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Metal matrix composite
Summary
Metal_matrix_composites
There is some overlap between MMCs and cermets, with the latter typically consisting of less than 20% metal by volume. When at least three materials are present, it is called a hybrid composite. MMCs can have much higher strength-to-weight ratios, stiffness, and ductility than traditional materials, so they are often used in demanding applications. MMCs typically have lower thermal and electrical conductivity and poor resistance to radiation, limiting their use in the very harshest environments.
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Partial dislocation
Summary
Partial_dislocation
In materials science, a partial dislocation is a decomposed form of dislocation that occurs within a crystalline material. An extended dislocation is a dislocation that has dissociated into a pair of partial dislocations. The vector sum of the Burgers vectors of the partial dislocations is the Burgers vector of the extended dislocation.
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Polymer blend
Summary
Polymer_blend
In materials science, a polymer blend, or polymer mixture, is a member of a class of materials analogous to metal alloys, in which at least two polymers are blended together to create a new material with different physical properties.
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Polymer matrix composite
Summary
Polymer_matrix_composite
In materials science, a polymer matrix composite (PMC) is a composite material composed of a variety of short or continuous fibers bound together by a matrix of organic polymers. PMCs are designed to transfer loads between fibers of a matrix. Some of the advantages with PMCs include their light weight, high resistance to abrasion and corrosion, and high stiffness and strength along the direction of their reinforcements.
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Porous media
Summary
Porous_medium
In materials science, a porous medium or a porous material is a material containing pores (voids). The skeletal portion of the material is often called the "matrix" or "frame". The pores are typically filled with a fluid (liquid or gas). The skeletal material is usually a solid, but structures like foams are often also usefully analyzed using concept of porous media.
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Porous media
Summary
Porous_medium
A porous medium is most often characterised by its porosity. Other properties of the medium (e.g. permeability, tensile strength, electrical conductivity, tortuosity) can sometimes be derived from the respective properties of its constituents (solid matrix and fluid) and the media porosity and pores structure, but such a derivation is usually complex. Even the concept of porosity is only straightforward for a poroelastic medium.
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Porous media
Summary
Porous_medium
Often both the solid matrix and the pore network (also known as the pore space) are continuous, so as to form two interpenetrating continua such as in a sponge. However, there is also a concept of closed porosity and effective porosity, i.e. the pore space accessible to flow. Many natural substances such as rocks and soil (e.g. aquifers, petroleum reservoirs), zeolites, biological tissues (e.g. bones, wood, cork), and man made materials such as cements and ceramics can be considered as porous media.
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Porous media
Summary
Porous_medium
Many of their important properties can only be rationalized by considering them to be porous media. The concept of porous media is used in many areas of applied science and engineering: filtration, mechanics (acoustics, geomechanics, soil mechanics, rock mechanics), engineering (petroleum engineering, bioremediation, construction engineering), geosciences (hydrogeology, petroleum geology, geophysics), biology and biophysics, material science. Two important current fields of application for porous materials are energy conversion and energy storage, where porous materials are essential for superpacitors, (photo-)catalysis, fuel cells, and batteries.
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Precipitate-free zone
Summary
Precipitate-free_zone
In materials science, a precipitate-free zone (PFZ) refers to microscopic localized regions around grain boundaries that are free of precipitates (solid impurities forced outwards from the grain during crystallization). It is a common phenomenon that arises in polycrystalline materials (crystalline materials with stochastically-oriented grains) where heterogeneous nucleation of precipitates is the dominant nucleation mechanism. This is because grain boundaries are high-energy surfaces that act as sinks for vacancies, causing regions adjacent to a grain boundary to be devoid of vacancies. As it is energetically favorable for heterogeneous nucleation to occur preferentially around defect-rich sites such as vacancies, nucleation of precipitates is impeded in the vacancy-free regions immediately adjacent to grain boundaries
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Refractory lining
Summary
Refractory_materials
In materials science, a refractory (or refractory material) is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, inorganic, non-metallic, porous, and heterogeneous. They are typically composed of oxides or carbides, nitrides etc. of the following elements: silicon, aluminium, magnesium, calcium, boron, chromium and zirconium.ASTM C71 defines refractories as "non-metallic materials having those chemical and physical properties that make them applicable for structures, or as components of systems, that are exposed to environments above 1,000 °F (811 K; 538 °C)".Refractory materials are used in furnaces, kilns, incinerators, and reactors. Refractories are also used to make crucibles and moulds for casting glass and metals and for surfacing flame deflector systems for rocket launch structures. Today, the iron and steel industry and metal casting sectors use approximately 70% of all refractories produced.
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Sandwich structured composite
Summary
Sandwich-structured_composite
In materials science, a sandwich-structured composite is a special class of composite materials that is fabricated by attaching two thin-but-stiff skins to a lightweight but thick core. The core material is normally low strength, but its higher thickness provides the sandwich composite with high bending stiffness with overall low density. Open- and closed-cell-structured foams like polyethersulfone, polyvinylchloride, polyurethane, polyethylene or polystyrene foams, balsa wood, syntactic foams, and honeycombs are commonly used core materials.
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Sandwich structured composite
Summary
Sandwich-structured_composite
Sometimes, the honeycomb structure is filled with other foams for added strength. Open- and closed-cell metal foam can also be used as core materials. Laminates of glass or carbon fiber-reinforced thermoplastics or mainly thermoset polymers (unsaturated polyesters, epoxies...) are widely used as skin materials. Sheet metal is also used as skin material in some cases. The core is bonded to the skins with an adhesive or with metal components by brazing together.
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Mono-crystalline silicon
Summary
Single_Crystal
In materials science, a single crystal (or single-crystal solid or monocrystalline solid) is a material in which the crystal lattice of the entire sample is continuous and unbroken to the edges of the sample, with no grain boundaries. The absence of the defects associated with grain boundaries can give monocrystals unique properties, particularly mechanical, optical and electrical, which can also be anisotropic, depending on the type of crystallographic structure. These properties, in addition to making some gems precious, are industrially used in technological applications, especially in optics and electronics.Because entropic effects favor the presence of some imperfections in the microstructure of solids, such as impurities, inhomogeneous strain and crystallographic defects such as dislocations, perfect single crystals of meaningful size are exceedingly rare in nature. The necessary laboratory conditions often add to the cost of production.
