{"segments": [{"id": 1, "seek": 3925, "start": 19.49, "end": 39.25, "text": "بسم الله الرحمن الرحيم المرة الماضية بدينا في موضوع ال carbohydrates بدينا في موضوع ال carbohydrates وقولنا انه امكوانين من carbon و ما .. و بعدين طبعا بدينا في ال sugars", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 1829, 8315, 8978, 3714, 2407, 11242, 45367, 2423, 36817, 47525, 1829, 8315, 8978, 3714, 2407, 11242, 45367, 2423, 36817, 4032, 39648, 8315, 16472, 3224, 1975, 2304, 4117, 2407, 7649, 9957, 9154, 5954, 4032, 19446, 4386, 4032, 39182, 9957, 23032, 3555, 3615, 995, 47525, 1829, 8315, 8978, 2423, 37551], "avg_logprob": -0.14636230375617743, "compression_ratio": 1.8243243243243243, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 19.49, "end": 19.83, "word": "بسم", "probability": 0.929931640625}, {"start": 19.83, "end": 19.97, "word": " الله", "probability": 0.9697265625}, {"start": 19.97, "end": 20.31, "word": " الرحمن", 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chiral center بيصير في عندنا مركبين بعد هيك قصة ال D و L بتستمر بزيادة ال chiral center و بيبدأ العدد يزيد فبناء على ذلك بناء على ذلك فبموضوع ال sugars", "tokens": [35, 34051, 441, 8978, 9673, 2288, 5016, 37977, 16247, 12610, 7578, 4032, 45164, 12174, 1211, 8315, 45164, 43242, 8315, 472, 23782, 304, 3056, 4724, 1829, 9381, 13546, 8978, 43242, 8315, 3714, 31747, 3555, 9957, 39182, 39896, 4117, 12174, 9381, 3660, 2423, 413, 4032, 441, 39894, 14851, 29973, 4724, 11622, 1829, 18513, 3660, 2423, 23782, 304, 3056, 4032, 4724, 1829, 44510, 10721, 18863, 3215, 3215, 7251, 11622, 25708, 6156, 3555, 1863, 16606, 15844, 29910, 23275, 44945, 16606, 15844, 29910, 23275, 6156, 3555, 2304, 2407, 11242, 45367, 2423, 37551], "avg_logprob": -0.24751421639865095, "compression_ratio": 1.6789473684210525, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 79.34, "end": 79.84, "word": "D", "probability": 0.477294921875}, {"start": 79.84, "end": 80.94, "word": " أو", "probability": 0.51220703125}, 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"text": "خمسة كايرال سنترز وجدت بنتوقع انه لسكر مكون من ست ذرات كربون بهذا الشكل يكون عنده اتنين و تلاتين ايزومات طبعا لما تمت عملية الاغلاق لما تمت عملية اغلاق الالكول على ال الديهايد", "tokens": [9778, 2304, 3794, 3660, 9122, 995, 13546, 6027, 8608, 29399, 2288, 11622, 49610, 3215, 2655, 4724, 29399, 30543, 3615, 16472, 3224, 5296, 3794, 37983, 3714, 4117, 2407, 1863, 9154, 8608, 2655, 29910, 2288, 9307, 9122, 25513, 11536, 39627, 15730, 25124, 28820, 7251, 30544, 43242, 3224, 1975, 2655, 1863, 9957, 4032, 6055, 1211, 9307, 9957, 1975, 1829, 11622, 20498, 9307, 23032, 3555, 3615, 995, 5296, 15042, 46811, 2655, 6225, 42213, 10632, 2423, 5718, 118, 15040, 4587, 5296, 15042, 46811, 2655, 6225, 42213, 10632, 1975, 17082, 15040, 4587, 2423, 6027, 4117, 12610, 15844, 2423, 2423, 16254, 11296, 25708], "avg_logprob": -0.2453286033315757, "compression_ratio": 1.8705882352941177, "no_speech_prob": 0.0, "words": [{"start": 181.62, "end": 182.26, "word": "خمسة", "probability": 0.8182373046875}, {"start": 182.26, "end": 