06,720 +علميين انا اقوله العلمية و ليس العلمانية حتى كمان + +118 +00:10:06,720 --> 00:10:11,260 +بالكثر ولا العلمانية فما المقصود بالعلمانية كما + +119 +00:10:11,260 --> 00:10:15,060 +رأيناها قبل قليل من مقارنة بينها و بين العلمية + +120 +00:10:15,060 --> 00:10:20,740 +التي يدعونها ان هم هم يعني علميين و ليسوا يعني لا + +121 +00:10:20,740 --> 00:10:26,190 +دينيينفي عنده يعني فارقين واضحين وظاهرين يعني + +122 +00:10:26,190 --> 00:10:30,510 +الفرق الأول ان العلمانية كما رأيناها قبل قليل + +123 +00:10:30,510 --> 00:10:38,490 +مالها؟ تفضلي يعني + +124 +00:10:38,490 --> 00:10:41,350 +هذا ملخص اللي بتكرر جاعد معانا في التعريف عشان + +125 +00:10:41,350 --> 00:10:46,230 +بدنا نقارن بين و بين العلمية وبالتالي العلمية ماذا + +126 +00:10:46,230 --> 00:10:48,110 +تعني؟ اتفضلي + +127 +00:10:53,160 --> 00:10:58,180 +بارك الله فيك كلمة علمية نسبة إلى العلم هذه علمية + +128 +00:10:58,180 --> 00:11:02,580 +مش يقال علمانية ولا علمانية والوجه النظر العلمية + +129 +00:11:02,580 --> 00:11:06,140 +والمنهج العلمي هذا يعني بيحتكم إلى العلم في ضوء + +130 +00:11:06,140 --> 00:11:10,580 +الملاحظة والتجربة والاستقراء وغيره هذه يعني أدوات + +131 +00:11:10,580 --> 00:11:15,180 +ووسائل العلم الذي يقوم عليه أو التي يقوم عليها + +132 +00:11:15,180 --> 00:11:23,160 +العلم فارق آخر أن نجد العلمانية ما لهعن أن يكون أي + +133 +00:11:23,160 --> 00:11:26,480 +مصدر أو أن يكون مصدر للتشريعة المختلف في الحكم + +134 +00:11:26,480 --> 00:11:31,920 +والسياسة والدولة والحياة كل لكن العلمية تتكلم على + +135 +00:11:31,920 --> 00:11:36,580 +أيه يا أخوات تتحدث عن هو اتجاه اللي يحاول معرفة + +136 +00:11:36,580 --> 00:11:41,900 +القوانين القوانين القوانين الطبيعية بدرس قوانين + +137 +00:11:41,900 --> 00:11:45,840 +الطبيعية هل العلمانية اللي اتعرفنا عليها بمعناها + +138 +00:11:45,840 --> 00:11:49,260 +الأصلي والأساسي ال secularism هل هو اتجاه علمي + +139 +00:11:49,260 --> 00:11:52,990 +بيدرس قوانين الطبيعةهذا ليس علاقة، هو اتجاه لا + +140 +00:11:52,990 --> 00:11:55,750 +ديني بيعزل الدين، بيقصد الدين، بيفصل الدين، لا + +141 +00:11:55,750 --> 00:11:59,350 +ديني وهكذا هذه المعاني اللي احنا اتطلعنا عليها + +142 +00:11:59,350 --> 00:12:07,860 +وليس هو الاتجاه العلمي كما يدّعونو الرجوع قليلا + +143 +00:12:07,860 --> 00:12:12,700 +إلى ما كان عليه المسلمون في أثناء الحضارة + +144 +00:12:12,700 --> 00:12:18,600 +الإسلامية و في عز المسلمين و الحكم الإسلامي و + +145 +00:12:18,600 --> 00:12:24,720 +الخلافة الإسلامية المتتابعةقرون طويلة قبل أن تسقط + +146 +00:12:24,720 --> 00:12:30,640 +في هذا العصر الحديث والقرن الحالي وبالمناسبة كان + +147 +00:12:30,640 --> 00:12:35,760 +بالامس ذكرة + +148 +00:12:35,760 --> 00:12:40,860 +سقوط الخلافة العثمانية الإسلامية الأخيرة تلاتة + +149 +00:12:40,860 --> 00:12:42,860 +تلاتة بالامس + +150 +00:12:46,170 --> 00:12:50,870 +فبالرجوع إلى كما قلنا ما كان عليه المسلمون في + +151 +00:12:50,870 --> 00:12:58,010 +أثناء حضارتهم لنجد هذا الصراع اللذي كان بين + +152 +00:12:58,010 --> 00:13:04,190 +الكنيسة ورجال الكنيسة من جهة وبين العلم والعلماء + +153 +00:13:04,190 --> 00:13:09,740 +من جهة أخرى كان في تصادم واضح هو اللي سببردت الفعل + +154 +00:13:09,740 --> 00:13:14,220 +بالعلمانية لما وجدوا أن رجال الكنيسة والكنيسة + +155 +00:13:14,220 --> 00:13:17,220 +ونصوص الكنيسة تصادم العلم والحقائق العلمية + +156 +00:13:17,220 --> 00:13:20,880 +والنظريات العلمية وتقف ضدها وتواجهها وتحاكم + +157 +00:13:20,880 --> 00:13:25,660 +أصحابها وتعتقلهم وتلاحقهم قالوا أي دين هذا؟ أي دين + +158 +00:13:25,660 --> 00:13:30,280 +هذا الذي يعرض العلم وكذا؟ فكفروا بهذا الدين + +159 +00:13:31,910 --> 00:13:36,170 +وانقلبوا عليه وقالوا ونادوا بهذا الاتجاه الذي يفصل + +160 +00:13:36,170 --> 00:13:40,410 +الدين عن الحياة وشؤونا لكن في التاريخ الإسلامي لم + +161 +00:13:40,410 --> 00:13:44,970 +نشهد هذا الصراع ولا هذا الفصام ولا هذا الفصال + +162 +00:13:44,970 --> 00:13:49,750 +النكد اللى موجود حاليا واتأثر به المسلمون ونقلوه + +163 +00:13:49,750 --> 00:13:55,010 +كما سنرى في أسباب انتشار العلمانية في العالم + +164 +00:13:55,010 --> 00:13:55,490 +الإسلامي + +165 +00:14:00,440 --> 00:14:04,180 +إذا يا أخوات لما احنا نقول انه في تاريخنا الطويل + +166 +00:14:04,180 --> 00:14:08,260 +وحضارتنا الإسلامية مافيش هذا التصادم الذي حدث عند + +167 +00:14:08,260 --> 00:14:14,920 +الغرب، إذا يعني لا مبرر في المناداء أو للمناداب + +168 +00:14:14,920 --> 00:14:20,140 +بتطبيق العلمانية في عالمنا الإسلام إذا كان الغرب + +169 +00:14:20,140 --> 00:14:25,140 +محقا وله حق وانا مع هذا الحق إذا كان الغرب محق في + +170 +00:14:25,140 --> 00:14:29,060 +أن يكفر بالدين الذي وقف ضد العلم لأنه محرف أصلا + +171 +00:14:29,060 --> 00:14:32,210 +ليس بدينإن الدين عند الله الإسلام والدين واحد + +172 +00:14:32,210 --> 00:14:35,670 +والعقيدة واحدة في أصلها أما هذه العقيدة اللي + +173 +00:14:35,670 --> 00:14:39,810 +هنتعرف عليها بعد قليل في أسباب نشأة العلمانية في + +174 +00:14:39,810 --> 00:14:44,010 +الغرب سببها التحريف الذي قام به رجال الدين + +175 +00:14:44,010 --> 00:14:49,090 +والكنيسة لهذا الدين ويعني أظهر كأن الدين ضد العلم + +176 +00:14:49,090 --> 00:14:52,390 +وضد الحقائق العلمية فالعلماء ما عجبوه مش هذا الأمر + +177 +00:14:52,390 --> 00:14:55,210 +قالوا أي دين هذا الذي يقف ضد العلم هذا ليس بدين + +178 +00:14:55,740 --> 00:14:59,620 +فكفروا بهذا الدين، إذا كان لهم مبرر أن يقصوا + +179 +00:14:59,620 --> 00:15:03,060 +ويعزلوا الدين في واقعهم، لكن نحن كمسلمين هل لنا + +180 +00:15:03,060 --> 00:15:07,240 +ذلك المبرر؟ هل ديننا ونصوص الدينية عندنا ورجال + +181 +00:15:07,240 --> 00:15:10,420 +العلم عندنا؟ مش رجال الدين، مافيش رجال الدين عندنا + +182 +00:15:17,010 --> 00:15:23,810 +العلماء في أهل العلم يعني أهل العلم يعني أهل العلم + +183 +00:15:23,810 --> 00:15:24,110 +يعني أهل العلم يعني أهل العلم يعني أهل العلم يعني + +184 +00:15:24,110 --> 00:15:31,370 +أهل العلم يعني أهل العلم + +185 +00:15:32,530 --> 00:15:37,050 +فلم نجد لا في نصوصنا الشرعية المحفوظة بحفظ الله + +186 +00:15:37,050 --> 00:15:43,250 +تعالى لها ولا في عند أهل العلم من يصادم العلم أو + +187 +00:15:43,250 --> 00:15:46,730 +ما يصادم العلم ويقف ضده بل نجد العكس تماما نجد + +188 +00:15:46,730 --> 00:15:52,150 +التشجيع والتحفيز والتحريض على العلم والتحصيل + +189 +00:15:52,150 --> 00:15:55,610 +العلمي ولا مجال لذكر الأيات الكثيرة والأحاديث التي + +190 +00:15:55,610 --> 00:15:58,290 +تحض وتحث المسلمين على العلم + +191 +00:16:01,670 --> 00:16:07,150 +الموضوع الثالث الذي له علاقة بالعلمانية ونريد أن + +192 +00:16:07,150 --> 00:16:14,850 +نتعرف على علاقة وصلة العلمانية به هو الأخلاقوقد + +193 +00:16:14,850 --> 00:16:20,210 +لمحنا قبل قليل يعني في الحديث عنه لكن هنا سؤال + +194 +00:16:20,210 --> 00:16:24,690 +مطروح يعني قد يطرح البعض أو يسأل أو يستفسر ومن حقه + +195 +00:16:24,690 --> 00:16:28,970 +يعني العلمانية كلها ده يعني هي ضد الأخلاق او لا + +196 +00:16:28,970 --> 00:16:33,050 +تسمح بالأخلاق او تمنع الأخلاق او لا تمدح الأخلاق + +197 +00:16:33,050 --> 00:16:37,530 +يعني العالم الغربي للدرجاتي ده يقولوا يعني ضد + +198 +00:16:37,530 --> 00:16:43,690 +الأخلاق والقيم وال .. اه سؤاليعني وجيه ومطروح هل + +199 +00:16:43,690 --> 00:16:49,030 +تسمح العلمانية بالأخلاق والفضائل ولا لا تسمح فضل؟ + +200 +00:16:54,270 --> 00:16:58,190 +في قضاء الأخلاق العامة، الفضائع العامة، المبادئ + +201 +00:16:58,190 --> 00:17:01,790 +العامة، ماحدش يتجرى أن يقول أنا ضد، لا أنا ضد + +202 +00:17:01,790 --> 00:17:04,690 +الأمانة ولا الصدق ولا الإخلاص ولا إتقان العمل، بل + +203 +00:17:04,690 --> 00:17:08,610 +هم يتقنون أعمالهم وهم صادقون في كثير من القضايا، + +204 +00:17:08,610 --> 00:17:13,370 +في مجمل المبادئ والأخلاق العامة والمثل والعليا، + +205 +00:17:13,370 --> 00:17:18,340 +يتفق الجميع أن أشياء فطرية وإنسانيةلا يمكن أن نغفل + +206 +00:17:18,340 --> 00:17:25,000 +الواقع الموجود أننا والغرب والشرق وكل من متقدم في + +207 +00:17:25,000 --> 00:17:30,320 +الحياة المدنية اليوم يعني إنما الأمم الأخلاق وما + +208 +00:17:30,320 --> 00:17:35,260 +بقيت في أخلاقفي أخلاق نوعية أو نوع عامة يعني وجاء + +209 +00:17:35,260 --> 00:17:37,720 +النبي صلى الله عليه وسلم ليتمم مكارمة الأخلاق لأنه + +210 +00:17:37,720 --> 00:17:40,980 +في أخلاق والناس تحب الأخلاق وتمدح الأخلاق ما أحد + +211 +00:17:40,980 --> 00:17:43,800 +يمدح الكاذب ولا المنافق ولا بيمدح الكذاب ولا + +212 +00:17:43,800 --> 00:17:49,070 +الصراق في أي دين يعني صحيح أو محرفأو حتى مبدأ أو + +213 +00:17:49,070 --> 00:17:52,150 +مثل لا يمكن أن نلاحظ طب ها إيش اللي بيحصل أو إيش + +214 +00:17:52,150 --> 00:17:56,630 +هذه العلاقة؟ بنلاحظ في موضوعات محددة معينة هنا + +215 +00:17:56,630 --> 00:18:03,370 +العلمانية تسمح بما يتعارض مع بعض الأخلاق في بعض + +216 +00:18:03,370 --> 00:18:07,350 +النقاط وإحنا هنركز على نقطتين أو موضوعين هنشوف + +217 +00:18:07,350 --> 00:18:10,490 +فيها الفرق بين العلمانية والاتجاه العلماني + +218 +00:18:10,490 --> 00:18:16,400 +والاتجاه الديني أو الإسلامي فيها موضوع الأولهو + +219 +00:18:16,400 --> 00:18:21,080 +مجال العلاقة بين الراجل والمرأة تشوف هذه الأخلاق + +220 +00:18:21,080 --> 00:18:25,800 +التي يجب أن تقوم بين الراجل والمرأة والأداب هل هي + +221 +00:18:25,800 --> 00:18:28,780 +نفس الأداب اللي موجودة عندنا في ديننا ولا الآن + +222 +00:18:28,780 --> 00:18:35,690 +هنرا اختلاف ملحوظ وواضح الأمر الثانيهي ربط الأخلاق + +223 +00:18:35,690 --> 00:18:39,070 +بالدين هل العلمانية بتربط هذه الأخلاق التي هم + +224 +00:18:39,070 --> 00:18:42,990 +عليها أو يستيرون عليها بالدين مصدرها أو ينبوعها أو + +225 +00:18:42,990 --> 00:18:48,150 +أصلها أو أساسها هو الدين ولا ماذا يعني أو كيف وجهة + +226 +00:18:48,150 --> 00:18:51,730 +نظرهم في هذه الأخلاق نبدأ بالموضوع الأول مجال + +227 +00:18:51,730 --> 00:18:56,270 +العلاقة بين الرجل والمرء فبمقارنة بسيطة بين + +228 +00:18:56,270 --> 00:19:01,520 +الإسلاموالعلمانية في هذا المجال العلاقة بين الرجل + +229 +00:19:01,520 --> 00:19:08,860 +والمرأة هناك في الإسلام يا أخوات في إيش؟ في أحكام؟ + +230 +00:19:08,860 --> 00:19:14,060 +في تشريعات؟ مالا؟ تطبط هذه العلاقة تنظم هذه + +231 +00:19:14,060 --> 00:19:19,420 +العلاقة فكيف نظمها؟ يعني ما هي علاقة الرجل بالمرأة + +232 +00:19:19,420 --> 00:19:22,360 +في الإسلام؟ طبعا المرأة الغريبة عنه يعني مش أمه أو + +233 +00:19:22,360 --> 00:19:27,670 +أبوه كذا ده ليس الحديث عنهمع أي امرأة تحلله ان + +234 +00:19:27,670 --> 00:19:31,790 +يتزوجه او اي امرأة غريبة عنه يعني ليست من ارحمه + +235 +00:19:31,790 --> 00:19:33,330 +ولا من المحرمات عليه + +236 +00:19:38,010 --> 00:19:44,390 +الزواج والزواج فقط الطريق المشروع الشرعي الوحيد + +237 +00:19:44,390 --> 00:19:49,130 +للعلاقة المشروعة بين الرجل والمرأة هي طريق الزواج + +238 +00:19:49,130 --> 00:19:53,370 +أن يأتي من الباب الشرعي ليخطبها ويتزوجها فتصبح + +239 +00:19:53,370 --> 00:19:58,430 +حلالا له وزوجة له ويقيم معاها العلاقة المعروفة + +240 +00:19:58,430 --> 00:20:02,410 +الطبيعية بين الرجل والمرأة او الزوج وزوجته الآن + +241 +00:20:02,410 --> 00:20:07,060 +أصبح مش راجل ومرأة أصبح زوج وزوجةمش اي راجل و + +242 +00:20:07,060 --> 00:20:11,120 +امرأة يعملوا اي علاقة، لأ في زوج و زوجة، الان + +243 +00:20:11,120 --> 00:20:16,020 +أصبحوا هذا الطريق الشرعي و الوحيد و حرم في مقابل + +244 +00:20:16,020 --> 00:20:22,220 +ذلك ايش كل؟ + +245 +00:20:22,220 --> 00:20:25,220 +فجعل ايش؟ الزنا؟ نعم + +246 +00:20:30,150 --> 00:20:33,690 +نعم، التبرج والصفور وخلوة الرجل بالمرأة الأجنبية + +247 +00:20:33,690 --> 00:20:38,250 +والنظر إليها بشهوة، هذه علاقة رجل بالمرأة، هل يجوز + +248 +00:20:38,250 --> 00:20:42,550 +له أن يفعل بها الحرام إن لم تكن زوجته أن يقيمها + +249 +00:20:42,550 --> 00:20:47,630 +علاقة جنسية إن لم تكن زوجته؟ هل يجوز للمرأة في + +250 +00:20:47,630 --> 00:20:51,060 +المقابل أن تظهر أمام الرجل؟ هذه العلاقةيشوفها + +251 +00:20:51,060 --> 00:20:56,520 +متبرجة سافرة يخلو بيها وحده في مكان مغلق مافيش حد + +252 +00:20:56,520 --> 00:21:00,580 +مابقي طبعا حسب الضوابط والأحكام الشرعية يعني واضحة + +253 +00:21:00,580 --> 00:21:05,200 +النصوص يعني لا تحتاج منا إلى توضيح لإن كنا نحفظ + +254 +00:21:05,200 --> 00:21:13,220 +هذه النصوص لا يخلون أحدكم بامرأة إلا مع ذي محرم + +255 +00:21:13,220 --> 00:21:17,400 +يكون أبوها أخوها زوجها كذاوهذا الكلام يعني حتى في + +256 +00:21:17,400 --> 00:21:20,380 +الضرورات لما بيكون في ضرورة برضه يكون أبوها معاها + +257 +00:21:20,380 --> 00:21:24,540 +أخوها كده إلا في الحالات الحرجة جدا كإجراء عملية + +258 +00:21:24,540 --> 00:21:27,740 +جراحية فيها كده بالنوع أي حد لكن في فحص طبي في + +259 +00:21:27,740 --> 00:21:31,680 +ذهاب إلى مكان و مكان واحد ولا وحده مافعش أنا أروح + +260 +00:21:31,680 --> 00:21:37,120 +إلى طبيب خاص للكشف و الفحص كامرأةمهما كان هذا + +261 +00:21:37,120 --> 00:21:43,260 +الطبيب دينه وخلقه وعلمه ويغلق علي أنا وهو باب واحد + +262 +00:21:43,260 --> 00:21:47,420 +ونحن نكون حتى لو كان هذا ضروري وهي علاج لأنه ليس + +263 +00:21:47,420 --> 00:21:51,640 +ضرورة عملية ممنوعة أن يدخل أحد معاه فيها إلا إذا + +264 +00:21:51,640 --> 00:21:55,620 +قضى الأمر ذلك حسب الضرورات الشرعية والطبية أما + +265 +00:21:55,620 --> 00:22:00,240 +مدام مسموح إلي مدخل أختي معايا أمي زوجي ابني أخويا + +266 +00:22:00,240 --> 00:22:06,450 +أختي لهذا المحذور الشرعي لأنه في تحريم لهذه الخلقو + +267 +00:22:06,450 --> 00:22:11,790 +من هذا الباب يا اخوات اللي لا يجوز ان تعمل المسلمة + +268 +00:22:11,790 --> 00:22:15,010 +.. المرأة المسلمة بنت ان كانت او امرأة او كده + +269 +00:22:15,010 --> 00:22:19,570 +سكورتيرة في مكتب خاص لرجل فعشان تكون سكورتيرة + +270 +00:22:19,570 --> 00:22:22,930 +لواحدلأن هو وياها لحاله، هذا محدود شر، هذا مافيش + +271 +00:22:22,930 --> 00:22:25,950 +فيها مجاملة و لا فيها طب علشان طب عشان يا أستاذ و + +272 +00:22:25,950 --> 00:22:32,190 +لا طب ساهلها بحبحها، ده مافيش فيها القضية مجاملة و + +273 +00:22:32,190 --> 00:22:37,270 +رأي شخصي و تيسير .. ده حكم شر أيه، لا جهادة مع + +274 +00:22:37,270 --> 00:22:41,750 +النص، نص لا يخلو أحدهم بامرأة حتى لو كان بيحفظها + +275 +00:22:41,750 --> 00:22:45,440 +القرآنمش بيشتغلوا وياه أربعة و عشرين ساعة أمامه + +276 +00:22:45,440 --> 00:22:49,220 +إلا ما خلى رجلهم بامرأة إلا كان الشيطان ثالثهم + +277 +00:22:49,220 --> 00:22:52,600 +طبيعة البشر طبيعة الإنسان طبيعة الرجل طبيعة المرأة + +278 +00:22:52,600 --> 00:22:57,300 +وهذا الذي يعطي هذا الحكم الذي خلق المرأة والرجل + +279 +00:22:57,300 --> 00:23:01,580 +ألا يعلموا من خلقوهو اللطيف و الخبير فاللي بيعرف + +280 +00:23:01,580 --> 00:23:05,700 +فيه يعني طبيعة كل واحد من الجنسين الراجل والمرأة + +281 +00:23:05,700 --> 00:23:08,960 +هو اللي حذر هو اللي حرم هو اللي وضع هذا الحد فهو + +282 +00:23:08,960 --> 00:23:13,140 +العالم الخبير و الحكيم الخبير و هو لمصلحة الطرفين + +283 +00:23:13,140 --> 00:23:18,300 +و لمصلحة المجتمع كذلكالكلام في هذا المجال كبير و + +284 +00:23:18,300 --> 00:23:21,520 +كثير لما بدنا نخد فيه و نشوف التجاوزات اللي بتحدث + +285 +00:23:21,520 --> 00:23:25,020 +في مجتمعاتنا الإسلامية اليوم والمحاذير الشرعية في + +286 +00:23:25,020 --> 00:23:28,700 +خلوة الرجل بالمرأة في بعض الأماكن لكن في مؤسسات + +287 +00:23:28,700 --> 00:23:33,840 +عامة في أماكن في حكومة في تعليم في صحة في طقس كل + +288 +00:23:33,840 --> 00:23:38,760 +هذا يعني مسموح فيه بالضوابط الشرعية واللبس الشرعي + +289 +00:23:38,760 --> 00:23:42,980 +للمرأة اللي معروف لكن الحديث عن الخلوة في أي مكان + +290 +00:23:44,030 --> 00:23:47,430 +يعني إلا في الضرورة القصوى كما قلنا في إجراء عملية + +291 +00:23:47,430 --> 00:23:50,810 +جراحية فيها بنج و فيها كذا و لا يسمح لأحد في هذه + +292 +00:23:50,810 --> 00:23:53,810 +الحالة و ليست هي مجال لشهوة و لا إثارة و لا غير + +293 +00:23:53,810 --> 00:23:57,450 +فيما عدا ذلك الكلام هذا يعني من باب النصيحة و + +294 +00:23:57,450 --> 00:24:00,950 +الدين و يسمعون الملايين اليوم المسلمين و المسلمات + +295 +00:24:00,950 --> 00:24:04,710 +فليحذروا من الوقوف في هذا المحذور الشرعي تروح على + +296 +00:24:04,710 --> 00:24:08,830 +طبيب طبعا المقصود يعني طبيب و ليس طبيبة بدوا يكون + +297 +00:24:08,830 --> 00:24:13,930 +حد معاه كي يدخل الغرفة عند الكاشفواضح يا أخوات إن + +298 +00:24:13,930 --> 00:24:17,970 +شاء الله يكون يعني هذه النصيحة قد وصلت هذا الكلام + +299 +00:24:17,970 --> 00:24:20,950 +التفصيل اللي احنا ذكرناه في هذا المجال علاقة الرجل + +300 +00:24:20,950 --> 00:24:27,570 +بالمرأة والضوابط الشرعية الموجودة و المنصوص عليه + +301 +00:24:28,500 --> 00:24:31,540 +يقابلها في العلمانية؟ هل هذا الخلام اللي قلناه + +302 +00:24:31,540 --> 00:24:35,500 +يمكن خمس دقائق ولا عشر دقائق ويمكن لو بدنا نصفظ في + +303 +00:24:35,500 --> 00:24:38,840 +الحديث كان أكثر منه واحنا بنوضح في جزئية ومسألة + +304 +00:24:38,840 --> 00:24:42,120 +واحدة؟ هل ده كله موجود أمام الغرب لو الواحد من + +305 +00:24:42,120 --> 00:24:45,380 +الغرب الآن العلمان يسمعني وانا أتحدث عنه؟ ماذا + +306 +00:24:45,380 --> 00:24:48,600 +سيكون موقفه؟ هل سيصفق ليه ويمدحني ويقول برا وعليك + +307 +00:24:48,600 --> 00:24:53,260 +وشاطر واحنا عندنا برضه زي معانكم؟ ولا العكس تماما؟ + +308 +00:24:54,230 --> 00:24:58,910 +بنشوفها عكس تمام، بس ده احمد اه لا ضوابط ولا كده + +309 +00:24:58,910 --> 00:25:03,110 +ولا يعني في هذا المجال اللي احنا تحدثنا عنه في + +310 +00:25:03,110 --> 00:25:06,930 +علاقة الراجل بالمرأة سواء بالخلوة او بالمظاهر + +311 +00:25:06,930 --> 00:25:10,370 +اللتي نراها من التبرج والصفور والنظر بشهوة + +312 +00:25:10,370 --> 00:25:13,750 +والعلاقات المحرمة و هذا boyfriend و هذا boyfriend + +313 +00:25:13,750 --> 00:25:20,070 +ده ولا girlfriend مش بيسموهاهل عندهم هذا موجود في + +314 +00:25:20,070 --> 00:25:23,810 +الغرب؟ هل لدينا ال boy و ال boyة؟ لا ليس لدينا ال + +315 +00:25:23,810 --> 00:25:29,130 +boyة السودة و البنية مابنعرفش غير احنا و هذه + +316 +00:25:29,130 --> 00:25:33,310 +الأمور كلها موجودة في العالم الغربي و الأجنبي و + +317 +00:25:33,310 --> 00:25:38,670 +العلماني لأن العلمانية تفصل الدين هذه قيم دينية + +318 +00:25:38,670 --> 00:25:43,910 +شرعية اخلاق دينية شرعية مستمدة من الدين هم ليعرفون + +319 +00:25:43,910 --> 00:25:49,870 +هذه الضوابط و عندهم يعني ال freedomيعني to freedom + +320 +00:25:49,870 --> 00:25:56,750 +مطلقة يعني مافيش تحديد ولا حدود لأ عندهم الحرية + +321 +00:25:56,750 --> 00:26:01,350 +المطلقة في ان يفعل الإنسان ما يشاء رجل كان او + +322 +00:26:01,350 --> 00:26:07,930 +امرأة و عندهم ترخيص لدور الزنا يعني و ال .. مايعرف + +323 +00:26:07,930 --> 00:26:12,190 +بالدعارة الآن في العالم الغربي و العلماني و كذلك + +324 +00:26:12,190 --> 00:26:17,380 +هذه ال .. هذا ال ..الاطلاق لهذه الشهوات وهذه + +325 +00:26:17,380 --> 00:26:22,040 +الحرية المطلقة يعاني اليوم الغرب منها معاناة شديدة + +326 +00:26:22,040 --> 00:26:27,740 +من نتائجها المدمرة على مجتمعاته اللي أدت إلى أمراض + +327 +00:26:27,740 --> 00:26:31,420 +وأوبئة كبيرة يعني على رأسها ال aids أو ال eyes أو + +328 +00:26:31,420 --> 00:26:36,760 +ال aides في أكثر من يعني لفظ حسب الترجمةاللي مهلك + +329 +00:26:36,760 --> 00:26:42,080 +مش مئات مش ألاف حالات بالملايين من جراء هذا + +330 +00:26:42,080 --> 00:26:47,860 +الإطلاق العنان لهذه الشهوات المحرمة وصدق الله حين + +331 +00:26:47,860 --> 00:26:52,060 +يقول وَلَا تَقْرَبُ الذِّنَاءِ إِنَّهُ كَانَ + +332 +00:26:52,060 --> 00:26:59,740 +فَاحِشَةً وَسَاءَ سَبِيلًاسبيله سيء وساء سبيله + +333 +00:26:59,740 --> 00:27:05,420 +طريقه سيء مدمر مهلك وقدعن الغرب من هذه النتائج + +334 +00:27:05,420 --> 00:27:11,420 +الوخيمة من جراء هذا الإطلاق لهذه الشهوات الإطلاق + +335 +00:27:11,420 --> 00:27:17,920 +العنان لها وسنأخذ في بعض الموضوعات ذات الشأن في + +336 +00:27:17,920 --> 00:27:22,970 +الحديث عن المرأة في رابع وسائل التغريبوفي قضايا + +337 +00:27:22,970 --> 00:27:25,650 +المرأة في قضية من التمن قضايا اللي هندرسها + +338 +00:27:25,650 --> 00:27:32,610 +الإختلاط بين الجنسين سنرى يعني إحصائيات مهولة من + +339 +00:27:32,610 --> 00:27:36,330 +جراء الإختلاط بين الجنسين في المدارس التعليمية + +340 +00:27:36,330 --> 00:27:41,550 +لدرجة أن جورج بوشل إبن رئيس ولايات المتحدة + +341 +00:27:41,550 --> 00:27:48,930 +الأمريكية يعني أعطى جائزة وحوافز لمن يدعو إلى + +342 +00:27:48,930 --> 00:27:53,120 +الفصل بين الجنسين في المدارسإيش صاروا المتدينين؟ + +343 +00:27:53,120 --> 00:27:57,260 +كانوا أسلموا ولا يشدّعوا؟ لما يُعرض عليه من تقارير + +344 +00:27:57,260 --> 00:28:04,240 +المخاطر والخطورة اللي بتسببها الإختلاط من حمل بين + +345 +00:28:04,240 --> 00:28:08,120 +طالبات المراهقات في المدارس الكذا وإجهاد ومشكلة + +346 +00:28:08,120 --> 00:28:11,020 +إجتماعية كبرى يعني هم الأن بعانوا من هذا الكلام + +347 +00:28:11,020 --> 00:28:14,240 +رغم أنهم مش قادرين يمنعوه لكن بيشجعوا على الفصل + +348 +00:28:14,700 --> 00:28:17,860 +مدارس اللي بتدعو إلى الفصل إلها جوائز كده وهم + +349 +00:28:17,860 --> 00:28:20,760 +مذكور ومنصوص عليه وفي وثائق وفي أقوال و تصريحات + +350 +00:28:20,760 --> 00:28:24,740 +يعني هم بدوا يعودوا إلى مروج بدأوا يعودوا في بعض + +351 +00:28:24,740 --> 00:28:28,660 +القضايا البسيطة لكن مجتمع قائم من عشرات السنين على + +352 +00:28:28,660 --> 00:28:34,700 +ذلك مش سهل بجرد قلم انه يمتنع عن ذلك وهذا يعني ما + +353 +00:28:34,700 --> 00:28:38,940 +يميز الإسلام كمنهج عن غيره من المنهج الأرضي انه + +354 +00:28:38,940 --> 00:28:43,120 +صاحب العقيدة صاحب المبادئ عقيدته هي اللتي تدعو لكن + +355 +00:28:43,120 --> 00:28:46,850 +هذا مش عقيدتهمش معقول يرد على رئيس و لا على زعيم و + +356 +00:28:46,850 --> 00:28:49,630 +لا يترك كل ما عليه يعني هو مجتمع بعتبر حاله + +357 +00:28:49,630 --> 00:28:53,830 +ديمقراطي و حر و صاحب وجهة نظر و حرية الكاملة + +358 +00:28:53,830 --> 00:28:58,930 +فبيردش على مجرد واحد او حتى لو كان رئيسا او زعيما + +359 +00:28:58,930 --> 00:29:03,270 +ممكن يمشي على رأي و ممكن مايمشيش لكن المسلم فيه + +360 +00:29:03,270 --> 00:29:08,090 +الرب هو المشرع فيه رسول هو اللي برضه مشرع فهو + +361 +00:29:08,090 --> 00:29:14,970 +مأمور بالطاعة و كما رأينا أيضا في ال ..المقارنة + +362 +00:29:14,970 --> 00:29:18,590 +بين خصائص المجتمع المسلم وخصائص المجتمع الجاهل + +363 +00:29:18,590 --> 00:29:22,190 +شوفنا كيف المجتمع المسلم من خصائصه اللي هو + +364 +00:29:22,190 --> 00:29:29,460 +الانضباطالسلوك بالضوابط الربانية وشوفنا المرة مجرد + +365 +00:29:29,460 --> 00:29:32,840 +ما نزلت آيات الحجاب على طول بادرة مش لإن واحد اللي + +366 +00:29:32,840 --> 00:29:35,760 +جالها أو واحد نصحها لإنه ربنا اللي شرعه على طول + +367 +00:29:35,760 --> 00:29:39,100 +فخي عنده إيمان بالله دعاه المسلمين اللي كانوا + +368 +00:29:39,100 --> 00:29:42,580 +مدمنين خمر ومش قادرين يبطلوا وكذا step by step + +369 +00:29:42,580 --> 00:29:47,720 +وخطوة خطوة وبالتدرج وكذا لغايةما إجت الأيات اللي + +370 +00:29:47,720 --> 00:29:51,480 +تحسم القضية وإنما الخمر ولا ميصر ولا أنصاب ولا + +371 +00:29:51,480 --> 00:29:54,680 +أسلام ورجلهم من عمل الشيطان فاجتنبوا وفهل أنتم + +372 +00:29:54,680 --> 00:29:59,260 +منتهون قالوا انتهينا ودلجوا كل ما كان عندهم من + +373 +00:29:59,260 --> 00:30:04,500 +الأوعية والأنية التزاما وانضباطا بأمر الله هذا + +374 +00:30:04,500 --> 00:30:08,500 +الفرق بيننا كمسلمين لما بنلتزم بالأمر وبين الغرب + +375 +00:30:08,500 --> 00:30:11,960 +لو بدوا يلتزم هو حر يلتزم أو لا يلتزم مافيش حدا + +376 +00:30:11,960 --> 00:30:13,240 +بيلزم + +377 +00:30:15,280 --> 00:30:20,780 +الموضوع الثاني أو الموضوع الثاني من المواضع أو من + +378 +00:30:20,780 --> 00:30:26,440 +الموضعين اللي بيختلف فيها الإسلام أو تختلف فيها + +379 +00:30:26,440 --> 00:30:30,640 +العلمانية عن الإسلام اللي هي ربط الأخلاق بالدين + +380 +00:30:30,640 --> 00:30:38,140 +ممكن لما احنا يعني قليلا عن هذا الموضوع قبل قليل + +381 +00:30:38,140 --> 00:30:45,820 +فالعلمانية من من تأخذ أخلاقة اللي قد تسمح بهاولا + +382 +00:30:45,820 --> 00:30:50,720 +تعارضها او ترحب بها اخلاق والفضائل من اين بتاخدها؟ + +383 +00:30:50,720 --> 00:30:56,260 +هل بتاخدها من الدين؟ هل الدين هو الانبوع والمصدر + +384 +00:30:56,260 --> 00:31:02,200 +والمورد؟ لأ هائش المورد والمنبع والمصدر اللي بتاخد + +385 +00:31:02,200 --> 00:31:06,560 +منه و بتستقي منها قيمها و اخلاقها انت تقيم ذلك على + +386 +00:31:06,560 --> 00:31:09,560 +اساس philosophy او عمل براقميت او مصلحة او نفعية + +387 +00:31:09,800 --> 00:31:17,120 +بارك الله فيك ويسيروا على القول الذي وضعه لهم و + +388 +00:31:17,120 --> 00:31:20,140 +للغرب والحضارة الغربية المستمرة بالحضارة الغربية + +389 +00:31:20,140 --> 00:31:23,980 +الفيلسوفي الإيطالي ميكيا فيلي نيكولو ميكيا فيلي + +390 +00:31:23,980 --> 00:31:30,000 +الغاية تبرر الوسيلة عشان يوصل لغاية وبدويا ممكن + +391 +00:31:30,000 --> 00:31:35,140 +يسلك اليها أي وسيلة بأي طريقة بأي وسيلة مافيش + +392 +00:31:35,140 --> 00:31:37,820 +عندهم محرم ولا مش محرم شرعية ولا مش شرعية زي ما هي + +393 +00:31:37,820 --> 00:31:44,790 +أي وسيلةاللي هو الغاية تبرر الوسيلة في كتابه + +394 +00:31:44,790 --> 00:31:49,070 +المعروف بالأمير إذن هم بيقيموا هذه الأخلاق على + +395 +00:31:49,070 --> 00:31:57,810 +أساس فلسفي أو عملي اللي هو يعني براجماتي يعني + +396 +00:31:57,810 --> 00:32:03,090 +مصلحي نفعي حسب المصالح و المنافع وهذا اتجاه الغرب + +397 +00:32:03,090 --> 00:32:06,290 +اللي براجماتيةيعني أحيانا بكتبها بالغين و أحيانا + +398 +00:32:06,290 --> 00:32:11,410 +بالجيم حسب الترجمة هي تغييب المصلحة على المبدأ + +399 +00:32:11,410 --> 00:32:14,330 +يمكن يكون صاحب مبدأ عنده مبادئ لكن لما يشوف مصلحته + +400 +00:32:14,330 --> 00:32:18,330 +في اتجاه معين بيترك مبدأه و بيروح لمين لمصلحته .. + +401 +00:32:18,330 --> 00:32:21,890 +هذا براجمات .. براجمات يعني مرن شوية يعني هو + +402 +00:32:21,890 --> 00:32:25,340 +أحيانا بيوصفه بالمرونخلّيك براجماتي يعني خلّيك مرن + +403 +00:32:25,340 --> 00:32:28,520 +ماتكونش متصلم ومتشدّت طب أه ممكن أكون و الإسلام دي + +404 +00:32:28,520 --> 00:32:32,400 +عقل المرونة لكن هل المرونة أو البراجماتية تجعل + +405 +00:32:32,400 --> 00:32:35,580 +الإنسان يترك مبادئ ويتخلى عنها عشان يشوف مصلحته + +406 +00:32:35,580 --> 00:32:42,260 +الخاصة و النفعية وكذا المؤقتة وسبق + +407 +00:32:42,260 --> 00:32:45,540 +الحديث في هذه العلاقة واحنا بنتكلم على تعريف + +408 +00:32:45,540 --> 00:32:49,480 +العلمانية في الاستلاح + +409 +00:32:50,760 --> 00:32:53,940 +واتعرفنا على المعاجم الأوروبية في الحديث عنها + +410 +00:32:53,940 --> 00:33:00,400 +وجدنا من بين التعريفات أن العلمانية نظام اجتماعي + +411 +00:33:00,400 --> 00:33:06,660 +في الأخلاقلكن مؤسس على فكرة وجوب قيام القيم + +412 +00:33:06,660 --> 00:33:12,340 +السلوكية والأخلاقية على اعتبارات الدين و لا الحياة + +413 +00:33:12,340 --> 00:33:18,180 +المعاصرة والتضامن الاجتماعي دون النظر إلى الدين + +414 +00:33:18,180 --> 00:33:21,060 +يعني احنا مابناخد أخلاقنا و قيامنا من الدين حسب + +415 +00:33:21,060 --> 00:33:25,040 +الاعتبارات الاجتماعية و المنافع و المصالحهو عالم + +416 +00:33:25,040 --> 00:33:31,720 +مصالح اليوم عالم نفعي مصلحي يتوافق ويتحد ويتوحد + +417 +00:33:31,720 --> 00:33:36,020 +على المصالح الولايات المتحدة الأمريكية مقرأت + +418 +00:33:36,020 --> 00:33:39,880 +مصلحتها في التوحد الاتحاد الأوروبي وجد مصلحته في + +419 +00:33:39,880 --> 00:33:44,850 +انه يتوحد التجارية والاقتصادية والسياسية و الاخرو + +420 +00:33:44,850 --> 00:33:49,130 +هكذا اتحاد العالم اليوم يتوحد و يبني علاقاته حسب + +421 +00:33:49,130 --> 00:33:54,150 +المصلحة والمنفعة التي تعود عليها و أيضا في معجم + +422 +00:33:54,150 --> 00:33:59,230 +إكسفورد أيضا العلمانية في تعريفاتها الرأي الذي + +423 +00:33:59,230 --> 00:34:04,990 +يقول إنه لا ينبغي أن يكون الدين أساسا للأخلاق و + +424 +00:34:04,990 --> 00:34:08,800 +التربية اللي هو ال secureism اللي تكلمنا عنهبهذا + +425 +00:34:08,800 --> 00:34:12,680 +نكون قد انتهينا من الحديث عن علاقة العلمانية + +426 +00:34:12,680 --> 00:34:20,030 +بالدين بالعلم بالأخلاقو نبدأ بداية لأن في عندى + +427 +00:34:20,030 --> 00:34:24,210 +نشأتين نشأة العلمانية في أوروبا و في نشأة + +428 +00:34:24,210 --> 00:34:28,090 +العلمانية في العالم الإسلامي نقتصر اليوم في ما + +429 +00:34:28,090 --> 00:34:31,570 +تبقى من الوقت على الحديث على نشأة العلمانية في + +430 +00:34:31,570 --> 00:34:35,530 +أوروبا و نلخصكم إياها و نختصرها في بعض الكلمات + +431 +00:34:35,530 --> 00:34:41,630 +القاتية في هذه الصفحة المعروفة فبالاطلاع على نشأة + +432 +00:34:41,630 --> 00:34:46,940 +العلمانية نجد أن لها نشأة و لا نشأتيننشأتين في + +433 +00:34:46,940 --> 00:34:52,880 +نشأة ممكن نسميها قديمة أو أولى ونشأة ثانية أو + +434 +00:34:52,880 --> 00:34:59,860 +حديثة يعني أصل وفرق فالأصل أو النشأة القديمة نشأت + +435 +00:34:59,860 --> 00:35:05,300 +منذ القدم يعني في العام تلتمية خمسة وعشرين ميلادي + +436 +00:35:05,300 --> 00:35:09,800 +يعني في القرن الرابع الميلاديفي أواء القرن الرابع + +437 +00:35:09,800 --> 00:35:17,860 +الميلادي وقصتها أن رجال الكنيسة فصلوا بين الشريعة + +438 +00:35:17,860 --> 00:35:21,600 +والعقيد رجال الدين النصراني فصلوا بين الأمرين + +439 +00:35:21,600 --> 00:35:24,700 +قالوا في حاجة اسمها الشريعة وفي حاجة اسمها عقيد + +440 +00:35:25,300 --> 00:35:29,380 +العقيدة أو الدين عندهم، الدين النصران اللي هم + +441 +00:35:29,380 --> 00:35:33,520 +يدينون فيه، هو عبارة عن عقيدة فقط، مجموعة من + +442 +00:35:33,520 --> 00:35:37,700 +العقاد، هنتعرف عليها في المحاضرة القادمة في الحديث + +443 +00:35:37,700 --> 00:35:42,830 +عن أسباب نشأة العلمانيةفالدين عندهم عقيدة طب و + +444 +00:35:42,830 --> 00:35:47,010 +الشريعة في شرائع و أحكام و قوانين قالوا لأ هذه + +445 +00:35:47,010 --> 00:35:51,990 +الشريعة اللي بتنظم حياة الناس متروكة لمين للقانون + +446 +00:35:51,990 --> 00:35:56,450 +الوضعي الروماني هو اللي بوضع التشريعات و الأحكام و + +447 +00:35:56,450 --> 00:36:03,010 +القوانين و الأنظمة و قام هؤلاء اللي هم رجال + +448 +00:36:03,010 --> 00:36:06,650 +الكنيسة و رجال الدين بهذا الفصام و هذا الفصل بين + +449 +00:36:06,650 --> 00:36:14,360 +العقيدة و الشريعة تحت قولنسبوا طبعا زورا لأننا + +450 +00:36:14,360 --> 00:36:17,420 +نعتقد أن المسيح يقول هذا الكلام إلى السيد المسيح + +451 +00:36:17,420 --> 00:36:26,000 +عليه السلام اعطوا ما لقيصر لقيصر و ما لله لله + +452 +00:36:26,000 --> 00:36:31,640 +صلحوه في محذوف كلمة لله التانية اللي لقيصر اعطوه + +453 +00:36:31,640 --> 00:36:36,600 +لقيصر و اللي لله اعطوه لله اعطوا ما لقيصر لقيصر و + +454 +00:36:36,600 --> 00:36:43,370 +اعطوا ما لله لله ايش لقيصر؟الحكم و الملك و التشريع + +455 +00:36:43,370 --> 00:36:46,870 +و الأحكام هذا الملك هو اللي يعرف مصلحتنا الملك + +456 +00:36:46,870 --> 00:36:50,790 +اللي في الدنيا يعرف مصلحتنا لكن ملك الملوك مايعرفش + +457 +00:36:50,790 --> 00:36:54,690 +مصلحتنا اللي يعلم من خلق و هو اللطيف و الخبير و + +458 +00:36:54,690 --> 00:36:58,730 +الله عليهم خبير و الله عليهم حكيم قل أنتم أعلموا + +459 +00:36:58,730 --> 00:37:02,650 +أم لا و الله يعلم و أنتم لا تعلمون ربنا اللي بيعلم + +460 +00:37:02,650 --> 00:37:06,730 +بمصلحت اللي خلقنا أعلم بنا من غيره + +461 +00:37:09,640 --> 00:37:13,940 +فأعطوا ما لقيصر من هذه القوانين والأحكام + +462 +00:37:13,940 --> 00:37:19,280 +والتشريعات وجعلوه حقا له وما لله هي العقيدة + +463 +00:37:19,280 --> 00:37:22,620 +والعبادات بس العقيدة والعبادات هذا اللي لله ربنا + +464 +00:37:22,620 --> 00:37:25,540 +مالوش دعوة ولا ايه اللي دخل فيه ومن هنا بدأ مين + +465 +00:37:26,080 --> 00:37:29,680 +الفصل بين الدين والحياة بين الدين والدولة بين + +466 +00:37:29,680 --> 00:37:32,620 +الدين والحكم بين الدين والسياسة بين الدين + +467 +00:37:32,620 --> 00:37:37,800 +والقوانين والأحكام والتشريعات وهذا هو شكل + +468 +00:37:37,800 --> 00:37:42,040 +العلمانية الحقيقة هو هذا الفصل هو هذا العزل هو هذا + +469 +00:37:42,040 --> 00:37:47,490 +الاقصاء اقصاء الدين عن كل هذه الأمور اللي ذكرناهاو + +470 +00:37:47,490 --> 00:37:50,650 +أكثر كمان يعني هذا في مجال الحكم والقوانين و في + +471 +00:37:50,650 --> 00:37:53,870 +مجال الحياة الاجتماعية كمان و الخلقية كما رأينا + +472 +00:37:53,870 --> 00:37:58,630 +قبل قليل لأنه لا علاقة للدين بالأخلاق و ليست هي + +473 +00:37:58,630 --> 00:38:03,630 +مصدر هذه النشأةالأولى اللى ساهم فيها رجال الدين + +474 +00:38:03,630 --> 00:38:08,490 +بهذا الفصل تحت هذا القول المزعوم او المنصوب الى + +475 +00:38:08,490 --> 00:38:11,610 +المسيح عيسى عليه السلام اما النشأة الثانية + +476 +00:38:11,610 --> 00:38:17,570 +للعلمانية القصة اللى بنعيد فيها كتير وذكرناها اكثر + +477 +00:38:17,570 --> 00:38:22,290 +اللى هى اتفضلها نعم + +478 +00:38:27,820 --> 00:38:34,040 +يعني أبعد الغرب رجال الدين ورجال الكنيسة ورجال كذا + +479 +00:38:34,040 --> 00:38:42,060 +عن التدخل في الحياة وفي العلم متى حينما ظهر معارضة + +480 +00:38:42,060 --> 00:38:46,000 +رجال الكنيسة ورجال الدين والكنيسة للعلم والعلماء + +481 +00:38:46,000 --> 00:38:49,510 +يقولوا خلوكوا ع شكل صفوا ع شكلمتدخلوش فين، ولا في + +482 +00:38:49,510 --> 00:38:54,370 +علومنا، الحياة لنا، الكل دين، الكل كنيسة، الكل + +483 +00:38:54,370 --> 00:38:59,370 +شعائر، الكل عقيدة، هذه الحياة ومن ضمنها العلوم، + +484 +00:38:59,370 --> 00:39:02,970 +احنا اللي ابنضعها وقد ظهر ذلك بعد القرن السادس + +485 +00:39:02,970 --> 00:39:07,630 +عشر، نتيجة هذه الظروف اللي مرت بها أوروبا، فإذا + +486 +00:39:07,630 --> 00:39:15,580 +كان هناك مبرراتوأسباب فكرية ودينية وواقعية في + +487 +00:39:15,580 --> 00:39:21,760 +أوروبا لنشأة العلمانية سنتعرف عليها في المحاضرة + +488 +00:39:21,760 --> 00:39:27,800 +القادمة ان شاء الله بالتفصيل وهي ثلاثة أسباب رئيسة + +489 +00:39:27,800 --> 00:39:30,880 +قد يكون في غيرها لكن مجموعة في هذه الثلاث أسباب + +490 +00:39:31,880 --> 00:39:36,600 +أولا فساد العقيدة النصرانية وطغيان الكنيسة وفساد + +491 +00:39:36,600 --> 00:39:40,880 +رجالها ثانيا الثورة الفرنسية اللي قامت ودعت إلى + +492 +00:39:40,880 --> 00:39:45,720 +الحرية والعدالة وحقوق الإنسان وغيره ثالثا النشاط + +493 +00:39:45,720 --> 00:39:51,040 +اليهودي أيضا ساهم وساعد في نشأة العلمانية في الغرب + +494 +00:39:51,040 --> 00:39:54,300 +لأن اليهود يعني بيدسوا حالهم في كل شيء ومنه + +495 +00:39:54,300 --> 00:39:58,880 +العلمانية ويلهم دور يعني بارز وواضح سنتعرف عليه ان + +496 +00:39:58,880 --> 00:40:03,550 +شاء الله عند الحديث عن هذه الأسبابو نقف عند هذا + +497 +00:40:03,550 --> 00:40:08,370 +الحد و الله يعطيكوا العافية والسلام عليكم ورحمة + +498 +00:40:08,370 --> 00:40:11,690 +الله وبركاته بارك الله فيك + diff --git a/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/J8scBU8FV-g_raw.srt b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/J8scBU8FV-g_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..75e46b5d818d629e2690b92e8d131ec3de2ac329 --- /dev/null +++ b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/J8scBU8FV-g_raw.srt @@ -0,0 +1,1708 @@ +1 +00:00:20,890 --> 00:00:24,430 +الحمد لله والصلاة والسلام علي رسول الله أما بعد + +2 +00:00:24,430 --> 00:00:30,690 +كنا نتحدث في المحاضرة الماضية خواد عن الغزو الفكري + +3 +00:00:30,690 --> 00:00:35,970 +وعرفنا من خلال محاضرة أو المحاضرة الماضية المراد + +4 +00:00:35,970 --> 00:00:41,630 +بالغزو الفكري والفرق بين الغزو الفكري والغزو + +5 +00:00:41,630 --> 00:00:47,280 +العسكري ذكرنا سبعة حروبثم اتعرفنا على أهداف الغزو + +6 +00:00:47,280 --> 00:00:51,960 +الفكري وكان آخر الكلام والحديث في المحاضرة الماضية + +7 +00:00:51,960 --> 00:01:01,360 +عن أدباح وأنصار الغزو الفكري وهم أربعة أصناف، فقد + +8 +00:01:01,360 --> 00:01:03,340 +تذكرنا بهذه الأصناف الأربعة + +9 +00:01:06,140 --> 00:01:11,800 +واحد الأجاراء يعني العملاء كل زمان و ما كانت اتنين + +10 +00:01:11,800 --> 00:01:17,680 +الخارجون عن الإسلام و الدين تلاتة الجهلة بحقيقة + +11 +00:01:17,680 --> 00:01:24,700 +الإسلام أربع البتهاونون هذه أصناف أربعة لأتباع و + +12 +00:01:24,700 --> 00:01:29,280 +أنصار الغزو الفكرة اللي تعرفنا عليهم في المحاضرة + +13 +00:01:29,280 --> 00:01:33,310 +الماضية في آخر المحاضرةأما محاضرات اليوم فسيكون + +14 +00:01:33,310 --> 00:01:39,270 +الحديث فيها عن وسائل الغزو الفكري وهي ثلاثة وسائل + +15 +00:01:39,270 --> 00:01:46,830 +أساسي ما هي هذه الوسائل الثلاثة؟ فضل واحد التبشير، + +16 +00:01:46,830 --> 00:01:53,040 +اثنان الاستشراك، ثلاثةالتغري .. التغري وسيكون + +17 +00:01:53,040 --> 00:02:00,860 +الحديث في محاضرتنا اليوم عن أول وسائل الغزو الفكري + +18 +00:02:00,860 --> 00:02:06,320 +وهي وسيلة التبشير سنتحرف فيه على معنى التبشير لغة + +19 +00:02:06,320 --> 00:02:08,000 +واصطلاحا + +20 +00:02:10,700 --> 00:02:15,400 +قريب من التبشير التنصيب وهو بنفس المعنى لكن نتعرف + +21 +00:02:15,400 --> 00:02:18,380 +على أصل هذه الكلمة، أصل كلمة التبشير، أصل كلمة + +22 +00:02:18,380 --> 00:02:27,600 +التنصيب وإن كان معنى صدان في يعني هدف واحدثم تتعرف + +23 +00:02:27,600 --> 00:02:32,460 +على نشأة التبشير متى نشأ و كيف نشأ و أول من قام + +24 +00:02:32,460 --> 00:02:38,260 +بالتبشير من المباشرين ثم في نهاية المحاضرة نتحدث + +25 +00:02:38,260 --> 00:02:43,640 +عن وسائل التبشير وهي وسائل كثيرة و عديدة و متعددة + +26 +00:02:46,350 --> 00:02:52,930 +نبدأ الحديث عن التبشير و كالعادة دائما في أي مصطلح + +27 +00:02:52,930 --> 00:02:57,370 +نبدأ بتعريف هذا المصطلح لنتعرف على معنى ما المقصود + +28 +00:02:57,370 --> 00:03:01,710 +بالتبشير من حيث اللغة، من أين أصل كلمة التبشير؟ + +29 +00:03:01,710 --> 00:03:04,670 +التبشير من .. التبشير من البشرة أو الكشرة وهو + +30 +00:03:04,670 --> 00:03:09,990 +يتضمن لفهمات أساسية وهم الكشرة المطلقة والكشرة + +31 +00:03:09,990 --> 00:03:18,380 +المقيلةمتى تكون البشرة مطلقة؟ تكون البشرة مطلقا في + +32 +00:03:18,380 --> 00:03:23,900 +الخير، بشره، يبشره، يريد أن أبشرك، يفهم السامع أو + +33 +00:03:23,900 --> 00:03:28,120 +المسامع أنه سيبشره في الخير، طيب، فإذا كانت البشرة + +34 +00:03:28,120 --> 00:03:33,840 +بغير الخير، أي بشرهلابد من تقييدها، لا يقول أبشرك + +35 +00:03:33,840 --> 00:03:39,960 +و يسكت يذكر بما سيبشره ولذلك القرآن يقول فبشرهم + +36 +00:03:39,960 --> 00:03:47,700 +بعذاب ألين و هذا من باب التهكم والاستهزاء والسخرية + +37 +00:03:47,700 --> 00:03:51,360 +بهم لأن البشارة في الأصل لاتكون إلا بالخير حينما + +38 +00:03:51,360 --> 00:03:56,440 +يقول الله تعالى فبشرهم بعذاب ألين يتهكم بهم و + +39 +00:03:56,440 --> 00:04:00,640 +يستهزق بهم والتنصير + +40 +00:04:01,920 --> 00:04:08,560 +قريب التنصير من التبشير يعني أصل هذه الكلمة آتي من + +41 +00:04:08,560 --> 00:04:13,180 +التنصر + +42 +00:04:14,560 --> 00:04:19,480 +والفعل نصره والمصدر تنصيرا ما معنى نصره تنصيرا + +43 +00:04:19,480 --> 00:04:26,140 +أيه؟ جعله نصرانيا وفي الحديث كله مولود يولدوا على + +44 +00:04:26,140 --> 00:04:36,920 +الفمرى فأبواه يهودانه أو نصرانه أو مجسان + +45 +00:04:37,690 --> 00:04:43,930 +يهوداني يعني يجعلونه يهوديا مثله ينصراني يجعلونه + +46 +00:04:43,930 --> 00:04:49,790 +نصرانيا مثله يمجساني يجعلونه مجوسيا مثلهم يعني + +47 +00:04:49,790 --> 00:04:57,730 +أبوي الأب والأم أما التبشير وهو أول وسائل الغزو + +48 +00:04:57,730 --> 00:05:02,370 +الفكري اللتي نتحدث عنها في محاضرة اليوممن الناحية + +49 +00:05:02,370 --> 00:05:08,550 +الاصطلاحية يطلق التمشير على الحملة التي يتزعمها أو + +50 +00:05:08,550 --> 00:05:14,130 +تزعمتها الصليبية الأوروبية فيما يعرف بتعليم الدين + +51 +00:05:14,130 --> 00:05:18,510 +المسيحي ونشره يريدون أن يبشروا بهذا الدين يعني + +52 +00:05:18,510 --> 00:05:24,370 +ينشروا هذا الدين يريدون أن ينشروا دينهم وهناك + +53 +00:05:24,370 --> 00:05:29,710 +تعريف ربما من أفضل التعريفات للتمشير هو هذا + +54 +00:05:29,710 --> 00:05:35,200 +التعريفهو التنصير الرامي إلى زعزعة العقيدة + +55 +00:05:35,200 --> 00:05:38,420 +الإسلامية في قلوب و نفس المسلمين وتشكيكهم فيها + +56 +00:05:38,420 --> 00:05:46,720 +وبالتالي إخراجهم من الإسلام التبشير هو التنصير + +57 +00:05:46,720 --> 00:05:52,570 +يريد النصارى أن يبشروا بدينهم يعني أنيجعل الناس + +58 +00:05:52,570 --> 00:05:56,270 +يدخلوا في هذا دين ينصرونهم يعني يدخلونهم في دين + +59 +00:05:56,270 --> 00:06:03,570 +النصرانية والمستهدف هنا غير النصارى وفي المقام + +60 +00:06:03,570 --> 00:06:09,170 +الأول المسلمين بهدف زعزعت عقيدتهم وإخراجهم من + +61 +00:06:09,170 --> 00:06:14,090 +دينهم وصدق الله حيث يقول وَلَا يَزَالُونَ + +62 +00:06:14,090 --> 00:06:19,630 +يُقَاتِلُونَتُمُ عَنْ دِينِكُمْ إِلَى الصَّطَاعِ + +63 +00:06:19,630 --> 00:06:24,930 +هذا هو الهدفلي الكفار في كل زمان و مكان من قتالهم + +64 +00:06:24,930 --> 00:06:30,510 +للمسلمين ولا يزالون يقاتلونكم الهدف ما هو يرده حتى + +65 +00:06:30,510 --> 00:06:35,210 +يردوكم عن دينكم إن استطاعوا فيبذلوا كل ما في وسعهم + +66 +00:06:35,210 --> 00:06:41,010 +لذلكوالتمشير كما قلنا هو أحد وسائل الغزو الفكري + +67 +00:06:41,010 --> 00:06:46,710 +وصورة .. من صورة الغزو الفكري يستهدف العقول و + +68 +00:06:46,710 --> 00:06:50,230 +القلوب و الغزو العسكري كان يستهدف الأرض و يحتل + +69 +00:06:50,230 --> 00:06:54,050 +الأرض و ينهب الخيرات و الثروات الآن هذا الغزو + +70 +00:06:54,050 --> 00:06:59,380 +الفكري و منه التمشير و الاستشراك و التغريبيستهدف + +71 +00:06:59,380 --> 00:07:02,860 +العقول و القلوب و رأينا ذلك في الفرق بين الغزو + +72 +00:07:02,860 --> 00:07:08,220 +الفكري و الغزو العسلي هناك مصوص منقولة عن بعض + +73 +00:07:08,220 --> 00:07:13,420 +القساوسة و المهبان و المبشرين + +74 +00:07:14,140 --> 00:07:18,560 +بنقول عن هؤلاء مثل القصة اليسوعي ميز وهو يصف + +75 +00:07:18,560 --> 00:07:21,840 +التمشير + +76 +00:07:21,840 --> 00:07:27,740 +بالمفهوم الجديد أو الغزو بمفهومه الجديد فيصف + +77 +00:07:27,740 --> 00:07:32,760 +الحروب الصليبية الجديدة بالهادئة ويقصد بذلك + +78 +00:07:32,760 --> 00:07:37,540 +التمشير وغيرهأقول إن الحروب الصليبية الهادئة التي + +79 +00:07:37,540 --> 00:07:42,860 +بدأها مبشرون في القرن السابع عشر لا تزال مستمرة + +80 +00:07:42,860 --> 00:07:47,510 +إلى أيامنا هذهإذا وإن كانت الحروب الصليبية + +81 +00:07:47,510 --> 00:07:53,350 +العسكرية المادية قد انتهت، هناك حرب أو حروب من نوع + +82 +00:07:53,350 --> 00:07:59,470 +آخر، بصورة أخرى، بصورة جديدة، هي الحروب الهادئة، + +83 +00:07:59,470 --> 00:08:04,130 +يعني الغزو الفكري بكل وسائله، وعلى رأسها التبشير + +84 +00:08:04,130 --> 00:08:10,080 +الذي نتحدثعنه وهناك نصوص أيضًا أخرى لمجموعة تسمى + +85 +00:08:10,080 --> 00:08:14,920 +اليسوعيين وهم يعرضون نشاطهم في بلاد الشام فيقولون + +86 +00:08:14,920 --> 00:08:22,820 +ألم نكن نحن ورثة الصليبيين؟ يرجعوا أنفسهم ونسبهم + +87 +00:08:22,820 --> 00:08:26,780 +إلى مين؟ إلى الصليبيين والحروف الصليبيين فهؤلاء + +88 +00:08:26,780 --> 00:08:33,290 +المبشرون هم ورثة الصليبيينالذين قادوا الحروب + +89 +00:08:33,290 --> 00:08:38,270 +الصليبية العسكرية على العالم الإسلامي ويقول أيضا + +90 +00:08:38,270 --> 00:08:44,810 +الأب شانتور ويأتي المباشر تحت علم الصليب إذا هناك + +91 +00:08:44,810 --> 00:08:50,870 +رب بين التبشير والحروب الصليبية لأن هذه أو هذا + +92 +00:08:50,870 --> 00:08:56,910 +يعني التبشير هو من أثر ذات من أثر الحروب الصليبية + +93 +00:08:56,910 --> 00:09:00,250 +أو صورة جديدة له + +94 +00:09:02,310 --> 00:09:06,410 +كيف نشأ التبشير و متى نشأ التبشير و من اول من قام + +95 +00:09:06,410 --> 00:09:13,830 +بهذا العمل و هذه المهمة يذكر لنا التاريخ بان اول + +96 +00:09:13,830 --> 00:09:18,730 +من تولى مهمة التنصير بعد الحروف الصالبية ما فشلت و + +97 +00:09:18,730 --> 00:09:26,460 +انتهت هوالغس الأسباني Ramolol وهو نفسه Ramolol + +98 +00:09:26,460 --> 00:09:32,760 +اللي مر معنا سابقا ونحن هنا نتحدث عن الخطة اللي + +99 +00:09:32,760 --> 00:09:37,660 +عرضت على البابا سلسل تين الخامس بعد فشل الحروب + +100 +00:09:37,660 --> 00:09:42,260 +الصالبية عرضت عليه خطتان كان إحداهما خطة الغس + +101 +00:09:42,260 --> 00:09:47,960 +الأسباني Ramolol هو نفسه Ramolol مع اختلاف في حرف + +102 +00:09:47,960 --> 00:09:52,030 +الألف واللي هي هنا كما قلنا في الترجمةمن لغة إلى + +103 +00:09:52,030 --> 00:09:57,050 +لغة يختلف أحيانا بعض الغروب حسب المراجع والكتب هذا + +104 +00:09:57,050 --> 00:10:04,780 +الراجل وهذا القص الأسبانيأجهد نفسه واجتهد وتعب في + +105 +00:10:04,780 --> 00:10:10,160 +سبيل تعلم اللغة العربية حتى يكون مقبولا أمام العرب + +106 +00:10:10,160 --> 00:10:15,400 +والمسلمين ويفهمون عليه يفهم لغتهم ويفهمون لغتهم + +107 +00:10:15,400 --> 00:10:20,040 +فيريد أن يتعلم اللغة العربية وجال في البلاد + +108 +00:10:20,040 --> 00:10:25,900 +الإسلامية يبشر بالنصرانية ويناقش ويحاول علماء + +109 +00:10:25,900 --> 00:10:30,300 +المسلمينوأيضا التاريخ يدتر لنا أن الإرساليات + +110 +00:10:30,300 --> 00:10:33,820 +التبشيرية بدأت في القوون الوسطى وكان تركيزها + +111 +00:10:33,820 --> 00:10:39,060 +الأكبر على بلاد الهند والسند وجاوة طبعا جزائر هنا + +112 +00:10:39,060 --> 00:10:43,380 +ليست جزائر البلد أو المدينة وانما جزائر جمع .. + +113 +00:10:43,380 --> 00:10:48,820 +يعني هي الجزر جزيرة جزر او جزائر جزر السند وجزر + +114 +00:10:48,820 --> 00:10:54,300 +جاوة واهتمت هولندا تحديدا في تبشيرها بمنطقة جاوة + +115 +00:10:54,300 --> 00:11:01,370 +في أوائل القرن الثامن عشرو هناك أحد أيضًا النصارى + +116 +00:11:01,370 --> 00:11:06,410 +الكبار و يطلق عليه لقب البارون و كل هذه يعني ألقاب + +117 +00:11:06,410 --> 00:11:12,970 +لرجال الكنيسة القص و البارون و البابا و الراهب و + +118 +00:11:12,970 --> 00:11:18,090 +غير ذلك كتر ألقاب هذا البارون دويتز عمل على تأسيس + +119 +00:11:18,090 --> 00:11:24,970 +مدرسة كلية مهمتها تعليم أصول التبشير و وسائل + +120 +00:11:24,970 --> 00:11:31,800 +التبشيرولا تشبيه زمهان نقول كلية الدعو كلية + +121 +00:11:31,800 --> 00:11:36,140 +إسلامية هدفها ومهمتها أن تدعو إلى الله سبحانه + +122 +00:11:36,140 --> 00:11:40,820 +وتعالى وتعلم الطلاب كيف يدعون إلى الله ووسائل + +123 +00:11:40,820 --> 00:11:46,620 +الدعو فهو على غرار ذلك أنشأة كلية مهمتها تعليم + +124 +00:11:46,620 --> 00:11:51,900 +أصول التبشير ووسائل التبشير وهناك جمعيات تبشيرية + +125 +00:11:51,900 --> 00:11:58,980 +كثيرة تأسست في بلاد الغربثم تأسست أيضًا جمعيات + +126 +00:11:58,980 --> 00:12:08,080 +شبابية تعنى بالشباب والشابات والفتيات موجودة في + +127 +00:12:08,080 --> 00:12:13,200 +الغرب وفي الشرق كذلك وفي كل مكان الهدف منها أن + +128 +00:12:13,200 --> 00:12:20,160 +يستمع الشباب والشابات إلى أصوات المبشرين فيتأثروا + +129 +00:12:20,160 --> 00:12:20,380 +به + +130 +00:12:23,760 --> 00:12:28,720 +هذا أو هذه الوسيلة من وسائل الغزو الفكر هي وسيلة + +131 +00:12:28,720 --> 00:12:33,920 +التبشير لها أهداف من ورائها يسعى المباشرون + +132 +00:12:33,920 --> 00:12:38,640 +لتحقيقها قبل التعرف على هذه الأهداف هناك عمل مهم + +133 +00:12:38,640 --> 00:12:45,100 +لابد من التعرف عليه والذي قام به لويس التاسع ملك + +134 +00:12:45,100 --> 00:12:52,140 +فرنساحيث قام بتحويل الحملات الصليبية العسكرية التي + +135 +00:12:52,140 --> 00:12:57,480 +كانت في الحروب الصليبية إلى حملات صليبية سلمية على + +136 +00:12:57,480 --> 00:13:01,100 +غرار تلك الحملات حملة ورا حملة ورا حملة كان يرسل + +137 +00:13:01,100 --> 00:13:06,060 +حملات ولكن في هذه المرة تصبنا سلمية نفس الكلام + +138 +00:13:06,060 --> 00:13:11,740 +السابق الذي ذكره لان طب ما هي أهداف التبشير يا + +139 +00:13:11,740 --> 00:13:12,160 +اخوتي؟ + +140 +00:13:17,550 --> 00:13:22,270 +أول هذه الأهداف و أهم هذه الأهداف و على رأس هذه + +141 +00:13:22,270 --> 00:13:28,700 +الأهداف كلهاهو تنصير المسلمين، إيش تنصيرهم يعني؟ + +142 +00:13:28,700 --> 00:13:34,080 +يعني جعلوا النصارى يدينون الدين المنسوف، طبعا زور + +143 +00:13:34,080 --> 00:13:38,740 +الرب مبتعد إلى المسيح عليه السلام، لأنه لم يعد هذا + +144 +00:13:38,740 --> 00:13:42,680 +الدين هو دينه المسيحي، الذي يدعي أصحابه اليوم + +145 +00:13:42,680 --> 00:13:48,920 +النصرانية والمسيحية نسبة إلى المسيح لم تعدأو لم + +146 +00:13:48,920 --> 00:13:53,240 +يعد هذا الدين هو ذلك الدين الحق الذي نزل على سيدنا + +147 +00:13:53,240 --> 00:13:59,420 +عيسى عليه السلام حرفه النصارى وبدلوا وغيروا فيه + +148 +00:13:59,420 --> 00:14:04,780 +وزادوا عليه وانقصوا منه وادخلوا فيه العقائد + +149 +00:14:04,780 --> 00:14:10,480 +الباطلة والشركية والوثنية مثل التثليث القائم عليه + +150 +00:14:11,020 --> 00:14:17,040 +يعني الاعتقال بإن الله تعالى ثلاثة اب و ابن و عيسى + +151 +00:14:17,040 --> 00:14:21,740 +عليه السلام وروح القدس و الواسطة بين الأب و الابن، + +152 +00:14:21,740 --> 00:14:26,400 +و هذه يعني عقيدة سنتعرف عليها يعني لاحقالأن الهدف + +153 +00:14:26,400 --> 00:14:32,860 +الأول هو التنصير والله تعالى يؤكد لنا هذه الحقيقة + +154 +00:14:32,860 --> 00:14:38,860 +لكل من اليهود والنصارى لن يهدأ لهم بال و لن يقر + +155 +00:14:38,860 --> 00:14:46,500 +لهم قرار حتى يجدوا المسلمين إما أصبحوا يهودا أو + +156 +00:14:46,500 --> 00:14:53,600 +نصر و لن ترضى عنك اليهود ولا نصارى حتى تتبع ملتقا + +157 +00:14:53,970 --> 00:15:00,050 +لا نتأمل يا أخوان أي خير في هؤلاء لا يقبونا في + +158 +00:15:00,050 --> 00:15:08,170 +مؤمن إلا ولا ذنب لا يحافظون على العهد ولا يريدون + +159 +00:15:09,360 --> 00:15:14,540 +لنا الخير، ودوا ما عانيتم، ودوا يعني أحب من الود + +160 +00:15:14,540 --> 00:15:18,140 +والحب، ما عانت .. ما عانيتم يعني العنة اللي يصيب، + +161 +00:15:18,140 --> 00:15:23,480 +المشقة والضرر، أحب ما عليهم العنة والضرر والمشقة + +162 +00:15:23,480 --> 00:15:29,360 +والحصار اللي أنتم فيه، هم يعني مبسوطون على .. + +163 +00:15:29,360 --> 00:15:34,060 +ومبسرورون على هذا الأمر ودوا ما عانت، قد بدت + +164 +00:15:34,060 --> 00:15:38,860 +البغضاه من أفواهي، في تصريحات واضحة البغضاهولسة + +165 +00:15:38,860 --> 00:15:43,860 +وما تخفي صدورهم أكبر كما لسه في حاجات كتير انخبينا + +166 +00:15:43,860 --> 00:15:50,640 +ان لا يصرحون بيها فان هذا هو الهدف من ورائي + +167 +00:15:50,640 --> 00:15:56,000 +التبشير والتنصيب وادخال المسلمين في هذا الدين + +168 +00:15:56,000 --> 00:16:03,180 +النصراني المحرف كما قلناو هناك أقوال لمباشرين كثير + +169 +00:16:03,180 --> 00:16:07,340 +في هذا السياق و هذا المجلد تقول أحد المباشرين و + +170 +00:16:07,340 --> 00:16:14,580 +اسمه راي مان تقرألي يعني قوله فضل الأخرإنني أحاول + +171 +00:16:14,580 --> 00:16:21,120 +أن أنقل المسلم من محمد إلى المسيح، ومع ذلك يظن + +172 +00:16:21,120 --> 00:16:25,300 +المسلم أن لي في ذلك غير خاصة، أنا لا أحب المسلم + +173 +00:16:25,300 --> 00:16:28,180 +لذاته، ولا لأنه أخ لي في الإنسان الجامعي + +174 +00:16:31,170 --> 00:16:35,430 +ولو لأنني أريد ربحه إلى صفوف النصارى لما كنت + +175 +00:16:35,430 --> 00:16:40,330 +تعرضته له ليساعده إذا هو لا يحب المسلمين، لا حب في + +176 +00:16:40,330 --> 00:16:45,050 +المسلمين ولا حب في الخير، هو يريد أن يكثر سواب + +177 +00:16:45,050 --> 00:16:49,010 +النصارى، يريد أن يخرج المسلم من دينه إلى دين + +178 +00:16:49,010 --> 00:16:57,070 +النصرانية المحرفة كما ذكرنا وهذا تصريح واضحمن هذا + +179 +00:16:57,070 --> 00:17:03,090 +المبشر ومن ورأوا أنهم مريدون نقل المسلم من دينه من + +180 +00:17:03,090 --> 00:17:10,470 +نبيه إلى دينهم المحافظ وانت تصريحات وأقوال أخرى + +181 +00:17:10,470 --> 00:17:18,230 +ورغم جهود التنصيرالكثيفة والرهيبة والكثيرة في + +182 +00:17:18,230 --> 00:17:23,310 +البلدان الإسلامية وغير الإسلامية أيضا إلا إن كانت + +183 +00:17:23,310 --> 00:17:28,450 +حصيلتهم قليلة خاصة بين المسلمين وخاصة بين + +184 +00:17:28,450 --> 00:17:33,510 +المتعلمين منهم الذين يعرفون دينهم حق المعرفة لا + +185 +00:17:33,510 --> 00:17:38,740 +يقبل ولا يرضى مسلم أن يتوك دينه إلى دين آخرإذا + +186 +00:17:38,740 --> 00:17:42,880 +أراد أن ينتقل من دين إلى دين لن يجد أفضل من هذا + +187 +00:17:42,880 --> 00:17:46,220 +الدين اللي يدعو إلى التوحيد وإلى التسامح وإلى + +188 +00:17:46,220 --> 00:17:52,340 +الرحمة وهو دين حق وواضح وبين فيتركه إلى دين يدعو + +189 +00:17:52,340 --> 00:17:59,340 +إلى الشرك والتثليث وغير ذلك ولكن + +190 +00:18:00,390 --> 00:18:04,330 +في الأماكن التي نجحوا فيها أو المناطق التي نجحوا + +191 +00:18:04,330 --> 00:18:12,550 +فيها بعض النجاح ساعدهم في ذلك مين؟ الحكام الحكومات + +192 +00:18:12,550 --> 00:18:17,230 +والحكام سهلوا لهم هذه المهمة أعطوهم حرية كاملة + +193 +00:18:17,230 --> 00:18:21,210 +وكافية في أن يصرحوا وينرحوا في البلاد الإسلامية هم + +194 +00:18:21,210 --> 00:18:26,390 +حرين دون أن يعترضوا عليهم وعند مثال واضح في + +195 +00:18:26,390 --> 00:18:34,400 +أندونسيا وبعض الأفريقياحيث ساهم الحكام و الأنظمة + +196 +00:18:34,400 --> 00:18:41,480 +ساهمت في التنصير في هذه البلدة مع عام الآخر هو .. + +197 +00:18:42,100 --> 00:18:47,680 +الجاهل والفقر والمرض وهم يراهنون على مثل هذه + +198 +00:18:47,680 --> 00:18:52,100 +البيئات، بيئة الجاهل، بيئة الفقر، بيئة المرض، + +199 +00:18:52,100 --> 00:18:58,480 +فيخترقون المسلمين من خلال الجاهل، مثلا الجاهل في + +200 +00:18:58,480 --> 00:19:06,480 +دينه لن يجدقبضة في أن ينتقل إلى دين آخر إذا رقب في + +201 +00:19:06,480 --> 00:19:12,200 +هذا الدين و أغري به و خاصة إذا كان فقيرا مريضا و + +202 +00:19:12,200 --> 00:19:17,200 +هم يستخدمون في تبشير كما سنرى في وسائل التبشير و + +203 +00:19:17,200 --> 00:19:22,260 +الوسائل الإغراء و المساعدة و المعونة و المال و + +204 +00:19:22,260 --> 00:19:27,040 +الدواء وغير ذلك فهم في مثل هذه البيئات البيئة التي + +205 +00:19:27,040 --> 00:19:32,940 +ينتشر فيها الجهل و الفقر و المرضينجحون بعض + +206 +00:19:32,940 --> 00:19:39,120 +النجاحات مع تشجيع الحكومات كما قلنا هذا الهدف + +207 +00:19:39,120 --> 00:19:42,860 +الأول من أهداف التبشير إذا هدفهم الأول وطنصير + +208 +00:19:42,860 --> 00:19:47,560 +المسلمين أي جعلهم نصاب الهدف الثاني وهو لا يقل + +209 +00:19:47,560 --> 00:19:49,220 +خطورة عن الهدف الأول + +210 +00:19:52,390 --> 00:19:57,270 +إخراج المسلمين من دينه بارك الله فيك يا حسن يعني + +211 +00:19:57,270 --> 00:20:03,970 +إن لم يدخل المسلم في النصرانية فلا أقل من أن يخرج + +212 +00:20:03,970 --> 00:20:08,970 +من دينه وبعد ذلك لا يهمهم أين يدخل المهم يخرج من + +213 +00:20:08,970 --> 00:20:13,210 +دينه أو عن دينه وده هو الهدف ولا يزالون يقاتلونكم + +214 +00:20:13,210 --> 00:20:18,090 +حتى يردّونكم عن دينه إن استطاعوا إذا إنهم أهداف + +215 +00:20:18,090 --> 00:20:22,790 +إماولا ان ترضى عنك اليهود ولا النصارى حتى تتبع + +216 +00:20:22,790 --> 00:20:27,310 +ميلتهم ان يصبح مثلهم يهوديا او نصرانيا او هدف + +217 +00:20:27,310 --> 00:20:31,910 +الثاني ان لم ينجحوا في الأول على الأقل حتى يرضوكم + +218 +00:20:31,910 --> 00:20:35,470 +عن دينكم ان استطاعوا او يبقى الانسان يشك في هدف + +219 +00:20:35,470 --> 00:20:40,790 +الدين ويتذبذب فيه هناك هدف ثالث ايضا من اهداف + +220 +00:20:40,790 --> 00:20:45,850 +التبشير فضلوا الحيولة ضمن دخول المسار او الامة + +221 +00:20:45,850 --> 00:20:49,460 +المغاربة المصرانية في اسلامبرك الله فيك و هذا كمان + +222 +00:20:49,460 --> 00:20:56,620 +هدف يعني كبير كانوا يسعون اليه دائما و أبدا هناك + +223 +00:20:56,620 --> 00:21:04,510 +موجة كبيرة اجتاحة الغرب النصرانيفي دخول أعداد + +224 +00:21:04,510 --> 00:21:10,610 +كبيرة من الغربين في الإسلام، فغاضهم هذا الأمر، كيف + +225 +00:21:10,610 --> 00:21:16,750 +يعني يأتي المسلمون من أقاصر البلدان ويدخلوا بلادنا + +226 +00:21:16,750 --> 00:21:22,830 +وأرضنا وينشروا دينهم؟ويسحبون البصار من تحت أرجلنا + +227 +00:21:22,830 --> 00:21:28,930 +كما يقولون ونحن نتفرج عليهم لابد أن نمنع هذا المدى + +228 +00:21:28,930 --> 00:21:33,770 +الإسلام لابد أن نحول دون دخول النصارى وغير النصارى + +229 +00:21:33,770 --> 00:21:42,150 +في الإسلامفبدأوا بالهجوم على العالم الإسلامي ونشر + +230 +00:21:42,150 --> 00:21:47,750 +ديمون لأنه في قاعدة بتقول أو مذل خيره وسيلة للدفاع + +231 +00:21:47,750 --> 00:21:52,250 +للهجوم بدل ما ننتظرهم يأتوا إلينا نهجم عليهم + +232 +00:21:52,250 --> 00:22:00,530 +ونبغطهم ونبادرهم الهدف الرابع من أهداف التبشيرفي + +233 +00:22:00,530 --> 00:22:03,070 +الحقيقة بأن المبادئ الوطنية والتعليم النصراني هي + +234 +00:22:03,070 --> 00:22:07,730 +أفضل المبادئ بالنسبة للمبادئ الوطنية وهذا برضه هدف + +235 +00:22:07,730 --> 00:22:15,050 +سامي وكبير بالنسبة له بطريقتهم في التبشير + +236 +00:22:15,050 --> 00:22:21,170 +وبانخراطهم مع الذين يستهدفونهميعلمونهم المبادئ + +237 +00:22:21,170 --> 00:22:26,690 +والمثل والتعليم النصرانية ويقولون من ألطف ما يكون + +238 +00:22:26,690 --> 00:22:31,070 +في المعاملة ومن أحسن ما يكون حتى يعقوا إيحاءً + +239 +00:22:31,070 --> 00:22:36,530 +وتصوراً عند المسلمين بأنهم أفضل من المسلمين، والله + +240 +00:22:36,530 --> 00:22:40,170 +معاملتهم أفضل من المسلمين، والله عندهم أخلاق أفضل + +241 +00:22:40,170 --> 00:22:43,690 +من المسلمينوالله إن هدول أحسن من المسلمين، وده + +242 +00:22:43,690 --> 00:22:49,450 +عبارة يعني يردد بعض الجهلة في دينهم أن هؤلاء أفضل + +243 +00:22:49,450 --> 00:22:52,390 +منهم، أن هؤلاء أحسن منهم، والله لسه اليهود أحسن + +244 +00:22:52,390 --> 00:22:54,870 +منهم، والله لسه النصارى أحسن منهم، بيعملون بكده + +245 +00:22:54,870 --> 00:22:58,570 +وبيعملون، وهذا مقصود، وهذا مقصود، هذا المعاملة + +246 +00:22:58,570 --> 00:23:06,070 +الحسنة في ظاهرها مقصودة لهذا الغرض و لهذا الهدف، + +247 +00:23:06,070 --> 00:23:11,490 +وحتى يقبلهم الناس ويتقبلونهطبعا هم ليسوا أفضل مننا + +248 +00:23:11,490 --> 00:23:17,190 +بشيء ما هم عليه من الكفر والعقيدة الباغلة والضالة + +249 +00:23:17,190 --> 00:23:20,790 +مهما فعلوا الأفعيل لا يمكن أن يكونوا مقبولين + +250 +00:23:20,790 --> 00:23:27,650 +وفعلته وفعلتهم هذه مكشوفة لنا وهدفها معروف يعني من + +251 +00:23:27,650 --> 00:23:32,770 +وراقه فهم يريدون أن يوحوا لنا بهذا الأمر أيضا + +252 +00:23:32,770 --> 00:23:37,210 +النقطة الخامسة أو الهدف الخامس اتفضليإخضاع العالم + +253 +00:23:37,210 --> 00:23:40,370 +الإسلامي لسيطرة الاستعمار الأوروبي الغربي والتحكم + +254 +00:23:40,370 --> 00:23:44,930 +في مقدارات وإن كانت .. في مقدارات نعم بارك الله + +255 +00:23:44,930 --> 00:23:49,230 +فيك أحسن برضه من أهداف .. من أهدافهم إخضاع العالم + +256 +00:23:49,230 --> 00:23:55,310 +الإسلامي لسيطرة الاستعمار الأوروبي لإن هؤلاء يا + +257 +00:23:55,310 --> 00:23:59,830 +أخوات كما قلنا هم الوجه الأخر للاستعمار هم + +258 +00:23:59,830 --> 00:24:05,260 +الاستعمار في صورة جديدة وحديثةهم الوجه الآخر لنفس + +259 +00:24:05,260 --> 00:24:08,620 +العملة وجهان لعملة واحدة استعمار والتبشير + +260 +00:24:08,620 --> 00:24:12,400 +والاستشراف والتغريب كل هذه أدوات استعمارية جديدة + +261 +00:24:12,400 --> 00:24:17,900 +وحديثة وصور جديدة من الاستعمار والحروب الصليبية + +262 +00:24:17,900 --> 00:24:25,350 +العسكرية الأولى هذه بديلا أو هذه بديل عن تلكفمن + +263 +00:24:25,350 --> 00:24:28,530 +أهداف أهدافهم أن يخدعوا العالم الإسلامي اللي سيطرت + +264 +00:24:28,530 --> 00:24:34,190 +الاستعمار بإيحاءهم أيضا بأن الرجل الأبيض الغربي + +265 +00:24:34,190 --> 00:24:40,590 +المثقف المتعلم المتقدم الواعي المتحضر المتمدن + +266 +00:24:40,590 --> 00:24:48,160 +المتنور أفضل من هذا الرجل العربي أو الداقيعلى علمى + +267 +00:24:48,160 --> 00:24:54,060 +وما هو عليه وطبعا في ذلك افتتان ايام افتتان وفتوتن + +268 +00:24:54,060 --> 00:24:59,920 +بهؤلاء من المسلمين ناس كثم وبدأوا يسوقون لهم و + +269 +00:24:59,920 --> 00:25:05,120 +لأفكارهم و يدعون إلى اللحوق بهم و برقبهم و + +270 +00:25:05,120 --> 00:25:10,620 +بحضارتهم وسنتعرف على أمثلة و نماذج لهؤلاء الدعاء + +271 +00:25:10,620 --> 00:25:13,280 +الذين كانوا يدعون إلى ذلك + +272 +00:25:16,790 --> 00:25:22,790 +أيضا من الأهداف الهدف السادس من أهداف التبشير من + +273 +00:25:22,790 --> 00:25:27,110 +هنا تفضلي ترسيه فكرة قيام وطن قوم اليهود على أرض + +274 +00:25:27,110 --> 00:25:32,950 +فلسطين علينا صوتك كمان مرة ترسيه فكرة قيام دولة + +275 +00:25:32,950 --> 00:25:36,630 +دولة ووطن قوم اليهود على أرض فلسطين ترسيه برك الله + +276 +00:25:36,630 --> 00:25:43,010 +.. ترسيه فكرة قيام دولة ووطن قومي اليهود في فلسطين + +277 +00:25:43,010 --> 00:25:45,270 +طب وما علاقة النصارى باليهود؟ + +278 +00:25:47,740 --> 00:25:51,900 +انه اليهود و النصارى طبعا كلا هما ياخدوا عن بعض أو + +279 +00:25:51,900 --> 00:25:54,960 +هناك بعض النصارى المتصهينين لديهم يؤمنون بفكرة + +280 +00:25:54,960 --> 00:25:59,240 +الوطن القومي لليهود خاصة ان كثير من اليهود قاموا + +281 +00:25:59,240 --> 00:26:02,740 +بصهينة كثير من النصارى و ادخال شروح صهيونية في + +282 +00:26:02,740 --> 00:26:07,010 +كتابهم المقدس بما يخدم فكرتهمبارك الله فيك و أحسن + +283 +00:26:07,010 --> 00:26:10,290 +هناك ما يُعرف يا أخوات في صفوف النصارى أو عند + +284 +00:26:10,290 --> 00:26:16,690 +النصارى في الغرب بالنصارى المتصينين أو الصهيونيين + +285 +00:26:16,690 --> 00:26:20,610 +يعني هم نصارى في الأصل لكن يؤمنون بفكرة الصهيونيين + +286 +00:26:20,610 --> 00:26:27,180 +التي تقوم على إنشاء وطنقومي لليهود في فلسطين ودولة + +287 +00:26:27,180 --> 00:26:31,280 +لليهود في فلسطين وساهموا كثيرا في دعم اليهود في + +288 +00:26:31,280 --> 00:26:36,440 +ذلك ولا يزالون يساهمون ويساعدون ويمدون اليهود + +289 +00:26:36,440 --> 00:26:42,200 +ودولة اليهود بالمال وبكل ما يلزم هؤلاء المسيحيون + +290 +00:26:42,200 --> 00:26:48,050 +يطلع عليهم هذا الإطلاع انهم صهائناولو لم يكونوا + +291 +00:26:48,050 --> 00:26:54,990 +يهودا و كما نعرف أو نقدّت جميعا ملا الكفر واحدة + +292 +00:26:54,990 --> 00:26:59,070 +هؤلاء كفار وهؤلاء كفار وإذا كان العدو المشترك لهما + +293 +00:26:59,070 --> 00:27:02,830 +هم المسلمين كما قلنا في المحاضرة الماضية يتوحدون + +294 +00:27:03,630 --> 00:27:10,370 +ضدهم مصداقا لقوله تعالى والذين كفروا بعضهم أولياء + +295 +00:27:10,370 --> 00:27:15,350 +بعض الكفار بيولوا بعض على الكفر إذا كان المستهدف + +296 +00:27:15,350 --> 00:27:22,860 +والهدف والعدو هو الإسلام والمسلمينالهدف السابع + +297 +00:27:22,860 --> 00:27:38,700 +والأخير من أهداف التبشير بارك + +298 +00:27:38,700 --> 00:27:43,460 +الله فيك، أحسنت، دكف يعني، خير الكلام ما أقل هو ده + +299 +00:27:44,670 --> 00:27:50,170 +لما نقول من أهداف التبشير التغريب معنى ذلك هنا هي + +300 +00:27:50,170 --> 00:27:56,390 +نقطة التقاء لأ هنا نقطة التقاء بينهم لإن كل من + +301 +00:27:56,390 --> 00:28:02,190 +التبشير والاستشراك والتغريب يؤدون نفس الغاية + +302 +00:28:02,190 --> 00:28:09,570 +والهدف والغرض هم سائلللغزو الفكر يعني كأنهم بنات + +303 +00:28:09,570 --> 00:28:14,330 +لأم من واحد ولا أولاد لأم من واحد هي الغزو الفكري، + +304 +00:28:14,330 --> 00:28:19,270 +الكل يعني هدفه هو الغزو الفكري لعقول وقلوب + +305 +00:28:19,270 --> 00:28:22,010 +المسلمين، هذا من التمشير، هذا من التغريب، هذا من + +306 +00:28:22,010 --> 00:28:27,170 +الاستشراك، والكل في النهاية صوب بمصلحة واحد، مصلحة + +307 +00:28:27,170 --> 00:28:32,750 +الغرب والصليبيين والنصارى والاستعمار اللي يعني + +308 +00:28:32,750 --> 00:28:39,500 +تكلمنا عنهإذا هذه هي الأهداف .. أهداف التبشير + +309 +00:28:39,500 --> 00:28:46,560 +ننتقل الآن بعد الحديث عن أهداف التبشير إلى وسائل + +310 +00:28:46,560 --> 00:28:54,670 +التبشيرما هي الوسائل التي اعتمدها المباشرون لتحقيق + +311 +00:28:54,670 --> 00:29:00,670 +أهدافهم سالفة الذكر التي سبق وذكرناها قبل قليل + +312 +00:29:00,670 --> 00:29:06,870 +وانتهينا منها حينما نقرأ ونتفحص ونستعرض هذه + +313 +00:29:06,870 --> 00:29:13,040 +الوسائل نجد وسائل مالة كثيرة وعديدة وكبيرةمش واحدة + +314 +00:29:13,040 --> 00:29:17,320 +ولا تنتين ولا تلاتة ولا أربع في وسائل كثيرة يعني + +315 +00:29:17,320 --> 00:29:22,600 +وصلت إلى حوالي اتناشر وسيلة مذكورة عندنا هنا في + +316 +00:29:22,600 --> 00:29:28,680 +الكتاب على رأس هذه الوسائل ولعلها أخطرها أو أهمها + +317 +00:29:28,680 --> 00:29:37,340 +وسيلة .. اه وسيلة ايش اسمها؟ وسيلة اولا التعليم في + +318 +00:29:37,340 --> 00:29:40,960 +المدارس و الكليات و الجامعة وسيلة التعليم في + +319 +00:29:40,960 --> 00:29:45,980 +المدارسكذلك في الكليات و المعاهد و في الجامعة هذه + +320 +00:29:45,980 --> 00:29:50,220 +الوسيلة الأولى و المجال الأول يمكن أن نطلق عليه + +321 +00:29:50,220 --> 00:29:55,040 +اسم أو لفظ وسيلة أو مجال وسيلة أو مجال مجال الأول + +322 +00:29:55,040 --> 00:30:00,380 +أو الوسيلة الأولى و التعليم أولاه المبشرون أهمية + +323 +00:30:00,380 --> 00:30:07,460 +قصوى و كبراءوإعتبروه وسيلة لغاية فالتعليم عندهم هو + +324 +00:30:07,460 --> 00:30:12,660 +واسطة أو وسيلة لغاية هذه الغاية هي إيش غايتهم؟ هي + +325 +00:30:12,660 --> 00:30:16,400 +قيادة الناس إلى المسيحيين هي قيادة الناس إلى + +326 +00:30:16,400 --> 00:30:20,960 +المصرانين إلى المسيحيين وتعليمهم كيف يصبحوا يعني + +327 +00:30:20,960 --> 00:30:25,820 +مسيحيين وشعوبا مسيحيين من خلال التعليم كلنا نعلم + +328 +00:30:25,820 --> 00:30:32,720 +خطر وأهمية التعليم واعتبراليسوعيون أيضا في كتاب + +329 +00:30:32,720 --> 00:30:39,020 +لهم أن المبشر الأول عندهم والأهم هو المدرسة منه + +330 +00:30:39,020 --> 00:30:46,780 +يبدأون ومنه ينطلقون طيب هنا يعني يطرق سؤال ما هي + +331 +00:30:46,780 --> 00:30:53,960 +الطرق التي سلكها المبشرون في مجال التعليمايش الطرق + +332 +00:30:53,960 --> 00:30:57,480 +اللي سلكوها في مجال التعليم؟ فيها انه طرق عديدة + +333 +00:30:57,480 --> 00:31:02,860 +ندخلها ونفصل فيها طريقة الأولى في ذلك الأخت اللي + +334 +00:31:02,860 --> 00:31:10,600 +ورا هنا افضل انت اهأول حاجة أكثر من المدارس بنوا + +335 +00:31:10,600 --> 00:31:15,520 +مدارس فتحوا مدارس ورياض أطفال ليش مدارس ورياض + +336 +00:31:15,520 --> 00:31:21,200 +أطفال؟ لأنه بدهم يربوا هذا الجيل منذ أن هما أطفال + +337 +00:31:21,200 --> 00:31:25,700 +أول ما يوعى الطفل الصغير يعني ينشأ على الاستماع + +338 +00:31:25,700 --> 00:31:31,460 +إلى أقوالهم وإلى عقائدهم هناك تصريحات كثيرة + +339 +00:31:31,460 --> 00:31:38,820 +للمباشرين في ذلكبيعتبرون أنها .. أي المدارس ورياض + +340 +00:31:38,820 --> 00:31:43,020 +الأطفال تأتي بأحسن الثمار في تنصير المسلمين و + +341 +00:31:43,020 --> 00:31:48,140 +تعليمهم و هم صغار و يقول أيضا مبشر آخره جون موت + +342 +00:31:48,140 --> 00:31:52,780 +يقول يجب أن نحمل الأطفال الصغار إلى المسيح قبل + +343 +00:31:52,780 --> 00:31:59,250 +بلوغهم الرشدوقبل أن تأخذ طباء طبائعهم أشكالها + +344 +00:31:59,250 --> 00:32:04,010 +الإسلامي قبل ما يتشكل هذا الطفل بدنا احنا نلحق + +345 +00:32:04,010 --> 00:32:05,810 +ونكون أول man + +346 +00:32:08,600 --> 00:32:13,700 +يعلمه الدين بدل أن يعلمه أبواه الدين الإسلامي + +347 +00:32:13,700 --> 00:32:18,980 +وتشكل على ذلك لنسبق الأبواين فنقوم بتعليمه ذلك + +348 +00:32:18,980 --> 00:32:23,300 +السؤال اللي فضل وده كتعقيد بسيط بخصوصها للنقطة حيث + +349 +00:32:23,300 --> 00:32:26,160 +و أنا في خلال طرقتي على أحد الموقع الإلكترونية + +350 +00:32:26,160 --> 00:32:31,000 +يقال بأنه في رياض الأطفال يُعطل الطفل دمية يكون ما + +351 +00:32:31,000 --> 00:32:34,670 +بين الأربع إلى الخمس سنواتيوطل هو للطفل هدية، دمية + +352 +00:32:34,670 --> 00:32:39,370 +قد .. قد أتى بيها لك المسير حيثها، بقى يحبها هذا + +353 +00:32:39,370 --> 00:32:43,150 +الطفل ويتعامل معها ما يقارب شهر كامل، ثم بعد ذلك + +354 +00:32:43,150 --> 00:32:46,650 +تسرق هذه ال .. الدمية، من غير أن يشهر الطفل من هو + +355 +00:32:46,650 --> 00:32:49,910 +السارق، تكون من أحد المعلمة أو المديرة أو كذا، + +356 +00:32:49,910 --> 00:32:53,210 +تسرق و .. و .. و تبعد عن عين الطفل، يسرق عندما + +357 +00:32:53,210 --> 00:32:56,750 +يبكي الطفل ويسأل عنها، يقال له بأن محمد قد سرقها، + +358 +00:32:56,750 --> 00:32:59,830 +الطفل يسأل من هو محمد، يقول له إنه نبي المسلمين، + +359 +00:32:59,980 --> 00:33:03,240 +اللي زي رشد الطفل مدرومة مظاهرة على كل سيدنا محمد + +360 +00:33:03,240 --> 00:33:07,060 +والسيدات والبسانسيين بارك الله فيك و أحسنتي و كلام + +361 +00:33:07,060 --> 00:33:09,940 +كتير في هذا المجال لما نريد أن نذكر أمثلة و ندلل + +362 +00:33:09,940 --> 00:33:16,060 +عليه في يعني رياض الأطفال و في مدارسهم أيضا مما + +363 +00:33:16,060 --> 00:33:21,440 +ذكر و في القصص أن هناك يعني طاقتين أو شباكين صغار + +364 +00:33:21,440 --> 00:33:26,540 +و كده فيقال هذه هذا شباك أو طاقة محمد و هذه طاقة + +365 +00:33:26,540 --> 00:33:29,850 +عيسىشباب محمد فال مافيش فيه ولا حاجة و شباب عيسى + +366 +00:33:29,850 --> 00:33:33,870 +فيه حمبة حلوة شوكولاتة و ألعابة لما يغرق الطفل + +367 +00:33:33,870 --> 00:33:38,010 +فاهمش الطفل على حب عيسى و كراية محمد اللي لا يعطيه + +368 +00:33:38,010 --> 00:33:43,470 +شيء مع أننا .. مع أننا كمسلمين لنفرق بين أحد من + +369 +00:33:43,470 --> 00:33:46,930 +الأنبياء ولو نصل عندنا عيسى و موسى و محمد صلى الله + +370 +00:33:46,930 --> 00:33:50,090 +عليه و سلم كلهم أنبياء و رسل لكن هم عندهم ذلك + +371 +00:33:50,090 --> 00:33:57,380 +التفريق وهذا الحقد وهذا التعصب لنبي ضد نبيأيضا من + +372 +00:33:57,380 --> 00:34:00,920 +الطرق التي قمت بها في مجال التعليم + +373 +00:34:03,760 --> 00:34:06,780 +دي من الأخوات المسمانة .. انشاء الجامعات والكليات + +374 +00:34:06,780 --> 00:34:10,680 +أيضا لهم برك الله فيك جامعات أنشأوها في بلاد + +375 +00:34:10,680 --> 00:34:16,840 +المسلمين وكليات ومعاهد وفي عدة أسماء لبعض هذه + +376 +00:34:16,840 --> 00:34:21,740 +الجامعات مثل الجامعة الأمريكية في بيروت الجامعة + +377 +00:34:21,740 --> 00:34:24,660 +الأمريكية في القاهرة والجامعة الأمريكية عندنا هنا + +378 +00:34:24,660 --> 00:34:28,380 +في فلسطين في جنين موجود الجامعة الأمريكية احنا + +379 +00:34:28,380 --> 00:34:31,360 +بنتكلم على مستوى الجامعة وقبل المدارس موجود كثير + +380 +00:34:31,360 --> 00:34:35,360 +عندنا في غزة وفي كل مكانورياض الأطفال، مين تذكرنا + +381 +00:34:35,360 --> 00:34:38,920 +من المدارس الموجودة عندنا هنا في قطاع غزة ورياض + +382 +00:34:38,920 --> 00:34:43,620 +الأطفال اسمها راهبات الوردين، المدارس التبشرية، + +383 +00:34:43,620 --> 00:34:46,600 +العائلة المقدسة، دير اللاتين + +384 +00:34:48,380 --> 00:34:54,620 +اه المدرسة Rome Orthodox وغيرها من هذه المدارس + +385 +00:34:54,620 --> 00:34:58,160 +الموجودة و المنتشرة يعني هذه فقط المقعة الصغيرة + +386 +00:34:58,160 --> 00:35:01,380 +اللي فيها كل هذه المدارس فما بقالنا في دول كبيرة + +387 +00:35:01,380 --> 00:35:05,800 +فيعني مدارسهم و رياض أطفالهم و جامعاتهم و كلياتهم + +388 +00:35:05,800 --> 00:35:10,260 +و معاهدهم كثيرة و عديدة و منتشرة في كثير من + +389 +00:35:10,260 --> 00:35:17,510 +البلدان الإسلاميةايضا من الطرق التي سلكوها اختيار + +390 +00:35:17,510 --> 00:35:25,570 +المدرسين والمعلمين وطلبهم خاص كيف يختاروا المدرسين + +391 +00:35:25,570 --> 00:35:32,510 +والمعلمين وطلبهم خاصأولا يجب أن يكون المعلم في هذه + +392 +00:35:32,510 --> 00:35:38,030 +المدارس والجامعات والكليات أجنبيا غربيا من برا + +393 +00:35:38,030 --> 00:35:44,410 +يعني وليس يعني من أهل البلاد طيب إذا لم يجدوا .. + +394 +00:35:44,410 --> 00:35:51,510 +إذا لم يجدوه من خارج الوطن الذي يقيمون في هذه + +395 +00:35:51,510 --> 00:35:56,310 +المدارس والجامعات يختارونه نصرانيا من نفس البلد + +396 +00:36:00,540 --> 00:36:04,680 +يختارونه مسلما لا يعرف عن الإسلام يختارونه مسلما + +397 +00:36:04,680 --> 00:36:09,080 +بالاسم بالهوية فقط مسلم بالهوية ولا يعرفوا شيء عن + +398 +00:36:09,080 --> 00:36:14,040 +الإسلام حتى لا يؤثر في الطلاب أو الطلبات في مدارسه + +399 +00:36:14,040 --> 00:36:19,480 +هذا هو المقياس والنيار اللي بيختاروا في المدرسين + +400 +00:36:19,480 --> 00:36:24,120 +أيضا من الطرق اللي سلكوها في مجال التعليم كذلك يا + +401 +00:36:24,120 --> 00:36:28,200 +أخوات فضل الأخوة تعليم في كتب خاصة مراحل .. مختلف + +402 +00:36:28,200 --> 00:36:34,900 +مراحل التعليمنعم و هذه الكتب هل يعني للفائدة ولا + +403 +00:36:34,900 --> 00:36:41,540 +الهدف منها ايه؟ يملؤونها هذه الكتب و المؤلفات + +404 +00:36:41,540 --> 00:36:45,980 +اللتي يؤلفونها بالتشكيك حول الإسلام و الشبهات حول + +405 +00:36:45,980 --> 00:36:50,260 +الإسلام، هنتكلم على شبهات كثيرة يعني لاحقا و نرد + +406 +00:36:50,670 --> 00:36:57,010 +أيضا من الطرق التي سلكوها أبطال على أخوات ما + +407 +00:36:57,010 --> 00:36:58,830 +شاركوش معانا، فضلا + +408 +00:37:02,690 --> 00:37:07,850 +هذا كمان من أخطر أخوات الوسائل والطرق التي سلكها + +409 +00:37:07,850 --> 00:37:14,390 +هؤلاء في مدارس وفي رياضي الأطفال كانوا يجبرون + +410 +00:37:14,390 --> 00:37:18,810 +الطلاب وحتى في الجامعات مدام إله ومدام راضي الطالب + +411 +00:37:18,810 --> 00:37:23,310 +أو الطالب أن يدرس فيها بده يلتزم بقوانين المفروض + +412 +00:37:23,310 --> 00:37:29,130 +عليه فكان يدخل الكنيسةو يقوم ب .. على الأقل إما + +413 +00:37:29,130 --> 00:37:33,570 +نتفرج عليهم و نتأثر بهم أو نشارك معهم في صلاوات + +414 +00:37:33,570 --> 00:37:40,000 +الأحد اللي يقيمونالنقطة السادسة و الأخيرة في هذا + +415 +00:37:40,000 --> 00:37:48,340 +المجال والأعمال، فضل نقطة و هذا + +416 +00:37:48,340 --> 00:37:52,960 +برك الله فيك و هذا يتأتى من خلال المعلم و المدرس + +417 +00:37:52,960 --> 00:37:59,040 +إنما يكون أو هو في طبيعته قدوة و أسوأفيقتضي به + +418 +00:37:59,040 --> 00:38:03,860 +الطالب والطالبة من خلال هذا الاقتداء يقوم هذا + +419 +00:38:03,860 --> 00:38:08,820 +المعلم او المعلمة بغرس المبادئ الغربية والسلوك + +420 +00:38:08,820 --> 00:38:12,700 +الغربي فتأثر الطالب والطالبة بمعلمه او الطالبة + +421 +00:38:12,700 --> 00:38:18,960 +بمعلمته بمعلمتها في هذا السن المبكر سواء في رياضة + +422 +00:38:18,960 --> 00:38:23,320 +الأطفال او المدارس او حتى فيما بعد بالجامعة + +423 +00:38:27,380 --> 00:38:34,720 +نكتفي بهذا القدر والحد من الحديث عن أول مجال + +424 +00:38:34,720 --> 00:38:39,780 +ووسيلة من وسائل التبشير وهي وسيلة التعليم أو مجال + +425 +00:38:39,780 --> 00:38:43,140 +التعليم لنكمل ان شاء الله في المحاضرة القادمة + +426 +00:38:43,140 --> 00:38:48,580 +الحديث عن باقي وسائل التبشير أو مجالات التبشير ان + +427 +00:38:48,580 --> 00:38:52,600 +شاء الله تعالى والسلام عليكم ورحمة الله وبركاته + diff --git a/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/QSnVmdG-xDg_raw.json b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/QSnVmdG-xDg_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..c7ae35fa31fdaf35d6ad9b6bef2431fbf36b4100 --- /dev/null +++ b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/QSnVmdG-xDg_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4919, "start": 21.31, "end": 49.19, 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"text": "طبعا ده حلو يراود أي زعيم أو يعني ملك أو حاكم أو قائد بدل ما يكون حاكم على قطعة صغيرة من الأرض بده يحكم قطعة كبيرة و يكون يعني حاكم على أكبر قدر من المساحة والأرض فوعدوا", "tokens": [9566, 3555, 3615, 995, 11778, 3224, 11331, 1211, 2407, 7251, 23557, 23328, 36632, 30767, 3615, 32640, 34051, 37495, 22653, 3714, 23275, 34051, 11331, 995, 24793, 34051, 12174, 16373, 3215, 47525, 1211, 19446, 7251, 30544, 11331, 995, 24793, 15844, 12174, 9566, 27884, 20328, 17082, 48923, 9154, 16247, 43042, 47525, 3224, 7251, 5016, 24793, 12174, 9566, 27884, 9122, 3555, 48923, 4032, 7251, 30544, 37495, 22653, 11331, 995, 24793, 15844, 5551, 4117, 26890, 12174, 3215, 2288, 9154, 9673, 3794, 39319, 3660, 16070, 10721, 43042, 6156, 2407, 22488, 14407], "avg_logprob": -0.12763444420903228, "compression_ratio": 1.89937106918239, "no_speech_prob": 0.0, "words": [{"start": 1381.39, "end": 1381.73, "word": "طبعا", "probability": 0.9307861328125}, {"start": 1381.73, "end": 1381.87, "word": " ده", 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00:00:09,390 +الحمد لله يا رب العالمين والصلاة والسلام على أشرف + +2 +00:00:09,390 --> 00:00:14,810 +الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحبه + +3 +00:00:14,810 --> 00:00:19,390 +أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت + +4 +00:00:19,390 --> 00:00:24,370 +العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما + +5 +00:00:24,370 --> 00:00:28,910 +علمتنا وازدنا علم أمين يا رب العالمين أما بعد + +6 +00:00:30,790 --> 00:00:38,150 +فموضوع محاضرتنا اليوم هو الليبرالية وهو مذهب من + +7 +00:00:38,150 --> 00:00:43,750 +المذاهب الاجتماعية الوافدة التي غزانا فيها الغرب + +8 +00:00:43,750 --> 00:00:49,370 +بأفكاره المتعددة سيكون حديثنا عن الليبرالية + +9 +00:00:49,370 --> 00:00:59,450 +المعناها والأسس التي والأسس التي تقوم عليهاوأثارها + +10 +00:00:59,450 --> 00:01:06,790 +وأختارها الاجتماعية والثقافية والسياسية وفي نهاية + +11 +00:01:06,790 --> 00:01:12,870 +الأمر سنبين حكم الإسلام في الليبرالي أولاً لابد من + +12 +00:01:12,870 --> 00:01:18,450 +معرفة أو تعريف الليبرالية الليبرالية كمصطلح معناه + +13 +00:01:18,450 --> 00:01:24,890 +أو هي عبارة عن فلسفة فكرية غربية وضعية أي من وضع + +14 +00:01:24,890 --> 00:01:29,890 +البشرتنزع إلى المادية يعني تميل إلى المادية + +15 +00:01:29,890 --> 00:01:37,870 +والفردية والتحرر من كل قيد أو ثابت إلا ثابت واحد + +16 +00:01:37,870 --> 00:01:44,390 +هو عدم الثبات إذا هي ليست ثابتة بل هي متحررة + +17 +00:01:44,390 --> 00:01:52,150 +ومتغيرة على الدوام وهي مصطلح أجنبي معرب مأخوذ من + +18 +00:01:52,150 --> 00:01:59,740 +اللفظ الأجنبي liberalismوتعني التحررية وهي بمعناها + +19 +00:01:59,740 --> 00:02:04,820 +الدقيق أن يكون الإنسان حرا حرية كاملة تمة في + +20 +00:02:04,820 --> 00:02:10,000 +المجالات المتعددة السياسية والاقتصادية والثقافية + +21 +00:02:10,000 --> 00:02:18,560 +وهناك تعريفات عديدة للبرالية مرتكز هذه التعريفات + +22 +00:02:18,560 --> 00:02:25,890 +يدور حول معنى الاستقلاليةومعناها التحرر التام من + +23 +00:02:25,890 --> 00:02:31,290 +كل أنواع الإكراه الخارجي من الدولة أو من الجماعة + +24 +00:02:31,290 --> 00:02:38,310 +أو من الأفراد هناك مصطلحات أخرى غير الليبرالية + +25 +00:02:38,310 --> 00:02:44,850 +تطلق على الليبرالية من الليبراليين أنفسهم أو من + +26 +00:02:44,850 --> 00:02:50,030 +أناس أطلقوا عليهم هذه المصطلحات أو الأسماء الأخرى + +27 +00:02:51,630 --> 00:02:55,230 +وأول هذه المصطلحات الاسم الدارج والمشهور + +28 +00:02:55,230 --> 00:03:00,730 +الليبرالية وأيضا من أسمائها العصرانية والعقلانية + +29 +00:03:00,730 --> 00:03:05,970 +والتنوير والفكر التجديدى فالليبرالية كما عرفناها + +30 +00:03:05,970 --> 00:03:12,970 +تدعو إلى الحرية المطلقة وعبادة الفرد نفسه وهواه + +31 +00:03:12,970 --> 00:03:19,050 +وشهوتاهوعبّر عنها أيضًا بالتفلت المطلق والحرية + +32 +00:03:19,050 --> 00:03:26,150 +المطلقة التي لا تتقيد بدين ولا تعترف بدين أما + +33 +00:03:26,150 --> 00:03:36,070 +العصرانية فهي من العصر وذلك لأنها تطوّع وتحور نصوص + +34 +00:03:36,070 --> 00:03:42,070 +الشريعة وأحكام وأحكامها لتتوافق مع مستجدات العصر + +35 +00:03:42,070 --> 00:03:47,440 +ولذلك يقال عنها بالعصرانيةوالمصطلح الثالث + +36 +00:03:47,440 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00:05:07,620 +بشريعة من أحد لا من الله ولا من غير اللهوهنا سؤال + +49 +00:05:07,620 --> 00:05:14,920 +يُطرح أن الليبرالية تزعم أنه لا يوجد حق مطلق إلا + +50 +00:05:14,920 --> 00:05:22,240 +الحرية والتغيير فماذا يقصدون بذلك حينما ينفون أن + +51 +00:05:22,240 --> 00:05:26,560 +يكون هناك حق مطلق إلا الحرية التي يدعونها ويدعون + +52 +00:05:26,560 --> 00:05:31,960 +إليها والتغيير الذي يسعون إليه الجواب أنهم يقصدون + +53 +00:05:31,960 --> 00:05:39,290 +بذلكالكفر بثوابت القرآن والسنة وأحكام الشريعة التي + +54 +00:05:39,290 --> 00:05:46,350 +هي بالنسبة لنا كمسلمين حق مطلق فهم لا يعتبرون أن + +55 +00:05:46,350 --> 00:05:54,950 +هناك حق مطلق إلا الحرية والتغيير الذي يدعون إليه + +56 +00:05:54,950 --> 00:05:59,190 +والليبرالية أيضا تسوي بين الإسلام وغيره من المذاهب + +57 +00:05:59,190 --> 00:06:05,530 +الباطلةوماذا يقصدون من وراء هذه التسوية؟ يقصدون + +58 +00:06:05,530 --> 00:06:13,410 +تشريع شريعة من عندهم ومن عند أنفسهم تناقض شريعة + +59 +00:06:13,410 --> 00:06:19,670 +الله تعالى الذي يقول إن الدين عند الله الإسلام فهم + +60 +00:06:19,670 --> 00:06:23,770 +يساوون بين الإسلام الذي هو الدين الحق عند الله مع + +61 +00:06:23,770 --> 00:06:30,830 +المذاهب الباطلة الأخرىوالليبرالية هي الوجه الآخر + +62 +00:06:30,830 --> 00:06:36,710 +للعلمانية التي في حقيقتها فصل الدين عن الحياة + +63 +00:06:36,710 --> 00:06:41,810 +وجوانب الحياة ومجالات الحياة كلها فالليبرالية هي + +64 +00:06:41,810 --> 00:06:47,480 +الاسم الآخر والوجه الآخر لنفس العملةفلا يقيموا + +65 +00:06:47,480 --> 00:06:53,240 +الليبراليون أي وزن لشريعة الله تعالى إذا ناقض + +66 +00:06:53,240 --> 00:07:00,640 +التصويت الديمقراطي أحكام الشريعة حتى لو كانت نتيجة + +67 +00:07:00,640 --> 00:07:07,800 +التصويت عدم تحريم ما حرم اللهمثل الزنا، الشرب + +68 +00:07:07,800 --> 00:07:12,320 +الخمر، الربة، فإذا كانت نتيجة التصويت عدم تحريم + +69 +00:07:12,320 --> 00:07:18,200 +الزنا وعدم تحريم أو تجريم الشرب الخمر وعدم تحريم + +70 +00:07:18,200 --> 00:07:25,540 +الربة أو تحليل الربة فهم مع التصويت الديمقراطي + +71 +00:07:25,540 --> 00:07:28,060 +وحكم الأغلبية + +72 +00:07:30,950 --> 00:07:34,710 +ما هي الأسس التي تقوم عليها الليبرالي؟ الليبرالية + +73 +00:07:34,710 --> 00:07:41,690 +تقوم على أسس ثلاثة هي الحرية الفردية العقلانية هذه + +74 +00:07:41,690 --> 00:07:46,450 +هي الأسس الثلاثة التي تقوم عليها الليبرالي الأساس + +75 +00:07:46,450 --> 00:07:51,630 +الأول الحرية فماذا تعني الحرية عند الليبراليين؟ + +76 +00:07:52,600 --> 00:07:57,860 +تعني أن الفرد حر في أفعاله ومستقل في تصرفاته دون + +77 +00:07:57,860 --> 00:08:04,080 +أي تدخل من الدولة أو من غيرها فوظيفة الدولة هي + +78 +00:08:04,080 --> 00:08:09,780 +حماية هذه الحرية وتوسيعها وتعزيز الحقوق واستخلال + +79 +00:08:09,780 --> 00:08:17,520 +السلطات هذا هو الأساس الأول الحرية الأساس الثاني + +80 +00:08:17,520 --> 00:08:23,010 +الفرديةوماذا تعني عندهم الفردية؟ تعني استقلال + +81 +00:08:23,010 --> 00:08:30,450 +الفرد وحريته وقد جاءت هذه الفردية بمفهومين مختلفين + +82 +00:08:30,450 --> 00:08:38,580 +فما هما هذان المفهومان أحدهمابمعنى الأنانية + +83 +00:08:38,580 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+00:09:52,600 --> 00:09:58,200 +الليبرالية على العالم الإسلامي أولا ألغى الحكم + +96 +00:09:58,200 --> 00:10:03,040 +بالشريع الإسلامي واستبدله بالقوانين الوضعية ثانيا + +97 +00:10:03,040 --> 00:10:07,760 +قضى على التعليم الإسلامي وغير مناهجه وبنى المدارس + +98 +00:10:07,760 --> 00:10:14,660 +الأجنبية لتقبل الليبرالي ليقبل العالم الإسلامي + +99 +00:10:14,660 --> 00:10:20,140 +بالليبرالي ثالثا قام بتقوية الطواقف والمذاهب غير + +100 +00:10:20,140 --> 00:10:26,740 +الإسلامية باسم حقوق الأقليات وهذا العمل وغيره يبدو + +101 +00:10:27,970 --> 00:10:34,610 +غطاءه الظاهر لحماية الحريات ونبذ الطائفية والتعصب + +102 +00:10:34,610 --> 00:10:42,330 +لكن الباطن والهدف والحقيقة هي إبراز هذه الطواقف + +103 +00:10:42,330 --> 00:10:52,230 +الأقليات وتوليتهم على المسلمين وأيضا الولايات + +104 +00:10:52,230 --> 00:10:57,490 +المتحدة الأمريكية اهتمتبتفسير الإسلام تفسيراً + +105 +00:10:57,490 --> 00:11:04,370 +لبرالياً لماذا هذا الاهتمام؟ لماذا يريد الأمريكان + +106 +00:11:04,370 --> 00:11:09,750 +أن يفسروا الإسلام تفسيراً لبراليا؟ هناك سببان في + +107 +00:11:09,750 --> 00:11:16,210 +ذلك الأول لأن ذلك يحقق كثيرا من المصالح الحيوية + +108 +00:11:16,210 --> 00:11:21,520 +للهيمنة والسيطرة الأمريكيةلأنها تعلم أن إقصاء وعزل + +109 +00:11:21,520 --> 00:11:27,000 +الإسلام أمر مستحيل لقوة تأثير الإسلام فوجدت في + +110 +00:11:27,000 --> 00:11:33,340 +تحريفه أنجح السبب للقضاء على تأثيره وفعليته هذا + +111 +00:11:33,340 --> 00:11:38,020 +السبب الأول السبب الثاني لأن تفسير الإسلام تفسيراً + +112 +00:11:38,020 --> 00:11:43,990 +لبراليايقوي علاقة بلاد المسلمين وشعوب المسلمين + +113 +00:11:43,990 --> 00:11:49,110 +بالحضارة الغربية وقيمها مما يضمن عملية استمرار + +114 +00:11:49,110 --> 00:11:54,910 +الخضوع لها والاهداف الحقيقية لهذا المشروع الأمريكي + +115 +00:11:54,910 --> 00:12:02,080 +لفرضأو ليه تفسير الإسلام تفسيراً لبراليا يمكنوا + +116 +00:12:02,080 --> 00:12:09,040 +بيانه من خلال الأمور التالية أولا عادة ترتيب أوضاع + +117 +00:12:09,040 --> 00:12:15,560 +المنطقة لتتقبل النموذج الليبرالي في الشأن السياسي + +118 +00:12:15,560 --> 00:12:20,760 +اللي هو الديمقراطي وفي الشأن الاقتصادي في النظام + +119 +00:12:20,760 --> 00:12:28,120 +الرأسمالي الأمريكي الغربي الأوروبا ثانياتهيأت + +120 +00:12:28,120 --> 00:12:34,380 +المنطقة للعولمة ودخول الشركات الغربية في أسواقها + +121 +00:12:34,380 --> 00:12:40,560 +لزيادة الكسب والربح المادى ثالثا من الأهداف + +122 +00:12:40,560 --> 00:12:45,100 +الحقيقية لهذا المشروع العمل على تطبيع العلاقات بين + +123 +00:12:45,100 --> 00:12:51,220 +الكيان الصهيوني ودول المنطقة لتتقبل دول المنطقة + +124 +00:12:51,220 --> 00:12:55,720 +الكيان الصهيوني وتتعامل وتتعاون معاه + +125 +00:13:01,230 --> 00:13:05,870 +تميز طيار الليبراليين في بلاد المسلمين عن باق + +126 +00:13:05,870 --> 00:13:10,470 +الطيارات الليبرالية الأخرى بعدد أمور ما هي هذه + +127 +00:13:10,470 --> 00:13:14,950 +الأمور التي تميز بها طيار الليبراليين في بلاد + +128 +00:13:14,950 --> 00:13:22,370 +المسلمين في هناك ستة أمور الأمر الأول الوقوف في صف + +129 +00:13:22,370 --> 00:13:27,380 +المشروع الأمريكي في المنطقةوالمطالبة بما يريده + +130 +00:13:27,380 --> 00:13:33,600 +ويسعى إليه إذا الاصطفاف مع المشروع الأمريكي مثل + +131 +00:13:33,600 --> 00:13:38,480 +تغيير مناهج التعليم واستخدام القوة العسكرية لتغيير + +132 +00:13:38,480 --> 00:13:43,980 +الأنظمة كما نرا حاليا في واقع بلاد المسلمين وفرض + +133 +00:13:43,980 --> 00:13:51,140 +الديمقراطية التي يتشدق بها الغرب والأمريكانثانيا + +134 +00:13:51,140 --> 00:13:57,140 +مما يميز هذا التيار في بلاد المسلمين تطبيق مقاييس + +135 +00:13:57,140 --> 00:14:04,720 +النقد الغربي على نصوص الوحي الإلهي وإخضاع الوحي + +136 +00:14:04,720 --> 00:14:13,140 +للمنطق العقلاني يريدون أن يطبقوا النقد الذي + +137 +00:14:13,140 --> 00:14:15,580 +يوجهونه إلى أي + +138 +00:14:20,340 --> 00:14:26,520 +شعر أو نثر أو أدب أو لأي مجال من مجالات النقد يخضع + +139 +00:14:26,520 --> 00:14:32,340 +الوحي ونصوص الوحي لهذا النقد وكأن الوحي أيضا جهد + +140 +00:14:32,340 --> 00:14:36,120 +بشري أو مثل الجهد البشري الذي يخضع للنقد طبعا هذا + +141 +00:14:36,120 --> 00:14:40,800 +كلام الله عز وجل الذي لا يأتيه الباطل من بين يديه + +142 +00:14:40,800 --> 00:14:45,320 +ولا من خلفه فلا يجوز أن نخضعه لهذه المقاييس + +143 +00:14:45,320 --> 00:14:52,080 +البشريةلما يفعله البشر من نقد لنصوص الشعر أو النثر + +144 +00:14:52,080 --> 00:14:59,120 +أو الأدب أو غيرها من مجلة النقدأيضًا مما يتميز به + +145 +00:14:59,120 --> 00:15:03,960 +الليبراليون في بلاد المسلمين رفض العداء لغير + +146 +00:15:03,960 --> 00:15:07,460 +المسلمين لا يريدون مننا كمسلمين أن نعادي غير + +147 +00:15:07,460 --> 00:15:12,060 +المسلمين واعتبار أن ذلك نتيجة لظروف سياسية + +148 +00:15:12,060 --> 00:15:18,720 +واجتماعية فيريدون من المسلمين أن يتقبلوا الكفار + +149 +00:15:18,720 --> 00:15:25,140 +والفكر الغربي يعني بلا نقاشأيضًا مما يتميز به + +150 +00:15:25,140 --> 00:15:31,240 +هؤلاء الليبراليون في بلاد المسلمين اعتبار الأحكام + +151 +00:15:31,240 --> 00:15:37,600 +الشرعية أحكامًا وضعت في زمان معين ومكان معين + +152 +00:15:37,600 --> 00:15:43,640 +وانتهى دورها وانتهت صلاحيتها وليست أحكامًا دائمة + +153 +00:15:43,640 --> 00:15:53,610 +أبدًا خامسًا رفض الإرتباط بالإسلام واعتبارهماضي + +154 +00:15:54,670 --> 00:16:00,070 +سابق وقد عفى عليه الزمن وانتهى وأن الموجود عبارة + +155 +00:16:00,070 --> 00:16:04,090 +عن فكر علماء الدين ليس هذا هو الإسلام، الإسلام كان + +156 +00:16:04,090 --> 00:16:08,190 +قديما وزمان وعفى عليه الزمن ولسنا بحاجة اليه + +157 +00:16:08,190 --> 00:16:14,850 +اليوم، وهم يُعرف بمفهوم الحادثة كما يعني هذا الفكر + +158 +00:16:14,850 --> 00:16:18,830 +الغربي، الفكر الحادثة أنهم يؤمنون بكل شيء جديد + +159 +00:16:18,830 --> 00:16:26,190 +ويرفضون الإرتباط بكل ما هو ماضي وقديمسادسا من ما + +160 +00:16:26,190 --> 00:16:31,350 +يتميز به الليبراليون الشعوبية وكره .. و .. و + +161 +00:16:31,350 --> 00:16:38,510 +كراهية العرب واتهامهم بالجهل و بكل أنواع النقائص و + +162 +00:16:38,510 --> 00:16:44,690 +ذكر مثالبهم و نقائصهم و طبعا دي ظاهرة الإسقاط أن + +163 +00:16:44,690 --> 00:16:48,950 +هم في النهاية اللي .. اللي بيفهموا و هم أهل العلم + +164 +00:16:48,950 --> 00:16:54,520 +و أهل العقلوأهل التقدم والتطور دول العرب ناس لا + +165 +00:16:54,520 --> 00:17:03,720 +يفهمون ولا يتعلمون ولا يتطورون ولا يتقدمون ليه + +166 +00:17:03,720 --> 00:17:09,120 +الليبرالية أثار وأخطار على المسلمين وعلى دين + +167 +00:17:09,120 --> 00:17:15,080 +الإسلام وهي أثار وأخطار متعددة منها ما هو عقدي + +168 +00:17:15,080 --> 00:17:21,410 +ومنها ما هو اجتماعي وأخلاقي ومنها ما هو سياسيأولا + +169 +00:17:21,410 --> 00:17:25,990 +الأثار العقدية من الأثار العقدية لهذا الفكر + +170 +00:17:25,990 --> 00:17:32,110 +التشكيك في العقيدة الإسلامية الصحية يريدون تشكيك + +171 +00:17:32,110 --> 00:17:37,010 +المسلمين في عقيدتهم الصحية فنجد حتى من أبناء + +172 +00:17:37,010 --> 00:17:41,910 +المسلمين اليوم فنجد من أبناء المسلمين اليوم من يصف + +173 +00:17:41,910 --> 00:17:49,190 +النصارى مثلا بأنهم مؤمنون أو مسلمون أو موحدونوهذا + +174 +00:17:49,190 --> 00:17:52,930 +فيه تشكيك في العقيدة الصحيحة وكأنه كل من يحمي + +175 +00:17:52,930 --> 00:17:58,670 +العقيدة هو مؤمن مسلم على الحق ولا يفرقون بين + +176 +00:17:58,670 --> 00:18:03,450 +المسلم المؤمن أو الدين والعقيدة السليمة الصحيحة + +177 +00:18:03,450 --> 00:18:07,050 +وهي دين الإسلام الذي ارتضاه الله تعالى في قوله إن + +178 +00:18:07,050 --> 00:18:11,950 +الدين عند الله الإسلام ونفى أن يكون غير الإسلام + +179 +00:18:11,950 --> 00:18:17,330 +مقبولا ومن يبتغي غير الإسلام دينا فلن يقبل منه + +180 +00:18:18,610 --> 00:18:23,110 +أيضًا من هذه الأثار القطيعة تامة مع مصادر التلقي + +181 +00:18:23,110 --> 00:18:28,170 +والاستدلال عند المسلمين فهم لا يأخذون لا من القرآن + +182 +00:18:28,170 --> 00:18:34,450 +ولا من السنة ويريدون من المسلمين أن يتخلّوا عن هذه + +183 +00:18:34,450 --> 00:18:40,410 +المصادر الأمر الثالث إحياء التراث الفلسفي + +184 +00:18:40,410 --> 00:18:47,360 +الاعتزاليوتقريبه للناس في قالب جميل لأنه يعتمد على + +185 +00:18:47,360 --> 00:18:53,720 +العقل وعلى الفكر وبعيدا عن النصوص والوحي رابعا + +186 +00:18:53,720 --> 00:18:58,940 +موقفهم من التاريخ الإسلامي يشويهون التاريخ + +187 +00:18:58,940 --> 00:19:05,840 +الإسلامي ويشنون حملات تزوير وتشويه للتاريخ + +188 +00:19:05,840 --> 00:19:13,200 +الإسلاميخامسا الهزيمة النفسية أمام الأعداء + +189 +00:19:13,200 --> 00:19:17,960 +فالليبراليون العرب يريدون أن يغرسوا هذه الهزيمة + +190 +00:19:17,960 --> 00:19:25,620 +النفسية في أفراد الأمة ويثبتوا أن العرب والمسلمين + +191 +00:19:25,620 --> 00:19:33,060 +ليسوا في مصاف أهل الحضارة وأهل العلم وأهل التقدم + +192 +00:19:33,060 --> 00:19:43,560 +الغربيينيعني مهزومون ومتخلفون أمام التقدم والتطور + +193 +00:19:43,560 --> 00:19:48,600 +الذي عليه الغرض فكذا يريدون أن يقذفوا في روع + +194 +00:19:48,600 --> 00:19:54,500 +المسلمين وهذا الأمر الذي يريدون غرسه في أفراد + +195 +00:19:54,500 --> 00:20:00,500 +الأمة من خلال عدة أمور من هذه الأمور هدم حاجز + +196 +00:20:00,500 --> 00:20:06,380 +الولاء والبراءالذي يقوم عليه الإيمان، الإيمان يقوم + +197 +00:20:06,380 --> 00:20:11,280 +على الولاء والبراء، فلبد من الولاء للمؤمنين + +198 +00:20:11,280 --> 00:20:15,480 +والبراء من الكافرين، هم لا يريدون هذا التمييز و + +199 +00:20:15,480 --> 00:20:21,480 +هذا الحاجز، يريدون أن يكون الناس جميعا في دينهم + +200 +00:20:21,480 --> 00:20:27,870 +وعقيدتهم سواءأيضا تلغاء الجهاد ووصف الجهاد + +201 +00:20:27,870 --> 00:20:32,330 +بالارهاب ووصف المجاهدين بالارهابيين وهم يقومون مع + +202 +00:20:32,330 --> 00:20:39,870 +أنهم يقومون بحق مشروع شراعته وكفلته لهم القوانين + +203 +00:20:39,870 --> 00:20:47,610 +الدولية فضلا عن الدين والإسلام والقرآن يعني الذي + +204 +00:20:47,610 --> 00:20:55,700 +شرع هذه الفريضة فريضة الجهاد ومقاومة المحتلينالأمر + +205 +00:20:55,700 --> 00:20:59,980 +الثالث الترويج بأن المسلمين متخلفون ولا يمكن أن + +206 +00:20:59,980 --> 00:21:05,720 +يتقدموا أبداً والانبهار بالغرب رغم تراجع الحضارة + +207 +00:21:05,720 --> 00:21:10,700 +الغربية الأمر الرابع إفساح المجال أمام التيارات + +208 +00:21:10,700 --> 00:21:18,760 +منحرفة بدعوى حرية الرأي وانفتاح على الآخر يشجعوا + +209 +00:21:18,760 --> 00:21:26,050 +أي تيار منحرفأي طيار عنده ضلال وانحراف وابتعاد عن + +210 +00:21:26,050 --> 00:21:30,490 +العقيدة الإسلامية الصحيحة يدعم مثل هذه الطيارات و + +211 +00:21:30,490 --> 00:21:36,110 +هذه الأفكار بحجة حرية الرأي الأمر الخامس الارتماء + +212 +00:21:36,110 --> 00:21:41,870 +في أحضان الأعداء وتقليدهم وتقبل الغزو الفكري بحجة + +213 +00:21:41,870 --> 00:21:47,130 +صحة هذه الأديان كما قلنا عندهم أن الدين واحد ولا + +214 +00:21:47,130 --> 00:21:54,150 +فرق بين الإسلام وغيره من الأديان الأخرىهذه الأثار + +215 +00:21:54,150 --> 00:22:00,510 +العقدية الخطيرة التي تحدثنا عنها سابقاً أيضاً من + +216 +00:22:00,510 --> 00:22:05,230 +الأثار المترتبة على هذا الفكر الأثار الأخلاقية + +217 +00:22:05,230 --> 00:22:11,210 +والاجتماعية وعلى رأسها إفساد المرأة المسلمة فهم + +218 +00:22:11,210 --> 00:22:17,430 +يركزون في فكرهم على المرأة وحرية المرأة فهذا الفكر + +219 +00:22:17,430 --> 00:22:23,430 +معناه باختصار الحرية المطلقةللرجل والمرأة لأن + +220 +00:22:23,430 --> 00:22:29,210 +المرأة حرة في أن تفعل ما تشاء وبالتالي من أثار + +221 +00:22:30,220 --> 00:22:33,660 +الليبرالية من ناحية الأخلاقية والاجتماعية إفساد + +222 +00:22:33,660 --> 00:22:39,880 +المرأة المسلمة وجعلها دمية يتلاعب بها المنحرفون + +223 +00:22:39,880 --> 00:22:44,620 +سلوكيا وأخلاقيا أيضا من الأثار الأخلاقية + +224 +00:22:44,620 --> 00:22:51,100 +والاجتماعية طمس معالم الأخلاق الإسلامية عن طريق + +225 +00:22:51,100 --> 00:22:55,640 +نشر الإنحلال والتفسق الأخلاقي وقد فتح هذا الفكر + +226 +00:22:55,640 --> 00:23:02,370 +الباب على مسرعي لدعاة التغريبتلاتة ماتت واضعاف + +227 +00:23:02,370 --> 00:23:08,630 +جانب الأمر بالمعروف والنهي عن المنكر بحجة الحرية + +228 +00:23:08,630 --> 00:23:13,510 +فالناس أحرار أن يفعلوا ما يريدون وما يشاءون فلا + +229 +00:23:13,510 --> 00:23:18,010 +داعي لأمرهم أو نهيهم عن ما يفعلونه + +230 +00:23:20,760 --> 00:23:26,240 +أيضًا من الأثار لهذا الفكر الأثار السياسية وأخطر + +231 +00:23:26,240 --> 00:23:31,420 +هذه الأثار السياسية عزل الشريعة الإسلامية وإقصاءها + +232 +00:23:31,420 --> 00:23:39,080 +عن الدولة والحكم وعن الحياب الكليوحصر هذه الشريعة + +233 +00:23:39,080 --> 00:23:42,480 +و هذا الدين و هذا الإسلام في المسجد في العبادات + +234 +00:23:42,480 --> 00:23:48,120 +الشخصية وهذا هو مفهوم العلمانية كما قلنا سابقا أن + +235 +00:23:48,120 --> 00:23:53,620 +الليبرالية هي الوجه الآخر للعلمانية + +236 +00:23:53,620 --> 00:24:00,610 +التي تعني اللا دينية فجاءت الليبراليةكاسم ومصطلح + +237 +00:24:00,610 --> 00:24:07,230 +جديد ولكن في جوهرها وفي معناها نفس معنى العلمانية + +238 +00:24:07,230 --> 00:24:14,810 +التي تعني اللادينية أو فصل الدين عن الحياة فالدعوة + +239 +00:24:14,810 --> 00:24:18,030 +الليبرالية في حقيقتها هي العلمانية وانوجد + +240 +00:24:23,400 --> 00:24:29,000 +وإن وجد فاصل بينهم فهو فاصل رقيق جدا وكما قلنا + +241 +00:24:29,000 --> 00:24:35,990 +كأنهم وجهان لعملة واحدة أو اسمان لمسمة واحدةالأثر + +242 +00:24:35,990 --> 00:24:42,870 +الثاني الولاء للفكر الغربي والاستقواء بالأجنبي + +243 +00:24:42,870 --> 00:24:47,810 +الآن ما نشاهده في عالمنا الإسلامي وفي دولنا هناك + +244 +00:24:47,810 --> 00:24:54,850 +ولاء تام للغرب والاستقواء بالغرب والتحالف من قبل + +245 +00:24:54,850 --> 00:25:01,090 +الحكام والأنظمة العربية والإسلامية مع العالم + +246 +00:25:01,090 --> 00:25:09,860 +الغربي والأجنبيأخر ما نتحدث عنه في الليبرالية + +247 +00:25:09,860 --> 00:25:17,280 +الحكم الشرعي في الليبرالية كفكر وافد على الإسلام + +248 +00:25:17,280 --> 00:25:23,560 +والمسلمين فكما قلنا هذه فكرة غربية مستوردة وليست + +249 +00:25:23,560 --> 00:25:29,180 +من إنتاج المسلمين وهي تنفي ارتباطها بالأديان كلهاو + +250 +00:25:29,180 --> 00:25:35,100 +تعتبر كافة الأديان قيودا ثقيلة على الحريات فلابد + +251 +00:25:35,100 --> 00:25:41,710 +من التخلص منهاومحاولة التوفيق بين الليبرالية + +252 +00:25:41,710 --> 00:25:47,610 +والإسلام لمن يريد أن يوفق بين الليبرالية والإسلام + +253 +00:25:47,610 --> 00:25:54,530 +هي في الحقيقة تغيير لمفهوم كل واحد منهما هناك + +254 +00:25:54,530 --> 00:26:00,250 +مفهوم خاص للليبرالية ومفهوم خاص للإسلام وهذا + +255 +00:26:00,250 --> 00:26:06,550 +المفهوم يختلف تماما وبالكلية عن هذا المفهومواذا + +256 +00:26:06,550 --> 00:26:10,350 +هذه المحاولة أن نوفق بين الليبرالية والإسلام هذا + +257 +00:26:10,350 --> 00:26:16,370 +تغيير لمفهوم كل واحد منهما وتبديل لمعناه فيخرج عن + +258 +00:26:16,370 --> 00:26:23,470 +حقيقته إلى مفهوم مشوّى وبالتالي فسنبين أن + +259 +00:26:23,470 --> 00:26:28,110 +الليبرالية تعني في الإسلام أنواع متعددة من الكفر + +260 +00:26:28,110 --> 00:26:35,070 +والشرك المناقض لحقيقة الإسلام والدين فالذي يدرس + +261 +00:26:35,070 --> 00:26:38,410 +الليبرالية هيش أنها دعوة إلى الإلحاد ورفض الأديان + +262 +00:26:38,410 --> 00:26:43,860 +وعدم التقيد بالأديانوعدم الاحتكام إلى شريعة + +263 +00:26:43,860 --> 00:26:49,320 +الأديان حيث لا تعترف بهيمنة الدين على الحياة + +264 +00:26:49,320 --> 00:26:56,440 +الإنسانية لأنها تعطي الفرد الحرية الكاملة والمطلقة + +265 +00:26:56,440 --> 00:27:03,060 +بالتحلل من أي قيود حتى لو كانت قيود الدين أو القيم + +266 +00:27:03,060 --> 00:27:11,300 +والأخلاقفأساس الفكرة قائم على تعظيم العقل الإنساني + +267 +00:27:11,300 --> 00:27:18,620 +ولهذا ارتبطت عبارة الفكر الحر بالليبرالية التي + +268 +00:27:18,620 --> 00:27:21,800 +تعني الفكر الحر والإنسان حر والحرية التامة الحرية + +269 +00:27:21,800 --> 00:27:28,300 +المطلقة للإنسان وعليه فإن الليبرالية لا تتفق مع + +270 +00:27:28,300 --> 00:27:33,970 +الإسلاموهي ترى أن الدين لا دخل له في الحكم ولا في + +271 +00:27:33,970 --> 00:27:39,230 +السياسة ولا في المجتمع وأن الإنسان هو إله نفسه وهو + +272 +00:27:39,230 --> 00:27:46,850 +حر في تصرفاته الحرية التامة المطلقة والسلام عليكم + +273 +00:27:46,850 --> 00:27:48,930 +ورحمة الله وبركاته + diff --git a/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/UWRW1qbseLI.srt b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/UWRW1qbseLI.srt new file mode 100644 index 0000000000000000000000000000000000000000..4517e71487c803ea68608a5ad30a3c5f36fc406d --- /dev/null +++ b/PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/UWRW1qbseLI.srt @@ -0,0 +1,679 @@ +1 +00:00:05,080 --> 00:00:08,760 +الحمد لله رب العالمين والصلاة والسلام على أشرف + +2 +00:00:08,760 --> 00:00:13,820 +الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحبه + +3 +00:00:13,820 --> 00:00:18,120 +أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت + +4 +00:00:18,120 --> 00:00:22,640 +العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما + +5 +00:00:22,640 --> 00:00:27,080 +علمتنا وازدنا علماً آمين يا رب العالمين أما بعد + +6 +00:00:27,080 --> 00:00:32,800 +فهذه هي المحاضرة الثانية بعد الأولى التي تحدثنا + +7 +00:00:32,800 --> 00:00:38,890 +فيها عن مفردات المساق، مساق حاضر العالم الإسلامي + +8 +00:00:38,890 --> 00:00:44,630 +وقولنا في نهاية المحاضرة الأولى أننا سنتحدث في + +9 +00:00:44,630 --> 00:00:50,290 +المحاضرة الثانية وهي أولى المحاضرات يعني فعلياً + +10 +00:00:50,290 --> 00:00:55,350 +بالنسبة للمادة والكتاب سنتحدث عن المجتمع الإسلامي + +11 +00:00:55,350 --> 00:01:01,550 +وخصائص المجتمع الإسلامي قبل التعرف على معنى المجتمع + +12 +00:01:01,550 --> 00:01:07,170 +الإسلامي لابد من التعرف على أو تعريف المجتمع بصورة + +13 +00:01:07,170 --> 00:01:11,710 +عامة فالمجتمع هو مجموعة من الناس تعيش على شكل + +14 +00:01:11,710 --> 00:01:17,570 +جماعة منظمة تحكمها مجموعة قوانين وأحكام وتشريعات + +15 +00:01:17,570 --> 00:01:24,180 +وأعراف وتقاليد وبيشتركوا في موقع جغرافي واحد هنا + +16 +00:01:24,180 --> 00:01:28,480 +كده التعريفات للمجتمع و أيضاً من التعريفات جماعة من + +17 +00:01:28,480 --> 00:01:32,480 +الناس بيعيشوا في منطقة واحدة أو معينة تجمع بينهم + +18 +00:01:32,480 --> 00:01:38,320 +ثقافة مشتركة ويشعرون بالوحدة فيما بينهم ككيان + +19 +00:01:38,320 --> 00:01:44,150 +متميز إلى غير ذلك من التعريفات الأخرى ما يهمنا هو + +20 +00:01:44,150 --> 00:01:49,130 +تعريف المجتمع الإسلامي تحديداً فالمجتمع الإسلامي + +21 +00:01:49,130 --> 00:01:55,810 +متميز عن باقي المجتمعات الأخرى بما يحمله من خصائص + +22 +00:01:55,810 --> 00:02:01,650 +سنتعرف عليها بعد قليل فهو مجتمع يتميز عن باقي + +23 +00:02:01,650 --> 00:02:06,620 +المجتمعات الأخرى بتصوره الخاص وقوانينه الخاصة + +24 +00:02:06,620 --> 00:02:13,100 +وأحكامه التي يستمدها من القرآن والسنة وأفراد + +25 +00:02:13,100 --> 00:02:20,540 +المجتمع يشتركون بعقيدة واحدة ويتوجهون إلى قبلة + +26 +00:02:20,540 --> 00:02:28,050 +واحدة مهما تعددت أجناسهم وأعراقهم ولغاتهم ولا يخدش + +27 +00:02:28,050 --> 00:02:35,130 +هذه الصورة للمجتمع المسلم انحراف بعض أفراده عن + +28 +00:02:35,130 --> 00:02:42,170 +الخط المستقيم فالعبرة بالمجتمع الإسلامي بالمبادئ + +29 +00:02:42,170 --> 00:02:47,480 +العامة للمجتمع الإسلامي أما الواقع الذي يعيشه + +30 +00:02:47,480 --> 00:02:53,800 +المجتمع الإسلامي قد يختلف بعضه أو يخالف بعض أفراد + +31 +00:02:53,800 --> 00:02:58,160 +المجتمع الإسلامي يخالف هذه المبادئ فهم ليسوا حجة + +32 +00:02:58,160 --> 00:03:03,980 +على الإسلام ولا على خصائص المجتمع الإسلامي المفترض + +33 +00:03:03,980 --> 00:03:10,380 +أن تكون في المسلمين هنا + +34 +00:03:10,380 --> 00:03:17,490 +مميزات وخصائص يتميز المجتمع الإسلامي عن غيره من + +35 +00:03:17,490 --> 00:03:24,250 +المجتمعات أولى هذه الخصائص وأهم هذه الخصائص التصور + +36 +00:03:24,250 --> 00:03:31,600 +الاعتقادي الصحيح ما لا نجده في المجتمعات الأخرى غير + +37 +00:03:31,600 --> 00:03:37,000 +الإسلامية المجتمع الإسلامي يتميز بأن تصوره + +38 +00:03:37,000 --> 00:03:43,180 +الاعتقادي تصور صحيح سليم عن الله تعالى وعن ما يجب + +39 +00:03:43,180 --> 00:03:50,020 +لله تعالى أن هذا الإله واحد لا شريك له واحد في + +40 +00:03:50,020 --> 00:03:57,480 +ربوبيته فلا رب أي خالق سواه وواحد في ألوهيته أي لا + +41 +00:03:57,480 --> 00:04:03,800 +معبود بحق سواه وواحد في أسمائه الحسنى وصفاته + +42 +00:04:03,800 --> 00:04:08,340 +العليا أي لا يشاركه أحد من مخلوقاته بهذه الأسماء + +43 +00:04:08,340 --> 00:04:14,960 +الحسنى وهذه الصفات العليا العليا فهو كما وصف نفسه + +44 +00:04:14,960 --> 00:04:20,800 +ليس كمثله شيء وهو السميع البصير وقال أيضاً و لله + +45 +00:04:20,800 --> 00:04:27,200 +الأسماء الحسنى فدعوه بها هذه أول خاصية وميزة تميز + +46 +00:04:27,200 --> 00:04:32,240 +المجتمع الإسلامي عن باقي المجتمعات الأخرى هناك + +47 +00:04:32,240 --> 00:04:38,880 +خاصية أخرى هذه الخاصية هي الحاكمية في المجتمع + +48 +00:04:38,880 --> 00:04:46,080 +المسلم لله تعالى وحده فالله تعالى يقول إن الحكم + +49 +00:04:46,080 --> 00:04:53,830 +إلا لله إن الحكم إلا لله حصر وقصر إن بمعنى ما أو + +50 +00:04:53,830 --> 00:05:00,970 +ليس أداة نفي أي ليس أو ما الحكم إلا لله تعالى فحصل + +51 +00:05:00,970 --> 00:05:10,190 +الله تعالى الحكم له وحده وأيضاً على من يريد أن + +52 +00:05:10,190 --> 00:05:15,690 +يحتكم إلى حكم الجاهلية بقوله أفحكم الجاهلية يبغون + +53 +00:05:15,690 --> 00:05:22,930 +ومن أحسن من الله حكماً لقوم يوقنون فالمسلم الحق + +54 +00:05:22,930 --> 00:05:27,070 +والمجتمع المسلم يحتكم إلى الله تعالى في جميع + +55 +00:05:27,070 --> 00:05:33,030 +أحكامه وأحواله فالتشريع والحكم وسلطة التشريع والحكم + +56 +00:05:33,030 --> 00:05:37,410 +في المجتمع المسلم لله تعالى واحد فالحلال هو ما حله + +57 +00:05:37,410 --> 00:05:41,730 +الله ورسوله والحرام هو ما حرمه الله ورسوله ولا + +58 +00:05:41,730 --> 00:05:47,490 +يملك أحد من الناس مهما كان أن يشرع للناس من نفسه + +59 +00:05:47,490 --> 00:05:52,530 +وحسب هواه والمسلمون في المجتمع الإسلامي وظيفتهم هي + +60 +00:05:52,530 --> 00:05:58,380 +تنفيذ حكم الله تعالى وحتى العلماء لا يحرمون ولا + +61 +00:05:58,380 --> 00:06:04,380 +يحلون بل وظيفتهم وواجبهم أن يبينوا للناس حكم الله + +62 +00:06:04,380 --> 00:06:11,560 +تعالى الخاصية الثالثة من خصائص المجتمع الإسلامي أن + +63 +00:06:11,560 --> 00:06:18,840 +التجمع في هذا المجتمع على أساس رابطة العقيدة هناك + +64 +00:06:19,990 --> 00:06:25,470 +المجتمعات الأخرى غير الإسلامية تتجمع فيما بينها + +65 +00:06:25,470 --> 00:06:32,270 +على أواصر وروابط لكن هذه الروابط والأواصر التي + +66 +00:06:32,270 --> 00:06:38,570 +تجمعهم هي روابط وأواصر مادية دنيوية مصلحية ممكن أن + +67 +00:06:38,570 --> 00:06:43,090 +نجتمع على مصالح فيما بينهم لكن المجتمع المسلم + +68 +00:06:43,090 --> 00:06:49,570 +يتميز عن باقي المجتمعات الأخرى أن الرابط التي تجمع + +69 +00:06:49,570 --> 00:06:55,730 +بين أفراده هي رابطة الدين رابطة العقيدة رابطة + +70 +00:06:55,730 --> 00:07:01,110 +الإيمان وهذا أيضاً ما بينه القرآن الكريم في قوله + +71 +00:07:01,110 --> 00:07:07,070 +تعالى إنما المؤمنون إخوة ما الذي جعلهم إخوة ما + +72 +00:07:07,070 --> 00:07:13,650 +الذي جمع بينهم هو الإيمان إنما المؤمنون وقال عليه + +73 +00:07:13,650 --> 00:07:19,910 +الصلاة والسلام المسلم أخو المسلم ما الذي جعله أخاه هو + +74 +00:07:19,910 --> 00:07:25,330 +الإسلام إذا الإيمان الإسلام هو أساس الرابطة بين + +75 +00:07:25,330 --> 00:07:30,630 +المسلمين وبين أفراد المجتمع المسلم ولا ينظر + +76 +00:07:30,630 --> 00:07:38,350 +الإسلام إلى الفوارق التي بين الناس فلا تفرق هذه + +77 +00:07:38,350 --> 00:07:43,270 +الفوارق بين مسلم وآخر سواء كانت في اللون أو في + +78 +00:07:43,270 --> 00:07:49,880 +الجنس أو اللغة فالإسلام أزال كل هذه الفوارق بين + +79 +00:07:49,880 --> 00:07:54,140 +الأسود والأبيض، بين العربي والأعجمي والغومي + +80 +00:07:54,140 --> 00:07:59,620 +والفارسي فالكريم عند الله والأكرم عند الله هو + +81 +00:07:59,620 --> 00:08:07,460 +الأتقى، إن أكرمكم عند الله أتقاكم وليسمرتبط هذا + +82 +00:08:07,460 --> 00:08:12,320 +التكريم لا بلون ولا بجنس ولا بلغة وقال عليه الصلاة + +83 +00:08:12,320 --> 00:08:17,500 +والسلام لا فضل لعربي على أعجمي ولا لأعجمي على عربي + +84 +00:08:17,500 --> 00:08:23,260 +ولا لأبيض على أسود ولا لأسود على أبيض إلا بالتقوى + +85 +00:08:23,260 --> 00:08:32,720 +كلكم لآدم وآدم من تراب وأيضاً حرم الإسلام ومنع + +86 +00:08:32,720 --> 00:08:40,740 +التعصب من الذي ما كان يتعصب له أهل الجاهلية من قبل من + +87 +00:08:40,740 --> 00:08:46,420 +عصبية وقبلية فقال عليه الصلاة والسلام ليس مننا من + +88 +00:08:46,420 --> 00:08:50,160 +دعا إلى عصبية وليس مننا من قاتل على عصبية وليس + +89 +00:08:50,160 --> 00:08:54,920 +مننا من مات على عصبية تلك العصبية الجاهلية والحمية + +90 +00:08:54,920 --> 00:08:58,340 +الجاهلية التي كان عليها أهل الجاهلية أزالها + +91 +00:08:58,340 --> 00:09:04,770 +الإسلام بالكلية ونفر منها النبي صلى الله عليه وسلم + +92 +00:09:04,770 --> 00:09:11,450 +حينما وصفها بأنها منتنة فقال دعوها فإنها منتنة و + +93 +00:09:11,450 --> 00:09:16,870 +أيضاً علمنا النبي صلى الله عليه وسلم درساً في عدم + +94 +00:09:16,870 --> 00:09:25,850 +التفريق بين جنس و جنس ولغة ولغة فقال في حق سلمان + +95 +00:09:25,850 --> 00:09:31,050 +وهو فارسي وليس عربي سلمان من أهل البيت بل الذي + +96 +00:09:31,050 --> 00:09:36,090 +جعلهم من أهل بيت النبي صلى الله عليه وسلم مع أنه + +97 +00:09:36,090 --> 00:09:42,800 +فارسي الأصل جنسيته فارسية لغته فارسية لكن إسلامه + +98 +00:09:42,800 --> 00:09:51,140 +وإيمانه جعله أخاً مسلماً لجميع المسلمين ونسبه النبي + +99 +00:09:51,140 --> 00:09:59,180 +صلى الله عليه وسلم لبيته وهذا أيضاً دلال ابن رباح + +100 +00:09:59,180 --> 00:10:07,200 +العبد الأسود الحبشي ليس حراً كباقي الأحرار وليس + +101 +00:10:07,200 --> 00:10:09,420 +عربياً كالعرب + +102 +00:10:11,700 --> 00:10:19,180 +ليس أبيضا كان أسوداً وعبداً وحبشياً لكن إسلامه و + +103 +00:10:19,180 --> 00:10:26,360 +إيمانه جعله أخاً بل سيدا كما وصفه عمر رضي الله عنه + +104 +00:10:26,360 --> 00:10:32,640 +حينما قال أبو بكر سيدنا وأعتقى سيدنا يعني بلالاً + +105 +00:10:32,640 --> 00:10:39,100 +فجعله عمر رضي الله عنه سيدا مع أنه عبد حبشي لونه + +106 +00:10:39,100 --> 00:10:45,550 +أسود فلا ينظر الإسلام إلى اللأن ولا إلى اللغة ولا + +107 +00:10:45,550 --> 00:10:52,210 +إلى الجنس إن أكرمكم عند الله أتقاكم كذلك من خصائص + +108 +00:10:52,210 --> 00:10:57,270 +المجتمع الإسلامي أن الإنسان في المجتمع الإسلامي له + +109 +00:10:57,270 --> 00:11:04,310 +كرامته الإنسان كإنسان قبل أن يكون مسلماً والإسلام + +110 +00:11:04,310 --> 00:11:11,910 +يزيد من كرامته لكنه كإنسان جعله الله تعالى خليفته + +111 +00:11:11,910 --> 00:11:17,070 +.. جعله خليفة على الأرض حينما قال وَإِذْ قَالَ + +112 +00:11:17,070 --> 00:11:19,930 +رَبُّكَ لِلْمَلَائِكَةِ إِنِّي جَاعِلٌ فِي + +113 +00:11:19,930 --> 00:11:23,830 +الْأَرْضِ خَلِيفًا كذا الخليفة هو الإنسان وقد كرمه + +114 +00:11:23,830 --> 00:11:28,950 +الله تعالى كإنسان حينما قال وَلَقَدْ كَرَّمْنَ + +115 +00:11:28,950 --> 00:11:36,460 +بَنِي آدَمَ ولم يقول المسلم كل بني آدم أي بني آدم + +116 +00:11:36,460 --> 00:11:42,140 +لأنه مخلوق من مخلوقات الله خلقه الله تعالى في أحسن + +117 +00:11:42,140 --> 00:11:48,980 +صورة وفي أحسن تقويم وكرمه على باقي وسائر الخلق + +118 +00:11:50,060 --> 00:11:54,800 +وزوده بالمؤهلات والخصائص التي من شأنها القيام بحمل + +119 +00:11:54,800 --> 00:11:59,000 +الأمانة وأداء المسئولية فليس في المجتمع الإسلامي + +120 +00:11:59,000 --> 00:12:05,120 +الطبقية التي موجودة في سائر أو باقي المجتمعات غير + +121 +00:12:05,120 --> 00:12:08,760 +الإسلامية فالمجتمع الإسلامي يخلو من الإنسان السيد + +122 +00:12:08,760 --> 00:12:14,600 +الحاكم المطاع والعبد فليس فيه سادة وعبيد فالكل + +123 +00:12:14,600 --> 00:12:22,060 +سواء عند الله تعالى الكل عبيد لله حتى الحاكم حتى + +124 +00:12:22,060 --> 00:12:27,880 +الخليفة هو عبد لله تعالى كسائر العباد وهو يعني في + +125 +00:12:27,880 --> 00:12:32,720 +قمة الهرم وفي قمة المسئولية ولا يمتاز عن غيره من + +126 +00:12:32,720 --> 00:12:38,080 +أفراد الرعية إلا بثقة للمسئولية والأمانة كلكم راعي + +127 +00:12:38,080 --> 00:12:44,260 +وكلكم مسئول عن رعيته خامساً + +128 +00:12:44,260 --> 00:12:50,940 +من خصائص المجتمع الإسلامي السلوك المستقيم مع شريعة + +129 +00:12:50,940 --> 00:12:56,720 +الله تعالى فالمجتمع الإسلامي سلوكه منضبط ومستقيم + +130 +00:12:56,720 --> 00:13:06,220 +مع شريعة الله تعالى لا يتعارض معه بل المسلم المؤمن + +131 +00:13:06,220 --> 00:13:13,400 +في هذا الدين وهذا الإسلام حينما يسمع شيئا من آيات + +132 +00:13:13,400 --> 00:13:18,530 +الله أو حديث رسول الله صلى الله عليه وسلم لا يقول + +133 +00:13:18,530 --> 00:13:25,650 +إلا سمعنا وأطعنا يسمع ويطيع فسلوكه سلوك منضبط + +134 +00:13:25,650 --> 00:13:31,450 +مستقيم مع قول الله ورسوله مع شريعة الله تعالى + +135 +00:13:31,450 --> 00:13:37,970 +ولذلك تكاد المعاصي والجرائم الخلقية تغيب عن هذا + +136 +00:13:37,970 --> 00:13:45,670 +المجتمع وإذا ما كانت تكون نادرة وقليلة طالما أن + +137 +00:13:45,670 --> 00:13:51,870 +هذا المجتمع ملتزم بشريعة الله تعالى و هناك بعض + +138 +00:13:51,870 --> 00:13:59,030 +الأمثلة التي تبين مدى انسجام و انضباط سلوك + +139 +00:13:59,030 --> 00:14:04,370 +المسلمين مع شريعة الله وأحكام الله المثال الأول + +140 +00:14:04,370 --> 00:14:09,230 +حينما نزلت آياته تحريم الخمر في المدينة لم يتوانى + +141 +00:14:09,230 --> 00:14:21,990 +ولم يتردد من كان عنده أواني كثيرة وبأسعار باهظة + +142 +00:14:21,990 --> 00:14:29,810 +لم يتردد من أن يدلق كما يقال في الشوارع فأسرع القوم + +143 +00:14:29,810 --> 00:14:33,290 +إلى دلق ما عندهم من الخمر في الشوارع حتى الذي كان + +144 +00:14:33,290 --> 00:14:39,330 +بيده شيء لم ينتظر أن يكمل هذا الكأس ليشربه حينما + +145 +00:14:39,330 --> 00:14:42,630 +سمع منادي رسول الله صلى الله عليه وسلم ينادي + +146 +00:14:42,630 --> 00:14:49,120 +بتحريم الخمر ألقى ما في يده من القدح مثال ونموذج + +147 +00:14:49,120 --> 00:14:55,020 +آخر لما نزلت آيات الحجاب أسرعت نساء المسلمين إلى + +148 +00:14:55,020 --> 00:15:01,940 +مروطهم وصنعوا منها خماراً يستر عوراتهم لم يترددوا + +149 +00:15:01,940 --> 00:15:04,720 +ولم يتوانوا ولم ينتظروا حتى + +150 +00:15:07,360 --> 00:15:15,100 +يفصلوا أو يخيطوا أو يحصلوا على قماش مناسب بل كل + +151 +00:15:15,100 --> 00:15:21,500 +واحدة منهم يعني أسرعت إلى ما عندها من أي قطعة قماش + +152 +00:15:21,500 --> 00:15:26,760 +وسطرت بها عورتها التي أمرها الله تعالى 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"word": " المسلمين", "probability": 0.9964599609375}, {"start": 1137.22, "end": 1137.48, "word": " وفيه", "probability": 0.8273111979166666}, {"start": 1137.48, "end": 1137.86, "word": " نصارى", "probability": 0.9718017578125}, {"start": 1137.86, "end": 1138.54, "word": " ومسيحيين", "probability": 0.9518694196428571}, {"start": 1138.54, "end": 1138.94, "word": " وفيه", "probability": 0.92578125}, {"start": 1138.94, "end": 1139.28, "word": " وفيه", "probability": 0.8478190104166666}, {"start": 1139.28, "end": 1139.92, "word": " وفيه", "probability": 0.90625}, {"start": 1139.92, "end": 1140.26, "word": " يعني", "probability": 0.907470703125}, {"start": 1140.26, "end": 1140.9, "word": " نوع", "probability": 0.987060546875}, {"start": 1140.9, "end": 1141.18, "word": " من", "probability": 0.99560546875}, {"start": 1141.18, "end": 1141.96, "word": " التشويه", "probability": 0.9776611328125}, {"start": 1141.96, "end": 1142.84, "word": " والتشكيه", "probability": 0.830322265625}, {"start": 1142.84, "end": 1143.34, "word": " أو", "probability": 0.826171875}, {"start": 1143.34, "end": 1144.04, "word": " التمييع", "probability": 0.885009765625}, {"start": 1144.04, "end": 1144.44, "word": " لهذا", "probability": 0.947998046875}, {"start": 1144.44, "end": 1144.74, "word": " الدين", "probability": 0.958984375}], "temperature": 1.0}, {"id": 49, "seek": 117177, "start": 1145.17, "end": 1171.77, "text": "لهذا الدين وهو هجوم على هذا الإسلام وهذا الدين بسطار وغطاء وقناع الحداثة أصبحوا يستخدموا سطار وقناع لهم يستطرون من وراه كما قلنا في البداية استطر من وراه العلمانيون والماركسيون واللادينيون كلهم وهذا آخر أيضا شام شرابي ماذا يقول عن الحداثة", "tokens": [43761, 15730, 32748, 9957, 37037, 2407, 8032, 7435, 20498, 15844, 23758, 33688, 3794, 37440, 37037, 15730, 32748, 9957, 4724, 3794, 9566, 9640, 4032, 17082, 9566, 16606, 4032, 4587, 8315, 3615, 21542, 3215, 5718, 104, 3660, 5551, 9381, 49628, 14407, 7251, 14851, 9778, 40448, 14407, 8608, 9566, 9640, 4032, 4587, 8315, 3615, 5296, 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"end": 1161.67, "word": " العلمانيون", "probability": 0.95126953125}, {"start": 1161.67, "end": 1162.85, "word": " والماركسيون", "probability": 0.8851841517857143}, {"start": 1162.85, "end": 1164.31, "word": " واللادينيون", "probability": 0.6875}, {"start": 1164.31, "end": 1165.19, "word": " كلهم", "probability": 0.794677734375}, {"start": 1165.19, "end": 1167.01, "word": " وهذا", "probability": 0.6097819010416666}, {"start": 1167.01, "end": 1167.39, "word": " آخر", "probability": 0.894775390625}, {"start": 1167.39, "end": 1167.81, "word": " أيضا", "probability": 0.869140625}, {"start": 1167.81, "end": 1168.37, "word": " شام", "probability": 0.944580078125}, {"start": 1168.37, "end": 1168.89, "word": " شرابي", "probability": 0.8790283203125}, {"start": 1168.89, "end": 1169.33, "word": " ماذا", "probability": 0.8916015625}, {"start": 1169.33, "end": 1170.07, "word": " يقول", "probability": 0.986572265625}, {"start": 1170.07, "end": 1170.43, "word": " عن", "probability": 0.9921875}, 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السامية رد الظلم والعدوان والدفاع عن النفس وعن الأهل وعن المال وعن الوطن فهذه أغراض مشروعة لأن يرد الظالم عن نفسه", "tokens": [1211, 2655, 5016, 38436, 4587, 16247, 3224, 28259, 5172, 21136, 10943, 10632, 38392, 7251, 3794, 3615, 7578, 33688, 3794, 37440, 30731, 6055, 5016, 38436, 4587, 11296, 4032, 20292, 3794, 8978, 11296, 36632, 1975, 34268, 3215, 16606, 37495, 22653, 33688, 2288, 11296, 3555, 4386, 25724, 11296, 3215, 9673, 8592, 32887, 3615, 32239, 3794, 8978, 3224, 36632, 1975, 34268, 3215, 16606, 34051, 11933, 2288, 11296, 3555, 4724, 17082, 13546, 11331, 4587, 6156, 27842, 29538, 16247, 17082, 2288, 46958, 21136, 10943, 10632, 12602, 3215, 6024, 116, 19528, 16070, 22488, 2407, 7649, 16070, 3215, 5172, 45761, 18871, 28239, 36178, 4032, 3615, 1863, 16247, 3224, 1211, 4032, 3615, 1863, 9673, 6027, 4032, 3615, 1863, 2423, 2407, 9566, 1863, 6156, 3224, 24192, 5551, 17082, 2288, 46958, 37893, 32887, 27884, 5296, 33456, 7251, 2288, 3215, 6024, 116, 45340, 18871, 8717, 36178, 3224], 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0000000000000000000000000000000000000000..1613cc226f80933e3ce85f8aeded957d6162d6fe --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/-BbX2P1tmrQ_postprocess.srt @@ -0,0 +1,2076 @@ +1 +00:00:19,910 --> 00:00:24,660 +بسم الله الرحمن الرحيمفي موضوع الـ synthesis of + +2 +00:00:24,660 --> 00:00:31,900 +heterocyclic rings بنستأنف الان هنتكلم على مجموعة + +3 +00:00:31,900 --> 00:00:36,220 +من الإغلاقات بنقول هذه الإغلاقات القاسم المشترك + +4 +00:00:36,220 --> 00:00:40,860 +بينها ان فيها reactive intermediate الان ال + +5 +00:00:40,860 --> 00:00:43,680 +reactive intermediates في ال organ ال chemistry + +6 +00:00:43,680 --> 00:00:49,160 +اللي هي الأشياء اللي بتتكون للحظات بسيطة جدا و + +7 +00:00:49,160 --> 00:00:55,070 +تتفاعل بسرعةمر علينا بشكل أساسي منها احنا الـ + +8 +00:00:55,070 --> 00:00:58,570 +carbocation و ال carbanion و كثير من الأمثلة اللي + +9 +00:00:58,570 --> 00:01:05,850 +اتكلمنا فيها كانت حقيقة carbanions بنكونها بتهاجم + +10 +00:01:05,850 --> 00:01:09,950 +على carbocations بتتفاعل الان في عند reactive + +11 +00:01:09,950 --> 00:01:14,730 +intermediates تانية منها ال free radicals ال free + +12 +00:01:14,730 --> 00:01:18,450 +radicals they are reactive intermediates في عند + +13 +00:01:18,450 --> 00:01:22,930 +reactive intermediates اسمهاالـ Carbines في عند + +14 +00:01:22,930 --> 00:01:28,270 +reactive intermediates اسمها الـ Nitrenes الان هذه + +15 +00:01:28,270 --> 00:01:33,170 +ال reactive intermediates هي موضوعنا اليوم هنبدأ + +16 +00:01:33,170 --> 00:01:39,150 +بأي شغلة ال radical cyclization طبعا انتوا عارفين + +17 +00:01:39,150 --> 00:01:43,970 +ال radical ال free radical اللي هو الشيء المتعدل + +18 +00:01:43,970 --> 00:01:49,870 +او حتى ممكن يكون مشحون اللي بيحملElectron مفرد + +19 +00:01:49,870 --> 00:01:56,090 +يعني فيه odd electron وبالتالي تكوين الروابط .. + +20 +00:01:56,090 --> 00:02:00,770 +تكوين الروابط في ال radical cyclization بتمن خلال + +21 +00:02:00,770 --> 00:02:06,180 +المعادلة واحد زائد واحد يسوى اتنينالان في ال + +22 +00:02:06,180 --> 00:02:11,040 +reactions تكوين الروابط بيكون من خلال اتنين زائد + +23 +00:02:11,040 --> 00:02:15,220 +صفر يساوى اتنين يعني كنا لما نتكلم مثلا نقول هذا + +24 +00:02:15,220 --> 00:02:22,540 +nucleophile هاجم الان هدولة الإلكترونين هم اللي + +25 +00:02:22,540 --> 00:02:28,000 +هيصيروا finally الرابطةبالتالي لو سألنا الرابطة + +26 +00:02:28,000 --> 00:02:33,400 +هذه من أين جاية من نفس الإلكترونين فإلكترونين هنا + +27 +00:02:33,400 --> 00:02:38,820 +كونوا الرابطة و من هنا كانت المساهمة بصفر في ال + +28 +00:02:38,820 --> 00:02:44,220 +radical cyclization لأ هو إلكترون من هنا و إلكترون + +29 +00:02:44,220 --> 00:02:48,800 +من هنا طبعا هل يترى الواقع اللي موجود في ال + +30 +00:02:48,800 --> 00:02:51,980 +radical cyclization اللي فعلا يكون هنا إلكترون و + +31 +00:02:51,980 --> 00:02:57,650 +هنا واحد لأأحنا عادة اللي بنعمله أنه بنكون radical + +32 +00:02:57,650 --> 00:03:04,170 +على جهة واحدة بنكون radical على جهة واحدة بعد هيك + +33 +00:03:04,170 --> 00:03:09,550 +بننظر لل double bond بننظر لل double bond أنه .. + +34 +00:03:09,550 --> 00:03:13,830 +أنه هي موجود فيها إلكترونال يعني افترضوا عندكم هذا + +35 +00:03:13,830 --> 00:03:17,910 +ال radical هي ال double bond ال by bond الآن أنا + +36 +00:03:17,910 --> 00:03:25,510 +بننظرلهاإن هى عبارة عن إلكترونين وبناء على ذلك لو + +37 +00:03:25,510 --> 00:03:29,830 +إجى هذا الإلكترون مع هذا عمله رابطة بيظل هنا + +38 +00:03:29,830 --> 00:03:34,510 +radical هذا ال radical بده يتفاعل مع شغل تانى + +39 +00:03:34,510 --> 00:03:38,490 +ويعمل أكيد رابطة مش هيدله radical او لو إجى هذا ال + +40 +00:03:38,490 --> 00:03:42,310 +radical هنا عمل رابطة الآن لاحظوا ارجعنا لفكرة + +41 +00:03:42,730 --> 00:03:47,370 +الإكزو والإندو سايكلزيشن يعني لو إيجي هذا هنا معنا + +42 +00:03:47,370 --> 00:03:51,450 +ذلك ال radical اللي ضال ضاله لبرا فكأنه عندي إكزو + +43 +00:03:51,450 --> 00:03:56,610 +سايكلزيشن و لو إجت الرابط هانكأنه عندي + +44 +00:03:56,610 --> 00:04:01,750 +endocyclization فالان ال free radicals بشكل عام + +45 +00:04:01,750 --> 00:04:07,110 +أشهر شيء موجود فيهم الحلقات الخماسية والسوداسية + +46 +00:04:07,110 --> 00:04:14,600 +وغالبا الإغلاق المفضل هو ال exocyclizationيعني + +47 +00:04:14,600 --> 00:04:18,740 +كثير هتلاحظوا هجوم على carbon double bond carbon + +48 +00:04:18,740 --> 00:04:22,780 +مشهور في هذه المنطقة و الهجوم بيكون على ال + +49 +00:04:22,780 --> 00:04:26,540 +electron خلينا نتخيل هيك اللي للداخل وبالتالي + +50 +00:04:26,540 --> 00:04:30,390 +بيصير عندى اي نوع من ال cyclizationالـ + +51 +00:04:30,390 --> 00:04:36,330 +Exocyclization are preferred خلّينا نشوف الكلام من + +52 +00:04:36,330 --> 00:04:39,610 +خلال أمثلة في الأول بدنا نتذكر شو أنواع ال + +53 +00:04:39,610 --> 00:04:43,510 +radicals أنواع ال radicals في عندنا ال neutral + +54 +00:04:43,510 --> 00:04:47,790 +radicalsيعني في عندنا Radical متعادل، يعني لو + +55 +00:04:47,790 --> 00:04:52,230 +حسبنا الـ Formal Charge على الذرة اللي حاملة لـ + +56 +00:04:52,230 --> 00:04:57,650 +Free Radical هلاحظ ان ال Formal Charge صفر طبعا + +57 +00:04:57,650 --> 00:05:03,530 +ممكن هذا ال Radical المتعادل يكون على Carbon ويله + +58 +00:05:03,530 --> 00:05:09,030 +طريقة كيف نعمله Generation بنشوفها الآن وممكن يكون + +59 +00:05:09,030 --> 00:05:14,930 +على Nitrogenفى عندنا النوع التانى هدولة النوعين + +60 +00:05:14,930 --> 00:05:19,490 +هناخد أمثلة محددة عليهم اتفرجينا كيف بنعمل free + +61 +00:05:19,490 --> 00:05:23,730 +radical على ال nitrogen او بنسميه amino radical من + +62 +00:05:23,730 --> 00:05:28,290 +ال amino وكيف نعمل free radical على ال carbon + +63 +00:05:28,290 --> 00:05:32,270 +هدولة neutral radical فى عندنا protonated radical + +64 +00:05:32,760 --> 00:05:35,880 +يعني الـ free radical حاملة بروتون الذرة اللي + +65 +00:05:35,880 --> 00:05:40,300 +حاملها حاملة بروتون وبالتالي بيكون موجب هدولة + +66 +00:05:40,300 --> 00:05:45,320 +بيضيفوا بشكل كتير جيد على ال double bonds ال + +67 +00:05:45,320 --> 00:05:48,860 +neutral radical مرات بيكونوا un selective يعني + +68 +00:05:48,860 --> 00:05:55,160 +التفاعل تبعهمو في عندنا radicals complex to metal + +69 +00:05:55,160 --> 00:06:01,040 +ions with moderate reactivity اللي هناخده وباختصار + +70 +00:06:01,040 --> 00:06:04,940 +مش هنتوسع كتير في موضوع ال radicals لإيش؟ لأن + +71 +00:06:04,940 --> 00:06:09,820 +موضوع ال radicals في كل الأحوال كيميا كبيرةبشكل + +72 +00:06:09,820 --> 00:06:13,120 +عام الناس اللي بيشتغلوا بال free radicals مجموعات + +73 +00:06:13,120 --> 00:06:18,460 +متخصصة اهم شي عندها عشان تثبت انه تفاعل تم من خلال + +74 +00:06:18,460 --> 00:06:24,580 +ال free radical انه بيكون عندهم جهاز ال ESR ال ESR + +75 +00:06:24,580 --> 00:06:33,570 +اللي هوElectron Spin Resonance يعني خلّيني أقول أن + +76 +00:06:33,570 --> 00:06:39,670 +فكرة ال NMR اللي هو ال proton spin resonance فكرة + +77 +00:06:39,670 --> 00:06:44,760 +ال NMR قائمة على فكرة مجال مغناطيسي من شحنةموجبة + +78 +00:06:44,760 --> 00:06:48,800 +لأن حركة الشحنة تعمل المجال مغطي سماء لذلك الان في + +79 +00:06:48,800 --> 00:06:53,320 +النهاية الشحنة الموجبة بتعمل والشحنة السالبة بتعمل + +80 +00:06:53,320 --> 00:06:58,900 +والإلكترون بيعمل أي شحنة بتعمل وعشان هيك ال free + +81 +00:06:58,900 --> 00:07:05,100 +radical قائمة فكرته على شحنة الإلكترون ال NMR أو + +82 +00:07:05,100 --> 00:07:09,620 +ال ESRفكرته قائمة على شحنة الإلكترون وبتعمل مجال + +83 +00:07:09,620 --> 00:07:13,120 +مغناطيسي وما إلى ذلك ال proton NMR قائمة على + +84 +00:07:13,120 --> 00:07:17,960 +الشحنة المجبة عشانك الجهازين بنقدر نقول عنهم إيش + +85 +00:07:17,960 --> 00:07:21,600 +أولاد عام عادة اللي بيشتغلوا في ال free radicals + +86 +00:07:21,600 --> 00:07:25,240 +مجموعات بيكون عند هذا الجهاز اللي لو مر عليكم + +87 +00:07:25,240 --> 00:07:29,900 +electron spin resonance أو مرات بيكتبوا EPR + +88 +00:07:29,900 --> 00:07:34,480 +electron paramagnetic resonanceElectron Spin + +89 +00:07:34,480 --> 00:07:37,380 +Resonance أو Electron Paramagnetic Resonance + +90 +00:07:37,380 --> 00:07:40,640 +وبيشوفوا فيه الـ Free Radical أثناء ما بتكون في + +91 +00:07:40,640 --> 00:07:47,820 +التفاعل وبيعطي إشارة بمواصفات معينة خلّينا + +92 +00:07:47,820 --> 00:07:54,920 +نبدأ فيالـ Neutral نبدأ في الـ Neutral Radicals + +93 +00:07:54,920 --> 00:07:59,880 +ونبدأ بمثال بسيط Neutral Aminyl Radicals معنى + +94 +00:07:59,880 --> 00:08:03,940 +Aminyl يعني اتكونت على النيتروجين لو أخذنا هذا + +95 +00:08:03,940 --> 00:08:07,780 +المركب اللي فيه كلورين متصل بالنيتروجين اعملنا له + +96 +00:08:07,780 --> 00:08:12,220 +فوتوليسيز طبعا الفوتوليسيز بيكسر هذه الرابط اللي + +97 +00:08:12,220 --> 00:08:15,820 +مش قوية كتير بين الكلور والنيتروجين طبعا أي نوع من + +98 +00:08:15,820 --> 00:08:20,440 +الكسر هيعمل homolytic homolytic cleavage أو كسر + +99 +00:08:20,530 --> 00:08:24,030 +متجانس يعني كأنه لو اتخيلتوا ان هنا فيه إلكترونين + +100 +00:08:24,030 --> 00:08:28,510 +الكسر اللي بيصير اشمال وكسر متجانس طالما تم هذا + +101 +00:08:28,510 --> 00:08:32,770 +الكسر اذا هيتكون عندى ال nitrogen radical طبعا + +102 +00:08:32,770 --> 00:08:37,950 +بالتأكيد هنا كان عندنا زوج الإلكترونات اللى مشهور + +103 +00:08:37,950 --> 00:08:42,270 +ومعروف تبع ال nitrogen هذا مافيش فيه خلاف فلو احنا + +104 +00:08:42,270 --> 00:08:49,730 +حسبنا ال formal charge هنا خمسة ناقصرابطتين ناقص + +105 +00:08:49,730 --> 00:08:53,210 +تلت إلكترونات خمسة ناقص خمسة سفر إذا هذا ال + +106 +00:08:53,210 --> 00:08:57,630 +radical اللي موجود هنا هو عبارة عن ال neutral + +107 +00:08:57,630 --> 00:09:01,050 +radical هذا ال radical اللي هان ال neutral radical + +108 +00:09:01,050 --> 00:09:04,810 +الأن لاحظوا الفكرة اللي قلتها فكرة ال cyclization + +109 +00:09:04,810 --> 00:09:10,330 +الأن هاي هذا الإلكترون مع هذا الإلكترون عملوا + +110 +00:09:10,330 --> 00:09:14,050 +رابطة لاحظوا exocyclization + +111 +00:09:16,770 --> 00:09:21,010 +راديكل هذا الـ radical بياخد كلورين راديكل تنسوش + +112 +00:09:21,010 --> 00:09:26,390 +نطلع عندك كلورينradical فبيتكون المركب اللى موجود + +113 +00:09:26,390 --> 00:09:32,350 +عندكم هذا مثال على كيف انا اعمل generation of ال + +114 +00:09:32,350 --> 00:09:36,510 +neutral amino radical وكيف هذا بيسكر على ال double + +115 +00:09:36,510 --> 00:09:40,070 +bond ولاحظوا الكلام اللى حكيناه انه كان هنا ال + +116 +00:09:40,070 --> 00:09:43,610 +cyclization المفضل ال exo ولا ال endo ال + +117 +00:09:43,610 --> 00:09:49,650 +exocyclization وادى في هذه الحالة الى حلقة خماسية + +118 +00:09:52,680 --> 00:09:58,680 +في عندى ال neutral carbon radical عادة ال carbon + +119 +00:09:58,680 --> 00:10:03,860 +radical عادة ال carbon radical لما بنكونها الناس + +120 +00:10:03,860 --> 00:10:06,860 +اللى بيشتغلوا بال free radical عندهم مواد أولية + +121 +00:10:06,860 --> 00:10:10,840 +بتساعد على انه نكون ال carbon radical يعني افترضوا + +122 +00:10:10,840 --> 00:10:13,740 +انا بدي ابدأ من هذا المركب يعني خليكم من هذا + +123 +00:10:13,740 --> 00:10:18,740 +المركب انا المطلوب عندى حقيقة المطلوب عندى حقيقة + +124 +00:10:18,740 --> 00:10:23,350 +هذه الرابط اللى بين ال carbonو البروم اللى فيها + +125 +00:10:23,350 --> 00:10:32,110 +كام electron اتنين ان اكسرها كسر متجانس لو كسرتها + +126 +00:10:32,110 --> 00:10:38,830 +كسر متجانس هى صار عندى CH2 حاملة free radical كمان + +127 +00:10:38,830 --> 00:10:45,870 +CH2 O CH2 C double bond C و هذا الكلام على فرض انه + +128 +00:10:45,870 --> 00:10:50,920 +صرت عامل ال radicalبإمكاني هذه أرسمها بهذا الشكل + +129 +00:10:50,920 --> 00:10:55,540 +هذه نفس ال radical اللي هناك لكن مرسوم بشكل أنه + +130 +00:10:55,540 --> 00:10:59,200 +بده يعمل حلقة وبعدين هذه عندنا هنا إلكترونين + +131 +00:11:02,730 --> 00:11:07,530 +بدو يسكر على الـ Exocyclization و بحسب الميكانيزم + +132 +00:11:07,530 --> 00:11:13,270 +هياخد هيدروجين CH2 راديكال هتصفه مثل الان بيصير + +133 +00:11:13,270 --> 00:11:17,750 +السؤال كيف عادة بتمكسر هذه الرابط اللي هي اللي بين + +134 +00:11:17,750 --> 00:11:22,010 +الكربون والهالوجينالان اللي بيشتغلوا بال free + +135 +00:11:22,010 --> 00:11:25,930 +radical عادة بيستعملوا هذا المركب الديازو كومباون + +136 +00:11:25,930 --> 00:11:28,710 +مشهور ومتوفر عندهم في المختبرات بتاعة ال free + +137 +00:11:28,710 --> 00:11:33,090 +radical هذا بشوية تسخين بسيط بشوية تسخين بسيط + +138 +00:11:33,090 --> 00:11:36,530 +بيكسر بيفقد جزء نيتروجين هتخيلوا ان هاي إلكترون + +139 +00:11:36,530 --> 00:11:41,670 +إلكترون عملوا رابطة، شو هيطلع عندكم هنا؟Radical و + +140 +00:11:41,670 --> 00:11:45,390 +Radical بيطلع عند هذا ال radical هذا ال radical + +141 +00:11:45,390 --> 00:11:49,370 +بيفعلوه مع ال tributyltinhydride + +142 +00:11:49,370 --> 00:11:53,250 +tributyltinhydride + +143 +00:11:53,250 --> 00:11:59,570 +الان هذا بياخد من هنا H تخيلوا رابط زي هيك هياخد + +144 +00:11:59,570 --> 00:12:05,930 +ايشأجمع إلكترونها كوالي المُركّب المتعادل الآن + +145 +00:12:05,930 --> 00:12:12,070 +أعطاني الـ tributyltin radical ال tributyltin + +146 +00:12:12,070 --> 00:12:17,870 +radical بيجي ياخد ال PR radical هيعطيني + +147 +00:12:17,870 --> 00:12:23,410 +tributyltin bromide هاي ال tributyltin معه radical + +148 +00:12:23,410 --> 00:12:29,170 +لما ياخد ال PRRadical أعطاني الـ Tribute لـ + +149 +00:12:29,170 --> 00:12:36,070 +Tenebromide زائد الـ Radical اللي أنا عاوزههذا ال + +150 +00:12:36,070 --> 00:12:39,350 +radical اللي احنا عاوزينه زي ما فرجيناكوا الآن سكر + +151 +00:12:39,350 --> 00:12:44,070 +و اعطى منها ال radical لاحظوا الآن هيجي هذا يسحب + +152 +00:12:44,070 --> 00:12:51,510 +منها نقاتش شو بيرد؟ tributyl-10 برماء tributyl-10 + +153 +00:12:51,510 --> 00:12:56,690 +radical ل tributyl-10 radical بعود اكرر هذه الخطوة + +154 +00:12:56,690 --> 00:13:01,370 +اذا كأنه بمنطق تفاعلات ل free radicals صار في + +155 +00:13:01,370 --> 00:13:08,860 +عندكم تفاعلInitiation و Propagation و Termination + +156 +00:13:08,860 --> 00:13:13,380 +عند اللزوم يعني هذه الخطوة بس بتلزم للبداية اول + +157 +00:13:13,380 --> 00:13:19,000 +ترابيوت التن راديكال لزمن من خلال هدولر agent بعد + +158 +00:13:19,000 --> 00:13:23,780 +هيك نفس التفاعل بيصير يطلع لي ترابيوت التن راديكال + +159 +00:13:23,780 --> 00:13:29,990 +بتفاعلو هكذا إذا هذه الـ mechanism هي عبارة عن الـ + +160 +00:13:29,990 --> 00:13:34,190 +chain mechanism بكل الأحوال مثل هيك شغلات بده + +161 +00:13:34,190 --> 00:13:38,830 +الإنسان بهدوء يتضرب عليها واضحة الفكرة اللي فيها + +162 +00:13:38,830 --> 00:13:42,170 +يعني مابديش اتوه انا كتير بالافكار الفكرة ان هاي + +163 +00:13:42,170 --> 00:13:45,870 +radical و انا عندى two electrons electron و + +164 +00:13:45,870 --> 00:13:51,950 +electron عملوا bond دلوا radical أخدالـ H من هنا + +165 +00:13:51,950 --> 00:13:55,650 +يعني هذه الفكرة الأساسية اللي هي الـ cyclization + +166 +00:13:55,650 --> 00:13:59,950 +point وزي ما احنا متفقين ان احنا جاعدين بندرس كيف + +167 +00:13:59,950 --> 00:14:05,990 +بتتكون الحلقة الان قبل وبعد الحلقة في كيميا كتير + +168 +00:14:05,990 --> 00:14:10,150 +لكن تركيزنا احنا على تفاعل ال cyclization على + +169 +00:14:10,150 --> 00:14:17,140 +التفاعل اللي بيتمن خلاله عملية الإغلاقالنوع التاني + +170 +00:14:17,140 --> 00:14:21,000 +من الـ free radicals الـ protonated amino radical + +171 +00:14:22,160 --> 00:14:25,700 +يعني لو طلعنا على المركب اللي شوفناه أول مرة + +172 +00:14:25,700 --> 00:14:29,960 +أخدناه كان فيه زوج إلكترونات إذا بتدخله لو رسمناه + +173 +00:14:29,960 --> 00:14:35,800 +بالأزرق الآن هذا المركب لو ضفنا عليه acid زوج + +174 +00:14:35,800 --> 00:14:40,140 +الإلكترونات شو هيعمل مع ال acid؟ هيسحب منه بروتون + +175 +00:14:40,140 --> 00:14:44,800 +وبالتالي هنا حيصير عندكم quaternary نيتروجين أتم + +176 +00:14:44,800 --> 00:14:48,560 +هذه ال quaterna نيتروجين لو بنحسب لها ال form of + +177 +00:14:48,560 --> 00:14:53,950 +chargePositive بالتأكيد يعني هذا اللي كان أصلا زوج + +178 +00:14:53,950 --> 00:14:59,490 +إلكترونات و جاب من برا من الحامض H بلس فصار عندى + +179 +00:14:59,490 --> 00:15:05,210 +protonated compound الان هذا ال protonated radical + +180 +00:15:05,210 --> 00:15:10,950 +عادة في أربع molar sulfuric acid مع acidic acid + +181 +00:15:10,950 --> 00:15:20,520 +بيفقد CL من هنا CL radical بهذا الشكلواضح؟ هيتكون + +182 +00:15:20,520 --> 00:15:25,140 +عندنا ال free radical اللي موجود عندكم لو بنطلع + +183 +00:15:25,140 --> 00:15:28,960 +على هذا ال free radical هلاحظ أنه موجب ليش؟ لأ لو + +184 +00:15:28,960 --> 00:15:35,260 +بنقول خمسة ناقص كام رابطة ناقص إلكترون إذا هذا + +185 +00:15:35,260 --> 00:15:40,700 +radical كتايون واضح؟ إذا هذا radical كتايون في كل + +186 +00:15:40,700 --> 00:15:48,510 +الأحوال عندي radical هنا وعندي هناElectronail في + +187 +00:15:48,510 --> 00:15:50,990 +الـ Double bond شو نوع الـ Cyclization؟ + +188 +00:15:50,990 --> 00:15:55,270 +Exocyclization بتكون عندنا free radical وهذا ال + +189 +00:15:55,270 --> 00:16:02,110 +free radical بياخد Cl وعشان مايضلوش المركب موجب ال + +190 +00:16:02,110 --> 00:16:08,820 +H plus اللي إجت في البدايةبدا ايش؟ تفقد اتش بلس + +191 +00:16:08,820 --> 00:16:13,580 +اتش بلس اتش بلس اتش بلس اتش بلس اتش بلس اتش بلس + +192 +00:16:13,580 --> 00:16:19,080 +اتش + +193 +00:16:19,080 --> 00:16:21,660 +بلس اتش بلس اتش بلس اتش بلس اتش بلس اتش بلس اتش + +194 +00:16:21,660 --> 00:16:22,760 +بلس اتش بلس اتش بلس اتش بلس اتش بلس اتش بلس اتش + +195 +00:16:22,760 --> 00:16:22,960 +بلس اتش بلس اتش بلس اتش بلس اتش بلس اتش بلس اتش + +196 +00:16:22,960 --> 00:16:24,140 +بلس اتش بلس اتش بلس اتش بلس اتش بلس اتش بلس اتش + +197 +00:16:24,140 --> 00:16:31,280 +بلس اتش بلس اتش بلس اتش بلس اتش + +198 +00:16:31,280 --> 00:16:34,980 +بل + +199 +00:16:36,240 --> 00:16:40,240 +تنفذوا بهدوء و اتدربوا حالكوا عليه بهدوء انه احنا + +200 +00:16:40,240 --> 00:16:47,000 +بدأنا بهذا المركب بدون H plus عملنا له protonation + +201 +00:16:47,000 --> 00:16:50,840 +و عملنا ال free radical ال cyclization و بعد هيك + +202 +00:16:50,840 --> 00:16:56,540 +في النهاية هل في ناتج بيطلع positive وبناء على ذلك + +203 +00:16:56,540 --> 00:17:01,280 +زي ما اتجت ال H plus بدأ تطلع ال H plus هيظل على + +204 +00:17:01,280 --> 00:17:06,710 +ال nitrogenزوج إلكترونات الآن الـ nitrogen بوضعها + +205 +00:17:06,710 --> 00:17:12,090 +الطبيعي في الدنيا ايش وضعها الطبيعي تلت روابط وزوج + +206 +00:17:12,090 --> 00:17:15,710 +إلكترونات فهذا زوج الإلكترونات اللي كان مع ال + +207 +00:17:15,710 --> 00:17:19,530 +proton هو اللي بيصير زوج إلكترونات على ال nitrogen + +208 +00:17:19,530 --> 00:17:25,770 +هو اللي كان أساسا يعني لو تتخيلوا كل العملية عملية + +209 +00:17:25,770 --> 00:17:32,050 +catalysis يعني أصل المركب زي هيك بدون الـ H و بدون + +210 +00:17:32,050 --> 00:17:36,590 +ال positiveهذه زوج الإلكترونات دلوقتي ضفنا ال H و + +211 +00:17:36,590 --> 00:17:42,250 +ساعدت على تكوين ال radical و غيره و في الآخر فقدت + +212 +00:17:42,250 --> 00:17:49,930 +ال H في الآخر فقدت ال H يعني لو واحدة أحيانا بدها + +213 +00:17:49,930 --> 00:17:55,250 +تفكر تفهم التفاعل بدون كل هذا الكلام كيف بدها أفهم + +214 +00:17:55,250 --> 00:17:58,690 +التفاعل بدون كل هذا الكلام يعني على الجزء الأصلي + +215 +00:17:58,690 --> 00:18:04,190 +على الجزء الأصلي هي الجزء الأصليمش هذا الجزء + +216 +00:18:04,190 --> 00:18:09,990 +الأصلي بدون .. بدون هدول، هاي الجزء الأصلي اللي + +217 +00:18:09,990 --> 00:18:14,210 +عندك، هذا جزء متعادل، هاي الـ nitrogen تلت روابط + +218 +00:18:14,210 --> 00:18:18,850 +وزوج إلكترونات، الآن في كل الأحوال جربوا افهم + +219 +00:18:18,850 --> 00:18:26,570 +التفاعل، هاي إلكترون اتنين، تلاتة، + +220 +00:18:26,570 --> 00:18:33,080 +أربعةصحيح ولا لا؟ كل اللي صار كمحصلة أن هدول عملوا + +221 +00:18:33,080 --> 00:18:40,140 +رابط هان و هدول عملوا رابط هان ولا + +222 +00:18:40,140 --> 00:18:47,000 +في غير هيك؟ معدى ذلك كله catalysis يعني في النهاية + +223 +00:18:48,600 --> 00:18:51,660 +الذين يريدون أن يفهم هؤلاء إلكترونين وهؤلاء بايتين + +224 +00:18:51,660 --> 00:18:53,900 +هؤلاء اللي عملوا ان رابط وهؤلاء اللي عملوا ان رابط + +225 +00:18:53,900 --> 00:19:01,990 +صار ان رابط وصار CH2 رابط مع CLعشانك من ناحية + +226 +00:19:01,990 --> 00:19:06,130 +الذرات المعادلة جيدة و موزونة و الأشياء اللي دخلت + +227 +00:19:06,130 --> 00:19:09,990 +ك catalyst و ساعدت لتكوين ال radical بشكل جيد في + +228 +00:19:09,990 --> 00:19:14,650 +الآخر أشمالها بتطلع هذا الكلام نفسه هذا الكلام + +229 +00:19:14,650 --> 00:19:20,190 +نفسه هتلاحظوه بتكرر لكن بدل ما يكون مع H plus مع + +230 +00:19:20,190 --> 00:19:25,470 +metal plus وبالتالي بيصير ال radical اللي ساعد على + +231 +00:19:25,470 --> 00:19:33,250 +تكوينهالـ metal plus فلو أخدنا هذا المثال الآن + +232 +00:19:33,250 --> 00:19:36,570 +بديش أتوه أنا بكل هذا الكلام بديش أتوه بكل هذا + +233 +00:19:36,570 --> 00:19:39,650 +الكلام كل هذا الكلام مساعد على تكوين ال radical + +234 +00:19:39,650 --> 00:19:46,870 +لكن لو كنتوا أنتوا كنتوا يفهموا هاي الآن هاي ال CL + +235 +00:19:46,870 --> 00:19:47,650 +و هاي + +236 +00:19:52,100 --> 00:19:56,940 +الـ buy bond الان ايش المحصلة النهائية اللى هشوفها + +237 +00:19:56,940 --> 00:20:03,100 +في اخر الجواب رابطة هنا رابطة هنا لاحظوا ان هى + +238 +00:20:03,100 --> 00:20:06,060 +الرابطين اللى انا رسمته ودى CH2 + +239 +00:20:11,070 --> 00:20:16,330 +واضح؟ الآن هذا الكلام بتمن خلال أنه ييجي ال metal + +240 +00:20:16,330 --> 00:20:20,850 +يتحد مع ال CL يعمل روابط يعمل أشياء كتيرة مش + +241 +00:20:20,850 --> 00:20:26,170 +موضوعنا يعني مابديش أنا أتوه كتير في موضوع ال free + +242 +00:20:26,170 --> 00:20:30,370 +radicals بنقول إحنا ببساطة ال free radicals لما + +243 +00:20:30,370 --> 00:20:34,440 +بتشوفوها يا إما بتكون نيوتراليا اما بتكون + +244 +00:20:34,440 --> 00:20:39,120 +protonated يا اما بتكون complex to metal ions كل + +245 +00:20:39,120 --> 00:20:43,860 +هذا الكلام فقط مساعدة لعمل ايش؟ لعمل free radicals + +246 +00:20:43,860 --> 00:20:48,140 +لكن المفروض ان اي واحدة بتقدر تتخيل انها التفاعل + +247 +00:20:48,140 --> 00:20:53,760 +النهائي ببساطة وبسهولة يعني هي التفاعل النهائي هي + +248 +00:20:53,760 --> 00:20:58,900 +التفاعل النهائي واضح مافيش فيه اي مشكلة + +249 +00:21:03,890 --> 00:21:07,450 +بهيك الحقيقة يعني موضوع ال radicals انا متعمدا + +250 +00:21:07,450 --> 00:21:11,750 +ماحبيتش اتعمق فيه ليش؟ لأن هو يعني بحاجة خليني + +251 +00:21:11,750 --> 00:21:16,510 +اقول الى يعني خبرة من الناس اللي بيشتغلوا فيه بشكل + +252 +00:21:16,510 --> 00:21:20,530 +كتير و ربما بعد شوية هتلاحظوا الكلام بال carbine و + +253 +00:21:20,530 --> 00:21:24,990 +ال nitrogen يعني هتلاحظوا انه مجموعات بحثية بتكون + +254 +00:21:24,990 --> 00:21:30,020 +معينة اللي بتشتغل فيها يعني مش اي طالببيجي و بيقول + +255 +00:21:30,020 --> 00:21:33,020 +انه انا بشتغل بال free radical لازم يكون ضمن + +256 +00:21:33,020 --> 00:21:36,380 +مجموعة فيها مختصين بال free radical فيها ال + +257 +00:21:36,380 --> 00:21:40,400 +reagents اللي شفتوها بيصير عمر معتاد عنده ال + +258 +00:21:40,400 --> 00:21:45,320 +tributyl tenhydride كذا كل هذا الكلام و عنده جهاز + +259 +00:21:45,320 --> 00:21:49,280 +ال ESR بتأكد انه جاسه و شاف ال free radical و غير + +260 +00:21:49,280 --> 00:21:53,580 +و غيرته النوع + +261 +00:21:53,580 --> 00:21:58,050 +التاني منال reactive intermediates أو التاني + +262 +00:21:58,050 --> 00:22:01,610 +والتالت طبعا غير ال carbocations و ال carbon ions + +263 +00:22:01,610 --> 00:22:06,730 +اللي بنسميهم ال carbines و ال nitrines ال carbines + +264 +00:22:06,730 --> 00:22:11,710 +و ال nitrines هدولة ربما مروا عليكم بالذات ال + +265 +00:22:11,710 --> 00:22:17,770 +carbine و يمكن اللي مر عليكم الميثيلين الميثيلين + +266 +00:22:17,770 --> 00:22:28,020 +اللي هو CH2 بزوجبزوج إلكترونات ومابدناش .. مابدناش + +267 +00:22:28,020 --> 00:22:31,160 +ننسى + +268 +00:22:31,160 --> 00:22:37,820 +شغلة .. بدناش ننسى شغلة أنه أول ما الناس اقترحوا + +269 +00:22:37,820 --> 00:22:41,700 +أنه في بالدنيا الميثيلين .. أول ما الناس اقترحوا + +270 +00:22:41,700 --> 00:22:45,890 +أنه في بالدنيا الميثيلين .. هذا كاربين طبعااللي هو + +271 +00:22:45,890 --> 00:22:50,850 +رابطتين وزوج إلكترونات المجموع الكل يداش ستة اول + +272 +00:22:50,850 --> 00:22:56,230 +ما الناس اقترحوا ان في المثلين العلماء الكبار .. + +273 +00:22:56,230 --> 00:23:01,410 +العلماء الكبار ضحكوا عليهمو قالولهم انتوا بتحكوا + +274 +00:23:01,410 --> 00:23:05,010 +تقريبا هذا الكلام في الاربعينات الف وتسعمائية و + +275 +00:23:05,010 --> 00:23:07,950 +أربعين أشياء انتوا بتحكوا يعني خارج الدائرة خارج + +276 +00:23:07,950 --> 00:23:16,090 +مفاهيم الكيميا الأساسية المفهومة و لدرجة انه يعني + +277 +00:23:16,090 --> 00:23:21,790 +هزقوا اللي اقترح أفكار مثل المثلين و ربما في كتاب + +278 +00:23:21,790 --> 00:23:25,390 +ال organ chemistry تبع Morrison and Boyd إذا + +279 +00:23:25,390 --> 00:23:29,530 +فتحتوا الكتاب كله هتلاقوا رسموا caricature عليهم + +280 +00:23:30,340 --> 00:23:38,280 +يستهزقوا فيهم فحطوا فارين بيتكلموا مع بعض ففار + +281 +00:23:38,280 --> 00:23:42,660 +بيكلم الفار التاني بيقوله لو خلطنا كذا و كذا بيطلع + +282 +00:23:42,660 --> 00:23:47,480 +كذا فذاك الفار التاني بيقوله he's talking a + +283 +00:23:47,480 --> 00:23:51,160 +chemical talk يعني بيحكي مفردات كيميائية but he + +284 +00:23:51,160 --> 00:23:56,800 +knows nothing about chemistryيعني اللي بتكلم عن + +285 +00:23:56,800 --> 00:24:01,340 +الميثيلين و عن الكاربين بحكي كلام كيميا لكن بفهمش + +286 +00:24:01,340 --> 00:24:07,860 +إيش ولا كلمة في الكيميا زي اليوم كتير من الأدعياء + +287 +00:24:07,860 --> 00:24:11,800 +العلم أحيانا أدعياء الديمقراطية و مرات أدعياء + +288 +00:24:11,800 --> 00:24:15,420 +الدين و مرات أدعياء الشريعة بيحكوا كلام بتحسوا + +289 +00:24:15,420 --> 00:24:20,600 +المفردات شرعية لكن بروح العلم مابفهموش في العلم + +290 +00:24:20,600 --> 00:24:25,900 +واضح؟ و بعدين ثبت أن الكاربين باب كبيرمن أبواب + +291 +00:24:25,900 --> 00:24:32,280 +الكيميا وأساسي وإن الناس اللي استهزأت لم تكن على + +292 +00:24:32,280 --> 00:24:36,740 +حق ربما من أكثر الناس اللي طالها الاستهزاء + +293 +00:24:36,740 --> 00:24:43,900 +Vandhoef Vandhoef أول ما اقترح التركيب + +294 +00:24:43,900 --> 00:24:49,000 +التتراهيدرال للكاربون لجأ الكيميائيين الكبار في + +295 +00:24:49,000 --> 00:24:54,200 +عصرهاللي يهزقوه و هو شاب ناشئ صغير اقترح هذا + +296 +00:24:54,200 --> 00:24:58,940 +التركيب اللي يهزقوه و يقولوا عنه كلامك مش منطقي و + +297 +00:24:58,940 --> 00:25:04,890 +مابدخلش العقل يعني بمعنى انهم بدهم يدمروا تدميرو + +298 +00:25:04,890 --> 00:25:10,530 +تقريبا هذا الحكي سنة 1875 لكن خلال سنوات قليلة ثبت + +299 +00:25:10,530 --> 00:25:16,330 +انه كل الكيميا العضوية مبنية على ايش؟ على ال + +300 +00:25:16,330 --> 00:25:19,830 +tetrahedral structure تبع ال carbon اللي كان من + +301 +00:25:19,830 --> 00:25:22,650 +اوائل الناس اللي اتكلموا فيه van't hoof و اللي + +302 +00:25:22,650 --> 00:25:28,450 +اخدوش بهدلة لانه اتكلم فيه ولذلك اول ما اعطيت + +303 +00:25:28,450 --> 00:25:35,540 +جائزة نوبل انعطت ل van't hoofملاحظين انتوا؟ يعني + +304 +00:25:35,540 --> 00:25:40,660 +أول جائزة نوبل في الكيميا اللي أخدها اتهزق سابقا + +305 +00:25:40,660 --> 00:25:46,800 +على أفكاره و ربما هذا الكلام بيجيبنا على قصة .. + +306 +00:25:46,800 --> 00:25:55,260 +أيوة بسرعة Galileo و الفلك و Copernicus و تعرفوا + +307 +00:25:55,260 --> 00:26:01,760 +هذه الأشياء و كيف عذبمن الباباوية وممنوع وانت + +308 +00:26:01,760 --> 00:26:05,840 +بتكفر وانت كذا وانت كذا كل هذا المفروض يعني قصص في + +309 +00:26:05,840 --> 00:26:09,800 +تاريخ العلم بتخلي الناس في كل الأحوال يعني + +310 +00:26:09,800 --> 00:26:13,680 +يتواضعوا يعرفوا انه مرات كتيرة الفكرة لما بتنحكي + +311 +00:26:13,680 --> 00:26:19,580 +لأول مرة قد تبدو غريبة لكن قد تكون فعلا الفكرة + +312 +00:26:20,840 --> 00:26:25,040 +صحيحة حتى الناس اللي اتكلموا عن كروية الأرض و عن + +313 +00:26:25,040 --> 00:26:30,440 +غيرها اول ما اتكلموا اتبهدلوا و بعدين الزمن و اللي + +314 +00:26:30,440 --> 00:26:34,400 +اتكلموا عن ال carbines اول ما اتكلموا اتبهدلوا و + +315 +00:26:34,400 --> 00:26:40,440 +رسموا فيهم كريكاتيرات و الآن احنا ايش بنعمل؟ بندرس + +316 +00:26:40,440 --> 00:26:44,080 +ال carbine كعلم احنا الآن بنقول carbine and + +317 +00:26:44,080 --> 00:26:47,420 +nitrogen cyclization و بندرسه كعلم اللي قاله اول + +318 +00:26:47,420 --> 00:26:55,160 +مرة اخد ايش؟دوش البهدلة الآن الكاربين ربما مروا + +319 +00:26:55,160 --> 00:27:00,460 +عليكم هم ذرة كاربون بتتصل بذرتين و عليها زوج + +320 +00:27:00,460 --> 00:27:04,940 +إلكترونات فلما أنا بدي أقول كاربون برابطتين نفترض + +321 +00:27:04,940 --> 00:27:08,860 +هي أبسطها الميثيلين وزوج إلكترونات إذا هي electron + +322 +00:27:09,570 --> 00:27:15,610 +60 يعني كام إلكترون فيها؟ ستة، الآن طبعا هتظل + +323 +00:27:15,610 --> 00:27:19,490 +المشكلة في زوج الإلكترونات اللي هنا، الرابطات اللي + +324 +00:27:19,490 --> 00:27:23,210 +مافيش فيهم مشكلة، هل يا ترى زوج الإلكترونات هذا + +325 +00:27:23,210 --> 00:27:28,870 +هيكون ب Orbit الواحد؟هل زوج الألكترونات هنا هيكون + +326 +00:27:28,870 --> 00:27:33,210 +ب orbital واحد وبالتالي ال spin state تبعته هتكون + +327 +00:27:33,210 --> 00:27:40,350 +صفر ونقول عنه singlet او هل هتكون ب two orbitals + +328 +00:27:40,350 --> 00:27:45,090 +سواء كان أحدهم sp2 او كان عندي sp hybridization + +329 +00:27:45,090 --> 00:27:50,730 +يعني هنا بنحكي احنا عن هدول التلاتة sp2 hybrid + +330 +00:27:50,730 --> 00:27:57,900 +orbitals ومعهمب أوربيتال SB2 رابطة رابطة و ال SB2 + +331 +00:27:57,900 --> 00:28:04,460 +التالت فيه إلكترون أو بنحكي عن SB لينيار يعني كأني + +332 +00:28:04,460 --> 00:28:05,900 +بده أقول HC + +333 +00:28:07,890 --> 00:28:12,650 +أتش يعني هذا لاحظوا الشكل كإنه إيش صار ليليا و في + +334 +00:28:12,650 --> 00:28:16,710 +two orbitals بيكونوا perpendicular to each other + +335 +00:28:16,710 --> 00:28:20,910 +عموديات زي ما بيصير عندى في ال triple bond في كل + +336 +00:28:20,910 --> 00:28:25,150 +الأحوال هنا إلكترونين منفردات في orbitals مختلفة + +337 +00:28:25,150 --> 00:28:32,000 +اتنين زي واحد تلاتة فهنصير نحكي عن إيشبشكل عام الـ + +338 +00:28:32,000 --> 00:28:35,420 +triplet state is more stable than the singlet + +339 +00:28:35,420 --> 00:28:39,940 +state طبعا هل يتكون الكربين ال singlet ولا ال + +340 +00:28:39,940 --> 00:28:42,220 +triplet اكتر؟ + +341 +00:28:44,000 --> 00:28:48,560 +بشكل عام لـ triplet carbenes are generally stable + +342 +00:28:48,560 --> 00:28:53,160 +in the gaseous state while singlet carbenes occur + +343 +00:28:53,160 --> 00:28:56,680 +more often in aqueous media يعني بعتمد على نوع + +344 +00:28:56,680 --> 00:28:59,760 +التفاؤل يعني إذا أنا بعمل التفاؤل بال gaseous + +345 +00:28:59,760 --> 00:29:04,020 +state الأكثر أنه يكون الاحتمال triplet وإذا بشتغل + +346 +00:29:04,020 --> 00:29:05,100 +في ال + +347 +00:29:08,490 --> 00:29:14,030 +الـ aqueous media في وسط solvent الأكثر أنه بده + +348 +00:29:14,030 --> 00:29:20,880 +يكون HNDSinglet Carbine هذا بالنسبة للكربين طبعا + +349 +00:29:20,880 --> 00:29:24,220 +لو كان بهذا الشكل عادة بنوصفه ايش بنقول عنه احنا + +350 +00:29:24,220 --> 00:29:28,960 +داي راديكل يعني كأنه عندى اتنين free radical ع + +351 +00:29:28,960 --> 00:29:33,160 +كربون ولذلك هتلاحظوا انه باختصار مرات بيرسموا + +352 +00:29:33,160 --> 00:29:36,580 +الكربين زي هيك يعني بيقولوا هى الرابطتين وزوج + +353 +00:29:36,580 --> 00:29:41,680 +الكترونات زي هيك او هى الرابطتين زي هيك والكترون + +354 +00:29:41,680 --> 00:29:47,720 +والكترونفكأنه هدولة die radicals على نفس الكاربون + +355 +00:29:47,720 --> 00:29:52,820 +واضح؟ هذا كأنه زوج إلكترونات واحد مع بعضه، هدولة + +356 +00:29:52,820 --> 00:29:57,960 +كأنهم two free radicals هذا بالنسبة لل singlet و + +357 +00:29:57,960 --> 00:30:04,930 +لل tripletStates of Carbine طبعا ال Nitrene شبيه + +358 +00:30:04,930 --> 00:30:08,890 +في مناحية ال singlet و ال triplet لكن ال Nitrene + +359 +00:30:08,890 --> 00:30:15,070 +هو عبارة عن Nitrogen Monovalent يعني ال Carbine + +360 +00:30:15,070 --> 00:30:19,450 +قلنا عنه Divalent يعني في رابطتين و زوج إلكترونات + +361 +00:30:19,450 --> 00:30:24,750 +ال Nitrene Monovalent في رابطة و زوجي إلكترونات ما + +362 +00:30:24,750 --> 00:30:29,150 +المشترك بينهم الاتنين ال electron sextetإنه فيهم + +363 +00:30:29,150 --> 00:30:32,930 +ست إلكترونات وبالتالي ممكن يكونوا Electrophiles + +364 +00:30:32,930 --> 00:30:37,470 +يعني التنين فيهم ست إلكترونات في الكربين رابطتين + +365 +00:30:37,470 --> 00:30:44,010 +وزوج إلكترونات في النيترين رابطة وزوجين إلكترونات + +366 +00:30:44,010 --> 00:30:47,470 +وممكن يكونوا في ال singlet وممكن يكونوا في ال + +367 +00:30:47,470 --> 00:30:52,910 +triplet states الآن الكربين والنيترين طالما إنهم + +368 +00:30:52,910 --> 00:30:56,210 +reactive intermediates إذا بدوا يلزمهم إيش + +369 +00:30:56,210 --> 00:31:01,310 +generationيعني ما بنباعش وبنشره Carbine ولا بنباعه + +370 +00:31:01,310 --> 00:31:05,130 +وبنشره Nitrine لأ أنا أثناء التفاعل بكون ال + +371 +00:31:05,130 --> 00:31:08,690 +Carbine و بكون ال Nitrine بالتالي بيصير الموضوع + +372 +00:31:08,690 --> 00:31:12,430 +دارسنا في البداية كيف أكون Carbine و كيف أكون + +373 +00:31:12,430 --> 00:31:18,370 +Nitrine كونته أثناء التفاعل مباشرة هيتفاعل كيف + +374 +00:31:18,370 --> 00:31:25,070 +بتفاعل؟واضح؟ الان اشهر طرق تكوين ال carbenes من + +375 +00:31:25,070 --> 00:31:30,370 +خلال ال diazo compounds بتحلف نيتروجين و بتعطينا + +376 +00:31:30,370 --> 00:31:36,930 +ايش؟ carbene يعني لو افترضنا هذه كانت CH2 ايش بده + +377 +00:31:36,930 --> 00:31:43,970 +يصير اسمه؟ diazomethane و هتعطينا الميثيلين واضح؟ + +378 +00:31:43,970 --> 00:31:48,630 +او الجزء الصغير اللي يفقد مش يكون نيتروجين يكون CO + +379 +00:31:50,480 --> 00:31:54,740 +اللي هو أول أكسيد الكربون برضه هيعطيني كربين إذا + +380 +00:31:54,740 --> 00:32:00,280 +تكوين الكربين من خلال فقط جزء صغير بالتسخين أو + +381 +00:32:00,280 --> 00:32:05,540 +بالحرارة الجزء الصغير شو ممكن يكون نيتروجين يفقد + +382 +00:32:05,540 --> 00:32:10,560 +من ال diazo compound إيش يعني ال diazo يعني مركبات + +383 +00:32:10,560 --> 00:32:15,360 +فيها نيتروجين نيتروجين تاني diazo نيتروجين تاني أو + +384 +00:32:15,360 --> 00:32:19,060 +ال C double bond C double bond O شو هذا سمنا إحنا + +385 +00:32:20,130 --> 00:32:27,230 +كيتين من خلال أن الكيتين يفقد C + +386 +00:32:27,230 --> 00:32:31,710 +triple bond O carbon monoxide هدولة أشهر طريقتين + +387 +00:32:31,710 --> 00:32:36,170 +لتكوين الكربين خلينا نقول نحط في بالنا أن الكربين + +388 +00:32:36,170 --> 00:32:42,090 +اتكون بعد شوية بدنا نقول إيش أشهر تفاعلاته + +389 +00:32:42,090 --> 00:32:47,360 +وحنختصرهم بكلمتين بسيطات addition و insertionإذا + +390 +00:32:47,360 --> 00:32:51,760 +بلغة بسيطة اللي بيظل متذكر طول عمره الكربين يتكون + +391 +00:32:51,760 --> 00:32:57,440 +من فقط جزء صغير اللي هو نيتروجين أو CO ويتفاعل + +392 +00:32:57,440 --> 00:33:05,840 +بالإضافة بال insertion الإدخال واضح الفكرة؟ بهيك + +393 +00:33:05,840 --> 00:33:12,150 +بتصير الكيميا شويةمسيطر عليها الان في تفاعلات + +394 +00:33:12,150 --> 00:33:17,730 +تانية اقل شهرة لكن موجودة لتكوين الكاربينز موجود + +395 +00:33:17,730 --> 00:33:23,030 +كتير تفاعلات انه يفقد HX عن نفس الذرى زي هذه + +396 +00:33:23,030 --> 00:33:29,190 +الأمثلة بطرق مختلفة انه من هنا يفقد ذرات من هنا + +397 +00:33:29,190 --> 00:33:33,580 +تفقد HX باستعمار reagents كتيرةخلّيني أنا على + +398 +00:33:33,580 --> 00:33:37,960 +الطريقتين المشهورات يمكن بلزم أنكم اتراجعوا تفاعل + +399 +00:33:37,960 --> 00:33:43,140 +أخدته بتكون فيه Dichlorocarbine إذا أنتم متذكرينه، + +400 +00:33:43,140 --> 00:33:49,440 +من بتعطينا اسمه؟ Reimer-Thiemann Reaction بالظبط، + +401 +00:33:49,440 --> 00:33:54,200 +بيكون ال Dichlorocarbine هتلاحظوا أن ال carbine + +402 +00:33:54,200 --> 00:34:00,130 +اللي هناك بتفاعل برضه بالطرق اللي هنحكيهاالان كيف + +403 +00:34:00,130 --> 00:34:05,930 +الكاربين هذا بده يتفاعل التفاعل الأول addition انه + +404 +00:34:05,930 --> 00:34:09,270 +يضيف على ال double bond طبعا لما بده يضيف على ال + +405 +00:34:09,270 --> 00:34:13,430 +double bond بده يعمل مع ال double bond حلقة ثلاثية + +406 +00:34:13,430 --> 00:34:19,150 +الميكانيزم بيلزمه انه نرسم orbitals لكن كنتيجة + +407 +00:34:19,150 --> 00:34:23,670 +تجربة كنتيجة تفاعل مش كميكانيزم ال mechanism is + +408 +00:34:23,890 --> 00:34:26,630 +mostly a concerted mechanism ممكن تكون free + +409 +00:34:26,630 --> 00:34:30,870 +radical mechanism الان كنتيجة للي بدهم الجواب سريع + +410 +00:34:30,870 --> 00:34:35,830 +لو اتخيلت انا ان في عندي هنا by bond كم الكترون + +411 +00:34:35,830 --> 00:34:43,130 +فيها وعندي هنا الكربين كم الكترون اتنين الان اذا + +412 +00:34:43,130 --> 00:34:46,810 +افترضنا ان هذا يعمل رابط هنا و هذا رابط هنا بهذا + +413 +00:34:46,810 --> 00:34:52,740 +الشكل بكون عملت الحلقة الثلاثيةوالا لأ يعني الناس + +414 +00:34:52,740 --> 00:34:58,360 +اللي متعودين ربما أشهر شغل كنتوا تعملوها ال deals + +415 +00:34:58,360 --> 00:35:02,690 +أكبر طبعا هذه بكل الأحوال مش mechanismis not a + +416 +00:35:02,690 --> 00:35:06,410 +mechanism at all هذه بس كيف تكتبوا الناتج ال + +417 +00:35:06,410 --> 00:35:09,470 +mechanism a concerted mechanism او radical + +418 +00:35:09,470 --> 00:35:13,730 +mechanism موضوع تاني اياكم ثم اياكم الف مرة عشر + +419 +00:35:13,730 --> 00:35:16,510 +تلاف مرة ان واحدة تقول this is the mechanism of + +420 +00:35:16,510 --> 00:35:18,950 +the reaction اللي بتقول this is the mechanism of + +421 +00:35:18,950 --> 00:35:21,130 +the reaction ع طول بيصحب وشهدت ال baccalaureate + +422 +00:35:21,130 --> 00:35:24,930 +منها this is not a mechanism طريقة لكتابة ايش + +423 +00:35:24,930 --> 00:35:30,050 +النتيجة الان نفس الاشي طريقة لكتابة النتيجة ان + +424 +00:35:30,050 --> 00:35:34,670 +نعمل زي هيكإنما الميكانيزم لهذا التفاعل شيء تاني + +425 +00:35:34,670 --> 00:35:39,750 +كيف ال orbitals تلتقى هذا موضوع مختلف تماما يدرس + +426 +00:35:39,750 --> 00:35:44,290 +في مكان تاني طبعا لاحظوا أنه أنا هنا لما حطيت + +427 +00:35:44,290 --> 00:35:48,130 +الإلكترون مع بعض و حركته مع بعض كنت بتعامل مع أي + +428 +00:35:48,130 --> 00:35:54,040 +كاربينالـ singlet طب لو قلنا بدنا نتعامل مع ال + +429 +00:35:54,040 --> 00:35:57,100 +triplet carbene ال triplet carbene إلكترونين + +430 +00:35:57,100 --> 00:36:01,760 +منفصلات الآن طالما أنه ال triplet carbene هذا + +431 +00:36:01,760 --> 00:36:08,420 +اتخيلوا زي هيك إلكترونين منفصلات و هذا ال by bond + +432 +00:36:08,420 --> 00:36:15,660 +إلكترونين إذا ممكن نتخيل أن هذا عمل رابطة مجرد ما + +433 +00:36:15,660 --> 00:36:22,440 +يعمل رابطة شو صار هذه؟carbon عليها radical و هذه + +434 +00:36:22,440 --> 00:36:27,360 +ال carbon عليها radical وين راحت ال double bond + +435 +00:36:27,360 --> 00:36:34,260 +انتبهوا معايا هنا ايش انتوا فيه عندكم مواد .. هذه + +436 +00:36:34,260 --> 00:36:38,840 +فكرة كتير أساسية هنا في double bond اتطلعوا المركب + +437 +00:36:38,840 --> 00:36:46,060 +اللي أنا مثلا بدي فيه في R و في R كيف شكلهم ال + +438 +00:36:46,060 --> 00:36:55,890 +trans بيصيروا cisلأ، ليش؟ لأنه no rotation around + +439 +00:36:55,890 --> 00:36:59,310 +carbon double bond carbon، مافي rotation، الآن لو + +440 +00:36:59,310 --> 00:37:03,650 +تم هذا التفاعل كradical reaction، عمل رابطة، صارت + +441 +00:37:03,650 --> 00:37:09,830 +هذه single bond، في rotation ولا لأ؟ في rotation، + +442 +00:37:09,830 --> 00:37:15,940 +بناء على ذلك هذا الناتج ممكن يصير الوفطيب لو سكر + +443 +00:37:15,940 --> 00:37:20,560 +خلينا نتخيل هو بهذه المرحلة، هيعطينا أي مركب؟ الـ + +444 +00:37:20,560 --> 00:37:25,940 +Trans طب لو كان لافف؟ الـ Cis إذا إيش اللي ناتج + +445 +00:37:25,940 --> 00:37:33,280 +اللي متوقع من ال radical reaction؟ ال Trans و Cis + +446 +00:37:34,250 --> 00:37:38,110 +ملاحظين؟ خليط من الناتجين ليش صار متوقع + +447 +00:37:38,110 --> 00:37:41,350 +translucence لسبب بسيط ان انا حولت ال double bond + +448 +00:37:41,350 --> 00:37:45,130 +ل single bond ممنوع ال rotation مسموح ال rotation + +449 +00:37:45,130 --> 00:37:50,690 +الان لما هذا الكلام بعملهان ال mechanism اللي هنا + +450 +00:37:50,690 --> 00:37:56,350 +بنقول عنها concerted mechanism بمعنى بتتم بخطوة + +451 +00:37:56,350 --> 00:38:02,570 +واحدةأنا بعمل الرابطتين مباشرة مع كسر هذه الرابطة + +452 +00:38:02,570 --> 00:38:08,970 +مابعطيش فرصة للمجموعات انها ايش اتلفت وبناء على + +453 +00:38:08,970 --> 00:38:15,190 +ذلك لل Trans بيضلوا ايش ال Trans السبب انه ال + +454 +00:38:15,190 --> 00:38:21,400 +mechanism في singletconcerted وبناء على ذلك بيفرج + +455 +00:38:21,400 --> 00:38:26,700 +كتير ان اكون بدأت ب single carbine او اكون بدأت ب + +456 +00:38:26,700 --> 00:38:29,680 +triple carbine ل triple carbine في نفس الطريقة + +457 +00:38:29,680 --> 00:38:33,240 +هيكون لي single bond هيصير الدوران مسموح هيصير + +458 +00:38:33,240 --> 00:38:37,360 +عندي خليط من ال stereo isomers بينما single + +459 +00:38:37,360 --> 00:38:41,420 +carbine انا بتحول مباشرة من ال double bond لان ال + +460 +00:38:41,420 --> 00:38:46,710 +double bond مسموح ولا ممنوع الدوران حولها ممنوعةفي + +461 +00:38:46,710 --> 00:38:52,170 +حد قال مسموح؟ غلط لفظه ربنا بيعف عن الغلط اللفظ اه + +462 +00:38:52,170 --> 00:38:55,270 +الان انتبهوا معاه هاي ال double bond مسموح الدوران + +463 +00:38:55,270 --> 00:38:59,510 +حولها ولا لأ؟ لأ الان ال double bond مباشرة بيجي + +464 +00:38:59,510 --> 00:39:04,310 +عليه هذا بهاجم بتلتق ال orbitals بيصير cycle ال + +465 +00:39:04,310 --> 00:39:11,110 +cycle مسموح الدوران حولها ولا لأ؟ برضه لأ هاي اي + +466 +00:39:11,110 --> 00:39:16,980 +حلقة لو تخيلتوا هذه حلقةهل يا ترى مسموح الدوران + +467 +00:39:16,980 --> 00:39:21,120 +حول الحلقة؟ الحلقة ممنوعة الدوران حولها، احنا + +468 +00:39:21,120 --> 00:39:25,500 +أخدنا سابقا وعشان هيك ظاهرة الـcis والـtrans وين + +469 +00:39:25,500 --> 00:39:28,940 +كانت توجد في الدنيا؟ في الـdouble bond وحولنا + +470 +00:39:28,940 --> 00:39:33,460 +الحلقة في الروابط الأحدية، الآن أنا هنا بقى تحول + +471 +00:39:33,460 --> 00:39:41,100 +بقى تحول من وين لوين من double bond إلى ring + +472 +00:39:41,100 --> 00:39:46,440 +مباشرةالان ال double bond مافيش فيها rotation و ال + +473 +00:39:46,440 --> 00:39:49,680 +ring مافيش فيها rotation اذا المجموعات شو هيتصير + +474 +00:39:49,680 --> 00:39:53,980 +فيهم؟ هيظل زي ما هو فبتقول ال stereo chemistry is + +475 +00:39:53,980 --> 00:39:57,880 +retained يعني اللي كانوا trans بيظلوا trans لكن لو + +476 +00:39:57,880 --> 00:40:02,240 +التفاعل تم بال radical mechanism اللي كانوا trans + +477 +00:40:02,240 --> 00:40:05,640 +بيصيروا cis و trans و اللي كانوا cis بيصيروا cis و + +478 +00:40:05,640 --> 00:40:09,940 +trans اذا انا من النواتج بقدر اعرف ان اللي كان + +479 +00:40:09,940 --> 00:40:14,800 +عندى ال singlet ولا ال triplet او اي ميكانيزميعني + +480 +00:40:14,800 --> 00:40:18,380 +لو لاحظت أن هذه الـ mechanism هي اللي موجودة عندى + +481 +00:40:18,380 --> 00:40:21,760 +ببدأ أستنتج أنه لأ أنا اللي كان عندى biradical + +482 +00:40:21,760 --> 00:40:27,140 +واتفعل على خطوتين هذي two step mechanism هاي ال + +483 +00:40:27,140 --> 00:40:30,620 +step الأولى هاي ال step التانى biradical mechanism + +484 +00:40:30,620 --> 00:40:35,480 +is a two step mechanism بينما هذي ال concerted + +485 +00:40:35,480 --> 00:40:40,920 +mechanism is one step mechanism إذا عملية الإضافة + +486 +00:40:40,920 --> 00:40:47,970 +كام آلية لها؟تن تين .. شو هم القليتين؟ شو أسماءهم؟ + +487 +00:40:47,970 --> 00:40:53,530 +ال concerted mechanism اللي هي one step و ال + +488 +00:40:53,530 --> 00:40:57,450 +biradical mechanism اللي هي ال two step mechanism + +489 +00:40:58,390 --> 00:41:03,730 +واضح؟ هذا الكلام في ال cycle addition لما نجي جزء + +490 +00:41:03,730 --> 00:41:06,830 +كامل من شغلنا هيكون شرح ال cycle addition هيتكرر + +491 +00:41:06,830 --> 00:41:09,650 +معاكوا أكتر من مرة في ال one three bipolar cycle + +492 +00:41:09,650 --> 00:41:13,550 +addition في ال deals elder reaction لاحظوا لما أنا + +493 +00:41:13,550 --> 00:41:17,010 +توي نوّهت عندكم أنه deals elder ما حد يعمل أسهم + +494 +00:41:17,010 --> 00:41:20,190 +يقول this is the mechanism لأ و أنا لما بقولكوا + +495 +00:41:20,190 --> 00:41:22,690 +اعمل ال deals elder reaction what is the mechanism + +496 +00:41:22,690 --> 00:41:25,510 +of deals elder reaction يا بدو يكون الجواب + +497 +00:41:26,090 --> 00:41:29,510 +Concerted mechanism نرسملها ال orbitals يبدو يكون + +498 +00:41:29,510 --> 00:41:33,110 +الجواب two step mechanism biradical Concerted + +499 +00:41:33,110 --> 00:41:38,070 +mechanism is one step mechanism ال biradical is + +500 +00:41:38,070 --> 00:41:44,370 +two step mechanism ابهيك بنكون عملنا التفاعل الأول + +501 +00:41:44,370 --> 00:41:51,260 +على الكربيل اللي هوالاديشن وهي أمثلة عليه ع السريع + +502 +00:41:51,260 --> 00:41:55,240 +مثلين بياخدوا نص دقيقة عشان ننهي هاي مركب انتبهوا + +503 +00:41:55,240 --> 00:41:58,480 +معاك اداش الكلام سريع هاي دايازو كومباوند فقد + +504 +00:41:58,480 --> 00:42:04,410 +الدايازو صار ايش كربي يعني الكربي الباطن هناعمل + +505 +00:42:04,410 --> 00:42:09,530 +الحلقة الثلاثية واضح تكوين كربين وحلقة ثلاثية + +506 +00:42:09,530 --> 00:42:14,470 +فالحلقة الثلاثية من الكربين وهي هنا مثال تاني + +507 +00:42:14,470 --> 00:42:19,750 +الحقيقة بحتاج إلى وقت طويل اللي هو ال insertion of + +508 +00:42:19,750 --> 00:42:24,950 +carbons وموضوع ال nitrenes فيهم ال generation + +509 +00:42:24,950 --> 00:42:30,690 +وامثلة على ال addition و ال insertion كل هذا + +510 +00:42:30,690 --> 00:42:36,820 +الكلام بنخليهللمرة القادمة لكن اسمنا اتعرفنا على + +511 +00:42:36,820 --> 00:42:39,600 +ال Carbines او على التفاعل الأول في ال Carbines + +512 +00:42:39,600 --> 00:42:44,040 +اللي هو ال Cycloaddition لما ناخد ال Cycloaddition + +513 +00:42:44,040 --> 00:42:48,320 +هنعرف ان هذا بيسموه Chelotropiccycloaddition + +514 +00:42:48,320 --> 00:42:53,340 +reaction اتشيلو او اتشيلي يعني تكتب بطريقة اتشيلو + +515 +00:42:53,340 --> 00:42:57,360 +تربيك و اتشيلي تربيك هيمور مرة تانية في تصنيف + +516 +00:42:57,360 --> 00:43:00,700 +الـcycloadditions نفس هذا التفاعل اللي هناخده على + +517 +00:43:00,700 --> 00:43:04,500 +الكاربين والنيترين في الـcycloaddition ابهيك + +518 +00:43:04,500 --> 00:43:10,040 +ابننهي ان شاء الله و إلى لقاء قادم في المرة + +519 +00:43:10,040 --> 00:43:11,680 +القادمة ان شاء الله + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/-ViGZbdn3ZM.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/-ViGZbdn3ZM.srt new file mode 100644 index 0000000000000000000000000000000000000000..29370443dc3b72701452a902437bf4e9c1cd96a6 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/-ViGZbdn3ZM.srt @@ -0,0 +1,1823 @@ +1 +00:00:20,770 --> 00:00:26,750 +بسم الله الرحمن الرحيم خلينا نستكمل شيئًا بسيطًا في + +2 +00:00:26,750 --> 00:00:31,370 +موضوع الإغلاق على الرابطة الزوجية cyclization of + +3 +00:00:31,370 --> 00:00:35,410 +double bonds وإن شاء الله بيكون يعني معظم دارسينا + +4 +00:00:35,410 --> 00:00:40,110 +اليوم في الإغلاق على الرابطة الثلاثية لكن نستكمل + +5 +00:00:40,110 --> 00:00:46,430 +بعض الأمثلة الآن. آخر شغل اتكلمنا عنها اللي هو إنه + +6 +00:00:46,430 --> 00:00:50,930 +يكون الـorthoposition النوكليوفيل هذا الكلام قلنا + +7 +00:00:50,930 --> 00:00:55,050 +عنه أنه كثير مفيد لأنه بساعدني في تحضير الـfused + +8 +00:00:55,050 --> 00:01:00,370 +rings يعني أول ما الإنسان بده يشوف fused rings + +9 +00:01:00,370 --> 00:01:06,020 +ويقول إيش الـdisconnection اللي موجود عنده، بدي أقول + +10 +00:01:06,020 --> 00:01:08,720 +إيش الـdisconnection اللي موجود عنده، يعني لو أنا + +11 +00:01:08,720 --> 00:01:13,960 +جبت لكم في الامتحان هذا المركب الآن، بدي أذكر إنه + +12 +00:01:13,960 --> 00:01:19,180 +جنب الـdouble bond قلت لكم اعملوا كثير هنا، اعملوا + +13 +00:01:19,180 --> 00:01:30,400 +كثير يعني هذه إيش هتخلوها؟ C=O هاي + +14 +00:01:30,400 --> 00:01:35,820 +البنزين هن، أنا هنا عملت الكسر وهن جنب هدي الـ + +15 +00:01:35,820 --> 00:01:39,760 +double bond زي ما عملنا بالأمثلة السابقة، وهدي بترجع + +16 +00:01:39,760 --> 00:01:43,360 +لـC=O، ولأن لو الـorthoposition هجم + +17 +00:01:43,360 --> 00:01:47,740 +هيعمل هن إيش؟ هيعمل هن الـdouble bond لأن بعدك هذا + +18 +00:01:47,740 --> 00:01:54,080 +الجزء ممكن أن أعمله بهدوء من هن على أساس إنه + +19 +00:01:54,080 --> 00:02:01,420 +البنزين بجيب له نيترو، نيترو بخليه أمينو وهكذا، بدو + +20 +00:02:01,420 --> 00:02:06,800 +الإنسان بالتأكيد خبرة في هذا الموضوع، لكن الـ + +21 +00:02:06,800 --> 00:02:10,580 +cyclization على الـorthopositions موضوع كثير مهم + +22 +00:02:10,580 --> 00:02:15,360 + لمنطقة إيش؟ الـsynthesis of fused heterocyclic + +23 +00:02:15,360 --> 00:02:21,300 +rings الآن في عندي هنا بعض الأمثلة، يمكن أنا أركز + +24 +00:02:21,300 --> 00:02:25,540 +فيها على خطوة الإغلاق يعني المثال كبير ومثال من + +25 +00:02:25,540 --> 00:02:29,300 +اللي بيشتغلون الناس في الـresearch لكن أنا بهمني + +26 +00:02:29,300 --> 00:02:35,320 +مش كل شغلة، يعني في المثال بقدر ما بهمني لحظة + +27 +00:02:35,320 --> 00:02:39,660 +الإغلاق، شو نوع الـcyclization في كيمستري قبله + +28 +00:02:39,660 --> 00:02:44,460 +أحيانًا سهل، أحيانًا صعب شوية، يعني لاحظوا هذا المركب + +29 +00:02:44,460 --> 00:02:49,160 +اللي هو pyrimidine derivative مع aniline عمل هنا + +30 +00:02:49,160 --> 00:02:54,670 +إبدال للـCl مع النيتروجين صار عنده هذا الـenergy + +31 +00:02:54,670 --> 00:02:59,590 +عمل مع الـDMF والفوسفورالكلوريد هذا تفاعل في الـ + +32 +00:02:59,590 --> 00:03:04,710 +name reactions أخذتو اسمه Vilsmeier-Huck reaction + +33 +00:03:04,710 --> 00:03:09,150 +بحط الـformyl group، بحط الـformyl group، حط الـ + +34 +00:03:09,150 --> 00:03:13,970 +formyl group هذا الآن بعد ما أصبح لدي هنا Formally + +35 +00:03:13,970 --> 00:03:19,090 +Group هاي Orthoposition وهاي C=O ع طول + +36 +00:03:19,090 --> 00:03:23,330 +قلت الـOrthoposition عـC=O شو بيعمل؟ + +37 +00:03:23,330 --> 00:03:30,650 +OH مع H بيعمل Double Bond غالبًا بهذا الموقع، ربما + +38 +00:03:30,650 --> 00:03:37,070 +تكون منسية لأن هنا في إمكانية هاي Addition OH H + +39 +00:03:38,210 --> 00:03:45,050 +واضح الفكرة؟ فالـcyclization الخلاصة فعلاً شغل ortho + +40 +00:03:45,050 --> 00:03:50,580 +position in this example وطبعًا ممكن نجيب أمثلة + +41 +00:03:50,580 --> 00:03:54,140 +ثانية، يعني لاحظوا الباحث عادة اللي بيكون عنده + +42 +00:03:54,140 --> 00:03:58,740 +نقطة انطلاق ينطلق منها بيصير يغير ويعمل مشتقات + +43 +00:03:58,740 --> 00:04:03,120 +كثيرة، يعني نفس المركب السابق بدل مفاعله مع فنل + +44 +00:04:03,120 --> 00:04:09,120 +NH2 إجهان فاعله مع هيدرازين NH2NH2 بدل الـCl + +45 +00:04:10,440 --> 00:04:15,940 +بنيتروجين N-H N-H2 بعد هيك بيجي فاعله مع 1,2 + +46 +00:04:15,940 --> 00:04:19,060 +-dicarbonyl compounds كلنا عارفين إن الـC= + +47 +00:04:19,060 --> 00:04:27,200 +O مع الـN-H2 بيحفه مية C=N هيعمل + +48 +00:04:27,200 --> 00:04:32,320 +هنا C=N phenyl C=O phenyl + +49 +00:04:32,320 --> 00:04:36,200 +الآن أنا الخطوة بتاعتي اليوم شو هي؟ الـcyclization + +50 +00:04:36,200 --> 00:04:40,100 +على الـorthoposition هي الـcyclization على الـ + +51 +00:04:40,100 --> 00:04:43,600 +orthoposition اللي أنا بدي إياه، واضح الفكرة؟ + +52 +00:04:43,600 --> 00:04:47,040 +يعني الفكرة الأساسية اللي عندي اللي هي فكرة الـ + +53 +00:04:47,040 --> 00:04:51,220 +cyclization على الـorthoposition بيجيكوا تحفظوا كل + +54 +00:04:51,220 --> 00:04:55,320 +الأمثلة هذه أو تتوهوا فيها بقدر ما إنكم تكونوا + +55 +00:04:55,320 --> 00:05:00,430 +ماخدين إيش فكرة عن الموضوع، بالتأكيد هيكون في الـ + +56 +00:05:00,430 --> 00:05:04,470 +homework اللي هيكون مطلوب منكم إن تجيبوا لنا أقل شيء + +57 +00:05:04,470 --> 00:05:09,230 +من الـrecent research cyclization على + +58 +00:05:09,230 --> 00:05:12,410 +orthoposition يعني مجرد ما تفتحوا مجلة organic و + +59 +00:05:12,410 --> 00:05:16,430 +تشوفوا حلقات بتتحضر هتلاقوا few strings فمرات + +60 +00:05:16,430 --> 00:05:21,710 +كثيرة كيف حضرها، كيف خطوة الـcyclization هتلاحظوا + +61 +00:05:21,710 --> 00:05:27,420 +إنها cyclization على orthoposition تقريبًا كل + +62 +00:05:27,420 --> 00:05:30,800 +الأمثلة اللي مرت علينا لحد الآن كانت إغلاق على C + +63 +00:05:30,800 --> 00:05:35,560 +double bond O الآن الـC=S والـC + +64 +00:05:35,560 --> 00:05:39,460 +double bond N بيشبه الـC=O لكن الـC + +65 +00:05:39,460 --> 00:05:45,040 +double bond C فيها إيش احتمالان، هاي أنا عندي مثال + +66 +00:05:45,040 --> 00:05:52,610 +على إغلاق على C=S لو أخذنا هذا المركب + +67 +00:05:52,610 --> 00:05:57,810 +اللي هو عبارة عن diol alcohol يعني R2C الـC حاملة + +68 +00:05:57,810 --> 00:06:01,390 +OH، بعدين C ثانية حاملة OH يعني لو بدي آخده هذا + +69 +00:06:01,390 --> 00:06:08,870 +الجزء هو هذا كان زي هيك على موقع واحد واتنين عنده + +70 +00:06:08,870 --> 00:06:17,050 +OHOH فعلته مع المركب C=SCl2 هي الـC + +71 +00:06:17,050 --> 00:06:23,630 +double bond S Cl2 متذكرينه هذا إيش اسمه؟ + +72 +00:06:23,630 --> 00:06:29,710 +متذكرين ابن عمه؟ آه، ابن عمه اللي فيه الـoxygen + +73 +00:06:29,710 --> 00:06:35,670 +الفسجين، الغاز تبع الحروب السام، غاز الفسجين الآن + +74 +00:06:35,670 --> 00:06:44,390 +هذا ثيوفسجين، إذا هذا فسجين، هذا + +75 +00:06:48,780 --> 00:06:55,000 +الثيوفسجين والفسجين هما عبارة عن داى إلكتروفيل + +76 +00:06:55,000 --> 00:07:01,840 +وبالعكس الـالديهايدز والكيتونات بتفاعلوا كداى + +77 +00:07:01,840 --> 00:07:07,210 +إلكتروفيل ولا لأ؟ مروا عليكم إنه من الـالديهايد و + +78 +00:07:07,210 --> 00:07:14,390 +الـكيتون بمثل داى إلكتروفيل ومثلهم إيش؟ الفسجين + +79 +00:07:14,390 --> 00:07:18,830 +هذا ممكن يشتغل داى إلكتروفيل، الـEster بيشتغل داى + +80 +00:07:18,830 --> 00:07:26,830 +إلكتروفيل ولا لأ؟ الـEster بهمش، خلّينا نتذكر لو + +81 +00:07:26,830 --> 00:07:30,250 +قلنا R النوكليوفيل زائد + +82 +00:07:35,680 --> 00:07:42,480 +الآن هذي الـC.. هذي الـC Electrophile + +83 +00:07:42,480 --> 00:07:50,560 +ولا لأ؟ صار عندكم CH3C=O النوكليوفيل R + +84 +00:07:50,560 --> 00:07:56,210 +الآن ممكن يجي النوكليوفيل ثاني يهاجم، بيصير aldehyde + +85 +00:07:56,210 --> 00:07:59,550 +أو كيتون عند نزوم، أحيانًا ممكن ييجي نوكليوفايل + +86 +00:07:59,550 --> 00:08:04,350 +ثاني يهاجم يعمل Addition فبيشتغلوا كـdie + +87 +00:08:04,350 --> 00:08:07,930 +electrophile الآن من الـdie electrophiles اللي + +88 +00:08:07,930 --> 00:08:11,950 +مشهورة بدون خلاف، اللي مشهورة بدون خلاف الفسجين + +89 +00:08:11,950 --> 00:08:16,810 +والثيوفسجين ليش؟ لأنه ممكن نوكليوفايل يهاجم يعمل + +90 +00:08:16,810 --> 00:08:21,470 +إبدال أول ونوكليوفايل ثاني يهاجم يعمل إبدال ثاني + +91 +00:08:21,470 --> 00:08:26,460 +يعني هذه أسهل ما يمكن اللي هم إيش؟ الفسجين + +92 +00:08:26,460 --> 00:08:33,640 +والثيوفسجين فلما هذا النوكليوفيل هاجم طرد أول Cl + +93 +00:08:33,640 --> 00:08:37,300 +إذا عمل Substitution هنا ولو إجا كمان هذه + +94 +00:08:37,300 --> 00:08:41,440 +الأكسجين وهاجمت ما تحطوا ترد، إذا كام Substitution + +95 +00:08:41,440 --> 00:08:44,540 +صار عندي لما تتكون المركب Two Successive + +96 +00:08:44,540 --> 00:08:51,900 +Substitutions هو تفاعل على الـC=S لكن + +97 +00:08:51,900 --> 00:08:55,920 +هنا اللي تم عندي Addition ولا Substitution Two + +98 +00:08:55,920 --> 00:08:56,520 +Substitutions + +99 +00:08:58,990 --> 00:09:05,210 +هنا في عندنا مثال على تفاعل على Carbon double bond + +100 +00:09:05,210 --> 00:09:10,270 +Carbon لاحظوا معي في عندي في هذا المثال activated + +101 +00:09:10,270 --> 00:09:15,370 +Hydrogen هذه الهيدروجين اللي هنا activated لأنها + +102 +00:09:15,370 --> 00:09:20,070 +جنبها C=O وكمان C=O وكمان + +103 +00:09:20,070 --> 00:09:24,030 +N يعني هذه هيلو activated يعني بدها Base قوية ولا + +104 +00:09:24,030 --> 00:09:31,200 +ضعيفة؟ Base ضعيفة، الآن شلنا الهيدروجين شو عملنا؟ عملنا + +105 +00:09:31,200 --> 00:09:35,980 +سالب، هتبدأ السالب إذا تروح على الـCarbon double + +106 +00:09:35,980 --> 00:09:41,060 +bond Carbon الأصل، الآن كام Cyclization ممكن عندك + +107 +00:09:41,060 --> 00:09:48,520 +اثنين، إذا فعلنا بهذا الشكل وهذه تحركت للخارج بحيث + +108 +00:09:48,520 --> 00:09:53,910 +تصير هنا C− وبعدين CH، لاحظوا بعد ما تصير Minus + +109 +00:09:53,910 --> 00:09:59,450 +شو هتحط هنا؟ H، هذا الـcyclization اللي أنتم + +110 +00:09:59,450 --> 00:10:04,330 +شايفينه Exo ولا Endo؟ Exo، إذا هي الـcyclization + +111 +00:10:04,330 --> 00:10:09,330 +الخضراء هذا Exo cyclization بيقدر تكون الحلقة + +112 +00:10:09,330 --> 00:10:15,510 +الرباعية، طيب الآن نعمل الـcyclization الأحمر لو + +113 +00:10:15,510 --> 00:10:22,230 +هذا الهجوم تم هنا وهذه إيجي هنا وهتصير CH شو + +114 +00:10:22,230 --> 00:10:28,070 +حيصير عندي حلقة خمسية بهذا الشكل N C=O + +115 +00:10:28,070 --> 00:10:34,050 +C وأنا C وهذي C بهذا الشكل، واضح وهنا هيكون + +116 +00:10:34,050 --> 00:10:43,730 +عندكم CO2 Ethyl وهنا CO2 Ethyl وCO2 Ethyl هذا الـ + +117 +00:10:43,730 --> 00:10:49,500 +cyclization تم على أي ذرة؟ على هذه هي كإحنا عاملين + +118 +00:10:49,500 --> 00:10:53,780 +صح ولا.. الـCO2 Ethyl شبه الـNitrogen، هان الـCO2 + +119 +00:10:53,780 --> 00:11:01,080 +Ethyl لحظة، هي الـNitrogen هذي الـCarbon اللي هاجمت + +120 +00:11:01,080 --> 00:11:11,040 +هي التلاتة CO2 Ethyl بمعنى + +121 +00:11:11,040 --> 00:11:19,880 +إنه كانت الـdouble bond اللي عندي بهذا الشكل، هاي C + +122 +00:11:19,880 --> 00:11:25,400 +double bond O C C=C فلما تم الـ + +123 +00:11:25,400 --> 00:11:33,460 +cyclization بهذا الشكل، هذه وين هتيجي Minus H واضح + +124 +00:11:33,460 --> 00:11:38,240 +حيصير عندي Endocyclization والحلقة اللي بتتكون + +125 +00:11:38,240 --> 00:11:43,380 +خمسية، إذا مثل هذا المثال لو اجانا في امتحان وكنا + +126 +00:11:43,380 --> 00:11:49,260 +بنجاوبه، كام احتمال عندي؟ احتمالين الـExocyclization + +127 +00:11:49,260 --> 00:11:54,380 +والـEndocyclization لازم أنتم بايدكم تتدربوا + +128 +00:11:54,380 --> 00:11:58,980 +على هدول، ربما + +129 +00:11:58,980 --> 00:12:03,640 +إنه هذا الكربونيل اللي جنب الآن امدهذه مشكلة فيها + +130 +00:12:03,640 --> 00:12:08,660 +والمشكلة الثانية إن تعمل حلقة ثلاثية، يعني من + +131 +00:12:08,660 --> 00:12:16,930 +ناحية النظرية البحث في ذرة احتمال لكن لما نيجي نمد + +132 +00:12:16,930 --> 00:12:22,510 +وثلاثية فيها مشكلتين، طبعًا الكل هيجي يقول إنه أنا + +133 +00:12:22,510 --> 00:12:25,650 +أفضل في الحلقات الخماسية ولا الرباعية؟ الخماسية.. + +134 +00:12:25,650 --> 00:12:26,970 +الخماسية.. الخماسية.. الخماسية.. الخماسية.. + +135 +00:12:26,970 --> 00:12:27,590 +الخماسية.. الخماسية.. الخماسية.. الخماسية.. + +136 +00:12:27,590 --> 00:12:28,050 +الخماسية.. الخماسية.. الخماسية.. الخماسية.. + +137 +00:12:28,050 --> 00:12:29,190 +الخماسية.. الخماسية.. الخماسية.. الخماسية.. + +138 +00:12:29,190 --> 00:12:33,810 +الخماسية.. الخماسية.. الخماسية.. الخماسية.. + +139 +00:12:33,810 --> 00:12:37,850 +الخماسية.. الخماسية.. الخماسية.. الخماسية.. + +140 +00:12:37,850 --> 00:12:41,090 +الخماسية.. الخماسية.. الخماسية.. الخماسية.. + +141 +00:12:41,090 --> 00:12:43,190 +الخماسية .. الخماسية .. الخماسية .. الخماسية .. + +142 +00:12:43,190 --> 00:12:45,090 +الخماسية .. الخماسية .. الخماسي ولذلك مرات بيستعملوا + +143 +00:12:45,090 --> 00:12:48,570 +مصطلح بفترض أنه مار عليكم بال physical chemistry + +144 +00:12:48,570 --> 00:12:53,270 +بيقولوا في عندي شيء اسمه kinetic product وفي شيء + +145 +00:12:53,270 --> 00:12:57,230 +اسمه thermodynamic product الآن لو أنا بدي أصنف + +146 +00:12:57,230 --> 00:13:02,070 +هذه الخماسية بدي أقول عنها شيء thermodynamic + +147 +00:13:02,070 --> 00:13:07,130 +product يعني هذا it seems more stable هذا ال + +148 +00:13:07,130 --> 00:13:12,090 +product more stable Thermodynamic product الخماسي + +149 +00:13:12,090 --> 00:13:17,530 +أثبت من رباعي لكن ربما لما تم الإغلاق وهذه ال + +150 +00:13:17,530 --> 00:13:23,750 +minus بدأت تتفاعل بسرعة من الأقرب لها هذا الطرف ولا + +151 +00:13:23,750 --> 00:13:27,870 +هذا؟ فوجدت هذا الطرف فهذا ال product اللي اتكون + +152 +00:13:27,870 --> 00:13:32,430 +ايش هو بيكون ال kinetic product مرات كتير الناس + +153 +00:13:32,430 --> 00:13:35,550 +اللي بدرسوا هذا الموضوع بيعرفوا أنه بتكون kinetic + +154 +00:13:35,550 --> 00:13:39,830 +product بتكون بفصلوه بسيبوه بعد فترة بالذات لو + +155 +00:13:39,830 --> 00:13:44,470 +تركوه بالمحلول بيلاقوه بيعود بفكوا بتحول إلى + +156 +00:13:44,470 --> 00:13:49,010 +thermodynamic product واضح؟ لكن اللي موجود عندنا + +157 +00:13:49,010 --> 00:13:52,110 +احنا في هذا المثال ال kinetic product ولا ال + +158 +00:13:52,110 --> 00:13:54,950 +thermodynamic product ال kinetic product ليس ال + +159 +00:13:54,950 --> 00:14:00,690 +stable product لكن غالباً أنه بتكون بشكل أسرع غالباً + +160 +00:14:00,690 --> 00:14:10,250 +أنه بتكون بشكل أسرع هنا + +161 +00:14:10,250 --> 00:14:17,210 +في عندي مثال ثاني على عملية cyclization at carbon + +162 +00:14:17,210 --> 00:14:21,810 +-carbon double bond و المرة هذه لل nucleophile + +163 +00:14:21,810 --> 00:14:25,930 +اللي موجود عنده هو ال sulfur ال nucleophile هنا + +164 +00:14:25,930 --> 00:14:29,710 +بدي أنا بحكي لشغلة ال C double bond S ال sulfur + +165 +00:14:29,710 --> 00:14:34,250 +كتير بحب يشتغل ك nucleophile عشانكم مرات كتيرة و + +166 +00:14:34,250 --> 00:14:38,090 +انتوا بتشتغلوا على C double bond S بتلاقوها بتهاجم + +167 +00:14:38,090 --> 00:14:42,290 +من عند إيش؟ السلفر .. انتوا لو اتطلعتوا على هذا + +168 +00:14:42,290 --> 00:14:46,790 +التفاعل .. لاحظوا هذا التفاعل كيف عملوه .. فعلوه + +169 +00:14:46,790 --> 00:14:51,150 +في وجود بروم ..الآن البروم متذكرين انتوا على ال + +170 +00:14:51,150 --> 00:14:56,360 +double bond كان يضيف في الأول بروم بلس يعمل + +171 +00:14:56,360 --> 00:15:02,020 +برومونيوم أيون بذات لما أخدنا تفاعل اللي هو + +172 +00:15:02,020 --> 00:15:05,040 +addition of بروم to double bond bromination + +173 +00:15:05,040 --> 00:15:10,720 +الناس اللي متذكرين ال carbon double bond carbon مع + +174 +00:15:10,720 --> 00:15:16,180 +ال PR2 كنا نقول أن التفاعل بيبدأ بإضافة لبروم و + +175 +00:15:16,180 --> 00:15:22,060 +بيعمل برومونيوم أيون الآن بتضطر لبروم التانية + +176 +00:15:22,060 --> 00:15:29,910 +تيجي من وين؟ من العكس الـ PR الـ minus وعشان هيك اللي + +177 +00:15:29,910 --> 00:15:32,970 +هو ال addition of bromine to double bonds ايش كنا + +178 +00:15:32,970 --> 00:15:36,810 +نقول عنه؟ سن + +179 +00:15:36,810 --> 00:15:41,010 +ولا انتي اديشن انتي اديشن لما كنا ناخد الهيدروجين + +180 +00:15:41,010 --> 00:15:46,490 +في وجود مثل نقول سن اديشن هنا نقول انتي اديشن + +181 +00:15:46,490 --> 00:15:52,070 +الخلاصة أن إضافة البروم الموجب بيخلي هذه الكربون + +182 +00:15:52,070 --> 00:15:58,420 +بالإمكان أنه يجي يهاجم عليها ايش؟ بروم نيجاتيف يعني + +183 +00:15:58,420 --> 00:16:03,700 +هنا في عندي بير كاربون لو اجى في حالة البروميناشن + +184 +00:16:03,700 --> 00:16:08,000 +هييجي بير نيجاتيف في حالة زي هذه الحالة أنا استعانت + +185 +00:16:08,000 --> 00:16:12,500 +في البرومين واتفعل هنا شو اللي نيكليوفيل اللي عندي + +186 +00:16:12,500 --> 00:16:18,960 +سالفرواضح؟ Sulphur مش PR يعني كأنه صار عندي الهجوم + +187 +00:16:18,960 --> 00:16:25,160 +ل Sulphur و PR و مبينين انتي ولا لأ؟ يعني أصلاً هذي + +188 +00:16:25,160 --> 00:16:29,500 +اللي كانت double bond ملاحظين؟ + +189 +00:16:29,500 --> 00:16:34,140 +هذي اللي كانت أصلاً double bond لما ضف عليها لبرومو + +190 +00:16:34,140 --> 00:16:38,720 +.. لبرومو عمل برومونيوم أيون سكرت بإيش؟ بال + +191 +00:16:38,720 --> 00:16:42,600 +Sulphur مثل هذه الأمثلة متذكرين أنه أخدتوا زيها + +192 +00:16:42,600 --> 00:16:48,100 +انتوا بالظبط؟ لما كنا ناخد ال double bond و نقولكوا + +193 +00:16:48,100 --> 00:16:59,520 +مع PR2 في وجود مثلاً CL minus تبدأوا التفاعل ب A و + +194 +00:16:59,520 --> 00:17:12,050 +تكملوا ب R ب CL أو لو كان عندكوا مية تكملوه ب O H و + +195 +00:17:12,050 --> 00:17:19,090 +صار عندكم اللي هي ال halohedrons اللي هي المركبات + +196 +00:17:19,090 --> 00:17:25,120 +اللي فيها halogens و OHs كل هذا الكلام أرجو أنكم + +197 +00:17:25,120 --> 00:17:28,380 +ترجعوه يعني كتير بنحتاج كيميا نرجعها من السابق + +198 +00:17:28,380 --> 00:17:32,700 +اللي هو التفاعل على ال double bonds تفاعل + +199 +00:17:32,700 --> 00:17:36,240 +البروميناشن تفاعل ال hydrogenation تفاعل + +200 +00:17:36,240 --> 00:17:40,120 +البروميناشن في وجود أيون سالب يبدأ التفاعل + +201 +00:17:40,120 --> 00:17:44,600 +بالبروميناشن و يكمل بالأيون السالب وهذا مثال عليه + +202 +00:17:44,600 --> 00:17:51,460 +تمام؟ الآن ربما جزء من اللي بيساعد التفاعل هنا و + +203 +00:17:51,460 --> 00:17:56,440 +بشجع ال sulfur أكثر أنه يعمل ك ال nucleophile ال + +204 +00:17:56,440 --> 00:17:59,840 +nitrogen اللي قريبة يعني زوج الإلكترونات زوج + +205 +00:17:59,840 --> 00:18:03,540 +الإلكترونات اللي موجود هنا بإمكاننا احنا نتخيل أنه + +206 +00:18:03,540 --> 00:18:07,320 +تتحرك بهذا الشكل خلاص زوج الإلكترونات اللي هنا وين + +207 +00:18:07,320 --> 00:18:11,280 +يتحرك هم لاحظين هذه زوج الإلكترونات اتحرك هنا + +208 +00:18:11,280 --> 00:18:15,140 +معقول يصيروا خمس روابط لأ إذا هذا بده يجي يتحرك + +209 +00:18:15,140 --> 00:18:22,580 +هنا ال PR أخذت زوج الإلكترونات رجعت ل PR عادية و + +210 +00:18:22,580 --> 00:18:27,440 +بتتم التفاعل طبعاً هنا صار عندهم positive nitrogen + +211 +00:18:27,440 --> 00:18:32,360 +لما تم التحرك هنا في وجود الماء التفاعل كله ال C + +212 +00:18:32,360 --> 00:18:36,200 +double bond ان مشهور جداً أنه في وجود المية بتتحول + +213 +00:18:36,200 --> 00:18:40,240 +ل إيش؟ ل C double bond O بصير ال hydrolysis مار + +214 +00:18:40,240 --> 00:18:47,100 +عليكم hydrolysis of امينE means هنا نوع من ال E + +215 +00:18:47,100 --> 00:18:53,580 +means ال C double bond N بالمية بسهولة بتحول إلى C + +216 +00:18:53,580 --> 00:18:57,600 +double bond O كل هذا الكلام تم في هذا المثال أنا + +217 +00:18:57,600 --> 00:19:01,120 +بالنسبة لي المهم أن أنا عملت addition على + +218 +00:19:03,700 --> 00:19:07,480 +الـ Double bond أنا عملت تفاعل على الـ Double bond + +219 +00:19:07,480 --> 00:19:10,940 +الآن انتبهوا معي أن الـ Double bond حتى بمساعدة + +220 +00:19:10,940 --> 00:19:15,940 +لبروميل كم احتمال عندي فيها للـ cyclization اثنين + +221 +00:19:15,940 --> 00:19:21,760 +اثنين مش واحد يعني لما أنا فعلت على هذا الطرف + +222 +00:19:21,760 --> 00:19:26,440 +بيجيني الاحتمال الثاني ما المانع أن أفعل على هذا + +223 +00:19:26,440 --> 00:19:30,500 +الطرف و لو هذا الكلام بده يتم شو بده يكون الناتج + +224 +00:19:30,500 --> 00:19:37,970 +اللي عندي حلقة سداسية فيها السلفر هنا والكربون + +225 +00:19:37,970 --> 00:19:42,150 +والبرومين هنا يعني + +226 +00:19:42,150 --> 00:19:45,590 +لو جيبنالكم هذا وقلنا لكم بدنا ال possible + +227 +00:19:45,590 --> 00:19:49,210 +cyclization product ال possible cyclization + +228 +00:19:49,210 --> 00:19:53,310 +product الحقيقة أن السلفر يهاجم على هذا الكربون أو + +229 +00:19:53,310 --> 00:19:56,490 +على هذا الكربون على هذا الكربون عندكم الحلقة + +230 +00:19:56,490 --> 00:20:01,550 +الخماسية على هذا الكربون عندكم الحلقات السداسية + +231 +00:20:02,270 --> 00:20:06,830 +عليكم الحلقة السداسية والبرومين هنا كان عامل + +232 +00:20:06,830 --> 00:20:12,690 +مساعد في عملية إيش؟ في عملية التفاعل على ال double + +233 +00:20:12,690 --> 00:20:16,890 +bond بطريقة سبق أننا تعلمناها أن البرومين في + +234 +00:20:16,890 --> 00:20:20,430 +الأول بيضيف كبرومين موجب وبعدين ال nucleophile + +235 +00:20:20,430 --> 00:20:28,490 +بيكمل التفاعل هذا الكلام بأمل أنكم إيش؟ تترجعوا في + +236 +00:20:28,490 --> 00:20:33,010 +المنطقة أنا متأكد أن شرحته لكوا في ال organic a + +237 +00:20:33,010 --> 00:20:41,130 +بتذكر الآن تقريباً بنفس الفكرة هنا بيجينا أمثلة + +238 +00:20:41,130 --> 00:20:46,190 +ثانية هنا بيجينا أمثلة ثانية و لاحظوا أن اللي + +239 +00:20:46,190 --> 00:20:49,690 +بيساعد على ال cyclization على ال double bond يعني + +240 +00:20:49,690 --> 00:20:54,750 +هذه carbon carbon double bond ال nitrogen عبارة عن + +241 +00:20:54,750 --> 00:20:58,570 +ال nucleophile الآن صار واضح أندي أن في عندي + +242 +00:20:58,570 --> 00:21:03,970 +nucleophile و في عنده double bond الآن هذا ال + +243 +00:21:03,970 --> 00:21:09,490 +nucleophile وين ممكن يهاجم؟ أما على هذا المكان + +244 +00:21:09,490 --> 00:21:15,430 +وبالتالي exocyclization لو هاجم هنا وين هتيجي هذه؟ + +245 +00:21:15,430 --> 00:21:23,230 +هيصير عنده CH minus مظبوط ولا لا؟ الآن هذه في وجود + +246 +00:21:23,230 --> 00:21:28,590 +mercury chloride ال minus بتتحد مع ال mercury + +247 +00:21:28,590 --> 00:21:33,990 +chloride بدل الذئبق لاحظوا بيصير هذا عامل إيش؟ + +248 +00:21:33,990 --> 00:21:40,470 +مساعد لأنه أول ما هذه بدأت تتفعل هنا هذه CH2 بدأت + +249 +00:21:40,470 --> 00:21:47,190 +تصير CH2 minus الآن ال minus بيهاجم هنا بطرد بطرد + +250 +00:21:47,190 --> 00:21:51,030 +X واحدة من الاثنين و بيعملها دولة بعدين في ظروف + +251 +00:21:51,030 --> 00:21:56,370 +التفاعل لو ضفنا مية أو شيء برجع مكان هذه إيش يتكون + +252 +00:21:56,370 --> 00:22:02,920 +عنده؟ سي أتش ثري فهذه إجت عندي كعامل مساعد لو + +253 +00:22:02,920 --> 00:22:06,480 +اتخيلت أنها مش موجودة مش كنتوا هتكملوا التفاعل + +254 +00:22:06,480 --> 00:22:11,620 +بالشكل القاتل أن هذه هاجمت هذه صارت CH2- و بعدين + +255 +00:22:11,620 --> 00:22:19,180 +أخدت إيش؟ H plus واضح لكن التفاعل في وجود الـ HGX2 + +256 +00:22:19,180 --> 00:22:24,660 +بتم بشكل أفضل لكن كنتيجة لما يصير عند ال + +257 +00:22:24,660 --> 00:22:29,880 +Exocyclization هذا ال CH2 شو بده تصير؟ CH3 الآن هذا + +258 +00:22:29,880 --> 00:22:34,840 +أحد الاحتمالات في عند احتمال ثاني ولا لأ؟ اه + +259 +00:22:34,840 --> 00:22:38,780 +الاحتمال الثاني اللي خلينا نوضحه بالأحمر أن هذه + +260 +00:22:38,780 --> 00:22:49,950 +تهاجمها وجدها هذه كأنها صارت CH- هي أصلاً CH و أخدت + +261 +00:22:49,950 --> 00:22:55,290 +minus بتصير CH- الآن في المحصلة هتاخد H مروراً + +262 +00:22:57,260 --> 00:23:02,020 +بالاستعانة بالزئبق مروراً بالاستعانة بالزئبق إذا + +263 +00:23:02,020 --> 00:23:05,220 +هنا لو قلنا draw the possible cyclization of + +264 +00:23:05,220 --> 00:23:10,140 +products برضه المرسوم واحد منهم اللي هو ال exo ولا + +265 +00:23:10,140 --> 00:23:14,600 +ال endocyclization ال exo الآن ال endo واتدربوا + +266 +00:23:14,600 --> 00:23:19,820 +عليه اللي موجود زي ذلك هذا المثال تقريباً شبيه جداً + +267 +00:23:19,820 --> 00:23:23,920 +فيه عندي نيتروجين وضب ال bond إذا الهجوم تم بهذا + +268 +00:23:23,920 --> 00:23:28,730 +الشكل هذا اللي موجود عنده ال Exo اللي هو طلع + +269 +00:23:28,730 --> 00:23:35,430 +النتيجة و الحلقة المتكونة سداسية طيب لو تم الهجوم + +270 +00:23:35,430 --> 00:23:40,030 +بهذا الشكل شوفنا هذا ال Exo طب لو تم الهجوم بهذا + +271 +00:23:40,030 --> 00:23:40,610 +الشكل + +272 +00:23:43,150 --> 00:23:48,530 +حلقة سباعية و Endocyclization بدكوا تتدربوا أنكوا + +273 +00:23:48,530 --> 00:23:53,650 +ترسموها ليش؟ لأنه احنا بهمنا و كثير بنسألكم أنه ا + +274 +00:23:53,650 --> 00:23:57,390 +draw all the possible cyclization products فأنا + +275 +00:23:57,390 --> 00:24:01,430 +لما بحكي عن carbon double bond carbon بدكوا تعودوا + +276 +00:24:01,430 --> 00:24:06,110 +أنفسكم أنكوا ترسموه الناتجين اللي على طرفين الرابطة + +277 +00:24:06,110 --> 00:24:12,080 +الزوجية بعد هيك بتروحوا بتعملوا التجربة بتفصلوا + +278 +00:24:12,080 --> 00:24:16,380 +ناتج هالناتج بيستعمل طرق التشخيص هو هذا ولا هذا + +279 +00:24:16,380 --> 00:24:21,660 +بتهيئال طرق التشخيص سهل أن أنا أوضح لكم الجواب + +280 +00:24:21,660 --> 00:24:25,420 +يعني إذا بدنا نطلع شوية من ال heterocycle ال + +281 +00:24:25,420 --> 00:24:28,680 +chemistry للتشخيص لو فكرنا هنا أن احنا عاملين + +282 +00:24:28,680 --> 00:24:33,880 +الحلقة السباعية هيكون + +283 +00:24:33,880 --> 00:24:38,540 +عندكم هنا unmatched وهنا واحد اثنين ثلاثة أربعة خمسة + +284 +00:24:38,540 --> 00:24:45,470 +ساعةزيك الناتج carbon اثنين ثلاثة carbon اثنين + +285 +00:24:45,470 --> 00:24:49,930 +ثلاثة مش ال cyclization تمهان كم carbon صاروا + +286 +00:24:49,930 --> 00:24:55,650 +هدول اللي بين الـ N و الـ O ثلاثة لو الـ + +287 +00:24:55,650 --> 00:24:58,970 +cyclization تمهان كم carbon اثنين اثنين اللي هم + +288 +00:24:58,970 --> 00:25:03,410 +هدول الـ N الناتج المتوقع أما هذا الناتج أو هذاك + +289 +00:25:03,410 --> 00:25:11,410 +ناتج المفروض أن أنتم تشتغلوا ترسموا الناتجين بعدين + +290 +00:25:11,410 --> 00:25:16,470 +بتفصلوا هالمركب اللي طلع عندكم بتروحوا بتعملوله + +291 +00:25:16,470 --> 00:25:23,350 +spectroscopic analysis IR و NMR و Carbon 13 و ما + +292 +00:25:23,350 --> 00:25:27,010 +إلى ذلك و حسب النواتج بتقولوا آه اللي طلع عندي هذا + +293 +00:25:27,010 --> 00:25:30,470 +و هذا شو أسهل طريقة في التشخيص تتميز الـ اثنين هدول + +294 +00:25:30,470 --> 00:25:36,850 +عن بعض هدى NR ولا .. NR مش موضوع خلافه شو أسهل + +295 +00:25:36,850 --> 00:25:42,110 +طريقة في التشخيص تتميز هدول إيش اللي بده يبين ليه + +296 +00:25:42,110 --> 00:25:50,750 +إيش الإشارة الأكثر وضوحًا CH3 هذاك في CH3 على طول + +297 +00:25:50,750 --> 00:25:57,990 +حتى يمكن بجهاز الـ IR حتى يمكن بجهاز الـ IR عند 1380 + +298 +00:25:57,990 --> 00:26:01,450 +لا + +299 +00:26:01,450 --> 00:26:01,810 +لا + +300 +00:26:05,720 --> 00:26:13,460 +CH3 CH3 الـ ISO في هذه المنطقة يتبين زي هي CH3 + +301 +00:26:13,460 --> 00:26:18,560 +عادية طبعًا الأسهل كثير في الـ proton NMR يعني بين + +302 +00:26:18,560 --> 00:26:22,300 +هذا المركب اللي محناه و بين هذا في الـ proton NMR + +303 +00:26:22,300 --> 00:26:27,640 +أن أشوف CH3 ولا أشوف ثلاثة CH2 في الـ carbon 13 NMR + +304 +00:26:27,640 --> 00:26:33,850 +يعني التشخيص ليس عملية صعبة مش موضوعنا الآن لكن + +305 +00:26:33,850 --> 00:26:38,670 +احنا موضوعنا أنه دائمًا و أبدًا بدنا نفكر لما بنحكي + +306 +00:26:38,670 --> 00:26:45,050 +عن اغلاق على الـ double bond بكم ناتج الـ carbon + +307 +00:26:45,050 --> 00:26:49,670 +carbon double bond بناتجين و بتكون تعودوا إيديكوا + +308 +00:26:49,670 --> 00:26:56,370 +أنكوا ترسموا الناتجين بهيك تقريبًا بنكون انتهينا من + +309 +00:26:58,040 --> 00:27:12,840 +هذا الجزء المتعلق بالاغلاق على الـ double bond الآن + +310 +00:27:12,840 --> 00:27:19,500 +لو انتقلنا لدرسنا اليوم اللي هو الاغلاق على الـ + +311 +00:27:19,500 --> 00:27:25,750 +triple bond أسهل شيء الإنسان يقوله أنه يتذكر قول + +312 +00:27:25,750 --> 00:27:30,390 +الشاعر اللي بيقول ما ترانا نقوله إلا معادًا من + +313 +00:27:30,390 --> 00:27:33,850 +قولنا مكرورة يعني أنا ممكن أدعي أنه مش هنجيب + +314 +00:27:33,850 --> 00:27:39,450 +تقريبًا إشي جديد في الموضوع والدليل على هيك أنه بدنا + +315 +00:27:39,450 --> 00:27:44,920 +نبدأ بهذه اللوحة لمرة معناها ونقول أنه في الـ + +316 +00:27:44,920 --> 00:27:48,080 +cyclization على الـ triple bond عنده احتمالين + +317 +00:27:48,080 --> 00:27:53,480 +exocyclization و endocyclization الآن للـ triple + +318 +00:27:53,480 --> 00:28:01,280 +bonds المشهورة في الدنيا شو هي؟ عنده C triple bond + +319 +00:28:01,280 --> 00:28:08,840 +N R C triple bond N واضح؟ نشوف على أرض الواقع شو + +320 +00:28:08,840 --> 00:28:14,580 +اللي بي .. R C triple bond N وعندي R N triple bond + +321 +00:28:14,580 --> 00:28:20,900 +C وعندي R C triple bond C هدول الثلاثة المشهورين + +322 +00:28:20,900 --> 00:28:24,960 +في الدنيا هدول اللي هناخد عليهم أنثى لك الآن وين + +323 +00:28:24,960 --> 00:28:31,080 +بيتم الإغلاق؟ على الأحمر وين الأحمر؟ + +324 +00:28:39,960 --> 00:28:44,420 +واضح؟ أصل طريقة نفهم من قبل لما يكون عنده نيترالز + +325 +00:28:44,420 --> 00:28:49,100 +الهجوم على هذا الكربون لما يكون عنده أيزو نيترالز + +326 +00:28:49,100 --> 00:28:52,580 +أو أيزو سيا نايتز الهجوم على هذا الكربون يعني هنا + +327 +00:28:52,580 --> 00:28:57,520 +دائمًا اكزو هنا دائمًا اندو هنا اندلال + +328 +00:28:59,980 --> 00:29:04,040 +واضح؟ اللي فاهم هالكلام و بده يطلع اليوم تعب + +329 +00:29:04,040 --> 00:29:08,360 +بإمكانه يطلعه كل اللي هنشرحه أمثلة تطبيقية على + +330 +00:29:08,360 --> 00:29:13,700 +هدول الثلاث نقاط أنه ناخد C triple bond C مرة هن و + +331 +00:29:13,700 --> 00:29:18,980 +مرة هن C triple bond N دائمًا هن N triple bond C + +332 +00:29:18,980 --> 00:29:27,890 +دائمًا هن واضح؟ يعني بهيك احنا بنكون خلصنا محاضرة + +333 +00:29:27,890 --> 00:29:39,950 +اليوم كفكرة و كل اللي بيضل عندنا أمثلة أمثلة + +334 +00:29:39,950 --> 00:29:46,250 +على الموضوع، الآن في الأمثلة على الموضوع الكمبيوتر + +335 +00:29:46,250 --> 00:29:48,330 +اتمرد شوية + +336 +00:29:53,590 --> 00:29:57,670 +لا بس ما حلوه يتمرضى بنقطع .. بنقطع التسجيل + +337 +00:29:57,670 --> 00:30:07,670 +دقيقتين المفروض + +338 +00:30:07,670 --> 00:30:15,990 +أنا نسخة الـ file الجديد اللي فيه خمسة عشر slide هذا + +339 +00:30:15,990 --> 00:30:18,270 +نسخ + +340 +00:30:29,950 --> 00:30:31,350 +و أنتِ؟ + +341 +00:30:57,010 --> 00:30:59,050 +فاير و برايا دي كانت كلها كده + +342 +00:31:33,910 --> 00:31:40,050 +بنستمر و قلنا احنا كل اللي هنشوفه هو أمثلة على + +343 +00:31:40,050 --> 00:31:44,930 +الإغلاق على نيترالز و أيزو نيترالز و carbon-carbon + +344 +00:31:44,930 --> 00:31:49,470 +triple bonds خلّينا نشوف الأمثلة بسرعة في هذا + +345 +00:31:49,470 --> 00:31:55,070 +المثال بتوقع أن يتكون عدة ناتج ولا ناتجين ناتجين + +346 +00:31:55,070 --> 00:31:59,410 +الإغلاق على هذا الموقع وعلى هذا الموقع واضح طبعًا + +347 +00:31:59,410 --> 00:32:04,690 +أي إغلاق اللي مبين أنه تم بالتجربة واحد هذه لما + +348 +00:32:04,690 --> 00:32:08,530 +بتيجي هنا الـ C minus بتاخد H مبينة موجودة عندكم + +349 +00:32:08,530 --> 00:32:13,650 +يعني الـ C triple bond C بيبدأ يصير C double bond C + +350 +00:32:13,650 --> 00:32:18,430 +لأن التحول كانت رابطة من الثلاثة كذلك الحال في هذا + +351 +00:32:18,430 --> 00:32:24,210 +المثال كم إغلاق متوقع عندي اثنين الآن وين تم + +352 +00:32:24,210 --> 00:32:28,610 +الإغلاق؟ لاحظوا هذا الإغلاق الأول شو .. شو قلنا + +353 +00:32:28,610 --> 00:32:36,790 +عنه؟ اندو الآن في هذا المثال اكزو هي triple bond و + +354 +00:32:36,790 --> 00:32:41,330 +triple bond مرة اندو و مرة اكزو هذه نتيجة التجربة + +355 +00:32:41,330 --> 00:32:45,650 +لكن الإنسان قبل ما يعمل التجربة بيكون عارف الجواب + +356 +00:32:45,650 --> 00:32:51,370 +لأ واضح الفكرة يعني هذا الـ exocyclization عمل حلقة + +357 +00:32:51,370 --> 00:32:55,330 +خماسية لو عملنا اندو cyclization في هذه الحالة + +358 +00:32:55,330 --> 00:33:00,290 +هنعمل حلقة سداسية هنا الـ endocyclization عامل + +359 +00:33:00,290 --> 00:33:05,510 +خماسية لو عملنا exocyclization هنعمل رباعية الآن الـ + +360 +00:33:05,510 --> 00:33:08,510 +cyclization اللي مش موجود بإمكانكوا تتدربوا عليه + +361 +00:33:08,510 --> 00:33:13,550 +بس واضح أنه يعني القمر بسيط لحظو أنا استعمل الـ + +362 +00:33:13,550 --> 00:33:17,890 +base عشان يسحب الـ H اللي هنا و يخليه stronger الـ + +363 +00:33:17,890 --> 00:33:18,730 +nucleophile + +364 +00:33:21,420 --> 00:33:26,340 +هي مثال ثاني لـ triple bond شايفينها وين الـ + +365 +00:33:26,340 --> 00:33:32,720 +nucleophile الـ O الآن كل اللي بلزمني أن أقلم الجزيء + +366 +00:33:32,720 --> 00:33:39,640 +على بعضه الآن هذه الـ O لما بدها تهاجم اندو + +367 +00:33:39,640 --> 00:33:43,640 +أو اكزو أي واحد منهم اللي تم حسب ما أنتم شايفينه + +368 +00:33:43,640 --> 00:33:55,640 +أنا بالنتيجة و لذلك هذه اتحركت صارت CH- وصفية CH2 و + +369 +00:33:55,640 --> 00:34:03,100 +بعد هي عملت توتومريزم لـ CH3 يعني بين هذا الشكل و + +370 +00:34:03,100 --> 00:34:07,800 +هذا الشكل توتومريزم نوع من التوتومريزم واضح؟ شبه + +371 +00:34:07,800 --> 00:34:12,320 +بالكيتو إينول باليمين إينامين توتومريزم واضح؟ + +372 +00:34:12,320 --> 00:34:16,920 +هذا الـ الكين بيصير الكين بموقع ثاني و هذا بيصير + +373 +00:34:16,920 --> 00:34:21,040 +CH3 لكن بكل الأحوال الـ cyclization تم على هذا + +374 +00:34:21,040 --> 00:34:25,940 +الموقع إذا الـ cyclization هنا exocyclization + +375 +00:34:25,940 --> 00:34:30,320 +cyclization هنا exocyclization + +376 +00:34:31,910 --> 00:34:37,090 +هذا المثال نفس الفكرة تمامًا و مرة ثانية برضه + +377 +00:34:37,090 --> 00:34:40,890 +Exocyclization + +378 +00:34:40,890 --> 00:34:51,190 +هبدأ إلى حلقة سداسية لو جمعنا الذرات الآن + +379 +00:34:51,190 --> 00:34:55,910 +في هذا المثال عندي أنا لـ triple bond طب وين الـ + +380 +00:34:55,910 --> 00:35:01,580 +nucleophile اللي عندي؟ عندي هنا C double bond O الـ + +381 +00:35:01,580 --> 00:35:07,140 +O H للـ UQ5 مرة ثانية عندها كم احتمال احتمالين أي + +382 +00:35:07,140 --> 00:35:11,700 +احتمال منهم عملت الـ Exocyclization ممكن تهاجم + +383 +00:35:11,700 --> 00:35:18,020 +على الـ double bond بتعمل حلقة أصغر كلام سليم أنه + +384 +00:35:18,020 --> 00:35:23,580 +ممكن تهاجم هنا و باحتمالين بالضبط + +385 +00:35:24,050 --> 00:35:29,410 +واضح؟ الآن من هدول الأربعة اللي طلع بالتجربة و أدى + +386 +00:35:29,410 --> 00:35:34,170 +إلى حلقة خماسية الـ exocyclization على الـ triple + +387 +00:35:34,170 --> 00:35:40,550 +bond هنا في عنده أجزيم و OH يعني خلينا الـ OH هذه + +388 +00:35:40,550 --> 00:35:46,850 +نرسمها هنا جريب من الـ double bond واضح؟ إيش + +389 +00:35:46,850 --> 00:35:50,090 +الاحتمالات؟ واحد + +390 +00:35:51,610 --> 00:35:55,690 +أو اثنين حسب ما أنتم شايفين وين الـ cyclization تم + +391 +00:35:55,690 --> 00:36:01,750 +إذا إيش نوع الـ cyclization اكزو ولا اندو؟ + +392 +00:36:31,740 --> 00:36:39,410 +اندوسايكليزيات ثلاثية .. رباعية .. رباعية .. + +393 +00:36:39,410 --> 00:36:45,050 +خماسية .. خماسية .. خماسية .. خماسية .. خماسية .. + +394 +00:36:45,050 --> 00:36:51,470 +خماسية .. خماسية .. خماسية .. فمثل هذه الأسئلة لو + +395 +00:36:51,470 --> 00:36:54,810 +كنتوا بتسأله draw all the possible or four + +396 +00:36:54,810 --> 00:36:58,670 +possible cyclization products بده الإنسان خلاص + +397 +00:36:58,670 --> 00:37:03,390 +فاهم الفكرة الفكرة في الـ nucleophile ولا أكثر أكثر + +398 +00:37:03,390 --> 00:37:08,300 +من الـ nucleophile في double bond ولا أكثر أكثر من + +399 +00:37:08,300 --> 00:37:14,440 +double bond طبعًا هو الإنسان لو بده يزيد فلسفة أنه + +400 +00:37:14,440 --> 00:37:19,000 +ممكن يتخيل كمان أن هذه الـ N اللي متصلة بالـ OH is + +401 +00:37:19,000 --> 00:37:24,520 +also الـ UQU5 والله أنا شفتها بتتفاعل و بجيبك paper + +402 +00:37:24,520 --> 00:37:32,460 +عليها بتتفاعل .. بتتفاعل و بعدين بتفقد المية في + +403 +00:37:32,460 --> 00:37:39,260 +مقالات في نفس هذه الـ auxins التفاعل تم على الـ + +404 +00:37:39,260 --> 00:37:44,860 +nitrogen التفاعل تم على الـ nitrogen و ممكن خارج + +405 +00:37:44,860 --> 00:37:48,980 +يعني إطار المحاضرة أن أفرجيكم مثال تم هنا التفاعل + +406 +00:37:48,980 --> 00:37:54,920 +مش هنا ما تنسوش ما تنسوش ولا إشي يعني في كل الأحوال + +407 +00:37:54,920 --> 00:38:01,280 +الـ nucleophile زوج إلكترونات صح؟ إذا لو أنا بدي أجي + +408 +00:38:01,280 --> 00:38:08,320 +أقولكوا نظريًا كم الـ nucleophile عند هنا ثلاثة أنا + +409 +00:38:08,320 --> 00:38:12,860 +هنا عندي ثلاثة واضح؟ و كان ممكن يمكن لو هنا أطول + +410 +00:38:12,860 --> 00:38:17,360 +و بيطلع حلقة خماسية من هذا التفاعل أنه يتم على هذا + +411 +00:38:17,360 --> 00:38:21,320 +الـ nucleophile و في أمثلة في الدنيا في الأكزين + +412 +00:38:21,320 --> 00:38:26,660 +التفاعل بيتم من الـ nitrogen مش من الـ oxygen موجود + +413 +00:38:30,250 --> 00:38:32,730 +طب المثال اللي قبل .. مش هذا اللي قبل .. اللي قبلي + +414 +00:38:32,730 --> 00:38:38,970 +.. الصفحة اللي قبلي .. هذا الآن ممكن تهاجم على الـ + +415 +00:38:38,970 --> 00:38:41,110 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +416 +00:38:41,110 --> 00:38:42,350 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +417 +00:38:42,350 --> 00:38:42,610 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +418 +00:38:42,610 --> 00:38:43,010 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +419 +00:38:43,010 --> 00:38:43,410 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +420 +00:38:43,410 --> 00:38:43,490 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +421 +00:38:43,490 --> 00:38:46,820 +.. ال .. ال .. ال .. ال .. الإن هتهاجم من هنا + +422 +00:38:46,820 --> 00:38:52,960 +مافيش إمكانية هنا في إمكانية نظرية لكن دائما اللي + +423 +00:38:52,960 --> 00:38:56,040 +بتهاجم ال N H ليش؟ هذه لو بدها تهاجم هتعطيك N + +424 +00:38:56,040 --> 00:39:00,160 +positive يعني ال N عشان تكون ال nucleophile اللي + +425 +00:39:00,160 --> 00:39:07,100 +هي ال N H2 mainly و ال N H يعني ربما لو هذه كانت H + +426 +00:39:07,100 --> 00:39:12,380 +بيكون الكلام more logical يعني دائما النيوكليوفايل + +427 +00:39:12,380 --> 00:39:17,400 +أكثر ال NH2 و ال NH ليش لأنه ال neutral + +428 +00:39:17,400 --> 00:39:21,320 +النيوكليوفايل لما بيتفاعل بفقد H فلو كان NH + +429 +00:39:21,320 --> 00:39:25,400 +2 بصفة NH و لو كان NH بصفة NH هيك + +430 +00:39:25,400 --> 00:39:30,840 +اتعودنا احنا عليه لكن أيه كويس إن أنتم تبدأوا + +431 +00:39:30,840 --> 00:39:36,710 +تتفاعلوا مع إيشمعنا الموضوع و مع الاحتمالات هذا + +432 +00:39:36,710 --> 00:39:42,330 +المثال هو تفاعل على ال carbon ال triple bond + +433 +00:39:42,330 --> 00:39:47,930 +carbon مرة ثانية ester مع ال hydroxylamine أنتم + +434 +00:39:47,930 --> 00:39:51,110 +مرة معاكم ال hydroxylamine مع ال ketones و ال + +435 +00:39:51,110 --> 00:39:55,590 +aldehydes اللي بيعطيك oxygen addition لكن ال + +436 +00:39:55,590 --> 00:40:00,550 +hydroxylamine أو ال hydrazine substitute إيش بيعطي + +437 +00:40:00,550 --> 00:40:04,030 +مع ال ester Substitution لأن تفاعل ال ester + +438 +00:40:04,030 --> 00:40:07,390 +الأساسي Substitution بناء على ذلك هذا لما بيعمل + +439 +00:40:07,390 --> 00:40:12,270 +التفاعل التحضيري هذه بدأت هاجم هنا و ترد ال O + +440 +00:40:12,270 --> 00:40:19,830 +ethyl صار عندكم C double bond O NH OH الآن ال OH + +441 +00:40:19,830 --> 00:40:26,450 +عندها احتمالين ال Exo و ال Endo أي واحد اللي تم + +442 +00:40:26,450 --> 00:40:33,040 +هنا ال Endo ساكنزاشي إن هذه جت للداخل و صارت minus و + +443 +00:40:33,040 --> 00:40:38,260 +ما إلى ذلك طيب لو أنا أجيت سألتكم سؤال جبتلكم في + +444 +00:40:38,260 --> 00:40:46,600 +الامتحان هذا المركب و رسمتلكم هنا N او + +445 +00:40:46,600 --> 00:40:50,680 +NH طبعا حلو هيدرازين و قلتلكم ابدولي من هنا + +446 +00:40:50,680 --> 00:40:55,600 +هيدرازين هيدرازين + +447 +00:40:55,600 --> 00:41:01,780 +المحل هذابصير unmatched طبعا بديش answer إنه هذا + +448 +00:41:01,780 --> 00:41:04,340 +الآن اليوكليوفال و هذا اليوكليوفال و عندكم + +449 +00:41:04,340 --> 00:41:10,020 +احتمالات كلها بده تكون داخلة في ذهن و داخلة في + +450 +00:41:10,020 --> 00:41:19,040 +تفكير الإنسان و هو بيشتغل الآن هاجف أنا عشان نأخذ + +451 +00:41:19,040 --> 00:41:24,880 +الأمر بهدوء أكثر عند التفاعل على C triple bond N + +452 +00:41:24,880 --> 00:41:29,540 +هنجف إن التفاعل على C triple bond N إن شاء الله + +453 +00:41:29,540 --> 00:41:33,940 +المرة الجاية بنكمل بكون عنواننا reaction at + +454 +00:41:33,940 --> 00:41:39,640 +nitriles and isonitriles لأن الحقيقة ال nitriles و + +455 +00:41:39,640 --> 00:41:44,940 +ال isonitriles فيهم أمثلة ثرية و مفيدين بشكل clear + +456 +00:41:44,940 --> 00:41:47,120 +في ال heterocyclic synthesis diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/-ViGZbdn3ZM_raw.