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Mono-crystalline silicon
Summary
Single_Crystal
On the other hand, imperfect single crystals can reach enormous sizes in nature: several mineral species such as beryl, gypsum and feldspars are known to have produced crystals several meters across.The opposite of a single crystal is an amorphous structure where the atomic position is limited to short-range order only. In between the two extremes exist polycrystalline, which is made up of a number of smaller crystals known as crystallites, and paracrystalline phases. Single crystals will usually have distinctive plane faces and some symmetry, where the angles between the faces will dictate its ideal shape. Gemstones are often single crystals artificially cut along crystallographic planes to take advantage of refractive and reflective properties.
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Thermosetting polymer
Summary
Thermosetting_polymers
In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening ("curing") a soft solid or viscous liquid prepolymer (resin). Curing is induced by heat or suitable radiation and may be promoted by high pressure, or mixing with a catalyst. Heat is not necessarily applied externally, but is often generated by the reaction of the resin with a curing agent (catalyst, hardener). Curing results in chemical reactions that create extensive cross-linking between polymer chains to produce an infusible and insoluble polymer network.
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Thermosetting polymer
Summary
Thermosetting_polymers
The starting material for making thermosets is usually malleable or liquid prior to curing, and is often designed to be molded into the final shape. It may also be used as an adhesive. Once hardened, a thermoset cannot be melted for reshaping, in contrast to thermoplastic polymers which are commonly produced and distributed in the form of pellets, and shaped into the final product form by melting, pressing, or injection molding.
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Advanced composite materials (engineering)
Summary
Advanced_composite_materials_(engineering)
In materials science, advanced composite materials (ACMs) are materials that are generally characterized by unusually high strength fibres with unusually high stiffness, or modulus of elasticity characteristics, compared to other materials, while bound together by weaker matrices. These are termed "advanced composite materials" in comparison to the composite materials commonly in use such as reinforced concrete, or even concrete itself. The high strength fibers are also low density while occupying a large fraction of the volume.
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Advanced composite materials (engineering)
Summary
Advanced_composite_materials_(engineering)
Advanced composites exhibit desirable physical and chemical properties that include light weight coupled with high stiffness (elasticity), and strength along the direction of the reinforcing fiber, dimensional stability, temperature and chemical resistance, flex performance, and relatively easy processing. Advanced composites are replacing metal components in many uses, particularly in the aerospace industry. Composites are classified according to their matrix phase.
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Advanced composite materials (engineering)
Summary
Advanced_composite_materials_(engineering)
These classifications are polymer matrix composites (PMCs), ceramic matrix composites (CMCs), and metal matrix composites (MMCs). Also, materials within these categories are often called "advanced" if they combine the properties of high (axial, longitudinal) strength values and high (axial, longitudinal) stiffness values, with low weight, corrosion resistance, and in some cases special electrical properties. Advanced composite materials have broad, proven applications, in the aircraft, aerospace, and sports equipment sectors.
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Advanced composite materials (engineering)
Summary
Advanced_composite_materials_(engineering)
Even more specifically ACMs are very attractive for aircraft and aerospace structural parts. ACMs have been developing for NASA's Advanced Space Transportation Program, armor protection for Army aviation and the Federal Aviation Administration of the USA, and high-temperature shafting for the Comanche helicopter. Additionally, ACMs have a decades long history in military and government aerospace industries. However, much of the technology is new and not presented formally in secondary or undergraduate education, and the technology of advanced composites manufacture is continually evolving.
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Interstitial defect
Summary
Interstitial_element
In materials science, an interstitial defect is a type of point crystallographic defect where an atom of the same or of a different type, occupies an interstitial site in the crystal structure. When the atom is of the same type as those already present they are known as a self-interstitial defect. Alternatively, small atoms in some crystals may occupy interstitial sites, such as hydrogen in palladium. Interstitials can be produced by bombarding a crystal with elementary particles having energy above the displacement threshold for that crystal, but they may also exist in small concentrations in thermodynamic equilibrium. The presence of interstitial defects can modify the physical and chemical properties of a material.
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Intrinsic properties
Applications in science and engineering
Intrinsic_property > Applications in science and engineering
In materials science, an intrinsic property is independent of how much of a material is present and is independent of the form of the material, e.g., one large piece or a collection of small particles. Intrinsic properties are dependent mainly on the fundamental chemical composition and structure of the material. Extrinsic properties are differentiated as being dependent on the presence of avoidable chemical contaminants or structural defects.In biology, intrinsic effects originate from inside an organism or cell, such as an autoimmune disease or intrinsic immunity. In electronics and optics, intrinsic properties of devices (or systems of devices) are generally those that are free from the influence of various types of non-essential defects. Such defects may arise as a consequence of design imperfections, manufacturing errors, or operational extremes and can produce distinctive and often undesirable extrinsic properties. The identification, optimization, and control of both intrinsic and extrinsic properties are among the engineering tasks necessary to achieve the high performance and reliability of modern electrical and optical systems.
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Torsion tensor
The torsion of a filament
Torsion_form > Characterizations and interpretations > The torsion of a filament
In materials science, and especially elasticity theory, ideas of torsion also play an important role. One problem models the growth of vines, focusing on the question of how vines manage to twist around objects. The vine itself is modeled as a pair of elastic filaments twisted around one another. In its energy-minimizing state, the vine naturally grows in the shape of a helix. But the vine may also be stretched out to maximize its extent (or length). In this case, the torsion of the vine is related to the torsion of the pair of filaments (or equivalently the surface torsion of the ribbon connecting the filaments), and it reflects the difference between the length-maximizing (geodesic) configuration of the vine and its energy-minimizing configuration.
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Asperity (material science)
Summary
Asperity_(materials_science)
In materials science, asperity, defined as "unevenness of surface, roughness, ruggedness" (from the Latin asper—"rough"), has implications (for example) in physics and seismology. Smooth surfaces, even those polished to a mirror finish, are not truly smooth on a microscopic scale. They are rough, with sharp, rough or rugged projections, termed "asperities". Surface asperities exist across multiple scales, often in a self affine or fractal geometry.
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Asperity (material science)
Summary
Asperity_(materials_science)
The fractal dimension of these structures has been correlated with the contact mechanics exhibited at an interface in terms of friction and contact stiffness. When two macroscopically smooth surfaces come into contact, initially they only touch at a few of these asperity points. These cover only a very small portion of the surface area.
