{"id":0,"tokens":["However",",","no","more","cycles","have","been","performed","in","contrast","with","Li","\/","LiFePO4","cell","with","the","same","solid","electrolyte",".","In","turn",",","Choi","et","al",".","[","118","]","investigated","hybrid","solid","electrolyte","based","on","PEO","-","LiClO4","system","with","addition","of","52","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":1,"tokens":["The","relatively","low","content","of","organic","CEI","components","indicates","the","reduced","electrode","\/","electrolyte","side","reactions",",","validating","the","suppressed","lattice","oxygen","oxidizing","ability","of","the","spinel","phase","(","Co3O4","and","Co2TiO4","\/","CoAl2O4",")","for","LATP","@","LCO","-","700","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O"]}
{"id":2,"tokens":["and","a","high","Coulombic","efficiency","at","1",".","0C","\/","1",".","0C","charge","\/","discharge","for","500","cycles","(","more","detailed","electrochemical","performances","are","given","in","Supplementary","Fig",".","16",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":3,"tokens":["Cycling","performance","for","PEO","-","based","batteries","were","evaluated","at","60","°","C","with","the","cut","-","off","potential","range","from","3",".","0","to","4",".","2","V","and","a","current","density","of","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":4,"tokens":["(","33",")","Then","the","gassing","behavior","of","the","cell","using","modified","LiCoO2","was","characterized",".","The","onset","gas","release","voltage","was","largely","delayed",",","and","no","obvious","gas","release","was","detected","even","at","a","high","voltage","of","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":5,"tokens":["and","2",".","4","×","10","–","12","cm2","s","–","1","for","LP","-","2",",","PPy","-","3",",","and","PPy","-","LP","samples",",","demonstrating","better","Li","+","intercalation","\/","deintercalation","kinetics","in","the","coated","cathode","materials","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":6,"tokens":["In","the","second","coating","process",",","PPy","formed","a","continuous","coating","layer",",","which","made","up","for","the","Li3PO4","coating","defects",".","PPy","coating","reduced","the","separation","between","the","particles","and","also","resistance","of","the","electrode",","],"ner_tags":["O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","B-COATING_MATERIAL","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":7,"tokens":["Moreover",",","LixCoPO4","\/","Co3","(","PO4",")","2","are","thermally","stable","even","after","full","delithation",",","thus","minimizing","any","side","reactions","with","electrolytes",".","On","the","other","hand",",","in","attempts","to","increase","the","reversible","capacity","of","the","LiNiO2","-","based","material",","],"ner_tags":["O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":8,"tokens":["The","uniform","ALD","coating","provides","enhanced","stability",",","but","comes","at","the","cost","of","serving","as","an","additional","lithium","ion","diffusion","barrier",".","When","the","lithium","ion","conductivity","of","the","film","is","low","("],"ner_tags":["O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":9,"tokens":["(","31","−","35",")","In","this","respect",",","Hayashi","et","al",".","fabricated","a","lithium","tungsten","oxide","-","modified","LiCoO2","(","LCO",")","thin","-","film","electrode","by","pulsed","laser","deposition","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O"]}
{"id":10,"tokens":["5Co0",".","2Mn0",".","3O2","is","shown","in","Fig",".","4a",".","Fig",".","4c","and","d","show","the","high","-","resolution","TEM","(","HRTEM",")","images","of","LiNi0","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":11,"tokens":["When","the","coating","thickness","is","increased",",","the","polarization","is","increased",",","resulting","from","the","Li","+","\/","electron","migration","clearly","reflected","in","the","interfacial","charge","-","transfer","resistance","derived","from","the","impedance","plot","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":12,"tokens":["and","vacuum","-","dried","at","80","°","C","for","24","h",".","An","acid","–","base","titration","method","was","used","to","measure","the","content","of","HF","in","the","electrolyte",",","using","NaOH","solution","as","standard","solution","and","bromothymol","blue","as","indicator","solution","for","the","titration","experiment","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":13,"tokens":["the","ion","transport","pathway","shifts","to","liquid","-","modified","PEO","and","the","ionic","conductivity","is","significantly","enhanced","due","to","the","increased","ion","mobility","and","re","-","established","ion","conduction","channels","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":14,"tokens":["S5","a","–","c","in","Supplementary","data",".","Elemental","mappings","of","Co","(","a",",","d",",","g",")",",","O","(","b",",","e",",","h",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":15,"tokens":["and","(","b",")","a","cutoff","condition","of","4",".","5","V","vs",".","The","charging","current","density","was","maintained","C","\/","2","while","the","discharging","current","density","was","varied","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":16,"tokens":["It","was","believed","that","the","conformal","contact","between","solid","-","state","electrolyte","and","Li","metal",",","the","enhanced","interfacial","kinetics","due","to","thermally","lithiated","Al2O3","and","the","inhibition","of","Al2O3","against","the","formation","of","Li2CO3","are","all","ascribed","to","the","ALD","deposited","thin","film","on","the","surface","of","LLZO","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":17,"tokens":["Furthermore",",","the","LATP","layer","can","block","the","transfer","of","anions",",","which","reduces","the","double","-","layer","electric","field","and","prevents","the","decomposition","of","polymer","by","metallic","anode","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":18,"tokens":["The","film","we","developed","served","as","a","stable","and","lithium","permeable","interfacial","layer","for","NMC","-","811",".","Good","cycling","stability","can","be","obtained","for","300","cycles","with","capacity","retention","higher","than","99",".","9","%","per","cycle","at","a","wide","electrochemical","window","of","2",".","75","–","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":19,"tokens":["The","improvement","on","the","interfacial","stability","of","the","LATP","@","LCO","-","700","cell","can","be","attributed","to","the","physical","isolation","of","the","electrolyte","from","LiCoO2","by","the","stable","hybrid","phase","protective","coating","layer",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":20,"tokens":["The","improved","rate","capability","of","ZrO2","-","coated","NMC532","electrodes","are","exhibited","in","Fig",".","3d",".","ZrO2","ALD","-","5","retained","63",".","3","%","of","the","initial","capacity","at","3","C","-","rate",",","higher","than","those","of","bare","NMC","electrode","(","54",".","0","%",")"],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O"]}
{"id":21,"tokens":["which","is","demonstrated","to","be","highly","effective","to","improve","the","high","-","voltage","performance","of","LiCoO2",".","It","is","discovered","that","LiCoO2","reacts","with","Li1",".","5Al0",".","5Ti1",".","5","(","PO4",")","3","(","LATP",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":22,"tokens":["During","an","ALD","process",",","the","purging","time","is","an","important","parameter",",","thus","this","parameter","we","used","in","this","study","was","optimized",".","For","example",",","as","shown","in","Fig","."],"ner_tags":["O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":23,"tokens":["The","PPy","layer","could","form","a","uniform","film","which","can","make","up","for","the","Li3PO4","coating","defects","and","enhance","the","electronic","conductivity",".","The","stretchy","PPy","capsule","shell","can","reduce","the","generation","of","internal","cracks","by","resisting","the","internal","pressure","as","well","."],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":24,"tokens":["However",",","NCM","exhibits","several","limitations",",","including","poor","rate","capability","and","insufficient","capacity","retention",",","especially","at","high","cutoff","voltages","[","13","]",".","To","address","these","challenges",",","various","techniques","such","as","surface","modification","[","19","]",",","elemental","doping","[","20","]",","],"ner_tags":["O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O"]}
{"id":25,"tokens":["The","LiCoO2",",","surface","modified","with","2","wt","%","LATP","through","the","above","-","mentioned","method",",","exhibits","superior","4",".","6","V","cycle","and","rate","performances","at","both","room","temperature","and","45","°","C","."],"ner_tags":["O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":26,"tokens":["and","lithium","containing","compounds","(","e",".","g",".",",","LiNi0",".","5Mn0",".","5O2",",","(","15",")","LiFePO4",",","(","16",")","Li2MnO3",",","(","17",")"],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","O","O","O","O"]}
{"id":27,"tokens":["However",",","the","observed","grains","gradually","aggregate","together","as","the","temperature","further","increases","to","above","800","°","C",".","Thus",",","notwithstanding","that","the","bulk","structure","remains","unchanged","during","the","annealing","process",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":28,"tokens":["the","flexible","HSSE","is","formed","by","filling","LiTFSI","-","PEO","into","the","porous","3D","LLZO","skeleton",",","possessing","an","ionic","conductivity","of","2",".","5","×","10","−","4","S","cm","−","1","at","room","temperature","as","a","result","of","the","interconnected","lithium","conducting","channels","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":29,"tokens":["Æ","Due","to","the","complex","interaction","between","the","electrodes","and","electrolyte","during","charging","and","discharging","process",",","constant","decomposition","and","side","reactions","take","place","and","this","implies","the","consumption","of","active","Li","and","electrolytes",",","may","also","results","in","gas","evolution","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":30,"tokens":["(","21",",","22",")","Gas","generation","is","a","common","phenomenon",",","leading","to","negative","consequences","for","the","performance","and","cycle","life","of","LIBs",".","(","23","−","25",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":31,"tokens":["and","10","wt","%","PVDF","binder",".","The","exceptional","advantage","is","that","ALD","allows","for","the","direct","deposition","on","either","individual","electrode","material","particles","or","as","-","formed","composite","electrodes","[","12","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":32,"tokens":["the","Li3PO4","coating","layer","could","be","optimized","by","adjusting","the","amounts","of","LiOH","and","NH4H2PO4",".","(","1",")","3Li2CO3","+","2NH4H2PO4","→","2Li3PO4","+","2NH3","+","3CO2","+","3H2O","(","2",")","3LiOH","+","NH4H2PO4","→","Li3PO4","+","NH3","+","3H2O","Fig",".","3",".","FTIR","patterns","of","the","pristine","and","Li3PO4","coated","Li1","."],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":33,"tokens":["which","indicated","that","the","LiNi0",".","8Co0",".","1Mn0",".","1O2","cathode","material","was","coated","by","Li3PO4","and","PPy","polymer",",","consistent","with","the","FT","-","IR","and","XPS","analysis","."],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":34,"tokens":["8V","–","4",".","9","V","vs",".","The","most","common","material","in","this","class","is","LixFePO4","(","LFP",")",",","and","widely","used","olivine","type","of","cathode","with","a","theoretical","capacity","of","170","mAh","\/","g","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":35,"tokens":["All","the","cells","were","tested","at","room","temperature","with","the","charging","cut","-","off","potential","of","4",".","5","V","and","current","density","of","0",".","2","C","rate","(","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":36,"tokens":["34La0",".","51TiO3","membrane","[","31","]",",","tape","-","casting","Li0",".","34La0",".","56TiO3","ceramic","electrolyte","films","for","high","energy","density","[","32","]",".","For","high","capacity","SSBs",",","surely",",","nickel","-","rich","cathode","materials","are","most","potential","candidates","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":37,"tokens":["Compared","with","the","HRTEM","image","of","the","bare","NCM","-","523","(","Fig",".","3","(","b",")",")",",","the","25","ALD","-","ZnO","layers","coated","sample","(","Fig",".","3","(","c",")",")","exhibits","the","conformal","ultrathin","coating","layer","with","∼","43","."],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O"]}
{"id":38,"tokens":["It","can","be","clearly","seen","in","the","figure","that","tin","dioxide","grows","uniformly","on","LNMO","surface",".","The","figure","shows","the","working","schematic","diagram","of","SnO2","grown","on","the","surface","of","LNMO",","],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O"]}
{"id":39,"tokens":["0","V","does","not","increase","initial","capacity","but","drastically","decrease","cyclability","due","to","electrochemical","decomposition","of","the","solid","electrolyte",".","Through","these","authors","demonstrated","that","charge","cut","off","voltage","is","a","crucial","factor","for","SSBs","to","find","an","optimal","trade","-","off","between","specific","energy","density","and","cycle","life","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":40,"tokens":["The","peak","of","P","2p","located","at","133",".","1","eV","was","attributed","to","the","PPy","-","LP","sample",",","which","was","characteristic","of","the","tetrahedral","(","PO4",")","group","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":41,"tokens":["Al","-","O","-","2","and","(","c",")","Li","-","Al","-","O","-","2","at","various","scan","rates",";","(","d",")","the","relationship","of","the","peak","current","(","ip",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":42,"tokens":["The","LATP","modified","LiCoO2","powders","show","relatively","rough","surface","with","dot","-","like","nano","-","sized","particles","embedded","into","the","LiCoO2","surface",".","These","nano","-","sized","particles","are","LATP","which","can","be","confirmed","by","EDS","mapping","as","shown","in","Fig","."],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":43,"tokens":["Gels","are","prepared","by","introducing","a","liquid","phase","(","liquid","electrolyte","or","ionic","liquid",")","into","a","polymer","matrix","(","Fig",".","6",")",".","In","this","approach",",","electrolyte","materials","have","mechanical","properties","similar","to","plastic","solids","and",",","simultaneously",",","ion","transport","properties","closer","to","liquid","electrolytes","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":44,"tokens":["Very","recently",",","Wan","et","al",".","constructed","a","thin","and","asymmetric","solid","electrolyte",",","in","which","a","soft","polymer","layer","of","poly","(","ethylene","glycol",")","methyl","ether","acrylate","(","PEGMEA",")","was","stacked","with","the","rigid","Li7La3Zr2O12","(","LLZO",")","layer","modified","with","ultrathin","(","7","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":45,"tokens":["15","M","LiPF6","in","EC",":","EMC",":","DMC","0","3","\/","4","\/","3","vol","%",")",".","Li","\/","Li","symmetric","cells","were","assembled","in","the","glove","box","with","80","μ","l","of","the","prepared","electrolyte","for","each","cell","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":46,"tokens":["8","eV","with","a","Ni","(","LMM",")","peak","at","781",".","6","eV","and","a","Co","2p1","\/","2","main","peak","at","795",".","0","eV","[","39","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":47,"tokens":["Appleby","et","al",".","designed","Li0",".","35La0",".","55TiO3","(","LLTO",")","fibers","coated","with","thin","layer","of","PEO",",","which","exhibit","both","high","mechanical","strength","and","high","ionic","conductivity","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":48,"tokens":["This","suggests","that","CoxB","infusion","effectively","lowered","the","surface","and","GB","oxygen","activity","and","suppressed","the","electrolyte","oxidation","(","the","CoxB","infusion","may","also","work","by","physically","separating","the","electrolyte","from","cathode","surface",")","."],"ner_tags":["O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O"]}
{"id":49,"tokens":["Graphical","abstract","Download",":","Download","high","-","res","image","(","274KB",")","Download",":","Download","full","-","size","imageRecently",",","layer","-","structured","ternary","material","LiNixCoyMn","(","1","−","x","−","y",")","O2","(","0","<","x",",","y","<","1",")","with","α","-","NaFeO2","structure","has","been","one","of","the","most","promising","alternative","cathode","materials","to","replace","LiCoO2","in","the","next","generation","of","the","rechargeable","lithium","-","ion","battery","(","LIB",")","[","1","]",",","[","2","]",",","[","3","]",",","[","4","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":50,"tokens":["It","shows","that","the","bare","sample","had","the","highest","pH","value","of","11",".","97","due","to","the","lithium","residues",".","The","bare","sample","showed","an","initial","discharge","specific","capacity","of","178","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":51,"tokens":["and","the","superior","stability","has","an","electronic","-","structure","origin","that","effectively","suppresses","interface","oxygen","activity",".","This","rationalizes","the","design","of","a","reactive","-","wetting","metal","–","metalloid","glass29",",","30","coating","materials","with","selective","bonding",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O"]}
{"id":52,"tokens":["78","mS","\/","cm","@","RT",")","and","a","high","lithium","-","ion","transfer","number","(","tLi","+","0","0",".","74",")",",","which","could","be","attributed","to","the","enlarged","amorphous","region","induced","from","the","addition","of","PQ","filler","and","the","decreased","hopping","distance","of","Li","+","due","to","the","sufficient","carbonyl","groups","of","PQ","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":53,"tokens":["2","V","vs",".","For","instance",",","LiNixCoyMnzO2","(","with","x","+","y","+","z","0","1",",","NCM",")","is","considered","as","a","promising","cathode","material","originating","from","its","high","operation","potential","."],"ner_tags":["O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":54,"tokens":["Such","change","in","composition","would","notably","alter","the","ionic","transport","behavior","as","well","as","the","mechanical","properties",".","29","Figure","4","Open","in","figure","viewer","PowerPoint","Composite","polymer","-","inorganic","HSSEs","with","advanced","architecture","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":55,"tokens":["and","improve","the","safety","performances","of","SPBs",".","Highlights","•","Alumina","(","Al2O3",")","was","introduced","as","ceramic","filler","during","NCM","cathode","preparation",".","•","Al2O3","stabilized","oxidative","decomposition","of","liquid","electrolyte","(","∼","5","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":56,"tokens":["and","conductive","atomic","force","microscopy","(","C","-","AFM",")",",","and","understand","the","mechanism","of","the","excellent","electrochemical","performances","of","this","material",".","Finally",",","this","material","is","adopted","for","a","prismatic","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":57,"tokens":["Moreover",",","the","EIS","of","an","increased","LiAlO2","coating","content","was","performed","on","NMC","(","Fig",".","S4",")",".","Our","results","indicate","that","as","a","coating","material","of","NMC",",","utilization","of","an","ultrathin","lithium","-","ion","conductive","LiAlO2","significantly","reduces","the","interfacial","resistance","between","the","cathode","and","electrolyte","."],"ner_tags":["O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":58,"tokens":["Fig",".","To","prepare","the","cathode","electrodes",",","an","NMP","-","based","coating","slurry","containing","90","wt",".","%","LiNi1","\/","3Co1","\/","3Mn1","\/","3O2","(","NCM",",","10","μ","m",",","NCM","-","070",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":59,"tokens":["which","exhibit","a","high","initial","discharge","capacity","of","220",".","1","and","214",".","6","mAh","g","−","1","at","0",".","2C",",","respectively",".","After","50","cycles",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":60,"tokens":["As","mentioned","above",",","the","straight","sloping","line","at","the","low","frequency","region","is","related","to","solid","-","state","diffusion","of","Li","+","in","the","electrode","bulk",".","Therefore",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":61,"tokens":["But","the","Li3PO4","coated","samples","always","show","higher","discharge","capacities","than","the","pristine","sample",".","Especially",",","the","advantage","of","Li3PO4","coating","on","the","rate","performance","of","Li1","."],"ner_tags":["O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":62,"tokens":["(","f",")","Arrhenius","plots","of","ionic","conductivity","of","the","BAIEs","and","ILE",".","55","Reproduced","with","permission",".","Copyright","2017",",","The","Royal","Society","of","Chemistry",".","Yang","and","co","-","workers","fabricated","a","new","class","of","polymeric","ionic","liquid","-","silica","HSSE","via","a","sol","-","gel","route",",","in","which","the","poly","(","diallyldimethylammonium",")","bis","(","trifluoromethanesulfonyl",")","imide","(","P","(","DADMA",")","-","TFSI",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":63,"tokens":["the","pseudocapacitance","of","the","battery","is","34",".","6","%",",","41",".","7","%",",","48",".","3","%",",","54",".","5","%","and","59",".","6","%","(","Fig",".","7e",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":64,"tokens":["0","V",".","The","production","of","H2","can","be","restrained","by","a","Li1",".","4Al0",".","4Ti1",".","6","(","PO4",")","3","(","LATP",")","coating","on","LiCoO2","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O"]}
{"id":65,"tokens":["The","results","are","shown","in","Table","S1",".","As","expected",",","the","content","of","both","coatings","in","the","coated","cathodes","increases","with","ALD","cycles",",","which","reveals","that","the","thickness","of","the","coating","layers","increases","when","ALD","cycles","are","prolonged","during","the","ALD","process","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O"]}
{"id":66,"tokens":["Cyclic","voltammetry","(","CV",")","was","measured","on","a","Bio","-","Logic","VSP","multichannel","potentiostatic","-","galvanostatic","system","with","a","scan","rate","of","0",".","1","mV","s","−","1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":67,"tokens":["To","evaluate","the","impact","of","the","tungsten","oxide","coating","on","the","surface","functional","groups","and","the","interaction","of","the","NCM","-","811","surface","with","the","coating","layer",",","the","active","material","surfaces","were","analyzed","by","Fourier","transform","infrared","(","FT","-","IR",";"],"ner_tags":["O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":68,"tokens":["The","proposed","solid","electrolyte","demonstrated","improved","mechanical","properties",",","high","ionic","conductivity","at","30","°","C",",","and","very","stable","electrochemical","performance","(","0",".","08","%","\/","cycle",")","in","Li4Ti5O12","\/","LiCoO2","solid","-","state","cell","working","under","1C","charge","-","discharge","current","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":69,"tokens":["and","their","redox","behaviours","were","similar",",","as","shown","by","a","dQ","\/","dV","analysis","(","Supplementary","Fig",".","9a",",","b",")",".","However",",","CoxB","–","NCM","had","a","better","rate","capability","(","Fig",".","3a",",","b",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":70,"tokens":["However",",","these","layered","oxides","suffer","from","problems","related","to","the","capacity","fading",",","thermal","stability",",","and","safety","at","high","voltages",".","In","this","study",",","we","use","surface","coating","as","a","strategy","to","improve","the","thermal","stability","at","higher","voltages","."],"ner_tags":["O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":71,"tokens":["According","to","the","HRTEM","image","of","LNMO","@","SnO2","(","Fig",".","3c","–","e",")",",","the","nanoparticles","showed","a","well","-","defined","(","1","1","0",")"],"ner_tags":["O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":72,"tokens":["5","MPa",")",",","good","flame","resistance","and","excellent","interface","compatibility","with","Li","metal",".","Then",",","PAMM","-","based","GPE","was","further","tested","in","LiNi0",".","5Mn1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":73,"tokens":["18Co0",".","15Ni0",".","15Mn0",".","52O2","materials",",","together","with","those","of","the","pristine","-","post","annealed","sample",".","One","of","the","big","problems","for","Li","-","excess","layered","oxides","is","the","continuous","voltage","decay","during","charge","-","discharge","cycling","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":74,"tokens":["Furthermore",",","the","long","-","term","performance","of","NCM","-","811","∥","graphite","full","cells","was","investigated","at","different","operation","conditions",",","such","as","different","cutoff","voltages","and","at","an","increased","operating","temperature","of","40","°","C","."],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":75,"tokens":["Tokyo",",","Japan",")","transmission","electron","microscope","operated","at","200","keV","and","equipped","with","double","spherical","aberration","(","Cs",")","correctors",".","The","attainable","resolution","of","the","probe","defined","by","the","objective","prefield","was","78","pm","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":76,"tokens":["Nevertheless",",","lithium","impurities","still","exist","on","the","surface","for","TiO2","or","Al2O3","coated","materials",".","Thus","Li2CO3","forms","and","Li","+","ions","can","be","more","easily","leached","from","the","bulk","when","compared","with","V2O5","coated","sample",",","because","slightly","acidic","CO32","−","ions","are","conducive","to","lithium","leach","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":77,"tokens":["As","shown","in","Figure","5c",",","three","exothermic","peaks","in","the","DSC","curves","were","observed","during","the","heating","process","of","the","charged","LixCoO2","cathode","with","electrolyte",".","Specifically",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":78,"tokens":["and","morphology",".","Furthermore",",","the","application","and","effect","of","this","protective","coating","were","purposely","investigated","in","NCM","-","811","∥","graphite","LIB","full","cells",".","In","this","case",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O"]}
{"id":79,"tokens":["Qdis1","–","first","discharge","capacity",",","WT","–","working","temperature",",","CR","–","capacity","retention","Unfortunately",",","SSBs","with","LiFePO4","(","LFP",")","cathode","typically","deliver","specific","energy","lower","than","200","Wh","\/","kg","due","to","specific","properties","of","the","cathode","material",",","namely","the","average","charge","-","discharge","voltage","of","3","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":80,"tokens":["2","C",".","Honma","and","co","-","workers","prepared","solid","-","and","quasi","-","solid","-","state","electrolytes","by","varying","the","ratio","of","inorganic","nanoparticles","and","ILs",".","43b","The","solid","(","ILs",":","TiO2","molar","ratio","<","0",".","22",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":81,"tokens":["18Co0",".","15Ni0",".","15Mn0",".","52O2","is","much","more","significant","above","the","5C","rate",".","For","example",",","the","pristine","sample","shows","a","discharge","capacity","of","70","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":82,"tokens":["It","shows","that","the","polymers","have","good","thermal","stability",".","When","preparing","the","polymer","electrolyte",",","the","slurry","formed","by","PMMA","-","PVDF","@","LATP","(","Fig",".","4f",")","is","milky","white","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":83,"tokens":["07","and","1",".","46","times","higher","than","that","of","uncoated","-","LCOMg","at","0",".","1","and","3",".","0","C",",","respectively",".","This","improvement","of","the","cell","performances","with","the","LATP","coating","is","even","more","noteworthy","when","it","is","applied","to","the","prismatic","full","cells",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":84,"tokens":["To","compare","the","deteriorated","states","of","LATP","-","LCOMg","and","uncoated","-","LCOMg",",","the","SEM","images","and","the","elemental","distributions","from","the","EDS","of","the","cross","-","sectioned","particles","after","cycling","are","shown","in","Figure","4b",",","c","."],"ner_tags":["O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":85,"tokens":["The","lithium","residues","would","speed","up","the","hydrolysis","of","LiPF6",",","generating","more","LiF",",","H2O",",","HF",",","and","LixPOFy","-","type","compounds","according","to","those","reactions",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":86,"tokens":["This","property","is","material","-","sensitive","and","varies","with","different","materials",".","It","also","provides","more","channels","for","Li","+","ion","migration","[","36",",","46","]",".","The","corresponding","differential","capacity","plot","is","given","in","Fig",".","3","(","b",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":87,"tokens":["and","now","is","a","postdoctoral","appointee","at","Argonne","National","Laboratory",".","Her","research","interest","includes","functional","electrolytes",",","surface","modification","of","electrode","materials","for","lithium","ion","and","lithium","air","batteries","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":88,"tokens":["The","cell","assembly","was","conducted","in","an","argon","-","filled","glove","box","with","a","dew","point","below","−","80","°","C",".","To","measure","the","anodic","stability","of","the","Al2O3","-","containing","polymeric","binders",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":89,"tokens":["5","ppm","for","the","pristine","material","and","152",".","3","ppm","for","the","V2O5","-","coated","material",".","However",",","a","much","small","area","is","covered","by","the","compounds","for","the","case","of","the","separator","of","V2O5","-","coated","material","in","Fig",".","6","(","c",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":90,"tokens":["18Co0",".","15Ni0",".","15Mn0",".","52O2",".","Fig",".","4",".","SEM","images","of","the","(","a",")","pristine",",","and","(","b",")","1",".","0","wt","%",",","(","c",")","3","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":91,"tokens":["8","shows","the","schematics","of","forming","such","an","interphase","between","particles","of","LLZO","electrolyte","and","LCO","[","156","]",".","Schematics","of","the","interphase","-","engineered","all","-","ceramic","cathode","\/","electrolyte","(","reproduced","from","Han","et","al",".",")","[","156","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":92,"tokens":["(","2","-","6",")","LiNiO2","-","based","cathode","materials","(","Ni","content","≤","0",".","6",")","have","been","successfully","commercialized","for","LIBs",";","meanwhile",",","Ni","-","rich","(","Ni","content",">","0",".","6",")","layered","cathode","materials","have","attracted","a","lot","of","attention","because","of","their","higher","capacity","."],"ner_tags":["O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":93,"tokens":["Ni3","+","\/","Ni2","+","transformation","and","lithium","leach","can","be","delayed","by","coating","due","to","isolating","the","material","from","H2O","and","CO2",".","Explicit","evidence","for","a","larger","electrochemical","polarization","is","found","in","the","EIS","(","Fig",".","13","(","c",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":94,"tokens":["which","made","up","for","the","Li3PO4","coating","defects",".","Furthermore",",","the","continuous","coating","layer","could","prevent","direct","contact","between","bulk","material","and","electrolyte","and","then","suppressed","side","reactions","on","the","surface","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":95,"tokens":["Si",",","Mo",",","W",",","etc",".",")",",","LixVOPO4",",","LiVPO4F",",","LiMPO4","(","M","0","Mn",",","Co",",","Ni",")","displays","operating","voltage","above","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":96,"tokens":["The","self","-","aggregation","interface","on","the","NCM811","cathode","are","confirmed","by","TEM","and","EDS","results","(","Fig",".","2a","–","c",")",".","The","compatible","region","layer","has","a","thickness","of","about","10","nm","on","NCM811","particles","(","Fig",".","2a",")",","],"ner_tags":["O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O"]}
