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dc948c599976bad88a47b3cd353007a4fa37ca9c | ## Key Contributions
- **Novel materials or compounds**: Nanoceria-based sorbents for enhanced sorption of low specific activity [99]Mo.
- **Unique synthesis methods**: Development of CeO2 nanoparticles using wet chemical precipitation and hydrothermal approaches.
- **Specific applications or domains**: Potential application in the development of [99]Mo/[99m]Tc generators for nuclear medicine. | ## Materials
- **Precursor Materials**:
- Cerium nitrate hexahydrate (Ce(NO3)3·6H2O): 2 g.
- Sodium hydroxide: 0.4 M solution.
- **Solvents**:
- Milli-Q water.
- Ethanol absolute (1:4 v/v with water for chemical precipitation, 4:1 v/v for hydrothermal method).
- **Reagents**:
- Nitric acid (HNO3).
- 1 M NaOH solution for adjusting pH.
- **Specifications**:
- All chemicals of analytical grade from Merck, Darmstadt, Germany.
## Synthesis Equipment
- **Centrifuge**: Used at 4000 rpm for 15 minutes.
- **Drying Oven**: Temperature range of 50–70 °C for 12 hours.
- **Teflon-lined Stainless Steel Autoclave**: Used for hydrothermal synthesis at 150 °C for 12 hours.
## Synthesis Procedure
### Wet Chemical Precipitation
1. Dissolve 2 g of Ce(NO3)3·6H2O in a mixture of Milli-Q water and ethanol (1:4 v/v).
2. Add the solution drop-wise to a 0.4 M sodium hydroxide solution under continuous stirring, maintaining pH ~11.
3. Stir until a yellow suspension forms (~30 min).
4. Wash the precipitate with de-ionized water and ethanol; centrifuge and dry at 50–70 °C for 12 h.
5. Denote the sample as CP (Chemical Precipitation).
### Hydrothermal Modification
1. Transfer the precipitated NPs into a Teflon-lined stainless-steel autoclave.
2. Seal and maintain at 150 °C for 12 hours.
3. Wash, centrifuge, and dry the precipitate at 70 °C for 12 h.
4. Denote the sample as HT (Hydrothermal Treatment).
## Characterization Methods and Equipment
- **X-ray Powder Diffraction (XRD)**: D8 ADVANCE diffractometer (Bruker AXS) with Cu-Kα radiation. 2θ = 10–80° at room temperature.
- **BET Surface Area Measurement**: Gemini VII, ASAP 2020 (Micromeritics Instrument) using nitrogen sorption isotherms at −195 °C after a 12 h degas at 110 °C.
- **Zeta Potential Measurements**: Zeta-sizer (Nano ZS, Malvern, UK).
- **Field Emission Scanning Electron Microscopy (FE-SEM)**: JSM-7100F (JEOL).
## Product Characteristics
- **Final Product**: CeO2 nanoparticles.
- **Sorption Capacities**:
- HT-1: 192 ± 10 mg Mo·g^−1
- CP-2: 184 ± 12 mg Mo·g^−1
- **Morphological Characteristics**: Mesoporous structure with a spherical morphology in hydrothermally treated samples and a rough morphology in chemically precipitated samples. | [
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035cfeb4113531037c19e8251c43eb6073384404 | ## Key Contributions
- **Novel materials or compounds:** Epoxy-functional diblock copolymer nano-objects (spheres, worms, vesicles) synthesized via RAFT aqueous emulsion polymerization using glycidyl methacrylate.
- **Unique synthesis methods:** Utilization of RAFT aqueous emulsion polymerization under mild conditions to preserve epoxy groups and target specific nano-object morphologies. Epoxy-thiol chemistry for derivatization.
- **Specific applications or domains:** Potential applications in material science for creating stable nanoparticles with preserved functional groups for further chemical modifications. | ## Materials
- **Precursor Materials:**
- **Glycerol monomethacrylate (GMA):** Donated by GEO Specialty Chemicals, used without further purification.
- **Glycidyl methacrylate (GlyMA):** 97%, purchased from Sigma-Aldrich (UK).
