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===================== Product Identification ===================== Product ID:SODIUM CHLORIDE CAGE:016E9 CAGE:016E9 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CHLORIDE CAS:7647-14-5 RTECS #:VZ4725000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINS. SKIN: IMMEDIATELY WASH W/SOAP & COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR. IF BREATH ING IS DIFFICULT GIVE OXYGEN. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT . SWEEP UP PLACE IN A BAG FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & WASH SITE AFTER PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE. ============= Exposure Controls/Personal Protection ============= Work Hygienic Practices:DON'T GET IN EYES, ON SKIN, ON CLOTHING. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health WASTE DISPOSAL CONTD: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:1473.8F Spec Gravity:2.165 Appearance and Odor:WHITE ODORLESS SOLUBLE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, BROMINE TRIFLOMIDE & LITHIUM. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL: ADD TO A LARGE STIRRED EXCESS OF WATER. ADJUS TTHE PH TO NEUTRAL, SEPERATE ANY INSOLUBLE SOLIDS/LIQUIDS & PACKAGE THEM FOR HAZARRDOUS-WASTE DISPOSAL. FLUSH AQUEOUS SOLUTION DOWN THE DRAIN W/PLE NTY OF WATER. (SEE SUPP)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:K-BOND MORTAR CAGE:U0390 CAGE:U0390 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:PRLNG/RPTD INHAL OF RESP FREE CRYSTALLINE SILICA MAY CAUSE DELAYED LUNG INJURY (SILICOSIS). EXPOS TO NUISANCE DUST MAY CAUSE TEMPORARY IRRIT/DISCOMFORT OF NOSE, THROAT, LUNGS & MAY AGGRAVATE BRONCHIAL DISORDERS. PRODS CONTAIN MINOR AMTS OFORG &/INORG BINDERS WHICH BURN OUT DURING FIRST HEAT-UP.(EFTS OF OVEREXP) Explanation of Carcinogenicity:CRYSTALLINE SILICA:IARC GRP 2A, NTP GROUP 2. Effects of Overexposure:HLTH HAZ: DUSTS MAY CAUSE EYE AND RESPIRATORY IRRITATION. Medical Cond Aggravated by Exposure:BRONCHIAL DISORDERS, ASTHMA, EMPHYSEMA. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. INGEST: DRINK PLENTY OF WATER. SKIN: WASH WITH MILD SOAP AND WATER. EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, CALL MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:FOLLOW ROUTINE HOUSEKEEPING PROCEDURES. COLLECT SPILLED PRODUCT IN CLOSED CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:APPROPRIATE VENTILATION AND RESPIRATORY PROTECTION SHOULD BE PROVIDED IN COMPLIANCE W/OSHA STDS 29CFR 1910.94 & . 134. Other Precautions:AS MANUF, PRODS ARE ALUMINOSILICATES WHICH MAY TRANSFORM UPON HEATING TO MULLITE & CRISTOBALITE (FORM OF CRYSTALINE SILICA). REMOVAL OF PRODS AFTER SERVICE MAY GEN DUST. RPTD INHAL OF RESP FREE CRYSTA LLINE SILICA DUST MAY CAUSE (SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST RESPIRATOR IN COMPLIANCE WITH OSHA STD 29 CFR 1910.134: (NIOSH/MSHA APPRVD AIR PURIFYING, HALF MASK OR FULL FACEPIECE RESPIRATOR WITH APPROPRIATE FILTER PAD OR CARTRIDGE). Ventilation:LOCAL EXHAUST & MECHANICAL(GENERAL) EXHAUST. FOLLOW OSHA STD 29 CFR 1910.94. Other Protective Equipment:AS REQUIRED TO MEET APPLICABLE OSHA STANDARDS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health OTHER PREC: DELAYED LUNG INJURY(SILICOSIS). FOR FURTHER INFORMATION SEE THERMAL CERAMICS' PUBLICATION "HEALTH & SAFETY ASPECTS OF CRYSTALLINE SILICA"(8/89). ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.7-2.5 Solubility in Water:INSOLUBLE Appearance and Odor:COLOR VARIES DEPENDING ON PRODUCT. NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTES ARE NOT HAZARDOUS WASTES AS DEFINED BY RCRA (40CFR 261). COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS. METHOD OF DISPOSAL: LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:T4 CAC RIA KIT (125-I), TKT45 CAGE:5R665 CAGE:5R665 ============= Composition/Information on Ingredients ============= Ingred Name:T4 TRACER SOLUTION (CONSISTING OF INGREDIENTS 2 - 4) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:IODINE; (IODINE-125). %:<5 UCI. CAS:7553-56-2 RTECS #:NN1575000 Fraction by Wt: SEE ING OSHA PEL:0.1 PPM, C ACGIH TLV:0.1 PPM, C Ingred Name:SODIUM AZIDE CAS:26628-22-8 RTECS #:VY8050000 Fraction by Wt: 0.1% G OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BARBITURIC ACID, 5,5-DIETHYL-, SODIUM SALT; (SODIUM BARBITAL) CAS:144-02-5 RTECS #:CQ3850000 Fraction by Wt: 1.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:T4 SERUM STANDARDS A-F (CONSISTING OF INGS 6 - 7) RTECS #:9999999ZZ Fraction by Wt: N/K (F) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SODIUM AZIDE CAS:26628-22-8 RTECS #:VY8050000 Fraction by Wt: 0.1% G OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HUMAN SERUM OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:T4 ANTIBODY - COATED TUBES (CONTAINING NO HAZARDOUS INGREDIENTS) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:SMOKE/APPLY COSMETICS WHERE RADIOACTIVE MATLS ARE USED. DO NOT PIPET RADIOACTIVE SOLNS BY MOUTH. ALL (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:RADIOLOGICAL WORK SHOULD BE DONE IN DESIGNATED AREA AWAY FROM TRAFFIC. RADIOACTIVE MATLS SHOULD BE STORED (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:IN THEIR ORIGINAL CNTNRS IN DESIGNATED AREA. STDS:DO NOT PIPET BY MOUTH. DO NOT EAT, DRINK/SMOKE IN LAB. (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:AVOID SPLASHING OR FORMING AN AEROSOL. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HUMAN SERUM IN WHICH STANDARDS ARE FORMULATED WAS FOUND NEGATIVE FOR HIV ANTIBODY & NONREACTIVE FOR HBSAG WHEN TESTED W/LICENSED REAGENTS. NO KNOWN TEST METHOD CAN OFFER ASSURANCE THAT PRODUCTS DERIVE D FROM HUMAN BLOOD WILL NOT BE INFECTIOUS. HANDLE AS CAPABLE OF TRANSMITTING INFECTION. TRACER:AVOID (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:CONTACT W/EYES, SKIN & CLOTHING. SODIUM BARBITAL IS A LONG DURATION, HYPNOTIC SEDATIVE. SIDE EFFECTS INCLUDE HANGOVER, NAUSEA, HEADACHE, LETHARGY. DRUG DEPENDENCE MAY OCCUR. ORAL DOSE 300-500 MG. RADIOACTIVE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN:REMOVE CONTAMINATED CLOTHING & WASH EXPOSED SKIN THOROUGHLYW/SOAP & WATER. IF SKIN IS BROKEN OR MATL GETS INTO OPEN WOUND, GET MEDICAL ATTENTION. INGEST:FLUSH MOUTH W/WATER, INSURING RINSE IS NOT SWALLOWED. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:TRACER & STDS ARE NON-FLAMM, BUT ARE FORMULATED W/SODIUM AZIDE. SODIUM AZIDE MAY REACT W/LEAD & COPPER PLUMBING TO FORM EXPLO METALLIC AZIDES. IF DRAIN (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:TRACER:ANY RADIOACTIVE SPILLS SHOULD BE TAKEN CARE OF IMMED I/A/W ESTABLISHED PROC. STANDARDS:WIPE UP SPILLS W/ABSORB PAPER. THEN CLEAN SPILL AREA THORO W/5% SODIUM HYPOCHLORITE (CHLOROX) SOLN. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE TRACER, STANDARDS & TUBES AT 2-8C. RESEAL UNUSED TUBES IN PACKAGE. Other Precautions:TRACER:ADHERENCE TO BASIC RULES OF RADIA, SFTY SHOULD PROVIDE ADEQ PROT. USER IS REFERRED TO NATL BUREAU OF STDS HANDBOOK, NO.92, "SAFE HNDLG OF RADIO MATL" ISSUED MARCH 9, 1962. SUPERINTENDENT OF DO CUMENTS, U.S. GOVT PRINTING OFC,(SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:AVOID DIRECT CONTACT W/ALL RADIOACTIVE MATLS BY USING PROTECTIVE ARTICLES SUCH AS LAB COATS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ:DISP, FLUSH W/LG VOL OF RUNNING WATER TO PVNT AZIDE BUILD-UP. WASTE DISP METH:THAT RADIOACTIVE LBLS & LABELING ARE DEFACED. TUBES:DISCARD USED TUBES IN RADIOACTIVE WASTE. STDS:DISCARD ALL MA TLS USED TO WIPE UP SPILL IN BIOHAZ WASTE FOR PROPER DISP. OTHER PREC: WASHINGTON D.C. 20402. DO NOT EAT, DRINK, (ING 9) ================== Physical/Chemical Properties ================== Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . TRACER:ALL RADIOACTIVE MATLS MUST BE DISP OF I/A/W PREVAILING REGS & GUIDELINES OF AGENCIES HOLDING JURISDICTION OVER LAB. UNCONTAM CNTNRS MAY BE DISCA RDED INTO NONRADIOACTIVE WASTE PROVIDING (SUPDAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SLIDE UNIVERSAL RELEASE AEROSOL, 42620 CAGE:16888 CAGE:16888 ============= Composition/Information on Ingredients ============= Ingred Name:TRICHLOROFLUOROMETHANE (CFC-11) (SARA III) CAS:75-69-4 RTECS #:PB6125000 Fraction by Wt: 78% OSHA PEL:1000 PPM ACGIH TLV:C, 1000 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 Ingred Name:DICHLORODIFLUOROMETHANE (SARA III) CAS:75-71-8 RTECS #:PA8200000 Fraction by Wt: 8% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 10% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH SOAP AND WATER. INHAL:REMOVE TO FRESH AIR LOCATION AWAY FROM EXPOSURE. EYES:RINSE WITH PLENTY OF COOL, CLEAN WATER UNTIL IRRITATION SUBSIDES. INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:NO FLASH Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:HALOGENATED HC VAPORS FORM PHOSGENE-LIKE DECOMPOSITION PRODUCTS UPON PYROLYSIS. USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:AEROSOLS MAY BURST VIOLENTLY AT TEMPERATURES ABOVE 130F. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE FLUORIDES, CHLORIDES AND PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE LEAKING CONTAINER TO DISPOSAL SITE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE INDOORS AWAY FROM HEAT SOURCES/DIRECT SUNLIGHT.DO NOT PUNCTURE/INCINERATE.DO NOT DROP. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF FLUORIDES, CHLORIDES AND/OR PHOSGENE (FP N). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NEEDED (MFR). USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NOT NEEDED. Other Protective Equipment:NONE REQUIRED Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE EATING, SMOKING, OR USING SANITARY FACILITIES . Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:75.0F,23.9C Melt/Freeze Pt:M.P/F.P Text:-111F,-79C Vapor Pres:760 Vapor Density:HVR/AIR Spec Gravity:1.42 Evaporation Rate & Reference:.2 Solubility in Water:NIL Appearance and Odor:STRAW-COLORED MOBILE LIQUID, MILD HALOGENATED HC ODOR. Percent Volatiles by Volume:69 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:TEMPERATURES ABOVE 130F, DIRECT SUNLIGHT. Hazardous Decomposition Products:HALOGENATED HC VAPORS FORM PHOSGENE-LIKE DECOMPOSITION PRODUCTS UPON PYROLYSIS. FLUORIDES, CHLORIDES, PHOSGENE . ==================== Disposal Considerations ==================== Waste Disposal Methods:APPROVED METHOD FOR AEROSOLS IS CRUSHING IN SAFE-RATED COMPACTOR. DO NOT INCINERATE EMPTY OR FULL CONTAINERS. DISPOSE I/A/W FEDERAL, STATE AND LOCAL REGULATIONS .
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:SODIUM TRIFLUOROMETHANESULFONATE, 20837 CAGE:0JVJ1 CAGE:0JVJ1 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM TRIFLUOROMETHANESULFONATE CAS:2926-30-9 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY BE HARMFUL IF SWALLOWED, EFFECTS NOT KNOWN. MAY IRRITATE EYES, SKIN & MUCOUS MEMBRANES. NO CHRONIC EFFECTS KNOWN. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:REMOVE FROM EXPOSURE. EYES:FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINS. SKIN:REMOVE ANY CONTAMD CLOTHING. FLOOD SKIN W/LARGE VOLUMES OF WATER FOR 15 MINS. INGEST/INHAL:SEEK PROMPT, COMPETENT MED ATTN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER, CARBON DIOXIDE, DRY CHEMICAL, EXTINGUISHING AGENTS, DRY SAND, OR DRY GROUND DOLOMITE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . IF W/OUT RISK, REMOVE MATL FROM FIRE AREA. COOL CONTR W/WATER FROM MAXIMUM DISTANCE. Unusual Fire/Explosion Hazard:MAY EMIT TOXIC FUMES IF THERMALLY DECOMPOSED. ================== Accidental Release Measures ================== Spill Release Procedures:WEARING FULL PROT CLTHG & RESP PROT, ELIMINATE ALL SOURCES OF IGNIT. COVER SPILL W/DRY SAND/DRY VERMICULITE, MIX WELL & CAREFULLY TRANSFER TO WELL-MARKED CONTR. CLOSE CONTR TIGHTLY. SUBMIT OR RETAIN F OR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTR TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR ORDINARY USE, WEAR NIOSH/MSHA APPRVD HIGH EFFICIENCY PARTICLE RESPIRATOR. EMERGENCY, WEAR A NIOSH/MSHA APPRVD SCBA. Ventilation:LABORATORY FUME HOOD. Other Protective Equipment:LAB COAT & APRON, FLAME & CHEM RESIST COVERALLS, EYEWASH CAPABLE OF SUSTAINED FLUSHING, SFTY DRENCH SHOWER (SUPDAT) Work Hygienic Practices:WASH THOROUGHLY AFTER USE. Supplemental Safety and Health OTHER PROT EQUIP: MEETING ANSI DESIGN CRITERIA HYGENIC FACILITIES FOR WASHING. ================== Physical/Chemical Properties ================== HCC:N1 Evaporation Rate & Reference:NOT KNOWN Appearance and Odor:WHITE POWDER; ODOR NOT KNOWN. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACID, ACID FUMES Stability Condition to Avoid:THERMAL DECOMPOSITION. Hazardous Decomposition Products:HYDROGEN FLUORIDE FUMES, SO, SO*2, CO, CO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT STATE, LOCAL & FEDERAL REGULATIONS FOR PROPER DISPOSAL OF ORGANOSULFONATES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EXTINGUISHER,FIRE,VAPORIZING LIQUID. Preparer's Name:DGSC-SLM/ DOD-HMIS CAGE:MO879 CAGE:16236 CAGE:MO879 ============= Composition/Information on Ingredients ============= Ingred Name:BROMOCHLORODIFLUOROMETHANE (AS EXTINGUISHING AGENT) CAS:353-59-3 RTECS #:PA5270000 Other REC Limits:SEE LC50 INFORM. OSHA PEL:NONE ESTABLISHED ACGIH TLV:NONE ESTABLISHED Ingred Name:NITROGEN CAS:7727-37-9 RTECS #:QW9700000 ACGIH TLV:ASPHYXIANT; 9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50(RAT: 20 PPH/15M Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: ASPHYXIANT 'CNS' & PULMONARY EFFECTS. SKIN IRRITANT CHRONIC: NONE KNOWN. Effects of Overexposure:INHAL: DIZZINESS, DISORIENTATION, IMPAIRED COORDINATION, NARCOSIS, NAUSEA, OR VOMITING. LIGHT-HEADEDNESS, GIDDINESS, BREATH SHORTNESS. CARDIAC ARRHYTHMIA W/ UNCONSCIOUSNESS OR EVEN DEATH IH HI-CONC W/ LONG EXPOSURE; SKIN/EYES: CONTACT W/LIQUID CAN CAUSE FROSTBITE, OR SKIN IRRITATION. Medical Cond Aggravated by Exposure:CARDIAC PROBLEMS (PRODUCT IS AN ASPHYXIANT & CAN INDUCE CARDIAC MUSCLE SENSITIZATION TO CIRCULATING EPINEPHRINE-LKIE COMPOUNDS.) ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR-GET MED. ATTN. & GIVE O*2/CPR AS REQUIRED FOR SITUATION & HAND; DONOT GIVE EPINEPHRINE OR SIMILAIR DRUGS AS CATECOLAMINES INCREASE RISK OF ELICITING CARDIAC DYSRYTHMIAS. EYE S/SKIN: FLUSH W/ WATER - TREAT FOR FROSTBITE W/ MEDICAL ATTN. ; INGEST: NOT LIKELY TO OCCUR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS A FIRE EXTINGUISHANT & IS NON-FLAMMABLE. USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE 'SCBA' WHEN FIGHTING FIRES WHERE CHEMICALS ARE INVOLVED. 'SCBA' MAY BE NEEDED IF HALON-1211 CONTAINER RUPTURES OR RELEASE MATERIAL IN HEAT OF FIRE. Unusual Fire/Explosion Hazard:IN HEAT OF FIRE, HALON-1211 CONTAINER EXPOSED TO INTENSE HEAT OF FIRE MAY RUPTURE & MATERIAL COMPOSITION MAY OCCUR. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF UNNEEDED PERSONNEL VENTILATE AREA ESPECIALLY LOW PLACES WHERE HEAVY VAPORS MIGHT COLLECT. COOL OR REMOVE HOT METAL SURFACES OR SOURCES OF NON-EXTINGUISHED FLAMES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE & HANDLE AS A LIQUIFIED COMPRESSED GAS IN'DOT' APPROVED PRESSURE VESSELS AWAY FROM HI-TEMPERATURES. Other Precautions:AVOID UNNECESSARY EXPOSURE TO HALON 1211 ! ABOVE 4%(17 LBS/1000 CU FT AIR & >1 MIN:DIZZINESS,IMPAIRED COORDINATION & REDUCED MENTAL ALERTNESS);ABOVE 5% CONC(22 LBS/1000 CU FT OF AIR),USE AIR SUPPLIED RESPIRATORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NECCESSARY IF PROPER ENGINEERING CONTROLS ARE IN PLACE. IF PEL/TLV ARE EXCEEDED, USE POSITIVE PRESSURE AIR-SUPPLIED RESPIRATOR. REVIEW 29CFR1910.134 INSTRUCTIONS/WARNINGS AS WELL AS NIOSH -RESPIRATOR DECISON LOGIC PUB87.108. Ventilation:PROVIDE SUFFICIENT GENERAL/LOCAL EXHAUST VENTILATION IN PATTERN/VOLUME TO CONTROL INHALATION EXPOSURE BELOW PEL/TLV. Other Protective Equipment:AS REQUIRED TO MINIMIZE EXPOSURE & MAXIMIZE INDIVIDUAL PROTECTION. Work Hygienic Practices:OBSERVE PROCEDURES SET FORTH BY SAFETY/IH PERSONNEL FOR USE OF THIS MATERIAL FOR TASK AT HAND. Supplemental Safety and Health SMALL CONC( 5%) OF HALON EXTINGUISH FLAMES BY CHEMICALLY INTERRUPTING COMBUSTION-NOT BY REPLACING O*2. HOWEVER, VAPORIZATION OF EXCESSIVE AMTS. CAN DEPLETE OR REPLACE O*2 NEEDED FOR BREATHING; GENERIC 'MSDS' ON NSN IDENTIFIED BY "DCSC". UPON RECIPT OF A MFR'S MSDS UNDER THIS NSN, THE GENERIC WILL BE REMV. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:26F/-3.3C Melt/Freeze Pt:M.P/F.P Text:-257F/-161C Vapor Pres:1897 & 70F Vapor Density:5.7 Spec Gravity:1.83 Evaporation Rate & Reference:RAPID; REFERENCE UNK. Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS LIQUIFIED GAS(SEE BOILING PT) W/SLIGHT ETHERAL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACTIVE METALS (EG. ALKALINE EARTH & ALKALINE EARTH METALS, POWDERED AL, ZN, BE, ETC.) & METAL HYDRIDES. Stability Condition to Avoid:FLAMES OR HOT SURFACES >900F CAN CAUSE DECOMPOSITION OF MATERIAL. Hazardous Decomposition Products:AT HI-TEMPS(>900F) : HF, HBR, FREE BR, POSSIBLE CAEBONYL HALIDES, & OXIDES OF BROMING, FLURINE, OR CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY W/ALL FEDERAL, STATE. & LOCAL REGULATIONS. RECLAIM MATERIAL IN A SUITABLE VAPOR RECOVERY SYSTEM/EQUIPMENT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BUTANOL, A-399 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:1-BUTANOL; (N-BUTYL ALCOHOL) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 100% OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPP DATA:FLOW CAN BE STOPPED. USE WATER IN FLOODING AMTS AS FOG. SOLID STREAMS MAY NOT BE EFTIVE. COOL CNTNRS (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:W/FLOODING AMTS OF WATER. APPLY FROM AS FAR A DISTANCE AS POSSIBLE. AVOID BREATHING TOXIC VAPORS. KEEP UPWIND. RTECS #:9999999ZZ Ingred Name:EXPLO HAZ:MIXTURES ARE EXPLOSIVE ABOVE FLASH POINT. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:AUDITORY NERVE & VESTIBULAR INJURY IN WORKERS RESULTING IN SEVERE VERTIGO & HEARING LOSS. LUNG (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:HEMORRHAGE, REDUCED ERYTHROCYTE COUNT, LYMPHOCYTOSIS, ALBUMINURIA, EARLY DEGENERATIVE CHANGES OF LIVER, & (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:CORTICAL & TUBULAR DEGENERATION IN KIDNEYS WERE REPORTED IN ANIMALS FOLLOWING PRLNGD EXPOS TO 100PPM. (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:SKIN:IRRITANT. ACUTE:LIQ CNTCT MAY CAUSE IRRIT W/REDNESS & DRYNESS. SUBSTANCE MAY BE ABSORBED THRU INTACT (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:SKIN. SINGLE APPLICATIONS TO SKIN OF RABBITS RESULTED IN SLIGHT-MOD IRRIT. CHRONIC:RPTD/PRLNGD CNTCT HAS (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:BEEN REPORTED TO CAUSE DRYING,CRACKING & ECZEMATOID DERM OF FINGERS & HANDS DUE TO DEFATTING ACTION OF (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:LIQ. APPLICATION OF 42-55 ML/KG/DAY FOR 1-4 CONSECUTIVE DAYS TO RABBITS RESULTED IN 100% MORTALITY. (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:EYE:IRRITANT. ACUTE:VAP CONCS OF 25PPM MAY CAUSE SLIGHT IRRIT. APPLICATION OF 1 DROP OF LIQ TO RABBIT (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:EYES CAUSED MOD TEMPORARY INJURY WHICH WAS RATED 7 ON SCALE OF 10. CHRONIC:RPTD/PRLNGD EXPOS TO VAPS MAY (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:RESULT IN CONJUNCT.VACUOLAR KERATITIS, CHARACT BY VERY FINE TRANSPARENT VACUOLES RESEMBLING TINY BUBBLES (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:OF GAS IN EPITHELIAL LAYERS OF CORNEA HAS BEEN REPORTED IN WORKERS EXPSD TO BUTYL ALCOHOL & OTHER SOLVS. (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:EXPOS TO >200PPM FOR 10 YRS CAUSED CONJUNCTIVAL & CORNEAL EDEMA RESULTING IN LACRIMATION, BLURRING OF (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: VISION, CORNEAL INFLAMM, PHOTOPHOBIA & BURNING SENSATION W/INFLAMMATION CLEARING W/I A FEW DAYS W/NO (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:RESIDUAL DMG. INGEST:NARCOTIC. ACUTE:MAY CAUSE ABDOM PAIN,NAUSEA,VOMIT & DIARRHEA. INGEST OF HIGH DOSES (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:OF BUTYL ALCOHOL CAUSED COMPLETE PARALYSIS,CONSTRICTION OF PUPILS,REDUCTION IN CORNEAL,PUPILLARY & (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:CILIARY REFLEXES,NYSTAGMUS,SALIVATION, REDUCTION OF BODY TEMP & RESP, DEEP NARCOSIS, MARKED HEPATIC (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:HYPEREMIA, DEGENERATION OF LIVER & KIDNEYS & DEATH IN ANIMALS. CHRONIC:PRLNGD INGEST OF N-BUTYL ALCOHOL (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:IN DRINKING WATER RESULTED IN LIVER DAMAGE IN RATS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:INGEST:REMOVE INGESTED MATL BY GASTRIC LAVAGE OR EMESIS. GIVE ARTF RESP W/O*2 IF RESP DEPRESSED. (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:GET MD IMMED. NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. RTECS #:9999999ZZ Ingred Name:SPILL PROC:AREA! KEEP UNNECESSARY PEOPLE AWAY; ISOLATE HAZARD AREA AND DENY ENTRY. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT)790 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:IRRITANT/NARCOTIC. 8000PPM IDLH. ACUTE:VAP CONCS OF 25PPM MAY CAUSE MILD IRRIT TO RESP TRACT & NOSE. SUBSTANCE QUITE ODOROUS WHICH USUALLY PROVIDES ADEQ WARNING BUT OLFACTORY SENSES READILY BECO ME FATIGUED. EXPOS TO 50PPM MAY CAUSE HDCH & VERTIGO; HIGHER CONCS MAY CAUSE MARKED IRRIT, SORE THROAT,(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:NERVOUS SYS DEPRESS W/HDCH, DIZZ, DULL & DROWS. EXPOS TO 6600PPM PRODUCED GIDDINESS, PROSTRATION,NARCOSIS,ATAXIA & DEATH IN SOME ANIMALS. CHRONIC:LONG-TERM STUDY ON HUMANS EXPSD TO BUTYL ALCO HOL REVEALED LITTLE/NO IRRIT/COMPLICATIONS OCCURRED AT 100PPM/BELOW. HOWEVER, PRLNGD INHAL AT THIS LEVEL CAUSED (ING 5) Medical Cond Aggravated by Exposure:PERSONS W/A HISTORY OF CHRONIC RESPIRATORY, SKIN, OR EYE DISEASE MAY BE AT AN INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR IMMED.IF BRTHG STOPPED, GIVE ARTF RESP.KEEP WARM/AT REST.GET MD IMMED. SKIN:REMOVE CONTAMD CLTHG/SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LG AMTS OF WATER UNTI L NO EVID OF CHEM REMAINS (APPROX 15-20MIN). GET MD IMMED. EYE:WASH IMMED W/LG AMTS OF WATER/NORMAL SALINE,OCCASNLY LIFTING LIDS UNTIL NO EVID OF CHEM REMAINS(APPROX 15-20 MIN).GET MD IMMED. (ING 23) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:84.0F,28.9C Lower Limits:1.4% Upper Limits:11.2% Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY/ALCOHOL FOAM. LG FIRE:WATER SPRAY, FOG/ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WATER MAY BE INEFTIVE. MOVE CNTNR FROM FIRE AREA IF POSS. COOL FIRE-EXPSD CNTNRS W/WATER FROM (SUPP DATA) Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT/FLAME. VAPORS HEAVIER THAN AIR & MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNIT & FLASH BACK. VAPOR-AIR (ING 4) ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF CAN BE DONE W/O RISK. USE WATER SPRAY TO REDUCE VAPS. SML:TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP. LG:DIKE FAR AHEAD OF SPILL FOR LATER DISP. NO SMOKING, FLAMES/FLARES IN HAZ(ING 25) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE I/A/W 29 CFR 1910.106. Other Precautions:SUBSTANCES W/LOW ELECTROCONDUCTIVITY WHICH MAY BE IGNITED BY ELECTROSTATIC SPARKS SHOULD BE STORED IN CNTNRS WHICH MEET BONDING & GROUNDING GUIDELINES SPECIFIED IN NFPA 77-1983, RECOMMENDED PRACTICE O N STATIC ELECTRICITY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:REFER TO ORIGINAL MSDS . Ventilation:PROVIDE LOCAL EXHAUST/GEN DILUTION VENT TO MEET PUBLISHED EXPOS LIMITS. VENT EQUIP MUST BE EXPLOSION-PROOF. Other Protective Equipment:IMPERVIOUS CLOTHING AND EQUIPMENT. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. Supplemental Safety and Health FIRE FIGHT PROC:SIDE UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM STOR TANK ENDS.FOR MASSIVE FIRE IN STOR AREA,USE UNMANNED HOSE HOLDER/MONITOR NOZZ, ELSE WITHDRAW FROM AREA & LET FIRE BURN. WITHDRAW IMMED IN CASE OF RISING SOUND FROM VENTING SFTY DEVICE/ANY DISCOLORATION OF STOR TANK DUE TO FIRE. EXTING ONLY IF(ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:243F,117C Melt/Freeze Pt:M.P/F.P Text:-128F,-89C Vapor Pres:6.5 @ 25C Vapor Density:2.55 Spec Gravity:0.8098 Evaporation Rate & Reference:0.5 (BUTYL ACETATE = 1) Solubility in Water:7.7% Appearance and Odor:CLEAR,MOBILE,COLORLESS LIQ, W/STRONG, PUNGENT CHARACT ODOR SIMILAR TO FUEL OIL. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI METALS, ALUMINUM, T-BUTANOL, CHROMIC ANHYDRIDE, STRONG OXIDIZERS. SEE ORIGINAL MSDS FOR ADDL INFO . Stability Condition to Avoid:MAY BE IGNITED BY HEAT, SPARKS OR FLAMES. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC CO*X. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W STANDARDS APPLICABLE TO GENERATORS OF HAZ WASTE, 40 CFR 262. EPA HAZ WASTE NO U031. OBSERVE ALL FEDERAL, STATE & LOCAL REGS WHEN STORING/DISPOSING SUBSTANCE. FOR ASSISTANCE, CNT CT DISTRICT DIRECTOR OF EPA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPRAYWAY F-102 CONTACT ELECTRONIC CLEANER CAGE:55772 CAGE:55772 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA III) CAS:76-13-1 RTECS #:KJ4000000 Fraction by Wt: 98% Other REC Limits:1000 PPM OSHA PEL:1000PPM/1250STEL ACGIH TLV:1000PPM/1250STEL9192 Ozone Depleting Chemical:1 Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 02% Other REC Limits:1000 PPM OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:LIGHT HEADEDNESS,GIDDINESS,SHORTNESS OF BREATH,POSSIBLE NARCOSIS,POSSIBLE CARDIAC ARRHYTHMIAS ST HIGH CONCENTRATIONS. Effects of Overexposure:LIGHT HEADEDNESS,GIDDINESS SHORTNESS OF BREATH,POSSIBLE NARCOSIS,POSSIBLE CARDIAC ARRHYTHMIAS AT HIGH CONCENTRATIONS Medical Cond Aggravated by Exposure:NONE LISTED BY MFG. ======================= First Aid Measures ======================= First Aid:IF UNCONSCIOUS,REMOVE VICTIM TO FRESH AIR AND CALL A PHYSICIAN.IN CASE OF CONTACT WITH EYE FLUSH FOR AT LEAST !% MINUTES INGESTION CALL A PHYSICIAN ===================== Fire Fighting Measures ===================== Flash Point:NONE Upper Limits:NON-FLAM Extinguishing Media:NON-FLAMMABLE Fire Fighting Procedures:KEEP CONTAINERS COOL. USE EQUIPMENT OR SHIELDING AS REQUIRED TO PROTECT PERSONNEL AGAINST BURSTING,RUPTURING,OR VENTING CONTAINER WEAR PRESSURE (SEE SUPP DATA) Unusual Fire/Explosion Hazard:AT ELEVATED TEMPERATURES (>54C:130F) CONTAINERS MAY VENT,RUPTURE,OR BURST. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA ESPECIALLY LOW PLACES WHERE HEAVY VAPORS MIGHT COLLECT.REMOVE OPEN FLAMES.COLLECT WITH AN ABSORBANT MATERIAL & DISPOSAL ACCORDINGLY TO REGULATIONS Neutralizing Agent:NONE NOTED BY MFG ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE TEMPERATURES COULD EXCEED 54C(130F) Other Precautions:AVOID BREATHING VAPORS & PROLONGED SKIN EXPOSURE. USE ONLY IN WELL VENTILATED AREAS. NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING,OPEN FLAMES OR HOT SURFACES. HEAT AND/ OR UV RADIATION MAY CAUSE(SEE SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE UNDER NORMAL USE(MFG) NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN Ventilation:LOCAL SHOULD BE USED WHEN SPRAYING LARGE AMOUNTS.MECHANICAL SHOULD BE USED IN LOW PLACES Supplemental Safety and Health SPEC FIRE FIGHT:DEMAND SELF CONTAINED BREATHING APPARATUS. OTHER PREC:THE FORMATION OF CHLORIDES,FLOURIDES OR PHOSGENE ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:117.6F Vapor Pres:334MMHG@77 Vapor Density:>AIR Spec Gravity:1.5 Evaporation Rate & Reference:FASTER THEN N-BUTYL ACETA Solubility in Water:NEGLIGIBLE Appearance and Odor:FLUSHING HEAVY SPRAY, SLIGHT ETHERAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE LISTED BY MFG Stability Condition to Avoid:OPEN FLAMES & HIGH TEMPERATURES Hazardous Decomposition Products:HYDROCHLORIC & HYDROFLUORIC ACIDS. POSSIBLE PHOSGENE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT PUNCTURE OR INCINERATE CONTAINERS.GIVE EMPTY,LEAKING OR FULL CONTAINERS TO A DISPOSAL SERVICE EQUIPPED TO SAFELY HANDLE AND DISPOSE OF PRESSURIZED CONTAINERS.
1
eyes_protection_mandatory
======================================================= Product ID: 809 4674,KODAK CYAN TONER C2 Cage: EO274 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: EO274 Country: JA Cage: 0ZW37 Cage: 19139 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NOT PROVIDED Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD. Explanation Of Carcinogenicity: CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE):- INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF GOVT INDUSTRIAL HYGIENISTS (ACGIH): (CHROMIUM (I II) COMPOUNDS, AS CR): NOT CLASSIFIABLE AS A HUMAN CARCINOGEN (A4)- NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMIN (OSHA): NONE Signs And Symptions Of Overexposure: EYES: MAY CAUSE TRANSIENT IRRITATION. Medical Cond Aggravated By Exposure: NOT PROVIDED First Aid: INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. G ET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY M OUTH TO AN UNCONSCIOUS PERSON. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: DO NOT USE A VACUUM CLEANER TO CLEAN UP SPILLS OF POWDERED TONERS. THE VERY FINE PARTICLES CAN CAUSE A FIRE OR EXPLOSION. SWEEP MATERIAL ONTO PAPER AND PLACE IN A FIBER CARTON. AVOID GENERATION OF DUS T. Waste Disposal Methods: INCINERATE OR LANDFILL. CAN BE INCINERATED WHEN IN COMPLIANCE WITH LOCAL REGULATIONS. DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. Handling And Storage Precautions: KEEP CONTAINER CLOSED. POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. MINIMIZE DUST GENERATION AND ACCUMULATION. KEEP AWAY FROM SOURCES OF IGNITION. KEEP FROM CONTACT WITH OXIDIZING MATERIALS . Other Precautions: AVOID BREATHING DUST. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONE Extinguishing Media: WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard: POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE SHOULD BE NEEDED. Ventilation: GOOD VENTILATION (TYPICALLY 4-6 ROOD VOLUMES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. SHOULD BE WORN. Other Protective Equipment: WASHING FACILITIES. Work Hygienic Practices: IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE CONTACT. Supplemental Safety and Health: NONE ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 NRC/State LIC No: NOT RELEVANT M.P/F.P Text: 100-150C (212-302F) Vapor Pres: NEGLIGIBLE Spec Gravity: 1.0-1.5 Evaporation Rate & Reference: NOT PROVIDED Solubility in Water: NEGLIGIBLE Appearance and Odor: BLUE SOLID (POWDER), SLIGHT ODOR Percent Volatiles by Volume: NEGLIGIBLE Corrosion Rate: NOT PROVIDED ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NOT PROVIDED Materials To Avoid: STRONG OXIDIZING AGENTS Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NONE ======================================================= Toxicological Information ======================================================= Toxicological Information: EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD. ======================================================= Ecological Information ======================================================= Ecological: THIS MATERIAL HAS NOT BEEN TESTED FOR ENVIRONMENTAL EFFECTS. IN A SPILL SITUATION THESE MATERIALS MAY BE VISUALLY UNPLEASANT; HOWEVER, IT IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS. ======================================================= ======================================================= Transport Information: FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (800) 255-3434 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY. ======================================================= Regulatory Information ======================================================= Sara Title III Information: CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: CHROMIUM (I I I) COMPOUNDS Federal Regulatory Information: NOT PROVIDED State Regulatory Information: MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE. ======================================================= Other Information ======================================================= Other Information: LOW HAZARD FOR RECOMMENDED HANDLING. ======================================================= Transportation Information ======================================================= Trans ID NO: 154101 Product ID: 809 4674,KODAK CYAN TONER C2 Review Date: 07/19/2000 Net Unit Weight: 1.65 LBS Multiple KIT Number: 0 Unit Of Issue: CY Type Of Container: CYLINDER Additional Data: THE WEIGHT IS 750 GRAMS, PER MSDS. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: 809 4674,KODAK CYAN TONER C2 Cage: EO274 Assigned IND: Y Company Name: CANON INC Street: 30-2 SHIMOMARUKO 3-CHOME, OHTA-KU Zipcode: 00000 Country: JA Label Required IND: Y Date Of Label Review: 07/19/2000 Status Code: A MFG Label NO: NOT PROVIDED Label Date: 01/07/1998 Origination Skin Protection IND: NO Signal Word: CAUTION Respiratory Protection IND: NO Health Hazard: None Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS: NOT PROVIDED. LOW HAZARD FOR RECOMMENDED HANDLING. KEEP OUT OF REACH OF CHILDREN. FOR ADDITIONAL INFORMATION, SEE MATERIAL SAFETY DATA SHEET (MSDS) FOR THIS MATERIAL. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PHILTAC CAGE:GO225 CAGE:GO225 CAGE:6Y142 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCARBONS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: MILD IRRITATION. PRESSURIZED INJECTION OF PRODUCT UNDER THE SKIN CAN LEAD TO SERIOUSLY INFLAMMED TISSUE. IF LEFT UNTREATED INJURY CAN BE GANGRENOUS. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/RUNNING WATER FOR AT LEAST 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION: GIVE 2 GLASSES OF WATER & INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CAS ES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>280F, >138C Extinguishing Media:DRY CHEMICAL, FOAM, CO2 Fire Fighting Procedures:EVACUATE AREA. SHUT OFF SOURCE, IF POSSIBLE. USE NIOSH/MSHA SCBA & OTHER PROTECTIVE EQUIP &/OR GARMENTS. USE WATER FOG/SPRAY TO COOL EXPOSED CONTAINERS & EQUIP. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT &/OR GARMENTS. SHUT OFF SOURCE, IF POSSIBLE & CONTAIN SPILL. PROTECT FROM IGNITION. KEEP OUT OF WATER SOURCES & SEWERS. ABSORB IN DRY, INERT MATERIAL. TRANSFER TO DISPOSAL DR UMS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM IGNITION SOURCES. KEEP CONTAINERS CLOSED. Other Precautions:AVOID CONTACT W/SKIN, EYES & BREATHING OF MIST. AVOID PROLONGED SKIN CONTACT WITH USED MOTOR OIL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT GENERALLY REQUIRED. FOR CONCENTRATIONS EXCEEDING THE TLV, USE A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR. Ventilation:ADEQUATE VENTILATION TO KEEP BELOW TLV. Other Protective Equipment:PROTECTIVE GARMENTS Work Hygienic Practices:WASH HANDS AFTER HANDLING. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:<1 Vapor Density:>5 Spec Gravity:0.86-0.94 Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS TO DARK LIQUID W/MILD ODOR. Percent Volatiles by Volume:NEGL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXYGEN & STRONG OXIDIZING AGENTS Stability Condition to Avoid:IGNITION SOURCES Hazardous Decomposition Products:CARBON OXIDES & VARIOUS HYDROCARBONS ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR OTHERWISE MANAGE IN A PERMITTED WASTE MANAGEMENT FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PROLITE OPAQUE RESIN CAGE:GO317 CAGE:33339 CAGE:GO317 ============= Composition/Information on Ingredients ============= Ingred Name:TRIETHYLENE GLYCOL DIMETHACRYLATE CAS:109-16-0 RTECS #:OZ4100000 Fraction by Wt: 90-100% Ingred Name:ALKYL DIMETHACRYLATES ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION & DAMAGE. SKIN: MAY CAUSE IRRITATION. INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. INGESTION: MAY BE HARMFUL/FATAL. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, RASH ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: RINSE OUT MOUTH W/WATER. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES . ===================== Fire Fighting Measures ===================== Extinguishing Media:CHEMICAL FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:WEAR SCBA. Unusual Fire/Explosion Hazard:HEAT CAN CAUSE POLYMERIZATION W/RAPID RELEASE OF ENERGY ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/INERT MATERIAL. KEEP OUT OF SEWERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE AWAY FROM HEAT LIGHT & IGNITION SOURCES. ============= Exposure Controls/Personal Protection ============= Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS OF VAPORS RELEASED BY UNCURED MATERIAL Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.1 Solubility in Water:INSOLUBLE Appearance and Odor:WHITE LIQUID W/FRUITY ESTER LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING & OXIDIZING AGENTS, PEROXIDES & AMINES Stability Condition to Avoid:HEAT, LIGHT, AGING & SOURCES OF CONTAMINATION Hazardous Decomposition Products:OXIDES OF CARBON ==================== Disposal Considerations ==================== Waste Disposal Methods:UNPOLYMERIZED MATERIAL MAY BE HAZARDOUS WASTE. INCINERATE UNCURED MATERIAL IAW/FEDERA, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MS-190/CO*2 FREON TMC FLUX REMOVER Preparer's Name:JANET STEPHENS CAGE:18598 CAGE:18598 ============= Composition/Information on Ingredients ============= Ingred Name:METHYLENE CHLORIDE (SARA 313) (CERCLA) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 47-50% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM; Z-2 ACGIH TLV:50 PPM, A2; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA 313) CAS:76-13-1 RTECS #:KJ4000000 Fraction by Wt: 47-50% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000PPM/1250STEL9495 Ozone Depleting Chemical:1 Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 2-4% Other REC Limits:NONE RECOMMENDED OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;95 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50 INHAL RAT=15OOOPPM/2HR (INGRED 2) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES:MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION AND DEFATTING.INGEST:MAY CAUSE GI TRACT IRRITATION.ASPIRATION HAZARD.INHAL:VAPOR IS HEAVIER THAN AIR AND DISPLACES BREATHING OXYGEN AND CAUSE CARDIA C IRREGULARITIES.SYSTEMIC TOXICITY:METHYLENE CHLORIDE IS METABOLIZED TO CARBON MONOXIDE(ROUTES-INGEST/INHAL/ABSORPTION). Explanation of Carcinogenicity:METHYLENE CHLORIDE IS CLASSIFIED NTP-AC,IARC-I(HUMAN). Effects of Overexposure:INHAL:LIGHTHEADEDNESS,GIDDINESS,SHORTNESS OF BREATH,NARCOSIS,UNCONSIOUSNESS,DEATH. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN OR CARDIOVASULAR DISEASE OR HEART IRREGULARITIES MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.CALL PHYSICIAN.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOM ITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE 2 GLASSES ACTIVATED CHARCOAL SLURRY(50G/400ML WATER).DO NOT EPINEPHRINE OR SIMILAR CATACHOLAMINE DRUGS. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:NONE Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG. Unusual Fire/Explosion Hazard:CONTAINERS MAY BURST AT ELEVATED TEMPERATURES.FIRE CONDITIONS MAY EVOLVE TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION.USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.SHUT OFF LEAK IF SAFE.ALLOW TO EVAPORATE.SOAK UP LARGE SPILLS WITH A NON-COMBUSTIBLE INERT ABSORBANT(CLAY,SAND);PLACE IN P ROPER CONTAINER FOR DISPOSAL. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT TEMPERATURES BELOW 120F.FOLLOW LABEL DIRECTIONS.AVOID DIRECT SUNLIGHT Other Precautions:ROTATE STOCK;SHELF LIFE IS ONE YEAR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A SELF-CONTAINED BREATHING APPARATUS. Ventilation:LOCAL VENTILATION AT THE WORKSITE AND LOW AREAS;MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL. Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:V2 Boiling Pt:=36.7C, 98.F Vapor Pres:500 Vapor Density:4.9 Spec Gravity:1.42 pH:7 Evaporation Rate & Reference:0.3 CARBON TET=1 Solubility in Water:SLIGHT;0.66 W/W Appearance and Odor:AEROSOL.LIQUID IS CLEAR;COLORLESS;SOLVENT ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI,ALKALINE EARTH METALS(AL,BE,ZN,ETC.). Stability Condition to Avoid:HEAT ABOVE 120F/49C.AVOID SPRAYING NEAR OPEN FLAMES AND RED HOT SURFACES. Hazardous Decomposition Products:HF,HCL,POSSIBLE CARBONYL HALIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.EPA WASTE NUMBERS F001,F002.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BLUE LABEL REWORKABLE FIXATIF SPRAY,1803,804300 CAGE:EO225 CAGE:06608 CAGE:MART5 CAGE:EO225 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE-ISOBUTANE-N-BUTANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 10 - 20% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9596 Ingred Name:ETHYL ACETATE (CERCLA) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 1 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:400 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-AMINO-2-METHYL-1-PROPANOL CAS:124-68-5 RTECS #:UA5950000 Fraction by Wt: 1 - 10% Other REC Limits:NONE RECOMMENDED ACGIH TLV:NOT EXTABLISHED Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 1 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 200 PPM ACGIH TLV:S,200PPM/250STEL; 96 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 60 - 70% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, LIVER, KIDNEY, CNS, RESPIRATORY TRACT. ACUTE- EYE & SKIN IRRITANT. MAY CAUSE BLINDNESS. INHALATION MAY CAUSE IRRITATION OF RESPIRATORY TRACT & CNS EFFECTS. ASPIRATION HAZARD I F SWALLOEWED. WILL CAUSE DEFATTING OF SKIN. MAY BE ABSORBED THROUGH SKIN. CHRONIC- LUNG, LIVER OR KIDNEY DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, NAUSEA, VOMITING, DIZZINESS, FATIGUE, BLURRED VISION, TEARING, PAIN Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED LIVER, KIDNEY, CNS OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF NEEDED. EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. INHALED:MOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NECESSARY. ORAL:DO NOT INDUC E VOMITING. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:FLAMMABL AEROSOL Lower Limits:1.8% Upper Limits:9.5% Extinguishing Media:USE WATER FOG, DRY CHEMICAL OR CARBON DIOXIDE. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:SPRAY CANS UNDER PRESSURE. EXTREMELY FLAMMABLE. EXPLOSION HAZARD EXISTS WHEN SPRAY CANS HEATED. DO NOT ENTER SPRAY CAN STORAGE AREA IF FIRE PRESENT. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE IGNITION SOURCES. LEAKING CONTAINERS SHOULD BE PLACED OUTDOORS, IN AN OPEN CONTAINER, AWAY FROM SOURCES OF IGNITION. ALLOW PRESSURE TO DISSIPATE. ABSORB LIQUID WITH NON-FLAMMABL E ABSORBENT AND PLACE IN CONTAINER FOR DISPOSAL. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, VENTILATED AREAS AWAY FROM SOURCES OF IGNITION, SUNLIGHT. DO NOT STORE ABOVE 120F. Other Precautions:"EMPTY" CONTAINERS RETAIN RESIDUE. FOLLOW ALL LABEL INSTRUCTIONS. AVOID EYE OR SKIN CONTACT. KEEP OUT OF REACH OF CHILDREN. DO NOT BREATHE VAPORS. DO NOT SPRAY TOWARD FACE/HOT SURFACES. DELIBERATELY C ONCNETRATING AND INHALING CAN BE FATAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF TLV IS EXCEEDED OR FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR OR AIR-PURIFYING RESPIRATOR. IN EMERGENCY, WEAR A NIOSH-APPROVED POSITIVE-PRES SURE SELF-CONTAINED BREATHING APPARATUS. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:EYE WASH STATION & SAFETY SHOWERS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING OR DRINKING. Supplemental Safety and Health DIFFERENT FORMULA. ================== Physical/Chemical Properties ================== HCC:V3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:-40F - 181F Vapor Pres:3862 @ 70F Vapor Density:4.0 Spec Gravity:0.8 Viscosity:NOT KNOWN Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1) Solubility in Water:NIL Appearance and Odor:CLEAR LIQUID - SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG ALKALIS, SELECTED AMINES Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, DIRECT SUNLIGHT, TEMPERATURES ABOVE 120F, IMPACT Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT PUNCTURE, INCINERATE SPRAY CANS EVEN AFTER USE. DO NOT FLUSH INTO DRAINS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:83-5-104233 ELECTROSTATIC TONER CAGE:DO022 CAGE:DO022 CAGE:09177 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, AMORPHOUS, DUST CAS:112945-52-5 RTECS #:VV7310000 OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3; 8990 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 5-10% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:ACRYLIC RESIN (ACCD TO MFR:TONERS ARE MADE OF MIXTURES OF 2 OR MORE OF LISTED CHEMICALS.) CAS:9003-01-4 RTECS #:AT4680000 Ingred Name:POLYAMIDE RESIN Ingred Name:ZINC STEARATE CAS:557-05-1 RTECS #:ZH5200000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Effects of Overexposure:NO LIKELY ROUTE OF ABSORPTN OR PROBABLE HARMFUL EFFECTS.EXCESS EXPOS BY DUST INHALATN (SEE OTHR PREC ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN:WASH W/SOAP & WATER. INGESTION:GET MEDICAL AID. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER,CO*2,FOAM,DRY CHEM Fire Fighting Procedures:USE SCBA TO PROTECT AGAINST COMBUSTION PRODUCTS. Unusual Fire/Explosion Hazard:IN SPECIAL CONDITIONS THE DUST MAY FORM EXPLOSIVE MIXTURE IN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID BREATHING DUST. SHOVEL,VACUUM OR SWEEP AFTER WETTING. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY AREA. READ & FOLLOW PRECAUTIONS ON CONTAINER LABEL. DO NOT RE-USE CONTAINER. Other Precautions:SPEC GRAV:0.9-1.1. EFFECTS OF OVEREXP:OR SKIN CONTACT SHOULD BE AVOIDED AS A MATTER OF GOOD HYGIENE PRACTICES. DATE OF PREP:2/3/86. PRODUCT USED ON XEROX 4000,4500. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED DUST RESPIRATOR IF DUST IS NOT CONTROLLED. Ventilation:AIR EXCHANGE RATE OF APPROX 5-6 ROOM VOLUME CHANGES PER HOUR Other Protective Equipment:NOT REQUIRED. Supplemental Safety and Health STYRENE/ALLYL ALCOHOL COPOLY,MOD MALEIC ROSIN ESTER,ISOBUTYLMETHACRYLATE COPOLY,PENTAERYTHRITOL TETRABENZOATE,BISPHENOL-A-PROPYLENE OXIDE FUMARATE,POLYVINYL BUTYRAL RES,POLYVINYLIDENE FLUORIDE ================== Physical/Chemical Properties ================== Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK POWDER,NO ODOR. PARTICLE SIZE:1-35 MICRONS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:MOISTURE & TEMPERATURE ABOVE 90F (32.2C) Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE HAZARDOUS. DO NOT BREATHE. ==================== Disposal Considerations ==================== Waste Disposal Methods:REFER TO LOCAL REGULATIONS RELATIVE TO DISPOSAL OF SOLID WASTE. WASTE DISPOSAL MUST BE IN ACCORDANCE W/FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: 6405, REDUCING REAGENT (SEE SUPPL) Kit Part: Y Cage: 1NSJ1 Box: 329 ======================================================= Contractor Summary ======================================================= Cage: 59896 Contract Number: MDA414-01-P-2039 Cage: 1NSJ1 Box: 329 Cage: 34807 Box: 329 ======================================================= Ingredients ======================================================= Cas: 56-81-5 RTECS #: MA8050000 Percent by Wt: 95. OSHA PEL: 10 MG/M3 ACGIH TLV: 10 MG/M3 ACGIH STEL: NOT ESTABLISHED ------------------------------ Cas: 10025-69-1 RTECS #: XP8850000 Percent by Wt: 1.6 ACGIH TLV: 2 MG/M3 AS SN ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORL RAT LD50: 700 MG/KG Skin: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: TARGET ORGANS: SKIN. MAY BE IRRITATING TO THE SKIN. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: SKIN. MAY BE IRRITATING TO THE SKIN. First Aid: EYE: FLUSH WITH WATER FOR 15 MINUTES. INGESTION: INDUCE VOMITING. GIVE PLENTY OF WATER. CONSULT PHYSICIAN. INHALTION: REMOVE TO FRESH AIR. CONSULT PHYSICIAN. SKIN: RINSE SKIN THOROUGHLY. WASH WITH SOA P AND WATER. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SMALL SPILLS: ABSORB ON PAPER TOWELS OR MOP UP AND FLUSH DOWN DRAIN WITH EXCESS WATER. LARGE SPILLS: ABSORB ON INERT MATERIAL (KITTY LITTER) OR SPILL PADS, PLACE INTO A CLEAN, DRY PLASTIC PAIL WITH LI D. Waste Disposal Methods: SEND WASTE TO INCINERATOR. DISPOSE ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: CC Flash Point: =190.C, 374.F Extinguishing Media: DRY CHEMICAL, ALCOHOL FOAM, CO2. Fire Fighting Procedures: USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard: CONTACT WITH STRONG OXIDIZING AGENTS (SUCH AS NITRIC ACID) MAY CAUSE FIRE OR EXPLOSION. ======================================================= Control Measures ======================================================= Ventilation: NORMAL Other Protective Equipment: LAB COAT. Work Hygienic Practices: AVOID CONTACT WITH SKIN. Supplemental Safety and Health: NFPA HAZARD: HEALTH-1, FLAMMABILITY-0, REACTIVITY-0. SCALE: 4=EXTREME, 3=HIGH, 2=MODERATE, 1=SLIGHT, 0=LEAST. "SEE OTHER INFORMATION". ======================================================= Physical/Chemical Properties ======================================================= HCC: F2 Boiling Point: =180.C, 356.F Melt/Freeze Pt: =20.C, 68.F Vapor Pres: 3@20C Vapor Density: 3 Solubility in Water: SOLUBLE Appearance and Odor: CLEAR SLIGHTLY COLORED VISCOUS LIQUID; ODORLESS. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, OPEN FLAMES, AND HOT SURFACES. Materials To Avoid: CONTACT WITH NITRIC ACID OR OTHER STRONG OXIDIZERS. Hazardous Decomposition Products: ACROLEIN ======================================================= Toxicological Information ======================================================= Toxicological Information: ORL RAT LD50: 700 MG/KG AS STANNOUS CHLORIDE. ======================================================= Other Information ======================================================= Other Information: ITEM IS PART OF 20 PIECE KIT FOR IRON HIGH RANGE REFILL KIT #65-2877 FROM CAROLINA BIOLOGICAL. 4450, 4451, 2210, 2246, 4253, 4100, 4167, 4169, 4170, 6286, 7166, 7424, 4410, 6405, 7460, 7461, 4259, 448 3, 4484, 5250. PART OF 20 PIECE FRESHWATER REFILL KIT #65-2926. SEE MSDS SERIAL #CLKNF, CLKNM, CLKNQ, CLKNT, CLKRH, CLKRJ, CLKRS, CLKRV, CLKZT, CLKZW, CLKZX, CLKZY, CLKZZ, CLLBB, CLLBD, CLLBW, CLLC C, CLLCF, AND CLLFC. ======================================================= Transportation Information ======================================================= Trans ID NO: 158649 Product ID: 6405, REDUCING REAGENT (SEE SUPPL) Review Date: 08/31/2001 Multiple KIT Number: 0 Kit Part IND: Y Review IND: Y Unit Of Issue: CY Type Of Container: CYLINDER ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: 6405, REDUCING REAGENT (SEE SUPPL) Cage: 1NSJ1 Company Name: LAMOTTE COMPANY Street: 802 WASHINGTON AVE. PO Box: 329 Zipcode: 21620 Label Required IND: Y Date Of Label Review: 08/31/2001 Status Code: A Origination Code: F Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: NO Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS: SKIN. MAY BE IRRITATING TO THE SKIN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:N06002 HASTELLOY ALLOY X, 0.062 IN CAGE:80357 CAGE:80357 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 47% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 Ingred Name:COBALT (SARA III) CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: 1.5% Other REC Limits:0.05 PPM OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 Ingred Name:CHROMIUM (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 22% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 9.0% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:TUNGSTEN CAS:7440-33-7 RTECS #:YO7175000 Fraction by Wt: 0.60% OSHA PEL:5 MG/M3/ 10 STEL ACGIH TLV:5 MG/M3/10 STEL;9192 Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 18.5% OSHA PEL:5 MG/CUM Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 1.0% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 1.0% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0.5% Other REC Limits:1 MG(CU)/M3 (DUST) OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2MG/M3 FUME; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BORON CAS:7440-42-8 RTECS #:ED7350000 Fraction by Wt: 0.0008% Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: <20% OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9192 Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS FORMS) (SARA III) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: <20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:BARIUM (SARA III) CAS:7440-39-3 RTECS #:CQ8370000 Fraction by Wt: <20% OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3; 9192 Ingred Name:CALCIUM CAS:7440-70-2 RTECS #:EV8040000 Fraction by Wt: <20% Ingred Name:CALCIUM OXIDE CAS:1305-78-8 RTECS #:EW3100000 Fraction by Wt: <20% OSHA PEL:5 MG/M3 ACGIH TLV:2 MG/M3; 9192 Ingred Name:MAGNESIUM CAS:7439-95-4 RTECS #:OM2100000 Fraction by Wt: <20% Ingred Name:MAGNESIUM OXIDE CAS:1309-48-4 RTECS #:OM3850000 Fraction by Wt: <20% OSHA PEL:15 MG/M3 PARTICULATE ACGIH TLV:10 MG/M3;TDUST; 9293 Ingred Name:POTASSIUM CAS:7440-09-7 RTECS #:TS6460000 Fraction by Wt: <20% Ingred Name:POTASSIUM DIOXIDE CAS:12030-88-5 RTECS #:TT6053000 Fraction by Wt: <20% Ingred Name:SODIUM (SARA III) CAS:7440-23-5 RTECS #:VY0686000 Fraction by Wt: <20% Ingred Name:SODIUM OXIDE CAS:12401-86-4 RTECS #:WC4800000 Fraction by Wt: <20% Ingred Name:STRONTIUM CAS:7440-24-6 RTECS #:WK7825000 Fraction by Wt: <20% Ingred Name:STRONTIUM OXIDE CAS:1314-11-0 Fraction by Wt: <20% Ingred Name:TITANIUM (DRY POWDER) (TI) CAS:7440-32-6 RTECS #:XR1700000 Fraction by Wt: <20% Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INHALATION: NUISANCE DUST MAY CAUSE IRRITATION OF MUCOUS MEMBRANES/NOSE & THROAT, DIZZINESS, PULMONARY IRRITANT, TIGHTNESS IN CHEST, METAL FUME FEVER, DRY THROAT, COUGHING, LOW BACK PAIN, FATIGUE, & H EADACHE. SKIN: ALLERGIC REACTIONS & DERMATITIS. INGESTION: METALLIC TASTE, NAUSEA, BURNS & VOMITING. EYES: INJURY. Explanation of Carcinogenicity:CHROMIUM & NICKEL ARE ANIMAL & HUMAN CARCINOGENS. Effects of Overexposure:INHALATION: POSSIBLE LUNG FIBROSIS, RESPIRATORY HYPERSENSITIVITY/AFFECTS CENTRAL NERVOUS SYSTEM/MUSCULAR WEAKNESS, TREMORS, SYMPTOMS SIMILAR TO PARKINSON'S DISEASE & SIDEROSIS (BENIGN). ELECTRIC SHOCK CAN KILL. SHIELDING GASES CAN DISPLACEBREATHING AIR & CAUSE ASPHYXIATION IN CONFINED WORK SPACES/UNVENTILATED AREAS. Medical Cond Aggravated by Exposure:RESPIRATORY ALLERGIC CONDITIONS. SOME STUDIES SHOW A HIGHER LEVEL OF LUNG RELATED PROBLEMS AMONG OLDER WORKERS WHO SMOKE THAN THOSE WHO DID NOT SMOKE. ======================= First Aid Measures ======================= First Aid:SKIN/EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. INHALATION: REMOVE VICTIM FROM THE WELDING AREA. IF VICTIM IS UNCONSCIOUS, ADMINISTER OXYGEN. IF VICTIM IS NOT BREATHING, BEGIN RESUSCITATION. INGESTION:EMPLOY THE FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:READ & UNDERSTAND ANSI Z49.1 "SAFETY IN WELDING & CUTTING" & NFPA STANDARD 51B FOR FIRE PREVENTION IN "CUTTING & WELDING PROCESSES" BEFORE USING THIS PRODUCT. Unusual Fire/Explosion Hazard:PRODUCT IS NON-FLAMMABLE & NON-EXPLOSIVE, AS SHIPPED. WELDING ARCS & SPARKS CAN IGNITE COMBUSTIBLES & INITIATE FIRES & EXPLOSIONS. ================== Accidental Release Measures ================== Spill Release Procedures:IF THE FUMES ARE REMOVED BY FILTRATION/SOME OTHER MEANS & AIR/GAS STREAM IS PUT BACK INTO THE ROOM, GASES MAY BUILD UP TO TOXIC OR ASPHYXIATION LEVELS. GAS BUILD-UP SHOULD BE MONITORED & IF EXCESSIVE SHOULD BE REMOVED/REDUCED TO SAFE LEVELS. ======================Handling and Storage ====================== Handling and Storage Precautions:ARCS PRODUCE ULTRAVIOLET/INFRARED RADIATION. SMAW ELECTRODES ARE METAL CORE RODS COATED W/FLUX. AVOID PHYSICAL ACCIDENTS. READ LABELS. Other Precautions:TRAIN WELDER TO AVOID ELECTRIC SHOCK BY MAINTAINING A DRY WORK AREA, INSULATING FROM THE WORKPIECE & GROUND. DON'T TOUCH LIVE ELECTRICAL PARTS. PREVENT INJURY FROM RADIATION/SPARKS/& ELECTRIC SHOCK. K EEP HEAD OUT OF WELDING PLUME. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACES/WHERE VENTILATION IS INADEQUATE IN MAINTAINING EXPOSURE <TLV. DETERMINE THE COMPOSITION/QUANTITY OF FUMES/GASES BY TAKI NG AN AIR SAMPLE FROM INSIDE HELMET. Ventilation:USE ENOUGH VENTILATION, LOCAL EXHAUST AT THE ARC, OR BOTH TO KEEP FUMES & GASES FROM THE WORKER'S BREATHING ZONE & <TLV. Other Protective Equipment:ARM/SHOULDER PROTECTORS, APRONS, HATS, WELDER'S HELMET. SEE SUPP FOR LENSE SHADE RECOMMENDATIONS. Work Hygienic Practices:INGESTION OF MATERIAL IS POSSIBLE VIA DIRTY HAND CONTACT W/FOOD & MOUTH. Supplemental Safety and Health START W/LENSE SHADE THAT IS TOO DARK TO SEE THE WELD ZONE. THEN GO TO A LIGHTER SHADE (LOWER NUMBER SHADE) WHICH GIVE SUFFICIENT VIEW OF THE WELD ZONE. OTHER COATING INGREDIENTS (R 20% BY WT) SUCH AS OXIDES/FLUORIDES OF AL, BA, CA, MG, K, NA, SR, & TI. WELDING PRODUCES CHEMICALS KNOWN TO CAUSE CANCER BY THESTATE OF CA. ================== Physical/Chemical Properties ================== Spec Gravity:7-9 Solubility in Water:INSOLUBLE Appearance and Odor:BARE WIRE WELDING PRODUCTS ARE PRODUCED AS STRAIGHT LENGTHS & COILED WIRES. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CO/CO2/OZONE/OXIDES OF NITROGEN/CHROMIUM II & III/NICKEL/COBALT/COPPER. WELDING FUMES/GASES CANNOT BE EASILY CLASSIFIED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF FUME, FLUX & WELD GRINDING RESIDUES FROM THE WORK AREA, OR FROM FILTERS, IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-M-23573,MONOETHANOLAMINE CHLTNG AGT TY1 CAGE:3D869 CAGE:3D869 ============= Composition/Information on Ingredients ============= Ingred Name:MAGNESIUM OXIDE CAS:1309-48-4 RTECS #:OM3850000 OSHA PEL:15 MG/M3 PARTICULATE ACGIH TLV:10 MG/M3;TDUST; 9293 ===================== Hazards Identification ===================== Effects of Overexposure:METALLIC FUME FEVER. ======================= First Aid Measures ======================= First Aid:IRRIGATE EYES WITH WATER.WASH CONTAMINATED AREAS WITH SOAP & WATER. ===================== Fire Fighting Measures ===================== Unusual Fire/Explosion Hazard:MAY IGNITE & EXPLODE WHEN HEATED WITH SUBLIMED SULFUR,MAGNESIUM POWDER OR ALUMINUM POWDER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS WELL CLOSED.WEAR THICK HEATING W/SUBLIMED SULFUR,MAGNESIUM POWDER. Other Precautions:AVOID HEATING ALUMINUM POWDER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST RESPIRATORS,&/OR SELF-CONTAINED BREATHING APPARATUS. Ventilation:AS REQUIRED TO CONTROL TLV IN THE AIR. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:6512F Spec Gravity:3.6 Solubility in Water:SLIGHT Appearance and Odor:WHITE,FINE,ODORLESS POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DUMP INTO AN APPROVED LANDFILL SITE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NEYORO A-A CAGE:FO552 CAGE:FO552 CAGE:43710 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER (SARA III) CAS:7440-22-4 RTECS #:VW3500000 Fraction by Wt: 11.8% Other REC Limits:10 UG/CUM OSHA PEL:0.01 MG/M3 ACGIH TLV:0.1 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 3.2% Other REC Limits:1 MG(CU)/M3 (DUST) OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2MG/M3 FUME; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: PIGMENTATION, CUTS, & BURNS. INGESTION: GASTROINTESTINAL TRACT EFFECTS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN: PIGMENTATION, CUTS, & BURNS. INGESTION: GASTROINTESTINAL TRACT EFFECTS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE & OBTAIN PROMPT MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Unusual Fire/Explosion Hazard:SILVER DUST IS A MODERATE EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:IF LARGE QUANTITIES OF DUST ARE GENERATED, USE INDUSTRIAL VACUUM TO CLEAN UP. MOLTEN METAL SHOULD BE ALLOWED TO SOLIDIFY BEFORE CLEAN UP. ======================Handling and Storage ====================== Handling and Storage Precautions:PROVIDE PROTECTIVE EQUIPMENT WHEN CUTTING, GRINDING, SOLDERING, WELDING, MELTING, MACHINING, & HANDLING OF NON-FERROUS METALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR WHEN CUTTING, GRINDING, SOLDERING OR WELDING. Ventilation:LOCAL EXHAUST VENTILATION TO KEEP DUST, MIST OR FUMES <TLV. Supplemental Safety and Health ALLOY PRODCUTS ARE SOLID METALS SHAPED AS WIRE, PLATE, STRIP OR IN FINISHED FORMS AS INGOTS, NUGGETS, ELECTRICAL CONTACT ASSEMBLIES, SWITCHES OR AS OTHER FORMS FOR ELECTRONIC & DENTAL USE. ================== Physical/Chemical Properties ================== Appearance and Odor:SOLID METAL-WIRE, PLATE, STRIP, INGOTS, NUGGETS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:WELDING FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL OF DUST USING APPROVED METHODS CONSISTANT W/APPLICABLE LOCAL, STATE, & FEDERAL REGULATIONS. MOLTEN METAL SHOULD BE RECLAIMED USING STANDARD INDUSTRIAL PRACTICES SUCH AS REMELTING & REFINING.
1
eyes_protection_mandatory
Product ID:MIL-C-46168B (ME) AIRCRAFT WHITE PREPOLYMER Kit Part:Y CAGE:78767 CAGE:78767 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM ACGIH TLV:150 PPM/200STEL;9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM/300STEL;9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYLENE GLYCOL MONOETHYL ETHER ACETATE [2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)] CAS:111-15-9 RTECS #:KK8225000 Other REC Limits:NONE RECOMMENDED OSHA PEL:S,100 PPM ACGIH TLV:S, 5 PPM; 9394 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9394 Ingred Name:AMORPHOUS & DIATOMACEOUS SILICA [SILICA GEL] CAS:112945-52-5 RTECS #:VV7310000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EXPOSURE MAY CAUSE EYE, SKIN & RESPIRATORY TRACT IRRITATION. CHRONIC: UNKOWN. Explanation of Carcinogenicity:NO INGREDIENTS OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:WATERING OF EYES, DRYNESS OF THROAT, COUGHING, HEADACHE, TIGHTNESS IN CHEST OR BURNING SENSATION, SKIN RASH, ITCHING, HIVES & SWELLING OF EXTREMITIES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. CONSULT WITH PHYSICIAN. EYE: IMMEDIATELY FLUSH WITH LOTS OF WATER. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP & WATER. REMOVE CONTAMINA TED CLOTHING. CONSULT WITH PHYSICIAN. INGESTION: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE 1-2 GLASSES OF WATER. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:21.0F,-6.1C; TCC ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENNTILATE AREA. AVOID BREATHING VAPORS & WEAR USE NIOSH/MSHA APPROVED RESPIRATOR. ADD ABSORBENT TO SPILL, PLACE IN A SEALED METAL CONTAINER, USING NON-SPRAKING TOOL S. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DLA-HMIS: STORE IN A COOL, DRY PLACE AWAY FROM SOURCES OF IGNITION AND INCOMPATIBLE MATERIALS. Other Precautions:GROUND & BOND ALL EQUIPMENT & CONTAINERS WHEN POURING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR EMERGENCY OCCURS; USE NIOSH/MSHA APPROVED RESPIRATOR OR SUPPLIED AIR RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29 CFR 1910.134 AND MANUFACTURER'S RECO MMENDATIONS. Ventilation:USE ADEQUATE EXPLOSION-PROOF MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S)/PEL(S). Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health KEY1=F3. MSDS ENTERED BY DLA-HMIS UNDER PROJECT FOR GSA. ================= Stability and Reactivity Data ================= Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS. DLA-HMIS: EPA/RCRA WASTE NUMBER D001 (IGNITABLE) MAY APPLY TO UNUSED OR UNCONTAMINATED PRODUCT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRO-GARD FUEL INJECTOR CLEANER CAGE:0AHD1 CAGE:0AHD1 ============= Composition/Information on Ingredients ============= Ingred Name:POLYETHER AMINE IN INGRED #2. Other REC Limits:NONE RECOMMENDED Ingred Name:NAPHTHA, LIGHT AROMATIC (SOLVENT NAPHTHA) CAS:64742-95-6 RTECS #:WF3400000 Other REC Limits:NONE RECOMMENDED Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA 313) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 3.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9596 Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <2.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MESITYLENE (TRIMETHYLBENZENES) CAS:108-67-8 RTECS #:OX6825000 Fraction by Wt: <2.0% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:SLIGHT IRRIT,PROL IMPAIRMENT OF VISION.DEGREE OF INJURY DEPEND ON AMT OF MATL/SPEED OF 1STAID.SKIN:SEVERE IRRIT,PROL INJURY.DEGREE OF INJURY DEPEND ON AMT OF MATL/SPEED 1STAID.SKIN:PRACTICALLY NON -TOXIC TO INTERN ORG.INHAL:PROL INHAL CNS EFFECTS.INGEST:SLIGHTLY TOXIC TO INTERN ORG.ASPIRATION HAZ,SEVERE LUNG(SUPPLE) Effects of Overexposure:EYE:PAIN,TEARS,SWELLING,REDNESS,BLURRED VISION.SKIN:PAIN,FEELING OF HEAT,DISCOLORATION,SWELLING,BLISTERING.INHAL:CNS EFFECTS-HEAD,DIZZ,LOSS OF APPETITE,WEAK,LOSS OF COORDINATION.INGEST:Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH IMMED W/WATER FOR @LEAST 15MINS OPENING EYELIDS.REMOVE CONTACT LENSES IF WORN.IRRIT PERSISTS SEE DR.SKIN;REMOVE CONTAMIN CLOTH.WASH WELL W/SOAP/WATER.SIGNS/SYMPT OCCUR SEE DR.INHAL:SIGNS/SYM PT OCCUR MOVE TO FRESH AIR.EFFECTS CONTSEE DR.INGEST:GIVE WATER/MILK TO DRINK.CALL FOR MED ADVICE.DON'T INDUCE VOMIT UNLESS DIRECTED BY MED PERSON.TAKE TO MED EMERG TREAT CNTR W/PROD CNTNR(SUPPLEMEN) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:100F,38C Autoignition Temp:Autoignition Temp Text:660F Lower Limits:NO DATA AVAI Upper Limits:NO DATA AVAI Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures:FIRE INVOLVING MATL DO NOT ENTER ANY ENCLOSED/CONFINED FIRE SPACE W/O PROPER PROTECTIVE EQPMT INCLUDING SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:LIQ EVAPORATES/FORMS VAP(FUMES)WHICH CAN CATCH FIRE/BURN W/EXPLO VIOLENCE.INVISIBLE VAP SPREADS EASILY-CAN BE SET ON FIRE BY IGN SOURCES.FIRE HAZ >LIQ TEMP(SUP) ================== Accidental Release Measures ================== Spill Release Procedures:MATL MAY BE TOXIC TO AQUATIC ORGANISMS,SHOULD BE KEPT OUT OF SEWAGE/DRAINAGE SYS/BODIES OF WATER.STUDY AIR POLLUTION REGS.ELIMINATE ALL OPN FLAM.STOP LEAD/SPILL.CLEANUP ASAP,USE PPE.CONTAIN LIQ-PREVEN T CONTAM SOIL/WATER.FOLLOW REPORTING PROCEDURES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:USE ONLY IN WELL VENTIL AREA.KEEP CNTNR CLSD.REPLACE CAP/BUNG.EMPTIED CNTNR STILL CONTAINS HAZ/EXPLO VAP/LIQ.READ/OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL.READ ENTIRE DOC/LABEL BEF USING PROD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MATL MAY BE INHAL HAZ & UNLESS VENTILATION IS ADEQUATE THE USE OF APPROVED RESPIRATORY PROTECTION IS RECOMMENDED. Ventilation:USE THIS MATL ONLY IN WELL VENTILATED AREAS. Other Protective Equipment:PROTECTIVE CLOTHING. Work Hygienic Practices:DISCARD CONTAMIN NON-WATERPROOF SHOES/BOOTS.WASH CONTAMIN CLOTH.DON'T GET IN EYES/SKIN/CLOTH. Supplemental Safety and Health FIRE/EXPLO HAZ:RISES >85F. HEALTH HAZ:INJURY,DEATH. 1STAID:DR:INGEST/VOMIT CAN RESULT IN ASPIRATION OF LIGHT HYDROCARBON LIQ-CAN CAUSE PNEUMONITIS. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:N/DATA AVAI Melt/Freeze Pt:M.P/F.P Text:NA Decomp Temp:Decomp Text:NP Vapor Pres:0.59PSI Vapor Density:NDA Spec Gravity:0.82 pH:NP Viscosity:1.6CST @40C Evaporation Rate & Reference:NO DATA AVAILABLE. Solubility in Water:INSOLUBLE. Appearance and Odor:CLEAR COLORLESS TO PALE YELLOW LIQUID. Percent Volatiles by Volume:NDN Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT W/STRONG OXIDIZIGN AGENTS SUCH AS CHLORATE,NITRATES,PEROXIDES,ETC. Stability Condition to Avoid:DON'T USE/STORE NEAR FLAM/SPARK/HOT SURF.DON'T WELD/HEAT/DRILL CNTNR.CAUT:DON'T USE PRESSURE TO EMPTY DR-EXPLO MAY RESUL Hazardous Decomposition Products:NA.COMBUST PROD:NORMAL COMBUST FORMS CO2,WATER VAP,MAY PRODUCE OXIDES OF NITROGEN.INCOMPLETE COMBUST CAN PRODUCE CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE CONTAM MATLS IN DISPO CNTNRS/DISPO IN MANNER CONSISTENT W/APPLICABLE REGS.CONTACT LOC ENVIRO/HEALTH AUTHORITIES FOR APPROVED DISPO OF MATL.CONTAIN CHEMS SUBJ TO REPORTING REQMTS SEC 313 TITLE II I SARA/40CFR372.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZE-4B ZYGLO EMULSIFIER Preparer's Name:BRUCE C. GRAHAM CAGE:37676 CAGE:37676 ============= Composition/Information on Ingredients ============= Ingred Name:DISTILLATES (PETROLEUM),HYDROTREATED HEAVY NAPHTHENIC CAS:64742-52-5 RTECS #:PY8035000 Fraction by Wt: >60.0% Ingred Name:TERPINEOL,ALPHA- CAS:98-55-5 RTECS #:WZ6700000 Fraction by Wt: 10.0% ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:ACUTE:MAY IRRITATE EYES.SEE OVEREXPOSURE SYMPTOMS Effects of Overexposure:INHALATION:NOT LISTED BY MANUFACTURER.HOWEVER,FINE SPRAY/MIST MAY CAUSE IRRITATION TO BREATHING PASSAGES; EYES:LIQUID/MIST CAUSES IRRITATION; SKIN:PROLONGED OR REPEATED CONTACT CAUSES IRRITATION BY DI SSOLVING SKIN OILS; INGESTION:NOT NOTEDBY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY THE MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR; SKIN:REMOVE CONTAMINATED CLOTHES.WASH OFF PROMPTLY WITH SOAP AND WATER.USE SOOTHING LOTION.GET MEDICAL HELP IF IRRITATION PERSISTS; EYES:IMMEDIATELY RINSE EYES WITH COP IOUS AMOUNT OF WATER.GET MEDICAL ASSISTANCE IF IRRITATION PERSISTS; INGESTION:NOT STATED BY MANUFACTURER.GET MEDICAL ATTENTION IF INGESTED. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F/>93C Lower Limits:6.0 Upper Limits:1.0 Extinguishing Media:CARBON DIOXIDE,FOAM Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY Unusual Fire/Explosion Hazard:WHEN INVOLVE IN COMBUSTION,MAY EMIT TOXIC GASES AT OR ABOVE DECOMPOSITION TEMPERATURE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES.SM QTY:WIPE UP OR MOP UP BUT DO NOT BREATHE VAPORS.PLACE RAGS IN CLOSED DRUMS; LG QTY:WEAR PERSONAL SAFETY EQUIPMENTS.DIKE AREA FAR AHEAD.ABSORB LIQUID WITH COMMERCIAL ABSORBEN T.TRANSFER WASTE MATL IN SALVAGE TANKS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT SOURCES IN WELL VENTILATED AREA.AVOID AGAINST PHYSICAL DAMAGE TO CONTAINERS.KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:DO NOT BREATHE VAPORS.DO NOT SMOKE WHILE USING.DO NOT HEAT ABOVE 130F(54C).AVOID FREQUENT OR PROLONGED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR FOR CONFINED AREAS. Ventilation:GENERAL ROOM VENTILATION TO KEEP BELOW TLV LIMITS. Other Protective Equipment:NOT KNOWN Work Hygienic Practices:WASH OFF PROMPTLY WITH WATER.AVOID SKIN CONTACT. Supplemental Safety and Health NSN FOR KIT/SET OF MIL-I-25135D,TYPE II,METHOD B MATL;SET CONSISTS OF SKL-LO PENETRANT AND ZE-3 OR ZE-4B EMULSIFIER.THIS ENTRY FOR ZE-4B;QPL-25135-15 ALSO QUALIED ZE-3 & ZE-4B EMULSIFIERS FOR VARIOUS KITS TO GO WITH DIFFERENT PENETRANTS UNDER TYPE I,METHODS A,B,C,D & LEVELS 1,2,3,4;SEE OTHER PNI FOR OTHER PRODUCTS. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:410F/210C Vapor Pres:0.25 @100F Vapor Density:>1.0 Spec Gravity:0.92 Solubility in Water:NEGLIGIBLE Appearance and Odor:PINK OILY LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT KNOWN Stability Condition to Avoid:HEAT,HIGH TEMPERATURE. Hazardous Decomposition Products:EMITS OXIDES OF CARBON WHEN BURNING. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR DISPOSE OF AS EPA HAZARDOUS WASTE D001 (IGNITABLE WASTE),IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,STATE,LOCAL REGULATIONS;IF LOCAL AUTHORITIES PROHIBIT DUMPING RINSINGS DOWN THE SEWER,P URIFY RINSINGS WITH MAGNAFLUX WASTEWATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WESGO METAL PRODUCTS & ALLOYS PALCO CAGE:WESGO CAGE:WESGO ============= Composition/Information on Ingredients ============= Ingred Name:COBALT CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: 35% Other REC Limits:0.05 PPM OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 Ingred Name:PALLADIUM *92/1* CAS:7440-05-3 Fraction by Wt: 65% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION/DISCOLORATION. SKIN: IRRITATION/ALLERGIC REACTION/RASH/DERMATITIS/DISCOLORATION. INHALATION: NOSE/THROAT IRRITATION/SENSITIZED RESPIRATORY DISEASE/COUGH/SHORTNESS OF BREATH/NERVOUS SY STEM EFFECTS/WALKING/BALANCING DIFFICULTY/WEAKNESS/CRAMPS IN LEGS/HOARSENSS OF VOICE/MEMORY/JUDGMENT TROUBLE. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: BENIGN PNEUMOCONIOSIS CALLED STANNOSIS, MUCOUS MEMBRANE DISCOLORATION, UNSTABLE EMOTIONS, PNEUMONIA-LIKE ILLNESS. COPPER MAY PRODUCE KERATINIZATION OF HANDS/SOLES OF FEET. COBALT MAY PRODU CE PERMANENT DISABILITY OR DEATH. BORONMAY PRODUCE SHOCK/COMA. TITANIUM MAY PRODUCE LUNG FIBROSIS/CHRONIC BRONCHITIS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SUPPORT RESPIRATION AS NEEDED. SKIN: WASH W/MILD DETERGENT & WATER. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DON'T USE WATER USE DRY CHEMICAL, SAND OR OTHER APPROPRIATE EXTINGUISHING AGENT FOR SURROUNDING FIRE Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:MAY OCCUR W/CERTAIN METAL DUST FIRES. ================== Accidental Release Measures ================== Spill Release Procedures:USE NORMAL CLEAN-UP PROCEDURES USING WET SWEEPING OR VACUUM, TAKING CARE TO AVOID EXCESSIVE DUSTING. ======================Handling and Storage ====================== Other Precautions:AVOID DUST INHALATION & CONTACT OF MATERIALS W/EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR WHEN AIRBORNE DUST CONCENTRATIONS >PEL/TLV. Ventilation:SUFFICIENT GENERAL & LOCAL EXHAUST TO KEEP <PEL/TLV Other Protective Equipment:EYEWASH FOUNTAIN Work Hygienic Practices:MAINTAIN GOOD HOUSEKEEPING TECHNIQUES SUCH AS WET SWEEPING OR VACUUMING TO REMOVE DUST ACCUMULATION Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:842-3272F Spec Gravity:6-9 Solubility in Water:INSOLUBLE Appearance and Odor:SOLID METAL OR POWDER W/NO ODOR Percent Volatiles by Volume:0% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, STRONG OXIDIZERS, STRONG BASES, & MOISTURE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:UNLEADED GASOLINE Preparer's Name:DELNO MALZAHN,CIH CAGE:OOO33 CAGE:OOO33 ============= Composition/Information on Ingredients ============= Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: 0.5-4.9% OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:GASOLINE CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: 90-95% OSHA PEL:300 PPM/500 STEL ACGIH TLV:300 PPM/500STEL;9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN-RECENT STUDIES INDICATE KIDNEY DAMAGE AND KIDNEY CANCER IN RATS,AND LIVER CANCER IN MICE. Effects of Overexposure:MODERATELY IRRITATING TO SKIN.CAUSES REDNESS AND DRYING OF SKIN. IRRITATING TO MUCOUS MEMBRANES AND RESPIRATORY TRACT.WILL PRODUCE SYMPTOMS OF INTOXICATION. CAN ACT AS A SIMPLE ASPHYXIANT. INGESTION M AY CAUSE MILD EXCITATION,LOSS OF CONSCIOUSNESS,CONVULSIONS,CYANOSIS,CONGESTION AND CAPILLARY HEMORRHAGING OF LUNGS/ORGA. Medical Cond Aggravated by Exposure:MAY AGGRAVATE PRE-EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:FLUSH EYES WITH WATER FOR 15 MIN.GET MEDICAL ATTENTION. FOR SKIN,REMOVE CONTAMINATED CLOTHING,WASH WITH SOAP & WATER.IF INHALED,MOVE TO FRESH AIR.APPLY ARTIFICIAL RESPIRATION IF NOT BREATHING.GET MEDI CAL ATTENTION. IF INGESTED,DO NOT INDUCE VOMITING.IF SPONTANEOUS VOMITING OCCURS,HOLD VICTIM'S HEAD LOWER THAN HIPS TO PREVENT ASPIRATION. ===================== Fire Fighting Measures ===================== Flash Point:-45F Lower Limits:1.4 Upper Limits:7.6 Extinguishing Media:DRY CHEMICAL,FOAM,CARBON DIOXIDE. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS.WATER SPRAY MAY BE INEFFECITVE ON FLAMES,BUT SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:CAN BE IGNITED BY SELF-GENERATED STATIC ELECTRICITY;CONTAINERS SHOULD BE BONDED AND GROUNDED. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF HEAT OR IGNITION,INCLUDING INTERNAL COMBUSTION ENGINES AND ROWER TOOLS.CLEAN-UP SPILL BUT DO NOT FLUSH TO SEWER OR SURFACE WATER.VENTILATE AREA AND AVOID BREATHING VAPORS OR MISTS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN A COOL,DRY PLACE,AWAY FROM SOURCES OF HEAT OR IGNITION. GROUND AND BOND ALL TRANSFE & STORAGE EQUIP WITH SELF CL Other Precautions:CONTACT BELCHER COMPANY FOR FURTHER INFORMATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED RESPIRATORY PROTECTIVE EQUIPMENT FOR CLEANING LARGE SPILLS OR ENTRY INTO LARGE TANKS, VESSELS OR OTHER CONFINED SPACES. Ventilation:PROVIDE ADEQUATE VENTILATION TO KEEP MIST OR VAPORS BELOW ALLOWABLE EXPOSURE LEVELS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:80-430F Melt/Freeze Pt:M.P/F.P Text:VARIABLE Vapor Pres:325-525 Vapor Density:3.4 AIR=1 Spec Gravity:0.7-0.77 Solubility in Water:NEGLIGIBLE Appearance and Odor:BRONZE FLUID,AROMATIC ODOR. Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS,HALOGENS,STRONG ACIDS,ALKALIES. Stability Condition to Avoid:AVOID HEAT,SPARK,FLAMES,BUILD-UP OF STATIC ELECTRICITY. Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE AND HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE THROUGH A LICENSED WASTE DISPOSAL COMPANY. FOLLOW FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2B6-1216 PLASTI-GRIT TYPE II HARD (250 LB DRUM) CAGE:98231 CAGE:98231 ============= Composition/Information on Ingredients ============= Ingred Name:UREA, POLYMER W/FORMALDEHYDE CAS:9011-05-6 RTECS #:YU1610000 Fraction by Wt: 99.5% Ingred Name:STEARAMIDOPROPYLDIMETHYL-BETA-HYDROXYETHYL AMMONIUM NITRATE (QUATERNARY AMMONIUM COMPOUND) CAS:2764-13-8 Fraction by Wt: <0.5% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. INHALATION: RESPIRATORY TRACT IRRITATION. INGESTION: HARMFUL. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/EYES: IRRITATION. INHALATION: RESPIRATORY TRACT IRRITATION. INGESTION: HARMFUL. ======================= First Aid Measures ======================= First Aid:SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. INGESTION: INDUCE VOMITING BY GIVING TWO GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:32F Extinguishing Media:FOAM, DRY CHEMICAL, CO2, WATER, STEAM Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. WEAR A FULL FACE PIECE. Unusual Fire/Explosion Hazard:POWDER FORMS EXPLOSIVE MIXTURE W/AIR. SEALED (CLOSED) CONTAINERS CAN BUILD UP PRESSURE IF EXPOSED TO HEAT (FIRE). ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & PLACE IN APPROPRIATE DISPOSAL CONTAINER. USE PROPER SAFETY EQUIPMENT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED, PROPERLY LABELED CONTAINERS IN COOL VENTILATED AREA. KEEP AWAY FROM HEAT, OPEN FLAMES, & OXIDIZING AGENTS. Other Precautions:DON'T TRANSFER TO UNMARKED CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR AN APPROVED NIOSH/MSHA PROPERLY FITTED DUST RESPIRATOR. Ventilation:PROVIDE MECHANICAL/LOCAL EXHAUST VENTILATION TO KEEP <TLV. Other Protective Equipment:FACESHIELD, PROTECTIVE RUBBER APRON, SHOES OR BOOTS Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKING, OR APPLYING COSMETICS. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health THE UREA FORMALDEHYDE RESIN IS THERMOSET TO FORM A HARD INERT PLASTIC. THERE IS NO RESIDUAL RESIN. ================== Physical/Chemical Properties ================== Spec Gravity:1.5 pH:4-8 Solubility in Water:INSOLUBLE Appearance and Odor:GRANULAR, NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS Stability Condition to Avoid:IGNITION SOURCES SUCH AS OPEN FLAMES & EXCESSIVE HEAT Hazardous Decomposition Products:CO, CO2, SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A SANITARY LANDFILL IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EXTERIOR TRIM ENAMEL WHITE 17875 LEAD & CHR CAGE:2F266 CAGE:2F266 CAGE:6F266 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA III) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 4.0% Other REC Limits:NONE SPECIFIED OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:TEXANOL (ESTER ALCOHOL) CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: 2.0% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:VOC: 62 GRAMS/LITER RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE; SKIN: IRRITATION. EYES: IRRITATION. INGESTION: AMOUNTS INGESTED INCIDENTAL TO CONSUMER AND INDUSTRIAL HANDLING ARE NOT LIKELY TO CAUSE INJURY, HOWEVER, INGESTION OF LARGE AMOUNTS COULD CAUSE IN JURY. Explanation of Carcinogenicity:THIS PRODUCT CONTAINS NO KNOWN CARCINOGENS IN REPORTABLE QUANTITIES AS DEFINED BY NTP, IARC, OSHA, OR EPA. Effects of Overexposure:CHRONIC; INHALATION: PROLONGED INHALATION, IN CONFINED AREA, MAY LEAD TO MUCOUS MEMBRANE IRRITATION, DIZZINES, HEADACHE. Medical Cond Aggravated by Exposure:NONE, WHEN USED IN ACCORDANCE WITH SAFE HANDLING INSTRUCTIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF RESPIRATORY SYMPTOMS DEVELOP, SEEK MEDICAL ATTENTION AT ONCE. SKIN CONTACT: WASH OFF QUICKLY WITH PLENTY OF WATER, THEN SOAP & WATER. REMOVE & WASH CONTAMINATED CLO THING BEFORE REUSE. EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS, FOR AT LEAST 15 MINUTES. OBTAIN EMERGENCY MEDICAL TREATMENT. INGEST: GET EMERGENCY MED TREATMENT. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, DRY CHEMICAL, WATER, OR WATER FOG. Fire Fighting Procedures:WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:WILL NOT BURN, CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:COMPLY WITH ALL APPLICABLE HEATLH AND ENVIRONMENTAL REGULATIONS. VENTILATE AREA. SPILLS MAY BE COLLECTED WITH ABSORBENT MATERIALS. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR/SPRAY MIST. AVOID CONTACT WITH SKIN & EYES. AVOID TEMPERATURES BELOW 40F. KEEP FROM FREEZING Other Precautions:STORE CONTAINERS WITH LIDS TIGHTLY CLOSED AND APPROPRIATELY LABELED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR (NIOSH/OSHA) FOR PROTECTION AGAINST MATERIALS LISTED IN IN GREDIENTS. Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF EXPOSURE TO MATERIAL MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS Work Hygienic Practices:KEEP WORK AREA CLEAN/FREE FROM SPILLS/LEAKS. ALWAYS WASH HANDS W/SOAP & WATER BEFORE HANDLING FOOD, DRINK OR SMOKING. Supplemental Safety and Health THIS PRODUCT CONTAINS NO MERCURY IN REPORTABLE QUANTITIES AS DEFINED BY OSHA AND EPA. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Pres:23.8 @ 25C Vapor Density:> AIR pH:7-8 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:INFINITE Appearance and Odor:THIXOTROPIC LIQUID WITH SLIGHT ODOR; COLOR OF TINT Percent Volatiles by Volume:7.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS AND/OR HYDROFLUORIC ACID. Stability Condition to Avoid:ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENTS. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE Conditions to Avoid Polymerization:ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENTS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO FEDERAL, STATE & LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:101 0784 FILM CEMENT CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:1,4 DIOXANE,CAS#123-91-1,45-50***SUSPECTED CARCINOGEN*** RTECS #:JP8225000 Fraction by Wt: 50% ACGIH TLV:25PPM(S)(MFR) Ingred Name:METHYLENE CHLORIDE(SARA III) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 27% OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE (SARA III) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 17% OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CELLULOSE NITRATE,CAS#9004-70-0,1-5% CAS:9004-70-0 RTECS #:QW0970000 Fraction by Wt: 4% Ingred Name:ALLYL ISOTHIOCYANATE(OIL OF MUSTARD),CAS#57-06-7 RTECS #:NX8225000 Fraction by Wt: <1% ===================== Hazards Identification ===================== Effects of Overexposure:EYE/SKIN:IRR;INH:RESP.TRACT IRR,HEAD,DROWS,DIZZ,NAUSEA;ING:HARMFUL IF SWALLOWED. ======================= First Aid Measures ======================= First Aid:REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEED. SKIN:WASH WITH SOAP & WATER. EYES:FLUSH WITH WATER 15 MIN. KEEP WARM AND QUIET.ING:GIVE 1 OR 2 GLASSES OF WTR.INDUCE VOMIT-IF UNCONSCIOUS,NOTHING BY MOUTH . ===================== Fire Fighting Measures ===================== Flash Point:26F/-3C SCC Lower Limits:UNK Upper Limits:UNK Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,WATER SPRAY Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD BRTHG APP. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES.AVOID INHALATION AND SKIN CONTACT.ABSORB MATERIAL IN VERMICULITE OR OTHER SUITABLE ABSORBENT AND PLACE IN IMPERVIOUS CONTAINER FOR DISPOSAL.FEDERAL,STATE,AND LOCAL REGULATIO NS TAKE PRECEDENCE. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID IGNITION SOURCES.KEEP FROM CONTACT WITH OXIDIZING MATERIALS.STORE IN COOL,DRY AREA.KEEP CONTAINERS CLOSED.PROTECT FROM PHYSICAL DAMAGE. Other Precautions:OBSERVE PRECAUTIONARY LABEL INFORMATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPVD.ORGANIC VAPOR RESPIRATOR Ventilation:LOCAL EXHAUST OR MECHANICAL(GENERAL)RECOMMENDED Other Protective Equipment:AS NECESSARY TO PREVENT SKIN CONTACT. Supplemental Safety and Health MSDS DATED 05-30-85. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:120F/49C Vapor Pres:157 Vapor Density:2.69 Spec Gravity:1.03 Evaporation Rate & Reference:NOT AVAILABLE Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW LIQUID,SLIGHT PUNGENT ODOR. Percent Volatiles by Volume:98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID OXIDIZING MATERIALS Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,HYDROCHLORIC ACID. ==================== Disposal Considerations ==================== Waste Disposal Methods:ELIMINATE IGNITION SOURCES.AVOID INHALATION AND SKIN CONTACT.ABSORB MATERIAL IN VERMICULITE OR OTHER ABSORBING MATERIAL.DISPOSE OF ABSORBED MATL IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL EFFLUENT LAW S.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PETROLEUM HYDROCARBON PLUS ADDITIVES, SB 83 CAGE:70878 CAGE:70878 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENT Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHRONIC: NONE WHEN USED WITH GOOD HYGIENE PRACTICES. MAY OTHER WISE CAUSE SKIN AND EYE IRRITATION UPON PROLONGED OR REPEATED CONTACT. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH LARGE QUANTITIES OF WATER FOR 15 MIN & CALL A PHYSICIAN. SKIN: REMOVE EXCESS WITH CLOTH OR PAPER. WASH THOROUGHLY WITH SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGES TION: CONTACT A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:406F,208C Extinguishing Media:DRYCHEMICAL OR WATERFOG OR CARBON DIOXIDE OR FOAM OR SAND/EARTH. COOL FIRE EXPOSED CONTAINERS WITH WATER. Fire Fighting Procedures:DENSE SMOKE. FIRE FIGHTER SHOULD WEAR SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:DENSE SMOKE. ================== Accidental Release Measures ================== Spill Release Procedures:TRANSFER BULK OF MIXTURE INTO ANOTHER CONTAINER. ABSORB RESIDUE WITH AN INERT MATERIAL, SUCH AS EARTH, SAND OR VERMICULITE. SWEEP UP & DISPOSE AS SOLID WASTE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED UNTIL READY FOR USE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:NONE Other Protective Equipment:NONE Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 Spec Gravity:0.899 Viscosity:>100 Solubility in Water:NEGLIGIBLE Appearance and Odor:AMBER, LIQUID, OIL, MINERAL OIL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS SUCH AS HYDROGEN PEROXIDE, BROMINE & CHROMIC ACID. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:OXIDES OF SULFUR, NITROGEN OR PHOSPHORUS - SULFUR DIOXIDE OR HYDROGEN SULFIDE - HYDROCHLORIC ACID - ALDEHYDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STRIPING PAINTS-VOC COMPLIANT, 03313 ORANGE ATHLETIC CAGE:DO662 CAGE:SPRYN CAGE:DO662 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE VP: 760 CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 15% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:VM&P NAPHTHA; (ALIPHATIC PETROLEUM DISTILLATES) CAS:64742-89-8 Fraction by Wt: 12% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:NAPHTHOL SPIRITS; (VM&P NAPHTHA) VP: 12 CAS:64742-48-9 Fraction by Wt: 4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLUENE (SARA 313) (CERCLA) VP: 22 CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 13% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 10% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC COMPOUND: 56% BY WEIGHT, BAAQMD RULE 45 RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HNDLG/STOR PRECS: ARE GONE: KEEP AREA VENTD. DO NOT SMOKE. EXTING ALL FLAMES, PILOT LIGHTS & HEATERS. TURN OFF (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING & (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: GROUNDING PROCS. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN OR EXPOSE TO TEMP ABOVE 120F. HEAT FROM (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: OF THE DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: 10 MG/M3 (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ Ingred Name:RESP PROT: FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING PAINT OR THE ABRASIVE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOS TO VAPS/S PRAY MISTS. REDNESS & ITCHING OR BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC: (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: TOLUENE APPEARS ON THE NAVY OCCUP CHEM REPRO HAZS LIST. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . PRLNGD OVEREXP TO S OLV INGREDS LISTED MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRO SYS. REPORTS (SUPDAT) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THORO W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES: FLUSH EYES W/L ARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION. INGEST: NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F,<-18C Lower Limits:0.9% Upper Limits:36.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED FOG NOZZS ARE PREF. WATER MAY BE USED TO COOL CLSD (SUPDAT) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLO. DURING USE & UNTIL ALL VAPS (ING 7) Other Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER USING. THIS COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ LEVEL S ONLY DURING SANDING/ABRADING (ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED, NIOSH/MSHA APPROVED ORGANIC VAP/PARTICULATE RESP. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/ MIST RESP APPRVD BY NIOSH/MSHA (ING 14) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94,107,108. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. EFTS OF OVEREXP: HAVE ASSOC RPTD & PRLNGD OVEREXP TO SOLVS W/PERM BRAIN & NERVS SYS DMG. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<325F,<163C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:>50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCIN. DEPRESSURIZE CNTNR. DISPOSE OF I/A/W FED, STATE & LOC REGS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZEP SUN SOLVENT #0419 CAGE:27674 CAGE:27674 ============= Composition/Information on Ingredients ============= Ingred Name:D-LIMONENE (ORANGE DISTILLATE; CITRUS TERPENE; CYCLOHEXENE, 1-METHYL-4-(1-METHYL LETHENYL)-, (R)- CAS:5989-27-5 RTECS #:GW6360000 Fraction by Wt: 25-35% Other REC Limits:NONE RECOMMENDED Ingred Name:NONYLPHENOXYPOLYETHYLENEOXYETHANOL CAS:9016-45-9 RTECS #:MD0900000 Fraction by Wt: <5.0% Other REC Limits:NONE RECOMMENDED Ingred Name:NONYLPHENOXYPOLYETHYLENEOXYETHANOL CAS:9016-45-9 RTECS #:MD0900000 Fraction by Wt: <5.0% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY IRRITATE EYES/SKIN. EYE INFLAMMATION CHARACTERIZED BY REDNESS, WATERING, ITCHING. SKIN INFLAMMATION CHARACTERIZED BY ITCHING, SCALING, REDDENING, OCCASIONALLY BLISTERING. ONE INGREDIENT HAS CAUSED SENSITIZATION REACTIONS IN SMALL PERCENTAGE OF GENERAL POPULATION. CHRONIC: THERE ARE NO KNOWN EFFECTS. Medical Cond Aggravated by Exposure:INGREDIENTS IN THIS PRODUCT MAY AGGRAVATE EXISTING SKIN, EYE, RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH THOROUGHLY W/SOAP OR MILD DETERGENT. APPLY SKIN CREAM W/LANOLIN. GET MEDICAL AID IF IRRITATION PERSISTS. EYES: FLUSH W/PLENTY OF WATER >15 MIN OCCASIONALLY LIFTING LIDS. GET MEDICAL AID AT ONCE. INHALATION: GET TO FRESH AIR. IF IRRITATION PERSISTS GET MEDICAL AID PROMPTLY. INGESTION: DON'T INDUCE VOMITING. IF VOMITING OCCURS KEEP HEAD BELOW HIPS. GET EMERGENCY MEDICAL AID IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:122F,50C Lower Limits:0.7 Upper Limits:6.1 Extinguishing Media:CO2, DRY CHEMICAL. Fire Fighting Procedures:WEAR POSITIVE PRESSURE SCBA. Unusual Fire/Explosion Hazard:FIRE EXPOSED DRUMS SHOULD BE COOLED W/STREAM OF WATER. ================== Accidental Release Measures ================== Spill Release Procedures:IMMED REMOVE FLAME/IGNIT/HEAT SOURCES. ABSORB ON INERT ABSORBENT. PICK UP/PLACE RESIDUE IN SUITABLE WASTE CONTAINER OR IF PERMITTED FLUSH TO SEWER. THOROUGHLY FLUSH AREA W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:COMBUSTIBLE. STORE/USE AWAY FROM HEAT, SPARKS, OPEN FLAME, IGNITION SOURCES. DON'T USE IMMEDIATELY BEFORE OR AFTER ACIDIC DRAIN CLEANER. Other Precautions:STORE TIGHTLY CLOSED CONTAINER IN DRY AREA BETWEEN 40-120F. KEEP AWAY FROM SKIN/EYES. DON'T BREATHE SPRAY MISTS/VAPORS. DON'T REWEAR CONTAM CLOTHES UNTIL THOROUGHLY CLEANED. KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO EXTRA MEASURES NEEDED IF VENTILATION ADEQUATE. Ventilation:LOCAL EXHAUST VENTILATION AS NEEDED TO KEEP VAPOR CONCENTRATIONS BELOW EXPOSURE LIMITS (PEL/TLV). STRONGLY RECOMMENDED ESPECIALLY WHEN WEARING CONTACTS. Supplemental Safety and Health *EFFLUENT ULTIMATELY TREATED BY POTW NEUTRALIZATION OF SPENT TANK SOLUTION W/SUBSEQUENT DISCHARGE TO SEWER MAY BE POSSIBLE. CONSULT LOCAL, STATE, FEDERAL AGENCIES FOR PROPER DISPOSAL METHOD. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:220F,104C Vapor Pres:NOT EST. Vapor Density:>1.0 Spec Gravity:0.957 pH:9.9.5 Evaporation Rate & Reference:AS WATER Solubility in Water:COMPLETE Appearance and Odor:CLEAR, SLIGHTLY VISCOUS YELLOWISH LIQUID, CITRUS AROMA Percent Volatiles by Volume:83.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NK Stability Condition to Avoid:HEAT, OPEN FLAME, SPARK, OXIDIZING AGENTS. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, OTHER UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:LIQ CAN'T BE LANDFILLED UNLESS SOLIDIFIED. SPENT USE-DILUTIONS MAY REQ DISPOSAL AS HAZ WASTE AT PERMITTED TREATMENT/STORAGE/DISPOSAL FACILITY. IN MOST STATES HAZ WASTE =>220 LBS PER MONTH MAY BE DISPO SED IN CHEM/INDUST LANDFILL. IF*
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HEAT FENCE CAGE:OBTX0 CAGE:OBTX0 CAGE:55278 ============= Composition/Information on Ingredients ============= Ingred Name:BENTONITE CAS:1302-78-9 RTECS #:CT9450000 Fraction by Wt: 3-50% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (DUST) ACGIH TLV:5 MG/M3 (DUST) Ingred Name:DEIONIZED WATER Fraction by Wt: 50-70% Other REC Limits:NONE RECOMMENDED Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.05 MG/M3 RDUST9495 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: SHORT-TERM OVEREXPOSURE TO WELDING FUMES MAY RESULT IN DISCOMFORT SUCH AS: DIZZINESS, NAUSEA, DRYNESS, IRRITATION OF NOSE/THROAT/EYES, TIGHTNESS IN CHEST, FEVER, ALLERGIC REACTIONS. CHRONIC: LO NG-TERM EXPOSURE TO WELDING FUMES MAY LEAD TO SIDEROSIS AND IS BELIEVED TO AFFECT PULMONARY FUNCTION. Explanation of Carcinogenicity:CRYSTALLINE SILICA IS LISTED BY IARC AS A (2A) SUSPECTED CARCINOGEN. Effects of Overexposure:DIZZINESS, NAUSEA, DRYNESS, IRRITATION OF NOSE/THROAT/EYES, TIGHTNESS OF CHEST, FEVER, ALLERGIC RECTIONS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:REMOVE TO FRESH AIR & OBTAIN MEDICAL ATTENTION. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. ===================== Fire Fighting Measures ===================== Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND DISPOSE OF IN A DOT-APPROVED WASTE CONTAINER. KEEP OUT OF SEWERS, STORM DRAINS, SURFACE WATERS AND SOIL. COMPLY WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS FOR WASTE DISPOSAL . Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health OTHER PRECAUTIONS FOR ADDITIONAL SAFETY INFORMATION ON WELDING AND CUTTING, SEE AMERICAN STANDARD Z49.1-1983, "SAFETY IN WELDING AND CUTTING", AND THE WELDING HANDBOOK, VOL. 1, CHAPTER 9, "SAFE PRACTI CES IN WELDING AND CUTTING." BOTH ARE AVAILABLE FROM THE AMERICAN WELDING SOCIETY, PO BOX 351040, MIAMI, FL 33135. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:2.5 Appearance and Odor:GRAY/TAN PASTE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE, UNLESS OTHERWISE SPECIFIED. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE, OXIDES OF NITROGEN, OZONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR1826 B-2 BASE COMPOUND, 1826B12 Kit Part:Y CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM OXIDE;(TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE)(MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: <5% OSHA PEL:200 PPM ACGIH TLV:200 PPM; 300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POLYTHIOETHER POLYMER;(MERCAPTAN TERM POLYTHIOETHER) CAS:119147-78-3 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALUMINUM HYDROXIDE CAS:21645-51-2 RTECS #:BD0940000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA DERIVITIVES CAS:67762-90-7 OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:VOLATILE ORGANIC CONTENT: 48 G/L (COMBINED PART A & B) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ING 3: EYES: MAY CAUSE BURNING, TEARING & REDDENING. POSSIBLE TRANSIENT CORNEAL CLOUDING. SKIN: PROLONGED EXPOSURE MAY CAUSE REDNESS, BURNING, DRYING & CRACKING OF SKIN. INHAL: MAY CAUSE COUGHING, CHE ST PAIN. THROAT IRRITATION MAY CAUSE HEADACHES & DIZZINESS; MAY BE ANESTH & MAY CAUSE OTHER CNS EFTS.(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: REVERSIBLE LIVER DAMAGE IS POSSIBLE AT HIGH DOSES. INGEST: MAY CAUSE DROWSINESS, DIZZINESS & NAUSEA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LUKE WARM WATER FOR AT LEAST 15 MINUTES. IF SYMPTOMS PERSIST, CONSULT MD. SKIN: WASH W/SOAP & WATER. IF SYMPTOMS PERSIST, CONSULT MD. INHAL: REMOVE TO FRESH AIR. IF SYMPTOMS ARE PRESENT. CONSULT MD. INGEST: CONSULT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:150F,66C Lower Limits:1.8% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP INTO CONTAINERS. CLEAN-UP RESIDUE W/SUITABLE SOLVENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLOSED. DO NOT STORE >120F. GROUNDING & BONDING PROCEDURE SHOULD BE FOLLOWED WHEN TRANSPORTING MATERIAL. Other Precautions:EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE OR WELD ON OR NEAR DRUM. VAPORS OF THIS PRODUCT ARE HVR/AIR AND MAY COLLECT IN LOW OR CONFINED AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN APPLYING IN ANY CIRCUMSTANCES LIKELY TO PRODUCE AIRBORNE LEVEL OF HAZARDOUS INGREDIENTS IN EXCESS OF TLV, USE A NIOSH/MSHA APPROVED VAPOR CARTRIDGE OR AIR-SUPPLIED RESPIRATOR. Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW PEL. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE SMOKING OR EATING. AVOID INGESTION. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NONE Vapor Density:HVR/AIR Spec Gravity:1.453 Appearance and Odor:WHITE PASTE. Percent Volatiles by Volume:5.8 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:OXIDES OF CARBON, SULFUR DIOXIDE, TRACES OF HYDROGEN SULFIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA NO D-035 HAZARDOUS WASTE. DISPOSE OF IN COMPLIANCE WITH FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CORROSION REMOVING COMPOUND Preparer's Name:DGSC-SSH CAGE:LO745 CAGE:LO745 CAGE:2U704 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID (SARA III) CAS:7664-38-2 RTECS #:TB6300000 Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3/3 STEL ACGIH TLV:1 MG/M3/3 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Other REC Limits:NONE SPECIFIED OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-INHALE:MISTS CAUSE RESPIRATORY TRACT IRRITATION, COUGHING, DESTRUCTION OF MUCOUS MEMBRANES, PULMONARY EDEMA. EYE/SKIN:WILL PRODUCE SEVERE BURNS & INJURY. ORAL:WILL DAMAGE TISSUES ON CONTACT. MAY CAUSE SEVERE INJURY OR DEATH. CHRONIC-UNKNOWN. Effects of Overexposure:MISTS CAUSE RESPIRATORY TRACT IRRITATION, COUGHING, DESTRUCTION OF MUCOUS MEMBRANES, PULMONARY EDEMA. WILL PRODUCE SEVERE EYE AND SKIN BURNS & INJURY ON CONTACT. ORALLY WILL DAMAGE TISSUES ON CONTACT.MAY CAUSE SEVERE INJURY OR DEATH. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IMMEDIATELY. EYE/SKIN:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED. ORAL:DO NOT INDUCE VOMI TING. IF CONSCIOUS, DRINK LARGE AMOUNT OF WATER/MILK. CALL A PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:135F,57C MIN. Extinguishing Media:WATER SPRAY, CO2, FOAM/DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. WEAR PROTECTIVE EQUIPMENTS. CONTAIN SPILL AND LEAKS TO PREVENT DISCHARGE TO THE ENVIRONMENT. NEUTRALIZE CAUTIOUSLY WITH A BASE SUCH AS SODA ASH. TRAN SFER TO A CONTAINER FOR DISPOSAL. Neutralizing Agent:SODA ASH ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE IN COOL, VENTILATED AREA, IN TIGHTLY CLOSED CONTAINERS, AWAY FROM HEAT, FLAMES & ALKALIES. Other Precautions:AVOID BREATHING VAPORS OR MISTS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. KEEP OUT OF REACH OF C HILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A NIOSH-APPROVED MIST RESPIRATOR IS RECOMMENDED. IF CONCENTRATION EXCEEDS CAPACITY OF RESPIRATOR, USE SELF-CONTAINED BREATHING APPARATUS. Ventilation:MECHANICAL SUFFICIENT TO MAINTAIN LEVELS OF CONCENTRATION BELOW TLV OF ANY CONSTITUENTS. Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND IMPERVIOUS CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health NO MSDS WAS AVAILABLE FROM MANUFACTURER. THIS MSDS WAS PREPARED BY THE PROFESSIONALS OF DGSC-SSH WITHOUT ANY WARRANTY. IT IS THE USER'S RESPONSIBILITY TO GATHER INFORMATION AND USE THE MATERIAL PROPER LY TO PROTECT EMPLOYEES AND ENVIRONMENT. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:212F,100C pH:<2 Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIES Stability Condition to Avoid:FIRE AND EXCESSIVE HEAT Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: 111-45-W219, SANTOPRENE THERMOPLASTIC RUBBER (SUPDAT) Cage: 41599 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 41599 Cage: 00SQ0 Box: UNKNOW ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: OCCUP EXPOS TO THIS MATL IN NORM HDNLG & STOR HAS NOT BEEN REPORTED TO CAUSE SIGNIFICANT ADVERSE HUMAN HLTH EFTS. DUE TO ITS CHEM & PHYSICAL PROPERTIES, SANTOPRENE THERMOPLASTIC RUBBER DOES NOT APPEAR TO POSSESS ANY TOXICOLOGICAL PROPERTIES WHICH WOULD REQ SPECIAL HNDLG OTHER THAN GOOD INDUSTRIAL(EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: HYGIENE & SAFETY PRACTICES EMPLOYED W/ANY INDUSTRIAL MATL OF THIS TYPE. UNDER NORM PROCESSING CNDTNS, PROD WILL RELEASE FUMES & VAPS. COMPONENTS OF THESE RELEASES MAY VARY W/PROCESSING TIMES & TEMPS & THEREFORE SPECIFIC COMPOSITION CANNOT BE PREDICTED BASED ON CURRENT INFO. THESE PROCESS RELEASES Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INHAL: REMOVE TO FRESH AIR. IF BREATHING IS DFCLT, GET MED ATTN. EYES: FLUSH W/POTABLE WATER FOR AT LEAST 15 MINS. SEE MD(FP N). SKIN: FLUSH W/COPIOUS AMTS OF WATER. SEE MD(FP N). INGEST: CALL MD IMME DIATELY (FP N). ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: VACUUM OR SWEEP UP & PLACE IN CLEAN, COVERED CONTAINERS FOR RECYCLE OR DISPOSAL. SPILLED PRODUCT MAY CAUSE A SLIPPING HAZARD. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: WHEN DISCARDED, SANTOPRENE THERMOPLASTIC RUBBER IS NOT "HAZ WASTE" AS THAT TERM IS DEFINED IN 40CFR261, "IDENTIFICATION & LISTING OF HAZ WASTE". RECYCLE/BURN IN APPRVD INCIN/DISP OF IN APPRVD CHEM LAN DFILL I/A/W ALL APPLIC LOC, STATE & FED Handling And Storage Precautions: AVOID LEAVING CNTNR OPEN FOR PRLNGD PERIODS TO PVNT EXPOS TO HUMIDITY. STORE IN COOL, DRY PLACE.PRACS INCL AVOIDING UNNEC EXPOS & REMOVAL OF Other Precautions: SANTOPRENE THERMOPLASTIC RUBBER WILL PICK UP SMALL AMTS OF MOISTURE. USUAL PRECS IN PELLET HANDLING SHOULD BE OBSERVED TO PREVENT CONTAM BY DIRT/OTHER MATERIALS. AVOID BREATHING PROCESSING FUMES/VAPOR S. PROCESS USING ADEQ VENT. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: SCC Flash Point Text: >650F,>343C Extinguishing Media: WATER SPRAY/ANY CLASS A EXTINGUISHING AGENT. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT(FP N). Unusual Fire/Explosion Hazard: CARBON MONOXIDE IS LIBERATED AS A TOXIC DECOMPOSITION PRODUCT WHEN SANTOPRENE THERMOPLASTIC RUBBER IS IGNITED. ======================================================= Control Measures ======================================================= Respiratory Protection: AVOID BRTHG PROCESS VAPS/DUST. USE NIOSH/MSHA APPRVD RESP PROT EQUIP(FULL FACEPIECE RECOMM) WHEN AIRBORNE EXPOS IS EXCESS. CONSULT RESP MFR TO DETERMINE APPROP TYPE EQUIP FOR GIVEN APPLIC. OBSERVE RES P USE LIMITATIONS SPECIFIED BY Ventilation: ROVIDE NATURAL/MECH VENT TO MIN EXPOS. IF PRACTICAL, USE LOC MECH EXHST VENT AT SOURCES OF AIR CONTAM SUCH AS Other Protective Equipment: EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA(FP N). Work Hygienic Practices: USE GOOD INDUSTRIAL PRACTICE TO AVOID CONTACT. WASH HANDS & CONTAMD SKIN THORO AFTER HNDLG. Supplemental Safety and Health: TRADENAME/PART #: MOLDING GRADES. USERS OF THE "L" VERSION OF TO CONSULT THE "LR" VERSION FOR FURTHER INFORMATION(FP N). MATL TO AVOID: & ABOVE, PRDCG DECOMP OF ACETAL RESIN & FORMALDEHYDE AS DEC OMP PROD. DECOMP OF HALOGENATED POLYMERS & PHENOLIC RESINS MAY ALSO BE ACCELERATED WHEN ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 0.95-0.98 Appearance and Odor: BLACK/NATURAL (COLORABLE) PELLETS W/SLIGHTLY RUBBERLIKE ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: STABLE TO 500F. Materials To Avoid: SANTOPRENE THERMOPLASTIC RUBBER MAY REACT W/STRONG OXIDIZING CHEMS. REACTS W/ACETAL RESINS AT TEMPS 425F(218C)(SUPDAT) Hazardous Decomposition Products: SMOKE, CARBON MONOXIDE & POSS HYDROCARBONS MAY EVOLVE WHEN PROCESSING TEMPS EXCEED 500F/WHEN SANTOPRENE (ING 7 Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 111-45-W219, SANTOPRENE THERMOPLASTIC RUBBER (SUPDAT) Cage: 41599 Company Name: ADVANCED ELASTOMER SYSTEMS Street: 540 MARYVILLE CENTRE DR Zipcode: 63166-6735 Label Required IND: Y Date Of Label Review: 05/05/1995 Status Code: C Label Date: 05/05/1995 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE: RESPIRATORY TRACT IRRITATION. VAPOR MAY CAUSE NAUSEA, DROWSINESS & HEADACHE. CHRONIC: NONE SPECIFIED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMERCOAT 395 Kit Part:Y CAGE:55849 CAGE:55849 ============= Composition/Information on Ingredients ============= Ingred Name:EPICHLOROHYDRIN AND PHENYLAMINE RTECS #:KD4250000 Fraction by Wt: 35% ACGIH TLV:UNK Ingred Name:METHYL N-AMYL KETONE RTECS #:PG8750000 Fraction by Wt: <5% ACGIH TLV:100PPM Ingred Name:BUTYL CELLOSOLVE RTECS #:EP3600000 Fraction by Wt: <5% ACGIH TLV:50PPM Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <5% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:SKIN,EYES AND MUCOUS MEMBRANE IRRITATION;INHALATION:HEADACHE,DIZZINESS AND NAUSEA ======================= First Aid Measures ======================= First Aid:INHALATION:FRESH AIR AND ARTIFICIAL RESPIRATION IF REQUIRED.SKIN CONTACT:WASH WITH SOAP AND WATER.EYES:IMMEDIATE 15 MINUTES WATER FLUSH,CONTACT PHYSICIAN.CLOTHING:LAUNDER ===================== Fire Fighting Measures ===================== Flash Point:108F 42C Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM Fire Fighting Procedures:BLANKET FLAMES WITH MEDIA;WEAR APPROVED PORTABLE RESPIRATOR ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. USE ABSORBENT CLEAN UP MATERIALS. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID HEAT,OPEN FLAME. KEEP CONTAINER CLOSED. Other Precautions:AVOID INHALING VAPOR, SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AIRLINE HOOD TYPE RESPIRATOR Ventilation:EXHAUST FAN WITH DUCT Other Protective Equipment:NONSPARKING SHOES AND TOOLS Supplemental Safety and Health KEY1:J1. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:149C Spec Gravity:1.7 Appearance and Odor:SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:OPEN FLAME,SPARK OR ARC Hazardous Decomposition Products:COMBUSTION:CO,002,ACIDS,ALDEHYDES,ALIPHATIC KETONES,DIAMINES ==================== Disposal Considerations ==================== Waste Disposal Methods:CLOSED METAL CONTAINER IN ACCORDANCE WITH REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:9595S CRONAR REDUCERS,ADDITIVES,INITIATORS Preparer's Name:T R LOUER CAGE:23027 CAGE:90227 CAGE:23027 ============= Composition/Information on Ingredients ============= Ingred Name:HEAVY AROMATIC SOLVENT NAPHTHA PETROLEUM *96-3* CAS:64742-94-5 RTECS #:WF3100000 Ingred Name:ETHYL 3-ETHOXYPROPIONATE, PROPANOIC ACID, 3-ETHOXY-, ETHYL ESTER *96-3* CAS:763-69-9 RTECS #:UF3325000 Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS CAS:64742-88-7 Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:METHYL PARAHYDROXYBENZOATE, METHYLPARABEN CAS:99-76-3 RTECS #:DH2450000 Ingred Name:MIXED DIBASIC ESTERS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NOSE & THROAT IRRITATION. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. SKIN: IRRITATION, DERMATITIS. EYES: IRRITATION, BURNING. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, LOSS OF COORDINATION, DISCOMFORT, GI DISTRESS. ======================= First Aid Measures ======================= First Aid:INGESTION: CALL A PHYSICIAN IMMEDIATELY & HAVE THE NAMES OF INGREDIENTS AVAILABLE. INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYES: WASH W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:>100F Lower Limits:0.2 Upper Limits:13 Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT W/SCBA. WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS FLAMMABLE VAPORS WHICH, WHEN MIXED W/AIR, CAN BURN/EXPLODE. FINE MISTS/SPRAYS MAY BE FLAMMABLE AT TEMP 120F. Other Precautions:DON'T SAND, FLAME CUT, BRAZE/WELD DRY COATING W/O NIOSH/MSHA APPROVED RESPIRATOR/APPROPRIATE VENTILATION. DON'T BREATHE VAPORS/MISTS. DON'T PERMIT ANYONE W/O PROTECTION IN THE PAINTING AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A PROPERLY FITTED VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR USE W/PAINTS DURING APPLICATIONS. IN CONFINED AREAS, USE A POSITIVE-PRESSURE, SUPPLIED AIR RESPIRATOR. Ventilation:SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS. Other Protective Equipment:COVERALLS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING/SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:129-711F Vapor Density:>1 VOC Grams/Liter:7.4 Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:MISCIBLE Percent Volatiles by Volume:49-100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, SPARKS, FLAMES, TEMP >120F. Hazardous Decomposition Products:CO, CO2, SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IAW/FEDERAL, STATE & LOCAL REGULATIONS. FLAMMABLE LIQUID, UN1263.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COAST POWER STRIPPER CAGE:0SXN4 Contract Num:SP0450-99-D-4031-002Z CAGE:0SXN4 Contract Num:SP0450-99-D-4031-007Z CAGE:0SXN4 Contract Num:SP0450-99-M-C556 CAGE:0SXN4 ============= Composition/Information on Ingredients ============= Ingred Name:BUTYL CELLOSOLVE CAS:111-76-2 RTECS #:KJ8575000 < Wt:12. OSHA PEL:240 MG/M3;50 PPM ACGIH TLV:121 MG/M3;25 PPM Ingred Name:2-AMINOETHANOL CAS:141-43-5 RTECS #:KJ5775000 < Wt:7. OSHA PEL:6 MG/M3;3 PPM ACGIH TLV:7.5 MG/M3;3 PPM ACGIH STEL:15 MG/M3;6 PPM Ingred Name:SODIUM SILICATE CAS:1344-09-8 < Wt:3. Ingred Name:OTHER SPECIFIC CHEMICALS HELD AS A TRADE SECRET ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED OR REPEATED CONTACT OF CONCENTRATED PRODUCT WITH SKIN AND/OR EYES WILL CAUSE IRRITATION AND REDDENING. MAY CAUSE CHEMICAL BURNS IF CONTACT IS PROLONGED. HARMFUL OR FATAL SWALLOWED. Effects of Overexposure:CONTAINS MATERIAL WHICH PENETRATES SKIN READILY. INGESTION, PROLONGED OR WIDESPREAD CONTACT MAY RESULT IN THE ABSORPTION OF POTENTIALLY HARMFUL AMOUNTS. Medical Cond Aggravated by Exposure:AN EXISTING DERMATITIS; PULMONARY DYSFUNCTION. ======================= First Aid Measures ======================= First Aid:EYES-FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND CALL A PHYSICIAN IMMEDIATELY. SKIN-WASH AFFECTED AREA WITH LARGE AMOUNTS OF SOAP & WATER. CALL A PHYSICIAN IF IRRITATION PERSISTS. INGESTED-DO NOT IND UCE VOMITING! DILUTE BY DRINKING WATER (IF CONSCIOUS). CALL A PHYSICIAN IMMEDIATELY. INHALED-REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF BRETAHING STOPPED. OXYGEN MAY BE ADMINISTERED. CALL A P HYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE TO BOILING Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, OR DRY CHEMICAL. Fire Fighting Procedures:DO NOT ENTER CONFINED FIRE SPACES WITHOUT PROTECTIVE CLOTHING AND SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NDA. ================== Accidental Release Measures ================== Spill Release Procedures:SAFELY STOP LEAK/SPILL AT SOURCE. CONTAIN SPILL BY DIKING WITH SOIL OR OTHER INERT MATERIAL. MOP, PUMP, OR ABSORB WITH INERT MATERIAL & RECLAIM INTO SOUND CONTAINERS FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN TIN, GAVAIZED OR ALUMINUM CONTAINERS. Other Precautions:READ LABEL AND FOLLOW DIRECTIONS THOROUGHLY BEFORE USING THIS PRODUCT. CAUSES SEVERE BURNS TO SKIN & EYES. CONTACT WITH EYES CAN CAUSE PERMANENT EYE DAMAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ADEQUATE VENTILATION. Ventilation:MECHANICAL. CONTACT. Other Protective Equipment:WORK CLOTHING COVERING ARMS AND LEGS AS REQUIRED TO MINIMIZE CONTACT. Work Hygienic Practices:AVOID CONTACT WITH EYES AND WITH SKIN. USE ADEQUATE VENTILATION. FOLLOW FIRST AID PROCEDURES Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B2 Boiling Pt:=100.C, 212.F Vapor Pres:NDA Vapor Density:NDA Spec Gravity:1.047 pH:13 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, YELLOW, CLEAR, PLEASANTLY SCENTED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, OXIDIZERS. DO NOT MIX WITH CHLORINATED DETERGENTS OR SANITIZERS. Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PIGMENTS, VARIOUS COLORS CAGE:0WTR8 CAGE:0WTR8 ============= Composition/Information on Ingredients ============= Ingred Name:THIS PRODUCT, AS SUPPLIED IS NOT HAZARDOUS BY THE DEFINITION OF HAZARD DETERMINATION 29 CFR 1910.1200. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EFFECTS OF OVEREXPOSURE: EYES: CAN CAUSE IRRITATION, REDNESS, TEARING. SKIN: PROLONGED OR REPEATED CONTACT CAN CAUSE SLIGHT IRRITATION. INGESTION: CAN CAUSE GASTROINTESTINAL IRRITATION. Explanation of Carcinogenicity:NOT LISTED AS A CARCINOGEN BY NTP, IARC AND OSHA. Effects of Overexposure:SEE HEALTH HAZARDS ACUTE AND CHRONIC . ======================= First Aid Measures ======================= First Aid:SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER BEFORE REUSE. EYES: FLUSH WITH LARGE QUANTITIES OF WATER, LIFTING UPPER AND LOWER LIDS OCCASIONALLY, GET M EDICAL ATTENTION. INGESTION: INDUCE VOMITING, KEEP PERSON WARM, QUIET AND GET MEDICAL ATTENTION IMMEDIATELY. GIVE 2 GLASSES OF WATER IF CONSCIOUS. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON . INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING. CONTACT A PHYSICIAN IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>93.3C, 200.F GREATER THAN 200 Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICAL EXTINGUISHERS FOR SMALL FIRES. USE FOAM FOR LARGE FIRES. Fire Fighting Procedures:USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT . COOL CLOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BUILD EXPLOSIVE PRESSURE FROM HEAT. NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM, EVEN EMPTY. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS: STOP DISCHARGE & CONTAIN SPILL. RECOVER WITH PUMPING EQUIPMENT, COMMERCIAL ABSORBENTS, VERMICULITE OR OTHER INERT ABSORBENT MATERIALS. PLACE IN APPROPRIATE CONTAINER FOR FURTHER HANDLING . LARGE SPILLS: STOP DISCHARGE & CONTAIN SPILL OR CONTAMINATED MATERIAL USING DIKE, BARRIER OR OTHER MEANS. RECOVER WITH VACUUM TRUCK, ABSORBENTS OR OTHER MEANS. PLACE CONTAMINATED (TOXICOLOGICAL) ======================Handling and Storage ====================== Other Precautions:AVOID CONTACT WITH SKIN AND EYES. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE OF CONCERN . Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION. (SUPP SAFETY) Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS. ALSO, HAVE EYE BATH AND SAFETY SHOWER AVAILABLE (MEETING ANSI DESIGN CRITERIA, ). Supplemental Safety and Health ARE ADVISED; HOWEVER, OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. CONSULT YOU SAFETY EQUIPMENT SUPPLIER. PHYSICAL/CHEM ICAL PROPERTIES (CON'T): WEIGHT PER GALLON: 9.33 #. ================== Physical/Chemical Properties ================== Vapor Density:> AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NOT SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:NEGLIGIBLE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, ACIDS AND PEROXIDES. Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, LOW WEIGHT MOLECULAR WEIGHT HYDROCARBONS, ORGANIC ACIDS. =================== Toxicological Information=================== Toxicological Information:N/P SPILL/RELEASE PROCEDURES (CONT): MATERIAL IN SUITABLE CONTAINER(S) FOR FURTHER HANDLING. HAZARDS TO AVOID: DO NOT FLUSH TO STREAM, OTHER BODIES OF WATER OR SEWER. AVOID CONTACT WITH SKIN OR CLOT HING. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL METHODS: RECYCLE, IF FEASIBLE. INCINERATE AT AUTHORIZED FACILITY. TREATMENT AT INDUSTRIAL OR LIQUID WASTE TREATMENT FACILITY. LANDFILL AFTER SOLIDIFICATION IN A FACILITY AUTHORIZED TO RECEIVE WASTE. NOTE: THIS MATERIAL, IF BEING DISCARDED, SHOULD BE DISPOSED IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MERCURIC OXIDE CELL,BA-1574/U CAGE:90303 CAGE:90303 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 9% Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MERCURIC OXIDE (SARA III) CAS:21908-53-2 RTECS #:OW8750000 Fraction by Wt: 35 - 45% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG HG/M3;SKIN;C ACGIH TLV:0.1 MG HG/M3; 9293 Ingred Name:MERCURY (SARA III) CAS:7439-97-6 RTECS #:OV4550000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, C, 0.1 MG/M3 ACGIH TLV:S, 0.05 MG/M3; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ZINC (SARA III) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 12% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG ZNO/M3 ACGIH TLV:10 MG ZNO/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Fraction by Wt: 6% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG MN/M3 CEILING ACGIH TLV:5 MG MN/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR MERCURY IS 0.05 MG/M3. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE AND CHRONIC- RISK OF EXPOSURE OCCURS ONLY IF CELL IS MECHANICALLY, PHYSICALLY OR ELECTRICALLY ABUSED. KOH IS CAUSTIC AND MAY CAUSE SKIN BURNS, SEVERE EYE INJURY. AT ELEVATED TEMPERATURES, MERCUR Y VAPORS MAY BE GENERATED WHICH CAN CAUSE MERCURY INTOXICATION, CNS DISTURBANCES AND DISORDERS OF THE GUMS AND MOUTH. Effects of Overexposure:RISK OF EXPOSURE OCCURS ONLY IF CELL IS MECHANICALLY, PHYSICALLY OR ELECTRICALLY ABUSED. KOH IS CAUSTIC AND MAY CAUSE SKIN BURNS, SEVERE EYE INJURY. AT ELEVATED TEMPERATURES, MERCURY VAPORS MAY BE GEN ERATED WHICH CAN CAUSE MERCURY INTOXICATION, CNS DISTURBANCES AND DISORDERS OF THE GUMS AND MOUTH. Medical Cond Aggravated by Exposure:AN ACUTE EXPOSURE WILL NOT GENERALLY AGGRAVATE ANY MEDICAL CONDITION. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IMMEDIATELY. EYE/SKIN:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED. ORAL:GET EMERGENCY MEDI CAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:CELL MAY RELEASE TOXIC MERCURY VAPOR WHEN THE INTEGRITY OF THE CELL IS BROKEN OR INVOLVED IN FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:BATTERY AND CELL CASES WILL NORMALLY CONTAIN MATERIALS OF CONCERN. USE INDUSTRIAL ABSORBENT TO COLLECT LIQUID POTASSIUM HYDROXIDE. AVOID SKIN AND EYE CONTACT. DO NOT INHALE OF CELLS. Neutralizing Agent:ACID FOR POTASSIUM HYDROXIDE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. AVOID BREAKING, CRUSHING OR OTHERWISE DESTROYING THE PHYSICAL INTEGRITY OF THE CELL OR BATTERY. Other Precautions:DO NOT TOUCH BROKEN OR LEAKING BATTERIES. AVOID MECHANICAL OR ELECTRICAL ABUSE. DO NOT ATTEMPT TO RECHARGE. AVOID SHORT CIRCUITS. DO NOT CARRY BATTERIES LOOSE IN POCKET OR BAG. KEEP BATTERIES AWAY FRO M SMALL CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS WHEN CELLS ARE INVOLVED IN A FIRE. Ventilation:USE ADEQUATE LOCAL EXHAUST VENTILATION WHEN CELLS ARE INVOLVED IN A FIRE. Other Protective Equipment:EYE WASH STATION Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health THE ITEM OF SUPPLY IS A BATTERY (AN ARTICLE). UNDER NORMAL CONDITIONS OF USE AND STORAGE, NO EXPOSURE TO HAZARD CHEMICALS POSSIBLE. THE PHYSICAL PROPERTIES GIVEN BY MSDS COVERS THE COMPONENTS OF THE B ATTERY. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:357C (HG) Melt/Freeze Pt:M.P/F.P Text:360C KOH Decomp Temp:Decomp Text:500C HGO Vapor Pres:1 @126C HG Spec Gravity:11.1 (HGO) Evaporation Rate & Reference:NOT RELEVANT Solubility in Water: 50 % KOH Appearance and Odor:CLEAR LIQUID (KOH), RED CRYSTALS (HGO), BLACK POWDER (MNO2), GREY POWDER (HG+ZN ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:OVER-HEATING, CHARGING, SHORT CIRCUITS, DISASSEMBLING, CRUSHING OR PUNCTURING Hazardous Decomposition Products:TOXIC MERCURY VAPORS CAN BE PRODUCED AT ELEVATED TEMPERATURES. LIQUID POTASSIUM HYDROXIDE CAN LEAK. ==================== Disposal Considerations ==================== Waste Disposal Methods:CELLS AND BATTERIES MAY BE RETURNED AT SENDERS EXPENSE TO A PERMITTED TREATMENT, STORAGE, DISPOSAL FACILITY (TSDF). DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAW S AND REGULATIONS. DO NOT INCINERATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SILICONE GREASE COMPOUND Preparer's Name:DGSC-SSH CAGE:86511 CAGE:86511 ============= Composition/Information on Ingredients ============= Ingred Name:GREASE, SILICONE MIXTURE Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: MILD IRRITATION. INGESTION: IRRITATION. DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER AND GET MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF CONTACT WITH SK IN, WASH WITH SOAP AND WATER. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:IRRITATION OF EYES AND SKIN, GASTROINTESTINAL IRRITATION Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE PERSON TO FRESH AIR. RESTORE BREATHING. TREAT SYMPTOMATICALLY. GET MEDICAL HELP. EYES: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL TREATMENT. SK IN: WASH AFFECTED SKIN AREAS WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. CONSULT A PHYSICIAN IF IRRITATION PERSISTS. INGESTION: DO NOT INDUCE VOMITING: GIVE WATER AND GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>500F,>260C Lower Limits:NOT KNOWN Upper Limits:NOT KNOWN Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL AS APPROPRIATE FOR SURROUNDINGS. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE, SCRAPE OR SOAK UP IN AN INERT MATERIAL AND PUT IN A CONTAINER FOR DISPOSAL. WASH WALKING SURFACES WITH DETERGENT AND WATER TO REDUCE SLIPPAGE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:AVOID CONTACT WITH EYES. CONTROL DUST LEVELS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS FOR ORGANIC VAPORS. USE NIOSH/MSHA APPROVED AIRLINE TYPE RESPIRATORS OR HOODS IN CONFINED AREAS. Ventilation:SUFFICIENT VENTILATION TO CONTROL DUST LEVELS. Other Protective Equipment:USE DISPOSABLE OR IMPERVIOUS CLOTHING IF WORK CLOTHING CONTAMINATION IS LIKELY. USE PROTECTIVE SKIN CREAM IF REQUIRED. Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING OR USING THE WASH ROOM. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health PHIPPS PRODUCTS NO LONGER IN BUSINESS. MSDS PREPARED BY DGSC-SSH USING PROPERTIES OF OTHER PRODUCTS BOUGHT UNDER THIS STOCK NUMBER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NOT KNOWN Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN Vapor Pres:NEGLIGIBLE Vapor Density:NOT KNOWN Spec Gravity:1.01 Evaporation Rate & Reference:<1 Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE ODORLESS PASTE Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON DIOXIDE & CARBON MONOXIDE, AND SILICON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE DONE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:P-I BLACK INK; P95 284D CAGE:GO915 CAGE:90316 CAGE:GO915 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:MINERAL SEAL OIL RTECS #:PY8230000 ACGIH TLV:200 PPM (MFR) ===================== Hazards Identification ===================== Effects of Overexposure:SKIN:POSS DERMATITIS.MATERIAL IS HARMFUL OR FATAL IF SWALLOWED VAP MAY BE IRRIT TO MUCOUS MEM. ======================= First Aid Measures ======================= First Aid:INH:PROVIDE FRESH AIR & REST.SKIN:WASH THOROUGHLY W/SOAP & WATER.EYE:FLUSH W/ LG AMT OF WATER AT LEAST 15 MIN. CALL MD ===================== Fire Fighting Measures ===================== Flash Point:>200F COC Extinguishing Media:FOAM,CO*2,DRY CHEMICAL Fire Fighting Procedures:USE SELF-CONT BRTHNG APPAR.USING WATER STREAM SPREADS FIRE Unusual Fire/Explosion Hazard:A VAPOR ACCUMULATION W/FLASH &/OR EXPLODE IF IGNITED ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION.PROVIDE ADEQUATE VENTILATION. AVOID BRTHNG VAPORS.ABSORB ON ABSORBENT MATERIAL. USE NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY PLACE AWAY FROM SOURCES OF IGNITION IN ORGINAL, TIGHTLY CLOSED CONTAINER ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD AIR SUPPLIED MASK IN AREAS OF HIGH CONC. Ventilation:EXPLOSION PROOF AS NEC TO KEEP VAPOR CONC BELOW TLV. Other Protective Equipment:AS REQUIRED TO AVOID WETTING CLOTHING & SKIN. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:210F INITL Spec Gravity:0.999 Appearance and Odor:HIGH VISCOSITY BLACK LIQ W/MILD ODOR Percent Volatiles by Volume:75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT,OPEN FLAMES & SPARKS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IAW FED,STATE & LOCAL CODES