{"id":97,"tokens":["and","maintaining","the","interaction","between","PEO","and","LiDFOB","during","high","voltage","cycling",".","Nevertheless",",","the","achieved","progress","on","cyclability","of","the","investigated","solid","-","state","cell","is","still","far","from","threshold","allowing","its","practical","use","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":98,"tokens":["Ionic","liquids","are","widely","used","class","of","materials","in","high","voltage","lithium","batteries","with","liquid","electrolytes","due","to","their","exceptional","thermal","stability","and","electrochemical","stability","range",".","For","instance",",","PEO","-","LiTFSI","-","PYR14TFSI","(","N","-","butyl","-","N","-","methylpyrrolidinium","bis","(","trifluoromethanesulfonyl",")","imide",")","based","solid","polymer","electrolyte","(","Fig",".","5",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":99,"tokens":["As","we","discussed","above",",","in","the","case","of","the","coated","cathode","powder",",","ALD","is","capable","of","depositing","uniform","dense","coating","layers","with","poor","conductivity","on","the","cathode","particles","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","O","O"]}
{"id":100,"tokens":["This","Minireview","summarizes","the","recent","development","of","HSSEs","and","discusses","their","design","principles",",","performance","and","ionic","conducting","mechanism",".","Abstract","Conventional","liquid","electrolytes","for","lithium","batteries","usually","suffer","from","irreversible","decomposition","and","safety","concerns","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":101,"tokens":["Al2O3",",","SiO2","and","ZrO2","were","dispersed","in","polymer","matrix","to","suppress","the","crystallinity","of","polymer","chains",".","18","Such","inorganic","fillers","facilitate","motion","of","polymer","chains","and","notably","improve","the","ionic","conductivity","by","1","–","2","orders","of","magnitude","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":102,"tokens":["1","C",".","Wu","and","co","-","workers","proposed","a","nonaqueous","self","-","assemble","route","to","prepare","“","solid","in","liquid","”","HSSEs",",","in","which","the","ILs","are","encapsulated","within","3D","inorganic","TiO2","substrates","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":103,"tokens":["This","hinders","the","Li","+","and","electron","conduction",",","resulting","in","poor","kinetics","at","a","high","input","current",".","The","electrochemical","experiments","were","carried","out","using","2025","-","type","coin","cells",",","with","lithium","foil","as","the","anode","electrode","separated","by","the","porous","polypropylene","fi","lm","(","Celgard","2700",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":104,"tokens":["In","addition",",","the","routine","helps","weaken","the","space","charge","layer","of","active","material","commonly","inevitable","in","the","case",",","as","demonstrated","by","calculation","of","Density","Functional","Theory","and","Atomic","force","microscopy","analysis","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":105,"tokens":["The","thickness","evolution","of","the","ZrO2","coating","layers","resulting","from","different","ALD","cycles","was","studied","by","the","TEM","technique","(","see","Fig",".","S9","in","Supplementary","data",")","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":106,"tokens":["Lu","et","al",".","proposed","that","monoclinic","Li2TiO3","would","be","a","good","candidate",".","(","19",")","They","reported","that","Li2TiO3","-","coated","LiMO2","(","M","0","Ni",","],"ner_tags":["O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":107,"tokens":["The","development","of","high","-","voltage","LiCoO2","is","essential","for","achieving","lithium","-","ion","batteries","with","high","volumetric","energy","density",",","however",",","it","faces","a","great","deal","of","challenges","owing","to","the","materials",",","structure","and","interfacial","instability","issues","."],"ner_tags":["O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":108,"tokens":["TiF4","was","gently","grinded","prior","to","use",".","A","typical","pulse","and","purge","durations","for","TiF4","subcycle","are","0",".","1","s","and","15","s",",","respectively",".","Typical","pulse","and","purge","durations","for","AlCl3","subcycle","are","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O"]}
{"id":109,"tokens":["Adamas","-","beta",")","in","an","agate","mortar",".","The","mixture","was","then","calcined","at","750","°","C","for","12","h","under","an","oxygen","atmosphere","in","a","tubular","furnace",".","LiOH","(",">","99","%",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":110,"tokens":["and","W","is","the","finite","-","length","Warburg","impedance","that","reflects","the","solid","-","state","diffusion","of","Li","+","into","LiCoO2","cathode","[","65","]",".","Assuming","that","the","surface","film","is","related","to","ALD","derived","metal","oxide","layers",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":111,"tokens":["The","optimized","PVdF","–","HFP","\/","PEG","\/","PEGDMA","(","5","\/","3","\/","2","wt",".","%",")","electrolyte","containing","1M","LiPF6","\/","EC","–","diethyl","carbonate","(","DEC",")","(","electrolyte","uptake",":","98","%",")","showed","in","a","full","cell","with","carbon","anode","and","LiCoO2","cathode","high","ionic","conductivity","(","1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O"]}
{"id":112,"tokens":["The","samples","were","heated","in","a","stainless","steel","pan","with","gold","-","plated","copper","with","a","heating","rate","of","5","°","C","min","–","1",".","Figure","1","shows","a","schematic","illustration","of","the","coating","process","of","NCM","-","811","with","the","inorganic","tungsten","oxide","layer","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":113,"tokens":["On","the","other","hand",",","authors","did","not","prove","continuous","decomposition","of","the","SPE","whereas","showing","that","the","presence","of","PYR14TFSI","ionic","liquid","significantly","decreased","interfacial","resistance","and","diminished","the","dissolution","of","aluminum","corrosion","products","into","the","electrolyte","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":114,"tokens":["In","the","study",",","an","interface","engineering","strategy","was","facilely","employed","to","solve","the","issue","of","the","poor","interface","in","NCM811","\/","garnet","-","type","SSBs","by","bridging","Li","+","ion","transport","and","simultaneously","weakening","the","SCL","across","the","interface","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":115,"tokens":["In","this","class","also","IGPEs","materials","deserve","a","mention",".","The","implementation","of","ILs","materials","enables","improved","safety",",","along","with","good","cyclability","and","high","-","capacity","retention","at","room","temperature","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":116,"tokens":["5Co0",".","2Mn0",".","3O2","material",".","As","compared","with","the","position","of","bare","sample",",","small","band","shifts","to","lower","wavenumbers","are","observed","for","the","coated","sample",",","it","is","in","good","agreement","with","the","slight","increase","of","the","cell","parameters","[","34","]"],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":117,"tokens":["(","44",",","45",")","To","avoid","the","direct","contact","between","LiCoO2","and","PEO",",","NASICON","-","type","solid","electrolyte","LATP","was","introduced","as","a","coating","layer","on","LiCoO2","particles","through","a","mechanical","mixing","process","reported","in","our","previous","work","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":118,"tokens":["6","V",".","Because","the","characteristic","potential","for","violent","PEO","decomposition","and","gas","release","is","identified","as","4",".","5","V","versus","Li","\/","Li","+",",","this","voltage","may","be","referenced","as","the","cap","for","safe","operation","of","PEO","-","based","SPBs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":119,"tokens":["Among","solid","polymer","electrolytes",",","PEO","based","solid","materials","are","nowadays","the","most","widespread","option",".","In","its","pure","form","PEO","cannot","guarantee","great","performances","in","terms","of","conductivities","and","electrochemical","stabilities","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":120,"tokens":["Therefore",",","the","coating","layers","are","capable","of","forming","a","significant","protective","function","on","LiCoO2","cathodes",".","In","particular",",","the","Al2O3","coating","could","protect","the","cathode","more","effectively","from","the","reactions","with","the","electrolyte","during","the","charge","\/","discharge","processes","."],"ner_tags":["O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":121,"tokens":["Once","the","thickness","of","coating","layer","exceeds","the","threshold","value",",","the","Li","+","ion","and","electron","transport","kinetics","are","severely","affected","[","34a","]",".","The","intensity","ratio","of","(","003",")","\/","(","104",")","is","an","important","factor","to","determine","the","degree","of","disorder","in","the","layered","oxides","."],"ner_tags":["O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":122,"tokens":["and","good","compatibility","with","lithium","anode",".","In","addition",",","200","cycles","of","Li","\/","LiCoO2","at","25","°","C","were","demonstrated",".","It","is","important","to","note","that","the","lithium","salt","choice","is","important","for","high","voltage","stability","of","solid","electrolytes","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":123,"tokens":["9","V","vs",".","Li","\/","Li","+","couple",")","[","7","]",",","[","8","]",",","[","9","]",".","As","an","important","cathode","in","RLIBs",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O"]}
{"id":124,"tokens":["25","V","is","due","to","the","reduction","of","Mn4","+","[","34","]",".","First",",","the","oxidation","potential","for","the","oxygen","loss","process","increases","to","4",".","73","V","(","for","the","1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":125,"tokens":["Recently",",","Balo","et","al",".","[","58","]","investigated","the","effect","of","1","-","ethyl","-","3","-","methylimidazolium","bis","(","fluorosulfonyl",")","imide","(","EMIMFSI",")","on","PEO","-","LiTFSI","based","GPEs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":126,"tokens":["The","TEM","images","of","the","ZrO2","layer","fabricated","by","ALD","on","a","Si","wafer","are","shown","in","Fig",".","2a",".","The","thickness","of","the","ZrO2","layer","per","cycle","was","estimated","using","Si","wafer","owing","to","the","high","porosity","of","the","prepared","NMC532","electrode","[","28","]","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O"]}
{"id":127,"tokens":["which","are","expected","to","promote","the","development","of","high","performance","cathode","materials",".","Highlights","•","Ultrathin","coating","is","deposited","via","ALD","with","high","conformality","and","atomic","scale","thickness","control",".","•","Ultrathin","amphoteric","oxide","ZnO","coating","layer","is","amorphous",".","•","NCM","-","523","coated","with","8","ZnO","layers","exhibits","the","significantly","improved","electrochemical","performance",".","•","Ultrathin","coating","layer","can","protected","the","active","material","from","the","dissolution","and","HF","attack","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O"]}
{"id":128,"tokens":["5","V","half","-","cells","with","lithium","anode",".","The","2900","mA","h","full","cells","show","85","%","of","capacity","retention","after","500","cycles","and","more","than","60","%","after","700","cycles","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":129,"tokens":["Each","battery","contains","a","semicircle","caused","by","charge","transfer","resistance","(","Rct",")","and","a","diagonal","line","corresponding","to","Li","+","diffusion",".","It","can","be","seen","from","the","figure","that","the","impedance","of","the","three","batteries",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":130,"tokens":["In","a","separate","container",",","0",".","549","g","of","LiNO3","and","0",".","900","g","of","NH4H2PO4","were","dissolved","in","8","mL","of","water",".","After","completely","mixing","the","two","solutions",",","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":131,"tokens":["35","g","cm","–","3",".","The","pouch","-","type","full","-","cells","were","assembled","in","a","dry","room","with","a","humidity","of","less","than","1","%",".","The","plane","-","wave","cutoff","energy","was","set","to","be","520","eV","and","convergence","was","considered","as","reached","when","the","residue","atomic","forces","were","less","than","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":132,"tokens":["The","results","indicate","that","NCM811","coated","with","two","cycles","of","ALD","has","a","lower","charge","-","transfer","resistance","than","the","other","coating","cycles",".","Thus",",","an","optimized","thin","ALD","coating","can","act","as","a","protective","matrix","for","the","cathode","without","hindering","the","movement","of","ions","and","electron","across","the","interface","."],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":133,"tokens":["Recently",",","hybrid","solid","-","state","electrolytes","(","HSSEs",")","that","integrate","the","merits","of","different","electrolyte","systems","have","been","under","intensive","study",".","Herein",",","we","summarize","the","recent","progress","of","HSSEs","with","different","compositions","and","structures","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":134,"tokens":["Also",",","the","lattice","fringes","outside","the","layer","are","about","2",".","09","Å","and","2",".","61","Å",",","and","these","correspond","to","the","(","6","1","1",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":135,"tokens":["5","C",".","Moreover",",","rate","capability","of","this","cell","was","studied","from","0",".","5","C","to","5","C",",","at","C","rates","of","0",".","5",",","1",",","2",",","3","and","5","C",",","providing","the","discharge","capacity","of","109",".","1",",","100",".","1",",","89",".","3",",","80","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":136,"tokens":["The","electrochemical","performances","of","bare","and","ZnO","-","coated","samples","have","been","measured",",","and","the","influence","of","ZnO","coating","layer","on","the","rate","capability","and","cycleability","of","cathode","is","also","explored","."],"ner_tags":["O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O"]}
{"id":137,"tokens":["and","PMMA","(","in","the","weight","ratio","of","3",":","1",")","as","polymer","matrix",",","20","wt",".","%","of","LiTFSI","as","lithium","salt","and","70","wt",".","%","of","1","-","ethyl","-","3","-","methylimidazolium","bis","(","trifluoromethylsulfonyl",")","imide","(","EMIMTFSI",")","as","IL","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":138,"tokens":["After","60","cycles",",","the","corresponding","capacity","retentions","still","maintain","86",".","4","%",",","89",".","9","%",",","96",".","2","%","and","95",".","5","%",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":139,"tokens":["The","half","-","cells","were","charged","and","discharged","in","the","voltage","range","of","3",".","0","–","4",".","5","V","(","vs","Li","+","\/","Li",")","with","a","current","density","of","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":140,"tokens":["As","a","result",",","we","obtain","mixed","electronic","and","ionic","conductor","-","coated","LiCoO2","with","Mg","doping",".","We","thoroughly","characterize","the","coating","layer","by","various","analysis","techniques","including","scanning","electron","microscopy","(","SEM",")",",","transmission","electron","microscopy","(","TEM",")","with","electron","energy","loss","spectroscopy","(","EELS",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":141,"tokens":["This","indicates","that","a","slight","amount","of","Li","ions","are","released","from","the","lattice","during","post","annealing","due","to","the","small","free","enthalpy","of","lithium",".","The","lattice","parameters","of","the","two","coated","samples","are","all","similar","as","those","of","the","pristine","-","post","annealed","sample","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":142,"tokens":["1","J","g","−","1",".","The","exothermic","temperature","increases","to","289",".","73","°","C","with","the","coating","amount","increasing","to","3",".","0","wt","%",".","At","such","high","voltage",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":143,"tokens":["1Mn0",".","1O2","was","investigated",",","which","is","shown","in","Figures","S7","and","S8","(","Supporting","Information",")",".","Figure","7a","compares","the","initial","charge","and","discharge","curves","for","the","bare","LiNi0","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":144,"tokens":["Generally",",","increased","amount","of","LixPFyOz","is","generated","via","salt","decomposition","during","cycling","at","higher","cut","-","off","voltages",",","indicating","early","depletion","of","electrolyte","and","contamination","of","electrode","surface","[","34","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":145,"tokens":["and","a","line","at","low","frequency","region",",","being","in","good","agreement","with","previously","reported","results","[","63","]",",","[","64","]",".","Importantly",",","it","is","noticeable","that","the","EIS","of","Al2O3","coated","LiCoO2","shows","the","nearly","same","trend","for","the","20th","and","50th","cycles",",","but","its","diameter","of","two","overlapped","semicircles","has","higher","value","than","that","of","LiCoO2","through","these","two","cycles",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O"]}
{"id":146,"tokens":["the","amount","of","Co","content","in","the","electrolyte","was","measured","by","inductively","coupled","plasma","atomic","absorption","spectroscopy","(","ICP","-","AAS",")",".","Fig",".","1a","compares","the","XRD","pattern","of","pristine","LiCoO2","electrode","with","the","coated","LiCoO2","electrodes","by","TiO2",",","ZrO2",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","B-CATHODE_MATERIAL","O","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O"]}
{"id":147,"tokens":["Figure","6","shows","the","TEM","images","of","the","bare","LiNi0",".","8Co0",".","1Mn0",".","1O2","and","surface","-","modified","samples","to","confirm","the","dual","-","conductive","coating","layers","on","the","particles","surface","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O"]}
{"id":148,"tokens":["the","Al2O3","coating","brings","the","best","cycling","performance","while","the","ZrO2","coating","contributes","to","the","best","rate","capability",",","which","reveals","that","ALD","derived","coating","materials","are","functionally","specific",","],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O"]}
{"id":149,"tokens":["0","and","4",".","4","V","(","versus","Li","\/","Li","+",")","at","25","and","45","°","C",".","For","all","the","coin","cells",",","the","first","charge","–","discharge","cycle","was","conducted","at","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":150,"tokens":["and","a","remarkably","high","lithium","-","ion","transference","number","was","reported","by","Choi","et","al",".","[","130","]","Subsequently",",","Li","\/","LiCoO2","solid","-","state","cells","prepared","using","this","nanocomposite","solid","electrolyte","exhibited","high","electrochemical","performance","at","25","°","C","and","80","°","C","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":151,"tokens":["and","many","researchers","confirmed","the","successful","improvement","with","various","metal","oxides","as","coating","materials",".","(","12","-","18",")","However",",","because","most","of","the","metal","oxides",",","such","as",",","MgO",",","ZrO2",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":152,"tokens":["The","hypothesis","is","supported","by","simultaneously","suppressed","side","reactions","and","surface","phase","transformations","by","CoxB","infusion",".","To","demonstrate","the","correlation",",","we","first","characterized","the","fresh","surface","generated","by","intergranular","cracking","in","cycled","pristine","NCM","under","TEM","(","Fig",".","4b",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":153,"tokens":["In","order","to","investigate","the","chemical","states","of","all","the","elements","(","Li",",","Ni",",","Co",",","Mn",",","O",",","P",",","and","N",")","on","the","particles","surface","and","the","changes","of","the","surface","properties","for","the","cathode","materials",",","XPS","analysis","of","bare","LiNi0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":154,"tokens":["1C",",","0",".","5C",",","1C",",","2C",",","and","5C",",","respectively",",","indicating","a","capacity","retention","of","30",".","3","%","at","5C",",","the","LATP","@","LCO","-","700","exhibits","discharge","capacity","of","216",".","3",",","197",".","8",",","181",".","1",",","156",".","2",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":155,"tokens":["To","further","give","evidence","of","the","effect","of","the","dual","-","conductive","coating","layers","for","improving","the","cycling","stability",",","we","cycled","the","cells","assembled","with","bare","and","surface","-","modified","cathodes","at","1","C","to","accelerate","capacity","fading","as","shown","in","Figure","7c","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":156,"tokens":["2","μ","m",".","The","SEM","images","of","NCM",",","Al2O3","-","coated","NCM","and","LiAlO2","-","coated","NCM","are","compared","in","Fig",".","3",".","Contrary","to","the","smooth","and","clean","NCM","surface","(","Fig",".","3a",")",","],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O"]}
{"id":157,"tokens":["and","then","aged","for","24","h",".","The","electrochemical","test","was","measured","between","2",".","8","and","4",".","5","V","(","versus","Li","\/","Li","+",")","on","a","CT2001A","Land","instruments","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":158,"tokens":["5","s",",","waiting","time","and","purge","time","of","4","s",",","respectively",".","Vapors","of","two","precursors","were","alternately","carried","by","N2","gas","in","a","reaction","chamber","at","100","°","C","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":159,"tokens":["Generally",",","liquid","electrolytes","require","two","main","features",":","high","dielectric","constant","and","low","viscosity",",","hard","to","find","both","parameters","on","a","single","solvent",".","To","gain","both","salt","solvation","and","ions","transport",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":160,"tokens":["and","Li3PO4","simultaneously",".","Spinel","oxide","is","known","to","have","much","weaker","oxidizing","ability","at","high","voltages","than","layered","oxide",",","and","the","oxygen","activity","has","been","considered","as","the","root","cause","of","the","surface","instability","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":161,"tokens":["LiNi0",".","8Co0",".","1Mn0",".","1O2","powder","was","prepared","by","mixing","co","-","precipitated","Ni0",".","8Co0",".","1Mn0",".","1","(","OH",")","2","and","LiOH","·","H2O","at","a","molar","ratio","of","1",":","1",".","05",","],"ner_tags":["B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":162,"tokens":["PEO","based","solid","polymer","electrolytes","suffer","of","poor","mechanical","stability","at","common","SSB","battery","operating","temperature","(",">","50","°","C",")",".","The","use","of","inorganic","fillers","to","improve","mechanical","stability","of","PEO","-","based","SPEs","can","be","considered","as","a","very","efficient","strategy","among","others","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":163,"tokens":["S","-","4700",",","Hitachi",",","Japan",")",",","energy","-","dispersive","X","-","ray","spectroscopy",",","and","high","-","resolution","transmission","electron","microscopy","(","HR","-","TEM",";","JEM","-","2000",",","EX","-","II",",","JEOL",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":164,"tokens":["and","it","completely","wetted","the","GBs","with","an","equivalent","contact","angle","of","zero","degree",".","More","examples","of","TEM","-","EDS","mapping","in","Supplementary","Figs",".","6","–","8","confirmed","the","uniform","surface","coverage","and","infusion","into","the","GBs","deep","inside","the","secondary","particles","up","to",">","2","–","3","μ","m",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":165,"tokens":["In","this","light",",","Seki","and","co","-","authors","[","96","]","reported","improved","electrochemical","behavior","of","Li","\/","P","(","EO","\/","MEEGE","\/","AGE",")","-","LiBF4","\/","LiCoO2","solid","-","state","cell","with","Li3PO4","-","coated","LiCoO2","particles","(","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":166,"tokens":["We","also","noticed","that","the","voltage","hysteresis","increased","slower","for","coated","sample","when","compared","to","pristine","NMC","-","811","(","Figure","6d",")",".","The","fact","that","the","LiAlF4","coating","layer","suppressed","the","fast","impedance","growth","supports","that","LiAlF4","film","could","minimize","the","magnitude","of","parasitic","reactions","at","the","electrode","–","electrolyte","interface","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":167,"tokens":["The","organic","CEI","species","can","be","derived","from","the","electrolyte","degradation",",","such","as","the","ethylene","carbonate","(","EC",")","ring","-","opening",",","which","can","be","triggered","by","the","highly","oxidative","Co4","+","as","well","as","the","activated","lattice","oxygen","at","high","voltage",".","[","19","]"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":168,"tokens":["and","~","166","mAh","g","-","1","for","pristine",",","2",",","5",",","and","10","cycles","of","ALD","coating",".","It","is","clear","that","the","two","-","cycle","ALD","-","coated","electrode","has","a","higher","capacity","than","the","pristine","electrode","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":169,"tokens":["As","shown","in","Figure","9",",","the","bare","sample","has","the","highest","amount","of","dissolved","transition","metal","ions","(","Ni",",","Co",",","Mn",")","and","HF","in","the","electrolyte",",","whereas","less","transition","metal","ions","dissolved","from","the","surface","-","modified","cathode","electrodes","and","the","content","of","HF","decreased","as","well","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O"]}
{"id":170,"tokens":["In","turn",",","Park","and","co","-","authors","[","126","]","reported","hybrid","electrolyte","based","on","poly","(","1",",","4","-","butylene","adipate",")","(","PBA",")","polymer","mixed","with","LiClO4","and","60","–","80","wt",".","%","of","Li1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":171,"tokens":["9","mA","h","g","−","1","and","242",".","6","\/","206",".","8","mA","h","g","−","1",",","respectively",",","while","their","initial","coulombic","efficiencies","are","83",".","7","%",",","86",".","2","%","and","85",".","2","%",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":172,"tokens":["After","50","cycles",",","it","is","only","about","70",".","4","Ω",",","much","smaller","than","that","for","the","bare","one",".","From","the","plot","of","Zre","as","a","function","of","ω","−","1","\/","2","shown","in","Fig",".","10",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":173,"tokens":["In","contrast",",","the","aged","coated","materials","show","significantly","less","degradation","effects","at","the","electrode","surface",".","While","pushing","the","limit","of","cutoff","potentials","allows","batteries","to","provide","greater","energy","densities","with","enhanced","specific","capacities","and","higher","voltage","outputs",",","it","raises","key","challenges","with","thermodynamic","and","kinetic","stability","in","the","battery","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":174,"tokens":["S5","showed","the","close","-","knit","interface","in","NCM811","-","LP","-","LLZTO","SSB",".","The","excellent","cycling","stability","and","rate","performance","of","SSBs","indicate","the","good","safety","and","stability","of","the","garnet","-","type","SSBs","."],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":175,"tokens":["To","compare","CV","curves","of","these","two","types","of","coatings","on","LiCoO2","in","Fig",".","5",",","Fig",".","6","demonstrates","that","these","two","coatings","can","strongly","affect","lithium","extraction","from","LiCoO2","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O"]}
{"id":176,"tokens":["Among","others",",","these","challenges","are","hindering","the","broad","application","of","Ni","-","rich","materials","in","commercial","cells",".","One","of","the","challenges","for","a","suitable","NCM","-","811","material","lies","in","the","synthesis","process","of","the","Ni","-","rich","material","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":177,"tokens":["Herein",",","we","fabricated","an","ultrathin","ZrO2","coating","on","the","surface","of","the","as","-","prepared","NMC532","electrode","via","atomic","layer","deposition","(","ALD",")","to","improve","the","electrochemical","performances","of","the","high","-","voltage","NMC532","\/","graphite","system","."],"ner_tags":["O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O"]}
