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The dataset generation failed
Error code:   DatasetGenerationError
Exception:    ArrowNotImplementedError
Message:      Cannot write struct type 'elements_vars' with no child field to Parquet. Consider adding a dummy child field.
Traceback:    Traceback (most recent call last):
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/builder.py", line 1870, in _prepare_split_single
                  writer.write_table(table)
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/arrow_writer.py", line 620, in write_table
                  self._build_writer(inferred_schema=pa_table.schema)
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/arrow_writer.py", line 441, in _build_writer
                  self.pa_writer = self._WRITER_CLASS(self.stream, schema)
                File "/src/services/worker/.venv/lib/python3.9/site-packages/pyarrow/parquet/core.py", line 1010, in __init__
                  self.writer = _parquet.ParquetWriter(
                File "pyarrow/_parquet.pyx", line 2157, in pyarrow._parquet.ParquetWriter.__cinit__
                File "pyarrow/error.pxi", line 154, in pyarrow.lib.pyarrow_internal_check_status
                File "pyarrow/error.pxi", line 91, in pyarrow.lib.check_status
              pyarrow.lib.ArrowNotImplementedError: Cannot write struct type 'elements_vars' with no child field to Parquet. Consider adding a dummy child field.
              
              During handling of the above exception, another exception occurred:
              
              Traceback (most recent call last):
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/builder.py", line 1886, in _prepare_split_single
                  num_examples, num_bytes = writer.finalize()
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/arrow_writer.py", line 639, in finalize
                  self._build_writer(self.schema)
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/arrow_writer.py", line 441, in _build_writer
                  self.pa_writer = self._WRITER_CLASS(self.stream, schema)
                File "/src/services/worker/.venv/lib/python3.9/site-packages/pyarrow/parquet/core.py", line 1010, in __init__
                  self.writer = _parquet.ParquetWriter(
                File "pyarrow/_parquet.pyx", line 2157, in pyarrow._parquet.ParquetWriter.__cinit__
                File "pyarrow/error.pxi", line 154, in pyarrow.lib.pyarrow_internal_check_status
                File "pyarrow/error.pxi", line 91, in pyarrow.lib.check_status
              pyarrow.lib.ArrowNotImplementedError: Cannot write struct type 'elements_vars' with no child field to Parquet. Consider adding a dummy child field.
              
              The above exception was the direct cause of the following exception:
              
              Traceback (most recent call last):
                File "/src/services/worker/src/worker/job_runners/config/parquet_and_info.py", line 1417, in compute_config_parquet_and_info_response
                  parquet_operations = convert_to_parquet(builder)
                File "/src/services/worker/src/worker/job_runners/config/parquet_and_info.py", line 1049, in convert_to_parquet
                  builder.download_and_prepare(
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/builder.py", line 924, in download_and_prepare
                  self._download_and_prepare(
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/builder.py", line 1000, in _download_and_prepare
                  self._prepare_split(split_generator, **prepare_split_kwargs)
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/builder.py", line 1741, in _prepare_split
                  for job_id, done, content in self._prepare_split_single(
                File "/src/services/worker/.venv/lib/python3.9/site-packages/datasets/builder.py", line 1897, in _prepare_split_single
                  raise DatasetGenerationError("An error occurred while generating the dataset") from e
              datasets.exceptions.DatasetGenerationError: An error occurred while generating the dataset

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doi
string
paragraph_string
string
reaction
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reaction_string
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10.1016/j.materresbull.2006.03.011
La4Ti9O24 compounds with various degrees of Pb2+ a<...>meter (ICP) to check the stoichiometry (Table 2 ).