- **4,4′-azobis(4-cyanopentanoic acid) (ACVA):** 99%, Sigma-Aldrich.
- **2,2′-azobisisobutyronitrile (AIBN):** 98%, Sigma-Aldrich.
- **2-Cyano-2-propyl dithiobenzoate (CPDB):** Strem Chemicals Ltd (Cambridge, UK).
- **VA-044 initiator:** ≥97%.
- **L-cysteine:** 97%, Sigma-Aldrich.
- **Solvents and Reagents:**
- **Hexane (HPLC grade):** ≥97%, Sigma-Aldrich.
- **Sodium hydroxide (NaOH):** 98%, Sigma-Aldrich.
- **Concentrated hydrochloric acid (32%):** Fisher Scientific.
- **Deionised Water.**
## Synthesis Equipment
- **General Equipment:**
- **Round-bottomed flask, magnetic stirrer, ice bath, nitrogen gas setup, oil bath, vacuum oven, high vacuum manifold.**
- **Characterization Equipment:**
- **1H NMR Spectrometer:** Bruker Avance III HD 400 MHz.
- **Dynamic Light Scattering (DLS):** Malvern Zetasizer NanoZS.
- **Gel Permeation Chromatography (GPC):** Agilent 1260 Infinity system with Agilent PL gel 5 μm Mixed-C columns.
- **Transmission Electron Microscopy (TEM):** FEI Tecnai Spirit 2 microscope.
- **Small Angle X-ray Scattering (SAXS):** ESRF station ID02 (Grenoble, France) and Diamond Light Source station I22 (Didcot, UK).
## Synthesis Procedure
### Synthesis of PGMA28
1. **Preparation:**
- Mix CPDB (2.79 g, 12.6 mmol) with GMA (50.0 g, 0.312 mol) and ethanol (80.2 g).
- Cool in ice bath, degas with N2 for 40 min.
2. **Reaction:**
- Polymerize at 70 °C for 160 min; conversion 63%.
3. **Purification:**
- Dilute with methanol, precipitate in dichloromethane, redissolve, precipitate again.
### Synthesis of PGMA28-PGlyMAn Diblock Copolymer Nano-objects
1. **Preparation:**
- Weigh PGMA28 macro-CTA (0.25 g, 0.053 mmol) and add deionised water (9.09 g).
- Add VA-044 (4.30 mg, 0.013 mmol), adjust pH to 7.0–7.5.
2. **Reaction:**
- Add GlyMA (0.756 g, 5.32 mmol), degas with N2, polymerize at 50 °C for 1 h.
3. **Quenching:**
- Remove from oil bath, expose to air.
### Derivatisation with L-cysteine
1. **Dilution:**
- Dilute a 20% w/w dispersion to 5% w/w.
2. **Reaction:**
- Add excess L-cysteine (molar ratio 10), adjust pH to 8.5, react for 24 h at 20 °C.
3. **Purification:**
- Dialysis to remove unreacted L-cysteine, freeze-dry.
## Characterization Methods and Equipment
- **1H NMR Spectroscopy:** Bruker Avance III HD 400 MHz for structural analysis.
- **DLS and GPC:** For particle size and molecular weight distribution.
- **TEM and SAXS:** For morphology and structure assessment.
- **Elemental Microanalysis:** Vario MICRO Cube CHN/S analyser.
- **Rheology and Electrophoresis:** For physical properties and stability.
## Product Characteristics
- **Morphologies:** Spheres, worms, vesicles confirmed by TEM and SAXS.
- **Epoxy Functional Stability:** 90% retention after 6 weeks, reducing to 74% over 12 weeks.