{"id":178,"tokens":["Secondly",",","concentration","polarization","in","conventional","liquid","electrolytes",",","which","is","due","to","the","low","lithium","ion","transference","number",",","could","be","addressed","in","single","-","ion","conducting","SSEs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":179,"tokens":["and","2","-","ALD","-","cycle","coatings","show","the","best","effect",";","(","b",")","the","Al2O3","coating","with","high","band","gap","energy","(","Eg","0","9",".","00","eV",")","effectively","suppresses","the","phase","transitions","during","electrochemical","cycling",",","showing","better","cycling","performance","than","the","TiO2","and","ZrO2","ones",",","but","the","worse","rate","capability","from","its","poor","conductivity",";","(","c",")"],"ner_tags":["O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":180,"tokens":["LRE",")","because","oxidized","transition","metal","ions","and","oxygen","ions","in","the","cathode","active","materials","will","provoke","the","oxidative","decomposition","of","the","PEO","backbone","[","77",",","[","79","]",",","[","80","]",",","[","81","]",",","[","82","]","]",",","especially",",","in","the","presence","of","TFSI","−","anions","[","82","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":181,"tokens":["and","the","transmission","capacity","of","Li","+","at","the","interface","is","improved",".","So",",","the","interface","-","engineering","strategy","in","NCM811","-","LP","-","LLZTO","is","feasible","and","useful","for","SSBs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":182,"tokens":["It","can","be","found","that","progressive","reactions","between","LiCoO2","and","LATP","occur","with","the","increase","of","the","temperatures","(","Figure","2i",")",".","Detailed","Rietveld","refinement","results","are","shown","in","Figure","S9","and","Tables","S1","and","S2","in","the","Supporting","Information","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":183,"tokens":["Structural","analysis","shows","that","V2O5","-","coating","layer","has","more","advantage","over","other","oxide","coating","in","delaying","Ni3","+","\/","Ni2","+","transformation","and","lithium","extraction","from","bulk","surface",","],"ner_tags":["O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":184,"tokens":["Cypher","S",")",",","and","the","sample","was","distributed","on","a","mica","sheet","for","representation",".","The","electrochemical","cycling","performance","of","the","garnet","-","type","solid","state","battery","was","assessed","using","a","CR2025","coin","-","type","cell","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":185,"tokens":["Nickel","-","containing","electrolytes","were","prepared","by","dissolving","0",",","200","and","600","ppm","Ni","(","TFSI",")","2","(","TFSI",",","trifluoromethylsulfonimide",")","in","the","base","electrolyte","(","1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":186,"tokens":["To","confirm","this","hypothesis",",","Chen","and","Dahn","heat","treated","aged","LiCoO2","at","550","°","C","with","the","anticipation","of","reversing","the","effect","of","the","aged","surface",",","and","they","did","observe","similar","improvement","in","capacity","retention","of","the","grinded","sample","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":187,"tokens":["Atomic","-","resolution","HAADF","image","in","the","surface","region",",","local","layered",",","and","spinel","-","like","phases","are","enlarged","from","the","red","and","green","frames",",","respectively",",","as","indicated","by","the","overlaid","structural","models",".","e","–","h",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":188,"tokens":["(","3",",","4",")","The","accumulation","of","byproducts","at","the","interface","leads","to","high","internal","resistance",",","which","can","eventually","cause","battery","failure",".","In","the","past","few","decades",",","great","efforts","have","been","devoted","to","achieve","a","stable","interfacial","layer","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":189,"tokens":["46","Reproduced","with","permission",".","Copyright","2014",",","Wiley","-","VCH",".","(","b",")","Chemical","structures","and","ternary","phase","diagram","of","PIL","\/","TEOS","\/","Li","-","IL","and","appearances","of","HIGE","samples","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":190,"tokens":["In","terms","of","performance",",","achieving","high","ionic","conductivity","around","ambient","temperature","comparable","to","that","of","liquid","electrolytes","still","represents","the","primary","task","for","HSSEs",".","In","addition","to","choosing","components","with","high","intrinsic","ionic","conductivity",",","constructing","continuous","Li","+","ion","transport","channels","by","designing","nanostructured","components","("],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":191,"tokens":["Cobalt","boride","metallic","glass","was","successfully","applied","to","a","Ni","-","rich","layered","cathode","LiNi0",".","8Co0",".","1Mn0",".","1O2",".","It","dramatically","improved","the","rate","capability","and","cycling","stability",",","including","under","high","-","discharge","-","rate","and","elevated","-","temperature","conditions","and","in","pouch","full","-","cells","."],"ner_tags":["B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":192,"tokens":["Compared","between","LNMO","and","SnO2","@","LNMO","solid","-","state","batteries","with","two","positive","electrodes",",","the","Rct","of","LNMO","@","SnO2","solid","-","state","batteries","is","smaller","than","that","of","LNMO","solid","-","state","batteries",",","indicating","that","the","appearance","of","SnO2","coating","effectively","suppresses","the","increase","in","resistance","and","charge","transfer","resistance",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":193,"tokens":["0","eV","in","the","C","1s","spectra","that","was","attributed","to","carbonate","(","–","OCO2","–",")",",","including","lithium","alkyl","carbonate","and","lithium","carbonate",".","By","contrast",",","NCM","\/","Al2O3","showed","intense","peaks","at","approximately","685","eV","(","corresponding","to","LiF",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":194,"tokens":["and","red","represents","the","outside","surface","of","NCM811","-","LP","-","LLZTO",".","Zirconium","(","Zr",")",",","phosphorus","(","P",")",",","and","lanthanum","(","La",")","were","only","distributed","on","the","edge","(","the","region","indicated","in","the","red","circle",")","."],"ner_tags":["O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":195,"tokens":["On","the","other","hand",",","it","was","already","proved","that","PEO","-","LiTFSI","based","solid","electrolytes","are","anodically","stable","only","up","to","∼","3",".","7","-","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":196,"tokens":["and","5","wt","%","polytetrafluoroethylene","as","a","binder",".","The","calculated","amount","of","powder","was","dissolved","in","N","-","methyl","pyrrolidone","solvent","to","obtain","a","homogeneous","slurry",",","which","was","then","cast","onto","aluminum","foil","with","a","blade","and","dried","at","120","°","C","in","vacuum","for","6","h","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":197,"tokens":["While","the","bare","-","LCO","exhibits","discharge","capacity","of","225",".","5",",","193",".","7",",","157",".","6",",","120",".","4",",","and","68",".","5","mAh","g","−","1","under","0","."],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":198,"tokens":["In","addition",",","we","have","proved","that","the","excellence","of","this","material","is","preserved","in","the","industrial","application","for","the","4",".","4","V","prismatic","full","cells",".","The","cells","show","excellent","capacity","retention","of","85","%","after","500","cycles","and","more","than","60","%","after","700","cycles",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":199,"tokens":["Fig",".","12",".","XPS","spectra","of","C1s","(","a",")","and","O1s","(","b",")","taken","from","the","surface","of","pristine","and","V2O5","-","coated","sample","after","stored","in","air","for","30","days","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":200,"tokens":["Compared","with","the","bulk","TFY","signal",",","the","relatively","weak","Co4","+","associated","feature","in","TEY","can","be","attributed","to","inevitable","interface","reactions","against","carbonate","electrolyte",".","By","comparison","of","the","characteristic","peaks","(","A","and","B",")","for","both","cathodes",",","it","exhibits","much","more","stable","and","smaller","peak","intensity","for","LATP","@","LCO","-","700","when","compared","with","those","for","bare","-","LCO",",","suggesting","that","a","much","lower","amount","of","Co4","+","accumulated","on","the","LATP","@","LCO","-","700","and","relatively","modest","recovery","over","long","cycles","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":201,"tokens":["Here",",","we","provide","some","perspectives","that","may","be","worthy","of","particular","attention",".","Gaining","in","-","depth","understanding","of","lithium","conducting","mechanisms","in","HSSEs","is","an","important","task","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":202,"tokens":["Experimental","results","show","that","the","combination","of","a","solid","electrolyte","with","high","mechanical","elongation","and","ionic","conductivity","and","an","improved","cathode","material","exhibits","better","performance","than","previously","reported","all","-","solid","-","state","batteries","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":203,"tokens":["No",".","0415G02",";","and","“","Jiangsu","Postdoctoral","Science","Research","Foundation","”",",","No",".","1402030B",".","We","would","like","to","acknowledge","them","for","the","financial","support",".","Research","Article","J","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":204,"tokens":["(","3",")","Fig",".","6",".","Initial","charge","–","discharge","curves","of","the","bare","and","ZrO2","-","coated","LiNi0",".","5Co0",".","2Mn0",".","3O2","electrodes","at","room","temperature","(","25","°","C",")",",","indicating","the","initial","Coulombic","efficiency","is","remarkably","improved","after","ZrO2","coating","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O"]}
{"id":205,"tokens":["and","another","broad","peak","at","4",".","2","V","correspond","to","Co","3","+","-","Co","4","+",",","along","with","other","structural","transitions","similar","to","those","of","NCM811","[","15","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O"]}
{"id":206,"tokens":["Dramatic","electrochemical","performance","improvement","has","been","demonstrated","with","only","2","atomic","layers","of","Al2O3","on","LiCoO2",".","ALD","is","believed","to","be","an","important","technique","for","the","research","of","high","performance","cathode","materials","for","lithium","ion","batteries","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":207,"tokens":["and","it","has","been","blamed","for","dissolution","of","the","transition","metals","and","surface","corrosion","of","cathode","materials",".","52","The","electrochemical","performance","of","lithium","-","ion","cells","can","be","improved","by","simply","adding","nano","-","sized","oxide","particles","to","the","electrolyte","as","a","HF","scavenger","to","reduce","the","electrolyte","acidicity","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":208,"tokens":["(","7",",","38",")","XPS","analysis","clearly","reveals","that","the","PPy","-","LP","sample","has","Ni","2p",",","Co","2p",",","and","Mn","2p","peaks","with","negligible","binding","energy","shifts","compared","to","the","bare","sample",",","indicating","that","the","surface","structural","environments","of","Ni",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":209,"tokens":["Concerning","the","surface","-","initiated","degradation",",","two","major","decomposition","reaction","path","ways","were","shown","for","NCM","materials","under","high","voltage","operation","conditions",".","Firstly",",","the","surface","lattice","structures","suffer","from","irreversible","structural","transformation","at","high","voltages",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":210,"tokens":["At","the","scan","rate","of","0",".","2","mV","·","s","−","1","(","Fig",".","6c",")",",","as","the","number","of","turns","increases",",","the","CV","graph","gradually","overlaps",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":211,"tokens":["This","fact","strongly","supports","the","hypothesis","that","polyether","-","based","SPEs","can","be","used","in","cells","with","4",".","2","V","charge","cut","-","off","voltage","region","with","cathode","\/","SPE","interface","stabilizing","an","electrochemically","stable","catholyte","comprised","by","lithium","bis","(","oxalate",")","borate","(","LiBOB",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":212,"tokens":["Fig",".","5c","compares","the","cycling","performance","of","pristine","LiCoO2",",","ZrO2","coated","LiCoO2","powder","and","ZrO2","coated","LiCoO2","electrode",".","Different","irreversible","capacity","can","be","observed","in","the","inset","of","Fig",".","5c",",","where","ZrO2","coated","LiCoO2","powder","shows","higher","irreversible","capacity","than","the","other","two","cathodes","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O"]}
{"id":213,"tokens":["Al2O3",",","and","ZnO",",","etc",".",",","are","the","insulators","for","lithium","ions",",","the","coating","materials","may","work","as","obstacles","for","ionic","conduction",",","which","is","one","of","the","main","reasons","for","high","resistivity","at","the","interface","between","electrode","and","electrolytes","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":214,"tokens":["Among","three","ALD","films",",","LiF","thin","film","prepared","by","ALD","is","crystalline",",","while","AlF3","and","LiAlF4","thin","films","prepared","by","ALD","are","amorphous","(","see","Supporting","Information","for","grazing","incidence","X","-","ray","diffraction","(","GIXRD",")","characterization",")","."],"ner_tags":["O","O","B-COATING_METHOD","O","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_METHOD","O","O","O","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":215,"tokens":["Therefore",",","the","ultrathin","ALD","film","doesn","'","t","disrupt","the","original","electrical","pathways","constructed","between","the","components","in","the","electrode",",","reduce","the","overall","capacity","[","13","]","."],"ner_tags":["O","O","O","O","B-COATING_METHOD","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":216,"tokens":["the","cells","were","first","cycled","at","0",".","1C","between","3",".","0","and","4",".","4","V","versus","Li","\/","Li","+","as","a","formation","step",",","after","which","in","situ","XRD","measurements","were","performed","with","Cu","K","α","radiation","(","Smartlab",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":217,"tokens":["It","was","assembled","in","order",",","taken","out","in","the","glove","box","overnight",",","and","then","placed","in","a","drying","oven","at","60","°","C","for","12","h",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":218,"tokens":["This","change","is","due","to","the","specific","interaction","between","the","carbonyl","group","of","PMMA","and","the","CH2","group","of","PVDF",".","These","findings","indicate","the","formation","of","a","mixture","between","PMMA","and","PVDF","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":219,"tokens":["Then","citric","acid","was","added","into","the","solution","with","a","molar","ratio","of","Li",":","citric","acid","0","1",":","2",".","The","pH","value","of","the","solution","was","adjusted","to","7","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":220,"tokens":["It","was","continuously","fed","into","a","stirred","tank","reactor","(","capacity","of","4","l",")","with","4",".","0","M","NaOH","and","0",".","4","M","NH4OH","solutions","under","feeding","rates","of","300",",","300","and","40","ml","h","−","1",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":221,"tokens":["25","and","1","nm",",","respectively",".","The","composition","of","the","ZrO2","ALD","coating","was","confirmed","from","the","elemental","mapping","images","of","the","ZrO2","layer","on","Si","wafer","(","Fig",".","2b",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":222,"tokens":["Because","the","layer","-","structured","materials","including","LiCoO2","without","any","modification",",","in","which","transition","metal","ions","are","directly","coordinated","by","oxygen",",","may","suffer","from","easy","structure","collapse","during","cycling",",","particularly",","],"ner_tags":["O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":223,"tokens":["The","capacity","fading","rate","at","0",".","4C","is","only","0",".","08","%","per","cycle",".","The","so","-","called","crystal","habit","-","tuned","material","has","a","large","exposed","(","0","1","0",")","plane","which","ensures","fast","Li","+","intercalation","\/","de","-","intercalation","[","5","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":224,"tokens":["the","bare","NMC","electrode","and","(","d",")","ZrO2","ALD","-","5",".","Table","2",".","Lithium","diffusion","coefficient","(","cm2","s","−","1",")","of","bare","NMC","electrode","and","ZrO2","ALD","-","5","in","the","charge","and","discharge","regions","."],"ner_tags":["O","O","B-CATHODE_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O"]}
{"id":225,"tokens":["The","cells","were","first","charged","and","discharged","at","current","rates","of","0",".","2C",",","0",".","5C",",","1C",",","2C","and","5C","for","every","five","cycles",",","then","discharged","at","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":226,"tokens":["18Co0",".","15Ni0",".","15Mn0",".","52O2",".","Especially",",","the","material","with","1",".","0","wt","%","Li3PO4","shows","the","best","capacity","retention",".","In","comparison",",","the","capacity","fading","rate","for","the","pristine","Li1","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":227,"tokens":["Scanning","Kelvin","probe","microscopy","(","SKPM",")","[","35","]","in","AFM","is","one","of","the","best","measurements","for","assessing","the","interfacial","potential","because","of","its","high","single","electron","sensitivity",",","high","spatial","and","energy","resolution",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":228,"tokens":["LiNi0",".","5Co0",".","2Mn0",".","3O2","is","a","representative","kind","of","the","nickel","-","rich","ternary","materials","[","5","]",",","[","6","]",",","[","7","]","with","a","high","initial","discharge","capacity","approximately","200","mAh","g","−","1","."],"ner_tags":["B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":229,"tokens":["Due","to","this","surface","passivating","feature",",","the","electrochemical","performance","of","0",".","5","wt","%","LATP","modified","LiCoO2","has","also","been","evaluated","in","an","all","solid","lithium","battery","with","poly","(","ethylene","oxide",")","-","based","polymer","electrolyte","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":230,"tokens":["7","mAh","\/","g",")",".","This","is","because","the","electrolyte","would","react","with","the","active","materials","on","the","particles","surface",",","which","would","destroy","the","surface","structure","and","increase","the","charge","transfer","resistance","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":231,"tokens":["Whereas","the","electrodes","with","surface","modification","maintains","good","structural","stability","and","good","capacity","retention",".","Fig",".","4",".","EIS","spectra","of","ALD","Al","2","O","3","-","modified","electrodes","(","a",")","before","(","inset","shows","the","equivalent","circuit",")"],"ner_tags":["O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":232,"tokens":["Graphite","anodes","was","prepared","by","casting","an","NMP","-","based","coating","slurry","containing","92","wt",".","%","graphite","(","natural","graphite",",","15","μ","m",",","MPG",",","Mitsubishi",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":233,"tokens":["Fig",".","1","show","the","working","principle","of","all","solid","-","state","battery",".","The","surface","of","spinel","LNMO","electrode","shows","a","smooth","structure",".","In","the","autoclave",",","under","alkaline","conditions",",","SnO2","particles","grow","in","site","on","the","surface","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":234,"tokens":["As","seen","in","the","image","(","Fig",".","2c",")",",","the","region","indicated","in","a","white","circle","represents","the","cross","-","section","of","the","particle","(","Inside","the","particle",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":235,"tokens":["In","this","study",",","the","charge","cut","-","off","voltage","range","is","3",".","3","–","4",".","5","V",",","the","metal","oxide","coatings","on","the","cathode","electrodes","could","show","the","band","gap","energy","more","than","4",".","5","−","3",".","3","+","2",".","4","0","3","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":236,"tokens":["and","better","thermal","stability","than","the","pristine","material",".","The","improved","electrochemical","properties","can","be","attributed","to","the","multiple","positive","roles","of","Li3PO4","coating",".","First",",","the","Li3PO4","coating","layer","could","facilitate","the","activation","of","Mn4","+","ions","resulting","in","a","large","discharge","capacity","and","high","initial","columbic","efficiency","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":237,"tokens":["and","high","capacity","above","4",".","3","V","[","[","2","]",",","[","3","]",",","[","4","]",",","[","5","]","]",".","In","NMC532",",","this","capacity","fading","is","mainly","attributed","to","the","structural","change","from","layered","to","spinel","during","cycling",",","formation","of","a","thick","solid","-","electrolyte","-","interphase",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":238,"tokens":["Raman","spectra","of","bare","and","ZrO2","-","coated","LiNi0",".","5Co0",".","2Mn0",".","3O2","with","5","ALD","cycles",".","The","raw","line","is","the","best","fit","obtained","by","decomposition","of","three","A1g","and","three","Eg","bands","corresponding","to","the","vibrations","of","the","three","metal","-","ions","with","the","oxygen","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":239,"tokens":["By","precisely","manipulating","the","composition","and","structure",",","the","physical","and","(","electro",")","chemical","properties","of","HSSEs","have","been","notably","improved","compared","with","single","-","component","electrolytes","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":240,"tokens":["To","summarize",",","we","have","demonstrated","a","simple","method","to","construct","a","high","-","quality","CoxB","metallic","glass","infusion","(","beyond","that","of","typical","surface","coating",")","of","NCM","secondary","particles","by","reactive","wetting","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-COATING_METHOD","I-COATING_METHOD","O"]}
{"id":241,"tokens":["Fig",".","1",".","Schematic","of","a","single","ALD","cycle","for","ZrO2","coating",".","2032","type","coin","cells","were","assembled","to","investigate","the","electrochemical","properties","of","the","ZrO2","ALD","coated","NMC532","electrodes","."],"ner_tags":["O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","B-CATHODE_MATERIAL","O","O"]}
{"id":242,"tokens":["On","the","other","hand",",","SnO2","was","inhibited","the","generation","of","the","space","charge","layer","between","the","positive","electrode","and","the","solid","electrolyte","because","of","its","high","ionic","conductivity","[","28","]",",","[","29","]","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":243,"tokens":["After","400","cycles",",","the","ACIE","of","cells","with","uncoated","NCM","-","811","electrode","amounts","to","≈","50","%",",","whereas","the","ACIE","of","the","cells","with","coated","electrodes","only","adds","up","to","≈","37","%","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":244,"tokens":["and","(","g",")","cycling","performance","of","prototype","cell","at","0",".","4","C",".","34","Copyright","2017",",","American","Chemical","Society",".","Understanding","the","ionic","conducting","mechanism","of","polymer","-","inorganic","composites","would","be","critically","important","for","rational","design","of","HSSEs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":245,"tokens":["Then",",","the","resulting","stable","suspension","was","transferred","to","a","teflonlined","autoclave",",","and","hydrothermally","treated","at","180","°","C","for","24","h",".","After","that",",","LNMO","@","SnO2","materials","were","finally","collected","after","filtering",",","washing",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":246,"tokens":["the","non","-","uniformity","is","inherent","upon","postgrowth","annealing",",","and","film","cracking","may","take","place","during","slurry","making","and","\/","or","calendaring","processes",".","Due","to","the","complexity","and","compatibility","of","synthesis",",","there","is","no","report","of","LiAlF4","synthesis","other","than","physical","evaporation",",","to","the","best","of","our","knowledge","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O"]}
{"id":247,"tokens":["which","was","due","to","the","reaction","between","(","NH4",")","2HPO4","and","lithium","residuals","on","the","particles","surface","to","generate","Li3PO4",".","The","pH","value","decreased","a","little","to","11","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O"]}
{"id":248,"tokens":["To","increase","purging","time","to","10","s",",","the","amount","of","small","particles","decreased",",","which","indicates","that","the","prolonged","purging","time","could","help","decrease","the","precursor","condensed","on","the","LiCoO2","cathode","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":249,"tokens":["The","corresponding","LiCoO2","\/","GPE","\/","Li","cell","provided","slow","capacity","fading",",","with","only","10","%","of","capacity","loss","after","100","cycles",".","More","recently",",","Lombardo","et","al",".","[","35","]","published","results","about","a","high","voltage","cell","made","by","in","-","situ","polymerization","of","a","PVdF","\/","EC",":","dimethyl","carbonate","(","DMC",")","(","1",":","1","vol",".","%",")","precursor","."],"ner_tags":["O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":250,"tokens":["For","this","reason",",","along","with","the","development","of","thermally","and","electrochemically","stable","electrolytes",",","it","is","important","to","develop","separators","that","fit","to","operate","in","a","wide","temperature","range","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":251,"tokens":["Atomic","layer","deposition","(","ALD",")","is","an","advanced","vapor","deposition","technique","for","fabricating","ultrathin","layers",",","involving","layer","-","by","-","layer","process","based","on","self","-","terminating","surface","reactions","[","16",",","[","21","]",",","[","22","]",",","[","23","]","]","."],"ner_tags":["B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","B-COATING_METHOD","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":252,"tokens":["7C","discharge","cycling","tests","in","the","range","of","3",".","0","−","4",".","4","V","versus","Li","\/","Li","+","at","45","°","C",",","with","6","intermittent","cycles","with","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":253,"tokens":["That","is","to","say",",","V2O5","coating","layer","also","works","as","an","HF","inhibitor","to","enhance","battery","performance",",","which","is","not","exist","for","other","metal","oxide","coating","(","Al2O3",",","ZnO",",","ZrO2",")",",","metal","phosphate","(","AlPO4",","],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_MATERIAL","O"]}
{"id":254,"tokens":["Mahwah",",","NJ",",","USA",")","equipped","in","the","SEM","or","TEM",".","The","EELS","spectrum","was","obtained","in","the","STEM","mode","with","a","total","beam","current","of","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":255,"tokens":["Galvanostatic","charge","-","discharge","data","of","the","pristine","and","Li3PO4","coated","Li1",".","18Co0",".","15Ni0",".","15Mn0",".","52O2","materials","at","the","current","density","of","40","mA","g","−","1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":256,"tokens":["Beyond","PEO","based","polymers",",","several","such","alternative","polymer","hosts","(","polycarbonates",",","polysiloxanes",",","polyesters",",","PVdF",",","etc",".",")","suitable","for","using","in","solid","polymer","electrolytes","compatible","with","high","voltage","cathodes","have","been","already","discovered","[","74",",","101","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":257,"tokens":["Compared","to","NCM",",","both","the","coated","NCM","samples","exhibit","a","smaller","difference","in","oxidation","peaks","for","the","peak","positions","in","the","first","two","cycles",",","indicating","that","Al","-","O","-","2","and","Li","-","Al","-","O","-","2","exhibit","less","irreversible","capacity","."],"ner_tags":["O","O","B-CATHODE_MATERIAL","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":258,"tokens":["It","seems","that","for","a","certain","voltage","range",",","intensive","generation","of","H2","occurs","only","once","during","the","cycling",".","This","might","be","explained","as","follows",".","The","relatively","stable","interface","layer","is","formed","during","decomposition",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":259,"tokens":["and","50","cycles",")",":","(","a",")","TiO2",",","(","b",")","ZrO2",",","and","(","c",")","Al2O3",";","(","d",")","the","comparison","of","cycling","performance","of","LiCoO2","electrodes","coated","by","different","metal","oxides","with","2","ALD","cycles","."],"ner_tags":["O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-COATING_METHOD","O","O"]}
{"id":260,"tokens":["This","can","be","explained","by","the","reaction","of","(","NH4",")","2HPO4","and","lithium","residuals","to","generate","Li3PO4","at","high","temperature",".","During","the","reaction",",","(","NH4",")","2HPO4","induced","partial","chemical","leaching","of","Li","from","the","LiNi0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":261,"tokens":["Ethylene","carbonate","(","EC",")","is","the","most","suitable","solvent","for","SEI","formation","but","because","at","room","temperature","it","is","a","solid",",","it","must","be","used","together","with","acyclic","carbonates","(","DMC",",","DEC",",","EMC",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":262,"tokens":["3","V","using","a","measurement","system","(","LAND","CT2001A",")",".","AC","impedance","was","measured","over","a","frequency","range","of","0",".","01","Hz","to","105","Hz","on","a","CHI6081D","electrochemical","system","(","Chen","Hua",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":263,"tokens":["Zhang","et","al",".","[","122","]","proposed","the","addition","of","5","to","20","wt",".","%","poly","(","ethylene","oxide",")","to","argyrodite","Li6PS5Cl","to","enhanced","mechanical","properties","and","form","a","stable","lithium","\/","electrolyte","interface","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":264,"tokens":["Discharge","curves","of","the","GITT","measurements","conducted","after","the","140th","cycle","in","a",".","Inset",":","average","voltage","loss","and","its","standard","deviation","(","raw","data","available","in","Supplementary","Fig",".","11",")","over","different","GITT","steps",".","d",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":265,"tokens":["For","the","elemental","and","spectrum","analysis",",","EELS","and","EDS","were","conducted","by","HR","-","TEM","(","Aztec",",","Oxford","Instruments",")",".","The","slurry","obtained","was","coated","onto","aluminium","foil","and","dried","at","120","°","C","for","2","h","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":266,"tokens":["the","well","-","defined","XRD","peaks","represent","the","hexagonal","α","-","NaFeO","2","structure","with","the","R","-","3m","space","group","[","33","]",".","The","peaks","are","further","indexed","using","the","hexagonal","α","-","NaFeO","2","structure","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":267,"tokens":["18Co0",".","15Ni0",".","15Mn0",".","52O2","particles","after","Li3PO4","coating",".","This","indicates","that","more","Mn4","+","ions","can","be","activated","by","Li3PO4","coating",".","The","specific","capacities","of","the","plateau","region","for","the","Li3PO4","coated","samples","are","142","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O"]}
{"id":268,"tokens":["5Co0",".","2Mn0",".","3O2","powders",".","Depositions","of","ZrO2","coatings","on","the","particles","were","carried","out","in","an","atomic","layer","deposition","system","(","Picosun","SUNALE","TM","R","-","150B",")","using","tetrakis","(","dimethylamido",")","zirconium","(","Zr","(","NMe2",")","4",")"],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":269,"tokens":["3","mS","\/","cm",")",".","Moreover",",","the","performance","of","this","material","in","lithium","metal","batteries","was","studied","in","terms","of","discharge","capacity",",","coulombic","efficiency",",","rate","capability",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":270,"tokens":["Co",",","Mn",",","and","Al","found","in","Al","-","O","-","4","and","Li","-","Al","-","O","-","4","(","Fig",".","2",")","were","elucidated","by","XPS","analysis","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":271,"tokens":["11","shows","the","schematic","view","of","the","innovative","process","for","preparing","all","-","solid","-","state","lithium","-","ion","batteries","with","conventional","electrodes",".","To","investigate","its","electrochemical","stability","window",",","first","principle","calculation","has","been","carried","out","to","found","that","Li10GeP2S12","has","a","narrow","electrochemical","window","against","Li","metal","for","application","in","all","-","solid","-","state","Lithium","-","ion","batteries","and","that","a","desired","SEI","phase","formed","spontaneously","or","artificially","intended","is","crucial","for","its","application","in","all","-","solid","-","state","lithium","-","ion","batteries","[","83","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":272,"tokens":["The","decrease","of","CE","suggests","the","magnitude","of","parasitic","reactions","increased","at","elevated","temperature",".","With","a","stable","and","uniform","ALD","LiAlF4","coating",",","the","average","CE","improved","significantly","from","97",".","4","%","to","99",".","7","%","at","elevated","temperature","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":273,"tokens":["and","X","-","ray","photoelectron","spectroscopy","(","XPS",")",".","The","cycling","performances","of","the","LATP","modified","LiCoO2","were","evaluated","in","half","-","cell","with","liquid","electrolyte","and","lithium","battery","with","PEO","based","polymer","electrolyte","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":274,"tokens":["8","mAh","g","−","1",")",".","For","the","1st","cycle",",","both","cathodes","exhibit","notable","voltage","plateaus","at","≈","3",".","82",",","≈","4",".","2","and","≈","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":275,"tokens":["the","cells","from","LATP","-","LCOMg","exhibit","much","better","performances","than","the","ones","from","LATP","-","LCO",".","Experimental","evidence","supporting","this","assertion","will","be","presented","later",".","Sometimes",",","differential","capacity","(","dq","\/","dv",")","vs","cell","voltage","plots","provide","very","useful","information","on","the","phase","transitions","of","electrode","materials","during","lithiation","or","delithiation","."],"ner_tags":["O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":276,"tokens":["In","this","Minireview",",","we","will","summarize","the","recent","progress","of","HSSEs","with","enhanced","ionic","transport",",","(","electro",")","chemical","and","mechanical","properties",".","On","the","basis","of","their","compositions","and","micro","-","\/","nanostructures",",","these","HSSEs","will","be","categorized","into","several","groups",",","including","polymers","and","inorganic","components","integrated","through","different","structures",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":277,"tokens":["After","lift","-","out",",","the","prepared","TEM","samples","were","thinned","to","200","nm","using","a","30","kV","Ga","ion","beam",".","The","thinned","samples","were","next","polished","to","remove","surface","contamination","using","an","Ar","-","ion","milling","system","(","Model","1040","Nanomill",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":278,"tokens":["at","60","°","C","to","form","a","stable","polymer","solution",".","Polyvinylidene","fluoride","(","PVDF",")","powder","was","added","and","stirring","was","continued","for","3","h",".","Then","add","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":279,"tokens":["The","panorama","of","electrolytes","includes","nitriles","as","one","of","the","most","promising","materials","with","ion","conductivities","higher","than","30","mS","at","RT",",","even","if","limited","by","a","narrow","electrochemical","stability","window","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":280,"tokens":["and","wide","electrochemical","stability","window",".","However",",","pure","nitrile","based","electrolytes","cannot","be","used","in","a","self","-","standing","form","and","require","mechanical","reinforcement","[","72","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":281,"tokens":["Coin","cells","were","assembled","in","an","argon","-","filled","glove","box","by","using","lithium","foil","as","the","anode","electrode",",","the","porous","polypropylene","fi","lm","(","Celgard","2500",")","as","the","separator","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":282,"tokens":["Therefore",",","the","LiAlO2","coating","can","better","improve","the","rate","capability","of","the","cathode","materials",".","Fig",".","9",".","CV","curves","of","(","a",")","NCM",",","(","b",")"],"ner_tags":["O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O"]}