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/-ViGZbdn3ZM_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..49b5b01bec6d18aa61250bac430c27a7c6412d03 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/-ViGZbdn3ZM_raw.srt @@ -0,0 +1,1840 @@ +1 +00:00:20,770 --> 00:00:26,750 +بسم الله الرحمن الرحيم خلينا نستكمل شيء بسيط في + +2 +00:00:26,750 --> 00:00:31,370 +موضوع الإغلاق على الرابطة الزوجية cyclization of + +3 +00:00:31,370 --> 00:00:35,410 +double bonds وإن شاء الله بيكون يعني معظم دارسنا + +4 +00:00:35,410 --> 00:00:40,110 +اليوم في الإغلاق على الرابطة الثلاثية لكن نستكمل + +5 +00:00:40,110 --> 00:00:46,430 +بعض الأمثلة الآن أخر شغل اتكلمنا عنها اللي هوإنه + +6 +00:00:46,430 --> 00:00:50,930 +يكون ال orthoposition اليوكليوفايل هذا الكلام قلنا + +7 +00:00:50,930 --> 00:00:55,050 +عنه أنه كتير مفيد لأنه بساعدني في تحضير ال fused + +8 +00:00:55,050 --> 00:01:00,370 +rings يعني أول ما الإنسان بده يشوف fused rings + +9 +00:01:00,370 --> 00:01:06,020 +ويقول إيش ال disconnection اللي موجود عندهبدي اقول + +10 +00:01:06,020 --> 00:01:08,720 +ايش ال disconnection اللي موجود عنده يعني لو انا + +11 +00:01:08,720 --> 00:01:13,960 +جبتلكوا في الامتحان هذا المركب الان بدي اذكر انه + +12 +00:01:13,960 --> 00:01:19,180 +جنب ال double bond قلتلكوا اعملوا كثير هنا اعملوا + +13 +00:01:19,180 --> 00:01:30,400 +كثير يعني هذه ايش هتخلوها C double bond O هاي + +14 +00:01:30,400 --> 00:01:35,820 +البنزينةهن انا هنا اعملت الكسر وهن جنب هدى ال + +15 +00:01:35,820 --> 00:01:39,760 +double bond زى ما عملنا بالامثلة السابقة وهد بترجع + +16 +00:01:39,760 --> 00:01:43,360 +ل C double bond ولان لو ال ortho position هجم + +17 +00:01:43,360 --> 00:01:47,740 +هيعمل هن ايش؟ هيعمل هن ال double bond لان بعدك هذا + +18 +00:01:47,740 --> 00:01:54,080 +الجزء ممكن ان اعمله بهدوء من هن على اساس انه + +19 +00:01:54,080 --> 00:02:01,420 +البنزين بجيبله نيترو نيترو بخليه أمينو و هكذابدو + +20 +00:02:01,420 --> 00:02:06,800 +الإنسان بالتأكيد خبرة في هذا الموضوع لكن ال + +21 +00:02:06,800 --> 00:02:10,580 +cyclization على ال orthopositions موضوع كتير مهم + +22 +00:02:10,580 --> 00:02:15,360 +لمنطقة إيش ال synthesis of fused heterocyclic + +23 +00:02:15,360 --> 00:02:21,300 +ringsالان في عند هنا بعض الأمثلة يمكن انا اركز + +24 +00:02:21,300 --> 00:02:25,540 +فيها على خطوة الإغلاق يعني المثال كبير و مثال من + +25 +00:02:25,540 --> 00:02:29,300 +اللي بيشتغلون الناس في ال research لكن انا بهمني + +26 +00:02:29,300 --> 00:02:35,320 +مش كل شغلة يعني في المثال بقدر ما بهمنيلحظة + +27 +00:02:35,320 --> 00:02:39,660 +الإغلاق شو نوع ال cyclization في كيميستر قبله + +28 +00:02:39,660 --> 00:02:44,460 +أحيانا سهل أحيانا صعب شوية يعني لاحظوا هذا المركب + +29 +00:02:44,460 --> 00:02:49,160 +اللي هو pyrimidine derivative مع aniline عمل هنا + +30 +00:02:49,160 --> 00:02:54,670 +إبدال لل CLمع ال نيتروجين صار عنده هذا ال energy + +31 +00:02:54,670 --> 00:02:59,590 +عمل مع ال DMF و الفوسفورالكلوريد هذا تفاعل في ال + +32 +00:02:59,590 --> 00:03:04,710 +name reactions أخدتوا اسمه Vilsmeier-Huck reaction + +33 +00:03:04,710 --> 00:03:09,150 +بحط ال formula group بحط ال formula group حط ال + +34 +00:03:09,150 --> 00:03:13,970 +formula group هذاالان بعد ما أصبح لدي هنا Formally + +35 +00:03:13,970 --> 00:03:19,090 +Group هاي Orthoposition وهاي C Double Bond O ع طول + +36 +00:03:19,090 --> 00:03:23,330 +قولت ال Orthoposition ع C Double Bond O شو بيعمل؟ + +37 +00:03:23,330 --> 00:03:30,650 +OH مع H بيعمل Double Bond غالبا بهذا الموقع ربما + +38 +00:03:30,650 --> 00:03:37,070 +تكون منسية لأن هنا في إمكانية هاي Addition OH H + +39 +00:03:38,210 --> 00:03:45,050 +واضح الفكرة فال cyclization الخلاصة فعلا شغل ortho + +40 +00:03:45,050 --> 00:03:50,580 +position in this exampleوطبعا ممكن نجيب أمثلة + +41 +00:03:50,580 --> 00:03:54,140 +تانية، يعني لاحظوا الباحث عادة اللي بيكون عنده + +42 +00:03:54,140 --> 00:03:58,740 +نقطة انطلاق ينطلق منها بيصير يغير ويعمل مشتقات + +43 +00:03:58,740 --> 00:04:03,120 +كتيرة، يعني نفس المركب السابق بدل مفاعله مع فنل + +44 +00:04:03,120 --> 00:04:09,120 +NH2 إجهان فاعله مع هيدرازين NH2 NH2 بدل ال CL + +45 +00:04:10,440 --> 00:04:15,940 +بنيتروجين N-H N-H2 بعد هيك ايجى فاعله مع 1,2 + +46 +00:04:15,940 --> 00:04:19,060 +-dicarbonyl compounds كلنا عارفين ان ال C double + +47 +00:04:19,060 --> 00:04:27,200 +bond O مع ال N-H2 بيحفه مية C double bond N هيعمل + +48 +00:04:27,200 --> 00:04:32,320 +هنا C double bond N phenyl C double bond O phenyl + +49 +00:04:32,320 --> 00:04:36,200 +الان انا الخطوة بتاعتى اليوم شو هي ال cyclization + +50 +00:04:36,200 --> 00:04:40,100 +على ال orthopositionهي ال cyclization على ال + +51 +00:04:40,100 --> 00:04:43,600 +orthoposition اللي انا بدي دي اقل واضح الفكرة؟ + +52 +00:04:43,600 --> 00:04:47,040 +يعني الفكرة الأساسية اللي عندى اللي هي فكرة ال + +53 +00:04:47,040 --> 00:04:51,220 +cyclization على ال orthoposition بيجيكوا تحفظوا كل + +54 +00:04:51,220 --> 00:04:55,320 +الأمثلة هذه او اتوهوا فيها بقدر ما انكوا تكونوا + +55 +00:04:55,320 --> 00:05:00,430 +ماخدين إيشفكرة عن الموضوع بالتأكيد هيكون في ال + +56 +00:05:00,430 --> 00:05:04,470 +homework اللي هيكون مطلوب منكم ان تجيبولنا اقل اشي + +57 +00:05:04,470 --> 00:05:09,230 +من ال recent research cyclization على + +58 +00:05:09,230 --> 00:05:12,410 +orthoposition يعني مجرد ما تفتحوا مجلة organic و + +59 +00:05:12,410 --> 00:05:16,430 +تشوفوا حلقات بتتحضر هتلاقوا few strings فمرات + +60 +00:05:16,430 --> 00:05:21,710 +كتيرة كيف حضرها كيف خطوة ال cyclization هتلاحظوا + +61 +00:05:21,710 --> 00:05:27,420 +انها cyclization على orthopositionتقريبا كل + +62 +00:05:27,420 --> 00:05:30,800 +الأمثلة اللي مرت علينا لحد الآن كانت اغلاق على c + +63 +00:05:30,800 --> 00:05:35,560 +double bond o الان ال c double bond s و ال c + +64 +00:05:35,560 --> 00:05:39,460 +double bond n بيشبه ال c double bond o لكن ال c + +65 +00:05:39,460 --> 00:05:45,040 +double bond c فيها ايش احتمالين هاي انا عند مثال + +66 +00:05:45,040 --> 00:05:52,610 +على اغلاق على c double bond sلو أخدنا هذا المركب + +67 +00:05:52,610 --> 00:05:57,810 +اللي هو عبارة عن dye alcohol يعني R2C الـC حاملة + +68 +00:05:57,810 --> 00:06:01,390 +OH، بعدين C تانية حاملة OH يعني لو بدي أخده هذا + +69 +00:06:01,390 --> 00:06:08,870 +الجزء هو هذا كان زي هيك على موقع واحد واتنين عنده + +70 +00:06:08,870 --> 00:06:17,050 +OHOOH فعلته مع المركب C double bond SCl2هي ال C + +71 +00:06:17,050 --> 00:06:23,630 +double bond S Cl2 متذكرينه هذا إيش اسمه؟ + +72 +00:06:23,630 --> 00:06:29,710 +متذكرين ابن عمه؟ أه ابن عمه اللي فيه ال oxygen + +73 +00:06:29,710 --> 00:06:35,670 +الفسجين الغاز تبع الحروب السام غاز الفسجين الآن + +74 +00:06:35,670 --> 00:06:44,390 +هذا ثيوفسجين إذا هذا فسجين هذا + +75 +00:06:48,780 --> 00:06:55,000 +الثيوفوسجين والفوسجين هما عبارة عن داي إلكتروفايل + +76 +00:06:55,000 --> 00:07:01,840 +وبالعكس ال الديهايتز والكيتونز بتفاعلوا كداي + +77 +00:07:01,840 --> 00:07:07,210 +إلكتروفايل ولا لأ؟مروا عليكم انه من ال الديهيد و + +78 +00:07:07,210 --> 00:07:14,390 +ال كيتون بمثل داي إلكتروفايل و مثلهم ايش الفسجين + +79 +00:07:14,390 --> 00:07:18,830 +هذا ممكن يشتغل داي إلكتروفايل ال Easter بيشتغل داي + +80 +00:07:18,830 --> 00:07:26,830 +إلكتروفايل ولا لأ ال Easter بهمش خلّينا نتذكر لو + +81 +00:07:26,830 --> 00:07:30,250 +قلنا R اليوكليوفايل زائد + +82 +00:07:35,680 --> 00:07:42,480 +الان هذي الـ C .. هذي الـ C Electrophile + +83 +00:07:42,480 --> 00:07:50,560 +ولا لأ صار عندكم CH3C double bond O اليوكليوفيل R + +84 +00:07:50,560 --> 00:07:56,210 +الان ممكن يجي اليوكليوفيل تاني يهاجمميصارة الديهيد + +85 +00:07:56,210 --> 00:07:59,550 +او كيتون عند النزوم احيانا ممكن ييجي نيوكليوفايل + +86 +00:07:59,550 --> 00:08:04,350 +تاني يهاجم يعمل addition فبيشتغلوا ك die + +87 +00:08:04,350 --> 00:08:07,930 +electrophile الان من ال die electrophiles اللي + +88 +00:08:07,930 --> 00:08:11,950 +مشهورة بدون خلاف اللي مشهورة بدون خلاف الفسجين + +89 +00:08:11,950 --> 00:08:16,810 +والتيوفسجين ليش؟ لأنه ممكن نيوكليوفايل يهاجم يعمل + +90 +00:08:16,810 --> 00:08:21,470 +ابدال اول و نيوكليوفايل تاني يهاجم يعمل ابدال تاني + +91 +00:08:21,470 --> 00:08:26,460 +يعني هذه اسهل ما يمكن اللي هم ايشالفسجين + +92 +00:08:26,460 --> 00:08:33,640 +والثيوفسجين فلما هذا ال nucleophile هاجم طردأول CL + +93 +00:08:33,640 --> 00:08:37,300 +إذا عمل Substitution هنا و لو إجا كمان هذه + +94 +00:08:37,300 --> 00:08:41,440 +الأكسجين و هاجمت ماتحطوا ترد إذا كام Substitution + +95 +00:08:41,440 --> 00:08:44,540 +صار عندى لما اتكونها المركّب Two Successive + +96 +00:08:44,540 --> 00:08:51,900 +Substitutions هو تفاعل على الـ C double bond S لكن + +97 +00:08:51,900 --> 00:08:55,920 +هنا اللى تم عندى addition ولا Substitution Two + +98 +00:08:55,920 --> 00:08:56,520 +Substitutions + +99 +00:08:58,990 --> 00:09:05,210 +هنا في عندنا مثال على تفاعل على carbon double bond + +100 +00:09:05,210 --> 00:09:10,270 +carbon لاحظوا معي في عندى في هذا المثال activated + +101 +00:09:10,270 --> 00:09:15,370 +hydrogen هذه الهيدروجين اللى هنا activated لأنه + +102 +00:09:15,370 --> 00:09:20,070 +جنبها C double bond O وكمان C double bond O وكمان + +103 +00:09:20,070 --> 00:09:24,030 +N يعني هذه هيلو activated يعني بدها base قوى ولا + +104 +00:09:24,030 --> 00:09:31,200 +ضعيفباس ضعيف الآن شيلنا الهيدروجين شو عملنا عملنا + +105 +00:09:31,200 --> 00:09:35,980 +سالب هتبدأ السالب إذا تروح على ال carbon double + +106 +00:09:35,980 --> 00:09:41,060 +bond carbon الأصل الآن كام cyclization ممكن عندك + +107 +00:09:41,060 --> 00:09:48,520 +اتنين إذا فعلنا بهذا الشكل وهذه تحركت للخارج بحيث + +108 +00:09:48,520 --> 00:09:53,910 +تصير هنا C minus و بعدين CHلحظوا بعد ما تصير minus + +109 +00:09:53,910 --> 00:09:59,450 +شو هتحط هنا H هذا ال cyclization اللي انتوا + +110 +00:09:59,450 --> 00:10:04,330 +شايفينه اكزو ولا اندو اكزو اذا هي ال cyclization + +111 +00:10:04,330 --> 00:10:09,330 +الأخضر هذا اكزو cyclization بيقدر تكون الحلقة + +112 +00:10:09,330 --> 00:10:15,510 +الرباعية طيب الان نعمل ال cyclization الأحمر لو + +113 +00:10:15,510 --> 00:10:22,230 +هذا الهجوم تم هناو هذي إيجد هنا و هتصير CH شو + +114 +00:10:22,230 --> 00:10:28,070 +حيصير عندى حلقة خمسية بهذا الشكل N C double bond O + +115 +00:10:28,070 --> 00:10:34,050 +C و أنا C و هذي C بهذا الشكل واضح و هنا هيكون + +116 +00:10:34,050 --> 00:10:43,730 +عندكم CO2 إثل و هنا CO2 إثل و CO2 إثل هذا ال + +117 +00:10:43,730 --> 00:10:49,500 +cycleization تم علىأى ذرة على هذه هى كأحنا عاملين + +118 +00:10:49,500 --> 00:10:53,780 +صح ولا .. الـCO2 إيثل شبه الـNitrogen هان الـCO2 + +119 +00:10:53,780 --> 00:11:01,080 +إيثل لحظة هى الـNitrogen هذى الـCarbon اللى هاجمت + +120 +00:11:01,080 --> 00:11:11,040 +هى التلاتة CO2 إيثل بمعنى + +121 +00:11:11,040 --> 00:11:19,880 +انه كانت ال double bond اللى عندىبهذا الشكل هاي C + +122 +00:11:19,880 --> 00:11:25,400 +double bond O C C double bond C فلما تم ال + +123 +00:11:25,400 --> 00:11:33,460 +cyclization بهذا الشكل هذه وين هتيجي minus Hواضح + +124 +00:11:33,460 --> 00:11:38,240 +هيصير عندى endocyclization و الحلقة اللى بتتكون + +125 +00:11:38,240 --> 00:11:43,380 +خمسية اذا مثل هذا المثال لو اجانا فى امتحان و كنا + +126 +00:11:43,380 --> 00:11:49,260 +بنجاوبه كام احتمال عندى احتمالين ال exocyclization + +127 +00:11:49,260 --> 00:11:54,380 +و ال endocyclization لازم انتوا بيداكوا تتدربوا + +128 +00:11:54,380 --> 00:11:58,980 +على هدوله ربما + +129 +00:11:58,980 --> 00:12:03,640 +انه هذا الكربونيل اللى جنب الان امدهذه مشكلة فيها + +130 +00:12:03,640 --> 00:12:08,660 +والمشكلة التانية انها تعمل حلقة ثلاثية يعني من + +131 +00:12:08,660 --> 00:12:16,930 +ناحية النظرية البحثة في ذرة احتمال لكن لما نيجيأمد + +132 +00:12:16,930 --> 00:12:22,510 +و ثلاثية فيها مشكلتين طبعا الكل هيجي يقول أنه أنا + +133 +00:12:22,510 --> 00:12:25,650 +أفضل في الحلقات الخماسية ولا الرباعية الخماسية .. + +134 +00:12:25,650 --> 00:12:26,970 +الخماسية .. الخماسية .. الخماسية .. الخماسية .. + +135 +00:12:26,970 --> 00:12:27,590 +الخماسية .. الخماسية .. الخماسية .. الخماسية .. + +136 +00:12:27,590 --> 00:12:28,050 +الخماسية .. الخماسية .. الخماسية .. الخماسية .. + +137 +00:12:28,050 --> 00:12:29,190 +الخماسية .. الخماسية .. الخماسية .. الخماسية .. + +138 +00:12:29,190 --> 00:12:33,810 +الخماسية .. الخماسية .. الخماسية .. الخماسية .. + +139 +00:12:33,810 --> 00:12:37,850 +الخماسية .. الخماسية .. الخماسية .. الخماسية .. + +140 +00:12:37,850 --> 00:12:41,090 +الخماسية .. الخماسية .. الخماسية .. الخماسية .. + +141 +00:12:41,090 --> 00:12:43,190 +الخماسية .. الخماسية .. الخماسية .. الخماسية .. + +142 +00:12:43,190 --> 00:12:45,090 +الخماسية .. الخماسية .. الخماولذلك مرات بيستعملوا + +143 +00:12:45,090 --> 00:12:48,570 +مصطلح بفترض انه مار عليكم بال physical chemistry + +144 +00:12:48,570 --> 00:12:53,270 +بيقولوا في عندى اشي اسمه kinetic product وفي اشي + +145 +00:12:53,270 --> 00:12:57,230 +اسمه thermodynamic product الان لو انا بدي اصنف + +146 +00:12:57,230 --> 00:13:02,070 +هذه الخماسية بدي اقول عنها اش thermodynamic + +147 +00:13:02,070 --> 00:13:07,130 +product يعني هذا it seems more stable هذا ال + +148 +00:13:07,130 --> 00:13:12,090 +product more stableThermodynamic product الخماسي + +149 +00:13:12,090 --> 00:13:17,530 +أثبت من رباعي لكن ربما لما تم الإغلاق وهذه ال + +150 +00:13:17,530 --> 00:13:23,750 +minus بدأت تتفاعل بسرعة من الأقرب لهاهذا الطرف ولا + +151 +00:13:23,750 --> 00:13:27,870 +هذا؟ فوجدت هذا الطرف فهذا ال product اللي اتكون + +152 +00:13:27,870 --> 00:13:32,430 +ايش هو بيكون ال kinetic product مرات كتير الناس + +153 +00:13:32,430 --> 00:13:35,550 +اللي بدرسوا هذا الموضوع بيعرفوا انه بتكون kinetic + +154 +00:13:35,550 --> 00:13:39,830 +product بتكون بفصلوه بسيبوه بعد فترة بالذات لو + +155 +00:13:39,830 --> 00:13:44,470 +تركوه بالمحلول بيلاقوه بيعود بفكو بتحول الى + +156 +00:13:44,470 --> 00:13:49,010 +thermodynamic product واضح؟ لكن اللى موجود عندنا + +157 +00:13:49,010 --> 00:13:52,110 +احنا فى هذا المثال ال kinetic product ولا ال + +158 +00:13:52,110 --> 00:13:54,950 +thermodynamic product ال kinetic product ليس ال + +159 +00:13:54,950 --> 00:14:00,690 +stable product لكن غالبا انه بتكون بشكل أسرع غالبا + +160 +00:14:00,690 --> 00:14:10,250 +انه بتكون بشكل أسرع هنا + +161 +00:14:10,250 --> 00:14:17,210 +فى عندىمثال تاني على عملية cyclization at carbon + +162 +00:14:17,210 --> 00:14:21,810 +-carbon double bond و المرة هذه لل nucleophile + +163 +00:14:21,810 --> 00:14:25,930 +اللي موجود عنده هو ال sulfur ال nucleophile هنا + +164 +00:14:25,930 --> 00:14:29,710 +بدي انا بحكي لشغله ال C double bond S ال sulfur + +165 +00:14:29,710 --> 00:14:34,250 +كتير بحب يشتغل ك nucleophile عشانك مرات كتيرة و + +166 +00:14:34,250 --> 00:14:38,090 +انتوا بتشتغلوا على C double bond S بتلاقوها بتهاجم + +167 +00:14:38,090 --> 00:14:42,290 +من عند إيش؟السلفر .. انتوا لو اتطلعتوا على هذا + +168 +00:14:42,290 --> 00:14:46,790 +التفاعل .. الاحظوا هذا التفاعل كيف عملوه .. فعلوه + +169 +00:14:46,790 --> 00:14:51,150 +في وجود لبروم ..الان لبروم متذاكرين انتوا على ال + +170 +00:14:51,150 --> 00:14:56,360 +double bondكان يضيف في الأول إبروم بلس يعمل + +171 +00:14:56,360 --> 00:15:02,020 +إبرومونيوم أيون بذات لما أخدنا تفاعل اللي هو + +172 +00:15:02,020 --> 00:15:05,040 +addition of إبروم to double bond subromination + +173 +00:15:05,040 --> 00:15:10,720 +الناس اللي متذكرين ال carbon double bond carbon مع + +174 +00:15:10,720 --> 00:15:16,180 +ال PR2 كنا نقول أن التفاعل بيبدأ بإضافة لإبروم و + +175 +00:15:16,180 --> 00:15:22,060 +بيعمل إبرومونيوم أيون الآن بتضطر لإبروم التانية + +176 +00:15:22,060 --> 00:15:29,910 +تيجي من وينمن العكسالـ PR الـ minus وعشان هيك اللي + +177 +00:15:29,910 --> 00:15:32,970 +هو ال addition of bromine to double bonds ايش كنا + +178 +00:15:32,970 --> 00:15:36,810 +نقول عنه سن + +179 +00:15:36,810 --> 00:15:41,010 +ولا انتي اديشن انتي اديشن لما كنا ناخد الهيدروجين + +180 +00:15:41,010 --> 00:15:46,490 +في وجود متل نقول سن اديشن هنا نقول انتي اديشن + +181 +00:15:46,490 --> 00:15:52,070 +الخلاصة ان اضافة البروميل موجب بيخلي هذه الكربون + +182 +00:15:52,070 --> 00:15:58,420 +بالإمكان انه يجي يهاجم عليها ايشبر نيجاتيف يعني + +183 +00:15:58,420 --> 00:16:03,700 +هنا في عندى بير كاربون لو اجى في حالة البروميناشن + +184 +00:16:03,700 --> 00:16:08,000 +هيجى بير نيجاتيف في حالة زى هذه الحالة انا استعانت + +185 +00:16:08,000 --> 00:16:12,500 +فى البرومين واتفعل هنا شو اللى نيكليوفال اللى عندى + +186 +00:16:12,500 --> 00:16:18,960 +سالفرواضح؟ Sulphur مش PR يعني كأنه صار عندى الهجوم + +187 +00:16:18,960 --> 00:16:25,160 +ل Sulphur و PR و مبينين أنتى ولا لأ؟ يعني أصلا هذى + +188 +00:16:25,160 --> 00:16:29,500 +اللى كانت double bond ملاحظين؟ + +189 +00:16:29,500 --> 00:16:34,140 +هذى اللى كانت أصلا double bond لما ضف عليها لبرومو + +190 +00:16:34,140 --> 00:16:38,720 +.. لبرومو عمل برومونيوم ايون سكرت بإيش؟ بال + +191 +00:16:38,720 --> 00:16:42,600 +Sulphur مثل هذه الأمثلة متذكرين أنه أخدتوا زيها + +192 +00:16:42,600 --> 00:16:48,100 +أنتوا بالظبط؟لما كنا ناخد ال double bond و نقولكوا + +193 +00:16:48,100 --> 00:16:59,520 +مع PR2 في وجود مثلا CL minus تبدأوا التفاعل ب A و + +194 +00:16:59,520 --> 00:17:12,050 +تكملوا ب R ب CL او لو كان عندكوا مية تكملوه ب O Hو + +195 +00:17:12,050 --> 00:17:19,090 +صار عندكم اللي هي ال halohedrons اللي هي المركبات + +196 +00:17:19,090 --> 00:17:25,120 +اللي فيها halogens و OHsكل هذا الكلام ارجو انكم + +197 +00:17:25,120 --> 00:17:28,380 +ترجعوه يعني كتير بنحتاج كيميا نرجعها من السابق + +198 +00:17:28,380 --> 00:17:32,700 +اللي هو التفاعل على ال double bonds تفاعل + +199 +00:17:32,700 --> 00:17:36,240 +البروميناشن تفاعل ال hydrogenation تفاعل + +200 +00:17:36,240 --> 00:17:40,120 +البروميناشن في وجود ايون سالب يبدأ التفاعل + +201 +00:17:40,120 --> 00:17:44,600 +بالبروميناشن و يكمل بالايون السالب وهذا مثال عليه + +202 +00:17:44,600 --> 00:17:51,460 +تمام؟ الان ربما جزء من اللي بيساعدالتفاعل هنا و + +203 +00:17:51,460 --> 00:17:56,440 +بشجع ال sulfur اكتر انه يعمل ك ال nucleophile ال + +204 +00:17:56,440 --> 00:17:59,840 +nitrogen اللي قريبه يعني زوج الإلكترونات زوج + +205 +00:17:59,840 --> 00:18:03,540 +الإلكترونات اللي موجود هنا بإمكاننا احنا نتخيل انه + +206 +00:18:03,540 --> 00:18:07,320 +تتحرك بهذا الشكل خلا زوج الإلكترونات اللي هنا وين + +207 +00:18:07,320 --> 00:18:11,280 +يتحرك هم لاحظين هذه زوج الإلكترونات اتحرك هنا + +208 +00:18:11,280 --> 00:18:15,140 +معقول يصيروا خمس روابط لأ اذا هذا بده يجي يتحرك + +209 +00:18:15,140 --> 00:18:22,580 +هنا ال PRأخذت زوج الإلكترونات رجعت ل PR عادية و + +210 +00:18:22,580 --> 00:18:27,440 +بتم التفاعل طبعا هنا صار عندهم positive nitrogen + +211 +00:18:27,440 --> 00:18:32,360 +لما تم التحرك هنا في وجود الماء التفاعل كله ال C + +212 +00:18:32,360 --> 00:18:36,200 +double bond ان مشهور جدا انه في وجود الميه بتتحول + +213 +00:18:36,200 --> 00:18:40,240 +ل إيش ل C double bond O بصير ال hydrolysis مار + +214 +00:18:40,240 --> 00:18:47,100 +عليكم hydrolysis of امينE means هنا نوع من ال E + +215 +00:18:47,100 --> 00:18:53,580 +means ال C double bond N بالمية بسهولة بتحول إلى C + +216 +00:18:53,580 --> 00:18:57,600 +double bond O كل هذا الكلام تم في هذا المثال انا + +217 +00:18:57,600 --> 00:19:01,120 +بالنسبة لي المهم ان انا عملت addition على + +218 +00:19:03,700 --> 00:19:07,480 +الـ Double bond أنا عملت تفاعل على الـ Double bond + +219 +00:19:07,480 --> 00:19:10,940 +الان انتبهوا معي ان الـ Double bond حتى بمساعدة + +220 +00:19:10,940 --> 00:19:15,940 +لبروميل كام احتمال عندى فيها للـ cyclization اتنين + +221 +00:19:15,940 --> 00:19:21,760 +اتنين مش واحد يعني لما انا فعلت على هذا الطرف + +222 +00:19:21,760 --> 00:19:26,440 +بيجيني الاحتمال التانى ما المانع ان افعل على هذا + +223 +00:19:26,440 --> 00:19:30,500 +الطرف و لو هذا الكلام بده يتم شو بده يكون الناتج + +224 +00:19:30,500 --> 00:19:37,970 +اللى عندىحلقة سداسية فيها السلفر هنا والكربون + +225 +00:19:37,970 --> 00:19:42,150 +والبرومين هنا يعني + +226 +00:19:42,150 --> 00:19:45,590 +لو جيبنالكم هذا وقلنا لكم بدنا ال possible + +227 +00:19:45,590 --> 00:19:49,210 +cyclization product ال possible cyclization + +228 +00:19:49,210 --> 00:19:53,310 +product الحقيقة أن السلفر يهاجم على هذا الكربون أو + +229 +00:19:53,310 --> 00:19:56,490 +على هذا الكربون على هذا الكربون عندكم الحلقة + +230 +00:19:56,490 --> 00:20:01,550 +الخماسية على هذا الكربون عندكم الحلقات السداسية + +231 +00:20:02,270 --> 00:20:06,830 +عليكم الحلقة السوداسية والبرومين هنا كان عامل + +232 +00:20:06,830 --> 00:20:12,690 +مساعد في عملية ايش؟ في عملية التفاعل على ال double + +233 +00:20:12,690 --> 00:20:16,890 +bond بطريقة سبق اننا اتعلمناها ان البرومين في + +234 +00:20:16,890 --> 00:20:20,430 +الأول بيضيف كبرومين موجب وبعدين ال nucleophile + +235 +00:20:20,430 --> 00:20:28,490 +بيكمل التفاعل هذا الكلام بأمل انكم ايش؟ اترجعوا في + +236 +00:20:28,490 --> 00:20:33,010 +المنطقة انا متأكد انشرحته لكوا في ال organic a + +237 +00:20:33,010 --> 00:20:41,130 +بتذكر الان تقريبا بنفس الفكرة هنا بيجينا امثلة + +238 +00:20:41,130 --> 00:20:46,190 +تانية هنا بيجينا امثلة تانية و لاحظوا ان اللي + +239 +00:20:46,190 --> 00:20:49,690 +بيساعد على ال cyclization على ال double bond يعني + +240 +00:20:49,690 --> 00:20:54,750 +هذه carbon carbon double bond ال nitrogen عبارة عن + +241 +00:20:54,750 --> 00:20:58,570 +ال nucleophile الان صار واضح اندي ان في عندي + +242 +00:20:58,570 --> 00:21:03,970 +nucleophileو في عنده double bond الان هذا ال + +243 +00:21:03,970 --> 00:21:09,490 +nucleophile وين ممكن يهاجم؟ اما على هذا المكان + +244 +00:21:09,490 --> 00:21:15,430 +وبالتالي exocyclization لو هاجم هنا وين هتيجي هذه؟ + +245 +00:21:15,430 --> 00:21:23,230 +هيصير عنده CH minus مظبوط ولا لا؟ الان هذه في وجود + +246 +00:21:23,230 --> 00:21:28,590 +mercury chloride ال minus بتتحد مع ال mercury + +247 +00:21:28,590 --> 00:21:33,990 +chloride بدل الذئبقلاحظوا بيصير هذا عامل إيش؟ + +248 +00:21:33,990 --> 00:21:40,470 +مساعد لأنه أول ما هذه بدأت تتفعل هنا هذه CH2 بدأت + +249 +00:21:40,470 --> 00:21:47,190 +تصير CH2 minus الآن ال minus بيهاجم هنا بطرد بطرد + +250 +00:21:47,190 --> 00:21:51,030 +X واحدة من التنتين و بيعملها دولة بعدين في ظروف + +251 +00:21:51,030 --> 00:21:56,370 +التفاعل لو ضفنا ميه أو إشي برجع مكان هذه إيش يتكون + +252 +00:21:56,370 --> 00:22:02,920 +عنده؟سي أتش ثري فهذه إجت عندى كعامل مساعد لو + +253 +00:22:02,920 --> 00:22:06,480 +اتخيلت انها مش موجودة مش كنتوا هتكملوا التفاعل + +254 +00:22:06,480 --> 00:22:11,620 +بالشكل القاتل ان هذه هاجمت هذه صارت CH2- و بعدين + +255 +00:22:11,620 --> 00:22:19,180 +أخدت إيشH plus واضح لكن التفاعل في وجود الـ HGX2 + +256 +00:22:19,180 --> 00:22:24,660 +بتم بشكل أفضل لكن كنتيجة لما يصير عند ال + +257 +00:22:24,660 --> 00:22:29,880 +Exocyclization هذا ال CH2 شو بده تصير CH3 الآن هذا + +258 +00:22:29,880 --> 00:22:34,840 +أحد الاحتمالات في عند احتمال تاني ولا لأ اه + +259 +00:22:34,840 --> 00:22:38,780 +الاحتمال التاني اللي خلينا نوضحه بالأحمر ان هذه + +260 +00:22:38,780 --> 00:22:49,950 +تهاجمها وجدهاهذه كأنها صارت CH- هي أصلا CH و أخدت + +261 +00:22:49,950 --> 00:22:55,290 +minus بتصير CH- الآن في المحصلة هتاخد H مرورا + +262 +00:22:57,260 --> 00:23:02,020 +بالاستعانة بالزئبق مرورا بالاستعانة بالزئبق إذا + +263 +00:23:02,020 --> 00:23:05,220 +هنا لو قلنا draw the possible cyclization of + +264 +00:23:05,220 --> 00:23:10,140 +products برضه المرسوم واحد منهم اللي هو ال exo ولا + +265 +00:23:10,140 --> 00:23:14,600 +ال endocyclization ال exo الآن ال endو اتدربوا + +266 +00:23:14,600 --> 00:23:19,820 +عليه اللي موجود زي ذلك هذا المثال تقريبا شبيه جدا + +267 +00:23:19,820 --> 00:23:23,920 +فيه عندني نيتروجين وضب ال bond إذا الهجوم تم بهذا + +268 +00:23:23,920 --> 00:23:28,730 +الشكلهذا اللي موجود عنده ال Exo اللي هو طلع + +269 +00:23:28,730 --> 00:23:35,430 +النتيجة و الحلقة المتكونة سداسية طيب لو تم الهجوم + +270 +00:23:35,430 --> 00:23:40,030 +بهذا الشكل شوفنا هذا ال Exo طب لو تم الهجوم بهذا + +271 +00:23:40,030 --> 00:23:40,610 +الشكل + +272 +00:23:43,150 --> 00:23:48,530 +حلقة سباعية و Endocyclization بدكوا تتدربوا انكوا + +273 +00:23:48,530 --> 00:23:53,650 +ترسموها ليش؟ لأنه احنا بهمنا و كثير بنسألكم انه ا + +274 +00:23:53,650 --> 00:23:57,390 +draw all the possible cyclization products فانا + +275 +00:23:57,390 --> 00:24:01,430 +لما بحكي عن carbon double bond carbon بدكوا تعودوا + +276 +00:24:01,430 --> 00:24:06,110 +أنفسكم انكوا ترسموه الناتجين اللي على طرفين الرابط + +277 +00:24:06,110 --> 00:24:12,080 +الزوجية بعد هيكبتروحوا بتعملوا التجربة بتفصلوا + +278 +00:24:12,080 --> 00:24:16,380 +ناتج هالناتج بيستعمل طرق التشخيص هو هذا ولا هذا + +279 +00:24:16,380 --> 00:24:21,660 +بتهيأل طرق التشخيص سهل ان انا اتواضحلكم الجواب + +280 +00:24:21,660 --> 00:24:25,420 +يعني اذا بدنا نطلع شوية من ال heterocycle ال + +281 +00:24:25,420 --> 00:24:28,680 +chemistry للتشخيص لو فكرنا هنا ان احنا عاملين + +282 +00:24:28,680 --> 00:24:33,880 +الحلقة السباعية هيكون + +283 +00:24:33,880 --> 00:24:38,540 +عندكم هنا unatched وهنا واحد اتنين تلات اربع خمس + +284 +00:24:38,540 --> 00:24:45,470 +ساعةزيك الناتج carbon تنتين تلاتة carbon تنتين + +285 +00:24:45,470 --> 00:24:49,930 +تلاتة مش ال cyclization تمهان كام carbon صاروا + +286 +00:24:49,930 --> 00:24:55,650 +هدولة اللي بين الان و ال او تلاتة لو ال + +287 +00:24:55,650 --> 00:24:58,970 +cyclization تمهان كام carbon تنتين تنتين اللي هم + +288 +00:24:58,970 --> 00:25:03,410 +هدولة الان الناتج المتوقع اما هذا الناتج او هداك + +289 +00:25:03,410 --> 00:25:11,410 +ناتج المفروض ان انتوا تشتغلوا ترسمواالناتجين بعدين + +290 +00:25:11,410 --> 00:25:16,470 +بتفصلوا هالمركب اللي طلع عندكم بتروحوا بتعملوله + +291 +00:25:16,470 --> 00:25:23,350 +spectroscopic analysis IR و NMR و Carbon 13 و ما + +292 +00:25:23,350 --> 00:25:27,010 +إلى ذلك و حسب النواتج بتقولوا اه اللي طلع عندي هذا + +293 +00:25:27,010 --> 00:25:30,470 +و هذا شو أسهل طريقة في التشخيص تتميز الاتنين هدول + +294 +00:25:30,470 --> 00:25:36,850 +عن بعض هدى NR ولا .. NR مش موضوع خلافه شو أسهل + +295 +00:25:36,850 --> 00:25:42,110 +طريقة في التشخيص تتميز هدولإيش اللي بده يبين ليه + +296 +00:25:42,110 --> 00:25:50,750 +إيش الإشارة الأكتر وضوحا CH3 هذاك في CH3 على طول + +297 +00:25:50,750 --> 00:25:57,990 +حتى يمكن بجهاز ال IR حتى يمكن بجهاز ال IR عند 1380 + +298 +00:25:57,990 --> 00:26:01,450 +لا + +299 +00:26:01,450 --> 00:26:01,810 +لا + +300 +00:26:05,720 --> 00:26:13,460 +CH3 CH3 ال ISO في هذه المنطقة يتبين زي هي CH3 + +301 +00:26:13,460 --> 00:26:18,560 +عادية طبعا الأسهل كتير في ال proton NMR يعني بين + +302 +00:26:18,560 --> 00:26:22,300 +هذا المركب اللي محناه و بين هذا في ال proton NMR + +303 +00:26:22,300 --> 00:26:27,640 +ان اشوف CH3 ولا اشوف تلاتة CH2 في ال carbon 13 NMR + +304 +00:26:27,640 --> 00:26:33,850 +يعني التشخيص ليس عمليةصعبة مش موضوعنا الان لكن + +305 +00:26:33,850 --> 00:26:38,670 +احنا موضوعنا انه دائما و ابدا بدنا نفكر لما بنحكي + +306 +00:26:38,670 --> 00:26:45,050 +عن اغلاق على ال double bond بكم ناتج ال carbon + +307 +00:26:45,050 --> 00:26:49,670 +carbon double bond بناتجين و بتكون تعودوا إيديكوا + +308 +00:26:49,670 --> 00:26:56,370 +انكوا ترسموا الناتجين بهك تقريبا بنكون انتهينا من + +309 +00:26:58,040 --> 00:27:12,840 +هذا الجزء المتعلق بالاغلاق على ال double bond الان + +310 +00:27:12,840 --> 00:27:19,500 +لو انتقلنا لدرسنا اليوم اللي هو الاغلاق على ال + +311 +00:27:19,500 --> 00:27:25,750 +triple bondأسهل شيء الإنسان يقوله أنه يتذكر قول + +312 +00:27:25,750 --> 00:27:30,390 +الشاعر اللي بيقول ما ترانا نقوله إلا معادا من + +313 +00:27:30,390 --> 00:27:33,850 +قولنا مكرورة يعني أنا ممكن أدعي أنه مش هنجيب + +314 +00:27:33,850 --> 00:27:39,450 +تقريبا إشي جديد في الموضوع والدليل ع هيك أنه بدنا + +315 +00:27:39,450 --> 00:27:44,920 +نبدأ بهذه اللوحة لمرة معناهاونقول انه في الـ + +316 +00:27:44,920 --> 00:27:48,080 +cyclization على ال triple bond عنده احتمالين + +317 +00:27:48,080 --> 00:27:53,480 +exocyclization و endocyclization الان لل triple + +318 +00:27:53,480 --> 00:28:01,280 +bonds المشهورة في الدنيا شو هي؟ عنده C triple bond + +319 +00:28:01,280 --> 00:28:08,840 +N R C triple bond N واضح؟نشوف على أرض الواقع شو + +320 +00:28:08,840 --> 00:28:14,580 +اللي بي .. R C triple bond N وعندي R N triple bond + +321 +00:28:14,580 --> 00:28:20,900 +C وعندي R C triple bond C هدول التلاتة المشهورين + +322 +00:28:20,900 --> 00:28:24,960 +في الدنيا هدول اللي هناخد عليهم أنثى لك الآن وين + +323 +00:28:24,960 --> 00:28:31,080 +بيتم الإغلاق؟ على الأحمر وين الأحمر؟ + +324 +00:28:39,960 --> 00:28:44,420 +واضح؟ أصل طريقة نفهم من قبل لما يكون عنده نيترالز + +325 +00:28:44,420 --> 00:28:49,100 +الهجوم على هذا الكربون لما يكون عنده ايزو نيترالز + +326 +00:28:49,100 --> 00:28:52,580 +او ايزو سيا نايتز الهجوم على هذا الكربون يعني هنا + +327 +00:28:52,580 --> 00:28:57,520 +دائما اكزو هنا دائما اندو هنا اندلال + +328 +00:28:59,980 --> 00:29:04,040 +واضح؟ اللي فاهم هالكلام و بده تطلع اليوم تعبت + +329 +00:29:04,040 --> 00:29:08,360 +بإمكانه تطلعه كل اللي هنشرحه أمثلة تطبيقية على + +330 +00:29:08,360 --> 00:29:13,700 +هدول التلات نقاط إنه ناخد C triple bond C مرة هن و + +331 +00:29:13,700 --> 00:29:18,980 +مرة هن C triple bond N دائما هن N triple bond C + +332 +00:29:18,980 --> 00:29:27,890 +دائما هن واضح؟ يعني بهيك احنا بنكون خلصنامحاضرة + +333 +00:29:27,890 --> 00:29:39,950 +اليوم كفكرة و كل اللي بيضل عندنا أمثلة أمثلة + +334 +00:29:39,950 --> 00:29:46,250 +على الموضوع، الآن في الأمثلة على الموضوع الكمبيوتر + +335 +00:29:46,250 --> 00:29:48,330 +اتمرد شوية + +336 +00:29:53,590 --> 00:29:57,670 +لا بس ماحلوش يتمرضى بنقطع .. بنقطع التسجيل + +337 +00:29:57,670 --> 00:30:07,670 +تدقيقتين المفروض + +338 +00:30:07,670 --> 00:30:15,990 +انا نسخة ال file الجديد اللى فيه خمستاشر slide هذا + +339 +00:30:15,990 --> 00:30:18,270 +نسخ + +340 +00:30:29,950 --> 00:30:31,350 +وانتي؟ + +341 +00:30:57,010 --> 00:30:59,050 +فاير وبرايا دي كانت كلها كده + +342 +00:31:33,910 --> 00:31:40,050 +بنستمر وقولنا احنا كل اللى هنشوفه هو امثلة على + +343 +00:31:40,050 --> 00:31:44,930 +الإغلاق على نيترالز و ايزو نيترالز و carbon-carbon + +344 +00:31:44,930 --> 00:31:49,470 +triple bonds خلّينا نشوف الأمثلة بسرعة في هذا + +345 +00:31:49,470 --> 00:31:55,070 +المثال بتوقع ان يتكون عدة ناتج ولا ناتجين ناتجين + +346 +00:31:55,070 --> 00:31:59,410 +الإغلاق على هذا الموقع وعلى هذا الموقع واضح طبعا + +347 +00:31:59,410 --> 00:32:04,690 +اى إغلاق اللى مبين انه تمبالتجربة واحد هذه لما + +348 +00:32:04,690 --> 00:32:08,530 +بتيجي هنا ال C minus بتاخد H مبينة موجودة عندكم + +349 +00:32:08,530 --> 00:32:13,650 +يعني ال C triple bond C بيبدأ تسير C double bond C + +350 +00:32:13,650 --> 00:32:18,430 +لأن التحول كانت رابطة من التلاتة كذلك الحال في هذا + +351 +00:32:18,430 --> 00:32:24,210 +المثال كم إغلاق متوقع عندي اتنين الآن وين تم + +352 +00:32:24,210 --> 00:32:28,610 +الإغلاق؟ لاحظوا هذا الإغلاق الأول شو .. شو قولنا + +353 +00:32:28,610 --> 00:32:36,790 +عنه؟اندو الان في هذا المثال اكزو هي triple bond و + +354 +00:32:36,790 --> 00:32:41,330 +triple bond مرة اندو و مرة اكزو هذه نتيجة التجربة + +355 +00:32:41,330 --> 00:32:45,650 +لكن الإنسان قبل ما يعمل التجربة بيكون عارف الجواب + +356 +00:32:45,650 --> 00:32:51,370 +لأ واضح الفكرة يعني هذا ال exocyclization عمل حلقة + +357 +00:32:51,370 --> 00:32:55,330 +خماسية لو عملنا اندوcyclization في هذه الحالة + +358 +00:32:55,330 --> 00:33:00,290 +هنعمل حلقةسوداسية هنا ال endocyclization عامل + +359 +00:33:00,290 --> 00:33:05,510 +خمسية لو عملنا exocyclization هنعمل رباعية الآن ال + +360 +00:33:05,510 --> 00:33:08,510 +cyclization اللي مش موجود بإمكانكوا تتدربوا عليه + +361 +00:33:08,510 --> 00:33:13,550 +بس واضح انه يعني القمر بسيط لحظو انا استعمل ال + +362 +00:33:13,550 --> 00:33:17,890 +base عشان يسحب ال H اللي هنا و يخليه stronger ال + +363 +00:33:17,890 --> 00:33:18,730 +eucleophile + +364 +00:33:21,420 --> 00:33:26,340 +هي مثال تاني لـ triple bond شايفينها وين الـ + +365 +00:33:26,340 --> 00:33:32,720 +nucleophile الـ O الان كل اللي بلزمني انقلم الجزيق + +366 +00:33:32,720 --> 00:33:39,640 +على بعضه الان هذه الـ O لما بدها تهاجم اندو + +367 +00:33:39,640 --> 00:33:43,640 +او اكزو اي واحد منهم اللي تم حسب ما انتوا شايفينه + +368 +00:33:43,640 --> 00:33:55,640 +انا بالنتيجة و لذلك هذه اتحركتصارت CH- وصفية CH2 و + +369 +00:33:55,640 --> 00:34:03,100 +بعد هي عملت توتماريزم ل CH3يعني بين هذا الشكل و + +370 +00:34:03,100 --> 00:34:07,800 +هذا الشكل توتوماريزم نوع من التوتوماريزم واضح؟ شبه + +371 +00:34:07,800 --> 00:34:12,320 +بالكيتو إي نولو باليمين إي نامين توتوماريزم واضح؟ + +372 +00:34:12,320 --> 00:34:16,920 +هذا ال الكين بيصير الكين بموقع تاني و هذا بيصير + +373 +00:34:16,920 --> 00:34:21,040 +CH3 لكن بكل الأحوال ال cyclization تم على هذا + +374 +00:34:21,040 --> 00:34:25,940 +الموقع إذا ال cyclization هنا exocyclization + +375 +00:34:25,940 --> 00:34:30,320 +cyclization هنا exocyclization + +376 +00:34:31,910 --> 00:34:37,090 +هذا المثال نفس الفكرة تماما و مرة تانية برضه + +377 +00:34:37,090 --> 00:34:40,890 +Exocytalization + +378 +00:34:40,890 --> 00:34:51,190 +هبدأ إلى حلقة سداسية لو جمعنا الذرات الان + +379 +00:34:51,190 --> 00:34:55,910 +في هذا المثال عندي أنا ل triple bond طب وين ال + +380 +00:34:55,910 --> 00:35:01,580 +nucleophile اللي عندي؟ عندي هنا C double bond Oالـ + +381 +00:35:01,580 --> 00:35:07,140 +O H للـUQ5 مرة تانية عندها كم احتمال احتمالين اي + +382 +00:35:07,140 --> 00:35:11,700 +احتمال منهم عملات الـ Exocyclization ممكن اتهاجم + +383 +00:35:11,700 --> 00:35:18,020 +على ال double bond بتعمل حلقة اصغر كلام سليم انه + +384 +00:35:18,020 --> 00:35:23,580 +ممكن تهاجم هنا وباحتمالين بالظبط + +385 +00:35:24,050 --> 00:35:29,410 +واضح؟ الآن من هدول الأربعة اللي طلع بالتجربة و أدى + +386 +00:35:29,410 --> 00:35:34,170 +إلى حلقة خمسية ال exocyclization على ال triple + +387 +00:35:34,170 --> 00:35:40,550 +bond هنا في عنده أجزيم and OH يعني خلينا ال OH هذه + +388 +00:35:40,550 --> 00:35:46,850 +نرسمها هنا جريبة من ال double bond واضح؟ ايش + +389 +00:35:46,850 --> 00:35:50,090 +الاحتمالات؟ واحد + +390 +00:35:51,610 --> 00:35:55,690 +أو اتنين حسب ما انتوا شايفين وين ال cyclization تم + +391 +00:35:55,690 --> 00:36:01,750 +اذا ايش نوع ال cyclization اكزو ولا اندو؟ + +392 +00:36:31,740 --> 00:36:39,410 +اندروسايكليزياتثلاثية .. رباعية .. رباعية .. + +393 +00:36:39,410 --> 00:36:45,050 +خماسية .. خماسية .. خماسية .. خماسية .. خماسية .. + +394 +00:36:45,050 --> 00:36:51,470 +خماسية .. خماسية .. خماسية ..فمثل هذه الأسئلة لو + +395 +00:36:51,470 --> 00:36:54,810 +كنتوا بتسأله draw all the possible or four + +396 +00:36:54,810 --> 00:36:58,670 +possible cyclization products بده الإنسان خلاص + +397 +00:36:58,670 --> 00:37:03,390 +فاهم الفكرة الفكرة في ال eucleophile ولا اكتر اكتر + +398 +00:37:03,390 --> 00:37:08,300 +من ال eucleophile في double bond ولا اكترأكثر من + +399 +00:37:08,300 --> 00:37:14,440 +double bond طبعا هو الإنسان لو بده يزيد فلسفة انه + +400 +00:37:14,440 --> 00:37:19,000 +ممكن يتخيل كمان ان هذه ال N اللي متصلة بال OH is + +401 +00:37:19,000 --> 00:37:24,520 +also ال UQU5 والله أنا شفتها بتتفاعل و بجيبك paper + +402 +00:37:24,520 --> 00:37:32,460 +عليها بتتفاعل .. بتتفاعل و بعدين بتفقد الميهفي + +403 +00:37:32,460 --> 00:37:39,260 +مقالات في نفس هذه الـ auxins التفاعل تم على ال + +404 +00:37:39,260 --> 00:37:44,860 +nitrogen التفاعل تم على ال nitrogen و ممكن خارج + +405 +00:37:44,860 --> 00:37:48,980 +يعني إطار المحاضرة أن أفرجيكم مثال تم هان التفاعل + +406 +00:37:48,980 --> 00:37:54,920 +مش هان ماتنسوش ماتنسوش ولا إشي يعني في كل الأحوال + +407 +00:37:54,920 --> 00:38:01,280 +ال nucleophile زوج إلكترونات صح؟إذا لو أنا بدي أجي + +408 +00:38:01,280 --> 00:38:08,320 +أقولكوا نظريا كم ال eucleophile عند هنا تلاتة أنا + +409 +00:38:08,320 --> 00:38:12,860 +هنا عندى تلاتة واضح؟ وكان ممكن يمكن لو هنا أطول + +410 +00:38:12,860 --> 00:38:17,360 +وبيطلع حلقة خماسية من هذا التفاعل أنه يتم على هذا + +411 +00:38:17,360 --> 00:38:21,320 +ال eucleophile وفي أمثلة في الدنيا في الأكزين + +412 +00:38:21,320 --> 00:38:26,660 +التفاعل بيتم من ال nitrogen مش من ال oxygen موجود + +413 +00:38:30,250 --> 00:38:32,730 +طب المثل اللي قبل .. مش هذا اللي قبل .. اللي قبلي + +414 +00:38:32,730 --> 00:38:38,970 +.. الصفحة اللي قبلي .. هذا الان ممكن تهاجم على ال + +415 +00:38:38,970 --> 00:38:41,110 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +416 +00:38:41,110 --> 00:38:42,350 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +417 +00:38:42,350 --> 00:38:42,610 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +418 +00:38:42,610 --> 00:38:43,010 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +419 +00:38:43,010 --> 00:38:43,010 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +420 +00:38:43,010 --> 00:38:43,410 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +421 +00:38:43,410 --> 00:38:43,410 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +422 +00:38:43,410 --> 00:38:43,490 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +423 +00:38:43,490 --> 00:38:43,490 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +424 +00:38:43,490 --> 00:38:43,490 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +425 +00:38:43,490 --> 00:38:46,820 +.. ال .. ال .. ال .. ال .. الإن هتهاجم من هنا + +426 +00:38:46,820 --> 00:38:52,960 +مافيش إمكانية هنا في إمكانية نظرية لكن دايما اللي + +427 +00:38:52,960 --> 00:38:56,040 +بتهاجم ال N H ليش؟ هذه لو بدها تهاجم هتعطيك N + +428 +00:38:56,040 --> 00:39:00,160 +positive يعني ال N عشان تكون ال nucleophile اللي + +429 +00:39:00,160 --> 00:39:07,100 +هي ال N H2 mainly و ال N H يعني ربما لو هذه كانت H + +430 +00:39:07,100 --> 00:39:12,380 +بيكون الكلامmore logical يعني دايما النيوكليوفايل + +431 +00:39:12,380 --> 00:39:17,400 +اكثر الان اتش تو و الان اتش ليش لأنه ال neutral + +432 +00:39:17,400 --> 00:39:21,320 +النيوكليوفايل لما بيتفاعل بفقد اتش فلو كان ان اتش + +433 +00:39:21,320 --> 00:39:25,400 +تو بصفة ان اتش و لو كان ان اتش بصفة ان اتش هيك + +434 +00:39:25,400 --> 00:39:30,840 +اتعودنا احنا عليه لكن ايه كويس ان انتوا تبدأوا + +435 +00:39:30,840 --> 00:39:36,710 +تتفاعلوا مع ايشمع الموضوع و مع الاحتمالات هذا + +436 +00:39:36,710 --> 00:39:42,330 +المثال هو تفاعل على ال carbon ال triple bond + +437 +00:39:42,330 --> 00:39:47,930 +carbon مرة تانية easter مع ال hydroxylamine انتوا + +438 +00:39:47,930 --> 00:39:51,110 +مرة معاكوا ال hydroxylamine مع ال ketones و ال + +439 +00:39:51,110 --> 00:39:55,590 +aldehydes اللي بيعطيك oxygen addition لكن ال + +440 +00:39:55,590 --> 00:40:00,550 +hydroxylamine او ال hydrazine substituteأيش بيعطي + +441 +00:40:00,550 --> 00:40:04,030 +مع ال Easter Substitution لأن تفاعل ال Easter + +442 +00:40:04,030 --> 00:40:07,390 +الأساسي Substitution بناء على ذلك هذا لما بيعمل + +443 +00:40:07,390 --> 00:40:12,270 +التفاعل التحضيري هذه بدأت هاجم هنا و ترد ال O + +444 +00:40:12,270 --> 00:40:19,830 +Ethel صار عندكم C double bond O NH OH الأن ال OH + +445 +00:40:19,830 --> 00:40:26,450 +عندها احتمالين ال Exo و ال Indo أي واحد اللي تم + +446 +00:40:26,450 --> 00:40:33,040 +هناالاندو ساكنزاشي ان هذه جت للداخل و صارت minus و + +447 +00:40:33,040 --> 00:40:38,260 +ما إلى ذلك طيب لو انا اجيت سألكوا سؤال جبتلكوا في + +448 +00:40:38,260 --> 00:40:46,600 +الامتحان هذا المركب و رسمتلكوا هنا N او + +449 +00:40:46,600 --> 00:40:50,680 +NH طبعا حلو هيدرازين و قلتلكوا ابدولي من هنا + +450 +00:40:50,680 --> 00:40:55,600 +هيدرازين هيدرازين + +451 +00:40:55,600 --> 00:41:01,780 +المحل هذابصير unatched طبعا بديش answer انه هذا + +452 +00:41:01,780 --> 00:41:04,340 +الان اليوكليوفال و هذا اليوكليوفال و عندكم + +453 +00:41:04,340 --> 00:41:10,020 +احتمالات كلها بده تكون داخلة في ذهن و داخلة في + +454 +00:41:10,020 --> 00:41:19,040 +تفكير الإنسان و هو بيشتغل الآن هاجف انا عشانناخد + +455 +00:41:19,040 --> 00:41:24,880 +الأمر بهدوء أكتر عند التفاعل على C triple bond N + +456 +00:41:24,880 --> 00:41:29,540 +هنجف ان التفاعل على C triple bond N ان شاء الله + +457 +00:41:29,540 --> 00:41:33,940 +المرة الجاية بنكمل بكون عنواننا reaction at + +458 +00:41:33,940 --> 00:41:39,640 +nitriles and isonitriles لأن الحقيقة ال nitriles و + +459 +00:41:39,640 --> 00:41:44,940 +ال isonitriles فيهم أمثلة ثرية و مفيدين بشكل clear + +460 +00:41:44,940 --> 00:41:47,120 +في ال heterocyclic synthesis + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/0AW2jJkssxA.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/0AW2jJkssxA.srt new file mode 100644 index 0000000000000000000000000000000000000000..0e8fbdba019f45e2fc71bbf85194a0be342c3ded --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/0AW2jJkssxA.srt @@ -0,0 +1,4335 @@ +1 +00:00:20,670 --> 00:00:26,050 +بسم الله الرحمن الرحيم في موضوع الـ heterocyclic + +2 +00:00:26,050 --> 00:00:31,330 +synthesis سبق أن تكلمنا عن أكثر من طريقة عامة + +3 +00:00:31,330 --> 00:00:34,790 +لتحضير الـ heterocyclic rings تكلمنا عن الـ + +4 +00:00:34,790 --> 00:00:39,030 +cyclization reactions بأنواعها المرة الماضية + +5 +00:00:39,030 --> 00:00:45,130 +أعطينا مقدمة مختصرة باسطة بالمر عليها الآن في الـ + +6 +00:00:45,130 --> 00:00:49,310 +cycloaddition reactions بشكل عام قلنا أن الـ + +7 +00:00:49,310 --> 00:00:54,090 +Cycloadditional reactions تفاعلات محددة معروفة جزء + +8 +00:00:54,090 --> 00:01:01,870 +منها مُخْدَ أسماء وهذه التفاعلات زي ما اتفقنا فيها + +9 +00:01:01,870 --> 00:01:07,770 +نظم فيها by electrons أوتو يعني species بيقتربوا من + +10 +00:01:07,770 --> 00:01:12,630 +بعض و بيكونوا رابطتين بنفس اللحظة عشان هيك لأن في + +11 +00:01:12,630 --> 00:01:16,290 +عندي أنا cyclic intermediate بتصير بنحكي عن شيء + +12 +00:01:16,290 --> 00:01:24,100 +بنسميه pericyclic reactions واضح؟ الآن كتصنيف الـ + +13 +00:01:24,100 --> 00:01:28,180 +Cycloaddition reactions هلاحظ أنه في عندنا الأنواع + +14 +00:01:28,180 --> 00:01:33,660 +اللي موجودة أمامنا وزي ما اتفقنا أنه ممكن أن نصنف + +15 +00:01:33,660 --> 00:01:36,160 +احنا الـ Cycloaddition reactions من ناحية الـ + +16 +00:01:36,160 --> 00:01:39,400 +Geometry أو حجم الحلقة أو من ناحية الـ pi + +17 +00:01:39,400 --> 00:01:44,320 +-electrons تكلمنا عن الـ Chelotropic reactions + +18 +00:01:44,770 --> 00:01:48,710 +هدول الـ Chelotropic reactions ممكن يكون عندي من + +19 +00:01:48,710 --> 00:01:54,550 +ناحية الـ الـ Geometry ذرة فيها two pi-electrons + +20 +00:01:54,550 --> 00:01:58,870 +مع double bond وبالتالي يعطوني حلقة ثلاثية وممكن + +21 +00:01:58,870 --> 00:02:04,230 +يكون ذرة برضه فيها pi-electrons أو free electrons + +22 +00:02:04,230 --> 00:02:12,370 +مع two pi خلينا نقول يعطينا حلقة خماسية في كل + +23 +00:02:12,370 --> 00:02:16,910 +الأحوال الـ Chelotropic reaction من أبسط تعريفاته + +24 +00:02:16,910 --> 00:02:22,310 +أن أنا لما بشتغل على ال pi system أو ال pi + +25 +00:02:22,310 --> 00:02:26,590 +electrons يعني هنا في عند اتنين pi-electrons و هنا + +26 +00:02:26,590 --> 00:02:30,410 +في عند اتنين pi-electrons شايفينهم بالأحمر؟ أنا + +27 +00:02:30,410 --> 00:02:34,530 +بحول هدول ال pi-electrons إلى sigma bonds يعني في + +28 +00:02:34,530 --> 00:02:39,190 +cycle additions معنى أن أنا بدأ أعمل تنتيل bonds + +29 +00:02:39,190 --> 00:02:43,670 +أن بده يكون في عنده من ال pi-electrons تنتيل + +30 +00:02:43,670 --> 00:02:49,030 +يتحولوا إلى sigma bonds أنا أصبح أتاجر جديدة سيجما + +31 +00:02:49,030 --> 00:02:53,050 +بونز الآن في الـ Chelotropic reactions هدولة two + +32 +00:02:53,050 --> 00:02:56,710 +new سيجما بونز بيكونوا متصلات بنفس الذرة بيكونوا + +33 +00:02:56,710 --> 00:03:01,370 +متصلات بنفس الذرة واضح فهي معنى Chelotropic + +34 +00:03:01,370 --> 00:03:06,310 +reaction وكذلك الحال لو بدي أنظر لهذا هي أنا هنا + +35 +00:03:06,310 --> 00:03:12,250 +في عندي كم باي إلكترون؟ اتنين أربعة ستة طالما أنا بدي + +36 +00:03:12,250 --> 00:03:16,090 +أعمل two new سيجما بونز إذا هيلزمني من الست هدول + +37 +00:03:16,660 --> 00:03:22,140 +أربعة حيظل اتنين واضح لما أنا بقول بده يلزمني + +38 +00:03:22,140 --> 00:03:26,800 +أربعة معناه ذلك حيظل عنده باي واحدة ولذلك أنا لو + +39 +00:03:26,800 --> 00:03:31,440 +بده أجي أطلع مثلا هنا هي عملت sigma bond وهي كمان + +40 +00:03:31,440 --> 00:03:37,880 +sigma bond وظلت إيش؟ باي المجموع الكلي قداش؟ ستة هنا + +41 +00:03:37,880 --> 00:03:43,900 +كان أربعة ستة فهذا أيضًا Chelotropic reaction ليش؟ + +42 +00:03:43,900 --> 00:03:46,960 +لأن احنا عملنا ال two new sigma bonds at the same + +43 +00:03:46,960 --> 00:03:53,140 +atom الآن في مثل هذه التفاعلات اللي مثلا اسمه two + +44 +00:03:53,140 --> 00:03:57,680 +plus two cycle addition أنا هنا في عندي التنتين pi + +45 +00:03:57,680 --> 00:04:00,900 +electrons أو تنتين pi bonds وصاروا تنتين sigma + +46 +00:04:00,900 --> 00:04:06,890 +bonds مش فيها مشكلة ما ضلش عندي واضح؟ الآن في هذا + +47 +00:04:06,890 --> 00:04:11,110 +النوع خلينا نقول ال Diels-Alder reaction أنا + +48 +00:04:11,110 --> 00:04:13,830 +المجموع اللي عندي في ال pi-electron ستة هي اتنين + +49 +00:04:13,830 --> 00:04:20,130 +هي أربعة هي ستة الآن بالتأكيد حيصير عندي اتنين + +50 +00:04:20,130 --> 00:04:24,610 +أربعة واحد من هدول يجى على ال Y عشان ذلك ال Y بطلت + +51 +00:04:24,610 --> 00:04:31,500 +negative فما فيش يعني أفضل فقد أو اكتساب يعني + +52 +00:04:31,500 --> 00:04:34,600 +الإلكترونات بتروح بدون ما نعرف وين راحت لأ هذا + +53 +00:04:34,600 --> 00:04:37,980 +الكلام غير وارد كذلك الحالة في Diels-Alder + +54 +00:04:37,980 --> 00:04:43,460 +reaction يعني عندي اتنين أربعة ستة الآن هي دي صارت + +55 +00:04:43,460 --> 00:04:49,960 +sigma bond sigma bond وهي ضال عندي pi bond واحدة + +56 +00:04:49,960 --> 00:04:56,330 +واضح؟ ولذلك ربما كلكم بتذكروا لو ال Diels-Alder + +57 +00:04:56,330 --> 00:05:01,750 +reaction كان مع triple bond مش مع double bond + +58 +00:05:01,750 --> 00:05:06,030 +حيصير + +59 +00:05:06,030 --> 00:05:11,530 +double bond فالأعداد سليمة هذا التصنيف من ناحية + +60 +00:05:11,530 --> 00:05:15,370 +تسميتهم إذا هما ال Chelotropic reactions ال two + +61 +00:05:15,370 --> 00:05:18,130 +plus two cycloadditions ال one three dipolar + +62 +00:05:18,130 --> 00:05:21,700 +cycloadditions و Diels-Alder reaction الآن من ناحية + +63 +00:05:21,700 --> 00:05:25,780 +ال pi-electrons يا بيكونوا 2 plus 2 يا 2 plus 4 + +64 +00:05:25,780 --> 00:05:30,300 +يعني كلهم بتصنفوا تحت واحد من هدول التصنيف يعني كل + +65 +00:05:30,300 --> 00:05:33,680 +ال cycle additions كل ال cycle additions يا إما من + +66 +00:05:33,680 --> 00:05:38,980 +ناحية ال pi-electrons 2 plus 2 pi-electrons يا + +67 +00:05:38,980 --> 00:05:41,160 +بيكونوا 2 plus 4 + +68 +00:05:43,730 --> 00:05:47,430 +أشهر نوع .. أشهر نوع في الـ cycloaddition + +69 +00:05:47,430 --> 00:05:52,070 +reactions الـ 1,3-dipolar cycloaddition reactions + +70 +00:05:52,070 --> 00:05:57,810 +لاحظوا في كيمياء الكربون .. في كيمياء الكربون يعني + +71 +00:05:57,810 --> 00:06:01,890 +لما يكونوا كل الذرات كربون ربما الـ Diels-Alder + +72 +00:06:01,890 --> 00:06:08,630 +reaction هو الأشهر واضح؟ الآن لو بعض الذرات بطلوا + +73 +00:06:08,630 --> 00:06:14,420 +كربون ماذا نسمي التفاعل؟ نعطيه اسم يعني لما يكون + +74 +00:06:14,420 --> 00:06:19,200 +النظام بهذا الشكل وكلّه كربون، هذا Diels-Alder + +75 +00:06:19,200 --> 00:06:24,220 +عادي، الآن لو واحدة من هدولة صارت hetero atom يعني + +76 +00:06:24,220 --> 00:06:29,930 +أكسجين، نيتروجين، هالوجين، في أي مكان بنسميه hetero + +77 +00:06:29,930 --> 00:06:34,870 +Diels-Alder reaction واضح؟ الآن إيش اللي موجود منه + +78 +00:06:34,870 --> 00:06:38,770 +أكثر في الدنيا ال Diels-Alder اللي كلّه كربون + +79 +00:06:38,770 --> 00:06:44,390 +ولا ال hetero Diels-Alder reaction اللي كلّه كربون + +80 +00:06:44,390 --> 00:06:48,990 +واضح؟ الآن لو جينا على ال 1,3-dipolar + +81 +00:06:48,990 --> 00:06:53,090 +cycloaddition أيضًا ممكن نتخيل 1,3-dipolar + +82 +00:06:53,090 --> 00:07:00,440 +cycloaddition كل ذراته Carbon أو 1,3-dipolar + +83 +00:07:00,440 --> 00:07:03,700 +cycloaddition فيها هيترو أتوم هان أو هان أو هان أو + +84 +00:07:03,700 --> 00:07:08,600 +هان أو هان الآن هو المشهور أكثر ال 1,3-dipolar + +85 +00:07:08,600 --> 00:07:12,940 +cycloaddition reactions اللي فيها هيترو أتوم واضح + +86 +00:07:12,940 --> 00:07:17,200 +بمعنى لو بدنا نقول ال 1,3-dipolar cycloaddition + +87 +00:07:17,200 --> 00:07:22,720 +reactions اللي فيها كلها carbon الخمس ذرات لو + +88 +00:07:22,720 --> 00:07:26,720 +بتأخذها كنسبة مئوية من مجمل اللي منشور في هذا + +89 +00:07:26,720 --> 00:07:31,200 +المجال هي بالتأكيد أقل من 1% بتأكيد أقل + +90 +00:07:31,200 --> 00:07:34,220 +من 1% 99% من أمثلة ال + +91 +00:07:34,220 --> 00:07:38,640 +one three dipolar cycloaddition reactions هي عبارة + +92 +00:07:38,640 --> 00:07:45,180 +عن إيش؟ Hetero atoms ال Diels-Alder موجود فيه + +93 +00:07:45,180 --> 00:07:48,220 +الشغل الثاني يعني فيه كثير أنفلة في الدنيا الآن + +94 +00:07:48,220 --> 00:07:51,040 +hetero Diels-Alder reaction لكن بيظل في مجال + +95 +00:07:51,040 --> 00:07:56,500 +الكربون أشه موجود أكثر ولذلك في عندنا احنا يعني + +96 +00:07:56,500 --> 00:08:02,200 +موسوعات بالذات في موسوعة اسمها comprehensive + +97 +00:08:02,200 --> 00:08:08,120 +heterocyclic chemistry هذه موسوعة عملت في ال 84 و + +98 +00:08:08,120 --> 00:08:11,000 +تجددت أيضًا في التسعينات ويمكن الآن أطلع منها + +99 +00:08:11,000 --> 00:08:18,820 +كمان شيء comprehensive heterocyclic + +100 +00:08:18,820 --> 00:08:19,480 +chemistry + +101 +00:08:24,390 --> 00:08:28,390 +هذه موسوعة عامة ال comprehensive heterocyclic + +102 +00:08:28,390 --> 00:08:32,410 +chemistry اللي في ال 84 الآن في موسوعة ثانية + +103 +00:08:32,410 --> 00:08:41,310 +Cycloaddition reactions لإيه بدوها Cycloaddition + +104 +00:08:41,310 --> 00:08:52,980 +reactions طبعًا لإيه بدوها الآن لاحظوا معي العالم كيف + +105 +00:08:52,980 --> 00:08:57,280 +اليوم بيفكر والمفروض نفهم العالم كيف بيفكر جيدًا + +106 +00:08:57,280 --> 00:09:02,980 +العالم اليوم ما بيفكرش أن شخص معين يقوم بكل العمل + +107 +00:09:02,980 --> 00:09:07,580 +هذا الأسلوب يعني أسلوب صعب وعقيد والإنسان لا يملك + +108 +00:09:07,580 --> 00:09:13,350 +كل المقومات وكل الوقت وكل التخصص لذلك بيسعوا الناس + +109 +00:09:13,350 --> 00:09:17,610 +نحو نظام الموسوعات، يعني اليوم لما أنا بدي أجي + +110 +00:09:17,610 --> 00:09:21,310 +أحكي عن الـ cycloaddition reactions وأقول أن في + +111 +00:09:21,310 --> 00:09:24,950 +عندي one three-dipolar-cycloaddition reactions، في + +112 +00:09:24,950 --> 00:09:27,630 +عندي azides، في عندي diazo compounds، في عندي + +113 +00:09:27,630 --> 00:09:32,670 +nitrile oxides، nitrile amines، nitrile ylids، كذا + +114 +00:09:32,670 --> 00:09:37,320 +كذا قال بده بني آدم يجمع كل هذه المعلومات هذا + +115 +00:09:37,320 --> 00:09:42,260 +كثير فهم بيحطوا editor هذا ال editor بيكون مسئول + +116 +00:09:42,260 --> 00:09:47,200 +بتحرير هذه الموسوعة هو بيعرف كل الناس المتميزة في + +117 +00:09:47,200 --> 00:09:54,340 +هذا المجال وبيكلف كل إنسان متميز أن أنت حضر جزء + +118 +00:09:54,340 --> 00:09:59,240 +من الموضوع فناس بيحضروا ما كتب عن الأزايد ناس + +119 +00:09:59,240 --> 00:10:01,960 +بيحضروا ما كتب عن النيتريل اكسايد عن النيتريل اي + +120 +00:10:01,960 --> 00:10:06,740 +means هو بيجمعوا بنسق كل الكلام في الآخر بيطلعوا + +121 +00:10:06,740 --> 00:10:11,720 +بإيش؟ بموسوعة فالموسوعة بيكون لها editor editor + +122 +00:10:11,720 --> 00:10:20,040 +يعني محرر وجواتها أكثر من مؤلف كل شيء بيكون شخص ما + +123 +00:10:20,040 --> 00:10:25,540 +عمل تأليف في داخله فال editor ليس مؤلفًا ال editor + +124 +00:10:25,540 --> 00:10:29,680 +محرر بيعرف مين الناس اللي بتكتب كويس في المجال + +125 +00:10:29,680 --> 00:10:32,660 +اللي عندها أبحاث في المجال بكلفها بتجمع كل + +126 +00:10:32,660 --> 00:10:38,240 +المعلومات في النهاية بيقدروا يعملوا موسوعة عن أي + +127 +00:10:38,240 --> 00:10:44,420 +شغلة ياخدوا المجهود الجماعي خلينا نقول العلمي طبعًا + +128 +00:10:44,420 --> 00:10:48,440 +في موسوعات شوية عامة يعني مش علمية زي ما بتشوفوا + +129 +00:10:48,440 --> 00:10:54,800 +على ال internet ال Wikipedia مثلاً الآن هذه مش + +130 +00:10:54,800 --> 00:10:58,200 +ضروري أن كل من كتب فيها متخصص ولذلك بتلاقي ناس + +131 +00:10:58,200 --> 00:11:03,660 +بكتبوا شيء بسيط و بكتبوا هذه نواة أو بذرة يمكن أن + +132 +00:11:03,660 --> 00:11:11,630 +تتطور بخصوص هالموضوع هذا الآن خلينا نظل في النوع + +133 +00:11:11,630 --> 00:11:16,710 +الأشهر في ال cycle additions اللي هو ال 13-dipolar + +134 +00:11:16,710 --> 00:11:21,850 +cycle addition reactions الحقيقة يعني من أكثر + +135 +00:11:21,850 --> 00:11:25,790 +العلماء اللي صنفوا في هذا الموضوع يعني كان في + +136 +00:11:25,790 --> 00:11:32,620 +أمثلة متناثرة ما كانش ماخذ مسمى واضح يعني هنا في + +137 +00:11:32,620 --> 00:11:37,080 +مثال هنا في مثال لكن ما كانش مصنفين بشكل جيد هذا + +138 +00:11:37,080 --> 00:11:40,320 +الموضوع حتى أجا العالم Huisgen + +139 +00:11:44,090 --> 00:11:49,470 +وعمل يعني مقال شهير جمع فيه ال one three dipoles + +140 +00:11:49,470 --> 00:11:54,790 +حط المفهوم بشكل واضح ومن هداك الوقت صار هذا يعني + +141 +00:11:54,790 --> 00:11:59,550 +موضوع مستقل الذاته اسمه one three dipolar cycle + +142 +00:11:59,550 --> 00:12:02,970 +و additions بدأ الناس يطوروا فيه إلى أن وصل أنه + +143 +00:12:02,970 --> 00:12:07,530 +يكتب وينعمل فيه موسوعات زي ما اتكلمنا farيه + +144 +00:12:07,530 --> 00:12:12,350 +ويزجن أول ما انجمع الأشياء البسيطة المتنافرة صاغ + +145 +00:12:12,350 --> 00:12:15,810 +موضوع بصياغة جيدة في ال 1900 + +146 +00:12:26,360 --> 00:12:31,540 +عشان نفهم الموضوع لحظته أنت ربما لما تكلمنا عن ال + +147 +00:12:31,540 --> 00:12:35,020 +one three dipolar cycle addition قلنا أنه تلت ذرات + +148 +00:12:35,020 --> 00:12:39,520 +بدهم يتحدوا مع اثنتين بدهم يعطينا ايش بدهم يعطونا + +149 +00:12:39,520 --> 00:12:46,080 +حلقة خمسية الآن خليني آخذ هنا ال one three dipolar + +150 +00:12:46,080 --> 00:12:50,900 +cycle addition وال deals alder reaction ربما في + +151 +00:12:50,900 --> 00:12:54,700 +ال deals alder reaction كلكم بتعرفوا أن هذا الجزء + +152 +00:12:54,700 --> 00:12:57,480 +ايش أنا كنت أسميه + +153 +00:13:00,570 --> 00:13:07,430 +رابطتين واضح الآن الجزء الثاني لأنه بيتفاعل معه أنا + +154 +00:13:07,430 --> 00:13:16,210 +بأسميه diene file okay الآن اسم diene file أجى لأنه + +155 +00:13:16,210 --> 00:13:22,290 +بيتفاعل مع الدايين بمعنى هذا لو أخذنا أي شيء لوحده + +156 +00:13:22,290 --> 00:13:27,800 +ما بيكونش اسمه diene file يعني لو جيت أقول أنا مثلا C + +157 +00:13:27,800 --> 00:13:31,920 +double bond N ايش رأيكم فيها بأقولها دي بس C + +158 +00:13:31,920 --> 00:13:36,200 +double bond N فقط لا غير الآن لو اتفعلت مع داين + +159 +00:13:36,200 --> 00:13:40,440 +بأسميها ايش دينوفايل في ال one three dipolar cycle + +160 +00:13:40,440 --> 00:13:45,600 +addition الثلاث ذرات هدول عادة بيكونوا ماخذين موجة + +161 +00:13:45,600 --> 00:13:48,820 +بسالبة أو عاملين Dipolar على الأطراف مع resonance + +162 +00:13:48,820 --> 00:13:52,500 +structures تانية زي ما أنتم شايفين هنا و لذلك + +163 +00:13:52,500 --> 00:13:56,680 +لأنه دائما بيتفعلوا من موقع واحد وثلاثة سميهم ايش + +164 +00:13:56,680 --> 00:14:01,280 +one three dipolar cycle addition الآن هذا ديبول + +165 +00:14:01,280 --> 00:14:06,460 +هذا ديبول اللي بده يتفاعل معه شو هأسميه؟ + +166 +00:14:06,460 --> 00:14:11,000 +Dipolarophile واضح؟ + +167 +00:14:13,800 --> 00:14:18,640 +Dipolarophile وبناء على ذلك لو أنا في عندي سيضة + +168 +00:14:18,640 --> 00:14:21,020 +بال double bond M بدي أجي أسألكم وأقولكم هل دي + +169 +00:14:21,020 --> 00:14:26,080 +داينوفايل ولا دايبولاروفايل هي إذا اتفعلت مع + +170 +00:14:26,080 --> 00:14:30,120 +دايبول قلنا لها دايبولاروفايل وإذا اتفعلت مع داين + +171 +00:14:30,120 --> 00:14:33,320 +قلنا لها داينوفايل فكلمة داينوفايل و + +172 +00:14:33,320 --> 00:14:37,820 +دايبولاروفايل هي مش وصف للشيء بذاته لا هي وصف + +173 +00:14:37,820 --> 00:14:46,350 +للشيء حسب ما ايش حسب ما بتفاعل مع الأصناف الثانية + +174 +00:14:46,350 --> 00:14:50,610 +واضحة الفكرة؟ والله واضح لكم ياه بمثال اجتماعي زي + +175 +00:14:50,610 --> 00:14:55,110 +ما بتكون صبحية هي في النهاية صبحية الآن إذا تزوجت + +176 +00:14:55,110 --> 00:14:58,630 +أحمد بنقول عنها زوجة أحمد وإذا تزوجت محمد بنقول + +177 +00:14:58,630 --> 00:15:04,610 +زوجة محمد وهذه نفس الشيء هي double bond إذا صارت + +178 +00:15:04,610 --> 00:15:08,570 +مع الداين Dipolarophile داينوفايل مع الديبول + +179 +00:15:08,570 --> 00:15:14,450 +دايبولاروفايل واضحة الآن لما أبدي أجي أحكي عن + +180 +00:15:14,450 --> 00:15:19,170 +دايبولاروفايل أو داينوفايل مجرد double bond هتلاقوا + +181 +00:15:19,170 --> 00:15:24,410 +الأمر بسيط لكن ربما أمر عليكم وعارفينه لكن ايش + +182 +00:15:24,410 --> 00:15:29,530 +الأشياء اللي عادة بتشتهر أنها بتكون ديبولاروفايل ولذلك + +183 +00:15:29,530 --> 00:15:34,530 +لما بنيجي نحكي بتلاقونا أكثر بنركز ايش هي ال + +184 +00:15:34,530 --> 00:15:37,770 +dipoles؟ يعني احنا double bond أو triple bond + +185 +00:15:37,770 --> 00:15:42,130 +عارفينها، كل double bond أو triple bond تصلح في + +186 +00:15:42,130 --> 00:15:45,970 +لحظة من اللحظات أن نقول عنها dipolarophile أو + +187 +00:15:45,970 --> 00:15:51,980 +dienophile لكن عندما نأتي إلى الـ dipoles الحقيقة + +188 +00:15:51,980 --> 00:15:56,300 +الـ dipoles أعداد محددة من أشهر الأشياء اللي + +189 +00:15:56,300 --> 00:16:00,560 +موجودة هذا بمعنى إنه في أشياء تانية موجودة يعني + +190 +00:16:00,560 --> 00:16:04,980 +عليها بعض التفاعلات لو كان في عندي تلت ذرات + +191 +00:16:04,980 --> 00:16:12,190 +نيتروجين ورا بعض بنسمي ال .. ال dipole azide أزايد + +192 +00:16:12,190 --> 00:16:16,050 +زي ما في عندكم صوديوم أزايد لاحظوا هذا موجود بشكل + +193 +00:16:16,050 --> 00:16:20,950 +أنه هنا triple bond وهنا زوج الإلكترونات على + +194 +00:16:20,950 --> 00:16:26,170 +الطرف يعني موجود بشكل البروباريجيل تعرفوا + +195 +00:16:26,170 --> 00:16:29,810 +البروباريجيل اللي هو موازي للآليل بس ب triple bond + +196 +00:16:29,810 --> 00:16:33,750 +الآليل system double bond وبعدين single bond + +197 +00:16:33,750 --> 00:16:34,930 +البروباريجيل + +198 +00:16:37,490 --> 00:16:42,630 +الآن من هذا النوع ولاحظوا أن كله في ال triple + +199 +00:16:42,630 --> 00:16:46,590 +bond هذه في أحد ال resonance structures خلينا نقول + +200 +00:16:46,590 --> 00:16:51,470 +أن هذا ال resonance structure اللي في ال all octet + +201 +00:16:51,470 --> 00:16:58,800 +يعني كل الذرات اللي موجودين في all octet كل الذرات + +202 +00:16:58,800 --> 00:17:02,600 +اللي موجودين هنا بنطبق عليهم ال octet rule يعني + +203 +00:17:02,600 --> 00:17:07,120 +ما فيش ذرة فيها electron sextet مثلا أو ما إلى ذلك + +204 +00:17:07,120 --> 00:17:13,140 +يعني لو كنت بدأ أكمل في هذا المكان مثلا بدأ أكون + +205 +00:17:13,140 --> 00:17:18,340 +حاطط هنا هي ال minus وهي ال plus الآن أجمع عند ال + +206 +00:17:18,340 --> 00:17:21,800 +nitrogen هذا اثنين أربعة ستة ثمانية عند ال nitrogen + +207 +00:17:21,800 --> 00:17:25,680 +هذا اثنين أربعة ستة ثمانية عند هذا اثنين أربعة ستة + +208 +00:17:25,680 --> 00:17:30,420 +ثمانية فكل الذرات ايش اللي موجود حواليها all octet + +209 +00:17:30,420 --> 00:17:35,480 +فموجود هذا ال one three dipoles منها ال azides + +210 +00:17:35,480 --> 00:17:41,080 +الآن ال diazo compounds ومنها ال diazomethane ال + +211 +00:17:41,080 --> 00:17:45,410 +diazomethane اللي أخذناه بيعمل ال carbene بالتسخين + +212 +00:17:45,410 --> 00:17:49,090 +أو بال photolysis نفسه على حرارة عادية ممكن يعمل + +213 +00:17:49,090 --> 00:17:51,570 +cycle addition دائما ال cycle addition على ذرات + +214 +00:17:51,570 --> 00:17:57,610 +الطرفية ال diazo هيتنتين وال carbon ال diazo + +215 +00:17:57,610 --> 00:18:02,030 +compounds الآن بعدين بيجي عندي نيترال مع ال oxygen + +216 +00:18:02,920 --> 00:18:08,700 +Nitrile Oxide مع الـ Nitrogen Nitrile Amides و + +217 +00:18:08,700 --> 00:18:13,200 +بتشتهر أكثر ال Nitrile Amides في معظم المقالات + +218 +00:18:13,200 --> 00:18:20,680 +باسم Nitrile Amines هكذا تكتب كلمة واحدة يعني في + +219 +00:18:20,680 --> 00:18:24,240 +نسبة كبيرة من المقالات هتلاقوها .. هتلاقوها موجودة + +220 +00:18:24,240 --> 00:18:29,680 +باسم Nitrile Amines ال Nitrile Amines هي Nitrile + +221 +00:18:29,680 --> 00:18:36,770 +Amides والأشهر أنها تكتب ايش نيترال أمين النيترال + +222 +00:18:36,770 --> 00:18:42,370 +مع السلفر نيترال سلفايت والنيترال مع الكاربون + +223 +00:18:42,370 --> 00:18:46,390 +بتعرفوا مرة عليكم ممكن في ال reaction الفوسفوراس + +224 +00:18:46,390 --> 00:18:50,070 +اليد لما بيكون عندي ذرة من المجموعة الخامسة أو + +225 +00:18:50,070 --> 00:18:55,340 +السادسة موجبة مع الكاربون السالبة هذا بنسميه ياليد + +226 +00:18:55,340 --> 00:18:58,640 +عليكم المصطلح ياليد أو منها الفوسفوراس ياليد اللي + +227 +00:18:58,640 --> 00:19:03,580 +بيمر بالـ vitigre action فهذا نيترال ياليد كل هدول + +228 +00:19:03,580 --> 00:19:09,680 +نوع نوع ثاني اللي فيه الـ ال نيل تايب يعني زي + +229 +00:19:09,680 --> 00:19:14,560 +الآليل جروب وهنا كله اكتت double bond منها ال + +230 +00:19:14,560 --> 00:19:20,780 +نيترونز CN O minus منها الازوميثين اميدز هي + +231 +00:19:20,780 --> 00:19:26,710 +ازوميثين ازوميثين هي ال نيتروجين مع الكاربون ازو + +232 +00:19:26,710 --> 00:19:33,510 +ميثاين وهنا M M Mites هنا ازو ميثاين بجانب كربون + +233 +00:19:33,510 --> 00:19:41,130 +سالبة إلد، هنا كربونيل طالما كاربون سالبة إلد، هنا + +234 +00:19:41,130 --> 00:19:46,750 +ثيوكاربونيل طالما كاربون سالبة إلد، الآن هدول + +235 +00:19:46,750 --> 00:19:50,170 +تقريبا من أشهر ال one in three die bones اللي + +236 +00:19:50,170 --> 00:19:56,640 +موجودين، لو بدكم تسألوني من الخبرة يعني قداش + +237 +00:19:56,640 --> 00:20:01,820 +أشهرهم لو بدنا نقول أنه منشور مثلا مائة ألف مقال + +238 +00:20:01,820 --> 00:20:05,620 +على ال one three dipolar cycle editions ايش أكثر + +239 +00:20:05,620 --> 00:20:09,440 +الأشياء اللي عليها نشرات أكثر الأشياء اللي عليها + +240 +00:20:09,440 --> 00:20:13,960 +نشرات غالبا ال nitrile oxides وال nitrile amides + +241 +00:20:13,960 --> 00:20:17,360 +يمكن ال nitrile amides أكثر يعني أنا بصنفها نمرة + +242 +00:20:17,360 --> 00:20:21,480 +واحد ال nitrile oxides يمكن تكون نمرة اثنين ال + +243 +00:20:21,480 --> 00:20:27,710 +azides نمرة ثلاثة الدايزو كومباونز يمكن تكون نمرة + +244 +00:20:27,710 --> 00:20:33,590 +أربعة ولذلك احنا في نسبة كبيرة من الأمثلة اللي + +245 +00:20:33,590 --> 00:20:36,230 +عندنا هنركز على الـ nitrile amines وال nitrile + +246 +00:20:36,230 --> 00:20:40,770 +oxides هدول مشهورين نيترال سالفايتس لا يعني أمثلة + +247 +00:20:40,770 --> 00:20:44,390 +قليلة جدا لكن لو حد بده يستعرض شو الأمثلة اللي في + +248 +00:20:44,390 --> 00:20:47,250 +ال literature وال reviews اللي في ال literature + +249 +00:20:47,250 --> 00:20:50,630 +عن ال nitrile amines وال nitrile oxides هتلاحظوا + +250 +00:20:50,630 --> 00:20:51,230 +أنها ايش + +251 +00:20:56,310 --> 00:21:03,030 +الآن دعونا نقول أن one three dipole بيحتمل أكثر من + +252 +00:21:03,030 --> 00:21:06,690 +resonance structure هذا أمر طبيعي وأحيانا + +253 +00:21:06,690 --> 00:21:10,830 +بتلاحظوا أن في بعض ال resonance structures بيكون + +254 +00:21:10,830 --> 00:21:16,180 +في عنده إن بين إن الطرفين polar لكن في كل الأحوال + +255 +00:21:16,180 --> 00:21:20,120 +هدول دائما بيتفعلوا من موقع واحد وثلاثة ولذلك هم + +256 +00:21:20,120 --> 00:21:25,200 +بتسموه one three dipoles يعني مثلا هذا ال diazo + +257 +00:21:25,200 --> 00:21:29,180 +compounds هذه أحد ال resonance structures لاحظوا + +258 +00:21:29,180 --> 00:21:31,360 +هذه على الطرف وعلى الطرف الثاني + +259 +00:21:51,150 --> 00:21:55,930 +موجة بسالب على الأطراف لكن في resonance structures + +260 +00:21:55,930 --> 00:22:01,170 +ثانية منوعة بإمكان الإنسان يرسم أكثر من + +261 +00:22:05,860 --> 00:22:10,220 +الآن لو جينا وسألنا ايش ال mechanism of + +262 +00:22:10,220 --> 00:22:14,320 +cycloaddition + +263 +00:22:14,320 --> 00:22:22,160 +طبعا اتفقنا سابقا بشكل واضح معكم أن + +264 +00:22:22,160 --> 00:22:29,760 +نكتب ناتج المعادلة زي ما هو موجود هنا عشان فقط نعرف + +265 +00:22:29,760 --> 00:22:33,400 +نكتب الناتج هنا نيجي نقول هذه هذا زوج إلكترونات + +266 +00:22:33,400 --> 00:22:37,400 +حركة هان أوكي عملنا رابطة هذا هاتو هان أوكي عملنا + +267 +00:22:37,400 --> 00:22:46,300 +هذا حطه على الواعي هذا كلام pathway عشان نفهم كيف + +268 +00:22:46,300 --> 00:22:50,100 +نكتب الناتج نفس الشيء متعودين أنت تعمله if deals + +269 +00:22:50,100 --> 00:22:55,880 +other reaction however this is يعني at all not يعني + +270 +00:22:55,880 --> 00:23:00,560 +أي ميكانيزم يعني مش هي الميكانيزم لما بنيجي نحكي + +271 +00:23:00,560 --> 00:23:05,240 +عن ميكانيزم أي حد بده يفسر شغلة أو بده يحط + +272 +00:23:05,240 --> 00:23:09,220 +ميكانيزم هي الميكانيزم محاولة التفسير طب وفي + +273 +00:23:09,220 --> 00:23:14,940 +البداية ايش اللي أنا بدي أفسر واضح لازم يكون عنده + +274 +00:23:14,940 --> 00:23:21,560 +معطيات عشان يفسرها يعني بني آدم نفترض هذه من + +275 +00:23:21,560 --> 00:23:27,160 +الأخطاء الشائعة اللي يعني الطلاب بيغلطوها من + +276 +00:23:27,160 --> 00:23:32,580 +الأخطاء خليني أقول الشائعة للطلاب في فلسفة فهمهم + +277 +00:23:32,580 --> 00:23:37,340 +للميكانيزم بيكونوا الحقيقة مش فاهمينها .. مش + +278 +00:23:37,340 --> 00:23:43,800 +فاهمينها إطلاقا أن الميكانيزم هي محاولة تفسير لشيء + +279 +00:23:43,800 --> 00:23:50,100 +معين حصل وتم عنده وبحاول أنا أن أفهم كيف تم هذا + +280 +00:23:50,100 --> 00:23:54,780 +الشيء الآن الطالب في مرات كثيرة بالذات في المراحل + +281 +00:23:54,780 --> 00:23:59,620 +الأولى بيصير يتخيل أن هو لأ هو بيعمل الميكانيزم + +282 +00:23:59,620 --> 00:24:04,180 +تؤدي إلى النتائج الآن السؤال هل الميكانيزم اللي + +283 +00:24:04,180 --> 00:24:09,650 +تؤدي إلى النتائج ولا أنا في الأساس عند نتائج وبحاجة + +284 +00:24:09,650 --> 00:24:14,030 +إلى ميكانيزم عشان أفسر هذه النتائج، الأصل أن أنا + +285 +00:24:14,030 --> 00:24:19,010 +عندي نتائج وأنا بحاجة إلى قلية أن أفسر هذه + +286 +00:24:19,010 --> 00:24:26,580 +النتائج، يعني مثلاً نفترض جريمة قتل تمت، تمّت جريمة + +287 +00:24:26,580 --> 00:24:31,400 +القتل الآن بيصير الشرطة مطلوب منها أن تعطيني + +288 +00:24:31,400 --> 00:24:35,120 +آلية كيف تم هذا الكلام الآن يوم ما بدأت تيجي تعطي + +289 +00:24:35,120 --> 00:24:38,780 +آلية يوم ما بدأت تيجي تعطي آلية بدأت تجمع أدلة + +290 +00:24:38,780 --> 00:24:48,880 +بمعنى أول شيء بدأت تطلع لتوجد جريمة بدون بدون جثة + +291 +00:24:48,880 --> 00:24:54,550 +بدون قتل وأنا ما فيش عندي ميكانيزم بدون ناتج يعني + +292 +00:24:54,550 --> 00:24:58,230 +أنه حد يقعد يتخيل إنه هذا إجا وعمل هيك وعمل هيك + +293 +00:24:58,230 --> 00:25:02,490 +واتفعل هيك وفي نهاية مافيش عنده ناتج فألف بقى أي + +294 +00:25:02,490 --> 00:25:09,210 +ميكانيزم إن الإنسان يكون إيش فصل ناتج وفصل هذا + +295 +00:25:09,210 --> 00:25:16,440 +الناتج بشكل سليم وصحيح واستطاع إنه يشخص الشكل تبعه + +296 +00:25:16,440 --> 00:25:20,340 +يعني لما أنتم مثلاً أخذتم بالأس أنوان reactions + +297 +00:25:20,340 --> 00:25:26,260 +أنه في عندي ممكن تـ rearrangement على سبيل المثال + +298 +00:25:26,260 --> 00:25:30,580 +لو يا طورة ما فصلتوش الناتج ولاحظتوا أن الناتج فعلاً + +299 +00:25:30,580 --> 00:25:35,760 +أجت .. أجت لـ nucleophile مش مكان الـ X في مكان + +300 +00:25:35,760 --> 00:25:40,660 +ثاني كان .. قلتوا في rearrangement؟ اه .. إذا + +301 +00:25:40,660 --> 00:25:46,600 +صياغة الكلام بدأت تكون بالشكل القادم لأنه أنا في + +302 +00:25:46,600 --> 00:25:51,340 +الناتج مثلاً في التفاعلات اللي يقول عنها SN1 لأنه + +303 +00:25:51,340 --> 00:25:57,360 +أنا في الناتج لاحظت أنه ال nucleophile إجا مش محل + +304 +00:25:57,360 --> 00:26:01,910 +الـ X بس تنتج أنه في rearrangement ما بتكونش صياغة + +305 +00:26:01,910 --> 00:26:06,150 +لأنه في rearrangement إيجي الناتج مش محدد واضحة + +306 +00:26:06,150 --> 00:26:11,850 +هذه الفكرة فأي فهم لميكانيزم بيلزمه أن نكون فهمنا + +307 +00:26:11,850 --> 00:26:17,130 +الناتج جيداً ومواصفات الناتج جيداً وبعدين + +308 +00:26:17,130 --> 00:26:21,890 +الميكانيزم بتيجي محاولة لتفسير إيش كيف تكون هذا + +309 +00:26:21,890 --> 00:26:27,240 +الناتج وعشان هيك لما بنيجي نقول بدنا mechanism of + +310 +00:26:27,240 --> 00:26:30,380 +one three bipolar cycle addition بنقول في الأول + +311 +00:26:30,380 --> 00:26:34,120 +إيش الأشياء اللي لاحظناها على هذا التفاعل بحاجة + +312 +00:26:34,120 --> 00:26:37,840 +إلى تفسير يجب أن نعرفها جيداً وبعدين بنقترح + +313 +00:26:37,840 --> 00:26:41,260 +ميكانيزم بتفسرها مش بنعطيه ميكانيزم وبعدين بنقول + +314 +00:26:41,260 --> 00:26:45,220 +الأشياء بدأت تتبعلها الشغل الأولى للخواص ال + +315 +00:26:45,220 --> 00:26:51,190 +stereo selectivity إن معظم تفاعلات الـ 1,3-dipolar + +316 +00:26:51,190 --> 00:26:55,430 +cycloadditions are stereoselective إيش معنى هذا + +317 +00:26:55,430 --> 00:27:01,330 +الكلام؟ لو أنا إجيت على الـ Dipolarophile على سبيل + +318 +00:27:01,330 --> 00:27:05,190 +المثال ولاحظت إن هذا الـ Dipolarophile ماخد + +319 +00:27:05,190 --> 00:27:10,810 +Stereochemistry معينة Stereochemistry معينة بمعنى + +320 +00:27:10,810 --> 00:27:20,770 +الـ R1 و R3 فيه جايين على جهة واحدة الآن أنا لما بدي + +321 +00:27:20,770 --> 00:27:23,430 +أغيّر هذه لأنه في عندي double bond ال rotation + +322 +00:27:23,430 --> 00:27:27,530 +ممنوع مافيش إمكانية .. okay الآن لما أنا بدي آجي + +323 +00:27:27,530 --> 00:27:34,490 +أشوف الناتج هل يا ترى ال R1 و R3 بيظلهم على جهة + +324 +00:27:34,490 --> 00:27:38,790 +واحدة وال R2 و R4 على جهة واحدة بمعنى أنه في عندي + +325 +00:27:38,790 --> 00:27:42,030 +retention of configuration أنه مازالوا على جهة + +326 +00:27:42,030 --> 00:27:47,050 +واحدة ولا بينعكس وبتصير ال R1 على جهة وال R3 + +327 +00:27:47,050 --> 00:27:53,140 +على جهة في عندي احتمالين الآن مين اللي بده يجاوب + +328 +00:27:53,140 --> 00:27:58,340 +على هذا الكلام التجربة الآن التجربة قالت أنّه + +329 +00:27:58,340 --> 00:28:02,040 +التفاعل stereo selective يعني نفس ال stereo + +330 +00:28:02,040 --> 00:28:06,440 +selectivity اللي بتكون هنا أو نفس ال stereo + +331 +00:28:06,440 --> 00:28:10,480 +chemical arrangement خلينا نقول الشكل اللي فيه ال + +332 +00:28:10,480 --> 00:28:14,800 +R1 و R3 على جهة واحدة في ال reactant طلعوا على جهة + +333 +00:28:14,800 --> 00:28:18,870 +واحدة في ال product فالتفاعل هنا stereo selective هو + +334 +00:28:18,870 --> 00:28:24,510 +ممكن يطلعهم على جهتين متعاكستين أو على جهة واحدة + +335 +00:28:24,510 --> 00:28:29,810 +اختار أنه يطلعهم على جهة واحدة ما غيّر في ال stereo + +336 +00:28:29,810 --> 00:28:35,110 +chemistry واضح الفكرة فالتفاعل ضمن هذا المنطق is + +337 +00:28:35,110 --> 00:28:39,190 +stereo selective طبعاً ممكن الكلام يكون في نفس ال + +338 +00:28:39,190 --> 00:28:42,390 +one three dipole يعني R1 و R3 في ال one three + +339 +00:28:42,390 --> 00:28:46,670 +dipole جايين على جهة واحدة هل يا طرف الناتج بدهم + +340 +00:28:46,670 --> 00:28:50,410 +يكونوا على جهة واحدة ولا بدهم يبدوا ينعكسوا يصيروا + +341 +00:28:50,410 --> 00:28:56,120 +على جهتين واضح؟ الآن في نهاية بدنا التجربة التجربة + +342 +00:28:56,120 --> 00:29:02,000 +بتقول لأ بيضلوا مع بعضهم واحدة بمعنى هذا بشكل عام + +343 +00:29:02,000 --> 00:29:09,500 +بتكونش واضحة الفكرة؟ الآن هذه معلومة بنحطها في + +344 +00:29:09,500 --> 00:29:15,360 +دالنا بحاجة لأن الميكانيزم الجديدة تفسرها هذه + +345 +00:29:15,360 --> 00:29:18,580 +المعلومة بحاجة لأن الميكانيزم اللي احنا بدنا + +346 +00:29:18,580 --> 00:29:21,600 +نقترحها لل one three bipolar cycle addition أن تكون + +347 +00:29:21,600 --> 00:29:27,480 +تفسيرها لأن الميكانيزم تفسير وقائع واضحة الفكرة؟ + +348 +00:29:27,480 --> 00:29:35,700 +الآن لاحظوا كمان أشياء في التجربة العملية من ناحية + +349 +00:29:35,700 --> 00:29:41,040 +ال region selectivity radio selective متعلقة كيف + +350 +00:29:41,040 --> 00:29:45,360 +يتكون الناتج كشكل هندسي أن معظم ال one three + +351 +00:29:45,360 --> 00:29:48,020 +-dipolar cycle addition بنسبة كبيرة radioactive + +352 +00:29:48,020 --> 00:29:52,980 +بعضهم لا صحيح لكن بنسبة كبيرة radioactive إيش + +353 +00:29:52,980 --> 00:29:57,480 +معناه الكلام وهذا الكلام هيتكرر معكم في ال deals + +354 +00:29:57,480 --> 00:30:04,220 +elder reaction تماماً أنه أنا هنا بفعل double bond و + +355 +00:30:04,220 --> 00:30:08,400 +بتعمل الروابط صحيح؟ الآن يا طورة هذه ال double + +356 +00:30:08,400 --> 00:30:14,940 +bond A B لو أنا جبت اثنين اثنين هذه من جهة وهذه + +357 +00:30:14,940 --> 00:30:20,360 +من جهة إيش بيمنع أي واحدة أن تقول A double bond + +358 +00:30:24,420 --> 00:30:29,200 +ماذا يمنعها؟ وحتى على حركة الإلكترونات التي + +359 +00:30:29,200 --> 00:30:32,620 +تعودتم إليها واحد اثنين ثلاثة واحد اثنين ثلاثة + +360 +00:30:32,620 --> 00:30:33,000 +واحد اثنين ثلاثة واحد اثنين ثلاثة واحد اثنين ثلاثة + +361 +00:30:33,000 --> 00:30:33,820 +واحد اثنين ثلاثة واحد اثنين ثلاثة واحد اثنين ثلاثة + +362 +00:30:33,820 --> 00:30:36,660 +واحد اثنين ثلاثة واحد اثنين ثلاثة واحد اثنين ثلاثة + +363 +00:30:36,660 --> 00:30:38,740 +واحد اثنين ثلاثة واحد اثنين ثلاثة واحد اثنين ثلاثة + +364 +00:30:38,740 --> 00:30:44,160 +واحد اثنين ثلاثة واحد اثنين ثلاثة واحد اثنين ثلاثة + +365 +00:30:44,160 --> 00:30:51,220 +واحد اثنين ثلاثة واحد اثنين ثلاثة + +366 +00:30:51,220 --> 00:30:58,740 +واحد اثنين هؤلاء الايزو مارز ستيريو؟ ما اسمهم؟ + +367 +00:30:58,740 --> 00:31:02,320 +إنانشو + +368 +00:31:02,320 --> 00:31:06,280 +مارز إنانشو مارز والدياستيريو مارز هم نوع من + +369 +00:31:06,280 --> 00:31:08,320 +الايزو مارز الاستيريو هؤلاء الايزو مارز + +370 +00:31:08,320 --> 00:31:12,700 +الاستركترال يعني الايزو مارز الاستركترال اللي فيهم + +371 +00:31:12,700 --> 00:31:13,280 +عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة + +372 +00:31:13,280 --> 00:31:15,580 +عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن + +373 +00:31:15,580 --> 00:31:16,620 +عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة + +374 +00:31:16,620 --> 00:31:16,840 +عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن + +375 +00:31:16,840 --> 00:31:23,960 +عبارة عن عبارة عن عبصح ولا لأ هاي ترتيب الذرات A,B + +376 +00:31:23,960 --> 00:31:30,320 +,Z,Y,X الآن B,A,Z,Y,X different arrangement of + +377 +00:31:30,320 --> 00:31:34,320 +atoms ولا لأ إذا هدول معنى ratio isomers they are + +378 +00:31:34,320 --> 00:31:39,740 +structural isomers they are structural isomers + +379 +00:31:39,740 --> 00:31:46,900 +الآن يا ترى بتكون هذا أو هذا في مرات كثيرة التفاعل + +380 +00:31:46,900 --> 00:31:51,840 +بيختار واحداً منهم في نسبة كبيرة التفاعل radio + +381 +00:31:51,840 --> 00:31:55,900 +selective لكن أحياناً بيطلع mixture يعني يمكن يتكون + +382 +00:31:55,900 --> 00:31:59,180 +هذا بنسبة ستين هذا بنسبة أربعين هذا بنسبة سبعين + +383 +00:31:59,180 --> 00:32:06,340 +هذا بنسبة ثلاثين واضح فالجواب أن التفاعل أو most + +384 +00:32:06,340 --> 00:32:09,160 +of the 1,3-dipolar cycload addition are radio + +385 +00:32:09,160 --> 00:32:12,340 +selective and some of them are not selective يعني + +386 +00:32:12,340 --> 00:32:20,800 +they give both products واضحة الفكرة؟ الآن ليش مرات + +387 +00:32:20,800 --> 00:32:25,720 +بيختار ناتج من الناتجين ويطلعه ومرات بيطلعه + +388 +00:32:25,720 --> 00:32:30,040 +mixture of products؟ يوم بدي أحط ميكانيزم، + +389 +00:32:30,040 --> 00:32:36,040 +الميكانيزم بدي تقدر تفسر هذا الكلام الآن في موضوع + +390 +00:32:36,040 --> 00:32:41,240 +الـ mechanism صحيح أنه المتفق عليه بشكل عام بين + +391 +00:32:41,240 --> 00:32:46,440 +العلماء أنه ممكن نفكر باتجاهين ممكن نفكر ب + +392 +00:32:46,440 --> 00:32:51,850 +concerted mechanism يعني one step mechanism أو ب + +393 +00:32:51,850 --> 00:32:55,550 +two step mechanism، ممكن نسميها stepwise mechanism + +394 +00:32:55,550 --> 00:32:59,430 +أو by radical mechanism، هتلاحظوله أسماء كثيرة، + +395 +00:32:59,430 --> 00:33:04,790 +يعني نفكر بالتفاعل على إنه بتتم إما بخطوة واحدة أو + +396 +00:33:04,790 --> 00:33:10,330 +بتتم بإيش؟ بخطوة ثانية الـ Concerted Mechanism عشان + +397 +00:33:10,330 --> 00:33:16,610 +نفهمها جيداً نشوف ال orbitals اللي بده تتفاعل كيف + +398 +00:33:16,610 --> 00:33:20,310 +ال orbitals بده تجرب على بعض وكيف هذه ال orbitals + +399 +00:33:20,310 --> 00:33:24,010 +بده تعمل interactions ماخذين طبعاً بعين الاعتبار + +400 +00:33:24,010 --> 00:33:27,470 +فهمنا السابق لل orbitals وكيف بيكون ال + +401 +00:33:27,470 --> 00:33:32,370 +interaction ما بين ال orbitals of the same Phase + +402 +00:33:32,370 --> 00:33:36,970 +يعني بدنا ننتبه لأن ال phases لحظة ما بده يتم + +403 +00:33:36,970 --> 00:33:40,370 +التفاعل تكون سليمة وبدنا ننتبه أنه عادة اللي + +404 +00:33:40,370 --> 00:33:45,390 +بتفاعل هم من جهة معلومة من جهة ثانية بمعنى واحد + +405 +00:33:45,390 --> 00:33:48,990 +عنده إلكترونات والثاني عنده نقص في الإلكترونات + +406 +00:33:48,990 --> 00:33:54,390 +عشان يكتمل عمل الروابط الآن لو أجينا لل one three + +407 +00:33:54,390 --> 00:33:59,930 +dipole طالما عندي أنا ثلاثة atoms إذا بقدر أرسم كم + +408 +00:33:59,930 --> 00:34:03,830 +orbital ثلاثة molecular orbitals ال molecular + +409 +00:34:03,830 --> 00:34:08,870 +orbitals لو طلعنا عليهم بشكل جيد هلاحظنهم بهذا + +410 +00:34:08,870 --> 00:34:16,950 +الشكل أول orbital ال phases كلها إيش بتكون على جهة + +411 +00:34:18,020 --> 00:34:22,780 +واحدة الآن بعد هيك وبتقدروا تتخيلوا طبعاً إذا + +412 +00:34:22,780 --> 00:34:26,380 +أنتم متذكرين كأنه أنا عندها نموجة وما قطعتش + +413 +00:34:26,380 --> 00:34:33,420 +إطلاقاً من خلال إيش هذه ال orbitals الآن ال orbital + +414 +00:34:33,420 --> 00:34:39,440 +الثاني بهذا الشكل بده يكون ولو تخيلنا أن في عندنا + +415 +00:34:39,440 --> 00:34:41,100 +نموجة كم ند بدها تعمل + +416 +00:34:46,050 --> 00:34:57,350 +ولو جينا على ال orbital الثالث حيكون بهذا الشكل وكام + +417 +00:34:57,350 --> 00:35:03,970 +node حيكون عندنا؟ 10 تل واضح؟ الآن كل + +418 +00:35:03,970 --> 00:35:06,830 +الإلكترونات اللي عندي can buy electron في ال one + +419 +00:35:06,830 --> 00:35:11,090 +three dipole؟ أربعة وبناء على ذلك لو أنا بدأت أحط + +420 +00:35:11,090 --> 00:35:15,510 +اثنين هنا واثنين هنا هذا هيظل فاضي إذا هذا هو ال + +421 +00:35:15,510 --> 00:35:20,860 +HOMO وهذا هو الـ HOMO هي الـ HOMO وهي الـ + +422 +00:35:20,860 --> 00:35:23,720 +Highest Occupied Molecular Orbital و Lowest + +423 +00:35:23,720 --> 00:35:29,220 +Unoccupied Molecular Orbital الآن لو جئنا للـ + +424 +00:35:29,220 --> 00:35:34,680 +Dipolarophile الـ Dipolarophile في بس ذرتين وبناء + +425 +00:35:34,680 --> 00:35:38,460 +على ذلك كم Molecular Orbital هأعمل في؟ اثنين، يا ما + +426 +00:35:38,460 --> 00:35:46,380 +بيكون الـ phases على جهة واحدة أو على جهتين + +427 +00:35:48,080 --> 00:35:52,860 +متعاكستين الآن كل الإلكترونات اثنين هأحطهم هنا إذا + +428 +00:35:52,860 --> 00:35:59,980 +هي الـ HOMO وهي الـ LUMO الآن بعد هيك لما بدي يصير + +429 +00:35:59,980 --> 00:36:06,040 +تفاعل بين هذول الطرفين الأصل مين بتفاعل HOMO مع + +430 +00:36:06,040 --> 00:36:10,860 +LUMO هل يا ترى لو جربنا هذا الـ HOMO مع هذا الـ + +431 +00:36:10,860 --> 00:36:15,380 +LUMO بتفعلوا ولا لا أخر أنا شرط التفاعل الـ phases + +432 +00:36:16,620 --> 00:36:21,940 +تكونوا زي بعض هنا الـ phases متعاكسة وهنا الـ + +433 +00:36:21,940 --> 00:36:26,340 +phases متعاكسة إذا هذا الـ HOMO بنفع يتفاعل مع هذا + +434 +00:36:26,340 --> 00:36:30,460 +الـ HOMO بالتأكيد طب لو جئت للـ HOMO للـ + +435 +00:36:30,460 --> 00:36:36,560 +dipolarophile الـ phases جهة واحدة والـ HOMO هنا + +436 +00:36:36,560 --> 00:36:45,340 +طلعت الأطراف التفاعل على الأطراف الطرفين خضر و + +437 +00:36:45,340 --> 00:36:51,890 +الطرفين أيضًا هذا الـ LUMO وهذا الـ HOMO وهذا الـ + +438 +00:36:51,890 --> 00:36:57,130 +LUMO ممكن يتفاعلوا فالاحتمالين من ناحية الـ phases + +439 +00:36:57,130 --> 00:37:02,710 +سالمين ما فيش فيهم ولا مشكلة التفاعل ممكن يتم بين + +440 +00:37:02,710 --> 00:37:06,450 +الـ HOMO للـ Dipole مع الـ LUMO للـ Dipolarophile + +441 +00:37:06,450 --> 00:37:10,290 +أو الـ LUMO للـ Dipole مع الـ HOMO للـ + +442 +00:37:10,290 --> 00:37:15,230 +Dipolarophile من ناحية الـ phases الأمرين سليمين طيب + +443 +00:37:15,230 --> 00:37:20,090 +لما يكون عندي احتمالين أن هو الاحتمال اللي بيكون + +444 +00:37:20,090 --> 00:37:27,550 +أقرب وبيتم عادة أقل طاقة ممتاز اللي بينهم فرق أقل + +445 +00:37:27,550 --> 00:37:31,330 +في الطاقة وهذا بيعتمد على نوع المادتين هنا لما + +446 +00:37:31,330 --> 00:37:35,130 +أبتدي أجي أطلع هذه الطاقة تبعت هذا وتبعت هذا قداش + +447 +00:37:35,130 --> 00:37:42,410 +الـ difference بينهم قليل هذا أكبر، إذا لو أنا في + +448 +00:37:42,410 --> 00:37:45,970 +هذا المثال تحديدًا بدي أقول أي واحد اللي بده يتم + +449 +00:37:45,970 --> 00:37:54,310 +هذا الأزرق واضح؟ الآن لو افترضنا في مركب ثاني أن + +450 +00:37:54,310 --> 00:37:57,970 +هدول ارتفعوا لفوق أو هدول انخفضوا لتحت أسفل قتهم + +451 +00:37:57,970 --> 00:38:02,150 +ممكن يكون هذا الـ HOMO مع هذا الـ HOMO هما الأقرب إذا أي + +452 +00:38:02,150 --> 00:38:08,420 +اثنين يكونوا أقرب هذه العملية بتحددها طبيعة الـ + +453 +00:38:08,420 --> 00:38:11,740 +Dipole وطبيعة الـ Dipolarophile يعني ما لهاش جواب + +454 +00:38:11,740 --> 00:38:14,580 +محدد يعني ممكن مرة HOMO Dipole مع + +455 +00:38:14,580 --> 00:38:18,360 +HOMO Dipolarophile ومرة ثانية HOMO Dipole مع + +456 +00:38:18,360 --> 00:38:22,160 +LUMO Dipolarophile ليش؟ لأن هذا إله energies + +457 +00:38:22,160 --> 00:38:27,660 +معينة هيجي في مكان ما هنا لما بيكون لتحت بيكون هذا + +458 +00:38:27,660 --> 00:38:33,080 +الاحتمال طب لو هذا ارتفع كثير يعني لو اتخيلته أنه + +459 +00:38:33,080 --> 00:38:37,480 +مركب ثاني وأجه الـ HOMO والـ LUMO تعونوا بهذا + +460 +00:38:37,480 --> 00:38:46,400 +الشكل هاي HOMO وهاي LUMO قارنوا + +461 +00:38:46,400 --> 00:38:53,040 +هتلاحظوا أن هذا الـ HOMO مع هذا الـ LUMO بعيد هذا الـ + +462 +00:38:53,040 --> 00:38:59,140 +HOMO مع هذا الـ LUMO قريب فالفكرة بتعتمد على طبيعة + +463 +00:39:00,120 --> 00:39:04,580 +الـ Dipole والـ Dipolar Phi وين موقعهم بالإنرجي + +464 +00:39:04,580 --> 00:39:09,420 +هذه لا تمثل مشكلة في كل الأحوال الأمرين إيش مالهم + +465 +00:39:09,420 --> 00:39:17,260 +الأمرين من ناحية الـ phases صحيحين الآن أي أن كان + +466 +00:39:17,260 --> 00:39:21,660 +اللي بده يتفاعل لما أجربهم مع بعض هيبدأوا يقتربوا + +467 +00:39:21,660 --> 00:39:28,280 +بهذا الشكل والـ similar phases تيجي على بعض واضح + +468 +00:39:28,280 --> 00:39:35,340 +هنا هتلاحظوا شغلة هتلاحظوا شغلة أنه من هذه المنطقة + +469 +00:39:35,340 --> 00:39:41,660 +هتبدأ مشكلة الـ Regiochemistry بمعنى أنه لو أنا + +470 +00:39:41,660 --> 00:39:46,740 +اتخيلت هذا ثابت لو أنا اتخيلت هذا ثابت زي ما هو في + +471 +00:39:46,740 --> 00:39:51,780 +على أي جهة بتكون فاعله اللي تحت خليني أقول ناخد + +472 +00:39:51,780 --> 00:39:59,250 +هذا الأخضر مع هذا الفاضي آه الآن لو جبت هذا بطريقة + +473 +00:39:59,250 --> 00:40:06,730 +معينة بحيث أن هاي A وهاي B الآن لو جبت A الخضرة + +474 +00:40:06,730 --> 00:40:14,550 +الغامقة حطيتها هنا هيجي الـ B الفاضي معاكس لها ولا + +475 +00:40:14,550 --> 00:40:20,250 +لا؟ هيضبط أنّه تيجي A هنا وB هنا طب لو جبت الـ B + +476 +00:40:20,250 --> 00:40:23,630 +الخضرة + +477 +00:40:23,630 --> 00:40:31,040 +الغامقة حطيتها هنا هتيجي الـ A إذا الاحتمالين + +478 +00:40:31,040 --> 00:40:37,000 +هيضبطوا واضح يعني لو حد ماسك هدول بيقول بدي أجرب + +479 +00:40:37,000 --> 00:40:44,460 +أحط أخطر وفارق لو حط الـ A هنا والـ B هنا زبط معه + +480 +00:40:44,460 --> 00:40:48,060 +ولو حط الـ B هنا والـ A هنا زبط معه إذا في هذه + +481 +00:40:48,060 --> 00:40:52,360 +الحالة الـ two regio isomers in principle كفكرة + +482 +00:40:52,360 --> 00:40:57,870 +عامة are possible الاثنين من ناحية الـ phases ممكن + +483 +00:40:57,870 --> 00:41:02,530 +ينتجوا يعني + +484 +00:41:02,530 --> 00:41:05,890 +لما واحدة تقول بتحط هنا الـ A وهنا الـ B بنقول لها + +485 +00:41:05,890 --> 00:41:10,710 +إيش هي الـ A عليها أخضر غامج والـ B ما عليهاش زبطت + +486 +00:41:10,710 --> 00:41:15,390 +ولا لأ واحدة ثانية بتقول لها أنا بتحط هنا الـ B وهنا + +487 +00:41:15,390 --> 00:41:18,450 +الـ A الـ B برضه ليش؟ لأن كل واحدة عليها + +488 +00:41:21,110 --> 00:41:25,030 +فيز موجب وفيز سالب وبالتالي الاحتمالين من ناحية + +489 +00:41:25,030 --> 00:41:29,570 +المبدأ ممكنين في الـ regiochemistry خلينا شوية من + +490 +00:41:29,570 --> 00:41:33,470 +الـ regiochemistry هدول لما يبدأوا يقتربوا من بعض + +491 +00:41:33,470 --> 00:41:38,370 +لاحظوا أن هذا ما زال Double bond وطالما أن هو + +492 +00:41:38,370 --> 00:41:43,390 +Double bond الدوران حول الـ Double bond مسموح + +493 +00:41:43,390 --> 00:41:48,070 +ولا ممنوع؟ ممنوع وبناء على ذلك لو أنتم أنا كنتوا + +494 +00:41:48,070 --> 00:41:54,470 +متخيلين مثلًا زي ما كتبنا R1 وR3 هذا بدون تفاعل الـ + +495 +00:41:54,470 --> 00:41:59,550 +R1 والـ R3 تبعونه بتغيروا آه الآن بدنا نرجع لسؤال + +496 +00:41:59,550 --> 00:42:03,790 +من الـ Organic القديمة من الـ Organic القديمة هو + +497 +00:42:03,790 --> 00:42:10,050 +الدوران وين كان ممنوع؟ في الـ Double bond وفي الحلقة + +498 +00:42:10,050 --> 00:42:13,670 +ممتاز جدًا يعني الدوران حول الـ Double bond ممنوع + +499 +00:42:13,670 --> 00:42:18,710 +والدوران حول الحلقة ممنوع الآن اللي بيصير بهذه + +500 +00:42:18,710 --> 00:42:23,110 +الحالة لحظة ما أنا بدي أجيب هدول ويجربوا هنا في + +501 +00:42:23,110 --> 00:42:27,890 +عندي Double bond مسموح للمجموعتين يلفوا؟ لا بتظل + +502 +00:42:27,890 --> 00:42:32,010 +تجرب تجرب تجرب لحد ما الـ Orbitals يقتربوا تمامًا + +503 +00:42:32,010 --> 00:42:37,240 +شبكوا الـ Orbitals اتحولت من إيش؟ من Double bond + +504 +00:42:37,240 --> 00:42:43,800 +ممنوع الدوران فيها إلى حلقة ممنوع الدوران فيها إذا + +505 +00:42:43,800 --> 00:42:48,120 +بهيك بتتم الـ Stereochemistry بنقدر نفهم ليش في الـ + +506 +00:42:48,120 --> 00:42:51,180 +Stereochemistry التفاعلات هذه كانت Stereo + +507 +00:42:51,180 --> 00:42:55,840 +selective لأنه أنا حقيقة لما بجرب الـ Orbitals ع + +508 +00:42:55,840 --> 00:43:01,700 +بعض بتحول من Double bond ممنوع الدوران حولها إلى + +509 +00:43:01,700 --> 00:43:08,330 +حلقة أيضًا ممنوع الدوران حولها واضح الفكرة ما مرتش + +510 +00:43:08,330 --> 00:43:13,450 +بلحظة أنه صار عندي Single bond حرة بالإمكان أنه + +511 +00:43:13,450 --> 00:43:20,270 +يتم حولها إيش دوران واضح؟ وهذا الحقيقة اللي .. + +512 +00:43:20,270 --> 00:43:26,750 +اللي بتام كله هو اللي بنسميه احنا Concerted + +513 +00:43:26,750 --> 00:43:31,690 +mechanism يعني جبناهم مع بعض وعملنا الـ cyclic + +514 +00:43:31,690 --> 00:43:37,610 +intermediate وتم التفاعل هذا الميكانيزم اقترح من + +515 +00:43:37,610 --> 00:43:43,550 +العالم هوزجانو عشان ذلك ناس كثير بيقولوا أنا + +516 +00:43:43,550 --> 00:43:47,330 +هوزج الـ mechanism أو الـ Concerted mechanism اللي + +517 +00:43:47,330 --> 00:43:51,190 +هي ببساطة one step mechanism in which two bonds + +518 +00:43:51,190 --> 00:43:56,230 +are formed at the same time ولاحظوا زي ما شفنا + +519 +00:43:56,230 --> 00:44:02,370 +أنه لو أخذنا HOMO Dipole وHOMO Dipolar file من ناحية + +520 +00:44:02,370 --> 00:44:10,440 +الـ phases كله هذا صح هذا صح هذا صح هذا صح كله ممكن + +521 +00:44:10,440 --> 00:44:15,500 +إيش اللي بيحكم الأمر؟ الـ energy difference واضح + +522 +00:44:15,500 --> 00:44:19,140 +اللي بيحكم الأمر الـ energy difference الآن لاحظوا + +523 +00:44:19,140 --> 00:44:22,260 +لو هنا كانت هذه A وهذه B + +524 +00:44:25,780 --> 00:44:30,300 +إذا حد خطهم هيك A وB الـ Orbital صح ولا لأ؟ صح طب + +525 +00:44:30,300 --> 00:44:35,760 +لو حد لفهم برضه صح إذا هذه من ناحية الـ Orbitals + +526 +00:44:35,760 --> 00:44:39,220 +الاحتمالين صح عشان هيك لسه احنا لحد الآن ما + +527 +00:44:39,220 --> 00:44:44,640 +جوابناش على سؤال الـ regiochemistry ولو حد لف + +528 +00:44:44,640 --> 00:44:50,870 +هدول برضه بيضلوا صح ولا لأ؟ بيضلوا صح لما نقلبها لو + +529 +00:44:50,870 --> 00:44:53,790 +افترضنا أن هنا A وهنا B في النهاية عند اثنين + +530 +00:44:53,790 --> 00:44:59,870 +متعاكسات أو لو كتبنا B وA برضه صح برضه صح هيكون + +531 +00:44:59,870 --> 00:45:05,770 +واحد منهم موجب والثاني سالب ضمن هذا الكلام الـ two + +532 +00:45:05,770 --> 00:45:11,290 +regioisomers are still possible يعني بيكون فهمنا + +533 +00:45:11,290 --> 00:45:16,490 +ليش الـ Stereoselectivity لأن أنا كان عندي Double + +534 +00:45:16,490 --> 00:45:23,370 +bond R1 R3 واتحولت إلى حلقة فما صاروش فرصة لإيش + +535 +00:45:23,370 --> 00:45:32,210 +للدوران ولتغيير الـ Stereochemistry واضح؟ + +536 +00:45:32,210 --> 00:45:35,970 +هذا الكلام تقريبًا نفسه موجود هنا بصور أصغر ويوضح + +537 +00:45:35,970 --> 00:45:39,720 +الـ energy difference ما فيش فيه ولا شيء جديد الآن + +538 +00:45:39,720 --> 00:45:45,720 +بنجي لـ ميكانيزم ثاني stepwise ميكانيزم أو by + +539 +00:45:45,720 --> 00:45:50,820 +radical ميكانيزم على أساس أنه فيه إلكترونين أو two + +540 +00:45:50,820 --> 00:45:55,460 +step ميكانيزم وهذه الميكانيزم الحقيقة اقترحت من + +541 +00:45:55,460 --> 00:45:58,460 +العالم Firestone + +542 +00:46:01,650 --> 00:46:07,230 +الميكانيزم ممكن تكون .. الميكانيزم ممكن تكون by + +543 +00:46:07,230 --> 00:46:11,930 +radical mechanism بمعنى أنا بإمكاني أتخيل .. أنا + +544 +00:46:11,930 --> 00:46:15,090 +بإمكاني أتخيل أن هنا في إلكترونات وطبعًا هنا في + +545 +00:46:15,090 --> 00:46:18,950 +أندي إلكترون اثنين ثلاثة أربعة بإمكاني أتخيل أن + +546 +00:46:18,950 --> 00:46:24,590 +هذا وهذا عملوا إيش؟ رابطة طبعًا هدول هيعملوا زوج + +547 +00:46:24,590 --> 00:46:32,250 +إلكترونات يصير فوق إيش؟ الـ Y ظل عندي كم إلكترون؟ + +548 +00:46:32,250 --> 00:46:37,390 +اثنين هدول الإلكترونين بيسكروا في خطوة ثانية + +549 +00:46:37,390 --> 00:46:42,730 +عشان كده احنا قلنا by radical تمام؟ الآن هنا بتجينا + +550 +00:46:42,730 --> 00:46:49,170 +مشكلة أنه إذا أنا صرت عامل رابطة يعني لغيت هذه الـ + +551 +00:46:49,170 --> 00:46:55,430 +pi bond هنا أنا بقول أن الـ rotation ممنوع هذه + +552 +00:46:55,430 --> 00:47:01,170 +صارت Single صار عندي possible rotation طالما هذه + +553 +00:47:01,170 --> 00:47:05,130 +صارت Single معناه ذلك صار عندي possible rotation + +554 +00:47:05,130 --> 00:47:08,310 +طالما هذا الـ rotation possible إذا الـ R اللي + +555 +00:47:08,310 --> 00:47:11,730 +اثنتين كانوا لقدام ممكن واحدة منهم تصير للخلف + +556 +00:47:11,730 --> 00:47:17,130 +والثانية للأمام وارد طب وبيضلوا يلفوا بمعنى أنه + +557 +00:47:17,130 --> 00:47:20,630 +طالما هي عندي مجموعتين كانوا مربوطات بالـ Double + +558 +00:47:20,630 --> 00:47:24,550 +bond على جهة واحدة هي المجموعتين مربوطات بالـ Double + +559 +00:47:24,550 --> 00:47:29,080 +bond على جهة واحدة صارت الـ Double Single صار دوران + +560 +00:47:29,080 --> 00:47:33,060 +دائم وأبدي حول الـ Single point ممكن في لحظة من + +561 +00:47:33,060 --> 00:47:36,160 +اللحظات تكونوا على جهة و باللحظة على الجهة + +562 +00:47:36,160 --> 00:47:43,910 +المعاكسة الآن إذا هذا كمل التسكيروهم على نفس الجهة + +563 +00:47:43,910 --> 00:47:48,130 +بيعطينا retention of configuration وإذا كملت + +564 +00:47:48,130 --> 00:47:52,050 +تسكيرهم على جهتين متعاكستين بيعطينا inversion of + +565 +00:47:52,050 --> 00:47:56,930 +configuration إذا هنا كام stereo isomers are ممكن + +566 +00:47:56,930 --> 00:48:03,250 +عنده من ناحية المبدأ؟ اتنين طبعًا ممكن الناس في + +567 +00:48:03,250 --> 00:48:10,270 +بداية التفكير يفكروا بالشكل القاتل يقولوا التجربة + +568 +00:48:10,270 --> 00:48:16,090 +شو بتقول؟ أنه بيطلع واحد و ال stereo selective okay + +569 +00:48:16,090 --> 00:48:20,950 +طيب شو حكى السن تجه؟ أنّه ميكانيزم مش صحيحة آه + +570 +00:48:20,950 --> 00:48:27,650 +الآن لاحظوا مباشرة ازملتكم .. شو اسمك؟ سهل آه سهل + +571 +00:48:27,650 --> 00:48:32,110 +كحلوت بتقول والله أنّه ال mechanism مش صحيحة بس + +572 +00:48:32,110 --> 00:48:36,790 +انتبهوا لنقطة دائمًا انتبهوا لنقطة دائمًا واتعلموها + +573 +00:48:36,790 --> 00:48:39,350 +للحياة يوم ما ييجي + +574 +00:48:43,020 --> 00:48:51,100 +أقول فتوى مثلًا نقدر بسهولة نقول أن الفتوى مش صحيحة + +575 +00:48:51,100 --> 00:48:56,560 +لأنه ليس من أهل الفتوى وليس من أهل العلم لكن يوم + +576 +00:48:56,560 --> 00:49:02,430 +ما ييجي عالم كبير قاعد ودارس ال mechanisms وفهمان + +577 +00:49:02,430 --> 00:49:06,430 +و ماخد دكتوراه وبيخرج طلاب دكتوراه ويقترح + +578 +00:49:06,430 --> 00:49:11,650 +mechanisms بهذا الشكل طب هو يعني هلجيت هذه الشغلة + +579 +00:49:11,650 --> 00:49:18,510 +دارت إلك وما دارتش إله انتبهوا + +580 +00:49:18,510 --> 00:49:24,950 +معي صحيحة ولا لأ تمامًا زي لما بيجي المفتي بيحكي + +581 +00:49:24,950 --> 00:49:33,740 +فتوى كان إنسان بيجيبله طرف حديثه مباشرة بيبدأ يغلط + +582 +00:49:33,740 --> 00:49:37,240 +في مين؟ في المفتي الفهمان أو في العالم الكبير طب و + +583 +00:49:37,240 --> 00:49:41,040 +أنت إذا عرف الطرف الحديث المفروض المفتي أو العالم + +584 +00:49:41,040 --> 00:49:44,080 +الكبير عرف كل الأحاديث وكل الآيات وكل قواعد + +585 +00:49:44,080 --> 00:49:47,540 +الفقه والقياس والإجماع وما إلى ذلك وطلع منهم + +586 +00:49:47,540 --> 00:49:53,190 +فتوى واضح ولا لا؟ يعني هالشغلة أنت أنتبهتي لإنه + +587 +00:49:53,190 --> 00:49:56,550 +بيطلع ناتجين هو ما انتبهلهاش Firestone .. + +588 +00:49:56,550 --> 00:50:01,110 +Firestone عالم physical وعالم كبير بنقوله طيب إذا + +589 +00:50:01,110 --> 00:50:07,050 +أنت المطلوب منك تفسر لي التجربة .. التجربة بتقول + +590 +00:50:07,050 --> 00:50:13,470 +أنه بيطلع فقط هذا الناتج الميكانيزم تبعتك بهذا + +591 +00:50:13,470 --> 00:50:18,130 +الشكل بتطلع ناتجين معقول أنّه يحط ميكانيزم تناقض + +592 +00:50:18,130 --> 00:50:23,590 +التجربة ويقول هي ميكانيزم؟ واضح؟ هذا زي شرطة في + +593 +00:50:23,590 --> 00:50:27,830 +عنده قتيل واحد في الجريمة بيحط ميكانيزم وبيقول أن + +594 +00:50:27,830 --> 00:50:35,720 +قتله خمسة هو الواحد بيحط آلية تناقض التجربة طيب + +595 +00:50:35,720 --> 00:50:40,260 +إذا اللي بيصير .. إيش التفسير يا سيد؟ Firestone + +596 +00:50:40,260 --> 00:50:44,180 +عشان نحترم العالم وما نقولش عنه أنه بغلط + +597 +00:50:44,180 --> 00:50:48,480 +Firestone كان في عنده تفسير أنه بيطلع بس هذا + +598 +00:50:48,480 --> 00:50:52,640 +التفسير اللي عنده من خلال حسابات فيزيائية هو + +599 +00:50:52,640 --> 00:50:58,160 +بيشتغل عليها بيقول أول ما اتكون ال by radical هذا + +600 +00:50:58,160 --> 00:51:05,150 +شايفينه؟ عنده أحد احتمالين أما أنّه يعمل cyclization + +601 +00:51:05,150 --> 00:51:18,270 +صح يسكر أو أنّه يعمل rotation وبعد + +602 +00:51:18,270 --> 00:51:21,410 +ال rotation cyclization + +603 +00:51:32,020 --> 00:51:34,880 +جداش الساعة نص واحدة ونص + +604 +00:52:17,610 --> 00:52:25,390 +والله ثقة مفقودة هالهم أسبوع بيقولوا نظام ثمانية + +605 +00:52:36,860 --> 00:52:42,280 +يقولون ليبعت السلامة بالرد فقلت أنا والله ما نالني + +606 +00:52:42,280 --> 00:52:47,120 +خسر وهل يتجافى عني الموت ساعة إذا مات جافى عني + +607 +00:52:47,120 --> 00:52:53,850 +الأسر والضر يقولون main بالعراقي مريضة فقلت ايه + +608 +00:52:53,850 --> 00:52:58,950 +ليتني كنت الطبيب المداوية يقولون ليلة بالعراقي + +609 +00:52:58,950 --> 00:53:07,530 +ليلة بالعراقي مريضة يقولون ومن + +610 +00:53:07,530 --> 00:53:16,150 +أصعب القول الاستعانة على المعصية بمشيئة الله وقالوا + +611 +00:53:16,150 --> 00:53:20,410 +لو شاء الرحمن وما عبدناهم يعني إحنا ربنا رايدنا + +612 +00:53:20,410 --> 00:53:27,990 +نعبد الأصنام شوفوا كيف فالقول سهل يعني بنقول البني + +613 +00:53:27,990 --> 00:53:31,910 +آدم ماتدخنش بيقول إذا ربنا رايد مانديش أدخن بيقول + +614 +00:53:34,960 --> 00:53:40,500 +خلّينا نوضّح المشكلة الأساسية في ال mechanisms of + +615 +00:53:40,500 --> 00:53:45,080 +the reaction كانت مشكلة ال stereochemistry وكان + +616 +00:53:45,080 --> 00:53:48,720 +واضح عندنا أنّه في ال mechanism أو ال concerted + +617 +00:53:48,720 --> 00:53:53,340 +mechanism فسرنا ال retention of stereochemistry من + +618 +00:53:53,340 --> 00:53:56,860 +خلال أننا انتقلنا من double bond ممنوع الدوران + +619 +00:53:56,860 --> 00:54:01,650 +فيها إلى حلقة ممنوع الدوران فيها الآن لما نفكر بال + +620 +00:54:01,650 --> 00:54:05,690 +by radical mechanism مجرد ما صارت هذه single bond + +621 +00:54:05,690 --> 00:54:08,950 +صار في عندي possible rotation معناه ذلك هدول + +622 +00:54:08,950 --> 00:54:12,670 +المجموعات ممكن يتغيروا من جهة واحدة لجهتين لو + +623 +00:54:12,670 --> 00:54:16,030 +كملنا ال cyclization كام ناتج متوقع عندنا اتنين + +624 +00:54:16,030 --> 00:54:22,830 +طبعًا Firestone بفكر بهذا الكلام أنّه أنا أول ما صار + +625 +00:54:22,830 --> 00:54:26,090 +عندي هذه الرابطة و by radical هذا ال by radical + +626 +00:54:26,090 --> 00:54:30,450 +ممكن يعمل cyclization بهذا الشكل وممكن يعمل + +627 +00:54:30,450 --> 00:54:34,770 +rotation followed by cyclization الآن بالحسابات + +628 +00:54:34,770 --> 00:54:39,370 +اللي كان بيعملها Firestone بيقول أن الزمن اللي + +629 +00:54:39,370 --> 00:54:45,590 +لازم لل cyclization أقل كثير من الزمن اللي لازم + +630 +00:54:45,590 --> 00:54:51,510 +لل rotation ولذلك هو بيقول أنّه بالحسابات تبعته هذا + +631 +00:54:51,510 --> 00:54:56,010 +بيسكر قبل ما يلوف إذا كان بيسكر قبل ما يلوف لغ هذا + +632 +00:54:56,010 --> 00:55:02,050 +الاحتمال إذا طلع الناتج حط تفسير واضح الفكرة + +633 +00:55:02,050 --> 00:55:06,950 +فطالما أن هو بيقول قبل ما يلحق يلوف بيكون قبل + +634 +00:55:06,950 --> 00:55:13,120 +cyclization إذا هدول المجمعتين اتغيروا ولا اظلهم + +635 +00:55:13,120 --> 00:55:19,180 +على جهة واحدة؟ شوفنا إيش تفسير Firestone ل retention + +636 +00:55:19,180 --> 00:55:23,600 +of configuration أن هو بيقول بالظبط تحديدا أن the + +637 +00:55:23,600 --> 00:55:30,040 +compound cyclizes before it rotates تمام؟ بناء على + +638 +00:55:30,040 --> 00:55:34,900 +حسابات معينة الآن بنضل أنّه هذه محاولة تفسير وهذه + +639 +00:55:34,900 --> 00:55:39,100 +محاولة تفسير إيش اللي مقبول أكثر؟ آه بدل ما ننسى + +640 +00:55:39,100 --> 00:55:43,620 +اليوم صار في أجهزة كثير بتجسس ال free radicals إذا + +641 +00:55:43,620 --> 00:55:48,700 +اتكونوا اللي هو تحديدا جهاز إيش ال ESR ال + +642 +00:55:48,700 --> 00:55:54,540 +electron spin resonance هاليوم في فعلًا بنشوف + +643 +00:55:54,540 --> 00:55:58,240 +free radicals بال 1,3-dipolar cycloaddition + +644 +00:55:58,240 --> 00:56:05,500 +reactions الواقع أنّه كل تفاعل حقيقة بحاجة إلى أن + +645 +00:56:05,500 --> 00:56:12,010 +يدرس بشكل منفصل يعني فكرة أنّه نتخيل أنّه نقول هذه ال + +646 +00:56:12,010 --> 00:56:16,290 +mechanism عامة تصلح لكل ال one three bipolar cycle + +647 +00:56:16,290 --> 00:56:20,730 +addition reactions يعني فكرة غير سليمة من ناحية + +648 +00:56:20,730 --> 00:56:27,370 +بحتها ولذلك كل التفاعل يجب أن يدرس ويفهم هل يا ترى + +649 +00:56:27,370 --> 00:56:30,550 +أنا شوفت فيه free radicals ولا ماشوفتش فيه free + +650 +00:56:30,550 --> 00:56:37,190 +radicals اليوم بنقدر نقول القاتل من مجمل من مجمل ما + +651 +00:56:37,190 --> 00:56:43,370 +تم دراسته بتفاصيل من تفاعلات ربما أنّه فعلاً ما يزيد + +652 +00:56:43,370 --> 00:56:49,390 +عن 95% من ال 1,3-dipolar cycle addition reactions + +653 +00:56:49,390 --> 00:56:53,590 +اللي دورست ثبت أنّه مشيت ب concerted mechanism لكن + +654 +00:56:53,590 --> 00:56:58,390 +في أمثلة فعلًا شافوا فيها ال free radical mechanisms + +655 +00:56:58,390 --> 00:57:04,790 +ومشيت بال free radicals واضح؟ طبعًا بكل الأحوال هذا + +656 +00:57:04,790 --> 00:57:08,430 +الكلام أن أنا قاعد بشوف stereo chemistry وقاعد + +657 +00:57:08,430 --> 00:57:12,350 +بشوف جهاز ESR وقاعد بشوف free radical كل هذا + +658 +00:57:12,350 --> 00:57:17,690 +الكلام ما بمشيش مع الفكرة البسيطة بتاعت سنتين فكرة + +659 +00:57:17,690 --> 00:57:22,210 +أكمل المعادلة أن ال mechanism of the reaction أنّه + +660 +00:57:22,210 --> 00:57:27,690 +سهم اتنين تلاتة هذا الكلام غير مقبول إطلاقًا من + +661 +00:57:27,690 --> 00:57:31,350 +طالب سنة رابعة أنّه يقول أنّه this is a mechanism of + +662 +00:57:31,350 --> 00:57:36,090 +deal الكلام نفسه بالظبط وعشانك مش هنشرحه مرة ثانية + +663 +00:57:36,090 --> 00:57:39,630 +في Diels-Alder reaction بمعنى في Diels-Alder + +664 +00:57:39,630 --> 00:57:49,430 +reaction هنرسم orbitals ونشوف أن هدولة ممكن يعملوا + +665 +00:57:50,240 --> 00:57:55,120 +ال concerted mechanism هذا احتمال والاحتمال + +666 +00:57:55,120 --> 00:57:59,740 +الثاني أنّه إحنا هاي ال system هذا وهاي هذا لأن + +667 +00:57:59,740 --> 00:58:03,740 +هاي free radical هان و free radical هان هذه صارت + +668 +00:58:03,740 --> 00:58:09,080 +رابطة وهنا صارت الرابطة التاني ضايل التالتة تنعمل + +669 +00:58:09,080 --> 00:58:15,740 +وبالتالي ممكن هذا وهذا يسكروا مع بعض ويكون عندي + +670 +00:58:15,740 --> 00:58:19,580 +free radical طبعًا نفس ال issue ال Diels-Alder + +671 +00:58:19,580 --> 00:58:23,200 +reaction درس كل تفاعل بتفاعله اللي بده يحكي عن + +672 +00:58:23,200 --> 00:58:26,220 +تفاعل ميكانيزم بده يدخله على التجربة ويقعد في + +673 +00:58:26,220 --> 00:58:32,830 +المختبر تمام؟ النتيجة أن ال Diels-Alder reaction + +674 +00:58:32,830 --> 00:58:38,930 +مرات بيمشي ب concerted mechanism ومرات بيمشي ب + +675 +00:58:38,930 --> 00:58:43,410 +free radical mechanism يعني ما فيش جواب لكل ال + +676 +00:58:43,410 --> 00:58:47,330 +Diels-Alder reaction اللي في الكون أنهم concerted + +677 +00:58:47,330 --> 00:58:50,150 +mechanism ولا كل ال Diels-Alder reaction اللي في + +678 +00:58:50,150 --> 00:58:54,030 +ال cones أنهم by radical mechanism بعض التفاعلات + +679 +00:58:54,030 --> 00:58:58,070 +فعلاً بتمشي زي هيك وبعضها بتمشي ب concerted + +680 +00:58:58,070 --> 00:59:01,870 +mechanism فبيصير الحقيقة أن كل تفاعل بحاجة إلى + +681 +00:59:01,870 --> 00:59:07,010 +دراسة إيش تفصيلية لكن نسبة ال free radical + +682 +00:59:07,010 --> 00:59:11,070 +mechanism في ال Diels-Alder reaction أكثر كثير + +683 +00:59:11,070 --> 00:59:15,960 +منها في ال 1,3-dipolar cycloadditions ولذلك لو + +684 +00:59:15,960 --> 00:59:20,240 +كانوا ناس بيحكوا بمنطق العمومية فبتلاقوه بمنطق + +685 +00:59:20,240 --> 00:59:23,520 +العمومية بيقولوا most of the 1,3-dipolar + +686 +00:59:23,520 --> 00:59:26,960 +cycloadditions reactions proceed by a concerted + +687 +00:59:26,960 --> 00:59:30,600 +mechanism معظمها بتمشي ب concerted mechanism في ال + +688 +00:59:30,600 --> 00:59:36,580 +Diels-Alder أقل في نسبة لبأس بها فعلاً مثبتة + +689 +00:59:36,580 --> 00:59:43,170 +وموجودة وبتمشي بإيش؟ بي راديكال ميكانيزم الآن ال + +690 +00:59:43,170 --> 00:59:47,590 +homework اللي أنا بدي إياك تتعبوا فيه حقيقة أنّه من + +691 +00:59:47,590 --> 00:59:53,570 +الأشياء اللي اتدرست اجيب لي مثال على ال one three + +692 +00:59:53,570 --> 00:59:57,980 +dipolar cycloaddition أو على ال Diels-Alder + +693 +00:59:57,980 --> 01:00:03,800 +reaction مشي ب by radical mechanism يعني شخص بيعمل + +694 +01:00:03,800 --> 01:00:08,360 +mechanistic study ودرس وبيقول هي ال ESR وهي شفت + +695 +01:00:08,360 --> 01:00:13,860 +ال free radicals وما إلى ذلك وتجيبولنا وتشوفوا + +696 +01:00:13,860 --> 01:00:18,110 +كيف ال mechanistic study هي في نهاية علم كامل + +697 +01:00:18,110 --> 01:00:22,710 +متكامل بدنا مثال على one three dipolar + +698 +01:00:22,710 --> 01:00:27,150 +cycloaddition reaction أو Diels-Alder reaction مش + +699 +01:00:27,150 --> 01:00:33,110 +باشي بال by radical mechanism أو stepwise mechanism + +700 +01:00:33,110 --> 01:00:39,250 +كل الكلام هذا اللي إحنا جوابناه بتعلق بأي نقطة + +701 +01:00:39,250 --> 01:00:45,850 +نقطة ال stereo selectivity لسه ماحكينااش عن الراديو + +702 +01:00:45,850 --> 01:00:48,990 +سيلكتيفتي لسه ماحكينااش عن ال radio selectivity + +703 +01:00:48,990 --> 01:00:56,410 +الآن في ال radio selectivity ال orbitals لما بنيجي + +704 +01:00:56,410 --> 01:01:00,230 +بنعملها وطبعا هذا الكلام الآن أكتر شيء بنعمل + +705 +01:01:00,230 --> 01:01:02,850 +حسابيا يعني على ال computer اللي بيديه يعمل + +706 +01:01:02,850 --> 01:01:06,210 +molecular orbitals إذا بديتوا تأخذوا في ال quantum + +707 +01:01:06,210 --> 01:01:11,190 +برامج الكمبيوتر مجرد ما الإنسان يرسم الشكل بيقدر + +708 +01:01:11,190 --> 01:01:16,650 +يحسب ال .. إيش ال .. ال orbital energies وقد إيش ال + +709 +01:01:16,650 --> 01:01:22,710 +size بيكون لكل orbital تمام؟ الآن في عندي قاعدة + +710 +01:01:22,710 --> 01:01:29,110 +بتقول قاعدة عامة في الكيمياء وعامة في الحياة + +711 +01:01:29,110 --> 01:01:37,510 +العامة في الحياة إيش بتقول؟ الكبار بيلعبوا مع الكبار + +712 +01:01:37,510 --> 01:01:47,410 +والصغار بيلعبوا مع الصغار الغنية كتير بيقعدوا مع بعض + +713 +01:01:47,410 --> 01:01:53,550 +والفقرة كتير بيقعدوا مع بعض، مظبوط ولا لأ؟ طبعا مين + +714 +01:01:53,550 --> 01:02:00,880 +أسعد أكثر؟ انتبهوا معي مين أسعد أكثر الغنية كتير + +715 +01:02:00,880 --> 01:02:05,600 +لما بيقعدوا مع بعض ولا الفقرة كتير لما بيقعدوا مع + +716 +01:02:05,600 --> 01:02:11,960 +بعض الله أعلم كل واحد له وجهة نظر في الموضوع يعني + +717 +01:02:11,960 --> 01:02:18,460 +أنا بأذكر أن سمعت لأحد الناس اللي كانوا يعني مدراء + +718 +01:02:18,460 --> 01:02:24,140 +أعمال أو مرافقين للفنان الكبير بزمانه عبد الحليم + +719 +01:02:24,140 --> 01:02:30,630 +حافظ بتعرفوا كيف لما كان اسم كبير ومشهور وحفلة وكل + +720 +01:02:30,630 --> 01:02:35,870 +علية القوم قاعدين بيسمعوله رجال ونسوان هو الآن محط + +721 +01:02:35,870 --> 01:02:42,870 +الأنظار كلها فبنهاية حفلة الساعة تنتين تلاتة مروح + +722 +01:02:42,870 --> 01:02:47,610 +معاه بالسيارة مر ببساطة على اثنين عمال نظافة + +723 +01:02:47,610 --> 01:02:52,290 +بسيطين جدا تعبوا من الشغل بنظفوا بالليل وبالنهار + +724 +01:02:52,290 --> 01:02:57,790 +هناك فقعدوا هيك جانب حيطة وحطوا زيتون مع شوية خبز + +725 +01:02:57,790 --> 01:03:02,650 +وقاعدين بيأكلوا وبينبسطوا فجاله واجف نزل عندهم + +726 +01:03:02,650 --> 01:03:07,170 +صار يتطلع فيهم ويبكي قالوا أنا نفسي أكون زي هدول + +727 +01:03:09,030 --> 01:03:13,410 +مرات كتير حتى الحاكم الكبير اللي بيقعد اللي مع + +728 +01:03:13,410 --> 01:03:18,590 +حاكم كبير ومعظم جلسات الحكام جلسات ليست لخير الدين + +729 +01:03:18,590 --> 01:03:24,070 +ولا الدنيا بشكل عام بيتمنوا إنهم يكونوا يعيشوا + +730 +01:03:24,070 --> 01:03:28,730 +الحياة البسيطة اللي بعيشوها الناس الأناد القاعدة + +731 +01:03:28,730 --> 01:03:35,690 +العامة بالحياة حكيناها بالمثل بيصيغوها الطيور على + +732 +01:03:35,690 --> 01:03:44,470 +أشكالها بتقعوا، مظبوط ولا لأ؟ ب solubility بنصيغها؟ + +733 +01:03:44,470 --> 01:03:52,150 +ب like dissolves؟ بالكيمياء بنصيغها؟ soft soft، + +734 +01:03:52,150 --> 01:03:56,650 +hard hard؟ يعني هي ليست قاعدة كيمياء، بقدر ما هي + +735 +01:03:56,650 --> 01:04:06,010 +قاعدة إيش؟ حياة خلّي الكبار مع بعض والصغار مع بعض حتى + +736 +01:04:06,010 --> 01:04:10,070 +اللي بشتغلوا كمان يلحموا مواسير ساكل عليهم يلحموا + +737 +01:04:10,070 --> 01:04:13,770 +مصورتين كبار وال steel تبعهم عريض مع بعض بسهولة + +738 +01:04:13,770 --> 01:04:18,010 +لكن أصعب شغلة عنده لو كان بده في مصورة كبيرة يلحم + +739 +01:04:18,010 --> 01:04:21,690 +مصورة صغيرة أول ما يحط النار المصورة الصغيرة بتسيح + +740 +01:04:21,690 --> 01:04:25,450 +والكبيرة لسه ما سخنتش وبيصير هذا علم بحد ذاته + +741 +01:04:26,150 --> 01:04:31,810 +في النهاية الأشياء مع إيش متشابهتها وحتى الأخلاق + +742 +01:04:31,810 --> 01:04:37,390 +يوم إذا بعضهم لبعض نقضون المرء على دينه خليله اه + +743 +01:04:37,390 --> 01:04:43,500 +اليوم لو أنتو بتيجوا تتطلعوا هاي هذاهدول شكل + +744 +01:04:43,500 --> 01:04:49,920 +orbitals طلع هذا كبير وهذا إيش صغير الآن لما أنا + +745 +01:04:49,920 --> 01:04:54,400 +بدي آجي أحط هدول يا تورا لو حطيتهم بهذا الشكل خليت + +746 +01:04:54,400 --> 01:04:59,160 +الكبير هنا والصغير هنا لاحظوا ما ال carbon هذا + +747 +01:04:59,160 --> 01:05:03,980 +اللي حامله ال methyl وال co2 methyl اتصلت وين بال + +748 +01:05:03,980 --> 01:05:09,480 +nitrogen صح ولا لأ طيب من ناحية ال phases بقدر + +749 +01:05:09,480 --> 01:05:15,670 +أعمل العكس من ناحية ال phases يعني أن أحط زي هيك + +750 +01:05:15,670 --> 01:05:21,290 +أرسم هنا ال phase الصغير وأرسم هنا الكبير وأخلي + +751 +01:05:21,290 --> 01:05:28,870 +هذا خلوه ثابت زي ما هو أخلي هذه بهذا الشكل وهذه + +752 +01:05:28,870 --> 01:05:32,330 +بهذا + +753 +01:05:32,330 --> 01:05:38,750 +الشكل وأحط هنا المجمعتين المثل وال CO2 مثل الآن + +754 +01:05:38,750 --> 01:05:44,010 +هذا هو نفس هذا ولا لنفسه تماما ال phases معكوسة + +755 +01:05:44,010 --> 01:05:49,750 +طيب الآن لما آجي أقول هدولة هيك بتحدوا مع بعض و + +756 +01:05:49,750 --> 01:05:55,030 +بيكونوله مركب هذه ال carbon فيه متصلة وين بال + +757 +01:05:55,030 --> 01:06:01,990 +نيتروجين طيب و هدولة من ناحية ال phases هاي + +758 +01:06:01,990 --> 01:06:07,590 +ال carbon هادي بتحدوا تطلعول ال phases سالمين ولا + +759 +01:06:07,590 --> 01:06:14,040 +لأ من ناحية ال phases الاحتمالين موجودين وبناء على + +760 +01:06:14,040 --> 01:06:20,920 +ذلك الناتجين متوقعين لكن من ناحية ال hard hard وال + +761 +01:06:20,920 --> 01:06:25,320 +soft soft أو اللي ممكن نصيغه orbitals of the + +762 +01:06:25,320 --> 01:06:29,960 +same size interact أي الاحتمالات المفضلة؟ هذا + +763 +01:06:29,960 --> 01:06:35,620 +الاحتمال ليش؟ لأن هدولة الصغار أتوا مع بعض والكبار + +764 +01:06:35,620 --> 01:06:40,420 +أتوا مع بعض واضح؟ فصح من ناحية similarity of the + +765 +01:06:40,420 --> 01:06:45,760 +phases اثنين ممكنين بس من ناحية ال orbital size + +766 +01:06:45,760 --> 01:06:50,540 +فيهم واحد مفضل على الثاني وبناء على ذلك بهذا + +767 +01:06:50,540 --> 01:06:54,420 +التفاعل اللي متوقع فيه ناتجين هاي هذه ال carbon + +768 +01:06:54,420 --> 01:06:58,280 +اللي أنا رسمتها بالأحمر وهيها أنا رسمتها بالأحمر + +769 +01:06:58,280 --> 01:07:02,480 +مرة متصلة بال nitrogen ومرة متصلة بال carbon ال + +770 +01:07:02,480 --> 01:07:06,820 +orbitals بيقولوا أي المركبات اللي بدأوا يطلع + +771 +01:07:10,540 --> 01:07:13,900 +ال orbital size إذا اللي حكى من إيش ال + +772 +01:07:13,900 --> 01:07:19,280 +radiochemistry الآن هيجي البعض يقول طب أنت قلت ال + +773 +01:07:19,280 --> 01:07:22,940 +radiochemistry أحيانا مرات كتيرة اتفعوا radio + +774 +01:07:22,940 --> 01:07:29,720 +selective أحيانا لأ بيطلع خليط إذا ال orbitals + +775 +01:07:29,720 --> 01:07:35,300 +كانت تقريبا نفس الحجم + +776 +01:07:38,770 --> 01:07:42,570 +هييطلع خليط، بطل يفرق عندك، يعني وقت إيش بيصير + +777 +01:07:42,570 --> 01:07:46,350 +الفرق أو بتصير الانتقائية أو بتصير ال region + +778 +01:07:46,350 --> 01:07:51,070 +selectivity لما يكون كل مكان عندك difference كبير + +779 +01:07:51,070 --> 01:07:56,690 +في ال orbital size هان وهان واضح الفكرة؟ لما يكون + +780 +01:07:56,690 --> 01:08:00,970 +في عندي أنا كبير وصغير وأنا كبير وصغير وجدت في + +781 +01:08:00,970 --> 01:08:05,910 +الصين عندي نسبة ال ratio selectivity عالية لكن لو + +782 +01:08:05,910 --> 01:08:11,650 +ماكانش الأمر كذلك ممكن إنه يطلع عندكم إيش خلاص لو + +783 +01:08:11,650 --> 01:08:17,190 +أنتوا بتحسبوا جيدا على البرامج الحسوبية هنلاحظ بعد + +784 +01:08:17,190 --> 01:08:22,810 +شوية لما نستعرض الأمثلة إنه مرات بيكتب one ratio + +785 +01:08:22,810 --> 01:08:27,350 +isomer ومرات بيكتب خليط من الاثنين وبحط النسبة + +786 +01:08:27,350 --> 01:08:32,970 +المئوية بإمكانك وجدها أي مثال منهم تأخذوا وتدخلوا + +787 +01:08:32,970 --> 01:08:37,530 +على الكمبيوتر وتشوفوا كيف شكل ال orbitals ليش مرة + +788 +01:08:37,530 --> 01:08:42,700 +طبعا النتائج اللي هنعرضها هي نتائج تجريبية نتائج + +789 +01:08:42,700 --> 01:08:47,180 +إيش؟ تجارب ليش مرة بيقول طلع بس هذا ومرة طلعوا + +790 +01:08:47,180 --> 01:08:52,500 +الاثنين؟ هو يعكس التجربة ما تفسير التجربة أكيد إنه + +791 +01:08:52,500 --> 01:08:57,840 +في أحوال ال orbital size فيها مختلفة وبناء على ذلك + +792 +01:08:57,840 --> 01:09:04,000 +لما بنيجي .. بنعمل التفاعل بيكون شكله أفضل من الشكل + +793 +01:09:04,000 --> 01:09:09,260 +الثاني واضحة الفكرة؟ هذا بالنسبة لإيش؟ لـ Radio + +794 +01:09:09,260 --> 01:09:14,060 +Selectivity ليش مرات بتنوجد مرات بتنوجدش بتنوجد + +795 +01:09:14,060 --> 01:09:18,300 +لما يكون عند ال orbital size مختلف في ال dipole وال + +796 +01:09:18,300 --> 01:09:21,140 +dipolarophile واجدها الكبير بيروح مع الكبير + +797 +01:09:21,140 --> 01:09:26,920 +الصغير مع الصغير بتكون ناتج واحد لكن لو كان ال + +798 +01:09:26,920 --> 01:09:32,420 +orbital size نوعا ما متشابه هيُتكون mixture of + +799 +01:09:32,420 --> 01:09:33,420 +products + +800 +01:09:36,710 --> 01:09:41,650 +بهيك تقريبا بنكون خلصنا موضوع ال mechanism of 1,3 + +801 +01:09:41,650 --> 01:09:44,610 +-dipolar cycloaddition وشوفنا كيف ال mechanisms + +802 +01:09:44,610 --> 01:09:49,230 +بتجاوب على فكرة ال stereo selectivity وال radio + +803 +01:09:49,230 --> 01:09:53,150 +selectivity الآن لو أجينا على ال 1,3-dipoles أنا + +804 +01:09:53,150 --> 01:09:57,750 +قلتلكوا أشهر ال 1,3-dipoles ال nitrile oxides + +805 +01:09:57,750 --> 01:10:03,070 +الآن ال nitrile oxides في الغالب بنعمللها إيش اسمه + +806 +01:10:03,070 --> 01:10:06,950 +generation يعني ما بتكونش موجودة ع شكل nitrile + +807 +01:10:06,950 --> 01:10:12,150 +oxide لأ أنا ب .. بيكون عندي precursor مرت عليكم + +808 +01:10:12,150 --> 01:10:16,370 +كلمة precursor يعني مادة بطول منها ال nitrile + +809 +01:10:16,370 --> 01:10:18,170 +oxide بريه + +810 +01:10:20,660 --> 01:10:26,440 +هذا ال precursor بحضره أثناء التفاعل بعمل + +811 +01:10:26,440 --> 01:10:29,260 +generation of nitrile oxide مجرد ما عملت له + +812 +01:10:29,260 --> 01:10:33,820 +generation reactive بتفاعل بلاقي ال double bond + +813 +01:10:33,820 --> 01:10:37,600 +المناسبة بتفاعل ما لاقاش double bond المناسبة إيش؟ + +814 +01:10:38,540 --> 01:10:42,620 +بتفعل مع نفسه بعمل diaper مع نفسه يعني الـ Nitrile + +815 +01:10:42,620 --> 01:10:47,100 +Oxide الـ Nitrile Oxide إذا صرنا عاملين له ال + +816 +01:10:47,100 --> 01:10:52,240 +generation وما لاقاش ال double bond المناسبة يتفاعل + +817 +01:10:52,240 --> 01:10:56,360 +معها على طول بيروح بتفاعل مع نفسه اثنين من هذا بيعطينا + +818 +01:10:56,360 --> 01:11:06,290 +R C double bond M O وأنا R C double bond MO بيكون + +819 +01:11:06,290 --> 01:11:09,910 +minus plus بهذا الشكل هذا مركب اسمه فيوركسان هذا + +820 +01:11:09,910 --> 01:11:16,270 +دايما اتطلعوا المكونات تبعته RCNO RCNO فيوركسان + +821 +01:11:16,270 --> 01:11:16,950 +بنسميه + +822 +01:11:21,470 --> 01:11:26,330 +ما لاقاش مع مين يتفاعل إيش بيعمل الـ dimerization + +823 +01:11:26,330 --> 01:11:30,210 +الآن مش موضوع ال dimer احنا هنحط له double bond + +824 +01:11:30,210 --> 01:11:33,990 +مناسبة يتفاعل معها وفي كل الأحوال لو اشتغلتوا في + +825 +01:11:33,990 --> 01:11:37,550 +مستقبل حياتكم بـ nitrile oxides هتلاحظوا إنه جد ما + +826 +01:11:37,550 --> 01:11:43,410 +تحطوله إلا جزء منه بيعمل إيش؟ dimer وال dimer أنا + +827 +01:11:43,410 --> 01:11:47,690 +رغبان ولا ما بديش اياه؟ أنا ما بديش اياه الآن طب كيف + +828 +01:11:47,690 --> 01:11:52,750 +بنحضره؟ إذا بدأنا من ال أكزيم ال الديهايد أكزيم كنا + +829 +01:11:52,750 --> 01:11:56,570 +بنعرف الأكزيم هذا الأكزيم لو عملنا له chlorination + +830 +01:11:56,570 --> 01:12:01,310 +ب chlor .. ب chloroform وفي طرق طبعا تانية غير + +831 +01:12:01,310 --> 01:12:05,130 +غاز لكلور أنا كتير اشتغل فيه كنت استعمل نفس غاز + +832 +01:12:05,130 --> 01:12:08,410 +لكلور يعني بس في طرق تانية كتيرة + +833 +01:12:08,410 --> 01:12:11,650 +N-chlorosuccinimide وغيره وغيرته المهم + +834 +01:12:11,650 --> 01:12:16,820 +chlorination هذا ال chlorination ببدل ال H هذه ب CL + +835 +01:12:16,820 --> 01:12:23,740 +شو صار هذا المركب اسمه كلوروكزيم صار كلوروكزيم + +836 +01:12:23,740 --> 01:12:29,760 +إذا هذا البريكير صار كلوروكزيم أو مرات بيسموه + +837 +01:12:29,760 --> 01:12:33,340 +هيدروكسامويل كلوريد يعني هتقرؤ الاسمين + +838 +01:12:33,340 --> 01:12:36,380 +هيدروكسامويل + +839 +01:12:36,380 --> 01:12:38,640 +كلوريد + +840 +01:12:39,650 --> 01:12:43,190 +سواء كلوروكزيم أو هيدروكسامويل كلوريد هذا البري + +841 +01:12:43,190 --> 01:12:47,990 +كيرسر الآن هذا البري كيرسر أثناء التفاعل بمجد عليه + +842 +01:12:47,990 --> 01:12:51,510 +تري إيثيل أمين تري إيثيل أمين بايش هيسحب منه + +843 +01:12:51,510 --> 01:12:57,270 +HCl هيكون النيترال أكسايد بيلاقي الـ double bond + +844 +01:12:57,270 --> 01:13:05,050 +بتفعل معها إذا شفنا كيف احنا بنحضّر النيترال أكسايد + +845 +01:13:05,050 --> 01:13:11,690 +مبتدئين من ايش؟ بنفع نقول مبتدئين من الـ aldehyde ما + +846 +01:13:11,690 --> 01:13:16,790 +هو الـ aldehyde نفسه بيصير oxime واضح؟ + +847 +01:13:16,790 --> 01:13:21,430 +الـ aldehyde، oxime، chloro oxime، nitrile oxide، بعدين + +848 +01:13:21,430 --> 01:13:27,290 +بضيف له الـ double bond هذه الطريقة لتحضير الـ + +849 +01:13:27,290 --> 01:13:32,270 +precursor لنيترال أكسايد ممكن من الـ nitro + +850 +01:13:32,270 --> 01:13:32,970 +compounds + +851 +01:13:36,030 --> 01:13:42,410 +RCH2NO2 لو فعلوه مع فين الـ isocyanate بتعملوا بهذا + +852 +01:13:42,410 --> 01:13:49,730 +الشكل وبعدين بيكون ايش؟ nitrile oxide هذا أكثر للـ + +853 +01:13:49,730 --> 01:13:53,010 +الـ aliphatic compounds هذا أكثر للـ aromatic compounds + +854 +01:13:53,010 --> 01:13:57,590 +يعني إن الـ R تكون aliphatic غالبًا من هذا المصدر أو + +855 +01:13:57,590 --> 01:14:01,590 +استيل الـ R تكون aromatic غالبًا من هذا المصدر طبعًا + +856 +01:14:01,590 --> 01:14:08,070 +أي المصارد؟ الأشهر هذا المصدر يعني هذا أشهر مصدر للـ + +857 +01:14:08,070 --> 01:14:11,410 +generation of nitrile oxide اللي هي الـ aldehyde oxime + +858 +01:14:11,410 --> 01:14:19,030 +chloro oxime nitrile oxide okay لو أجينا لـ nitrile + +859 +01:14:19,030 --> 01:14:24,090 +sulfide كيف بنعمل له generation؟ بنجيب هذا المركب و + +860 +01:14:24,090 --> 01:14:29,290 +بنسخّنه شوية لحظة هذا المركب مجرد ما نسخّنه هنا في + +861 +01:14:29,290 --> 01:14:33,270 +عندكم هذه وهذه بدأ تيجي هنا يعني بده يفقد جزء ايش؟ + +862 +01:14:34,290 --> 01:14:39,790 +-CO2 ثاني أكسيد الكربون أعطاني nitrile sulfide واضح؟ + +863 +01:14:39,790 --> 01:14:45,110 +فالـ nitrile sulfide من هذا المركب اللي موجود أمامنا + +864 +01:14:45,110 --> 01:14:50,050 +بالتسخين بيفقد ثاني أكسيد الكربون وبيعطيني nitrile + +865 +01:14:50,050 --> 01:14:59,310 +sulfide طيب لو بدنا nitrile imine تقريبًا الفكرة + +866 +01:14:59,310 --> 01:15:03,390 +الأخيرة منه زي nitrile oxide هناك كان عندي chloro + +867 +01:15:04,530 --> 01:15:10,010 +oxime هنا C double bond N N H hydrazon و + +868 +01:15:10,010 --> 01:15:13,430 +chloro hydrazon + +869 +01:15:13,430 --> 01:15:18,230 +عادة بيسمّوه hydrazonoyl chloride hydrazonoyl + +870 +01:15:18,230 --> 01:15:24,030 +chloride اللي هو الـ chloro hydrazon بالـ triethylamine + +871 +01:15:24,030 --> 01:15:34,640 +شو هيسحب؟ H و Cl هيعمل له nitrile imine طبعًا هل + +872 +01:15:34,640 --> 01:15:41,060 +ممكن من مركّبات زي هذا سخن ويفقد جزء نيتروجين مركّبات + +873 +01:15:41,060 --> 01:15:46,280 +زي هذا سخن ويفقد جزء نيتروجين برضه وارد الآن + +874 +01:15:46,280 --> 01:15:52,360 +الطريقة الأشهر لتحضير nitrile imine الـ Hydrazinoid + +875 +01:15:54,430 --> 01:15:58,170 +بشكل عام hydrazonoyl chloride بالـ triethylamine + +876 +01:15:58,170 --> 01:16:03,430 +بيعطيني nitrile imine العملية مش صعبة موجودة حتى في + +877 +01:16:03,430 --> 01:16:07,810 +مختبراتنا يعني كثير بنحضّره وطبعًا بالصين إنه هذا + +878 +01:16:07,810 --> 01:16:13,550 +كيف بده يتحضّر هذا؟ بتحضّر ممكن من الـ chlorination + +879 +01:16:13,550 --> 01:16:19,270 +للهيدرازون وارد وفي طريقة مشهورة كثير اسمها جابي + +880 +01:16:19,270 --> 01:16:23,250 +كلينجمان Reaction واردة الطريقتين واردات والأشهر + +881 +01:16:23,250 --> 01:16:27,430 +فيهم الـ Gabbi Klingman Reaction خلنا نقول إنه الـ nitrile + +882 +01:16:27,430 --> 01:16:31,010 +imine من الـ hydrazon والـ halides والـ nitrile oxides + +883 +01:16:31,010 --> 01:16:37,740 +من الـ chloro oxime aldehydes عادةً ما بتوجد aldehydes + +884 +01:16:37,740 --> 01:16:42,480 +يعني ما فيش فيها مشكلة وبنقدر نفعلها diazomethane + +885 +01:16:42,480 --> 01:16:49,820 +له طرق معينة كيف يحضّروه الآن لو بدنا ناخذ أمثلة + +886 +01:16:49,820 --> 01:16:59,220 +في النهاية لاحظوا عنده عدد كبير جدًا من الأمثلة هل + +887 +01:16:59,220 --> 01:17:04,700 +ياتورا بدي أستعرضهم؟ لأ أنا بدي أحكي أفكار عامة في + +888 +01:17:04,700 --> 01:17:11,360 +موضوع الأمثلة، الأفكار العامة إنه بدنا نفكّر دائمًا + +889 +01:17:11,360 --> 01:17:16,060 +في أي مثال إنه عندي two possible products + +890 +01:17:17,200 --> 01:17:22,960 +يعني إذا أنتم بتقرأوا مقال المقال بيكون شخص عمل + +891 +01:17:22,960 --> 01:17:27,100 +التجربة فصل الناتج في هذه الحالة يا بيكون فصل one + +892 +01:17:27,100 --> 01:17:30,600 +product يا mixture of products وطلع نسبة المئوية + +893 +01:17:30,600 --> 01:17:35,720 +لكن لو احنا قلنا لكم أكمل أي معادلة cycle addition + +894 +01:17:35,720 --> 01:17:38,920 +1,3-dipolar cycle addition أو deals-Alder + +895 +01:17:38,920 --> 01:17:43,810 +reaction الأصل بشكل عام إن عندكم ايش؟ two products + +896 +01:17:43,810 --> 01:17:50,610 +طبعًا بشرط إنه الـ reactants تكون unsymmetrical لأنّه + +897 +01:17:50,610 --> 01:17:54,830 +لو مع reactants symmetrical أجلبوه هيطلعوا نفس + +898 +01:17:54,830 --> 01:18:01,350 +النتيجة مثلًا هنا هيعندي A زايد اطلع معاه هذه الآن + +899 +01:18:01,350 --> 01:18:06,800 +متصلة فيه إن هذه الآن free صح ولا لأ؟ الآن وهي + +900 +01:18:06,800 --> 01:18:10,680 +عندي double bond هي متصلة بـ methyl وهي بـ phenyl في هذه + +901 +01:18:10,680 --> 01:18:17,840 +الحالة هذا symmetrical ولا لأ؟ وهذا ... إذا كم + +902 +01:18:17,840 --> 01:18:22,560 +ناتج هنا متوقع؟ اثنين لاحظوا هو هنا هي يستعمل + +903 +01:18:22,560 --> 01:18:27,500 +الـ phenyl azide بعدين حطّيه للكربون اللي متصل + +904 +01:18:27,500 --> 01:18:34,310 +بالـ phenyl عند نيتروجين الحملة الـ phenyl لو قلنا لكم طب + +905 +01:18:34,310 --> 01:18:40,370 +ايش الناتج الثاني؟ الناتج الثاني إن الـ methyl تكون هنا + +906 +01:18:40,370 --> 01:18:44,950 +والـ phenyl تكون هنا يعني لو أنتم بتكونوا تكملوا + +907 +01:18:44,950 --> 01:18:48,070 +المعادلة أنتم مش قاعدين في المختبر لازم تحطّوا لي + +908 +01:18:48,070 --> 01:18:52,790 +كم ناتج؟ two possible products تمام؟ الآن هو عمل + +909 +01:18:52,790 --> 01:19:00,130 +تجربة وبناء على ذلك فصلنا ناتج واحد هذا الكلام هيدلّوا + +910 +01:19:00,130 --> 01:19:03,470 +يتكرر دائمًا التفاعل مع الـ 1,3-dipolar على أطراف الـ + +911 +01:19:03,470 --> 01:19:08,750 +1,3-dipolar هي الـ diazomethane هيتفاعل وين؟ هنا هنا + +912 +01:19:08,750 --> 01:19:13,150 +لاحظوا الـ diazomethane البعض منكم هيجي يقول طب يا + +913 +01:19:13,150 --> 01:19:17,470 +رب ما احنا أخذناه بشوية تسخين بيفقد نيتروجين + +914 +01:19:17,470 --> 01:19:22,940 +وبيعطيني carbene صح ولا لأ؟ عشان كده يا زلمة حتى + +915 +01:19:22,940 --> 01:19:26,740 +من المركّبات اللي صعبة في التحضير وعادةً بدها زجاج + +916 +01:19:26,740 --> 01:19:30,920 +ناعم اللي ما يعملش انفجار وبيحطّوا shield حماية + +917 +01:19:30,920 --> 01:19:34,440 +خفّة إنه يضرّ الناس اللي بيشتغلوا فيه يعني الشغل + +918 +01:19:34,440 --> 01:19:39,180 +فيه متعب لو عملوا تسخين أو photolysis الاحتمال + +919 +01:19:39,180 --> 01:19:44,620 +فعلاً إنه يفقد من هنا ويعمل carbene وبالتالي لاحظوا + +920 +01:19:44,620 --> 01:19:48,280 +هذا التفاعل لو كنت كتبت لكم حرارة أو photolysis ممكن + +921 +01:19:48,280 --> 01:19:51,920 +واحدة شاطرة تقول okay diazomethane فقد الـ nitrogen + +922 +01:19:51,920 --> 01:19:56,560 +عمل carbene بعدين تجيب الـ carbene هاد اللي حاملة methyl + +923 +01:19:56,560 --> 01:20:00,520 +و methyl وتعمل حلقة ثلاثية هذا الكلام كله وقتاش + +924 +01:20:00,520 --> 01:20:09,260 +مقبول؟ لو أنا قلت شوية heat أو ضوء يمكن لكن لاحظوا + +925 +01:20:09,260 --> 01:20:13,400 +الـ condition هنا في الـ diazomethane ايش؟ zero degree + +926 +01:20:13,400 --> 01:20:19,200 +centigrade و أعطاه وجد عشان ما يكسرش الـ nitrogen و + +927 +01:20:19,200 --> 01:20:24,080 +يتفاعل كـ 1,3-dipole فالـ diazomethane بدّه يظلّ + +928 +01:20:24,080 --> 01:20:28,960 +بفكركم إنه لو فلتت الشروط شوية في تسخين أو ضوء + +929 +01:20:29,760 --> 01:20:34,480 +هيحول لإيش؟ لـ carbene ويصير يشغل كيمياء carbene، هيبطل + +930 +01:20:34,480 --> 01:20:41,640 +كـ 1,3-dipole واضح الفكرة؟ هذا nitrile sulfide، كم + +931 +01:20:41,640 --> 01:20:49,680 +ناتج بتوقّع له على طول؟ + +932 +01:20:49,680 --> 01:20:55,100 +واحد، + +933 +01:20:55,100 --> 01:21:00,900 +ليش؟ لأن هذا متماثل، يعني لو جلبته هذه هذه + +934 +01:21:00,900 --> 01:21:07,120 +cyclopentane متماثلة تمام كل هذه الأمثلة ما لم + +935 +01:21:07,120 --> 01:21:12,760 +تتدربوا أنتم بأيديكم أنتم تكتبوها هتتغلّبوا الآن + +936 +01:21:12,760 --> 01:21:17,740 +أحيانًا بيكون التفاعل intramolecular يعني الـ + +937 +01:21:17,740 --> 01:21:20,720 +nitrile oxide يعني لاحظوا هنا هي nitrile oxide + +938 +01:21:20,720 --> 01:21:25,000 +ممكن عشان السهولة بس أنا أعيد رسمه أخلي الـ oxygen + +939 +01:21:25,000 --> 01:21:33,840 +هنا هذه الـ 1,3-dipole وهذه الـ double bond طبعًا في + +940 +01:21:33,840 --> 01:21:38,260 +الـ intramolecular هنا كم product عنده؟ كم + +941 +01:21:38,260 --> 01:21:43,500 +possible product؟ لأن الـ geometry مش الـ + +942 +01:21:43,500 --> 01:21:46,000 +stereochemistry، الـ geometry لا تسمح، يعني مقدرش + +943 +01:21:46,000 --> 01:21:50,820 +اللفّ ويقول وين ودّنك؟ واضحة الفكرة؟ + +944 +01:21:53,630 --> 01:21:58,370 +نيتروجين على الكربون والأكسجين symmetric ولا unsymmetric + +945 +01:21:58,370 --> 01:22:01,890 +هذا CMO + +946 +01:22:01,890 --> 01:22:07,150 +unsymmetric بزن CMO COO unsymmetric طب هي الـ double + +947 +01:22:07,150 --> 01:22:13,920 +bond CH2 و CHSO2 في نفس الكربون انعدل كم ناتج متوقّع + +948 +01:22:13,920 --> 01:22:17,800 +اثنين لاحظوا هنا طلع الاثنين يعني لو أنا أخذت هذا + +949 +01:22:17,800 --> 01:22:23,920 +الـ phenyl CNO phenyl CNO هذا الـ 1,3-dipole هي الـ 1,3- + +950 +01:22:23,920 --> 01:22:29,240 +dipole الآن مرة خلى هذه المجموعة اللي هي الـ SO2 + +951 +01:22:29,240 --> 01:22:35,260 +phenyl انعلمها باللون الأحمر على جهة الـ phenyl ومرة خلى + +952 +01:22:35,260 --> 01:22:39,340 +على الجهة الثانية فصل الناتجين وطلعوا بنسبة قداش؟ + +953 +01:22:40,320 --> 01:22:49,580 +68% لـ 32% تجربة واضحة؟ إذا أنا بدي انتبه لما بكون + +954 +01:22:49,580 --> 01:22:55,640 +بعمل معادلات وبكمّل تفاعلات إن في مرات كثير في + +955 +01:22:55,640 --> 01:23:01,730 +عنده الاحتمالين وفي نهاية التجربة هي الحكم كل هذه + +956 +01:23:01,730 --> 01:23:06,970 +الأمثلة الآن اللي موجودة بشكل كبير هي azide لما + +957 +01:23:06,970 --> 01:23:10,290 +يصير التفاعل مع الـ triple bond يعني الأمثلة + +958 +01:23:10,290 --> 01:23:13,270 +السابقة كانت مع double bond لما يصير مع الـ triple + +959 +01:23:13,270 --> 01:23:16,970 +bond للـ triple شو بدها تصير؟ double والـ double شو + +960 +01:23:16,970 --> 01:23:20,310 +بتصير؟ single الأمثلة السابقة كانت double؟ single + +961 +01:23:20,310 --> 01:23:25,770 +آه الآن هنا phenyl C≡C يعني لو أنا أخذت phenyl azide هي + +962 +01:23:25,770 --> 01:23:30,170 +الـ phenyl azide ملاحظين؟ + +963 +01:23:31,300 --> 01:23:34,800 +الآن هذا الـ phenyl azide symmetric ولا unsymmetric + +964 +01:23:34,800 --> 01:23:40,220 +unsymmetric الآن phenyl C≡C symmetric ولا + +965 +01:23:40,220 --> 01:23:44,880 +unsymmetric unsymmetric بناء على ذلك لما اتفاعل لاحظوا + +966 +01:23:44,880 --> 01:23:49,720 +معاه إنه ممكن الـ phenyl تيجي على جهة الـ N اللي هنا أو + +967 +01:23:49,720 --> 01:23:53,160 +الـ phenyl تيجي هنا two possible products في هذه + +968 +01:23:53,160 --> 01:23:59,780 +الحالة طالعين اثنين بالنسبة 42 لـ 2 + +969 +01:23:59,780 --> 01:24:05,590 +و50 هذا المثال الجميل فيه azide بس هو كتبوه هنا + +970 +01:24:05,590 --> 01:24:10,750 +على شكل any three يعني أنتم بتكونوا تفصلوه C N≡N + +971 +01:24:10,750 --> 01:24:15,970 +N هي الـ azide هذه اللي هي any three هي الـ carbon + +972 +01:24:15,970 --> 01:24:24,690 +هذه any three N≡N≡N≡N≡N≡N وهذه الكربون مجرد رفع + +973 +01:24:24,690 --> 01:24:28,370 +على فوقه عملت double bond يعني هي الجزء قبل ما + +974 +01:24:28,370 --> 01:24:33,970 +يعملوا هدول الروابط تطلع عليه oxygen CH2 C≡C + +975 +01:24:33,970 --> 01:24:40,750 +bond C oxygen CH2 C≡C نيتروجين اثنين ثلاثة + +976 +01:24:40,750 --> 01:24:46,100 +ثلاثة إذا هذا التفاعل inter ولا intermolecular؟ inter + +977 +01:24:46,100 --> 01:24:51,780 +molecular cycloaddition reaction للـ azide ولاحظوا + +978 +01:24:51,780 --> 01:24:58,120 +كيف كون ثلاث حلقات كيف كون ثلاث حلقات أنا بتهيألي كل + +979 +01:24:58,120 --> 01:25:04,070 +الأمثلة الحقيقة اللي موجودة من ناحية المبدأ بهذا + +980 +01:25:04,070 --> 01:25:08,470 +الشكل هذا اللي هنا يمكن نيتروجين هذه أطراف الـ 1,3 + +981 +01:25:08,470 --> 01:25:14,010 +-dipole carbon-NO ومثل البيريدين أكسيد لما يمر + +982 +01:25:14,010 --> 01:25:20,730 +علينا البيريدين أن أكسيد هنا أكسجين واحد اثنين + +983 +01:25:20,730 --> 01:25:27,250 +ثلاثة بيريدين أن أكسيد برضه هذا نترون هنا أطراف ال + +984 +01:25:27,250 --> 01:25:29,410 +1,3-dipole carbon-NO + +985 +01:25:32,480 --> 01:25:35,680 +معنى triple bond؟ symmetric ولا unsymmetric؟ + +986 +01:25:35,680 --> 01:25:41,920 +لاحظوا هنا طلع ناتج ما طلعش الثاني هو يعبر عن إيش + +987 +01:25:41,920 --> 01:25:45,060 +اللي طلع معاه بالتجربة لكن لو أنا جايب الكواشف و + +988 +01:25:45,060 --> 01:25:48,240 +أكمل المعادلة و أجيت الناتج الثاني بتكون تقلبّه + +989 +01:25:48,240 --> 01:25:56,260 +هذه، هذه تصير هذه ترسم الـ two regio isomers و هي + +990 +01:25:56,260 --> 01:26:02,640 +أمثلة إضافية وإضافية وإضافية خلينا نأخذ آخر + +991 +01:26:02,640 --> 01:26:08,400 +slide أو اثنتين عشان ننهي هذا الكلوروجزيم مع الـ + +992 +01:26:08,400 --> 01:26:13,020 +triethylamine شو بده يعمل لنا نترايل أكسيد لو + +993 +01:26:13,020 --> 01:26:18,960 +أجينا فعلنا مع الـ symbol هيدرازون هيدرازون + +994 +01:26:18,960 --> 01:26:25,060 +عادي هذا C double bond N C double bond N لما يتكون + +995 +01:26:25,060 --> 01:26:30,560 +هذا بده يعمل cycle addition على C double bond and + +996 +01:26:30,560 --> 01:26:35,160 +شو صارت الـ double bond single bond أعطانا one + +997 +01:26:35,160 --> 01:26:40,120 +product تمام أعطانا one product و في بعض الأحوال + +998 +01:26:40,120 --> 01:26:46,360 +لما هذه الـ R' كانت H التقت H و أنا H2 جاب بعض ممكن + +999 +01:26:46,360 --> 01:26:50,820 +يُفتنوا أمونيا و يعملوا bubble bond زي ما كان + +1000 +01:26:50,820 --> 01:26:54,120 +بيلتقي H و O H بيعملوا + +1001 +01:26:57,770 --> 01:27:03,910 +Double bond حدث ماء هنا حدث إيش أمونيا شايفين + +1002 +01:27:03,910 --> 01:27:09,390 +أنتم التفاعل إيش ماله بسيط جدا مجرد أن الإنسان + +1003 +01:27:09,390 --> 01:27:15,270 +يحضر الديهيد أكزيم كلور أكزيم و يحضر هيدرازون + +1004 +01:27:15,270 --> 01:27:22,210 +يخلطهم مع بعض ويطلع إيشو يطلع الناتج يعني لو + +1005 +01:27:22,210 --> 01:27:26,170 +كنتم بتعملوا هذا الكلام في المختبر كم .. كم + +1006 +01:27:26,170 --> 01:27:35,930 +محاضرة مختبر بدوا يلزمكوا فيها؟ ثلاث ساعات ولا ستة؟ + +1007 +01:27:35,930 --> 01:27:40,390 +الصحيح أنه التجريب والعمل وأنّكم تظبطوا ال + +1008 +01:27:40,390 --> 01:27:43,830 +conditions و تفصلوا النواتج و تعملولها NMR و + +1009 +01:27:43,830 --> 01:27:48,950 +تعملولها تشخيص وما إلى ذلك هذا الكلام بياخد منكم + +1010 +01:27:50,450 --> 01:27:55,730 +بياخد منكم جداش؟ أشهر أحيانا، يعني هذه المعادلة + +1011 +01:27:55,730 --> 01:27:59,770 +فقط هذه المعادلة مش أكثر كانت هي موضوع رسالتي + +1012 +01:27:59,770 --> 01:28:04,190 +للمجستير أنا اللي أخدت مني أشهر سنة الثمانين وت + +1013 +01:28:04,190 --> 01:28:08,480 +ثمانين، تسعة وثمانين يعني لاحظوا معادلة واحدة فقط + +1014 +01:28:08,480 --> 01:28:13,140 +فالكيمياء بده مشقة كتير، بده تعب كتير، ليش؟ لأن + +1015 +01:28:13,140 --> 01:28:17,460 +اللي هنا بيكتب R و R، بعدين يطور الـ R و الـ R مثل و + +1016 +01:28:17,460 --> 01:28:21,660 +مثل، إيثل وإيثل، بروبيل وبروبيل، سايكلوبنتانون، + +1017 +01:28:21,660 --> 01:28:26,280 +ممكن تكون سايكلو .. يعطي أمثلة للناس، اللي بيكتب + +1018 +01:28:26,280 --> 01:28:30,400 +Ar، طب هي الـ Ar بنزين ولا بارا كلورو بنزين ولا + +1019 +01:28:30,400 --> 01:28:36,190 +بارا مثل؟ بده يعمل من هنا أمثلة من هنا أمثلة يتأكد + +1020 +01:28:36,190 --> 01:28:39,490 +يفصل النواتج يعملها crystallization مرة أو مرتين + +1021 +01:28:39,490 --> 01:28:43,030 +لحد ما تصير نقية يعملها IR يعملها NMR يعملها + +1022 +01:28:43,030 --> 01:28:47,170 +elemental analysis هذا الكلام ما بتلاقوله مكلف معك + +1023 +01:28:47,170 --> 01:28:54,790 +و قداش من نص سنة إلى سنة من المجهود واضح؟ لاحظوا في + +1024 +01:28:54,790 --> 01:28:57,650 +ناس أجوا بدل ما يكون هذا simple هيدرازون يقولوا + +1025 +01:28:57,650 --> 01:29:03,200 +خلنا نخلي هذا الـ N H مثل ومثل برضه عملوا cycle + +1026 +01:29:03,200 --> 01:29:06,280 +addition وين؟ على الـ double bond هذا الـ double + +1027 +01:29:06,280 --> 01:29:12,900 +bond شو صارت؟ صارت single bond تمام؟ هذا شغل أعتقد + +1028 +01:29:12,900 --> 01:29:17,880 +أنه فيه مجموعة روسية اشتغلت عليه ففي ناس أجواء + +1029 +01:29:17,880 --> 01:29:23,640 +فكروا قالوا مرة خلنا الاثنتين هيدروجينز انتبهوا + +1030 +01:29:23,640 --> 01:29:33,220 +معايا ومرة خلنا الاثنتين مثل إيش ضال؟ الخلي واحدة + +1031 +01:29:33,220 --> 01:29:38,760 +هيدروجين وواحدة مثل ونعمل Cycloaddition واضح؟ + +1032 +01:29:38,760 --> 01:29:42,600 +المسكين اللي خلى واحدة هيدروجين وواحدة مثل إجى + +1033 +01:29:42,600 --> 01:29:45,920 +يعمل Cycloaddition تفاجأ أنه ما صار عنده + +1034 +01:29:45,920 --> 01:29:50,020 +Cycloaddition صار عنده تفاعل ثاني أجات هذه ال + +1035 +01:29:50,020 --> 01:29:54,520 +nitrogen بعد ما فقد الكلور والـH هاجمتها وهذه ال + +1036 +01:29:54,520 --> 01:29:58,180 +oxygen سكرّت على الـ double bond عملية Cyclization + +1037 +01:29:58,180 --> 01:30:01,180 +بخطوطين مش Cycloaddition الـ Cycloaddition بيعطي + +1038 +01:30:01,180 --> 01:30:07,920 +جداش حلقة خماسية فهذه الـ nitrogen في هذه الحالة + +1039 +01:30:07,920 --> 01:30:12,020 +بدل ما أعمل Cycloaddition على الـ double bond هذه ال + +1040 +01:30:12,020 --> 01:30:15,380 +nitrogen في نهاية نيوكليوفيل وهذه الـ carbon موجبة + +1041 +01:30:15,380 --> 01:30:20,080 +هاجمت عليها عملت bond هذه الـ oxygen نيوكليوفيل + +1042 +01:30:20,080 --> 01:30:26,430 +وهذه الـ carbon موجبة in principle أو لما تتحرك هذا + +1043 +01:30:26,430 --> 01:30:31,090 +الشكل وبالتالي أعطاني تفاعل بنسميه cycle + +1044 +01:30:31,090 --> 01:30:36,050 +condensation أعطاني حلقة سلسلة لاحظوا كم تغيير R + +1045 +01:30:36,050 --> 01:30:42,490 +بسيط تغيير بسيط بدل ما التفاعل يكون cycle addition + +1046 +01:30:42,490 --> 01:30:46,710 +اللي هو ثلاثة زي اثنين يساوي خمسة اتفعل بطريقة + +1047 +01:30:46,710 --> 01:30:51,070 +مختلفة وأعطاني نوع من الـ cycleization العادي + +1048 +01:30:51,070 --> 01:30:54,870 +cycleization enucleophile electrophile و + +1049 +01:30:54,870 --> 01:30:57,690 +enucleophile electrophile زي أنواع الـ cycleization + +1050 +01:30:57,690 --> 01:31:03,840 +اللي أخذناها طلع حلقة سداسية أكيد حلقة سداسية مش + +1051 +01:31:03,840 --> 01:31:06,280 +cycle addition ليش لأن الـ cycle addition one three + +1052 +01:31:06,280 --> 01:31:11,000 +bipolar cycle addition ثلاثة زي اثنين يساوي خمسة + +1053 +01:31:11,000 --> 01:31:15,060 +هذا أكيد مش cycle addition يمكن هذا بيحطكم بصورة + +1054 +01:31:15,060 --> 01:31:24,500 +كده الموضوع كبير في كل الأحوال بدناياكم تجيبولنا + +1055 +01:31:24,500 --> 01:31:31,410 +homework هذا كمان مثال ثاني لكن بدل ما يحطوا هنا + +1056 +01:31:31,410 --> 01:31:37,490 +مجموعة مثل حطوا مجموعة ساحبة للإلكترونات تطلعوا + +1057 +01:31:37,490 --> 01:31:41,770 +معي لما حطينا مجموعة مثل يمكن الناس اللي بيحاولوا + +1058 +01:31:41,770 --> 01:31:45,690 +يفهموا ليش التفاعل زي المثل إيش مالها؟ تعطي + +1059 +01:31:45,690 --> 01:31:49,330 +إلكترونات هنا في زوج إلكترونات إذا هذا كان + +1060 +01:31:49,330 --> 01:31:55,170 +نيوكليوفيل صار إيش؟ قوي نوعا ما إجا هاجم هنا وهذا + +1061 +01:31:55,170 --> 01:32:00,250 +كان نيوكليوفيل سكر هنا أعطانا الحلقة السداسية الآن + +1062 +01:32:00,250 --> 01:32:05,470 +لو بدل هذه المجموعة المعطية حطينا مجموعة ساحبة هل + +1063 +01:32:05,470 --> 01:32:09,550 +يا ترى هيسكرها الحلقة السداسية ولا بده يرجع لل + +1064 +01:32:09,550 --> 01:32:16,690 +cycle addition التجربة اللي بتوضح التجربة بتقول + +1065 +01:32:16,690 --> 01:32:21,670 +نرجع للـ cycle addition التجربة بتقول يجي على الصيف + +1066 +01:32:21,670 --> 01:32:27,490 +لقد شيل لإيش؟ لأن هذه بطلت strong nucleophile in + +1067 +01:32:27,490 --> 01:32:32,570 +principle فلاحظوا تغيرات بسيطة بتلف التفاعل من أن + +1068 +01:32:32,570 --> 01:32:36,610 +يكون cycle addition لأن يكون cyclization عادي كل + +1069 +01:32:36,610 --> 01:32:40,810 +هذا الكلام وين الإنسان بيواجهه لما يصير في واقع + +1070 +01:32:40,810 --> 01:32:43,970 +العمل التجريبي الآن الـ course عندكم أنتم يعني + +1071 +01:32:43,970 --> 01:32:47,890 +very general course بدكم مفاهيم .. مفاهيم عامة + +1072 +01:32:47,890 --> 01:32:53,210 +جدا في cycle addition بأمل أنه صارت واضحة عندكم و + +1073 +01:32:53,210 --> 01:32:59,400 +بتسمحلكوا أن تجيبولنا homework مش أقل من ثلاث أمثلة + +1074 +01:32:59,400 --> 01:33:03,640 +على الـ Cycloaddition الثلاث أمثلة مختلفة مثلا مثال + +1075 +01:33:03,640 --> 01:33:06,920 +يكون عن الآزايد مثال عن الديازوميثين مثال عن + +1076 +01:33:06,920 --> 01:33:09,620 +النيترال أكسيد مثال عن نيترال إيمين عن نيترال + +1077 +01:33:09,620 --> 01:33:16,240 +سالفايد افتحوا أي open access journal واكتبوا + +1078 +01:33:16,240 --> 01:33:20,960 +فيها Cycloaddition الـ homework هذا هتلاحظوا أنه + +1079 +01:33:20,960 --> 01:33:28,120 +بينحل بعشر دقائق بكون وجهكم إلى مقالات كتيرة جدا + +1080 +01:33:28,120 --> 01:33:32,380 +يعني مجرد ما تكتبوا one three bipolar cycle + +1081 +01:33:32,380 --> 01:33:39,180 +edition هيوجهكم إلى عشرات المقالات المنشورة حديثا + +1082 +01:33:39,180 --> 01:33:42,160 +و اللي العالم بيشتغلوا عليها في المجال بتسلمون الـ + +1083 +01:33:42,160 --> 01:33:47,440 +home working المرة القادمة إن شاء الله و بارك الله + +1084 +01:33:47,440 --> 01:33:47,880 +فيك diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/0AW2jJkssxA_raw.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/0AW2jJkssxA_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..a829c1f9cd6a0e1895c9d8161a67b0e5c7bf1695 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/0AW2jJkssxA_raw.srt @@ -0,0 +1,4336 @@ +1 +00:00:20,670 --> 00:00:26,050 +بسم الله الرحمن الرحيم في موضوع الـ heterocyclic + +2 +00:00:26,050 --> 00:00:31,330 +synthesis سبق إن اتكلمنا عن أكثر من طريقة عامة + +3 +00:00:31,330 --> 00:00:34,790 +لتحضير الـ heterocyclic rings اتكلمنا عن الـ + +4 +00:00:34,790 --> 00:00:39,030 +cyclization reactions بأنواعها المرة الماضية + +5 +00:00:39,030 --> 00:00:45,130 +أعطينا مقدمة مختصرة لبأس بالمر عليها الآن في الـ + +6 +00:00:45,130 --> 00:00:49,310 +cycloaddition reactionsبشكل عام قلنا ان الـ + +7 +00:00:49,310 --> 00:00:54,090 +Cycloadditional reactions تفاعلات محددة معروفة جزء + +8 +00:00:54,090 --> 00:01:01,870 +منها مخد أسماءو هذه التفاعلات زي ما اتفقنا فيها + +9 +00:01:01,870 --> 00:01:07,770 +نظم فيها by electrons اتو يعني species بيقتربوا من + +10 +00:01:07,770 --> 00:01:12,630 +بعض و بيكونوا رابطتين بنفس اللحظة عشان هيك لإن في + +11 +00:01:12,630 --> 00:01:16,290 +عندي أناcyclic intermediate بتصير بنحكي عن شيء + +12 +00:01:16,290 --> 00:01:24,100 +بنسميه pericyclic reactions واضح؟الان كتصنيف الـ + +13 +00:01:24,100 --> 00:01:28,180 +Cycloaddition reactions هلاحظ أنه في عندنا الأنواع + +14 +00:01:28,180 --> 00:01:33,660 +اللي موجودة أمامنا وزي ما اتفقنا أنه ممكن أنه نصنف + +15 +00:01:33,660 --> 00:01:36,160 +احنا الـ Cycloaddition reactions من ناحية الـ + +16 +00:01:36,160 --> 00:01:39,400 +Geometry أو حجم الحلقة أو من ناحية الـ Bi + +17 +00:01:39,400 --> 00:01:44,320 +-electrons اتكلمنا عن الـ Chelotropic reactions + +18 +00:01:44,770 --> 00:01:48,710 +هدول الـ Chelotropic reactions ممكن يكون عندى من + +19 +00:01:48,710 --> 00:01:54,550 +ناحية الـ الـ Geometry ذرة فيها two bi-electrons + +20 +00:01:54,550 --> 00:01:58,870 +مع double bond وبالتالي يعطونى حلقة ثلاثية وممكن + +21 +00:01:58,870 --> 00:02:04,230 +يكون ذرة برضه فيها bi-electrons او free electrons + +22 +00:02:04,230 --> 00:02:12,370 +مع two biخلّينا نقول يعطينا حلقة خماسية في كل + +23 +00:02:12,370 --> 00:02:16,910 +الأحوال الـ Chelotropic reaction من أبسط تعريفاته + +24 +00:02:16,910 --> 00:02:22,310 +انه انا لما بشتغل على ال by system او ال by + +25 +00:02:22,310 --> 00:02:26,590 +electrons يعني هنا في عند اتنين by electrons و هنا + +26 +00:02:26,590 --> 00:02:30,410 +في عند اتنين by electrons شايفينهم بالأحمر؟أنا + +27 +00:02:30,410 --> 00:02:34,530 +بحول هدول ال by electrons ل sigma bonds يعني في + +28 +00:02:34,530 --> 00:02:39,190 +cycle additions معنى انه انا بدأ اعمل تنتيل bonds + +29 +00:02:39,190 --> 00:02:43,670 +انه بده يكون في عنده من ال by electrons تنتيل + +30 +00:02:43,670 --> 00:02:49,030 +يتحولوا الى sigma bonds انا اصبح اتجارة جديدةسيجما + +31 +00:02:49,030 --> 00:02:53,050 +بونز الآن في الـ Chelotropic reactions هدولة two + +32 +00:02:53,050 --> 00:02:56,710 +new سيجما بونز بيكونوا متصلات بنفس الظرر بيكونوا + +33 +00:02:56,710 --> 00:03:01,370 +متصلات بنفس الظرر واضح فهي معنى Chelotropic + +34 +00:03:01,370 --> 00:03:06,310 +reaction وكذلك الحال لو بدى أنظر لهذا هى انا هنا + +35 +00:03:06,310 --> 00:03:12,250 +فى عندى كم بايلكترون اتنين اربعة ستة طالما انا بدى + +36 +00:03:12,250 --> 00:03:16,090 +اعمل two new سيجما بونز اذا هيلزمني من الست هدول + +37 +00:03:16,660 --> 00:03:22,140 +أربعة حيظله اتنين واضح لما انا بقول بده يلزمني + +38 +00:03:22,140 --> 00:03:26,800 +أربعة معناه ذلك حيظل عنده باي واحدة ولذلك انا لو + +39 +00:03:26,800 --> 00:03:31,440 +بده اجي اطلع مثلا هنا هي نعملت sigma bond وهي كمان + +40 +00:03:31,440 --> 00:03:37,880 +sigma bond وظلت ايش بايالمجموع الكلي قداش؟ ستة هنا + +41 +00:03:37,880 --> 00:03:43,900 +كان اربعة ستة فهذا ايضا تشيلو روبيك رياكشن ليش؟ + +42 +00:03:43,900 --> 00:03:46,960 +لان احنا عملنا ال two new sigma bonds at the same + +43 +00:03:46,960 --> 00:03:53,140 +atom الان في مثل هذه التفاعلات اللي مثلا اسمه two + +44 +00:03:53,140 --> 00:03:57,680 +plus two cycle addition انا هنا في عندى التنتين by + +45 +00:03:57,680 --> 00:04:00,900 +electrons او تنتين by bonds وصاروا تنتين sigma + +46 +00:04:00,900 --> 00:04:06,890 +bonds مش فيها مشكلة ماضلش عندىواضح؟ الآن في هذا + +47 +00:04:06,890 --> 00:04:11,110 +النوع خلّيني أقول ال deals elder reaction أنا + +48 +00:04:11,110 --> 00:04:13,830 +المجموع اللي عندى في ال by electron ستة هى اتنين + +49 +00:04:13,830 --> 00:04:20,130 +هى اربعة هى ستة الآن بالتأكيد هيصير عندى اتنين + +50 +00:04:20,130 --> 00:04:24,610 +اربعة واحد من هدول يجى على ال Y عشان ذلك ال Y بطلت + +51 +00:04:24,610 --> 00:04:31,500 +negativeفمافيش يعني أفضل فقد او اكتساب يعني + +52 +00:04:31,500 --> 00:04:34,600 +الإلكترونات بتروح بدون ما نعرف وين راحت لأ هذا + +53 +00:04:34,600 --> 00:04:37,980 +الكلام غير وارد كذلك الحالة في deals under + +54 +00:04:37,980 --> 00:04:43,460 +reaction يعني عندى اتنين اربعة ستة الان هي دي صارت + +55 +00:04:43,460 --> 00:04:49,960 +sigma bond sigma bond و هي ضال عندى bi bond واحدة + +56 +00:04:49,960 --> 00:04:56,330 +واضح؟ولذلك ربما كلكوا ابتذكروا لو ال deals elder + +57 +00:04:56,330 --> 00:05:01,750 +reaction كان مع triple bond مش مع double bond + +58 +00:05:01,750 --> 00:05:06,030 +هتصير + +59 +00:05:06,030 --> 00:05:11,530 +double bond فالأعداد سليمة هذا التصنيف من ناحية + +60 +00:05:11,530 --> 00:05:15,370 +تسميتهم إذا هما ال cellotropic reactions ال two + +61 +00:05:15,370 --> 00:05:18,130 +plus two cycloadditions ال one three dipolar + +62 +00:05:18,130 --> 00:05:21,700 +cycloadditions و deal elder reactionالان من ناحية + +63 +00:05:21,700 --> 00:05:25,780 +ال by electrons يا بيكونوا 2 plus 2 يا 2 plus 4 + +64 +00:05:25,780 --> 00:05:30,300 +يعني كلهم بتصنفوا تحت واحد من هدول التصنف يعني كل + +65 +00:05:30,300 --> 00:05:33,680 +ال cycle additions كل ال cycle additions يا إما من + +66 +00:05:33,680 --> 00:05:38,980 +ناحية ال by electrons 2 plus 2 by electrons يا + +67 +00:05:38,980 --> 00:05:41,160 +بيكونوا 2 plus 4 + +68 +00:05:43,730 --> 00:05:47,430 +أشهر نوع .. أشهر نوع في الـ cycloaddition + +69 +00:05:47,430 --> 00:05:52,070 +reactions الـ 1,3-dipolar cycloaddition reactions + +70 +00:05:52,070 --> 00:05:57,810 +لاحظوا في كيمية الكربون .. في كيمية الكربون يعني + +71 +00:05:57,810 --> 00:06:01,890 +لما يكونوا كل الذرات كربون ربما الـ Diels-Alder + +72 +00:06:01,890 --> 00:06:08,630 +reaction هو الأشهر واضح؟ الآن لو بعض الذرات بطلوا + +73 +00:06:08,630 --> 00:06:14,420 +كربونماذا نسمي التفاعل؟ نعطيه اسم يعني لما يكون + +74 +00:06:14,420 --> 00:06:19,200 +النظام بهذا الشكل و كله كربون، هذا deals ألدر + +75 +00:06:19,200 --> 00:06:24,220 +عادى، الآن لو واحدة من هدولة صارت hetero atom يعني + +76 +00:06:24,220 --> 00:06:29,930 +أكسوجين، نيتروجين، هانان، في أي مكانبنسميه hetero + +77 +00:06:29,930 --> 00:06:34,870 +Diels Alder reaction واضح؟ الان ايش اللى موجود منه + +78 +00:06:34,870 --> 00:06:38,770 +أنثى اكتر فى الدنيا ال Diels Alder اللى كله كربون + +79 +00:06:38,770 --> 00:06:44,390 +ولا ال hetero Diels Alder reaction اللى كله كربون + +80 +00:06:44,390 --> 00:06:48,990 +واضح؟ الان لو اجينا على ال 1,3-dipolar + +81 +00:06:48,990 --> 00:06:53,090 +cycloaddition ايضا ممكن نتخيل 1,3-dipolar + +82 +00:06:53,090 --> 00:07:00,440 +cycloaddition كل ذراتهCarbon او 1,3-dipolar + +83 +00:07:00,440 --> 00:07:03,700 +cycloaddition فيها هيتيرو اتم هان او هان او هان او + +84 +00:07:03,700 --> 00:07:08,600 +هان او هان الان هو المشهور اكتر ال 1,3-dipolar + +85 +00:07:08,600 --> 00:07:12,940 +cycloaddition reactions اللي فيها هيتيرو اتم واضح + +86 +00:07:12,940 --> 00:07:17,200 +بمعنى لو بدنا نقول ال 1,3-dipolar cycloaddition + +87 +00:07:17,200 --> 00:07:22,720 +reactionsاللي فيها كلها carbon الخمس ذرات لو + +88 +00:07:22,720 --> 00:07:26,720 +بتاخدها كنسبة مئوية من مجمل اللي منشور في هذا + +89 +00:07:26,720 --> 00:07:31,200 +المجال هي بالتأكيد أقل من واحد في المية بتأكيد أقل + +90 +00:07:31,200 --> 00:07:34,220 +من واحد في المية تسعة وتسعين في المية من أمثلة ال + +91 +00:07:34,220 --> 00:07:38,640 +one three dipolar cycloaddition reactions هي عبارة + +92 +00:07:38,640 --> 00:07:45,180 +عن إيش؟Hetero atoms ال deals all done موجود فيه + +93 +00:07:45,180 --> 00:07:48,220 +الشغل تاني يعني فيه كتير أنفلة في الدنيا الآن + +94 +00:07:48,220 --> 00:07:51,040 +hetero deals all done reaction لكن بيظل في مجال + +95 +00:07:51,040 --> 00:07:56,500 +الكربون اش موجود اكثر ولذلك في عندنا احنا يعني + +96 +00:07:56,500 --> 00:08:02,200 +موسوعات بالذات في موسوعة اسمهاcomprehensive + +97 +00:08:02,200 --> 00:08:08,120 +heterocyclic chemistry هذه موصوعة عملت في ال 84 و + +98 +00:08:08,120 --> 00:08:11,000 +اتجددت ايضا في التسائلات و يمكن الان اطلع منها + +99 +00:08:11,000 --> 00:08:18,820 +كمان شيء comprehensive heterocyclic + +100 +00:08:18,820 --> 00:08:19,480 +chemistry + +101 +00:08:24,390 --> 00:08:28,390 +هذه موسوعة عامة ال comprehensive heterocyclic + +102 +00:08:28,390 --> 00:08:32,410 +chemistry اللي في ال 84 الآن في موسوعة تانية + +103 +00:08:32,410 --> 00:08:41,310 +Cycloaddition reactions لإيه بدوها Cycloaddition + +104 +00:08:41,310 --> 00:08:52,980 +reactions طبعا إيه بدوهاالان لاحظوا معي العالم كيف + +105 +00:08:52,980 --> 00:08:57,280 +اليوم بيفكر والمفروض نفهم العالم كيف بيفكر جيدا + +106 +00:08:57,280 --> 00:09:02,980 +العالم اليوم مابفكرش انه شخص معين يقوم بكل العمل + +107 +00:09:02,980 --> 00:09:07,580 +هذا الأسلوب يعني أسلوب صعب وعقيد والانسان لايملك + +108 +00:09:07,580 --> 00:09:13,350 +كل المقومات وكل الوقت وكل التخصصولذلك بيسعوا الناس + +109 +00:09:13,350 --> 00:09:17,610 +نحو نظام الموسوعات، يعني اليوم لما انا بدي اجي + +110 +00:09:17,610 --> 00:09:21,310 +احكي عن الـcycloaddition reactions و اقول ان في + +111 +00:09:21,310 --> 00:09:24,950 +عندي one three-dipolar-cycloaddition reactions، في + +112 +00:09:24,950 --> 00:09:27,630 +عندي ozides، في عندي diazo compounds، في عندي + +113 +00:09:27,630 --> 00:09:32,670 +nitrile oxides، nitrile amines، nitrile ylids، كذا + +114 +00:09:32,670 --> 00:09:37,320 +كذاالقال بده بني آدم يجمع كل هذه المعلومات هذا + +115 +00:09:37,320 --> 00:09:42,260 +كثير فهم بيحطوا editor هذا ال editor بيكون مسئول + +116 +00:09:42,260 --> 00:09:47,200 +تحرير هذه الموسوعة هو بيعرف كل الناس المتميزة في + +117 +00:09:47,200 --> 00:09:54,340 +هذا المجال و بيكلفكل إنسان متميز أنه انت حضر جزء + +118 +00:09:54,340 --> 00:09:59,240 +من الموضوع فناس بيحضروا ما كتب عن الأزايد ناس + +119 +00:09:59,240 --> 00:10:01,960 +بيحضروا ما كتب عن النيترال اكسايد عن النيترال اي + +120 +00:10:01,960 --> 00:10:06,740 +means هو بيجمعوا بنسق كل الكلام في الآخر بيطلعوا + +121 +00:10:06,740 --> 00:10:11,720 +بإيش بموسوعة فالموسوعة بيكون لها editor editor + +122 +00:10:11,720 --> 00:10:20,040 +يعني محرر و جواتهاأكتر من مؤلف كل شيء بيكون شخص ما + +123 +00:10:20,040 --> 00:10:25,540 +عمل تأليف في داخله فال editor ليس مؤلفا ال editor + +124 +00:10:25,540 --> 00:10:29,680 +محرر بيعرف مين الناس اللي بتكتب كويس في المجال + +125 +00:10:29,680 --> 00:10:32,660 +اللي عندها أبحاث في المجال بكلفها بتجمع كل + +126 +00:10:32,660 --> 00:10:38,240 +المعلومات في النهاية بيقدروا يعملوا موسوعة عنأي + +127 +00:10:38,240 --> 00:10:44,420 +شغلة ياخدوا المجهود الجماعي خلينا نقول العلمي طبعا + +128 +00:10:44,420 --> 00:10:48,440 +في موسيقات شوية عامة يعني مش علمية زي ما بتشوفوا + +129 +00:10:48,440 --> 00:10:54,800 +على ال internet ال wikipedia مثلا الان هذه مش + +130 +00:10:54,800 --> 00:10:58,200 +ضروري ان كل من كتب فيها متخصص ولذلك بتلاقي ناس + +131 +00:10:58,200 --> 00:11:03,660 +بكتبوا شيء بسيط و بكتبوا هذه نواة او بذرة يمكن ان + +132 +00:11:03,660 --> 00:11:11,630 +تطور بخصوص هالموضوع هذاالان خلّينا نظل في النوع + +133 +00:11:11,630 --> 00:11:16,710 +الأشهر في ال cycle additions اللي هو ال 13-dipolar + +134 +00:11:16,710 --> 00:11:21,850 +cycle addition reactions الحقيقة يعني من أكثر + +135 +00:11:21,850 --> 00:11:25,790 +العلماء اللي صنفوا في هذا الموضوع يعني كان في + +136 +00:11:25,790 --> 00:11:32,620 +أمثلة متناثرة ماكانش ماخد مسمى واضحيعني هنا في + +137 +00:11:32,620 --> 00:11:37,080 +مثال هنا في مثال لكن ماكنش مصنفي بشكل جيد هذا + +138 +00:11:37,080 --> 00:11:40,320 +الموضوع حتى إجا العالم Huizgen + +139 +00:11:44,090 --> 00:11:49,470 +وعمل يعني مقال شهير جمع فيه ال one three dipoles + +140 +00:11:49,470 --> 00:11:54,790 +حط المفهوم بشكل واضح و من هداك الوقت صار هذا يعني + +141 +00:11:54,790 --> 00:11:59,550 +موضوع مستقل الذاته اسمه one three dipolar cycle + +142 +00:11:59,550 --> 00:12:02,970 +additions و بدوا الناس يطوروا فيه إلى أن وصل انه + +143 +00:12:02,970 --> 00:12:07,530 +يكتب و ينعمل فيه إيشموسوعات زي ما اتكلمنا فاريه + +144 +00:12:07,530 --> 00:12:12,350 +ويزجن اول ما انجمع الأشياء البسيطة المتنافرة صاغل + +145 +00:12:12,350 --> 00:12:15,810 +موضوع بصياغة جيدة في ال 1900 + +146 +00:12:26,360 --> 00:12:31,540 +عشان نفهم الموضوع لحظته انت ربما لما اتكلمنا عن ال + +147 +00:12:31,540 --> 00:12:35,020 +one three dipolar cycle addition قلنا انه تلت ذرات + +148 +00:12:35,020 --> 00:12:39,520 +بدهم يتحدوا مع تنتين بدهم يعطينا ايشبدهم يعطونا + +149 +00:12:39,520 --> 00:12:46,080 +حلقة خمسية الان خليني اخد هنا ال one three bipolar + +150 +00:12:46,080 --> 00:12:50,900 +cycle addition و ال deals elder reaction ربما في + +151 +00:12:50,900 --> 00:12:54,700 +ال deals elder reaction كلكوا بتعرفوا ان هذا الجزء + +152 +00:12:54,700 --> 00:12:57,480 +ايش انا كنت اسميه + +153 +00:13:00,570 --> 00:13:07,430 +رابطتين واضح الان الجزء التاني لانه بتفاعل معه انا + +154 +00:13:07,430 --> 00:13:16,210 +بسميه dino file okay الان اسم dino file اجه لانه + +155 +00:13:16,210 --> 00:13:22,290 +بتفاعل مع الدين بمعنى هذا لو أخدنا اي شيء لوحده + +156 +00:13:22,290 --> 00:13:27,800 +مابيكونش اسمه dino file يعني لو جيت اقول انا مثلاC + +157 +00:13:27,800 --> 00:13:31,920 +double bond N ايش رأيكوا فيها بقولها دي بس C + +158 +00:13:31,920 --> 00:13:36,200 +double bond N فقط لا غير الان لو اتفعلت مع دين + +159 +00:13:36,200 --> 00:13:40,440 +بسميها ايش دينوفايل في ال one three dipolar cycle + +160 +00:13:40,440 --> 00:13:45,600 +addition التلت ذرات هدولة عادة بيكونواماخدين موجة + +161 +00:13:45,600 --> 00:13:48,820 +بوسالد أو عاملين Dipolar على الأطراف مع resonance + +162 +00:13:48,820 --> 00:13:52,500 +structures تانية زي ما انتوا شايفين هنا و لذلك + +163 +00:13:52,500 --> 00:13:56,680 +لأنه دائما بتفعلوا من موقع واحد و تلاتة سمنهم ايش + +164 +00:13:56,680 --> 00:14:01,280 +one three dipolar cycle addition الان هذا ديبول + +165 +00:14:01,280 --> 00:14:06,460 +هذا ديبول اللي بده يتفعل معه شو هسميه؟ + +166 +00:14:06,460 --> 00:14:11,000 +Dipolarophile واضح؟ + +167 +00:14:13,800 --> 00:14:18,640 +Dipolarophile وبناء على ذلك لو أنا في عندى سيضة + +168 +00:14:18,640 --> 00:14:21,020 +بال bond M بدي أجي أسألكوا و أقولكوا هل دي + +169 +00:14:21,020 --> 00:14:26,080 +دايينوفايل ولا دايبولاروفايل هي إذا اتفعلت مع + +170 +00:14:26,080 --> 00:14:30,120 +دايبول قلنا لها دايبولاروفايل وإذا اتفعلت مع دايين + +171 +00:14:30,120 --> 00:14:33,320 +قلنا لها دايينوفايل فكلمة دايينوفايل و + +172 +00:14:33,320 --> 00:14:37,820 +دايبولاروفايل هي مش وصف للشيء بذاته لأ هي وصف + +173 +00:14:37,820 --> 00:14:46,350 +للشيء حسب ما إيشحسب ما بتفاعل مع الأصناف التانية + +174 +00:14:46,350 --> 00:14:50,610 +واضحة الفكرة؟ والله واضحلكوا ياه بمثال اجتماعي زي + +175 +00:14:50,610 --> 00:14:55,110 +ما بتكون صبحية هي في النهاية صبحية الآن إذا اتزوجت + +176 +00:14:55,110 --> 00:14:58,630 +أحمد بنقول عنها زوجته أحمد وإذا اتزوجت محمد بنقول + +177 +00:14:58,630 --> 00:15:04,610 +زوجته محمد وهذه نفس الاشي هي double bond إذا صارت + +178 +00:15:04,610 --> 00:15:08,570 +مع الضيينDipolarophile ديينوفايل مع الديبول + +179 +00:15:08,570 --> 00:15:14,450 +ديبولاروفايل واضحة الان لما ابدي اجي احكي عن + +180 +00:15:14,450 --> 00:15:19,170 +ديبولاروفايل او ديينوفايل مجرد double bond هتلاقوا + +181 +00:15:19,170 --> 00:15:24,410 +القمر بسيط لكن ربما امر عليكم وعارفينه لكن ايش + +182 +00:15:24,410 --> 00:15:29,530 +الأشياء اللي عادة بتشتهر انها بتكون ديبولفول ولذلك + +183 +00:15:29,530 --> 00:15:34,530 +لما بنيجي نحكي بتلاقونا اكثر بنركزايش هي ال + +184 +00:15:34,530 --> 00:15:37,770 +dipoles؟ يعني احنا double bond او triple bond + +185 +00:15:37,770 --> 00:15:42,130 +عارفينها، كل double bond او triple bond تصلح في + +186 +00:15:42,130 --> 00:15:45,970 +لحظة من اللحظات ان نقول عنها dipolarophile او + +187 +00:15:45,970 --> 00:15:51,980 +dienophileلكن عندما نأتي إلى الـ dipoles الحقيقة + +188 +00:15:51,980 --> 00:15:56,300 +الـ dipoles أعداد محددة من أشهر الأشياء اللي + +189 +00:15:56,300 --> 00:16:00,560 +موجودة هذا بمعنى إنه في أشياء تانية موجودة يعني + +190 +00:16:00,560 --> 00:16:04,980 +عليها بعض التفاعلات لو كان في عندى تلت ذرات + +191 +00:16:04,980 --> 00:16:12,190 +نيتروجين ورا بعض بنسمي ال .. ال dipole azideأزايد + +192 +00:16:12,190 --> 00:16:16,050 +زي ما في عندكم صوديوم أزايد لاحظوا هذا موجود بشكل + +193 +00:16:16,050 --> 00:16:20,950 +أنه هنا triple bond وهنا زوج الألكترونات ع + +194 +00:16:20,950 --> 00:16:26,170 +الظراهاد يعني موجود بشكل البروباريجيل تعرفوا + +195 +00:16:26,170 --> 00:16:29,810 +البروباريجيل اللي هو موازي للقلل بس ب triple bond + +196 +00:16:29,810 --> 00:16:33,750 +القلل system double bond و بعدين single bond + +197 +00:16:33,750 --> 00:16:34,930 +البروباريجيل + +198 +00:16:37,490 --> 00:16:42,630 +الان من هذا النوع و لاحظوا ان كله في ال triple + +199 +00:16:42,630 --> 00:16:46,590 +bond هذه في احد ال resonance structures خلينا نقول + +200 +00:16:46,590 --> 00:16:51,470 +ان هذا ال resonance structure اللي في ال all octet + +201 +00:16:51,470 --> 00:16:58,800 +يعني كل الذرات اللي موجودين في all octetكل الذرات + +202 +00:16:58,800 --> 00:17:02,600 +اللي موجودين هنا بنطبق عليهم ال octet rule يعني + +203 +00:17:02,600 --> 00:17:07,120 +مافيش ذرة فيها electron sextet مثلا أو ما إلى ذلك + +204 +00:17:07,120 --> 00:17:13,140 +يعني لو كنت بدأ أكمل في هذا المكان مثلا بدأ أكون + +205 +00:17:13,140 --> 00:17:18,340 +حاطط هناهي ال minus وهي ال plus الان اجمع عند ال + +206 +00:17:18,340 --> 00:17:21,800 +nitrogen هاد اتنين اربع ستة ثمانية عند ال nitrogen + +207 +00:17:21,800 --> 00:17:25,680 +هاد اتنين اربع ستة ثمانية عند هاد اتنين اربع ستة + +208 +00:17:25,680 --> 00:17:30,420 +ثمانية فكل الذرات اش اللي موجود حواليها all octet + +209 +00:17:30,420 --> 00:17:35,480 +فموجود هاد ال one three dipoles منها ال azides + +210 +00:17:35,480 --> 00:17:41,080 +الان ال diazo compounds و منها ال diazomethane ال + +211 +00:17:41,080 --> 00:17:45,410 +diazomethane اللي أخدناه بيعمل ال carbeneبالتسخين + +212 +00:17:45,410 --> 00:17:49,090 +او بال photolysis نفسه على حرارة عادية ممكن يعمل + +213 +00:17:49,090 --> 00:17:51,570 +cycle addition دائما ال cycle addition على ذرات + +214 +00:17:51,570 --> 00:17:57,610 +الاش الطرفية ال diazo هيتنتين و ال carbon ال diazo + +215 +00:17:57,610 --> 00:18:02,030 +compounds الان بعدين بيجي عندى نيترال مع ال oxygen + +216 +00:18:02,920 --> 00:18:08,700 +Nitrile Oxide مع الـ Nitrogen Nitrile Amides و + +217 +00:18:08,700 --> 00:18:13,200 +بتشتهر أكتر ال Nitrile Amides في معظم المقالات + +218 +00:18:13,200 --> 00:18:20,680 +باسم Nitrile Amines هكذا تكتب كلمة واحدة يعني في + +219 +00:18:20,680 --> 00:18:24,240 +نسبة كبيرة من المقالات هتلاقوها .. هتلاقوها موجودة + +220 +00:18:24,240 --> 00:18:29,680 +بمسمة Nitrile Amines ال Nitrile Amines هي Nitrile + +221 +00:18:29,680 --> 00:18:36,770 +Amidesوالأشهر انها تكتب ايش نيترال امين النيترال + +222 +00:18:36,770 --> 00:18:42,370 +مع السلفر نيترال سلفايت و النيترال مع الكاربون + +223 +00:18:42,370 --> 00:18:46,390 +بتعرفوا مرة عليكم ممكن في ال reaction الفوسفوراس + +224 +00:18:46,390 --> 00:18:50,070 +اليد لما بيكون عندى ذرة من المجموعة الخامسة او + +225 +00:18:50,070 --> 00:18:55,340 +السادسة موجبة مع الكاربون السالب هذا بنسميه اليدمر + +226 +00:18:55,340 --> 00:18:58,640 +عليكم المصطلح اليد او منها الفوسفوراس اليد اللي + +227 +00:18:58,640 --> 00:19:03,580 +بيمر بالـ vitigre action فهذا نيترال اليد كل هذوله + +228 +00:19:03,580 --> 00:19:09,680 +نوع نوع تاني اللي فيه ال ال نيل تايب يعني زي + +229 +00:19:09,680 --> 00:19:14,560 +القليل الجروب وهنا كله اكتت double bond منها ال + +230 +00:19:14,560 --> 00:19:20,780 +نيترونز cn o minus منها الازوميثين اميدز هى + +231 +00:19:20,780 --> 00:19:26,710 +ازوميثين ازوميثين هى ال نيتروجينمع الكربون ازو + +232 +00:19:26,710 --> 00:19:33,510 +ميثاين وهنا M M Mites هنا ازو ميثاين بزن كربون + +233 +00:19:33,510 --> 00:19:41,130 +سالبة الاتس هنا كربونيلطالما كاربون سالبة إلد، هنا + +234 +00:19:41,130 --> 00:19:46,750 +ثيوكاربونيل طالما كاربون سالبة إلد، الآن هدولة + +235 +00:19:46,750 --> 00:19:50,170 +تقريبا من أشهر ال one in three die bones اللي + +236 +00:19:50,170 --> 00:19:56,640 +موجودين، لو بدكوا تسألوني من الخبرةيعني قداش + +237 +00:19:56,640 --> 00:20:01,820 +أشهرهم لو بدنا نقول انه منشور مثلا مائة ألف مقال + +238 +00:20:01,820 --> 00:20:05,620 +على ال one three bipolar cycle editions ايش أكتر + +239 +00:20:05,620 --> 00:20:09,440 +الأشياء اللي عليها نشرات أكتر الأشياء اللي عليها + +240 +00:20:09,440 --> 00:20:13,960 +نشرات غالبا ال nitrile oxides و ال nitrile amides + +241 +00:20:13,960 --> 00:20:17,360 +يمكن ال nitrile amides أكتر يعني أنا بصنفها نمرة + +242 +00:20:17,360 --> 00:20:21,480 +واحد ال nitrile oxides يمكن تكون نمرة اتنين ال + +243 +00:20:21,480 --> 00:20:27,710 +azides نمرة تلاتةالدايازو كومباونز يمكن تكون نمراء + +244 +00:20:27,710 --> 00:20:33,590 +أربعة ولذلك احنا في نسبة كبيرة من الأمثلة اللي + +245 +00:20:33,590 --> 00:20:36,230 +عندنا هنركز على الـ nitrile amines و ال nitrile + +246 +00:20:36,230 --> 00:20:40,770 +oxides هدول مشهورين نيترال سالفايتس لأ يعني أمثلة + +247 +00:20:40,770 --> 00:20:44,390 +قليلة جدا لكن لو حد بده يستعرض شو الأمثلة اللي في + +248 +00:20:44,390 --> 00:20:47,250 +ال literature و ال reviews اللي في ال literature + +249 +00:20:47,250 --> 00:20:50,630 +عن ال nitrile amines و ال nitrile oxides هتلاحظوا + +250 +00:20:50,630 --> 00:20:51,230 +انها ايش + +251 +00:20:56,310 --> 00:21:03,030 +الآن دعونا نقول ان a13 dipole بيحتمل اكتر من + +252 +00:21:03,030 --> 00:21:06,690 +resonance structure هذا امر طبيعي و احيانا + +253 +00:21:06,690 --> 00:21:10,830 +بتلاحظوا ان في بعض ال resonance structures بيكون + +254 +00:21:10,830 --> 00:21:16,180 +في عنده انبين ان الطرفين polarلكن في كل الأحوال + +255 +00:21:16,180 --> 00:21:20,120 +هدول دائما تفعلهم من موقع واحد و تلاتة و لذلك هم + +256 +00:21:20,120 --> 00:21:25,200 +بتسموه one three dipoles يعني مثلا هذا ال diazo + +257 +00:21:25,200 --> 00:21:29,180 +compounds هاي أحد ال resonance structures لاحظوا + +258 +00:21:29,180 --> 00:21:31,360 +هاي على الطرف و على الطرف الثاني + +259 +00:21:51,150 --> 00:21:55,930 +موجة بسالب على الأطراف لكن في resonance structures + +260 +00:21:55,930 --> 00:22:01,170 +تانية منوعة بإمكان الإنسان يرسم أكتر من + +261 +00:22:05,860 --> 00:22:10,220 +الان لو جينا و سألنا ايش ال mechanism of + +262 +00:22:10,220 --> 00:22:14,320 +cycloaddition + +263 +00:22:14,320 --> 00:22:22,160 +طبعا اتفقنا سابقا بشكل واضح معكم ان + +264 +00:22:22,160 --> 00:22:29,760 +نكتب ناتج معادلةزي ما هو موجود هنا عشان فقط نعرف + +265 +00:22:29,760 --> 00:22:33,400 +نكتب الناتج هنا نيجي نقول هاي هذا زوج إلكترونات + +266 +00:22:33,400 --> 00:22:37,400 +حركه هان أوكي عملنا رابطة هذا هاتو هان أوكي عملنا + +267 +00:22:37,400 --> 00:22:46,300 +هذا حطه على الواعي هذا كلام pathway عشان نفهم كيف + +268 +00:22:46,300 --> 00:22:50,100 +نكتب الناتج نفس الاشي متعودين انت تعمله if deals + +269 +00:22:50,100 --> 00:22:55,880 +other reaction however this is يعنيat all not يعني + +270 +00:22:55,880 --> 00:23:00,560 +ايه ميكانيزم يعني مش هي الميكانيزم لما بنيجي نحكي + +271 +00:23:00,560 --> 00:23:05,240 +عن ميكانيزم اي حد بده يفسر شغلة او بده يحط + +272 +00:23:05,240 --> 00:23:09,220 +ميكانيزم هي الميكانيزم محاول التفسير طب و في + +273 +00:23:09,220 --> 00:23:14,940 +البداية ايش اللي انا بدي افسره واضح لازم يكون عنده + +274 +00:23:14,940 --> 00:23:21,560 +معطيات عشان يفسرها يعني بني ادم نفترضو هذه من + +275 +00:23:21,560 --> 00:23:27,160 +الأخطاء الشائعة اللي يعني الطلاب بيغلطوها من + +276 +00:23:27,160 --> 00:23:32,580 +الأخطاء خلّيني أقول الشائعة للطلاب في فلسفة فهمهم + +277 +00:23:32,580 --> 00:23:37,340 +للميكانزم بيكونوا الحقيقة مش فاهمينها .. مش + +278 +00:23:37,340 --> 00:23:43,800 +فاهمينها إطلاقاإن الميكانيزم هي محاولة تفسير لشيء + +279 +00:23:43,800 --> 00:23:50,100 +معين حصل و تم عنده وبحاول أنا أن أفهم كيف تم هذا + +280 +00:23:50,100 --> 00:23:54,780 +الشيء الآن الطالب في مرات كثيرة بالذات في المراحل + +281 +00:23:54,780 --> 00:23:59,620 +الأولى بيصير يتخيل أن هو لأ هو بيعمل الميكانيزم + +282 +00:23:59,620 --> 00:24:04,180 +تؤدي إلى النتائج الآن السؤال هل الميكانيزم اللي + +283 +00:24:04,180 --> 00:24:09,650 +تؤدي إلى النتائج ولا أنا في الأساس عند نتائجوبحاجة + +284 +00:24:09,650 --> 00:24:14,030 +إلى ميكانيزم عشان افسر هذه النتائج، الاصل ان انا + +285 +00:24:14,030 --> 00:24:19,010 +عندي نتائج وانا بحاجة الى قلية ان افسر هذه + +286 +00:24:19,010 --> 00:24:26,580 +النتائج، يعني مثلا نفترض جريمة قتل تمتتمت جريمة + +287 +00:24:26,580 --> 00:24:31,400 +القتل الآن بيصير الشرطة مطلوب منها انها تعطيني + +288 +00:24:31,400 --> 00:24:35,120 +آلية كيف تم هذا الكلام الآن يوم ما بديت تيجي تعطي + +289 +00:24:35,120 --> 00:24:38,780 +آلية يوم ما بديت تيجي تعطي آلية بديت تجمع ادلة + +290 +00:24:38,780 --> 00:24:48,880 +بمعنى اول اشي بديت تطلع لتوجد جريمة بدون بدون جثة + +291 +00:24:48,880 --> 00:24:54,550 +بدون قتل وانا مافيش عندى ميكانيزم بدون ناتجيعني + +292 +00:24:54,550 --> 00:24:58,230 +إنه حد يقعد يتخيل إنه هذا إجا وعمل هيك وعمل هيك + +293 +00:24:58,230 --> 00:25:02,490 +واتفعل هيك وفي نهاية مافيش عنده ناتج فألف بقى أي + +294 +00:25:02,490 --> 00:25:09,210 +ميكانيزم إن الإنسان يكون إيش فصل ناتج وفصل هذا + +295 +00:25:09,210 --> 00:25:16,440 +الناتج بشكل سليم وصحيح واستطاع إنه يشخصالشكل تبعك + +296 +00:25:16,440 --> 00:25:20,340 +يعني لما انتوا مثلا اخدتوا بالاس أنوان reactions + +297 +00:25:20,340 --> 00:25:26,260 +انه في عندى ممكن تـ rearrangement على سبيل المثال + +298 +00:25:26,260 --> 00:25:30,580 +لو ياطورة مافصلتوش الناتج ولاحظتوا ان الناتج فعلا + +299 +00:25:30,580 --> 00:25:35,760 +اجت .. اجت لـ nucleophile مش مكان ال X في مكان + +300 +00:25:35,760 --> 00:25:40,660 +تاني كان .. قلتوا في rearrangement؟ اه .. اذا + +301 +00:25:40,660 --> 00:25:46,600 +صياغة الكلام بدأ تكون بالشكل القادملأنه انا في + +302 +00:25:46,600 --> 00:25:51,340 +الناتج مثلا في التفاعلات اللي يقول عنها SN1 لأنه + +303 +00:25:51,340 --> 00:25:57,360 +انا في الناتج لاحظت انه ال nucleophile ايجا مش محل + +304 +00:25:57,360 --> 00:26:01,910 +ال X بس تنتج انه في rearrangementما بتكونش صياغة + +305 +00:26:01,910 --> 00:26:06,150 +لأنه في rearrangement إيجي الناتج مش محدد واضحة + +306 +00:26:06,150 --> 00:26:11,850 +هذه الفكرة فأي فهم لميكانيزم بيلزمه أن نكون فهمنا + +307 +00:26:11,850 --> 00:26:17,130 +الناتج جيدا ومواصفات الناتج جيدا و بعدين + +308 +00:26:17,130 --> 00:26:21,890 +الميكانيزم بتيجي محاولة لتفسير إيش كيف تكون هذا + +309 +00:26:21,890 --> 00:26:27,240 +الناتجو عشان هيك لما بنيجي نقول بدنا mechanism of + +310 +00:26:27,240 --> 00:26:30,380 +one three bipolar cycle addition بنقول في الأول + +311 +00:26:30,380 --> 00:26:34,120 +إيش الأشياء اللي لاحظناها على هذا التفاعل بحاجة + +312 +00:26:34,120 --> 00:26:37,840 +إلى تفسير يجب أن نعرفها جيدا و بعدين بنقترح + +313 +00:26:37,840 --> 00:26:41,260 +ميكانيزم بتفسرها مش بنعطيه ميكانيزم و بعدين بنقول + +314 +00:26:41,260 --> 00:26:45,220 +الأشياء بدأت تتبعلها الشغل الأولة للوحظات ال + +315 +00:26:45,220 --> 00:26:51,190 +stereo selectivityإن معظم تفاعلات الـ 1,3-dipolar + +316 +00:26:51,190 --> 00:26:55,430 +cycloadditions are stereoselective إيش معنى هذا + +317 +00:26:55,430 --> 00:27:01,330 +الكلام؟ لو أنا إجيت على الـ Dipolarophile على سبيل + +318 +00:27:01,330 --> 00:27:05,190 +المثال و لاحظت إن هذا الـ Dipolarophile ماخد + +319 +00:27:05,190 --> 00:27:10,810 +Stereochemistry معينة Stereochemistry معينة بمعنى + +320 +00:27:10,810 --> 00:27:20,770 +الـ R1 و R3 فيه جايين على جهةواحدةالان انا لما بدى + +321 +00:27:20,770 --> 00:27:23,430 +الغي اهانه لان في عندى double bond ال rotation + +322 +00:27:23,430 --> 00:27:27,530 +ممنوع مافيش إمكاني .. okay الان لما انا بدى اجي + +323 +00:27:27,530 --> 00:27:34,490 +اشوف الناتج هل يا ترى ال R1 و R3 بيظلهم على جهة + +324 +00:27:34,490 --> 00:27:38,790 +واحدة و ال R2 و R4 على جهة واحدة بمعنى انه في عندى + +325 +00:27:38,790 --> 00:27:42,030 +retention of configuration انه مازالوا على جهة + +326 +00:27:42,030 --> 00:27:47,050 +واحدة و لا بينعكس و بتصير ال R1 على جهة و ال R3 + +327 +00:27:47,050 --> 00:27:53,140 +على جهةفي عندى احتمالين الان مين اللى بده يجاوب + +328 +00:27:53,140 --> 00:27:58,340 +على هذا الكلام التجربة الان التجربة قالت انه + +329 +00:27:58,340 --> 00:28:02,040 +التفاعل stereo selective يعني نفس ال stereo + +330 +00:28:02,040 --> 00:28:06,440 +selectivity اللى بتكون هنا او نفس ال stereo + +331 +00:28:06,440 --> 00:28:10,480 +chemical arrangement خلينا نقول الشكل اللى فيه ال + +332 +00:28:10,480 --> 00:28:14,800 +R1 وR3 ع جهة واحدة فى ال reactant طلعوا على جهة + +333 +00:28:14,800 --> 00:28:18,870 +واحدة فى ال productفالتفعل هنا stereo selective هو + +334 +00:28:18,870 --> 00:28:24,510 +ممكن يطلعهم على جهتين متعاكستين او على جهة واحدة + +335 +00:28:24,510 --> 00:28:29,810 +اختار انهيطلعهم على جهة واحدة ماغيرش في ال stereo + +336 +00:28:29,810 --> 00:28:35,110 +chemistry واضح الفكرة فالتفاعل ضمن هذا المنطق is + +337 +00:28:35,110 --> 00:28:39,190 +stereo selective طبعا ممكن الكلام يكون في نفس ال + +338 +00:28:39,190 --> 00:28:42,390 +one three dipole يعني R1 وR3 في ال one three + +339 +00:28:42,390 --> 00:28:46,670 +dipole جيت على جهة واحدة هل يا طرف الناتج بدهم + +340 +00:28:46,670 --> 00:28:50,410 +يكونوا على جهة واحدة ولا بدهم يبدوا ينعكسوا يصيروا + +341 +00:28:50,410 --> 00:28:56,120 +على جهتينواضح؟ الآن في نهاية بدنا التجربة التجربة + +342 +00:28:56,120 --> 00:29:02,000 +بتقول لأ بيضلوا معاجها واحدة بمعنى هذا بشكل عام + +343 +00:29:02,000 --> 00:29:09,500 +بتكونش واضحة الفكرة؟ الآن هذه معلومة بنحطها في + +344 +00:29:09,500 --> 00:29:15,360 +دالنا بحاجة لإن الميكانيزم الجديدة تفسرهاهذه + +345 +00:29:15,360 --> 00:29:18,580 +المعلومة بحاجة لإن الميكانيزم اللي احنا بدنا + +346 +00:29:18,580 --> 00:29:21,600 +نقترحها لل one three bipolar cycle addition انها + +347 +00:29:21,600 --> 00:29:27,480 +تفسيرها لأنه الميكانيزم تفسير وقائع واضح الفكرة؟ + +348 +00:29:27,480 --> 00:29:35,700 +الآن لاحظوا كمان أشياء في التجربة العملية من ناحية + +349 +00:29:35,700 --> 00:29:41,040 +ال region selectivityradio selective متعلقة كيف + +350 +00:29:41,040 --> 00:29:45,360 +يتكون الناتج كشكل هندسي ان معظم ال one three + +351 +00:29:45,360 --> 00:29:48,020 +-dipolar cycle addition بنسبة كبيرة radioactive + +352 +00:29:48,020 --> 00:29:52,980 +بعضهم لأ صحيح لكن بنسبة كبيرة radioactive ايش + +353 +00:29:52,980 --> 00:29:57,480 +معناه الكلام وهذا الكلام هيتكرر معاكم في ال deals + +354 +00:29:57,480 --> 00:30:04,220 +elder reaction تماماانه انا هنا بفعل double bond و + +355 +00:30:04,220 --> 00:30:08,400 +بتعمل الروابط صحيح؟ الان يا تورا هذي ال double + +356 +00:30:08,400 --> 00:30:14,940 +bond A B لو انا جبت اتنين اتنين هذي من جهة و هذي + +357 +00:30:14,940 --> 00:30:20,360 +من جهة ايش بيمنع اي واحدة انها تقول A double bond + +358 +00:30:24,420 --> 00:30:29,200 +ماذا يمنعها؟ وحتى على حركة الإلكترونات التي + +359 +00:30:29,200 --> 00:30:32,620 +تعودتوا إليها واحد اتنين تلاتة واحد اتنين تلاتة + +360 +00:30:32,620 --> 00:30:33,000 +واحد اتنين تلاتة واحد اتنين تلاتة واحد اتنين تلاتة + +361 +00:30:33,000 --> 00:30:33,820 +واحد اتنين تلاتة واحد اتنين تلاتة واحد اتنين تلاتة + +362 +00:30:33,820 --> 00:30:36,660 +واحد اتنين تلاتة واحد اتنين تلاتة واحد اتنين تلاتة + +363 +00:30:36,660 --> 00:30:38,740 +واحد اتنين تلاتة واحد اتنين تلاتة واحد اتنين تلاتة + +364 +00:30:38,740 --> 00:30:44,160 +واحد اتنين تلاتة واحد اتنين تلاتة واحد اتنين تلاتة + +365 +00:30:44,160 --> 00:30:51,220 +واحد اتنين تلاتة واحد اتنين تلاتة + +366 +00:30:51,220 --> 00:30:58,740 +واحد اتنهؤلاء الايزو مارز استيريو؟ ما اسمهم؟ + +367 +00:30:58,740 --> 00:31:02,320 +انانشو + +368 +00:31:02,320 --> 00:31:06,280 +مارز الانانشو مارز و الدياستيريو مارز هم منوع من + +369 +00:31:06,280 --> 00:31:08,320 +الايزو مارز الاستيريو هؤلاء الايزو مارز + +370 +00:31:08,320 --> 00:31:12,700 +الاستركترال يعني الايزو مارز الاستركترال اللي فيهم + +371 +00:31:12,700 --> 00:31:13,280 +عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة + +372 +00:31:13,280 --> 00:31:15,580 +عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن + +373 +00:31:15,580 --> 00:31:16,620 +عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة + +374 +00:31:16,620 --> 00:31:16,840 +عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن + +375 +00:31:16,840 --> 00:31:23,960 +عبارة عن عبارة عن عبصح ولا لأ هاي ترتيب الذرات A,B + +376 +00:31:23,960 --> 00:31:30,320 +,Z,Y,X الان B,A,Z,Y,X different arrangement of + +377 +00:31:30,320 --> 00:31:34,320 +atoms ولا لأ اذا هدوله معنى ratio isomers they are + +378 +00:31:34,320 --> 00:31:39,740 +structural isomers they are structural isomers + +379 +00:31:39,740 --> 00:31:46,900 +الان يا ترى بتكون هذا او هذا في مرات كتيرة التفاعل + +380 +00:31:46,900 --> 00:31:51,840 +بيختار واحد منهمفي نسبة كبيرة التفاعل radio + +381 +00:31:51,840 --> 00:31:55,900 +selective لكن أحيانا بيطلع mixture يعني يمكن يتكون + +382 +00:31:55,900 --> 00:31:59,180 +هذا بنسبة ستين هذا بنسبة أربعين هذا بنسبة سبعين + +383 +00:31:59,180 --> 00:32:06,340 +هذا بنسبة تلاتين واضح فالجواب أن التفاعل أو most + +384 +00:32:06,340 --> 00:32:09,160 +of the 1,3-dipolar cycload addition are radio + +385 +00:32:09,160 --> 00:32:12,340 +selective and some of them are not selective يعني + +386 +00:32:12,340 --> 00:32:20,800 +they give both productsواضحة الفكرة؟ الآن ليش مرات + +387 +00:32:20,800 --> 00:32:25,720 +بيختار ناتج من الناتجين و بيطلعه و مرات بيطلعله + +388 +00:32:25,720 --> 00:32:30,040 +mixture of products؟ يوم بدي أحط ميكانيزم، + +389 +00:32:30,040 --> 00:32:36,040 +الميكانيزم بدي تقدر تفسر هذا الكلامالان في موضوع + +390 +00:32:36,040 --> 00:32:41,240 +الـ mechanism صحيح انه المتفق عليه بشكل عام بين + +391 +00:32:41,240 --> 00:32:46,440 +العلماء انه ممكن نفكر باتجاهين ممكن نفكر ب + +392 +00:32:46,440 --> 00:32:51,850 +concerted mechanism يعني one step mechanism اوبـ + +393 +00:32:51,850 --> 00:32:55,550 +two step mechanism، ممكن نسميها stepwise mechanism + +394 +00:32:55,550 --> 00:32:59,430 +أو by radical mechanism، هتلاحظوله أسماء كثيرة، + +395 +00:32:59,430 --> 00:33:04,790 +يعني نفكر بالتفاعل على إنه بتتم إما بخطوة واحدة أو + +396 +00:33:04,790 --> 00:33:10,330 +بتتم بإيش؟ بخطوة تانيةالـ Concerted Mechanism عشان + +397 +00:33:10,330 --> 00:33:16,610 +نفهمها جيدا نشوف ال orbitals اللي بده تتفاعل كيف + +398 +00:33:16,610 --> 00:33:20,310 +ال orbitals بده تجرب على بعض و كيف هذي ال orbitals + +399 +00:33:20,310 --> 00:33:24,010 +بده تعمل interactions ماخدين طبعا بعين الاعتبار + +400 +00:33:24,010 --> 00:33:27,470 +فهمنا السابق لل orbitals و كيف بيكون ال + +401 +00:33:27,470 --> 00:33:32,370 +interaction ما بين ال orbitals of the samePhase + +402 +00:33:32,370 --> 00:33:36,970 +يعني بدنا ننتبه لأن ال phases لحظة ما بده يتم + +403 +00:33:36,970 --> 00:33:40,370 +التفاعل تكون سليمة و بدنا ننتبه أنه عادة اللي + +404 +00:33:40,370 --> 00:33:45,390 +بتفاعل هم من جهة معلومه من جهة تانية بمعنى واحد + +405 +00:33:45,390 --> 00:33:48,990 +عنده إلكترونات والتاني عنده نقص في الإلكترونات + +406 +00:33:48,990 --> 00:33:54,390 +عشان يكتمل عمل الروادر الآن لو أجينا لل one three + +407 +00:33:54,390 --> 00:33:59,930 +dipole طالما عندي أنا تلاتة atomsأذا بقدر ارسم كام + +408 +00:33:59,930 --> 00:34:03,830 +orbital تلاتة molecular orbitals ال molecular + +409 +00:34:03,830 --> 00:34:08,870 +orbitals لو طلعنا عليهم بشكل جيد هلاحظنهم بهذا + +410 +00:34:08,870 --> 00:34:16,950 +الشكل اول orbital ال phases كلها ايش بتكون على جهة + +411 +00:34:18,020 --> 00:34:22,780 +واحدة الان بعد هيك و بتقدروا تتخيلوا طبعا اذا + +412 +00:34:22,780 --> 00:34:26,380 +انتوا متذاكرين كأنه انا عندها نموجة وماقطعتش + +413 +00:34:26,380 --> 00:34:33,420 +اطلاقا من خلال ايش هذه ال orbitals الان ال orbital + +414 +00:34:33,420 --> 00:34:39,440 +التاني بهذا الشكل بده يكون و لو تخيلنا ان في عندنا + +415 +00:34:39,440 --> 00:34:41,100 +نموجة كام ند بدها تعمل + +416 +00:34:46,050 --> 00:34:57,350 +و لو جينا على ال orbital التالت حيكون بهذا الشكل و + +417 +00:34:57,350 --> 00:35:03,970 +كام node حيكون عندنا؟ 10 تل واضح؟ الآن كل + +418 +00:35:03,970 --> 00:35:06,830 +الإلكترونات اللي عندى can buy electron في ال one + +419 +00:35:06,830 --> 00:35:11,090 +three dipole؟أربعة وبناء على ذلك لو انا بدأ احط + +420 +00:35:11,090 --> 00:35:15,510 +اتنين هنا و اتنين هنا هذا هيظل فاضي اذا هذا هو ال + +421 +00:35:15,510 --> 00:35:20,860 +homo وهذا هو ال homoهي الـ HOMO وهي الـ HOMO + +422 +00:35:20,860 --> 00:35:23,720 +Highest Occupied Molecular Orbital و Lowest + +423 +00:35:23,720 --> 00:35:29,220 +Unoccupied Molecular Orbital الان لو اجينا للـ + +424 +00:35:29,220 --> 00:35:34,680 +Dipolarophile الـ Dipolarophile فى بس ذرتين وبناء + +425 +00:35:34,680 --> 00:35:38,460 +على ذلك كام Molecular Orbital هعمل فى؟ تنين، يا ما + +426 +00:35:38,460 --> 00:35:46,380 +بيكون ال phases على جهة واحدة أو على جهتين + +427 +00:35:48,080 --> 00:35:52,860 +متعاكستين الان كل الالكترونات اتنين هحطهم هنا اذا + +428 +00:35:52,860 --> 00:35:59,980 +هي ال homo وهي ال lomo الان بعد هيك لما بدى يصير + +429 +00:35:59,980 --> 00:36:06,040 +تفاعل بين هذول الطرفين الاصل مين بتفاعل homo مع + +430 +00:36:06,040 --> 00:36:10,860 +lomo هل يا تورا لو جربنا هذا ال homo مع هذا ال + +431 +00:36:10,860 --> 00:36:15,380 +lomo بتفعلوا ولا لا اخر انا شرط التفاعل ال phases + +432 +00:36:16,620 --> 00:36:21,940 +اكونوا زي بعض هنا ال phases متعاكسة و هنا ال + +433 +00:36:21,940 --> 00:36:26,340 +phases متعاكسة اذا هذا ال homo بنفع يتفعل مع هذا + +434 +00:36:26,340 --> 00:36:30,460 +ال homo بالتأكيد طب لو اجيت لل homo لل + +435 +00:36:30,460 --> 00:36:36,560 +dibolarophile ال phases جهة واحدة و ال homo هنا + +436 +00:36:36,560 --> 00:36:45,340 +طلعت الأطراف التفاعل على الأطراف الطرفين خضر و + +437 +00:36:45,340 --> 00:36:51,890 +الطرفينأيضًا هذا الـ Lomo و هذا الـ Homo و هذا الـ + +438 +00:36:51,890 --> 00:36:57,130 +Lomo ممكن يتفاعلوا فالاحتمالين من ناحية ال phases + +439 +00:36:57,130 --> 00:37:02,710 +سالمين مافيش فيهم ولا مشكلة التفاعل ممكن يتم بين + +440 +00:37:02,710 --> 00:37:06,450 +الـ Homo للـ Dipole مع الـ Lomo للـ Dipolarophile + +441 +00:37:06,450 --> 00:37:10,290 +أو الـ Lomo للـ Dipole مع الـ Homo للـ + +442 +00:37:10,290 --> 00:37:15,230 +Dipolarophileمن ناحية ال phases الأمرين سليمين طيب + +443 +00:37:15,230 --> 00:37:20,090 +لما يكون عندى احتمالين ان هو الاحتمال اللى بيكون + +444 +00:37:20,090 --> 00:37:27,550 +اقرب و بيتم عادة اقل طاقة ممتاز اللى بينهم فرق اقل + +445 +00:37:27,550 --> 00:37:31,330 +في الطاقة و هذا بيعتمد عن نوع المادتين هنا لما + +446 +00:37:31,330 --> 00:37:35,130 +ابتدي اجي اطلع هذه الطاقة تبعت هذا و تبعت هذا قداش + +447 +00:37:35,130 --> 00:37:42,410 +ال difference بينهم قليل هذاأكبر، إذا لو أنا في + +448 +00:37:42,410 --> 00:37:45,970 +هذا المثال تحديدًا بدي أقول أي واحد اللي بده يتهم + +449 +00:37:45,970 --> 00:37:54,310 +هذا الأزرق واضح؟ الآن لو افترضنا في مركب تاني أن + +450 +00:37:54,310 --> 00:37:57,970 +هدول ارتفعوا لفوق أو هدول انخفضوا لتحت أسفل قتهم + +451 +00:37:57,970 --> 00:38:02,150 +ممكن يكون هذا الهم مع هذا الهم هما الأقرب إذا أي + +452 +00:38:02,150 --> 00:38:08,420 +اتنين يكونوا أقرب هذه عمليةبتحددها طبيعة الـ + +453 +00:38:08,420 --> 00:38:11,740 +Dipole و طبيعة الـ Dipolarophile يعني مالهاش جواب + +454 +00:38:11,740 --> 00:38:14,580 +محدد يعني ممكن مرة homoladipole مع + +455 +00:38:14,580 --> 00:38:18,360 +homoladipolarophile و مرة تانية homoladipole مع + +456 +00:38:18,360 --> 00:38:22,160 +homoladipolarophile ليش؟ لأن هذا إله energies + +457 +00:38:22,160 --> 00:38:27,660 +معينة هيجي في مكان ما هنا لما بيكون لتحت بيكون هذا + +458 +00:38:27,660 --> 00:38:33,080 +الاحتمال طب لو هذا ارتفع كتيريعني لو اتخيلته انه + +459 +00:38:33,080 --> 00:38:37,480 +مركب تاني و اجه ال homo و ال lomo تعونوا بهذا + +460 +00:38:37,480 --> 00:38:46,400 +الشكل هاي homo و هاي lomo قارنوا + +461 +00:38:46,400 --> 00:38:53,040 +هتلاحظوا ان هذا ال homo مع هذا ال lomo بعيد هذا ال + +462 +00:38:53,040 --> 00:38:59,140 +homo مع هذا ال lomo قريب فالفكرة بتعتمد على طبيعة + +463 +00:39:00,120 --> 00:39:04,580 +الـ Dipole والـ Dipolar Phi وين موقعهم بالإنرجي + +464 +00:39:04,580 --> 00:39:09,420 +هذه لا تمثل مشكلة في كل الأحوال الأمرين إيش مالهم + +465 +00:39:09,420 --> 00:39:17,260 +الأمرين من ناحية ال phases صحيحين الآن أي أن كان + +466 +00:39:17,260 --> 00:39:21,660 +اللي بده يتفاعل لما أجربهم مع بعض هيبدأوا يقتربوا + +467 +00:39:21,660 --> 00:39:28,280 +بهذا الشكل و ال similar phases تيجي على بعضواضح + +468 +00:39:28,280 --> 00:39:35,340 +هنا هتلاحظوا شغلة هتلاحظوا شغلة انه من هذه المنطقة + +469 +00:39:35,340 --> 00:39:41,660 +هتبدأ مشكلة الريجيو كيميستري بمعنى انه لو انا + +470 +00:39:41,660 --> 00:39:46,740 +اتخيلت هذا ثابت لو انا اتخيلت هذا ثابت زي ما هو في + +471 +00:39:46,740 --> 00:39:51,780 +على اي جهة بتكون فاعله اللي تحت خليني اقول ناخد + +472 +00:39:51,780 --> 00:39:59,250 +هذا الأخضر مع هذاالفاضي اه الان لو جبت هذا بطريقة + +473 +00:39:59,250 --> 00:40:06,730 +معينة بحيث ان هاي A وهاي B الان لو جبت A الخضرة + +474 +00:40:06,730 --> 00:40:14,550 +الغامقة حطيتها هنا هيجي ال B الفاضي معاكس لها ولا + +475 +00:40:14,550 --> 00:40:20,250 +لأ؟ هيظبط انها تيجي A هنا وB هنا طب لو جبت ال B + +476 +00:40:20,250 --> 00:40:23,630 +الخضرة + +477 +00:40:23,630 --> 00:40:31,040 +الغامقةحطيتها هان هتيجي ال a اذا الاحتمالين + +478 +00:40:31,040 --> 00:40:37,000 +هيظبطوا واضح يعني لو حد ماسك هدولة بيقول بدي اجرب + +479 +00:40:37,000 --> 00:40:44,460 +احط اخطر و فارق لو حط ال a هنا و ال b هنا زبط معاه + +480 +00:40:44,460 --> 00:40:48,060 +و لو حط ال b هنا و ال a هنا زبط معاه اذا في هذه + +481 +00:40:48,060 --> 00:40:52,360 +الحالة ال two regio isomers in principle كفكرة + +482 +00:40:52,360 --> 00:40:57,870 +عامة are possibleالاتنين من ناحية ال phases ممكن + +483 +00:40:57,870 --> 00:41:02,530 +ينتجوا يعني + +484 +00:41:02,530 --> 00:41:05,890 +لما واحدة تقول بتحط هنا ال a و هنا ال b بنقولها + +485 +00:41:05,890 --> 00:41:10,710 +إيش هي ال a عليها أخضر غامج و ال b ماعليهاش زبطت + +486 +00:41:10,710 --> 00:41:15,390 +ولا لأ واحدة تانية بتقولها أنا بتحط هنا ال b و هنا + +487 +00:41:15,390 --> 00:41:18,450 +ال a ال b برضه ليش لإن كل واحدة عليها + +488 +00:41:21,110 --> 00:41:25,030 +فز موجب وفز سالب وبالتالي الاحتمالين من ناحية + +489 +00:41:25,030 --> 00:41:29,570 +المبدأ ممكنين في ال radiochemistry خلينا شوية من + +490 +00:41:29,570 --> 00:41:33,470 +ال radiochemistry هدول لما يبدأوا يقتربوا من بعض + +491 +00:41:33,470 --> 00:41:38,370 +لاحظوا ان هذا ما زال double bond وطالما ان هو + +492 +00:41:38,370 --> 00:41:43,390 +double bond الدوران حوالين ال double bond مسموح + +493 +00:41:43,390 --> 00:41:48,070 +ولا ممنوع؟ممنوع و بناء على ذلك لو انتوا انا كنتوا + +494 +00:41:48,070 --> 00:41:54,470 +متخيلين مثلا زي ما كتبنا R1 و R3 هذا بدون تفاعل ال + +495 +00:41:54,470 --> 00:41:59,550 +R1 و ال R3 تبعونه بتغيروا اه الآن بدنا نرجع لسؤال + +496 +00:41:59,550 --> 00:42:03,790 +من ال organic القديمة من ال organic القديمة هو + +497 +00:42:03,790 --> 00:42:10,050 +الدوران وين كان ممنوعفي ال double bond و في الحلقة + +498 +00:42:10,050 --> 00:42:13,670 +ممتاز جدا يعني الدوران حول ال double bond ممنوع + +499 +00:42:13,670 --> 00:42:18,710 +والدوران حول الحلقة ممنوع الآن اللي بيصير بهذه + +500 +00:42:18,710 --> 00:42:23,110 +الحالة لحظة ما انا بدي اجيب هدولة و يجربوا هنا في + +501 +00:42:23,110 --> 00:42:27,890 +عندي double bond مسموح المجمعتين يلفوا؟ لأ بتظل + +502 +00:42:27,890 --> 00:42:32,010 +تجرب تجرب تجرب لحد ما ال orbitals يقتربوا تماما + +503 +00:42:32,010 --> 00:42:37,240 +شبكوا ال orbitals اتحولت من ايش؟من double bond + +504 +00:42:37,240 --> 00:42:43,800 +ممنوع الدوران فيها إلى حلقة ممنوع الدوران فيها إذا + +505 +00:42:43,800 --> 00:42:48,120 +بهيك بتتم ال stereo chemistry بنقدر نفهم ليش في ال + +506 +00:42:48,120 --> 00:42:51,180 +stereo chemistry التفاعلات هذه كانت stereo + +507 +00:42:51,180 --> 00:42:55,840 +selective لأنه أنا حقيقة لما بجرب ال orbitals ع + +508 +00:42:55,840 --> 00:43:01,700 +بعض بتحول من double bond ممنوع الدوران حولها إلى + +509 +00:43:01,700 --> 00:43:08,330 +حلقة أيضا ممنوع الدوران حولهاواضح الفكرة مامريتش + +510 +00:43:08,330 --> 00:43:13,450 +بلحظة انه صار عندى single bond حرة بالامكان انه + +511 +00:43:13,450 --> 00:43:20,270 +يتم حولها ايش دوران واضح؟ وهذا الحقيقة اللى .. + +512 +00:43:20,270 --> 00:43:26,750 +اللى بتام كله هو اللى بنسميه احنا concerted + +513 +00:43:26,750 --> 00:43:31,690 +mechanism يعني جبناهم مع بعض وعملنا ال cyclic + +514 +00:43:31,690 --> 00:43:37,610 +intermediate و تم التفاعلهذا الميكانيزم اخترحت من + +515 +00:43:37,610 --> 00:43:43,550 +العالم الهوزجانو عشان ذلك ناس كتير بيقولوا انا + +516 +00:43:43,550 --> 00:43:47,330 +اهوزج ال mechanism او ال concerted mechanism اللي + +517 +00:43:47,330 --> 00:43:51,190 +هي ببساطة one step mechanism in which two bonds + +518 +00:43:51,190 --> 00:43:56,230 +are formed at the same time و لاحظوا زي ما شفنا + +519 +00:43:56,230 --> 00:44:02,370 +انه لو أخدنا homodipol و homodipolar file من ناحية + +520 +00:44:02,370 --> 00:44:10,440 +ال phases كلههذا صح هذا صح هذا صح هذا صح كله ممكن + +521 +00:44:10,440 --> 00:44:15,500 +ايش اللي بيحكم القمر ال energy difference واضح + +522 +00:44:15,500 --> 00:44:19,140 +اللي بيحكم القمر ال energy difference الان لاحظوا + +523 +00:44:19,140 --> 00:44:22,260 +لو هنا كانت هذه A وهذه B + +524 +00:44:25,780 --> 00:44:30,300 +اذا حد خطهم هيك a و b ال orbital صح ولا لأ صح طب + +525 +00:44:30,300 --> 00:44:35,760 +لو حد لفهم برضه صح اذا هذه من ناحية ال orbitals + +526 +00:44:35,760 --> 00:44:39,220 +الاحتمالين صح عشان هيك لسه احنا لحد تلان ما + +527 +00:44:39,220 --> 00:44:44,640 +جوابناش على سؤال ال radiochemistry و لو حد لف + +528 +00:44:44,640 --> 00:44:50,870 +هدولة برضه بيضلوا صح ولا لأ بيضلوا صحلما نقلبه لو + +529 +00:44:50,870 --> 00:44:53,790 +افترضنا ان هنا A و هنا B في النهاية عند اتنين + +530 +00:44:53,790 --> 00:44:59,870 +متعاكسات او لو كتبنا B و A برضه صح برضه صح هيكون + +531 +00:44:59,870 --> 00:45:05,770 +واحد منهم موجب والتاني سالم فضمن هذا الكلام ال two + +532 +00:45:05,770 --> 00:45:11,290 +regioisomers are still possible يعني بيكون فهمنا + +533 +00:45:11,290 --> 00:45:16,490 +ليشالـ Stereoselectivity لأن أنا كان عندي Double + +534 +00:45:16,490 --> 00:45:23,370 +bond R1 R3 و اتحولت إلى حلقة فماصارش فرصة لإيش + +535 +00:45:23,370 --> 00:45:32,210 +لادوران و لتغيير الـ Stereochemistry واضح؟ + +536 +00:45:32,210 --> 00:45:35,970 +هذا الكلام تقريبا نفسه موجود هنا بصور أصغر و بوضح + +537 +00:45:35,970 --> 00:45:39,720 +ال energy difference مافيش فيه ولا شيء جديدالان + +538 +00:45:39,720 --> 00:45:45,720 +بنجي ل ميكانيزم تاني stepwise ميكانيزم او by + +539 +00:45:45,720 --> 00:45:50,820 +radical ميكانيزم على اساس انه فيه الكترونين او two + +540 +00:45:50,820 --> 00:45:55,460 +step ميكانيزم وهذه الميكانيزم الحقيقة اقترحت من + +541 +00:45:55,460 --> 00:45:58,460 +العالم firestone + +542 +00:46:01,650 --> 00:46:07,230 +الميكانيزم ممكن تكون ..الميكانيزم ممكن تكون by + +543 +00:46:07,230 --> 00:46:11,930 +radical mechanism بمعنى أنا بإمكاني أتخيل .. أنا + +544 +00:46:11,930 --> 00:46:15,090 +بإمكاني أتخيل أن هنا في إلكترونات و طبعا هنا في + +545 +00:46:15,090 --> 00:46:18,950 +أندي إلكترون اتنين تلاتة أربعة بإمكاني أتخيل أن + +546 +00:46:18,950 --> 00:46:24,590 +هذا و هذا عملوا إيش؟ رابطة طبعا هدول هيعملوا زوج + +547 +00:46:24,590 --> 00:46:32,250 +إلكترونات يصير فوق إيش؟ ال Yظل عندى كام إلكترون؟ + +548 +00:46:32,250 --> 00:46:37,390 +إتنين هدولا الإلكترونين بيسكروا في خطوة ثانية + +549 +00:46:37,390 --> 00:46:42,730 +عشانكى احنا قولنا by radical تمام؟ الآن هنا بتجينا + +550 +00:46:42,730 --> 00:46:49,170 +مشكلة انه إذا أنا صرت عامل رابطة يعني لغيت هذه ال + +551 +00:46:49,170 --> 00:46:55,430 +by bond هنا أنا بقول انه ال rotation ممنوع هذه + +552 +00:46:55,430 --> 00:47:01,170 +صارت single صار عندى possible rotationطالما هذه + +553 +00:47:01,170 --> 00:47:05,130 +صارت single معناه ذلك صار عندى possible rotation + +554 +00:47:05,130 --> 00:47:08,310 +طالما هذا ال rotation possible إذا ال R اللي + +555 +00:47:08,310 --> 00:47:11,730 +اتنتين كانوا لقدام ممكن واحدة منهم تصير للخلف + +556 +00:47:11,730 --> 00:47:17,130 +والتانية للأمام وارد طب و بيضلوا يلف بمعنى أنه + +557 +00:47:17,130 --> 00:47:20,630 +طالما هى عندى مجمعتين كانوا مربوطات بال double + +558 +00:47:20,630 --> 00:47:24,550 +bond على جهة واحدة هى المجمعتين مربوطات بال double + +559 +00:47:24,550 --> 00:47:29,080 +bond على جهة واحدة صارت ال double singleصار دوران + +560 +00:47:29,080 --> 00:47:33,060 +دائم و أبدي حوالين ال single point ممكن في لحظة من + +561 +00:47:33,060 --> 00:47:36,160 +اللحظات تكونوا على جهة و باللحظة على الجهة + +562 +00:47:36,160 --> 00:47:43,910 +المعاكسة الآن إذا هذا كمل التسكيروهم على نفس الجهة + +563 +00:47:43,910 --> 00:47:48,130 +بيعطينا retention of configuration وإذا كملت + +564 +00:47:48,130 --> 00:47:52,050 +تسكيرهم على جهتين متعاكستين بيعطينا inversion of + +565 +00:47:52,050 --> 00:47:56,930 +configuration إذا هنا كام stereo isomers are ممكن + +566 +00:47:56,930 --> 00:48:03,250 +عنده من ناحية المبدأ؟ اتنين طبعا ممكن الناس في + +567 +00:48:03,250 --> 00:48:10,270 +بداية التفكير يفكروا بالشكل القاتل يقولوا التجربة + +568 +00:48:10,270 --> 00:48:16,090 +شو بتقول؟انه بيطلع واحد و ال stereo selective okay + +569 +00:48:16,090 --> 00:48:20,950 +طيب شو حكى السن تجه؟ انها ميكانيزم مش صحيحة اه + +570 +00:48:20,950 --> 00:48:27,650 +الان لاحظوا مباشرة ازملتكم .. شو اسمك؟ سهل اه سهل + +571 +00:48:27,650 --> 00:48:32,110 +كحلوت بتقول والله انه ال mechanism مش صحيحة بس + +572 +00:48:32,110 --> 00:48:36,790 +انتبهوا لنقطة دائما انتبهوا لنقطة دائما و اتعلموها + +573 +00:48:36,790 --> 00:48:39,350 +للحياة يوم ما ييجي + +574 +00:48:43,020 --> 00:48:51,100 +أقول فتوة مثلا نقدر بسهولة نقول أن الفتوة مش صحيحة + +575 +00:48:51,100 --> 00:48:56,560 +لأنه ليس من أهل الفتوة وليس من أهل العلم لكن يوم + +576 +00:48:56,560 --> 00:49:02,430 +ما ييجي عالم كبيرقاعد و دارس ال mechanisms و فهمان + +577 +00:49:02,430 --> 00:49:06,430 +و ماخد دكتوراه و بيخرج طلاب دكتوراه و يقترح + +578 +00:49:06,430 --> 00:49:11,650 +mechanisms بهذا الشكل طب هو يعني هلجيت هذه الشغلة + +579 +00:49:11,650 --> 00:49:18,510 +دارت إلك و مادارتش إله انتبهوا + +580 +00:49:18,510 --> 00:49:24,950 +معي صحيه ولا لأ تماما زي لما بيجي المفتى بيحكي + +581 +00:49:24,950 --> 00:49:33,740 +فتوة كان إنسان بيجيبله طرف حديثو مباشرة بيبدأ يغلط + +582 +00:49:33,740 --> 00:49:37,240 +في مين؟ في المفتى الفهمان أو في العالم الكبير طب و + +583 +00:49:37,240 --> 00:49:41,040 +أنت إذا عرف الطرف الحديث المفروض المفتى أو العالم + +584 +00:49:41,040 --> 00:49:44,080 +الكبير عرف كل الأحاديث و كل الأيات و كل قواعد + +585 +00:49:44,080 --> 00:49:47,540 +الفقه و القياس و الإجماع و ما إلى ذلك و طلع منهم + +586 +00:49:47,540 --> 00:49:53,190 +فتوةواضح ولا لا؟ يعني هالشغلة انت انتبهتي لإنه + +587 +00:49:53,190 --> 00:49:56,550 +بيطلع ناتجين هو ما انتبهلهاش firestone .. + +588 +00:49:56,550 --> 00:50:01,110 +firestone عالم physical و عالم كبير بنقوله طيب إذا + +589 +00:50:01,110 --> 00:50:07,050 +انت المطلوب منك تفسرلي التجربة .. التجربة بتقول + +590 +00:50:07,050 --> 00:50:13,470 +إنه بيطلع فقط هذا الناتجالميكانيزم تبعتك بهذا + +591 +00:50:13,470 --> 00:50:18,130 +الشكل بتطلع ناتجين معقول أنه يحط ميكانيزم تناقض + +592 +00:50:18,130 --> 00:50:23,590 +التجربة ويقول هي ميكانيزم؟ واضح؟ هذا زي شرطة في + +593 +00:50:23,590 --> 00:50:27,830 +عنده قتيل واحد في الجريمة بيحط ميكانيزم وبيقول ان + +594 +00:50:27,830 --> 00:50:35,720 +قتله خمسة هو الواحد بيحط آليةإتناقض التجربة طيب + +595 +00:50:35,720 --> 00:50:40,260 +إذا اللي بيصير .. إيش التفسير يا سيد؟ Firestone + +596 +00:50:40,260 --> 00:50:44,180 +عشان نحترم العالم و ما نقولش عنه أنه بغلط + +597 +00:50:44,180 --> 00:50:48,480 +Firestone كان في عنده تفسير أنه بيطلع بس هذا + +598 +00:50:48,480 --> 00:50:52,640 +التفسير اللي عنده من خلال حسابات فيزيائية هو + +599 +00:50:52,640 --> 00:50:58,160 +بيشتغل عليها بيقول أول ما اتكون ال by radical هذا + +600 +00:50:58,160 --> 00:51:05,150 +شايفينه؟ عنده أحد احتماليناما انه يعمل cyclization + +601 +00:51:05,150 --> 00:51:18,270 +صح يسكر او انه يعمل rotation وبعد + +602 +00:51:18,270 --> 00:51:21,410 +ال rotation cyclization + +603 +00:51:32,020 --> 00:51:34,880 +جداش الساعة نص واحدة و نص + +604 +00:52:17,610 --> 00:52:25,390 +والله ثقة مفقودة هالهم اسبوع بيقولوا نظام تمانية + +605 +00:52:36,860 --> 00:52:42,280 +يقولون ليبعت السلامة بالرد فقلت أنا والله ما نالني + +606 +00:52:42,280 --> 00:52:47,120 +خسر وهل يتجافى عني الموت ساعة إذا مات جافى عني + +607 +00:52:47,120 --> 00:52:53,850 +الأسر والضر يقولونmain بالعراقي مريضة فقلت ايه + +608 +00:52:53,850 --> 00:52:58,950 +ليتني كنت الطبيب المداوية يقولون ليلة بالعراقي + +609 +00:52:58,950 --> 00:53:07,530 +ليلة بالعراقي مريضة يقولون ومن + +610 +00:53:07,530 --> 00:53:16,150 +أصعب القول الاستعانة على المعصية بمشيئة اللهوقالوا + +611 +00:53:16,150 --> 00:53:20,410 +لو شاء الرحمن وما عبدناهم يعني احنا ربنا رايدنا + +612 +00:53:20,410 --> 00:53:27,990 +نعبد الأصنام شوفوا كيف فالقول سهل يعني بنقول البني + +613 +00:53:27,990 --> 00:53:31,910 +آدم ماتدخنش بيقول إذا ربنا رايد مانديش أدخن بيقول + +614 +00:53:34,960 --> 00:53:40,500 +خلّينا نوضّح المشكلة الأساسية في الـmechanisms of + +615 +00:53:40,500 --> 00:53:45,080 +the reaction كانت مشكلة الـstereochemistry وكان + +616 +00:53:45,080 --> 00:53:48,720 +واضح عندنا أنه في الـmechanism أو الـconcerted + +617 +00:53:48,720 --> 00:53:53,340 +mechanism فسرنا ال retention of stereochemistry من + +618 +00:53:53,340 --> 00:53:56,860 +خلال أننا انتقلنا من double bond ممنوع الدوران + +619 +00:53:56,860 --> 00:54:01,650 +فيها إلى حلقة ممنوعة الدوران فيهاالان لما نفكر بال + +620 +00:54:01,650 --> 00:54:05,690 +by radical mechanism مجرد ما صارت هذه single bond + +621 +00:54:05,690 --> 00:54:08,950 +صار في عندى possible rotation معناه ذلك هدول + +622 +00:54:08,950 --> 00:54:12,670 +المجموعات ممكن يتغيروا من جهة واحدة لجهتين لو + +623 +00:54:12,670 --> 00:54:16,030 +كملنا ال cyclization كام ناتج متوقع عندنا اتنين + +624 +00:54:16,030 --> 00:54:22,830 +طبعا firestone بفكر بهذا الكلام انهانا اول ما صار + +625 +00:54:22,830 --> 00:54:26,090 +عندى هذه الرابطة و by radical هذا ال by radical + +626 +00:54:26,090 --> 00:54:30,450 +ممكن يعمل cyclization بهذا الشكل و ممكن يعمل + +627 +00:54:30,450 --> 00:54:34,770 +rotation followed by cyclization الان بالحسابات + +628 +00:54:34,770 --> 00:54:39,370 +اللى كان بيعملها firestone بيقول ان الزمن اللى + +629 +00:54:39,370 --> 00:54:45,590 +لازملا الـ cyclization أقل كتير من الزمن اللي لازم + +630 +00:54:45,590 --> 00:54:51,510 +لل rotation ولذلك هو بيقول انه بالحسابات تبعته هذا + +631 +00:54:51,510 --> 00:54:56,010 +بيسكر قبل ما يلوف إذا كان بيسكر قبل ما يلوف لغ هذا + +632 +00:54:56,010 --> 00:55:02,050 +الاحتمال إذا طلع الناتج حط تفسير واضح الفكرة + +633 +00:55:02,050 --> 00:55:06,950 +فطالما ان هو بيقول قبل ما يلحق يلوف بيكون قمل + +634 +00:55:06,950 --> 00:55:13,120 +cyclizationاذا هدول المجمعتين اتغيروا ولا اتظلهم + +635 +00:55:13,120 --> 00:55:19,180 +على جهة واحدة؟شوفنا ايش تفسير firestorm لretention + +636 +00:55:19,180 --> 00:55:23,600 +of configuration ان هو بيقول بالظبط تحديدا ان the + +637 +00:55:23,600 --> 00:55:30,040 +compound cyclizes before it rotates تمام؟ بناء على + +638 +00:55:30,040 --> 00:55:34,900 +حسابات معينة الآن بنضل انه هذه محاولة تفسير و هذه + +639 +00:55:34,900 --> 00:55:39,100 +محاولة تفسير ايش اللي مقبول اكثر؟ اه بدلاش ننسى + +640 +00:55:39,100 --> 00:55:43,620 +اليوم صار في اجهزة كتير بتجسس ال free radicals اذا + +641 +00:55:43,620 --> 00:55:48,700 +اتكونوااللي هو تحديدًا جهاز إيش الـ ESR الـ + +642 +00:55:48,700 --> 00:55:54,540 +electron spin resonance هالياطورة في فعلًا بنشوف + +643 +00:55:54,540 --> 00:55:58,240 +free radicals بالـ 1,3-dipolar cycloaddition + +644 +00:55:58,240 --> 00:56:05,500 +reactions الواقع إنه كل تفاعل حقيقة بحاجة إلى أن + +645 +00:56:05,500 --> 00:56:12,010 +يدرس بشكل منفصليعني فكرة أنه نتخيل أنه نقول هذه ال + +646 +00:56:12,010 --> 00:56:16,290 +mechanism عامة تصلح لكل ال one three bipolar cycle + +647 +00:56:16,290 --> 00:56:20,730 +addition reactions يعني فكرة غير سليمة من ناحية + +648 +00:56:20,730 --> 00:56:27,370 +بحتها ولذلك كل التفاعل يجب أن يدرس ويفهم هل يا ترى + +649 +00:56:27,370 --> 00:56:30,550 +أنا شوفت فيه free radicals ولا ماشوفتش فيه free + +650 +00:56:30,550 --> 00:56:37,190 +radicals اليوم بنقدر نقول القاتل من مجملمن مجمل ما + +651 +00:56:37,190 --> 00:56:43,370 +تم دراسته بتفاصيل من تفاعلات ربما انه فعلا ما يزيد + +652 +00:56:43,370 --> 00:56:49,390 +عن 95% من ال 1,3-dipolar cycle addition reactions + +653 +00:56:49,390 --> 00:56:53,590 +اللي دورست ثبت انها مشيت ب concerted mechanism لكن + +654 +00:56:53,590 --> 00:56:58,390 +في امثلةفعلا شافوا فيها ال free radical mechanisms + +655 +00:56:58,390 --> 00:57:04,790 +ومشيت بال free radicals واضح؟ طبعا بكل الأحوال هذا + +656 +00:57:04,790 --> 00:57:08,430 +الكلام ان انا قاعد بشوف stereo chemistry وقاعد + +657 +00:57:08,430 --> 00:57:12,350 +بشوف جهاز ESR وقاعد بشوف free radical كل هذا + +658 +00:57:12,350 --> 00:57:17,690 +الكلام مابمشيش مع الفكرة البسيطة بتاعت سنتين فكرة + +659 +00:57:17,690 --> 00:57:22,210 +أكمل المعادلة ان ال mechanism of the reactionانه + +660 +00:57:22,210 --> 00:57:27,690 +سهم اتنين تلاتة هذا الكلام غير مقبول اطلاقا من + +661 +00:57:27,690 --> 00:57:31,350 +طالب سنة رابعة انه يقول انه this is a mechanism of + +662 +00:57:31,350 --> 00:57:36,090 +deal الكلام نفسه بالظبط وعشانك مش هنشرحه مرة ثانية + +663 +00:57:36,090 --> 00:57:39,630 +في deals elder reaction بمعنى في deals elder + +664 +00:57:39,630 --> 00:57:49,430 +reaction هنرسم orbitals ونشوف ان هدولة ممكن يعملوا + +665 +00:57:50,240 --> 00:57:55,120 +الـ Concerted Mechanism هذا احتمال و الاحتمال + +666 +00:57:55,120 --> 00:57:59,740 +الثاني انه احنا هاي ال system هذا و هاي هذا لان + +667 +00:57:59,740 --> 00:58:03,740 +هاي free radical هان و free radical هان هذه صارت + +668 +00:58:03,740 --> 00:58:09,080 +رابطة و هنا صارت الرابط التاني ضايل التالتة تنعمل + +669 +00:58:09,080 --> 00:58:15,740 +وبالتالي ممكن هذا و هذاساكروا مع بعض و يكون عندى + +670 +00:58:15,740 --> 00:58:19,580 +free radical طبعا نفس ال issue ال deals elder + +671 +00:58:19,580 --> 00:58:23,200 +reaction دُرس كل تفاعل بتفاعله اللى بده يحكي عن + +672 +00:58:23,200 --> 00:58:26,220 +تفاعل ميكانيزم بده يدخله على التجربة و يقعد في + +673 +00:58:26,220 --> 00:58:32,830 +المختبر تمام؟النتيجة ان ال deals under reaction + +674 +00:58:32,830 --> 00:58:38,930 +مرات بيمشي بـ concerted mechanism و مرات بيمشي ب + +675 +00:58:38,930 --> 00:58:43,410 +free radical mechanism يعني مافيش جواب لكل ال + +676 +00:58:43,410 --> 00:58:47,330 +deals under reaction اللي في الكون انهمconcerted + +677 +00:58:47,330 --> 00:58:50,150 +mechanism و لا كل ال deals elder reaction اللي في + +678 +00:58:50,150 --> 00:58:54,030 +ال cones انهم by radical mechanism بعض التفاعلات + +679 +00:58:54,030 --> 00:58:58,070 +فعلا بتمشي زي هيك وبعضها بتمشي ب concerted + +680 +00:58:58,070 --> 00:59:01,870 +mechanism فبصير الحقيقة ان كل تفاعل بحاجة إلى + +681 +00:59:01,870 --> 00:59:07,010 +دراسة ايش تفصيلية لكن نسبة ال free radical + +682 +00:59:07,010 --> 00:59:11,070 +mechanism في ال deals elder reaction اكتر كتير + +683 +00:59:11,070 --> 00:59:15,960 +منهافي الـ 1,3-dipolar cycloadditions ولذلك لو + +684 +00:59:15,960 --> 00:59:20,240 +كانوا ناس بيحكوا بمنطق العمومية فبتلاقوه بمنطق + +685 +00:59:20,240 --> 00:59:23,520 +العمومية بيقولوا most of the 1,3-dipolar + +686 +00:59:23,520 --> 00:59:26,960 +cycloadditions reactions proceed by a concerted + +687 +00:59:26,960 --> 00:59:30,600 +mechanism معظمها بتمشي ب concerted mechanism في ال + +688 +00:59:30,600 --> 00:59:36,580 +deals altered أقل في نسبة لبأس بها فعلا مثبتة + +689 +00:59:36,580 --> 00:59:43,170 +وموجودة وبتمشي بإيش؟