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Asperity (material science)
Summary
Asperity_(materials_science)
Friction and wear originate at these points, and thus understanding their behavior becomes important when studying materials in contact. When the surfaces are subjected to a compressive load, the asperities deform through elastic and plastic modes, increasing the contact area between the two surfaces until the contact area is sufficient to support the load. The relationship between frictional interactions and asperity geometry is complex and poorly understood. It has been reported that an increased roughness may under certain circumstances result in weaker frictional interactions while smoother surfaces may in fact exhibit high levels of friction owing to high levels of true contact.The Archard equation provides a simplified model of asperity deformation when materials in contact are subject to a force. Due to the ubiquitous presence of deformable asperities in self affine hierarchical structures, the true contact area at an interface exhibits a linear relationship with the applied normal load.
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Bulk density
Summary
Bulk_density
In materials science, bulk density, also called apparent density or volumetric density, is a property of powders, granules, and other "divided" solids, especially used in reference to mineral components (soil, gravel), chemical substances, pharmaceutical ingredients, foodstuff, or any other masses of corpuscular or particulate matter (particles). Bulk density is defined as the mass of the many particles of the material divided by the total volume they occupy. The total volume includes particle volume, inter-particle void volume, and internal pore volume.Bulk density is not an intrinsic property of a material; it can change depending on how the material is handled. For example, a powder poured into a cylinder will have a particular bulk density; if the cylinder is disturbed, the powder particles will move and usually settle closer together, resulting in a higher bulk density. For this reason, the bulk density of powders is usually reported both as "freely settled" (or "poured" density) and "tapped" density (where the tapped density refers to the bulk density of the powder after a specified compaction process, usually involving vibration of the container.) In contrast, particle density is an intrinsic property of the solid and does not include the volume for voids between particles.
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Ceramic Matrix Composite
Summary
Ceramic_Matrix_Composite
In materials science, ceramic matrix composites (CMCs) are a subgroup of composite materials and a subgroup of ceramics. They consist of ceramic fibers embedded in a ceramic matrix. The fibers and the matrix both can consist of any ceramic material, whereby carbon and carbon fibers can also be regarded as a ceramic material.
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Friction force microscopy
Summary
Friction_force_microscopy
In materials science, chemical force microscopy (CFM) is a variation of atomic force microscopy (AFM) which has become a versatile tool for characterization of materials surfaces. With AFM, structural morphology is probed using simple tapping or contact modes that utilize van der Waals interactions between tip and sample to maintain a constant probe deflection amplitude (constant force mode) or maintain height while measuring tip deflection (constant height mode). CFM, on the other hand, uses chemical interactions between functionalized probe tip and sample. Choice chemistry is typically gold-coated tip and surface with R−SH thiols attached, R being the functional groups of interest.
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Friction force microscopy
Summary
Friction_force_microscopy
CFM enables the ability to determine the chemical nature of surfaces, irrespective of their specific morphology, and facilitates studies of basic chemical bonding enthalpy and surface energy. Typically, CFM is limited by thermal vibrations within the cantilever holding the probe. This limits force measurement resolution to ~1 pN which is still very suitable considering weak COOH/CH3 interactions are ~20 pN per pair. Hydrophobicity is used as the primary example throughout this consideration of CFM, but certainly any type of bonding can be probed with this method.
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Creep (deformation)
Summary
Creep_(deformation)
In materials science, creep (sometimes called cold flow) is the tendency of a solid material to undergo slow deformation while subject to persistent mechanical stresses. It can occur as a result of long-term exposure to high levels of stress that are still below the yield strength of the material. Creep is more severe in materials that are subjected to heat for long periods and generally increase as they near their melting point. The rate of deformation is a function of the material's properties, exposure time, exposure temperature and the applied structural load.
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Creep (deformation)
Summary
Creep_(deformation)
Depending on the magnitude of the applied stress and its duration, the deformation may become so large that a component can no longer perform its function – for example creep of a turbine blade could cause the blade to contact the casing, resulting in the failure of the blade. Creep is usually of concern to engineers and metallurgists when evaluating components that operate under high stresses or high temperatures. Creep is a deformation mechanism that may or may not constitute a failure mode.
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Creep (deformation)
Summary
Creep_(deformation)
For example, moderate creep in concrete is sometimes welcomed because it relieves tensile stresses that might otherwise lead to cracking. Unlike brittle fracture, creep deformation does not occur suddenly upon the application of stress. Instead, strain accumulates as a result of long-term stress. Therefore, creep is a "time-dependent" deformation.
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Critical resolved shear stress
Summary
Critical_resolved_shear_stress
In materials science, critical resolved shear stress (CRSS) is the component of shear stress, resolved in the direction of slip, necessary to initiate slip in a grain. Resolved shear stress (RSS) is the shear component of an applied tensile or compressive stress resolved along a slip plane that is other than perpendicular or parallel to the stress axis. The RSS is related to the applied stress by a geometrical factor, m, typically the Schmid factor: τ RSS = σ app m = σ app ( cos ⁡ ϕ cos ⁡ λ ) {\displaystyle \tau _{\text{RSS}}=\sigma _{\text{app}}m=\sigma _{\text{app}}(\cos \phi \cos \lambda )} where σapp is the magnitude of the applied tensile stress, Φ is the angle between the normal of the slip plane and the direction of the applied force, and λ is the angle between the slip direction and the direction of the applied force. The Schmid factor is most applicable to FCC single-crystal metals, but for polycrystal metals the Taylor factor has been shown to be more accurate.
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Critical resolved shear stress
Summary
Critical_resolved_shear_stress
The CRSS is the value of resolved shear stress at which yielding of the grain occurs, marking the onset of plastic deformation. CRSS, therefore, is a material property and is not dependent on the applied load or grain orientation. The CRSS is related to the observed yield strength of the material by the maximum value of the Schmid factor: σ y = τ CRSS m max {\displaystyle \sigma _{y}={\frac {\tau _{\text{CRSS}}}{m_{\text{max}}}}} CRSS is a constant for crystal families. Hexagonal close-packed crystals, for example, have three main families - basal, prismatic, and pyramidal - with different values for the critical resolved shear stress.