- **Derivatisation Efficiency:** Up to 91% conversion with L-cysteine, variably depending on morphology. | [
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6e606d85d689a4e63fe51a3008affceb1358079c | ## Key Contributions
- Novel materials or compounds: Silicon/Zinc oxide heterostructure nanowires
- Unique synthesis methods: Vapor transport and condensation with In catalyst
- Specific applications or domains: Photoluminescence studies, nanophotonics, and nanoelectronics | ## Materials
- **Precursor Materials:**
- In catalysts with sizes ranging from 40 to 100 nm (prior coating)
- Silane gas diluted in hydrogen (H2) gas in a ratio of 1:20 (5:100 sccm) for Si NWs synthesis
- In wire: 1.3 ± 0.1 mg (hung on a tungsten filament)
- ZnO powder mixed with graphite in a 1:1 ratio, total 0.2 g
- **Carrier Gases:**
- Hydrogen (H2) for Si NWs synthesis
- Nitrogen (N2) for ZnO deposition (tube setup with one end open and the other connected to N2 inlet)
## Synthesis Equipment
- **Vapor Transport and Condensation Setup:**
- Home-built plasma-assisted hot-wire chemical vapor deposition system
- Quartz tube furnace (for ZnO deposition)
- Tungsten filament (for In evaporation), filament temperature ~ 1,200°C
- N2 gas inlet system
## Synthesis Procedure
- **Si NWs Synthesis:**
1. Si NWs synthesized on a p-type Si(111) using plasma-assisted HWCVD with In catalysts.
2. Silane gas diluted with H2 used with a flow ratio of 5:100 sccm.
3. In wire (1.3 ± 0.1 mg) evaporated at ~1,200°C on a tungsten filament above the substrate under H2 plasma (100 sccm, 40 W).
- **ZnO Nanostructures Growth:**
1. Transfer the In-coated Si NWs to a quartz tube furnace.
2. Place a ZnO and graphite powder mixture (0.2 g, 1:1 ratio) at the hot zone center.
3. Position the substrate 12 cm from the powder, heat to ~1,100°C.
4. Different growth durations (0.5 to 2 hours), observe density and morphology changes.
## Characterization Methods and Equipment
- **Field Emission Scanning Electron Microscopy (FESEM):** Hitachi SU 8000 for morphology
- **Energy Dispersive X-ray (EDX) Spectroscopy:** EDAX Apollo XL SDD detector for composition
- **High-resolution Transmission Electron Microscopy (HRTEM):** JEOL JEM 2100F for structural analysis
- **X-ray Diffraction (XRD):** SIEMENS D5000 at grazing angle 5° for crystallinity
- **Photoluminescence (PL) Spectroscopy:** Renishaw InVia with 325 nm He-Cd laser for optical properties
## Product Characteristics
- **Final Product:**
- Average NW base and tip diameters: ~100 nm and ~20 nm
- ZnO NRs with mean diameter of 32 ± 10 nm
- Morphology: NPs decorated to core-shell to hierarchical core-shell based on ZnO growth times
- **Optical Properties:**
- PL spectra: Broad range 400 to 750 nm, with defect emissions and enhanced near band edge
- **Structural Properties:**
- ZnO wurtzite structure, preferential growth along [0001] for NRs
- **Yield and Purity:** N/A | [
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e6998dc79426cf42ddabfa2ac36c4794088e3247 | ## Key Contributions
- Novel materials or compounds: Bio-based polyesters derived from curcumin as an inherent natural diol monomer.
- Unique synthesis methods: Utilization of curcumin as a monomer in polyester synthesis through polycondensation with acid chlorides.
- Specific applications or domains: Potential use in photodegradable polymer applications and polymer-metal complexes for functional materials. | ## Materials
- Curcumin:
* Purity: Recrystallized in 2-propanol
* Supplier: Tokyo Chemical Industry Co. Ltd. (TCI)
- Sebacoyl chloride
- Suberoyl chloride
- Solvents:
* Chloroform
* Toluene
* Chlorobenzene
* Dichloromethane
- Triethylamine
- n-Hexane
## Synthesis Equipment
- N/A (The paper does not specify any particular equipment models or configurations)
## Synthesis Procedure
1. Prepare an equimolar suspension of curcumin in chloroform.
2. Add a chloroform solution of sebacoyl chloride to the suspension at 0°C in the presence of 2.0 equivalents of triethylamine under a nitrogen atmosphere.