{"id":283,"tokens":["After","long","-","term","cycling","at","high","cut","-","off","voltage",",","both","lattice","shrinkage","along","the","a","-","axis","and","expansion","along","the","c","-","axis","occur",",","eventually","reducing","the","unit","cell","volume","[","2",",","46","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":284,"tokens":["and","discharged","in","the","CC","mode","at","C","\/","5","(","0",".","28","mA","cm","−","2",")","for","three","consecutive","cycles",".","After","precycling",",","the","cycle","performance","was","evaluated","at","different","cut","-","off","voltages","of","3",".","0","–","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":285,"tokens":["and","Al2O3",".","Obviously",",","in","all","XRD","patterns",",","the","reflection","peaks","originating","from","LiCoO2","(","003",")",",","(","101",")",",","(","006",")",",","(","012",")",",","(","104",")",",","(","015",")",",","(","009",")",",","(","107",")",",","(","018",")",",","(","110",")",",","(","113",")",","],"ner_tags":["O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":286,"tokens":["67","Li","ions","could","complex","with","the","anionic","boron","centers","and","transport","thorough","the","pore","channel",",","which","exhibits","an","ionic","conductivity","of","3",".","5","×","10","−","5","S","cm","−","1","and","an","average","transference","number","of","≈","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":287,"tokens":["Such","enhanced","electrochemical","performance","of","the","coated","sample","is","ascribed","to","the","high","-","quality","ultrathin","amphoteric","oxide","ZnO","coating","layer",",","which","is","high","conformality","and","homogeneity","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":288,"tokens":["All","these","factors","play","an","important","role","in","the","real","solid","-","state","cell","environment","[","72",",","78",",","[","83","]",",","[","84","]",",","[","85","]",",","[","86","]","]"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":289,"tokens":["The","coating","materials","investigated","to","date","include","carbon",",","27","–","30","metal","oxides",",","31","–","33","metal","carbonates",",","34","metal","aluminates",",","35","metal","phosphates",",","36",",","37","metal","fluorides",",","38",",","39","metal","oxyfluorides",",","40","metal","hydroxides",",","41","and","Li2O","·","2B2O3","glass",",","42",",","43","as","well","as","cathode","materials","with","lower","reactivity","toward","non","-","aqueous","electrolytes",".","2",",","3","Li","and","coworkers","have","reviewed","the","research","literature","on","various","coating","materials","for","different","cathodes",",","as","well","as","methods","to","carry","out","surface","coating","."],"ner_tags":["O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":290,"tokens":["After","simulating","by","the","equivalent","circuit","in","the","inset","of","Fig",".","9a",",","it","was","found","that","Rct","of","LiCoO2","in","the","20th","cycle","is","336","Ω",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":291,"tokens":["As","a","result",",","the","first","Columbic","efficiency","increases","from","75",".","8","%","to","84",".","0","%","and","then","to","87",".","5","%",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":292,"tokens":["Data","generated","and","analysed","in","this","study","are","included","in","the","manuscript","and","its","Supplementary","Information",".","Highlights","•","ALD","derived","metal","oxide","(","TiO2",",","ZrO2",",","Al2O3",")","coatings","were","successfully","performed",".","•","Coatings","could","significantly","increase","battery","performance","of","the","commercial","LiCoO2",".","•","Al2O3","coating","brings","the","best","cycling","stability",".","•","ZrO2","coating","contributes","to","the","best","rate","capability","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O"]}
{"id":293,"tokens":["and","so","on",")",".","-","Multilayered","solid","electrolyte","design","[","173","]",".","-","Surface","protection","of","solid","electrolyte","membranes",".","Partial","or","full","replacement","PEO","and","its","derivatives","by","novel","polymers",",","plastic","crystals",",","ionic","liquids","and","inorganic","materials","(","inert","and","conductive",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":294,"tokens":["First",",","we","compared","the","EIS","of","the","coated","LNMO","liquid","and","solid","-","state","batteries","(","Fig",".","6a",")","to","analyze","the","process","of","charge","transfer","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":295,"tokens":["2","wt","%",",","(","c",")","0",".","5","wt","%",",","(","d",")","1","wt","%","and","(","e",")","1",".","5","wt","%","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":296,"tokens":["7","V","are","shown","in","Fig",".","S5",".","As","opposed","to","the","pristine","morphology","in","Fig",".","2a",",","small","cracks","can","be","observed","on","the","surface","of","the","cycled","NCM","(","Fig",".","S5a",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O"]}
{"id":297,"tokens":["However",",","the","rapid","moisture","uptaking","ability","of","Ni","-","rich","(","x","≥","0",".","8",")","materials","stemmed","from","the","slow","and","spontaneous","reduction","of","Ni3","+","to","Ni2","+","and","physical","\/","chemical","adsorption","of","synthetic","residue","Li2O","\/","LiOH","on","surface","has","been","the","problem","to","overcome","[","8","]",",","[","9","]",",","[","10","]",",","[","11","]","."],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":298,"tokens":["So","far",",","deposition","of","a","Si","thin","film","via","PECVD","[","146","]","and","Ge","by","ALD","technology","[","147","]","and","preparation","of","a","graphite","surface","layer","by","scratch","with","pencil","[","148","]","are","performed","to","reduce","the","interfacial","impedance","between","solid","electrolyte","and","cathode","particles","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":299,"tokens":["0","s","extended","exposure","of","the","first","precursor","to","the","cathode","electrode",";","(","3",")","purging","of","residual","precursor","and","any","byproducts","with","t2","s",";","(","4",")","pulsing","of","the","second","precursor","with","t3","s",";","(","5",")","a","3","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":300,"tokens":["the","observed","morphological","changes","imply","that","chemical","reactions","between","LiCoO2","and","LATP","may","occur","at","the","surface","of","the","LATP","@","LCO","sample",".","Figure","1","Open","in","figure","viewer","PowerPoint","a",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":301,"tokens":["To","confirm","it",",","during","the","electrode","storage","at","60","°","C",",","the","amount","of","Co","dissolution","into","the","electrolyte","was","tested","by","ICP","-","AAS",".","Increasing","the","cutoff","voltage","up","to","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":302,"tokens":["Therefore",",","we","can","reasonably","expect","that","the","addition","of","HF","scavenger","can","improve","the","capacity","retention","of","lithium","-","ion","cells","for","a","relatively","short","time",",","as","widely","reported","in","the","literature","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":303,"tokens":["In","addition",",","it","is","known","that","Li3PO4","has","appropriate","lithium","ionic","conducting","ability","and","is","chemically","stable","at","high","voltages",",","which","can","promise","a","high","-","voltage","-","stable","interface","with","suitable","lithium","diffusion","kinetics",".","[","13","]"],"ner_tags":["O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":304,"tokens":["and","battery","grade","electrolyte","LP30",",","1M","LiPF6","–","EC",":","DMC","(","1",":","1","w","\/","w",")",",","was","reported","by","Croce","et","al",".","[","41","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":305,"tokens":["Of","late",",","ALD","has","emerged","as","an","ideal","coating","method","with","excellent","uniformity","and","conformity",",","which","helps","overcome","the","interfacial","issues","in","LIBs","[","[","24","]",",","[","25","]",",","[","26","]",",","[","27","]","]","."],"ner_tags":["O","O","O","B-COATING_METHOD","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":306,"tokens":["1","C","and","could","light","a","LED","lamp","in","a","normal","state",",","in","a","bended","state","and","even","after","being","cut","a","half","away",".","Continuing","the","research","on","in","-","situ","polymerized","GPEs",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":307,"tokens":["Among","the","most","investigated","polymer","matrices",",","poly","(","propylene","carbonate",")","(","PPC",")","has","attracted","increasing","attention","as","a","promising","polymer","matrix","for","LIBs","owing","to","its","low","cost","and","biodegradability","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":308,"tokens":["and","687",".","0","eV","(","corresponding","to","LiPF6","and","LixPOyFz",",","respectively",")","in","the","F","1s","spectra","[","27","]",",","[","42","]",".","Considering","the","morphological","changes","and","XPS","results",",","we","inferred","that","the","surface","of","NCM","\/","Al2O3","was","covered","and","protected","by","dense","and","stable","inorganic","compounds",",","resulting","in","improved","oxidation","stability","under","high","-","voltage","operating","conditions","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":309,"tokens":["The","cells","were","cycled","between","3",".","0","and","4",".","4","V","with","the","rate","of","1","C",".","The","morphologies","and","internal","structures","of","uncoated","-","LCOMg","and","LATP","-","LCOMg","were","characterized","by","SEM","and","TEM","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":310,"tokens":["During","the","deposition",",","the","zirconium","precursor","was","heated","at","75","°","C","for","source","evaporation",",","while","water","was","kept","at","room","temperature",".","The","charge","–","discharge","tests","were","galvanostatically","performed","at","various","C","-","rates","(","1C","0","200","mA","g","−","1",")","in","the","potential","range","between","2","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":311,"tokens":["F","1s","(","contributed","by","CEI","components","of","metal","fluorides",",","such","as","NiF2","and","LiF",")","and","Ni","2p","signals","(","contributed","by","Ni","-","containing","CEI","components",",","such","as","NiF2",")","(","ref",".","45",")","were","observed","in","cycled","pristine","NCM","were","stronger","than","those","in","cycled","CoxB","–","NCM","(","Fig",".","4g","–","i",";","see","detailed","discussions","in","Supplementary","Table","5",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":312,"tokens":["In","contrast",",","it","is","revealed","that","a","direct","coating","on","prefabricated","LiCoO2","electrodes","performs","much","better","than","a","coating","on","LiCoO2","powders",".","It","is","further","disclosed","that","the","improved","electrochemical","performance","of","coated","LiCoO2","electrode","is","highly","dependent","on","the","coating","materials","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":313,"tokens":["After","500","cycles",",","the","specific","discharge","capacity","of","the","LNMO","@","SnO2","electrode","is","97","mAh","g","−","1",",","and","the","capacity","decay","rate","per","cycle","is","0",".","016","%","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":314,"tokens":["The","increase","of","Li","+","diffusion","coefficient","can","be","ascribed","to","the","modification","of","the","ultrathin","amorphous","ZnO","coating","layer",".","Fig",".","10",".","Relationships","between","Zimg","and","ω","−","1","\/","2","for","the","bare","NCM","-","523","and","ZnO","-","coated","NCM","-","523","electrodes",".","ALD","technology","has","facilely","used","to","deposit","the","ultrathin","amorphous","ZnO","coating","layer","onto","bare","NCM","-","523","to","enhance","the","electrochemical","performance","of","electrode","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":315,"tokens":["4","eV","with","a","satellite","peak","at","816",".","0","eV","were","assigned","to","Ni2","+","and","Ni3","+",",","respectively",".","Ni","was","a","mixture","of","+","2","and","+","3","valence","states",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":316,"tokens":["It","should","be","noted","that","due","to","some","overlap","of","diffraction","peaks","(","see","Fig",".","S3",")","of","the","Al","current","collector","with","those","of","the","LiCoO2","cathode",",","some","planes","("],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O"]}
{"id":317,"tokens":["Phase","constitutions","of","reaction","products","of","LiCoO2","and","LATP","heat","-","treated","at","different","temperatures",".","j",")","Schematic","illustration","of","the","surface","layer","growth","mechanism",".","The","spinel","phase","is","structurally","more","stable","than","the","layered","phase","with","weaker","oxygen","-","anion","oxidizing","ability","at","high","voltages","."],"ner_tags":["O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":318,"tokens":["Fig",".","9","shows","the","comparison","of","Li","ionic","conductivity","of","different","solid","electrolytes",".","Their","further","researches","on","this","LISICON","structured","sulfide","solid","electrolyte","have","resulted","double","the","highest","Li","ionic","conductivity","of","LISICON","structured","electrolyte","to","25","mS","\/","cm","at","room","temperature","through","partial","replacement","of","sulfur","with","some","chlorine","[","159","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":319,"tokens":["The","use","of","NCM622","\/","NCM333","cathodes","and","LLZO","\/","LLZTO","were","reported","in","polymer","-","type","SSBs","[","33","]",".","However",",","it","is","more","difficult","to","attain","fine","nickel","-","rich","NCM","\/","garnet","-","type","SSBs","due","to","some","tough","problems",",","one","of","them","is","the","interface","issue","."],"ner_tags":["O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":320,"tokens":["which","can","facilitate","Li","+","diffusion","at","the","electrode","\/","electrolyte","interface",".","(","22",")","In","addition",",","the","PO43","–","polyanions","can","react","with","Li2O","\/","LiOH","residues","on","the","cathode","surface",",","thus","reducing","the","pH","value","of","the","cathode","materials","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":321,"tokens":["Al2O3","might","have","been","pulverized","into","small","-","sized","particles","during","the","cathode","preparation","process",",","which","included","stirring",",","vortexing",",","and","slurry","mixing","processes",".","We","expect","that","the","scattered","small","-","sized","Al2O3","particles","were","advantageous","to","the","original","-","sized","Al2O3","particles","in","that","the","former","efficiently","enlarged","the","surface","area","and","contact","area","between","the","NCM","active","materials","compared","to","the","latter","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O"]}
{"id":322,"tokens":["This","exceptional","battery","performance","was","attributed","to","a","favorable","protection","film","on","the","LiCoO2","cathode","and","a","stable","SEI","film","on","the","Li","anode",".","More","recently",",","Ye","and","co","-","authors","[","47","]","developed","polymer","-","filler","-","reinforced","membranes","composed","of","lithiophilic","polyacenequinone","(","PQ",")","as","filler","and","thermoplastic","polyurethane","(","TPU",")","as","polymer","electrolyte","matrix","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":323,"tokens":["5","V","and","current","density","of","0",".","2C","rate",".","(","b",")","Charge","and","discharge","curves","at","1st",",","2nd",",","10th",",","30th",",","50th","cycle","of","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":324,"tokens":["Fig",".","5","illustrates","that","dramatic","improvement","on","the","electrochemical","performance","of","cathode","material","can","be","achieved","by","using","the","concentration","gradient","strategy",".","The","core","-","shell","structured","materials","have","a","thick","coating","shell",",","up","to","1","μ","m",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":325,"tokens":["0","wt","%","Li3PO4",".","However",",","too","much","of","Li3PO4","would","block","the","electrons","transport","which","hinder","the","electrochemical","properties","of","the","material",".","This","work","shows","that","1","."],"ner_tags":["O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":326,"tokens":["1","C","rate",")","between","2",".","8","and","4",".","3","V",".","Clearly",",","V2O5","-","coated","LiNi0",".","8Co0",".","1Mn0",".","1O2","delivers","a","similar","discharge","capacity","with","pristine","sample","at","201","mAh","g","−","1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":327,"tokens":["The","in","-","situ","polymerized","LiNi0",".","5Mn1",".","5O4","\/","GPE","\/","Li","cell","was","tested","a","C","\/","5","rate","within","the","voltage","range","3",".","5","–","5","."],"ner_tags":["O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":328,"tokens":["In","this","context",",","Amine","and","co","-","authors","[","48","]","reported","the","preparation","of","a","poly","(","methyl","methacrylate",")","(","PMMA",")","a","liquid","precursor","and","the","batteries","were","assembled","by","the","relatively","simple","technology","used","for","conventional","liquid","electrolyte","lithium","ion","batteries",",","followed","by","γ","-","ray","irradiation","of","the","assembled","cells","to","obtain","gel","polymer","type","cells","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":329,"tokens":["As","shown","in","Fig",".","4",",","the","binding","energies","of","Zn","2p3","\/","2","of","1021",".","5","eV","and","2p1","\/","2","of","1044",".","3","eV","are","observed",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":330,"tokens":["Moreover",",","the","charge","-","transfer","resistance","of","NCM811","-","LP","-","LLZTO","barely","increases","during","charge","\/","discharge","cycles","(","Fig",".","6d",")",".","The","Rct","values","of","AC","impedance","for","NCM811","-","LP","-","LLZTO","sample","is","only","218","."],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":331,"tokens":["All","cells","were","cycled","using","a","constant","current","charge","and","discharge","step",".","Using","these","same","methods",",","we","find","that","the","stability","window","of","the","fluorides","remains","wide","even","with","the","addition","of","second","metal","ions","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":332,"tokens":["and","cycling","stability","(","shown","by","the","1C","cycling","data","performed","after","the","rate","tests","in","Fig",".","3a","and","the","0",".","5","C","cycling","data","in","Supplementary","Fig",".","10",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":333,"tokens":["which","can","hardly","be","removed","by","cathode","coating",".","Indeed",",","as","shown","by","in","situ","XRD","during","electrochemical","cycling","(","Supplementary","Figs",".","20","and","21",")",",","pristine","NCM","and","CoxB","–","NCM","undergo","the","same","bulk","phase","transformation","and","lattice","expansion","and","\/","or","shrinkage","(","Supplementary","Fig",".","22",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":334,"tokens":["During","the","calculation","process","of","surface","energy",",","the","LiNi0",".","8Co0",".","1Mn0",".","1O2","and","Li6",".","4La3Zr1",".","4Ta0",".","6O12","are","simplified","to","LiNiO2","and","Li7La3Zr2O12",","],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":335,"tokens":["Compared","with","the","mechanically","induced","deformation","of","the","secondary","particle",",","particle","cracking",",","which","is","induced","by","electrochemical","stress","(","volume","change","during","the","delithiation","\/","lithiation",",","formation","of","new","phases","with","larger","lattice","parameters",")",",","takes","place","inside","the","particles","(","Figure","8e",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":336,"tokens":["and","(","iii",")","electrolyte","decomposition","at","the","cathode","and","subsequent","formation","of","a","solid","electrolyte","interphase","(","SEI",")","layer",",","resulting","in","increased","surface","impedance","[","18","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":337,"tokens":["which","again","demonstrates","the","superior","performance","of","CoxB","–","NCM",".","Lastly",",","we","tested","pristine","NCM","and","CoxB","–","NCM","in","400","mAh","-","pouch","-","type","full","-","cells","using","a","spherical","graphite","(","Gr",")","anode","and","conducted","long","-","term","cycling","in","the","range","of","2",".","8","−","4","."],"ner_tags":["O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":338,"tokens":["the","Rs","values","for","NCM",",","Al","-","O","-","2","and","Li","-","Al","-","O","-","2","are","similar",",","suggesting","that","neither","coating","dissolves","in","the","electrolyte","to","affect","the","solution","composition","and","conductivity","."],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":339,"tokens":["Fig",".","10",".","Nyquist","plots","and","fitting","data","of","NCM",",","Al","-","O","-","2",",","and","Li","-","Al","-","O","-","2","electrodes","with","an","amplitude","of","5","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":340,"tokens":["The","ZrO2","coating","layers","exhibit","a","bit","difference","with","respect","to","the","TiO2","ones",":","2","and","5","ALD","cycle","coatings","produced","positive","effect",",","but","negative","effect","from","10","to","50","ALD","cycles",";","(","3",")"],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O"]}
{"id":341,"tokens":["The","Al","2p3","\/","2","spectrum","demonstrates","a","binding","energy","at","~","73","eV","with","trivalent","Al","(","Fig",".","2f",")",".","Fig",".","2",".","XPS","spectra","and","fitting","results","of","Al","-","O","-","4","and","Li","-","Al","-","O","-","4",":","(","a",")","original","XPS","survey","spectra",",","(","b",")","nickel","spectra",",","(","c",")","cobalt","spectra",",","(","d",")","manganese","spectra",",","(","e",")","lithium","spectra",",","(","f",")","aluminum","spectra","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":342,"tokens":["Fig",".","9",".","Charge","-","discharge","profiles","of","the","(","a",")","pristine",",","and","(","b",")","1",".","0","wt","%",",","(","c",")","3","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":343,"tokens":["Particularly",",","LiNi0",".","5Mn0",".","3Co0",".","2O2","(","NMC532",")","is","one","of","the","most","promising","cathode","materials","for","practical","application","because","of","its","good","electrochemical","stability",",","comparatively","low","cost",",","low","toxicity",","],"ner_tags":["O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":344,"tokens":["In","our","research",",","we","synthesized","layered","LiNi0",".","8Co0",".","1Mn0",".","1O2","cathode","materials","and","then","surface","-","modified","these","materials","with","ionic","conductive","Li3PO4","and","electronic","conductive","PPy","polymer","."],"ner_tags":["O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":345,"tokens":["and","Li","-","Al","-","O","-","6",",","respectively",".","The","phase","of","each","sample","was","identified","by","X","-","ray","diffraction","(","XRD",",","Bruker","AXS","D8Advance",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":346,"tokens":["This","justifies","the","improved","electro","-","chemical","performance","of","2","cycle","ALD","modified","NCM811","electrode","at","room","temperature","and","elevated","temperature",".","Three","pairs","of","redox","peaks","are","present","in","the","voltage","window","of","2",".","8","-","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":347,"tokens":["For","these","reasons","the","present","review","summarizes","the","most","recent","research","efforts","in","the","field","of","high","voltage","solid","-","state","electrolytes","for","high","energy","density","Li","-","ion","cells","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":348,"tokens":["the","surface","chemistry","of","cathode","materials","and","the","correlation","between","the","surface","chemistry","and","the","material","performance","have","not","been","systematically","investigated",".","Most","reported","work","has","been","based","on","accelerated","experiments","in","which","the","materials","were","tested","shortly","after","they","were","synthesized",",","when","their","surface","was","“","clean",".","”","In","such","accelerated","experiments",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":349,"tokens":["and","high","-","temperature","(","45","°","C",")","conditions",",","as","it","greatly","suppressed","intergranular","cracking",",","side","reactions","and","impedance","growth",".","Schematic","coating","-","plus","-","infusion","microstructure","in","which","CoxB","uniformly","coats","the","surface","of","NCM","secondary","particle","and","infuses","into","GBs","between","the","NCM","primary","particles","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":350,"tokens":["Schematic","illustration","for","ALD","-","ZnO","growth","on","the","surface","of","NCM","-","523","powder",".","XRD","patterns","of","the","bare","NCM","-","523","powders","and","NCM","-","523","particles","coated","with","8","ALD","-","ZnO","layers","are","shown","in","Fig",".","2","."],"ner_tags":["O","O","O","B-COATING_METHOD","O","B-COATING_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","B-COATING_METHOD","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O"]}
{"id":351,"tokens":["which","would","reduce","the","dissolution","of","transition","metal","ions","and","formation","of","the","cracks","in","the","cycled","electrode",".","In","addition",",","the","ionic","conductive","Li3PO4","coating","layer","could","reduce","the","charge","transfer","resistance","during","cycling","and","increase","the","Li","+","diffusion","efficiency","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":352,"tokens":["Side","reactions","between","electrode",",","in","particular","high","oxidation","state","Ni4","+",",","and","organic","electrolyte","have","been","reported","to","be","one","of","the","key","failure","mechanisms","for","high","Ni","content","layered","metal","oxide","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":353,"tokens":["In","this","context",",","hybrid","polymer","\/","inorganic","electrolytes","can","be","considered","as","an","ultimate","solution","to","benefit","of","the","advantages","of","each","component",":","the","processability",",","flexibility",",","wettability","of","polymers","and","chemical",",","thermal","and","electrochemical","stability",",","ionic","conductivity","and","mechanical","properties","of","inorganic","materials","[","69",",","113","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":354,"tokens":["Wang","et","al","have","proposed","to","prepare","a","composite","electrolyte","by","casting","the","SPE","solution","(","polymer","\/","THF","\/","LiTFSI",")","onto","free","-","standing","aluminum","oxide","electrostatic","spinning","film","containing","ceramic","nanowires","[","116","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":355,"tokens":["which","were","much","higher","than","that","of","the","bare","LiNi0",".","8Co0",".","1Mn0",".","1O2","(","1",".","39","×","10","–","5","S","cm","–","1",")",",","because","of","the","presence","of","conductive","polymer","in","the","coating","layer","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":356,"tokens":["6","mS","\/","cm",",","which","corresponds","to","a","tLi","+","0","0",".","43",",","and","wide","electrochemical","stability","window","(","∼","4",".","30","V","vs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":357,"tokens":["the","most","promising","battery","is","composed","of","NCA","\/","PETEA","-","based","GPE","\/","(","graphite","–","Si","\/","C",")",".","After","nail","penetration","test","of","a","fully","charged","battery",",","it","exhibited","no","obvious","change","in","contrast","with","NCA","\/","LE","\/","(","graphite","–","Si","\/","C",")",","],"ner_tags":["O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":358,"tokens":["Electrochemical","impedance","spectroscopy","(","EIS",")","was","also","performed","on","the","VSP","instrument","by","applying","an","ac","potential","of","5","mV",".","The","enlarged","backgrounds","displayed","in","Fig","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":359,"tokens":["and","conductivity",".","39","Reproduced","with","permission",".","Copyright","2018",",","Wiley","-","VCH",".","(","h",")","Schematic","and","SEM","image","of","LAGP","-","epoxy","HSSE","with","cube","microarchitecture",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":360,"tokens":["Prior","to","the","analysis","in","the","FIB","workstation",",","epoxy","soaking","and","carbon","deposition","were","conducted","to","avoid","damage","to","the","Ga","ion","beam","and","preserve","the","sample","morphology","in","subsequent","lift","-","out","and","thinning","processes","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":361,"tokens":["The","polar","paste","is","composed","of","active","material",",","conductive","carbon",",","PVDF",",","and","LATP",",","whose","weight","ratio","is","7",":","1",":","1",":","1",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":362,"tokens":["the","Li","anode","used","in","this","work","is","made","of","excess","lithium","(","D","0","10","mm",",","H","0","0",".","6","mm",")",",","and","the","all","half","cells","are","assembled","using","the","same","process","and","Li","anode","materials",".","~","5","μ","L","liquid","electrolyte","was","used","to","wet","the","positive","and","negative","interface","in","the","work",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":363,"tokens":["Li","+","\/","Li",")","at","25","°","C",".","All","of","the","experimental","impedance","spectra","were","fitted","with","the","equivalent","circuit","model","(","Fig",".","10b",")","to","further","calculate","the","values","of","solution","resistance","(","Rs",")",",","surface","resistance","(","Rf",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":364,"tokens":["During","the","following","cycles","the","stabilization","of","the","SEI","layer","prevents","further","electrolyte","decomposition","and","the","cell","efficiency","values","increased",",","with","remarkable","reversibility","and","high","-","capacity","retention","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":365,"tokens":["Thus",",","although","the","reactive","wetting","ensures","a","complete","coverage","and","tight","adhesion","between","the","CoxB","and","NCM",",","it","does","not","consume","much","oxygen","from","the","NCM","lattice","and","will","probably","maintain","a","metallic","glass","nature29",",","30","."],"ner_tags":["O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":366,"tokens":["Schematic","illustrations","of","the","surface","engineering","of","LCO",".","SEM","images","of","b",")","bare","-","LCO","and","c",")","LATP","@","LCO","without","heat","treatment",".","The","LATP","@","LCO","sample","annealed","at","various","temperatures",":","d",")","400","°","C",",","e",")","550","°","C",",","f",")","700","°","C",","],"ner_tags":["O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":367,"tokens":["Mulit","-","doping","effect","of","on","the","Li","ion","diffusion","in","LLZO","lattice","(","a",")","3D","image","of","the","undoped","cubic","LLZO","structure","with","two","important","sites","of","24d","and","96","h","on","the","diffusion","way","of","Li","ion",";","(","b",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":368,"tokens":["N","is","the","number","of","unit","cell",",","and","A","is","the","surface","area","in","the","super","cell",".","The","factor","of","2","in","the","denominator","takes","account","of","the","fact","that","in","the","slab",",","we","have","two","surfaces",",","one","at","the","bottom","and","one","at","the","top","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":369,"tokens":["As","a","result",",","a","thicker","coating","has","led","to","higher","overpotential","and","reduced","capacity","in","the","past",".","(","24",")","This","phenomenon","becomes","more","substantial","when","metal","fluoride","is","applied","using","ALD",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","B-COATING_METHOD","O"]}
{"id":370,"tokens":["It","is","obvious","that","during","lithium","insertion","\/","extraction","processes",",","Rct","of","the","pristine","LiCoO2","continually","increases",".","In","the","comparison","to","that","of","the","pristine","LiCoO2",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O"]}