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Cross Slip
Summary
Cross_Slip
In materials science, cross slip is the process by which a screw dislocation moves from one slip plane to another due to local stresses. It allows non-planar movement of screw dislocations. Non-planar movement of edge dislocations is achieved through climb. Since the Burgers vector of a perfect screw dislocation is parallel to the dislocation line, it has an infinite number of possible slip planes (planes containing the dislocation line and the Burgers vector), unlike an edge or mixed dislocation, which has a unique slip plane.
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Cross Slip
Summary
Cross_Slip
Therefore, a screw dislocation can glide or slip along any plane that contains its Burgers vector. During cross slip, the screw dislocation switches from gliding along one slip plane to gliding along a different slip plane, called the cross-slip plane. The cross slip of moving dislocations can be seen by transmission electron microscopy.
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Euler angle
Crystallographic texture
Euler_Angles > Applications > Crystallographic texture
In materials science, crystallographic texture (or preferred orientation) can be described using Euler angles. In texture analysis, the Euler angles provide a mathematical depiction of the orientation of individual crystallites within a polycrystalline material, allowing for the quantitative description of the macroscopic material. The most common definition of the angles is due to Bunge and corresponds to the ZXZ convention. It is important to note, however, that the application generally involves axis transformations of tensor quantities, i.e. passive rotations. Thus the matrix that corresponds to the Bunge Euler angles is the transpose of that shown in the table above.
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Direct laser interference patterning
Summary
Direct_laser_interference_patterning
In materials science, direct laser interference patterning (DLIP) is a laser-based technology that uses the physical principle of interference of high-intensity coherent laser beams to produce functional periodic microstructures. In order to obtain interference, the beam is divided by a beam splitter, special prisms, or other elements. The beams are then folded together to form an interference pattern.
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Direct laser interference patterning
Summary
Direct_laser_interference_patterning
Sufficiently high power of the laser beam can thus result in the removal of material at the interference maximums thanks to ablation phenomenon, leaving the material intact at the minimums. In this way, a repeatable pattern can be permanently fixed on the surface of a given material. DLIP can be applied to almost any material and can change the properties of surfaces in many technological areas with regard to electrical and optical properties, tribology (friction and wear), light absorption and wettability (e.g., which can be related to hygienic properties).
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Disappearing polymorphs
Summary
Disappearing_polymorphs
In materials science, disappearing polymorphs (or perverse polymorphism) describes a phenomenon in which a seemingly stable crystal structure is suddenly unable to be produced, instead transforming into a polymorph, or differing crystal structure with the same chemical composition, during nucleation. Sometimes the resulting transformation is extremely hard or impractical to reverse, because the new polymorph may be more stable. It is hypothesized that contact with a single microscopic seed crystal of the new polymorph can be enough to start a chain reaction causing the transformation of a much larger mass of material. Widespread contamination with such microscopic seed crystals may lead to the impression that the original polymorph has "disappeared."
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Disappearing polymorphs
Summary
Disappearing_polymorphs
This is of concern to both the pharmaceutical and computer hardware industry, where disappearing polymorphs can ruin the effectiveness of their products, and make it impossible to manufacture the original product if there is any contamination. There have been cases of laboratories growing crystals of a particular structure and when they try to recreate this, the original crystal structure isn't created but a new crystal structure is.
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Disappearing polymorphs
Summary
Disappearing_polymorphs
The drug paroxetine was subject to a lawsuit that hinged on such a pair of polymorphs, and multiple life-saving drugs, such as ritonavir, have been recalled due to unexpected polymorphism. Although it may seem like a so-called disappearing polymorph has disappeared for good, it is believed that it is always possible in principle to reconstruct the original polymorph, though doing so may be impractically difficult. Disappearing polymorphs are generally metastable forms, that are replaced by a more stable form.It is hypothesized that "unintentional seeding" may also be responsible for the phenomenon in which it often becomes easier to crystallize synthetic compounds over time.
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Dispersion (materials science)
Summary
Dispersion_(materials_science)
In materials science, dispersion is the fraction of atoms of a material exposed to the surface. In general, D = NS/N, where D is the dispersion, NS is the number of surface atoms and NT is the total number of atoms of the material. It is an important concept in heterogeneous catalysis, since only atoms exposed to the surface can affect catalytic surface reactions. Dispersion increases with decreasing crystallite size and approaches unity at a crystallite diameter of about 0.1 nm.
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Effective medium
Summary
Effective_permittivity_and_permeability
In materials science, effective medium approximations (EMA) or effective medium theory (EMT) pertain to analytical or theoretical modeling that describes the macroscopic properties of composite materials. EMAs or EMTs are developed from averaging the multiple values of the constituents that directly make up the composite material. At the constituent level, the values of the materials vary and are inhomogeneous. Precise calculation of the many constituent values is nearly impossible.
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Effective medium
Summary
Effective_permittivity_and_permeability
However, theories have been developed that can produce acceptable approximations which in turn describe useful parameters including the effective permittivity and permeability of the materials as a whole. In this sense, effective medium approximations are descriptions of a medium (composite material) based on the properties and the relative fractions of its components and are derived from calculations, and effective medium theory. There are two widely used formulae.Effective permittivity and permeability are averaged dielectric and magnetic characteristics of a microinhomogeneous medium.
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Effective medium
Summary
Effective_permittivity_and_permeability
They both were derived in quasi-static approximation when the electric field inside a mixture particle may be considered as homogeneous. So, these formulae can not describe the particle size effect. Many attempts were undertaken to improve these formulae.
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Environmental stress fracture
Summary
Environmental_stress_fracture
In materials science, environmental stress fracture or environment assisted fracture is the generic name given to premature failure under the influence of tensile stresses and harmful environments of materials such as metals and alloys, composites, plastics and ceramics. Metals and alloys exhibit phenomena such as stress corrosion cracking, hydrogen embrittlement, liquid metal embrittlement and corrosion fatigue all coming under this category. Environments such as moist air, sea water and corrosive liquids and gases cause environmental stress fracture. Metal matrix composites are also susceptible to many of these processes.
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Environmental stress fracture
Summary
Environmental_stress_fracture
Plastics and plastic-based composites may suffer swelling, debonding and loss of strength when exposed to organic fluids and other corrosive environments, such as acids and alkalies. Under the influence of stress and environment, many structural materials, particularly the high-specific strength ones become brittle and lose their resistance to fracture.