بي راديكال ميكانيزم الان ال + +690 +00:59:43,170 --> 00:59:47,590 +homework اللى انا بدي اكو تتعبوا فيه حقيقة انه من + +691 +00:59:47,590 --> 00:59:53,570 +الأشياء اللى اتدرست اجيبولي مثال على ال one three + +692 +00:59:53,570 --> 00:59:57,980 +dipolar cycloadditionأو على ال deals elder + +693 +00:59:57,980 --> 01:00:03,800 +reaction مشي ب by radical mechanism يعني شخص بيعمل + +694 +01:00:03,800 --> 01:00:08,360 +mechanistic study ودرس وبيقول هي ال ESR و هي شفت + +695 +01:00:08,360 --> 01:00:13,860 +ال free radicals و ما إلى ذلك و تجيبولنا و تشوفوا + +696 +01:00:13,860 --> 01:00:18,110 +كيف ال mechanistic study هي في نهاية علمكامل + +697 +01:00:18,110 --> 01:00:22,710 +متكامل بدنا مثال على one three dipolar + +698 +01:00:22,710 --> 01:00:27,150 +cycloaddition reaction او Diels alder reaction مش + +699 +01:00:27,150 --> 01:00:33,110 +باش بال by radical mechanism او stepwise mechanism + +700 +01:00:33,110 --> 01:00:39,250 +كل الكلام هذا اللي احنا جوابناه بتعلق بأي نقطة + +701 +01:00:39,250 --> 01:00:45,850 +نقطة ال stereo selectivity لسه ماحكيناش عنالراديو + +702 +01:00:45,850 --> 01:00:48,990 +سيلكتيفتي لسه ماحكيناش عن ال radio selectivity + +703 +01:00:48,990 --> 01:00:56,410 +الان في ال radio selectivity ال orbitals لما بنيجي + +704 +01:00:56,410 --> 01:01:00,230 +بنعملها و طبعا هذا الكلام الأن أكتر شئ بنعمل + +705 +01:01:00,230 --> 01:01:02,850 +حسابيا يعني على ال computer اللي بديه يعمل + +706 +01:01:02,850 --> 01:01:06,210 +molecular orbitals إذا بديتوا تاخدوا في ال quantum + +707 +01:01:06,210 --> 01:01:11,190 +برامج الالكمبيوتر مجرد ما الإنسان يرسم الشكل بيقدر + +708 +01:01:11,190 --> 01:01:16,650 +يحسب ال .. إيش ال .. ال orbital energies وقدش ال + +709 +01:01:16,650 --> 01:01:22,710 +size بيكون لكل orbital تمام؟ الآن في عندي قاعدة + +710 +01:01:22,710 --> 01:01:29,110 +بتقول قاعدة عامة في الكيميا و عامة في الحياة + +711 +01:01:29,110 --> 01:01:37,510 +العامة في الحياة إيش بتقول؟ الكباربلعبوا مع الكبار + +712 +01:01:37,510 --> 01:01:47,410 +والصغار بلعبوا مع الصغار الغنية كتير بجعدوا مع بعض + +713 +01:01:47,410 --> 01:01:53,550 +والفجرة كتير بجعدوا مع بعض، مظبوط ولا لأ؟ طبعا مين + +714 +01:01:53,550 --> 01:02:00,880 +أسعد أكثر؟انتبهوا معي مين أسعد أكثر الغنية كتير + +715 +01:02:00,880 --> 01:02:05,600 +لما بيقعدوا مع بعض ولا الفقر كتير لما بيقعدوا مع + +716 +01:02:05,600 --> 01:02:11,960 +بعض الله أعلم كل واحد له وجهة نظر في الموضوع يعني + +717 +01:02:11,960 --> 01:02:18,460 +أنا بأذكر أن سمعت لأحد الناس اللي كانوا يعني مدراء + +718 +01:02:18,460 --> 01:02:24,140 +أعمال أو مرافقين للفنان الكبير بزمانه عبد الحليم + +719 +01:02:24,140 --> 01:02:30,630 +حافظبتعرفوا كيف لما كان اسم كبير ومشهور وحفلة وكل + +720 +01:02:30,630 --> 01:02:35,870 +علية القوم جاعدين بيسمعوله رجال ونسوان هو الآن محط + +721 +01:02:35,870 --> 01:02:42,870 +الأنظاركلها فبنهاية حفلة الساعة تنتين تلاتة مروح + +722 +01:02:42,870 --> 01:02:47,610 +معاه بالسيارة مر ببساطة على اتنين عمال نظافة + +723 +01:02:47,610 --> 01:02:52,290 +بسيطين جدا تعبوا من الشغل بنظفوا بالليل و بالانهار + +724 +01:02:52,290 --> 01:02:57,790 +هناك فقعدوا هيك جانب حيطة و حطوا زيتون مع شوية خبز + +725 +01:02:57,790 --> 01:03:02,650 +و قاعدين بيأكلوا و بينبسطوا فجاله واجف نزل عندهم + +726 +01:03:02,650 --> 01:03:07,170 +صار يتطلع فيهم و يبكي قالوا انا نفسي اكون زي هدول + +727 +01:03:09,030 --> 01:03:13,410 +مرات كثير حتى الحاكم الكبير اللى بيقعدش اللى مع + +728 +01:03:13,410 --> 01:03:18,590 +حاكم كبير ومعظم جلسات الحكام جلسات ليست لخير الدين + +729 +01:03:18,590 --> 01:03:24,070 +ولا الدنيا بشكل عام بتمنوا انهم يكونوا يعيشوا + +730 +01:03:24,070 --> 01:03:28,730 +الحياة البسيطة اللى بعيشوها الناس الأناد القاعدة + +731 +01:03:28,730 --> 01:03:35,690 +العامة بالحياة حكيناها بالمثل بيصيغوها الطيور على + +732 +01:03:35,690 --> 01:03:44,470 +أشكالهاتقعوا، مظبوط ولا لأ؟ ب solubility بنصيغها؟ + +733 +01:03:44,470 --> 01:03:52,150 +ب like dissolves؟ بالكيميا بنصيغها؟ soft soft، + +734 +01:03:52,150 --> 01:03:56,650 +hard hard؟ يعني هي ليست قاعدة كيميا، بقدر ما هي + +735 +01:03:56,650 --> 01:04:06,010 +قاعدة إيش؟ حياةخل الكبار مع بعض والصغار مع بعض حتى + +736 +01:04:06,010 --> 01:04:10,070 +اللي بيشتغلوا كمان يلحموا مواسير ساقل عليهم يلحموا + +737 +01:04:10,070 --> 01:04:13,770 +مصورتين كبار و ال steel تبعهم عريض مع بعض بسهولة + +738 +01:04:13,770 --> 01:04:18,010 +لكن أصعب شغلة عنده لو كان بده في مصورة كبيرة يلحم + +739 +01:04:18,010 --> 01:04:21,690 +مصورة صغيرة أول ما يحط النار المصورة الصغيرة بتسيح + +740 +01:04:21,690 --> 01:04:25,450 +و الكبيرة لسه ما السخنتش و بيصير هذا علم بحد ذاته + +741 +01:04:26,150 --> 01:04:31,810 +في النهاية الأشياء مع إيش متشابهتها وحتى الأخلاق + +742 +01:04:31,810 --> 01:04:37,390 +يوم إذا بعضهم لبعض نقضون المرء على دينه خليله اه + +743 +01:04:37,390 --> 01:04:43,500 +اليوم لو انتوا بتيجوا تتطلعوا هاي هذاهدول شكل + +744 +01:04:43,500 --> 01:04:49,920 +orbitals طلع هذا كبير وهذا ايش صغير الان لما انا + +745 +01:04:49,920 --> 01:04:54,400 +بدي اجي احط هدول يا تورا لو حطيتهم بهذا الشكل خليت + +746 +01:04:54,400 --> 01:04:59,160 +الكبير هنا والصغير هنا لاحظوا ما ال carbon هذا + +747 +01:04:59,160 --> 01:05:03,980 +اللي حامله ال methyl و ال co2 methyl اتصلت وين بال + +748 +01:05:03,980 --> 01:05:09,480 +nitrogen صح ولا لأ طيب من ناحية ال phases بقدر + +749 +01:05:09,480 --> 01:05:15,670 +اعمل العكسمن ناحية ال phases يعني ان احط زي هيك + +750 +01:05:15,670 --> 01:05:21,290 +ارسم هنا ال phase الصغير و ارسم هنا الكبير و اخلي + +751 +01:05:21,290 --> 01:05:28,870 +هذا خلوه ثابت زي ما هو اخلي هذه بهذا الشكل و هذه + +752 +01:05:28,870 --> 01:05:32,330 +بهذا + +753 +01:05:32,330 --> 01:05:38,750 +الشكل و احط هنا المجمعتين المثل و ال CO2 مثل الان + +754 +01:05:38,750 --> 01:05:44,010 +هذا هو نفس هذا ولا لأنفسه تماما ال phases معكوسة + +755 +01:05:44,010 --> 01:05:49,750 +طيب الآن لما اجي اقول هدولة هيك بتحدوا مع بعض و + +756 +01:05:49,750 --> 01:05:55,030 +بيكونوله مركب هذه ال carbon فيه متصلة وين بال + +757 +01:05:55,030 --> 01:06:01,990 +نيتروجين طيب و هدولة من ناحية ال phases هاي + +758 +01:06:01,990 --> 01:06:07,590 +ال carbon هادي بتحدوا تطلعول ال phases سالمين ولا + +759 +01:06:07,590 --> 01:06:14,040 +لأ من ناحية ال phases الاحتمالين موجودينوبناء على + +760 +01:06:14,040 --> 01:06:20,920 +ذلك الناتجين متوقعين لكن من ناحية ال hard hard و + +761 +01:06:20,920 --> 01:06:25,320 +ال soft soft او اللي ممكن نصيغه orbitals of the + +762 +01:06:25,320 --> 01:06:29,960 +same size interact اي الاحتمالات المفضلة؟ هذا + +763 +01:06:29,960 --> 01:06:35,620 +الاحتمالليش؟ لأن هدولة الصغار أتوا مع بعض والكبار + +764 +01:06:35,620 --> 01:06:40,420 +أتوا مع بعض واضح؟ فصح من ناحية similarity of the + +765 +01:06:40,420 --> 01:06:45,760 +phases اتنين ممكنين بس من ناحية ال orbital size + +766 +01:06:45,760 --> 01:06:50,540 +فيهم واحد مفضل على التانيوبناء على ذلك بهذا + +767 +01:06:50,540 --> 01:06:54,420 +التفاعل اللي متوقع فيه ناتجين هاي هذه ال carbon + +768 +01:06:54,420 --> 01:06:58,280 +اللي أنا رسمتها بالأحمر وهيها أنا رسمتها بالأحمر + +769 +01:06:58,280 --> 01:07:02,480 +مرة متصلة بال nitrogen و مرة متصلة بال carbon ال + +770 +01:07:02,480 --> 01:07:06,820 +orbitals بيقولوا أي المركبات اللي بدوا يطلع + +771 +01:07:10,540 --> 01:07:13,900 +ال orbital size إذا اللي حكى من إيش ال + +772 +01:07:13,900 --> 01:07:19,280 +radiochemistry الآن هيجي البعض يقول طب انت قولت ال + +773 +01:07:19,280 --> 01:07:22,940 +radiochemistry اف مرات كتيرة اتفعوا radio + +774 +01:07:22,940 --> 01:07:29,720 +selective اف مرات لأ بطلع خليط اذا ال orbitals + +775 +01:07:29,720 --> 01:07:35,300 +كانت تقريبا نفس الحجم + +776 +01:07:38,770 --> 01:07:42,570 +هيطلع خليط، بطل يفرق عندك، يعني وقت إيش بيصير + +777 +01:07:42,570 --> 01:07:46,350 +الفرق أو بتصير الانتقائية أو بتصير ال region + +778 +01:07:46,350 --> 01:07:51,070 +selectivity لما يكون كل مكان عندك difference كبير + +779 +01:07:51,070 --> 01:07:56,690 +في ال orbital size هان و هانواضح الفكرة؟ لما يكون + +780 +01:07:56,690 --> 01:08:00,970 +في عندى انا كبير و صغير و انا كبير و صغير وجدت في + +781 +01:08:00,970 --> 01:08:05,910 +الصين عندى نسبة ال ratio selectivity عالية لكن لو + +782 +01:08:05,910 --> 01:08:11,650 +ماكنش الامر كذلك ممكن انه يطلع عندكم ايش خلاص لو + +783 +01:08:11,650 --> 01:08:17,190 +انتوا بتحسبوا جيدا على البرامج الحسوبية هنلاحظ بعد + +784 +01:08:17,190 --> 01:08:22,810 +شوية لما نستعرض الأمثلة انه مرات بيكتب one ratio + +785 +01:08:22,810 --> 01:08:27,350 +isomerو مرات بكتب خليط من التنين و بحط النسبة + +786 +01:08:27,350 --> 01:08:32,970 +المئوية بإمكانك وجدها أي مثال منهم تاخدوا و تدخلوا + +787 +01:08:32,970 --> 01:08:37,530 +على الكمبيوتر و تشوفوا كيف شكل ال orbitals ليش مرة + +788 +01:08:37,530 --> 01:08:42,700 +طبعا النتائج اللي هنعرضها هي نتائج تجربيةنتائج + +789 +01:08:42,700 --> 01:08:47,180 +ايش؟ تجارب ليش مرة بيقول طلع بس هذا و مرة طلعوا + +790 +01:08:47,180 --> 01:08:52,500 +التانين؟ هو يعكس التجربة ما تفسير التجربة أكيد أنه + +791 +01:08:52,500 --> 01:08:57,840 +في أحوال ال orbital size فيها مختلف و بناء على ذلك + +792 +01:08:57,840 --> 01:09:04,000 +لما بنجي .. بنعمل التفاعل بيكون شكل أفضل من الشكل + +793 +01:09:04,000 --> 01:09:09,260 +التاني واضحة الفكرة؟ هذا بالنسبة لإيش؟لـ Radio + +794 +01:09:09,260 --> 01:09:14,060 +Selectivity ليش مرات بتنوجد مرات بتنوجدش بتنوجد + +795 +01:09:14,060 --> 01:09:18,300 +لما يكون عند ال orbital size مختلف في ال dipole و + +796 +01:09:18,300 --> 01:09:21,140 +ال dipolarophile واجدها الكبير بروح مع الكبير + +797 +01:09:21,140 --> 01:09:26,920 +الصغير مع الصغير بتكون ناتج واحد لكن لو كان ال + +798 +01:09:26,920 --> 01:09:32,420 +orbital size نوعا ما متشابه هيتكون mixture of + +799 +01:09:32,420 --> 01:09:33,420 +products + +800 +01:09:36,710 --> 01:09:41,650 +بهيك تقريبا بنكون خلصنا موضوع ال mechanism of 1,3 + +801 +01:09:41,650 --> 01:09:44,610 +-dipolar cycloaddition وشوفنا كيف ال mechanisms + +802 +01:09:44,610 --> 01:09:49,230 +بتجاوب على فكرة ال stereo selectivity و ال radio + +803 +01:09:49,230 --> 01:09:53,150 +selectivityالان لو اجينا على ال 1,3-dipoles انا + +804 +01:09:53,150 --> 01:09:57,750 +قولتلكوا اشهر ال 1,3-dipoles ال nitrile oxides + +805 +01:09:57,750 --> 01:10:03,070 +الان ال nitrile oxides في الغالب بنعمللها اش اسمه + +806 +01:10:03,070 --> 01:10:06,950 +generation يعني مابتكونش موجودة ع شكل nitrile + +807 +01:10:06,950 --> 01:10:12,150 +oxide لأ انا ب .. بيكون عندي precursor مرت عليكوا + +808 +01:10:12,150 --> 01:10:16,370 +كلمة precursor يعني مادة بطول منها ال nitrile + +809 +01:10:16,370 --> 01:10:18,170 +oxide بريه + +810 +01:10:20,660 --> 01:10:26,440 +هذا ال precursor بحضره أثناء التفاعل بعمل + +811 +01:10:26,440 --> 01:10:29,260 +generation of nitrile oxide مجرد ما عملت له + +812 +01:10:29,260 --> 01:10:33,820 +generation reactive بتفاعل بلاقي ال double bond + +813 +01:10:33,820 --> 01:10:37,600 +المناسبة بتفاعل مالاجهاش double bond المناسبة ايش؟ + +814 +01:10:38,540 --> 01:10:42,620 +بتفعل مع نفسه بعمل diaper مع نفسه يعني الـ Nitrile + +815 +01:10:42,620 --> 01:10:47,100 +Oxide الـ Nitrile Oxide إذا صرنا عاملين له ال + +816 +01:10:47,100 --> 01:10:52,240 +generation و مالجاش ال double bond المناسبة يتفاعل + +817 +01:10:52,240 --> 01:10:56,360 +معها ع طول بروح بتفاعل مع نفسه تنين من هذا بيعطينا + +818 +01:10:56,360 --> 01:11:06,290 +R C double bond M O و أنا R C double bond MO بيكون + +819 +01:11:06,290 --> 01:11:09,910 +minus plus بهذا الشكل هذا مركب اسمه فيوركسان هذا + +820 +01:11:09,910 --> 01:11:16,270 +دايما اتطلعوا المكونات تبعته RCNO RCNO فيوركسان + +821 +01:11:16,270 --> 01:11:16,950 +بنسميه + +822 +01:11:21,470 --> 01:11:26,330 +ملاقاش مع مين يتفاعل ايش بيعمل الـ dimerization + +823 +01:11:26,330 --> 01:11:30,210 +الان مش موضوع ال dimer احنا هنحطله double bond + +824 +01:11:30,210 --> 01:11:33,990 +مناسبة يتفاعل معها و في كل الأحوال لو اشتغلتوا في + +825 +01:11:33,990 --> 01:11:37,550 +مستقبل حياتكم بـ nitrile oxides هتلاحظوا انه جد ما + +826 +01:11:37,550 --> 01:11:43,410 +تحطوله الا جزء منه يعمل ايش؟ dimer و ال dimer انا + +827 +01:11:43,410 --> 01:11:47,690 +رغبان ولا مابديش اياه؟ انا مابديش اياه الان طب كيف + +828 +01:11:47,690 --> 01:11:52,750 +بنحضره؟إذا بدأنا من ال أكزيم ال الديهايد أكزيم كنا + +829 +01:11:52,750 --> 01:11:56,570 +بنعرف الأكزيم هذا الأكزيم لو عملنا له chlorination + +830 +01:11:56,570 --> 01:12:01,310 +ب chlor .. ب chloroform و في طرق طبعا تانية غير + +831 +01:12:01,310 --> 01:12:05,130 +غاز لكلور انا كثير اشتغل فيه كنت استعمل نفس غاز + +832 +01:12:05,130 --> 01:12:08,410 +لكلور يعنى بس في طرق تانية كتيرة + +833 +01:12:08,410 --> 01:12:11,650 +anichlorosaccinimide وغيره وغيرته المهم + +834 +01:12:11,650 --> 01:12:16,820 +chlorination هذا ال chlorination ببدل ال H هذهب CL + +835 +01:12:16,820 --> 01:12:23,740 +شو صار هذا المركب اسمه اكلوروكزيم صار اكلوروكزيم + +836 +01:12:23,740 --> 01:12:29,760 +اذا هذا البريكير صار اكلوروكزيم او مرات بيسموه + +837 +01:12:29,760 --> 01:12:33,340 +هيدروكسامويل اكلورايد يعني هتقرؤ الاسمين + +838 +01:12:33,340 --> 01:12:36,380 +هيدروكسامويل + +839 +01:12:36,380 --> 01:12:38,640 +اكلورايد + +840 +01:12:39,650 --> 01:12:43,190 +سواء كلوروكزيم او هيدروكسامويل كلورايت هذا البري + +841 +01:12:43,190 --> 01:12:47,990 +كيرسر الان هذا البري كيرسر اثناء التفاعل بمجد عليه + +842 +01:12:47,990 --> 01:12:51,510 +تري إيث الأمين تري إيث الأمين باس ايش هيسحب منه + +843 +01:12:51,510 --> 01:12:57,270 +HCl هيكون النيترال اكسيد بيلاقى ال double bond + +844 +01:12:57,270 --> 01:13:05,050 +بتفعل معاها اذا شفنا كيف احنا بنحضن النيترال اكسيد + +845 +01:13:05,050 --> 01:13:11,690 +مبتدئين من ايشبنفع نقول مبتدئين من ال الديهايد ما + +846 +01:13:11,690 --> 01:13:16,790 +هو ال الديهايد نفسه بيصير أكزيم واضح؟ + +847 +01:13:16,790 --> 01:13:21,430 +الديهايد، أكزيم، كلور أكزيم، نيترال أكسايد، بعدين + +848 +01:13:21,430 --> 01:13:27,290 +بضيف له ال double bond هذه الطريقة لتحضير ال + +849 +01:13:27,290 --> 01:13:32,270 +precursor لنيترال أكسايد ممكن من ال nitro + +850 +01:13:32,270 --> 01:13:32,970 +compounds + +851 +01:13:36,030 --> 01:13:42,410 +RCH2NO2 لو فعلوه مع فين ال isocyanate بتعملوا بهذا + +852 +01:13:42,410 --> 01:13:49,730 +الشكل و بعدين بيكون ايش نيترال اكسيد هذا اكتر لل + +853 +01:13:49,730 --> 01:13:53,010 +ال الفاتك كومباونز هذا اكتر لل الاروماتك كومباونز + +854 +01:13:53,010 --> 01:13:57,590 +يعني ان ال R تكون الفاتك غالبا من هذا المصار او + +855 +01:13:57,590 --> 01:14:01,590 +استيل ال R تكون الاروماتك غالبا من هذا المصار طبعا + +856 +01:14:01,590 --> 01:14:08,070 +اي المصارات الأشهرهذا المصار يعني هذا أشهر مصار لل + +857 +01:14:08,070 --> 01:14:11,410 +generation of nitrile oxide اللي هي الديهيد أكزيمي + +858 +01:14:11,410 --> 01:14:19,030 +كلور أكزيمي نيترال أكسيد okay لو أجينا لنيترال + +859 +01:14:19,030 --> 01:14:24,090 +سالفايد كيف بنعمله generation بنجيب هذا المركب و + +860 +01:14:24,090 --> 01:14:29,290 +بنسخنه شوية لحظة هذا المركب مجرد ما نسخنه هنا في + +861 +01:14:29,290 --> 01:14:33,270 +عندكم هذه و هذه بدأ تيجي هنا يعني بده يفقد جزء إيش + +862 +01:14:34,290 --> 01:14:39,790 +-CO2 ثانو أكسيد الكربون أعطاني نيترال سالفايد واضح + +863 +01:14:39,790 --> 01:14:45,110 +فالنيترال سالفايد من هذا المركب اللى موجود أمامنا + +864 +01:14:45,110 --> 01:14:50,050 +بالتسخين بيفقد ثانو أكسيد الكربون وبيعطيني نيترال + +865 +01:14:50,050 --> 01:14:59,310 +سالفايد طيب لو بدنا نيترال اميز تقريبا الفكرة + +866 +01:14:59,310 --> 01:15:03,390 +الأخيرة منه زى نيترال أكسيد هناك كان عندى كلورو + +867 +01:15:04,530 --> 01:15:10,010 +أكزيم هنا C double bond N N H هيدرازون و + +868 +01:15:10,010 --> 01:15:13,430 +Clorهيدرازون + +869 +01:15:13,430 --> 01:15:18,230 +عادة بيسموه هيدرازونويل كلورايد هيدرازونويل + +870 +01:15:18,230 --> 01:15:24,030 +كلورايد اللي هو ال Clorهيدرازون بال إتراي F الأمين + +871 +01:15:24,030 --> 01:15:34,640 +شو هيسحب؟ Hو CL هيعمل ليه نيترال إيمين طبعا هل + +872 +01:15:34,640 --> 01:15:41,060 +ممكن من مراكب زي هذا سخن و يفقد جزء نيتروجين مراكب + +873 +01:15:41,060 --> 01:15:46,280 +زي هذا سخن و يفقد جزء نيتروجين برضه وارد الآن + +874 +01:15:46,280 --> 01:15:52,360 +الطريقة الأشهر لتحضير نيترال إيمين الـ Hydrazinoid + +875 +01:15:54,430 --> 01:15:58,170 +بشكل عام هيدرازولويل كلوراي بالـ triethylamine + +876 +01:15:58,170 --> 01:16:03,430 +بيعطيني نيترال امين العملية مش صعبة موجودة حتى في + +877 +01:16:03,430 --> 01:16:07,810 +مختبراتنا يعني كتير بنحضره و طبعا بالصين انه هذا + +878 +01:16:07,810 --> 01:16:13,550 +كيف بده يتحضرهذا بتحضر ممكن من الchlorination + +879 +01:16:13,550 --> 01:16:19,270 +للهيدرازون وارد وفي طريقة مشهورة كتير اسمها جابي + +880 +01:16:19,270 --> 01:16:23,250 +كلينجمان رياكشن واردة الطريقتين واردات و الأشهر + +881 +01:16:23,250 --> 01:16:27,430 +فيهم الجابي كلينجمان رياكشن خلنا نقول انه النيترال + +882 +01:16:27,430 --> 01:16:31,010 +إيميل من الهيدرازون والهيلايتز و النيترال أكسايتز + +883 +01:16:31,010 --> 01:16:37,740 +من الكلورو أكزينزالاسايتس عادة لأ بتنوجد كاسايتس + +884 +01:16:37,740 --> 01:16:42,480 +يعني مافيش فيها مشكلة و بنقدر نفعلها الديازوميثين + +885 +01:16:42,480 --> 01:16:49,820 +له طرق معينة كيف يحضرونه الآن لو بدنا ناخد أمثلة + +886 +01:16:49,820 --> 01:16:59,220 +في النهاية لاحظوا عنده عدد كبير جدا من الأمثلة هل + +887 +01:16:59,220 --> 01:17:04,700 +ياتورا بدي أستعرضهم؟ لأ أنا بدي أحكيأفكار عامة في + +888 +01:17:04,700 --> 01:17:11,360 +موضوع الأمثلة، الأفكار العامة أنه بدنا نفكر دائما + +889 +01:17:11,360 --> 01:17:16,060 +في أي مثال أنه عندي two possible products + +890 +01:17:17,200 --> 01:17:22,960 +يعني إذا انتوا بتقرأوا مقال المقال بيكون شخص عمل + +891 +01:17:22,960 --> 01:17:27,100 +التجربة فصل الناتج في هذه الحالة يا بيكون فصل one + +892 +01:17:27,100 --> 01:17:30,600 +product يا mixture of products وطلع نسبة المئوية + +893 +01:17:30,600 --> 01:17:35,720 +لكن لو احنا قلنالكوا اكمل اي معادلة cycle addition + +894 +01:17:35,720 --> 01:17:38,920 +one three bipolar cycle addition او deals other + +895 +01:17:38,920 --> 01:17:43,810 +reaction الاصل بشكل عام ان عندكم ايش؟two products + +896 +01:17:43,810 --> 01:17:50,610 +طبعا بشرط انه ال reactants تكون unsymmetrical لأنه + +897 +01:17:50,610 --> 01:17:54,830 +لو مع reactants symmetrical اجلبوه هيطلعوا نفس + +898 +01:17:54,830 --> 01:18:01,350 +الناتج مثلا هنا هيعندي A زايد اتطلع معاه هذه الان + +899 +01:18:01,350 --> 01:18:06,800 +متصلة فيه انه هذه الان freeصح ولا لأ؟ الان وهى + +900 +01:18:06,800 --> 01:18:10,680 +عندى double bond هى متصلة بمثل وهى بفينيل فى هذى + +901 +01:18:10,680 --> 01:18:17,840 +الحالة هذا symmetrical ولا لأ؟ وهذا .. اذا كام + +902 +01:18:17,840 --> 01:18:22,560 +ناتج هنا متوقع؟ اتنين لاحظوا هو هنا هى يستعمل + +903 +01:18:22,560 --> 01:18:27,500 +الفينيل ازايد بعدين حطيه للكاربون اللى متصل + +904 +01:18:27,500 --> 01:18:34,310 +بالفينيل عند نيتروجينالحملة الفنل لو قلنا لكوا طب + +905 +01:18:34,310 --> 01:18:40,370 +إيش الناتج التاني الناتج التاني أن المثل تكون هنا + +906 +01:18:40,370 --> 01:18:44,950 +والفنل تكون هنا يعني لو أنتوا بتكونوا تكملوا + +907 +01:18:44,950 --> 01:18:48,070 +المعادلة أنتوا مش قاعدين في المختبر لازم تحطولي + +908 +01:18:48,070 --> 01:18:52,790 +كام ناتج two possible products تمام؟ الآن هو عمل + +909 +01:18:52,790 --> 01:19:00,130 +تجربة وبناء على ذلك فصلناتج واحد هذا الكلام هيدلوا + +910 +01:19:00,130 --> 01:19:03,470 +يتكرر دائما التفاعل مع ال 1,3-dipolar على أطراف ال + +911 +01:19:03,470 --> 01:19:08,750 +1,3-dipolar هي ال diazomethane هيتفاعل وين؟ هانوان + +912 +01:19:08,750 --> 01:19:13,150 +لاحظوا ال diazomethane البعض منكم هييجي يقول طب يا + +913 +01:19:13,150 --> 01:19:17,470 +رب ما احنا أخدناه بشوية تسخين بيفقد نيتروجين + +914 +01:19:17,470 --> 01:19:22,940 +وبيعطيني كربينصح ولا لأ؟ عشان كده يازوا مثيل حتى + +915 +01:19:22,940 --> 01:19:26,740 +من المراكبات اللي صعبة في التحضير و عادة بدها زجاج + +916 +01:19:26,740 --> 01:19:30,920 +ناعم اللي مايعملش الفجار و بيحطوا shield حماية + +917 +01:19:30,920 --> 01:19:34,440 +خفلة انه يضر الناس اللي بيشتغلوا فيه يعني الشغل + +918 +01:19:34,440 --> 01:19:39,180 +فيه متعبو لو عملوا تسقين او فوتوليسيز الاحتمال + +919 +01:19:39,180 --> 01:19:44,620 +فعلا انه يفقد من هنا و يعمل كاربين وبالتالي لاحظوا + +920 +01:19:44,620 --> 01:19:48,280 +هذا التفاعل لو كنت كتبلكوا حرارة او فوتوليسيز ممكن + +921 +01:19:48,280 --> 01:19:51,920 +واحدة شاطرة تقول okay ضيازوا مثيل فقد ال نيتروجين + +922 +01:19:51,920 --> 01:19:56,560 +عمل كاربين بعدين تجيب الكاربين هادر اللي حاملة مثل + +923 +01:19:56,560 --> 01:20:00,520 +و مثل و تعمل حلقة ثلاثية هذا الكلام كله وقتاش + +924 +01:20:00,520 --> 01:20:09,260 +مقبوللو انا قلت شوية heat او ضوء يمكن لكن لاحظوا + +925 +01:20:09,260 --> 01:20:13,400 +ال condition هنا في الديازو ميثين ايش؟ Zero degree + +926 +01:20:13,400 --> 01:20:19,200 +centigrade و اعطاه وجد عشان مايكسرش ال nitrogen و + +927 +01:20:19,200 --> 01:20:24,080 +يتفاعل ك one three dipole فالديازو ميثين بده يظل + +928 +01:20:24,080 --> 01:20:28,960 +بفكركوا انه لو فلتت الشروط شوية في تسخين او ضوء + +929 +01:20:29,760 --> 01:20:34,480 +هيحول لإيش؟ لكربين ويصير يشغل كيمية كربين، هيبطل + +930 +01:20:34,480 --> 01:20:41,640 +كوانثري دايبول واضح الفكرة؟ هذا نيترال سالفايد، كم + +931 +01:20:41,640 --> 01:20:49,680 +ناتج بتوقعله على طول؟ + +932 +01:20:49,680 --> 01:20:55,100 +واحد، + +933 +01:20:55,100 --> 01:21:00,900 +ليش؟ لأن هذا متماثل، يعني لو جلبته هذههذه + +934 +01:21:00,900 --> 01:21:07,120 +Cyclopentane متماثلة تمام كل هذه الأمثلة ما لم + +935 +01:21:07,120 --> 01:21:12,760 +تتدربوا أنتم بإيديكم أنتم تكتبوها هتتغلبوا الآن + +936 +01:21:12,760 --> 01:21:17,740 +أحيانا بيكون التفاعل Intramolecular يعني الـ + +937 +01:21:17,740 --> 01:21:20,720 +Nitrile Oxide يعني لاحظوا هنا هي Nitrile Oxide + +938 +01:21:20,720 --> 01:21:25,000 +ممكن عشان السهولة بس أنا أعيد رسمه أخلي ال Oxygen + +939 +01:21:25,000 --> 01:21:33,840 +هناهذه الـ 1,3-dipole وهذه الـ double bond طبعا في + +940 +01:21:33,840 --> 01:21:38,260 +الـ Intramolecular هنا كام product عنده؟ كام + +941 +01:21:38,260 --> 01:21:43,500 +possible product؟ لأن الـ Geometry مش الـ + +942 +01:21:43,500 --> 01:21:46,000 +Stereochemistry، الـ Geometry لا تسمح، يعني مقدرش + +943 +01:21:46,000 --> 01:21:50,820 +اللف ويقول وين ودنك؟ واضحة الفكرة؟ + +944 +01:21:53,630 --> 01:21:58,370 +نيترون على الكربون والأكسجين سيمتريك ولا انسيمتريك + +945 +01:21:58,370 --> 01:22:01,890 +هذا CMO + +946 +01:22:01,890 --> 01:22:07,150 +انسيمتريك بزن CMO COO انسيمتريك طب هاي ال double + +947 +01:22:07,150 --> 01:22:13,920 +bond CH2 و CHSO2 في نفسكبنان عدل كام ناتج متوقع + +948 +01:22:13,920 --> 01:22:17,800 +اتنين لاحظوا هنا طلع الاتنين يعني لو انا اخدت هذا + +949 +01:22:17,800 --> 01:22:23,920 +الفنل CNO فنل CNO هذا ال 13 دايبول هاي ال 13 + +950 +01:22:23,920 --> 01:22:29,240 +دايبول الان مرة خلى هذه المجموعة اللي هي ال S O 2 + +951 +01:22:29,240 --> 01:22:35,260 +فنل انعلمها باللون الأحمر على جهة الفنل و مرة خلى + +952 +01:22:35,260 --> 01:22:39,340 +على الجهة التانية فصل الناتجين و طلعوا بنسبة قداش + +953 +01:22:40,320 --> 01:22:49,580 +68% ل 32% تجربة واضح؟ اذا انا بدي انتبه لما بكون + +954 +01:22:49,580 --> 01:22:55,640 +بعمل معادلات و بكمل تفاعلات ان في مرات كتيرة في + +955 +01:22:55,640 --> 01:23:01,730 +عنده الاحتمالين و في نهاية التجربة هي الحكمكل هذه + +956 +01:23:01,730 --> 01:23:06,970 +الأمثلة الآن اللي موجودة بشكل كبير هي أزايد لما + +957 +01:23:06,970 --> 01:23:10,290 +يصير التفاعل مع ال triple bond يعني الأمثلة + +958 +01:23:10,290 --> 01:23:13,270 +السابقة كانت مع double bond لما يصير مع ال triple + +959 +01:23:13,270 --> 01:23:16,970 +bond لل triple شو بده هتصير؟ double وال double شو + +960 +01:23:16,970 --> 01:23:20,310 +بتصير؟ single الأمثلة السابقة كانت double؟ single + +961 +01:23:20,310 --> 01:23:25,770 +أه الأن هنا فنل CC يعني لو أنا أخدت فنل أزايد هي + +962 +01:23:25,770 --> 01:23:30,170 +الفنل أزايد املاحظين؟ + +963 +01:23:31,300 --> 01:23:34,800 +الان هذا الفينل ازايد سيمتريك ولا انسيمتريك + +964 +01:23:34,800 --> 01:23:40,220 +انسيمتريك الان فينل C triple bond C سيمتريك ولا + +965 +01:23:40,220 --> 01:23:44,880 +انسيمتريك انسيمتريك بناء على ذلك لما اتفاعل لاحظوا + +966 +01:23:44,880 --> 01:23:49,720 +معاه انه ممكن الفينل تيجي على جهة الان اللي هنا او + +967 +01:23:49,720 --> 01:23:53,160 +الفينل تيجي هنا two possible products في هذه + +968 +01:23:53,160 --> 01:23:59,780 +الحالة طالعين اتنين بالنسبة اتنين واربعين لاتنين + +969 +01:23:59,780 --> 01:24:05,590 +وخمسينهذا المثال الجميل فيه أزايد بس هو كتبوا هنا + +970 +01:24:05,590 --> 01:24:10,750 +على شكل any three يعني أنتوا بتكونوا تفصلوه C N N + +971 +01:24:10,750 --> 01:24:15,970 +N هاي الأزايد هذي اللي هي any three هاي ال carbon + +972 +01:24:15,970 --> 01:24:24,690 +هذي any three N N N N N N و هذيالكربون مجرد رفع + +973 +01:24:24,690 --> 01:24:28,370 +على فوقه عملت double bond يعني هاي الجزء قبل ما + +974 +01:24:28,370 --> 01:24:33,970 +يعملوا هذول الرابطين تطلع عليه Oxygen CH2 C triple + +975 +01:24:33,970 --> 01:24:40,750 +bond C Oxygen CH2 C triple bond C نيتروجين تنتين + +976 +01:24:40,750 --> 01:24:46,100 +تلاتةإذا هذا التفاعل إنتر ولا إنتر موليكلار؟ إنتر + +977 +01:24:46,100 --> 01:24:51,780 +موليكلار Cycloaddition reaction للأزيد و لاحظوا + +978 +01:24:51,780 --> 01:24:58,120 +كيف كون تلت حلقات كيف كون تلت حلقات أنا بتهيألي كل + +979 +01:24:58,120 --> 01:25:04,070 +الأمثلة الحقيقة اللي موجودةمن ناحية المبدأ بهذا + +980 +01:25:04,070 --> 01:25:08,470 +الشكل هذا اللي هنا يمكن نيترون هذه أطراف ال 1,3 + +981 +01:25:08,470 --> 01:25:14,010 +-dipole carbon-NO ومثل البريدين أكسيد لما يمر + +982 +01:25:14,010 --> 01:25:20,730 +علينا البريدين أن أكسيد هنا أكسجين واحد اتنين + +983 +01:25:20,730 --> 01:25:27,250 +تلاتة بريدين أن أكسيد برضه هذا نيترون هنا أطراف ال + +984 +01:25:27,250 --> 01:25:29,410 +1,3-dipole carbon-NO + +985 +01:25:32,480 --> 01:25:35,680 +معنى triple bond؟ symmetric ولا unsymmetric؟ + +986 +01:25:35,680 --> 01:25:41,920 +لاحظوا هنا طلع ناتج ما طلعش التاني هو يعبر عن إيش + +987 +01:25:41,920 --> 01:25:45,060 +اللي طلع معاه بالتجربة لكن لو أنا جايب الكوادة و + +988 +01:25:45,060 --> 01:25:48,240 +أكمل المعادلة و أجيت الناتج التاني بتكون تقلبه + +989 +01:25:48,240 --> 01:25:56,260 +هذي، هذي تصير هذي ترسم ال two regio isomers و هي + +990 +01:25:56,260 --> 01:26:02,640 +أمثلة إضافية و إضافية و إضافيةخلّينا ناخد آخر + +991 +01:26:02,640 --> 01:26:08,400 +slide أو تنتين عشان ننهي هذا اكلوروجزيم مع الـ + +992 +01:26:08,400 --> 01:26:13,020 +triethylamine شو بده يعمل لنا نيترائيل اكسايد لو + +993 +01:26:13,020 --> 01:26:18,960 +اجينا فعلنا مع ال symbol هيدرازون هيدرازون + +994 +01:26:18,960 --> 01:26:25,060 +عادي هذا C double bond N C double bond N لما يتكون + +995 +01:26:25,060 --> 01:26:30,560 +هذا بده يعمل cycle addition علىC double bond and + +996 +01:26:30,560 --> 01:26:35,160 +شو صارت ال double bond single bond أعطانا one + +997 +01:26:35,160 --> 01:26:40,120 +product تمام أعطانا one product و في بعض الأحوال + +998 +01:26:40,120 --> 01:26:46,360 +لما هذي ال R' كانت H التقت H و أنا H2 جاب بعض ممكن + +999 +01:26:46,360 --> 01:26:50,820 +يفتنوا أمونيا و يعملوا bubble bond زي ما كان + +1000 +01:26:50,820 --> 01:26:54,120 +بيلتقي H و O H بيعملوا + +1001 +01:26:57,770 --> 01:27:03,910 +Double bond حدث ماء هنا حدث ايش امونيا شايفين + +1002 +01:27:03,910 --> 01:27:09,390 +انتوا التفاعل ايش ماله بسيط جدا مجرد ان الانسان + +1003 +01:27:09,390 --> 01:27:15,270 +يحضر الديهيد اكزيم كلور اكزيم و يحضر هيدرازون + +1004 +01:27:15,270 --> 01:27:22,210 +يخلطهم مع بعض و يطلع ايشو يطلع الناتج يعني لو + +1005 +01:27:22,210 --> 01:27:26,170 +كنتوا بتعملوا هذا الكلام في المختبر كام .. كام + +1006 +01:27:26,170 --> 01:27:35,930 +محاضرة مختبر بدوا يلزمكوا فيه؟ تلت ساعات ولا ستة؟ + +1007 +01:27:35,930 --> 01:27:40,390 +الصحيح انه التجريب و العمل و انكوا تظبطوا ال + +1008 +01:27:40,390 --> 01:27:43,830 +conditions و تفصلوا النواتج و تعملولها NMR و + +1009 +01:27:43,830 --> 01:27:48,950 +تعملولها تشخيص و ما إلى ذلك هذا الكلام بياخد منكم + +1010 +01:27:50,450 --> 01:27:55,730 +بياخد منكم جداش؟ أشهر أحيانا، يعني هذه المعادلة + +1011 +01:27:55,730 --> 01:27:59,770 +فقط هذه المعادلة مش أكتر كانت هي موضوع رسالتي + +1012 +01:27:59,770 --> 01:28:04,190 +لماجستير أنا اللي أخدت مني أشهر سنة التمانية و + +1013 +01:28:04,190 --> 01:28:08,480 +تمانين، تسعة و تمانين يعنيلاحظوا معادلة واحدة فقط + +1014 +01:28:08,480 --> 01:28:13,140 +فالكيميا بده مشهود كتير، بده تعب كتير، ليش؟ لأن + +1015 +01:28:13,140 --> 01:28:17,460 +اللي هنا بيكتب R و R، بعدين يطور ال R و ال R مثل و + +1016 +01:28:17,460 --> 01:28:21,660 +مثل، إثل و إثل، بروبل و بروبل، سايكلو بنتانون، + +1017 +01:28:21,660 --> 01:28:26,280 +ممكن تكون سايكلو .. يعطي أمثلة للناس، اللي بيكتب + +1018 +01:28:26,280 --> 01:28:30,400 +AR، طب هي ال AR بنزينة ولا بارا كلورو بنزينة ولا + +1019 +01:28:30,400 --> 01:28:36,190 +بارا مثل؟بدو يعمل من هنا امثلة من هنا امثلة يتأكد + +1020 +01:28:36,190 --> 01:28:39,490 +يفصل النواتج يعملها crystallization مرة او مرتين + +1021 +01:28:39,490 --> 01:28:43,030 +لحد ما تصير نقية يعملها IR يعملها NMR يعملها + +1022 +01:28:43,030 --> 01:28:47,170 +elemental analysis هذا الكلام ما بتلاقوله مكلف معك + +1023 +01:28:47,170 --> 01:28:54,790 +وقداش من نص سنة الى سنة من المجهود واضح؟ لاحظوا في + +1024 +01:28:54,790 --> 01:28:57,650 +ناس اجوا بدل ما يكون هذا simple هيدرازون يقولوا + +1025 +01:28:57,650 --> 01:29:03,200 +خلنا نخلي هذا الـ N H مثل و مثلبرضه عملوا cycle + +1026 +01:29:03,200 --> 01:29:06,280 +addition وين؟ على ال double bond هذا ال double + +1027 +01:29:06,280 --> 01:29:12,900 +bond شو صارت؟ صارت single bond تمام؟ هذا شغل بعتقد + +1028 +01:29:12,900 --> 01:29:17,880 +انه فيه مجموعة روسية اشتغلت عليه ففي ناس ايجوا + +1029 +01:29:17,880 --> 01:29:23,640 +فكروا جالوا مرة خلنا التنتين هيدروجينز انتبهوا + +1030 +01:29:23,640 --> 01:29:33,220 +معايا و مرة خلنا التنتين مثل ايش ضال؟الخلّي واحدة + +1031 +01:29:33,220 --> 01:29:38,760 +هيدروجين و واحدة مثل و نعمل Cycloaddition واضح؟ + +1032 +01:29:38,760 --> 01:29:42,600 +المسكين اللي خلّى واحدة هيدروجين و واحدة مثل إجى + +1033 +01:29:42,600 --> 01:29:45,920 +يعمل Cycloaddition اتفاجأ انه ماصارش عنده + +1034 +01:29:45,920 --> 01:29:50,020 +Cycloaddition صار عنده تفاعل تاني إجت هذه ال + +1035 +01:29:50,020 --> 01:29:54,520 +nitrogen بعد ما فقد الكلور و الـH هاجمتها و هذه ال + +1036 +01:29:54,520 --> 01:29:58,180 +oxygen سكّرت على ال double bondعملية Cyclization + +1037 +01:29:58,180 --> 01:30:01,180 +بخطوطين مش Cycloaddition ال Cycloaddition بيعطي + +1038 +01:30:01,180 --> 01:30:07,920 +جداش حلقة خماسية فهذه ال nitrogen في هذه الحالة + +1039 +01:30:07,920 --> 01:30:12,020 +بدل ما اعمل Cycloaddition ع ال double bond هذه ال + +1040 +01:30:12,020 --> 01:30:15,380 +nitrogen في نهاية نيوكليوفايل وهذه ال carbon موجبة + +1041 +01:30:15,380 --> 01:30:20,080 +هاجمت عليها عملت bond هذه ال oxygen نيوكليوفايل + +1042 +01:30:20,080 --> 01:30:26,430 +وهذه ال carbon موجبة in principle او لما تتحركهذا + +1043 +01:30:26,430 --> 01:30:31,090 +الشكل وبالتالي اعطاني تفاعل بنسميه cycle + +1044 +01:30:31,090 --> 01:30:36,050 +condensation اعطاني حلقة سلسلة لاحظوا كم تغيير R + +1045 +01:30:36,050 --> 01:30:42,490 +بسيطتغيير بسيط بدل ما التفاعل يكون cycle addition + +1046 +01:30:42,490 --> 01:30:46,710 +اللي هو تلاتة زي اتنين يساوي خمسة اتفعل بطريقة + +1047 +01:30:46,710 --> 01:30:51,070 +مختلفة و أعطاني نوع من ال cycleization العادى + +1048 +01:30:51,070 --> 01:30:54,870 +cycleization enucleophile electrophile و + +1049 +01:30:54,870 --> 01:30:57,690 +enucleophile electrophile زي أنواع ال cycleization + +1050 +01:30:57,690 --> 01:31:03,840 +اللي أخدناها طلع حلقةسدسية اكيد حلقة سدسية مش + +1051 +01:31:03,840 --> 01:31:06,280 +cycle addition ليش لان ال cycle addition one three + +1052 +01:31:06,280 --> 01:31:11,000 +bipolar cycle addition تلاتة زي اتنين يساوي خمسة + +1053 +01:31:11,000 --> 01:31:15,060 +هذا اكيد مش cycle addition يمكن هذا بيحطكم بصورة + +1054 +01:31:15,060 --> 01:31:24,500 +كده الموضوع كبير في كل الأحوال بدناياكم تجيبولنا + +1055 +01:31:24,500 --> 01:31:31,410 +homeworkهذا كمان مثال تاني لكن بدل ما يحطوا هنا + +1056 +01:31:31,410 --> 01:31:37,490 +مجموعة مثل حطوا مجموعة ساحبة للإلكترونات تطلعوا + +1057 +01:31:37,490 --> 01:31:41,770 +معي لما حطينا مجموعة مثل يمكن الناس اللي بيحاولوا + +1058 +01:31:41,770 --> 01:31:45,690 +يفهموا ليش التفاعل زيكي المثل إيش مالها؟ تعطي + +1059 +01:31:45,690 --> 01:31:49,330 +إلكترونات هنا في زوج إلكترونات إذا هذا كان + +1060 +01:31:49,330 --> 01:31:55,170 +يوكليوفايل صار إيش؟قوى نوعا ما إجا هاجم هان وهذا + +1061 +01:31:55,170 --> 01:32:00,250 +كان يوكليوفايل سكر هان أعطانا الحلقة السداسية الآن + +1062 +01:32:00,250 --> 01:32:05,470 +لو بدل هذه المجموعة المعطية حطينا مجموعة ساحبة هل + +1063 +01:32:05,470 --> 01:32:09,550 +يا ترى هيسكرها الحلقة السداسية ولا بده يرجع لل + +1064 +01:32:09,550 --> 01:32:16,690 +cycle addition التجربة اللي بتوضح التجربة بتقول + +1065 +01:32:16,690 --> 01:32:21,670 +نرجع لل cycle additionتجربة بتقول يجي على الصيف + +1066 +01:32:21,670 --> 01:32:27,490 +لقد شيل لإيش لإن هذه بطلت strong nucleophile in + +1067 +01:32:27,490 --> 01:32:32,570 +principleفلاحظوا تغييرات بسيطة بتلف التفاعل من أن + +1068 +01:32:32,570 --> 01:32:36,610 +يكون cycle addition لأن يكون cyclization عادي كل + +1069 +01:32:36,610 --> 01:32:40,810 +هذا الكلام وين الإنسان بيواجهه لما يصير في واقع + +1070 +01:32:40,810 --> 01:32:43,970 +العمل التجريبى الآن ال course عندكم انتوا يعني + +1071 +01:32:43,970 --> 01:32:47,890 +very general course بدكم مفهومات .. مفاهيم عامة + +1072 +01:32:47,890 --> 01:32:53,210 +جدا في cycle addition بأمل أنه صارت واضحة عندكم و + +1073 +01:32:53,210 --> 01:32:59,400 +بتسمحلكوا أن تجيبولنا homeworkمش أقل من تلت أمثلة + +1074 +01:32:59,400 --> 01:33:03,640 +على الـ Cycloaddition التلت أمثلة مختلفة مثلا مثال + +1075 +01:33:03,640 --> 01:33:06,920 +يكون عن الآزايد مثال عن الديازوميثين مثال عن + +1076 +01:33:06,920 --> 01:33:09,620 +النيترال أكسيد مثال عن نيترال إيمين عن نيترال + +1077 +01:33:09,620 --> 01:33:16,240 +سالفايد افتحوا أي open access journal و اكتبوا + +1078 +01:33:16,240 --> 01:33:20,960 +فيها Cycloaddition ال homework هذا هتلاحظوا انه + +1079 +01:33:20,960 --> 01:33:28,120 +بينحل بعشر دقائقبكون وجهكم الى مقالات كتيرة جدا + +1080 +01:33:28,120 --> 01:33:32,380 +يعني مجرد ما تكتبوا one three bipolar cycle + +1081 +01:33:32,380 --> 01:33:39,180 +edition هيوجهكم الى عشرات المقالات المنشورة حديثا + +1082 +01:33:39,180 --> 01:33:42,160 +و اللي العالم بيشتغلوا عليها في المجال بتسلمون ال + +1083 +01:33:42,160 --> 01:33:47,440 +home working المرة القادمة ان شاء الله و برك الله + +1084 +01:33:47,440 --> 01:33:47,880 +فيك + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/1qWv9p9o0Os_postprocess.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/1qWv9p9o0Os_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..07c24d5439a8ed7838d02135f909196fad4af576 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/1qWv9p9o0Os_postprocess.srt @@ -0,0 +1,1572 @@ +1 +00:00:20,770 --> 00:00:25,450 +بسم الله الرحمن الرحيم المرة الماضية في موضوع + +2 +00:00:25,450 --> 00:00:31,170 +تحضير المراكبات الحلقية اتكلمنا على نوع من ال + +3 +00:00:31,170 --> 00:00:34,070 +reactive intermediates اللي هم ال carbines و ال + +4 +00:00:34,070 --> 00:00:38,690 +nitrines عرفنا إيش معنى carbine و إيش معنى nitrine + +5 +00:00:38,690 --> 00:00:42,940 +كيف نعمل generation لل carbineهذه الكربين كان + +6 +00:00:42,940 --> 00:00:47,020 +عبارة عن كربون بمجموعتين زائد زوج من الإلكترونات + +7 +00:00:47,020 --> 00:00:51,880 +النيترين نيتروجين برابطة واحدة وزوجين من + +8 +00:00:51,880 --> 00:00:57,100 +الإلكترونات طبعا ال generation للكربين أخدناها من + +9 +00:00:57,100 --> 00:01:00,340 +خلال ال diazo compounds أو من خلال ال ketenes + +10 +00:01:00,340 --> 00:01:04,760 +بيفقدوا small molecules و بعدين أخدنا أهم تفاعلات + +11 +00:01:04,760 --> 00:01:10,920 +الكربين قلنا للكربين تفاعلين أساسيا تفاعلالـ + +12 +00:01:10,920 --> 00:01:13,940 +Cycloaddition تحديدًا الـ Cycloaddition ليش؟ لأنه + +13 +00:01:13,940 --> 00:01:18,120 +الـ Cycloaddition formation of two new sigma bonds + +14 +00:01:18,120 --> 00:01:22,140 +at the same time بشكل عام وعمل cycle Cycloaddition + +15 +00:01:22,140 --> 00:01:25,860 +يعني هذا التفاعل اللي هو الـ Nitrene مع ال double + +16 +00:01:25,860 --> 00:01:29,420 +bond أو الكربين مع ال double bond هيعود مر معنا + +17 +00:01:29,420 --> 00:01:35,040 +لما بناخد أنواع ال Cycloaddition reactions هيعود + +18 +00:01:35,040 --> 00:01:38,600 +مر معنا لما بناخد أنواع ال Cycloaddition reactions + +19 +00:01:39,070 --> 00:01:44,170 +الان ال double bond مش دائما متوفر يعني double + +20 +00:01:44,170 --> 00:01:48,650 +bond انا لما بحط double bond بدي اجيب مركب تحديدا + +21 +00:01:48,650 --> 00:01:52,870 +و قصدا فيه double bond و افعله مع الكربين زي هذا + +22 +00:01:52,870 --> 00:01:56,970 +المثال او زي المثال اللي مثلا هنا جيبت مركب فيه + +23 +00:01:56,970 --> 00:02:00,930 +double bond مركب ديازو كمباوند هذا في وجود حرارة + +24 +00:02:00,930 --> 00:02:07,230 +او catalyst فقد ال nitrogen صار كربين الكربينلقى + +25 +00:02:07,230 --> 00:02:12,790 +double bond عمل عليها Cycloaddition + +26 +00:02:12,790 --> 00:02:19,310 +الآن السؤال لو الكربين ماحطتلوش double bond ايش + +27 +00:02:19,310 --> 00:02:24,410 +بده يعمل يعني كوّننا الكربين اتكون الكربين لكن + +28 +00:02:24,410 --> 00:02:28,870 +مالقاش double bond يتفاعل معاها هو الكربين بطبيعة + +29 +00:02:28,870 --> 00:02:33,550 +الحال reactive intermediate يعني لازم يتفاعل + +30 +00:02:34,570 --> 00:02:41,010 +مالاجهاش double bond ايش بدهوا يعمل في النهايةبصير + +31 +00:02:41,010 --> 00:02:45,310 +يعمل تفاعل تاني و ربما هو الأشهر والأكتر انتشارا + +32 +00:02:45,310 --> 00:02:48,390 +لل carbons و ال nitrenes بنسميه احنا تفاعل ال + +33 +00:02:48,390 --> 00:02:53,270 +insertion بيدخل بين ال carbon و ال H بيعمل + +34 +00:02:53,270 --> 00:02:57,350 +insertion معنى ال insertion و غالبا هذا ال + +35 +00:02:57,350 --> 00:03:01,270 +insertion ممكن تفهموه انه بتمن خلال حلقة ثلاثية + +36 +00:03:01,270 --> 00:03:07,890 +بيدخل الكربين ما بين الكربون و ال hydrogen يعني هى + +37 +00:03:07,890 --> 00:03:14,920 +مثلا هنافي عنده الميثيلين اللي هو أبسط ايش؟ أبسط + +38 +00:03:14,920 --> 00:03:19,220 +كاربين الان لو انا كنت بدى أشوف كيف بده يعمل هذا + +39 +00:03:19,220 --> 00:03:25,000 +التفاعل خلينا نركز نظرنا على هذه الكاربون على هذه + +40 +00:03:25,000 --> 00:03:30,860 +الكاربون و هذه ال H واضح؟ الان الكاربين بده يعمل + +41 +00:03:30,860 --> 00:03:35,540 +insertion يدخل بينهم يعني يدخل بين ال C و ال H كأن + +42 +00:03:35,540 --> 00:03:40,380 +بين ال C و ال H ايش بده أحط؟CH2 هذا الكلام كيف + +43 +00:03:40,380 --> 00:03:46,080 +عادة ممكن يتم عادة هذا الكلام ممكن يتم من خلال نوع + +44 +00:03:46,080 --> 00:03:50,920 +من الحلقة الثلاثية يعني تخيلوا ان هذا الكربين هيجي + +45 +00:03:50,920 --> 00:03:54,960 +يعمل حلقة ثلاثية بين هذا الكربون وهذا الهيدروجين + +46 +00:03:54,960 --> 00:04:01,200 +الآن عمل الكربين الحلقة الثلاثية بعد هيك بيكتمل + +47 +00:04:01,200 --> 00:04:07,490 +كسر طبعا هذه كمان ايش مالها صارت منقطةواضح؟ بعد + +48 +00:04:07,490 --> 00:04:12,070 +هيك بيكتمل كسر الرابط بين ال carbon و ال H الان + +49 +00:04:12,070 --> 00:04:15,230 +تخيلوا ان هذه الرابطة انكسرت ايش هيصير متصل بال + +50 +00:04:15,230 --> 00:04:24,050 +carbon؟ carbon CH2H CH3 هين موجود كأنه الان + +51 +00:04:24,050 --> 00:04:32,250 +بتقدروا تنظروا لهذه CH3 حقيقة انها CH2H + +52 +00:04:32,250 --> 00:04:38,160 +ايش اللي عمل ال insertion؟بين ال carbon و ال H ال + +53 +00:04:38,160 --> 00:04:45,660 +CH2 هي عملية ال insertion واضحة العملية الآن في + +54 +00:04:45,660 --> 00:04:50,340 +هذا النوع من التفاعلات في هذا النوع من التفاعلات + +55 +00:04:50,340 --> 00:04:55,510 +هتلاحظواكما هو الحال بشكل عام في الـ heterocyclic + +56 +00:04:55,510 --> 00:04:59,930 +chemistry أنه لازم تفكيركم يكون واسع يعني طالما + +57 +00:04:59,930 --> 00:05:04,310 +أنا بأحكي عن insertion بين carbon و hydrogen بناء + +58 +00:05:04,310 --> 00:05:09,190 +على ذلك، قداش الاحتمالات الممكنة؟ يعني مثلا بهذا + +59 +00:05:09,190 --> 00:05:14,030 +الجزء اللي هو البروبين، كم احتمال ممكن عنده؟ كم + +60 +00:05:14,030 --> 00:05:19,630 +نوع هيدروجين؟ اتخيلوا أن هذا الجزء في ال NMR حطته، + +61 +00:05:19,630 --> 00:05:21,130 +كم بيك هتشوفه؟ + +62 +00:05:24,340 --> 00:05:29,600 +كل الهيدروجينات اللي هنا تمانية هذه ال CH3 و هذه + +63 +00:05:29,600 --> 00:05:36,140 +ال CH3 زي بعض و هدول ال CH2 زي بعض بمعنى لو أنا + +64 +00:05:36,140 --> 00:05:42,340 +كان سؤالي draw all the possible insertion products + +65 +00:05:42,340 --> 00:05:46,460 +for this reaction draw all the possible insertion + +66 +00:05:46,460 --> 00:05:50,360 +products for this reaction هذا أحد ال insertion + +67 +00:05:50,360 --> 00:05:56,150 +products اللي إجت فيهال CH2 هنا ال insertion + +68 +00:05:56,150 --> 00:06:01,690 +product التاني وين بده يكون CH3 عادي وبناء على ذلك + +69 +00:06:01,690 --> 00:06:09,770 +لو انا بده اتخيله هيكون حقيقة CH3 CH2 خليني اقول + +70 +00:06:09,770 --> 00:06:15,290 +CH2 وهي ال H هذا اللي كان موجود اصلا و ايش هييجي + +71 +00:06:15,290 --> 00:06:22,020 +عندى بال insertion ال CH2 اذا هنا لما احطCH2 + +72 +00:06:22,020 --> 00:06:29,040 +واتصلت بالـ H CH2 عملت insertion هنا صار الجزء CH3 + +73 +00:06:29,040 --> 00:06:34,020 +CH2 CH2 CH3 هذا ال insertion اللي هنا على + +74 +00:06:34,020 --> 00:06:37,820 +secondary carbon هذا ال insertion اللي هنا على + +75 +00:06:37,820 --> 00:06:43,140 +primary carbon الآن التجربة بتقول انه بشكل عام + +76 +00:06:43,140 --> 00:06:51,570 +بشكل عام ال insertionبفضل ال tertiary على ال + +77 +00:06:51,570 --> 00:06:55,150 +secondary على ال primary بس مش هذا العامل الوحيد + +78 +00:06:55,150 --> 00:07:00,710 +المؤثر بديش أنسى كمان أن حجم الحلقة الناتج أحياناً + +79 +00:07:00,710 --> 00:07:04,350 +بيكون عامل مؤثر بالذات في ال ultra molecular + +80 +00:07:04,350 --> 00:07:08,810 +reactionيعني هنا مافيش عندى intramolecular + +81 +00:07:08,810 --> 00:07:13,750 +reaction فى عندى احتمالين الآن حسب التجربة اللى + +82 +00:07:13,750 --> 00:07:16,710 +طلعت ان هذا ال insertion ع secondary هذا ال + +83 +00:07:16,710 --> 00:07:20,750 +insertion ع primary ان هو اللى بيكون مفضل ال + +84 +00:07:20,750 --> 00:07:25,990 +insertion اللى على ال secondary الان لو أخدت أنا + +85 +00:07:26,750 --> 00:07:31,550 +مثال تاني Intramolecular reaction هاي هذا المركب + +86 +00:07:31,550 --> 00:07:37,090 +مع التسخين و النحاس و بنزين طارت هذه ال nitrogen و + +87 +00:07:37,090 --> 00:07:43,690 +صار عندى هنا ايش كربين الان اطلعولي الكربين هذه + +88 +00:07:43,690 --> 00:07:50,790 +ايش عندها احتمالات لل insertion هنا نعملها بلون + +89 +00:07:50,790 --> 00:07:56,230 +تاني هنا في عندى CHممكن تعمل insertion عليها ولا + +90 +00:07:56,230 --> 00:08:08,810 +لأ؟ وهنا في عندي CH وهنا في عندي CH وكل هادولة CH2 + +91 +00:08:08,810 --> 00:08:14,510 +CH2 CH2 they are secondary كلهم + +92 +00:08:14,510 --> 00:08:18,960 +secondaryلكن هذا ال insertion لما تيجي ال carbon + +93 +00:08:18,960 --> 00:08:24,220 +هنا تعمل رابطتها هيعطيني حلقة ثلاثية هذا ال + +94 +00:08:24,220 --> 00:08:27,600 +insertion هيعطيني حلقة ربعية هذا ال insertion + +95 +00:08:27,600 --> 00:08:32,560 +هيعطيني حلقة خمسية الان اذا صار عندى تلاتة + +96 +00:08:32,560 --> 00:08:36,620 +secondary في هذه الحالة اللى اتحكم في الناتج اكتر + +97 +00:08:36,620 --> 00:08:41,000 +اللى هو حجم الحلقة افضل الحلقات في التكون خمسية و + +98 +00:08:41,000 --> 00:08:46,590 +سادسية لحظة حتى احنا هنا ماتكلمناش اش في عندناع ال + +99 +00:08:46,590 --> 00:08:51,530 +R هذه و ال R هذه خلّيناهم محايدين لكن إلكم برضه + +100 +00:08:51,530 --> 00:08:55,050 +تتخيلوا .. إلكم برضه تتخيلوا إنه افترضوا اللي + +101 +00:08:55,050 --> 00:09:00,290 +كاتبها هنا R' هو حيدها يمكن عملها مجموعة نيترو ولا + +102 +00:09:00,290 --> 00:09:06,790 +كذا لكن لو افترضنا إن هذا ال R' كانت سلسلة كربونات + +103 +00:09:07,810 --> 00:09:11,310 +كان ايش بدو يكون التفكير انه كمان هنا في احتمال + +104 +00:09:11,310 --> 00:09:15,110 +insertion هنا في احتمال هنا في احتمال فموضوع + +105 +00:09:15,110 --> 00:09:20,210 +الاحتمالات لل insertions الحقيقة هو موضوع اشماله + +106 +00:09:20,210 --> 00:09:26,570 +واسع بشكل عام احنا في عندنا قاعدتين لكي نتخيل افضل + +107 +00:09:26,570 --> 00:09:31,000 +احتمال ممكن بس الحكم النهائي هو ايشالتجربة + +108 +00:09:31,000 --> 00:09:34,760 +القاعدتين ان ال tertiary افضل من ال secondary افضل + +109 +00:09:34,760 --> 00:09:37,580 +من ال primary في ال insertion و ان الحلقات الخمسية + +110 +00:09:37,580 --> 00:09:41,600 +و السادسية افضل من الربعية و الثلاثية واضح الفكرة + +111 +00:09:41,600 --> 00:09:49,260 +هذا طبعا بالذات موضوع الحلقات وانتش بيصير أساسا + +112 +00:09:49,260 --> 00:09:52,580 +حلقة في ال intramolecular reaction في ال + +113 +00:09:52,580 --> 00:09:55,680 +intramolecular هذا اللي بين جزيئين مافيش عندي + +114 +00:09:55,680 --> 00:09:59,670 +احتمال للحلقةهنا بس عندى احتمالي primary و + +115 +00:09:59,670 --> 00:10:03,330 +secondary، فى غيره؟ مافيش، لكن فى الـ + +116 +00:10:03,330 --> 00:10:06,390 +Intramolecular دائما الـ Intramolecular reaction + +117 +00:10:06,390 --> 00:10:11,530 +إيش قولنا عنه بيعمل؟ Cycle دائما أي reaction + +118 +00:10:11,530 --> 00:10:16,590 +Intramolecular هيعمل ليه Cycle؟ هيعمل حلقة، واضح؟ + +119 +00:10:16,590 --> 00:10:21,430 +ففى ال Intramolecular reaction صار عندى؟نوع + +120 +00:10:21,430 --> 00:10:25,710 +الكربون وحجم الحلقة في الـ Intermolecular reaction + +121 +00:10:25,710 --> 00:10:32,930 +اللي يتحكم في الموضوع نوع الكربون، واضح؟ مثلا، هذا + +122 +00:10:32,930 --> 00:10:37,070 +المثال واضح إن عندك ديازو كومباوند بتطير الـ + +123 +00:10:37,070 --> 00:10:44,050 +nitrogen ويتكون عندك كربين، تمام؟ الآن الـ + +124 +00:10:44,050 --> 00:10:48,430 +Cyclohexane in principle كل ذرات الهيدروجين تبعته + +125 +00:10:49,300 --> 00:10:54,640 +أقل تقدير على حرارة الغرفة واضح؟ ليش قلنا جملة على + +126 +00:10:54,640 --> 00:10:59,640 +حرارة الغرفة؟ + +127 +00:10:59,640 --> 00:11:04,040 +حد + +128 +00:11:04,040 --> 00:11:10,920 +بيقدر يتذكر؟ لأن الـ Cyclohexane الناس اللي + +129 +00:11:10,920 --> 00:11:15,120 +بيذكروا ال conformations تبعت الـ Cyclohexane لما + +130 +00:11:15,120 --> 00:11:19,130 +ياخد ال chair و ال boat conformationو ال boat + +131 +00:11:19,130 --> 00:11:26,410 +confirmation بشكل عام is more stable than .. is + +132 +00:11:26,410 --> 00:11:28,750 +less stable than the chair confirmation ال chair + +133 +00:11:28,750 --> 00:11:32,590 +confirmation هو ال more stable confirmation هذا ال + +134 +00:11:32,590 --> 00:11:37,630 +hydrogenات فيه بيصيروا نوعين بيصيروا ستة axial هاي + +135 +00:11:37,630 --> 00:11:43,030 +يوم بتدرسون بالأحمر واحد اتنين تلاتة اربعة خمسة + +136 +00:11:43,030 --> 00:11:49,630 +ستة ستة axial و ستةequatorial تمام طبعا + +137 +00:11:52,140 --> 00:11:55,980 +أنا في عندى ال flipping سريع على حرارة الغرفة + +138 +00:11:55,980 --> 00:11:59,100 +عشانك ال Axial بيصير Equatorial و ال Equatorial + +139 +00:11:59,100 --> 00:12:02,960 +Axial فبنقول أنه على حرارة الغرفة ال 12 زي بعض + +140 +00:12:02,960 --> 00:12:09,420 +لإنه عندى ال flipping سريع لكن لو بردنا على درجة + +141 +00:12:09,420 --> 00:12:14,480 +حرارة منخفضة جدا هيثبت بهذا الشكل و هنصير نشوف + +142 +00:12:14,480 --> 00:12:18,960 +الهيدروجين نوعين مش نوع واحدواضحة الفكرة + +143 +00:12:18,960 --> 00:12:23,660 +فالهيدروجين تبع ال Cyclohexane على حرارة الغرفة + +144 +00:12:23,660 --> 00:12:28,020 +نوع واحد رغم انه احنا هيناه رسمينه أحمر و أخضر + +145 +00:12:28,020 --> 00:12:32,660 +Axial و equatorial لكن في عنده very fast + +146 +00:12:32,660 --> 00:12:37,940 +convergence بين ال chair conformation اللي هيك و + +147 +00:12:37,940 --> 00:12:42,000 +ال chair conformation المعاكس له يعني هذا لما + +148 +00:12:42,000 --> 00:12:46,720 +بيصير ال chair conformation التاني المعاكس لهاللي + +149 +00:12:46,720 --> 00:12:50,060 +هو هذا الـ Chair Conformation لاحظوا هي هذا بتطلع + +150 +00:12:50,060 --> 00:12:52,200 +البن آدم اللي قاعد عليه هيك و هذا الـ Chair + +151 +00:12:52,200 --> 00:12:57,920 +المعاكس له اللي بيكونوا فيه .. اللي بيكونوا فيه + +152 +00:12:57,920 --> 00:13:04,300 +Axial بيصيروا equatorial اللي بيكونوا Axial + +153 +00:13:04,300 --> 00:13:07,640 +بيصيروا equatorial يعني هاي الحمر كانوا Axial + +154 +00:13:07,640 --> 00:13:11,900 +صاروا equatorial و اللي كانوا equatorial بيصيروا + +155 +00:13:11,900 --> 00:13:13,700 +إيش Axial + +156 +00:13:19,590 --> 00:13:22,990 +فبعملية ال flipping في جزء الـcyclohexane هاي + +157 +00:13:22,990 --> 00:13:26,350 +الخضر كانوا equatorial صاروا axial الحمر كانوا + +158 +00:13:26,350 --> 00:13:29,190 +axial صاروا equatorial و هكذا الان لما هذا ال + +159 +00:13:29,190 --> 00:13:33,230 +flipping يكون سريع بيصيروا الهيدروجينات نوع واحد + +160 +00:13:33,230 --> 00:13:39,490 +لكن لو بطقناه بالتبريد واضح؟ بيصيروا الهيدروجينات + +161 +00:13:39,490 --> 00:13:45,450 +كام نوع؟نوعين الآن خلوه homework معكوا ابحثولي عن + +162 +00:13:45,450 --> 00:13:50,230 +الـcyclohexane وشوفوا على أي درجة حرارة أقل تقدير + +163 +00:13:50,230 --> 00:13:55,290 +حتى في ال NMR بإمكاننا نشوف الهيدروجين فيه نوعين + +164 +00:13:55,290 --> 00:14:02,110 +واضح عن أنواع الهيدروجين وواجتشق أنا بقدر فعلا أن + +165 +00:14:02,110 --> 00:14:06,550 +أشوف الهيدروجينات في الـcyclohexane نوعين مش نوع + +166 +00:14:06,550 --> 00:14:12,400 +واحدالبنزين لأ البنزين ست هيدروجينات هدوله إيش؟ + +167 +00:14:12,400 --> 00:14:16,360 +مافيش عليهم خلاف they are fully equivalent لكن + +168 +00:14:16,360 --> 00:14:21,060 +اللي في الـcyclohexane بمثال عادي زي هذا اعتبرناهم + +169 +00:14:21,060 --> 00:14:26,060 +نوع واحد وبالتالي وين ما اعملنا ال insertion طبعا + +170 +00:14:26,060 --> 00:14:29,820 +اللي بدها تشوف ال insertion وين ال insertion تتخيل + +171 +00:14:29,820 --> 00:14:33,600 +انه كنا احنا شغالين على هذا الكربون وهي كام + +172 +00:14:33,600 --> 00:14:38,560 +هيدروجين على هذا الكربونهيدروجينتين الان لما صار + +173 +00:14:38,560 --> 00:14:44,780 +عليها التفاعل دلت هيدروجينة وين التانية؟ هايها + +174 +00:14:44,780 --> 00:14:48,720 +ولذلك + +175 +00:14:48,720 --> 00:14:54,320 +لما اقول وين اللي تم ال insertion هايه لاحظوا هذا + +176 +00:14:54,320 --> 00:15:01,700 +الجزء دخل بين ال carbon هذي و ال H تبعيههذا الجزء + +177 +00:15:01,700 --> 00:15:05,820 +من خلال الكاربين دخل بين الكاربون هذا والـ H + +178 +00:15:05,820 --> 00:15:15,920 +تاعتها هاي ال insertion واضحة الفكرة؟ + +179 +00:15:15,920 --> 00:15:21,960 +الآن + +180 +00:15:21,960 --> 00:15:27,470 +بنجي على ال Nitrenes ال Nitrenes نفس التفاعلاتالـ + +181 +00:15:27,470 --> 00:15:31,550 +Carbines Addition عضّب البندق insertion بصير الأمر + +182 +00:15:31,550 --> 00:15:36,750 +سهل لكن لو يجينا يقولنا Formation of Nitrenes برضه + +183 +00:15:36,750 --> 00:15:42,270 +هتلاحظوا ان الإنسان اللي بحب العلم بالموازاة اللي + +184 +00:15:42,270 --> 00:15:46,710 +بحب العلم بالموازاة هيلاحظ ان Formation of + +185 +00:15:46,710 --> 00:15:51,910 +Nitrenes و Carbines نفس الفكرة تماما يعني انا لما + +186 +00:15:51,910 --> 00:15:58,900 +كنت اعمل Formation ofخليني اقول الكربين ايش كنت + +187 +00:15:58,900 --> 00:16:07,140 +اخد؟ دايازو كومباونز يعني هذا المركب كان يكون RCNN + +188 +00:16:07,140 --> 00:16:13,580 +هذه كانت كربون و ايش الجزء اللي بده اشيله؟ + +189 +00:16:13,580 --> 00:16:18,980 +النيتروجين شيلت النيتروجين صار عنده كربين الآن + +190 +00:16:18,980 --> 00:16:24,340 +حولت النيتروجين .. الكربون هذه لنيتروجينبعد المكان + +191 +00:16:24,340 --> 00:16:32,940 +ديازو كمباوند صار ايش N3 ازايد يعني صار R N N + +192 +00:16:32,940 --> 00:16:39,080 +double bond N وشيلوا هذه الان اذا شيلت ال نيتروجين + +193 +00:16:39,080 --> 00:16:43,500 +من ال ديازو كمباوند كربين و اذا شيلت ال نيتروجين + +194 +00:16:43,500 --> 00:16:49,830 +من ال ازايدنيترين إذا هدولا تفاعلات فعلا موزين + +195 +00:16:49,830 --> 00:16:55,310 +لبعض و من البعض ولا لأ؟ 100% كذلك الحال لو أنا + +196 +00:16:55,310 --> 00:17:00,130 +ارجعت فيكم مثلا لنفس ال slide اللي حكينا فيه على + +197 +00:17:00,130 --> 00:17:07,190 +ال generation of الكربين قلنا بدلوا الكربون + +198 +00:17:07,190 --> 00:17:12,810 +بنيتروجين إيش صار هذا المركب؟ أزايد أنيترين شو + +199 +00:17:12,810 --> 00:17:19,540 +هيعطيني؟Nitrate وهنا الكيتيل بدلوا الكربون + +200 +00:17:19,540 --> 00:17:24,860 +بنيتروجيل N double bond C double bond O شو بيصير + +201 +00:17:24,860 --> 00:17:31,840 +اسمه RNCO ايزو + +202 +00:17:31,840 --> 00:17:37,860 +سيانات ايزو سيانات ومر علينا الفنل ايزو سياناتفى + +203 +00:17:37,860 --> 00:17:49,560 +slides تانية ايزو سيا نت ال R N C O ايزو سيا نت ال + +204 +00:17:49,560 --> 00:17:53,000 +ايزو سيا نت لاحظوا ايش التغيير الوحيد بين هدول + +205 +00:17:53,000 --> 00:17:58,740 +الشغلتين تغيير الكربون بنيتروجيل فالكربين من + +206 +00:17:58,740 --> 00:18:04,360 +الديازو كمباونز والكيتينز ال نيترينز بشكل أساسي من + +207 +00:18:04,360 --> 00:18:12,060 +الازايدز والايزو سيا نتوالفقد في الحالتين اما جزء + +208 +00:18:12,060 --> 00:18:19,220 +نيتروجين او جزء carbon monoxide شوفتوا كيف + +209 +00:18:19,220 --> 00:18:24,020 +بالموازاة ممكن نفهم الموضوع الان في طرق تانية كتير + +210 +00:18:24,020 --> 00:18:29,760 +اضافية ولكنها اقل ايش شهرة كلها ايضا فكرة تقوم على + +211 +00:18:29,760 --> 00:18:36,750 +فقد جزيات صغيرة لكن بشكل عام الاساس فقدنيتروجين من + +212 +00:18:36,750 --> 00:18:42,370 +ايش؟ من الازايد فقد نيتروجين من الازايد بيعطيني + +213 +00:18:42,370 --> 00:18:46,250 +نيترين او فقد CO من ال isocyanate خلّيني على + +214 +00:18:46,250 --> 00:18:52,590 +هالطريقتين هذول كطرق أساسية + +215 +00:18:52,590 --> 00:18:57,430 +هيقول لها هنا ال RNCO ايش اللي بتفقدوه؟ carbon + +216 +00:18:57,430 --> 00:19:03,830 +monoxide هتعطيني نيترينلما تفقد ال carbon monoxide + +217 +00:19:03,830 --> 00:19:10,670 +هتعطيني نيترينزي ما حكينا أنه أهم طريقتين + +218 +00:19:10,670 --> 00:19:16,070 +المشهورات لـ generation of nitrenes اللي هي from + +219 +00:19:16,070 --> 00:19:21,350 +azides and isocyanates الآن طرق تانية موجودة لكن + +220 +00:19:21,350 --> 00:19:24,670 +أقل أهمية، بذكرها ذكر سريع بس مانديش أتوقف عندها + +221 +00:19:24,670 --> 00:19:30,150 +مثلا الـ N-Aminoheterocycles أن هذا الـ NH2 + +222 +00:19:30,150 --> 00:19:35,830 +باستعمال الـ lead tetraacetate الـ LTALead + +223 +00:19:35,830 --> 00:19:41,450 +tetraacetate بتعمل هنا نيترين يعني هذه lead + +224 +00:19:41,450 --> 00:19:45,790 +tetraacetate + +225 +00:19:45,790 --> 00:19:51,850 +بتعمل هنا نيترين فعلا هى صار نيترين لو حطينا له + +226 +00:19:51,850 --> 00:19:54,990 +double bond بيعمل cycle addition عليها يعني في + +227 +00:19:54,990 --> 00:19:58,690 +المعادلة اللى عندكم كونا نيترين على هذه ال + +228 +00:19:58,690 --> 00:20:04,070 +nitrogen وحطينا معاها double bond مباشرة فعملت ايش + +229 +00:20:04,600 --> 00:20:09,320 +الـ Cycloaddition Reaction هذا تفاعل خاص أن يكون + +230 +00:20:09,320 --> 00:20:16,040 +موجود عندكم أن أمينوهيتيرو سايكل كذلك من الـ cell + +231 +00:20:16,040 --> 00:20:21,160 +filaments اللي هي الأن ببند أس هذه بالفوتوليسيز + +232 +00:20:21,160 --> 00:20:27,120 +بتفقد كل هذا الجزء وبتعمل نيترين واضح؟ الآن لاحظوا + +233 +00:20:27,120 --> 00:20:33,210 +أنا المهم عندي في هذا الموضوع أن هي عملتفقدت هذا و + +234 +00:20:33,210 --> 00:20:39,990 +كونت نيترين الان ايش النيترين ماحطيلوش double bond + +235 +00:20:39,990 --> 00:20:45,690 +يتفاعل معها ايش بده يعمل بده يحاول قدر الامكان + +236 +00:20:45,690 --> 00:20:49,890 +يعمل insertion الان طبعا ممكن اي واحد تفكر انه + +237 +00:20:49,890 --> 00:20:56,490 +بامكانه يعمل insertion على هيدروجين في جزء تاني او + +238 +00:20:56,490 --> 00:21:00,690 +في نفس الجزءيعني هو الآن هتلاحظ هو هيعمل insertion + +239 +00:21:00,690 --> 00:21:04,650 +على هذا المثل طب يا تورا بيعمل على اللي في الجزء + +240 +00:21:04,650 --> 00:21:10,370 +التاني دائما إذا كان التنافس بال intra molecular + +241 +00:21:10,370 --> 00:21:15,830 +reaction و intermolecular يعني هذه لما نيجي نرسمها + +242 +00:21:15,830 --> 00:21:20,370 +بشكل سليم ال nitrogen مش بعيدة عن المثل يعني طالما + +243 +00:21:20,370 --> 00:21:25,510 +هنا عندكم الكربونيل موجودة يعني التلات روابط كده + +244 +00:21:25,510 --> 00:21:30,970 +تكون الزاوية120 120 120 يعني هذي بتخيلوها كأنها + +245 +00:21:30,970 --> 00:21:34,690 +زيك C double bond O وهي ال Nitrene الان ال Nitrene + +246 +00:21:34,690 --> 00:21:38,310 +بموقع مناسب تماما تعمل insertion مع ال H اللي ها + +247 +00:21:38,310 --> 00:21:43,250 +طبعا لما تعمل insertion حاسين عندي أنا ان H هاي + +248 +00:21:43,250 --> 00:21:50,210 +دخلت ال Nitrene هذه هاي H تنتين و اين التالتة اللي + +249 +00:21:50,210 --> 00:21:55,390 +هاد ال H هدولة تعون المثل فالان دخلت بين ال carbon + +250 +00:21:56,600 --> 00:22:01,780 +والهيدروجين عبلت عملية إيش insertion الآن هذا + +251 +00:22:01,780 --> 00:22:06,800 +التفاعل Intramolecular لو مافيش إمكانية من ناحية + +252 +00:22:06,800 --> 00:22:10,280 +الـ Geometry يصير الـ Intramolecular reaction الـ + +253 +00:22:10,280 --> 00:22:13,780 +Nitrene شو هيعمل؟ هيظل نيترين؟ لأ، بروح بدخل على + +254 +00:22:13,780 --> 00:22:19,360 +مثلمن جزية تانية Intermolecular لكن لما يكون فيه + +255 +00:22:19,360 --> 00:22:23,100 +إمكانية لـ Intermolecular و Intermolecular من يتم + +256 +00:22:23,100 --> 00:22:27,340 +الـ Intermolecular الـ Intermolecular مفضل على ال + +257 +00:22:27,340 --> 00:22:33,220 +Intermolecular الآن هذا الجواب بهذا الشكل افهمناه + +258 +00:22:33,220 --> 00:22:40,200 +لكن لاحظوا انه طلع معه هننتج تاني هذا خارج الموضوع + +259 +00:22:40,200 --> 00:22:45,770 +لكن لأنه مهم و بتكرر لا بأس ان احكيلكوا عليهزائد + +260 +00:22:45,770 --> 00:22:52,190 +NCO إيزو سيانات يعني الـ C double bond O نيترين + +261 +00:22:52,190 --> 00:22:59,010 +صارت إيش؟ إيزو سيانات الـ C double bond O المتصلة + +262 +00:22:59,010 --> 00:23:03,870 +بنيترين بتصير إيزو سيانات يعني كأنه بتجلب الشبك + +263 +00:23:03,870 --> 00:23:08,870 +تبعها صارت هذه الكاربون بدل ما هي شابكة بدل ما هي + +264 +00:23:08,870 --> 00:23:14,150 +شابكة بالـ C اللي هنا صارت شابكة بال إيش؟ بال N + +265 +00:23:15,140 --> 00:23:19,320 +طبعا البعض بيقول كيف تم هذا الكلام هذه + +266 +00:23:19,320 --> 00:23:23,580 +rearrangement مشهورة جدا اسمها Cortes + +267 +00:23:23,580 --> 00:23:27,740 +rearrangement هذه العملية اللي طلعت الناتج التاني + +268 +00:23:27,740 --> 00:23:33,840 +اللي هنا rearrangement مشهورة شو اسمها Cortes + +269 +00:23:33,840 --> 00:23:37,480 +rearrangement في ال Cortes rearrangement خلنا نقول + +270 +00:23:37,480 --> 00:23:41,540 +كان عندنا C double bond O أزايد سخننا صارت C + +271 +00:23:41,540 --> 00:23:46,400 +double bond O نيترينلاحظت أنا الكلام سليم ولا لأ؟ + +272 +00:23:46,400 --> 00:23:50,820 +الآن بعد هيك هذه ال R بتعمل migration بال bond + +273 +00:23:50,820 --> 00:23:55,100 +تبعتها على ال nitrogen فهتصير ايش؟ R عبر حلقة + +274 +00:23:55,100 --> 00:24:04,440 +ثلاثية R N C O واضحة؟ يعني لما نكون راسمينها بهذا + +275 +00:24:04,440 --> 00:24:07,600 +الشكل سهل عليكم أن تتخيلوا هذه الحلقة الثلاثية + +276 +00:24:07,600 --> 00:24:12,400 +اللي تم من خلالها التفاعل؟فصار عندى الكورتياس + +277 +00:24:12,400 --> 00:24:18,360 +rearrangement بهذا الشكل وهذا من أشهر طرق + +278 +00:24:18,360 --> 00:24:21,580 +بالمناسبة تحضير ال isocyanates يعني اللى بده + +279 +00:24:21,580 --> 00:24:28,420 +isocyanates بياخد C double bond O أزايد بخلق C + +280 +00:24:28,420 --> 00:24:33,200 +double bond O نيترين و عندها فرصة عالية تتحول لإيش + +281 +00:24:34,690 --> 00:24:38,990 +عشانك في هذا التفاعل صح هذا ال نيترين عمل ال + +282 +00:24:38,990 --> 00:24:43,370 +insertion لكن عمل كمان تفاعل الأساسي اللي هو ال + +283 +00:24:43,370 --> 00:24:48,380 +courtesary arrangementو في اكتر من rearrangement + +284 +00:24:48,380 --> 00:24:51,400 +حوالين Cortias يعني لو كتبتوا انتوا في google + +285 +00:24:51,400 --> 00:24:55,560 +search Cortias rearrangement الأشياء الشبيهة مع + +286 +00:24:55,560 --> 00:24:59,180 +تغيرات في نوع ال R و إشي هتلاقوا حوالي ستة سبعة + +287 +00:24:59,180 --> 00:25:03,040 +rearrangements كلهم نفس فكرة ال Cortias باسماء + +288 +00:25:03,040 --> 00:25:08,200 +مختلفةكلهم نفس فكرة ال courtesy rearrangement + +289 +00:25:08,200 --> 00:25:11,600 +باسمها مختلفة يعني إذا بتحضرولنا عليهم واحدة تحضر + +290 +00:25:11,600 --> 00:25:15,460 +أن تشرحلنا بدقيقة تقولنا شو أسميهم أو ممكن تشرحهم + +291 +00:25:15,460 --> 00:25:19,560 +مجرد ما تكتبوا courtesy rearrangement هيجيبلكم and + +292 +00:25:19,560 --> 00:25:22,980 +related rearrangements يعني أكتر من rearrangement + +293 +00:25:22,980 --> 00:25:27,380 +كلهم مبدأهم نفس مبدأ إيش ال courtesy rearrangement + +294 +00:25:27,380 --> 00:25:31,180 +بلاش الآن نضايق فيهم أقدر الآن بالنسبة للتفاعلات + +295 +00:25:31,180 --> 00:25:35,700 +مديش أعيد الكلامعنده الـ Cycloaddition على الـ + +296 +00:25:35,700 --> 00:25:43,100 +Double Bond وقلنا إنه بشكل عام بيكون عنده الـ cis + +297 +00:25:43,100 --> 00:25:47,080 +product predominant إذا أنا بدأت بـ cis على أساس + +298 +00:25:47,080 --> 00:25:51,960 +إنه التفاعل concerted يعني one step reaction مش من + +299 +00:25:51,960 --> 00:25:56,020 +خلال biological mechanism يعني الكربين أو الـ + +300 +00:25:56,020 --> 00:26:01,040 +Nitrene إيش حالته؟ singlet والـ Trans لو بتكون + +301 +00:26:01,040 --> 00:26:07,790 +بتكون بنسب قليلةو ال insertion يعني هي مثلا هنا + +302 +00:26:07,790 --> 00:26:12,010 +مثال اتطلعوا عليه مباشرة any three بالتسخين شو + +303 +00:26:12,010 --> 00:26:20,650 +هتصير؟ نيتريل الان وين ال H القريبة؟ هيا ولذلك هذه + +304 +00:26:20,650 --> 00:26:28,330 +هتيجي هنا و ال H؟ وين هتصير؟ عن نيتروجين نشطط + +305 +00:26:34,010 --> 00:26:37,530 +لاحظوا الـ Nitrene دخل بين الـ Carbon و الـ H ولا + +306 +00:26:37,530 --> 00:26:44,390 +لأ؟ هاي ال Nitrene هذه كانت Carbon-H صارت Carbon + +307 +00:26:44,390 --> 00:26:51,070 +-Nitrene-H واضحت فكرة ال insertion كذلك الحال هنا + +308 +00:26:51,070 --> 00:26:55,170 +في هذا المثال الحقيقة اللي هنا تم برضه insertion + +309 +00:26:55,170 --> 00:26:57,190 +على الـ H اللي هنا اللي جاب ال double bond مش + +310 +00:26:57,190 --> 00:27:00,100 +reaction على ال double bondلأن لو هذا بدي أعمل + +311 +00:27:00,100 --> 00:27:02,380 +reaction على الضوء بالموت، بدي أعمل حلقة ثلاثية + +312 +00:27:02,380 --> 00:27:07,040 +ولذلك هنا لما بدأ أطلع في النهاية، إيش كان عندي + +313 +00:27:07,040 --> 00:27:12,420 +هنا؟ H أصار نيترين، هاي هنا H أصار نيترين، إجت الـ + +314 +00:27:12,420 --> 00:27:19,380 +Nitrene هنا، والـH مع الـNitrogen، إذا هذا التفاعل + +315 +00:27:19,380 --> 00:27:24,420 +insertion ولا addition؟insertion لأنه صعب ان اعمل + +316 +00:27:24,420 --> 00:27:28,080 +addition هنا هيك و هيك حلقة ثلاثية بحلقة ربعية + +317 +00:27:28,080 --> 00:27:33,640 +بحلقة سادسية كجيومتري عملية صعبة ولذلك هنا لما + +318 +00:27:33,640 --> 00:27:37,240 +اتكون ال nitrene التفاعل اللي استكمل هو تفاعل + +319 +00:27:37,240 --> 00:27:39,100 +insertion + +320 +00:27:40,920 --> 00:27:44,620 +و في الأمثلة التانية اللي موجودة هنا برضه aside و + +321 +00:27:44,620 --> 00:27:48,640 +insertion على هذا النقطة او هنا N3 aside و + +322 +00:27:48,640 --> 00:27:53,140 +insertion على المثل بتاع الأمر بيصير سهل ممكن بعد + +323 +00:27:53,140 --> 00:27:59,580 +ال insertion هنا تم عملية إيش حذف جزء هيدروجين + +324 +00:27:59,580 --> 00:28:05,700 +يعني اول ما بيصير ال insertion NH و CH2 واضح انه + +325 +00:28:05,700 --> 00:28:12,010 +في ال final product حذف كمان إيشجزء الهيدروجين + +326 +00:28:12,010 --> 00:28:19,270 +طبعا إيش القوة الدافعة لإنه يحدث جزء الهيدروجين؟ + +327 +00:28:19,270 --> 00:28:25,970 +ليش انحدث جزء الهيدروجين هنا؟ أثبت ليش أثبت؟ كلمة + +328 +00:28:25,970 --> 00:28:30,450 +كلمة كلمة أنوار شبطر لإنه المركبaromatic .. + +329 +00:28:30,450 --> 00:28:34,610 +aromaticity .. aromatic يعني لما يتكون بدون ال + +330 +00:28:34,610 --> 00:28:38,530 +double bond اللي هنا حلقتين بتمن إلكترونات حسب + +331 +00:28:38,530 --> 00:28:41,990 +قواعد هوكي اللي قشي بيكونوا aromatic جديش بديلة ال + +332 +00:28:41,990 --> 00:28:49,350 +aromatic عشرة four n plus two متذكرين ال aromatic + +333 +00:28:49,350 --> 00:28:58,530 +البنزين ستة النافتالين عشرة الفنانثرين أربعة عشر + +334 +00:28:59,980 --> 00:29:06,240 +اتذكروا ال aromatic ليش تنسوه؟ هذا إيش؟ can buy + +335 +00:29:06,240 --> 00:29:14,200 +electron النفثالين أخدتوها + +336 +00:29:14,200 --> 00:29:18,720 +قاعدة وكل ولا .. طيب ليش صير انت نسوه؟ + +337 +00:29:23,320 --> 00:29:26,060 +تنين اربعة ستة تمانية عشر اتناش اربعة في تلاتة + +338 +00:29:26,060 --> 00:29:28,120 +اتناش اربعة في تلاتة اتناش اربعة في تلاتة اتناش + +339 +00:29:28,120 --> 00:29:28,600 +اربعة في تلاتة اتناش اربعة في تلاتة اتناش اربعة في + +340 +00:29:28,600 --> 00:29:29,540 +تلاتة اتناش اربعة في تلاتة اتناش اربعة في تلاتة + +341 +00:29:29,540 --> 00:29:32,440 +اتناش اربعة في تلاتة اتناش اربعة في تلاتة اتناش + +342 +00:29:32,440 --> 00:29:35,320 +اربعة في تلاتة اتناش اربعة في تلاتة اتناش اربعة في + +343 +00:29:35,320 --> 00:29:37,900 +تلاتة اتناش اربعة في تلاتة اتناش اربعة في تلاتة + +344 +00:29:37,900 --> 00:29:41,580 +اتناش اربعة في تلاتة اتناش اربعة في تلاتة اتناش + +345 +00:29:41,580 --> 00:29:44,800 +ارب + +346 +00:29:47,280 --> 00:29:51,380 +كذلك الحال في الأمثلة اللي هنا بإمكاننا نطلع أي + +347 +00:29:51,380 --> 00:29:56,940 +نيتلوجين فقد، شو صار عنده؟ كاربين، هذا مثال على + +348 +00:29:56,940 --> 00:30:01,340 +كاربين كويس، مواضحه هنا، الآن كم احتمال insertion + +349 +00:30:01,340 --> 00:30:11,270 +عنده الكاربين هذا؟ اكتر، اكتر، ليش؟هنا احتمال و + +350 +00:30:11,270 --> 00:30:17,810 +هنا احتمال و على هذه المثل و هذه كمان CH2 CH3 كان + +351 +00:30:17,810 --> 00:30:24,610 +بإمكان أي حد يرسم الكياب CH2 CH3 و يخليها .. صح + +352 +00:30:24,610 --> 00:30:29,900 +ولا لأ؟ يعني هذه الإثلشوفوا كيف الإنسان بيوجه + +353 +00:30:29,900 --> 00:30:33,280 +تفكير الناس أحيانا يعني لو هذه الإثر كنت أنا رسمها + +354 +00:30:33,280 --> 00:30:38,520 +CHH و كاتب هنا CH3 إيش اللي صار أقرب؟ إيش اللي + +355 +00:30:38,520 --> 00:30:44,780 +باين لعينيكم؟ انه يعمل هذا ال insertion هذا + +356 +00:30:44,780 --> 00:30:49,800 +insertion على ال secondary بيعطي حلقة سداسية + +357 +00:30:49,800 --> 00:30:57,120 +سداسية شوفوا سداسية الآن ال insertion اللي تم اللي + +358 +00:30:57,120 --> 00:31:05,610 +هناأعطى حلقة خمسية طبعا بتلاحظوا الآن ان هذا ال + +359 +00:31:05,610 --> 00:31:10,550 +insertion على tertiary هذا tertiary و بنفس الوقت + +360 +00:31:10,550 --> 00:31:16,510 +أعطى حلقة خمسية و هاي نتيجة التجربة واضح؟ هاي + +361 +00:31:16,510 --> 00:31:20,010 +نتيجة التجربة في النهاية هنا نفس الاشي برضه هذا + +362 +00:31:20,010 --> 00:31:23,730 +carbon عنده إمكانية ل insertions كتيرة و لجأ انه + +363 +00:31:23,730 --> 00:31:29,270 +أنسب insertion يجي على ال nitrogen اللي هناواضح؟ + +364 +00:31:29,270 --> 00:31:32,890 +لجأ أنه أنسب insertion يجعل نيتروجين لهاتف بعتقد + +365 +00:31:32,890 --> 00:31:37,550 +أنه يعني هذه الأمثلة حقيقة أكتر من كافية الأمثلة + +366 +00:31:37,550 --> 00:31:42,910 +لا تنتهي يعني هي كمان مثال assigned nitrene على ال + +367 +00:31:42,910 --> 00:31:47,150 +مثل insertion حلقة سداسية من أجمل ما يمكن شو اسم + +368 +00:31:47,150 --> 00:31:52,890 +هذا المركب العام؟لاحظوا انتوا كيف انه ال general + +369 +00:31:52,890 --> 00:31:56,930 +methods بتحضروا فيها كل إشي و ع بالمين أحيانا + +370 +00:31:56,930 --> 00:32:01,290 +بيخطر .. ع بالمين بيخطر انه هذا المركب اتحضر من + +371 +00:32:01,290 --> 00:32:07,450 +نيترين كيميسترا يعني لو هذا كان الإنسان بدو ييجي + +372 +00:32:07,450 --> 00:32:14,550 +يفكر .. بدو ييجي يفكر ب retro synthesis إله واضح؟ + +373 +00:32:14,550 --> 00:32:19,220 +الآن حسب ال retro synthesis اللي موجود عندنامن + +374 +00:32:19,220 --> 00:32:23,480 +خلال نيترين كيميسترا لكن بصراحة لو هذا اتيكوا في + +375 +00:32:23,480 --> 00:32:28,200 +امتحان كيف انتوا هتفكروا فيه اسهل ال C double bond + +376 +00:32:28,200 --> 00:32:37,780 +N يتخلوها N H2 و C double bond O مش + +377 +00:32:37,780 --> 00:32:43,480 +هذا كلام منطقي 100% ال C double bond N يتخلوها N + +378 +00:32:43,480 --> 00:32:49,250 +H2 و C double bond O يعني هذا هي حلقة الثيوفينهي + +379 +00:32:49,250 --> 00:32:52,850 +حلقة السيوفين لما يكون عندكم c double bond o و هنا + +380 +00:32:52,850 --> 00:32:57,270 +whatever whatever و هنا and h2 و أكمل المعادلة + +381 +00:32:57,270 --> 00:33:00,990 +واضح؟ + +382 +00:33:00,990 --> 00:33:06,650 +و طبعا هنا ممكن يكون عندكم h الديهايد و لو هذا + +383 +00:33:06,650 --> 00:33:10,090 +بدكم ترجعوا فيه خطوة لورا ماعرفش إذا ممكن تفكروا + +384 +00:33:10,090 --> 00:33:13,750 +في ال smile hack reaction تحطوا ال formula group + +385 +00:33:13,750 --> 00:33:20,790 +اللي هنامش هذي formal ممكن تفكروا بالزمايرهاك لكن + +386 +00:33:20,790 --> 00:33:26,050 +لاحظوا في هذا المثال إجت ب insertion و ال + +387 +00:33:26,050 --> 00:33:29,210 +insertion بالمناسبة ممتبوعة ب oxidation يعني فقد + +388 +00:33:29,210 --> 00:33:33,910 +فيه هيدروجين تاني لأن أساس ناتج ال insertion هنا + +389 +00:33:33,910 --> 00:33:39,750 +إيش بدو يكون un-etch, etch, etch بس لما فقدوا + +390 +00:33:39,750 --> 00:33:45,180 +الهيدروجين تاني ضالت بس etch واحدةيعني هذا الناتج + +391 +00:33:45,180 --> 00:33:51,060 +هو ناتج insertion followed by oxidation أو loss of + +392 +00:33:51,060 --> 00:33:59,140 +hydrogen واضح؟ بهيك تقريبا بننتهي من موضوع ال + +393 +00:33:59,140 --> 00:33:59,960 +nitrenes + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/1qWv9p9o0Os_raw.json b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/1qWv9p9o0Os_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..f5e37a0aa389f1e5b432f246656c1a348f3bb1b3 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/1qWv9p9o0Os_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4090, "start": 20.77, "end": 40.91, "text": "بسم الله الرحمن الرحيم المرة الماضية في موضوع تحضير المراكبات الحلقية اتكلمنا على نوع من ال reactive intermediates اللي هم ال carbines و ال nitrines عرفنا إيش معنى carbine و إيش معنى nitrine كيف نعمل generation لل carbine", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 8978, 3714, 2407, 11242, 45367, 6055, 5016, 11242, 13546, 9673, 23557, 4117, 3555, 9307, 21542, 1211, 4587, 10632, 1975, 2655, 4117, 19528, 8315, 15844, 8717, 45367, 9154, 2423, 28897, 15184, 1024, 13672, 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reaction", "probability": 0.91650390625}, {"start": 344.1, "end": 344.72, "word": " draw", "probability": 0.20263671875}, {"start": 344.72, "end": 345.1, "word": " all", "probability": 0.96240234375}, {"start": 345.1, "end": 345.34, "word": " the", "probability": 0.9208984375}, {"start": 345.34, "end": 345.74, "word": " possible", "probability": 0.962890625}, {"start": 345.74, "end": 346.46, "word": " insertion", "probability": 0.986083984375}, {"start": 346.46, "end": 346.86, "word": " products", "probability": 0.86279296875}, {"start": 346.86, "end": 347.12, "word": " for", "probability": 0.9541015625}, {"start": 347.12, "end": 347.36, "word": " this", "probability": 0.9619140625}, {"start": 347.36, "end": 347.88, "word": " reaction", "probability": 0.91650390625}, {"start": 347.88, "end": 348.68, "word": " هذا", "probability": 0.9345703125}, {"start": 348.68, "end": 349.54, "word": " أحد", "probability": 0.87939453125}, {"start": 349.54, "end": 349.72, "word": " ال", "probability": 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"word": " هنا", "probability": 0.89306640625}, {"start": 379.63, "end": 379.85, "word": " لما", "probability": 0.910888671875}, {"start": 379.85, "end": 380.23, "word": " احط", "probability": 0.9435221354166666}], "temperature": 1.0}, {"id": 15, "seek": 40812, "start": 381.04, "end": 408.12, "text": "CH2 واتصلت بالـ H CH2 عملت insertion هنا صار الجزء CH3 CH2 CH2 CH3 هذا ال insertion اللي هنا على secondary carbon هذا ال insertion اللي هنا على primary carbon الآن التجربة بتقول انه بشكل عام بشكل عام ال insertion", "tokens": [5462, 17, 4032, 9307, 36520, 2655, 20666, 39184, 389, 5995, 17, 6225, 42213, 2655, 8969, 313, 34105, 20328, 9640, 25724, 11622, 38207, 5995, 18, 5995, 17, 5995, 17, 5995, 18, 23758, 2423, 8969, 313, 13672, 1829, 34105, 15844, 11396, 5954, 23758, 2423, 8969, 313, 13672, 1829, 34105, 15844, 6194, 5954, 6024, 48506, 16712, 7435, 25513, 3660, 39894, 39648, 16472, 3224, 4724, 8592, 28820, 6225, 10943, 4724, 8592, 28820, 6225, 10943, 2423, 8969, 313], "avg_logprob": 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{"start": 389.04, "end": 389.54, "word": " CH2", "probability": 0.88671875}, {"start": 389.54, "end": 390.32, "word": " CH2", "probability": 0.95166015625}, {"start": 390.32, "end": 391.82, "word": " CH3", "probability": 0.89208984375}, {"start": 391.82, "end": 392.7, "word": " هذا", "probability": 0.744140625}, {"start": 392.7, "end": 392.92, "word": " ال", "probability": 0.86865234375}, {"start": 392.92, "end": 393.5, "word": " insertion", "probability": 0.96875}, {"start": 393.5, "end": 393.64, "word": " اللي", "probability": 0.87451171875}, {"start": 393.64, "end": 393.8, "word": " هنا", "probability": 0.84765625}, {"start": 393.8, "end": 394.02, "word": " على", "probability": 0.56787109375}, {"start": 394.02, "end": 394.6, "word": " secondary", "probability": 0.84521484375}, {"start": 394.6, "end": 395.26, "word": " carbon", "probability": 0.9365234375}, {"start": 395.26, "end": 395.86, "word": " هذا", "probability": 0.91748046875}, {"start": 395.86, "end": 396.02, "word": " ال", 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الآن حسب التجربة اللى طلعت ان هذا ال insertion ع secondary هذا ال insertion ع primary ان هو اللى بيكون مفضل ال insertion اللى على ال secondary الان لو أخدت أنا", "tokens": [40228, 22653, 34105, 19446, 41185, 8592, 43242, 7578, 560, 2356, 4812, 17792, 5480, 6156, 7578, 43242, 7578, 1975, 33753, 2304, 6027, 9957, 6024, 48506, 11331, 35457, 16712, 7435, 25513, 3660, 13672, 7578, 23032, 1211, 34268, 16472, 23758, 2423, 8969, 313, 6225, 11396, 23758, 2423, 8969, 313, 6225, 6194, 16472, 31439, 13672, 7578, 4724, 1829, 30544, 3714, 5172, 11242, 1211, 2423, 8969, 313, 13672, 7578, 15844, 2423, 11396, 2423, 7649, 45164, 5551, 9778, 3215, 2655, 41850], "avg_logprob": -0.21340460761597282, "compression_ratio": 1.712041884816754, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 426.23, "end": 426.57, "word": "يعني", "probability": 0.688720703125}, {"start": 426.57, "end": 426.99, "word": " هنا", "probability": 0.84814453125}, {"start": 426.99, "end": 427.77, "word": " مافيش", 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"probability": 0.685546875}, {"start": 641.93, "end": 642.77, "word": " تمام؟", "probability": 0.9607747395833334}, {"start": 642.77, "end": 643.27, "word": " الآن", "probability": 0.7568359375}, {"start": 643.27, "end": 644.05, "word": " الـ", "probability": 0.794189453125}, {"start": 644.05, "end": 644.93, "word": " Cyclohexane", "probability": 0.8654378255208334}, {"start": 644.93, "end": 645.17, "word": " in", "probability": 0.73193359375}, {"start": 645.17, "end": 645.91, "word": " principle", "probability": 0.89794921875}, {"start": 645.91, "end": 646.63, "word": " كل", "probability": 0.81298828125}, {"start": 646.63, "end": 647.07, "word": " ذرات", "probability": 0.9065755208333334}, {"start": 647.07, "end": 647.69, "word": " الهيدروجين", "probability": 0.9517415364583334}, {"start": 647.69, "end": 648.43, "word": " تبعته", "probability": 0.917724609375}], "temperature": 1.0}, {"id": 26, "seek": 67814, "start": 649.3, "end": 678.14, "text": "أقل تقدير على حرارة الغرفة واضح؟ ليش قلنا جملة على حرارة الغرفة؟ حد بيقدر يتذكر؟ لأن الـ Cyclohexane الناس اللي بيذكروا ال conformations تبعت الـ Cyclohexane لما ياخد ال chair و ال boat conformation", "tokens": [10721, 4587, 1211, 6055, 28543, 13546, 15844, 11331, 2288, 9640, 3660, 6024, 118, 28480, 3660, 4032, 46958, 5016, 22807, 32239, 8592, 12174, 1211, 8315, 10874, 42213, 3660, 15844, 11331, 2288, 9640, 3660, 6024, 118, 28480, 3660, 22807, 11331, 3215, 4724, 1829, 28543, 2288, 7251, 2655, 8848, 37983, 22807, 5296, 33456, 2423, 39184, 10295, 66, 752, 675, 87, 1929, 2423, 8315, 3794, 13672, 1829, 4724, 1829, 8848, 37983, 14407, 2423, 18975, 763, 6055, 3555, 34268, 2423, 39184, 10295, 66, 752, 675, 87, 1929, 5296, 15042, 7251, 47283, 3215, 2423, 6090, 4032, 2423, 6582, 18975, 399], "avg_logprob": -0.1768092161730716, "compression_ratio": 1.6329787234042554, "no_speech_prob": 0.0, "words": [{"start": 649.3, "end": 650.24, "word": "أقل", "probability": 0.8987630208333334}, {"start": 650.24, "end": 650.64, "word": " تقدير", 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"probability": 0.873779296875}, {"start": 699.09, "end": 700.33, "word": " اتنين", "probability": 0.8978271484375}, {"start": 700.33, "end": 701.19, "word": " تلاتة", "probability": 0.94677734375}, {"start": 701.19, "end": 702.09, "word": " اربعة", "probability": 0.8543294270833334}, {"start": 702.09, "end": 703.03, "word": " خمسة", "probability": 0.9613037109375}, {"start": 703.03, "end": 704.01, "word": " ستة", "probability": 0.9811197916666666}, {"start": 704.01, "end": 704.69, "word": " ستة", "probability": 0.9012044270833334}, {"start": 704.69, "end": 705.23, "word": " axial", "probability": 0.94189453125}, {"start": 705.23, "end": 705.75, "word": " و", "probability": 0.89501953125}, {"start": 705.75, "end": 706.43, "word": " ستة", "probability": 0.8525390625}], "temperature": 1.0}, {"id": 28, "seek": 70963, "start": 707.03, "end": 709.63, "text": "equatorial تمام طبعا", "tokens": [12816, 1639, 831, 46811, 10943, 23032, 3555, 3615, 995], "avg_logprob": -0.3679687410593033, 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"end": 847.03, "text": "نوعين الآن خلوه homework معكوا ابحثولي عن الـcyclohexane وشوفوا على أي درجة حرارة أقل تقدير حتى في ال NMR بإمكاننا نشوف الهيدروجين فيه نوعين واضح عن أنواع الهيدروجين وواجتشق أنا بقدر فعلا أن أشوف الهيدروجينات في الـcyclohexane نوعين مش نوع واحد", "tokens": [1863, 45367, 9957, 6024, 48506, 16490, 1211, 2407, 3224, 14578, 20449, 4117, 14407, 48127, 5016, 12984, 12610, 1829, 18871, 2423, 39184, 1344, 66, 752, 675, 87, 1929, 4032, 8592, 38688, 14407, 15844, 36632, 11778, 47341, 3660, 11331, 2288, 9640, 3660, 5551, 4587, 1211, 6055, 28543, 13546, 11331, 49975, 8978, 2423, 426, 21173, 4724, 28814, 2304, 41361, 8315, 8717, 8592, 38688, 2423, 3224, 25708, 2288, 29245, 9957, 8978, 3224, 8717, 45367, 9957, 4032, 46958, 5016, 18871, 14739, 14407, 3615, 2423, 3224, 25708, 2288, 29245, 9957, 4032, 2407, 26108, 2655, 8592, 4587, 41850, 4724, 28543, 2288, 6156, 3615, 15040, 14739, 5551, 8592, 38688, 2423, 3224, 25708, 2288, 29245, 9957, 9307, 8978, 2423, 39184, 1344, 66, 752, 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{"id": 36, "seek": 92628, "start": 900.8, "end": 926.28, "text": "هذا الجزء من خلال الكاربين دخل بين الكاربون هذا والـ H تاعتها هاي ال insertion واضحة الفكرة؟ الآن بنجي على ال Nitrenes ال Nitrenes نفس التفاعلات", "tokens": [3224, 15730, 25724, 11622, 38207, 9154, 16490, 1211, 6027, 33251, 9640, 3555, 9957, 11778, 9778, 1211, 49374, 33251, 9640, 3555, 11536, 23758, 16070, 39184, 389, 6055, 995, 34268, 11296, 8032, 47302, 2423, 8969, 313, 4032, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 6024, 48506, 44945, 7435, 1829, 15844, 2423, 37942, 1095, 279, 2423, 37942, 1095, 279, 8717, 36178, 16712, 5172, 995, 30241, 9307], "avg_logprob": -0.2951660044491291, "compression_ratio": 1.5389610389610389, "no_speech_prob": 0.0, "words": [{"start": 900.8, "end": 901.24, "word": "هذا", "probability": 0.91796875}, {"start": 901.24, "end": 901.7, "word": " الجزء", "probability": 0.9796549479166666}, {"start": 901.7, "end": 901.82, "word": " من", "probability": 0.97314453125}, {"start": 901.82, "end": 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1422.08, "end": 1422.54, "word": " O", "probability": 0.9833984375}, {"start": 1422.54, "end": 1423.46, "word": " نيترين", "probability": 0.8648681640625}], "temperature": 1.0}, {"id": 56, "seek": 144920, "start": 1424.06, "end": 1449.2, "text": "لاحظت أنا الكلام سليم ولا لأ؟ الآن بعد هيك هذه ال R بتعمل migration بال bond تبعتها على ال nitrogen فهتصير ايش؟ R عبر حلقة ثلاثية R N C O واضحة؟ يعني لما نكون راسمينها بهذا الشكل سهل عليكم أن تتخيلوا هذه الحلقة الثلاثية اللي تم من خلالها التفاعل؟", "tokens": [15040, 5016, 19913, 2655, 41850, 2423, 28820, 10943, 8608, 20292, 2304, 49429, 5296, 10721, 22807, 6024, 48506, 39182, 39896, 4117, 29538, 2423, 497, 39894, 25957, 1211, 17011, 20666, 6086, 6055, 3555, 34268, 11296, 15844, 2423, 17903, 6156, 3224, 2655, 9381, 13546, 1975, 1829, 8592, 22807, 497, 6225, 26890, 11331, 1211, 28671, 38637, 1211, 5718, 104, 10632, 497, 426, 383, 422, 4032, 46958, 5016, 3660, 22807, 37495, 22653, 5296, 15042, 8717, 30544, 12602, 32277, 2304, 9957, 11296, 39627, 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"probability": 0.86767578125}, {"start": 1427.52, "end": 1428.04, "word": " هيك", "probability": 0.90771484375}, {"start": 1428.04, "end": 1428.48, "word": " هذه", "probability": 0.69677734375}, {"start": 1428.48, "end": 1428.62, "word": " ال", "probability": 0.88818359375}, {"start": 1428.62, "end": 1428.76, "word": " R", "probability": 0.401123046875}, {"start": 1428.76, "end": 1429.28, "word": " بتعمل", "probability": 0.939453125}, {"start": 1429.28, "end": 1429.96, "word": " migration", "probability": 0.72021484375}, {"start": 1429.96, "end": 1430.56, "word": " بال", "probability": 0.9453125}, {"start": 1430.56, "end": 1430.82, "word": " bond", "probability": 0.6572265625}, {"start": 1430.82, "end": 1431.28, "word": " تبعتها", "probability": 0.8504638671875}, {"start": 1431.28, "end": 1431.46, "word": " على", "probability": 0.84423828125}, {"start": 1431.46, "end": 1431.6, "word": " ال", "probability": 0.9140625}, {"start": 1431.6, "end": 1432.2, "word": " nitrogen", "probability": 0.87158203125}, {"start": 1432.2, "end": 1432.94, "word": " فهتصير", "probability": 0.8474609375}, {"start": 1432.94, "end": 1433.68, "word": " ايش؟", "probability": 0.781982421875}, {"start": 1433.68, "end": 1434.12, "word": " R", "probability": 0.77197265625}, {"start": 1434.12, "end": 1434.72, "word": " عبر", "probability": 0.8203125}, {"start": 1434.72, "end": 1435.1, "word": " حلقة", "probability": 0.9851888020833334}, {"start": 1435.1, "end": 1435.84, "word": " ثلاثية", "probability": 0.98603515625}, {"start": 1435.84, "end": 1437.66, "word": " R", "probability": 0.32421875}, {"start": 1437.66, "end": 1438.6, "word": " N", "probability": 0.4775390625}, {"start": 1438.6, "end": 1439.62, "word": " C", "probability": 0.80908203125}, {"start": 1439.62, "end": 1440.36, "word": " O", "probability": 0.9951171875}, {"start": 1440.36, "end": 1443.12, "word": " واضحة؟", "probability": 0.91943359375}, {"start": 1443.12, "end": 1443.38, "word": " يعني", "probability": 0.970947265625}, {"start": 1443.38, "end": 1443.5, "word": " لما", "probability": 0.75146484375}, {"start": 1443.5, "end": 1443.7, "word": " نكون", "probability": 0.966064453125}, {"start": 1443.7, "end": 1444.16, "word": " راسمينها", "probability": 0.76982421875}, {"start": 1444.16, "end": 1444.44, "word": " بهذا", "probability": 0.714111328125}, {"start": 1444.44, "end": 1444.86, "word": " الشكل", "probability": 0.994140625}, {"start": 1444.86, "end": 1445.44, "word": " سهل", "probability": 0.9617513020833334}, {"start": 1445.44, "end": 1445.82, "word": " عليكم", "probability": 0.710693359375}, {"start": 1445.82, "end": 1445.96, "word": " أن", "probability": 0.462646484375}, {"start": 1445.96, "end": 1446.46, "word": " تتخيلوا", "probability": 0.87236328125}, {"start": 1446.46, "end": 1446.66, "word": " هذه", "probability": 0.95068359375}, {"start": 1446.66, "end": 1447.06, "word": " الحلقة", "probability": 0.9881184895833334}, {"start": 1447.06, "end": 1447.6, "word": " الثلاثية", "probability": 0.9755045572916666}, {"start": 1447.6, "end": 1447.74, "word": " اللي", "probability": 0.76220703125}, {"start": 1447.74, "end": 1447.94, "word": " تم", "probability": 0.89306640625}, {"start": 1447.94, "end": 1448.08, "word": " من", "probability": 0.90771484375}, {"start": 1448.08, "end": 1448.44, "word": " خلالها", "probability": 0.9947509765625}, {"start": 1448.44, "end": 1449.2, "word": " التفاعل؟", "probability": 0.9509765625}], "temperature": 1.0}, {"id": 57, "seek": 147320, "start": 1449.92, "end": 1473.2, "text": "فصار عندى الكورتياس rearrangement بهذا الشكل وهذا من أشهر طرق بالمناسبة تحضير ال isocyanates يعني اللى بده isocyanates بياخد C double bond O أزايد بخلق C double bond O نيترين و عندها فرصة عالية تتحول لإيش", "tokens": [5172, 9381, 9640, 43242, 7578, 33251, 13063, 31371, 32277, 39568, 518, 39627, 15730, 25124, 28820, 37037, 15730, 9154, 5551, 8592, 3224, 2288, 23032, 2288, 4587, 20666, 2304, 8315, 35457, 3660, 6055, 5016, 11242, 13546, 2423, 307, 905, 6277, 1024, 37495, 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"probability": 0.53955078125}, {"start": 1457.44, "end": 1457.58, "word": " من", "probability": 0.91552734375}, {"start": 1457.58, "end": 1458.02, "word": " أشهر", "probability": 0.9403076171875}, {"start": 1458.02, "end": 1458.36, "word": " طرق", "probability": 0.822265625}, {"start": 1458.36, "end": 1458.98, "word": " بالمناسبة", "probability": 0.93564453125}, {"start": 1458.98, "end": 1459.36, "word": " تحضير", "probability": 0.8829345703125}, {"start": 1459.36, "end": 1459.5, "word": " ال", "probability": 0.853515625}, {"start": 1459.5, "end": 1460.38, "word": " isocyanates", "probability": 0.7325439453125}, {"start": 1460.38, "end": 1461.14, "word": " يعني", "probability": 0.7998046875}, {"start": 1461.14, "end": 1461.28, "word": " اللى", "probability": 0.88134765625}, {"start": 1461.28, "end": 1461.58, "word": " بده", "probability": 0.857666015625}, {"start": 1461.58, "end": 1462.58, "word": " isocyanates", "probability": 0.8587646484375}, {"start": 1462.58, "end": 1464.32, "word": " بياخد", "probability": 0.9127197265625}, {"start": 1464.32, "end": 1466.02, "word": " C", "probability": 0.306884765625}, {"start": 1466.02, "end": 1466.2, "word": " double", "probability": 0.2685546875}, {"start": 1466.2, "end": 1466.6, "word": " bond", "probability": 0.9169921875}, {"start": 1466.6, "end": 1467.1, "word": " O", "probability": 0.91796875}, {"start": 1467.1, "end": 1467.86, "word": " أزايد", "probability": 0.6717529296875}, {"start": 1467.86, "end": 1468.22, "word": " بخلق", "probability": 0.637451171875}, {"start": 1468.22, "end": 1468.42, "word": " C", "probability": 0.68896484375}, {"start": 1468.42, "end": 1468.58, "word": " double", "probability": 0.85595703125}, {"start": 1468.58, "end": 1468.82, "word": " bond", "probability": 0.94775390625}, {"start": 1468.82, "end": 1468.98, "word": " O", "probability": 0.96337890625}, {"start": 1468.98, "end": 1469.64, "word": " نيترين", "probability": 0.908203125}, {"start": 1469.64, "end": 1470.5, "word": " و", "probability": 0.86669921875}, {"start": 1470.5, "end": 1471.3, "word": " عندها", "probability": 0.5146484375}, {"start": 1471.3, "end": 1471.72, "word": " فرصة", "probability": 0.994384765625}, {"start": 1471.72, "end": 1472.02, "word": " عالية", "probability": 0.96875}, {"start": 1472.02, "end": 1472.68, "word": " تتحول", "probability": 0.827880859375}, {"start": 1472.68, "end": 1473.2, "word": " لإيش", "probability": 0.8299560546875}], "temperature": 1.0}, {"id": 58, "seek": 148587, "start": 1474.69, "end": 1485.87, "text": "عشانك في هذا التفاعل صح هذا ال نيترين عمل ال insertion لكن عمل كمان تفاعل الأساسي اللي هو ال courtesary arrangement", "tokens": [3615, 8592, 7649, 4117, 8978, 23758, 16712, 5172, 995, 30241, 20328, 5016, 23758, 2423, 8717, 36081, 2288, 9957, 6225, 42213, 2423, 8969, 313, 44381, 6225, 42213, 9122, 2304, 7649, 6055, 5172, 995, 30241, 16247, 3794, 32277, 1829, 13672, 1829, 31439, 2423, 4753, 279, 822, 17620], "avg_logprob": -0.35054346465546155, "compression_ratio": 1.3533834586466165, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1474.6899999999998, "end": 1475.57, "word": "عشانك", "probability": 0.6363525390625}, {"start": 1475.57, "end": 1475.71, "word": " في", "probability": 0.76611328125}, {"start": 1475.71, "end": 1475.99, "word": " هذا", "probability": 0.81103515625}, {"start": 1475.99, "end": 1476.69, "word": " التفاعل", "probability": 0.9306640625}, {"start": 1476.69, "end": 1477.51, "word": " صح", "probability": 0.885009765625}, {"start": 1477.51, "end": 1477.77, "word": " هذا", "probability": 0.7939453125}, {"start": 1477.77, "end": 1477.91, "word": " ال", "probability": 0.6181640625}, {"start": 1477.91, "end": 1478.43, "word": " نيترين", "probability": 0.721832275390625}, {"start": 1478.43, "end": 1478.83, "word": " عمل", "probability": 0.91845703125}, {"start": 1478.83, "end": 1478.99, "word": " ال", "probability": 0.73779296875}, {"start": 1478.99, "end": 1479.97, "word": " insertion", "probability": 0.97119140625}, {"start": 1479.97, "end": 1480.71, "word": " لكن", "probability": 0.73193359375}, {"start": 1480.71, "end": 1481.43, "word": " عمل", "probability": 0.978759765625}, {"start": 1481.43, "end": 1481.81, "word": " كمان", "probability": 0.7716471354166666}, {"start": 1481.81, "end": 1482.35, "word": " تفاعل", "probability": 0.9349365234375}, {"start": 1482.35, "end": 1483.01, "word": " الأساسي", "probability": 0.7542724609375}, {"start": 1483.01, "end": 1483.05, "word": " اللي", "probability": 0.72216796875}, {"start": 1483.05, "end": 1483.25, "word": " هو", "probability": 0.97412109375}, {"start": 1483.25, "end": 1483.37, "word": " ال", "probability": 0.40380859375}, {"start": 1483.37, "end": 1485.43, "word": " courtesary", "probability": 0.3167317708333333}, {"start": 1485.43, "end": 1485.87, "word": " arrangement", "probability": 0.67138671875}], "temperature": 1.0}, {"id": 59, "seek": 150380, "start": 1486.62, "end": 1503.8, "text": "و في اكتر من rearrangement حوالين Cortias يعني لو كتبتوا انتوا في google search Cortias rearrangement الأشياء الشبيهة مع تغيرات في نوع ال R و إشي هتلاقوا حوالي ستة سبعة rearrangements كلهم نفس فكرة ال Cortias باسماء مختلفة", "tokens": [2407, 8978, 1975, 4117, 2655, 2288, 9154, 39568, 518, 11331, 2407, 6027, 9957, 28522, 4609, 37495, 22653, 45164, 9122, 2655, 3555, 2655, 14407, 16472, 2655, 14407, 8978, 20742, 3164, 28522, 4609, 39568, 518, 16247, 8592, 1829, 16606, 25124, 21292, 3224, 3660, 20449, 6055, 17082, 13546, 9307, 8978, 8717, 45367, 2423, 497, 4032, 11933, 8592, 1829, 8032, 2655, 15040, 4587, 14407, 11331, 2407, 6027, 1829, 8608, 2655, 3660, 8608, 3555, 27884, 39568, 1117, 28242, 16095, 8717, 36178, 6156, 4117, 25720, 2423, 28522, 4609, 4724, 32277, 2304, 16606, 3714, 46456, 46538, 3660], "avg_logprob": -0.1671531583581652, "compression_ratio": 1.6323529411764706, "no_speech_prob": 0.0, "words": [{"start": 1486.62, "end": 1486.82, "word": "و", "probability": 0.61474609375}, {"start": 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{"start": 1491.4, "end": 1492.04, "word": " search", "probability": 0.970703125}, {"start": 1492.04, "end": 1492.94, "word": " Cortias", "probability": 0.788818359375}, {"start": 1492.94, "end": 1494.02, "word": " rearrangement", "probability": 0.826416015625}, {"start": 1494.02, "end": 1494.78, "word": " الأشياء", "probability": 0.948486328125}, {"start": 1494.78, "end": 1495.46, "word": " الشبيهة", "probability": 0.8486328125}, {"start": 1495.46, "end": 1495.56, "word": " مع", "probability": 0.974609375}, {"start": 1495.56, "end": 1496.2, "word": " تغيرات", "probability": 0.974365234375}, {"start": 1496.2, "end": 1496.36, "word": " في", "probability": 0.9296875}, {"start": 1496.36, "end": 1496.54, "word": " نوع", "probability": 0.988037109375}, {"start": 1496.54, "end": 1496.7, "word": " ال", "probability": 0.89404296875}, {"start": 1496.7, "end": 1496.88, "word": " R", "probability": 0.62841796875}, {"start": 1496.88, "end": 1497.0, "word": " و", "probability": 0.6640625}, {"start": 1497.0, "end": 1497.34, "word": " إشي", "probability": 0.7176920572916666}, {"start": 1497.34, "end": 1498.0, "word": " هتلاقوا", "probability": 0.847265625}, {"start": 1498.0, "end": 1498.44, "word": " حوالي", "probability": 0.9403076171875}, {"start": 1498.44, "end": 1498.84, "word": " ستة", "probability": 0.8186848958333334}, {"start": 1498.84, "end": 1499.18, "word": " سبعة", "probability": 0.8250325520833334}, {"start": 1499.18, "end": 1500.32, "word": " rearrangements", "probability": 0.93408203125}, {"start": 1500.32, "end": 1501.14, "word": " كلهم", "probability": 0.953369140625}, {"start": 1501.14, "end": 1501.44, "word": " نفس", "probability": 0.99560546875}, {"start": 1501.44, "end": 1501.82, "word": " فكرة", "probability": 0.9733072916666666}, {"start": 1501.82, "end": 1502.02, "word": " ال", "probability": 0.7333984375}, {"start": 1502.02, "end": 1502.54, "word": " Cortias", "probability": 0.919189453125}, {"start": 1502.54, "end": 1503.04, "word": " باسماء", "probability": 0.8228759765625}, {"start": 1503.04, "end": 1503.8, "word": " مختلفة", "probability": 0.9954833984375}], "temperature": 1.0}, {"id": 60, "seek": 153250, "start": 1504.76, "end": 1532.5, "text": "كلهم نفس فكرة ال courtesy rearrangement باسمها مختلفة يعني إذا بتحضرولنا عليهم واحدة تحضر أن تشرحلنا بدقيقة تقولنا شو أسميهم أو ممكن تشرحهم مجرد ما تكتبوا courtesy rearrangement هيجيبلكم and related rearrangements يعني أكتر من rearrangement كلهم مبدأهم نفس مبدأ إيش ال courtesy rearrangement بلاش الآن نضايق فيهم أقدر الآن بالنسبة للتفاعلات مديش أعيد الكلام", "tokens": [28820, 16095, 8717, 36178, 6156, 4117, 25720, 2423, 4753, 279, 88, 39568, 518, 4724, 32277, 2304, 11296, 3714, 46456, 46538, 3660, 37495, 22653, 11933, 15730, 39894, 5016, 11242, 2288, 12610, 8315, 25894, 16095, 36764, 24401, 3660, 6055, 5016, 11242, 2288, 14739, 6055, 46309, 5016, 1211, 8315, 4724, 3215, 38436, 28671, 6055, 39648, 8315, 13412, 2407, 5551, 38251, 1829, 16095, 34051, 3714, 43020, 6055, 46309, 5016, 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0.54638671875}, {"start": 1507.04, "end": 1507.64, "word": " courtesy", "probability": 0.3583170572916667}, {"start": 1507.64, "end": 1508.2, "word": " rearrangement", "probability": 0.87353515625}, {"start": 1508.2, "end": 1508.58, "word": " باسمها", "probability": 0.8026123046875}, {"start": 1508.58, "end": 1509.08, "word": " مختلفة", "probability": 0.9835205078125}, {"start": 1509.08, "end": 1509.48, "word": " يعني", "probability": 0.849609375}, {"start": 1509.48, "end": 1509.68, "word": " إذا", "probability": 0.876220703125}, {"start": 1509.68, "end": 1510.46, "word": " بتحضرولنا", "probability": 0.872802734375}, {"start": 1510.46, "end": 1510.88, "word": " عليهم", "probability": 0.916748046875}, {"start": 1510.88, "end": 1511.16, "word": " واحدة", "probability": 0.87109375}, {"start": 1511.16, "end": 1511.6, "word": " تحضر", "probability": 0.926513671875}, {"start": 1511.6, "end": 1512.04, "word": " أن", "probability": 0.2890625}, {"start": 1512.04, "end": 1512.68, "word": " تشرحلنا", "probability": 0.92177734375}, {"start": 1512.68, "end": 1513.1, "word": " بدقيقة", "probability": 0.721282958984375}, {"start": 1513.1, "end": 1513.46, "word": " تقولنا", "probability": 0.9485677083333334}, {"start": 1513.46, "end": 1513.64, "word": " شو", "probability": 0.893798828125}, {"start": 1513.64, "end": 1514.26, "word": " أسميهم", "probability": 0.935302734375}, {"start": 1514.26, "end": 1514.44, "word": " أو", "probability": 0.88623046875}, {"start": 1514.44, "end": 1514.72, "word": " ممكن", "probability": 0.9833984375}, {"start": 1514.72, "end": 1515.46, "word": " تشرحهم", "probability": 0.9947509765625}, {"start": 1515.46, "end": 1516.42, "word": " مجرد", "probability": 0.95556640625}, {"start": 1516.42, "end": 1516.52, "word": " ما", "probability": 0.78369140625}, {"start": 1516.52, "end": 1516.94, "word": " تكتبوا", "probability": 0.9861328125}, {"start": 1516.94, "end": 1517.5, "word": " courtesy", "probability": 0.6815592447916666}, {"start": 1517.5, "end": 1518.04, "word": " rearrangement", "probability": 0.9072265625}, {"start": 1518.04, "end": 1519.16, "word": " هيجيبلكم", "probability": 0.8636881510416666}, {"start": 1519.16, "end": 1519.56, "word": " and", "probability": 0.86572265625}, {"start": 1519.56, "end": 1520.38, "word": " related", "probability": 0.97314453125}, {"start": 1520.38, "end": 1521.32, "word": " rearrangements", "probability": 0.896240234375}, {"start": 1521.32, "end": 1521.56, "word": " يعني", "probability": 0.919189453125}, {"start": 1521.56, "end": 1521.96, "word": " أكتر", "probability": 0.928955078125}, {"start": 1521.96, "end": 1522.1, "word": " من", "probability": 0.99462890625}, {"start": 1522.1, "end": 1522.98, "word": " rearrangement", "probability": 0.826171875}, {"start": 1522.98, "end": 1523.6, "word": " كلهم", "probability": 0.91015625}, {"start": 1523.6, "end": 1524.12, "word": " مبدأهم", "probability": 0.959716796875}, {"start": 1524.12, "end": 1524.4, "word": " نفس", "probability": 0.99560546875}, {"start": 1524.4, "end": 1524.92, "word": " مبدأ", "probability": 0.97314453125}, {"start": 1524.92, "end": 1525.32, "word": " إيش", "probability": 0.7654622395833334}, {"start": 1525.32, "end": 1526.32, "word": " ال", "probability": 0.521484375}, {"start": 1526.32, "end": 1526.9, "word": " courtesy", "probability": 0.8614908854166666}, {"start": 1526.9, "end": 1527.38, "word": " rearrangement", "probability": 0.938720703125}, {"start": 1527.38, "end": 1527.72, "word": " بلاش", "probability": 0.7081705729166666}, {"start": 1527.72, "end": 1527.96, "word": " الآن", "probability": 0.73779296875}, {"start": 1527.96, "end": 1528.32, "word": " نضايق", "probability": 0.707275390625}, {"start": 1528.32, "end": 1528.54, "word": " فيهم", "probability": 0.80859375}, {"start": 1528.54, "end": 1529.18, "word": " أقدر", "probability": 0.5262858072916666}, {"start": 1529.18, "end": 1529.7, "word": " الآن", "probability": 0.7421875}, {"start": 1529.7, "end": 1530.16, "word": " بالنسبة", "probability": 0.95849609375}, {"start": 1530.16, "end": 1531.18, "word": " للتفاعلات", "probability": 0.9239095052083334}, {"start": 1531.18, "end": 1531.56, "word": " مديش", "probability": 0.638427734375}, {"start": 1531.56, "end": 1531.92, "word": " أعيد", "probability": 0.95458984375}, {"start": 1531.92, "end": 1532.5, "word": " الكلام", "probability": 0.9505208333333334}], "temperature": 1.0}, {"id": 61, "seek": 156286, "start": 1533.18, "end": 1562.86, "text": "عنده الـ Cycloaddition على الـ Double Bond وقلنا إنه بشكل عام بيكون عنده الـ cis product predominant إذا أنا بدأت بـ cis على أساس إنه التفاعل concerted يعني one step reaction مش من خلال biological mechanism يعني الكربين أو الـ Nitrene إيش حالته؟ singlet والـ Trans لو بتكون بتكون بنسب قليلة", "tokens": [3615, 41260, 3224, 2423, 39184, 10295, 66, 2907, 67, 849, 15844, 2423, 39184, 16633, 23604, 4032, 4587, 1211, 8315, 36145, 3224, 4724, 8592, 28820, 6225, 10943, 4724, 1829, 30544, 43242, 3224, 2423, 39184, 37847, 1674, 21456, 394, 11933, 15730, 41850, 47525, 10721, 2655, 4724, 39184, 37847, 15844, 5551, 3794, 32277, 36145, 3224, 16712, 5172, 995, 30241, 8543, 292, 37495, 22653, 472, 1823, 5480, 37893, 9154, 16490, 1211, 6027, 13910, 7513, 37495, 22653, 33251, 25513, 9957, 34051, 2423, 39184, 37942, 32252, 11933, 1829, 8592, 11331, 6027, 47395, 22807, 1522, 2631, 4032, 6027, 39184, 6531, 45164, 39894, 30544, 39894, 30544, 44945, 35457, 12174, 20292, 37977], "avg_logprob": -0.2910156396146004, "compression_ratio": 1.5421245421245422, "no_speech_prob": 0.0032501220703125, "words": [{"start": 1533.18, "end": 1533.84, "word": "عنده", "probability": 0.5387369791666666}, {"start": 1533.84, "end": 1534.5, "word": " الـ", "probability": 0.69140625}, {"start": 1534.5, "end": 1535.28, "word": " Cycloaddition", "probability": 0.775244140625}, {"start": 1535.28, "end": 1535.52, "word": " على", "probability": 0.775390625}, {"start": 1535.52, "end": 1535.7, "word": " الـ", "probability": 0.834716796875}, {"start": 1535.7, "end": 1535.88, "word": " Double", "probability": 0.60595703125}, {"start": 1535.88, "end": 1536.46, "word": " Bond", "probability": 0.537109375}, {"start": 1536.46, "end": 1537.54, "word": " وقلنا", "probability": 0.7430419921875}, {"start": 1537.54, "end": 1538.02, "word": " إنه", "probability": 0.6995849609375}, {"start": 1538.02, "end": 1538.58, "word": " بشكل", "probability": 0.9752604166666666}, {"start": 1538.58, "end": 1539.1, "word": " عام", "probability": 0.998046875}, {"start": 1539.1, "end": 1541.2, "word": " بيكون", "probability": 0.8390299479166666}, {"start": 1541.2, "end": 1542.34, "word": " عنده", "probability": 0.93701171875}, {"start": 1542.34, "end": 1542.92, "word": " الـ", "probability": 0.6182861328125}, {"start": 1542.92, "end": 1543.1, "word": " cis", "probability": 0.1439208984375}, {"start": 1543.1, "end": 1543.7, "word": " product", "probability": 0.91064453125}, {"start": 1543.7, "end": 1544.74, "word": " predominant", "probability": 0.828369140625}, {"start": 1544.74, "end": 1544.98, "word": " إذا", "probability": 0.9169921875}, {"start": 1544.98, "end": 1545.2, "word": " أنا", "probability": 0.83935546875}, {"start": 1545.2, "end": 1545.6, "word": " بدأت", "probability": 0.8629557291666666}, {"start": 1545.6, "end": 1545.74, "word": " بـ", "probability": 0.689208984375}, {"start": 1545.74, "end": 1546.14, "word": " cis", "probability": 0.7294921875}, {"start": 1546.14, "end": 1546.74, "word": " على", "probability": 0.890625}, {"start": 1546.74, "end": 1547.08, "word": " أساس", "probability": 0.9729817708333334}, {"start": 1547.08, "end": 1547.28, "word": " إنه", "probability": 0.809326171875}, {"start": 1547.28, "end": 1547.88, "word": " التفاعل", "probability": 0.939697265625}, {"start": 1547.88, "end": 1549.06, "word": " concerted", "probability": 0.735595703125}, {"start": 1549.06, "end": 1549.24, "word": " يعني", "probability": 0.79150390625}, {"start": 1549.24, "end": 1549.44, "word": " one", "probability": 0.85693359375}, {"start": 1549.44, "end": 1549.9, "word": " step", "probability": 0.78955078125}, {"start": 1549.9, "end": 1550.6, "word": " reaction", "probability": 0.93701171875}, {"start": 1550.6, "end": 1551.62, "word": " مش", "probability": 0.892578125}, {"start": 1551.62, "end": 1551.96, "word": " من", "probability": 0.9970703125}, {"start": 1551.96, "end": 1552.42, "word": " خلال", "probability": 0.99658203125}, {"start": 1552.42, "end": 1553.6, "word": " biological", "probability": 0.255126953125}, {"start": 1553.6, "end": 1554.54, "word": " mechanism", "probability": 0.8828125}, {"start": 1554.54, "end": 1554.82, "word": " يعني", "probability": 0.944580078125}, {"start": 1554.82, "end": 1555.32, "word": " الكربين", "probability": 0.80126953125}, {"start": 1555.32, "end": 1555.82, "word": " أو", "probability": 0.5068359375}, {"start": 1555.82, "end": 1556.02, "word": " الـ", "probability": 0.5634765625}, {"start": 1556.02, "end": 1556.38, "word": " Nitrene", "probability": 0.5008544921875}, {"start": 1556.38, "end": 1556.6, "word": " إيش", "probability": 0.85595703125}, {"start": 1556.6, "end": 1557.76, "word": " حالته؟", "probability": 0.86785888671875}, {"start": 1557.76, "end": 1558.3, "word": " singlet", "probability": 0.79931640625}, {"start": 1558.3, "end": 1559.74, "word": " والـ", "probability": 0.4330240885416667}, {"start": 1559.74, "end": 1560.26, "word": " Trans", "probability": 0.83935546875}, {"start": 1560.26, "end": 1560.64, "word": " لو", "probability": 0.96728515625}, {"start": 1560.64, "end": 1561.04, "word": " بتكون", "probability": 0.60333251953125}, {"start": 1561.04, "end": 1561.54, "word": " بتكون", "probability": 0.70654296875}, {"start": 1561.54, "end": 1562.06, "word": " بنسب", "probability": 0.915771484375}, {"start": 1562.06, "end": 1562.86, "word": " قليلة", "probability": 0.9488932291666666}], "temperature": 1.0}, {"id": 62, "seek": 158833, "start": 1564.85, "end": 1588.33, "text": "و ال insertion يعني هي مثلا هنا مثال اتطلعوا عليه مباشرة any three بالتسخين شو هتصير؟ نيتريل الان وين ال H القريبة؟ هيا ولذلك هذه هتيجي هنا و ال H؟ وين هتصير؟ عن نيتروجين نشطط", "tokens": [2407, 2423, 8969, 313, 37495, 22653, 39896, 50113, 15040, 34105, 50113, 6027, 1975, 2655, 9566, 1211, 3615, 14407, 47356, 3714, 3555, 33599, 25720, 604, 1045, 20666, 2655, 3794, 9778, 9957, 13412, 2407, 8032, 2655, 9381, 13546, 22807, 8717, 36081, 16572, 1211, 2423, 7649, 4032, 9957, 2423, 389, 25062, 16572, 49401, 22807, 8032, 25528, 35525, 8848, 23275, 29538, 8032, 31371, 7435, 1829, 34105, 4032, 2423, 389, 22807, 4032, 9957, 8032, 2655, 9381, 13546, 22807, 18871, 8717, 36081, 2288, 29245, 9957, 8717, 8592, 9566, 9566], "avg_logprob": -0.2801339381507465, "compression_ratio": 1.6141304347826086, "no_speech_prob": 0.0, "words": [{"start": 1564.85, "end": 1565.19, "word": "و", "probability": 0.92138671875}, {"start": 1565.19, "end": 1565.53, "word": " ال", "probability": 0.7060546875}, {"start": 1565.53, "end": 1566.39, "word": " insertion", "probability": 0.92138671875}, {"start": 1566.39, "end": 1566.97, "word": " يعني", "probability": 0.859375}, {"start": 1566.97, "end": 1567.15, "word": " هي", "probability": 0.0662841796875}, {"start": 1567.15, "end": 1567.53, "word": " مثلا", "probability": 0.96923828125}, {"start": 1567.53, "end": 1567.79, "word": " هنا", "probability": 0.83837890625}, {"start": 1567.79, "end": 1568.47, "word": " مثال", "probability": 0.963134765625}, {"start": 1568.47, "end": 1569.21, "word": " اتطلعوا", "probability": 0.7537027994791666}, {"start": 1569.21, "end": 1569.27, "word": " عليه", "probability": 0.93359375}, {"start": 1569.27, "end": 1569.87, "word": " مباشرة", "probability": 0.98828125}, {"start": 1569.87, "end": 1570.13, "word": " any", "probability": 0.1612548828125}, {"start": 1570.13, "end": 1570.59, "word": " three", "probability": 0.677734375}, {"start": 1570.59, "end": 1571.83, "word": " بالتسخين", "probability": 0.8931640625}, {"start": 1571.83, "end": 1572.01, "word": " شو", "probability": 0.901611328125}, {"start": 1572.01, "end": 1573.53, "word": " هتصير؟", "probability": 0.8509765625}, {"start": 1573.53, "end": 1574.59, "word": " نيتريل", "probability": 0.7298583984375}, {"start": 1574.59, "end": 1575.41, "word": " الان", "probability": 0.56500244140625}, {"start": 1575.41, "end": 1575.83, "word": " وين", "probability": 0.913818359375}, {"start": 1575.83, "end": 1575.97, "word": " ال", "probability": 0.95849609375}, {"start": 1575.97, "end": 1576.17, "word": " H", "probability": 0.158203125}, {"start": 1576.17, "end": 1577.93, "word": " القريبة؟", "probability": 0.9417724609375}, {"start": 1577.93, "end": 1578.19, "word": " هيا", "probability": 0.3494873046875}, {"start": 1578.19, "end": 1580.29, "word": " ولذلك", "probability": 0.791015625}, {"start": 1580.29, "end": 1580.65, "word": " هذه", "probability": 0.54296875}, {"start": 1580.65, "end": 1581.15, "word": " هتيجي", "probability": 0.965087890625}, {"start": 1581.15, "end": 1581.37, "word": " هنا", "probability": 0.958984375}, {"start": 1581.37, "end": 1581.51, "word": " و", "probability": 0.76220703125}, {"start": 1581.51, "end": 1581.63, "word": " ال", "probability": 0.869140625}, {"start": 1581.63, "end": 1583.99, "word": " H؟", "probability": 0.7098388671875}, {"start": 1583.99, "end": 1584.61, "word": " وين", "probability": 0.960693359375}, {"start": 1584.61, "end": 1586.45, "word": " هتصير؟", "probability": 0.9869140625}, {"start": 1586.45, "end": 1586.77, "word": " عن", "probability": 0.76123046875}, {"start": 1586.77, "end": 1587.53, "word": " نيتروجين", "probability": 0.8486328125}, {"start": 1587.53, "end": 1588.33, "word": " نشطط", "probability": 0.74090576171875}], "temperature": 1.0}, {"id": 63, "seek": 161855, "start": 1594.01, "end": 1618.55, "text": "لاحظوا الـ Nitrene دخل بين الـ Carbon و الـ H ولا لأ؟ هاي ال Nitrene هذه كانت Carbon-H صارت Carbon-Nitrene-H واضحت فكرة ال insertion كذلك الحال هنا في هذا المثال الحقيقة اللي هنا تم برضه insertion على الـ H اللي هنا اللي جاب ال double bond مش reaction على ال double bond", "tokens": [15040, 5016, 19913, 14407, 2423, 39184, 37942, 32252, 11778, 9778, 1211, 49374, 2423, 39184, 31453, 4032, 2423, 39184, 389, 49429, 5296, 10721, 22807, 8032, 47302, 2423, 37942, 32252, 29538, 25961, 2655, 31453, 12, 39, 20328, 9640, 2655, 31453, 12, 45, 270, 32252, 12, 39, 4032, 46958, 5016, 2655, 6156, 4117, 25720, 2423, 8969, 313, 9122, 8848, 23275, 21542, 6027, 34105, 8978, 23758, 9673, 12984, 6027, 21542, 38436, 28671, 13672, 1829, 34105, 46811, 4724, 43042, 3224, 8969, 313, 15844, 2423, 39184, 389, 13672, 1829, 34105, 13672, 1829, 10874, 16758, 2423, 3834, 6086, 37893, 5480, 15844, 2423, 3834, 6086], "avg_logprob": -0.24011479363757737, "compression_ratio": 1.8211009174311927, "no_speech_prob": 0.0, "words": [{"start": 1594.01, "end": 1594.63, "word": "لاحظوا", "probability": 0.9158935546875}, {"start": 1594.63, "end": 1595.11, "word": " الـ", "probability": 0.5716552734375}, {"start": 1595.11, "end": 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{"start": 1614.57, "end": 1615.17, "word": " insertion", "probability": 0.991455078125}, {"start": 1615.17, "end": 1615.33, "word": " على", "probability": 0.75390625}, {"start": 1615.33, "end": 1615.45, "word": " الـ", "probability": 0.916015625}, {"start": 1615.45, "end": 1615.61, "word": " H", "probability": 0.5}, {"start": 1615.61, "end": 1615.85, "word": " اللي", "probability": 0.962158203125}, {"start": 1615.85, "end": 1616.11, "word": " هنا", "probability": 0.72607421875}, {"start": 1616.11, "end": 1616.31, "word": " اللي", "probability": 0.94580078125}, {"start": 1616.31, "end": 1616.49, "word": " جاب", "probability": 0.7449951171875}, {"start": 1616.49, "end": 1616.61, "word": " ال", "probability": 0.255859375}, {"start": 1616.61, "end": 1616.79, "word": " double", "probability": 0.477783203125}, {"start": 1616.79, "end": 1617.01, "word": " bond", "probability": 0.94140625}, {"start": 1617.01, "end": 1617.19, "word": " مش", "probability": 0.81396484375}, {"start": 1617.19, 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{"start": 1638.78, "end": 1639.38, "word": " التفاعل", "probability": 0.9483642578125}, {"start": 1639.38, "end": 1640.1, "word": " insertion", "probability": 0.95458984375}, {"start": 1640.1, "end": 1640.36, "word": " ولا", "probability": 0.91650390625}, {"start": 1640.36, "end": 1641.68, "word": " addition؟", "probability": 0.96484375}], "temperature": 1.0}, {"id": 65, "seek": 165910, "start": 1642.1, "end": 1659.1, "text": "insertion لأنه صعب ان اعمل addition هنا هيك و هيك حلقة ثلاثية بحلقة ربعية بحلقة سادسية كجيومتري عملية صعبة ولذلك هنا لما اتكون ال nitrene التفاعل اللي استكمل هو تفاعل insertion", "tokens": [1292, 911, 313, 5296, 33456, 3224, 20328, 3615, 3555, 16472, 1975, 25957, 1211, 4500, 34105, 39896, 4117, 4032, 39896, 4117, 11331, 1211, 28671, 38637, 1211, 5718, 104, 10632, 4724, 5016, 1211, 28671, 12602, 3555, 3615, 10632, 4724, 5016, 1211, 28671, 8608, 18513, 3794, 10632, 9122, 7435, 1829, 20498, 2655, 16572, 6225, 42213, 10632, 20328, 3615, 49401, 35525, 8848, 23275, 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@@ -0,0 +1,1572 @@ +1 +00:00:20,770 --> 00:00:25,450 +بسم الله الرحمن الرحيم المرة الماضية في موضوع + +2 +00:00:25,450 --> 00:00:31,170 +تحضير المراكبات الحلقية اتكلمنا على نوع من ال + +3 +00:00:31,170 --> 00:00:34,070 +reactive intermediates اللي هم ال carbines و ال + +4 +00:00:34,070 --> 00:00:38,690 +nitrines عرفنا إيش معنى carbine و إيش معنى nitrine + +5 +00:00:38,690 --> 00:00:42,940 +كيف نعمل generation لل carbineهذه الكربين كان + +6 +00:00:42,940 --> 00:00:47,020 +عبارة عن كربون بمجموعتين زائد زوج من الإلكترونات + +7 +00:00:47,020 --> 00:00:51,880 +النيترين نيتروجين برابطة واحدة وزوجين من + +8 +00:00:51,880 --> 00:00:57,100 +الإلكترونات طبعا ال generation للكربين أخدناها من + +9 +00:00:57,100 --> 00:01:00,340 +خلال ال diazo compounds أو من خلال ال ketenes + +10 +00:01:00,340 --> 00:01:04,760 +بيفقدوا small molecules و بعدين أخدنا أهم تفاعلات + +11 +00:01:04,760 --> 00:01:10,920 +الكربين قلنا للكربين تفاعلين أساسيا تفاعلالـ + +12 +00:01:10,920 --> 00:01:13,940 +Cycloaddition تحديدًا الـ Cycloaddition ليش؟ لأنه + +13 +00:01:13,940 --> 00:01:18,120 +الـ Cycloaddition formation of two new sigma bonds + +14 +00:01:18,120 --> 00:01:22,140 +at the same time بشكل عام وعمل cycle Cycloaddition + +15 +00:01:22,140 --> 00:01:25,860 +يعني هذا التفاعل اللي هو الـ Nitrene مع ال double + +16 +00:01:25,860 --> 00:01:29,420 +bond أو الكربين مع ال double bond هيعود مر معنا + +17 +00:01:29,420 --> 00:01:35,040 +لما بناخد أنواع ال Cycloaddition reactions هيعود + +18 +00:01:35,040 --> 00:01:38,600 +مر معنا لما بناخد أنواع ال Cycloaddition reactions + +19 +00:01:39,070 --> 00:01:44,170 +الان ال double bond مش دائما متوفر يعني double + +20 +00:01:44,170 --> 00:01:48,650 +bond انا لما بحط double bond بدي اجيب مركب تحديدا + +21 +00:01:48,650 --> 00:01:52,870 +و قصدا فيه double bond و افعله مع الكربين زي هذا + +22 +00:01:52,870 --> 00:01:56,970 +المثال او زي المثال اللي مثلا هنا جيبت مركب فيه + +23 +00:01:56,970 --> 00:02:00,930 +double bond مركب ديازو كمباوند هذا في وجود حرارة + +24 +00:02:00,930 --> 00:02:07,230 +او catalyst فقد ال nitrogen صار كربين الكربينلقى + +25 +00:02:07,230 --> 00:02:12,790 +double bond عمل عليها Cycloaddition + +26 +00:02:12,790 --> 00:02:19,310 +الآن السؤال لو الكربين ماحطتلوش double bond ايش + +27 +00:02:19,310 --> 00:02:24,410 +بده يعمل يعني كوّننا الكربين اتكون الكربين لكن + +28 +00:02:24,410 --> 00:02:28,870 +مالقاش double bond يتفاعل معاها هو الكربين بطبيعة + +29 +00:02:28,870 --> 00:02:33,550 +الحال reactive intermediate يعني لازم يتفاعل + +30 +00:02:34,570 --> 00:02:41,010 +مالاجهاش double bond ايش بدهوا يعمل في النهايةبصير + +31 +00:02:41,010 --> 00:02:45,310 +يعمل تفاعل تاني و ربما هو الأشهر والأكتر انتشارا + +32 +00:02:45,310 --> 00:02:48,390 +لل carbons و ال nitrenes بنسميه احنا تفاعل ال + +33 +00:02:48,390 --> 00:02:53,270 +insertion بيدخل بين ال carbon و ال H بيعمل + +34 +00:02:53,270 --> 00:02:57,350 +insertion معنى ال insertion و غالبا هذا ال + +35 +00:02:57,350 --> 00:03:01,270 +insertion ممكن تفهموه انه بتمن خلال حلقة ثلاثية + +36 +00:03:01,270 --> 00:03:07,890 +بيدخل الكربين ما بين الكربون و ال hydrogen يعني هى + +37 +00:03:07,890 --> 00:03:14,920 +مثلا هنافي عنده الميثيلين اللي هو أبسط ايش؟ أبسط + +38 +00:03:14,920 --> 00:03:19,220 +كاربين الان لو انا كنت بدى أشوف كيف بده يعمل هذا + +39 +00:03:19,220 --> 00:03:25,000 +التفاعل خلينا نركز نظرنا على هذه الكاربون على هذه + +40 +00:03:25,000 --> 00:03:30,860 +الكاربون و هذه ال H واضح؟ الان الكاربين بده يعمل + +41 +00:03:30,860 --> 00:03:35,540 +insertion يدخل بينهم يعني يدخل بين ال C و ال H كأن + +42 +00:03:35,540 --> 00:03:40,380 +بين ال C و ال H ايش بده أحط؟CH2 هذا الكلام كيف + +43 +00:03:40,380 --> 00:03:46,080 +عادة ممكن يتم عادة هذا الكلام ممكن يتم من خلال نوع + +44 +00:03:46,080 --> 00:03:50,920 +من الحلقة الثلاثية يعني تخيلوا ان هذا الكربين هيجي + +45 +00:03:50,920 --> 00:03:54,960 +يعمل حلقة ثلاثية بين هذا الكربون وهذا الهيدروجين + +46 +00:03:54,960 --> 00:04:01,200 +الآن عمل الكربين الحلقة الثلاثية بعد هيك بيكتمل + +47 +00:04:01,200 --> 00:04:07,490 +كسر طبعا هذه كمان ايش مالها صارت منقطةواضح؟ بعد + +48 +00:04:07,490 --> 00:04:12,070 +هيك بيكتمل كسر الرابط بين ال carbon و ال H الان + +49 +00:04:12,070 --> 00:04:15,230 +تخيلوا ان هذه الرابطة انكسرت ايش هيصير متصل بال + +50 +00:04:15,230 --> 00:04:24,050 +carbon؟ carbon CH2H CH3 هين موجود كأنه الان + +51 +00:04:24,050 --> 00:04:32,250 +بتقدروا تنظروا لهذه CH3 حقيقة انها CH2H + +52 +00:04:32,250 --> 00:04:38,160 +ايش اللي عمل ال insertion؟بين ال carbon و ال H ال + +53 +00:04:38,160 --> 00:04:45,660 +CH2 هي عملية ال insertion واضحة العملية الآن في + +54 +00:04:45,660 --> 00:04:50,340 +هذا النوع من التفاعلات في هذا النوع من التفاعلات + +55 +00:04:50,340 --> 00:04:55,510 +هتلاحظواكما هو الحال بشكل عام في الـ heterocyclic + +56 +00:04:55,510 --> 00:04:59,930 +chemistry أنه لازم تفكيركم يكون واسع يعني طالما + +57 +00:04:59,930 --> 00:05:04,310 +أنا بأحكي عن insertion بين carbon و hydrogen بناء + +58 +00:05:04,310 --> 00:05:09,190 +على ذلك، قداش الاحتمالات الممكنة؟ يعني مثلا بهذا + +59 +00:05:09,190 --> 00:05:14,030 +الجزء اللي هو البروبين، كم احتمال ممكن عنده؟ كم + +60 +00:05:14,030 --> 00:05:19,630 +نوع هيدروجين؟ اتخيلوا أن هذا الجزء في ال NMR حطته، + +61 +00:05:19,630 --> 00:05:21,130 +كم بيك هتشوفه؟ + +62 +00:05:24,340 --> 00:05:29,600 +كل الهيدروجينات اللي هنا تمانية هذه ال CH3 و هذه + +63 +00:05:29,600 --> 00:05:36,140 +ال CH3 زي بعض و هدول ال CH2 زي بعض بمعنى لو أنا + +64 +00:05:36,140 --> 00:05:42,340 +كان سؤالي draw all the possible insertion products + +65 +00:05:42,340 --> 00:05:46,460 +for this reaction draw all the possible insertion + +66 +00:05:46,460 --> 00:05:50,360 +products for this reaction هذا أحد ال insertion + +67 +00:05:50,360 --> 00:05:56,150 +products اللي إجت فيهال CH2 هنا ال insertion + +68 +00:05:56,150 --> 00:06:01,690 +product التاني وين بده يكون CH3 عادي وبناء على ذلك + +69 +00:06:01,690 --> 00:06:09,770 +لو انا بده اتخيله هيكون حقيقة CH3 CH2 خليني اقول + +70 +00:06:09,770 --> 00:06:15,290 +CH2 وهي ال H هذا اللي كان موجود اصلا و ايش هييجي + +71 +00:06:15,290 --> 00:06:22,020 +عندى بال insertion ال CH2 اذا هنا لما احطCH2 + +72 +00:06:22,020 --> 00:06:29,040 +واتصلت بالـ H CH2 عملت insertion هنا صار الجزء CH3 + +73 +00:06:29,040 --> 00:06:34,020 +CH2 CH2 CH3 هذا ال insertion اللي هنا على + +74 +00:06:34,020 --> 00:06:37,820 +secondary carbon هذا ال insertion اللي هنا على + +75 +00:06:37,820 --> 00:06:43,140 +primary carbon الآن التجربة بتقول انه بشكل عام + +76 +00:06:43,140 --> 00:06:51,570 +بشكل عام ال insertionبفضل ال tertiary على ال + +77 +00:06:51,570 --> 00:06:55,150 +secondary على ال primary بس مش هذا العامل الوحيد + +78 +00:06:55,150 --> 00:07:00,710 +المؤثر بديش أنسى كمان أن حجم الحلقة الناتج أحياناً + +79 +00:07:00,710 --> 00:07:04,350 +بيكون عامل مؤثر بالذات في ال ultra molecular + +80 +00:07:04,350 --> 00:07:08,810 +reactionيعني هنا مافيش عندى intramolecular + +81 +00:07:08,810 --> 00:07:13,750 +reaction فى عندى احتمالين الآن حسب التجربة اللى + +82 +00:07:13,750 --> 00:07:16,710 +طلعت ان هذا ال insertion ع secondary هذا ال + +83 +00:07:16,710 --> 00:07:20,750 +insertion ع primary ان هو اللى بيكون مفضل ال + +84 +00:07:20,750 --> 00:07:25,990 +insertion اللى على ال secondary الان لو أخدت أنا + +85 +00:07:26,750 --> 00:07:31,550 +مثال تاني Intramolecular reaction هاي هذا المركب + +86 +00:07:31,550 --> 00:07:37,090 +مع التسخين و النحاس و بنزين طارت هذه ال nitrogen و + +87 +00:07:37,090 --> 00:07:43,690 +صار عندى هنا ايش كربين الان اطلعولي الكربين هذه + +88 +00:07:43,690 --> 00:07:50,790 +ايش عندها احتمالات لل insertion هنا نعملها بلون + +89 +00:07:50,790 --> 00:07:56,230 +تاني هنا في عندى CHممكن تعمل insertion عليها ولا + +90 +00:07:56,230 --> 00:08:08,810 +لأ؟ وهنا في عندي CH وهنا في عندي CH وكل هادولة CH2 + +91 +00:08:08,810 --> 00:08:14,510 +CH2 CH2 they are secondary كلهم + +92 +00:08:14,510 --> 00:08:18,960 +secondaryلكن هذا ال insertion لما تيجي ال carbon + +93 +00:08:18,960 --> 00:08:24,220 +هنا تعمل رابطتها هيعطيني حلقة ثلاثية هذا ال + +94 +00:08:24,220 --> 00:08:27,600 +insertion هيعطيني حلقة ربعية هذا ال insertion + +95 +00:08:27,600 --> 00:08:32,560 +هيعطيني حلقة خمسية الان اذا صار عندى تلاتة + +96 +00:08:32,560 --> 00:08:36,620 +secondary في هذه الحالة اللى اتحكم في الناتج اكتر + +97 +00:08:36,620 --> 00:08:41,000 +اللى هو حجم الحلقة افضل الحلقات في التكون خمسية و + +98 +00:08:41,000 --> 00:08:46,590 +سادسية لحظة حتى احنا هنا ماتكلمناش اش في عندناع ال + +99 +00:08:46,590 --> 00:08:51,530 +R هذه و ال R هذه خلّيناهم محايدين لكن إلكم برضه + +100 +00:08:51,530 --> 00:08:55,050 +تتخيلوا .. إلكم برضه تتخيلوا إنه افترضوا اللي + +101 +00:08:55,050 --> 00:09:00,290 +كاتبها هنا R' هو حيدها يمكن عملها مجموعة نيترو ولا + +102 +00:09:00,290 --> 00:09:06,790 +كذا لكن لو افترضنا إن هذا ال R' كانت سلسلة كربونات + +103 +00:09:07,810 --> 00:09:11,310 +كان ايش بدو يكون التفكير انه كمان هنا في احتمال + +104 +00:09:11,310 --> 00:09:15,110 +insertion هنا في احتمال هنا في احتمال فموضوع + +105 +00:09:15,110 --> 00:09:20,210 +الاحتمالات لل insertions الحقيقة هو موضوع اشماله + +106 +00:09:20,210 --> 00:09:26,570 +واسع بشكل عام احنا في عندنا قاعدتين لكي نتخيل افضل + +107 +00:09:26,570 --> 00:09:31,000 +احتمال ممكن بس الحكم النهائي هو ايشالتجربة + +108 +00:09:31,000 --> 00:09:34,760 +القاعدتين ان ال tertiary افضل من ال secondary افضل + +109 +00:09:34,760 --> 00:09:37,580 +من ال primary في ال insertion و ان الحلقات الخمسية + +110 +00:09:37,580 --> 00:09:41,600 +و السادسية افضل من الربعية و الثلاثية واضح الفكرة + +111 +00:09:41,600 --> 00:09:49,260 +هذا طبعا بالذات موضوع الحلقات وانتش بيصير أساسا + +112 +00:09:49,260 --> 00:09:52,580 +حلقة في ال intramolecular reaction في ال + +113 +00:09:52,580 --> 00:09:55,680 +intramolecular هذا اللي بين جزيئين مافيش عندي + +114 +00:09:55,680 --> 00:09:59,670 +احتمال للحلقةهنا بس عندى احتمالي primary و + +115 +00:09:59,670 --> 00:10:03,330 +secondary، فى غيره؟ مافيش، لكن فى الـ + +116 +00:10:03,330 --> 00:10:06,390 +Intramolecular دائما الـ Intramolecular reaction + +117 +00:10:06,390 --> 00:10:11,530 +إيش قولنا عنه بيعمل؟ Cycle دائما أي reaction + +118 +00:10:11,530 --> 00:10:16,590 +Intramolecular هيعمل ليه Cycle؟ هيعمل حلقة، واضح؟ + +119 +00:10:16,590 --> 00:10:21,430 +ففى ال Intramolecular reaction صار عندى؟نوع + +120 +00:10:21,430 --> 00:10:25,710 +الكربون وحجم الحلقة في الـ Intermolecular reaction + +121 +00:10:25,710 --> 00:10:32,930 +اللي يتحكم في الموضوع نوع الكربون، واضح؟ مثلا، هذا + +122 +00:10:32,930 --> 00:10:37,070 +المثال واضح إن عندك ديازو كومباوند بتطير الـ + +123 +00:10:37,070 --> 00:10:44,050 +nitrogen ويتكون عندك كربين، تمام؟ الآن الـ + +124 +00:10:44,050 --> 00:10:48,430 +Cyclohexane in principle كل ذرات الهيدروجين تبعته + +125 +00:10:49,300 --> 00:10:54,640 +أقل تقدير على حرارة الغرفة واضح؟ ليش قلنا جملة على + +126 +00:10:54,640 --> 00:10:59,640 +حرارة الغرفة؟ + +127 +00:10:59,640 --> 00:11:04,040 +حد + +128 +00:11:04,040 --> 00:11:10,920 +بيقدر يتذكر؟ لأن الـ Cyclohexane الناس اللي + +129 +00:11:10,920 --> 00:11:15,120 +بيذكروا ال conformations تبعت الـ Cyclohexane لما + +130 +00:11:15,120 --> 00:11:19,130 +ياخد ال chair و ال boat conformationو ال boat + +131 +00:11:19,130 --> 00:11:26,410 +confirmation بشكل عام is more stable than .. is + +132 +00:11:26,410 --> 00:11:28,750 +less stable than the chair confirmation ال chair + +133 +00:11:28,750 --> 00:11:32,590 +confirmation هو ال more stable confirmation هذا ال + +134 +00:11:32,590 --> 00:11:37,630 +hydrogenات فيه بيصيروا نوعين بيصيروا ستة axial هاي + +135 +00:11:37,630 --> 00:11:43,030 +يوم بتدرسون بالأحمر واحد اتنين تلاتة اربعة خمسة + +136 +00:11:43,030 --> 00:11:49,630 +ستة ستة axial و ستةequatorial تمام طبعا + +137 +00:11:52,140 --> 00:11:55,980 +أنا في عندى ال flipping سريع على حرارة الغرفة + +138 +00:11:55,980 --> 00:11:59,100 +عشانك ال Axial بيصير Equatorial و ال Equatorial + +139 +00:11:59,100 --> 00:12:02,960 +Axial فبنقول أنه على حرارة الغرفة ال 12 زي بعض + +140 +00:12:02,960 --> 00:12:09,420 +لإنه عندى ال flipping سريع لكن لو بردنا على درجة + +141 +00:12:09,420 --> 00:12:14,480 +حرارة منخفضة جدا هيثبت بهذا الشكل و هنصير نشوف + +142 +00:12:14,480 --> 00:12:18,960 +الهيدروجين نوعين مش نوع واحدواضحة الفكرة + +143 +00:12:18,960 --> 00:12:23,660 +فالهيدروجين تبع ال Cyclohexane على حرارة الغرفة + +144 +00:12:23,660 --> 00:12:28,020 +نوع واحد رغم انه احنا هيناه رسمينه أحمر و أخضر + +145 +00:12:28,020 --> 00:12:32,660 +Axial و equatorial لكن في عنده very fast + +146 +00:12:32,660 --> 00:12:37,940 +convergence بين ال chair conformation اللي هيك و + +147 +00:12:37,940 --> 00:12:42,000 +ال chair conformation المعاكس له يعني هذا لما + +148 +00:12:42,000 --> 00:12:46,720 +بيصير ال chair conformation التاني المعاكس لهاللي + +149 +00:12:46,720 --> 00:12:50,060 +هو هذا الـ Chair Conformation لاحظوا هي هذا بتطلع + +150 +00:12:50,060 --> 00:12:52,200 +البن آدم اللي قاعد عليه هيك و هذا الـ Chair + +151 +00:12:52,200 --> 00:12:57,920 +المعاكس له اللي بيكونوا فيه .. اللي بيكونوا فيه + +152 +00:12:57,920 --> 00:13:04,300 +Axial بيصيروا equatorial اللي بيكونوا Axial + +153 +00:13:04,300 --> 00:13:07,640 +بيصيروا equatorial يعني هاي الحمر كانوا Axial + +154 +00:13:07,640 --> 00:13:11,900 +صاروا equatorial و اللي كانوا equatorial بيصيروا + +155 +00:13:11,900 --> 00:13:13,700 +إيش Axial + +156 +00:13:19,590 --> 00:13:22,990 +فبعملية ال flipping في جزء الـcyclohexane هاي + +157 +00:13:22,990 --> 00:13:26,350 +الخضر كانوا equatorial صاروا axial الحمر كانوا + +158 +00:13:26,350 --> 00:13:29,190 +axial صاروا equatorial و هكذا الان لما هذا ال + +159 +00:13:29,190 --> 00:13:33,230 +flipping يكون سريع بيصيروا الهيدروجينات نوع واحد + +160 +00:13:33,230 --> 00:13:39,490 +لكن لو بطقناه بالتبريد واضح؟ بيصيروا الهيدروجينات + +161 +00:13:39,490 --> 00:13:45,450 +كام نوع؟نوعين الآن خلوه homework معكوا ابحثولي عن + +162 +00:13:45,450 --> 00:13:50,230 +الـcyclohexane وشوفوا على أي درجة حرارة أقل تقدير + +163 +00:13:50,230 --> 00:13:55,290 +حتى في ال NMR بإمكاننا نشوف الهيدروجين فيه نوعين + +164 +00:13:55,290 --> 00:14:02,110 +واضح عن أنواع الهيدروجين وواجتشق أنا بقدر فعلا أن + +165 +00:14:02,110 --> 00:14:06,550 +أشوف الهيدروجينات في الـcyclohexane نوعين مش نوع + +166 +00:14:06,550 --> 00:14:12,400 +واحدالبنزين لأ البنزين ست هيدروجينات هدوله إيش؟ + +167 +00:14:12,400 --> 00:14:16,360 +مافيش عليهم خلاف they are fully equivalent لكن + +168 +00:14:16,360 --> 00:14:21,060 +اللي في الـcyclohexane بمثال عادي زي هذا اعتبرناهم + +169 +00:14:21,060 --> 00:14:26,060 +نوع واحد وبالتالي وين ما اعملنا ال insertion طبعا + +170 +00:14:26,060 --> 00:14:29,820 +اللي بدها تشوف ال insertion وين ال insertion تتخيل + +171 +00:14:29,820 --> 00:14:33,600 +انه كنا احنا شغالين على هذا الكربون وهي كام + +172 +00:14:33,600 --> 00:14:38,560 +هيدروجين على هذا الكربونهيدروجينتين الان لما صار + +173 +00:14:38,560 --> 00:14:44,780 +عليها التفاعل دلت هيدروجينة وين التانية؟ هايها + +174 +00:14:44,780 --> 00:14:48,720 +ولذلك + +175 +00:14:48,720 --> 00:14:54,320 +لما اقول وين اللي تم ال insertion هايه لاحظوا هذا + +176 +00:14:54,320 --> 00:15:01,700 +الجزء دخل بين ال carbon هذي و ال H تبعيههذا الجزء + +177 +00:15:01,700 --> 00:15:05,820 +من خلال الكاربين دخل بين الكاربون هذا والـ H + +178 +00:15:05,820 --> 00:15:15,920 +تاعتها هاي ال insertion واضحة الفكرة؟ + +179 +00:15:15,920 --> 00:15:21,960 +الآن + +180 +00:15:21,960 --> 00:15:27,470 +بنجي على ال Nitrenes ال Nitrenes نفس التفاعلاتالـ + +181 +00:15:27,470 --> 00:15:31,550 +Carbines Addition عضّب البندق insertion بصير الأمر + +182 +00:15:31,550 --> 00:15:36,750 +سهل لكن لو يجينا يقولنا Formation of Nitrenes برضه + +183 +00:15:36,750 --> 00:15:42,270 +هتلاحظوا ان الإنسان اللي بحب العلم بالموازاة اللي + +184 +00:15:42,270 --> 00:15:46,710 +بحب العلم بالموازاة هيلاحظ ان Formation of + +185 +00:15:46,710 --> 00:15:51,910 +Nitrenes و Carbines نفس الفكرة تماما يعني انا لما + +186 +00:15:51,910 --> 00:15:58,900 +كنت اعمل Formation ofخليني اقول الكربين ايش كنت + +187 +00:15:58,900 --> 00:16:07,140 +اخد؟ دايازو كومباونز يعني هذا المركب كان يكون RCNN + +188 +00:16:07,140 --> 00:16:13,580 +هذه كانت كربون و ايش الجزء اللي بده اشيله؟ + +189 +00:16:13,580 --> 00:16:18,980 +النيتروجين شيلت النيتروجين صار عنده كربين الآن + +190 +00:16:18,980 --> 00:16:24,340 +حولت النيتروجين .. الكربون هذه لنيتروجينبعد المكان + +191 +00:16:24,340 --> 00:16:32,940 +ديازو كمباوند صار ايش N3 ازايد يعني صار R N N + +192 +00:16:32,940 --> 00:16:39,080 +double bond N وشيلوا هذه الان اذا شيلت ال نيتروجين + +193 +00:16:39,080 --> 00:16:43,500 +من ال ديازو كمباوند كربين و اذا شيلت ال نيتروجين + +194 +00:16:43,500 --> 00:16:49,830 +من ال ازايدنيترين إذا هدولا تفاعلات فعلا موزين + +195 +00:16:49,830 --> 00:16:55,310 +لبعض و من البعض ولا لأ؟ 100% كذلك الحال لو أنا + +196 +00:16:55,310 --> 00:17:00,130 +ارجعت فيكم مثلا لنفس ال slide اللي حكينا فيه على + +197 +00:17:00,130 --> 00:17:07,190 +ال generation of الكربين قلنا بدلوا الكربون + +198 +00:17:07,190 --> 00:17:12,810 +بنيتروجين إيش صار هذا المركب؟ أزايد أنيترين شو + +199 +00:17:12,810 --> 00:17:19,540 +هيعطيني؟Nitrate وهنا الكيتيل بدلوا الكربون + +200 +00:17:19,540 --> 00:17:24,860 +بنيتروجيل N double bond C double bond O شو بيصير + +201 +00:17:24,860 --> 00:17:31,840 +اسمه RNCO ايزو + +202 +00:17:31,840 --> 00:17:37,860 +سيانات ايزو سيانات ومر علينا الفنل ايزو سياناتفى + +203 +00:17:37,860 --> 00:17:49,560 +slides تانية ايزو سيا نت ال R N C O ايزو سيا نت ال + +204 +00:17:49,560 --> 00:17:53,000 +ايزو سيا نت لاحظوا ايش التغيير الوحيد بين هدول + +205 +00:17:53,000 --> 00:17:58,740 +الشغلتين تغيير الكربون بنيتروجيل فالكربين من + +206 +00:17:58,740 --> 00:18:04,360 +الديازو كمباونز والكيتينز ال نيترينز بشكل أساسي من + +207 +00:18:04,360 --> 00:18:12,060 +الازايدز والايزو سيا نتوالفقد في الحالتين اما جزء + +208 +00:18:12,060 --> 00:18:19,220 +نيتروجين او جزء carbon monoxide شوفتوا كيف + +209 +00:18:19,220 --> 00:18:24,020 +بالموازاة ممكن نفهم الموضوع الان في طرق تانية كتير + +210 +00:18:24,020 --> 00:18:29,760 +اضافية ولكنها اقل ايش شهرة كلها ايضا فكرة تقوم على + +211 +00:18:29,760 --> 00:18:36,750 +فقد جزيات صغيرة لكن بشكل عام الاساس فقدنيتروجين من + +212 +00:18:36,750 --> 00:18:42,370 +ايش؟ من الازايد فقد نيتروجين من الازايد بيعطيني + +213 +00:18:42,370 --> 00:18:46,250 +نيترين او فقد CO من ال isocyanate خلّيني على + +214 +00:18:46,250 --> 00:18:52,590 +هالطريقتين هذول كطرق أساسية + +215 +00:18:52,590 --> 00:18:57,430 +هيقول لها هنا ال RNCO ايش اللي بتفقدوه؟ carbon + +216 +00:18:57,430 --> 00:19:03,830 +monoxide هتعطيني نيترينلما تفقد ال carbon monoxide + +217 +00:19:03,830 --> 00:19:10,670 +هتعطيني نيترينزي ما حكينا أنه أهم طريقتين + +218 +00:19:10,670 --> 00:19:16,070 +المشهورات لـ generation of nitrenes اللي هي from + +219 +00:19:16,070 --> 00:19:21,350 +azides and isocyanates الآن طرق تانية موجودة لكن + +220 +00:19:21,350 --> 00:19:24,670 +أقل أهمية، بذكرها ذكر سريع بس مانديش أتوقف عندها + +221 +00:19:24,670 --> 00:19:30,150 +مثلا الـ N-Aminoheterocycles أن هذا الـ NH2 + +222 +00:19:30,150 --> 00:19:35,830 +باستعمال الـ lead tetraacetate الـ LTALead + +223 +00:19:35,830 --> 00:19:41,450 +tetraacetate بتعمل هنا نيترين يعني هذه lead + +224 +00:19:41,450 --> 00:19:45,790 +tetraacetate + +225 +00:19:45,790 --> 00:19:51,850 +بتعمل هنا نيترين فعلا هى صار نيترين لو حطينا له + +226 +00:19:51,850 --> 00:19:54,990 +double bond بيعمل cycle addition عليها يعني في + +227 +00:19:54,990 --> 00:19:58,690 +المعادلة اللى عندكم كونا نيترين على هذه ال + +228 +00:19:58,690 --> 00:20:04,070 +nitrogen وحطينا معاها double bond مباشرة فعملت ايش + +229 +00:20:04,600 --> 00:20:09,320 +الـ Cycloaddition Reaction هذا تفاعل خاص أن يكون + +230 +00:20:09,320 --> 00:20:16,040 +موجود عندكم أن أمينوهيتيرو سايكل كذلك من الـ cell + +231 +00:20:16,040 --> 00:20:21,160 +filaments اللي هي الأن ببند أس هذه بالفوتوليسيز + +232 +00:20:21,160 --> 00:20:27,120 +بتفقد كل هذا الجزء وبتعمل نيترين واضح؟ الآن لاحظوا + +233 +00:20:27,120 --> 00:20:33,210 +أنا المهم عندي في هذا الموضوع أن هي عملتفقدت هذا و + +234 +00:20:33,210 --> 00:20:39,990 +كونت نيترين الان ايش النيترين ماحطيلوش double bond + +235 +00:20:39,990 --> 00:20:45,690 +يتفاعل معها ايش بده يعمل بده يحاول قدر الامكان + +236 +00:20:45,690 --> 00:20:49,890 +يعمل insertion الان طبعا ممكن اي واحد تفكر انه + +237 +00:20:49,890 --> 00:20:56,490 +بامكانه يعمل insertion على هيدروجين في جزء تاني او + +238 +00:20:56,490 --> 00:21:00,690 +في نفس الجزءيعني هو الآن هتلاحظ هو هيعمل insertion + +239 +00:21:00,690 --> 00:21:04,650 +على هذا المثل طب يا تورا بيعمل على اللي في الجزء + +240 +00:21:04,650 --> 00:21:10,370 +التاني دائما إذا كان التنافس بال intra molecular + +241 +00:21:10,370 --> 00:21:15,830 +reaction و intermolecular يعني هذه لما نيجي نرسمها + +242 +00:21:15,830 --> 00:21:20,370 +بشكل سليم ال nitrogen مش بعيدة عن المثل يعني طالما + +243 +00:21:20,370 --> 00:21:25,510 +هنا عندكم الكربونيل موجودة يعني التلات روابط كده + +244 +00:21:25,510 --> 00:21:30,970 +تكون الزاوية120 120 120 يعني هذي بتخيلوها كأنها + +245 +00:21:30,970 --> 00:21:34,690 +زيك C double bond O وهي ال Nitrene الان ال Nitrene + +246 +00:21:34,690 --> 00:21:38,310 +بموقع مناسب تماما تعمل insertion مع ال H اللي ها + +247 +00:21:38,310 --> 00:21:43,250 +طبعا لما تعمل insertion حاسين عندي أنا ان H هاي + +248 +00:21:43,250 --> 00:21:50,210 +دخلت ال Nitrene هذه هاي H تنتين و اين التالتة اللي + +249 +00:21:50,210 --> 00:21:55,390 +هاد ال H هدولة تعون المثل فالان دخلت بين ال carbon + +250 +00:21:56,600 --> 00:22:01,780 +والهيدروجين عبلت عملية إيش insertion الآن هذا + +251 +00:22:01,780 --> 00:22:06,800 +التفاعل Intramolecular لو مافيش إمكانية من ناحية + +252 +00:22:06,800 --> 00:22:10,280 +الـ Geometry يصير الـ Intramolecular reaction الـ + +253 +00:22:10,280 --> 00:22:13,780 +Nitrene شو هيعمل؟ هيظل نيترين؟ لأ، بروح بدخل على + +254 +00:22:13,780 --> 00:22:19,360 +مثلمن جزية تانية Intermolecular لكن لما يكون فيه + +255 +00:22:19,360 --> 00:22:23,100 +إمكانية لـ Intermolecular و Intermolecular من يتم + +256 +00:22:23,100 --> 00:22:27,340 +الـ Intermolecular الـ Intermolecular مفضل على ال + +257 +00:22:27,340 --> 00:22:33,220 +Intermolecular الآن هذا الجواب بهذا الشكل افهمناه + +258 +00:22:33,220 --> 00:22:40,200 +لكن لاحظوا انه طلع معه هننتج تاني هذا خارج الموضوع + +259 +00:22:40,200 --> 00:22:45,770 +لكن لأنه مهم و بتكرر لا بأس ان احكيلكوا عليهزائد + +260 +00:22:45,770 --> 00:22:52,190 +NCO إيزو سيانات يعني الـ C double bond O نيترين + +261 +00:22:52,190 --> 00:22:59,010 +صارت إيش؟ إيزو سيانات الـ C double bond O المتصلة + +262 +00:22:59,010 --> 00:23:03,870 +بنيترين بتصير إيزو سيانات يعني كأنه بتجلب الشبك + +263 +00:23:03,870 --> 00:23:08,870 +تبعها صارت هذه الكاربون بدل ما هي شابكة بدل ما هي + +264 +00:23:08,870 --> 00:23:14,150 +شابكة بالـ C اللي هنا صارت شابكة بال إيش؟ بال N + +265 +00:23:15,140 --> 00:23:19,320 +طبعا البعض بيقول كيف تم هذا الكلام هذه + +266 +00:23:19,320 --> 00:23:23,580 +rearrangement مشهورة جدا اسمها Cortes + +267 +00:23:23,580 --> 00:23:27,740 +rearrangement هذه العملية اللي طلعت الناتج التاني + +268 +00:23:27,740 --> 00:23:33,840 +اللي هنا rearrangement مشهورة شو اسمها Cortes + +269 +00:23:33,840 --> 00:23:37,480 +rearrangement في ال Cortes rearrangement خلنا نقول + +270 +00:23:37,480 --> 00:23:41,540 +كان عندنا C double bond O أزايد سخننا صارت C + +271 +00:23:41,540 --> 00:23:46,400 +double bond O نيترينلاحظت أنا الكلام سليم ولا لأ؟ + +272 +00:23:46,400 --> 00:23:50,820 +الآن بعد هيك هذه ال R بتعمل migration بال bond + +273 +00:23:50,820 --> 00:23:55,100 +تبعتها على ال nitrogen فهتصير ايش؟ R عبر حلقة + +274 +00:23:55,100 --> 00:24:04,440 +ثلاثية R N C O واضحة؟ يعني لما نكون راسمينها بهذا + +275 +00:24:04,440 --> 00:24:07,600 +الشكل سهل عليكم أن تتخيلوا هذه الحلقة الثلاثية + +276 +00:24:07,600 --> 00:24:12,400 +اللي تم من خلالها التفاعل؟فصار عندى الكورتياس + +277 +00:24:12,400 --> 00:24:18,360 +rearrangement بهذا الشكل وهذا من أشهر طرق + +278 +00:24:18,360 --> 00:24:21,580 +بالمناسبة تحضير ال isocyanates يعني اللى بده + +279 +00:24:21,580 --> 00:24:28,420 +isocyanates بياخد C double bond O أزايد بخلق C + +280 +00:24:28,420 --> 00:24:33,200 +double bond O نيترين و عندها فرصة عالية تتحول لإيش + +281 +00:24:34,690 --> 00:24:38,990 +عشانك في هذا التفاعل صح هذا ال نيترين عمل ال + +282 +00:24:38,990 --> 00:24:43,370 +insertion لكن عمل كمان تفاعل الأساسي اللي هو ال + +283 +00:24:43,370 --> 00:24:48,380 +courtesary arrangementو في اكتر من rearrangement + +284 +00:24:48,380 --> 00:24:51,400 +حوالين Cortias يعني لو كتبتوا انتوا في google + +285 +00:24:51,400 --> 00:24:55,560 +search Cortias rearrangement الأشياء الشبيهة مع + +286 +00:24:55,560 --> 00:24:59,180 +تغيرات في نوع ال R و إشي هتلاقوا حوالي ستة سبعة + +287 +00:24:59,180 --> 00:25:03,040 +rearrangements كلهم نفس فكرة ال Cortias باسماء + +288 +00:25:03,040 --> 00:25:08,200 +مختلفةكلهم نفس فكرة ال courtesy rearrangement + +289 +00:25:08,200 --> 00:25:11,600 +باسمها مختلفة يعني إذا بتحضرولنا عليهم واحدة تحضر + +290 +00:25:11,600 --> 00:25:15,460 +أن تشرحلنا بدقيقة تقولنا شو أسميهم أو ممكن تشرحهم + +291 +00:25:15,460 --> 00:25:19,560 +مجرد ما تكتبوا courtesy rearrangement هيجيبلكم and + +292 +00:25:19,560 --> 00:25:22,980 +related rearrangements يعني أكتر من rearrangement + +293 +00:25:22,980 --> 00:25:27,380 +كلهم مبدأهم نفس مبدأ إيش ال courtesy rearrangement + +294 +00:25:27,380 --> 00:25:31,180 +بلاش الآن نضايق فيهم أقدر الآن بالنسبة للتفاعلات + +295 +00:25:31,180 --> 00:25:35,700 +مديش أعيد الكلامعنده الـ Cycloaddition على الـ + +296 +00:25:35,700 --> 00:25:43,100 +Double Bond وقلنا إنه بشكل عام بيكون عنده الـ cis + +297 +00:25:43,100 --> 00:25:47,080 +product predominant إذا أنا بدأت بـ cis على أساس + +298 +00:25:47,080 --> 00:25:51,960 +إنه التفاعل concerted يعني one step reaction مش من + +299 +00:25:51,960 --> 00:25:56,020 +خلال biological mechanism يعني الكربين أو الـ + +300 +00:25:56,020 --> 00:26:01,040 +Nitrene إيش حالته؟ singlet والـ Trans لو بتكون + +301 +00:26:01,040 --> 00:26:07,790 +بتكون بنسب قليلةو ال insertion يعني هي مثلا هنا + +302 +00:26:07,790 --> 00:26:12,010 +مثال اتطلعوا عليه مباشرة any three بالتسخين شو + +303 +00:26:12,010 --> 00:26:20,650 +هتصير؟ نيتريل الان وين ال H القريبة؟ هيا ولذلك هذه + +304 +00:26:20,650 --> 00:26:28,330 +هتيجي هنا و ال H؟ وين هتصير؟ عن نيتروجين نشطط + +305 +00:26:34,010 --> 00:26:37,530 +لاحظوا الـ Nitrene دخل بين الـ Carbon و الـ H ولا + +306 +00:26:37,530 --> 00:26:44,390 +لأ؟ هاي ال Nitrene هذه كانت Carbon-H صارت Carbon + +307 +00:26:44,390 --> 00:26:51,070 +-Nitrene-H واضحت فكرة ال insertion كذلك الحال هنا + +308 +00:26:51,070 --> 00:26:55,170 +في هذا المثال الحقيقة اللي هنا تم برضه insertion + +309 +00:26:55,170 --> 00:26:57,190 +على الـ H اللي هنا اللي جاب ال double bond مش + +310 +00:26:57,190 --> 00:27:00,100 +reaction على ال double bondلأن لو هذا بدي أعمل + +311 +00:27:00,100 --> 00:27:02,380 +reaction على الضوء بالموت، بدي أعمل حلقة ثلاثية + +312 +00:27:02,380 --> 00:27:07,040 +ولذلك هنا لما بدأ أطلع في النهاية، إيش كان عندي + +313 +00:27:07,040 --> 00:27:12,420 +هنا؟ H أصار نيترين، هاي هنا H أصار نيترين، إجت الـ + +314 +00:27:12,420 --> 00:27:19,380 +Nitrene هنا، والـH مع الـNitrogen، إذا هذا التفاعل + +315 +00:27:19,380 --> 00:27:24,420 +insertion ولا addition؟insertion لأنه صعب ان اعمل + +316 +00:27:24,420 --> 00:27:28,080 +addition هنا هيك و هيك حلقة ثلاثية بحلقة ربعية + +317 +00:27:28,080 --> 00:27:33,640 +بحلقة سادسية كجيومتري عملية صعبة ولذلك هنا لما + +318 +00:27:33,640 --> 00:27:37,240 +اتكون ال nitrene التفاعل اللي استكمل هو تفاعل + +319 +00:27:37,240 --> 00:27:39,100 +insertion + +320 +00:27:40,920 --> 00:27:44,620 +و في الأمثلة التانية اللي موجودة هنا برضه aside و + +321 +00:27:44,620 --> 00:27:48,640 +insertion على هذا النقطة او هنا N3 aside و + +322 +00:27:48,640 --> 00:27:53,140 +insertion على المثل بتاع الأمر بيصير سهل ممكن بعد + +323 +00:27:53,140 --> 00:27:59,580 +ال insertion هنا تم عملية إيش حذف جزء هيدروجين + +324 +00:27:59,580 --> 00:28:05,700 +يعني اول ما بيصير ال insertion NH و CH2 واضح انه + +325 +00:28:05,700 --> 00:28:12,010 +في ال final product حذف كمان إيشجزء الهيدروجين + +326 +00:28:12,010 --> 00:28:19,270 +طبعا إيش القوة الدافعة لإنه يحدث جزء الهيدروجين؟ + +327 +00:28:19,270 --> 00:28:25,970 +ليش انحدث جزء الهيدروجين هنا؟ أثبت ليش أثبت؟ كلمة + +328 +00:28:25,970 --> 00:28:30,450 +كلمة كلمة أنوار شبطر لإنه المركبaromatic .. + +329 +00:28:30,450 --> 00:28:34,610 +aromaticity .. aromatic يعني لما يتكون بدون ال + +330 +00:28:34,610 --> 00:28:38,530 +double bond اللي هنا حلقتين بتمن إلكترونات حسب + +331 +00:28:38,530 --> 00:28:41,990 +قواعد هوكي اللي قشي بيكونوا aromatic جديش بديلة ال + +332 +00:28:41,990 --> 00:28:49,350 +aromatic عشرة four n plus two متذكرين ال aromatic + +333 +00:28:49,350 --> 00:28:58,530 +البنزين ستة النافتالين عشرة الفنانثرين أربعة عشر + +334 +00:28:59,980 --> 00:29:06,240 +اتذكروا ال aromatic ليش تنسوه؟ هذا إيش؟ can buy + +335 +00:29:06,240 --> 00:29:14,200 +electron النفثالين أخدتوها + +336 +00:29:14,200 --> 00:29:18,720 +قاعدة وكل ولا .. طيب ليش صير انت نسوه؟ + +337 +00:29:23,320 --> 00:29:26,060 +تنين اربعة ستة تمانية عشر اتناش اربعة في تلاتة + +338 +00:29:26,060 --> 00:29:28,120 +اتناش اربعة في تلاتة اتناش اربعة في تلاتة اتناش + +339 +00:29:28,120 --> 00:29:28,600 +اربعة في تلاتة اتناش اربعة في تلاتة اتناش اربعة في + +340 +00:29:28,600 --> 00:29:29,540 +تلاتة اتناش اربعة في تلاتة اتناش اربعة في تلاتة + +341 +00:29:29,540 --> 00:29:32,440 +اتناش اربعة في تلاتة اتناش اربعة في تلاتة اتناش + +342 +00:29:32,440 --> 00:29:35,320 +اربعة في تلاتة اتناش اربعة في تلاتة اتناش اربعة في + +343 +00:29:35,320 --> 00:29:37,900 +تلاتة اتناش اربعة في تلاتة اتناش اربعة في تلاتة + +344 +00:29:37,900 --> 00:29:41,580 +اتناش اربعة في تلاتة اتناش اربعة في تلاتة اتناش + +345 +00:29:41,580 --> 00:29:44,800 +ارب + +346 +00:29:47,280 --> 00:29:51,380 +كذلك الحال في الأمثلة اللي هنا بإمكاننا نطلع أي + +347 +00:29:51,380 --> 00:29:56,940 +نيتلوجين فقد، شو صار عنده؟ كاربين، هذا مثال على + +348 +00:29:56,940 --> 00:30:01,340 +كاربين كويس، مواضحه هنا، الآن كم احتمال insertion + +349 +00:30:01,340 --> 00:30:11,270 +عنده الكاربين هذا؟ اكتر، اكتر، ليش؟هنا احتمال و + +350 +00:30:11,270 --> 00:30:17,810 +هنا احتمال و على هذه المثل و هذه كمان CH2 CH3 كان + +351 +00:30:17,810 --> 00:30:24,610 +بإمكان أي حد يرسم الكياب CH2 CH3 و يخليها .. صح + +352 +00:30:24,610 --> 00:30:29,900 +ولا لأ؟ يعني هذه الإثلشوفوا كيف الإنسان بيوجه + +353 +00:30:29,900 --> 00:30:33,280 +تفكير الناس أحيانا يعني لو هذه الإثر كنت أنا رسمها + +354 +00:30:33,280 --> 00:30:38,520 +CHH و كاتب هنا CH3 إيش اللي صار أقرب؟ إيش اللي + +355 +00:30:38,520 --> 00:30:44,780 +باين لعينيكم؟ انه يعمل هذا ال insertion هذا + +356 +00:30:44,780 --> 00:30:49,800 +insertion على ال secondary بيعطي حلقة سداسية + +357 +00:30:49,800 --> 00:30:57,120 +سداسية شوفوا سداسية الآن ال insertion اللي تم اللي + +358 +00:30:57,120 --> 00:31:05,610 +هناأعطى حلقة خمسية طبعا بتلاحظوا الآن ان هذا ال + +359 +00:31:05,610 --> 00:31:10,550 +insertion على tertiary هذا tertiary و بنفس الوقت + +360 +00:31:10,550 --> 00:31:16,510 +أعطى حلقة خمسية و هاي نتيجة التجربة واضح؟ هاي + +361 +00:31:16,510 --> 00:31:20,010 +نتيجة التجربة في النهاية هنا نفس الاشي برضه هذا + +362 +00:31:20,010 --> 00:31:23,730 +carbon عنده إمكانية ل insertions كتيرة و لجأ انه + +363 +00:31:23,730 --> 00:31:29,270 +أنسب insertion يجي على ال nitrogen اللي هناواضح؟ + +364 +00:31:29,270 --> 00:31:32,890 +لجأ أنه أنسب insertion يجعل نيتروجين لهاتف بعتقد + +365 +00:31:32,890 --> 00:31:37,550 +أنه يعني هذه الأمثلة حقيقة أكتر من كافية الأمثلة + +366 +00:31:37,550 --> 00:31:42,910 +لا تنتهي يعني هي كمان مثال assigned nitrene على ال + +367 +00:31:42,910 --> 00:31:47,150 +مثل insertion حلقة سداسية من أجمل ما يمكن شو اسم + +368 +00:31:47,150 --> 00:31:52,890 +هذا المركب العام؟لاحظوا انتوا كيف انه ال general + +369 +00:31:52,890 --> 00:31:56,930 +methods بتحضروا فيها كل إشي و ع بالمين أحيانا + +370 +00:31:56,930 --> 00:32:01,290 +بيخطر .. ع بالمين بيخطر انه هذا المركب اتحضر من + +371 +00:32:01,290 --> 00:32:07,450 +نيترين كيميسترا يعني لو هذا كان الإنسان بدو ييجي + +372 +00:32:07,450 --> 00:32:14,550 +يفكر .. بدو ييجي يفكر ب retro synthesis إله واضح؟ + +373 +00:32:14,550 --> 00:32:19,220 +الآن حسب ال retro synthesis اللي موجود عندنامن + +374 +00:32:19,220 --> 00:32:23,480 +خلال نيترين كيميسترا لكن بصراحة لو هذا اتيكوا في + +375 +00:32:23,480 --> 00:32:28,200 +امتحان كيف انتوا هتفكروا فيه اسهل ال C double bond + +376 +00:32:28,200 --> 00:32:37,780 +N يتخلوها N H2 و C double bond O مش + +377 +00:32:37,780 --> 00:32:43,480 +هذا كلام منطقي 100% ال C double bond N يتخلوها N + +378 +00:32:43,480 --> 00:32:49,250 +H2 و C double bond O يعني هذا هي حلقة الثيوفينهي + +379 +00:32:49,250 --> 00:32:52,850 +حلقة السيوفين لما يكون عندكم c double bond o و هنا + +380 +00:32:52,850 --> 00:32:57,270 +whatever whatever و هنا and h2 و أكمل المعادلة + +381 +00:32:57,270 --> 00:33:00,990 +واضح؟ + +382 +00:33:00,990 --> 00:33:06,650 +و طبعا هنا ممكن يكون عندكم h الديهايد و لو هذا + +383 +00:33:06,650 --> 00:33:10,090 +بدكم ترجعوا فيه خطوة لورا ماعرفش إذا ممكن تفكروا + +384 +00:33:10,090 --> 00:33:13,750 +في ال smile hack reaction تحطوا ال formula group + +385 +00:33:13,750 --> 00:33:20,790 +اللي هنامش هذي formal ممكن تفكروا بالزمايرهاك لكن + +386 +00:33:20,790 --> 00:33:26,050 +لاحظوا في هذا المثال إجت ب insertion و ال + +387 +00:33:26,050 --> 00:33:29,210 +insertion بالمناسبة ممتبوعة ب oxidation يعني فقد + +388 +00:33:29,210 --> 00:33:33,910 +فيه هيدروجين تاني لأن أساس ناتج ال insertion هنا + +389 +00:33:33,910 --> 00:33:39,750 +إيش بدو يكون un-etch, etch, etch بس لما فقدوا + +390 +00:33:39,750 --> 00:33:45,180 +الهيدروجين تاني ضالت بس etch واحدةيعني هذا الناتج + +391 +00:33:45,180 --> 00:33:51,060 +هو ناتج insertion followed by oxidation أو loss of + +392 +00:33:51,060 --> 00:33:59,140 +hydrogen واضح؟ بهيك تقريبا بننتهي من موضوع ال + +393 +00:33:59,140 --> 00:33:59,960 +nitrenes + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/2O9csqbNY1E.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/2O9csqbNY1E.srt new file mode 100644 index 0000000000000000000000000000000000000000..543e88f5caca6868e42689245e0bfd3c2646b9dd --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/2O9csqbNY1E.srt @@ -0,0 +1,1851 @@ +1 +00:00:21,010 --> 00:00:27,410 +بسم الله الرحمن الرحيم زي ما احنا اتفقنا أنه هنركز + +2 +00:00:27,410 --> 00:00:33,470 +كثير على الطرق المختلفة لتكوين الحلقات واتكلمنا عن + +3 +00:00:33,470 --> 00:00:37,790 +تفاعلات الإبدال، تفاعلات الإضافة على الروابط + +4 +00:00:37,790 --> 00:00:42,810 +الزوجية بأنواعها المختلفة، وبعدين بدأنا بتفاعلات + +5 +00:00:42,810 --> 00:00:49,390 +الإضافة على الروابط الثلاثية وبدأنا نتكلم عن ال + +6 +00:00:49,390 --> 00:00:52,550 +carbon ال triple bond carbon في المرة الماضية + +7 +00:00:52,550 --> 00:00:56,690 +وقلنا أن هنا الإضافة غالبا بتحتمل الاحتمالين + +8 +00:00:56,690 --> 00:01:01,230 +وشوفنا أمثلة بتحتمل ال exocyclization وال + +9 +00:01:01,230 --> 00:01:05,940 +endocyclization. الآن من أمثلة ال triple bonds + +10 +00:01:05,940 --> 00:01:10,520 +المهمة جدا واللي بتتكرر كثير الحقيقة في ال + +11 +00:01:10,520 --> 00:01:15,020 +organic synthesis اللي هي الإضافة على ال C triple + +12 +00:01:15,020 --> 00:01:20,320 +bond N يعني هذا تفاعل شهير جدا لازم إيديكم تتدرب + +13 +00:01:20,320 --> 00:01:26,450 +عليه. أنا بأكد إن حتى مساحة هذا التفاعل لأنه مهم لا + +14 +00:01:26,450 --> 00:01:30,530 +يمكن أنها تقل في مجمع الامتحانات اللي أنا بسأل فيها + +15 +00:01:30,530 --> 00:01:35,330 +ربما عن عشرة في المائة من علامة الامتحان من علامة + +16 +00:01:35,330 --> 00:01:40,330 +المساق كله، ولذلك عليكم أنكم إيش تتدربوا على هذا + +17 +00:01:40,330 --> 00:01:40,790 +التفاعل. + +18 +00:01:46,070 --> 00:01:52,110 +طبعا هذا cyclization جميل وسهل. الآن الاحتمال فيه + +19 +00:01:52,110 --> 00:01:58,910 +تقريبا احتمال واحد، لأن الكربون بشكل عام is more + +20 +00:01:58,910 --> 00:02:02,190 +positive than the nitrogen. واضح هذا الكلام من ال + +21 +00:02:02,190 --> 00:02:05,610 +electronegativity فهي ال electrophilic center + +22 +00:02:05,610 --> 00:02:08,470 +وبالتالي لو تخيلنا مثال زي هذا أن في عند + +23 +00:02:08,470 --> 00:02:13,540 +نيوكليوفايل بده يهاجم، وين هيكون الهجوم؟ على ال carbon + +24 +00:02:13,540 --> 00:02:20,200 +وبالتالي نوع ال cyclization is a exocyclization. + +25 +00:02:20,200 --> 00:02:23,180 +هذا شيء متفق عليه. الآن لما بيصير هذا ال + +26 +00:02:23,180 --> 00:02:27,720 +exocyclization، وزوج الإلكترونات بتحرك هنا على ال N + +27 +00:02:27,720 --> 00:02:32,860 +هذه طبعا زي عمليات الإضافة، بتصير N minus بتاخد H + +28 +00:02:32,860 --> 00:02:38,760 +بتصفى NH يعني هيصير عندي C double bond NH هنا تمت + +29 +00:02:38,760 --> 00:02:43,720 +عملية الإضافة. يعني الإضافة على الرابطة الزوجية أنه + +30 +00:02:43,720 --> 00:02:47,680 +الرابطة الزوجية تصير أحدية، أفقد by bond الإضافة + +31 +00:02:47,680 --> 00:02:51,020 +على الرابطة الثلاثية أنه الرابطة الثلاثية تصير + +32 +00:02:51,020 --> 00:02:54,720 +تنائية وأعمل two new sigma bonds أنا عملتهم، هاي + +33 +00:02:54,720 --> 00:02:58,100 +sigma bond وهاي sigma bond. فهذا التفاعل كتصنيف + +34 +00:02:58,100 --> 00:03:04,240 +يصنف إيش؟ تفاعل إضافة. هذا الناتج اللي اتكون عندي + +35 +00:03:04,240 --> 00:03:09,040 +اللي هو c double bond and h هذا احنا بنصنفه إيمين + +36 +00:03:09,990 --> 00:03:14,310 +اسمه imine. الآن ال emines بشكل عام بتعمل + +37 +00:03:14,310 --> 00:03:17,950 +tautomerism تقريبا زي ال tautomerism اللي + +38 +00:03:17,950 --> 00:03:24,590 +اتعلمتوها لل keto enol tautomerism فبتعمل enamine + +39 +00:03:24,590 --> 00:03:31,720 +بمعنى بتنتقل هيدروجين من هذا الموقع، هنا لو بدنا + +40 +00:03:31,720 --> 00:03:36,020 +نيجي نتطلع هذه ال H بتنتقل إلى هنا والرابطة + +41 +00:03:36,020 --> 00:03:40,820 +بتنتقل، لحظة حركة إلكترونات وحركة ذرات، حركة + +42 +00:03:40,820 --> 00:03:45,340 +إلكترونات وحركة ذرات. إذا أنا هنا بتكلم عن إيش؟ + +43 +00:03:45,340 --> 00:03:49,980 +بتكلم عن tautomerism لأن ال tautomerism إلكتروناتو + +44 +00:03:49,980 --> 00:03:53,680 +ذرات البروتونز بتتحرك. طبعا هذا ال tautomerism + +45 +00:03:53,680 --> 00:03:59,320 +بنسميه احنا إيمين إينامين tautomerism بفترض أنه مرت + +46 +00:03:59,320 --> 00:04:05,560 +عليكم زي ما مر عليكم الكيتو اينول، واضح؟ الآن في + +47 +00:04:05,560 --> 00:04:09,180 +الإيمين إنامين tautomerism، ال more stable بشكل عام + +48 +00:04:09,180 --> 00:04:13,360 +product is the amine. عكس ال keto وال enol يعني لو + +49 +00:04:13,360 --> 00:04:17,800 +أنا كنت بده اتخيل هدول موازين ل ال keto وال enol + +50 +00:04:17,800 --> 00:04:21,800 +tautomerism بقول هي ال ketone وطفر وهي ال enol + +51 +00:04:23,550 --> 00:04:27,130 +كيتو اينول التوتوميرزم في الاليفانتيك كومباونز التي + +52 +00:04:27,130 --> 00:04:29,270 +هي أكتر مستقرة، الكيتون + +53 +00:04:54,900 --> 00:05:01,120 +CNH2، وبنطلب من الإنسان أنه اعملنا تحضير لهذا + +54 +00:05:01,120 --> 00:05:05,040 +المركب يعني لو شفتوا مثل هذا المنظر، وقولنا لكوا + +55 +00:05:05,040 --> 00:05:08,060 +اعملوا تحضير لهذا المركب، بتكونوا تفكروا ب retro + +56 +00:05:08,060 --> 00:05:12,840 +synthesis على طول، بتكونوا تتخيلوا أن هذه كانت C + +57 +00:05:12,840 --> 00:05:17,300 +triple bond N. طبعا من واي بدأ، أكثر من جنبها من هذا + +58 +00:05:17,300 --> 00:05:21,240 +الموقع ولا من هذا؟ اكيد من الموقع اللي فيه ال + +59 +00:05:21,240 --> 00:05:25,950 +nucleophile. يعني أنا قلت أن هذه كانت هي قبوحانة، أي + +60 +00:05:25,950 --> 00:05:30,950 +رابطة الاتكوانات هذه ولا هذه؟ اكيد هذه. واضح وبالتالي + +61 +00:05:30,950 --> 00:05:35,570 +بقدر ارجع بسهولة لهذا المركب، يعني قلتلكوا اعملولي + +62 +00:05:35,570 --> 00:05:39,610 +retro synthesis لهذا المركب بتقدر تخيلوا هاي ال + +63 +00:05:39,610 --> 00:05:44,170 +Nucleophile ال CNH2 اللي جنب ال double bond، بمعنى + +64 +00:05:44,170 --> 00:05:50,810 +آخر ال enamine أصلها nitrile، C triple bond N + +65 +00:05:50,810 --> 00:05:56,090 +واضح؟ وهذا مثال بتشوفوه كثير. الآن ممكن بأحوال + +66 +00:05:56,090 --> 00:06:02,550 +معينة، ممكن بأحوال معينة أن الأمور تقف هنا، ممكن، + +67 +00:06:02,550 --> 00:06:07,260 +لو ما كانش فيها هيدروجين، تعمل هاتوتو بريزل. واضح؟ + +68 +00:06:07,260 --> 00:06:12,120 +ممكن أن أقف عند الإيمين موجود، لكن المشهور طالما + +69 +00:06:12,120 --> 00:06:15,600 +هذه الهيدروجين اللي بتعمل توتوميرزم موجودة، أن التفاعل + +70 +00:06:15,600 --> 00:06:21,260 +بيستمر أكثر. الآن في مرات كثيرة لما يكون هذا الكلام + +71 +00:06:21,260 --> 00:06:26,150 +مش ممكن، يعني أقف عند الإيمين، بدي يكون جزء من + +72 +00:06:26,150 --> 00:06:29,610 +الكيمياء العادية اللي مرت عليكوا بحياتكوا، أن هدول + +73 +00:06:29,610 --> 00:06:35,070 +ال emines they are unstable. فمرات كثيرة هتلاحظوا + +74 +00:06:35,070 --> 00:06:40,840 +أنه بتحولوا الى C double bond O. كثير هتلاحظوا أن + +75 +00:06:40,840 --> 00:06:44,880 +الأشياء اللي ممكن تصفي E means، ال E means they are + +76 +00:06:44,880 --> 00:06:48,620 +unstable، ضمن acidic conditions أو basic + +77 +00:06:48,620 --> 00:06:51,840 +conditions موجودة في التفاعل، هتلاحظوا أنه بدل ما + +78 +00:06:51,840 --> 00:06:58,200 +هي E mean إيش اللي كتبت في ال product النهائي. واضح؟ + +79 +00:06:58,200 --> 00:07:02,500 +اللي هو amine hydrolysis، amine hydrolysis. أن ال + +80 +00:07:02,500 --> 00:07:06,680 +amine هذا ممكن ما تلاقوه لو صار إيش C double point + +81 +00:07:06,680 --> 00:07:11,980 +O، بالذات لو كانش بيقدر يعمل التوتوميرزم. كل هذا + +82 +00:07:11,980 --> 00:07:19,390 +الكلام بتشوفوه، وخلينا الآن نشوف بعض الأمثلة على هذه + +83 +00:07:19,390 --> 00:07:23,810 +الفكرة، فكرة ال cyclization على ال night trials، لو + +84 +00:07:23,810 --> 00:07:28,150 +احنا اتينا واتطلعنا على هذا المثال وخلطناه + +85 +00:07:28,150 --> 00:07:31,870 +مركبين. الآن هنا في عندنا good leaving group اللي + +86 +00:07:31,870 --> 00:07:37,990 +هي ال ethoxy group مع ال NH2، هذا ال NH2 بتهاجم و + +87 +00:07:37,990 --> 00:07:43,550 +بتحل محل ال ethoxy group. لاحظوا هذا الجزء من الجزء + +88 +00:07:43,550 --> 00:07:44,450 +اللي هو R + +89 +00:07:47,080 --> 00:07:51,560 +CNHCN محطوط في الدائرة. لحظة، أنا حاطيته في الدائرة + +90 +00:07:51,560 --> 00:07:55,940 +عشان تعرفوا الجزئين. الآن أنا صار عندي C triple + +91 +00:07:55,940 --> 00:08:01,590 +bond N whatever. الآن هي نيوكليوفايل وهي C triple + +92 +00:08:01,590 --> 00:08:05,250 +bond N تانية. المفروض أن هذا النيوكليوفايل بده + +93 +00:08:05,250 --> 00:08:11,130 +يهاجم على هذه C triple bond N في النهاية بده يصفى + +94 +00:08:11,130 --> 00:08:15,850 +إيش NH2 ويعمل double bond يعني أول ما بده يهاجم + +95 +00:08:15,850 --> 00:08:22,530 +بهذا الشكل هتصير double bond NH لأن هنا في عندي C + +96 +00:08:22,530 --> 00:08:29,890 +H مجاورة وبالتالي اطول بتصير هذه NH2 و double + +97 +00:08:29,890 --> 00:08:36,090 +bond هنا حضرنا إيميدازول. واضح هنا حضرنا إيميدازول. + +98 +00:08:36,090 --> 00:08:39,970 +فالمثال المقصود بالنسبة لنا مش الخطوة الأولى، + +99 +00:08:39,970 --> 00:08:44,270 +الخطوة الأولى تجهيز، لكن خطوة ال cycleization اللي + +100 +00:08:44,270 --> 00:08:48,290 +فيها nucleophile هاجم على C triple bond N أنها + +101 +00:08:48,290 --> 00:08:49,490 +ولاحظوا + +102 +00:08:52,440 --> 00:08:56,180 +هذه دائما. الآن NH2 اللي جمد بالبند اللي هي + +103 +00:08:56,180 --> 00:09:01,940 +الإينامين هي نتاج الإغلاق على C triple bond N فاين + +104 +00:09:01,940 --> 00:09:07,140 +بتشوفوا الإينامين، تفكيركم أن هذه أصلا كانت C triple + +105 +00:09:07,140 --> 00:09:12,980 +bond N الآن + +106 +00:09:12,980 --> 00:09:18,060 +هنا في عندي أمثلة إضافية. لو اتطلعنا مثلا على هذا + +107 +00:09:18,060 --> 00:09:23,240 +المثال، عندي activated methylene group، CH2 + +108 +00:09:23,240 --> 00:09:28,400 +جمتن تان، C double bond N، هذا ال مالوني ترايل زي ال + +109 +00:09:28,400 --> 00:09:32,200 +مالونيك إيستر، يعني ال CH2 هنا بتكون إيش highly + +110 +00:09:32,200 --> 00:09:36,960 +activated وبالتالي ال base حتى ضعيفة ممكن تسحب وممكن + +111 +00:09:36,960 --> 00:09:42,600 +تهاجم هنا على C double bond O كيتون اللي هنا + +112 +00:09:42,600 --> 00:09:44,120 +يعني لاحظوا هذا الجزء + +113 +00:09:46,880 --> 00:09:50,500 +اللي هو C متصل فيها تنتين CNN هو هذا الجزء اللي + +114 +00:09:50,500 --> 00:09:55,940 +حطناه بدائرة. الآن هنا كان عندنا C double bond O + +115 +00:09:55,940 --> 00:10:00,500 +لما بده يتم عليها الإضافة من CH ماينوس شو بده تصير + +116 +00:10:00,500 --> 00:10:05,380 +OH okay عملنا الجزء الأول. هي الرابطة الجديدة اللي + +117 +00:10:05,380 --> 00:10:10,760 +احنا عملناها بينهم، هذه الرابطة الجديدة. الآن الخطوة + +118 +00:10:10,760 --> 00:10:15,320 +اللي بتهمنا، خطوة ال cycleization، ال nucleophile + +119 +00:10:15,320 --> 00:10:22,510 +موجودة وC triple bond N موجودة هتعمل إيمين وتحول + +120 +00:10:22,510 --> 00:10:29,470 +إلى إنامين، وطبعا اكيد ال OH اللي هنا ما H من + +121 +00:10:29,470 --> 00:10:36,910 +هنا هتحدث مية. واضح فبطلع عندي pyrole derivative + +122 +00:10:36,910 --> 00:10:41,210 +بطلع عندي pyrole derivative. لحظة أن التفاعلات + +123 +00:10:41,210 --> 00:10:44,230 +تفاعلات بسيطة، التفاعل الأول addition على C triple + +124 +00:10:44,230 --> 00:10:49,780 +bond O كخطوة تحضيرية والتفاعل الثاني Cyclization + +125 +00:10:49,780 --> 00:10:53,160 +على C triple bond N + +126 +00:10:59,510 --> 00:11:06,670 +المثال الثاني هنا لدي ثيويوريا، C double bond S NH2 + +127 +00:11:06,670 --> 00:11:12,150 +NH2. ثيويوريا، هذه ثيويوريا لما تتفاعل على فين ال CH + +128 +00:11:12,150 --> 00:11:17,690 +PR CN. لاحظوا هنا ال PR is a good leaving group + +129 +00:11:17,690 --> 00:11:22,250 +يعني ممكن بالخطوة الأولى يصير عندي substitution + +130 +00:11:22,250 --> 00:11:30,360 +فأنا لو اتيت اتطلعت هنالاحظوا معايا أن ال نيتروجين + +131 +00:11:30,360 --> 00:11:35,880 +هم النيوكليوفايل والكبريت كمان النيوكليوفايل ومرات + +132 +00:11:35,880 --> 00:11:41,540 +كثير لما بيلتقى الكبريت والنيتروجين الكبريت اقوى أنه + +133 +00:11:41,540 --> 00:11:45,800 +يتفاعل كنيوكليوفايل ولذلك التفاعل هنا تم من خلال + +134 +00:11:45,800 --> 00:11:51,320 +إيش الكبريت؟ يعني هذا الجزء هو الثيويوريا اللي + +135 +00:11:51,320 --> 00:11:56,830 +موجودة هنا. هذا اللي كان C double bond S NH2 NH2 + +136 +00:11:56,830 --> 00:12:02,090 +طبعا بإحدى صوره ممكن تتخيلوا SH double bond NH + +137 +00:12:02,090 --> 00:12:08,250 +مش صعب إطلاقا نتخيله. الآن الكبريت هاجم، طرد إيش ال + +138 +00:12:08,250 --> 00:12:14,570 +PR. هي عندي فين ال CH C triple bond N هذا الجزء + +139 +00:12:14,570 --> 00:12:19,190 +موجود وهي الجزء الثيويوريا اتفاعلت من خلال إيش + +140 +00:12:19,830 --> 00:12:24,830 +الكبريت، دائما .. دائما .. لما بيلتقي عندكوا كبريت و + +141 +00:12:24,830 --> 00:12:30,650 +نيتروجين كنوكليوفيل فاكروا كتير إن السلفر بنافس + +142 +00:12:30,650 --> 00:12:38,170 +النيتروجين وبقوة .. وبقوة على أنه يعني يتفاعل + +143 +00:12:38,170 --> 00:12:43,610 +كنيوكليوفايل الآن بعد هيك ال N-H و C-Triple bond N + +144 +00:12:43,610 --> 00:12:47,870 +شو بده تصير ال C-Triple bond N في النهاية N-H2 + +145 +00:12:47,870 --> 00:12:53,710 +Enamine بإمكاننا نفصلها خلاص احنا صرنا متفقين إن + +146 +00:12:53,710 --> 00:12:59,090 +الـ C triple bond N بتصير أمين واضح هاي الأمين + +147 +00:12:59,090 --> 00:13:04,650 +موجود بهذا الشكل بتم عملية الـ cyclization في هذا + +148 +00:13:04,650 --> 00:13:10,450 +المثال بتابع ليه لو بتتابعوا أيضا الأمثلة الثانية + +149 +00:13:10,450 --> 00:13:17,350 +كلها بنفس المنطق يعني هنا بتفقد عند مجموعة O إيثل + +150 +00:13:17,350 --> 00:13:22,250 +بيشبكوا هدول الجزيئين بإمكاننا أن نفرجيكم إن هذا + +151 +00:13:22,250 --> 00:13:29,610 +الجزء الـ CNCH2 NH2 اللي اتفاعل من خلال هذه + +152 +00:13:29,610 --> 00:13:35,670 +النيتروجين طرد O إيثل منها بمعنى هذا الجزء هذا + +153 +00:13:35,670 --> 00:13:43,630 +الأزرق CN CH2 NH طرد ال O إيثل و أعطانا C double + +154 +00:13:43,630 --> 00:13:49,570 +bond NH CO2 إيثل الآن هي النوكليوفيل وهي ال CN + +155 +00:13:49,570 --> 00:13:53,850 +شو اللي هتشوفه هناك بدون ما نطلع أمين هاي + +156 +00:13:53,850 --> 00:14:00,880 +الأمين واضح؟ هاي الأمين هذه الأمثلة إلا الإنسان + +157 +00:14:00,880 --> 00:14:06,200 +يعني نفسه يتدرب عليها بالجلم للرصاص و بالورقة لحد + +158 +00:14:06,200 --> 00:14:11,780 +ما يتقن إجراء التفاعل على ال nitriles و زي ما + +159 +00:14:11,780 --> 00:14:16,200 +قلنا هذا تفاعل شهير دائما لما تشوفوا ال amino + +160 +00:14:16,200 --> 00:14:20,380 +group جنب ال double bond جزء من تفكيركم في ال + +161 +00:14:20,380 --> 00:14:25,020 +synthesis للمركب بده يروح لإيش لأنه كان أصلها + +162 +00:14:25,020 --> 00:14:31,100 +nitrile كان أصلها nitrile الآن بيجينا + +163 +00:14:31,100 --> 00:14:34,940 +cyclization ثاني شبيه في هذا الـ cyclization + +164 +00:14:34,940 --> 00:14:40,520 +cyclization onto ايزو نايترايل لاحظوا الـ ايزو + +165 +00:14:40,520 --> 00:14:45,240 +نايترايل اللي هم ماخدين الصيغة العامة R N triple + +166 +00:14:45,240 --> 00:14:51,140 +bond C النايترايل R C triple bond N هنا انعكسوا + +167 +00:14:51,140 --> 00:14:54,440 +الذرات بمعنى هنا النيتروجين هنا الكربون ال + +168 +00:14:54,440 --> 00:14:59,370 +نايترايل C triple bond N الايزو نايترايل and triple + +169 +00:14:59,370 --> 00:15:04,650 +bond C الآن ال isonitriles طبعا لها resonance + +170 +00:15:04,650 --> 00:15:09,290 +structures منها إن هذي الكربون تكون سالب أو هذي ال + +171 +00:15:09,290 --> 00:15:13,130 +نيتروجين تكون موجبة و ممكن resonance structure + +172 +00:15:13,130 --> 00:15:20,090 +ثاني متعادل بشكل عام التفاعل على ال isonitrile أنا + +173 +00:15:20,090 --> 00:15:26,190 +بأحطه هنا عشان نتعلم كيف نفذه التفاعل دائما يتم على + +174 +00:15:26,190 --> 00:15:31,480 +الكربون التفاعل دائما يتم على الكربون والـ + +175 +00:15:31,480 --> 00:15:37,460 +cyclization is endocyclization واضح؟ بمعنى لو + +176 +00:15:37,460 --> 00:15:41,120 +اتخيلت إن هاي عندي هنا ايزو نايترايل يمكن البعض + +177 +00:15:41,120 --> 00:15:45,100 +يستغرب شوية إن بده يقول النوكليوفيل بده يهاجم + +178 +00:15:45,100 --> 00:15:49,940 +على minus يعني minus على minus لكن ما بديش أنسى إن + +179 +00:15:49,940 --> 00:15:55,490 +في resonance structures مش minus واضح؟ يعني معظم + +180 +00:15:55,490 --> 00:15:58,310 +الكتب لما بتكتب ما بتحطش هذا resonance structure + +181 +00:15:58,310 --> 00:16:04,690 +بتحط زي هيك وبالتالي بيبدأ الطالب يتحير إن هو أخذ + +182 +00:16:04,690 --> 00:16:09,530 +قواعد عامة إن لأ ال minus بده يروح على موجب لأ لأ + +183 +00:16:09,530 --> 00:16:13,290 +ما هو في هنا resonance structure بيكون متعادل مش + +184 +00:16:13,290 --> 00:16:19,000 +..مش minus لذلك التفاعل دائما وين بده يكون على ال + +185 +00:16:19,000 --> 00:16:22,880 +carbon اللي هنا طبعا لما بده يتم التفاعل هذا زوج + +186 +00:16:22,880 --> 00:16:27,100 +الإلكترونات في نهاية بده يصفي CH هذا زوج + +187 +00:16:27,100 --> 00:16:29,400 +الإلكترونات بده يصفي .. يعني لما أنا بده أعمل + +188 +00:16:29,400 --> 00:16:33,920 +رابطة هنا مع ال oxygen هذا زوج الإلكترونات بده يصفي + +189 +00:16:33,920 --> 00:16:37,720 +إيش CH بمعنى جزء ال isonitrile الحيون + +190 +00:16:40,700 --> 00:16:44,260 +لاحظوا طلعنا شوية برا الشاشة لكن اللي بدو يصير + +191 +00:16:44,260 --> 00:16:50,860 +موجود عندي هنا على هذه النقطة إيش CH + +192 +00:16:50,860 --> 00:16:57,020 +اللي بدو يصير موجود عندي CH على أساس إن ال H هذه + +193 +00:16:57,020 --> 00:17:02,280 +بدأ تيجي هنا بدل زوج الإلكترونات لأنه مش هتبقى C + +194 +00:17:02,280 --> 00:17:08,140 +minus لما بدنا نعمل رابطة فبناء على ذلك دائما لما + +195 +00:17:08,140 --> 00:17:13,110 +احنا بنشوف مثل هذا المنظر الآن الناس اللي بدهم + +196 +00:17:13,110 --> 00:17:17,290 +يفكروا بال retro synthesis يعني يتخيلوا إنهم بدهم + +197 +00:17:17,290 --> 00:17:23,310 +يحضروا هينوكليوفيل بعدين CN لاحظوا النوكليوفيل + +198 +00:17:23,310 --> 00:17:28,210 +CNN مباشرة بإمكانكم تصيروا تتخيلوا إن هذه ال CNN + +199 +00:17:28,210 --> 00:17:31,250 +كانت ايزو نايترايل + +200 +00:17:32,070 --> 00:17:36,230 +يعني الـ Nucleophile شابك بـ C double bond N + +201 +00:17:36,230 --> 00:17:42,970 +فبتكون إيش أصلها؟ Isonitrile والحقيقة إنه يعني + +202 +00:17:42,970 --> 00:17:48,810 +موجود أمثلة كتير أمثلة كتير على ال cyclization على + +203 +00:17:48,810 --> 00:17:56,630 +ال isonitrile على سبيل المثال هذا المركب لاحظوا في + +204 +00:17:56,630 --> 00:17:59,490 +هذا المركب عند الـ isonitrile عارف إن الـ + +205 +00:17:59,490 --> 00:18:03,110 +cyclization بدو يصير على الكربون تصير double bond + +206 +00:18:03,110 --> 00:18:06,370 +CH cyclization بدو يصير على الكربون تصير double + +207 +00:18:06,370 --> 00:18:11,730 +bond CH هنا استعمل CH2 جنبها R و double bond + +208 +00:18:11,730 --> 00:18:17,610 +لاحظوا إن هذه CH2 مش activated methylene group أو + +209 +00:18:17,610 --> 00:18:21,130 +مش highly activated methylene group لكن الكيميا + +210 +00:18:21,130 --> 00:18:27,180 +لتعرف المستحيل يعني ليش احنا بنقول إن في عندنا + +211 +00:18:27,180 --> 00:18:31,630 +base أقوى من base و بندرس ال strength of bases يوم + +212 +00:18:31,630 --> 00:18:34,390 +ما يكون عندي ال Malonic Easter بال Sodium + +213 +00:18:34,390 --> 00:18:37,130 +Carbonate ولا بالبريديل اللي هي ال bases اللي + +214 +00:18:37,130 --> 00:18:43,270 +ضعيفة بشيل منه ال protons بينما أشياء صعبة بصير + +215 +00:18:43,270 --> 00:18:46,510 +استعمل لها ال lithoxide أشياء أصعب ممكن استعمل لها + +216 +00:18:46,510 --> 00:18:52,390 +ال hydrides ممكن استعمل لها هذا المركب ال LDA هذا + +217 +00:18:52,390 --> 00:18:57,990 +ال LDA اللي هو Lithium Diisopropyl Amide هذا + +218 +00:18:57,990 --> 00:19:01,090 +المركب الأصلي تكونوا يمكن مار عليكوا أو من اليوم + +219 +00:19:01,090 --> 00:19:05,870 +تتعلموا lithium diisopropyl amine هذا المركب + +220 +00:19:05,870 --> 00:19:10,990 +commonly abbreviated LDA is a chemical compound + +221 +00:19:10,990 --> 00:19:16,530 +with this formula أهم شغلة فيه it is used as a + +222 +00:19:16,530 --> 00:19:22,210 +strong base يعني وين بنشوفه و بنقول عنه إيش strong + +223 +00:19:22,210 --> 00:19:26,830 +base lithium diisopropyl amide طالما strong base + +224 +00:19:26,830 --> 00:19:32,070 +هيشتغل على أي هيدروجين اللي موجودة هنا هيعمل ال + +225 +00:19:32,070 --> 00:19:36,730 +carbon nucleophile in this case واضح؟ عمل في هذه + +226 +00:19:36,730 --> 00:19:41,070 +الحالة ال carbon nucleophile الآن ببساطة احنا + +227 +00:19:41,070 --> 00:19:44,630 +قلنا تنفيذ الإغلاق كيف النوكليوفيل على ال + +228 +00:19:44,630 --> 00:19:51,480 +carbon بتصير double bond و CH واضح؟ للنوكليوفيل + +229 +00:19:51,480 --> 00:19:55,600 +هجومه على الكربون و بتصير ال triple bond و double + +230 +00:19:55,600 --> 00:20:03,140 +bond و CH هذا مثال أعطانا in those derivatives هذا + +231 +00:20:03,140 --> 00:20:06,560 +المثال أعطانا in those derivatives و الكربون + +232 +00:20:06,560 --> 00:20:14,120 +المستعمل كان هو للنوكليوفيل لاحظوا يمكن تلاحظوا + +233 +00:20:14,120 --> 00:20:19,920 +كمان ملاحظة إن هو استعمل إيش ناقص ثمانية وسبعين + +234 +00:20:19,920 --> 00:20:24,500 +درجة مئوية كما يبدو عشان يقدر يسيطر هذا ال + +235 +00:20:24,500 --> 00:20:27,920 +condition المناسب يمكن البعض يجي يتساءل ليش ناقص + +236 +00:20:27,920 --> 00:20:32,200 +ثمانية وسبعين ليش ما كانت ناقص ثمانين ولا ناقص + +237 +00:20:32,200 --> 00:20:40,200 +خمسة وسبعين يعني هي الثمانية وسبعين مقدسة واضح؟ + +238 +00:20:40,200 --> 00:20:45,200 +الآن كثير من المعادلات بحياتكم هتلاحظوا إنه + +239 +00:20:45,200 --> 00:20:51,530 +بتنعمل عند ناقص ثمانية وسبعين تمام ال 78 مش مقدسة + +240 +00:20:51,530 --> 00:20:58,430 +لكن في وسيلة تبريد سهلة للي بده تبريد كتير هذه + +241 +00:20:58,430 --> 00:21:02,770 +الوسيلة بتعطي ناقص 78 فهو بيستعمل يعني مش فارق + +242 +00:21:02,770 --> 00:21:06,230 +كتير كان لو بده يكون ناقص 80 ولا ناقص 70 ولا ناقص + +243 +00:21:06,230 --> 00:21:11,570 +85 لكن وسيلة التبريد اللي درجة وموجودة في + +244 +00:21:11,570 --> 00:21:16,680 +المختبرات بسهولة لهذا ال range من التبريد ابتعد + +245 +00:21:16,680 --> 00:21:24,700 +تناقص 78 هذه وسيلة التبريد شو هي الاسمها + +246 +00:21:24,700 --> 00:21:30,940 +الـ dry ice لأ النيتروجين السائل بنزلكوا لناقص 150 + +247 +00:21:30,940 --> 00:21:36,920 +و ناقص 200 ال liquid nitrogen بنزل لناقص 200 كتير + +248 +00:21:38,040 --> 00:21:43,040 +لكن الـ dry ice اللي هو عبارة عن ثاني أكسيد الكربون + +249 +00:21:43,040 --> 00:21:47,040 +في الحالة الصلبة بيكون موجود بتلاجات في المختبرات + +250 +00:21:47,040 --> 00:21:51,080 +زي التلج اللي بينباع هذا في الثلاجات بياخدوا قطع + +251 +00:21:51,080 --> 00:21:53,920 +منه و بيحطوه حوالين التفاعل أو بيحطوها ب solvent + +252 +00:21:53,920 --> 00:22:02,080 +فهذا عادة بيعطي حرارة ناقص 78 فممكن في المستقبل + +253 +00:22:02,080 --> 00:22:08,040 +تسمعوا البني آدم اللي بيشرح مثل هذا التفاعل لما بده + +254 +00:22:08,040 --> 00:22:12,220 +يحكي هو الواحد بده يفهم مصطلحات العلم تبعه يعني + +255 +00:22:12,220 --> 00:22:16,640 +بده يجي يقول إن this reaction using a strong base + +256 +00:22:16,640 --> 00:22:21,600 +in a dry ice شوف كيف الكيميا اللي بده يتكلم ما بدوش + +257 +00:22:21,600 --> 00:22:24,660 +يقول lithium di isopropyl amide lithium di + +258 +00:22:24,660 --> 00:22:28,700 +isopropyl amide finally is a strong base ناقص + +259 +00:22:28,700 --> 00:22:32,960 +ثمانية وسبعين is a dry ice فبتلاقي الواحد لما + +260 +00:22:32,960 --> 00:22:36,840 +بيحكي بيقول using a strong base in a dry ice + +261 +00:22:36,840 --> 00:22:42,460 +produces the carbanion which attacks the + +262 +00:22:42,460 --> 00:22:46,640 +isonitrile and cyclosis to endure واضحة هذه + +263 +00:22:46,640 --> 00:22:47,260 +الفكرة؟ + +264 +00:22:52,680 --> 00:23:00,300 +هنا مثال ثاني هي isonitrile جنبها CH2 لاحظوا هذه + +265 +00:23:00,300 --> 00:23:03,680 +الأمثلة كتير مشهورة في isonitrile cyclization إن + +266 +00:23:03,680 --> 00:23:08,760 +نجيب مركبات ال isonitrile جنبها CH2 ال CH2 اللي + +267 +00:23:08,760 --> 00:23:12,160 +جنب ال isonitrile is activated methylene group + +268 +00:23:12,160 --> 00:23:16,860 +وبناء على ذلك لو احنا استعملنا base لو احنا + +269 +00:23:16,860 --> 00:23:22,530 +استعملنا base هتسحب منها بروتون هتكون عندكالـ Ion + +270 +00:23:22,530 --> 00:23:27,290 +السالب هذا ممكن يضيف على مركبات زي C double bond + +271 +00:23:27,290 --> 00:23:30,430 +O على سبيل المثال يعني لو تخيلنا هذه C double bond + +272 +00:23:30,430 --> 00:23:34,650 +Y هي C double bond O هيضيف بالتأكيد هذا ال Ion + +273 +00:23:34,650 --> 00:23:44,140 +السالب و يعمل Y minus الآن أو O minus ال Y minus + +274 +00:23:44,140 --> 00:23:48,520 +وين تسكيرة مباشرة على ال C بتصير C double bond N + +275 +00:23:48,520 --> 00:23:57,360 +مع H واضح طبعا هنا عمل أول إيش الإغلاق و بعدين جاب + +276 +00:23:57,360 --> 00:24:03,240 +ال hydrogen بحيث إن هذه إيش هتصفى هو المحصلة + +277 +00:24:03,240 --> 00:24:09,800 +الموجودة لـ isonitrile C double bond NH وجنبها + +278 +00:24:09,800 --> 00:24:18,500 +نوكليوفيل هذي أصلها N triple bond C وهي ال Y هو + +279 +00:24:18,500 --> 00:24:24,180 +إيش للنوكليوفيل ال Y هو للنوكليوفيل + +280 +00:24:26,960 --> 00:24:30,920 +الحقيقة هذا النوع من الأمثلة كتير موجود .. كتير + +281 +00:24:30,920 --> 00:24:37,800 +موجود زي أمثلة لاحظوا مثلا ICH2 Isonitril جنب + +282 +00:24:37,800 --> 00:24:43,520 +التوسيل الآن الـ TS ما نفعش ككيميائيين تقرؤوها إيش؟ + +283 +00:24:43,520 --> 00:24:49,960 +TS إيش لازم تقرؤوها؟ توسيل المفروض الكيميائي يتذكر + +284 +00:24:49,960 --> 00:24:57,700 +التوسيل group أخذنا مجموعات توسيل و بروسل و ميسل و + +285 +00:24:57,700 --> 00:25:02,900 +تريفل في الـ organic إيه اللي هي التلوين اللي عليه + +286 +00:25:02,900 --> 00:25:10,380 +S double bond O double bond O مش كل مرة بدناها + +287 +00:25:10,380 --> 00:25:16,800 +بارا تلوين سالفونك أسد توسيل و لو كان بروم بروسل + +288 +00:25:16,800 --> 00:25:23,760 +الخلاصة هدول بيساعدوا في ثابت إيش الشحنة السالبة + +289 +00:25:23,760 --> 00:25:27,600 +اللي بده تتكون هنا عشان هيك الميثيلين جروب اللي + +290 +00:25:27,600 --> 00:25:32,420 +جنب الـ isonitrile والتوسيل لاحظوا كيف المنطق لما + +291 +00:25:32,420 --> 00:25:36,980 +الإنسان بده يفهم أنه هنا بده يتكون أيون سالب وهدي + +292 +00:25:36,980 --> 00:25:42,720 +activated مثيلين جروب لأنه جنبها مجموعة ممكن + +293 +00:25:42,720 --> 00:25:46,840 +الأيون السالب اللي بتكون يصيله stabilization بال + +294 +00:25:46,840 --> 00:25:50,840 +resonance ولذلك اطلعوا الـ base اللي استعملها + +295 +00:25:54,100 --> 00:25:59,880 +بوتاسيوم كربونيت weak base إيش السبب إنه قدر + +296 +00:25:59,880 --> 00:26:04,780 +يستعمل weak base إنه جنب الـ Tussle group إنه لما + +297 +00:26:04,780 --> 00:26:09,200 +يتكون الأيون السالب عنده اللي بعدين بيخليها + +298 +00:26:09,200 --> 00:26:12,360 +جمع الدهايد أو كيتون هذا الأيون السالب is stabilized + +299 +00:26:12,360 --> 00:26:15,680 +by the Tussle group stabilized through resonance + +300 +00:26:15,680 --> 00:26:21,350 +ولذلك في منطق في الكلام لما استعمل الـ weak base + +301 +00:26:21,350 --> 00:26:26,930 +الآن خلاه يهاجم على الـ الديهايد طبعا بإمكانكوا + +302 +00:26:26,930 --> 00:26:32,170 +انتوا تتخيلوا أنه هنا صار عندنا أيون سالب هاجم وين + +303 +00:26:32,170 --> 00:26:39,070 +على الـ الديهايد الكاربون الـ O صارت O minus في + +304 +00:26:39,070 --> 00:26:44,550 +مرحلتها الأولى O minus يعني الآن الـ O minus مباشرة + +305 +00:26:44,550 --> 00:26:52,180 +وين بدها تروح؟ على الـ carbon تصير عنده CH مع double + +306 +00:26:52,180 --> 00:26:58,700 +bond N وبتيعلي هذا المثال تماما زي المثال السابق + +307 +00:26:58,700 --> 00:27:02,680 +هذا المثال تماما زي المثال السابق هنا بدو يصير + +308 +00:27:02,680 --> 00:27:06,340 +عندكم الـ minus بدو يهاجم على الـ carbon لما يكون C + +309 +00:27:06,340 --> 00:27:10,640 +double bond N من الـ positive الـ C ولا الـ N + +310 +00:27:16,280 --> 00:27:20,040 +بالتالي الآن هذه لما يتحرك زوج الإلكترونات شو + +311 +00:27:20,040 --> 00:27:26,580 +بتصفى الآن الـ minus مباشرة مرة ثانية على C ايزو + +312 +00:27:26,580 --> 00:27:29,560 +نيترال سايكلايزيشن + +313 +00:27:34,470 --> 00:27:41,170 +هي مثال ثالث واستعمل هنا له strong base طبعا ممكن + +314 +00:27:41,170 --> 00:27:45,470 +واحدة تسأل ليش استعمل strong base أنا ما عنديش جواب + +315 +00:27:45,470 --> 00:27:51,070 +ليش؟ لأن نفس المثال هذا بـ weak base بيمشي حاله لأن + +316 +00:27:51,070 --> 00:27:56,330 +الـ sodium hydrate is a very strong base يعني الـ + +317 +00:27:56,330 --> 00:28:03,200 +sodium hydrate هذا كـ base ما بنقدرش احنا حتى + +318 +00:28:03,200 --> 00:28:08,460 +نستعمله .. بنقدرش نستعمله في الهواء يعني عادة لو + +319 +00:28:08,460 --> 00:28:13,160 +احنا عرضناه للهواء هيتفاعل مع الميه اللي موجودة في + +320 +00:28:13,160 --> 00:28:17,840 +الهواء ياخذ منها بروتون وتفاعل بحرارة شديدة + +321 +00:28:17,840 --> 00:28:22,260 +وبالتالي ممكن يولع يعني لو أنا باخد منه و بوزنه + +322 +00:28:22,260 --> 00:28:27,500 +بالهواء العادي بالذات في مناطق رطبة زي جو غزة قريب + +323 +00:28:27,500 --> 00:28:32,890 +من البحر لو أنا بستعمل الـ sodium hydrate و بوزنه + +324 +00:28:32,890 --> 00:28:37,470 +عادي زي البودرة زي السكر هيتفاعل من كتر ما هو + +325 +00:28:37,470 --> 00:28:41,230 +strong base مع الميه يسحب منها proton و تفاعل طارد + +326 +00:28:41,230 --> 00:28:47,250 +للحرارة ممكن إنه يعني يولع أو يشتعل نار و كتير من + +327 +00:28:47,250 --> 00:28:50,490 +الـ hydrates يعني هذه الصفة بتاعة دي are very + +328 +00:28:50,490 --> 00:28:54,350 +strong bases ولذلك الـ sodium hydrate غالبا لما + +329 +00:28:54,350 --> 00:28:59,540 +بالباع بالباع كـ oil suspension إيش معنى oil + +330 +00:28:59,540 --> 00:29:04,520 +suspension؟ يعني بتتخيلوا بالظبط زي ما تيجي تحطوا + +331 +00:29:04,520 --> 00:29:10,560 +سكر ونكون حاطينه في جلب زيت أو ملح أحيانا في جلب + +332 +00:29:10,560 --> 00:29:15,820 +زيت، هل الملح هيكون دايب في الزيت أو السكر هيدوب + +333 +00:29:15,820 --> 00:29:21,360 +في الزيت؟ لكن الزيت بيعمل طبقة حماية له من أنه + +334 +00:29:21,360 --> 00:29:25,520 +يتعرض لإيش؟ من أنه يتعرض للميه فالإنسان لما بيطول + +335 +00:29:25,520 --> 00:29:29,720 +منه بيطول مع الزيت وبيكون محسوب جداش نسبة الزيت + +336 +00:29:29,720 --> 00:29:33,180 +بمعنى اللي بيوزن مثلا من الـ sodium hydrate one + +337 +00:29:33,180 --> 00:29:38,380 +gram بيوزن الـ sodium hydrate بما أحاط فيه من إيش؟ + +338 +00:29:38,380 --> 00:29:42,440 +من زيت الآن حسب المكتوب على العبوة هو بيعرف أنه لو + +339 +00:29:42,440 --> 00:29:48,000 +وزن one gram من هذا المركب حقيقة نفترض فيه point + +340 +00:29:48,000 --> 00:29:53,140 +three gram زيت و point seven gram من الـ sodium + +341 +00:29:53,140 --> 00:29:57,100 +hydrate فاللي بيوزن one gram من الـ oil suspension + +342 +00:29:57,100 --> 00:30:01,260 +بيكون عارف إنه مش كله sodium hydrate جزء منه + +343 +00:30:01,260 --> 00:30:05,060 +sodium hydrate وجزء منه .. هذه كلها مهارات يعني + +344 +00:30:05,060 --> 00:30:10,820 +الأصل وين الإنسان بتمر عليه في المختبر طبعا ليش + +345 +00:30:10,820 --> 00:30:15,570 +استعمل هنا strong base أقل تقدير أنا ما عنديش جواب + +346 +00:30:15,570 --> 00:30:20,470 +لأنه ربما الـ weak base ممكن تقوم بهذا العمل + +347 +00:30:20,470 --> 00:30:26,330 +الخلاصة تكون عندنا هنا الـ ion السالب تكون عندنا + +348 +00:30:26,330 --> 00:30:32,410 +هنا الـ ion السالب الآن لاحظوا يوم ما أصير أحكي على + +349 +00:30:32,410 --> 00:30:36,950 +سيضة بالـ bond C يوم أصير أحكي على c double bond c + +350 +00:30:36,950 --> 00:30:42,390 +بتبدأ تصير شوية غلبة في الجواب أو شوية انتباه + +351 +00:30:42,390 --> 00:30:46,130 +لأكثر من احتمال يعني لما هنا في التلت حالات أنا + +352 +00:30:46,130 --> 00:30:50,750 +كونت أيون ثاند، مظبوط ولا لأ؟ اه، الآن لما كان على + +353 +00:30:50,750 --> 00:30:56,070 +c double bond o الهجوم على الـ c تأكيد لما كان على + +354 +00:30:56,070 --> 00:31:01,030 +C double bond N الهجوم على الـ C تأكيدا واضح لأن + +355 +00:31:01,030 --> 00:31:04,410 +الـ carbon is more positive الآن لما يكون C double + +356 +00:31:04,410 --> 00:31:09,550 +bond C هل يترى الهجوم على هذا الـ carbon ولا على + +357 +00:31:09,550 --> 00:31:14,810 +هذا الـ carbon؟ طبعا إذا هجم هنا هذا زوج الإلكترونات + +358 +00:31:14,810 --> 00:31:19,430 +هييجي على هذا الـ C يخليها minus وهذا اللي هو منفذه + +359 +00:31:21,160 --> 00:31:25,100 +الهجوم تمها هيزوج الإلكترونات يجي على هذه الـ C + +360 +00:31:25,100 --> 00:31:30,700 +صارت minus فلاحظوا أنا إيش عندكم R1 C الـ CH هذه + +361 +00:31:30,700 --> 00:31:36,040 +صارت minus طبعا الآن لو كان بده يكون الهجوم بطريقة + +362 +00:31:36,040 --> 00:31:41,100 +ثانية على هذه الـ carbon هيطلق ناتج ثاني إنه بده + +363 +00:31:41,100 --> 00:31:43,920 +يهجم على هذه الـ carbon هذه الـ C بده تصير minus + +364 +00:31:46,400 --> 00:31:50,900 +ما بقدرش أنا أقول إنه مش مستقري يعني هو الآن كتب + +365 +00:31:50,900 --> 00:31:56,480 +الناتج اللي طلع معه حسب التجربة لكن لو أنا باجي + +366 +00:31:56,480 --> 00:32:01,180 +بسأل هذا السؤال في الامتحان بالتأكيد هتكون صيغة + +367 +00:32:01,180 --> 00:32:05,980 +السؤال اكتب two possible products اكتب two + +368 +00:32:05,980 --> 00:32:09,440 +possible products الـ product الأول إنه هذا هجم هنا + +369 +00:32:09,440 --> 00:32:13,460 +والسيادة صارت minus وكملت الإغلاق والاحتمال الثاني + +370 +00:32:13,460 --> 00:32:17,820 +إن هذا هجم هنا والـ C هذه صارت minus وكمل إغلاق + +371 +00:32:17,820 --> 00:32:21,860 +ولذلك خلوه homework معكم إنه ارسموا الـ second + +372 +00:32:21,860 --> 00:32:26,220 +possible product يعني دائما احنا اتعودنا في هذا + +373 +00:32:26,220 --> 00:32:32,660 +المساق إنه نتخيل إنه في عندنا أكثر من احتمال ممكن + +374 +00:32:32,660 --> 00:32:37,160 +ونفكر بأكثر من اتجاه الآن إن هالتجربة في النهاية + +375 +00:32:37,160 --> 00:32:40,460 +طلعت هذا الاحتمال على العين والرأس لكن السؤال قبل + +376 +00:32:40,460 --> 00:32:47,230 +ما احنا نعمل التجربة ما عارفين ولذلك القصح إنه أنا + +377 +00:32:47,230 --> 00:32:50,450 +لو بدي أعمل هذا التفاعل إن أحط الاحتمالين بعدين + +378 +00:32:50,450 --> 00:32:55,210 +بيجيني الـ spectroscopic evidence الـ IR الـ NMR كذا + +379 +00:32:55,210 --> 00:33:00,570 +كذا بقعد اطلع في اتنين مين من هدول بتفق مع الناتج + +380 +00:33:00,570 --> 00:33:06,050 +اللي طلع عندي و بالمناسبة الـ two products are + +381 +00:33:06,050 --> 00:33:12,860 +isomers و structural isomers انتبهوا معاي لما نقول + +382 +00:33:12,860 --> 00:33:17,140 +two products are isomers، معناه ذلك لو إنسان بده + +383 +00:33:17,140 --> 00:33:21,480 +يعتمد مثلا على الـ mass spectrometer بشكل أساسي على + +384 +00:33:21,480 --> 00:33:25,380 +الـ molecular ion، مش هيقدر يفرق بينهم، التانين + +385 +00:33:25,380 --> 00:33:32,520 +بيعطوا نفس الـ molecular ion بيك الاتنين بيعطوا نفس + +386 +00:33:32,520 --> 00:33:35,560 +الـ molecular ion بيك طبعا في كل أحوال وأنا في + +387 +00:33:35,560 --> 00:33:39,980 +مرحلة تالية بحذف إيش الـ two cell group في مرحلة + +388 +00:33:39,980 --> 00:33:43,140 +تالية بحذف الـ two cell group يمكن حذف الـ two cell + +389 +00:33:43,140 --> 00:33:48,340 +خلى المركب symmetric بحيث إنه ما فرجش أي ناتج و + +390 +00:33:48,340 --> 00:33:54,120 +ربما لما تستكملوا الجواب على الآخر تلاحظوا إنه + +391 +00:33:54,120 --> 00:33:59,740 +هيطلع عندكم نفس الناتج مصادفة في هذا المثال واضح؟ + +392 +00:33:59,740 --> 00:34:03,460 +يعني في هذا المثال مصادفة ليش؟ لأن المجموعة اللي + +393 +00:34:03,460 --> 00:34:07,880 +هنا اللي هي الـ two cell حذفت لكن لو عنده مجموعات + +394 +00:34:07,880 --> 00:34:12,980 +إضافية هيكون فكرة الـ two possible products تبقى + +395 +00:34:12,980 --> 00:34:20,740 +موجودة عندكم واضح؟ جربوا اعملوا الناتج وشوفوا شو + +396 +00:34:20,740 --> 00:34:24,040 +اللي بيطلع عندكم طبعا ما علينا إن الـ two cell is + +397 +00:34:24,040 --> 00:34:28,890 +a good leaving group صحيح ولا لأ؟ ليش؟ لأن أنا + +398 +00:34:28,890 --> 00:34:35,410 +stabilized by resonance هذه الأمثلة كلها تقريبا + +399 +00:34:35,410 --> 00:34:41,290 +بنفس الفكرة ربما ما نمرش عليها كلها نمر على اثنين + +400 +00:34:41,290 --> 00:34:45,970 +أو ثلاثة يعني في هذا المثال نفس فكرة CH2 وين بدها + +401 +00:34:45,970 --> 00:34:50,990 +تهاجم؟ على الـ carbon تحت الـ C double bond S اللي + +402 +00:34:50,990 --> 00:34:55,270 +هو carbon disulfide صار عند S minus وين بده يسكر؟ + +403 +00:34:56,230 --> 00:35:04,310 +على هذا الموقع لو طلعنا على المركب الأخير phenyl + +404 +00:35:04,310 --> 00:35:11,790 +CH2NCl استعمل بيوتيل ليثيام which is a strong base + +405 +00:35:11,790 --> 00:35:18,020 +لاحظوا هنا استعمل organic base weak base طبعا اللي + +406 +00:35:18,020 --> 00:35:22,920 +بيعمل التجربة في غالب الأحوال خلينا نقول بيكون جرب + +407 +00:35:22,920 --> 00:35:26,720 +أكثر من شغل ولاجة إنه أفضل شيء إنه يستعمل أشياء + +408 +00:35:26,720 --> 00:35:32,120 +معينة ومرات اللي بيصير إنه ممكن الإنسان يستعمل + +409 +00:35:32,120 --> 00:35:37,220 +حاجة قوية لأنها متوفرة وسهلة لكن لو جرب يستعمل + +410 +00:35:37,220 --> 00:35:42,350 +أشياء أضعف ربما تمشي معاه أيضا في التفاعل واضح؟ + +411 +00:35:42,350 --> 00:35:47,470 +احنا الآن بناخد مبادئ لما انتوا تنتقلوا لمرحلة + +412 +00:35:47,470 --> 00:35:52,330 +العمل ربما تلاقوا إن انتوا عشان تفهموا هذا التفاعل + +413 +00:35:52,330 --> 00:35:55,290 +وتعملوا optimization يعني تشوفوا إيش أنسب شروط + +414 +00:35:55,290 --> 00:35:59,290 +يمكن تقعدوا شهور انتوا اتعدوا مرة حرارة كذا مرة + +415 +00:35:59,290 --> 00:36:01,690 +باستعمال هذه الـ base مرة باستعمال هذه الـ base مرة + +416 +00:36:01,690 --> 00:36:05,970 +باستعمال الـ base ثانية في النهاية إلى أنكم تصلوا + +417 +00:36:05,970 --> 00:36:10,070 +للي بيسموه الـ optimum conditions يعني أفضل + +418 +00:36:10,070 --> 00:36:16,190 +الشروط واضح الفكرة العامة طبعا base والـ base إيش + +419 +00:36:16,190 --> 00:36:21,780 +هتاخدو إبراطور من هنا وتعمل عند الـ minus الآن + +420 +00:36:21,780 --> 00:36:26,120 +بهذا المثال يمكن اللي مكتوب غلط هو اللي موجود فين + +421 +00:36:26,120 --> 00:36:31,320 +الـ NCS اللي بتوافق مع الناتج طبعا هذا إيش اسم المركز + +422 +00:36:31,320 --> 00:36:36,980 +فين الـ Isothiocyanate يعني فين الـ N double bond C + +423 +00:36:36,980 --> 00:36:42,050 +double bond S هيك شكله فنل single bond N double + +424 +00:36:42,050 --> 00:36:46,630 +bond C double bond S فنل ايزو ثيو سيانات طبعا + +425 +00:36:46,630 --> 00:36:50,830 +الفنل ايزو ثيو سيانات اللي بده يتم فيه الهجوم على + +426 +00:36:50,830 --> 00:36:57,750 +أي ذرة الكربون، الكربون very Electrophilic + +427 +00:36:57,750 --> 00:37:03,030 +Highly Electrophilic Atom لأن بين سلفر وبين + +428 +00:37:03,030 --> 00:37:07,330 +نيتروجين وبالتالي هذا الكربون موجه بكتير. الآن لما + +429 +00:37:07,330 --> 00:37:12,570 +يتم الهجوم زي هيك ممكن نتخيل أن هذا اتي عمل عندنا + +430 +00:37:12,570 --> 00:37:19,990 +H أو نتخيل أن اتي هنا عمل عندنا S minus الآن + +431 +00:37:19,990 --> 00:37:23,490 +لاحظوا أن جنب الكربون كمن يوكليوفين + +432 +00:37:25,760 --> 00:37:30,600 +الاثنين يعني هذه الحركة منطقية و كتير بتصير مع الـ + +433 +00:37:30,600 --> 00:37:34,620 +Isocyanates أن الإضافة تصفأ على هذه الكربون و + +434 +00:37:34,620 --> 00:37:39,160 +يصير عنده Single bond and etch أو على هذه لو قلنا + +435 +00:37:39,160 --> 00:37:42,180 +بس بدنا حركة الإلكترون بمعنى السالب ممكن يصير على + +436 +00:37:42,180 --> 00:37:46,940 +الـ نيتروجين ممكن يصير على الـ Sulfur بتفكروا دائما + +437 +00:37:46,940 --> 00:37:52,900 +بأكثر من احتمال الآن اللي موجود أنه صار على الـ سلفر + +438 +00:37:52,900 --> 00:37:56,680 +اللي موجود أنه صار على الـ سلفر، السلفر بشكل عام is + +439 +00:37:56,680 --> 00:38:01,180 +more nucleophilic than نيتروجين okay الآن والـ سلفر + +440 +00:38:01,180 --> 00:38:06,480 +سكر هنا أعطانا هذا الناتج الـ Isothiazone لكن هذا + +441 +00:38:06,480 --> 00:38:12,720 +ما بيمنعش .. هذا ما بيمنعش أن نظريا كان بالإمكان أنكم + +442 +00:38:12,720 --> 00:38:17,140 +تخلوا الهجوم أو الحركة هذه على الـ Nitrogen بمعنى + +443 +00:38:17,140 --> 00:38:23,860 +أن هذه تكون N minus حملة فينيل وهنا تكون C double + +444 +00:38:23,860 --> 00:38:31,220 +bond S فجربوا أنكم تكتبوا الـ Product الثاني اتخلص + +445 +00:38:31,220 --> 00:38:35,380 +C double bond S للخارج وهذه صارت N minus الـ N + +446 +00:38:35,380 --> 00:38:42,000 +minus سكرت على الكربون اللي هذا احتمال جدير جدا + +447 +00:38:42,000 --> 00:38:47,200 +بأن ينتبه له واضح؟ ليش؟ لأن صح الهجوم تم على + +448 +00:38:47,200 --> 00:38:50,740 +الكربون لأن الكربون جمها كم الـ Nucleophile + +449 +00:38:50,740 --> 00:38:54,100 +السلفر هو الـ Nucleophile والنيتروجين هو الـ + +450 +00:38:54,100 --> 00:38:58,680 +Nucleophile فمن ناحية نظرية الباحث ممكن نقول بهذا + +451 +00:38:58,680 --> 00:39:05,180 +الشكل يكتمل الـ Cyclization على I على ثيازول على + +452 +00:39:05,180 --> 00:39:10,300 +ثيازول عفوا إذا قلنا I على ثيازول this is ثيازول + +453 +00:39:10,300 --> 00:39:16,350 +أو لو تحركت بهذا الشكل والـ Nitrogen اللي هاجى و + +454 +00:39:16,350 --> 00:39:20,390 +ما عمل الـ Cyclization شو بيكون الناتج اميدازول + +455 +00:39:20,390 --> 00:39:27,570 +جربوا برضه في هذا المثال أنكم ترسموا الناتج الثاني + +456 +00:39:27,570 --> 00:39:32,550 +المتوقع دائما بدنا نعود أيدينا كل شيء بإمكاننا + +457 +00:39:32,550 --> 00:39:36,270 +نعمله الآن في المحاضرة لكن اللي بفيد الطالب في هذه + +458 +00:39:36,270 --> 00:39:41,920 +المراحل أن إيده تكتب كتير خلينا نقول هذه الأمثلة + +459 +00:39:41,920 --> 00:39:46,820 +شبيهة تماما في الموضوع تبعنا وبالتالي بإمكانكم + +460 +00:39:46,820 --> 00:39:53,160 +أيضا تتدربوا عليها بشكل جيد وبهيك بننهي موضوع + +461 +00:39:53,160 --> 00:39:57,720 +الإضافة للـ Triple bonds Carbon Carbon Triple bond + +462 +00:39:57,720 --> 00:40:02,100 +Carbon Nitrogen و Nitrogen Carbon Triple bond + +463 +00:40:02,100 --> 00:40:05,720 +وبنلتقي في المحاضرة القادمة diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/2O9csqbNY1E_postprocess.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/2O9csqbNY1E_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..f17ebe85ea66ced7076f5ff69286caf748e64a7f --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/2O9csqbNY1E_postprocess.srt @@ -0,0 +1,1852 @@ +1 +00:00:21,010 --> 00:00:27,410 +بسم الله الرحمن الرحيم زي ما احنا اتفقنا انه هنركز + +2 +00:00:27,410 --> 00:00:33,470 +كثير على الطرق المختلفة لتكوين الحلقات واتكلمنا عن + +3 +00:00:33,470 --> 00:00:37,790 +تفاعلات الإبدال تفاعلات الإضافة على الروابط + +4 +00:00:37,790 --> 00:00:42,810 +الزوجية بأنواعها المختلفة و بعدين بدأنا بتفاعلات + +5 +00:00:42,810 --> 00:00:49,390 +الإضافة علىالروابط الثلاثية وبدأنا نتكلم عن ال + +6 +00:00:49,390 --> 00:00:52,550 +carbon ال triple bond carbon في المرة الماضية + +7 +00:00:52,550 --> 00:00:56,690 +وقلنا ان هنا الإضافة غالبا بتحتمل الاحتمالين + +8 +00:00:56,690 --> 00:01:01,230 +وشوفنا أمثلة بتحتمل ال exocyclization و ال + +9 +00:01:01,230 --> 00:01:05,940 +endocyclizationالان من أمثلة ال triple bonds + +10 +00:01:05,940 --> 00:01:10,520 +المهمة جدا و اللي بتتكرر كثير الحقيقة في ال + +11 +00:01:10,520 --> 00:01:15,020 +organic synthesis اللي هي الإضافة على ال C triple + +12 +00:01:15,020 --> 00:01:20,320 +bond ان يعني هذا تفاعل شهير جدا لازم إيدكوا تتدرب + +13 +00:01:20,320 --> 00:01:26,450 +عليهأنا بأكد إن حتى مساحة هذا التفاعل لأنه مهم لا + +14 +00:01:26,450 --> 00:01:30,530 +يمكن إنها تقل بمجمع الامتحانات اللي أنا بسأل فيها + +15 +00:01:30,530 --> 00:01:35,330 +ربما عن عشرة في المية من علامة الامتحان من علامة + +16 +00:01:35,330 --> 00:01:40,330 +المساقل كله ولذلك عليكم أنكم إيش تتدربوا على هذا + +17 +00:01:40,330 --> 00:01:40,790 +التفاعل + +18 +00:01:46,070 --> 00:01:52,110 +طبعا هذا cyclization جميل وسهل الآن الاحتمال فيه + +19 +00:01:52,110 --> 00:01:58,910 +تقريبا احتمال واحد لان الكربون بشكل عام is more + +20 +00:01:58,910 --> 00:02:02,190 +positive than the nitrogen واضح هذا الكلام من ال + +21 +00:02:02,190 --> 00:02:05,610 +electronegativity فهي ال electrophilic center + +22 +00:02:05,610 --> 00:02:08,470 +وبالتالي لو تخيلنا مثال زي هذا ان في عند + +23 +00:02:08,470 --> 00:02:13,540 +نيوكليوفايل بده يهاجم وين هيكون الهجوم؟عال carbon + +24 +00:02:13,540 --> 00:02:20,200 +وبالتالي نوع ال cyclization is a exocyclization + +25 +00:02:20,200 --> 00:02:23,180 +هذا شيء متفق عليه الآن لما بيصير هذا ال + +26 +00:02:23,180 --> 00:02:27,720 +exocyclization وزوج الإلكترونات بتحرك هنا على ال N + +27 +00:02:27,720 --> 00:02:32,860 +هذه طبعا زي عمليات الإضافة بتصير N minus بتاخد H + +28 +00:02:32,860 --> 00:02:38,760 +بتصفى NH يعني هيصير عندى C double bond NH هنا تمت + +29 +00:02:38,760 --> 00:02:43,720 +عملية الإضافةيعني الإضافة على الرابطة الزوجية أنه + +30 +00:02:43,720 --> 00:02:47,680 +الرابطة الزوجية تصير أحدية أفقد by bond الإضافة + +31 +00:02:47,680 --> 00:02:51,020 +على الرابطة الثلاثية أنه الرابطة الثلاثية تصير + +32 +00:02:51,020 --> 00:02:54,720 +تنائية وأعمل two new sigma bonds أنا عملتهم هاي + +33 +00:02:54,720 --> 00:02:58,100 +sigma bond وهاي sigma bond فهذا التفاعل كتصنيف + +34 +00:02:58,100 --> 00:03:04,240 +يصنف إيش؟ تفاعل إضافة هذا الناتج اللي اتكون عندى + +35 +00:03:04,240 --> 00:03:09,040 +اللي هو c double bond and h هذا احنا بنصنفه ايمين + +36 +00:03:09,990 --> 00:03:14,310 +اسمه emine الان ال emines بشكل عام بتعمل + +37 +00:03:14,310 --> 00:03:17,950 +tautomerism تقريبا زي ال tautomerism اللي + +38 +00:03:17,950 --> 00:03:24,590 +اتعلمتوها لل keto enol tautomerism فبتعمل enamine + +39 +00:03:24,590 --> 00:03:31,720 +بمعنى بتنتقلهيدروجين من هذا الموقع هنا لو بدنا + +40 +00:03:31,720 --> 00:03:36,020 +نيجي نتطلع هذه الاتش بتنتقل إلى هنا والرابطة + +41 +00:03:36,020 --> 00:03:40,820 +بتنتقل لحظة حركة إلكترونات وحركة ذرات حركة + +42 +00:03:40,820 --> 00:03:45,340 +إلكترونات وحركة ذرات إذا أنا هنا بتكلم عن إيش؟ + +43 +00:03:45,340 --> 00:03:49,980 +بتكلم عن tautomerism لإن ال tautomerism إلكتروناتو + +44 +00:03:49,980 --> 00:03:53,680 +ذرات البروتونز بتتحرك طبعا هذا ال توتو ميريزم + +45 +00:03:53,680 --> 00:03:59,320 +بنسميه احنا امين انامين توتو ميريزم بفترض انه مرت + +46 +00:03:59,320 --> 00:04:05,560 +عليكم زي ما مر عليكم الكيتو اينول واضح؟ الان في + +47 +00:04:05,560 --> 00:04:09,180 +الامين انامين توتو ميريزم ال more stable بشكل عام + +48 +00:04:09,180 --> 00:04:13,360 +product is the amineعكس ال keto و ال anal يعني لو + +49 +00:04:13,360 --> 00:04:17,800 +انا كنت بده اتخيل هدول موازين ل ال keto و ال anal + +50 +00:04:17,800 --> 00:04:21,800 +tautomerism بقول هي ال ketone وطفر وهي ال anal + +51 +00:04:23,550 --> 00:04:27,130 +كيتوينو التوتوميرزم في الاليفانتيك كومباونز التي + +52 +00:04:27,130 --> 00:04:29,270 +هي أكتر مستقل الكيتون + +53 +00:04:54,900 --> 00:05:01,120 +CNH2 و بنطلب من الإنسان انه اعملنا تحضير لهذا + +54 +00:05:01,120 --> 00:05:05,040 +المركب يعني لو شفتوا مثل هذا المنظر و قولنا لكوا + +55 +00:05:05,040 --> 00:05:08,060 +اعملوا تحضير لهذا المركب بتكونوا تفكروا ب retro + +56 +00:05:08,060 --> 00:05:12,840 +synthesis ع طول بتكونوا تتخيلوا ان هذه كانت C + +57 +00:05:12,840 --> 00:05:17,300 +triple bond N طبعا من واي بدأ أكثر من جنبها من هذا + +58 +00:05:17,300 --> 00:05:21,240 +الموقع ولا من هذا اكيد من الموقع اللي فيه ال + +59 +00:05:21,240 --> 00:05:25,950 +nucleophileيعني انا قولت ان هذه كانت هي قبوحانة اي + +60 +00:05:25,950 --> 00:05:30,950 +رابط الاتكوانات هذه ولا هذه اكيد هذه واضح وبالتالي + +61 +00:05:30,950 --> 00:05:35,570 +بقدر ارجع بسهولة لهذا المركب يعني قلتلكوا اعملولي + +62 +00:05:35,570 --> 00:05:39,610 +retro synthesis لهذا المركب بتقدر تخيلوا هاي ال + +63 +00:05:39,610 --> 00:05:44,170 +Nucleophile ال CNH2 اللي جنب ال double bond بمعنى + +64 +00:05:44,170 --> 00:05:50,810 +اخر ال enamine أصلهاnight trial C triple bond N + +65 +00:05:50,810 --> 00:05:56,090 +واضح؟ وهذا مثال بتشوفوه كتير، الآن ممكن بأحوال + +66 +00:05:56,090 --> 00:06:02,550 +معينة، ممكن بأحوال معينة أن الأمور تقف هنا، ممكن، + +67 +00:06:02,550 --> 00:06:07,260 +لو ماكنش فيها هيدروجين، تعمل هاتوتو بريزلواضح؟ + +68 +00:06:07,260 --> 00:06:12,120 +ممكن أن أقف عند الإيمين موجود لكن المشهور طالما + +69 +00:06:12,120 --> 00:06:15,600 +هالهيدروجي اللي بتعمل تاوتومينزم موجودة أن التفاعل + +70 +00:06:15,600 --> 00:06:21,260 +بيستمر أكثر الآن في مرات كثيرة لما يكون هذا الكلام + +71 +00:06:21,260 --> 00:06:26,150 +مش ممكن، يعني أقف عند الإيمينبدي يكون جزء من + +72 +00:06:26,150 --> 00:06:29,610 +الكيميا العادية اللى مرت عليكوا بحياتكوا ان هدولا + +73 +00:06:29,610 --> 00:06:35,070 +ال emens they are unstable فمرات كثيرة هتلاحظوا + +74 +00:06:35,070 --> 00:06:40,840 +انه بتحولوا الى C double bond Oكتير هتلاحظوا أن + +75 +00:06:40,840 --> 00:06:44,880 +الأشياء اللي ممكن تصفي E means ال E means they are + +76 +00:06:44,880 --> 00:06:48,620 +unstable فضمن acidic conditions أو basic + +77 +00:06:48,620 --> 00:06:51,840 +conditions موجودة في التفاعل هتلاحظوا أنه بدل ما + +78 +00:06:51,840 --> 00:06:58,200 +هي E mean إيش اللي كتبت في ال product النهائيواضح؟ + +79 +00:06:58,200 --> 00:07:02,500 +اللي هو amine hydrolysis amine hydrolysis ان ال + +80 +00:07:02,500 --> 00:07:06,680 +amine هذا ممكن مات لقوا لو صار ايش C double point + +81 +00:07:06,680 --> 00:07:11,980 +O بالذات لو كانش بيمكنه يعمل التوتوميريزم كل هذا + +82 +00:07:11,980 --> 00:07:19,390 +الكلام بتشوفوه وخلينا الآن نشوف بعض الأمثلة علىهذه + +83 +00:07:19,390 --> 00:07:23,810 +الفكرة فكرة الـ cyclization على ال night trials لو + +84 +00:07:23,810 --> 00:07:28,150 +احنا اتينا و اتطلعنا على هذا المثال و خلطناه + +85 +00:07:28,150 --> 00:07:31,870 +مركبين الان هنا في عندنا good leaving group اللي + +86 +00:07:31,870 --> 00:07:37,990 +هي ال ethoxy group مع ال NH2 هذا ال NH2 بتهاجم و + +87 +00:07:37,990 --> 00:07:43,550 +بتحل محل ال ethoxy group لاحظوا هذا الجزء من الجزء + +88 +00:07:43,550 --> 00:07:44,450 +اللي هو R + +89 +00:07:47,080 --> 00:07:51,560 +CNHCN محطوط في الدائرة لحظة انا حاطيته في الدائرة + +90 +00:07:51,560 --> 00:07:55,940 +عشان تعرفوا الجزئين الان انا صار عندي C triple + +91 +00:07:55,940 --> 00:08:01,590 +bond N whatever الان هي نيكليوفايل وهيC triple + +92 +00:08:01,590 --> 00:08:05,250 +bond N تانية المفروض ان هذا الينيو كل يو فايل بده + +93 +00:08:05,250 --> 00:08:11,130 +يهاجم على هذه C triple bond N في النهاية بده يصف + +94 +00:08:11,130 --> 00:08:15,850 +ايش N H 2 ويعمل double bond يعني اول ما بده يهاجم + +95 +00:08:15,850 --> 00:08:22,530 +بهذا الشكل هتصير double bond N H لان هنا في عندى C + +96 +00:08:22,530 --> 00:08:29,890 +H مجاورة وبالتالي اطول بتصير هذه N H 2و double + +97 +00:08:29,890 --> 00:08:36,090 +bond هنا حضرنا اميدازول واضح هنا حضرنا اميدازول + +98 +00:08:36,090 --> 00:08:39,970 +فالمثال المقصود بالنسبة لنا مش الخطوة الأولى + +99 +00:08:39,970 --> 00:08:44,270 +الخطوة الأولى تجهيز لكن خطوة ال cycleization اللى + +100 +00:08:44,270 --> 00:08:48,290 +فيها nucleophile هاجم على C triple bond أنها + +101 +00:08:48,290 --> 00:08:49,490 +ولاحظوا + +102 +00:08:52,440 --> 00:08:56,180 +هذه دائما الان اتش تو اللي جمد بالبند اللي هي + +103 +00:08:56,180 --> 00:09:01,940 +الانامين هي نتاج الإغلاق على C triple bond N فاين + +104 +00:09:01,940 --> 00:09:07,140 +بتشوفوا الانامين تفكيركم ان هذه أصلا كانت C triple + +105 +00:09:07,140 --> 00:09:12,980 +bond N الآن + +106 +00:09:12,980 --> 00:09:18,060 +هنا في عندي أمثلة إضافية لو اتطلعنا مثلا على هذا + +107 +00:09:18,060 --> 00:09:23,240 +المثال عندي activated methylene groupسي اتش تو + +108 +00:09:23,240 --> 00:09:28,400 +جمتن تان سي دابل بوند ان هذا ال مالوني ترايل زي ال + +109 +00:09:28,400 --> 00:09:32,200 +مالونيك إيستر يعني ال CH2 هنا بتكون إيش highly + +110 +00:09:32,200 --> 00:09:36,960 +activated وبالتالي ال base حتى ضعيفة ممكن تسحب و + +111 +00:09:36,960 --> 00:09:42,600 +ممكن تهاجم هنا على سي دابل بوند or كيتون اللي هنا + +112 +00:09:42,600 --> 00:09:44,120 +يعني لاحظوا هذا الجزء + +113 +00:09:46,880 --> 00:09:50,500 +اللي هو C متصل فيها تنتين CNN هو هذا الجزء اللي + +114 +00:09:50,500 --> 00:09:55,940 +حطناه بدائرة الآن هنا كان عندنا C double bond O + +115 +00:09:55,940 --> 00:10:00,500 +لما بده يتم عليها الإضافة من CH ماينوس شو بده تصير + +116 +00:10:00,500 --> 00:10:05,380 +OH okay عملنا الجزء الأول هي الرابطة الجديدة اللي + +117 +00:10:05,380 --> 00:10:10,760 +احنا عملناها بينهم هذه الرابطة الجديدة الآن الخطوة + +118 +00:10:10,760 --> 00:10:15,320 +اللي بتهمنا خطوة الcycleization ال nucleophile + +119 +00:10:15,320 --> 00:10:22,510 +موجودو C triple bond N موجودة هتعمل ايمين و تحول + +120 +00:10:22,510 --> 00:10:29,470 +الى انامين و طبعا اكيد ال O اتش اللي هنا ما اتش من + +121 +00:10:29,470 --> 00:10:36,910 +هنا هتحدث مية واضح فبطلع عندى by role derivative + +122 +00:10:36,910 --> 00:10:41,210 +بطلع عندى by role derivative لحظة ان التفاعلات + +123 +00:10:41,210 --> 00:10:44,230 +تفاعلات بسيطة التفاعل أول addition على C triple + +124 +00:10:44,230 --> 00:10:49,780 +bond Oكخطوة تحضيرية والتفاعل التاني Cyclization + +125 +00:10:49,780 --> 00:10:53,160 +على C triple bond N + +126 +00:10:59,510 --> 00:11:06,670 +المثال التاني هنا لدي ثيويوريا C double bond S NH2 + +127 +00:11:06,670 --> 00:11:12,150 +NH2 ثيويوريا هذه ثيويوريا لما تتفاعل على فين ال CH + +128 +00:11:12,150 --> 00:11:17,690 +PR CN لاحظوا هنا ال PR is a good leaving group + +129 +00:11:17,690 --> 00:11:22,250 +يعني ممكن بالخطوة الأولى يصير عندى substitution + +130 +00:11:22,250 --> 00:11:30,360 +فانا لو اتيت اتطلعت هنالاحظوا معايا ان ال نيتروجين + +131 +00:11:30,360 --> 00:11:35,880 +هم اليوكليوفايل و السلفر كمان اليوكليوفايل و مرات + +132 +00:11:35,880 --> 00:11:41,540 +كتير لما بلتقى السلفر و النيتروجين السلفر اقوى انه + +133 +00:11:41,540 --> 00:11:45,800 +يتفاعل كنيوكليوفايل ولذلك التفاعل هنا تم من خلال + +134 +00:11:45,800 --> 00:11:51,320 +ايش السلفر يعني هذا الجزء هو الثيويوريا اللى + +135 +00:11:51,320 --> 00:11:56,830 +موجودة هناهذا اللي كان C double bond S N H 2 N H 2 + +136 +00:11:56,830 --> 00:12:02,090 +طبعا بإحدى صوره ممكن تتخيلوا S H double bond N H + +137 +00:12:02,090 --> 00:12:08,250 +مش صعب إطلاقا نتخيله الآن السلفر هاجم طرد إيش ال + +138 +00:12:08,250 --> 00:12:14,570 +PR هى عندى فين ال C H C triple bond N هذا الجزء + +139 +00:12:14,570 --> 00:12:19,190 +موجود وهي الجزء الثيويوريا اتفاعلت من خلال إيش + +140 +00:12:19,830 --> 00:12:24,830 +السلفر دائما .. دائما .. لما بيلتقي عندكوا سلفر و + +141 +00:12:24,830 --> 00:12:30,650 +نيتروجين كنيوكليوفايل فاكروا كتير ان السلفر بنافس + +142 +00:12:30,650 --> 00:12:38,170 +النيتروجين وبقوة .. وبقوة على انه يعني يتفاعل + +143 +00:12:38,170 --> 00:12:43,610 +كنيوكليوفايل الان بعد هيك ال N-H و C-Triple bond N + +144 +00:12:43,610 --> 00:12:47,870 +شو بده تصير ال C-Triple bond N في النهاية N-H2 + +145 +00:12:47,870 --> 00:12:53,710 +Enamineبإمكاننا نفصلها خلاص احنا صرنا متفقين انه + +146 +00:12:53,710 --> 00:12:59,090 +الـ C triple point N بتصيرانامين واضح هاي الانامين + +147 +00:12:59,090 --> 00:13:04,650 +موجود بهذا الشكل بتم عملية ال cycleization في هذا + +148 +00:13:04,650 --> 00:13:10,450 +المثال بتايع ليه لو بتتابعوا أيضا الأمثلة التانية + +149 +00:13:10,450 --> 00:13:17,350 +كلها بنفس المنطق يعني هنا بتفقد عند مجموعة O إثل + +150 +00:13:17,350 --> 00:13:22,250 +بيشبكوا هدول الجزيئين بإمكاننا ان نفرجيكم ان هذا + +151 +00:13:22,250 --> 00:13:29,610 +الجزءالـ CNCH2 NH2 اللى اتفاعل من خلال هذه + +152 +00:13:29,610 --> 00:13:35,670 +النيتروجين طرد O إثل منها بمعنى هذه الجزء هذا + +153 +00:13:35,670 --> 00:13:43,630 +الأزرقCN CH2 NH طرد ال O إثل و أعطانا C double + +154 +00:13:43,630 --> 00:13:49,570 +bond NH CO2 إثل الآن هي ال نيوكليوفايل وهي ال CN + +155 +00:13:49,570 --> 00:13:53,850 +شو اللي هتشوفه هناك بدون ما نطلع انامين هاي + +156 +00:13:53,850 --> 00:14:00,880 +الانامين واضح؟ هاي الانامينهذه الأمثلة إلا الإنسان + +157 +00:14:00,880 --> 00:14:06,200 +يعني نفسه يتدرب عليها بالجلم للرصاص و بالورقة لحد + +158 +00:14:06,200 --> 00:14:11,780 +ما يتقن إجراء التفاعل على ال night trials و زي ما + +159 +00:14:11,780 --> 00:14:16,200 +قلنا هذا تفاعل شهير دائما لما تشوفوا ال amino + +160 +00:14:16,200 --> 00:14:20,380 +group جنب ال double bond جزء من تفكيركوا في ال + +161 +00:14:20,380 --> 00:14:25,020 +synthesis للمركب بده يروح لإيش لأنه كان أصلها + +162 +00:14:25,020 --> 00:14:31,100 +night trial كان أصلها night trialالان بيجينا + +163 +00:14:31,100 --> 00:14:34,940 +cyclization تاني شبيه في هذا ال cyclization + +164 +00:14:34,940 --> 00:14:40,520 +cyclization onto ايزو نيترالات لاحظوا ال ايزو + +165 +00:14:40,520 --> 00:14:45,240 +نيترالات اللي هم ماخدين الصيغة العامة R N triple + +166 +00:14:45,240 --> 00:14:51,140 +bond C ال نيترالات R C triple bond N هنا انعكسوا + +167 +00:14:51,140 --> 00:14:54,440 +الذرات بمعنى هنا ال نيتروجين هنا الكربون ال + +168 +00:14:54,440 --> 00:14:59,370 +نيترالات C triple bond N الايزو نيترالاتand triple + +169 +00:14:59,370 --> 00:15:04,650 +bond C الان ال isonitriles طبعا لها resonance + +170 +00:15:04,650 --> 00:15:09,290 +structures منها ان هذي الكربون تكون سالب او هذي ال + +171 +00:15:09,290 --> 00:15:13,130 +نيتروجين تكون موجبة و ممكن resonance structure + +172 +00:15:13,130 --> 00:15:20,090 +تاني متعادل بشكل عام التفاعل على ال isonitrile انا + +173 +00:15:20,090 --> 00:15:26,190 +بحطه هنا عشان نتعلم كيف نفذه التفاعل دائما يتم على + +174 +00:15:26,190 --> 00:15:31,480 +الكربونالتفاعل دائما يتم على الكربون والـ + +175 +00:15:31,480 --> 00:15:37,460 +cyclization is endocyclization واضح؟ بمعنى لو + +176 +00:15:37,460 --> 00:15:41,120 +اتخيلت ان هاي عندى هنا ايزو نيترال يمكن البعض + +177 +00:15:41,120 --> 00:15:45,100 +يستغرب شوية انه بده يقول النيوكليوفال بده يهاجم + +178 +00:15:45,100 --> 00:15:49,940 +على minus يعني minus على minus لكن مابديش أنسى انه + +179 +00:15:49,940 --> 00:15:55,490 +في resonance structures مش minusواضح؟ يعني معظم + +180 +00:15:55,490 --> 00:15:58,310 +الكتب لما بتكتب ما بتحطش هذا resonance structure + +181 +00:15:58,310 --> 00:16:04,690 +بتحط زي هيك وبالتالي بيبدأ الطالب يتحير ان هو أخذ + +182 +00:16:04,690 --> 00:16:09,530 +قواعد عامة انه لأ ال minus بده يروح على موجب لأ لأ + +183 +00:16:09,530 --> 00:16:13,290 +ما هو في هنا resonance structure بيكون متعادل مش + +184 +00:16:13,290 --> 00:16:19,000 +..مش minus لذلك التفاعل دائما وين بده يكون على ال + +185 +00:16:19,000 --> 00:16:22,880 +carbon اللي هنا طبعا لما بده يتم التفاعل هذا زوج + +186 +00:16:22,880 --> 00:16:27,100 +الإلكترونات في نهاية بده يصفه CH هذا زوج + +187 +00:16:27,100 --> 00:16:29,400 +الإلكترونات بده يصفه .. يعني لما أنا بده أعمل + +188 +00:16:29,400 --> 00:16:33,920 +رابطة هنا مع ال oxygen هذا زوج الإلكترونات بده يصف + +189 +00:16:33,920 --> 00:16:37,720 +إيش CH بمعنى جزء ال isonitry الحيون + +190 +00:16:40,700 --> 00:16:44,260 +لاحظوا طلعنا شوية برا الشاشة لكن اللي بدو يصير + +191 +00:16:44,260 --> 00:16:50,860 +موجود عندي هنا على هذه النقطة إيش CH + +192 +00:16:50,860 --> 00:16:57,020 +اللي بدو يصير موجود عندي CH على أساس أن ال H هذه + +193 +00:16:57,020 --> 00:17:02,280 +بدأ تيجي هنا بدل زوج الألكترونات لأنه مش هتبقى C + +194 +00:17:02,280 --> 00:17:08,140 +minus لما بدنا نعمل رابطة فبناء على ذلك دائما لما + +195 +00:17:08,140 --> 00:17:13,110 +احنا بنشوفمثل هذا المنظر الآن الناس اللي بدهم + +196 +00:17:13,110 --> 00:17:17,290 +يفكروا بال retro synthesis يعني يتخيلوا انهم بدهم + +197 +00:17:17,290 --> 00:17:23,310 +يحضروا هينيوكليوفايل بعدين CN لاحظوا النيوكليوفايل + +198 +00:17:23,310 --> 00:17:28,210 +CNN مباشرة بإمكانكوا تصيروا تتخيلوا ان هذه ال CNN + +199 +00:17:28,210 --> 00:17:31,250 +كانت ايزونيترال + +200 +00:17:32,070 --> 00:17:36,230 +يعني الـ Eucleophile شابك بـ C double bond N + +201 +00:17:36,230 --> 00:17:42,970 +فبتكون إيش أصلها؟ Isonitrile والحقيقة أنه يعني + +202 +00:17:42,970 --> 00:17:48,810 +موجود أنفلة كتير أنفلة كتير على ال cyclization على + +203 +00:17:48,810 --> 00:17:56,630 +ال isonitrile على سبيل المثال هذا المركبلاحظوا في + +204 +00:17:56,630 --> 00:17:59,490 +هذا المُركّب عند الـ isonitrile عارف إن الـ + +205 +00:17:59,490 --> 00:18:03,110 +cyclisation بدو يصير على الكربون تصير double bond + +206 +00:18:03,110 --> 00:18:06,370 +CH cyclisation بدو يصير على الكربون تصير double + +207 +00:18:06,370 --> 00:18:11,730 +bond CH هنا استعمل CH2 جنبها R و double bond + +208 +00:18:11,730 --> 00:18:17,610 +لاحظوا إن هذه CH2 مش activated methylene group أو + +209 +00:18:17,610 --> 00:18:21,130 +مش highly activated methylene group لكن الكيميا + +210 +00:18:21,130 --> 00:18:27,180 +لتعرفالمستحيل يعني ليش احنا بنقول انه في عندنا + +211 +00:18:27,180 --> 00:18:31,630 +base اقوى من base و بندرس ال strength of basesيوم + +212 +00:18:31,630 --> 00:18:34,390 +ما يكون عندى ال Malonic Easter بال Sodium + +213 +00:18:34,390 --> 00:18:37,130 +Carbonate ولا بالبريديل اللى هي ال bases اللى + +214 +00:18:37,130 --> 00:18:43,270 +ضعيفة بشيل منه ال protons بينما أشياء صعبة بصير + +215 +00:18:43,270 --> 00:18:46,510 +استعمل لها ال lithoxide أشياء أصعب ممكن استعمل لها + +216 +00:18:46,510 --> 00:18:52,390 +ال hydrides ممكن استعمل لها هذا المركب ال LDA هذا + +217 +00:18:52,390 --> 00:18:57,990 +ال LDA اللى هو Lithium Dioisopropyl Amideهذا + +218 +00:18:57,990 --> 00:19:01,090 +المركب الاصلي تكونوا يمكن مار عليكوا او من اليوم + +219 +00:19:01,090 --> 00:19:05,870 +تتعلموا lithium diisopropyl amine هذا المركب + +220 +00:19:05,870 --> 00:19:10,990 +commonly abbreviated LDA is a chemical compound + +221 +00:19:10,990 --> 00:19:16,530 +with this formula اهم شغله فيه it is used as a + +222 +00:19:16,530 --> 00:19:22,210 +strong baseيعني وين بنشوفه و بنقول عنه ايش strong + +223 +00:19:22,210 --> 00:19:26,830 +base lithium diisopropyl amide طالما strong base + +224 +00:19:26,830 --> 00:19:32,070 +هيشتغل على أي هيدروجيل اللي موجودة هنا هيعمل ال + +225 +00:19:32,070 --> 00:19:36,730 +carbon enucleophile in this case واضح؟ عمل في هذه + +226 +00:19:36,730 --> 00:19:41,070 +الحالة ال carbon enucleophile الآن ببساطة احنا + +227 +00:19:41,070 --> 00:19:44,630 +قلنا تنفيذ الإغلاق كيف ال enucleophile على ال + +228 +00:19:44,630 --> 00:19:51,480 +carbon بتصير double bond و CHواضح؟ للـ nucleophile + +229 +00:19:51,480 --> 00:19:55,600 +هجومه على الكربون و بتصير ال triple bond و double + +230 +00:19:55,600 --> 00:20:03,140 +bond و CH هذا مثال أعطانا in those derivatives هذا + +231 +00:20:03,140 --> 00:20:06,560 +المثال أعطانا in those derivatives و الكربون + +232 +00:20:06,560 --> 00:20:14,120 +المستعمل كان هو لل nucleophile لاحظوا يمكن تلاحظوا + +233 +00:20:14,120 --> 00:20:19,920 +كمان ملاحظة ان هو استعمل ايشناقص تمانية وسبعين + +234 +00:20:19,920 --> 00:20:24,500 +درجة مئوية كما يبدو عشان يقدر يسيطر هذا ال + +235 +00:20:24,500 --> 00:20:27,920 +condition المناسب يمكن البعض يجي يتساءل ليش ناقص + +236 +00:20:27,920 --> 00:20:32,200 +تمانية وسبعين ليش ما كانت ناقص تمانين ولا ناقص + +237 +00:20:32,200 --> 00:20:40,200 +خمسة وسبعين يعني هي التمانية وسبعين مقدسة واضح؟ + +238 +00:20:40,200 --> 00:20:45,200 +الآن كثير من المعادلات بحياتكوا هتلاحظوا أنه + +239 +00:20:45,200 --> 00:20:51,530 +بتنعمل عند ناقص تمانية وسبعينتمام ال 78 مش مقدسة + +240 +00:20:51,530 --> 00:20:58,430 +لكن في وسيلة تبريد سهلة للي بده تبريد كتير هذه + +241 +00:20:58,430 --> 00:21:02,770 +الوسيلة بتعطي ناقص 78 فهو باستعمل يعني مش فارق + +242 +00:21:02,770 --> 00:21:06,230 +كتير كان لو بده يكون ناقص 80 ولا ناقص 70 ولا ناقص + +243 +00:21:06,230 --> 00:21:11,570 +85 لكن وسيلة التبريد اللي درجة وموجودة في + +244 +00:21:11,570 --> 00:21:16,680 +المختبرات بسهولةلهذا ال range من التبريد ابتعد + +245 +00:21:16,680 --> 00:21:24,700 +تناقص 78 هذه وسيلة التبريد شو هي الاسمها + +246 +00:21:24,700 --> 00:21:30,940 +ال dry ice لأ ال نيتروجين السائل بنزلكوا لناقص 150 + +247 +00:21:30,940 --> 00:21:36,920 +و ناقص 200 ال liquid nitrogen بنزل لناقص 200 كتير + +248 +00:21:38,040 --> 00:21:43,040 +لكن ال dry ice اللي هو عبارة عن ثاني أكسيد الكربون + +249 +00:21:43,040 --> 00:21:47,040 +في الحالة الصلبة بيكون موجود بتلجات في المختبرات + +250 +00:21:47,040 --> 00:21:51,080 +زي التلج اللي بينباع هذا في التلاجات بياخدوا قطع + +251 +00:21:51,080 --> 00:21:53,920 +منه و بيحطوه حوالين التفاعل أو بيحطوها ب solvent + +252 +00:21:53,920 --> 00:22:02,080 +فهذا عادة بيعطي حرارة ناقص 78 فممكن في المستقبل + +253 +00:22:02,080 --> 00:22:08,040 +تسمعوا البني آدم اللي بيشرح مثل هذا التفاعللما بده + +254 +00:22:08,040 --> 00:22:12,220 +يحكي هو الواحد بده يفهم مصطلحات العلم تبعه يعني + +255 +00:22:12,220 --> 00:22:16,640 +بده يجي يقول انه this reaction using a strong base + +256 +00:22:16,640 --> 00:22:21,600 +in a dry ice شوف كيف الكيميا اللي بده يتكلمبديوش + +257 +00:22:21,600 --> 00:22:24,660 +يقول lithium di isopropyl amide lithium di + +258 +00:22:24,660 --> 00:22:28,700 +isopropyl amide finally is a strong base ناقص + +259 +00:22:28,700 --> 00:22:32,960 +تمانية وسبعين is a dry ice فبتلاقي الواحد لما + +260 +00:22:32,960 --> 00:22:36,840 +بيحكي بيقول using a strong base in a dry ice + +261 +00:22:36,840 --> 00:22:42,460 +produces the carbanion which attacks the + +262 +00:22:42,460 --> 00:22:46,640 +isonitrile and cyclosis to endure واضحة هذه + +263 +00:22:46,640 --> 00:22:47,260 +الفكرة؟ + +264 +00:22:52,680 --> 00:23:00,300 +هنا مثال تاني هي isonitrile جنبها CH2 لاحظوا هذه + +265 +00:23:00,300 --> 00:23:03,680 +الأمثلة كتير مشهورة في isonitrile cyclization ان + +266 +00:23:03,680 --> 00:23:08,760 +نجيب مركبات ال isonitrile جنبها CH2 ال CH2 اللي + +267 +00:23:08,760 --> 00:23:12,160 +جنب ال isonitrile is activated methylene group + +268 +00:23:12,160 --> 00:23:16,860 +وبناء على ذلك لو احنا استعملنا base لو احنا + +269 +00:23:16,860 --> 00:23:22,530 +استعملنا base هتسحب منها بروتون هتكون عندكالـ Ion + +270 +00:23:22,530 --> 00:23:27,290 +السالب هذا ممكن يضيف على مراكبات زي C double bond + +271 +00:23:27,290 --> 00:23:30,430 +O على سبيل المثال يعني لو تخيلنا هذه C double bond + +272 +00:23:30,430 --> 00:23:34,650 +Y هي C double bond O هيضيف بالتأكيد هذا ال Ion + +273 +00:23:34,650 --> 00:23:44,140 +السالب و يعمل Y minusالان أو O minus ال Y minus + +274 +00:23:44,140 --> 00:23:48,520 +وين تسكيرة مباشرة على ال C بتصير C double bond N + +275 +00:23:48,520 --> 00:23:57,360 +مع H واضح طبعا هنا عمل أول إش الإغلاق و بعدين جاب + +276 +00:23:57,360 --> 00:24:03,240 +ال hydrogen بحيث أنه هذه إش هتصفىهو المحصلة + +277 +00:24:03,240 --> 00:24:09,800 +الموجودة لـ isonitrile C double bond NH وجنبها + +278 +00:24:09,800 --> 00:24:18,500 +نيوكليوفايل هذي أصلها N triple bond C وهي ال Y هو + +279 +00:24:18,500 --> 00:24:24,180 +أيش للنيوكليوفايل ال Y هو للنيوكليوفايل + +280 +00:24:26,960 --> 00:24:30,920 +الحقيقة هذا النوع من الأمثلة كتير موجود .. كتير + +281 +00:24:30,920 --> 00:24:37,800 +موجود زي أمثلة لاحظوا مثلا ICH2 Isonitril جنب + +282 +00:24:37,800 --> 00:24:43,520 +التوسيل الان ال TS مانفعش ككيميائيين تقرؤوها ايش؟ + +283 +00:24:43,520 --> 00:24:49,960 +TS ايش لازم تقرؤوها؟ توسيل المفروض الكيميائي يتذكر + +284 +00:24:49,960 --> 00:24:57,700 +التوسيل group أخدنا مجموعاتتوسل و بروسل و ميسل و + +285 +00:24:57,700 --> 00:25:02,900 +تريفل في ال organic ايه اللي هي التلوين اللي عليه + +286 +00:25:02,900 --> 00:25:10,380 +S double bond O double bond O مش كل مرة بدناه + +287 +00:25:10,380 --> 00:25:16,800 +بارا تلوين سالفونك أسد توسل و لو كان بروم بروسل + +288 +00:25:16,800 --> 00:25:23,760 +الخلاصة هدولة بيساعدوا في ثابت إيشالشحنة السالبة + +289 +00:25:23,760 --> 00:25:27,600 +اللى بده تتكون هان عشان هيك الميثيلين جروب اللى + +290 +00:25:27,600 --> 00:25:32,420 +جنب ال isonitrile والتوسل لاحظوا كيف المنطق لما + +291 +00:25:32,420 --> 00:25:36,980 +الإنسان بده يفهم أنه هان بده يتكون ايون سالب وهدي + +292 +00:25:36,980 --> 00:25:42,720 +activated مثيلين جروب لأنه جنبها مجموعة ممكن + +293 +00:25:42,720 --> 00:25:46,840 +الايون السالب اللى بتكون يصيله stabilization بال + +294 +00:25:46,840 --> 00:25:50,840 +resonance ولذلك اطلعوا ال base اللى استعملها + +295 +00:25:54,100 --> 00:25:59,880 +بوتاسيوم كربونيت weak base إيش السبب إنه قدر + +296 +00:25:59,880 --> 00:26:04,780 +يستعمل weak base إنه جنب الـTussle group إنه لما + +297 +00:26:04,780 --> 00:26:09,200 +يتكون الأيون السالب عنده اللي بعدين بيخليها + +298 +00:26:09,200 --> 00:26:12,360 +جمعالدهاد أو كيتون هذا الأيون السالب is stabilized + +299 +00:26:12,360 --> 00:26:15,680 +by the Tussle group stabilized through resonance + +300 +00:26:15,680 --> 00:26:21,350 +ولذلك في منطق في الكلام لما استعملالـ weak base + +301 +00:26:21,350 --> 00:26:26,930 +الآن خلّاه يهاجم على ال الديهايد طبعا بإمكانكوا + +302 +00:26:26,930 --> 00:26:32,170 +انتوا تتخيلوا انه هنا صار عندنا ايون سالب هاجم وين + +303 +00:26:32,170 --> 00:26:39,070 +على ال الديهايد الكاربون ال O صارت O minus في + +304 +00:26:39,070 --> 00:26:44,550 +مرحلتها الأولى O minus يعني الآن ال O minus مباشرة + +305 +00:26:44,550 --> 00:26:52,180 +وين بدها تروحعال carbon تصير عنده CH مع double + +306 +00:26:52,180 --> 00:26:58,700 +bond N وبتيعلي هذا المثال تماما زي المثال السابق + +307 +00:26:58,700 --> 00:27:02,680 +هذا المثال تماما زي المثال السابق هنا بدو يصير + +308 +00:27:02,680 --> 00:27:06,340 +عندكم ال minus بدو يهاجم عال carbon لما يكون C + +309 +00:27:06,340 --> 00:27:10,640 +double bond N من ال positive ال C ولا ال N + +310 +00:27:16,280 --> 00:27:20,040 +بالتالي الان هذه لما يتحرك زوج الالكترونات شو + +311 +00:27:20,040 --> 00:27:26,580 +بتصفه الان ال minus مباشرة مرة تانية على C ايزو + +312 +00:27:26,580 --> 00:27:29,560 +نيترال سايكلايزيشن + +313 +00:27:34,470 --> 00:27:41,170 +هي مثال تالت واستعمل هنا له strong base طبعا ممكن + +314 +00:27:41,170 --> 00:27:45,470 +واحدة تسأل ليش استعمل strong base أنا ماعنديش جواب + +315 +00:27:45,470 --> 00:27:51,070 +ليش لأن نفس المثال هذا ب weak base بيمشي حاله لأن + +316 +00:27:51,070 --> 00:27:56,330 +ال sodium hydrate is a very strong base يعني ال + +317 +00:27:56,330 --> 00:28:03,200 +sodium hydrate هذا ك baseما بنقدرش احنا حتى + +318 +00:28:03,200 --> 00:28:08,460 +نستعمله .. بنقدرش نستعمله في الهواء يعني عادة لو + +319 +00:28:08,460 --> 00:28:13,160 +احنا عرضنا لهواء هيتفاعل مع الميه اللي موجودة في + +320 +00:28:13,160 --> 00:28:17,840 +الهواء ياخد منها بروتل وتفاعل بحرارة شديدة + +321 +00:28:17,840 --> 00:28:22,260 +وبالتالي ممكن يولع يعني لو انا باخد منه و بوزنه + +322 +00:28:22,260 --> 00:28:27,500 +بالهواء العادي بالذات في مناطق رطبة زي جو غزة قريب + +323 +00:28:27,500 --> 00:28:32,890 +من البحرلو أنا بستعمل ال sodium hydrate و بوزنه + +324 +00:28:32,890 --> 00:28:37,470 +عادي زي البودرة زي السكر هيتفاعل من كتر ما هو + +325 +00:28:37,470 --> 00:28:41,230 +strong base مع الميه يسحب منها proton و تفاعل طارد + +326 +00:28:41,230 --> 00:28:47,250 +للحرارة ممكن انه يعني يولع او يشتعل نار و كتير من + +327 +00:28:47,250 --> 00:28:50,490 +ال hydrates يعني هذا الصفة بتاعة دي are very + +328 +00:28:50,490 --> 00:28:54,350 +strong bases ولذلك ال sodium hydrate غالبا لما + +329 +00:28:54,350 --> 00:28:59,540 +بالباع بالباع ك oil suspensionإيش معنى oil + +330 +00:28:59,540 --> 00:29:04,520 +suspension؟ يعني بتتخيلوا بالظبط زي ما تيجي تحطوا + +331 +00:29:04,520 --> 00:29:10,560 +سكر و نكون حاطينه في جلب زيت أو ملح أحيانا في جلب + +332 +00:29:10,560 --> 00:29:15,820 +زيت، هل الملح هيكون دايب في الزيت أو السكر هيدوب + +333 +00:29:15,820 --> 00:29:21,360 +في الزيت؟لكن الزيت بيعمل طبقة حماية له من أنه + +334 +00:29:21,360 --> 00:29:25,520 +يتعرض لإيش؟ من أنه يتعرض للميه فالإنسان لما بيطول + +335 +00:29:25,520 --> 00:29:29,720 +منه بيطول مع الزيت و بيكون محسوب جداش نسبة الزيت + +336 +00:29:29,720 --> 00:29:33,180 +بمعنى اللي بيوزن مثلا من ال sodium hydrate one + +337 +00:29:33,180 --> 00:29:38,380 +gram بيوزن ال sodium hydrate بما أحاط فيه من إيش؟ + +338 +00:29:38,380 --> 00:29:42,440 +من زيت الآن حسب المكتوب على العبو هو بيعرف أنه لو + +339 +00:29:42,440 --> 00:29:48,000 +وزن one gramمن هذا المركب حقيقة نفترض فيه point + +340 +00:29:48,000 --> 00:29:53,140 +three gram زيت و point seven gram من ال sodium + +341 +00:29:53,140 --> 00:29:57,100 +hydrate فال بيوزان one gram من ال oil suspension + +342 +00:29:57,100 --> 00:30:01,260 +بيكون عارف انه مش كله sodium hydrate جزء منه + +343 +00:30:01,260 --> 00:30:05,060 +sodium hydrate و جزء منه .. هذه كلها مهارات يعني + +344 +00:30:05,060 --> 00:30:10,820 +الاصل وين الإنسان بتمر عليه في المختبر طبعا ليش + +345 +00:30:10,820 --> 00:30:15,570 +استعمل هنا strong baseأقل تقدير أنا ماعنديش جواب + +346 +00:30:15,570 --> 00:30:20,470 +لأنه ربما ال weak base ممكن تقوم بهذا العمل + +347 +00:30:20,470 --> 00:30:26,330 +الخلاصة اتكون عندنا هنا ال ion السالب اتكون عندنا + +348 +00:30:26,330 --> 00:30:32,410 +هنا ال ion السالب الان لاحظوا يوم ما أصير أحكي على + +349 +00:30:32,410 --> 00:30:36,950 +سيضة بال bond Cيوم أصير أحكي على c double bond c + +350 +00:30:36,950 --> 00:30:42,390 +بتبدأ تصير شوية غلبة في الجواب أو شوية انتباه + +351 +00:30:42,390 --> 00:30:46,130 +لأكتر من احتمال يعني لما هنا في التلت حالات أنا + +352 +00:30:46,130 --> 00:30:50,750 +كونت ايون ثاند، مظبوط ولا لأ؟ اه، الان لما كان على + +353 +00:30:50,750 --> 00:30:56,070 +c double bond o الهجوم على ال c تأكيدالما كان على + +354 +00:30:56,070 --> 00:31:01,030 +C double bond N الهجوم على الـ C تأكيدا واضح لأن + +355 +00:31:01,030 --> 00:31:04,410 +ال carbon is more positive الان لما يكون C double + +356 +00:31:04,410 --> 00:31:09,550 +bond C هل يترى الهجوم على هذا ال carbon و لا على + +357 +00:31:09,550 --> 00:31:14,810 +هذا ال carbon طبعا إذا هجم هنا هذا زوج الإلكترونات + +358 +00:31:14,810 --> 00:31:19,430 +هيجي على هذا ال C يخليها minus وهذا اللي هو منفذه + +359 +00:31:21,160 --> 00:31:25,100 +الهجوم تمها هيزوج الالكترونات يجي على هذه الـ C + +360 +00:31:25,100 --> 00:31:30,700 +صارت minus فلاحظوا انا ايش عندكم R1 C الـ CH هذه + +361 +00:31:30,700 --> 00:31:36,040 +صارت minus طبعا الان لو كان بده يكون الهجوم بطريقة + +362 +00:31:36,040 --> 00:31:41,100 +تانية على هذه ال carbon هيطلق نتج تاني انه بده + +363 +00:31:41,100 --> 00:31:43,920 +يهجم على هذه ال carbon هذه ال C بده تصير minus + +364 +00:31:46,400 --> 00:31:50,900 +ما بقدرش انا اقول انه مش مستقري يعني هو الان كتب + +365 +00:31:50,900 --> 00:31:56,480 +الناتج اللي طلع معه حسب التجربة لكن لو انا باجي + +366 +00:31:56,480 --> 00:32:01,180 +بسأل هذا السؤال في الامتحان بالتأكيد هتكون صيغة + +367 +00:32:01,180 --> 00:32:05,980 +السؤال اكتب two possible products اكتب two + +368 +00:32:05,980 --> 00:32:09,440 +possible products ال product الأول انه هذا هجم هن + +369 +00:32:09,440 --> 00:32:13,460 +والسيادة صارت minus وكملت الإغلاق والاحتمال التاني + +370 +00:32:13,460 --> 00:32:17,820 +انه هذا هجم هنوالـ C هذه صارت minus وكمل إغلاق + +371 +00:32:17,820 --> 00:32:21,860 +ولذلك خلوه homework معكم أنه ارسموا ال second + +372 +00:32:21,860 --> 00:32:26,220 +possible product يعني دائما احنا اتعودنا في هذا + +373 +00:32:26,220 --> 00:32:32,660 +المساق أنه نتخيل أنه في عندنا أكثر من احتمال ممكن + +374 +00:32:32,660 --> 00:32:37,160 +ونفكر بأكثر من اتجاه الأن ان هالتجربة في النهاية + +375 +00:32:37,160 --> 00:32:40,460 +طلعت هذا الاحتمال على العين والرأس لكن السؤال قبل + +376 +00:32:40,460 --> 00:32:47,230 +ما احنا نعمل التجربةمش عارفين و لذلك القصح انه انا + +377 +00:32:47,230 --> 00:32:50,450 +لو بدي اعمل هذا التفاعل ان احط الاحتمالين بعدين + +378 +00:32:50,450 --> 00:32:55,210 +بيجيني ال spectroscopic evidence ال IR ال NMR كذا + +379 +00:32:55,210 --> 00:33:00,570 +كذا بقعد اطلع في اتنين مين من هدولة بتفق مع الناتج + +380 +00:33:00,570 --> 00:33:06,050 +اللي طلع عندى و بالمناسبة ال two products are + +381 +00:33:06,050 --> 00:33:12,860 +isomers و structural isomers انتبهوا معايالما نقول + +382 +00:33:12,860 --> 00:33:17,140 +two products are isomers، معناه ذلك لو إنسان بده + +383 +00:33:17,140 --> 00:33:21,480 +يعتمد مثلا على ال mass spectrometer بشكل أساسي على + +384 +00:33:21,480 --> 00:33:25,380 +ال molecular ion، مش هيقدر يفرق بينهم، التانين + +385 +00:33:25,380 --> 00:33:32,520 +بيعطوا نفس ال molecular ionبيك الاتنين بيعطوا نفس + +386 +00:33:32,520 --> 00:33:35,560 +ال molecular ion بيك طبعا في كل أحوال و انا في + +387 +00:33:35,560 --> 00:33:39,980 +مرحلة تالية بحذف ايش ال two cell group في مرحلة + +388 +00:33:39,980 --> 00:33:43,140 +تالية بحذف ال two cell group يمكن حذف ال two cell + +389 +00:33:43,140 --> 00:33:48,340 +خلى المركب symmetric بحيث انه مافرجش اي ناتج و + +390 +00:33:48,340 --> 00:33:54,120 +ربما لما تستكملوا الجواب على الآخر اتلاحظوا انه + +391 +00:33:54,120 --> 00:33:59,740 +هيطلع عندكمنفس النتج مصادفة في هذا المثال واضح؟ + +392 +00:33:59,740 --> 00:34:03,460 +يعني في هذا المثال مصادفة ليش؟ لأن المجموعة اللي + +393 +00:34:03,460 --> 00:34:07,880 +هنا اللي هي ال two cell حُدفت لكن لو عنده مجموعات + +394 +00:34:07,880 --> 00:34:12,980 +إضافية هيكون فكرة ال two possible products تبقى + +395 +00:34:12,980 --> 00:34:20,740 +موجودة عندكم واضح؟ جربوا اعملوا النتج وشوفوا شو + +396 +00:34:20,740 --> 00:34:24,040 +اللي بيطلع عندكم طبعا مار علينا ان ال two cell is + +397 +00:34:24,040 --> 00:34:28,890 +a good living groupصحيح ولا لأ؟ ليش؟ لأن أنا + +398 +00:34:28,890 --> 00:34:35,410 +stabilized by resonance هذه الأمثلة كلها تقريبا + +399 +00:34:35,410 --> 00:34:41,290 +بنفس الفكرة ربما مانمرش عليها كلها نمر على مثلين + +400 +00:34:41,290 --> 00:34:45,970 +أو تلاتة يعني في هذا المثال نفس فكرة CH2 وين بدها + +401 +00:34:45,970 --> 00:34:50,990 +تهاجم؟ على ال carbon تحت ال C double bond S اللي + +402 +00:34:50,990 --> 00:34:55,270 +هو carbon disulfide صار عند S minus وين بده يسكر؟ + +403 +00:34:56,230 --> 00:35:04,310 +على هذا الموقع لو طلعنا على المركب الأخير phenyl + +404 +00:35:04,310 --> 00:35:11,790 +CH2NCl استعمل بيوتيل ليثيام which is a strong base + +405 +00:35:11,790 --> 00:35:18,020 +لاحظوا هنا استعمل organic base weak baseطبعا اللي + +406 +00:35:18,020 --> 00:35:22,920 +بيعمل التجربة في غالب الأحوال خلينا نقول بيكون جرب + +407 +00:35:22,920 --> 00:35:26,720 +أكتر من شغل ولاجة أنه أفضل شيء أنه يستعمل أشياء + +408 +00:35:26,720 --> 00:35:32,120 +معينة و مرات اللي بيصير أنه ممكن الإنسان يستعمل + +409 +00:35:32,120 --> 00:35:37,220 +حاجة قوية لأنها متوفرة وسهلة لكن لو جرب يستعمل + +410 +00:35:37,220 --> 00:35:42,350 +أشياء أضعف ربماتمشي معاه ايضا في التفاعل واضح؟ + +411 +00:35:42,350 --> 00:35:47,470 +احنا الان بناخد مبادئ لما انتوا تنتقلوا لمرحلة + +412 +00:35:47,470 --> 00:35:52,330 +العملربما تلاقوا ان انتوا عشان تفهموا هذا التفاعل + +413 +00:35:52,330 --> 00:35:55,290 +و تعملوا optimization يعني تشوفوا ايش أنسب شروط + +414 +00:35:55,290 --> 00:35:59,290 +يمكن تقعدوا شهروا انتوا اتعدوا مرة حرارة كذا مرة + +415 +00:35:59,290 --> 00:36:01,690 +باستعمال هذه ال base مرة باستعمال هذه ال base مرة + +416 +00:36:01,690 --> 00:36:05,970 +باستعمال ال base تانية في النهاية الى انكم تصلوا + +417 +00:36:05,970 --> 00:36:10,070 +لاللي بيسموه ال optimum conditions يعني افضل + +418 +00:36:10,070 --> 00:36:16,190 +الشروط واضح الفكرة العامة طبعا base و ال base ايش + +419 +00:36:16,190 --> 00:36:21,780 +هتاخدو إبراطور من هنا و تعمل عند ال minus الآن + +420 +00:36:21,780 --> 00:36:26,120 +بهذا المثال يمكن اللي مكتوب غلط هو اللي موجود فين + +421 +00:36:26,120 --> 00:36:31,320 +ال ncs اللي بتفق مع الناتج طبعا هذا إيش اسم المركز + +422 +00:36:31,320 --> 00:36:36,980 +فين ال isothiocyanate يعني فين ال n double bond c + +423 +00:36:36,980 --> 00:36:42,050 +double bond s هيك شكلهفنل single bond N double + +424 +00:36:42,050 --> 00:36:46,630 +bond C double bond S فنل ايزو ثيو سيانات طبعا + +425 +00:36:46,630 --> 00:36:50,830 +الفنل ايزو ثيو سيانات اللي بده يتم فيه الهجوم على + +426 +00:36:50,830 --> 00:36:57,750 +اي ذرة ال carbon ال carbon varyElectrophilic + +427 +00:36:57,750 --> 00:37:03,030 +Highly Electrophilic Atom لأن بين سلفر وبين + +428 +00:37:03,030 --> 00:37:07,330 +نيتروجين وبالتالي هذا الكربون موجه بكتير الان لما + +429 +00:37:07,330 --> 00:37:12,570 +يتم الهجوم زي هيك ممكن نتخيل ان هذا اتي عمل عندنا + +430 +00:37:12,570 --> 00:37:19,990 +H او اتخيل ان اتي هنا عمل عندنا S minus الان + +431 +00:37:19,990 --> 00:37:23,490 +لاحظوا ان جنب الكربون كمن يوكليوفين + +432 +00:37:25,760 --> 00:37:30,600 +الاتنين يعني هذه الحركة منطقية و كتير بتصير مع ال + +433 +00:37:30,600 --> 00:37:34,620 +isocyanates ان الإضافة تصفأ على هذه الكاربون و + +434 +00:37:34,620 --> 00:37:39,160 +يصير عنده single bond and etch او على هذه لو قلنا + +435 +00:37:39,160 --> 00:37:42,180 +بس بدنا حركة الالكترون بمعنى السلب ممكن يصير على + +436 +00:37:42,180 --> 00:37:46,940 +ال نيتروجين ممكن يصير على ال sulfur بتفكروا دائما + +437 +00:37:46,940 --> 00:37:52,900 +بأكتر من احتمال الان اللي موجود انه صار علىالسلفر + +438 +00:37:52,900 --> 00:37:56,680 +اللى موجود انه صار على السلفر السلفر بشكل عام is + +439 +00:37:56,680 --> 00:38:01,180 +more nucleophilic than نيتروجين okay الان و السلفر + +440 +00:38:01,180 --> 00:38:06,480 +سكر هنا اعطانا هذا الناتج ال isothiazone لكن هذا + +441 +00:38:06,480 --> 00:38:12,720 +مابمنعش .. هذا مابمنعش انه نظريا كان بالامكان انكم + +442 +00:38:12,720 --> 00:38:17,140 +تخلوا الهجوم او الحركة هذه على ال nitrogen بمعنى + +443 +00:38:17,140 --> 00:38:23,860 +انه هذه تكون N minusحملة فينيل وهنا تكون c double + +444 +00:38:23,860 --> 00:38:31,220 +bond s فجربوا انكم تكتبوا ال product التاني اتخلص + +445 +00:38:31,220 --> 00:38:35,380 +c double bond s للخارج وهذه صارت n minus ال n + +446 +00:38:35,380 --> 00:38:42,000 +minus سكرت على ال carbon اللي هذا احتمال جدير جدا + +447 +00:38:42,000 --> 00:38:47,200 +بأن ينتبه لهواضح؟ ليش؟ لأن صح الهجوم تم على + +448 +00:38:47,200 --> 00:38:50,740 +الكاربون لأن الكاربون جمها كام الـ nucleophile + +449 +00:38:50,740 --> 00:38:54,100 +السلفر هو ال nucleophile والنيتروجين هو ال + +450 +00:38:54,100 --> 00:38:58,680 +nucleophile فمن ناحية نظرية البحثة ممكن نقول بهذا + +451 +00:38:58,680 --> 00:39:05,180 +الشكل يكتمل ال cyclization على I على ثيازول على + +452 +00:39:05,180 --> 00:39:10,300 +ثيازول عفوا إذا قولنا I على ثيازول this is ثيازول + +453 +00:39:10,300 --> 00:39:16,350 +أو لواتحركت بهذا الشكل و ال nitrogen اللي هاجى و + +454 +00:39:16,350 --> 00:39:20,390 +ماعمل ال cyclization شو هيكون الناتج اميدازول + +455 +00:39:20,390 --> 00:39:27,570 +جربوا برضه في هذا المثال انكم ترسموا الناتج التاني + +456 +00:39:27,570 --> 00:39:32,550 +المتوقع دائما بدنا نعود إيدينا كل شيء بإمكاننا + +457 +00:39:32,550 --> 00:39:36,270 +نعمله الآن في المحاضرة لكن اللي بفيد الطالب في هذه + +458 +00:39:36,270 --> 00:39:41,920 +المراحل انه إيدهتكتب كتير خلينا نقول هذه الأمثلة + +459 +00:39:41,920 --> 00:39:46,820 +شبيهة تماما في الموضوع تبعنا وبالتالي بإمكانكم + +460 +00:39:46,820 --> 00:39:53,160 +أيضا تتدربوا عليها بشكل جيد وبهيك بننهي موضوع + +461 +00:39:53,160 --> 00:39:57,720 +الإضافة لل triple bonds carbon carbon triple bond + +462 +00:39:57,720 --> 00:40:02,100 +carbon nitrogen و nitrogen carbon triple bond + +463 +00:40:02,100 --> 00:40:05,720 +وبنلتقي في المحاضرة القادمة + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/Bir78NGXpBQ.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/Bir78NGXpBQ.srt new file mode 100644 index 0000000000000000000000000000000000000000..355a76fadc63ea87ebe56d452877ba38eef39198 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/Bir78NGXpBQ.srt @@ -0,0 +1,1115 @@ +1 +00:00:20,670 --> 00:00:25,650 +بسم الله الرحمن الرحيم اليوم إن شاء الله بدنا نكمل + +2 +00:00:25,650 --> 00:00:30,650 +في موضوع تسمية المركبات الحلقية طبعًا درسنا الأساسي + +3 +00:00:30,650 --> 00:00:35,390 +إن شاء الله هيكون عن تسمية ال-spiral heterocyclic + +4 +00:00:35,390 --> 00:00:41,100 +compounds لكن إحنا زي ما طلبنا منكم أنه ممكن تحضروا + +5 +00:00:41,100 --> 00:00:46,640 +إلنا من المجلات الحديثة مركبات نشرت حديثًا نشوف كيف + +6 +00:00:46,640 --> 00:00:52,240 +الناس سمّوا هذه المركبات كيف إحنا فعلاً هل ما تعلمنا + +7 +00:00:52,240 --> 00:00:57,480 +من تسمية يكفي لأن نسمّي المركبات بطريقة سليمة وحتى + +8 +00:00:57,480 --> 00:01:03,430 +ممكن بطريقة ناقدة بمعنى إذا هم ارتكبوا خطأ معينًا + +9 +00:01:03,430 --> 00:01:07,810 +إحنا ممكن نقول أنه في هذه المنطقة هم عملوا خطأ + +10 +00:01:07,810 --> 00:01:14,770 +معينًا الآن هذا مركب جابته زميلاتكم من مجلة Molecules + +11 +00:01:14,770 --> 00:01:21,430 +منشور بالـ 2015 يعني شيء حديث جدًا وكاتب الاسم يفترض + +12 +00:01:21,430 --> 00:01:27,090 +زي ما هو موجود في المجلة أنا شوية ملاحظ إن هي حتى + +13 +00:01:27,090 --> 00:01:33,020 +مغيرة الاسم أو محتاجة على الاسم إذا خلينا نشوف وين + +14 +00:01:33,020 --> 00:01:38,400 +يعني الإشكال هل فعلاً التسمية اللي موجودة صحيحة ولا + +15 +00:01:38,400 --> 00:01:43,880 +لأ هذا fused heterocyclic compounds كمراجعة للكلام + +16 +00:01:43,880 --> 00:01:49,240 +اللي أخذناه الآن لو كنا بنسمّي هذا المركب اللي موجود + +17 +00:01:49,240 --> 00:01:53,780 +أمامنا هلاحظ أنه إحنا بنحكي عن حلقتين هدول + +18 +00:01:53,780 --> 00:01:57,600 +الحلقتين اللي فيهم نيتروجين of the same size + +19 +00:01:57,600 --> 00:02:01,820 +اثنتين حلقات سداسية وبناءً على ذلك القاسم اللي + +20 +00:02:01,820 --> 00:02:06,600 +بينهم إن هذه الحلقة فيها أربع ذرات من النيتروجين + +21 +00:02:06,600 --> 00:02:10,740 +بينما هذه الحلقة فيها ذرتين ولاحظوا إن هذه + +22 +00:02:10,740 --> 00:02:14,780 +النيتروجين تتبع الحلقتين بناءً على ذلك الـbase + +23 +00:02:14,780 --> 00:02:21,000 +component اللي هتكون موجودة عندي هي الحلقة هذه و + +24 +00:02:21,000 --> 00:02:23,060 +لما بدي اشتغل بدي أقول إيه + +25 +00:02:26,730 --> 00:02:31,010 +BCDEF هذا بالنسبة للروابط الموجودة في الـbase + +26 +00:02:31,010 --> 00:02:35,230 +component وطبعًا واضح إنها فيها أربع ذرات نيتروجين + +27 +00:02:35,230 --> 00:02:40,450 +إذا هي تترازين هي تترازين الآن هذه الحلقة فيها + +28 +00:02:40,450 --> 00:02:43,810 +ذرتين نيتروجين على موقع واحد وثلاثة إذا هذه + +29 +00:02:43,810 --> 00:02:49,290 +الحلقة بيرمدين ولو كنا بنحط أرقام واحد اثنين ثلاثة + +30 +00:02:49,290 --> 00:02:54,310 +أربعة خمسة ستة فلو إحنا جينا في الأول نشوف الـ + +31 +00:02:54,310 --> 00:02:59,890 +fusion بأي شكل موجود هلاحظ إن الـfusion من هنا بيه + +32 +00:02:59,890 --> 00:03:07,530 +والـfusion من هنا one two فلو بدأنا بهذا الشكل + +33 +00:03:07,530 --> 00:03:11,290 +التسمية هذا التترازين لو كنا بنعطيه أرقام واحد + +34 +00:03:11,290 --> 00:03:18,890 +اثنين ثلاثة أربعة خمسة إذا هذا one two four five + +35 +00:03:18,890 --> 00:03:28,390 +تترازين الآن هذا الـone two four five تترازين عامل + +36 +00:03:28,390 --> 00:03:36,870 +fusion من الرابطة بي الآن مرتبط مع الـبيرميدين من + +37 +00:03:36,870 --> 00:03:42,110 +واحد واثنين إذا هذا هيصير بيرميدو الـبيرميدين + +38 +00:03:42,110 --> 00:03:48,690 +بيرميدو one two B one two four five تترازين هذا + +39 +00:03:48,690 --> 00:03:53,660 +اسم الحلقتين من ناحية الـfusion الآن في عندنا + +40 +00:03:53,660 --> 00:03:58,220 +substituents هذه الـsubstituents بدأت تتبع نظام + +41 +00:03:58,220 --> 00:04:03,340 +ترقيم خارجي والقاعدة الأولى في نظام الترقيم إن + +42 +00:04:03,340 --> 00:04:11,680 +يكون عنده أقل أرقام الـhetero atoms فلو أنا تحركت + +43 +00:04:11,680 --> 00:04:16,860 +من هذا الموقع لاحظوا اجمعوا معنا الـhetero atoms + +44 +00:04:16,860 --> 00:04:23,260 +من هذه النقطة كنقطة بداية هتكون على واحد واثنين و + +45 +00:04:23,260 --> 00:04:34,580 +أربعة وخمسة وتسعة وأربعة وتسعة وأربعة وتسعة + +46 +00:04:34,580 --> 00:04:35,680 +وأربعة وتسعة وأربعة وتسعة وأربعة وتسعة و + +47 +00:04:35,680 --> 00:04:42,540 +أربعة وتسعة وأربعة وتسعة وأربعة وتسعة وأربعة + +48 +00:04:43,670 --> 00:04:49,550 +ثلاثة أربعة ثلاثة + +49 +00:04:49,550 --> 00:04:55,210 +واحد اثنين ثلاثة أربعة أربعة أربعين خمسة ستة سبعة + +50 +00:04:55,210 --> 00:05:02,890 +ثمانية تسعة واضح؟ إنه الترقيم اللي أقل؟ الترقيم هذا + +51 +00:05:02,890 --> 00:05:07,190 +الترقيم هذا من ناحية الـhetero atoms طالما الـhetero + +52 +00:05:07,190 --> 00:05:11,470 +atoms عملوا فرق عندي ما بروحش أطلع على القواعد + +53 +00:05:11,470 --> 00:05:16,110 +الثانية المتعلقة بالـfusion والكربون وما إلى ذلك + +54 +00:05:16,110 --> 00:05:21,730 +واضح ولذلك بدي ألتزم بالترقيم من هنا واحد طبعًا + +55 +00:05:21,730 --> 00:05:24,990 +البعض اللي بيقول القاعدة بتقول مع قريب الساعة مش + +56 +00:05:24,990 --> 00:05:28,130 +مشكلة إحنا بنعمل flipping لهذا الجزء بنصير باللف + +57 +00:05:28,130 --> 00:05:33,270 +مع قريب الساعة هذا الكلام أضبحناه حتى لو بيّن + +58 +00:05:33,270 --> 00:05:39,350 +ظاهريًا إن أنا هنا بشتغل عكس عقارب الساعة لكن مجرد + +59 +00:05:39,350 --> 00:05:44,130 +إن أعمل للمركب vertical flipping بصير مع عقارب + +60 +00:05:44,130 --> 00:05:48,450 +الساعة بصير ماشي مع القواعد تمامًا أربعة خمسة ستة + +61 +00:05:48,450 --> 00:05:54,230 +سبعة ثمانية تسعة الآن بنقدر نحط الـsubstituents + +62 +00:05:54,230 --> 00:05:59,400 +أنا بتهيألي هيربما الأخت كانت إذا خربت في هذه + +63 +00:05:59,400 --> 00:06:04,620 +اللقطة كانت بفضل هذا الترقيم، لكن أنا لا أرى ما + +64 +00:06:04,620 --> 00:06:10,010 +أراه يعني ترقيم المجلة هو الترقيم الصح والترقيم + +65 +00:06:10,010 --> 00:06:16,090 +اللي اقترحته هي هو ترقيم إيش أعلى وإحنا بدنا نأخذ + +66 +00:06:16,090 --> 00:06:22,230 +الـhetero atoms as a set كمجموعة يكونوا إيش أقل + +67 +00:06:22,230 --> 00:06:26,950 +ترقيم واضح وبناءً على ذلك لما بنيجي نحط المجموعات + +68 +00:06:26,950 --> 00:06:31,390 +ما فيش داعي نضيع الوقت كثير هتبين الفكرة على موقع + +69 +00:06:31,390 --> 00:06:37,990 +واحد الآن هذه المجموعة إيش بدنا نسمّيها؟ بدنا نحطها + +70 +00:06:37,990 --> 00:06:45,310 +بين قوسين بترقيم ثاني two prime hydroxy phenyl two + +71 +00:06:45,310 --> 00:06:54,310 +prime hydroxy phenyl الـ a هذي أربعة H وهذي six + +72 +00:06:54,310 --> 00:06:59,970 +all بتظهر في آخر المركب هنا هيكون one H لإن هذي + +73 +00:06:59,970 --> 00:07:05,410 +saturated هنا هيكون عندي eight methyl كل هذا الكلام + +74 +00:07:05,410 --> 00:07:09,350 +بتاهية اللي بنقدر نحطه والترتيب alphabetical لو + +75 +00:07:09,350 --> 00:07:13,090 +اتطلعنا على الجزء الأخير هنلاحظ إنه هو معبر عن الـ + +76 +00:07:13,090 --> 00:07:20,330 +on في نهاية الاسم هنا كاتب six four + +77 +00:07:20,330 --> 00:07:27,490 +H on وهذا إحنا بتاهية ليه؟ أخذنا كيف نعمله الـon + +78 +00:07:27,490 --> 00:07:31,930 +على موقع الستة ووجودها هنا عمل كمان four H وهذه + +79 +00:07:31,930 --> 00:07:37,960 +بتظلها one H واضح كل هذا الكلام حط ولذلك بنلاحظ + +80 +00:07:37,960 --> 00:07:44,260 +أنه الاسم عنده three نقرأ اللي موجود three two + +81 +00:07:44,260 --> 00:07:51,600 +hydroxy phenyl eight methyl eight methyl one + +82 +00:07:51,600 --> 00:07:56,900 +phenyl one H pyrimido one two B one two four five + +83 +00:07:56,900 --> 00:08:01,200 +tetrazine six four H all + +84 +00:08:03,670 --> 00:08:09,770 +هو اللي بيستعمله هذا النظام اللي بيحطه on بيحطه + +85 +00:08:09,770 --> 00:08:14,570 +بين قوسين الـ H الأقرب عليها اللي موجودة بسببها فلما + +86 +00:08:14,570 --> 00:08:20,410 +حط six four H on ضلّ عنده إيش one H ممكن عند ناس + +87 +00:08:20,410 --> 00:08:24,870 +ثانين يتلاقوهم كتبوها بطريقة مختلفة ممكن يكتبوا + +88 +00:08:24,870 --> 00:08:33,480 +six oxo one four dihydro ممكن يكتبوا 6 oxo في مقدمة + +89 +00:08:33,480 --> 00:08:38,040 +الاسم One Four Dihydro بس واضح إن الاسم بالطريقة + +90 +00:08:38,040 --> 00:08:42,580 +اللي حكيناها سليم هذا موجود للناس اللي بحبوا + +91 +00:08:42,580 --> 00:08:50,730 +يرجعوا في مجلة Molecules سنة 2015 صفحة 2500 أي حد + +92 +00:08:50,730 --> 00:08:59,350 +بيحب يراجع المثال بيقدر يشوفه من هذه المجلة طبعًا + +93 +00:08:59,350 --> 00:09:04,090 +بالتأكيد أنا بأعتبر يعني شيء جيد بالنسبة لكم إن + +94 +00:09:04,090 --> 00:09:08,950 +تقدر تشوفوا أمثلة زي هذه أشياء ما كناش بنعرف كيف + +95 +00:09:08,950 --> 00:09:13,450 +بتتسمّى قبل أسبوعين ثلاثة قبل محاضرتين الآن يعني + +96 +00:09:13,450 --> 00:09:18,050 +الحمد لله صار في عندكم خبرة في تسمية fused + +97 +00:09:18,050 --> 00:09:22,290 +heterocyclic compounds إذا بقرأ اسم بحس إنه هذا + +98 +00:09:22,290 --> 00:09:40,210 +الاسم مش غريب بقدر إن أفهم هذا الاسم الآن + +99 +00:09:40,990 --> 00:09:46,590 +نيجي لشيء جديد في موضوع التسمية موضوع الـspiral + +100 +00:09:46,590 --> 00:09:50,490 +hetero cyclic compounds الـspiral hetero cyclic + +101 +00:09:50,490 --> 00:09:54,970 +compounds زي ما اتفقنا إن هما حلقتين بيكونوا + +102 +00:09:54,970 --> 00:09:59,520 +مشتركين بـcarbon وعادة بيكون حول الـcarbon + +103 +00:09:59,520 --> 00:10:03,560 +تتراهيدرال arrangement بهذا الشكل يعني ما بيكونوش + +104 +00:10:03,560 --> 00:10:08,560 +planar بيكونوا في تتراهيدرال arrangement بهذا + +105 +00:10:08,560 --> 00:10:14,420 +الشكل واضح؟ الآن كيف بنسمّي الـspiral heterocycle + +106 +00:10:14,420 --> 00:10:18,180 +compound لو إحنا طلعنا بالتأكيد إحنا على السبورة + +107 +00:10:18,180 --> 00:10:23,100 +بنرسمهم planar لكن كفهم في مخنا لازم يكون واضح + +108 +00:10:23,100 --> 00:10:28,140 +عندنا إن فيهم واحدة في مستوى اللوح وواحدة عمودية + +109 +00:10:28,140 --> 00:10:33,540 +على مستوى اللوح بهذا الشكل واضح؟ الآن لما نيجي + +110 +00:10:33,540 --> 00:10:38,860 +نسمّي هذه المركبات بدنا نكتب كلمة Spiral في + +111 +00:10:38,860 --> 00:10:44,760 +البداية بدنا نكتب كلمة Spiral بعد هيك بنيجي بنحط + +112 +00:10:44,760 --> 00:10:51,870 +بين قوسين في كل حلقة عدا الذرة اللي هي الـ + +113 +00:10:51,870 --> 00:10:55,670 +spiroatom الكاربون، يعني هذه الانتخابة مش موجودة، + +114 +00:10:55,670 --> 00:11:01,290 +كم ذرة يوجد عندهم؟ هنا واحد، اثنين، ثلاثة، + +115 +00:11:01,290 --> 00:11:06,070 +أربعة، هنا واحد، اثنين، ثلاثة، أربعة، خمسة فلاحظوا + +116 +00:11:06,070 --> 00:11:09,890 +الحلقة الخماسية عدى الـspiral atom فيها كم ذرة؟ + +117 +00:11:09,890 --> 00:11:14,230 +أربعة الحلقة السداسية عدى الـspiral atom فيها كم + +118 +00:11:14,230 --> 00:11:19,350 +ذرة؟ خمسة الآن بحط عدد الذرات بدون الـspiral + +119 +00:11:19,350 --> 00:11:24,990 +atom واضح؟ في عندي أربعة وخمسة مين اللي بدكره + +120 +00:11:24,990 --> 00:11:31,100 +دائمًا في الأول؟ الأصغر الأصغر فلما أنا أكتب spiro + +121 +00:11:31,100 --> 00:11:35,880 +four five four نقطة five هيك طريقة التسمية four + +122 +00:11:35,880 --> 00:11:42,820 +نقطة five على طول أي واحدة بدّي تشوف هذا الكلام واجي + +123 +00:11:42,820 --> 00:11:48,920 +أسأل السؤال على السريع هدول الحلقات إيه؟ إيش نوعهم؟ + +124 +00:11:48,920 --> 00:11:53,000 +بدّي تقرأ الأرقام اللي هنا ويزيد على كل واحد واحدة + +125 +00:11:54,380 --> 00:11:59,920 +تقول هدول حلقتين خماسية وسداسية واضح؟ لو كتبت + +126 +00:11:59,920 --> 00:12:04,280 +هنا ثلاثة وأربعة إذا أنا بحكي عن حلقتين رباعية وخماسية + +127 +00:12:04,280 --> 00:12:08,600 +دائمًا الرقم اللي هنا أقل من حجم الحلقة + +128 +00:12:08,600 --> 00:12:13,120 +بواحد لإنه لما إحنا كتبناه لغينا إيش الـspiral + +129 +00:12:13,120 --> 00:12:19,790 +atom الآن بعد هيك بناخد العدد الذرع الكلي للذرات + +130 +00:12:19,790 --> 00:12:24,390 +الآن العدد الكلي ممكن تلاقوه بطريقتين إنّه تبدأ + +131 +00:12:24,390 --> 00:12:27,950 +تعدوا واحد اثنين ثلاثة كذا لحد ما تشوفهم عشرة + +132 +00:12:27,950 --> 00:12:33,630 +ديكان تسعة نونين ثمانية أوكتيل وهكذا طبعًا ممكن + +133 +00:12:33,630 --> 00:12:38,310 +طريقة أسلوب واحدة كانت متأكدة من هدول بإمكانها + +134 +00:12:38,310 --> 00:12:42,580 +تزيد عليهم واحد اللي كنا خاصين فيهم يعني هنا أربعة و + +135 +00:12:42,580 --> 00:12:48,400 +خمسة تسعة إذا اللي موجود عند حقيقة عشرة فالمركب + +136 +00:12:48,400 --> 00:12:58,640 +نونين نونين يعني ديكان نونين تسعة ديكان عشرة واضح؟ + +137 +00:12:58,640 --> 00:13:02,900 +يعني لما كنتوا تعرفوا شو هذي إذا عرفتو اللي ها + +138 +00:13:02,900 --> 00:13:10,840 +بزيادة واحد هيجي الآن كيف بدنا نبدأ نرقم عشان نحط + +139 +00:13:10,840 --> 00:13:14,860 +atoms يعني بعد شوية بدّه يج احط لها نيتروجينة هنا + +140 +00:13:14,860 --> 00:13:21,200 +أكسوجينة هنا كذا الـoxygen أحط لها أوكسا أوكسا ال + +141 +00:13:21,200 --> 00:13:26,620 +nitrogen احط لها ازا ال sulfur احط له ثيا ال + +142 +00:13:26,620 --> 00:13:30,140 +substituents اللي موجود على الخارج اكتوب 3 مثل 4 + +143 +00:13:30,140 --> 00:13:34,560 +whatever كيف بده اعمل كل هذا الكلام هتلاحظوا أن + +144 +00:13:34,560 --> 00:13:43,230 +أنا محتاج لترقيم الوف حوالين كل هدول الذرات كيف + +145 +00:13:43,230 --> 00:13:46,710 +بدأ اعمل الترقيم اللي حدد من خلاله الـ hetero + +146 +00:13:46,710 --> 00:13:50,630 +atoms اللي موجودين في داخل الحلقات و ال + +147 +00:13:50,630 --> 00:13:54,550 +substituents اللي محمولين على هدول الحلقات في + +148 +00:13:54,550 --> 00:14:00,690 +البداية إذا كان عندي حلقات مختلفة فالترقيم سيبدأ + +149 +00:14:00,690 --> 00:14:08,630 +من الحلقة الأصغر وسيبدأ مجاورا للـ Spiro atom إذا + +150 +00:14:08,630 --> 00:14:13,290 +كم احتمال عندي بيكون موجود للترقيم في هذه الحالة + +151 +00:14:13,290 --> 00:14:17,470 +احتمالين لأنه أنا لما أقول الأصغر هاي ال Spiro + +152 +00:14:17,470 --> 00:14:23,410 +atom إما من هنا أو من هنا واضح؟ اما من هذا الموقع + +153 +00:14:23,410 --> 00:14:35,490 +أو من هذا الموقع اما من هذا الموقع أو + +154 +00:14:35,490 --> 00:14:42,250 +من هذا الموقع اما + +155 +00:14:42,250 --> 00:14:47,370 +من هذا الموقع أو من هذا الموقع اما من هذا الموقع + +156 +00:14:47,370 --> 00:14:47,790 +هذا الموقع اما من هذا الموقع اما من هذا الموقع اما + +157 +00:14:47,790 --> 00:14:47,810 +من هذا الموقع اما من هذا الموقع اما من هذا الموقع + +158 +00:14:47,810 --> 00:14:50,510 +هذا الموقع اما من هذا الموقع اما من هذا الموقع اما + +159 +00:14:50,510 --> 00:14:51,330 +من هذا الموقع اما من هذا الموقع اما من هذا الموقع + +160 +00:14:51,330 --> 00:14:53,320 +اما من هذا الموقع اما من هذا الموقع اما من واضح؟ في + +161 +00:14:53,320 --> 00:14:56,160 +هذا المثال تحديدًا ما فيش فرق، لكن لو افترضت هنا + +162 +00:14:56,160 --> 00:15:00,680 +كانت ذرة nitrogen، إذا أنا إجبارًا بدي أبدأ منها، + +163 +00:15:00,680 --> 00:15:04,680 +ما أقدرش أبدأ من هذا الموقع، واضح الفكرة؟ الآن، + +164 +00:15:04,680 --> 00:15:08,340 +امشينا واحد، اثنين، ثلاثة، أربعة، خمسة، ووصلنا لل + +165 +00:15:08,340 --> 00:15:13,900 +spiral atom، مرة ثانية هنلاقي نفسنا أمام مفترض طرق + +166 +00:15:13,900 --> 00:15:17,820 +أن أنا بعد نسبة ايرو اتم أو هنا بعد نسبة ايرو اتم + +167 +00:15:17,820 --> 00:15:22,200 +قلت خمسة هن بتنزل ستة من هن وأستمر ولا ستة من هن + +168 +00:15:22,200 --> 00:15:25,600 +و أستمر نفس القواعد العامة اللي اتعلمناها في ال + +169 +00:15:25,600 --> 00:15:31,200 +organic اقل hetero atoms ولذلك لما أنا وصلت هنا + +170 +00:15:31,200 --> 00:15:35,140 +لنمرة خمسة إذا بديت من هن ستة هخلي ال hetero atom + +171 +00:15:35,140 --> 00:15:39,160 +على عشرة إذا بديت من هن ستة بتكون الترقيم الأقل + +172 +00:15:39,870 --> 00:15:43,310 +واضح؟ ولذلك الترقيم تبقى هيمشي ستة سبعة ثمانية + +173 +00:15:43,310 --> 00:15:51,450 +تسعة عشرة فهيصير هذا المركب الاسم تبعه كاتبينه + +174 +00:15:51,450 --> 00:15:56,870 +احنا ولا مش كاتبينه اسبايرو + +175 +00:15:56,870 --> 00:16:09,170 +four five كلهم عشرة دي كتير six أجهزة + +176 +00:16:10,970 --> 00:16:17,770 +واضح؟ بهذا الشكل بنعمل التسمية تبعتنا الآن هنشوف + +177 +00:16:17,770 --> 00:16:24,570 +عدة أمثلة متدرجة هنشوف عدة أمثلة متدرجة توضحلنا + +178 +00:16:24,570 --> 00:16:30,250 +كيف نتحرك في هذا الترقيم اللي بيلف حوالين الجزيرة + +179 +00:16:30,250 --> 00:16:34,130 +هاي + +180 +00:16:34,130 --> 00:16:38,250 +عندي مثال جديد + +181 +00:16:39,720 --> 00:16:48,100 +الآن هذا لما بدي اسميه لازم أقول Spiro الغسيل الآن + +182 +00:16:48,100 --> 00:16:54,120 +ثلاث ذرات عدل Spiro atom وأربع ذرات إذا هذا سيكون + +183 +00:16:54,120 --> 00:16:58,840 +Spiro 34لما بدأوا يقولوا كل الذرات ثلاثة وأربعة + +184 +00:16:58,840 --> 00:17:04,000 +سبعة، يزيدوها واحد، ثمانية، اكتين، إذا هذا Spiro + +185 +00:17:04,000 --> 00:17:10,660 +three four اكتين الترقيم إذا الحلقات مختلفة، يجب + +186 +00:17:10,660 --> 00:17:15,920 +أن يبدأ من الحلقة الصغيرة بجوار ال Spiro atom واحد + +187 +00:17:15,920 --> 00:17:19,000 +اثنين ثلاثة أربعة أو واحد اثنين ثلاثة أربعة في هذا + +188 +00:17:19,000 --> 00:17:23,820 +المثال مش فارق أوصلت لأربعة الآن الخمسة أخليها سلفر + +189 +00:17:23,820 --> 00:17:28,520 +ولا أخليها كاربون سلفر ولذلك هنكتبنا five + +190 +00:17:28,520 --> 00:17:34,780 +thyaspiro three four octane ثاني واضح هذا المثال + +191 +00:17:40,510 --> 00:17:48,630 +ناخد مثال ثاني الآن هذا المثال ربما مش مكتوب الاسم + +192 +00:17:48,630 --> 00:17:54,550 +تبعه لما بدي أبدأ أسمي مباشرة عندي كلمة Spiro و + +193 +00:17:54,550 --> 00:18:00,230 +القسين كم ذرة أنا عندي؟ واحد، اثنين، ثلاثة، أربعة، + +194 +00:18:00,230 --> 00:18:08,030 +خمسة، ثلاثة نقطة خمسة .. ثلاثة وخمسة .. ثمانية .. + +195 +00:18:08,030 --> 00:18:16,150 +ثمانية .. ثمانية .. ثمانية + +196 +00:18:16,150 --> 00:18:16,810 +.. ثمانية .. ثمانية .. ثمانية .. ثمانية .. ثمانية + +197 +00:18:16,810 --> 00:18:17,550 +.. ثمانية .. ثمانية .. ثمانية .. ثمانية .. ثمانية + +198 +00:18:17,550 --> 00:18:19,030 +.. ثمانية .. ثمانية .. ثمانية .. ثمانية .. ثمانية + +199 +00:18:19,030 --> 00:18:19,730 +.. ثمانية .. ثمانية .. ثمانية .. ثمانية .. ثمانية + +200 +00:18:19,730 --> 00:18:22,150 +.. ثمانية .. ثمانية .. ثمانية .. ثمانية .. ثمانية + +201 +00:18:22,150 --> 00:18:24,010 +.. ثمانية .. ثمانية .. ثمانية .. تم واضح طبعا + +202 +00:18:24,010 --> 00:18:29,550 +بالتأكيد هبدأ من الحلقة الأصغر one two three four + +203 +00:18:29,550 --> 00:18:33,610 +لحد الآن تمام الآن بدي أجي ع نمرة ستة hetero atom + +204 +00:18:33,610 --> 00:18:38,270 +واللي بعدها يمكن بتطلع ع تسعة أو ع خمسة hetero + +205 +00:18:38,270 --> 00:18:39,250 +atom ع تسعة + +206 +00:18:41,950 --> 00:18:46,590 +الآن هتيجوا لإنه أخدتوا قلتوا أن الأجزاء طالما + +207 +00:18:46,590 --> 00:18:50,410 +تساوت الاحتمالات في ال heteroatom number أن الأجزاء + +208 +00:18:50,410 --> 00:18:54,490 +الأولى ولذلك اجينا من هنا عشان نخلي ال oxygen على + +209 +00:18:54,490 --> 00:18:57,310 +خمسة وال sulfur على تسعة لأن ال oxygen لها أولوية + +210 +00:18:57,310 --> 00:19:03,850 +على ال sulfur فهذا لما بدنا نسميه هيصير five أجزاء + +211 +00:19:03,850 --> 00:19:11,330 +nine ثية spiro three five نونين + +212 +00:19:26,250 --> 00:19:32,190 +واضح؟ نشوف أمثلة إضافية حتى نرسخ هالمفاهيم + +213 +00:19:32,190 --> 00:19:34,910 +هتلاحظوا أن القواعد في ال organ ال chemistry يعني + +214 +00:19:34,910 --> 00:19:38,570 +مضطرة أو بتتكرر يعني الآن لما بدي أجي أسمي هذا + +215 +00:19:38,570 --> 00:19:44,520 +المركب واضح أنه عنده Spiral وحلقة سداسية وسداسية + +216 +00:19:44,520 --> 00:19:48,120 +يعني عندي خمسة carbons خمسة carbons فقلت Spyro + +217 +00:19:48,120 --> 00:19:54,940 +555 وخمسة وخمسة عشرة بزيادة واحد يندكين okay الآن + +218 +00:19:54,940 --> 00:20:01,210 +جبتها من وين بدأ أبدأ الترقيم حلقة سداسية وسداسية + +219 +00:20:01,210 --> 00:20:05,430 +لكن الواحد اللي من هنا بيخلي ال oxygen على نمرة + +220 +00:20:05,430 --> 00:20:09,410 +اثنين الواحد اللي من هنا بيخلي ال oxygen على نمرة + +221 +00:20:09,410 --> 00:20:13,350 +أربعة الواحد اللي من هنا بيخلي ال oxygen أعلى كتير + +222 +00:20:13,350 --> 00:20:17,110 +الواحد اللي من هنا هيك بيخليه أعلى كتير بدي أقل + +223 +00:20:17,110 --> 00:20:20,590 +oxygen طالما كل شيء متساوي ولذلك تم الاختيار + +224 +00:20:20,590 --> 00:20:26,360 +السليم أن الواحد من هنا 1,2,3,4,5,6 طبعا هنا ما فيش + +225 +00:20:26,360 --> 00:20:32,240 +فرق في الاحتمالات بأي طرق بنمشي إذا هنا صار 2 أجزاء + +226 +00:20:32,240 --> 00:20:39,970 +Spyro 55 يون دي كيل أو يون دي كيل هي مثال ثاني + +227 +00:20:39,970 --> 00:20:45,710 +الحلقات اللي موجودين عنده حلقة خماسية وخماسية + +228 +00:20:45,710 --> 00:20:49,910 +يعني هيحطوا أربعة وأربعة سباير و four five و four + +229 +00:20:49,910 --> 00:20:56,350 +four و بدي أزيد عليهم واحد لونين الآن لما بدي أجي + +230 +00:20:56,350 --> 00:21:03,550 +أرقم هذه خماسية وهذه خماسية هذه فيها Oxygen و + +231 +00:21:03,550 --> 00:21:06,110 +Carbon وهذه فيها Sulphur و Carbon مين اللي هتعطيها + +232 +00:21:06,110 --> 00:21:10,310 +الأولوية ال Oxygen فهقول واحد اثنين ثلاثة أربعة + +233 +00:21:10,310 --> 00:21:16,690 +خمسة وصلت خمسة ممكن أنزل هيك ستة أو هيك ستة على ال + +234 +00:21:16,690 --> 00:21:21,710 +heteroatom أقل ما يمكن ولذلك هذا بيصير one أجزاء + +235 +00:21:21,710 --> 00:21:30,130 +six thiospyro four four نونين ناخد + +236 +00:21:30,130 --> 00:21:39,640 +كمان مثال المثال اللي عندنا هذا واضح أنه بسيط فيه + +237 +00:21:39,640 --> 00:21:46,060 +فرق في الحلقات خماسية وسداسية إذا الحيبان عنده + +238 +00:21:46,060 --> 00:21:55,050 +أربعة وخمسة Spyro four five Dick في double bond + +239 +00:21:55,050 --> 00:22:02,110 +حيصير دي كيلو لو تانو تنتن دي try eel لكن موقع ال + +240 +00:22:02,110 --> 00:22:07,160 +eel يتبع الترقيم العام بدي أصبر عليه شوية الآن في + +241 +00:22:07,160 --> 00:22:12,320 +الترقيم العام يجب أن أبدأ من الحلقة الأصغر عندي + +242 +00:22:12,320 --> 00:22:15,880 +oxygen و carbon أكيد هقول oxygen one two three + +243 +00:22:15,880 --> 00:22:20,620 +four five الآن بعدها هي carbon و carbon لكن إذا + +244 +00:22:20,620 --> 00:22:24,520 +تحركنا بهذا الشكل أنا بخلي ال double bond أقل ما + +245 +00:22:24,520 --> 00:22:31,520 +يمكن واضح ال double bond أقل ما يمكن اللي هي ستة + +246 +00:22:31,520 --> 00:22:37,100 +واضح وبناء على ذلك بأعمل بهذا الشكل حيث أن عندي + +247 +00:22:37,100 --> 00:22:44,340 +one أجزاء بايرو four five ديك six إين يعني الإين + +248 +00:22:44,340 --> 00:22:50,030 +أو ال double point وين موجودة على نمرة ستة الآن بدو + +249 +00:22:50,030 --> 00:22:55,250 +يظل في بالكم شغلة أن هذه القواعد بناخدها مرتبة + +250 +00:22:55,250 --> 00:23:00,930 +يعني ال double bond ما بتسبقش ال hetero atom ال + +251 +00:23:00,930 --> 00:23:03,790 +double bond ما بتسبقش ال hetero atom في أنها تحدد + +252 +00:23:03,790 --> 00:23:08,710 +المواقع هذا المثال اللي بعد بيجيب تطبيق مباشر على + +253 +00:23:08,710 --> 00:23:12,130 +هذه النقطة يعني احنا عندنا حلقة خماسية وسوداسية + +254 +00:23:12,130 --> 00:23:19,070 +إذا كتبنا four five اثبار و four five Double point + +255 +00:23:19,070 --> 00:23:23,610 +لكن لكن وين ال in الآن من هنا الترقيم من الحلقة + +256 +00:23:23,610 --> 00:23:28,290 +الأصغر واحد اثنين ثلاثة أربعة خمسة الآن عند الخمسة + +257 +00:23:28,290 --> 00:23:33,920 +وقف هل يا تورا بدي اروح أخلي ال hetero atom أقل ما + +258 +00:23:33,920 --> 00:23:36,740 +يمكن ولا ال double bond أقل ما يمكن الجواب + +259 +00:23:36,740 --> 00:23:39,900 +بالتأكيد ال hetero atom إذا ال hetero atom بتحل + +260 +00:23:39,900 --> 00:23:43,180 +المشكلة ما بتطلعش على ال double bond ولذلك حطينا + +261 +00:23:43,180 --> 00:23:47,960 +ستة اللي تخلي ال hetero atom أقل ما يمكن ضمن هذا + +262 +00:23:47,960 --> 00:23:52,920 +الكلام لما صار six oxaspiro four five dick بداية + +263 +00:23:52,920 --> 00:23:57,700 +ال double bond وين صارت؟ عند تسعة فصار عند nine in + +264 +00:23:58,510 --> 00:24:02,750 +فإذا كان التنافس بينكم في تحديد المواقع بين + +265 +00:24:02,750 --> 00:24:08,460 +الهيتيرو أتم وبين ال double bond الهيتيرو اتم أو لا + +266 +00:24:08,460 --> 00:24:12,300 +طبعا لاحظوا هنا أن أنا بتعامل مع المركبات هذه + +267 +00:24:12,300 --> 00:24:16,800 +على أساس أن كأنها ال can's و جد ما بنوجد double + +268 +00:24:16,800 --> 00:24:20,500 +bonds بحددهم يعني واحدة double bond اين تنتين + +269 +00:24:20,500 --> 00:24:24,320 +تتراين تتراين تتراين ما بيجيش عندي قصة ال H وال + +270 +00:24:24,320 --> 00:24:30,180 +dihydro وما إلى ذلك أنا نسبت المركب لإيش؟ لل can + +271 +00:24:30,940 --> 00:24:36,040 +نسبة المركب لكين عادي وهذا ربما شفته في أول مثال + +272 +00:24:36,040 --> 00:24:38,300 +اللي هو ال hydrocarbon هذا اللي ما فيش فيه hetero + +273 +00:24:38,300 --> 00:24:45,740 +atom دي cane ال cane عادي ال cane عادي بهيك تقريبا + +274 +00:24:45,740 --> 00:24:50,820 +بيكون استعرضنا فكرة لا بأس بها عن تسمية Spiro + +275 +00:24:50,820 --> 00:24:55,420 +-heterocyclic compounds وبننهي بهذا الأمر الجزء + +276 +00:24:55,420 --> 00:24:58,520 +العام اللي احنا رغبنا أنه يكون موجود عندكم في + +277 +00:24:58,520 --> 00:25:01,960 +موضوع تسمية المركبات العضوية طبعا أن شاء الله بعد + +278 +00:25:01,960 --> 00:25:07,300 +هيك هنتحول إلى تحضير المركبات الحلقية غير + +279 +00:25:07,300 --> 00:25:08,620 +المتجانسة diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/Bir78NGXpBQ_postprocess.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/Bir78NGXpBQ_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..3779705cd8029ac7cbc3ce4753388887e25c4639 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/Bir78NGXpBQ_postprocess.srt @@ -0,0 +1,1116 @@ +1 +00:00:20,670 --> 00:00:25,650 +بسم الله الرحمن الرحيم اليوم ان شاء الله بدنا نكمل + +2 +00:00:25,650 --> 00:00:30,650 +في موضوع تسمية المركبات الحلقية طبعا درسنا الأساسي + +3 +00:00:30,650 --> 00:00:35,390 +ان شاء الله هيكون عن تسمية ال spiral heterocyclic + +4 +00:00:35,390 --> 00:00:41,100 +compounds لكن احنا زي ما طلبنا منكم انه ممكنتحضروا + +5 +00:00:41,100 --> 00:00:46,640 +إلنا من المجلات الحديثة مركبات نشرت حديثا نشوف كيف + +6 +00:00:46,640 --> 00:00:52,240 +الناس سموا هذه المركبات كيف احنا فعلا هل ما تعلمنا + +7 +00:00:52,240 --> 00:00:57,480 +من تسمية يكفي لأن نسم المركبات بطريقة سليمة وحتى + +8 +00:00:57,480 --> 00:01:03,430 +ممكن بطريقة ناقدة بمعنى إذا همارتكبوا خطأ معين + +9 +00:01:03,430 --> 00:01:07,810 +احنا ممكن نقول انه في هذه المنطقة هم عملوا خطأ + +10 +00:01:07,810 --> 00:01:14,770 +معين الان هذا مركب جابته ازملتكم من مجلة molecules + +11 +00:01:14,770 --> 00:01:21,430 +منشور بال 2015 يعني شي حديث جدا وكاتب الاسم يفترض + +12 +00:01:21,430 --> 00:01:27,090 +زي ما هو موجود في المجلة انا شوية ملاحظ ان هي حتى + +13 +00:01:27,090 --> 00:01:33,020 +مغيرة الاسم او محتاجة علىالاسم إذا خلّينا نشوف وين + +14 +00:01:33,020 --> 00:01:38,400 +يعني الإشكال هل فعلا التسمية اللي موجودة صحيحة ولا + +15 +00:01:38,400 --> 00:01:43,880 +لأ هذا fused heterocyclic compounds كمراجعة للكلام + +16 +00:01:43,880 --> 00:01:49,240 +اللي أخدناهالان لو كنا بنسمي هذا المركب اللى موجود + +17 +00:01:49,240 --> 00:01:53,780 +أمامنا هلاحظ انه احنا بنحكي عن حلقتين هدول + +18 +00:01:53,780 --> 00:01:57,600 +الحلقتين اللى فيهم نيتروجين of the same size + +19 +00:01:57,600 --> 00:02:01,820 +اتنتين حلقات سداسية وبناء على ذلك القاسم اللى + +20 +00:02:01,820 --> 00:02:06,600 +بينهم ان هذه الحلقة فيها اربع ذرات من النيتروجين + +21 +00:02:06,600 --> 00:02:10,740 +بينما هذه الحلقة فيها ذرتين ولاحظوا ان هذه + +22 +00:02:10,740 --> 00:02:14,780 +النيتروجين تتبع الحلقتينبناء على ذلك ال base + +23 +00:02:14,780 --> 00:02:21,000 +component اللى هتكون موجودة عندى هي الحلقة هذه و + +24 +00:02:21,000 --> 00:02:23,060 +لما بدي اشتغل بدي اقول ايه + +25 +00:02:26,730 --> 00:02:31,010 +BCDEF هذا بالنسبة للروابط الموجودة في ال base + +26 +00:02:31,010 --> 00:02:35,230 +component و طبعا واضح أنها فيها أربع ذرات نيتروجين + +27 +00:02:35,230 --> 00:02:40,450 +إذا هي تترازين هي تترازين الآن هذه الحلقة فيها + +28 +00:02:40,450 --> 00:02:43,810 +ذرتين نيتروجين على موقع واحد و تلاتة إذا هذه + +29 +00:02:43,810 --> 00:02:49,290 +الحلقةبيرمدين و لو كنا بنحط أرقام واحد اتنين تلاتة + +30 +00:02:49,290 --> 00:02:54,310 +أربعة خمسة ستة فلو احنا اجينا في الأول نشوف ال + +31 +00:02:54,310 --> 00:02:59,890 +fusion بأي شكل موجود هلاحظ ان ال fusion من هنا بيه + +32 +00:02:59,890 --> 00:03:07,530 +و ال fusion من هناone two فلو بدأنا بهذا الشكل + +33 +00:03:07,530 --> 00:03:11,290 +التسمية هذا التترازين لو كنا بنعطيه أرقام واحد + +34 +00:03:11,290 --> 00:03:18,890 +اتنين تلاتة اربعة خمسة اذا هذا one two four five + +35 +00:03:18,890 --> 00:03:28,390 +تترازين الان هذا ال one two four five تترازين عامل + +36 +00:03:28,390 --> 00:03:36,870 +fusion من الرابط بي الانمرتبط مع ال بيرميدين من + +37 +00:03:36,870 --> 00:03:42,110 +واحد و اتنين اذا هذا هيصير بيرميدو ال بيرميدين + +38 +00:03:42,110 --> 00:03:48,690 +بيرميدو one two B one two four five تترازين هذا + +39 +00:03:48,690 --> 00:03:53,660 +اسمالحلقتين من ناحية ال fusion الآن في عندنا + +40 +00:03:53,660 --> 00:03:58,220 +substituents هذه ال substituents بدأت تتبع نظام + +41 +00:03:58,220 --> 00:04:03,340 +ترقيم خارجي والقاعدة الأولى في نظام الترقيم ان + +42 +00:04:03,340 --> 00:04:11,680 +يكون عنده اقل ارقام ال hetero atoms فلو انا اتحركت + +43 +00:04:11,680 --> 00:04:16,860 +من هذا الموقعلاحظوا اجمعوا معنا الـ hetero atoms + +44 +00:04:16,860 --> 00:04:23,260 +من هذه النقطة كنقطة بداية هتكون على واحد و اتنين و + +45 +00:04:23,260 --> 00:04:34,580 +اربعة و خمسة و تسعة و أربعة و تسعة و أربعة و تسعة + +46 +00:04:34,580 --> 00:04:35,680 +و أربعة و تسعة و أربعة و تسعة و أربعة و تسعة و + +47 +00:04:35,680 --> 00:04:42,540 +أربعة و تسعة و أربعة و تسعة و أربعة و تسعة و أربعة + +48 +00:04:43,670 --> 00:04:49,550 +تلاتة اربعة تلاتة + +49 +00:04:49,550 --> 00:04:55,210 +واحد اتنين تلاتة اربع اربع ابرعين خمسة ستة سبعة + +50 +00:04:55,210 --> 00:05:02,890 +ثمانية تسعة واضح؟ انه الترقيم اللي اقل؟الترقيم هذا + +51 +00:05:02,890 --> 00:05:07,190 +الترقيم هذا من ناحية الهيتيرو أتمز طالما الهيتيرو + +52 +00:05:07,190 --> 00:05:11,470 +أتمز عملوا فرق عندى ما بروحش أطلع على القواعد + +53 +00:05:11,470 --> 00:05:16,110 +التانية المتعلقة بال fusion و carbon و ما إلى ذلك + +54 +00:05:16,110 --> 00:05:21,730 +واضح و لذلك بدي ألتزم بالترقيم من هنا واحد طبعا + +55 +00:05:21,730 --> 00:05:24,990 +البعض اللى بيقول القاعدة بتقول مع قريب الساعة مش + +56 +00:05:24,990 --> 00:05:28,130 +مشكلة احنا بنعمل flipping لهذا الجزء بنصير باللف + +57 +00:05:28,130 --> 00:05:33,270 +مع قريب الساعة هذا الكلام أضبحناهحتى لو بيّن + +58 +00:05:33,270 --> 00:05:39,350 +ظاهريا ان انا هنا بشتغل عكس عقارب الساعة لكن مجرد + +59 +00:05:39,350 --> 00:05:44,130 +ان اعمل للمركب vertical flipping بصير مع عقارب + +60 +00:05:44,130 --> 00:05:48,450 +الساعة بصير ماشي مع القواعد تماما اربعة خمسة ستة + +61 +00:05:48,450 --> 00:05:54,230 +سبعة ثمانية تسعة الان بنقدر نحط ال substituents + +62 +00:05:54,230 --> 00:05:59,400 +انا بتهيألي هيربما الأخت كانت اذا خربت في هذه + +63 +00:05:59,400 --> 00:06:04,620 +اللقطة كانت بفضل هذا الترقيم، لكن أنا لا أرى ما + +64 +00:06:04,620 --> 00:06:10,010 +اتراهايعني ترقيم المجلة هو الترقيم الصح والترقيم + +65 +00:06:10,010 --> 00:06:16,090 +اللى اقترحته هي هو ترقيم ايش اعلى واحنا بدنا ناخد + +66 +00:06:16,090 --> 00:06:22,230 +ال hetero atoms as a set كمجموعة يكونوا ايش اقل + +67 +00:06:22,230 --> 00:06:26,950 +ترقيم واضح وبناء على ذلك لما بنانيج نحط المجموعات + +68 +00:06:26,950 --> 00:06:31,390 +مافيش داعي نضيع الوقت كتير هتبين الفنل على موقع + +69 +00:06:31,390 --> 00:06:37,990 +واحد الآن هذه المجموعةإيش بدنا نسميها؟ بدنا نحطها + +70 +00:06:37,990 --> 00:06:45,310 +بين قوسين بترقيم تاني two prime hydroxy phenyl two + +71 +00:06:45,310 --> 00:06:54,310 +prime hydroxy phenyl ال a هذي أربعة أتش و هذي six + +72 +00:06:54,310 --> 00:06:59,970 +all بتظهر في آخر المركب هنا هيكون one etch لإن هذي + +73 +00:06:59,970 --> 00:07:05,410 +saturated هنا هيكون عندى eight methylكل هذا الكلام + +74 +00:07:05,410 --> 00:07:09,350 +بتاهية اللي بنقدر نحطه و الراتب alphabetical لو + +75 +00:07:09,350 --> 00:07:13,090 +اتطلعنا على الجزء الأخير هنلاحظ ان هو معبر عن ال + +76 +00:07:13,090 --> 00:07:20,330 +on في نهاية الاسم هانا كاتب six four + +77 +00:07:20,330 --> 00:07:27,490 +H on و هذا احنا بتاهية ليه؟ اخدنا كيف نعمله ال on + +78 +00:07:27,490 --> 00:07:31,930 +على موقع الستة و وجودها هنا عمل كمان four H و هذه + +79 +00:07:31,930 --> 00:07:37,960 +بتظلهاone H واضح كل هذا الكلام حط و لذلك بنلاحظ + +80 +00:07:37,960 --> 00:07:44,260 +أنه الاسم عنده three نقرأ اللي موجود three two + +81 +00:07:44,260 --> 00:07:51,600 +hydroxy phenyl eight methyl eight methyl one + +82 +00:07:51,600 --> 00:07:56,900 +phenyl one H pyrimido one two B one two four five + +83 +00:07:56,900 --> 00:08:01,200 +tetrazine six four H all + +84 +00:08:03,670 --> 00:08:09,770 +هو اللي بيستعمله هذا النظام اللي بيحطه on بيحطه + +85 +00:08:09,770 --> 00:08:14,570 +بين قسيل ال H الأقرب عليها اللي موجودة بسببها فلما + +86 +00:08:14,570 --> 00:08:20,410 +حط six four H on ضال عيده إيش one H ممكن عند ناس + +87 +00:08:20,410 --> 00:08:24,870 +تانين يتلاقوهم كتبوها بطريقة مختلفة ممكن يكتبوا + +88 +00:08:24,870 --> 00:08:33,480 +six oxo one four dihydroممكن يكتبوا 6 OXO في مقدمة + +89 +00:08:33,480 --> 00:08:38,040 +الإسم One Four Dihydro بس واضح أن الإسم بالطريقة + +90 +00:08:38,040 --> 00:08:42,580 +اللي حكيناها سليم هذا موجود للناس اللي بحبوا + +91 +00:08:42,580 --> 00:08:50,730 +ارجعوا في مجلة molecules سنة 2015 صفحة 2500أي حد + +92 +00:08:50,730 --> 00:08:59,350 +بيحب يراجع المثال بيقدر يشوفه من هذه المجلة طبعا + +93 +00:08:59,350 --> 00:09:04,090 +بالتأكيد انا باعتبر يعني شئ جيد بالنسبة لكم ان + +94 +00:09:04,090 --> 00:09:08,950 +تقدر تشوفوا أمثلة زي هذه أشياء ماكناش بنعرف كيف + +95 +00:09:08,950 --> 00:09:13,450 +بتتسمى قبل أسبوعين تلاتة قبل محاضرتين الآن يعني + +96 +00:09:13,450 --> 00:09:18,050 +الحمد لله صار في عندكم خبرة في تسميةFused + +97 +00:09:18,050 --> 00:09:22,290 +heterocyclic compounds اذا بقرأ اسم بحس انه هذا + +98 +00:09:22,290 --> 00:09:40,210 +الاسم مش غريب بقدر ان افهم هذا الاسم الان + +99 +00:09:40,990 --> 00:09:46,590 +نجي لشيء جديد في موضوع التسمية موضوع ال spiral + +100 +00:09:46,590 --> 00:09:50,490 +hetero cyclic compounds ال spiral hetero cyclic + +101 +00:09:50,490 --> 00:09:54,970 +compounds زي ما اتفقنا ان هما حلقتين بيكونوا + +102 +00:09:54,970 --> 00:09:59,520 +مشتركين ب carbonو عادة بيكون حول الكربون + +103 +00:09:59,520 --> 00:10:03,560 +تتراهيدرال arrangement بهذا الشكل يعني مابيكونوش + +104 +00:10:03,560 --> 00:10:08,560 +planner بيكونوا في تتراهيدرال arrangement بهذا + +105 +00:10:08,560 --> 00:10:14,420 +الشكل واضح؟ الآن كيف بنسمي ال spiral heterocycle + +106 +00:10:14,420 --> 00:10:18,180 +compound لو احنا طلعنا بالتأكيد احنا على السبورة + +107 +00:10:18,180 --> 00:10:23,100 +بنرسمهم plannerلكن كفهم في مخنا لازم يكون واضح + +108 +00:10:23,100 --> 00:10:28,140 +عندنا ان فيهم واحدة في مستوى اللوح و واحدة عمودية + +109 +00:10:28,140 --> 00:10:33,540 +على مستوى اللوح بهذا الشكل واضح؟ الآن لما نيجي + +110 +00:10:33,540 --> 00:10:38,860 +نسمي هذه المراكبات بدنا نكتب كلمة Spiral في + +111 +00:10:38,860 --> 00:10:44,760 +البداية بدنا نكتب كلمة Spiral بعد هيك بنيجي بنحط + +112 +00:10:44,760 --> 00:10:51,870 +بين جثينفي كل حلقة عدا الذرّة اللي هي الـ + +113 +00:10:51,870 --> 00:10:55,670 +Spiroatom الكاربون، يعني هذه الانتخابة مش موجودة، + +114 +00:10:55,670 --> 00:11:01,290 +كام ذرّة يوجد عندهم؟ هنا واحد، اتنين، تلاتة، + +115 +00:11:01,290 --> 00:11:06,070 +اربعة، هنا واحد، اتنين، تلاتة، اربعة، خمسةفلاحظوا + +116 +00:11:06,070 --> 00:11:09,890 +الحلقة الخماسية عدى ال spiral atom فيها كام ذرّة؟ + +117 +00:11:09,890 --> 00:11:14,230 +أربعة الحلقة السادسية عدى ال spiral atom فيها كام + +118 +00:11:14,230 --> 00:11:19,350 +ذرّة؟ خمسة الآن بحط عدد الذرّات بدون ال spiral + +119 +00:11:19,350 --> 00:11:24,990 +atom واضح؟ في عندي أربعة وخمسة مين اللي بدكره + +120 +00:11:24,990 --> 00:11:31,100 +دائما في الأول؟ الأصغرالأصغر فلما انا اكتب spyro + +121 +00:11:31,100 --> 00:11:35,880 +four five four نقطة five هيك طريقة التسمية four + +122 +00:11:35,880 --> 00:11:42,820 +نقطة five ع طول أي واحدة بدى تشوف هذا الكلام و اجي + +123 +00:11:42,820 --> 00:11:48,920 +أسأل السؤال ع السريع هدول الحلقات ايه؟ ايش نوعهم؟ + +124 +00:11:48,920 --> 00:11:53,000 +بدى تقرأ الأرقام اللي هانوي تزيد على كل واحد واحدة + +125 +00:11:54,380 --> 00:11:59,920 +تقول هدول حلقتين خماسية و ساداسية واضح؟ لو كتبت + +126 +00:11:59,920 --> 00:12:04,280 +هنا تلاتة و أربعة إذا أنا بحكي عن حلقتين قباعية و + +127 +00:12:04,280 --> 00:12:08,600 +خماسية دائما الرقم اللي هنا أقل من حجم الحلقة + +128 +00:12:08,600 --> 00:12:13,120 +بواحد لإنه لما إحنا كتبناه لغينا إيش ال spiral + +129 +00:12:13,120 --> 00:12:19,790 +atom الآنبعد هيك بناخد العدد الذرع الكلي للذرات + +130 +00:12:19,790 --> 00:12:24,390 +الان العدد الكلي ممكن تلاقوه بطريقتين انه تبدو + +131 +00:12:24,390 --> 00:12:27,950 +تعدوا واحد اتنين تلاتة كذا لحد ما تشوفهم عشرة + +132 +00:12:27,950 --> 00:12:33,630 +ديكان تسعة نونين تمانية اكتل و هكذا طبعا ممكن + +133 +00:12:33,630 --> 00:12:38,310 +طريقة أسلوب واحدة كانت متأكدة من هدول بإمكانها + +134 +00:12:38,310 --> 00:12:42,580 +تزيد عليهم واحد اللي كنا خاص منهميعني هنا أربعة و + +135 +00:12:42,580 --> 00:12:48,400 +خمسة تسعة إذا اللي موجود عند حقيقة عشرة فالمركب + +136 +00:12:48,400 --> 00:12:58,640 +نونين نونين يعني دكين نونين تسعة دكين عشرة واضح؟ + +137 +00:12:58,640 --> 00:13:02,900 +يعني لما كنتوا تعرفوا شو هذي إذا عرفتوا اللي ها + +138 +00:13:02,900 --> 00:13:10,840 +بزيادة واحد هيجي الآن كيف بدنا نبدأانرقم عشان نحط + +139 +00:13:10,840 --> 00:13:14,860 +atoms يعني بعد شوية بدهج احط ليها نيتروجينة هان + +140 +00:13:14,860 --> 00:13:21,200 +اكسوجينة هان كذا ال oxygen احطلها اكزا اكزا ال + +141 +00:13:21,200 --> 00:13:26,620 +nitrogen احطلها ازا ال sulfur احطله ثيا ال + +142 +00:13:26,620 --> 00:13:30,140 +substituents اللي موجود على الخارج اكتوب 3 مثل 4 + +143 +00:13:30,140 --> 00:13:34,560 +whatever كيف بده اعمل كل هذا الكلام هتلاحظوا ان + +144 +00:13:34,560 --> 00:13:43,230 +انا محتاجالى ترقيم الوف حوالين كل هدول الذرات كيف + +145 +00:13:43,230 --> 00:13:46,710 +بدأ اعمل الترقيم اللى حدد من خلاله الـ hetero + +146 +00:13:46,710 --> 00:13:50,630 +atoms اللى موجودين فى داخل الحلقات و ال + +147 +00:13:50,630 --> 00:13:54,550 +substituents اللى محمولين على هدول الحلقات فى + +148 +00:13:54,550 --> 00:14:00,690 +البداية إذا كان عند الحلقات مختلفة فالترقيم سيبدأ + +149 +00:14:00,690 --> 00:14:08,630 +من الحلقة الأصغر وسيبدأ مجاورا لالـ Spiro atom إذا + +150 +00:14:08,630 --> 00:14:13,290 +كم احتمال عندي بيكون موجود للترقيم في هذه الحالة + +151 +00:14:13,290 --> 00:14:17,470 +احتمالين لأنه أنا لما أقول الأصغر هاي ال Spiro + +152 +00:14:17,470 --> 00:14:23,410 +atom إما من هنا أو من هناواضح؟ اما من هذا الموقع + +153 +00:14:23,410 --> 00:14:35,490 +او من هذا الموقع اما من هذا الموقع او + +154 +00:14:35,490 --> 00:14:42,250 +من هذا الموقع اما + +155 +00:14:42,250 --> 00:14:47,370 +من هذا الموقع او من هذا الموقع اما من هذا الموقع + +156 +00:14:47,370 --> 00:14:47,790 +هذا الموقع اما من هذا الموقع اما من هذا الموقع اما + +157 +00:14:47,790 --> 00:14:47,810 +من هذا الموقع اما من هذا الموقع اما من هذا الموقع + +158 +00:14:47,810 --> 00:14:50,510 +هذا الموقع اما من هذا الموقع اما من هذا الموقع اما + +159 +00:14:50,510 --> 00:14:51,330 +من هذا الموقع اما من هذا الموقع اما من هذا الموقع + +160 +00:14:51,330 --> 00:14:53,320 +اما من هذا الموقع اما من هذا الموقع اما منواضح؟ في + +161 +00:14:53,320 --> 00:14:56,160 +هذا المثال تحديدًا مافيش فرق، لكن لو افترضت هنا + +162 +00:14:56,160 --> 00:15:00,680 +كانت ذرّة nitrogen، إذا أنا إجبارًا بدي أبدأ منها، + +163 +00:15:00,680 --> 00:15:04,680 +ماقدرش أبدأ من هذا الموقع، واضح الفكرة؟ الآن، + +164 +00:15:04,680 --> 00:15:08,340 +امشينا واحد، اتنين، تلاتة، أربعة، خمسة، ووصلنا لل + +165 +00:15:08,340 --> 00:15:13,900 +spiral atom، مرة تانية هنلاقي نفسنا أماممفترط طرق + +166 +00:15:13,900 --> 00:15:17,820 +ان انا بعد نسبة ايرو اتم او هنا بعد نسبة ايرو اتم + +167 +00:15:17,820 --> 00:15:22,200 +قلت خمس هن بتانزل ستة من هن و أستمر ولا ستة من هن + +168 +00:15:22,200 --> 00:15:25,600 +و أستمر نفس القواعد العامة اللي اتعلمناها في ال + +169 +00:15:25,600 --> 00:15:31,200 +organic اقل hetero atoms ولذلك لما انا اوصلت هنا + +170 +00:15:31,200 --> 00:15:35,140 +لنمره خمسة اذا بديت من هن ستة هخلي ال hetero atom + +171 +00:15:35,140 --> 00:15:39,160 +على عشرة اذا بديت من هن ستة بتكون الترقيم الاقل + +172 +00:15:39,870 --> 00:15:43,310 +واضح؟ و لذلك الترقيم تبقى هيمشي ستة سبعة ثمانية + +173 +00:15:43,310 --> 00:15:51,450 +تسعة عشرة فهيصير هذا المركب الاسم تبعه كاتبينه + +174 +00:15:51,450 --> 00:15:56,870 +احنا ولا مش كاتبينه اسبايرو + +175 +00:15:56,870 --> 00:16:09,170 +four five كلهم عشرة دي كتير six أجزة + +176 +00:16:10,970 --> 00:16:17,770 +واضح؟ بهذا الشكل بنعمل التسمية تبعتنا الآن هنشوف + +177 +00:16:17,770 --> 00:16:24,570 +عدة أمثلة متدرجة هنشوف عدة أمثلة متدرجة توضحلنا + +178 +00:16:24,570 --> 00:16:30,250 +كيف نتحرك في هذا الترقيم اللي بيلف حوالين الجزيرة + +179 +00:16:30,250 --> 00:16:34,130 +هاي + +180 +00:16:34,130 --> 00:16:38,250 +عندي مثال جديد + +181 +00:16:39,720 --> 00:16:48,100 +الان هذا لما بدي اسميه لازم اقول Spiro الغسيل الان + +182 +00:16:48,100 --> 00:16:54,120 +تلت ذرات عدل Spiro atom و اربع ذرات اذا هذا سيكون + +183 +00:16:54,120 --> 00:16:58,840 +Spiro 34لما بدأوا يقولوا كل الذرات تلاتة وأربعة + +184 +00:16:58,840 --> 00:17:04,000 +سبعة، يزيدوها واحد، تمانية، اكتين، إذا هذا Spiro + +185 +00:17:04,000 --> 00:17:10,660 +three four اكتين الترقيم إذا الحلقات مختلفة، يجب + +186 +00:17:10,660 --> 00:17:15,920 +أن يبدأ من الحلقة الصغيرة بجوار ال Spiro atomواحد + +187 +00:17:15,920 --> 00:17:19,000 +اتنين تلاتة اربعة او واحد اتنين تلاتة اربعة في هذا + +188 +00:17:19,000 --> 00:17:23,820 +المثال مش فارق اوصلت لاربعة الان الخمس اخليها سلفر + +189 +00:17:23,820 --> 00:17:28,520 +ولا اخليها كاربون سلفر ولذلك هنكتبنا five + +190 +00:17:28,520 --> 00:17:34,780 +thyaspiro three four octane تاني واضح هذا المثال + +191 +00:17:40,510 --> 00:17:48,630 +ناخد مثال تاني الآن هذا المثال ربما مش مكتوب الاسم + +192 +00:17:48,630 --> 00:17:54,550 +تبعه لما بدي أبدأ أسمي مباشرة عندي كلمة Spiro و + +193 +00:17:54,550 --> 00:18:00,230 +القسين كم ذره أنا عندي؟ واحد، اتنين، تلاتة، اربعة، + +194 +00:18:00,230 --> 00:18:08,030 +خمسة، تلاتة نقطةخمسة .. تلاتة و خمسة .. تمانية .. + +195 +00:18:08,030 --> 00:18:16,150 +تمانية .. تمانية .. تمانية + +196 +00:18:16,150 --> 00:18:16,810 +.. تمانية .. تمانية .. تمانية .. تمانية .. تمانية + +197 +00:18:16,810 --> 00:18:17,550 +.. تمانية .. تمانية .. تمانية .. تمانية .. تمانية + +198 +00:18:17,550 --> 00:18:19,030 +.. تمانية .. تمانية .. تمانية .. تمانية .. تمانية + +199 +00:18:19,030 --> 00:18:19,730 +.. تمانية .. تمانية .. تمانية .. تمانية .. تمانية + +200 +00:18:19,730 --> 00:18:22,150 +.. تمانية .. تمانية .. تمانية .. تمانية .. تمانية + +201 +00:18:22,150 --> 00:18:24,010 +.. تمانية .. تمانية .. تمانية .. تمواضح طبعا + +202 +00:18:24,010 --> 00:18:29,550 +بالتأكيد هبدأ من الحلقة الأصغر one two three four + +203 +00:18:29,550 --> 00:18:33,610 +لحد الآن تمام الان بدي اجي ع نمره ستة hetero atom + +204 +00:18:33,610 --> 00:18:38,270 +و اللي بعدها يمكن بتطلع ع تسعة او ع خمسة hetero + +205 +00:18:38,270 --> 00:18:39,250 +atom ع تسعة + +206 +00:18:41,950 --> 00:18:46,590 +الان هتيجيوا لإنه أخدتوا قلتوا ان الأجزا طالما + +207 +00:18:46,590 --> 00:18:50,410 +تساوى الاحتمالات في ال heteroatom number ان الأجزا + +208 +00:18:50,410 --> 00:18:54,490 +أولى و لذلك اجينا من هنا عشان نخلي ال oxygen على + +209 +00:18:54,490 --> 00:18:57,310 +خمسة و ال sulfur على تسعة لإن ال oxygen لها أولوية + +210 +00:18:57,310 --> 00:19:03,850 +على ال sulfur فهذا لما بدنا نسميه هيصير five أجزا + +211 +00:19:03,850 --> 00:19:11,330 +nine ثية spiro three five نونين + +212 +00:19:26,250 --> 00:19:32,190 +واضح؟ نشوف أمثلة إضافية حتى نرسّخ هالمفاهيم + +213 +00:19:32,190 --> 00:19:34,910 +هتلاحظوا أن القواعد في ال organ ال chemistry يعني + +214 +00:19:34,910 --> 00:19:38,570 +مضطرة أو بتتكرر يعني الآن لما بدي أجي أسمي هذا + +215 +00:19:38,570 --> 00:19:44,520 +المُركّب واضح أنه عنده Spiralوحلقة سدسية و سدسية + +216 +00:19:44,520 --> 00:19:48,120 +يعني عندي خمسة carbons خمسة carbons فقولت Spyro + +217 +00:19:48,120 --> 00:19:54,940 +555 وخمسة وخمسة عشرة بزيادة واحد يندكين okay الان + +218 +00:19:54,940 --> 00:20:01,210 +جبتها من وين بدأ أبدأ الترقيمحلقة صداسية و صداسية + +219 +00:20:01,210 --> 00:20:05,430 +لكن الواحد اللي من هنا بيخلي ال oxygen على نمره + +220 +00:20:05,430 --> 00:20:09,410 +اتنين الواحد اللي من هنا بيخلي ال oxygen على نمره + +221 +00:20:09,410 --> 00:20:13,350 +اربعة الواحد اللي من هنا بيخلي ال oxygen اعلى كتير + +222 +00:20:13,350 --> 00:20:17,110 +الواحد اللي من هنا هيك بيخليه اعلى كتير بدي اقل + +223 +00:20:17,110 --> 00:20:20,590 +oxygen طالما كل شيء متساوي ولذلك تم الاختيار + +224 +00:20:20,590 --> 00:20:26,360 +السليم ان الواحد من هنا1,2,3,4,5,6 طبعا هنا مافيش + +225 +00:20:26,360 --> 00:20:32,240 +فرق في الاحتمالات بأي طرق بنمشي إذا هنا صار 2 أجزا + +226 +00:20:32,240 --> 00:20:39,970 +Spyro 55 يون دي كيل أو يون دي كيلهي مثال تاني + +227 +00:20:39,970 --> 00:20:45,710 +الحلقات اللي موجودين عنده حلقة خماسية و خماسية + +228 +00:20:45,710 --> 00:20:49,910 +يعني هيحطوا أربعة و أربعة سباير و four five و four + +229 +00:20:49,910 --> 00:20:56,350 +four و بدي أزيد عليهم واحد لونين الآن لما بدي أجي + +230 +00:20:56,350 --> 00:21:03,550 +أرقم هذه خماسية و هذه خماسيةهذه فيها Oxygen و + +231 +00:21:03,550 --> 00:21:06,110 +Carbon وهذه فيها Sulphur و Carbon مين اللي هتعطيها + +232 +00:21:06,110 --> 00:21:10,310 +الأولوية ال Oxygen فهقول واحد اتنين تلاتة أربعة + +233 +00:21:10,310 --> 00:21:16,690 +خمسة وصلت خمسة ممكن أنزل هيك ستة أو هيك ستة على ال + +234 +00:21:16,690 --> 00:21:21,710 +heteroatom أقل ما يمكن ولذلك هذا بيصير one أجزة + +235 +00:21:21,710 --> 00:21:30,130 +six thiospyro four four نونين ناخد + +236 +00:21:30,130 --> 00:21:39,640 +كمان مثالالمثال اللي عندنا هذا واضح انه بسيط فيه + +237 +00:21:39,640 --> 00:21:46,060 +فرق في الحلقات خماسية و سداسية اذا الحيبان عنده + +238 +00:21:46,060 --> 00:21:55,050 +اربعة و خمسة Spyro four five Dickفي double bond + +239 +00:21:55,050 --> 00:22:02,110 +حيصير دي كيلو لو تانو تنتن دي try eel لكن موقع ال + +240 +00:22:02,110 --> 00:22:07,160 +eelيتبع الترقيم العام بدي أصبر عليه شوية الان في + +241 +00:22:07,160 --> 00:22:12,320 +الترقيم العام يجب ان ابدأ من الحلقة الأصغر عندي + +242 +00:22:12,320 --> 00:22:15,880 +oxygen و carbon اكيد هقول oxygen one two three + +243 +00:22:15,880 --> 00:22:20,620 +four five الان بعد هي carbon و carbon لكن اذا + +244 +00:22:20,620 --> 00:22:24,520 +اتحركنا بهذا الشكل انا بخلي ال double bond اقل ما + +245 +00:22:24,520 --> 00:22:31,520 +يمكن واضح ال double bond اقل ما يمكن اللي هيستة + +246 +00:22:31,520 --> 00:22:37,100 +واضح وبناء على ذلك بأعمل بهذا الشكل حيث أن عندي + +247 +00:22:37,100 --> 00:22:44,340 +one أجزاس بايرو four five ديك six إين يعني الإين + +248 +00:22:44,340 --> 00:22:50,030 +أو ال double point وين موجودة على نمرة ستةالان بدو + +249 +00:22:50,030 --> 00:22:55,250 +يظل في بالكم شغلة انه هذه القواعد بناخدها مرتبة + +250 +00:22:55,250 --> 00:23:00,930 +يعني ال double bond مابتسبقش ال hetero atom ال + +251 +00:23:00,930 --> 00:23:03,790 +double bond مابتسبقش ال hetero atom في انها تحدد + +252 +00:23:03,790 --> 00:23:08,710 +المواقع هذا المثال اللي بعد بيجيب تطبيق مباشر على + +253 +00:23:08,710 --> 00:23:12,130 +هذه النقطة يعني احنا عندنا حلقة خماسية و سوداسية + +254 +00:23:12,130 --> 00:23:19,070 +اذا كتبنا four five اثبار و four fiveDouble point + +255 +00:23:19,070 --> 00:23:23,610 +لكين لكن وين ال in الان من هنا الترقيم من الحلقة + +256 +00:23:23,610 --> 00:23:28,290 +الأصغر واحد اتنين تلاتة اربعة خمسة الان عند الخمسة + +257 +00:23:28,290 --> 00:23:33,920 +وقفتهل يا تورا بدي اروح اخلي ال hetero atom اقل ما + +258 +00:23:33,920 --> 00:23:36,740 +يمكن ولا ال double bond اقل ما يمكن الجواب + +259 +00:23:36,740 --> 00:23:39,900 +بالتأكيد ال hetero atom اذا ال hetero atom بتحل + +260 +00:23:39,900 --> 00:23:43,180 +المشكلة مابتطلعش على ال double bond ولذلك حطينا + +261 +00:23:43,180 --> 00:23:47,960 +ستة اللي تخلي ال hetero atom اقل ما يمكن فضمن هذا + +262 +00:23:47,960 --> 00:23:52,920 +الكلام لما صار six oxaspiro four five dick بداية + +263 +00:23:52,920 --> 00:23:57,700 +ال double bond وين صارت؟ عند تسعة فصار عند nine in + +264 +00:23:58,510 --> 00:24:02,750 +فإذا كان التنافس بينكم في تحديد المواقع بين + +265 +00:24:02,750 --> 00:24:08,460 +الهيتيرو أتم وبين ال double bondالهيتيرو اتم او لا + +266 +00:24:08,460 --> 00:24:12,300 +طبعا لاحظوا هنا انه انا باتعامل مع المركبات هذه + +267 +00:24:12,300 --> 00:24:16,800 +على اساس انه كأنها ال can's و جد ما بنوجد double + +268 +00:24:16,800 --> 00:24:20,500 +bonds بحددهم يعني واحدة double bond اين تنتين + +269 +00:24:20,500 --> 00:24:24,320 +تتراين تتراين تتراين مابيجيش عندى قصة ال H و ال + +270 +00:24:24,320 --> 00:24:30,180 +dihydro و ما إلى ذلك انا نسبت المركب لإيش ل ال can + +271 +00:24:30,940 --> 00:24:36,040 +نسبة المركب لكين عادي وهذا ربما شفته في أول مثال + +272 +00:24:36,040 --> 00:24:38,300 +اللي هو ال hydrocarbon هذا اللي مافيش فيه hetero + +273 +00:24:38,300 --> 00:24:45,740 +atom دي cane ال cane عادي ال cane عاديبهيك تقريبا + +274 +00:24:45,740 --> 00:24:50,820 +بيكون استعرضنا فكرة لا بأس بها عن تسمية Spiro + +275 +00:24:50,820 --> 00:24:55,420 +-heterocyclic compounds وبننهي بهذا الأمر الجزء + +276 +00:24:55,420 --> 00:24:58,520 +العام اللي احنا رغبنا انه يكون موجود عندكم في + +277 +00:24:58,520 --> 00:25:01,960 +موضوع تسمية المراكبات العضوية طبعا ان شاء الله بعد + +278 +00:25:01,960 --> 00:25:07,300 +هيك هنتحول إلى تحضير المراكبات الحلقية غير + +279 +00:25:07,300 --> 00:25:08,620 +المتجانسة + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/IIbXi_hIr50_postprocess.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/IIbXi_hIr50_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..c85bd7fb121dce67234766480ead03023fa818f1 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/IIbXi_hIr50_postprocess.srt @@ -0,0 +1,3276 @@ +1 +00:00:21,110 --> 00:00:26,070 +بسم الله الرحمن الرحيم اليوم بنكمل في موضوع تسمية + +2 +00:00:26,070 --> 00:00:30,610 +المراكبات الحلقية بعد ما اتعلمنا تسمية الحلقات + +3 +00:00:30,610 --> 00:00:36,380 +المنفردةIbn Jilah تسميت أكثر من حلقة الآن أكثر من + +4 +00:00:36,380 --> 00:00:40,160 +حلقة ممكن يتصلوا مع بعض الطريق تاني يعني لو + +5 +00:00:40,160 --> 00:00:45,420 +افترضنا مثلا أنه هذه حلقة و هذه حلقة تمام ممكن + +6 +00:00:45,420 --> 00:00:50,380 +يتصلوا بهذا الشكل من خلال رابطة طبعا معنى من خلال + +7 +00:00:50,380 --> 00:00:54,260 +رابطة من خلال ذرتين في هذه الحالة بيقول عنهم fused + +8 +00:00:54,260 --> 00:00:59,810 +rings وممكن يتصلوا فقط من خلال ذرة واحدةوالذرة + +9 +00:00:59,810 --> 00:01:02,750 +الواحدة لا يمكن الا انها تكون carbon ليش لان ال + +10 +00:01:02,750 --> 00:01:07,310 +carbon اللى بتحتمل اربع روابط فبنسميهم Spiro + +11 +00:01:07,310 --> 00:01:12,850 +compounds طبعا احنا هنبدأ في ال fused rings كيف + +12 +00:01:12,850 --> 00:01:17,410 +نسميهم الان هذه ring الف وهذه باه الاسم بدى يكون + +13 +00:01:17,410 --> 00:01:24,330 +خليط من الحلقتين تماما زى ما طالب الكيميابيدرس + +14 +00:01:24,330 --> 00:01:28,550 +الكيميا مع الفيزيا مخلوطين مع بعض فبنطلع ال course + +15 +00:01:28,550 --> 00:01:34,230 +اسمه physical chemistry الان هنا ممكن يتبادر سؤال + +16 +00:01:34,230 --> 00:01:38,670 +للذهن طب يا تورا physical chemistry يعني عيلته + +17 +00:01:38,670 --> 00:01:45,480 +chemistry ولا chemical physics؟ما بيصير وجهات نظر + +18 +00:01:45,480 --> 00:01:49,780 +وعشانك حتى في العلم في المجلة اللي أكتر بتركز على + +19 +00:01:49,780 --> 00:01:52,920 +الكيميا بنسميها journal of physical chemistry و + +20 +00:01:52,920 --> 00:01:56,520 +اللي بتركز أكتر على الفيزيا journal of chemical + +21 +00:01:56,520 --> 00:02:02,370 +physics يعني الشغلتين موجودينالان لما انا بدى اسمي + +22 +00:02:02,370 --> 00:02:08,870 +مركب ايضا يكون Spiro بحلقتين هى بنزين وهى على سبيل + +23 +00:02:08,870 --> 00:02:12,890 +المثال اكزازول هى الحلقتين هدوله هل يا تورا هذا + +24 +00:02:12,890 --> 00:02:18,730 +بدى اعمله بنزو اكزازول ولا بدنا نعمله اكزازول و + +25 +00:02:18,730 --> 00:02:23,830 +بنزين بمعنى مين بده تكون ال prefixاللي بتيجي في + +26 +00:02:23,830 --> 00:02:28,510 +الأول و بنحط لها حرف ال O و مين بده تكون ال base + +27 +00:02:28,510 --> 00:02:33,450 +component ربما هذه الجزئية من أصعب الجزئيات في هذا + +28 +00:02:33,450 --> 00:02:37,990 +الموضوع انه لما نشوف الحلقة تانية نقدر نعرف مين ال + +29 +00:02:37,990 --> 00:02:43,230 +prefix و مين ال base component هذه الشغلة الأولى + +30 +00:02:43,230 --> 00:02:47,950 +اللي بدنا نتعلمها واضحة هذه النقطة بعد ما نتعلمها + +31 +00:02:47,950 --> 00:02:53,950 +بتصير الأمور أسهلبناخد احنا قواعد انحدد من خلالها + +32 +00:02:53,950 --> 00:02:58,650 +ال base component هذه مجموعة من القواعد يجب ان + +33 +00:02:58,650 --> 00:03:04,470 +تطبق مرتبة بمعنى بنجي على القاعدة الأولى بنشوفها + +34 +00:03:04,470 --> 00:03:08,130 +بنقدر من خلالها انحدد ال base component اذا قدرنا + +35 +00:03:08,130 --> 00:03:12,630 +من خلالها انحدد مابنروحش للقاعدة التانية والتالتة + +36 +00:03:13,540 --> 00:03:17,940 +خطأ إن أطبق القاعدة التالتة أو الرابعة إذا كانت + +37 +00:03:17,940 --> 00:03:22,100 +القاعدة الأولى أو التانية بتحل المشكلة عنده ولذلك + +38 +00:03:22,100 --> 00:03:27,480 +لما هناخد سبع قواعد مش هيكون مطلوب مننا نحفظ السبع + +39 +00:03:27,480 --> 00:03:33,970 +قواعدمطلوب مننا نحفظ السبع قواعد بالترتيب، أن هذه + +40 +00:03:33,970 --> 00:03:37,910 +هي القاعدة الأولى، هذه التانية، هذه التالتة، هذه + +41 +00:03:37,910 --> 00:03:42,210 +الرابعة، اللي بنحل بالقاعدة التانية، ممكن كمان يحل + +42 +00:03:42,210 --> 00:03:47,230 +بالرابعة، طب أي الحلين اللي بدي استعمل؟ القاعدة + +43 +00:03:47,230 --> 00:03:51,730 +التانية، مش الرابعة، ولذلك هذه القواعد لتحديد ال + +44 +00:03:51,730 --> 00:03:57,820 +base component، يجب أن تُأخذ مرتبةقواعد بسيطة + +45 +00:03:57,820 --> 00:04:02,240 +القاعدة الأولى بتقولنا الآتي إذا اطلعتوا على + +46 +00:04:02,240 --> 00:04:06,160 +الحلقات لجيتوا واحدة منهم بتحتوي على نيتروجين + +47 +00:04:06,160 --> 00:04:10,220 +والتانية لأ بغض النظر كده عدد ال نيتروجين فاللي + +48 +00:04:10,220 --> 00:04:13,580 +بناخدها ال base component اللي بتحتوي على ال + +49 +00:04:13,580 --> 00:04:20,880 +نيتروجين الآن كتطبيق هي بنزين وهي أكزازولالان مين + +50 +00:04:20,880 --> 00:04:25,280 +اللى فيها نيتروجين؟ الـ Oxazole إذا ال Oxazole + +51 +00:04:25,280 --> 00:04:29,360 +base component البنزين بتيجي ال prefix فالمركب + +52 +00:04:29,360 --> 00:04:37,460 +بيصير ايش؟ Benzo Oxazole واضح؟ امشينا الان ابتجينا + +53 +00:04:37,460 --> 00:04:41,600 +القاعدة التانية طب لو يا ترى كان عندى حلقتين مافيش + +54 +00:04:41,600 --> 00:04:47,320 +فيهم نيتروجين مين بدنا نختار؟ هاي مثال هاي ثيوفين + +55 +00:04:48,510 --> 00:04:53,850 +ثيوفين وفيوران ومافيش فيهم نيتروجين مين بده نختار + +56 +00:04:53,850 --> 00:04:57,630 +الحلقة اللي فيها ال oxygen مفضلة على الحلقة اللي + +57 +00:04:57,630 --> 00:05:01,870 +فيها الكبريت ولذلك اللي فيها ال oxygen الفيوران + +58 +00:05:01,870 --> 00:05:06,660 +بنختارها base componentالان اللى فيها ال sulfur + +59 +00:05:06,660 --> 00:05:12,040 +بتصير ال prefix فهذا بنسميه احنا ثيينو إفيوران + +60 +00:05:12,040 --> 00:05:17,420 +الآن بدنا ننتبه بعض الحلقات لما بتيجي في ال prefix + +61 +00:05:17,420 --> 00:05:22,960 +مابتكونش باسمها الكامل مضاف ال o بنعمل فيها تحوير + +62 +00:05:22,960 --> 00:05:27,900 +بسيط يعني مثلا ال oxazole لو اجت prefixبتصير + +63 +00:05:27,900 --> 00:05:33,160 +OXAZOLO ماغيرناش عليها غير إن زدنا عليها O لكن بعض + +64 +00:05:33,160 --> 00:05:37,420 +الحلقات بنغير فيها شوية الآن هذه الحلقات اللي + +65 +00:05:37,420 --> 00:05:43,260 +بنغير فيها شوية مار علينا واحدة منها البنزين ما + +66 +00:05:43,260 --> 00:05:52,240 +بنقولش بنزينو بنقول بنزو نضلنا إيش متذكرينها الآن + +67 +00:05:52,240 --> 00:06:02,780 +الثيوفينما بنقولش sayofino، بنقول sayino الفيران، + +68 +00:06:02,780 --> 00:06:07,640 +لو إجانا في المقدمة، ما بنقولش fiorano، بنقول + +69 +00:06:07,640 --> 00:06:13,040 +fioro البردين، + +70 +00:06:13,040 --> 00:06:18,040 +لو إجانا في المقدمة، بنقولش beridino، بنقول berido + +71 +00:06:20,220 --> 00:06:24,980 +واضح؟ الاميدازول لو اجينا في المقدمة ما بنقولش + +72 +00:06:24,980 --> 00:06:27,720 +اميدازولو اميدازو + +73 +00:06:29,390 --> 00:06:34,990 +ولو مرمعنا أشياء شهيرة بنحكيها لكن بالمجمل مثلا + +74 +00:06:34,990 --> 00:06:39,410 +الأكزازول أكزازولو الأيزوكزازول أيزوكزازولو + +75 +00:06:39,410 --> 00:06:45,010 +التريازول التريازولو التترازين تترازينو نفس الإسم + +76 +00:06:45,010 --> 00:06:50,930 +بنزيد عليه او هدولة شوية فيهم إيش تحوير وبناء على + +77 +00:06:50,930 --> 00:06:57,740 +ذلك هذا لما بنسميه بنقول عنه ثيينوif you run الان + +78 +00:06:57,740 --> 00:07:02,380 +لو طالبة منكوا اتطلعت على هذا المركب if you run و + +79 +00:07:02,380 --> 00:07:05,140 +if you feel طب نتطلع على هذا برضه if you run و if + +80 +00:07:05,140 --> 00:07:09,740 +you feel هتسميه if you run و if you feel مباشرة + +81 +00:07:09,740 --> 00:07:13,980 +بدت تظهر عندنا مشكلة انه انا لو مسكت الحلقات يا + +82 +00:07:13,980 --> 00:07:18,120 +ترى و جيت اعمل fusion صح ممكن هذا الجزء ييجي مع + +83 +00:07:18,120 --> 00:07:21,220 +هذا بس ممكن هذا ييجي مع هذا يعني ممكن نصير ال + +84 +00:07:21,220 --> 00:07:28,370 +fusion بطرق مختلفةكيف بيصير ال fusion هذا الكلام + +85 +00:07:28,370 --> 00:07:34,650 +بنوضحه بالشكل الآتي بنيجي للحلقة ال base component + +86 +00:07:34,650 --> 00:07:41,110 +وبنتخيل لو كنا احنا بنرقمها واحد اتنين تلاتة اربعة + +87 +00:07:41,110 --> 00:07:47,560 +و النقطة البداية فيها ال oxygen واحد بنمر علىحسب + +88 +00:07:47,560 --> 00:07:50,600 +قواعدنا على الـ hetero atoms أسرع ما يمكن، مافيش + +89 +00:07:50,600 --> 00:07:54,220 +hetero atoms تانية، بدنا نمر على ال fusion أسرع ما + +90 +00:07:54,220 --> 00:07:58,140 +يمكن، على موقع الاتصال كأنه أنا لو كنت هذه بدي + +91 +00:07:58,140 --> 00:08:02,700 +أرقمها، بدي أقول واحد، اتنين، تلاتة، الآن الرابطة + +92 +00:08:02,700 --> 00:08:07,740 +الأولى منها، بعطيها الحرف A، كل الرابطة، والرابطة + +93 +00:08:07,740 --> 00:08:11,880 +الثانية B، يعني هذا لو بدي أعطي حروف، هذا A، هذا + +94 +00:08:11,880 --> 00:08:20,400 +B، C، D، Eكل رابطة بعطيها حرف الان لاحظوا ال + +95 +00:08:20,400 --> 00:08:25,720 +fusion على أي رابطة جاي بيه بناء على ذلك جنب + +96 +00:08:25,720 --> 00:08:30,540 +فيوران هنا بجثين مربعين بحط بيه بمعنى ان هذه + +97 +00:08:30,540 --> 00:08:37,200 +الحلقة ارتبطت من الرابطة بيه الان باجل الحلقة + +98 +00:08:37,200 --> 00:08:42,680 +التانية باجل الحلقة التانية بعملها ترقيم مش حروف + +99 +00:08:43,480 --> 00:08:49,800 +اللي هي ال prefix، الآن لمبدأ رقم واحد، تنين، + +100 +00:08:49,800 --> 00:08:54,180 +تلاتة، أربعة، خمسة، إذا انتبهوا معي ال base + +101 +00:08:54,180 --> 00:09:01,820 +component حروف ال prefix أرقام، الآن هذه من وين + +102 +00:09:01,820 --> 00:09:08,050 +شابكة؟تلاتة اثنان خلّينا نصبر شوية لو عملنا + +103 +00:09:08,050 --> 00:09:12,830 +المراكب التالي هاي ال base component ايه بيه هذي + +104 +00:09:12,830 --> 00:09:20,320 +من وين بيهطيب، هنا لو بدي أرقم واحد، اتنين، تلاتة، + +105 +00:09:20,320 --> 00:09:24,220 +برضه لو سألت، من وين شابك هذه الحلقة؟ من اتنين، + +106 +00:09:24,220 --> 00:09:27,140 +تلاتة، لو بدي اكتب هنا اتنين، تلاتة، و هنا اتنين، + +107 +00:09:27,140 --> 00:09:32,400 +تلاتة، مش هيميزني المركبين، المركبين مختلفين، الآن + +108 +00:09:32,400 --> 00:09:36,200 +بنيجي بنقول القاتل، كيف اتحركنا و احنا بنذكر + +109 +00:09:36,200 --> 00:09:40,880 +الحروف؟ اتحركنا بهذا الشكل A B، هي اتجاه الحركة + +110 +00:09:40,880 --> 00:09:46,710 +تبعتناصحيح ولا لأ؟ الان الأرقام بنذكرها بنفس + +111 +00:09:46,710 --> 00:09:52,850 +الاتجاه بنخل الأرقام تتبع الاتجاه نفسه بناء على + +112 +00:09:52,850 --> 00:09:57,170 +ذلك هنا ال fusion ايش بنكتب باله؟ تلاتة اتنين + +113 +00:09:57,170 --> 00:10:04,150 +فبصير هذا فينو ثري فاصمة تو و بنحط شرطة بفيوران + +114 +00:10:04,150 --> 00:10:11,510 +الان لو المركب التاني اتيت بدي اعمله هاي حركتي a b + +115 +00:10:15,130 --> 00:10:23,190 +لما بدي الأرقام بنفس الاتجاه اتنين تلاتة اذا هذا + +116 +00:10:23,190 --> 00:10:30,870 +المركب ثيينو ثري تو بي فيوران هداك ثيينو تو ثري بي + +117 +00:10:30,870 --> 00:10:34,530 +فيوران لاحظوا هذه الحركة البسيطة خلتني اميز بين + +118 +00:10:34,530 --> 00:10:40,350 +المركبين الان كان واحدة ممكن تسأل سؤالتقول طب احنا + +119 +00:10:40,350 --> 00:10:44,770 +لو استعملنا هنا حروف كان حاطينا هنا حروف بالمرة و + +120 +00:10:44,770 --> 00:10:49,430 +خلينا نقول ان الحرف اللي هنا بيحددلي مكان الفيوران + +121 +00:10:49,430 --> 00:10:54,330 +و الحرف اللي هنا مكان اتصال الثيوفينلو جربنا نعمل + +122 +00:10:54,330 --> 00:10:58,990 +هالكلام، هنقول a, b، كان بدنا نكتب b, b، و لو + +123 +00:10:58,990 --> 00:11:02,890 +جربنا نعملها، هنقول a, b، هنكتب b, b، ماقدرناش + +124 +00:11:02,890 --> 00:11:07,370 +نميز، لأن الحرف مالوش نقطة بداية و نقطة نهاية، لكن + +125 +00:11:07,370 --> 00:11:11,110 +الأرقام اللي هم بداية و نهاية، أنه نقول three, two + +126 +00:11:11,110 --> 00:11:17,380 +غير أنه نقول two, threeوبهذا الشكل الآن تقريبا كل + +127 +00:11:17,380 --> 00:11:21,920 +مرة بنصير لما نحدد ال base component من باب + +128 +00:11:21,920 --> 00:11:25,760 +التدريب نحدد الحرف اللي متصله من خلال ال base + +129 +00:11:25,760 --> 00:11:30,460 +component والأرقام اللي متصلين من خلالهم او اللي + +130 +00:11:30,460 --> 00:11:35,500 +متصل من خلاله ال prefix بهيك بيصير الاسم كامل + +131 +00:11:35,500 --> 00:11:41,640 +لاحظوا معي ملاحظة انه احنا لما كتبنا هنا الحروفو + +132 +00:11:41,640 --> 00:11:46,900 +كتبنا هنا الأرقام كنا ننظر لكل حلقة كأنها واحدة + +133 +00:11:46,900 --> 00:11:50,260 +واحدة يعني كأن امرقم هذي واحد اتنين تلاتة اربعة + +134 +00:11:50,260 --> 00:11:54,000 +خمسة هذي واحد اتنين تلاتة اربعة خمسة كأنها واحدة + +135 +00:11:54,000 --> 00:11:59,560 +واحدة الان لو بعدك بدي اتخيل لو بعدك بدي اتخيل ان + +136 +00:11:59,560 --> 00:12:06,030 +انا على الجزء حطيت هنا مثلا CH3كيف بتحدد موقعها + +137 +00:12:06,030 --> 00:12:11,690 +تحديد موقع ال substituents بما في ذلك ال H لأنه + +138 +00:12:11,690 --> 00:12:14,970 +بنعتبرها substituent ال saturated atom او ال + +139 +00:12:14,970 --> 00:12:20,470 +dihydro او ما إلى ذلك هذا بيتبع نظام ترقيم تاني + +140 +00:12:20,470 --> 00:12:25,450 +ليس له علاقة بهذا بنعمل نظام تاني بنتعلمه بعد ما + +141 +00:12:25,450 --> 00:12:29,110 +ننتهي من هذا الموضوع هذا النظام التاني بلف حوالين + +142 +00:12:29,110 --> 00:12:36,550 +الجزيء كله بطريقة معينة وبالتالي بصيرفي عندى هدولة + +143 +00:12:36,550 --> 00:12:41,130 +ناشئين من الترقيم الداخل اللى هان هذه ناشئة من وصف + +144 +00:12:41,130 --> 00:12:45,170 +الحروف الداخل اللى هان بعد هيك لما انا بدى اعمل + +145 +00:12:45,170 --> 00:12:48,250 +ترقيم هادي substituent هان هان substituent هان + +146 +00:12:48,250 --> 00:12:54,270 +substituent بده يلزمني لكل النظام ترقيم كامل الوف + +147 +00:12:54,270 --> 00:12:58,450 +حوالي كل الجزء هذا بنتعلم بعدين ولذلك الان مش + +148 +00:12:58,450 --> 00:13:02,980 +هتشوفوا substituents هتشوفوافقط هذا الجزء من الإسم + +149 +00:13:02,980 --> 00:13:08,260 +اللى بيوضح للحلقات وكيف اوضح ال fusion لما نتقد + +150 +00:13:08,260 --> 00:13:14,140 +هالكلام بنتعلم نظام الترقيم الشامل اللى بيلوف + +151 +00:13:14,140 --> 00:13:19,560 +حوالين كل الجزية عشانك اريحلنا تطبيقيا ان هذه + +152 +00:13:19,560 --> 00:13:25,000 +الحروف و هذه الأرقام نكتبها في داخل الحلقات ليش؟ + +153 +00:13:25,000 --> 00:13:29,180 +لأن هذا المكان الخارجي بعد شوية هححط عليه أرقام + +154 +00:13:29,180 --> 00:13:35,590 +جديدةيعني مثلا في هذا الجزء هأكتب واحد اتنين تلاتة + +155 +00:13:35,590 --> 00:13:41,470 +تلاتة prime أربعة خمسة ستة ستة prime هيصف بهذا + +156 +00:13:41,470 --> 00:13:45,930 +الشكل قواعد هذا الترقيم نتعلمها بعدين ولذلك أنا + +157 +00:13:45,930 --> 00:13:49,190 +دائما بنصح الطلاب و الناس اللي بتعلمه يحطوا الحروف + +158 +00:13:49,190 --> 00:13:52,370 +هنا في داخل الحلقة هذه الأرقام اللي وضحت ال fusion + +159 +00:13:52,370 --> 00:13:57,760 +في داخل هذه الحلقة لأنه بعد هيك هيجينيترقيم شامل + +160 +00:13:57,760 --> 00:14:02,100 +الان وجدت لو حطيت هنا مثلهان اثلهان فنلهان كذا كله + +161 +00:14:02,100 --> 00:14:10,280 +بقدر اضيفه واضح الفكرة؟ هذه تقريبا هي الصورة + +162 +00:14:10,280 --> 00:14:14,340 +الكلية اللي بدو يكون عليها تسمية ال fuse rings + +163 +00:14:14,340 --> 00:14:19,260 +الان هي عنده كام قاعدة مرة علينا؟ تنتين الان + +164 +00:14:19,260 --> 00:14:26,660 +القاعدة التالتة طب يا ترىلو ما نحلتش مشكلتنا في + +165 +00:14:26,660 --> 00:14:30,980 +القاعدة الأولى والتانية هنا بتكون تنتبهوا معي ان + +166 +00:14:30,980 --> 00:14:35,040 +الأشياء اللى أخدناها مكونة من حلقتين بنعتبرها قطعة + +167 +00:14:35,040 --> 00:14:40,420 +واحدة one component يعني أخدنا احنا ال Indol كاسم + +168 +00:14:41,140 --> 00:14:46,120 +أخدنا الـ Isoindole أخدنا الكوينولين أخدنا ال + +169 +00:14:46,120 --> 00:14:51,940 +Isoquinoline هدولة بنعملهم إيش؟ كوحدة واحدة ولذلك + +170 +00:14:51,940 --> 00:14:56,160 +هذا المركب اللي موجود الآن أمامي لو أنا بدي أجي + +171 +00:14:56,160 --> 00:15:02,220 +بقول هاي وحدة فيه ال Indole هاي وحدة تانيةالـ By + +172 +00:15:02,220 --> 00:15:05,760 +Rule لو أنا بدأ أطبق القواعد القاعدة الأولى بتقول + +173 +00:15:05,760 --> 00:15:09,120 +إذا واحدة من الوحدتين فيها نيتروجين اختارها + +174 +00:15:09,120 --> 00:15:13,940 +التنتين فيهم نيتروجين إذا القاعدة الأولى مانفعتش + +175 +00:15:13,940 --> 00:15:17,060 +القاعدة التانية بتقول إذا مافيش فيهم نيتروجين + +176 +00:15:17,060 --> 00:15:21,080 +اختارها التنتين فيهم نيتروجين التانية مانفعتش الآن + +177 +00:15:21,080 --> 00:15:25,260 +القاعدة التالتة بتقول للآتة if one component + +178 +00:15:25,260 --> 00:15:30,330 +consists of two or more rings it choose itهذه ال + +179 +00:15:30,330 --> 00:15:33,490 +component من حلقتين هذه ال component من حلقة + +180 +00:15:33,490 --> 00:15:37,870 +فبختار ال component اللي من حلقتين واضح الفكرة + +181 +00:15:37,870 --> 00:15:44,770 +طبعا هذه ال component لها اسم Indol واضح؟ و هذه + +182 +00:15:44,770 --> 00:15:52,610 +Byrol فمركبه بيصير Byrol و Indol الآن لو بدي بسرعة + +183 +00:15:52,610 --> 00:15:58,940 +أحط لحروف أكيد عندي هنا ايه؟بأكيد عندي هانا one + +184 +00:15:58,940 --> 00:16:03,400 +two three اذا هذه ال base component شابكة من وين + +185 +00:16:03,400 --> 00:16:11,000 +من بيه بنفس الاتجاه اذا هذا by rollo two three بي + +186 +00:16:11,000 --> 00:16:17,400 +ان دول الارقام + +187 +00:16:17,400 --> 00:16:22,880 +بتتبع ايشو عشان هيك الناس اللي متعودين يكتبوا + +188 +00:16:22,880 --> 00:16:25,560 +التسمية و يجاوبوا على سؤال التسمية دول اللي دايما + +189 +00:16:25,560 --> 00:16:29,380 +بيغلطوا مالهمش حظ في الدنيا اللي بيسموا أي مركب من + +190 +00:16:29,380 --> 00:16:36,880 +قدام لورا دائما التسمية تبدأ من الخلف للأمام يعني + +191 +00:16:36,880 --> 00:16:41,520 +لو واحدة قاعدة بتسمي هذا المركب ايش اول اشي لازم + +192 +00:16:41,520 --> 00:16:45,700 +تجيبه ال base component لما تجيبها بدأت تكتب ان + +193 +00:16:45,700 --> 00:16:51,640 +دولبعدين بتحط payroll الان ايش اول اشي بتجيبه ال + +194 +00:16:51,640 --> 00:16:57,180 +اندول من وين شابك بيه بعد ما تحط بيه و اتجاه ال + +195 +00:16:57,180 --> 00:17:02,820 +بيه اتنين و تلاتة بيتبعوا ال بيه واضح؟ لو كانت ال + +196 +00:17:02,820 --> 00:17:05,860 +nitrogen هنا قعدت واحد اتنين تلاتة كانت هتكتب + +197 +00:17:05,860 --> 00:17:10,620 +تلاتة اتنينهتعكس و لذلك واحدة تيجي بدأ تبدأ هذا + +198 +00:17:10,620 --> 00:17:14,780 +التسمية انها تكتب الرقمين هدولة قبل ما تكتب الحرف + +199 +00:17:14,780 --> 00:17:19,500 +هذا عمرا مابتنش صعب اما هدول الرقمين تبعين للحرف + +200 +00:17:19,500 --> 00:17:26,450 +واضح فالتسمية دائما لما بنفهم جيدا من وين بتبدأمن + +201 +00:17:26,450 --> 00:17:30,690 +الخلف للأمام وهذا من وجه نظري أنا دائما في ال + +202 +00:17:30,690 --> 00:17:33,770 +organic chemistry اللي لازم تكونوا فاهمينه الآن + +203 +00:17:33,770 --> 00:17:41,030 +افهمنا هذا المثال طيب اجينا على هذا المركب لاحظوا + +204 +00:17:41,030 --> 00:17:44,350 +بدي اطبق عليه القواعد القاعد الأولى one contains + +205 +00:17:44,350 --> 00:17:49,630 +nitrogen both contain nitrogenالقاعدة التانية لو + +206 +00:17:49,630 --> 00:17:52,890 +مافيش نيتروجين بصيرش القاعدة التالتة لو واحدة فيها + +207 +00:17:52,890 --> 00:17:56,930 +اكتر من component لأ هذا one component و هذا one + +208 +00:17:56,930 --> 00:18:02,670 +component وقتها بروح للقاعدة الرابعة القاعدة + +209 +00:18:02,670 --> 00:18:07,290 +الرابعة بتقول if you have two rigs of different + +210 +00:18:07,290 --> 00:18:12,770 +size choose the larger اذا عندك حلقات من حجم مختلف + +211 +00:18:12,770 --> 00:18:22,250 +اختار الأكبرالان هذه سوداسية و هذه خماسية من اللي + +212 +00:18:22,250 --> 00:18:29,150 +بدأ اختارها السوداسية بيريدين الخماسية بايرول اذا + +213 +00:18:29,150 --> 00:18:36,010 +بايرول و بيريدين و لما تحط الحروف بي بي بهذا + +214 +00:18:36,010 --> 00:18:40,770 +الاتجاه الان لما نرقم واحد اتنين تلاتة اذا هذا + +215 +00:18:42,950 --> 00:18:51,010 +تلاتة بي بيرولو تو ثري بي بيريدين بيرولو تو ثري بي + +216 +00:18:51,010 --> 00:18:58,190 +بيريدين واضح؟ اذا هذه القاعدة اي قاعدة الرابعة + +217 +00:18:58,190 --> 00:19:03,230 +خليني اعطيكم مثال صغير جدا عشان تعرفوا ان القواعد + +218 +00:19:03,230 --> 00:19:07,930 +يجب ان تطبقوها بالترتيب يعني مثلا لو انا كنت + +219 +00:19:07,930 --> 00:19:10,450 +جايبلكم هذا المثال + +220 +00:19:15,160 --> 00:19:20,940 +و واحدة قالت إذا عندي حلقتين اختارت الأكبر وجدت + +221 +00:19:20,940 --> 00:19:25,000 +إيش هتختار ال base component؟ هذه هتكون على طول + +222 +00:19:25,000 --> 00:19:30,700 +ارتكبة خطأ ليش؟ لأن القاعدة الأولى بتقول إذا واحدة + +223 +00:19:30,700 --> 00:19:34,140 +فيها نيتروجين والتانية لا اختار الأولى لأن القاعدة + +224 +00:19:34,140 --> 00:19:40,280 +الأولى حلت المشكلة ماوصلتش ل 4واضح؟ ماتيجيش واحدة + +225 +00:19:40,280 --> 00:19:44,640 +تقول انت علمتنا انه اختار الحلقة الأكبر انا صح + +226 +00:19:44,640 --> 00:19:49,340 +علمتك اختار الحلقة الأكبر كالقاعدة رابعة لما ما + +227 +00:19:49,340 --> 00:19:52,580 +تحلش مشكلتك القاعدة الأولى و التالية و التالتة و + +228 +00:19:52,580 --> 00:19:55,420 +الرابعة لكن هنا في القاعدة الأولى هذه فيها + +229 +00:19:55,420 --> 00:19:57,680 +نيتروجين هذه مش فيها نيتروجين which is the best + +230 +00:19:57,680 --> 00:20:02,280 +component؟ اللي فيها ال nitrogen واضح الفكرة؟ + +231 +00:20:02,280 --> 00:20:07,480 +عشانك انا بقول مائة مرة اهتموا بهذه القواعد حسب + +232 +00:20:11,180 --> 00:20:18,520 +الآن نجي لمثال جديدلو طلعنا على هذا المثال و بدنا + +233 +00:20:18,520 --> 00:20:22,280 +نختار ال base component لاحظوا حسب القاعدة الأولى + +234 +00:20:22,280 --> 00:20:26,600 +التلتين فيهم nitrogen التانية والتالتة مش موضوعنا + +235 +00:20:26,600 --> 00:20:29,440 +القاعدة الرابعة بتقول لو واحدة أكبر من التانية + +236 +00:20:29,440 --> 00:20:34,200 +التلتين خماسيات لحد الان ماحلناش المشكلة الان + +237 +00:20:34,200 --> 00:20:37,580 +بتجينا القاعدة الخامسة ات choose the one with more + +238 +00:20:37,580 --> 00:20:42,750 +hetero atomsالان لما بدي اجي اختار هذه فيها تنتين + +239 +00:20:42,750 --> 00:20:46,490 +hetero atoms هذه فيها one hetero atom اذا انيا + +240 +00:20:46,490 --> 00:20:49,290 +اللي بدي اخدها ال base component اللي فيها تنتين + +241 +00:20:49,290 --> 00:20:53,750 +الخمسية اللي فيها نيتروجينتين جنب بعض ال بيرازول + +242 +00:20:53,750 --> 00:21:00,670 +صار هذا بيرولو بيرازول واضح؟ الان لما بدي اعطي + +243 +00:21:00,670 --> 00:21:05,670 +حروف هاعطي A B C + +244 +00:21:07,580 --> 00:21:11,740 +A,B,C من وين هذه الشابكة؟ و هاي الاتجاه اللي عندك + +245 +00:21:11,740 --> 00:21:17,940 +لو كنت برقم من هنا واحد ايش + +246 +00:21:17,940 --> 00:21:24,800 +بدي اذكر؟ تلاتة اتنين تلاتة اتنين تلاتة اتنين C + +247 +00:21:24,800 --> 00:21:35,280 +بايرازول شوفنا كيف الآن بنيجي لمركبين جدادلحظوا + +248 +00:21:35,280 --> 00:21:38,220 +دول الاتنين لو بدنا نشوف مين ال base component + +249 +00:21:38,220 --> 00:21:45,540 +الاتنين فيهم نيتروجين والاتنين نفس الحجم والاتنين + +250 +00:21:45,540 --> 00:21:49,120 +كل واحد فيه two hetero atoms يعني القاعدة الخامسة + +251 +00:21:49,120 --> 00:21:52,540 +كمان مش ذاتة معاه two hetero atoms و two hetero + +252 +00:21:52,540 --> 00:21:56,120 +atoms الآن في هذه الحالة بقول اللي two hetero + +253 +00:21:56,120 --> 00:22:03,490 +atoms فيهم أجزاء أفضل من الأزاءواضح؟ فال أجزا أزا + +254 +00:22:03,490 --> 00:22:08,510 +أفضل أو الثايا أزا أفضل من الأزا أزا و هكذا حسب + +255 +00:22:08,510 --> 00:22:12,790 +الترتيب اللي أجزا أكتر من ثايا أكتر من أزا وبناء + +256 +00:22:12,790 --> 00:22:17,250 +على ذلك هذه الحلقة اللي هي الأجزازون هي ال base + +257 +00:22:17,250 --> 00:22:27,560 +component هذه هيالـ prefix اميدازول بتصير اميدازو + +258 +00:22:27,560 --> 00:22:33,100 +فهذا اميدازو اكزازول الان لو كنت بدعطي الحروف طبعا + +259 +00:22:33,100 --> 00:22:39,080 +اكيد انا عندي هان الواحد اتنين تلاتة اربعة خمسة + +260 +00:22:39,080 --> 00:22:47,260 +عشان هيك الحروف اللي عندي هتيجي A B C D هذا شابك + +261 +00:22:47,260 --> 00:22:57,320 +من D هذا شابك من Dالان عندى 123 و 123 بفض اللى + +262 +00:22:57,320 --> 00:23:03,000 +بيعطينا اقل ترقيم على ال fusion 12345 + +263 +00:23:03,000 --> 00:23:14,700 +اذا هذا اميدازو 45D اكزازول واضح اميدازو 45D + +264 +00:23:14,700 --> 00:23:16,520 +اكزازول + +265 +00:23:27,460 --> 00:23:35,040 +بنجي لقمان قاعدة نتطلع على هالمُركّبين الاتنين + +266 +00:23:35,040 --> 00:23:39,460 +فيهم نيتروجين والاتنين خماسيات والاتنين فيهم + +267 +00:23:39,460 --> 00:23:43,560 +ذارتين هيتيرو أتم والذارتين أكسوجين ونيتروجين + +268 +00:23:43,560 --> 00:23:48,470 +وأكسوجين ونيتروجينوقتها بقول هنا ال oxygen و ال + +269 +00:23:48,470 --> 00:23:52,170 +nitrogen جايين one two هنا ال oxygen و ال nitrogen + +270 +00:23:52,170 --> 00:23:54,910 +one three ال one two مفضل على ال one three في هذه + +271 +00:23:54,910 --> 00:23:58,530 +الحالة إذا ال base component هذه اللي جانب بعض + +272 +00:23:58,530 --> 00:24:04,670 +اسمها ايزوكزازول و الإبعاد اكزازول فهذا المركب كله + +273 +00:24:04,670 --> 00:24:07,150 +بيصير اكزازولو + +274 +00:24:08,950 --> 00:24:13,810 +Isoxazole طبعا لما بدي اعطي هذا حروف one, two, + +275 +00:24:14,070 --> 00:24:22,150 +three, four, five يعني هي الحرف A, B, C, D إذا هذا + +276 +00:24:22,150 --> 00:24:26,650 +شابك ال Isoxazole من أي رابطة؟ D لما بدي أرقمها + +277 +00:24:26,650 --> 00:24:33,630 +أنا ملزم واحد, اتنين, تلاتة, أربعة, خمسة هذا بيتبع + +278 +00:24:33,630 --> 00:24:39,130 +هذاخمسة أربعة لأن هذا السبب المتحرك به هذا الاتجاه + +279 +00:24:39,130 --> 00:24:43,470 +واضحة + +280 +00:24:43,470 --> 00:24:52,030 +الأرقام تتبع الحروف إذا هذا أكزازولو five four دي + +281 +00:24:52,030 --> 00:24:59,870 +ايزوكزازولو هعندي كمان مثال على نفس القاعدةالان + +282 +00:24:59,870 --> 00:25:03,750 +هنا نيتروجين 2 و هنا نيتروجين 3 من اللي هيكون + +283 +00:25:03,750 --> 00:25:04,770 +الأولوية + +284 +00:25:08,180 --> 00:25:12,500 +BC اللي هي ال بيرازول وهذا اميدازول اذا هذا + +285 +00:25:12,500 --> 00:25:17,720 +اميدازو بيرازول ABC بهذا الاتجاه الان لو تحركنا + +286 +00:25:17,720 --> 00:25:24,320 +واحد اتنين تلاتة اربعة خمسة هذا ايش هيكون four + +287 +00:25:24,320 --> 00:25:31,580 +five C بيرازول اذا هذا اميدازو four five C بيرازول + +288 +00:25:31,580 --> 00:25:35,960 +اميدازو four five C بيرازول + +289 +00:25:38,220 --> 00:25:42,960 +واضح تماما ان هذه القواعد الأساسية بتخدمكم بشكل + +290 +00:25:42,960 --> 00:25:48,940 +كافي لعمل او تسمية ال fuse drinks اكيد بيلزم امثلة + +291 +00:25:48,940 --> 00:25:53,460 +اضافية احنا نحلها لكن لكل مجتهد نصيب جد ما بتطلعوا + +292 +00:25:53,460 --> 00:25:56,240 +في المجلات جد ما بتطلعوا في الكتب جد ما بتحلوا + +293 +00:25:56,240 --> 00:26:03,120 +مسائل جد ما بيصير عندكم ايشخبرة و بتستفيدوا هذا + +294 +00:26:03,120 --> 00:26:07,300 +موضوع تحديد الحروف والارقام بتاية ليه وضحناه في كل + +295 +00:26:07,300 --> 00:26:16,000 +الأمثلة الان بإمكاننا ناخد أمثلة موجودة عندنا لكن + +296 +00:26:16,000 --> 00:26:21,940 +خلينا نأجلها لحد ما ناخد كمان كيف بنعمل الترقيم + +297 +00:26:21,940 --> 00:26:26,570 +الخارجي عشان لما ناخد مثالنستكمل التسمية تبعته + +298 +00:26:26,570 --> 00:26:31,690 +كامل يعني نعمله تحديد ال base component تحديد ال + +299 +00:26:31,690 --> 00:26:39,750 +prefix تحديد مواقع الاتصال و نظام الترقيم الخارجي + +300 +00:26:39,750 --> 00:26:46,090 +تبعه الآن كيف بنرقم مجموعة من الحلقات الترقيم + +301 +00:26:46,090 --> 00:26:52,400 +الشامل الكل اللي بيلف حوالين إيش الحلقاتبدنا نعمل + +302 +00:26:52,400 --> 00:26:58,620 +الآتي نتخيل أنه في عندنا rectangular coordinates + +303 +00:26:58,620 --> 00:27:03,980 +المحاور هذه ال X و ال Y الآن بدنا نجيب الجزئ تبعنا + +304 +00:27:03,980 --> 00:27:10,840 +نحط أكبر ما يمكن من الحلقات فيه على الخط الأفقي + +305 +00:27:10,840 --> 00:27:14,160 +يعني لاحظوا هيك في عندنا أربع حلقات هنا طالعين + +306 +00:27:14,160 --> 00:27:20,020 +تلاتة الأربعة أين خليتهم؟ على الخط الأفقيالان ما + +307 +00:27:20,020 --> 00:27:26,520 +زاد بنحطه في الربع اللي هان لأعلى يعني مالحطوش لا + +308 +00:27:26,520 --> 00:27:30,580 +تحت ولا بنحطه هان بهذا الشكل بدأ اتخيل ان انا + +309 +00:27:30,580 --> 00:27:36,140 +بامسك الجزء لما اعمل كل هذا الكلام بدأ ابدأ ارقم + +310 +00:27:36,140 --> 00:27:41,040 +من بعد الخط الأفقي من أول حلقة وامشي معاه قارب + +311 +00:27:41,040 --> 00:27:44,260 +الساعة يعني هذه الخط الأفق خلصت هذه الحلقات اللي + +312 +00:27:44,260 --> 00:27:49,560 +طالعة واحدكل carbon بتاخد شرقك بتاخد اللي قبلها + +313 +00:27:49,560 --> 00:27:55,520 +ماخد شرطة او ايه يعني هذا ال carbon ال fusion one + +314 +00:27:55,520 --> 00:28:02,480 +one ايه او one prime one one ايه او بيسبوها مرات + +315 +00:28:03,400 --> 00:28:08,280 +تفهم منها one a لو عليها substitute one one a two + +316 +00:28:08,280 --> 00:28:15,240 +three four five five a six six a seven eight + +317 +00:28:15,240 --> 00:28:20,020 +لاحظوا ال hetero atom بتاخد رقم متاخدش a لو اجت ال + +318 +00:28:20,020 --> 00:28:26,260 +hetero atom بال fusion بتاخد رقم لو اجت ال carbon + +319 +00:28:27,090 --> 00:28:31,730 +تاخد ايش رقم واضح لو اجت الهيتيرو اتم بتاخد رقم لو + +320 +00:28:31,730 --> 00:28:36,670 +اجت ال carbon مابتاخد ايش رقم يمكن هنا الحقيقة + +321 +00:28:36,670 --> 00:28:43,270 +بفيد ان انوه لنقطة اكيد هتمر عليكم ان الهيتيرو اتم + +322 +00:28:43,270 --> 00:28:47,370 +الوحيدة اللي ممكن تيجي مشتركة بين حلقتين ال + +323 +00:28:47,370 --> 00:28:53,270 +nitrogenواضح؟ يعني ال oxygen فقط بيعمل رابطتين، + +324 +00:28:53,270 --> 00:28:58,390 +وأقل اتصال هنا بين حلقتين بده رابطتين تانية، تلاتة + +325 +00:28:58,780 --> 00:29:02,100 +يا بيكون carbon في اربعة وبالتالي بيجيله double + +326 +00:29:02,100 --> 00:29:06,220 +bond او رابط ماه، يا بيكون nitrogen فقط التلات + +327 +00:29:06,220 --> 00:29:12,520 +روابط، فنقاط ال fusion فقط ممكن تكون carbon او + +328 +00:29:12,520 --> 00:29:17,140 +nitrogen، أكسجل مش ممكن تكون، الآن لو كانت + +329 +00:29:17,140 --> 00:29:22,420 +nitrogen وإجا ال nitrogen بال fusion زي هذا المثال + +330 +00:29:31,000 --> 00:29:36,440 +زي هذا المثال هل يا ترى ال nitrogen بدنا نعتبره + +331 +00:29:36,440 --> 00:29:42,060 +يتبع هذه الحلقة ولا يتبع هذه الحلقة الصحيح انه + +332 +00:29:42,060 --> 00:29:47,860 +بيتبع الحلقتين بمعنى بقول ان هذه تعاملوا معاها على + +333 +00:29:47,860 --> 00:29:52,980 +انها حلقة كاملة وشوفوا ايش اسمها و هذه اتعاملوا + +334 +00:29:52,980 --> 00:29:57,380 +معاها ايضا انها حلقة كاملةوأتوا دول الحلقاتين + +335 +00:29:57,380 --> 00:30:01,100 +عملوا fusion ولذلك الحلقاتين اللي بيكونوا هذا + +336 +00:30:01,100 --> 00:30:09,450 +النظام حقيقة هم ال oxazoleالـ Birol فلو مثل هذا + +337 +00:30:09,450 --> 00:30:14,190 +المركب بدي أسميه في عندي حلقة Oxazole تحتوي على + +338 +00:30:14,190 --> 00:30:17,670 +نيتروجين يعني لو كنتوا بتكونوا طابقوا القواعد هذه + +339 +00:30:17,670 --> 00:30:22,390 +الحلقة ال Oxazole فيها نيتروجين ولا لأ؟ هذه الحلقة + +340 +00:30:22,390 --> 00:30:26,970 +ال Birol فيها نيتروجين ولا لأ؟ أكيدلما بدأ احدد + +341 +00:30:26,970 --> 00:30:30,610 +مين ال base component خماسية و خماسية بس هاد فيها + +342 +00:30:30,610 --> 00:30:35,690 +two hetero atoms هاد فيها one hetero atom ولذلك ال + +343 +00:30:35,690 --> 00:30:42,690 +base component هنا إيش هتكون ال oxazole و ال + +344 +00:30:42,690 --> 00:30:52,910 +prefix ال byrole فهذا byrole oxazole الان لما بدأ + +345 +00:30:52,910 --> 00:31:05,060 +أعطي حروف aبـ C و لما ضعت أرقام 1,2,3,4,5 من وين + +346 +00:31:05,060 --> 00:31:13,140 +هذا شابك؟ بيرولو 1,2,C اوكزازول بيرولو 1,2,C + +347 +00:31:13,140 --> 00:31:17,200 +اوكزازول فالهيتيرو أتم لما تيجي بنقطة ال fusion + +348 +00:31:17,200 --> 00:31:23,010 +تحسب على حلقتينواضح؟ تحسب على الحلقتين و اشتغلوا + +349 +00:31:23,010 --> 00:31:28,370 +على هذا الأساس و لما بتمر معنى في الترقيم بتاخد + +350 +00:31:28,370 --> 00:31:33,330 +رقم يعني لاحظوا أنا ال oxygen أخذ رقم ال nitrogen + +351 +00:31:33,330 --> 00:31:36,750 +أنا ال oxygen عادي لكن هذه ال nitrogen جاية في + +352 +00:31:36,750 --> 00:31:40,750 +نقطة fusion بتاخد رقم بينما هذه ال carbon و هذه ال + +353 +00:31:40,750 --> 00:31:44,050 +carbon و هذه ال carbon اللي بيقاتل fusion بياخدوش + +354 +00:31:44,050 --> 00:31:51,170 +رقم واضح؟ و ال machine اللي بنعمله مععقارب الساعة + +355 +00:31:51,170 --> 00:31:56,830 +الماشي اللى بنعمله بعد ما نتخيل انه رتبنا الجزئ مع + +356 +00:31:56,830 --> 00:32:00,930 +عقارب الساعة طبعا هذه الحالة حالة كبيرة وواسعة + +357 +00:32:00,930 --> 00:32:05,310 +يعني احنا مرات الأمر بالنسبة لنا أسهل كتير يعني كل + +358 +00:32:05,310 --> 00:32:09,930 +اللى بيكون عندى عبارة عن حلقتين زى كل الأمثلة اللى + +359 +00:32:09,930 --> 00:32:18,510 +أنا شفتها طبعا لما يبدأ يصير عندى حلقتين ببدأ + +360 +00:32:19,660 --> 00:32:24,540 +أتغلب بشغلة جديدة خلّينا بس نتأكد أن كل الأشياء + +361 +00:32:24,540 --> 00:32:28,740 +هنا موجودة الـ C-atoms which belong to more than + +362 +00:32:28,740 --> 00:32:34,160 +one ring are omitted الكربونز بينحذفوا الـ + +363 +00:32:34,160 --> 00:32:38,360 +heteroatoms in such positions are however included + +364 +00:32:38,360 --> 00:32:45,170 +هذا الكلام واضح؟ واضحالان بيجيني السؤال if there + +365 +00:32:45,170 --> 00:32:48,530 +are several possible orientations in the + +366 +00:32:48,530 --> 00:32:53,250 +coordinate system اذا انا اجيت وطبقت القاعدة + +367 +00:32:53,250 --> 00:32:58,190 +الأولى و لجيت عندى اكثر من احتمال كيف بدى امشي؟ + +368 +00:32:58,780 --> 00:33:03,420 +واضح؟ طبعا إيش اللي بقصده؟ أنا القاعدة بتقول حط + +369 +00:33:03,420 --> 00:33:09,420 +الحلقات بشكل أفقي، الآن لو مسكنكم هذا كمثال + +370 +00:33:09,420 --> 00:33:15,180 +وقلنالكم امسكوه بشكل أفقي، ممكن واحدة تحط الحلقتين + +371 +00:33:15,180 --> 00:33:20,140 +بهذا الشكل، ممكن واحدة تجلبهم، يعني تخلي .. تعمل + +372 +00:33:20,140 --> 00:33:24,760 +flipping، هي horizontal، ممكن واحدة تجلبهم لتحتمن + +373 +00:33:24,760 --> 00:33:29,500 +أي نقطة انا بدي ابدا حقيقة لما انا باجي باطلع + +374 +00:33:29,500 --> 00:33:32,720 +بالذات لما يكونوا حلقتين وهذا اكثر اشي بيمر عليكم + +375 +00:33:32,720 --> 00:33:37,160 +تطبيقيا هذه النقطة ممكن تكون نقطة البداية وامشي مع + +376 +00:33:37,160 --> 00:33:41,580 +قارب الساعة لو عملتله flipping جلبته لفوق وجهته + +377 +00:33:41,580 --> 00:33:46,100 +هتصير هذه النقطة نقطة البداية وامشي برضه معهعقاري + +378 +00:33:46,100 --> 00:33:49,760 +بالساعة و لو جلبته بهذا الشكل هذه النقطة يمكن أن + +379 +00:33:49,760 --> 00:33:52,480 +تكون نقطة البداية و امشي مع عقاري بالساعة و لو + +380 +00:33:52,480 --> 00:33:56,060 +جلبته كمان مرة هذه النقطة ممكن أن تكون نقطة + +381 +00:33:56,060 --> 00:33:59,240 +البداية و امشي مع عقاري بالساعة ماعرفش اذا هذه + +382 +00:33:59,240 --> 00:34:05,460 +الشغلة مش كتير واضحة ممكن اوضحها اكثر ممكن اوضحها + +383 +00:34:05,460 --> 00:34:12,380 +اكثر خلينا ناخد دقيقة وقت و نوضح هذه الشغلة + +384 +00:34:13,690 --> 00:34:20,930 +نجرب نرسم تقريبا نفس هدول الحلقتين عندي حلقة + +385 +00:34:20,930 --> 00:34:27,050 +خماسية و حلقة خماسية تانية خلينا نفترضهم بهذا + +386 +00:34:27,050 --> 00:34:35,190 +الشكل مش كثير موضوعنا الان لو حطينا هنا nitrogen و + +387 +00:34:35,190 --> 00:34:43,230 +هنا nitrogen و في اي مكان هنا مثلا oxygen + +388 +00:34:46,930 --> 00:34:54,690 +و نكبر هذه الرسمة شوية عشان تظهر + +389 +00:34:54,690 --> 00:35:01,930 +الان هاي هذول حلقتين و محتوطات بشكل أفقي صحيح ممكن + +390 +00:35:01,930 --> 00:35:12,070 +نعمل لهم نسخ و لاصق و كمان مرة لاصق و كمان مرة + +391 +00:35:12,070 --> 00:35:13,670 +لاصق + +392 +00:35:15,380 --> 00:35:20,500 +الان لاحظوا حطناهم زي ما هما لو تخيلنا انه بدنا + +393 +00:35:20,500 --> 00:35:24,300 +نجلب هذول الحلقتين مجرد ما نجلبهم يعني نقول object + +394 +00:35:24,300 --> 00:35:36,520 +flip vertical و لو مسكت هذه الحلقة و جلبتها برضه + +395 +00:35:36,520 --> 00:35:43,400 +object flip horizontal و بعدين هذه بعد ما جلبتها + +396 +00:35:45,720 --> 00:35:55,160 +ممكن ننسخها تاني و + +397 +00:35:55,160 --> 00:36:01,700 +نعود نجلبها vertical object flip vertical الان + +398 +00:36:01,700 --> 00:36:09,420 +لاحظوا نفس الحلقاتنفس الحلقات و كلها بترتيب أفقي و + +399 +00:36:09,420 --> 00:36:15,480 +لما بده يجي إنسان يقول بدي أمشي مع قارب الساعة بدي + +400 +00:36:15,480 --> 00:36:20,420 +أمشي مع قارب الساعة الآن بهذا الشكل هو بيمشي مع + +401 +00:36:20,420 --> 00:36:25,060 +قارب الساعة واحد اتنين تلاتة تلاتة برايم اربعة + +402 +00:36:25,060 --> 00:36:30,900 +خمسة ستة ستة برايم و بهذا الشكل واحد اتنين تلاتة + +403 +00:36:30,900 --> 00:36:36,950 +اربعة خمسةواحد اتنين تلاتة تلاتة برايم اربعة خمسة + +404 +00:36:36,950 --> 00:36:42,290 +ستة ستة برايم وبهذا الشكل بيمشي مع قريب الساعة + +405 +00:36:42,290 --> 00:36:48,250 +كمان من هذه النقطة مش اخر حلقة وبهذا الشكل بيمشي + +406 +00:36:48,250 --> 00:36:53,610 +مع قريب الساعة ولذلك حقيقة بيكون الإنسان مفكر جيدا + +407 +00:36:53,610 --> 00:36:58,730 +بهذه الحالة ان هو عنده اربع احتمالات الآن اي من + +408 +00:36:58,730 --> 00:37:03,810 +هذه الاحتمالات انا بدي ااخدهو هيصير عندكم تساؤل يا + +409 +00:37:03,810 --> 00:37:08,170 +تورا هو احنا كل مرة بدنا نرسم الحلقة و ندخل على + +410 +00:37:08,170 --> 00:37:11,850 +برنامج الرسم و نعمل الأربع احتمالات أول مرتين + +411 +00:37:11,850 --> 00:37:16,110 +تلاتة لغرض التدريب ممكن تعملوهم بعد هيك بتصيروا + +412 +00:37:16,110 --> 00:37:22,310 +اتحلوا المشكلة لوحدكم في كل الأحوال نقطة البداية + +413 +00:37:22,310 --> 00:37:26,290 +اللي عندكم لو انتوا تخيلتوا خط ال fusion اللي + +414 +00:37:26,290 --> 00:37:34,320 +موجود هناشايفينه؟ نقطة البداية ممكن تكون أي نقطة + +415 +00:37:34,320 --> 00:37:37,060 +من الأربع نقاط اللي جنبها هذه نقطة جنبها و ممكن + +416 +00:37:37,060 --> 00:37:43,980 +تكون هذه نقطة البداية لما جلبته ممكن هذه و لما + +417 +00:37:43,980 --> 00:37:49,640 +جلبته كمان مرة صار ممكن هذه ال oxygen ال carbon او + +418 +00:37:49,640 --> 00:37:55,460 +هذه يعني نقاط البداية الممكنة في هذه الحالة حقيقة + +419 +00:37:55,460 --> 00:38:03,330 +هم الأربع نقاطاللي بيجاوره خط ل fusion كل نقطة + +420 +00:38:03,330 --> 00:38:10,210 +منهم ممكن أنها تكون نقطة بداية تمام؟ الآن باجي من + +421 +00:38:10,210 --> 00:38:18,010 +كل نقطة و بشوف أي دوران بيعطيلي أقل مجموع لل + +422 +00:38:18,010 --> 00:38:22,810 +hetero atoms لمواقع ال hetero atoms اللي بتعطيلي + +423 +00:38:22,810 --> 00:38:30,150 +أقل مجموع هي اللي بدي أخدهاواضح؟ يعني هنا لو كنت + +424 +00:38:30,150 --> 00:38:33,750 +باخد النظام بهذا الشكل، شو المجموع اللي عندي؟ + +425 +00:38:33,750 --> 00:38:39,190 +واحد، اتنين، تلاتة، تلاتة prime، أربعة، هاي الـ + +426 +00:38:39,190 --> 00:38:45,750 +hetero atoms، واضح؟ الآن لو كنت باخد منها، واحد، + +427 +00:38:45,750 --> 00:38:51,890 +اتنين، تلاتة، أربعة، خمسة، ستة، لو كنت باخد منها، + +428 +00:38:51,890 --> 00:38:58,040 +نلاحظوا أنا بأمشيمع قريب الساعة في كل لحظة تلاتة + +429 +00:38:58,040 --> 00:39:04,340 +لو ماخد منها واحد هذه الواحد لأن الحلقة هذه أول + +430 +00:39:04,340 --> 00:39:10,380 +ذرة فيها واحد تانين تلاتة تلاتة براي أربعة خمسة + +431 +00:39:10,380 --> 00:39:16,940 +ستة ولو بدي أمشي من هنا واحدهي واحد اتنين مع عقارب + +432 +00:39:16,940 --> 00:39:21,760 +الساعة من هنا واحد اتنين تلاتة تلاتة prime اربعة + +433 +00:39:21,760 --> 00:39:28,700 +خمسة ستة الان ان هو اقل ترقيمليش في أخر واحدة + +434 +00:39:28,700 --> 00:39:35,100 +مانقمش واحد من عند الكاربو ولاش؟ دائما الواحد أول + +435 +00:39:35,100 --> 00:39:39,920 +الحلقة الأخيرة على إيد الشمال يعني لو رجعنا احنا، + +436 +00:39:39,920 --> 00:39:42,620 +مديش أطلع من هذه ال slide، على slide ال powerpoint + +437 +00:39:42,620 --> 00:39:46,760 +لما عملت، أخر إشي في الحلقات اللي كنت حاططهم على + +438 +00:39:46,760 --> 00:39:51,500 +ال coordinate، أخر حلقة من الشمالبقى امشي بقى، + +439 +00:39:51,500 --> 00:39:55,920 +الان هدولة حلقتين، مين اخر حلقة؟ هذه، وين اخر + +440 +00:39:55,920 --> 00:40:00,320 +موقع؟ من الشمال، اللي هو الموقع اللي بعد خط ال + +441 +00:40:00,320 --> 00:40:04,660 +fusion، هذا اللي بدي ابدأ منه، الموقع اللي بعد خط + +442 +00:40:04,660 --> 00:40:10,820 +ال fusion، الان لما بيجي بنطلع، وين اقل ترقيم؟ هو + +443 +00:40:10,820 --> 00:40:17,360 +الترقيم اللي موجود عنده، واضح؟ باخدههيصير سؤال هل + +444 +00:40:17,360 --> 00:40:21,940 +يا تورا كل مرة .. كل مرة بدي أعمل هذا الكلام؟ لأ + +445 +00:40:21,940 --> 00:40:27,340 +أنا بسهل لكم بعطيكم تطبيقيا قاعدة بسيطة افترضوا + +446 +00:40:27,340 --> 00:40:34,820 +هذا المركب موجود معكم بأي شكل من الأشكال مرسوم؟ + +447 +00:40:34,820 --> 00:40:38,220 +ممكن يجيكم في الامتحان مرسوم زي هيك أو زي هيك أو + +448 +00:40:38,220 --> 00:40:44,080 +زي هيك أو زي هيك كيف بدي أعمل الترقيم الصحي؟نتخيل + +449 +00:40:44,080 --> 00:40:49,620 +أي رسمة منهم اللي جايانا؟ ممكن نتخيل هذه؟ خليني + +450 +00:40:49,620 --> 00:40:53,380 +نشتغل عليها و نعتبر أنه بس هي اللي جاية، بدي أجي + +451 +00:40:53,380 --> 00:41:01,940 +خط ل fusion و أعد من الأربع جهات و أشوف أين أقل + +452 +00:41:01,940 --> 00:41:08,180 +ترقيم، أطول، واحد، تنين، تلاتة، تلاتة prime، أربع، + +453 +00:41:08,180 --> 00:41:13,270 +خمسة، ستة، هاي واحد، بحفظ المخواحد اتنين تلاتة + +454 +00:41:13,270 --> 00:41:18,570 +تلاتة برايم اربعة خمسة ستة واحد اتنين تلاتة تلاتة + +455 +00:41:18,570 --> 00:41:24,010 +برايم اربعة خمسة ستة واحد اتنين تلاتة تلاتة برايم + +456 +00:41:24,010 --> 00:41:28,370 +اربعة خمسة ستة بعيد من كل نقطة باعتبرها نقطة بداية + +457 +00:41:28,370 --> 00:41:31,170 +هذه بداية هذه بداية هذه بداية يعني لو قلت هذه + +458 +00:41:31,170 --> 00:41:35,170 +البداية الأولى هي التانية هي التالتة هي الرابعة + +459 +00:41:35,170 --> 00:41:40,410 +لاحظوا البداية الأولى أعطتني ايش اتنين اتنين + +460 +00:41:42,750 --> 00:41:46,790 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +461 +00:41:46,790 --> 00:41:47,810 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +462 +00:41:47,810 --> 00:41:49,430 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +463 +00:41:49,430 --> 00:41:50,390 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +464 +00:41:50,390 --> 00:41:52,390 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +465 +00:41:52,390 --> 00:41:54,350 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +466 +00:41:54,350 --> 00:41:55,610 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +467 +00:41:55,610 --> 00:42:04,730 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +468 +00:42:04,730 --> 00:42:07,750 +تلاتة + +469 +00:42:10,350 --> 00:42:15,430 +انطلقوا من اي نقطة و لوفوا خارج ال fusion بتكونوا + +470 +00:42:15,430 --> 00:42:21,370 +100% مع قرب الساعةليش؟ لأنه بجلب او بجلب تان بصير + +471 +00:42:21,370 --> 00:42:25,910 +مع عقارب الساعة يعني انا لما بقولك امشي من هنا و + +472 +00:42:25,910 --> 00:42:29,230 +انبهنا ضد عقارب الساعة مو انا لو جلبت الجزئ هاي و + +473 +00:42:29,230 --> 00:42:32,770 +جلبت و صرت مع عقارب الساعة الان بده رايحك من عقارب + +474 +00:42:32,770 --> 00:42:36,590 +الساعة بدك تنسي قصة عقارب الساعة انت مية في المية + +475 +00:42:36,590 --> 00:42:43,080 +لو اتحركت بأي اتجاه احدىالأشكال تبعته هتكون معقارة + +476 +00:42:43,080 --> 00:42:46,720 +بالساعة ولذلك كونوا متأكدين ما تخافوش من قصة + +477 +00:42:46,720 --> 00:42:51,600 +معقارة بالساعة إذا تحركتم خارج ال fusion مش + +478 +00:42:51,600 --> 00:42:57,620 +باتجاهه من هنا للخارج من هنا للخارج من هنا للخارج + +479 +00:42:57,620 --> 00:43:02,040 +من هنا للخارج انتوا مليون في المية معقارة بالساعة + +480 +00:43:02,040 --> 00:43:09,460 +مافيش فيها نقاش والشكل مرسوم يعني الاحتجتها قمايه + +481 +00:43:09,460 --> 00:43:17,480 +مرسومهلجيت لما امشي واحد اتنين تلاتة تلاتة prime + +482 +00:43:17,480 --> 00:43:23,340 +هينماشي مع قريب الساعة ولا لا بأحد أشكاله ماشي مع + +483 +00:43:23,340 --> 00:43:28,940 +قريب الساعة واضح الفكرة يعني مجرد ان اتخيل ان جلدت + +484 +00:43:28,940 --> 00:43:33,040 +وبصير ماشي مع قريب الساعة كلهم بيمشي مع قريب + +485 +00:43:33,040 --> 00:43:40,320 +الساعة الان لو هنا جربنا بنقول واحد تلاتة اربعة + +486 +00:43:41,900 --> 00:43:46,320 +و هكذا لما نجرب كل الاحتمالات ان هو الاحتمال اللى + +487 +00:43:46,320 --> 00:43:54,200 +هنكتشف انه صح و انه اقل ترقيم تلاتة واحد تلاتة + +488 +00:43:54,200 --> 00:44:01,460 +تلاتة براي اربعة خمسة ستة ستة براي الآن واحدة + +489 +00:44:01,460 --> 00:44:04,520 +هتقول هذا يالله مش معاقر بالسعة بنقوله لأشي اقل + +490 +00:44:04,520 --> 00:44:06,640 +بيه مرتين هيا هذا هو هذا + +491 +00:44:09,710 --> 00:44:13,690 +لحظوا هي هنا عند احساس انه كأنه مش مع قريب الساعة + +492 +00:44:13,690 --> 00:44:16,910 +لان انا بقولها لأ لما تحطيه بالشكل الصحيح ترجع مع + +493 +00:44:16,910 --> 00:44:24,270 +قريب الساعة هذا بهذا الشكل مع + +494 +00:44:24,270 --> 00:44:30,470 +قريب الساعة واضح فانا بدون ما اتعب حالي و ارسم + +495 +00:44:30,470 --> 00:44:34,390 +الاربع رسمات عشان امشي مع قريب الساعة بدأ اقول عند + +496 +00:44:34,390 --> 00:44:40,010 +اربع نقاط ابتدائيبالذات لما يكون عندى حلقتين اللى + +497 +00:44:40,010 --> 00:44:45,590 +بتعطيني ال hetero atoms اقل ما يمكن امشي عليها و + +498 +00:44:45,590 --> 00:44:50,070 +هي اكيد صح و هي اكيد كمان مع قارب الساعة حسب + +499 +00:44:50,070 --> 00:44:54,210 +القاعدة لو رسمت بطريقة ثانية يعني هذا الترقيم + +500 +00:44:54,210 --> 00:44:58,950 +اتخيلوا لو كان انا عندكم مثل ايش هتكتبوها؟ + +501 +00:45:01,200 --> 00:45:05,980 +CH6 مثل و اتكمله المركب طب لو لفيته و جلبت كل + +502 +00:45:05,980 --> 00:45:10,440 +الأشياء هتيجي المثل هنا ولا لأ و هكون معاه قارب + +503 +00:45:10,440 --> 00:45:18,200 +الساعة و لذلك مابلزمنيش انا كفكرة فهمتكم القاعدة + +504 +00:45:18,200 --> 00:45:25,410 +بعموميتها لكن مابلزمنيش كل مرةأقعد أن أجلب الأشياء + +505 +00:45:25,410 --> 00:45:30,230 +لأ أنا عنده أربع نقاط ابتداء بشوف مين اللي فيهم + +506 +00:45:30,230 --> 00:45:39,930 +بيعطيني أقل ترقيم أو أقل مجموع أرقام و بمشي عليه + +507 +00:45:39,930 --> 00:45:44,650 +واضح؟ هذا الكلام مع الأمثلة الإثرائية و الأمثلة + +508 +00:45:44,650 --> 00:45:48,670 +اللي بتكون تحلوها من المجلات أكيد ان شاء الله بصير + +509 +00:45:48,670 --> 00:45:51,010 +بالنسبة لكم واضح + +510 +00:45:54,620 --> 00:45:59,840 +شوفنا إذا هذا المثال لو أنا إجيت أسميه .. لو أنا + +511 +00:45:59,840 --> 00:46:04,480 +إجيت أسمي هذا المثال اللي رسمناه الآن تمام؟ و + +512 +00:46:04,480 --> 00:46:08,780 +لاحظوا أن هذا المثال مش عارف هو و لا غيره اللي + +513 +00:46:08,780 --> 00:46:15,320 +رسمناه تقعد النظر .. الآن هاي هذا مثال جديد افترضه + +514 +00:46:15,320 --> 00:46:20,800 +لما بتكون تفكروا في وين خط ال fusion هاي + +515 +00:46:21,980 --> 00:46:27,140 +وين النقاط اللى بدى ابتدأ منها هذى او هذى او هذى + +516 +00:46:27,140 --> 00:46:31,580 +او هذى النقاط اللى جنب خط ال fusion جربوا ان هذى + +517 +00:46:31,580 --> 00:46:36,340 +اعطتلي واحد و تلاتة و اربعة هذا الترقيم شو اعطانى؟ + +518 +00:46:36,340 --> 00:46:42,400 +واحد + +519 +00:46:42,400 --> 00:46:46,960 +اتنين تلاتة تلاتة برايم اربعة خمسة ستة هذا الترقيم + +520 +00:46:46,960 --> 00:46:57,540 +واحد اربعة و ستةواحد اربعة و ستة و هذا تلاتة + +521 +00:46:57,540 --> 00:47:02,960 +اربعة و ستة و ستة عشان هيك لما اختار اختار هذا + +522 +00:47:02,960 --> 00:47:07,700 +الترقيم اللي خلّى هذه ال atom كأنها substitute + +523 +00:47:07,700 --> 00:47:14,540 +تاخد ايش one H فال H بتتبع الترقيم الخارجي و كتب + +524 +00:47:14,540 --> 00:47:21,910 +لكم ال one three four هذاis preferred to one three + +525 +00:47:21,910 --> 00:47:24,410 +six واحدة هتقول وين ال one three six هاي واحد + +526 +00:47:24,410 --> 00:47:27,870 +اتنين تلاتة اربعة خمسة ستة افضل من ال one three + +527 +00:47:27,870 --> 00:47:34,290 +six و افضل من ال one four six اللي هو واحد اتنين + +528 +00:47:34,290 --> 00:47:39,130 +تلاتة تلاتة prime اربعة خمسة ستة هذا is preferred + +529 +00:47:39,130 --> 00:47:43,090 +to one three six و one four six وكمان واحد ماذكروش + +530 +00:47:43,090 --> 00:47:54,660 +هواللي لو كان ماخد من هنا يعني + +531 +00:47:54,660 --> 00:47:58,200 +لو واحدة بده تعمل الأربع ترقيمات الاربع ترقيمات + +532 +00:47:58,200 --> 00:48:01,620 +اللي عندها one three four one three six one four + +533 +00:48:01,620 --> 00:48:06,520 +six three four six ايش اللي بده تختاره ال one + +534 +00:48:06,520 --> 00:48:13,300 +three four واضح؟الـ 134 الان كيف يكون الجزء مرسوم + +535 +00:48:13,300 --> 00:48:17,480 +جربوا الأربع احتمالات في مخكم اللي بيعطيكم ال + +536 +00:48:17,480 --> 00:48:21,080 +hetero atoms أقل ما يمكن استعملوه حتى لو كنتوا + +537 +00:48:21,080 --> 00:48:25,900 +ظاهريا نبين انه بتلفوا ضد عقارب الساعة أحد رسومات + +538 +00:48:25,900 --> 00:48:30,760 +هذا الشكل لما تعملوله flipping بيكون حقيقة إيش؟ مع + +539 +00:48:30,760 --> 00:48:35,400 +عقارب الساعة أحد رسومات هذا الشكل بيكون مع عقارب + +540 +00:48:35,400 --> 00:48:43,280 +الساعة واضحة الفكرة؟الان إذا القاعدة الأولى give + +541 +00:48:43,280 --> 00:48:47,780 +low numbers for the hetero atoms as a set يعني + +542 +00:48:47,780 --> 00:48:56,420 +مجموع ال hetero atoms يكون أقل ما يمكن الآن دايما + +543 +00:48:56,420 --> 00:49:02,070 +بيصير عندي مشاكليعني لو اجت طالبة فيكم اتحل هذا + +544 +00:49:02,070 --> 00:49:08,090 +المثال جالس بده اطبق القواعد هاي خط ال fusion كم + +545 +00:49:08,090 --> 00:49:15,450 +احتمال عندها اربعة منها هاي + +546 +00:49:15,450 --> 00:49:20,820 +الأربع احتمالاتالان لاحظوا هذا الاختمال 1,2 + +547 +00:49:20,820 --> 00:49:25,460 +الهيتيرو أتمز 1,6 أعطاها الهيتيرو أتمز طب هذا + +548 +00:49:25,460 --> 00:49:36,440 +الاختمال 1,2,3,4,5,6 1,6 برضه هذا الاختمال 1,2,3,4 + +549 +00:49:36,440 --> 00:49:37,720 +,5,6 + +550 +00:49:41,530 --> 00:49:45,050 +لاحظوا دائما لما يطلع عندكم احتمالات متساوية اللي + +551 +00:49:45,050 --> 00:49:49,910 +فيه الرقم الأقل خدوه يعني لما يطلع عندكم واحد وستة + +552 +00:49:49,910 --> 00:49:56,310 +وتلاتة واربع هذه فيها رقم ايش الواحد اذا المجموع + +553 +00:49:56,310 --> 00:50:01,730 +اتساوى بدأ اخد اللي فيها الرقم الاقل طب لو واحدة + +554 +00:50:01,730 --> 00:50:02,670 +منها اتجربت + +555 +00:50:06,970 --> 00:50:14,990 +الان قلنا واحد وستة وهك واحد وستة وهك واحد وستة + +556 +00:50:14,990 --> 00:50:17,090 +صار عندى احتمالين + +557 +00:50:20,670 --> 00:50:24,750 +لو اتساوى و give low numbers for hetero atoms when + +558 +00:50:24,750 --> 00:50:29,570 +considered in the order oxygen أكتر من السلفر أكتر + +559 +00:50:29,570 --> 00:50:34,410 +من النيتروجين يعني هنا لو حطيت هنا واحد بكون + +560 +00:50:34,410 --> 00:50:38,790 +أعطيته للأكسجين ستة للسلفر لو حطيت هنا واحد بكون + +561 +00:50:38,790 --> 00:50:42,610 +أعطيته للسلفر ستة للأكسجين أنا وقتها بدي الأكسجين + +562 +00:50:42,610 --> 00:50:48,660 +يكون أقل من السلفرواضح؟ وعشان هيك اختارت هذا لأن + +563 +00:50:48,660 --> 00:50:51,380 +هذا بيعطينا ال oxygen ع واحد ال sulfur ع ستة هذا + +564 +00:50:51,380 --> 00:50:54,360 +بيعطينا ال oxygen ع ستة ال sulfur ع واحد وانا + +565 +00:50:54,360 --> 00:51:02,020 +دائما اقزثيا اذا الاولويات واضحة الفكرة؟ اذا هذا + +566 +00:51:02,020 --> 00:51:06,280 +هي الترقيم الصحيح تبعه اجتني قاعدة جديدة انه لما + +567 +00:51:06,280 --> 00:51:13,220 +لجيت نفس مجموع الترقيم 167 و 167 فاضلت ان اخلي ال + +568 +00:51:13,220 --> 00:51:18,500 +oxygen تكونأقل ترقيم فضلت أن أجعل ال oxygen أقل + +569 +00:51:18,500 --> 00:51:27,700 +ترقيم الآن بنجي لأمثلة شوية أصعب مثل هذا المثال لو + +570 +00:51:27,700 --> 00:51:33,400 +أجينا نجرب هذا المثال بأكثر من احتمال هلاحظ أنه + +571 +00:51:35,240 --> 00:51:43,080 +مجموع الأرقام 1,4,5,8 متكرر ربما يعني لو أنا إجيت + +572 +00:51:43,080 --> 00:51:51,120 +رقمت من هنا 1,2,3,4,4,5,6,7,8 الـ hetero atoms + +573 +00:51:51,120 --> 00:51:53,400 +ماخدة أي أرقام هنا؟ + +574 +00:51:56,190 --> 00:52:02,810 +واحد واربعة وخمسة و تمانية طالما اتجهنا احنا + +575 +00:52:02,810 --> 00:52:08,670 +للخارج هاي خط ال fusion واضح طيب لو رقمنا من جهة + +576 +00:52:08,670 --> 00:52:17,570 +تانية من هنا واحد اتنين تلاتة اربعة خمسة ستة سبعة + +577 +00:52:17,570 --> 00:52:26,380 +تمانية نفس الأرقام لاحظين واحدأربعة خمسة تمانية + +578 +00:52:26,380 --> 00:52:32,340 +واحد اربعة خمسة تمانية واضح هاي احتمالين طبعا اكيد + +579 +00:52:32,340 --> 00:52:37,760 +دول الاحتمالات يمكن اقل واحد اتنين تلاتة هذا + +580 +00:52:37,760 --> 00:52:38,440 +الاحتمال + +581 +00:52:43,320 --> 00:52:47,880 +خمسة تمانية هاي كم احتمال صار عندى واحد اربعة خمسة + +582 +00:52:47,880 --> 00:52:53,820 +تمانية تلت احتمالات هذا واحد تنين تلت اربعة تنين + +583 +00:52:53,820 --> 00:53:04,650 +اربعة سبعة تمانية لأ بدنا نمشي هذا واحد تنين تلتة3 + +584 +00:53:04,650 --> 00:53:12,190 +prime 4 5 6 7 8 هذا كبير جدا الاحتمال لكن كم + +585 +00:53:12,190 --> 00:53:16,710 +احتمال طلع عند الأرقام بتاعتهم 1 4 5 8 تلت + +586 +00:53:16,710 --> 00:53:21,510 +احتمالات من اللي بدأ اختاره فيهم تلت احتمالات الآن + +587 +00:53:21,510 --> 00:53:26,170 +بنقول give low numbers to fusion carbon atoms حاول + +588 +00:53:26,170 --> 00:53:30,290 +تخلي ال carbon اللي في ال fusion تكون اقل ترقيا + +589 +00:53:31,640 --> 00:53:37,440 +تمام؟ الآن في هذا الاحتمال ال carbon ماخد رقم ايه؟ + +590 +00:53:37,440 --> 00:53:41,440 +اربعة ايه؟ طب لو اتيت على هذا الاحتمال واحد، + +591 +00:53:41,440 --> 00:53:45,280 +اتنين، تلاتة، اربعة، خمسة، ستة، سبعة، تمانية لكن + +592 +00:53:45,280 --> 00:53:50,640 +لو رقمت من هنا واحد، اتنين، تلاتة، اربعة، خمسة، + +593 +00:53:50,640 --> 00:53:54,140 +ستة، سبعة، تمانية تمانية ايه؟ اتت carbon for + +594 +00:53:54,140 --> 00:54:00,250 +fusion الاحتمال هذا اربعة ايه؟ طب لو رقمنا من هنا1 + +595 +00:54:00,250 --> 00:54:09,110 +,2,3,4,5,6,7,8,8 اذا من اقل احتمال اعطي ال carbon + +596 +00:54:09,110 --> 00:54:12,830 +في ال fusion هذا الاحتمال الاربعة ايه فاختارته + +597 +00:54:14,060 --> 00:54:18,100 +واضح؟ عشان هيك give low numbers to fusion carbon + +598 +00:54:18,100 --> 00:54:22,080 +atoms يعني خل ال carbon اللي بال fusion لو ما + +599 +00:54:22,080 --> 00:54:25,440 +حلقاش القاعدة الأولى في الترقيم و القاعدة التانية + +600 +00:54:25,440 --> 00:54:29,940 +في الترقيم اتطلع على ال carbon مرة تانية بأكد هذول + +601 +00:54:29,940 --> 00:54:34,620 +القواعد بدنا نمشي فيهم ايضا امرتبين يعني ماحدش + +602 +00:54:34,620 --> 00:54:38,700 +ييجي يحكيلي على ال carbon بتاعة ال fusion لو كانوا + +603 +00:54:38,700 --> 00:54:44,180 +مجموع ال hetero atoms بحلوا المشكلةيعني القاعدة + +604 +00:54:44,180 --> 00:54:49,040 +الأولى اللى عندى مجموع ال hetero atoms أقل ما يمكن + +605 +00:54:49,040 --> 00:54:54,920 +مازبطتش بنتقل ان اعطى أولوية لل oxygen عن ال + +606 +00:54:54,920 --> 00:55:01,680 +sulfur عن الثية مازبطش زى هذا المثال بتطلع على ان + +607 +00:55:01,680 --> 00:55:05,980 +اخلى ال carbon اللى موجودة بال fusion أقل ترقيم + +608 +00:55:05,980 --> 00:55:13,400 +مازبطشهذه طبعا امثلة بيقول استعمله هذا مش هذا او + +609 +00:55:13,400 --> 00:55:17,440 +هذا حط الترقيمات التانية اللي شرحناها واضح اللي + +610 +00:55:17,440 --> 00:55:23,780 +بيخلي ال fusion ايش ده خد تمانية ايه اللي وضحناه + +611 +00:55:23,780 --> 00:55:31,430 +الآن لو يا توراأجينا لمثال جديد كل القواعد اللي + +612 +00:55:31,430 --> 00:55:36,730 +فيه ما خدمتناش بنجي لقاعدة جديدة يعني اتطلعوا على + +613 +00:55:36,730 --> 00:55:43,890 +هذا المثال لو اتيت اتطلعت خط ال fusion هيك نقاط + +614 +00:55:43,890 --> 00:55:48,670 +الابتدائي اللي عنده هذه و هذه و هذه و هذه صح؟ + +615 +00:55:48,670 --> 00:55:51,690 +المجموع تبعهم واحد و تلاتة + +616 +00:56:07,260 --> 00:56:13,920 +مش قادرين نحل المشكلة الان ممكن نخفف جزء من + +617 +00:56:13,920 --> 00:56:22,060 +المشكلة ال oxygen له أولوية هذا واحدتلاتة أكسوجين + +618 +00:56:22,060 --> 00:56:26,960 +و هدولة نيتروجين أحسن من خلال واحد و تلاتة + +619 +00:56:26,960 --> 00:56:30,940 +نيتروجين و أكسوجين أربعة و ستة بس حاجين إنه كمان + +620 +00:56:30,940 --> 00:56:36,300 +هذا الاحتمال واحد و تلاتة فيه أكسوجين و أربعة و + +621 +00:56:36,300 --> 00:56:40,300 +ستة نيتروجين يعني معنى ذلك إنه أنا عيد أربع + +622 +00:56:40,300 --> 00:56:44,060 +احتمالات كلهم مجموع أرقام و واحد و تلاتة و أربعة و + +623 +00:56:44,060 --> 00:56:48,840 +ستة هذا الاحتمال الواحد و تلاتة فيهاكسوجين هذا + +624 +00:56:48,840 --> 00:56:53,840 +الاحتمال الواحد وتلاتة فيه اكسوجين هنا نيتروجين + +625 +00:56:53,840 --> 00:56:57,420 +مابديش هدول الاحتمالين لكن الان انا صارت مشكلتي + +626 +00:56:57,420 --> 00:57:03,480 +محصورة ان اقول واحد اتنين تلاتة واربعة وستة ولا + +627 +00:57:03,480 --> 00:57:11,220 +واحد اتنين تلاتة واربعة وستة يعني ابدأ هيك ولا + +628 +00:57:11,220 --> 00:57:17,750 +ابدأ هيكالأكسجين ماخد نفس الأرقام واحد و تلاتة + +629 +00:57:17,750 --> 00:57:22,630 +والنيتروجين أربعة و ستة واحد و تلاتة وأربعة و ستة + +630 +00:57:22,630 --> 00:57:27,150 +يعني انا اختصرت احتماليه لكن ما زالت المشكلة عندى + +631 +00:57:27,150 --> 00:57:32,510 +قائمة الان بيقول لي give low numbers to indicate + +632 +00:57:32,510 --> 00:57:37,310 +saturated atoms خلى ال saturated atoms يجوا أقل ما + +633 +00:57:37,310 --> 00:57:42,110 +يمكن طيب الان وين ال saturated atoms هنا؟ + +634 +00:57:44,550 --> 00:57:48,390 +لما ابدأ اكتب في المركب Dihydro طب انا مش هاكتب + +635 +00:57:48,390 --> 00:57:52,470 +2H4H، ايش بكتب؟ 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، + +636 +00:57:52,470 --> 00:57:52,510 +2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، + +637 +00:57:52,510 --> 00:57:53,250 +2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، + +638 +00:57:53,250 --> 00:57:57,710 +2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، + +639 +00:57:57,710 --> 00:58:12,930 +2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، 2H4H، + +640 +00:58:12,930 --> 00:58:18,420 +2H4H،انقول اصح اعطيهم اتنين واربعة ولا اتنين وستة + +641 +00:58:18,420 --> 00:58:23,880 +هيك اتنين واربعة هيك اتنين وستة باختار الاتنين + +642 +00:58:23,880 --> 00:58:32,700 +واربعة لكن زي ما حكينا ان هذا الكلام كله بالترتيب + +643 +00:58:32,700 --> 00:58:37,720 +قواعد الترقيم هذه ايضا كلها بتكون بالترتيب كل + +644 +00:58:37,720 --> 00:58:43,260 +قواعد الترقيم هذه بتكون بالترتيبواضح الفكرة؟ كل + +645 +00:58:43,260 --> 00:58:47,360 +قواعد الترقيم هذه بالترديد يعني ماحدش يجي يقولي + +646 +00:58:47,360 --> 00:58:51,980 +بدي أحل مشكلة الجزء من خلال ال saturated atoms لو + +647 +00:58:51,980 --> 00:58:55,900 +كان مجموع ال hetero atoms as a set بحل المشكلة + +648 +00:58:55,900 --> 00:59:00,920 +احنا وقتاشي وصلنا لها الكلام لما أخدنا نفس المجموع + +649 +00:59:00,920 --> 00:59:04,660 +و نفس الأجزاء زي ال oxygen على واحد و تلاتة و ال + +650 +00:59:04,660 --> 00:59:07,720 +nitrogen على أربع أشخاص كله مشترك وصلت لهذا + +651 +00:59:07,720 --> 00:59:08,360 +الاحتمال + +652 +00:59:11,340 --> 00:59:18,440 +الان بهيك تقريبا بتكون أخدنا قواعد أساسية وجدها + +653 +00:59:18,440 --> 00:59:23,200 +بنقدر نحل الأمثلة اللي موجودة عندكم وإن كان أنا + +654 +00:59:23,200 --> 00:59:29,560 +زيدت عليها بعض ال substituents من منطلق إنه نصير + +655 +00:59:29,560 --> 00:59:35,590 +جادرين نعمل ترقيم خارجيلاحظوا تسمية الـ Fused + +656 +00:59:35,590 --> 00:59:40,070 +Rings؟ عدة أمور تحديد الـ Base Component لـ Prefix + +657 +00:59:40,070 --> 00:59:44,130 +مواقع الاتصال والترقيم الخارجي كل هذا الكلام + +658 +00:59:44,130 --> 00:59:48,510 +بيجتمع في تسمية مُركَّب خلّينا ناخد هذا كمثال + +659 +00:59:48,510 --> 00:59:52,210 +وأكيد الـ AC قصد فيها Asset يعني Small C مش + +660 +00:59:52,210 --> 00:59:57,610 +Capital C Small + +661 +00:59:57,610 --> 01:00:03,100 +Cالان ع طول افضل انتوا نجلوني هتحس انه الكلام + +662 +01:00:03,100 --> 01:00:10,820 +selected هذا يتبع القاعدة الاولى اذا المركبة by + +663 +01:00:10,820 --> 01:00:20,580 +role و قدام ال by role sayino الان ال by role متحد + +664 +01:00:20,580 --> 01:00:28,420 +من a بي و لو رقمتها ال one twothree تلاتة اتنين + +665 +01:00:28,420 --> 01:00:35,900 +تلاتة اتنين لاحظوا بعد ما كتبت هذا الكلام لو انا + +666 +01:00:35,900 --> 01:00:41,140 +هدول اللي جوا مساحتهم مالهمش لزوم هدولة بحطهم عشان + +667 +01:00:41,140 --> 01:00:47,160 +احدد مواقع الاتصال الان الجزيء هيلزمه + +668 +01:00:48,880 --> 01:00:54,280 +ترقيم خارجي جديد عشان احدد ال substituents كام + +669 +01:00:54,280 --> 01:01:00,560 +substituents عندى فى هذا الجزء؟ تنتين تنتين ال + +670 +01:01:00,560 --> 01:01:05,380 +position of saturation هذا يجب ان يحدد وهذا يجب ان + +671 +01:01:05,380 --> 01:01:09,580 +تحدد ليش كان ال double bond ممكن تكون هنا بتغير + +672 +01:01:09,580 --> 01:01:18,490 +موقع التشبع مظبوط ولا لأ الآن هى الخط اللى عندىأجي + +673 +01:01:18,490 --> 01:01:22,710 +أبدأ أفكر الترقيم، كم نقطة محتمل له؟ + +674 +01:01:27,680 --> 01:01:32,460 +تنين تلاتة أربعة يعني الهيتيرو أتمزيت واحد وأربعة + +675 +01:01:32,460 --> 01:01:38,320 +هيك واحد اتنين تلاتة أربعة خمسة ستة عيين هنا واحد + +676 +01:01:38,320 --> 01:01:43,320 +اتنين تلاتة أربعة خمسة ستة عيين هذه واحد اتنين + +677 +01:01:43,320 --> 01:01:47,240 +تلاتة أربعة لاحظوا الآن عندي ترقميل اللي صرت متحير + +678 +01:01:47,240 --> 01:01:49,400 +فيه واحد وأربعة + +679 +01:01:54,980 --> 01:01:58,840 +يعني لو واحدة رقمت من هنا هتحط الاتيرو أتمس واحد + +680 +01:01:58,840 --> 01:02:06,710 +اربع او منها واحد اربععندها ترقمين واحد واربعة، + +681 +01:02:06,710 --> 01:02:11,250 +الآن الترقمين تساوي، هروح للقاعدة اللي بتقوللي + +682 +01:02:11,250 --> 01:02:15,450 +الأكزا أكتر من الثيا أكتر من الأزا، هل أخلي + +683 +01:02:15,450 --> 01:02:19,910 +الأكسجين واحد والسالفر أربعة ولا أخلي السالفر واحد + +684 +01:02:19,910 --> 01:02:24,490 +والأكسجين أربعة؟ السالفر واحد والأكسجين أربعة + +685 +01:02:25,780 --> 01:02:28,800 +السلفر واحد والنيتروجين أربعة نيتروجين قصمة + +686 +01:02:28,800 --> 01:02:33,480 +نيتروجين النيتروجين واحد والسلفر أربعة ولا السلفر + +687 +01:02:33,480 --> 01:02:47,000 +واحد والنيتروجين أربعة اذا ترقيمي و + +688 +01:02:47,000 --> 01:02:52,720 +هذا لما يبدو الآن ياخد الاسم الصحيح الكامل three + +689 +01:02:52,720 --> 01:02:53,800 +-acetyl + +690 +01:02:56,250 --> 01:03:05,210 +four H ثينو small letter three two بي roll واضح + +691 +01:03:05,210 --> 01:03:09,410 +الفكرة ناخد + +692 +01:03:09,410 --> 01:03:18,870 +مركب تاني نجرب فيه أي مركب حابين نعمله لأن الباقي + +693 +01:03:18,870 --> 01:03:27,260 +هنسيبه لكم homework الباقي بنسيبه homeworkو طبعا + +694 +01:03:27,260 --> 01:03:33,340 +مع إحضار أمثلة من المجلات الحديثة أربع خمس أمثلة + +695 +01:03:33,340 --> 01:03:41,180 +اللي تتقنوا هذا الكلام ناخد هذا ناخد + +696 +01:03:41,180 --> 01:03:48,850 +هذا المركب الآن أول شيء بدناياالـ Base Component + +697 +01:03:48,850 --> 01:03:53,190 +على أي قاعدة بنختار الـ Base Component؟ على + +698 +01:03:53,190 --> 01:03:59,790 +القاعدة اللي سمعوني كلمة الرابعة مايعدوهاش لأن + +699 +01:03:59,790 --> 01:04:04,150 +القاعدة الأولى بتحل المشكلة بروحش للرابعة واحدة + +700 +01:04:04,150 --> 01:04:07,190 +فيها نيتروجين واتانة فيش فيها نيتروجين القاعدة + +701 +01:04:07,190 --> 01:04:10,970 +الأولى مش هذه أكبر و هذه أصغر الرابعة بروحش + +702 +01:04:10,970 --> 01:04:17,140 +للرابعة إذا الأولى بتحل المشكلة هذه أشياءبردين إذا + +703 +01:04:17,140 --> 01:04:26,060 +المركبة بردين و جوسم ربع و قدامه ثيوفين ثيينه الآن + +704 +01:04:26,060 --> 01:04:33,580 +البردين من ون متحد بي بهذا الاتجاه الآن لما بدي + +705 +01:04:33,580 --> 01:04:41,820 +الثيوفين إذا بنفس اتجاه ال بي two three بي ثيينه + +706 +01:04:41,820 --> 01:04:48,580 +two three بي بردين خلصتمن ان احدد ال base + +707 +01:04:48,580 --> 01:04:52,900 +component ل prefix نقاط الاتصال الان كل الترقيمات + +708 +01:04:52,900 --> 01:04:59,000 +الداخلية مالهاش نزوم بده ترقيم خارجي عشان يحدد ال + +709 +01:04:59,000 --> 01:05:03,980 +substituents اللي هو كم substituent هنا تنتين ال + +710 +01:05:03,980 --> 01:05:12,360 +diehydro وال brom ال diehydro وال bromواضح؟ طبعا + +711 +01:05:12,360 --> 01:05:18,840 +لو إجيت بدي أعد واحد اتنين تلاتة أربعة خمسة ستة + +712 +01:05:18,840 --> 01:05:24,240 +سبعة واحد و سبعة و واحد اتنين تلاتة أربعة خمسة ستة + +713 +01:05:24,240 --> 01:05:29,000 +و سبعة بعد ذلك بيطلع أعلى كتير يمكن واحد اتنين + +714 +01:05:29,000 --> 01:05:34,840 +تلاتة تلاتة prime أربعة تلاتة و أربعة تلاتة و + +715 +01:05:34,840 --> 01:05:38,360 +أربعة سبعة أقل واحد سبعة تمانية + +716 +01:05:41,210 --> 01:05:45,290 +و من هنا واحد اتنين تلاتة اربعة و خمسة تسعة اكتر + +717 +01:05:45,290 --> 01:05:52,270 +اذا ايش الترقيم اللى بدى اختاره واحد اتنين ايش + +718 +01:05:52,270 --> 01:05:56,950 +القاعد اللى فدتني هنا مجموع الهيتير و اتونس مجموع + +719 +01:05:56,950 --> 01:06:02,030 +الهيتير و اتونس تلاتة و اربعة مرات كتير بنختصر هنا + +720 +01:06:02,030 --> 01:06:08,200 +نكتب هدول عشان ما نخدش الشخصواضح؟ الان على واحد و + +721 +01:06:08,200 --> 01:06:14,560 +اتنين ايش عندكم؟ دايهايدرو وعلى سبعة بنكتبهم + +722 +01:06:14,560 --> 01:06:21,540 +alphabetical seven برومو one + +723 +01:06:21,540 --> 01:06:32,000 +two دايهايدرو شرطة بنكمل ثيينو seven برومو one two + +724 +01:06:32,000 --> 01:06:40,170 +دايهايدرو ثيينو two three بي بيرديواضح؟ واضح الان + +725 +01:06:40,170 --> 01:06:46,290 +هذا الكلام بالتأكيد بحاجة الى تدريب و التدريب + +726 +01:06:46,290 --> 01:06:52,910 +مسئولية الطالب انه يحلم كل الأمثلة هذه اللي موجودة + +727 +01:06:52,910 --> 01:07:00,470 +عندنا و يجيب homework ينزل على المجلات يشوف كيف + +728 +01:07:00,470 --> 01:07:05,540 +الناس بيصمم و هاي عندى كمانممكن احل كمان مثال اذا + +729 +01:07:05,540 --> 01:07:09,980 +سمحتوا ناخده من اللي فيه حلقتين عشان نشوف كمان + +730 +01:07:09,980 --> 01:07:18,900 +بدنا نعمل الترقيم تبعهم الان ناخد هذا المثال هذا + +731 +01:07:18,900 --> 01:07:23,360 +المثال لو اجيناه بدنا انحله شو الحلقات اللي احنا + +732 +01:07:23,360 --> 01:07:30,440 +بنعرفها اللي فيه هذه component وهذه component + +733 +01:07:33,140 --> 01:07:37,440 +هذا ال component اسمها كوينولين وهذا ال component + +734 +01:07:37,440 --> 01:07:42,300 +اسمها بيريدين التنتين فيهم نيتروجين إذا القاعدة + +735 +01:07:42,300 --> 01:07:47,020 +الأولى بتفيدني؟ لأ القاعدة التانية؟ لأ القاعدة + +736 +01:07:47,020 --> 01:07:50,200 +التالتة بتقول إذا المركب من two components واحدة + +737 +01:07:50,200 --> 01:07:54,300 +منهم من حلقتين والتانية من حلقة اختار اللي من + +738 +01:07:54,300 --> 01:07:59,140 +حلقتين إذا هذا المركب كوينولين + +739 +01:08:02,890 --> 01:08:12,650 +بين جوسين بايريدو بايريدو كوينولين واضح؟ الان لو + +740 +01:08:12,650 --> 01:08:19,770 +بد الأرقام بياتبعوا الحروف اذا هاي ال a الكوينولين + +741 +01:08:19,770 --> 01:08:24,450 +عادة منهم بترقب one two three اذا هاي a بي + +742 +01:08:24,450 --> 01:08:29,230 +فالكوينولين متصل من بي لما بيدرقب منها one two + +743 +01:08:29,230 --> 01:08:30,710 +three four + +744 +01:08:35,380 --> 01:08:46,420 +بايريدو 32 بي اكوينولين بايريدو 32 بي اكوينولين + +745 +01:08:46,420 --> 01:08:54,420 +الان خلصت بدى الترقيم الخارجى كيف بدى ابدأ الترقيم + +746 +01:08:54,420 --> 01:09:01,880 +الخارجى؟هنا بطل عندكوا حلقتين صاروا تلاتة .. صاروا + +747 +01:09:01,880 --> 01:09:06,820 +تلاتة الترقيم لو كان بهذا الشكل هيبدأ من هذه + +748 +01:09:06,820 --> 01:09:11,540 +النقطة مع قرب الساعة و ممكن تجلبوه بيبدأ من هذه + +749 +01:09:11,540 --> 01:09:14,140 +النقطة مع قرب الساعة و ممكن تعملوه ال flipping + +750 +01:09:14,140 --> 01:09:21,730 +بهذا الشكل بيبدأ من هذهأو من هذه وبناء على ذلك لما + +751 +01:09:21,730 --> 01:09:26,830 +نقول كام نقطة يمكن أن تكون نقطة ابتداء ايضا أربعة + +752 +01:09:26,830 --> 01:09:32,070 +لكن وين الأربعة تتخيلوا هذا خط fusion و هذا خط + +753 +01:09:32,070 --> 01:09:41,050 +fusion و الأربعة اللي جنبهم للخارج يعني هاي + +754 +01:09:41,050 --> 01:09:45,370 +الأربعة احتمالاتاللي وجدتها هيك بمشي معاها قريب + +755 +01:09:45,370 --> 01:09:49,890 +الساعة حواليه كله لو عملت له flipping من هنا لو + +756 +01:09:49,890 --> 01:09:54,690 +عملت horizontal flipping بصير من هنا كمان مرة + +757 +01:09:54,690 --> 01:10:00,230 +vertical flipping هي الأربع نقاط اللي عندكم فكأنه + +758 +01:10:00,230 --> 01:10:03,990 +اتخيلوا هدول الخطين من هنا و من هنا مستحيل تبدو + +759 +01:10:03,990 --> 01:10:08,350 +هتبدو يا من هنا يا من هنا أربع نقاط عندكمأيضا أربع + +760 +01:10:08,350 --> 01:10:11,250 +نقاط، الآن في هذه الأربع نقاط، شوفوا لي أين الـ + +761 +01:10:11,250 --> 01:10:16,570 +hetero atoms أقل ترقيم؟ واحد، اتنين، تلاتة، أربعة، + +762 +01:10:16,570 --> 01:10:23,310 +واحد وخمسة، منها اتنين، تلاتة، أربعة وكتير، منها + +763 +01:10:23,310 --> 01:10:27,930 +كتير، منها كتير، منها كتير، منها كتير، منها كتير، + +764 +01:10:27,930 --> 01:10:28,170 +منها كتير، منها كتير، منها كتير، منها كتير، منها + +765 +01:10:28,170 --> 01:10:28,310 +كتير، منها كتير، منها كتير، منها كتير، منها كتير، + +766 +01:10:28,310 --> 01:10:29,910 +كتير، منها كتير، منها كتير، منها كتير، منها كتير، + +767 +01:10:32,420 --> 01:10:43,720 +5,2,3,4,5,2 + +768 +01:10:43,720 --> 01:10:51,060 +,3,4,5,2,3,4,5,2 + +769 +01:10:51,060 --> 01:10:59,460 +,3 + +770 +01:10:59,460 --> 01:11:02,040 +,4,5,2,3,4,5,2,3,4,5,2,3,4,5,2,3,4,5,2,3,4,5,2,3,4 + +771 +01:11:02,040 --> 01:11:02,180 +,2,3,4,5,2,3,4,5,2,3,4,5,2,3,4,5,2,3,4,5,2,3,4,5,2 + +772 +01:11:02,180 --> 01:11:03,830 +,3,4,5,2,3,4,5,2,3,4,5,2,3,4,5,2,3,4,5,2,3,4,ثم + +773 +01:11:03,830 --> 01:11:09,130 +مثل بيريدو 3 2 بيكلوليل يمكن هدول المركبات تحسهم + +774 +01:11:09,130 --> 01:11:13,750 +كأنه بنرسمهم على خط أفقي و بنخلف الربع الأعلى + +775 +01:11:13,750 --> 01:11:19,430 +الحقيقة أنه حسب قواعد الرسم خلصته من الجديد ولا + +776 +01:11:19,430 --> 01:11:23,070 +لسه فيه مشكلة هذا خلصنا منه + +777 +01:11:32,540 --> 01:11:36,600 +هذا الحقيقة بيرسموه بهذا الشكل وبالتالي هم عبارة + +778 +01:11:36,600 --> 01:11:42,820 +عن تلت حلقات بشكل أفقي وهذا أيضا بنرسمه يعني + +779 +01:11:42,820 --> 01:11:46,020 +مابنرسمش الحلقات بزوايا بحيث نتخيل هذه كأنها في + +780 +01:11:46,020 --> 01:11:51,970 +الربع الأعلى لأ بنرسم الحلقات بهذا الشكلديروا + +781 +01:11:51,970 --> 01:11:55,490 +بالكوا موضوع التسمية هذا موضوع كبير يعني لو بدكوا + +782 +01:11:55,490 --> 01:11:59,750 +تشوفوا الحلقات وقداشي بتكبر وممكن يكونوا خمس ست + +783 +01:11:59,750 --> 01:12:02,550 +حلقات وكيف تحطوهم على ال coordinate system + +784 +01:12:21,680 --> 01:12:25,380 +على كيف ترسم الحلقات و بيكونوا خمس و ست و عشر + +785 +01:12:25,380 --> 01:12:31,940 +حلقات هذا لشغل متقدم انما الشغل تبعنا لهذه المرحلة + +786 +01:12:31,940 --> 01:12:35,760 +بيكفي فهذا المركب حقيقة بنرسمه مش زيك بنرسم + +787 +01:12:35,760 --> 01:12:39,540 +الحلقات بهذا الشكل وبالتالي هم تلاتة أفقيات و لو + +788 +01:12:39,540 --> 01:12:44,880 +كنتوا بدكم تعطوه اسم مثلا هذا أو هذا أي واحد حابين + +789 +01:12:44,880 --> 01:12:53,340 +تسموا فيهم بسرعة الأولاني هذا كام component؟طلعوا + +790 +01:12:53,340 --> 01:13:00,540 +معاه كنتين الان هذه اسمها اندول اندول + +791 +01:13:00,540 --> 01:13:07,760 +الها اسم و هذا فيوران فيوران اذا هذا مركب اندول + +792 +01:13:07,760 --> 01:13:17,300 +استعمل الأسود يمكن اوضح فيورو فيورو + +793 +01:13:17,300 --> 01:13:23,810 +اندول الاندول من وين شابك بي اي بي one two three2 + +794 +01:13:23,810 --> 01:13:29,970 +,3,b الان ماعدى ذلك لو كنتوا تعملوا الترقيم من عند + +795 +01:13:29,970 --> 01:13:40,570 +ال oxygen كام substitute وانت فيه واحدة لحظه + +796 +01:13:40,570 --> 01:13:42,870 +كان ممكن ال double bond يكون هنا و انا وجدت ال + +797 +01:13:42,870 --> 01:13:48,770 +atom هنا صح ولا لأ طبعا لما بدى ارقم من ال oxygen + +798 +01:13:48,770 --> 01:13:55,120 +للخارج او من هناالاربع احتمالات اللى بدأ ارقم منهم + +799 +01:13:55,120 --> 01:14:00,340 +وين هم اكسوجين مش + +800 +01:14:00,340 --> 01:14:06,360 +هدولة تلت حلقات هي خطوط ال fusion هذا خط وين + +801 +01:14:06,360 --> 01:14:11,380 +الاربع احتمالات اللى بدأ انطلق منهم اكسوجين اللى + +802 +01:14:11,380 --> 01:14:12,280 +جنب ال fusion + +803 +01:14:18,050 --> 01:14:23,670 +هذا الترقيم أعطاني واحد تنين تلاتة أربعة تلاتة + +804 +01:14:23,670 --> 01:14:28,190 +وأربعة هذا الترقيم واحد تنين تلاتة أربعة خمسة ستة + +805 +01:14:28,190 --> 01:14:36,870 +سبعة كتير واحد وسبعة تمانية هذا الترقيم عالي جدا + +806 +01:14:36,870 --> 01:14:43,970 +هذا الترقيم واحد تنين تلاتة أربعة خمسة ستة أنه أقل + +807 +01:14:43,970 --> 01:14:44,550 +ترقيم + +808 +01:14:54,620 --> 01:14:57,740 +ثمانية .. لاحظوا لما يكون عندى two fusions جانب + +809 +01:14:57,740 --> 01:15:05,360 +بعض ايش بقول تمانية prime تمانية double prime دولة + +810 +01:15:05,360 --> 01:15:12,260 +two fusions ورا بعض واضح طبعا واضح ان ال H طلعت + +811 +01:15:12,260 --> 01:15:19,060 +على اي رقم هنا four H four + +812 +01:15:19,060 --> 01:15:25,340 +H في euro two three B in دولفور أتش فيورو تو ثري + +813 +01:15:25,340 --> 01:15:32,700 +بي في دولة بايران بايران بايرينو + +814 +01:15:32,700 --> 01:15:42,080 +البايرين لو انوجدت بايرينو واضح هذه الأمثلة طبعا + +815 +01:15:42,080 --> 01:15:49,980 +بضل عندنا تسمية الاش ال spyro compounds ال spyro + +816 +01:15:49,980 --> 01:15:57,270 +compounds بدهم مش أقلمن تلت ساعة لكل ما بتحلوا كل + +817 +01:15:57,270 --> 01:16:00,410 +ما بجيبوا أمثلة من الكتب من المجلات مسمية و + +818 +01:16:00,410 --> 01:16:05,370 +بتطبقوا عليها القواعد بتتقنوا الكلام واضح؟ ابهيك + +819 +01:16:05,370 --> 01:16:08,090 +بننهي اليوم ان شاء الله + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/PM-rNe4EDFE_postprocess.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/PM-rNe4EDFE_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..2100a963ebef87808df3a77d52e27d4215a3f89e --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/PM-rNe4EDFE_postprocess.srt @@ -0,0 +1,2444 @@ +1 +00:00:21,260 --> 00:00:26,340 +بسم الله الرحمن الرحيم بعد ما أخدنا الطرق العامة + +2 +00:00:26,340 --> 00:00:31,560 +لتحضير ال heterocycles انتقلنا لاخذ أنفلة محددة + +3 +00:00:31,560 --> 00:00:36,380 +بدأنا بالحلقات السوداسية وأخدنا تقريبا من أشهر + +4 +00:00:36,380 --> 00:00:40,120 +الحلقات السوداسية الberidine في المرة الماضية، + +5 +00:00:40,120 --> 00:00:44,800 +الآن الberidine إذا صارموجود مع البنزين على شكل + +6 +00:00:44,800 --> 00:00:49,380 +fused rings بصير عند المركب بنزو بردين in + +7 +00:00:49,380 --> 00:00:55,220 +principle الان لما نيجي نطلع على ال بنزو بردين لو + +8 +00:00:55,220 --> 00:00:58,940 +بدنا نقول a b يعني بنزو b بردين و هنا لو بدنا نقول + +9 +00:00:58,940 --> 00:01:04,690 +a b c بنزو c بردينلكن ما حد بيسمي بهذه التسمية + +10 +00:01:04,690 --> 00:01:10,730 +هدول المركبين أخدوا أسماء شهرة يلتزم بها اللي هم + +11 +00:01:10,730 --> 00:01:15,250 +ال quinoline و ال isoquinoline اللي موجودين بهذا + +12 +00:01:15,250 --> 00:01:22,610 +الشكلفى الترقيم طبعا حسب القواعد المتبعة بدنا نبدأ + +13 +00:01:22,610 --> 00:01:26,070 +هان من ال nitrogen واحد اتنين تلاتة اربع خمسة و + +14 +00:01:26,070 --> 00:01:30,950 +هكذا طبعا بده يتبع الترقيم شغلة مهمة انه لو كانوا + +15 +00:01:30,950 --> 00:01:36,050 +هدول الحلقات effused مع حلقات تانية بده يكون هنا + +16 +00:01:36,050 --> 00:01:42,590 +عندى ايه؟و هنا عندى V و C و D و هكذا واضح؟ و لذلك + +17 +00:01:42,590 --> 00:01:45,410 +في ال isoquinoline لما بيكون ترقيم من هنا واحد + +18 +00:01:45,410 --> 00:01:51,230 +اتنين تلاتة بتكون هذه A وهذه B فلو اجى ال + +19 +00:01:51,230 --> 00:01:54,790 +isoquinoline مع حلقة تانية من هنا بيكون عامل + +20 +00:01:54,790 --> 00:02:00,310 +fusion من وين من B إذا كان هو ال base component ان + +21 +00:02:00,310 --> 00:02:06,800 +كون منتبهين لهذه النقطة الآنلو بدنا نشوف كيف طرق + +22 +00:02:06,800 --> 00:02:12,100 +تحضير الكوينولين والايزو كوينولين هتلاحظوا انه + +23 +00:02:12,100 --> 00:02:18,300 +بالمجمل هي طرق تقليدية كل الكيميا بالمناسبة مع + +24 +00:02:18,300 --> 00:02:22,580 +مرور الوقت بتصير أمرها سهليعني في النهاية إذا + +25 +00:02:22,580 --> 00:02:27,460 +الكيميا بدها تصفى على ال nucleophile و ال + +26 +00:02:27,460 --> 00:02:31,820 +electrophile هالكلمتين أو free radicals يعني في + +27 +00:02:31,820 --> 00:02:34,340 +النهاية أنا بدي bond يبدأ أجيبها nucleophile و + +28 +00:02:34,340 --> 00:02:38,900 +electrophile 2 زائد 0 بيساوي 2 او free radicals 1 + +29 +00:02:38,900 --> 00:02:43,000 +زايد 1 بيساوي 2 و بتصفى تلت ارباع الكيميا بهذا + +30 +00:02:43,000 --> 00:02:46,700 +الشكل معنادالك الكيميا ضمن هالمبدأ العام بتصير + +31 +00:02:46,700 --> 00:02:52,770 +إيش؟ربما من أسهل .. ربما من أسهل العلوم في عدة طرق + +32 +00:02:52,770 --> 00:02:57,930 +للكوينولين synthesis منها اللي بنسمي احنا scrub + +33 +00:02:57,930 --> 00:03:01,650 +synthesis هنا هتلاحظوا أسماء كتيرة انا بهمن الفكرة + +34 +00:03:01,650 --> 00:03:06,150 +مانديش احفظ انه scrub هو هذا دويبنر فون ميلر هو + +35 +00:03:06,150 --> 00:03:11,150 +هذا فريد ليندر هو هذا لأ بناخد الفكرة scrub اللي + +36 +00:03:11,150 --> 00:03:16,050 +عملوا خلط الانيلين مع الجليسرين مع حمض الكابريتيك + +37 +00:03:16,050 --> 00:03:20,790 +طلع عنده كوينولينAniline، Glycerin، حمض كابريتيك + +38 +00:03:20,790 --> 00:03:26,930 +الآن كلنا بنعرف لجليسرين كام كاربون، تلاتة و عليهم + +39 +00:03:26,930 --> 00:03:33,050 +OHs لما فهموا التفاعل جيدا لما فهموا التفاعل جيدا + +40 +00:03:33,050 --> 00:03:36,650 +لجليسرين مع حمض الكابريتيك بيعطينا ال + +41 +00:03:36,650 --> 00:03:41,330 +Acrylaldehyde هذا هاي كاربون تلتين تلاتة وحدة في + +42 +00:03:41,330 --> 00:03:46,970 +ميه من هناو أتش و أتش و عمل كمان مية تانية و عمل + +43 +00:03:46,970 --> 00:03:50,790 +oxidation واضح؟ يعني حدفت انتين أتش و عمل + +44 +00:03:50,790 --> 00:03:55,810 +oxidation فصار عندي هذا ال alpha beta unsaturated + +45 +00:03:55,810 --> 00:03:59,990 +carbonyl compound اللي احنا بنسميه ايش؟ + +46 +00:03:59,990 --> 00:04:04,970 +Acrylaldehyde و منه ال Acrylonitrile لما بيكون + +47 +00:04:04,970 --> 00:04:11,310 +عندىCN واضحة الفكرة؟ ربما هذا الكلام اجيبنا بس + +48 +00:04:11,310 --> 00:04:15,130 +كثقافة، مديش اتعب كتير في هذه النقطة، هذا المركب + +49 +00:04:15,130 --> 00:04:21,490 +اللي لو الناس حطوا في مواتير السيارات .. لو الناس + +50 +00:04:21,490 --> 00:04:26,810 +حطوا في مواتير السياراتالسيرج بدل الوقود سيارات + +51 +00:04:26,810 --> 00:04:31,850 +الديزل فحركة ال glycerin بيطلع هذا المركب اللي + +52 +00:04:31,850 --> 00:04:35,810 +بيعمل رائحة نفاذة وبتعرفوا بغزة نتيجة الحصار + +53 +00:04:35,810 --> 00:04:39,690 +السيارات والباصات اللي بتمشي على الديزل استعملوا + +54 +00:04:39,690 --> 00:04:44,190 +الزيوت مكان الوقود اللي هي السيرج وقشة وكان يطلع + +55 +00:04:44,190 --> 00:04:48,370 +هذا المركب المزعج من ال glycerin اللي بيجي من تكسر + +56 +00:04:48,370 --> 00:04:53,380 +الزيوتفي كل الأحوال إذا وصلت الأمور زي هيك قليلين + +57 +00:04:53,380 --> 00:04:57,020 +و Alpha Beta Unsaturated Carbonyl Compounds بيصير + +58 +00:04:57,020 --> 00:05:02,260 +بالزمن الجلمين الأحمر والإيش والأزرق ال + +59 +00:05:05,040 --> 00:05:10,480 +و عند النزوم ال ortho position is اليوكليوفايل هذه + +60 +00:05:10,480 --> 00:05:14,040 +ال alpha beta unsaturated carbonyl compound في + +61 +00:05:14,040 --> 00:05:17,660 +النهاية بيصير عليها اي تفاعل Michael addition + +62 +00:05:17,660 --> 00:05:23,580 +الاضافة على هذا الطرف الطرف البعيد هيعملنا هنا ال + +63 +00:05:23,580 --> 00:05:26,100 +Michael addition و حولنا ال double bond الى single + +64 +00:05:26,100 --> 00:05:29,240 +bond هذا اليوكليوفايل مع ال electrophile + +65 +00:05:33,060 --> 00:05:38,180 +بطلع عندى Equinoline واضحة الفكرة؟ الان اصل الـ + +66 +00:05:38,180 --> 00:05:42,400 +Scrap Synthesis ماكنش هذا المركب كان Glycerin + +67 +00:05:42,400 --> 00:05:46,500 +H2SO4 لكن لما فهموا التفاعل قالوا هدول الاتنين + +68 +00:05:46,500 --> 00:05:51,040 +بيطلعوا هذا المركب الان صار الناس اللى فهمت + +69 +00:05:51,040 --> 00:05:54,560 +التفاعل جيدا يقولوا طب لو جيبنا اي Alpha Beta + +70 +00:05:54,560 --> 00:05:58,000 +Unsaturated Carbonyl Compound بحطينا هنا Methyl, + +71 +00:05:58,100 --> 00:06:02,080 +Ethyl, Propylحضرناها بأي طريقة تانية يعني مش ضرورة + +72 +00:06:02,080 --> 00:06:05,020 +من ال glycerin و ال sulfuric acid يعني جيبناها + +73 +00:06:05,020 --> 00:06:08,660 +substituted alpha beta unsaturated carbonyl + +74 +00:06:08,660 --> 00:06:13,120 +compound وفعلنا نفس التفاعل هيعمل نفس الشيء لكن + +75 +00:06:13,120 --> 00:06:16,260 +هيطلع عند البريدين في هذا ال .. الليكونولين في هذا + +76 +00:06:16,260 --> 00:06:19,880 +الحالة substituted هذا deutner von miller + +77 +00:06:19,880 --> 00:06:25,200 +synthesis فهو واضح أن هو اشتقاق من ال scrub + +78 +00:06:25,200 --> 00:06:30,090 +synthesisيعني فهم القصة جيدة وكرر المثال مع + +79 +00:06:30,090 --> 00:06:35,210 +substituted alpha beta unsaturated aldehyde واضح + +80 +00:06:35,210 --> 00:06:42,070 +الفكرة؟ فدولة يخرجوا من مشكات واحدة + +81 +00:06:43,220 --> 00:06:48,920 +الان لو اجينا لتحضير تالق compass synthesis سهل + +82 +00:06:48,920 --> 00:06:52,040 +جدا هذا nucleophile و ال orthoposition ال + +83 +00:06:52,040 --> 00:06:55,620 +principle is a nucleophile الان التنتين ال c + +84 +00:06:55,620 --> 00:07:02,440 +double bond o's they are electrophiles نبدأ من هنا + +85 +00:07:02,440 --> 00:07:05,660 +ال n h2o مع ال c double bond o و c double bond n و + +86 +00:07:05,660 --> 00:07:09,440 +ال orthoposition بيهاجم هان زي ما اتعلمنا مافيش + +87 +00:07:09,440 --> 00:07:16,020 +فيها ولا مشكلةلو اتينا لفريد ليندار ال synthesis + +88 +00:07:16,020 --> 00:07:23,390 +مرات هذا بتلاقوه في الكتب ايه فوق نقطينأما لاندر + +89 +00:07:23,390 --> 00:07:27,950 +اللي هي ال A الممالة للكاسر طبعا اللي بالكمبيوتر + +90 +00:07:27,950 --> 00:07:32,370 +ماعنده A عنده نقطين بيحطها A بعدها E و كذلك ال O + +91 +00:07:32,370 --> 00:07:37,010 +بيحطها O بعدها E و هكذا في الكتابة هذا أيضا من + +92 +00:07:37,010 --> 00:07:40,910 +ناحية المبدأ هذا أيضا من ناحية المبدأ nucleophile + +93 +00:07:40,910 --> 00:07:44,730 +و electrophile يعني أنا هنا لما بيكون في عندي + +94 +00:07:44,730 --> 00:07:51,350 +activated methylene group هذا in principle minus و + +95 +00:07:51,350 --> 00:07:58,900 +هناالان ال N O2 بيعملها reduction بعد ما يشبك + +96 +00:07:58,900 --> 00:08:02,940 +هدولة ال N O2 بيعملها reduction يعني بيخليها N H2 + +97 +00:08:02,940 --> 00:08:14,110 +صارت minus و هذه plus فاحنا بنشبك هنابعدين استعمال + +98 +00:08:14,110 --> 00:08:19,010 +base بيصير minus بنشبكه، بعدين ال N O2 بال + +99 +00:08:19,010 --> 00:08:23,270 +reduction بتصير N H2 N H2 C double bond O C double + +100 +00:08:23,270 --> 00:08:28,600 +bond Nواضح؟ فلحتى الآن قاعدة فعلا أن الأفكار اللي + +101 +00:08:28,600 --> 00:08:33,460 +موجودة ومستعملة هي أفكار بسيطة مكررة معتمدة على + +102 +00:08:33,460 --> 00:08:36,840 +فهمنا اللي أخدناه في ال cyclization reactions + +103 +00:08:36,840 --> 00:08:41,000 +ولذلك يعني احنا اهتمنا أن ندرس ال course مش كأنفلة + +104 +00:08:41,000 --> 00:08:46,580 +لأن ندرس المبدأ في الأساس و بعدين بتلاحظوا انه + +105 +00:08:46,580 --> 00:08:50,320 +كوينولين ايزو كوينولين وغيره يعني لما ابدي اجي + +106 +00:08:50,320 --> 00:08:54,020 +الآن لل ايزو كوينولين هلاجي مرة تانية الفكرة + +107 +00:08:55,120 --> 00:08:59,980 +اليوكليوفايل الالكتروفايل مش ازيادة يعني لو أخذنا + +108 +00:08:59,980 --> 00:09:03,040 +هذا المركب هنا في عند اليوكليوفايل و ال + +109 +00:09:03,040 --> 00:09:09,580 +orthoposition is اليوكليوفايل الان ال acid halides + +110 +00:09:09,580 --> 00:09:15,020 +are dielectrophiles دالكم متساكنينها هذه + +111 +00:09:15,020 --> 00:09:18,320 +dielectrophile + +112 +00:09:21,280 --> 00:09:26,580 +ليش؟ بنشوف مشهد اي موجة بـ Acid chloride لما هنا + +113 +00:09:26,580 --> 00:09:29,320 +يصير الهجوم شو بده يصير عليها اول تفاعل + +114 +00:09:29,320 --> 00:09:33,400 +Substitution is ان هي بيستفدت منك Electrophile + +115 +00:09:33,400 --> 00:09:38,680 +صارت هنا C double bond O هي موجة مرة تانية ايش بده + +116 +00:09:38,680 --> 00:09:43,300 +يصير عليك؟ addition in this case بتصير OH و ال OH + +117 +00:09:43,300 --> 00:09:48,000 +مع ال H بتحدث و لاحظوا بعدين هو عمل عملية + +118 +00:09:48,000 --> 00:09:52,550 +oxidation إضافية بده شوق شوية أصعبواضحة الفكرة؟ + +119 +00:09:52,550 --> 00:09:59,430 +فضلنا متذكرين ال yeast و ال acid halides و ال acid + +120 +00:09:59,430 --> 00:10:03,470 +anhydrides in principle they are dielectrophiles + +121 +00:10:03,470 --> 00:10:06,890 +they act as dielectrophiles هذا الكلام حتى في ال + +122 +00:10:06,890 --> 00:10:11,750 +organic synthesis العامة بفيدكم لأنه جزء كبير من + +123 +00:10:11,750 --> 00:10:15,090 +فهم ال organic synthesis نفهم ال electrophiles و + +124 +00:10:15,090 --> 00:10:19,810 +ال nucleophilesكذلك الحال ال .. ال .. ال .. ال .. + +125 +00:10:19,810 --> 00:10:21,050 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +126 +00:10:21,050 --> 00:10:21,370 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +127 +00:10:21,370 --> 00:10:22,370 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +128 +00:10:22,370 --> 00:10:23,730 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +129 +00:10:23,730 --> 00:10:27,770 +ال .. ال .. ال .. ال .. ال .. + +130 +00:10:27,770 --> 00:10:28,310 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +131 +00:10:28,310 --> 00:10:28,790 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +132 +00:10:28,790 --> 00:10:30,930 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +133 +00:10:30,930 --> 00:10:31,370 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +134 +00:10:31,370 --> 00:10:31,390 +ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال + +135 +00:10:31,390 --> 00:10:32,430 +.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. + +136 +00:10:32,430 --> 00:10:34,220 +.. ال .. ال .. ال .. ال .. ال .. ال .. الانا هاي + +137 +00:10:34,220 --> 00:10:38,880 +في عندى اكيد ال dying nuclei فاي ال two minuses + +138 +00:10:38,880 --> 00:10:46,060 +لما ال N H2 بده تهاجم هنا هتعمل C double bond N ال + +139 +00:10:46,060 --> 00:10:50,720 +N ال C double bond N ال nitrogen is more + +140 +00:10:50,720 --> 00:10:53,740 +electronegative than carbon اذا هذه ال carbon + +141 +00:10:53,740 --> 00:11:00,950 +موجبة هاي موجةوهي موجة فمن ال الديهايد كأنه صار + +142 +00:11:00,950 --> 00:11:05,050 +عندك الموجة مرتين إجا منه في الأول و بعدين لما صار + +143 +00:11:05,050 --> 00:11:09,030 +C double bond N يعني هذه ال C كأنها موجة بمرتين في + +144 +00:11:09,030 --> 00:11:11,770 +المرة الأولى مع ال الديهايد صارت C double bond N + +145 +00:11:11,770 --> 00:11:16,670 +صارت موجة بقىو لذلك هاي انا عندى ال die + +146 +00:11:16,670 --> 00:11:21,110 +nucleophile اتفعل اول ال nucleophile و اتفعل تاني + +147 +00:11:21,110 --> 00:11:26,670 +nucleophile و عمل عندنا ايش ال cyclization و عمل + +148 +00:11:26,670 --> 00:11:31,450 +عندنا ال cyclization هذا + +149 +00:11:31,450 --> 00:11:36,150 +ايش بيسموه pectid sphingular isoquinoline + +150 +00:11:36,150 --> 00:11:42,510 +synthesis Boomerang synthesis لو بنجى بنطلع عليه + +151 +00:11:42,510 --> 00:11:46,610 +فى عندنا هناالـ Eucleophil في عندنا هنا + +152 +00:11:46,610 --> 00:11:53,670 +Electrophile الـ NH2 عبارة عن الـ Eucleophil دائما + +153 +00:11:53,670 --> 00:11:57,570 +إذا لجينا الـ NH2 مع الـ C double bond O بدنا + +154 +00:11:57,570 --> 00:12:01,630 +نتوقع أن نعمل C double bond N لو لجيناها مع halide + +155 +00:12:01,630 --> 00:12:04,230 +أو إيش ممكن تعمل substitution زي ما شوفته في + +156 +00:12:04,230 --> 00:12:08,910 +الأمثلة هي NH2 مع C double bond N مع C double bond + +157 +00:12:08,910 --> 00:12:12,590 +O C double bond N عملنا أول رابطة الآن هنا عندي O + +158 +00:12:12,590 --> 00:12:17,250 +-ethylهدولة they are good living group in + +159 +00:12:17,250 --> 00:12:23,010 +principle يعني هي السالب وهي الموجب substitution + +160 +00:12:23,010 --> 00:12:26,550 +ال Oethyl لما تحذف مع القتش اللي هنا في النهاية + +161 +00:12:26,550 --> 00:12:33,150 +Ethanol ضال عندى كمان Oethyl مع قتش تانية يعني + +162 +00:12:33,150 --> 00:12:37,670 +بحذف ال Ethanol كم مرة مرتين فبطلع عندى + +163 +00:12:39,190 --> 00:12:42,910 +Isoquinoline هذا بيسميه Boomerangs Fritz + +164 +00:12:42,910 --> 00:12:49,530 +Boomerangs Fritz Synthesis الآن زي ما بتلاحظوا أنه + +165 +00:12:49,530 --> 00:12:52,870 +طرق تحضير ال Equinolines و Isoquinolines كانوا + +166 +00:12:52,870 --> 00:12:55,990 +مسميات كثيرة ماكنش هيكوا تحفظوا ولا مسمى لكن + +167 +00:12:55,990 --> 00:13:00,590 +كأفكار لو قولنا أكمل أي معادلة بيبين أنه الفكرة + +168 +00:13:00,590 --> 00:13:07,010 +أنه على الامتحان الطالب يجيب إيشجلمين أزرق و أحمر + +169 +00:13:07,010 --> 00:13:10,890 +الأحمر لليوكليوفال يفهموا أين بالظبط والأزرق + +170 +00:13:10,890 --> 00:13:15,670 +للإلكتروفال والكيميا في النهاية بوجبه السادس واضح؟ + +171 +00:13:15,670 --> 00:13:18,790 +الآن لو جينا لـchemistry of equanoline and + +172 +00:13:18,790 --> 00:13:23,070 +isoquinoline نبدأ بالـEucleophilic Substitution + +173 +00:13:24,820 --> 00:13:29,220 +الان مر معناه المرة الماضية في البريدين الـ chiba + +174 +00:13:29,220 --> 00:13:33,800 +bean reaction اللى بيساعد عليه وجود ال nitrogen و + +175 +00:13:33,800 --> 00:13:39,620 +بيتم عادةجنب الـ Nitrogen ففي الكوينولين هي الموقع + +176 +00:13:39,620 --> 00:13:42,720 +اللي جنب الـ Nitrogen وفي ال ISO كوينولين هذا + +177 +00:13:42,720 --> 00:13:45,600 +الموقع اللي عادة بتتم عليه اللي هو الموقع المجاور + +178 +00:13:45,600 --> 00:13:49,820 +لـ Nitrogen عشان لما النيوكليوفاين ييجي ال + +179 +00:13:49,820 --> 00:13:53,240 +Nitrogen بصفتها Electronegative أتم تحمل الشحن + +180 +00:13:53,240 --> 00:13:56,940 +السالي بقى هي المشكلة أنه بدو ييجي السالي بيهاجم + +181 +00:13:56,940 --> 00:14:02,110 +علىسالد لأن الحلقة كلها كثافة إلكترونية عشان اكل + +182 +00:14:02,110 --> 00:14:05,290 +الـ Eucleophilic Substitution على الـ Aromatic صعب + +183 +00:14:05,290 --> 00:14:10,870 +لأن الـ Eucleophile بتيجي على إلكترونات لكن هنا + +184 +00:14:10,870 --> 00:14:14,770 +وجود الـ Nitrogen لما ييجي الـ Eucleophile بهذا + +185 +00:14:14,770 --> 00:14:20,550 +الشكل الآن الـ Nitrogen بتحمل الإلكترونات و بساعد + +186 +00:14:20,550 --> 00:14:27,450 +في الحمل أنه بيجي جنبها ال Sodium Plusواضح الفكرة + +187 +00:14:27,450 --> 00:14:31,150 +يعني هنا بتيجي ال N H2 هذا left صارت N minus N + +188 +00:14:31,150 --> 00:14:36,550 +minus جنب ال A plus بيمشي بعدين بتم الفقد بيكتمل + +189 +00:14:36,550 --> 00:14:39,230 +ال nucleophilic substitution الميكانيزم وضحناه في + +190 +00:14:39,230 --> 00:14:43,670 +حالةالبريدين مافيش داعي نعيدها الان اللي بنحكي + +191 +00:14:43,670 --> 00:14:49,910 +احنا انه ال reaction بيعمل amination للكوينولين و + +192 +00:14:49,910 --> 00:14:52,530 +ايزو كوينولين ال amination ل الكوينولين على + +193 +00:14:52,530 --> 00:14:55,950 +position 2 و ال amination ل الايزو كوينولين على + +194 +00:14:55,950 --> 00:15:01,070 +position 1 و كيف بتتم العملية نفس ما كانت في حالة + +195 +00:15:01,070 --> 00:15:07,350 +ايش البريدين مرة واحدة نشرح التفاعلالان بنفس + +196 +00:15:07,350 --> 00:15:12,410 +المنطق لو فعلنا مع ال KOH بدل ما يكون ال + +197 +00:15:12,410 --> 00:15:17,410 +nucleophile في ال chichibabine reaction NH2 الان + +198 +00:15:17,410 --> 00:15:22,190 +بيكون OH هتيجي ال OH على هذا الموقع او على هذا + +199 +00:15:22,190 --> 00:15:26,950 +الموقع و اذا عملنا tautomerism بتصير هذه C double + +200 +00:15:26,950 --> 00:15:30,250 +bond O او C double bond O بهذا الشكل اذا هذا + +201 +00:15:30,250 --> 00:15:35,010 +التفاعل مع ال KOH على الحرارة الموضحة هو نفس فكرة + +202 +00:15:36,440 --> 00:15:39,440 +لتشيطش بابيل reaction in principle الـ + +203 +00:15:39,440 --> 00:15:43,980 +eucleophilic substitution هجمت الـ OH و طردت الـ H + +204 +00:15:43,980 --> 00:15:48,180 +مع الالكترونيرف ان يوكليوفايل ماكان يوكليوفايل + +205 +00:15:48,180 --> 00:15:53,300 +واضحة الان + +206 +00:15:53,300 --> 00:15:59,180 +ممكن تمل الـ eucleophilic substitution على غير + +207 +00:16:00,250 --> 00:16:05,010 +الهيدروجين يعني مش بس الهيدروجين تبدل لأ ممكن ايضا + +208 +00:16:05,010 --> 00:16:11,190 +ال halogens يتم عليها ابدال اذا بنلاحظ في حالة + +209 +00:16:11,190 --> 00:16:18,870 +الكوينولين بتم ابدال عن موقع اتنين واربعة بشكل سهل + +210 +00:16:18,870 --> 00:16:24,530 +وفي حالة ال isoquinoline بتم الابدال عن موقع واحد + +211 +00:16:24,530 --> 00:16:32,330 +بشكل سهلولذلك لاحظوا هنا لو فعلنا فينيل CH2CN مع + +212 +00:16:32,330 --> 00:16:37,730 +Sodium Nitrate الفينيل CH2CN مع ال base هذا ال + +213 +00:16:37,730 --> 00:16:44,010 +strong base ال Sodamide هتصير ال CH2 نيجاتيف الآن + +214 +00:16:44,010 --> 00:16:47,670 +هي نيوكليوفايل هذا ال نيوكليوفايل بده يحل محل + +215 +00:16:47,670 --> 00:16:50,870 +واحدة من ال chlorine في عندى chlorine على موقع + +216 +00:16:50,870 --> 00:16:57,090 +اربعةأربعة برايم خمسة ستة سبعة أربعة وسبعة محل أي + +217 +00:16:57,090 --> 00:17:02,030 +واحدة بحل محل أربعة اذا هنا صار عندي selective + +218 +00:17:02,030 --> 00:17:06,630 +substitution يعني في عندي تنتين كلورين تنتين + +219 +00:17:06,630 --> 00:17:11,510 +كلورين لكن ال substitution تم على موقع أربعة مش + +220 +00:17:11,510 --> 00:17:17,020 +على موقع سبعة عادة لل nucleophilic substitutionفي + +221 +00:17:17,020 --> 00:17:21,020 +الكوينولين بتتم على اتنين او اربعة الان اربعة + +222 +00:17:21,020 --> 00:17:25,020 +موجود عليها و سبعة موجود عليها ايه أسهل؟ اربعة + +223 +00:17:25,020 --> 00:17:28,800 +أسهل من سبعة في المثال اللي بعده هاين دي كلور على + +224 +00:17:28,800 --> 00:17:32,020 +واحد و على تلاتة في ال ISO كوينولين ال + +225 +00:17:32,020 --> 00:17:35,900 +substitution بتتم بسهولة على موقع واحد ولذلك لما + +226 +00:17:35,900 --> 00:17:42,570 +فعلنا هنا مع ال Malonic yeastاللي هو في وجود base + +227 +00:17:42,570 --> 00:17:45,390 +زي Sodium Hydride او غيره هيصير ايون سالب في + +228 +00:17:45,390 --> 00:17:51,070 +النهاية حال ما حل اي chlorine على موقع واحد برضه + +229 +00:17:51,070 --> 00:17:54,970 +selective substitution اذا لو احنا و مرات كثيرة + +230 +00:17:54,970 --> 00:17:58,350 +بنيجي بنسأل الطلاب والله ال eucleophilic + +231 +00:17:58,350 --> 00:18:02,490 +substitution occurs at position فراغ في الكونولين + +232 +00:18:02,490 --> 00:18:08,130 +two في ال isoquinemainly two لو بتحكي اتش اتش + +233 +00:18:08,130 --> 00:18:11,470 +بابيه ال reaction او هنا على اتنين و اربع في ال + +234 +00:18:11,470 --> 00:18:15,770 +eyes of quinoline واحد موقع واحد طبعا ال + +235 +00:18:15,770 --> 00:18:19,050 +electrophilic substitution و ال nucleophilic + +236 +00:18:19,050 --> 00:18:22,230 +substitution على الberidine أخدناهم كانوا على + +237 +00:18:22,230 --> 00:18:25,630 +الberidine على موقع اتنين و ال electrophilic + +238 +00:18:25,630 --> 00:18:31,200 +substitution على موقع تلاتةو البريدين أن أكسيد + +239 +00:18:31,200 --> 00:18:35,800 +بيعمل إبدال على بوقع أربعة لما نتذكر هذه الأشياء + +240 +00:18:35,800 --> 00:18:39,320 +الأن طيب ال electrophilic substitution على + +241 +00:18:39,320 --> 00:18:43,180 +الكوينولين و ال ISO كوينولين وين بتبدأ؟الـ + +242 +00:18:43,180 --> 00:18:45,880 +Electrophilic Substitution على الكوينولين ايزو + +243 +00:18:45,880 --> 00:18:49,160 +كوينولين بتمشي على حلقة البريدين بتم على حلقة + +244 +00:18:49,160 --> 00:18:54,460 +البنزين اللي جامعه على مواقع خمسة او تمانية في + +245 +00:18:54,460 --> 00:18:59,420 +مرات جليلة بتم على الموقعين بس غالبا حسب التجربة + +246 +00:18:59,420 --> 00:19:03,800 +يا بتم على خمسة يا بتم على تمانية الحكم ان هي هو + +247 +00:19:03,800 --> 00:19:09,560 +التجربة يعني لو كان ال Electrophile Deuterium في + +248 +00:19:09,560 --> 00:19:15,590 +الكوينولين بتم على موقع تمانيةالـ Nitration في + +249 +00:19:15,590 --> 00:19:20,450 +الكوالولين بتم على خمسة و تمانية بنسبة واحد لواحد + +250 +00:19:20,450 --> 00:19:26,330 +البروميناشن بتم على خمسة فقط ال sulfonation بتم + +251 +00:19:26,330 --> 00:19:30,310 +على تمانية فقطفي كل الأحوال هذه نتائج تجربية، لكن + +252 +00:19:30,310 --> 00:19:36,030 +الكلمة العامة أن الـ Electrophilic Substitution في + +253 +00:19:36,030 --> 00:19:38,770 +الكوينولين، في الأيزوكوينولين بتم على خمسة أو + +254 +00:19:38,770 --> 00:19:44,470 +تمانية أو الموقعين معاهم، الأيزوكوينولين مثلا + +255 +00:19:44,470 --> 00:19:49,170 +لديوتيريا بتم على خمسة، الـNitration بتم على خمسة + +256 +00:19:49,170 --> 00:19:53,680 +و تمانية، لكن الآن النسبةتس على واحد البروميناشن + +257 +00:19:53,680 --> 00:19:59,600 +بتتم على خمسة واضح كل هذه في نهاية نتائج تجربية + +258 +00:19:59,600 --> 00:20:03,080 +يعني مش مطلوب من الطالب انه يحفظها بس بيظلم + +259 +00:20:03,080 --> 00:20:06,400 +الذاكرين انه لو بدنا electrophilic substitution at + +260 +00:20:06,400 --> 00:20:10,120 +quinoline او isoquinoline it occurs at positions + +261 +00:20:10,120 --> 00:20:17,080 +five and eight اخر slide في هذا الموضوع لquinoline + +262 +00:20:17,080 --> 00:20:22,380 +and oxidesطبعا بنعرف كيف نعمل كوينولين أن أكسيد زي + +263 +00:20:22,380 --> 00:20:27,520 +ما عملنا البريدين أن أكسيد ان احنا بناخد كوينولين + +264 +00:20:27,520 --> 00:20:32,920 +مع bare acid بيعملنا كوينولين أن أكسيد الان هذا + +265 +00:20:32,920 --> 00:20:36,500 +الكوينولين أن أكسيد عملوا عليه بعض الكيميا الممتعة + +266 +00:20:36,500 --> 00:20:41,780 +عملوله فوتوليسيز عملوله فوتوليسيز طبعا + +267 +00:20:41,780 --> 00:20:45,960 +بالفوتوليسيز حصلوا على هدولة المركبين كنتائج + +268 +00:20:45,960 --> 00:20:53,460 +نهائيةواضح؟ يعني equinoline two own وهذا بنزو + +269 +00:20:53,460 --> 00:21:00,180 +اكزازيبين وانت three اكزازيبين، واضح؟الان لو قلنا + +270 +00:21:00,180 --> 00:21:05,440 +بدنا نفسر كيف من هذا المُركّب بالفوتوليسيز بنحصل + +271 +00:21:05,440 --> 00:21:10,240 +على هدول المُركّبين الان بيفترضوا انه هذه ال + +272 +00:21:10,240 --> 00:21:15,480 +oxygen ممكن ك intermediate تعمل حلقة ثلاثية هنا + +273 +00:21:15,480 --> 00:21:20,880 +بعد هيك هذه الحلقة الثلاثية ممكن تفتح من هذا + +274 +00:21:20,880 --> 00:21:25,350 +الموقعمكان هذه الرابطة لو فتحت مكان هذه الرابطة + +275 +00:21:25,350 --> 00:21:30,430 +هيصير عندي O minus لو عملنا ترتيب للإلكترونات خلاص + +276 +00:21:30,430 --> 00:21:35,290 +صرنا نجلين ال O هنا يعني بمعنى أن ال O شو اللي + +277 +00:21:35,290 --> 00:21:42,950 +نقلهامن موقع واحد لموقع اتنين هذا تماما زي بني ادم + +278 +00:21:42,950 --> 00:21:49,830 +هيك بتتخيلوا الامر زي بني ادم او خلينا نقول لسه + +279 +00:21:49,830 --> 00:21:53,910 +بيجري بين المباني المتقاربة كان على هذا الموقع + +280 +00:21:53,910 --> 00:21:57,390 +بعدين صار على هذا الموقع بعدين صار على هذا الموقع + +281 +00:21:57,390 --> 00:22:01,670 +في كل الأحوال لما نقول كيف بده يصير هو بده يحط رجل + +282 +00:22:01,670 --> 00:22:08,530 +هنا ورجل هنا ع شكل مثلث بعدين بيسيب هذه واضح؟هي زي + +283 +00:22:08,530 --> 00:22:13,310 +هيك حط الرجلتين هيك ترك هذه انتقل موقع الان لو عمل + +284 +00:22:13,310 --> 00:22:18,750 +كمان شغلة بنتقل كمان موقع نفس الاشي هنا ال oxygen + +285 +00:22:18,750 --> 00:22:22,470 +هلاحظ انه انتقلت من ال nitrogen للكربون المجاورة + +286 +00:22:22,470 --> 00:22:28,530 +عبر حلقة ثلاثية الان في المركب اللي تحت ال oxygen + +287 +00:22:28,530 --> 00:22:36,380 +هلاحظ انه انتقلت ايش كمان نقلة تانيةواضح؟ ودخلت + +288 +00:22:36,380 --> 00:22:40,560 +جوا الحلقة الآن خلي هذا ال oxygen تكسر من هنا بعد + +289 +00:22:40,560 --> 00:22:44,940 +ما كسرت تروح تعمل حلقة بهذا الشكل و بعدين تفتح + +290 +00:22:44,940 --> 00:22:53,880 +الحلقات من هنا واضح؟ دخلت ال oxygen إيش؟ جوا + +291 +00:22:53,880 --> 00:23:00,280 +الحلقة كل هذا عبر الحلقاتثلاثية عبر three membered + +292 +00:23:00,280 --> 00:23:05,140 +.. three membered ring intermediate واضح؟ هذا طبعا + +293 +00:23:05,140 --> 00:23:09,520 +من باب التفسير ان جيد ان الانسان مرات يشوف شغلات + +294 +00:23:09,520 --> 00:23:13,820 +زي هيك على أساس انه في المستقبل لو افترضنا انه صار + +295 +00:23:13,820 --> 00:23:18,740 +عنده مثلا شغلة بده يفهمها اشي يكون مر عليه .. يكون + +296 +00:23:18,740 --> 00:23:26,370 +مر عليه مفاهيم من هذا القبيلهك تقريبا بنكون أعطينا + +297 +00:23:26,370 --> 00:23:33,670 +فكرة مجزة عن ال Equinoline و ال Isoequinoline + +298 +00:23:33,670 --> 00:23:43,310 +بعرفش ممكن نبدأ مباشرة في الجزء اللي بعد هيك اللي + +299 +00:23:43,310 --> 00:23:43,610 +هو + +300 +00:23:46,710 --> 00:23:52,490 +ال بيرونز ممكن نبدأ مباشرة في الجزء اللي بعد هيك + +301 +00:23:52,490 --> 00:23:57,330 +ال بيرونز ال + +302 +00:23:57,330 --> 00:24:02,430 +بيرونز هي المركبات اللي هي عبارة عن حلقات سداسية + +303 +00:24:02,430 --> 00:24:08,170 +فيها اكسجين طبعا هتلاحظوا مباشرة انه لما كان يكون + +304 +00:24:08,170 --> 00:24:16,600 +عندى نيترجل ال نيترجل بحتمل ايش؟النيتروجين بيحتمل + +305 +00:24:16,600 --> 00:24:20,620 +double bond وبالتالي ماكنش يكون عندى موجب لو بدى + +306 +00:24:20,620 --> 00:24:24,520 +اعمل اكسوجينو اعمل ال double bonds يعني اعمل هذا + +307 +00:24:24,520 --> 00:24:28,500 +ال aromatic system هيصير عندى موجب وجدتها اذا في + +308 +00:24:28,500 --> 00:24:32,680 +مركب هيصير على شكل salt انه ال oxygen موجبة و هنا + +309 +00:24:32,680 --> 00:24:38,860 +في عندى ايون سالب ايون سالب فبصير عنده band كامل + +310 +00:24:38,860 --> 00:24:43,840 +اسمه ال beryllium salts واضح ال beryllium salts + +311 +00:24:43,840 --> 00:24:49,300 +هدولة مركبات بناخد فكرة مختصرة عنهمالمراكبات + +312 +00:24:49,300 --> 00:24:54,580 +التانية إذا في عندي Oxygen و C double bond O الان + +313 +00:24:54,580 --> 00:24:58,060 +هدولة اللي موجود منهم ان تكون ال C double bond O + +314 +00:24:58,060 --> 00:25:03,780 +على موقع اتنين هذا بنسميه Alpha Byron او تكون على + +315 +00:25:03,780 --> 00:25:08,720 +موقع اربعة هاي Alpha Beta Gamma واحد اتنين تلاتة + +316 +00:25:08,720 --> 00:25:12,600 +اربعة اللي هو Gamma Byron طبعا ممكن نسميهم تسميات + +317 +00:25:12,600 --> 00:25:21,340 +عادية Two H Byronon أكيد بالإيه و for h بايرين for + +318 +00:25:21,340 --> 00:25:27,060 +on هذا بنسميه alpha byron و هذا بنسميه gamma byron + +319 +00:25:27,060 --> 00:25:32,560 +الآن اللي احنا بدنا ناخده فكرة أيضا مختصرة جدا حتى + +320 +00:25:32,560 --> 00:25:36,440 +تكون المراكبات معروفة لنا ع ال beryllium salts كيف + +321 +00:25:36,440 --> 00:25:41,340 +ممكن نحضرها كيف ممكن نشوف تفاعلاتها على ال alpha + +322 +00:25:41,340 --> 00:25:46,900 +byrons تحضيرهم أهم تفاعلاتهم و علىالـ Gamma By + +323 +00:25:46,900 --> 00:25:54,020 +Roles واضح؟ الآن ل preparation of beryllium salts + +324 +00:25:54,020 --> 00:26:00,750 +عادة ال beryllium salts بنحضرهم منالبريدين هنا + +325 +00:26:00,750 --> 00:26:06,350 +بنستعمل بيريدين حامل SO3 على ال N طبعا هيكون اكيد + +326 +00:26:06,350 --> 00:26:10,570 +هذي ال نيتروجين اشمالها موجبة يعني بيريدينيام + +327 +00:26:10,570 --> 00:26:15,550 +compounds او بيريدينيام salts مع ال OH- بيهاجموا + +328 +00:26:15,550 --> 00:26:19,030 +على الكربون و بيحطوا O و بيهاجموا و بيطردوا ال N + +329 +00:26:19,030 --> 00:26:22,530 +مع ال SO3 في النهاية بيصير عند سيدة بال bond O O + +330 +00:26:22,530 --> 00:26:28,020 +minus يعني بيعملواأول إشيرينج opening بعدين بيحلوا + +331 +00:26:28,020 --> 00:26:33,640 +محل إيش ال nitrogen و بيطردوها بصفع عندى تنتين C + +332 +00:26:33,640 --> 00:26:37,060 +double bond O الان واحدة منهم ال O minus بدا + +333 +00:26:37,060 --> 00:26:45,280 +تهاجمها بهذا الشكل و تسكر و تطرد ال OH فحيصير عندى + +334 +00:26:45,280 --> 00:26:50,310 +Oبتلت روابط ايش هتكون الموجة بهذا بتتم + +335 +00:26:50,310 --> 00:26:55,270 +بالبريكلوريك أسد فلاحظوا هنا البريكلوريك أسد ايون + +336 +00:26:55,270 --> 00:27:03,090 +السالب ClO4- فهذا بيصير بيريليام بيريكلوريت + +337 +00:27:03,090 --> 00:27:08,510 +بيريليام بيريكلوريت ما هو الايون السالب من + +338 +00:27:08,510 --> 00:27:16,120 +البريكلوريك أسدبريكلوريت واضح بريليام بير إكلوريت + +339 +00:27:16,120 --> 00:27:23,540 +هذه بشكل عام مثال على البريليام سولت هاي مثال + +340 +00:27:23,540 --> 00:27:28,700 +بريليام بير إكلوريت ممكن الناس يشتريوه موجود الآن + +341 +00:27:28,700 --> 00:27:34,460 +لو قولنا طيب البريليام سولت هذه كيف بدأت تتفاعل + +342 +00:27:34,460 --> 00:27:40,230 +برضه تفاعلها الأساسي ring opening هنامجاور لإيش؟ + +343 +00:27:40,230 --> 00:27:44,630 +للأكسجين على أساس أنه جنب الأكسجين بيكون في عنده + +344 +00:27:44,630 --> 00:27:49,130 +كمان موجة ممكن أي ليكليوفايل يهاجم هنا ويعمل ring + +345 +00:27:49,130 --> 00:27:55,250 +opening على سبيل المثال لو أخدنا الأنليل مثلاهي + +346 +00:27:55,250 --> 00:27:59,930 +انيلين خلوه يهاجم على الكاربون اللي موجود هنا صار + +347 +00:27:59,930 --> 00:28:05,570 +عند فن الان اتش وهذه صفية c double bond o مثل الان + +348 +00:28:05,570 --> 00:28:10,930 +ال nitrogen nucleophile بقدر يسكر على ال c double + +349 +00:28:10,930 --> 00:28:17,840 +bond o فين هيسكر ب c double bond انأو n-o-h طبعا + +350 +00:28:17,840 --> 00:28:23,400 +لأنه عند فنل مش قادر اعمل حذف فهيصف عندى في + +351 +00:28:23,400 --> 00:28:28,880 +النهاية ايش؟ Salt يعني هذا الايون الموجب هيكون معه + +352 +00:28:28,880 --> 00:28:39,760 +الايون السالب فبيطلع عندى peridinium salt + +353 +00:28:40,570 --> 00:28:45,310 +كذلك الحل لو جيبت النيوكليوفايل اكزيم ايش هيكون + +354 +00:28:45,310 --> 00:28:51,050 +اللي بده يهاجم هنا ال nitrogen هيفتح على C double + +355 +00:28:51,050 --> 00:28:55,610 +bond O و بعدين هيطرد ال C double bond O مرة تانية + +356 +00:28:55,610 --> 00:28:59,750 +حطيت هنا جزء النيوكليوفايل اللي هو ال nitrogen هنا + +357 +00:28:59,750 --> 00:29:04,310 +جزء النيوكليوفايل اللي هو ال nitrogen هناك ال + +358 +00:29:04,310 --> 00:29:10,350 +nitrogen كان بيحملالنيتروجين بيحمل O- لإن طلع على + +359 +00:29:10,350 --> 00:29:21,210 +شكل ميزو ايونيك او inner sol لو جبنا CH2- CH2- + +360 +00:29:21,210 --> 00:29:28,090 +الآن في هذه الحالة لليوكليوفايل كاربون والكاربون + +361 +00:29:28,090 --> 00:29:34,620 +برضه هيهاجم علىالمكان المجاور للـ Oxygen يعمل Ring + +362 +00:29:34,620 --> 00:29:38,280 +Opening و Recyclization على الـ C double bond O + +363 +00:29:38,280 --> 00:29:42,600 +طبعاً لما يكون المهاجم Carbon, Nitro, + +364 +00:29:45,000 --> 00:29:48,720 +Methane و سحبنا منه في الأساس Proton باستعمال + +365 +00:29:48,720 --> 00:29:52,520 +strong base يعني هذا أصلا CH3NO2 باستعمال Sodium + +366 +00:29:52,520 --> 00:29:56,270 +أو Sodium Hydrate خلّينا منه Ionسالب زمان انتوا + +367 +00:29:56,270 --> 00:30:01,090 +بتعودين تعملوا الايون السالب وهاجم لان هذه carbon + +368 +00:30:01,090 --> 00:30:03,810 +بإمكانها تعمل ايش بعد هيك؟ + +369 +00:30:33,070 --> 00:30:38,960 +بنزين رينجطب أول مثل إجت هنا على هذا ال position + +370 +00:30:38,960 --> 00:30:42,980 +نجي نقول لو بده تيجي المثل التاني هتيجي Orthopara + +371 +00:30:42,980 --> 00:30:49,820 +مش هتيجي على ميتا لو بدأ .. لو افترضنا جاب تلاتة + +372 +00:30:49,820 --> 00:30:53,640 +مثل طب هي ال مثل بتودي Orthopara يمكن تصبط معاه بس + +373 +00:30:53,640 --> 00:30:57,240 +كيف بنجيب التلاتة مثل هو في الأساس موجودين ع + +374 +00:30:57,240 --> 00:31:01,500 +بيردين واضح الفكرة؟ ممكن احنا نبدأ في ال nitration + +375 +00:31:02,210 --> 00:31:05,110 +ما هو ال nitration لو بدأتي فيه هيودي على ال meta + +376 +00:31:05,110 --> 00:31:11,830 +position ال nitration هيودي على ال meta position + +377 +00:31:11,830 --> 00:31:16,890 +الآن هل يا تورا .. هل يا تورا بإمكانك لو بدك تبدأي + +378 +00:31:16,890 --> 00:31:23,710 +بهدف البنزين أنك تكوني بادية ب aniline مش هيرجع ال + +379 +00:31:23,710 --> 00:31:29,790 +aniline يعني تفاعل ال reduction أنه ال nitroصير + +380 +00:31:29,790 --> 00:31:34,670 +أنيلين هذا معروف بس عمركوا أخدتوا أن الأنيليل برجع + +381 +00:31:34,670 --> 00:31:37,710 +نايت تروح؟ لأ ممكن الأنيليل مثلا بالديازانيوم + +382 +00:31:37,710 --> 00:31:40,690 +السال تنشيها خالص الأنكشت و بعدين نعمل نايترايشن + +383 +00:31:40,690 --> 00:31:50,290 +بعد ما نعمل الوثلاجة على أي حال مرات + +384 +00:31:50,290 --> 00:31:58,590 +يعني هذا بيفرجيكم إيش عجائب الكيميابالنسبة للألفا + +385 +00:31:58,590 --> 00:32:08,530 +بايرون في عند الحقيقة عدة طرق ممكن نتخيل من هذه + +386 +00:32:08,530 --> 00:32:14,050 +الطرق وجود acid وهذا ال acid على موقع alpha beta + +387 +00:32:14,050 --> 00:32:22,510 +beta keto acids يعني هذا beta keto acid لاعجوا هذا + +388 +00:32:22,510 --> 00:32:28,280 +ال beta keto acid أساساجابوه من مركب تاني في + +389 +00:32:28,280 --> 00:32:32,600 +alcohol يعني كان dye .. dye acid و عملوه مع ال + +390 +00:32:32,600 --> 00:32:38,240 +sulfuric acid كذا المهم صفيه على ال beta keto acid + +391 +00:32:38,240 --> 00:32:43,800 +او beta الديهايد اسدعادة بيتا اكزو أسد هى C double + +392 +00:32:43,800 --> 00:32:48,900 +bond O OH CH2C double bond O الان هذا بدى يتفاعل + +393 +00:32:48,900 --> 00:32:55,620 +مع نفسه واضح هذا لما بدى يتفاعل مع نفسه فى عندى + +394 +00:32:55,620 --> 00:33:04,600 +هنا ال oxygen هادى ممكن يتحل محل ال OH هى صار عندى + +395 +00:33:04,600 --> 00:33:10,130 +OC double bond O طبعا انتوا هنا ممكن تتخيلوا اذا + +396 +00:33:10,130 --> 00:33:15,850 +غلبتكوا هذه انكم تعملوا ايش ال Elon form تعملوا ال + +397 +00:33:15,850 --> 00:33:17,950 +Elon form يعني تعملوا زي هيك + +398 +00:33:23,790 --> 00:33:30,570 +واضح؟ صار عندكم O C double bond O و بعد هيك هذه ال + +399 +00:33:30,570 --> 00:33:35,570 +CH2 لما يرجع عن double bond ال double bond تهاجم + +400 +00:33:35,570 --> 00:33:42,670 +على ال C double bond O هتعملو H ما H في النهاية + +401 +00:33:42,670 --> 00:33:47,570 +elimination لاحظوا ان هذا التفاعل هذا التفاعل بتام + +402 +00:33:47,570 --> 00:33:52,750 +في وجود H بلس في وجود حامض و لذلك احنا اكثر بنفسره + +403 +00:33:52,750 --> 00:33:57,990 +باستعمال ايش ال enon يعني مابنجيش نحط هنا انه + +404 +00:33:57,990 --> 00:34:04,560 +كوّننا negative ion لأ احنا بنحط هنا bubble bondهي + +405 +00:34:04,560 --> 00:34:10,460 +صار اندهيد بهذا الشكل وهنا OH وبالتالي هاي شوفنا + +406 +00:34:10,460 --> 00:34:16,920 +أول تسكير وبعد هيك هذه ال double bond بتسكرها يعني + +407 +00:34:16,920 --> 00:34:22,740 +ما استعملناش ايش ما استعملناش strong base في هذه + +408 +00:34:22,740 --> 00:34:25,880 +الحالة طلعت ده ال alpha + +409 +00:34:34,920 --> 00:34:36,580 +بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون + +410 +00:34:36,580 --> 00:34:39,260 +بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون + +411 +00:34:40,570 --> 00:34:43,810 +مافيش فيه substitution بمعنى هذه عملية + +412 +00:34:43,810 --> 00:34:49,070 +decarboxylation عملية decarboxylation بتحذف مجموعة + +413 +00:34:49,070 --> 00:34:55,110 +ال acid واضح؟ بتحذف مجموعة ال acid من ناحية المبدأ + +414 +00:34:55,110 --> 00:35:02,470 +هذا ال synthesisفي نسبة شبه هذي ال oxygen هتهاجم + +415 +00:35:02,470 --> 00:35:07,050 +هنا الديهيد زي ال alpha beta unsaturated acid هذي + +416 +00:35:07,050 --> 00:35:12,550 +ال oxygen بتهاجم هنا بتطرد ال OH هيصار في عندك ال + +417 +00:35:12,550 --> 00:35:19,170 +O C double bond O و بعد هيك ال double bond بتسكر + +418 +00:35:19,170 --> 00:35:25,950 +هنا فبيطلع عندنا هذا المركب طبعا ال dihydro + +419 +00:35:28,410 --> 00:35:32,290 +Dihydroalphabyron، لاحظوا هنا Dihydroalphabyron، + +420 +00:35:32,290 --> 00:35:38,390 +هاي C double bond O CH واضح؟ كارمون اتنين تلاتة، + +421 +00:35:38,390 --> 00:35:44,730 +هذه لما هاجمت صار عندي single Dihydroalphabyron، + +422 +00:35:44,730 --> 00:35:47,810 +الالت Dihydroalphabyron، شو عمله في الالب + +423 +00:35:47,810 --> 00:35:53,290 +روموساكسينمايد؟ اتراي ايه في الأميل؟ Oxidation + +424 +00:35:53,890 --> 00:35:59,870 +Oxidation يعني بيشيل بيشيل to هيدروجينز هذا المركب + +425 +00:35:59,870 --> 00:36:05,650 +ستة و ستين مرتين يعني بيكون مش واصل له مرة دي + +426 +00:36:05,650 --> 00:36:11,290 +carboxylation مرة بيعمل عندنا oxidation إلى أنه + +427 +00:36:11,290 --> 00:36:16,910 +يصل له في + +428 +00:36:16,910 --> 00:36:23,610 +طرق تانيةنفس الفكرة تقريبا ان بالنسبة هنا بإمكاننا + +429 +00:36:23,610 --> 00:36:28,570 +استعمال ال Easter مش ال acid يعني في المثال السابق + +430 +00:36:28,570 --> 00:36:30,790 +كان عندنا ال acid نعمل substitution على ال acid + +431 +00:36:30,790 --> 00:36:34,670 +أنا بستعمل ال Easter برضه ال E نو ال form ال O بده + +432 +00:36:34,670 --> 00:36:39,650 +تاجم تترد ال O إثل و هذا ال double bond بده تسكر + +433 +00:36:39,650 --> 00:36:46,530 +هنا هيطلق عندنا Alpha Byron المثال اللي بعد اللي + +434 +00:36:46,530 --> 00:36:51,600 +موجود عندنا هذاهذا استعمله في basic medium يعني + +435 +00:36:51,600 --> 00:36:57,640 +نرجع لفكرة ايش ال carbon انايون و حط هنا ال carbon + +436 +00:36:57,640 --> 00:37:00,980 +يعني هذه بإمكاننا نتخيلها carbon ال triple bond + +437 +00:37:00,980 --> 00:37:08,720 +carbon و هنا ال C double bond O O ethane لاحظوا + +438 +00:37:08,720 --> 00:37:14,380 +انه هنا عمل whatever هنا ايش في هنا مجموعة اربان + +439 +00:37:14,380 --> 00:37:21,000 +انه هنا عمل الايون السالبو هذا الايون السالب على + +440 +00:37:21,000 --> 00:37:25,740 +الكربون اللي هنا عمل اي نوع من ال cyclization ال + +441 +00:37:25,740 --> 00:37:30,000 +endocyclization + +442 +00:37:30,000 --> 00:37:33,500 +هذي بتيجي ال double bond هنا على الكربون عشان تصير + +443 +00:37:33,500 --> 00:37:40,300 +CH و بعدين ال oxygen لو سحب ال hydrogen التانية + +444 +00:37:40,300 --> 00:37:44,140 +بيصير عندى هنا ايون سالب الايون السالب اعملوله + +445 +00:37:44,140 --> 00:37:49,420 +resonance على ال A على ال Oواضحة الفكرة؟ يعني في + +446 +00:37:49,420 --> 00:37:55,640 +خطوتها الأولى .. في خطوتها الأولى بهذا الشكل وهي + +447 +00:37:55,640 --> 00:38:01,870 +عندكم هنا صار سي ات مازال عندكم هنا إيش؟مازال + +448 +00:38:01,870 --> 00:38:06,470 +عندكم H مازال عندكم H لما تسحبوها بس بيصير عندكم + +449 +00:38:06,470 --> 00:38:10,650 +further موقع minus الان هذا ال minus مقدر اعمل + +450 +00:38:10,650 --> 00:38:14,430 +resonance double bond بيصير O minus O minus اتسكر + +451 +00:38:14,430 --> 00:38:20,090 +هذا شبيه الكلام بأي synthesis مر عليكم في الأول + +452 +00:38:20,090 --> 00:38:26,940 +بالfeist binary if you run synthesisاللي بتذكر نفس + +453 +00:38:26,940 --> 00:38:32,920 +الفكرة بالفيس بين refuranesynthesis كنا نعمل ال .. + +454 +00:38:32,920 --> 00:38:38,180 +إيه نقول؟ نيون اللي على ال oxygen و يسكل يعمل + +455 +00:38:38,180 --> 00:38:42,180 +refuran و ممكن لما نعود نذكر بالrefuran يمروا + +456 +00:38:42,180 --> 00:38:46,260 +علينا واضح؟ + +457 +00:38:50,790 --> 00:38:59,850 +هذا أيضًا synthesis إضافي بيعتمد على ال CH2 و ال C + +458 +00:38:59,850 --> 00:39:04,350 +double bond O مثل بيستعمل very strong base بيستعمل + +459 +00:39:04,350 --> 00:39:07,570 +very strong base لأن ال very strong base هتعمل + +460 +00:39:07,570 --> 00:39:12,430 +carb أنيون هنا و بتقدر تعمل كمان carb أنيون على + +461 +00:39:12,430 --> 00:39:17,340 +المثلهدول ال two carb anions اللي جابهم بالامدس + +462 +00:39:17,340 --> 00:39:24,120 +غالبا صود امد لما يفعلوا مع ال CO2 الطرف منهم هذا + +463 +00:39:24,120 --> 00:39:33,560 +CH2 هياخد CO2 بيعمل C double bond O O minus في + +464 +00:39:33,560 --> 00:39:38,640 +وجود الحمض بيخليها O H يعني هنا عملنا two ions + +465 +00:39:38,640 --> 00:39:42,640 +فعلنا هذا مع ال C double bond O هي C double bond O + +466 +00:39:43,190 --> 00:39:48,470 +الـ carbon بتاعتها موجبة فهذا الايون هاجمها وصار + +467 +00:39:48,470 --> 00:39:58,310 +عنده CWO O minus الـ O minus صارت OH فصار عندى هذا + +468 +00:39:58,310 --> 00:40:06,550 +ال acid الان هذا لو رتبنا ال oxygen اللى هنا بتسكر + +469 +00:40:06,550 --> 00:40:10,570 +هذا اي بيرون Alpha ولا Gamma اللى بيحضروا الآن + +470 +00:40:12,410 --> 00:40:21,610 +مازال الفا بيرون بيحمل + +471 +00:40:21,610 --> 00:40:25,590 +على هذا الموقع OH طبعا بتكون C double bond O بتعمل + +472 +00:40:25,590 --> 00:40:31,110 +ولا توتو ميريزي بتصير ايش؟ OH فهذا ال oxygen في + +473 +00:40:31,110 --> 00:40:36,130 +النهايةاللي هنا هتسكر على ال c double bond o يعني + +474 +00:40:36,130 --> 00:40:40,590 +اللي بده يلزم ان انتوا تعملوا c double bond o o h + +475 +00:40:40,590 --> 00:40:46,790 +و تمشوا بهذا الشكل ch2 c double bond o ch2 c + +476 +00:40:46,790 --> 00:40:52,690 +double bond o r هاي المركب بهذا الشكل الان لو + +477 +00:40:52,690 --> 00:40:58,230 +عملتوله in on form لو عملتوله in on form شو هيصفة + +478 +00:40:58,230 --> 00:41:04,680 +عندكمعملوا cyclization وهذا هو C-double bond وهذا + +479 +00:41:04,680 --> 00:41:09,560 +هو E-null form هنا بيصير double bond OH واضح + +480 +00:41:09,560 --> 00:41:17,160 +الفكرة تقريبا يمكن هذا الكلام انا مواضحه هنا هاي + +481 +00:41:17,160 --> 00:41:20,260 +المركب الأصلي هذا اللي طلع عندنا كيف عمل + +482 +00:41:20,260 --> 00:41:26,130 +cyclization هاي هذا ال ketone عملالـ E0 الـ OH هذه + +483 +00:41:26,130 --> 00:41:31,090 +هاجمت سكرت هنا طردت substitution OH و طبعا هنا + +484 +00:41:31,090 --> 00:41:35,610 +عاملين already E0 تاني واضح + +485 +00:41:39,300 --> 00:41:44,980 +الان لو اجينا ل ال alpha byrons و قولنا ايش اهم + +486 +00:41:44,980 --> 00:41:49,460 +تفاعلاتهم اهم تفاعلات ال alpha byrons بالمجمل ان + +487 +00:41:49,460 --> 00:41:56,400 +they are masked Dayens طبعا ايش اللي موجود فيهم و + +488 +00:41:56,400 --> 00:42:02,290 +بده ينحذفالـ CO2 و بناء على ذلك لما انتم تشتغلوا + +489 +00:42:02,290 --> 00:42:07,770 +deals under reaction عليهم و نحط الناتج النهائي + +490 +00:42:07,770 --> 00:42:12,630 +لاحظوا هي هنا تفاعل مع ال triple bond عادة ال + +491 +00:42:12,630 --> 00:42:17,410 +deals under reaction بطلع في الحلقة السادسية كم + +492 +00:42:17,410 --> 00:42:21,370 +buy bond؟ واحدة لما تكون هذا triple bond صاروا + +493 +00:42:21,370 --> 00:42:27,360 +تلتين لما يفقد ال CO2 صاروا تلاتةطلع عندى مشتقة + +494 +00:42:27,360 --> 00:42:32,320 +بنزين واضح فانتوا لو بدكم تعملوا التفاعل في + +495 +00:42:32,320 --> 00:42:35,940 +النهاية هو deals ألدر بهذا الشكل الناتج الأولى + +496 +00:42:35,940 --> 00:42:43,250 +نعمله بشكل واضحيعني الناتج الأولي بيصير C Double + +497 +00:42:43,250 --> 00:42:50,110 +bond C هو انا واطفر واطفر وشبك من هذا الموقع ومن + +498 +00:42:50,110 --> 00:42:53,030 +هذا الموقع هي الحلقة السوداسية تبع ال deals ألدر + +499 +00:42:53,030 --> 00:42:57,710 +واحد اتنين تلاتة أربعة خمسة ستة طبعا هادولة ال + +500 +00:42:57,710 --> 00:43:03,050 +turbines هيروح هيصير وين واضح + +501 +00:43:03,050 --> 00:43:08,690 +الفكرة الآن لما بنكسر ال CO2 هاي حركة و الحركة + +502 +00:43:08,690 --> 00:43:14,850 +التانيةبصير عنده الاروماتيكو مارس يعني نارفنا من + +503 +00:43:14,850 --> 00:43:18,910 +وين اجوا التلاتة bonds واحدة من ال deals ألتر + +504 +00:43:18,910 --> 00:43:23,850 +واحدة لأنه انا استعملت ال treble bond و واحدة من + +505 +00:43:23,850 --> 00:43:31,850 +كاسر ال CO2 و بإمكانكم تنفذوا القمر بهدوء الآن في + +506 +00:43:31,850 --> 00:43:35,510 +هذا المركب لو إيجي يضيفوا على هذا ال double bond + +507 +00:43:36,910 --> 00:43:40,530 +الاصل ان ال deals ألذر نفسه لما بدو يتم على هذا + +508 +00:43:40,530 --> 00:43:44,730 +الموقع او هذا الموقع هيعطيني double bond واحدة + +509 +00:43:44,730 --> 00:43:50,850 +الان فقد ال CO2 بدو يعطيني double bond تانية فقد + +510 +00:43:50,850 --> 00:43:58,330 +ال بيرول ماقدش من هنا بيروليدين طبعا هذا مش ثقت + +511 +00:43:58,330 --> 00:44:01,270 +بيرول تترا هيدرو بيرول اللي هو ال بيروليدين + +512 +00:44:01,270 --> 00:44:07,080 +بيروليدينمع ال H بيفقد على شكل بيروليديل حيصير + +513 +00:44:07,080 --> 00:44:12,760 +عندى تلاتة double bullets جيد ان هاد الأمور يعني + +514 +00:44:12,760 --> 00:44:20,120 +تنسب في كل الأحوال لكم تبدأوا انتوا يعني تتسلوا + +515 +00:44:20,120 --> 00:44:27,360 +عليها بجلب ارصاص هيقالت هو يا حاملة ال + +516 +00:44:27,360 --> 00:44:28,000 +by role + +517 +00:44:33,320 --> 00:44:43,360 +بهذا الشكل وهي عندي هنا H بيرون خماسي فلاحظوا + +518 +00:44:43,360 --> 00:44:52,340 +فقد هذا ال CO2 ايش هيعمللكم رابطة فقد هذه مع H + +519 +00:44:52,340 --> 00:45:00,070 +مجاورة رابطة و ال deals ألبقفقط بلزم انه بدو + +520 +00:45:00,070 --> 00:45:06,070 +تعملوا هيك امثلة بالجلم لارصاص هتحسوا انه مش هتكون + +521 +00:45:06,070 --> 00:45:09,630 +ايش صعبة يعني واضح انه تلت روابط من وين اجوا + +522 +00:45:09,630 --> 00:45:14,770 +فهمناهم واحدة من ال deals قلتها التانية من حدث ال + +523 +00:45:14,770 --> 00:45:20,590 +CO2 التالتة من حدث البروليدين البروليدين هذه مع H + +524 +00:45:20,590 --> 00:45:29,560 +مجاورة هذا المثال زي ما بنلاحظ ايضالاحظوا هى عندى + +525 +00:45:29,560 --> 00:45:34,380 +هذه حدف الـCO2 هدى ضب ال bond عادية و تنتل اذا لدي + +526 +00:45:34,380 --> 00:45:38,980 +ال deals elder هيعطيني كام bond واحدة حدف ال CO2 + +527 +00:45:38,980 --> 00:45:45,680 +التانى الآن هذا المثال بعد ما اتفعل زى هيك صار + +528 +00:45:45,680 --> 00:45:50,940 +عندى ضيينة جديدة اتفعل مرة تانية مع نفس ال + +529 +00:45:53,660 --> 00:46:00,220 +مش هذا عفوا مش افتلامد لأ + +530 +00:46:00,220 --> 00:46:07,220 +لأ من المليك acid مليك anhydride ملامد من المليك + +531 +00:46:07,220 --> 00:46:12,400 +هذا لما بيكون بهذا الشكل شو بنسمي احنا ابدأوا معاه + +532 +00:46:12,400 --> 00:46:21,690 +متدرجا سيضة بال point O OH OHمليك أسد، مليك أسد، + +533 +00:46:21,690 --> 00:46:26,710 +مليك أسد، + +534 +00:46:26,710 --> 00:46:32,730 +مليك أسد، مليك أسد، مليك أسد، مليك أسد، مليك أسد، + +535 +00:46:32,730 --> 00:46:37,810 +مليك أسد، مليك أسد، مليك أسد، مليك أسد، مليك أسد، + +536 +00:46:37,810 --> 00:46:39,170 +مليك أسد، مليك أسد، مليك أسد، مليك أسد، مليك أسد، + +537 +00:46:39,170 --> 00:46:39,450 +مليك أسد، مليك أسد، مليك أسد، مليك أسد، مليك أسد، + +538 +00:46:39,450 --> 00:46:47,910 +مليك أسد، مليك أسد، مليك أسد، مليك أسد،لكن مافيش + +539 +00:46:47,910 --> 00:46:54,390 +فيه double bond سكسينامي و لما يكون حامل بروم انا + +540 +00:46:54,390 --> 00:47:01,450 +بروم و سكسينامي يعني لما يكون مافيش double bond و + +541 +00:47:01,450 --> 00:47:09,470 +تحط هنا بروم ايش بيصير المركبان إبراهيمو + +542 +00:47:09,470 --> 00:47:15,610 +ساكسينيكاسيد لكن لما يكون فيه ال double bond بيكون + +543 +00:47:15,610 --> 00:47:19,690 +جاي مش من ال ساكسينيك من الماليك اللي هو ال sis + +544 +00:47:19,690 --> 00:47:26,350 +acid لترايز شو بنسميه؟ لأ المالك اسد حامض مختلف + +545 +00:47:26,350 --> 00:47:27,110 +تماما + +546 +00:47:30,350 --> 00:47:34,590 +في Maleic اللي في حرف ال E هو اللي توي رأسها منها + +547 +00:47:34,590 --> 00:47:39,630 +Maleic Acid الماليك أسل حمض مختلف تماما ال Trans + +548 +00:47:39,630 --> 00:47:44,330 +من الماليك واحد منهم بيجي من التفاح والتاني من + +549 +00:47:44,330 --> 00:47:52,910 +الغنم Maleic و Pneumaticمليك أسد و فيوماريك أسد + +550 +00:47:52,910 --> 00:47:58,650 +both are both are dye acids مليك أسد و فيوماريك + +551 +00:47:58,650 --> 00:48:02,290 +أسد السس هو المليك هو اللي بيعمل الانهيدريد + +552 +00:48:02,290 --> 00:48:08,110 +الفيوماريك بيعملش سايكليك انهيدريد طبعا هذا هيرود + +553 +00:48:08,110 --> 00:48:11,250 +يعمل ديلز ألدر reaction تاني لو بدكوا تجربوا + +554 +00:48:11,250 --> 00:48:15,970 +ترسموهحلقة سداسية تانية بهذا الشكل يمكن المنظر هيك + +555 +00:48:15,970 --> 00:48:20,270 +يبين غريب لكن هي في النهاية another deals another + +556 +00:48:20,270 --> 00:48:24,950 +reaction هى الضايين وهنا بتكون جيبه هذا ال double + +557 +00:48:24,950 --> 00:48:31,850 +bond يعني كأنه هذا هو ناتج هان و هان و هذا ال + +558 +00:48:31,850 --> 00:48:38,890 +double bond بتسير في النص واضحة الفكرةفما تستغربوش + +559 +00:48:38,890 --> 00:48:44,990 +هذا الناتج لو مرة تانية بدي أوضحلكوا يا c double + +560 +00:48:44,990 --> 00:48:53,090 +bond o c double bond o and final ولاحظوا هذه + +561 +00:48:53,090 --> 00:48:56,250 +الحلقة السوداسية اللي من هدول الطرف اللي بدي اتعمل + +562 +00:48:56,250 --> 00:49:01,730 +ضيق الان لو كنا حاطين بهذا الشكل + +563 +00:49:05,750 --> 00:49:14,970 +CW Bond O CW Bond O N Female واضح؟ الآن هذه وين + +564 +00:49:14,970 --> 00:49:21,650 +بدها تيجي تعمل الروابط تبعونها هي الضيين بناء على + +565 +00:49:21,650 --> 00:49:28,190 +ذلك بدنا نعمل رابطة ه و رابطة + +566 +00:49:33,980 --> 00:49:39,400 +هذه الحلقة السودسية واحد اتنين تلاتة اربعة خمسة + +567 +00:49:39,400 --> 00:49:44,940 +ستة طبعا لما بدوا يصير حركة الروابط واحد اتنين وين + +568 +00:49:44,940 --> 00:49:50,200 +هتيجي ال double bond؟ في وسط اللي كان ضيين الآن + +569 +00:49:50,200 --> 00:49:55,600 +هادي عشان مايتغلبش يرسمها زي هيك رسمها واحد double + +570 +00:49:55,600 --> 00:50:01,120 +bond اتنين طلعوا سجل doublesingle بس هو رسمهم + +571 +00:50:01,120 --> 00:50:07,200 +single double single يعني هذا المركب هو نفسه هذا + +572 +00:50:07,200 --> 00:50:13,380 +واضح؟ مجرد طريقة الرسم هو عبارة عن deals elder + +573 +00:50:13,380 --> 00:50:19,040 +reaction deals elder reaction على مرتين هو عبارة + +574 +00:50:19,040 --> 00:50:25,940 +عن deals elder reaction على مرتين وهذا المركب هو + +575 +00:50:25,940 --> 00:50:28,680 +نفسه هذا فقط الإختلاف وين؟ + +576 +00:50:39,950 --> 00:50:46,630 +الان لو جينا لل gamma byrons نشوف تحضيرهم ممكن + +577 +00:50:46,630 --> 00:50:56,860 +نحضرهم من ال acetone مع ال diethyl oxalateلحظوا + +578 +00:50:56,860 --> 00:51:01,780 +هذا الحامض اللي فيه CWO CWO جبعت oxalic acid لو + +579 +00:51:01,780 --> 00:51:06,540 +عملنا له ال Easter ضايقث ال oxalate أو ال oxalic + +580 +00:51:06,540 --> 00:51:10,820 +acid Easter لو أتينا فعلنا مع ال acetone في وجود + +581 +00:51:10,820 --> 00:51:14,760 +base في وجود base لحظوا ال base إيش هتعمل على ال + +582 +00:51:14,760 --> 00:51:20,500 +methyls اللي هنا in a principlenegative و هنسكر + +583 +00:51:20,500 --> 00:51:25,800 +بهذا الشكل و هنسكر بهذا الشكل يعني نطرد ال O إثل و + +584 +00:51:25,800 --> 00:51:31,640 +ال O إثل هذه صارت CH2CWbO CH2CWbO في وجود acid + +585 +00:51:31,640 --> 00:51:37,780 +نعمل من واحد منهم ال enol OH و نخليها تسكر هنا + +586 +00:51:37,780 --> 00:51:47,670 +واضح؟ نخليها تسكر هنا هتعمل ال O و بعد هيكيتكون + +587 +00:51:47,670 --> 00:51:53,830 +عندى ال gamma-byron واضح بعد ما اتكون ال gamma + +588 +00:51:53,830 --> 00:51:59,490 +-byron كمان عملله in principle decarboxylation + +589 +00:51:59,490 --> 00:52:04,130 +عملله decarboxylation عساس نحصل على المركب هذا + +590 +00:52:04,130 --> 00:52:09,630 +اللى عادة إيش بنسميه ال parent gamma-byron إيش + +591 +00:52:09,630 --> 00:52:14,080 +يعني parentيعني مافيش عليه ولا إبدال يعني هذا ال + +592 +00:52:14,080 --> 00:52:20,960 +parent gamma byron حصل عليه من ال acetone مع ال + +593 +00:52:20,960 --> 00:52:25,260 +oxalic acid ester اللي هو ال dye ester تبع ال + +594 +00:52:25,260 --> 00:52:31,060 +oxalic acid بالطريقة اللي أنتوا شايفينهاالتفاعل + +595 +00:52:31,060 --> 00:52:35,260 +التالي لتحضير الـ Gamma Byron اللي هو الـ Glysin + +596 +00:52:35,260 --> 00:52:41,880 +Condensation of Ethyl Propionate with Acetone طبعا + +597 +00:52:41,880 --> 00:52:45,180 +هنا لما بدى استعمل الـ Ethyl ONA يعني Sodium + +598 +00:52:45,180 --> 00:52:49,540 +Ethoxide معنا ذلك انه انا في خطوة الاولى بدأ اعمل + +599 +00:52:49,540 --> 00:52:56,150 +ايون سالب بدأ اعملهذا الإبدال صار أن هذا موجود + +600 +00:52:56,150 --> 00:53:00,170 +الآن في وجود sulfuric acid خلينا نتخيل أنه عندنا + +601 +00:53:00,170 --> 00:53:05,150 +enol double bond OH تسكر على ال triple bond + +602 +00:53:05,150 --> 00:53:14,170 +endocyclization يعني هذه هي هيك OH صارت + +603 +00:53:14,170 --> 00:53:20,750 +endocyclization على ال triple bond endocyclization + +604 +00:53:20,750 --> 00:53:27,470 +علىTriple bond هذا في كل الأحوال لسه من اكلايزن + +605 +00:53:27,470 --> 00:53:34,050 +لأنه ايون سالب على الهيستر يعني الكلايزن ايون سالب + +606 +00:53:34,050 --> 00:53:40,250 +على الهيستر الالدون الالدون و عيلته ايون سالب على + +607 +00:53:40,250 --> 00:53:45,750 +الكيتون او الالدهيد الالدون is a addition reaction + +608 +00:53:45,750 --> 00:53:52,270 +والكلايزن is substitution reactionتقريبا يعني هذه + +609 +00:53:52,270 --> 00:53:58,350 +فكرة عامة عن ال alpha byrons و ال gamma byrons في + +610 +00:53:58,350 --> 00:54:04,290 +لقاء تاني بنكمل في موضوع الحلقات التانية ال by + +611 +00:54:04,290 --> 00:54:08,090 +role و الفيوران و الثيوفين + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/XhLJ7pC0Mjs.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/XhLJ7pC0Mjs.srt new file mode 100644 index 0000000000000000000000000000000000000000..8c3e57474aa73462a3528351fc33c00c95a7d16a --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/XhLJ7pC0Mjs.srt @@ -0,0 +1,2311 @@ +1 +00:00:20,670 --> 00:00:25,450 +بسم الله الرحمن الرحيم بنبدأ الآن بالفصل الثاني في + +2 +00:00:25,450 --> 00:00:29,630 +مادة الـ heterocyclic chemistry طبعا في هذا الفصل + +3 +00:00:29,630 --> 00:00:35,000 +بدنا ناخد تحضير الـ heterocyclic rings يمكن سابقا + +4 +00:00:35,000 --> 00:00:39,740 +حكينالكوا أن الناس يعني مناهج في هذا الموضوع بعض + +5 +00:00:39,740 --> 00:00:43,180 +الناس بيفضلوا أنهم ييجوا على الحلقات المعروفة و + +6 +00:00:43,180 --> 00:00:46,980 +يصيروا يتكلموا عنها حلقة حلقة يعني ييجوا يقولوا + +7 +00:00:46,980 --> 00:00:50,540 +chemistry of Pyrrole و يشرحوا كيف بنحضر الـ Pyrrole + +8 +00:00:50,540 --> 00:00:54,740 +وتفاعلاته chemistry of furan chemistry of Pyridine + +9 +00:00:54,740 --> 00:01:00,820 +وهكذا في توجه ثاني للتعامل مع الموضوع أننا نقول + +10 +00:01:00,820 --> 00:01:05,800 +كيف الطرق العامة لتحضير الـ heterocyclic rings in + +11 +00:01:05,800 --> 00:01:10,600 +general يعني أخذ طريقة هذه الطريقة ممكن من خلالها + +12 +00:01:10,600 --> 00:01:14,840 +أن أحضر حلقة ثلاثية أو ربعية أو خمسية أو سداسية + +13 +00:01:14,840 --> 00:01:20,060 +الحلقة ممكن تكون فيوران بيرول ثيوفين وهذا التوجه + +14 +00:01:20,060 --> 00:01:23,900 +اللي احنا هنمشي فيه يعني هناخد general methods for + +15 +00:01:23,900 --> 00:01:27,400 +preparation of heterocyclic compounds هذا هيكون + +16 +00:01:27,400 --> 00:01:31,980 +يعني ياخذ مننا جزء كبير من هذا المساق الـ general + +17 +00:01:31,980 --> 00:01:35,920 +methods for heterocyclic synthesis وبعد هيك ممكن + +18 +00:01:35,920 --> 00:01:40,800 +نتطرق لبعض الأمثلة المحددة ونتأكد من مجمل الطرق + +19 +00:01:40,800 --> 00:01:43,840 +اللي بتحضر في هذه المركبات المشهورة + +20 +00:01:46,050 --> 00:01:52,290 +كمقدمة عامة لما أنا بدي أحكي عن تحضير حلقة سواء + +21 +00:01:52,290 --> 00:01:57,530 +كنت بأحكي عن تحضير حلقة كربون أو حتى عن تحضير + +22 +00:01:57,530 --> 00:02:01,650 +heterocycle ring ممكن أتخيل أن أنا ممكن أعمل + +23 +00:02:01,650 --> 00:02:08,070 +التحضير بعدة طرق الطريقة الأولى بنسميها cyclization + +24 +00:02:08,070 --> 00:02:12,730 +reaction اللي بنقصده بـ cyclization reaction أنه + +25 +00:02:12,730 --> 00:02:17,990 +أنا في خطوة الإغلاق بيكون عندي طرفين فقط لازمني + +26 +00:02:17,990 --> 00:02:21,370 +أسكر رابطة بتصير حلقة لاحظوا بهذا الشكل هاي + +27 +00:02:21,370 --> 00:02:26,250 +الطرفين سكرت الرابطة الأخيرة صارت حلقة هذا التفاعل + +28 +00:02:26,250 --> 00:02:29,670 +بسميه cyclization reaction يعني ممكن أتخيل أن هنا + +29 +00:02:29,670 --> 00:02:33,030 +في عندي ذرات في عندي مثلا nucleophile و + +30 +00:02:33,030 --> 00:02:36,050 +electrophile أو free radical و free radical بدي + +31 +00:02:36,050 --> 00:02:38,530 +هذا الـ nucleophile يسكر عن الـ electrophile عم + +32 +00:02:38,530 --> 00:02:43,680 +الرابطة صارت حلقة هذا إيش بنقول عنه؟ cyclization + +33 +00:02:43,680 --> 00:02:47,520 +reaction وهتلاحظوا أن الـ cyclization reaction هو + +34 +00:02:47,520 --> 00:02:51,760 +one bond formation reaction يعني في لحظة الإغلاق + +35 +00:02:51,760 --> 00:02:56,860 +أنا بعمل رابطة الآن هذا ما يمنعش أن أنا حتى أصل + +36 +00:02:56,860 --> 00:03:00,740 +لهذه الذرات كلها مرتبة أن أكون أعمل التفاعلين + +37 +00:03:00,740 --> 00:03:04,120 +ثلاثة من الكيمياء العادية لحد ما شبكت هدول لكن أنا + +38 +00:03:04,120 --> 00:03:09,120 +بتكلم عن لحظة إغلاق الحلقة بهذا الشكل كم رابطة + +39 +00:03:09,120 --> 00:03:13,900 +بعمل؟ رابطة واحدة صار في عندي حلقة هذا الـ + +40 +00:03:13,900 --> 00:03:20,340 +cyclization reaction النوع الثاني Cycloaddition + +41 +00:03:20,340 --> 00:03:26,100 +reaction أنه أنا بجيب قطعتين بجرب هدول القطعتين + +42 +00:03:26,100 --> 00:03:30,500 +على بعض وفي لحظة الإغلاق بعمل رابطتين مش رابطة + +43 +00:03:30,500 --> 00:03:36,440 +واحدة هاي قطعتين بجربهم في لحظة الإغلاق كم رابطة + +44 +00:03:36,440 --> 00:03:41,640 +بعمل؟ رابطتين هذا اللي أنا بسميه Cycloaddition + +45 +00:03:41,640 --> 00:03:44,960 +reaction cycloaddition reaction يعني لحظة هي قطعة + +46 +00:03:44,960 --> 00:03:49,580 +وهي قطعة ربما مثلا هذه ذرتين ربما هذه ثلاثة أو + +47 +00:03:49,580 --> 00:03:54,620 +أربعة بجربهم مع بعض في لحظة الإغلاق كم رابطة بعمل + +48 +00:03:54,620 --> 00:03:58,840 +رابطتين هذا بسميه Cycloaddition reaction ومنه + +49 +00:03:58,840 --> 00:04:02,780 +أنواع كثيرة منه أنواع كثيرة يعني وبحاجة إلى تفصيل + +50 +00:04:02,780 --> 00:04:09,350 +كبير الشغلة الثالثة بنسميها ring transformation + +51 +00:04:09,350 --> 00:04:14,330 +reaction يعني أنه بيكون في عندي حلقة هذه الحلقة + +52 +00:04:14,330 --> 00:04:21,150 +بخليها تفتح وتسكر بشكل جديد هذه الحلقة بتعمل ring + +53 +00:04:21,150 --> 00:04:25,310 +opening وبعدين ring closure يعني في الـ ring + +54 +00:04:25,310 --> 00:04:30,630 +transformation في عندي حلقة هالحلقة هذه لازم تفتح + +55 +00:04:30,630 --> 00:04:33,730 +وتسكر بوضع جديد يعني لو أنا بدي أفرجيكوا ياها + +56 +00:04:33,730 --> 00:04:39,650 +بمثال لو افترضت أن كل هذا جزء هي عندي حلقة واضح؟ و + +57 +00:04:39,650 --> 00:04:42,630 +خليني أفترض هنا في عندي substituent الآن هذه + +58 +00:04:42,630 --> 00:04:47,980 +الحلقة فتحت سكرت من هنا صار عندي حلقة جديدة ولا لأ + +59 +00:04:47,980 --> 00:04:51,860 +صار عندي بالتأكيد حلقة جديدة الآن في الـ ring + +60 +00:04:51,860 --> 00:04:56,120 +transformation الحلقة لما بتفتح وبتسكر على حلقة + +61 +00:04:56,120 --> 00:05:00,120 +جديدة ممكن من ناحية المبدأ أن حلقة خمسية تفتح و + +62 +00:05:00,120 --> 00:05:04,160 +تسكر على حلقة خمسية يعني يظل عندي نفس حجم الحلقة + +63 +00:05:04,860 --> 00:05:09,400 +ممكن يصير عندي شيء بسميه ring contraction يعني + +64 +00:05:09,400 --> 00:05:14,340 +الحلقة الخمسية تصير مثلا ربعية أو ثلاثية الحلقة + +65 +00:05:14,340 --> 00:05:20,400 +الخمسية لو كبرت بيصير اسمه ring enlargement أو + +66 +00:05:20,400 --> 00:05:27,140 +ring expansion الخمسية تصير سداسية أو سباعية الآن + +67 +00:05:27,140 --> 00:05:32,280 +في أمثلة كثيرة وحنحاول نستعرض بعض الأمثلة على ring + +68 +00:05:32,280 --> 00:05:35,700 +transformation على نفس الحلقة أو لحلقة أصغر أو + +69 +00:05:35,700 --> 00:05:41,160 +لحلقة أكبر لكن لاحظوا معي أن غالبا الـ ring + +70 +00:05:41,160 --> 00:05:46,770 +transformations هدول ما بيكونوش شيء منهجي يعني + +71 +00:05:46,770 --> 00:05:52,550 +الإنسان بيدرسه لغرض تحضير حلقة معينة هم في الغالب + +72 +00:05:52,550 --> 00:05:56,390 +بيصيروا مع الباحثين بالمصادفة يعني بيكونوا بيعملوا + +73 +00:05:56,390 --> 00:06:01,450 +تفاعل معين بتفاجأة أنه الحلقة فتحت وبتسكر بشكل + +74 +00:06:01,450 --> 00:06:07,070 +جديد ولذلك مرات كثيرة بنلاقيهم موجودين حتى تحت اسم + +75 +00:06:07,070 --> 00:06:12,860 +rearrangement أن الجزء فتح وأقعد يرتب نفسه بشكل + +76 +00:06:12,860 --> 00:06:18,920 +جديد وغالبا هدول بيصيروا مع الباحثين بشكل مفاجئ + +77 +00:06:18,920 --> 00:06:23,320 +يعني هو ما بيكونش شغال وفكروا أن الحلقة هذه + +78 +00:06:23,320 --> 00:06:26,580 +الخمسية بدأ تفتح منها وبتسكر جديد هو بيعمل تفاعل + +79 +00:06:26,580 --> 00:06:31,020 +على طرف ما ربما من الحلقة بتفاجأة أن الحلقة فتحت و + +80 +00:06:31,020 --> 00:06:34,860 +بتتسكر بشكل جديد سواء كحلقة أكبر أو بساوي في الحجم + +81 +00:06:34,860 --> 00:06:40,290 +أو أصغر وإن شاء الله أنه هستعرض لكم يعني بعض + +82 +00:06:40,290 --> 00:06:45,250 +الأمثلة في هذا الموضوع حتى تحسوا في هذا الأمر يعني + +83 +00:06:45,250 --> 00:06:50,210 +إذا واجهكم في المستقبل وبالتأكيد ممكن توجدها أن + +84 +00:06:50,210 --> 00:06:52,810 +نعطيكوا homework أن نقول كل واحدة تنزل على + +85 +00:06:52,810 --> 00:06:56,710 +المجلات مجرد ما تكتب ring transformation عن البني + +86 +00:06:56,710 --> 00:07:01,430 +آدم اللي بيصير معه شغل زيك في البحث هتلاحظوا أن + +87 +00:07:01,430 --> 00:07:05,550 +عنوان العنوان تبعه Ring Transformation of + +88 +00:07:05,550 --> 00:07:06,990 +Heterocyclic Compounds + +89 +00:07:12,720 --> 00:07:16,700 +فلو كتبتوا في أي search كلمة ring transformation + +90 +00:07:16,700 --> 00:07:21,820 +هيظهر عندكم آلاف المقالات اللي ممكن توضحلكوا هذا + +91 +00:07:21,820 --> 00:07:25,440 +الكلام احنا إن شاء الله لما نمشي بهذا الترتيب نشرح + +92 +00:07:25,440 --> 00:07:27,960 +الـ cyclization reactions بعدين الـ cycle addition + +93 +00:07:27,960 --> 00:07:31,740 +reactions بعدين ring transformations بنستعرض بعض + +94 +00:07:31,740 --> 00:07:37,080 +الأمثلة وواجهتها بنطلب منكم أنكم تجيبولنا أنتو من + +95 +00:07:37,080 --> 00:07:40,740 +خلال اجتهادكم وإنزالكم على المجلات أيضا أمثلة + +96 +00:07:40,740 --> 00:07:45,580 +إضافية في موضوع الـ Ring Transformation نقطة + +97 +00:07:45,580 --> 00:07:50,000 +البداية عندنا هتكون إيش؟ Cyclization Reactions + +98 +00:07:50,000 --> 00:07:56,280 +تفاعلات الإغلاق الحلقي الآن في عندنا عالم اسمه + +99 +00:07:56,280 --> 00:08:01,820 +Baldwin حط عدة قواعد لعملية الإغلاق يعني كيف نصنف + +100 +00:08:01,820 --> 00:08:05,580 +عملية الإغلاق ومش زمان هذا الكلام يعني تقريبا في + +101 +00:08:05,580 --> 00:08:11,340 +الـ 76 وصارت هذه مشهورة قواعد الإغلاق Baldwin's + +102 +00:08:11,340 --> 00:08:15,090 +Rule أو rules ومرات لما بيكون فيه احتمالين والله + +103 +00:08:15,090 --> 00:08:18,470 +ممكن يسكر بهذا الشكل أو بهذا الشكل الناس اللي + +104 +00:08:18,470 --> 00:08:21,970 +بيدرسوا الموضوع بتاع معون كبير بيقولوا والله هذا + +105 +00:08:21,970 --> 00:08:25,450 +الإغلاق أفضل من هذا الإغلاق يعني تخيلوا هاي عندي + +106 +00:08:25,450 --> 00:08:28,090 +زي هيك مثلا هل الإغلاق بهذا الشكل ولا بهذا الشكل + +107 +00:08:28,090 --> 00:08:32,030 +ولا بهذا الشكل في عندي أكثر من إيش cyclization أو + +108 +00:08:32,030 --> 00:08:36,010 +possible cyclization فـ Baldwin rules قواعد بالدوين + +109 +00:08:36,010 --> 00:08:40,390 +بتوضح له كيف ممكن يكون هذا الإغلاق وإيش بنسمي + +110 +00:08:40,390 --> 00:08:45,860 +عملية الإغلاق الآن بالدوين لما تكلم عن عملية الـ + +111 +00:08:45,860 --> 00:08:50,640 +cyclization جال في عنده طرفين طرف بده يسكر على + +112 +00:08:50,640 --> 00:08:55,220 +الطرف الثاني واضح طرف بده يسكر على الطرف الثاني + +113 +00:08:55,220 --> 00:09:00,540 +الآن ممكن نفترض الحالة الأولى أن هذا الطرف مثلا + +114 +00:09:00,540 --> 00:09:05,200 +نيوكليوفيل بده يسكر على الطرف اللي هنا نفترض هذا + +115 +00:09:05,200 --> 00:09:11,950 +CCL كنا تعلمنا أن النيوكليوفيل بيهاجم على الكربون + +116 +00:09:11,950 --> 00:09:18,330 +وبيطرد الـ CL إذا هنا substitution reaction واضح طيب + +117 +00:09:18,330 --> 00:09:23,870 +لما بالدوين بيسمي هذا الكلام كيف بيسميه أول شيء + +118 +00:09:23,870 --> 00:09:28,470 +بيكتب هنا رقم هو رقم الحلقة المتكونة طبعا هنا احنا + +119 +00:09:28,470 --> 00:09:31,490 +مش محددينها يعني لو افترضنا أن الحلقة اللي تكونت + +120 +00:09:31,490 --> 00:09:37,920 +خماسية شو بده يكتب؟ الآن بعد هيك بيجي بيتطلع على + +121 +00:09:37,920 --> 00:09:42,520 +الذرة اللي تم عليها الهجوم هذه الرابطة هل تحركت + +122 +00:09:42,520 --> 00:09:48,280 +للخارج حتى لو انكسرت ولا تحركت للداخل هنا تحركت + +123 +00:09:48,280 --> 00:09:54,190 +للخارج طلعت برا فبيكتب EXO بعدين بيجي بيسأل هذه + +124 +00:09:54,190 --> 00:09:58,150 +الذرع اللي تم عليها الإغلاق الـ geometry حواليها + +125 +00:09:58,150 --> 00:10:02,430 +tetragonal يعني ربعية تتراهيدرال ولا triangular + +126 +00:10:02,430 --> 00:10:06,070 +ثلاثية لترياجونال اللي فيهم الـ double bonds ولا + +127 +00:10:06,070 --> 00:10:11,120 +diagonal اللي فيهم الـ triple bonds اللي لينيار إذا + +128 +00:10:11,120 --> 00:10:16,720 +الهجوم يمكن أن يكون على carbon رباعية يعني بأربع + +129 +00:10:16,720 --> 00:10:20,020 +روابط وحدية أو في عند double bond وبالتالي الـ + +130 +00:10:20,020 --> 00:10:25,100 +geometry بتكون triangular أو على carbon فيها + +131 +00:10:25,100 --> 00:10:29,220 +triple bond الـ geometry بتكون linear أو diagonal + +132 +00:10:29,220 --> 00:10:34,560 +فبهذه الحالة إذا كانت حركة الخارج رابطة للخارج أقول + +133 +00:10:34,560 --> 00:10:40,100 +اكزو ترياجونال اكزو دياجونال لاحظوا معي أن لما + +134 +00:10:40,100 --> 00:10:46,160 +تكون عندي رابطة أحادية الرابطة الأحادية بتنكسر تماما و + +135 +00:10:46,160 --> 00:10:52,100 +بتطلع كل الـ Y لكن لو كان عندي رابطة ثنائية زي ما + +136 +00:10:52,100 --> 00:10:56,780 +تكون هذه C دبل بوند O بتنكسر بس رابطة واحدة منها + +137 +00:10:56,780 --> 00:11:01,720 +بتصير O minus وبعدين بتصير OH لو كانت رابطة + +138 +00:11:01,720 --> 00:11:06,360 +ثلاثية بس بتنكسر رابطة واحدة بيظل كم رابطة عيدي؟ + +139 +00:11:06,360 --> 00:11:12,700 +اثنتين الآن الأمر الحقيقي السهل في حالة الهجوم اللي + +140 +00:11:12,700 --> 00:11:18,360 +موجود عندنا هنا هو أسهل شيء التتراجونال لكن لما + +141 +00:11:18,360 --> 00:11:22,020 +بيكون عندي رابطة ثنائية هنلاحظ أنه في عندنا + +142 +00:11:22,020 --> 00:11:26,920 +احتمالين هل يا ترى حسب طبيعة الرابطة الهجوم بده + +143 +00:11:26,920 --> 00:11:31,260 +يتم على الـ X و الحركة للخارج أو ممكن الهجوم يتم + +144 +00:11:31,260 --> 00:11:35,890 +على الـ Y و زوج الإلكترونات يتحرك في الداخل هذا + +145 +00:11:35,890 --> 00:11:40,390 +الكلام بالتأكيد هيعطيني حجمين مختلفين من الحلقات + +146 +00:11:40,390 --> 00:11:44,150 +يعني لما الهجوم هنا يتم على الـ X إذا افترضنا أن + +147 +00:11:44,150 --> 00:11:48,370 +هذه الحلقة خمسية لو الهجوم هنا تم على الـ Y شو + +148 +00:11:48,370 --> 00:11:53,890 +الحلقة الحادثية؟ سداسية كذلك الحال هنا ممكن يكون + +149 +00:11:53,890 --> 00:11:57,230 +الهجوم هيك على الـ X نفترض حلقة خمسية لو تم على ال + +150 +00:11:57,230 --> 00:12:03,220 +Y حلقة سداسية وبالتأكيد أنا هنقول Indo + +151 +00:12:03,220 --> 00:12:08,550 +Indocyclization فانميز .. إيش اللي بنقصده بال + +152 +00:12:08,550 --> 00:12:12,030 +Exocyclization و إيش اللي بنقصده بال + +153 +00:12:12,030 --> 00:12:15,830 +Endocyclization في عندي Exocyclization و + +154 +00:12:15,830 --> 00:12:20,710 +Endocyclization الآن هل يا ترى هيمشي عند أكتر Exo + +155 +00:12:20,710 --> 00:12:23,810 +ولا Endocyclization المفروض أن أنتم بتقدروا + +156 +00:12:23,810 --> 00:12:28,510 +تجاوبوا على هذا الكلام يعني لو أنا بستعمل carbon + +157 +00:12:28,510 --> 00:12:32,630 +double bond carbon تقريبا الطرفين في الـ polarity + +158 +00:12:32,630 --> 00:12:38,850 +carbon و carbon بنكون احنا حقيقة مش عارفين هنشوف + +159 +00:12:38,850 --> 00:12:44,890 +مين في هال two carbons more electrophilic ممكن + +160 +00:12:44,890 --> 00:12:48,650 +الهجوم يطم عليها و بنفس الوقت برضه بنطلع على حجم + +161 +00:12:48,650 --> 00:12:51,950 +الحلقة تنسوش أن أنتم أخذتو أنه أنسب أحجام + +162 +00:12:51,950 --> 00:12:56,070 +الحلقات الخمسية والستاسية لأن الزاوية فيهم 128 + +163 +00:12:56,070 --> 00:13:02,900 +مقارنة بالربعية زاوية التسعين بالثلاثية الستين + +164 +00:13:02,900 --> 00:13:07,360 +واضحة الفكرة فبنان ع ذلك لو هان عندي carbon و + +165 +00:13:07,360 --> 00:13:12,560 +carbon التفكير عندي بده يكون حذر أنه فعلا بده أفكر + +166 +00:13:12,560 --> 00:13:16,660 +هالياطورة بده يتم عندي exocyclization ولا + +167 +00:13:16,660 --> 00:13:21,060 +endocyclization لكن مثلا من خبرتكم لو كانت هذه C + +168 +00:13:21,060 --> 00:13:25,600 +double bond O جدّاش أخذتو addition reactions على + +169 +00:13:25,600 --> 00:13:29,320 +الـ C double bond O من الـ more electrophilic + +170 +00:13:29,320 --> 00:13:34,960 +carbon أتم الـ carbon ولا الـ oxygen الـ carbon و + +171 +00:13:34,960 --> 00:13:40,080 +لذلك كان دائما الهجوم على الـ carbon واضح فنفس + +172 +00:13:40,080 --> 00:13:45,020 +الكلام هيتكرر لو كانت C triple bond C هتفكروا كتير + +173 +00:13:45,020 --> 00:13:47,920 +هل الـ cyclization على هذا الموقع أو هذا الموقع لكن + +174 +00:13:47,920 --> 00:13:53,370 +لو كانت C triple bond N أنا الآن بقول لكم 99 وكسر + +175 +00:13:53,370 --> 00:13:57,570 +كمان في المية على الـ C الهجوم مش على الـ N، واضح؟ + +176 +00:13:57,570 --> 00:14:04,630 +فأكتر شيء هيمر معنى اللي هو الـ Indocyclizations في + +177 +00:14:04,630 --> 00:14:10,730 +C triple bond C و في C double bond C لكن مثلا الـ C + +178 +00:14:10,730 --> 00:14:15,650 +double bond O و C triple bond N هدولة غالبا بيصير + +179 +00:14:15,650 --> 00:14:19,090 +الهجوم فيهم على الـ carbon و بيكون عنده + +180 +00:14:19,090 --> 00:14:24,150 +exocyclization طبعا الأمثلة كتيرة احنا ما نستعجلش + +181 +00:14:24,150 --> 00:14:30,190 +و بنشوف الأمثلة في حينه طبعا هذا الكلام بيوضح لنا + +182 +00:14:31,120 --> 00:14:34,940 +أنه كل الـ Baldwin rules كانت عبارة عن رقم بوضع حجم + +183 +00:14:34,940 --> 00:14:39,260 +الحلقة كانت عبارة عن كلمة Exo endo اللي وضحنا إيش + +184 +00:14:39,260 --> 00:14:43,240 +معناها وكانت عبارة عن نوع الذرع اللي بتيم عليها + +185 +00:14:43,240 --> 00:14:46,460 +الهجوم Trigonal و Trigonal و Diagonal إذا الـ + +186 +00:14:46,460 --> 00:14:50,300 +Baldwin rules لما بتصنف عملية Cyclization كام رمز + +187 +00:14:50,300 --> 00:14:56,440 +هتعطيلي تلاتة حجم الحلقة و Exo endo و نوع الذرع + +188 +00:14:56,440 --> 00:15:02,200 +اللي بتيم عليها الهجوم لو بدى مثال لو افترضت مثلا + +189 +00:15:02,200 --> 00:15:06,200 +أخذنا هذا المثال الآن و قلنا هي الـ oxygen هذي + +190 +00:15:06,200 --> 00:15:10,980 +عبارة عن الـ nucleophile و هي عندي C double bond O + +191 +00:15:10,980 --> 00:15:14,820 +وين هيتم الهجوم على الـ C و لا على الـ O؟ على الـ C + +192 +00:15:14,820 --> 00:15:22,800 +بهذا الشكل إذا كيف هتتحرك هذي؟ O و تصير O-H تهيألي + +193 +00:15:22,800 --> 00:15:26,920 +هذه الشغل عارفين addition to carbon double bond O + +194 +00:15:26,920 --> 00:15:33,030 +in aldehydes و هذا هو الناتج لأنه لما بدأ أصنف هذا + +195 +00:15:33,030 --> 00:15:38,730 +الـ cycleization شو بدأ أسميه الحلقة المتكونة إذا + +196 +00:15:38,730 --> 00:15:47,450 +five الحركة Exo هنا الجيومتري Trigonal بس إذا في + +197 +00:15:47,450 --> 00:15:51,130 +ضاب البندر Trigonal إذا هذا الـ cycleization five + +198 +00:15:54,360 --> 00:15:59,380 +واضح؟ هذا الـ cyclization five exo-trigonal الآن + +199 +00:15:59,380 --> 00:16:05,100 +لو شوفنا مثال ثاني المثال الثاني في OH و في carbon + +200 +00:16:05,100 --> 00:16:09,840 +ال triple bond carbon لاحظوا هذا المثال بيغلب ليش؟ + +201 +00:16:09,840 --> 00:16:13,140 +لأن ممكن الـ cyclization يتم هان و في هذه الحالة + +202 +00:16:13,140 --> 00:16:18,620 +الحلقة خماسية و ممكن الـ cyclization يتم هان و في + +203 +00:16:18,620 --> 00:16:23,760 +هذا الحلقة سداسية هذا بدنا نقول الكيمياء علم تجريبي + +204 +00:16:25,210 --> 00:16:29,450 +لأن السنة بتجربة أي شيء بتقوله ليش؟ لأن الخماسي + +205 +00:16:29,450 --> 00:16:34,450 +والسداسي التنتين يعني من أفضل الحلقات في التكوين + +206 +00:16:34,450 --> 00:16:39,270 +فالإنسان قبل ما يعمل التفاعل بيكون مش عارف حقيقة + +207 +00:16:39,270 --> 00:16:43,130 +وين تم التفاعل، الآن عملوا التفاعل، فصلوا الناتج، + +208 +00:16:43,130 --> 00:16:50,290 +لاحظوا أن هذا الـ cycleization اللي تم هذا أي + +209 +00:16:50,290 --> 00:16:56,320 +cycleization؟ الـ Exo ولا الـ Indo؟ الـ اندو لاحظوا الـ + +210 +00:16:56,320 --> 00:16:59,460 +double bond هنا كان في عندي OH تطلع هذه الـ + +211 +00:16:59,460 --> 00:17:04,220 +carbon شايفينها هذه الـ carbon اللي هنا بتاعة الـ + +212 +00:17:04,220 --> 00:17:09,680 +triple bond كان عليها OH لأ إطلاقا الآن تمت + +213 +00:17:09,680 --> 00:17:18,360 +الحركة للداخل صارت C minus والـ C minus صارت C H إذا + +214 +00:17:18,360 --> 00:17:24,140 +إيش نوع الـ cyclization هنا Indo ولا Exo؟ Indo + +215 +00:17:24,140 --> 00:17:28,220 +الآن الـ carbon اللي تم عليها الـ cyclization اللي + +216 +00:17:28,220 --> 00:17:32,460 +هي الـ carbon الثانية تبعت الـ triple bond طالما + +217 +00:17:32,460 --> 00:17:37,860 +triple bond إذا Diagonal جيومتري إلها ولذلك هذا الـ + +218 +00:17:37,860 --> 00:17:44,590 +cyclization بنسميه six Indo Diagonal 6 اندو + +219 +00:17:44,590 --> 00:17:48,950 +Diagonal 6 لأن الحلقة السداسية Indo لأن الحركة + +220 +00:17:48,950 --> 00:17:52,530 +للداخل يعني تم الهجوم على الذرة الخارجية وتكوين + +221 +00:17:52,530 --> 00:17:59,010 +الحلقة الأكبر يعني دائما كلمة Exo تعني تكوين + +222 +00:17:59,010 --> 00:18:05,690 +الحلقة الأصغر وكلمة Endo تعني تكوين الحلقة الأكبر + +223 +00:18:05,690 --> 00:18:13,840 +يعني لو أجينا أعطناكم زي هيك وقلنا لكم اعملوا لنا الـ + +224 +00:18:13,840 --> 00:18:23,460 +five اندو دياجونال اكتبوا الناتج five + +225 +00:18:23,460 --> 00:18:28,820 +Exo اكتبوا + +226 +00:18:28,820 --> 00:18:34,680 +ال five Exo Diagonal product وقتها بدكم تقولوا أن + +227 +00:18:34,680 --> 00:18:41,570 +هذه الـ oxygen هاجمت هنا أن هذه تحملت على الـ carbon + +228 +00:18:41,570 --> 00:18:48,990 +اللي هنا و نكتب الناتج C + +229 +00:18:48,990 --> 00:18:55,930 +double bond O C واحدة و هنا الـ oxygen الهجوم تمها + +230 +00:18:55,930 --> 00:19:02,110 +الآن هانضل C + +231 +00:19:02,110 --> 00:19:08,850 +double bond A و H هذا زوج الإلكترونات اللي كانت + +232 +00:19:08,850 --> 00:19:14,130 +الرابطة هذا اللي احنا عاملينه هو اللي كان الرابط + +233 +00:19:14,130 --> 00:19:20,130 +اللي اتحركت بهذا الشكل هي الـ five Exo Diagonal و + +234 +00:19:20,130 --> 00:19:26,450 +هي الـ six Endo Diagonal product واضح؟ الآن اللي + +235 +00:19:26,450 --> 00:19:30,270 +بيكون بيعمل تجربة أو بيكون بيعمل مخطط بحث و بيقول + +236 +00:19:30,270 --> 00:19:34,910 +أنا بدي اعمل هذا التفاعل الأصل أنه يقول we expect + +237 +00:19:34,910 --> 00:19:38,650 +two products to be formed which one will be formed + +238 +00:19:38,650 --> 00:19:43,750 +this depends on the experiment هذا الكلام في نهاية + +239 +00:19:43,750 --> 00:19:47,870 +الكيمياء علم تجريبي يتكون هذا المركب و لهذا المركب + +240 +00:19:47,870 --> 00:19:55,580 +الله أعلم هنلاحظ أثناء دراستنا أنه كثير بتكون + +241 +00:19:55,580 --> 00:19:59,500 +ضالكم وعييلة الاحتمالات المختلفة للتفاعلات هي + +242 +00:19:59,500 --> 00:20:04,580 +الكيمياء بجزء كبير منها فكرة isomers و فكرة + +243 +00:20:04,580 --> 00:20:08,860 +احتمالات مختلفة للتفاعلات مرت معكم في مناطق كثير + +244 +00:20:08,860 --> 00:20:12,460 +و هتظل تتكرر معنا أثناء دراستنا في الـ heterocyclic + +245 +00:20:12,460 --> 00:20:22,580 +chemistry هاي مثلا في عندنا مثال جديد ممكن نفكر فيه + +246 +00:20:22,580 --> 00:20:27,220 +.. ممكن نفكر فيه هذا المثال فيه Oxygen خلينا نقول + +247 +00:20:27,220 --> 00:20:32,260 +الـ Oxygen Nucleophile الآن لو سألنا يا ترى كام + +248 +00:20:32,260 --> 00:20:39,300 +احتمال عندي للـ Cyclization هنا الأصل أن نقول تلاتة + +249 +00:20:39,300 --> 00:20:43,500 +حتى لو هو ناقش احتمالين خلينا نشوف الاحتمالات اللي + +250 +00:20:43,500 --> 00:20:48,000 +ناقشها هو ناقش احتمال أن هذا الـ Oxygen اتهاجم على + +251 +00:20:48,000 --> 00:20:55,540 +هذا الـ Carbon وهنا بدو يصير Indo وهنا تجيني H كانت H + +252 +00:20:55,540 --> 00:21:01,580 +موجودة هي الـ double bond واضح؟ إذا هجوم الـ oxygen + +253 +00:21:01,580 --> 00:21:05,480 +على هذا الـ carbon هو أحد الاحتمالات ولا لأ؟ شو + +254 +00:21:05,480 --> 00:21:11,920 +سميناها؟ five Indo والهجوم على الـ Trigonal هنا لأن + +255 +00:21:11,920 --> 00:21:21,610 +هاي رابطتين وهنا فيه H و H هاي الـ Trigonal الآن هو + +256 +00:21:21,610 --> 00:21:28,650 +رسم الجزئ مجرد أنه رسمه بطريقة ثانية قال ما المانع و + +257 +00:21:28,650 --> 00:21:32,210 +ممكن نتخيل أن هادي كنا رسمينها لأعلى و هنا الـ + +258 +00:21:32,210 --> 00:21:35,410 +oxygen ما المانع أن هادي الـ oxygen اتهاجم على الـ + +259 +00:21:35,410 --> 00:21:40,630 +carbon تبعت الـ E star و في الـ E stars التفاعل + +260 +00:21:40,630 --> 00:21:46,490 +الأساسي في الأحماض و مشتقاتها إيش سميناها؟ هذه الكلمة + +261 +00:21:46,490 --> 00:21:51,050 +يعني ممنوع أنكم تنسوها بحياتكم لما جسمنا الـ + +262 +00:21:51,050 --> 00:21:55,050 +carbonyl compounds لنوعين جلنا الـ aldehydes و الـ + +263 +00:21:55,050 --> 00:21:59,550 +ketones دائما مع بعض في شبطر الأحماض و مشتقاتها + +264 +00:21:59,550 --> 00:22:05,450 +دائما مع بعض في شبطر، ليش؟ لأن الـ aldehydes و الـ + +265 +00:22:05,450 --> 00:22:10,050 +ketones يميزهم شيء مشترك واحد و تفاعل الإضافة + +266 +00:22:10,050 --> 00:22:15,750 +الأحماض و مشتقاتها يميزها شيء مشترك واحد و تفاعل + +267 +00:22:15,750 --> 00:22:23,590 +الإبدال متذكرين؟ ولذلك لما كان مر عليكم على سبيل + +268 +00:22:23,590 --> 00:22:27,590 +المثال تفاعلين مشهورين ودائما تسألوا فيهم واحد + +269 +00:22:27,590 --> 00:22:30,670 +بيمر عندكم في الـ aldehydes و ketones و واحد في + +270 +00:22:30,670 --> 00:22:35,450 +الأحماض ومشتقاتها الـ aldol Claisen reaction الـ aldol + +271 +00:22:35,450 --> 00:22:41,050 +addition reaction الـ Claisen substitution reaction + +272 +00:22:41,050 --> 00:22:45,030 +واضح؟ ولذلك لو أنا هنا بدي أخد هذا الإغلاق الأصفر + +273 +00:22:46,270 --> 00:22:50,250 +أو أخلي الـ Oxygen اتهاجم على C double bond O شو + +274 +00:22:50,250 --> 00:22:54,290 +هتطرد الـ O Methane تفاعل الـ Ester تفاعل الـ Ester + +275 +00:22:54,290 --> 00:22:58,090 +Substitution هينتج عنده هذا الناتج طبعا هذه هتكون + +276 +00:22:58,090 --> 00:23:05,670 +خارج الـ Cyclization ربما هذا المثال بشكل الحالي + +277 +00:23:05,670 --> 00:23:11,410 +يجيب لكم أو يوضح لكم مشكلة من أهم الأمور اللي بتغلب + +278 +00:23:11,410 --> 00:23:15,310 +الطلبة اللي بتغلب الطلبة في الـ heterocyclic + +279 +00:23:15,310 --> 00:23:20,350 +chemistry على الإطلاق هذه النقطة أن يستطيع أي + +280 +00:23:20,350 --> 00:23:28,270 +إنسان أن يرسم الجزء بطريقة معينة فيوحي لكم بإغلاق + +281 +00:23:28,270 --> 00:23:33,810 +معين بسهولة ويرسموا بطريقة ثانية فأنتم بيكون + +282 +00:23:33,810 --> 00:23:38,770 +الإغلاق يبين بعيد عنكم ولذلك بهذا الشكل لما حطّ ال + +283 +00:23:38,770 --> 00:23:42,730 +O جنب هذا ال carbon كان سهل عليكم تشوفوا الإغلاق + +284 +00:23:42,730 --> 00:23:49,460 +الآن ال O حطّها بعيد عن هذا ال carbon واضح نفس هذا + +285 +00:23:49,460 --> 00:23:53,600 +المثال أنا كان ممكن أرسمه بطريقة هذه C double bond + +286 +00:23:53,600 --> 00:23:59,080 +O O مثل أطلع لفوق أخلي هذا C double bond C لبرا + +287 +00:23:59,080 --> 00:24:06,020 +هيها المتصلة مباشرة بعدها إيش عندي CH2 كمان CH2 + +288 +00:24:06,020 --> 00:24:16,720 +كمان O هذا هو نفس هذا، هذا هو نفس هذا، مسكت هذه، + +289 +00:24:16,720 --> 00:24:20,540 +سحبت للأعلى، يعني لو على برنامج الرسم بالماوس، + +290 +00:24:20,540 --> 00:24:25,980 +بسحب هذه لأعلى، الآن بهذا الشكل، إيش ال E حق اللي + +291 +00:24:25,980 --> 00:24:30,640 +أسرع على ذهنكم؟ أن هذه ال O وهي ال E star، نحن + +292 +00:24:30,640 --> 00:24:36,500 +مليون مرة عملنا تفاعل Oxygen على E star، الآن خلّيني + +293 +00:24:36,500 --> 00:24:40,920 +أُكد على هذه النقطة وهي من أهم المشاكل اللي بتواجه + +294 +00:24:40,920 --> 00:24:44,800 +الطالب في الكيميا الحلقية مرات كثير بيعتقد أنه + +295 +00:24:44,800 --> 00:24:50,580 +فاهم وبيجي على الامتحان أنه فاهم لكن يمكن أفضل كلمة + +296 +00:24:50,580 --> 00:24:55,320 +بقول لكم إياها عشان يجي له الفكرة إنه كيف يجيب + +297 +00:24:55,320 --> 00:24:59,760 +الشغلات على بعض وتسكر بالشكل الصحيح صدقوني ما بينفع + +298 +00:24:59,760 --> 00:25:06,990 +غير شغلة واحدة عارفين شو هي؟ رضا الله ورضا الوالدين + +299 +00:25:06,990 --> 00:25:11,630 +رضا الله ورضا الوالدين، غير هيك ممكن ما يجي على + +300 +00:25:11,630 --> 00:25:15,610 +بالكم الإغلاق اللي بده يتم وتصيروا تفكروا تشتغلوا + +301 +00:25:15,610 --> 00:25:20,050 +تكونوا بتعملوا ببحث معين لأنكم رسمتوا الجزيء بشكل + +302 +00:25:20,050 --> 00:25:24,590 +معين أوحى لكم بزاوية معينة يعني لو هذا الجزيء + +303 +00:25:24,590 --> 00:25:29,850 +مرسوم بهذا الشكل ربما الإيحاء الأسرع إلى ذهنكم هذا + +304 +00:25:29,850 --> 00:25:34,960 +الـ cycleization هيعطيني نفس الناتج اللي هنا، واضح أن + +305 +00:25:34,960 --> 00:25:40,920 +الحلقة خماسية وأن الـ cyclization اكزو اه ولذلك + +306 +00:25:40,920 --> 00:25:44,480 +هذا five اكزو الـ triangular لأن هذا الـ triangular + +307 +00:25:44,480 --> 00:25:50,380 +الآن لاحظوا معي أن الرسم الجزء بهذه الطريقة يمكن + +308 +00:25:50,380 --> 00:25:57,070 +بيان أنه بشكل واضح سايكلايزيشن ثاني ممكن يتم بسهولة + +309 +00:25:57,070 --> 00:26:01,110 +أن هذه double bond C double bond O وهذه C double + +310 +00:26:01,110 --> 00:26:07,230 +bond C ما المانع أن يجي الـ cycleization هذا بهذا + +311 +00:26:07,230 --> 00:26:13,590 +الشكل وهذا تيجي للخارج واجت لو بدي أشوف إيش + +312 +00:26:13,590 --> 00:26:15,890 +الناتج اللي بدي يكون اللي هو نفس هذا ال + +313 +00:26:15,890 --> 00:26:19,890 +cycleization اللي هذا اللي يتم على هذا الكربون و + +314 +00:26:19,890 --> 00:26:26,640 +اجت هذا الناتج اللي عندي حلقة رباعية ومن هنا ال + +315 +00:26:26,640 --> 00:26:32,320 +CH2 صارت single bond وأخدت H CH3C + +316 +00:26:32,320 --> 00:26:41,990 +O مثل هذا ما كتبوها، ولذلك لما أنا بدي أجي أحكي كم + +317 +00:26:41,990 --> 00:26:46,250 +احتمال cyclization ممكن عندي في هذا المثال لحتى + +318 +00:26:46,250 --> 00:26:49,830 +الآن ضمن احتمالات الكيميا طالما carbon double bond + +319 +00:26:49,830 --> 00:26:54,170 +carbon ممكن أتمّ هان بحلقة خمسية ممكن أتمّ هان بحلقة + +320 +00:26:54,170 --> 00:26:58,890 +رباعية ممكن أتمّ هان بحلقة خمسية ثانية طبعًا واحدة + +321 +00:26:58,890 --> 00:27:03,630 +بتقول نظريًا الجواب اه لو كان في XY ممكن أتمّ هان + +322 +00:27:05,700 --> 00:27:09,740 +ممكن يتم على هذا ال oxygen إغلاق للداخل وهيعطينا + +323 +00:27:09,740 --> 00:27:14,420 +وجهة حلقة ربما سداسية لكن لما بكون عندي سيضة بال + +324 +00:27:14,420 --> 00:27:18,060 +bond O وأنا عارف شوية علم في الكيميا أن ال carbon + +325 +00:27:18,060 --> 00:27:21,160 +هي اللي بده تكون electrophilic more than the + +326 +00:27:21,160 --> 00:27:27,760 +oxygen استبعدت الاحتمال اللي هنا، واضح؟ لكن كرسم، لو + +327 +00:27:27,760 --> 00:27:32,820 +إنسان بده يرسم جميع الاحتمالات، النظرية للإغلاق في + +328 +00:27:32,820 --> 00:27:37,460 +هذا المركب، بده يرسم أكثر من احتمال، واضح؟ + +329 +00:27:37,460 --> 00:27:41,420 +خلّينا نقول أقل تقدير هذه الاحتمالات اللي موجودة، + +330 +00:27:41,420 --> 00:27:45,200 +هذا الاحتمال واضح، هذا واضح، هذا لو كنت الآن بدي + +331 +00:27:45,200 --> 00:27:48,420 +أسمّيه الاحتمال، اللي هو بهذا الشكل + +332 +00:27:52,260 --> 00:27:58,080 +إذا for اكزو ترياجونال + +333 +00:27:58,080 --> 00:28:05,360 +for اكزو ترياجونال واضح؟ الآن هذه بتكون من أول + +334 +00:28:05,360 --> 00:28:10,180 +دراستنا للموضوع بتعطيكم فكرة أن دائمًا تطلعوا على + +335 +00:28:10,180 --> 00:28:14,820 +الجزيء ترسموه بأكثر من طريقة تحطّوا أكثر من احتمال + +336 +00:28:14,820 --> 00:28:19,640 +بالورقة والقلم الآن التجربة شو بتطلع؟ الحلقة + +337 +00:28:19,640 --> 00:28:24,080 +الرباعية أو الخماسية أو السداسية ما تقولوا إطلاقًا أن + +338 +00:28:24,080 --> 00:28:28,440 +الحلقة الخمسية أو السداسية more stable وتستثنوا + +339 +00:28:28,440 --> 00:28:33,540 +الرباعية أو الثلاثية كثير مركبات فيهم حلقات رباعية و + +340 +00:28:33,540 --> 00:28:38,640 +مركبات ثابتة ومشهورة خدوا كل عيلة البنسالين إذا + +341 +00:28:38,640 --> 00:28:42,500 +مرت عليكم البنسالين مش عبارة عن ال beta lactam + +342 +00:28:42,500 --> 00:28:46,920 +ring وهذه حلقة رباعية أشهر المضادات الحيوية يعني + +343 +00:28:46,920 --> 00:28:52,060 +من أشهر اكتشافات الكيمياء المركبات اللي فصلت و + +344 +00:28:52,060 --> 00:28:56,040 +أخدت استعمال البنسالين، البنسالين حلقة رباعية و + +345 +00:28:56,040 --> 00:28:59,460 +بالباع كأدوية والناس بتعالج فيه وما إلى ذلك ما + +346 +00:28:59,460 --> 00:29:04,560 +تستثنوا بالورقة والقلم احتمالات الآن على أرض + +347 +00:29:04,560 --> 00:29:10,940 +الواقع، الله أعلم لما نحن بدنا نبدأ نشرح بالتأكيد + +348 +00:29:10,940 --> 00:29:13,800 +الآن بيصير الكلام عندكم واضح أن كيف أنا بدي أشرح + +349 +00:29:13,800 --> 00:29:20,030 +الـ cyclization reactions، هأبدأ بهذا النوع وهذا + +350 +00:29:20,030 --> 00:29:24,210 +النوع إبدال لأن أنا بطلع ال Y بعدين addition على + +351 +00:29:24,210 --> 00:29:27,250 +ال double bond سواء كانت carbon double bond oxygen + +352 +00:29:27,250 --> 00:29:30,650 +أو carbon triple bond أو carbon double bond carbon + +353 +00:29:30,650 --> 00:29:33,610 +أو ممكن أعمل substitution على carbon double bond + +354 +00:29:33,610 --> 00:29:39,070 +oxygen إذا كانت من عائلة الأحماض ومشتقاتها بعدين + +355 +00:29:39,070 --> 00:29:43,870 +هأروح على ال carbonTriple bond carbon و carbon + +356 +00:29:43,870 --> 00:29:47,310 +triple bond nitrogen و nitrogen triple bond carbon + +357 +00:29:47,310 --> 00:29:51,410 +فبناء على ذلك هيصير توزيع المحاضرات اللي نحن + +358 +00:29:51,410 --> 00:29:57,090 +بنشرحهم بوضوح الـ substitution أن عندي هنا مجموعة + +359 +00:29:57,090 --> 00:30:01,170 +بده أطردها هالوجين أو good leaving group بعد هيك + +360 +00:30:01,170 --> 00:30:05,590 +reaction at double bonds بعدين reaction at triple + +361 +00:30:05,590 --> 00:30:09,590 +bonds فإيش اللي هنبدأ فيه؟ الـ Substitution + +362 +00:30:09,590 --> 00:30:15,910 +Reactions تفاعلات الإبدال على تتراجونال كربون + +363 +00:30:18,670 --> 00:30:22,710 +لو شفنا الموضوع لاحظوا في ناس اشتغلوا على هذا + +364 +00:30:22,710 --> 00:30:25,890 +الموضوع ومن هنا بتقدروا تشوفوا أهمية أنكم + +365 +00:30:25,890 --> 00:30:30,810 +تتعلموا طريقة من أنكم تتعلموا تحضير مركب معين أنا + +366 +00:30:30,810 --> 00:30:35,010 +الآن الطريقة عندي اليوكليوفايل وإبدال صح؟ خليني + +367 +00:30:35,010 --> 00:30:38,730 +أقول هي الآن اشتون يوكليوفايل وال PR good living + +368 +00:30:38,730 --> 00:30:46,110 +group خلت الذرات ثلاثة بعمل هنا ال cyclization بيصير + +369 +00:30:46,110 --> 00:30:51,870 +ولا ما بيصيرش وبطرد ال PR three exo tetragonal + +370 +00:30:51,870 --> 00:30:56,170 +cyclization بعمل هنا ال cyclization لو زدت ذرة + +371 +00:30:56,170 --> 00:31:02,970 +four exo tetragonal cyclization بزيد كمان ذرة five + +372 +00:31:02,970 --> 00:31:09,200 +exo tetragonal six exo tetragonal فهذه الفكرة عامة + +373 +00:31:09,200 --> 00:31:16,760 +كم حلقة حضرنا منها لو بتطلعوا أزردين وأزتدين و + +374 +00:31:16,760 --> 00:31:24,460 +بيرولدين وبيبريدين كل أنواع الحلقات لكن حضرناهم + +375 +00:31:24,460 --> 00:31:28,800 +بفكرة واحدة اللي هي فكرة الـ cycleization أو الـ + +376 +00:31:28,800 --> 00:31:31,820 +substitution at saturated carbon + +377 +00:31:34,220 --> 00:31:37,940 +الآن اعملوا دراسات للناس اللي اشتغلوا على هذا + +378 +00:31:37,940 --> 00:31:44,000 +الموضوع على قد إيش سرعة التفاعل اعتمادًا على حجم + +379 +00:31:44,000 --> 00:31:49,410 +الحلقة لاحظوا أن لو يعتبروا مثلًا ال ring size + +380 +00:31:49,410 --> 00:31:56,070 +الحلقة الرباعية واحد الحلقة الخماسية بتكون أسرع في + +381 +00:31:56,070 --> 00:32:00,270 +التكون بـ 6 في 10 و4 يعني 60 ألف مرة من الحلقة + +382 +00:32:00,270 --> 00:32:04,230 +الرباعية هذا كلام منطقي نحن اتعلمنا أن الخماسي + +383 +00:32:04,230 --> 00:32:09,770 +أفضل من الرباعي السداسية بـ ألف مرة لاحظوا + +384 +00:32:09,770 --> 00:32:16,320 +السباعية مرتين يعني ضعيفة جدًا الرباعية كنا ما عطيناها + +385 +00:32:16,320 --> 00:32:19,420 +هي الـ reference اللي قرأنا فيها خليناها واحد + +386 +00:32:19,420 --> 00:32:26,380 +الثلاثية 70 ربما البعض يستغرب من أي منطقة أن + +387 +00:32:26,380 --> 00:32:32,760 +الثلاثية أكثر من الرباعية مع العلم لو أنتم بتاخذوا + +388 +00:32:32,760 --> 00:32:37,640 +الكلام بمنطق الزوايا وأن الزاوية اللي متراوحة الـ + +389 +00:32:37,640 --> 00:32:42,680 +109 أو 109.5 وهذه الخماسية 108 كلام منطقي + +390 +00:32:42,680 --> 00:32:47,520 +السداسية 120 كلام منطقي السباعية خلاص بتبعد وما + +391 +00:32:47,520 --> 00:32:50,900 +إلى ذلك الحلقات الكبيرة صعب التكوين صعب أنهم + +392 +00:32:50,900 --> 00:32:55,530 +يلتقوا مع بعض الأطراف البعيدة لكن السؤال اللي أنتم + +393 +00:32:55,530 --> 00:33:00,470 +ممكن تستغربوا أن الحلقة الرباعية زاويتها 90 + +394 +00:33:00,470 --> 00:33:06,670 +الثلاثية زاويتها 60 فالتوقع اللي ممكن تتوقعوا أن + +395 +00:33:06,670 --> 00:33:11,690 +الرباعية تتكون أفضل من الثلاثية بهذا المثال بكل + +396 +00:33:11,690 --> 00:33:16,310 +الأحوال الثلاثية اللي تكونت هي مور عليكم أمثلة + +397 +00:33:16,310 --> 00:33:21,270 +يكون الاحتمال ما بين حلقة رباعية وخماسية واتلاحظوا + +398 +00:33:21,270 --> 00:33:25,590 +اللي بتتكون الرباعية مش الخماسية Chemistry is an + +399 +00:33:25,590 --> 00:33:29,350 +experimental science بعدين تصيروا تفسروها تقولوا + +400 +00:33:29,350 --> 00:33:32,630 +thermodynamically control the product ولا كاينة + +401 +00:33:32,630 --> 00:33:36,170 +kinetic control the product إيش ما كان هذا موضوع ثاني + +402 +00:33:36,170 --> 00:33:41,370 +لكن في كل الأحوال الأساس التجربة في الحلقات + +403 +00:33:41,370 --> 00:33:44,510 +الثلاثية ليش بيقولوا الحلقات الثلاثية بتتكون؟ + +404 +00:33:44,510 --> 00:33:49,650 +بعرفش إذا أحد منكم عمره فكر أن هالـ orbitals فعلاً + +405 +00:33:49,650 --> 00:33:53,470 +صعب جدًا يعني لو أنا تخيلت الحلقة الثلاثية بهذا + +406 +00:33:53,470 --> 00:33:58,750 +الشكل الـ orbitals صعب جدًا تنضغط بزاوية 60 الآن أي + +407 +00:33:58,750 --> 00:34:03,940 +شيء مش قادر ينضغط شو بيعمل؟ بيطلع لبرا.. بيطلع + +408 +00:34:03,940 --> 00:34:07,760 +لبرا ولذلك الـ orbitals هنا بتيجي بين الـ carbon و + +409 +00:34:07,760 --> 00:34:14,620 +الـ carbon الـ orbitals هنا بتيجي للخارج بهذا الشكل + +410 +00:34:14,620 --> 00:34:21,240 +يعني تخيل هذه orbital وهذه orbital فتركيز + +411 +00:34:21,240 --> 00:34:24,880 +الإلكترونات بيكونش بين الذرتين بيكون للخارج وهنا + +412 +00:34:24,880 --> 00:34:29,620 +نفس الشيء هذه orbitals وهذه orbitals هنا نفس + +413 +00:34:29,620 --> 00:34:37,000 +الشيء هي orbitals وهي + +414 +00:34:37,000 --> 00:34:40,900 +orbitals الآن لاحظوا لو أنا بدي أشوف كل هذه الـ + +415 +00:34:40,900 --> 00:34:44,560 +orbital الآن ككثافة إلكترونية صارت في الخارج it + +416 +00:34:44,560 --> 00:34:53,940 +looks like banana زي الموزة شكل الـ orbitals ولذلك + +417 +00:34:53,940 --> 00:34:59,700 +هذه بيسمّوها banana like orbitals يعني orbitals + +418 +00:34:59,700 --> 00:35:04,900 +بتشبه الموزة فلو أنتم بدكم تكتبوا تشوفوا كلام + +419 +00:35:04,900 --> 00:35:11,340 +أكثر عن الموضوع اكتبوا banana like orbitals الـ + +420 +00:35:11,340 --> 00:35:16,060 +orbitals بتشبه إيش؟ الموزة طالعة لبرا مش جاي بين + +421 +00:35:16,060 --> 00:35:21,300 +الذرتين الآن لاحظوا هنا الزاوية أكبر ولا مش أكبر؟ + +422 +00:35:21,300 --> 00:35:25,920 +أكبر من الـ 60 لأن الـ orbitals مستحيل تتضغط بهذا + +423 +00:35:25,920 --> 00:35:30,860 +الشكل فالإلكترونات بتصير كثافتهم مش مباشرة بين + +424 +00:35:30,860 --> 00:35:36,240 +الذرتين بتصير طالعة على برا واضح؟ فهذا قد يكون جزء + +425 +00:35:36,240 --> 00:35:41,060 +من تفسير أنه يعني عامة بتشوفوا أن الحلقة الثلاثية + +426 +00:35:41,060 --> 00:35:47,360 +هنا طلعت ربما بنسب أو بسرعة أفضل حتى من الرباعية + +427 +00:35:51,390 --> 00:35:57,030 +الآن أيش بالظبط تكون أي حلقة و كيف تكون هذا علم + +428 +00:35:57,030 --> 00:36:00,810 +كامل بحاجة لتفصيل ما تنسوش أن احنا لما أخذنا + +429 +00:36:00,810 --> 00:36:07,790 +الـ cyclobutane بداية قولنا the cyclobutane is not a + +430 +00:36:07,790 --> 00:36:13,350 +planar molecule احنا ما بتكونش تنسوا اللي هي الـ .. + +431 +00:36:13,350 --> 00:36:18,620 +ايش .. بيشبه أيش الـ cyclobutane؟ الـ butterfly + +432 +00:36:18,620 --> 00:36:24,240 +الفراشة قولنا الـ cyclobutane مش زي هيك بنعمله و + +433 +00:36:24,240 --> 00:36:33,590 +planar لأ بنعمله زي الفراشة تخيلوا هيك زي الـ + +434 +00:36:33,590 --> 00:36:38,190 +butterfly هذا درسناه في الـ geometry واخذنا الحلقة + +435 +00:36:38,190 --> 00:36:41,750 +الخمسية it is like an open envelope واخذنا الحلقة + +436 +00:36:41,750 --> 00:36:45,370 +السوداسية فيها conformations it shares و both + +437 +00:36:45,370 --> 00:36:49,980 +conformations و أشياء هذا الكلام كله يرجع له في + +438 +00:36:49,980 --> 00:36:55,180 +دراسة الحلقات الأصلية فالآن كيف بدها تصفى الزوايا + +439 +00:36:55,180 --> 00:36:59,860 +و أطوال الروابط في هذه الحلقات هذا كلام بيدرسه + +440 +00:36:59,860 --> 00:37:03,960 +أكثر ناس بيدرسه اللي بيدرسوا الـ molecular geometry + +441 +00:37:03,960 --> 00:37:08,780 +و بيعملوا لبعض المركبات x-ray بالتالي بتلاقوهم + +442 +00:37:08,780 --> 00:37:13,580 +حاطين كل أطوال الروابط و كل زوايا الروابط الزوايا + +443 +00:37:13,580 --> 00:37:20,160 +العادية و الـ dihedral angles أشياء كثيرة، ناخذ مثال + +444 +00:37:20,160 --> 00:37:27,100 +ثاني لحظوا هذا المثال هذا المثال الجميل بالشكل + +445 +00:37:27,100 --> 00:37:32,260 +القاتم عندي carboxylate anion carboxylate anion + +446 +00:37:32,260 --> 00:37:38,660 +هذا الـ carboxylate anion بيهاجم هنا بيطرد الـ Br + +447 +00:37:38,660 --> 00:37:46,240 +هيعمل حلقة و exo tetrafuran واضح الآن + +448 +00:37:46,240 --> 00:37:50,420 +انتبهوا معي وين بتكون الـ heterocycle الكيميسترا سهلة + +449 +00:37:50,420 --> 00:37:56,420 +وين بتصعد لما أنا بأجي أرسم لكم المثال بهذا الشكل + +450 +00:37:56,420 --> 00:38:01,780 +جاهز يعني أنا حاطط لنيوكليوفيل تماما عند الـ + +451 +00:38:01,780 --> 00:38:07,040 +electrophile ولا أجمّل لكن لما أنا بأجي أقول لكم + +452 +00:38:07,040 --> 00:38:17,610 +أنه والله عنده CH2 بعدين CH2 + +453 +00:38:17,610 --> 00:38:22,230 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +454 +00:38:22,230 --> 00:38:26,890 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +455 +00:38:26,890 --> 00:38:27,690 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +456 +00:38:27,690 --> 00:38:28,550 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +457 +00:38:28,550 --> 00:38:36,130 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +458 +00:38:36,130 --> 00:38:41,760 +CH2 CH2 CH يعني عملت الانيم وبعد هيك تتخيلوا كيف + +459 +00:38:41,760 --> 00:38:46,300 +لفّيتوا الجزء الجزء جربت الـ O- عند هذا الكربون + +460 +00:38:46,300 --> 00:38:50,980 +اللي حامله بروم عشان يتم التفاعل ولذلك بقول لكم + +461 +00:38:50,980 --> 00:38:54,860 +أنا أن الـ heterocycle chemistry بدها خبرة يعني + +462 +00:38:54,860 --> 00:38:59,060 +بهذا الشكل completely following equation سهلة بهذا + +463 +00:38:59,060 --> 00:39:05,410 +الشكل بالتأكيد هتبدو تحس أنه صعب وين الـ nucleophile + +464 +00:39:05,410 --> 00:39:09,110 +وين الـ electrophile كيف ألف الأشياء المرسومة + +465 +00:39:09,110 --> 00:39:13,990 +أحيانا ممكن يكون الجزء مرسوم ومحطوطين الطرفين اللي + +466 +00:39:13,990 --> 00:39:17,990 +بدهم يعملوا cyclization أبعد ما يمكن على بعض آخر + +467 +00:39:17,990 --> 00:39:21,690 +ما يخطر على بالكم أن هذول بدهم ييجوا يعملوا + +468 +00:39:21,690 --> 00:39:26,480 +cyclization ولذلك اللي بده يسهل على طلابه في + +469 +00:39:26,480 --> 00:39:30,240 +المستقبل لما بدرسوا الكيمياء أفضل شيء أنه يرسم + +470 +00:39:30,240 --> 00:39:35,400 +الجزء بوضعية جيدة تتيح أن الطالب يشوف التفاعل + +471 +00:39:35,400 --> 00:39:40,760 +بطريقة بسيطة أو سهلة هذا الكلام بيساعد على الفهم + +472 +00:39:40,760 --> 00:39:45,160 +لكن بنفس الوقت ممكن يكون له أثر ضار أنه على أرض + +473 +00:39:45,160 --> 00:39:49,980 +الواقع لو إجا لهذا الطالب سؤال مش مرسوم بسهولة + +474 +00:39:49,980 --> 00:39:53,360 +ما تعودش يشغل مخه كثير واضح؟ + +475 +00:40:00,990 --> 00:40:08,550 +الآن ناخذ مثال إضافة، يسموه الـ Darzen Condensation + +476 +00:40:08,550 --> 00:40:12,290 +Reaction أو Darzen Reaction وهذا الـ Darzen + +477 +00:40:12,290 --> 00:40:18,090 +Reaction بيحضروا فيه الـ Epoxides بيحضروا فيه الـ + +478 +00:40:18,090 --> 00:40:22,910 +Epoxides بتعرفوا الـ Epoxides اللي هي الحلقات + +479 +00:40:22,910 --> 00:40:29,890 +الثلاثية شو الـ Darzen Reaction هذا؟ هو تفاعل كيتون + +480 +00:40:29,890 --> 00:40:34,290 +أو aldehyde احنا أي إيش اللي استعملناها؟ الديهيد + +481 +00:40:34,290 --> 00:40:41,170 +بنزل الديهيد تفاعل كيتون أو الديهيد مع alpha halo ester + +482 +00:40:41,170 --> 00:40:45,950 +alpha halo ester لو طلعت أنا عند سي دي بالبنت + +483 +00:40:45,950 --> 00:40:52,170 +أو اقفل هاي CH2 على موقع alpha عند هالوجين + +484 +00:40:53,180 --> 00:40:57,680 +فصار هذا alpha halo ester يعرفنا إذا كيف alpha halo + +485 +00:40:57,680 --> 00:41:03,080 +ester الآن هذا الـ alpha halo ester أكيد في الخطوة + +486 +00:41:03,080 --> 00:41:08,240 +الأولى تبعت التفاعل بالفعل مع base اتذكروا أن عندي + +487 +00:41:08,240 --> 00:41:14,080 +هنا في الأصل CH2 بين C=O و بين halogen + +488 +00:41:14,080 --> 00:41:18,400 +الـ CH2 لبين تنتين C=O ولا بين C= + +489 +00:41:18,400 --> 00:41:23,160 +bond O و C≡N أو بين C=O و + +490 +00:41:23,160 --> 00:41:26,800 +Sulphur أو بين C=O و Halogen شو سميناها + +491 +00:41:26,800 --> 00:41:32,800 +هذه CH2 Activated Methylene Group فيها Acidic + +492 +00:41:32,800 --> 00:41:38,500 +Hydrogens فبأبسط base تفقد هيدروجين صار عنده anion + +493 +00:41:38,500 --> 00:41:44,280 +سالب صار عنده anion سالب الآن هذا الـ anion السالب + +494 +00:41:44,280 --> 00:41:47,140 +زي ما تعلمتوا في الـ organic synthesis هذا الـ anion + +495 +00:41:47,140 --> 00:41:51,840 +السالب لما بده يهاجم وين بده يهاجم؟ على الـ C= + +496 +00:41:51,840 --> 00:41:58,140 +bond O وهذا تصير O- في المرحلة الأولى و لو + +497 +00:41:58,140 --> 00:42:02,520 +سكرنا التفاعل بتصير OH الآن خلوها تهاجم على الـ C + +498 +00:42:02,520 --> 00:42:07,480 +double bond O و تصير الـ O- هذا الجزء الأول + +499 +00:42:07,480 --> 00:42:16,480 +اللي هو Phenyl C و حاملة H و O- اللي هو هذا + +500 +00:42:16,480 --> 00:42:22,870 +الجزء و صار شابّق معه الـ carbon اللي من هنا حاملة H + +501 +00:42:22,870 --> 00:42:31,190 +واحدة و CO2 ethyl و حاملة هنا Ph و حاملة هنا Ph الآن + +502 +00:42:31,190 --> 00:42:37,480 +سهل جدا علينا نفهم سهل جدا علينا نفهم أن هذه الـ O- + +503 +00:42:37,480 --> 00:42:44,340 +مباشرة ممكن تهاجم و تطرد الـ Ph في 3-exo + +504 +00:42:44,340 --> 00:42:50,020 +tetragonal reaction صح ولا لأ؟ ليش 3؟ لأن + +505 +00:42:50,020 --> 00:42:56,200 +الحلقة المتكونة ثلاثية exo لأن الـ Ph طردت + +506 +00:42:56,200 --> 00:43:01,040 +tetragonal لأن الكربون اللي تم عليها التفاعل + +507 +00:43:01,040 --> 00:43:02,380 +تتراجونال + +508 +00:43:04,370 --> 00:43:10,650 +إذا هنا تم تفاعل بـ 3-exo-tetragonal reaction ولا + +509 +00:43:10,650 --> 00:43:17,010 +لأ؟ واضح؟ هنا حضرنا الـ Epoxide فالآن التحضير + +510 +00:43:17,010 --> 00:43:20,430 +عندنا بدأ شوية شوية يمشي للأمام صار في الأول بدي + +511 +00:43:20,430 --> 00:43:24,750 +أعمل خطوة تحضيرية أجهز القطع اللي بدي تعمل الـ + +512 +00:43:24,750 --> 00:43:28,450 +cyclization وبعدين خطوة الـ cyclization الآن احنا + +513 +00:43:28,450 --> 00:43:31,750 +بنقول في الـ heterocyclic chemistry شغلنا بده يشمل + +514 +00:43:31,750 --> 00:43:36,310 +الشغل ثاني موضوعنا الـ cyclization هذا لكن عشان + +515 +00:43:36,310 --> 00:43:40,170 +أحضر هذا الجزء بدي الـ chemistry القديمة هذه old + +516 +00:43:40,170 --> 00:43:45,230 +chemistry هذه كيمياء قديمة المفروض أن الطالب + +517 +00:43:45,230 --> 00:43:52,410 +يتعلمها من الأول الآن لو يا ترى لو يا ترى بدي + +518 +00:43:52,410 --> 00:43:57,150 +واحدة شاطرة من اللي بدأت تستوعب معنا موضوع + +519 +00:43:57,150 --> 00:44:05,060 +الاحتمالات و تفكر معاه، بنتج ثاني لهذا الكفاعة على + +520 +00:44:05,060 --> 00:44:08,000 +الـ C=O لحظة أنا الـ C=O + +521 +00:44:08,000 --> 00:44:13,440 +مخفية تماما مخفية حاطة على جانب ولا إشي ولا + +522 +00:44:13,440 --> 00:44:18,560 +مبينها لكن لو أنا مجرد أن رسمت هذه C=O + +523 +00:44:18,560 --> 00:44:26,420 +أو ethyl وجدت هذا ما المانع أن يكون عندكم هذا + +524 +00:44:26,420 --> 00:44:33,550 +التفكير و substitution ما هو E-ester سيطلع عندي حلقة + +525 +00:44:33,550 --> 00:44:39,270 +رباعية واضح طبعا هو بيعتمد على نتائج التجربة لكن + +526 +00:44:39,270 --> 00:44:45,950 +في كل الأحوال أنتم بدّكم يكون عندكم تفكير دائما + +527 +00:44:45,950 --> 00:44:53,260 +كبير في أكثر من احتمال هذا الاحتمال وارد يعني زي ما + +528 +00:44:53,260 --> 00:44:58,100 +في substitution لـ halogen atom في substitution + +529 +00:44:58,100 --> 00:45:04,300 +من ناحية المبدأ على الـ E-esters الآن بالتجربة و هذا + +530 +00:45:04,300 --> 00:45:08,200 +الـ Darzen reaction أن المفضل الـ substitution على + +531 +00:45:08,200 --> 00:45:12,440 +الكربون اللي حامله الـ halogen بس ما بدّيش الطالب + +532 +00:45:12,440 --> 00:45:18,770 +يكون ناسي أن في عندها احتمالات ثانية و لو يعني من + +533 +00:45:18,770 --> 00:45:24,390 +الناحية النظرية ممكنة و تؤدي إلى نتائج ثانية و هذا + +534 +00:45:24,390 --> 00:45:28,470 +جزء سيبقى ملازم لكم في الـ heterocyclic chemistry + +535 +00:45:28,470 --> 00:45:35,610 +أنكم تفكروا بإيش بأكثر من احتمال ناخذ مثال إضافي + +536 +00:45:35,610 --> 00:45:42,190 +بسيط لو أخذنا هذا المركب و فعلنا مع RNH2 لحظة + +537 +00:45:42,190 --> 00:45:45,370 +عملنا هذا مثال سهل خطوة تحضيرية عملنا + +538 +00:45:45,370 --> 00:45:50,630 +substitution للـ Ph بـ RNH الآن وين الـ nucleophile + +539 +00:45:50,630 --> 00:45:59,050 +الجديد الآن اتسكر على الـ Ph هتعطيني حلقة ثلاثية + +540 +00:45:59,050 --> 00:46:04,850 +تهيأ لي هذا المثال مثال بسيط و سهل + +541 +00:46:10,050 --> 00:46:15,690 +يَلْزَمْني تقريبا كمان دقيقتين تلاتة بعد إذنكم هذا + +542 +00:46:15,690 --> 00:46:19,550 +تحضير كثير مهم اسمه five spinary furan synthesis + +543 +00:46:19,550 --> 00:46:23,270 +هذا بيشتغل على alpha, halo, ketone مع beta, keto, + +544 +00:46:23,330 --> 00:46:28,870 +ester في وجود pyridine لاحظوا معاه بيعتمد على CH2 + +545 +00:46:28,870 --> 00:46:33,230 +اللي هنا activated الـ pyridine بيصحب منها بروتون لما + +546 +00:46:33,230 --> 00:46:37,830 +يصحب بروتون بدوا يهاجم وين؟ على الـ oxygen هذه + +547 +00:46:37,830 --> 00:46:46,130 +خلوها OH بهذا الشكل الآن لو سحبنا كمان بروتون ثاني + +548 +00:46:46,130 --> 00:46:52,470 +من نفس هذه الـ CH و عملنا tautomerism بتصير عندي الـ + +549 +00:46:52,470 --> 00:46:57,630 +O هذه - الـ O هذه - الآن هذه الـ O- + +550 +00:46:57,630 --> 00:47:02,010 +بتسكر على الـ Cl ولا لأ؟ إذا أنا عملت سحب بروتون + +551 +00:47:02,010 --> 00:47:06,770 +مرتين يعني هنا في عندي كم بروتون؟ اتنين أول إشي + +552 +00:47:06,770 --> 00:47:11,810 +سحبت هذا البروتون و عملت الـ bond بعدين سحبت البروتون + +553 +00:47:11,810 --> 00:47:15,090 +التاني صار عنده هنا - هذا الـ - لو عملت له + +554 +00:47:15,090 --> 00:47:21,950 +tautomerism يعني حركته هنا و خلت هذه O- و خلتها + +555 +00:47:21,950 --> 00:47:27,210 +تسكر على الـ Cl شو طلع عندي substituted furan هذه + +556 +00:47:27,210 --> 00:47:29,490 +طريقة معروفة بنسميها احنا أيش + +557 +00:47:33,830 --> 00:47:36,990 +اعتمدت على أني سحبت كم بروتون من هذا الموقع + +558 +00:47:36,990 --> 00:47:40,750 +المنشط الـ activated اتنين المرة الأولى و المرة + +559 +00:47:40,750 --> 00:47:43,410 +الثانية بعد ما اتكونت هذه الـ intermediates سحبت + +560 +00:47:43,410 --> 00:47:50,670 +هنا كمان بروتون و عملت الـ enolate anion هذا enolate + +561 +00:47:50,670 --> 00:47:55,770 +anion فحضرنا + +562 +00:47:55,770 --> 00:48:01,720 +الحقيقة في عندكم أكثر من مثال إضافي يعني + +563 +00:48:01,720 --> 00:48:06,260 +هذه مثلا CH2 activated لو سحبت منها بروتون صارت + +564 +00:48:06,260 --> 00:48:13,860 +minus هذهجم على الـ Cl شو تترد؟ الـ Cl الآن عندي هنا + +565 +00:48:13,860 --> 00:48:19,380 +كمان مثال هي CH2 activated لحظة هذا المثال هو نفس + +566 +00:48:19,380 --> 00:48:24,410 +هذا لكن أنا أعدت رسمه عشان أفرجيكم كيف لما نرسمه + +567 +00:48:24,410 --> 00:48:30,130 +بطريقة سهلة الآن بهذا الشكل مش واضح لكم إنه أنا + +568 +00:48:30,130 --> 00:48:32,970 +بدي أكوّن ربما الـ nucleophile هنا و بدي أجيبه + +569 +00:48:32,970 --> 00:48:37,010 +يهاجم هنا هو نفس المثال لكن أنا أعدت رسمه بطريقة + +570 +00:48:37,010 --> 00:48:44,190 +سهلة هي الـ minus اللي بيصير هنا هتسهل هذا نفس هذا + +571 +00:48:44,940 --> 00:48:50,600 +لاحظوا كيف طريقة الرسم بتساعد + +572 +00:48:50,600 --> 00:48:55,560 +على الحل هذا أيضا نفس المثال، هذه الأنيون بدها + +573 +00:48:55,560 --> 00:49:01,500 +تهاجم على الكاربون، شو بدها تطرد؟ الـ Br كل هذه + +574 +00:49:01,500 --> 00:49:06,140 +الطرق substitution reactions ولا لأ؟ وتؤدي إلى + +575 +00:49:06,140 --> 00:49:10,540 +حلقات بالأشكال اللي احنا شوفناها وبهيك بننهي موضوع + +576 +00:49:10,540 --> 00:49:13,820 +الـ substitution reaction المرة الجاية بدو يكون إن + +577 +00:49:13,820 --> 00:49:18,440 +شاء الله موضوعنا على الـ reactions at double bonds + +578 +00:49:18,440 --> 00:49:21,020 +اللي هي addition reactions diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/XhLJ7pC0Mjs_postprocess.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/XhLJ7pC0Mjs_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..a5c9b7b70c3f467c9f85b1ade0756a736b76c714 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/XhLJ7pC0Mjs_postprocess.srt @@ -0,0 +1,2312 @@ +1 +00:00:20,670 --> 00:00:25,450 +بسم الله الرحمن الرحيم بنبدأ الآن بالفصل التاني في + +2 +00:00:25,450 --> 00:00:29,630 +مادة ال heterocyclic chemistry طبعا في هذا الفصل + +3 +00:00:29,630 --> 00:00:35,000 +بدنا ناخد تحضير ال heterocyclic ringsيمكن سابقا + +4 +00:00:35,000 --> 00:00:39,740 +حكينالكوا ان الناس يعني مناهج في هذا الموضوع بعض + +5 +00:00:39,740 --> 00:00:43,180 +الناس بفضله انهم ييجوا على الحلقات المعروفة و + +6 +00:00:43,180 --> 00:00:46,980 +يصيروا يتكلموا عنها حلقة حلقة يعني ييجوا يقولوا + +7 +00:00:46,980 --> 00:00:50,540 +chemistry of Bayerol و يشرحوا كيف بنحضر ال Bayerol + +8 +00:00:50,540 --> 00:00:54,740 +و تفاعلاته chemistry of furan chemistry of Berlin + +9 +00:00:54,740 --> 00:01:00,820 +و هكذافي توجه تاني للتعامل مع الموضوع اننا نقول + +10 +00:01:00,820 --> 00:01:05,800 +كيف الطرق العامة لتحضير ال heterocyclic rings in + +11 +00:01:05,800 --> 00:01:10,600 +general يعني اخد طريقة هذه الطريقة ممكن من خلالها + +12 +00:01:10,600 --> 00:01:14,840 +ان احضر حلقة ثلاثية او ربعية او خمسية او سادسية + +13 +00:01:14,840 --> 00:01:20,060 +الحلقة ممكن تكون فيوران بيرول فيوفين وهذا التوجه + +14 +00:01:20,060 --> 00:01:23,900 +اللي احنا هنمشي فيه يعني هناخدgeneral methods for + +15 +00:01:23,900 --> 00:01:27,400 +preparation of heterocyclic compounds هذا هيكون + +16 +00:01:27,400 --> 00:01:31,980 +يعني ياخد مننا جزء كبير من هذا المساق ال general + +17 +00:01:31,980 --> 00:01:35,920 +methods for heterocyclic synthesis وبعد هيك ممكن + +18 +00:01:35,920 --> 00:01:40,800 +نتطرق لبعض الأمثلة المحددة ونتأكد من مجمل الطرق + +19 +00:01:40,800 --> 00:01:43,840 +اللي تحضر في هذه المراكبات المشهورة + +20 +00:01:46,050 --> 00:01:52,290 +كمقدمة عامة لما انا بدي احكي عن تحضير حلقة سواء + +21 +00:01:52,290 --> 00:01:57,530 +كنت بحكي عن تحضير حلقة كربون او حتى عن تحضير + +22 +00:01:57,530 --> 00:02:01,650 +heterocycle crane ممكن اتخيل ان انا ممكن اعمل + +23 +00:02:01,650 --> 00:02:08,070 +التحضير بعدة طرقالطريقة الأولى بنسميها cyclization + +24 +00:02:08,070 --> 00:02:12,730 +reaction اللى بنقصده ب cyclization reaction أنه + +25 +00:02:12,730 --> 00:02:17,990 +أنا في خطوة الإغلاق يكون عندى طرفين فقط لازمني + +26 +00:02:17,990 --> 00:02:21,370 +أسكر رابطة بتصير حلقة لاحظوا بهذا الشكل هاي + +27 +00:02:21,370 --> 00:02:26,250 +الطرفينسكرت الرابطة الأخيرة صارت حلقة هذا التفاعل + +28 +00:02:26,250 --> 00:02:29,670 +بسمي cycleization reaction يعني ممكن اتخيل ان هنا + +29 +00:02:29,670 --> 00:02:33,030 +في عندي ذرات في عندي مثلا nucleophile و + +30 +00:02:33,030 --> 00:02:36,050 +electrophile او free radical و free radical بدي + +31 +00:02:36,050 --> 00:02:38,530 +هذا ال nucleophile يسكر عن ال electrophile عم + +32 +00:02:38,530 --> 00:02:43,680 +الرابطةصارت حلقة هذا ايش بنقول عنه؟ cycleization + +33 +00:02:43,680 --> 00:02:47,520 +reaction و هتلاحظوا ان ال cycleization reaction هو + +34 +00:02:47,520 --> 00:02:51,760 +one bond formation reaction يعني في لحظة الإغلاق + +35 +00:02:51,760 --> 00:02:56,860 +انا بعمل رابطة الان هذا مابمنعش ان انا حتى اصل + +36 +00:02:56,860 --> 00:03:00,740 +لهذه الذرات كلها مرتبة ان اكون اعمل التفاعلين + +37 +00:03:00,740 --> 00:03:04,120 +تلاتة من الكيميا العاديةلحد ما شبكت هدول لكن انا + +38 +00:03:04,120 --> 00:03:09,120 +بتكلم عن لحظة اغلاق الحلقة بهذا الشكل كام رابطة + +39 +00:03:09,120 --> 00:03:13,900 +بعمل؟ رابطة واحدة صار في عندى حلقة هذا ال + +40 +00:03:13,900 --> 00:03:20,340 +cyclization reactionالنوع التاني Cycloaddition + +41 +00:03:20,340 --> 00:03:26,100 +reaction أنه أنا بجيب قطعتين بجرب هدول القطعتين + +42 +00:03:26,100 --> 00:03:30,500 +على بعض و في لحظة الإغلاق بعمل رابطتين مش رابطة + +43 +00:03:30,500 --> 00:03:36,440 +واحدة هاي قطعتين بجربهم في لحظة الإغلاق كام رابطة + +44 +00:03:36,440 --> 00:03:41,640 +بعمل؟ رابطتين هذا اللي أنا بسميه Cycloaddition + +45 +00:03:41,640 --> 00:03:44,960 +reactioncycloaddition reaction يعني لحظة هي قطعة + +46 +00:03:44,960 --> 00:03:49,580 +وهي قطعة ربما مثلا هذه ذرتين ربما هذه تلاتة او + +47 +00:03:49,580 --> 00:03:54,620 +اربعة بجربهم مع بعض في لحظة الإغلاق كام رابطة بعمل + +48 +00:03:54,620 --> 00:03:58,840 +رابطتين هذا بسميه Cycloaddition reaction ومنه + +49 +00:03:58,840 --> 00:04:02,780 +أنواع كتيرة منه أنواع كتيرة يعني و بحاجة إلى تفصيل + +50 +00:04:02,780 --> 00:04:09,350 +كبيرالشغلة التالتة بنسميها ring transformation + +51 +00:04:09,350 --> 00:04:14,330 +reaction يعني انه بيكون في عندى حلقة هذه الحلقة + +52 +00:04:14,330 --> 00:04:21,150 +بخليها تفتح و تسكر بشكل جديدهذه الحلقة بتعمل ring + +53 +00:04:21,150 --> 00:04:25,310 +opening و بعدين ring closure يعني في ال ring + +54 +00:04:25,310 --> 00:04:30,630 +transformation في عندى حلقة هالحلقة هذه لازم تفتح + +55 +00:04:30,630 --> 00:04:33,730 +و تسكر بوضع جديد يعني لو انا بدي افرجيكوا ياها + +56 +00:04:33,730 --> 00:04:39,650 +بمثال لو افترضت ان كل هذا جزء هي عندى حلقة واضح؟ و + +57 +00:04:39,650 --> 00:04:42,630 +خليني افترض هنا في عندى substituent الآن هذه + +58 +00:04:42,630 --> 00:04:47,980 +الحلقة فتحت سكرت من هناصار عندى حلقة جديدة ولا لأ + +59 +00:04:47,980 --> 00:04:51,860 +صار عندى بالتأكيد حلقة جديدة الان في ال ring + +60 +00:04:51,860 --> 00:04:56,120 +transformation الحلقة لما بتفتح و بتسكر على حلقة + +61 +00:04:56,120 --> 00:05:00,120 +جديدة ممكن من ناحية المبدأ ان حلقة خماسية تفتح و + +62 +00:05:00,120 --> 00:05:04,160 +تسكر على حلقة خماسية يعني يظل عندى نفس حجم الحلقة + +63 +00:05:04,860 --> 00:05:09,400 +ممكن يصير عندى شيء بسميه ring contraction يعني + +64 +00:05:09,400 --> 00:05:14,340 +الحلقة الخمسية تصير مثلا ربعية او ثلاثية الحلقة + +65 +00:05:14,340 --> 00:05:20,400 +الخمسية لو كبرت بيصير اسمه ring enlargement او + +66 +00:05:20,400 --> 00:05:27,140 +ring expansionالخماسية تصير سداسية أو سباعية الآن + +67 +00:05:27,140 --> 00:05:32,280 +في أمثلة كتير وحنحاول نستعرض بعض الأمثلة على ring + +68 +00:05:32,280 --> 00:05:35,700 +transformation على نفس الحلقة أو لحلقة أصغر أو + +69 +00:05:35,700 --> 00:05:41,160 +لحلقة أكبر لكن لاحظوا معي أن غالبا ال ring + +70 +00:05:41,160 --> 00:05:46,770 +transformations هدولة مابيكونوش شيء منهجييعني + +71 +00:05:46,770 --> 00:05:52,550 +الإنسان بيدرسه لغرض تحضير حلقة معينة هم في الغالب + +72 +00:05:52,550 --> 00:05:56,390 +بيصيروا مع الباحثين المصادفة يعني بيكونوا بيعملوا + +73 +00:05:56,390 --> 00:06:01,450 +تفاعل معين بتفاجأة أنه الحلقة فتحت و تسكت بشكل + +74 +00:06:01,450 --> 00:06:07,070 +جديد ولذلك مرات كتيرة بنلاقيهم موجودين حتى تحت اسم + +75 +00:06:07,070 --> 00:06:12,860 +rearrangementإن الجزء فتح و أقعد ترتيب نفسه بشكل + +76 +00:06:12,860 --> 00:06:18,920 +جديد و غالبا هدولة بيصيروا مع الباحثين بشكل مفاجئ + +77 +00:06:18,920 --> 00:06:23,320 +يعني هو مابيكونش شغال و فكروا أن الحلقة هذه + +78 +00:06:23,320 --> 00:06:26,580 +الخمسية بدأ تفتح منها و تتسكر جديد هو بيعمل تفاعل + +79 +00:06:26,580 --> 00:06:31,020 +على طرف ما ربما من الحلقة بتفاجأة أن الحلقة فتحت و + +80 +00:06:31,020 --> 00:06:34,860 +تتسكرت بشكل جديد سواء كحلقة أكبر أو بساوي في الحجم + +81 +00:06:34,860 --> 00:06:40,290 +أو أصغروإن شاء الله أنه هستعرض لكم يعني بعض + +82 +00:06:40,290 --> 00:06:45,250 +الأمثلة في هذا الموضوع حتى تحسوا في هذا الأمر يعني + +83 +00:06:45,250 --> 00:06:50,210 +إذا واجهكم في المستقبل وبالتأكيد ممكن وجدها أنه + +84 +00:06:50,210 --> 00:06:52,810 +نعطيكوا homework أنه نقول كل واحدة تنزل على + +85 +00:06:52,810 --> 00:06:56,710 +المجلات مجرد ما تكتب bring transformation عن البني + +86 +00:06:56,710 --> 00:07:01,430 +آدم اللي بيصير معه شغل زيك في البحث هتلاحظوا أنه + +87 +00:07:01,430 --> 00:07:05,550 +عنوان العلوان تبعهRing Transformation of + +88 +00:07:05,550 --> 00:07:06,990 +Heterocyclic Compounds + +89 +00:07:12,720 --> 00:07:16,700 +فلو كتبتوا في أي search كلمة ring transformation + +90 +00:07:16,700 --> 00:07:21,820 +هيطلع عندكم آلاف المقالات اللى ممكن توضحلكوا هذا + +91 +00:07:21,820 --> 00:07:25,440 +الكلام احنا ان شاء الله لما نمشي بهذا الترتيب نشرح + +92 +00:07:25,440 --> 00:07:27,960 +ال cycleization reactions بعدين ال cycle addition + +93 +00:07:27,960 --> 00:07:31,740 +reactions بعدين ring transformations بنستعرض بعض + +94 +00:07:31,740 --> 00:07:37,080 +الأمثلة وواجهتها بنطلب منكم انكم اجيبولنا انتوا من + +95 +00:07:37,080 --> 00:07:40,740 +خلال اجتهادكم وانزولكوا على المجلات ايضا امثلة + +96 +00:07:40,740 --> 00:07:45,580 +اضافية في موضوعالـ Ring Transformation نقطة + +97 +00:07:45,580 --> 00:07:50,000 +البداية عندنا هتكون إيش؟ Cyclization Reactions + +98 +00:07:50,000 --> 00:07:56,280 +تفاعلات الإغلاق الحلقي الآن في عندنا عالم اسمه + +99 +00:07:56,280 --> 00:08:01,820 +Baldwin حط عدة قواعد لعملية الإغلاق يعني كيف نصنف + +100 +00:08:01,820 --> 00:08:05,580 +عملية الإغلاق ومش زمان هذا الكلام يعني تقريبا في + +101 +00:08:05,580 --> 00:08:11,340 +ال 76 وصارت هذه مشهورة قواعد الإغلاق Baldwin's + +102 +00:08:11,340 --> 00:08:15,090 +Ruleأو rules و مرات لما بيكون فيه احتمالين و الله + +103 +00:08:15,090 --> 00:08:18,470 +ممكن يسكر بهذا الشكل او بهذا الشكل الناس اللي + +104 +00:08:18,470 --> 00:08:21,970 +بيدرسوا الموضوع بتاع معون كبير بيقولوا و الله هذا + +105 +00:08:21,970 --> 00:08:25,450 +الإغلاق أفضل من هذا الإغلاق يعني اتخيلوا هاي عندي + +106 +00:08:25,450 --> 00:08:28,090 +زي هيك مثلا هل الإغلاق بهذا الشكل و لا بهذا الشكل + +107 +00:08:28,090 --> 00:08:32,030 +و لا بهذا الشكل في عندي أكثر من إيش cyclization أو + +108 +00:08:32,030 --> 00:08:36,010 +possible cyclization ف Baldwin rules قواعد بالدوين + +109 +00:08:36,010 --> 00:08:40,390 +بتوضح له كيف ممكن يكون هذا الإغلاق و إيش بنسمي + +110 +00:08:40,390 --> 00:08:45,860 +عملية الإغلاقالان بالدوين لما اتكلم عن عملية الـ + +111 +00:08:45,860 --> 00:08:50,640 +cyclization جال في عنده طرفين طرف بده يسكر على + +112 +00:08:50,640 --> 00:08:55,220 +الطرف التاني واضح طرف بده يسكر على الطرف التاني + +113 +00:08:55,220 --> 00:09:00,540 +الان ممكن نفترض الحالة الأولى ان هذا الطرف مثلا + +114 +00:09:00,540 --> 00:09:05,200 +نيوكليوفين بده يسكر على الطرف اللي هنا نفترض هذا + +115 +00:09:05,200 --> 00:09:11,950 +CCLكنا اتعلمنا ان النيكليوفايل بيهاجم على الكربون + +116 +00:09:11,950 --> 00:09:18,330 +وبطلد ال CL إذا هنا substitution reaction واضح طيب + +117 +00:09:18,330 --> 00:09:23,870 +لما بالدوين بيسمي هذا الكلام كيف بيسميه أول اشي + +118 +00:09:23,870 --> 00:09:28,470 +بيكتب هنا رقم هو رقم الحلقة المتكونة طبعا هنا احنا + +119 +00:09:28,470 --> 00:09:31,490 +مش محددينها يعني لو افترضنا ان الحلقة اللي اتكونت + +120 +00:09:31,490 --> 00:09:37,920 +خماسية شو بده يكتب؟الان بعد هك بيجي بتطلع على + +121 +00:09:37,920 --> 00:09:42,520 +الذرة اللى تم عليها الهجوم هذه الرابطة هل تحركت + +122 +00:09:42,520 --> 00:09:48,280 +للخارج حتى لو كسرت ولا تحركت للداخل هنا تحركت + +123 +00:09:48,280 --> 00:09:54,190 +للخارج طلعت برا فبيكتب EXOبعدين بيجي بيسأل هذه + +124 +00:09:54,190 --> 00:09:58,150 +الذرع اللى تم عليها الإغلاق الـ geometry حواليها + +125 +00:09:58,150 --> 00:10:02,430 +tetragonal يعني ربعية تتراهيدرال ولا triangular + +126 +00:10:02,430 --> 00:10:06,070 +ثلاثية لترياجونال الفيوم ال double bonds ولا + +127 +00:10:06,070 --> 00:10:11,120 +diagonalاللي فيهم ال triple bonds اللي ليار اذا + +128 +00:10:11,120 --> 00:10:16,720 +الهجوم يمكن ان يكون على carbon رباعية يعني باربع + +129 +00:10:16,720 --> 00:10:20,020 +روابط وحدية او في عند double bond وبالتالي ال + +130 +00:10:20,020 --> 00:10:25,100 +geometry بتكون triangular او على carbon فيها + +131 +00:10:25,100 --> 00:10:29,220 +triple bond ال geometry بتكون linear او diagonal + +132 +00:10:29,220 --> 00:10:34,560 +فبهذه الحالةإذا كانت حركة الخارج رابطة للخارج اقول + +133 +00:10:34,560 --> 00:10:40,100 +اكزو ترياجونال اكزو دياجونال لاحظوا معي ان لما + +134 +00:10:40,100 --> 00:10:46,160 +تكون عندي رابطة احديةالرابطة الأحدية بتكسر تماما و + +135 +00:10:46,160 --> 00:10:52,100 +بتطلع كل ال Y لكن لو كان عندي رابطة ثنائية زي ما + +136 +00:10:52,100 --> 00:10:56,780 +تكون هذه C ضب البند O بتنكسر بس رابطة واحدة منها + +137 +00:10:56,780 --> 00:11:01,720 +بتصير O minus و بعدين بتصير OH لو كانت رابطة + +138 +00:11:01,720 --> 00:11:06,360 +ثلاثية بس بتنكسر رابطة واحدة بيظل كام رابطة عيدي؟ + +139 +00:11:06,360 --> 00:11:12,700 +تنتينالان الامر الحقيقي السهل في حالة الهجوم اللى + +140 +00:11:12,700 --> 00:11:18,360 +موجود عندنا هنا هو أسهل الشيء التتراجونال لكن لما + +141 +00:11:18,360 --> 00:11:22,020 +بيكون عندى رابطة ثنائية هنلاحظ أنه في عندنا + +142 +00:11:22,020 --> 00:11:26,920 +احتمالين هل يا تورا حسب طبيعة الرابطة الهجوم بده + +143 +00:11:26,920 --> 00:11:31,260 +يتم على ال X و الحركة للخارج أو ممكن الهجوم يتم + +144 +00:11:31,260 --> 00:11:35,890 +على ال Y و زوج الإلكترونات يتحرك في الداخلهذا + +145 +00:11:35,890 --> 00:11:40,390 +الكلام بالتأكيد هيعطيني حجمين مختلفين من الحلقات + +146 +00:11:40,390 --> 00:11:44,150 +يعني لما الهجوم هنا يتم على ال X إذا افترضنا أن + +147 +00:11:44,150 --> 00:11:48,370 +هذه الحلقة خمسية لو الهجوم هنا تم على ال Y شو + +148 +00:11:48,370 --> 00:11:53,890 +الحلقة الحادثية؟ سداسية كذلك الحال هنا ممكن يكون + +149 +00:11:53,890 --> 00:11:57,230 +الهجوم هيك على ال X نفترض حلقة خمسية لو تم على ال + +150 +00:11:57,230 --> 00:12:03,220 +Y حلقة سداسية وبالتأكيد أنا هنقولIndo + +151 +00:12:03,220 --> 00:12:08,550 +Indocyclizationفانميز .. إيش اللي بنقصده بال + +152 +00:12:08,550 --> 00:12:12,030 +Exocyclization و إيش اللي بنقصده بال + +153 +00:12:12,030 --> 00:12:15,830 +Endocyclization في عندي Exocyclization و + +154 +00:12:15,830 --> 00:12:20,710 +Endocyclization الآن هل يا ترى هيمشي عند أكتر Exo + +155 +00:12:20,710 --> 00:12:23,810 +ولا Endocyclization المفروض أن أنتوا بتقدروا + +156 +00:12:23,810 --> 00:12:28,510 +تجاوبوا على هذا الكلام يعني لو أنا بستعمل carbon + +157 +00:12:28,510 --> 00:12:32,630 +double bond carbon تقريبا الطرفين في ال polarity + +158 +00:12:32,630 --> 00:12:38,850 +carbon و carbonبنكون احنا حقيقة مش عارفين هنشوف + +159 +00:12:38,850 --> 00:12:44,890 +مين في هال two carbons more electrophilic ممكن + +160 +00:12:44,890 --> 00:12:48,650 +الهجوم يطم عليها و بنفس الوقت برضه بنطلع على حجم + +161 +00:12:48,650 --> 00:12:51,950 +الحلقة تنسوش ان انتوا أخدتوا أنه أنسب أحجام + +162 +00:12:51,950 --> 00:12:56,070 +الحلقات الخمسية والستاسية لأن الزاوية فيهم 128 + +163 +00:12:56,070 --> 00:13:02,900 +مقارنة بالربعية زاوية التسعين بالثلاثيةالستين + +164 +00:13:02,900 --> 00:13:07,360 +واضحة الفكرة فبنان ع ذلك لو هان عندي carbon و + +165 +00:13:07,360 --> 00:13:12,560 +carbon التفكير عندي بده يكون حذر انه فعلا بده افكر + +166 +00:13:12,560 --> 00:13:16,660 +هالياطورة بده يتم عندي exocyclization ولا + +167 +00:13:16,660 --> 00:13:21,060 +endocyclization لكن مثلا من خبرتكم لو كانت هذه C + +168 +00:13:21,060 --> 00:13:25,600 +double bond Oجدّاش أخدتوا addition reactions على + +169 +00:13:25,600 --> 00:13:29,320 +الـ C double bond O من ال more electrophilic + +170 +00:13:29,320 --> 00:13:34,960 +carbon اتم ال carbon ولا ال oxygen ال carbon و + +171 +00:13:34,960 --> 00:13:40,080 +لذلك كان دايما الهجوم على ال carbon واضح فنفس + +172 +00:13:40,080 --> 00:13:45,020 +الكلام هيتكرر لو كانت C triple bond C هتفكروا كتير + +173 +00:13:45,020 --> 00:13:47,920 +هل ال cyclization على هذا الموقع او هذا الموقع لكن + +174 +00:13:47,920 --> 00:13:53,370 +لو كانت C triple bond Nأنا الآن بقولكوا 99 وكسر + +175 +00:13:53,370 --> 00:13:57,570 +كمان في المية على الـC الهجوم مش على الـN، واضح؟ + +176 +00:13:57,570 --> 00:14:04,630 +فأكتر شيء هيمر معنىاللي هو ال Indocyclizations في + +177 +00:14:04,630 --> 00:14:10,730 +C triple bond C و في C double bond C لكن مثلا ال C + +178 +00:14:10,730 --> 00:14:15,650 +double bond O و C triple bond N هدولة غالبا بيصير + +179 +00:14:15,650 --> 00:14:19,090 +الهجوم فيهم على ال carbon و بيكون عنده + +180 +00:14:19,090 --> 00:14:24,150 +exocyclization طبعا الأمثلة كتيرة احنا ما نستعجلش + +181 +00:14:24,150 --> 00:14:30,190 +و بنشوف الأمثلة في حينه طبعا هذا الكلام بيوضح لنا + +182 +00:14:31,120 --> 00:14:34,940 +إنه كل ال Baldwin rules كانت عبارة عن رقم بوضع حجم + +183 +00:14:34,940 --> 00:14:39,260 +الحلقة كانت عبارة عن كلمة Exoendo اللي وضحنا إيش + +184 +00:14:39,260 --> 00:14:43,240 +معناها وكانت عبارة عن نوع الذرع اللي بتيم عليها + +185 +00:14:43,240 --> 00:14:46,460 +الهجوم Tragonal و Triagonal و Diagonal إذا ال + +186 +00:14:46,460 --> 00:14:50,300 +Baldwin rules لما بتصنف عملية Cyclization كام رمز + +187 +00:14:50,300 --> 00:14:56,440 +هتعطيلي تلاتة حجم الحلقة و Exoendo و نوع الذرع + +188 +00:14:56,440 --> 00:15:02,200 +اللي بتيم عليها الهجوملو بدى مثال لو افترضت مثلا + +189 +00:15:02,200 --> 00:15:06,200 +أخدنا هذا المثال الآن و قولنا هى ال oxygen هذى + +190 +00:15:06,200 --> 00:15:10,980 +عبارة عن ال nucleophile و هى عندى C double bond O + +191 +00:15:10,980 --> 00:15:14,820 +وين هيتم الهجوم على ال C و لا على ال O؟ على ال C + +192 +00:15:14,820 --> 00:15:22,800 +بهذا الشكل إذا كيف هتتحرك هذى؟ O و تصير O-H تهيألي + +193 +00:15:22,800 --> 00:15:26,920 +هذه الشغل عارفين addition to carbon double bond O + +194 +00:15:26,920 --> 00:15:33,030 +in aldehydesوهذا هو الناتج لأنه لما بدأ أصنف هذا + +195 +00:15:33,030 --> 00:15:38,730 +ال cycleization شو بدأ أسميه الحلقة المتكونة اذا + +196 +00:15:38,730 --> 00:15:47,450 +five الحركة اكزو هنا الجيومتري ترياجونال بس اذا في + +197 +00:15:47,450 --> 00:15:51,130 +ضاب البندر ترياجونال اذا هذا ال cycleization five + +198 +00:15:54,360 --> 00:15:59,380 +واضح؟ هذا الـ cyclization five exo-triangular الان + +199 +00:15:59,380 --> 00:16:05,100 +لو شوفنا مثال تاني المثال التاني في OH و في carbon + +200 +00:16:05,100 --> 00:16:09,840 +ال triple bond carbon لاحظوا هذا المثال بيغلب ليش؟ + +201 +00:16:09,840 --> 00:16:13,140 +لأن ممكن ال cyclization يتمهان و في هذا الحالة + +202 +00:16:13,140 --> 00:16:18,620 +الحلقة خماسية و ممكن ال cyclization يتمهان و في + +203 +00:16:18,620 --> 00:16:23,760 +هذا الحلقة سداسية هذا بدنا نقول الكيميا علم تجريبي + +204 +00:16:25,210 --> 00:16:29,450 +لأن السنة بتجربة أي شيء بتقوله ليش؟ لأن الخماسي + +205 +00:16:29,450 --> 00:16:34,450 +والسوداسي التنتين يعني من أفضل الحلقات في التكوين + +206 +00:16:34,450 --> 00:16:39,270 +فالإنسان قبل ما يعمل التفاعل بيكون مش عارف حقيقة + +207 +00:16:39,270 --> 00:16:43,130 +وين تم التفاعل، الآن عملوا التفاعل، فصلوا الناتج، + +208 +00:16:43,130 --> 00:16:50,290 +لاحظوا أن هذا ال cycleization اللي تم هذا أي + +209 +00:16:50,290 --> 00:16:56,320 +cycleization؟ ال Ex ولا ال Indo؟الاندو لاحظوا ال + +210 +00:16:56,320 --> 00:16:59,460 +double bond هنا كان في عندى اي اتش تطلع هذه ال + +211 +00:16:59,460 --> 00:17:04,220 +carbon شايفينها هذه ال carbon اللي هنا بتاعة ال + +212 +00:17:04,220 --> 00:17:09,680 +triple bond كان عليها اي اتش لأ اطلاقا الان تمت + +213 +00:17:09,680 --> 00:17:18,360 +الحركة للداخل صارت C minus وال C minus صارت C Hإذا + +214 +00:17:18,360 --> 00:17:24,140 +إيش لوح الـ cyclization هنا Indow ولا Exo؟ Indow + +215 +00:17:24,140 --> 00:17:28,220 +الآن ال carbon اللي تم عليها ال cyclization اللي + +216 +00:17:28,220 --> 00:17:32,460 +هي ال carbon التانية تبعت ال triple bond طالما + +217 +00:17:32,460 --> 00:17:37,860 +triple bond إذا diagonal جيومتر إلها ولذلك هذا ال + +218 +00:17:37,860 --> 00:17:44,590 +cyclization بنسميه six Indow diagonal6 اندو + +219 +00:17:44,590 --> 00:17:48,950 +دياجونال 6 لأن الحلقة السوداسية اندو لأن الحركة + +220 +00:17:48,950 --> 00:17:52,530 +للداخل يعني تم الهجوم على الذرة الخارجية وتكوين + +221 +00:17:52,530 --> 00:17:59,010 +الحلقة الأكبر يعني دائما كلمة exo تعني تكوين + +222 +00:17:59,010 --> 00:18:05,690 +الحلقة الأصغر وكلمة endo تعني تكوين الحلقة الأكبر + +223 +00:18:05,690 --> 00:18:13,840 +يعني لو أجينا أعطناكم زي هيك وقلنا لكم اعملولناالـ + +224 +00:18:13,840 --> 00:18:23,460 +five اندو دياجونال اكتبوا الناتج five + +225 +00:18:23,460 --> 00:18:28,820 +exo اكتبوا + +226 +00:18:28,820 --> 00:18:34,680 +ال five exo diagonal product وقتها بدكم تقولوا ان + +227 +00:18:34,680 --> 00:18:41,570 +هذه ال oxygen هاجمت هنا ان هذهتتحملت على ال carbon + +228 +00:18:41,570 --> 00:18:48,990 +اللي هنا و نكتب الناتج C + +229 +00:18:48,990 --> 00:18:55,930 +double bond O C واحدة و هنا ال oxygen الهجوم تمها + +230 +00:18:55,930 --> 00:19:02,110 +الانهاد حضل C + +231 +00:19:02,110 --> 00:19:08,850 +double bond A و H هذا زوج الألكترونات اللي كانت + +232 +00:19:08,850 --> 00:19:14,130 +الرابطةهذا اللى احنا عاملينه هو اللى كان الرابط + +233 +00:19:14,130 --> 00:19:20,130 +اللى اتحركت بهذا الشكل هى ال five exo diagonal و + +234 +00:19:20,130 --> 00:19:26,450 +هى ال six endo diagonal productواضح؟ الآن اللي + +235 +00:19:26,450 --> 00:19:30,270 +بيكون بيعمل تجربة أو بيكون بيعمل مخطط بحث و بيقول + +236 +00:19:30,270 --> 00:19:34,910 +انا بدي اعمل هذا التفاعل الاصل انه يقول we expect + +237 +00:19:34,910 --> 00:19:38,650 +two products to be formed which one will be formed + +238 +00:19:38,650 --> 00:19:43,750 +this depends on the experiment هذا الكلام في نهاية + +239 +00:19:43,750 --> 00:19:47,870 +الكيميا علم تجريبى يتكون هذا المركب و لهذا المركب + +240 +00:19:47,870 --> 00:19:55,580 +الله أعلمو هنلاحظ أثناء دراستنا أنه كثير بتكون + +241 +00:19:55,580 --> 00:19:59,500 +ضالكوا وعييلة الاحتمالات المختلفة للتفاعلات هي + +242 +00:19:59,500 --> 00:20:04,580 +الكيميا بجزء كبير منها فكرة isomers و فكرة + +243 +00:20:04,580 --> 00:20:08,860 +احتمالات مختلفة للتفاعلات مرت معاكم في مناطق كثير + +244 +00:20:08,860 --> 00:20:12,460 +و هتظل تتكرر معنا أثناء دراستنا في ال heterocyclic + +245 +00:20:12,460 --> 00:20:22,580 +chemistry هاي مثلا في عندنا مثال جديدممكن نفكر فيه + +246 +00:20:22,580 --> 00:20:27,220 +.. ممكن نفكر فيه هذا المثال فيه Oxygen خلينا نقول + +247 +00:20:27,220 --> 00:20:32,260 +ال Oxygen نيوكليوفاي الأن لو سألنا يا تورا كام + +248 +00:20:32,260 --> 00:20:39,300 +احتمال عندي لل Cyclization هنا الاصل أن نقول تلاتة + +249 +00:20:39,300 --> 00:20:43,500 +حتى لو هو ناقش احتمالين خلينا نشوف الاحتمالات اللي + +250 +00:20:43,500 --> 00:20:48,000 +نقشها هو ناقش احتمال ان هذا ال Oxygen اتهاجم على + +251 +00:20:48,000 --> 00:20:55,540 +هذا ال Carbonوهنا بدو يصير Indo وهنا تجيني H كان H + +252 +00:20:55,540 --> 00:21:01,580 +موجودة هي ال double bond واضح؟ إذا هجوم ال oxygen + +253 +00:21:01,580 --> 00:21:05,480 +على هذا ال carbon هو أحد الاحتمالات ولا لأ؟ شو + +254 +00:21:05,480 --> 00:21:11,920 +سمناه؟ five Indo والهجوم على ال Triagonal هنا لأن + +255 +00:21:11,920 --> 00:21:21,610 +هاي رابطتين وهنا فيه H وH هاي ال Triagonalالان هو + +256 +00:21:21,610 --> 00:21:28,650 +رسم الجزئ مجرد انه رسمه بطريق تاني قال ما المانع و + +257 +00:21:28,650 --> 00:21:32,210 +ممكن نتخيل ان هادى كنا رسمينها لأعلى و هنا ال + +258 +00:21:32,210 --> 00:21:35,410 +oxygen ما المانع ان هادى ال oxygen اتهاجم على ال + +259 +00:21:35,410 --> 00:21:40,630 +carbon تبعت ال E star و في ال E stars التفاعل + +260 +00:21:40,630 --> 00:21:46,490 +الأساسي في الأحمض و مشتقاتها ايش سمناها؟هذه الكلمة + +261 +00:21:46,490 --> 00:21:51,050 +يعني ممنوع انكوا تنسوها بحياتكم لما جسمنا ال + +262 +00:21:51,050 --> 00:21:55,050 +carbonyl compounds لنوعين جلنا ال aldehydes و ال + +263 +00:21:55,050 --> 00:21:59,550 +ketones دايما مع بعض في شبطر الأحماض و مشتقاتها + +264 +00:21:59,550 --> 00:22:05,450 +دايما مع بعض في شبطر، ليش؟لأن ال aldehydes و ال + +265 +00:22:05,450 --> 00:22:10,050 +ketones يميزهم شيء مشترك واحد و تفاعل الإضافة + +266 +00:22:10,050 --> 00:22:15,750 +الأحماض و مشتقاتها يميزها شيء مشترك واحد و تفاعل + +267 +00:22:15,750 --> 00:22:23,590 +الإبدالمتذكرين؟ ولذلك لما كان مر عليكم على سبيل + +268 +00:22:23,590 --> 00:22:27,590 +المثال تفاعلين مشهورين ودائما تسألوا فيهم واحد + +269 +00:22:27,590 --> 00:22:30,670 +بيمر عندكم في ال الديادس والكيتونز وواحد في + +270 +00:22:30,670 --> 00:22:35,450 +الأحماض ومشتاقاتها الالدول كليزن reaction الالدول + +271 +00:22:35,450 --> 00:22:41,050 +addition reaction الكليزن substitution reaction + +272 +00:22:41,050 --> 00:22:45,030 +واضح؟ ولذلك لو أنا هنا بدي أخد هذا الإغلاق الأصفر + +273 +00:22:46,270 --> 00:22:50,250 +أو أخلّي ال Oxygen اتهاجم على C double bond O شو + +274 +00:22:50,250 --> 00:22:54,290 +هتطرد ال O Methane تفاعل ال Easter تفاعل ال Easter + +275 +00:22:54,290 --> 00:22:58,090 +Substitution هينتج عنده هذا الناتج طبعا هذه هتكون + +276 +00:22:58,090 --> 00:23:05,670 +خارج ال Cyclizationربما هذا المثال بشكل الحالي + +277 +00:23:05,670 --> 00:23:11,410 +يجيبلكم أو يوضحلكم مشكلة من أهم الأمور اللي بتغلب + +278 +00:23:11,410 --> 00:23:15,310 +الطلبة اللي بتغلب الطلبة في ال heterocyclic + +279 +00:23:15,310 --> 00:23:20,350 +chemistry على الإطلاق هذه النقطة أن يستطيع أي + +280 +00:23:20,350 --> 00:23:28,270 +إنسان أن يرسمالجزء بطريقة معينة فيوحي لكم بإغلاق + +281 +00:23:28,270 --> 00:23:33,810 +معين بسهولة ويرسموا بطريقة ثانية فإنتوا بيكون + +282 +00:23:33,810 --> 00:23:38,770 +الإغلاق يبين بعيد عنكم ولذلك بهذا الشكل لما حط ال + +283 +00:23:38,770 --> 00:23:42,730 +O جنب هذا ال carbon كان سهل عليكم تشوفوا الإغلاق + +284 +00:23:42,730 --> 00:23:49,460 +الآن ال O حطها بعيدعن هذا ال carbon واضح نفس هذا + +285 +00:23:49,460 --> 00:23:53,600 +المثال انا كان ممكن ارسمه بطريقة هذه C double bond + +286 +00:23:53,600 --> 00:23:59,080 +O O مثل اطلع لفوق اخلي هذا C double bond C لبرا + +287 +00:23:59,080 --> 00:24:06,020 +هيها المتصلة مباشرة بعدها ايش عندى CH2 كمان CH2 + +288 +00:24:06,020 --> 00:24:16,720 +كمان O هذا هو نفس هذاهذا هو نفس هذا، مسكت هذه، + +289 +00:24:16,720 --> 00:24:20,540 +سحبت الأعلى، يعني لو على برنامج الرسم بالماوس، + +290 +00:24:20,540 --> 00:24:25,980 +بسحب هذه لأعلى، الآن بهذا الشكل، ايش ال E حق اللي + +291 +00:24:25,980 --> 00:24:30,640 +أسرع على ذهنكم؟ ان هاي ال O وهي ال E star، احنا + +292 +00:24:30,640 --> 00:24:36,500 +مليون مرة عملنا تفاعل Oxygen على E starالان خلّيني + +293 +00:24:36,500 --> 00:24:40,920 +أكد على هذه النقطة و هي من أهم المشاكل اللي بتواجه + +294 +00:24:40,920 --> 00:24:44,800 +الطالب في الكيميا الحلقية مرات كتير بيعتقد أنه + +295 +00:24:44,800 --> 00:24:50,580 +فاهم و بيجي ع الامتحان أنه فاهم لكن يمكن أفضل كلمة + +296 +00:24:50,580 --> 00:24:55,320 +بقولكوا إياها عشان يجيله الفكرة إنه كيف يجيب + +297 +00:24:55,320 --> 00:24:59,760 +الشغلات ع بعض و تسكر بالشكل الصحيح صدقوني ما بينفع + +298 +00:24:59,760 --> 00:25:06,990 +غير شغلة واحدة عارفين شو هي؟رضى الله ورضى الوالدين + +299 +00:25:06,990 --> 00:25:11,630 +رضى الله ورضى الوالدين غير هيك ممكن مايجيش على + +300 +00:25:11,630 --> 00:25:15,610 +بالكم الإغلاق اللى بده يتم و تصيروا تفكروا تشتغلوا + +301 +00:25:15,610 --> 00:25:20,050 +تكونوا بتعملوا ببحث معين لأنكوا رسمتوا الجزيء بشكل + +302 +00:25:20,050 --> 00:25:24,590 +معين أوحى لكم بزاوية معينة يعني لو هذا الجزيء + +303 +00:25:24,590 --> 00:25:29,850 +مرسوم بهذا الشكل ربما الإيحاء الأسرع إلى ذهنكم هذا + +304 +00:25:29,850 --> 00:25:34,960 +ال cycleization هيعطيني نفس الناتج اللى هناواضح ان + +305 +00:25:34,960 --> 00:25:40,920 +الحلقة خماسية وانه الـ cyclization اكزو اه و لذلك + +306 +00:25:40,920 --> 00:25:44,480 +هذا five اكزو ال triangular لان هذا ال triangular + +307 +00:25:44,480 --> 00:25:50,380 +الان لاحظوا معي ان الرسم الجزء بهذه الطريقة يمكن + +308 +00:25:50,380 --> 00:25:57,070 +بيان انهبشكل واضح سايكلايزيشن تاني ممكن يتم بسهولة + +309 +00:25:57,070 --> 00:26:01,110 +ان هاي double bond C double bond O وهاي C double + +310 +00:26:01,110 --> 00:26:07,230 +bond C ما المانع انه يجي ال cycleization هاد بهذا + +311 +00:26:07,230 --> 00:26:13,590 +الشكل و هاد تيجي للخارج و اجت لو بدى اشوف ايش + +312 +00:26:13,590 --> 00:26:15,890 +الناتج اللى بدى يكون اللى هو نفس هذا ال + +313 +00:26:15,890 --> 00:26:19,890 +cycleization اللى هاد اللى يتم على هذا الكربون و + +314 +00:26:19,890 --> 00:26:26,640 +اجت هذا الناتج اللى عندىحلقة رباعية و من هنا ال + +315 +00:26:26,640 --> 00:26:32,320 +CH2 صارت single bond و أخدت H CH3C + +316 +00:26:32,320 --> 00:26:41,990 +O مثل هذا ما كتبوشهاولذلك لما انا بدي اجي احكي كام + +317 +00:26:41,990 --> 00:26:46,250 +احتمال cyclization ممكن عندى في هذا المثال لحتى + +318 +00:26:46,250 --> 00:26:49,830 +الآن ضمن احتمالات الكيميا طالما carbon double bond + +319 +00:26:49,830 --> 00:26:54,170 +carbon ممكن اتمهانة بحلقة خمسية ممكن اتمهانة بحلقة + +320 +00:26:54,170 --> 00:26:58,890 +ربعية ممكن اتمهانة بحلقة خمسية تانية طبعا واحدة + +321 +00:26:58,890 --> 00:27:03,630 +بتقول نظريا الجواب اه لو كان في XY ممكن اتمهانة + +322 +00:27:05,700 --> 00:27:09,740 +ممكن يتم على هذا ال oxygen اغلاق للداخل و هيعطينا + +323 +00:27:09,740 --> 00:27:14,420 +وجهة حلقة ربما سداسية لكن لما بكون عندى سيضة بال + +324 +00:27:14,420 --> 00:27:18,060 +bond O و انا عارف شوية علم في الكيميا ان ال carbon + +325 +00:27:18,060 --> 00:27:21,160 +هي اللي بده تكون electrophilic more than the + +326 +00:27:21,160 --> 00:27:27,760 +oxygen استثمت الاحتمال اللي هناواضح؟ لكن كرسم، لو + +327 +00:27:27,760 --> 00:27:32,820 +إنسان بده يرسم جميع الاحتمالات، النظرية للإغلاق في + +328 +00:27:32,820 --> 00:27:37,460 +هذا المُركّب، بده يرسم أكتر من احتمال، واضح؟ + +329 +00:27:37,460 --> 00:27:41,420 +خلّينا نقول أقل تقدير هذه الاحتمالات اللي موجودة، + +330 +00:27:41,420 --> 00:27:45,200 +هذا الاحتمال واضح، هذا واضح، هذا لو كنت الأن بده + +331 +00:27:45,200 --> 00:27:48,420 +أسميه الاحتمال، اللي هو بهذا الشكل + +332 +00:27:52,260 --> 00:27:58,080 +أذا for اكزو ترياجونال + +333 +00:27:58,080 --> 00:28:05,360 +for اكزو ترياجونال واضح؟ الآن هذه بتكون من أول + +334 +00:28:05,360 --> 00:28:10,180 +دراستنا للموضوع بتعطيكوا فكرة انه دائما تطلعوا على + +335 +00:28:10,180 --> 00:28:14,820 +الجزيء ترسموه بأكثر من طريقة تحطوا اكثر من احتمال + +336 +00:28:14,820 --> 00:28:19,640 +بالورقة والجلم الآن التجربة شو بتطلع؟الحلقة + +337 +00:28:19,640 --> 00:28:24,080 +الربعية أو الخمسية أو السادسية ما تقولوش إطلاقا أن + +338 +00:28:24,080 --> 00:28:28,440 +الحلقة الخمسية أو السادسية more stable و تستثنوا + +339 +00:28:28,440 --> 00:28:33,540 +الربعية أو ثلاثية كتير مركبات فيهم حلقات ربعية و + +340 +00:28:33,540 --> 00:28:38,640 +مركبات ثابتة و مشهورة خدوا كل عيلة البنسالينإذا + +341 +00:28:38,640 --> 00:28:42,500 +مرت عليكم البنسالين مش عبارة عن ال beta lactam + +342 +00:28:42,500 --> 00:28:46,920 +ring وهذه حلقة رباعية أشهر المضادات الحيوية يعني + +343 +00:28:46,920 --> 00:28:52,060 +من أشهر اكتشافات الكيبيا المركبات اللي فُصلت و + +344 +00:28:52,060 --> 00:28:56,040 +أخدت استعمال البنسالين البنسالين حلقة رباعية و + +345 +00:28:56,040 --> 00:28:59,460 +بالباع كأدوية و الناس بتعالج فيه و ما إلى ذلك ما + +346 +00:28:59,460 --> 00:29:04,560 +تستثنوا بالورقة و القلم احتمالات الآن على أرض + +347 +00:29:04,560 --> 00:29:10,940 +الواقعالله أعلم لما احنا بدنا نبدأ نشرح بالتأكيد + +348 +00:29:10,940 --> 00:29:13,800 +الآن بيصير الكلام عندكم واضح انه كيف انا بدي اشرح + +349 +00:29:13,800 --> 00:29:20,030 +الـ cyclization reactions هابدأ بهذا النوعوهذا + +350 +00:29:20,030 --> 00:29:24,210 +النوع إبدال لأن أنا بطلع ال Y بعدين addition على + +351 +00:29:24,210 --> 00:29:27,250 +ال double bond سواء كانت carbon double bond oxygen + +352 +00:29:27,250 --> 00:29:30,650 +او carbon triple bond او carbon double bond carbon + +353 +00:29:30,650 --> 00:29:33,610 +او ممكن اعمل substitution على carbon double bond + +354 +00:29:33,610 --> 00:29:39,070 +oxygen اذا كانت من عائلة الأحماض ومشتقتها بعدين + +355 +00:29:39,070 --> 00:29:43,870 +هروح على ال carbonTriple bond carbon و carbon + +356 +00:29:43,870 --> 00:29:47,310 +triple bond nitrogen و nitrogen triple bond carbon + +357 +00:29:47,310 --> 00:29:51,410 +فبناء على ذلك هيصير توزيع المحاضرات اللي احنا + +358 +00:29:51,410 --> 00:29:57,090 +بنشرحهم بوضوح ال substitution انه عندي هنا مجموعة + +359 +00:29:57,090 --> 00:30:01,170 +بده اطردها هالوجين او good leaving group بعد هيك + +360 +00:30:01,170 --> 00:30:05,590 +reaction at double bonds بعدين reaction at triple + +361 +00:30:05,590 --> 00:30:09,590 +bonds فإيش اللي هنبدأ فيهالـ Substitution + +362 +00:30:09,590 --> 00:30:15,910 +Reactions تفاعلات الإبدال على تتراجونال كربون + +363 +00:30:18,670 --> 00:30:22,710 +لو شفنا الموضوع لاحظوا في ناس اشتغلوا على هذا + +364 +00:30:22,710 --> 00:30:25,890 +الموضوع و من هنا بتقدروا تشوفوا اهمية انكوا + +365 +00:30:25,890 --> 00:30:30,810 +تتعلموا طريقة من انكوا تتعلموا تحضير مركب معين انا + +366 +00:30:30,810 --> 00:30:35,010 +الآن الطريقة عندى اليوكليوفايل و إبدان صح؟ خليني + +367 +00:30:35,010 --> 00:30:38,730 +اقول هي الان اتشتون يوكليوفايل و ال PR good living + +368 +00:30:38,730 --> 00:30:46,110 +group خلت الذرات تلاتة بعمل هنا ال cyclizationبصير + +369 +00:30:46,110 --> 00:30:51,870 +ولا مابصيرش و بطرد ال PR three exo tetragonal + +370 +00:30:51,870 --> 00:30:56,170 +cyclization بعمل هنا ال cyclization لو زيدت ذرة + +371 +00:30:56,170 --> 00:31:02,970 +four exo tetragonal cyclization بزيد كمان ذرة five + +372 +00:31:02,970 --> 00:31:09,200 +exo tetragonal six exo tetragonal فهذه الفكرةعامة + +373 +00:31:09,200 --> 00:31:16,760 +كام حلقة حضرنا منها لو بتطلعوا أزردين و أزتدين و + +374 +00:31:16,760 --> 00:31:24,460 +بيرولدين و بيبردين كل أنواع الحلقات لكن حضرناهم + +375 +00:31:24,460 --> 00:31:28,800 +بفكرة واحدة اللي هي فكرة ال cycleization أو ال + +376 +00:31:28,800 --> 00:31:31,820 +substitution at saturated carbon + +377 +00:31:34,220 --> 00:31:37,940 +الان اعملوا دراسات للناس اللي اشتغلوا على هذا + +378 +00:31:37,940 --> 00:31:44,000 +الموضوع على قداش سرعة التفاعل اعتمادا على حجم + +379 +00:31:44,000 --> 00:31:49,410 +الحلقة لاحظوا ان لو يعتبروا مثلاال ring size + +380 +00:31:49,410 --> 00:31:56,070 +الحلقة الربعية واحد الحلقة الخماسية بتكون أسرع في + +381 +00:31:56,070 --> 00:32:00,270 +التكون ب 6 في 10 و 4 يعني 60 ألف مرة من الحلقة + +382 +00:32:00,270 --> 00:32:04,230 +الربعية هذا كلام منطقي احنا اتعلمنا ان الخماسي + +383 +00:32:04,230 --> 00:32:09,770 +أفضل من الرباعي السداسية بال ألف مرة لاحظوا + +384 +00:32:09,770 --> 00:32:16,320 +السباعيةمرتين يعني ضعيفة جدا الربعية كنا ماعطينها + +385 +00:32:16,320 --> 00:32:19,420 +هي ال reference اللي قرالنا فيها خليناها واحد + +386 +00:32:19,420 --> 00:32:26,380 +الثلاثية سبعين ربما البعض يستغرب من أي منطقة ان + +387 +00:32:26,380 --> 00:32:32,760 +الثلاثيةأكتر من الرباعية مع العلم لو انتوا بتاخدوا + +388 +00:32:32,760 --> 00:32:37,640 +الكلام بمنطق الزوايا و ان الزاوية اللى مترايحة ال + +389 +00:32:37,640 --> 00:32:42,680 +109 او 109.5 و هذه الخماسية 108 كلام منطقي + +390 +00:32:42,680 --> 00:32:47,520 +السوداسية 120 كلام منطقي السوبعية خلاص بتبعد و ما + +391 +00:32:47,520 --> 00:32:50,900 +إلى ذلك الحلقات الكبيرة صعب التكوين صعب انهم + +392 +00:32:50,900 --> 00:32:55,530 +يلتقوا مع بعض الأطراف البعيدة لكنالسؤال اللي انتوا + +393 +00:32:55,530 --> 00:33:00,470 +ممكن تستغربوا انه الحلقة الرباعية زاويتها تسعين + +394 +00:33:00,470 --> 00:33:06,670 +الثلاثية زاويتها ستين فالتوقع اللي ممكن تتوقعوا ان + +395 +00:33:06,670 --> 00:33:11,690 +الرباعية تتكون أفضل من الثلاثية بهذا المثال بكل + +396 +00:33:11,690 --> 00:33:16,310 +الأحوال الثلاثية اللي اتكونت هيمور عليكوا أمثلة + +397 +00:33:16,310 --> 00:33:21,270 +يكون الاحتمال ما بين حلقة رباعية وخماسية واتلاحظوا + +398 +00:33:21,270 --> 00:33:25,590 +اللي بتتكون الرباعية مش الخماسيةChemistry is an + +399 +00:33:25,590 --> 00:33:29,350 +experimental science بعدين تصيروا تفسروها تقولوا + +400 +00:33:29,350 --> 00:33:32,630 +thermodynamically control the product ولا كاينة + +401 +00:33:32,630 --> 00:33:36,170 +تكلف control the product ايش ماكان هذا موضوع تاني + +402 +00:33:36,170 --> 00:33:41,370 +لكن في كل الأحوال الأساسالتجربة في الحلقات + +403 +00:33:41,370 --> 00:33:44,510 +الثلاثية ليش بيقولوا الحلقات الثلاثية بتتكون؟ + +404 +00:33:44,510 --> 00:33:49,650 +بعرفش إذا حد منكوا عمرو فكر إنه هال orbitals فعلا + +405 +00:33:49,650 --> 00:33:53,470 +صعب جدا يعني لو أنا تخيلت الحلقة الثلاثية بهذا + +406 +00:33:53,470 --> 00:33:58,750 +الشكل ال orbitals صعب جدا تنضغط بزاوية 60 الآن أي + +407 +00:33:58,750 --> 00:34:03,940 +شيء مش قادر ينضغط شو بيعمل؟بيطلع لبرا .. بيطلع + +408 +00:34:03,940 --> 00:34:07,760 +لبرا و لذلك ال orbitals هنا بتيجيش بين ال carbon و + +409 +00:34:07,760 --> 00:34:14,620 +ال carbon ال orbitals هنا بتيجي للخارج بهذا الشكل + +410 +00:34:14,620 --> 00:34:21,240 +يعني تخيل هاي orbital و هاي orbital فتركيز + +411 +00:34:21,240 --> 00:34:24,880 +الإلكترونات بيكونش بين الذرتين بيكون للخارج و هنا + +412 +00:34:24,880 --> 00:34:29,620 +نفس الشيء هاي orbitals و هاي orbitals هنا نفس + +413 +00:34:29,620 --> 00:34:37,000 +الشيءهي orbitals وهي + +414 +00:34:37,000 --> 00:34:40,900 +orbitals الان لاحظوا لو انا بدى اشوف كل هذه ال + +415 +00:34:40,900 --> 00:34:44,560 +orbital الان ككثافة إلكترونية صارت في الخارج it + +416 +00:34:44,560 --> 00:34:53,940 +looks like banana زي الموزةشكل ال orbitals ولذلك + +417 +00:34:53,940 --> 00:34:59,700 +هذي بيسموها banana like orbitals يعني orbitals + +418 +00:34:59,700 --> 00:35:04,900 +بتشبه الموزة فلو انتوا بدكوا تكتبوا تشوفوا كلام + +419 +00:35:04,900 --> 00:35:11,340 +اكتر عن الموضوع اكتبوا banana like orbitals ال + +420 +00:35:11,340 --> 00:35:16,060 +orbitals بتشبه ايش الموزة طال على برا مش جاي بين + +421 +00:35:16,060 --> 00:35:21,300 +الذرتين الان لاحظوا هنا الزاويةأكبر ولا مش أكبر؟ + +422 +00:35:21,300 --> 00:35:25,920 +أكبر من ال 60 لأن ال orbitals مستحيل تتضغط بهذا + +423 +00:35:25,920 --> 00:35:30,860 +الشكل فالإلكترونات بتصير كثافتهم مش مباشرة بين + +424 +00:35:30,860 --> 00:35:36,240 +الذرتين بتصير طالة على برا واضح؟ فهذا قد يكون جزء + +425 +00:35:36,240 --> 00:35:41,060 +من تفسير أنه يعني عامات بتشوفوا أن الحلقة الثلاثية + +426 +00:35:41,060 --> 00:35:47,360 +هنا طلعت ربما بنسب أو بسرعة أفضل حتى من الرباعية + +427 +00:35:51,390 --> 00:35:57,030 +الان ايش بالظبط تكون اي حلقة و كيف تكون هذا علم + +428 +00:35:57,030 --> 00:36:00,810 +كامل بحاجة لتفصيل ماتنسيش ان احنا لما أخدنا + +429 +00:36:00,810 --> 00:36:07,790 +الـcyclobutane بداية قولنا cyclobutane is not a + +430 +00:36:07,790 --> 00:36:13,350 +planar molecule احنا مابتكونش تنسوا اللي هي ال .. + +431 +00:36:13,350 --> 00:36:18,620 +ايش .. بيشبه ايش ال cyclobutaneال butterfly + +432 +00:36:18,620 --> 00:36:24,240 +الفراشة قولنا ال cyclobutane مش زي هيك بنعمله و + +433 +00:36:24,240 --> 00:36:33,590 +planner لأ بنعمله زي الفراشة تخيلوا هيكزي ال + +434 +00:36:33,590 --> 00:36:38,190 +butterfly هذا درسناه في ال geometry واخدنا الحلقة + +435 +00:36:38,190 --> 00:36:41,750 +الخمسية it is like an open envelope واخدنا الحلقة + +436 +00:36:41,750 --> 00:36:45,370 +السوداسية فيها conformations it share و both + +437 +00:36:45,370 --> 00:36:49,980 +conformations و أشياء هذا الكلام كله يرجع لهفي + +438 +00:36:49,980 --> 00:36:55,180 +دراسة الحلقات الأصلية فالان كيف بدها تصفى الزوايا + +439 +00:36:55,180 --> 00:36:59,860 +و أطوال الروابط في هذه الحلقات هذا كلام بيدرسه + +440 +00:36:59,860 --> 00:37:03,960 +أكتر ناس بدرسه اللي بيدرسوا ال molecular geometry + +441 +00:37:03,960 --> 00:37:08,780 +و بيعملوا لبعض المركبات x-ray بالتالة بتلاقوهم + +442 +00:37:08,780 --> 00:37:13,580 +حاطين كل أطوال الروابط و كل زوايا الروابط الزوايا + +443 +00:37:13,580 --> 00:37:20,160 +العادية و ال dihedral angles أشياء كثيرةناخد مثال + +444 +00:37:20,160 --> 00:37:27,100 +تاني لحظوا هذا المثال هذا المثال الجميل بالشكل + +445 +00:37:27,100 --> 00:37:32,260 +القاتى عندى carboxylate anion carboxylate anion + +446 +00:37:32,260 --> 00:37:38,660 +هذا ال carboxylate anion بيهاجم هنا بيطرد لبروم + +447 +00:37:38,660 --> 00:37:46,240 +هيعمل حلقةتو اكزو تترا هيدروفيوران واضح الان + +448 +00:37:46,240 --> 00:37:50,420 +انتبهوا معي وين بتكون ال heterocycle كيميسترا سهلة + +449 +00:37:50,420 --> 00:37:56,420 +وين بتصعد لما انا باجي ارسملكم المثال بهذا الشكل + +450 +00:37:56,420 --> 00:38:01,780 +جاهز يعني انا حاطط لنيوكليوفايل تماما عند ال + +451 +00:38:01,780 --> 00:38:07,040 +electrode file ولا اجمل لكن لما انا باجي اقولكم + +452 +00:38:07,040 --> 00:38:17,610 +انه والله عنده CH2بر بعدين CH2 + +453 +00:38:17,610 --> 00:38:22,230 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +454 +00:38:22,230 --> 00:38:26,890 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +455 +00:38:26,890 --> 00:38:27,690 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +456 +00:38:27,690 --> 00:38:28,550 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +457 +00:38:28,550 --> 00:38:36,130 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +458 +00:38:36,130 --> 00:38:41,760 +CH2 CH2 CHيعني عملت الانايم و بعد هيك تتخيلوا كيف + +459 +00:38:41,760 --> 00:38:46,300 +لفيتوا الجزء الجزء جربت ال O minus عند هذا الكربون + +460 +00:38:46,300 --> 00:38:50,980 +اللي حامله بروميل عشان تم التفاعل ولذلك بقولكوا + +461 +00:38:50,980 --> 00:38:54,860 +انا انه ال heterocycle chemistry بيدها خبرة يعني + +462 +00:38:54,860 --> 00:38:59,060 +بهذا الشكل completely following equation سهلة بهذا + +463 +00:38:59,060 --> 00:39:05,410 +الشكلبالتأكيد هتبدو تحس انه صعب وين ال nucleophile + +464 +00:39:05,410 --> 00:39:09,110 +وين ال electrophile كيف ألف الأشياء المرسومة + +465 +00:39:09,110 --> 00:39:13,990 +أحيانا ممكن يكون الجزء مرسوم ومحتوطين الطرفين اللي + +466 +00:39:13,990 --> 00:39:17,990 +بدهم يعملوا cyclization أبعد ما يمكن على بعض آخر + +467 +00:39:17,990 --> 00:39:21,690 +ما يخطر ع بالكوا أن هدول بدهم ييجوا يعملوا + +468 +00:39:21,690 --> 00:39:26,480 +cyclizationولذلك اللي بده يسهل على طلابه في + +469 +00:39:26,480 --> 00:39:30,240 +المستقبل لما بدرسوا الكيميا أفضل شيء أنه يرسم + +470 +00:39:30,240 --> 00:39:35,400 +الجزئ بوضعية جيدة تتيح أن الطالب يشوف التفاؤل + +471 +00:39:35,400 --> 00:39:40,760 +بطريقة بسيطة أو سهلة هذا الكلام بيساعد على الفهم + +472 +00:39:40,760 --> 00:39:45,160 +لكن بنفس الوقت ممكن يكون له أثر ضار أنه على أرض + +473 +00:39:45,160 --> 00:39:49,980 +الواقع لو إجا لهذا الطالب سؤال مش مرسوم بسهولة + +474 +00:39:49,980 --> 00:39:53,360 +ماتعودش يشغل مخه كتير واضح؟ + +475 +00:40:00,990 --> 00:40:08,550 +الان ناخد مثال اضافهبسموه ال Darzen Condensation + +476 +00:40:08,550 --> 00:40:12,290 +Reaction او Darzen Reaction وهذا ال Darzen + +477 +00:40:12,290 --> 00:40:18,090 +Reaction بيحضروا فيه ال Epoxides بيحضروا فيه ال + +478 +00:40:18,090 --> 00:40:22,910 +Epoxides بتعرفوا ال Epoxides اللي هي الحلقات + +479 +00:40:22,910 --> 00:40:29,890 +الثلاثية شو ال Darzen Reaction هذا؟ هو تفاعل كيتون + +480 +00:40:29,890 --> 00:40:34,290 +او Aldehyde احنا انا اي اش اللي استعملناها؟الديهيد + +481 +00:40:34,290 --> 00:40:41,170 +بنزل ديهيد تفاعل كيتون او الديهيد مع الفا هالو إي + +482 +00:40:41,170 --> 00:40:45,950 +ستار الفا هالو إي ستار لو طلعت أنا عند سيدا بالبنت + +483 +00:40:45,950 --> 00:40:52,170 +او اقفل هاي سي اتش تو على موقع الفا عند هالوجين + +484 +00:40:53,180 --> 00:40:57,680 +فصار هذا ألفهالو إيستر يعرفنا إذا كيف ألفهالو + +485 +00:40:57,680 --> 00:41:03,080 +إيستر الآن هذا الألفهالو إيستر أكيد في الخطوة + +486 +00:41:03,080 --> 00:41:08,240 +الأولى تبعت التفاعل بالفعل مع base اتذكروا أن عندي + +487 +00:41:08,240 --> 00:41:14,080 +هنا في الأصل CH2 بين C double bond O و بين halogen + +488 +00:41:14,080 --> 00:41:18,400 +ال CH2 لبين تنتين C double bond O ولا بين C double + +489 +00:41:18,400 --> 00:41:23,160 +bond O و C triple bond Nأو بين C double bond O و + +490 +00:41:23,160 --> 00:41:26,800 +Sulphur أو بين C double bond O وHalogen شو سمناها + +491 +00:41:26,800 --> 00:41:32,800 +هذه CH2 Activated Methylene Group فيها Acidic + +492 +00:41:32,800 --> 00:41:38,500 +Hydrogens فبأبسط بيس تفقد هيدروجين صار عندهان ايون + +493 +00:41:38,500 --> 00:41:44,280 +سالب صار عندهان ايون سالب الآن هذا الايون السالب + +494 +00:41:44,280 --> 00:41:47,140 +زي ما اتعلمتوا في ال organic synthesis هذا الايون + +495 +00:41:47,140 --> 00:41:51,840 +السالب لما بدو يهاجم وين بدو يهاجم؟على ال C double + +496 +00:41:51,840 --> 00:41:58,140 +bond O و هذا تصير O minus في المرحلة الأولى و لو + +497 +00:41:58,140 --> 00:42:02,520 +سكرنا التفاعل بتصير O H الآن خلوها تاجم على ال C + +498 +00:42:02,520 --> 00:42:07,480 +double bond O و تصير ال O minus هذا الجزء الأول + +499 +00:42:07,480 --> 00:42:16,480 +اللي هو Phenyl C وحملة H و O minus اللي هو هذا + +500 +00:42:16,480 --> 00:42:22,870 +الجزءوصار شابق معه ال carbon اللي من هنا حاملة H + +501 +00:42:22,870 --> 00:42:31,190 +واحدة و CO2 إثل و حاملة هنا PR و حاملة هنا PR الآن + +502 +00:42:31,190 --> 00:42:37,480 +سهل جدا علينا نفهمسهل جدا علينا نفهم أن هذه الـ O- + +503 +00:42:37,480 --> 00:42:44,340 +مباشرة ممكن تهاجم وتطرد الـ PR في three exo + +504 +00:42:44,340 --> 00:42:50,020 +tetragonal reaction صح ولا لأ؟ ليش three؟ لأن + +505 +00:42:50,020 --> 00:42:56,200 +الحلقة المتكونة ثلاثية exo لأن الـ PR طردت + +506 +00:42:56,200 --> 00:43:01,040 +tetragonal لأن الكاربون اللي تم عليها التفاعل + +507 +00:43:01,040 --> 00:43:02,380 +تتراجونال + +508 +00:43:04,370 --> 00:43:10,650 +أذا هنا تم تفاعل بـ 3-exo-tetragonal reaction ولا + +509 +00:43:10,650 --> 00:43:17,010 +لأ؟ واضح؟ هنا حضرنا الـ Epoxide فالان التحضير + +510 +00:43:17,010 --> 00:43:20,430 +عندنا بدأ شوية شوية يمشي للأمام صار في الأول بدي + +511 +00:43:20,430 --> 00:43:24,750 +أعمل خطوة تحضيرية أجهز القطع اللي بدي تعمل الـ + +512 +00:43:24,750 --> 00:43:28,450 +cyclization وبعدين خطوة الـ cyclization الآن احنا + +513 +00:43:28,450 --> 00:43:31,750 +بنقول في الـ heterocyclic chemistry شغلنا بده يشمل + +514 +00:43:31,750 --> 00:43:36,310 +الشغل تانيموضوعنا ال cycleization هذا لكن عشان + +515 +00:43:36,310 --> 00:43:40,170 +احضر هذا الجزء بدي ال chemistry القديمة هذه old + +516 +00:43:40,170 --> 00:43:45,230 +chemistry هذه كيميا قديمة المفروض ان الطالب + +517 +00:43:45,230 --> 00:43:52,410 +اتعلمها من الاول الان لو يا ترى لو يا ترى بدي + +518 +00:43:52,410 --> 00:43:57,150 +واحدة شاطرة من اللي بدت تستوعب معنا موضوع + +519 +00:43:57,150 --> 00:44:05,060 +الاحتمالات و تفكر معاهبنتج تاني لهذا الكفاعة على + +520 +00:44:05,060 --> 00:44:08,000 +الـ c double bond o لحظة انا ال c double bond o + +521 +00:44:08,000 --> 00:44:13,440 +مخفية تماما مخفية حاططة على جانب ولا اشي ولا + +522 +00:44:13,440 --> 00:44:18,560 +مبينها لكن لو انا مجرد ان رسمت هذه c double bond o + +523 +00:44:18,560 --> 00:44:26,420 +او اثل وجدت هذا ما المانع ان يكون عندكم هذا + +524 +00:44:26,420 --> 00:44:33,550 +التفكيرو substitution ما هو E star سيطلع عندى حلقة + +525 +00:44:33,550 --> 00:44:39,270 +رباعية واضح طبعا هو بيعتمد على نتائج التجربة لكن + +526 +00:44:39,270 --> 00:44:45,950 +في كل الأحوال انتوا بدى يكون عندكم تفكير دائما + +527 +00:44:45,950 --> 00:44:53,260 +كبير في أكثر من احتمالهذا الاحتمال وارد يعني زي ما + +528 +00:44:53,260 --> 00:44:58,100 +في substitution ل ال halogen atom في substitution + +529 +00:44:58,100 --> 00:45:04,300 +من ناحية المبدأ على ال E stars الآن بالتجربة و هذا + +530 +00:45:04,300 --> 00:45:08,200 +ال Darcy reaction انه المفضل ال substitution على + +531 +00:45:08,200 --> 00:45:12,440 +الكربون اللي حامله ال halogen بس مابديش الطالب + +532 +00:45:12,440 --> 00:45:18,770 +يكون ناسي ان في عندهاحتمالات تانية و لو يعني من + +533 +00:45:18,770 --> 00:45:24,390 +الناحية النظرية ممكنة وتؤدي إلى نتائج تانية وهذا + +534 +00:45:24,390 --> 00:45:28,470 +جزء سيبقى ملازم لكم في ال heterocyclic chemistry + +535 +00:45:28,470 --> 00:45:35,610 +انكوا تفكروا بإيش بأكثر من احتمال ناخد مثال إضافي + +536 +00:45:35,610 --> 00:45:42,190 +بسيطلو أخدنا هذا المُركّب وفعلنا مع RNH2 لحظة + +537 +00:45:42,190 --> 00:45:45,370 +اعملنا هذا مثال سهل خطوة تحذيرية اعملنا + +538 +00:45:45,370 --> 00:45:50,630 +substitution لل PR ب RNH الان وين ال nucleophile + +539 +00:45:50,630 --> 00:45:59,050 +الجديد الان اتسكر على ال PR هتعطيني حلقة ثلاثية + +540 +00:45:59,050 --> 00:46:04,850 +تهيألي هذا المثال مثال بسيط وسهل + +541 +00:46:10,050 --> 00:46:15,690 +هيلزمني تقريبا كمان دقيقتين تلاتة بعد اذنكوا هذا + +542 +00:46:15,690 --> 00:46:19,550 +تحضير كتير مهم اسمه five spinary effuran synthesis + +543 +00:46:19,550 --> 00:46:23,270 +هذا بيشتغل على Alpha, Halo, Ketone مع Beta, Keto, + +544 +00:46:23,330 --> 00:46:28,870 +Ester في وجود بيريدين لاحظوا معاه بيعتمد على CH2 + +545 +00:46:28,870 --> 00:46:33,230 +اللي هنا activated البريدين بيصحب منها بروتون لما + +546 +00:46:33,230 --> 00:46:37,830 +يصحب بروتون بدوا يهاجم وين؟ على ال oxygen هذه + +547 +00:46:37,830 --> 00:46:46,130 +خلوها OHبهذا الشكل الآن لو سحبنا كمان بروتون تاني + +548 +00:46:46,130 --> 00:46:52,470 +من نفس هذه ال CH وعملنا tau to Mars بتصير عندى ال + +549 +00:46:52,470 --> 00:46:57,630 +O هذه minus ال O هذه minus الآن هذه ال O minus + +550 +00:46:57,630 --> 00:47:02,010 +بتسكر على ال CL ولا لأ اذا انا عملت سحب بروتون + +551 +00:47:02,010 --> 00:47:06,770 +مرتين يعني هنا في عندى كام بروتونالاتنين اول اشي + +552 +00:47:06,770 --> 00:47:11,810 +سحبت هذا لبروتون وعملت ال bond بعد ات سحبت لبروتون + +553 +00:47:11,810 --> 00:47:15,090 +التالس صار عنده هنا minus هذا ال minus لو عملتله + +554 +00:47:15,090 --> 00:47:21,950 +tautomerism يعني حركته هنا وخلت هذه O minus وخلتها + +555 +00:47:21,950 --> 00:47:27,210 +تسكر على ال CL شو طلع عندى substituted furan هذه + +556 +00:47:27,210 --> 00:47:29,490 +طريقة معروفة بنسميها احنا ايش + +557 +00:47:33,830 --> 00:47:36,990 +اعتمدت على اني سحبت كام بروتون من هذا الموقع + +558 +00:47:36,990 --> 00:47:40,750 +المنشط ال activated اتنين المرة الأولى و المرة + +559 +00:47:40,750 --> 00:47:43,410 +الثانية بعد ما اتكونت هذه ال intermediates سحبت + +560 +00:47:43,410 --> 00:47:50,670 +هنا كمان بروتون وعملت ال enolate anion هذا enolate + +561 +00:47:50,670 --> 00:47:55,770 +anion فحضرنا + +562 +00:47:55,770 --> 00:48:01,720 +الفيورانالحقيقة في عندكم اكثر من مثال اضافي يعني + +563 +00:48:01,720 --> 00:48:06,260 +هذه مثلا CH2 activated لو سحبت منها بروتون صارت + +564 +00:48:06,260 --> 00:48:13,860 +minus هتهجم على الان شو تترد؟ ال CL الان عندي هنا + +565 +00:48:13,860 --> 00:48:19,380 +كمان مثال هي CH2 activated لحظة هذا المثال هو نفس + +566 +00:48:19,380 --> 00:48:24,410 +هذالكن أنا أعدت رسمه عشان أفرجيكوا كيف لما نرسمه + +567 +00:48:24,410 --> 00:48:30,130 +بطريقة سهلة الآن بهذا الشكل مش واضح إلكم إنه أنا + +568 +00:48:30,130 --> 00:48:32,970 +بدي أكوّن ربما الـ nucleophile هنا و بدي أجيبه + +569 +00:48:32,970 --> 00:48:37,010 +يهاجم هنا هو نفس المثال لكن أنا أعدت رسمه بطريقة + +570 +00:48:37,010 --> 00:48:44,190 +سهلة هي ال minus اللي بيصير هنا هتسهل هذا نفس هذا + +571 +00:48:44,940 --> 00:48:50,600 +لاحظوا كيف طريقة الرسم بتساعد + +572 +00:48:50,600 --> 00:48:55,560 +على الحل هذا أيضا نفس المثال، هذه الأنوان بدها + +573 +00:48:55,560 --> 00:49:01,500 +تهاجم على الكاربون، شو بدها تطرد؟الـ PR كل هذه + +574 +00:49:01,500 --> 00:49:06,140 +الطرق substitution reactions ولا لأ؟ وتؤدي إلى + +575 +00:49:06,140 --> 00:49:10,540 +حلقات بالأشكال اللي احنا شوفناها وبهيك بننهي موضوع + +576 +00:49:10,540 --> 00:49:13,820 +ال substitution reaction المرة الجاية بدو يكون ان + +577 +00:49:13,820 --> 00:49:18,440 +شاء الله موضوعنا على ال reactions at double bonds + +578 +00:49:18,440 --> 00:49:21,020 +اللي هي addition reactions + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/aQtq119C9WI_postprocess.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/aQtq119C9WI_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..a37b334974aa04973ad04ff0f1fa65db0fd8dbbb --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/aQtq119C9WI_postprocess.srt @@ -0,0 +1,3580 @@ +1 +00:00:20,670 --> 00:00:27,310 +بسم الله الرحمن الرحيم اليوم قبل ما نبدأ المحاضرة + +2 +00:00:27,310 --> 00:00:32,730 +الجديدة تبعتنا بدنا نحاول نتطلع على الامتحان اللي + +3 +00:00:32,730 --> 00:00:39,390 +قدمته و نشوف الحلول ولو بشكل عام للأسئلة اللي مرت + +4 +00:00:39,390 --> 00:00:45,600 +معنالعلكوا يعني تستفيدوا منها كان السؤال الأول + +5 +00:00:45,600 --> 00:00:53,740 +سؤال تسمية واضح و طبعا في سؤال التسميةاتفقنا احنا + +6 +00:00:53,740 --> 00:00:58,840 +انه لما بيكون عندنا oxygen و sulfur و nitrogen بده + +7 +00:00:58,840 --> 00:01:03,040 +تكون نقطة البداية اللى عندنا من عند ال oxygen و + +8 +00:01:03,040 --> 00:01:08,680 +بناء على ذلك لما بنرقم هنا واحد اتنين تلاتة اربعة + +9 +00:01:08,680 --> 00:01:14,180 +خمسة فهيكون عندى one two three five الان بدنا + +10 +00:01:14,180 --> 00:01:21,190 +نذكرهم برضه oxygen بعدين sulfur بعدينأه ف ال one + +11 +00:01:21,190 --> 00:01:26,870 +oxygen اكزا التنين ثيا و تلاتة و خمسة ديازول فاللي + +12 +00:01:26,870 --> 00:01:33,550 +موجود عندى one two three five اكزا ثيا ديازول الآن + +13 +00:01:33,550 --> 00:01:39,250 +على المرأة التنين عندنا اكزامعروفة على تلاتة + +14 +00:01:39,250 --> 00:01:43,350 +وأربعة diphenyl طبعا من ناحية المبدأ هذه ال atom + +15 +00:01:43,350 --> 00:01:49,390 +تعتبر saturated وبناء على ذلك حطينا كمان هذه ال + +16 +00:01:49,390 --> 00:01:54,670 +nitrogen تحتمل in principle 3H فبصير الاسم العام 2 + +17 +00:01:54,670 --> 00:02:01,370 +-oxo-3-4-diphenyl-3-H-1-2-3-5-oxathiazole + +18 +00:02:03,030 --> 00:02:08,810 +المركب الثاني عبارة عن infused drinks المفروض + +19 +00:02:08,810 --> 00:02:13,990 +الإنسان ينظر نظرة عامة يحدد ال components اللي + +20 +00:02:13,990 --> 00:02:18,490 +موجودين ال components .. هذه ال components معروفة + +21 +00:02:18,490 --> 00:02:23,890 +بالنسبة إلينا هذه isoquinoline .. isoquinoline و + +22 +00:02:23,890 --> 00:02:30,820 +ال component التانية هذهone two four one two four + +23 +00:02:30,820 --> 00:02:37,300 +ال triazine طبعا صار أخطاء عند الطلاب منوعة بشكل + +24 +00:02:37,300 --> 00:02:41,100 +أساسي أن الترقيم لازم يبدأ من هنا يعني هذا واحد + +25 +00:02:41,100 --> 00:02:45,880 +اتنين تلاتة وبناء على ذلك لما تكون هذه A هذه B ف + +26 +00:02:45,880 --> 00:02:51,820 +ال fusion من عند B مش من عند Aواضح ده من الترقيم + +27 +00:02:51,820 --> 00:02:55,220 +من بداية الحلقة وهذا الكلام الحاجز الان هنا في + +28 +00:02:55,220 --> 00:02:59,780 +عندي واحد اتنين تلاتة اربعة بناء على ذلك هيكون + +29 +00:02:59,780 --> 00:03:04,740 +four three بي ايزوكوينولين طبعا هذا الاتريازينو + +30 +00:03:04,740 --> 00:03:11,760 +المفروض انحدد واش نكتب عليه one two four اتريازينو + +31 +00:03:12,930 --> 00:03:17,310 +و ننهي بال O فال .. ال two rings اللي عندي one two + +32 +00:03:17,310 --> 00:03:21,750 +four تريازين و four three بي ايزو كوينولين الان لو + +33 +00:03:21,750 --> 00:03:25,130 +مشينا في الترقيم على اقل number من ال hetero atoms + +34 +00:03:25,130 --> 00:03:28,910 +الترقيم اللي بدي ياخد كل الحلقات من برة هيكون + +35 +00:03:28,910 --> 00:03:34,740 +ترقيمنا من هنا واحد اتنين تلاتة اربعة خمسةستة and + +36 +00:03:34,740 --> 00:03:39,780 +so on الان على نمرة تلاتة في عندكم ethyl و نمرة + +37 +00:03:39,780 --> 00:03:45,320 +ستة saturated atom 6H فبصير الاسم العام three + +38 +00:03:45,320 --> 00:03:49,760 +ethyl six H one two four tryazino four three B + +39 +00:03:49,760 --> 00:03:57,690 +isoquinoline واضح؟الان المركبات اللى بعد Spiro + +40 +00:03:57,690 --> 00:04:03,070 +compounds طبعا احنا فى ال Spiro بنكتب كلمة Spiro و + +41 +00:04:03,070 --> 00:04:06,930 +جداش الحلقتين مخصوم منهم الذرع اللى فى الوسط هنا + +42 +00:04:06,930 --> 00:04:10,710 +بيضل عندى اربعة هنا بيضل عندى خمسة اذا هذا Spiro + +43 +00:04:10,710 --> 00:04:17,890 +four five العدد الكل جداش عشرة ديكين طبعا لإن فى + +44 +00:04:17,890 --> 00:04:26,720 +عندى ضايين هيصير ديك ضايينلأن في عندى own هتذكر ال + +45 +00:04:26,720 --> 00:04:30,580 +own او ممكن تذكروها also في الخارج مش هنختلف كثير + +46 +00:04:30,580 --> 00:04:35,220 +الان الترقيم من الحلقة الأصغر و من الطرف و بناء + +47 +00:04:35,220 --> 00:04:39,980 +على ذلك هيكون اكيد من ال oxygen واحد اتنين تلاتة + +48 +00:04:39,980 --> 00:04:44,300 +اربعة الان انا خمسة بعدين بدأ اتحرك على ال double + +49 +00:04:44,300 --> 00:04:49,240 +bond ستة و ستة بناء على ذلك هروح على ال double + +50 +00:04:49,240 --> 00:04:53,030 +bond اللي بتجيب لها أقل substituteواضح يعني + +51 +00:04:53,030 --> 00:04:56,590 +اتحركوا من هنا ستة خلوا هذا ال methoxy على تسعة او + +52 +00:04:56,590 --> 00:05:01,950 +عشرة لأ بناء على ذلك بنقول ستة سبعة تمانية تسعة + +53 +00:05:01,950 --> 00:05:08,750 +عشر هاي الترقيم فبصير عندى six methoxy one oxa + +54 +00:05:08,750 --> 00:05:15,850 +spyro four five dick six nine اللي هي بدايات ال + +55 +00:05:15,850 --> 00:05:23,990 +double bondsضايين ات اون ممكن تسهل لو ات اون + +56 +00:05:23,990 --> 00:05:30,230 +انكتبت ات اكزو في الأول مش هتكون مشكلة كبيرة واضح + +57 +00:05:30,230 --> 00:05:36,810 +الان واضح تماما ان كل هذه الأمثل لرغم ان الناس + +58 +00:05:36,810 --> 00:05:41,830 +عادة بيتقلموا احيانا ان هم بيخطئوا ان هي الكيميا + +59 +00:05:41,830 --> 00:05:47,330 +تطبيق والدنيانصيب لكن الشيء المؤكد مئة في المئة + +60 +00:05:47,330 --> 00:05:54,530 +أنه مافيش فيهم ولا حرف خارج ايش يعني خارج ما تم + +61 +00:05:54,530 --> 00:05:58,930 +دراسته الآن بعد ذلك جيبنالكم مركبات و قولنا لكم + +62 +00:05:58,930 --> 00:06:03,390 +ارسموا طبعا بتكون تبدأوا هذا المركب من ال paper + +63 +00:06:03,390 --> 00:06:08,880 +dealالبيبردين اللي هو البردين المشبق واضح؟ الآن + +64 +00:06:08,880 --> 00:06:13,660 +البيبردين عليه إبدال على نمرة أربعة بناء على ذلك + +65 +00:06:13,660 --> 00:06:17,920 +إذا كنت تجي على نمرة أربعة تطلعوا إبدال طب إيش + +66 +00:06:17,920 --> 00:06:22,720 +اللي موجود عليه على نمرة أربعة؟ موجود عليه one two + +67 +00:06:22,720 --> 00:06:27,660 +three four one three four oxadiazol هيحطينا ال one + +68 +00:06:27,660 --> 00:06:30,860 +three four oxadiazol لما نيجي نقول one three four + +69 +00:06:30,860 --> 00:06:36,470 +oxadiazol صار groupدائما ال group بتنتهي بأي + +70 +00:06:36,470 --> 00:06:43,550 +نهاية؟ YL مش أنا من ال مثيل كنت أاخد مثل من ال + +71 +00:06:43,550 --> 00:06:48,730 +إيثين إثل من البروبيل و ايزوبروبيل من البيوتين + +72 +00:06:48,730 --> 00:06:53,890 +بيوتل وبناء على ذلك لما هذا بده يصير group هو أكزا + +73 +00:06:53,890 --> 00:07:01,800 +ديازولهيصير أجزا ديازوليل لكن المفل معروف أنها + +74 +00:07:01,800 --> 00:07:06,620 +بتشبك من نقطة واحدة محددة طب الأجزا ديازوليا طب + +75 +00:07:06,620 --> 00:07:11,900 +بتشبك منها ولا منها؟لازم احدد مكان الشبك اللي هو + +76 +00:07:11,900 --> 00:07:16,320 +ال L هذه اللي بيشبك من عندها فبنقول two L بمعنى + +77 +00:07:16,320 --> 00:07:20,500 +شبك من موقع اتنين يعني هاي هذا ترقيم واحد اتنين + +78 +00:07:20,500 --> 00:07:25,600 +تلاتة اربعة خمسة ستة هذا ال بيبردين ال بيبردين على + +79 +00:07:25,600 --> 00:07:29,960 +موقع اربعة شبك اعرفنا ان هذه الأربعة خاصة في ال + +80 +00:07:29,960 --> 00:07:34,320 +ايش؟ في ال بيبردين الان هنا في عندي ترقيم تاني one + +81 +00:07:34,320 --> 00:07:41,400 +two three four fiveفال Oxidazole من وين شابك؟ من + +82 +00:07:41,400 --> 00:07:46,100 +ال carbon ولا من ال nitrogen؟ من موقع اتنين عشان + +83 +00:07:46,100 --> 00:07:50,300 +هيك بنقول Oxidazole L بس من وين عامل حاله group؟ + +84 +00:07:50,300 --> 00:07:57,380 +من اتنين ولا من تلاتة؟ اذا بنقول Oxidazole 2L وفي + +85 +00:07:57,380 --> 00:08:01,640 +كل ما بنستعمل حلقة او ما إلى ذلك ك substitute + +86 +00:08:01,640 --> 00:08:08,650 +بنستعمل ال YL و بنحدد وين شابكة؟ ان نحط رقمقبل هذه + +87 +00:08:08,650 --> 00:08:16,810 +الحلقة السؤال الأخير اللي هو عبارة عن infused + +88 +00:08:16,810 --> 00:08:21,490 +drinks عبارة عن infused drinks واضح ان في عندكم + +89 +00:08:21,490 --> 00:08:30,170 +تترازين حلقة سداسية وفي عندكم بريمدين برضه حلقة + +90 +00:08:30,170 --> 00:08:37,510 +سداسية الآن حلقة التترازين من وين شابكةمن B وحلقة + +91 +00:08:37,510 --> 00:08:42,990 +البراميديل من وين شابكة من 1 و 2 لو اتخيلتوا ان + +92 +00:08:42,990 --> 00:08:48,550 +انتوا بتعملوا هذا المركب من الصفر يعني مش موجود + +93 +00:08:48,550 --> 00:08:53,370 +عندكم كيف تفكروا فيه أسهل شئ تفكروا فيه انه تقولوا + +94 +00:08:53,370 --> 00:08:59,870 +هاي الحلقة السادسية وهي الحلقة السادسية التانية + +95 +00:08:59,870 --> 00:09:06,760 +الآن هذه ال base component من وين شابكةمن B طالما + +96 +00:09:06,760 --> 00:09:13,140 +شابكة من B إذا في إلها A إذا افترضوا يهان A يهان A + +97 +00:09:13,140 --> 00:09:18,080 +بأي طريقة بتعملوها هي AB و أنا ماشي بهذا الشكل + +98 +00:09:18,080 --> 00:09:25,200 +الآن ال pyramidine من وين شابك من 1 و 2 بنفس الاشي + +99 +00:09:25,200 --> 00:09:26,900 +واضح؟ + +100 +00:09:29,060 --> 00:09:33,940 +الان لما ابدي اجي اشتغل و احط الذرات اللي موجودين + +101 +00:09:33,940 --> 00:09:38,720 +هنا طبعا طالما انه انا قلت هاي AB اذا ترقيم هذا + +102 +00:09:38,720 --> 00:09:47,120 +واحد اتنين تلاتة اربعة خمسة ستة و ترقيم هذا واحد + +103 +00:09:47,120 --> 00:09:54,520 +اتنين نعمله بلون تاني تلاتة اربعة خمسة ستة الان + +104 +00:09:54,520 --> 00:10:00,800 +التترازين وين موجودين فيه ال nitrogenعلى واحد + +105 +00:10:00,800 --> 00:10:06,060 +واثنين واربعة + +106 +00:10:06,060 --> 00:10:14,880 +وخمسة ال pyramidين طبعا دائما واحد تلاتة هاي واحد + +107 +00:10:14,880 --> 00:10:21,960 +كلامنا سليم مافيش عندنا مشكلة وهي تلاتة واضح؟زي + +108 +00:10:21,960 --> 00:10:26,320 +هيك بنشتغلوا يعني بنحط الحلقات بدون ولا شيء بنحط + +109 +00:10:26,320 --> 00:10:32,740 +ال B و بنحط الأرقام و بنبدأ بهدوء نرجع الآن صرنا + +110 +00:10:32,740 --> 00:10:35,760 +عاملين الحلقاتين بعد هيك بدنا نشوف إيش ال + +111 +00:10:35,760 --> 00:10:39,640 +substituents اللي عندنا طبعا لما بدأ أرقم على أقل + +112 +00:10:39,640 --> 00:10:44,880 +atoms على أقل atoms الحقيقة هتلاحظوا أنه أنا بدأ + +113 +00:10:44,880 --> 00:10:47,880 +أتحرك من هنا هذا اللي بجيب الأقل number of atoms + +114 +00:10:48,640 --> 00:10:53,420 +واحد، اتنين من أحد الأطراف للخارج واحد، اتنين، + +115 +00:10:53,420 --> 00:10:58,280 +تلاتة، أربعة، خمسة واحد، اتنين، تلاتة، أربعة، + +116 +00:10:58,280 --> 00:11:06,740 +خمسة، ستة، سبعة، تمانية، تسعة ناين إبراهيم واضح؟ + +117 +00:11:06,740 --> 00:11:10,040 +هذا الترقيم الخارجي الآن هذا الترقيم الخارجي على + +118 +00:11:10,040 --> 00:11:13,560 +نمرة تمانية شو موجود عليه مثل + +119 +00:11:17,260 --> 00:11:23,260 +وعلى إيش ضال؟ على نمره ستة + +120 +00:11:23,260 --> 00:11:32,480 +on في غير هيك؟ مافيش، إذا بدي أحط ال double bonds + +121 +00:11:32,480 --> 00:11:35,540 +بدي أحط ال double bonds اللي اتسكر كل ما قد ذلك + +122 +00:11:35,540 --> 00:11:39,500 +هانا بتحتمل double bond؟ أكيد هانا بتحتمل double + +123 +00:11:39,500 --> 00:11:41,800 +bond؟ أكيد هانا بتحتمل double bond؟ أكيد هانا + +124 +00:11:41,800 --> 00:11:43,060 +بتحتمل double bond؟ أكيد + +125 +00:11:47,400 --> 00:11:55,540 +واضح؟ بحاجة إلى انه يتحللوا الأمر تحليلا هادئا + +126 +00:11:55,540 --> 00:12:08,960 +واضح اذا هذا المركب اللي موجود عندنا نمسكه الآن + +127 +00:12:08,960 --> 00:12:15,030 +هذا السؤال بحقيقةأخدنا احنا لما اتكلمنا عن ال + +128 +00:12:15,030 --> 00:12:19,010 +carbenes و ال nitrenes يعني لما نقول انه بدنا ال + +129 +00:12:19,010 --> 00:12:25,350 +benzoyl chloride يعني فينل C double bond O Cl بدنا + +130 +00:12:25,350 --> 00:12:30,550 +منه الفينل ايزو سيانيت الان هذا بنقدر بال Sodium + +131 +00:12:30,550 --> 00:12:38,390 +Azide نخليه فينل C double bond O Azide + +132 +00:12:38,390 --> 00:12:46,480 +الان بال photolysisبنخليه Nitrene و ال Nitrene بال + +133 +00:12:46,480 --> 00:12:51,640 +courtesery arrangement شو بيصير؟ Fennel N double + +134 +00:12:51,640 --> 00:12:55,220 +bond C double bond O أخدناها courtesery + +135 +00:12:55,220 --> 00:13:00,700 +arrangement و حطناها واضح؟ + +136 +00:13:00,700 --> 00:13:06,040 +فهذا كيف + +137 +00:13:06,040 --> 00:13:10,120 +نحضر ال Fennel Isocyanate من البنزوي الكلور + +138 +00:13:21,780 --> 00:13:29,040 +بعد هيك كان عندنا اسئلة مطلوب فيها ان نكمل + +139 +00:13:29,040 --> 00:13:36,260 +المعادلات والاصل الحقيقة انه يعني تفكروا + +140 +00:13:36,260 --> 00:13:40,640 +بالامور البساطة و التفكير هذه ما بتتغلبوا اطلاقا + +141 +00:13:40,640 --> 00:13:45,660 +.. ما بتتغلبوا اطلاقا يعني في السؤال الأول لو + +142 +00:13:45,660 --> 00:13:49,520 +انتوا اتطلعتوا انا في عندى هذه ال c double bond و + +143 +00:13:49,520 --> 00:13:57,140 +هذا electrifiedو ال CBR Electrophile تاني واضح؟ + +144 +00:13:57,140 --> 00:14:01,940 +الآن هاي Electrophile و هاي Electrophile نكتب موجب + +145 +00:14:01,940 --> 00:14:06,480 +كامل نفهم منه إنه إيش هذا Electrophile الآن هنا في + +146 +00:14:06,480 --> 00:14:14,480 +عندي أكمن يوكليوفايل من ناحية المبدأ أربعة و لو + +147 +00:14:14,480 --> 00:14:18,200 +بدكوا تحطوهم مع كوسين بتطلعوا تمام مركبات عند + +148 +00:14:18,200 --> 00:14:24,480 +اللزومواضح؟ لكن المفروض برضه قدر الإمكان تجتهدوا + +149 +00:14:24,480 --> 00:14:27,480 +يعني تطلعوا أشياء معقولة، رغم هيك، يعني كل ما + +150 +00:14:27,480 --> 00:14:33,100 +نشتغل على فكرة enucleophile أو electrophile، يعني + +151 +00:14:33,100 --> 00:14:35,540 +هذا enucleophile، هذا enucleophile، هذا + +152 +00:14:35,540 --> 00:14:39,460 +enucleophile، هذا enucleophileتمام؟ و تخيلوا لو + +153 +00:14:39,460 --> 00:14:43,900 +بدأت من هنا و خلته يحل محل ال PR سكرت بهدى .. بهدى + +154 +00:14:43,900 --> 00:14:47,820 +.. بهدى .. الان بعدين بدى اوزن انه برضه افضل + +155 +00:14:47,820 --> 00:14:53,320 +الحلقات احيانا الحلقات الاش الخماسية و السوداسية + +156 +00:14:53,320 --> 00:14:58,480 +فربما كان أنسب شىء انكوا تبدأوا دائما بالإبدال و + +157 +00:14:58,480 --> 00:15:02,500 +كتير مروا علينا أنفلة كنا نبدأ فيها مباشرة احنا + +158 +00:15:02,500 --> 00:15:06,720 +بإيش؟ بالإبدال يعني الان اشتغلوا تحل محل ال PR + +159 +00:15:07,870 --> 00:15:13,550 +تمام؟ مش زعلان كتير لو حد بدأ من هذه واضح؟ وعشان + +160 +00:15:13,550 --> 00:15:18,090 +ايه؟ يعني بنسيب للناس حرية، لكن طبعا ال N-H2O + +161 +00:15:18,090 --> 00:15:21,590 +الأفضل في التفاعل هذي، ال N-H2O هذي بتشبه الأمل، + +162 +00:15:21,590 --> 00:15:26,190 +وبناء على ذلك بدكوا تجيبوا هذه هنا وتطردوا ال PR، + +163 +00:15:26,190 --> 00:15:30,150 +واضح؟ بدكوا تجيبوا هذه هنا وتطردوا ال PR، حيصير في + +164 +00:15:30,150 --> 00:15:30,650 +عندك + +165 +00:15:35,950 --> 00:15:41,350 +C double bond O خلّينا نحط هنا N H هاي ال N + +166 +00:15:41,350 --> 00:15:46,190 +التانية هاي ال carbon الآن بعد هيك هذه ال carbon + +167 +00:15:46,190 --> 00:15:53,190 +شو حاملة اللي هي هذه ال carbon سلفر + +168 +00:15:53,190 --> 00:15:59,470 +و نيترجل واضح أسهل طريقة تحط المركبين لو أنتوا + +169 +00:15:59,470 --> 00:16:02,550 +تخيلتوا أن هنا السلفر و هنا ال نيترجل + +170 +00:16:04,740 --> 00:16:11,060 +بتقدروا تسكروا على حلقة على هذه ال .. ال C double + +171 +00:16:11,060 --> 00:16:15,360 +bond O تهاجموا على ال C double bond O و تسكروا على + +172 +00:16:15,360 --> 00:16:20,800 +حلقة و لو انتوا اتخيلتوا بتهيألي فيه ممكن CH2 + +173 +00:16:20,800 --> 00:16:28,600 +مفقودة بيبقى نحطها لأن ال PR محمولة على CH2 يعني + +174 +00:16:28,600 --> 00:16:31,480 +هذه unatched + +175 +00:16:33,870 --> 00:16:40,710 +carbon و هنا في عندكم اما sulfur او اما نيتروجين + +176 +00:16:40,710 --> 00:16:45,590 +الان بتقدروا تجلبوهم تقدروا تجلبوهم يعني تخلوا ال + +177 +00:16:45,590 --> 00:16:49,090 +sulfur يسكر هنا و تطلع حلقة سداسية فيها sulfur او + +178 +00:16:49,090 --> 00:16:53,130 +تخلوا ال sulfur هنا و تسكروا بإيش بالنيتروجين و + +179 +00:16:53,130 --> 00:16:59,240 +تستكبلوا الجوابتعملوا ال elimination و كل شيء واضح + +180 +00:16:59,240 --> 00:17:03,400 +يعني خليني اركز على الفكرة الأساسية الفكرة + +181 +00:17:03,400 --> 00:17:09,000 +الأساسية هذا substitution كان درسنا الأول واضح هذا + +182 +00:17:09,000 --> 00:17:12,860 +substitution كان درسنا الأول و بعد هيك ان ال + +183 +00:17:12,860 --> 00:17:17,160 +sulfur can act as a nucleophile و مرات كتير اقولنا + +184 +00:17:17,160 --> 00:17:20,900 +تخيلوا ان هذه موجودة بهذا الشكل و هذه عبارة عن S + +185 +00:17:20,900 --> 00:17:25,640 +minusحكينا أكتر من المثال كيف الـ C double bond S + +186 +00:17:25,640 --> 00:17:28,940 +الـ Sulphur فيها بتشتغل كنيوكليوفال هذا ممكن و لو + +187 +00:17:28,940 --> 00:17:33,380 +ناس خلوا الـ C double bond S للخارج و كتبوها on H2 + +188 +00:17:33,380 --> 00:17:40,220 +مع الـ C double bond O بتفاعلوا فهذه المسألة حقيقة + +189 +00:17:40,220 --> 00:17:45,040 +هي تفاعل Di-electrophile مع Di-nucleophile + +190 +00:17:45,040 --> 00:17:51,430 +واحتمالاتهاكثيرة جدا يمكن افضل احتمالين اللي انا + +191 +00:17:51,430 --> 00:17:55,350 +يعني نوّهت لهم اللي هم الحلقات السدسية سواء هان + +192 +00:17:55,350 --> 00:17:59,090 +سلفر و هان نيتروجين او نيتروجين و هان C double + +193 +00:17:59,090 --> 00:18:01,150 +bond بس واضح الفكرة + +194 +00:18:14,070 --> 00:18:18,670 +السؤال التاني الحقيقة سؤال بسيط برضه بحاجة الى + +195 +00:18:18,670 --> 00:18:24,550 +ترتيب ليش لأن انا في عندى هنا ال nucleophile و هنا + +196 +00:18:24,550 --> 00:18:27,370 +في عندى halogen ال halogen دايما شو بيعمل عليها ال + +197 +00:18:27,370 --> 00:18:31,710 +nucleophile من ال organic A substitution اذا هذا + +198 +00:18:31,710 --> 00:18:38,470 +بيهاجم يطرد ال Cl فصار عندكم ال aromatic ring فيها + +199 +00:18:38,470 --> 00:18:40,730 +S و هنا CH2 + +200 +00:18:43,240 --> 00:18:50,820 +وهنا ممكن هيك نتخيلها CH2Cl وهنا إيش في عندكم C + +201 +00:18:50,820 --> 00:18:56,360 +triple bond N الآن لاحظوا هاي المنظر و أعطيتكوا + +202 +00:18:56,360 --> 00:19:03,660 +base إيش بتعمل ال base؟ على CH2 اللي هنا على CH2 + +203 +00:19:03,660 --> 00:19:07,380 +اللي بين ال CL و ال S بناء على ذلك هتعمل الايون + +204 +00:19:07,380 --> 00:19:12,310 +السالقو تاجم هنا و بتكملوا التذكير على ال cyanide + +205 +00:19:12,310 --> 00:19:19,110 +بتكملوا التذكير على ال cyanide فهيكون عندكم S و + +206 +00:19:19,110 --> 00:19:23,630 +هنا double bond NH2 و هاد ال CN + +207 +00:19:29,500 --> 00:19:34,200 +فهذا السؤال أيضا هو السؤال النيكليوفي اللى بيعمل + +208 +00:19:34,200 --> 00:19:39,200 +substitution و بعدين carbon نيكليوفي اللى بنعمله + +209 +00:19:39,200 --> 00:19:43,920 +بال base و بيسكر على ال CN و بتاع لمعظم الجزء اللى + +210 +00:19:43,920 --> 00:19:49,200 +كنا نشرحه كان عبارة عن أمثلة شبيهة بهذا النوع من + +211 +00:19:49,200 --> 00:19:55,240 +الأمثلة و في كل الأحوال هذه الأسئلة هي عبارة عن + +212 +00:19:55,240 --> 00:20:00,380 +أسئلة من ال homework اللى إنتوا جيبتوهيعني لما + +213 +00:20:00,380 --> 00:20:03,880 +قلنا لكوا هاتوا أمثلة تطبيقية من المجلات أنتوا + +214 +00:20:03,880 --> 00:20:08,540 +جبتوا هذه الأسئلة يعني + +215 +00:20:08,540 --> 00:20:11,960 +أنا ماحطيت أي سؤال تركتكوا أنتوا تحطوا الامتحان + +216 +00:20:11,960 --> 00:20:17,260 +الآن قلنا لكوا بدنا أمثلة على الكربين والنيترين + +217 +00:20:17,260 --> 00:20:24,080 +جابت إيمان أن هذا aside و بال heat بدو يصير + +218 +00:20:25,590 --> 00:20:29,950 +النيتريل النيتريل بدو يعمل insertion مش عنده + +219 +00:20:29,950 --> 00:20:33,750 +double bonds من أحيات المبدأ فال insertion الأول + +220 +00:20:33,750 --> 00:20:39,590 +على ال N عمل حلقة خماسية الآن ال insertion من + +221 +00:20:39,590 --> 00:20:44,530 +التاني على هذه ال H بس مجرد أنكم ترتبوا شكل الجزء + +222 +00:20:44,530 --> 00:20:50,330 +يعني لو جربتوا ترتبوا شكل الجزء S double bond O + +223 +00:20:50,330 --> 00:20:54,190 +double bond O وحطيته هنا N وحطيته + +224 +00:20:57,910 --> 00:21:03,650 +البنزينة ها دي هان وهنا نيتروجين عملت insertion + +225 +00:21:03,650 --> 00:21:07,910 +على البنزينة واضح بيطلع عندكوا ايش حلقة سباعية + +226 +00:21:07,910 --> 00:21:13,870 +واحد اتنين تلاتة اربعة خمسة ستة ستة حلقة سباعية + +227 +00:21:13,870 --> 00:21:18,490 +واللي اشتغلوا طلع عندهم الناتجين زي ما هم بتدعوا + +228 +00:21:19,240 --> 00:21:23,600 +يعني insertion هنا هنا لو كان فيه إمكانية كان طلعة + +229 +00:21:23,600 --> 00:21:27,900 +السداسية هنا أبعد شوية هتطلع السباعية فال + +230 +00:21:27,900 --> 00:21:30,420 +insertion هذا عامل حلقة خمسية و ال insertion هنا + +231 +00:21:30,420 --> 00:21:45,100 +عامل حلقة سباعية هذا + +232 +00:21:45,100 --> 00:21:51,290 +المثال طبعامعتمد بشكل أساسي على أن ال acid + +233 +00:21:51,290 --> 00:21:55,990 +chlorides تفاعلهم الأساسي ال substitution يعني + +234 +00:21:55,990 --> 00:22:02,710 +مابدناش ننسى اللي هي المعلومات العامة جدا في + +235 +00:22:02,710 --> 00:22:05,630 +الكيميا اللي احنا أخدناها بناء على ذلك هيكون أنها + +236 +00:22:05,630 --> 00:22:08,350 +نسيطة بال bond O NH + +237 +00:22:11,330 --> 00:22:17,590 +ان اتش تو ان اتش + +238 +00:22:17,590 --> 00:22:21,490 +تو ان اتش + +239 +00:22:21,490 --> 00:22:29,570 +تو ان اتش تو ان اتش تو ان اتش تو ان اتش تو ان اتش + +240 +00:22:29,570 --> 00:22:32,870 +تو ان اتش تو ان اتش تو ان اتش تو ان اتش تو ان اتش + +241 +00:22:32,870 --> 00:22:38,350 +تو ان اتش تو ان اتش تو ان اتش تو ان اتش تو ان اتش + +242 +00:22:38,350 --> 00:22:38,450 +تو ان اتش تو ان اتش تو ان اتش تو ان اتش تو ان اتش + +243 +00:22:38,450 --> 00:22:38,870 +تو ان اتش تو ان اتش تو ان اتش تو ان اتش تو ان اتش + +244 +00:22:38,870 --> 00:22:38,990 +تو ان اتش تو ان اتش تو ان اتش تو ان اتش تو ان اتش + +245 +00:22:38,990 --> 00:22:41,170 +تو ان اتش تو ان اتش + +246 +00:22:46,430 --> 00:22:55,270 +Fennel هنا C double bond O NH و هنا N double bond + +247 +00:22:55,270 --> 00:23:05,230 +C طبعا هذه خلوها CH3 هنا CH2 هنا C double bond O + +248 +00:23:05,230 --> 00:23:08,470 +CH3 + +249 +00:23:08,470 --> 00:23:11,390 +واضح؟ + +250 +00:23:12,690 --> 00:23:16,030 +هذه كانت C double bond O و C double bond O الان + +251 +00:23:16,030 --> 00:23:21,990 +ايش ضال عندكم من nucleophile و Electrophile الان H + +252 +00:23:21,990 --> 00:23:28,110 +و C double bond O الان H و C double bond O وبناء + +253 +00:23:28,110 --> 00:23:31,790 +على ذلك لو هدولة بتكون تيجي تساكرهم على نفس الاشي + +254 +00:23:31,790 --> 00:23:39,300 +هيعطوني حلقة معقولةطبعا ممكن نعود نرتب المنظر يعني + +255 +00:23:39,300 --> 00:23:42,100 +الإنسان بيشتغل فيه قلم لرصاص و بيعود يرتب واحد + +256 +00:23:42,100 --> 00:23:46,680 +اتنين تلاتة اربعة خمسة و بيعمل ال elimination + +257 +00:23:46,680 --> 00:23:53,080 +اللازمة واضح؟ حلقات خمسية فهذا عبارة عن + +258 +00:23:53,080 --> 00:23:58,180 +substitution عادي عبارة عن addition عادي عبارة عن + +259 +00:23:58,180 --> 00:24:01,440 +addition تاني انا اتش على c double bond او بيصير + +260 +00:24:01,440 --> 00:24:07,470 +عندي o اتش مع اتش من هنابيعملوا إيش في النهاية ال + +261 +00:24:07,470 --> 00:24:12,130 +double bond انا فكرت انه ال N H نعملها double bond + +262 +00:24:12,130 --> 00:24:15,970 +و ال O بتصير negative و بتهجم على الكربونين التاني + +263 +00:24:15,970 --> 00:24:21,510 +اي N H فيهم اللي هجمت على الكربونين ال N هادي .. + +264 +00:24:21,510 --> 00:24:24,750 +اللي هجمت على الكربونين هادي؟ هاي اللي تحت ال .. + +265 +00:24:24,750 --> 00:24:28,510 +طيب هادي .. ها دي شتت ال H حطيتها double bond و ال + +266 +00:24:28,510 --> 00:24:32,450 +O صارت negative و هجمت على الكربونين الأولى، صارت + +267 +00:24:32,450 --> 00:24:36,330 +صبعية، حلقة صبعيةفى كل الأحوال بيكون طبعا less + +268 +00:24:36,330 --> 00:24:40,470 +likely يعني دائما اتعودوا تشوفوا الأمور من الزاوية + +269 +00:24:40,470 --> 00:24:49,990 +الاشه من الزاوية الواضحة أحيانا و الدائرة الآن + +270 +00:24:49,990 --> 00:24:56,120 +هذا تفاعل على triple bond ل triple bondبتم عليها + +271 +00:24:56,120 --> 00:25:00,440 +Cyclization بلزا موجود الـ Eucleophil يهاجم عليها + +272 +00:25:00,440 --> 00:25:04,120 +الان احنا ريحناكم كم ال Eucleophil عندكم هذا ال + +273 +00:25:04,120 --> 00:25:08,440 +Oxygen ال Eucleophil و هذا ال Nitrogen ال + +274 +00:25:08,440 --> 00:25:13,180 +Eucleophil حركوهم مش هذا single bond بقدر احركهم + +275 +00:25:13,180 --> 00:25:19,020 +الان لما بدهم يسكروا على ال triple bond بيسكروا + +276 +00:25:19,020 --> 00:25:25,770 +اما ها او ها الان انا ريحتكم قلتله بدي حلقاتإذا + +277 +00:25:25,770 --> 00:25:31,050 +هذا الإغلاق بهذا الشكل بيطلع حلقة خمسية نتخيل زوج + +278 +00:25:31,050 --> 00:25:35,750 +الإلكترونات تتحرك هكذا و لو لفنا ال N بتصير ال N + +279 +00:25:35,750 --> 00:25:40,070 +هان و ال C double bond O هان بيعمل حلقة خمسية إذا + +280 +00:25:40,070 --> 00:25:47,510 +التذكير على هذا الطرف تحديدا مرة بال Oو مرة بال N + +281 +00:25:47,510 --> 00:25:51,410 +طبعا ال O بتسكر اكيد لما يكون جانب N ان هاي زوجي + +282 +00:25:51,410 --> 00:25:55,050 +الإلكترونات بتحرك هيك وهذه بتسكر واخدنا اكثر من + +283 +00:25:55,050 --> 00:25:59,930 +مثال تحديدا شبيهين بهذه او ال N نفسنا نكون مبدلين + +284 +00:25:59,930 --> 00:26:03,070 +كاتبين أنا ال N وانا ال C double bond O في + +285 +00:26:03,070 --> 00:26:06,910 +الحالتين هذا اغلاق لحلقة خمسية لكن لو هتفكر يعمل + +286 +00:26:06,910 --> 00:26:11,430 +endocyclization سواء بال O او بال N هيطلع حلقات + +287 +00:26:11,840 --> 00:26:15,400 +سداسية لو حط 100 أكتر ان ييجي يعمل ال cycleization + +288 +00:26:15,400 --> 00:26:20,000 +على ال E start هيطلع حلقات أكبر الأصل في اللي + +289 +00:26:20,000 --> 00:26:23,820 +بيشتغل كيميا يكون يفكر بكل شيء ويمكن كان احنا + +290 +00:26:23,820 --> 00:26:29,100 +منهجنا حقيقة ان نعودكم يتفكروا في المسألة من وجهات + +291 +00:26:29,100 --> 00:26:35,700 +نظر مختلفة لكن هدولة الناتجين اللي طلعوا أجابتهم + +292 +00:26:35,700 --> 00:26:38,800 +منار + +293 +00:26:42,220 --> 00:26:51,080 +الان هذا السؤال سؤال بسيط لكن للأسف ان انا كان قصد + +294 +00:26:51,080 --> 00:26:55,740 +اده من three chlorobrobanol فلاني ماكتبتش + +295 +00:26:55,740 --> 00:27:00,460 +لبروبانول لغيت السؤال لكن بكل الأحوال لما بتقول + +296 +00:27:00,460 --> 00:27:07,300 +بروبانول هي تلات ذرات وهي OH وهي CLيعني لما نشوفه + +297 +00:27:07,300 --> 00:27:10,820 +من ال three chlorobrobanol الان لاحظوا انا جاي بال + +298 +00:27:10,820 --> 00:27:17,720 +O وال C وال C واحد اتنين طبعا ال CL طالعة من هذه + +299 +00:27:17,720 --> 00:27:21,860 +الكربون هاي ال probanol التلات كربونات ال three + +300 +00:27:21,860 --> 00:27:26,080 +chlorobrobanol الان لاحظوا كربون تنتين تلاتة اجاني + +301 +00:27:26,080 --> 00:27:32,300 +CNH2 ال CNH2 ايش بترجمها على طول انا CN اذا انا لو + +302 +00:27:32,300 --> 00:27:41,250 +عملت CN minus صار عندىهي هدولة التلاتة وهنا C + +303 +00:27:41,250 --> 00:27:48,350 +triple bond N وهي ال OH اكتمل + +304 +00:27:48,350 --> 00:27:53,150 +السؤال انه هذه ال O تسكر هنا بيصير ايمين انا مين + +305 +00:27:53,150 --> 00:27:56,230 +واضح + +306 +00:27:56,230 --> 00:28:03,130 +يعني ماكنش في هالفكرة الكبيرة كتير يعني اقصده + +307 +00:28:05,360 --> 00:28:11,660 +هذا السؤال الاصل انه لما نعطيكوا نقطة البداية فيه + +308 +00:28:11,660 --> 00:28:15,500 +برضه انه يكون سهل يعني لما بد الأثل اثري اكزو + +309 +00:28:15,500 --> 00:28:20,460 +بيوتانوات لاحظوا معي هاي ال C double bond O O أثل + +310 +00:28:20,460 --> 00:28:25,540 +طبعا ال O أثل شايفين انتوا في السؤال O أثل اذا + +311 +00:28:25,540 --> 00:28:30,660 +طردت مش مشكلة بعدين هاي واحد تنين هاي تلاتة هاي + +312 +00:28:30,660 --> 00:28:31,500 +اثري اكزو + +313 +00:28:34,110 --> 00:28:37,710 +لاحظوا الناس اللي بيفكروا إذا عندكم هذا ال إثل one + +314 +00:28:37,710 --> 00:28:41,410 +two three four three أكزو بيوتانويت هتقولوا هاي ال + +315 +00:28:41,410 --> 00:28:48,630 +C double bond O CH2 هادي C double bond O اللي كانت + +316 +00:28:48,630 --> 00:28:54,530 +هنا إذا كل القصة صارت unatched فقط + +317 +00:28:56,670 --> 00:29:00,850 +يعني مجرد ان ارسم هذا بشكل سليم و اقول Hydroxyl + +318 +00:29:00,850 --> 00:29:08,310 +amine C double bond NO Hydroxyl amine هنا بيصير + +319 +00:29:08,310 --> 00:29:11,930 +عندكوا addition N H2O على C double bond O وهنا + +320 +00:29:11,930 --> 00:29:18,130 +بيصير عندى substitution واضح؟ + +321 +00:29:18,130 --> 00:29:25,280 +addition و substitution على اي حال هذه كانتأسئلة + +322 +00:29:25,280 --> 00:29:31,240 +لامتحان، لمتحان محلولة وبكل الأحوال بتحسوا أنها + +323 +00:29:31,240 --> 00:29:37,880 +منصمين الأشياء اللي اتعلمناها لكن بالتأكيد الناس + +324 +00:29:37,880 --> 00:29:43,320 +في امتحان مش كلهم هيجيبه علامات كاملة ومش كلهم + +325 +00:29:43,320 --> 00:29:47,600 +يعني هينزل عليهم فتوح العارفين هذا أمر طبيعي في + +326 +00:29:47,600 --> 00:29:51,840 +الحياة يعني طبيعي جدا، مظبوط ولا لأ؟ + +327 +00:29:54,840 --> 00:29:59,680 +هك حال الدنيا ربنا سبحانه وتعالى حتى يعني فضل قال + +328 +00:29:59,680 --> 00:30:06,400 +ورفعنا بعضكم فوق بعض درجات اللي .. حال + +329 +00:30:06,400 --> 00:30:17,540 +الدنيا مش منطقة نقاش هذه الآن + +330 +00:30:17,540 --> 00:30:21,160 +خلينا نبتدأ في درسنا الجديد + +331 +00:31:36,700 --> 00:31:43,060 +دارسنا اليوم أمثلة تطبيقية على تحضير بعض الحلقات + +332 +00:31:43,060 --> 00:31:49,240 +المشهورة بنبتدأ بالحلقات السوداسية وعلى رأس + +333 +00:31:49,240 --> 00:31:52,320 +الحلقات السوداسية ال aromatic rings اللي هي + +334 +00:31:52,320 --> 00:31:53,620 +البريدي + +335 +00:31:55,430 --> 00:32:01,250 +طبعا لو بدنا نحكي عن البردين بالتفصيل البردين is a + +336 +00:32:01,250 --> 00:32:04,490 +water miscible liquid نتعرف عليه أكتر لأنه مرات + +337 +00:32:04,490 --> 00:32:08,450 +مار معاكم ك organic base في التفاعلات و استعمال + +338 +00:32:10,630 --> 00:32:15,210 +بدوب في الميه انتبهوا جيدا ال boiling point تبعته + +339 +00:32:15,210 --> 00:32:19,490 +115 يعني لو بتشتغلوا عليه بتفاعل هيغلبكوا في + +340 +00:32:19,490 --> 00:32:24,810 +التبخير طبعا with an unpleasant odor ريحته سيئة + +341 +00:32:24,810 --> 00:32:29,050 +جدا و بيقولوا كمان خاطيرة الآن هذا الكلام بيخليكوا + +342 +00:32:29,050 --> 00:32:33,270 +لو كنتوا بتشتغلوا تفاعل أو بتصمموا تفاعل قدر + +343 +00:32:33,270 --> 00:32:37,170 +الإمكان إذا كان بإمكانكوا تستبدلوا ال peridine ك + +344 +00:32:37,170 --> 00:32:41,600 +organic baseال base تاني أهوان شوية منه بيكون أفضل + +345 +00:32:41,600 --> 00:32:46,320 +يعني مابيكونش هو الخيار الأفضل البريدين من ناحيتين + +346 +00:32:46,320 --> 00:32:52,200 +من ناحية رائحته السيئة خطورته و نقطة غليانه + +347 +00:32:52,200 --> 00:32:59,060 +العالية فأنا مثلا لو كنت بكتير تفاعلات بدي organic + +348 +00:32:59,060 --> 00:33:05,340 +base و استعملت ال triethylamine base مشهورة and + +349 +00:33:06,340 --> 00:33:11,400 +Ethyl-3 Try Ethyl-amine أهون كتير من البريدين و من + +350 +00:33:11,400 --> 00:33:15,260 +ناحية تبخرها أسهل لما بده أخلص التفاعل بدها تتبخر + +351 +00:33:15,260 --> 00:33:19,920 +أسهل من البريدين واضح يعني مايكونش البريدين الخيار + +352 +00:33:19,920 --> 00:33:25,220 +الأول لو كنا بنستعمل ايش organic base نتيجة + +353 +00:33:25,220 --> 00:33:30,480 +هالمشاكل اللي حكيناها طبعا هو polar solvent على + +354 +00:33:30,480 --> 00:33:36,140 +العين والرأس baseال BKA تبعته خمسة يعني ال + +355 +00:33:36,140 --> 00:33:40,040 +basicity تبعته نوعا ما بالنسبة لل weak bases عالية + +356 +00:33:40,040 --> 00:33:43,300 +يعني ما بنقارنهش احنا بال N A O H على سبيل المثال + +357 +00:33:43,300 --> 00:33:47,000 +ال strong bases لكن لل weak bases يعني لو بدنا + +358 +00:33:47,000 --> 00:33:51,860 +نقارنه بالمية مثلا as a base لأ البردين اعلى كتير + +359 +00:33:52,510 --> 00:33:57,230 +يمكن سبق اننا حكينا لكم ان البريدين دائما الناس + +360 +00:33:57,230 --> 00:34:01,330 +لما بيذكروا بيقارنوا ال basicity تبعته مع ايش؟ مع + +361 +00:34:01,330 --> 00:34:05,770 +ال by role واضح؟ على اي اساس طبعا هم بيقارنوا على + +362 +00:34:05,770 --> 00:34:09,250 +اساس ان البريدين فيه على ال nitrogen تبعته زوج + +363 +00:34:09,250 --> 00:34:13,570 +الإلكترونات لكن هذه زوج الإلكترونات اللى موجودة + +364 +00:34:13,570 --> 00:34:17,430 +على ال nitrogen خارج ال aromatic system يعني هنا + +365 +00:34:17,430 --> 00:34:22,990 +في عندى ستة by electronsلحالمهم وزوج الإلكترونات + +366 +00:34:22,990 --> 00:34:27,250 +هذا في الخارج، الآن في ال buy roll عندي أنا زوج + +367 +00:34:27,250 --> 00:34:31,510 +إلكترونات لكن زوج الإلكترونات هو جزء من ال + +368 +00:34:31,510 --> 00:34:35,150 +aromatic system عشانك هذا زوج الإلكترونات + +369 +00:34:35,150 --> 00:34:39,970 +available to be donated يعني جاهز أنه يُعطى للخارج + +370 +00:34:39,970 --> 00:34:44,890 +و هذا معناه base، ال base هي اللي بتعطي إيش؟بينما + +371 +00:34:44,890 --> 00:34:48,570 +هذا زوج الالكترونات is part of the aromatic system + +372 +00:34:48,570 --> 00:34:53,950 +مابينعطاش للخارج ولذلك لما بنيجي بنسأل more basic + +373 +00:34:53,950 --> 00:34:59,250 +البريدين ولا ال بيرولالبريدين الان بيصيروا في + +374 +00:34:59,250 --> 00:35:03,970 +الكيميا الحلقية حقيقة و مرات كتير بتقرؤوها بمقالات + +375 +00:35:03,970 --> 00:35:09,090 +لما بيتكلموا على ال nitrogen على ال nitrogen اللي + +376 +00:35:09,090 --> 00:35:13,710 +في الحلقات بيصيروا يوصفوهم بيقولوا nitrogen زي + +377 +00:35:13,710 --> 00:35:16,930 +تبعت البريدين او nitrogen زي تبعت ال بيرول + +378 +00:35:16,930 --> 00:35:22,310 +فبيستعملوا مصطلح peridine like nitrogen الان + +379 +00:35:22,310 --> 00:35:26,850 +البريدين like nitrogen بهذا الشكلهي ال nitrogen .. + +380 +00:35:26,850 --> 00:35:33,890 +هي ال nitrogen اللي عليها إيش؟اللي عليها double + +381 +00:35:33,890 --> 00:35:37,990 +bond بهذا الشكل الـ pyrrole-like نيتروجين + +382 +00:35:37,990 --> 00:35:42,830 +النيتروجين اللي حاملة ان اتش واضح؟ ولذلك لو مثلا + +383 +00:35:42,830 --> 00:35:47,410 +انا بدي اخد عند النزوم الـ triazole على سبيل + +384 +00:35:47,410 --> 00:35:52,890 +المثال او اميدازول هلاحظ في الاميدازول ان في عندي + +385 +00:35:52,890 --> 00:35:56,770 +pyridine-like نيتروجين وفي عندي pyrrole-like + +386 +00:35:56,770 --> 00:36:01,150 +نيتروجينواضح يعني هذه ال nitrogen زي نيتروجين + +387 +00:36:01,150 --> 00:36:05,430 +البريدين و لو اتطلعت على زوج الإلكترونات اللي فيها + +388 +00:36:05,430 --> 00:36:08,910 +موجود زوج إلكترونات خارجي هذه ال nitrogen زي + +389 +00:36:08,910 --> 00:36:12,310 +نيتروجين الفيرول هذا زوج الإلكترونات part of the + +390 +00:36:12,310 --> 00:36:16,530 +aromatic system of اميدازول الاميدازول aromatic هي + +391 +00:36:16,530 --> 00:36:23,620 +اتنين اربعة و زوج الإلكتروناتستة واضح فبتلاحظوا + +392 +00:36:23,620 --> 00:36:28,080 +هذا المصطلح موجود بيرول like نيتروجين و بيريدين + +393 +00:36:28,080 --> 00:36:31,280 +like نيتروجين يعني ال نيتروجين اللي بتشبه نيتروجين + +394 +00:36:31,280 --> 00:36:35,360 +ال بيرول و ال نيتروجين اللي بتشبه ال نيتروجين اللي + +395 +00:36:35,360 --> 00:36:43,650 +موجودة في ال بيريدينأما من المراكبات البريدين ال + +396 +00:36:43,650 --> 00:36:48,290 +بيكولين ال بيكولين اللي هم ال مثل بيريدين طبعا + +397 +00:36:48,290 --> 00:36:53,070 +هيكون موجود يا على موقع اتنين يعني اورثو بيريد ال + +398 +00:36:53,070 --> 00:36:58,350 +بيكولينيا على موقع تلاتة ميتا بيكولين يا على موقع + +399 +00:36:58,350 --> 00:37:03,470 +أربعة بارا بيكولين فإذا قرأنا بيكولين اللي هي ال + +400 +00:37:03,470 --> 00:37:08,990 +مثل بيريدينز كام بيكولين موجود تلاتة يا بتكون + +401 +00:37:08,990 --> 00:37:13,150 +المثل على موقع اتنين او تلاتة او اربعة لاحظوا لو + +402 +00:37:13,150 --> 00:37:18,210 +احنا عملنا oxidation لل aliphatic sided chain اللي + +403 +00:37:18,210 --> 00:37:21,910 +هنا المثل هذا بتبقى acid ل acid + +404 +00:37:27,320 --> 00:37:32,870 +البرادين اللي عليه acid على موقع تلاتةواحد اتنين + +405 +00:37:32,870 --> 00:37:37,650 +تلاتة بيسموه نيكوتينك أسد يعني بيصير اسم لازم + +406 +00:37:37,650 --> 00:37:42,430 +ينحفظ عند الطلاب نيكوتينك أسد واللي على موقع أربعة + +407 +00:37:42,430 --> 00:37:47,470 +ايزو نيكوتينك أسد طبعا ايش السبب انه هذا سموه + +408 +00:37:47,470 --> 00:37:52,150 +نيكوتينك أسد هذا نسبة الى النكوتين النكوتين اللي + +409 +00:37:52,150 --> 00:37:57,910 +وين موجود في السجائر النكوتين هو عبارة عن بيريدين + +410 +00:37:57,910 --> 00:38:04,580 +حامل بيروليدينالان من وين متصل البروليدين هذا في + +411 +00:38:04,580 --> 00:38:10,260 +البريدين؟ من موقع تلاتة فلأن الاتصال هنا للاسد تم + +412 +00:38:10,260 --> 00:38:14,440 +من موقع تلاتة فصار هذا الاتصال شبيه باتصال من + +413 +00:38:14,440 --> 00:38:19,960 +نيكوتين ولذلك الحامض اللي متصل من تلاتة سموه + +414 +00:38:20,700 --> 00:38:25,500 +نكوتينك أسد طبعا لما يلاجوا الحامض اللى متصل من + +415 +00:38:25,500 --> 00:38:31,060 +أربعة شو سموه ايزو نكوتينك أسد فإذا قرأنا نكوتينك + +416 +00:38:31,060 --> 00:38:35,200 +و ايزو نكوتينك أسد معنا ذلك حسب طبيعة الاتصال + +417 +00:38:35,200 --> 00:38:39,660 +النكوتينك هو الحامض اللى متصل على البريدين من موقع + +418 +00:38:39,660 --> 00:38:50,810 +تلاتة الآن كيف بنحضر البريدينالبريديل حقيقة له طرق + +419 +00:38:50,810 --> 00:38:55,850 +كتيرة للتحضير اكثر من طريقة طرق كثيرة جدا من هذه + +420 +00:38:55,850 --> 00:39:00,550 +الطرق ال hands synthesis في ال hands synthesis + +421 +00:39:00,550 --> 00:39:04,930 +بيخلطوا خلطة واحدة اهوية واحدة one three + +422 +00:39:04,930 --> 00:39:11,780 +-dicarbonyl compound مع امونيا مع الديهيدالان + +423 +00:39:11,780 --> 00:39:16,460 +هدولة لما خلطوهم طلعو لهم dihydroberidine حقيقة + +424 +00:39:16,460 --> 00:39:22,080 +يعني beridine نقصه double bond الان لو اجينا نفصل + +425 +00:39:22,080 --> 00:39:26,140 +هذا ال synthesis لو اجينا نفصل هذا ال synthesis شو + +426 +00:39:26,140 --> 00:39:30,940 +ال 1,3-dicarbonyl compound اللي بيستعملوهبيستعملوا + +427 +00:39:30,940 --> 00:39:34,240 +Beta Keto Easter يعني هنا تطلعوا فيه عندكوا Easter + +428 +00:39:34,240 --> 00:39:40,280 +C ضب البند O و O مثل Easter هذه موقع Alpha وهذه + +429 +00:39:40,280 --> 00:39:48,040 +موقع Beta إذا أنا هنا استعملت Beta Keto Easter + +430 +00:39:48,920 --> 00:39:54,060 +Estar هذا هنا في عند CW بندقه وانا CW بندقه + +431 +00:39:54,060 --> 00:39:58,700 +العلاقة بينهم احد اتنين تلاتة one three dicarbonyl + +432 +00:39:58,700 --> 00:40:04,620 +compound الان هذا ال beta key to Estar لو فعلناه + +433 +00:40:04,620 --> 00:40:07,840 +مع ال ammonia هم عادة بيخلطوا كل شيء بس بنحاول + +434 +00:40:07,840 --> 00:40:12,780 +نفسر كيف صارت التفاعللو فعلنا مع ال ammonia امونيا + +435 +00:40:12,780 --> 00:40:17,540 +مع c double bond او شو بتعمل امين و الامين بيعمل + +436 +00:40:17,540 --> 00:40:24,180 +انامين توتو ميريزم اذا هي ال ammonia مع beta keto + +437 +00:40:24,180 --> 00:40:30,610 +ester اعطتني الانامين تماممازال عندي ال 1,3 + +438 +00:40:30,610 --> 00:40:34,410 +-dicarbonyl compound موجود بدنا نفعله مع ال + +439 +00:40:34,410 --> 00:40:39,090 +الديهايد الان لو هذا المركب نفسه أخدته مرة تانية + +440 +00:40:39,090 --> 00:40:43,090 +طبعا انا ال ammonia عندي موجودة ك base ال ammonia + +441 +00:40:43,090 --> 00:40:49,350 +موجودة ك base و عندي ال activated hydrogen بين E + +442 +00:40:49,350 --> 00:40:53,410 +star و C double bond O يعني بين تلتين C double + +443 +00:40:53,410 --> 00:40:58,170 +bond O اذا هنا ممكن يصير عندي ايونسالي بيهاجم هنا + +444 +00:40:58,170 --> 00:41:03,130 +يعمل OH وكمان يعمل elimination صار عنده C double + +445 +00:41:03,130 --> 00:41:07,030 +bond يعني هذه اللي كانت AR C double bond O تم + +446 +00:41:07,030 --> 00:41:15,110 +الهجوم من هنا بيصير OH و OH مع H elimination واضح؟ + +447 +00:41:15,110 --> 00:41:20,490 +هاي؟أتكون عندى كمان جزء هذا الجزء لو بدى اعطيه وصف + +448 +00:41:20,490 --> 00:41:27,010 +هو in on مشهد ال c double bond o on وفي ال keen in + +449 +00:41:27,010 --> 00:41:31,530 +on طبعا لو بتتطلع عليه انتوا من زاوية تانية هو + +450 +00:41:31,530 --> 00:41:35,490 +عبارة عن alpha beta unsaturated carbonyl compound + +451 +00:41:35,490 --> 00:41:39,590 +يعني لو قولت هى c double bond o هى موقع alpha هى + +452 +00:41:39,590 --> 00:41:46,520 +موقع beta هذا ال in on عبارة عن ايشAlpha Beta + +453 +00:41:46,520 --> 00:41:52,980 +Unsaturated Carbonyl Compound الان اذا انا اخدت ال + +454 +00:41:52,980 --> 00:41:57,420 +one three by carbonyl compound مرتين مرة مع ال + +455 +00:41:57,420 --> 00:42:02,860 +ammonia عملت enamine ومرة مع ال aldehyde وعملت + +456 +00:42:02,860 --> 00:42:09,680 +enone الان بدي اخلط ال enamine و ال enoneبدفع + +457 +00:42:09,680 --> 00:42:15,740 +للانامين والانون الان ضلكم تذكرين ان هذا alpha + +458 +00:42:15,740 --> 00:42:19,620 +beta unsaturated carbonyl compound وال alpha beta + +459 +00:42:19,620 --> 00:42:23,400 +unsaturated carbonyl compound له تفاعل مشهور جدا + +460 +00:42:23,400 --> 00:42:30,400 +من متذكراه Michael additionمايكل اديشن انه ييجي + +461 +00:42:30,400 --> 00:42:34,020 +نيوكليوفايل بيهاجم على المكان اللي بعيد في ال + +462 +00:42:34,020 --> 00:42:39,640 +double bond تمام؟ الان لو احنا بدنا نفهم حقيقة + +463 +00:42:39,640 --> 00:42:46,560 +المايكل اديشن هتشوفوه بالمحصلة هو إضافة على هذا ال + +464 +00:42:46,560 --> 00:42:51,910 +double bond تمام؟يعني على موقع واحد وع موقع اتنين + +465 +00:42:51,910 --> 00:42:56,990 +لكن ال michael edition لما بنطلع عليه بعمك بنقول + +466 +00:42:56,990 --> 00:43:03,750 +عنه one four edition بنقولش عنه one two edition لأ + +467 +00:43:03,750 --> 00:43:07,850 +بنقول عن ال michael edition one four edition خليني + +468 +00:43:07,850 --> 00:43:13,870 +اوضحلكوا هذه النقطة بشكل منفصل ليش ال michael + +469 +00:43:13,870 --> 00:43:20,000 +edition بنسميه احنا one four editionلو انا اتخيلت + +470 +00:43:20,000 --> 00:43:25,460 +ان هاي في عندى زي هيك و هاي C double bond O و هان + +471 +00:43:25,460 --> 00:43:34,080 +ال nucleophile نفترض RNH2 تمام الان وين عادة بده + +472 +00:43:34,080 --> 00:43:39,960 +تهاجم ال RNH2 بده تهاجم على هذا الموقع okay لما + +473 +00:43:39,960 --> 00:43:45,920 +تهاجم هان هذه بده تتحرك بهذا الشكل هذه بده تتحرك + +474 +00:43:45,920 --> 00:43:54,320 +بهذا الشكلبناء على ذلك هيصير عندى هاي الجزء اللى + +475 +00:43:54,320 --> 00:44:03,740 +موجود بالأصمر وهنا ايجى عندى N H R ال double bond + +476 +00:44:03,740 --> 00:44:15,930 +صارت وين؟ هنا و ال O هذه أخدت ال Hما يصارت O- أخدت + +477 +00:44:15,930 --> 00:44:24,930 +الـ H الان لو اتطلعت 1 2 3 4 اذا الإضافة هنا وين + +478 +00:44:24,930 --> 00:44:30,310 +تمت؟ على 1 و 4 فمن هنا احنا بنقول this is one four + +479 +00:44:30,310 --> 00:44:35,990 +addition ال Michael addition الان بعد ما عملنا هذا + +480 +00:44:35,990 --> 00:44:41,220 +الكلام بنجيب نتطلع على الناتج اللي طلع عندناالنتج + +481 +00:44:41,220 --> 00:44:49,700 +اللي طلع عندنا هو عبارة عن in all in all الان ال + +482 +00:44:49,700 --> 00:44:53,180 +in all في الaliphatic compounds stable ولا + +483 +00:44:53,180 --> 00:44:59,040 +unstable؟ unstable برجع لإيش؟ ل ال keto system + +484 +00:44:59,040 --> 00:45:03,000 +افترضوا هنا كان عندكم أي شغل مش فارق أيضا اه إذا + +485 +00:45:03,000 --> 00:45:07,500 +هذا لما بدي ارجع ل ال keto form وين هترجع ال H؟ + +486 +00:45:09,230 --> 00:45:14,790 +هترجع على موقع اتنين هيصير عندى c double bond o + +487 +00:45:14,790 --> 00:45:20,390 +هيصار key to system وهذه موجودة هنا وهذه هنا الآن + +488 +00:45:20,390 --> 00:45:34,090 +صار عندنا هنا NHR وهذه الـ HR ففي المحصلة بيّن + +489 +00:45:34,090 --> 00:45:40,240 +مايكل اديشن one two editionالميكل اديشن المحصلته + +490 +00:45:40,240 --> 00:45:43,960 +one two addition كانت هذه double bond صارت single + +491 +00:45:43,960 --> 00:45:48,720 +bond وهيأجوا two new sigma bonds لكن from let's + +492 +00:45:48,720 --> 00:45:53,760 +say ميكانيستيك point of view هذا عبارة عن one four + +493 +00:45:53,760 --> 00:45:58,020 +addition ولذلك مرات بتقرأوا على الميكل اديشن لما + +494 +00:45:58,020 --> 00:46:01,700 +بتنافذوا انتوا ومابتكونش ميكانيزم ولا إشي بتكونوا + +495 +00:46:01,700 --> 00:46:04,200 +تلغوا ال double bond و تحطوا هنا ال nucleophile و + +496 +00:46:04,200 --> 00:46:08,960 +هنا ال H خلصنالكن لما نقرأ عنه انه one four + +497 +00:46:08,960 --> 00:46:12,840 +edition بدنا نكون فاهمين ليش اتسمى ال michael + +498 +00:46:12,840 --> 00:46:14,860 +edition one four edition + +499 +00:46:25,250 --> 00:46:31,970 +نرجع لاصحابنا اللي هم مين الامين و الانامين + +500 +00:46:31,970 --> 00:46:39,130 +الانامين و الانون الان اذا كان لنيوكليوفايل اذا + +501 +00:46:39,130 --> 00:46:43,050 +كان لنيوكليوفايل اللي بده يعمل ال michael addition + +502 +00:46:43,050 --> 00:46:47,030 +يعني انا الان بده اعمل ال michael additionأنا هى + +503 +00:46:47,030 --> 00:46:50,010 +عندى ال alpha beta unsaturated carbonyl compound و + +504 +00:46:50,010 --> 00:46:54,010 +بدى أعمل عليه ال michael addition كمحصلة ايش هيصف + +505 +00:46:54,010 --> 00:46:58,050 +عند ال michael addition على 1 و 2 صح بسميه انا + +506 +00:46:58,050 --> 00:47:03,050 +ايش؟one four addition لكن محصلته نهائية على هذا + +507 +00:47:03,050 --> 00:47:08,890 +الموقع الان اذا كان لنيوكليوفايل مش نيوكليوفايل + +508 +00:47:08,890 --> 00:47:13,650 +عادي واضح زي ما كتبنا RNH2 لأ كان عبارة عن أزواج + +509 +00:47:13,650 --> 00:47:17,810 +إلكترونات هاجيبهم بالشكل هذا يعني هاي عندكم ال + +510 +00:47:17,810 --> 00:47:23,230 +nitrogen حاركوها بهذا الشكل هذه ال double bond + +511 +00:47:23,230 --> 00:47:28,770 +خلوها هي ال by تروح نيوكليوفايل هنا و في الآخروين + +512 +00:47:28,770 --> 00:47:35,470 +هيجي ال H؟ على هذا الموقع طبعا هذه صارت لما اتحركت + +513 +00:47:35,470 --> 00:47:41,430 +ايمين ممكن نعود و نرجعها؟ لقينا مين، الآن هنا تمت + +514 +00:47:41,430 --> 00:47:49,570 +الإضافة اللي هي في النهاية صفية إيش؟ زي ما اتفقنا، + +515 +00:47:49,570 --> 00:47:55,960 +على موقع واحد و اتنينكمحصلة نائية لكن ايش سمينا + +516 +00:47:55,960 --> 00:48:00,300 +الإضافة احنا لان اتحركنا بهذا الشكل conjugate + +517 +00:48:00,300 --> 00:48:04,860 +addition ف ال conjugate addition هي نوع من ال + +518 +00:48:04,860 --> 00:48:08,100 +michael addition لكن احنا بتحرك double poles و + +519 +00:48:08,100 --> 00:48:12,800 +إلكترونات واضح مش ال eucleophile عادي فعشان ايك + +520 +00:48:12,800 --> 00:48:17,260 +سمينا conjugate addition هو في نهاية نوع من الاش + +521 +00:48:18,140 --> 00:48:21,720 +الـ Michael addition طبعاً صار إيه مين؟ الإيه مين + +522 +00:48:21,720 --> 00:48:26,740 +بيعود يرجع لإيه نمين ممتاز صار عند ال N H2 و C + +523 +00:48:26,740 --> 00:48:31,740 +double bond O سكروهم N H2 و C double bond O C + +524 +00:48:31,740 --> 00:48:37,960 +double bond N إيه مين؟ ممكن تعود تصير إيه نمين؟ في + +525 +00:48:37,960 --> 00:48:44,100 +كل الأحوال في كل الأحوالالمُركّب اللي طلع عندى لو + +526 +00:48:44,100 --> 00:48:47,300 +بتكون تتأملوا فيه جيدا .. لو بتكون تتأملوا فيه + +527 +00:48:47,300 --> 00:48:51,000 +جيدا و ترجعوا للي استعملته .. انتوا استعملتوا كام + +528 +00:48:51,000 --> 00:48:54,600 +جزء من الـ 1,3-dicarbonyl compound؟ اتنين .. كام + +529 +00:48:54,600 --> 00:48:58,880 +جزء من الـ nitrogen؟ الأمونيا؟ كم الديهيد؟ لو + +530 +00:48:58,880 --> 00:49:04,560 +إجيتوا تتطلعوا هدولة كيف مع بعض عملوا البريدين هذا + +531 +00:49:04,560 --> 00:49:11,360 +الجزء من 1,3-dicarbonyl compoundإن هو هذا و هذا + +532 +00:49:11,360 --> 00:49:16,880 +الجزء الـ 1,3-dicarbonyl compound التاني و هذا + +533 +00:49:16,880 --> 00:49:24,480 +الجزء الآن الـ Ammonia هذا الآن الـ Ammonia و الـ + +534 +00:49:24,480 --> 00:49:33,160 +ARC الالدهيد إذا البريدين هنتكوّن من جزء الـ 1,3 + +535 +00:49:33,160 --> 00:49:36,820 +-dicarbonyl compound من جزء الالدهيد من جزء + +536 +00:49:36,820 --> 00:49:42,480 +Ammoniaواضحك الفكرة؟ طبعا لأنه أنا استعملت نفس ال + +537 +00:49:42,480 --> 00:49:47,600 +1,3-dicarbonyl compound مرتين يعني لما بخلطهم .. + +538 +00:49:47,600 --> 00:49:54,840 +كيف بخلطهم النسبة؟ 2 إلى 1 إلى 1 عشان تثبت النسبة + +539 +00:49:54,840 --> 00:49:59,620 +.. 2 إلى 1 إلى 1 لأنه استعملت هذا بنسبة 2 البريدين + +540 +00:49:59,620 --> 00:50:04,300 +اللي طلع عند طلعتSymmetrical Pyridine يعني لاحظوا + +541 +00:50:04,300 --> 00:50:10,920 +هنا مثل هنا مثل هنا إيستر هنا إيستر هم لاحظين + +542 +00:50:10,920 --> 00:50:16,440 +السيمتري ليش؟ لأنه أنا هذا استعملته نفسه مرتين مرة + +543 +00:50:16,440 --> 00:50:22,320 +جزء منه عمل لي أنمين ومرة جزء منه عمل لي إنون + +544 +00:50:22,320 --> 00:50:27,070 +واضح؟طبعا هم اول ما كانوا خلطين هالكلام و طلع + +545 +00:50:27,070 --> 00:50:30,610 +بردين اخدوا فترة لحد ما فهموا ايه بعدين فهموا + +546 +00:50:30,610 --> 00:50:36,970 +الجثة كويس الجثة ان هذا التفاعل بيمر عبر ايش in a + +547 +00:50:36,970 --> 00:50:42,370 +mean و in on طيب الان حد بيفكر بشكل جيد كيميائي + +548 +00:50:42,370 --> 00:50:49,710 +بيفكر جيدا ايش بتتوقع انه ممكن يفكر؟ + +549 +00:50:52,580 --> 00:50:57,580 +ممكن يقول انا بقدر ابتفاع المنفصل احضر انامين + +550 +00:50:57,580 --> 00:51:04,060 +الجواب اه بده يخلطله اي 13-dicarbonyl compound مع + +551 +00:51:04,060 --> 00:51:10,720 +اموني بيحضر امين واحد تاني بيقول بقدر انا احضر + +552 +00:51:10,720 --> 00:51:15,880 +انون بيجيب 13-dicarbonyl compound تاني عند النزوم + +553 +00:51:15,880 --> 00:51:22,170 +مع الديهايدبحضر إيه نون؟ يعني تخيلوا لو أنه جينا + +554 +00:51:22,170 --> 00:51:26,170 +قولنا لواحد أنت خد هذا بنسبة واحد والأمونيا بواحد، + +555 +00:51:26,170 --> 00:51:30,790 +اشتغلوا بلا حالة وانت خد مركب تاني، افترضوا هذا + +556 +00:51:30,790 --> 00:51:34,230 +أخد ال one three-dicarbonyl حط فيه هاناميثين + +557 +00:51:34,230 --> 00:51:38,070 +والتاني أخد one three-dicarbonyl اللي فعله مع + +558 +00:51:38,070 --> 00:51:45,370 +الألديا وحط اثينهذا هيحضر القنون اللي فيه مثل هذا + +559 +00:51:45,370 --> 00:51:51,530 +هيحضر القنون اللي فيه اثل اثل اثل اثل اثل اثل اثل + +560 +00:51:51,530 --> 00:51:52,350 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +561 +00:51:52,350 --> 00:51:55,210 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +562 +00:51:55,210 --> 00:52:00,170 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +563 +00:52:00,170 --> 00:52:04,830 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +564 +00:52:04,830 --> 00:52:09,990 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثبيجيب + +565 +00:52:09,990 --> 00:52:14,090 +انامين من أي منطقة بدوا إياها في الدنيا و واحد + +566 +00:52:14,090 --> 00:52:18,130 +تاني بيجيب أي انون إذا خلطت الانامين مع الانون + +567 +00:52:18,130 --> 00:52:22,270 +أحطهم جانب بعض و أفعلهم ممكن أخلى الأربعة هدولة + +568 +00:52:22,270 --> 00:52:28,370 +كلهم إيش مختلفات يعني في أصل ال hand synthesis + +569 +00:52:28,370 --> 00:52:34,940 +البريدين اللي بيطلع symmetrical لكنلما اجوا طوروا + +570 +00:52:34,940 --> 00:52:39,660 +هذا ال synthesis هيجابوا هنا in amine مثلا in + +571 +00:52:39,660 --> 00:52:47,080 +amine في methyl و E star و جابوا in on في ar و cl + +572 +00:52:47,080 --> 00:52:53,220 +في النهاية in amine و in on هذه بدأت تفاعل ال + +573 +00:52:53,220 --> 00:52:55,860 +double bond وتيجي تعمل الإضافة هنا وهذا الآن بدأ + +574 +00:52:55,860 --> 00:53:01,980 +تسكرها هذه المحصلةواضح؟ لما نكمل هذا الإغلاق + +575 +00:53:01,980 --> 00:53:05,800 +هيعملنا ال addition طبعا انتبه لما عملنا ال + +576 +00:53:05,800 --> 00:53:10,180 +addition أكيد هالي مشتوبة لأن عملنا addition على + +577 +00:53:10,180 --> 00:53:13,880 +ال double bond صحيح؟ + +578 +00:53:13,880 --> 00:53:22,080 +واضح؟ ما حذفناش اشي نفسي لأ لأ فيه edges + +579 +00:53:27,430 --> 00:53:35,850 +حتى لو بحط هنا CO2 مثل في كل الأحوال المشكلة وين + +580 +00:53:35,850 --> 00:53:42,350 +عندها موجودة في ال double bond + +581 +00:54:16,170 --> 00:54:20,450 +هيعملنا هنا ال addition و ال double bond صارت + +582 +00:54:20,450 --> 00:54:24,810 +single bond بعد كده ال N H2 مع ال C double bond O + +583 +00:54:24,810 --> 00:54:29,870 +بدهم يعملوا C double bond N لاحظوا في عندكم Cl و H + +584 +00:54:31,030 --> 00:54:39,730 +كمان فقدوا HCL في هذه الحالة للأسف ما نبهتناش حتى + +585 +00:54:39,730 --> 00:54:47,550 +يكون السئل + +586 +00:54:47,550 --> 00:54:52,850 +ان هذه carboxylation ال CO2 مثل صحيح؟ او ال H2O + +587 +00:54:52,850 --> 00:54:56,090 +السئل ولا لا؟ بديش ال computer يكون اتجمد + +588 +00:55:08,700 --> 00:55:15,740 +كل الأحوال يعني ارجع ان الفكرة تكون ايش ارجع + +589 +00:55:15,740 --> 00:55:21,240 +ان الفكرة تكون واضحة اساس الفكرة وين انه طالما انا + +590 +00:55:21,240 --> 00:55:27,340 +فهمت ان التفاعل بين انا مين و انا one بصير بإمكاني + +591 +00:55:27,340 --> 00:55:32,620 +اجيب الانا مين من جهةو الانون من جهة تانية وأعمل + +592 +00:55:32,620 --> 00:55:37,380 +تفاعلي بدون ولا مشكلة conjugate addition followed + +593 +00:55:37,380 --> 00:55:41,660 +by cyclization conjugate addition followed by + +594 +00:55:41,660 --> 00:55:48,810 +cyclizationالان في تفاعل اسهل لتحضير البريدين ان + +595 +00:55:48,810 --> 00:55:52,830 +نفعل one five-dicarbonyl compound يعني لو أخدنا + +596 +00:55:52,830 --> 00:55:57,330 +واحد اتنين تلاتة اربعة خمسة مع الامونيا بيبقوا + +597 +00:55:57,330 --> 00:56:01,470 +يعمل امين انامين مرتين اضيف على السيطة بالبوند او + +598 +00:56:01,470 --> 00:56:06,970 +بتاعة لهذا واضح انه بيبقوا يعطينا اللي هو ال + +599 +00:56:06,970 --> 00:56:10,890 +diehydroberidine بأي عامل مؤكسب ممكن نحوله + +600 +00:56:10,890 --> 00:56:12,790 +البريدين + +601 +00:56:17,180 --> 00:56:24,130 +الان غير هيك البريدين تنسوش انه حلقةسداسية + +602 +00:56:24,130 --> 00:56:29,850 +البريدين حلقة سداسية و الحلقة السداسية من أشهر طرق + +603 +00:56:29,850 --> 00:56:35,430 +تحضيرها ديالز ألدر reaction ولذلك عند أنا طرق + +604 +00:56:35,430 --> 00:56:40,850 +كثيرة جدا بتخليني أحضر البريدين باستعمال ديالز + +605 +00:56:40,850 --> 00:56:45,550 +ألدر reaction مرات باستعمل اللي سمناهم mask دايين + +606 +00:56:45,550 --> 00:56:49,330 +اتكلمنا عنهم يعني هذا الدايين هي الدايين اللي + +607 +00:56:49,330 --> 00:56:53,150 +موجود عندك الآن هذا ال oxygen في النهايةبتكون في + +608 +00:56:53,150 --> 00:56:57,010 +الحلقة السادسية بتكسر رابطاتها و بتفقد ع شكل O H و + +609 +00:56:57,010 --> 00:57:05,130 +H ففي النهاية هاي أربعة و اتنين ستة صفة عندك بردين + +610 +00:57:05,130 --> 00:57:11,990 +بهذا الشكل هاي أربعة و اتنينستة طبعا صفة عندى + +611 +00:57:11,990 --> 00:57:16,070 +بيريدين هنا بكم double bond واحدة ليش لإن هدولا + +612 +00:57:16,070 --> 00:57:19,930 +كلهم double bonds ممكن البعض يتساءل ليش هناك صفة + +613 +00:57:19,930 --> 00:57:23,570 +aromatic بيريدين لإنه لما بكسر هذه بجيب double + +614 +00:57:23,570 --> 00:57:28,350 +bond وبعدين عملت اكسه وبتصير OH وعملت أكسه ده OH + +615 +00:57:28,350 --> 00:57:34,810 +OH فهي السبب لو حاولتوا تفصلوها بهدوء هتلاحظوا ان + +616 +00:57:34,810 --> 00:57:40,780 +هي سبب انه جيبت ال two aromaticأو two new bi bonds + +617 +00:57:40,780 --> 00:57:46,300 +فصيفي aromatic هذا مع ال triple bond هيعطينا حلقة + +618 +00:57:46,300 --> 00:57:52,040 +سدسية بكم bond؟ تنتين هذه من ال deals ألدر وال + +619 +00:57:52,040 --> 00:57:54,940 +triple بتصير double الآن صار عند تنتين double + +620 +00:57:54,940 --> 00:58:01,140 +bonds قربنا على ال aromatic بشوية تسخين بنشيل + +621 +00:58:01,140 --> 00:58:03,840 +هيدروجين بنصل ل ال aromatic + +622 +00:58:06,880 --> 00:58:10,320 +الان هذا مرة تانية ماسك ضايين ايش اللي بده يفقد + +623 +00:58:10,320 --> 00:58:16,540 +منه ال C double bond O فلاحظوا ال triple bond + +624 +00:58:16,540 --> 00:58:21,900 +بتخليله double bond و ال deals other double bond و + +625 +00:58:21,900 --> 00:58:27,500 +لما يفقد ال C O2 كمان بيجيبلي كمان bondصف عندي + +626 +00:58:27,500 --> 00:58:32,720 +ايش؟ aromatic الان انتوا بتكونوا تتخيلوا كيف + +627 +00:58:32,720 --> 00:58:37,780 +الكيميا عجيبة انه لو حد بيقول بدي بيريدين وعليه + +628 +00:58:37,780 --> 00:58:43,060 +خمس بنزينات two, three, four, five, six بنتفن + +629 +00:58:43,060 --> 00:58:47,780 +البريدين يمكن البعض يفكر ياخد البريدين يعمله + +630 +00:58:47,780 --> 00:58:52,240 +substitution من بيجي ع باله انه من هدولة المركبين + +631 +00:58:52,240 --> 00:59:01,750 +جابهم واضح؟هي جيبنا hetero-dienophile مع ديين عادي + +632 +00:59:01,750 --> 00:59:05,510 +طبعا هنا في عندى two cell group ال two cell group + +633 +00:59:05,510 --> 00:59:08,650 +ايه شمالها تفقد بسهولة باكسدا و بيصير + +634 +00:59:08,650 --> 00:59:16,110 +decarboxylation برضه بنحولله aromatic pyridine هذا + +635 +00:59:16,110 --> 00:59:21,390 +المركب مرة تانية mask ديين ايش اللي بده يفقد فيه + +636 +00:59:21,390 --> 00:59:27,950 +CO2 و triple bondالـ triple bond بتخلي bond و هنا + +637 +00:59:27,950 --> 00:59:32,010 +من ال deals ألدر كمان bond صاروا تنتين و مع فقد ال + +638 +00:59:32,010 --> 00:59:38,270 +co2 كمان bond هى صار عندى aromatic هذا المركب بدى + +639 +00:59:38,270 --> 00:59:45,530 +يفقد فيه مثل أمين هى ضيين double single double و + +640 +00:59:45,530 --> 00:59:52,300 +ال triple bondبتصير double bond واضح صار عندى + +641 +00:59:52,300 --> 00:59:58,120 +تنتين double bonds مع فقد هذا الجزء بتيجي التالتة + +642 +00:59:58,120 --> 01:00:03,600 +زى ما انتوا ملاحظين هذا الكلام كله أمثلة منوعة + +643 +01:00:03,600 --> 01:00:09,400 +وكتيرة على تحضير البريدين وهى كمان هذا المثال نفسه + +644 +01:00:09,400 --> 01:00:14,300 +هذا المثال الأخير one two four تريازين بفقد + +645 +01:00:14,300 --> 01:00:19,700 +نيتروجين هى ضايينضايقين فيه بس نيتروجين واحدة مع + +646 +01:00:19,700 --> 01:00:25,620 +double bond و بعدين decarboxylation او اشي زي هيك + +647 +01:00:25,620 --> 01:00:29,590 +او هاد يمكن ال triple double bond عاديةبتعملوا + +648 +01:00:29,590 --> 01:00:33,770 +أكسدة في نهاية بيصير ash peridine فزي ما بتلاحظوا + +649 +01:00:33,770 --> 01:00:38,010 +أنه ال deals elder ال deals elder reaction لإنه + +650 +01:00:38,010 --> 01:00:42,090 +بيعطي حلقة سداسية و ال peridine حلقة سداسية + +651 +01:00:42,090 --> 01:00:46,570 +الأمثلة لتحضير ال peridine بال deals elder + +652 +01:00:46,570 --> 01:00:52,370 +reaction أمثلةكثير جدا يعني سويانة الآن اذا قلنا + +653 +01:00:52,370 --> 01:00:57,270 +ان كلها الأمثلة أمثلة قديمة ان اقولكم كمان انتوا + +654 +01:00:57,270 --> 01:01:02,390 +هاتولنا جديد ناس حضروا derivatives جديدة للبريدين + +655 +01:01:02,390 --> 01:01:05,830 +بال deals elder reaction يعني روحوا home work على + +656 +01:01:05,830 --> 01:01:10,730 +المجلات وقولوا بيريدين by deals elder reaction غير + +657 +01:01:10,730 --> 01:01:15,690 +هذه الأمثلة هتلاقوا ناس كمان حضروا البريدين بال + +658 +01:01:15,690 --> 01:01:24,320 +deals elder reactionتمام في synthesis إضافي + +659 +01:01:24,320 --> 01:01:29,400 +للبريدين بنسميه chronic synthesis لchronic + +660 +01:01:29,400 --> 01:01:33,780 +synthesis بنستعمل فيه two four بالتال ديون يعني + +661 +01:01:33,780 --> 01:01:38,080 +عندي خمس كربونات على اتنين وعلى اربع أسيضة + +662 +01:01:38,080 --> 01:01:42,320 +بالبندقوز الان لما نفعله مع ال ammonium acetate + +663 +01:01:42,320 --> 01:01:49,490 +بنعمل على واحدة منهم امين و بتسيطin amine يعني هذه + +664 +01:01:49,490 --> 01:01:53,350 +أصلا CH3 + +665 +01:01:53,350 --> 01:01:58,250 +CH2 CH3 CH2 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 + +666 +01:01:58,250 --> 01:02:02,610 +CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 + +667 +01:02:02,610 --> 01:02:06,110 +CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 + +668 +01:02:06,110 --> 01:02:10,830 +CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 + +669 +01:02:10,830 --> 01:02:14,240 +CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CHالكيتون + +670 +01:02:14,240 --> 01:02:20,540 +اللى فيه CH2 activated اللى فيه activated CH2 ليش + +671 +01:02:20,540 --> 01:02:26,020 +لإن أنا بين تنتينC double bond Os يعني اللي هو one + +672 +01:02:26,020 --> 01:02:31,320 +two three four five نفس المركب اللي بتانا فيه يعني + +673 +01:02:31,320 --> 01:02:36,320 +كأنه احنا أخدنا ال two four dicarbonyl compound + +674 +01:02:36,320 --> 01:02:40,120 +هذا ولا two four بنتين two four ديون مع ال + +675 +01:02:40,120 --> 01:02:43,820 +ammonium acetate على جزء منه عمل هذا ال ammonia + +676 +01:02:43,820 --> 01:02:49,960 +والجزء التاني سابهزي ما هو .. الآن .. هنا لو بدنا + +677 +01:02:49,960 --> 01:02:54,420 +نيجي نتطلع بمنطق Enucleophile و Electrophile .. + +678 +01:02:54,420 --> 01:03:03,000 +هذه عبارة عن Enucleophile .. هذه C .. هذه .. هذه C + +679 +01:03:03,000 --> 01:03:09,480 +.. Electrophileواضح؟ C double bond O وبناء على ذلك + +680 +01:03:09,480 --> 01:03:13,000 +هذه هتهاجم على ال C اللي هنا لاحظوا من هنا جبت أنا + +681 +01:03:13,000 --> 01:03:18,440 +N, C, C, C هدولة كلهم جبتهم من هذه القطعة ومن هنا + +682 +01:03:18,440 --> 01:03:22,600 +هي نيوكليوفايل وإلكتروفايل فهذا ال synthesis لو + +683 +01:03:22,600 --> 01:03:27,660 +أنا بدي أصنفه هو عبارة عن 4 plus 2 synthesis يعني + +684 +01:03:27,660 --> 01:03:32,220 +أربع قطع اجوا من هنا نيتروجين كاربون كاربون كاربون + +685 +01:03:32,220 --> 01:03:37,720 +نيتروجين كاربون كاربون كاربون ومن هناcarbon و + +686 +01:03:37,720 --> 01:03:44,880 +carbon طبعا هذا عبارة عن أبساطة أبسط مثال في + +687 +01:03:44,880 --> 01:03:49,900 +الكيميا موجب سالب سالب موجب لاحظوا الفكرة العامة + +688 +01:03:49,900 --> 01:03:54,840 +تبعته هي فكرة احنا لما بدنا نحكي cyclization ايش + +689 +01:03:54,840 --> 01:04:01,060 +الاحتمالين اللي عندنا يا اما اتنين موجبو اتنين + +690 +01:04:01,060 --> 01:04:04,400 +سالب يعني اتنين Electrophile و اتنين Nucleophile + +691 +01:04:04,400 --> 01:04:07,800 +او بنحط Nucleophile يبقى له Electrophile او + +692 +01:04:07,800 --> 01:04:10,740 +Electrophile يبقى له Nucleophile هذا اي فكرة منهم + +693 +01:04:10,740 --> 01:04:17,500 +اللي موجودة هنا فكرة تانية واضح فكرة Nucleophiles + +694 +01:04:17,500 --> 01:04:25,600 +و Electrophiles الان + +695 +01:04:25,600 --> 01:04:29,920 +لو اجينا ل chemistry of pyridine + +696 +01:04:32,000 --> 01:04:36,860 +ال chemistry of pyridine حقيقة ممكن نتطلع عليها من + +697 +01:04:36,860 --> 01:04:43,260 +ناحيتين ممكن نتطلع علي ال nitrogen اللي حامله زوج + +698 +01:04:43,260 --> 01:04:48,020 +إلكترونات وهنا بدنا نقول أن هذه بتتفاعل + +699 +01:04:48,020 --> 01:04:53,060 +كنيوكليوفايل طالما بتتفاعل كنيوكليوفايل إذا هتبحث + +700 +01:04:53,060 --> 01:04:58,480 +عن إيش؟ عن إلكتروفايل موجب أو نعمل إبدال على + +701 +01:04:58,480 --> 01:05:03,310 +الحلقةElectrophilic Aromatic Substitution خلّينا + +702 +01:05:03,310 --> 01:05:09,350 +نبدأ بالنيتروجين لو أخدت مثل أيوديد مش مثل أيوديد + +703 +01:05:09,350 --> 01:05:14,430 +الكربون اللي فيه موجبة واليوت سالبة الآن خلّيها + +704 +01:05:14,430 --> 01:05:18,990 +تتفاعل بيعمل الان مثل بيريدين طبعا لما يعمل المثل + +705 +01:05:18,990 --> 01:05:24,430 +بتصير النيتروجين موجبة وقتها هيعمل مركّب ايوني ان + +706 +01:05:24,430 --> 01:05:30,200 +مثل بيريدينيوم أيوديد هسميه ليش بيريدينيوم؟لأن + +707 +01:05:30,200 --> 01:05:37,400 +الايون الموجب نهايته اونيوم مش + +708 +01:05:37,400 --> 01:05:44,660 +اتفقنا امونيوم اوكزونيوم بيردينيوم واضح ايون موجب + +709 +01:05:44,660 --> 01:05:49,660 +بيردينيوم ايضايت او هنا لو مرة تانية استفدنا من + +710 +01:05:49,660 --> 01:05:52,760 +هذا زوج الالكترونات اللي هنا مع الاستليكلورايد + +711 +01:05:52,760 --> 01:05:56,910 +الان في الاستليكلورايد وين الموجبالـ C double bond + +712 +01:05:56,910 --> 01:06:00,670 +O لكن لأنه أستيليكلورايدي التفاعل هيكون + +713 +01:06:00,670 --> 01:06:07,130 +substitution من مشتقات الحمض فهيعمل acetylation + +714 +01:06:07,130 --> 01:06:11,570 +هنا هيعمل acetylation و برضه هتصير الـ nitrogen + +715 +01:06:11,570 --> 01:06:15,910 +موجبة وبناء على ذلك هيتكون عندي إيش ال salt الأن + +716 +01:06:15,910 --> 01:06:20,570 +لاحظوا هذا بفسرلي ليش مرات أنا بستعمل البريدين ك + +717 +01:06:20,570 --> 01:06:24,760 +isolating agent ليش لأن هو هنا حمل ال acetineبعد + +718 +01:06:24,760 --> 01:06:29,020 +شوية بيرود يفقد ال acetyl بسهولة لتفاعل تاني بده + +719 +01:06:29,020 --> 01:06:33,080 +ال acetyl و لذلك هذا يقولنا عنه ايش ال البريدين او + +720 +01:06:33,080 --> 01:06:36,660 +هذا ال agent is a good oscillating agent يعني هو + +721 +01:06:36,660 --> 01:06:40,900 +كأنه أخد ال acetyl منها و بعد شوية بيفقدها اللي + +722 +01:06:40,900 --> 01:06:45,420 +تتفاعل معاهreagent تاني فمن هنا بيصير ك catalyst + +723 +01:06:45,420 --> 01:06:49,580 +يعني هو للحظة أخد ال acetyl بعدين خليني أقول لو + +724 +01:06:49,580 --> 01:06:54,080 +جبنا nucleophile معين لل nucleophile بيرد ياخد ال + +725 +01:06:54,080 --> 01:06:58,640 +acetyl منه و يعمل R C double bond on nucleophile + +726 +01:06:58,640 --> 01:07:05,340 +فصار البريدين زي catalyst زي واصفة حمل ال حمل ال + +727 +01:07:05,340 --> 01:07:10,300 +acetyl و بعدين فقدها بإيش بسهولة حمل ال acetyl + +728 +01:07:10,300 --> 01:07:18,420 +بعدين فقدهاالسهولة من التفاعلات أيضا ان البريدين + +729 +01:07:18,420 --> 01:07:22,060 +على ال نيتروجين مع ال bare acid بيعمل oxide، + +730 +01:07:22,060 --> 01:07:26,260 +unoxide الان ال unoxides في ال heterocycle كيميستر + +731 +01:07:26,260 --> 01:07:31,100 +مشهورينيعني كثير فيه heterocycles على ال nitrogen + +732 +01:07:31,100 --> 01:07:35,300 +بيكون في عندى oxygen و بناء على ذلك بتصير ال + +733 +01:07:35,300 --> 01:07:40,460 +nitrogen موجبة و ال oxygen اشمالها سالبة لاحظوا + +734 +01:07:40,460 --> 01:07:45,060 +هنا بختلف عن المراكبين اللى جابلت شغلة المراكبين + +735 +01:07:45,060 --> 01:07:48,620 +اللى جابلت ال nitrogen موجبة و اليود السالب مفصول + +736 +01:07:48,620 --> 01:07:52,700 +عنها هذا اش بنسمي احنا salt او هنا ال nitrogen + +737 +01:07:52,700 --> 01:08:00,980 +موجبة و ال chlorine مفصولة هذا saltالموجب والسالب + +738 +01:08:00,980 --> 01:08:07,080 +هنا مفصولين هذا salt لكن لما يكون الموجب والسالب + +739 +01:08:07,080 --> 01:08:14,540 +في نفس الجزء مثل الان أكسيد تأخذ عدة أسماء من ضمن + +740 +01:08:14,540 --> 01:08:18,660 +الأسماء التي تأخذها وممكن تشوفوها انه يتسمى inner + +741 +01:08:18,660 --> 01:08:25,410 +saltف ال inner salt الموجب و السلب فيه بنفس الجزية + +742 +01:08:25,410 --> 01:08:31,210 +ال salt الموجب لحال و السلب لحال كمان من الأسماء + +743 +01:08:31,210 --> 01:08:37,250 +اللي اتعلمتوها اذا انتوا متذاكرين zwitter ionic + +744 +01:08:37,250 --> 01:08:41,050 +zwitter ionic جاي من الألمان zwei يعني ثناء اتنين + +745 +01:08:41,050 --> 01:08:46,690 +zwei اتنين zwitter ionic يعني ثناء الايونية كمان + +746 +01:08:46,690 --> 01:08:49,130 +بيجي باسم betens + +747 +01:08:51,910 --> 01:08:57,690 +لما تقرأوا عن عائلة اسمها بيتينز هذه اللي هي + +748 +01:08:57,690 --> 01:09:02,550 +المركبات اللي فيها موجب و سالب و من أشهر التسميات + +749 +01:09:02,550 --> 01:09:10,450 +الـ mesionic compound بيسموها أيش كمان؟ mesionic + +750 +01:09:10,450 --> 01:09:16,770 +compounds اللي هي المركبات اللي فيها موجب و سالب + +751 +01:09:16,770 --> 01:09:25,280 +في حلقةوكمان بيسموهم Sidnones Sidnones طبعا + +752 +01:09:25,280 --> 01:09:29,180 +Sidnones لأنه من أوائل المراكبات اللي انفصلت كحلقة + +753 +01:09:29,180 --> 01:09:34,480 +خماسية خلينا نقول فيها موجب و هانا سالد كان مراكب + +754 +01:09:34,480 --> 01:09:39,420 +فصله ب Sidney بأستراليا فنسبة ل Sidney سموه + +755 +01:09:39,420 --> 01:09:44,450 +Sidinoneطبعا واضح تماما انه في ال homework بتكون + +756 +01:09:44,450 --> 01:09:49,470 +جيبولي ال Sedanon الأصلي طبعا الأصل ال Sedanon + +757 +01:09:49,470 --> 01:09:53,490 +مركب واحد لكن لأنه المركب فيه الظاهر الموجب + +758 +01:09:53,490 --> 01:09:56,970 +والثالث صار كل ما نزيه مرات بعض الناس يقولوا عنه + +759 +01:09:56,970 --> 01:10:04,580 +إيش Sedanon الميزو ايونكتقريبا من أشهرها للحلقات + +760 +01:10:04,580 --> 01:10:09,560 +ان الحلقة فيها موجب و بتحمل اش O سالبة كل هذه + +761 +01:10:09,560 --> 01:10:12,500 +الأشياء ممكن تلاقوا inner salt, zwitterionic, + +762 +01:10:12,620 --> 01:10:19,180 +betaine, mesoionic, sedanone كل هذا لواصف مراكبات + +763 +01:10:19,180 --> 01:10:26,470 +زي اش زي البريدينان اكسيد و بالمناسبة هذا البريدين + +764 +01:10:26,470 --> 01:10:30,050 +ان اكسيد للي بيلتبه لل one three dipolar + +765 +01:10:30,050 --> 01:10:33,830 +cycloaddition أخدته النيترون هو عبارة عن one three + +766 +01:10:33,830 --> 01:10:38,150 +dipolar بتفعل من هنا و من هنا مع double bond و + +767 +01:10:38,150 --> 01:10:44,530 +بيعمل حلقة خمسية واحد اتنين تلاتة اربع خمسة الان + +768 +01:10:44,530 --> 01:10:49,130 +البريدين ان اكسيد لو فعلناه مع الفوسفوراس ال + +769 +01:10:49,130 --> 01:10:53,870 +trichloride بيرود يفقد ال oxygen يرجع بريدينتمام؟ + +770 +01:10:53,870 --> 01:11:00,790 +يعني احنا ببساطة ممكن نعمل pyridine anoxide نخليه + +771 +01:11:00,790 --> 01:11:04,570 +يتحد ال nitrogen ب oxygen و ممكن نرود نتخلص من + +772 +01:11:04,570 --> 01:11:09,450 +ايش؟ من ال oxygen ال phosphorus trihalide الآن + +773 +01:11:09,450 --> 01:11:16,840 +الناس بيقولوا ان العبثية في الكيمياءاشمالها مرفوضة + +774 +01:11:16,840 --> 01:11:21,420 +يعني لو انه بس العملية انه اعمل unoxide واتريح منه + +775 +01:11:21,420 --> 01:11:27,400 +بس استعملت مواد عضوية وشميت كيمويات وضيعت وجتك على + +776 +01:11:27,400 --> 01:11:31,960 +الفاضي هذا الكلام مقبول ولا لأ مش مقبول لكن انا + +777 +01:11:31,960 --> 01:11:37,080 +باستفيد حقيقةمن البريدين ان اكسايد استفادة كبيرة + +778 +01:11:37,080 --> 01:11:42,640 +جدا الاستفادة الكبيرة جدا ان انا لو اجيت على + +779 +01:11:42,640 --> 01:11:47,260 +البريدين لما اتعلمت تفاعلات الإبدال اعملتله + +780 +01:11:47,260 --> 01:11:56,160 +نيتراشن بال HNO3 و Sulphuric Acid H2SO4 النيتراشن + +781 +01:11:56,160 --> 01:12:01,620 +بتنفي على موقع تلاتة واضح؟ وين بتيجي مجموعة + +782 +01:12:01,620 --> 01:12:07,430 +النيترو فيه؟ع موقع تلاتة فبصير عندى three nitro + +783 +01:12:07,430 --> 01:12:10,910 +pyridine لو بدى اعمل nitration ع ال pyridine الان + +784 +01:12:10,910 --> 01:12:17,370 +لو عملت ال nitration ع ال pyridine and oxide بتم ع + +785 +01:12:17,370 --> 01:12:25,730 +موقع اربعة واضح؟ الان بعد هيك لو اتيت اتخلصت في + +786 +01:12:25,730 --> 01:12:27,470 +هذه الحالة من + +787 +01:12:30,220 --> 01:12:35,640 +الاكسيد بصير حصلت على 4 نيترو بيردين عشانك لو اجيت + +788 +01:12:35,640 --> 01:12:39,840 +سألكوا كيف بتحضروا ل 3 نيترو بيردين هتقولولي + +789 +01:12:39,840 --> 01:12:44,560 +نيتراشن of بيردين عادي طب وال 4 نيترو بيردين + +790 +01:12:45,590 --> 01:12:50,130 +Nitration للانوكسيد وبعدين بخلص من الانوكسيد واضح + +791 +01:12:50,130 --> 01:12:54,550 +الفكرة طبعا انتبهوا معاك انه اللي حضر ال 4 نيترو + +792 +01:12:54,550 --> 01:12:58,930 +بيقدر بعد هيك ال نيترو سواء قبل او بعد يعمل لها + +793 +01:12:58,930 --> 01:13:04,810 +reduction ل .. ل امين اذا بهاد الطريقة اللي صار + +794 +01:13:04,810 --> 01:13:12,310 +بيبقى ان احضر ال ايش ال 4 امينو بيردين طب بقدر من + +795 +01:13:12,310 --> 01:13:17,510 +هنا احضر كمان ال 3 امينو بيردينأكيد reduction إذا + +796 +01:13:17,510 --> 01:13:21,970 +لو سألناكم كيف بدكم تحضروا ال three nitro و ال + +797 +01:13:21,970 --> 01:13:25,970 +four nitro pyridine بدنا نكون عارفين لو قولنا طيب + +798 +01:13:25,970 --> 01:13:30,190 +ال three amino و ال four amino اللي حضر ال three + +799 +01:13:30,190 --> 01:13:34,850 +nitro و ال four nitro بحضر ال three amino و ال + +800 +01:13:34,850 --> 01:13:42,650 +four amino شو ضال عندى ال two aminoيعني هي نقولت + +801 +01:13:42,650 --> 01:13:49,550 +في amino ع تلاتة من هذه و amino على أربعة ضايل ايش + +802 +01:13:49,550 --> 01:13:55,710 +ال amino على اتنين مين يتطوع يحضرها مع ال nitrogen + +803 +01:13:55,710 --> 01:14:02,750 +بتروح ع تلاتة في البريدين ع تلاتة و في البريدين + +804 +01:14:02,750 --> 01:14:08,950 +عنوكسايد على أربعة ضال عندي ايش ع تنين في حد منكم + +805 +01:14:08,950 --> 01:14:19,040 +بيقدر يعملهافي راجل طيب يمكن مات اسمه Chichibabin + +806 +01:14:19,040 --> 01:14:25,940 +Chichibabin عملها اذا انتوا مش قادرين تعملوا تحطوا + +807 +01:14:25,940 --> 01:14:30,660 +الامين على موقع اتنين مش نايتريشن عفوا اميناشن + +808 +01:14:30,660 --> 01:14:36,500 +امين مباشرة على موقع اتنين Chichibabin عملها تمام + +809 +01:14:36,500 --> 01:14:43,220 +يعني مش ناقص غيرينشدله هذا المنشد يقول عملها + +810 +01:14:43,220 --> 01:14:46,820 +Chichi Babel كيف عملها Chichi Babel؟ + +811 +01:14:46,820 --> 01:14:52,140 +باليوكليوفيليك substitution انتوا عارفين عادة عن + +812 +01:14:52,140 --> 01:14:54,760 +ال aromatic اللي بيتم ال Electrophilic ولا + +813 +01:14:54,760 --> 01:14:59,970 +اليوكليوفيليك substitutionElectrophilic الاروماتيك + +814 +01:14:59,970 --> 01:15:03,910 +لانها كلها إلكترونات عادة اللي بيهاجم عليها إيش + +815 +01:15:03,910 --> 01:15:09,070 +Electrophile لكن أحيانا ممكن تتم ال Eucleophilic + +816 +01:15:09,070 --> 01:15:11,650 +Substitution ومر عليكم بعض لل Eucleophilic + +817 +01:15:11,650 --> 01:15:15,130 +Substitution في كورسات ال organic العامة بالذات + +818 +01:15:15,130 --> 01:15:21,900 +لما بيكون عندكممجموعات with a drawing يعني لما كان + +819 +01:15:21,900 --> 01:15:28,020 +يكون عندكم زي هيك كلور و هنا نيترو و كمان نيترو و + +820 +01:15:28,020 --> 01:15:33,680 +كمان نيترو و اتفعلوها مع ال N A O H كانت تيجي ال O + +821 +01:15:33,680 --> 01:15:38,660 +H تحل هذا ال nucleophilic substitution موجود في ال + +822 +01:15:38,660 --> 01:15:43,200 +general organic واضح؟ كانت تيجي ال O H تحل محل + +823 +01:15:43,200 --> 01:15:47,730 +كلور الآنالشيطشي بابين عمل الـ Eucleophilic + +824 +01:15:47,730 --> 01:15:54,630 +Substitution بيجي بفاعل الـ Sodamide مع البريدين + +825 +01:15:54,630 --> 01:16:00,590 +طبعا هنا في عنده H و Sodamide عبارة عن NA plus NH2 + +826 +01:16:00,590 --> 01:16:07,990 +minus من اللي بده يهاجم الـ NH2 اتخيلوا انتوا هنا + +827 +01:16:07,990 --> 01:16:13,750 +في عندكم H و جاية الـ NH2 هذه بده تهاجم هناوين بده + +828 +01:16:13,750 --> 01:16:18,530 +يروح هذا زوجي الإلكترونات في عندي أصلا أنا زوجي + +829 +01:16:18,530 --> 01:16:23,370 +هذا بيجي هنا بتصير ال N minus ال N minus بتلاقي + +830 +01:16:23,370 --> 01:16:29,970 +إيش ال N A plus بتعمل معها زي سوء بتعدلها خلصت + +831 +01:16:29,970 --> 01:16:33,550 +مشكلة ال minus ليش؟ لأن ال minus لاجي موجب الآن + +832 +01:16:33,550 --> 01:16:40,400 +بعد هيك مجرد أن هذه ترجع هناتطلع ال H مع + +833 +01:16:40,400 --> 01:16:47,020 +إلكتروناتها الآن جبت N H2 مع إلكتروناتها و طردت H + +834 +01:16:47,020 --> 01:16:52,660 +مع إلكتروناتها جبت نيوكليوفايل و ال H minus اللي + +835 +01:16:52,660 --> 01:16:59,100 +طرتها نيوكليوفايل جبت سالب و طردتسالب إذا هذا أي + +836 +01:16:59,100 --> 01:17:03,380 +نوع من ال substitution اليوكليوفيليك substitution + +837 +01:17:03,380 --> 01:17:07,940 +هذا التفاعل اسمه Chichibabin reaction هتلاحظوه + +838 +01:17:07,940 --> 01:17:11,840 +موجود مش بس في البريدين وين في نيتروجين على موقع + +839 +01:17:11,840 --> 01:17:17,550 +اتنين جنبها بحط امينبصير general reaction يعني في + +840 +01:17:17,550 --> 01:17:22,530 +ال by role برضه على موقع اتنين بيحط امين باستعمال + +841 +01:17:22,530 --> 01:17:26,910 +ايش ال chichibabine reaction اللي هو تفاعل + +842 +01:17:26,910 --> 01:17:33,690 +السوداميد مع البريدين بيحط لوين ال ال NH2 على موقع + +843 +01:17:33,690 --> 01:17:37,830 +اتنين و ال chichibabine reaction is a nucleophilic + +844 +01:17:37,830 --> 01:17:40,690 +substitution reaction ماحدش يفكروا ايش + +845 +01:17:41,900 --> 01:17:44,780 +Electrophilic Substitution Reaction It is + +846 +01:17:44,780 --> 01:17:50,100 +Eucleophilic Substitution Reaction إذا لو الآن + +847 +01:17:50,100 --> 01:17:53,340 +إجينا السؤال How can you prepare two + +848 +01:17:53,340 --> 01:17:57,200 +aminobiridine، three aminobiridine، four + +849 +01:17:57,200 --> 01:18:04,330 +aminobiridine، بعرف ال two amino؟الثالثة أمينو + +850 +01:18:04,330 --> 01:18:10,830 +نيتراش عادى وبعدها ردوكشن الفورة أمينو نيتراش عادى + +851 +01:18:10,830 --> 01:18:16,530 +و بعدها ردوكشنطبعا فى ناس هيحتجوا يقولوا انتوا + +852 +01:18:16,530 --> 01:18:21,770 +شرحتولنا لل eucleophilic substitution الفرعى قبل + +853 +01:18:21,770 --> 01:18:26,030 +ما تحكوا ايش ال electrophilic substitution على + +854 +01:18:26,030 --> 01:18:30,030 +البريدين الان هل البريدين بتمعلى electrophilic + +855 +01:18:30,030 --> 01:18:36,040 +substitution من ناحية المبدأبتم ولكن أبطأ كتير من + +856 +01:18:36,040 --> 01:18:39,920 +البنزين يعني حوالي مليون مرة البريدين less + +857 +01:18:39,920 --> 01:18:44,560 +reactive than بنزين يعني ال nitration بالعافية بتم + +858 +01:18:44,560 --> 01:18:48,220 +لخمسة في المية ال chlorineation بشكل متوسط ال + +859 +01:18:48,220 --> 01:18:51,780 +bromination ب good yield في كل الأحوال بدي استعمل + +860 +01:18:51,780 --> 01:18:59,700 +CL2 مثلا FeCl3 Br2 FeBr3 ال nitration HNO3 H2SO4 + +861 +01:19:00,520 --> 01:19:06,340 +الكلام اللى اتعلمناه بصير السؤال طبعا ليش بتتم على + +862 +01:19:06,340 --> 01:19:11,520 +موقع تلاتة يعني عادة ال electrophilic substitution + +863 +01:19:11,520 --> 01:19:18,180 +وان بتتمع موقع تلاتة الان الناس اللى فاهمه من ال + +864 +01:19:18,180 --> 01:19:21,800 +organic chemistry ليش بتتم المواقع ايام ما كنا + +865 +01:19:21,800 --> 01:19:25,140 +نقول بعض المجموعات meta directing groups و بعضها + +866 +01:19:25,140 --> 01:19:29,280 +ortho para directing groups لازم يرسموا ايش + +867 +01:19:29,280 --> 01:19:33,500 +resonance structures يعني يجربوا يحطوا الإبدال على + +868 +01:19:33,500 --> 01:19:37,980 +موقع اتنين و يحطوا الإبدال ع موقع تلاتة و يحطوا + +869 +01:19:37,980 --> 01:19:43,280 +الإبدال ع موقع اربعة و يرسموا ايشكل ال resonance + +870 +01:19:43,280 --> 01:19:48,880 +structures يرسموا كل ال resonance structures لو + +871 +01:19:48,880 --> 01:19:52,860 +اجينا حاطينا الإبدال على موقع اتنين هلاحظ ان في + +872 +01:19:52,860 --> 01:19:55,500 +عندنا resonance structure و منهم resonance + +873 +01:19:55,500 --> 01:19:59,560 +structure غير مقبول في نيتروجين بتحمل موجة + +874 +01:19:59,560 --> 01:20:03,900 +نيتروجين عادة بتحمل ايش؟ سالب و لو اجينا نحط على + +875 +01:20:03,900 --> 01:20:07,220 +موقع اربعة هلاحظ برضه عندى two resonance + +876 +01:20:07,220 --> 01:20:10,080 +structures و واحد منهم غير مقبول نيتروجين فيه + +877 +01:20:10,080 --> 01:20:15,350 +بتحمل موجةالان لو حطينا على موقع تلاتة هلاحظ + +878 +01:20:15,350 --> 01:20:17,590 +الموجب على ال carbon هنا أو على ال carbon هنا مش + +879 +01:20:17,590 --> 01:20:20,850 +على ال nitrogen فصار هنا في عندي two resonance + +880 +01:20:20,850 --> 01:20:23,950 +structures و هنا two resonance structures و هنا + +881 +01:20:23,950 --> 01:20:28,250 +two resonance structures لكن هذا غير مقبول .. و + +882 +01:20:28,250 --> 01:20:31,570 +هذا غير مقبول ف two resonance structures مقبولين + +883 +01:20:31,570 --> 01:20:37,350 +في أي حالة بيكونوا في ال three substitutionsبناء + +884 +01:20:37,350 --> 01:20:42,390 +على ذلك، لو عملنا هذه التفاعلات على البريدين، على + +885 +01:20:42,390 --> 01:20:47,910 +أي موقع بتتم؟ على موقع تلاتة، الـ Electrophilic + +886 +01:20:47,910 --> 01:20:51,010 +Substitution بتتم على تلاتة، و أيه ذكرنا بعض + +887 +01:20:51,010 --> 01:20:54,430 +الأمثلة عليه؟ + +888 +01:20:56,200 --> 01:21:01,160 +بتهيأ ليه؟ بنكون أعطينا فكرة عن البريدين تفاعلاته + +889 +01:21:01,160 --> 01:21:05,700 +عن نيتروجين ال electrophilic substitution تبعه و + +890 +01:21:05,700 --> 01:21:08,240 +ال eucleophilic substitution شو المشهور في ال + +891 +01:21:08,240 --> 01:21:10,340 +eucleophilic substitution عن البريدين + +892 +01:21:13,730 --> 01:21:18,730 +وأخدنا الطرق المختلفة لتحضير البريدين ان شاء الله + +893 +01:21:18,730 --> 01:21:23,830 +المرة القادمة بنبدأ في الكوينولين و Isoquinoline + +894 +01:21:23,830 --> 01:21:27,970 +اللي هم في النهاية بنزو بيريدين يعني واضح؟ اللي هم + +895 +01:21:27,970 --> 01:21:30,110 +في النهاية بنزو بيريدين + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bC4LHhVjass.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bC4LHhVjass.srt new file mode 100644 index 0000000000000000000000000000000000000000..ae4bdfd679e4f9fbfc2272ec385d923d531c3ad5 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bC4LHhVjass.srt @@ -0,0 +1,2815 @@ +1 +00:00:20,820 --> 00:00:25,420 +بسم الله الرحمن الرحيم اليوم إن شاء الله بتكون + +2 +00:00:25,420 --> 00:00:30,700 +المحاضرة الأخيرة لنا في هذا المساق بعد ما تكلمنا + +3 +00:00:30,700 --> 00:00:34,020 +عن تسمية ال heterocycle compounds والطرق العامة + +4 +00:00:34,020 --> 00:00:39,600 +للتحضير وأخذنا أمثلة من انتقال بعض الحلقات تحضيرها و + +5 +00:00:39,600 --> 00:00:44,280 +تفاعلاتها أخذنا حلقات سداسية وبعدين من الحلقات + +6 +00:00:44,280 --> 00:00:51,410 +الخمسية درسنا ال pyrrole طبعا لو أتينا سألنا سؤال + +7 +00:00:51,410 --> 00:00:55,270 +تقليدي من الحلقات الخماسية الثانية المشهورة جدا + +8 +00:00:55,270 --> 00:01:01,790 +غير ال pyrrole هي حقيقة الفيوران والثيوفين ولذلك + +9 +00:01:01,790 --> 00:01:06,050 +الآن إن شاء الله هناخد فكرة أيضًا مختصرة عن + +10 +00:01:06,050 --> 00:01:08,750 +الفيوران والثيوفين + +11 +00:01:10,860 --> 00:01:15,940 +طبعا كل المركبات الحلقية الحقيقية يعني موجودة في + +12 +00:01:15,940 --> 00:01:21,260 +التطبيق وموجودة في أكثر من استعمال ودائمًا بنحب + +13 +00:01:21,260 --> 00:01:26,240 +نبدأ أن نعرض بعض هذه المركبات اللي موجودة في + +14 +00:01:26,240 --> 00:01:31,300 +التطبيق يعني مثلًا من المركبات الحلقية اللي موجودة + +15 +00:01:31,300 --> 00:01:36,620 +في الطبيعة هذا المركب واضح أنه مشتقة فيوران بسموه + +16 +00:01:36,620 --> 00:01:43,430 +rose furan يبدو مركب عطري هذا المركب اللي هو + +17 +00:01:43,430 --> 00:01:47,970 +Vitamin C أو الـ Ascorbic Acid هو عبارة أيضًا عن + +18 +00:01:47,970 --> 00:01:57,890 +furan derivative ال furan كمركب يعني قليل + +19 +00:01:57,890 --> 00:02:01,470 +أنه الإنسان ينطلق منه في التحضير في المختبر يعني + +20 +00:02:01,470 --> 00:02:05,390 +عادة المركب اللي موجود في المختبر وبنعمل منه + +21 +00:02:05,390 --> 00:02:08,630 +derivatives لما بنشتغل على ال furan هو ال furan + +22 +00:02:08,630 --> 00:02:12,250 +aldehyde اللي فيه ال aldehyde على موقع اثنين furan + +23 +00:02:12,920 --> 00:02:18,160 +2-furfuraldehyde وماخد اسم شهرة furfural من + +24 +00:02:18,160 --> 00:02:23,440 +مركبات الفيوران المهم جدا الدواء السحري هذا ال + +25 +00:02:23,440 --> 00:02:28,440 +رانيتدين اللي يستعمل لعلاج قرحة المعدة بيسموها + +26 +00:02:28,440 --> 00:02:32,520 +peptic ulcer طبعًا استعمل سابقًا الآن الفهم اللي + +27 +00:02:32,520 --> 00:02:36,760 +موجود عن قرحة المعدة أنه هي عبارة عن bacterial + +28 +00:02:36,760 --> 00:02:41,360 +infections هي يعني عدوى بكتيرية أو هي مرض بكتيري + +29 +00:02:42,000 --> 00:02:47,640 +وبالتالي بيعالجوها بالمضادات الحيوية مع مشتقات + +30 +00:02:47,640 --> 00:02:53,100 +أيضًا حلقات خمسية اللي هو ال omeprazole مع مضادات + +31 +00:02:53,100 --> 00:03:00,160 +clarithromycin و amoxicillin يعني بيسموه العلاج ال triple + +32 +00:03:00,160 --> 00:03:04,260 +therapy اللي الآن موجود طبعًا هذا يرجع فيه للأطباء + +33 +00:03:04,260 --> 00:03:11,300 +لكن هو خليط من المضادات الحيوية وال omeprazole لكن + +34 +00:03:11,300 --> 00:03:16,400 +لسنوات طويلة استعمل الرانيتدين ولحتى الآن في ناس + +35 +00:03:16,400 --> 00:03:20,720 +بيستعملوله آلام المعدة وما إلى ذلك لاحظوا أنه + +36 +00:03:20,720 --> 00:03:26,360 +الرانيتدين بشكل أساسي أيضًا هو عبارة عن furan + +37 +00:03:26,360 --> 00:03:31,350 +derivative هذا الدواء الآن لو أتينا على ال + +38 +00:03:31,350 --> 00:03:35,310 +synthesis of furan ال synthesis of furan في + +39 +00:03:35,310 --> 00:03:40,530 +عندنا synthesis متكرر ربما اللي هو ال 1,4- + +40 +00:03:40,530 --> 00:03:45,030 +dicarbonyl compounds واحنا تكلمنا أنه ال 1,4- + +41 +00:03:45,030 --> 00:03:49,370 +dicarbonyl compounds ممكن نحضر منهم ال pyrrole + +42 +00:03:49,370 --> 00:03:52,630 +ممكن نحضر منهم ال furan ممكن نحضر منهم الثيوفين + +43 +00:03:53,340 --> 00:03:58,400 +لما بدنا نحضر الفيوران بدنا هذا المركب نفسه ينفعل + +44 +00:03:58,400 --> 00:04:02,120 +مع acid اللي هو ال Paal-Knorr furan synthesis ف + +45 +00:04:02,120 --> 00:04:05,940 +oxygen منهم بتشغل كإنها ال nucleophile بتهاجم على + +46 +00:04:05,940 --> 00:04:09,460 +ال oxygen الثانية وبيستكمل ال elimination والتفاعل + +47 +00:04:09,460 --> 00:04:15,040 +لما كنا نحضر pyrrole كنا نضيف الأمونيا بحيث + +48 +00:04:15,040 --> 00:04:21,140 +أن هذا ال nucleophile يصير NH2 ولما بدنا بعد + +49 +00:04:21,140 --> 00:04:25,460 +شوية نشوف كيف يستعمل ال 1,4-dicarbonyl compound + +50 +00:04:25,460 --> 00:04:30,280 +لتحضير الثيوفين بدنا نحول واحدة من ال oxygen ل + +51 +00:04:30,280 --> 00:04:34,420 +sulfur وبالتالي بيصير ال sulfur يهاجم as a + +52 +00:04:34,420 --> 00:04:39,060 +nucleophile ويطلع أنه ثيوفين فهذا ال synthesis + +53 +00:04:39,060 --> 00:04:46,230 +الأول ل furan ال synthesis الثانية هي ال Feist- + +54 +00:04:46,230 --> 00:04:50,730 +Bénary Furan Synthesis اللي أخذنا فيه ال alpha- + +55 +00:04:50,730 --> 00:04:56,250 +Halo Keto مع ال beta-Keto Ester لاحظوا معنى أنه + +56 +00:04:56,250 --> 00:05:01,410 +برضه لما احنا أخذنا ال pyrrole Synthesis كنا ناخد + +57 +00:05:01,410 --> 00:05:06,330 +هدول الاثنين لكن نضيف عليهم كمان ايش ال ammonia أو + +58 +00:05:06,330 --> 00:05:12,970 +ال amine الآن لو أخذناهم لوحدهم طبعًا مر علينا كيف + +59 +00:05:12,970 --> 00:05:18,370 +هذا التفاعل بتم في وجود base الآن هذه ال CH2 هي + +60 +00:05:18,370 --> 00:05:24,800 +عبارة عن activated methylene group ويمكن أن أنا أفقد + +61 +00:05:24,800 --> 00:05:29,500 +بروتون يصير عندي carbanion ال carbanion أكيد بده + +62 +00:05:29,500 --> 00:05:36,490 +يهاجم هنا ويعمل ال OH- بعد ما هذا يتكون يمكن أنه + +63 +00:05:36,490 --> 00:05:39,810 +يفقد البروتون الثاني يعني احنا بنكون متذاكرين أنه + +64 +00:05:39,810 --> 00:05:44,990 +في هنا كم بروتون أساسًا CH2 ففقد البروتون الأول + +65 +00:05:44,990 --> 00:05:50,550 +عمل هذا الارتباط لو فقد البروتون الثاني بيصير عندي + +66 +00:05:50,550 --> 00:05:54,970 +carbanion الآن لو عملنا التوتومريزم هذا ال carbanion اما + +67 +00:05:54,970 --> 00:05:59,390 +بيكون على ال carbon هنا أو بيجعل oxygen وتنتقل ال + +68 +00:05:59,390 --> 00:06:05,450 +double bond واضح هذا مش توتومريزم عفوا resonance + +69 +00:06:05,450 --> 00:06:10,190 +عشان ما يعني يكون الكلام دقيق لما نشوف هذا ال + +70 +00:06:10,190 --> 00:06:14,970 +resonance structure هذا enolate anion enol enolate + +71 +00:06:14,970 --> 00:06:20,710 +enolate anion الآن طالما صار عندي O- هتهاجم + +72 +00:06:20,710 --> 00:06:24,210 +على ال + +73 +00:06:24,210 --> 00:06:29,790 +CH2Cl وتطرد ال Cl وبالتالي يتكون عندي furan + +74 +00:06:30,670 --> 00:06:35,390 +derivative هذا مر علينا اللي هو Feist-Bénary + +75 +00:06:35,390 --> 00:06:39,070 +reference synthesis أول ما درسنا ال substitution + +76 +00:06:39,070 --> 00:06:44,750 +reaction كطريقة لإغلاق الحلقة واضح؟ والناس اللي + +77 +00:06:44,750 --> 00:06:51,430 +متذكرة ربما ال Baldwin rules + +78 +00:06:51,430 --> 00:06:56,690 +ايه هذا هتسميه exo ولا endocyclization هذا عبارة + +79 +00:06:56,690 --> 00:07:03,180 +عن exocyclization على tetragonal ولا tetragonal ولا + +80 +00:07:03,180 --> 00:07:07,460 +diagonally carbon tetragonal اه إذا هذا exo + +81 +00:07:07,460 --> 00:07:13,920 +tetragonally cyclization exo tetragonally cyclization + +82 +00:07:13,920 --> 00:07:18,140 +هذا ال Feist-Bénary referent synthesis قلنا عنه بدنا + +83 +00:07:18,140 --> 00:07:24,360 +ننتبه أن هو متداخل مع ال pyrrole synthesis + +84 +00:07:24,360 --> 00:07:28,920 +يعني نفس هدول ال two reagents لو صار في عنده ال + +85 +00:07:28,920 --> 00:07:33,100 +ammonia لو صار في عنده ال ammonia اللي هيصير أنه + +86 +00:07:33,100 --> 00:07:36,260 +هذه ال seed of المنطقة هي هتصير nitrogen وبالتالي + +87 +00:07:36,260 --> 00:07:41,440 +اللي هيسكر هنا nitrogen طالما أنهم الثلاثة موجودين + +88 +00:07:41,440 --> 00:07:47,740 +هيخرج عندي كمان pyrrole ك byproduct لما نكون + +89 +00:07:47,740 --> 00:07:56,120 +نحضر ال pyrrole الآن بالنسبة لتفاعلات الفيوران طبعا + +90 +00:07:56,120 --> 00:08:00,440 +أخذنا احنا المرة الماضية لما درسنا ال + +91 +00:08:00,440 --> 00:08:04,760 +electrophilic substitution اللي هو التفاعل الأساسي + +92 +00:08:04,760 --> 00:08:10,680 +لل aromatic compounds أن ال pyrrole هو ال most active + +93 +00:08:10,680 --> 00:08:15,580 +في ال electrophilic substitution أكثر من الفيوران + +94 +00:08:15,580 --> 00:08:19,880 +أكثر من الثيوفين وكلهم في النهاية أكثر من البنزين + +95 +00:08:19,880 --> 00:08:23,700 +السبب أن كلهم أكثر من البنزين هو وجود ال + +96 +00:08:23,700 --> 00:08:27,360 +electronegative atom فأنا لما بيدّي عندي + +97 +00:08:27,360 --> 00:08:32,460 +electrophile من الخارج كل ما كانت الحلقة محتوى + +98 +00:08:32,460 --> 00:08:37,900 +الإلكتروني أكثر كل ما كانت التفاعل ايش أكثر واضح؟ + +99 +00:08:39,400 --> 00:08:45,380 +بشكل عام ال reaction مثله مثل ال pyrrole بتم على + +100 +00:08:45,380 --> 00:08:50,720 +موقع اثنين لنفس الأسباب المتعلقة بال resonance + +101 +00:08:50,720 --> 00:08:58,020 +structures لكن الفيوران خلينا نقول فيه ميزة أن هو + +102 +00:08:58,020 --> 00:09:03,890 +من ناحية ال aromaticity أقل من البيرول وأقل من هذه + +103 +00:09:03,890 --> 00:09:08,950 +الحلقات طبعا أهم شغلة مرتبطة بفكرة ال aromaticity + +104 +00:09:08,950 --> 00:09:14,470 +أنه يعني لو رجعنا كفكرة للبنزين لو رجعنا كفكرة + +105 +00:09:14,470 --> 00:09:19,170 +للبنزين أنه كنا نقول احنا أنه البنزين في double + +106 +00:09:19,170 --> 00:09:24,750 +bonds لكن ما بعملش addition على ال double bond + +107 +00:09:26,520 --> 00:09:31,740 +واضحة؟ يعني أهم شغلة في ال aromaticity أنه بنعتبر + +108 +00:09:31,740 --> 00:09:35,360 +ال double bonds كإنها مش موجودة يعني ما بنيجيش نلغي + +109 +00:09:35,360 --> 00:09:38,860 +ما بنيجيش نلغي double bond ونخليها single bond و + +110 +00:09:38,860 --> 00:09:42,360 +نعمل addition على ال double bond هذا المميز + +111 +00:09:42,360 --> 00:09:46,780 +الأساسي لل aromatic compounds أنه they don't react + +112 +00:09:46,780 --> 00:09:51,260 +at the double bond they don't undergo addition + +113 +00:09:51,260 --> 00:09:56,650 +reactions الآن الفيوران من المركبات اللي ال + +114 +00:09:56,650 --> 00:10:00,930 +aromaticity بتبقيها ضعيفة وبالتالي بيعمل addition + +115 +00:10:00,930 --> 00:10:04,610 +reactions يعني بيعمل ال electrophilic aromatic + +116 +00:10:04,610 --> 00:10:08,890 +substitution لكن بيعمل ال addition بمعنى آخر + +117 +00:10:08,890 --> 00:10:14,030 +double bond منه بتصير عبارة عن ايش؟ بتصير عبارة عن + +118 +00:10:14,030 --> 00:10:20,090 +single bond الآن هذا الكلام هذا الكلام حقيقة معتمد + +119 +00:10:20,090 --> 00:10:26,080 +على نوع التفاعل يعني على ظروف التفاعل يعني لو عملنا + +120 +00:10:26,080 --> 00:10:35,300 +البروميناشن في aprotic solvent زي ال DMF مش polar + +121 +00:10:35,300 --> 00:10:39,220 +aprotic solvent هلاحظ أنه بتم التفاعل عادي جدا + +122 +00:10:39,220 --> 00:10:42,200 +Electrophilic Aromatic Substitution + +123 +00:10:42,200 --> 00:10:50,040 +على الموقع 2 لو البروميناشن نفسه عملناه في وجود + +124 +00:10:50,040 --> 00:10:55,100 +protic polar solvent زي الميثانول زي الميثانول الآن + +125 +00:10:55,100 --> 00:11:01,810 +الميثانول ميزته هو ك solvent أنه هو solvent وهو + +126 +00:11:01,810 --> 00:11:07,630 +nucleophile هو solvent وهو nucleophile فلو احنا + +127 +00:11:07,630 --> 00:11:14,990 +جربنا أن نمشي بالتدريج كيف بتتم عملية ال + +128 +00:11:14,990 --> 00:11:18,690 +electrophilic substitution خلينا نقول أن المنطلق + +129 +00:11:18,690 --> 00:11:24,190 +تبعنا كان من زوج الإلكترونات اللي موجود هنا وجاي + +130 +00:11:24,190 --> 00:11:28,770 +عندنا Br+ الآن ال Br+ بده الإلكترونات + +131 +00:11:28,770 --> 00:11:33,410 +من وين؟ من الحلقة هذه عندي ست إلكترونات هو بده + +132 +00:11:33,410 --> 00:11:38,270 +إلكترونات فلو تخيلنا هذا الشكل تخيلنا زي هيك هنا + +133 +00:11:38,270 --> 00:11:43,770 +أكيد كان في H هذه الرابطة هتيجي تشبك بإيش بالبرومين + +134 +00:11:44,700 --> 00:11:49,220 +هذه الرابطة هتشبك في البرومين عادة الـ + +135 +00:11:49,220 --> 00:11:53,680 +Electrophilic Substitution الطبيعي لما كان بيكتمل + +136 +00:11:53,680 --> 00:11:58,060 +أنه زي ما أتي عندي Electrophile موجب يعني لو أنا + +137 +00:11:58,060 --> 00:12:01,800 +بدي Electrophilic Substitution عادي أن زي ما أتي + +138 +00:12:01,800 --> 00:12:08,920 +عندي Electrophile موجب نفقت الـH الموجبة ونرجع هذه + +139 +00:12:08,920 --> 00:12:13,420 +ونرجع هذه ونرجع زوج الإلكترونات هذا الوضع اللي + +140 +00:12:13,420 --> 00:12:16,180 +موجود بهذا الشكل هذا الـ Electrophilic Aromatic + +141 +00:12:16,180 --> 00:12:20,600 +Substitution واضح؟ إنه يجي عنده الـ Electrophile + +142 +00:12:20,600 --> 00:12:26,340 +بأرموجة إنه يفقد عنده بعد هيك الـ Electrophile H + +143 +00:12:26,340 --> 00:12:30,460 +Plus واضح؟ هذا إيش بيكون بهذا الشكل اللي مرسوم + +144 +00:12:30,460 --> 00:12:35,480 +الآن Electrophilic Aromatic Substitution و بيصير + +145 +00:12:35,480 --> 00:12:40,000 +مثل هذا الجزء يعني لو هذا الكلام تم هيصير عندي زي + +146 +00:12:40,000 --> 00:12:45,830 +الجزء اللي موجود عندنا هنا الآن في وجود الميثانول + +147 +00:12:45,830 --> 00:12:49,130 +يعني هذا الكلام نفسه لو أنا بدي أفسر هذا ال + +148 +00:12:49,130 --> 00:12:54,910 +ميكانيزم بدي أقول واحد اثنين ثلاثة واضح؟ في وجود + +149 +00:12:54,910 --> 00:12:57,950 +الميثانول يعني لو قلنا كيف هذا البرومينيش اللي + +150 +00:12:57,950 --> 00:13:02,470 +بدي يصير بيقول هيقع علينا الفيوران مع ال Br plus بهذا + +151 +00:13:02,470 --> 00:13:09,220 +الشكل تفقد ال H plus فصرنا التفاعل لفوق لكن في وجود + +152 +00:13:09,220 --> 00:13:16,920 +الميثانول بيصير عندي مصار بيصير عند مصار بيصير عند مسار جديد + +153 +00:13:16,920 --> 00:13:23,140 +أو مسار ثاني للتفاعل لما بيوجد عندنا الميثانول + +154 +00:13:23,140 --> 00:13:28,560 +بيصير في عندنا مسار ثاني للتفاعل خلينا نتخيل هذا + +155 +00:13:29,760 --> 00:13:34,360 +المسار الثاني اللي موجود عندنا للتفاعل طبعا هنا في + +156 +00:13:34,360 --> 00:13:41,060 +عندنا إيش H بلس والميثانول is the Nucleophile بناء + +157 +00:13:41,060 --> 00:13:48,360 +على ذلك هذا الميثانول بيجي يهاجم هنا وهذه ترجع على + +158 +00:13:48,360 --> 00:13:55,200 +ال oxygen واضح في هذه الحالة لما أنا أضفت في + +159 +00:13:55,200 --> 00:14:01,600 +الخطوة الأولى Br plus وفي الخطوة الثانية the + +160 +00:14:01,600 --> 00:14:05,360 +Nucleophile يعني في النهاية plus minus هذا استكمال + +161 +00:14:05,360 --> 00:14:10,560 +لفكرة ال addition طبعا أكيد ال methanol هيفقد ال H + +162 +00:14:10,560 --> 00:14:17,220 +هذا أمر طبيعي الآن لاحظوا هنا ال H هذه ما زالت + +163 +00:14:17,220 --> 00:14:25,140 +موجودة و ال H هذه ما زالت موجودة في هذه الحالة في + +164 +00:14:25,140 --> 00:14:30,040 +هذه الحالة صار عندي Addition reaction فده الحالة + +165 +00:14:30,040 --> 00:14:34,580 +صار عندي Addition reaction ليش؟ لأنه أنا بديت في + +166 +00:14:34,580 --> 00:14:38,780 +two double bonds وهنا كم double bond عندي؟ واحدة + +167 +00:14:38,780 --> 00:14:45,100 +ففي عندي Addition reaction في وجود الميثانول، واضح؟ + +168 +00:14:45,700 --> 00:14:49,400 +بهذه الحالة صار في عندي Addition reaction في وجود + +169 +00:14:49,400 --> 00:14:54,500 +الميثانول طبعا ممكن بعد هيك ممكن بعد هيك كمان + +170 +00:14:54,500 --> 00:15:00,140 +تستبدل ال Br هذه بخطوة لاحقة أنا بالنسبة لي ال + +171 +00:15:00,140 --> 00:15:04,780 +addition في هذه الحالة استكمل يعني قدرت أشوف إنه + +172 +00:15:04,780 --> 00:15:10,360 +تم عندي تفاعل ال addition الآن بعد هيك كيف ممكن + +173 +00:15:10,360 --> 00:15:16,360 +نتخيل إنه تم استبدال ال Br اللي موجودة هنا بمجموعة + +174 +00:15:16,360 --> 00:15:21,500 +إيش أو مثل ثانية يعني صار عندي كم مثل group صار + +175 +00:15:21,500 --> 00:15:27,700 +عندي two مثل groups صار عندي two مثل groups من + +176 +00:15:27,700 --> 00:15:34,440 +خلال مرة ثانية إذا احنا بدنا نطلع على هذا المركب + +177 +00:15:34,440 --> 00:15:38,780 +اللي موجود هنا لو تخيلنا إنه زوج الإلكترونات اللي + +178 +00:15:38,780 --> 00:15:47,120 +هنا هذا زوج الإلكترونات يتحرك بهذا الشكل وجدتها + +179 +00:15:47,120 --> 00:15:52,580 +معقول يصير عندي خمس روابط هنا إذا هتطلع البروم على + +180 +00:15:52,580 --> 00:15:59,700 +شكل Br- يعني لما تتم هذه الحركة هو زوج + +181 +00:15:59,700 --> 00:16:04,740 +الإلكترونات في هذه الحالة بيطرد البروم على شكل Br- + +182 +00:16:04,740 --> 00:16:11,820 +الآن إذا إجا الميثانول الآن اتفاعل معه ورجع زوجي + +183 +00:16:11,820 --> 00:16:17,480 +الإلكترونات بهذا الشكل رجعنا للمركب الأصلي طبعا لو + +184 +00:16:17,480 --> 00:16:24,400 +إجينا سألنا إيش نوع الإبدال هذا الأخير طلع عندي Br + +185 +00:16:24,400 --> 00:16:32,400 +minus إجا عندي methanol طلع ال nucleophile أي جاء + +186 +00:16:32,400 --> 00:16:37,300 +الـ Nucleophile إذا هنا الإبدال الـ Nucleophilic + +187 +00:16:37,300 --> 00:16:40,060 +Substitution أنا عارف إنه Substitution لكن السؤال + +188 +00:16:40,060 --> 00:16:44,600 +أي Substitution ما هو ال Substitution نوعين في + +189 +00:16:44,600 --> 00:16:48,140 +Nucleophilic Substitution و في Electrophilic + +190 +00:16:48,140 --> 00:16:52,680 +Substitution أنا لما شيلت Br minus و حطيت يعني ال + +191 +00:16:52,680 --> 00:16:58,180 +hydrogen مازالت موجودة ال hydrogen مازالت + +192 +00:16:58,180 --> 00:17:02,620 +موجودة أنا كل اللي عملته كمحصلة لما أشوف هذا + +193 +00:17:02,620 --> 00:17:05,840 +التفاعل هنا و أشوف هذه النتيجة هنا شو اللي عملته + +194 +00:17:05,840 --> 00:17:15,060 +شيلت Br minus حطيت O مثل إذا هذا ال Nucleophilic + +195 +00:17:15,060 --> 00:17:19,500 +substitution طبعا اللي احنا بدنا نستنتجه من هذه ال + +196 +00:17:19,500 --> 00:17:26,140 +slide بالمجمل إنه الفيوران صراحة بيعمل Electrophilic + +197 +00:17:26,140 --> 00:17:30,880 +Aromatic Substitution إذا كان عنده Aprotic Solvent + +198 +00:17:30,880 --> 00:17:34,780 +لكن لو كان في عنده Protic Solvent هذا ال Protic + +199 +00:17:34,780 --> 00:17:40,370 +Solvent له Nucleophilic Power ممكن يعمل Addition + +200 +00:17:40,370 --> 00:17:45,650 +في خطوته الأولى وممكن يكمل يعمل الـ Nucleophilic + +201 +00:17:45,650 --> 00:17:49,410 +Substitution يعني اللي تم هنا هي عملية Addition + +202 +00:17:49,410 --> 00:17:52,290 +يعني هذا التفاعل اللي بدنا نوصفه بيقول أن هذا + +203 +00:17:52,290 --> 00:17:56,370 +Addition كان عندي two double bonds صاروا one + +204 +00:17:56,370 --> 00:18:03,870 +double bond زيادة في محتوى ال sigma bonds ونقص في + +205 +00:18:03,870 --> 00:18:08,290 +محتوى ال pi bonds هذا عبارة عن إيش addition الآن + +206 +00:18:08,290 --> 00:18:12,070 +بعد ال addition تمت شغلة جديدة اللي هي عملية ال إيش + +207 +00:18:12,070 --> 00:18:18,030 +ال nucleophilic substitution واضح؟ كل هذا الكلام + +208 +00:18:18,030 --> 00:18:28,470 +بيعمله الفيوران سجل كهرباء تعمل المشاكل الله + +209 +00:18:28,470 --> 00:18:29,210 +يعطيك الله عافية + +210 +00:18:33,230 --> 00:18:35,030 +بس يوم برد شوية ما بتاعي + +211 +00:19:17,260 --> 00:19:20,960 +احنا أهم شيء أن هذه اللقطة الكبيرة كنا مخلصينها + +212 +00:19:33,130 --> 00:19:34,010 +ماذا تحب؟ + +213 +00:19:52,960 --> 00:19:59,660 +إذا الخلاصة اللي احنا وصلنا لها هنا إنه الفيوران + +214 +00:19:59,660 --> 00:20:05,000 +خلافا لل aromatic compounds اللي هي أساسا تفاعلها + +215 +00:20:05,000 --> 00:20:08,680 +الأساسي ال Electrophilic Aromatic Substitution ممكن + +216 +00:20:08,680 --> 00:20:13,340 +يعمل Addition reactions ممكن يعمل Addition + +217 +00:20:13,340 --> 00:20:19,260 +reactions الآن كتأكيد لهذا المعنى لو تابعنا ال + +218 +00:20:19,260 --> 00:20:24,600 +nitrogen of a furan لاحظوا معنى عملوا ال nitrogen + +219 +00:20:24,600 --> 00:20:30,740 +مرتين مرة في وجود ال Nucleophile قوي اللي هو ال + +220 +00:20:30,740 --> 00:20:35,100 +acetate anion ومرة في وجود ال Nucleophile ضعيف + +221 +00:20:35,100 --> 00:20:41,170 +يعني هذا ال Nucleophile strong هذا ال Nucleophile weak + +222 +00:20:41,170 --> 00:20:46,830 +الآن ال Nucleophile القوي تدخل في التفاعل ومشي + +223 +00:20:46,830 --> 00:20:51,530 +التفاعل على مسار ال إيش ال Addition اثنتين double + +224 +00:20:51,530 --> 00:20:56,010 +bond صاروا واحدة double bond معناه ذلك تمت عملية + +225 +00:20:56,010 --> 00:20:58,930 +Addition ولو ال Addition هنا بيبين one four + +226 +00:20:58,930 --> 00:21:01,450 +Addition مش مشكلة في النهاية أنا لغيت double bond + +227 +00:21:01,450 --> 00:21:04,690 +يعني يمكن الطلاب متعودين إنهم يشوفوا ال Addition + +228 +00:21:05,640 --> 00:21:09,000 +one two Addition في النهاية one two Addition أو + +229 +00:21:09,000 --> 00:21:12,320 +one four Addition finally Addition و ليش احنا + +230 +00:21:12,320 --> 00:21:16,700 +أساسا بنسمي ال Addition وبميزه برقم بنقول إنه في + +231 +00:21:16,700 --> 00:21:21,440 +one two Addition لأنه برضه في الدنيا في one four + +232 +00:21:21,440 --> 00:21:24,660 +Addition هذا أكيد Addition و لغيت فيه double bond + +233 +00:21:24,660 --> 00:21:28,760 +لاحظوا لما استعملنا ال Nitration في وجود weakened + +234 +00:21:28,760 --> 00:21:34,830 +Nucleophile تمبس Nitration عادي Electrophilic + +235 +00:21:34,830 --> 00:21:40,630 +Aromatic Substitution ما تمش فيه عنده اللي هو ال + +236 +00:21:40,630 --> 00:21:47,130 +Addition reaction الآن بعد هيك إنه هذا المركب اللي + +237 +00:21:47,130 --> 00:21:51,370 +هنا عملوا له أكسدة أو فقد ال acetic acid في البيردين + +238 +00:21:51,370 --> 00:21:57,090 +هذا أمر بتهيأ له واضح وسهل يعني مش عملية صعبة إنه + +239 +00:21:57,090 --> 00:22:06,480 +بديفقد AcO مع H واضح؟ بالإمكان أن ننفذها بسهولة + +240 +00:22:06,480 --> 00:22:14,290 +ويرجع يصير في عندنا إيش؟ اللي هو مركب ال Substitution + +241 +00:22:14,290 --> 00:22:18,930 +مركب ال Substitution العادي لكن بالتأكيد هذا المركب مر + +242 +00:22:18,930 --> 00:22:24,850 +عبر ال Addition reaction وتم فصل وتم فصل هذا + +243 +00:22:24,850 --> 00:22:27,950 +المركب اللي هو مركب ال Addition reaction يعني لو + +244 +00:22:27,950 --> 00:22:31,730 +انتوا تخيلتوا إن هنا في عندكم hydrogen تخيلتوا + +245 +00:22:31,730 --> 00:22:39,910 +إن هنا في عندكم هيدروجين بهذا الشكل إذا فقدت هذه + +246 +00:22:39,910 --> 00:22:42,730 +الهيدروجين هذه ال bond هتتحرك بهذا الشكل هذه + +247 +00:22:42,730 --> 00:22:51,270 +هتتحرك بهذا الشكل هذه الآن هي ال AcO minus وهذه + +248 +00:22:51,270 --> 00:23:00,670 +ال H AcO minus مع ال H اللي هي AcO H + +249 +00:23:05,320 --> 00:23:10,960 +الفكرة إنه اعتمادا على Nucleophilic power of the + +250 +00:23:10,960 --> 00:23:14,940 +solvent أو Nucleophile يعني في المثال السابق كان + +251 +00:23:14,940 --> 00:23:19,100 +الميثانول ال solvent أو هنا حطينا احنا Nucleophile + +252 +00:23:19,100 --> 00:23:23,970 +من عندنا ممكن إنه على الفيوران تمت عملية ال + +253 +00:23:23,970 --> 00:23:28,210 +Addition فيه خروج عن المقلوب لإيش؟ للـ Aromatic + +254 +00:23:28,210 --> 00:23:31,170 +compounds لأن الـ Aromatic compounds المقلوب لها + +255 +00:23:31,170 --> 00:23:35,850 +الـ Electrophilic Aromatic Substitution الآن + +256 +00:23:35,850 --> 00:23:42,210 +بالنسبة للـ Cycloaddition reactions الحقيقة إنه إذا + +257 +00:23:42,210 --> 00:23:46,890 +بتعملوا مقارنة مع البيرول البيرول تقريبا كان من + +258 +00:23:46,890 --> 00:23:51,290 +أضعف الحلقات الثلاث لإنه بيعمل Cycle Addition + +259 +00:23:51,290 --> 00:23:55,830 +reactions أو بيتفاعل كدايين الأول ما احنا اتكلمنا عن + +260 +00:23:55,830 --> 00:23:59,730 +الفيوران وقلنا إن ال Aromaticity فيه ضعيفة + +261 +00:23:59,730 --> 00:24:05,210 +وبالتالي عمل Addition فبنقدر نتخيل إن هذا الفيوران + +262 +00:24:05,210 --> 00:24:10,710 +أيضا بشكل أكبر ممكن يتعامل كأنه داين يعني مش كتير + +263 +00:24:10,710 --> 00:24:15,310 +مُفْرَج مع هدول ال .. ال pi bonds إنهم يكونوا رابطين + +264 +00:24:15,310 --> 00:24:19,070 +حالهم مع هذه وإنهم عاملين وحدة واحدة اللي هي + +265 +00:24:19,070 --> 00:24:24,450 +اسمها إيش ال Aromatic cloud واضح؟ فبالتالي الفيوران + +266 +00:24:24,450 --> 00:24:30,370 +بشكل كبير بيشتغل كداين يعني الأمثلة على ال Cycle + +267 +00:24:30,370 --> 00:24:34,630 +Addition reactions of فيوران أو تحديدا Diels Alder + +268 +00:24:34,630 --> 00:24:37,610 +Cycle Addition reactions of فيوران، أزواج داين + +269 +00:24:37,610 --> 00:24:42,290 +موجودة كتير وعشان هيك بنقدر نعطيكوا Homework احنا + +270 +00:24:42,290 --> 00:24:48,500 +إنه جيبولنا أمثلة على ديالز ألدر Cycle Addition of + +271 +00:24:48,500 --> 00:24:53,080 +فيوران موجودة كثير الفيوران هنا بيتعامل كأنه داين + +272 +00:24:53,080 --> 00:24:57,620 +لو افترضنا هنا مع المالك انهايدريد بنقدر نعمل + +273 +00:24:57,620 --> 00:25:03,420 +نستكمل Cycle Addition ونكون الحلقة السداسية ولا + +274 +00:25:03,420 --> 00:25:09,960 +لأ؟ إيه؟ واحد اثنين ثلاثة أربعة خمسة ستة وضبط ال + +275 +00:25:09,960 --> 00:25:15,390 +bond واحدة مجرد إنه ال Oxygen رسمها لوين؟ على شكل + +276 +00:25:15,390 --> 00:25:20,550 +Bridge هذا عبارة عن Diels Alder Cycle Addition وهي + +277 +00:25:20,550 --> 00:25:24,550 +الحلقة السداسية اللي تكونت من ال Cycle Addition + +278 +00:25:24,550 --> 00:25:28,850 +مع الماليك Anhydride + +279 +00:25:30,310 --> 00:25:33,850 +كذلك الحال في الـ Cycloaddition مع الـ + +280 +00:25:33,850 --> 00:25:37,950 +Acrylonitrile بتعرفوا هذا المركب يمكن مار عليكم + +281 +00:25:37,950 --> 00:25:41,570 +اسمه Acrylonitrile ولو كان هنا C double bond OH + +282 +00:25:41,570 --> 00:25:46,870 +بيكون Acrylaldehyde ولو كان C double bond O O H + +283 +00:25:46,870 --> 00:25:51,650 +Acrylic Acid اه في Acrylic Acid Acrylonitrile + +284 +00:25:51,650 --> 00:25:57,670 +Acrylaldehyde الآن مع الفوران مرة ثانية مرة ثانية + +285 +00:25:57,670 --> 00:26:02,160 +التفاعل اللي بده يتم هو Diels-Alder reaction يعني + +286 +00:26:02,160 --> 00:26:07,400 +الفوران بده يمثل داين وهذا ال double bond هي + +287 +00:26:07,400 --> 00:26:12,340 +عبارة عن داين و file الآن جيد الكلام اللي موجود + +288 +00:26:12,340 --> 00:26:15,720 +هنا بفرجيكم كيف أنه + +289 +00:26:18,230 --> 00:26:22,450 +تغيير شروط التفاعل تغيير شروط التفاعل يعني لما + +290 +00:26:22,450 --> 00:26:30,750 +الطالب في المستقبل بده يشتغل بشغلة معينة يكون عنده + +291 +00:26:30,750 --> 00:26:35,490 +يعني القابلية لإنه ياخد ويعطي مع التفاعل يغير + +292 +00:26:35,490 --> 00:26:39,350 +الشروط لحد ما يصل للي بيسموها الـ optimum + +293 +00:26:39,350 --> 00:26:43,370 +conditions عشان هيك لما مرات أنتو بتشوفوا مثلا + +294 +00:26:43,370 --> 00:26:47,840 +واحد بيجي بيعمل رسالة ماجستير تلاقوه عمل بس تفاعل + +295 +00:26:47,840 --> 00:26:52,940 +واحد أول ما بيخطر على بالكم أنه تفاعل واحد عادة + +296 +00:26:52,940 --> 00:26:57,920 +احنا في حصة مختبر واحدة تلت ساعات بنعمل التفاعل و + +297 +00:26:57,920 --> 00:27:02,680 +بنطلع النتيجة بتتفاجأوا إن هذا البني آدم اشتغل خمس + +298 +00:27:02,680 --> 00:27:07,080 +ست شهور لحد ما عمل هذا التفاعل طب شو كان بيعمل + +299 +00:27:07,080 --> 00:27:12,400 +بالخمس ست شهور بيغير ال conditions لحد ما يصل لل + +300 +00:27:12,400 --> 00:27:17,460 +optimum conditions إيش أفضل شروط إيش أفضل شروط أنا + +301 +00:27:17,460 --> 00:27:23,480 +ممكن أعمل عليها التفاعل بأفضل مردود ومش دائما + +302 +00:27:23,480 --> 00:27:30,460 +بالمناسبة مش دائما مردود القوة هو الحل الأفضل لكل + +303 +00:27:30,460 --> 00:27:36,140 +التفاعلات يعني مرات كتيرة لما تتعاملوا حتى مع + +304 +00:27:36,140 --> 00:27:40,140 +البني آدمين حتى مع الأطفال الصغار ممكن لو ضربتوا + +305 +00:27:40,140 --> 00:27:45,900 +الطفل الصغير يصير عنده ردة فعل سلبية وعناد سلبي + +306 +00:27:45,900 --> 00:27:51,840 +وممكن بكلمة حلوة أو بحبة شوكولاتة بسيطة تاخدوا منه + +307 +00:27:51,840 --> 00:27:58,260 +أضعاف ما ممكن تاخدوا منه بالإيذاء أو بالضرب، + +308 +00:27:58,260 --> 00:28:02,520 +وعشان هيك يعني هذا التفاعل على سبيل المثال، لاحظوا + +309 +00:28:02,520 --> 00:28:06,940 +كيف عملوه بطرق مختلفة، تركوه على ال room + +310 +00:28:06,940 --> 00:28:12,700 +temperature يتحرك خمس أسابيع، في النهاية حصلوا على + +311 +00:28:12,700 --> 00:28:19,790 +yield 39% أجواء استعملوا ضغط عالي very very very + +312 +00:28:19,790 --> 00:28:23,750 +high atmospheric pressure very very high pressure + +313 +00:28:23,750 --> 00:28:28,410 +على أربع ساعات أعطاني خمسة وخمسين في المية + +314 +00:28:28,410 --> 00:28:34,110 +استعملوا Lewis acid zinc iodide لمدة ثمانية و + +315 +00:28:34,110 --> 00:28:39,790 +أربعين ساعة حصلوا على إيش؟ على 100% فهنا هذه ال + +316 +00:28:39,790 --> 00:28:44,690 +conditions اللي بيغيرها الإنسان هي جزء من عمل + +317 +00:28:44,690 --> 00:28:49,090 +التفاعلات يعني مش بس الإنسان بيعمل التفاعل أول مرة + +318 +00:28:49,090 --> 00:28:53,270 +وخلاص لأ والله طب أنتو عملتوا التفاعل لسه توي + +319 +00:28:53,270 --> 00:28:58,830 +كنا بنحكي في aprotic solvent طب يا تورى لو عملناها + +320 +00:28:58,830 --> 00:29:02,990 +في protic solvent لاحظته قبل شوية كيف التفاعل هنا + +321 +00:29:02,990 --> 00:29:07,010 +اتغير ما بين الـ protic solvent وما بين الـ + +322 +00:29:07,010 --> 00:29:11,770 +aprotic solvent ما بين الحرارة الضغط الاستعمال + +323 +00:29:11,770 --> 00:29:18,280 +catalyst هنا استعملوا Lewis acid في النهاية حصلوا + +324 +00:29:18,280 --> 00:29:25,140 +على 100% yield خلال 48 ساعة، كل أحوال هذه شروط + +325 +00:29:25,140 --> 00:29:31,300 +تعتبر سهلة وممتازة، فهذا هو وظيفة الإنسان اللي + +326 +00:29:31,300 --> 00:29:37,810 +بيشتغل في المختبر إنما شخص خلط مادتين ومن أول مرة + +327 +00:29:37,810 --> 00:29:40,590 +ضمن الظروف اللي استعملها ما طلعش نتيجة لأ والله + +328 +00:29:40,590 --> 00:29:44,990 +التفاعل بيمشيش طب يمكن التفاعل متأثر بالرطوبة يمكن + +329 +00:29:44,990 --> 00:29:49,870 +ال solvent اللي حاطه وأنت مش مناسب يمكن التفاعل بده + +330 +00:29:49,870 --> 00:29:54,950 +تسخين يمكن التفاعل بده dry conditions يمكن التفاعل + +331 +00:29:54,950 --> 00:30:00,770 +بده يكون under inert gas كل هذه الأشياء بتكون جزء + +332 +00:30:00,770 --> 00:30:06,850 +من الـ جزء من العمل المخبري اللي الإنسان بده يطور + +333 +00:30:06,850 --> 00:30:10,670 +روحه عليه لو اشتغل في الـ heterocyclic chemistry + +334 +00:30:10,670 --> 00:30:16,590 +ولذلك كل مقال أنتو بتقرأوه هتلاحظوه معادلة لكن + +335 +00:30:16,590 --> 00:30:20,850 +غالبا كل مقال هو نتاج رسالة ماجستير أو جزء من + +336 +00:30:20,850 --> 00:30:24,910 +رسالة دكتوراه أخدت أشهر إذا ما أخدتش سنين هو البني + +337 +00:30:24,910 --> 00:30:32,000 +آدم إيش بيعمل يظبط ال conditions تفاعلات + +338 +00:30:32,000 --> 00:30:37,840 +Cycloaddition إضافة مثلا هذا التفاعل مع الـ triple + +339 +00:30:37,840 --> 00:30:43,000 +bond اللي هو Dimethylacetylene dicarboxylate مع + +340 +00:30:43,000 --> 00:30:47,900 +الفوران الفوران مرة ثانية بده يتفاعل كأنه داين + +341 +00:30:47,900 --> 00:30:54,280 +طبعا إذا كان التفاعل مع الـ triple bond كم double + +342 +00:30:54,280 --> 00:30:58,020 +bond هنشوف في Diels-Alder reaction نتين هذا لو + +343 +00:30:58,020 --> 00:31:01,740 +فعلناه مع الـ H plus هتفتح الحلقة يصير عندي OH + +344 +00:31:01,740 --> 00:31:07,580 +ويجيني كمان double bond كمان double bond صار عندي + +345 +00:31:07,580 --> 00:31:12,580 +مشتقة بنزين طبعا على بال مين بيختار لو جولة حضرت + +346 +00:31:12,580 --> 00:31:16,300 +هذا المركب اللي هو Benzene derivative إن هذا المركب + +347 +00:31:16,300 --> 00:31:17,300 +كان منطلقه + +348 +00:31:23,910 --> 00:31:29,970 +النفس المركب بدل ما يفعلوه مع H plus عملوله + +349 +00:31:29,970 --> 00:31:34,630 +Hydrogenation الآن هنا الـ Hydrogenation لسبب معين + +350 +00:31:34,630 --> 00:31:38,390 +صار selective Hydrogenation إيش يعني selective + +351 +00:31:38,390 --> 00:31:42,660 +Hydrogenation؟ يعني إنه في عنده نتين double bonds + +352 +00:31:42,660 --> 00:31:48,420 +يعني كان ممكن الـ Hydrogenation تتم هان أو هان فكما + +353 +00:31:48,420 --> 00:31:50,960 +يبدو الـ Hydrogenation راح على الـ double bond اللي + +354 +00:31:51,970 --> 00:31:57,790 +يعني ما فيش حواليها crowding ربما تمام فأعطانا هذا + +355 +00:31:57,790 --> 00:32:03,530 +المركب وهذا المركب بيعمل اللي بنسميه احنا retro + +356 +00:32:03,530 --> 00:32:07,650 +Diels-Alder يمكن مرت عليكم هذه الجملة لأن في Diels- + +357 +00:32:07,650 --> 00:32:14,010 +Alder وفي retro ربما بالـ fragmentation بالـ mass + +358 +00:32:14,010 --> 00:32:20,610 +spectrometry أيضا مثل هذه الجملة بتمر طبعا لما بده + +359 +00:32:20,610 --> 00:32:24,120 +يعمل الـ Retro Diels-Alder Reaction كأننا بدنا نقول + +360 +00:32:24,120 --> 00:32:27,400 +إن هذا بدأ تتحرك بالشكل وهذا بدأ تتحرك بالشكل و + +361 +00:32:27,400 --> 00:32:35,180 +هذا بدأ تتحرك بالشكل ف CH2 CH2 هتفقد على شكل الكين + +362 +00:32:36,080 --> 00:32:41,300 +CH2 CH2 هات تحركت صار الكين والإيثالين وأنا + +363 +00:32:41,300 --> 00:32:47,400 +حصلنا على a new furan derivative فلو أجينا وسألنا + +364 +00:32:47,400 --> 00:32:54,180 +والله مبتدئين من الفوران هذا unsubstituted furan + +365 +00:32:54,180 --> 00:32:58,880 +حصلنا على one two three four three four + +366 +00:33:03,280 --> 00:33:10,360 +في فوران كيف تم هذا عبر هذه السلسلة Diels-Alder + +367 +00:33:10,360 --> 00:33:18,380 +Hydrogenation Retro Retro Diels-Alder Retro cycle + +368 +00:33:18,380 --> 00:33:22,360 +addition واضح + +369 +00:33:22,360 --> 00:33:31,050 +هذه الفكرة وطبعا كيف حضرنا مشتق بنزين أيضا من + +370 +00:33:31,050 --> 00:33:35,770 +الفوران طبعا في كل الأحوال يعني مثل هذه الأشياء + +371 +00:33:35,770 --> 00:33:43,370 +هي حقيقة يعني من عجاب الكيمياء اللي قبل ما الناس + +372 +00:33:43,370 --> 00:33:46,610 +يفهموا الكيمياء كانت الكيمياء بالنسبة لهم قمر إيش + +373 +00:33:46,610 --> 00:33:50,550 +غريب إن أنت تبدأ فوران تطلع فوران ثاني تبدأ + +374 +00:33:50,550 --> 00:33:55,460 +في فوران تطلع بنزين لكن لاحظوا اللي بيحلل الأمور + +375 +00:33:55,460 --> 00:34:00,620 +بهدوء بيقدر يستوعب كيف بتتم التفاعلات الكيميائية + +376 +00:34:00,620 --> 00:34:05,380 +وهذا في النهاية مثل هذه الخلاصة هي اللي أنتو لازم + +377 +00:34:05,380 --> 00:34:11,720 +تصلوا لها في المستوى الرابع تقريبا هذه فكرة خلينا + +378 +00:34:11,720 --> 00:34:17,280 +نقول عن الفوران وتفاعلاته يمكن من أهم الشغلات + +379 +00:34:17,280 --> 00:34:22,430 +اللي لاحظتوها إن الفوران بيعمل addition وبيعمل + +380 +00:34:22,430 --> 00:34:30,590 +cycle addition وبيعمل Diels-Alder cycle addition + +381 +00:34:30,590 --> 00:34:37,610 +as a داين يعني كداين الفوران بيشتغل + +382 +00:34:37,610 --> 00:34:39,290 +كداين + +383 +00:34:47,390 --> 00:34:51,590 +إذا انتقلنا للحلقة الأخيرة اللي إن شاء الله + +384 +00:34:51,590 --> 00:34:57,430 +بندرسها في هذا المساق اللي هو الـ Thiophene طبعا + +385 +00:34:58,200 --> 00:35:05,000 +دائما بنقول إيش الـ importance للثيوفين يمكن + +386 +00:35:05,000 --> 00:35:08,400 +جايبين مركبين من المركبات اللي بتحتوي على + +387 +00:35:08,400 --> 00:35:12,660 +الـ thiphene في هذا الـ slide هذا المركب اسمه Byron + +388 +00:35:12,660 --> 00:35:17,920 +Tal هذا الـ Byron Tal مكتوب عليه is a broad + +389 +00:35:17,920 --> 00:35:22,980 +spectrum anthelmintic agent effective against mainly + +390 +00:35:22,980 --> 00:35:30,400 +pinworm and hookworm طبعا المفروض تكونوا عارفين إيش + +391 +00:35:30,400 --> 00:35:35,720 +معنى broad spectrum لما تمر معاكم Broad Spectrum + +392 +00:35:35,720 --> 00:35:41,960 +بتمر... بـ antibiotic مثلا بتلاقوا بيستعملوا Broad + +393 +00:35:41,960 --> 00:35:47,000 +Spectrum الآن اللي بيقصدوا في هذه الحالة أنها تقضي + +394 +00:35:47,000 --> 00:35:51,180 +على أنواع كثيرة مختلفة من البكتيريا بشكل أساس لو + +395 +00:35:51,180 --> 00:35:53,860 +قالوا Broad Spectrum Antibacterial Agent يعني + +396 +00:35:53,860 --> 00:35:58,640 +بيقضي على بكتيريا موجبة لجررام وسالبة لجررام جرام + +397 +00:35:58,640 --> 00:36:02,600 +positive و جرام negative بكتيريا الآن هذا المركب + +398 +00:36:02,600 --> 00:36:06,480 +broad spectrum anthelmintic agent يعني قاتل + +399 +00:36:06,480 --> 00:36:13,380 +للديدان وخصوصا اللي بيسموها الـ pinworm، ما أعرفش + +400 +00:36:13,380 --> 00:36:20,410 +إذا مرت عليكم الـ pinworm هادي ولا لأ لكن عادة طالما + +401 +00:36:20,410 --> 00:36:25,590 +إن أنتو يعني أمهات جيد إنكوا تكونوا عارفين الـ pin + +402 +00:36:25,590 --> 00:36:31,230 +worm جيدا هذه دودة صغيرة بيضة تقريبا بتكون الطول + +403 +00:36:31,230 --> 00:36:37,600 +تبعها 1 سم وبتكون موجودة كثير عند الأطفال + +404 +00:36:37,600 --> 00:36:42,140 +و بتنتقل عدوى ما بين الأطفال بعض و من بعض بالذات + +405 +00:36:42,140 --> 00:36:47,620 +الأطفال الصغار وعادة الأمهات بيشوفوا هذه الدودة + +406 +00:36:47,620 --> 00:36:51,380 +... هذه الدودة لما بيغيروا للأطفال يعني مع الـ... مع + +407 +00:36:51,380 --> 00:36:54,920 +البراز ع، الفتحة، الشرج المشكلة هذه لما بتطلع و + +408 +00:36:54,920 --> 00:37:00,700 +بتحط البيض بتؤلم الطفل كثير و بالتالي بتعمل حساسية + +409 +00:37:01,370 --> 00:37:06,290 +بتعمل حساسية كتير لازم ياخدوا علاج ولازم كل + +410 +00:37:06,290 --> 00:37:09,890 +الملابس بتاعة الطفل وغيرها وغيرها كمان تنغسل + +411 +00:37:09,890 --> 00:37:16,830 +بماء ساخن ويكون في حذر من العدوى بين الأطفال شايف + +412 +00:37:16,830 --> 00:37:24,290 +في تعليق زي اللي مش عاجبك الكلام أو عندك ايوة + +413 +00:37:24,290 --> 00:37:30,710 +اه اه اللي هي الـ pin worm والـ hookworm وما إلى + +414 +00:37:30,710 --> 00:37:37,990 +ذلك المركب الثاني اللي هو اللي بنسميه بيوتين أو + +415 +00:37:37,990 --> 00:37:42,490 +vitamin H هذا اللي موجود في الخميرة وفي البيض و + +416 +00:37:42,490 --> 00:37:46,810 +يمكن لهذا السبب الخميرة والبيض مع الزمن بتاعة + +417 +00:37:46,810 --> 00:37:52,050 +الرائحة السيئة ليش؟ لأنها بتحتوي في النهاية على الـ + +418 +00:37:52,050 --> 00:37:56,250 +sulfur الكبريت والـ sulfur هيعطي الـ H2S والـ SO2 وما + +419 +00:37:56,250 --> 00:38:03,870 +إلى ذلك مركبات كبريتية الآن بالنسبة للـ ring + +420 +00:38:03,870 --> 00:38:10,310 +synthesis في عندنا الـ synthesis الشهير اللي هو من + +421 +00:38:10,310 --> 00:38:14,790 +الـ 1,4-dicarbonyl compounds اللي قولنا بنحضر منها + +422 +00:38:15,910 --> 00:38:20,710 +فيورانو ثيوفين و بايرول اللي هو لما نحضر الثيوفين + +423 +00:38:20,710 --> 00:38:26,670 +لازم نحول واحدة من C=O بالبوند أو إلى Sulfur هذا + +424 +00:38:26,670 --> 00:38:32,210 +الكلام ممكن يتم بالـ before استن إذا تم هذا التحويل + +425 +00:38:32,210 --> 00:38:36,650 +بعد هيك عملية الـ addition عملية يعني ما فيش فيها + +426 +00:38:36,650 --> 00:38:40,170 +مشكلة لكن أهم شيء أنه أنا بدي أحول C=O بالبوند أو + +427 +00:38:40,170 --> 00:38:45,570 +إلى C=S فالـ reagent اللي بيستعمل عادة + +428 +00:38:45,570 --> 00:38:50,710 +لتحويل C=O لـ C=S هو before + +429 +00:38:50,710 --> 00:38:52,170 +S10 + +430 +00:38:56,060 --> 00:39:04,380 +P2S5 Sulphide واضح؟ الآن في عندنا Reagent أو H2S مع + +431 +00:39:04,380 --> 00:39:10,280 +HCl برضه بيمشي في عندنا Reagent مشهور كثير بتشوفوه + +432 +00:39:10,280 --> 00:39:14,900 +اللي هو Lawesson's Reagent هذا برضه Reagent بيحول + +433 +00:39:14,900 --> 00:39:20,520 +الـ C=O إلى C=S Lawesson's + +434 +00:39:20,520 --> 00:39:27,670 +Reagent بينشر متوفر كثير في عندنا مثلًا هذا مثلًا + +435 +00:39:27,670 --> 00:39:33,490 +هذا Tetrazolione بـ C=O مع الـ Lawesson's + +436 +00:39:33,490 --> 00:39:42,070 +Reagent Tetrazothiole Tetrazothiole هيتحول لـ C + +437 +00:39:42,070 --> 00:39:51,530 +=S التحول إلى C=S الآن + +438 +00:39:51,530 --> 00:39:57,150 +الـ synthesis التاني اللي هو الـ Hinsberg Synthesis + +439 +00:39:57,150 --> 00:40:00,510 +of Thiophene في الـ Hinsberg Synthesis of + +440 +00:40:00,510 --> 00:40:05,890 +Thiophene بناخد احنا 1,2-Diketo System يعني C + +441 +00:40:05,890 --> 00:40:10,670 +=O متجاورت على موقع واحد واتنين 1,2 + +442 +00:40:10,670 --> 00:40:15,350 +-Diketo system و بناخد مركب زي هذا الآن واضح أنه + +443 +00:40:15,350 --> 00:40:20,150 +المركب اللي زي هذا مخدينه احنا فيه activated مثلًا + +444 +00:40:20,150 --> 00:40:25,110 +groups CH2 CH2 كان ممكن أنتم تتخيلوا كان ممكن + +445 +00:40:25,110 --> 00:40:25,910 +تتخيلوا + +446 +00:40:30,520 --> 00:40:37,720 +ROR أن هذا التفاعل ببساطة لما يعمل حلقة في وجود + +447 +00:40:37,720 --> 00:40:42,140 +base Sodium ethoxide مستعمل أن هنا سيصبح لدي + +448 +00:40:42,140 --> 00:40:46,500 +C=O وهنا سيصبح لدي C=S + +449 +00:40:46,500 --> 00:40:50,060 +C-C=C + +450 +00:40:50,060 --> 00:40:56,180 +هيثيوفيل واضح يعني يصبح هنا أيون سالب يهاجم على الـ + +451 +00:40:56,180 --> 00:41:00,740 +C=O وهنا Ion سالب هاجم على الـ C + +452 +00:41:00,740 --> 00:41:04,060 +=O وفي الحالتين O-H مع H O-H مع H + +453 +00:41:04,060 --> 00:41:08,340 +Double bonds لكن الحقيقة بتلاحظوا أنتم أنه + +454 +00:41:08,340 --> 00:41:15,980 +بالتفصيل عمل شوية أشياء إضافية ليش كل ... ليش عمل كل + +455 +00:41:15,980 --> 00:41:20,200 +هذا الكلام؟ لو التفاعل تم بالطريقة اللي احنا + +456 +00:41:20,200 --> 00:41:24,700 +حكيناها ببساطة وهذه صارت C=O وهذه صارت + +457 +00:41:24,700 --> 00:41:30,900 +C=O وهنا R وR إيش بيكون شكل الناتج الأخير؟ + +458 +00:41:30,900 --> 00:41:37,120 +اتطلعوا معنا، هيكون R وR على موقع 3 و4 وCO2 إيثيل + +459 +00:41:37,120 --> 00:41:44,780 +وCO2 إيثيل الآن الناتج اللي طلع معه ما فيش فيه CO2 + +460 +00:41:44,780 --> 00:41:50,560 +إيثيل على الجهتين هنا في CO2 إيثيل هنا في عنده CO2 + +461 +00:41:50,560 --> 00:41:57,740 +minus واضح وبناء على ذلك صار مضطر أنه يحاول يفكر + +462 +00:41:57,740 --> 00:42:04,560 +ليش هذه بدل ما تكون CO2 إيثيل بيأتي على شكل CO2 + +463 +00:42:04,560 --> 00:42:09,460 +minus في النتيجة واحنا في الكيمياء عادة بنفسر + +464 +00:42:09,460 --> 00:42:13,140 +نتائج، يعني هنعمل التفاعل بين هدول، بنتوقع يطلع + +465 +00:42:13,140 --> 00:42:18,440 +R و R و CO2 و إيثيل على جهتين، الآن واحدة تطلع إيثيل + +466 +00:42:18,440 --> 00:42:23,040 +والتانية في النهاية acid CO2 minus، ما قالتش plus، + +467 +00:42:23,040 --> 00:42:32,600 +هتصير إيش؟ CO2H طبعًا التفسير مش كثير يعني غريب + +468 +00:42:32,600 --> 00:42:37,220 +بالتأكيد احنا في البداية .. بالتأكيد في البداية + +469 +00:42:37,220 --> 00:42:43,060 +هنعمل الـ ion السالب اللي موجود عندنا وهذا الـ ion + +470 +00:42:43,060 --> 00:42:48,600 +السالب بنخليه يهاجم على الـ C=O يعني هذا + +471 +00:42:48,600 --> 00:42:52,760 +أمر طبيعي يعني هيعملنا هنا الـ أيون السالب وخلناه + +472 +00:42:52,760 --> 00:42:56,300 +يهاجم على الـ C=O بناء على ذلك الـ C + +473 +00:42:56,300 --> 00:43:02,360 +=O شو بدها تصير الآن الـ O- بدها + +474 +00:43:02,360 --> 00:43:07,720 +تهاجم هنا لما تهاجم هان بهذا الشكل عبر اللي + +475 +00:43:07,720 --> 00:43:13,240 +بيسموها Tetrahedral Mechanism إذا مرت عليكم أنه هذه + +476 +00:43:13,240 --> 00:43:20,620 +هاجمت هذه بتصير O- وبعدين ترجع هذه وتترد + +477 +00:43:20,620 --> 00:43:26,760 +عندنا الـ O إيثيل وبناء على ذلك لما رجعت هذه هنا و + +478 +00:43:26,760 --> 00:43:33,360 +تردت الـ O إيثيل شو صار عندي C=O O- + +479 +00:43:33,360 --> 00:43:38,360 +ملاحظين أنتم صار عندي C=O O- لما + +480 +00:43:38,360 --> 00:43:45,080 +فتحت الحلقة من هنا وتردت الـ O إيثيل من هذا الموقع + +481 +00:43:45,080 --> 00:43:53,320 +الآن مرة ثانية خلوا هذه الـ CH2 تهاجم على C= + +482 +00:43:53,320 --> 00:43:58,640 +O اللي هنا تعمل OH وبعدين تعمل Elimination + +483 +00:43:58,640 --> 00:44:02,120 +يعني الـ key step .. الـ key step وين كانت في أي + +484 +00:44:02,120 --> 00:44:08,720 +من منطقة الخطوة الأساسية كانت في عبر تكوين هذه الحلقة + +485 +00:44:08,720 --> 00:44:12,760 +وأن تكون عند هنا C=O + +486 +00:44:18,740 --> 00:44:23,220 +التفسير اللي تم هو + +487 +00:44:23,220 --> 00:44:29,360 +عبر حلقة إشمالها سداسي يعني لاحظوا بدأ من هذه الـ H + +488 +00:44:29,360 --> 00:44:36,460 +وعملها أنا زي هيك صاروا خمسة bonds كسر من هنا فقدت + +489 +00:44:36,460 --> 00:44:43,020 +الـ H+ C=C كسر هذه هيك الذي يتابع الأسهم + +490 +00:44:43,020 --> 00:44:47,420 +بهدوء فيكم يستطيع أن يسأل كيف فقدت الـ O إثنين بعد + +491 +00:44:47,420 --> 00:44:52,660 +ذلك CH2 مع C=O بتقوله أمر روتيني أن CH2 مع + +492 +00:44:52,660 --> 00:44:55,680 +C=O سيعطينا CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +493 +00:44:55,680 --> 00:45:01,140 +مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +494 +00:45:01,140 --> 00:45:05,740 +مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +495 +00:45:05,740 --> 00:45:09,020 +مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +496 +00:45:09,020 --> 00:45:12,850 +مع CH2 مع CH2 مع CH2 مع CH2 مع ما طلعش عندي Ester + +497 +00:45:12,850 --> 00:45:19,210 +على الجهتين فكان لابد من يعني محاولة تفسير + +498 +00:45:19,210 --> 00:45:27,210 +Synthesis ثالث بيسموه Gewald Synthesis طبعًا في + +499 +00:45:27,210 --> 00:45:33,330 +عنده C=O على position Alpha SH مع X + +500 +00:45:33,330 --> 00:45:39,910 +CH2 CN X أي مجموعة في + +501 +00:45:39,910 --> 00:45:47,210 +وجود في وجود base بتكون هذه الـ CH2 بتكون هذه الـ + +502 +00:45:47,210 --> 00:45:54,090 +CH2 activated مثلًا group هذه الـ CH2 اللي موجودة + +503 +00:45:54,090 --> 00:45:59,730 +خلينا هيك نقولها CH2 في جهة معينة إيش في حواليها + +504 +00:45:59,730 --> 00:46:06,710 +CN و في جهة ثانية ممكن نقول CN الـ X يعني افترضوها + +505 +00:46:06,710 --> 00:46:14,690 +هاي مثال عليها صارت CH2 بين اثنتين CN اللي هو إيش + +506 +00:46:14,690 --> 00:46:21,410 +هذا كنتوا تسموه لما يكون Ethyl malonate Ethyl هذا + +507 +00:46:21,410 --> 00:46:25,810 +الـ malonate Neutral لما يكون Ethyl و Ethyl + +508 +00:46:25,810 --> 00:46:30,830 +الـ malonate Ethyl الـ malonate Neutral الآن الـ CH2 مع + +509 +00:46:30,830 --> 00:46:35,730 +الـ C=O شو بدهم يعملوا؟ C=C + +510 +00:46:35,730 --> 00:46:40,670 +بمعنى تفقد الـ H2 مع الـ O يعني هذا في وجود الـ base + +511 +00:46:40,670 --> 00:46:46,610 +يصير minus بهاجم OH OH مع الـ H CH2 مع C= + +512 +00:46:46,610 --> 00:46:51,230 +O هذه اللي كانت CH2 وهذه اللي كانت C= + +513 +00:46:51,230 --> 00:46:56,750 +O إذا تم التفاعل بهذا الشكل وصار عندي Carbon + +514 +00:46:56,750 --> 00:47:00,050 +=C من خلال هذا التفاعل تحديدا + +515 +00:47:02,930 --> 00:47:06,230 +بعد هيك الـ Sulfur in nucleophile تذكير على الـ Amino + +516 +00:47:06,230 --> 00:47:10,450 +groups كلنا متذكرين أنه التذكير عفوًا على الـ + +517 +00:47:10,450 --> 00:47:16,830 +Neutral group بيعطينا Finally Amino بيصير عندنا في + +518 +00:47:16,830 --> 00:47:22,510 +الخطوة الأولى Amine والـ Amine بيعمل Tautomerization + +519 +00:47:22,510 --> 00:47:28,990 +لـ Enamine فبيطلع عندنا هذا المركب إذا تفصيل هذا + +520 +00:47:28,990 --> 00:47:32,950 +التفاعل هو تفصيل سهل ضمن المبادئ العامة اللي احنا + +521 +00:47:32,950 --> 00:47:37,570 +اتعلمناها اللي هي تكوين أيون سالب Addition على C + +522 +00:47:37,570 --> 00:47:44,770 +=O بعدين Exo Addition على الـ Neutral + +523 +00:47:44,770 --> 00:47:53,290 +بيعطينا Enamine كمحصلة ويمكن بتقدروا تحسوا أنتم + +524 +00:47:53,290 --> 00:47:59,310 +الآن أنه قد إيش بيكون مفيد لما احنا درسنا المبادئ + +525 +00:47:59,310 --> 00:48:02,370 +العامة .. درسنا المبادئ العامة للكيمياء الحلقية و + +526 +00:48:02,370 --> 00:48:05,470 +بعدين اجينا ناخذ الأمثلة يعني لو احنا كنا بدنا + +527 +00:48:05,470 --> 00:48:10,170 +نبدأ بالـ Thiophene أو بالـ Thiophene Derivative وبدنا هنا + +528 +00:48:10,170 --> 00:48:14,150 +واحنا مش متعودين نشوف كيف الـ Nucleophile بيسكر على الـ + +529 +00:48:14,150 --> 00:48:19,400 +CN وبيعطينا الـ Enamine احنا أخذنا الفكرة العامة أن + +530 +00:48:19,400 --> 00:48:23,740 +Nucleophile بيعمل Cyclization على الـ C أن بيعطينا + +531 +00:48:23,740 --> 00:48:28,600 +Amine والـ Amine بيعمل Enamine الـ A مرت علينا في + +532 +00:48:28,600 --> 00:48:34,360 +تحضير الـ Thiophene ما بتكونش فكرة إيش؟ ما بتكونش فكرة + +533 +00:48:34,360 --> 00:48:41,740 +صعبة بالنسبة للـ reactions of Thiophene الـ + +534 +00:48:41,740 --> 00:48:45,700 +Electrophilic Substitution بشكل عام على الـ Thiophene + +535 +00:48:45,700 --> 00:48:51,010 +أيضًا بتم على موقع اثنين يعني في الـ Pyrrole والـ Furan + +536 +00:48:51,010 --> 00:48:54,710 +والـ Thiophene الـ Electrophilic Substitution الموقع + +537 +00:48:54,710 --> 00:48:59,430 +الأساسي اللي هو موقع إيش اثنين الآن أمثلة Nitration + +538 +00:48:59,430 --> 00:49:04,030 +Halogenation الـ Formulation الأمثلة كثيرة ما يعني + +539 +00:49:04,030 --> 00:49:07,530 +بدناش ناخذ أي مثال فيها بشكل عام لكن بنقول احنا + +540 +00:49:07,530 --> 00:49:11,010 +بشكل عام Electrophilic Substitution occurs at + +541 +00:49:11,010 --> 00:49:19,570 +position two لو اجينا للـ Reactivity مين فيهم؟ أنشط + +542 +00:49:19,570 --> 00:49:21,890 +في الـ Electrophilic Substitution، حكينا هذا + +543 +00:49:21,890 --> 00:49:26,770 +الكلام، أن الـ Pyrrole أنشط كثير من الـ Furan، + +544 +00:49:26,770 --> 00:49:33,170 +الـ Furan أنشط من الـ Thiophene وكلهم أنشط من الـ Benzene + +545 +00:49:35,400 --> 00:49:41,080 +الآن الـ Furan لاحظ ما في ملاحظة بتختلف عليهم أنه + +546 +00:49:41,080 --> 00:49:46,100 +كان هو أكثر واحد بيعمل إيش Addition يعني بالإضافة + +547 +00:49:46,100 --> 00:49:49,300 +للـ Substitution الـ Furan اللي بيميز أنه بيعمل + +548 +00:49:49,300 --> 00:49:52,820 +Addition يعني الـ Thiophene لسه معظم تفاعلاته + +549 +00:49:53,490 --> 00:49:57,670 +Substitution الـ Addition فيه قليل أكثر واحد في + +550 +00:49:57,670 --> 00:50:02,790 +هدول الثلاثة بيعملوا Addition اللي هو الـ Furan أكثر + +551 +00:50:02,790 --> 00:50:11,130 +واحد بيعمل Addition اللي هو الـ Furan طبعًا لو اجينا + +552 +00:50:11,130 --> 00:50:15,470 +للـ Cycle Addition وعملنا مقارنة بينهم قولنا الـ Pyrrole + +553 +00:50:15,470 --> 00:50:21,300 +بيعمل Cycle Addition قليل جدًا، الـ Furan لأ + +554 +00:50:21,300 --> 00:50:28,300 +بيشتغل كـ Dien بشكل أساسي، الـ Thiophene بيشتغل كـ Dien + +555 +00:50:28,300 --> 00:50:33,840 +وبيشتغل كـ Dien وفاعل يعني ممكن يتم التفاعل فيه as a + +556 +00:50:33,840 --> 00:50:37,600 +Diene على اثنتين Double Bonds وممكن يتم على واحدة + +557 +00:50:37,600 --> 00:50:40,920 +من الـ Double Bonds فقط على واحدة من الـ Double + +558 +00:50:40,920 --> 00:50:47,320 +Bonds واجهته بيكون بيشتغل كـ ايش كـ Dienophile الآن + +559 +00:50:47,320 --> 00:50:54,500 +لاحظوا معنى أنه أحيانًا بيجيبوا أمثلة أنه يا ترى الـ + +560 +00:50:54,500 --> 00:50:59,730 +Electrophilic Substitution بتتم على موقع اثنين طيب + +561 +00:50:59,730 --> 00:51:06,110 +لو جبنا ثيوفين و موقع اثنين فيه مشغول أساسا و + +562 +00:51:06,110 --> 00:51:12,070 +جربنا أن نعمل نيتراشن وين بده يتم؟ يعني هم هنا + +563 +00:51:12,070 --> 00:51:18,800 +شغالين و موقع اثنين وعملوا الـ Nitration طبعا لاحظوا + +564 +00:51:18,800 --> 00:51:21,280 +أنه لو كانت المجموعة اللي هي على موقع اثنين + +565 +00:51:21,280 --> 00:51:25,120 +electron releasing ال Nitration بتتم على موقع خمسة + +566 +00:51:25,120 --> 00:51:28,440 +اللي هو كأنه اثنين من الجهة الثانية و لو كانت + +567 +00:51:28,440 --> 00:51:31,960 +المجموعة electron withdrawing ال Nitration بتتم + +568 +00:51:31,960 --> 00:51:39,520 +على موقع أربعة واحد اثنين ثلاثة أربعة طبعا واضح + +569 +00:51:39,520 --> 00:51:44,930 +بالإضافة إلى موقع خمسة بنسب معينة واضح أن هذا ال + +570 +00:51:44,930 --> 00:51:51,590 +slide هي slide إيش تجريبية يعني بدون ما الإنسان + +571 +00:51:51,590 --> 00:51:57,390 +يكون عنده تجربة مش هيصل لهذا الكلام يعني في نهاية + +572 +00:51:57,390 --> 00:52:07,070 +نتيجة تجريبية الآن سكروا عليه موقع اثنين وخمسة + +573 +00:52:09,370 --> 00:52:14,150 +وبناءً على ذلك عملوا له Acetylation لاحظوا أنه تم + +574 +00:52:14,150 --> 00:52:20,950 +التفاعل على موقع ثلاثة وتم أيضًا إبدال + +575 +00:52:20,950 --> 00:52:26,130 +Electrophilic Substitution على موقع خمسة لاحظوا + +576 +00:52:26,130 --> 00:52:32,480 +هنا شلنا احنا R Plus وحطينا مكانها C O Methyl + +577 +00:52:32,480 --> 00:52:35,340 +Plus يعني هذا الإبدال Electrophilic Substitution + +578 +00:52:35,340 --> 00:52:39,360 +زي ما كنا نشيل H Plus ونحط بدالها Electrophile + +579 +00:52:39,360 --> 00:52:45,140 +هنا shall be R Plus هنا يمكن نستعمل كلمة Ipso + +580 +00:52:45,140 --> 00:52:50,660 +ما أعرفش إذا هذه الكلمة مرت عليكم ولا لأ Ipso معناها + +581 +00:52:50,660 --> 00:52:55,300 +على نفس الموطن يعني عادة لما بيتم ال substitution + +582 +00:52:55,300 --> 00:52:58,120 +في ال aromatic compounds لو افترضنا أن هنا في + +583 +00:52:58,120 --> 00:53:01,740 +مجموعة X احنا كنا نقول أن ال substitution ممكن يتم + +584 +00:53:01,740 --> 00:53:06,630 +على ال ortho، على الميتا، على البارا، إبدال هذه Ortho، + +585 +00:53:06,630 --> 00:53:09,250 +هذه ميتا، هذه بارا، طب لو الإبدال يجي محل هذه + +586 +00:53:09,250 --> 00:53:16,430 +نفسها، وقتها بنسميه Ipso substitution، واضح؟ فكل + +587 +00:53:16,430 --> 00:53:22,070 +هذه الأمثلة واضح تمامًا أنها أمثلة تجريبية + +588 +00:53:24,240 --> 00:53:29,140 +طبعًا هل ممكن يتم عند الـ nucleophilic substitution + +589 +00:53:29,140 --> 00:53:34,880 +أيضًا جربوا أنهم يفعلوا هذا المركب مع نيوكليوفايل + +590 +00:53:34,880 --> 00:53:42,580 +أمين جابوا أمين و الأمين هو نيوكليوفايل في النهاية + +591 +00:53:42,580 --> 00:53:49,010 +الأمين حل ما حل إيش ال PR minus في المحصلة عبر + +592 +00:53:49,010 --> 00:53:51,630 +ميكانيزم الـ Nucleophilic Substitution زي اللي + +593 +00:53:51,630 --> 00:53:55,350 +حكيناها أول ما تكلمنا عن الـ Chichibabine + +594 +00:53:55,350 --> 00:54:01,530 +reaction وغيره بنفس المنطق بإمكانه لـ Nucleophile + +595 +00:54:01,530 --> 00:54:05,490 +يهاجمها تتحرك البن تتحرك لاحظوا الـ Nitro اللي هنا + +596 +00:54:05,490 --> 00:54:10,610 +ساعد على إتمام الـ Nucleophilic Substitution يمكن + +597 +00:54:10,610 --> 00:54:14,890 +أنتم مروا معكم حتى على البنزين الـ Nucleophilic + +598 +00:54:14,890 --> 00:54:22,180 +Substitution كان ممكن وين؟ آه يعني في البنزين + +599 +00:54:22,180 --> 00:54:26,060 +المثال المشهور المثال المشهور اللي بتنفي ال + +600 +00:54:26,060 --> 00:54:30,880 +nucleophilic substitution لما يكون عندي Cl وثلاثة + +601 +00:54:30,880 --> 00:54:36,840 +نيترو الآن هذه النيترو بتسحب الإلكترونات وبناء على + +602 +00:54:36,840 --> 00:54:42,020 +ذلك طالما في كثير مجموعات بتسحب الإلكترونات بإمكان + +603 +00:54:42,020 --> 00:54:49,600 +ال nucleophile يجي يهاجم زي مثلًا ال OH minus نأخذ + +604 +00:54:49,600 --> 00:54:53,220 +الـ Nucleophile in this case الـ OH minus بإمكانه + +605 +00:54:53,220 --> 00:54:57,360 +يهاجم هنا وجد هال minus مراح ينحمل على هذيك ال O مرة + +606 +00:54:57,360 --> 00:55:02,660 +هان مرة هان يعني في مجموعات مساعدة لكن لو فعلنا + +607 +00:55:02,660 --> 00:55:08,300 +لchlorobenzene لحاله مع ال OH minus بتتمي إبدال بس + +608 +00:55:08,300 --> 00:55:11,000 +ل Trinitrochlorobenzene + +609 +00:55:11,870 --> 00:55:14,870 +مع ال sodium hydroxide يمكن شوية تسخين كان بتتم + +610 +00:55:14,870 --> 00:55:19,430 +الإبداء فلاحظوا أنا كيف تدخل ال nitro group في + +611 +00:55:19,430 --> 00:55:23,110 +المساعدة على إتمام إيش ال nucleophilic + +612 +00:55:23,110 --> 00:55:26,610 +substitution يعني هذا بيهاجم هان بتتحرك هذي بتتحرك + +613 +00:55:26,610 --> 00:55:33,450 +هذي صفية السالب في الآخر وين صفة محمول؟ على ال Oxygen + +614 +00:55:33,450 --> 00:55:36,510 +فال Oxygen بتاعة ال Nitro ساعدت في حملة السالب + +615 +00:55:36,510 --> 00:55:40,830 +بعدها لو كل شيء رجع زي ما كان هذي رجعت هذي رجعت هذي + +616 +00:55:40,830 --> 00:55:48,950 +رجعت إيش هيطرد عليه ال PR minus واضح ال PR minus + +617 +00:55:48,950 --> 00:55:54,970 +بالنسبة + +618 +00:55:54,970 --> 00:56:01,180 +لل Cycloaddition reactions الثيوفين ممكن يشتغل + +619 +00:56:01,180 --> 00:56:05,520 +كدايين وهي الدليل على ذلك تفاعله مع المليك + +620 +00:56:05,520 --> 00:56:11,540 +أنهيدرايد هذا بتابع له تفاعل مشهور جدًا بهذا الشكل + +621 +00:56:11,540 --> 00:56:15,800 +بيكمل وبيعمل Diels Alder cycle addition الآن هنا + +622 +00:56:15,800 --> 00:56:21,060 +الثيوفين اشتغل كإيش؟ داين هو في النهاية بور داين + +623 +00:56:21,060 --> 00:56:25,580 +يعني مش داين قوي زي الفيوران يعني اللي بيشوف + +624 +00:56:25,580 --> 00:56:30,080 +أمثلة لفيوران وأمثلة لثيوفين مين بيشتغل أكثر + +625 +00:56:30,080 --> 00:56:37,620 +كداين؟ الفيوران هي مثال ثاني بهذا المثال الثاني من + +626 +00:56:37,620 --> 00:56:42,500 +هذا الجزء .. هذا التفاعل المشهور بيعمل له .. اللي + +627 +00:56:42,500 --> 00:56:46,300 +إيش بنسميه احنا؟ بنزين .. بنزين .. آه كلكم + +628 +00:56:46,300 --> 00:56:49,640 +عارفينه البنزين، الآن البنزين مع الفيوران + +629 +00:56:52,600 --> 00:56:57,280 +هيعمل Cycloaddition Diels Alder Cycloaddition هيكون + +630 +00:56:57,280 --> 00:57:01,940 +عنده هذه ال triple bond تصير double bond ومن ال + +631 +00:57:01,940 --> 00:57:06,420 +Cycloaddition من Diels Alder كمان double bond الآن + +632 +00:57:06,420 --> 00:57:12,480 +هذا بعد هيك بيفقد السلفر فقد السلفر هيعطيني ash + +633 +00:57:12,480 --> 00:57:18,580 +كمان by product السلفر لما بيطلع في النهاية ما بيصير + +634 +00:57:18,580 --> 00:57:22,160 +يتجمع على شكل ash الصورة الطبيعية اللي بيطلع فيها + +635 +00:57:22,160 --> 00:57:28,980 +أسيت .. أسيت مش السلفر في الطبيعة ال allotropic + +636 +00:57:28,980 --> 00:57:36,740 +form يعني على أي allotrope S8 واضح؟ بيطلع على شكل + +637 +00:57:36,740 --> 00:57:40,920 +S8 وحيللاحظوا يمكن اللي اشتغلوا التفاعل أنه بيكون + +638 +00:57:40,920 --> 00:57:46,340 +عندهم بودرة كبريت صفراء بيطلع على شكل بودرة صفراء + +639 +00:57:46,340 --> 00:57:53,500 +هنا أيضًا الخلاصة الثيوفين هنا اشتغل as داين في + +640 +00:57:53,500 --> 00:57:58,640 +هذا المثال مع البنزين الثيوفين اشتغل as داين + +641 +00:58:00,800 --> 00:58:10,820 +الآن أمثلة إضافية هنستعمل أيضًا ثيوفين مع + +642 +00:58:10,820 --> 00:58:17,930 +triple bond مرة ثانية يعمل Cycloaddition طلع عندي + +643 +00:58:17,930 --> 00:58:22,670 +مركب بكام bond؟ كام buy bond؟ اثنتين وفقد السلفر + +644 +00:58:22,670 --> 00:58:27,350 +جاب الثالثة يعني ال deal's elder reaction نفسه + +645 +00:58:27,350 --> 00:58:32,370 +بيعطينا buy bond ولـ triple bond كمان واحدة وفقد + +646 +00:58:32,370 --> 00:58:38,810 +السلفر آه فعلى بال مين أن هذا المركب جاي من وين؟ من + +647 +00:58:38,810 --> 00:58:45,670 +ثيوفين، الآن في هذا المثال، لأ شوية الكلام مختلف، + +648 +00:58:45,670 --> 00:58:50,610 +هم فعلوا الثيوفين، لكن المرة هذه بدنا نرسم + +649 +00:58:50,610 --> 00:58:52,310 +الثيوفين بهذا الشكل + +650 +00:58:55,040 --> 00:59:01,280 +اتفعل كداينوفايل يعني على double bond واحدة منه + +651 +00:59:01,280 --> 00:59:05,780 +وهذا كان عبارة عن الداين خلينا نقول اللي بده يفقد + +652 +00:59:05,780 --> 00:59:09,700 +إيش في النهاية ال nitrogen هذا masked ديين + +653 +00:59:09,700 --> 00:59:14,680 +التترازيل مر علينا لما تكلمنا عن masked ديين هو + +654 +00:59:14,680 --> 00:59:21,600 +عبارة عن masked ديين فلما تم التفاعل على هذه ال + +655 +00:59:21,600 --> 00:59:28,810 +bondواضح وفقدت ال double bond فقدت ال nitrogen + +656 +00:59:28,810 --> 00:59:35,130 +عملها double bond لاحظوا إيش اللي صار عنده صار + +657 +00:59:35,130 --> 00:59:41,170 +عنده fused compound صار عنده fused compound ولو + +658 +00:59:41,170 --> 00:59:45,510 +بدنا نقول لكم الاسم العام تبعه + +659 +00:59:48,060 --> 00:59:54,420 +الحلقة اللي فيها نيتروجين هي الأساس واضح إيش اسمها + +660 +00:59:54,420 --> 01:00:00,880 +هذه السداسية اللي فيها نيتروجين بيردازين + +661 +01:00:00,880 --> 01:00:07,900 +بيرمدين بيرازين بيردازين بيردازين وبناء على ذلك + +662 +01:00:07,900 --> 01:00:10,880 +الآن لاحظوا أن هنحيكون عندي + +663 +01:00:15,430 --> 01:00:25,770 +BCD 12345 إذا هذا هيكون ثيينو تو ثري دي بيريدازين + +664 +01:00:25,770 --> 01:00:30,390 +derivative ثيينو تو ثري دي بريدازين derivative + +665 +01:00:30,390 --> 01:00:35,570 +المهم في هذا الموضوع أن هذا التترازين أن هذا + +666 +01:00:35,570 --> 01:00:40,250 +التترازين كان عبارة عن الداين ال mask الداين وأن + +667 +01:00:40,250 --> 01:00:45,990 +الثيوفين هنا اشتغل as a diene file الثيوفين هنا + +668 +01:00:45,990 --> 01:00:48,470 +كان ديينه file + +669 +01:00:50,840 --> 01:00:55,060 +ولاحظوا على بال مين برضه لو طلب هذا التحذير بيجي على + +670 +01:00:55,060 --> 01:00:58,620 +البال أن هذه كانت حلقة سداسية فيها نيتروجين وأن + +671 +01:00:58,620 --> 01:01:09,260 +هذا عبر Diels Alder reaction الآن مرة ثانية + +672 +01:01:09,260 --> 01:01:10,600 +الثيوفين + +673 +01:01:15,460 --> 01:01:21,040 +مع هذا المركب Diazo compound الدايزو مع التسخين + +674 +01:01:21,040 --> 01:01:33,640 +شو بيعطينا؟ كاربين CO2 كاربين دايزو + +675 +01:01:33,640 --> 01:01:38,560 +بالتسخين بفقد ال nitrogen بيعطينا كاربين الآن + +676 +01:01:38,560 --> 01:01:43,840 +الكاربين إيش بيعمل؟ التي هي الـ Chelotropic + +677 +01:01:43,840 --> 01:01:49,640 +Cycloaddition على double bond وهو لديه double bond + +678 +01:01:49,640 --> 01:01:54,980 +وبناء على ذلك عمل لـ Chelotropic reaction عليها + +679 +01:01:54,980 --> 01:02:02,360 +واضح؟ هذا تفاعل كاربين يعمل Cycloaddition على double + +680 +01:02:02,360 --> 01:02:08,940 +bond إذا هنا الثيوفين الـ aromaticity عنده مقدسة + +681 +01:02:08,940 --> 01:02:14,300 +بزامه اتفاعل بأكثر من طريقة كداين وبأكثر من + +682 +01:02:14,300 --> 01:02:18,020 +طريقة اتفاعل ك double bond يعني ال double bond + +683 +01:02:18,020 --> 01:02:22,620 +نفسها اتفاعلت كإنها double bond يعني مش كإنها ضمن + +684 +01:02:22,620 --> 01:02:28,120 +منظومة إيش خلينا نقول الـ aromatic system مش كإنها + +685 +01:02:28,120 --> 01:02:33,240 +ضمن منظومة الـ aromatic system فمش مقدسة الـ + +686 +01:02:33,240 --> 01:02:38,600 +aromaticity عنده الآن هنا في عندنا مرة ثالثة أو + +687 +01:02:38,600 --> 01:02:48,820 +رابعة أو خامسة ثيوفين مع ال triple bond هيعمل + +688 +01:02:48,820 --> 01:02:53,000 +وهنا لو قلنا carbon carbon + +689 +01:02:55,650 --> 01:03:01,190 +2 plus 2 + +690 +01:03:01,190 --> 01:03:06,450 +Cycloaddition طبعًا الثيوفين في الأساس اللي مستعمله + +691 +01:03:06,450 --> 01:03:14,350 +تترا مثل ثيوفين عليه أربع مجموعات مثل مش مشكلة وهي + +692 +01:03:14,350 --> 01:03:21,680 +مع Acetylene derivative أو دايسيانو أسيتيلين فبيعمل + +693 +01:03:21,680 --> 01:03:25,140 +two plus two cycle addition إذا هنا اللي اتفاعل من + +694 +01:03:25,140 --> 01:03:29,060 +الثيوفين ال double bond اللي اتفاعل من هنا من + +695 +01:03:29,060 --> 01:03:31,940 +الثيوفين ال double bond واللي اتفاعل هنا ال + +696 +01:03:31,940 --> 01:03:34,740 +double bond مرات اتفاعل على ال double bond عمل + +697 +01:03:34,740 --> 01:03:38,680 +cycle addition Chelotropic reaction two plus two + +698 +01:03:38,680 --> 01:03:46,910 +حتى Diels Alder اتفعل كداينوفايل واتفعل كداين + +699 +01:03:46,910 --> 01:03:51,470 +فكل أمثلة ال cycle addition حقيقة موجودة على + +700 +01:03:52,830 --> 01:03:57,350 +الثيوفين كل أمثلة ال cycle addition موجودة على + +701 +01:03:57,350 --> 01:04:03,490 +الثيوفين بهيك بننتهي من إعطاء فكرة عامة عن هذه + +702 +01:04:03,490 --> 01:04:08,170 +الحلقات الخماسية وبننهي هذا المساق بأمل أن تكونوا + +703 +01:04:08,170 --> 01:04:14,930 +أخذتوا فكرة لا بأس بها عن الكيمياء الحلقية بأمل أن + +704 +01:04:14,930 --> 01:04:17,550 +تكونوا أخذتم فكرة لا بأس بها عن الكيمياء الحلقية diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bC4LHhVjass_raw.json b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bC4LHhVjass_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..a396f0d073a3277b1fc8392a6848fc027a07a2d0 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bC4LHhVjass_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4794, "start": 20.82, "end": 47.94, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله بتكون 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0.951171875}, {"start": 528.96, "end": 529.56, "word": " الأسباب", "probability": 0.9339192708333334}, {"start": 529.56, "end": 530.14, "word": " المتعلقة", "probability": 0.974365234375}, {"start": 530.14, "end": 530.32, "word": " بال", "probability": 0.5615234375}, {"start": 530.32, "end": 530.72, "word": " resonance", "probability": 0.89892578125}, {"start": 530.72, "end": 531.44, "word": " structures", "probability": 0.7705078125}, {"start": 531.44, "end": 532.5, "word": " لكن", "probability": 0.80712890625}, {"start": 532.5, "end": 534.12, "word": " الفيوران", "probability": 0.8050537109375}, {"start": 534.12, "end": 535.84, "word": " خلينا", "probability": 0.66448974609375}, {"start": 535.84, "end": 536.12, "word": " نقول", "probability": 0.992431640625}, {"start": 536.12, "end": 536.42, "word": " فيه", "probability": 0.922119140625}, {"start": 536.42, "end": 537.02, "word": " ميزة", "probability": 0.9893798828125}, {"start": 537.02, "end": 537.66, "word": " ان", "probability": 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0.96630859375}, {"start": 543.89, "end": 544.53, "word": " الحلقات", "probability": 0.9921875}, {"start": 544.53, "end": 545.25, "word": " طبعا", "probability": 0.8367919921875}, {"start": 545.25, "end": 545.67, "word": " أهم", "probability": 0.930419921875}, {"start": 545.67, "end": 546.29, "word": " شغلة", "probability": 0.8816731770833334}, {"start": 546.29, "end": 547.27, "word": " مرتبطة", "probability": 0.971484375}, {"start": 547.27, "end": 547.69, "word": " بفكرة", "probability": 0.9547119140625}, {"start": 547.69, "end": 547.91, "word": " ال", "probability": 0.947265625}, {"start": 547.91, "end": 548.95, "word": " aromaticity", "probability": 0.78515625}, {"start": 548.95, "end": 550.01, "word": " انه", "probability": 0.6407470703125}, {"start": 550.01, "end": 550.75, "word": " يعني", "probability": 0.912109375}, {"start": 550.75, "end": 550.91, "word": " لو", "probability": 0.97314453125}, {"start": 550.91, "end": 551.49, "word": " رجعنا", "probability": 0.9447021484375}, {"start": 551.49, "end": 552.33, "word": " كفكرة", "probability": 0.98681640625}, {"start": 552.33, "end": 553.27, "word": " للبنزين", "probability": 0.91875}, {"start": 553.27, "end": 553.61, "word": " لو", "probability": 0.70703125}, {"start": 553.61, "end": 553.99, "word": " رجعنا", "probability": 0.9947509765625}, {"start": 553.99, "end": 554.47, "word": " كفكرة", "probability": 0.9912109375}, {"start": 554.47, "end": 555.81, "word": " للبنزين", "probability": 0.980078125}, {"start": 555.81, "end": 556.79, "word": " انه", "probability": 0.746826171875}, {"start": 556.79, "end": 556.97, "word": " كنا", "probability": 0.922119140625}, {"start": 556.97, "end": 557.23, "word": " نقول", "probability": 0.9697265625}, {"start": 557.23, "end": 557.51, "word": " احنا", "probability": 0.8130696614583334}, {"start": 557.51, "end": 557.79, "word": " انه", "probability": 0.61767578125}, {"start": 557.79, "end": 558.43, "word": " البنزين", "probability": 0.9866943359375}, {"start": 558.43, 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double bond و نخليها single bond و نعمل addition على ال double bond هذا المميز الأساسي لل aromatic compounds أنه they don't react at the double bond they don't undergo addition reactions", "tokens": [2407, 46958, 5016, 3660, 22807, 37495, 22653, 5551, 16095, 13412, 17082, 37977, 8978, 2423, 45831, 507, 14739, 3224, 44945, 34268, 26890, 2423, 3834, 14713, 9122, 28814, 1863, 11296, 37893, 3714, 29245, 23328, 3660, 37495, 22653, 3714, 16758, 1863, 7435, 1829, 8592, 8717, 1211, 17082, 1829, 3714, 16758, 1863, 7435, 1829, 8592, 8717, 1211, 17082, 1829, 3834, 6086, 4032, 8717, 9778, 20292, 11296, 2167, 6086, 4032, 8717, 25957, 1211, 4500, 15844, 2423, 3834, 6086, 23758, 9673, 2304, 1829, 11622, 16247, 3794, 32277, 1829, 24976, 45831, 21810, 14739, 3224, 436, 500, 380, 4515, 412, 264, 3834, 6086, 436, 500, 380, 26426, 4500, 12215], "avg_logprob": -0.13579962738588744, "compression_ratio": 1.728813559322034, "no_speech_prob": 0.0, "words": [{"start": 566.52, "end": 567.36, "word": "واضحة؟", 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{"start": 578.42, "end": 578.76, "word": " bond", "probability": 0.96923828125}, {"start": 578.76, "end": 578.86, "word": " و", "probability": 0.98876953125}, {"start": 578.86, "end": 579.18, "word": " نعمل", "probability": 0.9845377604166666}, {"start": 579.18, "end": 579.68, "word": " addition", "probability": 0.97412109375}, {"start": 579.68, "end": 580.28, "word": " على", "probability": 0.845703125}, {"start": 580.28, "end": 580.42, "word": " ال", "probability": 0.8720703125}, {"start": 580.42, "end": 580.68, "word": " double", "probability": 0.955078125}, {"start": 580.68, "end": 581.1, "word": " bond", "probability": 0.95458984375}, {"start": 581.1, "end": 581.74, "word": " هذا", "probability": 0.92919921875}, {"start": 581.74, "end": 582.36, "word": " المميز", "probability": 0.9947509765625}, {"start": 582.36, "end": 583.1, "word": " الأساسي", "probability": 0.989990234375}, {"start": 583.1, "end": 583.24, "word": " لل", "probability": 0.91552734375}, {"start": 583.24, "end": 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"probability": 0.93212890625}, {"start": 590.32, "end": 591.26, "word": " addition", "probability": 0.9521484375}, {"start": 591.26, "end": 592.36, "word": " reactions", "probability": 0.826171875}], "temperature": 1.0}, {"id": 25, "seek": 62042, "start": 592.93, "end": 620.43, "text": "الان الفيوران من المركبات اللى ال aromaticity تبقيتها ضعيفة وبالتالي بيعمل addition reactions يعني بيعمل ال electrophilic aromatic substitution لكن بيعمل ال addition بمعنى اخر double bond منه بتصير عبارة عن ايش؟ بتصير عبارة عن single bond الان هذا الكلام هذا الكلام حقيقة معتمد على", "tokens": [6027, 7649, 27188, 1829, 13063, 7649, 9154, 9673, 31747, 3555, 9307, 13672, 7578, 2423, 45831, 507, 6055, 3555, 4587, 36081, 11296, 48812, 3615, 33911, 3660, 46599, 6027, 2655, 6027, 1829, 4724, 1829, 25957, 1211, 4500, 12215, 37495, 22653, 4724, 1829, 25957, 1211, 2423, 7072, 5317, 388, 299, 45831, 35827, 44381, 4724, 1829, 25957, 1211, 2423, 4500, 4724, 2304, 3615, 1863, 7578, 1975, 34740, 3834, 6086, 9154, 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تبقيتها", "probability": 0.77001953125}, {"start": 597.93, "end": 598.63, "word": " ضعيفة", "probability": 0.9693603515625}, {"start": 598.63, "end": 599.61, "word": " وبالتالي", "probability": 0.895703125}, {"start": 599.61, "end": 600.49, "word": " بيعمل", "probability": 0.9666748046875}, {"start": 600.49, "end": 600.93, "word": " addition", "probability": 0.8251953125}, {"start": 600.93, "end": 601.89, "word": " reactions", "probability": 0.7607421875}, {"start": 601.89, "end": 602.65, "word": " يعني", "probability": 0.90576171875}, {"start": 602.65, "end": 603.17, "word": " بيعمل", "probability": 0.9796142578125}, {"start": 603.17, "end": 603.39, "word": " ال", "probability": 0.9580078125}, {"start": 603.39, "end": 604.23, "word": " electrophilic", "probability": 0.79632568359375}, {"start": 604.23, "end": 604.61, "word": " aromatic", "probability": 0.87109375}, {"start": 604.61, "end": 605.31, "word": " substitution", "probability": 0.8701171875}, {"start": 605.31, "end": 605.99, "word": " لكن", "probability": 0.791015625}, {"start": 605.99, "end": 606.57, "word": " بيعمل", "probability": 0.9912109375}, {"start": 606.57, "end": 606.71, "word": " ال", "probability": 0.96728515625}, {"start": 606.71, "end": 607.11, "word": " addition", "probability": 0.943359375}, {"start": 607.11, "end": 608.31, "word": " بمعنى", "probability": 0.9888671875}, {"start": 608.31, "end": 608.89, "word": " اخر", "probability": 0.6898193359375}, {"start": 608.89, "end": 610.69, "word": " double", "probability": 0.71826171875}, {"start": 610.69, "end": 611.07, "word": " bond", "probability": 0.90283203125}, {"start": 611.07, "end": 611.43, "word": " منه", "probability": 0.979736328125}, {"start": 611.43, "end": 611.87, "word": " بتصير", "probability": 0.9217122395833334}, {"start": 611.87, "end": 612.33, "word": " عبارة", "probability": 0.9852294921875}, {"start": 612.33, "end": 612.53, "word": " عن", "probability": 0.9833984375}, {"start": 612.53, "end": 613.05, "word": " ايش؟", 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1157.26, "end": 1160.96, "text": "احنا أهم إشي أن هذه اللقطة الكبيرة كنا مخلصينها", "tokens": [39319, 8315, 5551, 16095, 11933, 8592, 1829, 14739, 29538, 13672, 47432, 3660, 33251, 3555, 48923, 9122, 8315, 3714, 9778, 1211, 9381, 9957, 11296], "avg_logprob": -0.2021484375, "compression_ratio": 1.1466666666666667, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 1157.26, "end": 1157.82, "word": "احنا", "probability": 0.713623046875}, {"start": 1157.82, "end": 1158.08, "word": " أهم", "probability": 0.8671875}, {"start": 1158.08, "end": 1158.36, "word": " إشي", "probability": 0.6173502604166666}, {"start": 1158.36, "end": 1158.46, "word": " أن", "probability": 0.44580078125}, {"start": 1158.46, "end": 1158.72, "word": " هذه", "probability": 0.52099609375}, {"start": 1158.72, "end": 1159.2, "word": " اللقطة", "probability": 0.9514973958333334}, {"start": 1159.2, "end": 1159.62, "word": " الكبيرة", "probability": 0.9874674479166666}, {"start": 1159.62, "end": 1159.9, "word": " 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"temperature": 1.0}, {"id": 99, "seek": 233217, "start": 2321.51, "end": 2332.17, "text": "C double bond S فال reagent اللي بيستعمل عادة لتحويل C double bond O لC double bond S هو before S10", "tokens": [34, 3834, 6086, 318, 6156, 6027, 26949, 317, 13672, 1829, 4724, 1829, 14851, 25957, 1211, 6225, 18513, 3660, 5296, 2655, 5016, 2407, 26895, 383, 3834, 6086, 422, 5296, 34, 3834, 6086, 318, 31439, 949, 318, 3279], "avg_logprob": -0.3842905534280313, "compression_ratio": 1.2115384615384615, "no_speech_prob": 0.0, "words": [{"start": 2321.51, "end": 2321.75, "word": "C", "probability": 0.3935546875}, {"start": 2321.75, "end": 2321.97, "word": " double", "probability": 0.08685302734375}, {"start": 2321.97, "end": 2322.23, "word": " bond", "probability": 0.89892578125}, {"start": 2322.23, "end": 2322.49, "word": " S", "probability": 0.76513671875}, {"start": 2322.49, "end": 2323.55, "word": " فال", "probability": 0.620361328125}, {"start": 2323.55, "end": 2324.31, "word": " reagent", 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إلى", "probability": 0.7763671875}, {"start": 2384.55, "end": 2385.77, "word": " C", "probability": 0.86279296875}, {"start": 2385.77, "end": 2386.01, "word": " double", "probability": 0.87109375}, {"start": 2386.01, "end": 2386.51, "word": " bond", "probability": 0.97607421875}, {"start": 2386.51, "end": 2387.33, "word": " S", "probability": 0.96875}, {"start": 2387.33, "end": 2391.53, "word": " الان", "probability": 0.5882568359375}, {"start": 2391.53, "end": 2392.59, "word": " ال", "probability": 0.90966796875}, {"start": 2392.59, "end": 2393.05, "word": " synthesis", "probability": 0.448486328125}, {"start": 2393.05, "end": 2393.85, "word": " التاني", "probability": 0.9319661458333334}], "temperature": 1.0}, {"id": 102, "seek": 240963, "start": 2394.85, "end": 2409.63, "text": "اللي هو الـ Hinsberg Synthesis of Thiophane في الـ Hinsberg Synthesis of Thiophane بناخد احنا 1,2-Diketo System يعني C double bond O متجاورات على موقع واحد واتنين", "tokens": [6027, 20292, 31439, 2423, 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نيوكليوفايل في النهاية الامين حل ما حل ايش ال PR minus في المحصلة", "tokens": [9566, 3555, 3615, 995, 8032, 1211, 3714, 43020, 7251, 39237, 43242, 2423, 39184, 14962, 5317, 388, 299, 35827, 36632, 11242, 995, 10874, 25513, 14407, 16472, 16095, 7251, 5172, 30241, 14407, 23758, 9673, 31747, 3555, 20449, 8717, 1829, 2407, 28820, 1829, 38688, 995, 26895, 1975, 2304, 9957, 10874, 16758, 14407, 1975, 2304, 9957, 4032, 2423, 10943, 9957, 8032, 2304, 8717, 1829, 2407, 28820, 1829, 38688, 995, 26895, 8978, 28239, 11296, 10632, 2423, 10943, 9957, 11331, 1211, 19446, 11331, 1211, 1975, 1829, 8592, 2423, 11568, 3175, 8978, 9673, 5016, 36520, 3660], "avg_logprob": -0.295138892200258, "compression_ratio": 1.6546391752577319, "no_speech_prob": 0.0, "words": [{"start": 3204.24, "end": 3204.78, "word": "طبعا", "probability": 0.8604736328125}, {"start": 3204.78, "end": 3205.78, "word": " هل", "probability": 0.81640625}, {"start": 3205.78, "end": 3206.3, "word": " ممكن", "probability": 0.9541015625}, 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هنا ساعد على إتمام الـ Nucleophilic Substitution يمكن أنتم مروا معاكم حتى على البنزين الـ Nucleophilic Substitution كان ممكن وين؟", "tokens": [3615, 26890, 3714, 1829, 41361, 1829, 11622, 2304, 2423, 39184, 426, 1311, 306, 5317, 388, 299, 42090, 6518, 30767, 1829, 13672, 1829, 11331, 4117, 1829, 8315, 11296, 5551, 12610, 19446, 1975, 2655, 4117, 19528, 8315, 18871, 2423, 39184, 761, 480, 897, 455, 533, 5480, 4032, 17082, 13546, 3224, 44945, 36178, 9673, 1863, 9566, 4587, 4724, 28814, 2304, 41361, 3224, 5296, 39184, 426, 1311, 306, 49242, 7251, 3224, 26108, 2304, 11296, 6055, 2655, 5016, 31747, 29739, 1863, 6055, 2655, 5016, 31747, 20193, 5016, 19913, 14407, 2423, 39184, 37942, 340, 13672, 1829, 34105, 8608, 995, 22488, 15844, 11933, 39237, 10943, 2423, 39184, 426, 1311, 306, 5317, 388, 299, 42090, 6518, 7251, 43020, 14739, 39237, 3714, 2288, 14407, 20449, 995, 24793, 11331, 49975, 15844, 29739, 1863, 11622, 9957, 2423, 39184, 426, 1311, 306, 5317, 388, 299, 42090, 6518, 25961, 3714, 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0.52655029296875}, {"start": 3248.99, "end": 3249.73, "word": " Nucleophilic", "probability": 0.93798828125}, {"start": 3249.73, "end": 3250.27, "word": " Substitution", "probability": 0.951416015625}, {"start": 3250.27, "end": 3250.61, "word": " يمكن", "probability": 0.7734375}, {"start": 3250.61, "end": 3250.89, "word": " أنتم", "probability": 0.626220703125}, {"start": 3250.89, "end": 3251.21, "word": " مروا", "probability": 0.705078125}, {"start": 3251.21, "end": 3251.69, "word": " معاكم", "probability": 0.9646809895833334}, {"start": 3251.69, "end": 3252.45, "word": " حتى", "probability": 0.9111328125}, {"start": 3252.45, "end": 3252.69, "word": " على", "probability": 0.83642578125}, {"start": 3252.69, "end": 3253.57, "word": " البنزين", "probability": 0.9698486328125}, {"start": 3253.57, "end": 3254.21, "word": " الـ", "probability": 0.73095703125}, {"start": 3254.21, "end": 3254.89, "word": " Nucleophilic", "probability": 0.943115234375}, {"start": 3254.89, "end": 3255.87, "word": " Substitution", "probability": 0.981689453125}, {"start": 3255.87, "end": 3256.65, "word": " كان", "probability": 0.9716796875}, {"start": 3256.65, "end": 3257.05, "word": " ممكن", "probability": 0.987060546875}, {"start": 3257.05, "end": 3257.73, "word": " وين؟", "probability": 0.85009765625}], "temperature": 1.0}, {"id": 140, "seek": 328784, "start": 3259.88, "end": 3287.84, "text": "أه يعني في البنزين المثال المشهور المثال المشهور اللى بتنفي ال nucleophilic substitution لما يكون عندى Cl و تلاتة نيترو الآن هذه النيترو بتسحب الإلكترونات وبناء على ذلك طالما في كتير مجموعات بتسحب الإلكترونات بإمكان ال nucleophile ييجى يهاجم زى مثلا ال OH minus", "tokens": [10721, 3224, 37495, 22653, 8978, 29739, 1863, 11622, 9957, 9673, 12984, 6027, 9673, 8592, 3224, 13063, 9673, 12984, 6027, 9673, 8592, 3224, 13063, 13672, 7578, 39894, 1863, 41185, 2423, 14962, 5317, 388, 299, 35827, 5296, 15042, 7251, 30544, 43242, 7578, 2033, 4032, 6055, 1211, 9307, 3660, 8717, 36081, 32887, 6024, 48506, 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{"start": 3268.62, "end": 3270.14, "word": " و", "probability": 0.6357421875}, {"start": 3270.14, "end": 3270.88, "word": " تلاتة", "probability": 0.78363037109375}, {"start": 3270.88, "end": 3271.56, "word": " نيترو", "probability": 0.8361002604166666}, {"start": 3271.56, "end": 3272.78, "word": " الآن", "probability": 0.6207275390625}, {"start": 3272.78, "end": 3273.62, "word": " هذه", "probability": 0.5263671875}, {"start": 3273.62, "end": 3274.06, "word": " النيترو", "probability": 0.769287109375}, {"start": 3274.06, "end": 3274.7, "word": " بتسحب", "probability": 0.9561767578125}, {"start": 3274.7, "end": 3275.76, "word": " الإلكترونات", "probability": 0.8740234375}, {"start": 3275.76, "end": 3276.52, "word": " وبناء", "probability": 0.8544921875}, {"start": 3276.52, "end": 3276.84, "word": " على", "probability": 0.85693359375}, {"start": 3276.84, "end": 3277.26, "word": " ذلك", "probability": 0.995849609375}, {"start": 3277.26, "end": 3277.58, "word": " طالما", "probability": 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مثلا", "probability": 0.955810546875}, {"start": 3286.54, "end": 3286.8, "word": " ال", "probability": 0.935546875}, {"start": 3286.8, "end": 3287.02, "word": " OH", "probability": 0.41357421875}, {"start": 3287.02, "end": 3287.84, "word": " minus", "probability": 0.2783203125}], "temperature": 1.0}, {"id": 141, "seek": 331100, "start": 3289.16, "end": 3311.0, "text": "ناخد الـ Nucleophile in this case الـ OH minus بإمكانه يهاجم هنا وجد هال minus مراح ينحمل عهاد ال O مرة هان مرة هان يعني في مجموعات مساعدة لكن لو فعلنا لchlorobenzene لحاله مع ال OH minus بتمشي ابدال بس ل Trinitrochlorobenzene", "tokens": [1863, 47283, 3215, 2423, 39184, 13612, 2160, 49242, 294, 341, 1389, 2423, 39184, 13931, 3175, 4724, 28814, 2304, 41361, 3224, 7251, 3224, 26108, 2304, 34105, 49610, 3215, 8032, 6027, 3175, 3714, 23557, 5016, 7251, 1863, 35571, 1211, 6225, 11296, 3215, 2423, 422, 3714, 25720, 8032, 7649, 3714, 25720, 8032, 7649, 37495, 22653, 8978, 3714, 7435, 2304, 45367, 9307, 47524, 995, 22488, 3660, 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فلاحظوا أنا كيف تدخل ال nitro group في المساعدة على إتمام إيش ال nucleophilic substitution يعني هذا بيهاجم هان بتتحرك هذي بتتحرك هذي صفية السالب في الآخر وين صفة محمول؟", "tokens": [2304, 3615, 2423, 20265, 15435, 34454, 7251, 43020, 13412, 2407, 10632, 6055, 3794, 9778, 9957, 25961, 4724, 39237, 33688, 44510, 16606, 6156, 15040, 5016, 19913, 14407, 41850, 9122, 33911, 6055, 3215, 9778, 1211, 2423, 10900, 340, 1594, 8978, 9673, 3794, 995, 22488, 3660, 15844, 11933, 39237, 10943, 11933, 1829, 8592, 2423, 14962, 5317, 388, 299, 35827, 37495, 22653, 23758, 4724, 1829, 3224, 26108, 2304, 8032, 7649, 39894, 2655, 5016, 31747, 8032, 8848, 1829, 39894, 2655, 5016, 31747, 8032, 8848, 1829, 20328, 5172, 10632, 21136, 6027, 3555, 8978, 6024, 95, 34740, 4032, 9957, 20328, 5172, 3660, 3714, 35571, 12610, 22807], "avg_logprob": -0.24515625223517418, "compression_ratio": 1.5169491525423728, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 3311.87, "end": 3312.19, "word": "مع", 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" كيف", "probability": 0.972412109375}, {"start": 3316.53, "end": 3317.49, "word": " تدخل", "probability": 0.9815673828125}, {"start": 3317.49, "end": 3317.65, "word": " ال", "probability": 0.95166015625}, {"start": 3317.65, "end": 3318.29, "word": " nitro", "probability": 0.5533447265625}, {"start": 3318.29, "end": 3318.87, "word": " group", "probability": 0.92578125}, {"start": 3318.87, "end": 3319.43, "word": " في", "probability": 0.92529296875}, {"start": 3319.43, "end": 3320.39, "word": " المساعدة", "probability": 0.97890625}, {"start": 3320.39, "end": 3320.55, "word": " على", "probability": 0.83642578125}, {"start": 3320.55, "end": 3321.09, "word": " إتمام", "probability": 0.9090169270833334}, {"start": 3321.09, "end": 3321.53, "word": " إيش", "probability": 0.7210286458333334}, {"start": 3321.53, "end": 3322.25, "word": " ال", "probability": 0.29833984375}, {"start": 3322.25, "end": 3323.11, "word": " nucleophilic", "probability": 0.8616943359375}, {"start": 3323.11, "end": 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التسخين", "probability": 0.9024658203125}, {"start": 3681.04, "end": 3681.24, "word": " شو", "probability": 0.8056640625}, {"start": 3681.24, "end": 3683.94, "word": " بيعطينا؟", "probability": 0.8218994140625}, {"start": 3683.94, "end": 3685.36, "word": " كاربين", "probability": 0.717315673828125}, {"start": 3685.36, "end": 3688.24, "word": " CO2", "probability": 0.6453857421875}, {"start": 3688.24, "end": 3690.24, "word": " كاربين", "probability": 0.73052978515625}, {"start": 3690.24, "end": 3693.64, "word": " دايازو", "probability": 0.9189453125}, {"start": 3693.64, "end": 3694.76, "word": " بالتسخين", "probability": 0.93427734375}, {"start": 3694.76, "end": 3695.32, "word": " بفقد", "probability": 0.8917643229166666}, {"start": 3695.32, "end": 3695.48, "word": " ال", "probability": 0.82666015625}, {"start": 3695.48, "end": 3696.06, "word": " nitrogen", "probability": 0.26708984375}, {"start": 3696.06, "end": 3697.14, "word": " بيعطينا", "probability": 0.9556640625}, {"start": 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0000000000000000000000000000000000000000..80c76bd86ee6c73cd77a4f8478b023c685bd5aa3 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bC4LHhVjass_raw.srt @@ -0,0 +1,2828 @@ +1 +00:00:20,820 --> 00:00:25,420 +بسم الله الرحمن الرحيم اليوم ان شاء الله بتكون + +2 +00:00:25,420 --> 00:00:30,700 +المحاضرة الأخيرة لنا في هذا المساق بعد ما اتكلمنا + +3 +00:00:30,700 --> 00:00:34,020 +عن تسمية ال heterocycle compounds و الطرق العامة + +4 +00:00:34,020 --> 00:00:39,600 +للتحضير و أخدنا أمثلة منتقال بعض الحلقات تحضيرها و + +5 +00:00:39,600 --> 00:00:44,280 +تفاعلاتها أخدنا حلقات سداسية و بعدين من الحلقات + +6 +00:00:44,280 --> 00:00:51,410 +الخمسية درسنا ال by roleطبعا لو أجينا سألنا سؤال + +7 +00:00:51,410 --> 00:00:55,270 +تقليدي من الحلقات الخماسية التانية المشهورة جدا + +8 +00:00:55,270 --> 00:01:01,790 +غير ال by role هي حقيقة الفيوران والثيوفين ولذلك + +9 +00:01:01,790 --> 00:01:06,050 +الآن ان شاء الله هناخد فكرة ايضا مختصرة عن + +10 +00:01:06,050 --> 00:01:08,750 +الفيوران والثيوفين + +11 +00:01:10,860 --> 00:01:15,940 +طبعا كل المراكبات الحلقية الحقيقة يعني موجودة في + +12 +00:01:15,940 --> 00:01:21,260 +التطبيق و موجودة في أكثر من استعمال و دائما بنحب + +13 +00:01:21,260 --> 00:01:26,240 +نبدأ أن نعرض بعض هذه المراكبات اللي موجودة في + +14 +00:01:26,240 --> 00:01:31,300 +التطبيق يعني مثلا من المراكبات الحلقية اللي موجودة + +15 +00:01:31,300 --> 00:01:36,620 +في الطبيعة هذا المراكب واضح أنه مشتقة فيوران بسموه + +16 +00:01:36,620 --> 00:01:43,430 +rose fiorana يبدو مراكب عطريهذا المُركّباللي هو + +17 +00:01:43,430 --> 00:01:47,970 +Vitamin C أو الـ Ascorbic Acid هو عبارة أيضًا عن + +18 +00:01:47,970 --> 00:01:57,890 +Furan Furan derivative ال Furan كمركب يعني قليل + +19 +00:01:57,890 --> 00:02:01,470 +أنه الإنسان ينطلق منه في التحضير في المختبر يعني + +20 +00:02:01,470 --> 00:02:05,390 +عادة المركب اللي موجود في المختبر و بنعمل منه + +21 +00:02:05,390 --> 00:02:08,630 +derivatives لما بنشتغل على ال Furan هو ال Furan + +22 +00:02:08,630 --> 00:02:12,250 +aldehyde اللي فيه ال aldehyde على موقع اتنين Furan + +23 +00:02:12,920 --> 00:02:18,160 +two-carboxyldehyde وماخد اسم شهرة forforal من + +24 +00:02:18,160 --> 00:02:23,440 +مركبات الفيوران المهم جدا الدواء السحري هذا ال + +25 +00:02:23,440 --> 00:02:28,440 +راندين اللى يستعمل لعلاج قرحة المعدة بيسموها + +26 +00:02:28,440 --> 00:02:32,520 +peptic ulcer طبعا استعمل سابقا الان الفهم اللى + +27 +00:02:32,520 --> 00:02:36,760 +موجود عن قرحة المعدة انه هي عبارة عن bacterial + +28 +00:02:36,760 --> 00:02:41,360 +infections هي يعني عدوى بكتيرية او هي مرض بكتيري + +29 +00:02:42,000 --> 00:02:47,640 +وبالتالي بيعلجوها بالمضادات الحيوية مع مشتقات + +30 +00:02:47,640 --> 00:02:53,100 +أيضًا حلقات خمسية اللي هو ال Hemoprasol مع مضادات + +31 +00:02:53,100 --> 00:03:00,160 +Claramycin و Amoxetid يعني بيسموه العلاج ال triple + +32 +00:03:00,160 --> 00:03:04,260 +therapy اللي الآن موجود طبعًا هذا يرجع فيه للأطباء + +33 +00:03:04,260 --> 00:03:11,300 +لكن هو خليط من المضادات الحيويةو ال emiprazole لكن + +34 +00:03:11,300 --> 00:03:16,400 +لسنوات طويلة استعمل الرندين و لحتى الآن في ناس + +35 +00:03:16,400 --> 00:03:20,720 +بيستعملوله ألام المعدة و ما إلى ذلك لاحظوا أنه + +36 +00:03:20,720 --> 00:03:26,360 +الرندين بشكل أساسي أيضا هو عبارة عن furan + +37 +00:03:26,360 --> 00:03:31,350 +derivative هذا الدواءالان لو اجينا على ال + +38 +00:03:31,350 --> 00:03:35,310 +synthesis of فيوران ال synthesis of فيوران في + +39 +00:03:35,310 --> 00:03:40,530 +عندنا synthesis متكرر ربما اللي هو ال one four + +40 +00:03:40,530 --> 00:03:45,030 +-dicarbonyl compounds و احنا اتكلمنا انه ال one + +41 +00:03:45,030 --> 00:03:49,370 +four-dicarbonyl compounds ممكن نحضر منهم ال birol + +42 +00:03:49,370 --> 00:03:52,630 +ممكن نحضر منهم ال فيوران ممكن نحضر منهم الثيوفين + +43 +00:03:53,340 --> 00:03:58,400 +لما بدنا نحضر الفيوران بدنا هذا المركب نفسه انفعله + +44 +00:03:58,400 --> 00:04:02,120 +مع acid اللي هو ال بالكنور فيوران synthesis ف + +45 +00:04:02,120 --> 00:04:05,940 +oxygen منهم بتشغل كإنها ال eucleophile بتهاجم على + +46 +00:04:05,940 --> 00:04:09,460 +ال oxygen التانية و بيستكمل ال elimination و + +47 +00:04:09,460 --> 00:04:15,040 +التفاعل لما كنا نحضر كبيرول كنا نضيف أمونيا بحيث + +48 +00:04:15,040 --> 00:04:21,140 +أن هذا ال eucleophile يصيرهن اتش 2 و لما بدنا بعد + +49 +00:04:21,140 --> 00:04:25,460 +شوية نشوف كيف يستعمل ال 1,4-dicarbonyl compound + +50 +00:04:25,460 --> 00:04:30,280 +لتحضير الثيوفين بدنا نحول واحدة من ال oxygen ل + +51 +00:04:30,280 --> 00:04:34,420 +sulfur وبالتالي بيصير ال sulfur يهاجم as in + +52 +00:04:34,420 --> 00:04:39,060 +nucleophile و يطلع انه ثيوفين فهذا ال synthesis + +53 +00:04:39,060 --> 00:04:46,230 +الأول ل الفيورام ال synthesis التانيهو الفايست + +54 +00:04:46,230 --> 00:04:50,730 +بيناري في Uran Synthesis اللي أخدنا فيه ال Alpha + +55 +00:04:50,730 --> 00:04:56,250 +Halo Keto مع ال Beta Keto E Star لاحظوا معنى أنه + +56 +00:04:56,250 --> 00:05:01,410 +برضه لما احنا أخدناالـ Pyrrole Synthesis كنا ناخد + +57 +00:05:01,410 --> 00:05:06,330 +هدولة التنين لكن نضيف عليهم كمان ايش ال ammonia او + +58 +00:05:06,330 --> 00:05:12,970 +ال amine الان لو أخدناهم لوحدهم طبعا مر علينا كيف + +59 +00:05:12,970 --> 00:05:18,370 +هذا التفاعل بتم في وجود base الان هذه ال CH2 هي + +60 +00:05:18,370 --> 00:05:24,800 +عبارة عن activatedمثلين group ويمكن ان انا تفقد + +61 +00:05:24,800 --> 00:05:29,500 +بروتون يصير عندي carbon ion ال carbon ion اكيد بده + +62 +00:05:29,500 --> 00:05:36,490 +يهاجم هنا ويعملالـ OH- بعد ما هذا يتكون يمكن انه + +63 +00:05:36,490 --> 00:05:39,810 +يفقد البروتون التاني يعني احنا بنكون متذاكرين انه + +64 +00:05:39,810 --> 00:05:44,990 +في هنا كام بروتون اساسا CH2 ففقد البروتون الاول + +65 +00:05:44,990 --> 00:05:50,550 +عمل هذا الارتباط لو فقد البروتون التاني بيصير عندى + +66 +00:05:50,550 --> 00:05:54,970 +minus الان لو عملنا التوتمريزم هذا ال minus اما + +67 +00:05:54,970 --> 00:05:59,390 +بيكون على ال carbon هنا او بيجعل oxygen وتنتقل ال + +68 +00:05:59,390 --> 00:06:05,450 +double bondواضح هذا مش توتوميريزم عفوا resonance + +69 +00:06:05,450 --> 00:06:10,190 +عشان ما يعني يكون الكلام دقيق لما نشوف هذا ال + +70 +00:06:10,190 --> 00:06:14,970 +resonance structure هذا inolate anion inol inol + +71 +00:06:14,970 --> 00:06:20,710 +inolate anion الآن طالما صار عندي O minus هتهاجم + +72 +00:06:20,710 --> 00:06:24,210 +على ال + +73 +00:06:24,210 --> 00:06:29,790 +CH2Cl و تطرد ال CL وبالتالي يتكون عندى furan + +74 +00:06:30,670 --> 00:06:35,390 +derivative هذا مر علينا اللي هو الفاist بين + +75 +00:06:35,390 --> 00:06:39,070 +reference synthesis أول ما درسنا ال substitution + +76 +00:06:39,070 --> 00:06:44,750 +reaction كطريقة لإغلاق الحلقة واضح؟ والناس اللي + +77 +00:06:44,750 --> 00:06:51,430 +متذكرة ربما ال Baldwin rules + +78 +00:06:51,430 --> 00:06:56,690 +إيش هذا هتسميه exo ولا endocyclization هذا عبارة + +79 +00:06:56,690 --> 00:07:03,180 +عن exocyclization علىتترايجونال و لا تتراجونال و + +80 +00:07:03,180 --> 00:07:07,460 +لا دياجونال كاربون تتراجونال اه اذا هذا اكزو + +81 +00:07:07,460 --> 00:07:13,920 +تتراجونال cyclization اكزو تتراجونال cyclization + +82 +00:07:13,920 --> 00:07:18,140 +هذا الفيس بين ال referent synthesis قلنا عنه بدنا + +83 +00:07:18,140 --> 00:07:24,360 +ننتبه ان هو متداخل معاشرمع ال by role synthesis + +84 +00:07:24,360 --> 00:07:28,920 +يعني نفس هدولة ال two reagents لو صار في عنده ال + +85 +00:07:28,920 --> 00:07:33,100 +ammonia لو صار في عنده ال ammonia اللي هيصير انه + +86 +00:07:33,100 --> 00:07:36,260 +هذي ال seed of المنطقة هو هتصير nitrogen وبالتالي + +87 +00:07:36,260 --> 00:07:41,440 +اللي هيسكر هنا nitrogen طالما أنهم التلاتة موجودين + +88 +00:07:41,440 --> 00:07:47,740 +هيطلع عندى كمان if urine ك by product لما نكون + +89 +00:07:47,740 --> 00:07:56,120 +نحضر ال by roleالان بالنسبة لتفاعلات الفيوران طبعا + +90 +00:07:56,120 --> 00:08:00,440 +اخدنا احنا المرة الماضية لما درسنا ال + +91 +00:08:00,440 --> 00:08:04,760 +electrophilic substitution اللي هو التفاعل الأساسي + +92 +00:08:04,760 --> 00:08:10,680 +لل aromatic compounds انهال by role هو ال unshot + +93 +00:08:10,680 --> 00:08:15,580 +في ال electrophilic substitution أكثر من الفيوران + +94 +00:08:15,580 --> 00:08:19,880 +أكثر من الثيوفين و كلهم في نهاية أكثر من البنزين + +95 +00:08:19,880 --> 00:08:23,700 +السبب أن كلهم أكثر من البنزين هو وجود ال + +96 +00:08:23,700 --> 00:08:27,360 +electronegative atom فأنا لما بدو ييجي عندي + +97 +00:08:27,360 --> 00:08:32,460 +electrophile من الخارج كل ما كانت الحلقة محتوى + +98 +00:08:32,460 --> 00:08:37,900 +الإلكتروني أكثر كل ما كانت التفاعل ايش أكثر واضح؟ + +99 +00:08:39,400 --> 00:08:45,380 +بشكل عام ال reaction مثله مثل ال by role بتم على + +100 +00:08:45,380 --> 00:08:50,720 +موقع اتنين لنفس الأسباب المتعلقة بال resonance + +101 +00:08:50,720 --> 00:08:58,020 +structures لكن الفيوران خلينا نقول فيه ميزة ان هو + +102 +00:08:58,020 --> 00:09:03,890 +من ناحيةالـ aromaticity أقل من البيرول وأقل من هذه + +103 +00:09:03,890 --> 00:09:08,950 +الحلقات طبعا أهم شغلة مرتبطة بفكرة ال aromaticity + +104 +00:09:08,950 --> 00:09:14,470 +انه يعني لو رجعنا كفكرة للبنزين لو رجعنا كفكرة + +105 +00:09:14,470 --> 00:09:19,170 +للبنزين انه كنا نقول احنا انه البنزين في double + +106 +00:09:19,170 --> 00:09:24,750 +bonds لكن مابعملش addition على ال double bond + +107 +00:09:26,520 --> 00:09:31,740 +واضحة؟ يعني أهم شغلة في ال aromaticity أنه بنعتبر + +108 +00:09:31,740 --> 00:09:35,360 +ال double bonds كإنها مش موجودة يعني مابنجيش نلغي + +109 +00:09:35,360 --> 00:09:38,860 +مابنجيش نلغي double bond و نخليها single bond و + +110 +00:09:38,860 --> 00:09:42,360 +نعمل addition على ال double bond هذا المميز + +111 +00:09:42,360 --> 00:09:46,780 +الأساسي لل aromatic compounds أنه they don't react + +112 +00:09:46,780 --> 00:09:51,260 +at the double bond they don't undergo addition + +113 +00:09:51,260 --> 00:09:56,650 +reactionsالان الفيوران من المركبات اللى ال + +114 +00:09:56,650 --> 00:10:00,930 +aromaticity تبقيتها ضعيفة وبالتالي بيعمل addition + +115 +00:10:00,930 --> 00:10:04,610 +reactions يعني بيعمل ال electrophilic aromatic + +116 +00:10:04,610 --> 00:10:08,890 +substitution لكن بيعمل ال addition بمعنى اخر + +117 +00:10:08,890 --> 00:10:14,030 +double bond منه بتصير عبارة عن ايش؟ بتصير عبارة عن + +118 +00:10:14,030 --> 00:10:20,090 +single bond الان هذا الكلام هذا الكلام حقيقة معتمد + +119 +00:10:20,090 --> 00:10:26,080 +علىنوع التفاعل يعني على ظروف التفاعل يعني لو عملنا + +120 +00:10:26,080 --> 00:10:35,300 +البروميناشن في أبروتك سولفان زي ال DMF مش بولر + +121 +00:10:35,300 --> 00:10:39,220 +بروتك سولفان هلاحظ أنه بتم التفاعل عادي جدا + +122 +00:10:39,220 --> 00:10:42,200 +Substitution Electrophilic Aromatic Substitution + +123 +00:10:42,200 --> 00:10:50,040 +على الموقع 2لو البروميناشن نفسه اعملناه في وجود + +124 +00:10:50,040 --> 00:10:55,100 +بروتيك بولار سولفنت زي الميثانول زي الميثانول الان + +125 +00:10:55,100 --> 00:11:01,810 +الميثانول ميزته هو كسولفنت انههو solvent و هو + +126 +00:11:01,810 --> 00:11:07,630 +nucleophile هو solvent و هو nucleophile فلو احنا + +127 +00:11:07,630 --> 00:11:14,990 +جربنا ان نمشي بالتدريج كيف بتتم عملية ال + +128 +00:11:14,990 --> 00:11:18,690 +electrophilic substitution خلينا نقول ان المنطلق + +129 +00:11:18,690 --> 00:11:24,190 +تبعنا كان من زوج الالكترونات اللي موجود هنا و جاي + +130 +00:11:24,190 --> 00:11:28,770 +عندنا PR موجب الآن ال PR الموجب بده ال الكترونات + +131 +00:11:28,770 --> 00:11:33,410 +من وين؟من الحلقة هاي عندي ست إلكترونات هو بده + +132 +00:11:33,410 --> 00:11:38,270 +إلكترونات فلو تخيلنا هذا الشكل تخيلنا زي هيك هنا + +133 +00:11:38,270 --> 00:11:43,770 +أكيد كان في H هذه الرابط هتيجي تشبك بإيش بالبروميل + +134 +00:11:44,700 --> 00:11:49,220 +هذه الرابطة هتشبك في البرومين عادة الـ + +135 +00:11:49,220 --> 00:11:53,680 +Electrophilic Substitution الطبيعي لما كان بيكتمل + +136 +00:11:53,680 --> 00:11:58,060 +انه زي ما اتي عندى Electrophile موجب يعني لو انا + +137 +00:11:58,060 --> 00:12:01,800 +بدي Electrophilic Substitution عادي انه زي ما اتي + +138 +00:12:01,800 --> 00:12:08,920 +عندى Electrophile موجب نفقت الـH الموجبة ونرجع هذه + +139 +00:12:08,920 --> 00:12:13,420 +ونرجع هذه ونرجع زوج الالكتروناتهذا الوضع اللي + +140 +00:12:13,420 --> 00:12:16,180 +موجود بهذا الشكل هذا الـ Electrophilic Aromatic + +141 +00:12:16,180 --> 00:12:20,600 +Substitution واضح؟ انه ييجي عنده الـ Eucleophile + +142 +00:12:20,600 --> 00:12:26,340 +بأرموجة انه يفقد عنده بعد هيك الـ Eucleophile H + +143 +00:12:26,340 --> 00:12:30,460 +Plus واضح؟ هذا إيش بيكون بهذا الشكل اللي مرسوم + +144 +00:12:30,460 --> 00:12:35,480 +الآن Electrophilic Aromatic Substitution و بيصير + +145 +00:12:35,480 --> 00:12:40,000 +مثل هذا الجزء يعني لو هذا الكلام تم هيصير عندى زي + +146 +00:12:40,000 --> 00:12:45,830 +الجزء اللي موجود عندنا هناالان في وجود الميثانول + +147 +00:12:45,830 --> 00:12:49,130 +يعني هذا الكلام نفسه لو انا بدي افسر هذا ال + +148 +00:12:49,130 --> 00:12:54,910 +ميكانيزم بدي اقول واحد اتنين تلاتة واضح؟ في وجود + +149 +00:12:54,910 --> 00:12:57,950 +الميثانول يعني لو قولنا كيف هذا البروميناتش اللي + +150 +00:12:57,950 --> 00:13:02,470 +بدي يصير بيقول هايقعنا الفيوران مع ال PR plus بهذا + +151 +00:13:02,470 --> 00:13:09,220 +الشكل تفقد ال H plusفصرنا التفاعل لفوق لكن في وجود + +152 +00:13:09,220 --> 00:13:16,920 +الميثانول بيصير عند أنا مصار بيصير عند مصار جديد + +153 +00:13:16,920 --> 00:13:23,140 +او مصار تاني للتفاعل لما بيواجد عندنا الميثانول + +154 +00:13:23,140 --> 00:13:28,560 +بيصير في عندنا مصار تاني للتفاعل خلينا نتخيل هذا + +155 +00:13:29,760 --> 00:13:34,360 +المسار التاني اللى موجود عندنا للتفاعل طبعا هنا في + +156 +00:13:34,360 --> 00:13:41,060 +عندنا ايش H بلس والميثانول is النيوكليوفايل بناء + +157 +00:13:41,060 --> 00:13:48,360 +على ذلك هذا الميثانول بيجي يهاجم هنا وهذه ترجع على + +158 +00:13:48,360 --> 00:13:55,200 +ال oxygen واضح في هذه الحالة لما انا اضفت في + +159 +00:13:55,200 --> 00:14:01,600 +الخطوة الأولى PR plusوفي الخطوة التانية in + +160 +00:14:01,600 --> 00:14:05,360 +eucleophile يعني في النهاية plus minus هذا استكمال + +161 +00:14:05,360 --> 00:14:10,560 +لفكرة ال addition طبعا أكيد ال methanol هيفقد ال H + +162 +00:14:10,560 --> 00:14:17,220 +هذا أمر طبيعي الآن لاحظوا هنا ال H هذه ما زالت + +163 +00:14:17,220 --> 00:14:25,140 +موجودة و ال H هذه ما زالت موجودة في هذه الحالة في + +164 +00:14:25,140 --> 00:14:30,040 +هذه الحالة صار عند additional reactionفده الحالة + +165 +00:14:30,040 --> 00:14:34,580 +صار عندى addition reaction ليش؟ لأنه أنا بديت في + +166 +00:14:34,580 --> 00:14:38,780 +two double bonds وهنا كام double bond عندى؟ واحدة + +167 +00:14:38,780 --> 00:14:45,100 +ففي عندى addition reaction في وجود الميثانو، واضح؟ + +168 +00:14:45,700 --> 00:14:49,400 +بهذه الحالة صار في عندى addition reaction في وجود + +169 +00:14:49,400 --> 00:14:54,500 +الميثانول طبعا ممكن بعد هيك ممكن بعد هيك كمان + +170 +00:14:54,500 --> 00:15:00,140 +تستبدل ال PR هذه بخطوة لاحقة انا بالنسبة ليه ال + +171 +00:15:00,140 --> 00:15:04,780 +addition في هذه الحالة استكمل يعني اقدرت اشوف انه + +172 +00:15:04,780 --> 00:15:10,360 +تم عندى تفاعل ال addition الان بعد هيك كيف ممكن + +173 +00:15:10,360 --> 00:15:16,360 +نتخيل انه تم استبدال ال PR اللى موجودة هنابمجموعة + +174 +00:15:16,360 --> 00:15:21,500 +ايش او مثل تانية يعني صار عندى كام مثل group صار + +175 +00:15:21,500 --> 00:15:27,700 +عندى two مثل groups صار عندى two مثل groups من + +176 +00:15:27,700 --> 00:15:34,440 +خلال مرة تانية اذا احنا بدنا نطلع على هذا المركب + +177 +00:15:34,440 --> 00:15:38,780 +اللى موجود هنا لو تخيلنا انه زوج الالكترونات اللى + +178 +00:15:38,780 --> 00:15:47,120 +هانهذا زوج الإلكترونات تحرك بهذا الشكل وجدتها + +179 +00:15:47,120 --> 00:15:52,580 +معقول يصير عندى خمس روابط هنا إذا هتطلع البروم على + +180 +00:15:52,580 --> 00:15:59,700 +شكل PR- يعني لما اتتم هذه الحركة هو زوج + +181 +00:15:59,700 --> 00:16:04,740 +الإلكترونات في هذه الحالة بيطرد البروم على شكل PR- + +182 +00:16:04,740 --> 00:16:11,820 +الآن إذا إجا الميثانول الآن اتفاعل معاهورجع زوجي + +183 +00:16:11,820 --> 00:16:17,480 +الإلكترونات بهذا الشكل رجعنا للمركب الأصلي طبعا لو + +184 +00:16:17,480 --> 00:16:24,400 +إجينا سألنا إيش نوع الإبدال هذا الأخير طلع عندى PR + +185 +00:16:24,400 --> 00:16:32,400 +minus إجى عندى methanol طلع ال nucleophileأي جاء + +186 +00:16:32,400 --> 00:16:37,300 +الـ Nucleophile إذا هنا الإبدال الـ Nucleophilic + +187 +00:16:37,300 --> 00:16:40,060 +Substitution أنا عارف أنه Substitution لكن السؤال + +188 +00:16:40,060 --> 00:16:44,600 +أي Substitution ما هو ال Substitution نوعين في + +189 +00:16:44,600 --> 00:16:48,140 +Nucleophilic Substitution و في Electrophilic + +190 +00:16:48,140 --> 00:16:52,680 +Substitution أنا لما شيلت PR minus و حطيت يعني ال + +191 +00:16:52,680 --> 00:16:58,180 +hydrogen مازالوا موجودات ال hydrogenمازالوا + +192 +00:16:58,180 --> 00:17:02,620 +موجودات انا كل اللي عملته كمحصلة لما اشوف هذا + +193 +00:17:02,620 --> 00:17:05,840 +التفاعل هان و اشوف هذه النتيجة هان شو اللي عملته + +194 +00:17:05,840 --> 00:17:15,060 +شيلت PR minus حطيت O مثل اذا هذا اليوكليوفيليك + +195 +00:17:15,060 --> 00:17:19,500 +substitution طبعا اللي احنا بدنا نستنتجه من هذه ال + +196 +00:17:19,500 --> 00:17:26,140 +slide بالمجمل انه الفيورانصح بيعمل Electrophilic + +197 +00:17:26,140 --> 00:17:30,880 +Aromatic Substitution إذا كان عنده Abrotic Solvent + +198 +00:17:30,880 --> 00:17:34,780 +لكن لو كان في عنده Protic Solvent هذا ال Protic + +199 +00:17:34,780 --> 00:17:40,370 +Solvent له Enucleophilic Power ممكن يعملAddition + +200 +00:17:40,370 --> 00:17:45,650 +في خطوته الأولى و ممكن يكمل يعمل الـ Eucleophilic + +201 +00:17:45,650 --> 00:17:49,410 +Substitution يعني اللى تم هنا هي عملية Addition + +202 +00:17:49,410 --> 00:17:52,290 +يعني هذا التفاعل اللى بدنا نوصفه بيقول أن هذا + +203 +00:17:52,290 --> 00:17:56,370 +Addition كان عندى two double bonds صاروا one + +204 +00:17:56,370 --> 00:18:03,870 +double bond زيادة في محتوىال sigma bonds ونقص في + +205 +00:18:03,870 --> 00:18:08,290 +محتوى ال by bonds هذا عبارة عن إيش addition الآن + +206 +00:18:08,290 --> 00:18:12,070 +بعد ال addition تمت شغل جديدة اللي هي عملية ال إيش + +207 +00:18:12,070 --> 00:18:18,030 +ال nucleophilic substitution واضح؟ كل هذا الكلام + +208 +00:18:18,030 --> 00:18:28,470 +بيعمله الفيوران سجل كهرارة تعمل المشاكل الله + +209 +00:18:28,470 --> 00:18:29,210 +يعطيك الله عافية + +210 +00:18:33,230 --> 00:18:35,030 +بس يوم برد شوية ما بتاعي + +211 +00:19:17,260 --> 00:19:20,960 +احنا أهم إشي أن هذه اللقطة الكبيرة كنا مخلصينها + +212 +00:19:33,130 --> 00:19:34,010 +ماذا تحب؟ + +213 +00:19:52,960 --> 00:19:59,660 +إذا الخلاصة اللي احنا أوصلنا لها هنا انه الفيوران + +214 +00:19:59,660 --> 00:20:05,000 +خلافا لل aromatic compounds اللي هي أساسا تفعيل + +215 +00:20:05,000 --> 00:20:08,680 +الأساس ال electrophilic aromatic substitution ممكن + +216 +00:20:08,680 --> 00:20:13,340 +يعملaddition reactions ممكن يعمل addition + +217 +00:20:13,340 --> 00:20:19,260 +reactions الان كتأكيد لهذا المعنى لو تابعنا ال + +218 +00:20:19,260 --> 00:20:24,600 +nitrogen of a furan لاحظوا معنى عملوا ال nitrogen + +219 +00:20:24,600 --> 00:20:30,740 +مرتين مرة في وجود ال nucleophile قوي اللي هو ال + +220 +00:20:30,740 --> 00:20:35,100 +acetate anion و مرة في وجود ال nucleophile ضعيف + +221 +00:20:35,100 --> 00:20:41,170 +يعني هذا ال nucleophilestrong هذا لنكليوفايل weak + +222 +00:20:41,170 --> 00:20:46,830 +الان لنكليوفايل القوى اتدخل في التفاعل ومشي + +223 +00:20:46,830 --> 00:20:51,530 +التفاعل على مسار ال ايش ال addition تنتين double + +224 +00:20:51,530 --> 00:20:56,010 +bond صاروا واحدة double bond معناه ذلك تمت عملية + +225 +00:20:56,010 --> 00:20:58,930 +addition و لو ال addition هنا بيبين one four + +226 +00:20:58,930 --> 00:21:01,450 +addition مش مشكلة في النهاية انا لغير double bond + +227 +00:21:01,450 --> 00:21:04,690 +يعني يمكن الطلاب متعودين انهم يشوفوا ال addition + +228 +00:21:05,640 --> 00:21:09,000 +one two addition في النهاية one two addition او + +229 +00:21:09,000 --> 00:21:12,320 +one four addition finally addition و ليش احنا + +230 +00:21:12,320 --> 00:21:16,700 +أساسا بنسمي ال addition و بنميزه برقم بنقول انه في + +231 +00:21:16,700 --> 00:21:21,440 +one two addition لأنه برضه في الدنيا في one four + +232 +00:21:21,440 --> 00:21:24,660 +addition هذا اكيد addition و لغيت فيه double month + +233 +00:21:24,660 --> 00:21:28,760 +لاحظوا لما استعملنا ال nitration في وجود weakened + +234 +00:21:28,760 --> 00:21:34,830 +eucleophile تمبسNitration عادي Electrophilic + +235 +00:21:34,830 --> 00:21:40,630 +Aromatic Substitution ما تمش فيه عنده اللي هو ال + +236 +00:21:40,630 --> 00:21:47,130 +addition reaction الآن بعد هيك انه هذا المركب اللي + +237 +00:21:47,130 --> 00:21:51,370 +هنا عملوله أكسد أو فقد ال acetic acid في البريدين + +238 +00:21:51,370 --> 00:21:57,090 +هذا أمر بتهيأليه واضح وسهل يعني مش عملية صعبة انه + +239 +00:21:57,090 --> 00:22:06,480 +بديفقد ACO مع Hواضح؟ بالإمكان أن ننفذها بسهولة + +240 +00:22:06,480 --> 00:22:14,290 +ويرجع يصير في عندنا إيش؟ اللي هو مركّبالسبستيوشن + +241 +00:22:14,290 --> 00:22:18,930 +مركب السبستيوشن العادي لكن بالتأكيد هذا المركب مر + +242 +00:22:18,930 --> 00:22:24,850 +عبر ال addition reaction و تم فصل و تم فصل هذا + +243 +00:22:24,850 --> 00:22:27,950 +المركب اللي هو مركب ال addition reaction يعني لو + +244 +00:22:27,950 --> 00:22:31,730 +انتوا اتخيلتوا ان هنا في عندكم hydrogen اتخيلتوا + +245 +00:22:31,730 --> 00:22:39,910 +ان هنافي عندكم هيدروجين بهذا الشكل إذا فقدت هذه + +246 +00:22:39,910 --> 00:22:42,730 +الهيدروجين هذه ال bond هتتحرك بهذا الشكل هذه + +247 +00:22:42,730 --> 00:22:51,270 +هتتحرك بهذا الشكل هذه الان هي ال ACO minus و هذه + +248 +00:22:51,270 --> 00:23:00,670 +ال H ACO minus مع ال H اللي هي ACO + +249 +00:23:05,320 --> 00:23:10,960 +الفكرة انه اعتمادا على نيوكليوفيليك باور of the + +250 +00:23:10,960 --> 00:23:14,940 +solvent او نيوكليوفايل يعني في المثال السابق كان + +251 +00:23:14,940 --> 00:23:19,100 +الميثانول ال solvent او هنا حطينا احنا نيوكليوفايل + +252 +00:23:19,100 --> 00:23:23,970 +من عندنا ممكن انه على الفيوران تم عمليةالـ + +253 +00:23:23,970 --> 00:23:28,210 +addition فيه خروج عن المقلوف لإيش؟ للـ aromatic + +254 +00:23:28,210 --> 00:23:31,170 +compounds لأن الـ aromatic compounds المقلوف لها + +255 +00:23:31,170 --> 00:23:35,850 +الـelectrophilic aromatic substitution الآن + +256 +00:23:35,850 --> 00:23:42,210 +بالنسبة للـcycloaddition reactions الحقيقة أنه إذا + +257 +00:23:42,210 --> 00:23:46,890 +بتعملوا مقارنة مع البيرول البيرول تقريبا كان من + +258 +00:23:46,890 --> 00:23:51,290 +أضعفالحلقات الثلاث لإنه يعمل cycle addition + +259 +00:23:51,290 --> 00:23:55,830 +reactions أو يتفعل كضيين الأول ما احنا اتكلمنا عن + +260 +00:23:55,830 --> 00:23:59,730 +الفيوران وقلنا ان ال aromaticity فيه اضعيفة + +261 +00:23:59,730 --> 00:24:05,210 +وبالتالي عمل addition فبنقدر نتخيل ان هذا الفيوران + +262 +00:24:05,210 --> 00:24:10,710 +أيضابشكل أكبر ممكن يتعامل كأنه ضايين، يعني مش كتير + +263 +00:24:10,710 --> 00:24:15,310 +مفرج مع هدول ال .. ال by bonds أنهم يكونوا رابطين + +264 +00:24:15,310 --> 00:24:19,070 +حالهم مع هذه و أنهم عاملين وحدة واحدة اللي هي + +265 +00:24:19,070 --> 00:24:24,450 +اسمها إيش ال aromatic cloudواضح؟ فبالتالي الفيوران + +266 +00:24:24,450 --> 00:24:30,370 +بشكل كبير بيشتغل كضايين، يعني الأمثلة على ال cycle + +267 +00:24:30,370 --> 00:24:34,630 +addition reactions of فيوران أو تحديدا deals elder + +268 +00:24:34,630 --> 00:24:37,610 +cycle addition reactions of فيوران، أزئ ضايين + +269 +00:24:37,610 --> 00:24:42,290 +موجودة كتير، وعشان هيك بنقدر نعطيكوا homework احنا + +270 +00:24:42,290 --> 00:24:48,500 +انه جيبولناأمثلة على ديالز ألدر cycle addition of + +271 +00:24:48,500 --> 00:24:53,080 +فيوران موجود كثير الفيوران هنا بيتعامل كأنه ضايين + +272 +00:24:53,080 --> 00:24:57,620 +لو افترضنا هنا مع المليك انهيدريد بنقدر نعمل + +273 +00:24:57,620 --> 00:25:03,420 +نستكمل cycle addition ونكون الحلقة السوداسية ولا + +274 +00:25:03,420 --> 00:25:09,960 +لأ؟ ايه؟ واحد اتنين تلاتة اربعة خمسة ستة وضب ال + +275 +00:25:09,960 --> 00:25:15,390 +bond واحدة مجرد انه ال oxygen رسمها لوين؟على شكل + +276 +00:25:15,390 --> 00:25:20,550 +bridge هذا عبارة عن deals elder cycle addition وهي + +277 +00:25:20,550 --> 00:25:24,550 +الحلقة السوداسية اللى اتكونت من ال cycle addition + +278 +00:25:24,550 --> 00:25:28,850 +مع الماليك unhydrated + +279 +00:25:30,310 --> 00:25:33,850 +كذلك الحال في الـ Cycloaddition مع الـ + +280 +00:25:33,850 --> 00:25:37,950 +Acrylonitrile بتعرفوا هذا المركب يمكن مار عليكم + +281 +00:25:37,950 --> 00:25:41,570 +اسمه Acrylonitrile و لو كان هنا C double bond OH + +282 +00:25:41,570 --> 00:25:46,870 +بيكون Acrylaldehyde و لو كان C double bond O O H + +283 +00:25:46,870 --> 00:25:51,650 +Acrylic Acid اه في Acrylic Acid Acrylonitrile + +284 +00:25:51,650 --> 00:25:57,670 +Acrylaldehyde الان معلف يوران مرة ثانية مرة ثانية + +285 +00:25:57,670 --> 00:26:02,160 +التفاعل اللي بده يتمهو deals elder reaction يعني + +286 +00:26:02,160 --> 00:26:07,400 +الفيوران بده يمثل اتضايين و هذا ال double bond هي + +287 +00:26:07,400 --> 00:26:12,340 +عبارة عن اتضايين و file الآن جيد الكلام اللي موجود + +288 +00:26:12,340 --> 00:26:15,720 +هنا بفرجيكم كيف انه + +289 +00:26:18,230 --> 00:26:22,450 +تغيير شروط التفاعل تغيير شروط التفاعل يعني لما + +290 +00:26:22,450 --> 00:26:30,750 +الطالب في المستقبل بده يشتغل بشغلة معينة يكون عنده + +291 +00:26:30,750 --> 00:26:35,490 +يعني القابلية لإنه ياخد و يعطي مع التفاعل يغير + +292 +00:26:35,490 --> 00:26:39,350 +الشروط لحد ما يصل للي بيسموها ال optimum + +293 +00:26:39,350 --> 00:26:43,370 +conditions عشان هيك لما مرات انتوا بتشوفوا مثلا + +294 +00:26:43,370 --> 00:26:47,840 +واحد بيجي بيعمل رسالة ماجستيرهتلاقوه عمل بس تفاعل + +295 +00:26:47,840 --> 00:26:52,940 +واحد اول ما بيخطر على بالكم انه تفاعل واحد عادة + +296 +00:26:52,940 --> 00:26:57,920 +احنا في حصة مختبر واحدة تلت ساعات بنعمل التفاعل و + +297 +00:26:57,920 --> 00:27:02,680 +بنطلع النتيجة بتتفاجأوا ان هذا البني ادم اشتغل خمس + +298 +00:27:02,680 --> 00:27:07,080 +ست شهورلحد ما عمل هذا التفاعل طب شو كان بيعمل + +299 +00:27:07,080 --> 00:27:12,400 +بالخمس ست شهور بيغير ال conditions لحد ما يصل لل + +300 +00:27:12,400 --> 00:27:17,460 +optimum conditions ايش افضل شروط ايش افضل شروط انا + +301 +00:27:17,460 --> 00:27:23,480 +ممكن اعمل عليها التفاعل بافضل مردود ومش دائما + +302 +00:27:23,480 --> 00:27:30,460 +بالمناسبة مش دائما مردود القوةهو الحل الأفضل لكل + +303 +00:27:30,460 --> 00:27:36,140 +التفاعلات يعني مرات كتيرة لما تتعاملوا حتى مع + +304 +00:27:36,140 --> 00:27:40,140 +البني أدمين حتى مع الأطفال الصغار ممكن لو ضربتوا + +305 +00:27:40,140 --> 00:27:45,900 +الطفل الصغير يصير عنده ردة فعل سلبية وعناد سلبي + +306 +00:27:45,900 --> 00:27:51,840 +وممكن بكلمة حلوة أو بحبة شوكولاتة بسيطة تاخدوا منه + +307 +00:27:51,840 --> 00:27:58,260 +أضعاف ما ممكن تاخدوا منه بالإشبالعنف أو بالضرب، + +308 +00:27:58,260 --> 00:28:02,520 +وعشان هيك يعني هذا التفاعل على سبيل المثال، لاحظوا + +309 +00:28:02,520 --> 00:28:06,940 +كيف عملوه بطرق مختلفة، تركوه على ال room + +310 +00:28:06,940 --> 00:28:12,700 +temperature يتحرك خمس أسابيع، في النهاية حصلوا على + +311 +00:28:12,700 --> 00:28:19,790 +yield 39%أجوا استعملوا ضغط عالي very very very + +312 +00:28:19,790 --> 00:28:23,750 +high atmospheric pressure very very high pressure + +313 +00:28:23,750 --> 00:28:28,410 +على أربع ساعات أعطاني خمسة و خمسين في المية + +314 +00:28:28,410 --> 00:28:34,110 +استعملوا Lewis acid zinc iodide لمدة تمانية و + +315 +00:28:34,110 --> 00:28:39,790 +أربعين ساعة حصلوا على إيش؟على 100% فهنا هذه ال + +316 +00:28:39,790 --> 00:28:44,690 +conditions اللي بيغيرها الإنسان هي جزء من عمل + +317 +00:28:44,690 --> 00:28:49,090 +التفاعلات يعني مش بس الإنسان بيعمل التفاعل أول مرة + +318 +00:28:49,090 --> 00:28:53,270 +و خلاص لأ و الله طب أنتوا عملتوا التفاعل لسه توي + +319 +00:28:53,270 --> 00:28:58,830 +كنا بنحكي في abrotic solventطب يا تورا لو عملناها + +320 +00:28:58,830 --> 00:29:02,990 +في protein solvent لاحظته قبل شوية كيف التفاعل هنا + +321 +00:29:02,990 --> 00:29:07,010 +اتغير ما بين ال protein solvent و ما بين ال + +322 +00:29:07,010 --> 00:29:11,770 +protein solvent ما بين الحرارة الضغط الاستعمال + +323 +00:29:11,770 --> 00:29:18,280 +catalyst هنا استعملوا Lewis acidفي النهاية حصلوا + +324 +00:29:18,280 --> 00:29:25,140 +على 100% yield خلال 48 ساعة، كل أحوال هذه شروط + +325 +00:29:25,140 --> 00:29:31,300 +تعتبر سهلة وممتازة، فهذا هو وظيفة الإنسان اللي + +326 +00:29:31,300 --> 00:29:37,810 +بيشتغلفي المختبر انما شخص خلط مادتين ومن اول مرة + +327 +00:29:37,810 --> 00:29:40,590 +ضمن الظروف اللى استعملها ماطلعش نتيجة لأ والله + +328 +00:29:40,590 --> 00:29:44,990 +التفاعل بيمشيش طب يمكن التفاعل متأثر بالرطوبة يمكن + +329 +00:29:44,990 --> 00:29:49,870 +ال solvent اللى حاط وانت مش مناسب يمكن التفاعل بده + +330 +00:29:49,870 --> 00:29:54,950 +تسخين يمكن التفاعل بده dry conditions يمكن التفاعل + +331 +00:29:54,950 --> 00:30:00,770 +بده يكون under inert gas كل هذه الأشياء بتكون جزء + +332 +00:30:00,770 --> 00:30:06,850 +من الاشجزء من العمل المخبري اللي الإنسان بده يطور + +333 +00:30:06,850 --> 00:30:10,670 +روحه عليه لو اشتغل في ال heterocyclic chemistry + +334 +00:30:10,670 --> 00:30:16,590 +ولذلك كل مقال أنتوا بتقرأوه هتلاحظوه معادلة لكن + +335 +00:30:16,590 --> 00:30:20,850 +غالبا كل مقال هو نتاج رسالة ماجستير أو جزء من + +336 +00:30:20,850 --> 00:30:24,910 +رسالة دكتوراه أخدت أشهر إذا ما أخدتش سنين هو البني + +337 +00:30:24,910 --> 00:30:32,000 +آدم إيش يعمل اظبط ال conditionsتفاعلات + +338 +00:30:32,000 --> 00:30:37,840 +Cycloaddition إضافية مثلا هذا التفاعل مع ال triple + +339 +00:30:37,840 --> 00:30:43,000 +bond اللي هو dimethylacetylene dicarboxylate مع + +340 +00:30:43,000 --> 00:30:47,900 +الفيوران الفيوران مرة ثانية بده يتفاعل كأنه دايين + +341 +00:30:47,900 --> 00:30:54,280 +طبعا إذا كان التفاعلمع ال triple bond كم double + +342 +00:30:54,280 --> 00:30:58,020 +bond هنشوف في deals under reaction تنتين هذا لو + +343 +00:30:58,020 --> 00:31:01,740 +فعلناه مع ال H plus هتفتح الحلقة يصير عندي OH + +344 +00:31:01,740 --> 00:31:07,580 +ويجيني كمان double bond كمان double bond صار عندي + +345 +00:31:07,580 --> 00:31:12,580 +مشتقة بنزين طبعا على بال مين بيختر لو جولة حضره + +346 +00:31:12,580 --> 00:31:16,300 +هذا المركب اللي هو بنزين derivative انه هذا المركب + +347 +00:31:16,300 --> 00:31:17,300 +كان منطلقه + +348 +00:31:23,910 --> 00:31:29,970 +النفس المركب بدل ما يفعلوه مع H plus عملوله + +349 +00:31:29,970 --> 00:31:34,630 +hydrogenation الان هنا ال hydrogenation لسبب معين + +350 +00:31:34,630 --> 00:31:38,390 +صار selective hydrogenation ايش يعني selective + +351 +00:31:38,390 --> 00:31:42,660 +hydrogenation؟يعني انه في عنده تنتين double bonds + +352 +00:31:42,660 --> 00:31:48,420 +يعني كان ممكن ال hydrogenation تم هان او هان فكما + +353 +00:31:48,420 --> 00:31:50,960 +يبدو ال hydrogenation راح على ال double bond اللي + +354 +00:31:51,970 --> 00:31:57,790 +يعني مافيش حواليها crowding ربما تمام فأعطانا هذا + +355 +00:31:57,790 --> 00:32:03,530 +المراكب وهذا المراكب بيعمل اللي بنسميه احنا retro + +356 +00:32:03,530 --> 00:32:07,650 +deals alder يمكن مرت عليكم هذه الجملة لأن في deals + +357 +00:32:07,650 --> 00:32:14,010 +alder وفي retro ربما بال fragmentation بال mass + +358 +00:32:14,010 --> 00:32:20,610 +spectrometry أيضا مثل هذه الجملة بتمر طبعا لما بده + +359 +00:32:20,610 --> 00:32:24,120 +يعملالـ Retrodeal Alder Reaction كأننا بدنا نقول + +360 +00:32:24,120 --> 00:32:27,400 +أن هذا بدأ تتحرك بالشكل و هذا بدأ تتحرك بالشكل و + +361 +00:32:27,400 --> 00:32:35,180 +هذا بدأ تتحرك بالشكل ف CH2 CH2 هتفقد على شكل الكين + +362 +00:32:36,080 --> 00:32:41,300 +CH2 CH2 هات اتحركت صار الكينيل والإيثالين وانا + +363 +00:32:41,300 --> 00:32:47,400 +حصلنا على a new furan derivative فلو أجينا و سألنا + +364 +00:32:47,400 --> 00:32:54,180 +والله مبتدئين من الفيوران هذا unsubstituted furan + +365 +00:32:54,180 --> 00:32:58,880 +حصلنا على one two three four three four + +366 +00:33:03,280 --> 00:33:10,360 +فى اوران كيف تم هذا عبر هذه السلسلة deals elder + +367 +00:33:10,360 --> 00:33:18,380 +hydrogenation retro retro deals elder retro cycle + +368 +00:33:18,380 --> 00:33:22,360 +addition واضح + +369 +00:33:22,360 --> 00:33:31,050 +هذه الفكرة وطبعا كيف حضرنا مشتقق بنزين ايضامن + +370 +00:33:31,050 --> 00:33:35,770 +الفيوران طبعا في كل الأحوال يعني مثل هذه الأشياء + +371 +00:33:35,770 --> 00:33:43,370 +هي حقيقة يعني من عجاب الكيميا اللي قبل ما الناس + +372 +00:33:43,370 --> 00:33:46,610 +يفهموا الكيميا كانت الكيميا بالنسبة لهم قمر ايش + +373 +00:33:46,610 --> 00:33:50,550 +غريب ان انت تبدأ فيوران تطلع فيوران تاني تبدأ + +374 +00:33:50,550 --> 00:33:55,460 +فيوران تطلعبنزين لكن لاحظوا اللي بيحلل الأمور + +375 +00:33:55,460 --> 00:34:00,620 +بهدوء بيقدر يستوعب كيف بتتم التفاعلات الكيميائية + +376 +00:34:00,620 --> 00:34:05,380 +وهذا في النهاية مثل هذه الخلاصة هي اللي انتوا لازم + +377 +00:34:05,380 --> 00:34:11,720 +تصلولها في المستوى الرابع تقريبا هذه فكرة خلينا + +378 +00:34:11,720 --> 00:34:17,280 +نقول عن الفيوران وتفاعلاته يمكن من أهم الشغلات + +379 +00:34:17,280 --> 00:34:22,430 +اللي لاحظتوها ان الفيوران بيعمل additionو بيعمل + +380 +00:34:22,430 --> 00:34:30,590 +cycle addition و بيعمل deals elder cycle addition + +381 +00:34:30,590 --> 00:34:37,610 +as a دايين يعني كدايين الفيران بيشتغل + +382 +00:34:37,610 --> 00:34:39,290 +كدايين + +383 +00:34:47,390 --> 00:34:51,590 +اذا انتقلنا للحلقة الأخيرة اللى ان شاء الله + +384 +00:34:51,590 --> 00:34:57,430 +بندرسها في هذا المساق اللى هو الـ Theophany طبعا + +385 +00:34:58,200 --> 00:35:05,000 +دائما بنقول إيش ال importance لالثيوفين يمكن + +386 +00:35:05,000 --> 00:35:08,400 +جايبين مراكبين من المراكبات اللي بتحتوي على + +387 +00:35:08,400 --> 00:35:12,660 +الثيوفين في هذا ال slide هذا المراكب اسمه Byron + +388 +00:35:12,660 --> 00:35:17,920 +Tal هذا ال Byron Tal مكتوب عليه is a broad + +389 +00:35:17,920 --> 00:35:22,980 +spectrum anthelmic agent effective against mainly + +390 +00:35:22,980 --> 00:35:30,400 +pinworm and hookwormطبعا المفروض تكونوا عارفين إيش + +391 +00:35:30,400 --> 00:35:35,720 +معنى broad spectrumلما تمر معاكم Broad Spectrum + +392 +00:35:35,720 --> 00:35:41,960 +بتمر .. بAntibiotic مثلا بتلاقيوا بيستعملوا Broad + +393 +00:35:41,960 --> 00:35:47,000 +Spectrum الآن اللي بيقصدوا في هذه الحالة أنها تقضي + +394 +00:35:47,000 --> 00:35:51,180 +على أنواع كثيرة مختلفة من البكتيريا بشكل أساس لو + +395 +00:35:51,180 --> 00:35:53,860 +قالوا Broad Spectrum Antibacterial Agent يعني + +396 +00:35:53,860 --> 00:35:58,640 +بيقضي على بكتيريا موجبة لجرام و سالبة لجرام جرام + +397 +00:35:58,640 --> 00:36:02,600 +positive و جرام negative بكتيرياالان هذا المركب + +398 +00:36:02,600 --> 00:36:06,480 +broad spectrum anthelmintic agent يعني قاتل + +399 +00:36:06,480 --> 00:36:13,380 +لاديدان و خصوصا اللي بيسموها ال بال ورم، ماعرفش + +400 +00:36:13,380 --> 00:36:20,410 +إذا مرت عليكم ال بال ورم هادي ولا لألكن عادة طالما + +401 +00:36:20,410 --> 00:36:25,590 +ان انتوا يعني أمهات جيد انكوا تكونوا عارفين ال بن + +402 +00:36:25,590 --> 00:36:31,230 +ورم جيدا هذه دودة صغيرة بيضة تقريبا بتكون الطول + +403 +00:36:31,230 --> 00:36:37,600 +تبعها واحد سانتمترو بتكون موجودة كثير عند الأطفال + +404 +00:36:37,600 --> 00:36:42,140 +و بتنتقل عدوى ما بين الأطفال بعض و من بعض بالذات + +405 +00:36:42,140 --> 00:36:47,620 +الأطفال الصغار و عادة الأمهات بيشوفوا هذه الدودة + +406 +00:36:47,620 --> 00:36:51,380 +.. هذه الدودة لما بيغيروا للأطفال يعني مع ال .. مع + +407 +00:36:51,380 --> 00:36:54,920 +البرازع، الفتحة، الشرجة المشكلة هذه لما بتطلع و + +408 +00:36:54,920 --> 00:37:00,700 +بتحط البيض بتؤلم الطفل كثير و بالتالي بتعمل حساسية + +409 +00:37:01,370 --> 00:37:06,290 +بتعمل حساسية كتير لازم ياخدوا علاج و لازم كل + +410 +00:37:06,290 --> 00:37:09,890 +الملابس بتاعة الطفل و غيرها و غيراتها كمان تنغسل + +411 +00:37:09,890 --> 00:37:16,830 +بميه سخنه و يكون في حذر من العدوى بين الأطفال شايف + +412 +00:37:16,830 --> 00:37:24,290 +في تعليق زي اللي مش عاجبك الكلام أو عندك ايوة + +413 +00:37:24,290 --> 00:37:30,710 +اه اه اللي هي ال pen wormو ال hookworm و ما إلى + +414 +00:37:30,710 --> 00:37:37,990 +ذلك المركب التاني اللي هو اللي بنسميه بيوتين او + +415 +00:37:37,990 --> 00:37:42,490 +vitamin H هذا اللي موجود في الخميرة و في البيض و + +416 +00:37:42,490 --> 00:37:46,810 +يمكن لهذا السبب الخميرة و البيض مع الزمن بتاعة + +417 +00:37:46,810 --> 00:37:52,050 +الرائحةالسيئة ليش لأنها بتحتوى في النهاية على ال + +418 +00:37:52,050 --> 00:37:56,250 +sulfur الكبريت وال sulfur هيعطي ال H2S و ال SO2 و + +419 +00:37:56,250 --> 00:38:03,870 +ما إلى ذلك مركبات كبريتية الآن بالنسبة لل ring + +420 +00:38:03,870 --> 00:38:10,310 +synthesis في عندنا ال synthesis الشهير اللي هو من + +421 +00:38:10,310 --> 00:38:14,790 +ال 1,4-dicarbonyl compounds اللي قولنا بنحضر منها + +422 +00:38:15,910 --> 00:38:20,710 +فيورانو ثيوفين و بايرول اللي هو لما نحضر الثيوفين + +423 +00:38:20,710 --> 00:38:26,670 +لازم نحول واحدة من سيضا بالبوند او إلى سالفر هذا + +424 +00:38:26,670 --> 00:38:32,210 +الكلام ممكن تم بال before أستن إذا تم هذا التحويل + +425 +00:38:32,210 --> 00:38:36,650 +بعد هيك عملية ال addition عملية يعني مافيش فيها + +426 +00:38:36,650 --> 00:38:40,170 +مشكلة لكن أهم إشي أنه أنا بدي أحول سيضا بالبوند او + +427 +00:38:40,170 --> 00:38:45,570 +إلىC double bond S فال reagent اللي بيستعمل عادة + +428 +00:38:45,570 --> 00:38:50,710 +لتحويل C double bond O لC double bond S هو before + +429 +00:38:50,710 --> 00:38:52,170 +S10 + +430 +00:38:56,060 --> 00:39:04,380 +DK Sulphide واضح؟ الان في عندنا Reagent او H2S مع + +431 +00:39:04,380 --> 00:39:10,280 +HCl برضه بيمشي في عندنا Reagent مشهور كتير بتشوفوه + +432 +00:39:10,280 --> 00:39:14,900 +اللي هو Lewisin's Reagent هذا برضه Reagent بيحول + +433 +00:39:14,900 --> 00:39:20,520 +الـ C double bond O إلى C double bond S Lewisin's + +434 +00:39:20,520 --> 00:39:27,670 +Reagent بينشروا متوفر كتيرفي عندنا مثلًا هذا مثلًا + +435 +00:39:27,670 --> 00:39:33,490 +هذا تترازولون بـ C double bond O مع الـ Lewisin's + +436 +00:39:33,490 --> 00:39:42,070 +reagent تترازول ثيون تترازول ثيون هيتحول لـ C + +437 +00:39:42,070 --> 00:39:51,530 +double bond S التحول إلى C double bond S الان + +438 +00:39:51,530 --> 00:39:57,150 +ال synthesis التانياللي هو الـ Hinsberg Synthesis + +439 +00:39:57,150 --> 00:40:00,510 +of Thiophane في الـ Hinsberg Synthesis of + +440 +00:40:00,510 --> 00:40:05,890 +Thiophane بناخد احنا 1,2-Diketo System يعني C + +441 +00:40:05,890 --> 00:40:10,670 +double bond O متجاورات على موقع واحد واتنين1,2 + +442 +00:40:10,670 --> 00:40:15,350 +-Diketo system و بناخد مركب زي هذا الآن واضح انه + +443 +00:40:15,350 --> 00:40:20,150 +المركب اللي زي هذا مخدينه احنا فيه activated مثلين + +444 +00:40:20,150 --> 00:40:25,110 +groups CH2 CH2 كان ممكن انتوا تتخيلوا كان ممكن + +445 +00:40:25,110 --> 00:40:25,910 +تتخيلوا + +446 +00:40:30,520 --> 00:40:37,720 +ROR ان هذا التفاعل ببساطة لما يعمل حلقة في وجود + +447 +00:40:37,720 --> 00:40:42,140 +base Sodium ethoxide مستعمل ان هنا سيصبح لدي + +448 +00:40:42,140 --> 00:40:46,500 +double bond وهنا سيصبح لدي double bond sulfur + +449 +00:40:46,500 --> 00:40:50,060 +single bond double bond carbon carbon double bond + +450 +00:40:50,060 --> 00:40:56,180 +هيثيوفيل واضح يعني يصبح هنا ايون سالب يهاجم علىالـ + +451 +00:40:56,180 --> 00:41:00,740 +C double bond O وهنا Ion سالب هاجم على الـ C + +452 +00:41:00,740 --> 00:41:04,060 +double bond O وفي الحالتين O H مع H O H مع H + +453 +00:41:04,060 --> 00:41:08,340 +Double bonds لكن الحقيقة بتلاحظوا انتوا انه + +454 +00:41:08,340 --> 00:41:15,980 +بالتفصيل عمل شويةأشياء إضافية ليش كل .. ليش عمل كل + +455 +00:41:15,980 --> 00:41:20,200 +هذا الكلام؟ لو التفاعل تم بالطريقة اللي احنا + +456 +00:41:20,200 --> 00:41:24,700 +حكيناها ببساطة وهذه صارت double bond وهذه صارت + +457 +00:41:24,700 --> 00:41:30,900 +double bond وهنا R وR ايش بيكون شكل الناتج الأخير؟ + +458 +00:41:30,900 --> 00:41:37,120 +اتطلعوا معنا، هيكون R وR ع موقع 3 و4 وCO2 إيثل + +459 +00:41:37,120 --> 00:41:44,780 +وCO2 إيثلالان الناتج اللى طلع معه مافيش فيه CO2 + +460 +00:41:44,780 --> 00:41:50,560 +إثل على الجهتين هنا في CO2 إثل هنا في عنده CO2 + +461 +00:41:50,560 --> 00:41:57,740 +minus واضح و بناء على ذلك صار مضطر انه يحاول يفكر + +462 +00:41:57,740 --> 00:42:04,560 +ليش هذه بدل ما تكون CO2 إثل بيانت على شكل CO2 + +463 +00:42:04,560 --> 00:42:09,460 +minus في النتيجةو احنا في الكيميا عادة بنفسر + +464 +00:42:09,460 --> 00:42:13,140 +نتائج، يعني هبنعمل التفاعل بين هدولة، بنتوقع يطلع + +465 +00:42:13,140 --> 00:42:18,440 +R و R و CO2 و إثل على جهتين، الآن واحدة تطلع إثل + +466 +00:42:18,440 --> 00:42:23,040 +والتانية في النهاية acid CO2 minus، ماقاتش plus، + +467 +00:42:23,040 --> 00:42:32,600 +هتصير إيش؟ CO2أتش طبعا التفسير مش كتير يعني غريب + +468 +00:42:32,600 --> 00:42:37,220 +بالتأكيد احنا في البداية .. بالتأكيد في البداية + +469 +00:42:37,220 --> 00:42:43,060 +هنعمل ال ion السالب اللي موجود عندنا و هذا ال ion + +470 +00:42:43,060 --> 00:42:48,600 +السالب بنخليه هاجمعلى ال c double bond o يعني هذا + +471 +00:42:48,600 --> 00:42:52,760 +أمر طبيعي يعني هيعملنا هنا الايون السالب وخلناه + +472 +00:42:52,760 --> 00:42:56,300 +يهاجم على ال c double bond o بناء على ذلك ال c + +473 +00:42:56,300 --> 00:43:02,360 +double bond o شو بده تصيرالان الـ O minus بدها + +474 +00:43:02,360 --> 00:43:07,720 +تهاجم هنا لما تهاجم هان بهذا الشكل عبر اللي + +475 +00:43:07,720 --> 00:43:13,240 +بيسموها تتراهيدرال ميكانيزم إذا مرت عليكم انه هذه + +476 +00:43:13,240 --> 00:43:20,620 +هاجمت هذه بتصير O minus و بعدين ترجع هذهوتترد + +477 +00:43:20,620 --> 00:43:26,760 +عندنا الـ O إثل وبناء على ذلك لما رجعت هذه هنا و + +478 +00:43:26,760 --> 00:43:33,360 +تردت الـ O إثل شو صار عندى C double bond O O minus + +479 +00:43:33,360 --> 00:43:38,360 +ملاحظين انتوا صار عندى C double bond O O minus لما + +480 +00:43:38,360 --> 00:43:45,080 +فتحت الحلقة من هنا و تردت الـ O إثل من هذا الموقع + +481 +00:43:45,080 --> 00:43:53,320 +الآن مرة تانية خلوا هذهالـ CH2 اتهاجم على C double + +482 +00:43:53,320 --> 00:43:58,640 +bond O اللي هنا تعمل OH و بعدين تعمل elimination + +483 +00:43:58,640 --> 00:44:02,120 +يعني ال key step .. ال key step وين كانت في أي + +484 +00:44:02,120 --> 00:44:08,720 +منطقة الخطوة الأساسية كانت في عبر تكوين هذه الحلقة + +485 +00:44:08,720 --> 00:44:12,760 +و انه اتكون عند هنا C double bond O + +486 +00:44:18,740 --> 00:44:23,220 +التفسير اللي تم هو + +487 +00:44:23,220 --> 00:44:29,360 +عبر حلقة اشمالها سدسي يعني لاحظوا بدأ من هذه ال H + +488 +00:44:29,360 --> 00:44:36,460 +وعملها انا زي هيك صاروا خمسة bonds كسر من هنا فقدت + +489 +00:44:36,460 --> 00:44:43,020 +ال H plus double bond كسر هذه هيكالذي يتابع الأسهم + +490 +00:44:43,020 --> 00:44:47,420 +بهدوء فيكم يستطيع أن يسأل كيف فقدت الـ O إثنى بعد + +491 +00:44:47,420 --> 00:44:52,660 +ذلك CH2 مع CW bond O بتيقله أمر روتيني أن CH2 مع + +492 +00:44:52,660 --> 00:44:55,680 +CW bond O سيعطينا CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +493 +00:44:55,680 --> 00:45:01,140 +مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +494 +00:45:01,140 --> 00:45:05,740 +مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +495 +00:45:05,740 --> 00:45:09,020 +مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +496 +00:45:09,020 --> 00:45:09,020 +مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +497 +00:45:09,020 --> 00:45:09,020 +مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +498 +00:45:09,020 --> 00:45:09,020 +مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 مع CH2 + +499 +00:45:09,020 --> 00:45:12,850 +مع CH2 مع CH2 مع CH2 مع CH2 معما طلعش اندي Easter + +500 +00:45:12,850 --> 00:45:19,210 +على الجهتين فكان لابد من يعني محاولة تفسير + +501 +00:45:19,210 --> 00:45:27,210 +Synthesis تالت بيسموه Gewald Synthesis طبعا في + +502 +00:45:27,210 --> 00:45:33,330 +عنده C double bond O على position Alpha SH مع X + +503 +00:45:33,330 --> 00:45:39,910 +CH2 CN X أي مجموعة في + +504 +00:45:39,910 --> 00:45:47,210 +وجودفي وجود base بتكون هذه الـ CH2 بتكون هذه الـ + +505 +00:45:47,210 --> 00:45:54,090 +CH2 activated مثلين group هذه الـ CH2 اللي موجودة + +506 +00:45:54,090 --> 00:45:59,730 +خلينا هيك نقولها CH2 في جهة معينة إيش في حواليها + +507 +00:45:59,730 --> 00:46:06,710 +CNN وفي جهة تانية ممكن نقول CNN ال X يعني افترضوها + +508 +00:46:06,710 --> 00:46:14,690 +هاي مثال عليها صارت CH2 بين تنتين CNNاللي هو إيش + +509 +00:46:14,690 --> 00:46:21,410 +هذا كنتوا تسموه لما يكون E star مالونيك E star هذا + +510 +00:46:21,410 --> 00:46:25,810 +المالونيك نيترال لما يكون E star و E star + +511 +00:46:25,810 --> 00:46:30,830 +المالونيك E star المالونيك نيترال الآن ال CH2 مع + +512 +00:46:30,830 --> 00:46:35,730 +ال C double bond O شو بدهم يعمله؟C double bond C + +513 +00:46:35,730 --> 00:46:40,670 +بمعنى تفقد ال H2 مع ال O يعني هذا في وجود ال base + +514 +00:46:40,670 --> 00:46:46,610 +يصير minus بهاجم OH OH مع ال H CH2 مع C double + +515 +00:46:46,610 --> 00:46:51,230 +bond O هذه اللي كانت CH2 وهذه اللي كانت C double + +516 +00:46:51,230 --> 00:46:56,750 +bond O إذا تم التفاعل بهذا الشكل وصار عندي carbon + +517 +00:46:56,750 --> 00:47:00,050 +double bond carbon من خلال هذا التفاعل تحديدا + +518 +00:47:02,930 --> 00:47:06,230 +بعد هيك ال sulfur in eucleophil تذكير على ال amino + +519 +00:47:06,230 --> 00:47:10,450 +groups كلنا متذكرين انه التذكير عفوا على ال + +520 +00:47:10,450 --> 00:47:16,830 +neutral group بيعطينا finally amino بيصير عندنا في + +521 +00:47:16,830 --> 00:47:22,510 +الخطوة الأولى إمين و الإمين بيعمل tautomerization + +522 +00:47:22,510 --> 00:47:28,990 +لإينامينفبيطلع عندنا هذا المركب اذا تفصيل هذا + +523 +00:47:28,990 --> 00:47:32,950 +التفاعل هو تفصيل سهل ضمن المبادئ العامة اللي احنا + +524 +00:47:32,950 --> 00:47:37,570 +اتعلمناها اللي هي تكوين ايون سالم addition على c + +525 +00:47:37,570 --> 00:47:44,770 +double bond o بعدين اكزو addition على النيترال + +526 +00:47:44,770 --> 00:47:53,290 +بيعطينا اين امين كمحصلة ويمكن بتقدروا تحسوا انتوا + +527 +00:47:53,290 --> 00:47:59,310 +الآنانه قداش بيكون مفيد لما احنا درسنا المبادئ + +528 +00:47:59,310 --> 00:48:02,370 +العامة .. درسنا المبادئ العامة للكيميا الحلقية و + +529 +00:48:02,370 --> 00:48:05,470 +بعدين اجينا ناخد الأمثلة يعني لو احنا كنا بدنا + +530 +00:48:05,470 --> 00:48:10,170 +نبدأ بالثيوران او بالثيوفين derivative و بدنا هنا + +531 +00:48:10,170 --> 00:48:14,150 +و احنا مش متعودين نشوف كيف اليوكليوفايل بيسكر ع ال + +532 +00:48:14,150 --> 00:48:19,400 +CN و بيعطينا الانامينأحنا أخدنا الفكرة العامة أن + +533 +00:48:19,400 --> 00:48:23,740 +أنيوكليوفايل بيعمل cyclization على الـC أن بيعطينا + +534 +00:48:23,740 --> 00:48:28,600 +إيمين والإيمين بيعمل الانامين الـA مرت علينا في + +535 +00:48:28,600 --> 00:48:34,360 +تحضير الثيوفين ما بتكونش فكرة إيش؟ ما بتكونش فكرة + +536 +00:48:34,360 --> 00:48:41,740 +صعبة بالنسبة لل reactions of ثيوفينالـ + +537 +00:48:41,740 --> 00:48:45,700 +Electrophilic Substitution بشكل عام على الثيوفين + +538 +00:48:45,700 --> 00:48:51,010 +أيضا بتم على موقع اتنينيعني في ال بيرون والفيوران + +539 +00:48:51,010 --> 00:48:54,710 +والثيوفين ال electrophilic substitution الموقع + +540 +00:48:54,710 --> 00:48:59,430 +الأساسي اللي هو موقع إيش اتنين الان أمثلة نيتريش + +541 +00:48:59,430 --> 00:49:04,030 +هالوجيناش ال formulation الأمثلة كتيرة ما يعني + +542 +00:49:04,030 --> 00:49:07,530 +بدناش ناخد أي مثال فيها بشكل عام لكن بنقول إحنا + +543 +00:49:07,530 --> 00:49:11,010 +بشكل عام electrophilic substitution occurs at + +544 +00:49:11,010 --> 00:49:19,570 +position two لو إجينا لل reactivity مين فيهم؟أنشط + +545 +00:49:19,570 --> 00:49:21,890 +في الـ Electrophilic Substitution، حكينا هذا + +546 +00:49:21,890 --> 00:49:26,770 +الكلام، أن الـ Birol أنشط كتير من الفيوران، + +547 +00:49:26,770 --> 00:49:33,170 +الفيوران أنشط من الثيوفين و كلهم أنشط من البنزين + +548 +00:49:35,400 --> 00:49:41,080 +الان الفيوران لاحظ ما في ملاحظة بتختلف عليهم انه + +549 +00:49:41,080 --> 00:49:46,100 +كان هو اكثر واحد بيعمل ايش addition يعني بالاضافة + +550 +00:49:46,100 --> 00:49:49,300 +لل substitution الفيوران اللي بيميز انه بيعمل + +551 +00:49:49,300 --> 00:49:52,820 +addition يعني الثيوفين لسه معظم تفاعلاته + +552 +00:49:53,490 --> 00:49:57,670 +substitution ال addition فيه قليل اكثر واحد في + +553 +00:49:57,670 --> 00:50:02,790 +هدولة التلاتة بيعمل addition اللي هو الفيوران اكثر + +554 +00:50:02,790 --> 00:50:11,130 +واحد بيعمل addition اللي هو الفيوران طبعا لو اجينا + +555 +00:50:11,130 --> 00:50:15,470 +لل cycle addition وعملنا مقارنة بينهم قولنا ال by + +556 +00:50:15,470 --> 00:50:21,300 +role بيعمل cycle additionقليل جدا، الفيوران لأ + +557 +00:50:21,300 --> 00:50:28,300 +بيشتغل كضيين بشكل أساسي، الثيوفين بيشتغل كضيين + +558 +00:50:28,300 --> 00:50:33,840 +وبيشتغل كضيين وفاعليعني ممكن يتم التفاعل فيه as a + +559 +00:50:33,840 --> 00:50:37,600 +diene على تنتين double bonds وممكن يتم على واحدة + +560 +00:50:37,600 --> 00:50:40,920 +من ال double bonds فقط على واحدة من ال double + +561 +00:50:40,920 --> 00:50:47,320 +bonds واجهته بيكون بيشتغل كاش ك dienophile الان + +562 +00:50:47,320 --> 00:50:54,500 +لاحظوا معنى أنه أحيانا بيجيبوا أمثلة أنه يا ترى ال + +563 +00:50:54,500 --> 00:50:59,730 +electrophilic substitution بتيم على موقع اتنينطيب + +564 +00:50:59,730 --> 00:51:06,110 +لو جبنا ثيوفين و موقع اتنين فيه مشهول أساسا و + +565 +00:51:06,110 --> 00:51:12,070 +جربنا ان نعمل نيتراشن وين بده يتم؟ يعني هم هنا + +566 +00:51:12,070 --> 00:51:18,800 +شغال و موقع اتنينوعملوا الـ Nitration طبعا لاحظوا + +567 +00:51:18,800 --> 00:51:21,280 +انه لو كانت المجموعة اللي هي على موقع اتنين + +568 +00:51:21,280 --> 00:51:25,120 +electron releasing ال Nitration بتم على موقع خمسة + +569 +00:51:25,120 --> 00:51:28,440 +اللي هو كأنه اتنين من الجهة التانية و لو كانت + +570 +00:51:28,440 --> 00:51:31,960 +المجموعة electron with a drawing ال Nitration بتم + +571 +00:51:31,960 --> 00:51:39,520 +على موقع اربعة واحد اتنين تلاتة اربعة طبعا واضح + +572 +00:51:39,520 --> 00:51:44,930 +بالاضافة إلى موقعخمسة بنسب معينة واضح ان هذا ال + +573 +00:51:44,930 --> 00:51:51,590 +slide هي slide ايش تجربية يعني بدون ما الإنسان + +574 +00:51:51,590 --> 00:51:57,390 +يكون عنده تجربة مش هيصل هذا الكلام يعني في نهاية + +575 +00:51:57,390 --> 00:52:07,070 +نتيجة تجربية الآن سكروا عليه موقع اتنين و خمسة + +576 +00:52:09,370 --> 00:52:14,150 +و بناءً على ذلك عملوله Acetylation لاحظوا أنه تم + +577 +00:52:14,150 --> 00:52:20,950 +التفاعل على موقع تلاتة و تم أيضًا إبدال + +578 +00:52:20,950 --> 00:52:26,130 +Electrophilic Substitution على موقع خمسة لاحظوا + +579 +00:52:26,130 --> 00:52:32,480 +هنا شيلنا احنا PR Plus و حطينا مكانهاC O Methyl + +580 +00:52:32,480 --> 00:52:35,340 +Plus يعني هذا الإبدال Electrophilic Substitution + +581 +00:52:35,340 --> 00:52:39,360 +زي ما كنا نشيل H Plus و نحط بدالها Electrophile + +582 +00:52:39,360 --> 00:52:45,140 +هنا shall be R Plus هنا يمكن نستعمل كلمةIpso + +583 +00:52:45,140 --> 00:52:50,660 +ماعرفش إذا هذه الكلمة مرت عليكم ولا لأ Ipso معناه + +584 +00:52:50,660 --> 00:52:55,300 +على نفس الموطن يعني عادة لما بيتم ال substitution + +585 +00:52:55,300 --> 00:52:58,120 +في ال aromatic compounds لو افترضنا ان هنا في + +586 +00:52:58,120 --> 00:53:01,740 +مجموعة X احنا كنا نقول ان ال substitution ممكن يتم + +587 +00:53:01,740 --> 00:53:06,630 +على ال orthoع الميتا، ع البارا، إبدال هذه Ortho، + +588 +00:53:06,630 --> 00:53:09,250 +هذه ميتا، هذه بارا، طب لو الإبدال يجي محل هذه + +589 +00:53:09,250 --> 00:53:16,430 +نفسها، وقتها بنسميه Ipsosubstitution، واضح؟ فكل + +590 +00:53:16,430 --> 00:53:22,070 +هذه الأمثلة واضح تمام أنها أمثلة تجريبية + +591 +00:53:24,240 --> 00:53:29,140 +طبعا هل ممكن يتم عند الـ nucleophilic substitution + +592 +00:53:29,140 --> 00:53:34,880 +أيضا جربوا انهم يفعلوا هذا المركب مع نيوكليوفايل + +593 +00:53:34,880 --> 00:53:42,580 +امين جابوا امين و الامين هم نيوكليوفايل في النهاية + +594 +00:53:42,580 --> 00:53:49,010 +الامين حل ما حل ايش ال PR minus في المحصلةعبر + +595 +00:53:49,010 --> 00:53:51,630 +ميكانيزم الـ Nucleophilic Substitution زي اللي + +596 +00:53:51,630 --> 00:53:55,350 +حكيناها أول ما اتكلمنا عن الـ Chichibabine + +597 +00:53:55,350 --> 00:54:01,530 +reaction وغيره بنفس المنطق بإمكانه لـ Nucleophile + +598 +00:54:01,530 --> 00:54:05,490 +يهاجمها تتحرك البن تتحرك لاحظوا الـ Nitro اللي هنا + +599 +00:54:05,490 --> 00:54:10,610 +ساعد على إتمام الـ Nucleophilic Substitution يمكن + +600 +00:54:10,610 --> 00:54:14,890 +أنتم مروا معاكم حتى على البنزين الـ Nucleophilic + +601 +00:54:14,890 --> 00:54:22,180 +Substitution كان ممكن وين؟أه يعني في البنزين + +602 +00:54:22,180 --> 00:54:26,060 +المثال المشهور المثال المشهور اللى بتنفي ال + +603 +00:54:26,060 --> 00:54:30,880 +nucleophilic substitution لما يكون عندى Cl و تلاتة + +604 +00:54:30,880 --> 00:54:36,840 +نيترو الآن هذه النيترو بتسحب الإلكترونات وبناء على + +605 +00:54:36,840 --> 00:54:42,020 +ذلك طالما في كتير مجموعات بتسحب الإلكترونات بإمكان + +606 +00:54:42,020 --> 00:54:49,600 +ال nucleophile ييجى يهاجم زى مثلا ال OH minusناخد + +607 +00:54:49,600 --> 00:54:53,220 +الـ Nucleophile in this case الـ OH minus بإمكانه + +608 +00:54:53,220 --> 00:54:57,360 +يهاجم هنا وجد هال minus مراح ينحمل عهاد ال O مرة + +609 +00:54:57,360 --> 00:55:02,660 +هان مرة هان يعني في مجموعات مساعدة لكن لو فعلنا + +610 +00:55:02,660 --> 00:55:08,300 +لchlorobenzene لحاله مع ال OH minus بتمشي ابدال بس + +611 +00:55:08,300 --> 00:55:11,000 +ل Trinitrochlorobenzene + +612 +00:55:11,870 --> 00:55:14,870 +مع ال sodium hydroxide يمكن شوية تسخين كان بتم + +613 +00:55:14,870 --> 00:55:19,430 +الإبداء فلاحظوا أنا كيف تدخل ال nitro group في + +614 +00:55:19,430 --> 00:55:23,110 +المساعدة على إتمام إيش ال nucleophilic + +615 +00:55:23,110 --> 00:55:26,610 +substitution يعني هذا بيهاجم هان بتتحرك هذي بتتحرك + +616 +00:55:26,610 --> 00:55:33,450 +هذي صفية السالب في الآخر وين صفة محمول؟عال Oxygen + +617 +00:55:33,450 --> 00:55:36,510 +فال Oxygen بتاعت ال Nitro ساعدت في حملة السالب + +618 +00:55:36,510 --> 00:55:40,830 +بعدك لو كل شيء رجع زي ما كان هذي رجعت هذي رجعت هذي + +619 +00:55:40,830 --> 00:55:48,950 +رجعت ايش هيطرد عليه ال PR minus واضح ال PR minus + +620 +00:55:48,950 --> 00:55:54,970 +بالنسبة + +621 +00:55:54,970 --> 00:56:01,180 +لل Cycloaddition reactionsالثيوفين ممكن يشتغل + +622 +00:56:01,180 --> 00:56:05,520 +كضايين وهي الدليل على ذلك تفاعله مع المليك + +623 +00:56:05,520 --> 00:56:11,540 +أنهيدرايد هذا بتايع له تفاعل مشهور جدابهذا الشكل + +624 +00:56:11,540 --> 00:56:15,800 +بيكمل و بيعمل deals elder cycle addition الان هنا + +625 +00:56:15,800 --> 00:56:21,060 +الثيوفين اشتغل كاش؟ ضيين هو في النهاية بور ضيين + +626 +00:56:21,060 --> 00:56:25,580 +يعني مش هالضيين القوى زي الفيوران يعني اللي بيشوف + +627 +00:56:25,580 --> 00:56:30,080 +أمثلة لفيوران و أمثلة لثيوفين مين بيشتغل أكثر + +628 +00:56:30,080 --> 00:56:37,620 +كضيين؟ الفيورانهي مثال تاني بهذا المثال التاني من + +629 +00:56:37,620 --> 00:56:42,500 +هذا الجزء .. هذا التفاعل المشهور بيعمله .. اللي + +630 +00:56:42,500 --> 00:56:46,300 +إيش بنسميه احنا؟ بنزاين .. بنزاين .. آه كلكوا + +631 +00:56:46,300 --> 00:56:49,640 +عارفينه البنزاين، الآن البنزاين مع الفيوران + +632 +00:56:52,600 --> 00:56:57,280 +هيعمل Cycloaddition ديالز ألدر Cycloaddition هيكون + +633 +00:56:57,280 --> 00:57:01,940 +عنده هذه ال triple bond تصير double bond و من ال + +634 +00:57:01,940 --> 00:57:06,420 +Cycloaddition من ديالز ألدر كمان double bond الآن + +635 +00:57:06,420 --> 00:57:12,480 +هذا بعد هيك بيفقد السلفةفقد السلفر هيعطيني ash + +636 +00:57:12,480 --> 00:57:18,580 +كمان by bond السلفر لما بيطلع في النهاية ماصيره + +637 +00:57:18,580 --> 00:57:22,160 +يتجمع على شكل ash الصورة الطبيعية اللي بيطلع فيها + +638 +00:57:22,160 --> 00:57:28,980 +اسئت .. اسئت مش السلفر في الطبيعة ال allotropic + +639 +00:57:28,980 --> 00:57:36,740 +form يعني على أي allotropeS8 واضح؟ بيطلع على شكل + +640 +00:57:36,740 --> 00:57:40,920 +S8 وحيلاحظوا يمكن اللي اشتغلوا التفاعل انه بيكون + +641 +00:57:40,920 --> 00:57:46,340 +عندهم بودرة كبريت صفرة بيطلع على شكل بودرة صفرة + +642 +00:57:46,340 --> 00:57:53,500 +هنا ايضا الخلاصة الثيوفين هانا اشتغل as إضايين في + +643 +00:57:53,500 --> 00:57:58,640 +هذا المثال مع البنزين الثيوفين اشتغل as إضايين + +644 +00:58:00,800 --> 00:58:10,820 +الان امثلة اضافية هنستعمل ايضا ثيوفين مع + +645 +00:58:10,820 --> 00:58:17,930 +triple bond مرة تانيةعمل Cycloaddition طلع عندى + +646 +00:58:17,930 --> 00:58:22,670 +مركب بكام bond؟ كام buy bond؟ تنتين وفقد السلفر + +647 +00:58:22,670 --> 00:58:27,350 +جاب التالتة يعني ال deal's elder reaction نفسه + +648 +00:58:27,350 --> 00:58:32,370 +بيعطينا buy bond و لل triple bond كمان واحدة وفقد + +649 +00:58:32,370 --> 00:58:38,810 +السلفر اه فعلى بال مين ان هذا المركبجاي من وين؟ من + +650 +00:58:38,810 --> 00:58:45,670 +ثيوفين، الآن في هذا المثال، لأ شوية الكلام مختلف، + +651 +00:58:45,670 --> 00:58:50,610 +هم فعلوا الثيوفين، لكن المرة هذه بدنا نرسم + +652 +00:58:50,610 --> 00:58:52,310 +الثيوفين بهذا الشكل + +653 +00:58:55,040 --> 00:59:01,280 +اتفعل كديينوفايل يعني على double bond واحدة منه + +654 +00:59:01,280 --> 00:59:05,780 +وهذا كان عبارة عن الديين خلينا نقول اللي بده يفقد + +655 +00:59:05,780 --> 00:59:09,700 +إيش في النهاية ال nitrogen هذا masked ديين + +656 +00:59:09,700 --> 00:59:14,680 +التترازيل مار علينا لما اتكلمنا عن masked ديين هو + +657 +00:59:14,680 --> 00:59:21,600 +عبارة عن masked ديين فلما تم التفاعل على هذه ال + +658 +00:59:21,600 --> 00:59:28,810 +bondواضح وفقدت ال double bond فقدت ال nitrogen + +659 +00:59:28,810 --> 00:59:35,130 +عملها double bond لاحظوا ايش اللي صار عنده صار + +660 +00:59:35,130 --> 00:59:41,170 +عنده fused compound صار عنده fused compound ولو + +661 +00:59:41,170 --> 00:59:45,510 +بدنا تقولولنا الاسم العام تبعه + +662 +00:59:48,060 --> 00:59:54,420 +الحلقة اللى فيها نيتروجين هي الاساس واضح ايش اسمها + +663 +00:59:54,420 --> 01:00:00,880 +هذه السوداسية اللى فيها نيتروجين تين بيردازين + +664 +01:00:00,880 --> 01:00:07,900 +بيرمدين بيرازين بيردازين بيردازين وبناء على ذلك + +665 +01:00:07,900 --> 01:00:10,880 +الان لاحظوا ان هنحيكون عندى + +666 +01:00:15,430 --> 01:00:25,770 +BCD 12345 إذا هذا هيكون ثيينو تو ثري دي بيريدازين + +667 +01:00:25,770 --> 01:00:30,390 +derivativeثيينو تو ثري دي بريدازين derivative + +668 +01:00:30,390 --> 01:00:35,570 +المهم في هذا الموضوع ان هذا التترازين ان هذا + +669 +01:00:35,570 --> 01:00:40,250 +التترازين كان عبارة عن الضيين ال mask الضيين و ان + +670 +01:00:40,250 --> 01:00:45,990 +الثيوفين هنا اشتغل as a deino file الثيوفين هنا + +671 +01:00:45,990 --> 01:00:48,470 +كان ديينه file + +672 +01:00:50,840 --> 01:00:55,060 +ولاحظوا ع بال مين برضه لو طلب هذا التحذير بيجي على + +673 +01:00:55,060 --> 01:00:58,620 +البال ان هذه كانت حلقة سداسية فيها نيتروجين وان + +674 +01:00:58,620 --> 01:01:09,260 +هذا عبر ديالز ألدر reaction الآن مرة ثانية + +675 +01:01:09,260 --> 01:01:10,600 +الثيوفين + +676 +01:01:15,460 --> 01:01:21,040 +مع هذا المركب دايازو كومباون الدايازو مع التسخين + +677 +01:01:21,040 --> 01:01:33,640 +شو بيعطينا؟ كاربين CO2 كاربين دايازو + +678 +01:01:33,640 --> 01:01:38,560 +بالتسخين بفقد ال nitrogen بيعطينا كاربين الآن + +679 +01:01:38,560 --> 01:01:43,840 +الكاربين ايش بيعمل؟التي هي الـ Chelotropic + +680 +01:01:43,840 --> 01:01:49,640 +Cycloaddition على ضب البوند وهو لديه ضب البوند + +681 +01:01:49,640 --> 01:01:54,980 +وبناء على ذلك عمل لـ Chelotropic reaction عليها + +682 +01:01:54,980 --> 01:02:02,360 +واضح؟ هذا تفاعل كربين يعمل Cycloaddition على ضب + +683 +01:02:02,360 --> 01:02:08,940 +البوند إذا هنا الثيوفينالـ aromaticity عنده مقدسة + +684 +01:02:08,940 --> 01:02:14,300 +بزامه اتفاعل بأكثر من طريقة أزإضايين وبأكثر من + +685 +01:02:14,300 --> 01:02:18,020 +طريقة اتفاعل ك double bond يعني ال double bond + +686 +01:02:18,020 --> 01:02:22,620 +نفسها اتفاعلت كإنها double bond يعني مش كإنها ضمن + +687 +01:02:22,620 --> 01:02:28,120 +منظومة إيش خلينا نقولالـ aromatic system مش كأنها + +688 +01:02:28,120 --> 01:02:33,240 +ضمن منظومة الـ aromatic system فمش مقدسة الـ + +689 +01:02:33,240 --> 01:02:38,600 +aromaticity عنده الآن هنا في عندنا مرة تالتة أو + +690 +01:02:38,600 --> 01:02:48,820 +رابعة أو خامسة ثيوفين مع ال triple bond هيعمل + +691 +01:02:48,820 --> 01:02:53,000 +و هنا لو قلنا carbon carbon + +692 +01:02:55,650 --> 01:03:01,190 +2 plus 2 + +693 +01:03:01,190 --> 01:03:06,450 +Cycloaddition طبعا الثيوفين في الأساس اللي مستعمله + +694 +01:03:06,450 --> 01:03:14,350 +تترا مثل ثيوفين عليه أربع مجموعات مثل مش مشكلة وهي + +695 +01:03:14,350 --> 01:03:21,680 +مع Acetylene derivative أو دايسيانو أسيتيلينفبيعمل + +696 +01:03:21,680 --> 01:03:25,140 +two plus two cycle addition إذا هنا اللي اتفاعل من + +697 +01:03:25,140 --> 01:03:29,060 +الثيوفين ال double bond اللي اتفاعل من هنا من + +698 +01:03:29,060 --> 01:03:31,940 +الثيوفين ال double bond و اللي اتفاعل هنا ال + +699 +01:03:31,940 --> 01:03:34,740 +double bond مرات اتفاعل على ال double bond عمل + +700 +01:03:34,740 --> 01:03:38,680 +cycle addition cellotropic reaction two plus two + +701 +01:03:38,680 --> 01:03:46,910 +حتى deals elderاتفعل ك دايينوفايل و اتفعل ك دايين + +702 +01:03:46,910 --> 01:03:51,470 +فكل أمثلة ال cycle addition حقيقة موجودة على + +703 +01:03:52,830 --> 01:03:57,350 +الثيوفين كل أمثلة ال cycle addition موجودة على + +704 +01:03:57,350 --> 01:04:03,490 +الثيوفين بهيك بننتهي من إعطاء فكرة عامة عن هذه + +705 +01:04:03,490 --> 01:04:08,170 +الحلقات الخماسية وبننهي هذا المساق بأمل أن تكونوا + +706 +01:04:08,170 --> 01:04:14,930 +أخدتوا فكرة لا بأس بها عن الكيميا الحلقية بأمل أن + +707 +01:04:14,930 --> 01:04:17,550 +تكونوا أخدتوا فكرة لا بأس بها عن الكيميا الحلقية + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bXzOV3H6R70.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bXzOV3H6R70.srt new file mode 100644 index 0000000000000000000000000000000000000000..8a05e315d6451888be3bbad82062e8ca15230dbe --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bXzOV3H6R70.srt @@ -0,0 +1,2046 @@ +1 +00:00:20,890 --> 00:00:25,550 +بسم الله الرحمن الرحيم اليوم بنبدأ معكم في موضوع + +2 +00:00:25,550 --> 00:00:29,330 +جديد في مجال تحضير الـ heterocyclic rings واحنا + +3 +00:00:29,330 --> 00:00:35,410 +اتفقنا سابقا أنه بدنا نشرح طرق عامة لتحضير الـ + +4 +00:00:35,410 --> 00:00:40,730 +heterocyclic rings من خلال أن نحضر حلقات مختلفة + +5 +00:00:40,730 --> 00:00:45,610 +ما نركزش على حلقة واحدة لأن نركز على طريقة أول ما + +6 +00:00:45,610 --> 00:00:52,350 +اتكلمنا اتكلمنا على تفاعل الإبدال على ذرة كربون + +7 +00:00:52,350 --> 00:00:56,510 +بتحمل أربع روابط زي ما سميناها tetragonal carbon و + +8 +00:00:56,510 --> 00:01:04,360 +ربما تتذكروا أن احنا استعنا بقواعد Baldwin فلما + +9 +00:01:04,360 --> 00:01:10,800 +كنا بنعمل إبدال على tetragonal carbon كنا بنشيل + +10 +00:01:10,800 --> 00:01:16,220 +مجموعة مرتبطة برابطة واحدة ولذلك ما كانش هنا في عندنا + +11 +00:01:16,220 --> 00:01:20,040 +احتمال إلا أن الـ cyclization يكون ايش + +12 +00:01:20,040 --> 00:01:25,100 +exocyclization يعني ما فيش إمكانية أن يكون عندي في + +13 +00:01:25,100 --> 00:01:30,080 +الـ tetragonal cyclization endocyclization بس طالما + +14 +00:01:30,080 --> 00:01:34,180 +أنها رابطة بدأت تتحرك إذا هي فقط هتتحرك للخارج و + +15 +00:01:34,180 --> 00:01:39,020 +يتم الـ cyclization أخذنا أمثلة كتير الآن لما نيجي + +16 +00:01:39,020 --> 00:01:45,280 +نشتغل على الـ diagonal atoms أو carbons في عندنا + +17 +00:01:45,280 --> 00:01:48,700 +double bond الآن لما يصير في عندنا double bond + +18 +00:01:48,700 --> 00:01:53,940 +بيصير في عندنا إمكانية لنوعين من الـ cyclization لـ + +19 +00:01:53,940 --> 00:01:56,940 +exocyclization يعني واحدة من الـ double bonds خلينا + +20 +00:01:56,940 --> 00:01:59,800 +نقول هذا الـ pi bond تتحرك للخارج this is + +21 +00:01:59,800 --> 00:02:03,540 +exocyclization وهذه بتكون الحقيقة عملية addition + +22 +00:02:03,540 --> 00:02:09,640 +أو أن الـ double bond تتحرك بداخل الحلقة يعني هذه + +23 +00:02:09,640 --> 00:02:15,120 +وبالتالي بيكون عندنا endocyclization ففي حالة ما + +24 +00:02:15,120 --> 00:02:19,300 +بنحكي عن الـ double bonds بصير في عنا احتمالين من + +25 +00:02:19,300 --> 00:02:22,360 +ناحية المبدأ في البداية أن في احتمال الـ + +26 +00:02:22,360 --> 00:02:27,880 +exocyclization في احتمال الـ endocyclization هذا + +27 +00:02:27,880 --> 00:02:31,300 +إذا تكلمنا عن الـ double bonds بشكل عام + +28 +00:02:44,980 --> 00:02:49,500 +الـ C double bond O الـ C double bond N الـ C + +29 +00:02:49,500 --> 00:02:55,020 +double bond S وربما الـ C double bond C لو أنا + +30 +00:02:55,020 --> 00:02:59,060 +بتطلع على هدول الـ double bonds اللي موجودين عندي + +31 +00:02:59,060 --> 00:03:04,500 +بلاحظ أن في الـ double bonds التلاتة الأوليين نسبة + +32 +00:03:05,610 --> 00:03:10,730 +الاستقطاب فيهم عالية بحيث أن الكربون في الغالب + +33 +00:03:10,730 --> 00:03:15,110 +هتكون partially positive وهذه partially negative + +34 +00:03:15,110 --> 00:03:19,490 +وبناء على ذلك لما ييجي الـ nucleophile يهاجم هيجي + +35 +00:03:19,490 --> 00:03:24,730 +يهاجم على الكربون وهتتحرك هذه الرابطة بهذا الشكل + +36 +00:03:24,730 --> 00:03:30,020 +فغالبا مع هذولة التلاتة هنصير نحكي عن exo + +37 +00:03:30,020 --> 00:03:34,040 +-cyclization يعني بكون عندي احتمال واحد exo + +38 +00:03:34,040 --> 00:03:38,140 +-cyclization لما بحكي أنا عن carbon double bond + +39 +00:03:38,140 --> 00:03:43,420 +carbon الآن مختلف أن which carbon will be more + +40 +00:03:43,420 --> 00:03:48,310 +positive than the other it depends on the other + +41 +00:03:48,310 --> 00:03:53,510 +groups هنا وبناء على ذلك ممكن نحكي عن + +42 +00:03:53,510 --> 00:03:57,650 +exocyclization وممكن نحكي عن endocyclization + +43 +00:03:57,650 --> 00:04:02,230 +وبالتالي بكل احتمال أكثر أن نحصل على two products + +44 +00:04:02,230 --> 00:04:06,730 +في حالة الـ carbon carbon double bonds يعني لما + +45 +00:04:06,730 --> 00:04:10,210 +نقول أكمل المعادلة لو عندنا carbon oxygen double + +46 +00:04:10,210 --> 00:04:14,270 +bond هو تفاعل واحد الـ nucleophile will attack the + +47 +00:04:14,270 --> 00:04:20,250 +carbon atom واضحة فهدولة لسه بيصيروا بالنسبة لنا + +48 +00:04:20,250 --> 00:04:24,330 +أسهل لأن بيحتملوا احتمال واحد اللي هو الـ + +49 +00:04:24,330 --> 00:04:27,570 +exocyclization في غالب الأحوال هنا في عندي + +50 +00:04:27,570 --> 00:04:31,450 +احتمالين الـ exocyclization و الـ endocyclization we + +51 +00:04:31,450 --> 00:04:36,650 +expect two products الآن النتيجة ممكن يطلع الـ exo و + +52 +00:04:36,650 --> 00:04:40,430 +ممكن يطلع الـ endo وممكن يطلع خليط منهم في النهاية + +53 +00:04:40,430 --> 00:04:47,610 +الكيميا بتضل ايش؟ علم تجريبي هنشوف أمثلة بالتدريج + +54 +00:04:47,610 --> 00:04:53,450 +نتناقش كل الـ cyclization على هذه الأنواع من الـ + +55 +00:04:53,450 --> 00:04:54,130 +double bonds + +56 +00:05:01,910 --> 00:05:06,670 +هنا بدنا نذكر بشغلة كتير مهمة بالنسبة للسيطة بالـ + +57 +00:05:06,670 --> 00:05:11,110 +bond O السيطة بالـ bond O لما تدرس في الـ organ الـ + +58 +00:05:11,110 --> 00:05:15,510 +chemistry اللي هي الـ carbonyl group قلنا الـ + +59 +00:05:15,510 --> 00:05:20,340 +carbonyl compounds يقسموا إلى نوعين أساسيين و + +60 +00:05:20,340 --> 00:05:23,780 +يصنفوا حتى في كتب الكيميا العضوية بهذا الشكل + +61 +00:05:51,230 --> 00:05:55,050 +الالديهايدات والكيتونات لحال والأحماض الكربوكسيلية + +62 +00:05:55,050 --> 00:06:00,510 +ومشتقاتها لحال ليش هذا التصنيف اعتمادا على التفاعل + +63 +00:06:00,510 --> 00:06:05,670 +الأساسي لكل عائلة الالديهايدات والكيتونات تفاعلها + +64 +00:06:05,670 --> 00:06:09,630 +الأساسي الـ addition الآن شطرين كلكوا بتقولوا + +65 +00:06:09,630 --> 00:06:12,170 +addition وبعد شهر بتقولوا substitution لكن في + +66 +00:06:12,170 --> 00:06:17,730 +الامتحان إلا نسبة تلاتين في المية من الطالبات بييجوا + +67 +00:06:17,730 --> 00:06:21,450 +يشتغلوا بالعكس ويعملوا خطأ لأن ما بيصدقوش أنهم + +68 +00:06:21,450 --> 00:06:26,510 +ما بيعملوا أخطاء مثلا هذه الـ C double bond O لو + +69 +00:06:26,510 --> 00:06:31,630 +بدنا نتخيلها هذه ألديهايد ولا لا؟ ألديهايد محذوف ايش + +70 +00:06:31,630 --> 00:06:35,130 +فلو بدي أعمل عليها التفاعل المفروض هذا الـ nitrogen + +71 +00:06:35,130 --> 00:06:38,830 +in nucleophile هاجم هنا أضيف على الـ C double bond + +72 +00:06:38,830 --> 00:06:42,730 +O صارت الـ double bond single bond إذا هذه عملية + +73 +00:06:42,730 --> 00:06:49,220 +ايش؟ صفة عندي هنا OH وجنبها NH غالبا إذا الـ OH و + +74 +00:06:49,220 --> 00:06:54,000 +الـ NH جنب بعض أو ممكن حتى OH مع CH تانية جنبها + +75 +00:06:54,000 --> 00:07:00,600 +يعملوا حذف للميّه OH مع H بلس الـ OH مع زوج + +76 +00:07:00,600 --> 00:07:03,960 +الإلكترونات مع H بلس بيعملوا double bond لو كانت + +77 +00:07:03,960 --> 00:07:06,820 +تنافس أن الـ OH تحدث H عن الـ nitrogen أو عن + +78 +00:07:06,820 --> 00:07:10,560 +الكربون هتحدث عن الـ nitrogen وبناء على ذلك + +79 +00:07:10,560 --> 00:07:14,840 +النتيجة النهائية هتكون C double bond N هذا الكلام + +80 +00:07:14,840 --> 00:07:18,780 +كتير مر علينا يعني لما كنا ناخد تفاعلات الـ amines + +81 +00:07:18,780 --> 00:07:23,220 +مع الـ ketones تفاعلات الـ oximes تفاعلات الـ .. الـ + +82 +00:07:23,220 --> 00:07:27,250 +hydrazones كنا نقول C double bond O زي N H2 C + +83 +00:07:27,250 --> 00:07:31,250 +double bond N وننهي الموضوع واضح؟ هذه عملية الـ + +84 +00:07:31,250 --> 00:07:34,390 +addition اللي بتتم في الـ aldehydes أو الـ ketones + +85 +00:07:34,390 --> 00:07:41,170 +الآن لو كان عندي C double bond O E star أو acid أو + +86 +00:07:41,170 --> 00:07:43,290 +اللي هي العائلة التانية acids and their + +87 +00:07:43,290 --> 00:07:48,090 +derivatives بتتم عملية ايش؟ Substitution أن هذه + +88 +00:07:48,090 --> 00:07:53,430 +بتهاجم وبتطرد الـ X وبناء على ذلك بيصير عنده C + +89 +00:07:53,430 --> 00:07:58,010 +double bond O in this case and H حسب النيوكليوفايل + +90 +00:07:58,010 --> 00:08:03,130 +لو كانت هذه OH بيكون C double bond O وبتصير + +91 +00:08:03,130 --> 00:08:05,810 +العائلات في الكيميا العضوية زي ما أنتم عارفينها + +92 +00:08:05,810 --> 00:08:09,330 +الـ C double bond O جنب O يعني Cyclic E star + +93 +00:08:09,330 --> 00:08:14,430 +بيسموها لاكتون الـ C double bond O جنب N Cyclic + +94 +00:08:14,430 --> 00:08:15,630 +Amide بيسموها + +95 +00:08:17,900 --> 00:08:23,960 +ماذا يسمونه Cyclic Amide؟ لاكتَم اللي موجود في حلقة + +96 +00:08:23,960 --> 00:08:28,700 +البنسالين الحلقة الرباعية الـ beta-lactam اللي + +97 +00:08:28,700 --> 00:08:35,060 +بتذكروا حلقة البنسالين فيها سيطة بالـ bond O و N و + +98 +00:08:35,060 --> 00:08:42,720 +هذه الحلقة مرتبطة بحلقة خماسية عشان كده بيسموها beta + +99 +00:08:42,720 --> 00:08:45,880 +-lactam لأن هاي موقع Alpha والـ nitrogen هذا على + +100 +00:08:46,890 --> 00:08:53,710 +بيتا واضح فبنقول احنا بيتا لاكتام وما إلى ذلك + +101 +00:08:53,710 --> 00:08:58,170 +بناء على ذلك بتكون بهذا الشكل إذا بدنا نكون + +102 +00:08:58,170 --> 00:09:04,170 +مظبوطين عشان نقول هاي alpha هاي beta وهنا حلقة + +103 +00:09:04,170 --> 00:09:10,740 +خماسية أو حلقة سداسية واضح؟ حلقة خماسية اللي هي + +104 +00:09:10,740 --> 00:09:14,720 +مشتقات البنسالين الأساسية لو بدنا نفس البنسالين + +105 +00:09:14,720 --> 00:09:18,200 +المشتقات الجديدة صاروا يبدلوا الخماسية بسداسية + +106 +00:09:18,200 --> 00:09:22,300 +الـ cephalosporins وما إلى ذلك بكل الأحوال + +107 +00:09:22,300 --> 00:09:26,780 +اللاكتون واللاكتامز المفروض أشياء تكون معروفة عندكم + +108 +00:09:26,780 --> 00:09:31,220 +إذا أنا في السيطة بالـ bond O بدي أكون منتبه أن + +109 +00:09:31,220 --> 00:09:37,660 +التفاعل اللي عندي هل هو تفاعل Addition ولا تفاعل + +110 +00:09:37,660 --> 00:09:43,960 +Substitution الآن لو بدنا ناخد أمثلة على + +111 +00:09:43,960 --> 00:09:48,560 +نيوكليوفايل مختلفة الآن النيوكليوفايل الـ oxygen + +112 +00:09:48,560 --> 00:09:54,140 +النيوكليوفايل عادي عليه أزواج إلكترونات هذا سهل الـ + +113 +00:09:54,140 --> 00:09:59,420 +nitrogen النيوكليوفايل عادي الـ carbon بيكون + +114 +00:09:59,420 --> 00:10:07,990 +النيوكليوفايل ولكن بإيش؟ بمساعدة الجيران ليش؟ لأن + +115 +00:10:07,990 --> 00:10:12,190 +الكربون بوضعه الطبيعي ما عليه أزواج إلكترونات + +116 +00:10:12,190 --> 00:10:16,950 +الكربون بوضعه الطبيعي بيعمل أربع روابط ما عليه + +117 +00:10:16,950 --> 00:10:20,770 +أزواج إلكترونات الأكسجين وضعه الطبيعي في الدنيا + +118 +00:10:20,770 --> 00:10:26,270 +رابطتين وزوجين إلكترونات موجودة فكرة النيوكليوفير + +119 +00:10:26,270 --> 00:10:31,660 +فيها النيتروجين ثلاث روابط وزوج إلكترونات لكن + +120 +00:10:31,660 --> 00:10:36,820 +الكربون أربع روابط إذا الكربون لما بدأ أجي أفكر + +121 +00:10:36,820 --> 00:10:43,620 +فيه وقت ايش بيشتغل in nucleophile بدي أتذكر الـ + +122 +00:10:43,620 --> 00:10:48,240 +activation للـ hydrogen اللي موجودة على الكربون + +123 +00:10:48,240 --> 00:10:56,040 +بحيث أن تفقد كأحماض مر علينا أن جنب السيطة بالـ + +124 +00:10:56,040 --> 00:11:05,650 +bond أو لما بيكون عندكم CH2 هذه بتكون activated CH2 + +125 +00:11:05,650 --> 00:11:13,470 +أو CH3 الآن بيزيد الـ activation لو كانت الـ CH2 كمان + +126 +00:11:13,470 --> 00:11:18,310 +C double bond O واضح؟ زي الـ malonic ester بيصير + +127 +00:11:18,310 --> 00:11:23,270 +سهل أن هذه تفقد H plus وقتها بده يظل عنده carbon + +128 +00:11:23,270 --> 00:11:27,530 +minus صار عنده carbon in nucleophile واضح؟ طبعا + +129 +00:11:27,530 --> 00:11:31,770 +ممكن على C double bond O واحدة تم فقد هيدروجين + +130 +00:11:31,770 --> 00:11:37,250 +بالتأكيد زي تفاعل Aldol اتذكروا Aldol في الـ + +131 +00:11:37,250 --> 00:11:42,030 +Acetaldehyde كان تم من هنا اتفقد الهيدروجين لكن + +132 +00:11:42,030 --> 00:11:49,010 +بكون بدي ايش؟ strong base لكن هنا weaker base بتمشي + +133 +00:11:49,010 --> 00:11:54,110 +قاعدة أضعف بتمشي هنا بكون بدي قاعدة قوية الآن بدل + +134 +00:11:54,110 --> 00:11:57,150 +السيطة البندقية في عندي احتمالات تانية ايش اللي + +135 +00:11:57,150 --> 00:12:04,570 +ممكن يكون عندي؟ سيان يكون عندي سالفر يكون عندي + +136 +00:12:04,570 --> 00:12:11,120 +بنزين في الـ ring يكون عندي halogen كل هذا الكلام + +137 +00:12:11,120 --> 00:12:16,540 +لو إن وجد كمان جنب الـ CH2 بيساعد على أن هاد الـ CH2 + +138 +00:12:16,540 --> 00:12:21,500 +تصير أشمالها activated وبالتالي باستعمال الـ base + +139 +00:12:21,500 --> 00:12:28,240 +بتفقد الـ proton فبصير عندي carbon nucleophile طيب + +140 +00:12:28,240 --> 00:12:33,190 +غير الـ carbon nucleophile نتذكر الـ carbon + +141 +00:12:33,190 --> 00:12:37,690 +nucleophiles مع بعض غير جنب ال C double bond O + +142 +00:12:37,690 --> 00:12:42,890 +وين ال carbon كمان بيكون nucleophile يعني قلنا + +143 +00:12:42,890 --> 00:12:46,690 +جنب ال C double bond O بمساعدة ال C double bond O + +144 +00:12:46,690 --> 00:12:50,590 +ومثلها أحيانا C double bond N ممكن و C double bond + +145 +00:12:50,590 --> 00:12:54,970 +C ممكن الكربون بيشغل ال nucleophile طب غير هذا + +146 +00:12:54,970 --> 00:13:02,170 +الكلام وين بيكون ال Carbon Nucleophile مر علينا + +147 +00:13:02,170 --> 00:13:07,170 +الـ Grignard Reagent احنا قلنا ان ال Grignard R + +148 +00:13:07,170 --> 00:13:14,270 +مع إلكتروناتها بنعتبر ال Grignard MgX العامل + +149 +00:13:14,270 --> 00:13:20,740 +الفعال فيه R مع إلكتروناتها فالـ Grignard reagent + +150 +00:13:20,740 --> 00:13:25,780 +is a carbon-nucleophile طبعا زي الـ Grignard + +151 +00:13:25,780 --> 00:13:29,220 +بتجيني الـ organometallics التانية لو كان ليثيام + +152 +00:13:29,220 --> 00:13:35,460 +المهم مع metal واضح؟ ال carbon مع metals فال + +153 +00:13:35,460 --> 00:13:38,360 +carbon بياخد زوج الإلكترونات و هي بيشتغلوا ال + +154 +00:13:38,360 --> 00:13:42,220 +nucleophile هذا أيضا carbon-nucleophile إيش كمان + +155 +00:13:42,220 --> 00:13:44,800 +مر علينا carbon-nucleophile؟ + +156 +00:13:47,060 --> 00:13:53,380 +الـ Acetylides يعني لو قلنا الـ R C triple bond CH + +157 +00:13:53,380 --> 00:13:58,840 +قلنا احنا ان ال terminal alkynes are acidic يعني + +158 +00:13:58,840 --> 00:14:05,160 +هذا في وجود strong base strong base ما هي ال + +159 +00:14:05,160 --> 00:14:09,460 +lithium ال strong base؟ شو هيفقد؟ ال H بس ال H + +160 +00:14:09,460 --> 00:14:13,500 +لحالها إذا دل عند زوج إلكترونات و ال carbon هنا + +161 +00:14:13,500 --> 00:14:18,670 +صارت إشمالها minus الان كل هذا الكلام اللى أخدناه + +162 +00:14:18,670 --> 00:14:23,090 +في ال organic chemistry بلحظة من اللحظات ممكن يمر + +163 +00:14:23,090 --> 00:14:27,230 +معنا عشان يكوّن carbon اليوكليوفايل يتفاعل على ال + +164 +00:14:27,230 --> 00:14:31,130 +C double bond O و بدنا نكون من ذاكرينه واضح؟ على + +165 +00:14:31,130 --> 00:14:35,070 +سبيل المثال لو اتطلعنا على المركب اللى موجود + +166 +00:14:35,070 --> 00:14:42,870 +أمامنا لاحظوا كام CH2 موجودة فيه هذه واحدة CH2 CH2 + +167 +00:14:42,870 --> 00:14:48,550 +هذه بين C=O و Sulphur إذا هذه Activated ولا لأ + +168 +00:14:48,550 --> 00:14:53,490 +Activated هذه زيها بين C=O و Sulphur إذا + +169 +00:14:53,490 --> 00:14:58,770 +Activated لاحظوا لما أنا بفعل مع Base احنا مختصرين + +170 +00:14:58,770 --> 00:15:03,630 +الكلام أول ما بيصير مع Base كأنه اعمل اتهانة minus + +171 +00:15:03,630 --> 00:15:09,170 +و minusواضح؟ الآن بعد هيك هذي لما بدا تيجي تتفعل و + +172 +00:15:09,170 --> 00:15:13,570 +تعمل رابطة هنا شو هيصير ال او؟ OH OH هنا + +173 +00:15:13,570 --> 00:15:21,380 +H احذفوا ميه OH مع H C=C نفس الكلام على + +174 +00:15:21,380 --> 00:15:26,560 +الجهة التانية OH مع H C=C او الكلام العام + +175 +00:15:26,560 --> 00:15:32,480 +اللى كنا نعرفه زمان انه لو التقى في النهاية H2 و C + +176 +00:15:32,480 --> 00:15:38,300 +Double bond O هي ال H2 مع ال O بيصير C=C + +177 +00:15:38,300 --> 00:15:42,180 +زى لما كنا نفعل C=O مع H2 كيف كنا نكتب + +178 +00:15:42,180 --> 00:15:48,830 +التفاعل كمحصلة هي C=O كيتون او الديهايد + +179 +00:15:48,830 --> 00:15:54,170 +طبعا مع NH2 او RNH2 + +180 +00:15:54,170 --> 00:16:00,790 +عطول نحط C=N طبعا + +181 +00:16:00,790 --> 00:16:06,310 +هذا التفاعل ايش احنا بنسميه + +182 +00:16:06,310 --> 00:16:10,250 +ايوة + +183 +00:16:10,250 --> 00:16:12,190 +قوله صح addition + +184 +00:16:17,960 --> 00:16:22,500 +Elimination تفاعلين في بعض Addition elimination + +185 +00:16:22,500 --> 00:16:25,840 +لأن مش كل مرة بنذكر في ال addition elimination + +186 +00:16:25,840 --> 00:16:31,000 +خلاص شفنا NH2 مع C=O NH2 امين مع + +187 +00:16:31,000 --> 00:16:35,960 +الديهايد او كيتون C=N بس بتكون كتفاعل + +188 +00:16:35,960 --> 00:16:40,000 +تمت من خلال ال ايش ال addition elimination لأن هنا + +189 +00:16:40,000 --> 00:16:45,950 +ال CH2 زيها بالظبط عملة ال addition وعملة ال + +190 +00:16:45,950 --> 00:16:50,270 +elimination بالطريقة + +191 +00:16:50,270 --> 00:16:51,650 +اللى وضحناها لكم + +192 +00:17:00,720 --> 00:17:08,560 +هنا في عندنا مثال تاني هذا المثال التاني بنسمي + +193 +00:17:08,560 --> 00:17:13,540 +احنا بالكنور synthesis of furan تحضير الفيوران + +194 +00:17:13,540 --> 00:17:18,680 +بطريقة يعني هدول علماء بالكنور بنستعمل فيها 1 + +195 +00:17:18,680 --> 00:17:22,520 +,4-dicarbonyl compounds لما انا بدي اجي اقول + +196 +00:17:22,520 --> 00:17:27,750 +واحد اتنين تلاتة اربع يعني ال C=O أو + +197 +00:17:27,750 --> 00:17:31,730 +الـ Dicarbonyl Compounds على أي مواقع نسبية على + +198 +00:17:31,730 --> 00:17:35,830 +واحد وأربعة حتى لو كانوا في الجزء مش على واحد + +199 +00:17:35,830 --> 00:17:39,980 +وأربعة بيسميهم إيش احنا؟ 1,4 يعني افترضت كأني + +200 +00:17:39,980 --> 00:17:45,500 +انا عندي two carbons 1 2 3 4 5 6 + +201 +00:17:45,500 --> 00:17:48,640 +7 8 يعني افترضت ان كل هذه السلسلة تمان + +202 +00:17:48,640 --> 00:17:52,040 +كربونات لكن هذا لما بنسميه .. شو بنقول عنه؟ 1 + +203 +00:17:52,040 --> 00:17:55,200 +,4 1,4-dicarbonyl compounds مانجيش نقول عنه + +204 +00:17:55,200 --> 00:17:59,840 +مثلا 3,7 or whateverواضح الفكرة؟ هذا ال 1 + +205 +00:17:59,840 --> 00:18:03,120 +,4-dicarbonyl compounds الان هذا ال 1,4 + +206 +00:18:03,120 --> 00:18:07,900 +-dicarbonyl compounds بنخليه يسكر ال C= + +207 +00:18:07,900 --> 00:18:12,260 +O على C=O تانيا بنضيف شوية حامض + +208 +00:18:12,260 --> 00:18:15,840 +الحامض عارفين انه بيعمل catalysis لل C= + +209 +00:18:15,840 --> 00:18:20,540 +O بساعدها في الإغلاق الان انتوا حرين تفهموا + +210 +00:18:20,540 --> 00:18:24,910 +ان ال C=C هناالـ Nucleophile هاجمت على الـ + +211 +00:18:24,910 --> 00:18:28,450 +Carbon يعني الـ Bi-bond الـ Nucleophile هاجمت على + +212 +00:18:28,450 --> 00:18:31,850 +الـ Carbon على العين والرأس اللي مش حابة تفهم + +213 +00:18:31,850 --> 00:18:37,290 +هالكلام تتذكر ان هذا كمان انا ممكن ارسمله ايش؟ + +214 +00:18:37,290 --> 00:18:42,270 +Enol Form ممكن ارسمله Enol Form و اتخيل ان هذه الـ + +215 +00:18:42,270 --> 00:18:50,600 +O هاجمت هنا صار عندي OH الان لما بيصير هنا عندي OH + +216 +00:18:50,600 --> 00:18:56,860 +مع H مجاورة بدون يعملوا حذف صار C=C فلو + +217 +00:18:56,860 --> 00:19:00,760 +رسمنا ال Enol form لواحدة منهم خلينها تسكر على C + +218 +00:19:00,760 --> 00:19:03,780 +=C وعملت رابطة + +219 +00:19:05,190 --> 00:19:11,490 +و OH مع H صار عنده الفيوران فبصير احدى طرق تحضير + +220 +00:19:11,490 --> 00:19:15,790 +الفيوران حقيقة بالكنور سينثسيز of furan لو اجينا + +221 +00:19:15,790 --> 00:19:19,670 +نسألكم بالكنور سينثسيز of furan is a substitution + +222 +00:19:19,670 --> 00:19:25,370 +reaction no it is an addition reaction حولنا فيه + +223 +00:19:25,370 --> 00:19:31,460 +صيغة بالبنط O إلى OH هذا هو ال additionواضح؟ this + +224 +00:19:31,460 --> 00:19:37,360 +is an addition reaction هذا تفاعل النيوكليوفايل + +225 +00:19:37,360 --> 00:19:43,800 +اللي موجود فيه الأكسجين والإلكتروفايل الـC= + +226 +00:19:43,800 --> 00:19:51,480 +O الآن ممكن بطريقة بالكنور سينثسيز نحضر ال + +227 +00:19:51,480 --> 00:19:57,680 +pyrrole أيضا من ال 1,4-dicarbonyl compoundsيعني ال 1 + +228 +00:19:57,680 --> 00:20:01,580 +,4-dicarbonyl compounds هين حضرنا منهم أول إيش إيش + +229 +00:20:01,580 --> 00:20:06,020 +الفيوران ممكن نحضر منهم ال pyrrole كيف بدنا نعمل + +230 +00:20:06,020 --> 00:20:10,740 +هذا الكلام بنيجي الفاعل الأمين مع ال 1,4 + +231 +00:20:10,740 --> 00:20:15,060 +-dicarbonyl compounds الآن ع طول ال NH2 مع ال C + +232 +00:20:15,060 --> 00:20:19,780 +=O شو بدهم يعملولي addition followed by + +233 +00:20:19,780 --> 00:20:26,190 +elimination C=NR هذا عبارة عنامين ال C + +234 +00:20:26,190 --> 00:20:31,710 +=N ان امين اخدنا tautomerism اللي هي امين + +235 +00:20:31,710 --> 00:20:36,890 +اينامين اين يعني في عندي الكيل و امين اللي هي N + +236 +00:20:36,890 --> 00:20:42,230 +H عادية فهذا الامين هذا الانامين which is more + +237 +00:20:42,230 --> 00:20:47,130 +stable بشكل عام هذه زي ال keto enol tautomerism + +238 +00:20:47,990 --> 00:20:50,890 +متذكرين كيتو اينو التوتمريزم اللي مش متذاكرة + +239 +00:20:50,890 --> 00:20:54,450 +بيرجعها وكان ال more stable form بالأليفات ال + +240 +00:20:54,450 --> 00:20:59,730 +compounds الكيتون الان برضه في عندي توتمريزم تالي + +241 +00:20:59,730 --> 00:21:01,190 +شبه ال اين + +242 +00:21:03,900 --> 00:21:07,720 +الإمين والإينامين هذا هو الشكل المستقل في شكل + +243 +00:21:07,720 --> 00:21:11,340 +الإينامين فأنا عملت الإيمين وبيعمل توتماريزم + +244 +00:21:11,340 --> 00:21:15,680 +للإينامين الآن هي ال يوكليوفايل عندى هى في عند ال + +245 +00:21:15,680 --> 00:21:18,980 +يوكليوفايل هذا ال يوكليوفايل بيعمل addition ع + +246 +00:21:18,980 --> 00:21:26,000 +السيدة بالبنده O ولا لأ شو هتصفه؟ OH مع H + +247 +00:21:28,540 --> 00:21:33,180 +dehydration بحذف ميه ال OH مع أزواج إلكتروناتها + +248 +00:21:33,180 --> 00:21:36,420 +ما قدش plus يعني كأنه بتكون .. تتخيلوا أن هذه + +249 +00:21:36,420 --> 00:21:45,100 +بتلفها تطرد واضح؟ صار عندي pyrrole صار عندي pyrrole + +250 +00:21:45,100 --> 00:21:51,340 +إذا هي ال 1,4-dicarbonyl compound إيش + +251 +00:21:51,340 --> 00:21:59,200 +حضرنا منه؟ furan وحضرنا منه؟pyrrole الـ A هيمر + +252 +00:21:59,200 --> 00:22:04,240 +معنا مرة تانية أنه ممكن نحضر منه thiophene كمان كيف + +253 +00:22:04,240 --> 00:22:08,620 +ممكن نحضر منه thiophene أنه احنا في البداية بنعمل + +254 +00:22:08,620 --> 00:22:13,080 +تفاعل له مع ال sulfur يعني بنخلي هذا تصير sulfur و + +255 +00:22:13,080 --> 00:22:17,520 +زي ما سكرنا في حالة ال oxygen بنسكر في حالة ال + +256 +00:22:17,520 --> 00:22:17,860 +sulfur + +257 +00:22:20,650 --> 00:22:24,330 +سهل أن نحوّل C=O إلى C=S + +258 +00:22:24,330 --> 00:22:30,990 +باستعمال Reagents زي الـ B2S5، Diphosphorus + +259 +00:22:30,990 --> 00:22:34,710 +Pentasulfide أو في Reagent تاني اسمه Lawesson's + +260 +00:22:34,710 --> 00:22:40,010 +Reagent Lawesson's Reagent هذا Reagent مختصر حوّل + +261 +00:22:40,010 --> 00:22:45,170 +الـ C=O إلى C=S + +262 +00:22:47,740 --> 00:22:54,520 +Lawesson's reagent ممكن تشوفوه في الموسوعات او ما + +263 +00:22:54,520 --> 00:22:58,060 +إلى ذلك عبارة عن aromatic compounds في كذا sulfur + +264 +00:22:58,060 --> 00:23:03,300 +لو فعلناه وضيفته باختصار انه يحول C=O + +265 +00:23:03,300 --> 00:23:07,900 +الى C=S فإذا قرأته قال اه يعني this is + +266 +00:23:07,900 --> 00:23:10,140 +Lawesson's reagent + +267 +00:23:13,410 --> 00:23:16,830 +واضح؟ إذا لاحظوا هاي ال 1,4-dicarbonyl + +268 +00:23:16,830 --> 00:23:20,410 +compounds للناس اللي بيحبوا الامتحانات بيصير سؤال + +269 +00:23:20,410 --> 00:23:22,690 +typical لإنه نقولهم والله من 1,4- + +270 +00:23:22,690 --> 00:23:27,090 +dicarbonyl compounds حضرولنا if you run with pyrrole, + +271 +00:23:27,310 --> 00:23:28,210 +if you run with pyrrole, if you run with pyrrole, if you run + +272 +00:23:28,210 --> 00:23:28,230 +with pyrrole, if you run with pyrrole, if you run with pyrrole, + +273 +00:23:28,230 --> 00:23:28,290 +if you run with pyrrole, if you run with pyrrole, if you run + +274 +00:23:28,290 --> 00:23:31,730 +with pyrrole, if you run with pyrrole, if you run with pyrrole, + +275 +00:23:31,810 --> 00:23:33,410 +if you run with pyrrole, if you run with pyrrole, if you run + +276 +00:23:33,410 --> 00:23:34,030 +with pyrrole, if you run with pyrrole, if you run + +277 +00:23:34,030 --> 00:23:38,310 +with pyrrole, if you run with pyrrole, هي مثال إضافي على + +278 +00:23:38,310 --> 00:23:41,910 +ال pyrrole هو نفس المثال السابق أنه جيبنا احنا + +279 +00:23:41,910 --> 00:23:45,450 +امين مع واحدة من ال C=O's يعني كأنه + +280 +00:23:45,450 --> 00:23:51,250 +هنا صار an R امين in amine وخلوها تسكر هنا نفس + +281 +00:23:51,250 --> 00:23:57,910 +المثال السابق تماما لكن صار الـ by role ضمن حلقة + +282 +00:23:57,910 --> 00:23:59,930 +أكبر + +283 +00:24:06,170 --> 00:24:12,310 +أيضا من التفاعلات الإضافية على هذا الموضوع اللي هي + +284 +00:24:12,310 --> 00:24:18,070 +التفاعل على الـ CH3O Synthesis of Indole الآن هنا + +285 +00:24:18,070 --> 00:24:23,310 +بيجوا بيشتغلوا على الـ CH3 هل يا ترى هذه الـ CH3 + +286 +00:24:23,310 --> 00:24:35,490 +اكتفيت ولا لأ تنسوا أنتم أنه احنا قلنا CH3 CH3 + +287 +00:24:38,030 --> 00:24:43,750 +Jump C=O اكتفيت ولا لأ الآن الـ C + +288 +00:24:43,750 --> 00:24:46,930 +=O أو C=C نفس الفكرة + +289 +00:24:46,930 --> 00:24:52,610 +بيعملوا من ناحية إلكترونية واضح؟ يعني هذه CH3 في + +290 +00:24:52,610 --> 00:25:00,070 +النهاية جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +291 +00:25:00,070 --> 00:25:00,690 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +292 +00:25:00,690 --> 00:25:01,850 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +293 +00:25:01,850 --> 00:25:01,890 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +294 +00:25:01,890 --> 00:25:01,930 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +295 +00:25:01,930 --> 00:25:17,550 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +296 +00:25:17,550 --> 00:25:24,370 +جام CH لاحظوا كم شغل استعملناه strong base و heat + +297 +00:25:24,370 --> 00:25:30,810 +في النهاية خليناها دي CH2- و خليناها تضيف على C + +298 +00:25:30,810 --> 00:25:34,110 +=O و ما تعملش هنا المركب لأنه جنب + +299 +00:25:34,110 --> 00:25:39,230 +aromatic كامد حتى يعني بمعنى لما يضيف هنا حيصير + +300 +00:25:39,230 --> 00:25:46,610 +عنده OH و جنبها NH و جنبها هنا CH في كل الأحوال + +301 +00:25:46,610 --> 00:25:54,210 +الحقيقية في OH مع H هيطلع عنده الـ Indole هذا عبارة + +302 +00:25:54,210 --> 00:26:00,810 +عن تفاعل carbon nucleophile مع C=O + +303 +00:26:00,810 --> 00:26:04,930 +المثال + +304 +00:26:04,930 --> 00:26:12,490 +اللي هنا مثال جميل Nitro وع طول كلكم بتتذكروا كيمياء + +305 +00:26:12,490 --> 00:26:16,130 +البنزين والانيلين الـ Nitro بال reduction هو + +306 +00:26:16,130 --> 00:26:22,490 +الانيلين احنا كيف بنحضره reduction of Nitro بنزين + +307 +00:26:22,490 --> 00:26:26,150 +بناء على ذلك لو أنا أخدت الـ Nitro compound هذا بال + +308 +00:26:26,150 --> 00:26:30,890 +reduction شو حيصير عندي؟ الـ NH2 عبارة عن الـ + +309 +00:26:30,890 --> 00:26:36,430 +nucleophile وين بدو يهاجم؟ على الـ C=O + +310 +00:26:36,430 --> 00:26:46,300 +بهذا الشكل صارتو اتش و اتش مع اتش بيعمل + +311 +00:26:46,300 --> 00:26:51,940 += و بيسكر صار أيضا عندنا اندول هم لاحظين + +312 +00:26:51,940 --> 00:26:57,560 +كيف بنصل لمركب بطرق مختلفة لكن بنفس الفكرة يعني + +313 +00:26:57,560 --> 00:27:01,220 +الاندول بهذه الطريقة و من هذا المركب و من هذا + +314 +00:27:01,220 --> 00:27:08,340 +المركب طبعا مختلفين في إش موجود عندهم في الـ R والـ + +315 +00:27:08,340 --> 00:27:16,270 +R واضح؟ يمكن هنا خليني أروح لفكرة أساسية كثيرا في الـ + +316 +00:27:16,270 --> 00:27:20,430 +heterocycle chemistry أنه ليش أنا جاعد كل مرة بأحضّر + +317 +00:27:20,430 --> 00:27:25,010 +الـ endol بطريقة معينة أو لما بدي أجي آخذ الفيوران + +318 +00:27:25,010 --> 00:27:29,870 +بدي أحضر .. آخذ لي عشر .. عشر أو خمستاشر synthesis + +319 +00:27:29,870 --> 00:27:35,540 +of الفيوران الكيمياء الحلقية .. الكيمياء الحلقية + +320 +00:27:35,540 --> 00:27:42,300 +بتختلف عن كيمياء البنزين اختلاف أساسي وجوهري جدا + +321 +00:27:42,300 --> 00:27:49,200 +كيمياء البنزين مبناها ككيمياء مبنية على أن في عند + +322 +00:27:49,200 --> 00:27:57,640 +حلقة البنزين موجودة تمام؟ وإيش أنا لازمني على حلقة + +323 +00:27:57,640 --> 00:28:04,900 +البنزين أبدأ من بنزين وبصير أضيف أول substituent + +324 +00:28:04,900 --> 00:28:08,600 +وثاني substituent وبأخذ الأفكار اللي تعلمتها + +325 +00:28:08,600 --> 00:28:11,160 +activating groups و deactivating groups و + +326 +00:28:11,160 --> 00:28:14,020 +orthopara directing groups و metadirecting groups + +327 +00:28:14,020 --> 00:28:19,580 +لكن منطلقي لتحضير الـ substituted بنزين يعني لو بدي + +328 +00:28:19,580 --> 00:28:29,330 +مركب زي هذا مثلا CH3 NO2 هذا من أين أنا بأحضره من + +329 +00:28:29,330 --> 00:28:33,950 +البنزين أبدأ البنزين الكيلةشن المثل بتودي + +330 +00:28:33,950 --> 00:28:38,590 +أورثوبارا وبعدين نيتريشن منطلقي الحلقة اللي زيه + +331 +00:28:38,590 --> 00:28:43,910 +الآن الـ heterocyclic chemistry لا تنطلق من الحلقات + +332 +00:28:45,030 --> 00:28:49,890 +طبعا يعني اللي بده في الـ heterocyclic chemistry + +333 +00:28:49,890 --> 00:28:57,030 +substituted فيوران على سبيل المثال ربما نادر جدا + +334 +00:28:57,030 --> 00:29:01,410 +نفترض هنا عند مجموعة X أو Y أن يكون التفكير اللي + +335 +00:29:01,410 --> 00:29:05,810 +عنده التفكير اللي عنده أن أبدأ بـ فيوران وأحط + +336 +00:29:05,810 --> 00:29:11,800 +المجموعات اللي بدك إياها هنا التفكير اللي عنده أن + +337 +00:29:11,800 --> 00:29:19,000 +هذا الفيوران كيف بتحضّر أصلا بأحط المجموعات عليه من + +338 +00:29:19,000 --> 00:29:24,700 +قبل التحضير من قبل عملية إغلاق يعني لو كنت أوضح + +339 +00:29:24,700 --> 00:29:30,060 +أنا أرجع للمثال اللي هنا لاحظوا بهذا المثال كم + +340 +00:29:30,060 --> 00:29:35,940 +مجموعة أنا عندي على الفيوران أربع مجموعات ولا أحد في + +341 +00:29:35,940 --> 00:29:40,180 +الدنيا بيفكر أنه لما بده يحضر هذا المركب .. لما + +342 +00:29:40,180 --> 00:29:46,260 +يحضر هذا المركب أنه يجيب فيوران ويبعث باقي + +343 +00:29:46,260 --> 00:29:50,160 +نضيف المجموعة كذا كذا كذا كل المجموعات اللي بدي + +344 +00:29:50,160 --> 00:29:56,840 +إياها بأضيفها قبل عملية إيش الإغلاق بأجيب مركب فيه C + +345 +00:29:56,840 --> 00:30:00,220 +=O جبت و الـ R هذه و أنا C=O + +346 +00:30:00,220 --> 00:30:02,700 +جبت هذا الـ R وهذا الـ R بكون عامله وهذا عامله + +347 +00:30:02,700 --> 00:30:07,820 +بالكيمياء العادية وبعدين بسكر فالـ substituents في + +348 +00:30:07,820 --> 00:30:13,580 +الـ heterocyclic compounds بتلحط قبل الإغلاق في الـ + +349 +00:30:13,580 --> 00:30:19,080 +aromatic compounds بتنحط غالبا بعد الإغلاق يعني + +350 +00:30:19,080 --> 00:30:23,700 +منطلقنا هناك البنزين بس احنا هنا ما بننطلق من حلقة + +351 +00:30:23,700 --> 00:30:27,580 +نقول الـ parent ونصير نحضر منها وعشان هيك الـ + +352 +00:30:27,580 --> 00:30:31,760 +heterocyclic synthesis مختلفة بفكرته عن أن الواحد + +353 +00:30:31,760 --> 00:30:37,050 +يكون بأحضّر aromatic compounds اللي بده شغلة بأحط + +354 +00:30:37,050 --> 00:30:41,930 +الأشياء وين؟ على القطع اللي بده يعمل عليها الإغلاق + +355 +00:30:41,930 --> 00:30:46,190 +بأحط الأشياء اللي لازمها على القطع الأصلية اللي بده + +356 +00:30:46,190 --> 00:30:50,410 +يعمل لها cyclization مش بيحضّر حلقة أو بيروح بيشتري + +357 +00:30:50,410 --> 00:30:53,570 +payroll أو furan وبعدين بيقول بده أعمل عليه تفاعل + +358 +00:30:53,570 --> 00:30:58,830 +هذا الكلام في الـ heterocyclic compounds قليل جدا + +359 +00:30:58,830 --> 00:31:06,460 +واضح الفكرة؟ يعني هاي مثلا الدول عليه substituents + +360 +00:31:06,460 --> 00:31:11,880 +معينة بدنا نحطها من البداية وبعدين نعمل الـ + +361 +00:31:11,880 --> 00:31:18,670 +cycleization اللي موجود عندنا نشوف مركبات جديدة مثلا + +362 +00:31:18,670 --> 00:31:24,650 +بنزو فيوران نشوف مركبات بنزو فيوران هاي الـ بنزو + +363 +00:31:24,650 --> 00:31:31,390 +فيوران هذا اللي موجود عندنا عليه two substituents + +364 +00:31:31,390 --> 00:31:36,010 +هنا يعني لو افترضنا أن هذا الـ R مثل خليني أحط + +365 +00:31:36,010 --> 00:31:41,570 +فرضيا أن هذا الـ R CH3 وهذا الـ R C=O + +366 +00:31:41,570 --> 00:31:43,630 +خليني أقول إيثل + +367 +00:31:48,440 --> 00:31:56,400 +واضح؟ ما بأفكرش أنا أن هذا المركب أجي أحضره من + +368 +00:31:56,400 --> 00:32:00,820 +بنزوفيوران وبعدين أقول كيف بده أحط الـ CH3 وكيف + +369 +00:32:00,820 --> 00:32:08,650 +بده أحط الـ CO2 .. الـ C=O إيثل واضح؟ لأ + +370 +00:32:08,650 --> 00:32:13,630 +بأجي من نقطة البداية لما بأصمم الـ synthesis بأحطها + +371 +00:32:13,630 --> 00:32:17,970 +دول الأشياء الآن لو بدأت بفينول هذا المركب عبارة + +372 +00:32:17,970 --> 00:32:23,110 +عن إيش؟ فينول والفينول عليه C=O R + +373 +00:32:23,110 --> 00:32:29,970 +وجدت لما أنا بأحطها بأخليها تكون C=O CH3 + +374 +00:32:29,970 --> 00:32:37,050 +صار عندي سؤال أن كيف تحضّر هذا المركب أنت؟ واضح؟ + +375 +00:32:37,050 --> 00:32:41,750 +يعني بيصير سؤالي كـ organ الـ chemistry أنه أنا هذا + +376 +00:32:41,750 --> 00:32:47,370 +المركب لازمني وجدت هذا لأنه مشتقة بنزين، بترجع + +377 +00:32:47,370 --> 00:32:51,770 +لكيمياء البنزين، كيف ممكن نحضّر هذا المركب؟ طبعا + +378 +00:32:51,770 --> 00:32:56,530 +هتتذكروا أن الـ acidity group بنقدر نحطها، لكن الـ + +379 +00:32:56,530 --> 00:33:02,500 +OHعادة لما بنحطها بنعمل نيترو والنيترو بنحوله + +380 +00:33:02,500 --> 00:33:07,060 +لانيلين والانيلين لديازونيوم سولت والديازونيوم + +381 +00:33:07,060 --> 00:33:12,360 +سولت مع H+ نخليه فينول الآن الفينول أورثو بارا + +382 +00:33:12,360 --> 00:33:16,080 +directing group مثلا أو الامين أورثو بارا + +383 +00:33:16,080 --> 00:33:20,460 +directing group له واضح الفكرة كيف؟ اه الآن هذا + +384 +00:33:20,460 --> 00:33:26,330 +الكلام أعمله وحطينا CH3N أبني جهانا فعّال هذا الجزء + +385 +00:33:26,330 --> 00:33:32,790 +مع PR CH2 C=OR يعني هذه عبارة عن إيش C + +386 +00:33:32,790 --> 00:33:38,550 +=OR ثانية الآن لو أنا بدي هذه إيثل من + +387 +00:33:38,550 --> 00:33:43,670 +البداية بأحطها إيثل لو بديها مثل من البداية بأحطها + +388 +00:33:43,670 --> 00:33:53,890 +مثل يعني أنا حطيت إيش الآن لاحظوا لدي CH2 حاملة بار + +389 +00:33:53,890 --> 00:34:00,410 +و OH هذا عبارة عن النوكليوفيل مار علي لو خلطته مع + +390 +00:34:00,410 --> 00:34:05,590 +بعض الـ substitution أسألتوا + +391 +00:34:05,590 --> 00:34:10,130 +substitution غالبا لأن هذه primary صار عندكم O + +392 +00:34:14,140 --> 00:34:21,140 +CH2C=O إيثل الآن لما أستعمل الـ base CH2 + +393 +00:34:21,140 --> 00:34:23,860 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +394 +00:34:23,860 --> 00:34:36,740 +CH2 CH2 + +395 +00:34:41,310 --> 00:34:46,530 +Elimination طلع المركب اللي عنده شفتوا كيف نظام + +396 +00:34:46,530 --> 00:34:49,590 +الـ synthesis في الـ heterocyclic chemistry أن + +397 +00:34:49,590 --> 00:34:55,450 +المجموعات اللي بتديها على الناتج أبدأ من البداية + +398 +00:34:55,450 --> 00:35:02,110 +أخليها تكون موجودة عنده واضح؟ من البداية أبدأ + +399 +00:35:02,110 --> 00:35:05,890 +أخليها تكون موجودة عنده يعني لو مثلا افترضنا أن + +400 +00:35:05,890 --> 00:35:12,420 +طالبة في الأساس مهتمة أن هذه المجموعة تكون إيثل أول + +401 +00:35:12,420 --> 00:35:15,840 +ما بدها تحضّر هنا بدل ما تجيب الـ reagent اللي + +402 +00:35:15,840 --> 00:35:26,600 +يتفاعل هنا يكون CH3 OCl CH3 هتجيب CH3 OCl إيثل + +403 +00:35:30,990 --> 00:35:35,170 +فالـ مجموعات عادة بنحطها من الأول إنما مافي عندنا في + +404 +00:35:35,170 --> 00:35:39,190 +الـ heterocyclic chemistry أن أقول بأحضّر الحلقة نقية + +405 +00:35:39,190 --> 00:35:42,570 +أو بأشتريها شراية وبعدين أعمل عليها substitution + +406 +00:35:42,570 --> 00:35:49,590 +فهذا مبدأ عام عندنا في موضوع الـ heterocyclic + +407 +00:35:49,590 --> 00:35:56,430 +synthesis وخذ الأمثلة الآن + +408 +00:35:56,430 --> 00:36:02,740 +نجي لهذا المركب أيزوكزازول وهذا أيزوكزازول عليه + +409 +00:36:02,740 --> 00:36:08,360 +مجموعتين R لاحظوا كيف التحضير تبعه لو أخذنا احنا + +410 +00:36:08,360 --> 00:36:11,680 +one three-dicarbonyl compound + +411 +00:36:15,050 --> 00:36:21,750 +يعني هي كربون واحد اثنين ثلاثة كأننا بنقول أن هذه + +412 +00:36:21,750 --> 00:36:26,850 +C=O وهذه C=O هي واحد + +413 +00:36:26,850 --> 00:36:31,750 +اثنين ثلاثة إذا هذا one three-dicarbonyl compound + +414 +00:36:31,750 --> 00:36:38,470 +ولا لأ طيب لو فعلته مع أن H2OH هيدروكسلامين مع + +415 +00:36:38,470 --> 00:36:42,290 +كيتون إيش بيعطيني على طول أكزين + +416 +00:36:44,870 --> 00:36:48,390 +Hydroxylamine مع كيتون خليه يتفاعل على هذا الـ C + +417 +00:36:48,390 --> 00:36:53,570 +=O هتصير C=N O H This is N + +418 +00:36:53,570 --> 00:36:59,910 +أكزيم وهذه C=O موجودة هنا الآن هذه الـ + +419 +00:36:59,910 --> 00:37:09,010 +on-eucleophile ممكن تتسكر هنا وتعمل عنده؟ OH مع H + +420 +00:37:09,010 --> 00:37:16,170 +elimination إيش صار عندك؟ isoxazole لاحظوا طبعا هذا + +421 +00:37:16,170 --> 00:37:23,310 +الكلام لناس بدهم يتخيلوا أنهم بدهم يتعبوا شوية + +422 +00:37:23,310 --> 00:37:27,950 +بيصير جزء من التفكير اللي عندهم يا ترى لو إجا و + +423 +00:37:27,950 --> 00:37:32,390 +سألني how can you prepare this compound؟ بدكم + +424 +00:37:32,390 --> 00:37:37,590 +تُبْدُوا في الـ ايش الـ disconnection approach لو قلت لكم + +425 +00:37:37,590 --> 00:37:42,090 +كيف ممكن تحضر هذا المركب بدكم تبدوا في الـ + +426 +00:37:42,090 --> 00:37:44,690 +disconnection approach الآن في الـ disconnection + +427 +00:37:44,690 --> 00:37:49,370 +approach بدءوا يبدأ يصير معروف عندكم أنه أول قطع + +428 +00:37:49,370 --> 00:37:52,430 +ممكن تعملوا من هنا و ترجعوا هذه إلى C double bond + +429 +00:37:52,430 --> 00:37:58,810 +O and + +430 +00:37:58,810 --> 00:38:06,600 +O H هذا القطع الأول دائماً Giving you كل يو فاي + +431 +00:38:06,600 --> 00:38:12,280 +بإمكانكم تعملوا قطع و ترجعوا هذه إلى C double + +432 +00:38:12,280 --> 00:38:16,120 +bond O يعني كأن هذه كانت OH OH الـ OH كانت C double + +433 +00:38:16,120 --> 00:38:19,720 +bond O بعد هيك ممكن تعملوا القطع الثاني + +434 +00:38:22,880 --> 00:38:26,920 +واضح؟ فمعظم هذه الأمثلة اللي موجودة بإمكانكم + +435 +00:38:26,920 --> 00:38:31,280 +أنتوا تعملوا تدريب عليها أنه لو اجت اه ما احنا + +436 +00:38:31,280 --> 00:38:36,760 +عارفين أنه كل C double bond N شو كان أساسها؟ C + +437 +00:38:36,760 --> 00:38:42,220 +double bond O and H2 هذه الـ O اللي جنب C double + +438 +00:38:42,220 --> 00:38:48,160 +bond C أو بشكل عام عشان أساعدكم للمستقبل وين + +439 +00:38:48,160 --> 00:38:52,480 +بتشوفوا؟ وين بتشوفوا في الـ disconnection approach؟ + +440 +00:38:52,480 --> 00:38:58,620 +C double bond C و جنب هاليوكليوفايل ما تبقى بره + +441 +00:38:58,620 --> 00:39:03,980 +بيقول لكم كيف هذا اتحضر Carbohydrate بدكم؟ على طول + +442 +00:39:03,980 --> 00:39:07,380 +يكون التفكير تبعكم أن هذا + +443 +00:39:10,460 --> 00:39:16,720 +كان C double bond O وهنا كان نيوكليوفايل + +444 +00:39:16,720 --> 00:39:23,580 +عارفين و هذا سهل معناه الـ Retrosynthesis فتطلعوا + +445 +00:39:23,580 --> 00:39:28,420 +على هذه الفكرة الجيدة يعني هذا الجزء من الجزء .. + +446 +00:39:28,420 --> 00:39:33,620 +هذا الجزء من الجزء احفظوه أن الـ C double bond C + +447 +00:39:33,620 --> 00:39:38,620 +اللي جنبها نيوكليوفايل بقدر أنا أقول أن حصلها C + +448 +00:39:38,620 --> 00:39:43,620 +double bond O نيوكليوفايل بهذا الشكل واضحة هذه + +449 +00:39:43,620 --> 00:39:44,260 +الفكرة؟ + +450 +00:39:54,240 --> 00:40:00,560 +بجينا Cyclization جديد هذا الـ Cyclization بنقوله + +451 +00:40:00,560 --> 00:40:04,320 +cyclization onto an ortho position of a بنزين ring + +452 +00:40:04,320 --> 00:40:11,520 +الإغلاق على موقع أورثو من حلقة البنزين وهذا النوع + +453 +00:40:11,520 --> 00:40:16,110 +من الـ cyclization بيعطينا fused rings يعني كثير جداً + +454 +00:40:16,110 --> 00:40:21,850 +لما بتشوفوا الـ fused rings أول ما تفكروا فيهم + +455 +00:40:21,850 --> 00:40:26,650 +فكروا بهذا الـ cyclization اللي هو الـ cyclization + +456 +00:40:26,650 --> 00:40:33,470 +على موقع Ortho الآن ايش قصة موقع Ortho هذا ببساطة + +457 +00:40:33,470 --> 00:40:36,850 +الـ ortho position يعني لو هي .. هي أنا عندي إبدال + +458 +00:40:36,850 --> 00:40:40,490 +من هذه النقطة وين موقع Ortho الـ ortho position + +459 +00:40:40,490 --> 00:40:46,320 +بتكون اعتبروه أن هو الـ nucleophileالأورثو بوزيشن + +460 +00:40:46,320 --> 00:40:53,820 +أكتس از اليوكليوفايل الأورثو بوزيشن أكتس از + +461 +00:40:53,820 --> 00:40:57,840 +اليوكليوفايل واضح هذا الفكرة يعني لما آجي أنا + +462 +00:40:57,840 --> 00:41:03,520 +أتخيل هذا الجزيء أن هذا الـ intermediate هي موضوعي + +463 +00:41:03,520 --> 00:41:07,480 +لكن خلينا نشوف كيف اتكونت اتكونت من أنيلين هي + +464 +00:41:07,480 --> 00:41:16,140 +الأنيلين شايفينه؟ فين السكرته على 1,3-dicarbonyl + +465 +00:41:16,140 --> 00:41:20,800 +compounds R,CWBond O,CH2,CWBond OR يعني الـCWBond + +466 +00:41:20,800 --> 00:41:25,860 +O اللي هنا مع الـNH2 عملت ليه؟ CWBond N هذه خطوة + +467 +00:41:25,860 --> 00:41:30,520 +تحضيرية مش خطوة إغلاق حلقة هذه كيلية عادية CWBond + +468 +00:41:30,520 --> 00:41:35,480 +O مع NH2 أصل هذه الآن اللي بهمني أنا في + +469 +00:41:35,480 --> 00:41:37,640 +الـcyclization اللي هي + +470 +00:41:41,310 --> 00:41:46,970 +هذه الآن هنا بإمكانكم تفهموا الموضوع أن هذه الـ + +471 +00:41:46,970 --> 00:41:51,990 +double bond بإمكانها تيجي تهاجم هنا وتعمل addition + +472 +00:41:51,990 --> 00:41:56,050 +أو H تعمل addition بعد هي بتفقد الـ H اللي هنا + +473 +00:41:56,050 --> 00:42:03,790 +بترجع هذه واضحة الفكرة يعني هذه الـ double bond + +474 +00:42:03,790 --> 00:42:08,690 +بإمكانها تعمل addition الـ H هذه سهلة تفقد بتفقد + +475 +00:42:09,410 --> 00:42:13,850 +وبرجع البنزين للغرض التطبيق ما تنش يا كم ضايعوا مخكم + +476 +00:42:13,850 --> 00:42:17,950 +ووجدكم في ايش؟ في أنكم تتخيلوا أسهم على طول بدكم + +477 +00:42:17,950 --> 00:42:22,130 +تحطوا الجواب أن هذا الـ orthoposition هذا الـ + +478 +00:42:22,130 --> 00:42:25,550 +orthoposition اللي زي هيك هذه الـ double .. هذه الـ + +479 +00:42:25,550 --> 00:42:28,930 +bond اللي هنا مع الـ H وأنتم غاضبين وين بدكم + +480 +00:42:28,930 --> 00:42:35,910 +تنجلوها بدل ما هي هيك بدون ما نقعد نتعب حالنا هيك + +481 +00:42:35,910 --> 00:42:37,750 +و الـ .. و هذه ايش صارت + +482 +00:42:41,270 --> 00:42:44,470 +يعني تخيلوا ببساطة كأنه الـ double .. كأنه الـ + +483 +00:42:44,470 --> 00:42:48,670 +single bond اللي مع الـ H حطيناها هنا وجيبنا الـ + +484 +00:42:48,670 --> 00:42:53,870 +action هذه محصلة التفاؤد هاي بتتم عملية ايش؟ الـ + +485 +00:42:53,870 --> 00:42:59,190 +cyclization طبعاً بعد هيك OH مع H شو بيعملوا عندهم + +486 +00:42:59,190 --> 00:43:06,810 +double bond هذا المثال نفس الشيء بس بدنا فيه بدل + +487 +00:43:06,810 --> 00:43:12,280 +aniline فيلون انتبهوا بقى كيف أنا نفس الفكرة كيف + +488 +00:43:12,280 --> 00:43:18,540 +بصمم التحضير بنفس الفكرة يعني هنا فين الـ N H2 و + +489 +00:43:18,540 --> 00:43:25,160 +هنا فين الـ O H الآن هذا الـ O H روح اتحطته مع R C O + +490 +00:43:25,160 --> 00:43:32,360 +C H C L لحظة الـ O H وين بتروح بتسكل بتطرد الـ C L + +491 +00:43:32,360 --> 00:43:38,030 +الـ substitution الـ Eucleophilic Substitution هاي + +492 +00:43:38,030 --> 00:43:42,930 +صار عندكم CHR اللي هي موجودة هنا و C double bond O + +493 +00:43:42,930 --> 00:43:48,210 +هاي الـ orthoposition الرابط اللي هنا وين بده تصير؟ + +494 +00:43:48,210 --> 00:43:53,170 +صارت هنا، هاذي؟ + +495 +00:43:53,170 --> 00:44:04,070 +OH OH واضحة؟ الـ OH و الـ H عملوا إغلاق على + +496 +00:44:04,070 --> 00:44:09,780 +أي حال؟ أفهمنا إذا الـ cyclization على الـ + +497 +00:44:09,780 --> 00:44:15,060 +orthoposition في عندي أنا أنثى إضافية كلها في الـ + +498 +00:44:15,060 --> 00:44:18,900 +cyclization على الـ orthoposition لكن اللي بيصير + +499 +00:44:18,900 --> 00:44:25,060 +أنه شوية بالفصل عندكم المثال يعني هذه الـ NH2 اللي + +500 +00:44:25,060 --> 00:44:29,160 +هتحل محل الـ PR وبعدين هذا الـ cyclization سهل ولا + +501 +00:44:29,160 --> 00:44:36,070 +لأ؟ سهل هذه الآن H2 أن تعمل إبدال للـ CL لأن هذا + +502 +00:44:36,070 --> 00:44:41,350 +acid chloride وبعدين هذا الـ orthoposition يسكر + +503 +00:44:41,350 --> 00:44:48,150 +هنا سهل أمثلة كثير جداً وعشان هيك جزء من الـ + +504 +00:44:48,150 --> 00:44:52,490 +homework اللي هتجيبه هذه الأمثلة الحقيقة من مجالات + +505 +00:44:52,490 --> 00:44:56,290 +يعني اعتبروا أن أنا كمان جيبت homework هذه من مجلة + +506 +00:44:56,290 --> 00:44:59,970 +مثلاً اسمها journal of chemical research في النهاية + +507 +00:44:59,970 --> 00:45:05,930 +بيعمل عدة تفاعلات ممكن نناقش هذه الأمثلة في المرة + +508 +00:45:05,930 --> 00:45:11,880 +الجاية لكن كل محورها ايش؟ cyclization على الـ + +509 +00:45:11,880 --> 00:45:17,460 +orthoposition وبهيك بننهي الجزء تبعنا ومر علينا + +510 +00:45:17,460 --> 00:45:21,920 +أنفلة منوعة من الـ cyclization على الـ C double bond + +511 +00:45:21,920 --> 00:45:27,160 +O بما في ذلك أن الـ orthoposition يكون بيشتغل كـnucleophile +512 +00:45:27,160 --> 00:45:27,880 +as a nucleophile diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bXzOV3H6R70_postprocess.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bXzOV3H6R70_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..66a627583aaaeddb4a9f0905d599188b1fbb1bb8 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bXzOV3H6R70_postprocess.srt @@ -0,0 +1,2048 @@ +1 +00:00:20,890 --> 00:00:25,550 +بسم الله الرحمن الرحيم اليوم بنبدأ معكوا في موضوع + +2 +00:00:25,550 --> 00:00:29,330 +جديد في مجال تحضير ال heterocyclic rings و احنا + +3 +00:00:29,330 --> 00:00:35,410 +اتفقنا سابقا انه بدنا نشرح طرق عامة لتحضير ال + +4 +00:00:35,410 --> 00:00:40,730 +heterocyclic rings من خلال انحضر حلقات مختلفة + +5 +00:00:40,730 --> 00:00:45,610 +مانركزش على حلقة واحدة لأ نركز على طريقةأول ما + +6 +00:00:45,610 --> 00:00:52,350 +اتكلمنا اتكلمنا على تفاعل الإبدال على ذرة كربون + +7 +00:00:52,350 --> 00:00:56,510 +بتحمل أربع روابط زي ما سمناها tetragonal carbon و + +8 +00:00:56,510 --> 00:01:04,360 +ربما اتذكروا انه احنا استعانا بقواعدBaldwin فلما + +9 +00:01:04,360 --> 00:01:10,800 +كنا بنعمل إبدال على tetragonal carbon كنا بنشيل + +10 +00:01:10,800 --> 00:01:16,220 +مجموعة مرتبطة برابط واحدة ولذلك ماكنش هنا في عندنا + +11 +00:01:16,220 --> 00:01:20,040 +احتمال الا ان ال cyclization يكون ايش + +12 +00:01:20,040 --> 00:01:25,100 +exocyclization يعني مافيش امكانية ان يكون عندى في + +13 +00:01:25,100 --> 00:01:30,080 +ال tetragonal cyclization endocyclizationبس طالما + +14 +00:01:30,080 --> 00:01:34,180 +انها رابطة بدأت تتحرك اذا هي فقط هتتحرك للخارج و + +15 +00:01:34,180 --> 00:01:39,020 +يتم ال cyclization اخدنا امثلة كتير الان لما نيجي + +16 +00:01:39,020 --> 00:01:45,280 +نشتغل على ال diagonal atoms او carbons في عندنا + +17 +00:01:45,280 --> 00:01:48,700 +double bond الان لما يصير في عندنا double bond + +18 +00:01:48,700 --> 00:01:53,940 +بيصير في عندنا إمكانيةلنوعين من الـ cyclization لـ + +19 +00:01:53,940 --> 00:01:56,940 +exocyclization يعني واحدة من ال double bonds خلينا + +20 +00:01:56,940 --> 00:01:59,800 +نقول هذا ال by bond تتحرك للخارج this is + +21 +00:01:59,800 --> 00:02:03,540 +exocyclization وهذه بتكون الحقيقة عملية addition + +22 +00:02:03,540 --> 00:02:09,640 +او ان ال double bond تتحرك بداخل الحلقة يعني هذه + +23 +00:02:09,640 --> 00:02:15,120 +وبالتالي بيكون عندنا endocyclization ففي حالةما + +24 +00:02:15,120 --> 00:02:19,300 +بنحكي عن ال double bonds بصير في عنا احتمالين من + +25 +00:02:19,300 --> 00:02:22,360 +ناحية المبدأ في البداية انه في احتمال ال + +26 +00:02:22,360 --> 00:02:27,880 +exocyclization في احتمال ال endocyclization هذا + +27 +00:02:27,880 --> 00:02:31,300 +اذا اتكلمنا عن ال double bonds بشكل عام + +28 +00:02:44,980 --> 00:02:49,500 +الـ C double bond O الـ C double bond N الـ C + +29 +00:02:49,500 --> 00:02:55,020 +double bond S وربما الـ C double bond C لو أنا + +30 +00:02:55,020 --> 00:02:59,060 +بتطلع على هدول ال double bonds اللي موجودين عندى + +31 +00:02:59,060 --> 00:03:04,500 +بلاحظ أنه في ال double bonds التلاتة الأوليين نسبة + +32 +00:03:05,610 --> 00:03:10,730 +الاستقطاب فيهم عالية بحيث ان الكربون في الغالب + +33 +00:03:10,730 --> 00:03:15,110 +هتكون partially positive وهذه partially negative + +34 +00:03:15,110 --> 00:03:19,490 +وبناء على ذلك لما ييجي اليوكليوفايل يهاجم هييجي + +35 +00:03:19,490 --> 00:03:24,730 +يهاجم على الكربون و هتتحرك هذه الرابطة بهذا الشكل + +36 +00:03:24,730 --> 00:03:30,020 +فغالبا مع هذولة التلاتة هنصير نحكي عنexo + +37 +00:03:30,020 --> 00:03:34,040 +-cyclization يعني بكون عندى احتمال واحد exo + +38 +00:03:34,040 --> 00:03:38,140 +-cyclization لما بحكي انا عن carbon double bond + +39 +00:03:38,140 --> 00:03:43,420 +carbon الان مختلف انه which carbon will be more + +40 +00:03:43,420 --> 00:03:48,310 +positive than the other it depends on theother + +41 +00:03:48,310 --> 00:03:53,510 +groups هنا وبناء على ذلك ممكن نحكي عن + +42 +00:03:53,510 --> 00:03:57,650 +exocyclization وممكن نحكي عن endocyclization + +43 +00:03:57,650 --> 00:04:02,230 +وبالتالي بكل احتمال اكثر ان نحصل على two products + +44 +00:04:02,230 --> 00:04:06,730 +في حالة ال carbon carbon double bonds يعني لما + +45 +00:04:06,730 --> 00:04:10,210 +نقول اكمل المعادلة لو عندنا carbon oxygen double + +46 +00:04:10,210 --> 00:04:14,270 +bond هو تفاعل واحد ال nucleophile will attack the + +47 +00:04:14,270 --> 00:04:20,250 +carbon atomواضحة فهدولة لسه بيصيروا بالنسبة لنا + +48 +00:04:20,250 --> 00:04:24,330 +اسهل لإنه بيحتملوا احتمال واحد اللي هو ال + +49 +00:04:24,330 --> 00:04:27,570 +exocyclization في غالب الأحوال هنا في عندي + +50 +00:04:27,570 --> 00:04:31,450 +احتمالين ال exocyclization و ال endocyclization we + +51 +00:04:31,450 --> 00:04:36,650 +expect two products الآن النتيجة ممكن يطلع ال exو + +52 +00:04:36,650 --> 00:04:40,430 +ممكن يطلع ال endو ممكن يطلع خليط منهم في النهاية + +53 +00:04:40,430 --> 00:04:47,610 +الكيميا بتضل ايشعلم تجريبي هنشوف أمثلة بالتدريج + +54 +00:04:47,610 --> 00:04:53,450 +تناقش كل ال cycleization على هذه الأنواع من ال + +55 +00:04:53,450 --> 00:04:54,130 +double bonds + +56 +00:05:01,910 --> 00:05:06,670 +هنا بدنا نذكر بشغلة كتير مهمة بالنسبة للسيضة بال + +57 +00:05:06,670 --> 00:05:11,110 +bond O السيضة بال bond O لما تدرس في ال organ ال + +58 +00:05:11,110 --> 00:05:15,510 +chemistry اللي هي ال carbonyl group قلنا ال + +59 +00:05:15,510 --> 00:05:20,340 +carbonyl compounds يقسموا إلى نوعين أساسيينو + +60 +00:05:20,340 --> 00:05:23,780 +يصنفوا حتى في كتب الكيميا العضوية بهذا الشكل + +61 +00:05:51,230 --> 00:05:55,050 +الالديهيدس والكيتونز لحال و الأحمض الكربوكسيلية + +62 +00:05:55,050 --> 00:06:00,510 +ومشتقاتها لحال ليش هذا التصنيف اعتمادا على التفاعل + +63 +00:06:00,510 --> 00:06:05,670 +الأساسي لكل عائلة الالديهيدس والكيتونز تفاعلها + +64 +00:06:05,670 --> 00:06:09,630 +الأساسي ال addition الان شطرين كلكوا بتقولوا + +65 +00:06:09,630 --> 00:06:12,170 +addition و بعد شهر بتقولوا substitution لكن في + +66 +00:06:12,170 --> 00:06:17,730 +الامتحان الا نسبة تلاتين في المية من الطالباتييجوا + +67 +00:06:17,730 --> 00:06:21,450 +يشتغلوا بالعكس ويعملوا خطأ لان ما بيصدقوش انهم + +68 +00:06:21,450 --> 00:06:26,510 +مابيعملوا اخطاء مثلا هذه الـ C double bond O لو + +69 +00:06:26,510 --> 00:06:31,630 +بدنا نتخيلها هذه الديهايد ولا لا الديهايد محذوف اش + +70 +00:06:31,630 --> 00:06:35,130 +فلو بدى تم عليها التفاعل المفروض هذا الـ nitrogen + +71 +00:06:35,130 --> 00:06:38,830 +in nucleophile هاجم هنا اضيف على الـ C double bond + +72 +00:06:38,830 --> 00:06:42,730 +O صارت ال double bond single bond اذا هذه عملية + +73 +00:06:42,730 --> 00:06:49,220 +ايش؟صفة عندي هنا OH و جنبها NH غالبا إذا ال OH و + +74 +00:06:49,220 --> 00:06:54,000 +ال NH جنب بعض أو ممكن حتى OH مع CH تانية جنبها + +75 +00:06:54,000 --> 00:07:00,600 +يعملوا حذف للميّه OH مع H بلس الـ OH مع زوج + +76 +00:07:00,600 --> 00:07:03,960 +الإلكترونات مع H بلس بيعملوا double bond لو كانت + +77 +00:07:03,960 --> 00:07:06,820 +تنافس أن الـ OH تحدث H عن الـ nitrogen أو عن + +78 +00:07:06,820 --> 00:07:10,560 +الكرمون هتحدث عن الـ nitrogen وبناء على ذلك + +79 +00:07:10,560 --> 00:07:14,840 +النتيجة النهائية هتكون C double bond N هذا الكلام + +80 +00:07:14,840 --> 00:07:18,780 +كتير مر علينا يعني لما كنا ناخد تفاعلات ال amines + +81 +00:07:18,780 --> 00:07:23,220 +مع ال ketones تفاعلات ال oximes تفاعلات ال .. ال + +82 +00:07:23,220 --> 00:07:27,250 +hydrazonesكنا نقول C double bond O زي N H2 C + +83 +00:07:27,250 --> 00:07:31,250 +double bond N وننهي الموضوع واضح؟ هذه عملية ال + +84 +00:07:31,250 --> 00:07:34,390 +addition اللي بتتم في ال aldehydes او ال ketones + +85 +00:07:34,390 --> 00:07:41,170 +الان لو كان عندي C double bond O E star او acid او + +86 +00:07:41,170 --> 00:07:43,290 +اللي هي العائلة التانية acids and their + +87 +00:07:43,290 --> 00:07:48,090 +derivatives بتتم عملية ايش؟Substitution ان هذه + +88 +00:07:48,090 --> 00:07:53,430 +بتهاجم وبتطرد ال X وبناء على ذلك بيصير عنده C + +89 +00:07:53,430 --> 00:07:58,010 +double bond O in this case and H حسب النيوكليوفايل + +90 +00:07:58,010 --> 00:08:03,130 +لو كانت هذه OH بيكون C double bond O وبتصير + +91 +00:08:03,130 --> 00:08:05,810 +العائلات في الكيميا العضوية زي ما انتوا عارفينها + +92 +00:08:05,810 --> 00:08:09,330 +ال C double bond O جنب O يعني Cyclic E star + +93 +00:08:09,330 --> 00:08:14,430 +بيسموها لاكتون ال C double bond O جنب N Cyclic + +94 +00:08:14,430 --> 00:08:15,630 +Amide بيسموها + +95 +00:08:17,900 --> 00:08:23,960 +ماذا يسمونه Cyclic Amide؟ لكتم اللي موجود في حلقة + +96 +00:08:23,960 --> 00:08:28,700 +البنسالين الحلقة الربعية ال beta-lactam اللي + +97 +00:08:28,700 --> 00:08:35,060 +بتذكروا حلقة البنسالين فيها سيضة بال bond O و N و + +98 +00:08:35,060 --> 00:08:42,720 +هذه الحلقة مرتبطة بحلقة خماسية عشانك بيسموها beta + +99 +00:08:42,720 --> 00:08:45,880 +-lactam لأن هاي موقع Alpha و ال nitrogen هذا على + +100 +00:08:46,890 --> 00:08:53,710 +بيتا واضح فبنقول احنا بيتا لاكتامو وما إلى ذلك + +101 +00:08:53,710 --> 00:08:58,170 +بناء على ذلك بتكون بهذا الشكل اذا بدنا نكون + +102 +00:08:58,170 --> 00:09:04,170 +مظبوطين عشان نقول هاي alpha هاي beta وهنا حلقة + +103 +00:09:04,170 --> 00:09:10,740 +خماسية او حلقة سداسيةواضح؟ حلقة خماسية اللي هي + +104 +00:09:10,740 --> 00:09:14,720 +مشتقات البنسالين الأساسية لو بدنا نفس البنسالين + +105 +00:09:14,720 --> 00:09:18,200 +المشتقات الجديدة صاروا يبدلوا الخماسية بسوداسية + +106 +00:09:18,200 --> 00:09:22,300 +الـ cephalosporins وما إلى ذلك بكل الأحوال + +107 +00:09:22,300 --> 00:09:26,780 +اللاكتون واللاكتمز المفروض أشياء تكون معروفة عندكم + +108 +00:09:26,780 --> 00:09:31,220 +إذا أنا في السيطة بال bond O بدي أكون منتبه أن + +109 +00:09:31,220 --> 00:09:37,660 +التفاعل اللي عندي هل هو تفاعلAddition و لا تفاعل + +110 +00:09:37,660 --> 00:09:43,960 +Substitution الان لو بدنا ناخد امثلة على + +111 +00:09:43,960 --> 00:09:48,560 +نيوكليوفايل مختلفة الان النيوكليوفايل ال oxygen + +112 +00:09:48,560 --> 00:09:54,140 +النيوكليوفايل عادي عليه أزواج إلكترونات هذا سهل ال + +113 +00:09:54,140 --> 00:09:59,420 +nitrogen النيوكليوفايل عادي ال carbon بيكون + +114 +00:09:59,420 --> 00:10:07,990 +النيوكليوفايل ولكنبإيش؟ بمساعدة الجيران ليش؟ لأن + +115 +00:10:07,990 --> 00:10:12,190 +الكاربون بوضعه الطبيعي ماعليه أزواج إلكترونات + +116 +00:10:12,190 --> 00:10:16,950 +الكاربون بوضعه الطبيعي بيعمل أربع روابط ماعليه + +117 +00:10:16,950 --> 00:10:20,770 +أزواج إلكترونات الأكسجين وضعها الطبيعي في الدنيا + +118 +00:10:20,770 --> 00:10:26,270 +رابطتين وزوجين إلكترونات موجودة فكرة النيوكليوفير + +119 +00:10:26,270 --> 00:10:31,660 +فيها النيتروجينثلاث روابط وزوج إلكترونات لكن + +120 +00:10:31,660 --> 00:10:36,820 +الكربون أربع روابط إذا الكربون لما بدأ أجي أفكر + +121 +00:10:36,820 --> 00:10:43,620 +فيه وقت إيش بيشتغل in eucleophile بدي أتذكر ال + +122 +00:10:43,620 --> 00:10:48,240 +activation لل hydrogen اللي موجودة على الكربون + +123 +00:10:48,240 --> 00:10:56,040 +بحيث إنها تفقد كأحماض مر علينا إنه جنب السيضة بال + +124 +00:10:56,040 --> 00:11:05,650 +bondأو لما بيكون عندكم CH2 هذه بتكون activated CH2 + +125 +00:11:05,650 --> 00:11:13,470 +او CH3 الآن بيزيد ال activation لو كانت ال CH2كمان + +126 +00:11:13,470 --> 00:11:18,310 +C double bond O واضح؟ زي الـ malonic ester بيصير + +127 +00:11:18,310 --> 00:11:23,270 +سهل إنه هذه تفقد H plus وقتها بده يظل عنده carbon + +128 +00:11:23,270 --> 00:11:27,530 +minus صار عنده carbon in eucleophile واضح؟ طبعا + +129 +00:11:27,530 --> 00:11:31,770 +ممكن على C double bond O واحدة تم فقد هيدروجين + +130 +00:11:31,770 --> 00:11:37,250 +بالتأكيد زي تفاعل Aldol اتذكروا Aldol في ال + +131 +00:11:37,250 --> 00:11:42,030 +Acetaldehydeكان تم من هنا اتفقد الهيدروجين لكن + +132 +00:11:42,030 --> 00:11:49,010 +بكون بدي ايش strong base لكن هنا weaker base بتمشي + +133 +00:11:49,010 --> 00:11:54,110 +قاعدة اضعف بتمشي هنا بكون بدي قاعدة قوية الان بدل + +134 +00:11:54,110 --> 00:11:57,150 +السيطاب البندقه في عندى احتمالات تانية ايش اللي + +135 +00:11:57,150 --> 00:12:04,570 +ممكن يكون عندى؟ سيان يكون عندى سالفر يكون عندى + +136 +00:12:04,570 --> 00:12:11,120 +بنزينة في ال rainيكون عندى halogen كل هذا الكلام + +137 +00:12:11,120 --> 00:12:16,540 +لو انوجد كمان جنب ال CH2 بيساعد على ان هاد ال CH2 + +138 +00:12:16,540 --> 00:12:21,500 +تصير اشمالها activated وبالتالي باستعمال ال base + +139 +00:12:21,500 --> 00:12:28,240 +بتفقد ال proton فبصير عندى carbon nucleophile طيب + +140 +00:12:28,240 --> 00:12:33,190 +غيرالـ carbon enucleophile نتذكر ال carbon + +141 +00:12:33,190 --> 00:12:37,690 +enucleophiles مع بعض غير جنب ال C double bond O + +142 +00:12:37,690 --> 00:12:42,890 +وين ال carbon كمان بيكون enucleophile يعني قلنا + +143 +00:12:42,890 --> 00:12:46,690 +جنب ال C double bond O بمساعدة ال C double bond O + +144 +00:12:46,690 --> 00:12:50,590 +ومثلها أحيانا C double bond L ممكن و C double bond + +145 +00:12:50,590 --> 00:12:54,970 +C ممكن الكربون بيشغل ال enucleophile طب غير هذا + +146 +00:12:54,970 --> 00:13:02,170 +الكلام وين بيكونالـ Carbon Nucleophile مر علينا + +147 +00:13:02,170 --> 00:13:07,170 +الـ Greenyard Reagent احنا قلنا ان ال Greenyard R + +148 +00:13:07,170 --> 00:13:14,270 +مع إلكتروناتها بنعتبر ال Greenyard M G X العامل + +149 +00:13:14,270 --> 00:13:20,740 +الفعال فيه R مع إلكتروناتهافالـ Greenyard reagent + +150 +00:13:20,740 --> 00:13:25,780 +is a carbon-eucleophile طبعا زي الـ Greenyard + +151 +00:13:25,780 --> 00:13:29,220 +بتجيني الـ organometallics التانية لو كان ليثيام + +152 +00:13:29,220 --> 00:13:35,460 +المهم مع metal واضح؟ ال carbon مع metals فال + +153 +00:13:35,460 --> 00:13:38,360 +carbon بياخد زوج الإلكترونات و هي بيشتغلوا ال + +154 +00:13:38,360 --> 00:13:42,220 +eucleophile هذا أيضا carbon-eucleophile إيش كمان + +155 +00:13:42,220 --> 00:13:44,800 +مر علينا carbon-eucleophile؟ + +156 +00:13:47,060 --> 00:13:53,380 +الـ Acetylates يعني لو قلنا الـ R C triple bond CH + +157 +00:13:53,380 --> 00:13:58,840 +قلنا احنا ان ال terminal alkynes are acidic يعني + +158 +00:13:58,840 --> 00:14:05,160 +هذا في وجود strong base strong base ما هي ال + +159 +00:14:05,160 --> 00:14:09,460 +lithium ال strong base؟ شو هيفقد؟ ال H بس ال H + +160 +00:14:09,460 --> 00:14:13,500 +لحالها إذا دل عند زوج إلكترونات و ال carbon هنا + +161 +00:14:13,500 --> 00:14:18,670 +صارت إشمالها minusالان كل هذا الكلام اللى أخدناه + +162 +00:14:18,670 --> 00:14:23,090 +في ال organ ال chemistry بلحظة من اللحظات ممكن يمر + +163 +00:14:23,090 --> 00:14:27,230 +معنا عشان يكوّن carbon اليوكليوفايل يتفاعل على ال + +164 +00:14:27,230 --> 00:14:31,130 +C double bond ا و بدنا نكون من ذاكرينه واضح؟ على + +165 +00:14:31,130 --> 00:14:35,070 +سبيل المثال لو اتطلعنا على المركب اللى موجود + +166 +00:14:35,070 --> 00:14:42,870 +أمامنا لاحظوا كام CH2 موجودة فيههذه واحدة CH2 CH2 + +167 +00:14:42,870 --> 00:14:48,550 +هذه بين CW.O و Sulphur إذا هذه Activated ولا لأ + +168 +00:14:48,550 --> 00:14:53,490 +Activated هذه زيها بين CW.O و Sulphur إذا + +169 +00:14:53,490 --> 00:14:58,770 +Activated لاحظوا لما أنا بفعل مع Base احنا مختصرين + +170 +00:14:58,770 --> 00:15:03,630 +الكلام أول ما بيصير مع Base كأنه اعمل اتهانة minus + +171 +00:15:03,630 --> 00:15:09,170 +و minusواضح؟ الآن بعد هيك هذي لما بدا تيجي تتفعل و + +172 +00:15:09,170 --> 00:15:13,570 +تعمل رابطة هنا شو هيصير ال او؟ او اتش او اتش هنا + +173 +00:15:13,570 --> 00:15:21,380 +اتش احذفوا ميهO H مع H Double bond نفس الكلام على + +174 +00:15:21,380 --> 00:15:26,560 +الجهة التانية O H مع H Double bond او الكلام العام + +175 +00:15:26,560 --> 00:15:32,480 +اللى كنا نعرفه زمان انه لو التقى في النهاية H2 و C + +176 +00:15:32,480 --> 00:15:38,300 +Double bond O هى ال H2 مع ال O بيصير double bond + +177 +00:15:38,300 --> 00:15:42,180 +زى لما كنا نفعل C Double bond O مع H2 كيف كنا نكتب + +178 +00:15:42,180 --> 00:15:48,830 +التفاعل كمحصلةهي C double bond O كيتون او الديهايد + +179 +00:15:48,830 --> 00:15:54,170 +طبعا مع NH2 او RNH2 + +180 +00:15:54,170 --> 00:16:00,790 +عطول نحط C double bond N طبعا + +181 +00:16:00,790 --> 00:16:06,310 +هذا التفاعل ايش احنا بنسميه + +182 +00:16:06,310 --> 00:16:10,250 +ايوة + +183 +00:16:10,250 --> 00:16:12,190 +قوله صح addition + +184 +00:16:17,960 --> 00:16:22,500 +Elimination تفاعلين في بعض Addition elimination + +185 +00:16:22,500 --> 00:16:25,840 +لأن مش كل مرة بنذكر في ال addition elimination + +186 +00:16:25,840 --> 00:16:31,000 +خلاص شفنا N H2 مع C double bond O N H2 امين مع + +187 +00:16:31,000 --> 00:16:35,960 +الديهايد او كيتون C double bond N بس بتكون كتفاعل + +188 +00:16:35,960 --> 00:16:40,000 +تمت من خلال ال ايش ال addition elimination لأن هنا + +189 +00:16:40,000 --> 00:16:45,950 +ال CH2 زيها بالظبطعملة ال addition وعملة ال + +190 +00:16:45,950 --> 00:16:50,270 +elimination بالطريقة + +191 +00:16:50,270 --> 00:16:51,650 +اللى وضحناها لكم + +192 +00:17:00,720 --> 00:17:08,560 +هنا في عندنا مثال تاني هذا المثال التاني بنسمي + +193 +00:17:08,560 --> 00:17:13,540 +احنا بالكنور synthesis of furan تحضير الفيوران + +194 +00:17:13,540 --> 00:17:18,680 +بطريقة يعني هدول علماء بالكنور بنستعمل فيها one + +195 +00:17:18,680 --> 00:17:22,520 +four-dicarbonyl compounds لما انا بدي اجي اقول + +196 +00:17:22,520 --> 00:17:27,750 +واحد اتنين تلاتة اربع يعني ال C double bond Oأو + +197 +00:17:27,750 --> 00:17:31,730 +الـ Dicarbonyl Compounds على أي مواقع نسبية على + +198 +00:17:31,730 --> 00:17:35,830 +واحد وأربعة حتى لو كانوا في الجزء مش على واحد + +199 +00:17:35,830 --> 00:17:39,980 +وأربعة بيسميهم إيش احنا؟one four يعني افترضت كأني + +200 +00:17:39,980 --> 00:17:45,500 +انا عندي two carbons one two three four five six + +201 +00:17:45,500 --> 00:17:48,640 +seven eight يعني افترضت ان كل هذه السلسلة تمان + +202 +00:17:48,640 --> 00:17:52,040 +كربونات لكن هذا لما بنسميه .. شو بنقول عنه؟ one + +203 +00:17:52,040 --> 00:17:55,200 +four one four dicarbonyl compounds مانجيش نقول عنه + +204 +00:17:55,200 --> 00:17:59,840 +مثلا three seven or whateverواضح الفكرة؟ هذا الـ 1 + +205 +00:17:59,840 --> 00:18:03,120 +,4-dicarbonyl compounds الان هذا الـ 1,4 + +206 +00:18:03,120 --> 00:18:07,900 +-dicarbonyl compounds بنخليه يسكر الـ C double + +207 +00:18:07,900 --> 00:18:12,260 +bond O على C double bond O تانيا بنضيف شوية حامض + +208 +00:18:12,260 --> 00:18:15,840 +الحامض عارفين انه بيعمل catalysis للـ C double + +209 +00:18:15,840 --> 00:18:20,540 +bond O بساعدها في الإغلاق الان انتوا حرين تفهموا + +210 +00:18:20,540 --> 00:18:24,910 +ان ال double bond هناالـ Eucleophile هاجمت على الـ + +211 +00:18:24,910 --> 00:18:28,450 +Carbon يعني الـ Bi-bond الـ Eucleophile هاجمت على + +212 +00:18:28,450 --> 00:18:31,850 +الـ Carbon على العين والرأس اللي مش حابة تفهم + +213 +00:18:31,850 --> 00:18:37,290 +هالكلام تتذكر ان هذا كمان انا ممكن ارسمله ايش؟ + +214 +00:18:37,290 --> 00:18:42,270 +Enol Form ممكن ارسمله Enol Form و اتخيل ان هذه الـ + +215 +00:18:42,270 --> 00:18:50,600 +Oهاجمت هنا صار عندي OH الان لما بيصير هنا عندي OH + +216 +00:18:50,600 --> 00:18:56,860 +مع H مجاورة بدون يعملوا حذف صار double bond فلو + +217 +00:18:56,860 --> 00:19:00,760 +رسمنا ال E وال form لواحدة منهم خلينها تسكر على C + +218 +00:19:00,760 --> 00:19:03,780 +double bond وعملت رابطة + +219 +00:19:05,190 --> 00:19:11,490 +و OH مع H صار عنده الفيوران فبصير احدى طرق تحضير + +220 +00:19:11,490 --> 00:19:15,790 +الفيوران حقيقة بالكنور سينثسيز of فيوران لو اجينا + +221 +00:19:15,790 --> 00:19:19,670 +نسألكم بالكنور سينثسيز of فيوران is a substitution + +222 +00:19:19,670 --> 00:19:25,370 +reaction no it is an addition reaction حولنا فيه + +223 +00:19:25,370 --> 00:19:31,460 +صيغة بالبنط O إلى OH هذا هو ال additionواضح؟ this + +224 +00:19:31,460 --> 00:19:37,360 +is an addition reaction هذا تفاعل النيوكليوفايل + +225 +00:19:37,360 --> 00:19:43,800 +اللي موجود فيه الأكسجين والإلكتروفايل الـC double + +226 +00:19:43,800 --> 00:19:51,480 +bond O الآن ممكن بطريقة بالكنور سينثسيز نحضر ال + +227 +00:19:51,480 --> 00:19:57,680 +بيروت أيضا من ال 1,4-dicarbonyl compoundsيعني ال 1 + +228 +00:19:57,680 --> 00:20:01,580 +,4-dicarbonyl compounds هين حضرنا منهم أول إيش إيش + +229 +00:20:01,580 --> 00:20:06,020 +الفيورام ممكن نحضر منهم ال by role كيف بدنا نعمل + +230 +00:20:06,020 --> 00:20:10,740 +هذا الكلام بنيجي الفاعل الأمين مع ال 1,4 + +231 +00:20:10,740 --> 00:20:15,060 +-dicarbonyl compounds الآن ع طول ال NH2 مع ال C + +232 +00:20:15,060 --> 00:20:19,780 +double bond O شو بدهم يعملولي addition followed by + +233 +00:20:19,780 --> 00:20:26,190 +elimination C double bond NR هذا عبارة عنامين ال C + +234 +00:20:26,190 --> 00:20:31,710 +double bond ان امين اخدنا tautomerism اللي هي امين + +235 +00:20:31,710 --> 00:20:36,890 +اينامين اين يعني في عندي الكيل و امين اللي هي ان + +236 +00:20:36,890 --> 00:20:42,230 +اتش عادية فهذا الامين هذا الانامين which is more + +237 +00:20:42,230 --> 00:20:47,130 +stable بشكل عام هذه زي ال keto enol tautomerism + +238 +00:20:47,990 --> 00:20:50,890 +متذكرين كيتو اينو التوتمريزم اللي مش متذاكرة + +239 +00:20:50,890 --> 00:20:54,450 +بيرجعها وكان ال more stable form بالأليفات ال + +240 +00:20:54,450 --> 00:20:59,730 +compounds الكيتون الان برضه في عندي توتمريزم تالي + +241 +00:20:59,730 --> 00:21:01,190 +شبه ال اين + +242 +00:21:03,900 --> 00:21:07,720 +الإمين والإينامين هذا هو الشكل المستقل في شكل + +243 +00:21:07,720 --> 00:21:11,340 +الإينامين فأنا عملت الإيمين وبيعمل توتماريزم + +244 +00:21:11,340 --> 00:21:15,680 +للإينامين الآن هي ال يوكليوفايل عندى هى في عند ال + +245 +00:21:15,680 --> 00:21:18,980 +يوكليوفايل هذا ال يوكليوفايل بيعمل addition ع + +246 +00:21:18,980 --> 00:21:26,000 +السيدة بالبنده O ولا لأ شو هتصفه؟ OH مع H + +247 +00:21:28,540 --> 00:21:33,180 +dehydration بحذف ميه ال O H مع أزواج إلكتروناتها + +248 +00:21:33,180 --> 00:21:36,420 +ما قدش plus يعني كأنه بتكون .. تتخيلوا أن هذه + +249 +00:21:36,420 --> 00:21:45,100 +بتلفها تطرد واضح؟ صار عندي by rule صار عندي by + +250 +00:21:45,100 --> 00:21:51,340 +rule إذا هي ال one-fourth dicarbonyl compound إيش + +251 +00:21:51,340 --> 00:21:59,200 +حضرنا منه؟ furan وحضرنا منه؟by role الـ A هيمر + +252 +00:21:59,200 --> 00:22:04,240 +معنا مرة تانية أنه ممكن نحضر منه ثيوفين كمان كيف + +253 +00:22:04,240 --> 00:22:08,620 +ممكن نحضر منه ثيوفين أنه احنا في البداية بنعمل + +254 +00:22:08,620 --> 00:22:13,080 +تفاعل له مع ال sulfur يعني بنخلي هذا تصير sulfur و + +255 +00:22:13,080 --> 00:22:17,520 +زي ما سكرنا في حالة ال oxygen بنسكر في حالة ال + +256 +00:22:17,520 --> 00:22:17,860 +sulfur + +257 +00:22:20,650 --> 00:22:24,330 +سهل أن نحوّل C double bond O إلى C double bond S + +258 +00:22:24,330 --> 00:22:30,990 +باستعمال Reagents زي الـ B2S5، Diphosphorus + +259 +00:22:30,990 --> 00:22:34,710 +Mintesulfide أو في Reagent تاني اسمه Lewison's + +260 +00:22:34,710 --> 00:22:40,010 +Reagent Lewison's Reagent هذا Reagent مختصر حوّل + +261 +00:22:40,010 --> 00:22:45,170 +الـ C double bond O إلى C double bond S + +262 +00:22:47,740 --> 00:22:54,520 +Lewison's reagent ممكن تشوفوه في الموسوعات او ما + +263 +00:22:54,520 --> 00:22:58,060 +إلى ذلك عبارة عن aromatic compounds في كذا sulfur + +264 +00:22:58,060 --> 00:23:03,300 +لو فعلناه وضيفته باختصار انه يحول C double bond O + +265 +00:23:03,300 --> 00:23:07,900 +الى C double bond S فإذا قرأته قال اه يعني this is + +266 +00:23:07,900 --> 00:23:10,140 +Lewison's reagent + +267 +00:23:13,410 --> 00:23:16,830 +واضح؟ إذا لاحظوا هاي ال one-fourth dicarbonyl + +268 +00:23:16,830 --> 00:23:20,410 +compounds للناس اللي بيحبوا الامتحانات بيصير سؤال + +269 +00:23:20,410 --> 00:23:22,690 +typeical لإنه نقولهم والله من one-fourth + +270 +00:23:22,690 --> 00:23:27,090 +dicarbonyl compounds حضرولنا if you run by role, + +271 +00:23:27,310 --> 00:23:28,210 +if you run by role, if you run by role, if you run + +272 +00:23:28,210 --> 00:23:28,230 +by role, if you run by role, if you run by role, + +273 +00:23:28,230 --> 00:23:28,290 +if you run by role, if you run by role, if you run + +274 +00:23:28,290 --> 00:23:31,730 +by role, if you run by role, if you run by role, + +275 +00:23:31,810 --> 00:23:33,410 +if you run by role, if you run by role, if you run + +276 +00:23:33,410 --> 00:23:34,030 +if you run by role, if you run by role, if you run + +277 +00:23:34,030 --> 00:23:38,310 +by role, if you run by role, ifهي مثال إضافي على + +278 +00:23:38,310 --> 00:23:41,910 +ال by role هو نفس المثال السابق أنه جيبنا احنا + +279 +00:23:41,910 --> 00:23:45,450 +امين مع واحدة من ال c double bond o's يعني كأنه + +280 +00:23:45,450 --> 00:23:51,250 +هنا صار an R امين in Amin وخلوها تسكر هنا نفس + +281 +00:23:51,250 --> 00:23:57,910 +المثال السابق تماما لكن صار ال by role ضمن حلقة + +282 +00:23:57,910 --> 00:23:59,930 +أكبر + +283 +00:24:06,170 --> 00:24:12,310 +أيضا من التفاعلات الإضافية على هذا الموضوع اللي هي + +284 +00:24:12,310 --> 00:24:18,070 +التفاعل على الـ CH3O Synthesis of Indole الان هنا + +285 +00:24:18,070 --> 00:24:23,310 +بيجوا بيشتغلوا على ال CH3 هل يا ترى هذي ال CH3 + +286 +00:24:23,310 --> 00:24:35,490 +اكتفيت و لا لأ تنسوش انتوا انه احنا قلنا CH3 CH3 + +287 +00:24:38,030 --> 00:24:43,750 +Jump C double bond O اكتفيت و لا لأ الان ال C + +288 +00:24:43,750 --> 00:24:46,930 +double bond O او C double bond C نفس الفكرة + +289 +00:24:46,930 --> 00:24:52,610 +بيعملوا من ناحية إلكترونيةواضح؟ يعني هذه CH3 في + +290 +00:24:52,610 --> 00:25:00,070 +النهاية جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +291 +00:25:00,070 --> 00:25:00,690 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +292 +00:25:00,690 --> 00:25:01,850 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +293 +00:25:01,850 --> 00:25:01,890 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +294 +00:25:01,890 --> 00:25:01,930 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +295 +00:25:01,930 --> 00:25:17,550 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +296 +00:25:17,550 --> 00:25:24,370 +جام CHلاحظوا كام شغل استعملناه strong base و heat + +297 +00:25:24,370 --> 00:25:30,810 +في النهاية خلّينها دي CH2- و خلّينها تضيف على C + +298 +00:25:30,810 --> 00:25:34,110 +double bond O و ماتعملش هنا المركّب لأنه جنب + +299 +00:25:34,110 --> 00:25:39,230 +aromatic كامد حتى يعني بمعنى لما يضيف هنا حيصير + +300 +00:25:39,230 --> 00:25:46,610 +عنده OH و جنبها NH و جنبها هنا CH في كل الأحوال + +301 +00:25:46,610 --> 00:25:54,210 +الحقيقية في OHمع H هيطلع عنده ال Indole هذا عبارة + +302 +00:25:54,210 --> 00:26:00,810 +عن تفاعل carbon nucleophile مع C double bond O + +303 +00:26:00,810 --> 00:26:04,930 +المثال + +304 +00:26:04,930 --> 00:26:12,490 +اللي هنا مثال جميلNitro وع طول كلكم بتتذكروا كيمية + +305 +00:26:12,490 --> 00:26:16,130 +البنزين والانليلين ال Nitro بال reduction هو + +306 +00:26:16,130 --> 00:26:22,490 +الانليلين احنا كيف بنحضره reduction of Nitro بنزين + +307 +00:26:22,490 --> 00:26:26,150 +بناء على ذلك لو انا أخدت ال Nitro compound هذا بال + +308 +00:26:26,150 --> 00:26:30,890 +reduction شو حيصير عندى؟ ال NH2 عبارة عن ال + +309 +00:26:30,890 --> 00:26:36,430 +nucleophile وين بدو يهاجم؟ على ال C double bond O + +310 +00:26:36,430 --> 00:26:46,300 +بهذا الشكل صارتو اتش و اتش مع اتش بيعمل + +311 +00:26:46,300 --> 00:26:51,940 +double bond و بيسكر صار أيضا عندنا اندول هم لاحظين + +312 +00:26:51,940 --> 00:26:57,560 +كيف بنصل لمركب بطرق مختلفة لكن بنفس الفكرة يعني + +313 +00:26:57,560 --> 00:27:01,220 +الاندول بهذه الطريقة و من هذا المركب و من هذا + +314 +00:27:01,220 --> 00:27:08,340 +المركب طبعا مختلفين في إش موجود عندهم في ال R و ال + +315 +00:27:08,340 --> 00:27:16,270 +Rواضح؟ يمكن هنا خليني أروح لفكرة أساسية كتير في ال + +316 +00:27:16,270 --> 00:27:20,430 +heterocycle chemistry أنه ليش أنا جاعد كل مرة بحضر + +317 +00:27:20,430 --> 00:27:25,010 +ال endol بطريقة معينة أو لما بدي أجي أخد الفيوران + +318 +00:27:25,010 --> 00:27:29,870 +بدي أحضر .. أخدلي عشر .. عشر أو خمستاشر synthesis + +319 +00:27:29,870 --> 00:27:35,540 +of الفيورانالكيميا الحلقية .. الكيميا الحلقية + +320 +00:27:35,540 --> 00:27:42,300 +بتختلف عن كيمية البنزين اختلاف أساسي وجوهري جدا + +321 +00:27:42,300 --> 00:27:49,200 +كيمية البنزين مبناها ككيمية مبنية على ان في عند + +322 +00:27:49,200 --> 00:27:57,640 +حلقة البنزين موجودةتمام؟ و ايش انا لازمني على حلقة + +323 +00:27:57,640 --> 00:28:04,900 +البنزين بابدأ من بنزين و بصير اضيف اول substituent + +324 +00:28:04,900 --> 00:28:08,600 +و تاني substituent و باخد الأفكار اللي اتعلمتها + +325 +00:28:08,600 --> 00:28:11,160 +activating groups و deactivating groups و + +326 +00:28:11,160 --> 00:28:14,020 +orthopara directing groups و metadirecting groups + +327 +00:28:14,020 --> 00:28:19,580 +لكن منطلقي لتحضير ال substituted بنزين يعني لو بدى + +328 +00:28:19,580 --> 00:28:29,330 +مركب زي هذا مثلاCH3 NO2 هذا من أين أنا بحضره من + +329 +00:28:29,330 --> 00:28:33,950 +البنزين ببدأ البنزين الكيلاشن المثل بتودي + +330 +00:28:33,950 --> 00:28:38,590 +أورثوبارا و بعدين نيتريشن منطلقي الحلقة اللي زيه + +331 +00:28:38,590 --> 00:28:43,910 +الآن ال heterocyclic chemistry لا تنطلق من الحلقات + +332 +00:28:45,030 --> 00:28:49,890 +طبعا يعني اللي بده في ال heterocyclic chemistry + +333 +00:28:49,890 --> 00:28:57,030 +substituted فيوران على سبيل المثال ربما نادر جدا + +334 +00:28:57,030 --> 00:29:01,410 +نفترض هنا عند مجموعة X أو Y ان يكون التفكير اللي + +335 +00:29:01,410 --> 00:29:05,810 +عنده التفكير اللي عنده ان ابدأ ب فيوران و احط + +336 +00:29:05,810 --> 00:29:11,800 +المجموعات اللي بدك اياهم هناالتفكير اللي عنده أن + +337 +00:29:11,800 --> 00:29:19,000 +هذا الفيوران كيف بتحضر أصلا بحط المجموعات عليه من + +338 +00:29:19,000 --> 00:29:24,700 +قبل التحضير من قبل عملية إغلاق يعني لو كنت أوضح + +339 +00:29:24,700 --> 00:29:30,060 +أنا أرجع للمثال اللي هنا لاحظوا بهذا المثال كم + +340 +00:29:30,060 --> 00:29:35,940 +مجموعة أنا عندي على الفيوران أربع مجموعاتولا حد في + +341 +00:29:35,940 --> 00:29:40,180 +الدنيا بيفكر انه لما بده يحضر هذا المركب .. لما + +342 +00:29:40,180 --> 00:29:46,260 +يحضر هذا المركب انه يجيبأفيران و يبعد الف باجي + +343 +00:29:46,260 --> 00:29:50,160 +نضيف المجموعة كذا كذا كذا كل المجموعات اللي بدي + +344 +00:29:50,160 --> 00:29:56,840 +إياها بضيفها قبل عملية إيش الإغلاق بجيب مركب فيه C + +345 +00:29:56,840 --> 00:30:00,220 +double bond O جب و ال R هادي و أنا C double bond O + +346 +00:30:00,220 --> 00:30:02,700 +جب هذا ال R و هذا ال R بكون عامله و هذا عامله + +347 +00:30:02,700 --> 00:30:07,820 +بالكيميا العادية و بعدين بسكر فال substituents في + +348 +00:30:07,820 --> 00:30:13,580 +ال heterocyclic compounds بتلحطقبل الإغلاق في الـ + +349 +00:30:13,580 --> 00:30:19,080 +aromatic compounds بتنحط غالبا بعد الإغلاق يعني + +350 +00:30:19,080 --> 00:30:23,700 +منطلقنا هناك البنزين بس احنا هنا ما بننطلق من حلقة + +351 +00:30:23,700 --> 00:30:27,580 +نقول ال parent ونصير نحضر منها وعشان هيك ال + +352 +00:30:27,580 --> 00:30:31,760 +heterocyclic synthesis مختلفة بفكرته عن أن الواحد + +353 +00:30:31,760 --> 00:30:37,050 +يكون حاضر aromatic compoundsاللي بده شغلة بحط + +354 +00:30:37,050 --> 00:30:41,930 +الأشياء وين؟ على القطع اللي بده يعمل عليها الإغلاق + +355 +00:30:41,930 --> 00:30:46,190 +بحط الأشياء اللي لازمها على القطع الأصلية اللي بده + +356 +00:30:46,190 --> 00:30:50,410 +يعمل لها cyclization مش بيحضر حلقة أو بروح بشتري + +357 +00:30:50,410 --> 00:30:53,570 +payroll أو furan وبعدين بيقول بده أعمل عليه تفاعل + +358 +00:30:53,570 --> 00:30:58,830 +هذا الكلام في ال heterocyclic compounds قليل جدًا + +359 +00:30:58,830 --> 00:31:06,460 +واضح الفكرة؟يعني هاي مثلا الدول عليه substituents + +360 +00:31:06,460 --> 00:31:11,880 +معينة بدنا نحطها من البداية و بعدين نعمل ال + +361 +00:31:11,880 --> 00:31:18,670 +cycleization اللي موجود عندنانشوف مراكب جديد مثلا + +362 +00:31:18,670 --> 00:31:24,650 +بنزو فيوران نشوف مراكب بنزو فيوران هاي ال بنزو + +363 +00:31:24,650 --> 00:31:31,390 +فيوران هذا اللي موجود عندنا عليه two substituents + +364 +00:31:31,390 --> 00:31:36,010 +هنا يعني لو افترضنا ان هذا ال R مثل خليني احط + +365 +00:31:36,010 --> 00:31:41,570 +فرضيا ان هذا ال R CH3 و هذا ال R C double bond O + +366 +00:31:41,570 --> 00:31:43,630 +خليني اقول اثل + +367 +00:31:48,440 --> 00:31:56,400 +واضح؟ مابفكرش انا ان هذا المركب اجي احضره من + +368 +00:31:56,400 --> 00:32:00,820 +بنزوفيوران و بعدين اقول كيف بده احط ال CH3 و كيف + +369 +00:32:00,820 --> 00:32:08,650 +بده احط ال CO2 .. ال C double bond O إثلواضح؟ لأ + +370 +00:32:08,650 --> 00:32:13,630 +باجي من نقطة البداية لما بصمم ال synthesis بحطها + +371 +00:32:13,630 --> 00:32:17,970 +دول الأشياء الان لو بدأت بفينول هذا المركب عبارة + +372 +00:32:17,970 --> 00:32:23,110 +عن ايش؟ فينول و الفينول عليه C double bond O R + +373 +00:32:23,110 --> 00:32:29,970 +وجدت لما انا بحطها بخليها تكون C double bond O CH3 + +374 +00:32:29,970 --> 00:32:37,050 +صار عندي سؤال ان كيف تحضر هذا المركب انت؟واضح؟ + +375 +00:32:37,050 --> 00:32:41,750 +يعني بيصير سؤالي ك organ ال chemistry أنه أنا هذا + +376 +00:32:41,750 --> 00:32:47,370 +المُركّب لازمني وجدت هذا لأنه مشتقت بنزين، بترجع + +377 +00:32:47,370 --> 00:32:51,770 +لكمية البنزين، كيف ممكن نحضر هذا المُركّب؟ طبعا + +378 +00:32:51,770 --> 00:32:56,530 +هتتذكروا أن ال acidity group بنقدر نحطها، لكن ال + +379 +00:32:56,530 --> 00:33:02,500 +OHعادة لما بنحطها بنعمل نيترو والنيترو نحوله + +380 +00:33:02,500 --> 00:33:07,060 +لانيلين والانيلين لديازونيوم سولت والديازونيوم + +381 +00:33:07,060 --> 00:33:12,360 +سولت مع H بلس نخليه فينول الان الفينول اورثو بارا + +382 +00:33:12,360 --> 00:33:16,080 +directing group مثلا او الامين اورثو بارا + +383 +00:33:16,080 --> 00:33:20,460 +directing group له واضح الفكرة كيف؟ اه الان هذا + +384 +00:33:20,460 --> 00:33:26,330 +الكلام اعمله وحطينا CH3N ابني جهانا فاعلهذا الجزء + +385 +00:33:26,330 --> 00:33:32,790 +مع PR CH2 C double bond OR يعني هذه عبارة عن ايش C + +386 +00:33:32,790 --> 00:33:38,550 +double bond OR تانية الان لو انا بدي هذه اثل من + +387 +00:33:38,550 --> 00:33:43,670 +البداية بحطها اثل لو بديها مثل من البداية بحطها + +388 +00:33:43,670 --> 00:33:53,890 +مثل يعني انا حطيت ايشالان لاحظوا لدي CH2 حاملة بار + +389 +00:33:53,890 --> 00:34:00,410 +و OH هذا عبارة عن اليوكليوفايل مار علي لو خلطته مع + +390 +00:34:00,410 --> 00:34:05,590 +بعض ال substitution أسألتوا + +391 +00:34:05,590 --> 00:34:10,130 +substitution غالبا لأن هذه primary صار عندكم O + +392 +00:34:14,140 --> 00:34:21,140 +CH2C double bond O إفل الان لما أستعمل ال base CH2 + +393 +00:34:21,140 --> 00:34:23,860 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +394 +00:34:23,860 --> 00:34:36,740 +CH2 CH2 + +395 +00:34:41,310 --> 00:34:46,530 +Elimination طلع المركّب اللي عنده شفتوا كيف نظام + +396 +00:34:46,530 --> 00:34:49,590 +ال synthesis في ال heterocyclic chemistry ان + +397 +00:34:49,590 --> 00:34:55,450 +المجموعات اللي بتديها على الناتج بابدأ من البداية + +398 +00:34:55,450 --> 00:35:02,110 +أخليها تكون موجودة عنده واضح؟ من البداية بابدأ + +399 +00:35:02,110 --> 00:35:05,890 +أخليها تكون موجودة عنده يعني لو مثلا افترضنا أن + +400 +00:35:05,890 --> 00:35:12,420 +طالبة في الأساس مهتمة أن هذه المجموعة تكون إثلأول + +401 +00:35:12,420 --> 00:35:15,840 +ما بدها تحضر هنا بدل ما تجيب ال reagent اللي + +402 +00:35:15,840 --> 00:35:26,600 +اتفعله هنا يكون CH3 OCl CH3 هتجيب CH3 OCl إثل + +403 +00:35:30,990 --> 00:35:35,170 +فالمجموعات عادة بنحطها من الأول انما مافي عندنا في + +404 +00:35:35,170 --> 00:35:39,190 +ال heterocyclic chemistry ان اقول بحضر الحلقة نقية + +405 +00:35:39,190 --> 00:35:42,570 +او باشتريها شراية وبعدين اعمل عليها substitution + +406 +00:35:42,570 --> 00:35:49,590 +فهذا مبدأ عام عندنا في موضوع ال heterocyclic + +407 +00:35:49,590 --> 00:35:56,430 +synthesis واخد الأمثلة الان + +408 +00:35:56,430 --> 00:36:02,740 +نجي لهذا المركبأيزوكزازول وهذا أيزوكزازول عليه + +409 +00:36:02,740 --> 00:36:08,360 +مجموعتين R لاحظوا كيف التحضير تبعه لو أخدنا احنا + +410 +00:36:08,360 --> 00:36:11,680 +one three-dicarbonyl compound + +411 +00:36:15,050 --> 00:36:21,750 +يعني هي carbon واحد اتنين تلاتة كأننا بنقول ان هذي + +412 +00:36:21,750 --> 00:36:26,850 +C double bond O و هذي C double bond O هي واحد + +413 +00:36:26,850 --> 00:36:31,750 +اتنين تلاتة اذا هذا one three-dicarbonyl compound + +414 +00:36:31,750 --> 00:36:38,470 +ولا لأ طيب لو فعلته مع ان H2OH هيدروكسلامين مع + +415 +00:36:38,470 --> 00:36:42,290 +كيتون ايش بيعطيني على طول اكزين + +416 +00:36:44,870 --> 00:36:48,390 +Hydroxylamine مع كيتون خليه يتفعل على هذا الـ C + +417 +00:36:48,390 --> 00:36:53,570 +double bond O هتصير C double bond N O H This is N + +418 +00:36:53,570 --> 00:36:59,910 +أكزيم وهذه C double bond O موجودة هنا الآن هذه الـ + +419 +00:36:59,910 --> 00:37:09,010 +on-eucleophile ممكن تتسكر هنا وتعمل عنده؟ OH مع H + +420 +00:37:09,010 --> 00:37:16,170 +elimination إيش صار عندك؟ isoxazoleلاحظوا طبعا هذا + +421 +00:37:16,170 --> 00:37:23,310 +الكلام لناس بدهم يتخيلوا انهم بدهم يتعبوا شوية + +422 +00:37:23,310 --> 00:37:27,950 +بيصير جزء من التفكير اللي عندهم يا تورا لو ايجا و + +423 +00:37:27,950 --> 00:37:32,390 +سألني how can you prepare this compound؟ بدكوا + +424 +00:37:32,390 --> 00:37:37,590 +تبدو في ال ايش ال disconnection approachلو قلكوا + +425 +00:37:37,590 --> 00:37:42,090 +كيف ممكن تحضر هذا المركب بدكوا تبدو في ال + +426 +00:37:42,090 --> 00:37:44,690 +disconnection approach الان في ال disconnection + +427 +00:37:44,690 --> 00:37:49,370 +approach بدوا يبدأ يصير معروف عندكم انه اول قطع + +428 +00:37:49,370 --> 00:37:52,430 +ممكن تعملوا من هنا و ترجعوا هذه الى c double bond + +429 +00:37:52,430 --> 00:37:58,810 +o and + +430 +00:37:58,810 --> 00:38:06,600 +o h هذا القطع الاولدائما جامبلين يوكل يو فاي + +431 +00:38:06,600 --> 00:38:12,280 +بإمكانكوا تعملوا قطع و ترجعوا هذه الى C double + +432 +00:38:12,280 --> 00:38:16,120 +bond O يعني كأن هذه كانت OH OH ال OH كانت C double + +433 +00:38:16,120 --> 00:38:19,720 +bond O بعد هيك ممكن تعملوا القطع التاني + +434 +00:38:22,880 --> 00:38:26,920 +واضح؟ فمعظم هذه الأمثلة اللي موجودة بإمكانكوا + +435 +00:38:26,920 --> 00:38:31,280 +انتوا تعملوا تدريب عليها انه لو اجت اه مااحنا + +436 +00:38:31,280 --> 00:38:36,760 +عارفين انه كل c double bond n شو كان أساسها؟ c + +437 +00:38:36,760 --> 00:38:42,220 +double bond o and h2هذه ال O اللي جنب C double + +438 +00:38:42,220 --> 00:38:48,160 +bond C او بشكل عام عشان اساعدكوا للمستقبل وين + +439 +00:38:48,160 --> 00:38:52,480 +بتشوفوا؟ وين بتشوفوا في ال disconnection approach؟ + +440 +00:38:52,480 --> 00:38:58,620 +C double bond C و جنب هاليوكليوفايل ما تبقى بره + +441 +00:38:58,620 --> 00:39:03,980 +بيقولكوا كيف هذا اتحضر Carbohydrate بدكوا؟ على طول + +442 +00:39:03,980 --> 00:39:07,380 +يكون التفكير تبعكم ان هذا + +443 +00:39:10,460 --> 00:39:16,720 +كان C double bond O وهنا كان لينيو كليو فاير + +444 +00:39:16,720 --> 00:39:23,580 +عارفين و هذا سهل معناهالـ Retrosynthesis فتطلعوا + +445 +00:39:23,580 --> 00:39:28,420 +على هذه الفكرة الجيدة يعني هذا الجزء من الجزء .. + +446 +00:39:28,420 --> 00:39:33,620 +هذا الجزء من الجزء احفظوه ان الـ C double bond C + +447 +00:39:33,620 --> 00:39:38,620 +اللي جنبها نيوكليوفايل بقدر انا اقول انه حصلها C + +448 +00:39:38,620 --> 00:39:43,620 +double bond O نيوكليوفايل بهذا الشكل واضحة هذه + +449 +00:39:43,620 --> 00:39:44,260 +الفكرة؟ + +450 +00:39:54,240 --> 00:40:00,560 +بجينا cyclization جديد هذا ال cyclization بنقوله + +451 +00:40:00,560 --> 00:40:04,320 +cyclization onto an ortho position of a بنزين ring + +452 +00:40:04,320 --> 00:40:11,520 +الإغلاق على موقع أورثو من حلقة البنزين وهذا النوع + +453 +00:40:11,520 --> 00:40:16,110 +من ال cyclization بيعطينا fused ringsيعني كتير جدا + +454 +00:40:16,110 --> 00:40:21,850 +لما بتشوفوا ال fused rings اول ما تفكروا فيهم + +455 +00:40:21,850 --> 00:40:26,650 +فكروا بهذا ال cyclization اللي هو ال cyclization + +456 +00:40:26,650 --> 00:40:33,470 +على موقع Ortho الان ايش قصة موقع Ortho هذا ببساطة + +457 +00:40:33,470 --> 00:40:36,850 +ال ortho position يعني لو هى .. هى انا عندي ابدال + +458 +00:40:36,850 --> 00:40:40,490 +من هذه النقطة وين موقع Ortho ال ortho position + +459 +00:40:40,490 --> 00:40:46,320 +بتكون تاعتبروه ان هو ال nucleophileالأورثو بوزيشن + +460 +00:40:46,320 --> 00:40:53,820 +اكتس از اليوكليوفايل الأورثو بوزيشن اكتس از + +461 +00:40:53,820 --> 00:40:57,840 +اليوكليوفايل واضح هذا الفكرة يعني لما اجي انا + +462 +00:40:57,840 --> 00:41:03,520 +اتخيل هذا الجزيء ان هذا ال intermediate هي موضوعي + +463 +00:41:03,520 --> 00:41:07,480 +لكن خلينا نشوف كيف اتكونت اتكونت من أنيلين هي + +464 +00:41:07,480 --> 00:41:16,140 +الانيلين شايفينه؟ فين السكرته على 1,3-dicarbonyl + +465 +00:41:16,140 --> 00:41:20,800 +compounds R,CWBond O,CH2,CWBond OR يعني الـCWBond + +466 +00:41:20,800 --> 00:41:25,860 +O اللي هنا مع الـNH2 عملت ليه؟ CWBond N هذه خطوة + +467 +00:41:25,860 --> 00:41:30,520 +تحضيرية مش خطوة إغلاق حلقة هذه كيلية عادية CWBond + +468 +00:41:30,520 --> 00:41:35,480 +O مع NH2 أصل هذه الآن اللي بهمني أنا في + +469 +00:41:35,480 --> 00:41:37,640 +الـcyclization اللي هي + +470 +00:41:41,310 --> 00:41:46,970 +هذه الآن هنا بإمكانكم تفهموا الموضوع ان هذه ال + +471 +00:41:46,970 --> 00:41:51,990 +double bond بإمكانها تيجي تهاجم هنا وتعمل addition + +472 +00:41:51,990 --> 00:41:56,050 +او H تعمل addition بعد هي بتفقد ال H اللي هنا + +473 +00:41:56,050 --> 00:42:03,790 +بترجع هذه واضح الفكرة يعني هذه ال double bond + +474 +00:42:03,790 --> 00:42:08,690 +بإمكانها تعمل addition ال H هذه سهلة تفقد بتفقد + +475 +00:42:09,410 --> 00:42:13,850 +وبرجع البنزين للغرض التطبيق مانتش ياكم ضايعوا مخكم + +476 +00:42:13,850 --> 00:42:17,950 +و وجدكم في إيش في أنكوا تتخيلوا أسهم على طول بدكم + +477 +00:42:17,950 --> 00:42:22,130 +تحطوا الجواب أن هذا ال orthoposition هذا ال + +478 +00:42:22,130 --> 00:42:25,550 +orthoposition اللي زي هيك هذه ال double .. هذه ال + +479 +00:42:25,550 --> 00:42:28,930 +bond اللي هنا مع ال H و أنتم غاضبين وين بدكم + +480 +00:42:28,930 --> 00:42:35,910 +تنجلوها بدل ما هي هيك بدون ما نقعد نتعب حالنا هيك + +481 +00:42:35,910 --> 00:42:37,750 +و ال .. و هذه إيش صارت + +482 +00:42:41,270 --> 00:42:44,470 +يعني تخيلوا ببساطة كأنه ال double .. كأنه ال + +483 +00:42:44,470 --> 00:42:48,670 +single bond اللي مع ال H حطناها هنا و جيبنا ال + +484 +00:42:48,670 --> 00:42:53,870 +action هذه محصلة التفاؤد هاي بتتم عملية إيش ال + +485 +00:42:53,870 --> 00:42:59,190 +cyclization طبعا بعد هيك OH مع H شو بيعملوا عنده + +486 +00:42:59,190 --> 00:43:06,810 +double bond هذا المثال نفس الشيء بس بدنا فيه بدل + +487 +00:43:06,810 --> 00:43:12,280 +anilineفيلون انتبهوا بقى كيف انا نفس الفكرة كيف + +488 +00:43:12,280 --> 00:43:18,540 +بصمم التحضير بنفس الفكرة يعني هنا فين ال N H2 و + +489 +00:43:18,540 --> 00:43:25,160 +هنا فين ال O H الان هذا ال O H روح اتحطته مع R C O + +490 +00:43:25,160 --> 00:43:32,360 +C H C L لحظة ال O H وين بتروح بتسكل بتطرد ال C L + +491 +00:43:32,360 --> 00:43:38,030 +ال substitutionالـ Eucleophilic Substitution هاي + +492 +00:43:38,030 --> 00:43:42,930 +صار عندكم CHR اللي هي موجودة هنا و C double bond O + +493 +00:43:42,930 --> 00:43:48,210 +هاي ال orthoposition الرابط اللي هنا وين بده تصير؟ + +494 +00:43:48,210 --> 00:43:53,170 +صارت هنا، هاذي؟ + +495 +00:43:53,170 --> 00:44:04,070 +OH OH واضح؟ ال OH و ال H عملوا إغلاق على + +496 +00:44:04,070 --> 00:44:09,780 +أي حال؟أفهمنا إذا ال cyclization على ال + +497 +00:44:09,780 --> 00:44:15,060 +orthoposition في عندي أنا أنثى إضافية كلها في ال + +498 +00:44:15,060 --> 00:44:18,900 +cyclization على ال orthoposition لكن اللى بيصير + +499 +00:44:18,900 --> 00:44:25,060 +انه شوية بالفصل عندكم المثال يعني هذه ال NH2 اللى + +500 +00:44:25,060 --> 00:44:29,160 +هتحل محل ال PR و بعدين هذا ال cyclization سهل ولا + +501 +00:44:29,160 --> 00:44:36,070 +لأ؟سهل هذه الان H2 انها تعمل إبدال لل CL لأن هذا + +502 +00:44:36,070 --> 00:44:41,350 +acid chloride و بعدين هذا ال orthoposition يسكر + +503 +00:44:41,350 --> 00:44:48,150 +هناسهل أمثلة كتير جدا و عشان هيك جزء من ال + +504 +00:44:48,150 --> 00:44:52,490 +homework اللي هتجيبه هذه الأمثلة الحقيقة من مجالات + +505 +00:44:52,490 --> 00:44:56,290 +يعني اعتبروا ان انا كمان جيبت homework هذه من مجلة + +506 +00:44:56,290 --> 00:44:59,970 +مثلا اسمها journal of chemical research في النهاية + +507 +00:44:59,970 --> 00:45:05,930 +بيعمل عدة تفاعلات ممكن ناقش هذه الأمثلة في المرة + +508 +00:45:05,930 --> 00:45:11,880 +الجاية لكن كل محورها ايش؟cyclization على ال + +509 +00:45:11,880 --> 00:45:17,460 +orthoposition وبهك بننهي الجزء تبعنا ومر علينا + +510 +00:45:17,460 --> 00:45:21,920 +أنفلة منوعة من ال cyclization على ال c double bond + +511 +00:45:21,920 --> 00:45:27,160 +o بما في ذلك أن ال orthoposition يكون بيشتغل كاش ك + +512 +00:45:27,160 --> 00:45:27,880 +nucleophile + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bXzOV3H6R70_raw.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bXzOV3H6R70_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..c95b14cc661186bb8833c73e755babe65934f42e --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/bXzOV3H6R70_raw.srt @@ -0,0 +1,2072 @@ +1 +00:00:20,890 --> 00:00:25,550 +بسم الله الرحمن الرحيم اليوم بنبدأ معكوا في موضوع + +2 +00:00:25,550 --> 00:00:29,330 +جديد في مجال تحضير ال heterocyclic rings و احنا + +3 +00:00:29,330 --> 00:00:35,410 +اتفقنا سابقا انه بدنا نشرح طرق عامة لتحضير ال + +4 +00:00:35,410 --> 00:00:40,730 +heterocyclic rings من خلال انحضر حلقات مختلفة + +5 +00:00:40,730 --> 00:00:45,610 +مانركزش على حلقة واحدة لأ نركز على طريقةأول ما + +6 +00:00:45,610 --> 00:00:52,350 +اتكلمنا اتكلمنا على تفاعل الإبدال على ذرة كربون + +7 +00:00:52,350 --> 00:00:56,510 +بتحمل أربع روابط زي ما سمناها tetragonal carbon و + +8 +00:00:56,510 --> 00:01:04,360 +ربما اتذكروا انه احنا استعانا بقواعدBaldwin فلما + +9 +00:01:04,360 --> 00:01:10,800 +كنا بنعمل إبدال على tetragonal carbon كنا بنشيل + +10 +00:01:10,800 --> 00:01:16,220 +مجموعة مرتبطة برابط واحدة ولذلك ماكنش هنا في عندنا + +11 +00:01:16,220 --> 00:01:20,040 +احتمال الا ان ال cyclization يكون ايش + +12 +00:01:20,040 --> 00:01:25,100 +exocyclization يعني مافيش امكانية ان يكون عندى في + +13 +00:01:25,100 --> 00:01:30,080 +ال tetragonal cyclization endocyclizationبس طالما + +14 +00:01:30,080 --> 00:01:34,180 +انها رابطة بدأت تتحرك اذا هي فقط هتتحرك للخارج و + +15 +00:01:34,180 --> 00:01:39,020 +يتم ال cyclization اخدنا امثلة كتير الان لما نيجي + +16 +00:01:39,020 --> 00:01:45,280 +نشتغل على ال diagonal atoms او carbons في عندنا + +17 +00:01:45,280 --> 00:01:48,700 +double bond الان لما يصير في عندنا double bond + +18 +00:01:48,700 --> 00:01:53,940 +بيصير في عندنا إمكانيةلنوعين من الـ cyclization لـ + +19 +00:01:53,940 --> 00:01:56,940 +exocyclization يعني واحدة من ال double bonds خلينا + +20 +00:01:56,940 --> 00:01:59,800 +نقول هذا ال by bond تتحرك للخارج this is + +21 +00:01:59,800 --> 00:02:03,540 +exocyclization وهذه بتكون الحقيقة عملية addition + +22 +00:02:03,540 --> 00:02:09,640 +او ان ال double bond تتحرك بداخل الحلقة يعني هذه + +23 +00:02:09,640 --> 00:02:15,120 +وبالتالي بيكون عندنا endocyclization ففي حالةما + +24 +00:02:15,120 --> 00:02:19,300 +بنحكي عن ال double bonds بصير في عنا احتمالين من + +25 +00:02:19,300 --> 00:02:22,360 +ناحية المبدأ في البداية انه في احتمال ال + +26 +00:02:22,360 --> 00:02:27,880 +exocyclization في احتمال ال endocyclization هذا + +27 +00:02:27,880 --> 00:02:31,300 +اذا اتكلمنا عن ال double bonds بشكل عام + +28 +00:02:44,980 --> 00:02:49,500 +الـ C double bond O الـ C double bond N الـ C + +29 +00:02:49,500 --> 00:02:55,020 +double bond S وربما الـ C double bond C لو أنا + +30 +00:02:55,020 --> 00:02:59,060 +بتطلع على هدول ال double bonds اللي موجودين عندى + +31 +00:02:59,060 --> 00:03:04,500 +بلاحظ أنه في ال double bonds التلاتة الأوليين نسبة + +32 +00:03:05,610 --> 00:03:10,730 +الاستقطاب فيهم عالية بحيث ان الكربون في الغالب + +33 +00:03:10,730 --> 00:03:15,110 +هتكون partially positive وهذه partially negative + +34 +00:03:15,110 --> 00:03:19,490 +وبناء على ذلك لما ييجي اليوكليوفايل يهاجم هييجي + +35 +00:03:19,490 --> 00:03:24,730 +يهاجم على الكربون و هتتحرك هذه الرابطة بهذا الشكل + +36 +00:03:24,730 --> 00:03:30,020 +فغالبا مع هذولة التلاتة هنصير نحكي عنexo + +37 +00:03:30,020 --> 00:03:34,040 +-cyclization يعني بكون عندى احتمال واحد exo + +38 +00:03:34,040 --> 00:03:38,140 +-cyclization لما بحكي انا عن carbon double bond + +39 +00:03:38,140 --> 00:03:43,420 +carbon الان مختلف انه which carbon will be more + +40 +00:03:43,420 --> 00:03:48,310 +positive than the other it depends on theother + +41 +00:03:48,310 --> 00:03:53,510 +groups هنا وبناء على ذلك ممكن نحكي عن + +42 +00:03:53,510 --> 00:03:57,650 +exocyclization وممكن نحكي عن endocyclization + +43 +00:03:57,650 --> 00:04:02,230 +وبالتالي بكل احتمال اكثر ان نحصل على two products + +44 +00:04:02,230 --> 00:04:06,730 +في حالة ال carbon carbon double bonds يعني لما + +45 +00:04:06,730 --> 00:04:10,210 +نقول اكمل المعادلة لو عندنا carbon oxygen double + +46 +00:04:10,210 --> 00:04:14,270 +bond هو تفاعل واحد ال nucleophile will attack the + +47 +00:04:14,270 --> 00:04:20,250 +carbon atomواضحة فهدولة لسه بيصيروا بالنسبة لنا + +48 +00:04:20,250 --> 00:04:24,330 +اسهل لإنه بيحتملوا احتمال واحد اللي هو ال + +49 +00:04:24,330 --> 00:04:27,570 +exocyclization في غالب الأحوال هنا في عندي + +50 +00:04:27,570 --> 00:04:31,450 +احتمالين ال exocyclization و ال endocyclization we + +51 +00:04:31,450 --> 00:04:36,650 +expect two products الآن النتيجة ممكن يطلع ال exو + +52 +00:04:36,650 --> 00:04:40,430 +ممكن يطلع ال endو ممكن يطلع خليط منهم في النهاية + +53 +00:04:40,430 --> 00:04:47,610 +الكيميا بتضل ايشعلم تجريبي هنشوف أمثلة بالتدريج + +54 +00:04:47,610 --> 00:04:53,450 +تناقش كل ال cycleization على هذه الأنواع من ال + +55 +00:04:53,450 --> 00:04:54,130 +double bonds + +56 +00:05:01,910 --> 00:05:06,670 +هنا بدنا نذكر بشغلة كتير مهمة بالنسبة للسيضة بال + +57 +00:05:06,670 --> 00:05:11,110 +bond O السيضة بال bond O لما تدرس في ال organ ال + +58 +00:05:11,110 --> 00:05:15,510 +chemistry اللي هي ال carbonyl group قلنا ال + +59 +00:05:15,510 --> 00:05:20,340 +carbonyl compounds يقسموا إلى نوعين أساسيينو + +60 +00:05:20,340 --> 00:05:23,780 +يصنفوا حتى في كتب الكيميا العضوية بهذا الشكل + +61 +00:05:51,230 --> 00:05:55,050 +الالديهيدس والكيتونز لحال و الأحمض الكربوكسيلية + +62 +00:05:55,050 --> 00:06:00,510 +ومشتقاتها لحال ليش هذا التصنيف اعتمادا على التفاعل + +63 +00:06:00,510 --> 00:06:05,670 +الأساسي لكل عائلة الالديهيدس والكيتونز تفاعلها + +64 +00:06:05,670 --> 00:06:09,630 +الأساسي ال addition الان شطرين كلكوا بتقولوا + +65 +00:06:09,630 --> 00:06:12,170 +addition و بعد شهر بتقولوا substitution لكن في + +66 +00:06:12,170 --> 00:06:17,730 +الامتحان الا نسبة تلاتين في المية من الطالباتييجوا + +67 +00:06:17,730 --> 00:06:21,450 +يشتغلوا بالعكس ويعملوا خطأ لان ما بيصدقوش انهم + +68 +00:06:21,450 --> 00:06:26,510 +مابيعملوا اخطاء مثلا هذه الـ C double bond O لو + +69 +00:06:26,510 --> 00:06:31,630 +بدنا نتخيلها هذه الديهايد ولا لا الديهايد محذوف اش + +70 +00:06:31,630 --> 00:06:35,130 +فلو بدى تم عليها التفاعل المفروض هذا الـ nitrogen + +71 +00:06:35,130 --> 00:06:38,830 +in nucleophile هاجم هنا اضيف على الـ C double bond + +72 +00:06:38,830 --> 00:06:42,730 +O صارت ال double bond single bond اذا هذه عملية + +73 +00:06:42,730 --> 00:06:49,220 +ايش؟صفة عندي هنا OH و جنبها NH غالبا إذا ال OH و + +74 +00:06:49,220 --> 00:06:54,000 +ال NH جنب بعض أو ممكن حتى OH مع CH تانية جنبها + +75 +00:06:54,000 --> 00:07:00,600 +يعملوا حذف للميّه OH مع H بلس الـ OH مع زوج + +76 +00:07:00,600 --> 00:07:03,960 +الإلكترونات مع H بلس بيعملوا double bond لو كانت + +77 +00:07:03,960 --> 00:07:06,820 +تنافس أن الـ OH تحدث H عن الـ nitrogen أو عن + +78 +00:07:06,820 --> 00:07:10,560 +الكرمون هتحدث عن الـ nitrogen وبناء على ذلك + +79 +00:07:10,560 --> 00:07:14,840 +النتيجة النهائية هتكون C double bond N هذا الكلام + +80 +00:07:14,840 --> 00:07:18,780 +كتير مر علينا يعني لما كنا ناخد تفاعلات ال amines + +81 +00:07:18,780 --> 00:07:23,220 +مع ال ketones تفاعلات ال oximes تفاعلات ال .. ال + +82 +00:07:23,220 --> 00:07:27,250 +hydrazonesكنا نقول C double bond O زي N H2 C + +83 +00:07:27,250 --> 00:07:31,250 +double bond N وننهي الموضوع واضح؟ هذه عملية ال + +84 +00:07:31,250 --> 00:07:34,390 +addition اللي بتتم في ال aldehydes او ال ketones + +85 +00:07:34,390 --> 00:07:41,170 +الان لو كان عندي C double bond O E star او acid او + +86 +00:07:41,170 --> 00:07:43,290 +اللي هي العائلة التانية acids and their + +87 +00:07:43,290 --> 00:07:48,090 +derivatives بتتم عملية ايش؟Substitution ان هذه + +88 +00:07:48,090 --> 00:07:53,430 +بتهاجم وبتطرد ال X وبناء على ذلك بيصير عنده C + +89 +00:07:53,430 --> 00:07:58,010 +double bond O in this case and H حسب النيوكليوفايل + +90 +00:07:58,010 --> 00:08:03,130 +لو كانت هذه OH بيكون C double bond O وبتصير + +91 +00:08:03,130 --> 00:08:05,810 +العائلات في الكيميا العضوية زي ما انتوا عارفينها + +92 +00:08:05,810 --> 00:08:09,330 +ال C double bond O جنب O يعني Cyclic E star + +93 +00:08:09,330 --> 00:08:14,430 +بيسموها لاكتون ال C double bond O جنب N Cyclic + +94 +00:08:14,430 --> 00:08:15,630 +Amide بيسموها + +95 +00:08:17,900 --> 00:08:23,960 +ماذا يسمونه Cyclic Amide؟ لكتم اللي موجود في حلقة + +96 +00:08:23,960 --> 00:08:28,700 +البنسالين الحلقة الربعية ال beta-lactam اللي + +97 +00:08:28,700 --> 00:08:35,060 +بتذكروا حلقة البنسالين فيها سيضة بال bond O و N و + +98 +00:08:35,060 --> 00:08:42,720 +هذه الحلقة مرتبطة بحلقة خماسية عشانك بيسموها beta + +99 +00:08:42,720 --> 00:08:45,880 +-lactam لأن هاي موقع Alpha و ال nitrogen هذا على + +100 +00:08:46,890 --> 00:08:53,710 +بيتا واضح فبنقول احنا بيتا لاكتامو وما إلى ذلك + +101 +00:08:53,710 --> 00:08:58,170 +بناء على ذلك بتكون بهذا الشكل اذا بدنا نكون + +102 +00:08:58,170 --> 00:09:04,170 +مظبوطين عشان نقول هاي alpha هاي beta وهنا حلقة + +103 +00:09:04,170 --> 00:09:10,740 +خماسية او حلقة سداسيةواضح؟ حلقة خماسية اللي هي + +104 +00:09:10,740 --> 00:09:14,720 +مشتقات البنسالين الأساسية لو بدنا نفس البنسالين + +105 +00:09:14,720 --> 00:09:18,200 +المشتقات الجديدة صاروا يبدلوا الخماسية بسوداسية + +106 +00:09:18,200 --> 00:09:22,300 +الـ cephalosporins وما إلى ذلك بكل الأحوال + +107 +00:09:22,300 --> 00:09:26,780 +اللاكتون واللاكتمز المفروض أشياء تكون معروفة عندكم + +108 +00:09:26,780 --> 00:09:31,220 +إذا أنا في السيطة بال bond O بدي أكون منتبه أن + +109 +00:09:31,220 --> 00:09:37,660 +التفاعل اللي عندي هل هو تفاعلAddition و لا تفاعل + +110 +00:09:37,660 --> 00:09:43,960 +Substitution الان لو بدنا ناخد امثلة على + +111 +00:09:43,960 --> 00:09:48,560 +نيوكليوفايل مختلفة الان النيوكليوفايل ال oxygen + +112 +00:09:48,560 --> 00:09:54,140 +النيوكليوفايل عادي عليه أزواج إلكترونات هذا سهل ال + +113 +00:09:54,140 --> 00:09:59,420 +nitrogen النيوكليوفايل عادي ال carbon بيكون + +114 +00:09:59,420 --> 00:10:07,990 +النيوكليوفايل ولكنبإيش؟ بمساعدة الجيران ليش؟ لأن + +115 +00:10:07,990 --> 00:10:12,190 +الكاربون بوضعه الطبيعي ماعليه أزواج إلكترونات + +116 +00:10:12,190 --> 00:10:16,950 +الكاربون بوضعه الطبيعي بيعمل أربع روابط ماعليه + +117 +00:10:16,950 --> 00:10:20,770 +أزواج إلكترونات الأكسجين وضعها الطبيعي في الدنيا + +118 +00:10:20,770 --> 00:10:26,270 +رابطتين وزوجين إلكترونات موجودة فكرة النيوكليوفير + +119 +00:10:26,270 --> 00:10:31,660 +فيها النيتروجينثلاث روابط وزوج إلكترونات لكن + +120 +00:10:31,660 --> 00:10:36,820 +الكربون أربع روابط إذا الكربون لما بدأ أجي أفكر + +121 +00:10:36,820 --> 00:10:43,620 +فيه وقت إيش بيشتغل in eucleophile بدي أتذكر ال + +122 +00:10:43,620 --> 00:10:48,240 +activation لل hydrogen اللي موجودة على الكربون + +123 +00:10:48,240 --> 00:10:56,040 +بحيث إنها تفقد كأحماض مر علينا إنه جنب السيضة بال + +124 +00:10:56,040 --> 00:11:05,650 +bondأو لما بيكون عندكم CH2 هذه بتكون activated CH2 + +125 +00:11:05,650 --> 00:11:13,470 +او CH3 الآن بيزيد ال activation لو كانت ال CH2كمان + +126 +00:11:13,470 --> 00:11:18,310 +C double bond O واضح؟ زي الـ malonic ester بيصير + +127 +00:11:18,310 --> 00:11:23,270 +سهل إنه هذه تفقد H plus وقتها بده يظل عنده carbon + +128 +00:11:23,270 --> 00:11:27,530 +minus صار عنده carbon in eucleophile واضح؟ طبعا + +129 +00:11:27,530 --> 00:11:31,770 +ممكن على C double bond O واحدة تم فقد هيدروجين + +130 +00:11:31,770 --> 00:11:37,250 +بالتأكيد زي تفاعل Aldol اتذكروا Aldol في ال + +131 +00:11:37,250 --> 00:11:42,030 +Acetaldehydeكان تم من هنا اتفقد الهيدروجين لكن + +132 +00:11:42,030 --> 00:11:49,010 +بكون بدي ايش strong base لكن هنا weaker base بتمشي + +133 +00:11:49,010 --> 00:11:54,110 +قاعدة اضعف بتمشي هنا بكون بدي قاعدة قوية الان بدل + +134 +00:11:54,110 --> 00:11:57,150 +السيطاب البندقه في عندى احتمالات تانية ايش اللي + +135 +00:11:57,150 --> 00:12:04,570 +ممكن يكون عندى؟ سيان يكون عندى سالفر يكون عندى + +136 +00:12:04,570 --> 00:12:11,120 +بنزينة في ال rainيكون عندى halogen كل هذا الكلام + +137 +00:12:11,120 --> 00:12:16,540 +لو انوجد كمان جنب ال CH2 بيساعد على ان هاد ال CH2 + +138 +00:12:16,540 --> 00:12:21,500 +تصير اشمالها activated وبالتالي باستعمال ال base + +139 +00:12:21,500 --> 00:12:28,240 +بتفقد ال proton فبصير عندى carbon nucleophile طيب + +140 +00:12:28,240 --> 00:12:33,190 +غيرالـ carbon enucleophile نتذكر ال carbon + +141 +00:12:33,190 --> 00:12:37,690 +enucleophiles مع بعض غير جنب ال C double bond O + +142 +00:12:37,690 --> 00:12:42,890 +وين ال carbon كمان بيكون enucleophile يعني قلنا + +143 +00:12:42,890 --> 00:12:46,690 +جنب ال C double bond O بمساعدة ال C double bond O + +144 +00:12:46,690 --> 00:12:50,590 +ومثلها أحيانا C double bond L ممكن و C double bond + +145 +00:12:50,590 --> 00:12:54,970 +C ممكن الكربون بيشغل ال enucleophile طب غير هذا + +146 +00:12:54,970 --> 00:13:02,170 +الكلام وين بيكونالـ Carbon Nucleophile مر علينا + +147 +00:13:02,170 --> 00:13:07,170 +الـ Greenyard Reagent احنا قلنا ان ال Greenyard R + +148 +00:13:07,170 --> 00:13:14,270 +مع إلكتروناتها بنعتبر ال Greenyard M G X العامل + +149 +00:13:14,270 --> 00:13:20,740 +الفعال فيه R مع إلكتروناتهافالـ Greenyard reagent + +150 +00:13:20,740 --> 00:13:25,780 +is a carbon-eucleophile طبعا زي الـ Greenyard + +151 +00:13:25,780 --> 00:13:29,220 +بتجيني الـ organometallics التانية لو كان ليثيام + +152 +00:13:29,220 --> 00:13:35,460 +المهم مع metal واضح؟ ال carbon مع metals فال + +153 +00:13:35,460 --> 00:13:38,360 +carbon بياخد زوج الإلكترونات و هي بيشتغلوا ال + +154 +00:13:38,360 --> 00:13:42,220 +eucleophile هذا أيضا carbon-eucleophile إيش كمان + +155 +00:13:42,220 --> 00:13:44,800 +مر علينا carbon-eucleophile؟ + +156 +00:13:47,060 --> 00:13:53,380 +الـ Acetylates يعني لو قلنا الـ R C triple bond CH + +157 +00:13:53,380 --> 00:13:58,840 +قلنا احنا ان ال terminal alkynes are acidic يعني + +158 +00:13:58,840 --> 00:14:05,160 +هذا في وجود strong base strong base ما هي ال + +159 +00:14:05,160 --> 00:14:09,460 +lithium ال strong base؟ شو هيفقد؟ ال H بس ال H + +160 +00:14:09,460 --> 00:14:13,500 +لحالها إذا دل عند زوج إلكترونات و ال carbon هنا + +161 +00:14:13,500 --> 00:14:18,670 +صارت إشمالها minusالان كل هذا الكلام اللى أخدناه + +162 +00:14:18,670 --> 00:14:23,090 +في ال organ ال chemistry بلحظة من اللحظات ممكن يمر + +163 +00:14:23,090 --> 00:14:27,230 +معنا عشان يكوّن carbon اليوكليوفايل يتفاعل على ال + +164 +00:14:27,230 --> 00:14:31,130 +C double bond ا و بدنا نكون من ذاكرينه واضح؟ على + +165 +00:14:31,130 --> 00:14:35,070 +سبيل المثال لو اتطلعنا على المركب اللى موجود + +166 +00:14:35,070 --> 00:14:42,870 +أمامنا لاحظوا كام CH2 موجودة فيههذه واحدة CH2 CH2 + +167 +00:14:42,870 --> 00:14:48,550 +هذه بين CW.O و Sulphur إذا هذه Activated ولا لأ + +168 +00:14:48,550 --> 00:14:53,490 +Activated هذه زيها بين CW.O و Sulphur إذا + +169 +00:14:53,490 --> 00:14:58,770 +Activated لاحظوا لما أنا بفعل مع Base احنا مختصرين + +170 +00:14:58,770 --> 00:15:03,630 +الكلام أول ما بيصير مع Base كأنه اعمل اتهانة minus + +171 +00:15:03,630 --> 00:15:09,170 +و minusواضح؟ الآن بعد هيك هذي لما بدا تيجي تتفعل و + +172 +00:15:09,170 --> 00:15:13,570 +تعمل رابطة هنا شو هيصير ال او؟ او اتش او اتش هنا + +173 +00:15:13,570 --> 00:15:21,380 +اتش احذفوا ميهO H مع H Double bond نفس الكلام على + +174 +00:15:21,380 --> 00:15:26,560 +الجهة التانية O H مع H Double bond او الكلام العام + +175 +00:15:26,560 --> 00:15:32,480 +اللى كنا نعرفه زمان انه لو التقى في النهاية H2 و C + +176 +00:15:32,480 --> 00:15:38,300 +Double bond O هى ال H2 مع ال O بيصير double bond + +177 +00:15:38,300 --> 00:15:42,180 +زى لما كنا نفعل C Double bond O مع H2 كيف كنا نكتب + +178 +00:15:42,180 --> 00:15:48,830 +التفاعل كمحصلةهي C double bond O كيتون او الديهايد + +179 +00:15:48,830 --> 00:15:54,170 +طبعا مع NH2 او RNH2 + +180 +00:15:54,170 --> 00:16:00,790 +عطول نحط C double bond N طبعا + +181 +00:16:00,790 --> 00:16:06,310 +هذا التفاعل ايش احنا بنسميه + +182 +00:16:06,310 --> 00:16:10,250 +ايوة + +183 +00:16:10,250 --> 00:16:12,190 +قوله صح addition + +184 +00:16:17,960 --> 00:16:22,500 +Elimination تفاعلين في بعض Addition elimination + +185 +00:16:22,500 --> 00:16:25,840 +لأن مش كل مرة بنذكر في ال addition elimination + +186 +00:16:25,840 --> 00:16:31,000 +خلاص شفنا N H2 مع C double bond O N H2 امين مع + +187 +00:16:31,000 --> 00:16:35,960 +الديهايد او كيتون C double bond N بس بتكون كتفاعل + +188 +00:16:35,960 --> 00:16:40,000 +تمت من خلال ال ايش ال addition elimination لأن هنا + +189 +00:16:40,000 --> 00:16:45,950 +ال CH2 زيها بالظبطعملة ال addition وعملة ال + +190 +00:16:45,950 --> 00:16:50,270 +elimination بالطريقة + +191 +00:16:50,270 --> 00:16:51,650 +اللى وضحناها لكم + +192 +00:17:00,720 --> 00:17:08,560 +هنا في عندنا مثال تاني هذا المثال التاني بنسمي + +193 +00:17:08,560 --> 00:17:13,540 +احنا بالكنور synthesis of furan تحضير الفيوران + +194 +00:17:13,540 --> 00:17:18,680 +بطريقة يعني هدول علماء بالكنور بنستعمل فيها one + +195 +00:17:18,680 --> 00:17:22,520 +four-dicarbonyl compounds لما انا بدي اجي اقول + +196 +00:17:22,520 --> 00:17:27,750 +واحد اتنين تلاتة اربع يعني ال C double bond Oأو + +197 +00:17:27,750 --> 00:17:31,730 +الـ Dicarbonyl Compounds على أي مواقع نسبية على + +198 +00:17:31,730 --> 00:17:35,830 +واحد وأربعة حتى لو كانوا في الجزء مش على واحد + +199 +00:17:35,830 --> 00:17:39,980 +وأربعة بيسميهم إيش احنا؟one four يعني افترضت كأني + +200 +00:17:39,980 --> 00:17:45,500 +انا عندي two carbons one two three four five six + +201 +00:17:45,500 --> 00:17:48,640 +seven eight يعني افترضت ان كل هذه السلسلة تمان + +202 +00:17:48,640 --> 00:17:52,040 +كربونات لكن هذا لما بنسميه .. شو بنقول عنه؟ one + +203 +00:17:52,040 --> 00:17:55,200 +four one four dicarbonyl compounds مانجيش نقول عنه + +204 +00:17:55,200 --> 00:17:59,840 +مثلا three seven or whateverواضح الفكرة؟ هذا الـ 1 + +205 +00:17:59,840 --> 00:18:03,120 +,4-dicarbonyl compounds الان هذا الـ 1,4 + +206 +00:18:03,120 --> 00:18:07,900 +-dicarbonyl compounds بنخليه يسكر الـ C double + +207 +00:18:07,900 --> 00:18:12,260 +bond O على C double bond O تانيا بنضيف شوية حامض + +208 +00:18:12,260 --> 00:18:15,840 +الحامض عارفين انه بيعمل catalysis للـ C double + +209 +00:18:15,840 --> 00:18:20,540 +bond O بساعدها في الإغلاق الان انتوا حرين تفهموا + +210 +00:18:20,540 --> 00:18:24,910 +ان ال double bond هناالـ Eucleophile هاجمت على الـ + +211 +00:18:24,910 --> 00:18:28,450 +Carbon يعني الـ Bi-bond الـ Eucleophile هاجمت على + +212 +00:18:28,450 --> 00:18:31,850 +الـ Carbon على العين والرأس اللي مش حابة تفهم + +213 +00:18:31,850 --> 00:18:37,290 +هالكلام تتذكر ان هذا كمان انا ممكن ارسمله ايش؟ + +214 +00:18:37,290 --> 00:18:42,270 +Enol Form ممكن ارسمله Enol Form و اتخيل ان هذه الـ + +215 +00:18:42,270 --> 00:18:50,600 +Oهاجمت هنا صار عندي OH الان لما بيصير هنا عندي OH + +216 +00:18:50,600 --> 00:18:56,860 +مع H مجاورة بدون يعملوا حذف صار double bond فلو + +217 +00:18:56,860 --> 00:19:00,760 +رسمنا ال E وال form لواحدة منهم خلينها تسكر على C + +218 +00:19:00,760 --> 00:19:03,780 +double bond وعملت رابطة + +219 +00:19:05,190 --> 00:19:11,490 +و OH مع H صار عنده الفيوران فبصير احدى طرق تحضير + +220 +00:19:11,490 --> 00:19:15,790 +الفيوران حقيقة بالكنور سينثسيز of فيوران لو اجينا + +221 +00:19:15,790 --> 00:19:19,670 +نسألكم بالكنور سينثسيز of فيوران is a substitution + +222 +00:19:19,670 --> 00:19:25,370 +reaction no it is an addition reaction حولنا فيه + +223 +00:19:25,370 --> 00:19:31,460 +صيغة بالبنط O إلى OH هذا هو ال additionواضح؟ this + +224 +00:19:31,460 --> 00:19:37,360 +is an addition reaction هذا تفاعل النيوكليوفايل + +225 +00:19:37,360 --> 00:19:43,800 +اللي موجود فيه الأكسجين والإلكتروفايل الـC double + +226 +00:19:43,800 --> 00:19:51,480 +bond O الآن ممكن بطريقة بالكنور سينثسيز نحضر ال + +227 +00:19:51,480 --> 00:19:57,680 +بيروت أيضا من ال 1,4-dicarbonyl compoundsيعني ال 1 + +228 +00:19:57,680 --> 00:20:01,580 +,4-dicarbonyl compounds هين حضرنا منهم أول إيش إيش + +229 +00:20:01,580 --> 00:20:06,020 +الفيورام ممكن نحضر منهم ال by role كيف بدنا نعمل + +230 +00:20:06,020 --> 00:20:10,740 +هذا الكلام بنيجي الفاعل الأمين مع ال 1,4 + +231 +00:20:10,740 --> 00:20:15,060 +-dicarbonyl compounds الآن ع طول ال NH2 مع ال C + +232 +00:20:15,060 --> 00:20:19,780 +double bond O شو بدهم يعملولي addition followed by + +233 +00:20:19,780 --> 00:20:26,190 +elimination C double bond NR هذا عبارة عنامين ال C + +234 +00:20:26,190 --> 00:20:31,710 +double bond ان امين اخدنا tautomerism اللي هي امين + +235 +00:20:31,710 --> 00:20:36,890 +اينامين اين يعني في عندي الكيل و امين اللي هي ان + +236 +00:20:36,890 --> 00:20:42,230 +اتش عادية فهذا الامين هذا الانامين which is more + +237 +00:20:42,230 --> 00:20:47,130 +stable بشكل عام هذه زي ال keto enol tautomerism + +238 +00:20:47,990 --> 00:20:50,890 +متذكرين كيتو اينو التوتمريزم اللي مش متذاكرة + +239 +00:20:50,890 --> 00:20:54,450 +بيرجعها وكان ال more stable form بالأليفات ال + +240 +00:20:54,450 --> 00:20:59,730 +compounds الكيتون الان برضه في عندي توتمريزم تالي + +241 +00:20:59,730 --> 00:21:01,190 +شبه ال اين + +242 +00:21:03,900 --> 00:21:07,720 +الإمين والإينامين هذا هو الشكل المستقل في شكل + +243 +00:21:07,720 --> 00:21:11,340 +الإينامين فأنا عملت الإيمين وبيعمل توتماريزم + +244 +00:21:11,340 --> 00:21:15,680 +للإينامين الآن هي ال يوكليوفايل عندى هى في عند ال + +245 +00:21:15,680 --> 00:21:18,980 +يوكليوفايل هذا ال يوكليوفايل بيعمل addition ع + +246 +00:21:18,980 --> 00:21:26,000 +السيدة بالبنده O ولا لأ شو هتصفه؟ OH مع H + +247 +00:21:28,540 --> 00:21:33,180 +dehydration بحذف ميه ال O H مع أزواج إلكتروناتها + +248 +00:21:33,180 --> 00:21:36,420 +ما قدش plus يعني كأنه بتكون .. تتخيلوا أن هذه + +249 +00:21:36,420 --> 00:21:45,100 +بتلفها تطرد واضح؟ صار عندي by rule صار عندي by + +250 +00:21:45,100 --> 00:21:51,340 +rule إذا هي ال one-fourth dicarbonyl compound إيش + +251 +00:21:51,340 --> 00:21:59,200 +حضرنا منه؟ furan وحضرنا منه؟by role الـ A هيمر + +252 +00:21:59,200 --> 00:22:04,240 +معنا مرة تانية أنه ممكن نحضر منه ثيوفين كمان كيف + +253 +00:22:04,240 --> 00:22:08,620 +ممكن نحضر منه ثيوفين أنه احنا في البداية بنعمل + +254 +00:22:08,620 --> 00:22:13,080 +تفاعل له مع ال sulfur يعني بنخلي هذا تصير sulfur و + +255 +00:22:13,080 --> 00:22:17,520 +زي ما سكرنا في حالة ال oxygen بنسكر في حالة ال + +256 +00:22:17,520 --> 00:22:17,860 +sulfur + +257 +00:22:20,650 --> 00:22:24,330 +سهل أن نحوّل C double bond O إلى C double bond S + +258 +00:22:24,330 --> 00:22:30,990 +باستعمال Reagents زي الـ B2S5، Diphosphorus + +259 +00:22:30,990 --> 00:22:34,710 +Mintesulfide أو في Reagent تاني اسمه Lewison's + +260 +00:22:34,710 --> 00:22:40,010 +Reagent Lewison's Reagent هذا Reagent مختصر حوّل + +261 +00:22:40,010 --> 00:22:45,170 +الـ C double bond O إلى C double bond S + +262 +00:22:47,740 --> 00:22:54,520 +Lewison's reagent ممكن تشوفوه في الموسوعات او ما + +263 +00:22:54,520 --> 00:22:58,060 +إلى ذلك عبارة عن aromatic compounds في كذا sulfur + +264 +00:22:58,060 --> 00:23:03,300 +لو فعلناه وضيفته باختصار انه يحول C double bond O + +265 +00:23:03,300 --> 00:23:07,900 +الى C double bond S فإذا قرأته قال اه يعني this is + +266 +00:23:07,900 --> 00:23:10,140 +Lewison's reagent + +267 +00:23:13,410 --> 00:23:16,830 +واضح؟ إذا لاحظوا هاي ال one-fourth dicarbonyl + +268 +00:23:16,830 --> 00:23:20,410 +compounds للناس اللي بيحبوا الامتحانات بيصير سؤال + +269 +00:23:20,410 --> 00:23:22,690 +typeical لإنه نقولهم والله من one-fourth + +270 +00:23:22,690 --> 00:23:27,090 +dicarbonyl compounds حضرولنا if you run by role, + +271 +00:23:27,310 --> 00:23:28,210 +if you run by role, if you run by role, if you run + +272 +00:23:28,210 --> 00:23:28,230 +by role, if you run by role, if you run by role, + +273 +00:23:28,230 --> 00:23:28,290 +if you run by role, if you run by role, if you run + +274 +00:23:28,290 --> 00:23:31,730 +by role, if you run by role, if you run by role, + +275 +00:23:31,810 --> 00:23:33,410 +if you run by role, if you run by role, if you run + +276 +00:23:33,410 --> 00:23:33,410 +by role, if you run by role, if you run by role, + +277 +00:23:33,410 --> 00:23:33,410 +if you run by role, if you run by role, if you run + +278 +00:23:33,410 --> 00:23:33,410 +by role, if you run by role, if you run by role, + +279 +00:23:33,410 --> 00:23:34,030 +if you run by role, if you run by role, if you run + +280 +00:23:34,030 --> 00:23:38,310 +by role, if you run by role, ifهي مثال إضافي على + +281 +00:23:38,310 --> 00:23:41,910 +ال by role هو نفس المثال السابق أنه جيبنا احنا + +282 +00:23:41,910 --> 00:23:45,450 +امين مع واحدة من ال c double bond o's يعني كأنه + +283 +00:23:45,450 --> 00:23:51,250 +هنا صار an R امين in Amin وخلوها تسكر هنا نفس + +284 +00:23:51,250 --> 00:23:57,910 +المثال السابق تماما لكن صار ال by role ضمن حلقة + +285 +00:23:57,910 --> 00:23:59,930 +أكبر + +286 +00:24:06,170 --> 00:24:12,310 +أيضا من التفاعلات الإضافية على هذا الموضوع اللي هي + +287 +00:24:12,310 --> 00:24:18,070 +التفاعل على الـ CH3O Synthesis of Indole الان هنا + +288 +00:24:18,070 --> 00:24:23,310 +بيجوا بيشتغلوا على ال CH3 هل يا ترى هذي ال CH3 + +289 +00:24:23,310 --> 00:24:35,490 +اكتفيت و لا لأ تنسوش انتوا انه احنا قلنا CH3 CH3 + +290 +00:24:38,030 --> 00:24:43,750 +Jump C double bond O اكتفيت و لا لأ الان ال C + +291 +00:24:43,750 --> 00:24:46,930 +double bond O او C double bond C نفس الفكرة + +292 +00:24:46,930 --> 00:24:52,610 +بيعملوا من ناحية إلكترونيةواضح؟ يعني هذه CH3 في + +293 +00:24:52,610 --> 00:25:00,070 +النهاية جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +294 +00:25:00,070 --> 00:25:00,690 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +295 +00:25:00,690 --> 00:25:01,850 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +296 +00:25:01,850 --> 00:25:01,890 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +297 +00:25:01,890 --> 00:25:01,890 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +298 +00:25:01,890 --> 00:25:01,930 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +299 +00:25:01,930 --> 00:25:01,930 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +300 +00:25:01,930 --> 00:25:01,930 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +301 +00:25:01,930 --> 00:25:17,550 +جام CH3 جام CH3 جام CH3 جام CH3 جام CH3 + +302 +00:25:17,550 --> 00:25:24,370 +جام CHلاحظوا كام شغل استعملناه strong base و heat + +303 +00:25:24,370 --> 00:25:30,810 +في النهاية خلّينها دي CH2- و خلّينها تضيف على C + +304 +00:25:30,810 --> 00:25:34,110 +double bond O و ماتعملش هنا المركّب لأنه جنب + +305 +00:25:34,110 --> 00:25:39,230 +aromatic كامد حتى يعني بمعنى لما يضيف هنا حيصير + +306 +00:25:39,230 --> 00:25:46,610 +عنده OH و جنبها NH و جنبها هنا CH في كل الأحوال + +307 +00:25:46,610 --> 00:25:54,210 +الحقيقية في OHمع H هيطلع عنده ال Indole هذا عبارة + +308 +00:25:54,210 --> 00:26:00,810 +عن تفاعل carbon nucleophile مع C double bond O + +309 +00:26:00,810 --> 00:26:04,930 +المثال + +310 +00:26:04,930 --> 00:26:12,490 +اللي هنا مثال جميلNitro وع طول كلكم بتتذكروا كيمية + +311 +00:26:12,490 --> 00:26:16,130 +البنزين والانليلين ال Nitro بال reduction هو + +312 +00:26:16,130 --> 00:26:22,490 +الانليلين احنا كيف بنحضره reduction of Nitro بنزين + +313 +00:26:22,490 --> 00:26:26,150 +بناء على ذلك لو انا أخدت ال Nitro compound هذا بال + +314 +00:26:26,150 --> 00:26:30,890 +reduction شو حيصير عندى؟ ال NH2 عبارة عن ال + +315 +00:26:30,890 --> 00:26:36,430 +nucleophile وين بدو يهاجم؟ على ال C double bond O + +316 +00:26:36,430 --> 00:26:46,300 +بهذا الشكل صارتو اتش و اتش مع اتش بيعمل + +317 +00:26:46,300 --> 00:26:51,940 +double bond و بيسكر صار أيضا عندنا اندول هم لاحظين + +318 +00:26:51,940 --> 00:26:57,560 +كيف بنصل لمركب بطرق مختلفة لكن بنفس الفكرة يعني + +319 +00:26:57,560 --> 00:27:01,220 +الاندول بهذه الطريقة و من هذا المركب و من هذا + +320 +00:27:01,220 --> 00:27:08,340 +المركب طبعا مختلفين في إش موجود عندهم في ال R و ال + +321 +00:27:08,340 --> 00:27:16,270 +Rواضح؟ يمكن هنا خليني أروح لفكرة أساسية كتير في ال + +322 +00:27:16,270 --> 00:27:20,430 +heterocycle chemistry أنه ليش أنا جاعد كل مرة بحضر + +323 +00:27:20,430 --> 00:27:25,010 +ال endol بطريقة معينة أو لما بدي أجي أخد الفيوران + +324 +00:27:25,010 --> 00:27:29,870 +بدي أحضر .. أخدلي عشر .. عشر أو خمستاشر synthesis + +325 +00:27:29,870 --> 00:27:35,540 +of الفيورانالكيميا الحلقية .. الكيميا الحلقية + +326 +00:27:35,540 --> 00:27:42,300 +بتختلف عن كيمية البنزين اختلاف أساسي وجوهري جدا + +327 +00:27:42,300 --> 00:27:49,200 +كيمية البنزين مبناها ككيمية مبنية على ان في عند + +328 +00:27:49,200 --> 00:27:57,640 +حلقة البنزين موجودةتمام؟ و ايش انا لازمني على حلقة + +329 +00:27:57,640 --> 00:28:04,900 +البنزين بابدأ من بنزين و بصير اضيف اول substituent + +330 +00:28:04,900 --> 00:28:08,600 +و تاني substituent و باخد الأفكار اللي اتعلمتها + +331 +00:28:08,600 --> 00:28:11,160 +activating groups و deactivating groups و + +332 +00:28:11,160 --> 00:28:14,020 +orthopara directing groups و metadirecting groups + +333 +00:28:14,020 --> 00:28:19,580 +لكن منطلقي لتحضير ال substituted بنزين يعني لو بدى + +334 +00:28:19,580 --> 00:28:29,330 +مركب زي هذا مثلاCH3 NO2 هذا من أين أنا بحضره من + +335 +00:28:29,330 --> 00:28:33,950 +البنزين ببدأ البنزين الكيلاشن المثل بتودي + +336 +00:28:33,950 --> 00:28:38,590 +أورثوبارا و بعدين نيتريشن منطلقي الحلقة اللي زيه + +337 +00:28:38,590 --> 00:28:43,910 +الآن ال heterocyclic chemistry لا تنطلق من الحلقات + +338 +00:28:45,030 --> 00:28:49,890 +طبعا يعني اللي بده في ال heterocyclic chemistry + +339 +00:28:49,890 --> 00:28:57,030 +substituted فيوران على سبيل المثال ربما نادر جدا + +340 +00:28:57,030 --> 00:29:01,410 +نفترض هنا عند مجموعة X أو Y ان يكون التفكير اللي + +341 +00:29:01,410 --> 00:29:05,810 +عنده التفكير اللي عنده ان ابدأ ب فيوران و احط + +342 +00:29:05,810 --> 00:29:11,800 +المجموعات اللي بدك اياهم هناالتفكير اللي عنده أن + +343 +00:29:11,800 --> 00:29:19,000 +هذا الفيوران كيف بتحضر أصلا بحط المجموعات عليه من + +344 +00:29:19,000 --> 00:29:24,700 +قبل التحضير من قبل عملية إغلاق يعني لو كنت أوضح + +345 +00:29:24,700 --> 00:29:30,060 +أنا أرجع للمثال اللي هنا لاحظوا بهذا المثال كم + +346 +00:29:30,060 --> 00:29:35,940 +مجموعة أنا عندي على الفيوران أربع مجموعاتولا حد في + +347 +00:29:35,940 --> 00:29:40,180 +الدنيا بيفكر انه لما بده يحضر هذا المركب .. لما + +348 +00:29:40,180 --> 00:29:46,260 +يحضر هذا المركب انه يجيبأفيران و يبعد الف باجي + +349 +00:29:46,260 --> 00:29:50,160 +نضيف المجموعة كذا كذا كذا كل المجموعات اللي بدي + +350 +00:29:50,160 --> 00:29:56,840 +إياها بضيفها قبل عملية إيش الإغلاق بجيب مركب فيه C + +351 +00:29:56,840 --> 00:30:00,220 +double bond O جب و ال R هادي و أنا C double bond O + +352 +00:30:00,220 --> 00:30:02,700 +جب هذا ال R و هذا ال R بكون عامله و هذا عامله + +353 +00:30:02,700 --> 00:30:07,820 +بالكيميا العادية و بعدين بسكر فال substituents في + +354 +00:30:07,820 --> 00:30:13,580 +ال heterocyclic compounds بتلحطقبل الإغلاق في الـ + +355 +00:30:13,580 --> 00:30:19,080 +aromatic compounds بتنحط غالبا بعد الإغلاق يعني + +356 +00:30:19,080 --> 00:30:23,700 +منطلقنا هناك البنزين بس احنا هنا ما بننطلق من حلقة + +357 +00:30:23,700 --> 00:30:27,580 +نقول ال parent ونصير نحضر منها وعشان هيك ال + +358 +00:30:27,580 --> 00:30:31,760 +heterocyclic synthesis مختلفة بفكرته عن أن الواحد + +359 +00:30:31,760 --> 00:30:37,050 +يكون حاضر aromatic compoundsاللي بده شغلة بحط + +360 +00:30:37,050 --> 00:30:41,930 +الأشياء وين؟ على القطع اللي بده يعمل عليها الإغلاق + +361 +00:30:41,930 --> 00:30:46,190 +بحط الأشياء اللي لازمها على القطع الأصلية اللي بده + +362 +00:30:46,190 --> 00:30:50,410 +يعمل لها cyclization مش بيحضر حلقة أو بروح بشتري + +363 +00:30:50,410 --> 00:30:53,570 +payroll أو furan وبعدين بيقول بده أعمل عليه تفاعل + +364 +00:30:53,570 --> 00:30:58,830 +هذا الكلام في ال heterocyclic compounds قليل جدًا + +365 +00:30:58,830 --> 00:31:06,460 +واضح الفكرة؟يعني هاي مثلا الدول عليه substituents + +366 +00:31:06,460 --> 00:31:11,880 +معينة بدنا نحطها من البداية و بعدين نعمل ال + +367 +00:31:11,880 --> 00:31:18,670 +cycleization اللي موجود عندنانشوف مراكب جديد مثلا + +368 +00:31:18,670 --> 00:31:24,650 +بنزو فيوران نشوف مراكب بنزو فيوران هاي ال بنزو + +369 +00:31:24,650 --> 00:31:31,390 +فيوران هذا اللي موجود عندنا عليه two substituents + +370 +00:31:31,390 --> 00:31:36,010 +هنا يعني لو افترضنا ان هذا ال R مثل خليني احط + +371 +00:31:36,010 --> 00:31:41,570 +فرضيا ان هذا ال R CH3 و هذا ال R C double bond O + +372 +00:31:41,570 --> 00:31:43,630 +خليني اقول اثل + +373 +00:31:48,440 --> 00:31:56,400 +واضح؟ مابفكرش انا ان هذا المركب اجي احضره من + +374 +00:31:56,400 --> 00:32:00,820 +بنزوفيوران و بعدين اقول كيف بده احط ال CH3 و كيف + +375 +00:32:00,820 --> 00:32:08,650 +بده احط ال CO2 .. ال C double bond O إثلواضح؟ لأ + +376 +00:32:08,650 --> 00:32:13,630 +باجي من نقطة البداية لما بصمم ال synthesis بحطها + +377 +00:32:13,630 --> 00:32:17,970 +دول الأشياء الان لو بدأت بفينول هذا المركب عبارة + +378 +00:32:17,970 --> 00:32:23,110 +عن ايش؟ فينول و الفينول عليه C double bond O R + +379 +00:32:23,110 --> 00:32:29,970 +وجدت لما انا بحطها بخليها تكون C double bond O CH3 + +380 +00:32:29,970 --> 00:32:37,050 +صار عندي سؤال ان كيف تحضر هذا المركب انت؟واضح؟ + +381 +00:32:37,050 --> 00:32:41,750 +يعني بيصير سؤالي ك organ ال chemistry أنه أنا هذا + +382 +00:32:41,750 --> 00:32:47,370 +المُركّب لازمني وجدت هذا لأنه مشتقت بنزين، بترجع + +383 +00:32:47,370 --> 00:32:51,770 +لكمية البنزين، كيف ممكن نحضر هذا المُركّب؟ طبعا + +384 +00:32:51,770 --> 00:32:56,530 +هتتذكروا أن ال acidity group بنقدر نحطها، لكن ال + +385 +00:32:56,530 --> 00:33:02,500 +OHعادة لما بنحطها بنعمل نيترو والنيترو نحوله + +386 +00:33:02,500 --> 00:33:07,060 +لانيلين والانيلين لديازونيوم سولت والديازونيوم + +387 +00:33:07,060 --> 00:33:12,360 +سولت مع H بلس نخليه فينول الان الفينول اورثو بارا + +388 +00:33:12,360 --> 00:33:16,080 +directing group مثلا او الامين اورثو بارا + +389 +00:33:16,080 --> 00:33:20,460 +directing group له واضح الفكرة كيف؟ اه الان هذا + +390 +00:33:20,460 --> 00:33:26,330 +الكلام اعمله وحطينا CH3N ابني جهانا فاعلهذا الجزء + +391 +00:33:26,330 --> 00:33:32,790 +مع PR CH2 C double bond OR يعني هذه عبارة عن ايش C + +392 +00:33:32,790 --> 00:33:38,550 +double bond OR تانية الان لو انا بدي هذه اثل من + +393 +00:33:38,550 --> 00:33:43,670 +البداية بحطها اثل لو بديها مثل من البداية بحطها + +394 +00:33:43,670 --> 00:33:53,890 +مثل يعني انا حطيت ايشالان لاحظوا لدي CH2 حاملة بار + +395 +00:33:53,890 --> 00:34:00,410 +و OH هذا عبارة عن اليوكليوفايل مار علي لو خلطته مع + +396 +00:34:00,410 --> 00:34:05,590 +بعض ال substitution أسألتوا + +397 +00:34:05,590 --> 00:34:10,130 +substitution غالبا لأن هذه primary صار عندكم O + +398 +00:34:14,140 --> 00:34:21,140 +CH2C double bond O إفل الان لما أستعمل ال base CH2 + +399 +00:34:21,140 --> 00:34:23,860 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +400 +00:34:23,860 --> 00:34:36,740 +CH2 CH2 + +401 +00:34:41,310 --> 00:34:46,530 +Elimination طلع المركّب اللي عنده شفتوا كيف نظام + +402 +00:34:46,530 --> 00:34:49,590 +ال synthesis في ال heterocyclic chemistry ان + +403 +00:34:49,590 --> 00:34:55,450 +المجموعات اللي بتديها على الناتج بابدأ من البداية + +404 +00:34:55,450 --> 00:35:02,110 +أخليها تكون موجودة عنده واضح؟ من البداية بابدأ + +405 +00:35:02,110 --> 00:35:05,890 +أخليها تكون موجودة عنده يعني لو مثلا افترضنا أن + +406 +00:35:05,890 --> 00:35:12,420 +طالبة في الأساس مهتمة أن هذه المجموعة تكون إثلأول + +407 +00:35:12,420 --> 00:35:15,840 +ما بدها تحضر هنا بدل ما تجيب ال reagent اللي + +408 +00:35:15,840 --> 00:35:26,600 +اتفعله هنا يكون CH3 OCl CH3 هتجيب CH3 OCl إثل + +409 +00:35:30,990 --> 00:35:35,170 +فالمجموعات عادة بنحطها من الأول انما مافي عندنا في + +410 +00:35:35,170 --> 00:35:39,190 +ال heterocyclic chemistry ان اقول بحضر الحلقة نقية + +411 +00:35:39,190 --> 00:35:42,570 +او باشتريها شراية وبعدين اعمل عليها substitution + +412 +00:35:42,570 --> 00:35:49,590 +فهذا مبدأ عام عندنا في موضوع ال heterocyclic + +413 +00:35:49,590 --> 00:35:56,430 +synthesis واخد الأمثلة الان + +414 +00:35:56,430 --> 00:36:02,740 +نجي لهذا المركبأيزوكزازول وهذا أيزوكزازول عليه + +415 +00:36:02,740 --> 00:36:08,360 +مجموعتين R لاحظوا كيف التحضير تبعه لو أخدنا احنا + +416 +00:36:08,360 --> 00:36:11,680 +one three-dicarbonyl compound + +417 +00:36:15,050 --> 00:36:21,750 +يعني هي carbon واحد اتنين تلاتة كأننا بنقول ان هذي + +418 +00:36:21,750 --> 00:36:26,850 +C double bond O و هذي C double bond O هي واحد + +419 +00:36:26,850 --> 00:36:31,750 +اتنين تلاتة اذا هذا one three-dicarbonyl compound + +420 +00:36:31,750 --> 00:36:38,470 +ولا لأ طيب لو فعلته مع ان H2OH هيدروكسلامين مع + +421 +00:36:38,470 --> 00:36:42,290 +كيتون ايش بيعطيني على طول اكزين + +422 +00:36:44,870 --> 00:36:48,390 +Hydroxylamine مع كيتون خليه يتفعل على هذا الـ C + +423 +00:36:48,390 --> 00:36:53,570 +double bond O هتصير C double bond N O H This is N + +424 +00:36:53,570 --> 00:36:59,910 +أكزيم وهذه C double bond O موجودة هنا الآن هذه الـ + +425 +00:36:59,910 --> 00:37:09,010 +on-eucleophile ممكن تتسكر هنا وتعمل عنده؟ OH مع H + +426 +00:37:09,010 --> 00:37:16,170 +elimination إيش صار عندك؟ isoxazoleلاحظوا طبعا هذا + +427 +00:37:16,170 --> 00:37:23,310 +الكلام لناس بدهم يتخيلوا انهم بدهم يتعبوا شوية + +428 +00:37:23,310 --> 00:37:27,950 +بيصير جزء من التفكير اللي عندهم يا تورا لو ايجا و + +429 +00:37:27,950 --> 00:37:32,390 +سألني how can you prepare this compound؟ بدكوا + +430 +00:37:32,390 --> 00:37:37,590 +تبدو في ال ايش ال disconnection approachلو قلكوا + +431 +00:37:37,590 --> 00:37:42,090 +كيف ممكن تحضر هذا المركب بدكوا تبدو في ال + +432 +00:37:42,090 --> 00:37:44,690 +disconnection approach الان في ال disconnection + +433 +00:37:44,690 --> 00:37:49,370 +approach بدوا يبدأ يصير معروف عندكم انه اول قطع + +434 +00:37:49,370 --> 00:37:52,430 +ممكن تعملوا من هنا و ترجعوا هذه الى c double bond + +435 +00:37:52,430 --> 00:37:58,810 +o and + +436 +00:37:58,810 --> 00:38:06,600 +o h هذا القطع الاولدائما جامبلين يوكل يو فاي + +437 +00:38:06,600 --> 00:38:12,280 +بإمكانكوا تعملوا قطع و ترجعوا هذه الى C double + +438 +00:38:12,280 --> 00:38:16,120 +bond O يعني كأن هذه كانت OH OH ال OH كانت C double + +439 +00:38:16,120 --> 00:38:19,720 +bond O بعد هيك ممكن تعملوا القطع التاني + +440 +00:38:22,880 --> 00:38:26,920 +واضح؟ فمعظم هذه الأمثلة اللي موجودة بإمكانكوا + +441 +00:38:26,920 --> 00:38:31,280 +انتوا تعملوا تدريب عليها انه لو اجت اه مااحنا + +442 +00:38:31,280 --> 00:38:36,760 +عارفين انه كل c double bond n شو كان أساسها؟ c + +443 +00:38:36,760 --> 00:38:42,220 +double bond o and h2هذه ال O اللي جنب C double + +444 +00:38:42,220 --> 00:38:48,160 +bond C او بشكل عام عشان اساعدكوا للمستقبل وين + +445 +00:38:48,160 --> 00:38:52,480 +بتشوفوا؟ وين بتشوفوا في ال disconnection approach؟ + +446 +00:38:52,480 --> 00:38:58,620 +C double bond C و جنب هاليوكليوفايل ما تبقى بره + +447 +00:38:58,620 --> 00:39:03,980 +بيقولكوا كيف هذا اتحضر Carbohydrate بدكوا؟ على طول + +448 +00:39:03,980 --> 00:39:07,380 +يكون التفكير تبعكم ان هذا + +449 +00:39:10,460 --> 00:39:16,720 +كان C double bond O وهنا كان لينيو كليو فاير + +450 +00:39:16,720 --> 00:39:23,580 +عارفين و هذا سهل معناهالـ Retrosynthesis فتطلعوا + +451 +00:39:23,580 --> 00:39:28,420 +على هذه الفكرة الجيدة يعني هذا الجزء من الجزء .. + +452 +00:39:28,420 --> 00:39:33,620 +هذا الجزء من الجزء احفظوه ان الـ C double bond C + +453 +00:39:33,620 --> 00:39:38,620 +اللي جنبها نيوكليوفايل بقدر انا اقول انه حصلها C + +454 +00:39:38,620 --> 00:39:43,620 +double bond O نيوكليوفايل بهذا الشكل واضحة هذه + +455 +00:39:43,620 --> 00:39:44,260 +الفكرة؟ + +456 +00:39:54,240 --> 00:40:00,560 +بجينا cyclization جديد هذا ال cyclization بنقوله + +457 +00:40:00,560 --> 00:40:04,320 +cyclization onto an ortho position of a بنزين ring + +458 +00:40:04,320 --> 00:40:11,520 +الإغلاق على موقع أورثو من حلقة البنزين وهذا النوع + +459 +00:40:11,520 --> 00:40:16,110 +من ال cyclization بيعطينا fused ringsيعني كتير جدا + +460 +00:40:16,110 --> 00:40:21,850 +لما بتشوفوا ال fused rings اول ما تفكروا فيهم + +461 +00:40:21,850 --> 00:40:26,650 +فكروا بهذا ال cyclization اللي هو ال cyclization + +462 +00:40:26,650 --> 00:40:33,470 +على موقع Ortho الان ايش قصة موقع Ortho هذا ببساطة + +463 +00:40:33,470 --> 00:40:36,850 +ال ortho position يعني لو هى .. هى انا عندي ابدال + +464 +00:40:36,850 --> 00:40:40,490 +من هذه النقطة وين موقع Ortho ال ortho position + +465 +00:40:40,490 --> 00:40:46,320 +بتكون تاعتبروه ان هو ال nucleophileالأورثو بوزيشن + +466 +00:40:46,320 --> 00:40:53,820 +اكتس از اليوكليوفايل الأورثو بوزيشن اكتس از + +467 +00:40:53,820 --> 00:40:57,840 +اليوكليوفايل واضح هذا الفكرة يعني لما اجي انا + +468 +00:40:57,840 --> 00:41:03,520 +اتخيل هذا الجزيء ان هذا ال intermediate هي موضوعي + +469 +00:41:03,520 --> 00:41:07,480 +لكن خلينا نشوف كيف اتكونت اتكونت من أنيلين هي + +470 +00:41:07,480 --> 00:41:16,140 +الانيلين شايفينه؟ فين السكرته على 1,3-dicarbonyl + +471 +00:41:16,140 --> 00:41:20,800 +compounds R,CWBond O,CH2,CWBond OR يعني الـCWBond + +472 +00:41:20,800 --> 00:41:25,860 +O اللي هنا مع الـNH2 عملت ليه؟ CWBond N هذه خطوة + +473 +00:41:25,860 --> 00:41:30,520 +تحضيرية مش خطوة إغلاق حلقة هذه كيلية عادية CWBond + +474 +00:41:30,520 --> 00:41:35,480 +O مع NH2 أصل هذه الآن اللي بهمني أنا في + +475 +00:41:35,480 --> 00:41:37,640 +الـcyclization اللي هي + +476 +00:41:41,310 --> 00:41:46,970 +هذه الآن هنا بإمكانكم تفهموا الموضوع ان هذه ال + +477 +00:41:46,970 --> 00:41:51,990 +double bond بإمكانها تيجي تهاجم هنا وتعمل addition + +478 +00:41:51,990 --> 00:41:56,050 +او H تعمل addition بعد هي بتفقد ال H اللي هنا + +479 +00:41:56,050 --> 00:42:03,790 +بترجع هذه واضح الفكرة يعني هذه ال double bond + +480 +00:42:03,790 --> 00:42:08,690 +بإمكانها تعمل addition ال H هذه سهلة تفقد بتفقد + +481 +00:42:09,410 --> 00:42:13,850 +وبرجع البنزين للغرض التطبيق مانتش ياكم ضايعوا مخكم + +482 +00:42:13,850 --> 00:42:17,950 +و وجدكم في إيش في أنكوا تتخيلوا أسهم على طول بدكم + +483 +00:42:17,950 --> 00:42:22,130 +تحطوا الجواب أن هذا ال orthoposition هذا ال + +484 +00:42:22,130 --> 00:42:25,550 +orthoposition اللي زي هيك هذه ال double .. هذه ال + +485 +00:42:25,550 --> 00:42:28,930 +bond اللي هنا مع ال H و أنتم غاضبين وين بدكم + +486 +00:42:28,930 --> 00:42:35,910 +تنجلوها بدل ما هي هيك بدون ما نقعد نتعب حالنا هيك + +487 +00:42:35,910 --> 00:42:37,750 +و ال .. و هذه إيش صارت + +488 +00:42:41,270 --> 00:42:44,470 +يعني تخيلوا ببساطة كأنه ال double .. كأنه ال + +489 +00:42:44,470 --> 00:42:48,670 +single bond اللي مع ال H حطناها هنا و جيبنا ال + +490 +00:42:48,670 --> 00:42:53,870 +action هذه محصلة التفاؤد هاي بتتم عملية إيش ال + +491 +00:42:53,870 --> 00:42:59,190 +cyclization طبعا بعد هيك OH مع H شو بيعملوا عنده + +492 +00:42:59,190 --> 00:43:06,810 +double bond هذا المثال نفس الشيء بس بدنا فيه بدل + +493 +00:43:06,810 --> 00:43:12,280 +anilineفيلون انتبهوا بقى كيف انا نفس الفكرة كيف + +494 +00:43:12,280 --> 00:43:18,540 +بصمم التحضير بنفس الفكرة يعني هنا فين ال N H2 و + +495 +00:43:18,540 --> 00:43:25,160 +هنا فين ال O H الان هذا ال O H روح اتحطته مع R C O + +496 +00:43:25,160 --> 00:43:32,360 +C H C L لحظة ال O H وين بتروح بتسكل بتطرد ال C L + +497 +00:43:32,360 --> 00:43:38,030 +ال substitutionالـ Eucleophilic Substitution هاي + +498 +00:43:38,030 --> 00:43:42,930 +صار عندكم CHR اللي هي موجودة هنا و C double bond O + +499 +00:43:42,930 --> 00:43:48,210 +هاي ال orthoposition الرابط اللي هنا وين بده تصير؟ + +500 +00:43:48,210 --> 00:43:53,170 +صارت هنا، هاذي؟ + +501 +00:43:53,170 --> 00:44:04,070 +OH OH واضح؟ ال OH و ال H عملوا إغلاق على + +502 +00:44:04,070 --> 00:44:09,780 +أي حال؟أفهمنا إذا ال cyclization على ال + +503 +00:44:09,780 --> 00:44:15,060 +orthoposition في عندي أنا أنثى إضافية كلها في ال + +504 +00:44:15,060 --> 00:44:18,900 +cyclization على ال orthoposition لكن اللى بيصير + +505 +00:44:18,900 --> 00:44:25,060 +انه شوية بالفصل عندكم المثال يعني هذه ال NH2 اللى + +506 +00:44:25,060 --> 00:44:29,160 +هتحل محل ال PR و بعدين هذا ال cyclization سهل ولا + +507 +00:44:29,160 --> 00:44:36,070 +لأ؟سهل هذه الان H2 انها تعمل إبدال لل CL لأن هذا + +508 +00:44:36,070 --> 00:44:41,350 +acid chloride و بعدين هذا ال orthoposition يسكر + +509 +00:44:41,350 --> 00:44:48,150 +هناسهل أمثلة كتير جدا و عشان هيك جزء من ال + +510 +00:44:48,150 --> 00:44:52,490 +homework اللي هتجيبه هذه الأمثلة الحقيقة من مجالات + +511 +00:44:52,490 --> 00:44:56,290 +يعني اعتبروا ان انا كمان جيبت homework هذه من مجلة + 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المراكبات اللي ثبتت كأساس في هذا النظام يجب ان يعرفها كل متعلم للكيميا الحلقية المراكبات اللي موجودة أمامنا", "tokens": [1211, 19452, 45164, 1975, 1829, 23032, 6027, 3555, 9122, 2655, 3555, 7607, 4812, 18871, 3224, 8978, 1975, 2304, 2655, 5016, 7649, 8032, 1863, 3615, 9566, 1829, 3224, 32771, 1211, 9566, 23758, 20193, 7251, 38251, 7578, 4724, 32277, 2304, 1975, 7435, 2655, 15042, 3615, 1829, 11331, 35457, 12174, 14407, 22488, 389, 292, 33313, 1601, 8910, 5296, 31377, 2304, 8717, 38251, 1829, 3224, 430, 6016, 29114, 9154, 9673, 23557, 4117, 3555, 9307, 13672, 1829, 38637, 3555, 2655, 2655, 9122, 10721, 3794, 32277, 8978, 23758, 28239, 19913, 10943, 7251, 7435, 3555, 16472, 37495, 28480, 11296, 28242, 44650, 3615, 19528, 24976, 4117, 32640, 25528, 21542, 1211, 4587, 10632, 9673, 23557, 4117, 3555, 9307, 13672, 1829, 3714, 29245, 23328, 3660, 5551, 2304, 10943, 8315], "avg_logprob": -0.22096353496114413, "compression_ratio": 1.6213991769547325, "no_speech_prob": 0.0, "words": [{"start": 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"word": " اللي", "probability": 0.92822265625}, {"start": 1936.72, "end": 1936.98, "word": " يعني", "probability": 0.87646484375}, {"start": 1936.98, "end": 1937.12, "word": " ان", "probability": 0.83349609375}, {"start": 1937.12, "end": 1937.34, "word": " شاء", "probability": 0.983642578125}, {"start": 1937.34, "end": 1937.48, "word": " الله", "probability": 0.9521484375}, {"start": 1937.48, "end": 1937.94, "word": " بأمل", "probability": 0.916015625}, {"start": 1937.94, "end": 1938.4, "word": " انه", "probability": 0.8515625}, {"start": 1938.4, "end": 1938.72, "word": " في", "probability": 0.796875}, {"start": 1938.72, "end": 1939.1, "word": " لقاء", "probability": 0.9767252604166666}, {"start": 1939.1, "end": 1939.56, "word": " قادم", "probability": 0.9933268229166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 1943.556625, "duration_after_vad": 1778.065624999995} \ No newline at end of file diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/nHngaEW_N3o.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/nHngaEW_N3o.srt new file mode 100644 index 0000000000000000000000000000000000000000..dbed1d22e7451ecdcd04ac9c7630096ec77146db --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/nHngaEW_N3o.srt @@ -0,0 +1,3527 @@ +1 +00:00:21,290 --> 00:00:27,050 +بسم الله الرحمن الرحيم بنستمر في موضوع ال cycle + +2 +00:00:27,050 --> 00:00:31,390 +addition reactions المرة الماضية اتكلمنا عن ال + +3 +00:00:31,390 --> 00:00:34,810 +cycle addition كمفهوم عام و اتكلمنا عن ال 1,3- + +4 +00:00:34,810 --> 00:00:38,590 +-dipolar cycle addition يمكن في ال 1,3-dipolar + +5 +00:00:38,590 --> 00:00:43,200 +cycle addition حكينا فكرة عامة بالنسبة للميكانيزم + +6 +00:00:43,200 --> 00:00:47,240 +أن الميكانيزم ممكن تكون concerted mechanism أو + +7 +00:00:47,240 --> 00:00:51,220 +radical mechanism الآن هذا الكلام هتلاحظه أنه + +8 +00:00:51,220 --> 00:00:55,020 +بتكرر في Diels-Alder reaction بتكرر عند اللزوم في + +9 +00:00:55,020 --> 00:00:58,760 +two plus two cycle additions ولذلك مش هنعيد + +10 +00:00:58,760 --> 00:01:04,080 +الميكانيزم هنا مجرد أننا نتعرف على التفاعل و ناخد + +11 +00:01:04,080 --> 00:01:10,660 +أمثلة عنه. Diels-Alder reaction بالنسبة لكم معروف و + +12 +00:01:10,660 --> 00:01:16,020 +دائما بتقولوا أنه داين و داينوفايل بيتفاعلوا مع + +13 +00:01:16,020 --> 00:01:20,540 +بعض و بيعطوا حلقة سداسية فهو من ناحية ال pi + +14 +00:01:20,540 --> 00:01:25,260 +electron 4 plus 2 و من ناحية ال atoms 4 plus 2 + +15 +00:01:25,260 --> 00:01:32,750 +بيعطي حلقة سداسية. يمكن أول reaction انعمل كان + +16 +00:01:32,750 --> 00:01:37,370 +heterocyclic ولو ال Diels-Alder موجود منه أمثلة + +17 +00:01:37,370 --> 00:01:40,510 +في ال carbocyclic chemistry أكثر من heterocyclic + +18 +00:01:40,510 --> 00:01:44,790 +chemistry لكن هنا في عندي ال cyclopentadiene هذا + +19 +00:01:44,790 --> 00:01:48,990 +يمثل الدين و هنا الرابطة بين ال nitrogen + +20 +00:01:48,990 --> 00:01:56,090 +و النيتروجين Diethyl azodicarboxylate وبيعملوا ال + +21 +00:01:56,090 --> 00:02:00,410 +cycle addition و هي الحلقة السداسية مع وجود ال + +22 +00:02:00,410 --> 00:02:06,530 +double bond. هذا تقريبا أول مثال في ال Diels-Alder + +23 +00:02:06,530 --> 00:02:13,400 +reaction. خلينا نقول فيه four atoms واضح؟ يمكن + +24 +00:02:13,400 --> 00:02:16,560 +أنتم متعودين على ال Diels-Alder reaction على + +25 +00:02:16,560 --> 00:02:21,880 +شغلة أنكوا تقولوا في النهاية بدي شيء يكون مصدر + +26 +00:02:21,880 --> 00:02:25,700 +أكثر للإلكترونات و شيء يكون electron deficient عشان + +27 +00:02:25,700 --> 00:02:30,700 +يتم التفاعل. الآن اللي كنتوا بتاخدوه أنتم أنه ال داين + +28 +00:02:30,700 --> 00:02:35,390 +يكون عليه مجموعات تكون معطية للإلكترونات electron + +29 +00:02:35,390 --> 00:02:40,050 +releasing groups و ال داينوفايل يكون عليه electron + +30 +00:02:40,050 --> 00:02:44,210 +withdrawing group كأنه صار عنده طرف سالب و طرف + +31 +00:02:44,210 --> 00:02:50,060 +موجب وهدولة بيعملوا Diels-Alder reaction. بتقيل بدل + +32 +00:02:50,060 --> 00:02:53,280 +المرة الفاتت قولنا احنا أنه عشان أنتم تكملوا Diels- + +33 +00:02:53,280 --> 00:02:57,040 +Alder reaction بتتخيلوا مثل هذه الحركات لكن ال + +34 +00:02:57,040 --> 00:03:01,340 +mechanism بالتأكيد لأ is either a concerted + +35 +00:03:01,340 --> 00:03:03,760 +mechanism أو a radical mechanism و اللي بيحكم + +36 +00:03:03,760 --> 00:03:10,290 +الكلام في النهاية التجربة اللي بتطلع عندنا. الآن + +37 +00:03:10,290 --> 00:03:15,450 +طالما أن أنا بقول بدي شيء سالب و شيء موجب بيصير + +38 +00:03:15,450 --> 00:03:19,730 +السؤال ما المانع .. ما المانع أن هذا الكلام ينعكس + +39 +00:03:19,730 --> 00:03:23,950 +يعني يكون هنا المجموعات المعطية للإلكترونات و هنا + +40 +00:03:23,950 --> 00:03:28,510 +المجموعات الساحبة للإلكترونات. ما هو هيك إذا قلنا + +41 +00:03:28,510 --> 00:03:31,830 +هاي سالب و موجب ما المانع أن يكون سالب و موجب بهذا + +42 +00:03:31,830 --> 00:03:37,210 +الشكل. من ناحية النظرية البحثية مافيش ولا مانع. يمكن + +43 +00:03:37,210 --> 00:03:41,210 +الناس أول أمثلة في Diels-Alder reaction كانت هذا + +44 +00:03:41,210 --> 00:03:44,890 +النوع من الأمثلة و لذلك اعتادوا أنهم يحكوا زي هيك + +45 +00:03:44,890 --> 00:03:51,270 +الآن بالتأكيد الأمثلة الثانية انوجدت و لذلك لما + +46 +00:03:51,270 --> 00:03:54,490 +انوجدت الأمثلة الثانية أن هنا يكون مجموعات ساحبة + +47 +00:03:54,490 --> 00:04:00,720 +للإلكترونات و هنا مجموعات معطية للإلكترونات. بدوا + +48 +00:04:00,720 --> 00:04:06,620 +يطلقوا عليها اسم لأن هذا اعتبر كأصل أو شيء موجود + +49 +00:04:06,620 --> 00:04:11,580 +في الأول سموها إيش inverse electron demand Diels + +50 +00:04:11,580 --> 00:04:15,520 +-Alder reaction يعني Diels-Alder معكوسة من ناحية + +51 +00:04:15,520 --> 00:04:18,060 +الفهم الإلكتروني. يعني هنا ال electron releasing + +52 +00:04:18,060 --> 00:04:22,040 +groups و هنا ال electron withdrawing groups in + +53 +00:04:22,040 --> 00:04:28,280 +principle. واضح. فلو أنتم بدكم تكتبوا فقط في أي + +54 +00:04:28,280 --> 00:04:32,360 +مجلة أو على ال google search inverse electron + +55 +00:04:32,360 --> 00:04:36,100 +demand Diels-Alder reaction هيجيكوا عشرات و مئات + +56 +00:04:36,100 --> 00:04:41,120 +الأمثلة. فالاحتمالين موجودين ال Diels-Alder بالصيغة + +57 +00:04:41,120 --> 00:04:44,420 +اللي أول ما بيتعلمها الطالب و ال Diels-Alder + +58 +00:04:44,420 --> 00:04:48,870 +بالطريقة خلينا نقول اللي معكوسة إلكترونيا عما + +59 +00:04:48,870 --> 00:04:54,330 +تعلموا. بس في النهاية طريقتين صحيحة يا موجودة بوسالد + +60 +00:04:54,330 --> 00:05:00,450 +الآن إيش أشهر ال dienophiles و أشهر ال dienes اللي + +61 +00:05:00,450 --> 00:05:03,930 +بتستعمل؟ طبعا احنا ليش بنسميهم dienophiles ال double + +62 +00:05:03,930 --> 00:05:07,330 +bonds لأنه بيتفاعلوا مع داين. لو كانوا بتفاعلوا مع + +63 +00:05:07,330 --> 00:05:11,990 +three dipole كان إيش سمناهم؟ dipolarophiles. ممكن + +64 +00:05:11,990 --> 00:05:15,740 +تمتفاعل على C double bond O بتكون double bond + +65 +00:05:15,740 --> 00:05:20,620 +الدهيدز أو كيتونز على C double bond N أمينز على C + +66 +00:05:20,620 --> 00:05:25,600 +triple bond N نايتريلز. C double bond S ثيو الدهيدز + +67 +00:05:25,600 --> 00:05:34,920 +أو ثيو كيتونز. N=N ازو كربونيل كومباوندز. NO نايتروزو + +68 +00:05:34,920 --> 00:05:41,880 +كومباوند. N=S سلفينيل أمينز. N=S سلفينيل هذا أمين + +69 +00:05:41,880 --> 00:05:49,490 +سلفينيل أمين. الآن ال dienes أكثر برضه ممكن تكون عندك + +70 +00:05:49,490 --> 00:05:52,310 +alpha beta unsaturated carbonyl compound يعني هذا + +71 +00:05:52,310 --> 00:05:56,190 +carbonyl compound هذه الموقع alpha beta عشان ذلك + +72 +00:05:56,190 --> 00:06:00,030 +إيش قلنا عنه؟ alpha beta unsaturated carbonyl + +73 +00:06:00,030 --> 00:06:02,870 +compound و هو اللي يمكن يطلع عندك و هذا من ال Diels- + +74 +00:06:02,870 --> 00:06:07,890 +Alder reaction للناس اللي متذاكرين أو alpha beta + +75 +00:06:07,890 --> 00:06:12,390 +unsaturated amines. هذا carbonyl compound هذا amine + +76 +00:06:12,390 --> 00:06:19,940 +و alpha beta أو فينيل و أريل اي means هاي عندي + +77 +00:06:19,940 --> 00:06:24,940 +برضه اي means و بتكون حاملة هنا مجموعة فينيل أو + +78 +00:06:24,940 --> 00:06:31,560 +أريل اي means هذه الأشياء لاحظوا معاه مش ضروري + +79 +00:06:31,560 --> 00:06:37,580 +تكون موجودة لوحدها يعني ممكن تكون موجودة ضمن حلقة + +80 +00:06:37,580 --> 00:06:42,180 +تمامًا زي أول مثال احنا حكيناه. زي أول مثال احنا + +81 +00:06:42,180 --> 00:06:48,970 +حكيناه. هنقولنا هاي داين لو بدنا نعلم الآن + +82 +00:06:48,970 --> 00:06:54,770 +الداين من هنا هاي + +83 +00:06:54,770 --> 00:06:59,430 +الداين. لكن الداين موجود ضمن إيش؟ حلقة ضمن ال cycle + +84 +00:06:59,430 --> 00:07:04,110 +بنت داين و لذلك هنا بنقول احنا أن الداين masked + +85 +00:07:04,110 --> 00:07:08,990 +masked من إيش؟ من قناع يعني مختفي. الجزء التالي + +86 +00:07:08,990 --> 00:07:17,660 +فبنصير في عندنا مصطلح masked dienes. في عندنا مصطلح + +87 +00:07:17,660 --> 00:07:22,880 +masked dienes. الآن لاحظوا هنا بيجيبلنا هذا المنظر + +88 +00:07:22,880 --> 00:07:28,100 +بعدين بيقولنا ممكن يكون موجود في ال oxazole طب إيش + +89 +00:07:28,100 --> 00:07:33,720 +هو ال oxazole one of three compound يعني أنه هنا + +90 +00:07:33,720 --> 00:07:39,440 +oxygen لاحظوا الحلقة الخمسية ال oxazole الآن صار + +91 +00:07:39,440 --> 00:07:46,390 +من ضمن ال oxazole هي ال diene واضح؟ أو بيجيبلي مثال + +92 +00:07:46,390 --> 00:07:49,990 +ثاني في هذه الحالة the masked داين ممكن يكون موجود ب + +93 +00:07:49,990 --> 00:07:54,350 +1,2,4 تريازين. تريازين يعني ثلاث + +94 +00:07:54,350 --> 00:07:57,650 +نيتروجينات يعني كأنا بدي أحطها نيتروجين و أنا + +95 +00:07:57,650 --> 00:08:05,350 +نيتروجين. الآن هذا ما بيصيروا إيش؟ بعد ما يتفعل هيفقد + +96 +00:08:05,350 --> 00:08:10,560 +جزء ال nitrogen و لو كان أوكزازون هيفقد جزء الـ + +97 +00:08:10,560 --> 00:08:16,640 +Oxygen. الآن هذا عبارة عن Mask الداين. واضح Mask + +98 +00:08:16,640 --> 00:08:22,540 +الداين. فأنتم ممكن تشوفوا مركب زي هذا و بنفس الوقت + +99 +00:08:22,540 --> 00:08:27,300 +تاخدوا جزء الداين منه فقط هذا الجزء. طب و الجزء + +100 +00:08:27,300 --> 00:08:32,840 +الثاني بيحدث. الآن هذا ال 1,2,3,4, 1, + +101 +00:08:32,840 --> 00:08:36,020 +2,4 تريازين. طب لو كان 1,2,4,5 + +102 +00:08:36,020 --> 00:08:42,210 +تترازين. لاحظوا إيش بده أحط هنا N double bond N. + +103 +00:08:42,210 --> 00:08:49,490 +الآن هذا الجزء اللي مصيره هينحدث وينصف التترازين + +104 +00:08:50,550 --> 00:08:57,170 +عفوًا الداين. C=N-N=C هذه الأربع ذرات تبعون الداين + +105 +00:08:57,170 --> 00:09:03,770 +فالداين can be a part of a ring واضح؟ وغالبًا هذا + +106 +00:09:03,770 --> 00:09:10,150 +الكلام ممكن يكون جزء من حلقة فيها جزء صغير يمكن أن + +107 +00:09:10,150 --> 00:09:15,210 +يفقد. يعني أنتم بتفكروا في أشهر الأشياء اللي يمكن + +108 +00:09:15,210 --> 00:09:18,830 +أن تفقد أشهر الأشياء اللي يمكن أن تفقد جزئيات + +109 +00:09:18,830 --> 00:09:24,080 +نيتروجين. ممكن يكون التفكير بجزء carbon monoxide + +110 +00:09:24,080 --> 00:09:34,160 +مثلًا بحلقة ما زي هيك و يكون عنده CO أو CO2 لو بدي + +111 +00:09:34,160 --> 00:09:45,490 +CO2 بدي أفكر بشغل زي هيك. الآن هي ال CO2 ممكن + +112 +00:09:45,490 --> 00:09:49,610 +ينفقد. الواحد، الثانية، الثالثة، الرابعة، كل هذه + +113 +00:09:49,610 --> 00:09:54,310 +عبارة عن إيش؟ Masked Dienes وعشان ذلك لما بنشوف أنا + +114 +00:09:54,310 --> 00:10:00,490 +الأسماء بنلاحظ أن أسماء حلقات كانت داين جزء من + +115 +00:10:00,490 --> 00:10:06,550 +الحلقة. كانت داين جزء من إيش؟ جزء من الحلقة. وهذا + +116 +00:10:06,550 --> 00:10:11,970 +الكلام أثناء يعني دراستنا للأمثلة هيظل يتكرر + +117 +00:10:11,970 --> 00:10:16,840 +معنا. ممكن يكون أزوالكينز يعني في نيتروجينتين + +118 +00:10:16,840 --> 00:10:22,880 +نايتروزوالكينز. أسيل إمينز هي أمين و هنا في مجموعة + +119 +00:10:22,880 --> 00:10:29,100 +الأسيل. C double bond O أمين and أسيل إمين يعني هذه + +120 +00:10:29,100 --> 00:10:33,200 +الأسيل متصلة بالإيش؟ بالنيتروجين. كل هذه عبارة عن + +121 +00:10:33,200 --> 00:10:42,030 +أمثلة ل Possible Dienes. الآن لو بدنا نتطلع على + +122 +00:10:42,030 --> 00:10:47,130 +مجموعات من الأمثلة ممكن نتكلم بطريقتين. ممكن نقول + +123 +00:10:47,130 --> 00:10:52,150 +احنا أنه ال Dienophile يكون فيه هيتيرو أتم و ال + +124 +00:10:52,150 --> 00:10:56,950 +Dien يكون كله Carbons هذا واحد. ممكن ال Dienophile + +125 +00:10:56,950 --> 00:11:01,370 +يكون Carbons و ال Dien فيه هيتيرو أتم و in + +126 +00:11:01,370 --> 00:11:05,070 +principle. ممكن الطرفين كمان يكون فيهم هيتيرو أتم + +127 +00:11:06,100 --> 00:11:09,920 +الآن اتخيل ال hetero atoms ممكن يكون هان هان هان + +128 +00:11:09,920 --> 00:11:12,140 +هان هان هان هان هان هان هان هان هان هان هان هان + +129 +00:11:12,140 --> 00:11:12,360 +هان هان هان هان هان هان هان هان هان هان هان هان + +130 +00:11:12,360 --> 00:11:13,640 +هان هان هان هان هان هان هان هان هان هان هان هان + +131 +00:11:13,640 --> 00:11:13,800 +هان هان هان هان هان هان هان هان هان هان هان هان + +132 +00:11:13,800 --> 00:11:14,120 +هان هان هان هان هان هان هان هان هان هان هان هان + +133 +00:11:14,120 --> 00:11:14,700 +هان هان هان هان هان هان هان هان هان هان هان هان + +134 +00:11:14,700 --> 00:11:22,120 +هان هان هان هان هان هان هان هان هان + +135 +00:11:22,120 --> 00:11:25,420 +هان هان هان هان هان هان هان هان هان + +136 +00:11:29,200 --> 00:11:33,500 +Carbons. لاحظوا لما يجي يتفاعل مع ال C double bond + +137 +00:11:33,500 --> 00:11:38,100 +O هاي جزء ال C double bond O لو بدنا نتطلع عليه + +138 +00:11:38,100 --> 00:11:45,060 +هذا الداينوفايل اللي كان أصلاً و تم التفاعل معاه + +139 +00:11:45,060 --> 00:11:51,900 +وظل عند إيش؟ رابطة واحدة. الآن واضح أن هذا التفاعل + +140 +00:11:51,900 --> 00:11:56,560 +مثلًا غالبًا بيجي من فئة الإيش؟ ال inverse electron + +141 +00:11:56,560 --> 00:12:06,160 +demand ولا normal هذا normal normal ضاغطين عليه + +142 +00:12:06,160 --> 00:12:09,560 +electron donating groups مثل ومثل اللي هو ال + +143 +00:12:09,560 --> 00:12:13,680 +normal هنا مثلا فنل ممكن تكون electron .. هذا + +144 +00:12:13,680 --> 00:12:19,880 +normal دي ال alder reaction طبعا الفنل CO هي + +145 +00:12:19,880 --> 00:12:25,200 +موجودة وباقي التفاعل بنقدر نكمله + +146 +00:12:27,660 --> 00:12:31,640 +أمثلة على هذا النوع الحقيقة موجودة كثير يعني + +147 +00:12:31,640 --> 00:12:36,860 +لاحظوا مصنف هنا الأمثلة بشكل جيد يعني في البداية + +148 +00:12:36,860 --> 00:12:43,800 +كل اللي موجود ضاغطين يكون كله carbon و ال hetero + +149 +00:12:43,800 --> 00:12:49,080 +atoms تكون في ضاغطينه files وتعطي نتائج ربما + +150 +00:12:49,080 --> 00:12:54,940 +تلاحظوا مثلا لو كان عندي ال C triple bond N ال C + +151 +00:12:54,940 --> 00:12:59,450 +triple bond N شو بتصفه؟C double bond و لذلك هنا + +152 +00:12:59,450 --> 00:13:06,930 +الحلقة صفيت بكم رابطة زوجية رابطتين لاحظوا هذا + +153 +00:13:06,930 --> 00:13:12,730 +النوع من الأمثلة .. هذا النوع من الأمثلة مرات كثير + +154 +00:13:12,730 --> 00:13:20,430 +بيكون هو الأقرب لإنه لو فقد مجمعتين و عمل رابطة أن + +155 +00:13:20,430 --> 00:13:25,560 +يصير aromaticولذلك هنا أنا بعيد عن ال aromatic ال + +156 +00:13:25,560 --> 00:13:31,760 +aromatic بدها تلت روابط زوجية عندي واحدة بدها نتين + +157 +00:13:31,760 --> 00:13:36,540 +فإنه هذا يتحول ل aromatic صعب الآن هذا ماشي تلتين + +158 +00:13:36,540 --> 00:13:41,960 +الطريق هذا المركب ماشي تلتين الطريق ولذلك لاحظوا + +159 +00:13:41,960 --> 00:13:48,940 +أنه ممكن يفقد مثلا مجموعة oethyl مع H معينة و + +160 +00:13:48,940 --> 00:13:52,740 +يعمل ال aromatic طبعا البعض ممكن يقول هذا أي مين + +161 +00:13:52,740 --> 00:13:56,880 +خلو أي مين خلو ال double bond هنا و خلو H هنا + +162 +00:13:56,880 --> 00:14:03,710 +هاي H مع Oethel تفقد بصير عندي في نهاية المركب ب + +163 +00:14:03,710 --> 00:14:08,430 +redeem derivative فلما بكون عندي quintel double + +164 +00:14:08,430 --> 00:14:13,610 +bonds بكون أنا أقرب لإنه أفقد مجموعتين سواء + +165 +00:14:13,610 --> 00:14:16,790 +hydrogen سواء ethanol سواء ammonia حسب طبيعة + +166 +00:14:16,790 --> 00:14:28,270 +المركب وإنه يصير عند الناتج شماله aromatic الآن + +167 +00:14:28,270 --> 00:14:34,990 +أحيانا التفاعل ممكن يكون Intramolecular Deals Elder + +168 +00:14:34,990 --> 00:14:37,670 +Reactions زي ما شوفنا برضه إنه كان في ال 1,3 + +169 +00:14:37,670 --> 00:14:42,250 +-dipolar cycloaddition Intramolecular 1,3-dipolar + +170 +00:14:42,250 --> 00:14:46,010 +cycloaddition يعني هنا عندي حلقة ربعية Strained لو + +171 +00:14:46,010 --> 00:14:50,130 +اتخيلت إن هذه الحلقة مع ظروف التفاعل 180 degree + +172 +00:14:50,130 --> 00:14:55,870 +centigrade و 16 ساعة مش ذو ظروف بسيطة فتحت بهذا + +173 +00:14:55,870 --> 00:14:59,430 +الشكل و ال double bond صارت hand بمعنى صار عندي + +174 +00:14:59,430 --> 00:15:02,030 +hand double bond و double bond أنهي هذا الجزء هو + +175 +00:15:02,030 --> 00:15:08,950 +عبارة عن إيش الدين وال C double bond ال dienophile + +176 +00:15:08,950 --> 00:15:14,470 +فلو أنا كملت ال deals ألدر reaction هتصير هذه + +177 +00:15:14,470 --> 00:15:19,000 +الحلقة السادسة هبصي رادس الحلقة السادسة طبعا هيكون + +178 +00:15:19,000 --> 00:15:24,120 +أنا عند إيش double bond و اعمل tautomerism in a + +179 +00:15:24,120 --> 00:15:28,700 +mean tautomerism يعني ما .. مانخافش من تحريك ال + +180 +00:15:28,700 --> 00:15:34,420 +double bonds في tautomerisms هنا الآن double bond + +181 +00:15:34,420 --> 00:15:40,610 +إن الاتفاعلتك Dienophile وبالتالي طلع عندي مركب زي + +182 +00:15:40,610 --> 00:15:46,850 +هذا هنا ال Nitroso الآن double bond أو اتفاعلت ك + +183 +00:15:46,850 --> 00:15:56,450 +Dienophile عادي الآن ممكن نجيب أمثلة ثانية hetero + +184 +00:15:56,450 --> 00:16:04,600 +Diene و Dienophile Carbons واضح هذا مثلا Alpha Beta + +185 +00:16:04,600 --> 00:16:06,480 +Unsaturated Ketone + +186 +00:16:14,590 --> 00:16:19,230 +الدينوفايل وأكيد بيعمل cycle addition نفس الشيء + +187 +00:16:19,230 --> 00:16:24,070 +هنا alphabet unsaturated أمين عند اللزوم مع double + +188 +00:16:24,070 --> 00:16:28,430 +bond مع double bond لاحظوا الأمثلة الحقيقة يعني هي + +189 +00:16:28,430 --> 00:16:34,310 +مجرد إنكوا تطبقوا ال deals elder reaction مافيش + +190 +00:16:34,310 --> 00:16:39,150 +داعي إن الإنسان يقف عند كل مثال فيها يعني هي هذا + +191 +00:16:39,150 --> 00:16:45,020 +المثال هنجيب مجرد هذه هنا ونعمل الحلقة السداسية + +192 +00:16:45,020 --> 00:16:50,440 +هنا هاي جزء ضاغطين C and C double bond C مع هذه + +193 +00:16:50,440 --> 00:16:55,260 +بيطلع عندي حلقات هنا نفس الشيء هاي ضاغطين واحد + +194 +00:16:55,260 --> 00:17:02,100 +اتنين تلاتة أربعة مع double bond برضه هيطلق حلقات + +195 +00:17:02,100 --> 00:17:05,740 +I + +196 +00:17:05,740 --> 00:17:11,690 +don't know شيء هذا على أي حال ما عرضناه من الأمثلة + +197 +00:17:11,690 --> 00:17:17,550 +بتخيالي يغني عن إننا نضيع وقت في هذه الآن ال deals + +198 +00:17:17,550 --> 00:17:22,730 +and reactions زي ما قلنا لكم واسع جدا حتى أنتو + +199 +00:17:22,730 --> 00:17:26,530 +يعني تقتنعوا بالوسع تبعه إيش بدي يكون المطلوب منكم + +200 +00:17:27,560 --> 00:17:32,640 +هو تجيبوا homework مثال على normal Diels-Alder + +201 +00:17:32,640 --> 00:17:38,180 +reaction ومثال على inverse electron demand Diels + +202 +00:17:38,180 --> 00:17:41,860 +-Alder reaction مجرد ما تروحوا على المجلات + +203 +00:17:41,860 --> 00:17:49,060 +هتلاحظوا أنثى جميلة وكثير موجودة في المجلات Diels + +204 +00:17:49,060 --> 00:17:54,040 +-Alder cycle addition normal أو هو في العنوان نفسه + +205 +00:17:54,040 --> 00:17:58,200 +حتى مكتوب Inverse Electron Demand Deals Elder + +206 +00:17:58,200 --> 00:17:59,920 +Cycle Addition + +207 +00:18:02,480 --> 00:18:07,840 +من أنواع ال cycle additions الثانية اللي هو ال two + +208 +00:18:07,840 --> 00:18:11,740 +plus two cycle addition من أنواع ال cycle + +209 +00:18:11,740 --> 00:18:14,740 +additions الثانية ال two plus two cycle addition + +210 +00:18:14,740 --> 00:18:19,140 +الآن غالبا هذا ال two plus two cycle addition + +211 +00:18:19,140 --> 00:18:27,620 +مشهور أكثر ما يمكن مع اللي هي ال dienes اللي بتكون + +212 +00:18:27,620 --> 00:18:32,800 +بهذا الشكل المتوالية واضحاللي هي ال cumulated + +213 +00:18:32,800 --> 00:18:38,060 +dienes يعني double bond وكمان double bond فمن + +214 +00:18:38,060 --> 00:18:42,360 +أشهر المركبات المشهورة في هذا المجال ال N double + +215 +00:18:42,360 --> 00:18:47,780 +bond C double bond O اللي هي ال isocyanates و ال C + +216 +00:18:47,780 --> 00:18:49,740 +double bond C double bond O + +217 +00:18:52,480 --> 00:18:57,840 +الكيتين الآن في ال isocyanates حيصير عندكم مشكلة + +218 +00:18:57,840 --> 00:19:02,100 +أنه في نتين double bonds مع أي واحدة بتفاعل أكثر + +219 +00:19:02,100 --> 00:19:08,120 +غالبا مع ال isocyanates التفاعل مع الآن double + +220 +00:19:08,120 --> 00:19:13,980 +bond C هو الأشهر واضح؟يعني التفاعل هيكون على أي + +221 +00:19:13,980 --> 00:19:17,960 +double bond هذه الآن لاحظوا مرات فعلها مع ال ال + +222 +00:19:17,960 --> 00:19:22,240 +keen يعني لو بدنا نطلع احنا الجزء اللي عندنا هذا + +223 +00:19:22,240 --> 00:19:30,160 +هو الجزء الأزرق أو هنا ال ar هذا هو الجزء الأزرق + +224 +00:19:30,160 --> 00:19:37,920 +هنا هذا الجزء هنا هذا الجزء طبعا يمكن في نقطة ما + +225 +00:19:37,920 --> 00:19:42,940 +نوّهتش إليها أنا في ال deals ألدر reaction إنه + +226 +00:19:42,940 --> 00:19:47,610 +دائما وأبدا عندكم احتمال إيش؟radio isomers يعني + +227 +00:19:47,610 --> 00:19:51,190 +أنه هل يطلع عنده one product ولا يطلع عنده + +228 +00:19:51,190 --> 00:19:56,470 +mixture of products ربما معظم الأمثلة اللي موجودة + +229 +00:19:56,470 --> 00:20:01,170 +بيطلع فيها ناتج واحد لكن ما بنعش أنه ممكن يطلع + +230 +00:20:01,170 --> 00:20:05,870 +mixture of product الآن الإنسان لما بيعمل التفاعل + +231 +00:20:05,870 --> 00:20:12,140 +في النهاية بيكون مش عارف وبده يحط عنده الاحتمالين + +232 +00:20:12,140 --> 00:20:17,140 +بدو يحط عنده الاحتمالين الآن نفس الشيء عندنا هنا في + +233 +00:20:17,140 --> 00:20:21,240 +ال two plus two cycle addition يعني أنا هنا أخدت N + +234 +00:20:21,240 --> 00:20:23,700 +double bond c double bond وعملت عليها cycle + +235 +00:20:23,700 --> 00:20:27,900 +addition هل يا ترى ال R هذه بده تكون على جهة ال N + +236 +00:20:27,900 --> 00:20:33,120 +ولا ممكن نأكسهانرسم النتيجة الثانية كذلك الحال هان + +237 +00:20:33,120 --> 00:20:36,840 +واضح هل الآن هدى عجلة ال C double bond O ولا الآن + +238 +00:20:36,840 --> 00:20:41,320 +ممكن تيجي عجلة الآن فمن ناحية نظرية البحث + +239 +00:20:43,560 --> 00:20:47,440 +1,3-dipolar cycloaddition وكل دي الزقال ده ال + +240 +00:20:47,440 --> 00:20:51,460 +reaction وكل 2 plus 2 cycloaddition reaction الأصل + +241 +00:20:51,460 --> 00:20:56,840 +نظريا إنه متوقع منه كام regioisomers اتنين الأحيان + +242 +00:20:56,840 --> 00:20:59,900 +الناس في الخبرة بيقدروا يقدروا اللي بيشتغلوا في + +243 +00:20:59,900 --> 00:21:05,000 +المجال أي regioisomers أكثر منطقية بالنظر إلى + +244 +00:21:05,000 --> 00:21:09,820 +طبيعة الذرات ومين فيها سالب أكثر ومين فيها موجب + +245 +00:21:09,820 --> 00:21:15,760 +أكثر لكن الحكم النهائي هو إيش هو التجربة الحكم + +246 +00:21:15,760 --> 00:21:26,360 +النهائي بالتأكيد هو التجربة لاحظوا + +247 +00:21:26,360 --> 00:21:32,020 +مثلا في هذا المثل مع ال ISO-thiocyanate مع ال ISO + +248 +00:21:32,020 --> 00:21:35,700 +-thiocyanate التفاعل ما تمش على الأرض بال bond C + +249 +00:21:35,700 --> 00:21:43,520 +تم على ال C double bond S هي تجربة هذا الجزء هو + +250 +00:21:43,520 --> 00:21:46,820 +الجزء الأزرق اللي اتفاعل وبالتأكيد عندي two + +251 +00:21:46,820 --> 00:21:50,760 +possible regioisomers التفاعل مع ال key teams + +252 +00:21:50,760 --> 00:21:57,020 +غالبا بتتم على ال C double bond C هاي R R C double + +253 +00:21:57,020 --> 00:22:02,440 +bond C وال double bond O بتكون exocyclic يعني + +254 +00:22:02,440 --> 00:22:08,370 +للخارج وحتى لو اتفاعل نفسه مع أمين ولا مع الديهيد + +255 +00:22:08,370 --> 00:22:14,370 +أو كيتون اللي هي ال كيتين وتوابعها الآن ممكن + +256 +00:22:14,370 --> 00:22:22,130 +يتفاعل مثل هذا المركب الأمين أو دايمين مع كيتين مع + +257 +00:22:22,130 --> 00:22:29,240 +كيتين لاحظوا هذه جزء الكيتين هذا جزء الكتين RR CWB + +258 +00:22:29,240 --> 00:22:35,480 +CWB O وهنا في عندي CWB N و CWB N سيمتريك هذا المركب + +259 +00:22:35,480 --> 00:22:42,780 +بأي طرق فعله أعمل التفاعل على واحدة من هدولة الـ + +260 +00:22:42,780 --> 00:22:50,490 +CWB N وطبعا ممكن مع الأزو كومباونز المركبات اللي + +261 +00:22:50,490 --> 00:22:56,150 +فيها نيتروجين يتفاعل مع الكيينز أو مع أي نول أي + +262 +00:22:56,150 --> 00:23:01,670 +ثارز يعني الاحتمالات زي ما أنتو شايفين إيش في ال + +263 +00:23:01,670 --> 00:23:09,910 +two plus two احتمالات كثيرة وواسعة وربما أشهرها زي + +264 +00:23:09,910 --> 00:23:14,350 +ما شفنا في أي نوع من ال ال dienes ال formulated + +265 +00:23:14,350 --> 00:23:25,250 +اللي فيهم أكثر من double bond جنب بعض مشهور + +266 +00:23:25,250 --> 00:23:30,470 +في ال two plus two name reaction paterno bouché + +267 +00:23:30,470 --> 00:23:34,610 +reaction هذا ال paterno bouché reaction هو تفاعل + +268 +00:23:34,610 --> 00:23:41,010 +كيتون تفاعل كيتون مع الكيل تفاعل كيتون مع الكيل في + +269 +00:23:41,010 --> 00:23:45,980 +وجود الضوء كما يبدو الناس اللي درسوا التفاعل إن هو + +270 +00:23:45,980 --> 00:23:51,920 +عبارة عن radical reaction بمعنى بتيم على خطوتين + +271 +00:23:51,920 --> 00:23:54,980 +دائما لما نحكي radical reaction بتيم على خطوتين + +272 +00:23:54,980 --> 00:23:59,580 +فلو أنا اتخيلت هذه ال phenyl phenyl C double bond + +273 +00:23:59,580 --> 00:24:06,200 +O هذا الجزء الأزرق هو هذا الجزء عمل رابطة مع الجزء + +274 +00:24:06,200 --> 00:24:12,710 +الثاني يعني لو اتخيلنا الإلكترونات بهذا الشكل هي + +275 +00:24:12,710 --> 00:24:19,310 +هنعملوا رابطة راديكل وراديكل واضح؟ ضال عندي free + +276 +00:24:19,310 --> 00:24:23,310 +radical و free radical هدول ال free radical بعد + +277 +00:24:23,310 --> 00:24:29,150 +هيك ممكن يسكروا الآن بالتأكيد في عندي حكمال لإيش ل + +278 +00:24:29,150 --> 00:24:33,030 +radio isomers يعني هل يا ترى ال carbon اللي حاملة + +279 +00:24:33,030 --> 00:24:37,450 +تين مثل هتيجي جنب ال carbon اللي حاملة تين funnel + +280 +00:24:37,450 --> 00:24:44,880 +زي ما هو مبين هنا هذا الجزء إيه اللي اتفاعله ولا + +281 +00:24:44,880 --> 00:24:48,480 +هذا الجزء اللي بده ينعكس الكربون اللي حاملة نتيل + +282 +00:24:48,480 --> 00:24:54,720 +مثل بده تيجي بجهة معاكسة لاحظين يعني كأنه أنا بعمل + +283 +00:24:54,720 --> 00:24:59,160 +cycle addition هل هذه الترابط تتفعل بهذا الشكل ولا + +284 +00:24:59,160 --> 00:25:04,090 +بهذا الشكل واضحة الفكرة في النهاية اللي بيحكم + +285 +00:25:04,090 --> 00:25:09,190 +الجواب التجربة بس في كل الأحوال طالما بحكي عن two + +286 +00:25:09,190 --> 00:25:14,710 +plus two cycle addition إذا كم ناتج بتوقع ناتجين + +287 +00:25:14,710 --> 00:25:20,930 +والنهاية التجربة هي الحكم + +288 +00:25:24,180 --> 00:25:27,560 +الأخرى شغلة ممكن نحكيها بالـ Cycloaddition + +289 +00:25:27,560 --> 00:25:32,960 +Reactions لـ Chelotropic Reactions وبالتالي احنا + +290 +00:25:32,960 --> 00:25:38,240 +ركزنا عليها لما تكلمنا على الكاربينز والنيترينز + +291 +00:25:38,240 --> 00:25:42,340 +وقلنا لـ Chelotropic Reactions إن تعمل الـ 2 new + +292 +00:25:42,340 --> 00:25:48,210 +sigma bonds at one atom واضح ولذلك مثلا هنا لو + +293 +00:25:48,210 --> 00:25:52,430 +بدنا نأخذ هذا النيترين بده يتفاعل على double bond بده + +294 +00:25:52,430 --> 00:25:56,610 +يعمل عند الحلقة الثلاثية الآن الـ two new sigma + +295 +00:25:56,610 --> 00:26:00,670 +bonds صاروا موجودين أين؟ على ذرة النيتروجين أو هذا + +296 +00:26:00,670 --> 00:26:04,550 +النيترين على سبيل المثال بده أفعله مع الـ double bond + +297 +00:26:04,550 --> 00:26:10,690 +الـ two new sigma bonds أين موجودين؟ هي sigma bond + +298 +00:26:10,690 --> 00:26:16,250 +وهي sigma bond على نفس النيتروجين هنا وهذا معنى + +299 +00:26:16,250 --> 00:26:21,270 +كلمة ايش Chelotropic reaction سواء قلناها بالـ أو + +300 +00:26:21,270 --> 00:26:30,070 +بالـ اي يعني ممكن تقرأها Chelo بالـ أو وتشيل بالـ اي + +301 +00:26:30,070 --> 00:26:34,570 +القرأتين الموجودين Chelotropic و Chelotropic + +302 +00:26:34,570 --> 00:26:38,590 +reaction فالـ Cycloaddition of Carbines and Nitrines + +303 +00:26:38,590 --> 00:26:44,170 +وأخذنا أمثلة كثيرة عليه هو من أشهر الأمثلة على التي + +304 +00:26:44,170 --> 00:26:49,770 +تسمى الـ Chelotropic Reactions أيضًا إضافة الـ + +305 +00:26:49,770 --> 00:26:53,810 +Sulphur Dioxide للـ Conjugated Dienes وكلنا بدنا + +306 +00:26:53,810 --> 00:26:56,990 +نكون متذكرين إن الـ Sulphur هنا في عليه أزواج من + +307 +00:26:56,990 --> 00:27:03,090 +الإلكترونات واضح هذا التفاعل بيكون عبارة من ناحية + +308 +00:27:03,090 --> 00:27:08,230 +إلكترونية عن 4 Plus 2 فقط من هدول هيشاركوا + +309 +00:27:08,230 --> 00:27:12,150 +لكن من ناحية الـ atoms هو عبارة عن four plus one + +310 +00:27:12,150 --> 00:27:17,990 +بيعطي حلقة خماسية طالما إنه الرابطتين اجوا على + +311 +00:27:17,990 --> 00:27:23,870 +السلفر هنا إذا هذا التفاعل عبارة عن Chelotropic + +312 +00:27:23,870 --> 00:27:28,990 +reaction لاحظوا إن هذا التفاعل تفاعل عكسي وحقيقة + +313 +00:27:28,990 --> 00:27:33,550 +هم ما بيستفيدوش من التفاعل الطردي لأ بيستفيدوا + +314 +00:27:33,550 --> 00:27:39,150 +أكثر من التفاعل العكسي بمعنى موجود هذا المركب وهذا + +315 +00:27:39,150 --> 00:27:43,430 +المركب بالتسخين أو كذا بيفقد الـ SO2 وبيعطي + +316 +00:27:43,430 --> 00:27:50,800 +الدايين فبيصير هذا مصدر لتوفير الداين لمين؟ لمين لازم + +317 +00:27:50,800 --> 00:27:58,860 +نتضيين؟ لتضيين الـ reaction لتضيين الـ file ف أنا لما + +318 +00:27:58,860 --> 00:28:04,200 +بدي تضيين بجيبه من هذا المركب بالتسخين بيفقد SO2 + +319 +00:28:04,200 --> 00:28:09,360 +طبعا ممتاز إنه يفقد SO2 لأن SO2 غاز هيطير يعني مش + +320 +00:28:09,360 --> 00:28:13,080 +هيضل في التفاعل فمن ناحية الـ processing والعمل + +321 +00:28:13,080 --> 00:28:18,880 +أثناء التفاعل بيكون الأمر أسهل بيكون الأمر سهل + +322 +00:28:19,720 --> 00:28:26,740 +بيكون الأمر سهل تقريبا بهيك بنكون غطينا احنا موضوع + +323 +00:28:28,150 --> 00:28:32,530 +الـ cycle addition reactions باللخص اللي أخذنا منه + +324 +00:28:32,530 --> 00:28:35,870 +الـ one three bipolar cycle addition والـ deals + +325 +00:28:35,870 --> 00:28:40,250 +alder والـ two plus two والـ Chelotropic بأنواعها + +326 +00:28:40,250 --> 00:28:45,690 +بالتأكيد يعني بأمل إنكم تجيبولي أقل تقدير مثال + +327 +00:28:45,690 --> 00:28:49,270 +سواء على two plus two cycle addition أو الـ + +328 +00:28:49,270 --> 00:28:52,550 +Chelotropic reaction كل ما قرأت أكثر كل ما تعبت + +329 +00:28:52,550 --> 00:28:58,790 +أكثر فتحت المجلات أكثر بتصيروا ايش؟ familiar أكثر + +330 +00:28:58,790 --> 00:29:07,330 +بجزء الكيميا طالما + +331 +00:29:07,330 --> 00:29:16,170 +وصلنا لهيك يمكن كلكم تتذكرون عشان الإنسان يكمل + +332 +00:29:16,170 --> 00:29:22,550 +موضوع الـ synthesis إن احنا قلنا الـ synthesis بشكل + +333 +00:29:22,550 --> 00:29:28,360 +عام ثلاث طرق الأولى Cyclization one bond + +334 +00:29:28,360 --> 00:29:32,260 +formation الطريقة الثانية Cycloaddition two bond + +335 +00:29:32,260 --> 00:29:38,000 +formation الطريقة الثالثة Ring Transformation حلقة + +336 +00:29:38,000 --> 00:29:45,420 +معينة تفتح وتسكر سواء كبرت أو صغرت بنفس الحجم كل + +337 +00:29:45,420 --> 00:29:51,240 +الأمثلة موجودة الآن بشكل عام النوع الأول الـ + +338 +00:29:51,240 --> 00:29:55,060 +cyclization reaction اللي بعمله الإنسان وبيخطط + +339 +00:29:55,060 --> 00:29:59,300 +له إنه بيطلع زي هيك الـ Cycloaddition reaction + +340 +00:29:59,300 --> 00:30:04,520 +الإنسان بعمله بيجيب القطعتين وبيجيبول آمل أني أحضر + +341 +00:30:04,520 --> 00:30:08,340 +هذا المركب من الـ Cycloaddition reaction واضح الـ + +342 +00:30:08,340 --> 00:30:13,240 +ring transformation تسعين في المية إذا مش أكثر + +343 +00:30:13,240 --> 00:30:18,240 +بتطلع للإنسان صدفة يعني لا هي على البال ولا على + +344 +00:30:18,240 --> 00:30:22,720 +الخاطر بيكون الإنسان قاعد بيشتغل بحلقة معينة + +345 +00:30:22,720 --> 00:30:28,860 +بيتفاجأ أن الحلقة فتحت أو سكرت بإيش؟ بشكل جديد + +346 +00:30:28,860 --> 00:30:34,580 +ولذلك مرات بيكون الأمر مفاجئ للإنسان ليش؟ لأنه هو + +347 +00:30:34,580 --> 00:30:39,540 +ما بيفكرش يعني شخص بيعمل تفاعل بتوقع ناتج قاعد + +348 +00:30:39,540 --> 00:30:43,840 +بيحاول يشوف بالـ IR بالـ NMR بالـ mass بالأجهزة + +349 +00:30:43,840 --> 00:30:48,980 +الطيفية الناتج حسب ما هو بيفكر لكن ما بيجيش على باله + +350 +00:30:48,980 --> 00:30:56,320 +إن التفاعل فاجأه وعمل ring transformation، بالذات + +351 +00:30:56,320 --> 00:31:00,560 +لما مرات أثناء الـ ring transformation كمان تفقد + +352 +00:31:00,560 --> 00:31:05,320 +أجزاء تفقد أجزاء من المواد المتفاعلة وعشان ذلك + +353 +00:31:05,320 --> 00:31:09,700 +مرات بالعافية الإنسان يعني بده يعني complete + +354 +00:31:09,700 --> 00:31:15,180 +spectroscopic evidence أو X-ray للمركب لما يصير + +355 +00:31:15,180 --> 00:31:19,840 +مقتنع إنه تمت هالـ ring transformation على أي حال + +356 +00:31:19,840 --> 00:31:25,060 +أنا هأطرح عليكم بعض الأمثلة وأكيد أنتم بإمكانكم + +357 +00:31:25,060 --> 00:31:29,120 +تجيبوا أمثلة ثانية يعني مجرد ما تكتبوا العنوان + +358 +00:31:29,120 --> 00:31:33,380 +ring transformation هتلاحظوا كده إن فيه أمثلة في + +359 +00:31:33,380 --> 00:31:40,950 +الدنيا عليها معظم الأمثلة اللي بدي أطرحها عليكم اليوم + +360 +00:31:40,950 --> 00:31:46,130 +يعني خليني أقول كانت من شغلي وكانت من المصادفات + +361 +00:31:46,130 --> 00:31:52,370 +اللي طلعت عندي أثناء ما كنت يعني بأشتغل ولذلك ربما + +362 +00:31:52,370 --> 00:31:57,010 +كل مثال في ذهن الإنسان إله قصة يعني لاحظوا المدرس + +363 +00:31:57,010 --> 00:32:01,140 +لما بيشرح مثلا دي ال elder reaction هو بيجيب أمثلة + +364 +00:32:01,140 --> 00:32:04,520 +من الـ literature لكن عمري ما عملت deals under + +365 +00:32:04,520 --> 00:32:08,280 +reaction بدرسها لكن ما اشتغلتش deals under reaction + +366 +00:32:08,280 --> 00:32:12,120 +لكن لما مثلا بدي أجي أحكي one three bipolar cycle + +367 +00:32:12,120 --> 00:32:15,220 +addition reactions لأ اشتغلت كثير أمثلة ring + +368 +00:32:15,220 --> 00:32:18,780 +transformation تقريبا معظم الأمثلة اللي بدنا + +369 +00:32:18,780 --> 00:32:25,780 +نجيبها هي أمثلة يعني عصرناها اشتغلناها طلعت معنا + +370 +00:32:25,780 --> 00:32:32,050 +صدفة ما كناش ايش متوقعينها الآن خلينا نجيب مثال + +371 +00:32:32,050 --> 00:32:37,230 +اشتغلوه غيرنا لكن مثال بسيط وواضح بيوضح لنا الفكرة + +372 +00:32:38,340 --> 00:32:45,640 +هذا المثال عبارة عن تترازولون طبعا تترازول لأنه + +373 +00:32:45,640 --> 00:32:49,700 +حلقة خماسية ولما يكون عليه C double bond O هنقول + +374 +00:32:49,700 --> 00:32:55,500 +عليه ايش كـ general name تترازولون الآن انتبهوا معي + +375 +00:32:55,500 --> 00:33:00,240 +لما تكونوا بتلقوا محاضرات أو بتلقوا أبحاث تخرج أو + +376 +00:33:00,240 --> 00:33:05,830 +في المستقبل في مؤتمرات عمر الإنسان هو بيشرح ما + +377 +00:33:05,830 --> 00:33:12,310 +بيقعد يسمي المركب تسمية كاملة بيضيع وقت الناس واضح؟ + +378 +00:33:12,310 --> 00:33:16,830 +يعني هذا المركب لما أنا بدي اسميه تسمية كاملة بدي + +379 +00:33:16,830 --> 00:33:21,170 +أقول one two three four one four dimethyl one four + +380 +00:33:21,170 --> 00:33:26,670 +dihydrotetrasol five all مش ممكن يكون مقبول وانتوا + +381 +00:33:26,670 --> 00:33:30,310 +بتكونوا تفهموا الناس إنكم تقولوا one one + +382 +00:33:30,310 --> 00:33:34,130 +four dimethyl one four dihydrotetrasol five all + +383 +00:33:34,130 --> 00:33:39,470 +react with كذا to produce one two dimethyl هذا + +384 +00:33:39,470 --> 00:33:45,210 +الكلام مش وارد إنما تذكر الأسماء أو المركبات إما + +385 +00:33:45,210 --> 00:33:51,470 +برقم يعني نقول compound 5 produces مثلا compound 6 + +386 +00:33:52,270 --> 00:33:56,950 +أو بالـ General Name تبع العائلة يعني نقول هذا + +387 +00:33:56,950 --> 00:34:02,870 +Tetrazolone خلاص okay بالفوتوليسيز هذا التترازولون + +388 +00:34:02,870 --> 00:34:06,210 +بيفقد نيتروجين يعني أنتم بإمكانكم لو تخيلتوا إن + +389 +00:34:06,210 --> 00:34:10,890 +هنا الإلكترونات هي هدول الاثنين عملوا صاروا ايش + +390 +00:34:11,900 --> 00:34:14,940 +جزء النيتروجين بثلاث روابط بيبقى الإلكترون و + +391 +00:34:14,940 --> 00:34:20,640 +الإلكترون عملوا bond فاعطونا هذه الحلقة الثلاثية + +392 +00:34:20,640 --> 00:34:27,520 +طبعا هذا عبارة عن نوع من ايش الحلقة كانت خماسية + +393 +00:34:27,520 --> 00:34:34,000 +صارت ثلاثية وفوق جزء نيتروجين هذا شغل واحد ألماني + +394 +00:34:34,000 --> 00:34:41,100 +اسمه ايش Kvast ومجموعته في الخمسين والسبعين لكن + +395 +00:34:41,100 --> 00:34:45,060 +بيوضح لكم ايش معنى ring contraction يعني تحديدا + +396 +00:34:45,060 --> 00:34:55,000 +الآن نجي لأمثلة ثانية هذا المثال أو هذا المركب + +397 +00:34:55,000 --> 00:35:00,620 +هذا المركب حقيقة لو بتتطلع عليه تم تحضيره من الـ + +398 +00:35:00,620 --> 00:35:03,560 +Cycloaddition لازم يصير عندكم خبرة لأنه احنا + +399 +00:35:03,560 --> 00:35:06,120 +قلنا الـ 1,3-dipolar cycloaddition من أشهر الـ + +400 +00:35:06,120 --> 00:35:11,480 +Nitrile Oxide وين بتشوفوا C double bond and O + +401 +00:35:11,480 --> 00:35:15,120 +هدول ارجعوا فيهم إنه ممكن يكونوا Nitrile Oxide + +402 +00:35:15,120 --> 00:35:21,790 +okay ضاف على C double bond and ويمكن ناقشنا C + +403 +00:35:21,790 --> 00:35:26,570 +double bond anhydrazone إذا هذه حلقة خماسية نشأت + +404 +00:35:26,570 --> 00:35:30,670 +من الـ cycle addition الآن هذه الحلقة الخماسية + +405 +00:35:30,670 --> 00:35:39,960 +بتحمل هنا مجموعة Amino طيب مجموعة الـ Amino كلنا + +406 +00:35:39,960 --> 00:35:45,700 +بنعرف تفاعلاتها يعني لو احنا اجينا قلنا لكم لو + +407 +00:35:45,700 --> 00:35:51,000 +سمحتوا بدنا نفاعل مجموعة RNH2 يعني معادلة organic + +408 +00:35:51,000 --> 00:35:56,080 +عامة RNH2 + +409 +00:35:56,080 --> 00:36:00,920 +زائد على سبيل المثال Easter ولا acid chloride + +410 +00:36:02,020 --> 00:36:08,800 +خلينا نقول acid chloride CH3CW bond OCL هذا very + +411 +00:36:08,800 --> 00:36:13,760 +general reaction معروف بالنسبة لنا ولا لأ إن هذا + +412 +00:36:13,760 --> 00:36:24,680 +الـ amino بتتفاعل هنا بتطرد الـ CL وبيصير عندي RNH عمد + +413 +00:36:24,680 --> 00:36:29,500 +CW bond O نفترض CH3 + +414 +00:36:30,540 --> 00:36:36,280 +واضح؟ هذا تفاعل طبيعي جدا الآن نفس التفاعل فكر + +415 +00:36:36,280 --> 00:36:40,720 +الإنسان إنه يعمله مع acid chloride خليني أقول هذا + +416 +00:36:40,720 --> 00:36:45,240 +in general XC double bond OCL اللي أنتم بتتوقعوه + +417 +00:36:45,240 --> 00:36:50,740 +طبيعي إن هذه بدأت تهاجم هنا عندي C double bond O و + +418 +00:36:50,740 --> 00:36:54,380 +C L شو اللي بده يترد؟ الـ acid chlorides undergo + +419 +00:36:54,380 --> 00:36:58,400 +substitution reaction حيصير عندي N H C double bond + +420 +00:36:58,400 --> 00:37:03,200 +O X هالـ X هذه ممكن تكون هيدروجين مثل فينيل CH2CL + +421 +00:37:03,200 --> 00:37:08,140 +كل هذا كأمثلة انُعمل + +422 +00:37:08,140 --> 00:37:17,300 +الحقيقة أنه اللي بيصير أنه هذا التفاعل نفسه لما عمل + +423 +00:37:17,300 --> 00:37:22,800 +بتسخين من المرة الأولى و بحرارة عالية ما أعطى هذا + +424 +00:37:22,800 --> 00:37:26,820 +الناتج يعني هذا الناتج .. هذا الناتج كان + +425 +00:37:26,820 --> 00:37:34,700 +intermediate مرّ التفاعل فيه و راح عمل شغل إضافية + +426 +00:37:36,080 --> 00:37:39,980 +عمل ring transformation يعني ما وقف أنا الآن أي + +427 +00:37:39,980 --> 00:37:43,460 +بني آدم بيتوقع أنه بده التفاعل عبارة عن + +428 +00:37:43,460 --> 00:37:48,320 +condensation جمع فيه جزيئين و في الـ molecular mass + +429 +00:37:48,320 --> 00:37:52,480 +بده يطلع هالجزيئين مجموعات و يشوف عنده C double + +430 +00:37:52,480 --> 00:37:57,400 +bond O و يشوف عنده N H يعني تخيلوا أن أحد بيعمل هذا + +431 +00:37:57,400 --> 00:38:03,830 +التفاعل و بده يعمل تحليل صار ولا ما صار له بدأت بال + +432 +00:38:03,830 --> 00:38:07,230 +IR أسوأ الأجهزة أو أقل الأجهزة فائدة بقول اه والله + +433 +00:38:07,230 --> 00:38:12,970 +كان هنا فيه N H 2 هذه الـ N H 2 مثلا من منطقة 3300 + +434 +00:38:12,970 --> 00:38:19,070 +سنتمتر minus one ايش صارت؟ صارت N H واحدة وصار عندي + +435 +00:38:19,070 --> 00:38:26,210 +C double bond O لو بدي أنا الـ IR هذا الكلام اللي + +436 +00:38:26,210 --> 00:38:30,990 +بدي أطلعه، الآن بنفس الناتج، بني آدم يتفاجأ، لا في أنه + +437 +00:38:30,990 --> 00:38:38,550 +أتش ولا في C double bond O ولو كنا بنتطلع على مثلا + +438 +00:38:38,550 --> 00:48:43,830 +الـ NMR افترضه أنا عندي مثل و مثل كمان الـ مثل و + +439 +00:38:43,830 --> 00:38:50,210 +الـ مثل طارق فالانسان بيبدأ ايش في هذه الحالات يتغلب + +440 +00:38:50,210 --> 00:38:53,950 +بيبدأ الإنسان يتغلب و أحيانا ما تصدقوش أن الواحد + +441 +00:38:53,950 --> 00:39:00,920 +أخذ شهرين ثلاثة هو بيحاول يفهم ايش اللي صار معه في + +442 +00:39:00,920 --> 00:39:05,820 +النهاية اللي صار كما يبدو أن هذا الجزء فوقه ككيتون + +443 +00:39:05,820 --> 00:39:10,580 +و هذه الـ oxygen سواء بهذا الشكل أو تخيلتوا أن + +444 +00:39:10,580 --> 00:39:15,720 +عندكم الـ tautomeric form يعني تخيلوها هذه double bond + +445 +00:39:15,720 --> 00:39:22,380 +N و هذه OH عند اللزوم الآن هذه اسكت هنا هذول + +446 +00:39:22,380 --> 00:39:25,020 +صاروا بمثل الحلقة الجديدة + +447 +00:39:27,860 --> 00:39:42,680 +طلعوا O C N N C واضحة الفكرة O C N N C O C N N C + +448 +00:39:42,680 --> 00:39:48,400 +هذا المركب اللي طلع عندي 134 Oxadiazol + +449 +00:39:51,640 --> 00:39:56,440 +طبعا هل فعلا هذا الجزء فقد على شكل كيتون؟ الإنسان + +450 +00:39:56,440 --> 00:40:00,080 +بعد ذلك بالتجربة بيحاول يفحص هل محلول التفاعل فيه + +451 +00:40:00,080 --> 00:40:05,350 +كيتون ولا لأ؟ يمكن فحص مواجهة كيتونال nitrogen + +452 +00:40:05,350 --> 00:40:09,870 +أكيد فقدت لكن بأي طريقة is not clear مش دائما + +453 +00:40:09,870 --> 00:40:17,050 +الكلام عام طيب هل التفاعل بالتأكيد بالتأكيد مرّ عبر + +454 +00:40:17,050 --> 00:40:22,050 +هذا المركب الوسيط ولا لأ؟ لاحظوا الإنسان أول ما + +455 +00:40:22,050 --> 00:40:28,270 +بيفعل بيحط هذا مع ايش؟ يسخنه حرارة فصل هذا النتج + +456 +00:40:28,270 --> 00:40:32,810 +وما فصلش هذا الآن بعد ما يتعب و ياخد له شهر شهرين + +457 +00:40:32,810 --> 00:40:37,570 +تعب و تفكير okay فهم الصورة بيرجع يقول طب يا تورا + +458 +00:40:37,570 --> 00:40:44,750 +لو عملت التفاعل بحرارة بسيطة و انتبهت أكثر ممكن + +459 +00:40:44,750 --> 00:40:52,580 +أفصل هذا الناتج الوسطاني الحقيقة أنه تم فصل في + +460 +00:40:52,580 --> 00:40:56,220 +الأول واحد بيسخن على طول و مشي واتفاعل واتكون + +461 +00:40:56,220 --> 00:41:00,300 +واتفاعل على اللي بعده، الآن بدي أهدي ايش؟ ظروف + +462 +00:41:00,300 --> 00:41:04,440 +التفاعل، يمكن أن يفصل هذا، يمكن أن يفصل هذا، طيب، + +463 +00:41:04,440 --> 00:41:09,420 +الآن هذا ممكن لو سخناها مع نفس ظروف التفاعل أو + +464 +00:41:09,420 --> 00:41:12,840 +مثلا الـ Trifluoroacetic Anhydrite كعمل مساعد، + +465 +00:41:12,840 --> 00:41:19,360 +أسكر لهذا، الجواب آه إذا هذا التفاعل تم بالتسخين + +466 +00:41:19,360 --> 00:41:25,820 +المباشر و فصلنا هذا و تم كمان ايش؟ على تدرج بحيث + +467 +00:41:25,820 --> 00:41:30,540 +أننا نفصل الـ intermediate و نتأكد منها و نشخصها و + +468 +00:41:30,540 --> 00:41:34,680 +نشوف فعلا زي ما قلنا في الـ IR و في الـ NMR الـ N H و + +469 +00:41:34,680 --> 00:41:38,400 +الـ C double bond O هدول مازالوا موجودين فجأة كل + +470 +00:41:38,400 --> 00:41:44,390 +شيء تغير و هدول طلعوا و بس بنحصل على مركب يعني + +471 +00:41:44,390 --> 00:41:48,590 +لو افترضتوا هذه كانت مثلا Methyl يعني كنا مستعملين + +472 +00:41:48,590 --> 00:41:52,070 +Acetylchloride فقط هتشوفوا هنا الـ Methyl و + +473 +00:41:52,070 --> 00:41:55,590 +البنزينة طب و الأشياء اللي كانت هنا كلها و أنا + +474 +00:41:55,590 --> 00:42:04,050 +كله ايش ماله؟ اختفى هذا Ring Transformation تحوّل + +475 +00:42:04,050 --> 00:42:10,410 +في الـ 1,2,4 أكزا دايازول لـ 1,3,4 أكزا دايازول + +476 +00:42:10,410 --> 00:42:14,750 +يعني هذه حلقة خمسية صارت حلقة خمسية بس بالتأكيد + +477 +00:42:14,750 --> 00:42:20,220 +هذه بوضعية هذه بوضع ثاني يمكن البعض يقول طب ليش + +478 +00:42:20,220 --> 00:42:25,300 +بيصير هيك ring transformation دائما؟ أي شخص بده + +479 +00:42:25,300 --> 00:42:30,860 +يحسّن ظروفه بيحسّن للأفضل ولا للأسوأ؟ للأفضل انتبهوا + +480 +00:42:30,860 --> 00:42:38,880 +أن هذا is non aromatic هذا aromatic فربما تكون الـ + +481 +00:42:38,880 --> 00:42:42,280 +aromaticity هي الدافع أنه يصير هذا الـ ring + +482 +00:42:42,280 --> 00:42:46,350 +transformation واضح الـ stability المرتبطة بالـ + +483 +00:42:46,350 --> 00:42:50,890 +conjugation اللي هي الـ delocalization الـ energy و + +484 +00:42:50,890 --> 00:42:54,910 +الـ كذا ربما أن هي تكون الدافعة لحظة هذه يعني + +485 +00:42:54,910 --> 00:42:59,430 +بعتبرها ring transformation محظوظة ليش؟ لأن أنا + +486 +00:42:59,430 --> 00:43:03,050 +كمان فصلت الـ intermediate يعني أحيانا صعب أن + +487 +00:43:03,050 --> 00:43:06,830 +الإنسان يكون حاطط product و يقول بتوقع أنه مرّ + +488 +00:43:06,830 --> 00:43:10,810 +عبرها الـ intermediate لكن أقوى دليل إذا الإنسان + +489 +00:43:10,810 --> 00:43:15,600 +ايش ماله؟ فصل الـ intermediate و شخصه وعوّض حطه بظروف + +490 +00:43:15,600 --> 00:43:23,040 +التفاعل و خلى يكمل التفاعل و هذا تقريبا اللي صار + +491 +00:43:23,040 --> 00:43:29,320 +بهذا المثال الآن + +492 +00:43:29,320 --> 00:43:34,620 +أحيانا الإنسان لما بيعمل ring transformation معيّن + +493 +00:43:34,620 --> 00:43:41,570 +و بفهمه جيدا بيصير بإمكانه يعمّمها واضحة الفكرة يعني + +494 +00:43:41,570 --> 00:43:47,050 +خليني أجعل هذا الـ ring transformation حقيقة أول ما + +495 +00:43:47,050 --> 00:43:52,210 +عملت كنا نسخن مع CH2Cl يعني كان المركب اللي احنا + +496 +00:43:52,210 --> 00:43:57,970 +بنفاعل معه هو C double bond OCl وهنا ايش اللي + +497 +00:43:57,970 --> 00:44:01,930 +موجود؟ CH2Cl + +498 +00:44:01,930 --> 00:44:06,330 +طبعا التفاعل هيكون من هذه القمعين وهنا وبالتالي الـ + +499 +00:44:06,330 --> 00:44:13,380 +X ايش كانت؟ CH2CN هذا أول معويل التفاعل الآن بيصير + +500 +00:44:13,380 --> 00:44:16,260 +الواحد يسأل نفسه السؤال شوف كيف الـ project بيبدأ + +501 +00:44:16,260 --> 00:44:21,140 +يكبر مع بني آدم طب يا تورا لو غيرت هذه الحمرة بـ + +502 +00:44:21,140 --> 00:44:26,860 +مثل بـ فنل بـ H برضه بيصير ring transformation ولا لأ؟ + +503 +00:44:26,860 --> 00:44:35,710 +بيصير جرد في كل الأحوال صح؟ واضحة يعني بيبدأ بمثال + +504 +00:44:35,710 --> 00:44:42,630 +لكن بإمكانه هنا يصير يعمل تغيير معيّن وبالتالي بدل + +505 +00:44:42,630 --> 00:44:49,450 +ما كانت هذه بس CH2CL قدرنا نحط General formula X + +506 +00:44:49,450 --> 00:44:55,290 +قدرنا نحقنه كتب ايش؟ X الآن في كل الأحوال عندي أنا + +507 +00:44:55,290 --> 00:45:00,190 +ربما أهم شغل بهذه المنطقة ايش؟ الـ C double bond O + +508 +00:45:00,190 --> 00:45:05,270 +شوف كيف الواحد ممكن يطور الأفكار طب خليني أجيب C + +509 +00:45:05,270 --> 00:45:10,940 +double bond O خارج نطاق خارج نطاق الـ .. الـ acid + +510 +00:45:10,940 --> 00:45:15,440 +chlorides اللي طلعت هذه المراكبات ايش فيه مراكبات + +511 +00:45:15,440 --> 00:45:22,780 +فيها C double bond O الـ isocyanates الـ isocyanates + +512 +00:45:22,780 --> 00:45:31,640 +مش phenyl N C double bond هي phenyl N double bond + +513 +00:45:31,640 --> 00:45:39,240 +C double bond O و الـ isocyanate phenyl N double bond + +514 +00:45:39,240 --> 00:45:45,160 +C double bond S الآن لو بدها تيجي الـ amino تهاجم + +515 +00:45:45,160 --> 00:45:51,660 +وين هتهاجم الـ amino؟ على هذه الـ carbon هذه هتلف هنا + +516 +00:45:51,660 --> 00:45:58,160 +تعطيني N H فحسين عندي N H من هنا C double + +517 +00:45:58,160 --> 00:46:07,170 +bond O أو S وبعدين هذا بتصفى unmatched final هل + +518 +00:46:07,170 --> 00:46:11,530 +بيمكن أعمل التفاعل بهدوء و أفصل هدول المركبين okay + +519 +00:46:11,530 --> 00:46:16,910 +ممكن طيب لو حطينا لهم catalyst هل هدول التانين + +520 +00:46:16,910 --> 00:46:22,630 +هيسكروا هنا بنفس الطريقة كل هذا الجزء زي ما اتفقنا + +521 +00:46:22,630 --> 00:46:29,470 +و يصير عندي OCNNC بس هنا ايش أصبحت؟ حاملة unmatched + +522 +00:46:29,470 --> 00:46:34,510 +final مازال 134 اكزا بيازول طب لو استعملتي الـ + +523 +00:46:34,510 --> 00:46:38,290 +sulfur وجدت ايش هيصير هنا + +524 +00:46:46,530 --> 00:46:52,490 +الحقيقة أنه فعلا ممكن تم وفعلا فصلت هذه المراكبات + +525 +00:46:52,490 --> 00:46:57,350 +و هدول يعني الـ touring transformation كانوا + +526 +00:46:57,350 --> 00:47:00,990 +منشورين في مجلة الـ heterocycles اليابانية و الـ + +527 +00:47:00,990 --> 00:47:06,290 +journal heterocycle chemistry الأمريكية في أوائل + +528 +00:47:06,290 --> 00:47:13,900 +التسعينات يعني قبل ما يقارب الـ 15-16 سنة فهدول + +529 +00:47:13,900 --> 00:47:20,240 +أمثلة على ايش؟ ring transformations خلينا ناخد + +530 +00:47:20,240 --> 00:47:25,260 +مثال ثاني على الـ ring transformations هذا المثال + +531 +00:47:25,260 --> 00:47:30,080 +هذا precursor of nitrile oxide اللي اتكلمنا عنه + +532 +00:47:30,080 --> 00:47:35,040 +اللي هو chloroxime مصيره ايش؟ هيعطيه Nitral oxide + +533 +00:47:35,040 --> 00:47:40,220 +الآن الـ nitral oxide ممكن من ناحية المبدأ زي ما + +534 +00:47:40,220 --> 00:47:45,380 +حكينا تتفاعل على الـ double bond و تعمل cycle + +535 +00:47:45,380 --> 00:47:49,360 +addition يعني لو احنا قلنا لكم أكمل المعادلة + +536 +00:47:49,360 --> 00:47:55,140 +Nitral oxide هذا مع الـ double bond أكثر شيء ممكن + +537 +00:47:55,140 --> 00:48:00,710 +تفكروا فيه أنكم تعملوا ايش؟ cycloaddition على الـ + +538 +00:48:00,710 --> 00:48:09,190 +double bond وقتها هتكتبوا الناتج R N R عفوا + +539 +00:48:09,190 --> 00:48:15,590 +C double bond N O وهنا تحطوا C N هذه اللي هي هذه + +540 +00:48:15,590 --> 00:48:24,450 +الـ C N حاملة R prime و R double prime وهنا NH CH3 + +541 +00:48:24,450 --> 00:48:28,930 +هذا الـ product Cycloaddition هذه Nitral oxide وهذه + +542 +00:48:28,930 --> 00:48:32,710 +الـ double bond هذا الـ 1,3-dipolar cycloaddition + +543 +00:48:32,710 --> 00:48:37,210 +product ويمكن تلاحظوا أن هذا الـ 1,3-dipolar + +544 +00:48:37,210 --> 00:48:40,250 +cycloaddition product هو الناتج اللي اتكون في + +545 +00:48:40,250 --> 00:48:45,170 +الأمثلة اللي قبل شوية بس بشرط لما كانت هذه un-H و H + +546 +00:48:45,170 --> 00:48:50,630 +un-H2 أنه أنا كان ايش معالج عندكم؟ un-H2 ارجعوا + +547 +00:48:50,630 --> 00:48:54,870 +للمثال اللي بدأنا فيه هذه أصلها شو كان + +548 +00:48:58,880 --> 00:49:05,820 +هيدرازون R R C double bond N N H Methyl R R C + +549 +00:49:05,820 --> 00:49:08,340 +double bond N N H Methyl + +550 +00:49:16,290 --> 00:49:20,050 +cycloaddition product لكن الكيمياء زي ما قلنا بدن + +551 +00:49:20,050 --> 00:49:24,530 +المرة ألف علم ايش ماله؟ تجريبية ما مشت cycloaddition + +552 +00:49:24,530 --> 00:49:29,790 +product لما فقدت الـ HCl مع الـ triethylamine إجت هذه + +553 +00:49:29,790 --> 00:49:32,350 +اتفاعلت هان على الكاربون هذا في نهاية الـ + +554 +00:49:32,350 --> 00:49:36,510 +nucleophile الكاربون إلكتروفيل وهذه الـ O سكرت هنا + +555 +00:49:36,510 --> 00:49:41,510 +وهذه صارت N H أعطتني شيء بسميه Cyclo + +556 +00:49:41,510 --> 00:49:44,850 +-condensation يعني اتنين تفاعل نيوكليوفيل + +557 +00:49:44,850 --> 00:49:49,230 +إلكتروفيل هذا نيوكليوفيل هذا إلكتروفيل هذا + +558 +00:49:49,230 --> 00:49:54,850 +نيوكليوفيل هذا إلكتروفيل C N هي موجب هي سلب هذه + +559 +00:49:54,850 --> 00:49:58,790 +الآن نيوكليوفيل هذه الكربون في الـ wolffry dipol + +560 +00:49:58,790 --> 00:50:03,730 +إلكتروفيل فهذا التفاعل بنسميه Cyclo-condensation + +561 +00:50:03,730 --> 00:50:09,060 +أعطى حلقة سداسية مش Cyclo addition ما تمشي التفاعل + +562 +00:50:09,060 --> 00:50:12,580 +مع الـ Methylhydrazone بالـ Cycloaddition reaction + +563 +00:50:12,580 --> 00:50:16,300 +فهذا كان آخر شيء شرحته لكم المرة الماضية في الـ + +564 +00:50:16,300 --> 00:50:22,160 +Cycloaddition الآن لاحظوا هذا المثال أعطاني حلقة + +565 +00:50:22,160 --> 00:50:28,780 +سداسية فيها Oxygen وكام نيتروجينة Oxytriazine + +566 +00:50:30,480 --> 00:50:35,560 +In general أوكسى ترايزين، الآن انتبهوا معي، في ناس + +567 +00:50:35,560 --> 00:50:40,140 +قبل هيك عملوا هذا التفاعل بشروط تفاعل مختلفة وما + +568 +00:50:40,140 --> 00:50:44,660 +طلعش معاهم أوكسى ترايزين عشان هيك تصيروا تنتبهوا + +569 +00:50:44,660 --> 00:50:51,410 +أكثر أن التفاعل مش بس المواد المتفاعلة، التفاعل هو + +570 +00:50:51,410 --> 00:50:56,810 +المواد المتفاعلة وشروط التفاعل تمامًا زي ما نيجي + +571 +00:50:56,810 --> 00:51:01,950 +نقول أن التربية مش بس اللي بنعلمه لابننا في الدار + +572 +00:51:01,950 --> 00:51:05,930 +اللي بنعلمه لابننا في الدار والبيئة المحيطة ولدت + +573 +00:51:05,930 --> 00:51:10,430 +ربّ في منطقة كلها يعني عفواً شوارع وإشي مش زي ما + +574 +00:51:10,430 --> 00:51:13,870 +ولدت ربّ مثلًا في منطقة كلها أخلاق وأدب وناس + +575 +00:51:13,870 --> 00:51:17,750 +محترمين، واضح؟ يعني هي أنا بدي آخد الـ Hydrazinol + +576 +00:51:17,750 --> 00:51:23,770 +chloride مع هذا وأغير بس هذه الشروط وفي فعل الناس + +577 +00:51:23,770 --> 00:51:28,050 +غيروا هذه الشروط بدل ما يستعملوا الـ Triethylamine + +578 +00:51:28,050 --> 00:51:33,830 +والـ Chloroform استعملوا Ether مع reflux تمام + +579 +00:51:33,830 --> 00:51:39,530 +استعملوا Ether مع reflux ما طلعش معهم هذا الناتج + +580 +00:51:39,530 --> 00:51:46,440 +طلع معهم ناتج غريب جداً 1,2,4-Triazole + +581 +00:51:46,440 --> 00:51:50,400 +1,2,3,4-Triazole لما بدهم + +582 +00:51:50,400 --> 00:51:54,480 +يفسروا بيقولوا Okay خلينا نتخيل أنه هذه + +583 +00:51:54,480 --> 00:51:58,540 +Nucleophile على عين وراسه هاجمت على الـ + +584 +00:51:58,540 --> 00:52:02,420 +Electrophile اللي هان بعد فقد هذا، الآن احنا قبل + +585 +00:52:02,420 --> 00:52:07,540 +شوية كملنا أن هذا Nucleophile بيهاجمها، طب ما الـ + +586 +00:52:07,540 --> 00:52:10,060 +Nitrogen كمان عليها زوج إلكترونات + +587 +00:52:12,640 --> 00:52:16,180 +الملاحظين أنتو كيف المنطق يعني؟ إذا جمّلنا بالخطوة + +588 +00:52:16,180 --> 00:52:22,140 +الأولى خلاص ماشيناها شبكنا هذا من هذا، الآن هي الـ + +589 +00:52:22,140 --> 00:52:29,680 +Nucleophile وهي الـ Nucleophile، الهجوم من هذه الـ + +590 +00:52:29,680 --> 00:52:33,520 +Oxygen أعطى أي ناتج الحلقة السداسية، الحلقة + +591 +00:52:33,520 --> 00:52:37,640 +السداسية، طيب يا ترا لو تم الهجوم من الـ Nitrogen + +592 +00:52:37,640 --> 00:52:44,500 +بيعطي الخماسية وبيصير عنده OH OH جنب بعض، بفقد ايش؟ + +593 +00:52:44,500 --> 00:52:49,900 +بفقد التريازول، بفقد ماء بيصير التريازول، 1,2, + +594 +00:52:49,900 --> 00:52:55,660 +4-التريازول، واضح؟ الآن كما يبدو أن هذا التفاعل + +595 +00:52:55,660 --> 00:52:59,620 +لما تم بالـ Ether والـ reflux نشر ناس ريزيتانو + +596 +00:52:59,620 --> 00:53:04,320 +مجموعة معينة أعطى الحلقة الخماسية، لما ناس عملوه على + +597 +00:53:04,320 --> 00:53:08,160 +البارد بتريثيل أمين وكلوروفورم أعطى الحلقة + +598 +00:53:08,160 --> 00:53:12,820 +السداسية عشان مجرد تغيير الـ Condition قد يُغير + +599 +00:53:12,820 --> 00:53:17,480 +في الناتج، لحتى الآن احنا جبنا سيرة الـ Ring + +600 +00:53:17,480 --> 00:53:23,260 +Transformation، لأ جبنا أن هذا التفاعل في ظرفين + +601 +00:53:23,260 --> 00:53:28,480 +مختلفين أعطى نواتج مختلفة وقدرنا نفهمه منطقيًا يعني + +602 +00:53:28,480 --> 00:53:32,060 +أنه بدأ بالنيوكليوفيليك Addition وبعدين بده يسكر أي + +603 +00:53:32,060 --> 00:53:38,200 +من الـ Two نيوكليوفايلز بده يهاجم بيصير الآن بعد هيك + +604 +00:53:38,200 --> 00:53:43,440 +كانت المفاجأة أن نفس هذا السداسي ممكن يعمل Ring + +605 +00:53:43,440 --> 00:53:49,630 +Transformation ويصير خماسي، يفتح ويقعد يسكر من أول + +606 +00:53:49,630 --> 00:53:54,690 +وجديد على الخماسي، يعني بعد ما تكون كان مجرد تسخين + +607 +00:53:54,690 --> 00:53:59,950 +لهذا مع الـ Acetic Acid وحتى يعني أنا ما زلت بقول + +608 +00:53:59,950 --> 00:54:02,870 +أنه لأ سخناه كمان لحاله يعني حاطينه في الـ Test + +609 +00:54:02,870 --> 00:54:07,450 +Tube كـ Solid وسخناه على النار حاسينه ماء بتطلع + +610 +00:54:07,450 --> 00:54:13,590 +منه شفنا بخار وتكسر وسكر من أول وجديد، الآن كل + +611 +00:54:13,590 --> 00:54:19,510 +الفكرة أنه فتح من هنا، هذه صارت OH هجت الـ H هنا وهذه + +612 +00:54:19,510 --> 00:54:26,390 +صارت Double Bond N، الـ N بعد هيك ردّ سكر منها، واضحة + +613 +00:54:26,390 --> 00:54:30,810 +الفكرة يعني كأنه كان مسكر هيك بحلقة سداسية كبيرة + +614 +00:54:30,810 --> 00:54:37,830 +فتح وسكر على أصغر منها سكر على حلقة خماسية وأعطى + +615 +00:54:37,830 --> 00:54:42,930 +للـ Triazole اللي حصل عليه الجماعة الثانية، واضح؟ هذه + +616 +00:54:42,930 --> 00:54:46,490 +هي ببساطة Ring Transformation، احنا ايش قلنا Ring + +617 +00:54:46,490 --> 00:54:51,250 +Transformation ببساطة؟ Ring Opening و New Ring + +618 +00:54:51,250 --> 00:54:55,630 +Cyclization، أنه صار عنده Ring Opening وبعد ما + +619 +00:54:55,630 --> 00:55:01,130 +فتحت الحلقة كانت زي هيك سكرت من جهة ثانية، طبعًا هذا + +620 +00:55:01,130 --> 00:55:04,670 +نوع من الـ Ring Contraction + +621 +00:55:06,200 --> 00:55:13,040 +ستة صارت خمسة، This is a Ring Contraction Ring + +622 +00:55:13,040 --> 00:55:17,280 +Transformation أو Reaction واضحة هذه الفكرة + +623 +00:55:17,280 --> 00:55:23,040 +ولاحظوا + +624 +00:55:23,040 --> 00:55:27,640 +مرة ثانية ربما يعني للي بيفكر ايش اللي بيخلي + +625 +00:55:27,640 --> 00:55:33,580 +التفاعل يمشي زي هيك أن هذا Aromatic Stability + +626 +00:55:35,600 --> 00:55:40,780 +أن هو آآآآآآ + +627 +00:55:40,780 --> 00:55:43,180 +آآآآآآآآآآآآ + +628 +00:55:43,180 --> 00:55:53,600 +آآآآآآآآآآآآ + +629 +00:56:05,790 --> 00:56:09,770 +فكروا بالـ Neutral Amine يعني لو أنا كنت بدأ أفكر + +630 +00:56:09,770 --> 00:56:17,430 +بهذا بفكر بـ C Double Bond N وحطه هنا Ar وحطه هنا + +631 +00:56:17,430 --> 00:56:21,790 +Acetyl، هذا Neutral Amine لما يفقد الـ HCl بده يكون + +632 +00:56:21,790 --> 00:56:31,550 +زي هيك، طب وهذه الـ R RCl هذه الحقيقة أصلها C + +633 +00:56:31,550 --> 00:56:41,270 +Double Bond N O H، أوكسيم C Double Bond N O H، الآن + +634 +00:56:41,270 --> 00:56:44,910 +لما أفعل هذا مع أوكسيم شو اللي بتوقع أنا كـ Cycle + +635 +00:56:44,910 --> 00:56:51,610 +Addition أنه من هنا الـ Double Bond تروح ومن هنا + +636 +00:56:51,610 --> 00:56:55,950 +تروح، طبعًا الزوج الإلكتروني بييجيها Two New Sigma + +637 +00:56:55,950 --> 00:57:04,300 +Bonds وهيكون هنا ايش عندكم O H، الأصل أنه ايش اللي + +638 +00:57:04,300 --> 00:57:10,800 +معلق على الآن OH، هذا الـ Cycloaddition بطريقة ما + +639 +00:57:10,800 --> 00:57:16,820 +ما زالت لحد الآن مش معروفة بيفقد الـ Oxygen وصار Un + +640 +00:57:16,820 --> 00:57:20,760 +-Etch يعني لو أنتو بتكملوا المعادلة منطقيًا + +641 +00:57:20,760 --> 00:57:26,580 +Cycloaddition of Oxime مع نيترال أمين الأصل ايش + +642 +00:57:26,580 --> 00:57:33,720 +يعطيكم؟ أن حاملة O H، الآن إذا قدرت قادر أعطاه N + +643 +00:57:33,720 --> 00:57:38,820 +H مع العلم التفاعل الموازي للنيترال أكسيد مع + +644 +00:57:38,820 --> 00:57:43,160 +أوكسيم مسجل أنه بيعطي O H، موجود ناس معينين عاملينه + +645 +00:57:43,160 --> 00:57:50,700 +لكن هذا أعطاه N H N H، الآن هذا الحقيقة شغل + +646 +00:57:50,700 --> 00:57:55,480 +Cycle Addition احنا اشتغلناه وعندنا يعني Evidence + +647 +00:57:55,480 --> 00:58:00,120 +100% يعني نقدر نقول له أنه فعلاً فقد الـ Oxygen + +648 +00:58:00,120 --> 00:58:04,600 +عاملينه Nitrogen 15 NMR، كل أنواع التحاليل عملنا + +649 +00:58:04,600 --> 00:58:09,700 +أكثر من نشرة منه في مجلات محترمة فعلاً هو زي هيك + +650 +00:58:09,700 --> 00:58:13,460 +الآن أهم شيء لاحظوا أن هذا Aromatic ولا Non + +651 +00:58:13,460 --> 00:58:19,710 +Aromatic، نون أروماتيك، طب في N H لو قلنالكو أكمل + +652 +00:58:19,710 --> 00:58:26,250 +المعادلة مع Acidic Anhydride Substitution بده يحط + +653 +00:58:26,250 --> 00:58:29,670 +Acetyl، يعني هذا الآن بده تحط الـ C Double Bond O + +654 +00:58:29,670 --> 00:58:35,390 +CH3 لمن الـ Acetyl، مجرد حط المركب سخنه مع Acidic + +655 +00:58:35,390 --> 00:58:40,530 +Anhydride الأصل أنه يطلع عندنا هذا الناتج، الكلام + +656 +00:58:40,530 --> 00:58:45,750 +منطقي ولا لأ؟ الآن بقدرة قادر لاحظنا أنه فقدت جزء + +657 +00:58:45,750 --> 00:58:51,650 +كبير من الجزء، فقدت هذه الأشياء كلها وبيطلع عندنا + +658 +00:58:51,650 --> 00:58:57,990 +1,2,4-التريازول مختلف وأروماتيك، لاحظوا هذا + +659 +00:58:57,990 --> 00:59:05,530 +أروماتيك، هذا ما كانش أروماتيك وفقدت الـ R والـ R والـ + +660 +00:59:05,530 --> 00:59:12,690 +... هدول بالذات بشكل أساسي، طيب ايش اللي صار + +661 +00:59:12,690 --> 00:59:16,490 +بيحاول الإنسان يحط تفسير كيف صارت الـ Ring + +662 +00:59:16,490 --> 00:59:21,150 +Transformation، خلنا نقول أن تخيلنا أن هذه السيطة + +663 +00:59:21,150 --> 00:59:25,610 +بالـ Bond O ممكن تيجي على الـ R والـ R اللي هنا تهاجم + +664 +00:59:25,610 --> 00:59:31,310 +تعمل نوعًا ما ما يشبه الحلقة الرباعية وبعد هيك من + +665 +00:59:31,310 --> 00:59:37,310 +هنا يفقد هذا الـ RRC مع الـ O على شكل كيتون وتيجي الـ + +666 +00:59:37,310 --> 00:59:40,230 +Nitrogen اللي هنا تسكر على الـ Carbon اللي هنا + +667 +00:59:40,230 --> 00:59:43,450 +هيطلع + +668 +00:59:43,450 --> 00:59:47,930 +عندي هذا المركب الـ Aromatic اللي فقد بشكل أساسي + +669 +00:59:47,930 --> 00:59:54,470 +هدول شغلتين وهذا الـ Oxygen، الآن من ناحية تشخيص + +670 +00:59:54,470 --> 00:59:58,790 +تشخيص سليم 100% ما في مشكلة، من ناحية التفسير + +671 +00:59:58,790 --> 01:00:04,160 +التفسير ما حدش بيتدعى أنه تفسيره سليم، لإيش؟ لأن أنا + +672 +01:00:04,160 --> 01:00:07,880 +أنا بحط Intermediates يعني إشي أنا مش شايفه يعني + +673 +01:00:07,880 --> 01:00:14,820 +المركبات، المركبات، Okay الإنسان بيقدر يشوفها يعني + +674 +01:00:14,820 --> 01:00:19,380 +هذا شفناه، الآن هذا ما شفناهش وهذا ما شفناهش وهذا + +675 +01:00:19,380 --> 01:00:23,420 +ما شفناهش، لكن بيحاول الإنسان يتخيل أنه كيف على أقل + +676 +01:00:23,420 --> 01:00:27,620 +تقدير تم هذا الكلام، في كل الأحوال هذا عبارة عن + +677 +01:00:27,620 --> 01:00:33,820 +Ring Transformation، حلقة خماسية بترتيب معين صارت + +678 +01:00:33,820 --> 01:00:39,580 +حلقة خماسية ثانية، هذه Non Aromatic هذه Aromatic + +679 +01:00:39,580 --> 01:00:47,430 +فقدت جزيئات معينة، فقدت الـ RCR فقدت أشياء كثيرة، هذه + +680 +01:00:47,430 --> 01:00:51,870 +Ring Transformation، الآن تخيلوا أن إنسان طلب منه + +681 +01:00:51,870 --> 01:00:56,870 +أنه بس يعمل Acetylation لهذه هل بدون ما يفصل ناتج + +682 +01:00:56,870 --> 01:01:00,690 +عمره كان بيتوقع أنه بيصير هيك شغلات عشان هيك أنا + +683 +01:01:00,690 --> 01:01:04,570 +بقول أن الـ Ring Transformation مفاجئة بتطلع + +684 +01:01:04,570 --> 01:01:12,530 +للإنسان وبتعب لما يصل لتشخيص المركب وأحيانًا بتعب + +685 +01:01:12,530 --> 01:01:18,210 +أنه يحط أيش تفسير كيف تم التفاعل، بتعب أني أحط تفسير + +686 +01:01:18,210 --> 01:01:24,790 +أيضًا كيف تم التفاعل، نأخذ + +687 +01:01:24,790 --> 01:01:31,310 +كمان Ring Transformations ثانية نفس هذا المركب + +688 +01:01:31,310 --> 01:01:36,370 +اللي بدأنا فيه طوالي، لاحظوا ايش كنا كاتبين الكيمائية + +689 +01:01:36,370 --> 01:01:40,670 +Acetyl، طب لو أجينا فرغنا الـ Acetyl، الـ Acetyl عبارة عن + +690 +01:01:40,670 --> 01:01:47,940 +ايش؟ C Double Bond O CH3، من حقنا نفكر أنه بدنا نعمل + +691 +01:01:47,940 --> 01:01:53,640 +عليها أوكسيم، إنسان فاعل هذا مع هيدروكسيل أمين، الـ C + +692 +01:01:53,640 --> 01:01:58,420 +Double Bond O ببدأ تصير C Double Bond N O H ويفصل + +693 +01:01:58,420 --> 01:02:04,260 +أوكسيم، عمركوا عملتم أوكسيم في المختبر؟ أكيد في مختبر + +694 +01:02:04,260 --> 01:02:08,760 +Organic عام بيعملوا هيدرازون وأوكسيم كيتون أو + +695 +01:02:08,760 --> 01:02:13,740 +الديهيد، هذا كيتون زاد هيدروكسيل أمين بالتسخين شوية + +696 +01:02:13,740 --> 01:02:21,200 +بيعطيني أوكسيم، الآن هذا التفاعل كيتون مع هيدروكسيل + +697 +01:02:21,200 --> 01:02:25,840 +أمين الحقيقة بالتسخين أعطاش الـ أوكسيم أعطى مركب + +698 +01:02:25,840 --> 01:02:33,920 +ثاني وحلقة سداسية، جلب المركب بشكل غريب جدًا، اللي + +699 +01:02:33,920 --> 01:02:40,520 +أنا اتخيله أنه إنسان بنتظر الأوكسيم وبفكر حاله طلع + +700 +01:02:40,520 --> 01:02:46,770 +الأوكسيم وهو نطلع مركب ثاني، واضح؟ جدّيش بدّه يأخذ منه + +701 +01:02:46,770 --> 01:02:51,910 +وقت لما يكتشف أنه لا التفاعل ضحك عليه وطلع له مركب + +702 +01:02:51,910 --> 01:02:56,090 +ثاني أنا بقى أذكر أن هذا الكلام يمكن أخذ له ما + +703 +01:02:56,090 --> 01:03:01,760 +يقارب الخمس، ست أشهر من الدكتور نبيل الحلبي لما كان + +704 +01:03:01,760 --> 01:03:05,660 +بيعمل الدكتوراه تبعته يعني هذا جزء من الدكتوراه + +705 +01:03:05,660 --> 01:03:09,800 +تبعته في النهاية انتبهوا معه لما اكتشفنا أن هذا + +706 +01:03:09,800 --> 01:03:12,680 +التفاعل فعلا عملها الـ ring transformation اللي + +707 +01:03:12,680 --> 01:03:18,800 +هنشرحها قولنا طب خلينا نشتغل الأجزيم بهدوء على نار + +708 +01:03:18,800 --> 01:03:26,360 +هادئة بإمكاننا نفصله في الأولادة ما كان مفصول بهدوء + +709 +01:03:26,360 --> 01:03:29,980 +وبشروط خليه يتحرك لحاله طالت أربع أيام على البارد + +710 +01:03:29,980 --> 01:03:36,380 +بلاش بنص ساعة على السخن انفصل الأجزيم انحلت ايش نص + +711 +01:03:36,380 --> 01:03:40,380 +المشكلة طيب يا ترى هل الأجزيم هذا لو بقعد يكسخ + +712 +01:03:40,380 --> 01:03:44,420 +خناه مرة ثانية مع نفسه المحلول بيعمل ring + +713 +01:03:44,420 --> 01:03:48,240 +transformation اه اذا هذا التفاعل من التفاعلات + +714 +01:03:48,240 --> 01:03:53,360 +اللي بتسخيل كثير مشي بهذا الشكل وليجدر بالإنسان + +715 +01:03:53,360 --> 01:04:01,510 +بنوع من الهدوء يفصل الـ intermediate أجزيم فيه واضحة + +716 +01:04:01,510 --> 01:04:05,930 +الفكرة جدر بالإنسان بنوع من الهدوء يفصل الـ + +717 +01:04:05,930 --> 01:04:10,130 +intermediate أجزيم طبعا الآن بيصير الإنسان يفكر طب + +718 +01:04:10,130 --> 01:04:16,010 +كيف يا ترى هذا الأجزيم هذا اللي فصلناه وسخناه و + +719 +01:04:16,010 --> 01:04:21,020 +أعطاه ذاك الناتج يعني أصلا عارفين أن هذا عبر هذا + +720 +01:04:21,020 --> 01:04:26,840 +الـ intermediate كيف هذا الكلام ممكن يكون تم جربنا + +721 +01:04:26,840 --> 01:04:35,830 +أن نعمل تفسير جربنا أن نعمل تفسير خلنا نشوف اللي + +722 +01:04:35,830 --> 01:04:40,810 +احنا حطناه التفسير اللي عملناه هي الـ example مرسوم + +723 +01:04:40,810 --> 01:04:45,850 +بطريقة معينة أن من هنا فقد هذا الجزء غالبا على + +724 +01:04:45,850 --> 01:04:52,070 +شكل الـ key ولو احنا حركنا هدول شوية بدلناهم شوية + +725 +01:04:52,070 --> 01:04:56,050 +روابط والجزء بلف زي ما بده يعني مجرد نخلي الـ N H + +726 +01:04:56,050 --> 01:05:03,760 +هذه لهنا نجيب هنا C double bond NOH يعني هذه + +727 +01:05:03,760 --> 01:05:11,320 +الكربون هذه الكربون خليني أعلمها هي نفسها هذه + +728 +01:05:11,320 --> 01:05:15,800 +الكربون لأن بعد ما يفقد هذا على شكل alkyl شو حملة + +729 +01:05:15,800 --> 01:05:23,000 +هذه الكربون H minus صفية وحملة C حملة مثل double + +730 +01:05:23,000 --> 01:05:28,680 +bond L و H حطوه بهذا الشكل وبعد هيك كملوا الـ + +731 +01:05:28,680 --> 01:05:36,640 +cyclization بهذا الشكل وهذا تصير ايش فكل + +732 +01:05:36,640 --> 01:05:41,540 +اللي تم عملية فقد هذا الجزء عملية فقد هذا الجزء + +733 +01:05:41,540 --> 01:05:45,780 +carbon تنتل تلاتة وغالبا أن هذا الجزء فقد على شكل + +734 +01:05:45,780 --> 01:05:53,020 +ايش لكن وحصلنا على حلقة سداسية لأن هذا نوع من + +735 +01:05:53,020 --> 01:05:59,940 +الايش ring expansion أو enlargement ring expansion + +736 +01:05:59,940 --> 01:06:05,160 +وكان مبين أنه صار فيه amino group واضحة كان مبين + +737 +01:06:05,160 --> 01:06:09,760 +أن صار فيه amino group واضحة وتم تشخيص هذا + +738 +01:06:09,760 --> 01:06:15,240 +المركب والكلام يعني تم نشره في الـ journal in + +739 +01:06:15,240 --> 01:06:19,660 +Organica Chemica Act يعني مجلة محترمة + +740 +01:06:20,840 --> 01:06:25,880 +الآن كل الهدف اللي كان عندنا حقيقة مش الـ ring + +741 +01:06:25,880 --> 01:06:32,500 +transformation الـ ring transformation اجت وين؟ هجت + +742 +01:06:32,500 --> 01:06:37,740 +على جانب ليش؟ لأن احنا الهدف اللي كان عندنا نحضر + +743 +01:06:37,740 --> 01:06:41,880 +الـ oxime زي ما بيعملوا جماعة الـ inorganic جماعة الـ + +744 +01:06:41,880 --> 01:06:47,680 +inorganic بدهم by ligand عشان يجيبوا metal هي الآن + +745 +01:06:47,680 --> 01:06:52,420 +عليها زوج إلكترونات وهي الآن etch الآن مع metal زي + +746 +01:06:52,420 --> 01:06:58,560 +nickel 2 plus مثلا لما نحط اتنين من هذا مش هيعملوا + +747 +01:06:58,560 --> 01:07:04,240 +روابط وحدة coordinate covalent وواحدة رابط عادية + +748 +01:07:04,240 --> 01:07:09,420 +covalent bond هي أنا فقدت H وكمان جزء زيه بيفقد H + +749 +01:07:09,420 --> 01:07:15,540 + وكل اللي بدنا نحصل عليه الـ complex اللي يكون عامل + +750 +01:07:15,540 --> 01:07:21,000 +complexation وين؟ على هذه الـ nitrogen تبعت الـ + +751 +01:07:21,000 --> 01:07:26,820 +oxime وعلى هذه الـ H لاحظوا لما نفقد من هنا H ومن + +752 +01:07:26,820 --> 01:07:32,460 +الجزء الثاني H هي صار كم سالب عنده والـ metal + +753 +01:07:32,460 --> 01:07:37,220 +موجب بـ اتنين اذا بيطلع له .. بيطلع له complex + +754 +01:07:37,220 --> 01:07:44,660 +للأسف الشديد مرة ثانية اللي لاحظناه ما أعرفش إذا هذه + +755 +01:07:44,660 --> 01:07:48,920 +الصورة مكبرينها ولا لا مرة ثانية اللي لاحظناه احنا + +756 +01:07:48,920 --> 01:07:54,580 +بنحط الـ metal عشان يتفاعل من هنا من الجهتين واضح + +757 +01:07:54,580 --> 01:08:00,180 +يعني هيعمل زي هيك وهيطلع الشكل الثاني اللي لاحظ + +758 +01:08:00,180 --> 01:08:05,880 +ما هو كان متعب إلا يعني أخذ وقت كثير أنه برضه + +759 +01:08:05,880 --> 01:08:10,220 +التفاعل ما تمشي زي هيك شو هالتفاعلات اللي بتغلب + +760 +01:08:10,220 --> 01:08:15,420 +قبلها شو عمل التفاعل التفاعل بيجي على باله بطريقة + +761 +01:08:15,420 --> 01:08:21,100 +ما أنه يكسر هذه الرابطة انتبهوا معي شوفوا ايش اللي + +762 +01:08:21,100 --> 01:08:26,100 +بيصير جوا الجزئية الـ N كسر هذه لفوها هاتوا الـ + +763 +01:08:26,100 --> 01:08:30,200 +carbon هنا وشبكوها على هذه الـ N في مشكلة بعد ما + +764 +01:08:30,200 --> 01:08:33,480 +كسرت هذه اللي هاني بلفها صارت هانا الـ carbon اللي + +765 +01:08:33,480 --> 01:08:39,640 +حاملة ايش R و R وشبكوها على الـ N صار عند هذه الحلقة + +766 +01:08:39,640 --> 01:08:44,580 +الخمسية واحد اثنين تلاتة أربعة خمسة يعني هذه الـ + +767 +01:08:44,580 --> 01:08:45,520 +CRR + +768 +01:08:47,660 --> 01:08:52,960 +كسرت من هذه الـ N واجت شبكة في هذه الـ N زي كانها + +769 +01:08:52,960 --> 01:08:59,640 +كانت شبكتها شبكتها ماني هانا شبكة بايش؟ بـ N وهانا + +770 +01:08:59,640 --> 01:09:08,540 +شبكة بـ N كسرت شبكة منها الـ N وين صار عندي؟ وين صار + +771 +01:09:08,540 --> 01:09:12,970 +عندي الـ nitrogen اللي ممكن يعمله؟ الـ complex مع + +772 +01:09:12,970 --> 01:09:18,070 +الـ metal على هذا المكان واضح الـ nitrogens اللي ممكن + +773 +01:09:18,070 --> 01:09:21,370 +يعملوا الـ complex مع الـ metal هنا وصار عندكم هنا N + +774 +01:09:21,370 --> 01:09:25,930 +أو ماينوس يعني تم عملية أكسدة ايش الـ H والـ H في + +775 +01:09:25,930 --> 01:09:32,790 +مجمل الجزئية واضح N أو ماينوس والجزئية اتغيرت هذا لو + +776 +01:09:32,790 --> 01:09:38,320 +بدأوا يعملوا complex هيعملوا من هنا إطلاقا مش الكلام + +777 +01:09:38,320 --> 01:09:42,940 +الأول يعني لاحظوا أن الحلقة اللي احنا بدأنا فيها + +778 +01:09:42,940 --> 01:09:49,080 +شو كانت one two four triazole يعني الـ heterocyclic + +779 +01:09:49,080 --> 01:09:57,420 +ring الأساسية تطلع عليها one two four triazole + +780 +01:09:57,420 --> 01:10:02,080 +الآن لما بيعمل هيك وبيلف هذا شو صارت الحلقة + +781 +01:10:02,080 --> 01:10:04,840 +الأساسية imidazole + +782 +01:10:06,010 --> 01:10:13,730 +13 diazole imidazole وحامل أكسجين الـ hetero cycle هي + +783 +01:10:13,730 --> 01:10:17,750 +imidazole وحامل أكسجين بعض الناس بيقول معقول + +784 +01:10:17,750 --> 01:10:21,890 +هالكلام ولا بتتخيلوا + +785 +01:10:21,890 --> 01:10:27,170 +أنه كان وكسر وعمل يعني هذه ring transformation + +786 +01:10:27,170 --> 01:10:34,130 +ثانية بالتأكيد لو لأن الإنسان فصل كريستال وعمل X + +787 +01:10:34,130 --> 01:10:38,150 +-ray كريستالوجرافي ولا عمر حد في الدنيا بيصدق هذا + +788 +01:10:38,150 --> 01:10:42,890 +الكلام واضح؟ هذه الـ images ولاحظوا مش الـ Nitrogens + +789 +01:10:42,890 --> 01:10:49,420 +دائما بنرسمها بالأزرق والأكسجين بالأحمر الأعضاء + +790 +01:10:49,420 --> 01:10:52,700 +الـ imidazole هي الـ N O وهي الكربون اللي حاملة + +791 +01:10:52,700 --> 01:10:56,860 +مجموعتين الميثيل اللي رسمناها هذه الحلقة الجديدة + +792 +01:10:56,860 --> 01:11:05,300 +شايفينها؟ الآن هذا نتاج X-ray في بعض الـ X-ray الـ X + +793 +01:11:05,300 --> 01:11:09,380 +-ray ايش بيسموه؟ determination يعني you are sure + +794 +01:11:09,380 --> 01:11:14,250 +of this structure يعني أنت مش جاعد الـ spectroscopic + +795 +01:11:14,250 --> 01:11:20,590 +evidence NMR IR Carbon 13 هذا الإنسان بيشك فيه + +796 +01:11:20,590 --> 01:11:26,610 +ليش؟ لأن فيه شوية عجل ممكن يكون غلط والدليل على + +797 +01:11:26,610 --> 01:11:32,010 +هيك أن انتوا في امتحان التشخيص كلكوا عندكوا الـ + +798 +01:11:32,010 --> 01:11:37,270 +spectra IR Proton Mass Carbon 13 صح ولا لأ؟ بس مش + +799 +01:11:37,270 --> 01:11:41,920 +كلكوا بتجيبوا 100% ليش؟ لأن بتستعملوا العقل و + +800 +01:11:41,920 --> 01:11:46,740 +العقل يمكن أن يخطئ عشانك ناس بيجيبوا تسعين ناس + +801 +01:11:46,740 --> 01:11:49,400 +بيجيبوا ثمانين ناس بيجيبوا سبعين طب يا رب كل الـ + +802 +01:11:49,400 --> 01:11:53,380 +spectra عندكوا صح الـ spectra مش موضوع خلاف الركع + +803 +01:11:53,380 --> 01:11:58,220 +لايش الركع العقل ولذلك الـ spectroscopic evidence + +804 +01:11:58,220 --> 01:12:02,300 +ممكن أنكوا تخطئوا فيه عشانكوا بتجيبوش علامة كاملة + +805 +01:12:02,300 --> 01:12:08,470 +في كورس التشخيص الآن الـ X-ray زي بني آدم راح عنده + +806 +01:12:08,470 --> 01:12:12,610 +كسر بإيده حطه على جهاز الـ X-Ray شافوا الكسر شو + +807 +01:12:12,610 --> 01:12:18,310 +ضال كلام؟ خلاص عملنا X-Ray ولذلك الـ X-Ray في الـ + +808 +01:12:18,310 --> 01:12:24,610 +.. بيسموه Structure Determination تحديد بينما كل + +809 +01:12:24,610 --> 01:12:29,530 +سبكتروسكوبي شو بيسمي احنا؟ Structure Elucidation + +810 +01:12:29,530 --> 01:12:34,150 +الـ Elucidation بعمش مرة معاكم كلمة ولا لأ؟ + +811 +01:12:34,150 --> 01:12:34,970 +استنتاج + +812 +01:12:38,150 --> 01:12:42,110 +structure elucidation انتوا بتستنتجوا + +813 +01:12:42,110 --> 01:12:46,390 +الشكل طالما بتستنتجوا شغل المخ المخ يمكن ايش ان + +814 +01:12:46,390 --> 01:12:51,930 +يخطئ لكن لما أنا بحكي عن structure determination + +815 +01:12:51,930 --> 01:12:58,850 +هذا وين بشوفه؟ بالـ X-ray طلع لي صورة X-ray بعد صورة + +816 +01:12:58,850 --> 01:13:03,230 +الـ X-ray لما بيصوروا الفك مثلا وبيشوفوا أنه طحونة + +817 +01:13:03,230 --> 01:13:08,470 +عجل مسوسة ولا اشي زي هيك بضلش إلا أنه بدهم يخلعوها + +818 +01:13:08,470 --> 01:13:13,210 +خلاص شفنا الصورة واضح؟ هذا الكلام لو لأن الإنسان + +819 +01:13:13,210 --> 01:13:17,230 +شاف الـ X-Ray ولا عمره فكر أنه تصير هيك ring + +820 +01:13:17,230 --> 01:13:21,530 +transformation إطلاقا ولا بتكون على الباب الآن + +821 +01:13:21,530 --> 01:13:26,930 +اتخيلوا انتوا عاد لما يكون شخص جاعد بيشتغل project + +822 +01:13:26,930 --> 01:13:32,270 +عشان تفهموا الفرق ما بين التجربة وما بين الواقع + +823 +01:13:32,270 --> 01:13:36,630 +العملي قاعد بيشتغل project وبده يعمل هذا الأجزيم + +824 +01:13:36,630 --> 01:13:40,630 +شوف ايش اللي حطه في الـ proposal تكوين هذا الأجزيم + +825 +01:13:40,630 --> 01:13:45,810 +وبعدين ييجي metal هنا يتفاعل على الأجزيم وسخن و + +826 +01:13:45,810 --> 01:13:49,930 +بده بالخطوة الثانية بده يخلط الـ metal وما إلى ذلك + +827 +01:13:49,930 --> 01:13:55,130 +لا طلع معه هذا الأجزيم في الأول طلع معه organic + +828 +01:13:55,130 --> 01:13:59,770 +product ثاني أخذ له ست شهور لما فهم الشغل عوض اشتغل + +829 +01:13:59,770 --> 01:14:05,950 +على البارد فصل ايش الـ oxime بعد ما فصلوه يلا يا + +830 +01:14:05,950 --> 01:14:09,310 +oxime بدنا ياك تتفعل مع الـ metal هنا حطوه مع الـ + +831 +01:14:09,310 --> 01:14:15,050 +nickel اسيتات ولا ايش زي هيك برضه الناتج بيطلع + +832 +01:14:15,050 --> 01:14:23,430 +غريب وبينجلب المجموعات لو لأن في تقنيات حديثة زي + +833 +01:14:23,430 --> 01:14:28,090 +الـ X-Ray أنا متأكد يمكن لو ما عرضتش عليكم X-Ray تلت + +834 +01:14:28,090 --> 01:14:32,870 +أرباعكم ما بيصدقش هالأشياء أن والله هذه كسرت ولفت + +835 +01:14:32,870 --> 01:14:39,110 +واجت هنا إلا إذا في ثقة متبادلة + +836 +01:14:39,110 --> 01:14:45,690 +ولا الكلام بمنطق الـ .. بمنطق الـ .. العقل دائما الـ + +837 +01:14:45,690 --> 01:14:53,420 +rigid transformation بقول HDG مفاجئ وبياخد من الناس + +838 +01:14:53,420 --> 01:14:58,480 +وقت كثير وعشان هيك ممكن الناس يخلطوا في شغلات + +839 +01:14:58,480 --> 01:15:03,380 +كثيرة يعني ممكن تشوفوا انتوا كعناوين للمقالات + +840 +01:15:03,380 --> 01:15:07,260 +ويجرب حد منكوا يدخل على الـ google search بتلاقوا + +841 +01:15:07,260 --> 01:15:12,460 +العنوان اسمه the correct structure of كذا ايش معنى + +842 +01:15:12,460 --> 01:15:20,270 +الكلام أن في ناس قبل هيك اشتغلوا الشغل وحطوا شيء + +843 +01:15:20,270 --> 01:15:25,090 +معين، incorrect، مش صح، ناس عادوا من وراهم جاء لهم + +844 +01:15:25,090 --> 01:15:28,070 +يا عم اللي أنتم استنتجتوا في ال spectroscopic + +845 +01:15:28,070 --> 01:15:34,350 +بشغلكم وكذا، مش صح، هذا الشكل الصحيح في منطقة + +846 +01:15:34,350 --> 01:15:39,530 +الكيميا يعني ما لم يكتمل the evidence بشكل كبير و + +847 +01:15:39,530 --> 01:15:44,150 +من أفضل إكمال the evidence أنه الإنسان يشوف + +848 +01:15:44,150 --> 01:15:47,790 +structure مثلا ب X-ray على سبيل المثال بيضل + +849 +01:15:47,790 --> 01:15:53,750 +الإنسان ايش بيشوف الآن بعد هيك بيصير الإنسان واثق + +850 +01:15:53,750 --> 01:15:58,850 +من الشكل لكن مش كثير أحيانا بيكون واثق من + +851 +01:15:58,850 --> 01:16:03,690 +التفسيرات اللي حطها كيف تم هذا التكون يعني انتبهوا + +852 +01:16:03,690 --> 01:16:10,230 +معي أنه في عندي شكل لما بصل أنا ل X-ray أنا بقول I + +853 +01:16:10,230 --> 01:16:14,870 +am sure أنا تأكدت من الشكل الآن طب كيف صار زي كذا + +854 +01:16:14,870 --> 01:16:18,870 +مجون انكسر من هنا لهنا هذا موجب هذا سالب الآن هذه + +855 +01:16:18,870 --> 01:16:24,170 +المنطقة ممكن يكون فيها ايش خطأ لأن هذه منطقة عقل + +856 +01:16:24,170 --> 01:16:31,270 +ومنطقة تفسير فالانسان في كل يعني مبادئ حياته يكون + +857 +01:16:31,270 --> 01:16:38,320 +مميز بين شغلتين بين الشغلة اللي هي حقيقة وشغلة اللي + +858 +01:16:38,320 --> 01:16:44,320 +هي ايش تفسير الآن النظرية بشكل عام هي محاولة ايش + +859 +01:16:44,320 --> 01:16:50,760 +تفسير ولذلك أنتم الآن بتقدروا لأي شيء مجتمعي + +860 +01:16:50,760 --> 01:16:57,260 +تقولوا أن هذا الكلام حقيقة يعني مثلا الموظفين بغزة + +861 +01:16:57,260 --> 01:17:06,980 +لم يتقاضوا راتب هذا حقيقة لا تحتمل الخطأ لكن السبب + +862 +01:17:06,980 --> 01:17:12,300 +حكومة الوحدة ولا الحكومة السابقة ولا الدول المانحة + +863 +01:17:12,300 --> 01:17:17,750 +ولا الدول العربية هذه محاولات تفسير تحتمل الخطأ + +864 +01:17:17,750 --> 01:17:23,890 +الآن أصعب شيء إذا الإنسان دخل الجامعة وتخرج منها + +865 +01:17:23,890 --> 01:17:28,670 +وهو بتبنى وجهة نظر تفسيرية يحتمل غيرها ومصير عليها + +866 +01:17:28,670 --> 01:17:32,930 +معنا ذلك هذا ما تعلمش ثقافة الجامعة ثقافة الجامعة + +867 +01:17:32,930 --> 01:17:38,550 +أن الواحد يعرف ايش الشيء الأكيد ويقول هذا أكيد ايش + +868 +01:17:38,550 --> 01:17:43,470 +الشيء اللي بيحتمل ويقول هذا ايش يحتمل الآن هذا + +869 +01:17:43,470 --> 01:17:49,220 +الشكل أكيد التفسير غير أكيد، الآن في كثير من + +870 +01:17:49,220 --> 01:17:54,300 +الظواهر اللي في الحياة هتواجهكم، الظاهرة نفسها، + +871 +01:17:54,300 --> 01:17:58,360 +أكيدة، يعني أن اليوم صار عندها منخفض ونزل تلج + +872 +01:17:58,360 --> 01:18:04,240 +كثير، هذا شيء أكيد الآن بعض الناس يبدأوا تفسيرات و + +873 +01:18:04,240 --> 01:18:08,480 +الله هذا نتيجة ثاني أكسيد الكربون ولا نتيجة الكذا + +874 +01:18:08,480 --> 01:18:12,220 +ولا نتيجة تغيرات المناخية طب وكل واحد بيحط ايش + +875 +01:18:12,220 --> 01:18:18,380 +تفسير من عنده بأمل أنه يكون صار عندكوا فكرة ايش + +876 +01:18:18,380 --> 01:18:22,260 +معنى ال ring transformation بس بالتأكيد مش هيصير + +877 +01:18:22,260 --> 01:18:27,060 +ما عندكم إحساس ايش صارت إلا إذا كنتم بتشتغلوا + +878 +01:18:27,060 --> 01:18:31,200 +رسالة ماجستير وحصلت معكوا وأخرتكوا خمس .. خمس ست + +879 +01:18:31,200 --> 01:18:36,360 +شهور سبعة لحد ما تفهموها بكل الأحوال مطلوب منكوا + +880 +01:18:36,360 --> 01:18:41,720 +homework مثال على ال ring transformation مجرد ما + +881 +01:18:41,720 --> 01:18:46,480 +تكتبوا ring transformation هيجيكوا أنفلة كتيرة واضح + +882 +01:18:46,480 --> 01:18:49,600 +و بننهي لهذا القصد diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/nHngaEW_N3o_raw.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/nHngaEW_N3o_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..f3cedc0f3c0610b52add3fbfd0b12095467201a1 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/nHngaEW_N3o_raw.srt @@ -0,0 +1,3532 @@ +1 +00:00:21,290 --> 00:00:27,050 +بسم الله الرحمن الرحيم بنستمر في موضوع ال cycle + +2 +00:00:27,050 --> 00:00:31,390 +addition reactions المرة الماضية اتكلمنا عن ال + +3 +00:00:31,390 --> 00:00:34,810 +cycle addition كمفهوم عام و اتكلمنا عن ال 13 + +4 +00:00:34,810 --> 00:00:38,590 +-dipolar cycle addition يمكن في ال 13-dipolar + +5 +00:00:38,590 --> 00:00:43,200 +cycle additionحكينا فكرة عامة بالنسبة للميكانيزم + +6 +00:00:43,200 --> 00:00:47,240 +ان الميكانيزم ممكن تكون concerted mechanism او + +7 +00:00:47,240 --> 00:00:51,220 +radical mechanism الآن هذا الكلام هتلاحظه انه + +8 +00:00:51,220 --> 00:00:55,020 +بتكرر في deals under reaction بتكرر عند اللزوم في + +9 +00:00:55,020 --> 00:00:58,760 +two plus two cycle additions ولذلك مش هنعيد + +10 +00:00:58,760 --> 00:01:04,080 +الميكانيزم هنا مجرد اننا نتعرف على التفاعل و ناخد + +11 +00:01:04,080 --> 00:01:10,660 +أمثلة عنهالديلز ألدر ري أكشن بالنسبة لكم معروف و + +12 +00:01:10,660 --> 00:01:16,020 +دائما بتقولوا انه دايين و دايينوفايل بيتفاعلوا مع + +13 +00:01:16,020 --> 00:01:20,540 +بعض و بيعطوا حلقة سداسية فهو من ناحية ال buy + +14 +00:01:20,540 --> 00:01:25,260 +electron 4 plus 2 و من ناحية ال atoms 4 plus 2 + +15 +00:01:25,260 --> 00:01:32,750 +بيعطي حلقة سداسيةيمكن اول reaction انعمل كان + +16 +00:01:32,750 --> 00:01:37,370 +heterocyclic ولو ال deal's alder موجود منه امثلة + +17 +00:01:37,370 --> 00:01:40,510 +في الكاربو سايكليك كيميستري اكثر من heterocyclic + +18 +00:01:40,510 --> 00:01:44,790 +كيميستري لكن هنا في عندي ال cyclopentadiene هذا + +19 +00:01:44,790 --> 00:01:48,990 +بيمثل الدين وهنا الرابط بين ال nitrogen + +20 +00:01:48,990 --> 00:01:56,090 +والنيتروجينDiethyl azodicarboxylate وبيعملوا ال + +21 +00:01:56,090 --> 00:02:00,410 +cycle addition وهي الحلقة السادسية مع وجود ال + +22 +00:02:00,410 --> 00:02:06,530 +double bond هذا تقريبا اول مثال في ال deals elder + +23 +00:02:06,530 --> 00:02:13,400 +reaction خلينا نقول فيه thyro atoms واضح؟يمكن + +24 +00:02:13,400 --> 00:02:16,560 +انتوا متعودين على ال deal's elder reaction على + +25 +00:02:16,560 --> 00:02:21,880 +شغلة انكوا تقولوا في النهاية بدى شيء يكون مصدر + +26 +00:02:21,880 --> 00:02:25,700 +اكثر للالكترونات وشيء يكون electron deficient عشان + +27 +00:02:25,700 --> 00:02:30,700 +تم التفاعل الان اللي كنتوا تاخدوا انتوا انه الضيين + +28 +00:02:30,700 --> 00:02:35,390 +يكون عليه مجموعاتتكون معطية للإلكترونات electron + +29 +00:02:35,390 --> 00:02:40,050 +releasing groups والديينوفايل يكون عليه electron + +30 +00:02:40,050 --> 00:02:44,210 +with a drawing group كأنه صار عنده طرف سالب وطرف + +31 +00:02:44,210 --> 00:02:50,060 +موجب وهدولة بيعملوا deals under reactionبتقيل بدل + +32 +00:02:50,060 --> 00:02:53,280 +المرة الف قولنا احنا انه عشان انتوا تكملوا deals + +33 +00:02:53,280 --> 00:02:57,040 +under reaction بتتخيلوا مثل هذه الحركات لكن ال + +34 +00:02:57,040 --> 00:03:01,340 +mechanism بالتأكيد لأ is either a concerted + +35 +00:03:01,340 --> 00:03:03,760 +mechanism او a radical mechanism و اللي بيحكم + +36 +00:03:03,760 --> 00:03:10,290 +الكلام في النهاية التجربة اللي بتطلع عندناالان + +37 +00:03:10,290 --> 00:03:15,450 +طالما ان انا بقول بدي اشي سالب و اشي موجب بيصير + +38 +00:03:15,450 --> 00:03:19,730 +السؤال ما المانع .. ما المانع ان هذا الكلام ينعكس + +39 +00:03:19,730 --> 00:03:23,950 +يعني يكون هنا المجموعات المعطية للإلكترونات وهنا + +40 +00:03:23,950 --> 00:03:28,510 +المجموعات الساحبة للإلكترونات ما هو هيك اذا قلنا + +41 +00:03:28,510 --> 00:03:31,830 +هاي سالب وموجب ما المانع ان يكون سالب وموجب بهذا + +42 +00:03:31,830 --> 00:03:37,210 +الشكلمن ناحية النظرية البحثة مافيش و لا مانع يمكن + +43 +00:03:37,210 --> 00:03:41,210 +الناس أول أمثلة في deal's elder reaction كانت هذا + +44 +00:03:41,210 --> 00:03:44,890 +النوع من الأمثلة و لذلك اعتادوا انهم يحكوا زي هيك + +45 +00:03:44,890 --> 00:03:51,270 +الآن بالتأكيد الأمثلة التانية انوجدت و لذلك لما + +46 +00:03:51,270 --> 00:03:54,490 +انوجدت الأمثلة التانية ان هنا يكون مجموعات ساحبة + +47 +00:03:54,490 --> 00:04:00,720 +للإلكترونات وهنا مجموعات معطية للإلكتروناتبدوا + +48 +00:04:00,720 --> 00:04:06,620 +يطلقوا عليها اسم لأن هذا اعتبر كأصل أو شيء الموجود + +49 +00:04:06,620 --> 00:04:11,580 +في الأول سموها إيش inverse electron demand Diels + +50 +00:04:11,580 --> 00:04:15,520 +-Alder reaction يعني Diels-Alder معكوسة من ناحية + +51 +00:04:15,520 --> 00:04:18,060 +الفهم الإلكتروني يعني هنا ال electron releasing + +52 +00:04:18,060 --> 00:04:22,040 +groups وهنا ال electronwith drawing groups in + +53 +00:04:22,040 --> 00:04:28,280 +principle واضح فلو انتوا بدكوا تكتبوا فقط في اي + +54 +00:04:28,280 --> 00:04:32,360 +مجلة او على ال google search inverse electron + +55 +00:04:32,360 --> 00:04:36,100 +demand Diels-Alder reaction هيجيكوا عشرات ومئات + +56 +00:04:36,100 --> 00:04:41,120 +الأمثلة فالاحتمالين موجودين ال Diels-Alder بالصيغة + +57 +00:04:41,120 --> 00:04:44,420 +اللى اول ما بيتعلمها الطالب و ال Diels-Alder + +58 +00:04:44,420 --> 00:04:48,870 +بالطريقة خلينا نقول اللى معكوسةإلكترونيا عما + +59 +00:04:48,870 --> 00:04:54,330 +تعلموا بس في نهاية طريقتين صحيحة يا موجة بوسالد + +60 +00:04:54,330 --> 00:05:00,450 +الان إيش أشهر ال dienophiles و أشهر ال dienes اللي + +61 +00:05:00,450 --> 00:05:03,930 +تستعمل طبعا احنا ليش بنسميهم dienophiles ال double + +62 +00:05:03,930 --> 00:05:07,330 +bonds لأنه بيتفاعلوا مع ديين لو كانوا بتفاعلوا معه + +63 +00:05:07,330 --> 00:05:11,990 +three dipole كان إيش سمناهم dipolarophiles ممكن + +64 +00:05:11,990 --> 00:05:15,740 +تمتفاعل على C double bond Oبتكون double bond + +65 +00:05:15,740 --> 00:05:20,620 +الديهيدز او كيتونز على C double bond N امينز على C + +66 +00:05:20,620 --> 00:05:25,600 +triple bond N نيترالز C double bond S ثيو الديهيدز + +67 +00:05:25,600 --> 00:05:34,920 +او ثيو كيتونز NN ازو كربونيل كومباونز NO نيتروزو + +68 +00:05:34,920 --> 00:05:41,880 +كومباوند NS سالفينل امينز NS سالفينل هذا امين + +69 +00:05:41,880 --> 00:05:49,490 +سالفينل امينالان ال dials اكتر برضهممكن تكون عندك + +70 +00:05:49,490 --> 00:05:52,310 +alpha beta unsaturated carbonyl compound يعني هذا + +71 +00:05:52,310 --> 00:05:56,190 +carbonyl compound هذه الموقع alpha beta عشان ذلك + +72 +00:05:56,190 --> 00:06:00,030 +ايش قلنا عنه alpha beta unsaturated carbonyl + +73 +00:06:00,030 --> 00:06:02,870 +compound وهو اللي يمكن يطلع عندك و هذا من ال deals + +74 +00:06:02,870 --> 00:06:07,890 +elder reaction للناس اللي متذاكرين او alpha beta + +75 +00:06:07,890 --> 00:06:12,390 +unsaturated amines هذا carbonyl compound هذا amine + +76 +00:06:12,390 --> 00:06:19,940 +و alpha betaأو unvenil و unaryl اي means هاي عندى + +77 +00:06:19,940 --> 00:06:24,940 +برضه اي means و بتكون حاملة هنا مجموعة venil او + +78 +00:06:24,940 --> 00:06:31,560 +aryl اي means هذه الأشياء لاحظوا معاه مش ضرورى + +79 +00:06:31,560 --> 00:06:37,580 +تكون موجودة لوحدها يعني ممكن تكون موجودة ضمن حلقة + +80 +00:06:37,580 --> 00:06:42,180 +تماما زى أول مثال احنا حكيناه زى أول مثال احنا + +81 +00:06:42,180 --> 00:06:48,970 +حكيناه انهقولنا هاي ضايين لو بدنا نعلم الآن + +82 +00:06:48,970 --> 00:06:54,770 +الضايين من هنا هاي + +83 +00:06:54,770 --> 00:06:59,430 +الضايين لكن الضايين موجود ضمن إيش حلقة ضمن الcycle + +84 +00:06:59,430 --> 00:07:04,110 +بنت ضايين ولذلك هنا بنقول إحنا أن الضايين masked + +85 +00:07:04,110 --> 00:07:08,990 +masked من إيش من قناع يعني مختفي الجزء التالي + +86 +00:07:08,990 --> 00:07:17,660 +فبنصير في عندنا مصطلح maskeddienes في عندنا مصطلح + +87 +00:07:17,660 --> 00:07:22,880 +mask dienes الان لاحظوا هنا بيجيبلنا هذا المنظر + +88 +00:07:22,880 --> 00:07:28,100 +بعدين بيقولنا ممكن يكون موجود في ال oxazole طب ايش + +89 +00:07:28,100 --> 00:07:33,720 +هو ال oxazole one of three compound يعني انه هنا + +90 +00:07:33,720 --> 00:07:39,440 +oxygen لاحظوا الحلقة الخمسية ال oxazole الان صار + +91 +00:07:39,440 --> 00:07:46,390 +من ضمن ال oxazole هي ال dieneواضح؟ او بيجيبلي مثال + +92 +00:07:46,390 --> 00:07:49,990 +تاني في هذه الحالة the mask ضايق ممكن يكون موجود ب + +93 +00:07:49,990 --> 00:07:54,350 +one, two, four إتريازين إتريازين يعني تلت + +94 +00:07:54,350 --> 00:07:57,650 +نيتروجينات يعني كأنا بدي أحطها نيتروجين و أنا + +95 +00:07:57,650 --> 00:08:05,350 +نيتروجين الآن هذا ماصيروا إيش بعد ما يتفعل هيفقد + +96 +00:08:05,350 --> 00:08:10,560 +جزء ال nitrogen و لو كان أكزازون هيفقد جزءالـ + +97 +00:08:10,560 --> 00:08:16,640 +Oxygen الان هذا عبارة عن Mask الضيين واضح Mask + +98 +00:08:16,640 --> 00:08:22,540 +الضيين فانتوا ممكن تشوفوا مركب زي هذا و بنفس الوقت + +99 +00:08:22,540 --> 00:08:27,300 +تاخدوا جزء الضيين منه فقط هذا الجزء طب و الجزء + +100 +00:08:27,300 --> 00:08:32,840 +الثاني بيحدث الان هذا ال one two three four one + +101 +00:08:32,840 --> 00:08:36,020 +two four تريازين طب لو كان one two four five + +102 +00:08:36,020 --> 00:08:42,210 +تترازينلاحظوا ايش بده احط هنا ان double bond ان + +103 +00:08:42,210 --> 00:08:49,490 +الان هذا الجزء اللي مصيره هينحدث وينصف التترازين + +104 +00:08:50,550 --> 00:08:57,170 +عفوًا الضيين CNNC هذه الأربع ذرات تبعون الضيين + +105 +00:08:57,170 --> 00:09:03,770 +فالضيين can be a part of a ring واضح؟ وغالبًا هذا + +106 +00:09:03,770 --> 00:09:10,150 +الكلام ممكن يكون جزء من حلقة فيها جزء صغير يمكن أن + +107 +00:09:10,150 --> 00:09:15,210 +يفقد يعني إنتوا بتفكروا في أشهر الأشياء اللي يمكن + +108 +00:09:15,210 --> 00:09:18,830 +أن تفقد أشهر الأشياء اللي يمكن أن تفقد جزيات + +109 +00:09:18,830 --> 00:09:24,080 +نيتروجينممكن يكون التفكير بجزء carbon monoxide + +110 +00:09:24,080 --> 00:09:34,160 +مثلا بحلقة ما زي هيك و يكون عنده CO او CO2 لو بدي + +111 +00:09:34,160 --> 00:09:45,490 +CO2 بدي افكر بشغل زي هيك الان هي ال CO2ممكن + +112 +00:09:45,490 --> 00:09:49,610 +ينفقدها الواحد، التانية، التلاتة، أربعة، كل هذه + +113 +00:09:49,610 --> 00:09:54,310 +عبارة عن إيش؟ Masked Dains وعشان ذلك لما بنشوف أنا + +114 +00:09:54,310 --> 00:10:00,490 +الأسماء بنلاحظ أن أسماء حلقات كانت داين جزء من + +115 +00:10:00,490 --> 00:10:06,550 +الحلقة كانت داين جزء من إيش؟ جزء من الحلقة وهذا + +116 +00:10:06,550 --> 00:10:11,970 +الكلام أثناء يعني دراستنا للأمثلة هيظل يتكرر + +117 +00:10:11,970 --> 00:10:16,840 +معناهاممكن يكون ازوالكينز يعني في نيتروجينتين + +118 +00:10:16,840 --> 00:10:22,880 +نيتروزوالكينز أن أسل إمينز هي إمين وهنا في مجموعة + +119 +00:10:22,880 --> 00:10:29,100 +الأسل C double bond and إمين and أسل إمين يعني هذه + +120 +00:10:29,100 --> 00:10:33,200 +الأسل متصلة بالإيش بالنيتروجين كل هذه عبارة عن + +121 +00:10:33,200 --> 00:10:42,030 +أمثلة لPossible Dienes الان لو بدنا نتطلع على + +122 +00:10:42,030 --> 00:10:47,130 +مجموعات من الأمثلة ممكن نتكلم بطريقتين ممكن نقول + +123 +00:10:47,130 --> 00:10:52,150 +احنا انه ال Dienophile يكون فيه هيتيرو أتم و ال + +124 +00:10:52,150 --> 00:10:56,950 +Dien يكون كله Carbons هذا واحد ممكن ال Dienophile + +125 +00:10:56,950 --> 00:11:01,370 +يكون Carbons و ال Dien فيه هيتيرو أتم و in + +126 +00:11:01,370 --> 00:11:05,070 +principle ممكن الطرفين كمان يكون فيهم هيتيرو أتم + +127 +00:11:06,100 --> 00:11:09,920 +الان اتخيل ال hetero atoms ممكن يكون هان هان هان + +128 +00:11:09,920 --> 00:11:12,140 +هان هان هان هان هان هان هان هان هان هان هان هان + +129 +00:11:12,140 --> 00:11:12,140 +هان هان هان هان هان هان هان هان هان هان هان هان + +130 +00:11:12,140 --> 00:11:12,360 +هان هان هان هان هان هان هان هان هان هان هان هان + +131 +00:11:12,360 --> 00:11:13,640 +هان هان هان هان هان هان هان هان هان هان هان هان + +132 +00:11:13,640 --> 00:11:13,800 +هان هان هان هان هان هان هان هان هان هان هان هان + +133 +00:11:13,800 --> 00:11:14,120 +هان هان هان هان هان هان هان هان هان هان هان هان + +134 +00:11:14,120 --> 00:11:14,700 +هان هان هان هان هان هان هان هان هان هان هان هان + +135 +00:11:14,700 --> 00:11:22,120 +هان هان هان هان هان هان هان هان هان + +136 +00:11:22,120 --> 00:11:25,420 +هان هان هان هان هان هان هان هان هان + +137 +00:11:29,200 --> 00:11:33,500 +Carbons لاحظوا لما يجي يتفاعل مع الـ C double bond + +138 +00:11:33,500 --> 00:11:38,100 +O هاي جزء الـ C double bond O لو بدنا نتطلع عليه + +139 +00:11:38,100 --> 00:11:45,060 +هذا الديينوفايل اللي كان أصلا و تم التفاعل معاه + +140 +00:11:45,060 --> 00:11:51,900 +وظال عند إيش؟ رابطة واحدة الآن واضح أن هذا التفاعل + +141 +00:11:51,900 --> 00:11:56,560 +مثلا غالبا بيجي من فئة الإيش ال inverse electron + +142 +00:11:56,560 --> 00:12:06,160 +demandولا normal هذا normal normal اضايين عليه + +143 +00:12:06,160 --> 00:12:09,560 +electron donating groups مثل ومثل اللي هو ال + +144 +00:12:09,560 --> 00:12:13,680 +normal هنا مثلا فنل ممكن تكون electron .. هذا + +145 +00:12:13,680 --> 00:12:19,880 +normal دي ال alder reaction طبعا الفنل CO هي + +146 +00:12:19,880 --> 00:12:25,200 +موجودة وباق التفاعل بنقدر نكمله + +147 +00:12:27,660 --> 00:12:31,640 +أمثلة على هذا النوع الحقيقة موجودة كتير يعني + +148 +00:12:31,640 --> 00:12:36,860 +لاحظوا مصنف هنا الأمثلة بشكل جيد يعني في البداية + +149 +00:12:36,860 --> 00:12:43,800 +كل اللي موجود اتضايين يكون كله carbon و ال hetero + +150 +00:12:43,800 --> 00:12:49,080 +atoms تكون في اتضايينه files وتعطي نتائج ربما + +151 +00:12:49,080 --> 00:12:54,940 +تلاحظوا مثلا لو كان عندي ال C triple bond N ال C + +152 +00:12:54,940 --> 00:12:59,450 +triple bond N شو بتصفه؟C double bond و لذلك هنا + +153 +00:12:59,450 --> 00:13:06,930 +الحلقة صفيت بكم رابطة زوجية رابطتين لاحظوا هذا + +154 +00:13:06,930 --> 00:13:12,730 +النوع من الأمثلة .. هذا النوع من الأمثلة مرات كتير + +155 +00:13:12,730 --> 00:13:20,430 +بيكون هو الأقرب لإنه لو فقد مجمعتين و عمل رابط أن + +156 +00:13:20,430 --> 00:13:25,560 +يصير aromaticولذلك هنا انا بعيد عن ال aromatic ال + +157 +00:13:25,560 --> 00:13:31,760 +aromatic بدها تلت روابط زوجيا عندى واحدة بد تنتين + +158 +00:13:31,760 --> 00:13:36,540 +فانه هذا يتحول ل aromatic صعب الان هذا ماشي تلتين + +159 +00:13:36,540 --> 00:13:41,960 +الطريق هذا المركب ماشي تلتين الطريق ولذلك لاحظوا + +160 +00:13:41,960 --> 00:13:48,940 +انه ممكن يفقد مثلا مجموعة oethyl مع اتش معينةو + +161 +00:13:48,940 --> 00:13:52,740 +يعمل ال aromatic طبعا البعض ممكن يقول هذا اي مين + +162 +00:13:52,740 --> 00:13:56,880 +خلو اينا مين خلو ال double bond هنا و خلو H هنا + +163 +00:13:56,880 --> 00:14:03,710 +هاي H مع Oethel تفقدبصير عندى في نهاية المركب ب + +164 +00:14:03,710 --> 00:14:08,430 +redeem derivative ف لما بكون عندى quintel double + +165 +00:14:08,430 --> 00:14:13,610 +bonds بكون انا اقرب لانه افقد مجموعتين سواء + +166 +00:14:13,610 --> 00:14:16,790 +hydrogen سواء ethanol سواء ammonia حسب طبيعة + +167 +00:14:16,790 --> 00:14:28,270 +المركب و انه يصير عند الناتج اشماله aromatic الان + +168 +00:14:28,270 --> 00:14:34,990 +احيانا التفاعلممكن يكون Intramolecular Deals Elder + +169 +00:14:34,990 --> 00:14:37,670 +Reactions زي ما شوفنا برضه انه كان في ال 1,3 + +170 +00:14:37,670 --> 00:14:42,250 +-dipolar cycloaddition Intramolecular 1,3-dipolar + +171 +00:14:42,250 --> 00:14:46,010 +cycloaddition يعني هنا عندي حلقة ربعية Strained لو + +172 +00:14:46,010 --> 00:14:50,130 +اتخيلت ان هذه الحلقة مع ظروف التفاعل 180 degree + +173 +00:14:50,130 --> 00:14:55,870 +centigrade و 16 ساعة مش ذو ظروفبسيطة فتحت بهذا + +174 +00:14:55,870 --> 00:14:59,430 +الشكل و ال double bond صارت hand بمعنى صار عندي + +175 +00:14:59,430 --> 00:15:02,030 +hand double bond و double bond الانهي هذا الجزء هو + +176 +00:15:02,030 --> 00:15:08,950 +عبارة عن ايش الدين وال C double bond ال dienophile + +177 +00:15:08,950 --> 00:15:14,470 +فلو انا كملت ال deals ألدر reaction هتصير هذه + +178 +00:15:14,470 --> 00:15:19,000 +الحلقة السادسيةهبصي رادس الحلقة السادسة طبعا هيكون + +179 +00:15:19,000 --> 00:15:24,120 +انا عند ايش double bond و اعمل tautomerism in a + +180 +00:15:24,120 --> 00:15:28,700 +mean tautomerism يعني ما .. مانخافش من تحريك ال + +181 +00:15:28,700 --> 00:15:34,420 +double bonds في tautomerisms هنا الان double bond + +182 +00:15:34,420 --> 00:15:40,610 +ان الاتفاعلتكDienophile وبالتالي طلع عندى مركب زى + +183 +00:15:40,610 --> 00:15:46,850 +هذا هنا ال Nitroso الان double bond او اتفاعلت ك + +184 +00:15:46,850 --> 00:15:56,450 +Dienophile عادي الان ممكن نجيب امثلة تانية hetero + +185 +00:15:56,450 --> 00:16:04,600 +Diene و Dienophile Carbons واضحهذا مثلا Alpha Beta + +186 +00:16:04,600 --> 00:16:06,480 +Unsaturated Ketone + +187 +00:16:14,590 --> 00:16:19,230 +الدينوفايل و اكيد بيعمل cycle addition نفس الاشي + +188 +00:16:19,230 --> 00:16:24,070 +هنا alphabet unsaturated امين عند اللزوم مع double + +189 +00:16:24,070 --> 00:16:28,430 +bond مع double bond لاحظوا الأمثلة الحقيقة يعني هي + +190 +00:16:28,430 --> 00:16:34,310 +مجرد انكوا اتطبقوا ال deals elder reaction مافيش + +191 +00:16:34,310 --> 00:16:39,150 +داعي انه الإنسان يقف عند كل مثال فيها يعني هي هذا + +192 +00:16:39,150 --> 00:16:45,020 +المثال هنجيب مجرد هذه هنا و نعمل الحلقةالسوداسية + +193 +00:16:45,020 --> 00:16:50,440 +هنا هاي جزء اضايين c and c double bond c مع هذه + +194 +00:16:50,440 --> 00:16:55,260 +بطلع عندى حلقات هنا نفس الشيء هاي اضايين واحد + +195 +00:16:55,260 --> 00:17:02,100 +اتنين تلاتة اربعة مع double bond برضه هيطلق حلقات + +196 +00:17:02,100 --> 00:17:05,740 +I + +197 +00:17:05,740 --> 00:17:11,690 +don't know اشي هذاعلى اي حال ما عرضناه من الأمثلة + +198 +00:17:11,690 --> 00:17:17,550 +بتهيألي يغني عن اننا نضيع وقت في هذه الان ال deals + +199 +00:17:17,550 --> 00:17:22,730 +and reactions زي ما قلنالكم واسع جدا حتى انتوا + +200 +00:17:22,730 --> 00:17:26,530 +يعني تقتنعوا بالوسع تبعه ايش بدي يكون المطلوب منكم + +201 +00:17:27,560 --> 00:17:32,640 +هو تجيبوا homework مثال على normal Diels-Alder + +202 +00:17:32,640 --> 00:17:38,180 +reaction ومثال على inverse electron demand Diels + +203 +00:17:38,180 --> 00:17:41,860 +-Alder reaction مجرد ما تروحوا على المجلات + +204 +00:17:41,860 --> 00:17:49,060 +هتلاحظوا أنثى جميلة وكتيرة موجودة في المجلات Diels + +205 +00:17:49,060 --> 00:17:54,040 +-Alder cycle addition normal اوهو في العنوان نفسه + +206 +00:17:54,040 --> 00:17:58,200 +حتى مكتوب Inverse Electron Demand Deals Elder + +207 +00:17:58,200 --> 00:17:59,920 +Cycle Addition + +208 +00:18:02,480 --> 00:18:07,840 +من أنواع ال cycle additions الثانية اللى هو ال two + +209 +00:18:07,840 --> 00:18:11,740 +plus two cycle addition من أنواع ال cycle + +210 +00:18:11,740 --> 00:18:14,740 +additions التانية ال two plus two cycle addition + +211 +00:18:14,740 --> 00:18:19,140 +الآن غالبا هذا ال two plus two cycle addition + +212 +00:18:19,140 --> 00:18:27,620 +مشهور اكثر ما يمكن مع اللى هي ال dienes اللى بتكون + +213 +00:18:27,620 --> 00:18:32,800 +بهذا الشكل المتوالية واضحاللي هي ال cumulated + +214 +00:18:32,800 --> 00:18:38,060 +dienes يعني double bond و كمان double bond فمن + +215 +00:18:38,060 --> 00:18:42,360 +أشهر المركبات المشهورة في هذا المجال ال N double + +216 +00:18:42,360 --> 00:18:47,780 +bond C double bond O اللي هي ال isocyanates و ال C + +217 +00:18:47,780 --> 00:18:49,740 +double bond C double bond O + +218 +00:18:52,480 --> 00:18:57,840 +الكيتين الان في ال isocyanates حيصير عندكم مشكلة + +219 +00:18:57,840 --> 00:19:02,100 +انه في تنتين double bonds مع اي واحدة بتفاعل اكثر + +220 +00:19:02,100 --> 00:19:08,120 +غالبا مع ال isocyanates التفاعل مع الان double + +221 +00:19:08,120 --> 00:19:13,980 +bond C هو الأشهر واضح؟يعني التفاعل هيكون على اي + +222 +00:19:13,980 --> 00:19:17,960 +double bond هذه الان لاحظوا مرات فعلها مع ال ال + +223 +00:19:17,960 --> 00:19:22,240 +keen يعني لو بدنا نطلع احنا الجزء اللي عندنا هذا + +224 +00:19:22,240 --> 00:19:30,160 +هو الجزء الأزرق او هنا ال ar هذا هو الجزء الأزرق + +225 +00:19:30,160 --> 00:19:37,920 +هنا هذا الجزء هنا هذا الجزءطبعا يمكن في نقطة ما + +226 +00:19:37,920 --> 00:19:42,940 +نوّحتش إليها أنا في ال deals ألدر reaction إنه + +227 +00:19:42,940 --> 00:19:47,610 +دائما و أبدا عندكم احتمال إيش؟radio isomers يعني + +228 +00:19:47,610 --> 00:19:51,190 +أنه هل يطلع عنده one product و لا يطلع عنده + +229 +00:19:51,190 --> 00:19:56,470 +mixture of products ربما معظم الأمثلة اللي موجودة + +230 +00:19:56,470 --> 00:20:01,170 +بيطلع فيها ناتج واحد لكن مابمنعش أنه ممكن يطلع + +231 +00:20:01,170 --> 00:20:05,870 +mixture of product الآن الإنسان لما بيعمل التفاعل + +232 +00:20:05,870 --> 00:20:12,140 +في النهاية بيكون مش عارف و بده يحط عندهالاحتمالين + +233 +00:20:12,140 --> 00:20:17,140 +بدو يحط عنده الاحتمالين الان نفس الشي عندنا هنا في + +234 +00:20:17,140 --> 00:20:21,240 +ال two plus two cycle addition يعني انا هنا اخدت n + +235 +00:20:21,240 --> 00:20:23,700 +double bond c double bond وعملت عليها cycle + +236 +00:20:23,700 --> 00:20:27,900 +addition هل يا تورا ال R هذه بده تكون على جهة ال n + +237 +00:20:27,900 --> 00:20:33,120 +ولا ممكن نأكسهانرسم النتيجة التانية كذلك الحال هان + +238 +00:20:33,120 --> 00:20:36,840 +واضح هل الان هدى عجلة ال C double bond O ولا الان + +239 +00:20:36,840 --> 00:20:41,320 +ممكن تيجي عجلة الان فمن ناحية نظرية البحثة + +240 +00:20:43,560 --> 00:20:47,440 +1,3-dipolar cycloaddition وكل دي الزقال ده ال + +241 +00:20:47,440 --> 00:20:51,460 +reaction وكل 2 plus 2 cycloaddition reaction الأصل + +242 +00:20:51,460 --> 00:20:56,840 +نظريا أنه متوقع منه كام regioisomers اتنين الأحيان + +243 +00:20:56,840 --> 00:20:59,900 +الناس في الخبرة بيقدروا يقدروا اللي بيشتغلوا في + +244 +00:20:59,900 --> 00:21:05,000 +المجال أي regioisomers أكثر منطقية بالنظر إلى + +245 +00:21:05,000 --> 00:21:09,820 +طبيعة الذرات و مين فيها سالب أكثر و مين فيها موجب + +246 +00:21:09,820 --> 00:21:15,760 +أكثر لكن الحكم النهائي هو إيشهو التجربة الحكم + +247 +00:21:15,760 --> 00:21:26,360 +النهائي بالتأكيد هو التجربة لاحظوا + +248 +00:21:26,360 --> 00:21:32,020 +مثلا في هذا المثل مع ال ISO-thiocyanate مع ال ISO + +249 +00:21:32,020 --> 00:21:35,700 +-thiocyanate التفاعل ما تمش على الأرض بال bond C + +250 +00:21:35,700 --> 00:21:43,520 +تم على ال C double bond Sهي تجرب هذا الجزء هو + +251 +00:21:43,520 --> 00:21:46,820 +الجزء الأزرق اللي اتفاعل وبالتأكيد عندي two + +252 +00:21:46,820 --> 00:21:50,760 +possible regioisomers التفاعل مع ال key teams + +253 +00:21:50,760 --> 00:21:57,020 +غالبا بتتم على ال C double bond C هاي R R C double + +254 +00:21:57,020 --> 00:22:02,440 +bond C وال double bond O بتكون exocyclic يعني + +255 +00:22:02,440 --> 00:22:08,370 +للخارجوحتى لو اتفاعل نفسه مع امين و لا مع الديهيد + +256 +00:22:08,370 --> 00:22:14,370 +او كيتون اللي هي ال كيتين و توابعها الان ممكن + +257 +00:22:14,370 --> 00:22:22,130 +يتفاعل مثل هذا المركب الامين او دايمين مع كيتين مع + +258 +00:22:22,130 --> 00:22:29,240 +كيتين لاحظوا هذه جزء الكيتينهذا جزء الكتين RR CWB + +259 +00:22:29,240 --> 00:22:35,480 +CWB O وهنا في عندي CWB ن وCWB N سيمتريك هذا المركب + +260 +00:22:35,480 --> 00:22:42,780 +بأي طرق فعله أعمل التفاعل على واحدة من هدولة الـ + +261 +00:22:42,780 --> 00:22:50,490 +CWB N وطبعا ممكن معالأزو كومباونز المركبات اللي + +262 +00:22:50,490 --> 00:22:56,150 +فيها نيتروجين يتفاعل مع الكيينز او مع اي نول اي + +263 +00:22:56,150 --> 00:23:01,670 +ثارز يعني الاحتمالات زي ما انتوا شايفين ايش في ال + +264 +00:23:01,670 --> 00:23:09,910 +two plus two احتمالات كتيرة وواسعة وربما أشهرها زي + +265 +00:23:09,910 --> 00:23:14,350 +ما شفنا في اي نوع من ال ال dienes ال formulated + +266 +00:23:14,350 --> 00:23:25,250 +اللي فيهمأكتر من double bond جنب بعض مشهور + +267 +00:23:25,250 --> 00:23:30,470 +في ال two plus two name reaction paterno bouché + +268 +00:23:30,470 --> 00:23:34,610 +reaction هذا ال paterno bouché reaction هو تفاعل + +269 +00:23:34,610 --> 00:23:41,010 +كيتون تفاعل كيتون مع الكيل تفاعل كيتون مع الكيل في + +270 +00:23:41,010 --> 00:23:45,980 +وجود الضوءكما يبدو الناس اللي درسوا التفاعل ان هو + +271 +00:23:45,980 --> 00:23:51,920 +عبارة عن radical reaction بمعنى بتيم على خطوتين + +272 +00:23:51,920 --> 00:23:54,980 +دائما لما نحكي radical reaction بتيم على خطوتين + +273 +00:23:54,980 --> 00:23:59,580 +فلو انا اتخيلت هذه ال phenyl phenyl C double bond + +274 +00:23:59,580 --> 00:24:06,200 +O هذا الجزء الأزرق هو هذا الجزء عمل رابطة مع الجزء + +275 +00:24:06,200 --> 00:24:12,710 +التاني يعني لو اتخيلنا الإلكترونات بهذا الشكلهي + +276 +00:24:12,710 --> 00:24:19,310 +هنعملوا رابطة راديكل و راديكل واضح؟ ضال عندى free + +277 +00:24:19,310 --> 00:24:23,310 +radical و free radical هدول ال free radical بعد + +278 +00:24:23,310 --> 00:24:29,150 +هيك ممكن يسكروا الآن بالتأكيد في عندى حكمال لإيش ل + +279 +00:24:29,150 --> 00:24:33,030 +radio isomers يعني هل يا ترى ال carbon اللى حاملة + +280 +00:24:33,030 --> 00:24:37,450 +تين مثل هتيجى جنب ال carbon اللى حاملة تين funnel + +281 +00:24:37,450 --> 00:24:44,880 +زى ما هو مبين هناهذه الجزء ايه اللى اتفاعله ولا + +282 +00:24:44,880 --> 00:24:48,480 +هذا الجزء اللى بده ينعكس الكاربون اللى حاملة تنتل + +283 +00:24:48,480 --> 00:24:54,720 +مثل بده تيجي بجهه معاكسة لاحظين يعني كأنه انا بعمل + +284 +00:24:54,720 --> 00:24:59,160 +cycle addition هل هذه التراب تتفعل بهذا الشكل ولا + +285 +00:24:59,160 --> 00:25:04,090 +بهذا الشكل واضحة الفكرةفي النهاية اللى بيحكم + +286 +00:25:04,090 --> 00:25:09,190 +الجواب التجربة بس في كل الأحوال طالما بحكي عن two + +287 +00:25:09,190 --> 00:25:14,710 +plus two cycle addition إذا كام ناتج بتوقع ناتجين + +288 +00:25:14,710 --> 00:25:20,930 +و النهاية التجربة هي الحكمة + +289 +00:25:24,180 --> 00:25:27,560 +الاخر شغلة ممكن نحكيها بالـ Cycloadditional + +290 +00:25:27,560 --> 00:25:32,960 +Reactions لـ Chelotropic Reactions وبالتالي احنا + +291 +00:25:32,960 --> 00:25:38,240 +ركزنا عليها لما اتكلمنا على الكربينز والنيترينز + +292 +00:25:38,240 --> 00:25:42,340 +وقلنا لـ Chelotropic Reactions ان اعمل ال 2 new + +293 +00:25:42,340 --> 00:25:48,210 +sigma bonds atone atom واضح و لذلك مثلا هنا لو + +294 +00:25:48,210 --> 00:25:52,430 +بدنا ناخد هذا نيترين بده يتفعل على double bond بده + +295 +00:25:52,430 --> 00:25:56,610 +يعمل عند الحلقة الثلاثية الآن ال two new sigma + +296 +00:25:56,610 --> 00:26:00,670 +bonds صاروا موجودين اين؟ ع ذرة ال نيتروجين او هذا + +297 +00:26:00,670 --> 00:26:04,550 +نيترين على سبيل المثال بده افعله مع ال double bond + +298 +00:26:04,550 --> 00:26:10,690 +ال two new sigma bonds اين موجودين؟ هي sigma bond + +299 +00:26:10,690 --> 00:26:16,250 +و هي sigma bond على نفس ال nitrogen هناوهذا معنى + +300 +00:26:16,250 --> 00:26:21,270 +كلمة ايش Chelotropic reaction سواء قولناها بال او + +301 +00:26:21,270 --> 00:26:30,070 +بال اي يعني ممكن تقرأها Chelo بال او وتشيلي بال اي + +302 +00:26:30,070 --> 00:26:34,570 +القراقتين الموجودين Chelotropic و Chelotropic + +303 +00:26:34,570 --> 00:26:38,590 +reaction فال Cycloadition of Carbines and Nitrines + +304 +00:26:38,590 --> 00:26:44,170 +واخدنا أمثلة كتير عليه هو من أشهر الأمثلة علىالتي + +305 +00:26:44,170 --> 00:26:49,770 +تسمى الـ Chelotropic Reactions أيضًا إضافة الـ + +306 +00:26:49,770 --> 00:26:53,810 +Sulphur Dioxide للـ Conjugated Dienes وكلنا بدنا + +307 +00:26:53,810 --> 00:26:56,990 +نكون متذكرين إن ال Sulphur هنا في عليه أزواج من + +308 +00:26:56,990 --> 00:27:03,090 +الإلكترونات واضح هذا التفاعل هيكون عبارة من ناحية + +309 +00:27:03,090 --> 00:27:08,230 +إلكترونية عن 4 Plusتو اتنين فقط من هدول هيشتركوا + +310 +00:27:08,230 --> 00:27:12,150 +لكن من ناحية ال atoms هو عبارة عن four plus one + +311 +00:27:12,150 --> 00:27:17,990 +بيعطي حلقة خماسية طالما انه الرابطتين اجوا على + +312 +00:27:17,990 --> 00:27:23,870 +السلفر هناإذا هذا التفاعل عبارة عن Chelotropic + +313 +00:27:23,870 --> 00:27:28,990 +reaction لاحظوا إن هذا التفاعل تفاعل عكسي و حقيقة + +314 +00:27:28,990 --> 00:27:33,550 +هم ما بيستفيدوش من التفاعل الطردي لأ بيستفيدوا + +315 +00:27:33,550 --> 00:27:39,150 +أكثر من التفاعل العكسي بمعنى موجود هذا المركب و + +316 +00:27:39,150 --> 00:27:43,430 +هذا المركب بالتسخين أو كذا بيفقد ال SO2 و بيعطي + +317 +00:27:43,430 --> 00:27:50,800 +الضيين فبصير هذا مصدر لتوفير الضيين لمينلمين لازم + +318 +00:27:50,800 --> 00:27:58,860 +نتضيين؟ لتضيين ال reaction لتضيين ال file فانا لما + +319 +00:27:58,860 --> 00:28:04,200 +بد تضيين بجيبه من هذا المركب بالتسخين بيفقد SO2 + +320 +00:28:04,200 --> 00:28:09,360 +طبعا ممتاز انه يفقد SO2 لان SO2 غاز هيطير يعني مش + +321 +00:28:09,360 --> 00:28:13,080 +هيضل في التفاعل فمن ناحية ال processing و العمل + +322 +00:28:13,080 --> 00:28:18,880 +أثناء التفاعل هيكون الأمر اشماله هيكون الأمر سهل + +323 +00:28:19,720 --> 00:28:26,740 +هيكون الأمر سهل تقريبا بهيك بنكون غطينا احنا موضوع + +324 +00:28:28,150 --> 00:28:32,530 +ال cycle addition reactions باللخص اللي أخدنا منه + +325 +00:28:32,530 --> 00:28:35,870 +ال one three bipolar cycle addition و ال deals + +326 +00:28:35,870 --> 00:28:40,250 +alder و ال two plus two و ال Chelotropic بأنواعها + +327 +00:28:40,250 --> 00:28:45,690 +بالتأكيد يعني بأمل أنكوا تجيبولي أقل تقدير مثال + +328 +00:28:45,690 --> 00:28:49,270 +سواء على two plus two cycle addition أو ال + +329 +00:28:49,270 --> 00:28:52,550 +Chelotropic reaction كل ما قرأت أكثر كل ما تعبت + +330 +00:28:52,550 --> 00:28:58,790 +أكثر فتحت المجلات أكثر بتصيروا إيش؟familiar أكتر + +331 +00:28:58,790 --> 00:29:07,330 +بجزء الكيميا طالما + +332 +00:29:07,330 --> 00:29:16,170 +أوصلنا لهيك يمكن كلكم اتذكرين عشان الإنسان يستكمل + +333 +00:29:16,170 --> 00:29:22,550 +موضوع ال synthesis ان احنا قلنا ال synthesis بشكل + +334 +00:29:22,550 --> 00:29:28,360 +عام تلتالطريقة الأولى Cyclization one bond + +335 +00:29:28,360 --> 00:29:32,260 +formation الطريقة الثانية Cycloaddition two bond + +336 +00:29:32,260 --> 00:29:38,000 +formation الطريقة التالتة Ring Transformation حلقة + +337 +00:29:38,000 --> 00:29:45,420 +معينة تفتح وتسكر سواء كبرت او زغرت بنفس الحجم كل + +338 +00:29:45,420 --> 00:29:51,240 +الأمثلة موجودة الآن بشكل عامالنوع الأول الـ + +339 +00:29:51,240 --> 00:29:55,060 +cyclization reaction اللي بيعمله الإنسان و بيخطط + +340 +00:29:55,060 --> 00:29:59,300 +له أنه بيطلع زي هيكالـ Cycloaddition reaction + +341 +00:29:59,300 --> 00:30:04,520 +الإنسان بعمله بجيب القطعتين و جيبول آمل أني أحضر + +342 +00:30:04,520 --> 00:30:08,340 +هذا المركب من الـ Cycloaddition reaction واضح ال + +343 +00:30:08,340 --> 00:30:13,240 +ring transformation تسعين في المية إذا مش أكتر + +344 +00:30:13,240 --> 00:30:18,240 +بتطلع للإنسان صدفة يعني لا هي على البال ولا على + +345 +00:30:18,240 --> 00:30:22,720 +الخاطر بيكون الإنسان قاعد بيشتغل بحلقة معينة + +346 +00:30:22,720 --> 00:30:28,860 +بتفاجأ أنها الحلقة فتحتو سكرت بإيش؟ بشكل جديد + +347 +00:30:28,860 --> 00:30:34,580 +ولذلك مرات بيكون الأمر مفاجئ للإنسان ليش؟ لأنه هو + +348 +00:30:34,580 --> 00:30:39,540 +مابفكرش يعني شخص بيعمل تفاعل بتوقع ناتج قاعد + +349 +00:30:39,540 --> 00:30:43,840 +بيحاول يشوف بال IR بال NMR بال mass بالأجهزة + +350 +00:30:43,840 --> 00:30:48,980 +الطيفية الناتج حسب ما هو بيفكر لكن مابيجيش ع باله + +351 +00:30:48,980 --> 00:30:56,320 +أن التفاعلفاجأه وعمل ring transformation، بالذات + +352 +00:30:56,320 --> 00:31:00,560 +لما مرات أثناء ال ring transformation كمان تفقد + +353 +00:31:00,560 --> 00:31:05,320 +أجزاء، تفقد أجزاء من المواد المتفاعلة، و عشان ذلك + +354 +00:31:05,320 --> 00:31:09,700 +مرات بالعافية الإنسان يعني بدهيعني complete + +355 +00:31:09,700 --> 00:31:15,180 +spectroscopic evidence أو X-ray للمُركّب لما يصير + +356 +00:31:15,180 --> 00:31:19,840 +مقتنع أنه تمت هال ring transformation على أي حال + +357 +00:31:19,840 --> 00:31:25,060 +أنا هأطرح عليكم بعض الأمثلة وأكيد انتوا بإمكانكوا + +358 +00:31:25,060 --> 00:31:29,120 +تجيبوا أمثلة تانية يعني مجرد ما تكتبوا العنوان + +359 +00:31:29,120 --> 00:31:33,380 +ring transformation هتلاحظوا كدهش أنه فيه أمثلة في + +360 +00:31:33,380 --> 00:31:40,950 +الدنيا عليهامعظم الأمثلة اللي بدي أطرح عليكم اليوم + +361 +00:31:40,950 --> 00:31:46,130 +يعني خليني أقول كانت من شغلي و كانت من المصادفات + +362 +00:31:46,130 --> 00:31:52,370 +اللي طلعت عندى أثناء ما كنت يعني بأشتغل ولذلك ربما + +363 +00:31:52,370 --> 00:31:57,010 +كل مثال في ذهن الإنسان إله قصة يعني لاحظوا المدرس + +364 +00:31:57,010 --> 00:32:01,140 +لما بيشرح مثلا دي ال elder reactionهو بيجيب أمثلة + +365 +00:32:01,140 --> 00:32:04,520 +من ال literature لكن أنا عمري ماعملت deals under + +366 +00:32:04,520 --> 00:32:08,280 +reaction بدرسه لكن ماشتغلتش deals under reaction + +367 +00:32:08,280 --> 00:32:12,120 +لكن لما مثلا بدي أجي أحكي one three bipolar cycle + +368 +00:32:12,120 --> 00:32:15,220 +addition reactions لأ اشتغلت كثير أمثلة ring + +369 +00:32:15,220 --> 00:32:18,780 +transformation تقريبا معظم الأمثلة اللي بدنا + +370 +00:32:18,780 --> 00:32:25,780 +نجيبها هي أمثلة يعني عصرناها اشتغلناها طلعت معنى + +371 +00:32:25,780 --> 00:32:32,050 +صدفة ماكناش ايش متوقعينهاالان خلينا نجيب مثال + +372 +00:32:32,050 --> 00:32:37,230 +اشتغلوه غيرنا لكن مثال بسيط وواضح بيوضحلنا الفكرة + +373 +00:32:38,340 --> 00:32:45,640 +هذا المثال عبارة عن تترازولون طبعا تترازول لأنه + +374 +00:32:45,640 --> 00:32:49,700 +حلقة خمسية و لما يكون عليه c double bond o هنقول + +375 +00:32:49,700 --> 00:32:55,500 +عنه إيش ك general name تترازولون الان انتبهوا معي + +376 +00:32:55,500 --> 00:33:00,240 +لما تكونوا بتلقوا محاضرات أو بتلقوا أبحاث تخرج أو + +377 +00:33:00,240 --> 00:33:05,830 +في المستقبل في مؤتمراتعمر الإنسان هو بيشرح ما + +378 +00:33:05,830 --> 00:33:12,310 +بيقعد يسمي المركب تسمية كاملة يضيع وقت الناسواضح؟ + +379 +00:33:12,310 --> 00:33:16,830 +يعني هذا المركب لما انا بدي اسميه تسمية كاملة بدي + +380 +00:33:16,830 --> 00:33:21,170 +اقول one two three four one four dimethyl one four + +381 +00:33:21,170 --> 00:33:26,670 +dihydrotetrasol five all مش ممكن يكون مقبول و + +382 +00:33:26,670 --> 00:33:30,310 +انتوا بتكونوا تفهموا الناس انكوا تقولوا one one + +383 +00:33:30,310 --> 00:33:34,130 +four dimethyl one four dihydrotetrasol five all + +384 +00:33:34,130 --> 00:33:39,470 +react with كذا to produce one two dimethyl هذا + +385 +00:33:39,470 --> 00:33:45,210 +الكلام مش واردإنما تذكر الأسماء أو المركّبات إما + +386 +00:33:45,210 --> 00:33:51,470 +برقم يعني نقول compound 5 produces مثلا compound 6 + +387 +00:33:52,270 --> 00:33:56,950 +أو بالـ General Name تبع العائلة يعني نقول هذا + +388 +00:33:56,950 --> 00:34:02,870 +Tetrazolone خلاص okay بالفوتوليسيز هذا التترازولون + +389 +00:34:02,870 --> 00:34:06,210 +بيفقد نيتروجين يعني انتوا بإمكانكوا لو تخيلتوا ان + +390 +00:34:06,210 --> 00:34:10,890 +هنا الالكترونات هاي هدول الاتنين عملوا صاروا إيش + +391 +00:34:11,900 --> 00:34:14,940 +جزء ال نيتروجين بتلات روابط بيبقى الاكترون و + +392 +00:34:14,940 --> 00:34:20,640 +الاكترون عملوه bond فاعطونا هذه الحلقة الثلاثية + +393 +00:34:20,640 --> 00:34:27,520 +طبعا هذا عبارة عن نوع من ايشالحلقة كانت خماسية + +394 +00:34:27,520 --> 00:34:34,000 +صارت ثلاثية و فوق جزء نيترجين هذا شغل واحد ألماني + +395 +00:34:34,000 --> 00:34:41,100 +اسمه ايش Kvast و مجموعته في الخمس و سبعين لكن + +396 +00:34:41,100 --> 00:34:45,060 +بيوضحلكوا ايش معنى ring contraction يعني تحديدا + +397 +00:34:45,060 --> 00:34:55,000 +الان نيجي لامثلة تانيةهذا المثال أو هذا المُركّب + +398 +00:34:55,000 --> 00:35:00,620 +هذا مُركّب حقيقة لو بتتطلع عليه تم تحضيره من الـ + +399 +00:35:00,620 --> 00:35:03,560 +Cycloaddition لازم يصير عندكوا خبرة لأنه احنا + +400 +00:35:03,560 --> 00:35:06,120 +قولنا الـ 1,3-dipolar cycloaddition من أشهر الـ + +401 +00:35:06,120 --> 00:35:11,480 +Nitrile Oxide وين بتشوفوا C double bond and O + +402 +00:35:11,480 --> 00:35:15,120 +هدولة ارجعوا فيهم انه ممكن يكونوا Nitrile Oxide + +403 +00:35:15,120 --> 00:35:21,790 +okay ضاف على C double bond andو يمكن ناقشنا C + +404 +00:35:21,790 --> 00:35:26,570 +double bond anhydrazone إذا هذه حلقة خماسية نشأت + +405 +00:35:26,570 --> 00:35:30,670 +من ال cycle addition الآن هذه الحلقة الخماسية + +406 +00:35:30,670 --> 00:35:39,960 +بتحمل هنا مجموعة Amino طيب مجموعة ال Aminoكلنا + +407 +00:35:39,960 --> 00:35:45,700 +بنعرف تفاعلاتها يعني لو احنا اجينا قولنا لكم لو + +408 +00:35:45,700 --> 00:35:51,000 +سمحتوا بدنا نفعل مجموعة RNH2 يعني معادلة organic + +409 +00:35:51,000 --> 00:35:56,080 +عامة RNH2 + +410 +00:35:56,080 --> 00:36:00,920 +زائد على سبيل المثال Easter ولا acid chloride + +411 +00:36:02,020 --> 00:36:08,800 +خلّينا نقول acid chloride CH3CW bond OCL هذا very + +412 +00:36:08,800 --> 00:36:13,760 +general reaction معروف بالنسبة لنا ولا لأ ان هذا + +413 +00:36:13,760 --> 00:36:24,680 +ال amino تتفاعل هنا تطرد ال CL و بيصير عند RNH عمد + +414 +00:36:24,680 --> 00:36:29,500 +CW bond O نفترض CH3 + +415 +00:36:30,540 --> 00:36:36,280 +واضح؟ هذا تفاعل طبيعي جدا، الآن نفس التفاعل فكر + +416 +00:36:36,280 --> 00:36:40,720 +الإنسان إنه يعمله مع acid chloride خلّيني أقول هذا + +417 +00:36:40,720 --> 00:36:45,240 +in general XC double bond OCL اللي أنتم بتتوقعوه + +418 +00:36:45,240 --> 00:36:50,740 +طبيعي، إنه هذه بدأ تهاجم هناعندي C double bond O و + +419 +00:36:50,740 --> 00:36:54,380 +C L شو اللي بده يترد؟ ال acid chlorides undergo + +420 +00:36:54,380 --> 00:36:58,400 +substitution reaction حيصير عندي N H C double bond + +421 +00:36:58,400 --> 00:37:03,200 +O X هال X هذي ممكن تكون هيدروجين مثل فينيل CH2CL + +422 +00:37:03,200 --> 00:37:08,140 +كل هذا كأمثلة انعمل + +423 +00:37:08,140 --> 00:37:17,300 +الحقيقة انه اللي بيصيرانه هذا التفاعل نفسه لما عمل + +424 +00:37:17,300 --> 00:37:22,800 +بتسخين من المرة الأولى و بحرارة عالية ماعطش هذا + +425 +00:37:22,800 --> 00:37:26,820 +الناتج يعني هذا الناتج .. هذا الناتج كان + +426 +00:37:26,820 --> 00:37:34,700 +intermediate مر التفاعل فيه و راح عمل شغل إضافية + +427 +00:37:36,080 --> 00:37:39,980 +عمل ring transformation يعني ماوقفش انا الان اي + +428 +00:37:39,980 --> 00:37:43,460 +بني ادم بتوقع انه بده التفاعل عبارة عن + +429 +00:37:43,460 --> 00:37:48,320 +condensation جمع فيه جزيئين و في ال molecular mass + +430 +00:37:48,320 --> 00:37:52,480 +بده يطلع هالجزيئين مجموعات و يشوف عنده C double + +431 +00:37:52,480 --> 00:37:57,400 +bond O و يشوف عنده N H يعني تخيلوا ان حد بيعمل هذا + +432 +00:37:57,400 --> 00:38:03,830 +التفاعل و بده يعمل تحليل صار ولا ما صارلو بدأت بال + +433 +00:38:03,830 --> 00:38:07,230 +IR أسوأ الأجهزة أو أقل الأجهزة فادة بقول اه والله + +434 +00:38:07,230 --> 00:38:12,970 +كان هنا فيه N H 2 هاي ال N H 2 مثلا من منطقة 3300 + +435 +00:38:12,970 --> 00:38:19,070 +سنتمتر minus one ايش صارت صارت N H واحدة وصار عندى + +436 +00:38:19,070 --> 00:38:26,210 +C double bond Oلو بدي أنا ال IR هذا الكلام اللي + +437 +00:38:26,210 --> 00:38:30,990 +بدي أطلعه، الآن بنفس الناتج، ابني اتفاجأ، لا في أن + +438 +00:38:30,990 --> 00:38:38,550 +أتشولا في C double bond O و لو كنا بنتطلع على مثلا + +439 +00:38:38,550 --> 00:38:43,830 +ال NMR افترضه انا عندي مثل و مثل كمان المثل و + +440 +00:38:43,830 --> 00:38:50,210 +المثل طارق فالانسان بيبدأ ايش في هذه الحالات يتغلب + +441 +00:38:50,210 --> 00:38:53,950 +بيبدأ الانسان يتغلب و احيانا مابتصدقوش ان الواحد + +442 +00:38:53,950 --> 00:39:00,920 +اخد شهرين تلاتة هو بيحاول يفهم ايش اللي صار معاهفي + +443 +00:39:00,920 --> 00:39:05,820 +النهاية اللى صار كما يبدو ان هذا الجزء فوقه ككيتون + +444 +00:39:05,820 --> 00:39:10,580 +و هذه ال oxygen سواء بهذا الشكل او تخيلتوا ان + +445 +00:39:10,580 --> 00:39:15,720 +عندكم التوتوميرك form يعني تخيلوها هذي double bond + +446 +00:39:15,720 --> 00:39:22,380 +N و هذي OH عند اللزوم الان هذي اتسكت هنا هذوله + +447 +00:39:22,380 --> 00:39:25,020 +صاروا بمثله الحلقة الجديدة + +448 +00:39:27,860 --> 00:39:42,680 +طلعوا O C N N C واضحة الفكرة O C N N C O C N N C + +449 +00:39:42,680 --> 00:39:48,400 +هذا المركب اللي طلع عندى 134 Oxadiazol + +450 +00:39:51,640 --> 00:39:56,440 +طبعا هل فعلا هذا الجزء فقد على شكل كيتون؟ الإنسان + +451 +00:39:56,440 --> 00:40:00,080 +بعد ذلك بالتجربة بيحاول يفحص هل محلول التفاعل فيه + +452 +00:40:00,080 --> 00:40:05,350 +كيتون ولا لأ؟ يمكن فحص مواجهة كيتونال nitrogen + +453 +00:40:05,350 --> 00:40:09,870 +أكيد فقدت لكن بأي طريقة is not clear مش دايما + +454 +00:40:09,870 --> 00:40:17,050 +الكلام عام طيب هل التفاعل بالتأكيد بالتأكيد مر عبر + +455 +00:40:17,050 --> 00:40:22,050 +هذا المركب الوسيط ولا لأ لاحظوا الإنسان أول ما + +456 +00:40:22,050 --> 00:40:28,270 +بيفعل بحط هذا مع ايش تسخينه حرارة فصل هذا النتج + +457 +00:40:28,270 --> 00:40:32,810 +وما فصلش هذاالان بعد ما يتعب و ياخدله شهر شهرين + +458 +00:40:32,810 --> 00:40:37,570 +تعب و تفكير okay فهم الصورة بيعود يقول طب يا تورا + +459 +00:40:37,570 --> 00:40:44,750 +لو عملت التفاعل بحرارة بسيطة و انتبهت اكثر ممكن + +460 +00:40:44,750 --> 00:40:52,580 +افصل هذا الناتج الوسطاني الحقيقة انه تم فصلفي + +461 +00:40:52,580 --> 00:40:56,220 +الأول واحد بيسخن على طوله ومشي واتفاعل واتكون + +462 +00:40:56,220 --> 00:41:00,300 +واتفاعل على اللي بعده، الآن بدي أهدي ايش؟ ظروف + +463 +00:41:00,300 --> 00:41:04,440 +التفاعل، يمكن أن يفصل هذا، يمكن أن يفصل هذا، طيب، + +464 +00:41:04,440 --> 00:41:09,420 +الآن هذا ممكن لو سخناها مع نفس ظروف التفاعل أو + +465 +00:41:09,420 --> 00:41:12,840 +مثلا الـ Trifluoroacetic Anhydrite كعمل مساعد، + +466 +00:41:12,840 --> 00:41:19,360 +اسكر لهذا، الجواب آهإذا هذا التفاعل تم بالتسخين + +467 +00:41:19,360 --> 00:41:25,820 +المباشر وفصلنا هذا و تم كمان إيش على تدرج بحيث + +468 +00:41:25,820 --> 00:41:30,540 +أننا نفصل ال intermediate و نتأكد منها و نشخصها و + +469 +00:41:30,540 --> 00:41:34,680 +نشوف فعلا زي ما قلنا في ال IR و في ال NMR ال N H و + +470 +00:41:34,680 --> 00:41:38,400 +ال C double bond O هدول مازالوا موجودين فجأة كل + +471 +00:41:38,400 --> 00:41:44,390 +إشي تغير و هدولة طلعواو بس بنحصل على مُركّب يعني + +472 +00:41:44,390 --> 00:41:48,590 +لو افترضتوا هذه كانت مثلا Methyl يعني كنا مستعملين + +473 +00:41:48,590 --> 00:41:52,070 +Acetylchloride فقط هتشوفوا هنا ال Methyl و + +474 +00:41:52,070 --> 00:41:55,590 +البنزينة طب و الأشياء اللي كانت هنا كلها و الأنا + +475 +00:41:55,590 --> 00:42:04,050 +كله إيش ماله؟ اختفى هذاRing Transformation اتحول + +476 +00:42:04,050 --> 00:42:10,410 +في الـ 1,2,4 اكزا دايازول لـ 1,3,4 اكزا دايازول + +477 +00:42:10,410 --> 00:42:14,750 +يعني هذه حلقة خمسية صارت حلقة خمسية بس بالتأكيد + +478 +00:42:14,750 --> 00:42:20,220 +هذه بوادو هديكي بوات تاني يمكن البعض يقول طب ليش + +479 +00:42:20,220 --> 00:42:25,300 +بيصير هيك ring transformation دائما اي شخص بده + +480 +00:42:25,300 --> 00:42:30,860 +يحسن ظروفه بيحسن للأفضل ولا للأسوأ للأفضل انتبهوا + +481 +00:42:30,860 --> 00:42:38,880 +ان هذا is non aromatic هذا aromatic فربما تكون ال + +482 +00:42:38,880 --> 00:42:42,280 +aromaticity هي الدافع انه يصير هذا ال ring + +483 +00:42:42,280 --> 00:42:46,350 +transformationواضح ال stability المرتبطة بال + +484 +00:42:46,350 --> 00:42:50,890 +conjugation اللي هي ال delocalization ال energy و + +485 +00:42:50,890 --> 00:42:54,910 +ال كذا ربما ان هي تكون الدافعة لحظة هذه يعني + +486 +00:42:54,910 --> 00:42:59,430 +بعتبرها ring transformation محظوظة ليش؟ لأن انا + +487 +00:42:59,430 --> 00:43:03,050 +كمان فصلت ال intermediate يعني احيانا صعب ان + +488 +00:43:03,050 --> 00:43:06,830 +الانسان يكون حاطط product و يقول بتوقع انه مر + +489 +00:43:06,830 --> 00:43:10,810 +عبرها ال intermediate لكن اقوى دليل اذا الانسان + +490 +00:43:10,810 --> 00:43:15,600 +ايش ماله؟فصل ال intermediate وشخصه وعوض حطه بظروف + +491 +00:43:15,600 --> 00:43:23,040 +التفاعل وخلى يكمل التفاعل وهذا تقريبا اللي صار + +492 +00:43:23,040 --> 00:43:29,320 +بهذا المثال الآن + +493 +00:43:29,320 --> 00:43:34,620 +أحيانا الإنسان لما بيعمل ring transformation معين + +494 +00:43:34,620 --> 00:43:41,570 +و بفهمه جيدا بيصير بإمكانهعمّمها واضح الفكرة يعني + +495 +00:43:41,570 --> 00:43:47,050 +خليني اجعل هذا ال ring transformation حقيقة اول ما + +496 +00:43:47,050 --> 00:43:52,210 +عملت كنا انسخن مع CH2Cl يعني كان المركب اللي احنا + +497 +00:43:52,210 --> 00:43:57,970 +بنفاعل معه هو C double bond OCl وهنا ايش اللي + +498 +00:43:57,970 --> 00:44:01,930 +موجود CH2Cl + +499 +00:44:01,930 --> 00:44:06,330 +طبعا التفاعل هيكون من هذه القمعين وهنا وبالتالي ال + +500 +00:44:06,330 --> 00:44:13,380 +X ايش كانتCH2CN هذا أول معويل التفاعل الآن بيصير + +501 +00:44:13,380 --> 00:44:16,260 +الواحد يسأل نفسه السؤال شوف كيف ال project بيبدأ + +502 +00:44:16,260 --> 00:44:21,140 +يكبر مع البني آدم طب يا تورا لو غيرت هذه الحمرة ب + +503 +00:44:21,140 --> 00:44:26,860 +مثل بفنل ب H برضه بيصير ring transformation ولا لأ + +504 +00:44:26,860 --> 00:44:35,710 +بيصير جرد في كل الأحوال صحواضح يعني بيبدأ بمثال + +505 +00:44:35,710 --> 00:44:42,630 +لكن بإمكانه هنا يصير يعمل تغيير معين وبالتالي بدل + +506 +00:44:42,630 --> 00:44:49,450 +ما كانت هذه بس CH2CL اقدرنا نحطGeneral formula X + +507 +00:44:49,450 --> 00:44:55,290 +قدنا نحقنه كتب إيش؟ X الآن في كل الأحوال عند أنا + +508 +00:44:55,290 --> 00:45:00,190 +ربما أهم شغل بهذه المنطقة إيش؟ الـ C double bond O + +509 +00:45:00,190 --> 00:45:05,270 +شوف كيف الواحد ممكن يطور الأفكار طب خليني أجيب C + +510 +00:45:05,270 --> 00:45:10,940 +double bond O خارج نطاقخارج نطاق ال .. ال acid + +511 +00:45:10,940 --> 00:45:15,440 +chlorides اللي طلعت هذه المراكبات إيش فيه مراكبات + +512 +00:45:15,440 --> 00:45:22,780 +فيها C double bond O ال isocyanates ال isocyanates + +513 +00:45:22,780 --> 00:45:31,640 +مش phenyl N C double bond هي phenyl N double bond + +514 +00:45:31,640 --> 00:45:39,240 +C double bond O و ال isocyanate phenylان دابل بوند + +515 +00:45:39,240 --> 00:45:45,160 +سي دابل بوند اس الان لو بده تيجي ال amino تهاجم + +516 +00:45:45,160 --> 00:45:51,660 +وين هتهاجم ال amino على هذه ال carbon هذه هتلف هنا + +517 +00:45:51,660 --> 00:45:58,160 +تعطيني ان اتش فحسين عندي ان اتش من هنا سي دابل + +518 +00:45:58,160 --> 00:46:07,170 +بوند او اوS و بعدين هذا بتصفى unatched final هل + +519 +00:46:07,170 --> 00:46:11,530 +بيمكن اعمل التفاعل بهدوء و افصل هدول المركبين okay + +520 +00:46:11,530 --> 00:46:16,910 +ممكن طيب لو حطينا لهم catalyst هل هدول التانين + +521 +00:46:16,910 --> 00:46:22,630 +هيسكروا هنا بنفس الطريقة كل هذا الجزء زي ما اتفقنا + +522 +00:46:22,630 --> 00:46:29,470 +و يصير عندي OCNNC بس هنا إيش أصبحت حاملة unatched + +523 +00:46:29,470 --> 00:46:34,510 +finalمازال 134 اكزا بيازول طب لو استعملتي ال + +524 +00:46:34,510 --> 00:46:38,290 +sulfur وجدت ايش هيصير هنا + +525 +00:46:46,530 --> 00:46:52,490 +الحقيقة انه فعلا ممكن تم و فعلا فصلت هذه المراكبات + +526 +00:46:52,490 --> 00:46:57,350 +و هدولة يعني ال touring transformation كانوا + +527 +00:46:57,350 --> 00:47:00,990 +نشرتين في مجلة ال heterocycles اليابانية و ال + +528 +00:47:00,990 --> 00:47:06,290 +journal heterocycle chemistry الأمريكية في أوائل + +529 +00:47:06,290 --> 00:47:13,900 +التسعيناتيعني قبل ما يقارب ال 15-16 سنة فهدول + +530 +00:47:13,900 --> 00:47:20,240 +أمثلة على إيش؟ ring transformations خلينا ناخد + +531 +00:47:20,240 --> 00:47:25,260 +مثال تاني على ال ring transformations هذا المثال + +532 +00:47:25,260 --> 00:47:30,080 +هذا precursor of nitrile oxide اللي اتكلمنا عنه + +533 +00:47:30,080 --> 00:47:35,040 +اللي هو chloroximeمصيروا ايش هيعطيه؟ نيترال اكسيد + +534 +00:47:35,040 --> 00:47:40,220 +الان الـ nitral oxide ممكن من ناحية المبدأ زي ما + +535 +00:47:40,220 --> 00:47:45,380 +حكينا تتفاعل على ال double bond وتعمل cycle + +536 +00:47:45,380 --> 00:47:49,360 +addition يعني لو احنا قولنالكوا اكمل المعادلة + +537 +00:47:49,360 --> 00:47:55,140 +نيترال اكسيد هذا مع ال double bond اكتر شيء ممكن + +538 +00:47:55,140 --> 00:48:00,710 +تفكروا فيه انكوا تعملوا ايش؟cycloaddition على الـ + +539 +00:48:00,710 --> 00:48:09,190 +double bond وقيتها هتكتبوا الناتج R N R عفواً + +540 +00:48:09,190 --> 00:48:15,590 +C double bond N O وهنا تحطوا C N هذي اللي هي هذي + +541 +00:48:15,590 --> 00:48:24,450 +الـ C N حملة R إبرايم وR double إبرايم وهنا NH CH3 + +542 +00:48:24,450 --> 00:48:28,930 +هذا ال product Cycloadditionهذه نيترال أكسيد وهذه + +543 +00:48:28,930 --> 00:48:32,710 +الـ double bond هذا الـ 1,3-dipolar cycloaddition + +544 +00:48:32,710 --> 00:48:37,210 +product ويمكن تلاحظوا أن هذا الـ 1,3-dipolar + +545 +00:48:37,210 --> 00:48:40,250 +cycloaddition product هو الناتج اللي اتكون في + +546 +00:48:40,250 --> 00:48:45,170 +الأمثلة اللي قبل شوية بس بشرط لما كانت هذه un-H وH + +547 +00:48:45,170 --> 00:48:50,630 +un-H2 انه انا كان ايش معلج عندكم un-H2 ارجعوا + +548 +00:48:50,630 --> 00:48:54,870 +للمثال اللي بدأنا فيه هذه أصلها شو كان + +549 +00:48:58,880 --> 00:49:05,820 +هيدرازون رار سي دابل بوند ام ام اتش ميثل رار سي + +550 +00:49:05,820 --> 00:49:08,340 +دابل بوند ام ام اتش ميثل + +551 +00:49:16,290 --> 00:49:20,050 +cycloaddition product لكن الكيميا زي ما قلنا بدن + +552 +00:49:20,050 --> 00:49:24,530 +المرة ألف علم إيش ماله تجريبة ما تمش cycloaddition + +553 +00:49:24,530 --> 00:49:29,790 +product لما فقد ال HCl مع ال triethylamine إجت هذه + +554 +00:49:29,790 --> 00:49:32,350 +اتفاعل تهان على الكاربون هذا في نهاية ال + +555 +00:49:32,350 --> 00:49:36,510 +nucleophile الكاربون إلكتروفايل وهذه ال O سكرت هنا + +556 +00:49:36,510 --> 00:49:41,510 +وهذه صارتان اتش اعطتني شيء بسميه Cyclo + +557 +00:49:41,510 --> 00:49:44,850 +-condensation يعني اتنين تفاعل نيوكليوفايل + +558 +00:49:44,850 --> 00:49:49,230 +إلكتروفايل هذا نيوكليوفايل هذا إلكتروفايل هذا + +559 +00:49:49,230 --> 00:49:54,850 +نيوكليوفايل هذا إلكتروفايل سي ان هيموجب هيسلب هذه + +560 +00:49:54,850 --> 00:49:58,790 +الان نيوكليوفايل هذه الكربل في الولفري دايبول + +561 +00:49:58,790 --> 00:50:03,730 +إلكتروفايل فهذا التفاعل بنسميه Cyclo-condensation + +562 +00:50:03,730 --> 00:50:09,060 +أعطى حلقة سدسية مش Cyclo additionما تمشي التفاعل + +563 +00:50:09,060 --> 00:50:12,580 +مع الـ Methylhydrazone بالـ Cycloaddition reaction + +564 +00:50:12,580 --> 00:50:16,300 +فهذا كان آخر شيء شرحته لكم المرة الماضية في الـ + +565 +00:50:16,300 --> 00:50:22,160 +Cycloaddition الان لاحظوا هذا المثال أعطاني حلقة + +566 +00:50:22,160 --> 00:50:28,780 +سداسية فيها Oxygen وكام نيتروجينة Oxytriazine + +567 +00:50:30,480 --> 00:50:35,560 +In general أجزة ريازين، الآن انتبهوا معي، في ناس + +568 +00:50:35,560 --> 00:50:40,140 +قبل هيك عملوا هذا التفاعل بشروط تفاعل مختلف وما + +569 +00:50:40,140 --> 00:50:44,660 +طلعش معاهم أجزة ريازين عشان هيك تصيروا تنتبهوا + +570 +00:50:44,660 --> 00:50:51,410 +أكثر أن التفاعل مش بس المواد المتفاعلةالتفاعل هو + +571 +00:50:51,410 --> 00:50:56,810 +المواد المتفاعلة وشروط التفاعل تماما زي ما نيجي + +572 +00:50:56,810 --> 00:51:01,950 +نقول أن التربية مش بس اللي بنعلمه لإبننا في الدار + +573 +00:51:01,950 --> 00:51:05,930 +اللي بنعلمه لإبننا في الدار و البيئة المحيطة ولدت + +574 +00:51:05,930 --> 00:51:10,430 +رب في منطقة كلها يعني عفوا شوارع و إشي مش زي ما + +575 +00:51:10,430 --> 00:51:13,870 +ولدت رب مثلا في منطقة كلها أخلاج و أدب و ناس + +576 +00:51:13,870 --> 00:51:17,750 +محترمين واضح؟ يعني هاي أنا بدي أخد ال hydrazinol + +577 +00:51:17,750 --> 00:51:23,770 +chloride مع هذاو اغير بس هذه الشروط و في فعل الناس + +578 +00:51:23,770 --> 00:51:28,050 +غيروا هذه الشروط بدل ما يستعملوا ال triethylamine + +579 +00:51:28,050 --> 00:51:33,830 +و ال chloroform استعملوا ether مع reflex تمام + +580 +00:51:33,830 --> 00:51:39,530 +استعملوا ether مع reflex ماطلعش معهم هذا الناتج + +581 +00:51:39,530 --> 00:51:46,440 +طلع معهم ناتج غريب جداone two four triazole one + +582 +00:51:46,440 --> 00:51:50,400 +two three four one two four triazole لما بدهم + +583 +00:51:50,400 --> 00:51:54,480 +يفسروا بيقولوا okay خلّينا نتخيل أنه هذه + +584 +00:51:54,480 --> 00:51:58,540 +enucleophile على عين وراسه هاجمت على ال + +585 +00:51:58,540 --> 00:52:02,420 +electrophile اللي هان بعد فقد هذا الان احنا قبل + +586 +00:52:02,420 --> 00:52:07,540 +شوية كملنا أن هذا enucleophile بيهاجمها طب ما ال + +587 +00:52:07,540 --> 00:52:10,060 +nitrogen كمان عليها زوج إلكترونات + +588 +00:52:12,640 --> 00:52:16,180 +الملاحظين انتوا كيف المنطق يعني إذا جميلنا بالخطوة + +589 +00:52:16,180 --> 00:52:22,140 +الأولى خلاص ماشيناها شبكنا هذا من هذا الآن هي ال + +590 +00:52:22,140 --> 00:52:29,680 +nucleophile و هي ال nucleophile الهجوم من هذه ال + +591 +00:52:29,680 --> 00:52:33,520 +oxygen أعطى أي ناتج الحلقة السوداسية الحلقة + +592 +00:52:33,520 --> 00:52:37,640 +السوداسية طيب يا تورا لو تم الهجوم من ال nitrogen + +593 +00:52:37,640 --> 00:52:44,500 +بيعطي الخمسية و بيصير عنده OH OH جنب بعضبفقد ايش؟ + +594 +00:52:44,500 --> 00:52:49,900 +بفقد التريازول، بفقد ميا بصير التريازول، one two + +595 +00:52:49,900 --> 00:52:55,660 +four التريازول، واضح؟الان كما يبدو ان هذا التفاعل + +596 +00:52:55,660 --> 00:52:59,620 +لما تم بال ether و ال reflex نشره ناس ريزيتانو + +597 +00:52:59,620 --> 00:53:04,320 +مجموعة معينة اعطى الحلقة الخمسية لما ناس عملوه على + +598 +00:53:04,320 --> 00:53:08,160 +البارد بترايث الأمين و كلوروفورم اعطى الحلقة + +599 +00:53:08,160 --> 00:53:12,820 +السادسية عشان مقدش تغيير ال condition قد اله تغير + +600 +00:53:12,820 --> 00:53:17,480 +في النتاج لحتى الان احنا جيبنا سيرة ال ring + +601 +00:53:17,480 --> 00:53:23,260 +transformationلأ جيبنا أن هذا التفاعل في ظرفين + +602 +00:53:23,260 --> 00:53:28,480 +مختلفين أعطى نواتج مختلفة وقدرنا نفهمه منطقيا يعني + +603 +00:53:28,480 --> 00:53:32,060 +أنه بدأ باليوكليوفيليك addition وبعدين بده يسكر أي + +604 +00:53:32,060 --> 00:53:38,200 +من ال two يوكليوفايلز بده يهاجم بيصير الآن بعد هيك + +605 +00:53:38,200 --> 00:53:43,440 +كانت المفاجأة أن نفس هذا السداسي ممكن يعمل ring + +606 +00:53:43,440 --> 00:53:49,630 +transformation ويصير خماسييفتح و يقعد يسكر من أول + +607 +00:53:49,630 --> 00:53:54,690 +و جديد على الخماس يعني بعد ما اتكون كان مجرد تسخين + +608 +00:53:54,690 --> 00:53:59,950 +لهذا مع ال acetic acid و حتى يعني انا مازلت بتقول + +609 +00:53:59,950 --> 00:54:02,870 +انه لأ سخناه كمان لحاله يعني حاطناه في ال test + +610 +00:54:02,870 --> 00:54:07,450 +tube ك solid و سخناه على النار حاسينه ميه بتطلع + +611 +00:54:07,450 --> 00:54:13,590 +منه شوفنا بخار و تكسر و سكر من أول و جديد الان كل + +612 +00:54:13,590 --> 00:54:19,510 +الفكرة انه فتح من هناهذه صارت OH هجت ال H هنا وهذه + +613 +00:54:19,510 --> 00:54:26,390 +صارت double bond N ال N بعد هيك رد سكر منها واضحة + +614 +00:54:26,390 --> 00:54:30,810 +الفكرة يعني كأنه كان مسكر هيك بحلقة سداسية كبيرة + +615 +00:54:30,810 --> 00:54:37,830 +فتح و سكر على أصغر منها سكر على حلقة خمسية و أعطى + +616 +00:54:37,830 --> 00:54:42,930 +لل triazole اللي حصل عليه الجماعة التانيةواضح؟ هذه + +617 +00:54:42,930 --> 00:54:46,490 +هي ببساطة ring transformation احنا ايش قولنا ring + +618 +00:54:46,490 --> 00:54:51,250 +transformation ببساطة؟ ring opening و new ring + +619 +00:54:51,250 --> 00:54:55,630 +cyclization انه صار عنده ring opening و بعد ما + +620 +00:54:55,630 --> 00:55:01,130 +فتحت الحلقة كانت زي هيك سكرت من جهة تانية طبعا هذا + +621 +00:55:01,130 --> 00:55:04,670 +نوع من ال ring contraction + +622 +00:55:06,200 --> 00:55:13,040 +ستة صارت خمسة this is a ring contraction ring + +623 +00:55:13,040 --> 00:55:17,280 +transformation او reaction واضحة هذه الفكرة + +624 +00:55:17,280 --> 00:55:23,040 +ولاحظوا + +625 +00:55:23,040 --> 00:55:27,640 +مرة تانية ربما يعني للي بيفكر انه ايش اللي بيخلي + +626 +00:55:27,640 --> 00:55:33,580 +التفاعل يمشي زي هيك ان هذا aromatic stability + +627 +00:55:35,600 --> 00:55:40,780 +ان هو ايه ايه ايه ايه ايه + +628 +00:55:40,780 --> 00:55:43,180 +ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه + +629 +00:55:43,180 --> 00:55:53,600 +ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه + +630 +00:56:05,790 --> 00:56:09,770 +فكروا بالـ Neutral Amine يعني لو أنا كنت بدأ أفكر + +631 +00:56:09,770 --> 00:56:17,430 +بهذا بفكر بـ C double bond N وحطه هنا Ar وحطه هنا + +632 +00:56:17,430 --> 00:56:21,790 +Acetyl هذا Neutral Amine لما يفقد الـ HCl بده يكون + +633 +00:56:21,790 --> 00:56:31,550 +زي هيك طب و هذه الـ R RCl هذه الحقيقة أصلها C + +634 +00:56:31,550 --> 00:56:41,270 +double bond NO H اكزيب C double bond N O H الان + +635 +00:56:41,270 --> 00:56:44,910 +لما افعل هذا مع اكزيب شو اللي بتوقع انا ك cycle + +636 +00:56:44,910 --> 00:56:51,610 +addition انه من هنا ال double bond تروح و من هنا + +637 +00:56:51,610 --> 00:56:55,950 +تروح طبعا الزوج الالكتروني تحيجها two new sigma + +638 +00:56:55,950 --> 00:57:04,300 +bonds و هيكون هنا ايش عندكم O Hالاصل انه ايش اللي + +639 +00:57:04,300 --> 00:57:10,800 +معلق على الان OH هذا ال Cycloaddition بطريقة ما + +640 +00:57:10,800 --> 00:57:16,820 +مازالت لحد الآن مش معروفة بيع ال oxygen وصار un + +641 +00:57:16,820 --> 00:57:20,760 +-etch يعني لو انتوا بتكملوا المعادلة منطقيا + +642 +00:57:20,760 --> 00:57:26,580 +Cycloaddition of oxime مع نيترال امين الاصل ايش + +643 +00:57:26,580 --> 00:57:33,720 +يعطيكم؟ان حاملة O H الان اذا قدرت قادر اعطاه ان + +644 +00:57:33,720 --> 00:57:38,820 +اتش مع العلم التفاعل الموازي للنيترال اكسيد مع + +645 +00:57:38,820 --> 00:57:43,160 +اكزيمي مسجل انه بيعطي O H موجود ناس معينين عاملينه + +646 +00:57:43,160 --> 00:57:50,700 +لكن هذا اعطاهان اتش ان اتش الان هذا الحقيقة شغل + +647 +00:57:50,700 --> 00:57:55,480 +cycle addition احنا اشتغلناه وعندنا يعني evidence + +648 +00:57:55,480 --> 00:58:00,120 +100% يعني نقدر نقول له ان هو فعلا فقد ال oxygen + +649 +00:58:00,120 --> 00:58:04,600 +عاملينه nitrogen 15 NMR كل أنواع التحاليل اعملنا + +650 +00:58:04,600 --> 00:58:09,700 +اكثر من نشرة منه في مجلات محترمة فعلا هو زي هيك + +651 +00:58:09,700 --> 00:58:13,460 +الان اهم شيء لاحظوا ان هذا aromatic ولا non + +652 +00:58:13,460 --> 00:58:19,710 +aromaticنون اروماتيك طب في ان اتش لو قلنالكوا اكمل + +653 +00:58:19,710 --> 00:58:26,250 +المعادلة مع acidic anhydride substitution بده يحط + +654 +00:58:26,250 --> 00:58:29,670 +acetyl يعني هاد الان بده تحط ال C double bond O + +655 +00:58:29,670 --> 00:58:35,390 +CH3 لمن ال acetyl مجرد الحط المركب سخنه مع acidic + +656 +00:58:35,390 --> 00:58:40,530 +anhydride الاصل انه يطلع عندنا هذا الناتجالكلام + +657 +00:58:40,530 --> 00:58:45,750 +منطقي ولا لأ؟ الان بقدرة جادر لاحظنا انه فقدت جزء + +658 +00:58:45,750 --> 00:58:51,650 +كبير من الجزء فقدت هذه الأشياء كلها و بيطلع عندنا + +659 +00:58:51,650 --> 00:58:57,990 +one two four اتريازول مختلف و aromatic لاحظوا هذا + +660 +00:58:57,990 --> 00:59:05,530 +aromatic هذا ماكنش aromatic و فقدت ال R و ال R و + +661 +00:59:05,530 --> 00:59:12,690 +ال ..هدولة بالذات بشكل أساسي طيب إيش اللي صار + +662 +00:59:12,690 --> 00:59:16,490 +بيحاول الإنسان تحط تفسير كيف صارت ال ring + +663 +00:59:16,490 --> 00:59:21,150 +transformation خلنا نقول إن اتخيلنا إن هذه السيطة + +664 +00:59:21,150 --> 00:59:25,610 +بال bond O ممكن تيجي على ال R وال R اللي هنا تهاجم + +665 +00:59:25,610 --> 00:59:31,310 +تعمل نوعا ما ما يشبه الحلقة الرباعية وبعد هيك من + +666 +00:59:31,310 --> 00:59:37,310 +هنا يفقد هذا ال RRC مع ال O على شكل كيتونو تيجي ال + +667 +00:59:37,310 --> 00:59:40,230 +nitrogen اللى هنا تسكر على ال carbon اللى هنا + +668 +00:59:40,230 --> 00:59:43,450 +هيطلع + +669 +00:59:43,450 --> 00:59:47,930 +عندى هذا المركب ال aromatic اللى فقد بشكل أساسى + +670 +00:59:47,930 --> 00:59:54,470 +هدول شغلتين و هذا ال oxygen الان من ناحية تشخيص + +671 +00:59:54,470 --> 00:59:58,790 +تشخيص سليم 100% مافي مشكلة من ناحية التفسير + +672 +00:59:58,790 --> 01:00:04,160 +التفسير ماحدش بتدعى انه تفسيرهسليم لإيش لأن أنا + +673 +01:00:04,160 --> 01:00:07,880 +أنا بحط intermediates يعني اشي انا مش شايفه يعني + +674 +01:00:07,880 --> 01:00:14,820 +المركبات المركبات okay الإنسان بيقدر يشوفها يعني + +675 +01:00:14,820 --> 01:00:19,380 +هذا شفناهالان هذا ماشوفناهش و هذا ماشوفناهش و هذا + +676 +01:00:19,380 --> 01:00:23,420 +ماشوفناهش لكن بحاول الإنسان يتخيل أنه كيف على أقل + +677 +01:00:23,420 --> 01:00:27,620 +تقدير تم هذا الكلام في كل الأحوال هذا عبارة عن + +678 +01:00:27,620 --> 01:00:33,820 +ring transformation حلقة خماسية بترتيب معين صارت + +679 +01:00:33,820 --> 01:00:39,580 +حلقة خماسية تانية هذه non aromatic هذه aromatic + +680 +01:00:39,580 --> 01:00:47,430 +فقدت جزيئات معينة فقدت ال RCR فقدت أشياء كتيرةهذه + +681 +01:00:47,430 --> 01:00:51,870 +ring transformation الان اتخيلوا ان انسان طلب منه + +682 +01:00:51,870 --> 01:00:56,870 +انه بس يعمل acetylation لهذه هل بدون ما يفصل ناتج + +683 +01:00:56,870 --> 01:01:00,690 +عمره كان بتوقع انه بيصير هيك شغلات عشان هيك انا + +684 +01:01:00,690 --> 01:01:04,570 +بقول ان ال ring transformation مفاجئة بتطلع + +685 +01:01:04,570 --> 01:01:12,530 +للانسان و بتعب لما يصل لتشخيص المركب و احيانا بتعب + +686 +01:01:12,530 --> 01:01:18,210 +انه يحط ايشتفسير كيف تم التفاعل بتعب أني أحط تفسير + +687 +01:01:18,210 --> 01:01:24,790 +أيضا كيف تم التفاعل ناخد + +688 +01:01:24,790 --> 01:01:31,310 +كمان ring transformations تانية نفس هذا المركب + +689 +01:01:31,310 --> 01:01:36,370 +اللي بدأنا فيه طوى لاحظوا إيش كنا كاتبين الكهانة + +690 +01:01:36,370 --> 01:01:40,670 +أسيتل طب لو إجينا فرغنا الأسيتل الأسيتل عبارة عن + +691 +01:01:40,670 --> 01:01:47,940 +إيش؟C double bond O CH3 من حقنا نفكر أنه بدنا نعمل + +692 +01:01:47,940 --> 01:01:53,640 +عليها أجزيم إنسان فاعل هذا مع هيدروكس الأمين الـC + +693 +01:01:53,640 --> 01:01:58,420 +double bond O بدأ تصير C double bond N OH ويفصل + +694 +01:01:58,420 --> 01:02:04,260 +أجزيمعمركوا عملتم أكزيم في المختبر أكيد في مختبر + +695 +01:02:04,260 --> 01:02:08,760 +organic عام بيعملوا هيدرازون و أكزيم كيتون او + +696 +01:02:08,760 --> 01:02:13,740 +الديهيد هذا كيتون زاد هيدروكس الأمين بالتسخين شوية + +697 +01:02:13,740 --> 01:02:21,200 +بيعطيني أكزيم الأن هذا التفاعل كيتون مع هيدروكس + +698 +01:02:21,200 --> 01:02:25,840 +الأمين الحقيقة بالتسخين أعطاش الأكزيم أعطى مركب + +699 +01:02:25,840 --> 01:02:33,920 +تانيو حلقة سدسيا جلب المركب بشكل غريب جدا، اللي + +700 +01:02:33,920 --> 01:02:40,520 +انا اتخيله انه انسان بنتظر الأجزيم و بفكر حاله طلع + +701 +01:02:40,520 --> 01:02:46,770 +الأجزيم و هو نطلع مركب تانيواضح؟ جديش بدى تاخد منه + +702 +01:02:46,770 --> 01:02:51,910 +وقت لما يكتشف انه لأ التفاعل ضحك عليه و طلعله مركب + +703 +01:02:51,910 --> 01:02:56,090 +ثاني انا بقى اذكر ان هذا الكلام يمكن أخدله ما + +704 +01:02:56,090 --> 01:03:01,760 +يقارب الخمس، ست أشهرمن الدكتور نبيل الحلبى لما كان + +705 +01:03:01,760 --> 01:03:05,660 +بيعمل الدكتوراه تبعته يعني هذا جزء من الدكتوراه + +706 +01:03:05,660 --> 01:03:09,800 +تبعته في النهاية انتبهوا معاه لما اكتشفنا ان هذا + +707 +01:03:09,800 --> 01:03:12,680 +التفاعل فعلا عملها ال ring transformation اللي + +708 +01:03:12,680 --> 01:03:18,800 +هنشرحها قولنا طب خلينا نشتغل الأجزيم بهدوء على نار + +709 +01:03:18,800 --> 01:03:26,360 +هادية بإمكاننا نفصله في الأولادة ما كان مفصولبهدوء + +710 +01:03:26,360 --> 01:03:29,980 +وبشروط خليه يتحرك لحاله طالت اربع أيام على البارد + +711 +01:03:29,980 --> 01:03:36,380 +بلاش بنص ساعة على السخن انفصل الأجزيم انحلت ايش نص + +712 +01:03:36,380 --> 01:03:40,380 +المشكلة طيب يا ترى هل الأجزيم هذا لو بقعد يكسخ + +713 +01:03:40,380 --> 01:03:44,420 +خناه مرة تانية مع نفسه المحلول بيعمل ring + +714 +01:03:44,420 --> 01:03:48,240 +transformation اه اذا هذا التفاعل من التفاعلات + +715 +01:03:48,240 --> 01:03:53,360 +اللي بتسخيل كتير مشي بهذا الشكل وليجدر الإنسان + +716 +01:03:53,360 --> 01:04:01,510 +بنوع من الهدوءيفصل ال intermediate أجزيم فيه واضحة + +717 +01:04:01,510 --> 01:04:05,930 +الفكرة جدر الإنسان بنوع من الودوء يفصل ال + +718 +01:04:05,930 --> 01:04:10,130 +intermediate أجزيم طبعا الآن بيصير الإنسان يفكر طب + +719 +01:04:10,130 --> 01:04:16,010 +كيف يا ترى هذا الأجزيم هذا اللي فصلناه و سخناه و + +720 +01:04:16,010 --> 01:04:21,020 +أعطاه ذاك الناتج يعني أصلا عارفين أن هذامر عبر هذا + +721 +01:04:21,020 --> 01:04:26,840 +ال intermediate كيف هذا الكلام ممكن يكون تم جربنا + +722 +01:04:26,840 --> 01:04:35,830 +ان نعمل تفسير جربنا ان نعمل تفسير خلنا نشوفاللي + +723 +01:04:35,830 --> 01:04:40,810 +احنا حطناه التفسير اللي عملناه هي ال اكزيب مرسوم + +724 +01:04:40,810 --> 01:04:45,850 +بطريقة معينة انه من هنا فقد هذا الجزء غالبا على + +725 +01:04:45,850 --> 01:04:52,070 +شكل ال key و لو احنا حركنا هدول شوية بدلناهم شوية + +726 +01:04:52,070 --> 01:04:56,050 +روابط والجزء بلف زي ما بده يعني مجرد نخلي ال N H + +727 +01:04:56,050 --> 01:05:03,760 +هذه لهنا نجيب هنا C double bond NOH يعني هذه + +728 +01:05:03,760 --> 01:05:11,320 +الكربون هذه الكربون خليني أعلمها هي نفسها هذه + +729 +01:05:11,320 --> 01:05:15,800 +الكربون لأن بعد ما يفقد هذا على شكل الكيل شو حملة + +730 +01:05:15,800 --> 01:05:23,000 +هذه الكربون H minus صفية و حملة C حملة مثل double + +731 +01:05:23,000 --> 01:05:28,680 +bond Lو H حطوه بهذا الشكل و بعد هيك كملوا ال + +732 +01:05:28,680 --> 01:05:36,640 +cyclization بهذا الشكل وهذا تصير ايش فكل + +733 +01:05:36,640 --> 01:05:41,540 +اللي تم عملية فقد هذا الجزء عملية فقد هذا الجزء + +734 +01:05:41,540 --> 01:05:45,780 +carbon تنتل تلاتة و غالبا ان هذا الجزء فقد على شكل + +735 +01:05:45,780 --> 01:05:53,020 +ايش لكن و حصلنا على حلقة سداسية لان هذا نوع من + +736 +01:05:53,020 --> 01:05:59,940 +الايشring expansion او enlargement ring expansion + +737 +01:05:59,940 --> 01:06:05,160 +وكان مبين انه صار فيه amino group واضحة كان مبين + +738 +01:06:05,160 --> 01:06:09,760 +انه صار فيه amino group واضحة و تم تشخيص هذا + +739 +01:06:09,760 --> 01:06:15,240 +المركب و الكلام يعني تم نشره في ال journal in + +740 +01:06:15,240 --> 01:06:19,660 +Organica Chemica Act يعني مجلة محترمة + +741 +01:06:20,840 --> 01:06:25,880 +الان كل الهدف اللى كان عندنا حقيقة مش ال ring + +742 +01:06:25,880 --> 01:06:32,500 +transformation ال ring transformation إجت وين؟هجت + +743 +01:06:32,500 --> 01:06:37,740 +على جانب ليش؟ لأنه احنا الهدف اللي كان عندنا نحضر + +744 +01:06:37,740 --> 01:06:41,880 +ال oxime زي ما بيعملوا جماعة ال inorganic جماعة ال + +745 +01:06:41,880 --> 01:06:47,680 +inorganic بدهم by لجن عشان يجيبوا metal هي الآن + +746 +01:06:47,680 --> 01:06:52,420 +عليها زوج إلكترونات وهي الآن etch الان مع metal زي + +747 +01:06:52,420 --> 01:06:58,560 +nickel 2 plus مثلا لما نحط اتنين من هذا مش هيعملوا + +748 +01:06:58,560 --> 01:07:04,240 +روابطوحدة coordinate covalent و واحدة رابط عادية + +749 +01:07:04,240 --> 01:07:09,420 +covalent bond هي أنا فقدت H و كمان جزء زيه بيفقد H + +750 +01:07:09,420 --> 01:07:15,540 +و كل اللي بدنا نحصل عليه ال complex اللي يكون عامل + +751 +01:07:15,540 --> 01:07:21,000 +complexation وين؟ على هذه ال nitrogen تبعت ال + +752 +01:07:21,000 --> 01:07:26,820 +oxime و على هذه ال Hلحظوا لما نفقد من هنا H و من + +753 +01:07:26,820 --> 01:07:32,460 +الجزء التاني H هى صار اكم سالب عنده و ال metal + +754 +01:07:32,460 --> 01:07:37,220 +موجة ب اتنين اذا بطلع ليه .. بطلع ليه complex + +755 +01:07:37,220 --> 01:07:44,660 +للأسف الشديد مرة تانية اللى لاحظناه ماعرفش اذا هذه + +756 +01:07:44,660 --> 01:07:48,920 +الصورة مكبرينها ولا لا مرة تانية اللى لاحظناه احنا + +757 +01:07:48,920 --> 01:07:54,580 +بنحط ال metal عشان يتفاعل من هنا من الجهتينواضح + +758 +01:07:54,580 --> 01:08:00,180 +يعني هيعمل زي هيك و هيطلع الشكل التاني اللي لاحظ + +759 +01:08:00,180 --> 01:08:05,880 +ماهو كان متعب إلا يعني أخد وقت كثير أنه برضه + +760 +01:08:05,880 --> 01:08:10,220 +التفاعل ما تمش زي هيك شو هالتفاعلات اللي بتغلب + +761 +01:08:10,220 --> 01:08:15,420 +قبلها شو عمل التفاعل التفاعل إيجي على باله بطريقة + +762 +01:08:15,420 --> 01:08:21,100 +ما أنه يكسر هذه الرابطةتبهوا معايا شوفوا إيش اللي + +763 +01:08:21,100 --> 01:08:26,100 +بيصير جوا الجزية ال N كسر هذه لفوها هاتوا ال + +764 +01:08:26,100 --> 01:08:30,200 +carbon هنا وشبكوها على هذه ال N في مشكلة بعد ما + +765 +01:08:30,200 --> 01:08:33,480 +كسرت هذه اللي هاني بلفها صارت هانا ال carbon اللي + +766 +01:08:33,480 --> 01:08:39,640 +حاملة ايش R وR وشبكوها على ال N صار عند هذه الحلقة + +767 +01:08:39,640 --> 01:08:44,580 +الخمسية واحد اتنين تلاتة اربعة خمسة يعني هذه ال + +768 +01:08:44,580 --> 01:08:45,520 +CRR + +769 +01:08:47,660 --> 01:08:52,960 +كسرت من هذه الان و إجت شبكة في هذه الان زي كائنها + +770 +01:08:52,960 --> 01:08:59,640 +كانت شبكةها شبكتها ماني هانا شبكة بإيش؟ بان و هانا + +771 +01:08:59,640 --> 01:09:08,540 +شبكة بان كسرت شبكة منها الان وين صار عندى؟ وين صار + +772 +01:09:08,540 --> 01:09:12,970 +عندى ال nitrogen اللي ممكن يعمله؟الكمبليكس مع + +773 +01:09:12,970 --> 01:09:18,070 +الميتال على هذا المكان واضح ال نيتروجنز اللي ممكن + +774 +01:09:18,070 --> 01:09:21,370 +يعملوا الكمبليكس مع الميتال هنا وصار عندكم هنا ن + +775 +01:09:21,370 --> 01:09:25,930 +او ماينوس يعني تم عملية اكسيدياش اللي اتش و اتش في + +776 +01:09:25,930 --> 01:09:32,790 +مجمل الجزئي واضح ن او ماينوس و الجزئي اتغير هذا لو + +777 +01:09:32,790 --> 01:09:38,320 +بدوا يعملوا كمبليكس هيعملوا من هناأطلاقا مش الكلام + +778 +01:09:38,320 --> 01:09:42,940 +الأول يعني لاحظوا ان الحلقة اللي احنا بدأنا فيها + +779 +01:09:42,940 --> 01:09:49,080 +شو كانت one two four triazole يعني ال heterocyclic + +780 +01:09:49,080 --> 01:09:57,420 +ring الأساسية تطلع عليها one two four triazole + +781 +01:09:57,420 --> 01:10:02,080 +الان لما بيعمل هيك و بيلف هذا شو صارت الحلقة + +782 +01:10:02,080 --> 01:10:04,840 +الأساسية اميدازول + +783 +01:10:06,010 --> 01:10:13,730 +13 ديازول اميدازول و حامل اكسوجين الهيتيرو ساكل هي + +784 +01:10:13,730 --> 01:10:17,750 +اميدازول و حامل اكسوجين بعض الناس بيقول معقول + +785 +01:10:17,750 --> 01:10:21,890 +هالكلام ولا بتتخيلوا + +786 +01:10:21,890 --> 01:10:27,170 +انه كان و كسر وعمل يعني هذه ring transformation + +787 +01:10:27,170 --> 01:10:34,130 +تانيةبالتأكيد لو لأن الإنسان فصل كريستال وعمل X + +788 +01:10:34,130 --> 01:10:38,150 +-ray كريستالографي ولا عمر حد في الدنيا بيصدق هذا + +789 +01:10:38,150 --> 01:10:42,890 +الكلام واضح؟ هذه الـimages ولاحظوا مش الـNitrogens + +790 +01:10:42,890 --> 01:10:49,420 +دائما بنرسمها بالأزرق والأكسجلبالأحمر الأعضاء + +791 +01:10:49,420 --> 01:10:52,700 +الاميدازول هي ال N O وهي الكربون اللي حاملة + +792 +01:10:52,700 --> 01:10:56,860 +مجموعتين الميثل اللي رسمناها هذه الحلقة الجديدة + +793 +01:10:56,860 --> 01:11:05,300 +شايفينها؟ الآن هذا نتاج X-ray في بعض ال X-ray ال X + +794 +01:11:05,300 --> 01:11:09,380 +-ray إيش بيسموه؟ determination يعني you are sure + +795 +01:11:09,380 --> 01:11:14,250 +of this structureيعني انت مش جاعد ال spectroscopic + +796 +01:11:14,250 --> 01:11:20,590 +evidence NMR IR Carbon 13 هذا الإنسان بيشك فيه + +797 +01:11:20,590 --> 01:11:26,610 +ليش؟ لأنه فيه شوية عجل ممكن يكون غلط والدليل على + +798 +01:11:26,610 --> 01:11:32,010 +هيك انه انتوا في امتحان التشخيص كلكوا عندكوا ال + +799 +01:11:32,010 --> 01:11:37,270 +spectra IR Proton Mass Carbon 13 صح ولا لأ؟ بس مش + +800 +01:11:37,270 --> 01:11:41,920 +كلكوا بتجيبوا 100% ليش؟لأنه بتستعملوا العقل و + +801 +01:11:41,920 --> 01:11:46,740 +العقل يمكن أن يخطئ عشانك ناس بيجيبوا تسعين ناس + +802 +01:11:46,740 --> 01:11:49,400 +بيجيبوا تمانين ناس بيجيبوا سبعين طب يا رب كل ال + +803 +01:11:49,400 --> 01:11:53,380 +spectra عندكوا صح ال spectra مش موضوع خلاف الركع + +804 +01:11:53,380 --> 01:11:58,220 +لإيش الركع العقل ولذلك ال spectroscopic evidence + +805 +01:11:58,220 --> 01:12:02,300 +ممكن أنكوا تخطئوا فيه عشانكوا بتجيبوش علامة كاملة + +806 +01:12:02,300 --> 01:12:08,470 +في كورس التشخيص الآن ال X-rayزي بني أدم راح عنده + +807 +01:12:08,470 --> 01:12:12,610 +كسر بإيده حطه على جهاز ال X-Ray شافوا الكسر، شو + +808 +01:12:12,610 --> 01:12:18,310 +ضال كلام؟ خلاص، عملنا X-Ray ولذلك ال X-Ray في ال + +809 +01:12:18,310 --> 01:12:24,610 +.. بيسموه Structure Determination، تحديد بينما كل + +810 +01:12:24,610 --> 01:12:29,530 +سبكتروسكوبي، شو بيسمي احنا؟ Structure Elucidation + +811 +01:12:29,530 --> 01:12:34,150 +الـ Elucidation، بعمش مرة معاكم كلمة ولا لأ؟ + +812 +01:12:34,150 --> 01:12:34,970 +استنتاج + +813 +01:12:38,150 --> 01:12:42,110 +elucidation structure elucidation انتوا بتستنتجوا + +814 +01:12:42,110 --> 01:12:46,390 +الشكل طالما بتستنتجوا شغل المخ المخ يمكن ايش ان + +815 +01:12:46,390 --> 01:12:51,930 +يخطط لكن لما انا بحكي عن structure determination + +816 +01:12:51,930 --> 01:12:58,850 +هذا وين بشوفه بال X-ray طلعلي صورة X-ray بعد صورة + +817 +01:12:58,850 --> 01:13:03,230 +ال X-ray لما بيصوروا الفك مثلا و بيشوفوا انه طحونة + +818 +01:13:03,230 --> 01:13:08,470 +عجل مسوسة ولا اشي زي هيكبضلش إلا إنه بدهم يخلعوها، + +819 +01:13:08,470 --> 01:13:13,210 +خلاص شفنا الصورة، واضح؟ هذا الكلام لو لإنه الإنسان + +820 +01:13:13,210 --> 01:13:17,230 +شاف ال X-Ray و لا عمره فكر إنه تصير هيك رنج + +821 +01:13:17,230 --> 01:13:21,530 +ترانسفورماشن، إطلاقا ولا بتكون على الباب، الآن + +822 +01:13:21,530 --> 01:13:26,930 +اتخيلوا أنتوا عاد لما يكون شخص جاعد بيشتغل project + +823 +01:13:26,930 --> 01:13:32,270 +عشان تفهموا الفرق ما بينتجربة و ما بين الواقع + +824 +01:13:32,270 --> 01:13:36,630 +العملي قاعد بيشتغل project و بده يعمل هذا الأجزيم + +825 +01:13:36,630 --> 01:13:40,630 +شوف إيش اللي حطه في ال proposal تكوين هذا الأجزيم + +826 +01:13:40,630 --> 01:13:45,810 +و بعدين ييجي metal هنا يتفاعل على الأجزيم و سخن و + +827 +01:13:45,810 --> 01:13:49,930 +بده بالخطوة التانية بده يخلط ال metal و ما إلى ذلك + +828 +01:13:49,930 --> 01:13:55,130 +لأ طلع معه هذا الأجزيم في الأولطلع معه organic + +829 +01:13:55,130 --> 01:13:59,770 +product تاني أخدله ست شهور لما فهم الشغل عوض اشتغل + +830 +01:13:59,770 --> 01:14:05,950 +على البارد فصل ايش ال oxime بعد ما فصلوا يلا يا + +831 +01:14:05,950 --> 01:14:09,310 +oxime بدنا ياك تتفعل مع ال metal هنا حطوا مع ال + +832 +01:14:09,310 --> 01:14:15,050 +nickel اسيتات ولا ايش زي هيك برضه الناتج بيطلع + +833 +01:14:15,050 --> 01:14:23,430 +غريب و بينجلب المجموعاتلو لأنه في تقنيات حديثة زي + +834 +01:14:23,430 --> 01:14:28,090 +ال X-Ray أنا متأكد يمكن لو ماعرضتش عليكم X-Ray تلت + +835 +01:14:28,090 --> 01:14:32,870 +ارباعكم مابصدقش هالاشياء ان والله هذه كسرت ولفت + +836 +01:14:32,870 --> 01:14:39,110 +وإجتهانا إلا إذا في ثقة متبادلة + +837 +01:14:39,110 --> 01:14:45,690 +و لا الكلام بمنطق ال .. بمنطق ال .. العقل دائما ال + +838 +01:14:45,690 --> 01:14:53,420 +rigid transformation بقول HDGمفاجئ وبياخد من الناس + +839 +01:14:53,420 --> 01:14:58,480 +وقت كتير وعشان هيك ممكن الناس يخلطوا في شغلات + +840 +01:14:58,480 --> 01:15:03,380 +كثيرة يعني ممكن تشوفوا انتوا كعناوين للمقالات + +841 +01:15:03,380 --> 01:15:07,260 +ويجرب حد منكوا يدخل على ال google search بتلاقوا + +842 +01:15:07,260 --> 01:15:12,460 +العنوان اسمه the correct structure of كذا ايش معنى + +843 +01:15:12,460 --> 01:15:20,270 +الكلام ان في ناس قبل هيك اشتغلوا الشغل وحطواشيء + +844 +01:15:20,270 --> 01:15:25,090 +معين، incorrect، مش صح، ناس عادوا من وراهم جالو + +845 +01:15:25,090 --> 01:15:28,070 +لهم يا عم اللي انتوا استنتجتوا في ال spectroscopic + +846 +01:15:28,070 --> 01:15:34,350 +بشغلكم و كذا، مش صح، هاي الشكل الاش الصح فمنطقة + +847 +01:15:34,350 --> 01:15:39,530 +الكيميا يعني ما لم يكتمل ال evidence بشكل كبير و + +848 +01:15:39,530 --> 01:15:44,150 +من أفضل إكمال ال evidenceإنه الإنسان يشوف + +849 +01:15:44,150 --> 01:15:47,790 +structure مثلا ب X-ray على سبيل المثال بيضل + +850 +01:15:47,790 --> 01:15:53,750 +الإنسان إيش ب شك الآن بعد هيك بيصير الإنسان واثق + +851 +01:15:53,750 --> 01:15:58,850 +من الشكل لكن مش كتير أحيانا بيكون واثق من + +852 +01:15:58,850 --> 01:16:03,690 +التفسيرات اللي حطها كيف تم هذا التكون يعني انتبهوا + +853 +01:16:03,690 --> 01:16:10,230 +معي إنه في عندي شكل لما بصل أنا ل X-ray أنا بقولI + +854 +01:16:10,230 --> 01:16:14,870 +am sure انا اتاكدت من الشكل الان طب كيف صار زيك + +855 +01:16:14,870 --> 01:16:18,870 +مجون انكسر من هنا لف هنا هذا موجب هذا سلب الان هذه + +856 +01:16:18,870 --> 01:16:24,170 +المنطقة ممكن يكون فيها ايش خطأ لان هذه منطقة عقل + +857 +01:16:24,170 --> 01:16:31,270 +ومنطقة تفسير فالانسان في كل يعني مبادئ حياته يكون + +858 +01:16:31,270 --> 01:16:38,320 +مميز بين شغلتينبين الشغلة اللي هي حقيقة وشغلة اللي + +859 +01:16:38,320 --> 01:16:44,320 +هي ايش تفسير الان النظرية بشكل عام هي محاولة ايش + +860 +01:16:44,320 --> 01:16:50,760 +تفسير ولذلك انتوا الان بتقدروا لأي شيء مجتمعي + +861 +01:16:50,760 --> 01:16:57,260 +تقولوا ان هذا الكلام حقيقة يعني مثلا الموظفين بغزا + +862 +01:16:57,260 --> 01:17:06,980 +لم يتقاضوا راتب هذا حقيقةلا تحتمل الخطأ لكن السبب + +863 +01:17:06,980 --> 01:17:12,300 +حكومة الوحدة ولا الحكومة السابقة ولا الدول المانحة + +864 +01:17:12,300 --> 01:17:17,750 +ولا الدول العربية هذه محاولات تفسيرتحتمل الخطأ + +865 +01:17:17,750 --> 01:17:23,890 +الآن أصعب شيء إذا الإنسان دخل الجامعة واتخرج منها + +866 +01:17:23,890 --> 01:17:28,670 +وهو بتبنى وجهة نظر تفسيرية يحتمل غيرها ومصير عليها + +867 +01:17:28,670 --> 01:17:32,930 +معنا ذلك هذا ماتعلمش ثقافة الجامعة ثقافة الجامعة + +868 +01:17:32,930 --> 01:17:38,550 +أن الواحد يعرف إيش الإشي الأكيد ويقول هذا أكيد إيش + +869 +01:17:38,550 --> 01:17:43,470 +الإشي اللي بحتمل ويقول هذا إيش يحتمل الآن هذا + +870 +01:17:43,470 --> 01:17:49,220 +الشكل أكيد التفسيرغير أكيد، الآن في كتير من + +871 +01:17:49,220 --> 01:17:54,300 +الظواهر اللي في الحياة هتواجهكم، الظاهرة نفسها، + +872 +01:17:54,300 --> 01:17:58,360 +أكيدة، يعني أن اليوم صار عندها منخفض و نزل تلج + +873 +01:17:58,360 --> 01:18:04,240 +كتير، هذا إشيأكيد الآن بعض الناس يبدأوا تفسيرات و + +874 +01:18:04,240 --> 01:18:08,480 +الله هذا نتيجة ثانو أكسيد الكربون ولا نتيجة الكذا + +875 +01:18:08,480 --> 01:18:12,220 +ولا نتيجة تغيرات المناخية طب و كل واحد بحط ايش + +876 +01:18:12,220 --> 01:18:18,380 +تفسير من عنده بأمل انه يكون صار عندكوا فكرةإيش + +877 +01:18:18,380 --> 01:18:22,260 +معنى ال ring transformation بس بالتأكيد مش هيصير + +878 +01:18:22,260 --> 01:18:27,060 +ما عندكم إحساس إيش صارت إلا إذا كنتوا بتشتغلوا + +879 +01:18:27,060 --> 01:18:31,200 +رسالة ماجستير و حصلت معكوا و أخرتكوا خمس .. خمس ست + +880 +01:18:31,200 --> 01:18:36,360 +شهور سبعة لحد ما تفهموها بكل الأحوال مطلوب منكوا + +881 +01:18:36,360 --> 01:18:41,720 +homework مثال على ال ring transformation مجرد ما + +882 +01:18:41,720 --> 01:18:46,480 +تكتبوا ring transformation هيجيكوا أنفلة كتيرةواضح + +883 +01:18:46,480 --> 01:18:49,600 +و بننهي لهذا القصد + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/sUku3WpljhE_raw.json b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/sUku3WpljhE_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..58931e768c6eb43a91f0803fc848ad2d42ae43a3 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/sUku3WpljhE_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 3267, "start": 20.69, "end": 32.67, "text": "بسم الله الرحمن الرحيم الآن موضوعنا ما زال في الطرق العامة في تحضير ال heterocyclic rings العنوان العام electrocyclic reactions", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 6024, 48506, 3714, 2407, 11242, 45367, 8315, 19446, 30767, 6027, 8978, 41950, 2288, 4587, 18863, 10943, 3660, 8978, 6055, 5016, 11242, 13546, 2423, 20789, 31078, 66, 1050, 11136, 18863, 1863, 2407, 7649, 18863, 10943, 16717, 1344, 66, 1050, 12215], "avg_logprob": -0.14150191813099142, 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{"start": 803.31, "end": 803.75, "word": " كفينيل", "probability": 0.86982421875}, {"start": 803.75, "end": 804.61, "word": " دايازوميثين", "probability": 0.9539620535714286}, {"start": 804.61, "end": 805.43, "word": " انسخنوا", "probability": 0.7759765625}, {"start": 805.43, "end": 805.97, "word": " شوية", "probability": 0.9259440104166666}, {"start": 805.97, "end": 807.87, "word": " بيعمل", "probability": 0.949462890625}, {"start": 807.87, "end": 808.33, "word": " الاش", "probability": 0.5130615234375}, {"start": 808.33, "end": 809.51, "word": " الإلكترو", "probability": 0.71258544921875}, {"start": 809.51, "end": 810.07, "word": " سايكليك", "probability": 0.931640625}, {"start": 810.07, "end": 810.71, "word": " رياكشن", "probability": 0.9662109375}, {"start": 810.71, "end": 811.03, "word": " و", "probability": 0.5595703125}, {"start": 811.03, "end": 811.65, "word": " بيسكر", "probability": 0.8543701171875}, {"start": 811.65, "end": 812.25, "word": " ل", "probability": 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{"start": 824.79, "end": 825.47, "word": " تلقائي", "probability": 0.96865234375}, {"start": 825.47, "end": 825.87, "word": " جدا", "probability": 0.958984375}, {"start": 825.87, "end": 826.27, "word": " ليش", "probability": 0.614013671875}, {"start": 826.27, "end": 826.65, "word": " لأنه", "probability": 0.7745768229166666}, {"start": 826.65, "end": 827.01, "word": " واضح", "probability": 0.9469401041666666}, {"start": 827.01, "end": 827.31, "word": " double", "probability": 0.6201171875}, {"start": 827.31, "end": 827.73, "word": " single", "probability": 0.8193359375}, {"start": 827.73, "end": 828.05, "word": " double", "probability": 0.92431640625}, {"start": 828.05, "end": 828.43, "word": " single", "probability": 0.919921875}, {"start": 828.43, "end": 828.89, "word": " double", "probability": 0.962890625}, {"start": 828.89, "end": 830.65, "word": " بالتالي", "probability": 0.796722412109375}, {"start": 830.65, "end": 831.47, "word": " حركة", "probability": 0.9871419270833334}, 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bond", "probability": 0.96923828125}, {"start": 852.79, "end": 853.33, "word": " O", "probability": 0.9453125}, {"start": 853.33, "end": 856.09, "word": " azide", "probability": 0.699462890625}, {"start": 856.09, "end": 857.43, "word": " بالتسخين", "probability": 0.8986328125}, {"start": 857.43, "end": 857.89, "word": " شو", "probability": 0.937744140625}, {"start": 857.89, "end": 858.43, "word": " بتصير", "probability": 0.9680989583333334}, {"start": 858.43, "end": 859.43, "word": " C", "probability": 0.494140625}, {"start": 859.43, "end": 859.65, "word": " double", "probability": 0.939453125}, {"start": 859.65, "end": 860.01, "word": " bond", "probability": 0.9658203125}, {"start": 860.01, "end": 860.59, "word": " O", "probability": 0.98388671875}, {"start": 860.59, "end": 861.97, "word": " نيترين", "probability": 0.8367919921875}], "temperature": 1.0}, {"id": 35, "seek": 88638, "start": 863.42, "end": 886.38, "text": "الـ C double bond O أزايد بالتسخيل بتصير C double bond O نيترين وقلنا كمان ان الـ C double bond O نيترين بال courtesary arrangement بتشبك من هنا من الان فبصير عندك carbon N double bond C double bond O لاحظوا هاي ال carbon اللي مبينه بالأحمر وين هتشبك", "tokens": [6027, 39184, 383, 3834, 6086, 422, 5551, 11622, 995, 25708, 20666, 2655, 3794, 9778, 26895, 39894, 9381, 13546, 383, 3834, 6086, 422, 8717, 36081, 2288, 9957, 4032, 4587, 1211, 8315, 9122, 2304, 7649, 16472, 2423, 39184, 383, 3834, 6086, 422, 8717, 36081, 2288, 9957, 20666, 4753, 279, 822, 17620, 39894, 8592, 3555, 4117, 9154, 34105, 9154, 2423, 7649, 6156, 3555, 9381, 13546, 43242, 4117, 5954, 426, 3834, 6086, 383, 3834, 6086, 422, 20193, 5016, 19913, 14407, 8032, 47302, 2423, 5954, 13672, 1829, 3714, 3555, 9957, 3224, 20666, 10721, 5016, 29973, 4032, 9957, 8032, 2655, 8592, 3555, 4117], "avg_logprob": -0.26052297286841336, "compression_ratio": 1.7733990147783252, "no_speech_prob": 0.0, "words": [{"start": 863.42, "end": 863.68, "word": "الـ", "probability": 0.6064453125}, {"start": 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هذه ال court yes rearrangement اللي حكينا عنها في المحاضرة الماضية الآن هذا ال system اللي مبين باللون الأحمر fully conjugated system بيعمل electro cycle creation و بيسكر", "tokens": [3615, 1863, 8717, 36081, 2288, 29245, 9957, 31453, 426, 12322, 31453, 426, 12322, 1975, 2655, 5016, 12610, 2655, 5296, 286, 539, 1344, 282, 473, 29538, 2423, 4753, 2086, 39568, 518, 13672, 1829, 11331, 4117, 1829, 8315, 18871, 11296, 8978, 9673, 5016, 46958, 25720, 9673, 46958, 10632, 6024, 48506, 23758, 2423, 1185, 13672, 1829, 3714, 3555, 9957, 20666, 1211, 11536, 16247, 5016, 29973, 4498, 29456, 770, 1185, 4724, 1829, 25957, 1211, 16717, 6586, 8016, 4032, 4724, 1829, 3794, 37983], "avg_logprob": -0.25771360005004496, "compression_ratio": 1.462962962962963, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 887.35, "end": 887.71, "word": "عن", "probability": 0.595947265625}, {"start": 887.71, "end": 888.33, "word": " نيتروجين", "probability": 0.8720703125}, {"start": 888.33, "end": 888.97, 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اللي", "probability": 0.841796875}, {"start": 895.61, "end": 895.93, "word": " حكينا", "probability": 0.966552734375}, {"start": 895.93, "end": 896.23, "word": " عنها", "probability": 0.992919921875}, {"start": 896.23, "end": 896.57, "word": " في", "probability": 0.8603515625}, {"start": 896.57, "end": 897.11, "word": " المحاضرة", "probability": 0.981689453125}, {"start": 897.11, "end": 897.57, "word": " الماضية", "probability": 0.9903971354166666}, {"start": 897.57, "end": 898.39, "word": " الآن", "probability": 0.6392822265625}, {"start": 898.39, "end": 899.19, "word": " هذا", "probability": 0.9482421875}, {"start": 899.19, "end": 899.93, "word": " ال", "probability": 0.955078125}, {"start": 899.93, "end": 900.47, "word": " system", "probability": 0.94580078125}, {"start": 900.47, "end": 901.59, "word": " اللي", "probability": 0.9599609375}, {"start": 901.59, "end": 901.89, "word": " مبين", "probability": 0.853515625}, {"start": 901.89, "end": 902.25, "word": " باللون", "probability": 0.9519856770833334}, {"start": 902.25, "end": 902.81, "word": " الأحمر", "probability": 0.9542643229166666}, {"start": 902.81, "end": 903.39, "word": " fully", "probability": 0.8115234375}, {"start": 903.39, "end": 904.19, "word": " conjugated", "probability": 0.94384765625}, {"start": 904.19, "end": 904.79, "word": " system", "probability": 0.9697265625}, {"start": 904.79, "end": 905.61, "word": " بيعمل", "probability": 0.9378662109375}, {"start": 905.61, "end": 905.99, "word": " electro", "probability": 0.62890625}, {"start": 905.99, "end": 906.47, "word": " cycle", "probability": 0.447998046875}, {"start": 906.47, "end": 907.03, "word": " creation", "probability": 0.53515625}, {"start": 907.03, "end": 907.19, "word": " و", "probability": 0.67529296875}, {"start": 907.19, "end": 907.67, "word": " بيسكر", "probability": 0.800048828125}], "temperature": 1.0}, {"id": 37, "seek": 93050, "start": 908.16, "end": 930.5, "text": "فهذا التفاعل تم فيه عمليتين اتعلمناه من العملية الأولى ان الآزايد بالتسخين صار نيترين و العملية التانية ان الـ C double bond O نيترين عملت Cortis rearrangement ل Isocyanate عملت Cortis rearrangement ل Isocyanate", "tokens": [5172, 3224, 15730, 16712, 5172, 995, 30241, 46811, 8978, 3224, 6225, 2304, 20292, 2655, 9957, 1975, 2655, 3615, 19528, 8315, 3224, 9154, 18863, 42213, 10632, 16247, 12610, 7578, 16472, 6024, 95, 11622, 995, 25708, 20666, 2655, 3794, 9778, 9957, 20328, 9640, 8717, 36081, 2288, 9957, 4032, 18863, 42213, 10632, 16712, 7649, 10632, 16472, 2423, 39184, 383, 3834, 6086, 422, 8717, 36081, 2288, 9957, 6225, 42213, 2655, 28522, 271, 39568, 518, 5296, 286, 539, 1344, 282, 473, 6225, 42213, 2655, 28522, 271, 39568, 518, 5296, 286, 539, 1344, 282, 473], "avg_logprob": -0.22586804959509107, "compression_ratio": 1.7624309392265194, "no_speech_prob": 0.0, "words": [{"start": 908.16, "end": 908.62, "word": "فهذا", "probability": 0.8352864583333334}, {"start": 908.62, "end": 909.24, "word": " التفاعل", "probability": 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{"start": 922.38, "end": 923.38, "word": " rearrangement", "probability": 0.809326171875}, {"start": 923.38, "end": 923.8, "word": " ل", "probability": 0.93017578125}, {"start": 923.8, "end": 926.54, "word": " Isocyanate", "probability": 0.733740234375}, {"start": 926.54, "end": 927.34, "word": " عملت", "probability": 0.9747721354166666}, {"start": 927.34, "end": 927.82, "word": " Cortis", "probability": 0.87548828125}, {"start": 927.82, "end": 928.96, "word": " rearrangement", "probability": 0.94384765625}, {"start": 928.96, "end": 929.1, "word": " ل", "probability": 0.9873046875}, {"start": 929.1, "end": 930.5, "word": " Isocyanate", "probability": 0.9732421875}], "temperature": 1.0}, {"id": 38, "seek": 95452, "start": 932.44, "end": 954.52, "text": "هذه أمثلة إضافية المثال اللي هنا واضح أنه مثال شوية بسيط لأنه عندي double bonds مجرد أنه رتبناهم على شكل حلقة و خلناهم يتحركوا بيعمل cyclization مافيش فيه مشكلة كثيرة هذا المثال لأ مش ينبين فيه double bonds لكن موجود فيه إيش؟", "tokens": 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of the unicycle شو قلنا عنه rearrangements rearrangement هذا موضوع تالت الآن ال cycle addition reactions", "tokens": [5172, 6027, 39184, 19474, 2144, 472, 6086, 11723, 16490, 1211, 9381, 8315, 3224, 28242, 13672, 1829, 5551, 9778, 3215, 8315, 3224, 25961, 19474, 2144, 6024, 48506, 2423, 6586, 4500, 3714, 2407, 11242, 45367, 6055, 7649, 1829, 8032, 22653, 7435, 1829, 8717, 7435, 25513, 12174, 9566, 34268, 9957, 20449, 45030, 11242, 8717, 25957, 1211, 9122, 10943, 12602, 16758, 9566, 3660, 12602, 16758, 9566, 2655, 9957, 28239, 45367, 16712, 6027, 2655, 8978, 2423, 2674, 3170, 5296, 2423, 13081, 295, 264, 517, 2632, 2160, 13412, 2407, 12174, 1211, 8315, 18871, 3224, 39568, 1117, 39568, 518, 23758, 3714, 2407, 11242, 45367, 6055, 6027, 2655, 6024, 48506, 2423, 6586, 4500, 12215], "avg_logprob": -0.2478095760969358, "compression_ratio": 1.7469879518072289, "no_speech_prob": 0.0, "words": [{"start": 1282.04, "end": 1282.4, "word": "فالـ", "probability": 0.4544270833333333}, {"start": 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"temperature": 1.0}, {"id": 55, "seek": 134251, "start": 1317.13, "end": 1342.51, "text": "Cyclo-addition reaction is a pericyclic معنى pericyclic تفاعل بتكون فيه لترانزيشن state تبعته with a cyclic geometry تفاعل هذي لترانزيشن state عاملة حلقة ولا لأ هذي اللي بتتكونه بتتكون روبوت هذي لترانزيشن state Cyclic ولا لأ هذا التفاعل إيش بنسميه احنا؟", "tokens": [34, 88, 66, 752, 12, 25224, 849, 5480, 307, 257, 680, 2632, 66, 1050, 20449, 1863, 7578, 680, 2632, 66, 1050, 6055, 5172, 995, 30241, 39894, 30544, 8978, 3224, 5296, 2655, 2288, 7649, 11622, 1829, 8592, 1863, 1785, 6055, 3555, 34268, 3224, 365, 257, 38154, 1050, 18426, 6055, 5172, 995, 30241, 8032, 8848, 1829, 5296, 2655, 2288, 7649, 11622, 1829, 8592, 1863, 1785, 6225, 10943, 37977, 11331, 1211, 28671, 49429, 5296, 10721, 8032, 8848, 1829, 13672, 1829, 39894, 2655, 30544, 3224, 39894, 2655, 30544, 12602, 37746, 35473, 8032, 8848, 1829, 5296, 2655, 2288, 7649, 11622, 1829, 8592, 1863, 1785, 10295, 66, 1050, 49429, 5296, 10721, 23758, 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"end": 1323.99, "word": " بتكون", "probability": 0.85107421875}, {"start": 1323.99, "end": 1324.21, "word": " فيه", "probability": 0.9326171875}, {"start": 1324.21, "end": 1324.97, "word": " لترانزيشن", "probability": 0.784942626953125}, {"start": 1324.97, "end": 1325.57, "word": " state", "probability": 0.20849609375}, {"start": 1325.57, "end": 1326.79, "word": " تبعته", "probability": 0.87890625}, {"start": 1326.79, "end": 1329.09, "word": " with", "probability": 0.587890625}, {"start": 1329.09, "end": 1329.35, "word": " a", "probability": 0.7822265625}, {"start": 1329.35, "end": 1329.81, "word": " cyclic", "probability": 0.891357421875}, {"start": 1329.81, "end": 1330.57, "word": " geometry", "probability": 0.35009765625}, {"start": 1330.57, "end": 1331.47, "word": " تفاعل", "probability": 0.84228515625}, {"start": 1331.47, "end": 1331.61, "word": " هذي", "probability": 0.463623046875}, {"start": 1331.61, "end": 1332.33, "word": " لترانزيشن", "probability": 0.9588623046875}, {"start": 1332.33, "end": 1332.85, "word": " state", "probability": 0.884765625}, {"start": 1332.85, "end": 1333.61, "word": " عاملة", "probability": 0.8929036458333334}, {"start": 1333.61, "end": 1333.99, "word": " حلقة", "probability": 0.9742838541666666}, {"start": 1333.99, "end": 1334.23, "word": " ولا", "probability": 0.6787109375}, {"start": 1334.23, "end": 1334.61, "word": " لأ", "probability": 0.9296875}, {"start": 1334.61, "end": 1334.93, "word": " هذي", "probability": 0.7444661458333334}, {"start": 1334.93, "end": 1335.23, "word": " اللي", "probability": 0.673828125}, {"start": 1335.23, "end": 1335.95, "word": " بتتكونه", "probability": 0.537506103515625}, {"start": 1335.95, "end": 1336.37, "word": " بتتكون", "probability": 0.6363118489583334}, {"start": 1336.37, "end": 1336.77, "word": " روبوت", "probability": 0.380859375}, {"start": 1336.77, "end": 1337.65, "word": " هذي", "probability": 0.6565348307291666}, {"start": 1337.65, "end": 1338.33, "word": " لترانزيشن", "probability": 0.923126220703125}, {"start": 1338.33, "end": 1338.67, "word": " state", "probability": 0.89013671875}, {"start": 1338.67, "end": 1339.55, "word": " Cyclic", "probability": 0.6550496419270834}, {"start": 1339.55, "end": 1339.77, "word": " ولا", "probability": 0.9296875}, {"start": 1339.77, "end": 1340.21, "word": " لأ", "probability": 0.97802734375}, {"start": 1340.21, "end": 1340.83, "word": " هذا", "probability": 0.460205078125}, {"start": 1340.83, "end": 1341.35, "word": " التفاعل", "probability": 0.96142578125}, {"start": 1341.35, "end": 1341.57, "word": " إيش", "probability": 0.7774251302083334}, {"start": 1341.57, "end": 1342.09, "word": " بنسميه", "probability": 0.9249267578125}, {"start": 1342.09, "end": 1342.51, "word": " احنا؟", "probability": 0.858154296875}], "temperature": 1.0}, {"id": 56, "seek": 135858, "start": 1343.16, "end": 1358.58, "text": "بـ Recycling chemical reaction in which two or more unsaturated molecules or parts of molecules يعني هاي جزيئان 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"word": " الحلقة", "probability": 0.9759114583333334}, {"start": 1480.06, "end": 1481.24, "word": " الناتجة", "probability": 0.881103515625}, {"start": 1481.24, "end": 1481.64, "word": " و", "probability": 0.93310546875}, {"start": 1481.64, "end": 1482.0, "word": " ممكن", "probability": 0.8857421875}, {"start": 1482.0, "end": 1482.9, "word": " نصنفهم", "probability": 0.9623046875}, {"start": 1482.9, "end": 1483.9, "word": " اعتمادا", "probability": 0.9205322265625}, {"start": 1483.9, "end": 1484.3, "word": " على", "probability": 0.8125}, {"start": 1484.3, "end": 1485.14, "word": " عدد", "probability": 0.990234375}, {"start": 1485.14, "end": 1485.3, "word": " ال", "probability": 0.96337890625}, {"start": 1485.3, "end": 1485.6, "word": " By", "probability": 0.06231689453125}, {"start": 1485.6, "end": 1486.5, "word": " Electrons", "probability": 0.88916015625}, {"start": 1486.5, "end": 1487.5, "word": " المتفاعلة", "probability": 0.931884765625}, {"start": 1487.5, "end": 1487.64, "word": 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150457, "start": 1495.97, "end": 1504.57, "text": "هذا الـ Chelotropic reaction هو حقيقة اللى مر علينا لما كنا ناخد ال cycle addition of carbenes and nitrates", "tokens": [3224, 15730, 2423, 39184, 24345, 310, 39173, 5480, 31439, 11331, 38436, 28671, 13672, 7578, 3714, 2288, 25894, 8315, 5296, 15042, 9122, 8315, 8717, 47283, 3215, 2423, 6586, 4500, 295, 1032, 1799, 279, 293, 10900, 12507], "avg_logprob": -0.23654513474967745, "compression_ratio": 1.153225806451613, "no_speech_prob": 0.0, "words": [{"start": 1495.97, "end": 1496.53, "word": "هذا", "probability": 0.948486328125}, {"start": 1496.53, "end": 1496.83, "word": " الـ", "probability": 0.722412109375}, {"start": 1496.83, "end": 1497.43, "word": " Chelotropic", "probability": 0.7980143229166666}, {"start": 1497.43, "end": 1498.11, "word": " reaction", "probability": 0.65087890625}, {"start": 1498.11, "end": 1498.81, "word": " هو", "probability": 0.95849609375}, {"start": 1498.81, "end": 1499.51, "word": " حقيقة", "probability": 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+00:00:36,140 --> 00:00:40,680 +ربما كان في نقطة أن احنا اتكلمنا على الطرفين، بمعنى + +5 +00:00:40,680 --> 00:00:44,920 +اتكلمنا على حلقة تكون غير مشبعة تمامًا (fully) + +6 +00:00:44,920 --> 00:00:49,500 +unsaturated ring وعلى حلقة تكون مشبعة تمامًا (fully) + +7 +00:00:49,500 --> 00:00:55,020 +saturated ring، بواقع الحال، مرات كثير بيمر معنى حاجة + +8 +00:00:55,020 --> 00:01:01,050 +بين بين، يعني بيكون الحلقة فيها مواقع غير مشبعة + +9 +00:01:01,050 --> 00:01:05,830 +وفيها مواقع مشبعة، في هذه الحالة كيف بدنا نسمي + +10 +00:01:05,830 --> 00:01:09,790 +الحلقة؟ يعني مثلًا بالحلقة الخماسية، أنا قلت الـ + +11 +00:01:09,790 --> 00:01:14,150 +unsaturated ring نهايتها -ane، الـ saturated ring + +12 +00:01:14,150 --> 00:01:20,070 +نهايتها -ane، طب حلقة فيها جزء unsaturated وجزء saturated + +13 +00:01:20,070 --> 00:01:24,930 +كيف بدي أسميها؟ في البداية بقول بدي أنسبها إلى الـ -ane + +14 +00:01:24,930 --> 00:01:29,630 +بدي أنسبها للـ unsaturated system، وبعد هيك بدي أجي + +15 +00:01:29,630 --> 00:01:36,200 +لمواقع التشبع وأحددها، إذا كان عندي فقط موضع واحد + +16 +00:01:36,200 --> 00:01:42,920 +للتشبع بحدده بحرف H، إذا عندي موقعين بحددهم بـ + +17 +00:01:42,920 --> 00:01:49,200 +dihydro، إذا عندي ثلاث مواقع بحددهم بـ H و dihydro، و + +18 +00:01:49,200 --> 00:01:53,820 +بخلي الـ H تأخذ الترقيم الأقل، إذا عندي أربع مواقع + +19 +00:01:53,820 --> 00:01:59,220 +بحددهم بـ tetrahydro، إذا عندي خمس مواقع بحددهم بـ + +20 +00:01:59,220 --> 00:02:04,240 +H وتتراهايدرو، والـ H هتأخذ الترقيم الأقل، هذا + +21 +00:02:04,240 --> 00:02:11,580 +الكلام بنقدر نفهمه أكثر من خلال أمثلة، لاحظوا مثلًا + +22 +00:02:11,580 --> 00:02:16,580 +في المثال الأول، في عندنا حلقة ثلاثية فيها نيتروجين + +23 +00:02:16,580 --> 00:02:22,920 +أنا في الحلقة الثلاثية، لما حطيت الروابط الزوجية دلّ + +24 +00:02:22,920 --> 00:02:26,740 +في عندي موقع مشبع، يعني الـ nitrogen والـ carbon + +25 +00:02:26,740 --> 00:02:30,540 +عادة بيحتملوا double bond لكن مش موجودة + +26 +00:02:32,680 --> 00:02:36,600 +لذلك، حلقة ثلاثية بـ double bond كان ممكن أرسمها + +27 +00:02:36,600 --> 00:02:40,900 +بهذا الشكل اللي موجود عندنا، وكان ممكن أرسمها بهذا + +28 +00:02:40,900 --> 00:02:45,360 +الشكل، طب يا ترى هل هذا المركب وهذا المركب + +29 +00:02:45,360 --> 00:02:50,720 +بيأخذوا نفس الاسم؟ لو أنا كنت بدأت أسميهم، لو أنا كنت + +30 +00:02:50,720 --> 00:02:56,740 +بدأت أسميهم على الـ unsaturated ring هأقول أن هذا as + +31 +00:02:56,740 --> 00:03:07,290 +aziridine، وهذا برضه as aziridine، خلينا نحطه بـ in زي ما حكت + +32 +00:03:07,290 --> 00:03:14,150 +اسم اللي كتب as aziridine، لكن هنا ما زال في عندنا موقع + +33 +00:03:14,150 --> 00:03:20,570 +مشبع، اللي هو في هذه الحالة الموقع هذا، وهنا الموقع + +34 +00:03:20,570 --> 00:03:27,510 +هذا، بنحدد هذا الموقع من خلال إضافة إيش؟ H لتحديد + +35 +00:03:27,510 --> 00:03:31,450 +الموقع المشبع، في هذا الترقيم هذا موقع واحد، إذا + +36 +00:03:31,450 --> 00:03:41,410 +نحن بنقول 1H-aziridine، في المركب الثاني بدي أقول + +37 +00:03:41,410 --> 00:03:44,530 +الـ nitrogen رقم واحد، الـ H بدي الـ saturated + +38 +00:03:44,530 --> 00:03:48,350 +position ياخذ أقل ترقيم، بمعنى بعد ما بحطها أنا + +39 +00:03:48,350 --> 00:03:52,370 +واحد، هل يا ترى بدي أقول واحد اتنين تلاتة يصير + +40 +00:03:52,370 --> 00:03:57,630 +الموقع المشبع تلاتة؟ ولا أقول واحد اتنين تلاتة يصير + +41 +00:03:57,630 --> 00:04:01,730 +اتنين اتنين، بخلي الموقع المشبع أقل ترقيم، إذا هذا + +42 +00:04:01,730 --> 00:04:08,050 +2H-aziridine، واضح؟ + +43 +00:04:08,570 --> 00:04:12,890 +لو جيت على المركب اللي بعده، لاحظوا المركبين + +44 +00:04:12,890 --> 00:04:19,110 +حلقة رباعية بـ double bond، الآن كم موقع مشبع عندي + +45 +00:04:19,110 --> 00:04:23,830 +في هذه الحلقة؟ الـ oxygen لا تحتمل روابط أكثر من + +46 +00:04:23,830 --> 00:04:27,970 +اتنين، الـ carbons عليهم double bond لكن هذه الـ + +47 +00:04:27,970 --> 00:04:30,850 +nitrogen تحتمل double bond ولذلك الـ double bond + +48 +00:04:30,850 --> 00:04:35,690 +ممكن تكون بهذا الموقع هنا، هذه الـ nitrogen هي الذرة + +49 +00:04:36,800 --> 00:04:42,900 +المشبعة، أو تكون بهذا الموقع، الـ double bond هذه الـ + +50 +00:04:42,900 --> 00:04:48,960 +نيتروجين هي الذرة المشبعة، الآن لو اجيت لاسم المركب + +51 +00:04:48,960 --> 00:04:54,440 +بدي اسميه إيش؟ بدي أنسبه لـ -ete للحلقة الرباعية غير + +52 +00:04:54,440 --> 00:05:04,110 +المشبعة، إذا هذا oxazet، وأي oxazet؟ 1,2- لأن + +53 +00:05:04,110 --> 00:05:09,770 +هذا الأكسجين واحد، وهذه رقم اتنين، الآن الذرة + +54 +00:05:09,770 --> 00:05:15,790 +المشبعة وين موقعها؟ إذا هذا 2H-1,2-oxazet، لو أتيت على المركب اللي بعده نفس الشيء تمامًا + +55 +00:05:15,790 --> 00:05:21,490 +هيكون 1,2-oxazet، لاحظوا ترقيمنا رقم واحد + +56 +00:05:21,490 --> 00:05:26,310 +واتنين، اهتمينا بشكل أساسي بالـ hetero atoms، ما حدش + +57 +00:05:26,310 --> 00:05:31,170 +يجي يقول لي بتخلي الموقع المشبع أقل ترقيم، يروح يقول + +58 +00:05:31,170 --> 00:05:34,930 +1,2، اهتمامي أساسًا الـ hetero atoms أقل ما يمكن + +59 +00:05:34,930 --> 00:05:41,430 +إذا هذا 1,2,3,4، هذا 1,2-oxazet، oxazet + +60 +00:05:41,430 --> 00:05:53,910 +oxazet، oxazet، oxazet، oxazet، oxazet + +61 +00:05:53,910 --> 00:05:58,410 +oxazet، oxazet، + +62 +00:05:58,410 --> 00:05:59,990 +oxazet، oxazet، oxazet، oxazet، oxazet، oxazet + +63 +00:05:59,990 --> 00:06:04,430 +oxazet، oxazet، oxazet، oxazet، oxazet، oxazet، + +64 +00:06:04,430 --> 00:06:06,850 +oxazet، oxazet، oxazet، oxazet، oxazet، oxazet + +65 +00:06:06,850 --> 00:06:11,350 +oxazet، oxazet، oxazet، oxazet، oxazet، oxazet، + +66 +00:06:11,350 --> 00:06:11,930 +oxazet، oxazet، oxazet، oxazet، oxazet + +67 +00:06:11,930 --> 00:06:15,010 +oxazet، أز + +68 +00:06:17,190 --> 00:06:23,150 +واضح؟ هذا موقع وهذا الموقع مشبعين، بيحتملوا رابطة + +69 +00:06:23,150 --> 00:06:27,630 +وكان ممكن تكون موجودة هذه الرابطة في هذه الحالة + +70 +00:06:27,630 --> 00:06:32,330 +بدي أحدد هذول المواقع، بدي أحدد هذول المواقع، طيب + +71 +00:06:32,330 --> 00:06:36,210 +لما بدي أحدد هذول المواقع، إيش الترقيم اللي بدي + +72 +00:06:36,210 --> 00:06:44,270 +أعطيه؟ واحد، اتنين، تلاتة، أربعة، + +73 +00:06:50,480 --> 00:06:57,660 +طيب، ما أنا .. بدي هدول 1,2، okay، بهذا الشكل 1, + +74 +00:06:57,660 --> 00:07:00,820 +2، وبهذا الشكل 1,2، هنا حسين عند اتنين وتلاتة أقل خمسة، وواحد وأربعة، خمسة، بفضل أشوف الرقم + +75 +00:07:00,820 --> 00:07:08,020 +الأقل عندك، إذا هذا، لو بدي أسميه إيش هأسميه؟ diazet، + +76 +00:07:08,020 --> 00:07:16,780 +طبعًا أي diazet، 1,2- 1,2-diazet، إيش أخد + +77 +00:07:16,780 --> 00:07:24,130 +مواقع مشبعة؟ 1,4-dihydro، مرة + +78 +00:07:24,130 --> 00:07:37,370 +تانية نعمله بشكل أوضح، واحد، اتنين، تلاتة، أربعة، واضح؟ + +79 +00:07:37,370 --> 00:07:45,750 +diazet، diazet، + +80 +00:07:45,750 --> 00:07:47,850 +diazet، + +81 +00:07:49,410 --> 00:07:55,550 +oxazet، في مشكلة على الـ diazet الآن؟ هذا الـ diazet، + +82 +00:07:55,550 --> 00:08:00,950 +الـ nitrogen فيه على أي مواقع؟ 1,2- 1,2- + +83 +00:08:00,950 --> 00:08:05,410 +diazet، ضاعت المشكلة عندكم أنه بدي أبدأ الـ 1,2- + +84 +00:08:05,410 --> 00:08:11,060 +منها ولا الـ 1,2- منها؟ إذا بدأت بهذا الشكل، + +85 +00:08:11,060 --> 00:08:16,440 +المواقع المشبعة عندكم هتأخذ أرقام إيش؟ واحد وأربعة، + +86 +00:08:16,440 --> 00:08:22,080 +وإذا بدأت بهذا الشكل اتنين وتلاتة، واحد وأربعة، واتنين وتلاتة، صار عندكم مشكلة أن هي فيها الرقم + +87 +00:08:22,080 --> 00:08:25,860 +الأقل، الـ 1 بمشي عليها، إذا هذا هيصير 1,4- + +88 +00:08:25,860 --> 00:08:33,720 +dihydro، + +89 +00:08:33,720 --> 00:08:35,940 +dihydro، + +90 +00:08:37,400 --> 00:08:46,320 +1,2,3,4,5,6,7,8,9,10,11,12، + +91 +00:08:46,320 --> 00:08:50,920 +13,14,15، + +92 +00:08:50,920 --> 00:09:00,480 +16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31، + +93 +00:09:00,480 --> 00:09:02,180 +32,33,33,33,33,33,33,33,33,33,33,33,33,33,33,33، + +94 +00:09:02,180 --> 00:09:08,000 +33-dihydro، لاحظوا لما كان عندي موقع مشبع واحد + +95 +00:09:08,000 --> 00:09:15,960 +استعملت الـ H، لما صار عندي موقعين dihydro، بعد شوية + +96 +00:09:15,960 --> 00:09:22,800 +ممكن نشوف أمثلة فيها تلات مواقع مشبعة، شو هنستعمل؟ H + +97 +00:09:22,800 --> 00:09:28,500 +و dihydro، ما بيستعملوش tetrahydro أو الـ trihydro + +98 +00:09:28,500 --> 00:09:31,920 +بعض الناس .. يا عفوا، أن الـ trihydro، بعض الناس ممكن + +99 +00:09:31,920 --> 00:09:34,940 +يتخيل أن ممكن أقول الـ trihydro، الـ trihydro مش + +100 +00:09:34,940 --> 00:09:38,460 +موجودة، يعني لو فتشت كتب الكيمياء الحلقية وتسميته + +101 +00:09:38,460 --> 00:09:42,120 +مافيش حاجة اسمها الـ trihydro، لما يكون عندي تلات ذرات + +102 +00:09:42,120 --> 00:09:47,220 +مشبعة، بنستعمل توضيح + +103 +00:09:47,220 --> 00:09:53,640 +مواقع التشبع بـ H و dihydro، وبخلي الـ H تكون أخذة رقم + +104 +00:09:53,640 --> 00:10:02,380 +الأقل فيهم، خلينا نتطلع مثلًا على أمثلة معينة فيها + +105 +00:10:02,380 --> 00:10:10,820 +ها تلات مواقع المشبعة، أنا بتخيل يمكن هذا المثال فيه + +106 +00:10:10,820 --> 00:10:16,490 +تلات مواقع مشبعة، يعني هذه الأمثلة اللي موجودة عندنا + +107 +00:10:16,490 --> 00:10:20,210 +خلينا بس نحدد فيها المواقع المشبعة، وبإمكانكم + +108 +00:10:20,210 --> 00:10:24,310 +تشتغلوا أكثر أنتم فيها، هذا المركب .. كم موقع مشبع + +109 +00:10:24,310 --> 00:10:27,390 +فيه؟ اتنين .. اتنين .. إذا لما تسموه إيش هتقولوا + +110 +00:10:27,390 --> 00:10:34,010 +عنه؟ dihydro .. dihydro .. هذا المركب .. اتنين + +111 +00:10:34,010 --> 00:10:38,950 +.. dihydro .. dihydro .. هذا المركب اللي هنا + +112 +00:10:38,950 --> 00:10:41,970 +.. واحد .. موقع واحد فقط + +113 +00:10:44,780 --> 00:10:52,660 +موقع واحد، هذا المركب موقع واحد، واضح؟ هذه المواقع + +114 +00:10:52,660 --> 00:10:57,140 +هي اللي بدنا نحددها، وأكيد الترقيم هيخضع لقواعد + +115 +00:10:57,140 --> 00:11:01,680 +الترقيم العامة، يعني هنا أنا ملزم أقول واحد، اتنين + +116 +00:11:01,680 --> 00:11:06,740 +تلاتة، أربعة، خمسة، هنا ملزم أقول واحد، اتنين، تلاتة + +117 +00:11:06,740 --> 00:11:11,790 +أربعة، خمسة، مش عندي، واضح؟ هنا هأجي أقول واحد، اتنين، + +118 +00:11:11,790 --> 00:11:15,810 +تلاتة، أربعة، خمسة، لاحظوا هنا ما بدأت الترقيم من هذه + +119 +00:11:15,810 --> 00:11:19,130 +النقطة، لأن لو بدأت من هنا 1,2,3، 1,2, + +120 +00:11:19,130 --> 00:11:22,990 +3، لكن هذا 1,2,3، بيخلي الموقع المشبع + +121 +00:11:22,990 --> 00:11:29,530 +تلاتة، هذا 1,2,3، بيخليه واحد، هنا هأمشي 1, + +122 +00:11:29,530 --> 00:11:36,250 +2,3,4,5، أو 1,2,3,4, + +123 +00:11:36,250 --> 00:11:42,240 +إذا هذا الترقيم اللي بدي أستعمله، وبتكمل الأسماء + +124 +00:11:42,240 --> 00:11:45,800 +بالطريقة اللي اتعلمناها، لو طلعنا على المركب اللي + +125 +00:11:45,800 --> 00:11:52,780 +هنا، كان موقع مشبع فيه، هنستعمل لهم أيضًا dihydro، + +126 +00:11:52,780 --> 00:12:01,860 +هيكون ترقيمنا 1,2,3,4,5، 2,5- + +127 +00:12:03,850 --> 00:12:08,630 +واضح؟ كملوا الاسم الآن، لو اتطلعنا على المركب اللي + +128 +00:12:08,630 --> 00:12:15,470 +موجود عندنا هنا، في عنده تلات مواقع مشبعة فيه، خلينا + +129 +00:12:15,470 --> 00:12:20,810 +نسميه بشكل كامل، قلنا حلقة سداسية فيها مواقع + +130 +00:12:20,810 --> 00:12:26,110 +unsaturated ومواقع saturated، إذا هنسبها للنهاية + +131 +00:12:26,110 --> 00:12:34,950 +-ine، إذا هذا المركب -ine، أي -ine؟ أي حلقة سداسية oxa + +132 +00:12:34,950 --> 00:12:40,250 +diazine، لأنه فيه oxygen ونتين nitrogen، هذا oxa + +133 +00:12:40,250 --> 00:12:47,650 +diazine، oxa diazine، شو مواقع الـ oxygen والـ + +134 +00:12:47,650 --> 00:12:54,190 +nitrogen؟ ملزمين نبدأ ترقيمنا من الـ oxygen والمركّب + +135 +00:12:54,190 --> 00:12:57,510 +الـ hetero atoms أسرع ما يمكن، إذا إحنا ملزمين بهذا + +136 +00:12:57,510 --> 00:13:09,010 +الترقيم، مش في خيار، إذا هذا 1,3,4-oxadiazine، دلّ + +137 +00:13:09,010 --> 00:13:17,190 +في عنده توضيح المواقع المشبعة، هذا موقع 3، هذا موقع + +138 +00:13:17,190 --> 00:13:23,860 +6، هذا موقع، كيف بدي أوضحهم؟ باستعمال الـ H والـ + +139 +00:13:23,860 --> 00:13:29,760 +dihydro، عادة الموقع اللي ماخذ الـ H هو اللي بيخلي + +140 +00:13:29,760 --> 00:13:35,680 +إيش أقل ما يمكن، وبكتبه مباشرة قبل هذا الاسم، إذا + +141 +00:13:35,680 --> 00:13:42,280 +هذا المركب two H هي اللي وضحت الموقع هذا إيش ضال + +142 +00:13:42,280 --> 00:13:47,500 +عندك؟ 3,6-dihydro + +143 +00:13:48,830 --> 00:13:58,570 +فهذا المُركّب 3,6-dihydro-2-H-1,3,4-oxadiazine واضح؟ + +144 +00:13:58,570 --> 00:14:04,170 +لاحظوا أنه أنا بشكل عام حتى تنتبهوا لأهمية تحديد + +145 +00:14:04,170 --> 00:14:09,330 +مواقع التشبع بجيبلكم نفس المُركّب فقط اتغير فيه + +146 +00:14:09,330 --> 00:14:14,370 +double bonds يعني هذا أكسوجين وذرتين نتروجين واحد + +147 +00:14:14,370 --> 00:14:23,370 +تلاتة أربعة هذا نفسه فقط غيرت مواقع التشبع ولذلك لو + +148 +00:14:23,370 --> 00:14:27,390 +بتطلع على الاسم اللي هنكتبه هناك لنفس هذا المركب + +149 +00:14:27,390 --> 00:14:30,650 +هتلاحظوا إنه هتلاحظوا فيه 1,3,4 + +150 +00:14:30,650 --> 00:14:38,130 +oxodiazine الـ 1,3,4-oxodiazine ثابتة، + +151 +00:14:38,130 --> 00:14:42,870 +الآن بعد ذلك الاختلاف فقط في مواقع التشبع اللي أنا + +152 +00:14:42,870 --> 00:14:48,430 +عبرت عنها بهذه الأشياء واضح؟ ولذلك هذا لو بدنا + +153 +00:14:48,430 --> 00:14:55,670 +نكتب الاسم تبعه هنا هو عبارة عن 1,3,4-oxa + +154 +00:14:55,670 --> 00:15:03,850 +-diazine وهذا المركب لما بدا رقم واحد اثنين ثلاثة + +155 +00:15:03,850 --> 00:15:13,970 +أربعة خمسة ستة أكيد هيكون 2-H-5,6-dihydro + +156 +00:15:13,970 --> 00:15:20,140 +2-H-5,6- طبعًا لما نذكره بشكل كامل 5,6 + +157 +00:15:20,140 --> 00:15:24,340 +-Dihydro-2-H-1,3,4-Oxidized لاحظوا الموقع المشبع + +158 +00:15:24,340 --> 00:15:29,000 +اللي بيوضحه بالـ H دائمًا بيكون ملتصق بالاسم الآن + +159 +00:15:29,000 --> 00:15:34,820 +Dihydro و Tetrahydro بتوضع في البداية تعمل ك + +160 +00:15:34,820 --> 00:15:39,190 +Substituent يعني لو في substituents ثانية هذي بتيجي + +161 +00:15:39,190 --> 00:15:43,150 +كـ alphabetical حرف الـ D لو في عندك الحرف الـ A + +162 +00:15:43,150 --> 00:15:46,310 +لو في عندك مثل الحرف الـ M وبحطهم مرتبين + +163 +00:15:46,310 --> 00:15:50,890 +alphabetically واضح فالـ Dihydro والـ Tetra + +164 +00:15:50,890 --> 00:15:59,450 +hydro تعامل كأنها substituent وبتتوضح أو بتاخد + +165 +00:15:59,450 --> 00:16:03,090 +موقعها حسب الترتيب الـ alphabetical مع ال + +166 +00:16:03,090 --> 00:16:10,530 +substituents الثانية الآن أحيانًا في نظام قديم + +167 +00:16:10,530 --> 00:16:16,850 +لتوضيح التشبع وعدم التشبع يعني في الحالات اللي هي + +168 +00:16:16,850 --> 00:16:22,290 +الحلقة لا هي مشبعة بالكامل ولا هي غير مشبعة + +169 +00:16:22,290 --> 00:16:27,810 +بالكامل هذا النظام القديم بيعتمد مش على أن أحدد + +170 +00:16:27,810 --> 00:16:33,340 +المواقع المشبعة لأ أحدد الـ double bondsلاحظوا + +171 +00:16:33,340 --> 00:16:37,720 +إنتوا المركب، النص نص، يعني فيه مشبع وغير + +172 +00:16:37,720 --> 00:16:43,480 +مشبع، فيه مواقع مشبعة وفيه double bonds، مظبوط + +173 +00:16:43,480 --> 00:16:47,360 +ولا لا؟ في الأمثلة السابقة، أنا إيش اللي كنت + +174 +00:16:47,360 --> 00:16:53,570 +أحدده؟ المواقع المشبعة وأنثى الـ double bonds في + +175 +00:16:53,570 --> 00:16:58,750 +نظام ثاني موجود وقديم لكن ممكن تقرأ وأنثى عليه + +176 +00:16:58,750 --> 00:17:03,770 +بيحدد مواقع الـ double bonds مش مواقع التشبع يعني + +177 +00:17:03,770 --> 00:17:08,290 +بيركز على إنه عشان يميز شكل عن الشكل الثاني إنه + +178 +00:17:08,290 --> 00:17:11,490 +يذكر وين موقع الـ double bond أو التلتين double + +179 +00:17:11,490 --> 00:17:15,690 +bonds الموجودين طبعًا هو بيذكر موقع البداية لل + +180 +00:17:15,690 --> 00:17:19,730 +double bond أكيد الـ double bond ماخدة موقعين مثلًا + +181 +00:17:19,730 --> 00:17:26,090 +هذا المركب هي فيه unsaturated part وفيه saturated + +182 +00:17:26,090 --> 00:17:33,430 +part فلما احنا بنيجي بنسميه بنظام الـ Dihydro لو + +183 +00:17:33,430 --> 00:17:37,830 +هذا بدي اسمه أنا بنظام الـ Dihydro كيف بدي اسمه؟ + +184 +00:17:37,830 --> 00:17:45,030 +بدي أقول هي نمرة واحد اثنين ثلاثة أربعة خمسة وهذا + +185 +00:17:45,030 --> 00:17:46,590 +إيش يكون اسمه؟ + +186 +00:17:48,570 --> 00:17:54,650 +2,3-Dihydro + +187 +00:17:54,650 --> 00:18:00,310 +بيرول ماشي + +188 +00:18:00,310 --> 00:18:05,630 +المركب بيرول أو بعدين بنحط بيرول and أكسيد لأن ال + +189 +00:18:05,630 --> 00:18:11,050 +بيرول حامل أكسجين يعني مش مشكلة كبيرة بيرول and + +190 +00:18:11,050 --> 00:18:18,650 +أكسيد لاحظوا نسبنا لإيش؟ للـ Pyrole وخلّينا المواقع + +191 +00:18:18,650 --> 00:18:23,610 +المشبعة أقل ما يمكن الآن في نظام ثاني للتسمية أن + +192 +00:18:23,610 --> 00:18:27,510 +أنا أذكر الـ double bonds طبعًا بحط الـ Dimethyls إن + +193 +00:18:27,510 --> 00:18:32,610 +أنا أذكر موقع الـ double bond في هذه الحالة بستعمل + +194 +00:18:32,610 --> 00:18:37,970 +الرمز Delta وبخلّي الـ double bond تاخد أقل ترقيم + +195 +00:18:39,230 --> 00:18:44,270 +لحظة هغير نظام الترقيم هقرأ واحد اثنين ثلاثة أربعة + +196 +00:18:44,270 --> 00:18:48,350 +خمسة فلما أنا بقول Delta 2 معنى ذلك بداية ال + +197 +00:18:48,350 --> 00:18:51,690 +double bond على موقع اثنين يعني الـ double bond + +198 +00:18:51,690 --> 00:18:55,050 +هتكون طالما هذه بيانت Delta 2 إذا هتكون ال + +199 +00:18:55,050 --> 00:19:00,250 +double bond بين اثنين وثلاثة الآن في حالة الحلقة + +200 +00:19:00,250 --> 00:19:06,510 +الخمسية جاب لي نهاية جديدة ما مرتش عليها أنا كان + +201 +00:19:06,510 --> 00:19:12,010 +عندي النهاية للحلقة الـ unsaturated all ولـ fully + +202 +00:19:12,010 --> 00:19:18,410 +saturated ولـ deal جاب لي نهاية جديدة، إيش هي؟ + +203 +00:19:18,410 --> 00:19:19,110 +قليل + +204 +00:19:22,790 --> 00:19:28,610 +واضح؟ ووضح مكان الـ double bond باستعمال Delta فجال + +205 +00:19:28,610 --> 00:19:33,570 +Delta 2 يعني بتبدأ على الموقع اثنين وخلّى الترقيم + +206 +00:19:33,570 --> 00:19:38,490 +يمر على الـ double bond أسرع ما يمكن طبعًا آخذين + +207 +00:19:38,490 --> 00:19:44,420 +بعلي اعتبار إن لو فيه ترو أتوم الأصل لهم الأولوية + +208 +00:19:44,420 --> 00:19:49,900 +ولذلك هذا المركب ضمن هذه التسمية صار 5,5- + +209 +00:19:49,900 --> 00:19:55,200 +dimethyl Delta 2 بداية الـ double bond Delta 2 + +210 +00:19:55,200 --> 00:20:03,660 +Pyrroline N-oxide لو أتيت على المركب الثاني مافيش + +211 +00:20:03,660 --> 00:20:10,140 +فيه N-oxide وDimethyl سماه Delta 2 Pyrroline لكن + +212 +00:20:10,140 --> 00:20:15,720 +لو أنا كنت بدي اسمي هذا المركب الـ Delta 2 + +213 +00:20:15,720 --> 00:20:25,140 +Pyrroline حسب نظام الـ Dihydro بدي أسأل نفسي كم موقع + +214 +00:20:25,140 --> 00:20:31,900 +مشبع فيه؟ ثلاثة، تلت مواقع مشبعة، إذا هستعمل فيه + +215 +00:20:31,900 --> 00:20:38,250 +نظام؟ الـ H والـ Dihydro التلات مواقع مشبعة هذا + +216 +00:20:38,250 --> 00:20:41,550 +الموقع وهذا الموقع وهذا الموقع وهعطيهم أقل + +217 +00:20:41,550 --> 00:20:48,270 +ترقيم إذا هيصير الترقيم تبعي واحد اثنين ثلاثة + +218 +00:20:48,270 --> 00:20:54,930 +أربعة خمسة هقول أن هذا بيرول + +219 +00:20:54,930 --> 00:21:02,650 +والـ 2,3-Dihydro + +220 +00:21:04,760 --> 00:21:11,780 +هذا الأشهر واللي احنا هنستعمله لكن اللي بيقرأ في + +221 +00:21:11,780 --> 00:21:17,260 +مجلات قديمة اللي هيمر عليه بين يوم ويوم ثاني Delta 2 + +222 +00:21:17,260 --> 00:21:21,020 +Delta 3 هيجي يقول أنا هذه الشغلة ما أخذتهاش في + +223 +00:21:21,020 --> 00:21:26,080 +التسمية لأ بنقول تاريخيًا هذا الكلام موجود إنه ممكن + +224 +00:21:26,080 --> 00:21:32,560 +أتعامل مع المركبات اللي هيبين بين يعني لا هي مشبعة + +225 +00:21:32,560 --> 00:21:35,860 +تمامًا ولا غير مشبعة تمامًا باستعمال هذه الطريقة، + +226 +00:21:35,860 --> 00:21:39,060 +هذه طريقة قديمة، الآن الطريقة المعتمدة بالـ IUPAC + +227 +00:21:39,060 --> 00:21:43,060 +Nomenclature هي هذه الطريقة، لكن يا ترى + +228 +00:21:43,060 --> 00:21:48,180 +الإنسان بيقرأ ممكن يمر عليه تسميات بهذا الشكل، أقل + +229 +00:21:48,180 --> 00:21:53,470 +تقدير، إذا مرت عليه، يكون فاهم إيش معنى هذه + +230 +00:21:53,470 --> 00:21:58,250 +التسميات؟ إيش معنى هذه التسميات؟ وإن كان الآن، + +231 +00:21:58,250 --> 00:22:01,450 +يعني لو بدأت أقول في السنوات الأخيرة إجليل + +232 +00:22:01,450 --> 00:22:05,190 +هتلاحظه ناس بيسموا بهذه الطريقة، يعني الكل بيحاول + +233 +00:22:05,190 --> 00:22:08,270 +يلتزم بالـ IUPAC لكن لو قرأته مقال مثلًا + +234 +00:22:08,270 --> 00:22:12,350 +من السبعينات، من الثمانينات، من الستينات، هتلاحظه + +235 +00:22:12,350 --> 00:22:17,340 +في هذا النظام، فاللي بده يقرأ في نهاية بده يفهم وزي + +236 +00:22:17,340 --> 00:22:22,120 +ما حكيتلكوا أنا ومرة ثانية بأكد هاي مثلًا عندي + +237 +00:22:22,120 --> 00:22:26,540 +مركب حلقة خمسية Oxygen وTwo Nitrogens أخذت منها + +238 +00:22:26,540 --> 00:22:32,280 +التلات احتمالات الـ fully unsaturated والـ fully + +239 +00:22:32,280 --> 00:22:40,800 +saturated واللي موجود بين بين ضمن هذا النظام الـ + +240 +00:22:40,800 --> 00:22:44,620 +fully unsaturated سميته 1,2,3,4,5- + +241 +00:22:44,620 --> 00:22:52,820 +1,2,4-oxadiazole والـ fully saturated 1, + +242 +00:22:52,820 --> 00:22:58,780 +2,4-oxadiazolidine أخذنا النهاية واضح؟ الآن + +243 +00:22:58,780 --> 00:23:05,240 +هذا اللي أتي بين بينه أخذ نهاية جديدة ولين صار 1, + +244 +00:23:05,240 --> 00:23:14,420 +2,4-oxadiazoline الآن لما صار بهذا الشكل أحدد + +245 +00:23:14,420 --> 00:23:21,540 +موقع الـ double bond في هذا النظام أحدد موقع ال + +246 +00:23:21,540 --> 00:23:27,940 +double bond مش التشبع إذا أنا هحط Delta Delta 2 + +247 +00:23:33,160 --> 00:23:38,060 +هذا Delta تشوفوه Delta تشوفوه Delta تشوفوه Delta + +248 +00:23:38,060 --> 00:23:42,970 +تشوفوه نظام الثالثة بيحدد لموقع الـ Double bond مش + +249 +00:23:42,970 --> 00:23:47,630 +موقع المشبع واضح؟ وعشان هيك ما نستغربش كثير لو + +250 +00:23:47,630 --> 00:23:53,750 +قرأنا مثلًا هذا الاسم بيسمي معدى الحلقات الخمسية + +251 +00:23:53,750 --> 00:23:57,890 +فيها all و deal و lil الحلقات الثانية بيسميها + +252 +00:23:57,890 --> 00:24:03,270 +باستعمال Tetrahedral و Dihedral لكن ما بيحددش + +253 +00:24:03,270 --> 00:24:08,200 +مواقع التشبع بيحدد موقع إيش الـ Double bond فهذا في + +254 +00:24:08,200 --> 00:24:13,340 +موقع اثنين ثلاثة أربعة مشبعين ولذلك قال Tetra + +255 +00:24:13,340 --> 00:24:18,040 +hydro الآن هل يا ترى بده يحدد أربع مواقع التشبع ولا + +256 +00:24:18,040 --> 00:24:22,540 +يحدد موقع الـ double bond ضمن هذا النظام حدد موقع + +257 +00:24:22,540 --> 00:24:28,080 +الـ double bond بأقل ما يمكن فإيش قال 1,2,3, + +258 +00:24:28,080 --> 00:24:33,750 +بـ Delta 3 Delta 3 Tetrahydro Pyridine لعبوا + +259 +00:24:33,750 --> 00:24:39,290 +لو هذا المركب اللي كنتوا تسموه إنتوا بتحديد الأربع + +260 +00:24:39,290 --> 00:24:49,030 +ذرات المشبعة كان إيش هتحطوه؟ أيضًا تابع البريدين، + +261 +00:24:49,030 --> 00:24:54,850 +هذا كلام صحيح وTetrahydro مافي خلاف، لكن وين + +262 +00:24:54,850 --> 00:25:03,280 +الأربع ذرات؟ واحد، اثنين، ثلاثة، أربعة خمسة ستة + +263 +00:25:03,280 --> 00:25:06,820 +مواقع التشبع واحد اثنين اثنين اثنين اثنين + +264 +00:25:06,820 --> 00:25:07,340 +اثنين اثنين اثنين اثنين اثنين اثنين + +265 +00:25:07,340 --> 00:25:11,060 +اثنين اثنين اثنين اثنين اثنين اثنين اثنين + +266 +00:25:11,060 --> 00:25:11,660 +اثنين اثنين اثنين اثنين اثنين اثنين اثنين + +267 +00:25:11,660 --> 00:25:11,720 +اثنين اثنين اثنين اثنين اثنين اثنين اثنين + +268 +00:25:11,720 --> 00:25:13,760 +اثنين اثنين اثنين اثنين اثنين اثنين اثنين + +269 +00:25:13,760 --> 00:25:14,000 +اثنين اثنين اثنين اثنين اثنين اثنين اتن + +270 +00:25:17,250 --> 00:25:23,590 +1,2,3,6-Tetrahydro هنا ذكرت مواقع التشبع هنا ذكرت + +271 +00:25:23,590 --> 00:25:27,790 +الـ double bond وهذه الأمثلة زيها هي في هذا الموقع + +272 +00:25:27,790 --> 00:25:31,390 +واحد اثنين ثلاثة أربعة لاحظوا كم موقع مشبع عندي + +273 +00:25:31,390 --> 00:25:37,010 +هنا واحد اثنين ثلاثة كان بإمكاني أذكرهم وأقول H + +274 +00:25:37,010 --> 00:25:43,330 +وDihydro أو بإمكاني أقول وين بداية الـ double bond + +275 +00:25:43,330 --> 00:25:53,250 +Delta 5 استعمل الـ Dihydro هنا وهذا Oxazoline + +276 +00:25:53,250 --> 00:26:00,210 +طبعًا ما استعملش Isoxazole له لو كنت بستعمله + +277 +00:26:00,210 --> 00:26:04,770 +Dihydro بدأ استعمله Isoxazole + +278 +00:26:06,800 --> 00:26:13,280 +و1,2,3-Dihydro Isoxazole لكن لما استعمل + +279 +00:26:13,280 --> 00:26:17,560 +باستعمال الـ Delta 1,2- بداية الـ double bond 2, + +280 +00:26:17,560 --> 00:26:24,600 +فجال Delta 2-Oxazoline ولاحظوا صارت النهاية لهي + +281 +00:26:24,600 --> 00:26:30,910 +ولا هي only دين صار عندي نهاية جديدة قولين على + +282 +00:26:30,910 --> 00:26:37,390 +أي حال زي ما حكيتلكوا هذا نظام قديم قلّ استعماله + +283 +00:26:37,390 --> 00:26:41,890 +ولكن لا بأس أن احنا نكون اتعرفنا عليه اللي لو + +284 +00:26:41,890 --> 00:26:46,970 +قرأنا مركب ولجينا فيه delta وفوقها رمز نعرف أن + +285 +00:26:46,970 --> 00:26:50,590 +هذا الرمز هو بداية double bond + +286 +00:26:54,970 --> 00:26:58,290 +من الأشياء اللي بتواجهنا أيضا في تسمية الـ + +287 +00:26:58,290 --> 00:27:02,830 +heterocyclic compounds إذا كانوا بيحتووا على C + +288 +00:27:02,830 --> 00:27:07,530 +double bond O أو C double bond S بنسميها exocyclic + +289 +00:27:07,530 --> 00:27:11,170 +C double bond O أو C double bond S الآن الـ C + +290 +00:27:11,170 --> 00:27:16,230 +double bond O عادة بنعطيها النهاية on والـ C + +291 +00:27:16,230 --> 00:27:18,910 +double bond S عادة بنعطيها النهاية + +292 +00:27:22,900 --> 00:27:29,800 +ثيون وهي عندنا أمثلة في هذا المركب مثلا واحد + +293 +00:27:29,800 --> 00:27:36,680 +اتنين تلاتة أربعة خمسة هتلاحظوا هذا تترازول على + +294 +00:27:36,680 --> 00:27:42,070 +نمرة خمسة ايش فيه؟ five-theon الآن وضحنا مواقع + +295 +00:27:42,070 --> 00:27:46,750 +التشبع على واحد واربعة dimethyl واستعمل five-h + +296 +00:27:46,750 --> 00:27:52,130 +one-fourth-dihydro one-fourth-dimethyl five-h الآن + +297 +00:27:52,130 --> 00:27:55,370 +على خلاف بين الناس اللي بيسموا أن لازم تكون ال + +298 +00:27:55,370 --> 00:28:00,710 +five-h ولا أن ترجعها تصير one-h ونكون أدق في + +299 +00:28:00,710 --> 00:28:04,650 +القواعد four-five-dihydro one-h على أساس أن احنا + +300 +00:28:04,650 --> 00:28:10,020 +اتفقنا أن الهتلاحظوا أن في ناس سموا مركبات + +301 +00:28:10,020 --> 00:28:14,180 +واعتادوا أنهم يذكروها بشكل معين بمعنى في تسمية + +302 +00:28:14,180 --> 00:28:18,100 +الكيميا الحلقية ولما ترجعوا لواقع الناس كيف + +303 +00:28:18,100 --> 00:28:24,900 +بيسموا وللمقالات هتبدو تلاحظوا أنه في أشياء بسيطة + +304 +00:28:24,900 --> 00:28:30,220 +هتلاحظوا خلاف عن القواعد بشكلها الدقيق واضح؟ يعني + +305 +00:28:30,220 --> 00:28:34,220 +مش هتلاحظوا أن كل التسميات اللي موجودة في المجلات + +306 +00:28:34,220 --> 00:28:39,160 +تسميات ملتزمة بالقواعد بشكل دقيق، الأصل أنها تكون + +307 +00:28:39,160 --> 00:28:45,730 +ملتزمة، بس هتلاحظوا انحراف عنها وأنتم بتقرأوه في + +308 +00:28:45,730 --> 00:28:50,850 +أكثر من حالة طبعا هذا المثال مسمى بطريقتين ممكن + +309 +00:28:50,850 --> 00:28:54,930 +هذا الـ oxygen الـ exocyte اللي نستعمل لها exo و + +310 +00:28:54,930 --> 00:28:58,650 +نحطه كأنه substitute وممكن نحطه في نهاية الاسم في + +311 +00:28:58,650 --> 00:29:03,890 +نهاية on واضح؟ الأمرين موجودين يعني لما عندي c + +312 +00:29:03,890 --> 00:29:08,290 +double bond o ممكن أخرها لنهاية الاسم زي ما بعمل + +313 +00:29:08,290 --> 00:29:14,120 +ketone اسيتون بروبانون بيوتانون أحطها بنهاية الاسم + +314 +00:29:14,120 --> 00:29:18,700 +بنهاية on وأحدد موقعها طبعا واضح هنا أن هاي + +315 +00:29:18,700 --> 00:29:28,860 +الترقيم 1 2 3 4 5 6 ولذلك بيبين المركب 6 on 124 + +316 +00:29:28,860 --> 00:29:35,720 +triazine in اللي هي بتاعة الحلقة السوداسية وانحذفت + +317 +00:29:35,720 --> 00:29:41,280 +منها الـ E لأنها التقت مع Ohana على نمرة أربعة مثلا + +318 +00:29:41,280 --> 00:29:45,180 +حاملة Amino ع نمرة واحد حاملة Phenyl وفي عنده + +319 +00:29:45,180 --> 00:29:50,060 +مواقع مشبعة واحد واربعة وخمسة وستة ف one four five + +320 +00:29:50,060 --> 00:29:54,820 +six tetrahedral one two four triazine six oxo + +321 +00:29:54,820 --> 00:29:59,000 +لاحظوا لو بتكونوا تجربوا تفهموها الاسم منطقي ولا + +322 +00:29:59,000 --> 00:30:01,520 +لأ تريازين + +323 +00:30:02,480 --> 00:30:07,840 +six oxo تترا هايدرو هاي الأربع مواقع المشبعة four + +324 +00:30:07,840 --> 00:30:12,520 +amino one phenyl ما فيش مشكلة بهذه الحالة استعمل + +325 +00:30:12,520 --> 00:30:18,760 +بدل ما يحط six oxo كتبها جوا الاسم six oxo هذا + +326 +00:30:18,760 --> 00:30:30,620 +بتلاقوه الشغلتين بتلاقوهم موجودين لأ + +327 +00:30:30,620 --> 00:30:36,160 +هذا هذا لما رقم استعمل زي هيك one two three four + +328 +00:30:36,160 --> 00:30:43,240 +five اعتبر أن هذه تلت مواقع التشابع الشيء الوحيد + +329 +00:30:43,240 --> 00:30:48,080 +اللي أنا نبحت له أنه ممكن يكون فيه غلط أن أحدد هذه + +330 +00:30:48,080 --> 00:30:53,460 +وهذول فلو بدي أخلي هذه أقل ما يمكن بدي أقول one + +331 +00:30:53,460 --> 00:30:57,880 +etch وجدت بدي أخلي مواقع التشبع التانين four + +332 +00:30:57,880 --> 00:31:01,700 +five يعني لو أنا بدي أخد الأصحى لاحظوا أنا أحيانا + +333 +00:31:01,700 --> 00:31:05,880 +بجيبلكم أسماء زي ما بينت في المجلات وفي المقالات + +334 +00:31:06,370 --> 00:31:12,670 +ونبهت إنه في شيء ممكن يكون أدق الآن هذا درجة إنه + +335 +00:31:12,670 --> 00:31:16,070 +ينكتب في المجلات بهذا الشكل احنا لما قلنا تلت + +336 +00:31:16,070 --> 00:31:21,770 +مواقع تشبع ايش اللي بنخليه أقل ترقيم الـ H إذا + +337 +00:31:21,770 --> 00:31:26,590 +المفروض أقول هنا one H وهنا four five ونبهت أنا + +338 +00:31:26,590 --> 00:31:33,090 +لهذه المشكلة وقلت إنه أنا بجيبلكم أمور زي ما هي في + +339 +00:31:33,090 --> 00:31:38,030 +أرض الواقع أنه في أرض الواقع لما تسمعوا ما بتلاقوش + +340 +00:31:38,030 --> 00:31:42,810 +الشيء المثالي طبيعي ولا لأ؟ في أرض الواقع كل الناس + +341 +00:31:42,810 --> 00:31:47,570 +بتجوزوا عشان يعيشوا حياة سعيدة لكن جداش اللي منهم + +342 +00:31:47,570 --> 00:31:53,470 +بيعيش حياة سعيدة؟ + +343 +00:31:53,470 --> 00:31:56,310 +لأ بقى أنا بدي الـ nitrogen + +344 +00:32:18,420 --> 00:32:26,080 +لو بتتطلعوا على هذا المركب على سبيل المثال لاحظوا + +345 +00:32:26,080 --> 00:32:33,260 +هذا المركب ممكن أسميه أنا باستعمال الـ dihydro و + +346 +00:32:33,260 --> 00:32:39,640 +أحط النهاية on في النهاية هذا by role طلعوا معايا + +347 +00:32:39,640 --> 00:32:46,080 +by role ولا لأ على موقع اتنين عنده on على موقع + +348 +00:32:46,080 --> 00:32:52,760 +واحد مشبع إذا قلت one edge الآن ايش عندي كمان مواقع + +349 +00:32:52,760 --> 00:32:55,460 +باعتبارها مشبعة يعني بمعنى ما فيش فيها double bonds + +350 +00:32:55,460 --> 00:33:01,460 +في الداخل اتنين وخمسة double bond ما فيش ولذلك + +351 +00:33:01,460 --> 00:33:06,880 +بيان عندكم two five dihydro one hydroxy one two + +352 +00:33:06,880 --> 00:33:12,540 +three methyl four phenyl كل الاسم بتقدروا تشوفوه، + +353 +00:33:12,540 --> 00:33:20,060 +الآن هذا أحيانا بيكتبوه شوية بشكل مختلف صغير، إذا + +354 +00:33:20,060 --> 00:33:24,640 +شفتوا بشكل مختلف مش كتير يعني تتأثروا، إنه أنا في + +355 +00:33:24,640 --> 00:33:30,040 +النهاية قلت إنه في عندي في الاسم one H وفي عندي + +356 +00:33:30,040 --> 00:33:36,600 +بالاسم تو on وكتبتهم بهذا الشكل مرات كتيرة لما يجي + +357 +00:33:36,600 --> 00:33:42,440 +يكتبوا by role بيحطوا two on وبيدخلوا بين جثين الـ + +358 +00:33:42,440 --> 00:33:48,240 +one H يعني في نهاية ما غيرت أنه في عندي one H ولا + +359 +00:33:49,350 --> 00:33:54,830 +تو اون لكن طريقة الكتابة أن أنا أكتب اتنين أو + +360 +00:33:54,830 --> 00:34:00,430 +وبين جثين أحدد موقع الاتش المشبع وهذا الحقيقة + +361 +00:34:00,430 --> 00:34:06,010 +نظام حديث مستعمل كتير أن أنا لما يكون عنده موقع + +362 +00:34:06,010 --> 00:34:10,450 +مشبع مع الـ om بأكتب مثلا two own أو three own + +363 +00:34:10,450 --> 00:34:15,390 +وبين جثين بحط الموقع المشبع ولذلك هذا المركب مثلا + +364 +00:34:15,390 --> 00:34:22,780 +لما بدي أجي أسميه one, two, three, four, five, six + +365 +00:34:22,780 --> 00:34:31,340 +هتلاحظوا ايش مكتوب بيرازين two on الآن هذا أدى إلى + +366 +00:34:31,340 --> 00:34:36,880 +موقع مشبع شو هو الموقع المشبع three H فهتلاحظوا + +367 +00:34:36,880 --> 00:34:43,870 +مرات بيكتب بيرازين two three H on لاحظوا اللي اسمه + +368 +00:34:43,870 --> 00:34:48,150 +هان اعتبر أنه عنده بس موقع مشبع رفض أنه يعتبر + +369 +00:34:48,150 --> 00:34:53,610 +الـ CW.O موقع مشبع ناس تانيين بيقولوا لأ الـ CW.O + +370 +00:34:53,610 --> 00:34:58,650 +موقع مشبع وهذا الكلام اللي موجود هان هذا الآن + +371 +00:34:58,650 --> 00:35:03,710 +بتظهر مناطق خلافية وجيدة في هذه المرحلة جيدة في + +372 +00:35:03,710 --> 00:35:07,110 +هذه المرحلة تشوف الدنيا على حقيقتها يعني في مناطق + +373 +00:35:07,110 --> 00:35:13,600 +لما تقرأوا بين مؤلف ومؤلف على نفس المركب هتلاحظوا + +374 +00:35:13,600 --> 00:35:18,600 +فيه عندكم نوع من ايش نوع من الاختلاف هي هنا طلع + +375 +00:35:18,600 --> 00:35:24,500 +ليه three H وخلّى two on أن أكتب three H وبعدين + +376 +00:35:24,500 --> 00:35:29,180 +two on ولا أكتب two on وبين قصير أحط three H + +377 +00:35:29,180 --> 00:35:34,480 +بتشوفوا النظامين الشغلتين هتشوفوهم يعني أنا في + +378 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"probability": 0.9539388020833334}, {"start": 1201.42, "end": 1203.66, "word": " مافيش", "probability": 0.8719075520833334}, {"start": 1203.66, "end": 1203.9, "word": " في", "probability": 0.81689453125}, {"start": 1203.9, "end": 1204.6, "word": " N", "probability": 0.2039794921875}, {"start": 1204.6, "end": 1205.1, "word": "-oxide", "probability": 0.727294921875}, {"start": 1205.1, "end": 1205.26, "word": " و", "probability": 0.95751953125}, {"start": 1205.26, "end": 1205.84, "word": " dimethyl", "probability": 0.722412109375}, {"start": 1205.84, "end": 1206.88, "word": " سماه", "probability": 0.67626953125}, {"start": 1206.88, "end": 1207.64, "word": " delta", "probability": 0.84033203125}, {"start": 1207.64, "end": 1208.34, "word": " two", "probability": 0.9453125}, {"start": 1208.34, "end": 1209.58, "word": " byroline", "probability": 0.8720703125}, {"start": 1209.58, "end": 1210.14, "word": " لكن", "probability": 0.732421875}, {"start": 1210.14, "end": 1210.42, "word": " لو", 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223301, "start": 2232.07, "end": 2233.01, "text": "القاتل", "tokens": [6027, 4587, 9307, 1211], "avg_logprob": -0.076708984375, "compression_ratio": 0.5714285714285714, "no_speech_prob": 0.0, "words": [{"start": 2232.07, "end": 2233.01, "word": "القاتل", "probability": 0.95751953125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2233.156, "duration_after_vad": 2147.1149999999934} \ No newline at end of file diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/zENVekzcB0Q.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/zENVekzcB0Q.srt new file mode 100644 index 0000000000000000000000000000000000000000..c512ceaab2c24a549f4d79f682ac0bad1c73bb2a --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/zENVekzcB0Q.srt @@ -0,0 +1,1707 @@ +1 +00:00:20,740 --> 00:00:25,960 +بسم الله الرحمن الرحيم في موضوع أمثلة على حلقات + +2 +00:00:25,960 --> 00:00:30,140 +معينة بعد ما تكلمنا عن الحلقات السوداسية أخذنا + +3 +00:00:30,140 --> 00:00:34,520 +البريديل، الكوينولين، الايزوكوينولين، فكرة عن ال + +4 +00:00:34,520 --> 00:00:39,960 +.. ال-Pyrroles in general بننتقل للحلقات الخماسية + +5 +00:00:39,960 --> 00:00:44,760 +طبعا أشهر الحلقات الخماسية ال-Pyrrole والفيوران و + +6 +00:00:44,760 --> 00:00:51,200 +الثيوفين برضه بناخد فكرة مختصرة عنهم. ال-Pyrrole لو + +7 +00:00:51,200 --> 00:00:55,580 +بدنا نبدأ فيه خلّينا نقول نبدأ بأهميته يمكن في + +8 +00:00:55,580 --> 00:01:01,400 +أذهان الكل مرتبط ال-Pyrrole بال-Porphyrin Ring اللي + +9 +00:01:01,400 --> 00:01:04,580 +هي الحلقة اللي موجودة في ال-Hemoglobin واللي بتم + +10 +00:01:04,580 --> 00:01:08,940 +فيها الارتباط مع الحديد وعملية بعد هيك ال + +11 +00:01:08,940 --> 00:01:12,620 +complexation مع ال-oxygen ونقل ال-oxygen كل هذا + +12 +00:01:12,620 --> 00:01:16,420 +الكلام ربما في الكيميا الحيوية وفي ال-Bioin + +13 +00:01:16,420 --> 00:01:21,280 +organic chemistry مر عليكم فهذا بيوضح لأهمية ال-Pyr + +14 +00:01:21,280 --> 00:01:28,400 +role هي جزء مكون أساسي من مكونات ايش؟ الدم ال- + +15 +00:01:28,400 --> 00:01:32,300 +Hemoglobin طبعا موازن ال-Pyrrole في النبات + +16 +00:01:32,950 --> 00:01:36,650 +الكلوروفيل باختلاف طبعا في ال-Substitution + +17 +00:01:36,650 --> 00:01:42,230 +والاختلاف الأشهر في ال-Metal يعني الإنسان ال-Metal + +18 +00:01:42,230 --> 00:01:46,570 +اللي موجود عنده الحديد في النباتات المغنيسيوم + +19 +00:01:48,080 --> 00:01:54,380 +الآن هذا طبعا بيصير يجيب لمواد بتتكسر في الجسم + +20 +00:01:54,380 --> 00:01:58,360 +مثلا ال-Bilirubin ال-Bilirubin هذا مشهور اللي هو + +21 +00:01:58,360 --> 00:02:04,980 +الصفار اللي عادة بتم قياسه وبنقياسه لصفار الكلية + +22 +00:02:04,980 --> 00:02:08,900 +أحيانا بيسموه Hematoidin is the yellow breakdown + +23 +00:02:08,900 --> 00:02:12,480 +product of normal heme catabolism يعني من تكسر + +24 +00:02:12,480 --> 00:02:18,520 +الدم بيطلع اللي هي مادة ال-Bilirubin هذه أو الصفار + +25 +00:02:18,520 --> 00:02:22,180 +caused by the body clearance of aged red blood + +26 +00:02:22,180 --> 00:02:28,500 +cells يعني كل ما الخلايا الدموية قدمت تعرفوا الدم + +27 +00:02:28,500 --> 00:02:32,960 +والخلايا أشمالها في حالة التجدد فالحالة الخلايا + +28 +00:02:32,960 --> 00:02:37,050 +القديمة اللي هي بنسميها ال-Aged cells يعني الكبيرة + +29 +00:02:37,050 --> 00:02:42,130 +بتتغير الآن لما بتتغير بدا تتكسر من نواتج تكسرها + +30 +00:02:42,130 --> 00:02:46,810 +البلوروبين فالبلوروبين موجود في ال-Principle + +31 +00:02:46,810 --> 00:02:53,560 +الحلقات اللي موجودة في ايش؟ في ال-Porphyrin Ring من + +32 +00:02:53,560 --> 00:02:58,800 +المركبات المشهورة أيضا ال-Vitamin B12 اللي هو + +33 +00:02:58,800 --> 00:03:03,960 +Cobalamin عادة ممكن نسميه اللي هو فيه ال-Cobalt + +34 +00:03:03,960 --> 00:03:09,460 +وفيه برضه حلقات ال-Pyrrole Water soluble vitamin + +35 +00:03:09,460 --> 00:03:15,580 +وله يعني وظيفة أساسية في ال-Brain وفي ال-Nervous + +36 +00:03:15,580 --> 00:03:21,170 +system لابد يكون موجود. مش موضوعنا طبعا نحو ال + +37 +00:03:21,170 --> 00:03:26,930 +Biochemistry في مركبات بسيطة برضه فيها ال-Pyrrole + +38 +00:03:26,930 --> 00:03:32,170 +يعني هذا المركب أربعة هو عبارة عن Insect Pheromone + +39 +00:03:32,170 --> 00:03:36,370 +بتعرفوا ال-Pheromones اللي هي المواد اللي بتفرزها + +40 +00:03:36,370 --> 00:03:41,630 +الحشرات وبتكون من خلالها التواصل بشكل أساسي أكثر + +41 +00:03:41,630 --> 00:03:47,590 +شيء اللي هو التواصل الجنسي يعني لما بتكون الحشرات + +42 +00:03:47,590 --> 00:03:51,730 +في الحقول مش زي البشر الناس عارفة بعض لأن الحشرات + +43 +00:03:52,130 --> 00:03:58,410 +يعني المسافات واسعة كيف بدو يصير التكاثر عند + +44 +00:03:58,410 --> 00:04:01,950 +الحشرات كيف بدو الذكور والإناث يعرفوا بعض ففي + +45 +00:04:01,950 --> 00:04:05,690 +النهاية أحد الأصناف الذكور أو الإناث بيفرز كميات + +46 +00:04:05,690 --> 00:04:11,130 +بسيطة جدا من مواد شو بنسميها ال-Pheromones لأن هذه + +47 +00:04:11,130 --> 00:04:15,550 +المواد بتكون جاذبة للجنس الآخر لما تعلموا العلماء + +48 +00:04:15,550 --> 00:04:20,530 +عرفوا ال-Pheromones بالضبط وعرفوا تحضيرها استفادوا + +49 +00:04:20,530 --> 00:04:25,760 +منها بإيش؟ استفادوا منها بالمكافحة البيولوجية + +50 +00:04:25,760 --> 00:04:30,500 +للحشرات. استفادوا منها بالمكافحة البيولوجية للحشرات + +51 +00:04:30,500 --> 00:04:35,880 +كيف؟ أنه أنا لو بعرف مثلا حشرة دودة القطن على سبيل + +52 +00:04:35,880 --> 00:04:40,780 +المثال أن الآنثى بتفرز فيرومون معين وهذا الفيرومون + +53 +00:04:40,780 --> 00:04:45,920 +بيخلي الذكور ييجوا باتجاه الفيرومون حضروا الفيرومون + +54 +00:04:45,920 --> 00:04:48,800 +في المختبر رأيك مركب؟ ممكن أحضره مثلا أنا في + +55 +00:04:48,800 --> 00:04:52,400 +المختبر، حضروه في المختبر وصاروا يبيعوه + +56 +00:04:52,400 --> 00:04:58,280 +للمزارعين، صاروا يبيعوه للمزارعين أجيبوا مثلا زي + +57 +00:04:58,280 --> 00:05:03,380 +عصا بهذا الشكل وحطوا عليها الفيرومون مع سمك + +58 +00:05:03,380 --> 00:05:08,620 +يحطوه في الحقيقة الآن كل الحشرات عادة بتتجذب هنا + +59 +00:05:08,620 --> 00:05:11,500 +على الفيرومون فمجرد ما بتيجي على هذا الفيرومون + +60 +00:05:11,500 --> 00:05:17,640 +بتلاقوها بتلتصق في العصا اللي فيها سمك مخلوق مع + +61 +00:05:17,640 --> 00:05:23,140 +نسبة من الـPheromone فهم إذا أبادوا أحد الجنسين + +62 +00:05:23,140 --> 00:05:30,650 +معنى ذلك قضوا على ايش؟ على الحشرة بالمجمل طبعا + +63 +00:05:30,650 --> 00:05:35,410 +البرولين هذا Amino Acid هو ال-Amino Acid ال-Cyclic + +64 +00:05:35,410 --> 00:05:39,790 +المشهور اللي اسمه برولين ومهم في ال-Biochemistry + +65 +00:05:39,790 --> 00:05:45,790 +لأنه عادة ال-Turns بتصير من عنده في ال... لما ناخد + +66 +00:05:45,790 --> 00:05:49,030 +ال-Protein Structure ونقول أن ال-Protein Structure + +67 +00:05:49,030 --> 00:05:53,070 +بيصير Globular وبيصير Turn من وين بتصير ال-Turns؟ + +68 +00:05:53,260 --> 00:05:57,400 +من عند البرولين لأنه لما بيعمل البروتين بيبطل فيه + +69 +00:05:57,400 --> 00:06:00,860 +هيدروجين فمنطقته مش فيه هيدروجين بوند + +70 +00:06:00,860 --> 00:06:05,520 +النيكوتين ربما تكلمنا عنه لما حكينا عن البريدين + +71 +00:06:05,520 --> 00:06:11,020 +وبنفس الوقت هو عبارة عن بريدين وبيروليدين + +72 +00:06:11,820 --> 00:06:16,420 +وموجودين على موقع تلاتة على البريدين فهو في + +73 +00:06:16,420 --> 00:06:22,460 +النهاية هجين من البريدين ومن البيروليدين هذه كل + +74 +00:06:22,460 --> 00:06:26,580 +المركبات هي عبارة عن مركبات في الطبيعة في الحياة + +75 +00:06:26,580 --> 00:06:29,720 +في جسم الإنسان فيها بيرول ولذلك احنا بنقول أن ال + +76 +00:06:29,720 --> 00:06:38,660 +بيرول له أهمية خاصة مميزة الآن لو اجينا لتحضير ال- + +77 +00:06:38,660 --> 00:06:44,080 +Pyrrole في عندنا ال-Knorr Synthesis شو هو ال- + +78 +00:06:44,080 --> 00:06:49,200 +Knorr Synthesis؟ الأساس لـ Knorr Synthesis كان + +79 +00:06:49,200 --> 00:06:53,880 +بيستعمل Two Equivalents من ال-Ethylacetoacetate + +80 +00:06:53,880 --> 00:06:58,380 +واحد بيحوله إلى أوكسيم بعدين بيدوبه في Acetic + +81 +00:06:58,380 --> 00:07:02,080 +ال-Acetic من خلال أنه يدوب في Acetic ال-Acetic أسيد + +82 +00:07:02,080 --> 00:07:05,320 +مع Sodium Nitrite بيصير أوكسيم بيعمل Reduction + +83 +00:07:05,320 --> 00:07:09,480 +للأوكسيم لأمين وبعدين بتفعل مع الجزء الثاني هذا + +84 +00:07:09,480 --> 00:07:14,720 +الكلام وصفي لو بدنا نشوف الكلام زي ما اتفقنا احنا + +85 +00:07:14,720 --> 00:07:19,140 +كم Equivalent بدي من ال-Ethyl Acetoacetate اتنين + +86 +00:07:19,140 --> 00:07:25,460 +الآن هاي واحد منهم هذا Ethyl Acetoacetate لو أتيت + +87 +00:07:25,460 --> 00:07:30,780 +فعلته مع ال-Sodium Nitrate في وجود ال-Acetic Acid + +88 +00:07:30,780 --> 00:07:34,580 +ال-Sodium Nitrate في وجود ال-Acetic Acid على ال + +89 +00:07:34,580 --> 00:07:39,800 +CH2 اللي موجودة هنا بيعمل أوكسيم يمكن هذا يكون + +90 +00:07:39,800 --> 00:07:44,300 +بالنسبة لكم شوية تفاعل غريب لأن انتم متعودين على + +91 +00:07:44,300 --> 00:07:51,670 +الأوكسيم من C Double Bond O مع الهيدروكسيل أمين يعني + +92 +00:07:51,670 --> 00:07:58,510 +هذا الأوكسيم اللي أنتم بتعرفوه لكن ربما ما مر + +93 +00:07:58,510 --> 00:08:06,730 +معكم أن ال-CH2 بتعمل أوكسيم ال-CH2 ال-Activated مع + +94 +00:08:06,730 --> 00:08:10,530 +ال-Sodium Nitrite وال-Acetic Acid بتعمل أوكسيم + +95 +00:08:11,110 --> 00:08:14,830 +خلّينا الآن ناخذها as such أنها بتعمل أوكسيم + +96 +00:08:14,830 --> 00:08:19,910 +التفاعل قديم تقريبا من 1874 وتفاصيله أنا + +97 +00:08:19,910 --> 00:08:26,430 +جبتلكم إياه حتى ما يضل غريب عليكم بس الآن نقبل أن + +98 +00:08:26,430 --> 00:08:32,990 +هذا الجزء الأول أنا عملت ايش؟ أوكسيم. الأوكسيم بال- + +99 +00:08:32,990 --> 00:08:37,420 +Reduction بيصير أمين هذه سهلة Reduction of Oximes + +100 +00:08:37,420 --> 00:08:40,880 +بتعطينا Amines هذه مشهورة أن ال-Oximes بال- + +101 +00:08:40,880 --> 00:08:47,000 +Reduction بتصير Amines الآن بجيب الجزء الثاني من + +102 +00:08:47,000 --> 00:08:52,020 +الآخر أسيد وأسيد يعني لاحظوا هذا كان ايش؟ الجزء + +103 +00:08:52,020 --> 00:08:56,540 +الأول صار Oxygen وصار Amine إذا كم جزء أنا + +104 +00:08:56,540 --> 00:09:03,960 +استعملت من ال-Ethyl Acetoacetate جزيئين ودخلت ال- + +105 +00:09:03,960 --> 00:09:08,600 +NH2 من خلال أنه عملت أوكسيم وعملت Reduction إذا + +106 +00:09:08,600 --> 00:09:13,100 +وصلنا لهذه المرحلة صار الأمر سهل لأن هذه عندي ال- + +107 +00:09:13,100 --> 00:09:17,220 +Nucleophile وهذه عندي هنا ال-Nucleophile طبعا في + +108 +00:09:17,220 --> 00:09:22,200 +ال-Conditions تبع التفاعل هذه أنا فيها عندي موجب in + +109 +00:09:22,200 --> 00:09:26,480 +Principle وموجب مش ضايقني نكمل ال-Cyclization + +110 +00:09:26,480 --> 00:09:31,260 +هنا بيصير C Double Bond N إيمين إنامين وهذه هتسكر + +111 +00:09:31,260 --> 00:09:37,100 +OH مع H تعمل Elimination لاحظوا أن هذا التفاعل + +112 +00:09:37,100 --> 00:09:43,060 +استعمل Two Equivalents من ال-Ethyl Acetoacetate + +113 +00:09:43,060 --> 00:09:47,590 +اللي هي لو أنا أتيت أطلع اللي في أطراف المثلو ال- + +114 +00:09:47,590 --> 00:09:50,330 +Ester Group هاي One Equivalent وهاي Two + +115 +00:09:50,330 --> 00:09:53,990 +Equivalents اجوا متعاكسين ولذلك بطريقة أو بأخرى + +116 +00:09:53,990 --> 00:09:58,370 +فيه ال-Symmetry يعني هاي... هاي ال-Ethyl Aceto + +117 +00:09:58,370 --> 00:10:02,090 +acetate وهاي ال-Ethyl Acetoacetate واتجت ال- + +118 +00:10:02,090 --> 00:10:07,250 +Nitrogen زيادة عليهم من وين؟ من ال-Oxime اللي + +119 +00:10:07,250 --> 00:10:13,410 +عملناله Reduction ل... للأمين فهو فعلا Two + +120 +00:10:13,410 --> 00:10:16,350 +Equivalents من ال-Ethyl Acetoacetate هاي شفناهم + +121 +00:10:16,350 --> 00:10:21,810 +كيف اجوا وكيف عملوا الجزء مع ال-Nitrogen اللي + +122 +00:10:21,810 --> 00:10:25,290 +اجت من الأوكسيم هذا اللي بنسميه Knorr Synthesis + +123 +00:10:25,290 --> 00:10:31,390 +طبعا ال-Nitrogen of ألفا ال-Carbon Atom اللي هي + +124 +00:10:31,390 --> 00:10:35,710 +هذه ال-Carbon ال-CH2 نعملها نيتروزو نفاعلها من + +125 +00:10:35,710 --> 00:10:40,690 +نيتروزو ونيتروزو أخد الأوكسيم توتمر منه هذا ال- + +126 +00:10:40,690 --> 00:10:46,690 +Nitrosation مشهور تفاعل أول من عمله واكتشفه + +127 +00:10:46,690 --> 00:10:55,330 +Victor Meyer في ال-1873 و1874 يعني التفاعل قديم + +128 +00:10:55,330 --> 00:11:02,260 +تفاصيله موجود هنا ككلام وموجود هناك معادلات بدي + +129 +00:11:02,260 --> 00:11:06,080 +أمشي عليها بسرعة لأن هي General Organic Chemistry + +130 +00:11:06,080 --> 00:11:10,520 +لكن الفكرة أنه احنا لما نبدأ بال-Sodium Nitrite + +131 +00:11:10,520 --> 00:11:17,240 +بال-Acetic Acid بنعمل Protonation فصار عندي Nitrous + +132 +00:11:17,240 --> 00:11:21,140 +Acid مع Sodium Acetate كمان Protonation صار عندي + +133 +00:11:21,140 --> 00:11:28,270 +الأيون الموجب هذا الأيون الموجب بيفقد المية فبيصير + +134 +00:11:28,270 --> 00:11:32,730 +عنده ال-Nitroso Group يعني هذا لما يفقد المية + +135 +00:11:32,730 --> 00:11:38,990 +بيصير عنده ال-N O Positive الآن لو أتيت واتطلعت + +136 +00:11:38,990 --> 00:11:44,390 +على هذا الجزئية ال-Ethyl Acetoacetate أنا لسه مخليه + +137 +00:11:44,390 --> 00:11:51,140 +أرتاح ال-Ethyl Acetoacetate أخذ منه الآنول أخذ منه + +138 +00:11:51,140 --> 00:11:58,480 +الأنول Form وفاءله مع النيتروزو فهدد الالكترونات + +139 +00:11:58,480 --> 00:12:03,620 +بهذا الشكل بهذا الشكل بتتحرك فالدبل بوند + +140 +00:12:03,620 --> 00:12:08,540 +هتهاجم على النيتروجين الموجب هيصير عندي هذا لو عملت له + + + +141 +00:12:08,540 --> 00:12:12,940 +tautomerism + +142 +00:12:12,940 --> 00:12:21,910 +هيصير عندي OH طبعا هيكون زائد ايش في النهاية ال + +143 +00:12:21,910 --> 00:12:26,630 +acetic acid يعني هيفقد لما هذا التفاعل تم في + +144 +00:12:26,630 --> 00:12:32,270 +النهاية هيفقد ايش H مع ال OAc يعني لاحظوا أن هذا + +145 +00:12:32,270 --> 00:12:37,030 +التفاعل كله هذا التفاعل كله أخذ من هنا ايش ال + +146 +00:12:37,030 --> 00:12:43,610 +nitrogen لكن فقد أيضًا H H مع ال OAc + +147 +00:12:46,110 --> 00:12:51,390 +أسيتيك أسيد و اجت ال nitrous هنا و اللي كان هتحس لو + +148 +00:12:51,390 --> 00:12:56,430 +نفذته بهدوء أنه في H فقدت ليا هتفقد H و هتروح + +149 +00:12:56,430 --> 00:13:01,150 +مع ايش مع الايون السالب اللي هنا على شكل ايه أسيتيك + +150 +00:13:01,150 --> 00:13:05,410 +أسيد واضح يعني هتفقد H و هتروح مع الايون السالب + +151 +00:13:05,410 --> 00:13:10,630 +واضح ليش؟ لأن أنتم لو طلعتوا على هذا كمحصلة هذا + +152 +00:13:10,630 --> 00:13:15,870 +كمحصلة كم H موجودة فيه الوحدة هذا كان محصلة كان + +153 +00:13:15,870 --> 00:13:20,750 +فيها نقاش كان فيها نقاش يعني في نقاش فقدت هذه ال + +154 +00:13:20,750 --> 00:13:25,770 +نقاش اللي فقدت وين راحت؟ مع ال acetic واضح على أي + +155 +00:13:25,770 --> 00:13:31,690 +حال هذا شكل عام حتى ما تستغربوش هذا التفاعل لكن في + +156 +00:13:31,690 --> 00:13:35,770 +شكل عام ال activated hydrogen atom مع ال sodium + +157 +00:13:35,770 --> 00:13:41,930 +nitrate بتصير ايش؟ oxime هذا تفاعل قديم من ال 1800 + +158 +00:13:42,920 --> 00:13:47,860 +واضح؟ ال CH2 ال activated جامب إيستر و جامب كيتون و + +159 +00:13:47,860 --> 00:13:54,880 +جامب نيترالز و جامب نيترو شغل كثير موجود عليها و + +160 +00:13:54,880 --> 00:14:00,060 +كله بندرج تحت المسمى العام اللي هو Nitrosation of + +161 +00:14:00,060 --> 00:14:05,510 +Aliphatic Carbon Atoms بتعمل إيش عنده؟ oxime الآن + +162 +00:14:05,510 --> 00:14:10,370 +إذا صار عند الأكزيم بعد هيك ال reduction سهل و + +163 +00:14:10,370 --> 00:14:13,970 +استكمال التفاعل و فهمه بتكون عملية ايش سهلة يعني و + +164 +00:14:13,970 --> 00:14:18,450 +ربما أصعب شيء هنا للي بيكون بعرفش إنها CH2 بتعمل + +165 +00:14:18,450 --> 00:14:22,250 +أكزيم مع ال sodium nitrite في ال acetic acid هذا + +166 +00:14:22,250 --> 00:14:25,830 +اللي احنا ذكرنا له تفاصيله إنما ال reduction و + +167 +00:14:25,830 --> 00:14:28,170 +بعدين هنا ال nucleophile ال electrophile ال + +168 +00:14:28,170 --> 00:14:31,110 +nucleophile كل هذا أمر بسيط + +169 +00:14:32,980 --> 00:14:36,460 +التحضير الثاني بالك Nor Synthesis of Pyrrole هذا + +170 +00:14:36,460 --> 00:14:40,100 +بيعتمد أن احنا نستعمل one four-dicarbonyl compound + +171 +00:14:40,100 --> 00:14:45,280 +one two three four الآن مع ال ammonia مع ال + +172 +00:14:45,280 --> 00:14:49,560 +ammonia أو amine derivative هيصير C double bond N + +173 +00:14:49,560 --> 00:14:54,960 +والآن مرة ثانية تسكل على ال oxygen فبصير Pyrrole ف + +174 +00:14:54,960 --> 00:15:00,420 +eight and ten C double bond O على موقع 14 مع ال + +175 +00:15:00,420 --> 00:15:05,680 +nitrogen شو هيعطوني؟ Pyrrole الآن هذا الكلام بيذكركوا + +176 +00:15:05,680 --> 00:15:10,500 +بإيش؟ + +177 +00:15:10,500 --> 00:15:15,420 +أن نيتروجين مع باي كربونيل كومباوند هانا قاعدة + +178 +00:15:15,420 --> 00:15:22,080 +بتعطي بيرول و هذا ايش اسمه؟ بالكنورد سينثيسيس of + +179 +00:15:22,080 --> 00:15:29,760 +Pyrrole ال Furan هناخد التنتين هدولة باسد ونخلي + +180 +00:15:29,760 --> 00:15:35,950 +أكسجين يتسكر عادة صحو ال Thiophene هناخد التنتين هدولة + +181 +00:15:35,950 --> 00:15:39,870 +مع سلفة ونخلي واحدة تسكر على التانية يعني من ال + +182 +00:15:39,870 --> 00:15:43,570 +one four-dicarbonyl compound أنا هحضر ال Pyrrole من + +183 +00:15:43,570 --> 00:15:48,430 +خلاله واتفاعل مع ال nitrogen هحضر ال Furan و هحضر + +184 +00:15:48,430 --> 00:15:53,570 +كمان ال Thiophene لكن برضه ال die-carbonyl compound مع + +185 +00:15:53,570 --> 00:16:01,880 +ال nitrogen بتذكرني بإيش؟ بال Pyridine الو لو كان عندي + +186 +00:16:01,880 --> 00:16:06,480 +one-five-dicarbonyl compound كنت أحصل على Pyridine و + +187 +00:16:06,480 --> 00:16:11,680 +كان ايش اسم التفاعل؟ لا ارجعوا عليك ارجعوا على + +188 +00:16:11,680 --> 00:16:16,760 +ال Pyridine لما كان عندي one-five-dicarbonyl compound + +189 +00:16:16,760 --> 00:16:20,560 +عادي مكتوب reaction of ammonia أزاق ال one-five + +190 +00:16:20,560 --> 00:16:23,020 +-dicarbonyl one-five-dicarbonyl طيب بالكنور + +191 +00:16:23,020 --> 00:16:30,710 +synthesis of Pyridine ما تسمش بالكنور؟ واضح؟ فال 14 + +192 +00:16:30,710 --> 00:16:38,070 +بيعطو Pyrrole ال 15 بيعطو Pyridine و زي ما قلنا أن + +193 +00:16:38,070 --> 00:16:43,510 +من ال 14 dicarbonyl compound بيمكن احضر ال Pyrrole + +194 +00:16:43,510 --> 00:16:48,550 +و ال Furan و ال Thiophene و مرة جيبنا سؤال starting + +195 +00:16:48,550 --> 00:16:53,350 +from 14 dicarbonyl compound how can you prepare Pyrrole + +196 +00:16:53,350 --> 00:16:57,010 +, Furan, and Thiophene مع الأمير بنحضر إيش؟ + +197 +00:17:00,020 --> 00:17:05,260 +الآن لو اجينا ل synthesis ثاني لل Pyrrole hence Pyrrole + +198 +00:17:05,260 --> 00:17:11,260 +synthesis ال Hantzsch Pyrrole synthesis بيشبه + +199 +00:17:11,260 --> 00:17:17,620 +الفيسبينري Furan synthesis بيشبه الفيسبينري Furan + +200 +00:17:17,620 --> 00:17:21,620 +synthesis خلينا نقول كيف بيشبه الفيسبينري Furan + +201 +00:17:21,620 --> 00:17:27,010 +synthesis احنا لو أخذنا هذا البيتا كيتو إيستر البيتا + +202 +00:17:27,010 --> 00:17:35,310 +كيتو إيستر البيتا كيتو إيستر البيتا كيتو إيستر + +203 +00:17:35,310 --> 00:17:36,510 +البيتا كيتو إيستر البيتا كيتو إيستر البيتا كيتو + +204 +00:17:36,510 --> 00:17:41,610 +إيستر البيتا كيتو إيستر البيتا كيتو إيستر البيتا + +205 +00:17:41,610 --> 00:17:41,950 +كيتو إيستر البيتا كيتو إيستر البيتا كيتو إيستر + +206 +00:17:41,950 --> 00:17:43,390 +البيتا كيتو إيستر البيتا كيتو إيستر البيتا كيتو + +207 +00:17:43,390 --> 00:17:44,390 +إيستر البيتا كيتو إيستر البيتا كيتو إيستر البيتا + +208 +00:17:44,390 --> 00:17:49,730 +البيبيتا كيتو إيستر زائد ألفا هالو كيتون هدولة + +209 +00:17:49,730 --> 00:17:54,830 +اتنين بيعطوني Furan وهذا ال synthesis هو Hantzsch + +210 +00:17:54,830 --> 00:18:00,630 +بيناري Furan synthesis أخذنا تفصيله Hantzsch بيناري + +211 +00:18:00,630 --> 00:18:06,170 +Furan synthesis الآن لو خلطنا معهم أمونيا بيصير + +212 +00:18:06,170 --> 00:18:11,350 +يعطيني إيش؟ Pyrrole يعني بيتا كيتو إيستر ألفا هالو + +213 +00:18:11,350 --> 00:18:18,090 +كيتون و Ammonia بيصير يعطيني عفوا Pyrrole الآن في + +214 +00:18:18,090 --> 00:18:22,610 +النهاية اللي خلط التلاتة ما بضمنش أن كل مرة في + +215 +00:18:22,610 --> 00:18:25,050 +الأول بده تتفاعل ال ammonia زي ما هنشوف في + +216 +00:18:25,050 --> 00:18:30,790 +التفاصيل و بعدين يكتمل التفاعل و بالتالي ممكن بعض + +217 +00:18:30,790 --> 00:18:35,990 +هذه الجزيات معادي تعطي إيش؟ Furan و لذلك لو اجاكم + +218 +00:18:35,990 --> 00:18:44,020 +سؤال علّل أن في هذا ال synthesis بيطلع عندي Furan + +219 +00:18:44,020 --> 00:18:49,140 +as a by-product بدنا نكون إيش؟ فاهمين طب على وقتنا + +220 +00:18:49,140 --> 00:18:54,660 +نفصله هذا ال synthesis كيف بيطلع ال Pyrrole احنا + +221 +00:18:54,660 --> 00:18:59,300 +أخذنا كيف بيطلع ال Furan و ممكن نرجعله كيف بيطلع + +222 +00:18:59,300 --> 00:19:05,060 +ال Pyrrole ال C double bond O مع ال NH2 هتعمل إمين + +223 +00:19:05,060 --> 00:19:09,780 +إينامين إينامين هي عملت الإينامين الآن لما بدأت إيش + +224 +00:19:09,780 --> 00:19:17,260 +تتفاعل مع الـ α-هالو-كيتون لما تتفاعل مع الـ α-هالو + +225 +00:19:17,260 --> 00:19:22,300 +-كيتون ممكن تتخيل بهذا الشكل وهذه تتحل محل + +226 +00:19:22,300 --> 00:19:26,320 +الـ Cl الـ another substitution reaction، هذه + +227 +00:19:26,320 --> 00:19:29,780 +نعملت الـ bond، دل عندة نيتروجين مع السيطرة بالـ + +228 +00:19:29,780 --> 00:19:35,580 +bond O هتعمل ال N مش هتقدر تعمل C double bond N + +229 +00:19:35,580 --> 00:19:40,100 +يعني هتعمل N واحدة لأن مثلًا هتعمل R حتى لو عملت C + +230 +00:19:40,100 --> 00:19:45,060 +double bond N في حال أن هذه كانت Hydrogen إمين + +231 +00:19:45,060 --> 00:19:54,140 +هتصير إيش؟ إينامين واضحة الفكرة؟ الآن في التفاعل اللي + +232 +00:19:54,140 --> 00:19:57,380 +كان عندنا .. في التفاعل اللي كان عندنا اللي هو تبع + +233 +00:19:57,380 --> 00:20:02,220 +ال Furan، بس اللي كنا نسويه أنه إحنا مش محاولين + +234 +00:20:02,220 --> 00:20:11,080 +هذه اه ما كناش محاولين هذه لـ ل nitrogen كانت + +235 +00:20:11,080 --> 00:20:15,720 +double bond؟ اه و بالتالي كان أتم عند الإغلاق + +236 +00:20:15,720 --> 00:20:20,220 +عليها بنرجع ل Hantzsch بين refluent synthesis + +237 +00:20:20,220 --> 00:20:25,740 +بالتفصيل أخذتو أنتم كيف كان نبدأ من هنا نكون ال + +238 +00:20:25,740 --> 00:20:26,100 +ion + +239 +00:20:38,980 --> 00:20:45,510 +الخلاصة أن هدولة البيتا كيتو إيستر ألفا هالو كيتو + +240 +00:20:45,510 --> 00:20:50,610 +لحالهم بيعطوني Furan لو حطيت معهم أمونيا صار هذا + +241 +00:20:50,610 --> 00:20:55,710 +التفاعل في البداية أمين إينامين وبعدين عملنا هذا + +242 +00:20:55,710 --> 00:21:02,260 +التفاعل كنيوكليوفايل إلكتروفايل بيعطيني إيش؟ Pyrrole + +243 +00:21:02,260 --> 00:21:06,860 +لو اجيت أنا لل reactions of Pyrrole ال reactions ال + +244 +00:21:06,860 --> 00:21:11,820 +reactions of Pyrrole في عندي ممكن يتم reactions على + +245 +00:21:11,820 --> 00:21:16,080 +ال nitrogen و ممكن يتم في شكل أساسي electrophilic + +246 +00:21:16,080 --> 00:21:18,300 +substitution على ال ring يعني بدي أصنف ال + +247 +00:21:18,300 --> 00:21:25,320 +reactions نوعين على ال nitrogen و على الآن ربما + +248 +00:21:25,320 --> 00:21:31,000 +كلکم تتذكرون كلمة أن على ال nitrogen هذا ال + +249 +00:21:31,000 --> 00:21:36,660 +pair اللي موجود على ال Pyrrole نشيط أن يتفاعل مع + +250 +00:21:36,660 --> 00:21:41,780 +الخارج ولا لأ؟ ليش؟ لأن هذا جزء من ال aromatic + +251 +00:21:41,780 --> 00:21:45,560 +system طب لما أنا بدي ال nitrogen يتفاعل مع الخارج + +252 +00:21:45,560 --> 00:21:50,710 +بدي اعمل عملية تحضيرية في الأول إيش العملية + +253 +00:21:50,710 --> 00:21:54,210 +التحضيرية اللي بدي أعملها عشان تمت فعل على + +254 +00:21:54,210 --> 00:22:02,310 +الـ Nitrogen a؟ بدي أجي لهذه الـ NH بالمثل أسحب منها + +255 +00:22:02,310 --> 00:22:10,120 +الـ H أخليها N- واجهته بيصير التفاعل من خلال زوجة + +256 +00:22:10,120 --> 00:22:13,520 +الإلكترونات اللي هتتبع الـ minus إذا أنا كخطوة + +257 +00:22:13,520 --> 00:22:17,840 +أولى للتفاعل مع ال nitrogen بعمل ال methylation of + +258 +00:22:17,840 --> 00:22:21,500 +Pyrrole يعني ممكن أفاعل مع ال sodium مع ال potassium + +259 +00:22:21,500 --> 00:22:25,540 +مع ال دمد أو البوتاسامد ب liquid ammonia في كل + +260 +00:22:25,540 --> 00:22:31,160 +الأحوال هدولة هيصحبوا ال hydrogen هيعملولي إيش؟ الـ + +261 +00:22:31,160 --> 00:22:34,640 +minus الأن الأن الـ minus هاي في عند أنا زوج + +262 +00:22:34,640 --> 00:22:38,080 +إلكترونات part of the aromatic system وفي عندي زوج + +263 +00:22:38,080 --> 00:22:46,850 +إلكترونات جاهز إنه يتفاعلواضح؟ هذا زوج الإلكترونات + +264 +00:22:46,850 --> 00:22:50,210 +اللي جاهز أنه يتفاعل هو اللي بعد هيك يتفعل مع الـ + +265 +00:22:50,210 --> 00:22:54,050 +Electrophile ف أنا مش الهدف عندي أن أعمل ال minus و + +266 +00:22:54,050 --> 00:22:58,570 +جمبها K plus يعني Sodium Salt of Pyrrole لا أنا بدي + +267 +00:22:58,570 --> 00:23:03,270 +ال Salt هذا بعد هيك اروح افعله مع ايش؟ مع ال + +268 +00:23:03,270 --> 00:23:06,770 +Electrophile الآن بنفس المنطقة لو عملت Grignard + +269 +00:23:06,770 --> 00:23:11,510 +Reagent برضه هيعندي زوج الإلكترونات الأصلي وهي هذا + +270 +00:23:11,510 --> 00:23:17,190 +الزوج اللي هيكون إيش؟ جاهز أنه يتفاعد بعمل Grignard + +271 +00:23:17,190 --> 00:23:21,930 +reagent على ال nitrogen مع المغنيسيوم بعمل + +272 +00:23:21,930 --> 00:23:26,510 +شبيه بال Grignard reagent MgBr ليش؟ لأن ال Grignard + +273 +00:23:26,510 --> 00:23:31,510 +reagent أساسا على carbon MgBr أنا عملته على إيش؟ على + +274 +00:23:31,510 --> 00:23:36,590 +ال nitrogen مع ال lithium حتى لو كان covalent هو + +275 +00:23:36,590 --> 00:23:40,090 +عند زوجي الإلكترونات اللي هنا لكن في النهاية + +276 +00:23:40,090 --> 00:23:45,320 +هستفيد من ايش أنا؟ زوج الإلكترونات اللي على + +277 +00:23:45,320 --> 00:23:49,920 +الـ Nitrogen الآن هذا زوج الإلكترونات اللي على + +278 +00:23:49,920 --> 00:23:55,280 +الـ Nitrogen بفعله أنا مع الـ Electrophile بيشتغل + +279 +00:23:55,280 --> 00:23:59,140 +كالـ Nucleophile يعني مثلًا لو فعلته مع الـ Methyl + +280 +00:23:59,140 --> 00:24:03,880 +Iodide بيجي بيهاجم و بيحل محل ال Iodine هيعمل + + + +281 +00:24:03,880 --> 00:24:08,130 +Methylation لاحظوا معه لو قلت لكم how can you + +282 +00:24:08,130 --> 00:24:13,450 +prepare الميثيل بيرول و يجي حد قال لي بهذا الشكل + +283 +00:24:13,450 --> 00:24:21,950 +بدي آخذ الـ بيرول مباشرة + +284 +00:24:21,950 --> 00:24:28,410 +مع الميثيل أيودايد مش حيصير فانا بعمل بالصوديوم بخلي + +285 +00:24:28,410 --> 00:24:33,010 +هذه الـ minus و الـ minus مع الـ methyl iodide واضحة + +286 +00:24:33,010 --> 00:24:39,070 +الفكرة إذا صار عندي by role negative ion بعدين + +287 +00:24:39,070 --> 00:24:42,570 +بفعلها هاي كمان مرة مع الـ methyl iodide اللي هو + +288 +00:24:42,570 --> 00:24:46,190 +هذا اللي مع المغنيسيوم الشبيه بالـ Grignard يعني نفس + +289 +00:24:46,190 --> 00:24:49,190 +الشيء عمل Methylation و الـ yield زي ما أنتم + +290 +00:24:49,190 --> 00:24:53,250 +شايفين ايش معها ممتازة كل هذه التفاعلات على أي ذرة + +291 +00:24:54,080 --> 00:24:59,920 +على الـ Nitrogen لكن لابد لها من خطوة تحضيرية هاي هنا + +292 +00:24:59,920 --> 00:25:04,040 +مع الـ Acetyl الـ Acetyl is a nucleophile ولا لأ + +293 +00:25:04,040 --> 00:25:10,220 +CH3C double bond OCl طبعا هيكون التفاعل تفاعل + +294 +00:25:10,220 --> 00:25:15,700 +Substitution تحط لـ Acetyl على الـ Nitrogen الآن هنا + +295 +00:25:15,700 --> 00:25:19,940 +عملت كمان Electrophilic Substitution على الحلقة لكن + +296 +00:25:19,940 --> 00:25:25,390 +هذا التفاعل على الـ Nitrogen واضح؟ هاي مع الـ Benzoyl + +297 +00:25:25,390 --> 00:25:33,110 +بنزويل كلوريد فينيل C double bond O Cl مع السالب + +298 +00:25:33,110 --> 00:25:37,390 +اللي هنا بس عمل على الـ nitrogen ما عملش على الحلقة + +299 +00:25:38,140 --> 00:25:42,360 +واضح يعني هنا تم إبدال عادي عن الـ Nitrogen و لحظة + +300 +00:25:42,360 --> 00:25:45,840 +كمان Electrophilic substitution على الحلقة هنا بس + +301 +00:25:45,840 --> 00:25:51,300 +تم عن الـ Nitrogen في نهاية الكيمياء ايش علم تجريبي يعني + +302 +00:25:51,300 --> 00:25:54,980 +شو أفرجت الـ acid الـ chloride عن الـ benzoyl + +303 +00:25:54,980 --> 00:25:59,060 +chloride لكن مع الـ acid الـ chloride طلع عندي إبدال + +304 +00:25:59,060 --> 00:26:03,080 +على الحلقة Electrophilic substitution مع الـ + +305 +00:26:03,080 --> 00:26:06,120 +benzoyl chloride بس الإبدال تم على الـ nitrogen + +306 +00:26:06,120 --> 00:26:11,310 +الآن النوع الثاني من تفاعلات الـ by role اللي هو الـ + +307 +00:26:11,310 --> 00:26:15,350 +electrophilic substitution عادة الـ electrophilic + +308 +00:26:15,350 --> 00:26:20,710 +substitution يتم على موقعين لو عملنا resonance + +309 +00:26:20,710 --> 00:26:23,330 +structures حتى لو اعتبرنا ان هذا resonance + +310 +00:26:23,330 --> 00:26:27,010 +structure يعني غير محبب اللي فيه الموجب على الـ + +311 +00:26:27,010 --> 00:26:30,090 +nitrogen على موقع اثنين عندي two resonance + +312 +00:26:30,090 --> 00:26:33,910 +structures على موقع ثلاثة عندي one resonance + +313 +00:26:33,910 --> 00:26:37,310 +structure ولذلك الـ substitution بتتم على الـ birol على + +314 +00:26:37,310 --> 00:26:40,970 +موقع اثنين بيضلوا متذكرين انه في الـ electrophilic + +315 +00:26:40,970 --> 00:26:44,950 +substitution بشكل عام الـ birol بتفاعل أسرع من + +316 +00:26:44,950 --> 00:26:49,080 +الفيوران أسرع من الثيوفين كلهم أسرع من البنزين + +317 +00:26:49,080 --> 00:26:54,200 +يعني كل هذه الحلقات أسرع من البنزين طبعا ممكن حد + +318 +00:26:54,200 --> 00:26:57,060 +يقول ليش أسرع من البنزين لأن فيهم في النهاية الـ + +319 +00:26:57,060 --> 00:27:00,240 +electronegative atom بتعطي إلكترونات بزيادة و + +320 +00:27:00,240 --> 00:27:04,280 +التفاعل Electrophilic substitution يعني سالب محب + +321 +00:27:04,280 --> 00:27:10,000 +فهذه الذرات اللي بتعطي إلكترونات زيادة هتزيد سرعة + +322 +00:27:10,000 --> 00:27:15,520 +ايش؟ التفاعل الآن الأمثلة زي ما احنا شايفين كثير + +323 +00:27:15,520 --> 00:27:19,320 +نيتراشن، كلوريناشن، بروميناشن، وويلزمير إذا + +324 +00:27:19,320 --> 00:27:22,640 +متذكّرينه الـ formal group لاحظوا في معظم الحالات على + +325 +00:27:22,640 --> 00:27:26,020 +موقع اثنين، اثنين وخمسة، اثنين، اثنين، اثنين + +326 +00:27:26,020 --> 00:27:29,700 +وخمسة، اثنين وخمسة في مرة يمكن طلع على نسبة ثلاثة + +327 +00:27:29,700 --> 00:27:35,100 +بنسبة يعني عدم فالـ substitution بشكل أساسي بيكون + +328 +00:27:35,100 --> 00:27:38,520 +mono substitution على اثنين مرات بيصير على + +329 +00:27:52,370 --> 00:27:56,190 +البيرول كمان بيعمل + +330 +00:27:57,940 --> 00:28:02,400 +cycloaddition reactions with dichlorocarbine البعض + +331 +00:28:02,400 --> 00:28:05,640 +هييجي يقول من وين الـ dichlorocarbine الناس اللي + +332 +00:28:05,640 --> 00:28:09,340 +أخذوا Reimer-Tiemann reaction اللي هو الـ + +333 +00:28:09,340 --> 00:28:12,200 +chloroform بالايثر في الـ base بيعمل + +334 +00:28:12,200 --> 00:28:17,920 +dichlorocarbine يعني Carbene بهذا الشكل carbon Cl + +335 +00:28:17,920 --> 00:28:23,350 +Cl بهذا الشكل وهذا الـ Carbine لما يجي يتفاعل هنا + +336 +00:28:23,350 --> 00:28:27,770 +يعمل insertion هنا في رابط حول لايش؟لالديهايد + +337 +00:28:27,770 --> 00:28:31,150 +اللي بده يتذكر هذا التفاعل يمكن التفاعل بهذا الشكل + +338 +00:28:31,150 --> 00:28:38,000 +يبدو ايش؟ غريب لكن لو أنتم تذكرتوا التفاعل في الـ + +339 +00:28:38,000 --> 00:28:43,540 +organic اللي هو اسمه Reimer-Tiemann reaction + +340 +00:28:43,540 --> 00:28:47,160 +Reimer-Tiemann reaction هاي كنا على الفينول مع الـ + +341 +00:28:47,160 --> 00:28:51,020 +chloroform بيصير هنا Dichlorocarbine وبعدين بيصير + +342 +00:28:51,020 --> 00:28:53,960 +له reduction للـ aldehyde هاي تفاصيل الـ Reimer + +343 +00:28:53,960 --> 00:28:58,190 +-Tiemann reaction مر عليكم كاملا في وين؟ في الـ + +344 +00:28:58,190 --> 00:29:03,310 +organic synthesis فما في داعي نرجع له تكوين الـ + +345 +00:29:03,310 --> 00:29:07,410 +formal من هذا التفاعل هو مشابه لـ Raymartimer + +346 +00:29:07,410 --> 00:29:12,730 +reaction أمر طبيعي لكن ربما الأمر الغريب انه يجي + +347 +00:29:12,730 --> 00:29:19,070 +يتكون عندكم ايش؟ يتكون عند البيردين لكن إذا أنتم + +348 +00:29:19,070 --> 00:29:22,530 +قلتوا انه في عندكم في النهاية Dichlorocarbine + +349 +00:29:22,530 --> 00:29:28,110 +يعني Carbon مع Chlorine هنا و عملوا Cycloaddition + +350 +00:29:28,110 --> 00:29:34,190 +اكسروا الـ ring من هنا كده ايش صار عندي نيتروجين + +351 +00:29:34,190 --> 00:29:40,780 +كاربون كاربون حاملة CL و ما طلعناش CL عشان هيك تفسير + +352 +00:29:40,780 --> 00:29:45,020 +هذا الـ 3-chloropyridine الـ by-product بتم من + +353 +00:29:45,020 --> 00:29:49,540 +خلال ان انا اقول ان الـ dichlorocarbine عمل cycle + +354 +00:29:49,540 --> 00:29:54,060 +addition على الـ double bond اللي هنا و عمل ring + +355 +00:29:54,060 --> 00:29:58,700 +opening مرات سألنا الطلاب كيف بتفسر انه بهذا + +356 +00:29:58,700 --> 00:30:04,800 +التفاعل طلع عنده 3-chloropyridine بدا اقول cycle + +357 +00:30:04,800 --> 00:30:09,280 +addition of dichlorocarbine followed by Ring + +358 +00:30:09,280 --> 00:30:15,120 +Opening واضح الكلام و كل قصة Dichlorocarbine يعني + +359 +00:30:15,120 --> 00:30:20,760 +قصة Trimer reaction هي تقريبا نفس التفسير مع مركب + +360 +00:30:20,760 --> 00:30:24,880 +ثاني جبنا Dichlorocarbine من مصدر ثاني و بعدين + +361 +00:30:24,880 --> 00:30:29,980 +Ring Opening عملناه و بيوضحوا تماما و طلع برضه 3 + +362 +00:30:29,980 --> 00:30:34,480 +-chloropyridine نفس فكرة الـ Ring Expansion نفس + +363 +00:30:34,480 --> 00:30:40,210 +فكرة الـ Dichlorocarbine اللي بيعمل الـ Chelotropic + +364 +00:30:40,210 --> 00:30:46,990 +Cycloaddition على الـ Double Bond الآن الـ Diels + +365 +00:30:46,990 --> 00:30:50,430 +-Alder Reaction الـ By Rules بشكل عام من أضعف + +366 +00:30:50,430 --> 00:30:53,710 +الحلقات اللي بتعمل الـ Diels-Alder Reaction طبعا + +367 +00:30:53,710 --> 00:30:56,690 +لما بتعمل الـ Diels-Alder Reaction هتعمل بصفتها + +368 +00:30:56,690 --> 00:31:01,730 +ايش؟ Dien يعني هاي جزء الـ Dien اللي فيها، هاي جزء + +369 +00:31:01,730 --> 00:31:04,750 +الـ Dien، لكن في بعض الأمثلة هاي + +370 +00:31:04,750 --> 00:31:07,790 +Ethoxycarbonylbirol + +371 +00:31:07,790 --> 00:31:11,990 +مثلا مع الـ die مثل استيلين، Diecarboxylate يعني + +372 +00:31:11,990 --> 00:31:16,250 +هان استيلين، إذا أنا لما بدا أعمل Diels Alder هنا، + +373 +00:31:16,250 --> 00:31:21,510 +بدا أجي على هذه النقطة وعلى هذا النقطة و أعمل + +374 +00:31:21,510 --> 00:31:26,270 +الحلقة السداسية واضح؟ لاحظوا هاي جزء الـ Pyrrole و ما + +375 +00:31:26,270 --> 00:31:30,990 +زال حامل الـ NCO2 Ethyl و هاي هذا الجزء اللي اجا من + +376 +00:31:30,990 --> 00:31:40,010 +الـ Acetylene هاي جزء الـ Acetylene و هاي جزء الـ + +377 +00:31:40,010 --> 00:31:44,610 +Pyrrole واضح؟ و عملنا حلقة سداسية واحد، اثنين، ثلاثة، + +378 +00:31:44,610 --> 00:31:50,010 +اربعة، خمسة، ستة هذه الحلقة السداسية كاملة؟ واحدة + +379 +00:31:50,010 --> 00:31:55,930 +من الـ Diels Alder واحدة من الـ triple bond فقط بيلزم + +380 +00:31:55,930 --> 00:32:02,010 +ان شيء نكون يعني ان ننفذ هذا الكلام نتعود عليه نرسمه + +381 +00:32:02,010 --> 00:32:07,590 +بجلد رصاص بهدوء عشان الصين عندنا تدريب أيضا الـ by + +382 +00:32:07,590 --> 00:32:11,790 +role ممكن يعمل 2 plus 2 cycle addition يعني هاي by + +383 +00:32:11,790 --> 00:32:18,450 +role مع كيتون في النهاية بتطلع لي هذا المركب طب انا + +384 +00:32:18,450 --> 00:32:22,750 +بدي أفسر كيف اتكون هذا المركب خلينا نفترض ان هو + +385 +00:32:22,750 --> 00:32:27,940 +عمل في الأول 2 plus 2 cycle addition و بعدين هنا + +386 +00:32:27,940 --> 00:32:33,360 +عمل ring opening يعني هذا 2 plus 2 cycle addition + +387 +00:32:33,360 --> 00:32:38,420 +عطاني حلقة رباعية بعد هيك لو حركنا الالكترونات + +388 +00:32:38,420 --> 00:32:43,240 +بشكل معين هيصير عندنا الـ O minus الـ H اللي هنا + +389 +00:32:43,240 --> 00:32:54,960 +هنبدأ من عندها هاي الـ O minus OH واضح؟ يعني هذه الـ + +390 +00:32:54,960 --> 00:32:58,800 +bond هنا صارت double bond وهذه صارت O minus مع الـ + +391 +00:32:58,800 --> 00:32:59,540 +H من هنا + +392 +00:33:03,130 --> 00:33:06,890 +فهذا الـ alcohol اللي اتكون عندنا لو بدنا نقول + +393 +00:33:06,890 --> 00:33:09,850 +explain the formation of this alcohol بدنا نقول ان + +394 +00:33:09,850 --> 00:33:16,390 +هذا تم عبر two plus two cycloaddition بهيك بنكون + +395 +00:33:16,390 --> 00:33:19,730 +أعطينا فكرة عن الـ by role وقلنا انه التفاعلات + +396 +00:33:19,730 --> 00:33:23,230 +الأساسية عن الـ Nitrogen و الـ electrophilic + +397 +00:33:23,230 --> 00:33:28,850 +substitution الـ cycloadditions أمثلة قليلة جدا + +398 +00:33:28,850 --> 00:33:33,990 +محدودة جدا ذكرنا منها مثلَين أما تفاعلاته الأساسية + +399 +00:33:33,990 --> 00:33:41,050 +عن الـ Nitrogen من خلال ايش؟ الايون السالب، عن + +400 +00:33:41,050 --> 00:33:44,550 +الـ Nitrogen من خلال الايون السالب، الـ electrophilic + +401 +00:33:44,550 --> 00:33:49,020 +substitution تبعه على أي مواقع؟ اثنين وخمسة لاحظوا + +402 +00:33:49,020 --> 00:33:52,800 +اللي بده يحس انه القمر مش صعب يفهم بادئ الأساسية + +403 +00:33:52,800 --> 00:33:57,240 +الـ Pyrrole بتفاعل عن الـ Nitrogen من خلال تكوين أيون سالب + +404 +00:33:57,240 --> 00:34:00,620 +في الأول مع معدن بعمل Electrophilic substitution + +405 +00:34:00,620 --> 00:34:05,100 +على مواقع اثنين أو اثنين وخمسة و طبعا بنفسره من + +406 +00:34:05,100 --> 00:34:09,890 +خلال الـ resonance اللي هو بعض الانواع اللي هي Cycle + +407 +00:34:09,890 --> 00:34:13,630 +Addition سواء كان Diels Alder Cycle Addition أو 2 + +408 +00:34:13,630 --> 00:34:17,530 +Plus 2 Cycle Addition لما نروح على الـ furan هنلاحظ + +409 +00:34:17,530 --> 00:34:21,370 +انه الـ furan في Diels Alder أمثلته أكثر كثير كثير + +410 +00:34:21,370 --> 00:34:26,340 +من الـ Pyrrole يعني لو انتم بتكونوا بتفتشوا في الـ + +411 +00:34:26,340 --> 00:34:31,560 +net على Diels Alder مع Furan هتلاقوا عشرات مئات + +412 +00:34:31,560 --> 00:34:34,360 +الأمثلة Diels Alder مع الـ Pyrrole عدد قليل من + +413 +00:34:34,360 --> 00:34:38,440 +الأمثلة لكن بكل الأحوال احنا ما بدناش ياكم تفتشوا على + +414 +00:34:38,440 --> 00:34:44,360 +هدول بدنا ياكم تجيبوا لنا من الـ net أمثلة على تحضير + +415 +00:34:44,360 --> 00:34:49,900 +تحضيرات جديدة لـ quinoline و الـ isoquinoline و الـ + +416 +00:34:49,900 --> 00:34:56,980 +Pyrrole بدناش الـ Pyrrole Quinoline و Isoquinoline و + +417 +00:34:56,980 --> 00:35:01,900 +Pyrrole روحوا على المجلات الجديدة شوفوا طرق جديدة + +418 +00:35:01,900 --> 00:35:04,900 +موجودة في المجلات How can you prepare new + +419 +00:35:04,900 --> 00:35:08,620 +derivatives of quinoline, of Isoquinoline, of + +420 +00:35:08,620 --> 00:35:12,080 +Pyrrole؟ ما بديش انسى أنا ان الـ quinolines يعني هي + +421 +00:35:12,080 --> 00:35:17,950 +مركبات يعني خليني أقول أساسية جداً في علاج + +422 +00:35:17,950 --> 00:35:24,170 +الروماتيزم وغيرها يعني والملاريا بشكل أساسي يعني + +423 +00:35:24,170 --> 00:35:29,270 +لو كتبتوا أنتم antimalarial الأدوية المضادة + +424 +00:35:29,270 --> 00:35:34,370 +للملاريا هيطلع عندكم الـquinolines عائلات كبيرة جداً + +425 +00:35:34,370 --> 00:35:39,510 +للأدوية الـ antimalarial من الـquinolins وبهكذا بننهي + +426 +00:35:39,510 --> 00:35:43,090 +محاضرتنا لليوم وإن شاء الله إلى لقاء آخر diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/zENVekzcB0Q_postprocess.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/zENVekzcB0Q_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..993e42b775405429b9c8dacb73e529f827f7379e --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/zENVekzcB0Q_postprocess.srt @@ -0,0 +1,1704 @@ +1 +00:00:20,740 --> 00:00:25,960 +بسم الله الرحمن الرحيم في موضوع أمثلة على حلقات + +2 +00:00:25,960 --> 00:00:30,140 +معينة بعد ما اتكلمنا عن الحلقات السوداسية أخدنا + +3 +00:00:30,140 --> 00:00:34,520 +البريديل، الكوينولين، الايزوكوينولين، فكرة عن ال + +4 +00:00:34,520 --> 00:00:39,960 +.. ال byrons in general بننتقل للحلقات الخماسية + +5 +00:00:39,960 --> 00:00:44,760 +طبعا أشهر الحلقات الخماسية ال byrol و الفيوران و + +6 +00:00:44,760 --> 00:00:51,200 +الثيوفين برضه بناخد فكرة مختصرة عنهمالـ Birol لو + +7 +00:00:51,200 --> 00:00:55,580 +بدنا نبدأ فيه خلّينا نقول نبدأ بأهميته يمكن في + +8 +00:00:55,580 --> 00:01:01,400 +أذهان الكل مرتبط ال Birol بال Porphyrin Ring اللي + +9 +00:01:01,400 --> 00:01:04,580 +هي الحلقة اللي موجودة في ال Hemoglobin و اللي بتم + +10 +00:01:04,580 --> 00:01:08,940 +فيهاالارتباط مع الحديد و عملية بعد هيك ال + +11 +00:01:08,940 --> 00:01:12,620 +complexation مع ال oxygen و نقل ال oxygen كل هذا + +12 +00:01:12,620 --> 00:01:16,420 +الكلام ربما في الكيميا الحيوية و في ال bio in + +13 +00:01:16,420 --> 00:01:21,280 +organic chemistry مر عليكم فهذا بيوضح لأهمية ال by + +14 +00:01:21,280 --> 00:01:28,400 +role هي جزء مكون أساسي من مكونات ايش الدم ال + +15 +00:01:28,400 --> 00:01:32,300 +hemoglobin طبعا موازن ال by role في النبات + +16 +00:01:32,950 --> 00:01:36,650 +الكلوروفيل باختلاف طبعا في ال substitution + +17 +00:01:36,650 --> 00:01:42,230 +والاختلاف الأشهر في ال metal يعني الإنسان ال metal + +18 +00:01:42,230 --> 00:01:46,570 +اللي موجود عنده الحديد في النباتات المجنيسية + +19 +00:01:48,080 --> 00:01:54,380 +الان هذا طبعا بيصير يجيب لمواد بتتكسر في الجسم + +20 +00:01:54,380 --> 00:01:58,360 +مثلا ال باليروبين ال باليروبين هذا مشهور اللي هو + +21 +00:01:58,360 --> 00:02:04,980 +الصفار اللي عادة بتم قياسه و بنقياسه لصفار الكلية + +22 +00:02:04,980 --> 00:02:08,900 +أحيانا بيسمو hematodein is the yellow breakdown + +23 +00:02:08,900 --> 00:02:12,480 +product of normal heme catabolism يعني من تكسر + +24 +00:02:12,480 --> 00:02:18,520 +الدم بيطلع اللي هي مادة ال باليروبين هذهأو الصفار + +25 +00:02:18,520 --> 00:02:22,180 +caused by the body clearance of aged red blood + +26 +00:02:22,180 --> 00:02:28,500 +cells يعني كل ما الخلايا الدموية قدمت تعرفوا الدم + +27 +00:02:28,500 --> 00:02:32,960 +والخلايا أشمالها في حالة التجدد فالحالة الخلايا + +28 +00:02:32,960 --> 00:02:37,050 +القديمة اللي هي بنسميها ال agedسيلز يعني الكبيرة + +29 +00:02:37,050 --> 00:02:42,130 +بتتغير الان لما بتتغير بدا تتكسر من نواتج تكسرها + +30 +00:02:42,130 --> 00:02:46,810 +البلوروبين فالبلوروبين موجود في ال principle + +31 +00:02:46,810 --> 00:02:53,560 +الحلقات اللي موجودة في إيش؟ في ال porphyrin ringمن + +32 +00:02:53,560 --> 00:02:58,800 +المراكبات المشهورة أيضا ال vitamin B12 اللي هو + +33 +00:02:58,800 --> 00:03:03,960 +cobalamin عادة ممكن نسميه اللي هو فيه ال cobalt + +34 +00:03:03,960 --> 00:03:09,460 +وفيه برضه حلقات ال birol water soluble vitamin + +35 +00:03:09,460 --> 00:03:15,580 +وإله يعني وظيفة أساسية في ال brain وفي ال nervous + +36 +00:03:15,580 --> 00:03:21,170 +system لابد يكون موجود مش موضوعنا طبعاانحو ال + +37 +00:03:21,170 --> 00:03:26,930 +biochemistryفي مركبات بسيطة برضه فيها ال by role + +38 +00:03:26,930 --> 00:03:32,170 +يعني هذا المركب أربعة هو عبارة عن insect pheromone + +39 +00:03:32,170 --> 00:03:36,370 +بتعرفوا ال pheromones اللي هي المواد اللي بتفرزها + +40 +00:03:36,370 --> 00:03:41,630 +الحشرات وبتكن من خلالها التواصل بشكل أساسي أكتر + +41 +00:03:41,630 --> 00:03:47,590 +شيء اللي هو التواصل الجنسي يعني لما بتكون الحشرات + +42 +00:03:47,590 --> 00:03:51,730 +في الحقول مش زي البشر الناس عارفة بعض لإن الحشرات + +43 +00:03:52,130 --> 00:03:58,410 +يعني المسافات واسعة كيف بدو يصير التكاتر عند + +44 +00:03:58,410 --> 00:04:01,950 +الحشرات كيف بدو الذكور والإناث يعرفوا بعض ففي + +45 +00:04:01,950 --> 00:04:05,690 +النهاية أحد الأصناف الذكور أو الإناث بيفرز كميات + +46 +00:04:05,690 --> 00:04:11,130 +بسيطة جدا من مواد شو بنسميها ال pheromones لأن هذه + +47 +00:04:11,130 --> 00:04:15,550 +المواد بتكون جاذبة للجنس الآخر لما اتعلموا العلماء + +48 +00:04:15,550 --> 00:04:20,530 +عرفوا ال pheromones بالظبط وعرفوا تحضيرها استفادوا + +49 +00:04:20,530 --> 00:04:25,760 +منها بإيش؟استفادوا منها بالمكافحة البيولوجية + +50 +00:04:25,760 --> 00:04:30,500 +للحشرات استفادوا منها بالمكافحة البيولوجية للحشرات + +51 +00:04:30,500 --> 00:04:35,880 +كيف؟ انه انا لو بعرف مثلا حشرة دودة القطن على سبيل + +52 +00:04:35,880 --> 00:04:40,780 +المثال ان الانثا بتفرز فيرومون معين وهذا الفيرومون + +53 +00:04:40,780 --> 00:04:45,920 +بيخلي الذكور ييجوا باتجاه الفيرومونحضروا الفيرومون + +54 +00:04:45,920 --> 00:04:48,800 +في المختبر، رأيك مركب؟ ممكن احضره مثلا انا في + +55 +00:04:48,800 --> 00:04:52,400 +المختبر، حضروه في المختبر و صاروا يبيعوه + +56 +00:04:52,400 --> 00:04:58,280 +للمزارعين، صاروا يبيعوه للمزارعين اجيبوا مثلا زي + +57 +00:04:58,280 --> 00:05:03,380 +عصا بهذا الشكل و حطوا عليها الفيرومون مع سمكو + +58 +00:05:03,380 --> 00:05:08,620 +يحطوه في الحقيقه الان كل الحشرات عادة بتتجذب هنا + +59 +00:05:08,620 --> 00:05:11,500 +على الفيرومون فمجرد ما بتيجي على هذا الفيرومون + +60 +00:05:11,500 --> 00:05:17,640 +بتلاقوها بتلتصق في العصا اللي فيها سمك مخلوق مع + +61 +00:05:17,640 --> 00:05:23,140 +نسبة من الاش الفيرومين فهم إذا أبادوا أحد الجنسين + +62 +00:05:23,140 --> 00:05:30,650 +معنى ذلك قضوا على إيش؟ على الحشرة بالمجملطبعا + +63 +00:05:30,650 --> 00:05:35,410 +البرولين هذا amino acid هو ال amino acid ال cyclic + +64 +00:05:35,410 --> 00:05:39,790 +المشهور اللي اسمه إبرولين ومهم في ال biochemistry + +65 +00:05:39,790 --> 00:05:45,790 +لأنه عادة ال turns بتصير من عنده في ال .. لما ناخد + +66 +00:05:45,790 --> 00:05:49,030 +ال protein structure ونقول ان ال protein structure + +67 +00:05:49,030 --> 00:05:53,070 +بيصير globular و بيصير turn من وين بتصير ال turns؟ + +68 +00:05:53,260 --> 00:05:57,400 +من عند البرولين لأنه لما بيعمل البروتين بيبطل فيه + +69 +00:05:57,400 --> 00:06:00,860 +انديهيدروجين فمنطقته مش فيه هيدروجين بوندي + +70 +00:06:00,860 --> 00:06:05,520 +النكوتين ربما اتكلمنا عنه لما حكينا عن البريدين + +71 +00:06:05,520 --> 00:06:11,020 +وبنفس الوقت هو عبارة عن بيريدين و بيروليدين + +72 +00:06:11,820 --> 00:06:16,420 +وموجودين على موقع تلاتة على البريدين فهو في + +73 +00:06:16,420 --> 00:06:22,460 +النهاية الكلويد من البريدين ومن البروليدين هذه كل + +74 +00:06:22,460 --> 00:06:26,580 +المركبات هي عبارة عن مركبات في الطبيعة في الحياة + +75 +00:06:26,580 --> 00:06:29,720 +في جسم الإنسان فيها بيرول ولذلك احنا بنقول ان ال + +76 +00:06:29,720 --> 00:06:38,660 +بيرول له أهمية خاصة مميزةالان لو اجينا لتحضير ال + +77 +00:06:38,660 --> 00:06:44,080 +buy roll في عندنا ال ignore synthesis شو هو ال + +78 +00:06:44,080 --> 00:06:49,200 +ignore synthesis؟الأساس لـ Knorr Synthesis كان + +79 +00:06:49,200 --> 00:06:53,880 +بيستعمل two equivalents من الـ Ethylacetoacetate + +80 +00:06:53,880 --> 00:06:58,380 +واحد بيحوله إلى أكزيم بعدين بيدوبه في Iglesia + +81 +00:06:58,380 --> 00:07:02,080 +الacetic من خلال أنه يدوب في Iglesia الacetic أسد + +82 +00:07:02,080 --> 00:07:05,320 +مع Sodium Nitrite بيصير أكزيم بيعمل reduction + +83 +00:07:05,320 --> 00:07:09,480 +للأكزيم لأمين وبعدين بتفعل مع الجزء التانيهذا + +84 +00:07:09,480 --> 00:07:14,720 +الكلام وصفي لو بدنا نشوف الكلام زي ما اتفقنا احنا + +85 +00:07:14,720 --> 00:07:19,140 +اكم equivalent بدي من الethyl acetoacetate اتنين + +86 +00:07:19,140 --> 00:07:25,460 +الان هاي واحد منهمهذا Ethyl Acetoacetate لو أتيت + +87 +00:07:25,460 --> 00:07:30,780 +فعلته مع ال Sodium Nitrate في وجود ال Acetic Acid + +88 +00:07:30,780 --> 00:07:34,580 +ال Sodium Nitrate في وجود ال Acetic Acid على ال + +89 +00:07:34,580 --> 00:07:39,800 +CH2 اللي موجودة هنا بيعمل أكزيم يمكن هذا يكون + +90 +00:07:39,800 --> 00:07:44,300 +بالنسبة لكم شوية تفاعل غريب لإن انتم متعودين على + +91 +00:07:44,300 --> 00:07:51,670 +الأكزيممن C double bond O مع الهيدروكس الأمين يعني + +92 +00:07:51,670 --> 00:07:58,510 +هذا الأكزيم اللي انتوا بتعرفوه لكن ربما مامرش + +93 +00:07:58,510 --> 00:08:06,730 +معاكم ان ال CH2 بتعمل أكزيم ال CH2 ال activated مع + +94 +00:08:06,730 --> 00:08:10,530 +ال sodium nitrite و ال acetic acid بتعمل أكزيم + +95 +00:08:11,110 --> 00:08:14,830 +خلّينا الآن ناخدوا as such أنها بتعمل أجزيم + +96 +00:08:14,830 --> 00:08:19,910 +التفاعل القديم تقريبا من 1874 و تفاصيله أنا + +97 +00:08:19,910 --> 00:08:26,430 +جبتلكوا يا حتى ما يضلوش غريب عليكم بس الآن نقبل أن + +98 +00:08:26,430 --> 00:08:32,990 +هذا الجزء الأول أنا عمل إيش أجزيم الأجزيم بال + +99 +00:08:32,990 --> 00:08:37,420 +reduction بصير أمينهذه سهلة reduction of oxygens + +100 +00:08:37,420 --> 00:08:40,880 +بتعطينا amines هذي مشهورة ان ال oxygens بال + +101 +00:08:40,880 --> 00:08:47,000 +reduction بتصير amines الآن بجيب الجزء التاني من + +102 +00:08:47,000 --> 00:08:52,020 +الاخ الأسد و أسد يعني لاحظوا هذا كان إيش الجزء + +103 +00:08:52,020 --> 00:08:56,540 +الأول صار oxygen و صار amine إذا كام جزء أنا + +104 +00:08:56,540 --> 00:09:03,960 +استعملتمن الـ ethyl acetoacetate جزيئين ودخلت الـ + +105 +00:09:03,960 --> 00:09:08,600 +NH2 من خلال أنه عملت أكزيم وعملت reduction إذا + +106 +00:09:08,600 --> 00:09:13,100 +وصلنا لهذه المرحلة سار الأمر سهل لأن هذه عندني الـ + +107 +00:09:13,100 --> 00:09:17,220 +nucleophile وهذه عندني هنا الـ nucleophile طبعا في + +108 +00:09:17,220 --> 00:09:22,200 +ال conditions تبع التفاعل هذه أنا فيه عندىموجب in + +109 +00:09:22,200 --> 00:09:26,480 +principle وموجب مش ضايق الغير نكمل ال cyclization + +110 +00:09:26,480 --> 00:09:31,260 +هنا بيصير C double bond N إمين إنامين وهذه هتسكر + +111 +00:09:31,260 --> 00:09:37,100 +OH مع H تعمل elimination لاحظوا أن هذا التفاعل + +112 +00:09:37,100 --> 00:09:43,060 +استعمل two equivalents من الethyl acetoacetate + +113 +00:09:43,060 --> 00:09:47,590 +اللي هي لو أنا أتيت أطلعك اللي في أطراف المثلو ال + +114 +00:09:47,590 --> 00:09:50,330 +a star group هاي one equivalent و هاي two + +115 +00:09:50,330 --> 00:09:53,990 +equivalent اتجوا متعاكسين و لذلك بطريقة او باخره + +116 +00:09:53,990 --> 00:09:58,370 +فيه ال symmetry يعني هاي .. هاي ال ethyl aceto + +117 +00:09:58,370 --> 00:10:02,090 +acetate و هاي ال ethyl aceto acetate و اتجت ال + +118 +00:10:02,090 --> 00:10:07,250 +nitrogen ازياد عليهم من وين؟ من ال oxime اللي + +119 +00:10:07,250 --> 00:10:13,410 +عملناله reduction ل ..للأمين فهو فعلا two + +120 +00:10:13,410 --> 00:10:16,350 +equivalents من الethyl acetoacetate هاي نشوفناهم + +121 +00:10:16,350 --> 00:10:21,810 +كيف اجوا و كيف عملوا الجزاء مع ال nitrogen اللي + +122 +00:10:21,810 --> 00:10:25,290 +اجت من الأكزيم هذا اللي بنسميه Knorr synthesis + +123 +00:10:25,290 --> 00:10:31,390 +طبعا ال nitrogen of ألفات ال carbon atom اللي هي + +124 +00:10:31,390 --> 00:10:35,710 +هذه ال carbon ال CH2 نعملها نيتروزو أفعلها من + +125 +00:10:35,710 --> 00:10:40,690 +نيتروزو و نيتروزو أخد الأكزيم توتمر منههذا الـ + +126 +00:10:40,690 --> 00:10:46,690 +Nitrosation مشهور تفاعل أول من عمله و اكتشفه + +127 +00:10:46,690 --> 00:10:55,330 +Victor Meyer في الـ 1873 و 1874 يعني التفاعل قديم + +128 +00:10:55,330 --> 00:11:02,260 +تفاصيله موجود هنا ككلام و موجود هناكمعادلات بدي + +129 +00:11:02,260 --> 00:11:06,080 +أمشي عليها بسريع لإن هي general organic chemistry + +130 +00:11:06,080 --> 00:11:10,520 +لكن الفكرة أنه احنا لما نبدأ بال sodium nitrite + +131 +00:11:10,520 --> 00:11:17,240 +بالacetic acid بنعمل protonation فصار عندى nitrous + +132 +00:11:17,240 --> 00:11:21,140 +acid مع sodium acetate كمان protonation صار عندى + +133 +00:11:21,140 --> 00:11:28,270 +الايون الموجب هذا الايون الموجب بيفقد الميهفبصير + +134 +00:11:28,270 --> 00:11:32,730 +عنده ال Nitroso group يعني هذا لما يفقد الميه + +135 +00:11:32,730 --> 00:11:38,990 +بيصير عنده ال N O positive الان لو اتيت و اتطلعت + +136 +00:11:38,990 --> 00:11:44,390 +على هذا الجزيه ال ethyl acetoacetate انا لسه مخليه + +137 +00:11:44,390 --> 00:11:51,140 +اتريح ال ethyl acetoacetate اخد منهالانول اخد منه + +138 +00:11:51,140 --> 00:11:58,480 +الانول form و افعله مع النيتروزو فهدد الالكترونات + +139 +00:11:58,480 --> 00:12:03,620 +بهذا الشكل بهذا الشكل بتتحرك فال double bond + +140 +00:12:03,620 --> 00:12:08,540 +هتهاجم على الان الموجب هيصير عندى هذا لو عملت له + +141 +00:12:08,540 --> 00:12:12,940 +tautomerism + +142 +00:12:12,940 --> 00:12:21,910 +هيصير عندى OH طبعا هيكون زائد ايشفي النهاية ال + +143 +00:12:21,910 --> 00:12:26,630 +acidic acid يعني هيفقد لما هذا التفاعل تم في + +144 +00:12:26,630 --> 00:12:32,270 +النهاية هيفقد ايش H مع ال OAC يعني لاحظوا ان هذا + +145 +00:12:32,270 --> 00:12:37,030 +التفاعل كله هذا التفاعل كله اخد من هنا ايش ال + +146 +00:12:37,030 --> 00:12:43,610 +nitrogen لكن فقد ايضا H H مع ال OAC + +147 +00:12:46,110 --> 00:12:51,390 +أسيتك أسد و إجت ال نيتروز هنا و اللي كان هتحس لو + +148 +00:12:51,390 --> 00:12:56,430 +نفذته بهدوء أنه في اتش فقدت ليا هتفقد اتش و هتروح + +149 +00:12:56,430 --> 00:13:01,150 +مع ايش مع الايون السالب اللي هنا على شكل ايه اسيتك + +150 +00:13:01,150 --> 00:13:05,410 +أسد واضح يعني هتفقد اتش و هتروح مع الايون السالب + +151 +00:13:05,410 --> 00:13:10,630 +واضح ليش لأن انتوا لو طلعتوا على هذا كمحصلة هذا + +152 +00:13:10,630 --> 00:13:15,870 +كمحصلة كم اتش موجودة فيهوحدة هذا كان محصلة كان + +153 +00:13:15,870 --> 00:13:20,750 +فيها نقاش كان فيها نقاش يعني في نقاش فقدت هذه ال + +154 +00:13:20,750 --> 00:13:25,770 +نقاش اللي فقدت وين راحت مع ال acidic واضح على أي + +155 +00:13:25,770 --> 00:13:31,690 +حال هذا شكل عام حتى ما تستغربوش هذا التفاعل لكن في + +156 +00:13:31,690 --> 00:13:35,770 +شكل عام ال activated hydrogen atom مع ال sodium + +157 +00:13:35,770 --> 00:13:41,930 +nitrate بتصير ايش اكزيم هذا تفاعل قديم من ال 1800 + +158 +00:13:42,920 --> 00:13:47,860 +واضح؟ ال CH2 الاكتفات جامب إيستر و جامب كيتر و + +159 +00:13:47,860 --> 00:13:54,880 +جامب نيترالز و جامب نيترو شغل كثير موجود عليها و + +160 +00:13:54,880 --> 00:14:00,060 +كله بندرج تحت المسمى العام اللي هو Nitrosation of + +161 +00:14:00,060 --> 00:14:05,510 +Aliphatic Carbon Atoms بتعمل إيش عنده؟أكزيم الآن + +162 +00:14:05,510 --> 00:14:10,370 +إذا صار عند الأكزيم بعد هيك ال reduction سهل و + +163 +00:14:10,370 --> 00:14:13,970 +استكمال التفاعل و فهمه بتكون عملية أيش سهلة يعني و + +164 +00:14:13,970 --> 00:14:18,450 +ربما أصعب شيء هنا للي بيكون بعرفش إنها CH2 بتعمل + +165 +00:14:18,450 --> 00:14:22,250 +أكزيم مع ال sodium nitrite في الacetic acid هذا + +166 +00:14:22,250 --> 00:14:25,830 +اللي احنا ذكرنا له تفاصيله إنما ال reduction و + +167 +00:14:25,830 --> 00:14:28,170 +بعدين هنا ال nucleophile ال electrophile ال + +168 +00:14:28,170 --> 00:14:31,110 +nucleophile كل هذا أمر بسيط + +169 +00:14:32,980 --> 00:14:36,460 +التحضير التاني بالك Nor Synthesis of Birol هذا + +170 +00:14:36,460 --> 00:14:40,100 +بيعتمد ان احنا نستعمل one four-dicarbonyl compound + +171 +00:14:40,100 --> 00:14:45,280 +one two three four الان مع ال ammonia مع ال + +172 +00:14:45,280 --> 00:14:49,560 +ammonia او AME derivative هيصير C double bond N + +173 +00:14:49,560 --> 00:14:54,960 +والان مرة تانية تسكل على ال oxygen فبصير Birol ف + +174 +00:14:54,960 --> 00:15:00,420 +eight and ten C double bond O على موقع 14 مع ال + +175 +00:15:00,420 --> 00:15:05,680 +nitrogen شو هيعطوني؟Birol الان هذا الكلام بيذكركوا + +176 +00:15:05,680 --> 00:15:10,500 +بإيش؟ + +177 +00:15:10,500 --> 00:15:15,420 +انه نيتروجين مع باي كربونيل كومباوند هانا قاعدة + +178 +00:15:15,420 --> 00:15:22,080 +بتعطي بيرول و هذا إيش اسمه؟ بالكنورد سينثيسيس of + +179 +00:15:22,080 --> 00:15:29,760 +بيرول الفيورين هناخد التنتين هدولة باسد ونخلي + +180 +00:15:29,760 --> 00:15:35,950 +أكسجين يتسكر عادة صحوالتيوفين هناخد التنتين هدولة + +181 +00:15:35,950 --> 00:15:39,870 +مع سلفة ونخلي واحدة تسكر على التانية يعني من ال + +182 +00:15:39,870 --> 00:15:43,570 +one four-dicarbonyl compound انا هحضر ال بيرول من + +183 +00:15:43,570 --> 00:15:48,430 +خلاله واتفاعل مع ال nitrogen هحضر الفيوران و هحضر + +184 +00:15:48,430 --> 00:15:53,570 +كمان التيوفين لكن برضه ال die-carbonyl compound مع + +185 +00:15:53,570 --> 00:16:01,880 +ال nitrogen بتذكرني بإيش؟بالبريدين الو لو كان عندي + +186 +00:16:01,880 --> 00:16:06,480 +one-five-dicarbonyl compound كنت أحصل على بريدين و + +187 +00:16:06,480 --> 00:16:11,680 +كان إيش اسم التفاعل؟ لأ ارجعوا عليك ارجعوا على + +188 +00:16:11,680 --> 00:16:16,760 +البريدين لما كان عندي one-five-dicarbonyl compound + +189 +00:16:16,760 --> 00:16:20,560 +عادي مكتوب reaction of ammonia أزاق ال one-five + +190 +00:16:20,560 --> 00:16:23,020 +-dicarbonyl one-five-dicarbonyl طيب بالكنور + +191 +00:16:23,020 --> 00:16:30,710 +synthesis of بريدين ماتسماش بالكنور؟واضح؟ فال 14 + +192 +00:16:30,710 --> 00:16:38,070 +بيعطو by role ال 15 بيعطو by ready وزي ما قلنا انه + +193 +00:16:38,070 --> 00:16:43,510 +من ال 14 dicarbonyl compound بيمكن احضر ال by role + +194 +00:16:43,510 --> 00:16:48,550 +و ال furan و الثيوفين و مرة جيبنا سؤال starting + +195 +00:16:48,550 --> 00:16:53,350 +from 14 dicarbonyl compound how can you prepare by + +196 +00:16:53,350 --> 00:16:57,010 +role, furan, and theophine مع الأمير بنحضر ايش؟ + +197 +00:17:00,020 --> 00:17:05,260 +الان لو اجينا ل synthesis تاني لل by role hence by + +198 +00:17:05,260 --> 00:17:11,260 +role synthesis الهنس by role synthesis بيشبه + +199 +00:17:11,260 --> 00:17:17,620 +الفيسبينري فيوران سينثيسي بيشبه الفيسبينري فيوران + +200 +00:17:17,620 --> 00:17:21,620 +سينتيسي خلينا نقول كيف بيشبه الفيسبينري فيوران + +201 +00:17:21,620 --> 00:17:27,010 +سينتيسي احنا لو أخدناهذا البيتا كيتو إيستر البيتا + +202 +00:17:27,010 --> 00:17:35,310 +كيتو إيستر البيتا كيتو إيستر البيتا كيتو إيستر + +203 +00:17:35,310 --> 00:17:36,510 +البيتا كيتو إيستر البيتا كيتو إيستر البيتا كيتو + +204 +00:17:36,510 --> 00:17:41,610 +إيستر البيتا كيتو إيستر البيتا كيتو إيستر البيتا + +205 +00:17:41,610 --> 00:17:41,950 +كيتو إيستر البيتا كيتو إيستر البيتا كيتو إيستر + +206 +00:17:41,950 --> 00:17:43,390 +البيتا كيتو إيستر البيتا كيتو إيستر البيتا كيتو + +207 +00:17:43,390 --> 00:17:44,390 +إيستر البيتا كيتو إيستر البيتا كيتو إيستر البيتا + +208 +00:17:44,390 --> 00:17:49,730 +البيبيتا كيتو إيستر زائد ألفة هالو كيتون هدولة + +209 +00:17:49,730 --> 00:17:54,830 +اتنين بيعطوني فيوران وهذا ال synthesis هو فيست + +210 +00:17:54,830 --> 00:18:00,630 +بيناري فيوران synthesis أخدنا تفصيله فيست بيناري + +211 +00:18:00,630 --> 00:18:06,170 +فيوران synthesis الآن لو خلطنا معهم أمونيا بيصير + +212 +00:18:06,170 --> 00:18:11,350 +يعطيني إيش بريدين يعني بيتا كيتو إيستر ألفة هالو + +213 +00:18:11,350 --> 00:18:18,090 +كيتونو Ammonia بيصير يعطيني عفوا By role الآن في + +214 +00:18:18,090 --> 00:18:22,610 +النهاية اللي خلط التلاتة مابضمنش انه كل مرة في + +215 +00:18:22,610 --> 00:18:25,050 +الأول بده تتفاعل ال ammonia زي ما هنشوف في + +216 +00:18:25,050 --> 00:18:30,790 +التفاصيل و بعدين يكتمل التفاعل و بالتالي ممكن بعض + +217 +00:18:30,790 --> 00:18:35,990 +هذه الجزيات معادي تعطي ايش؟ Furan و لذلك لو اجاكم + +218 +00:18:35,990 --> 00:18:44,020 +سؤال علّل انه في هذا ال synthesis بيطلع عندىFuran + +219 +00:18:44,020 --> 00:18:49,140 +as a by-product بدنا نكون إيش؟ فاهمين طب على وقتنا + +220 +00:18:49,140 --> 00:18:54,660 +نفصله هذا ال synthesis كيف بيطلع ال by-role إحنا + +221 +00:18:54,660 --> 00:18:59,300 +أخدنا كيف بيطلع ال Furan و ممكن نرجعله كيف بيطلع + +222 +00:18:59,300 --> 00:19:05,060 +ال by-role ال C double bond O مع ال NH2 هتعمل إمين + +223 +00:19:05,060 --> 00:19:09,780 +إنامين إنامين هى عملت الإنامين الآن لما بداتيش + +224 +00:19:09,780 --> 00:19:17,260 +تتفاعل معالـ α-هالو-كيتون لما تتفاعل مع الـ α-هالو + +225 +00:19:17,260 --> 00:19:22,300 +-كيتون ممكن تتخيل بهذا الشكل وهذه تتحل محل + +226 +00:19:22,300 --> 00:19:26,320 +الـClone الـ another substitution reaction، هذه + +227 +00:19:26,320 --> 00:19:29,780 +نعملت الـ bond، دل عنده نيتروجين مع السيطرة بالـ + +228 +00:19:29,780 --> 00:19:35,580 +bond Oهتعمل ال N مش هتقدر تعمل C double bond N + +229 +00:19:35,580 --> 00:19:40,100 +يعني هتعمل N واحدة لأن مثلا هتعمل R حتى لو عملت C + +230 +00:19:40,100 --> 00:19:45,060 +double bond N في حال أن هذه كانت Hydrogen إمين + +231 +00:19:45,060 --> 00:19:54,140 +هتصير إيش إنامينواضحة الفكرة؟ الآن في التفاعل اللي + +232 +00:19:54,140 --> 00:19:57,380 +كان عندنا .. في التفاعل اللي كان عندنا اللي هو تبع + +233 +00:19:57,380 --> 00:20:02,220 +الفيوران، بس اللي كنا نسويه أنه إحنا مش محاولين + +234 +00:20:02,220 --> 00:20:11,080 +هذهأه ماكناش محاولين هذه ل .. ل nitrogen كانت + +235 +00:20:11,080 --> 00:20:15,720 +double bond؟ أه و بالتالي كان اتم عنده الإغلاق + +236 +00:20:15,720 --> 00:20:20,220 +عليها بنرجع لالفايس بين refluent synthesis + +237 +00:20:20,220 --> 00:20:25,740 +بالتفصيل أخدتوا انتوا كيف كان نبدأ من هنا نكوّن ال + +238 +00:20:25,740 --> 00:20:26,100 +ion + +239 +00:20:38,980 --> 00:20:45,510 +الخلاصة ان هدولةالبيتا كيتو إيستر ألف هالو كيتو + +240 +00:20:45,510 --> 00:20:50,610 +لحالهم بيعطوني فيوران لو حطيت معهم أمونيا صار هذا + +241 +00:20:50,610 --> 00:20:55,710 +التفاعل في البداية امين انامين وبعدين اعملنا هذا + +242 +00:20:55,710 --> 00:21:02,260 +التفاعل كنيكليوفايل إلكتروفايل بيعطيني إيش؟بايرول + +243 +00:21:02,260 --> 00:21:06,860 +لو اجيت انا لل reactions of بايرول ال reactions ال + +244 +00:21:06,860 --> 00:21:11,820 +reactions of بايرول في عندى ممكن يتم reactions على + +245 +00:21:11,820 --> 00:21:16,080 +ال nitrogen و ممكن يتم في شكل اساسي electrophilic + +246 +00:21:16,080 --> 00:21:18,300 +substitution على ال ring يعني بدى اصنف ال + +247 +00:21:18,300 --> 00:21:25,320 +reactions نوعين على ال nitrogen و علىالان ربما + +248 +00:21:25,320 --> 00:21:31,000 +كلكم اتذكرين كلمة انه على ال nitrogen هذا اللون + +249 +00:21:31,000 --> 00:21:36,660 +bear اللي موجود على ال by roll نشيط انه يتفاعل مع + +250 +00:21:36,660 --> 00:21:41,780 +الخارج ولا لأ؟ ليش؟ لأن هذا جزء من ال aromatic + +251 +00:21:41,780 --> 00:21:45,560 +system طب لما انا بدي ال nitrogen يتفاعل مع الخارج + +252 +00:21:45,560 --> 00:21:50,710 +بدي اعمل عملية تحضيرية في الأولإيش العملية + +253 +00:21:50,710 --> 00:21:54,210 +التحضيرية اللي بدي أعملها عشان تمت فاعل على + +254 +00:21:54,210 --> 00:22:02,310 +الـNitrogena؟ بدي أجي لهذه الـNH بالمثل أسحب منها + +255 +00:22:02,310 --> 00:22:10,120 +الـH أخليها N-واجهته بيصير التفاعل من خلال زوجة + +256 +00:22:10,120 --> 00:22:13,520 +الإلكترونات اللى هتتبع الـ minus إذا أنا كخطوة + +257 +00:22:13,520 --> 00:22:17,840 +أولى للتفاعل مع ال nitrogen بعمل ال methylation of + +258 +00:22:17,840 --> 00:22:21,500 +بيرول يعني ممكن أفاعل مع ال sodium مع ال potassium + +259 +00:22:21,500 --> 00:22:25,540 +مع ال دمد أو البوتاسامد ب liquid ammonia في كل + +260 +00:22:25,540 --> 00:22:31,160 +الأحوال هدولة هيصحبوا ال hydrogen هيعملولي إيش؟الـ + +261 +00:22:31,160 --> 00:22:34,640 +minus الأن الأن الـ minus هاي في عند أنا زوج + +262 +00:22:34,640 --> 00:22:38,080 +إلكترونات part of the aromatic system وفي عندي زوج + +263 +00:22:38,080 --> 00:22:46,850 +إلكترونات جاهز إنه يتفاعلواضح؟ هذا زوج الإلكترونات + +264 +00:22:46,850 --> 00:22:50,210 +اللي جاهز انه يتفاعل هو اللي بعد هيك يتفعل مع الـ + +265 +00:22:50,210 --> 00:22:54,050 +Electrophile فانا مش الهدف عندى ان اعمل ال minus و + +266 +00:22:54,050 --> 00:22:58,570 +جمبها K plus يعني Sodium Salt of Birol لأ أنا بدي + +267 +00:22:58,570 --> 00:23:03,270 +ال Salt هذا بعد هيك اروح افعله مع إيش؟ مع ال + +268 +00:23:03,270 --> 00:23:06,770 +Electrophile الآن بنفس المنطقة لو اعملت Greenyard + +269 +00:23:06,770 --> 00:23:11,510 +Reagent برضه هيعندي زوج الإلكترونات الأصلي وهي هذا + +270 +00:23:11,510 --> 00:23:17,190 +الزوج اللي هيكون إيش؟جاز انه يتفاعد بعمل green + +271 +00:23:17,190 --> 00:23:21,930 +yard reagent على ال nitrogen مع المغنيسيام بعمل + +272 +00:23:21,930 --> 00:23:26,510 +شبيه بال green yard reagent MgBr ليش؟ لأن ال green + +273 +00:23:26,510 --> 00:23:31,510 +yard أساسا على carbon MgBr أنا عملته على إيش؟ على + +274 +00:23:31,510 --> 00:23:36,590 +ال nitrogen مع ال lithium حتى لو كان covalent هو + +275 +00:23:36,590 --> 00:23:40,090 +عند زوجي الإلكترونات اللي هنا لكن في النهاية + +276 +00:23:40,090 --> 00:23:45,320 +هستفيد من إيش أنا؟زوج الإلكترونات اللي على + +277 +00:23:45,320 --> 00:23:49,920 +الـNitrogen الآن هذا زوج الإلكترونات اللي على + +278 +00:23:49,920 --> 00:23:55,280 +الـNitrogen بفعله أنا مع الـElectrophile بيشتغل + +279 +00:23:55,280 --> 00:23:59,140 +كالـNucleophile يعني مثلا لو فعلته مع الـMethyl + +280 +00:23:59,140 --> 00:24:03,880 +Iodide بيجي بيهاجم و بيحل محل اليوت هيعملت + +281 +00:24:03,880 --> 00:24:08,130 +Methylationلاحظوا معاه لو قلتلكوا how can you + +282 +00:24:08,130 --> 00:24:13,450 +prepare الميثل بيرول و ايجي حد قاللي بهذا الشكل + +283 +00:24:13,450 --> 00:24:21,950 +بدي اخد ال بيرول مباشرة + +284 +00:24:21,950 --> 00:24:28,410 +مع الميثل ايودايد مش حياتيفانا بعمل بالصوديوم بخلي + +285 +00:24:28,410 --> 00:24:33,010 +هذه ال minus و ال minus مع ال methyl iodide واضحة + +286 +00:24:33,010 --> 00:24:39,070 +الفكرة اذا صار عندى by role negative ion بعدين + +287 +00:24:39,070 --> 00:24:42,570 +بفعلها هاي كمان مرة مع ال methyl iodide اللي هو + +288 +00:24:42,570 --> 00:24:46,190 +هذا اللي مع المغنيسيون الشبيه بال green يعني نفس + +289 +00:24:46,190 --> 00:24:49,190 +الاشي عمل methylation و ال yield زي ما انتوا + +290 +00:24:49,190 --> 00:24:53,250 +شايفين ايش معله ممتازة كل هذه التفاعلات على اي ذرة + +291 +00:24:54,080 --> 00:24:59,920 +عال Nitrogen لكن لابد لها من خطوة تحضيرية هاي هنا + +292 +00:24:59,920 --> 00:25:04,040 +مع ال Acetyl ال Acetyl is a nucleophile ولا لأ + +293 +00:25:04,040 --> 00:25:10,220 +CH3C double bond OCl طبعا هيكون التفاعل تفاعل + +294 +00:25:10,220 --> 00:25:15,700 +Substitution تحط ل Acetyl عال Nitrogen الآن هنا + +295 +00:25:15,700 --> 00:25:19,940 +قملت كمان Electrophilic Substitution ع الحلقة لكن + +296 +00:25:19,940 --> 00:25:25,390 +هذا التفاعل عال Nitrogenواضح؟ هاي مع ال بنزويل + +297 +00:25:25,390 --> 00:25:33,110 +بنزويل كلورايد فينيل C double bond O Cl مع السالب + +298 +00:25:33,110 --> 00:25:37,390 +اللي هنا بس عمل على ال nitrogen ماعملش على الحلقة + +299 +00:25:38,140 --> 00:25:42,360 +واضح يعني هنا تم إبدال عادي عن نيتروجين و لحظه + +300 +00:25:42,360 --> 00:25:45,840 +كمان Electrophilic substitution على الحلقة هنا بس + +301 +00:25:45,840 --> 00:25:51,300 +تم عن نيتروجين في نهاية الكيميا إيش علم تجريب يعني + +302 +00:25:51,300 --> 00:25:54,980 +شو إفرجت ال acid ال chloride عن ال benzoyl + +303 +00:25:54,980 --> 00:25:59,060 +chloride لكن مع ال acid ال chloride طلع عندى إبدال + +304 +00:25:59,060 --> 00:26:03,080 +على الحلقة Electrophilic substitution مع ال + +305 +00:26:03,080 --> 00:26:06,120 +benzoyl chloride بس الإبدال تم على ال nitrogen + +306 +00:26:06,120 --> 00:26:11,310 +الآنالنوع التاني من تفاعلات ال by role اللي هو ال + +307 +00:26:11,310 --> 00:26:15,350 +electrophilic substitution عادة ال electrophilic + +308 +00:26:15,350 --> 00:26:20,710 +substitution يتم على موقعإتنين لو عملنا resonance + +309 +00:26:20,710 --> 00:26:23,330 +structures حتى لو اعتبرنا ان هذا resonance + +310 +00:26:23,330 --> 00:26:27,010 +structure يعني غير محبب اللي فيه الموجب على ال + +311 +00:26:27,010 --> 00:26:30,090 +nitrogen على موقع اتنين عندي two resonance + +312 +00:26:30,090 --> 00:26:33,910 +structures على موقع تلاتة عندي one resonance + +313 +00:26:33,910 --> 00:26:37,310 +structure ولذلك ال substitution بتمع ال birol على + +314 +00:26:37,310 --> 00:26:40,970 +موقع اتنين بيضل متذكرين انه في ال electrophilic + +315 +00:26:40,970 --> 00:26:44,950 +substitution بشكل عام ال birol بتفاعل أسرع من + +316 +00:26:44,950 --> 00:26:49,080 +الفيوران أسرع من الفتيوفينو كلهم أسرع من البنزين + +317 +00:26:49,080 --> 00:26:54,200 +يعني كل هذه الحلقات أسرع من البنزين طبعا ممكن حد + +318 +00:26:54,200 --> 00:26:57,060 +يقول ليش أسرع من البنزين لأن فيهم في النهاية ال + +319 +00:26:57,060 --> 00:27:00,240 +electronegative atom بتعطي إلكترونات بزيادة و + +320 +00:27:00,240 --> 00:27:04,280 +التفاعل electrophilic substitution يعني سالب عموجة + +321 +00:27:04,280 --> 00:27:10,000 +فهذه الذرات اللي بتعطي إلكترونات زيادة هتزيد سرعة + +322 +00:27:10,000 --> 00:27:15,520 +إيش؟التفاعل الآن الأمثلة زي ما احنا شايفين كتير + +323 +00:27:15,520 --> 00:27:19,320 +نيتراشن، كلوريناشن، جروميناشن، وويلزمير إذا + +324 +00:27:19,320 --> 00:27:22,640 +متذكرينه الـformal group لاحظوا في معظم الحلات على + +325 +00:27:22,640 --> 00:27:26,020 +موقع اتنين، اتنين وخمسة، اتنين، اتنين، اتنين + +326 +00:27:26,020 --> 00:27:29,700 +وخمسة، اتنين وخمسة في مرة يمكن طلع على نسبة تلاتة + +327 +00:27:29,700 --> 00:27:35,100 +بنسبة يعني عدم فال substitution بشكل أساسي بيكون + +328 +00:27:35,100 --> 00:27:38,520 +mono substitution على اتنين مرات بيصير على + +329 +00:27:52,370 --> 00:27:56,190 +البيرول كمان بيعمل + +330 +00:27:57,940 --> 00:28:02,400 +cycloaddition reactions with dichlorocarbine البعض + +331 +00:28:02,400 --> 00:28:05,640 +هييجي يقول من وين ال dichlorocarbine الناس اللي + +332 +00:28:05,640 --> 00:28:09,340 +أخدوا Reimer-Thiemann reaction اللي هو ال + +333 +00:28:09,340 --> 00:28:12,200 +chloroform بال إيثار في ال base بيعمل + +334 +00:28:12,200 --> 00:28:17,920 +dichlorocarbine يعني carbine بهذا الشكل carbon Cl + +335 +00:28:17,920 --> 00:28:23,350 +Clبهذا الشكل وهذا الـ Carbine لما يجي يتفاعل هنا + +336 +00:28:23,350 --> 00:28:27,770 +يعمل insertion هنا في نابط حول لإيش؟ لالديهايد + +337 +00:28:27,770 --> 00:28:31,150 +اللي بده يتذكر هذا التفاعل يمكن التفاعل بهذا الشكل + +338 +00:28:31,150 --> 00:28:38,000 +يبدو إيش؟غريب لكن لو انتوا تذكرتوا التفاعل في ال + +339 +00:28:38,000 --> 00:28:43,540 +organic اللي هو اسمه Reimer-Thiemann reaction + +340 +00:28:43,540 --> 00:28:47,160 +Reimer-Thiemann reaction هاي كنا عالفينول مع ال + +341 +00:28:47,160 --> 00:28:51,020 +chloroform بيصير هنا Dichlorocarbine وبعدين بيصير + +342 +00:28:51,020 --> 00:28:53,960 +له reduction لل aldehyde هاي تفاصيل ال Reimer + +343 +00:28:53,960 --> 00:28:58,190 +-Thiemann reaction مر عليكوا كاملا في وين؟في ال + +344 +00:28:58,190 --> 00:29:03,310 +organic synthesis فمافيش داعي نرجعله فتكوين ال + +345 +00:29:03,310 --> 00:29:07,410 +formal من هذا التفاعل هو مشابه ل Raymartimer + +346 +00:29:07,410 --> 00:29:12,730 +reaction أمر طبيعي لكن ربما الأمر الغريب أنه يجي + +347 +00:29:12,730 --> 00:29:19,070 +يتكون عندكم إيشاه يتكون عند بيردين لكن اذا انتوا + +348 +00:29:19,070 --> 00:29:22,530 +قولتوا انه في عندكم في النهاية Dichlorocarbine + +349 +00:29:22,530 --> 00:29:28,110 +يعني Carbon مع Chlorine هنا وعملوا Cycloaddition + +350 +00:29:28,110 --> 00:29:34,190 +اكسروا ال ring من هنا كده ايش صار عندى نيتروجين + +351 +00:29:34,190 --> 00:29:40,780 +كاربون كاربون حملة CL ومطلعقتش CLعشان هيك تفسير + +352 +00:29:40,780 --> 00:29:45,020 +هذا الـ 3-chloropyridine الـ by-product بتم من + +353 +00:29:45,020 --> 00:29:49,540 +خلال إن أنا أقول إن الـ dichlorocarbine عمل cycle + +354 +00:29:49,540 --> 00:29:54,060 +addition على الـ double bond اللي هنا و عمل ring + +355 +00:29:54,060 --> 00:29:58,700 +opening مرات سألنا الطلاب كيف بتفسر إنه بهذا + +356 +00:29:58,700 --> 00:30:04,800 +التفاعل طلع عنده 3-chloropyridine بدا أقول cycle + +357 +00:30:04,800 --> 00:30:09,280 +addition of dichlorocarbine followed byRing + +358 +00:30:09,280 --> 00:30:15,120 +Opening واضح الكلام و كل قصة Dichlorocarbine يعني + +359 +00:30:15,120 --> 00:30:20,760 +قصة Trimer reaction هي تقريبا نفس التفسير مع مركب + +360 +00:30:20,760 --> 00:30:24,880 +تاني جيبنا Dichlorocarbine من مصدر تاني و بعدين + +361 +00:30:24,880 --> 00:30:29,980 +Ring Opening عملناه و بيوضحوا تماما و طلع برضه 3 + +362 +00:30:29,980 --> 00:30:34,480 +-chloropyridine نفس فكرة ال Ring Expansion نفس + +363 +00:30:34,480 --> 00:30:40,210 +فكرةالـ Dichlorocarbine اللي بيعمل الـ Chelotropic + +364 +00:30:40,210 --> 00:30:46,990 +Cycloaddition على الـ Double Bond الآن الـ Diels + +365 +00:30:46,990 --> 00:30:50,430 +-Alder Reaction الـ By Rules بشكل عام من أضعف + +366 +00:30:50,430 --> 00:30:53,710 +الحلقات اللي بتعمل الـ Diels-Alder Reaction طبعا + +367 +00:30:53,710 --> 00:30:56,690 +لما بتعمل ال Diels-Alder Reaction هتعمل بصفتها + +368 +00:30:56,690 --> 00:31:01,730 +إيش؟deals يعني هاي جزء الداين اللي فيها، هاي جزء + +369 +00:31:01,730 --> 00:31:04,750 +الداين، لكن في بعض الأمثلة هاي + +370 +00:31:04,750 --> 00:31:07,790 +unethoxycarbonylbirol + +371 +00:31:07,790 --> 00:31:11,990 +مثلا مع ال die مثل أستيلين، diecarboxylate يعني + +372 +00:31:11,990 --> 00:31:16,250 +هان أستيلين، إذا أنا لما بدأ أعمل deals ألدر هنا، + +373 +00:31:16,250 --> 00:31:21,510 +بدأ أجي على هذه النقطةوعلى هذا النقطة و اعمل + +374 +00:31:21,510 --> 00:31:26,270 +الحلقة السداسية واضح؟ لاحظوا هاي جزء ال VIROL وما + +375 +00:31:26,270 --> 00:31:30,990 +زال حامل ال NCO2 إثل و هاي هذا الجزء اللي إجا من + +376 +00:31:30,990 --> 00:31:40,010 +ال Acetylene هاي جزء ال Acetylene و هاي جزء ال + +377 +00:31:40,010 --> 00:31:44,610 +VIROL واضح؟ وعملنا حلقة سداسية واحد، اتنين، تلات، + +378 +00:31:44,610 --> 00:31:50,010 +اربع، خمس، ستة هذه الحلقة السداسية كام Vibon؟واحدة + +379 +00:31:50,010 --> 00:31:55,930 +من ال deals ألدر واحدة من ال triple bond فقط بيلزم + +380 +00:31:55,930 --> 00:32:02,010 +أن أشي نكونيعني ان نفذ هذا الكلام نتعود عليه نرسمه + +381 +00:32:02,010 --> 00:32:07,590 +بجلم درصاص بهدوء عشان الصين عندنا تدريب ايضا ال by + +382 +00:32:07,590 --> 00:32:11,790 +role ممكن يعمل 2 plus 2 cycle addition يعني هاي by + +383 +00:32:11,790 --> 00:32:18,450 +role مع كيتون في النهاية بتطلعلي هذا المركب طب انا + +384 +00:32:18,450 --> 00:32:22,750 +بدى افسر كيف اتكون هذا المركب خلينا نفترض ان هو + +385 +00:32:22,750 --> 00:32:27,940 +عمل في الأول2 plus 2 cycle addition و بعدين هنا + +386 +00:32:27,940 --> 00:32:33,360 +عمل ring opening يعني هذا 2 plus 2 cycle addition + +387 +00:32:33,360 --> 00:32:38,420 +عطاني حلقة رباعية بعد هيك لو حركنا الإلكترونات + +388 +00:32:38,420 --> 00:32:43,240 +بشكل معين هيصير عندنا ال O minus ال H اللي هنا + +389 +00:32:43,240 --> 00:32:54,960 +هنبدأ من عندها هاي ال O minus OH واضح؟ يعني هذهالـ + +390 +00:32:54,960 --> 00:32:58,800 +bond هنا صارت double bond وهذه صارت O minus مع ال + +391 +00:32:58,800 --> 00:32:59,540 +H من هنا + +392 +00:33:03,130 --> 00:33:06,890 +فهذا ال alcohol اللي اتكون عندنا لو بدنا نقول + +393 +00:33:06,890 --> 00:33:09,850 +explain the formation of this alcohol بدنا نقول ان + +394 +00:33:09,850 --> 00:33:16,390 +هذا تم عبر two plus two cycloaddition ابهيك بنكون + +395 +00:33:16,390 --> 00:33:19,730 +اعطينا فكرة عن ال by role وقلنا انه التفاعلات + +396 +00:33:19,730 --> 00:33:23,230 +الأساسية عن ال nitrogen و ال electrophilic + +397 +00:33:23,230 --> 00:33:28,850 +substitution ال cycloadditions أمثلة قليلة جدا + +398 +00:33:28,850 --> 00:33:33,990 +محدودة جدا ذكرنا منها مثلانينأما تفاعلاته الأساسية + +399 +00:33:33,990 --> 00:33:41,050 +عن نيتروجين من خلال إيش؟ الايون السالب، عن + +400 +00:33:41,050 --> 00:33:44,550 +نيتروجين من خلال الايون السالب، الـelectrophilic + +401 +00:33:44,550 --> 00:33:49,020 +substitution تبعه على أي مواقعاتنين و خمسة لاحظوا + +402 +00:33:49,020 --> 00:33:52,800 +اللي بديه يحس انه القمر مش صعب يفهم بادئ الأساسية + +403 +00:33:52,800 --> 00:33:57,240 +ال بيرول بتفعل عن نيتروجين من خلال تكوين ايون سالك + +404 +00:33:57,240 --> 00:34:00,620 +في الأول مع معدن بعمل electrophilic substitution + +405 +00:34:00,620 --> 00:34:05,100 +على مواقع اتنين او اتنين و خمسة و طبعا بنفسره من + +406 +00:34:05,100 --> 00:34:09,890 +خلال ال resonance اللي هو بعض الأنفلةاللي هي Cycle + +407 +00:34:09,890 --> 00:34:13,630 +Addition سواء كان Deals Elder Cycle Addition أو 2 + +408 +00:34:13,630 --> 00:34:17,530 +Plus 2 Cycle Addition لما نروح على الفيوران هنلاحظ + +409 +00:34:17,530 --> 00:34:21,370 +أنه الفيوران في Deals Elder أمثلته أكتر كتير كتير + +410 +00:34:21,370 --> 00:34:26,340 +من ال By Roll يعني لو أنتوا بتكونوا تفتشوافي ال + +411 +00:34:26,340 --> 00:34:31,560 +net على deals alder مع furan هتلاقوا عشرات مئات + +412 +00:34:31,560 --> 00:34:34,360 +الأمثلة deals alder مع ال bayron عدد قليل من + +413 +00:34:34,360 --> 00:34:38,440 +الأمثلة لكن بكل الأحوال احنا بدناش ياكم تفتشوا على + +414 +00:34:38,440 --> 00:34:44,360 +هدولة بدنا ياكم تجيبولنا من ال net أمثلة على تحضير + +415 +00:34:44,360 --> 00:34:49,900 +تحضيرات جديدة ل quinoline و ال isoquinoline و ال + +416 +00:34:49,900 --> 00:34:56,980 +bayron بدناش ال bayronsEquinoline و Isoquinoline و + +417 +00:34:56,980 --> 00:35:01,900 +Birol روحوا على المجلات الجديدة شوفوا طرق جديدة + +418 +00:35:01,900 --> 00:35:04,900 +موجودة في المجلات How can you prepare new + +419 +00:35:04,900 --> 00:35:08,620 +derivatives of equinoline, of Isoquinoline, of + +420 +00:35:08,620 --> 00:35:12,080 +Birol؟ مابديش أنسى أنا أن ال equinolines يعني هي + +421 +00:35:12,080 --> 00:35:17,950 +مركبات يعني خليني أقول أساسية جدافي علاج + +422 +00:35:17,950 --> 00:35:24,170 +الروماتيزم وغيرها يعني والملاريا بشكل أساسي يعني + +423 +00:35:24,170 --> 00:35:29,270 +لو كتبتوا أنتوا antimalarial الأدوية المضادة + +424 +00:35:29,270 --> 00:35:34,370 +للملاريا هيطلع عندكم الquinolins عائلات كبيرة جدا + +425 +00:35:34,370 --> 00:35:39,510 +للأدوية ال antimalarial من الquinolins وبهك بننهي + +426 +00:35:39,510 --> 00:35:43,090 +محاضرتنا لليوم وإن شاء الله إلى لقاء آخر + diff --git a/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/zENVekzcB0Q_raw.srt b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/zENVekzcB0Q_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..8dec3bf0dc7c33dbd074d4bfee8c3a9f97b89102 --- /dev/null +++ b/PL9fwy3NUQKwaduqrzr0CaayOSRqHYwDpv/zENVekzcB0Q_raw.srt @@ -0,0 +1,1708 @@ +1 +00:00:20,740 --> 00:00:25,960 +بسم الله الرحمن الرحيم في موضوع أمثلة على حلقات + +2 +00:00:25,960 --> 00:00:30,140 +معينة بعد ما اتكلمنا عن الحلقات السوداسية أخدنا + +3 +00:00:30,140 --> 00:00:34,520 +البريديل، الكوينولين، الايزوكوينولين، فكرة عن ال + +4 +00:00:34,520 --> 00:00:39,960 +.. ال byrons in general بننتقل للحلقات الخماسية + +5 +00:00:39,960 --> 00:00:44,760 +طبعا أشهر الحلقات الخماسية ال byrol و الفيوران و + +6 +00:00:44,760 --> 00:00:51,200 +الثيوفين برضه بناخد فكرة مختصرة عنهمالـ Birol لو + +7 +00:00:51,200 --> 00:00:55,580 +بدنا نبدأ فيه خلّينا نقول نبدأ بأهميته يمكن في + +8 +00:00:55,580 --> 00:01:01,400 +أذهان الكل مرتبط ال Birol بال Porphyrin Ring اللي + +9 +00:01:01,400 --> 00:01:04,580 +هي الحلقة اللي موجودة في ال Hemoglobin و اللي بتم + +10 +00:01:04,580 --> 00:01:08,940 +فيهاالارتباط مع الحديد و عملية بعد هيك ال + +11 +00:01:08,940 --> 00:01:12,620 +complexation مع ال oxygen و نقل ال oxygen كل هذا + +12 +00:01:12,620 --> 00:01:16,420 +الكلام ربما في الكيميا الحيوية و في ال bio in + +13 +00:01:16,420 --> 00:01:21,280 +organic chemistry مر عليكم فهذا بيوضح لأهمية ال by + +14 +00:01:21,280 --> 00:01:28,400 +role هي جزء مكون أساسي من مكونات ايش الدم ال + +15 +00:01:28,400 --> 00:01:32,300 +hemoglobin طبعا موازن ال by role في النبات + +16 +00:01:32,950 --> 00:01:36,650 +الكلوروفيل باختلاف طبعا في ال substitution + +17 +00:01:36,650 --> 00:01:42,230 +والاختلاف الأشهر في ال metal يعني الإنسان ال metal + +18 +00:01:42,230 --> 00:01:46,570 +اللي موجود عنده الحديد في النباتات المجنيسية + +19 +00:01:48,080 --> 00:01:54,380 +الان هذا طبعا بيصير يجيب لمواد بتتكسر في الجسم + +20 +00:01:54,380 --> 00:01:58,360 +مثلا ال باليروبين ال باليروبين هذا مشهور اللي هو + +21 +00:01:58,360 --> 00:02:04,980 +الصفار اللي عادة بتم قياسه و بنقياسه لصفار الكلية + +22 +00:02:04,980 --> 00:02:08,900 +أحيانا بيسمو hematodein is the yellow breakdown + +23 +00:02:08,900 --> 00:02:12,480 +product of normal heme catabolism يعني من تكسر + +24 +00:02:12,480 --> 00:02:18,520 +الدم بيطلع اللي هي مادة ال باليروبين هذهأو الصفار + +25 +00:02:18,520 --> 00:02:22,180 +caused by the body clearance of aged red blood + +26 +00:02:22,180 --> 00:02:28,500 +cells يعني كل ما الخلايا الدموية قدمت تعرفوا الدم + +27 +00:02:28,500 --> 00:02:32,960 +والخلايا أشمالها في حالة التجدد فالحالة الخلايا + +28 +00:02:32,960 --> 00:02:37,050 +القديمة اللي هي بنسميها ال agedسيلز يعني الكبيرة + +29 +00:02:37,050 --> 00:02:42,130 +بتتغير الان لما بتتغير بدا تتكسر من نواتج تكسرها + +30 +00:02:42,130 --> 00:02:46,810 +البلوروبين فالبلوروبين موجود في ال principle + +31 +00:02:46,810 --> 00:02:53,560 +الحلقات اللي موجودة في إيش؟ في ال porphyrin ringمن + +32 +00:02:53,560 --> 00:02:58,800 +المراكبات المشهورة أيضا ال vitamin B12 اللي هو + +33 +00:02:58,800 --> 00:03:03,960 +cobalamin عادة ممكن نسميه اللي هو فيه ال cobalt + +34 +00:03:03,960 --> 00:03:09,460 +وفيه برضه حلقات ال birol water soluble vitamin + +35 +00:03:09,460 --> 00:03:15,580 +وإله يعني وظيفة أساسية في ال brain وفي ال nervous + +36 +00:03:15,580 --> 00:03:21,170 +system لابد يكون موجود مش موضوعنا طبعاانحو ال + +37 +00:03:21,170 --> 00:03:26,930 +biochemistryفي مركبات بسيطة برضه فيها ال by role + +38 +00:03:26,930 --> 00:03:32,170 +يعني هذا المركب أربعة هو عبارة عن insect pheromone + +39 +00:03:32,170 --> 00:03:36,370 +بتعرفوا ال pheromones اللي هي المواد اللي بتفرزها + +40 +00:03:36,370 --> 00:03:41,630 +الحشرات وبتكن من خلالها التواصل بشكل أساسي أكتر + +41 +00:03:41,630 --> 00:03:47,590 +شيء اللي هو التواصل الجنسي يعني لما بتكون الحشرات + +42 +00:03:47,590 --> 00:03:51,730 +في الحقول مش زي البشر الناس عارفة بعض لإن الحشرات + +43 +00:03:52,130 --> 00:03:58,410 +يعني المسافات واسعة كيف بدو يصير التكاتر عند + +44 +00:03:58,410 --> 00:04:01,950 +الحشرات كيف بدو الذكور والإناث يعرفوا بعض ففي + +45 +00:04:01,950 --> 00:04:05,690 +النهاية أحد الأصناف الذكور أو الإناث بيفرز كميات + +46 +00:04:05,690 --> 00:04:11,130 +بسيطة جدا من مواد شو بنسميها ال pheromones لأن هذه + +47 +00:04:11,130 --> 00:04:15,550 +المواد بتكون جاذبة للجنس الآخر لما اتعلموا العلماء + +48 +00:04:15,550 --> 00:04:20,530 +عرفوا ال pheromones بالظبط وعرفوا تحضيرها استفادوا + +49 +00:04:20,530 --> 00:04:25,760 +منها بإيش؟استفادوا منها بالمكافحة البيولوجية + +50 +00:04:25,760 --> 00:04:30,500 +للحشرات استفادوا منها بالمكافحة البيولوجية للحشرات + +51 +00:04:30,500 --> 00:04:35,880 +كيف؟ انه انا لو بعرف مثلا حشرة دودة القطن على سبيل + +52 +00:04:35,880 --> 00:04:40,780 +المثال ان الانثا بتفرز فيرومون معين وهذا الفيرومون + +53 +00:04:40,780 --> 00:04:45,920 +بيخلي الذكور ييجوا باتجاه الفيرومونحضروا الفيرومون + +54 +00:04:45,920 --> 00:04:48,800 +في المختبر، رأيك مركب؟ ممكن احضره مثلا انا في + +55 +00:04:48,800 --> 00:04:52,400 +المختبر، حضروه في المختبر و صاروا يبيعوه + +56 +00:04:52,400 --> 00:04:58,280 +للمزارعين، صاروا يبيعوه للمزارعين اجيبوا مثلا زي + +57 +00:04:58,280 --> 00:05:03,380 +عصا بهذا الشكل و حطوا عليها الفيرومون مع سمكو + +58 +00:05:03,380 --> 00:05:08,620 +يحطوه في الحقيقه الان كل الحشرات عادة بتتجذب هنا + +59 +00:05:08,620 --> 00:05:11,500 +على الفيرومون فمجرد ما بتيجي على هذا الفيرومون + +60 +00:05:11,500 --> 00:05:17,640 +بتلاقوها بتلتصق في العصا اللي فيها سمك مخلوق مع + +61 +00:05:17,640 --> 00:05:23,140 +نسبة من الاش الفيرومين فهم إذا أبادوا أحد الجنسين + +62 +00:05:23,140 --> 00:05:30,650 +معنى ذلك قضوا على إيش؟ على الحشرة بالمجملطبعا + +63 +00:05:30,650 --> 00:05:35,410 +البرولين هذا amino acid هو ال amino acid ال cyclic + +64 +00:05:35,410 --> 00:05:39,790 +المشهور اللي اسمه إبرولين ومهم في ال biochemistry + +65 +00:05:39,790 --> 00:05:45,790 +لأنه عادة ال turns بتصير من عنده في ال .. لما ناخد + +66 +00:05:45,790 --> 00:05:49,030 +ال protein structure ونقول ان ال protein structure + +67 +00:05:49,030 --> 00:05:53,070 +بيصير globular و بيصير turn من وين بتصير ال turns؟ + +68 +00:05:53,260 --> 00:05:57,400 +من عند البرولين لأنه لما بيعمل البروتين بيبطل فيه + +69 +00:05:57,400 --> 00:06:00,860 +انديهيدروجين فمنطقته مش فيه هيدروجين بوندي + +70 +00:06:00,860 --> 00:06:05,520 +النكوتين ربما اتكلمنا عنه لما حكينا عن البريدين + +71 +00:06:05,520 --> 00:06:11,020 +وبنفس الوقت هو عبارة عن بيريدين و بيروليدين + +72 +00:06:11,820 --> 00:06:16,420 +وموجودين على موقع تلاتة على البريدين فهو في + +73 +00:06:16,420 --> 00:06:22,460 +النهاية الكلويد من البريدين ومن البروليدين هذه كل + +74 +00:06:22,460 --> 00:06:26,580 +المركبات هي عبارة عن مركبات في الطبيعة في الحياة + +75 +00:06:26,580 --> 00:06:29,720 +في جسم الإنسان فيها بيرول ولذلك احنا بنقول ان ال + +76 +00:06:29,720 --> 00:06:38,660 +بيرول له أهمية خاصة مميزةالان لو اجينا لتحضير ال + +77 +00:06:38,660 --> 00:06:44,080 +buy roll في عندنا ال ignore synthesis شو هو ال + +78 +00:06:44,080 --> 00:06:49,200 +ignore synthesis؟الأساس لـ Knorr Synthesis كان + +79 +00:06:49,200 --> 00:06:53,880 +بيستعمل two equivalents من الـ Ethylacetoacetate + +80 +00:06:53,880 --> 00:06:58,380 +واحد بيحوله إلى أكزيم بعدين بيدوبه في Iglesia + +81 +00:06:58,380 --> 00:07:02,080 +الacetic من خلال أنه يدوب في Iglesia الacetic أسد + +82 +00:07:02,080 --> 00:07:05,320 +مع Sodium Nitrite بيصير أكزيم بيعمل reduction + +83 +00:07:05,320 --> 00:07:09,480 +للأكزيم لأمين وبعدين بتفعل مع الجزء التانيهذا + +84 +00:07:09,480 --> 00:07:14,720 +الكلام وصفي لو بدنا نشوف الكلام زي ما اتفقنا احنا + +85 +00:07:14,720 --> 00:07:19,140 +اكم equivalent بدي من الethyl acetoacetate اتنين + +86 +00:07:19,140 --> 00:07:25,460 +الان هاي واحد منهمهذا Ethyl Acetoacetate لو أتيت + +87 +00:07:25,460 --> 00:07:30,780 +فعلته مع ال Sodium Nitrate في وجود ال Acetic Acid + +88 +00:07:30,780 --> 00:07:34,580 +ال Sodium Nitrate في وجود ال Acetic Acid على ال + +89 +00:07:34,580 --> 00:07:39,800 +CH2 اللي موجودة هنا بيعمل أكزيم يمكن هذا يكون + +90 +00:07:39,800 --> 00:07:44,300 +بالنسبة لكم شوية تفاعل غريب لإن انتم متعودين على + +91 +00:07:44,300 --> 00:07:51,670 +الأكزيممن C double bond O مع الهيدروكس الأمين يعني + +92 +00:07:51,670 --> 00:07:58,510 +هذا الأكزيم اللي انتوا بتعرفوه لكن ربما مامرش + +93 +00:07:58,510 --> 00:08:06,730 +معاكم ان ال CH2 بتعمل أكزيم ال CH2 ال activated مع + +94 +00:08:06,730 --> 00:08:10,530 +ال sodium nitrite و ال acetic acid بتعمل أكزيم + +95 +00:08:11,110 --> 00:08:14,830 +خلّينا الآن ناخدوا as such أنها بتعمل أجزيم + +96 +00:08:14,830 --> 00:08:19,910 +التفاعل القديم تقريبا من 1874 و تفاصيله أنا + +97 +00:08:19,910 --> 00:08:26,430 +جبتلكوا يا حتى ما يضلوش غريب عليكم بس الآن نقبل أن + +98 +00:08:26,430 --> 00:08:32,990 +هذا الجزء الأول أنا عمل إيش أجزيم الأجزيم بال + +99 +00:08:32,990 --> 00:08:37,420 +reduction بصير أمينهذه سهلة reduction of oxygens + +100 +00:08:37,420 --> 00:08:40,880 +بتعطينا amines هذي مشهورة ان ال oxygens بال + +101 +00:08:40,880 --> 00:08:47,000 +reduction بتصير amines الآن بجيب الجزء التاني من + +102 +00:08:47,000 --> 00:08:52,020 +الاخ الأسد و أسد يعني لاحظوا هذا كان إيش الجزء + +103 +00:08:52,020 --> 00:08:56,540 +الأول صار oxygen و صار amine إذا كام جزء أنا + +104 +00:08:56,540 --> 00:09:03,960 +استعملتمن الـ ethyl acetoacetate جزيئين ودخلت الـ + +105 +00:09:03,960 --> 00:09:08,600 +NH2 من خلال أنه عملت أكزيم وعملت reduction إذا + +106 +00:09:08,600 --> 00:09:13,100 +وصلنا لهذه المرحلة سار الأمر سهل لأن هذه عندني الـ + +107 +00:09:13,100 --> 00:09:17,220 +nucleophile وهذه عندني هنا الـ nucleophile طبعا في + +108 +00:09:17,220 --> 00:09:22,200 +ال conditions تبع التفاعل هذه أنا فيه عندىموجب in + +109 +00:09:22,200 --> 00:09:26,480 +principle وموجب مش ضايق الغير نكمل ال cyclization + +110 +00:09:26,480 --> 00:09:31,260 +هنا بيصير C double bond N إمين إنامين وهذه هتسكر + +111 +00:09:31,260 --> 00:09:37,100 +OH مع H تعمل elimination لاحظوا أن هذا التفاعل + +112 +00:09:37,100 --> 00:09:43,060 +استعمل two equivalents من الethyl acetoacetate + +113 +00:09:43,060 --> 00:09:47,590 +اللي هي لو أنا أتيت أطلعك اللي في أطراف المثلو ال + +114 +00:09:47,590 --> 00:09:50,330 +a star group هاي one equivalent و هاي two + +115 +00:09:50,330 --> 00:09:53,990 +equivalent اتجوا متعاكسين و لذلك بطريقة او باخره + +116 +00:09:53,990 --> 00:09:58,370 +فيه ال symmetry يعني هاي .. هاي ال ethyl aceto + +117 +00:09:58,370 --> 00:10:02,090 +acetate و هاي ال ethyl aceto acetate و اتجت ال + +118 +00:10:02,090 --> 00:10:07,250 +nitrogen ازياد عليهم من وين؟ من ال oxime اللي + +119 +00:10:07,250 --> 00:10:13,410 +عملناله reduction ل ..للأمين فهو فعلا two + +120 +00:10:13,410 --> 00:10:16,350 +equivalents من الethyl acetoacetate هاي نشوفناهم + +121 +00:10:16,350 --> 00:10:21,810 +كيف اجوا و كيف عملوا الجزاء مع ال nitrogen اللي + +122 +00:10:21,810 --> 00:10:25,290 +اجت من الأكزيم هذا اللي بنسميه Knorr synthesis + +123 +00:10:25,290 --> 00:10:31,390 +طبعا ال nitrogen of ألفات ال carbon atom اللي هي + +124 +00:10:31,390 --> 00:10:35,710 +هذه ال carbon ال CH2 نعملها نيتروزو أفعلها من + +125 +00:10:35,710 --> 00:10:40,690 +نيتروزو و نيتروزو أخد الأكزيم توتمر منههذا الـ + +126 +00:10:40,690 --> 00:10:46,690 +Nitrosation مشهور تفاعل أول من عمله و اكتشفه + +127 +00:10:46,690 --> 00:10:55,330 +Victor Meyer في الـ 1873 و 1874 يعني التفاعل قديم + +128 +00:10:55,330 --> 00:11:02,260 +تفاصيله موجود هنا ككلام و موجود هناكمعادلات بدي + +129 +00:11:02,260 --> 00:11:06,080 +أمشي عليها بسريع لإن هي general organic chemistry + +130 +00:11:06,080 --> 00:11:10,520 +لكن الفكرة أنه احنا لما نبدأ بال sodium nitrite + +131 +00:11:10,520 --> 00:11:17,240 +بالacetic acid بنعمل protonation فصار عندى nitrous + +132 +00:11:17,240 --> 00:11:21,140 +acid مع sodium acetate كمان protonation صار عندى + +133 +00:11:21,140 --> 00:11:28,270 +الايون الموجب هذا الايون الموجب بيفقد الميهفبصير + +134 +00:11:28,270 --> 00:11:32,730 +عنده ال Nitroso group يعني هذا لما يفقد الميه + +135 +00:11:32,730 --> 00:11:38,990 +بيصير عنده ال N O positive الان لو اتيت و اتطلعت + +136 +00:11:38,990 --> 00:11:44,390 +على هذا الجزيه ال ethyl acetoacetate انا لسه مخليه + +137 +00:11:44,390 --> 00:11:51,140 +اتريح ال ethyl acetoacetate اخد منهالانول اخد منه + +138 +00:11:51,140 --> 00:11:58,480 +الانول form و افعله مع النيتروزو فهدد الالكترونات + +139 +00:11:58,480 --> 00:12:03,620 +بهذا الشكل بهذا الشكل بتتحرك فال double bond + +140 +00:12:03,620 --> 00:12:08,540 +هتهاجم على الان الموجب هيصير عندى هذا لو عملت له + +141 +00:12:08,540 --> 00:12:12,940 +tautomerism + +142 +00:12:12,940 --> 00:12:21,910 +هيصير عندى OH طبعا هيكون زائد ايشفي النهاية ال + +143 +00:12:21,910 --> 00:12:26,630 +acidic acid يعني هيفقد لما هذا التفاعل تم في + +144 +00:12:26,630 --> 00:12:32,270 +النهاية هيفقد ايش H مع ال OAC يعني لاحظوا ان هذا + +145 +00:12:32,270 --> 00:12:37,030 +التفاعل كله هذا التفاعل كله اخد من هنا ايش ال + +146 +00:12:37,030 --> 00:12:43,610 +nitrogen لكن فقد ايضا H H مع ال OAC + +147 +00:12:46,110 --> 00:12:51,390 +أسيتك أسد و إجت ال نيتروز هنا و اللي كان هتحس لو + +148 +00:12:51,390 --> 00:12:56,430 +نفذته بهدوء أنه في اتش فقدت ليا هتفقد اتش و هتروح + +149 +00:12:56,430 --> 00:13:01,150 +مع ايش مع الايون السالب اللي هنا على شكل ايه اسيتك + +150 +00:13:01,150 --> 00:13:05,410 +أسد واضح يعني هتفقد اتش و هتروح مع الايون السالب + +151 +00:13:05,410 --> 00:13:10,630 +واضح ليش لأن انتوا لو طلعتوا على هذا كمحصلة هذا + +152 +00:13:10,630 --> 00:13:15,870 +كمحصلة كم اتش موجودة فيهوحدة هذا كان محصلة كان + +153 +00:13:15,870 --> 00:13:20,750 +فيها نقاش كان فيها نقاش يعني في نقاش فقدت هذه ال + +154 +00:13:20,750 --> 00:13:25,770 +نقاش اللي فقدت وين راحت مع ال acidic واضح على أي + +155 +00:13:25,770 --> 00:13:31,690 +حال هذا شكل عام حتى ما تستغربوش هذا التفاعل لكن في + +156 +00:13:31,690 --> 00:13:35,770 +شكل عام ال activated hydrogen atom مع ال sodium + +157 +00:13:35,770 --> 00:13:41,930 +nitrate بتصير ايش اكزيم هذا تفاعل قديم من ال 1800 + +158 +00:13:42,920 --> 00:13:47,860 +واضح؟ ال CH2 الاكتفات جامب إيستر و جامب كيتر و + +159 +00:13:47,860 --> 00:13:54,880 +جامب نيترالز و جامب نيترو شغل كثير موجود عليها و + +160 +00:13:54,880 --> 00:14:00,060 +كله بندرج تحت المسمى العام اللي هو Nitrosation of + +161 +00:14:00,060 --> 00:14:05,510 +Aliphatic Carbon Atoms بتعمل إيش عنده؟أكزيم الآن + +162 +00:14:05,510 --> 00:14:10,370 +إذا صار عند الأكزيم بعد هيك ال reduction سهل و + +163 +00:14:10,370 --> 00:14:13,970 +استكمال التفاعل و فهمه بتكون عملية أيش سهلة يعني و + +164 +00:14:13,970 --> 00:14:18,450 +ربما أصعب شيء هنا للي بيكون بعرفش إنها CH2 بتعمل + +165 +00:14:18,450 --> 00:14:22,250 +أكزيم مع ال sodium nitrite في الacetic acid هذا + +166 +00:14:22,250 --> 00:14:25,830 +اللي احنا ذكرنا له تفاصيله إنما ال reduction و + +167 +00:14:25,830 --> 00:14:28,170 +بعدين هنا ال nucleophile ال electrophile ال + +168 +00:14:28,170 --> 00:14:31,110 +nucleophile كل هذا أمر بسيط + +169 +00:14:32,980 --> 00:14:36,460 +التحضير التاني بالك Nor Synthesis of Birol هذا + +170 +00:14:36,460 --> 00:14:40,100 +بيعتمد ان احنا نستعمل one four-dicarbonyl compound + +171 +00:14:40,100 --> 00:14:45,280 +one two three four الان مع ال ammonia مع ال + +172 +00:14:45,280 --> 00:14:49,560 +ammonia او AME derivative هيصير C double bond N + +173 +00:14:49,560 --> 00:14:54,960 +والان مرة تانية تسكل على ال oxygen فبصير Birol ف + +174 +00:14:54,960 --> 00:15:00,420 +eight and ten C double bond O على موقع 14 مع ال + +175 +00:15:00,420 --> 00:15:05,680 +nitrogen شو هيعطوني؟Birol الان هذا الكلام بيذكركوا + +176 +00:15:05,680 --> 00:15:10,500 +بإيش؟ + +177 +00:15:10,500 --> 00:15:15,420 +انه نيتروجين مع باي كربونيل كومباوند هانا قاعدة + +178 +00:15:15,420 --> 00:15:22,080 +بتعطي بيرول و هذا إيش اسمه؟ بالكنورد سينثيسيس of + +179 +00:15:22,080 --> 00:15:29,760 +بيرول الفيورين هناخد التنتين هدولة باسد ونخلي + +180 +00:15:29,760 --> 00:15:35,950 +أكسجين يتسكر عادة صحوالتيوفين هناخد التنتين هدولة + +181 +00:15:35,950 --> 00:15:39,870 +مع سلفة ونخلي واحدة تسكر على التانية يعني من ال + +182 +00:15:39,870 --> 00:15:43,570 +one four-dicarbonyl compound انا هحضر ال بيرول من + +183 +00:15:43,570 --> 00:15:48,430 +خلاله واتفاعل مع ال nitrogen هحضر الفيوران و هحضر + +184 +00:15:48,430 --> 00:15:53,570 +كمان التيوفين لكن برضه ال die-carbonyl compound مع + +185 +00:15:53,570 --> 00:16:01,880 +ال nitrogen بتذكرني بإيش؟بالبريدين الو لو كان عندي + +186 +00:16:01,880 --> 00:16:06,480 +one-five-dicarbonyl compound كنت أحصل على بريدين و + +187 +00:16:06,480 --> 00:16:11,680 +كان إيش اسم التفاعل؟ لأ ارجعوا عليك ارجعوا على + +188 +00:16:11,680 --> 00:16:16,760 +البريدين لما كان عندي one-five-dicarbonyl compound + +189 +00:16:16,760 --> 00:16:20,560 +عادي مكتوب reaction of ammonia أزاق ال one-five + +190 +00:16:20,560 --> 00:16:23,020 +-dicarbonyl one-five-dicarbonyl طيب بالكنور + +191 +00:16:23,020 --> 00:16:30,710 +synthesis of بريدين ماتسماش بالكنور؟واضح؟ فال 14 + +192 +00:16:30,710 --> 00:16:38,070 +بيعطو by role ال 15 بيعطو by ready وزي ما قلنا انه + +193 +00:16:38,070 --> 00:16:43,510 +من ال 14 dicarbonyl compound بيمكن احضر ال by role + +194 +00:16:43,510 --> 00:16:48,550 +و ال furan و الثيوفين و مرة جيبنا سؤال starting + +195 +00:16:48,550 --> 00:16:53,350 +from 14 dicarbonyl compound how can you prepare by + +196 +00:16:53,350 --> 00:16:57,010 +role, furan, and theophine مع الأمير بنحضر ايش؟ + +197 +00:17:00,020 --> 00:17:05,260 +الان لو اجينا ل synthesis تاني لل by role hence by + +198 +00:17:05,260 --> 00:17:11,260 +role synthesis الهنس by role synthesis بيشبه + +199 +00:17:11,260 --> 00:17:17,620 +الفيسبينري فيوران سينثيسي بيشبه الفيسبينري فيوران + +200 +00:17:17,620 --> 00:17:21,620 +سينتيسي خلينا نقول كيف بيشبه الفيسبينري فيوران + +201 +00:17:21,620 --> 00:17:27,010 +سينتيسي احنا لو أخدناهذا البيتا كيتو إيستر البيتا + +202 +00:17:27,010 --> 00:17:35,310 +كيتو إيستر البيتا كيتو إيستر البيتا كيتو إيستر + +203 +00:17:35,310 --> 00:17:36,510 +البيتا كيتو إيستر البيتا كيتو إيستر البيتا كيتو + +204 +00:17:36,510 --> 00:17:41,610 +إيستر البيتا كيتو إيستر البيتا كيتو إيستر البيتا + +205 +00:17:41,610 --> 00:17:41,950 +كيتو إيستر البيتا كيتو إيستر البيتا كيتو إيستر + +206 +00:17:41,950 --> 00:17:43,390 +البيتا كيتو إيستر البيتا كيتو إيستر البيتا كيتو + +207 +00:17:43,390 --> 00:17:44,390 +إيستر البيتا كيتو إيستر البيتا كيتو إيستر البيتا + +208 +00:17:44,390 --> 00:17:44,390 +كيتو إيستر البيتا كيتو إيستر البيتا كيتو إيستر + +209 +00:17:44,390 --> 00:17:49,730 +البيبيتا كيتو إيستر زائد ألفة هالو كيتون هدولة + +210 +00:17:49,730 --> 00:17:54,830 +اتنين بيعطوني فيوران وهذا ال synthesis هو فيست + +211 +00:17:54,830 --> 00:18:00,630 +بيناري فيوران synthesis أخدنا تفصيله فيست بيناري + +212 +00:18:00,630 --> 00:18:06,170 +فيوران synthesis الآن لو خلطنا معهم أمونيا بيصير + +213 +00:18:06,170 --> 00:18:11,350 +يعطيني إيش بريدين يعني بيتا كيتو إيستر ألفة هالو + +214 +00:18:11,350 --> 00:18:18,090 +كيتونو Ammonia بيصير يعطيني عفوا By role الآن في + +215 +00:18:18,090 --> 00:18:22,610 +النهاية اللي خلط التلاتة مابضمنش انه كل مرة في + +216 +00:18:22,610 --> 00:18:25,050 +الأول بده تتفاعل ال ammonia زي ما هنشوف في + +217 +00:18:25,050 --> 00:18:30,790 +التفاصيل و بعدين يكتمل التفاعل و بالتالي ممكن بعض + +218 +00:18:30,790 --> 00:18:35,990 +هذه الجزيات معادي تعطي ايش؟ Furan و لذلك لو اجاكم + +219 +00:18:35,990 --> 00:18:44,020 +سؤال علّل انه في هذا ال synthesis بيطلع عندىFuran + +220 +00:18:44,020 --> 00:18:49,140 +as a by-product بدنا نكون إيش؟ فاهمين طب على وقتنا + +221 +00:18:49,140 --> 00:18:54,660 +نفصله هذا ال synthesis كيف بيطلع ال by-role إحنا + +222 +00:18:54,660 --> 00:18:59,300 +أخدنا كيف بيطلع ال Furan و ممكن نرجعله كيف بيطلع + +223 +00:18:59,300 --> 00:19:05,060 +ال by-role ال C double bond O مع ال NH2 هتعمل إمين + +224 +00:19:05,060 --> 00:19:09,780 +إنامين إنامين هى عملت الإنامين الآن لما بداتيش + +225 +00:19:09,780 --> 00:19:17,260 +تتفاعل معالـ α-هالو-كيتون لما تتفاعل مع الـ α-هالو + +226 +00:19:17,260 --> 00:19:22,300 +-كيتون ممكن تتخيل بهذا الشكل وهذه تتحل محل + +227 +00:19:22,300 --> 00:19:26,320 +الـClone الـ another substitution reaction، هذه + +228 +00:19:26,320 --> 00:19:29,780 +نعملت الـ bond، دل عنده نيتروجين مع السيطرة بالـ + +229 +00:19:29,780 --> 00:19:35,580 +bond Oهتعمل ال N مش هتقدر تعمل C double bond N + +230 +00:19:35,580 --> 00:19:40,100 +يعني هتعمل N واحدة لأن مثلا هتعمل R حتى لو عملت C + +231 +00:19:40,100 --> 00:19:45,060 +double bond N في حال أن هذه كانت Hydrogen إمين + +232 +00:19:45,060 --> 00:19:54,140 +هتصير إيش إنامينواضحة الفكرة؟ الآن في التفاعل اللي + +233 +00:19:54,140 --> 00:19:57,380 +كان عندنا .. في التفاعل اللي كان عندنا اللي هو تبع + +234 +00:19:57,380 --> 00:20:02,220 +الفيوران، بس اللي كنا نسويه أنه إحنا مش محاولين + +235 +00:20:02,220 --> 00:20:11,080 +هذهأه ماكناش محاولين هذه ل .. ل nitrogen كانت + +236 +00:20:11,080 --> 00:20:15,720 +double bond؟ أه و بالتالي كان اتم عنده الإغلاق + +237 +00:20:15,720 --> 00:20:20,220 +عليها بنرجع لالفايس بين refluent synthesis + +238 +00:20:20,220 --> 00:20:25,740 +بالتفصيل أخدتوا انتوا كيف كان نبدأ من هنا نكوّن ال + +239 +00:20:25,740 --> 00:20:26,100 +ion + +240 +00:20:38,980 --> 00:20:45,510 +الخلاصة ان هدولةالبيتا كيتو إيستر ألف هالو كيتو + +241 +00:20:45,510 --> 00:20:50,610 +لحالهم بيعطوني فيوران لو حطيت معهم أمونيا صار هذا + +242 +00:20:50,610 --> 00:20:55,710 +التفاعل في البداية امين انامين وبعدين اعملنا هذا + +243 +00:20:55,710 --> 00:21:02,260 +التفاعل كنيكليوفايل إلكتروفايل بيعطيني إيش؟بايرول + +244 +00:21:02,260 --> 00:21:06,860 +لو اجيت انا لل reactions of بايرول ال reactions ال + +245 +00:21:06,860 --> 00:21:11,820 +reactions of بايرول في عندى ممكن يتم reactions على + +246 +00:21:11,820 --> 00:21:16,080 +ال nitrogen و ممكن يتم في شكل اساسي electrophilic + +247 +00:21:16,080 --> 00:21:18,300 +substitution على ال ring يعني بدى اصنف ال + +248 +00:21:18,300 --> 00:21:25,320 +reactions نوعين على ال nitrogen و علىالان ربما + +249 +00:21:25,320 --> 00:21:31,000 +كلكم اتذكرين كلمة انه على ال nitrogen هذا اللون + +250 +00:21:31,000 --> 00:21:36,660 +bear اللي موجود على ال by roll نشيط انه يتفاعل مع + +251 +00:21:36,660 --> 00:21:41,780 +الخارج ولا لأ؟ ليش؟ لأن هذا جزء من ال aromatic + +252 +00:21:41,780 --> 00:21:45,560 +system طب لما انا بدي ال nitrogen يتفاعل مع الخارج + +253 +00:21:45,560 --> 00:21:50,710 +بدي اعمل عملية تحضيرية في الأولإيش العملية + +254 +00:21:50,710 --> 00:21:54,210 +التحضيرية اللي بدي أعملها عشان تمت فاعل على + +255 +00:21:54,210 --> 00:22:02,310 +الـNitrogena؟ بدي أجي لهذه الـNH بالمثل أسحب منها + +256 +00:22:02,310 --> 00:22:10,120 +الـH أخليها N-واجهته بيصير التفاعل من خلال زوجة + +257 +00:22:10,120 --> 00:22:13,520 +الإلكترونات اللى هتتبع الـ minus إذا أنا كخطوة + +258 +00:22:13,520 --> 00:22:17,840 +أولى للتفاعل مع ال nitrogen بعمل ال methylation of + +259 +00:22:17,840 --> 00:22:21,500 +بيرول يعني ممكن أفاعل مع ال sodium مع ال potassium + +260 +00:22:21,500 --> 00:22:25,540 +مع ال دمد أو البوتاسامد ب liquid ammonia في كل + +261 +00:22:25,540 --> 00:22:31,160 +الأحوال هدولة هيصحبوا ال hydrogen هيعملولي إيش؟الـ + +262 +00:22:31,160 --> 00:22:34,640 +minus الأن الأن الـ minus هاي في عند أنا زوج + +263 +00:22:34,640 --> 00:22:38,080 +إلكترونات part of the aromatic system وفي عندي زوج + +264 +00:22:38,080 --> 00:22:46,850 +إلكترونات جاهز إنه يتفاعلواضح؟ هذا زوج الإلكترونات + +265 +00:22:46,850 --> 00:22:50,210 +اللي جاهز انه يتفاعل هو اللي بعد هيك يتفعل مع الـ + +266 +00:22:50,210 --> 00:22:54,050 +Electrophile فانا مش الهدف عندى ان اعمل ال minus و + +267 +00:22:54,050 --> 00:22:58,570 +جمبها K plus يعني Sodium Salt of Birol لأ أنا بدي + +268 +00:22:58,570 --> 00:23:03,270 +ال Salt هذا بعد هيك اروح افعله مع إيش؟ مع ال + +269 +00:23:03,270 --> 00:23:06,770 +Electrophile الآن بنفس المنطقة لو اعملت Greenyard + +270 +00:23:06,770 --> 00:23:11,510 +Reagent برضه هيعندي زوج الإلكترونات الأصلي وهي هذا + +271 +00:23:11,510 --> 00:23:17,190 +الزوج اللي هيكون إيش؟جاز انه يتفاعد بعمل green + +272 +00:23:17,190 --> 00:23:21,930 +yard reagent على ال nitrogen مع المغنيسيام بعمل + +273 +00:23:21,930 --> 00:23:26,510 +شبيه بال green yard reagent MgBr ليش؟ لأن ال green + +274 +00:23:26,510 --> 00:23:31,510 +yard أساسا على carbon MgBr أنا عملته على إيش؟ على + +275 +00:23:31,510 --> 00:23:36,590 +ال nitrogen مع ال lithium حتى لو كان covalent هو + +276 +00:23:36,590 --> 00:23:40,090 +عند زوجي الإلكترونات اللي هنا لكن في النهاية + +277 +00:23:40,090 --> 00:23:45,320 +هستفيد من إيش أنا؟زوج الإلكترونات اللي على + +278 +00:23:45,320 --> 00:23:49,920 +الـNitrogen الآن هذا زوج الإلكترونات اللي على + +279 +00:23:49,920 --> 00:23:55,280 +الـNitrogen بفعله أنا مع الـElectrophile بيشتغل + +280 +00:23:55,280 --> 00:23:59,140 +كالـNucleophile يعني مثلا لو فعلته مع الـMethyl + +281 +00:23:59,140 --> 00:24:03,880 +Iodide بيجي بيهاجم و بيحل محل اليوت هيعملت + +282 +00:24:03,880 --> 00:24:08,130 +Methylationلاحظوا معاه لو قلتلكوا how can you + +283 +00:24:08,130 --> 00:24:13,450 +prepare الميثل بيرول و ايجي حد قاللي بهذا الشكل + +284 +00:24:13,450 --> 00:24:21,950 +بدي اخد ال بيرول مباشرة + +285 +00:24:21,950 --> 00:24:28,410 +مع الميثل ايودايد مش حياتيفانا بعمل بالصوديوم بخلي + +286 +00:24:28,410 --> 00:24:33,010 +هذه ال minus و ال minus مع ال methyl iodide واضحة + +287 +00:24:33,010 --> 00:24:39,070 +الفكرة اذا صار عندى by role negative ion بعدين + +288 +00:24:39,070 --> 00:24:42,570 +بفعلها هاي كمان مرة مع ال methyl iodide اللي هو + +289 +00:24:42,570 --> 00:24:46,190 +هذا اللي مع المغنيسيون الشبيه بال green يعني نفس + +290 +00:24:46,190 --> 00:24:49,190 +الاشي عمل methylation و ال yield زي ما انتوا + +291 +00:24:49,190 --> 00:24:53,250 +شايفين ايش معله ممتازة كل هذه التفاعلات على اي ذرة + +292 +00:24:54,080 --> 00:24:59,920 +عال Nitrogen لكن لابد لها من خطوة تحضيرية هاي هنا + +293 +00:24:59,920 --> 00:25:04,040 +مع ال Acetyl ال Acetyl is a nucleophile ولا لأ + +294 +00:25:04,040 --> 00:25:10,220 +CH3C double bond OCl طبعا هيكون التفاعل تفاعل + +295 +00:25:10,220 --> 00:25:15,700 +Substitution تحط ل Acetyl عال Nitrogen الآن هنا + +296 +00:25:15,700 --> 00:25:19,940 +قملت كمان Electrophilic Substitution ع الحلقة لكن + +297 +00:25:19,940 --> 00:25:25,390 +هذا التفاعل عال Nitrogenواضح؟ هاي مع ال بنزويل + +298 +00:25:25,390 --> 00:25:33,110 +بنزويل كلورايد فينيل C double bond O Cl مع السالب + +299 +00:25:33,110 --> 00:25:37,390 +اللي هنا بس عمل على ال nitrogen ماعملش على الحلقة + +300 +00:25:38,140 --> 00:25:42,360 +واضح يعني هنا تم إبدال عادي عن نيتروجين و لحظه + +301 +00:25:42,360 --> 00:25:45,840 +كمان Electrophilic substitution على الحلقة هنا بس + +302 +00:25:45,840 --> 00:25:51,300 +تم عن نيتروجين في نهاية الكيميا إيش علم تجريب يعني + +303 +00:25:51,300 --> 00:25:54,980 +شو إفرجت ال acid ال chloride عن ال benzoyl + +304 +00:25:54,980 --> 00:25:59,060 +chloride لكن مع ال acid ال chloride طلع عندى إبدال + +305 +00:25:59,060 --> 00:26:03,080 +على الحلقة Electrophilic substitution مع ال + +306 +00:26:03,080 --> 00:26:06,120 +benzoyl chloride بس الإبدال تم على ال nitrogen + +307 +00:26:06,120 --> 00:26:11,310 +الآنالنوع التاني من تفاعلات ال by role اللي هو ال + +308 +00:26:11,310 --> 00:26:15,350 +electrophilic substitution عادة ال electrophilic + +309 +00:26:15,350 --> 00:26:20,710 +substitution يتم على موقعإتنين لو عملنا resonance + +310 +00:26:20,710 --> 00:26:23,330 +structures حتى لو اعتبرنا ان هذا resonance + +311 +00:26:23,330 --> 00:26:27,010 +structure يعني غير محبب اللي فيه الموجب على ال + +312 +00:26:27,010 --> 00:26:30,090 +nitrogen على موقع اتنين عندي two resonance + +313 +00:26:30,090 --> 00:26:33,910 +structures على موقع تلاتة عندي one resonance + +314 +00:26:33,910 --> 00:26:37,310 +structure ولذلك ال substitution بتمع ال birol على + +315 +00:26:37,310 --> 00:26:40,970 +موقع اتنين بيضل متذكرين انه في ال electrophilic + +316 +00:26:40,970 --> 00:26:44,950 +substitution بشكل عام ال birol بتفاعل أسرع من + +317 +00:26:44,950 --> 00:26:49,080 +الفيوران أسرع من الفتيوفينو كلهم أسرع من البنزين + +318 +00:26:49,080 --> 00:26:54,200 +يعني كل هذه الحلقات أسرع من البنزين طبعا ممكن حد + +319 +00:26:54,200 --> 00:26:57,060 +يقول ليش أسرع من البنزين لأن فيهم في النهاية ال + +320 +00:26:57,060 --> 00:27:00,240 +electronegative atom بتعطي إلكترونات بزيادة و + +321 +00:27:00,240 --> 00:27:04,280 +التفاعل electrophilic substitution يعني سالب عموجة + +322 +00:27:04,280 --> 00:27:10,000 +فهذه الذرات اللي بتعطي إلكترونات زيادة هتزيد سرعة + +323 +00:27:10,000 --> 00:27:15,520 +إيش؟التفاعل الآن الأمثلة زي ما احنا شايفين كتير + +324 +00:27:15,520 --> 00:27:19,320 +نيتراشن، كلوريناشن، جروميناشن، وويلزمير إذا + +325 +00:27:19,320 --> 00:27:22,640 +متذكرينه الـformal group لاحظوا في معظم الحلات على + +326 +00:27:22,640 --> 00:27:26,020 +موقع اتنين، اتنين وخمسة، اتنين، اتنين، اتنين + +327 +00:27:26,020 --> 00:27:29,700 +وخمسة، اتنين وخمسة في مرة يمكن طلع على نسبة تلاتة + +328 +00:27:29,700 --> 00:27:35,100 +بنسبة يعني عدم فال substitution بشكل أساسي بيكون + +329 +00:27:35,100 --> 00:27:38,520 +mono substitution على اتنين مرات بيصير على + +330 +00:27:52,370 --> 00:27:56,190 +البيرول كمان بيعمل + +331 +00:27:57,940 --> 00:28:02,400 +cycloaddition reactions with dichlorocarbine البعض + +332 +00:28:02,400 --> 00:28:05,640 +هييجي يقول من وين ال dichlorocarbine الناس اللي + +333 +00:28:05,640 --> 00:28:09,340 +أخدوا Reimer-Thiemann reaction اللي هو ال + +334 +00:28:09,340 --> 00:28:12,200 +chloroform بال إيثار في ال base بيعمل + +335 +00:28:12,200 --> 00:28:17,920 +dichlorocarbine يعني carbine بهذا الشكل carbon Cl + +336 +00:28:17,920 --> 00:28:23,350 +Clبهذا الشكل وهذا الـ Carbine لما يجي يتفاعل هنا + +337 +00:28:23,350 --> 00:28:27,770 +يعمل insertion هنا في نابط حول لإيش؟ لالديهايد + +338 +00:28:27,770 --> 00:28:31,150 +اللي بده يتذكر هذا التفاعل يمكن التفاعل بهذا الشكل + +339 +00:28:31,150 --> 00:28:38,000 +يبدو إيش؟غريب لكن لو انتوا تذكرتوا التفاعل في ال + +340 +00:28:38,000 --> 00:28:43,540 +organic اللي هو اسمه Reimer-Thiemann reaction + +341 +00:28:43,540 --> 00:28:47,160 +Reimer-Thiemann reaction هاي كنا عالفينول مع ال + +342 +00:28:47,160 --> 00:28:51,020 +chloroform بيصير هنا Dichlorocarbine وبعدين بيصير + +343 +00:28:51,020 --> 00:28:53,960 +له reduction لل aldehyde هاي تفاصيل ال Reimer + +344 +00:28:53,960 --> 00:28:58,190 +-Thiemann reaction مر عليكوا كاملا في وين؟في ال + +345 +00:28:58,190 --> 00:29:03,310 +organic synthesis فمافيش داعي نرجعله فتكوين ال + +346 +00:29:03,310 --> 00:29:07,410 +formal من هذا التفاعل هو مشابه ل Raymartimer + +347 +00:29:07,410 --> 00:29:12,730 +reaction أمر طبيعي لكن ربما الأمر الغريب أنه يجي + +348 +00:29:12,730 --> 00:29:19,070 +يتكون عندكم إيشاه يتكون عند بيردين لكن اذا انتوا + +349 +00:29:19,070 --> 00:29:22,530 +قولتوا انه في عندكم في النهاية Dichlorocarbine + +350 +00:29:22,530 --> 00:29:28,110 +يعني Carbon مع Chlorine هنا وعملوا Cycloaddition + +351 +00:29:28,110 --> 00:29:34,190 +اكسروا ال ring من هنا كده ايش صار عندى نيتروجين + +352 +00:29:34,190 --> 00:29:40,780 +كاربون كاربون حملة CL ومطلعقتش CLعشان هيك تفسير + +353 +00:29:40,780 --> 00:29:45,020 +هذا الـ 3-chloropyridine الـ by-product بتم من + +354 +00:29:45,020 --> 00:29:49,540 +خلال إن أنا أقول إن الـ dichlorocarbine عمل cycle + +355 +00:29:49,540 --> 00:29:54,060 +addition على الـ double bond اللي هنا و عمل ring + +356 +00:29:54,060 --> 00:29:58,700 +opening مرات سألنا الطلاب كيف بتفسر إنه بهذا + +357 +00:29:58,700 --> 00:30:04,800 +التفاعل طلع عنده 3-chloropyridine بدا أقول cycle + +358 +00:30:04,800 --> 00:30:09,280 +addition of dichlorocarbine followed byRing + +359 +00:30:09,280 --> 00:30:15,120 +Opening واضح الكلام و كل قصة Dichlorocarbine يعني + +360 +00:30:15,120 --> 00:30:20,760 +قصة Trimer reaction هي تقريبا نفس التفسير مع مركب + +361 +00:30:20,760 --> 00:30:24,880 +تاني جيبنا Dichlorocarbine من مصدر تاني و بعدين + +362 +00:30:24,880 --> 00:30:29,980 +Ring Opening عملناه و بيوضحوا تماما و طلع برضه 3 + +363 +00:30:29,980 --> 00:30:34,480 +-chloropyridine نفس فكرة ال Ring Expansion نفس + +364 +00:30:34,480 --> 00:30:40,210 +فكرةالـ Dichlorocarbine اللي بيعمل الـ Chelotropic + +365 +00:30:40,210 --> 00:30:46,990 +Cycloaddition على الـ Double Bond الآن الـ Diels + +366 +00:30:46,990 --> 00:30:50,430 +-Alder Reaction الـ By Rules بشكل عام من أضعف + +367 +00:30:50,430 --> 00:30:53,710 +الحلقات اللي بتعمل الـ Diels-Alder Reaction طبعا + +368 +00:30:53,710 --> 00:30:56,690 +لما بتعمل ال Diels-Alder Reaction هتعمل بصفتها + +369 +00:30:56,690 --> 00:31:01,730 +إيش؟deals يعني هاي جزء الداين اللي فيها، هاي جزء + +370 +00:31:01,730 --> 00:31:04,750 +الداين، لكن في بعض الأمثلة هاي + +371 +00:31:04,750 --> 00:31:07,790 +unethoxycarbonylbirol + +372 +00:31:07,790 --> 00:31:11,990 +مثلا مع ال die مثل أستيلين، diecarboxylate يعني + +373 +00:31:11,990 --> 00:31:16,250 +هان أستيلين، إذا أنا لما بدأ أعمل deals ألدر هنا، + +374 +00:31:16,250 --> 00:31:21,510 +بدأ أجي على هذه النقطةوعلى هذا النقطة و اعمل + +375 +00:31:21,510 --> 00:31:26,270 +الحلقة السداسية واضح؟ لاحظوا هاي جزء ال VIROL وما + +376 +00:31:26,270 --> 00:31:30,990 +زال حامل ال NCO2 إثل و هاي هذا الجزء اللي إجا من + +377 +00:31:30,990 --> 00:31:40,010 +ال Acetylene هاي جزء ال Acetylene و هاي جزء ال + +378 +00:31:40,010 --> 00:31:44,610 +VIROL واضح؟ وعملنا حلقة سداسية واحد، اتنين، تلات، + +379 +00:31:44,610 --> 00:31:50,010 +اربع، خمس، ستة هذه الحلقة السداسية كام Vibon؟واحدة + +380 +00:31:50,010 --> 00:31:55,930 +من ال deals ألدر واحدة من ال triple bond فقط بيلزم + +381 +00:31:55,930 --> 00:32:02,010 +أن أشي نكونيعني ان نفذ هذا الكلام نتعود عليه نرسمه + +382 +00:32:02,010 --> 00:32:07,590 +بجلم درصاص بهدوء عشان الصين عندنا تدريب ايضا ال by + +383 +00:32:07,590 --> 00:32:11,790 +role ممكن يعمل 2 plus 2 cycle addition يعني هاي by + +384 +00:32:11,790 --> 00:32:18,450 +role مع كيتون في النهاية بتطلعلي هذا المركب طب انا + +385 +00:32:18,450 --> 00:32:22,750 +بدى افسر كيف اتكون هذا المركب خلينا نفترض ان هو + +386 +00:32:22,750 --> 00:32:27,940 +عمل في الأول2 plus 2 cycle addition و بعدين هنا + +387 +00:32:27,940 --> 00:32:33,360 +عمل ring opening يعني هذا 2 plus 2 cycle addition + +388 +00:32:33,360 --> 00:32:38,420 +عطاني حلقة رباعية بعد هيك لو حركنا الإلكترونات + +389 +00:32:38,420 --> 00:32:43,240 +بشكل معين هيصير عندنا ال O minus ال H اللي هنا + +390 +00:32:43,240 --> 00:32:54,960 +هنبدأ من عندها هاي ال O minus OH واضح؟ يعني هذهالـ + +391 +00:32:54,960 --> 00:32:58,800 +bond هنا صارت double bond وهذه صارت O minus مع ال + +392 +00:32:58,800 --> 00:32:59,540 +H من هنا + +393 +00:33:03,130 --> 00:33:06,890 +فهذا ال alcohol اللي اتكون عندنا لو بدنا نقول + +394 +00:33:06,890 --> 00:33:09,850 +explain the formation of this alcohol بدنا نقول ان + +395 +00:33:09,850 --> 00:33:16,390 +هذا تم عبر two plus two cycloaddition ابهيك بنكون + +396 +00:33:16,390 --> 00:33:19,730 +اعطينا فكرة عن ال by role وقلنا انه التفاعلات + +397 +00:33:19,730 --> 00:33:23,230 +الأساسية عن ال nitrogen و ال electrophilic + +398 +00:33:23,230 --> 00:33:28,850 +substitution ال cycloadditions أمثلة قليلة جدا + +399 +00:33:28,850 --> 00:33:33,990 +محدودة جدا ذكرنا منها مثلانينأما تفاعلاته الأساسية + +400 +00:33:33,990 --> 00:33:41,050 +عن نيتروجين من خلال إيش؟ الايون السالب، عن + +401 +00:33:41,050 --> 00:33:44,550 +نيتروجين من خلال الايون السالب، الـelectrophilic + +402 +00:33:44,550 --> 00:33:49,020 +substitution تبعه على أي مواقعاتنين و خمسة لاحظوا + +403 +00:33:49,020 --> 00:33:52,800 +اللي بديه يحس انه القمر مش صعب يفهم بادئ الأساسية + +404 +00:33:52,800 --> 00:33:57,240 +ال بيرول بتفعل عن نيتروجين من خلال تكوين ايون سالك + +405 +00:33:57,240 --> 00:34:00,620 +في الأول مع معدن بعمل electrophilic substitution + +406 +00:34:00,620 --> 00:34:05,100 +على مواقع اتنين او اتنين و خمسة و طبعا بنفسره من + +407 +00:34:05,100 --> 00:34:09,890 +خلال ال resonance اللي هو بعض الأنفلةاللي هي Cycle + +408 +00:34:09,890 --> 00:34:13,630 +Addition سواء كان Deals Elder Cycle Addition أو 2 + +409 +00:34:13,630 --> 00:34:17,530 +Plus 2 Cycle Addition لما نروح على الفيوران هنلاحظ + +410 +00:34:17,530 --> 00:34:21,370 +أنه الفيوران في Deals Elder أمثلته أكتر كتير كتير + +411 +00:34:21,370 --> 00:34:26,340 +من ال By Roll يعني لو أنتوا بتكونوا تفتشوافي ال + +412 +00:34:26,340 --> 00:34:31,560 +net على deals alder مع furan هتلاقوا عشرات مئات + +413 +00:34:31,560 --> 00:34:34,360 +الأمثلة deals alder مع ال bayron عدد قليل من + +414 +00:34:34,360 --> 00:34:38,440 +الأمثلة لكن بكل الأحوال احنا بدناش ياكم تفتشوا على + +415 +00:34:38,440 --> 00:34:44,360 +هدولة بدنا ياكم تجيبولنا من ال net أمثلة على تحضير + +416 +00:34:44,360 --> 00:34:49,900 +تحضيرات جديدة ل quinoline و ال isoquinoline و ال + +417 +00:34:49,900 --> 00:34:56,980 +bayron بدناش ال bayronsEquinoline و Isoquinoline و + +418 +00:34:56,980 --> 00:35:01,900 +Birol روحوا على المجلات الجديدة شوفوا طرق جديدة + +419 +00:35:01,900 --> 00:35:04,900 +موجودة في المجلات How can you prepare new + +420 +00:35:04,900 --> 00:35:08,620 +derivatives of equinoline, of Isoquinoline, of + +421 +00:35:08,620 --> 00:35:12,080 +Birol؟ مابديش أنسى أنا أن ال equinolines يعني هي + +422 +00:35:12,080 --> 00:35:17,950 +مركبات يعني خليني أقول أساسية جدافي علاج + +423 +00:35:17,950 --> 00:35:24,170 +الروماتيزم وغيرها يعني والملاريا بشكل أساسي يعني + +424 +00:35:24,170 --> 00:35:29,270 +لو كتبتوا أنتوا antimalarial الأدوية المضادة + +425 +00:35:29,270 --> 00:35:34,370 +للملاريا هيطلع عندكم الquinolins عائلات كبيرة جدا + +426 +00:35:34,370 --> 00:35:39,510 +للأدوية ال antimalarial من الquinolins وبهك بننهي + +427 +00:35:39,510 --> 00:35:43,090 +محاضرتنا لليوم وإن شاء الله إلى لقاء آخر +