{ "left_side": [ "La(NO3)3·6H2O", "TiCl4" ], "right_side": [ "La4Ti9O24" ] }
TiCl4 + La(NO3)3·6H2O -> La4Ti9O24
{ "additives": [], "amounts_vars": { "a": null, "b": null, "c": null, "d": null, "f": null, "g": null, "h": null, "i": null, "k": null, "l": null, "m": null, "n": null, "p": null, "q": null, "r": null, "s": null, "t": null, "u": null, "w": null, "x": null, "y": null, "z": null, "α": null, "β": null, "γ": null, "δ": null, "χ": null }, "composition": [ { "amount": "1", "elements": { "Ac": null, "Ag": null, "Al": null, "As": null, "Au": null, "B": null, "Ba": null, "Be": null, "Bi": null, "Br": null, "C": null, "Ca": null, "Cd": null, "Ce": null, "Cf": null, "Cl": null, "Cm": null, "Co": null, "Cr": null, "Cs": null, "Cu": null, "Dy": null, "Er": null, "Eu": null, "F": null, "Fe": null, "Ga": null, "Gd": null, "Ge": null, "H": null, "Hf": null, "Hg": null, "Ho": null, "Hs": null, "I": null, "In": null, "Ir": null, "K": null, "La": "4", "Li": null, "Lu": null, "Mg": null, "Mn": null, "Mo": null, "N": null, "Na": null, "Nb": null, "Nd": null, "Ni": null, "Np": null, "O": "24", "Os": null, "P": null, "Pb": null, "Pd": null, "Pr": null, "Pt": null, "Pu": null, "Rb": null, "Re": null, "Rh": null, "Ru": null, "S": null, "Sb": null, "Sc": null, "Se": null, "Si": null, "Sm": null, "Sn": null, "Sr": null, "Ta": null, "Tb": null, "Tc": null, "Te": null, "Th": null, "Ti": "9", "Tl": null, "Tm": null, "U": null, "V": null, "W": null, "Y": null, "Yb": null, "Zn": null, "Zr": null }, "formula": "La4Ti9O24", "species": { "Ag": null, "Al": null, "Al2O4": null, "AlO2": null, "AlO4": null, "AlSiO4": null, "As": null, "AsO3": null, "AsO4": null, "Au": null, "B": null, "B2O5": null, "B4O9": null, "BO2": null, "BO3": null, "Ba": null, "Be": null, "Bi": null, "Br": null, "BrO3": null, "C": null, "C17H35COO": null, "C2O4": null, "C3H5O(COO)3": null, "C4H4O6": null, "C6H12N4": null, "C6H5COO": null, "C6H5O": null, "C6H5O7": null, "C8H4O4": null, "CF3SO3": null, "CH2": null, "CH3COCHCOCH3": null, "CH3COO": null, "CH3COOH": null, "CN": null, "CN2": null, "CO(NH2)2": null, "CO3": null, "Ca": null, "Cd": null, "Ce": null, "Cf": null, "Cl": null, "ClO": null, "ClO4": null, "Cm": null, "Co": null, "Cr": null, "Cr2O7": null, "CrO4": null, "Cs": null, "Cu": null, "Dy": null, "Er": null, "Eu": null, "F": null, "Fe": null, "Fe(CN)6": null, "FeO3": null, "FeO4": null, "Ga": null, "Gd": null, "Ge": null, "H": null, "H2C2O4": null, "H2O": null, "H2PO4": null, "HAsO4": null, "HCO3": null, "HCOO": null, "HO2": null, "HPO4": null, "HSO4": null, "Hf": null, "Hg": null, "Ho": null, "Hs": null, "I": null, "I3": null, "IO": null, "IO3": null, "IO4": null, "In": null, "Ir": null, "K": null, "La": "4", "Li": null, "Lu": null, "Me": null, "Mg": null, "Mn": null, "MnO4": null, "Mo": null, "Mo2O7": null, "Mo3O10": null, "Mo4O13": null, "Mo8O26": null, "MoO4": null, "N": null, "N3": null, "NH4": null, "NO2": null, "NO3": null, "Na": null, "Nb": null, "NbO3": null, "Nd": null, "Ni": null, "NiO2": null, "NiO3": null, "Np": null, "O": "24", "OCH(CH3)2": null, "OH": null, "Os": null, "P": null, "P2O7": null, "PF6": null, "PO2": null, "PO3": null, "PO3F": null, "PO4": null, "Pb": null, "PbO3": null, "Pd": null, "Pr": null, "Pt": null, "Pu": null, "Rb": null, "Re": null, "Rh": null, "Ru": null, "S": null, "S2": null, "S2O3": null, "SCN": null, "SO3": null, "SO4": null, "Sb": null, "SbO3": null, "SbO4": null, "Sc": null, "Se": null, "SeO4": null, "Si": null, "Si2O7": null, "SiF6": null, "SiO3": null, "SiO4": null, "Sm": null, "Sn": null, "SnO3": null, "SnO4": null, "Sr": null, "Ta": null, "Tb": null, "Tc": null, "Te": null, "TeO3": null, "TeO4": null, "Th": null, "Ti": "9", "TiO": null, "TiO3": null, "TiO4": null, "Tl": null, "Tm": null, "U": null, "UO2": null, "V": null, "V2O7": null, "VO": null, "VO3": null, "VO4": null, "W": null, "WO4": null, "Y": null, "Yb": null, "Zn": null, "Zr": null, "ZrO": null } } ], "elements_vars": {}, "is_acronym": false, "material_formula": "La4Ti9O24", "material_name": "", "material_string": "La4Ti9O24", "mp_id": "mp-560383", "oxygen_deficiency": null, "phase": "" }
La4Ti9O24
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null, "C5H4N": null, "C6H12N4": null, "C6H5COO": null, "C6H5O": null, "C6H5O7": null, "C8H4O4": null, "CF3SO3": null, "CH2": null, "CH3C6H4SO3": null, "CH3CH2COO": null, "CH3COCHCOCH3": null, "CH3COO": null, "CH3COOH": null, "CN": null, "CN2": null, "CO(NH2)2": null, "CO3": null, "Ca": null, "Cd": null, "Ce": null, "Cf": null, "Cl": "4", "ClO": null, "ClO2": null, "ClO3": null, "ClO4": null, "Cm": null, "Co": null, "Cr": null, "Cr2O7": null, "CrO4": null, "Cs": null, "Cu": null, "Dy": null, "Er": null, "Eu": null, "F": null, "Fe": null, "Fe(CN)6": null, "FeO4": null, "Ga": null, "Gd": null, "Ge": null, "H": null, "H2C2O4": null, "H2O": null, "H2PO4": null, "HAsO4": null, "HC2O4": null, "HCO3": null, "HCOO": null, "HO2": null, "HPO4": null, "Hf": null, "Hg": null, "Ho": null, "Hs": null, "I": null, "IO": null, "IO3": null, "IO4": null, "In": null, "Ir": null, "K": null, "La": null, "Li": null, "Lu": null, "Mg": null, "Mn": null, "MnO4": null, "Mo": null, "Mo2O7": null, "Mo7O24": null, "Mo8O26": null, "MoO4": null, "N": null, "N3": null, "NH4": null, "NO2": null, "NO3": null, "Na": null, "Nb": null, "NbO3": null, "Nd": null, "Ni": null, "NiO3": null, "No": null, "Np": null, "O": null, "OCH(CH3)2": null, "OCH2CH2CH2CH3": null, "OH": null, "Os": null, "P": null, "P2O7": null, "PF6": null, "PO2": null, "PO3": null, "PO3F": null, "PO4": null, "Pb": null, "Pd": null, "Pm": null, "Pr": null, "Pt": null, "Pu": null, "Rb": null, "Re": null, "Rh": null, "Ru": null, "S": null, "S2": null, "S2O3": null, "SCN": null, "SO3": null, "SO4": null, "Sb": null, "SbO4": null, "Sc": null, "Se": null, "SeO4": null, "Si": null, "SiF6": null, "SiO3": null, "SiO4": null, "Sm": null, "Sn": null, "SnO3": null, "SnO4": null, "Sr": null, "Ta": null, "Tb": null, "Tc": null, "Te": null, "TeO3": null, "TeO4": null, "Th": null, "Ti": "1", "TiO": null, "TiO3": null, "TiO4": null, "Tl": null, "Tm": null, "U": null, "UO2": null, "V": null, "V2O7": null, "VO": null, "VO3": null, "VO4": null, "W": null, 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[ "water" ]
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precipitation
10.1016/j.apcata.2012.04.027
The anatase TiO2 support was obtained by adding 0.<...> flowing air. The BET surface area is 77.1 m2 g−1.