182.74, "word": " كايرال", "probability": 0.626220703125}, {"start": 182.74, "end": 183.32, "word": " سنترز", "probability": 0.6751708984375}, {"start": 183.32, "end": 183.7, "word": " وجدت", "probability": 0.601318359375}, {"start": 183.7, "end": 184.42, "word": " بنتوقع", "probability": 0.7833251953125}, {"start": 184.42, "end": 185.04, "word": " انه", "probability": 0.609619140625}, {"start": 185.04, "end": 186.58, "word": " لسكر", "probability": 0.8326822916666666}, {"start": 186.58, "end": 187.08, "word": " مكون", "probability": 0.6051025390625}, {"start": 187.08, "end": 187.28, "word": " من", "probability": 0.98779296875}, {"start": 187.28, "end": 187.56, "word": " ست", "probability": 0.81298828125}, {"start": 187.56, "end": 188.0, "word": " ذرات", "probability": 0.81591796875}, {"start": 188.0, "end": 188.48, "word": " كربون", "probability": 0.953125}, {"start": 188.48, "end": 188.94, "word": " بهذا", "probability": 0.794189453125}, {"start": 188.94, "end": 189.46, "word": " الشكل", "probability": 0.9921875}, {"start": 189.46, "end": 190.14, "word": " يكون", "probability": 0.9326171875}, {"start": 190.14, "end": 190.82, "word": " عنده", "probability": 0.904541015625}, {"start": 190.82, "end": 191.36, "word": " اتنين", "probability": 0.86572265625}, {"start": 191.36, "end": 191.46, "word": " و", "probability": 0.736328125}, {"start": 191.46, "end": 192.14, "word": " تلاتين", "probability": 0.947265625}, {"start": 192.14, "end": 193.36, "word": " ايزومات", "probability": 0.68916015625}, {"start": 193.36, "end": 194.16, "word": " طبعا", "probability": 0.9464111328125}, {"start": 194.16, "end": 194.62, "word": " لما", "probability": 0.879638671875}, {"start": 194.62, "end": 195.08, "word": " تمت", "probability": 0.983154296875}, {"start": 195.08, "end": 195.6, "word": " عملية", "probability": 0.986328125}, {"start": 195.6, "end": 196.48, "word": " الاغلاق", "probability": 0.781884765625}, {"start": 196.48, "end": 196.9, "word": " لما", "probability": 0.73291015625}, {"start": 196.9, "end": 197.32, "word": " تمت", "probability": 0.983154296875}, {"start": 197.32, "end": 197.76, "word": " عملية", "probability": 0.9754231770833334}, {"start": 197.76, "end": 198.3, "word": " اغلاق", "probability": 0.984130859375}, {"start": 198.3, "end": 199.2, "word": " الالكول", "probability": 0.7208251953125}, {"start": 199.2, "end": 200.24, "word": " على", "probability": 0.86669921875}, {"start": 200.24, "end": 200.58, "word": " ال", "probability": 0.9501953125}, {"start": 200.58, "end": 201.54, "word": " الديهايد", "probability": 0.703857421875}], "temperature": 1.0}, {"id": 9, "seek": 21844, "start": 201.96, "end": 218.44, "text": "بهذا الشكل اتكون عندى هنا ال new chiral center وقولنا الكاربون هذه اللى بتعمل ال new chiral center شو بنسميها احنا انوميرك كاربون الان معنى new chiral center ان هو ال OH هذى بنسميها اما لأعلى", "tokens": [3555, 3224, 15730, 25124, 28820, 1975, 2655, 30544, 43242, 7578, 34105, 2423, 777, 23782, 304, 3056, 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0.86181640625}, {"start": 