{"id":371,"tokens":["This","result","can","be","associated","with","the","deconstruction","of","LiCoO2","structure","and","polarization","enhancement","at","high","cut","-","off","voltage","upon","cycling",",","which","hinders","the","lithium","reinsertion","during","the","discharge","process","and","thus","lead","to","the","existence","of","Co4","+","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":372,"tokens":["Herein",",","we","successfully","fabricated","an","ultrathin","ZrO2","coating","on","the","surface","of","an","as","-","fabricated","electrode","based","on","NMC532","active","material","via","ALD",".","The","electrochemical","and","structural","properties","of","the","bare","and","ZrO2","ALD","-","coated","NMC532","electrodes","at","high","-","voltage","operation","(","4","."],"ner_tags":["O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":373,"tokens":["and","the","development","of","the","all","-","solid","-","state","battery","is","promoted",".","The","solid","-","state","lithium","metal","batteries","are","one","of","the","most","promising","next","-","generation","energy","storage","devices","owing","to","its","high","energy","density","and","safety","[","1","]",",","[","2","]",",","[","3","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":374,"tokens":["which","significantly","affects","of","the","charge","transfer","resistance","of","the","cathode",".","As","a","result",",","TiO2","coated","LiCoO2","shows","different","Rct","in","the","20th","and","the","50th","cycle",",","that","is",",","81","Ω","and","132","Ω",",","respectively",",","while","97","Ω","and","103","Ω","for","ZrO2","coating",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O"]}
{"id":375,"tokens":["SEM",",","XPS",",","and","XRD","Characterization","Morphological","investigation","and","EDS","mapping","analysis","of","the","samples","were","conducted","using","a","field","emission","scanning","electron","microscope","with","an","energy","dispersive","X","-","ray","detector","(","SEM",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":376,"tokens":["(","63",",","64",")","The","main","thermal","decomposition","of","layered","transition","metal","oxide","materials","typically","starts","in","a","temperature","range","of","150","–","250","°","C","and","is","caused","by","structural","degradation","and","oxygen","release","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":377,"tokens":["The","calculation","of","the","SOH","of","80","%","is","based","on","the","capacity","of","the","fifth","cycle","after","formation",".","The","initial","Ceff","of","≈","86",".","2","%","is","very","similar","for","both","samples","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":378,"tokens":["The","electrolyte","was","1","M","LiPF6","dissolved","in","EC","+","DMC","(","1",":","1","in","volume",")","solution",".","The","CR2025","coin","type","cells","were","assembled","in","an","argon","-","filled","glovebox",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":379,"tokens":["Rate","capabilities","of","the","unit","cells","based","on","NCM","and","NCM","\/","Al2O3","at","(","a",")","a","cutoff","condition","of","4",".","3","V","vs",".","Li","\/","Li","+","(","25","°","C",")"],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":380,"tokens":["Consequently",",","Li","impurities","at","the","surface","of","the","active","material","are","removed",",","leading","to","improved","rate","capability",",","improved","thermal","stability",",","and","reduced","internal","resistance","in","LIB","cells","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":381,"tokens":["Inc",".",")","spectrometer","with","monochromatic","Al","K","α","radiation","(","h","υ","0","1486",".","7","eV",")",".","The","base","pressure","of","the","sample","chamber","was","kept","below","3",".","0","×","10","–","10","mbar","during","XPS","measurements","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":382,"tokens":["Prior","to","coating",",","the","well","-","ordered","layered","structure","can","be","easily","identified","(","Fig",".","4b",")",".","The","surface","of","bare","particle","is","smooth","and","there","is","no","other","impurity","phase","on","the","surface","of","particles","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":383,"tokens":["Depositions","of","ZnO","coatings","on","the","particles","were","carried","out","in","an","atomic","layer","deposition","system","(","Picosun","SUNALE","TM","R","-","150B",")","using","diethyl","zinc","Zn","(","C2H5",")","2","and","ultrapure","grade","H2O","as","precursors","with","exposure","time","of","0","."],"ner_tags":["O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":384,"tokens":["2","wt","%","and","0",".","5","wt","%",",","it","does","not","compromise","the","capacity","compared","to","the","bare","LiCoO2","(","176","mAh","\/","g",")","and","the","initial","discharge","capacity","is","177","and","176","mAh","\/","g",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":385,"tokens":["The","more","uneven","distribution","of","ions","is",",","the","more","great","the","SCL","effect","is",".","Introducing","a","binder","-","like","substance","in","the","compatible","surface","region","is","an","effective","strategy","in","helping","join","the","materials","and","in","addressing","the","absolute","separation","between","NCM811","and","LLZTO","particles","(","Fig",".","1d",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":386,"tokens":["Also",",","this","material","was","tested","in","a","4",".","45","V","LiCoO2","\/","Li","cell",",","obtaining","superior","capacity","retention","(","85","%","after","700","cycles",")","and","excellent","rate","capability","(","15C",")","even","at","60","°","C","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":387,"tokens":["To","overcome","the","technical","drawbacks","of","the","above","approaches",",","we","developed","a","facile","cathode","fabrication","technique","by","introducing","a","well","-","known","alumina","(","Al2O3",")","ceramic","filler","during","the","cathode","electrode","preparation","step","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":388,"tokens":["An","extremely","low","interface","impedance","of","1","Ω","•","cm","[","2","]","has","been","achieved","in","LLZO","materials","via","ALD","deposition","of","Al2O3","from","the","original","1710","Ω","•","cm","[","2",",","149","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":389,"tokens":["and","interface","oxygen","coordinated","by","one","B",",","two","Ni","and","two","Ni","atoms","(","f",")",".","Regarding","the","improved","mechanical","stability",",","although","CoxB","infusion","mitigates","SCC","by","stabilizing","surface","oxygen","and","suppressing","the","side","reactions",",","it","also","benefits","from","a","mechanical","perspective",",","as","less","cracking","was","found","even","at","the","end","of","the","first","charge","(","Supplementary","Fig",".","18",")","when","the","chemical","effect","should","be","less","conspicuous","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":390,"tokens":["Profiles","of","(","c",")","charging","HPPC","and","(","d",")","discharging","HPPC","of","the","unit","cells","based","on","NCM","and","NCM","\/","Al2O3","at","25","°","C","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":391,"tokens":["Li7La3Zr2O12","(","6","1","1",")","crystal","face","are","0",".","89",",","1",".","76","and","2",".","74","J","\/","m2",",","correspondingly",".","These","data","were","used","to","represent","NCM811","(","using","LiNiO2",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O"]}
{"id":392,"tokens":["Work","on","Si",",","(","52",",","53",")","Ge",",","(","54",")","and","SiO2","(","55",")","has","been","reported","to","indicate","small","and","consistent","energy","differences","between","the","crystalline","and","amorphous","phases","(","∼","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":393,"tokens":["(","30",")","They","showed","that","this","material","exhibited","much","better","electrochemical","performances","than","the","LiCoO2","cathode","without","LATP",".","In","this","study",",","we","use","LATP","(","x","0","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O"]}
{"id":394,"tokens":["At","the","primary","particle","surface",",","under","HF","acid","etching","during","phase","transformation",",","the","structural","degradation","of","the","NCM","cathode","is","triggered","by","evolution","and","the","slow","surface","dissolution","of","the","transition","metal","ions","[","13","]",",","[","17","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":395,"tokens":["By","calculating","the","reaction","energy","of","dehydrogenation","reaction","with","a","noble","electrode","and","a","delithiated","LiCoO2","cathode",",","we","found","that","(","Figure","3",")","the","reaction","energy","is","highest","in","absolute","value","at","the","surface","of","Li0",".","5CoO2","when","external","potential","is","applied","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":396,"tokens":["The","improved","cyclic","stability","of","the","ZrO2","coated","LiNi0",".","5Co0",".","2Mn0",".","3O2","at","the","elevated","temperature","can","be","ascribed","to","the","appearance","of","the","ZrO2","coating","that","stabilizes","the","surface","structure","of","LiNi0","."],"ner_tags":["O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":397,"tokens":["66","It","exhibits","an","ionic","conductivity","in","the","order","of","10","−","4","S","cm","−","1","and","a","high","lithium","transference","number","of","0",".","7","–","0",".","8","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":398,"tokens":["In","order","to","understand","the","occupation","of","doping","atoms","in","the","LLZO","lattice","and","the","corresponding","influence","on","the","Li","ionic","conductivity",",","some","theoretical","work","has","been","performed","to","investigate","the","possible","Li","pathway","in","the","lattices","of","undoped","and","doped","LLZO","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":399,"tokens":["Al","-","O","-","4","and","(","b",")","Li","-","Al","-","O","-","4",".","The","initial","charge","\/","discharge","profiles","of","NCM",",","Al","-","O","-","2","and","Li","-","Al","-","O","-","2","at","a","current","density","of","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":400,"tokens":["and","the","higher","value","(",">","1",".","2",")","of","I003","\/","I104","in","NCM811","-","LP","-","LLZTO","means","that","the","good","cationic","order","of","Li","+","\/","Ni2","+","is","not","changed","after","the","interface","-","engineered","process","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":401,"tokens":["From","energy","dispersive","X","-","ray","spectroscopy","(","EDS",")","mapping",",","it","was","enriched","in","Co","and","B","and","depleted","in","Ni","and","O","compared","with","the","NCM","lattice","(","Fig",".","2e",")",",","consistent","with","the","targeted","CoxB","composition","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O"]}
{"id":402,"tokens":["C2H6",",","HCHO",",","O2",",","CH3OH",",","CO2",",","CH3CHO",",","CH3CH2OH",",","and","HCOOH",".","The","significant","gas","release","along","with","the","continuous","cell","voltage","jittering","suggests","a","violent","decomposition","of","PEO","(","Figure","1b",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":403,"tokens":["Moreover",",","the","three","cathodes","differ","in","their","electrochemical","cycling","performance",".","The","capacity","loss","after","100","cycles","is","29","%",",","31","%",",","and","19","%","for","pristine","LiCoO2",",","ZrO2","coated","LiCoO2","powder","and","ZrO2","coated","LiCoO2","electrode",",","respectively","."],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O"]}
{"id":404,"tokens":["However",",","part","of","the","smaller","capacity","could","also","be","related","to","the","suppression","of","the","side","reactions","of","the","cathode","electrode","with","the","electrolyte",",","as","will","be","confirmed","by","the","electrochemical","impedance","spectroscopy","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":405,"tokens":["Recently",",","atomic","layer","deposition","(","ALD",")","technique","has","been","successfully","used","to","prepare","the","uniform",",","dense",",","homogenous",",","conformal","coating","with","well","-","controlled","thickness","on","either","individual","particles","or","the","whole","composite","electrodes","for","the","Li","-","ion","batteries","[","23","]",",","[","24","]",",","[","25","]",",","[","26","]","."],"ner_tags":["O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":406,"tokens":["This","will","be","discussed","below","in","more","detail",".","To","effect","of","Al2O3","on","the","rate","capabilities","of","the","NCM","-","based","cathodes","was","investigated",".","As","could","be","expected","from","the","reduced","total","cell","resistance","of","NCM","\/","Al2O3",",","NCM","\/","Al2O3","showed","much","improved","rate","capabilities","compared","to","bare","NCM","under","not","only","a","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":407,"tokens":["which","provides","Li","+","transport","channels","along","the","pores",",","as","shown","in","Figure","6","e",".","Systematic","studies","reveal","that","larger","pore","size","and","stronger","Lewis","acidity","of","OMSs","favor","the","lithium","ion","transport","in","MOF","channels","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":408,"tokens":["Besides","the","intrinsic","bulk","structure","instability","nature",",","the","surface","instability","issues","become","more","pronounced","at","high","voltages",".","[","5","]","On","the","one","hand",",","the","recent","research","reveals","that","the","lattice","oxygen","of","LiCoO2","is","activated","after","removal","of","half","lithium","(","Li0",".","5CoO2",",","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":409,"tokens":["Later",",","the","same","group","synthesized","a","similar","HSSE","based","on","dehydrated","UiO","-","66","(","Zr6O4","(","OH",")","4","(","bdc",")","6",";","bdc2","−","0","1",",","4","-","benzenedicarboxylate",")","with","unsaturated","Zr4","+","sites","to","graft","with","lithium","tert","-","buoxide",",","showing","an","ambient","ionic","conductivity","of","1",".","8","×","10","−","5","S","cm","−","1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":410,"tokens":["The","controllable","coatings","were","deposited","via","ALD",".","It","was","demonstrated","that","the","controllable","coatings","are","effective","in","improving","both","cycling","stability","and","rate","capability","of","LiCoO2","cathode",".","LiCoO2","electrodes","were","prepared","by","slurry","-","casting","on","Al","foils","that","served","as","current","collectors","."],"ner_tags":["O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":411,"tokens":["(","For","interpretation","of","the","references","to","color","in","this","figure","caption",",","the","reader","is","referred","to","the","web","version","of","this","article",".",")","Table","2","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":412,"tokens":["and","ethyl","methyl","carbonate","(","EMC",")","(","EC",":","DMC",":","EMC","0","1",":","1",":","8",",","by","v","\/","v","ratio",")",".","Galvanostatic","charge","-","discharge","cycling","was","performed","on","a","Land","-","2100","automatic","battery","tester","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":413,"tokens":["Furthermore",",","the","LLZTO","-","LP","that","was","generated","on","the","NCM811","particles","could","promote","the","binding","between","the","cathode","and","solid","state","electrolyte","and","weaken","the","space","charge","layer","in","them","because","of","their","physical","properties","and","the","slow","surface","potential","drop",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":414,"tokens":["LiCoO2","and","LATP","were","synthesized","by","a","solid","-","state","synthesis","method",".","For","LiCoO2","powder",",","stoichiometric","amounts","of","lithium","hydroxide","and","cobalt","acetate","were","mixed","thoroughly","and","then","heated","at","400","°","C","for","6","h","followed","by","800","°","C","for","10","h","in","air","[","46","]","."],"ner_tags":["B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":415,"tokens":["Finally",",","coupling","of","mature","ALD","technique","to","fluidizing","techniques","can","help","provide","uniform","coating","or","complete","surface","treatment","of","particles","for","better","protection",".","Research","funded","by","U","."],"ner_tags":["O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":416,"tokens":["the","1st","cycle","at","0",".","2C","and","b",")","the","50th","cycle","at","0",".","5C","(","1C","0","274","mA","g","−","1",")",".","c",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":417,"tokens":["2O2","(","NMC532",",","L","&","F","Co",".",")",",","3","wt","%","polyvinylidene","fluoride","(","PVDF",",","SOLEF","5130",",","Solvay","SA",")",",","and","3","wt","%","carbon","black","(","super","P","Li","®",")","in","N","‐","methyl","‐","2","‐","pyrrolidone","(","NMP",")","solvent","coated","on","an","aluminum","collector","."],"ner_tags":["I-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":418,"tokens":["0","M","LiPF6","in","a","mixture","of","ethylene","carbonate","(","EC",")","and","ethyl","methyl","carbonate","(","EMC",")","(","3","\/","7",",","v","\/","v",")","(","Panax","Etec","Co",".",")","was","used","as","the","electrolyte","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":419,"tokens":["Using","LiCoO2","as","an","example","material",",","they","demonstrated","the","impact","of","the","surface","chemistry","on","the","performance","of","the","material",".","26","They","found","that","the","capacity","retention","was","greatly","improved","by","simply","grinding","the","LiCoO2","powders",","],"ner_tags":["O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":420,"tokens":["45","For","example",",","Lu","etc",".","prepared","a","IL","-","SiO2","nanoparticle","hybrid","electrolyte","(","Figure","5","a",")",",","which","shows","improved","ionic","conductivity","and","electrochemical","stability","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":421,"tokens":["The","lithium","-","ion","cells","were","cycled","at","various","C","-","rates","and","within","a","3",".","0","–","4",".","9","V","voltage","range",",","delivering","a","capacity","of","120","mAh","\/","g","at","C","\/","3","rate",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":422,"tokens":["While","there","may","be","other","factors","that","could","also","contribute","to","the","improved","stability","when","LiAlF4","is","applied",",","the","reduced","parasitic","reaction","at","the","electrode","–","electrolyte","interface","is","an","important","one","as","suggested","by","our","CE","analysis","and","impedance","spectra","analysis","(","see","Supporting","Information","for","a","brief","discussion","of","failure","mechanisms","and","additional","characterizations",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":423,"tokens":["69","Such","3D","COF","with","anionic","framework","could","conduct","Li","+","ions","after","incorporating","Li","+","as","the","counter","ion",".","As","shown","in","Figure","7","c","and","d",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":424,"tokens":["The","polymer","separator","(","1","layer",",","16","mm","Ø",",","Celgard","2500",",","Celgard",")","was","wetted","with","90","μ","L","of","the","electrolyte","(","1","M","LiPF6","in","a","mass","ratio","of","3",":","7","of","ethylene","carbonate","(","EC",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":425,"tokens":["S8","shown",",","the","amount","of","Li2CO3","in","the","two","pristine","samples","is","much","more","than","that","in","interface","-","engineering","cathode",",","and","this","result","is","further","proof","of","the","better","electrochemical","performance","of","NCM811","-","LP","-","LLZTO","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O"]}
{"id":426,"tokens":["5","nA",",","followed","by","fine","polish","at","an","accelerating","voltage","of","2","kV","with","a","small","current","of","40","pA",".","The","atomic","structure","of","the","LiCoO2","was","characterized","using","an","ARM","-","200CF","(","JEOL",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O"]}
{"id":427,"tokens":["60","The","ionic","conductivity","can","be","adjusted","by","increasing","the","pore","size","of","MOF","matrix","or","tuning","the","concentration","of","gust","electrolyte","salts",",","reaching","a","value","as","high","as","2",".","5","×","10","−","4","S","cm","−","1","at","room","temperature","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":428,"tokens":["69","Å",")","and","Li","+","(","0",".","76","Å",")",",","Ni2","+","ions","can","occupy","lithium","sites",",","which","is","called","“","cation","mixing","”","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":429,"tokens":["2","mA","h","g","−","1","to","149",".","3","mA","h","g","−","1","with","a","capacity","retention","of","only","79",".","7","%","after","100","cycles","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":430,"tokens":["Maybe","the","introduce","of","nanometer","scale","LLZTO","in","the","positive","electrode","is","beneficial","for","the","densification","of","the","NCM811","-","LP","-","LLZTO","electrode",".","The","surface","of","nickel","rich","cathode","and","LLZTO","are","both","easily","to","react","with","air","and","result","the","generation","of","Li2CO3","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":431,"tokens":["54056","Å",")",".","Fig",".","2","(","b",")","shows","that",",","in","comparison","with","pristine","sample","having","smooth","surface","and","well","-","defined","edges","(","an","inset","is","a","TEM","image",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":432,"tokens":["Note","that","the","PPy","-","LP","sample","had","the","highest","Li","+","diffusion","coefficient","which","was","achieved","by","being","coated","with","high","ionic","conductive","Li3PO4","and","high","electronic","conductive","PPy","."],"ner_tags":["O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","O"]}
{"id":433,"tokens":["0","V","and","30","°","C","could","maintain","of","91","%","of","initial","relatively","low","discharge","capacity","of","100","mAh","\/","g","over","200","cycles","showing","high","coulombic","efficiency","excepting","the","1st","cycle","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":434,"tokens":["The","thicknesses","of","ZrO2","coating","layers","were","varied","using","two","different","ALD","cycles","[","5",",","20","]",",","which","were","chosen","to","be","the","optimum","cycles","for","LIB","performance","based","on","the","previous","studies","[","15",",","16",",","23","]","."],"ner_tags":["O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":435,"tokens":["The","binding","energy","of","the","NCM811",",","LP","and","LLZTO","are","1",".","49",",","1",".","16","and","1",".","07","eV",",","which","shows","that","lithium","ions","are","difficult","to","extract","from","the","cathode","material","."],"ner_tags":["O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":436,"tokens":["which","we","abbreviate","as","‘","infusion","’","to","distinguish","it","from","a","typical","surface","coating",".","This","is","similar","to","the","complete","wetting","of","GBs","by","liquid","metal","(","for","example",",","liquid","Ga","in","aluminium","GBs",")",","],"ner_tags":["O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":437,"tokens":["There","are","two","kinds","of","structures","of","garnet","structured","LLZO",",","thus","tetragonal","and","cubic","structured","LLZO","phases",",","where","the","Li","ionic","conductivity","of","the","tetragonal","phase","much","higher","than","that","of","the","cubic","phase","[","138","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":438,"tokens":["and","2C",",","respectively",".","The","discharge","capacity","decreases","with","the","increasing","current","density","owing","to","the","lower","diffusion","rate","of","the","cathode","electrodes","at","a","higher","current","rate","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O"]}
{"id":439,"tokens":["However",",","evaporation","methods","limit","the","application","of","LiAlF4","to","devices","with","a","planar","geometry",".","(","32",",","33",")","Compared","to","the","above","-","mentioned","methods",",","ALD","could","achieve","uniform","coating","on","high","surface","area","electrodes","directly","."],"ner_tags":["O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":440,"tokens":["In","Figure","5",",","we","tested","the","rate","performance","of","pristine","and","ALD","coated","NMC","-","811","electrodes","with","an","electrochemical","window","of","2",".","75","–","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":441,"tokens":["The","HAADF","images","were","acquired","with","a","collection","angle","of","90","–","370","mrad",".","The","EELS","elemental","mapping","was","performed","with","an","energy","dispersion","of","1","eV","per","channel","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":442,"tokens":["She","obtained","her","M",".","E",".","and","Ph",".","D",".","degree","in","Chemical","Engineering","and","Technology","from","Tianjin","University","at","2017",".","She","was","a","visiting","graduate","researcher","with","Prof","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":443,"tokens":["In","the","meanwhile",",","two","new","bands","appear","at","1035","cm","−","1","and","1097","cm","−","1","which","can","be","assigned","to","the","asymmetrical","stretching","of","PO","thus","confirming","the","formation","of","Li3PO4","[","8","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O"]}
{"id":444,"tokens":["It","is","interesting","to","note","that","despite","the","fact","of","limited","electrochemical","stability",",","polyethylene","oxide","and","its","derivatives","have","always","been","and","seem","to","remain","one","of","the","most","popular","class","of","polymer","materials","used","for","the","development","of","solid","polymer","electrolytes","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":445,"tokens":["As","shown","in","Fig",".","2a","and","b",",","the","morphological","characteristics","of","the","NCM","cathodes","after","the","addition","of","Al2O3","were","not","significantly","different",".","The","NCM","particles","were","well","dispersed","in","the","super","-","P","Li","regardless","of","the","existence","of","Al2O3","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":446,"tokens":["3","mAhh","g","−","1","for","NCM","\/","Al2O3","and","bare","NCM",",","respectively",")",".","Along","with","this","result",",","NCM","\/","Al2O3","showed","smaller","DC","-","IR","properties","during","the","HPPC","test","for","both","the","charging","and","discharging","processes","over","every","SOC","(","Fig",".","9c","and","d",")","."],"ner_tags":["O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":447,"tokens":["S4800",",","Hitachi",")",".","The","crystal","structure","of","samples","was","analyzed","by","XRD","(","Bruker",",","D8","ADVANCE",")",".","The","XPS","spectra","were","recorded","by","an","ESCALAB","250","Xi",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":448,"tokens":["10","eV","is","attributed","to","the","O","1s","binding","energy","of","Li3PO4","[","8","]",",","[","33","]",".","However",",","the","intensity","of","the","Li2CO3","-","related","O1s","peak","gradually","decreases","which","indicates","that","the","Li2CO3","impurity","is","partly","cleaned","by","the","Li3PO4","coating","process","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","I-COATING_METHOD","O"]}
{"id":449,"tokens":["20","To","date",",","few","candidate","additives","have","been","reported","to","provide","a","protective","passivation","film","for","cathodes",".","Alternatively",",","surface","coatings","have","been","reported","to","extend","the","performance","of","cathode","materials","by","either","changing","the","surface","chemistry25",",","26","or","providing","physical","protection","layers",".","2",",","3","This","paper","discusses","the","role","of","surface","coatings","in","high","-","performance","cathode","materials","for","lithium","-","ion","batteries",",","as","well","as","surface","coating","techniques","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":450,"tokens":["5Mn1",".","5O4","[","27","]",",","[","28","]",",","[","29","]",",","[","30","]",".","Herein","in","this","work",",","Li3PO4","was","studied","as","a","coating","material","for","the","Li","-","excess","Li1","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":451,"tokens":["15","The","inserted","polymer","layer","effectively","buffers","the","growth","of","lithium","dendrites",",","as","well","as","the","formation","of","solid","electrolyte","interphase","and","side","reaction","between","Li","metal","and","garnet","pellets","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":452,"tokens":["Goodenough","et","al",".","[","3","]",",","dominates","the","cathode","electrode","material","of","commercial","lithium","ion","batteries","for","consumer","electronics","due","to","its","high","volumetric","energy","density","as","well","as","good","rate","capability","and","cycling","stability","[","4","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":453,"tokens":["Ni0",".","8Co0",".","1Mn0",".","1","(","OH",")","2","precursor","was","obtained","from","Green","Eco","-","Manufacture","Co",".","The","active","cathode","material","of","LiNi0",".","8Co0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":454,"tokens":["With","a","detailed","analysis","on","their","local","lattice","fringe",",","it","was","surprising","to","find","that",",","while","the","bulk","structure","remains","a","pristine","layered","structure","with","an","interplane","spacing","of","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":455,"tokens":["6","eV",")",".","The","crystallographic","structure","of","NMC532","electrodes","was","examined","using","an","X","-","ray","diffractometer","(","XRD",",","D","\/","MAX","-","2500",",","Rigaku",")","with","Cu","Ka","radiation","at","a","scan","rate","of","1","°","min","−","1","."],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":456,"tokens":["Furthermore",",","O1s","peak","at","low","binding","energy","of","pristine","sample","disappears",".","This","suggests","that","lattice","oxygen","is","almost","fully","covered","up","by","the","adsorbed","species","or","active","oxygen","species","on","the","surface","of","the","stored","sample","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":457,"tokens":["LiPF6",")","in","a","mixed","organic","solvent","(","e",".","g",".","ethylene","carbonate","–","dimethyl","carbonate",",","EC","–","DMC",")","embedded","in","a","separator","felt","[","6","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":458,"tokens":["On","the","other","hand",",","the","electrolyte","decomposition","products",",","cathode","electrolyte","interphase","(","CEI",")",",","have","also","been","found","unstable","at","high","voltages","and","involved","in","a","dynamic","evolution","of","dissolution","-","deposition","over","charge","–","discharge","cycles",".","[","7","]"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":459,"tokens":["The","secondary","aggregate","particles","are","highly","disintegrated",",","leading","to","more","penetration","of","electrolyte","to","the","bulk","and","accelerate","structural","degradation","along","with","other","surface","side","reactions","resulting","in","the","dissolution","of","the","transition","metals","in","the","delithiated","state","[","42","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":460,"tokens":["However",",","a","superior","film","which","satisfies","all","major","requirements","simultaneously","including","electrochemically","inert",",","chemically","stable",",","lithium","ion","conductive",",","and","highly","uniform","is","still","missing","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":461,"tokens":["which","effectively","protects","the","LiNi0",".","8Co0",".","1Mn0",".","1O2","surface","from","attack","of","the","violent","liquid","electrolyte",".","Fig",".","5",".","(","a",")","The","initial","charge","\/","discharge","curves","of","pristine","and","V2O5","-","coated","sample","at","0","."],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O"]}
{"id":462,"tokens":["The","metal","oxide","ZrO2","thin","film","was","also","coated","on","LiCoO2","powder","by","the","similar","process","for","the","comparison",".","The","morphologies","and","structures","of","various","metal","oxide","thin","film","coating","layers","were","observed","by","a","field","emission","scanning","electron","microscope","(","FE","-","SEM",","],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","B-COATING_MATERIAL","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":463,"tokens":["5","wt","%","LATP","modified","-","LiCoO2","just","exhibits","a","small","increase","in","polarization","with","well","-","maintained","capacity",".","Rate","performance","of","0",".","5","wt","%","LATP","modified","-","LiCoO2","and","bare","LiCoO2","at","0","."],"ner_tags":["O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":464,"tokens":["All","electrochemical","measurements","were","carried","out","in","two","-","electrode","coin","cells","(","CR2032",",","Hohsen","Corporation",")","with","a","NCM","-","811","-","based","(","uncoated","or","coated",")","positive","electrode","(","12","mm","Ø",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":465,"tokens":["8Co0",".","1Mn0",".","1",")","(","OH",")","2",")","with","LiOH","·","H2O","in","a","molar","ratio","of","1",":","1",".","025",",","followed","by","a","heat","treatment","at","450","°","C","for","2","h","and","then","at","800","°","C","for","10","h","in","flowing","oxygen","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":466,"tokens":["Aldrich",")",".","To","achieve","a","uniform","dispersion","of","Al2O3","in","the","solution",",","the","NMP","-","based","Al2O3","\/","PVdF","slurry","was","stirred","for","24","h","(","at","room","temperature",",","25","°","C",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":467,"tokens":["Previous","work","by","Li","et","al",".","(","21",")","has","shown","that","the","fast","capacity","decay","is","related","to","the","interface","instability","when","cycled","at","a","wide","electrochemical","window","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":468,"tokens":["2","C","(","50","mA","g","−","1",")","in","a","voltage","range","of","2",".","7","–","4",".","5","V","vs",".","Li","\/","Li","+",";","(","b",")","rate","capability","of","NCM",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O"]}