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Environmental stress fracture
Summary
Environmental_stress_fracture
While their fracture toughness remains unaltered, their threshold stress intensity factor for crack propagation may be considerably lowered. Consequently, they become prone to premature fracture because of sub-critical crack growth. This article aims to give a brief overview of the various degradation processes mentioned above.
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Fast ion conductor
Summary
Solid_electrolytes
In materials science, fast ion conductors are solid conductors with highly mobile ions. These materials are important in the area of solid state ionics, and are also known as solid electrolytes and superionic conductors. These materials are useful in batteries and various sensors.
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Fast ion conductor
Summary
Solid_electrolytes
Fast ion conductors are used primarily in solid oxide fuel cells. As solid electrolytes they allow the movement of ions without the need for a liquid or soft membrane separating the electrodes. The phenomenon relies on the hopping of ions through an otherwise rigid crystal structure.
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Material fatigue
Summary
Metal_fatigue
In materials science, fatigue is the initiation and propagation of cracks in a material due to cyclic loading. Once a fatigue crack has initiated, it grows a small amount with each loading cycle, typically producing striations on some parts of the fracture surface. The crack will continue to grow until it reaches a critical size, which occurs when the stress intensity factor of the crack exceeds the fracture toughness of the material, producing rapid propagation and typically complete fracture of the structure. Fatigue has traditionally been associated with the failure of metal components which led to the term metal fatigue.
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Material fatigue
Summary
Metal_fatigue
In the nineteenth century, the sudden failing of metal railway axles was thought to be caused by the metal crystallising because of the brittle appearance of the fracture surface, but this has since been disproved. Most materials, such as composites, plastics and ceramics, seem to experience some sort of fatigue-related failure.To aid in predicting the fatigue life of a component, fatigue tests are carried out using coupons to measure the rate of crack growth by applying constant amplitude cyclic loading and averaging the measured growth of a crack over thousands of cycles.
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Material fatigue
Summary
Metal_fatigue
However, there are also a number of special cases that need to be considered where the rate of crack growth is significantly different compared to that obtained from constant amplitude testing. Such as the reduced rate of growth that occurs for small loads near the threshold or after the application of an overload; and the increased rate of crack growth associated with short cracks or after the application of an underload.If the loads are above a certain threshold, microscopic cracks will begin to initiate at stress concentrations such as holes, persistent slip bands (PSBs), composite interfaces or grain boundaries in metals. The stress values that cause fatigue damage are typically much less than the yield strength of the material.
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Fracture toughening mechanisms
Summary
Fracture_toughness
In materials science, fracture toughness is the critical stress intensity factor of a sharp crack where propagation of the crack suddenly becomes rapid and unlimited. A component's thickness affects the constraint conditions at the tip of a crack with thin components having plane stress conditions and thick components having plane strain conditions. Plane strain conditions give the lowest fracture toughness value which is a material property. The critical value of stress intensity factor in mode I loading measured under plane strain conditions is known as the plane strain fracture toughness, denoted K Ic {\displaystyle K_{\text{Ic}}} .
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Fracture toughening mechanisms
Summary
Fracture_toughness
When a test fails to meet the thickness and other test requirements that are in place to ensure plane strain conditions, the fracture toughness value produced is given the designation K c {\displaystyle K_{\text{c}}} . Fracture toughness is a quantitative way of expressing a material's resistance to crack propagation and standard values for a given material are generally available. Slow self-sustaining crack propagation known as stress corrosion cracking, can occur in a corrosive environment above the threshold K Iscc {\displaystyle K_{\text{Iscc}}} and below K Ic {\displaystyle K_{\text{Ic}}} . Small increments of crack extension can also occur during fatigue crack growth, which after repeated loading cycles, can gradually grow a crack until final failure occurs by exceeding the fracture toughness.
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Fragile matter
Summary
Fragile_matter
In materials science, fragile matter is a granular material that is jammed solid. Everyday examples include beans getting stuck in a hopper in a whole food shop, or milk powder getting jammed in an upside-down bottle. The term was coined by physicist Michael Cates, who asserts that such circumstances warrant a new class of materials.
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Fragile matter
Summary
Fragile_matter
The jamming thus described can be unjammed by mechanical means, such as tapping or shaking the container, or poking it with a stick. Cates proposed that such jammed systems differ from ordinary solids in that if the direction of the applied stress changes, the jam will break up. Sometimes the change of direction required is very small.
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Fragile matter
Summary
Fragile_matter
Perhaps the simplest example is a pile of sand, which is solid in the sense that the pile sustains its shape despite the force of gravity. Slight tilting or vibration is enough to enable the grains to shift, collapsing the pile. Not all jammed systems are fragile, i.e. foam.
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Fragile matter
Summary
Fragile_matter
Shaving foam is jammed because the bubbles are tightly packed together under the isotropic stress imposed by atmospheric pressure. If it were a fragile solid, it would respond plastically to shear stress, however small. But because bubbles deform, foam actually responds elastically provided that the stress is below a threshold value. Fragile matter is also not to be confused with cases in which the particles have adhered to one another ("caking").
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Friability
Summary
Friability
In materials science, friability ( FRY-ə-BIL-ə-tee), the condition of being friable, describes the tendency of a solid substance to break into smaller pieces under duress or contact, especially by rubbing. The opposite of friable is indurate. Substances that are designated hazardous, such as asbestos or crystalline silica, are often said to be friable if small particles are easily dislodged and become airborne, and hence respirable (able to enter human lungs), thereby posing a health hazard. Tougher substances, such as concrete, may also be mechanically ground down and reduced to finely divided mineral dust.
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Friability
Summary
Friability
However, such substances are not generally considered friable because of the degree of difficulty involved in breaking the substance's chemical bonds through mechanical means. Some substances, such as polyurethane foams, show an increase in friability with exposure to ultraviolet radiation, as in sunlight. Friable is sometimes used metaphorically to describe "brittle" personalities who can be "rubbed" by seemingly-minor stimuli to produce extreme emotional responses.
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Galfenol
Summary
Galfenol
In materials science, galfenol is the general term for an alloy of iron and gallium. The name was first given to iron-gallium alloys by United States Navy researchers in 1998 when they discovered that adding gallium to iron could amplify iron's magnetostrictive effect up to tenfold. Galfenol is of interest to sonar researchers because magnetostrictor materials are used to detect sound, and amplifying the magnetostrictive effect could lead to better sensitivity of sonar detectors. Galfenol is also proposed for vibrational energy harvesting, actuators for precision machine tools, active anti-vibration systems, and anti-clogging devices for sifting screens and spray nozzles.