{ "left_side": [ "TiCl4" ], "right_side": [ "TiO2" ] }
TiCl4 -> TiO2
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TiO2
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[ "water", "water" ]
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precipitation
10.1063/1.4967923
The precursor salts, cobalt chloride (CoCl2, 6H2O)<...>−↔ FeOOH+ H2O, Co(OH)2+2FeOOH → CoFe2O4+ 2H2O+ H+.
{ "left_side": [ "CoCl2", "FeCl3" ], "right_side": [ "CoFe2O4" ] }
FeCl3 + CoCl2 -> CoFe2O4
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CoFe2O4
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[ "ethylene glycol", "ethanol", "ethanol", "ethylene glycol" ]
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hydrothermal
10.1039/c7nr01644a
For the growth of ZnCo2O4 NRs, H:ZnO NR samples we<...>e used for the growth of ZnCo2O4 NRs on H:ZnO NRs.
{ "left_side": [ "Co(NO3)3·6H2O", "Zn(NO3)2·6H2O" ], "right_side": [ "ZnCo2O4" ] }
Zn(NO3)2·6H2O + Co(NO3)3·6H2O -> ZnCo2O4
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ZnCo2O4
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[ "water" ]
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[ { "material": "zinc nitrate hexahydrate", "quantity": [ { "number": 1, "unit": "mmol" } ] }, { "material": "cobalt nitrate hexahydrate", "quantity": [ { "number": 2, "unit": "mmol" } ] }, { "material": "urea", "quantity": [ { "number": 6, "unit": "mmol" } ] }, { "material": "ammonium fluoride", "quantity": [ { "number": 5, "unit": "mmol" } ] } ]
hydrothermal
10.1039/c3ce00037k
All chemicals were of analytical grade and purchas<...>tions were kept the same as the typical synthesis.
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Cu(NO3)2·3H2O + CH4N2S + C6H9NO -> Cu39S28
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Cu39S28
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[]
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hydrothermal
10.1039/c2ce25512j
The reagents were analytical grade and used withou<...>d finally dried in a vacuum oven at 60 °C for 3 h.
{ "left_side": [ "AgNO3", "La(NO3)3·6H2O", "N2H4·H2O", "Na2TeO3", "Pb(CH3COO)2·3H2O" ], "right_side": [ "AgPb10LaTe12" ] }
La(NO3)3·6H2O + Na2TeO3 + Pb(CH3COO)2·3H2O + AgNO3 + N2H4·H2O -> AgPb10LaTe12
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AgPb10LaTe12
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[ "water", "ethanol" ]
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hydrothermal
10.1007/s10854-016-5792-7
In this study, the synthesis of EuVO4 was performe<...>sphere. Reaction conditions are listed in Table 1.
