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===================== Product Identification ===================== Product ID:PROTECTIVE TOP COAT, PSI-3 Kit Part:Y CAGE:PLATI CAGE:PLATI ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA) (VAPOR PRESSURE 0.1 MM HG @ 77F) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 2% Other REC Limits:NONE RECOMMENDED ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ESTER ALCOHOL (VAPOR PRESSURE 1.0 MM HG @ 189F) CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:COATING VOC: 92 LB/GL (110 G/L) RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE IRRITATION TO SKIN, EYES, AND INTESTINAL SYSTEM. CHRONIC: PROLONGED OR REPEATED EXPOSURE ABOVE TLV MAY RESULT IN PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Effects of Overexposure:INHALATION: NOSE, THROAT, RESPIRATORY TRACT IRRITATION (HEADACHE, NAUSEA). EYE: IRRITATION. SKIN: PROLONGED & REPEATED CONTACT WITH PRODUCT MAY CAUSE SKIN IRRITATION. ABSORPTION: REDNESS, DRYING SKIN, OR OTHER SIGNS OF IRRITATION OR CONTACT DERMATITIS. INGESTION: GI IRRITATION, NAUSEA, VOMITING, AND DIARRHEA. Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER AT LEAST 15 MINUTES. TAKE TO PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. REMVOE CONTAMINATED CLOTHING. IF IRRITATION PERSISTS, CONSULT PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. CONSULT PHYSICIAN. INGESTION: DRINK 1 OR 2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:247F,119C Lower Limits:0.6 Upper Limits:4.2 Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:COOL CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:CLOSED CONTAINER EXPOSED TO HIGH TEMPERATURES MAY EXPLODE OR BURST DUE TO BUILD UP OF STEAM PRESSURE. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE, CONTAIN, OR ABSORB WITH INERT MATERIALS. TRANSFER TO CONTAINER FOR RECOVERY OR DISPOSAL. PREVENT RUNOFF INTO SEWERS, STREAMS, OR OTHER BODIES OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT EXPOSE TO EXTREME IN TEMPERATURE. AVOID EXPOSURE TO HIGH TEMPERATURES. DO NOT ALLOW TO FREEZE. Other Precautions:DO NOT TAKE INTERNALLY. AVOID PROLONGED OR REPEATED EXPOSURE TO LEVELS ABOVE TLV. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. IF TLV IS EXCEEDED USE NIOSH/MSHA APPROVED ORGANIC VAPOR AND MIST, SUPPLIED AIR, OR SELF CONTAINED BREATHING APPARATUS. Ventilation:USE ADEQUATE MECHANICAL (GENERAL AND/OR LOCAL) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:WEAR IMPERVIOUS CLOTHING. EYEWASH STATION. Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING RESTROOMS. REMOVE AND WASH ALL CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:387 TO 471F Vapor Density:< AIR Spec Gravity:1.3 (H2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:COMPLETE Appearance and Odor:TYPICAL FOR WATER BASED PAINTS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS, CARBON DIOXIDE, CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC. ON THERMAL DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:M-D TRU-TEST PAINTER'S SELECT VINYL-ACRYLIC LTX HOUSE PAINT CAGE:TRUTE CAGE:TRUTE ============= Composition/Information on Ingredients ============= Ingred Name:VOL ORGANIC CMPD: <250 G/L RTECS #:9999999VO Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <5% Other REC Limits:10 MG/CUM OSHA PEL:50 PPM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF EYES, NOSE, THROAT, & MUCOUS MEMBRANES OF RESPIRATORY TRACT. SKIN/EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: IRRITATION TO EYES, NOSE, THROAT, & MUCOUS MEMBRANES OF RESPIRATORY TRACT. SKIN/EYES: IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYES: FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER. INGESTION: GIVE 2 GLASSES OF WATER TO DILUTE. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENT ION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:WATER MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE OR BUILD-UP PRESSURE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE & CONTAIN SPILL W/INERT MATERIAL SUCH AS SAND OR EARTH. TRANSFER THE LIQUID TO CONTAINERS FOR RECOVERY OR DISPOSAL. KEEP SPILL OUT OF SEWERS & OPEN BODIES OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. AVOID CONTACT W/SKIN & EYES. DON'T TAKE INTERNALLY. AVOID INHALATION OF VAPORS OR SPRAY MISTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN BRUSHED OR ROLLED NONE REQUIRED IF GOOD VENTILATION MAINTAINED. DURING SPRAY APPLICATION, AN APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE AIRBORN PARTICLES OF OVERSPRAY IS REQUIRED. Ventilation:SUFFICIENT TO KEEP <TLV. Other Protective Equipment:EYE WASH FACILITY, PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING, OR USING WASHROOM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Density:<AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:VARIES W/COLOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXTREME HEAT & FREEZING ==================== Disposal Considerations ==================== Waste Disposal Methods:LIQUID MATERIAL & CONTAMINATED DIKING MATERIAL SHOULD BE LANDFILLED ACCORDING TO CURRENT LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5112 (QUART), MAR-HYDE SINGLE STAGE SELF (SUPDAT) CAGE:71344 CAGE:71344 CAGE:42400 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA). VP:70. CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 45-50% OSHA PEL:200 PPM ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, ISOBUTYL ESTER; (ISOBUTYL ACETATE) (CERCLA). VP:12.8. CAS:110-19-0 RTECS #:AI4025000 Fraction by Wt: 20-25% OSHA PEL:150 PPM ACGIH TLV:150 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-HEPTANONE; (METHYL AMYL KETONE). VP:2.14. CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 5-10% OSHA PEL:100 PPM ACGIH TLV:50 PPM Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:22. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 0-5% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 0-5% OSHA PEL:20 MPPCF ACGIH TLV:2 MG/M3 RDUST Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0-5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SUPDAT:LEVELS >1000 PPM (5 TIMES GREATER THAN TLV) FOR MOST OF GESTATION PERIOD. NOTE:TOLUENE APPEARS ON NAVY (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:INFO & SAFE HANDLING & EXPOSURE INFO . RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:PREVENT PROLONGED OR REPEATED CONTACT OF WET MATERIAL W/SKIN. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYES:CONT W/LIQ OR VAP MAY RSLT IN IRRIT, REDNESS, TEARING & BLURRED VISION. SKIN:CONT W/WET MATL MAY RSLT IN IRRIT, DERM & POSS DEFAT. INHAL:EXCESSIVE INHAL OF VAPS MAY CAUSE NASAL & RESP IRRIT , ACUTE NERV SYS DEPRESS, FATG, WEAK, NAUS, HDCH, DIZZ, POSS UNCONS & EVEN ASPHY. INGEST:INGEST OF THIS(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:MATL MAY CAUSE GI IRRIT, NAUS, DIARR & VOMIT. ASPIR OF MATL INTO LUNGS DUE TO VOMIT MAY PRDCE CHEM PNEUM WHICH CAN BE FATAL. CHRONIC:EXCESSIVE OVEREXP TO COMPONENTS OF THIS MATL HAS BEEN SUGG ESTED TO CAUSE LIVER ABNORMS IN HUMANS.OVEREXP TO COMPONENTS OF THIS MATL HAS ALSO BEEN FOUND TO CAUSE (SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH IMMED W/LG AMTS OF WATER FOR AT LST 15 MINS. TAKE TO MD FOR MED TREATMENT. SKIN:IMMED WASH AFFECTED AREA W/SOAP & WATER. REMOVE CONTAM CLTHG. CONSULT MD IF IRRIT DEVELOPS. INHAL:REMOVE PERS TO FRESH AIR. RESTORE BRTHG. KEEP PERSWARM & QUIET. TREAT SYMPTOMATICALLY. GET MED ATTN. INGEST:DRINK 1-2 GLASSES OF WATER TO DILUTE. KEEP PERS WARM & QUIET. CONSULT MD/POIS CTL CTR IMMED. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:23.0F,-5.0C Lower Limits:1.1% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CONTAINERS TO PREVENT PRESSURE BUILD-UP & POSSIBLE EXPLOSION. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID - CLASS 1B. VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG FLOOR & BE IGNITED BY SPARKS OR FLAMES AT A DISTANCE FROM WHERE MATL IS BEING USED. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. WEAR PROTECTIVE EQUIPMENT. AVOID BREATHING VAPORS. CONTAIN SPILL, ABSORB EXCESS W/DRY INERT MATERIAL & REMOVE PROMPTLY W/NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE MATERIAL IN A COOL, WELL-VENTILATED AREA. DO NOT STORE AT TEMPERATURES ABOVE 120F. DO NOT USE OR STORE NEAR HEAT, SPARKS OR OPEN FLAME. Other Precautions:KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS DESIGNED TO REMOVE PARTICULATE MATTER & ORGANIC SOLVENT VAPORS. Ventilation:GENERAL DILUTION/LOC EXHST VENT SHOULD BE PROVIDED TO KEEP EXPOS BELOW ACCEPT LIMS & TO KEEP SOLV VAPS BELOW LEL. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . IMPERMEABLE CLTHG SHOULD BE WORN TO (ING 10) Work Hygienic Practices:ALWAYS WASH HANDS AFTER USING THIS MATERIAL & BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:ETCHING PRIMER. HAZ DECOMP PROD:CARBON DIOXIDE & VARIOUS HYDROCARBONS. EFTS OF OVEREXP:FOLLOWING EFTS IN LAB ANIMALS:LIVER ABNORMS, KIDNEY DMG, LUNG DMG, SPLEEN DMG & BRAIN DM G. MINOR EMBRYOTOXIC/ FETOTOXIC EFTS HAVE BEEN OBSERVED IN LAB RATS EXPOS TO METHYL ETHYL KETONE BY INHAL AT (ING 7) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>175F,>79C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.92 Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:87.478 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURES & SOURCES OF IGNITION. Hazardous Decomposition Products:HAZ FUMES MAY BE PRDCD WHEN MATL IS HEATED TO DECOMP. FUMES MAY CONTAIN HYDROGEN CHLORIDE, CARBON MONOXIDE, (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS. BEFORE ATTEMPTING CLEAN-UP OR DISPOSING OF MATERIAL, REFER TO HAZARD INFORMATION IN OTHER SECTIONS OF THIS MSDS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:220A110, 5-STAR RUST-STOP METAL ENAMEL DOVE CAGE:ACEHA CAGE:ACEHA ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL,2-PROPOXY-; (N-PROPOXY ETHANOL). VP: 0.6 CAS:2807-30-9 RTECS #:KM2800000 Fraction by Wt: <1% OSHA PEL:50 PPM (MFR) ACGIH TLV:50 PPM (MFR) Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRIT). VP: 2 CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 36% OSHA PEL:500 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS 140 FLASH). VP: 0.5 CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 3.5% OSHA PEL:500 PPM (MFR) ACGIH TLV:100 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION IS ANESTHETIC. IRRITATION OF RESPIRATORY TRACT OR NERVOUS SYSTEM DEPRESSION. HEADACHE, DIZZINESS, NAUSEA, CONFUSION, UNCONSCIOUSNESS OR COMA. SKIN/EYE: PRIMARY IRRITATION. REPORTS HAVE ASSO C RPTD & PRLNGD OCCUPATIONAL OVEREXP TOSOLVENTS WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOSURE, RESTORE BREATHING, KEEP WARM AND QUIET, CALL MD. EYES: FLUSH IMMEDIATELY WITH RUNNING WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP AND WATER AND APPLY SKIN CREAM. C ALL MD IN ALL CASES. INGEST: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:105F,41C Lower Limits:0.9% Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMP MAY NOT BE IMMED APPARENT. (SUPP DATA) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIPMENT, SPARKS & OPEN FLAME. HEAT MAY CAUSE PRESSURE BUILD-UP IN CLOSED CNTNRS, WATER MAY BE USED TO COOL. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DOL STORAGE CATEGORY 2. CONTENTS ARE COMBUSTIBLE, KEEP AWAY FROM HEAT AND OPEN FLAME. USE ONLY WITH ADEQ VENT. USE APPRVD BONDING & GROUNDING PROC. Other Precautions:AVOID BRTHG VAP AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT TRANSFER CONTENTS TO OTHER CONTAINERS FOR STORAGE. DO NOT TAKE INTERNALLY. KEEP OUT OF R EACH OF CHILDREN. CONSULT NFPA CODE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING AND ADMINISTRATIVE CONTROL OF AIR CONTAMINANTS ARE NOT POSSIBLE, USE RESPIRATORY DEVICES APPROVED BY NIOSH/ MSHA FOR PROTECTION AGAINST SPRAY MIST AND VAPORS. Ventilation:LOCAL EXHAUST PREFERABLE. MECHANICAL (GENERAL) EXHAUST ACCEPTABLE. SPECIAL VENTILATION REQUIRED TO KEEP BELOW TLV & LEL. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING, DISCARD CONTAMINATED SHOES. WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:CALL MD. WATER SPRAY MAY BE INEFT. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>308F,>153C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Spec Gravity:1.12 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:60.65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:HIGH TEMPERATURES, OPEN FLAME. Hazardous Decomposition Products:BY FIRE: CO2 AND CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KERMAC 210-245 NAPHTHA CAGE:6G213 CAGE:0WA27 CAGE:6G213 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHA, LIGHT ALIPHATIC CAS:64742-89-8 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM (PET. DIST) ACGIH TLV:300 PPM (VM & P) Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <0.1% Other REC Limits:NONE RECOMMENDED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE AND SKIN IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS. ASPIRATION AFTER INGESTION MAY CAUSE PNEUMONITIS. CHRONIC: DERMATITIS. Explanation of Carcinogenicity:NONE OF THE INGREDIENTS IN THIS PRODUCT IS LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYES/SKIN: IRRITATION. INHALATION: HEADACHE, NASAL AND RESPIRATORY IRRITATION, NAUSEA, DROWSINESS, BREATHLESSNESS, FATIGUE, CENTRAL NERVOUS SYSTEM DEPRESSION, CONVULSIONS, AND LOSS OF CONSCIOUSNESS. I NGESTION: ASPIRATION HAZARD, AND SAME SYMPTOMS AS INHALATION. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, SEE DOCTOR. SKIN: WASH WITH SOAP AND WATER WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. INHALATION: REMOVE VICTIM T O FRESH AIR. GIVE OXYGEN/CPR IF NEEDED.SEE DOCTOR. INGESTION: DO NOT INDUCE VOMITING. SEE DOCTOR IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:25.0F,-3.9C Lower Limits:1 Upper Limits:8 Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER STREAMAY SPREAD FIRE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. VAPORS CAN TRAVEL AND FLASHBACK. EXPLOSION HAZARD IN FIRE SITUATION. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE PERSONNEL. ELIMINATE IGNITION SOURCES. VENTILATE AREA. WEAR PROTECTIVE CLOTHING AND EQUIPMENT. ABSORB IN INERT MATERIAL AND PLACE IN APPROPIATE DISPOSAL CONTAINER AND COVER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE, HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. KEEP CONTAINERS CLOSED. Other Precautions:AVOID EYE AND SKIN CONTACT. DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA-APPROVED RESPIRATOR OR SCBA AS APPROPIATE FOR EXPOSURE OF CONCERN. Ventilation:MECHANICAL (GENERAL) VENTILATION OR LOCAL EXHAUST VENTILATION TO KEEP EXPOSURE LEVELS BELOW PEL. Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT. EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:200-250F Vapor Pres:827 Vapor Density:3-4 Spec Gravity:0.72 Evaporation Rate & Reference:0.14 (ETHYL ETHER = 1) Solubility in Water:NEGLIGIBLE Appearance and Odor:WATER WHITE LIQUID. PETROLEUM NAPHTHA ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, INCOMPLETELY BURNED CARBON PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3640301 IVOSEAL (LIQUID) Preparer's Name:BUECHEL CAGE:65413 CAGE:6S413 CAGE:65413 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 40.00% Other REC Limits:1900 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MUCOUS MEMBRANE IRRITATION. SKIN: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: MUCOUS MEMBRANE IRRITATION. SKIN: IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR, SEEK MED ATT. IF NECESSARY. INGESTION: DILUTE W/WATER, SEEK MED ATT. EYES: FLUSH W/WATER FOR 20 MINUTES, SEEK MED ATT. SKIN: WASH AFFECTED AREA W/SOAP & WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:54.4F Lower Limits:3.3% Upper Limits:19% Extinguishing Media:FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SPREAD INERT ABSORBANT & COLLECT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED Ventilation:USE LOCAL EXHAUST VENTILATION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:78.5C Vapor Density:>1.6 Spec Gravity:0.89 Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS LIQUID; ALCOHOL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS Stability Condition to Avoid:HEAT Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ACCORDING TO LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PA-80-70 BREATHING APPARATUS CAGE:53833 CAGE:53833 ============= Composition/Information on Ingredients ============= Ingred Name:OXYGEN, COMPRESSED CAS:7782-44-7 RTECS #:RS2060000 Fraction by Wt: 19.5-23% Ingred Name:NITROGEN CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: 77-80.5% ACGIH TLV:ASPHYXIANT; 9192 Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 0.1% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 Ingred Name:CARBON MONOXIDE CAS:630-08-0 RTECS #:FG3500000 Fraction by Wt: 0.002% OSHA PEL:50 PPM ACGIH TLV:25 PPM; 9293 Ingred Name:MOISTURE CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: TRACE ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS NOT APPLICABLE. Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: NONE AT ATMOSPHERIC PRESSURES. CHRONIC: NONE. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:NONE Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:NOT APPLICABLE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG AS APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CYLINDERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:CYLINDERS MAY BURST WHEN EXPOSED TO HEAT OF FIRE. OXIDIZING ATMOSPHERE INCREASES THE LIKELIHOOD OF FIRES. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONNEL FROM RELEASE AREA. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT CYLINDERS FROM PHYSICAL DAMAGE. STORE AWAY FROM EXTREME HEAT. KEEP CYLINDER VALVES CLOSED WHEN NOT IN USE AND WHEN EMPTY. Other Precautions:DO NOT DEFACE CYLINDERS OR LABELS. HANDLE CYLINDERS WITH PROPER CAUTION. ============= Exposure Controls/Personal Protection ============= Other Protective Equipment:SAFETY SHOES AND HEARING PROTECTION. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. USE PROPER CARE WHEN HANDLING AND STORING CYLINDERS. Supplemental Safety and Health THIS IS GRADE D BREATHING AIR WHICH MEETS THE SPECIFICATIONS OF THE COMPRESSED GAS ASSOCIATION. ================== Physical/Chemical Properties ================== HCC:G3 Vapor Pres:GAS @ 20C Vapor Density:1 Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS COMPRESSED GAS, ODORLESS Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID FLAMMABLE AND COMBUSTIBLE MATERIALS - ESPECIALLY GREASES AND OILS. Stability Condition to Avoid:EXTREMELY HIGH TEMPERATURES Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:MOVE LEAKY CYLINDER TO OUTDOORS OR VENTILATED HOOD. ALLOW GAS TO DISCHARGE AT MODERATE RATE. REMOVE ALL FLAMMABLE MATERIALS FROM VICINITY. DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FED ERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KODAK FLEXICOLOR BLEACH, PART B Kit Part:Y CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 45 - 55% Other REC Limits:NONE SPECIFIED Ingred Name:AMMONIUM FERRIC ETHLYENEDIAMINETETRAACETIC ACID CAS:21265-50-9 Fraction by Wt: 40 - 45% Other REC Limits:NONE SPECIFIED Ingred Name:AMMONIA (SARA III) CAS:7664-41-7 RTECS #:BO0875000 Fraction by Wt: 6% Other REC Limits:NONE SPECIFIED OSHA PEL:50 PPM ACGIH TLV:25 PPM/35 STEL; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ETHYLENEDIAMINE-TETRAACETIC ACID (EDTA) (SARA III) CAS:60-00-4 RTECS #:AH4025000 Fraction by Wt: 1 - 5% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN, INHALATION AND INGESTION- LOW HAZARD FOR RECOMMENDED HANDLING. EYES- MAY CAUSE TRANSIENT IRRITATION. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION- IF SYMPTOMATIC, REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES- ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. SKIN- WASH AFTER EAC H CONTACT. INGESTION- DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE APPROPRIATE AGENT FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH MATERIAL TO THE SEWER WITH LARGE AMOUNTS OF WATER. FOR LARGE SPILLS, ABSORB SPILL WITH INERT MATERIAL AND PLACE IN A CONTAINER FOR CHEMICAL WASTE. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:GOOD VENTILATION SHOULD BE SUFFICIENT. RESPIRATORY PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES. Ventilation:SUPPLEMENTARY VENTILATION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES. Other Protective Equipment:NONE Work Hygienic Practices:WASH HANDS AFTER HANDLING THIS MATERIAL. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 MM HG Vapor Density:0.6 Spec Gravity:1.29 pH:7.1 Solubility in Water:COMPLETE Appearance and Odor:DARK REDDISH BROWN SOLUTION, SLIGHT AMMONIA ODOR. Percent Volatiles by Volume:55 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON DIOXIDE AND PROBABLY CARBON MONOXIDE. AMMONIA GAS AND OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAW.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DIMETHYLANILINE CAGE:PURIT CAGE:PURIT ============= Composition/Information on Ingredients ============= Ingred Name:ANILINE, N,N-DIMETHYL-; (N,N-DIMETHYL-ANILINE) (SARA III) CAS:121-69-7 RTECS #:BX4725000 Other REC Limits:25 MG/M3, S (MFR) OSHA PEL:5 PPM;10 PPM STEL, S ACGIH TLV:5 PPM;10 PPM STEL, S EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:CONTACT VIA SPLASH. SKIN:MATERIAL IS ABSORBED BY SKIN. INHAL:INHALATION BOTH WHEN COLD & WHEN HEATED. INGEST:VERY UNLIKELY. CAUSES CYANOSIS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IRRIGATE W/WATER FOR AT LEAST 15 MINUTES. SKIN:WASH W/SOAP & PLENTY OF WATER. INHAL:REMOVE FROM WORK AREA. IF OVERCOME, CALL FIRE DEPARTMENT & REQUEST FIRST AID SQUAD. INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:SMALL FIRES:DRY CHEMICAL, CO*2, WATER SPRAY OR FOAM. LARGE FIRES:WATER SPRAY, FOG OR FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT APPLY WATER. DIKE, ADD INERT ABSORBENT; SAND, DIRT, ETC. SHOVEL UP, DEPOSIT IN DRUMS. REPEATEDLY FLUSH W/SOAP & WATER. OBSERVE NO SMOKING AREA. OBSERVE FEDERAL, STATE & LOCAL LAWS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE, AVOID TEMPERATURE EXTREMES. DO NOT BREATH VAPOR. DO NOT GET ON SKIN. ALWAYS USE SUCTION HOOD OR NIOSH/MSHA APPROVED AIR-SUPPLIED RESPIRATOR. Other Precautions:AFTER USE, ALWAYS CLOSE CONTAINER. AVOID BREATHING, CONTACT, INGESTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED AIR-SUPPLIED RESPIRATOR. IF VENTILATION CONTROLS ARE NOT IN PLACE, SEE "GUIDE TO INDUSTRIAL RESPIRATORY PROTECTION" PUBLISHED BY NIOSH. Ventilation:USE CLSD SYS PROCESS WHERE POSS. WHEN NOT POSS, USE SUCTION HOOD ON DRUM & ON EQUIP RECEIVING VESSEL. ALSO, USE (SUPDAT) Other Protective Equipment:USE LONG PANTS, LONG SLEEVE SHIRT. Work Hygienic Practices:WASH OFF W/SOAP & WATER. WASH HANDS BEFORE EATING. Supplemental Safety and Health VENT:NEGATIVE PRESSURE LOCAL VENTILATION. ================== Physical/Chemical Properties ================== HCC:T3 Solubility in Water:NEGLIGIBLE Appearance and Odor:LIQUID; AMINE-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, STRONG ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO FEDERAL, STATE & LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CPS235109/CPS238050 DELO 400 SAE 10W CAGE:04BH0 CAGE:04BH0 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT REFINED HYDROTREATED HEAVY PARAFFINIC DISTILLATE, HYDROTREATED HEAVY PARAFFINIC DISTILLATE, LUBRICATING OIL. CAS:64742-54-7 RTECS #:PY8035500 OSHA PEL:5 MG/CUM (MIST) OSHA STEL:10 MG/CUM(MIST) Ingred Name:OIL PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038500 Other REC Limits:5 MG/CUM OSHA PEL:5 MG/CUM(MIST) OSHA STEL:10 MG/CUM(MIST) ACGIH STEL:10 MG/CUM(MIST) Ingred Name:ADDITIVES < Wt:15. Ingred Name:DIALKYL (ALKYL) DITHIOPHOSPHORIC ACID, ZINC SALT *95-1* CAS:68649-42-3 < Wt:3. Ingred Name:LUBRICATING BASE OIL > Wt:85. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:BASED ON DATA FROM SIMILAR MATERIALS, THIS SUBSTANCE SHOULD BE PRACTICALLY NON-TOXIC & IS NOT EXPECTED TO CAUSE PROLONGED/SIGNIFICANT HEALTH HAZARDS. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/FRESH WATER FOR 15 MINS. REMOVE CONTACT LENSES IF WORN. SKIN: WASH THOROUGHLY W/SOAP & WATER. INGESTION: GIVE WATER/MILK TO DRINK. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:=200.C, 392.F Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG Fire Fighting Procedures:DON'T ENTER ANY ENCLOSED/CONFINED SPACE W/OUT PROPER PROTECTIVE EQUIPMENT, INCLUDING SCBA. Unusual Fire/Explosion Hazard:DRUM MAY RUPTURE IF EMPTIED W/PRESSURE. RESIDUE MAY IGNITE W/EXPLOSIVE VIOLENCE IF HEATED SUFFICIENTLY. ================== Accidental Release Measures ================== Spill Release Procedures:STOP SOURCE OF LEAK/RELEASE. CLEAN UP AS SOON AS POSSIBLE. CONTAIN LIQUID TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE WATER/GROUND WATER. CLEAN UP W/ABSORBENT MATERIALS/BY PUMPING. WHERE APPROPR IATE, REMOVE CONTAMINATED SOIL. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T USE PRESSURE TO EMPTY DRUM. DON'T WELD, HEAT/DRILL CONTAINER. Other Precautions:AVOID PROLONGED/FREQUENTLY REPEATED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF OPERATING CONDITIONS CREATE AIRBORNE CONCENTRATIONS WHICH EXCEED THE RECOMMENDED EXPOSURE STANDARDS, THE USE OF AN APPROVED RESPIRATOR IS REQUIRED. Ventilation:ADEQUATE TO KEEP THE AIRBORNE CONCENTRATIONS OF THIS MATERIAL BELOW THE RECOMMENDED EXPOSURE STANDARD. Other Protective Equipment:PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE & LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.89 Solubility in Water:INSOLUBLE Appearance and Odor:DARK BROWN LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS SUCH AS CHLORATES, NITRATES, PEROXIDES Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CO2, WATER VAPOR & OXIDES OF SULFUR/NITROGEN/PHOSPHOROUS. INCOMPLETE COMBUSTION CAN PRODUCE CO. =================== Toxicological Information=================== Toxicological Information:THIS PRODUCT CONTAINS PETROLEUM BASE OILS WHICH MAY BE REFINED BY VARIOUS PROCESSES INCLUDING SEVERE SOLVENT EXTRACTION, SEVERE HYDROCRACKING/SEVERE HYDROTREATING. NONE OF THE OILS REQUIRES A CANCER W ARNING UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). THESE OILS HAVE NOT BEEN LISTED IN THE NTP ANNUAL RESERCH ON CANCER AS; CARCINOGEN TO HUMANS GROUP 1, CARCINOGENIC TO HUMANS GRO UP 2A/CARCINOGENIC TO HUMANS GROUP 2B. ===================== Ecological Information ===================== Ecological:THIS MATERIAL IS NOT EXPECTED TO PRESENT ANY ENVIRONMENTAL PROBLEMS OTHER THAN THOSE ASSOCIATED W/OIL SPILLS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE CONTAMINATED MATERIALS IN DISPOSABLE CONTAINERS & DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:NOT DESIGNATED AS A HAZARDOUS MATERIAL BY THE FEDERAL DOT. ======================= Other Information =======================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:19461 REFRACTIVE INDEX LIQUID SERIES E ND = 1.440-1.555 CAGE:10684 CAGE:10684 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: OILY FEEL. NOT LIKELY WHEN CONDITIONS OF INTENDED USE ARE FOLLOWED. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN: OILY FEEL. NOT LIKELY WHEN CONDITIONS OF INTENDED USE ARE FOLLOWED. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. FLUSH W/LARGE QUANTITIES OF WATER. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. INGESTION: DON'T INDUCE VOMITING. ADMINISTER WATER OR MILK. OBT AIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F Extinguishing Media:USE CO2, DRY CHEMICAL OR FOAM. Fire Fighting Procedures:TREAT AS PETROLEUM GREASE/OIL FIRE. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB, PLACE IN PLASTIC CONTAINER, CAP OR TWIST TIE CLOSURE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 65F & 90F. AVOID DIRECT SUNLIGHT, CONTACT W/SKIN & BREATHING OF VAPORS. Other Precautions:COMBUSTIBLE LIQUID. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE PRODUCT IN A VENTILATION HOOD. Ventilation:LOCAL EXHAUST/MECHANICAL: NORMAL ROOM AIR CHANGES (TWO/HR). Other Protective Equipment:USE OF CHEMICAL LAB APRON Work Hygienic Practices:ALWAYS USE GOOD HYGIENIC WORK/PRACTICES AS TO HOUSEKEEPING & PERSONAL HYGIENE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>496F Vapor Pres:0.5 Vapor Density:>1 Spec Gravity:1.1 Evaporation Rate & Reference:(MINERAL OIL = 1): 1 Solubility in Water:SLIGHT Appearance and Odor:COLORLESS TO PALE YELLOW LIQUID, SWEET BALSAMIC WOODY ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, IRON Stability Condition to Avoid:DIRECT SUNLIGHT, OPEN FLAMES & OTHER SOURCES OF IGNITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SULFURIC ACID 1.O NORMAL SOLUTION Resp. Party Other MSDS Num.:SS 1121 Preparer's Name:MICHAEL RASZEJA CAGE:6V042 CAGE:6V042 Contract Num:MDA414-00-P-0162 CAGE:0X801 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID CAS:7664-93-9 RTECS #:WS5600000 = Wt:4.9 OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 ACGIH STEL:3 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 = Wt:95.1 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:MAY BE HARMFUL IF SWALLOWED. CONTACT MAY CAUSE IRRITATION TO SKIN, EYES AND MUCOUS MEMBRANES. EXERCISE APPROPRIATE PROCEDURES TO MINIMIZE POTENTIAL HAZARDS. Effects of Overexposure:CONTACT MAY CAUSE IRRITATION TO SKIN, EYES AND MUCOUS MEMBRANES. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING. INGESTION: I SWALLOWED, DO NOT INDUCE VOMITING.IF CONSCIOUS, DRINK LARGE QUANTITIES OF MILK OR WATER.GET IMMEDIAT E MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. EYES: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY.GET IMMEDIATED MEDICAL ATTENT ION. INHALATION: REMOVE TO FRESH AIR.IF NOT BREATHING,GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,GIVE OXYGEN.GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:IF INVOLVED IN A FIRE SITUATION USE WATER SPRAY. Fire Fighting Procedures:THESE SOLUTIONS ARE VERY DILUTE. IN FIRE CONDITIONS, WEAR A NIOSH/MSHA-APPROVED SELF-CONTAINED BREATHING Unusual Fire/Explosion Hazard:ATTACKS MANY METALS, RELEASIN HYDROGEN. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS; CAN REACT VIGOROUSLY WITH ALKALI MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:NEUTRALIZE WITH SODIUM BICARBONATE(SODA ASH) AND FLUSH TO SEWER WITH COPIOUS AMOUNTS OF WATER. Neutralizing Agent:NEUTRALIZE WITH SODIUM BICARBONATE(SODA ASH). ======================Handling and Storage ====================== Handling and Storage Precautions:STOREIN A COOL PLACE. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. REMOVE AND WASH CONTAMINATED CLOTHING. READ LABEL ON CONTAINER BEFORE USING. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. KEEP OUT OF REACH OF CH ILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED AT ROOM TEMPERATURES. Ventilation:LOCAL/MECHANICAL: NONE NEEDED Supplemental Safety and Health CHEM SCIENTIFIC P/N: V15-1L ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=0.C, 32.F Vapor Pres:14 (WATER) Vapor Density:0.7(WATER) Spec Gravity:1.0 Evaporation Rate & Reference:SLIGHTLY LESS THAN 1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS LIQUID, NO ODOR Percent Volatiles by Volume:95.1% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ATTACKS MANY METALS, BASES. REACTS WITH ALKALIES. Stability Condition to Avoid:EXCESSIVE TEMPERATURE AND HEAT. Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, MAY RELEASE SULFUR DIOXIDE FUMES. =================== Toxicological Information=================== Toxicological Information:NOT PROVIDED ===================== Ecological Information ===================== Ecological:NOT PROVIDED ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE,TREATMENT,OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS.THESE DISPOSAL GUIDE LINES ARE INTENDED FOR CATALOG-SIZE QUANTITIES ONLY. FLUSH NEUTRALIZED ACID TO SEWER WITH COPIOUS AM OUNTS OF WATER. =================== MSDS Transport Information =================== Transport Information:SEE TRANSPORTATION DATA. ===================== Regulatory Information ===================== SARA Title III Information:EHS RQ = 1000 LB. IN AEROSOL FORMS IT IS A 313 CHEMICAL Federal Regulatory Information:CERCLA RQ = 1000 LB State Regulatory Information:NOT PROVIDED ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CS 3204, PART B Kit Part:Y Preparer's Name:HERBERT MOORE CAGE:14439 CAGE:14439 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE DIOXIDE (DUST) (EXPOSURE LIMITS BASED ON DUST PARTICLES.PARTICLES WETTED OUT THERFORE PARTICLES WON'T RESULT) CAS:1313-13-9 RTECS #:OP0350000 Fraction by Wt: 65% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:VOC: 1 GM/LITER RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IMPAIRMENT OF CENTRAL NERVOUS SYSTEM. Effects of Overexposure:SLUGGISHNESS, SLEEPLESSNESS AND/OR WEAKNESS IN THE LEGS. Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER, CONTACT PHYSICINA. SKIN: WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:DRY CHEMICAL, CO2, FOAM, WATER Fire Fighting Procedures:IN CONFINED AREA WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:EXPLOSION HAZARD IF HEATED WITH OXIDIZABLE MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP AND TRANSFER TO SAFETY CONTAINER, WASH SURFACE WITH SOAP AND WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA. Other Precautions:WASH HANDS BEFORE EATING, DRINKING OR SMOKING AFTER HANDLING THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED. Other Protective Equipment:APPROPRIATE TO PREVENT PROLONGED CONTACT WITH SKIN. Work Hygienic Practices:TRAIN PERSONNEL IN SAFE HANDLING OF THIS PRODUCT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:LIQ@RM TEMP Spec Gravity:2.0 (WATER=1) pH:9.0 Viscosity:1000 POISES Evaporation Rate & Reference:NIL (BU AC=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK PASTE, OILY ODOR Percent Volatiles by Volume:2.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS AND COMBUSTIBLES, H2S, POTASSIUM AZIDE Stability Condition to Avoid:NONE Hazardous Decomposition Products:CO2, CO, NO, NO2, DUST ==================== Disposal Considerations ==================== Waste Disposal Methods:REACT WITH BASE COMPONENT AND DISPOSE AS SOLID WASTE ACCORDING TO FEDERAL, STATE, AND LOCAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: CAD062064746.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:246A MPD-Q64 NK130 CAGE:INTCN CAGE:02964 CAGE:INTCN ============= Composition/Information on Ingredients ============= Ingred Name:OCTYL DECYL DIMETHYL AMMONIUM CHLORIDE Fraction by Wt: 1.650% Ingred Name:DIOCTYL DIMETHYL AMMONIUM CHLORIDE Fraction by Wt: 0.825% Ingred Name:DIDECYL DIMETHYL AMMONIUM CHLORIDE CAS:32426-11-2 Fraction by Wt: 0.825% Ingred Name:ALKYL DIMETHYLBENZYL AMMONIUM CHLORIDE, BENZALKONIUM CHLORIDE CAS:8001-54-5 RTECS #:BO3325000 Fraction by Wt: 2.2% Ingred Name:SODIUM OXIDE CAS:12401-86-4 RTECS #:WC4800000 Fraction by Wt: 0.34% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50: 2.8 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: HARMFUL & FATAL. SKIN: SEVERE BURNS, IRRITATION TO OPEN CUTS & SORES. INHALATION: IRRITATION OF RESPIRATORY SYSTEM. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: HARMFUL & FATAL. SKIN: SEVERE BURNS, IRRITATION TO OPEN CUTS & SORES. INHALATION: IRRITATION TO RESPIRATORY SYSTEM. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: WASH W/WATER FOR 15 MINS. SEE PHYSICIAN. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GIVE A TEASPOONFULL OF MILD OF MAGNESIA, FOLLOWED W/MILK & WATER TO DILUTE MATERIA L, & RAW EGG WHITES. DON'T INDUCE VOMITING. AVOID ALCOHOL. CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, FOG, FOAM, DRY CHEMICAL, CO2, ALCOHOL FOAM Fire Fighting Procedures:AVOID EXPOSURE TO FUMES & VAPORS. WEAR SELF-CONTAINED POSITIVE PRESSURIZED BREATHING APPARATUS . Unusual Fire/Explosion Hazard:USE WATER SPRAY TO COOL ADJACENT FIRE-EXPOSED CONTAINERS. PRODUCT WON'T BURN BUT MAY SPATTER IF TEMPERATURE EXCEEDS BOILING POINT. ================== Accidental Release Measures ================== Spill Release Procedures:FLOORS MAY BE SLIPPERY. USE CARE TO AVOID FALLS. SOAK UP & ABSORB SPILL ON DIATOMACEOUS EARTH, SAWDUST OR OTHER INERT MATERIAL. DIKE W/LARGE SPILLS, PUMP TO SUITABLE CONTAINERS FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. DON'T CONTAMINATE WATER & FOOD. STORE UPRIGHT IN ORIGINAL CLOSED CONTAINER. DON'T GET IN EYES, ON SKIN, OR ON CLOTHING. Other Precautions:AVOID ENTRY INTO SEWERS & NATURAL WATER. REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID BREATHING OF VAPOR & SPRAY. STORE IN COOL DRY AREA. AVOID EXPOSURE TO FUMES & VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMAL ROOM VENTILATION. USE MSHA/NIOSH APPROVED OR EQUIVALENT TO >TLV. Ventilation:LOCAL EXHAUST: PREFERRED. MECHANICAL: ACCEPTABLE. Other Protective Equipment:IMPERVIOUS RUBBER BOOTS, APRON, EYEWASH, SAFETY SHOWER Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGIENE. WASH AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Pres:17 Vapor Density:0.62 Spec Gravity:1.0108 pH:13.0 Evaporation Rate & Reference:(WATER = 1): 1.0 Solubility in Water:COMPLETE Appearance and Odor:CLEAR BLUE THIN LIQUID PLEASANT FRESH ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING, CHLORINE BLEACH, REDUCING AGENTS, ANIONICS Stability Condition to Avoid:FREEZING Hazardous Decomposition Products:CO2, CO, NITROUS OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS. BURN IN A APPROVED INCINERATOR. DISINFECTANT, LIQUID. DOT HAZARD CLASS: CORROSIVE MATERIAL; UN1903.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DAVISON BLUE INDICATING GEL,TEL-TALE INDICATING GEL GR 47/48 Resp. Party Other MSDS Num.:5008B Preparer's Name:J.H. CONVEY, MGR ENVIR SV CAGE:1L2Z7 CAGE:1L2Z7 Contract Num:SP0450-00-M-D-682 CAGE:9T424 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA GEL CAS:63231-67-4 RTECS #:VV7340000 Ingred Name:COBALT CHLORIDE CAS:7646-79-9 RTECS #:GF9800000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:48-HR ORAL LD50 (RAT) > 31,600 MG/KG Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES Health Hazards Acute and Chronic:AVOID PROLONGED BREATHING OF DUST OR CONTACT OF DUST WITH THE SKIN. THE DRYING ACTION OF THIS MATERIAL CAN CAUSE IRRITATION OF THE MUCOUS MEMBRANES OF THE NOSE AND THROAT AND IRRITATION OF THE SKIN. I F ITS USE REQUIRES MANUAL HANDLING, WRISTLETS. IF DUSTY CONDITIONS PREVAIL, WEAR A PROPERLY FITTED DISCOMFORT. WHEN POURING INTO A CONTAINER OF FLAMMABLE LIQUID, GROUND BOTH CONTAINERS ELECTRICALLY TO PREVENT A STATIC ELECTRIC SPARK. Explanation of Carcinogenicity:COBALT AND COBALT COMPOUNDS ARE INCLUDED ON THE IARC HUMAN CARCINOGENS LIST. Effects of Overexposure:THE DRYING ACTION OF THIS MATERIAL CAN CAUSE IRRITATION OF THE MUCOUS MEMBRANES OF THE NOSE AND THROAT AND IRRITATION OF THE SKIN. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY WASH FROM EYES WITH LARGE AMOUNTS OF WATER, OCCASIONALLY LIFTING THE UPPER & LOWER EYE LIDS. IF IRRITATION OCCURS AND PERSISTS, SEEK MEDICAL ATTENTION. SKIN: WASH WITH SOAP & WATER. INGESTION: MATERIAL WILL PASS THROUGH THE BODY NORMALLY. INHALATION: REMOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:NO DATA PROVIDED BY RESPONSIBLE PARTY. Fire Fighting Procedures:NO DATA PROVIDED BY RESPONSIBLE PARTY. Unusual Fire/Explosion Hazard:NO DATA PROVIDED BY RESPONSIBLE PARTY. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR VACUUM UP. Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED BREATHING OF DUST OR CONTACT OF DUST WITH SKIN. Other Precautions:WHEN POURING INTO A CONTAINER OF FLAMMABLE LIQUID, GROUND BOTH CONTAINERS ELECTRICALLY TO PREVENT A STATIC ELECTRIC SPARK. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF DUSTY CONDITIONS PREVAIL, WEAR A PROPERLY FITTED NIOSH-APPROVED DUST RESPIRATOR. Ventilation:NO DATA PROVIDED BY RESPONSIBLE PARTY. Other Protective Equipment:NO DATA PROVIDED BY RESPONSIBLE PARTY. Work Hygienic Practices:AVOID PROLONGED BREATHING OF DUST OR CONTACT OF DUST WITH THE SKIN. Supplemental Safety and Health NO DATA PROVIDED BY RESPONSIBLE PARTY. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:2.1 pH:6.5-7.5 ABOUT Solubility in Water:SILICA GEL BASE INSOLUBLE Appearance and Odor:CLEAR BLUE GRANULES. ODOR: NONE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS WITH HYDROGEN FLUORIDE. Stability Condition to Avoid:NO DATA PROVIDED BY RESPONSIBLE PARTY. Hazardous Decomposition Products:NO DATA PROVIDED BY RESPONSIBLE PARTY. =================== Toxicological Information=================== Toxicological Information:ANIMAL TOXICOLOGY: 48-HOUR ORAL LD50 (RAT) EST >31, 600 MG/KG. 48-HOUR DERMAL LD50 (RABBIT) EST > 2,000 MG/KG. CONSIDERED AN OCCULAR IRRITANT. TESTS FOR FDA APPROVAL FOR USE IN FOODS: NOT A FOOD GRADE PRODUCT. HUMAN TOXICOLOGY: SILICA GELIS A SYNTHETIC AMORPHOUS SILICA NOT TO BE CONFUSED WITH CRYSTALLINE SILICA. EPIDEMIOLOGICAL STUDIES INDICATE LOW POTENIAL FOR ADVERSE HEALTH EFFECTS. IN THE ACTIV ATED FORM, SILICA GEL ACTS A DESSICANT AND CAN CAUSE A DRYING IRRITATION OF THE MUCOUS MEMBRANES & SKIN IN CASES OF SEVERE EXPOSURE. COBALT CHLORIDE CAUSES DERMATITIS AND IRRITATION OF NASAL PASSAGES & LUNGS. ===================== Ecological Information ===================== Ecological:SILICA GEL IS NOT KKNOWN TO HAVE ANY ADVERSE EFFECT ON THE AQUATIC ENVIRONMENT. THE SILICA BASE IS INSOLUBLE AND NONTOXIC. COBALT CHLORIDE MAY LEACH AWAY OF CONTACT WITH WATER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN AN APPROVED LANDFILL ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS. COVER PROMPTLY TO AVOID BLOWING OF DUST. =================== MSDS Transport Information =================== Transport Information:NOT CLASSIFIED AS A HAZARDOUS MATERIAL. ===================== Regulatory Information ===================== SARA Title III Information:COBALT COMPOUNDS ARE LISTED AS A TOXIC CHEMICAL UNDER SECTION 313 OF TITLE III OF SARA. Federal Regulatory Information:USDA: NOT APPLICABLE. OSHA-SILICA GEL-PEL= 6 MG/M3. COBALT CHLORIDE -PEL=NOT LISTED IN 29 CFR 1910.1000. NIOSH- SILICA GEL ANIMAL TESTS CONDUCTED IN 1976-78. 18 MONTH EXPOSURE AT 15 MG/M3 SHOWED SILIC A DEPOSITION IN RESPIRATORY MACROPHAGES AND LYMPH NODES, MINIMUM LUNG FUNCTION IMPAIRMENT AND NO SILICOSIS. FDA- NOT A FOOD GRADE PRODUCT. FOR PHARMACEUTICAL OR FOOD USE;, FP GRADES OF SYLOID SHOULD B E SPECIFIED. ACGIH: SILICA GEL- TLV=10 MG/M3, COBALT CHLORIDE-TLV=0.02 MG/M3. State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NR-150,POLYMIDE SOLUTIONS CAGE:GO775 CAGE:18873 CAGE:GO775 ============= Composition/Information on Ingredients ============= Ingred Name:N-METHYL-2-PYRROLIDONE,CAS#872-50-4 CAS:872-50-4 RTECS #:UY5790000 Fraction by Wt: 55% ACGIH TLV:>1000 PPM Ingred Name:AROMATIC TETRACARBOCYLIC ACID Fraction by Wt: 30% Ingred Name:AROMATIC DIAMINES Fraction by Wt: 15% ===================== Hazards Identification ===================== Effects of Overexposure:SKIN & EYE IRRITATION,NAUSEA & BURNING SENSATION ON INHALATION. ======================= First Aid Measures ======================= First Aid:REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. EYES, SKIN: FLUSH W. H*2O REMOVE/ ISOLATE CONTAM CLOTHING. KEEP WARM & QUIET. GIVE CPR/OXYGEN IF NEED. STAY UPWIND. KEEP UNPROTECTED PERSONS AWAY FROM AREA . ===================== Fire Fighting Measures ===================== Flash Point:203F/95C OC Lower Limits:2.18 Upper Limits:12.2 Extinguishing Media:WATER Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. KEEP UPWIND. WEAR SCBA/PROTECTIVE CLOTHING. SM SPILL:ABSORB W SAND,EARTH, OTHER ABSORBANT MAIL. LG:DIKE FOR LATER DISPOSAL. FLUSH AREA W WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:METAL CONTAINERS SHOULD BE SELECTED WITH CARE BECAUSE OF CORROSIVE ACTION OF SOLUTIONS.KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:USE WTH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQMNTS UNDER ORDINARY CONDITIONS/ADEQUATE VENT. Ventilation:DIRECT LOCAL EXHAUST OR GENERAL VENTILATION. Other Protective Equipment:APRONS SUGGESTED Supplemental Safety and Health PHYSICAL DATA FOR 2-METHYL-2-PYRROLIDONE ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:396F/202C Vapor Pres:0.5 Vapor Density:UNK Spec Gravity:1.027 Solubility in Water:COMPLETE Appearance and Odor:ALMOST WATER WHITE,SLIGHT AMINE ODOR. Percent Volatiles by Volume:50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METHYL PYRROLIDONE(NMP)IS A CHEMICALLY INERT SOLVENT. Stability Condition to Avoid:NONE Hazardous Decomposition Products:WHEN HEATED >260C/500F,DECOMPOSES. ==================== Disposal Considerations ==================== Waste Disposal Methods:ELIMINATE IGNITION SOURCES. DESTROY BY LIQUID INCINERATION. INCINERATION WILL BE EASIER BY MIXING WITH A MORE FLAMMABLE SOLVENT. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE INTERNATIONAL,F ED,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-L-26087B AM.I GRADE I LUBRICATING OIL CAGE:82925 CAGE:82925 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL (NAPHTHENIC/PARAFFINIC) Fraction by Wt: >99.0% OSHA PEL:5MG/CUM,AS OIL MIST ACGIH TLV:5MG/CUM,AS OIL MIST Ingred Name:OTHER COMPONENTS (TYPE NOT SPECIFIED) Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES,SKIN,RESPIRATORY OR G.I.TRACTS;CNS EFFECTS LIKE HEADACHE,DIZZINESS,NAUSEA AND VOMITING. REDNESS OR BURNS OF EYES/SKIN POSSIBLE.CHRONIC:DRYING OF SKIN,DEFATTING OR DERMATITIS,D AMAGE TO LUNGS. Explanation of Carcinogenicity:DATA PER MSDS Effects of Overexposure:MAY CAUSE IRRITATION OF EYES,SKIN,RESPIRATORY OR G.I.TRACTS;MAY CAUSE HEADACHE,DIZZINESS,NAUSEA,VOMITING OR GI TRACT DISTURBANCES POSSIBLE.BURNS OR REDNESS OF EYES/CRACKING OR DRYNESS OF SKIN. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:385F,196C Lower Limits:0.9 Upper Limits:7.0 Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;CONTAIN FREE MATERIAL IF POSSIBLE;USE SUITABLE INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.DO MOT USE CONTAMINATED CLOTHES. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR AS REQUIRED IF ABOVE PEL/TLV OR SCBA IN AN ENCLOSED AREA. Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:610F,321C Vapor Pres:<0.01 Vapor Density:>5.0 Spec Gravity:0.93 Evaporation Rate & Reference:<0.01(N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT YELLOW TO PALE AMBER COLORED LIQUID,CHARACTERISTIC OIL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OTHER UNIDENTIFIED COMPONENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ODORLESS ALKYD INT UNDERCOAT WHITE 37875 CAGE:OBRN9 CAGE:33832 CAGE:OBRN9 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENTS: ODORLESS MINERAL SPIRITS CAS:64741-65-7 Fraction by Wt: 29.5% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM; 590 MG/M3 ACGIH TLV:100 PPM; 590 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:HIGH VAPOR CONCENTRATIONS (OVER 1000 PPM) ARE IRRITATING TO THE EYE & RESPIRATORY TRACT. MAY CAUSE HEADACHES & DIZZINESS. PROLONGED SKIN CONTACT IRRITATES. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH WITH WATER 15 MINS OR UNTIL IRRITATION SUBSIDES. IF IRRITATION PERSISTS, CALL A PHYSICIAN. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING AND WASH THOROUGHLY WITH SOAP AND WATER. INHALA TION: IF OVERCOME BY VAPORS, REMOVE TO FRESH AIR, CALL PHYSICIAN. INGESTION; DO NOT INDUCE VOMITING, CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:125F,52C Lower Limits:1 Upper Limits:6 Extinguishing Media:CARBON DIOXIDE, FOAM, WATER FOG, DRY CHEMICAL. Fire Fighting Procedures:USE AIR SUPPLIED BREATHING EQUIPMENT FOR ENCLOSED CONTAINERS WITH WATER SPRAY. AVOID BREATHING VAPOR OR FUMES. Unusual Fire/Explosion Hazard:IF LEAK OR SPILL HAS IGNITED, USE WATER SPRAY TO DISPERSE THE VAPORS FROM FIRE FIGHTERS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES. KEEP FROM HEAT, SPARKS & OPEN FLAME. ADD ABSORBENT (SAND, EARTH, SAWDUST) TO SPILL. VENTILATE AREA. IF LARGE SPILL, KEEP PRODUCT FROM ENTERING SEWERS & WATERCOURSES BY DIK ING. ADVISE AUTHORITIES IF PRODUCT HAS ENTERED. ======================Handling and Storage ====================== Handling and Storage Precautions:REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE HYDROCARBON VAPOR CANISTER OR SUPPLIED AIR RESPIRATORY IN CONFINED AREA. Ventilation:LOCAL EXHAUST: FACE VELOCITY 60FPM. MECHANICAL: USE EXPLOSION-PROOF EQUIPMENT. SPECIAL: USE ONLY W/ADEQUATE VENTILATION. Other Protective Equipment:USE CHEMICAL RESISTANT APRON OR OTHER CLOTHING TO AVOID REPEATED SKIN CONTACT. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health KEEP CONTAINER CLOSED WHEN NOT IN USE. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:346F,174C Melt/Freeze Pt:M.P/F.P Text:<0F,<-18C Vapor Pres:4 MM HG Vapor Density:5.3 Spec Gravity:1.385 Evaporation Rate & Reference:.1 Solubility in Water:INSOLUBLE Appearance and Odor:WHITE, LIQUID, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CAN REACT WITH OXIDIZING MATERIALS WHEN HEATED TO DECOMPOSITION. Stability Condition to Avoid:HIGH TEMPERATURE. Hazardous Decomposition Products:CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:ASSURE CONFORMITY WITH APPLICABLE DISPOSAL REGULATIONS. DISPOSE OF ABSORBED MATERIAL AT AN APPROVED DISPOSAL SITE OR FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:718X WB, K07812 CAGE:DO642 CAGE:DO642 CAGE:SHRWN ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE VAPOR PRESS: 760. CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 14% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:BUTANE VAPOR PRESS: 760. CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 6% OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:VM & P NAPHTHA; (LT. ALIPHATIC HYDROCARBON SOLVENT) VAPOR PRESS: 53. CAS:64742-89-8 Fraction by Wt: 14% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:NAPHTHA, HEAVY ALKYLATE; (MINERAL SPIRITS (ODORLESS)) VAPOR PRESS: 1. CAS:64741-65-7 Fraction by Wt: 6% Other REC Limits:100 PPM (MFR) OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:TOLUENE (SARA 313) (CERCLA) VAPOR PRESS: 22. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 12% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CYCLOHEXANE (SARA 313) (CERCLA) VAPOR PRESS: 100. CAS:110-82-7 RTECS #:GU6300000 Fraction by Wt: 1% OSHA PEL:300 PPM ACGIH TLV:300 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPDAT: (TOTAL DUST), 5 MG/M3 (RESP FRACTION). RTECS #:9999999ZZ Ingred Name:STOR/HNDLG: SMOKE-EXTING ALL FLAMES, PILOT LTS & HEATER-TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: SOURCES OF IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROC. CNTNTS UNDER PRESS. DO NOT (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: PUNCTURE, INCIN/EXPOSE TO TEMP >120F. HEAT FROM SUNLT, RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: COULD CAUSE CNTNR TO BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: DELIB CONC & INHALING CNTNTS CAN BE HARMFUL/FATAL. WARNING:PROD CNTNS CHEM(S) KNOWN TO ST OF CA TO CAUSE(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EFTS OF OVEREXP: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. SIGNS & SYMPS OF OVEREXP: REDNESS & ITCH/BURN SENSATION MAY INDIC ATE EYE/EXCESSIVE SKIN EXPOS. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE EXPOS TO (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS: TO VAPS/SPRAY MISTS. CHRONIC: PRLGD OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, CARDIOVASCULAR & REPRO SYSTEMS. RPTS HAVE ASSOC RPTD/PRLGD OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. TOLUENE APPEARS ON NAVYLIST OF CHEM REPRO HAZS. CONSULT APPROP HLTH PROFESSIONALS CONCERNING (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOS. RESTORE BRTHG. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THORO WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES: FLUSH WITH LARGE A MOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. DO NOT INDUCE VOMIT. GIVE CONSCIOUS PATIENT SEVERAL GLASSES OF WATER. SEEK MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:<0F,<-18C Lower Limits:1.0% Upper Limits:9.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . IF WATER IS USED, FOG NOZZ PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & POSS (SUPDAT) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLO. DURING USE & UNTIL ALL VAPS GONE: KEEP AREA VENT-DO NOT (ING 8) Other Precautions:COATING MAY CNTN MATLS CLASSED AS NUISANCE PARTICULATES (LISTED AS DUST IN INGS) WHICH MAY BE PRESENT @ HAZ LEVS ONLY DURING SAND/ABRADING DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH APPRVD ORG VAP/PARTICULATE RESP FOR PROT AGAINST MATLS IN INGS. WHEN SAND/ABRADING DRIED FILM, WEAR NIOSH APPRV D DUST/MIST RESP FOR DUST WHICH (SUPDAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO MATLS IN INGS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA (SUPDAT) Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST & SKIN/EYE CONT. WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC: AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EFTS OF OVEREXP: HAZS LIST & SAFE HNDLG & EXPOS INFO . RESP PROT: MAY BE GENERATED FROM PROD, UNDERLYING PAINT/ABRASIVE. VENT: STDS 1910.94, 1910.107, 1910.108. OTHER PRECS: MG/M3 (TOTAL DUST), 3 MG/M3 (RESP FRACTION), OSHA PEL 15 MG/M3 (ING 7) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0F,<-18C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.80 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:91 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZARDOUS WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISP OF I/A/W FED, ST & LOC REGS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STYLE 815C BRAIDED GRAPHITE REINFORCED CAGE:0CPW5 CAGE:0CPW5 ============= Composition/Information on Ingredients ============= Ingred Name:GRAPHITE (NATURAL) CAS:7782-42-5 RTECS #:MD9659600 Fraction by Wt: >99% OSHA PEL:15 MPPCF; Z-3 ACGIH TLV:2 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THESE ITEMS ARE SOLID SHAPES WHOSE NORMAL USE DOES NOT GENERATE ANY DUST. PROLONGED OR REPEATED BREATHING OF DUST CAN RESULT IN PNEUMOCONIOSIS. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH POTABLE WATER FOR AT LEAST 15 MINUTES. SEEK MD. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING(GIVE O*2/ARTF RESP). ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WILL NOT SUPPORT COMBUSTION. USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:FOLLOW GOOD HOUSEKEEPING PROCEDURES. VACUUM OR SWEEP LOOSE PARTICLES AND/OR DUST. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR NUISANCE DUST. Ventilation:LOCAL EXHAUST PREFERRED. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:0.3-1.8(H*2O=1) Solubility in Water:NEGLIGIBLE. Appearance and Odor:BLACK, FLEXIBLE SHEET & TAPE:BLACK, SOLID SHAPES, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE - PRODUCT IS INERT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN APPROPRIATE LANDFILL IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FLURO-CHEK E-41 EMULSIFIER CAGE:0BYN5 CAGE:0BYN5 ============= Composition/Information on Ingredients ============= Ingred Name:NONYLPHENOL POLYETHOXATE/NONYLPHENOXYPOLY(ETHYLENEOXY)ETHANOL CAS:9016-45-9 RTECS #:MD0900000 Fraction by Wt: 35% Other REC Limits:NONE SPECIFIED Ingred Name:GLYCOLS, POLYETHYLENE, MONO(P-(1,1,3,3-TETRAMETHYL BUTYL)PHENYL) ETHER (TRITON X) CAS:9002-93-1 RTECS #:MD0907700 Fraction by Wt: 15% Other REC Limits:NONE SPECIFIED Ingred Name:DIETHYLENE GLYCOL MONOBUTYL ETHER CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 50% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-EYE:MAY CAUSE SLIGHT-MODERATE IRRITATION.SKIN:MAY CAUSE SLIGHT IRRITATION.INHALE:MISTS MAY CAUSE MODERATE-SEVERE IRRITATION OF RESPIRATORY TRACT.ORAL:MODERATE-SEVERE GI TRACT IRRITATION.CHRONIC- NONE KNOWN. Effects of Overexposure:MAY CAUSE SLIGHT-MODERATE EYE IRRITATION. MAY CAUSE SLIGHT SKIN IRRITATION. INHALATION OF MISTS MAY CAUSE MODERATE-SEVERE IRRITATION OF RESPIRATORY TRACT. ORALLY MAY CAUSE MODERATE-SEVERE GI TRACT IRR ITATION. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.SKIN:WASH WITH SOAP & WATER.EYE:FLUSH WITH WATER FOR 15 MINUTES,HOLDING EYELIDS OPEN.INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.ORAL:IF CONSCI OUS,DRINK WATER/MILK.CONSULT MEDICAL PERSONNEL BEFORE INDUCING VOMITING.IF MEDICAL ADVICE CANNOT BE OBTAINED,THEN TAKE THE PERSON & PRODUCT CONTAINER TO THE NEAREST MEDICAL EMERGENCY TREATMENT CENTER. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:230F,110C Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures:USE SELF-CONTAINED RESPIRATORY PROTECTION Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILLAGE, STOP LEAK AT SOURCE IF POSSIBLE. VENTILATE AREA. PUMP LIQUID INTO DOT DRUMS FOR DISPOSAL. ABSORB REMAINING LIQUID & PLACE IN DOT DRUMS FOR DISPOSAL. WASH AREA WITH WATER. KEEP CONC & WASH WATER FROM ENTERING SEWERS & WATERWAYS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE IN DRY,PROTECTED AREA AWAY FROM STRONG OXIDIZING AGENTS. Other Precautions:WASH HANDS & FACE WITH SOAP & WATER BEFORE SMOKING OR EATING. IMMEDIATELY REMOVE CONTAMINATED CLOTHING. LAUNDER BEFORE REUSE. DO NOT LAUNDER AT HOME. DISCARD SHOES THAT BECOME CONTAMINATED ON THE INTE RIOR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE OR SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE . Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:BOOTS AND APRON, MADE OF SOLVENT RESISTANT MATERIAL (E.G. NEOPRENE, VITON, ETC..), EYE WASH FOUNTAIN, EMERGENCY SHOWER Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:450F,232C Vapor Pres:1 Vapor Density:>1 Spec Gravity:1.01 pH:8(3.1% Evaporation Rate & Reference:<1 (BU AC=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, RED, VISCOUS LIQUID, MILD ODOR Percent Volatiles by Volume:50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, STRONG ACIDS, STRONG CAUSTIC Stability Condition to Avoid:HIGH HEAT, FLAME Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:TRANSFER TO RECLAIMING CENTER FOR RECYCLING/REUSE IF POSSIBLE. TRANSFER TO LICENSED HAZARDOUS WASTE TREATMENT OR DISPSAL SITE FOR DISPOSAL UNDER APPLICABLE LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ENAMEL, INTERIOR, WHITE 27778 SEMI-GLOSS Preparer's Name:ED DOENGES CAGE:60189 CAGE:60189 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS (STODDARD SOLVENT) CAS:8052-41-3 Fraction by Wt: 24.9% Other REC Limits:NONE SPECIFIED OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:CALCIUM CARBONATE (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 21.8% Other REC Limits:NONE SPECIFIED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:MAGNESIUM SILICATE (TALC) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 4.4% Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3, 20 MPPCF ACGIH TLV:2 MG/M3, 15 MPPCF Ingred Name:TITANIUM DIOXIDE (TITANIUM OXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 21.8% Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE; IRRITATION OF EYES AND SKIN MAY OCCUR WITH OVEREXPOSURE. CONTINUED BREATHING OF VAPORS MAY IRRITATE RESPIRATORY TRACT. CHRONI C; REPORTS HAVE ASSOCIATED PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Effects of Overexposure:HEADACHE, NAUSEA, AND DIZZINESS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE VICTIM TO FRESH AIR. RESTORE RESPIRATION, IF NECESSARY, TREAT SYMPTOMATICALLY. EYE CONTACT: FLUSH IMMEDIATELY WITH COPIOUS AMOUNTS OF WATER FOR 15 MINUTES. CONSULT A PHYSICIAN. SKIN CONTACT: WASH AFFECTED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. INGESTION: DO NOT INDUCE VOMITING. CONTACT PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:105F,41C Autoignition Temp:Autoignition Temp Text:572 F Lower Limits:1.0 Upper Limits:6.0 Extinguishing Media:CO2, DRY CHEMICAL Fire Fighting Procedures:USE SCBA. WATER SPRAY MAY BE USEFUL IN MINIMIZING VAPORS & COOLING CONTAINERS EXPOSED TO HEAT AND FLAMES. Unusual Fire/Explosion Hazard:NO INFORMATION FOUND. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. WEAR APPROPRIATE PERSONAL PROTECTION EQUIPMENT AND APPROVED RESPIRATOR. CONTAIN SPILL & PUT IN VAPOR TIGHT CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN AREAS TO COMPLY WITH ANSI-NFPA 30 FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED NIOSH/MSHA ORGANIC VAPOR RESPIRATOR. Ventilation:SUFFICIENT VENT TO KEEP HAZARDOUS MATERIALS BELOW APPLICABLE EXPOSURE LEVELS. Work Hygienic Practices:WASH HANDS PROPERLY BEFORE EATING, DRINKING, OR USING WASHROOM FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:323F,162C Vapor Pres:2 Vapor Density:>1 Spec Gravity:1.375 Viscosity:77 - 89 KU Evaporation Rate & Reference:<1 (BU AC=1) Solubility in Water:N/L Appearance and Odor:LIQUID, ALIPHATIC ODOR Percent Volatiles by Volume:49.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HEAT, OPEN FLAME Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D001.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPOCAST 7W AT, FPC 2093 Kit Part:Y CAGE:0267X POLYMERS CAGE:99384 CAGE:0267X ============= Composition/Information on Ingredients ============= Ingred Name:BISPHENOL A-EPICHLOROHYDRIN COPOLYMER;(BISPHENOL A DIGLYCIDYL ETHER RESIN). LD50: (ORAL,RAT) >5,000 MG/KG. CAS:25068-38-6 RTECS #:SL6475000 Fraction by Wt: 74% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA GEL;(SILICA AMORPHOUS) CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: 5% OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:SILICIC ACID, CALCIUM SALT; (CALCIUM SILICATE) CAS:1344-95-2 RTECS #:VV9150000 Fraction by Wt: 5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:2(3H)-FURANONE, DIHYDRO-; (BUTYROLACTONE) CAS:96-48-0 RTECS #:LU3500000 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE;(TITANIUM DIOXIDE). CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CASTOR OIL, HYDROGENATED;(HYDROGENATED, CASTOR OIL). CAS:8001-78-3 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE; (SILICA CRISTOBALITE) CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 1% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.05 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHAL:VAP/MISTS MAY POSS BE HARMFUL IF INHALED. EYE: MODERATELY IRRIT TO EYES. INGEST: SLIGHTLY IRRITATING TO SKIN. INGEST: POSSIBLY BE HARMFUL IF SWALLOWED. DELAYED: PRLNGD/RPTD EXPOS CAN CAUSE ALLER GIC RXN. ALSO, RPTD OVEREXP OF DUST MAYCAUSE DELAYED & SERIOUS INJURY. THIS PRODUCT CONTAINS SILICA(EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-CRISTOBALITE:IARC MONO, SUPPLEMENT. VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON(SUPDAT) Effects of Overexposure:HLTH HAZ: CRISTOBALITE WHICH IS SUSPECTED OF CANCER HAZARD. Medical Cond Aggravated by Exposure:ALLERGY, ECZEMA OR EYE CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHAL: MOVE SUBJECT TO FRESH AIR. EYE: FLUSH W/LARGE AMOUNT OF WATER FOR AT LEAST 15 MINUTES. GET PROMPT MEDICAL ATTN. SKIN: WASH THOROUGHLY W/SOAP & WATER. REMOVE & WASH CLTHG BEFORE REUSE. INGEST: D ILUTE BY GIVING 2 GLASSES OF WATER TO DRINK. SEE MD. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. NOTE TO MD: ALLERGIC DERM/RESP RESPONSE IN SUSCEPTIBLE INDIVIDUALS MAY BE DELAYED.(SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:>208F,>98C Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER SPRAY. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP ALL TRACES OF SPILL. SHOVEL AS MUCH OF MATL AS POSSIBLE INTO CLEAN, DRY CNTNRS. ON HARD SURFACE USE ABSORB MATL TO PICK UP REMAINDER; ON LOOSE SURFACES SHOVEL UP CONTAMD LAYER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STOR TEMP 35C. AVOID ALL SKIN CONT. MAY CAUSE ALLERGIC RXN. WASH EXPOSED AREA THORO W/SOAP & WATER AFTER HNDLG MATL. Other Precautions:STORE IN COOL, DRY AREA W/ADEQUATE VENTILATION. PLEASE READ TECHNICAL DATA SHEET BEFORE HANDLING THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED IF GOOD VENTILATION IS MAINTAINED. WEAR RESPIRATOR(NIOSH/MSHA APPRVD) SUITABLE FOR CONCENTRATIONS & TYPE OF AIR CONTAMINANTS ENCOUNTERED. Ventilation:NORMAL ROOM VENTILATION. Other Protective Equipment:PROTECTIVE CLOTHING, EMERGENCY EYEWASH & DELUGE SHOWER WHICH MEETS ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: IT MAY APPEAR AFTER WEEKS/EVEN MONTHS OF FREQUENT & PROLONGED CONTACT. EXPLAN OF CARCIN: CARCINOGENS, 1994: ANTICIPATED TO BE CARCINOGENS. ================== Physical/Chemical Properties ================== HCC:V7 Vapor Pres:<1 @ 20C Vapor Density:>1 Spec Gravity:1.35 (H*2O=1) Evaporation Rate & Reference:<1 (BUAC=1) Solubility in Water:MODERATE Appearance and Odor:WHITE COLOR SOFT PASTE, NO ODOR. Percent Volatiles by Volume:<1(WT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, ACIDS. Stability Condition to Avoid:ELEVATED TEMPERATURES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, ALDEHYDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED EQUIPMENT. INCINERATE OR LANDFILL CONTAMD DIKING MATERIAL IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS(FP N).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FRESH GUARD CAGE:AIRKE CAGE:AIRKE CAGE:85884 ============= Composition/Information on Ingredients ============= Ingred Name:NONHAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN & EYES: MAY CAUSE IRRITATION. INGEST: MAY CAUSE STOMACH DISTRESS, NAUSEA OR VOMITING. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMED W/PLENTY OF COOL RUNNING WATER. REMOVE CONT LENSES. CONTINUE FLUSHING FOR @ LST 15 MIN. SKIN: FLUSH W/PLENTY OF COOL RUNNING WATER. WASH THORO W/SOAP & WATER. INGEST: RINSE MOUTH; TH EN DRINK 1-2 LG GLASSES OF WATER. DO NOT INDUCE VOMIT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O2/ARTF RESP) . IF IRRIT/ (SUPP DATA) ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:PRODUCT DOES NOT SUPPORT COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE/DAM LARGE SPILLS. PUMP TO CONTAINERS OR SOAK UP ON INERT ABSORBENT. FLUSH RESIDUE TO SANITARY SEWER. USE PROPER PROTECTIVE EQUIPMENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NO REQUIREMENTS BEYOND STANDARD INDUSTRIAL HYGIENE PRACTICES. Supplemental Safety and Health PH: 6.5-7.5 (100%). FIRST AID PROC: DISCOMFORT PERSISTS, CALL A PHYSICIAN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Spec Gravity:1.03-1.05 pH:SUPDAT Solubility in Water:COMPLETE Appearance and Odor:CLEAR YELLOW LIQUID; CHARACTERISTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:DO NOT MIX WITH ANYTHING BUT WATER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL AMOUNTS MAY BE SEWERED. CONSULT STATE, FEDERAL AND LOCAL AUTHORITIES FOR RESTRICTIONS ON DISPOSAL OF CHEMICAL WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SODIUM HYDROXIDE, PURUM PELLETS, S320 3, S320 50 Resp. Party Other MSDS Num.:21300 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE. (EINECS# 215-185-5) CAS:1310-73-2 RTECS #:WB4900000 = Wt:100. Other REC Limits:NIOSH 10MG/M3 IDLH OSHA PEL:2 MG/M3 TWA ACGIH TLV:C 2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT AVAILABLE. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: CAUSES DIGESTIVE AND RESPIRATORY TRACT BURNS. CAUSES SEVERE EYE AND SKIN BURNS. TARGET ORGANS: NONE. POTENTIAL HEALTH EFFECTS: EYE: CAUSES SEVERE EYE BURNS. SKIN: CAUSES SKIN BURN S. MAY CAUSE DEEP, PENETRATING ULCERS OF THE SKIN. INGESTION: HARMFUL IF SWALLOWED. CAUSES GASTROINTESTINAL TRACT BURNS. CAUSES SEVERE PAIN, NAUSEA, VOMITING, DIARRHEA, AND SHOCK. INHALATION: IRRITATI ON MAY LEAD TO CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. CAUSES SEVERE IRRITATION OF UPPER RESPIRATORY TRACT WITH COUGHING, BURNS, BREATHING DIFFICULTY, AND POSSIBLE COMA. CHRONIC: PROLONGED OR REPEAT ED SKIN CONTACT MAY CAUSE DERMATITIS. Explanation of Carcinogenicity:SODIUM HYDROXIDE - NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. Effects of Overexposure:N/P. FIRST AID (CONT): TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL AID. NOTES TO PHYSICIAN: TREAT SYMPTOMATICALL Y AND SUPPORTIVELY. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER LIDS. GET MEDICAL AID IMMEDIATELY. SKIN: GET MEDICAL ATTENTION IMMEDIATELY. IMMEDIATELY F LUSH SKIN WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. DISCARD CONTAMINATED CLOTHING IN A MANNER WHICH LIMITS FURTHER EXPOSURE. INGESTION: DO N OT INDUCE VOMITING. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL AID IMMEDIATELY. INHALATION: REMOVE FROM EXPOS URE (SIGNS & SYMPTOMS OF OVEREXPOSURE) ===================== Fire Fighting Measures ===================== Flash Point:NOT AVAILABLE. Autoignition Temp:Autoignition Temp Text:NOT AV Lower Limits:NOT AVAIL Upper Limits:NOT AVAIL. Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTENT FOAM. Fire Fighting Procedures:WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. WEAR A SELF-CONTAINED BREATHING APPARATUS (SCBA) (NIOSH APPROVED - ) TO PREVENT CONTACT WITH THERMAL DECOMPOSITION PRODU CTS. USE WATER WITH CAUTION AND IN FLOODING AMOUNTS. CONTACT WITH MOISTURE OR WATER (UNUSUAL FIRE AND EXPLOSION HAZARD) Unusual Fire/Explosion Hazard:N/P.FIRE FIGHTING PROCEDURE (CONT): MAY GENERATE SUFFICIENT HEAT TO IGNITE NEARBY COMBUSTIBLE MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. AVOID GENERATING DUSTY CONDITIONS. GENERAL INFORMATION: USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN (CONTROL ME ASURES) SECTION OF THIS MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLING: WASH THOROUGHLY AFTER HANDLING. USE WITH ADEQUATE VENTILATION. DO NOT ALLOW WATER TO GET INTO THE CONTAINER BECAUSE OF VIOLENT REACTION. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT I NGEST OR INHALE.STORAGE: STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM (OTHER PRECAUTIONS) Other Precautions:N/P. HANDLING AND STORAGE PRECAUTIONS (CONT): INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM STRONG ACIDS. KEEP AWAY FROM WATER. KEEP AWAY FROM METALS. KEEP AWAY FROM FLAMMABLE LIQUIDS. KEEP AWAY FROM ORGANIC HALOGENS. CORROSIVES AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH APPROVED AIR PURIFYING DUST OR MIST RESPIRATOR OR EUROPEAN STANDARD EN 149. EXPOSURE LIMITS: SODIUM HYDROXIDE: ACGIH - C 2 MG/M3; NIOSH - 10 MG/M3 IDLH; OSHA - FINAL PELS - 2 MG/M3 TWA. OS HA VACATED PELS: SODIUM HYDROXIDE: NO OSHA VACATED PELS ARE LISTED FOR THIS CHEMICAL. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. . Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SYNONYMS: CAUSTIC SODE, AETZNATRON, SODA LYE, SODIUM HYDRATE. PHYSICAL / CHEMICAL PROPERTIES (CONT): MOLECULAR FORMULA: HNAO. MOLECULAR WEIGHT: 40.00. EMERGENCY OVERVIEW: APPEARANCE: WHITE. D ANGER! CORROSIVE. HYGROSCOPIC. HAZARD SYMBOLS: C. RISK PHRASES: 35. ================== Physical/Chemical Properties ================== Boiling Pt:=1390.C, 2534.F B.P. Text:@ 760.00 MM HG. Melt/Freeze Pt:=318.C, 604.4F Decomp Temp:Decomp Text:NOT AVAILABLE. Vapor Pres:100 MM HG. Vapor Density:NOT AVAIL. Spec Gravity:2.1300 G/CM3. pH:NOT AVAILABLE. Viscosity:NOT AVAILABLE. Evaporation Rate & Reference:NOT AVAILABLE. Solubility in Water:1 G / 0.9 ML WATER. Appearance and Odor:WHITE SOLID. ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES GENERATES LARGE AMOUNTS OF HEAT WHEN IN CONTACT WITH WATER AND MAY STEAM AND SPLATTER. REACTS WITH MINERAL ACIDS TO FORM CORRESPONDING SALTS; REACTS WITH WEAK ACID GASES LIKE HYDROGEN SULFIDE, SULFUR DIOXIDE, AND CARBON DIO Stability Condition to Avoid:INCOMPATIBLE MATERIALS, MOISTURE, CONTACT WITH WATER, ACIDS. Hazardous Decomposition Products:TOXIC FUMES OF SODIUM OXIDE, SODIUM PEROXIDE FUMES. Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED. =================== Toxicological Information=================== Toxicological Information:LD50/LC50: NOT AVAILABLE. CARCINOGENICITY: NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. EPIDEMIOLOGY: NO INFORMATION REPORTED. TERATOGENICITY: NO INFORMATION REPORTED. REPRODUCTIVE EFFECTS: NO INFO RMATION REPORTED. NEUROTOXICITY: NO INFORMATION REPORTED. MUTAGENICITY: MUTATION DATA REPORTED. OTHER STUDIES: NO INFORMATION REPORTED. OTHER INFO (CONT): CANADA'S INGREDIENT DISCLOSURE LIST. EXP OSURE LIMITS: CAS # 1310-73-2: OEL - AUSTRALIA: TWA 2 MG/M3. OEL - BELGIUM: STEL 2 MG/M3. OEL DENMARK: TWA 2 MG/M3. OEL - FINLAND: TWA 2 MG/M3. OEL - FRANCE: TWA 2 MG/M3. OEL - GERMANY: TWA 2 MG/M3. O EL - JAPAN: STEL (ECOLOGICAL INFO) ===================== Ecological Information ===================== Ecological:ECOTOXICITY: TLM, MOSQUITO FISH, 125 PPM/96HR. (FRESH WATER); TLM, BLUEGILL, 99 MG/48HR. (TAP WATER). ENVIRONMENTAL FATE: THIS CHEMICAL IS NOT MOBILE IN SOLID FORM, ALTHOUGH IT ABSORBS MOISTURE VERY EASILY. ONCE LIQUID, SODIUM HYDROXIDE LEACHES RAPIDLY INTO THE SOIL, POSSIBLY CONTAMINATING WATER SOURCES. PHYSICAL/CHEMICAL: NO INFORMATION FOUND.OTHER: NO INFORMATION FOUND. TOX INFO (CONT): 2 MG/M3. OEL - THE NETHERLANDS: TWA 2 MG/M3. OEL - THE PHILLIPINES: TWA 2 MG/M3. OEL - SWEDEN: TWA 2 MG/M3. OEL - SWITZERLAND: TWA 2 MG/M3, STEL 4 MG/M3. OEL - THAILAND: TWA 2 MG/M3. OEL - TURKEY: TWA 2 MG/M3. OEL - UNITED (TRANSPORT INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATIONS OF CONTAMINATES, RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS, RCRA F-SERIES, RC RA P-SERIES, AND RCRA U-SERIES: NONE LISTED. NOT LISTED AS A MATERIAL BANNED FROM LAND DISPOSAL ACC ORDING TO RCRA. =================== MSDS Transport Information =================== Transport Information:US DOT: SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZARD CLASS: 8. UN NUMBER: UN1823. PACKING GROUP: II. IMO: SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZARD CLASS: 8. UN NUMBER: 1823. PACKING GROUP: 2 . IATA: SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZARD CLASS: 8. UN NUMBER: 1823. PACKING CLASS: 2. RID/ADR: SHIPPING NAME: SODIUM HYDROXIDE, SOLID. DANGEROUS GOODS CODE: 8 (41B). UN NUMBER: 1823. CANADIAN TDG: SHIPPING NAME: SODIUM HYDROXIDE. HAZARD CLASS: 8 (9.2). UN NUMBER: UN1823. ECOLOGICAL INFO (CONT): KINGDOM: TWA 2 MG/M3; STEL 2 MG/M3. OEL IN BULGARIA, COLOMBIA CHECK ACGIH TLV. C ONTACT NEHC FOR ADDITIONAL INFO ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): CAS # 1310-73-2: FINAL RQ= 1000 POUNDS (454 KG). SECTION 302 (TPQ): NONE OF THE CHEMICALS IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS # 1310-73-2: ACUTE, REACTIVE. SECTION 313: NOCHEMICALS ARE REPORTABLE UNDER SECTION313. FEDERAL REGULATORY (CONT): CAS # 1310-73-2 IS LISTED AS A HAZARDOUS SUBSTANCE UNDER THE CWA. NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED AS PRIORI TY POLLUTANTS UNDER THE CWA. NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED AS TOXIC POLLUTANTS UNDER THE CWA. OSHA: NONE OF THE CHEMICALS IN THIS PRODUCT ARE CONSIDERED HIGHLY HAZARDOUS BY OSHA. Federal Regulatory Information:TSCA: CAS# 1310-73-2 IS LISTED ON THE TSCA INVENTORY. HEALTH AND SAFETY REPORTING LIST: NONE OF THE CHEMICALS ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEMICAL TEST RULES: NONE OF THE CHEMICALS IN THIS PRODUCT ARE UNDER A CHEMICAL TEST RULE.SECTION 12B: NONE OF THE CHEMICALS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMICALS IN THIS MATERIAL HAVE A SNUR UNDER TSCA. CLEAN AIR ACT: THIS MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS. THIS MATERI AL DOES NOT CONTAIN ANY CLASS 1 OZONE DEPLETORS. THIS MATERIAL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: (SARA III) State Regulatory Information:SODIUM HYDROXIDE CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHE MICALS IN THIS PRODUCT ARE LISTED. EUROPEAN / INTERNATIONAL REGULATIONS: EUROPEAN LABELING IN ACCORDANCE WITH EC DIRECTIVES: HAZARD SYMBOLS: C. RISK PHRASES: R 35 CAUSES SEVERE BURNS. SAFETY PHRASE S: S 26 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL 45 IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (OTHER INFO) ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & SYNTHETIC RUBBER COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RO 30, 3180-00 Preparer's Name:JENNIFER HALL CAGE:EO350 CAGE:EO350 ============= Composition/Information on Ingredients ============= Ingred Name:DISTILLATES, CLAY-TREATED HEAVY NAPHTHENIC; (MINERAL OIL PETROLEUM) CAS:64742-44-5 RTECS #:SE7449700 Fraction by Wt: 100% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:SUPDAT:LIKELIHOOD OF SPLASHING, OIL RESIST CLTHG SHOULD BE WORN. NEVER WEAR OIL SOAKED CLTHG. LAUNDER/DRY CLEAN (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:BEFORE WEARING. DISCARD OIL SOAKED SHOES. AFFIX WARNING LABELS ON CONTAINERS I/A/W 29 CFR 1910.1200 (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:(HAZARD COMMUNICATION STANDARD). RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT:NOT USE GASOLINE, SOLVS, KEROSENE/HARSH ABRASIVE SKIN CLEANERS FOR WASHING EXPOS SKIN AREAS. TAKE A(ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:SHOWER AFTER WORK IF GEN CONT OCCURS. REMOVE OIL-SOAKED CLTHG & LAUNDER BEFORE REUSE. LAUNDER/DISCARD (ING 7) RTECS #:9999999ZZ RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:TESTS ON SIMILAR MATERIALS SUGGEST THAT NO SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED TO OCCUR UPON SHORT-TERM EXPOSURE. INGESTION:PRACTICALLY NON-TOXIC. CHRONIC:PROLONGED AND/OR REPEATED C ONTACT WITH THIS MATERIAL MAY PRODUCE SKIN IRRITATION AND INFLAMMATION. TOXICOLOGICAL INFORMATION:TESTS(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:ON SIMILAR MATERIALS SHOW A LOW ORDER OF ACUTE ORAL AND DERMAL TOXICITY. LOW ACUTE TOXICITY EXPECTED ON INHALATION. EYE EFFECTS:MINIMAL IRRITATION ON CONTACT. SKIN EFFECTS:PRACTICALLY NON-TOX IC IF ABSORBED. MAY CAUSE MILD IRRITATION WITH PROLONGED AND REPEATED CONTACT. THIS PRODUCT IS SEVERELY HYDROTREATED. Medical Cond Aggravated by Exposure:PERSONNEL W/PRE-EXISTING SKIN DISORDERS SHOULD AVOID CONTACT W/THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH IMMED W/WATER FOR AT LST 15 MINS/UNTIL IRRIT SUBSIDES. IF IRRIT PERSISTS, CONSULT MD. SKIN:WASH THORO W/SOAP & WATER. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. IF IRRIT/RASH DEVELS, OBTAIN M ED ASSISTANCE. IMMED REMOVE SOAKED CLTHG. INGEST:DO NOT INDUCE VOMIT. OBTAIN EMER MED ATTN. INHAL:REMOVE PATIENT TO FRESH AIR & CONSULT MD. IF BRTHG IS DFCLT, GIVE OXYG. IF NOT BRTHG, GIVE ARTF RESP. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>350F,>177C Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER FOG & FOAM. NOTE:WATER, FOG & FOAM MAY CAUSE FROTHING & SPATTERING. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROT EQUIP . USE WATER TO COOL CNTNRS EXPOSED TO FLAMES. DO NOT ENTER ENCLSD/CONFINED WORK SPACE W/OUT PROPER PROT EQUIP. Unusual Fire/Explosion Hazard:SLIGHTLY COMBUST. OSHA/NFPA CLASS IIIB COMBUST LIQ. IF HEATED ABOVE ITS FLASH POINT WILL RELS FLAMM VAPS WHICH CAN BURN IN OPEN/BE EXPLO IN CONFINED (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNITION SOUCES. CONTAIN SPILL & KEEP FROM ENTERING WATERWAYS OR SEWERS. USE PERSONAL PROTECTIVE EQUIPMENT. ADVISE EPA; STATE AGENCY IF REQUIRED. ABSORB ON INERT MATERIAL. SHOVEL, SWEEP OR VA CUUM SPILL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM FLAMES, SPARKS OR HOT SURFACES. NEVER USE A TORCH TO CUT OR WELD ON OR NEAR CONTAINER. EMPTY OIL CONTAINERS CAN CONTAIN EXPOSIVE VAPS. Other Precautions:NFPA CLASS IIIB STORAGE. AVOID PROLONGED &/OR REPEATED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMALLY NOT REQUIRED IF ADEQUATE VENTILATION. IF OCCUPATIONAL EXPOSURE LIMITS ARE EXCEEDED WEAR NIOSH APPROVED APPARATUS. Ventilation:USE ADEQUATE VENTILATION TO KEEP OIL MISTS OF THIS MATERIAL BELOW APPLICABLE STANDARD(S). Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . IF PRLNG CONT CANNOT BE AVOIDED, WEAR IMPERVIOUS CLTHG. IF(SUPDAT) Work Hygienic Practices:WASH THORO AFTER HNDLG. WASH HANDS W/SOAP & WATER BEFORE EATING, DRINKING, SMOKING/USE OF TOILET FACILITIES. DO (ING 5) Supplemental Safety and Health VP:<0.0001 @ 20C. EXPLO HAZ:SPACES IF EXPOS TO IGNIT SOURCE. MISTS/SPRAYS MAY BE FLAMM BELOW OIL'S NORMAL FLASH POINT. KEEP AWAY FROM EXTREME HEAT/OPEN FLAME. PRODS OF COMBUST INCL FUMES, SMOKE & POLYVINYL ALCOHOL; VITON). OTHER PROT EQUIP:THERE IS A (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>500F,>260C Vapor Pres:SUPP DATA Vapor Density:>5 Spec Gravity:0.9 (H*2O=1) pH:NEUT Evaporation Rate & Reference:1000X SLOWER/ETHYL ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, PALE, STRAW COLORED LIQUID; LIGHT BLAND PETROLEUM ODOR. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:SOURCES OF IGNITION. Hazardous Decomposition Products:COMBUSTION MAY PRODUCE CARBON MONOXIDE & OTHER ASPHYXIANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW FED, STATE & LOCAL REGS. NOT A RCRA HAZ WASTE IF UNCONTAM. IF "USED", RCRA CRITERIA MUST BE DETERMINED. DO NOT FLUSH TO DRAIN/STORM SEWER. CONTRACT TO AUTHORIZED DISPOSAL SERVICE. IF PERMITTED INCIN MAY BE PRACTICAL. RECOMMEND RECYCLING.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:131 6363 EKTACHEM REFERENCE FLUID II Kit Part:Y CAGE:DO392 CAGE:19139 CAGE:03KD1 CAGE:DO392 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 80-85% Other REC Limits:NONE RECOMMENDED Ingred Name:CESIUM CHLORIDE CAS:7647-17-8 RTECS #:FK9625000 Fraction by Wt: 15-20% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM BICARBONATE CAS:144-55-8 RTECS #:VZ0950000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:POLY(1-VINYL-2-PYRROLIDINONE) CAS:9003-39-8 RTECS #:TR8160000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM HYDROXIDE (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/INHAL:LOW HAZARD FOR RECOMMENDED HANDLING. EYES:NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRITATION. INGEST:EXPECTED TO BE A LOW INGEST HAZ. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY CLASSIFICATION:IARC/ACGIH/NTP/OSHA:NONE. Effects of Overexposure:TRANSIENT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:IF SYMPTOMATIC MOVE TO FRESH AIR. GET MED ATTN IF SYMPTONS PERSIST. EYES:ANY MATL THAT CONTACTS EYE SHOULD BE WASHED OUT IMMED W/WATER. GET MED ATTN. SKIN:WASH W/SOAP & WATER. GET MED ATTN IF SY MPTOMS OCCUR. INGEST:DRINK 1-2 GLASSES OF WATER. SEEK MED ATTN. NEVER GIVE ANYTHING BY MOUTH TO UNCONSC PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONE,NON-COMBUST Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE ABSORB W/VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN CONTAINER FOR CHMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENTILATION. KEEP CNTNR CLSD. STORAGE ABOVE 8C(46F) MAY AFFECT PRODUCT QUALITY. STORAGE BELOW 2C(36F) MAY AFFECT PRODUCT QUALITY. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYEBATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH W/SOAP & WATER AFT HNDLG. FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES. WASH CONTAMIN CLOTHING BEF REUSE. Supplemental Safety and Health PER MSDS:18 VIALS. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18MM Vapor Density:0.6 Spec Gravity:1.168 pH:9.5 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, COLORLESS, ODORLESS. Percent Volatiles by Volume:80-85 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE WITH COMMON MATERIALS & CONTAMINANTS W/WHICH THE MATERIAL MAY REASONABLY COME INTO CONTACT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HYDROGEN CHLORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREATMENT/DISPOSAL MAY BE SUBJECT TO NATIONAL/STATE/LOCAL LAWS. FLUSH TO SEWER W/LG AMTS OF WATER. CHEM SUBJ TO REPORTING REQMTS OF SEC 313 OF TITLE III OF SARA & 40CFR PART 372:NONE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PETROLEUM ETHER CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS CAS:8032-32-4 Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHRONIC:REPEATED OR PROLONGED INHALATION MAY CAUSE DIZZINESS, WEAKNESS,WEIGHT LOSS,ANEMIA,PAINS IN THE LIMBS,PERIPHERAL NUMBNESS,& PARESTHESIAS; PROLONGED SKIN Effects of Overexposure:INHALE:NAUSEA,VOMITING,COUGH,& PULMONARY IRRITATION PROGRESSING TO PULMONARY EDEMA,BLOODY SPUTUM & BROCHIAL PNEUMONIA WITH FEVER & COUGH; SKIN:IRRITATION,DEFATTOW & SHALLOW RESPERIATION, UNCONSCIOUSNE SS, & CONVULSIONS. Medical Cond Aggravated by Exposure:NONE STATED. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE FROM EXPOSURE, IF BREATHING HAS STOPPED,GIVE ARTIFICIAL RESPIRATION; SKIN:REMOVE CONTAMINATED CLOTHING & SHOES,WASH AFFECTED AREAS WITH SOAP OR MILD DETERGENT & LARGE AMOUNTS OF WATER, I H LARGE AMOUNTS OF WATER,OCCATIONALLY LIFTING UPPER & LOWER EYELIDS; INGEST:DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:<0F/-18C Lower Limits:1.1 Upper Limits:5.9 Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL FOAM. Fire Fighting Procedures:COOL FIRE EXPOSED CONTAINERS WITH WATER FROM SIDE UNTIL WELL AFTER FIRE IS OUT. Unusual Fire/Explosion Hazard:NONE STATED. ================== Accidental Release Measures ================== Spill Release Procedures:FOR SMALL SPILLS, TAKE UP WITH SAND OR OTHER INERT ABSORBENT MATERIAL AND PLACE INTO CONTAINERS FOR LATER DOSPOSAL. CLOSE CONTAINERS TIGHTLY AND LABEL FLAMMABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH SKIN OR CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, USE CHEMICAL CARTRIDGE RESPIRATOR WITH A FULL FACE-PIECE AND AN ORGANIC VAPOR CARTRIDGE. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION OR GENERAL DILUTION VENTILATION TO MEET PEL LIMITS. USE EXPLOSION-PROOF EQUIPMENT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:=35.C, 95.F Melt/Freeze Pt:=-40.C, -40.F Vapor Pres:40 Spec Gravity:0.6 Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS LIQUID WITH AN ODOR LIKE GASOLINE OR KEROSENE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG OXIDANTS. Stability Condition to Avoid:AWAY FROM HEAT OR SPARKS OR IGNITION SOURCES. Hazardous Decomposition Products:TOXIC OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW ALL FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:517-, ACUFLEX Preparer's Name:ROBERT J. HARRIS CAGE:70103 CAGE:70103 ============= Composition/Information on Ingredients ============= Ingred Name:EPOXY RESIN Ingred Name:POLYURETHANE RESIN Ingred Name:SILICONE RESIN Ingred Name:OIL-MODIFIED ALKYD RESIN Ingred Name:BACKING (CLOTH, FIBER, PAPER); (SUBSTRATE (CLOTH, MAT, FILM, PAPER)) Ingred Name:COATING CONTAINING INGREDIENT 9 OR 10 RTECS #:9999999ZZ Ingred Name:ACRYLIC ADHESIVE;(PRESSURE-SENSITIVE ACRYLIC ADHESIVE) Ingred Name:MICA;(MICA DUST) CAS:12001-26-2 RTECS #:VV8760000 OSHA PEL:20 MPPCF ACGIH TLV:3 MG/M3 RDUST; 9293 Ingred Name:FULLY CURED RESINS (CONSISTING OF INGREDIENTS 2-6). IMPREGNATED OR COATED ON INGREDIENT 7. RTECS #:9999999ZZ Ingred Name:POLYESTER RESIN ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO ADVERSE ACUTE OR CHRONIC HEALTH EFFECTS ARE EXPECTED FROM HANDLING THESE MATERIALS. SOME INDIVIDUALS MAY EXPERIENCE MILD TRANSIENT SKIN IRRITATION FROM REPEATED HANDLING, AND EXPOSED FIBERGLASS ALO NG SLIT EDGES OF MATERIAL MAY ALSO CAUSE MINOR SKIN IRRITATION. IF MATERIAL IS SUPPLIED WITH MICA (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:DUST, INHALATION OF THIS DUST MAY PRODUCE MECHANICAL IRRITATION OF NOSE, THROAT AND UPPER RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH POTABLE WATER FOR A MINIMUM OF 15 MINUTES. GET MD . INHAL:MOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTF RESP) . SKIN:FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:WATER, DRY CHEMICAL, CO2 OR FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE STANDARD METHODS. Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA APPROVED DUST MASK SHOULD BE WORN IF NECESSARY FOR WORKER COMFORT OR IN THE UNLIKELY EVENT THAT AIRBORNE DUST CONCENTRATIONS GENERATED DURING HANDLING EXCEED THE OSHA PEL. Ventilation:THOROUGH GENERAL VENTILATION. Other Protective Equipment:NO SPECIFIC PROTECTIVE EQUIPMENT IS REQUIRED. Work Hygienic Practices:PROPER INDUSTRIAL HYGIENE RECOMMENDED. Supplemental Safety and Health APPEAR/ODOR:IN COLOR. BLACK OLEORESINOUS- VARNISHED MATERIAL MAY HAVE CHARACTERISTIC GREASY FINISH. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:FLEXIBLE SHEETS OR TAPES; YELLOW TAN, WHITE, GRAY, BLACK, BROWN OR BLUE (SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:FULLY CURED INSULATION IS NOT A HAZARDOUS WASTE UNDER CURRENT RCRA AND CERCLA DEFINITIONS. DISPOSAL MUST BE IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MALEIC ACID Preparer's Name:ALEXANDER A. PICCIRILLI CAGE:63759 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:MALEIC ACID (CERCLA) CAS:110-16-7 RTECS #:OM9625000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 708MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:CORROSIVE.MAY CAUSE IRRITATION,POSSIBLE CORNEAL EROSION.SKIN:MAY CAUSE IRRITATION AND DERMATITIS.INGEST:MODERATELY TOXIC.MAY BE FATAL IF SWALLOWED.MAY CAUSE GI TRACT IRRITATION.MAY DAMAGE MOUTH,E SOPHAGUS AND STOMACH.INHAL:MAY CAUSE RESPIRATORY IRRITATION. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:DIFFICULTY BREATHING,COUGHING.EYES:REDNESS,PAIN. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.GET MEDICAL ATTENTION.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.GET MEDI CAL ATTENTION.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE 1-2 GLASSES OF WATER OR MILK. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER SPRAY,DRY CHEMICAL(ABC),CARBON DIOXIDE,HALON,STANDARD FOAM. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:SUBLIMES AT 396F;EMITS FUMES UPON HEATING.DECOMPOSITION FUMES MAY BE TOXIC.REACTS VIGOROUSLY WITH OXIDIZING AGENTS. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER IF NOT CONTAMINATED.USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.SWEEP OR VACUUM;DO NOT CREATE DUST;PLACE IN AN APPROPRIATE CONTAINER FOR DISPOSAL.FLUSH SPILL AREA WITH WATER.DO NOT POLLUTE WATERWAYS WITH RINSEATE. Neutralizing Agent:NOT REPORTED. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS. Other Precautions:AVOID SKIN AND EYE CONTACT.DO NOT INHALE VAPORS/MISTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A NIOSH/MSHA APPROVED RESPIRATOR FOR DUST. Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL. Other Protective Equipment:SMOCK,APRON.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:EXECISE GOOD LABORATORY PRACTICES.WASH HANDS AFTER USE AND BEFORE EATING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:268F,131C Decomp Temp:Decomp Text:275F,135C Vapor Pres:NEGLIGIBLE Vapor Density:4.0 Spec Gravity:1.59 Evaporation Rate & Reference:NON-VOLATILE Solubility in Water:APPRECIABLE Appearance and Odor:WHITE CRYSTALLINE POWDER;FAINT ACIDULOUS ODOR. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS,ALKALI METALS,STRONG BASES,AMINES.SOLUTIONS OF MALEIC ACID MAY CORRODE METAL. Stability Condition to Avoid:AT 230C,IT CONVERTS TO FUMARIC ACID AND UNDERGOES PARTIAL CARBONIZATION AND FORMATION OF MALEIC ANHYDRIDE. Hazardous Decomposition Products:AT 230C,CONVERTS TO FUMARIC ACID AND UNDERGOES PARTIAL CARBONIZATION AND FORMATION OF MALEIC ANHYDRIDE(READILY SUBLIMES) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.MAY BE INCINERATED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:199/R-442-STARCH ACID/SULFITE INDICATOR POWDER CAGE:OAFT1 CAGE:94525 CAGE:OAFT1 ============= Composition/Information on Ingredients ============= Ingred Name:SULFAMIC ACID CAS:5329-14-6 RTECS #:WO5950000 Fraction by Wt: <85% Ingred Name:STARCH, SOLUBLE *94-4* CAS:9005-84-9 Fraction by Wt: <15% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION & BURNS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNS. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. INGESTION: INDUCE VOMITING. DILUTE BY GIVING PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON FLAMMABLE Extinguishing Media:WATER, ALCOHOL FOAM, DRY CHEMICAL Fire Fighting Procedures:USE A SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/VERMICULITE/SIMILAR ABSORBENT, SWEEP UP & PLACE IN DRY GARBAGE; FLUSH TO SEWER/GROUND W/PLENTY OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA AWAY FROM ANY REACTIVE MATERIALS/CHEMICALS. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST Other Protective Equipment:RUBBER APRON. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:COMPLETE Appearance and Odor:WHITE POWDER W/NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIS OXIDIZER, ANY REACTIVE MATERIALS. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DS 8000 SERIES ADHESIVE, 8014 Preparer's Name:BILL MCDONALD CAGE:0FSN9 CAGE:0FSN9 ============= Composition/Information on Ingredients ============= Ingred Name:PHENOL, POLYMER WITH FORMALDEHYDE, GLYCIDYL ETHER; (EPOXY NOVOLAC RESIN) CAS:28064-14-4 Fraction by Wt: 70-80% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:7-OXABICYCLO(4.1.0)HEPTANE, 3-(EPOXYETHYL)-; (VINYLCYCLOHEXENE DIOXIDE) CAS:106-87-6 RTECS #:RN8640000 Fraction by Wt: 15-25% OSHA PEL:10 PPM, S ACGIH TLV:10 PPM; A2, S Ingred Name:REFRACTORY FIBERS, ALUMINOSILICATE; (ALUMINOSILICATE (VITREOUS) CERAMIC FIBERS) CAS:142844-00-6 Fraction by Wt: 0-5% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:10 MG/M3 (MFR) Ingred Name:SILICA, AMORPHOUS FUMED; (FUMES SILICA, CRYSTALLINE-FREE) CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: 0-10% OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): >4000 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE IRRIT, NASAL DISCOMFORT, & DISCHARGE. USE ONLY W/ADEQ VENT. SKIN: SINGLE DOSE EXPOS IS NOT LIKELY TO RSLT IN MATL BEING ABSORBED THRU SKIN IN HARMFUL AMTS. EYES: MAY CAUSE SLIG HT TRANSIENT IRRIT & PAIN. SEV EXCESS REDDENING & SWELL OF CORNEA MAY OCCUR. INGEST: SINGLE DOSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:VINYLCYCLOHEXENE DIOXIDE: IARC MONOGRAPHS, VOLUME 60, PAGE 361, 1994: GROUP 2B. NTP 7TH ANNUAL REPORT ON (SUP DAT) Effects of Overexposure:HLTH HAZ: ORAL TOXICITY IS LOW. SML AMTS SWALLOWED INCIDENTAL TO NORM HNDLG OPERATIONS ARE NOT LIKELY TO CAUSE INJURY ALTHOUGH MAY CAUSE NAUS, ABDOM DISCOMFORT, VOMIT, & DIARR. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. INGESTION: INDUC E VOMITING. INHALATION: REMOVE TO FRESHAIR. CONSULT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:428F,220C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, WATER, AND ALCOHOL RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MAY POLYMERIZE UNDER EXTREME HEAT AND RUPTURE A CLOSED CONTAINER. EXPOSURE TO HIGH TEMPERATURES MAY CAUSE INSTABILITY. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP IN ABSORBENT MATERIAL AND COLLECT IN SUITABLE CONTAINERS. RESIDUAL RESIN MAY BE REMOVED WITH STEAM OR HOT SOAPY WATER. USE OF METHYLENE CHLORIDE OR SOLVENTS SHOULD BE AVOIDED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PRACTICE GOOD CAUTION AND PERSONAL CLEANLINESS TO AVOID CONTACT WITH SKIN AND/OR EYES. AVOID BREATHING VAPORS FROM MATERIAL. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR MOST CONDITIONS, NO RESPIRATORY PROTECTION SHOULD BE NEEDED; HOWEVER, IF HANDLING AT ELEVATED TEMPERATURES WITHOUT SUFFICIENT VENTILATION, USE A NIOSH APPROVED, FULL-FACE, AIR-PURIFYING RESPIRATOR . Ventilation:USE ONLY WITH ADEQUATE VENTILATION. LOCAL EXHAUST VENTILATION MAY BE NECESSARY FOR SOME OPERATIONS. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . WEAR CLEAN BODY COVERING/CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MATLS TO AVOID: WATER. DECOMP PRODS SHOULD BE TREATED AS POTENTIALLY HAZ SUBSTANCES, W/APPROP PREC. EXPLAN OF CARCIN: CARCINOGENS, 1994: ANTICIPATED TO BE CARCINOGEN. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>464F,>240C Vapor Pres:<20 @ 20C Spec Gravity:1.20 Solubility in Water:<2% @ 25C Appearance and Odor:GRAY VISCOUS LIQUID WITH MILD ETHER ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONT WITH AMINES, STRONG ALKALINE MATERIALS, MINERAL ACIDS, METAL SALTS. REACTION WITH AMINES MAY GENERATE HEAT. Stability Condition to Avoid:AVOID EXCESSIVE HEATING OVER LONG PERIODS WHICH MAY DEGRADE THE RESIN. Hazardous Decomposition Products:UNLIKELY TO OCCUR BY ITSELF, HOWEVER, INCOMPLETE COMBUST/PYROLYSIS WILL RSLT IN PHENOLICS, CARBON MONOXIDE, & (SUP DAT) Conditions to Avoid Polymerization:MASSES OF >1 LB OF PRODUCT PLUS ALIPHATIC AMINE WILL CAUSE IRREVERSIBLE POLYMERIZATION W/CONSIDERABLE HEAT BUILD UP. ==================== Disposal Considerations ==================== Waste Disposal Methods:RESINS CAN BE DISPOSED OF BY INCINERATION/LANDFILL I/A/W LOCAL, STATE & FEDERAL REGULATIONS. AFTER 2 EPOXY COMPONENTS IN ADHESIVE KIT HAVE REACTED, RESULTING MATERIAL MAY QUALIFY FOR NONHAZARDOUS WAST E DISPOSAL UNDER APPROPRIATE REGULATORYSTATUS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LEAD-FREE YELLOW TREE MARKING PAINT, E&I 23 17 Preparer's Name:DOYLE YODER CAGE:17833 CAGE:17833 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: <15% OSHA PEL:200 PPM, S ACGIH TLV:200PPM/250STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:STODDARD SOLVENT; (ALIPHATIC HYDROCARBONS) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: <35% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:SUP DAT: FLAME, SPKS, STATIC ELEC/OTHER SOURCES OF IGNIT: THEY MAY EXPLODE & CAUSE INJURY/DEATH. EMPTY DRUMS (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED & PROMPTLY RETURNED TO DRUM RECONDITIONER/PROPERLY DISP OF. (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: CAUSE INTOXICATION & CNS DEPRESS. METHANOL IS METABOLIZED TO FORMIC ACID & FORMALDEHYDE. THESE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: METABOLITES CAN CAUSE METABOLIC ACIDOSIS, VISUAL DISTURB & BLINDNESS. SINCE METABOLISM IS REQUIRED FOR (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: THESE TOX SYMPS, THEIR ONSET MAY BE DELAYED FROM 6-30 HRS FOLLOWING INGEST. ETHANOL COMPETES FOR THE SAME(ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: METABOLIC PATHWAY & HAS BEEN USED TO PVNT METHANOL METABOLISM. ETHANOL ADMIN IS INDICATED IN SYMPTOMATIC(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: PATIENTS/AT METHANOL CONCS ABOVE 20 UG/DL. METHANOL IS EFFECTIVELY REMOVED BY HEMODIALYSIS. KEEP PERS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: WARM, QUIET & GET IMMED MED ATTN. DO NOT INDUCE VOMIT, BECAUSE ASPIR OF MATL INTO LUNGS FROM VOMIT CAN (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. RTECS #:9999999ZZ Ingred Name:SPILL PROC: AVOID RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO WATERWAYS. RTECS #:9999999ZZ Ingred Name:RESP PROT: NIOSH APPRVD POS PRESS AIR SUPPLIED RESP IF THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE, EXPOS (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: LEVELS ARE NOT KNOWN/ANY OTHER CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQ PROTECTION. RTECS #:9999999ZZ Ingred Name:OTHER PREC: USE ONLY IN WELL-VENTD AREA. GROUND & BOND CONTRS WHEN TRANSFERRING MATL. USE SPK-PROOF TOOLS & (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: EXPLO-PROOF EQUIP. AVOID PRLNG/RPTD CONT W/SKIN. AVOID BRTHG VAPS FROM HEATED MATL. AVOID CONT W/EYES & CLTHG. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:LIQ, AEROSOLS & VAPS ARE IRRIT & CAN CAUSE PAIN, TEARING, REDDENING & SWELL W/STINGING SENSATION &/FEELING LIKE THAT OF FINE DUST IN EYES. SKIN:PRLNG/RPTD CONT CAN RSLT IN DEFAT & DRYING OFSKIN WHICH MAY RSLT IN SKIN IRRIT & DERM (RASH). INHAL:HDCH, DIZZ, NAUS, DECRD BLOOD PRESS, CHANGES IN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:HEART RATE & CYANOSIS (BLUISH DISCOLORATION OF SKIN & NAILS) MAY RSLT FROM OVEREXP TO VAP/SKIN EXPOS. INGEST:MAY BE HARMFUL/FATAL. CHRONIC:RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIBERATELY CONC & INHALING CONTENTS MAY BE HARMFUL/FATAL. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. GET IMMED MED ATTN. SKIN: IMMED FLUSH W/PLENTY OF WATER. WASH W/SOAP & WATER. REMOVE SOILED CLTHG & WASH SEPARATELY BEFORE REUSE. GET MED ATTN I F IRRIT DEVELOPS/PERSISTS. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. GET IMMED MED ATTN. INGEST: NOTE TO MD: PROD CONTAINS METHANOL WHICH CAN (ING 8) ===================== Fire Fighting Measures ===================== Flash Point:72.0F,22.2C Lower Limits:1.0% Upper Limits:36.0% Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . CONTRS CAN BUILD UP PRESS IF EXPOSED TO HEAT (FIRE). WATER RUNOFF CAN CAUSE ENVIRON DMG. DIKE & (SUP DAT) Unusual Fire/Explosion Hazard:AVOID BRTHG DUSTS & FUMES FROM BURNING MATL. VAPS MAY FORM EXPLO MIXT W/AIR. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. "EMPTY" CONTRS RETAIN (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERS. REMOVE ALL SOURCES OF IGNIT. VENT AREA. EQUIP EMPLOYEES W/APPROP PROT EQUIP. DIKE AROUND SPILLED MATL. COVER SPILL W/ABSORB MATL & SHOVEL W/NON-SPK TOOLS INTO CONTR. R EMOVE CONTRS TO SAFE AREA & SEAL. (ING 15) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM HEAT, SPKS & FLAME. KEEP CONTR CLSD WHEN NOT IN USE. DO NOT INHALE MIST/VAPOR. Other Precautions:KEEP OUT OF REACH OF CHILDREN. APPLY W/BACK TO WIND DURING OUTDOOR APPLICATION. CONTRS OF THIS MATL MAY BE HAZ WHEN EMPTIED. SINCE EMPTIED CONTRS RETAIN PROD RESIDUES (VAP, LIQ &/SOLID), ALL HAZ PREC GIVEN IN MSDS MUST BE OBSERVED. (ING 18) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH APPRVD AIR PURIFYING RESP W/ORG VAP CARTRIDGE/CANISTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONCS ARE EXPECTED TO EXCEED EXPOS LIMS. PROT PROVIDED BY AIR PURIFYING RES PS IS LIMITED. USE NIOSH APPRVD (ING 16) Ventilation:LOCAL EXHAUST VENTILATION MAY BE NEC TO CONTROL ANY AIR CONTAMINANTS TO W/IN THEIR TLVS DURING USE OF THIS PRODUCT. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . CHEMICAL RESISTANT SUIT AND RUBBER BOOTS. Work Hygienic Practices:WASH THORO AFTER HNDLG. DO NOT WEAR CONT LENSES. WASH HANDS BEFORE EATING/SMKNG. REMOVE CONTAM CLTHG, WASH BEFORE REUSE. Supplemental Safety and Health FIRE FIGHT PROC: COLLECT WATER USED TO FIGHT FIRE. WATER SPRAY MAY BE USED FOR COOLING CONTRS TO PVNT POSS PRESS BUILD-UP & AUTO-IGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: PROD RESIDUE (LIQ &/VAP) & CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE SUCH CONTRS TO HEAT, (ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>147F,>64C Vapor Density:HVR/AIR Spec Gravity:0.9888 VOC Grams/Liter:5.12 Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE Solubility in Water:PARTIAL Appearance and Odor:YELLOW LIQUID, SLIGHT SOLVENT ODOR Percent Volatiles by Volume:84.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS AMD OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND NO*X. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH STATE AND FEDERAL LAWS. DO NOT DISCHARGE INTO WATERWAYS WITHOUT PROPER AUTHORITY. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS . ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:855 7852 FIXER AND REPLENISHER,TANK,PART A,MX 1633 Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 Fraction by Wt: 45 - 50% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 35 - 40% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT Ingred Name:AMMONIUM BISULFITE (CERCLA) CAS:10192-30-0 RTECS #:WT3595000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM ACETATE (CERCLA) CAS:631-61-8 RTECS #:AF3675000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA) CAS:7631-90-5 RTECS #:VZ2000000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES. ACUTE- EYES:NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN:LOW HAZARD FOR RECOMMENDED HANDLING. INHALATION:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. ORA L:EXPECTED TO BE A LOW INGESTION HAZARD. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:TRANSIENT EYE IRRITATION Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING EYE DISORDERS MAY BE MORE SUCCEPTIBLE TO THE EFFECTS FROM EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT INDUCE VOMITING. IF CONSCIOUS, D RINK 1-2 GLASSES OF WATER. SEEK MEDICALATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION PRODUCTS MAY BE FORMED. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. OTHERWISE, ABSORB SPILL WITH INERT MATERIAL SUCH AS VERMICULITE, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CO NTAMINATION. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER CLOSED. Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID EYE CONTACT. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING, DRINKING/SMOKING. Supplemental Safety and Health KEY1:N1. ECOLOGICAL INFORMATION: THIS MATERIAL IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A MODERATE BIOCHEMICAL OXYGEN DEMAND, A MODERATE POTENTIAL TO AFFECT SOME AQUATIC ORGANISMS. AFTER DILUTION WITH LARGE AMOUNT OF WATER, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 @ 68F Vapor Density:0.6 Spec Gravity:1.32 pH:5.2 Solubility in Water:COMPLETE Appearance and Odor:YELLOW LIQUID - VINEGAR ODOR Percent Volatiles by Volume:35- 40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, BASES, SODIUM HYPOCHLORITE (BLEACH) Stability Condition to Avoid:NONE Hazardous Decomposition Products:AMMONIA, SULFUR DIOXIDE, CHLORAMINE, NITROGEN OXIDES, CHLORAMINE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL REGULATIONS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER, IF PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALL CLIMATE VACUUM PUMP OIL CAGE:07295 CAGE:54379 CAGE:07295 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV, 5 MG/M3 AS OIL MIST. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES- MAY MILDLY IRRITATING. PRACTICALLY NON-IRRITATING. INHALATION- LOW RISK OF INHALATION. IN ENCLOSED SPACES OR WHEN HOT, VAPORS MAY REACH CONCENTRATIONS SUFFICIENT TO CAUSE CNS EFFECTS. INGESTION- LOW TOXICITY. VERY LARGE AMOUNTS INGESTED MAY CAUSE CNS EFFECTS. SKIN- LOW IRRITANT. Effects of Overexposure:SKIN- PROLONGED AND/OR FREQUENT CONTACT MAY CAUSE DRYING, CRACKING (DERMATITIS) OR FOLLICULITIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES- FLUSH WITH LARGE VOLUMES OF WATER. SEE PHYSICIAN IF ANY COMPLICATIONS ARISE. INHALATION- REMOVE TO FRESH AIR. RESPIRATORY SUPPORT IF NECESSARY. SEEK MEDICAL AID. INGESTION- DO NOT INDUCE VOMITIN G. SEEK MEDICAL AID. SKIN- WASH WITH SOAP AND WATER. DO NOT WEAR HEAVILY CONTAMINATED CLOTHING BEFORE LAUNDERING. INJECTION: SUBCUTANEOUS INJECTION IS A MEDICAL EMERGENCY. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:435F,224C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER FOG. Fire Fighting Procedures:NO DATA AVAILABLE. Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF HEAT OR IGNITION, PROVIDE ADEQUATE VENTILATION, CONTAIN LEAK. ABSORB SMALL SPILLS WITH SUITABLE MATERIAL SUCH AS RAGS, STRAW OR SAND. REPORT SPILLS AS REQUIRED TO APPROPRIATE AUTHORI TIES. AVOID PROLONGED CONTACT WITH USEDOIL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 120F. DO NOT APPLY HIGH HEAT OR FLAME TO CONTAINER. KEEP SEPARATE FROM STRONG OXIDIZING AGENTS. Other Precautions:EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUE WHICH COULD INCLUDE FLAMMABLE OR EXPLOSIVE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMALLY NONE REQUIRED. IF HIGH VAPOR OR MIST CONCENTRATIONS EXPECTED USE RESPIRATOR, NIOSH/MSHA-APPROVED IS REQUIRED. Ventilation:LOCAL EXHAUST TO KEEP MISTS BELOW TLV. VERY HIGH MIST CONCENTRATIONS CAN RESULT IN A FIRE AND EXPLOSION HAZARD. Other Protective Equipment:WEAR BODY-COVERING WORK CLOTHES TO AVOID PROLONGED OR REPEATED EXPOSURE. Work Hygienic Practices:LAUNDER SOILED WORK CLOTHES BEFORE REUSE. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:703F,373C Vapor Pres:<4X10-5 Vapor Density:>1 Spec Gravity:0.87 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:FAINT YELLOW OR AMBER LIQUID, BLAND ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS. Stability Condition to Avoid:NO DATA AVAILABLE. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF THE MATERIAL IS A HAZARDOUS WASTE AT THE TIME OF DISPOSAL. CHECK BEFORE DISPOSING TO BE SURE YOU ARE IN COMPLIANCE WITH ALL APPLICABLE LAWS AND REG ULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TURCO 4217 CAGE:61102 CAGE:95510 CAGE:61102 ============= Composition/Information on Ingredients ============= Ingred Name:OCTYLPHENOXYPOLY(ETHYLENEOXY)ETHANOL CAS:9002-93-1 RTECS #:MD0907700 Fraction by Wt: 50% Other REC Limits:NONE RECOMMENDED Ingred Name:ISOPROPANOL CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 50% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT GIVEN FOR PRODUCT Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-MAY CAUSE MODERATE TO SEVERE EYE OR SKIN IRRITATION.DRIES SKIN(DEFATS).TOXIC AMOUNTS MAY BE ABSORBED THROUGH THE SKIN.INHALATION-MODERATE IRRITATION,HEADACHE,DIZINESS.MISTS-SEVERE RESPIRATORY IR RITATION,NAUSEA.INGESTION-MODERATE TO SEVERE IRRITATION, NAUSEA. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CONFIRMED OR SUSPECTED CARCINOGENS. Effects of Overexposure:ACUTE-MAY CAUSE MODERATE TO SEVERE EYE OR SKIN IRRITATION.DRIES SKIN(DEFATS).TOXIC AMOUNTS MAY BE ABSORBED THROUGH THE SKIN.INHALATION-MODERATE IRRITATION,HEADACHE,DIZINESS.MISTS-SEVERE RESPIRATORY IR RITATION,NAUSEA.INGESTION-MODERATE TO SEVERE IRRITATION, NAUSEA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL ADVICE. INHALATIO N: REMOVE TO FRESH AIR. FOR DIFFICULT BREATHING,ADMINISTER OXYGEN/OR CPR.GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING.IF VOMITING,KEEP HEAD BELOW HIPS.GIVE MILK OR WATER.GET MEDICAL HELP. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:57.0F,13.9C Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:USE SELF-CONTAINED RESPIRATORY EQUIPMENT. Unusual Fire/Explosion Hazard:VAPORS FROM THIS PRODUCT ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND TO BE IGNITED AT A POINT REMOTE FROM THE MATERIAL HANDLING AREA. ================== Accidental Release Measures ================== Spill Release Procedures:CONCENTRATE AND CONFINE SPILL.STOP LEAKS(IF SAFE).VENTILATE AREA.REMOVE NON-ESSENTIAL PERSONNEL.PUMP LIQUID INTO DOT APPROVED DRUMS(ABSORB REMAINING LIQUID AND PUT IN SAME DRUM).WASH AREA WITH WATER.D ISPOSE OF WASH WATER IF REGULATIONS PERMIT. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP CONTAINERS CLOSED WHEN MATERIAL IS NOT IN USE. KEEP AWAY FROM IGNITION SOURCES. AVOID PROLONGED OR REPEATED CONTACT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR WITH FULL FACEPIECE AND ORGANIC VAPOR CARTRIDGES IN A POSITIVE PRESSURE MODE.WHERE THERE ARE LOW CONCENTRATIONS(AND SUFFICIENT OXYGEN)USE AN ORGANIC VA POR CARTRIDGE MASK.SEE 29CFR1910-134. Ventilation:LOCAL AND MECHANICAL(GENERAL) EXHAUST TO PROVIDE ADEQUATE VENTILATION.USE EXPLOSION PROOF EQUIPMENT. Other Protective Equipment:WEAR INDUSTRIAL WORK CLOTHING. USE RUBBER APRON OR BOOTS IF NEEDED. HAVE EMERGENCY EYE WASH AND SAFETY SHOWER AVAILABLE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health THIS MSDS REFLECTS A CHANGE IN FORMULATION. AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MIST. DO NOT INGEST. READ PRECAUTIONS ON LABEL BEFORE USE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:180F,82C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:20 MMHG Vapor Density:>1 (AIR=1) Spec Gravity:0.90 pH:7-CONC Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR,LIGHT-YELLOW LIQUID,ALCOHOL ODOR. Percent Volatiles by Volume:50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS,ACIDS AND ALKALIES. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE AND OTHER TOXIC VOLATILE ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONCENTRATE:1-TRANSFER TO A RECLAMATION CENTER.2- TRANSFER TO A LICENSED HAZARDOUS WASTE TREATMENT OR DISPOSAL SITE(PER APPLICABLE REGULATIONS).SPENT SOLUTIONS AND RINSES:VARIES WITH CONDITIONS. CONTA CT YOUR LOCAL TERRITORY MANAGER FOR RECOMMENDATION
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1003M OCR BLACK Preparer's Name:WALTER PETZOLD CAGE:FO301 CAGE:FO301 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: NAUSEA & DIARRHEA. EYES: IRRITATION. SKIN: DERMATITIS IN SENSITIVE INDIVIDUALS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: NAUSEA & DIARRHEA. EYES: IRRITATION. SKIN: DERMATITIS IN SENSITIVE INDIVIDUALS ======================= First Aid Measures ======================= First Aid:SKIN: WASH WITH SOAP & WATER. INGESTION: IF SWALLOWED: DON'T INDUCE VOMITING, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:365F Extinguishing Media:CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SPREAD ABSORBENT AND SWEEP UP. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXCESSIVE HEAT & OPEN FLAME. Other Precautions:AVOID SWALLOWING AND CONTACT WITH EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE WITH NORMAL USE. Ventilation:MECHANICAL Other Protective Equipment:WEAR IMPERVIOUS CLOTHING IF INTIMATE CONTACT IS EXPECTED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:460F Vapor Pres:.1 Solubility in Water:1% Appearance and Odor:BLACK LIQUID; FAINT OILY ODOR. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, BASES, OR OXIDIZING AGENTS Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:SECURE LANDFILL OR INCINERATORS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON DIOXIDE Preparer's Name:D. EMERICH OR D. ELLISON CAGE:54905 CAGE:54905 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 100% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO INFORMATION GIVEN ON MSDS BY MFR. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHRONIC EXPOSURE TO HIGH CONCENTRATIONS CAN PARALYZE RESPIRATORY CENTER. INCREASED INHALATION WILL CAUSE INCREASED BREATHING RATE. UNCONSCIOUSNESS AND DEATH MAY RESULT. Explanation of Carcinogenicity:MFR GAVE NO EXPLINATION OTHER THAN THE "NO" FOR EACH LISTING. Effects of Overexposure:LIQUID/SOLID CONTACT,ANY BODY TISSUE: FROSTBITE,BURNING. INHALATION:INCREASED RESPIRATORY RATE,RESPIRATORY PARALYSIS,ASPHIXIATION. Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:CONTACT:TREAT AS FROSTBITE,WARM AFFECTED AREA,GET MEDICAL ATTENTION. INHALED:REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT OR STOPS,ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION AND GET IMMEDIATE MEDIC AL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:NONE. THIS MATERIAL IS AN EXTINGUISHING AGENT. Fire Fighting Procedures:NONE. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:LEAKS WILL DISSIPATE RAPIDLY AND HARMLESSLY TO ATMOSPHERE. FOR CONFINED AREAS REMOVE ALL PERSONNEL AND VENTILAATE AREA. VENT TO ATMOSPHERE. Neutralizing Agent:NONE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM DIRECT HEAT OR OPEN FLAME. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE EXPECTED TO BE NEEDED. USE SELF CONTAINED BREATHING APPARATUS OR AIR-LINE RESPIRATOR,IF CONCENTRATION LOWERS OXYGEN CONTENT OF THE AIR BELOW 19%. Ventilation:GENERAL AREA AND LOCAL EXHAUST VENTILATION RECOMMENDED. Other Protective Equipment:NONE REQUIRED Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PRACTICE AND GOOD HOUSEKEEPING PRACTICES. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:G3 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:-109F,-78C Vapor Pres:GAS Vapor Density:1.52 Evaporation Rate & Reference:HIGH Solubility in Water:0.8 V/V Appearance and Odor:COLORLESS LIQUID OR GAS.NO ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CHEMICALLY ACTIVE METALS SUCH AS SODIUM,POTASSIUM,HOT TITANIUM. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:MRR DID NOT ADDRESS THIS FIELD. DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMMONIUM SULFOCYANATE (THIOCYANIC ACID, (SU CAGE:DO242 CAGE:0SK29 CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:THIOCYANIC ACID, AMMONIUM SALT;(AMMONIUM THIOCYANATE) (SARA III) CAS:1762-95-4 RTECS #:XK7875000 OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TOXIC BY INGESTION. INHALATION OF VAPORS RESULTING FROM DECOMPOSITION OR CONTACT WITH ACID CAN BE FATAL. MAY CAUSE SKIN AND EYE IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:DATA NOT AVAILABLE. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH SOAP & WATER THOROUGHLY. EYE:IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHAL:MOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGEST:IF CO NSCIOUS, INDUCE VOMITING. GIVE CYANIDE ANTIDOTE IF UNCONSCIOUS: INHALATION OF AMYL NITRATE VAPOR FOR FIVE SECONDS AT 15 SECOND INTERVALS. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING MATERIAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MAY EXPLODE IF MIXED WITH PB (NO3) 2. ================== Accidental Release Measures ================== Spill Release Procedures:TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE AWAY FROM ACIDS. DO NOT BREATHE DUST OR VAPOR. DO NOT GET IN EYES, ON SKIN OR CLOTHING. Other Precautions:DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:EYE WASH AND SAFETY EQUIPMENT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MFR PT#/TRADE NAME:AMMONIUM SALT), AX1415. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:338F,170C Melt/Freeze Pt:M.P/F.P Text:301F,150C Spec Gravity:1.305 (H*2O=1) Solubility in Water:FREELY Appearance and Odor:COLORLESS DELIQUESCENT CRYSTALS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS. Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:HYDROGEN CYANIDE, AMMONIA, NO*X, SO*X. ==================== Disposal Considerations ==================== Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: NIKLAD 776A, 45250 Cage: 99442 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 99442 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50:(ORAL, RAT) 350 MG/KG (AMMONIA GAS) Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE TOXICOLOGICAL PROPERTIES: IRRITATES EYES, NOSE, THROAT; DYSPNEA; BRONCHOSPASM; CHEST PAIN; PULMONARY EDEMA; PINK FROTHY SPUTUM; SKIN BURNS; VESICULATION. CHRONIC: NICKEL COMPOUNDS: DERMATITIS (N ICKEL ITCH); PNEUMONITIS, ALLERGIC ASTHMA. AMMONIA: EYE, NOSE AND THROAT IRRITATION, AND CHEST PAIN. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYE: IMMEDIATELY FLUSH WITH LARGE QUANTITIES OF WATER FOR AT LEAST 15 MINUTES AND CALL MD. SKIN: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. INHAL: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT , GIVE OXYGEN AND CALL MD. INGEST: CONTACT MD IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR PROTECTIVE CLOTHING AND EQUIPMENT DURING CLEANUP. ABSORB SPILLS ON AN INERT MATERIAL SUCH AS EARTH, SAND OR VERMICULITE; SWEEP UP AND DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF I/A/W ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. Handling And Storage Precautions: WEAR PROTECTIVE CLOTHING AND EQUIPMENT WHILE HANDLING. STORE AWAY FROM DIRECT HEAT OR SUNLIGHT. KEEP CONTAINERS TIGTHLY CLOSED WHEN NOT IN USE. Other Precautions: DO NOT SWALLOW. AVOID EYE AND SKIN CONTACT. AVOID CONTACT WITH CLOTHING. KEEP FROM FEED OR FOOD PRODUCTS. KEEP OUT OF REACH OF CHILDREN! ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: CLOSED CONTAINERS EXPOSED TO FIRE MAY BE COOLED WITH WATER. Fire Fighting Procedures: NONE. Unusual Fire/Explosion Hazard: NONE ======================================================= Control Measures ======================================================= Respiratory Protection: IF THE TLV/PEL OF THE PRODUCT OR ANY COMPONENT IS EXCEEDED, USA A NIOSH/MSHA APPROVED SCBA. Ventilation: LOCAL IF NECESSARY TO MAINTAIN ALLOWABLE PEL (PERMISSIBLE EXPOSURE LIMIT) OR TLV (THRESHOLD LIMIT VALUE). Other Protective Equipment: RUBBER APRON, RUBBER BOOTS. EMERGENCY EYE WASH AND DELUGE SHOWER (FP N). Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. WASH CLOTHING BEFORE REUSE. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= HCC: B3 B.P. Text: >212F,>100C Spec Gravity: 1.4 PH: 11.7 Solubility in Water: 100% Appearance and Odor: CLEAR, BLUE LIQUID; AMMONIA ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: DIRECT HEAT AND SUNLIGHT. Materials To Avoid: NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products: NONE Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 26802 Product ID: NIKLAD 776A, 45250 Review Date: 01/31/1992 Multiple KIT Number: 0 Review IND: Y Additional Data: NOT REGULATED FOR TRANSPORTATION ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: NIKLAD 776A, 45250 Cage: 99442 Company Name: WITCO ALLIED-KELITE DIV OF WITCO CHEMICAL CORP Street: 400 MIDLAND AVE Zipcode: 48203-3734 Label Required IND: Y Date Of Label Review: 11/26/1991 Status Code: C Label Date: 11/26/1991 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: IRRITATES EYES, NOSE AND THROAT. CAN CAUSE DYSPNEA, BRONCHOSPASM, CHEST PAIN, PULMONARY EDEMA, PINK FROTHY SPUTUM, SKIN BURNS AND VESICULATION. DO NOT SWALLOW. AVOID EYE AND SKIN CONTACT. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. AVOID CONTACT WITH CLOTHES. CHRONIC: DERMATITIS, NICKEL ITCH, PNEUMONITIS, ALLERGIC ASTHMA, NOSE AND THROAT IRRITATION AND CHEST PAIN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IMPCO HI-TEMP CATALYST Preparer's Name:MICHAEL BALLOU CAGE:24221 CAGE:24221 ============= Composition/Information on Ingredients ============= Ingred Name:DICUMYL PEROXIDE CAS:80-43-3 RTECS #:SD8150000 Fraction by Wt: 98% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. INHALATION: RESPIRATORY IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/EYES: IRRITATION. INHALATION: RESPIRATORY IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION OR OXYGEN IF BREATHING IS DIFFICULT. TREAT SYMPTOMATICALLY. EYES: FLUSH W/PLENTY OF SOAP & WATER. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MINS. INGESTION: IF CONSCIOUS, DRINK LARGE QUANTITIES OF LIQUID TO DILUTE. NEVER GIVE LIQUIDSOR INDUCE VOMITING IF UNCONSCIOUS. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:260F Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM, OR CO2 Fire Fighting Procedures:COOL CONTAINERS W/WATER IF EXPOSED TO FIRE. DIRECT HOSE STREAMS FROM A PROTECTED LOCATION. WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:MATERIAL IN CONTAINERS MAY DECOMPOSE VIOLENTLY WHEN EXPOSED TO HEAT. BURNS W/FLARE EFFECT. ================== Accidental Release Measures ================== Spill Release Procedures:IF SOLID, SALVAGE IN CLEAN, STEEL DRUMS. ABSORB ANY LIQUID IN CLEAN SAND & PLACE IN CLEAN, STEEL DRUMS FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:MAY DECOMPOSE VIOLENTLY WHEN OVERHEATED.KEEP AWAY FROM HEAT SOURCES. STORE <95F, OUT OF DIRECT SUNLIGHT. MELT ONLY IN WATER BATH AT 140F MAXIMUM TEMP. Other Precautions:AVOID CONTAMINATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR SELF-CONTAINED BREATHING APPARATUS IN EXCESSIVE FUMES FROM PRODUCT DECOMPOSITION. Work Hygienic Practices:REMOVE/WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:100F Vapor Pres:15.4 Spec Gravity:1.014 Evaporation Rate & Reference:SLOWER THAN BU AC Solubility in Water:NEGLIGIBLE Appearance and Odor:PALE YELLOW-WHITE GRANULAR SOLID: ACRID; FRUITY ODOR. Percent Volatiles by Volume:NEGL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS/ACIDIC MATERIALS SUCH AS FRIEDEL-CRAFTS OR OXIDATION/CATALYSTS/STRONG & REDUCING AGENTS/COPPER ALLOYS/LEAD/IRON Stability Condition to Avoid:HEAT, DIRECT SUNLIGHT, TEMPS >131F, & CONTAMINATION Hazardous Decomposition Products:PHENOLS, CO, CO2, SMOKE, ACETOPHENONE, CUML ALCOHOL, A-METHYL STYRENE, METHANE, & ETHANE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE A 5% CONCENTRATION IN #2 FUEL OIL IN AN RCRA APPROVED INCINERATOR.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IMPACT (SEE SUPPL) Resp. Party Other MSDS Num.:58396 CAGE:58396 Contract Num:SP0450-99-M-C508 CAGE:58396 Contract Num:SP0450-99-M-ND31 CAGE:58396 Contract Num:SP0450-99-MC724 CAGE:58396 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: TO 100% Other REC Limits:NONE RECOMMENDED Ingred Name:CITRUS TERPENES CAS:5989-27-5 RTECS #:GW6360000 Minumum % Wt:75. Maxumum % Wt:85. Other REC Limits:NONE RECOMMENDED Ingred Name:COCONUT DIETHANOLAMIDO CAS:8051-30-7 Minumum % Wt:5. Maxumum % Wt:10. Other REC Limits:NONE RECOMMENDED Ingred Name:NONIONIC SURFACTANT CAS:9016-45-9 RTECS #:MD0900000 Minumum % Wt:5. Maxumum % Wt:10. Other REC Limits:NONE RECOMMENDED Ingred Name:DYE Minumum % Wt:0. Maxumum % Wt:5. Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY MANUFACTURER Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Explanation of Carcinogenicity:NO DATA PROVIDED BY MANUFACTURER Effects of Overexposure:REDNESS, BURNING, OR TEARING OF EYES, SKIN DEFATTING, DRYNESS, IRRITATION, NOSE, THROAT, AND LUNGS IRRITATION, MOUTH, THROAT, AND GASTROINTESTINAL SYSTEM IRRITATION Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER ======================= First Aid Measures ======================= First Aid:INHALATION: GET TO FRESH AIR. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. EYES: FLUSH WITH LARGE AMOUNT OF WATER, HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: FLUSH WIT H WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INGESTION: DO NOT INDUCE VOMITING. DRINK LARGE AMOUNT OF WATER. SEEK MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=54.4C, 130.F Lower Limits:1.0 Upper Limits:6.0 Extinguishing Media:FOAM, CO2 OR DRY CHEMICAL. Fire Fighting Procedures:DO NOT USE WATER. Unusual Fire/Explosion Hazard:DRUMS HEATED BY FIRE CAN EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP OR OTHERWISE ABSORB AND HOLD FOR DISPOSAL. Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED DURING STORAGE. Other Precautions:AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. KEEP OUT OF REACH OF CHILDREN. FOR INSTITUTIONAL AND INDUSTRIAL USE ONLY. FOR USE BY TRAINED PERSONNEL ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IUSE IN WELL VENTILATED AREA. Ventilation:PROVIDE LOCAL EXHAUST TO KEEP TLV OF INGREDIENTS BELOW ACCEPTABLE LIMIT. Work Hygienic Practices:GOOD PRACTICE REQUIRES THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL. Supplemental Safety and Health NONE **CONTD FROM PRODUCT ID: PRODUCT CODES: 9A 531, 9G 531, 9N 531, 9I 531. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:=168.3C, 335.F B.P. Text:INITIAL Vapor Pres:<10MM HG @ 68F Vapor Density:>1 Spec Gravity:0.864 pH:11.5 - 12.0 Viscosity:NOT KNOWN Evaporation Rate & Reference:<1 (WATER=1) Solubility in Water:EMULSIFIES Appearance and Odor:THIN ORANGE LIQUID - PLEASANT ODOR Percent Volatiles by Volume:90+ ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:EXCESSIVE HEAT, OPEN FLAMES, SPARKS Hazardous Decomposition Products:CARBON MONOXIDE POSSIBLE IF BURNED. =================== Toxicological Information=================== Toxicological Information:NO DATA PROVIDED BY MANUFACTURER ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY MANUFACTURER ==================== Disposal Considerations ==================== Waste Disposal Methods:ANY METHOD IN ACCORDANCE WITH APPLICABLE LAWS. =================== MSDS Transport Information =================== Transport Information:NO DATA PROVIDED BY MANUFACTURER ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OFSECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372: NONE. Federal Regulatory Information:NO DATA PROVIDED BY MANUFACTURER State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RHODORSIL FLUIDS 47 V 50 THROUGH V 2,500,000 CAGE:0A5D1 CAGE:050Q3 CAGE:0A5D1 CAGE:RH0NE ============= Composition/Information on Ingredients ============= Ingred Name:POLYDIMETHYLSILOXANE CAS:63148-62-9 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5000 MG/KG Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NON-IRRITATING TO SKIN & EYES. INHALATION HAZARDS ARE MINIMAL. LOW ACUTE ORAL TOXICITY. NOTE: UNDER CERTAIN CONDITIONS, PRODUCT MAY GENERATE FORMALDEHYDE AS A BY-PRODUCT OF OXIDATIVE THERMAL DECOMPOSI TION. FORMALDEHYDE IS LISTED AS A POTENTIAL HUMAN CARCINOGEN BY IARC, NTP AND OSHA. Explanation of Carcinogenicity:MAY FORM FORMALDEHYDE ON OXIDATIVE THERMAL DECOMPOSITION-FORMALDEHYDE IS LISTED AS A CARCINOGEN BY IARC, NTP, OSHA. Effects of Overexposure:NO ADDITIONAL DATA FOUND. Medical Cond Aggravated by Exposure:NO DATA FOUND. ======================= First Aid Measures ======================= First Aid:EYES-WIPE OFF EXCESS W/GAUZE PAD; FLUSH WITH WATER FOR 15 MINUTES, LIFT LIDS. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. SKIN-WIPE OF EXCESS W/CLEAN CLOTH. WASH W/SOAP & WATER. GET MEDICAL ATTENTIO N IF IRRITATION DEVELOPS. INHALED-SEEK MEDICAL ATTENTION. INGESTED-IF CONSCIOUS, INDCUE VOMITING BY STICKING FINGER DOWN THROAT. GET IMMEDIATE MEDICAL ATTENTION. NOTE: TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:570F,299C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL FIRE FIGHTER'S PROTECTIVE GEAR. USE WATER TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE GEAR. ABSORB ON VERMICULITE. SWEEP INTO APPROPRIATE CONTAINER. WASH SPILL AREA AFTER MATERIAL PICKUP IS COMPLETE WITH AN APPROPRIATE SOLVENT SUCH AS PAINT THINNER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMPERATURE IN TIGHTLY CLOSED CONTAINERS. AVOID DIRECT OR PROLONGED CONTACT WITH SKIN & EYES. WASH HANDS AFTER HANDLING. Other Precautions:DO NOT RUB EYES WITH SOILED HANDS. DO NOT EAT, DRINK OR SMOKE IN THE WORK AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:PROVIDE ADEQUATE VENTILATION. USE LOCAL EXHAUST AS NEEDED. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health REGULATORY DATA: TSCA-PRODUCT IS TSCA CERTIFIED; TRANSPORTATION-NOT REGULATED; RQ (CERCLA)-NOT LISTED; SARA TITLE III-NOT LISTED. ================== Physical/Chemical Properties ================== HCC:V6 Melt/Freeze Pt:M.P/F.P Text:-65F,-54C Vapor Pres:0.01 @392F Spec Gravity:0.96 Viscosity:50-2500000 CS Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR, VISCOUS LIQUID; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG BASES, STRONG OXIDIZING MATERIALS. Stability Condition to Avoid:AVOID HEAT & OPEN FLAME. Hazardous Decomposition Products:ON COMBUSTION-SILICA AND OXIDES OF CARBON. FORMALDEHYDE IS A BY-PRODUCT OF OXIDATIVE THERMAL DECOMPOSITION. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:816 5417, KODAK INK JET GEN 1.5-MEDIUM WEIGHT & HEAVY WEIGHT CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:POLYETHYLENE RTECS #:PM9002884 Fraction by Wt: 15-25% Other REC Limits:NONE RECOMMENDED Ingred Name:OTHER NOT HAZARDOUS INGREDIENTS Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:POLYMERS Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:CELLULOSE Fraction by Wt: 70-80% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:GENERAL: THIS PRODUCT WILL NOT CAUSE ANY SPECIAL HEALTH OR SAFETY HAZAR, WHEN USED AS INTENDED. PHOTOGRADE INK JET PAPER(S) ARE NOT HAZARDOUS TO HEALTH. Explanation of Carcinogenicity:NOT CARCINOGENIC. Effects of Overexposure:NONE. Medical Cond Aggravated by Exposure:NONE. ======================= First Aid Measures ======================= First Aid:NONE SPECIFIED BY MANUFACTURER. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:IN THE EVENT OF A FIRE, FIRE-FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:CONSIDERABLE HEATING ABOVE AMBIENT CONDITIONS IS REQUIRED BEFORE IGNITION AND COMBUSTION OCCUR. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. EXPOSURE TO MOISTURE, HIGH TEMPERATURE, AND HUMIDITY SHOULD BE AVOIDED BECAUSE THIS COULD AFFECT DRYING AND IMAGE QUALITY. Other Precautions:LABELLING: NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED. Ventilation:NONE NEEDED. Other Protective Equipment:NONE NEEDED. Work Hygienic Practices:WASH HANDS AFTER USE. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:PHOTOGRADE INK JET PAPER(S). ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:THE PRODUCTS OF COMBUSTION DEPEND ON THE BURNING CONDITIONS & ARE LIKELY TO INCLUDE CARBON MONOXIDE, OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL OR DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:ENAMEL ALKYD LUSTERLESS LO VOC CT GRAY 36118, 771606 Preparer's Name:W A ELLISON CAGE:61196 CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:N-BUTYL ACETATE (SOLVENT) (VAPOR PRESSURE 10 MM HG @ 20C) (LFL 1.7; UFL 7.6) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM;STEL 200 PPM ACGIH TLV:150 PPM;STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SOLVENT NAPHTHA, LIGHT AROMATIC (SOLVENT) CAS:64742-95-6 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:XYLENE (SOLVENT) (SARA III) (VAPOR PRESSURE 5 MM HG @ 20C) (LFL 1.0; UFL 7.0) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM;STEL 150 PPM ACGIH TLV:100 PPM;STEL 150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL ISOAMYL KETONE (SOLVENT) CAS:110-12-3 RTECS #:MP3850000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM; 240 MG/M3 ACGIH TLV:50 PPM; 240 MG/M3 Ingred Name:STODDARD SOLVENT (SOLVENT) (LFL 0.8) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM; 525 MG/M3 ACGIH TLV:100 PPM; 525 MG/M3 Ingred Name:TITANIUM DIOXIDE (PIGMENT) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:TALC (PIGMENT) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 30% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3; 20 MPPCF ACGIH TLV:2 MG/M3; 15 MPPCF Ingred Name:SILICA, CRYSTALLINE (PIGMENT) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1000 MG/M3 ACGIH TLV:0.1000 MG/M3 Ingred Name:SILICA, CRYSTALLINE - TRIPOLI CAS:1317-95-9 RTECS #:VV7336000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1000 MG/M3 ACGIH TLV:0.1000 MG/M3 Ingred Name:TOLUENE (SOLVENT) (SARA III) (VAPOR PRESSURE 22 MM HG @ 20C) (SKIN) (LFL 1.7; UFL 7.1) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM;STEL 150 PPM ACGIH TLV:50 PPM; 147 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL ETHYL KETONE (SOLVENT) (SARA III) (VAPOR PRESSURE 70 MM HG @ 20C) (LFL 2.0; UFL 10.0) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM;STEL 300 PPM ACGIH TLV:200 PPM;STEL 300 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VOC: 3.06 LB/GAL LESS WATER & NEGLIGIBLY PHOTOCHEMICALLY REACTIVE MATERIALS; 367 G/L LESS WATER; CALCULATED RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES Health Hazards Acute and Chronic:ACUTE; INGEST: GASTROINTESTINAL IRRIT, NAUSEA, VOMITING. ASPIRATION INTO LUNG MAY CAUSE CHEM PNEUMONITIS (CAN BE FATAL). INHAL: NOSE OR THROAT IRRIT. ACUTE CENTRAL NERVOUS SYSTEM DEPRESSION (HEADACHES , DIZZINESS, NAUSEA, CONFUSION). EYE: SEVERE IRRIT. SKIN: ABSORBED THROUGH SKIN IN HARMFUL AMTS. DEFATTING & SKIN IRRIT. Explanation of Carcinogenicity:IARC CONSIDERS CRYSTALLINE SILICA TO HAVE LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS & SUFFICIENT IN ANIMALS. Effects of Overexposure:CHRONIC; SILICOSIS (DISABLING LUNG DISEASE). LIVER, KIDNEY AND BLOOD INJURY. ENHANCES NEUROTOXICITY (SYNERGISTIC EFFECT RESULTED IN PERIPHERAL NEUROPATHY). PROLONGED & REPEATED OVEREXPOSURE: PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. CONCENTRATING & INHALING PRODUCT MAY BE HARMFUL OR FATAL. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA. ======================= First Aid Measures ======================= First Aid:INGEST: DONT INDUCE VOMITING. CALL POISON CTR/EMERG ROOM/DR IMMED. INHAL:REMOVE TO FRESH AIR IMMED. IF BREATHING STOPPED, GIVE ARTIF RESPRTN. KEEP WARM & QUIET. GET MED AID IMMED. EYE: FLUSH W/WATER 1 5 MIN, LIFTING EYELIDS. GET MED AID. SKIN: REMOVE CONTAM CLOTHES. WASH AFFECTED AREA W/SOAP & WATER. GET MED AID IF IRRIT PERSISTS. NOTE TO DR:DIRECT TREATMENT AT CLINICAL CONDITION & SYMPTOM CONTROL. ===================== Fire Fighting Measures ===================== Flash Point:24.0F,-4.4C Autoignition Temp:Autoignition Temp Text:572 F Lower Limits:0.8 Upper Limits:10.0 Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CO2, DRY CHEMICAL, ALCOHOL FOAM) FOR FLAMMABLE LIQ. POLYMER FOAM PREFERRED FOR LARGE FIRES. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, USE TO COOL EXPOSED CONTAINERS (FOG NOZZLES PREFERRED) TO PREVENT PRESSURE BUILDUP, AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO HEAT. Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY BE HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. GET MEDICAL AID. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR RSPRTR,EYE,HAND,BODY PROTECTN. KEEP SPECTATORS AWAY. ELIMINATE IGNIT SOURCES. DIKE & CONTAIN W/INERT MAT'L (SAND/EARTH/ETC). TRANSFER LIQ/USED ABSORBENT TO COVERED METAL CONTAINER. USE NON-SPARKI NG TOOL. PREVENT SEWER, GROUNDWATER CONTAMINATION. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 115 F. STORE LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29 CFR 1910.106. DO NOT TAKE INTERNALLY. DO NOT BREATHE SANDING DUST. Other Precautions:CLOSE CONTAINER AFTER EACH USE. DO NOT WASH & REUSE EMPTY CONTAINER FOR ANY PURPOSE. GROUND & BOND CONTAINERS TO RECEIVING CONTAINER. DO NOT WELD, BRAZE, OR CUT ON EMPTY CONTAINER. NEVER USE PRESSURETO EMPTY. DRUM IS NOT A PRESSURE VESSEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTD,MAY NOT REQ RSPRTR.IN RESTRICTD VENT,NIOSH CHEM CARTRIDGE RSPRTR MAY BE REQ'D.SPRAYNG,MECHAN PREFILTER MAY ALSO BE REQ'D.CONFIND AREAS,USE AIR SUPPLD RSPRTR.SEE OSHA 29CFR1910.134"RESP PROTEC T"&"RESP PROTECT-MANUAL & GUIDELINE"AIHA Ventilation:LOCAL EXHAUST VENT TO KEEP BELOW TLV. REMOVE DECOMPOSITION PRODUCT. SEE "INDUST VENT-MANUAL RECOMMENDED PRACTICES" ACGIH Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:175 TO 390F Melt/Freeze Pt:M.P/F.P Text:-50F,-46C Decomp Temp:Decomp Text:1832F,1000C Vapor Pres:70 @ 68F Vapor Density:> AIR Spec Gravity:1.4 pH:4-7 Viscosity:67 - 77 KU Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER Solubility in Water:SLIGHT IN WATER Appearance and Odor:LIQUID, SOLVENT ODOR Percent Volatiles by Volume:43 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS. Stability Condition to Avoid:AVOID EXCESSIVE HEAT (>115F) AND SOURCES OF IGNITION. Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE & CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE, & LOCAL LAWS OR REGULATIONS. THIS PRODUCT, IF DISCARDED DIRECTLY, WOULD BE CLASSIFIED A HAZARDOUS WASTE BASED ON ITS IGNITABILITY CHARACTERISTIC (FLASH POINT 140F OR LESS). PROPER RCRA CLASSIFICATION: D001.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STAINLESS STEEL ELECTRODES, 308-16 CAGE:HO911 CAGE:HO911 CAGE:24559 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 ACGIH TLV:10 MG/M3 (MFR) Ingred Name:CHROMIUM (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NICKEL (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:MANGANESE (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 OSHA PEL:5 MG/M3 DUST, C ACGIH TLV:5 MG/M3 DUST Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 OSHA PEL:10 PPM ACGIH TLV:10 PPM Ingred Name:NIOBIUM; (ALSO CALLED COLUMBIUM) CAS:7440-03-1 ACGIH TLV:5 MG/M3 (MFR) Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:POTASSIUM TITANATE CAS:12030-97-6 ACGIH TLV:10 MG/M3 (MFR) Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:FLUORSPAR; (CALCIUM FLUORIDE) CAS:14542-23-5 ACGIH TLV:2.5 MG/M3 (MFR) Ingred Name:CRYOLITE; (SODIUM ALUMINUM FLUORIDE) CAS:15096-52-3 RTECS #:WA9625000 ACGIH TLV:2.5 MG/M3 (MFR) Ingred Name:FELDSPAR CAS:68476-25-5 ACGIH TLV:2 MG/M3 (MFR) Ingred Name:CHROMIUM (III) OXIDE (2:3); (CHROMIUM OXIDE) CAS:1308-38-9 RTECS #:GB6475000 ACGIH TLV:0.5 MG/M3 (CR) Ingred Name:POTASSIUM SILICATE CAS:1312-76-1 ACGIH TLV:5 MG/M3 (MFR) Ingred Name:SODIUM SILICATE CAS:1344-09-8 ACGIH TLV:5 MG/M3 (MFR) Ingred Name:POTASSIUM HYDROXIDE (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 OSHA PEL:2 MG/M3, C ACGIH TLV:2 MG/M3, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:EYE PROT:FULL LENGTH FCSHLD , W/FILTER LENS, PROT SCREENS, Ingred Name:ING 18:TOO DARK, THEN GO TO LIGHTER SHADE WHICH GIVES SUFFICIENT VIEW OF WELD ZONE. Ingred Name:SUPP DATA:CONSTITUENTS OF PROD COULD INCLUDE PRIMARILY OXIDES OF IRON; SECONDARILY OXIDES OF CHROMIUM, NICKEL, (ING 21) Ingred Name:ING 20:MANGANESE, SILICON & MOLYBDENUM. GASEOUS RXN IN PRODS MAY INCL CARBON MONOXIDE & CARBON DIOXIDE. OZONE & (ING 22) Ingred Name:ING 21:NITROGEN OXIDES MAY BE FORMED BY THE RADIATION FROM ARCS. FOR MORE SPECIFIC INFORMATION, CONTACT NEHC . ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:WELDING MAY CREATE ELECTRIC ARC; FUMES AND GASES CAN BE DANGEROUS. ARC RAYS CAN INJURE EYES AND BURN SKIN. ELECTRIC SHOCK CAN KILL. ACUTE:EXPOSURE TO WELDING FUMES:DIZZINESS, NAUSEA, DRYNESS AND IRRIT ATION OF NOSE, EYES, THROAT, CHEST TIGHTNESS, FEVER, ALLERGIC REACTION. CHRONIC:SIDEROSIS, BELIEVED TO AFFECT PULM FUNC. Explanation of Carcinogenicity:NICKEL:IARC MONOGRAPHS ON EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 257, 1990:GRP 2B. NTP 7TH ANNUAL RPT (SUPDAT) Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY AMERICAN RED CROSS. INHAL:REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION. INGEST:CALL MD IMMEDIATELY . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINI MUM OF 15 MINUTES, SEEK ASSISTANCE FROMMD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE COMBUSTIBLES & FLAMMABLES. REFER TO ANSI Z49.1 FOR FIRE PREVENTION DURING THE USE OF WELDING & ALLIED PROCEDURES. ================== Accidental Release Measures ================== Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT TOUCH LIVE ELECTRICAL PARTS & INSULATE FROM WORK & GROUND. USE EXHST SYS. MAKE SURE EXHST SYS DOES NOT CONTAIN FUME CONSTITUENTS ABOVE PELS. Other Precautions:TRAIN WORKER TO KEEP HEAD OUT OF FUMES. OTHER PRECS FOR ADDNL SFTY INFO ON WELDING & CUTTING, SEE ANSI Z49.1-1983, SFTY IN WELDING & CUTTING & WELDING HANDBOOK, VOL 1, CHAPTER 9, SAFE PRACTICES IN WEL DING & CUTTING, BOTH AVAIL FROM (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN IN CONFINED SPACE OR LOCAL EXHAUST DOES NOT KEEP EXPOSURE BELOW RECOMMENDED EXPOSURE LIMIT. Ventilation:USE ENOUGH LOCAL EXHAUST VENT & LOCAL EXHAUST AT ARC TO KEEP FUMES & GASES FROM WORKER'S BREATHING ZONE & GENERAL AREA. Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER. HAND, HEAD, BODY PROT TO PVNT INJURY FROM RADIA, SPKS & ELEC SHOCK. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLAN OF CARCIN:ON CARCINS, 1994:ANTIC TO BE CARCIN. ANIMAL:LUNGS, NASAL CAVITIES. CHROMIUM (III) OXIDE (2:3):NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE CARCIN. OTHER PREC:AWS INC, 550 N.W. LEJU DECOMP PROD:USED. REAS EXPECTED FUME (ING 20) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:COMPOSITION & QUALITY OF WELDING FUMES & GASES ARE DEPENDENT UPON METAL BEING WELDED, PROCESS, PROC & ELECTRODES(SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT RESIDUE, DISPOSABLE CONTAINER OR LINER IN ENVIRONMENTALLY ACCEPTABLE MANNER IN FULL COMPLIANCE W/FEDERAL, STATE & LOCAL RE GULATIONS. ======================================================================