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Galfenol
Summary
Galfenol
Galfenol is machinable and can be produced in sheet and wire form.In 2009, scientists from Virginia Polytechnic Institute and State University, and National Institute of Standards and Technology (NIST) used neutron beams to determine the structure of galfenol. They determined that the addition of gallium changes the lattice structure of the iron atoms from regular cubic cells to one in which the faces of some of the cells become slightly rectangular. The elongated cells tend to clump together in the alloy, forming localized clumps within the material.
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Galfenol
Summary
Galfenol
These clumps have been described by Peter Gehring of the NIST Center for Neutron Research as "something like raisins within a cake". It has also been proposed that there is an intrinsic mechanism generating this enhanced magnetostriction, which has its origins in the electronic structure of the material as described by density functional theory. It is understood that the addition of gallium to pure iron alters the electronic structure and atomic arrangements in the material in such a way as to enhance the material's magnetoelastic constant.
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Grain growth
Summary
Grain_growth
In materials science, grain growth is the increase in size of grains (crystallites) in a material at high temperature. This occurs when recovery and recrystallisation are complete and further reduction in the internal energy can only be achieved by reducing the total area of grain boundary. The term is commonly used in metallurgy but is also used in reference to ceramics and minerals. The behaviors of grain growth is analogous to the coarsening behaviors of grains, which implied that both of grain growth and coarsening may be dominated by the same physical mechanism.
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Grain refining
Summary
Grain_refining
In materials science, grain-boundary strengthening (or Hall–Petch strengthening) is a method of strengthening materials by changing their average crystallite (grain) size. It is based on the observation that grain boundaries are insurmountable borders for dislocations and that the number of dislocations within a grain has an effect on how stress builds up in the adjacent grain, which will eventually activate dislocation sources and thus enabling deformation in the neighbouring grain as well. By changing grain size, one can influence the number of dislocations piled up at the grain boundary and yield strength. For example, heat treatment after plastic deformation and changing the rate of solidification are ways to alter grain size.
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Hardness tester
Summary
Hardness_tests
In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard metals such as titanium and beryllium are harder than soft metals such as sodium and metallic tin, or wood and common plastics. Macroscopic hardness is generally characterized by strong intermolecular bonds, but the behavior of solid materials under force is complex; therefore, hardness can be measured in different ways, such as scratch hardness, indentation hardness, and rebound hardness. Hardness is dependent on ductility, elastic stiffness, plasticity, strain, strength, toughness, viscoelasticity, and viscosity. Common examples of hard matter are ceramics, concrete, certain metals, and superhard materials, which can be contrasted with soft matter.
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Intergranular corrosion
Summary
Sensitization_effect
In materials science, intergranular corrosion (IGC), also known as intergranular attack (IGA), is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides. (Cf. transgranular corrosion.)
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Lamellar structure
Summary
Lamellar_structure
In materials science, lamellar structures or microstructures are composed of fine, alternating layers of different materials in the form of lamellae. They are often observed in cases where a phase transition front moves quickly, leaving behind two solid products, as in rapid cooling of eutectic (such as solder) or eutectoid (such as pearlite) systems. Such conditions force phases of different composition to form but allow little time for diffusion to produce those phases' equilibrium compositions. Fine lamellae solve this problem by shortening the diffusion distance between phases, but their high surface energy makes them unstable and prone to break up when annealing allows diffusion to progress.
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Lamellar structure
Summary
Lamellar_structure
A deeper eutectic or more rapid cooling will result in finer lamellae; as the size of an individual lamellum approaches zero, the system will instead retain its high-temperature structure. Two common cases of this include cooling a liquid to form an amorphous solid, and cooling eutectoid austenite to form martensite. In biology, normal adult bones possess a lamellar structure which may be disrupted by some diseases. == References ==
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Liquefaction
Summary
Liquefaction
In materials science, liquefaction is a process that generates a liquid from a solid or a gas or that generates a non-liquid phase which behaves in accordance with fluid dynamics. It occurs both naturally and artificially. As an example of the latter, a "major commercial application of liquefaction is the liquefaction of air to allow separation of the constituents, such as oxygen, nitrogen, and the noble gases." Another is the conversion of solid coal into a liquid form usable as a substitute for liquid fuels.
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Material failure theory
Material failure
Material_failure_theory > Material failure
In materials science, material failure is the loss of load carrying capacity of a material unit. This definition introduces to the fact that material failure can be examined in different scales, from microscopic, to macroscopic. In structural problems, where the structural response may be beyond the initiation of nonlinear material behaviour, material failure is of profound importance for the determination of the integrity of the structure. On the other hand, due to the lack of globally accepted fracture criteria, the determination of the structure's damage, due to material failure, is still under intensive research.
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Metallic elements
Refractory metal
Metal_manufacturing > Categories > Refractory metal
In materials science, metallurgy, and engineering, a refractory metal is a metal that is extraordinarily resistant to heat and wear. Which metals belong to this category varies; the most common definition includes niobium, molybdenum, tantalum, tungsten, and rhenium. They all have melting points above 2000 °C, and a high hardness at room temperature.
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Misorientation
Summary
Misorientation
In materials science, misorientation is the difference in crystallographic orientation between two crystallites in a polycrystalline material. In crystalline materials, the orientation of a crystallite is defined by a transformation from a sample reference frame (i.e. defined by the direction of a rolling or extrusion process and two orthogonal directions) to the local reference frame of the crystalline lattice, as defined by the basis of the unit cell. In the same way, misorientation is the transformation necessary to move from one local crystal frame to some other crystal frame. That is, it is the distance in orientation space between two distinct orientations.
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Misorientation
Summary
Misorientation
If the orientations are specified in terms of matrices of direction cosines gA and gB, then the misorientation operator ∆gAB going from A to B can be defined as follows: g B = Δ g A B g A Δ g A B = g B g A − 1 {\displaystyle {\begin{aligned}&g_{B}=\Delta g_{AB}g_{A}\\&\Delta g_{AB}=g_{B}g_{A}^{-1}\end{aligned}}} where the term g A − 1 {\displaystyle g_{A}^{-1}} is the reverse operation of gA, that is, transformation from crystal frame A back to the sample frame. This provides an alternate description of misorientation as the successive operation of transforming from the first crystal frame (A) back to the sample frame and subsequently to the new crystal frame (B). Various methods can be used to represent this transformation operation, such as: Euler angles, Rodrigues vectors, axis/angle (where the axis is specified as a crystallographic direction), or unit quaternions.