{ "left_side": [ "Eu(NO3)3·6H2O", "NH4VO3" ], "right_side": [ "EuVO4" ] }
Eu(NO3)3·6H2O + NH4VO3 -> EuVO4
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EuVO4
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"WO4": null, "Y": null, "Yb": null, "Zn": null, "Zr": null, "ZrO": null } } ], "elements_vars": {}, "is_acronym": false, "material_formula": "NH4VO3", "material_name": "", "material_string": "NH4VO3", "mp_id": "mp-743581", "oxygen_deficiency": null, "phase": "" } ]
[ "water" ]
[ { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": [ "water" ], "temperature": null, "time": null }, "string": "dissolved", "type": "MixingOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": null, "time": null }, "string": "added", "type": "MixingOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": null, "time": null }, "string": "added", "type": "MixingOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": null, "time": null }, "string": "filtered", "type": "PurificationOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": [ "water" ], "temperature": null, "time": null }, "string": "washed", "type": "PurificationOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": { "max_value": 90, "min_value": 90, "units": "°C", "values": [ 90 ] }, "time": null }, "string": "dried", "type": "DryingOperation" }, { "conditions": { "atmosphere": [ "air" ], "mixing_device": null, "mixing_media": null, "temperature": { "max_value": 550, "min_value": 550, "units": "°C", "values": [ 550 ] }, "time": { "max_value": 300, "min_value": 300, "units": "min", "values": [ 300 ] } }, "string": "calcined", "type": "HeatingOperation" } ]
[ { "material": "Ammonium metavanadate", "quantity": [ { "number": 1, "unit": "mmol" } ] }, { "material": "Eu(NO3)3·6H2O", "quantity": [ { "number": 1, "unit": "mmol" } ] }, { "material": "water", "quantity": [ { "number": 60, "unit": "ml" } ] } ]
precipitation
10.1016/j.jssc.2008.06.049
A 7.2 M NH4OH solution was added to a 0.5 M aqueou<...>400, 600, 800 °C) for 6 h under air was performed.
{ "left_side": [ "Fe(NO3)3·9H2O" ], "right_side": [ "Fe2O3" ] }
Fe(NO3)3·9H2O -> Fe2O3
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Fe2O3
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[]
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precipitation
10.1016/j.jpowsour.2013.01.021
To prepare a concentration-gradient cathode materi<...> form the concentration-gradient cathode material.
{ "left_side": [ "(Mn1/3N1/3Co1/3)CO3", "CoSO4", "Li2CO3", "MnSO4", "NiSO4" ], "right_side": [ "Li1.13(Mn0.534Ni0.233Co0.233)0.87O2" ] }
Li2CO3 + NiSO4 + MnSO4 + CoSO4 + (Mn1/3N1/3Co1/3)CO3 -> Li1.13(Mn0.534Ni0.233Co0.233)0.87O2
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[]
[ { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": null, "time": null }, "string": "stirred", "type": "MixingOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": null, "time": null }, "string": "fed", "type": "MixingOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": null, "time": null }, "string": "filtered", "type": "PurificationOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": null, "time": null }, "string": "washed", "type": "PurificationOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": { "max_value": 110, "min_value": 110, "units": "°C", "values": [ 110 ] }, "time": null }, "string": "dried", "type": "DryingOperation" }, { "conditions": { "atmosphere": null, "mixing_device": null, "mixing_media": null, "temperature": { "max_value": 500, "min_value": 500, "units": "°C", "values": [ 500 ] }, "time": { "max_value": 8, "min_value": 8, "units": "h", "values": [ 8 ] } }, "string": "preheated", "type": "HeatingOperation" }, { "conditions": { "atmosphere": [ "air" ], "mixing_device": null, "mixing_media": null, "temperature": { "max_value": 900, "min_value": 900, "units": "°C", "values": [ 900 ] }, "time": { "max_value": 10, "min_value": 10, "units": "h", "values": [ 10 ] } }, "string": "calcined", "type": "HeatingOperation" } ]
null
precipitation
10.1039/C2AN35259A
2.3.1 Preparation of superparamagnetic Fe3O4 parti<...>finally drying in a vacuum oven at 60 °C for 24 h.
{ "left_side": [ "FeCl3·6H2O", "FeSO4·7H2O" ], "right_side": [ "Fe3O4" ] }
FeSO4·7H2O + FeCl3·6H2O -> Fe3O4
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Fe3O4
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precipitation
End of preview.