3. Stir the resulting mixture for 1 hour at room temperature.
4. Filter to remove any insoluble precipitate.
5. Reprecipitate the crude polymer in n-hexane twice.
6. Dissolve the obtained polymer in chloroform and wash with water three times.
7. Remove the solvent to obtain the polyester.
## Characterization Methods and Equipment
- Gel permeation chromatography:
* Conditions: Chloroform as eluent, polystyrene standards.
- NMR Spectroscopy:
* Techniques: ^1H NMR, ^13C NMR
* Solvent: CDCl3
- UV-vis absorption spectra
## Product Characteristics
- Molecular Weight: Mn ranged from 5000 to 32000
- Efficiency: Yield of up to 68%
- Solubility: Soluble in common organic solvents like dichloromethane and chloroform
- Physical appearance: Yellow-orange colored polymer, yellowish transparent film upon casting. | [
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268010866620f9c4a0f1e18f44b44982a7ac1e29 | "## Key Contributions\n\n- Novel materials or compounds: Polyvinyl alcohol (PVA) crosslinked with gl(...TRUNCATED) | "## Materials\n- Polyvinyl alcohol (PVA, MW = 85,000–124,000 g/mol) - Sigma-Aldrich, St. Louis, MO(...TRUNCATED) | [-0.013861132,0.010613595,-0.029986829,-0.033147268,0.01142859,0.007857544,-0.017519277,-0.016648289(...TRUNCATED) |
41b869d11327e459eb9523f907f3f739ae986795 | "## Key Contributions\n- Novel materials or compounds: Dual stimuli-responsive poly(N-isopropylacryl(...TRUNCATED) | "## Materials\n- **Precursors:**\n - 2-bromoethanol (95.0%)\n - 2,3,3-trimethyl-3H-indol (97.0%)\n(...TRUNCATED) | [-0.042213637,0.011630682,-0.020590758,-0.025957774,0.033492237,0.024035454,-0.030576503,-0.01628166(...TRUNCATED) |
263c34bb148011a0c857cfc63cc7f2de620a21db | "## Key Contributions\n- Novel materials or compounds: Ce-Zr mixed oxide catalysts (CexZr1-xO2) with(...TRUNCATED) | "## Materials\n- **Precursors:**\n - Cerium(III) nitrate hexahydrate (Ce(NO3)3·6H2O), 99.0%, Sigma(...TRUNCATED) | [0.0022441067,-0.027580902,-0.027235143,-0.030825714,-0.02501431,0.009601451,-0.05526819,-0.00509329(...TRUNCATED) |
5da9579d88a83807c718c61b50283814a32ff23c | "## Novel Materials or Compounds\n- Two types of porous coordination cages (PCCs) were developed: PC(...TRUNCATED) | "## Materials\n- **PCC-4 Synthesis**:\n - Cobalt chloride hexahydrate: 23.7 mg, 0.1 mmol\n - 2,4,6(...TRUNCATED) | [-0.014449002,0.01220975,-0.02258427,-0.020009471,0.012189206,0.011744094,-0.06042559,-0.018009894,-(...TRUNCATED) |
3b2d42e5a89f5c9acba839a2646af69a12377766 | "## Key Contributions\n- Novel materials or compounds: Pure chromium coatings using PVD techniques.\(...TRUNCATED) | "## Materials\n- High-purity chromium target materials: \n * Dimensions are 300 mm × 100 mm and ϕ(...TRUNCATED) | [-0.002013853,-0.013473152,-0.033930372,-0.057337176,-0.0018528126,0.027353143,-0.020884402,-0.01004(...TRUNCATED) |
2ea9c85096f366d3d07ff04843178dc7e3fda289 | "## Key Contributions\n- **Novel materials or compounds**: Methyl cellulose and magnesium acetate te(...TRUNCATED) | "## Materials\n- **Precursor materials**:\n - Methyl Cellulose with a viscosity of 350-550 cps from(...TRUNCATED) | [0.008045287,0.019969083,-0.022838656,-0.012716532,-0.01057418,0.018226374,-0.027070949,-0.01053487,(...TRUNCATED) |
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