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Paracrystallinity
Summary
Paracrystallinity
In materials science, paracrystalline materials are defined as having short- and medium-range ordering in their lattice (similar to the liquid crystal phases) but lacking crystal-like long-range ordering at least in one direction.
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Permeance
Materials science
Permeance > Materials science
In materials science, permeance is the degree to which a material transmits another substance.
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Polymorphism (crystallography)
Summary
Polymorph_(mineralogy)
In materials science, polymorphism describes the existence of a solid material in more than one form or crystal structure. Polymorphism is a form of isomerism. Any crystalline material can exhibit the phenomenon. Allotropy refers to polymorphism for chemical elements.
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Polymorphism (crystallography)
Summary
Polymorph_(mineralogy)
Polymorphism is of practical relevance to pharmaceuticals, agrochemicals, pigments, dyestuffs, foods, and explosives. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure." According to McCrone, polymorphs are "different in crystal structure but identical in the liquid or vapor states." Materials with two polymorphs are called dimorphic, with three polymorphs, trimorphic, etc.In some cases, polymorphism was "discovered" on a computer by crystal structure prediction first, before chemists actually synthesize the crystal in the lab.
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Quenching
Summary
Quenching
In materials science, quenching is the rapid cooling of a workpiece in water, oil, polymer, air, or other fluids to obtain certain material properties. A type of heat treating, quenching prevents undesired low-temperature processes, such as phase transformations, from occurring. It does this by reducing the window of time during which these undesired reactions are both thermodynamically favorable, and kinetically accessible; for instance, quenching can reduce the crystal grain size of both metallic and plastic materials, increasing their hardness. In metallurgy, quenching is most commonly used to harden steel by inducing a martensite transformation, where the steel must be rapidly cooled through its eutectoid point, the temperature at which austenite becomes unstable.
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Quenching
Summary
Quenching
In steel alloyed with metals such as nickel and manganese, the eutectoid temperature becomes much lower, but the kinetic barriers to phase transformation remain the same. This allows quenching to start at a lower temperature, making the process much easier. High-speed steel also has added tungsten, which serves to raise kinetic barriers, which among other effects gives material properties (hardness and abrasion resistance) as though the workpiece had been cooled more rapidly than it really has. Even cooling such alloys slowly in air has most of the desired effects of quenching; high-speed steel weakens much less from heat cycling due to high-speed cutting.Extremely rapid cooling can prevent the formation of all crystal structures, resulting in amorphous metal or "metallic glass".
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Radar absorbent material
Summary
Radar-absorbent_material
In materials science, radiation-absorbent material (RAM) is a material which has been specially designed and shaped to absorb incident RF radiation (also known as non-ionising radiation), as effectively as possible, from as many incident directions as possible. The more effective the RAM, the lower the resulting level of reflected RF radiation. Many measurements in electromagnetic compatibility (EMC) and antenna radiation patterns require that spurious signals arising from the test setup, including reflections, are negligible to avoid the risk of causing measurement errors and ambiguities.
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Recrystallization temperature
Summary
Recrystallization_temperature
In materials science, recrystallization is a process by which deformed grains are replaced by a new set of defect-free grains that nucleate and grow until the original grains have been entirely consumed. Recrystallization is usually accompanied by a reduction in the strength and hardness of a material and a simultaneous increase in the ductility. Thus, the process may be introduced as a deliberate step in metals processing or may be an undesirable byproduct of another processing step. The most important industrial uses are softening of metals previously hardened or rendered brittle by cold work, and control of the grain structure in the final product. Recrystallization temperature is typically 0.3–0.4 times the melting point for pure metals and 0.5 times for alloys.
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Reinforcement (composite)
Summary
Reinforcement_(composite)
In materials science, reinforcement is a constituent of a composite material which increases the composite's stiffness and tensile strength.
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Segregation in materials
Summary
Segregation_in_materials
In materials science, segregation is the enrichment of atoms, ions, or molecules at a microscopic region in a materials system. While the terms segregation and adsorption are essentially synonymous, in practice, segregation is often used to describe the partitioning of molecular constituents to defects from solid solutions, whereas adsorption is generally used to describe such partitioning from liquids and gases to surfaces. The molecular-level segregation discussed in this article is distinct from other types of materials phenomena that are often called segregation, such as particle segregation in granular materials, and phase separation or precipitation, wherein molecules are segregated in to macroscopic regions of different compositions. Segregation has many practical consequences, ranging from the formation of soap bubbles, to microstructural engineering in materials science, to the stabilization of colloidal suspensions.
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Segregation in materials
Summary
Segregation_in_materials
Segregation can occur in various materials classes. In polycrystalline solids, segregation occurs at defects, such as dislocations, grain boundaries, stacking faults, or the interface between two phases. In liquid solutions, chemical gradients exist near second phases and surfaces due to combinations of chemical and electrical effects. Segregation which occurs in well-equilibrated systems due to the instrinsic chemical properties of the system is termed equilibrium segregation. Segregation that occurs due to the processing history of the sample (but that would disappear at long times) is termed non-equilibrium segregation.
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Modulus of rigidity
Summary
Modulus_of_rigidity
In materials science, shear modulus or modulus of rigidity, denoted by G, or sometimes S or μ, is a measure of the elastic shear stiffness of a material and is defined as the ratio of shear stress to the shear strain: G = d e f τ x y γ x y = F / A Δ x / l = F l A Δ x {\displaystyle G\ {\stackrel {\mathrm {def} }{=}}\ {\frac {\tau _{xy}}{\gamma _{xy}}}={\frac {F/A}{\Delta x/l}}={\frac {Fl}{A\Delta x}}} where τ x y = F / A {\displaystyle \tau _{xy}=F/A\,} = shear stress F {\displaystyle F} is the force which acts A {\displaystyle A} is the area on which the force acts γ x y {\displaystyle \gamma _{xy}} = shear strain. In engineering := Δ x / l = tan ⁡ θ {\displaystyle :=\Delta x/l=\tan \theta } , elsewhere := θ {\displaystyle :=\theta } Δ x {\displaystyle \Delta x} is the transverse displacement l {\displaystyle l} is the initial length of the area.The derived SI unit of shear modulus is the pascal (Pa), although it is usually expressed in gigapascals (GPa) or in thousand pounds per square inch (ksi). Its dimensional form is M1L−1T−2, replacing force by mass times acceleration.