{"id":469,"tokens":["Finally",",","the","electrochemical","performance","of","this","GPE","(","50","wt",".","%","PQ","filler",")","was","then","examined","in","a","half","-","cell","system","by","employing","NCM622","as","cathode",",","delivering","a","high","specific","capacity","of","145","mAh","\/","g","and","a","stable","coulombic","efficiency","approaching","99","%","after","100","cycles","at","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":470,"tokens":["Building","a","compatible","layer","that","is","identical","to","the","solid","state","electrolyte","(","LLZTO",")","on","the","surface","of","NCM811","could","help","weaken","the","SCL",",","because","the","SCL","depends","on","the","distribution","of","ions","concentration","on","the","surface","[","41","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":471,"tokens":["While","the","interfacial","stability","between","the","electrode","and","electrolyte","must","be","improved","in","order","to","achieve","the","long","-","term","stability","and","meet","the","safety","requirements","[","8","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":472,"tokens":["which","decreases","the","stress","among","the","binder",",","the","cathode",",","and","the","conductive","agent",",","thereby","reduce","the","formation","of","the","voids","among","them","[","66","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":473,"tokens":["Over","-","prolonged","cycling","can","aggravate","the","dissolution","of","transition","metals",",","especially","Mn",".","All","the","aforementioned","mechanisms","are","further","aggravated","at","elevated","temperature","conditions","and","cause","degradation","of","the","electrodes","[","42","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":474,"tokens":["By","properly","selecting","the","chemical","composition","and","manipulating","the","microscopic","architecture",",","inorganic","-","polymer","HSSEs","would","bring","a","notable","leap","towards","the","practical","applications","of","conventional","polymer","and","inorganic","-","based","SSEs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":475,"tokens":["and","the","characteristic","lattice","plane","(","0","0","2",")","has","a","lattice","spacing","of","about","2",".","46","Å",",","and","this","demonstrates","that","the","layer","contains","LP","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":476,"tokens":["This","work","was","also","supported","by","the","Korea","Science","and","Engineering","Foundation","(","KOSEF",")","grant","funded","by","the","Korea","government","(","MEST",")","(","No",".","2009","-","0092780",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":477,"tokens":["They","prepared","self","-","standing","polymer","membranes","by","solvent","casting","technique",",","obtaining","films","of","150","–","200","μ","m","thickness",".","Thus",",","the","optimized","formulation","of","IGPE","(","PEO","+","20","wt",".","%","LiTFSI","+","10","wt",".","%","EMIMFSI",")","showed","the","highest","value","of","ionic","conductivity","(","σ",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":478,"tokens":["This","may","lead","to","the","loss","of","the","electronic","contact","between","the","particles","and","enhanced","parasitic","side","reactions","due","to","the","formation","of","new","contact","surfaces","between","the","electrolyte","and","the","active","material","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":479,"tokens":["The","morphology","of","the","particles","was","measured","by","scanning","electron","microscope","(","JEOL",",","JSM","-","5612LV",")","with","an","accelerating","voltage","of","20","kV",",","and","by","transmission","electron","microscope","(","Tecnai","G12",",","200","kV",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":480,"tokens":["Increasing","the","charge","cut","-","off","potential","will","result","in","higher","energy","densities","[","4","]",",","[","10","]",".","However",",","the","relatively","poor","cycling","performance","at","higher","operation","potentials","is","a","major","drawback","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":481,"tokens":["1","s","and","15","s",",","respectively",".","Typical","pulse","and","purge","durations","for","TiF4","subcycle","are","0",".","1","s","and","15","s",",","respectively",".","Spherical","precursor","Ni0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":482,"tokens":["Figure","6","Open","in","figure","viewer","PowerPoint","MOF","-","liquid","HSSEs",".","(","a",")","Formation","of","solid","electrolyte","based","on","Mg2","(","dobdc",")","MOF","and","schematic","of","structure","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":483,"tokens":["Freed","H","+","leads","to","the","formation","of","extremely","strong","acid","HTFSI",",","which","will","further","attack","PEO","resulting","in","cleavage","of","PEO","bonds",".","Like","other","acids",",","HTFSI","may","also","corrode","LiCoO2","particles",",","resulting","in","the","degradation","of","cathode","structures","and","formation","of","the","cathode","–","SPE","interface","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":484,"tokens":["A","metal","oxide","such","as","ZrO2","serves","as","a","HF","scavenger","that","suppresses","the","dissolution","of","active","materials","via","the","following","reaction","[","16",",","21","]",":","(","7",")"],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":485,"tokens":["Galvanostatic","cycling","was","performed","on","a","symmetric","Li","\/","Li","cell","at","a","Li","plating","\/","stripping","current","density","of","1",".","0","or","2",".","0","mA","cm","−","2","with","a","cycling","capacity","of","2","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":486,"tokens":["13","The","PEO","-","based","GPE","effectively","decreases","the","interfacial","resistance","and","the","LAGP","layer","blocks","the","shuttling","of","polysulfides",",","which","prevents","the","loss","of","active","materials","in","the","cathode","and","internal","short","-","circuit","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":487,"tokens":["and","the","composite","was","then","densified","with","cold","pressing","after","removal","of","solvent","to","build","a","3D","interface","between","solid","electrolyte","and","cathode","[","161","]",".","Fig","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":488,"tokens":["This","journal","is","©","The","Royal","Society","of","Chemistry","2010","Abstract","Hybrid","solid","-","state","electrolytes","(","HSSEs",")","are","keys","to","the","development","of","lithium","batteries","with","enhanced","energy","density","and","safety","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":489,"tokens":["the","LATP","@","LCO","-","700","also","demonstrates","a","superior","performance","with","the","high","initial","discharge","capacity","and","the","excellent","capacity","retention",",","and","best","high","-","temperature","cycle","performances","among","the","reported","results","(","Figure","3e",";"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":490,"tokens":["After","characterizing","the","electrochemical","properties","of","this","GPE",",","they","assembled","LiFe0",".","2Mn0",".","8PO4","\/","IPN","-","PDEC","\/","Li","cells","and","tested","them","in","a","voltage","range","of","2",".","5","–","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":491,"tokens":["The","SEM","images","of","the","bare","and","ZrO2","-","coated","NMC532","electrodes","(","Fig",".","2c",")","show","neither","deformation","of","the","cathode","nor","any","difference","from","the","bare","NMC532","electrode","(","bare","NMC",")",",","indicating","that","the","ultrathin","ZrO2","layer","is","coated","onto","the","as","-","prepared","electrode","in","a","non","-","invasive","manner","."],"ner_tags":["O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":492,"tokens":["which","are","ascribed","to","the","ZrO2","coating","[","14","]",".","Fig",".","6",".","Cyclic","voltammograms","of","(","a",")","the","bare","NMC","electrode","and","(","b",")","ZrO2","ALD","-","5","at","a","scan","rate","of","0","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O"]}
{"id":493,"tokens":["Therefore",",","Li3PO4","coating","could","be","an","effective","way","to","improve","the","electrochemical","properties","of","Li","-","excess","layered","cathode","materials",".","This","work","was","supported","by","the","973","Program","(","No",".","2015CB251103",")",","],"ner_tags":["O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":494,"tokens":["Biologic",",","France",".",")","A","thin","layer","of","Al","2","O","3","film","was","deposited","in","a","laminar","-","flow","-","type","thermal","ALD","reactor","(","NCD",","],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O"]}
{"id":495,"tokens":["The","cathode","electrode","was","prepared","by","mixing","the","LiCoO2","powder",",","carbon","black","and","polyvinylidene","fluoride","(","PVDF",")","binder","with","a","weight","ratio","of","95",":","2",":","3","and","blade","coating","on","Al","foil","."],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":496,"tokens":["5","and","206",".","1","mAh","g","−","1","for","the","ZrO2","-","coated","LiNi0",".","5Co0",".","2Mn0",".","3O2","with","2",",","5","and","8","ALD","cycles",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O"]}
{"id":497,"tokens":["For","HF","titration",",","the","cycled","cells","were","carefully","disassembled","and","all","contents","of","the","cell","washed","thoroughly","with","DMC","for","one","week","in","the","glove","box",".","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":498,"tokens":["(","11",",","12",")","Third",",","the","anisotropic","lattice","volume","contraction","or","expansion","among","primary","particles","during","charging","\/","discharging","test","will","result","in","cracks","which","lead","to","deteriorative","cycling","performance","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":499,"tokens":["In","comparison",",","the","LMA","paired","with","CoxB","–","NCM","had","a","smooth","surface","and","a","dense","SEI","layer","(","Fig",".","5d",",","e",")",".","The","contrasting","morphology","was","closely","related","to","the","composition","and","stability","of","the","SEI",","],"ner_tags":["O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":500,"tokens":["By","contrast",",","ZrO2","coated","LiCoO2","powder","shows","an","obvious","difference","during","the","first","two","charge","processes",",","which","indicates","that","a","big","irreversible","process","occurs","in","the","first","charge","process","due","to","ZrO2","coating","on","LiCoO2","powder","."],"ner_tags":["O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O"]}
{"id":501,"tokens":["Al","2","O","3","-","coated","electrode","\/","Fig",".","6",".","Schematic","of","ALD","Al","2","O","3","-","modified","NCM811","electrode","6",".","Conclusions","We","successfully","modified","the","interface","of","the","NCM811","cathode","by","Al","2","O","3","using","ALD","."],"ner_tags":["B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_METHOD","O"]}
{"id":502,"tokens":["the","diffusion","coefficient","of","Li","+","(","DLi","+",")","can","be","calculated","from","the","formula","below",":","(","23",",","44",",","45",")","(","7",")","R","represents","the","gas","constant",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":503,"tokens":["the","core","-","shell","structure","[","13","]",",","and","electrolyte","additives","[","14","]",".","Among","these",",","surface","modification","is","highly","successful","in","mitigating","the","irreversible","side","reactions","and","preventing","structural","collapse","for","long","cycles","[","10","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":504,"tokens":["the","composite","exhibited","high","capacity","(","around","180","mAh","\/","g",")","and","good","cycle","performance","at","high","potential","(","4",".","5","V",")",".","Lee","et","al",".","[","44","]","prepared","the","LATP","modified","LiCoO2","powder","by","a","precursor","coating","method",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":505,"tokens":["and","Figure","5","(","PPy","-","LP",")",".","Homogeneous","distributions","of","Ni",",","Co",",","and","Mn","elements","on","the","surface","of","the","PPy","-","LP","sample","were","clearly","observed","."],"ner_tags":["O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O"]}
{"id":506,"tokens":["the","primary","particle","size","was","around","250","nm","in","diameter",",","and","it","formed","a","spherical","secondary","particle","by","aggregating","with","each","other",".","The","average","particle","size","for","the","spherical","secondary","particle","is","about","8","μ","m","in","diameter","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":507,"tokens":["the","test","result","shows","that","the","polymer","electrolyte","membrane","has","a","lithium","-","ion","migration","rate","of","0",".","56","at","60","°","C",".","This","experimental","result","is","caused","mainly","due","to","the","double","matrix","organic","polymer","macromolecule","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":508,"tokens":["which","in","turn","cause","large","polarization",".","All","the","samples","are","composed","of","sphere","-","like","particles",".","The","layered","structure","of","the","materials","can","still","be","identified","by","the","FFT","patterns","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":509,"tokens":["These","coatings","significantly","decreased","lithium","diffusion","and","electron","transport","in","the","cathode","particles",";","as","a","result",",","it","is","reasonable","that","the","coated","cathode","powder","shows","lower","performance","than","the","pristine","one","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":510,"tokens":["The","smaller","initial","value","of","Δ","V","indicates","less","electrode","polarization","and","better","cycle","reversibility","[","[","39","]",",","[","40","]",",","[","41","]","]",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":511,"tokens":["Atomic","layer","deposition","(","ALD",")","is","a","non","-","solution","-","based","coating","technique","for","conformal","coating","of","thin","films","and","surface","layers","down","to","atomic","thickness","with","homogeneity",",","a","well","-","controllable","thickness",","],"ner_tags":["B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","B-COATING_METHOD","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":512,"tokens":["and","structural","order","[","23","]","in","Table","1",".","However",",","no","additional","peak","can","be","assigned","to","the","Raman","active","modes","of","the","amorphous","or","crystallized","ZrO2","at","the","corresponding","spectrum","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O"]}
{"id":513,"tokens":["and","hybrid","electric","vehicles","(","HEVs",")","[","1","]",",","[","2","]",",","[","3","]",",","[","4","]",",","[","5","]",",","[","6","]",",","[","7","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":514,"tokens":["The","results","demonstrate","that","the","side","reaction","between","PEO","and","LiCoO2","can","be","restrained","significantly","by","the","compact","ultrathin","film","of","LATP",".","Fig",".","6",".","(","a",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":515,"tokens":["and","1","m","LiPF6","in","ethylene","carbonate","\/","dimethyl","carbonate","(","EC","\/","DMC",",","1",":","1","in","volume",")","as","an","electrolyte","in","an","argon","-","filled","glovebox","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":516,"tokens":["The","O","1s","XPS","of","the","pristine","sample","is","composed","of","two","peaks",".","The","other","one","with","binding","energy","of","532",".","19","eV","is","due","to","the","CO32","−","group","of","Li2CO3","[","32","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":517,"tokens":["In","early","studies",",","it","was","believed","that","the","improved","ionic","conductivity","of","polymer","-","inorganic","HSSEs","is","attributed","to","the","cation","transfer","within","the","interphase","region","around","the","inorganic","particles","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":518,"tokens":["This","research","was","supported","by","the","National","Natural","Science","Foundation","of","China","(","51572194","and","51672189",")",",","The","Key","Project","of","the","Tianjin","Science","&","Technology","Support","Program","(","17YFZCGX00550",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":519,"tokens":["Cobalt","boride","metallic","glass","was","successfully","applied","to","a","Ni","-","rich","layered","cathode","LiNi0",".","8Co0",".","1Mn0",".","1O2",".","It","dramatically","improved","the","rate","capability","and","cycling","stability",",","including","under","high","-","discharge","-","rate","and","elevated","-","temperature","conditions","and","in","pouch","full","-","cells","."],"ner_tags":["B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":520,"tokens":["Fig",".","11","shows","the","average","discharge","voltage","and","specific","discharge","energy","of","the","samples","at","the","current","density","of","40","mA","g","−","1",".","The","average","discharge","voltage","of","the","pristine","Li1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":521,"tokens":["which","explains","that","V2O5","continuously","works","as","an","HF","scavenger","and","protects","the","active","material","during","storage",".","This","protective","effect","of","the","coating","layer","from","the","reactive","electrolyte","may","lead","to","enhanced","electrochemical","properties","of","the","coated","material","."],"ner_tags":["O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":522,"tokens":["X","-","ray","diffraction","analysis","(","XRD",")","was","performed","to","examine","the","phase","purity","of","the","LiCoO2","after","surface","treatment","(","Figure","S3",",","Supporting","Information",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":523,"tokens":["The","resulting","formation","energy","is","−","3",".","55","eV","\/","atom",".","This","value","is","calculated","at","0","K","and","0","atm","and","uses","a","reference","energy","of","zero","for","the","pure","elements","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":524,"tokens":["Their","discovery","also","proves","the","applicability","of","sulfide","electrolytes","for","the","development","of","all","solid","-","state","lithium","-","ion","batteries","both","with","high","voltage","and","high","current","capability",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":525,"tokens":["The","best","performance","was","obtained","with","LiFSI","salt","whereas","solid","electrolytes","based","on","LiTFSI","and","LiClO4","salts","demonstrated","very","poor","electrochemical","performance",".","High","-","voltage","-","tolerated","polymer","electrolyte","(","HVTPE",")","based","on","poly","(","fluoroethylene","carbonate",")","(","PFEC",")",",","synthesized","through","ring","-","opening","polymerization",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":526,"tokens":["the","coating","amount",",","and","thickness",",","as","well","as","the","cell","setup","in","which","the","cathode","material","is","studied",".","Even","though","there","are","reports","showing","an","improved","rate","capability","for","the","coated","or","doped","cathode","materials",",","(","35",",","44",")","there","also","various","reports","showing","a","similar","or","even","worse","rate","performance","of","the","coated","cathode","material","in","comparison","to","an","uncoated","material","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O"]}
{"id":527,"tokens":["Thermo","Fisher","with","monochromatic","150","W","Al","K","α","radiation",".","The","XPS","data","were","analyzed","with","software","Avantage","and","the","binding","energies","were","calibrated","by","the","C","1s","line","at","284","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":528,"tokens":["and","Al2O3","coatings","by","50","ALD","cycles",".","The","spectra","of","the","standard","TiO2",",","ZrO2",",","and","Al2O3","are","also","shown","for","comparison",".","The","coating","layer","shows","the","similar","peaks","to","the","standard","TiO2",",","indicating","the","TiO2","deposition","on","LiCoO2","cathode","by","the","ALD","process","."],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","B-COATING_METHOD","I-COATING_METHOD","O"]}
{"id":529,"tokens":["and","(","4","2","2",")","planes",",","respectively",",","which","can","be","indexed","to","LLZTO",".","The","EDS","image","(","Fig",".","2b",")","shows","that","zirconium","(","Zr",")",",","phosphorus","(","P",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":530,"tokens":["Wuxi","Xinguang","Powder","Equipment","Co",".",",","Ltd",".",",","China",")",".","The","mixture","was","then","further","mechanically","mixed","at","3000","rpm","min","−","1","for","20","min","using","a","mechanical","fusion","device","(","VSH","-","3",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":531,"tokens":["6","V","(","Figure","2b",")",".","In","addition",",","the","electrochemical","cycling","stability","of","the","cell","after","LATP","coating","was","also","significantly","improved","(","Figure","2c",",","d",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":532,"tokens":["For","comparison",",","the","F","\/","Li","atomic","ratio","in","ALD","LiF","film","and","F","\/","Al","atomic","ratio","in","ALD","AlF3","film","were","0",".","97","and","3",".","45",",","respectively","(","see","Supporting","Information",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","B-COATING_METHOD","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":533,"tokens":["B","\/","B","′",",","and","C","\/","C","′",")","corresponding","to","the","oxidation","and","reduction","reactions",",","which","are","positioned","at","(","4",".","069","\/","3","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":534,"tokens":["The","mechanism","behind","is","not","fully","understood","yet",",","but","could","be","a","subject","for","analysis","in","future","studies","due","to","the","strong","opportunity","to","increase","the","energy","density","of","high","power","lithium","ion","cells","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":535,"tokens":["Fig",".","7",".","Rate","capability","of","the","bare","and","ZrO2","-","coated","LiNi0",".","5Co0",".","2Mn0",".","3O2","electrodes","at","25","°","C",".","The","cyclic","stabilities","of","the","uncoated","and","coated","LiNi0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":536,"tokens":["5C","for","100","cycles","when","cycled","at","room","temperature","and","45","°","C",",","respectively",",","which","are","much","higher","than","those","of","bare","-","LCO","(","only","50",".","3","%","and","≈","32",".","5","%","capacity","remains",",","respectively",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":537,"tokens":["This","observation","indicates","that","the","coating","is","able","to","form","a","protective","layer",",","reducing","the","direct","contact","between","the","active","material","and","the","electrolyte","solution",",","thus","increasing","the","thermal","stability","and","the","safety","properties","of","the","NCM","-","811","material","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O"]}
{"id":538,"tokens":["and","8","ALD","cycles","(","d",")",".","XPS","measurement","was","used","to","analyze","surface","compositions","of","ZrO2","coated","LiNi0",".","5Co0",".","2Mn0",".","3O2","with","5","ALD","cycles","to","confirm","the","formation","of","the","oxide","coating","layer","."],"ner_tags":["O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":539,"tokens":["The","mixture","was","calcined","at","750","°","C","for","12","h","under","an","oxygen","atmosphere","in","a","tubular","furnace",".","A","similar","process","was","employed","to","prepare","NCM811","-","LLZTO","sample","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O"]}
{"id":540,"tokens":["2C","charge","\/","discharges","conducted","after","every","100","cycles",".","e",",","Cycling","performance","of","CoxB","–","NCM","\/","Gr","and","pristine","NCM","\/","Gr","full","-","cells","at","1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":541,"tokens":["Fig",".","3",".","(","a",",","b",")","Charge","–","discharge","and","differential","capacity","plot","of","ALD","-","modified","NCM811","at","room","temperature","(","0",".","2","C","rate",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":542,"tokens":["In","2013",",","Choi","et","al",".","[","109","]",",","fabricated","very","thin",",","deformable","and","safety","reinforced","(","with","PET",")","nonwoven","membrane","plastic","crystal","polymer","electrolyte","based","on","UV","-","cured","ETPTA","cross","-","linker","and","SN","-","LiTFSI","system","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":543,"tokens":["The","Li2O","residue","can","persist","outside","the","reaction","product","and","then","react","with","the","CO2","gas","in","air","forming","a","Li2CO3","surface","layer","[","30","]",".","The","particle","size","is","not","uniform","but","most","of","them","are","smaller","than","500","nm","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":544,"tokens":["The","authors","declare","that","they","have","no","known","competing","financial","interests","or","personal","relationships","that","could","have","appeared","to","influence","the","work","reported","in","this","paper",".","This","work","was","financially","supported","by","National","Key","R","&","D","Program","of","China","(","Grant","No",".","2018YFB0905400",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":545,"tokens":["This","indicates","that","the","surface","modification","has","no","significant","negative","impact","on","the","rate","performance","of","NCM","-","811","∥","graphite","full","cells",",","and","simultaneously",",","the","coating","layer","possesses","good","ionic","conductivity","."],"ner_tags":["O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O"]}
{"id":546,"tokens":["and","it","was","advantageous","to","weaken","the","SCL",".","Schematic","diagrams","of","the","interface","engineering","for","surface","energy","(","a",")",",","(","c",")","for","NCM811",",","(","b",")","(","d",")","for","NCM811","-","LP","-","LLZTO","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":547,"tokens":["357","nm","due","to","the","(","011",")","planes","of","Li3PO4",",","(","23","-","26",")","indicating","partly","crystallized","of","the","Li3PO4","nanoparticles",".","Figure","6c","shows","the","TEM","image","of","the","PPy","-","3","sample","which","reveals","that","LiNi0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":548,"tokens":["The","pH","value","of","the","powders","(","pristine",",","V2O5","-",",","TiO2","-","and","Al2O3","-","coated","samples",")","immersed","in","water","is","monitored","by","adding","20","g","powder","to","200","mL","purified","water","with","constant","stirring","with","a","magnetic","stirrer","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-COATING_MATERIAL","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":549,"tokens":["It","has","attracted","great","attention",",","such","as","LiAlO2","-","inlaid","LiNi0",".","5Co0",".","2Mn0",".","3O2","exhibiting","a","better","electrochemical","performance","than","the","pristine","one","[","37","]","."],"ner_tags":["O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":550,"tokens":["Charge","and","discharge","curves","at","1st",",","2nd",",","10th",",","30th",",","50th","cycle","of","0",".","5","%","LATP","modified","-","LiCoO2",".","(","b",")","Relationships","between","cycle","number","and","discharge","capacity","of","unmodified","-","LiCoO2","and","0",".","5","%","LATP","modified","-","LiCoO2","particles","for","poly","(","ethylene","oxide",")","cells","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":551,"tokens":["To","confirm","this",",","NCM",",","Al","-","O","-","2","and","Li","-","Al","-","O","-","2","were","investigated","via","CV","analysis","at","various","scan","rates","."],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":552,"tokens":["Later",",","the","same","group","reported","a","hybrid","solid","electrolyte","(","PEO10","–","(","LiN","(","CF3SO2",")","2","-","10","wt",".","%","LiPF6",")","and","10","wt",".","%","of","BaTiO3","with","improved","electrochemical","stability","range","and","enhanced","electrochemical","performance","in","Li","\/","LiNi0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":553,"tokens":["Fig",".","1",".","The","XRD","patterns","(","a",")","and","Rietveld","refinements","(","b",")","of","pristine","and","V2O5","-","coated","sample",".","This","coating","layer","was","further","examined","by","carried","out","HRTEM","characterization","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":554,"tokens":["and","its","modifications","\/","growth","with","successive","cycling","cause","capacity","fade","of","the","cell",".","Although","the","top","of","the","O","-","2p","bands","of","an","oxide","host","can","be","lowered","to","more","than","5","eV","below","μ","A","(","Li",")","by","replacing","an","oxide","ion","with","a","polyanion","as","in","LiNiPO4","(","see","Fig",".","4",")",",","investigation","of","these","high","-","voltage","cathodes","has","been","limited","because","the","organic","liquid","carbonate","electrolytes","used","in","the","LIBs","decompose","at","a","voltage","higher","than","5","V","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":555,"tokens":["5","mg","of","Ketjen","black","and","0",".","5","mg","of","Teflonized","acetylene","black","(","TAB","-","2",")",".","Cyclic","voltammetry","and","impedance","measurements","were","conducted","using","an","electrochemical","analyzer","(","SP","-","150",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":556,"tokens":["75","and","98",".","45","%",",","respectively",",","after","100","cycles",".","This","results","clearly","show","the","improvement","in","the","electro","-","chemical","performance","of","the","ALD","-","modified","Ni","-","rich","cathodes","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":557,"tokens":["Therefore",",","there","is","an","appropriate","thickness","of","ALD","coatings","for","the","ultimate","optimization","of","electrochemical","performances","of","the","electrodes",".","Meanwhile",",","the","ultrathin","coating","layer","with","amorphous","phase","would","favor","the","lithium","diffusion","due","to","its","open","structures","."],"ner_tags":["O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":558,"tokens":["Rct","corresponds","to","the","charge","transfer","resistance",",","CPE","is","the","capacitance","of","the","electrode","\/","electrolyte","double","layer",",","and","W1","represents","the","Warburg","impedance",".","Furthermore",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":559,"tokens":["The","inert","chemical","properties","of","transition","metal","phosphates","were","effective","in","preventing","side","reactions","between","the","cathode","and","the","electrolyte",".","Besides","the","above","mentioned","transition","metal","phosphates",",","Li3PO4","is","also","a","typical","phosphate","material","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":560,"tokens":["Download",":","Download","Word","document","(","4MB",")","Supplementary","data",".","Highlights","•","SnO2","is","generated","in","situ","on","the","surface","of","the","positive","electrode","LiNi0",".","5Mn1","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":561,"tokens":["and","thus","the","poor","reaction","kinetics",";","see","Figure","S8","in","the","Supporting","Information",")",".","Further",",","EELS","mapping","analysis","on","the","coating","layer","in","Figure","2e","–","h","reveals","a","concentration","-","gradient","Ti","distribution","in","the","surface","region","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":562,"tokens":["A","very","recent","work","is","using","an","interphase","Li2",".","3","-","xC0",".","7","+","xB0",".","3","-","xO3","to","coating","both","solid","electrolyte","and","cathode","particles","to","realize","an","all","-","ceramic","lithium","-","ion","battery","with","high","electrochemical","performance","."],"ner_tags":["O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":563,"tokens":["7","V","[","32","]",".","Mohanty","et","al",".","coated","NCM811","and","NCA","particles","directly","with","Al","2","O","3","and","TiO","2","using","ALD","and","studied","them","as","pouch","cells","at","different","cutoff","voltages","[","8","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":564,"tokens":["With","the","interface","engineering",",","the","in","-","situ","generated","Li3PO4","tightly","fix","Li6",".","4La3Zr1",".","4Ta0",".","6O12","on","LiNi0",".","8Co0",".","1Mn0",".","1O2",",","improving","the","compatibility","between","LiNi0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":565,"tokens":["Al","-","O","-","4",",","(","e",")","Li","-","Al","-","O","-","4",",","(","f",")","Al","-","O","-","5",",","(","g",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":566,"tokens":["at","an","elevated","temperature",",","whereas","the","pristine","electrode","exhibits","only","46",".","59","%",".","Electrochemical","results","showed","that","surface","engineering","could","significantly","mitigate","the","detrimental","side","reactions","along","the","interface","and","thereby","improve","the","stability","and","rate","performance","of","NCM811","under","both","room","-","temperature","and","elevated","-","temperature","conditions","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":567,"tokens":["Aladdin","]",",","ethyl","acetoacetate","(","EAcAc",")",",","ultrapure","water",",","and","ethanol",".","Concentrations","of","0",".","125",",","0",".","25",",","0",".","60",",","1",".","25",",","2",".","5",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":568,"tokens":["The","lower","Δ","a",",","Δ","c",",","and","Δ","V","values","of","ZrO2","ALD","-","5","imply","reduced","structure","disordering","compared","to","bare","NMC","electrode",".","Furthermore",",","cycled","ZrO2","ALD","-","5","has","a","lower","c","\/","a","ratio","of","(","5",".","08",")","than","cycled","bare","NMC","electrode","(","5",".","11",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O"]}