661.83, "end": 662.61, "word": " الان", "probability": 0.763916015625}, {"start": 662.61, "end": 663.33, "word": " بالشكل", "probability": 0.89013671875}, {"start": 663.33, "end": 663.83, "word": " هذا", "probability": 0.93994140625}, {"start": 663.83, "end": 665.27, "word": " بتكون", "probability": 0.899169921875}, {"start": 665.27, "end": 665.99, "word": " ايش؟", "probability": 0.835205078125}], "temperature": 1.0}, {"id": 30, "seek": 68234, "start": 667.32, "end": 682.34, "text": "أكسيال طبعا ال equatorial الفراغ اللي حواليها أفضل من الفراغ اللي حواليه الأكسيال الأكسيال crowded لاحظوا فيها steric hindrance فيها ممانعة فراغية مالهاش واسعة واضح", "tokens": [10721, 4117, 3794, 1829, 6027, 23032, 3555, 3615, 995, 2423, 45544, 831, 27188, 2288, 5718, 118, 13672, 1829, 11331, 2407, 6027, 1829, 11296, 5551, 5172, 11242, 1211, 9154, 27188, 2288, 5718, 118, 13672, 1829, 11331, 2407, 6027, 1829, 3224, 16247, 4117, 3794, 1829, 6027, 16247, 4117, 3794, 1829, 6027, 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{"start": 673.14, "end": 673.3, "word": " من", "probability": 0.9912109375}, {"start": 673.3, "end": 673.7, "word": " الفراغ", "probability": 0.989501953125}, {"start": 673.7, "end": 673.82, "word": " اللي", "probability": 0.981689453125}, {"start": 673.82, "end": 674.22, "word": " حواليه", "probability": 0.90224609375}, {"start": 674.22, "end": 674.7, "word": " الأكسيال", "probability": 0.8065185546875}, {"start": 674.7, "end": 675.6, "word": " الأكسيال", "probability": 0.82236328125}, {"start": 675.6, "end": 677.3, "word": " crowded", "probability": 0.431884765625}, {"start": 677.3, "end": 677.96, "word": " لاحظوا", "probability": 0.89306640625}, {"start": 677.96, "end": 678.18, "word": " فيها", "probability": 0.93603515625}, {"start": 678.18, "end": 678.76, "word": " steric", "probability": 0.61932373046875}, {"start": 678.76, "end": 679.34, "word": " hindrance", "probability": 0.89306640625}, {"start": 679.34, "end": 679.68, "word": " فيها", "probability": 0.806640625}, {"start": 679.68, "end": 680.18, "word": " ممانعة", "probability": 0.9671630859375}, {"start": 680.18, "end": 680.64, "word": " فراغية", "probability": 0.91748046875}, {"start": 680.64, "end": 681.02, "word": " مالهاش", "probability": 0.79315185546875}, {"start": 681.02, "end": 681.6, "word": " واسعة", "probability": 0.8448893229166666}, {"start": 681.6, "end": 682.34, "word": " واضح", "probability": 0.9150390625}], "temperature": 1.0}, {"id": 31, "seek": 70760, "start": 682.56, "end": 707.6, "text": "الـ equatorial مترايحة أكثر ولذلك هذا الشكل ال equatorial هو ال beta هذا الشكل ال axial هو ال alpha عشان هيك ال beta بيكون more stable لأن ال OH اللي موجودة فيه ال new chiral center لأنميرك كربون بتكون مترايحة من الناحية الفرغية مافيش حد مضايقها واضح؟ لحظوا هذه ال OH الجديدة اللي اتكونت عندى", "tokens": [6027, 39184, 45544, 831, 44650, 23557, 1829, 5016, 3660, 5551, 4117, 49115, 35525, 8848, 23275, 23758, 25124, 28820, 2423, 45544, 831, 31439, 2423, 9861, 23758, 25124, 28820, 2423, 46851, 31439, 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{"start": 701.28, "end": 701.66, "word": " الناحية", "probability": 0.8551025390625}, {"start": 701.66, "end": 702.16, "word": " الفرغية", "probability": 0.80841064453125}, {"start": 702.16, "end": 702.66, "word": " مافيش", "probability": 0.7388509114583334}, {"start": 702.66, "end": 702.98, "word": " حد", "probability": 0.98388671875}, {"start": 702.98, "end": 703.86, "word": " مضايقها", "probability": 0.81220703125}, {"start": 703.86, "end": 704.82, "word": " واضح؟", "probability": 0.74761962890625}, {"start": 704.82, "end": 705.2, "word": " لحظوا", "probability": 0.8824462890625}, {"start": 705.2, "end": 705.36, "word": " هذه", "probability": 0.7958984375}, {"start": 705.36, "end": 705.5, "word": " ال", "probability": 0.9736328125}, {"start": 705.5, "end": 705.84, "word": " OH", "probability": 0.6865234375}, {"start": 705.84, "end": 706.46, "word": " الجديدة", "probability": 0.94140625}, {"start": 706.46, "end": 706.62, "word": " اللي", "probability": 0.8955078125}, {"start": 706.62, "end": 707.14, "word": " اتكونت", "probability": 0.9078369140625}, {"start": 707.14, "end": 707.6, "word": " عندى", "probability": 0.851318359375}], "temperature": 1.0}, {"id": 32, "seek": 73696, "start": 708.02, "end": 736.96, "text": "الان في ال equatorial form هي مترايحة في ال axial form مش مترايحة في جنبها مجموعات تانية بتعمل ازدحام فراغي فلما نكون بدنا نفسر ليش ال beta موجودة اكثر من ال alpha بنقول because the beta o h is found in the equatorial position لان موجودة في ال equatorial ال equatorial is not a crowded position", "tokens": [6027, 7649, 8978, 2423, 45544, 831, 1254, 39896, 44650, 23557, 1829, 5016, 3660, 8978, 2423, 46851, 1254, 37893, 44650, 23557, 1829, 5016, 3660, 8978, 10874, 1863, 3555, 11296, 3714, 7435, 2304, 45367, 9307, 6055, 7649, 10632, 39894, 25957, 1211, 1975, 11622, 3215, 5016, 10943, 6156, 2288, 5718, 118, 1829, 6156, 1211, 15042, 8717, 30544, 47525, 8315, 8717, 36178, 2288, 32239, 8592, 2423, 9861, 3714, 29245, 23328, 3660, 1975, 4117, 49115, 9154, 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{"start": 1094.0, "end": 1094.88, "word": " الكيتون", "probability": 0.8707682291666666}, {"start": 1094.88, "end": 1095.9, "word": " خلينا", "probability": 0.7647705078125}, {"start": 1095.9, "end": 1096.28, "word": " ناخد", "probability": 0.99072265625}, {"start": 1096.28, "end": 1096.82, "word": " مثال", "probability": 0.88525390625}, {"start": 1096.82, "end": 1097.32, "word": " لو", "probability": 0.8994140625}, {"start": 1097.32, "end": 1097.88, "word": " اخدنا", "probability": 0.857177734375}, {"start": 1097.88, "end": 1098.38, "word": " مثلا", "probability": 0.94775390625}, {"start": 1098.38, "end": 1099.1, "word": " السكر", "probability": 0.9443359375}, {"start": 1099.1, "end": 1100.04, "word": " المسكر", "probability": 0.8473307291666666}], "temperature": 1.0}, {"id": 48, "seek": 111330, "start": 1101.06, "end": 1113.3, "text": "اللي قلنا عنه بيتا دي جلوكو بيرانوز وين رسمينه على هيئة الكرسي هل هذا لما سكر لما صار بيرانوز ضال فيه الديهايد؟", "tokens": [6027, 20292, 