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Slip (materials science)
Summary
Slip_(materials_science)
In materials science, slip is the large displacement of one part of a crystal relative to another part along crystallographic planes and directions. Slip occurs by the passage of dislocations on close/packed planes, which are planes containing the greatest number of atoms per area and in close-packed directions (most atoms per length). Close-packed planes are known as slip or glide planes.
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Slip (materials science)
Summary
Slip_(materials_science)
A slip system describes the set of symmetrically identical slip planes and associated family of slip directions for which dislocation motion can easily occur and lead to plastic deformation. The magnitude and direction of slip are represented by the Burgers vector, b. An external force makes parts of the crystal lattice glide along each other, changing the material's geometry. A critical resolved shear stress is required to initiate a slip.
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Stress relaxation
Summary
Stress_relaxation
In materials science, stress relaxation is the observed decrease in stress in response to strain generated in the structure. This is primarily due to keeping the structure in a strained condition for some finite interval of time hence causing some amount of plastic strain. This should not be confused with creep, which is a constant state of stress with an increasing amount of strain. Since relaxation relieves the state of stress, it has the effect of also relieving the equipment reactions.
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Stress relaxation
Summary
Stress_relaxation
Thus, relaxation has the same effect as cold springing, except it occurs over a longer period of time. The amount of relaxation which takes place is a function of time, temperature and stress level, thus the actual effect it has on the system is not precisely known, but can be bounded. Stress relaxation describes how polymers relieve stress under constant strain.
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Stress relaxation
Summary
Stress_relaxation
Because they are viscoelastic, polymers behave in a nonlinear, non-Hookean fashion. This nonlinearity is described by both stress relaxation and a phenomenon known as creep, which describes how polymers strain under constant stress.
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Stress relaxation
Summary
Stress_relaxation
Experimentally, stress relaxation is determined by step strain experiments, i.e. by applying a sudden one-time strain and measuring the build-up and subsequent relaxation of stress in the material (see figure), in either extensional or shear rheology. Viscoelastic materials have the properties of both viscous and elastic materials and can be modeled by combining elements that represent these characteristics. One viscoelastic model, called the Maxwell model predicts behavior akin to a spring (elastic element) being in series with a dashpot (viscous element), while the Voigt model places these elements in parallel.
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Stress relaxation
Summary
Stress_relaxation
Although the Maxwell model is good at predicting stress relaxation, it is fairly poor at predicting creep. On the other hand, the Voigt model is good at predicting creep but rather poor at predicting stress relaxation (see viscoelasticity). The extracellular matrix and most tissues are stress relaxing, and the kinetics of stress relaxation have been recognized as an important mechanical cue that affects the migration, proliferation, and differentiation of embedded cells.Stress relaxation calculations can differ for different materials: To generalize, Obukhov uses power dependencies: σ ( t ) = σ 0 1 − {\displaystyle \sigma (t)={\frac {\sigma _{0}}{1-}}} where σ 0 {\displaystyle \sigma _{0}} is the maximum stress at the time the loading was removed (t*), and n is a material parameter. Vegener et al. use a power series to describe stress relaxation in polyamides: σ ( t ) = ∑ m , n A m n m ( ϵ 0 ′ ) n {\displaystyle \sigma (t)=\sum _{m,n}^{}{A_{mn}^{m}(\epsilon '_{0})^{n}}} To model stress relaxation in glass materials Dowvalter uses the following: σ ( t ) = 1 b ⋅ log ⁡ 10 α ( t − t n ) + 1 10 α ( t − t n ) − 1 {\displaystyle \sigma (t)={\frac {1}{b}}\cdot \log {\frac {10^{\alpha }(t-t_{n})+1}{10^{\alpha }(t-t_{n})-1}}} where α {\displaystyle \alpha } is a material constant and b and t n {\displaystyle t_{n}} depend on processing conditions. The following non-material parameters all affect stress relaxation in polymers: Magnitude of initial loading Speed of loading Temperature (isothermal vs non-isothermal conditions) Loading medium Friction and wear Long-term storage
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Superplastic deformation
Summary
Superplasticity
In materials science, superplasticity is a state in which solid crystalline material is deformed well beyond its usual breaking point, usually over about 400% during tensile deformation. Such a state is usually achieved at high homologous temperature. Examples of superplastic materials are some fine-grained metals and ceramics. Other non-crystalline materials (amorphous) such as silica glass ("molten glass") and polymers also deform similarly, but are not called superplastic, because they are not crystalline; rather, their deformation is often described as Newtonian fluid.
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Superplastic deformation
Summary
Superplasticity
Superplastically deformed material gets thinner in a very uniform manner, rather than forming a "neck" (a local narrowing) that leads to fracture. Also, the formation of microvoids, which is another cause of early fracture, is inhibited. Superplasticity must not be confused with superelasticity.
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Burgers vector
Summary
Burgers_vector
In materials science, the Burgers vector, named after Dutch physicist Jan Burgers, is a vector, often denoted as b, that represents the magnitude and direction of the lattice distortion resulting from a dislocation in a crystal lattice. The vector's magnitude and direction is best understood when the dislocation-bearing crystal structure is first visualized without the dislocation, that is, the perfect crystal structure. In this perfect crystal structure, a rectangle whose lengths and widths are integer multiples of a (the unit cell edge length) is drawn encompassing the site of the original dislocation's origin. Once this encompassing rectangle is drawn, the dislocation can be introduced.
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Burgers vector
Summary
Burgers_vector
This dislocation will have the effect of deforming, not only the perfect crystal structure, but the rectangle as well. The said rectangle could have one of its sides disjoined from the perpendicular side, severing the connection of the length and width line segments of the rectangle at one of the rectangle's corners, and displacing each line segment from each other. What was once a rectangle before the dislocation was introduced is now an open geometric figure, whose opening defines the direction and magnitude of the Burgers vector.