{"id":569,"tokens":["Thus",",","after","100","cycles","it","is","observed","that","the","specific","discharge","capacity","of","Li2CuO2","@","LNMC","at","1C","-","rate","is","∼","90","mAh","\/","g","with","∼","69","%","capacity","retention",",","while","the","same","values","of","pristine","LNMC","are","∼","29","mAh","\/","g","and","∼","30","%",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":570,"tokens":["and","type","II","coordinated","by","three","Ni","and","two","Li",".","Note","that","in","the","bulk","of","LiNiO2",",","the","lattice","oxygen","was","always","coordinated","by","three","Ni","and","three","Li","(","inset","of","Supplementary","Fig",".","30b",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":571,"tokens":["1C",".","Here","1",".","0C","is","defined","as","220","mA","g","−","1",".","To","evaluate","the","rate","capability",",","the","cells","were","charged","at","0",".","5C","and","discharged","at","rates","of","0",".","5",",","1",".","0",",","2",".","0",",","3",".","0",",","5",".","0",",","7","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":572,"tokens":["Guo","et","al",".","introduced","Li1",".","4Al0",".","4Ti1",".","6","(","PO4",")","3","on","a","cathode","and","improved","LiNi0",".","6Co0",".","2Mn0",".","2O2","\/","Ipn","-","PEA","\/","Li","SSBs","[","28","]","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":573,"tokens":["Beyond","the","traditional","polymer","and","inorganic","solid","electrolytes",",","hybrid","systems","that","integrate","multiple","ionic","conductive","and","\/","or","structural","components","might","finally","pave","the","way","towards","large","-","scale","applications","of","solid","-","state","batteries","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":574,"tokens":["This","cell","delivered","a","maximum","discharge","capacity","of","∼","166","mAh","\/","g","at","0",".","1","C","rate","within","2",".","4","–","4",".","2","V","voltage","range",",","retaining","∼","67","%","of","the","maximum","capacity","up","to","the","50th","cycle","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":575,"tokens":["The","decomposition","temperature","of","NH4H2PO4","is","as","low","as","180","°","C",",","and","the","PO43","−","anion","thus","will","readily","react","with","Li2CO3","and","LiOH","to","form","Li3PO4","as","Equation","1","-","2","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O"]}
{"id":576,"tokens":["Enchem",",","Korea",")","were","used",".","The","prepared","cathodes","NCM","were","punched","(","diameter","0","12","mm",")","and","dried","in","a","vacuum","oven","at","60","°","C","for","12","h","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":577,"tokens":["For","example",",","Niitani","et","al",".","[","98","]",",","[","99","]","reported","triblock","copolymer","based","PS","-","b","-","PPME","-","b","-","PS","-","LiClO4","(","PPME","-","poly","(","ethylene","glycol",")","methyl","ether","methacrylate",",","PS","-","polystyrene",")","solid","polymer","electrolyte","with","microphase","separation","and",",","as","result",",","high","ionic","conductivity","at","30","°","C",",","improved","mechanical","stability",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":578,"tokens":["and","(","1","0","1",")","crystal","plane","of","0",".","321","and","0",".","264","nm",",","indicating","that","SnO2","grows","on","the","surface","of","LNMO","to","form","nanoparticles","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":579,"tokens":["Safety","is","of","utmost","importance","to","the","development","of","Li","-","ion","batteries","(","LIBs",")","with","a","high","energy","density",".","(","1","−","4",")","Gas","release",",","usually","caused","by","decomposition","of","highly","delithiated","cathodes","and","formation","and","decomposition","of","the","solid","electrolyte","interphase","(","SEI",")",",","poses","a","great","threat","to","the","safety","of","batteries",",","because","it","will","lead","to","battery","swelling",",","deformation",",","thermal","runaway",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":580,"tokens":["the","obtained","powder","was","heat","-","treated","at","750","°","C","for","6","h","in","a","furnace","and","naturally","cooled","to","room","temperature",".","This","product","is","hereafter","denoted","by","LATP","-","LCOMg","."],"ner_tags":["O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O"]}
{"id":581,"tokens":["Moreover",",","this","electrolyte","was","tested","in","a","coin","cell","with","a","LiCoO2","cathode","and","a","natural","graphite","anode",",","after","activating","it","by","filling","with","1M","LiPF6","\/","PC",":","DMC","(","1",":","1",")","liquid","electrolyte","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":582,"tokens":["Within","this","system",",","nickel","-","rich","layered","LiNi0",".","6Co0",".","2Mn0",".","2O2","(","NCM",")","displays","good","Li","-","ion","diffusivity","with","minimal","temperature","dependence","[","11","]",",","as","well","as","a","higher","specific","capacity","than","both","LiNi0","."],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":583,"tokens":["Thus",",","the","effect","of","the","thin","coating","is","less","distinct","to","enhance","the","performance","of","the","electrode",".","Additionally",",","the","quasi","-","straight","line","in","the","low","frequency","region","refers","to","a","semi","-","infinite","Warburg","diffusion","process","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":584,"tokens":["and","g","(","cross","section",")",".","In","the","course","of","electrode","compression",",","secondary","particles","of","the","active","material","can","be","deformed","by","the","applied","pressure",",","leading","to","cracking","of","the","particle","perimeter","(","Figure","8d",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":585,"tokens":["Zhang","and","co","-","workers","designed","a","LLZO","incorporated","poly","(","vinylidene","fluoride","-","hexafluoropropylene",")","(","PVDF","-","HFP",")","HSSE",",","presenting","high","ionic","conductivity",",","wide","electrochemical","window",",","good","flexibility","and","high","thermal","stability","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":586,"tokens":["All","structural","models","were","entirely","relaxed","until","the","ionic","Hellmann","–","Feynman","forces","were","smaller","than","0",".","001","eV","\/","Å","and","the","energy","tolerances","were","less","than","10","−","6","eV","\/","atom","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":587,"tokens":["(","39",",","45",",","46",")","To","get","a","better","idea","of","the","impact","of","the","coating","layer","on","the","rate","capability",",","additional","studies","on","dependence","of","the","coating","amount","are","needed","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":588,"tokens":["and","plug","-","in","hybrid","electric","vehicles","(","P","-","HEVs",")","[","1","]",",","[","2","]",",","[","3","]",",","[","4","]",".","It","is","reported","LiNixM1","−","xO2","materials","inherit","the","merits","of","mono","metal","oxide","LiCoO2",",","LiNiO2","and","LiMnO2",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","B-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O"]}
{"id":589,"tokens":["Until","now",",","there","are","no","reports","about","the","effect","of","surface","modification","of","LiNiO2","-","based","materials","by","V2O5","on","electrochemical","performance","at","a","high","cutoff","voltage","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":590,"tokens":["(","27",",","65",",","66",")","Surface","modification","via","ceramic","coatings","has","proven","to","be","an","effective","method","to","stabilize","the","active","material","surface",".","Especially",",","metal","oxides","such","as","Al2O3",",","(","44",",","67",")","(","44",",","67",")","TiO2",",","(","68",")","SiO2",",","(","45",",","46",")","(","45",",","46",")","ZrO2",",","(","69",")","(","69",")"],"ner_tags":["O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O"]}
{"id":591,"tokens":["Each","step","migrating","energy","of","improved","sample","is","lower","than","the","pristine","NCM811",",","which","is","beneficial","for","the","Li","-","ion","transport","and","interface","compatibility",".","This","phenomenon","is","well","explained","by","DFT","calculation","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":592,"tokens":["The","reactive","infusion","of","oxides","by","other","TM","boride",",","phosphide","and","\/","or","silicide","metallic","glasses",",","to","produce","‘","functional","cermets","’",",","should","be","a","generic","modification","strategy","for","many","electrodes","used","in","advanced","energy","storage","and","conversion","."],"ner_tags":["O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":593,"tokens":["Such","enhanced","electrochemical","performance","of","the","coated","sample","is","ascribed","to","its","high","-","quality","ultrathin","amorphous","ALD","oxide","coating",",","which","can","protect","the","active","material","from","HF","attack",",","reduce","the","dissolution","of","metal","ions","in","the","electrode","and","favor","the","lithium","diffusion","of","the","oxide","proved","by","the","electrochemical","impedance","spectroscopy","(","EIS",")","tests","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":594,"tokens":["In","order","to","see","if","this","new","material","has","the","potential","for","industrial","use",",","prismatic","full","cells","of","2900","mA","h","were","manufactured",".","The","cathode","was","composed","of","the","active","material",",","conducting","material",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":595,"tokens":["the","synthesized","materials","had","only","a","limited","period","of","exposure","to",",","and","possible","contamination","by",",","the","ambient","air",".","Chen","and","Dahn25",",","26","reported","a","significant","impact","of","surface","chemistry","when","cathode","materials","were","stored","in","a","more","severe","condition","or","for","extended","period","of","time","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":596,"tokens":["However",",","a","serious","problem","at","high","cut","-","off","voltage","is","the","capacity","fading","during","charge","-","discharge","cycling",",","caused","by","electrolyte","decomposition","and","dissolution","of","cathode","materials","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":597,"tokens":["The","samples","were","then","washed","with","anhydrous","ethanol",",","collected","by","vacuum","filtration","and","dried","at","120","°","C","under","vacuum","overnight",".","After","stirring","for","15","min",",","40","ml","of","clear","solution","was","separated","by","vacuum","filtering","and","additional","100","ml","of","deionized","water","was","added","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":598,"tokens":["which","is","mainly","due","to","the","break","down",".","This","process","is","mainly","due","to","the","decomposition","in","the","polymer","electrolyte",".","After","170","°","C",",","the","DSC","glass","transitions","and","the","electrolyte","begins","to","decompose","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":599,"tokens":["The","Al","2","O","3","coating","can","prevent","the","detrimental","surface","reactions","at","a","high","temperature",".","Thus",",","the","morphology","of","the","active","material","is","well","-","maintained","even","after","extensive","cycling",",","whereas","the","bare","electrode","undergoes","severe","degradation","."],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":600,"tokens":["With","the","addition","of","the","compatible","LP",",","it","is","relatively","easy","for","Li","+","ions","to","migrate","from","NCM811","to","LP","and","LP","to","LLZTO","comparing","to","that","NCM811","directly","to","LLZTO",","],"ner_tags":["O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":601,"tokens":["In","a","typically","wet","-","chemical","procedure",",","e",".","g",".","sol","–","gel","method",",","nonuniform","agglomeration","exists","and","the","thick","porous","coating","species","is","observed","[","15","]","."],"ner_tags":["O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":602,"tokens":["The","exothermal","reaction","in","CoxB","–","NCM","charged","at","4",".","4","V","(","versus","Li","\/","Li","+",")","took","place","at","a","higher","temperature","of","269",".","5","°","C","with","a","lower","heat","generation","of","487","."],"ner_tags":["O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":603,"tokens":["the","demand","for","electric","vehicles","(","EVs",")","and","energy","storage","systems","(","ESSs",")","to","achieve","renewable","and","sustainable","energy","is","increasing","[","1","]",",","[","2","]",",","[","3","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":604,"tokens":["For","a","fair","comparison",",","the","different","cells","were","cycled","to","an","SOH","of","80","%",".","Nevertheless",",","it","also","has","to","be","kept","in","mind","that","the","thermal","stability","of","the","uncoated","and","coated","materials","may","change","over","charge","\/","discharge","cycling",",","i",".","e",".",",","degradation","effects","such","as","phase","changes","and","particle","cracking","can","lead","to","a","reduced","thermal","stability","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":605,"tokens":["and","the","slurry","was","evenly","pasted","onto","an","Al","current","collector",".","The","electrode","was","dried","at","100","°","C","for","12","h","under","vacuum","to","remove","the","NMP","solvent","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":606,"tokens":["With","ongoing","charge","\/","discharge","cycling",",","uncoated","and","coated","NCM","-","811","electrodes","display","an","increasing","difference","in","the","slope","of","ACIE",",","whereas","the","surface","-","coated","sample","exhibits","a","reduced","ACIE","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":607,"tokens":["at","room","temperature",".","On","the","contrary",",","the","references","for","comparison","show","poor","performances",".","The","cells","with","uncoated","-","LCOMg","undergo","a","significant","capacity","drop","at","the","early","cycles","(","up","to","∼","100","cycles",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":608,"tokens":["Even","worse",",","nanostructured","LiCoO2","suffers","from","its","poor","tap","density",",","leading","to","the","low","RLIB","energy","density",".","In","contrast",",","micron","-","sized","LiCoO2","cathode","mitigates","somewhat","the","above","-","discussed","challenges",","],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":609,"tokens":["2","to","143",".","3","mAh","g","−","1",".","The","specific","capacity","of","V2O5","-","coated","electrode","was","initially","much","higher",",","189",".","4","mAh","g","−","1","after","1","month",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":610,"tokens":["Specifically",",","metal","-","organic","frameworks","(","MOFs",")","and","covalent","organic","frameworks","(","COFs",")","with","tunable","pore","structure","and","adaptable","functional","groups","have","been","used","to","develop","HSSEs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":611,"tokens":["Although","the","Al2O3","coating","delivers","stable","electrochemical","properties","with","reduced","contact","area","between","the","active","material","and","the","electrolyte",",","with","an","increase","in","coating","content",",","the","Al2O3","-","coated","NCM","rate","capability","reveals","even","worse","than","that","observed","for","the","pristine","NCM","(","Fig",".","S3c",")","."],"ner_tags":["O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O"]}
{"id":612,"tokens":["75La3Zr1",".","75Ta0",".","25O12","(","LLZTO",")","-","LiTFSI","composite","solid","electrolyte","was","proposed","by","Zhang","[","125","]","Solid","-","state","Li","\/","LiFe0",".","2Mn0",".","8PO4","battery","demonstrated","promising","cycle","life","(","83",".","1","%","of","initial","capacity","after","80","cycles",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":613,"tokens":["The","first","discharge","capacities","for","the","Li3PO4","coated","samples","are","272",".","5","mAh","g","−","1","(","1",".","0","wt","%","Li3PO4",")","and","263",".","0","mAh","g","−","1","(","3","."],"ner_tags":["O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":614,"tokens":["The","initial","capacity","of","the","V2O5","-","coated","LiNi0",".","8Co0",".","1Mn0",".","1O2","is","171","mAh","g","−","1",",","as","compared","to","that","of","pristine","one","having","170","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":615,"tokens":["Fig",".","6",".","Rate","capability","of","the","bare","and","ZnO","-","coated","NCM","-","523","electrodes","at","25","°","C",".","The","influence","of","ALD","-","ZnO","coating","on","the","cycling","performance","of","NCM","-","523","was","also","investigated","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O"]}
{"id":616,"tokens":["and","sharp","attenuation","of","discharge","capacity","[","[","16","]",",","[","17","]",",","[","18","]","]",".","Energy","density","of","LiCoO2","at","different","cut","-","off","voltage","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O"]}
{"id":617,"tokens":["Ab","initio","calculations","and","molecular","dynamics","can","be","another","set","of","powerful","tools","to","investigate","the","impact","of","ALD","coating","on","the","kinetics","of","charge","transfer","and","mass","transfer","through","the","surface","of","cathode","materials","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":618,"tokens":["and","110","mAh","\/","g","at","0",".","2",",","0",".","5",",","1","(","0",".","8","mA","\/","cm2",")","2",",","and","3","C","discharge","rates",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":619,"tokens":["By","mixing","these","solvents",",","it","has","been","possible","to","reach","the","ionic","conductivity","in","the","range","of","5","–","10","mS","\/","cm","at","room","temperature","(","RT",")",",","with","a","range","of","thermal","stability","between","-","30","to","60","°","C","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":620,"tokens":["Of","three","reported","different","configurations","of","surface","coating",",","i",".","e",".",",","rough","coating",",","core","–","shell","structure","coating","and","ultra","-","thin","film","coating","[","34","]",","],"ner_tags":["O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":621,"tokens":["Electrochem",".","Sci",".","Technol",".",",","2019",",","10","(","2",")",",","196","-","205","Enhancement","of","Electrochemical","Activity","of","Ni","-","rich","LiNi","0",".","8","Mn","0",".","1","Co","0",".","1","O","2","by","Precisely","Controlled","Al","2","O","3","Nanocoatings","via","Atomic","Layer","Deposition","Hari","Vignesh","Ramasamy","1",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O"]}
{"id":622,"tokens":["8Co0",".","1Mn0",".","1O2",".","This","is","further","confirmed","by","Rietveld","analysis",".","The","lattice","constants","for","pristine","(","a","0","2",".","8711","Å",",","c","0","14","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":623,"tokens":["In","addition","to","the","preset","gas","mass",",","a","profile","detection","mode","that","could","record","the","fragments","with","mass","-","to","-","charge","ratios","(","m","\/","z",")","from","0","to","140","was","used","to","detect","other","fragments","during","the","violent","decomposition","process","(","Figure","S2","and","Table","S1",")",",","indicating","a","severe","internal","chain","scission","degradation","mechanism","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":624,"tokens":["which","produces","free","Li","+","to","transfer","along","the","hexagonal","channels",".","As","a","result",",","the","MOF","-","based","HSSE","delivers","a","conductivity","of","3",".","1","×","10","−","4","S","cm","−","1","at","26","°","C","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":625,"tokens":["The","weaker","surface","potential","is","helpful","for","the","interface","compatibility","and","electrochemical","performance",".","Atomic","force","microscopy","(","AFM",")","results","of","the","interfacial","potential","images","of","(","a",")",",","(","b",")","NCM811","and","(","d",")",",","(","e",")","NCM811","-","LP","-","LLZTO","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":626,"tokens":["Schematic","diagrams","of","solid","Li","-","metal","battery","with","solid","polymer","electrolytes","(","e1","and","e2",")",",","inorganic","ceramic","electrolytes","(","e3",")","and","hybrid","polymer","-","inorganic","solid","state","electrolytes","(","HSSEs",")","(","e4",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":627,"tokens":["the","controllable","and","ultra","-","thin","LiAlO2","coating","can","be","more","effective","in","improving","the","cycling","stability","and","rate","capability","of","the","NCM","cathodes",".","Therefore",",","this","work","demonstrates","that","the","utilization","of","lithium","-","ion","conducting","films","provides","avenues","of","opportunity","for","building","high","performance","cathode","materials","for","LIBs","."],"ner_tags":["O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O"]}
{"id":628,"tokens":["In","2014",",","hybrid","microporous","gel","polymer","electrolytes","based","on","PVdF","\/","polyurethane","lithium","salt","(","PLS",")","were","prepared","by","Xing","et","al",".","[","38","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":629,"tokens":["After","that",",","a","series","of","compositions","of","Li1","+","xAlxTi2","-","x","(","PO4",")","3","(","abbreviated","as","LATP",")","has","been","developed","with","various","x","with","the","amorphous","structure","aiming","at","high","Lithium","-","ionic","conductivity","and","good","process","capability","as","well","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":630,"tokens":["It","is","worth","noting","that","the","dissolution","of","LiCoO2","into","the","electrolyte","can","be","controlled","by","surface","chemical","reaction","[","69","]",".","In","this","study",",","three","types","of","metal","oxide","layers","were","coated","on","LiCoO2","electrode",","],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O"]}
{"id":631,"tokens":["Various","metal","oxides","(","TiO2",",","ZrO2","and","Al2O3",")","were","directly","coated","on","the","LiCoO2","electrode","in","an","ALD","reactor","(","Savannah","100",",","Cambridge","Nanotechnology","Inc",".",",","USA",")","."],"ner_tags":["O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":632,"tokens":["5Co0",".","2Mn0",".","3O2","[","4","]",",","better","than","91","%","of","the","LiAlO2","-","coated","LiNi0",".","5Co0",".","2Mn0",".","3O2","[","37","]","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O"]}
{"id":633,"tokens":["which","demonstrates","its","effectiveness","on","the","enhancement","of","the","high","-","voltage","cycle","and","thermal","stability","of","LiCoO2",".","We","discover","that","LiCoO2","can","react","with","LATP","at","700","°","C","to","form","exclusively","the","spinel","phases","(","Co3O4",",","CoAl2O4",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":634,"tokens":["which","is","reflected","by","the","strong","improvement","of","the","capacity","retention",".","Another","important","aspect","is","the","effect","of","the","tungsten","oxide","coating","on","the","overall","impedance","of","the","cell",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":635,"tokens":["(","e",")","1C","(","55","°","C",")",",","and","(","f",")","1C","(","80","°","C",")",".","S4b","depicts","the","1st",",","2nd",",","3rd",",","50th","and","100th","charge","\/","discharge","curves","of","the","garnet","-","type","NCM811","-","LP","-","LLZTO","\/","LLZTO","\/","Li","SSBs","at","current","densities","of","40","and","200","mA","g","−","1",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":636,"tokens":["the","magnitude","of","parasitic","reactions","was","monitored","by","measuring","the","Coulombic","efficiency","(","CE",")","of","the","battery",".","The","CE","is","defined","as","CE","0","capacity","of","discharge","\/","capacity","of","charge","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":637,"tokens":["No",".","BA2013142","and","the","Talent","Program","of","Nanjing","University","of","Aeronautics","and","Astronautics","(","NUAA",")","(","2012",")",".","We","would","like","to","acknowledge","them","for","the","financial","support","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":638,"tokens":["1","mV","s","−","1","and","a","potential","range","of","2",".","7","–","4",".","5","V","(","vs",".","Li","\/","Li","+",")",".","Electrochemical","impedance","spectroscopy","(","EIS",")","was","conducted","on","a","Princeton","Applied","Research","VersaSTAT","4","electrochemical","workstation",",","using","2","-","electrode","cells","(","amplitude","voltage","is","5","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":639,"tokens":["Co",".",",","Tokyo",",","Japan",")","at","200","kV",",","which","is","equipped","with","a","spherical","aberration","corrector","(","CEOS","Gmbh",",","Heidelberg",",","Germany",")",".","The","elemental","distribution","of","the","materials","was","characterized","by","the","energy","dispersive","spectrometer","(","EDS",",","EDAX",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":640,"tokens":["The","electrode","voltage","was","swept","from","0","to","6",".","0","V","at","a","scan","rate","of","1",".","0","mV","s","−","1",".","The","assembled","2032","-","type","coin","cells","(","NCM","\/","Li","metal",")","were","aged","for","12","h","and","precycled","using","a","formation","step","and","stabilization","step","in","the","voltage","range","from","3","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":641,"tokens":["and","quasi","-","solid","(","0",".","22","<","ILs",":","TiO2","molar","ratio","<","0",".","55",")","TiO2","-","ILs","HSSEs","give","conductivities","of","9","×","10","−","4","and","3","×","10","−","3","S","cm","−","1","at","100","°","C",",","respectively","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":642,"tokens":["Compared","to","uncoated","-","LCOMg","(","167",".","6","mA","h","g","–","1",")",",","LATP","-","LCOMg","exhibits","a","significantly","improved","discharge","capacity","at","the","first","cycle","(","185","."],"ner_tags":["O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":643,"tokens":["Surface","modified","LiCoO2","was","prepared","by","a","solution","-","based","synthesis","method",".","LiCoO2","particles","was","introduced","into","LATP","aqueous","sol","with","the","loading","of","0",".","2","wt","%",",","0","."],"ner_tags":["O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":644,"tokens":["Fig",".","4e",")","even","at","the","surface","of","the","secondary","particles","and","much","less","Ni","reduction","and","oxygen","defects","(","Fig",".","4f",")",".","The","suppressed","surface","cation","reduction",",","cation","densification","and","surface","phase","transformation","apparently","benefit","from","CoxB","infusion",",","as","the","morphology","and","chemistry","remained","unchanged","at","both","surfaces","and","GBs",",","confirmed","by","TEM","(","Supplementary","Figs",".","23b",",","24","and","25a",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":645,"tokens":["which","is","in","good","agreement","with","the","references","[","54","]",",","[","55","]",".","The","results","in","Fig",".","4a","–","c","clearly","reveal","that","the","ALD","technique","is","capable","of","depositing","ultra","-","thin","metal","oxide","coating","layers","to","completely","cover","LiCoO2","cathode",";","moreover",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O"]}
{"id":646,"tokens":["1Co0",".","1O2","(","NMC","-","811",")","cycled","at","2",".","75","–","4",".","50","V","vs","Li","+","\/","Li",".","The","high","Ni","content","layered","lithium","transition","-","metal","oxides","have","attracted","great","interest",",","owing","to","their","high","capacity","and","low","cost","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":647,"tokens":["and","the","discharge","capacities","still","remained","about","117",".","5","mAh","g","−","1","(","55","°","C",",","1C",")","and","115",".","2","mAh","g","−","1","(","80","°","C",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":648,"tokens":["It","is","interesting","to","observe","the","domain","walls","in","the","microstructure","of","Li","-","rich","and","Li","-","poor","LLTO","materials","with","the","high","resolution","TEM","images",",","and","the","correspondingly","random","or","highly","disordered","structure","near","the","domain","wall","in","the","Li","-","poor","sample","Fig",".","12","(","b",")","[","169","]","is","ascribed","to","a","high","lattice","strain","developed","in","the","Li","-","rich","LLTO","sample",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":649,"tokens":["Generally","speaking",",","the","inorganic","part","of","hybrid","electrolytes","can","be","represented","by","two","types","of","fillers",":","inert","and","lithium","conductive","ones",".","A","multitude","of","inactive","fillers","were","reported","for","low","voltage","systems","(","e",".","g","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":650,"tokens":["5","V","cutoff",")",".","Nyquist","plots","for","the","unit","cells","after","(","a",")","precycling","and","(","c",")","cycling","at","a","cutoff","condition","of","4",".","3","V","(","25","°","C",")",",","relevant","to","Fig",".","5a","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":651,"tokens":["Thus",",","the","surface","modification","technique","proposed","herein",",","which","involves","ultrathin","layer","coating","via","atomic","layer","deposition","on","the","prepared","electrode",",","has","a","promising","application","in","high","-","voltage","lithium","ion","batteries","."],"ner_tags":["O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":652,"tokens":["As","shown","above",",","the","Li","impurity","such","as","Li2O","will","accelerate","these","reactions","for","pristine","material",".","Another","salient","feature","of","this","technique","is","that","it","can","be","performed","at","very","low","temperatures","(","less","than","300","o","C","and","even","room","temperature",")","on","complex","structures","and","three","-","dimensional","substrates","[","27","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":653,"tokens":["(","31","-","33",")","Last","but","not","the","least",",","the","interfacial","layer","needs","to","be","uniform","across","the","large","high","surface","area","of","the","electrode",".","While","solution","-","phase","coating","methods","on","individual","particles","of","cathode","materials","hold","the","advantages","of","being","cost","-","effective","and","easy","integration","for","large","scale","production",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":654,"tokens":["18Co0",".","15Ni0",".","15Mn0",".","52O2",".","However",",","the","interplanar","distance","increases","to","0",".","493","nm","(","for","the","1",".","0","wt","%","coated","sample",")"],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":655,"tokens":["In","addition",",","hybridized","forms","are","investigated","i",".","e",".","lithium","difluoro","(","oxalate",")","borate","(","LiDBOB",")",".","One","of","the","latest","approaches","were","observed","in","implementing","imides","salts","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":656,"tokens":["The","stability","of","the","positive","electrode","-","electrolyte","interface","is","still","the","main","bottleneck","to","develop","high","voltage","cells",".","Moreover",",","important","research","efforts","are","devoted","to","the","substitution","of","graphite","anodes","with","Li","metal",":","this","would","improve","the","energy","density","of","the","cell","dramatically","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":657,"tokens":["The","measurement","of","lithium","ion","conductivity","in","the","liquid","cell","setup","has","been","reported","previously",".","(","29",",","41",")","The","equivalent","circuit","consists","of","two","parallel","R","\/","CPE","at","both","high","(","CPESE","\/","RSE",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":658,"tokens":["and","Al2O3",",","respectively",".","As","it","is","shown",",","three","types","of","metal","oxide","coatings","significantly","affect","the","energy","capacities","and","the","cycling","performance","of","LiCoO2","cathode",":","(","1",")"],"ner_tags":["O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O"]}