12174, 1211, 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"end": 1104.08, "word": " بيرانوز", "probability": 0.8859375}, {"start": 1104.08, "end": 1104.32, "word": " وين", "probability": 0.5067138671875}, {"start": 1104.32, "end": 1105.0, "word": " رسمينه", "probability": 0.73553466796875}, {"start": 1105.0, "end": 1105.46, "word": " على", "probability": 0.88916015625}, {"start": 1105.46, "end": 1105.92, "word": " هيئة", "probability": 0.88330078125}, {"start": 1105.92, "end": 1107.0, "word": " الكرسي", "probability": 0.939453125}, {"start": 1107.0, "end": 1107.46, "word": " هل", "probability": 0.7030029296875}, {"start": 1107.46, "end": 1107.8, "word": " هذا", "probability": 0.90869140625}, {"start": 1107.8, "end": 1108.46, "word": " لما", "probability": 0.85498046875}, {"start": 1108.46, "end": 1109.08, "word": " سكر", "probability": 0.800537109375}, {"start": 1109.08, "end": 1109.42, "word": " لما", "probability": 0.797607421875}, {"start": 1109.42, "end": 1109.72, "word": " صار", "probability": 0.918212890625}, {"start": 1109.72, "end": 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هذا التفاعل البسيط أن الكحول بيحل محل اليود ولذلك ملخص هدول التنتين أن الكحول مع الانهيدريد بيعطيني إيثر للشجر والكحول مع ال مثل أيودايد بيعطيني إيثر", "tokens": [3224, 1829, 3615, 9566, 1829, 22653, 9122, 2304, 11933, 1829, 49115, 22807, 16490, 2304, 3794, 11933, 1829, 12984, 2288, 9307, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 4032, 46958, 5016, 27188, 4117, 25720, 22807, 31439, 8717, 36178, 23758, 16712, 5172, 995, 30241, 29739, 3794, 1829, 9566, 14739, 33251, 5016, 12610, 4724, 1829, 5016, 1211, 3714, 5016, 1211, 45595, 23328, 35525, 8848, 23275, 3714, 1211, 9778, 9381, 8032, 3215, 12610, 16712, 29399, 9957, 14739, 33251, 5016, 12610, 20449, 2423, 7649, 3224, 25708, 2288, 25708, 4724, 40228, 9566, 1829, 22653, 11933, 1829, 49115, 24976, 8592, 7435, 2288, 16070, 4117, 5016, 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بنسميها؟ Glycosidic bond موجودة ويلها أهمية جزء كبير من أهمية هذه المنطقة أنه لما بعدك السكريات بدهم يبدوا يعملوا dimers مع بعض يتحدوا هنلاحظ فائدة هذه ال glycosidic bond لأنه بربطوا من خلالها واضح؟ يربطوا مع بعض من خلالها", "tokens": [2304, 3615, 2423, 13931, 20328, 9640, 2655, 44650, 36520, 3660, 20449, 1975, 1829, 8592, 22807, 20449, 2423, 19654, 13412, 2407, 44945, 38251, 1829, 11296, 22807, 460, 356, 6877, 327, 299, 6086, 3714, 29245, 23328, 3660, 4032, 26895, 11296, 5551, 16095, 10632, 10874, 11622, 38207, 9122, 3555, 13546, 9154, 5551, 16095, 10632, 29538, 9673, 1863, 9566, 28671, 14739, 3224, 5296, 15042, 39182, 4117, 21136, 4117, 16572, 9307, 47525, 16095, 7251, 44510, 14407, 7251, 25957, 1211, 14407, 5013, 433, 20449, 45030, 11242, 7251, 2655, 24401, 14407, 8032, 1863, 15040, 5016, 19913, 6156, 16373, 41891, 29538, 2423, 22633, 6877, 327, 299, 6086, 5296, 33456, 3224, 4724, 25513, 9566, 14407, 9154, 16490, 1211, 6027, 11296, 4032, 46958, 5016, 22807, 7251, 25513, 9566, 14407, 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"probability": 