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METHYL ALCOHOL 14280, A41200LC CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA). LD50: (ORAL, RAT) 5628 MG/KG. CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: >99% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM; 250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPDAT: BERYLLIUM DIHYDRIDE, CARBON TETRACHLORIDE + METALS, CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: CYANURIC CHLORIDE, DIETHYL ZINC, NITRIC ACID & POTASSIUM TERTBUTOXIDE. PLEASE REFER TO THE NFPA FIRE (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: PROTECTION GUIDE FOR ALL SPECIFICS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: TO THOSE DESCRIBED FOR INGEST. CHRONIC: PRLNGD/RPTD SKIN CONTACT MAY CAUSE DERM. CHRONIC INHAL (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: & INGEST MAY CAUSE EFTS SIMILAR TO THOSE OF ACUTE INHAL & INGEST. TARGET ORGANS: KIDNEYS, CNS, LIVER, EYES. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: VOMIT BY GIVING ONE TEASPOON OF SYRUP OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTE TO MD: EFTS MAY BE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: DELAYED. ETHANOL MAY INHIBIT METABOLISM. ANTIDOTE: NO SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE EMTPY CNTNRS TO HEAT, SPARKS OR OPEN FLAMES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: CAUSES MODERATE IRRIT. VAPS MAY CAUSE IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN: MAY CAUSE SKIN IRRIT. MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. INGEST: MAY CAUSE IRRIT OF DIGEST TRACT. MAY CAUSE CNS DEPRESS CHARACTERIZED BY EXCITEMENT, FOLLOWED BY HDCH, DIZZ, DROW & NAUS. ADVANCED STAGES (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: MAY CAUSE COLLAPSE, UNCON, COMA & POSS DEATH DUE TO RESP FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL: MAY CAUSE RESP TRACT IRRIT. MAY CAUSE LIVER & KIDNEY DMG. MAY CAUSE ADVERSE CNS EFTS INCLUD ING HDCH, CONVULSIONS & POSS DEATH. MAYCAUSE VISUAL IMPAIRMENT & POSS PERM BLINDNESS. MAY CAUSE EFTS SIMILAR (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH EYES W/PLENTY OF WATER FOR AT LST 15 MIN, OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB OR KEEP EYES CLOSED. SKIN: FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LST 15 MIN WHILE REMOVING CONTAMCLTHG & SHOES. GET MED AID IF IRRIT DEVELOPS OR PERSISTS. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MED AID IMMED. INDUCE (ING 7) ===================== Fire Fighting Measures ===================== Flash Point:53.6F,12.0C Lower Limits:6.0% Upper Limits:31.0% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESIST FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:CNTNRS CAN BUILD UP PRESS IF EXPOSED TO HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DURING FIRE, IRRITATING & HIGHLY TOX GASES MAY (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP WITH NONSPARKING TOOL, THEN PLACE INTO SUITABLE CONTAINER FOR DISPOSAL. USE WATER SPRAY TO DISPERSE GAS/VAPOR. REMOVE ALL SOURCES OF IGNITION. ABSORB SPILL USING ABSORBENT, NON-COMBUSTIBLE MA TERIAL SUCH AS EARTH, SAND OR VERMICULITE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNITION. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:WASH THOROUGHLY AFTER HNDLG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. USE W/ADEQ VENT. EMPTY CNTNRS RETAIN PROD RESIDUE (LIQ &/OR VAP) & CAN BE DANGEROUS. DO NOT GET ON SKIN OR IN EYES. DO NOT INGEST OR INHALE. DO NOT PRESSURIZE, (ING 10) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ: BE GENERATED BY THERMAL DECOMP OR COMBUSTS. FLAM LIQ. CAN RELS VAPS THAT FORM EXPLO MIXS AT TEMPS ABOVE FLASH POINT. MATL TO AVOID: SODIUM HYPOCHLORITE). ACTIVE METALS (SUCH AS POTASSIUM & MAGNESIUM). SUBSTANCE IS ALSO INCOMPAT W/SPECIFIC CHEMS INCLUDING: ACETYL BROMIDE, ALKYL ALUMINUM SALTS, (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:148F,65C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:96 Vapor Density:1.1 Spec Gravity:0.7910 Evaporation Rate & Reference:5.2 (ETHER =1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; SLIGHT ALCOHOL-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUPDAT) Stability Condition to Avoid:STABLE AT ROOM TEMP IN CLSD CNTNRS UNDER NORM STORAGE & HNDLG CNDTNS. AVOID HIGH TEMPS, INCOMPAT MATLS, IGNIT SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SOMACA HI SHEEN GLASS CLEANER Preparer's Name:LAURA E RADEVSKI CAGE:55899 CAGE:55899 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 5-10% Other REC Limits:N/K OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:DIACETONE ALCOHOL (4-HYDROXY-4-METHYL-2-PENTANONE) CAS:123-42-2 RTECS #:SA9100000 Other REC Limits:N/K OSHA PEL:50 PPM ACGIH TLV:50 PPM; 9192 Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Other REC Limits:N/K OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9192 Ingred Name:ISOBUTANE (OF PROPANE/ISOBUTANE PROPELLANT BLEND) CAS:75-28-5 RTECS #:TZ4300000 Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NIOSH STUDIES INDICATE 2-BUTOXYETHANOL HAS CAUSED REPRODUCTIVE DISORDERS IN LABORATORY ANIMALS (RATS OR MICE) & MAY HAVE THE POTENTIAL FOR CAUSING SIMILAR DISORDERS IN HUMANS . Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:MAY IRRITATE ON PROLONGED & REPEATED CONTACT.SKIN/INGESTION:N/K .INHALATION:PROLONGED EXPOSURE TO CONCENTRATED VAPOR MAY CAUSE HEADACHES,DIZZINESS,NAUSEA. Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.IF IRRITATION PERSISTS,CONTACT A PHYSICIAN.SKIN:N/K .INGESTION:CALL MD IMMEDIATELY .INHALATION:MOVE VICTIM TO FRESH AIR.RESTORE RESPIRATION IF NECESSARY. ===================== Fire Fighting Measures ===================== Flash Point:SEE SUPP DATA Extinguishing Media:DRY CHEMICAL,FOAM,CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .WATER SPRAY MAY BE USED TO COOL CANS IN VICINITY OF FIRE OR EXCESSIVE HEAT. Unusual Fire/Explosion Hazard:TEMPERATURE ABOVE 130F,54C MAY CAUSE CANS TO BURST.HAZARDOUS DECOMPOSITION PRODUCTS:THERMAL DECOMP MAY PRODUCE CARBON DIOXIDE & CARBON MONOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP SPILLS WITH INERT AND ABSORBENT MATERIAL. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT OR OPEN FLAME OR WHERE TEMPERATURE EXCEEDS 130F,54C. Other Precautions:KEEP OUT OF REACH OF CHILDREN & PETS.DO NOT DELIBERATELY INHALE VAPOR OR SPRAY MIST.AVOID CONTACT WITH EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Other Protective Equipment:NONE REQUIRED Supplemental Safety and Health FL PT:FLAME PROJECTION:NONE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Decomp Temp:Decomp Text:N/K Spec Gravity:ABOUT 1,H*2O=1 Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE Solubility in Water:MISCIBLE Appearance and Odor:WHITE FOAM/SLIGHT AMMONIA ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS,ALUMINUM,COPPER. Stability Condition to Avoid:TEMPERATURE ABOVE 130F,54C;OPEN FLAME. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON DIOXIDE & CARBON MONOXIDE. Conditions to Avoid Polymerization:TEMPERATURES ABOVE 130F,54C. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .DISPOSE CANS IN NON-INCINERATED TRASH ONLY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRAMITOL 25E HERBICIDE A-371A CAGE:KO472 CAGE:KO472 ============= Composition/Information on Ingredients ============= Ingred Name:SURFACTANTS Ingred Name:PETROLEUM SOLVENT (INCLUDES NEXT FOUR INGREDS) Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 OSHA PEL:100 PPM OSHA STEL:150 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:O-XYLENE CAS:95-47-6 RTECS #:ZE2450000 OSHA PEL:435 MG/M3;100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYLBENZENE CAS:100-41-4 RTECS #:DA0700000 OSHA PEL:435 MG/M3;100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:543 MG/M3;125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,2,4-TRIMETHYLBENZENE CAS:95-63-6 RTECS #:DC3325000 Ingred Name:N-BUTANOL CAS:71-36-3 RTECS #:EO1400000 OSHA PEL:300 MG/M3;100 PPM ACGIH STEL:C152 MG/M3;C50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYLENE GLYCOL MONOPHENYL ETHER CAS:122-99-6 RTECS #:KM0350000 Ingred Name:PROMETON (25%) CAS:1610-18-0 RTECS #:XY4200000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 2100MG/KG BODY WT Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ETYHYLENE GLYCOL NOMO PHENYL ETHER:EXPO WILL RESULT IN SEVERE EYE IRRIT & MOD CORNEAL INJURY.LIV/ KIDNEY/THYROID/BLOOD EFFECTS HAVE BEEN OBSERVED IN ANIMAL STUDIES.N-BUTANOL:PROL EXPO MAY RESULT IN DR YING/CRACK OF SKIN FRM DEFATT ACTION.THERE'S EVIDENCE THAT LONG-TERM REP EXPO TO VAP CONC >50PPM MAY RESULT IN SOME LOSS OF HEARING.VAP CAN CAUSE SPEC INJURY TO CORNEA.SKIN/RESP TRACT IRRIT MAY OCCUR W/BRIEF EXPOS.CAUSES SEVERE EYE IRRIT W/LACRIMATION.INHAL MAY RESULT IN LOSS OFCONSC,HEAD,NAU,DIZZ,DROWS,VOMIT.PETRO SOLVT:SM AMTS OF SEVERAL SURFACTANTS HAVE BEEN REPORTED BY MFG TO CAUSE SKIN IRRIT UPON PROL/RESP CONTACT. Explanation of Carcinogenicity:PER MSDS XYLENE AND O-XYLENE ARE IARC 3 CARCINOGENS.PROPOSITION 65:NOT APPLICABLE. Effects of Overexposure:EXPO MAY CAUSE IRREVERSIBLE EYE DMG & SEVERE SKIN IRRIT.IF SWALLOWED,ABD PAIN,NAU,VOMIT,GASTRITIS,WEAK,HEAD,OR DIARR CAN OCCUR.PROL INHAL EXPO MAY CAUSE RESP TRACT IRRIT & CNS DEPRESSION,RESULTING IN HEAD,DIZZ,BLURRED VISION OR NAU.PETRO SOLVT IN PRODUCT CAN CAUSE CHEM PNEUMONITIS IF ASPIRATED. Medical Cond Aggravated by Exposure:INDIVIDUALS W/CHRONIC RESP DISORDERS OR PRE-EXISTING DERM SHOULD USE EXTRA CARE IN HNDLG PRODUCT. TARGET ORGANS:LIVER,KIDNEY,THYROID,BLOOD,EYES, RESP TRACT, INNER EAR, SKIN, CENTRAL NERV SYST. ======================= First Aid Measures ======================= First Aid:POIS SUSPECTED IMMED CONTACT DR/NEAREST HOSP OR POIS CNTRL CNTR.TELL PERSON CONTACTED COMPLETE PRODUCT NAME & TYPE/AMT OF EXPO.DESCRIBE ANY SYMPTS/FOLLOW ADVICE GIVEN.INGEST:DONT INDUCE VOMIT.VICTIM F ULLY CONSC IMMED GIVE LG QUANT OF H2O TODRINK, GET MED ATTN.NEVER GIVE ANYTNING BY MOUTH IF UNCONSC.EYE:IMMED RINSE W/LG AMT OF H2O.HOLD EYELIDS APART TO RINSE ENTIRE SURF.DONT APPLY MEDICATING AGENTS EXCEPT ON ADVICE OF DR.SKIN:WASH W/PLENTY OF SOAP/H2O INCLUDE HAIR/UNDER FINGERNAILS.DONT APPLYMEDICATING AGETNS EXCEPT ON ADVICE OF DR.REMOVE CONTAM CLOTH/DECONTAM PRIOR TO USE.INHAL:MOVE TO FRESH AIR.APPLY ART RESP(SEE OTHER INFO) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=36.7C, 98.F Autoignition Temp:=340.C, 644.F Lower Limits:1.3% Upper Limits:4.9%+/-.25 Extinguishing Media:USE DRY CHEMICAL FOAM OR CO2 EXTINGUISHING MEDIA. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS. EVACUATE PERSONNEL. PREVENT USE OF CONTAMINATED BUILDINGS, AREA, AND EQUIPMENT UNTIL DECONTAMINATED. Unusual Fire/Explosion Hazard:THIS PRODUCT IS FLAMMABLE AND FORMS FLAMMABLE MIXTURES ABOVE 77F. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE, CARBON MONOXIDE OR CO2. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR CHEM GOGG/FULLFACE SHIELD,RUBB FULLFC CHEM CARTRIDGE RESP W/ORG VAP CARTRIDGES&PESTICIDE PRE-CARTRIDGES/SCBA.SM SPILL-COVER W/ABS ORBENT MATL LIKE PET LITTER.SWEEPUP,PLACE IN APPROV CHEM CNTNR.WASH SPILL AREA W/H2O PLUS STRONG DETRGT,ABSORB W/PET LITTER/OTHER ABSORB MATL,SWEEPUP,PLACE IN CHEM CNTNR.SEAL,HNDLG IN(SEE NEUTR AGENT) Neutralizing Agent:N/P. SPILL:APPROV MANNER.FLUSH AREA W/H2O TO REMOVE RESIDUE.DONT ALLOW WASH H2O TO COTNAM H2O SUPPLIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE MATL IN WELL-VENTI,SECURE AREA OUT OF REACH OF CHILDREN & DOMESTIC ANIMALS.DONT STORE FOOD,BEVERAGES OR TOBACCO PRODUCTS IN STORAGE AREA.PREVENT EATING,DRINKING,TOBACCO USAGE,COSMETIC APPLIATION IN AREAS WHERE THERES POTENTIAL FOR EXPOSURE TO MATL.ALWAYS WASH THOROUGHLY AFT HNDLG. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:TO AVOID BREATHING MIST OR SPRAY,WEAR NIOSH-APPROVED FULL-FACE CHEMICAL CARTRIDGE RESPIRATOR W/ORGANIC VAPOR CARTRIDGES & PESTICIDE PRE-CARTRIDGES OR SUPPLIED-AIR RESPIRATOR. SHIELD. Other Protective Equipment:TO AVOID SKIN CONTACT WEAR RUBBER BOOTS,LONG-SLEEVED SHIRT,LONG PANTS & HEAD COVERING.AOVE CNTRL MEASURES RECOMMENDATIONS FOR MFG,COMMERCIAL BLENDING,PKG WORKERS. Work Hygienic Practices:PREVENT EAT/DRINK/TOBACCO USAGE/COSMETIC APPLICATION IN AREAS WHERE THERES POT FOR EXPO TO MATL.ALWAYS WASH THOROUGHLY AFT HNDLG.APPLICATORS/HNDLRS:PLS REF TO PROD LABEL FOR PPE & CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:120-130C Vapor Pres:PROMETON 3.10E-06MBAR@20C Spec Gravity:7.80LBS/GAL pH:7-8 Solubility in Water:0.7GL@22C FOR PROMETON Appearance and Odor:YELLOW TO AMBER LIQUID WITH AROMATIC SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:STRONG ACIDS. Hazardous Decomposition Products:NONE KNOWN. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE, BUT ARE NOT LIMITED TO, CARBON MONOXIDE OR CARBON DIOXIDE. =================== Toxicological Information=================== Toxicological Information:INGEST:SLIGHTLY TOXIC ORAL LD50(RAT):2100MG;KG BODY WT. DERM:SLIGHTLY TOXIC DERM LD50 (RABBIT):2000-2500 MG/KG BODY WT.INHAL:SLIGHTLY TOXIC INHAL LC50(RAT):>2.5MG/L AIR-4HRS. EYE CONTACT:CORRO(RABBIT) .SKIN CONTACT:SEVERELY IRRIT(RABBIT).SKIN SENS:NA.NUTAGENIC POT: PROMETON-NONE OBSERV.REPROD HAZ POT:PROMETHONE-NONE OBSERV.CHRONIC/SUBCHRONIC TOX STUDIES:PROMETON-LIVER EFFECTS(MICE).CARC POT:PROMETO N-NONE OBSERV.OTHER TOX INFO:NA. ===================== Ecological Information ===================== Ecological:PROMETON:PRACTICALLY NONTOXIC TO BIRDS & SLIGHTLY TOXIC TO AQUATIC INVERTEBRATES & FISH.ECO-ACUTE TOXI FOR PROMETON-RAINBOW TROUT 96HR LC50=19.6MG/L;BLUEGILL SUNFISH 96HR LC50=41.5MG/L;DAPHNIA MAGNA 4 8HR LC50=37.5MG/L;BOBWHITE ORAL LD50>2264MG/KG;MALLARD ORAL LD50=3158MG/KG;BOBWHITE 8DAY DIETARY LC50>5620PPM;MALLARD 8DAY DIETARY LC50 >5620PPM.ECO-CHRONIC TOXI-PROMETON:FISH(FATHEAD MINNOW)EARLY LIF E STAGE MATC 13.7MG/L; INVERTEBRATE(DAPHNIA MEGNA)LIFE CYCLE MATC 4.83MG/L;MALLARD REPRO NOEC 175PPM.ENVIRO FATE-PROMETON:NA. ==================== Disposal Considerations ==================== Waste Disposal Methods:DONT REUSE PRODUCT CONTAINERS.DISPOSE OF PRODUCT CONTAINERS,WASTE CONTAINERS, & RESIDUES ACCORDING TO LOCAL,STATE,AND FEDERAL HEALTH AND ENVIRO REGULATIONS.CHARACTERISTIC WASTE:IGNITABLE;LISTED WASATE :D001. =================== MSDS Transport Information =================== Transport Information:PER MSDS:DOT CLASSIFICATION:COMPOUNDS,TREE OR WEED KILLING,LIQUID(XYLENE),CLASS 3,NA1993,PG III.B/L FREIGHT CLASSIFICATION:COMPOUND;WEED KILLING (HERBICIDE),N.O.S.;INTERNATIONAL TRANSPO:NA. ===================== Regulatory Information ===================== SARA Title III Information:SEC 311/312:ACUTE HEALTH HAZ,CHRONIC HEALTH HAZ,FIRE HAZ.SEC 313 CHEM(S):1,2,4-TRIMETHYLBENZENE(CAS#95-63-6),ETHYL BENEZE(CAS#:100-41-4),O-XYLENE(CAS#:95-47-6), XYLENE(CAS# 1330-20-7),N-BUTANOL (CAS#71-36-3),ETHYLENE GLYCOL MONO PHENYL ETHER (CAS#122-99-6). Federal Regulatory Information:CERCLA RQ:6400 GALLONS(BUTANOL CONTENT)/1280 GALLONS (XYLENE CONTENT). RCRA CLASSIFICATION:IGNITABLE; TSCA STATUS:EXEMPT FROM TSCA. State Regulatory Information:PROPOSITION 65:NOT APPLICABLE. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZYTEL, EFE1068 NC010 Kit Part:Y Preparer's Name:D.L. LICZWEK CAGE:B0589 CAGE:82348 CAGE:B0589 ============= Composition/Information on Ingredients ============= Ingred Name:NYLON (NYLON 66) CAS:32131-17-2 Fraction by Wt: >98% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:LUBRICANT Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:STABILIZER Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:MAY NOT PROVIDE ADEQ PROTECTION. RTECS #:9999999ZZ Ingred Name:EYE PROT:SHIELD WHEN POSSIBILITY EXISTS FOR EYE & FACE CONT DUE TO SPLASHING/SPRAYING OF MOLTEN MATL. NIOSH/MSHA (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:FULL FACE MASK RESP PROVIDES PROTECTION FROM EYE IRRITATION. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT)>10,000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:SINGLE LG ORAL EXPOS (10,000 MG/KG) PRODUCED ONLY SLIGHT INITIAL WEIGHT LOSS. TWO-YEAR TESTS IN RATS & ONE YEAR TESTS IN DOGS @ LEV OF 10% IN DIET PRODUCED NO ADVERSE EFTS. RPTD INHAL EXPOS PROD UCED NO GROSS CHANGES & ONLY MICROSCOPIC LUNG & KIDNEY CHANGES. THE CMPD IS NOT SKIN IRRITANT. TESTS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:IN ANIMALS DEMONSTRATE NO CARCIN ACTIVITY. NO ADVERSE HLTH EFTS ARE EXPECTED FROM HUMAN EXPOS TO POLYHEXAMETHYLENE ADIPAMIDE, EXCEPT FOR MECH IRRIT OF SKIN & EYES CAUSE BY PARTICLES. SIGNIFIC ANT SKIN PERMEATION, AND SYSTEMIC TOX, AFTER CONTACT APPEARS UNLIKELY. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:CONSULT PHYS IF NEC. IF EXPOS TO FUMES FROM OVERHEATING/COMBUST, MOVE TO FRESH AIR. CONSULT PHYS IF SYMP PERSIST. SKIN:CLEANSING SKIN AFTER USE IS ADVISABLE. IF MOLTEN POLYMER GETS ON SKIN, COOLRAPIDLY W/COLD WATER. DO NOT ATTEMPT TO PEEL POLYMER FROM SKIN. OBTAIN MED TREATMENT FOR THERMAL BURN. EYE:IMMED FLUSH W/PLENTY OF WATER FOR @ LEAST 15 MINS. CALL PHYS. INGEST:CONSULT PHYS IF NEC. ===================== Fire Fighting Measures ===================== Flash Point:752F,400C Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CO*2. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . KEEP PERSONNEL REMOVED AND UPWIND OF FIRE. Unusual Fire/Explosion Hazard:LG MOLTEN MASSES MAY IGNITE SPONT IN AIR. WATER QUENCHING OF SUCH MASSES IS GOOD PRACTICE. HAZ GASES/VAP PRODUCED IN FIRE ARE:AMMONIA, CO; SM AMTS OF (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:NOTE:REVIEW FIRE FIGHT MEASURES & HNDLG (PERS) SECTIONS BEFORE PROCEEDING W/CLEAN-UP. USE APPROP PERSONAL PROT EQUIP DURING CLEAN-UP. SWEEP UP TO PVNT A SLIPPING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:COOL, DRY PLACE. KEEP CNTNRS TIGHTLY CLSD TO PVNT MOISTURE ABSORPTION & CONTAMINATION. Other Precautions:MEDICAL USE: CAUTION:DO NOT USE IN MED APPLIC INVOLVING PERM IMPLANTATION IN HUMAN BODY. FOR OTHER MED APPLIC SEE DU PONT CAUTION BULLETIN NO. H-50102. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD AIR PURIFYING RESP W/ORG VAP CARTRIDGE & NIOSH/MSHA DUST/MIST FILTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONC ARE EXPECTED TO EXCEED EXPOS LIM. PROT PROVIDE D BY NIOSH/MSHA AIR PURIFYING (SUPDAT) Ventilation:LOCAL VENTL TO CONTROL FUMES FROM HOT PROCESSING. Other Protective Equipment:IF THERE IS POTENTIAL CONT W/HOT MOLTEN MATL, WEAR HEAT RESIST CLOTHING AND FOOTWEAR. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health % VOLAT:1% (WATER). EXPLO HAZ:HYDROGEN CYANIDE & ALDEHYDES. WASTE DISP METH:PROVINCIAL, & LOCAL REGS. RESP PROT:RESP IS LIM. USE NIOSH/MSHA POSITIVE PRESS AIR SUPPLIED RESP IF THERE IS ANY POTNTL FOR UNCONTROLLED RELEASE, EXPOS LEV ARE NOTKNOWN, OR ANY OTHER CIRCUMSTANCE WHERE NIOSH/MSHA AIR PURIFYING RESP (ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>482F,>250C Spec Gravity:1.22-1.38 Evaporation Rate & Reference:NOT KNOWN Solubility in Water:INSOLUBLE Appearance and Odor:GRANULES, NO ODOR Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND OXIDIZING AGENTS. Stability Condition to Avoid:HEATING ABOVE 340 DEGREES C. Hazardous Decomposition Products:CYCLOPENTANONE, CARBON MONOXIDE, ALDEHYDES, AND AMMONIA. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREF OPTIONS FOR DISP ARE (1)RECYCLING, (2)INCIN W/ENERGY RECOVERY, & (3) LANDFILL. HIGH FUEL VALUE OF PROD MAKES OPTION 2 VERY DESIRABLE FOR MAT THAT CANNOT BE RECYCLED. TREATMENT STOR, TRANSPORTATIO N & DISP MUST BE I/A/W APPLIC FED, STATE/ (SUPDAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:525238-00 MOBIL MULTI-PURPOSE ATF CAGE:3U728 CAGE:3U728 CAGE:19135 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 0.11% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PETROLEUM HYDROCARBONS Fraction by Wt: NP Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:ADDITIVES Fraction by Wt: NP Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL (RATS) LD50 >2000MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ORAL/DERMAL:PRACTICALLY NON-TOXIC BASED ON TESTING OF SIMILAR PRODUCTS &/OR COMPONENTS.INHAL:NA.HARMFUL CONCEN OF MISTS &/OR VAP UNLIKELY TO ENCOUNTERED THRU ANY CUSTOMARY/REASONABLY FORESEEABLE HNDLG /USE/MISUSE OF PRODUCT.EYESKIN:PRACTICALLY NON-IRRIT BASED ON TESTING OF SIMILAR PRODUCTS &/OR COMPONENTS. Explanation of Carcinogenicity:PER MSDS:CHRONIC MOUSE SKIN PAINTING STUDIES OF SEVERELY TREATED OILS SHOWED NO EVIDENCE OF CARC EFFECTS. Effects of Overexposure:NO SIGNIFICANT EFFECTS EXPECTED. PRODUCT ASSESSED IAW OSHA 29CFR1910.1200 & DETERMINED NOT TO BE HAZARDOUS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH THOROUGHLY W/WATER.IRRIT OCCURS CALL DR.SKIN:WASH AREAS W/SOAP/WATER.INHAL:NOT EXPECTED TO BE A PROBLEM.INGEST:NOT EXPECTED TO BE A PROBLEM.HOWEVER IF GREATER THAN 1/2L(PT)INGESTED IMMED GIV E 1-2GLASSES OF WATER & CALL DR/HOSP EMERG RM/POIS CONTROL CENTER FOR ASSISTANCE.DONT INDUCE VOMIT OR GIVE ANYTHING BY MOUTH TO UNCONSC PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>338F,>170C Autoignition Temp:Autoignition Temp Text:NE Lower Limits:NA Upper Limits:NA Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WATER/FOAM MAY CAUSE FROTHING.USE WATER TO KEEP FIRE EXPO CNTNR COOL.WATERSPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPO.PREVENT RUNOFF FRM FIRE CNTRL/(SUPPL) Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:REPORT SPILLS AS REQUIRED TO APPROP AUTHORITIES.US COAST GUARD REGS REQUIRE IMMED REPORT OF SPILLS THAT COULD REACH WATERWAY INCLUDE INTERM DRY CREEKS.REPORT TO COAST GUARD 800-424-8802.ACCIDENT/ROAD SPILL 800-424-9300(CHEMTREC).ADSORB ON FIRE(SUPPL) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPEC PRECAUTIONS NECESSARY BEYOND NORMAL GOOD HYGIENE PRACTICES.SEE PPE SECTION OF MSDS.DONT STORE IN OPN/UNLABEL CNTNR. Other Precautions:STORE AWAY FRM STRONG OXIDIZING AGENTS/COMBUST MATL. DISPO:COMPLIANCE W/APPLIC LAWS/REGS/CONSIDERATION OF PROD CHARACTER @DISPO TIME.UNUSE PROD NOT LISTED BY EPA HAZ WASTE/NOT FORMULATED TO CONTAIN HA Z MATLS.USED PROD MAY BE REG.NO SARA CHE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQMTS UNDER ORDINARY CONDITIONS OF USE & W/ADEQUATE VENTILATION. Ventilation:NO SPECIAL REQMTS UNDER ORDINARY CONDITIONS OF USE & W/ADEQUATE VENTILATION. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:GOOD PERSONAL HYGIENE PRACGTICES SHOULD ALWAYS BE FOLLOWED. Supplemental Safety and Health FIREFIGHT:DILUTION FRM ENTER STREAMS/SEWERS/DRINKING WATER SUPPLY.FIRES IN ENCLSD ARAS FIRE FIGHTERS MUST USE SCBA. SPILL:RETARDANT TREAT SAWDUST,DIATOMACEOUS EARTH,ETC.SHOVEL UP/DISPO @APPROP WASTE D ISPO FACI IAW CURRENT APPLIC LAW/REG/PROD CHARACTERISTICS @DISPO TIME.PREVENT SPILL ENTER STORM SEWER/DRAIN/CONTACT SOIL ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:>316.1C, 601.F Melt/Freeze Pt:M.P/F.P Text:NA Decomp Temp:Decomp Text:NP Vapor Pres:<0.1 Vapor Density:>2.0 Spec Gravity:0.869 pH:NA VOC Grams/Liter:.36 Viscosity:36.0CST @40C Evaporation Rate & Reference:NE Solubility in Water:NEGLIGIBLE Appearance and Odor:LIQUID, RED COLOR, MILD ODOR Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:EXTREME HEAT. Hazardous Decomposition Products:METAL OXIDES, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:SUITABLE FOR BURNING IN ENCLSD CNTRL BURNER FOR FUEL VALUE/DISPO BY SUPERVISED INCINERATION.BURNING MAY BE LIMITED PURSUANT TO RCRA.SUITABLE FOR PROCESSING BY APPROV RECYCL FACI/DISPO @APPROP GOVT WAS TE DISPO FACIL.USE METHODS SUBJ TO USER(OTH PRECA) ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GLOSS ENAMEL INK, GE-139 CAGE:38065 CAGE:38065 ============= Composition/Information on Ingredients ============= Ingred Name:2(3H)-FURANONE, DIHYDRO-; (GAMMA-BUTYROLACTONE) LD50: (ORAL, RAT) 1580 MG/KG CAS:96-48-0 RTECS #:LU3500000 Fraction by Wt: 3-7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:2-CYCLOHEXEN-1-ONE, 3,5,5-TRIMETHYL-; (3,5,5-TRIMETHYL-2-CYCLOHEXEN-1-ONE) (SARA III) LD50: (ORAL, RAT) 2330 MG/KG CAS:78-59-1 RTECS #:GW7700000 Fraction by Wt: 15-40% OSHA PEL:4 PPM ACGIH TLV:5 PPM, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SOLVENT NAPHTHA; (PETROLEUM DISTILLATES) LD50: (ORAL, RAT) 3000 MG/KG CAS:64742-94-5 RTECS #:WF3100000 Fraction by Wt: 10-30% OSHA PEL:N/K ACGIH TLV:100 PPM (MFR) Ingred Name:PHTHALIC ACID, DIOCTYL ESTER; (DIOCTYL PHTHALATE) (SARA III) LD50: (ORAL, RAT) > 30000 MG/KG CAS:117-84-0 RTECS #:TI1925000 Fraction by Wt: 1-5% OSHA PEL:5 MG/M3; 10 PPM STEL ACGIH TLV:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, '2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE) LD50: (ORAL, RAT) 8532 MG/KG CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 5-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:2-PENTANONE, 4-HYDROXY-4-METHYL-; (4-HYDROXY-4-METHYL-2-PENTANONE) LD50: (ORAL, RAT) 4000 MG/KG CAS:123-42-2 RTECS #:SA9100000 Fraction by Wt: 5-30% OSHA PEL:50 PPM ACGIH TLV:50 PPM Ingred Name:VOLATILE ORGANIC COMPOUNDS: 4.1 - 6.3 LBS/GAL (487 - 750 G/L) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:OF ING 2 SHOWS SOME INCIDENCE OF CARCIN IN ANIMALS AT HIGH DOSES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN:POSS IRRIT & DEFAT DERM, ESP W/ RPTD/PRLNG CNTCT. EYES:SEV IRRIT. INHAL:SOLV VAP MAY CAUSE IRRIT TO UPPER RESP TRACT & LEAD TO CNS DEPRESS CHARACT BY HDCH, DIZZ, NAUS, VOMIT, DROW, ABDOM P AIN & INCOORDINATION. SEV OVEREXP MAY LEAD TO RESP FAILURE, COMA & POSS DEATH. OTHER CNS EFTS POSS. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:INGEST:WILL CAUSE IRRIT & BURNING OF MOUTH. IN RARE CASES, ING 3 MAY SENSITIZE HEART MUSC CAUSING CARD ARRHY. CHRONIC: SKIN:SOLV MAY BE ABSORBED THRU INTACT SKIN & EVENTUALLY CAUSE SYSTEMIC POIS &/OR CNS DEPRESS. EYES:IRRIT & POSS CONJ UPON RPTD CNTCT. INHAL:SOLV VAP MAY CAUSE IRRIT TO NOSE, THROAT & LUNGS & (SUPDAT) Medical Cond Aggravated by Exposure:SOME PRE-EXISTING MEDICAL DISORDERS (E.G. ASTHMA). ======================= First Aid Measures ======================= First Aid:EYES: WASH IMMED W/COPIOUS QTY OF INDUS EYE WASH/WATER FOR @ LEAST 15 MIN & GET MED AID. SKIN: IMMED WASH AFFECTED AREAS W/INDUS HAND CLEANER/SOAP & WATER. GET MED AID IF SYMP PERSIST. REMOVE CONTAMD CLTHG. INGEST: GIVE TWO GLASSES WATER TO DRINK IF CONSCIOUS. DO NOT INDUCE VOMIT. GET MED AID IMMED. INHAL: MOVE TO FRESH AIR. RESTORE BRTHG IF NEC. KEEP WARM & QUIET & GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:136F,58C Lower Limits:1% Upper Limits:5.28% Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, UNIVERSAL- TYPE FOAM APPLIED BY MANUFACTURER'S RECOMMENDED TECHNIQUES. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. ISOLATE HAZ AREA. USE WATER SPRAY TO COOL FIRE-EXPOS CNTNRS & ALSO DISPERSE VAP; REIGNIT IS POSSIBLE. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL TO SOURCE OF IGNITION & SUBSEQUENTLY "FLASH BACK" TO SOURCE OF PRODUCT DISCHARGE CAUSING FIRE OR EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. STOP & CONTAIN DISCHARGE (IF WITHOUT RISK) BY CONSTRUCTING BARRIERS/APPLYING INERT SORBENT (E.G. SAND, EARTH). PREVENT DISCHARGE FROM ENTERING SEWERS OR WATER COURSES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:GROUND & BOND ALL EQUIPMENT & CONTAINERS TO PREVENT A POSSIBLE STATIC CHARGE BUILDUP. USE SPARK-RESISTANT TOOLS. Other Precautions:STORE IN A COOL, WELL-VENTILATED ENVIRONMENT. KEEP AWAY FROM HEAT, SPARKS & OTHER SOURCES OF IGNITION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST & GENERAL VENTILATION AS REQUIRED, TO MAINTAIN EMISSIONS AT A POINT OF USE BELOW TLV-TWA OR PEL. Other Protective Equipment:FOOTWEAR & OTHER PROTECTIVE CLOTHING AS REQUIRED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EFTS OF OVEREXP:EVENTUALLY TO KIDNEY, LIVER & BLADDER AFFECTS. INGEST:WILL CAUSE IRRIT & BURNING OF MOUTH, ABDOM PAIN, CNS DEPRESS &/OR SYSTEMIC POIS. ING 4 IS CLASSIFIED AS POSS CARCIN TO HUMANS. MAY ALSO CAUSE TERATOGENIC/EMBRYOTOXIC EFTS BASED ON STUDIES ON LAB ANIMALS. INTERIM RPTS ON 2 YR TOX STUDY (ING 8) ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>293F,>145C Vapor Density:4.6 Spec Gravity:0.99-1.24 @ 20C Evaporation Rate & Reference:<1 (NBUAC=1) Appearance and Odor:LIQUID, VARIOUS COLORS; MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS AND BASES. Stability Condition to Avoid:EXCESSIVE HEAT, IGNITION SOURCES (E.G. SPARKS, STATIC ELECTRIFICATION, FLAME, ETC), STRONG BASES & OXIDIZERS. Hazardous Decomposition Products:COMBUSTION: CARBON DIOXIDE & CARBON MONOXIDE PLUS OTHER ORGANIC OR INORGANIC OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE OR PROPERLY CONTAINED, CONTAMINATED SOLIDS IN AN APPROVED WASTE TREATMENT FACILITY WHERE PERMITTED UNDER APPROPRIATE FEDERAL, STATE & LOCAL REGULATIONS. DO NOT DISPOSE OF WASTES IN LO CAL SEWERS OR WITH NORMAL REFUSE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RESIDUAL FUEL OIL (FUEL OIL #4,) CAGE:KO838 CAGE:KO838 CAGE:0NUX1 ============= Composition/Information on Ingredients ============= Ingred Name:FUEL OIL NO. 4 CAS:68476-31-3 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:HYDROGEN SULFIDE (SARA III) CAS:7783-06-4 RTECS #:MX1225000 Fraction by Wt: TRACE Other REC Limits:NONE RECOMMENDED OSHA PEL:(C),20 PPM ACGIH TLV:10 PPM/15 STEL; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL RAT IS >5 GM/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-INGESTION:LOW TOXICITY. MAY CAUSE GI TRACT IRRITATION. INHALATION:INHALATION OF MIST/VAPORS/FUMES MAY CAUSE RESPIRATORY TRACT IRRITATION. SMALL AMOUNT ASPIRATED INTO LUNGS MAY CAUSE CHEMICAL PNE UMONITIS. EYE:IRRITATION. SKIN:REPEATEDCONTACT MAY CAUSE IRRITATION. CHRONIC:DERMATITIS. Effects of Overexposure:EYES/SKIN: IRRITATION. INHALATION: HEADACHE, NAUSEA, WEAKNESS, SEDATION, AND UNCONSCIOUSNESS. INGESTION:NAUSEA, DIARRHEA. Medical Cond Aggravated by Exposure:SKIN DISEASE. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. SEE DOCTOR. SKIN:REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND WATER.SEE DOCTOR. INHALATION:REMOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NEEDED. SEE DOCTOR. INGESTION: DO NOT INDUCE VOMITING. SEE DOCTOR IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:140F,60C Extinguishing Media:USE CARBON DIOXIDE, FOAM, HALON, WATER SPRAY OR ANY APPROVED EXTINGUSHING AGENT FOR CLASS B FIRES. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. CONTAINER MAY EXPLODE IN HEAT OF FIRE. SMOKE MAY BE TOXIC. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE AREA. USE NON-SPARKING TOOLS. WEAR PROPER PROTECTIVE EQUIPMENT. STOP LEAK AND CONTAIN SPILL. ABSORB IN INERT ABSORBENT AND PLACE INTO APPROPIATE DISPOSAL CONTAINE R AND SEAL. WASH AREA WITH DETERGENT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED PLACE,AWAY FROM HEAT,IGNITION SOURCES AND INCOMPATIBLE MATERIALS.KEEP CONTAINERS CLOSED WHEN NOT IN USE. Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE. DO NOT PRESSURIZE, CUT, WELD OR EXPOSE TO HEAT, FLAME, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED WITH ADEQUATE VENTILATION. NIOSH RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE APPROPIATE FOR EXPOSURE OF CONCERN OR SCBA IF TLV IS EXCEEDED. Ventilation:SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST VENTILATION. Other Protective Equipment:FULL BODY LONG-SLEEVED GARMENTS TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN. DO NOT BREATHE VAPORS. WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:400F,204C Vapor Pres:NEGLIGIBLE Vapor Density:>1 Spec Gravity:0.95-1.0 Viscosity:1.0 CST @104F Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:NEGLIGIBLE Appearance and Odor:BALCK VISCOUS LIQUID, PETROLEUM OIL ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, COMBINATION OF SULFURIC AND NITRIC ACIDS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON OXIDES AND VARIOUS HYDROCARBONS WHEN BURNED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:US9526-01 (ASBESTOS FELT MATERIAL) Preparer's Name:RONALD L. RAMSEY CAGE:8X148 CAGE:5G441 CAGE:8X148 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 Fraction by Wt: 70-76% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9394 Ingred Name:PHENOLIC RESIN Fraction by Wt: 24-30% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR ASBESTOS IS 0.2 FIBERS/CC Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:HEALTH HAZARD-HAZARD WOULD ARISE ONLY IF PRODUCT IS SUBJECTED TO MECHANICAL ACTION THAT WOULD RELEASE FIBERS.ACUTE HAZARD:EYE AND SKIN IRRITATION. CHRONIC HAZARD:INHALATION OF AIRBORNE FIBERS CAN CAUS E ASBESTOSIS,LUNG CANCER AND MESOTHELIOMA.INGESTION CAN CAUSE CANCER OF GI TRACT AND LARYNX. Explanation of Carcinogenicity:ASBESTOS IS LISTED UNDER NTP,IARC AND OSHA. ETHYLENE THIOUREA IS LISTED UNDER NTP AND IARC. Effects of Overexposure:EYE/SKIN:IRRITATION. INHALATION:SYMPTOMS OF LABORED BREATHING,RESTRICTED PULMONARY FUNCTION APPEAR 15-20 YEARS AFTER EXPOSURE. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. HIGHER RISK WITH SMOKERS. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.IF IRRITATION PERSISTS,SEE DOCTOR. SKIN:WASH WITH SOAP AND WATER WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.IF IRRITATION PERSISTS,SEE DOCTO R. INHALATION:REMOVE VICTIM TO FRESH AIR.SEE DOCTOR. INGESTION:NO SPECIFIC ACTION.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND FREE(FRIABLE) ASBESTOS. ================== Accidental Release Measures ================== Spill Release Procedures:WET WASTE.VACUUM UP ANY WASTE WITH HEPA FILTERED VACUUM CLEANER. WEAR PROTECTIVE EQUIPMENT AND HALF FACE RESPIRATOR WITH HEPA FILTERS. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLEAN,DRY PLACE,AWAY FROM STRONG OXIDIZING AGENTS. NORMAL WASH UP AFTER HANDLING IS RECOMMENDED. Other Precautions:ASBESTOS IS BONDED BY AN ELASTOMETER COMPOUND, HOWEVER, DO NOT MISUSE BY IMPROPER CUTTING OR HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS. Ventilation:IF FIBERS MAY BE RELEASED, USE LOCAL EXHAUST VENTILATION. Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS AND DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED AND BECOME AIRBORNE. ================== Physical/Chemical Properties ================== HCC:T7 Spec Gravity:0.6 Appearance and Odor:TAN FELT WITH PHENOLIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:SMOKE,CARBON MONOXIDE,HYDROGEN CHLORIDE,CHLORINE BEARING DECOMPOSITION PRODUCTS,ASBESTOS FIBERS,UNKNOWN PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. ASBESTOS DUST SHOULD BE WETTED AND VACUUMED UP WITH HEPA FILTERED VACUUM CLEANER,SEALED IN A PLASTIC BAG,AND TURNED IN TO DISPOSAL COMPANY.DISPOSE OF IN ACCOR DANCE WITH ALL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KEROSENE STANDARD AR 2841 CAGE:3R931 CAGE:3R931 ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE; (PETROLEUM DISTILLATE) CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: CAN CAUSE SEV IRRIT, REDNESS, TEARING, BLURRED VISION. SKIN: PRLNG/RPTD CONT CAN CAUSE MOD IRRIT, DEFAT, DERM. INHAL: EXCESS INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT, CNS EFTS INCL DIZZ , WEAK, FATG, NAUS, HDCH & POSS UNCON, & EVEN DEATH. SWALLOWING CAN CAUSE GI IRRIT, NAUS, VOMIT, & (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: DIARR. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM PNEUMIT WHICH CAN BE FATAL. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: THORO WASH EXPOS AREA W/SOAP & WATER. REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. EYES: FLUSH W/LGE AMTS OF WATER, LIFTING UPPER & LOWER LIDS OCCAS. GET MED ATTN. INGEST: DO NOT INDUCE VOMIT, KE EP PERS WARM, QUIET & GET MED ATTN. ASPIR OF MATL INTO LUNGS DUE TO VOMIT CAN CAUSE CHEM PNEUMIT WHICH CAN BE FATAL. INHAL: REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN OXYGEN. IF BRTHG HAS (SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point:144F,62C Lower Limits:0.7% Extinguishing Media:USE REGULAR FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT & POSS ENDANGER LIFE OF FIREFIGHTER, ESP IF (SUP DAT) Unusual Fire/Explosion Hazard:VAPS HVR/AIR & MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY HEAT, PILOT LIGHTS, OTHER FLAMES & IGNIT SOURCES AT LOCATIONS DISTANT FROM MATL (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB LIQ ON PAPER, VERMICULITE, FLOOR ABSORB/OTHER ABSORB MATL & TRANSFER TO HOOD. ALLOW VOLAT PORTION TO EVAP IN HOOD. ALLOW SUFFICIENT TIME FOR VAPS TO COMPLETELY CLEAR HOOD DUCT WORK. DISP OF REM AINING MATL I/A/W APPLICABLE REGULATIONS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTRS OF THIS MATL MAY BE HAZ WHEN EMPTIED, SINCE EMPTIED CONTRS RETAIN PROD RESIDUES (VAP, LIQ, AND/OR SOLID), ALL HAZ PREC GIVEN MUST BE OBSERVED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. Ventilation:PROVIDE SUFFICIENT MEHCANICAL VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S. Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: SPRAYED INTO CONTRS OF HOT, BURNING LIQ. EXPLO HAZ: HNDLG POINT. NEVER USE WELDING/CUTTING TORCH ON/NEAR BOTTLE (EVEN EMPTY) BECAUSE PROD (EVEN JUST REDISUE) CAN IGNITE EXPLO. FIRST A ID PROC: STOPPED, GIVE ARTF RESP. KEEP PERS WARM, QUIET & GET MED ATTN. EYE PROT: GOGG & FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:320F,160C Vapor Pres:0.27 @100F Vapor Density:>AIR Spec Gravity:<1(H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SLIGHT Appearance and Odor:CLEAR SLIGHTLY VISCOUS LIQUID Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, VARIOUS HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH STATE, FEDERAL, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DULUX ALKYD ENAMEL 24D CAGE:19898 CAGE:90227 CAGE:19898 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:AROMATIC HYDROCARBONS (VAPOR PRESSURE = 5) ACGIH TLV:50 PPM Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN) CAS:8030-30-6 RTECS #:SE7555000 OSHA PEL:100 PPM Ingred Name:ACRYLIC RESIN ===================== Hazards Identification ===================== Effects of Overexposure:NOSE/THROAT IRRITATION. HEADACHE, DIZZINESS, NAUSEA, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS ======================= First Aid Measures ======================= First Aid:IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES; CALL A PHYSICIAN. IN CASE OF SKIN CONTACT WASH W/SOAP & WATER. IF IRRITATION OCCURS, CONTACT A PHYSICIAN. IF AFFECT ED BY INHALATION OF VAPOR, REMOVE TO FRESH AIR ===================== Fire Fighting Measures ===================== Flash Point:20-73F (CC) Lower Limits:1.1% Upper Limits:14% Extinguishing Media:FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:WEAR SCBA. WATER COOL CONTAINERS PREVENT PRESSURE BUILD UP Unusual Fire/Explosion Hazard:FINE MISTS OR SPRAYS MAY BE FLAMMABLE AT TEMPERATURES BELOW THE FLASH POINT. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION. PREVENT SKIN CONTACT AND BREATHING OF VAR. CONFINE AND REMOVE WITH INERT ABSORBANT. ======================Handling and Storage ====================== Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY FROM HEAT, SPARKS & FLAME. CLOSE CONTAINER AFTER EACH USEGROUND CONTAINERS WHEN POURING. Other Precautions:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING OR SMOKING. DON'T STORE ABOVE 120F. DON'T SAND/FLAME CUT/BRAZE OR WELD DRY COING W/OUT A NIOSH/MSHA APPROVED RESP/APPROPRIATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A PROPERLY FITTED NIOSH/MSHA APPROVED PAINT SPRAY RESPIRATOR. Ventilation:PROVIDE VENTILATION TO KEEP BELOW TLV Supplemental Safety and Health ALSO CONTAINS: TITANIUM DIOXIDE (XR2275000), 10MG/CUM. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:176-426F Vapor Density:>AIR Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SLIGHT Percent Volatiles by Volume:68.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE Hazardous Decomposition Products:CO, CO2, SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS. DON'T INCINERATE IN CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GREEN 24533, SEMI-GLOSS ENAMEL CAGE:OBRN9 CAGE:33832 CAGE:OBRN9 ============= Composition/Information on Ingredients ============= Ingred Name:PIGMENTS, 29-33% Ingred Name:VEHICLE, 67-71% Ingred Name:SOLVENTS, 12-13% Ingred Name:ADDITIVES, .5-1% ===================== Hazards Identification ===================== Effects of Overexposure:DIZZINESS ======================= First Aid Measures ======================= First Aid:REMOVE TO FRESH AIR. SKIN & EYES: FLUSH W/WATER. ===================== Fire Fighting Measures ===================== Flash Point:100F PMCC Extinguishing Media:CO*2 ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE AT TEMPS OVER 150F BECAUSE OF EXPANSION OF CONTAINER CONTENTS. Other Precautions:DO NOT FREEZE. DOT: COMBUSTIBLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APP RESP PROT FOR EXP OF CONCERN Ventilation:LOCAL: OPEN WINDOW. MECH: FANS, MFG REC Supplemental Safety and Health % VOLATILE BY VOL: 59-60%. INGREDIENT PERCENTAGES ARE APPROX, EXCEEDING 100%. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:320F Spec Gravity:1.1100 Evaporation Rate & Reference:.06 TOLUENE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IAW FED, STATE, LOCAL REGULATIONS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FIBERGLASS FABRIC, 1241 GRAY CAGE:IO573 CAGE:0VULI CAGE:IO573 ============= Composition/Information on Ingredients ============= Ingred Name:FIBERGLASS; (CONTINUOUS FILAMENT/FIBERGLASS) MP: 1292F,700C CAS:65997-17-3 Fraction by Wt: >85.0% OSHA PEL:5 MG/M3 RESP DUST ACGIH TLV:10 MG/M3 (<7MICRONS) Ingred Name:WEAVING SIZE RTECS #:9999999ZZ Fraction by Wt: >2.0% Other REC Limits:N/H Ingred Name:ACRYLIC LATEX BINDER Fraction by Wt: 1-14% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PIGMENT Fraction by Wt: 0.3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:CANCER WHEN THE ANIMALS BREATHED LARGE QUANTITIES OF GLASS FIBERS. ARTIFICIAL IMPLANTATION OR INJECTION (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:OF FINE GLASS FIBERS INTO THE CHEST, ABDOMINAL CAVITY OR TRACHEA OF LABORATORY ANIMALS HAS PRODUCED CANCER. RTECS #:9999999ZZ Ingred Name:VENT:LOCAL EXHAUST VENTILATION IS NOT FEASIBLE. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:LONG-SLEEVED CLOTHING. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN, EYES, AND RESPIRATORY IRRITATION. OSHA CLASSIFIES FIBROUS GLASS AS A NUISANCE DUST. ACUTE:INHAL: MECHANICAL IRRIT OF THE MOUTH, NOSE, & THROAT. SKIN:TRANSIENT MECHANICAL IRRITATION. EYE:DIRECT C ONTACT WILL CAUSE MECHANICAL IRRITATION. INGEST:UNLIKELY TO OCCUR. OBSERVE INDIVIDUAL. IF SYMPTOMS OF (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:GI IRRIT DEVELOP, CONSULT PHYSICIAN. CHRONIC:INHAL:MANY STUDIES HAVE BEEN CONDUCTED TO DETERM LONG-TERM EFTS OF FIBROUS GLASS INHAL. ALTHOUGH INCONCLUSIVE, SOME RESEARCH INDICATED MFG EMPLOYE ES FIRST EMPLOYED MORE THAN 30 YEARS AGO IN FACTORIES THAT MFRS GLASS WOOL & MINERAL WOOL & MINERAL WOOL HAVE AN(SUPDAT) Medical Cond Aggravated by Exposure:ANY CONDITIONS GENERALLY AGGRAVATED BY MECHANICAL IRRITATANTS IN AIR OR ON SKIN. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES; GET MEDICAL ASSISTANCE IF IRITATION PERSISTS. SKIN: WASH WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR; DRINK WATER TO CLEAR THROAT AND BLOW NOSE TO EXPEL FIBERS. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Extinguishing Media:USE THAT WHICH IS APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . THERMAL DECOMPOSITION OF FIBER COATING MAY PRODUCE AN IRRITATING MIXTURE OF SMOKE AND FUMES. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:PREVENT SPREAD OF FIBERGLASS DUST AND AVOID DUST GENERATION CONDITIONS. THOSE INVOLVED IN CLEANUP OF PARTICULATES SHOULD USE APPROPRIATE PERSONAL PROTECTION EQUIPMENT. VACUUM CLEAN DUSTS. IF SWEEPING IS NECESSARY, USE A DUST SUPPRESSANT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AND USE IN A MANNER THAT WILL PREVENT AIRBORNE PARTICULATES IN THE WORKPLACE. Other Precautions:NONE KNOWN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE DUST LEVELS EXCEED THE TLV, USE NIOSH APPROVED RESPIRATOR TO PROTECT AGAINST NUISANCE DUSTS. Ventilation:LOCAL EXHAUST:RECOMMENDED FOR PROCESSING MACHINERY WHERE DUST GENERATION IS APPARENT. MECHANICAL (GENERAL) WHERE (ING 7) Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . BARRIER CREAM. WORK APRONS/SMOCKS. WEAR LOOSE FITTING, (ING 8) Work Hygienic Practices:WASH THOROUGHLY AFTER WORK. RECOMMEND LAUNDER WORK CLOTHES SEPARATELY AND WIPE OUT WASHER AT END OF CYCLE. Supplemental Safety and Health EFTS OF OVEREXP:INCRD RATE OF LUNG CANCER AS COMPARED TO CERTAIN OTHER REFERENCE POPULATIONS. FURTHER STUDY IS PLANNED TO IDENTIFY THOSE FACTORS ASSOCD W/RPTD INCRD RATE. SIMILAR FINDINGS WERE NOT RPT D REGARDING EMPLOYEES IN TEXTILE MFR PLANTS. ANIMAL STUDIES HAVE NOT DEMONSTRATED AN INCRD RATE IN LUNG (ING 5) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:SEE ING 1 Spec Gravity:2.5 (H*2O = 1) Solubility in Water:INSOLUBLE Appearance and Odor:WOVEN FABRIC/NO DISCERNABLE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN MOST CASES, MOVE FIBERGLASS SCRAP CAN BE DISPOSE OF IN A SANITARY LANDFILL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. CHECK WITH LOCAL AUTHORITIES OF ANY QUESTIONS CONCENRING DISPOSA L.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:48747 PURGEABLE HALOCARBON MIXTURE CAGE:54968 CAGE:54968 ============= Composition/Information on Ingredients ============= Ingred Name:PERCHLOROETHYLENE (TETRACHLOROETHYLENE) (SUSPECTED ANIMAL CARCINOGEN BY NTP & IARC - GROUP 2B) *95-2* CAS:127-18-4 RTECS #:KX3850000 Fraction by Wt: 0.012% Other REC Limits:50 PPM OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TRICHLOROETHYLENE, TCE, TRICHLOROETHENE (IARC HUMAN INADEQUATE - GROUP 3).*95-2* CAS:79-01-6 RTECS #:KX4550000 Fraction by Wt: 0.012% Other REC Limits:50 PPM OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *95-2* CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 99.592% Other REC Limits:200 PPM OSHA PEL:260 MG/CUM ACGIH TLV:262 MG/CUM (SKIN) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CARBON TETRACHLORIDE (SUSPECTED CARCINOGEN BY ACGIH & NTP, ANIMAL CARCINOGEN BY IARC, IARC GROUP 2B) *95-2* CAS:56-23-5 RTECS #:FG4900000 Fraction by Wt: 0.012% Other REC Limits:5 PPM OSHA PEL:2 PPM ACGIH TLV:5 PPM (SKIN) EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ozone Depleting Chemical:1 Ingred Name:DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSP HUMAN CARC BY ACGIH, SUSP ANIM CARC BY IARC; NTP - IARC GROUP 2B) *95-2* CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 0.012% ACGIH TLV:174 MG/CUM (A2) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,3-DICHLOROPROPENE (ANIMAL CARCINOGEN BY IARC-GROUP 2B; SUSPECTED CARCINOGEN BY NTP) *95-2* CAS:542-75-6 RTECS #:UC8310000 Fraction by Wt: 0.012% Other REC Limits:1 PPM ACGIH TLV:4.5 MG/CUM (A2) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:CHLOROBENZENE (MONOCHLOROBENZENE) (CONFIRMED ANIMAL CARCINOGEN BY NTP) *95-2* CAS:108-90-7 RTECS #:CZ0175000 Fraction by Wt: 0.06% Other REC Limits:75 PPM OSHA PEL:350 MG/CUM ACGIH TLV:46 MG/CUM IC EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:1,2-DICHLOROETHANE, ETHYLENE DICHLORIDE (SUSPECTED ANIMAL CARCINOGEN BY IARC, SUSPECTED CARC BY NTP - GROUP 2B) *95-2* CAS:107-06-2 RTECS #:KI0525000 Fraction by Wt: 0.06% Other REC Limits:40 MG/CUM OSHA PEL:1 PPM ACGIH TLV:10 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (CHLOROTHENE NU), AEROTHANE TT, CHLOROTHENE (IARC CARC - GROUP 3)*95-2* CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 0.06% Other REC Limits:450 PPM STEL OSHA PEL:350 PPM ACGIH TLV:350 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:1,1-DICHLOROETHANE (ETHYLIDINE CHLORIDE) CAS:75-34-3 RTECS #:KI0175000 Fraction by Wt: 0.012% Other REC Limits:200 PPM OSHA PEL:400 MG/CUM ACGIH TLV:810 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,1,2-TRICHLOROETHANE (SUSPECTED ANIMAL CARCINOGEN BY IARC GROUP 3) *95-2* CAS:79-00-5 RTECS #:KJ3150000 Fraction by Wt: 0.012% Other REC Limits:10 PPM OSHA PEL:45 MG/CUM ACGIH TLV:55 MG/CUM (SKIN) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:1,1,2,2-TETRACHLOROETHANE (SUSPECTED ANIMAL CARCINOGEN BY IARC - GROUP 3) *95-2* CAS:79-34-5 RTECS #:KI8575000 Fraction by Wt: 0.012% Other REC Limits:1 PPM OSHA PEL:35 MG/CUM ACGIH TLV:6.9 MG/CUM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:O-DICHLOROBENZENE, 1,2-DICHLOROBENZENE (ORTHO) CAS:95-50-1 RTECS #:CZ4500000 Fraction by Wt: 0.012% Other REC Limits:50 PPM OSHA PEL:300 MG/CUM ACGIH TLV:301 MG/CUM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:1,3-DICHLOROBENZENE (META) CAS:541-73-1 RTECS #:CC4499000 Fraction by Wt: 0.012% EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:P-DICHLOROBENZENE, 1,4-DICHLOROBENZENE (PARA); BENZENE, P-DICHLORO; PARADICHLORBENZENE(ANIMAL CAR IARC/NTP GRP 2B)*95-2* CAS:106-46-7 RTECS #:CZ4550000 Fraction by Wt: 0.012% Other REC Limits:75 PPM A2 CARCINOGEN OSHA PEL:450 MG/CUM ACGIH TLV:451 MG/CUM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:VINYLIDENE CHLORIDE, 1,1-DICHLOROETHENE, 1,1-DICHLOROETHYLENE, VDC CAS:75-35-4 RTECS #:KV9275000 Fraction by Wt: 0.024% Other REC Limits:5 PPM OSHA PEL:1 PPM ACGIH TLV:20 MG/CUM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TRANS-1,2-DICHLOROETHYLENE, TRANS-1,2-DICHLOROETHENE CAS:156-60-5 RTECS #:KV9400000 Fraction by Wt: 0.06% ACGIH TLV:200 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,2-DICHLOROROPANE CAS:78-87-5 RTECS #:TX9625000 Fraction by Wt: 0.012% Other REC Limits:75 PPM OSHA PEL:75 PPM ACGIH TLV:347 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 5628 MG/KG METHANOL Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:HARMFUL IF INHALED. FATAL IF SWALLOWED. EYES: MAY CAUSE BLINDNESS. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:HEADACHE, NAUSEA, GASTROINTESTINAL DISTURBANCES ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/LARGE VOLUMES OF WATER. INHALATION: MOVE TO FRESH AIR. IF BREATHING STOPS, GIVE CPR. INGESTION: NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. NEVER TRY TO MAKE AN UNCONSICOUS PERSON VOMIT. GIVE2 TABLESPOONS OF BAKING SODA IN A GLASS OF WATER, PRESS FINGER TO BACK OF TONGUE TO INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:50F Lower Limits:6 Upper Limits:36 Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WHEN FIGHTING A CHEMICAL FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA. ELIMINATE ALL IGNITION SOURCES. ======================Handling and Storage ====================== Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP AWAY FROM OXIDIZERS & FROM IGNITION SOURCES. Other Precautions:AVOID EYE/SKIN CONTACT. AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR FACE MASK W/ORGANIC VAPOR CANISTER. Ventilation:USE ONLY IN WELL VENTILATED AREA. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:149F Melt/Freeze Pt:M.P/F.P Text:-144F Vapor Pres:100 Vapor Density:1.1 Spec Gravity:0.79 Evaporation Rate & Reference:(ETHER=1): >1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESSLIQUID Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC ACIDS Stability Condition to Avoid:IGNITION SOURCES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SUPER CONVOY DARK GRAY 2PK CONSISTS OF 370( Kit Part:Y CAGE:8N481 CAGE:8N481 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-PROPOXY-; (2-PROPOXYETHANOL). VP: 1.3 CAS:2807-30-9 RTECS #:KM2800000 Fraction by Wt: 3.0% Ingred Name:NAPHTHA, LIGHT AROMATIC. VP: 3.0 CAS:64742-95-6 Fraction by Wt: 16.0% ACGIH TLV:100 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:LIQUID MAY CAUSE EYE BURNS. PROLONGED SKIN CONTACT WITH LIQUID MAY PRODUCE IRRITATION. EYE, NOSE AND THROAT IRRITATION MAY RESULT FROM EXPOSURE TO VAPOR. NARCOTIC EFFECTS OCCUR AT HIGHER CONCENTRATION S OF VAPOR. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY, EYE, AND SKIN CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYE: IRRIGATE IMMEDIATELY AND THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES AND GET MD. SKIN: FLUSH IMMEDIATELY AND THOROUGHLY WITH WATER. INHAL: REMOVE FROM EXPOSURE, TREAT SYMPTOMATICALLY, AND GET M D. INGEST: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:110F,43C Lower Limits:1.0% Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . AVOID SOLID STREAM OF WATER, USE FOG FOR COOLING. Unusual Fire/Explosion Hazard:FLAMMABLE VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. FLUSH SPILL AWAY WITH WATER SPRAY. SMALL SPILLS MAY BE COLLECTED WITH ABSORBENT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MATL IS CLASSIFIED AS FLAM LIQ.KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME.KEEP CNTNR CLSD.AVOID EYE CONT, PRLNGD SKIN CONT & INHAL OF HIGH CONC OF VAP. Other Precautions:USE W/VENT ADEQ TO MAINTAIN VAP CONC <TLV OF 50 PPM. HAZ PROD RESIDUE MAY REMAIN AFTER PROD HAS BEEN REMOVED FROM ITS CNTNR. DO NOT REUSE "EMPTY" CNTNR W/OUT COMMERCIAL CLEANING OR RECONDITIONING. SEE ALSO 29 CODE OF FED REG 1910.1000. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS SHOULD BE WORN IF NEEDED. Ventilation:LOCAL EXHAUST RECOMMENDED. Other Protective Equipment:SAFETY SHOWER & EYEBATH IN WORK AREA. Work Hygienic Practices:REMOVE PAINT FROM SKIN CONTACT AFTER EXPOSURE. Supplemental Safety and Health MFR PART NO: + 368C, 370K COATINGS. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:300F,149C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Spec Gravity:1.57 Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:39.30 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS CAN CAUSE A VIGOROUS REACTION. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:AS WITH ANY OTHER ORGANIC MATERIAL, COMBUSTION WILL PRODUCE CO2 AND PROBABLY CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:MIX WITH A COMPATIBLE CHEMICAL WHICH IS LESS COMBUSTIBLE AND INCINERATE. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS CONCERNING HEALTH AND POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:75685-02532, RED DEVIL ACRYLIC LATEX GLOSS (SUPDAT) CAGE:JO303 CAGE:63727 CAGE:JO303 ============= Composition/Information on Ingredients ============= Ingred Name:PROPIONIC ACID, 2-METHYL-, MONOESTER WITH 2,2,4-TRIMETHYL-1,3--PENTANEDIOL; (2,2,4-TRIMETHYL-1,3-PENTANEDIOL(ING 2) CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: <5% Ingred Name:ING 1: MONOISOBUTYRATE). LD50 (ORAL, RAT): 3200 MG/KG. RTECS #:9999999ZZ Ingred Name:1,2-PROPANEDIOL; (PROPYLENE GLYCOL). LD50 (ORAL,RAT): 20 GRAM/KG. CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: <5% OSHA PEL:0.05 PPM ACGIH TLV:0.05 PPM Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0-20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SUPP DATA: EXTENT FEASIBLE, SKIN AND EYE CONTACT AND INHALATION OF CHEMICAL PRODUCTS. RTECS #:9999999ZZ Ingred Name:SPILL PROC:SPILLS INVOLVING MULTIPLE UNITS: RESP IF VENT IS ADEQ, NO RESP PROT IS NEC.IF RESP IS DEEMED TO BE NEC(ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:SEEK PROFESSIONAL ADVICE PRIOR TO RESP SELECTION & USE. FOLLOW OSHA RESP REGS (29 CFR 1910.134). IF THERE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:IS POTNTL FOR UNCONTROLLED RELS, EXPOS LEVS ARE NOT KNOWN, OR ANY OTHER CIRCUMSTANCES WHERE AIR PURIFYING (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION, USE A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:2,2,4-TRIMETHYL-1,3-PENTANEDIOL MONOISOBUTYRATE (CAS# 25265-77-4) CAUSES TRANSIENT SKIN & EYE (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: IRRIT INVOLVING REDNESS & SWELLING. 2,2,4-TRIMETHYL-1,3-PENTANEDIOL MONOISOBUTYRATE IS OF LOW ORDER OF (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: TOX WHEN TAKEN ORALLY. PROPYLENE GLYCOL IS COLORLESS, ODORLESS, WATER-SOLUBLE LIQ. BECAUSE OF IT'S LOW (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:ORDER OF TOX,IT IS OFTEN USED IN COMMERCIAL FORMS OF FOODS, DRUGS & COSMETICS. EYE CONT & FREQUENT DERMAL(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: CONT W/PROPYLENE GLYCOL CAN CAUSE SLIGHT SKIN IRRIT WHICH HAS BEEN DESCRIBED BY FAINT, PATCHY REDNESS (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: W/SWELLING. PROPYLENE GLYCOL IS RAPIDLY ABSORBED FROM GI TRACT. THERE IS LITTLE DIFFERENCE IN ACUTE ORAL(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: TOXICITY OF PROPYLENE GLYCOL IN DIFFERENT SPECIES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: >5.0 GRAM/KG.ING 1:3200 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: LOCAL EFFECTS (EYES, SKIN, NOSE, THROAT, STOMACH, ETC.) MAY CAUSE SLIGHT IRRITATION TO THOSE WITH SENSITIVE SKIN.THIS SECTION PROVIDES RELEVANT INFO W/REGARD TO ANY TOX STUDIES PERFORMED ON PRO D,OR "PURE" FORM OF COMPONENT(S).INFO CAN BE SUBJECT TO MISINTERPRETATION. ESSNTL (EFTS OF OVEREXP) Effects of Overexposure:HLTH HAZ:THAT FOLLOWING INFO BE INTERPRETED BY INDIVS TRAINED IN ITS EVAL FOR ASSIST W/INTERPRETING INFO,CONT HAZ INFO SERVICES AT 1-800-228-5635 EXT 218/(612)221-3999 EXT 218, 24 HOURS-A-DAY. PROD BA SED: SKIN TESTING W/FORMULA SHOWED POTNTL FOR VERY SLIGHT, READILY REVERSIBLE SKIN IRRIT (PII=1.42). ING BASED:(ING 11) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH W/PLENTY OF WATER.REMOVE CONT LENSES & CONTINUE FLUSHING FOR AT LST 15 MINS.SEEK MD ATTN IF IRRIT DEVELOPS & PERSISTS.SKIN: REMOVE CONTAMD CLTHG. FLUSH AFFECTED AREA W/WATER, THEN WASH THORO W/MILD SOAP & WATER.SEEK MD ATTNIF IRRIT DEVELOPS & PERSISTS.INGEST: WIPE OUT MOUTH & GIVE 1-2 GLASSES OF WATER.CONT PHYS/POIS CNTRL CENTER. INHAL: REMOVE TO FRESH AIR IMMED.SEEK MD (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:NONE TO BOILING Extinguishing Media:USE MATERIAL COMPATIBLE WITH OTHER BURNING MATERIAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT LIKELY TO CONTRIBUTE TO A FIRE HAZARD. HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT ATTEMPT TO CLEAN UP CHEM SPILLS W/OUT APPROP PERS PROT EQUIP. COLLECT SPILLED PROD & TRANSFER TO SEALABLE CNTNR FOR REUSE/DISP. RINSE AREA & COLLECT WATER FOR DISP. KEEP WASTE OUT OF SEWERS, WA TERSHEDS, & WATERWAYS. FOR CLEANING UP (ING 7) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE MATERIALS. USE WITH PROPER PERSONAL PROTECTIVE EQUIPMENT. Other Precautions:EMPTY CNTNRS MAY RETAIN HAZ PROPERTIES, FOLLOW ALL MSDS/LABEL WARNINGS EVEN AFTER CNTNR IS EMPTIED. DO NOT REUSE EMPTY CONTAINER FOR FOOD, CLOTHING, OR PRODS FOR HUMAN OR ANIMAL CONSUMPTION. KEEP THIS AND ALL CHEMS OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:ASSURE THAT VENTILATION IS ADEQUATE. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:USE GOOD PERS & INDUS HYGIENE PRACTS.WASH THORO AFTER USING PROD.KEEP PROD OFF OF CLTHG & EQUIP.LAUNDER CONTAMD (SUPDAT) Supplemental Safety and Health TRADE NAME/PART #:ENAMEL-ALL SHADES. PH:8.75 +/- 0.25.FIRST AID PROC: ATTN IF BRTHG DFCLTY DEVELOPS.NOTES TO PHYS:CONT HAZ INFO SERVICES FOR ASSIST W/MANAGEMENT OF EXPOS TO THIS PROD. HYGIENE PRACT:CL THG BEFORE RE-USE. DO NOT EAT, DRINK, OR SMOKE IN ANY WORK AREA. IT IS ALWAYS GOOD HYGIENE PRACT TO LIMIT, TO (ING 6) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:197F,92C Vapor Density:>1 Volatile Org Content %:9 Spec Gravity:1.017-1.243 pH:SUPDAT Evaporation Rate & Reference:<1(N-BUTYL ACETATE=1) Solubility in Water:DILUTABLE Appearance and Odor:OPAQUE, VISCOUS LIQUID WITH SLIGHT AMMONIA ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. DO NOT MIX WITH OTHER MATERIALS UNLESS SPECIFIED ON THE LABEL. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL EXPERT FOR ADVICE ON THE DISPOSAL OF THIS MATERIAL. CHARACTERISTICS OF RECOVERED MATERIAL MAY DIFFER FROM THOSE OF ORIGINAL MATERIAL. ENSURE THAT DISPOSAL IS IN COMPLIANCE WITH LOCAL, ST ATE AND FEDERAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:01537 AIRCRAFT HYDRAULIC OIL 15 Preparer's Name:MANAGER, PRODUCT SAFETY CAGE:OTTJ3 CAGE:59595 CAGE:OTTJ3 CAGE:2R503 ============= Composition/Information on Ingredients ============= Ingred Name:2,6-DI-TERT-BUTYL-P-CRESOL; (2,6-DI-TERT-BUTYL-4-METHYLPHENOL) CAS:128-37-0 RTECS #:GO7875000 Fraction by Wt: 3-10.99% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3; 9495 Ingred Name:BUTYLATED TRIPHENYL PHOSPHATE W/30% TRIPHENYL PHOSPHATE(CAS#115-86-6) CAS:56803-37-3 Fraction by Wt: .1-.99% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROTREATED MIDDLE PETROLEUM DISTILLATE;(SOLVENT REFINED HYDROTREATED MIDDLE DISTILLATE) CAS:64742-46-7 RTECS #:JN9379645 Fraction by Wt: 80-94.9% Other REC Limits:NONE RECOMMENDED Ingred Name:METHACRYLIC ACID;COPOLYMER WITH METHYL & LAURYL ESTERS CAS:30795-64-3 Fraction by Wt: 3-10.99% Other REC Limits:NONE RECOMMENDED Ingred Name:METHYL METHACRYLATE (SARA 313) (CERCLA), 0.01-0.09%. CAS:80-62-6 RTECS #:OZ5075000 Fraction by Wt: SEE ING Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT):>5G/KG,PRACTICALLY NONTOX Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:MINIMAL IRRIT,EPERIENCED AS TEMP DISCOMFORT.SKIN:PROL/WIDESPREAD CONTACT RESULT IN ABSORPTION OF POT HARMFUL AMTS OF MATL.PROLONG CONTACT W/WET CLOTH-DEFATTING,IRRIT.INHAL:VAP/MIST IN EXCESS CONCE N IRRIT NOSE/THROAT.PROL/REPEAT OVEREXPO-ABSORPTION OF HARMFUL AMTS.INGEST:ABD DISCOMFORT,NAU,ASPIRATION HAZ (SIGN/SYM) Explanation of Carcinogenicity:PER MSDS:MIDDLE DISTILLATED HAVE CAUSE SKIN CANCER IN LAB ANIMALS APPLIED REPEATED/LEFT IN PLACE BETWEEN APPLICATIONS. Effects of Overexposure:HEALTH HAZ:RESULTING IN LUNG DMG.INTERFERE W/N &/OR MUSCULAR FUNCTIONS BY INHIBITION OF ESTERASE.DISFIGUREMENT,FUNCTION LOSS IF INJECTED. EYE IRRIT-TEMP DISCOMFORT.SKIN DEFAT/IRRIT,LOC REDNESS W/POSSI BLE MILD DISCOMFORT.IRRIT NOSE/THROAT,HEAD,NAU,DROWS.ABD DISCOMFORT,NAU,DIARR,ASPIRATION INTO LUNGS RESULT IN LUNG DMG. Medical Cond Aggravated by Exposure:REP OVEREXPO MAY AGGRAVATE/ENHANCE EXISTING CNS DYSFUNCTION PROD BY DISORDERS KNOWN TO CAUSE CNS EFFECTS/DMG(DIABETES,ALCOHOL/DRUG ABUSE,PARKINSON'S DISEASE)DEFATTING PROPERT AGGRAVATE EXISTING DERM. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/LOTS OF H20 FOR SEVERAL MINS.IRRIT PERSISTS GET MED ATTN.SKIN:WASH W/LOTS OF SOAP/WATER TIL ALL TRACES OF MATL REMOVED.REMOVE CONTAMIN CLOTH.IRRIT PERSISTS/CONTACT PROLONG GET MED ATTN.ING EST:GET IMMED MED ATTN.ONLY INDUCE VOMIT AS DIRECTED BY DR.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC/CONVULSING.INHAL:IRRIT/HEAD/NAU/DROWS OCCURS MOVE TO FRESH AIR.BREATH DIFF GET MED ATTN.(OTHER PRECA) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:180F,82C Lower Limits:N/D Upper Limits:N/D Extinguishing Media:PER NFPA:USE WATERSPRAY,DRY CHEM,FOAM,CO2.WATER/FOAM MAY CAUSE FROTH. Fire Fighting Procedures:USE WATER TO COOL FIRE-EXPO CNTNRS.LEAK/SPILL NOT IGN USE WATERSPRAY TO DISPERSE VAP/PROTECT PERSONS ATTEMPTING TO STOP LEAK. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA.AVOID BREATH VAP.USE SCBA/SUPPLIED AIR FOR LG SPILLS/CONFINED AREAS.CONTAIN IF POSSIBLE.WIPE UP/ABSORB ON SUITABLE MATL.SHOVEL UP.PREVENT ENTRY INTO SEWERS/WATERWAYS.AVOID CONTACT W/SKI N/EYE/CLOTHING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FRM HEAT/OPN FLAME.TRANSP/HNDLG/STORE IAW OSHA REG 1910.106/DOT REGS.READ/UNDERSTAND MSDS BEF HNDLG/DISPO PROD. Other Precautions:DR:HIGH PRESSURE INJECTION OF MATL INTO SKIN CAN CAUSE SEVERE INJURY IF NOT TREATED.USE X-RAY.ASPIRATION OF PROD DURING INDUCED EMESIS CAN RESULT IN LUNG INJURY.USE METHOD LEAST LIKELY TO CAUSE ASPIRA TION.PROD HAS ARYLPHOSPHATE-(SUPPLEMEM) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AIRBORNE CONCEN SHOULD BE KEPT LOWEST LVELS POSSIBLE.IF VAP/MIST/DUST GENERATED USE NIOSH/MSHA APPROVED RESP AS APPROPRIATE.SUPPLIED AIR RESP PROT SHOULD BE USED FOR CLEAN LG SPILLS/UPON ENTRY INTO TK S/VESS/CONF SPACES. Ventilation:ADEQUATE TO MEET COMPONENT OCCUPATIONAL EXPO LIMITS. Other Protective Equipment:PROT CLOTH:UNIFORMS,COVERALLS,LAB COATS,BOOTS RESISTANT TO CHEM/PETRO DISTILLATES. Work Hygienic Practices:CLEAN (LAUNDRAY MORE EFFECTIVE-INFORM LAUNDRY OF CONTAMIN)CONTAMIN CLOTH BEF REUSE;DESTROY NON-RESIST FOOTWEAR. Supplemental Safety and Health OTHER PRECAUT:INHIBITS ESTERASE. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>400F,>204C Vapor Pres:N/D Vapor Density:N/D Spec Gravity:0.8729 Viscosity:13.2CST @40C Solubility in Water:N/D Appearance and Odor:RED LIQUID Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS VIOLENTLY W/STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOX LEVELS CO,CO2,IRRIT ALDEHYDES & KETONES & COMBUSTION PRODS/CMPDS OF PHOSPHORUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PROD DOES NOT MEET CRITERIA OF HAZ WASTE IF DISCARDED IN PURCHASED FORM.PER RCRA USER RESPONSABILITY TO DERMINE @DISPO TIME WHETHER PROD MEETS RCRA CRITERIAL FOR HAZ WASTE.
1
eyes_protection_mandatory
======================================================= Product ID: ULTRA ETCH 50 - REPLENISHER Cage: JO703 ======================================================= Contractor Summary ======================================================= Cage: 5R956 Cage: JO703 ======================================================= Ingredients ======================================================= Cas: 12125-02-9 RTECS #: BP4550000 % Wt: 23-25 OSHA PEL: 10 MG/M3 ACGIH TLV: 10 MG/M3 FUME EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 1336-21-6 RTECS #: BQ9625000 % Wt: 21-23 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 10361-29-2 % Wt: 2-4 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7664-41-7 RTECS #: BO0875000 OSHA PEL: 50 PPM ACGIH TLV: 25 PPM/35 STEL EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------ Cas: 7440-38-2 RTECS #: CG0525000 SEVERAL HUNDRED PARTS PER MILLION. % Wt: <0.1 OSHA PEL: SEE 1910.1018 ACGIH TLV: 0.01 MG/M3, A1 EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 7440-43-9 RTECS #: EU9800000 % Wt: <0.1 OSHA PEL: 0.2 MG/M3 DUST; Z-2 ACGIH TLV: 0.01 MG/M3 DUST EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ------------------------------ Cas: 7440-47-3 RTECS #: GB4200000 % Wt: <0.1 OSHA PEL: 1 MG/M3 ACGIH TLV: 0.5 MG/M3 EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 7439-92-1 RTECS #: OF7525000 % Wt: <0.1 OSHA PEL: SEE 1910.1025 ACGIH TLV: 0.15MG/M3 DUST EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ ----------------------------- CORROSIVITY) RQ = 100 LB. ----------------------------- CANCER, OR BIRTH DEFECTS, AND/OR OTHER REPROD HARM" ----------------------------- ----------------------------- OF IT INTO GEN WORK AREA. REFER TO ----------------------------- PRACTICES" FOR DETAILS. ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENTS 1 & 2 Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: INGEST: HUMAN POIS BY INGEST. MAY CAUSE IRRIT/BURNING OF DIGESTIVE TRACT. SYMPS MAY INCL NAUS, VOMIT, ABDOM PAIN, & DIARR. INHAL: LIQ & VAP IRRITATING TO MUC MEMB & UPPER RESP TRACT. SYMPS MAY INCL COUGH, SORE THROAT, SHORTNESS OF BREATH. SKIN: IRRITATING. SYMPS MAY INCL IRRIT, REDNESS, & PAIN. (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: EYE: MAY CAUSE SEV IRRIT, REDNESS, PAIN, BLURRED OR IMPAIRED VISION, DISCOLORATION, & DMG. CHRONIC: MAY AGGRAVATE OTHER PRE-EXISTING DISEASES TO INCLUDE DISEASES OF EYES, SKIN, LUNGS. LEAD A PPEARS ON NAVY LISTING OF OCCUP CHEM REPROD HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING (SUPDAT) Medical Cond Aggravated By Exposure: MAY AGGRAVATE OTHER PRE-EXISTING DISEASES TO INCLUDE DISEASES OF THE EYES, SKIN, LUNGS. First Aid: EYE CONT: IMMED, FLUSH W/LG AMTS OF WATER FOR @ LST 15 MINS WHILE HOLDING EYELIDS APART. WASHING W/IN 1 MIN IS ESSTNL TO ACHIEVE MAX EFTIVENESS. GET IMMED MED ATTN AFTER FLUSHING. SKIN CONT: WASH AREA THORO W/SOAP & WATER. REMOVE CONTAMD CLTHG & LAUNDER BEFORE REUSE. IF IRRIT SHOULD DEVELOP, GET MED ATTN. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE (SUPDAT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: NEVER ALLOW SPILLS TO ENTER SEWERS/WATERWAYS. VENTILATE SPILL AREA. REMOVE ALL SOURCES OF HEAT/IGNIT. VACUUM/SOAK UP SPILLED MATL. PACKAGE FOR RECLAMATION/RECOVERY. WHATEVER CANNOT BE SAVED MAY BE NEU TRALIZED W/DILUTE ACID & SENT TO APPRVD Neutralizing Agent: DILUTE ACID. Waste Disposal Methods: DISPOSE OF IN APPRVD CHEM WASTE LANDFILL I/A/W APPLIC FEDERAL, STATE, & LOCAL REGS. IF APPRVD, MAY BE SENT TO WASTEWATER TREATMENT FACILITY. SUPERFUND REPORTABLE QTY(RQ): 5000 LBS (AMMONIUM CHLORIDE), 100O LBS (AMMONIUM HYDROXIDE). HAZ WASTE Handling And Storage Precautions: KEEP IN TIGHTLY CLSD CNTNR. STORE IN COOL, DRY, WELL-VENITLATED AREA, & AWAY FROM DIRECT SUNLIGHT. PROTECT FROM FREEZING. Other Precautions: KEEP AWAY FROM INCOMPAT MATLS. PROTECT FROM PHYSICIAL DMG. GOGGS/SHIELD. WASH THOROU AFTER USING. AVOID BRTHG DUST/MIST. USE W/ADEQ VENT. WARNING: THIS PROD MAY ======================================================= Fire and Explosion Hazard Information ======================================================= Lower Limits: 15.5-16.0% Upper Limits: 25-27% Extinguishing Media: USE ANY SUITABLE MEANS TO EXTINGUISH SURROUNDING FIRE. COOL DRUMS WITH WATER SPRAY. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: THERMAL DECOMPOSITION RELEASES OXIDES OF CARBON, TOXIC AMMONIA FUMES, AND OXIDES OF NITROGEN. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPRVD RESP IF EXPOS MAY, OR DOES EXCEED OCCUP EXPOS LIMITS. GENERALLY, NIOSH APPRVD DUST/MIST RESP MAY BE WORN IN AREAS WHERE TLV IS EXCEEDED UP TO 10 TIMES. ALTERNATELY, A NIOSH APPRVD SUPPLIE D AIR FULL FACEPIECE RESP OR Ventilation: SYS OF LOC EXHAUST IS REC TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMITS. LOC EXHAUST IS USUALLY PREFERRED Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). BODY COVERING CLOTHING. Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES SHOULD BE BE WORN WHEN WORKING WITH THIS MATERIAL. Supplemental Safety and Health: VP: AQUEOUS-APPROX. 20. MP: <10C (CRYSTALLIZATION) (<50F). APPEAR/ODOR: CORROSIVE. EFTS OF OVEREXP: LATEST HAZARD LIST INFO & SAFE HANDLING & EXPOSURE INFO (FP N). FIRST AID PROC: OXYG. CALL PHYS. ING EST: NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. DO NOT INDUCE VOMIT. GIVE PLENTY OF WATER. CALL PHYS IMMEDIATELY. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >212F,>100C M.P/F.P Text: SUPDAT Vapor Pres: SUPDAT Vapor Density: <1 Spec Gravity: 1.021 (WATER=1) PH: 9-10 Evaporation Rate & Reference: NOT KNOWN Solubility in Water: COMPELTE Appearance and Odor: CLEAR, COLORLESS TO PALE-BLUE LIQUID; STRONG AMMONIA ODOR. DO NOT SMELL-(SUPDAT ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: DO NOT STORE IN DIRECT SUNLIGHT/EXPOSE TO HEAT. PROTECT FROM FREEZING. AVOID CONT W/INCOMPATIBLE MATERIALS. Materials To Avoid: ACIDS AND OXIDIZING MATERIALS; CORROSIVE TO SOME METALS. REACTS W/HALOGENS AND CERTAIN ORGANICS. Hazardous Decomposition Products: THERMAL DECOMP RELEASES OXIDES OF CARBON, TOXIC AMMONIA FUMES, AND OXIDES OF NITROGEN. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: ULTRA ETCH 50 - REPLENISHER Cage: JO703 Assigned IND: Y Company Name: PHILLIPP BROTHERS CHEMICALS INC Street: ONE PARKER PLAZA Zipcode: 07024 Label Required IND: Y Date Of Label Review: 06/22/1998 Status Code: C Label Date: 06/22/1998 Origination Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: INGEST: HUMAN POISON BY INGESTION. MAY CAUSE IRRITATION OR BURNING OF DIGESTIVE TRACT. SYMPTOMS MAY INCLUDE NAUSEA, VOMITING, ABDOMINAL PAIN, AND DIARRHEA. INHALATION: LIQUID AND VAPOR IRRITATI NG TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. SYMPTOMS MAY INCLUDE COUGHING, SORE THROAT, SHORTNESS OF BREATH. SKIN: IRRITATING. SYMPTOMS MAY INCLUDE IRRITATION, REDNESS, & PAIN. EYE: MAY CAUSE SEVERE IRRITATION, REDNESS, PAIN, BLURRED/IMPAIRED VISION, DISCOLORATION & DAMAGE. CHRONIC: LEAD APPEARS ON NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N). MAY AGGRAVATE PRE-EXISTING COND ITIONS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SARAN RESIN F-310 CAGE:71981 CAGE:96717 CAGE:71981 ============= Composition/Information on Ingredients ============= Ingred Name:COPOLYMER OF VINYLIDENE CHLORIDE AND ACRYLONITRILE Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED OSHA PEL:NOT ESTABLISHED. ACGIH TLV:NOT ESTABLISHED. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-EYES:MAY CAUSE MECHANICAL INJURY.SKIN:NON-IRRITATING.INHALATION:NOT LIKELY TO BE A HAZARD.INGESTION:TOXICITY IS LOW.MAY ACT AS OBSTRUCTION IF SWALLOWED.CHRONIC-NOT ANTICIPATED TO CAUSE ANY SIGNI FICANT ADVERSE EFFECTS. Effects of Overexposure:MAY CAUSE MECHANICAL INJURY IN EYES. INHALATION NOT LIKELY TO BE A HAZARD. INGESTION HAS A LOW TOXICITY. MAY ACT AS OBSTRUCTION IF SWALLOWED. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES:IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 5 MINUTES.SKIN/INHALATION/INGESTION:NO ADVERSE EFFECTS ANTICIPATED.HOWEVER,WASH SKIN WITH WATER.IF INHALED,REMOVE FROM EXPOSURE.IF SWALLOWED,CALL A PH YSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER FOG, CARBON DIOXIDE Fire Fighting Procedures:WEAR FIRE-FIGHTING EQUIPMENT AND A POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS TO PROTECT AGAINST HYDROGEN CHLORIDE IF RESIN IS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:IT MAY FORM HYDROGEN CHLORIDE AND OTHER UNIDENTIFIED PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND TRANSFER TO AN APPROPRIATE CONTAINER FOR DISPOSAL. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,VENTILATED AREA AWAY FROM INCOMPATIBLE PRODUCTS. Other Precautions:RESIN DEGRADES VERY SLOWLY EVOLVING HCL.KEEP IT AS COOL AS POSSIBLE.RESIN IS MOST FREQUENTLY USED IN COMBINATION WITH FLAMMABLE SOLVENT.TRANSFERRING OF RESIN FROM CONTAINER CAUSES STATIC BUILD UP WHIC H MAY CAUSE FIRE NEAR FLAMMABLE SOLVENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:GOOD GENERAL VENTILATION IS SUFFICIENT FOR MOST CONDITIONS. Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, CLEAN BODY-COVERING CLOTHING AND APRON Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE P/N A UNDER THE SAME NSN. ================== Physical/Chemical Properties ================== HCC:N1 Decomp Temp:Decomp Text:>392F,>200C Spec Gravity:1.60 Solubility in Water:INSOLUBLE Appearance and Odor:WHITE GRANULAR SOLID - UNKNOWN ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES IRON, ZINC, COPPER, ALUMINUM IN SOLUTION, STRONG BASES Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES Hazardous Decomposition Products:HYDROGEN CHLORIDE IS EVOLVE RAPIDLY WHEN RESIN IS EXPOSED TO TEMPERATURES GREATER THAN 200C. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN AN INCINERATOR EQUIPPED TO HANDLE HYDROGEN CHLORIDE FUMES OR BURY IN AN APPROVED LANDFILL. PROCEDURES MUST BE COMPLY WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IMPERIAL 2075TH HYDRAULIC LUBE OIL CAGE:DO955 CAGE:58563 CAGE:DO955 ============= Composition/Information on Ingredients ============= Ingred Name:ADDITIVES, <1% IN GAL ===================== Fire Fighting Measures ===================== Flash Point:410-440F COC Extinguishing Media:CO*2, DRY CHEM, WATER FOG, FOAM Fire Fighting Procedures:USE NIOSH/MSHA SELF-CNTND BRTHNG APPARATUS. COOL CNTNRS. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE & CONTAIN SPILL W/INERT DIKING MATL, TRANSFER SOLID & LIQ DIKING MATL TO SEPARATE CNTNR FOR RECOVERY OR DISPOSAL. AREA MAY BE SLIPPERY, CARE SHOULD BE TAKEN TO AVOID FALLS. PREVENT MATL FROM GETT ING INTO SEWERS & OPEN BODIES OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:LOW TEMP STORAGE INCREASES VISCOSITY OF THESE OILS. THESE OILS STOP POURING AT -18 TO -30C. ============= Exposure Controls/Personal Protection ============= Supplemental Safety and Health VAP PRESS <1MM @20C ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>600F Spec Gravity:0.876 Evaporation Rate & Reference:<1 BUTYL ACETATE Solubility in Water:NEGLIGIBLE Appearance and Odor:STRAW TO AMBER COLOR, NO ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CARBON MONOXIDE & CARBON DIOXIDE DUE TO BURNING ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE LIQ IN APPRVD EQUIP. LANDFILL CONTAM DIKING MATL IAW LOCAL, STATE, FED REG.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:T-GRADE PIGMENT MARKING INK, ALL COLORS, 014539 CAGE:GO822 CAGE:GO822 CAGE:0MBZ9 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (AROMATIC PETROLEUM NAPHTHA) CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 10-30% OSHA PEL:100 PPM (MFR) ACGIH TLV:N/K Ingred Name:BENZENE, TRIMETHYL- (MIXED ISOMERS); (TRIMETHYLBENZENE) CAS:25551-13-7 RTECS #:DC3220000 Fraction by Wt: 10-30% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 7-13% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:LIGROINE; (NAPHTHA) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 7-13% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:XYLENE (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1-5% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CUMENE (SARA 313) (CERCLA) CAS:98-82-8 RTECS #:GR8575000 Fraction by Wt: 1-5% OSHA PEL:S, 50 PPM ACGIH TLV:S, 50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS AN EYE, SKIN AND MUCOUS MEMBRANE IRRITANT AND CENTRAL NERVOUS SYSTEM DEPRESSENT. INHALATION MAY CAUSE HEADACHE, DIZZINESS, LOSS OF APPETITE, WEAKNESS AND LOSS OF COORDINATION. MAY ALSO CAUS E FATIGUE, NAUSEA, VOMITING, ABDOMINAL PAIN, AND NARCOSIS. CONTACT WITH EYES OR SKIN CAUSES IRRITATION (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS:AND INFLAMMATION OF TISSUES. INGESTION MAY CAUSE NAUSEA, VOMITING, COLIC, DIARRHEA, HEADACHE, DIZZINESS AND TOXIC EFFECTS INCLUDING SIGNS OF CENTRAL NERVOUS SYSTEM DEPRESSION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE CONTACT:FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND SEEK MEDICAL ATTENTION. SKIN CONTACT:WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. INHALATION:REMOVE TO FRESH AIR, IF DISCOMFORTPERSISTS, SEEK MEDICAL ATTENTION. INGESTION:DO NOT INDUCE VOMITING, CALL PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:92.0F,33.3C Lower Limits:1.0% Upper Limits:6.0% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:ISOLATE SPILL FROM SOURCES OF IGNITION. CONTAIN SPILL USING SUITABLE ABSORBENT-CONTAINERIZE IN AN APPROVED DOT CONTAINER FOR PROPER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MATERIAL IS CLASSIFIED AS FLAMMABLE-KEEP AWAY FROM HEAT AND OPEN FLAME. Other Precautions:HAZARDOUS PRODUCT RESIDUE MAY REMAIN AFTER THE PRODUCT HAS BEEN REMOVED FROM ITS CONTAINER. DO NOT REUSE "EMPTY" CONTAINER W/O COMMERCIAL CLEANING OR RECONDITIONING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR WHEN AIRBORNE LEVELS MAY EXCEED PEL. Ventilation:LOCAL EXHAUST:PREFERABLE. GENERAL EXHAUST:ACCEPTABLE. Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . AS NECESSARY TO AVOID PROLONGED CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPEC GRAV:0.91-1.25 (H*2O=1). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>245F,>118C Vapor Pres:3.0 Vapor Density:3.9 Spec Gravity:SUPP DATA Evaporation Rate & Reference:25 (ETHER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:VARIOUS COLORS WITH AROMATIC HYDROCARBON ODOR. Percent Volatiles by Volume:63-70 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES KEEP AWAY FROM STRONG OXIDIZERS AND ACIDS. Stability Condition to Avoid:AVOID EXPOSURE TO HEAT, FLAME AND SPARKS. Hazardous Decomposition Products:CARBON MONOXIDE FROM BURNING. Conditions to Avoid Polymerization:AVOID EXPOSURE TO HEAT AND FLAME. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:OXALIC ACID CAGE:1L168 CAGE:1L168 CAGE:1L164 ============= Composition/Information on Ingredients ============= Ingred Name:OXALIC ACID CAS:144-62-7 RTECS #:RO2450000 Fraction by Wt: >99% OSHA PEL:1 MG/M3/2 STEL ACGIH TLV:1 MG/M3/2 STEL; 9192 ===================== Hazards Identification ===================== Effects of Overexposure:EYES,SKIN,INHALE:CAUSES IRRITATION. INGESTION:VERY TOXIC, CORROSIVE POISON. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W H*2O,GET MEDICAL ATTN;SKIN:FLUSH W H*2O;INHALED:GIVE ART RESPIR IF NEEDED,GET MED ATTN;INGESTED:DRINK H*2O, DO NOT INDUCE VOMITING,GET MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Flash Point:SEE ADD DATA Extinguishing Media:H*2O SPRAY, DRY CHEM.,ALCOHOL FOAM, OR CO*2. Unusual Fire/Explosion Hazard:IF MOLTEN, H*2O OR FOAM MAY CAUSE FROTHING. RELEASES FORMIC ACID, CO, & CO*2 AT FIRE TEMPERAT ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE FLAME/IGNITION SOURCES.SM SPILL:SWEEP UP MATL. LG SPILL*SHOVEL MATL INTO CONTAINERS.AVOID DUSTING.NOTE:PRODUCT IS TOXIC. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL-VENTILATED AREA,AWAY FROM ANY ACUTE FIRE HAZARDS.OUTSIDE STORAGE PREFERRED. KEEP AWAY FROM FOODSTUFFS. Other Precautions:NO SMOKING OR EATING WHEN HANDLING PRODUCT. CONTACT W EYES MAY CAUSE CORNEAL DAMAGE. SEE NATIONAL SAFETY COUNCIL DATA SHEET D-406, "OXALIC ACID". ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FUME OR HIGH EFF PARTICULATE RESPIR. Ventilation:PROVIDE ADEQUATE EXHAUST TO MAINTAIN LOW DUST, LOW MIST. Other Protective Equipment:RUBBER ARPON, FACE SHIELD, CLOTHING TO AVOID SKIN CONTACT Supplemental Safety and Health SYNONYMS:ETHANEDIOIC ACID;OXALIC ACID DIHYDRATE. SUBLIMES AT BOILING POINT. ITEM IS CLASS (LARGE CRYSTALS)IN SPECIFICATION. LD50(ORL-RAT)IS 375MG/KG. ================== Physical/Chemical Properties ================== HCC:C3 Boiling Pt:B.P. Text:30SF, 150C Spec Gravity:1.653 Solubility in Water:APPRECIABLE Appearance and Odor:COLORLESS, ODORLESS CRYSTALS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID OXIDANTS,CHLORITES,HYPOCHLORITES,FURFURYL ALC.,SILVER Stability Condition to Avoid:COMBUSTIBLE SOLID AT 215F;DECOMPOSES 300-320F. Hazardous Decomposition Products:FORMIC ACID, CO,CO*2 REPORTED AT FIRE TEMPERATURE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT SEWER. SM & LG SPILL*DEPOSIT IN POSTED TOXIC SUBSTANCE LANDFILL IN COMPLIANCE WITH LOCAL,STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METHYL ALCOHOL 14280, A54RS115 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ALCOHOL; (METHANOL) (SARA 313) (CERCLA) LD50 (ORAL RAT): 5628 MG/KG CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: >99% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM/250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUP DAT: BERYLLIUM DIHYDRIDE, CARBON TETRACHLORIDE + METALS, CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: CYANURIC CHLORIDE, DIETHYL ZINC, NITRIC ACID, & POTASSIUM TERTBUTOXIDE. PLEASE REFER TO THE NFPA FIRE (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: PROTECTION GUIDE FOR ALL SPECIFICS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE DERM. CHRONIC INHAL & INGEST MAY CAUSE EFTS SIMILAR TO (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: THOSE OF ACUTE INHALATION AND INGESTION. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INDUCE VOMIT BY GIVING 1 TEASPOON OF SYRUP OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: EFTS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: MAY BE DELAYED. ETHANOL MAY INHIBIT METABOLISM. ANTIDOTE: NO SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: MOD IRRIT. VAPS MAY CAUSE IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN: MAY CAUSE IRRIT. MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. INGEST: MAY CAUSE IRRIT OF DIGESTIVE TRACT. MAY CAUSE CNS DEPRESS, INCL EXCITEMENT, FOLLOWEDBY HDCH, DIZZ, DROW, & NAUS. ADVANCED STAGES MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: COLLAPSE, UNCON, COMA & POSS DEATH DUE TO RESP FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL: MAY CAUSE RESP TRACT IRRIT, LIVER & KIDNEY DAMAGE, ADVERSE CNS EFTS INCLUDING HDCH, CONVULSIONS, & PO SS DEATH. MAY CAUSE VISUAL IMPAIRMENT &POSS PERM BLINDNESS, & EFTS SIMILAR TO THOSE DESCRIBED FOR INGEST. (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING & SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. (ING 7) ===================== Fire Fighting Measures ===================== Flash Point:53.6F,12.0C Lower Limits:6.00% Upper Limits:31.00% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:CONTRS CAN BUILD-UP PRESS IF EXPOSED TO HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DURING FIRE, IRRITATING & HIGHLY TOX GASES (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERS PROT EQUIP AS INDICATED. SCOOP UP W/NON-SPARKING TOOL, THEN PLACE INTO SUITABLE CONTR FOR DISP. USE WATER SPRAY TO DISPERSE GAS/VAP. REMOVE SOURCES OF IGNIT. ABSORB SPILL USING ABSORB,NON-COMBUST MATL SUCH AS EARTH, SAND/VERMICULITE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENT. EMPTY CONTAINERS RETAIN PROD RESIDUE (LIQUID, &/OR VAPOR), & CAN BE DANGEROUS. DO NOT GET ON SKIN/IN EYES. DO NOT INGEST/INHALE. Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY CONTAINERS TO HEAT, SPARKS/OPEN FLAMES. KEEP AWAY FROM SOURCES OF IGNITION. STORE IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM IN COMPATIBLE SUBSTANCES. FLAMMABLES-AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health EXPLO HAZ: MAY BE GENERATED BY THERMAL DECOMP/COMBUST. FLAM LIQ. CAN RELEASE VAPS THAT FORM EXPLO MIXTS AT TEMPS ABOVE FLASH POINT. MATLS TO AVOID: SODIUM HYPOCHLORITE). ACTIVE METALS (SUCH AS POTASSI UM & MAGNESIUM). SUBSTANCE IS ALSO INCOMPATIBLE W/SPECIFIC CHEMS INCL: ACETYL BROMIDE, ALKYL ALUMINUM SALTS, (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:148F,65C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:96 MMHG Vapor Density:1.1 Spec Gravity:0.791 Evaporation Rate & Reference:5.2 (ETHER=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH SLIGHT ALCOHOL-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUP DAT) Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS, IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA U-SERIES: WASTE NUMBER U154 (IGNITABLE WASTE). THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3410, UNSANDED CERAMIC TILE GROUT-LATEX (SUPP DATA) CAGE:6K348 CAGE:3N569 CAGE:6K348 ============= Composition/Information on Ingredients ============= Ingred Name:PORTLAND CEMENT CAS:65997-15-1 RTECS #:VV8770000 Fraction by Wt: <48% OSHA PEL:50 MPPCF ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: <48% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 3% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:GROUT DUST CAN IRRIT, DIRECT CONT (WET/DRY) CAN CAUSE SERIOUS BURNS. RPTD EXPOS TO DUST MAY CAUSE INFLAMM OF CORNEAS. SKIN:ALKALI CONTENT CAN DRY SKIN & CAUSE CRACKING. RPTD/PRLNG EXPOS MAY RSLT I N BURNS &/OR DERM. HYPERSENSITIVE INDIVIDUALS MAY BE EXTREMELY SUSCEPTIBLE. INHAL:DUST CAN CAUSE IRRIT/(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:INFLAMM OF UPPER RESP SYS. RPTD/PRLNG EXPOS TO DUST CNTNG FREE SILICA MAY RSLT IN SCARRING OF LUNGS W/COUGH & SHORTNESS OF BREATH. DELAYED LUNG INJURY, SILICOSIS, COULD RSLT FROM RPTD BRTHG O F FREE SILICA DUST PARTICLES. INGEST:ALKALI PROPERTIES OF GROUT CAN RSLT IN SERIOUS BURNS TO MOUTH, ESOPHAGUS & (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:IRRIGATE IMMED W/LG AMTS OF CLEAN WATER FOR AT LST 15 MINS. SEEK PROMPT MED ATTN. SKIN:WASH EXPOSED SKIN W/MILD SOAP & WATER. IF IRRIT (CRACKING, REDNESS) PERSISTS, SEEK MED ATTN. INHAL:REMOVE VIC TIM TO FRESH AIR. IF IRRIT/INFLAMM OF UPPER RESP SYS DEVELOPS/PERSISTS, SEEK PROMPT MED ATTN. INGEST:DILUTE BY DRINKING SEVERAL GLASSES OF CLEAN WATER. DO NOT INDUCE VOMIT. GROUT IS ALKALI & (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NOT A FLAMMABLE HAZARD. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP DUST LEVELS TO A MINIMUM. IF AIRBORNE DUST DEVELOPS, TAKE APPROPRIATE STEPS FOR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION. SWEEP OR VACUUM MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP DRY UNTIL USED. KEEP CONTAINERS CLOSED. Other Precautions:THE CEMENT CONTAINED IN THIS PRODUCT PRESENTS A COMBINATION OF SKIN CONTACT & RESPIRATORY HAZARDS. TAKE APPROPRIATE PRECAUTIONS WHEN UTILIZING THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED PARTICAL MASKS OR DUST RESPIRATORS. Ventilation:LOCAL EXHAUST SHOULD BE USED, IF NECESSARY, TO CONTROL AIRBORNE DUST LEVELS. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . BARRIER CREAMS. DISPOSABLE COVERALLS (SUPDAT) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:FORTIFIED (ALL COLORS). EFTS OF OVEREXP:DIGESTIVE TRACT. FIRST AID PROC:MAY CAUSE BURNS. SEEK IMMEDIATE MEDICAL ATTENTION. OTHER PROT EQUIP:MAY BE CONSIDERED TO PROTECT EXPOSE D SKIN & CLOTHING. ================== Physical/Chemical Properties ================== Solubility in Water:INFINITELY DILUTABLE Appearance and Odor:DRY POWDER (VARIOUS COLORS); CHARACTERISTIC CEMENT ODOR. Percent Volatiles by Volume:<1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS SOLID WASTE I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BOSTIC C/A 1008B Kit Part:Y Preparer's Name:D.C. MOLBERG CAGE:EMHAR CAGE:EMHAR ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ACETATE (SARA III) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 28.1% OSHA PEL:400 PPM ACGIH TLV:400 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 27.2% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 17.0% OSHA PEL:15MG/M3 TDUST/5 FUME ACGIH TLV:10MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:50-500MG/MK; LC50:200-2000PPM Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHRONIC: LONG TERM OVEREXPOSURE TO TOLUENE HAS BEEN ASSOCIATE WITH KIDNEY AND LIVER DAMAGE AND BRAIN CELL ABNORMALITY; HAZARDOUS IF INGESTED OR INHALED. Effects of Overexposure:EYE IRRITATION, DIZZINESS, WEAKINESS, HEADACHE, NAUSEA, VOMITING, DIARRHEA, NAR-COSIS. ======================= First Aid Measures ======================= First Aid:SKIN: IMMEDIATELY FLUSH EYES W/PLENTY OFWATER FOR 15 MINUTES. INHAL: REMOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING, MOUTH-TO-MOUTH. IF DIFFICULTY BREATHING GIVE O XYGEN, CALL A PHYSICIAN.INGST: DO NOT INDUCE VOMITING AS THIS MAY CAUSE FURTHER COMPLICATIONS, CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:14 F -10.00 C Lower Limits:1.61 Upper Limits:9.31 Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE, FLOOD WITH WATER Fire Fighting Procedures:USE SELF CONTAINED BREATHING APPARATUS Unusual Fire/Explosion Hazard:USE SELF CONTAINED BREATHING APPARATUS ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP LIQ W/ABSORBENT SUCH AS SAND, EARTH, SWEEPING COMPOUND OR SOME OTHER ABSORBENT. PACKAGE IN STEEL DRUMS WHICH ARE IN GOOD CONDITION. THOROUGLY CLEAN AREA WHERE SPILL OCCURRED ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL LOCATION (60-80 DEG F) AWAY FROM SUNLIGH & ANY SOURCE OF HEAT, ETC. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT BEING USED Other Precautions:USE WITH ADEQUATE VENTILATION, AVOID PROLONGED OR REPEATED BREATHING OF VAPORS. AVOID SKIN CONTACT. USE IN AN AREA FREE FROM FLAME AND SPARKS ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SELF CONTAINED BREATHING APPARATUS Ventilation:LOCAL IS PREFERRED, MECHANICAL IS ACCEPTABLE. Other Protective Equipment:SAFETY SHOWER AND EYE BATH Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:133-245 F Vapor Density:3.11 Spec Gravity:1.10 Evaporation Rate & Reference:3.1 Solubility in Water:2.3 Appearance and Odor:A TN LIQUID WITH A SWEET ODOR Percent Volatiles by Volume:55.7 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, STRONG ACIDS OR ALKALIS Hazardous Decomposition Products:DUE TO THE COMPLEX NATURE. FUMES MAY INCULDE CARBON DIOXIDE CARBON MONOXIDE, WTR VAPOR, OXIDES-NITROGEN, TOXIC FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FED, STATE & LOCAL RE. BE AWARE THAT STATE & LOCAL REG MAY DIFFER WIDELY DEPENDING ON LOCATION & IN MANY CASES BE DIFFERENT FROM FEDERAL RULES. THIS PRODUCT WOULD BE CLAS SIFIED AS A HAZARDOUS WASTE UNDER FED REG.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WAGNER PREMIUM BRAKE FLUID (H-120),HEAVY DU CAGE:94988 CAGE:94988 ============= Composition/Information on Ingredients ============= Ingred Name:POLYPROPYLENE GLYCOL CAS:25322-69-4 Fraction by Wt: 2-5% Other REC Limits:NONE SPECIFIED Ingred Name:DI-/TETRAETHYLENE GLYCOL MIXTURE Fraction by Wt: 15-20% Other REC Limits:NONE SPECIFIED Ingred Name:ALIPHATIC ALCOHOL CAS:70955-04-3 Fraction by Wt: 2-6% Other REC Limits:NONE SPECIFIED Ingred Name:DIETHYLENE GLYCOL MONOBUTYL ETHER CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED Ingred Name:DIETHYLENE GLYCOL MONOBUTYL ETHER CAS:143-22-6 Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED Ingred Name:DIETHYLENE GLYCOL MONOPROPYL ETHER CAS:6881-94-3 Fraction by Wt: 8-10% Other REC Limits:NONE SPECIFIED Ingred Name:DIETHYLENE GLYCOL,MIXED ALKYL ETHERS (C1-C6) Fraction by Wt: 10-20% Other REC Limits:NONE SPECIFIED Ingred Name:TRIETHYLENE GLYCOL, MIXED ALKYL ETHERS (C1-C6) Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED Ingred Name:TRIETHYLENE GLYCOL MONOETHYL ETHER CAS:112-50-5 RTECS #:KK8950000 Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION, TEARING, BURNING. SKIN: MILD IRRITATION. CAN BE ABSORBED IN TOXIC AMOUNTS. OTHER EFFECTS MAY INCLUDE NAUSEA, BURNING OR IRRITATED ESOPHAGUS AND STOMACH, EDEMA, JAUNDICE, ABDOMINAL PA IN, HEADACHE, DIZZINESS, UNCOORDINATION, CONFUSION, UNCONSCIOUSNESS, LIVER AND KIDNEY DAMAGE. INGESTION: MAY BE FATAL. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYES: IRRITATION, TEARING, BURNING. SKIN: IRRITATION, CAN BE ABSORBED IN TOXIC AMOUNTS. OTHER EFFECTS: NAUSEA, BURNING OR IRRITAED ESOPHAGUS AND STOMACH, EDEMA, JAUNDICE, ABDOMINAL PAIN, HEADACHE, DIZ ZINESS, UNCOORDINATION, CONFUSION AND UNCONSCIOUSNESS, LIVER AND KIDNEY DAMAGE. INGESTION MAY BE FATAL. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. GET MEDICAL ATTENTION. INHALATION: MOVE VICTIM TO FRESH AIR. RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION. INGESTION: IF VICTIM IS CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>200F,>93C Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE, HALON. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. USE ABSORBENT MATERIAL AND SWEEP OR PICKUP MATERIAL AND PLACE INTO CLOSED CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A WELL VENTILATED, COOL, DRY AREA AWAY FROM OXIDIZING AGENTS. Other Precautions:NONE KNOWN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF MATERIAL IS AIRBORNE OR BECOMES IRRITATING, USE A NIOSH/OHSA APPROVED RESPIRATOR FOR ORGANIC VAPORS AND MIST IN ACCORDANCE WITH NIOSH/OSHA RESPIRATORY PROTECTION REQUIREMENTS (29CFR 1910.134). Ventilation:GENERAL VENTILATION IS ACCEPTABLE. LOCAL VENTILATION IS PREFERRED. Other Protective Equipment:USE COVERALLS WHERE SPLASH/SRAY IS LIKELY. PROVIDE EYE WASH STATION AND SAFETY SHOWER IN WORK AREA. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:440F,227C Spec Gravity:1.02 pH:9.2 Solubility in Water:SOLUBLE Appearance and Odor:AMBER LIQUID. MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, STRONG ACIDS, AMMONIUM COMPOUNDS, REDUCING AGENTS. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROEN, SODIUM MONOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:"VELPAR" HERBICIDE, M0000054 Preparer's Name:REGISTRATION & REG AFF CAGE:18773 CO. CAGE:9V583 CAGE:18773 ============= Composition/Information on Ingredients ============= Ingred Name:HEXAZINONE CAS:51235-04-2 RTECS #:XY7850000 Fraction by Wt: 90% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:WARNING! MAY IRRITATE EYES,NOSE THROAT & SKIN. ======================= First Aid Measures ======================= First Aid:INHALATION:CONSCIOUS/UNCONSCIOUS ASSIST TO FRESH AIR.GIVE ARTIFICIAL RESPIRATIONIF NECESSARY.SKIN/EYE:FLUSH/WASH WITH WATER.INGESTION:INDUCE VOMITING IMMDEIATELY BY GIVING TWO GLASSES OF WATER & STICK ING FINGER DOWN THROAT.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.CONTACT PHYSICIAN. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:>350C Upper Limits:0.015 G/L Extinguishing Media:WATER SPRAY, CHEMICAL FOAM, DRY CHEMICAL OR CARBON DIOXIDE Fire Fighting Procedures:WESR SELF-CONTAINED BREATHING APPARATUS.USE WATER SPRAY.COOL TANK/CONTAINER W/WATER SPRAY. Unusual Fire/Explosion Hazard:DUST FORMS EXPLOSIVE MIXTURE W/AIR. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE SPILL.PREVENT LIQ FROM ENTERING SEWERS,WTR WAYS OR LOW AREAS.SHOVEL OR SWEEP UP.IF SPILL ARE ISON GROUND NEAR VALUABLE PLANTS OR TREES,REMOVE TOP3 INCHES OF SOIL AFTER INITIAL CLEANUP.USE APPROPR IATE PERSONAL PROTECTIVE EQUIP DURING CLEAN UP. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN WELL VENT AREA.KEEP CNT TIGHTLY CLOSED.DONOT STORE W/OTHER PESTICIDES,FERT,FOOD OR FEED.DO NOT STORE OR CONSUME FOOD,DRINK OR TOBACCO IN * Other Precautions:*HANDLING/STORAGE PRECAUTIONS:AREA WHERE THEY MAY BECOME CONTAMINATED W/THIS MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID DUST GENERATION. Ventilation:USE ONLY WITH ADEQUATE VENTILATION Other Protective Equipment:COVERALL PROTECTIVE CLOTHING. Supplemental Safety and Health PERSONAL PROTECTIVE EQUIP.DO NOT CONSUME FOOD,DRINK, OR TOBACCO IN THE AREAS WHERE THEY MAY BECOME CONTAMINATED W/THIS MATERIAL. ================== Physical/Chemical Properties ================== Vapor Pres:NIL MM HG Spec Gravity:@25C 1.25 Solubility in Water:WATER SOLUBLE POWDER Appearance and Odor:BEIGE POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE W/STRONG ACIDS OR BASES (SLOWLY HYDROLYZES.) Hazardous Decomposition Products:DECOMPOSITION WILL NOT OCCUR. Conditions to Avoid Polymerization:POLYMERIZATION WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:TREATMENT,STORAGE,TRANSPORATION & DISPOSAL MUST BEIN ACCORDANCE W/FEDERAL,STATE & LOCAL REGULATIONS.DO NOT FLUSH TO SURFACE WTR OR SANITARY SEWERS SYSTEM.REMOVE NONUSABLE SOLID MATERIAL &/OR CONTAMINA TED SOIL,FOR DIS IN AN APPR & PERMITTEDLANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACETONITRILE, 99.93+% HPLC GRADE, 270717 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONITRILE LD50: (ORAL, RAT) 2460 MG/KG CAS:75-05-8 RTECS #:AL7700000 OSHA PEL:70 MG/M3;40 PPM ACGIH TLV:67 MG/M3;40 PPM ACGIH STEL:101 MG/M3;60 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE EFFECTS: HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. VAPOR OR MISTS IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION. ACETONITRILE IS M ETABOLIZED IN THE LIVER TO WATER, FORMIC ACID AND HYDROGEN CYANIDE. THE CYANIDE IS FURTHER METABOLIZED TO THIOCYANATE. THE ONSET OF SYMPTOMS IS GENERALLY DELAYED PENDING CONVERSION TO CYANIDE. ADVERSE EFFECTS MAY INCLUDE NAUSEA, VOMITING, DIARRHEA, HEADACHE, DIZZINESS, RASHES AND CYANOSIS. OTHER SYMPTOMS INCLUDE MENTAL EXCITEMENT OR DEPRESSION, DROWSINESS, IMPAIRED PERCEPTION, INCOORDINATION, STUP OR, (EFFECTS OF OVEREXPOSURE) Effects of Overexposure:HEALTH EFFECTS: COMA AND DEATH. TARGET ORGANS: CENTRAL NERVOUS SYSTEM. LIVER, KIDNEYS. BLOOD, LUNGS. ALSO, SEE TOXICOLOGICAL INFORMATION. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH SKIN WITH WATER. EYES: CONTAMINATION OF EYES SHOULD BE TREATED BY IMMEDIATE AND PROLONGED IRRIGATION WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. INHALATION: IF INHALED, REMOVE T O FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. RE MOVE AND WASH CONTAMINATED CLOTHING PROMPTLY. DISCARD CONTAMINATED SHOES. ===================== Fire Fighting Measures ===================== Flash Point:=5.6C, 42.F Autoignition Temp:=522.8C, 973.F Lower Limits:4.4% Upper Limits:16% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHMENT. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK. CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNITION. WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS, CARBON ABSORBENT. TAKE UP AND PLA CE IN CLOSED CONTAINERS. TRANSPORT OUTDOORS. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED. KEEP AWAY FROM HEAT, SPRAKS AND OPEN FLAME. STORE IN A COOL, DRY PLACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . WEAR OTHER PROTECTIVE CLOTHING. Work Hygienic Practices:DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health TOXICOLOGICAL INFO: LD50: 4480 MG/KG 85GMAT -, 16,1982. IVN-MOUSE LD50: 612 MG/KG 85GMAT -, 16,1982. ORAL-CAT LD50: 200 MG/KG ZAARAM 19,225,1969. INHAL-CAT LD50: 18 GM/M3 85GMAT -,16,1982. ORL-RABBIT DL50: 50 MG/KG ZAARAM 19,225,1969. INHAL-RABBIT LC50: 2828 PPM/4H JOCMA7 1,634,1959. SKIN-RABBIT LD50: (OTHER INFO) ================== Physical/Chemical Properties ================== Boiling Pt:>81.C, 177.8F B.P. Text:81-82C Melt/Freeze Pt:=-48.C, -54.4F Vapor Pres:72.8 MM 20C Vapor Density:1.41 Spec Gravity:0.786 Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, BASES, OXIDIZING AGENTS, REDUCING AGENTS, ALKALI METALS. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND NITROGEN OXIDES. HYDROGEN CYANIDE. =================== Toxicological Information=================== Toxicological Information:TO THE BEST OF OUR KNOWLEDGE, CHEM, PHYSICAL & TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. RTECS #: AL7700000 ACETONITRILE. IRRIT DATA - SKIN-RBT 500 MG OPEN MILD UCDS 3/18/1965. T OX DATA - ORAL-RAT LD50: 2460 MG/KG UCDS 3/18/1965. INHAL-RAT LC50: 7551 PPM/8H JOCMA7 1,634,1959. IPR-RAT LD50: 850 MG/KG JOCMA7 1,634,1959. SCU-RAT LD50: 3500 MG/KG 85GMAT -, 16,1982. IVN-RAT LD50: 1680 MG/KG JOCMA7 1,634,1959. PAR-RAT LD50: 1100 MG/KG 85GMAT -, 16,1982. ORL-MOUSE LD50: 269 MG/KG ARTODN 55,47,1984. INHAL-MOUSE LC50: 2693 PPM/1H CTOXAO 18,991,1981. IPR-MOUSE LD50: 175 MG/KG TXAPA 9 59,589,1981. SCU-MOUSE (SUPDAT) ===================== Ecological Information ===================== Ecological:DATA NOT YET AVAILABLE. OTHER INFO: (MUSCULOSKELETAL SYSTEM). NUTRITIONAL & GROSS METABOLIC (CHANGES IN: METABOLIC ACIDOSIS). TUMORIGENIC (EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA). ONLY SELECTED REGISTRY OF TOX EFTS OF CHEM SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFO. FEDERAL REG INFO: 40 PPM (70 MG/M3) CFRGBR 29,1910.1000,1994. OSHA PEL (CONSTRUC): 8H TWA 40 PPM (70 MG/M3) CFRGBR 29,1926.55,1994. OSHA PEL (SHIPYARD): 8H TWA 40 PPM (70 MG/M3) CFRGBR 29, 1915.1000,1993. OSHA PEL (FED CONT): 8H TWA 40 PPM (70 MG/M3) CFRGBR 41,50-204.50,1994. (TRAN SPORT INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGUL ATIONS. =================== MSDS Transport Information =================== Transport Information:CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFO. OEL-ARAB REPUBLIC OF EGYPT: TWA 40 PPM (70 MG/M3); SKIN JAN 1993. OEL-AUSTRALIA: TWA 40 PPM (70 MG/M3); STEL 60 PPM; SKIN JAN 1993. OEL-AUSTRI A: TWA 40 PPM (70 MG/M3) JAN 1993. OEL-BELGIUM: TWA 40 PPM (67 MG/M3); STEL 60 PPM (101 MG/M3); SKIN JAN 1993. OEL-DENMARK: TWA 40 PPM (70 MG/M3); STEL 60 PPM (105 MG/M3) JAN 1993. OEL-FINLAND: TWA 40 PPM (70 MG/M3); STEL 60 PPM (105 MG/M3) JAN 1993. OEL-FRANCE: TWA 40 PPM (70 MG/M3) JAN 1993. OEL-GERMANY: TWA 40 PPM (70 MG/M3) JAN 1993. OEL-HUNGARY: TWA 50 MG/M3; STEL 100 MG/M3; SKIN JAN 1993. OE L-THE NETHERLANDS: (SARA REG INFO) ===================== Regulatory Information ===================== SARA Title III Information:THIS PROD IS SUBJECT TO SARA SECTION 313 REPORTING REQS. TRANSPORT INFO: TWA 40 PPM (70 MG/M3) JAN 1993. OEL-THE PHILIPPINES: TWA 40 PPM (70 MG/M3) JAN 1993. OEL-RUSSIA: STEL 10 MG/M3 JAN 1993. OEL-SW ITZERLAND: TWA 40 PPM (70 MG/M3); STEL 80 PPM; SKIN JAN 1993. OEL-TURKEY: TWA 40 PPM (70 MG/M3) JAN 1993. OEL-UNITED KINGDOM: TWA 40 PPM (70 MG/M3); STEL 60 PPM JAN 1993. OEL IN BULGARIA, COLOMBIA, JO RDAN, KOREA CHECK ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV. NIOSH REL TO ACETONITRILE-AIR: 10H TWA 20 PPM NIOSH DHHS #92-100,1992. NOHS 1974: HZD 02900; NIS 9; TNF 302; NOS 25 ; TNE 28201. (STATE REG INFO) Federal Regulatory Information:EUROPEAN INFO - EC INDEX #: 608-001-00-3. HIGHLY FLAMMABLE. TOXIC. R 11 IGHTLY FLAMMABLE. R 23/24/25 TOXIC BY INHAL, IN CONTACT W/SKIN & IF SWALLOWED. S 16 KEEP AWAY FROM SOURCES OF IGNIT - NO SMOKING . S 27 TAKE OFF IMMED ALL CONTAM CLTHG. S 45 IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW LABEL WHERE POSS). REVIEWS, STDS & REGS - OEL=MAK. ACGIH TLV-NOT CLASSIFIABLE AS HUM AN CARCIN DTLVS TLV/BEI, 1997. ACGIH TLV-STEL 101 MG/M3 (60 PPM) DTLVS TLV/BEI, 1997. ACGIH TLV-TWA 67 MG/M3 (40 PPM) DTLVS TLV/BEI, 1997. MSHA STD-AIR: TWA 40 PPM (70 MG/M3) DTLVS 3,3,1971. OSHA PEL (GEN INDU): 8H TWA (ECOLOGICAL INFO) State Regulatory Information:N/P. SARA REG INFO: NOES 1983; HZD 02900; NIS 19; TNF 1172; NOS 27; TNE 31341; TFE 7957. EPA TSCA SECTION 8(B) CHEMICAL INVENTORY. EPA TSCA 8(A) PRELIMINARY ASSESSMENT INFO, FINAL RULE FEREAC 47, 2699 2, 82. EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES ON EPA IRIS DATABASE. EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, DECEMBER 1998. NIOSH ANALYTICAL METHOD, 1994: ACETONITRILE, 1606. NTP CARCINOGENESIS STUDIES (INHAL); NO EVIDENCE: MOUSE NTPTR NTP-TR-447,96. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:H-D MOTORCYCLE OIL SAE 20W50, H-D 99826 SP Preparer's Name:JOANNE HOUCK CAGE:78628 CAGE:78628 CAGE:8X531 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETRO DISTILS, SOLVENT-REFINED (SEVERE) HEAVY PARAFFINIC; (SEVERELY SOLV REFINED HEAVY PARAFFINC PETRO OIL) CAS:64741-88-4 RTECS #:PY8040501 Fraction by Wt: 60-75% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:STYRENE COPOLYMERS; (STYRENE/ETHYLENE-PROPYLENE COPOLYMER (HYDROGENATED)) Fraction by Wt: 0-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYISOBUTENYL SUCCINIMIDE/AMIDE CAS:67762-80-5 Fraction by Wt: 2-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MAGNESIUM SULFONATE; (MAGNESIUM PETROLEUM SULFONATE) CAS:61789-87-5 Fraction by Wt: 0-2% OSHA PEL:5 MG/M3, C (MG) ACGIH TLV:10 MG/M3 (MG) Ingred Name:PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC SALTS (2:1); (ZINC DIALKYL DITHIOPHOSPHATE) (ZDDP) CAS:68649-42-3 Fraction by Wt: 1.35% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CALCIUM PHENATE CAS:72162-32-4 Fraction by Wt: 2-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:2-PROPENOIC ACID, 2-METHYL-, EICOSYL ESTER, POLYMER; (ACRYLIC COPOLYMER) CAS:68171-46-0 Fraction by Wt: 0-1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:SEEN IN RATS. SUPPLIER BELIEVES THERE IS NO RISK OF HUMAN MALE REPRO IMPAIRMENT FROM EXPOS. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:DISPOSAL SERVICE. RTECS #:9999999ZZ Ingred Name:RESP PROT:FULL-FACE AIR PURIFYING RESP WITH DUST/MIST FILTERS/HEPA FILTER CARTRIDGES IS ACCEPT TO 50 TIMES EXPOS(ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:LIM. PROT BY AIR PURIFYING RESPS IS LTD. USE POS PRESS-DEMAND FULL-FACE SUPPLIED AIR RESP/SCBA FOR EXPOS (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:>50X EXPOS LIM. IF EXPOS IS ABOVE IDLH (IMMED DANGEROUS TO LIFE & HLTH) OR THERE IS POSSIBILITY OF AN (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:UNCONTROLLED RELS/EXPOS LEVELS ARE UNKNOWN THEN USE POS PRESS-DEMAND FULL-FACE SUPPLIED AIR RESP W/ESCAPE(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:BOTTLE OR SCBA. RTECS #:9999999ZZ RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:RESIST CLTHG. FOLLOWING MATLS ARE ACCEPT AS PROT CLTHG MATLS: POLYVINYL ALCOHOL (PVA); (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:POLYVINYL CHLORIDE (PVC); NEOPRENE; NITRILE; VITON; POLYURETHANE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL) >15 G/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NOT EXPECTED TO CAUSE SEV EMER HAZ. INHAL:NO EFTS EXPECTED. LOW ACUTE TOX. SKIN:PRACTICALLY NON-TOXIC IF ABSORBED. MAY CAUSE MILD TO MOD IRRIT W/PRLNG OR RPTD CONT. EYE:CONT MAY CAUSE MILD IRRIT. INGE ST:PRACTICALLY NON-TOXIC. CAUT! PRLNG/RPTD CONT W/USED MOTOR OIL MAY BE HARMFUL TO SKIN & COULD CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:SKIN CANCER. TOX INFO:MAGNESIUM PETRO SULFONATE:IN ANIMAL STUDIES, OTHER METAL SULFONATES CAUSED SKIN IRRIT & ALLERGIC RXNS; NO EVID IN HUMANS OF SIMILAR EFTS. ZINC DIALKYL DITHIOPHOSPHATE:IN HAL:TOX HYDROGEN SULFIDE IS GENERATED WHEN HEATED >155F. THIS CAN CAUSE RESP COLLAPSE, COMA & DEATH. SKIN:PRLNG/(SUPDAT) Medical Cond Aggravated by Exposure:SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE PERSON TO FRESH AIR. SKIN:WASH W/SOAP & WATER UNTIL NO ODOR REMAINS. WASH CLOTHING BEFORE REUSE. EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, OBTAIN MED ASSISTANCE. I NGEST:INDUCTION OF VOMITING NOT REQUIRED. OBTAIN EMERGENCY MEDICAL ATTENTION. SMALL AMOUNTS WHICH ACCIDENTALLY ENTER MOUTH SHOULD BE RINSED OUT UNTIL TASTE OF IT IS GONE. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>400F,>204C Extinguishing Media:WATER SPRAY, REGULAR FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CAN BE MADE TO BURN (FLASH POINT GREATER THAN 200F). ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL. ADVISE EPA; STATE AGENCY IF REQUIRED. ABSORB ON INERT MATERIAL SHOVEL, SWEEP OR VACUUM SPILL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NFPA CLASS IIIB STORAGE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CONC-IN-AIR DETERMINES PROT NEEDED. USE ONLY NIOSH APPRVD RESP PROT. RESP PROT USUALLY NOT NEEDED UNLESS PROD IS HEATED/MISTED. HALF-MASK AIR PURIFYING RESP W/DUST/MIST FILTERS/HEPA FILTER CARTRIDGES IS ACCEPT TO 10 TIMES EXPOS LIM.(ING 10) Ventilation:VENTILATE AS NEEDED TO COMPLY W/EXPOSURE LIMIT. GENERAL DILUTION VENTILATION ACCEPTABLE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . IF CONT IS UNAVOIDABLE, WEAR CHEM (ING 16) Work Hygienic Practices:WASH THOROUGHTLY AFTER HANDLING. PROMPTLY WASH AFFECTED AREA W/SOAP & WATER. LAUNDER SOILED CLOTHES. Supplemental Safety and Health VP:<0.0001 @ 20C. EVAP RATE:1000X SLOWER (ETHYL ETHER=1). EFTS OF OVEREXP:RPTD CONT MAY CAUSE MOD IRRIT, REDNESS, DRYING, CRACKING, DERM. EYES:IRRIT. INGEST:HARMFUL IF SWALLOWED. CALCIUM PHENATE:SKIN: IRRIT. AFTER DAILY HIGH DOSE APPLICATIONS IN MALE RABBITS, TESTICLES FAILED TO MATURE NORMALLY. THIS EFT WAS NOT (ING 8) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:WIDE RANGE Vapor Pres:SUPP DATA Spec Gravity:0.88 (H*2O=1) Evaporation Rate & Reference:SUPP DATA Solubility in Water:NIL Appearance and Odor:DARK FLUID; SLIGHT ODOR. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON MONOXIDE & ASPHYXIANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW FEDERAL, STATE & LOCAL REGULATIONS. NOT A RCRA HAZARDOUS WASTE IF UNCONTAMINATED. IF "USED", RCRA CRITERIA (IGNITABILITY, REACTIVITY, CORROSIVITY, TOX CHARACTS) MUST BE DETERMINED. DO NOT FLUSH TO DRAIN/STORM SEWER. CONTRACT TO AUTH(ING 9)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CHROMIC ACID Preparer's Name:C.A.EISENHART CAGE:87664 CAGE:60777 CAGE:87664 ============= Composition/Information on Ingredients ============= Ingred Name:CHROMIUM (VI) OXIDE CAS:1333-82-0 RTECS #:GB6650000 Fraction by Wt: >99% OSHA PEL:C, 0.1 MG/M3 (CRO3) ACGIH TLV:0.05 MG/M3(CR); 8990 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NIOSH:.025MG(CR4)/M3;10HR TWA=.05MG Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE-EYE:DUST IS EXTREMELY CORROSIVE;CAN CAUSE SEVERE DAMAGE.SKIN:IRRITATION.INHAL:IRRITATION OF THE NASAL SEPTUM & RESPIRATORY TRACT.INGESTION:CAN CAUSE EXTREME TISSUE DESTRUCTION,KIDNEY FAILURE & D EATH.CHRONIC-EYE:CONJUNCTIVITIS.SKIN:ESPEC. BROKEN,MAY CAUSE "CHROME SORE". Explanation of Carcinogenicity:CR (VI) COMPOUNDS ARE CONSIDERED SUSPECT CARCINOGENS. Effects of Overexposure:EYES:CORROSIVE,SEVERE DAMAGE,PERMANENT INJURY,BLINDNESS;SKIN:BURNS,IRRITATION,CHROME SORES,SKIN SENSITIZATION, KIDNEY FAIL SEPTUM & RESPIRATORY TRACT,ASTHMA-LIKE SYMPTOMS;INGESTION: TISSUE DISTRUCTION ,SEVERE INJURY,DELAYED TOXIC EFFECTS,KIDNEY OR LIVER FAILURE. Medical Cond Aggravated by Exposure:CONTACT WITH BROKEN SKIN CAN CAUSE "CHROME SORES".SKIN CAN BECOME SENSITIZED AND MASSIVE OVER-EXPOSURE TO SOLUTIONS CAN ABSORB HARMFUL AMOUNTS, LEADING TO KIDNEY FAILURE AND DEATH. ======================= First Aid Measures ======================= First Aid:EYE:IMMEDIATELY FLUSH WITH RUNNING WATER FOR 15 MIN.GET MEDICAL ATTENTION.SKIN:IMMEDIATELY FLUSH WITH RUNNING WATER FOR 15 MIN.DESTROY CONTAMINATED SHOES.CALL A DOCTOR.INHALATION:REMOVE TO FRESH AIR.G IVE CPR IF NEEDED.CALL A PHYSICIAN.INGESTION:DON'T INDUCE VOMITING.IF CONSCIOUS,GIVE LOTS OF WATER/MILK.GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL OR CO2. DO NOT USE WATER.(UNDER CERTAIN CONDITIONS CONTACT WITH WATER CAN CAUSE STEAM EXPLOSIONS). Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:PRODUCT MAY CAUSE FIRE IF IT DRYS ON CLOTHING,WOOD,COMBUSTIBLES.CONTACT WITH FLAMMABLE MATERIALS MAY CAUSE IMMEDIATE FIRE OR EXPLOSION,ESPECIALLY IF HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR RESPIRATOR EQUIPPED WITH PARTICULATE WASTE CONTAINERS. Neutralizing Agent:20% SODIUM BICARBONATE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED PLACE AWAY FROM OTHER CHEMICALS & SOURCES OF CONTAMINATION.KEEP CONTAINER TIGHTLY CLOSED.DO NOT STORE IN HUMID PLACE Other Precautions:DO NOT CUT,GRIND,WELD OR DRILL NEAR CONTAINER.TREAT EMPTY CONTAINERS AS IF THEY WERE FULL.FOLLOW HAZARD WARNINGS. DO NOT GET IN EYES,SKIN OR CLOTHING.DO NOT BREATHE THE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED CARTRIDGE RESPIRATOR FOR ACID MISTS. Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING DUST EMISSIONS AT THE POINT OF USE BELOW THE PEL. Other Protective Equipment:ACID RESISTANT SLICKER SUIT WITH PVC APRON & BOOTS. EYEWASH STATION & SAFETY SHOWER. Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING IMMEDIATELY.DO NOT DAILY. Supplemental Safety and Health NOTE TO PHYSICIAN:MASSIVE OVEREXPOSURE TO SOLUTIONS COULD LEAD TO KIDNEY FAILURE AND DEATH.EARLY RENAL DIALYSIS IS RECOMMENDED.ONE GRAM ASCORBIC ACID (ORAL/IV) FOLLOWED BY 100 MG T.I.D. FOR 14 DAYS.SK IN ULCERS MAY BE TREATED BY REMOVAL FROMEXPOSURE,DAILY CLEANSING & DEBRIDEMENT, & ANTIBIOTIC CREAM. ================== Physical/Chemical Properties ================== HCC:D3 NRC/State Lic Num:NONE Melt/Freeze Pt:M.P/F.P Text:387F (197C) Spec Gravity:2.7 Solubility in Water:62.5% Appearance and Odor:DARK RED FLAKES, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS,COMBUSTIBLE MATERIALS SUCH AS OILS OR GREASES,WATER AND ORGANICS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:CHROMIC OXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LEXOL-NF NEATSFOOT FORMULA Preparer's Name:HERNDON JENKINS, PH.D. CAGE:2B632 CAGE:2B632 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:NONE. ACUTE AND CHRONIC- NONE. Explanation of Carcinogenicity:NONE Effects of Overexposure:NONE Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:NONE REQUIRED. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:AS WITH ANY FIRE, WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CONTAINER MAY RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:MAY BE DISCHARGED TO PUBLIC SEWAGE SYSTEM WITH LARGE AMOUNT OF WATER, IF PERMITTED. MAY BE ABSORBED AND SENT TO SANITARY LANDFILL. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID HEAT ABOVE 140F. AVOID PRESSURE THAT WOULD DAMAGE SHIPPING CASE. Other Precautions:WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND BEFORE EATING, DRINKING, SMOKING. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:NONE Other Protective Equipment:EYE WASH STATION RECOMMENDED Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:35 Vapor Density: 1 Spec Gravity:1 Evaporation Rate & Reference:1 (N-BUTYL ACETATE=1) Solubility in Water:MIXES Appearance and Odor:TRANSLUCENT YELLOWISH TO BROWNISH LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:HEAT Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:ZINC DUST CAGE:HO925 CAGE:HO925 CAGE:06634 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC (SARA III) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 100% OSHA PEL:10 MG ZNO/M3 ACGIH TLV:10 MG ZNO/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHALATION OF EXCESSIVE QUANTITIES OF DUST, PARTICULARLY IF FRESHLY FORMED ZINC OXIDE FUME IS PRESENT WILL CAUSE "METAL FUME FEVER". SYMPTOMS INCLUDE HEADACHE, FEVER, CHILLS, MUSCLE ACHES, NAUSE A, VOMITING, WEAKNESS & TIREDNESS. ATTACK MAY LAST 6-24 HOURS. NO LONG-TERM EFFECTS KNOWN. (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:EYE:CONTACT WILL RESULT IN IRRITATION. Medical Cond Aggravated by Exposure:IF YOU HAVE A CONDITION THAT COULD BE AGGRAVATED BY EXPOSURE TO DUST OR ORGANIC VAPORS, SEE MD PRIOR TO USE. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER FOR AT LEAST 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & CLEAN BEFORE REUSE. INHAL:REMOVE TO FRESH AIR. PROVIDE OXYGEN IF BREATHING IS DIFFICULT. USE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MD. INGEST:DO NOT INDUCE VOMITING. ALWAYS GET MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL. DO NOT USE WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . EVACUATE HAZ AREA. COVER ALL OPEN ZINC DUST CNTNRS. DO NOT SPREAD OUT MATL. WATER WILL REACT (SUPP DATA) Unusual Fire/Explosion Hazard:HYDROGEN GAS EVOLVES WHEN IN CONTACT W/MOISTURE, ALKALIS OR ACIDS. MAY EXPLODE ON CNTCT W/OXIDIZING AGENTS SUCH AS SULFUR & OXYGEN OR OTHERS. ================== Accidental Release Measures ================== Spill Release Procedures:USE DRY CLEANUP METHODS THAT DO NOT DISPERSE DUST INTO AIR. AVOID BREATHING DUST. TAKE UP MATERIAL & SEAL TIGHTLY FOR PROPER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT & WATER & STRONG OXIDIZING AGENTS. KEEP CNTNRS CLOSED. STORE IN COOL, DRY PLACE W/ADEQUATE VENTILATION. Other Precautions:DO NOT WELD, HEAT OR DRILL ON FULL OR EMPTY CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED AIR-PURIFYING RESPIRATOR WHEN NECESSARY. Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED. USE ONLY W/VENTILATION TO KEEP LEVELS BELOW EXPOSURE GUIDELINES. Other Protective Equipment:WEAR IMPERVIOUS CLOTHING. Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health FIRE FIGHT PROC:W/HOT ZINC DUST TO FORM HYDROGEN WHICH IS AN EXPLOSIVE GAS. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:1665F,907C Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT W/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:WATER AND MOISTURE. Hazardous Decomposition Products:HYDROGEN GAS W/WATER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:139 6498 KODAK PROF CLEAN PRINT FOUNTAIN SOLN(ORIG)MAKES 1G CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 90-95% Other REC Limits:NONE RECOMMENDED Ingred Name:ALUMINUM NITRATE CAS:13473-90-0 RTECS #:BD1040000 Fraction by Wt: 2% Other REC Limits:NONE RECOMMENDED Ingred Name:POLYCRYLAMIDE (ACRYLAMIDE, POLYMERS) CAS:9003-05-8 RTECS #:AS3700000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:CITRIC ACID DISODIUM SALT CAS:144-33-2 RTECS #:GE7500000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:DERMAL LD-50:>20ML/KG.CTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES:NO SPECIFIC HAZARD KNOWN.MAY CAUSE TRANSIENT IRRITATION. SKIN:LOW HAZARD FOR RECOMMENDED HNDLG. INGEST:EXPECTED TO BE LOW INGESTION HAZ ARD. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY CLASSIFICATION:IARC/ACGIH/NTP/OSHA:NONE. Effects of Overexposure:TRANSIENT EYE IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:IF SYMPTOMATIC MOVE TO FRESH AIR.TREAT SYMPTOMATICALLY.GET MED ATTN IF SYMPTOMS PERSIST.EYES:ANY MATL THAT CONTACTS EYE SHOULD BE WASHED OUT IMMED W/WATER.SYMPOTMS OCCUR GET MED ATTN.SKIN:WASH W /SOAP & WATER.GET MED ATTN IF SYMPTOMS OCCUR.INGEST:DRINK 1-2 GLASSES OF WATER.SEEK MED ATTN.NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Autoignition Temp:Autoignition Temp Text:NP Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:NONE(NON-COMBUSTIBLE) Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE ABSORB W/VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT W/EYES & PROL/REP CONTACT W/SKIN.USE W/ADEQU VENTI.KEEP CONTAINER CLOSED. Other Precautions:STRONGLY ACIDIC AQU SOLN.PROPERTIES:LOW BIOCHEM OXY DEMAND,LITTLE POT TO CAUSE OXY DEPLETION IN AQY SYS,HI POT TO AFFECT SOME AQU ORGANISMS,LOW POT TO AFFECT 2ND WASTE TREAT MICROBIAL METABOLISM,LOW P OT TO BIOCONCEN.AFT DIL W/LG AMTS OF(SU) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYEBATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFT HNDLG.GOOD INDUCSTRIAL HYGIENE PRAC TO MIN EYE/SKIN CONTACT. Supplemental Safety and Health OTHER PRECAUT:WATER/2ND WASTE TREAT MATL NOT EXPECTED TO CAUSE ADVERSE ENVIRO EFFECTS. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.04 pH:2.5 Viscosity:NP Evaporation Rate & Reference:NP Solubility in Water:COMPLETE Appearance and Odor:LIQUID, AMBER COLOR, ODORLESS Percent Volatiles by Volume:90 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE W/COMMON MATERIALS & CONTAMINANTS W/WHICH MATL MAY REASONABLY COME INTO CONTACT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE (NON-COMBUSTIBLE) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREATMENT/DISPOSAL MAY BE SUBJECT TO NATIONAL/STATE/LOCAL LAWS. FLUSH TO SEWER W/LG AMTS OF WATER. CHEM SUBJ TO REPORTING REQMTS OF SEC 313 TITLE III SARA/40CFR372:NITRATE COMPOUNDS (WATER D ISSOCIABLE).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MOORCRAFT INTERIOR & EXTERIOR BLOCK FILLER, 173 CAGE:09585 CAGE:09585 CAGE:91950 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <3.4% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICA GEL; (SILICA, AMORPHOUS) CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: <3.6% OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:SILICATE, MICA; (SILICA, MICA) CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: <7.5% OSHA PEL:20 MPPCF ACGIH TLV:3 MG/M3 RDUST Ingred Name:CLAY (KAOLIN); (HYDROUS ALUM SILICATES) CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: <10.5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE) CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: <25.9% OSHA PEL:10 MG/M3 (MFR) ACGIH TLV:10 MG/M3 (MFR) Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA, CRYSTALLINE) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <0.3% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: IRRITATION OF THE RESPIRATORY TRACT. SKIN/EYES: PRIMARY IRRITATION. INGESTION OF LARGE AMOUNTS COULD CAUSE SERIOUS INJURY. CHRONIC: SANDING DUST INHALATION MAY CAUSE LUNG DAMAGE. Explanation of Carcinogenicity:CRYSTALLINE, SILICA-QUARTZ: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 341, 1987: GROUP 2A. NTP 7TH ANNUAL (SUP DAT) Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE EXPECTED WHEN USED IN ACCORDANCE WITH SAFE HANDLING AND USE INFORMATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL HELP FOR ANY BREATHING DIFFICULTY. EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. CALL MD. SKIN: WASH WITH SOAP AND WATER. INGESTION: DRINK 1 O R 2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>250F,>121C Extinguishing Media:USE FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . COOL EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. TOXIC GASES MAY FORM WHEN PRODUCT BURNS. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH WITH WATER. ABSORB WITH SAWDUST OR RAGS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT THROW OR DROP CONTAINERS. Other Precautions:AVOID CONTACT WITH EYES AND PROLONGED CONTACT WITH SKIN OR BREATHING OF SPRAY MIST OR SANDING DUST. CLOSE CONTAINER AFTER EACH USE. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR SPECIFIED FOR PROTECTION AGAINST PAINT SPRAY MIST AND SANDING DUST IN RESTRICTED OR CONFINED AREAS. Ventilation:ADEQUATE TO MAINTAIN WORKING ATMOSPHERE BELOW TLV AND LEL. MECHANICAL EXHAUST MAY BE REQUIRED IN CONFINED AREAS. Other Protective Equipment:CLOTHING ADEQUATE TO PROTECT SKIN. EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:REMOVE AND WASH CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM. Supplemental Safety and Health EXPLAN OF CARCIN: REPORT ON CARCINOGENS, 1994: ANTICIPATED BO BE CARCINOGEN. ================== Physical/Chemical Properties ================== Vapor Density:HVR/AIR Spec Gravity:1.51 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER Percent Volatiles by Volume:59.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:ELEVATED TEMPERATURES. Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON DIOXIDE AND CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONVENTIONAL PROCEDURES IN COMPLIANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE SEALED CONTAINERS.