{"id":659,"tokens":["Inc",".",",",")","with","a","Solartron","1260","impedance","gain","phase","analyzer",".","The","cells","were","cycled","in","a","voltage","range","of","2",".","5","–","4",".","3","V","and","a","constant","current","rate","of","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":660,"tokens":["Ni",",","Mn",")","bonds",",","respectively",".","There","is","an","additional","peak","at","868","cm","−","1","for","the","pristine","sample","which","is","attributed","to","the","Li2CO3","impurity","in","the","material","[","26","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":661,"tokens":["52","and","were","dissolved","in","de","-","ionized","water","with","vigorous","stirring",".","After","stirring","at","50","°","C","for","15","h",",","the","viscous","solution","was","dried","at","120","°","C","in","a","vacuum","oven","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":662,"tokens":["And","it","could","prevent","the","active","material","from","the","metallic","dissolution","and","HF","attack",",","and","improve","the","structural","stability","at","high","voltage",".","In","addition",",","the","ultrathin","coating","layer","does","not","block","lithium","ion","diffusion","into","the","cathode","particles","during","the","charge","–","discharge","process","."],"ner_tags":["O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":663,"tokens":["Both","observations","above","suggest","a","suppressed","CEI","growth","in","CoxB","–","NCM","(","Fig",".","4j",",","k",")",".","Third",",","by","in","situ","differential","electrochemical","mass","spectrometry","(","DEMS",")","measurements","(","Fig",".","4l",")",",","we","found","much","less","gas","evolution","(","CO2","and","O2",")","during","the","first","charge","cycle","of","CoxB","–","NCM","than","during","that","of","pristine","NCM","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","O"]}
{"id":664,"tokens":["and","Al2O3","is","3",".","18",",","5",".","80",",","and","9",".","00","eV",",","respectively","[","37","]",",","[","70","]",".","Therefore",",","the","Al2O3","coating","provides","the","best","cycling","stability",",","while","the","worst","for","the","TiO2","coating","."],"ner_tags":["O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":665,"tokens":["2C","rate",".","The","morphology","of","the","modified","-","LiCoO2","was","investigated","by","scanning","electron","microscope","(","SEM",")","and","transmission","electron","microscope","(","TEM",")",".","Dissolution","of","the","transition","metal","(","Co3","+",")","was","analyzed","by","X","-","ray","photoelectron","spectroscopy","(","XPS",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":666,"tokens":["Therefore",",","some","cutting","edge","surface","sensitive","characterization","techniques","like","soft","X","-","ray","absorption","spectroscopy","(","XAS",")","and","high","resolution","transmission","electron","microscope","(","HRTEM",")","and","electron","diffraction","can","be","critical","in","understanding","the","specific","structure","-","property","relationship","of","coating","materials","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O"]}
{"id":667,"tokens":["(","41",")","LiPF6","is","unstable","when","operating","at","high","voltage","with","water","molecules",".","The","amount","of","Li2O","\/","LiOH","residues","substantially","decreased","after","(","NH4",")","2HPO4","modification","as","eq","1","shows",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O"]}
{"id":668,"tokens":["The","reaction","temperature","and","pH","were","maintained","at","55","°","C","and","11",",","respectively",",","under","vigorous","stirring",",","and","the","reaction","time","was","12","h",".","The","dehydrated","[","Ni0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":669,"tokens":["8Co0",".","1Mn0",".","1O2","in","air",".","A","TEM","micrograph","of","fresh","LiNi0",".","8Co0",".","1Mn0",".","1O2","powder","(","Fig",".","2","(","a",")",")","shows","good","crystallinity","at","the","edges","of","the","grains","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":670,"tokens":["Therefore",",","the","suppressed","TM","dissolution","by","our","coating","conveyed","an","additional","benefit","by","removing","the","crossover","effect","on","the","LMA","and","improved","the","full","-","cell","cycling","stability","(","Supplementary","Fig",".","29",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":671,"tokens":["Recent","studies","have","shown","that","Li3PO4","coating","could","improve","the","cyclability","and","rate","capability","of","some","cathode","materials","such","as","LiCoO2",",","Li","(","Ni0",".","6Co0",".","2Mn0",".","2",")","O2",",","LiFePO4","and","LiNi0","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","B-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":672,"tokens":["and","so","on",".","(","10",")","Then",",","conductive","polymer","material","was","used","for","a","secondary","coating","in","order","to","further","improve","the","electrical","conductivity","of","the","cathode","materials","and","make","up","for","the","coating","defects","of","the","Li3PO4","coating","layer","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O"]}
{"id":673,"tokens":["which","showed","a","drastic","swelling",",","followed","by","violent","combustion","when","the","nail","penetrated","into","the","pouch",".","Lastly",",","Ma","[","54","]","studied","a","cross","-","linked","GPE","based","on","in","-","situ","generated","poly","(","acrylic","anhydride","-","2","-","methyl","-","acrylic","acid","-","2","-","oxirane","-","ethyl","ester","-","methyl","methacrylate",")","(","PAMM",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":674,"tokens":["and","(","iii",")","Al2O3",";","(","b",")","Ti",",","(","c",")","Zr",",","and","(","d",")","Al","K","edge","structure","in","TiO2",",","ZrO2",","],"ner_tags":["O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O"]}
{"id":675,"tokens":["They","demonstrated","that","the","electrochemical","performance","of","PVdF","-","HFP","based","electrolyte","improved","by","blending","the","strong","polar","carbonyl","groups","of","PPC","into","the","PVdF","-","HFP","polymer","matrix","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":676,"tokens":["0","and","4",".","4","V","versus","Li","\/","Li","+","at","25","°","C",",","pristine","NCM","and","CoxB","–","NCM","showed","similar","charge","–","discharge","curves",",","a","discharge","capacity","around","215","mAh","g","−","1","and","first","-","cycle","Coulombic","efficiency","around","91",".","5","%",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":677,"tokens":["As","confirmed","by","the","Fourier","transform","infrared","spectroscopy",",","redshift","of","symmetric","stretching","vibration","of","C","0","O","and","blueshift","of","stretching","vibration","of","C","-","O","-","C","(","Figure","5","d",")","suggest","a","strong","interaction","between","Li","+","and","the","functional","group","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":678,"tokens":["This","HPPC","pulse","profile","was","repeated","at","every","10","%","increment","of","the","state","-","of","-","charge","(","SOC",")","between","the","full","charge","and","full","discharge","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":679,"tokens":["The","AC","impedance","of","the","unit","cells","was","investigated","using","a","VSP","impedance","analyzer","(","Bio","-","Logic","SAS",",","France",")","in","the","frequency","range","from","1","MHz","to","50","mHz","at","an","amplitude","of","10","mV","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":680,"tokens":["Complete","lithium","-","ion","cells","were","assembled","using","nanostructured","Sn","–","C","composite","anode",",","LiNi0",".","5Mn1",".","5O4","cathode","and","EGPE","-","PVdF","-","CTFE","electrolyte","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":681,"tokens":["Sigma","-","Aldrich",",","99",".","99","%","trace","metals","basis","in","isopropanol","(","EMSURE","ACS",")","and","heated","to","50","°","C","for","12","h",".","The","dispersion","was","dried","at","130","°","C","to","remove","the","isopropanol","and","annealed","for","12","h","at","450","°","C","in","an","argon","atmosphere","to","obtain","the","tungsten","oxide","coating","layer","at","the","surface","of","NCM","-","811","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":682,"tokens":["3","Meanwhile",",","alternative","lithium","battery","systems",",","including","Li","–","S","and","Li","–","O2",",","have","been","under","active","exploration","as","new","generation","energy","storage","systems","with","much","higher","energy","density","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":683,"tokens":["Yet",",","this","is","no","less","important","that","diffusion","of","lithium","-","ions","in","solid","-","state","battery","positive","electrodes",",","especially","in","high","-","area","-","density","solid","-","state","positive","electrodes","with","practical","application","significance","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":684,"tokens":["We","chose","a","Ni","-","rich","layered","cathode","LiNi0",".","8Co0",".","1Mn0",".","1O2","(","NCM",")","of","great","industrial","interest","as","a","model","system","to","demonstrate","our","coating","strategy","."],"ner_tags":["O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":685,"tokens":["National","Natural","Science","Foundation","of","China","(","No",".","51472104",",","21473075",",","51272088",")",",","the","Defense","Industrial","Technology","Development","Program","(","No",".","B1420133045",")",",","and","Graduate","Innovation","Fund","of","Jilin","University","(","Project","No",".","2014042",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":686,"tokens":["Indeed",",","depending","on","the","contents","of","polymer","and","inorganic","in","the","composites",",","the","HSSEs","would","be","transformed","from","“","ceramic","-","in","-","polymer","”","to","“","polymer","-","in","-","ceramic","”","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":687,"tokens":["Fig",".","9","presents","the","cyclic","performance","of","the","bare","and","ZrO2","-","coated","electrodes","subjected","to","a","high","current","density","of","1000","mA","g","−","1","(","5C",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":688,"tokens":["3","mAh","\/","g",",","which","retained","only","65",".","8","%","after","200","cycles",".","The","poor","cycling","properties","of","the","bare","sample","might","be","due","to","its","high","surface","reactivity","with","electrolyte","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":689,"tokens":["which","were","assembled","inside","a","glovebox","filled","with","ultrapure","Ar",",","in","which","the","O","2","and","H","2","O","levels","were","maintained","below","1","ppm",".","Commercial","NCM811","(","Ecopro",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O"]}
{"id":690,"tokens":["5Co0",".","2Mn0",".","3O2","with","precise","thickness","-","control","at","atomic","scale",".","The","coated","cathode","material","with","8","ALD","cycles","exhibits","the","significantly","improved","discharge","capacity","and","cycleability",",","as","compared","with","those","of","the","bare","one","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":691,"tokens":["which","implies","the","possible","applications","of","solid","-","state","batteries","at","low","temperature",".","The","solid","Li4Ti5O12","\/","BAIE","\/","Li","cell","demonstrates","a","high","capacity","of","110","mAh","g","−","1","at","5","C","at","80","°","C","for","3000","cycles","with","Coulombic","efficiencies","of",">","99",".","8","%","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":692,"tokens":["The","measured","lithium","ion","conductivity","of","ALD","LiAlF4","is","4","orders","of","magnitude","higher","than","that","of","LiF","or","AlF3","reported","in","the","literature",".","(","30",")","For","comparison","purposes",","],"ner_tags":["O","O","O","O","O","O","B-COATING_METHOD","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":693,"tokens":["Co","2p","(","h",")",",","Ni","2p","(","i",")","and","Mn","2p","(","i",")","for","CoxB","–","NCM",".","k","–","n",",","XPS","spectra","of","B","1s","(","k",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":694,"tokens":["and","then","calcined","at","850","°","C","for","12","h","in","air","to","obtain","the","spherical","LiNi0",".","5Co0",".","2Mn0",".","3O2","powders",",","marked","as","NCM","-","523","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O"]}
{"id":695,"tokens":["The","results","indicate","that","in","the","crystal","lattice",",","Mn","is","mainly","in","+","4","valence","state","[","16","]",",","[","39","]",".","This","is","consistent","with","the","results","in","Fig",".","2e","[","40","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":696,"tokens":["Later",",","Golapan","et","al",".","[","37","]","synthesized","PVdF","-","PAN","electrospun","fibrous","membranes",",","converted","them","into","GPEs","by","soaking","in","1M","LiClO4","-","PC","solution","and","tested","them","in","LiCoO2","\/","GPE","\/","Li","cells","at","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":697,"tokens":["The","results","show","that","unexpected","H2","release","was","detected","in","a","LiCoO2","|","PEO","-","LiTFSI","|","Li","cell","when","it","was","cycled","between","4",".","2","and","3","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":698,"tokens":["1","and","66",".","5","mAh","\/","g",",","respectively",".","More","recently",",","the","same","research","group","[","46","]","reported","a","cellulose","-","supported","poly","(","methyl","vinyl","ether","-","alt","-","maleic","anhydride",")","(","P","(","MVE","-","MA",")",")","based","GPE","(","abbreviated","as","PMM","-","CPE",")",",","with","a","wide","electrochemical","window","(",">","5","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":699,"tokens":["In","this","context",",","Kim","and","Sun","[","44","]","reported","the","synthesis","of","acrylonitrile","-","methyl","methacrylate","-","styrene","(","AMS",")","terpolymers","and","the","preparation","of","AMS","-","based","gel","polymer","electrolytes","using","binary","plasticizing","solvents","consisting","of","EC","\/","DMC","(","1",":","1",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":700,"tokens":["Based","on","obtained","results",",","further","improvement","will","be","expected","when","these","three","coating","layers","are","deposited","onto","nano","-","sized","LiCoO2",".","Fig",".","8",".","Rate","capability","of","LiCoO2","electrodes","coated","by","metal","oxides","with","different","ALD","cycles","(","0",",","2",",","5",",","10",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-COATING_METHOD","O","O","O","O","O","O","O","O","O","O"]}
{"id":701,"tokens":["8Co0",".","1Mn0",".","1O2","-","Li3PO4","-","Li6",".","4La3Zr1",".","4Ta0",".","6O12","(","NCM811","-","LP","-","LLZTO",")","as","an","active","material",".","First",",","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":702,"tokens":["With","the","increase","of","the","loading","amount","of","the","LATP",",","the","surface","coverage","increases","and","a","uniform","and","relatively","dense","membrane","-","like","coating","layer","can","be","formed","when","the","content","of","LATP","exceeds","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":703,"tokens":["6","V",".","Figure","3a",",","b","shows","the","selected","galvanostatic","charge","\/","discharge","profiles","of","bare","-","LCO","and","LATP","@","LCO","-","700","for","the","1st","and","the","50th","cycle",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":704,"tokens":["Thus",",","battery","performance","is","generally","improved","in","terms","of","operating","temperature",",","C","-","rate","capability","and","cyclability","in","comparison","with","SPEs",".","Moreover",",","these","materials","may","be","used","in","a","combination","with","high","voltage","cathode","materials",",","due","to","their","wider","electrochemical","stability","window","comparing","to","competitors","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":705,"tokens":["This","material","showed","high","ionic","conductivity","(","3",".","7","mS","\/","cm","at","room","temperature",")",",","lithium","-","ion","transference","number","(","0",".","44",")","as","well","as","electrochemical","stability","window","vs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":706,"tokens":["2","indicate","the","well","-","ordered","α","-","NaFeO2","structure","with","the","limited","cation","mixing","for","both","bare","and","coated","samples","[","4","]",",","[","23","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":707,"tokens":["O2","nanoplates","using","the","hydrothermal","method",".","Both","cation","doping","and","anion","doping","aim","to","stabilize","the","crystal","structure","or","increase","the","electronic","conductivity","of","the","material","thus","enhances","the","electrochemical","performance","of","Li","-","excess","layered","oxides","to","some","extent","."],"ner_tags":["I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O"]}
{"id":708,"tokens":["The","Co","2p","XPS","signal","can","be","found","on","Li","anodes","coupled","with","bare","and","0",".","2","wt","%","LATP","coated","LiCoO2",",","while","it","is","almost","absent","on","Li","anodes","from","cells","with","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":709,"tokens":["Although","the","interfacial","resistance","could","be","reduced","by","introducing","a","small","amount","of","liquid","electrolyte","or","applying","specific","surface","coating",",","unwanted","side","reactions","might","still","occur","at","the","interphase","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":710,"tokens":["The","material","shows","three","broad","peaks","in","the","following","reduction","process",".","The","oxygen","loss","and","structure","transformation","could","be","retarded","by","this","severe","structure","distortion",".","Assuming","all","the","battery","cells","are","assembled","by","the","same","procedure",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":711,"tokens":["In","comparison",",","Shang","et","al",".","recently","demonstrated","tungsten","doping","for","NCM","-","811",",","causing","a","significant","extension","appearing","in","the","lattice","parameters","due","to","the","higher","ionic","radius","of","W6","+","(","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":712,"tokens":["2","V",".","The","surface","coating","of","LiCoO2","with","a","stable","solid","electrolyte","Li1",".","4Al0",".","4Ti1",".","6","(","PO4",")","3","(","LATP",")","can","mitigate","such","a","surface","catalytic","effect","and","therefore","extend","the","stable","working","voltage","to",">","4","."],"ner_tags":["O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":713,"tokens":["Their","rate","capability","is","shown","in","Fig",".","5d",".","During","the","current","density","increase","from","100","to","700","mA","g","−","1",",","the","coated","electrode","always","shows","much","higher","energy","capacities","than","the","coated","powder","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":714,"tokens":["The","NMC532","electrodes",",","which","were","coated","by","ZrO2","after","5","and","20","ALD","cycles",",","are","denoted","as","ZrO2","ALD","-","5","and","ZrO2","ALD","-","20",",","respectively","."],"ner_tags":["O","B-CATHODE_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","B-COATING_METHOD","O","O","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","B-COATING_MATERIAL","B-COATING_METHOD","O","O","O","O","O"]}
{"id":715,"tokens":["212","V","corresponding","to","the","hexagonal","-","monoclinic","phase","transition","can","be","obviously","observed","when","the","cathode","is","charged","beyond","4",".","2","V",",","which","is","good","agreement","with","the","references","[","71","]",",","[","72","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":716,"tokens":["To","the","best","of","our","knowledge",",","few","reports","focus","on","the","effect","of","LiAlO2","coatings","on","LiNi0",".","6Co0",".","2Mn0",".","2O2","cathode","materials","at","high","cutoff","voltages","of","4",".","5","\/","4","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":717,"tokens":["Cell","Operation",":","-","Lower","operating","temperature",".","-","Lower","charge","cut","-","off",".","Lower","operating","temperature",".","Lower","charge","cut","-","off",".","Finally",",","although","authors","mostly","discussed","existing","technical","challenges","and","opportunities","in","this","thematic","review",",","it","will","be","equally","important","to","put","more","focused","effort","on","sustainable","materials","and","production","technology","in","the","frame","of","the","modern","concepts","of","circular","economy","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":718,"tokens":["In","this","context",",","it","is","critical","to","mitigate","the","capacity","fading","of","LiCoO2","in","order","to","satisfy","RLIB","application",".","The","charge","–","discharge","cycling","of","RLIB","cathodes","is","highly","related","with","their","surface","chemistry","[","27","]",",","thus","surface","modification","via","coating","was","demonstrated","being","an","effective","strategy","to","decrease","the","cathode","dissolution","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","I-COATING_METHOD","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O"]}
{"id":719,"tokens":["Moreover",",","the","influence","of","bias","on","the","Li","ionic","conductivity","at","the","grain","boundaries","of","LATP","glass","-","ceramic","powders","was","also","investigated",",","which","showed","that","a","periodic","energy","barrier","exists","at","the","grain","boundaries","of","LATP","samples",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":720,"tokens":["The","top","of","the","O","-","2p","bands","of","the","layered","oxides","LiMO2","is","∼","4",".","0","eV","below","μ","A","(","Li",")",",","which","is","why","oxide","hosts","are","used","as","cathodes","of","present","-","day","LIBs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":721,"tokens":["As","expected",",","coated","LiCoO2","electrode","shows","higher","capacity","retention","than","the","pristine","one",".","Oppositely",",","coated","LiCoO2","powder","shows","poorer","cycling","performance","than","the","pristine","one","."],"ner_tags":["O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O"]}
{"id":722,"tokens":["Meanwhile",",","strong","Co","2p","and","B","1s","signals","were","observed","in","cycled","CoxB","–","NCM",",","which","indicates","the","CoxB","surface","coating","was","not","covered","by","thick","CEIs",",","even","after","prolonged","cycling","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-CATHODE_MATERIAL","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":723,"tokens":["Both","Li2CO3","and","LiOH","impurities","formed","on","the","cathode","'","s","surface","will","worsen","its","machining","performance","and","electrochemical","performance",".","One","practicable","way","to","solve","the","rapid","moisture","uptaking","problem","of","LiNiO2","-","based","cathode","materials","may","coat","their","surfaces","with","nano","-","scale","layers","of","lithium","-","reactive","material","such","as","Co3","(","PO4",")","2","[","14","]",",","[","15","]","."],"ner_tags":["O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O"]}
{"id":724,"tokens":["After","100","cycles",",","it","drops","to","105","mAh","·","g","−","1",",","with","a","capacity","decay","rate","of","94",".","2","%",",","and","the","initial","specific","capacity","at","a","rate","of","0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":725,"tokens":["With","increasing","ALD","cycles",",","the","cathodes","exhibit","higher","Δ","V",".","However",",","ZrO2","and","Al2O3","coatings","exhibit","higher","Δ","V","with","all","ALD","cycles",".","In","contrast",","],"ner_tags":["O","O","B-COATING_METHOD","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","B-COATING_METHOD","O","O","O","O","O"]}
{"id":726,"tokens":["No",".","M25018",";","“","Priority","Academic","Program","Development","of","Jiangsu","Higher","Education","Institutions","(","PAPD",")","”",",","“","the","special","fund","of","the","scientific","and","technological","achievements","transformation","project","in","Jiangsu","province","”",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":727,"tokens":["Very","recently",",","Jiang","and","co","-","workers","reported","polyelectrolyte","COFs","by","integrating","flexible","oligo","(","ethylene","oxide",")","chains","onto","the","pore","walls",".","71","Compared","with","bare","COFs","without","polymer","chains",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":728,"tokens":["Insets","of","panel","c",":","fast","Fourier","transform","patterns","showing","crystalline","NCM","(","bottom","left",")","and","amorphous","CoxB","(","top","right",")",".","e",",","EDS","mapping","of","site","A","in","d",".","f",",","EDS","mapping","of","site","B","in","d","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":729,"tokens":["and","electrochemical","window","up","to","4",".","8","V","(","vs",".","The","Li","\/","LiFe0",".","2Mn0",".","8PO4","cell","with","the","blending","GPE","delivered","a","high","discharge","capacity","of","162",".","3",",","155","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":730,"tokens":["which","is","very","unfavorable","for","Li","-","ion","transport","across","the","cathode","\/","electrolyte","interface","region","in","NCM811","SSBs","(","Fig",".","3a",")",".","It","is","hard","to","jump","from","a","lower","surface","energy","crystal","face","to","a","higher","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":731,"tokens":["In","this","paper",",","SnO2","is","grown","in","situ","on","LiNi0",".","5Mn1",".","5O4","(","LNMO",")","to","increase","the","specific","capacity","and","stabilize","the","cycle","performance","."],"ner_tags":["O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":732,"tokens":["Acknowledgements","Y",".","W",".",",","Q",".","Z",".",",","and","Z",".","X",".","contributed","equally","to","this","work",".","The","work","was","supported","by","funding","from","the","National","Key","R","&","D","Program","of","China","(","2016YFB0100100",")",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":733,"tokens":["Thirdly",",","SSEs","possessing","improved","(","electro",")","chemical","and","thermal","stabilities","suggest","wide","potential","window",",","improved","interphase","with","electrodes",",","and","higher","working","temperature",".","6","The","most","widely","studied","SSEs","can","be","generally","divided","into","two","categories",":","polymers","and","inorganic","ceramics","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":734,"tokens":["In","addition",",","PEO","\/","LLZTO","HSSE","containing","nano","-","size","LLZTO","particles","displayed","conductivity","nearly","two","orders","of","magnitude","higher","than","those","with","micro","-","size","ones",",","signifying","the","importance","of","microscopic","structure","and","interphase","in","the","HSSEs","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":735,"tokens":["and","pristine","NCM","(","bottom",")","after","200","cycles","under","a","7C","discharge","rate","at","45","°","C",".","For","the","atomistic","details",",","first","-","principles","calculations","were","conducted","on","the","(","104",")","surface","of","LiNiO2","and","on","the","interface","between","the","LiNiO2","(","104",")","surface","and","amorphous","CoxB","."],"ner_tags":["O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","B-COATING_MATERIAL","O"]}
{"id":736,"tokens":["Co",",","and","Mn",")","nanobelts","exhibited","very","good","rate","capability","and","cycling","property",".","In","addition",",","based","on","the","fact","that","Li4Ti5O12","does","not","suffer","from","significant","volume","change","during","lithium","cycling",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":737,"tokens":["Using","the","relationship","between","the","peak","current","(","Ip",")","versus","the","CV","scan","rate","(","ν","1","\/","2",")",",","the","lithium","-","ion","diffusion","coefficient","(","cm2","s","−","1",")","of","NMC532","electrodes","with","and","without","ZrO2","can","be","computed","according","to","the","following","equation","[","32","]",":","(","8",")","where","n","is","the","number","of","electrons","in","a","specific","electrochemical","reaction",","],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":738,"tokens":["In","this","light","it","is","important","to","note","that","there","are","many","published","reports","about","extended","anodic","stability","range","up","to","5","V","vs",".","Li","\/","Li","+","lithium","reference","electrode","(","LRE",")","of","several","advanced","PEO","-","LiTFSI","based","solid","polymer","electrolytes",",","however",",","showing","electrochemical","performance","in","solid","-","state","cells","with","LFP","cathodes","only","[","70","]",",","[","71","]",",","[","72","]",",","[","73","]",",","[","74","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":739,"tokens":["The","former","might","integrate","polymer","and","inorganic","electrolytes",",","while","the","latter","typically","consists","of","liquid","electrolytes","encapsulated","in","robust","porous","hosts",".","10","To","date",",","a","variety","of","HSSEs","with","different","compositions","and","micro","-","\/","nanostructures","have","been","reported","(","Figure","1","b",")","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":740,"tokens":["Obviously",",","the","electrochemical","performance","of","ALD","-","coated","LiCoO2","electrode","strongly","depends","on","the","type","of","coating","materials","that","the","Al2O3","coating","shows","the","best","cycling","stability","while","the","ZrO2","coating","is","capable","of","obtaining","the","best","rate","capability","."],"ner_tags":["O","O","O","O","O","O","B-COATING_METHOD","O","O","B-CATHODE_MATERIAL","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O"]}
{"id":741,"tokens":["3","V","and","3",".","0","–","4",".","5","V","in","the","CC","\/","CV","mode","(","C","\/","5","(","0",".","28","mA","cm","−","2",")","for","both","the","charging","and","discharging","processes",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":742,"tokens":["Thus",",","the","detailed","reason","for","the","XPS","peak","shift","of","ALD","-","ZrO2","coated","electrode","is","also","ongoing","work","in","our","laboratory",".","Based","on","the","results","of","XPS","and","HRTEM",",","we","can","conclude","that","the","uniform","amorphous","ZrO2","layers","were","successfully","coated","on","the","LiNi0","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_METHOD","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL"]}
{"id":743,"tokens":["which","lead","to","resistive","spinel","and","rock","salt","phases","and","loss","of","oxygen",",","reacting","with","the","electrolyte","[","11","]",",","[","14","]",",","[","15","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":744,"tokens":["which","corresponds","well","to","the","coating","layer","thickness",".","Fig",".","2",".","(","a",")","TEM","image","and","(","b",")","elemental","mapping","of","ZrO2","layer","on","Si","wafer","."],"ner_tags":["O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O"]}
{"id":745,"tokens":["6","V",",","it","was","found","that","the","surface","doping","of","Ti","and","its","surface","segregation","stabilized","the","lattice","oxygen","of","LiCoO2","and","contributed","to","its","enhanced","high","-","voltage","cycle","stability",".","[","11","]"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":746,"tokens":["0","mA","h","g","–","1",")",".","Even","more","remarkable","is","the","enhanced","cycling","ability","of","LATP","-","LCOMg",".","As","shown","in","Figure","2a",",","uncoated","-","LCOMg","demonstrates","a","very","sharp","discharge","capacity","fade",",","particularly",",","after","30","cycles",",","whereas","LATP","-","LCOMg","shows","an","extremely","improved","cycling","ability",";","its","capacity","after","100","cycles","(","176","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":747,"tokens":["5","V",".","This","result","indicates","that","the","coating","medium","of","V2O5","is","not","introduced","into","the","bulk","of","LiNi0",".","8Co0",".","1Mn0",".","1O2","structure","once","again","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","O","O","O","O","O","O","O","B-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","I-CATHODE_MATERIAL","O","O","O","O"]}
{"id":748,"tokens":["Considering","the","local","structure",",","the","type","I","‘","surface","’","O","(","now","becoming","an","interfacial","O",")","is","coordinated","either","by","one","Co",",","two","Ni","and","three","Li","atoms","(","inset","of","Fig",".","6e",")"],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}
{"id":749,"tokens":["This","results","in","lower","activation","barrier","for","diffusion","of","lithium","in","the","layered","structure",".","Thus","optimized","Al","2","O","3","coating","decreases","the","activation","energy","at","the","interface",",","thereby","increasing","the","Li","+","ion","migration",",","leading","to","a","high","capacity","[","35","]","."],"ner_tags":["O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","B-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","I-COATING_MATERIAL","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O","O"]}