0.9151611328125}, {"start": 2408.7, "end": 2409.54, "word": " هنلاحظ", "probability": 0.9154296875}, {"start": 2409.54, "end": 2410.14, "word": " فائدة", "probability": 0.9817708333333334}, {"start": 2410.14, "end": 2410.48, "word": " هذه", "probability": 0.3974609375}, {"start": 2410.48, "end": 2410.58, "word": " ال", "probability": 0.8076171875}, {"start": 2410.58, "end": 2411.42, "word": " glycosidic", "probability": 0.8731689453125}, {"start": 2411.42, "end": 2411.56, "word": " bond", "probability": 0.95166015625}, {"start": 2411.56, "end": 2411.88, "word": " لأنه", "probability": 0.8401692708333334}, {"start": 2411.88, "end": 2412.26, "word": " بربطوا", "probability": 0.8045654296875}, {"start": 2412.26, "end": 2412.42, "word": " من", "probability": 0.99560546875}, {"start": 2412.42, "end": 2413.02, "word": " خلالها", "probability": 0.9967041015625}, {"start": 2413.02, "end": 2414.08, "word": " واضح؟", "probability": 0.921142578125}, {"start": 2414.08, "end": 2414.52, "word": " يربطوا", "probability": 0.925537109375}, {"start": 2414.52, "end": 2414.62, "word": " مع", "probability": 0.99072265625}, {"start": 2414.62, "end": 2414.86, "word": " بعض", "probability": 0.998291015625}, {"start": 2414.86, "end": 2415.0, "word": " من", "probability": 0.998046875}, {"start": 2415.0, "end": 2415.44, "word": " خلالها", "probability": 0.9954833984375}], "temperature": 1.0}, {"id": 103, "seek": 243448, "start": 2417.16, "end": 2434.48, "text": "لو اجينا رسمنالكم مركب هذا sugar من الجولوكوز هل هذا يا تورا فيه glycosidic bond ولا لأ تطلع عليه هاي carbon او", "tokens": [1211, 2407, 1975, 7435, 1829, 8315, 12602, 38251, 8315, 23275, 2304, 3714, 31747, 3555, 23758, 5076, 9154, 25724, 12610, 2407, 4117, 2407, 11622, 8032, 1211, 23758, 35186, 6055, 13063, 995, 8978, 3224, 22633, 6877, 327, 299, 6086, 49429, 5296, 10721, 6055, 9566, 1211, 3615, 47356, 8032, 47302, 5954, 1975, 2407], "avg_logprob": -0.321997556031919, "compression_ratio": 1.2941176470588236, 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الصفصاف لما كانوا بيغلو شجر الصفصاف بيطلع هذا المركب كانوا ياخدوله الصداع الناس الزمان فيه glycosidic bond لاحظوا اللى بتتأمل فيه بشكل بشكل قوى هتلاحظ ان هذا بيشبه ايش الاسميرين", "tokens": [24437, 4351, 1975, 15730, 23758, 9673, 31747, 3555, 13672, 7578, 24525, 2304, 3224, 8608, 6027, 1829, 3794, 9957, 9154, 13412, 7435, 2288, 31767, 5172, 9381, 31845, 5296, 15042, 25961, 14407, 4724, 1829, 17082, 1211, 2407, 13412, 7435, 2288, 31767, 5172, 9381, 31845, 4724, 1829, 9566, 1211, 3615, 23758, 9673, 31747, 3555, 25961, 14407, 7251, 47283, 3215, 12610, 3224, 31767, 28259, 3615, 2423, 8315, 3794, 6024, 110, 2304, 7649, 8978, 3224, 22633, 6877, 327, 299, 6086, 20193, 5016, 19913, 14407, 13672, 7578, 39894, 2655, 10721, 42213, 8978, 3224, 4724, 8592, 28820, 4724, 8592, 28820, 12174, 2407, 7578, 8032, 2655, 15040, 5016, 19913, 16472, 23758, 4724, 1829, 8592, 3555, 3224, 1975, 1829, 8592, 2423, 32277, 2304, 13546, 9957], "avg_logprob": -0.19070512616736257, "compression_ratio": 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