1
eyes_protection_mandatory
======================================================= Product ID: SAFE-FR 595-1 Cage: UVTEC ======================================================= Contractor Summary ======================================================= Cage: UVTEC ======================================================= Ingredients ======================================================= % Wt: >0.1 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: NONE EXPECTED. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, CONTACT A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, CONTACT PHYSICIAN. INHAL: REMOVE TO FRESH AIR. IF A DVERSE CONDITIONS PERSIST, CONTACT PHYSICIAN. INGEST: EXPOSURE UNLIKELY, HOWEVER, IF IT OCCURS CONTACT PHYSICIAN IMMED. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SWEEP UP AND RETURN TO CONTAINER, OR DISCARD IF CONTAMINATED. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: SOLID WASTE DISPOSAL I/A/W FEDERAL, STATE, AND LOCAL REGULATIONS. Handling And Storage Precautions: NONE. NORMAL BULK STORAGE AND HANDLING OF PLASTICS. DO NOT EXPOSE MATERIALS TO EXCESSIVE HEAT, COLD/MOISTURE. Other Precautions: IF IRRITATION OCCURS, CONSULT OSHA STANDARD(S) FOR ZINC. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, FOAM/DRY CHEMICAL. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: PARTICULATE MASK: IF DUSTING OCCURS, USE NIOSH/MSHA APPROVED CHEMICAL RESPIRATOR. Ventilation: LOCAL EXHAUST. SPECIAL VENT REQUIREMENTS: NONE, HOWEVER, DUST CREATION SHOULD BE MINIMIZED. Other Protective Equipment: NONE. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 Spec Gravity: 1.4(H*2O=1) Solubility in Water: ESSENTIALLY SOLUBLE Appearance and Odor: UNDERWATER, DICED/STRAND CUT PELLETS; ESSENTIALLY NO ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE KNOWN. Materials To Avoid: NONE KNOWN. Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, MAY BE EVOLVED ABOVE 300C. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SAFE-FR 595-1 Cage: UVTEC Company Name: UVTEC INC Street: 1121 108TH ST Zipcode: 76011-3110 Label Required IND: Y Date Of Label Review: 10/12/1993 Status Code: C Label Date: 10/12/1993 Origination Code: G Skin Protection IND: YES Signal Word: NONE Respiratory Protection IND: YES Health Hazard: None Contact Hazard: None Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: NONE SPECIFIED BY MANUFACTURER. CHRONIC: NONE SPECIFIED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:170 COBALT BLUE LIQUITEX ACRYLIC ARTIST COLOR CAGE:BINNE CAGE:BINNE ============= Composition/Information on Ingredients ============= Ingred Name:COBALT ALUMINATE BLUE *94-3* CAS:1345-16-0 OSHA PEL:0.005 MG/CUM (DUST) ACGIH TLV:0.1 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: INERT, NUISANCE PARTICULATE DUST. SKIN: NON-TOXIC. INHALATION: INERT, NUISANCE PARTICULATE DUST. INGESTION: MAY BE IRRITATING TO GI TRACT. CHRONIC: REPEATED OVEREXPOSURE TO THIS PIGMENT DUST MAY CAUSE EYE, SKIN & RESPIRATORY TRACT IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: INERT, NUISANCE PARTICULATE DUST. SKIN: NON-TOXIC. INHALATION: INERT, NUISANCE PARTICULATE DUST. INGESTION: MAY BE IRRITATING TO GI TRACT. CHRONIC: REPEATED OVEREXPOSURE TO THIS PIGMENT DUST MAY CAUSE EYE, SKIN & RESPIRATORY TRACT IRRITATION. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN/EYE/RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/WATER FOR 15 MINS. SKIN: WIPE EXCESS & FLUSH W/WATER USING SOAP IF AVAILABLE. INHALATION: REMOVE TO FRESH AIR & TREAT SYMPTOMATICALLY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:>212F Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL, CO2 Unusual Fire/Explosion Hazard:PRODUCT WILL SPLATTER & BOIL >212F. PRODUCT WHEN DRY MAY DECOMPOSE & IGNITE >400F. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP RESIDUE W/ABSORBENT, PLACE IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL. FLUSH AREA W/WATER TO REMOVE TRACE RESIDUE. SMALL: TAKE UP W/ABSORBENT MATERIAL & PLACE IN NON-LEAKING CONTAINERS, SEA L TIGHTLY FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Other Precautions:AVOID CONTACT W/EYES. DON'T INHALE FROM AIR BRUSH/SANDING OPERATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH CERTIFIED MASK FOR DUST & MISTS. Ventilation:REQUIRED TO CONTROL VAPOR CONCENTRATIONS. AIR BRUSHING: WINDOW EXHAUST FANS. Other Protective Equipment:EYE WASH FOUNTAINS & SAFETY SHOWERS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Decomp Temp:Decomp Text:>400F Vapor Density:>1 Spec Gravity:1.34 Evaporation Rate & Reference:(ETHER = 1): <1 Percent Volatiles by Volume:40-60 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:TEMPS >212F Hazardous Decomposition Products:CO2, CO & UNIDENTIFIED ORGANIC COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE, LOCAL & EPA REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:42-31 SUPERFLAT CAGE:34483 CAGE:34483 CAGE:60806 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: <0.5% Other REC Limits:200 PPM OSHA PEL:260 MG/CUM ACGIH TLV:262 MG/CUM (SKIN) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:NAPHTHA PETROLEUM, HEAVY ALKYLATE C9-C12 BOILING PT 302-428F *93-4* CAS:64741-65-7 Fraction by Wt: <5% Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; PETROLEUM DISTILLATE, HYDROTREATED ,(MINERAL SPIRITS) CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 20% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: PROLONGED/REPEATED CONTACT MAY CAUSE IRRITATION/DERMATITIS. INHALATION: MAY BE IRRITATING TO THE MUCOUS MEMBRANES. OVEREXPOSURE TO VAPORS CAN CAUSE CNS DEPRESSION. ASPIRATION O F HYDROCARBON LIQUID INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS & PULMONARY EDEMA/HEMORRHAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DEFATTING, DRYING, HEADACHE, DIZZINESS, NAUSEA, LOSS OF CONSCIOUSNESS, LOSS OF COORDINATION ======================= First Aid Measures ======================= First Aid:EYES: WASH W/FRESH WATER FOR AT LEAST 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: MOVE PERSON TO FRESH AIR. IF BREATHING HAS STOPPED, APPLY CPR. INGESTION: DON'T INDUCE VOMITING. ASPIRA TION HAZARD. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F Lower Limits:1 Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:USE AIR SUPPLIED RESCUE EQUIPMENT FOR ENCLOSED AREAS. AVOID SPREADING BURNING LIQUID W/WATER USED FOR COOLING PURPOSES. Unusual Fire/Explosion Hazard:LIQUID EVAPORATES & FORMS INVISIBLE VAPORS WHICH SPREAD EASILY & CAN BE IGNITED BY MANY IGNITION SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES. VENTILATE CONFINED SPACES. KEEP PEOPLE AWAY. ADD ABSORBENT SAND, EARTH/SAWDUST & RECOVER INTO A SUITABLE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. DON'T HANDLE/STORE NEAR HEAT, FLAMES, SPARKS & STRONG OXIDANTS. STORE IN A COOL, WELL-VENTILATED AREA. Other Precautions:AVOID BREATHING VAPORS. ROTATE STOCK, USE OLDER MATERIAL FIRST. INSPECT FOR LEAKY CONTAINER. PRODUCT WILL DISSOLVE & SOFTEN SOME RUBBER & PLASTICS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROVED ORGANIC VAPOR RESPIRATOR/AN AIR SUPPLYING RESPIRATOR UNLESS VENTILATION IS ADEQUATE TO KEEP AIRBORNE CONCENTRATIONS BELOW EXPOSURE STANDARDS. OTHER SPECIAL PRECAUTIONS SUCH AS ENVIRONMEN TAL CONTAINMENT DEVICES MAY BE REQUIRED. Ventilation:GENERAL MECHANICAL MAY BE SUFFICIENT. IF INADEQUATE, USE LOCAL EXHAUST. Other Protective Equipment:FACESHIELDS, IMPERMEABLE APRONS, HEAD CAPS, EYE WASHES & SAFETY SHOWERS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:314-387F Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:44 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS, RUBBER & PLASTICS Stability Condition to Avoid:DIRECT HEATING, HIGH TEMPERATURE, POORLY VENTED HOT AREAS, FLAMES, SPARKS, TEMP >85F & OTHER IGNTION SOURCES Hazardous Decomposition Products:CO2, CO, ACROLEIN, SMOKE & ACRID FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. DON'T DUMP INTO LAKES, STREAMS/OTHER WATER SUPPLY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WATERBORNE ACRYLIC SANDING SEALER, 64-11 Preparer's Name:LINDA OVERTON CAGE:33200 CAGE:33200 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTOXYETHANOL. (NUISANCE DUST PELS: ACGIH TLV/TWA [TOTAL DUST]: 10 MG/CU. M. OSHA PEL [TOTAL DUST]: 15 MG/CU. M.; [RESPIRABLE DUST] 5 MG/CU. M. (VAPOR PRESSURE: .60 MMHG @ 68F) CAS:111-76-2 RTECS #:KJ8575000 = Wt:5. OSHA PEL:25 PPM (SKIN) ACGIH TLV:25 PPM (SKIN) ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE TOXICOLOGICAL Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: WITH POOR VENTILATION, VAPOR SPRAY OR MIST MAY IRRITATE RESPIRATORY MUCOUS MEMBRANES, CAUSING HEADACHE AND NAUSEA. EYE CONTACT: PRIMARY IRRITANT. CHRONIC: NONE RECOGNIZED. Explanation of Carcinogenicity:THIS PRODUCT CONTAINS NO REPORTED CARCINOGENS OR SUSPECTED CARCINOGENS. Effects of Overexposure:SEE HEALTH HAZARDS ACUTE AND CHRONIC. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NECESSARY, RESTORE BREATHING; CONTACT PHYSICIAN AT ONCE. EYES: FLUSH AT ONCE WITH LARGE AMOUNTS OF LUKEWARM WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION.SKIN: REMOVE FROM SKIN WITH SOAP AND WATER. REMOVE DRENCHED CLOTHING. IF IRRITATION PERSISTS, CONSULT PHYSICIAN. INGESTION: IF VICTIM IS CONSCIOUS, GIVE 2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VO MITING. CONSULT PHYSICIAN OR POISON CONTROL CENTER AT ONCE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. AFTER WATER EVAPORATES, REMAINING MATERIAL WILL BURN; USE CO2, DRY CHEMICAL OR FOAM [NFPA CLASS B EXTINGUISHER]. Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS (SCBA) AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT; USE WATER SPRAY TO COOL. PRODUCT IN OPEN CONTAINERS MAY SPLATTER WHEN TEMPERATURE EXCEEDS BOILING POINT OF WATER. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA (AS DESCRIBED IN CONTROL MEASURES SECTION). AVOID UNNECESSARY SKIN CONTACT. STOP AND/OR CONTAIN SPILL IF IT CAN BE DONE SAFELY, AVOIDING DISCHARGE INTO DRAINS, SEWERS OR WATERWAYS. COLL ECT BY ABSORPTION, SHOVEL AND/OR WET MOPPING. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120 DEGREES F. CLOSE CONTAINER AFTER EACH USE. Other Precautions:DO NOT TAKE INTERNALLY. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DURING SPRAY APPLICATION, USE NIOSH-APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY. IF EXPOSURE EXCEEDS ANY TLV LISTED IN INGREDIENTS SECTION, USE NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. Ventilation:USE VENTILATION AS REQUIRED TO CONTROL VAPOR, DUST AND FUMES. AVOID PROLONGED OR REPEATED BREATHING OF VAPORS. SIDESHIELDS. Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . NONE REQUIRED (MFR). Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=171.1C, 340.F Vapor Pres:17 MMHG @ 68F Vapor Density:HEAV AIR Spec Gravity:1.03 VOC Pounds/Gallon:163 VOC Grams/Liter:1.36 Evaporation Rate & Reference:SLOWER BUTYL ACETATE Appearance and Odor:LIQUID; NO ODOR SPECIFIED BY MANUFACTURER . Percent Volatiles by Volume:71.25 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:HEATING TO DECOMPOSITION, AS IN A FIRE OR WELDING, MAY PRODUCE HAZARDOUS FUMES. FUMES MAY CONTAIN CARBON DIOXIDE, CARBON MONOXIDE AND OXIDES OF NITROGEN. =================== Toxicological Information=================== Toxicological Information:LC50: ACUTE INHALATION (RAT): 450 PPM-4HR. LD50: ACUTE ORAL (RAT): 0.5 - 3.0 G/KG. OTHER TEST: ACUTE DERMAL-RABBIT: 0.4 G/KG. THIS PRODUCT CONTAINS PIGMENTS WHICH MAY BECOME A DUST NUISANCE WHEN REMOV ED BY ABRASIVE BLASTING, SANDLING OR GRINDING. EXPOSURE LIMITS FOR NUISANCE DUSTS ARE: ACGIH TLV/TWA - TOTAL DUST - 10 MG/M3. OSHA PEL - TOTAL DUST - 15 MG/M3.WHERE THESE LIMITS ARE EXCEEDED, USE NI OSH APPROVED RESPIRATOR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL, COUNTY, STATE AND FEDERAL REGULATIONS BY INCINERATING, TREATING AND DISPOSING IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. =================== MSDS Transport Information =================== Transport Information:DOT: N/A. DOT #: N/A. FLAMMABILITY CLASSIFICATION: N/A. ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW ACT OF 1986 AND OF 40 CFR 372. THIS INFORMATI ON MUST BE INCLUDED IN ALL MATERIAL SAFETY DATA SHEETS THAT ARE COPIED AND DISTRIBUTED FOR THIS PRODUCT: 2-BUTOXYETHANOL, CAS# 111-76-2, WEIGHT PCT: 5.000. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPOT-CHECK DEVELOPER SKD-S2, 5 GAL Preparer's Name:BRUCE C. GRAHAM CAGE:59042 CAGE:37676 CAGE:59042 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL; (2-PROPANOL) (SARA 313). LD50:(ORAL,MOUSE) 3.6 G/KG. CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 40-70% OSHA PEL:400 PPM ACGIH TLV:400 PPM;500 STEL Ingred Name:ACETONE; (2-PROPANONE) (SARA 313) (CERCLA). LD50:(ORAL,RAT) 5 G/KG. CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 10-30% OSHA PEL:1000 PPM ACGIH TLV:750 PPM;1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE (PROPELLANT)) CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 30% OSHA PEL:1000 PPM (MFR) ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN CONTACT:CAN IRRITATE BY REMOVING NATURAL SKIN OILS ON LONG OR REPEATED EXPOSURE. EYES:IRRITATING, BUT DOES NOT DAMAGE TISSUE. INHAL:CAUSES DIZZINESS & NAUSEA. INGEST:NOT SIGNIFICANT IN SMALL (MOU THFUL) AMOUNTS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE. ======================= First Aid Measures ======================= First Aid:SKIN:WASH OFF W/SOAP & WATER. USE SOOTHING LOTION. EYES:RINSE CAREFULLY UNDER UPPER & LOWER EYELIDS USING PLENTY OF WATER FOR AT LST 15 MINS. INHAL:REMOVE TO FRESH AIR IF DIZZY/NAUSEATED. INGEST:DO NO T INDUCE VOMIT. ACCIDENTAL INGEST OF A SINGLE MOUTHFUL IS NOT EXPECTED TO CAUSE SIGNIFICANT HARM. NOTE:IN ALL SEV CASES, REGIONAL (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:2F,-17C Lower Limits:2% Upper Limits:15% Extinguishing Media:CARBON DIOXIDE, FOAM, WATER. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . KEEP CONTAINERS COOL W/WATER SPRAY. Unusual Fire/Explosion Hazard:BULK & AEROSOL:IGNITION WILL OCCUR IF USED NEAR FLAMES, ARCS OR OTHER IGNITION SOURCES. AEROSOL CANS MAY BURST >130F (54C) & ADD TO EXISTING FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:TURN OFF OR REMOVE SOURCES OF IGNITION. MOP UP OR SWEEP W/ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING VAPORS. AVOID EYE CONTACT. AVOID REPEATED OR PROLONGED SKIN CONTACT. STORE AWAY FROM HEAT SOURCE. DO NOT SPRAY AROUND ARCS OR FLAME. Other Precautions:EXTREMELY FLAMMABLE WHITE LIQUID & AEROSOL. FAST EVAPORATING VAPORS CAN REACH HAZARDOUS LEVELS QUICKLY IN UNVENTILATED SPACES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR W/FILTER IF SPRAYED IN ENCLOSED, UNVENTILATED SPACE. Ventilation:USE WHERE VENTILATION WILL CARRY VAPORS AWAY FROM OCCUPIED AREAS. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VP:BULK:150 @ 100F; AEROSOL:65 PSI @ 75F. FIRST AID PROC:POISON CONTROL CENTER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>132F,>56C Vapor Pres:SUPP DATA Vapor Density:3 Spec Gravity:0.87 pH:NEUT Evaporation Rate & Reference:0.4 (ETHER) Solubility in Water:90% Appearance and Odor:WHITE LIQUID; ALCOHOL ODOR. Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WHEN BURNING, SOOT, OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . SEND TO A LICENSED WASTE FACILITY FOR PROPER DISPOSAL. RCRA: HAZARDOUS WASTE. U.S. EPA WASTE NUMBER: F003 & D001.
1
eyes_protection_mandatory
======================================================= NIIN: 01-281-8794 Product ID: 7502A SCOTCHBOND 2 LIGHT CURE DENTAL ADHESIVE Cage: 0K0U5 ======================================================= Contractor Summary ======================================================= Cage: 76381 Cage: 0K0U5 ======================================================= Item Description Information ======================================================= Item Manager: S9M Specification Number: UNKNOWN Type/Grade/Class: UNKNOWN Unit of Issue: PG UI Container Qty: 1 Type of Container: BOX ======================================================= Ingredients ======================================================= Cas: 30757-19-8 % Wt: <62.1 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 868-77-9 RTECS #: OZ4725000 % Wt: <37.2 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 2767-84-2 % Wt: <1 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 50438-75-0 % Wt: <1 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50 (RAT) IS UNKNOWN Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHALATION/INGESTION: UNDER NORMAL CONDITIONS OF USE MATERIAL IS NOT HAZARDOUS THROUGH THESE ROUTES OF EXPOSURE. ACUTE: MAY CAUSE MILD EYE IRRITATION ON CONTACT. CHRONIC: PROLONGED OR REPEATED CONTACT MAY CAUSE ALLERGIC SKIN REACTION. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: EYES: REDNESS, SWELLING, PAIN AND TEARING. SKIN: REDNESS, SWELLIMG, BLISTERING, AND ITCHING. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: FLUSH WITH LOTS OF WATER. IF IRRITATION PERSISTS, SEE DOCTOR. INGESTED: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE 2 GLASSES OF WATER. GET IMMEDIATE MEDICAL HELP. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: VENTILATE AREA. CONTAIN SPILL. COVER WITH ABSORBENT MATERIAL. PLACE IN AN APPROVED METAL CONTAINER AND SEAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. MANUFACTURER RECOMMENDS MIXING WITH FLAMMABLE MATERIAL AND INCINERATE IN PERMITTED FACILITY. Handling And Storage Precautions: STORE AT ROOM TEMPERATURE. Other Precautions: DO NOT EAT, DRINK, OR SMOKE WHEN USING THIS MATERIAL. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: DRY CHEMICAL OR CARBON DIOXIDE Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS AND BUNKER GEAR. Unusual Fire/Explosion Hazard: NONE ======================================================= Control Measures ======================================================= Respiratory Protection: NONE NORMALLY REQUIRED. Ventilation: USE IN A WELL-VENTILATED AREA. Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES. Supplemental Safety and Health: PER TIR:ITEM IS CANCELLED USE NSN 6520-01-389-2079 DTD:94182. ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 B.P. Text: UNKNOWN M.P/F.P Text: UNKNOWN Decomp Text: UNKNOWN Vapor Pres: UNKNOWN Vapor Density: UNKNOWN Spec Gravity: 1.2 PH: 7 Viscosity: 600 CPS Evaporation Rate & Reference: UNKNOWN Solubility in Water: INSOLUBLE Appearance and Odor: CLEAR, SLIGHT YELLOW, SLIGHT ACRYLATE ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: UNKNOWN Hazardous Decomposition Products: UNKNOWN Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NONE ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 121723 Product ID: 7502A SCOTCHBOND 2 LIGHT CURE DENTAL ADHESIVE Review Date: 12/30/1992 Net Unit Weight: UNKNOWN Multiple KIT Number: 0 Review IND: Y Unit Of Issue: PG Container QTY: 1 Type Of Container: BOX ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: 7502A SCOTCHBOND 2 LIGHT CURE DENTAL ADHESIVE Cage: 0K0U5 Company Name: MINNESOTA MINING AND MFG CO DENTAL PRODUCTS DIV Street: 3M CENTER Zipcode: 55144-1000 Date Of Label Review: 12/30/1992 Status Code: C Label Date: 12/30/1992 Origination Code: Z =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GOLD MEDAL MBA ELASTOMERIC CAGE:6W507 CAGE:6W507 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT; (PETROLEUM DISTILLATE) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 50% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:ASPHALT; (PETROLEUM) CAS:8052-42-4 RTECS #:CI9900000 OSHA PEL:N/K ACGIH TLV:5 MG/M3 (FUME) Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (PETROLEUM DISTILLATE) CAS:64742-95-6 RTECS #:WF3400000 Other REC Limits:50 PPM/8 HR (MFR) OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:OVEREXPOSURE TO VAPORS CAUSES EYE IRRITATION, BLURRED VISION, DIZZINESS, HEADACHES & EVEN UNCONSCIOUSNESS. PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE MODERATE IRRITATION OR DERMATITIS. SWALLOWING CA N CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING & DIARRHEA. ASPIRATION OF MATERIAL INTO THE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM VAPORS IMMEDIATELY. IF OVERCOME, CALL MD. IF BREATHING STOPPED OR IRREGULAR, START RESUSCITATION OR ADMINISTER OXYGEN AS NEEDED. EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 M INUTES, LIFTING UPPER & LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHES & WASH W/WATERLESS HANDCLEANER OR SOAP & WATER. INGEST:DO NOT INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:105F,41C Lower Limits:0.9% Upper Limits:6% Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG, SPRAY. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DO NOT MIX/STORE W/STRONG OXIDANTS LIKE LIQ CHLORINE/OXYGEN. KEEP CNTNRS TIGHTLY CLSD. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNIT. KEEP PEOPLE AWAY. RECOVER FREE LIQ. ADD ABSORB(SAND, EARTH, SAWDUST, ETC) TO SPILL AREA. AVOID BRTHG VAPS. VENTILATE CONFINED SPACES. OPEN ALL WINDOWS & DOORS. KEEP PRODS OUT OF SEWERS & WATERCOURSES BY DIKING/ (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO NOT HANDLE OR STORE NEAR HEAT, SPARKS, FLAME OR STRONG OXIDANTS. ADEQUATE VENTILATION REQUIRED. Other Precautions:AVOID BREATHING VAPORS. AVOID PROLONGED OR REPEATED CONTACT W/SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED HYDROCARBON VAPOR CANISTER OR SUPPLIED-AIR RESPIRATORY PROTECTION IN CONFINED OR ENCLOSED SPACES - IF NEEDED. Ventilation:LOCAL EXHAUST:FACE VELOCITY 60 FPM. USE W/ADEQUATE VENTILATION. Other Protective Equipment:USE CHEMICAL-RESISTANT APRON OR OTHER CLOTHING TO AVOID REPEATED OR PROLONGED SKIN CONTACT. EYEWSH FNTN/DELUGE SHWR Work Hygienic Practices:REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. REMOVE CONTAM SHOES & THORO DRY BEFORE REUSE. WASH SKIN THORO W/SOAP(SUPDAT) Supplemental Safety and Health EXPLO HAZ:TO HOT SURFS REQS SPECIAL PRECS. DURING EMER CNDTNS, OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. SPILL PROC:IMPOUNDING & ADVISE AUTHS. HYGIE NE PRACT:& WATER AFTER CONTACT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>310F,>154C Vapor Pres:2 @ 68F Vapor Density:HVR/AIR Evaporation Rate & Reference:SLOWER (BUTYL ACETATE=1) Solubility in Water:NONE Appearance and Odor:BLACK FLUID; ODOR CHARACTERISTIC OF PETROLEUM SOLVENT. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FUMES, SMOKE & CARBON DIOXIDE. CARBON MONOXIDE IF COMBUSTION IS INCOMPLETE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . ASSURE CONFORMITY W/ALL APPLICABLE DISPOSAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CAT MIL-C-83286B TYPE 27886, 03W163CAT Kit Part:Y Preparer's Name:NORM GAUL CAGE:33458 CAGE:33458 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:VOLATILE ORGANIC COMPOUNDS: 533 G/L. RTECS #:9999999ZZ Ingred Name:SUPP DATA: SENSATION. SKIN ABSORP: PRLNG/RPTD CONTACT CAN CAUSE MOD IRRIT, DRYING & DEFATTING OF SKIN WHICH CAN (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: CAUSE SKIN TO CRACK. INGEST: ACUTE: CAN RESULT IN IRRIT & POSS CORR ACTIN IN MOUTH, STOMACH TISS & DIGEST(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: TRACT. VOMIT MAY CAUSE ASPIR OF SOLVENT RESULTING IN CHEMICAL PNEUMONITIS. RTECS #:9999999ZZ Ingred Name:HNDLG/STOR: CLOSED CONTAINERS. STORE IN WELL VENTILATED AREAS. RTECS #:9999999ZZ Ingred Name:HNDLG/STOR: CLOSED CONTAINERS. STORE IN WELL VENTILATED AREAS. RTECS #:9999999ZZ Ingred Name:RESP PROT: NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS RECOMMENDED. A (TC23C NIOSH/MSHA) VAP PARTICULATE RESP MAY BE (ING 14) Ingred Name:ING 12: APPROP WHERE AIR MONITORING DEMONSTRATES VAPOR LEVELS BELOW TEN TIMES APPLIC EXPOS LIMITS. Ingred Name:VENT: MUST BE UTILIZED. REMOVE ALL IGNIT SOURCES (HEAT, SPARKS, FLAME & HOT SURFACES). Ingred Name:ETHYL-3-ETHOXYPROPIONATE. VP: 0.7 @ 68F. CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 15% Ingred Name:HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE (HDI). VP: 0. CAS:28182-81-2 RTECS #:NQ9170000 Fraction by Wt: 20% Ingred Name:HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE (HDI). VP: 0. CAS:28182-81-2 RTECS #:NQ9170000 Fraction by Wt: 25% Ingred Name:AROMATIC HYDROCARBONS. VP: 3 @ 68F. CAS:74842-95-6 Fraction by Wt: <5% Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <5% OSHA PEL:150 PPM; 200 STEL ACGIH TLV:150 PPM; 200 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ISOBUTYL KETONE (SARA III). VP: 15 @ 68F. CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 35% OSHA PEL:50 PPM; 75 STEL ACGIH TLV:50 PPM; 75 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: VAPS ARE IRRIT TO EYES, NOSE & THROAT. INHAL MAY CAUSE HDCHS, DFCLT BRTHG & LOSS OF CONSCIOUSNESS. CHRONIC: AS RSLT OF PREVIOUS RPTD OVEREXP/SINGLE LARGE DOSE, CERTAIN INDIVID WILL DEVOLOP ISOC YANATE SENSIT WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOS OF ISOCYANATE LVLS WELL BELOW TLV OF (EFTS OF OVREREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: ISOCYANATES. OVEREXP: INHAL: IRRIT OF RESP TRACT & ACUTE CNS DEPRESS CHARACT BY FOLLOWING PROGRESSIVE STEPS: HDCH, DIZZ, STAGGERING GAIT, CONFUSN, UNCON/COMA. SKIN/EYE; SKIN: ISOCYANTES REAC T W/SKIN PROTEIN & MOISTURE & CAN CAUSEIRRIT. SYMPS MAY BE SWELLING, REDNESS & RASH. EYES: LIQ, AEROSOLS(SUPP DATA) Medical Cond Aggravated by Exposure:ASTHMA & ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA, AND DERMATITIS. ISOCYANATE SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHAL: MOVE TO AN AREA FREE FROM RISK OF FURTHER EXPOS. RESOTRE BRTHG. ASTHMATIC TYPE SYMPTOMS MAY DEVELOP & MAY BE IMMED/DELAYED BY SEVERAL HOURS. OBTAIN MD ATTN. SKIN: REMOVE CONTAMD CLTHG. WASH AFF ECTED AREAS THORO WITH SOAP & WATER FORAT LEAST 15 MINS. EYES: FLUSH WITH CLEAN LUKEWARM WATER (LOW PRESS) FOR AT LEAST 15 MINS, OCCASIONALLY LIFTING EYELIDS. OBTAIN MED ATTN. INGEST: DO NOT(ING 11) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:60F,15.6C Lower Limits:1.00% Upper Limits:8.00% Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILDUP, AUTO IGNIT/EXPLO. DURING FIRE HDI (SUPP DATA) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, SPARKS, ELECT EQUIP & OPEN FLAME. CLSD CNTNRS MAY EXPLO WHEN EXPOS TO EXTREME HEAT. APPLIC TO HOT SURFS(SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:EVAC ALL NON-ESSENTIAL PERS. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES). VENTILATE AREA. CONTAIN & REMOVE WITH INERT ABSORBENT & NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BUILDINGS DESIGNED TO COMPLY W/OSHA 1910.106. AVOID STORING NEAR HIGH TEMPS, FIRE, OPEN FLAMES, & SPARK SOURCES. STORE IN TIGHTLY (ING 12) Other Precautions:KEEP CNTNRS TIGHT & UPRIGHT TO PVNT LEAKAGE. PVNT PRLNGD BRTHG OF VAPS/SPRAY MISTS. PRLGD OVEREXP MAY CAUSE AN ALLERGIC RXN. AVOID CONT W/SKIN & EYES. DO NOT TAKE INTERNALLY. DO NOT HANDLE UNTIL MFRS SAFETY PRES HAVE BEEN READ (ING 14) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESP FOR USE IN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING/FRESH AIR SUPPLIED) IS NECESSARY. OBSERVE OSHA REGS FOR RESP USE. VENT SHOULD BE PROVIDED TO KEEP EXPOSURE LEVELS BELOW OSH A PERMISSIBLE LIMITS. A (ING 13) Ventilation:EXHAUST VENT SUFFICIENT TO KEEP AIRBORNE CONC OF SOLV, HDI & POLYISOCYANATES BELOW THEIR RESPECTIVE TLV'S (ING 15) Other Protective Equipment:USE OF LONG SLEEVE & LONG LEG CLOTHING IS RECOMMENDED. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING/USING WASHROOM. SMOKE IN SMOKING AREAS ONLY. REMOVE & WASH CONTAMD CLTHG BEFORE REUSE. Supplemental Safety and Health FIE FIGHT PROC: VAPS & OTHER IRRIT VAPS MAY BE GENERATED BY COMBUST/THERM DECOMP. EXPLOS HAZ: REQS SPECIAL PRECS. DURING EMERG CNDTNS OVEREXP TO DECOMP RPODS MAY CAUSE A HLTH AZ. SYMPS MAY NOT BE IMME D APPARENT. EFTS OF OVEREXP: OR VAPS ARE IRRIT & MAY CAUSE TEARING, REDNESS, & SWELLING ACCOMPANIED BY STINGING (ING 8) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>241F,>116C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.95438 Evaporation Rate & Reference:0.92 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR. Percent Volatiles by Volume:63.1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, STRONG BASES, ALCOHOLS, METAL CMPDS AND SURFACE ACTIVE MATERIALS. Stability Condition to Avoid:CONTACT W/MOISTURE, MATERIAL WHICH REACT W/ISOCYANATES AND HIGH TEMPERATURES. Hazardous Decomposition Products:BY HIGH HEAT/TEMPS: CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN, TRACES OF HCN & HDI. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORD W/FEDERAL, STATE & LOCAL ENVIRON CONTROL REGS. EMPTY CNTNRS MUST BE HNDLD W/CARE DUE TO PRODUCT RESIDUE & FLAMMABLE VAPOR. DO NOT INCINERATE CLOSED CNTNRS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LIQUID CHLORINE BLEACH CAGE:MO186 CAGE:MO186 CAGE:0VL27 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYPOCHLORITE (SARA III) CAS:7681-52-9 RTECS #:NH3486300 Fraction by Wt: 5.25% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD 50 ORAL RAT= 5800 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:CAUSES SEVERE TEMPORARY IRRITATION. SKIN:MAY IRRITATE SENSITIVE SKIN. INGEST:MAY CAUSE GI IRRITATION. INHAL:MAY IRRITATE NOSE,THROAT AND LUNGS. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INGEST:NAUSEA,VOMITING. Medical Cond Aggravated by Exposure:MAY AGGRIVATE CHRONIC RESPIRATORY PROBLEMS(E.G. ASTHMA). ======================= First Aid Measures ======================= First Aid:IN ALL CASES,CALL A PHYSICIAN FOR PERSISTING SYMPTOMS. EYE:FLUSH WITH RUNNING WATER. SKIN:REMOVE CONTAMINATED CLOTHING, WASH WITH RUNNING WATER. INHAL:REMOVE TO FRESH AIR. INGEST:IF CONSCIOUS, DRINK A GLASSFUL OF TAP WATER.CALL THE POISONCONTROL CENTER AT 800-282-3171. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:TOXIC FUMES ARE PRODUCED IN FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL AMOUNTS CAN BE FLUSHED DOWN THE DRAIN WITH TAP WATER. FOR LARGE AMOUNTS, DILUTE WITH WATER; SOAK UP WITH AN INERT ABSORBANT; PLACE IN AN APPROPRIATE CONTAINER FOR DISPOSAL. Neutralizing Agent:DILUTE WITH WATER THE REDUCE THE OXIDIZING EFFECTS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. DO NOT MIX WITH ANY OTHER CHEMICALS. KEEP OUT OF REACH OF CHILDREN. DO NOT GET ON SKIN OR IN EYES. Other Precautions:WASH THOROUGHLY AFTER HANDLING. DO NOT REUSE EMPTY CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN EMERGENCY SITUATIONS, WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A SELF-CONTAINED BREATHING APPARATUS. Ventilation:USE WITH GOOD VENTILATION. LOCAL VENTILATION AT THE WORKSITE; MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL. Other Protective Equipment:EY WASH STATION,QUICK DRENCH SHOWER.IMPERVIOUS CLOTHING ...AS NEEDED. Work Hygienic Practices:WASH HANDS. SEPERATE WORK CLOTHES FROM STREET CLOTHES. LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:>100.C, 212.F Melt/Freeze Pt:=-9.C, 15.8F Vapor Density:19.2 Spec Gravity:1.08-1.2 pH:10-12 Solubility in Water:COMPLETE Appearance and Odor:LIQUID,CLEAR; LIGHT YELLOW TO GREEN; CHARACTERISTIC CHLORINE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURES, OPEN FLAMES. Hazardous Decomposition Products:VARIOUS HAZARDOUS CHLORINATED GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:P-HF, CRACK CHECK PENETRANT CAGE:0CHD7 CAGE:0CHD7 ============= Composition/Information on Ingredients ============= Ingred Name:BLEND OF MINERAL SPIRITS CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED Ingred Name:PETROLEUM HYDROCARBON Fraction by Wt: 50% Other REC Limits:100 PPM Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-NAPHTHALENOL (PHENYLAZO)PHENOL)-AZO ALKYL DERIVATIVES Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED Ingred Name:ISOBUTANE/PROPANE MIXTURE Fraction by Wt: 40% Other REC Limits:NONE SPECIFIED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CAN CAUSE IRRITATION TO NOSE, THROAT, RESPIRATORY TRACT, EYES, AND SKIN. IF VAPOR CONCENTRATION EXCEEDS TLV, POSSIBLE UNCONSCIOUSNESS OR COULD BE FATAL. Effects of Overexposure:INHALATION: MAY BE IRRITATING TO NOSE, THROAT, AND RESPIRATORY TRACT. MAY CAUSE HEADACHE, DIZZINESS, AND NAUSEA. INGESTION: HARMFUL IF SWALLOWED. EYES: LIQUID/VAPORS CAUSES SEVERE IRRITATION. SKIN: M ODERATE IRRITANT. PROLONGED OR REPEATEDCONTACT MAY CAUSE DEFATTING AND DRYING OF SKIN. Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL HELP. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. CALL A DOCTOR. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGE N IF BREATHING IS DIFFICULT GIVE ARTIFICIAL BREATHING AND ADMINISTER OXYGEN. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES.GET MED ATTENTION IF IRRITATION PERSISTS.SKIN:WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point:N/R (AEROSOL CAN Extinguishing Media:WATER FOG, DRY CHEMICAL, FOAM, CARBON DIOXIDE Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. COOL EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:AEROSOPL CANS WILL EXPLODE IN HEAT OF FIRE. TREAT AS CYLINDER OF COMPRESSED GAS. FACE SHIELDS, HELMETS AND SELF CONTAINED BREATHING APPARATUS IS RECOMMENDED. ================== Accidental Release Measures ================== Spill Release Procedures:IF LIQUID SPILLS OUT, VENTILATE AREA. REMOVE ALL SOURCES OF IGNITION. CLEAN UP WITH INERT MATERIALS. SEGREGATE AND REMOVE THE LEAKING AEROSOL CANS. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN DIRECT SUNLIGHT OR WHERE TEMPERATURE EXCEED 120F. AVOID SPLASH FILLING, OPEN FLAME, SPARKS. USE IN WELL-VENTILATED AREA. Other Precautions:DO NOT SPRAY ON FLAMES, HOT SURFACES. AVOID INHALATION OF VAPORS. AVOID PHYSICAL DAMAGE TO THE CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR TO PREVENT OVER-EXPOSURE IN ACCORDANCE WITH 29CFR1910.134 Ventilation:LOCAL EXHAUST IS ADEQUATE. Other Protective Equipment:NONE Work Hygienic Practices:WASH HANDS BEFORE HANDLING FOOD STUFF. AIR DRY CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. Supplemental Safety and Health ITEM IS TYPE II, METHOD C PENETRANT OF MIL-I-25135, REV E. ================== Physical/Chemical Properties ================== HCC:V3 Vapor Pres:<60 PSIG Vapor Density:>1 Spec Gravity:0.945 Solubility in Water:NEGLIGIBLE Appearance and Odor:RED CLEAR LIQUID WITH SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:OPEN FLAMES OR SPARK SOURCES Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:AEROSOL CONTAINER: DO NOT PUNCTURE OR INCINERATE. EMPTY CONTAINERS MAY BE DISPOSED OF THROUGH NORMAL CHANNELS. FULL OR PARTIALLY FILLED CONTAINERS ARE CONSIDERED HAZARDOUS WASTE. COMPLY WITH ALL FEDER AL, STATE, LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ANAEROBIC ID 232 CAGE:JO919 CAGE:61603 CAGE:JO919 ============= Composition/Information on Ingredients ============= Ingred Name:POLYGLYCOL DIMETHACRYLATES Fraction by Wt: 60-65% OSHA PEL:NONE LISTED ACGIH TLV:NONE LISTED Ingred Name:POLYESTER PLATSIZER Fraction by Wt: 30-35% OSHA PEL:NONE LISTED ACGIH TLV:NONE LISTED Ingred Name:TRIALKYLAMINE Fraction by Wt: <2% OSHA PEL:NONE LISTED ACGIH TLV:NONE LISTED Ingred Name:CUMENE HYDROPEROXIDE CAS:80-15-9 RTECS #:MX2550000 Fraction by Wt: <3% EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:NONE LISTED. Explanation of Carcinogenicity:NONE LISTED. Effects of Overexposure:NONE LISTED. Medical Cond Aggravated by Exposure:PROLONGED EXPOSURE TO SKIN MAY CAUSE IRRITATION TO A SENSITIVE PERSON. ======================= First Aid Measures ======================= First Aid:SKIN CONTACT: FLUSH WITH WATER. EYE CONTACT: FLUSH WITH WATER. INGESTION:DO NOT INDUCE VOMITING. SEEK MEDICAL ATTENTION TLV: DOES NOT APPLY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:200F/33.89C Extinguishing Media:FOAM,DRY CHEMICAL. Fire Fighting Procedures:SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING SHOULD BE WORN IF FIGHTING FIRES INVOLVING CHEMICALS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP IN INERT ABSORBENT,STORE IN CLOSED CONTAINER. Neutralizing Agent:NONE LISTED. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 100F AND AVOID PROLONGED SKIN CONTACT. Other Precautions:NONE LISTED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE LISTED. Ventilation:NORMALLY NOT NECESSARY. Other Protective Equipment:NONE LISTED. Work Hygienic Practices:NONE LISTED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>300F Vapor Pres:<5 AT 80F Vapor Density:(AIR=1) Spec Gravity:1.05 Solubility in Water:LOW Appearance and Odor:BLUE LIQUID-ODOR MILD. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE LISTED. Stability Condition to Avoid:NONE LISTED. Hazardous Decomposition Products:NONE Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR BURY IN ACCORDANCE WITH LOCAL AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR-1201-Q POLYSULFIDE SEALANT, ACCELERATOR Preparer's Name:A.F. SHARABY CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD DIOXIDE [LEAD PEROXIDE] CAS:1309-60-0 RTECS #:OG0700000 Fraction by Wt: 65% Other REC Limits:0.05 MG/M3 TWA Ingred Name:HYDROGENATED TERPHENYLS CAS:61788-32-7 RTECS #:WZ6535000 Fraction by Wt: 25% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 PPM ACGIH TLV:0.5 PPM; 9394 Ingred Name:LEAD OXIDE/LITHARGE CAS:1317-36-8 RTECS #:OG1750000 Fraction by Wt: 10% Other REC Limits:0.05 MG/M3 TWAA ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION OF AIRBORNE DUST PARTICLES OR INGESTION MAY CAUSE ANEMIA, CNS EFFECTS, ABDOMINAL COLIC OR KIDNEY FUNCTION LOSS. PRODUCT IS WETTED, SO RISK FROM INHALATION OF DUST IS MINIMAL. INORGANIC LEAD IS NOT READILY ABSORBED, SO INGESTION RISK IS ALSO MINIMAL. Explanation of Carcinogenicity:THIS PRODUCT CONTAINS A LEAD COMPOUND WHICH IS KNOWN BY THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY & CANCER. Effects of Overexposure:ATAXIA, HEADACHES, MUSCULAR TREMOR. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGESTED-CALL A PHYSICIAN. INHALED-REMOVE TO FRESH AIR. SKIN-WASH WITH SOAP & WATER. EYES-IMMEDIATELY FLUSH WITH LOTS OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER, CARBON DIXOIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. USE WATER TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:OXIDIZER. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP SPILLED MATERIAL. CLEAN-UP RESIDUE WITH RAGS & NON-FLAMMABLE SOLVENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. AVOID INGESTION. THIS PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF SARA 1986 AND 40 CFR PART 372. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. Ventilation:NOT APPLICABLE. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health MSDS REPRESENTS FORMULA CHANGE. MSDS ENTERED BY DLA-HMIS PER NAVY REQUEST. ================== Physical/Chemical Properties ================== HCC:D1 Spec Gravity:2.6 Viscosity:1000 POISE Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK, LIGHT PASTE. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EASILY OXIDIZABLE MATERIALS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:SMOKE, SOOT, CARBON MONOXIDE, CARBON DIOXIDE, LEAD COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS. EPA/RCRA WASTE NUMBER D008 (LEAD) MAY APPLY TO UNUSED/UNCONTAMINATED PRODUCT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ER 5556, INWELD ALUMINUM WIRES CAGE:66376 Contract Num:SP0490-00-D-4063 CAGE:00WU8 CAGE:66376 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINIUM CAS:7429-90-5 RTECS #:BD0330000 Minumum % Wt:85. Maxumum % Wt:99.5 OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:BERYLLIUM CAS:7740-41-7 RTECS #:DS1750000 Fraction by Wt: 0.0008% OSHA PEL:SEE TABLE Z-2 ACGIH TLV:0.002 MG/M3 ACGIH STEL:0.002 MG/M3 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:CHROMIUM CAS:7440-47-3 RTECS #:GB4200000 = Wt:.35 OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COPPER CAS:7440-50-8 RTECS #:GL5325000 = Wt:6.8 OSHA PEL:1 MG/M3 ACGIH TLV:0.2 MG/M3 AS FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 = Wt:.8 ACGIH TLV:5 MG/M3 AS OXIDE Ingred Name:MAGNESIUM . CAS:1309-48-4 RTECS #:OM3850000 = Wt:5.5 OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 OXIDE FUME Ingred Name:MANGANESE CAS:7439-96-5 RTECS #:OO9275000 = Wt:1. OSHA PEL:C5 MG/M3 ACGIH TLV:1.5 MG/M3 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 = Wt:13. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:ZINC . CAS:1314-13-2 RTECS #:ZH4810000 = Wt:8.2 OSHA PEL:15 MG/M3 ACGIH TLV:5 MG/M3 OXIDE FUME Ingred Name:COBALT CAS:7440-48-4 RTECS #:GF8750000 OSHA PEL:0.1 MG/M3 ACGIH TLV:0.05 MG/M3 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:SHORT TERM (ACUTE) OVEREXPOSURE TO WELDING FUMES MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA, AND DRYNESS OR IRRITATION OF THE NOSE, THROAT, OR EYES. LONG TERM (CHRONIC) OVEREXPOSURE TO WELDIN G FUMES MAY LEAD TO SIDEROSIS (IRON DEPOSITS IN THE LUNG) AND IS BELIEVED BY SOME INVESTIGATORS TO AFFECT PULMONARY FUNCTION. ARC RAYS CAN INJURE EYES AND BURN SKIN. ELECTRIC SHOCK CAN KILL. Effects of Overexposure:DIZZINESS, NAUSEA, AND DRYNESS OR IRRITATION OF THE NOSE, THROAT, OR EYES. Medical Cond Aggravated by Exposure:AGGRAVATION OF PREEXISTING RESPIRATORY OR ALLERGIC CONDITIONS MAY OCCUR IN SOME WORKERS. ======================= First Aid Measures ======================= First Aid:CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. FOR SKIN CONTACT, REMOVE PARTICLES BY THOROUGHLY WASHING WITH SOAP AND WATER. FOR EYE CONTACT, FLUSH WITH WATER FOR AT LEST 15 MINUTES, GET MEDICAL ATTENTION. FOR INHALATION, REMOVE FROM EXPOSURE, GET MEDICAL ATTENTION IF EXPERIENCING BREATHING DIFFICULTY. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:REFER TO AMERICAN NATIONAL STANDARD Z-49.1 FOR FIRE PREVENTING DURING THE USE OF WELDING PROCEDURES. Unusual Fire/Explosion Hazard:THESE PRODUCTS AS SHIPPED ARE NONHAZARDOUS, NONFLAMMABLE, NONEXPLOSIVE, AND NONREACTIVE. WELDING ARC AND SPARKS CAN IGNITE COMBUSTIBLES AND FLAMMABLES. ================== Accidental Release Measures ================== Spill Release Procedures:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:READ AND UNDERSTAND THE MANUFACTURES'S INSTRUCTIONS AND THE PRECAUTIONARY LABEL ON THIS PRODUCT. SEE AMERICAN NATIONAL STANDARD Z-49.1, SAFETY IN WELDING AND CUTTING, PUBLISHED BY THE AMERICAN WELDING SOCIETY, P.O. BPX 35410, MIAMI, FL 33135 AND OSHA PUBLICATION 2206 (29 C.F.R. 1910), U.S. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIES RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:USE ENOUGH VENTILATION, LOCAL EXHAUST AT THE ARC, OR BOTH, TO KEEP THE FUMES AND GASES BELOW THE TLV'S IN THE WORKERS BREATHING ZONE AND THE GENERAL AREA. Other Protective Equipment:WEAR HEAD, HAND AND BODY PROTECTION THAT HELP TO PREVENT INJURY FROM RADIATION, SPARKS AND ELECTRICAL SHOCK. SEE ANSI Z-49.1. SHIELD, ARM/SHOULDER PROTECTORS, HATS, AS WELL AS DARK SUBSTANTIAL CLOTHING). TRAIN THE WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS & TO INSULATE HIMSELF. Supplemental Safety and Health VENTILATION: TRAIN THE WELDING TO KEEP HIS HEAD OUT OF THE FUMES. EYE PROTECTION: AS A RULE OF THUMB, START WITH A SHADE WHICH IS TOO DARK TO SEE THE WELD ZONE. THEN GO TO THE NEXT LIGHTER SHADE WHICH GIVES SUFFICIENT VIEW OF WELD ZONE. PROVIDE PROTECTIVE SCREENS AND ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:>521.1C, 970.F M.P/F.P Text:970-1215 Spec Gravity:2.5-2.9 Solubility in Water:NIL Appearance and Odor:SOLID, METALLIC COLOR, NO ODOR. ================= Stability and Reactivity Data ================= Hazardous Decomposition Products:REASONABLY EXPETED FUMES/GASES WOULD INCLUDE METAL FUMES, OXIDES OF ALUMINUM & MAGNESIUM, CARBON MONOXIDE, CARBON DIOXIDE, OZONE, NITROGEN OXIDES, INFRA-RED RADIATION, & ULTRA-VIOLET RADIATION. =================== Toxicological Information=================== Toxicological Information:THRESHOLD LIMIT VALUE: THE ACGIH RECOMMENDED GENERAL LIMIT FOR WELDING FUME NOC (NOT OTHYERWISE CLASSIFID) IS 5 MG/M3. THE ACGIH 1984-85 PREFACE STATES: :THE TLV-TWA SHOULD BE USED AS GUIDES IN THE CO NTROL OF HEALTH HAZARDS AND SHOULD NOT BE USED AS FIRM LINES BETWEEN SAFE AND DANGEROUS CONCENTRATIONS". ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GREDAG 0033 CAGE:70079 CAGE:70079 ============= Composition/Information on Ingredients ============= Ingred Name:SOLID PIGMENT. Other REC Limits:SEE INGREDIENT NAME OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PETROLEUM OIL OSHA PEL:5 MG/M3 (MIST) ACGIH TLV:5 MG/M3 (MIST) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: NO ACUTE EFFECTS EXPECTED W/IN EXPOSURE LIMITS. INGEST: CAN CAUSE GI IRRITATION, NAUSEA, VOMITING AND DIARRHEA. EYE: MAY CAUSE TEMPORARY IRRITATION. CHRONIC: SKIN: REPEATED OR PROLONGED CONTACT CAN CAUSE IRRITATION AND DERMATITIS. Explanation of Carcinogenicity:THE CARRIER OILS USED IN THIS PRODUCT ARE NONCARCINOGENIC USING CURRENT BIOASSAY METHODS, PER IARC MONOGRAPH. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. INGEST: KEEP INDIVIDUAL CALM & SEEK MEDICAL ATTENTION IMMEDIATELY. EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND SEEK MEDICAL ATTENTION IF IRRITATION OCCURS. SKIN: WAS H WITH SOAP AND WATER, REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. ===================== Fire Fighting Measures ===================== Flash Point:360F,182C Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICALS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:APPLY ABSORBENT MATERIAL AND TRANSFER TO CONTAINERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED INHALATION OF MISTS OR VAPORS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV OF PRODUCT IS EXCEEDED, A NIOSH/MSHA APPROVED MECHANICAL OR SCBA IS ADVISED. Ventilation:MECHANICAL(GENERAL): PROVIDE SUFFICIENT MECHANICAL VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:NO SPECIAL EQUIPMENT DEEMED NECESSARY UNDER NORMAL USAGE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:700F,371C Melt/Freeze Pt:M.P/F.P Text:200F,93C Spec Gravity:91(H*2O=1) Solubility in Water:NIL Appearance and Odor:BLACK, SEMI-SOLID/BLAND ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: CRAFT AND FABRIC PAINT,PM 500 Cage: 21546 Resp. Party Other MSDS No.: MSDS #701 ======================================================= Contractor Summary ======================================================= Cage: 21546 ======================================================= Ingredients ======================================================= ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: NONE. NONTOXIC. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: ABRASIVE, CAN SCRATCH EYES. First Aid: EYE CONTACT: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN CONTACT: WASH WITH SOAP AND WATER. INGESTION: CALL PHYSICIAN IMMEDIATELY (FP N). INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OX YGEN OR ARTIFICIAL RESPIRATION) (FP N). ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: CLEAN UP PROPERLY WITH PAPER TOWELS AND WET SPONGE. Waste Disposal Methods: PUT PAPER TOWELS IN TRASH AND RINSE OUT SPONGE. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS (FP N). Handling And Storage Precautions: KEEP CONTAINER SEALED. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE APPROPRIATE TECHNIQUES AND MEDIA FOR SURROUNDING FIRE. Fire Fighting Procedures: NONE. WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: MATERIAL CAN SPATTER ABOVE 212F. POLYMER FILM CAN BURN. ======================================================= Control Measures ======================================================= Respiratory Protection: IF SPRAYING, DO NOT INHALE MIST. USE RESPIRATOR THAT IS NIOSH APPROVED FOR SPRAYS AND MISTS. Ventilation: LOCAL EXHAUST: RECOMMENDED. MECHANICAL (GENERAL): RECOMMENDED WHEN SPRAYING. SPECIAL: USE RESPIRATOR WHEN SPRAYING. OTHER: NONE. Other Protective Equipment: NONE NEEDED. ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER (FP N). Work Hygienic Practices: GOOD HYGIENE PRACTICES SHOULD BE FOLLOWED. ======================================================= Physical/Chemical Properties ======================================================= Boiling Point: =100.C, 212.F Vapor Pres: (MM HG) NOT APPLICABLE Vapor Density: (AIR=1)N/A Spec Gravity: 1.1 (WATER =1) PH: 7.0-9.0 Solubility in Water: INSOLUBLE Appearance and Odor: OPAQUE-COLORED LATEX PAINT. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= Toxicological Information: CONFORMS TO NONTOXIC ASTMD-4236: PRODUCTS BEARING THE NONTOXIC PRODUCT SEAL ARE CERTIFIED IN A PROGRAM OF TOXICOLOGICAL EVALUATION BY A NATIONALLY RECOGNIZED TOXICOLOGIST TO CONTAIN NO MATERIALS IN SU FFICIENT QUANTITIES TO BE TOXIC OR INJURIOUS TO HUMANS OR TO CAUSE ACUTE OR CHRONIC HEALTH PROBLEMS. THESE PRODUCTS ARE CERTIFIED TO BE LABELED IN ACCORDANCE WITH THE VOLUNTARY CHRONIC HAZARD LABELING STANDARD ASTMD-436. IN ADDITION THERE IS NO PHYSICAL HAZARD AS DEFINED WITHIN 29 CFR PART 1910.1200(C). ======================================================= Ecological Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: CODES: HEALTH: 0, FIRE: 0, REACTIVITY: 0, PROTECTIVE EQUIPMENT: G (IF SPRAYING). ======================================================= HAZCOM Label ======================================================= Product ID: CRAFT AND FABRIC PAINT,PM 500 Cage: 21546 Company Name: DUNCAN ENTERPRISES Street: 5673 E SHIELDS AVE Zipcode: 93727 Label Required IND: Y Date Of Label Review: 11/04/1999 Status Code: A Origination Code: F Skin Protection IND: YES Signal Word: NONE Respiratory Protection IND: YES Health Hazard: None Contact Hazard: None Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE; NONE. NONTOXIC. CHRONIC: NONE SPECIFIED BY MANUFACTURER (FP N). =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:146 4700,CONC,KODAK DEKTOL DEVELOPER (SINGLE POWDER) CAGE:19139 Contract Num:SP0500-96-D-9413-N858 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE MONOHYDRATE CAS:5968-11-6 Minumum % Wt:50. Maxumum % Wt:55. Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Minumum % Wt:30. Maxumum % Wt:35. Ingred Name:HYDROQUINONE CAS:123-31-9 RTECS #:MX3500000 = Wt:6. OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:4-(METHYLAMINO)PHENOL SULFATE CAS:55-55-0 RTECS #:SL8650000 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:SODIUM HEXAMETAPHOSPHATE CAS:10124-56-8 RTECS #:OY3675000 Minumum % Wt:1. Maxumum % Wt:5. EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POTASSIUM BROMIDE CAS:7758-02-3 RTECS #:TS7650000 Minumum % Wt:1. Maxumum % Wt:5. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD-50 (RAT): 0.5-5.0 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES Health Hazards Acute and Chronic:INHALATION: HARMFUL IF INHALED. AIRBORNE DUST IRRITATING. MAY CAUSE IRRITATION TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. AIRBORNE DUST IRRITAT ING. REPEATED EXPOSURE TO DUST MAY CAUSE EYE INJURY. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF THE GASTRO INTESTINAL TRACT IF SWALLOWED. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE):INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): HYDROQUINONE, GROUP 3 - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENIST S (ACGIH) (HYDROQUINONE): A3 - ANIMAL CARCINOGEN - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:CONTAINS: 4-(METHYLAMINO)PHENOL SULFATE. BASED ON ANIMAL DATA, MAY CAUSE ADVERSE EFFECTS ON THE FOLLOWING ORGANS/SYSTEMS: BLOOD, KIDNEY, SPLEEN. BASED ON ANIMAL DATA THIS MATERIAL CAN PRODUCE METHEMOG LOBIN WHICH, IN SUFFICIENT CONCENTRATION, CAUSES CYANOSIS, A BLUE-GRAY DISCOLORATION OF THE SKIN AND LIPS CAUSED BY A REDUCED ABILITY OF THE BLOOD TO CARRY OXYGEN. Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES: IMMEDIATELY FLUSH WITH WATER AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN: IMMEDIATELY FLUSH WI TH WATER AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF SKIN IRRITATION OR AN ALLERGIC SKIN REACTION DEVELOPS, GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE. D ESTROY OR THOROUGHLY CLEAN CONTAMINATED SHOES. INGESTION: ONLY INDUCE VOMITING AT THE INSTRUCTION OF MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN OR PO ISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, SWEEP UP AND PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-KEEP CONTAINER CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. PERSONAL Other Precautions:PRECAUTIONARY MEASURES-AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID) HAND CL EANER AND REGULAR CLEANING OF WORKING REACTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: DUST. A RESPIRATOR SHOULD BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED. RESPIRATOR: ACID GAS. IF RESPIRATORS USED, ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. APPROPRIATE FOR RISK OF EXPOSURE. FACE SHIELD. Other Protective Equipment:WEAR A FULL-FACE RESPIRATOR, IF NEEDED. EYE BATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health VENTILATION: USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. ================== Physical/Chemical Properties ================== HCC:T6 Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE Vapor Pres:@ 20?C (68?F):NEGLIGIBLE Spec Gravity:NOT AVAILABLE Solubility in Water:APPRECIABLE Appearance and Odor:WHITE, ODORLESS SOLID. Percent Volatiles by Volume:NEGLIGIBLE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:STABLE. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, SULFUR DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:HYDROQUINONE. IN F-344 RATS, CHRONIC ORAL ADMINISTRATION OF HYDROQUINONE HAS RESULTED IN THE FORMATION OF BENIGN KIDNEY TUMORS THOUGHT TO BE SECONDARY TO NEPHROPATHY. HYDROQUINONE-INDUCED NEPHROPATHY FOLLOWING ORAL ADMINISTRATION HAS BEEN NOTED IN THE MALE F-344 RAT, BUT NOT IN OTHER SPECIES OR RAT STRAINS TESTED. ALTHOUGH AN INCREASE IN MONONUCLEAR CELL LEUKEMIA IN F-344 FEMALE RATS HAS BEEN REPO RTED FOLLOWING CHRONIC ORAL ADMINISTRATION OF HYDROQUINONE, THIS FINDING WAS NOT REPRODUCED IN A SUBSEQUENT STUDY. ===================== Ecological Information ===================== Ecological:SUMMARY: DATA FOR THE MAJOR COMPONENTS OF THIS MATERIAL HAVE BEEN USED TO ESTIMATE THE ENVIRONMENTAL IMPACT OF THIS MATERIAL. THIS MATERIAL FORMS AMODERATELY ALKALINE AQUEOUS SOLUTION, & THIS PROPERTY MAY CAUSE ADVERSE ENVIRONMENTAL EFFECTS. HOWEVER, THIS MATERIAL, ITSELF, HAS NOT BEEN TESTED FOR ENVIRONMENTAL EFFECTS. IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A MODERATE BIOCHEMICAL OXYGENDEMAND & MAY CAUSE OXYGEN DEPLETION IN AQUEOUS SYSTEMS, A HIGH POTENTIAL TOAFFECT SOME AQUATIC ORGANISMS, A HIGH POTENTIAL TO AFFECT SECONDARY WASTETREATMENT MICROBIAL METABOLISM, A MODERATE POTENTIAL TO AFFECT THE GERMINATION.. AND/OR EAR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLD WIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: HYDROQUINONE Federal Regulatory Information:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE):- INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): HYDROQUINONE, GROUP 3. AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENI STS (ACGIH) (HYDROQUINONE): A3 - ANIMAL CARCINOGEN. NATIONAL TOXICOLOGY PROGRAM (NTP): NONE. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE. State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GAS, PREM UNLEADED CAGE:81355 CAGE:81355 CAGE:STOPN ============= Composition/Information on Ingredients ============= Ingred Name:GASOLINE CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: >95% OSHA PEL:300 PPM/500 STEL ACGIH TLV:300 PPM/500STEL;9192 Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: 1-5% OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:THE MANUFACTURER LISTS THE FIRST 2 INGREDIENTS THEN UNDER "NOTES", LISTS THE FOLLOWING 3 SARA 313 CHEMICALS. RTECS #:9999999ZZ Other REC Limits:NONE RECOMMENDED Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 3-7% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 4.6-11%. Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 1-4% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO INFORMATION GIVEN BY MFR ON THE MSDS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:MATERIAL IS SLIGHTLY IRRITATING TO BODY TISSUEES. INHALED OR INGESTED IT DEPRESSES THE CENTRAL NERVOUS SYSTEM. CHRONIC:REPEATED OR PROLONGED EXPOSURE TO BENZENE, EVEN AT RELATIVELY LOW CONCENT RATIONS, MAY RESULT IN VARIOUS BLOOD DISORDERS RANGING FROM ANEMIA TO LEUKEMIA. Explanation of Carcinogenicity:BENZENE IS LISTED BY ALL ABOVE AGENCIES AS CARCINOGENIC. Effects of Overexposure:EYE: MAY CAUSE SEVERE IRITATION, REDNESS, TEARING, BLURRED VISION; SKIN: PROLONGED CONTACT MAY CAUSE MODERATE IRRITATION, DEFATTING, DERMATITIS; INHALE: NASAL AND RESPIRATORY IRRITATION, DIZZINESS, WE AKNESS, FATIQUE, NAUSEA, ETC.; INGEST: GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA, OR ASPIRATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: WASH WITH SOAP AND WATER, REMOVE & LAUNDER CONTAMINATED CLOTHING; EYE: FLUSH WITH LARGE AMOUNTS OFWATER, LIFTING UPPER AND LOWER LIDS OCCATIONALLY, GET MEDICAL ATTENTION; INHALE: REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF NECESSARY. GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED; INGEST: DO NOT INDUCE VOMITING. KEEP PERSON WARM, QUIET. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-40F/-40C Lower Limits:1.5 Extinguishing Media:USE CARBON DIOXIDE, REGULAR FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:MATERIAL IS HIGHLY VOLATILE & READILY GIVES OFF VAPORS WHICH MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION & IGNITED BY PILOT LIGHTS, SPARKS, ETC. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. SMALL SPILL:ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, ETC, AND TRANSFER TO HOOD. LARGE SPILL:DIKE AREA TO CONTAIN. PUMP LIQUID TO SALVAGE TANK FOR LATER DISPOSA L. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPARKS & OPEN FLAME. KEEP CONTAINERS CLOSED. USE & STORE ONLY W/ADEQUATE VENTILATION. GROUND CONTAINERS WHEN TRANSFERRING PRODUCT. Other Precautions:DO NOT TRANSFER TO UNLABELED CONTAINERS. DO NOT USE CUTTING OR WELDING TORCH ON THIS CONTAINER. KEEP OUT OF REACH OF THE CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IF TLV IS EXCEEDED. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS UNDER CERTAIN CONDITIONS. ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO CONTROL EXPOSURES. Ventilation:PROVIDE SUFFICIENT MECHANICAL VENTILATION AND/OR LOCAL EXHAUST TO KEEP BELOW TLV. Other Protective Equipment:IMPERVIOUS CLOTHING AND BOOTS WHEN NEEDED TO PREVENT PROLONGED OR REPEATED SKIN CONTACT. Work Hygienic Practices:MFR: ?HMIS:USE GOOD INDUSTRIAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:70F/21C Vapor Pres:500 MMHG Vapor Density:4.0 Spec Gravity:0.74 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:CLEAR LIQUID. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:NO INFORMATION GIVEN BY MFR ON THE MSDS. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT RUNOFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. IF RUNOFF OCCURS, NOTIFY AUTHORITIES. SMALL SPILL TO BE EVAPORATED IN HOOD. LARGE SPILL TO BE DESTROYED BY LIQUID INCINERATION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:28 TITANIUM WHITE PHOTO OIL COLOR CAGE:JOHNM CAGE:JOHNM ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: >0.5% Other REC Limits:1900 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 15.4% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM FUME ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE CONTACT MAY CAUSE REDNESS & TEARING. SENSITIVE INDIVIDUALS MAY EXPERIENCE DERMATITIS AFTER LONG EXPOSURE TO SKIN. INGESTION OF LARGE AMOUNTS MAY CAUSE GI UPSET. FRESHLY FORMED FUMES, AS FROM BURNI NG, MAY CAUSE METAL FUME FEVER W/CHILLS, FEVER, TIGHTNESS IN CHEST, COUGH & LEUKOCYTES. Explanation of Carcinogenicity:NONE Effects of Overexposure:REDNESS, TEARING, IRRITATION, CHILLS, FEVER, TIGHTNESS IN CHEST, COUGH, LEUKOCYTES. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LUKEWARM WATER FOR 15 MINUTES. SKIN: REMOVE W/WATERLESS CLEANER THEN WASH W/SOAP & WARM WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: KEEP WARM/QUIET. OBTAIN MEDICAL ATTENTION IN AL L CASES. ===================== Fire Fighting Measures ===================== Flash Point:150F Extinguishing Media:FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:AVOID USE OF WATER, BUT IF ONLY ALTERNATIVE, IMPLEMENT. USE WATER TO KEEP FIRE EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:RAGS & WASTE PAPER CONTAINING THIS MATERIAL MAY HEAT & BURN SPONTANEOUSLY. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: PICK UP W/ABSORBENT MATERIAL & TRANSFER INTO CLOSED METAL CONTAINERS & SOAKED W/WATER. LARGE: CAN BE SCOOPED UP & PUT INTO CONTAINERS & SALVAGED. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID ACCUMULATION OF CONTAMINATED RAGS/WIPING MATERIALS BY IMMEDIATE IMMERSION IN WATER, STORE IN METAL CAN W/TIGHT LIDS. Other Precautions:PREVENT REPEATED/PROLONGED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Ventilation:INTERMITTENT CLEAN AIR EXCHANGES Other Protective Equipment:EYE WASHES Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:0.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, CHLORIDE, CHLORINATED RUBBER Hazardous Decomposition Products:CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:CAREFULLY INCINERATE/USE SECURE LANDFILL/SPECIAL WASTE LANDFILL IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIGHTY GRIP, 361 Preparer's Name:DIANE L. GALLAGHER CAGE:FO660 CAGE:FO660 CAGE:73165 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL 2-CYANOACRYLATE (MFR CAS # 7085-85-0) CAS:708-85-0 Fraction by Wt: 95% Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: BALANCE ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:LIQUID CAUSES SKIN TO BOND VERY RAPIDLY TO ITSELF OR ALMOST ANYTHING ELSE WHICH IT CONTACTS. LIQUID IN EYES WILL CAUSE IRRITATION & CAN BOND EYELIDS VERY QUICKLY. EXPOSURE TO VAPOR MAY CAUSE IRRITATIO N OF MUCOUS MEMBRANES. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SKIN:POSSIBLE REDNESS, MILD IRRITATION. EYES:IRRITATION, REDNESS, TEARING. INHAL:IRRITATION OF NASAL MUCOUSA, POSSIBLE HEADACHE OR GIDDINESS IN SOME INDIVIDUALS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . SKIN:FLUSH IMMEDIATELY W/WATER. PROLONGED SOAKING IN WARM WATER MAY HELP LOOSEN BOND TO SKIN. EYES:FLUSH IMMEDIATELY W/WATER FOR AT LEAST 15 MIN HOLDING EYELIDS APAR T; GET MED ATTENTION. DO NOT FORCE BONDED EYELIDS APART. INHAL:MOVE TO FRESH AIR, CONSULT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:181F,83C Lower Limits:1.7% Extinguishing Media:USE DRY CHEMICAL OR CO*2. WATER SPRAY MAY RESULT IN HAZARDOUS POLYMERIZATION. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE Unusual Fire/Explosion Hazard:PYROLYSIS MAY RSLT IN FORM OF TOX FUMES. ADHESIVE IN ABSORB MATL MAY UNDERGO RAPID POLYMERIZATION & CAUSE TEMPERATURE INCREASE THAT COULD RSLT IN AUTOIGNITION. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES, USE CLOTHS OR INERT ABSORBENT MATERIAL TO ABSORB ADHESIVE. INCINERATE IMMEDIATELY OR STORE IN CLOSED METAL CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT, OPEN FLAMES OR IGNITION SOURCES. AVOID CONTACT WITH EYES, SKIN & CLOTHING. AVOID BREATHING VAPOR. Other Precautions:IF SKIN BONDING OCCURS, ATTEMPTS TO FORCE SEPARATION MAY RESULT IN LOCAL, MECHANICAL TISSUE DAMAGE. REPEATED SOAKING IN WARM WATER MAY AID IN LOOSENING THE BOND. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR IF VENTILATION IS INADEQUATE. Ventilation:LOCAL EXHAUST AS NEEDED. MECHANICAL:SATISFACTORY UNDER MOST CONDITIONS. Other Protective Equipment:COVERALLS OR APRON MAY BE USED TO REDUCE RISK OF CONTACT W/ADHESIVE. Work Hygienic Practices:FOLLOW NORMAL GOOD HOUSEKEEPING PRACTICES. Supplemental Safety and Health BP: 149F, 65C @ 6 MMHG. SOL IN H*2O:INSOLUBLE. WATER INITIATES RAPID POLYMERIZATION. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:SUPDAT Melt/Freeze Pt:M.P/F.P Text:-22F,-30C Vapor Pres:0.17 Vapor Density:4.34 Spec Gravity:1.05 (H*2O=1) Evaporation Rate & Reference:0.15 (BUTYL ACETATE =1) Solubility in Water:SUPDAT Appearance and Odor:CLEAR TO SLIGHTLY HAZY LIQ W/PUNGENT, UNPLEASANT ODOR. VAP MILDLY LACHRYMATORY. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIALS CAN CAUSE A VIGOROUS REACTION. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:COMBUSTION MAY RESULT IN CO, CO*2 AND NO*X AND POSSIBLE FORMATION OF TOXIC FUMES. Conditions to Avoid Polymerization:CONTAM OF ADHESIVE W/ACIDIC/BASIC MATLS, PEROXIDES/WATER CAN RSLT IN RAPID POLYMERIZATION W/UNCONTROLLABLE RISE IN TEMP. ==================== Disposal Considerations ==================== Waste Disposal Methods:USE CONTROLLED INCINERATION OR LANDFILL IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HUMISEAL 1A20 CAGE:EO647 CAGE:EO647 CAGE:99109 ============= Composition/Information on Ingredients ============= Ingred Name:POPYLENE GLYCOL METHYL EHTER ACETATE CAS:108-65-6 RTECS #:AI8295000 Fraction by Wt: 21-31% Other REC Limits:NONE SPECIFIED Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 16-22% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 208% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENEDIISOCYANATE (MIXED ISOMERS) (SARA III) CAS:26471-62-5 RTECS #:NQ9490000 Fraction by Wt: >1% Other REC Limits:NONE SPECIFIED OSHA PEL:0.02 PPM ACGIH TLV:0.005 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:PREPOLYMER RESIN Fraction by Wt: 48-52% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-IRRITATION OF EYES, NOSE, THROAT, LUNGS AND SKIN. CHRONIC-LUNG AND SKIN SENSITIZATION, CARDIAC ABNORMALITIES. Explanation of Carcinogenicity:TOLUENE DIISOCYANATE IS LISTED BY IARC, NTP OR OSHA AS A SUSPECT CARCINOGEN. Effects of Overexposure:COUGHING, CHOKING AND DIFFICULTY IN BREATHING, HEADACHE, DIZZINESS, DROWSINESS, FATIGUE, IRREGULAR HEARTBEAT, SKIN AND EYE IRRITATION. Medical Cond Aggravated by Exposure:PRE-EXISTING HEART, KIDNEY, LUNG AND SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:INGESTION-DO NOT INDUCE VOMITING. CONTACT PHYSICIAN OR POISON CONTROL IMMEDIATELY. INHALATION-REMOVE TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. EYE-FLUSH WITH LARGE AMOUNTS OF WATE R. IF IRRITATION CONTINUES, CONTACT PHYSICIAN. SKIN-WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:83.0F,28.3C Lower Limits:1.0 Upper Limits:7.0 Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER MAY BE INEFFECTIVE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP OR ABSORB WITH INERT MATERIAL. PREVENT RUN-OFF TO SEWERS. ELIMINATE IGNITION SOURCES. VENTILATE TO MAINTAIN EXPOSURE BELOW PEL'S. RESIDUE MAY BE CLEANED UP WITH ALCOHOL/WATER OR AMMONIA SOLUTI ON. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM SPARKS, FLAME AND HIGH HEAT SOURCES. DO NOT STORE ABOVE 120F. Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. USED CONTAINERS RETAIN RESIDUE., DO WELD, CUT OR HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ORGANIC VAPOR CARTRIDGE, NIOSH/MSHA APPROVED. Ventilation:USE MECHANICAL VENTILATION TO MAINTAIN EXPOSURE BELOW P.E.L. AND LOCAL EXHAUST IF NEEDED AS SUPPLEMENTAL VENTILATION. Other Protective Equipment:IMPERVIOUS CLOTHING/BOOTS AS NEEDED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING PRODUCT. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:280F,138C Vapor Pres:2.4-10 Vapor Density:>1 Spec Gravity:1.36 Evaporation Rate & Reference:<1 ( BU AC =1 ) Solubility in Water:NEGLIGIBLE Appearance and Odor:LOW VISCOSITY, STRAW COLORED LIQUID WITH AROMATIC ODOR. Percent Volatiles by Volume:48-52 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, POSSIBLY PHOSGENE AND HYDROGEN CHLORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1,BROMO-2,5-PYRROLIDINEDIONE, O-796 CAGE:84898 CAGE:84898 CAGE:8Y898 ============= Composition/Information on Ingredients ============= Ingred Name:2-BROMO-2,5-PYRROLIDINEDIONE CAS:128-08-5 RTECS #:WN2275000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(RAT) 256 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONT LENSES SHOULD NOT BE WORN IN LAB. ALL CHEM SHOULD BE CONSIDERED HAZ-AVOID DIRECT PHYSICAL CONT! CAN CAUSE EYE & SKIN IRRIT. CAN BE FATAL IF ABSORBED THRU SKIN! CAN BE HARMFUL IF INHALED. CAN BE H ARMFUL IF SWALLOWED. RPTD EXPOS TO VAP AND/OR DUST CAN CAUSE EYE INJURY. CAN BE IRRITATING TO MUC MEMB.(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:CAN CAUSE DELAYED LUNG INJURY. CAN CAUSE GI DISTURB. POSSIBLE CHOLINESTERASE INHIBITOR-MAY CAUSE SEIZURES; NAUS; VOMIT; AIRWAY OBSTRUCTION AND/OR INCR MUCOUS SECRETIONS IN LUNGS. INGEST MAY C AUSE SEV CORR OF MOUTH. CHRONIC EXPOS MAY CAUSE BRONCH. PRLNGD EXPOS MAY CAUSE NAUS/HDCH/DIZZ AND/OR EYE DAMAGE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:AN ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF A POIS. IT SHOULD BE ADMIN ONLY BY PHYS/TRAINED EMER PERS. MED ADVICE CAN BE OBTAINED FROM POIS CTL CTR. INGEST:CALL MD IMMEDIATELY . EYES: FLUSH CONTINUOUSLY W/WATER FOR @ LEAST 15 MINS. SKIN:FLUSH W/WATER FOR 15-20 MINS. IF NO BURNS HAVE OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL:REMOVE PATIENT TO FRESH AIR. ADMIN OXYG (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR APPROP OSHA-REGULATED EQUIP. VENTILATE AREA. SWEEP UP AND PLACE IN APPROP CNTNR. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE ANY RESIDUES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE APPROP NIOSH/MSHA APPRVD SFTY EQUIP. AVOID CONT W/SKIN, EYES & CLTHG. KEEP TIGHTLY CLSD & STORE IN COOL DRY PLACE. STORE ONLY W/COMPAT CHEMICALS. Other Precautions:THIS PRODUCT IS FURNISHED FOR LABORATORY USE ONLY! PRODUCTS MAY NOT BE USED AS DRUGS, COSMETICS, AGRICULTURAL OR PESTICIDAL PRODUCTS, FOOD ADDITIVES OR AS HOUSEHOLD CHEMICALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD. Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC:IF PATIENT IS HAVING DFCLTY BRTHG. IF PATIENT HAS STOPPED BRTHG ADMIN ARTF RESP. IF PATIENT IS IN CARD ARREST ADMIN CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL MED ASSISTANCE HAS ARRIV ED. EYE PROT:FULL LENGTH FACESHIELD ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:361F,183C Evaporation Rate & Reference:NOT KNOWN Solubility in Water:SLIGHTLY SOLUBLE Appearance and Odor:WHITE CRYSTALLINE SOLID, PUNGENT, ACRID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG BASES, STRONG ACIDS. INCOMPAT W/IRON & ZINC & OTHER LIGHT METALS. Stability Condition to Avoid:SENSITIVE TO LIGHT-DARK COLOR DOES NOT AFFECT PURITY. Hazardous Decomposition Products:DECOMPOSED BY MOISTURE. DECOMPOSITION LIBERATES TOXIC FUMES. DECOMPOSITION PRODUCTS ARE CORROSIVE. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STAINLESS STEEL AC-DC,DC LIME,DCT,DCT-2 COVERED ELECTRODES CAGE:KO380 CAGE:76254 CAGE:KO380 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 20-70% Other REC Limits:NONE RECOMMENDED Ingred Name:CHROMIUM (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 10-25% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NICKEL (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 0-30% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9495 Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 2-8% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9495 Ingred Name:FLUORSPAR (MFR LISTS INVALID CAS # 7789-75-5,WHICH FAILS PARITY CHECK) CAS:14542-23-5 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED Ingred Name:MANGANESE (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9495 Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 1-8% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST;9495 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 1-12% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9495 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: <2% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9495 Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (SARA 313) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 0-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9495 Ingred Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 0-4% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM. ACGIH TLV:10 PPM. Ingred Name:COPPER (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0-4% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:NIOBIUM (ALSO CALLED COLUMBIUM) CAS:7440-03-1 Fraction by Wt: 0-2% Other REC Limits:NONE RECOMMENDED Ingred Name:TUNGSTEN,AS W,SOLUBLE COMPOUNDS. CAS:7440-33-7 RTECS #:YO7175000 Fraction by Wt: 0-4% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOE ESTABLISHED ACGIH TLV:1 MG/M3/3 STEL; 9495 Ingred Name:SILICATE BINDERS Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:UNCLASSIFIED WELDING FUMES=5MG/M3 PEL Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES,MAY RESULT IN METAL FUME FEVER,DIZZINESS, NAUSEA, FEVER, DRYNESS AND/OR IRRITATION OF NOSE, THROAT AND EYES. SKIN SENSITIVITY MAY ALSO BE NOTED. ACUTE EXPOSURE FRO M SOME TOXIC GASES MAY CAUSE PULMONARY EDEMA, ASPHYXIATION AND EXCESSIVE EXPOSURE CAN BE FATAL.(SUPPL) Explanation of Carcinogenicity:NICKEL AND CHROMIUM ARE CONSIDERED POSSIBLE CARCINOGENS UNDER OSHA. RESPIRATORY CANCER FROM WELDING FUME IS UNCONFIRMED. Effects of Overexposure:EXPOSURE TO WELDING FUMES MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA, FEVER, DRYNESS AND/OR IRRITATION OF NOSE, THROAT AND EYES. SKIN SENSITIVITY MAY ALSO BE NOTED. WATERY EYES, HEADACHE, BREA THING DIFFICULTY, FREQUENT COUGHING AND/OR CHEST PAINS MAY OCCURE FROM ACUTE EXPOSURE. TOXIC GASES CAN BE FATAL. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING RESPIRATORY AILMENTS(EG.ASTHMA) AND WILSON'S DISEASE MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:IN CASE OF ELECTRICAL SHOCK, TURN OFF POWER PRIOR TO REMOVAL FROM EXPOSURE AREA AND ADMINISTRATION OF FIRST AID. REMOVE FROM EXPOSURE AREA AND CALL FOR MEDICAL AID. ADMINISTER OXYGEN IF BREATHING IS D IFFICULT. IF NOT BREATHING, BEGIN ARTIFICIAL RESPIRATION. IF NO DETECTABLE PULSE, BEGIN EXTERNAL HEART MASSAGE. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUES AND PLACE IN SUITABLE DOT APPROVED CONTAINERS AND DISPOSE OF IN FULL COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. AVOID INHALATION AND SKIN EXPOSU RE. ======================Handling and Storage ====================== CLOTHING WHEN CUTTING, GRINDING OR WELDING. DO NOT EXPOSE SKIN TO RADIATION WHEN HOT CUTTING OR WELDING. Other Precautions:PROVIDE PROTECTIVE SCREENS TO SHIELD OTHERS. WHEN ELECTRODES AND FLUXES ARE CONSUMED, THE FUME AND GAS DECOMPOSITION PRODUCTS GENERATED ARE DIFFERENT IN FORM FROM THE INGREDIENTS LISTED. NEW COMPOUNDS NOT IN THE ELECTRODES MAY FORM. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE WELD FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN CUTTING, GRINDING OR WELDING IN A CONFINED SPACE OR WHERE LOCAL EXHAUST OR GENERAL VENTILATION DOES NOT KEEP EXPOSURE BELOW RECOMMENDED LIMITS. USE ONLY NIOSH APPROVED RESPIRATORS. Ventilation:USE ENOUGH VENTILATION WHEN CUTTING, GRINDING OR WELDING TO KEEP THE DUST, FUMES & GASES FROM THE WORKERS BREATHING ZONE Other Protective Equipment:FLAME RETARDANT CLOTHING WHEN CUTTING, GRINDING OR WELDING. DO NOT EXPOSE SKIN TO RADIATION WHEN HOT CUTTING OR WELDING. Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING OR SMOKING. LAUNDER CONTAMINATIED CLOTHING BEFORE REUSE. Supplemental Safety and Health HEALTH HAZARD(CONT'D):ARC RAYS CAN INJURE EYES AND BURN SKIN.ELECTRIC SHOCK CAN KILL.CHRONIC EXPOSURE TO WELDING FUMES CAN CAUSE SIDEROSIS(IRON DEPOSIT IN LUNGS),OSTEOPOROSIS,PNEUMONCONIOSIS.CHLORINAT ED SOLVENTS MAY DECOMPOSE TO TOXIC GASES.TO CHOOSE CORRECT LENS,PICK ONE SHADE LOWER THAN REQD TO BLOCK OUT ALL LIGHT. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:INSOLUBLE Appearance and Odor:WELDING ROD,1/8"DIAM.,14" LENGTH. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:IRON OXIDES AND FLUORIDES,OXIDES OF MG,CR,NI,CA,SI,TI,MO,AL,CU,COLUMBIAN,TUNGSTEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SODIUM HYDROSULFITE CAGE:63415 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROSULFITE RTECS #:JP2100000 Fraction by Wt: 99% ACGIH TLV:NOT GIVEN ===================== Hazards Identification ===================== Effects of Overexposure:CAN CAUSE BURNS TO SKIN OR EYES. ======================= First Aid Measures ======================= First Aid:EYE-FLUSH W/WATER. SKIN-WASH W/SOAP & WATER. INGEST-IMMED CALL DOC. EMPTY STOMACH BY LAVAGE W/MILK,SOAPY WATER OR TAP WATER. KEEP WARM & QUIET UNTIL MED ASSIST ARRIVES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY SAND,SODA ASH,CARBON DIOXIDE Fire Fighting Procedures:USE GAS MASK W/ACID CANISTER FOR SO*2 OR AIR-PAK Unusual Fire/Explosion Hazard:SML AMTS OF WATER OR HIGH HUMIDITY IN PRESENCE OF AIR CAUSE FIRE OR CREATE TEMPS TO IGNITE COMB MATL ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP ALL SPILLAGE. WASH DOWN AREA INTO A CHEMICAL SEWER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY PLACE AWAY FROM OXIDIZING CHEM & ACIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST MASK Other Protective Equipment:EYEWASH FOUNTAIN Supplemental Safety and Health MSDS DTD 3/87. VERY STRONG REDUCING AGENT. FIRE RISK IN CONTACT W/MOISTURE. ================== Physical/Chemical Properties ================== HCC:R1 NRC/State Lic Num:NOT RELEVANT Solubility in Water:18% Appearance and Odor:WHITE TO LIGHT YELLOW CRYSTALS,MILD SULFUR DIOXIDE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALL OXIDIZING & ACIDIC MATLS. Stability Condition to Avoid:MOISTURE & EXCESSIVE HEAT (ABOVE 120F) Hazardous Decomposition Products:SULFUR DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:WASH DOWN W/WATER INTO A CHEMICAL SEWER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZL-22D ZYGLO PENETRANT Kit Part:Y Preparer's Name:BRUCE C. GRAHAM CAGE:37676 CAGE:37676 ============= Composition/Information on Ingredients ============= Ingred Name:DISTILLATES,(PETROLEUM)HYDROTREATED MIDDLE CAS:64742-46-7 RTECS #:JN9379645 Fraction by Wt: 25.0% Ingred Name:KEROSENE CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: 10.0% ACGIH TLV:100MG/CUM Ingred Name:DISTILATES(PETROLEUM),CATALYTIC REFORMER FRACTIONER RESIDUE,LOW BOILING CAS:68477-31-6 Fraction by Wt: 20.0% Ingred Name:UNIDENTIFIED COMPONENTS Fraction by Wt: 45.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATES EYES,MILDLY. Effects of Overexposure:INHALATION:SPRAY MIST MAY IRRITATE THE BREATHING PASSAGES; EYES:LIQUID CONTACT MAY CAUSE IRRITATION; SKIN:SOLVENT IN THE PRODUCT MAY IRRITATE SKIN; INGESTION:NOT NOTED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NOT STATED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR.IF BREATHING IS DIFFICULT,GIVE OXYGEN; SKIN:REMOVE CONTAMINATED CLOTHES.WASH OFF WITH FLOWING WATER.USE SOOTHING LOTION.IF IRRITATION PERSISTS,GET MEDICAL ATTN; EYES:IMM EDIATELY RINSE/FLUSH WITH COPIOUS AMOUNT OF RUNNING WATER,AND GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F/>93C Extinguishing Media:CARBON DIOXIDE,FOAM. Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY.DO NOT SPRAY ON BURNING PRODUCT. Unusual Fire/Explosion Hazard:WHEN INVOLVE IN COMBUSTION,MAY EMIT TOXIC GASES AT OR ABOVE DECOMPOSITION TEMPERATURE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES.SM QTY:WIPE UP OR MOP UP BUT DO NOT BREATHE VAPORS.PLACE RAGS IN CLOSED DRUMS; LG QTY:WEAR PERSONAL SAFETY EQUIPMENTS.DIKE AREA FAR AHEAD.ABSORB LIQUID WITH COMMERCIAL ABSORBEN T.TRANSFER WASTE MATL IN SALVAGE TANKS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT SOURCES IN WELL VENTILATED AREA.AVOID AGAINST PHYSICAL DAMAGE TO CONTAINERS.KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:DO NOT BREATHE VAPORS.DO NOT SMOKE WHILE USING.DO NOT HEAT ABOVE 130F(54C).AVOID FREQUENT OR PROLONGED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A RESPIRATOR WITH CHEMICAL CARTRIDGE. IN CONFINED AREAS,WEAR A FULL MASK WITH SEPARATE AIR SUPPLY. Ventilation:GENERAL VENTILATION TO KEEP BELOW 350PPM LIMIT. Other Protective Equipment:EITHER USE IN A SPRAY BOOTH OR NEXT TO AN EXHAUST VENT. Work Hygienic Practices:WASH OFF PROMPTLY WITH WATER.AVOID SKIN CONTACT. Supplemental Safety and Health PER QPL-25135-15 OF MIL-I-25135D,THE SET MAY CONSIST OF ZL-22D OR ZL-27A PENETRANT AND ZE-3 OR ZE-4B EMULSIFIER UNDR TYPE I METHOD B,LEVEL 3;THIS NSN HAS 2 PARTS IN THE SET;THESE EMULSIFIERS & PENETRA NTS ARE ALSO QUALIFIED PRODUCTS OF OTHER TYPES,METHODS & LEVELS.SEE THE QPL;THIS ENTRY OF ZL-22D PENETRANT;KEY1:N1. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:410F/210C Vapor Pres:0.5 @100F Vapor Density:>1.0 Spec Gravity:0.95 Solubility in Water:NEGLIGIBLE Appearance and Odor:GREEN LIQUID WITH PETROLEUM DISTILLATE ODOR. Percent Volatiles by Volume:5.0% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MFR STATED "NONE". Stability Condition to Avoid:HEAT,HIGH TEMPERATURES. Hazardous Decomposition Products:EMITS OXIDES OF CARBON AND NITROGEN ON COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR DISPOSE OF AS EPA HAZARDOUS WASTE D001 (IGNITABLE WASTE),IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,STATE,LOCAL REGULATIONS;IF LOCAL AUTHORIES PROHIBIT DUMPING RINSINGS DOWN THE SEWER,PUR IFY RINSINGS W/MAGNAFLUX WASTEWATER TREATMNT SYSTM
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MARINE DIESEL FUEL (F76) Preparer's Name:STEPHEN A. ELBERT CAGE:15958 CAGE:15958 ============= Composition/Information on Ingredients ============= Ingred Name:DIESEL FUEL (CAS NO SPECIFIED BY MFR; NIOSH NO BY HMIS) CAS:68476-30-2 RTECS #:HZ1770000 Fraction by Wt: 100% Other REC Limits:HMIS:100 PPM/5 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS A MILD IRRITANT. MOST HAZARDOUS EXPOSURE IS TO AIRBORN MIST OR OTHER ASPIRATION OF LIQUID INTO LUNGS. PROLONGED/REPEATED OVEREXPOSURE MAY CAUSE LIVER OR KIDNEY DAMAGE. Explanation of Carcinogenicity:API HAS DONE STUDIES INDICATING THAT REPEATED OVER EXPOSURE MAY CAUSE CANCER IN MICE. Effects of Overexposure:EYE:MILD IRRITATION. SKIN:DRYING,DEFATTING WITH PROLONGED/REPEATED CONTACT. INHALED:HEADACHE,NAUSEA,CONFUSION,DROWSINESS. ASPIRATION OF LIQUID MAY CAUSE CHEMICAL PNEUMONITIS. INGESTED:G/I IRRITATION,N AUSEA,POSSIBLE VOMITING. Medical Cond Aggravated by Exposure:NONE EXPECTED. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:REMOVE CONTAMINATED CLOTHING (LAUNDER BEFORE REUSE) AND THOROUGHLY WASH AREA OF CONTACT WITH SOAP AND WATER. INHALED:REMOVE FROM EXPOSURE. RESUSCITATE OR GIVE OXYGEN IF NEEDED THEN GET MEDICAL ATTENTION. INGESTED:DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION. IF ANY IRRITATION PERSISTS OR IS SEVERE,GET MEDICAL CARE. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:120F-180F Lower Limits:0.6 Upper Limits:7.4 Extinguishing Media:FOAM,CARBON DIOXIDE,DRY CHEMICAL,WATER FOG. WATER MAY BE INEFFECTIVE AND MAY SPREAD FIRE IF IMPROPERLY USED. Fire Fighting Procedures:USE SELF CONTAINED BREATHING APPARATUS,ESPECIALLY IN ENCLOSED AREAS. WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED CONTAINRS AND EQUIPMENT. Unusual Fire/Explosion Hazard:WHEN HEATED SUFFICIENT,VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. SATURATED NEWSPAPERS,RAGS,ETC. MAY UNDERGO SPONTANEOUS COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. USE APPROPRIATE PROTECTIVE EQUIPMENT. CONTAIN LEAK.PREVENT LEAK FROM ENTERING SEWER,WATER WAY,ETC. RECOVER AS LIQUID. REPORT SPILL IF APPROPRIATE. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL AREA AWAY FROM OXIDIZERS AND IGNITION SOURCES. DETACHED STORAGE PREFERRED. GROUND CONTAINERS DURING TRANSFER. Other Precautions:"EMPTY" CONTAINERS MAY CONTAIN RESIDUE AND/OR FUMES WHICH ARE EXPLOSIVE. DO NOT CUT,WELD,ETC. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT EXPECTED TO BE NECESSARY. USE NIOSH/MSHA RESPIRATOR IF PRODUCT IS MISTED OR IF TLV/PEL IS EXCEEDED. Ventilation:USE LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV/PEL IF NORMAL ROOM VENTILATION IS IN SUFFICIENT. Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PRACTICE.AVOID UNNECESSARY CONTACT. Supplemental Safety and Health SPECIFICATION CALLS FOR MINIMUM FLASH POINT OF 140F. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:340F-675F Spec Gravity:0.88 Evaporation Rate & Reference:NEGLIGIBLE Appearance and Odor:CLEAR AMBER LIQUID, KEROSENE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:HEAT,IGNITION SOURCES. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. INCINERATION IS RECOMMENDED FOR DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:169-175 CONCORDE Preparer's Name:DICK KARBO CAGE:KMADD CAGE:KMADD ============= Composition/Information on Ingredients ============= Ingred Name:BARIUM COMPOUNDS Fraction by Wt: 21% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN CAUSE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F Extinguishing Media:FOAM, CO2, DRY CHEMICAL ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS. Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:LOCAL EXHAUST Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS USED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:470-610F Evaporation Rate & Reference:SLOWER THAN WATER Solubility in Water:INSOLUBLE Appearance and Odor:OILY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: A-S ACCELERATOR Cage: IO136 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: IO136 Box: 322 Cage: 84697 Box: 322 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:NAUS &/NARCOSIS. CHRONIC:CNTNS LEAD. PRLNGD SKIN CONT MAY CAUSE IRRIT IN SOME PERS. EXCESS INGEST MAY CAUSE METAL TASTE, MUSCLE ACHES, ABDOM PAINS & WEAK. EXCESS EXPOS TO LEAD MAY EFT CIRCULATOR Y, NERV & DIGEST SYS. DMG TO KIDNEYS MAY OCCUR W/OUT SYMPS. LEAD MAY CAUSE DELAYED EFTS OF BLOOD, GI,(EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ:NERV & REPRO SYS. TOLUOL, BASED ON ANIMAL DMG MAY CAUSE LIVER ABNORMS, KIDNEY, LUNG & SPLEEN DMG. HUMANS LIVER ABNORMS. NOTE:CONTAINS MATL WHICH APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZAR DS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HNDLG & EXPOS (SUPDAT) Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: SKIN: WASH W/SOAP & WATER. GET MEDICAL ATTN. EYES: FLUSH ABUNDENTLY W/CLEAN WATER & REFER TO MD. INGEST: DO NOT INDUCE VOMITING. REFER TO MD. INHAL: REMOVE PATIENT TO FRESH AIR/GIVE OXYGEN. USE ARTF R ESP IF PATIENT IS NOT BREATHING. REFER TO MD. UTILIZE THE SUGGESTED METHODS BELOW. IN EMERGENCY SITUATIONS NOTIFY MD IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ABSORB SPILL IN SAND, EARTH, VERMICULITE, OIL-DRI, OR SOL-SPEED-DRY. SHOVEL ABSORBED MATERIAL INTO STEEL CNTNR AND COVER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL CHEMICAL AND SOLVENT WASTE DISPOSAL REGULATIONS. Handling And Storage Precautions: STORE IN APPRVD SOLVENT STORAGE AREA. KEEP TIGHTLY CLOSED AWAY FROM HEAT OPEN FLAMES, SPARKS, HOT SURFACES AND OZIDIZING AGENTS. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: 40.0F,4.4C Lower Limits: 1.0% Upper Limits: 7.0% Extinguishing Media: CO*2, FOAM, DRY CHEMICAL. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT(FP N). USE WATER SPRAY TO COOL FIRE EXPOSED STRUCTURES & DISPERSE VAPOR CLOUD IF FIRE IS NOT PRESENT. Unusual Fire/Explosion Hazard: VAPOR IS HVR/THAN AIR & MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION & FLASHBACK. MAY LIBERATE TOXIC(LEAD) FUMES WHEN BURNING. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH/MSHA APPROVED ATMOSPHERE SUPPLYING/AIR PURIFYING RESPIRATOR FOR ORGANIC VAPORS AS REQUIRED TO MAINTAIN EXPOSURE LEVELS BELOW RECOMMENDED LIMITS. Ventilation: LOC EXHST: REMOVE VAPS DURING PROCESSING. MECH EXHST: EXPLOS-PROOF EQUIP. SPEC: REDUCE VAP CONC BELOW SPEC LIMITS. Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER(FP N). FULL PROTECTIVE CLOTHING AS REQUIRED TO PREVENT SKIN CONTACT. Work Hygienic Practices: WASH THORO AFTER HNDLG, ESPEC BEFORE EATING, DRINKING/SMOKING. DO NOT USE NEAR FOOD/FEED PRODS. CONTAMD CLTHG &(SUPDAT) Supplemental Safety and Health: USERS OF THE "L" VERSION OF TO CONSULT THE "LR" VERSION FOR FURTHER INFO(FP N). EFTS OF OVEREXP: INFORMATION(FP N). HYGIENE PRAC: SHOES SHOULD NOT BE WORN HOME. KEEP AREA CLEAN. CLEAN UP SPILLS I MMED. PRACTICE GOOD PERSONAL HYGIENE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 231F,111C Vapor Pres: 22 @ 20C Vapor Density: 3.2 Spec Gravity: 1.65 Appearance and Odor: YELLOW W/CHARACTERISTIC SOLVENT ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AVOID HEAT, OPEN FLAMES, SPARKS, HOT SURFACES. Materials To Avoid: OXIDIZING AGENTS. Hazardous Decomposition Products: OXIDES OF CARBON, LEAD, NITROGEN. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: A-S ACCELERATOR Cage: IO136 Assigned IND: Y Company Name: HAARTZ-MASON INC Street: 270 PLEASANT ST PO Box: 322 Zipcode: 02172 Label Required IND: Y Date Of Label Review: 05/31/1996 Status Code: C Label Date: 05/31/1996 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE:NAUSEA AND NARCOSIS, IRRITATION TO EYES AND MUCOUS MEMBRANES, SKIN DRYNESS. CHRONIC:CONTAINS LEAD AND TOLUENE WHICH ARE LISTED ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N). SKIN:IRRITATION. INGESTION:METALLIC TASTE IN MOUTH, MUSCLE ACHES, ABDOMINAL PAIN, WEAKNESS. DAMAGE TO KIDNEYS, CIRCULATORY, NERVOUS AND DIGESTIVE SYSTEM. =======================================================
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eyes_protection_mandatory