1
eyes_protection_mandatory
======================================================= Product ID: SPRAYMASTER DRYFALL ALKYD SPR 170 FLAT WHITE Cage: IO491 ======================================================= Contractor Summary ======================================================= Cage: 01PD6 Cage: IO491 ======================================================= Ingredients ======================================================= Cas: 1317-65-3 RTECS #: EV9580000 % Wt: 10-20 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ------------------------------ Cas: 8052-41-3 RTECS #: WJ8925000 % Wt: 1-5 OSHA PEL: 500 PPM ACGIH TLV: 100 PPM ------------------------------ Cas: 64742-89-8 % Wt: 5-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 64742-88-7 RTECS #: WF3450000 % Wt: 5-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 13463-67-7 RTECS #: XR2275000 % Wt: 5-10 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ------------------------------ Cas: 14808-60-7 RTECS #: VV7330000 % Wt: .1-1.0 OSHA PEL: N/K (FP N) ACGIH TLV: 0.1 MG/M3 RDUST ------------------------------ Cas: 12135-86-3 % Wt: 5-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 71-43-2 RTECS #: CY1400000 % Wt: .01-.1 OSHA PEL: N/K (FP N) ACGIH TLV: 10 PPM EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ------------------------------ Cas: 17068-78-9 % Wt: 1-5 OSHA PEL: 2 FIBERS/CC ACGIH TLV: 2 FIBERS/CC ------------------------------ Cas: 14807-96-6 RTECS #: MW2710000 % Wt: 10-20 OSHA PEL: 0.2 FIBERS/CC ACGIH TLV: 0.2 FIBER/CC ------------------------------ Cas: 14567-73-8 RTECS #: CI6560000 % Wt: 10-20 OSHA PEL: 2 FIBERS/CC ACGIH TLV: 2 FIBERS/CC ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 % Wt: 20-30 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 66070-62-1 PHTHALIC ANHYDRIDE % Wt: 5-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- RTECS #: 9999999VO OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- SPILL. PUMP TO STOR/SALVAGE VESSELS. USE ----------------------------- RINSE WATER OUT OF SEWERS & WATER COURSES. SML ----------------------------- ----------------------------- RESP PROT AS DIRECTED UNDER SPECIAL PROT ----------------------------- NEHC FOR MORE SPECIFIC INFORMATION (FP N). ----------------------------- CONVULS, LOSS OF CONSCIOUSNESS, CYANOSIS. ----------------------------- BE ABSORB THRU SKIN. NOTICE-RPTS HAVE ----------------------------- NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC ----------------------------- ----------------------------- HAZ. HUMAN: BLOOD. SILICA, CRYSTALLINE- ----------------------------- REPORT ON CARC, 1994: ANTICIPATED TO BE CARC. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: ACUTE: INHAL: IRRIT OF RESP TRACT. PRLNGD INHAL MAY LEAD TO FATG, DROW, DIZZ &/OR LIGHTHEADEDNESS, HDCH, UNCOORDINATION, NAUS, VOMIT, DIARR, COUGHING, SNEEZING, CNS DEPRESS, RESP PROBLEMS, METALLIC TA STE, ANESTHETIC EFT/NARC, FEVER & CHILLS, DEHYDRATION, PULM EDEMA, PNEUM, LOSS OF CONSCIOUSNESS, (EFTS OF OVEREXP) Explanation Of Carcinogenicity: BENZENE: IARC MONO, SUPP. VOL 7, PG 120, 1987: GRP 1. NTP 7TH ANNUAL RPT ON CARCIN, 1994: KNOWN TO BE CARCIN. Signs And Symptions Of Overexposure: HLTH HAZ: ASPHYX, DEATH. SKIN: IRRIT, PRLNGD/RPTD CONT CAN CAUSE DERM, DEFAT. EYE: IRRIT. PRLNGD/RPTD CONT CAN CAUSE CONJUNCT, BLURRED VISION, TEARING, REDNESS, SEV IRRIT. INGEST: MAY CAUSE LUNG INFLA MM & DMG DUE TO ASPIR OF MATL INTO LUNGS, FATG, DROW, DIZZ &/OR LIGHTHEADEDNESS, HDCH, UNCOORDINATION, NAUS, Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS, LUNG DISORDERS, ASTHMA-LIKE CONDITIONS. First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT BRTHG. GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET MED HELP FOR ANY BRTHG DFCLTY. SKIN: FLUSH W/WATER. THEN WASH THORO W/SOAP & WATER. REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE RE-USE. EYE: FLUSH IMMED W/LRG AMTS OF WATER, ESPECIALLY UNDER LIDS FOR AT LST 15 MINS. IF IRRIT/OTHER EFTS PERSIST, OBTAIN MED TREATMENT. (SUPDAT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRON REGS. ELIM ALL SOURCES OF IGNIT. VENT AREA. VENT AREA W/EXPLO-PROOF EQUIP. SPILLS MAY BE COLLECTED W/ABSORB MATLS. USE NON-SPARKING TOOLS. EVAC ALL UNNECESSARY PERSO NNEL. PLACE COLLECTED MATL IN PROPER (SUPDAT) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. Handling And Storage Precautions: STORE BELOW 80F. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP FROM FREEZING. USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. Other Precautions: KEEP OUT OF REACH OF CHILDREN. AVOID CONT W/SKIN & EYES, & BRTHG OF VAPS. KEEP CNTNRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. AVOID CNDTNS WHICH RSLT IN FORM OF INHALABLE PARTICLES SUCH AS SPRAYING/AB RADING (SANDING) PAINTED SURFS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 80F,26.7C Extinguishing Media: DRY CHEMICAL OR FOAM, WATER FOG. CARBON DIOXIDE. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLO WHEN EXPOS TO EXTREME HEAT/FIRE. VAPS MAY IGNITE EXPLO AT AMBIENT TEMPS. VAPS ARE HVR/AIR & MAY TRAVEL LONG DISTANCES TO SOURCE OF(SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation: PROVIDE DILUTION VENTILATION OR LOC EXHAUST TO PREVENT BUILD-UP OF VAPS. USE EXPLO-PROOF EQUIP. USE NON-SPARKING EQUIP. Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). IMPERVIOUS CLOTHING, APRON, BOOTS. Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING/SMOKING. Supplemental Safety and Health: CNDTNS TO AVOID: W/COMBUST MATLS. FIRST AID PROC: INGEST: OBTAIN MED TREATMENT IMMED. EXPLO HAZ: IGNIT & FLASH BACK. CLSD CNTNRS MAY BURST IF EXPOS TO EXTREME HEAT/FIRE. MAY DECOMPOSE UNDER FIRE CNDTN S EMITTING IRRIT &/OR TOX GASES. SPILL PROC: CNTNR. COMPLETE PERSONAL PROT EQUIP MUST BE USED DURING CLEANUP. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >176F,>80C Appearance and Odor: NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume: 65.93 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: ELEVATED TEMPS, CONT W/OXIDIZING AGENT, STORAGE NEAR ACIDS, FREEZING, SPARKS, OPEN FLAME. IGNIT SOURCES, CONT (SUPDAT) Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES. Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, ALDEHYDES, TOXIC GASES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SPRAYMASTER DRYFALL ALKYD SPR 170 FLAT WHITE Cage: IO491 Assigned IND: Y Company Name: ICI PAINTS Street: 925 EUCLID AVE Zipcode: 44115 Label Required IND: Y Date Of Label Review: 02/12/1998 Status Code: C Label Date: 02/12/1998 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Severe Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMM. ACUTE: INHAL: IRRIT. FATG, DROW, DIZZ &/OR LT HEADNESS, HDCH, UNCOORDINATION, NAUS, VOMIT, DIARR, COUGHING, SNEEZING, CNS DEPRESS, RESP PROBLEMS, METALLIC TASTE, ANESTHETIC EFT/NARC, FEVER & CH ILLS, DEHYDRATION, PULM EDEMA, PNEUM, LOSS OF CONSCIOUSNESS, ASPHYX, DEATH. SKIN: IRRIT, DERM, DEFAT. EYE: IRRIT, CONJUNCT, BLURRED VISION, REDNESS. INGEST: LUNG DMG, FATG, DROW, DIZZ, LT HEADNESS, HD CH, UNCOORD, NAUS, VOMIT, DIARR, GI DISTURB, CNS DEPRESS, DFCLTY BRTHG, CONVULSIONS, LOSS CONSCIOUSNESS. CHRONIC: CANCER HAZ. CONTAINS BENZENE & SILICA CRYSTALLINE-QUARTZ WHICH ARE LISTED AS HUMAN BLO OD & LUNG CARCINS (FP N). =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ENAMEL, EQUIP LT GRAY 26307 ID 749611 Preparer's Name:W. A. ELLISON CAGE:PRATT CAGE:PRATT CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS (SOLVENT) (VAPOR PRESSURE 2 MM HG @ 20C) (LFL: 1.0 UFL: 7.0) CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: 30% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/ 525 MG/M3 ACGIH TLV:100 PPM/ 525 MG/M3 Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.05 MG/M3 RDUST9293 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:TALC (PIGMENT) CAS:14807-96-6 RTECS #:VV7720000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3 /20 MPPCF ACGIH TLV:2 MG/M3 /15 MPPCF Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED OSHA PEL:15MG/M3 TDUST/5 FUME ACGIH TLV:10MG/M3 TDUST; 9293 Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: < 1% Other REC Limits:NONE SPECIFIED OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:VOC: 3.27 LB/GL LESS WATER & NPRS*; 392 G/L LESS WATER; CALCULATED *NEGLIGIBLY PHOTOCHEMICALLY REACTIVE MATERIALS RTECS #:9999999VO Other REC Limits:NONE SPECIFIED Ingred Name:VOC: 6.56 LB/GAL SOLIDS; 787 G/L SOLIDS; CALCULATED RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:IRRITATION (GASTROINTESTINAL, NOSE, THROAT, EYE, SKIN). LUNG ASPIRATION: CHEMICAL PNEUMONITIS/CAN BE FATAL. CENTRAL NERVE SYS DEPRESSION. SKIN DEFATTING. PNEUMOCONIOSIS. SEVERE DAMAGE TO BLOOD FORMING , NERVOUS, URINARY & REPRODUCTIVE SYS. SOLVENTS ARE ASSOCIATED W/PERMANENT BRAIN/NERVOUS SYS DAMAGE. Explanation of Carcinogenicity:CRYSTALLINE SILICA HAS LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS, SUFFICIENT EVIDENCE IN EXPERIMANTAL ANIMALS(IARC). Effects of Overexposure:INGEST: NAUSEA/VOMITING. INHALE: HEADACHES, DIZZINESS, NAUSEA, CONFUSION. CHRONIC OVEREXPOSURE: NO APPETITE, METALLIC TASTE IN MOUTH, ANXIETY, CONSTIPATION, NAUSEA, WEAKNESS, INSOMNIA, HEADACHE, MUSCL E/JOINT PAIN, FINE TREMORS, NUMBNESS, DIZZINESS, HYPERACTIVITY & COLIC. METAL FUME FEVER:FLU-LIKE, FEVER, CHILLS, COUGH. Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA. KIDNEY CONDITIONS MAY BE AGGRAVATED BY LEAD. OCCUPATIONAL EXPOSURE TO LEAD IS REGULATED BY OSHA-29CFR1910.1025. ======================= First Aid Measures ======================= First Aid:INGEST: DO NOT INDUCE VOMITING. CALL POISON CONTROL, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY. INHALE: REMOVE TO FRESH AIR IMMEDIATELY. GIVE ARTIFICIAL RESPIRATION IF NEEDED. KEEP WARM & QUIET. GET IMM EDIATE MEDICAL AID. EYE: FLUSH THOROUGHLY W/LARGE AMOUNTS OF WATER FOR 15 MIN. GET MEDICAL AID. SKIN: REMOVE CONTAMINATED CLOTHES. WASH AFFECTED AREA WITH SOAP & WATER. PERSISTANT IRRIT/MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point:>108F,>42C Autoignition Temp:Autoignition Temp Text:572F Lower Limits:1.0 Upper Limits:7.0 Extinguishing Media:USE NFPA CLASS B(CO2, ALL PURPOSE DRY CHEMICAL OR ALCOHOL FOAM) FOR LIQUID FIRES. POLYMER FOAM PREFERRED FOR LARGE FIRES Fire Fighting Procedures:USE SCBA. WATER MAY BE INEFFECTIVE, USE TO COOL CNTNRS(FOG NOZZLE PREFERABLE) TO PREVENT PRESSURE BUILD-UP&AUTO- IGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT Unusual Fire/Explosion Hazard:OVEREXPOSURE-DECOMP PRODUCTS MAY CAUSE HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMED APPARENT. GET MED AID. KEEP CNTNRS CLOSED, AWAY FROM IGNITE SOURCES-MAY EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. ELIMINATE IGNITE SOURCES. DIKE AND CONTAIN. REMOVE WITH INERT MATERIAL (SAND, EARTH, ETC). USE COVERED METAL CONTAINERS FOR RECOVERY OR DISPOSAL. USE NON-SPARKING TOOLS. PREVENT CONTAMINATION OF SEWERS, STREAMS AND GROUNDWATER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 100F. LARGE QUANTITY STORAGE: COMPLY WITH OSHA 29CFR1910.106. DO NOT TAKE INTERNALLY. CNTNRS CLOSED AFTER USE. KEEP FROM CHILDREN. Other Precautions:DO NOT REUSE CONTAINERS FOR ANY PURPOSE. CONTAINERS SHOULD BE GROUNDED AND BONDED TO THE RECEIVING CONTAINER. DO NOT WELD, BRAZE OR CUT ON EMPTY CONTAINER. NEVER USE PRESSURE TO EMPTY. DRUM IS NOT A P RESSURE VESSEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESTRICTED AREA: NIOSH APPR'D CHEMICAL CARTRIDGE RESPIRATOR. SPRAYING: MECHANICAL PREFILTER MAY BE REQUIRED. CONFINED AREA: NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR. EXCEEDED TLV AREA: NIOSH/MSHA A PPR'D RESPIRATOR W/RIGHT PROTECT FACTOR. Ventilation:GENERAL DILUTION/LOCAL EXHAUST VENTILATION IN SUFFICIENT VOLUME & PATTERN TO KEEP CONCENTRATIONS BELOW EXPOSURE LIMITS. Other Protective Equipment:AS REQUIRED TO PREVENT SKIN CONTACT. USE OSHA STANDARDS FOR LEAD. Work Hygienic Practices:DO NOT BREATHE SANDING DUST. WASH HANDS AND FACE BEFORE EATING OR DRINKING. REMOVE ANY DECOMPOSITION PRODUCTS FROM AREA. Supplemental Safety and Health HAZARDOUS/POSSIBLE HAZARDOUS INGREDIENTS/ WASTE. REFER TO OSHA 29CFR1910 FOR SAFETY/PROTECTIVE REQUIREMENTS. WELDING, BRAZING OR TORCH CUTTING MATERIALS COATED WITH THIS PRODUCT MAY PRODUCE METAL OXID ES. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:277 TO 388F Melt/Freeze Pt:M.P/F.P Text:-50F,-46C Decomp Temp:Decomp Text:1832F,1000C Vapor Pres:2 Vapor Density:> THAN AIR Spec Gravity:1.3 pH:4-7 Viscosity:67-77 KU Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER Solubility in Water:SLIGHT Appearance and Odor:LIQUID, SOLVENT ODOR Percent Volatiles by Volume:50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS OR ALKALINE MATERIALS. Stability Condition to Avoid:AVOID EXCESS HEAT (>100F) & IGNITION SOURCES. Hazardous Decomposition Products:BURNING (INCL:WELD/CUT)PRODUCES SMOKE,CARBON MONOXIDE, CARBON DIOXIDE. OXIDES OF LEAD, ZINC MAY BE GENERATED. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW FEDERAL, STATE & LOCAL REGULATIONS & LAWS. INCINERATE IN EPA PERMITTED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. USE PRECAUTIONS FOR DISPOSAL OF HAZARDOUS/TOXIC MATERIALS-D001/D008. USE HA ZARDOUS WASTE LANDFILL FOR USED ABSORBENTS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FOAM FREE DEFOAMING CONCENTRATE Preparer's Name:BONITA C. PATTERSON CAGE:GO003 CAGE:GO003 CAGE:59923 ============= Composition/Information on Ingredients ============= Ingred Name:POLYDIMETHYL SILOXANE EMULSION CAS:9016-00-6 RTECS #:TQ2690000 Fraction by Wt: 17-24% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DIRECT CONTACT W/EYES MAY CAUSE MILD IRRITATION. PROLONGED CONTACT W/SKIN MAY CAUSE IRRITATION. Explanation of Carcinogenicity:NO CHEMICALS LISTED AS CARCINOGENS OR AS POTENTIAL CARCINOGENS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. CALL DR. IF SYMPTOMS PERSIST. EYES: FLUSH W/WATER AT LEAST 15 MINUTES. CALL DR. IF IRRITATION DEVELOPS. SKIN: FLUSH W/WATER. CALL DR. IF IRRITATION DEVELOPS. INGESTION : DRINK LARGE AMOUNTS WATER. DO NOT INDUCE VOMITING. CALL DR. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F,>93C Extinguishing Media:NA Fire Fighting Procedures:PRODUCT IS NOT FLAMMABLE Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:BEFORE ATTEMPTING CLEAN-UP REFER TO HAZARD DATA ABOVE. CONTAIN SPILL, USE MOP/ABSORBENT/WET VACUUM TO COLLECT MAT'L FOR PROPER DISPOSAL. RINSE AREA W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE GOOD PERSONAL HYGEINE PRACTICE. WASH CONTAM CLOTHES/EQUIPMENT BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED IF GOOD VENTILATION MAINTAINED. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Pres:NOT EST. Vapor Density:NOT EST. Spec Gravity:1.0 Evaporation Rate & Reference:NOT EST. Solubility in Water:DISPERSIBLE Appearance and Odor:MILKY WHITE EMULSION, ODORLESS Percent Volatiles by Volume:>80.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN TO THE BUTCHER COMPANY Stability Condition to Avoid:NONE KNOWN TO THE BUTCHER COMPANY Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION ==================== Disposal Considerations ==================== Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION & DISPOSAL OF THIS MATERIAL MUST BE IN ACCORDANCE W/FEDERAL, STATE, LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: CC-21 Cage: 0FWB4 ======================================================= Contractor Summary ======================================================= Cage: 0FWB4 ======================================================= Ingredients ======================================================= Cas: 7647-01-0 RTECS #: MW4025000 Percent by Wt: 23.5 OSHA PEL: C7 MG/M3;C5 PPM ACGIH TLV: NOT ESTABLISHED ACGIH STEL: C7.5 MG/M3;C5 PPM EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 9016-45-9 RTECS #: AX0247000 Percent by Wt: 1. Other REC Limits: 1.00 ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHALATION: PROLONGED EXPOSURE TO VAPORS MAY CAUSE SIGNS & SYMPTOMS OF CENTRAL NEVOUS SYSTEM DEPRESSION SUCH AS HEADACHES, DIZZINESS, WEAKNESS AND LOSS OF COORDINATION. VAPOR/MIST MAY RESULT IN IRRITA TION TO THE ENTIRE RESPIRATORY TRACT. EYE: MAY RESULT IN SEVERE EYE IRRITATION AND POSSIBLE DAMAGE OF THE CORNEAL, REDNESS AND TEARING. SKIN: PROLONGED OR REPEATED SKIN COTNACT MAY RESULT IN SKIN IRRI TATION LEADING TO DERMATITIS, DEFATTING OF SKIN MAY ALSO OCCUR. INGESTION: MAY RESULT IN GASTROINTESTINAL IRRITATION, HEADACHE, NAUSEA, VOMITING AND DIARRHEA. Signs And Symptions Of Overexposure: CENTRAL NERVOUS SYSTEM DEPRESSION SUCH AS HEADACHES, DIZZINESS, WEAKNESS AND LOSS OF COORDINATION. IRRITATION TO RESPIRATORY TRACT. SEVERE EYE IRRITATION AND POSSIBLE DAMAGE OF THE CORNEAL. REDNESS AND TEARING. SKIN IRRITATION LEADING TO DERMATITIS, DEFATTING OF SKIN MAY ALSO OCCUR.GASTROINTESTINAL IRRITATION, HEADACHE, NAUSEA, VOMITING AND DIARRHEA. Medical Cond Aggravated By Exposure: NONE KNOWN First Aid: EYE: REMOVE CONTACT LENSE IMMEDIATELY. FLUSH EYE WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN: WASH SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. INHALATION: REM OVE TO FRESH AIR. GIVE OXYGEN OR CPR. INGESTION: DO NOT GIVE ANY MOUTH TO AN UNCONSIOUS OR CONVULSING PERSON. DO NOT INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: KEEP UNNECESSARY PEOPLE AWAY. SPILLS ARE SLIPPERY, DIKE & CONTAIN WITH INERT ABSORBANT MATERIAL COLLECT FOR DISPOSAL. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. CONSULT LOCAL AUTHORITY FOR ALTERNATE METHODS Handling And Storage Precautions: STORE IN A COOL WELL VENTILATED AREA AWAY FROM SPARK, HEAT AND OPEN FLAME Other Precautions: KEEP OUT OF REACH OF CHILDREN ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NON FLAMMABLE Autoignition Temp Text: N/E Lower Limits: 0.00 Upper Limits: 0.00 Extinguishing Media: DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER Fire Fighting Procedures: SELF CONTAINED BREATHING APPARATUS Unusual Fire/Explosion Hazard: TOXIC FUMES MAY BE EMITTED IF MATERIAL IS EXPOSED TO EXTREME TEMPERATURES ======================================================= Control Measures ======================================================= Respiratory Protection: USE SELF CONTAINED AIR MASK IN CLOSED ROOMS Ventilation: GOOD VENTILATION SHOULD BE MAINTAINED Other Protective Equipment: IMPERVIOUS APRON AND BOOTS. PROVIDE EMERGENCY SAFETY SHOWERS AND EYE WASH FOUNTAIN NEAR WORK AREA Work Hygienic Practices: DO NOT MIX THIS PRODUCT WITH OTHER CHEMICALS. TOXIC FUMES MAY BE EMITTED ======================================================= Physical/Chemical Properties ======================================================= Boiling Point: >100.C, 212.F Vapor Pres: N/E Vapor Density: >1.00 Spec Gravity: 1.128 PH: <1 Solubility in Water: SOLUBLE Appearance and Odor: OPAQUE FUMING THIN LIQUID ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: KEEP AWAY FROM HEAT OR OPEN FLAME Materials To Avoid: VERY STRONG OXIDIZING AGENTS Hazardous Decomposition Products: SMOKE, CARBON MONOXIDE, CARBON DIOXIDE AND OTHER TOXIC FUMES Hazardous Polymerization Indicator: NO ======================================================= Other Information ======================================================= Other Information: NFPA HEALTH = 2; FLAMMABILITY = 0; REACTIVITY = 2; SPECIAL = 0. WE BELIEVE THE STATEMENTS, TECHNICAL INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE RELIABLE, BUT THEY ARE GIVEN WITHOUT WARRANTY OR GUARANTEE OF ANY KIND ======================================================= HAZCOM Label ======================================================= Product ID: CC-21 Cage: 0FWB4 Company Name: POLYTECH Street: 2520 SAN FERNANDO ROAD Zipcode: 90065 Label Required IND: Y Date Of Label Review: 07/12/2000 Status Code: A Origination Code: G Hazard And Precautions: INHALATION: PROLONGED EXPOSURE TO VAPORS MAY CAUSE SIGNS & SYMPTOMS OF CENTRAL NEVOUS SYSTEM DEPRESSION SUCH AS HEADACHES, DIZZINESS, WEAKNESS AND LOSS OF COORDINATION. VAPOR/MIST MAY RESULT IN IRRITA TION TO THE ENTIRE RESPIRATORY TRACT. EYE: MAY RESULT IN SEVERE EYE IRRITATION AND POSSIBLE DAMAGE OF THE CORNEAL, REDNESS AND TEARING. SKIN: PROLONGED OR REPEATED SKIN COTNACT MAY RESULT IN SKIN IRRI TATION LEADING TO DERMATITIS, DEFATTING OF SKIN MAY ALSO OCCUR. INGESTION: MAY RESULT IN GASTROINTESTINAL IRRITATION, HEADACHE, NAUSEA, VOMITING AND DIARRHEA. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HERESITE P-413 Preparer's Name:D. EDWARD BLAKE CAGE:0VKU9 CAGE:0VKU9 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL; (DENATURED ETHYL ALCOHOL). VP:42 @ 68F. CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 25.4% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:CONTACT CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION. SKIN:CONTACT MAY CAUSE IRRITATION, DEFATTING & DERMATITIS. INHAL:CAN CAUSE NASAL & RESPIRATORY IRRITATION, DIZZINESS, WEAKNE SS, FATIGUE, NAUSEA & HEADACHE. INGEST:CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING & (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:DIARRHEA. ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/LG AMTS OF WATER FOR AT LST 15 MINS, LIFTING UPPER & LOWER LIDS OCCAS. GET MED ATTN PROMPTLY. SKIN:THORO WASH EXPOS AREA W/SOAP & WATER. REMOVE CONTAM CLTHG. LAUNDER CONTAM CLTHG BEFORE R EUSE. INHAL:REMOVE INDIVIDUAL TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN OXYGEN. IF BRTHG HAS STOPPED GIVE ARTF RESP. KEEP PERS WARM, QUIET & GET MED ATTN. INGEST:DO NOT INDUCE VOMIT. GIVE (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point:68.0F,20.0C Lower Limits:3.3% Extinguishing Media:"ALCOHOL" FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE COLD WATER TO COOL FIRE-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. KEEP AWAY FROM HEAT, SPARKS, ELECTRICAL EQUIPMENT & OPEN FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE NON-ESSNTL PERS. ELIM ALL IGNIT SOURCES. VENTILATE AREA. EQUIP CLEAN-UP CREW W/APPROP PROT EQUIP. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PVNT SPREADING. NOTIFY APPROP AUTHS IF NEC. PUMP/ SCOOP LIQ TO SALVAGE TANK/DRUM. REMAINING (SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT & OPEN FLAME. Other Precautions:KEEP CLOSURE TIGHT & CONTAINER UPRIGHT TO PREVENT LEAKAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA APPROVED RESPIRATOR IS REQUIRED IF TLV OF ANY INGREDIENT IS EXCEEDED. Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S. Other Protective Equipment:COVER AS MUCH EXPOSED SKIN AREA AS POSSIBLE W/APPROPRIATE CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC:CONSCIOUS INDIVIDUAL A GLASS OF MILK/WATER. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MED ATTN. SPILL PROC:LIQ MAY BE ABSORBED W/SAND, CLAY, EARTH OR FLOOR ABSORBENT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>176F,>80C Vapor Pres:SEE ING Vapor Density:HVR/AIR Spec Gravity:1.26 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:51 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:KEEP AWAY FROM HEAT, SPARKS, ELECTRICAL EQUIPMENT & OPEN FLAME. Hazardous Decomposition Products:BY FIRE: CO*2, CO & VARIOUS HYDROBCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MATL MUST BE DISP OF I/A/W FED, STATE & LOC ENVIRON CONTROL REGS. INCIN IS PREFERRED METH. EMPTY CNTNRS MUST BE HNDLD W/CARE DUE TO PROD RESIDUE. DECONTAM CNTNRS PRIOR TO DISP. DO NOT HEAT/CUT E MPTY CNTNR W/ELECTRIC OR GAS TORCH. ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:JP-4 CAGE:3P045 CAGE:3P045 ============= Composition/Information on Ingredients ============= Ingred Name:PENTANE CAS:109-66-0 RTECS #:RZ9450000 Fraction by Wt: < 2.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM/750 STEL ACGIH TLV:600 PPM/750STEL;9293 Ingred Name:HEXANE (N-HEXANE) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: < 5.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HEXANE ISOMERS (OTHER THAN N-HEXANE) Fraction by Wt: < 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM (MFR) ACGIH TLV:500 PPM (MFR) Ingred Name:CYCLOHEXANE (SARA III) CAS:110-82-7 RTECS #:GU6300000 Fraction by Wt: < 3.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM, 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: < 1% Other REC Limits:NONE RECOMMENDED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:METHYLCYCLOHEXANE CAS:108-87-2 RTECS #:GV6125000 Fraction by Wt: < 8% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:400 PPM; 9293 Ingred Name:N-HEPTANE CAS:142-82-5 RTECS #:MI7700000 Fraction by Wt: < 7% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9293 Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: < 2% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:OCTANE CAS:111-65-9 RTECS #:RG8400000 Fraction by Wt: < 5.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM/375 STEL ACGIH TLV:300 PPM/375STEL;9293 Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: < 4% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NONANE CAS:111-84-2 RTECS #:RA6115000 Fraction by Wt: < 3.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM; 9293 Ingred Name:TRIMETHYL BENZENE (SARA III) CAS:25551-13-7 RTECS #:DC3220000 Fraction by Wt: < 1.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9293 Ingred Name:NAPHTHALENE (SARA III) CAS:91-20-3 RTECS #:QJ0525000 Fraction by Wt: < 1% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM/15 STEL ACGIH TLV:10 PPM/15 STEL; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:DIMETHOXYETHANE CAS:110-71-4 RTECS #:KI1451000 Fraction by Wt: < 0.2% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE-HIGH VAPOR CONCENTRATIONS MAY CAUSE CNS DEPRESSION;I.E.HEADACHE,NAUSEA,DROWSINESS,DIZZINESS.ACCIDENTAL INGESTION MAY CAUSE SIMILAR SYMPTOMS.IT IS AN ASPIRATION HAZARD.MAY CAUSE EYE IRRITATION,RE DNESS,TEARING & BURNING.PROLONGED/REPEATED SKIN CONTACT CAN CAUSE IRRITATION,DEFATTING & DERMATITIS.CHRONIC-DERMATITIS. Explanation of Carcinogenicity:CONTAINS BENZENE WHICH CAUSES LEUKEMIA. VAPORS CAN CAUSE KIDNEY CANCER IN MALE RATS & LIVER CANCER IN FEMALE MICE. Effects of Overexposure:HIGH VAPOR CONCENTRATIONS MAY CAUSE CNS DEPRESSION; I.E. HEADACHE, NAUSEA, DROWSINESS, DIZZINESS. ACCIDENTAL INGESTION MAY CAUSE SIMILAR SYMPTOMS. IT IS AN ASPIRATION HAZARD. MAY CAUSE EYE IRRITATION, REDNESS, TEARING & BURNING. PROLONGED/REPEATED SKIN CONTACT CAN CAUSE IRRITATION, DEFATTING & DERMATITIS. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR IMPAIRED RESPIRATORY OR LIVER OR KIDNEY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:CALL A PHYSICIAN IN ALL CASES.EYES:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES,HOLDING EYELIDS OPEN.SKIN:WASH WITH SOAP & WATER.INHALED:REMOVE TO FRESH AIR & PROVIDE CPR/OXYGEN IF NECESSARY.ORAL:DO NO T INDUCE VOMITING.CALL A PHYSICIAN IMMEDIATELY.IF VOMITING OCCURS SPONTANEOUSLY,KEEP HEAD BELOW HIPS. ===================== Fire Fighting Measures ===================== Flash Point:<-10F,<-23C Lower Limits:1% Upper Limits:6% Extinguishing Media:USE CO2, FOAM, DRY CHEMICAL OR WATER FOG. WATER MAY BE INEFFECTIVE. PRODUCT FLOATS ON SURFACE OF WATER & REIGNITES. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT & A FULL FACED SELF CONTAINED BREATHING APPARATUS/SUPPLIED-AIR RESPIRATOR.COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:MATERIAL CONTAMINATED WITH THE PRODUCT AND STORED IN A CLOSED SPACE MAY UNDERGO SPONTANEOUS COMBUSTION. VAPORS MAY TRAVEL TO IGNITION SOURCE & FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS.ELIMINATE ALL SOURCES OF IGNITION.USE EXPLOSION-PROOF TOOLS.SHUT OFF FUEL SOURCE.DIKE SPILL.PREVENT LIQUID FROM ENTERING SEWERS/WATERWAYS.RECOVER FREE LIQUID.ADD SAND,EARTH OR OTHER ABSORBENT MATERIAL.TRANSFER TOCONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE IN ACCORDANCE WITH NATIONAL FIRE PROTECTION ASSOCIATION REGULATIONS.KEEP CONTAINERS CLOSED.HANDLE IN WELL-VENTILATED AREA. Other Precautions:"EMPTY" CONTAINERS RETAIN RESIDUE AND CAN BE DANGEROUS.DO NOT PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRIND OR EXPOSE SUCH CONTAINERS TO HEAT,FLAME,SPARKS.THEY MAY EXPLODE AND CAUSE INJURY/DEATH.AVOID REPEATED OR PROLONGED CONTACT WITH SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN CONCENTRATIONS IN AIR MAY EXCEED THE PERMISSIBLE EXPOSURE LIMIT, AND WHERE ENGINEERING, WORK PRACTICES ARE NOT ADEQUATE, WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OR ORGANIC VAPOR RE SPIRATOR OR SUPPLIED-AIR RESPIRATOR. Ventilation:LOCAL/MECHANICAL (GENERAL) VENTILATION - EXPLOSION PROOF, WELL GROUNDED EQUIPMENTS Other Protective Equipment:IMPERVIOUS CLOTHING TO AVOID SKIN AND EYE CONTACT. EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:AVOID CONTACT WITH EYES, SKIN OR CLOTHING. WASH HANDS AFTER USING PRODUCT. AVOID BREATHING VAPORS OR MISTS. Supplemental Safety and Health FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A, SAME NSN. FOR USE AS A MOTOR FUEL ONLY. DO NOT USE AS A CLEANING SOLVENT OR FOR OTHER NON-MOTOR FUEL USES. UNDER NORMAL WORKING CONDITIONS AT SERV ICE STATIONS, A RESPIRATOR IS NOT WARRANTED. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:120F,49C Vapor Pres:103-155 Spec Gravity:0.75 - 0.76 Solubility in Water:TRACE Appearance and Odor:COLORLESS LIQUID; AROMATIC ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, STATIC ELECTRICITY AND OTHER SOURCES OF IGNITION. PREVENT VAPORS ACCUMULATION. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL MUST BE IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS. THIS MATERIAL IS CLASSIFIED BY THE EPA AS A HAZARDOUS WASTE UND ER RCRA. NO. D001 IGNITABLE WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3220 L ACRYLIC SEMI-GLOSS MED BS Preparer's Name:T. SNIDER CAGE:0S2N2 CAGE:0S2N2 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 3% Other REC Limits:10 MG/CUM OSHA PEL:50 PPM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:VOLATILE ORGANIC COMPOUNDS: 1.38 LB/GL (165 G/L) - COATING RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NOSE, THROAT & LUNG IRRITATION. SKIN: IRRITATION, DERMATITIS. EYES: IRRITATION. INGESTION: GI IRRITATION. CHRONIC: LONG TERM UNPROTECTED OVEREXPOSURE TO MISTS FROM SPRAY APPLICATION MAY CA USE LUNG DISEASE (SILICOSIS). Explanation of Carcinogenicity:NONE Effects of Overexposure:HEADACHE, NAUSEA, IRRITATION, BURNING, VOMITING, DIARRHEA ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. APPLY CPR IF BREATHING HAS STOPPED. EYES: WASH W/CLEAN WATER FOR AT LEAST 15 MINS. SKIN: WASH W/SOAP & WATER. INGESTION: DRINK 1-2 GLASSES OF WATER TO DILUTE. ASPIRATI ON HAZARD. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT, INCLUDING SCBA IS RECOMMENDED. USE WATER TO COOL CONTAINERS. Unusual Fire/Explosion Hazard:WHEN EXPOSED TO EXTREME HEAT, CONTAINERS MAY BUILD UP PRESSURE & EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. PREVENT SKIN & EYE CONTACT & BREATHING OF VAPOR. CONTAIN & REMOVE W/INERT ABSORBENT. DON'T ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. ABSORB LARGE SPILLS W/SAND, CLAY/DIATOMAC EOUS EARTH. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >200F. Other Precautions:DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED FOR BRUSH & ROLL APPLICATION. FOR SPRAY APPLICATION, WEAR A PROPERLY FITTED NIOSH/MSHA APPROVED VAPOR/PARTICULATE RESPIRATOR UNTIL ALL VAPORS & SPRAY MIST ARE EXHAUSTED. Ventilation:SUFFICIENT IN VOLUME & PATTERN TO KEEP AIR CONTAMINANT CONCENTRATION BELOW APPLICABLE PEL/TLV EXPOSURE LIMITS. Other Protective Equipment:COVERALLS, HOOD Work Hygienic Practices:WASH HANDS BEFORE EATING/USING RESTROOM. REMOVE & LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health PROTECTIVE CREAMS MAY BE USED FOR CLEAN-UP, NOT FOR PROTECTION. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Density:<1 Spec Gravity:1.3 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:DILUTABLE Appearance and Odor:WHITE COLORED LIQUID W/AMMONIACAL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXTREME HEAT, TEMPS >200F ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GLASS BEADS CAGE:NRTHE CAGE:NRTHE ============= Composition/Information on Ingredients ============= Ingred Name:GLASS OXIDE (SILICONE/ALUMINUM/CALCIUM/SODIUM/MAGNESIUM/POTASSIUM OXIDE & SILICONE DIOXIDE CAS:65997-17-3 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:30MG/M3 10 MG/M3 RDUST Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:RESPIRATORY & EYE IRRITATION, DEHYDRATING TO NOSE/THROAT/SKIN. ======================= First Aid Measures ======================= First Aid:REMOVE TO FRESH AIR, WASH IN FRESH WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NA Upper Limits:NA Extinguishing Media:NONE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & DISCARD, AVOID EXCESS DUSTING. ======================Handling and Storage ====================== Handling and Storage Precautions:CARE SHOULD BE TAKEN TO AVOID DUSTING/SPILL WHICH COULD RESULT IN SLIPPAGE. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE OSHA APPROVED DUST MASK OR RESPIRATOR IF DUSTING OCCURS. Ventilation:LOCAL EXHAUST. Other Protective Equipment:NONE Work Hygienic Practices:NONE Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:1346F,730C Melt/Freeze Pt:M.P/F.P Text:1832F,1000C Vapor Pres:NA Vapor Density:NA Spec Gravity:2.46-2.49 Evaporation Rate & Reference:NA Solubility in Water:NONSOLUBLE Appearance and Odor:ESSENTIALLY CLEAR TRANSPARENT & COLORLESS, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NA Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIAL PRECAUTIONS. MAY BE DISPOSED OF IN ANY APPROVED LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GREY TYPE I CAGE:MEDUS CAGE:MEDUS ============= Composition/Information on Ingredients ============= Ingred Name:TRICALCIUM SILICATE; (3CAO.SIO*2) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:DICALCIUM SILICATE; (2CAO.SIO*2) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TRICALCIUM ALUMINATE; (CAO.AL*2O*3) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TETRACALCIUM ALUMINOFERRATE; (4CAO.AL*2O*3FE*2O*3) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:GYPSUM; (CASO*4.KH*2O) CAS:13397-24-5 RTECS #:MG2360000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:WET CEMENT, ESPECIALLY AS AN INGRED IN PLASTIC (UNHARDENED) CONCRETE, MORTAR OR SLURRIES, CAN DRY THE SKIN & CAUSE CAUSTIC BURNS. DIRECT CONTACT WITH EYES CAN CAUSE IRRIT. INHAL CAN IRRIT THE U PPER RESP SYSTEM. CHRONIC:CEMENT CAN CAUSE INFLAMM OF THE LINING TISS OF INTERIOR OF NOSE & INFLAMM (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OF CORNEA. HYPERSENSITIVE INDIVIDUALS MAY DEVELOP AN ALLERGIC DERM. (CEMENT MAY CONTAIN TRACE (LESS THAN 0.05%) AMTS OF CHROMIUM SALTS OR CMPDS INCL HEXAVALENT CHROMIUM, OR OTHER METALS FOUNDTO BE HAZ OR TOX IN SOME CHEM FORMS. THESE METALS ARE MOSTLY PRESENT AS TRACE SUBSTITUTIONS WITHIN PRINCIPAL MINERALS.) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IRRIGATE IMMEDIATELY AND REPEATEDLY WITH WATER FOR AT LEAST 15 MINUTES AND GET PROMPT MEDICAL ATTENTION. SKIN:WASH EXPOSED AREAS WITH SOAP AND WATER. APPLY STERILE DRESSINGS. INGEST:CONSULT A PHY SICIAN IMMEDIATELY. DRINK WATER. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:USE DRY CLEANUP METHODS THAT DO NOT DISPERSE THE DUST INTO THE AIR. AVOID BREATHING THE DUST. EMERGENCY PROCEDURES ARE NOT REQUIRED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PRECAUTIONS MUST BE TAKEN. CEMENT BURNS WITH LITTLE WARNING-LITTLE HEAT IS SENSED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN DUSTY ENVIRONMENT, THE USE OF NIOSH/MSHA APPROVED RESPIRATOR IS RECOMMENDED. Ventilation:LOCAL EXHAUST CAN BE USED TO CONTROL AIRBORNE DUST LEVELS. Other Protective Equipment:BARRIER CREAMS, BOOTS, & PROT CLTHG TO PROT SKIN FROM PRLNGD CONTACT W/WET CEMENT IN PLASTIC CONCRETE, MORTAR, SLURRIES. Work Hygienic Practices:IMMED AFTER WORKING WITH CEMENT OR CEMENT-CONTAINING MATLS, WORKERS SHOULD SHOWER WITH SOAP AND WATER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:3.15 (H*2O=1) Solubility in Water:SLIGHT (O.1-1.0%) Appearance and Odor:GRAY OR WHITE POWDER; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALUMINUM POWDER & OTHER ALKALI & ALKALI EARTH ELEMENTS WILL REACT IN WET MORTAR OR CONCRETE, LIBERATING HYDROGEN GAS. Stability Condition to Avoid:KEEP DRY UNTIL USED. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL AMTS OF MATL CAN BE DISP OF AS COMMON WASTE OR RETURNED TO THE CONTAINER FOR LATER USE IF IT IS NOT CONTAMINATED. LARGE VOL MAY REQUIRE SPECIAL HANDLING. DISPOSE OF IN ACCORDANCE WITH LOCAL, STA TE, AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:699, IMMERSION CLEANER & COLD PARTS CLEANER Preparer's Name:SK TECHNICAL SERVICES CAGE:IO253 CAGE:IO253 CAGE:30530 ============= Composition/Information on Ingredients ============= Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: >0.1% OSHA PEL:500 PPM;1000, C ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYLENE, TETRACHLORO-; (TETRACHLOROETHYLENE) CAS:127-18-4 RTECS #:KX3850000 Fraction by Wt: >0.1% OSHA PEL:100 PPM ACGIH TLV:25PPM/100,A3 STEL;94 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SUPP DATA: OLEIC ACID IS AN EXPERIMENTAL TUMORIGEN. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: DO NOT LEAVE VICTIM UNATTENDED. SEEK IMMED MED ATTN IF NECESSARY. RTECS #:9999999ZZ Ingred Name:RESP PROT:& EMER. SELECTION & USE OF RESP PROT EQUIP SHOULD I/A/W OSHA GEN INDUST STD 29 CFR 1910.134-RESP PROT. RTECS #:9999999ZZ Ingred Name:CHLORINATED SOLVENTS (CONTAINING ING 9&10) Fraction by Wt: <1.0% Ingred Name:SOLVENT NAPHTHA; (AROMATIC 150). MAY CONTAIN UP TO 5% INGRED 2. CAS:64742-94-5 RTECS #:WF3100000 OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:NAPHTHALENE CAS:91-20-3 RTECS #:QJ0525000 OSHA PEL:10 PPM;15 PPM STEL ACGIH TLV:10 PPM;15 PPM STEL EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:2-PYRROLIDINONE, 1-METHYL-; (N-METHYL-2-PYRROLIDONE) CAS:872-50-4 RTECS #:UY5790000 OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:DIPROPYLENE GLYCOL, MONOMETHYL ETHER CAS:34590-94-8 RTECS #:JM1575000 OSHA PEL:100PPM;150PPM STEL,S ACGIH TLV:100PPM;150PPM STEL,S Ingred Name:ETHANOL, 2-AMINO-; (ETHANOLAMINE) CAS:141-43-5 RTECS #:KJ5775000 OSHA PEL:3 PPM;6 PPM STEL ACGIH TLV:3 PPM;6 PPM STEL Ingred Name:9-OCTADECENOIC ACID, (Z)-; (OLEIC ACID) CAS:112-80-1 RTECS #:RG2275000 Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN: CORR TO LIVING TISSUE & IS ABSORBED THRU SKIN CAUSING SYSTEMIC POISONING. CONT W/UNPROTECTED SKIN CAN CAUSE DISCOLORATION, IRRIT, BLISTER & SLOW HEALING CHEM BURNS. EYES: CONT W/LIQ MAY C AUSE SEV CHEM BURNS & PRDCE PERM DAM. INHAL: MAY RSLT IN SEV RESP IRRIT; GI DISTRESS (NAUS/VOMIT), CNS,(EFTS OF OVEREXP) Explanation of Carcinogenicity:METHYLENE CHLORIDE, TETRACHLOROETHYLENE: GROUP 2B (IARC), GROUP 2 (NTP). Effects of Overexposure:HLTH HAZ:DEPRESS (HDCH, DROW, DIZZ, CONFUSN) & TINGLING OR NUMBNESS OF EXTREMITIES. SEV EXPOS MAY LEAD TO RESP FAILURE, COMA/DEATH. INGEST:MAY PRDCE BURN PAIN IN MOUTH & STOM, SEV ABDOM PAIN W/ NAUS/V OMIT/SLOW RESP & IRREG PULSE. SYMP SIMILAR TO THOSE FOR INHAL ALSO MAY OCCUR. CHRONIC: EXPOS TO HIGH CONC (SUPP DATA) Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING LIVER, KIDNEY, LUNG OR CARDIOVASCULAR DYSFUNC MAY HAVE INCR SUSCEPTIBILITY TO EFFECTS OF EXPOS. CONTACT WITH SKIN MAY AGGRAVATE PRE-EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/CLEAN H2O FOR @ LST 15 MIN LIFT LIDS OCCAS. CONSULT PHYS IF IRRIT PERSISTS. SKIN:REMOVE CONTAMD CLTHG. WASH SKIN TWICE W/SOAP/H2O. IF IRRIT DEVELOPS & PERSISTS, CONSULT PHYS. INGEST: ASPIR HAZ. IF CONSCIOUS, DILUTE W/4-8OZ OF H2O & SEEK IMMED MED ATTN. DO NOT INDUCE VOMIT. INHAL: REMOVE TO FRESH AIR IMMED. USE O2 IF THERE IS DFCLTY BRTHG/ARTF RESP IF RESP HAS STOPPED. (ING 12) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:142F,61C Lower Limits:0.8% Upper Limits:7.0% Extinguishing Media:NONE SPECIAL. MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DECOMP & COMBUSTION PROD MAY BE TOX. HEATED TANKS MAY RUPTURE, EXPLODE/BE THROWN INTO AIR. VAP ARE HVR/AIR & MAY TRAVEL GREAT DIST TO IGNIT SOURCES & FLASHBACK. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA & AVOID BRTHG VAP. ABSORB SPILL W/ OIL ABSORB/SODA ASH. CATCH & COLLECT FOR RECOVERY AS SOON AS POSSIBLE. SHOVEL INTO CLOSABLE CONTR FOR DISP. WEAR PROT EQUIP. CONTAIN AWAY FROM SURFACE WATE RS AND SEWERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, & OPEN FLAMES. USE W/ADEQ VENT. AVOID CONT W/SKIN/EYES/CLTHG. AVOID BRTHG VAP. EMPTY PROD CONTR MAY CNTN PROD RESIDUE. Other Precautions:DO NOT PRESSURIZE, CUT, HEAT, WELD, GRIND OR EXPOSE CONTAINERS TO FLAME OR OTHER SOURCES OF IGNITION. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPRVD RESP PROT EQUIP WHEN CONC OF VAP EXCEEDS APPLIC EXPOS LIM. DPNDG ON AIRBORNE CONC, USE NIOSH/MSHA APPRVD RESP/GAS MASK W/APPROP CARTRIDGES/CANISTERS (FOR ORG VAP). NIOSH/MSHA APP RVD SCBA IS REQD FOR LG SPILLS (ING 13) Ventilation:PROVIDE LOC EXHAUST/GEN DILUTION VENT, AS DETERMINED NECESSARY, TO MAINTAIN CONC OF VAPORS BELOW APPLIC EXPOS LIM. Other Protective Equipment:EMER EYEWASH, DELUGE SHOWER . WEAR SOLV- RESISTANT BOOTS/APRON OTHER PROT CLTHG WHERE SPILLS/SPLASHES ARE POSSIBLE Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. WASH THOROUGHLY WITH SOAP AND WATER AFTER HNDLG & BEFORE EAT/DRINK OR USING TOBACCO PROD. Supplemental Safety and Health SOL IN H2O: COMPLETELY MISCIBLE IN ALL PROPORTIONS. EFTS OF OVEREXP: MAY LEAD TO DAM TO LIVER/KIDNEYS/LUNGS. CONT W/SKIN MAY CAUSE DERM, GI DISORDERS & PRDCE SYM SIMILAR TO THOSE FOR INHAL. DIPROPLYEN E GLYCOL METHYL ETHER IS MILD ALLERGEN.NAPHTHALENE IS AN EXPERIMENTAL TUMORIGEN, & MUTAGENIC DATA EXISTS. (ING 11) ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:>210F,>99C Melt/Freeze Pt:M.P/F.P Text:<10F,<-12C Vapor Pres:10.9@25C Vapor Density:2.6 Spec Gravity:0.95(WATER=1) pH:10.8 Evaporation Rate & Reference:1.0(WATER=1) Solubility in Water:SUPP DATA Appearance and Odor:CLEAR, REDDISH BROWN LIQUID WITH HYDROCARBON ODOR. Percent Volatiles by Volume:92(WT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:(E.G. CHLORINE, PEROXIDES, STRONG ACIDS). Hazardous Decomposition Products:THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CO, NOX, AND ACRID SMOKE. Conditions to Avoid Polymerization:GLYCOL ETHERS HAVE BEEN SHOWN TO FORM EXPLOSIVE PEROXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. CONTACT SAFETY-KLEEN REGARDING RECYCLING.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:25F4 CAGE:03538 CAGE:03538 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNC ONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:V1 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER & NICKEL COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMYL ACETATE CAGE:62910 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:N-AMYL ACETATE (SARA III) * CAS:628-63-7 RTECS #:AJ1925000 OSHA PEL:100 PPM * ACGIH TLV:100 PPM; 9192 * EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 6,500 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-INHALE:MAY CAUSE RESPIRATORY TRACT IRRITATION,NARCOSIS,HEADACHE,FATIGUE,COUGH,NAUSEA,DIZZINESS,CNS DEPRESSION,KIDNEY & LIVER DAMAGE & EDEMA OF THE GLOTTIS.ORAL:MAY BE ABSORBED CAUSING SYMPTOMS S IMILAR TO INHALATION.EYES/SKIN:MAY CAUSEIRRITATION,REDNESS & PAIN.LIQUID DEGREASES THE SKIN.CHRONIC-DERMATITIS Effects of Overexposure:MAY CAUSE RESPIRATORY TRACT IRRITATION, NARCOSIS, HEADACHE, FATIGUE, COUGH, NAUSEA, DIZZINESS, CNS DEPRESSION, KIDNEY & LIVER DAMAGE & EDEMA OF THE GLOTTIS. ORALLY MAY BE ABSORBED CAUSING SYMPTOMS SIM ILAR TO INHALATION. MAY CAUSE EYES AND SKIN IRRITATION, REDNESS & PAIN. LIQUID DEGREASES THE SKIN. Medical Cond Aggravated by Exposure:USE OF ALCOHOLIC BEVERAGES MAY ENHANCE TOXIC EFFECTS. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IMMEDIATELY.EYE/SKIN:FLUSH WITH WATER FOR AT LEAST 15 MINUTES.HOLD EYELIDS OPEN.INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.ORAL:IF CONSCIOUS,DRINK WATER & INDUCE VOMITING.CALL A PHYSICIAN IMMEDIATELY.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:=15.6C, 60.F Autoignition Temp:=360.C, 680.F Lower Limits:1.1 Upper Limits:7.5 Extinguishing Media:CO2, FOAM/DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAPOR-AIR MIXTURES ARE EXPLOSIVE WITHIN FLAMMABLE LIMITS. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION SOURCE AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE & EVAC AREA.USE PROTCTV CLOTHG & RESP PROTCTION FM VAP.CONTAIN & RECOVR LIQ WHEN POSS.SPILLS MAY BE ABSORBD W/INERT MATL,VERMICULITE,DRY SAND & PLACE IN A CONTNR PENDING DISPOSAL.DO NOT FLUS H TO SEWER.HAVE DRY POWDER EXTINGUISHERON HAND. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-KEEP IN TIGHTLY CLOSED CONTAINERS AT COOL,VENTILATED AREA AWAY FROM INCOMPATIBLES.OUTSIDE OR DETACHED STORAGE IS PREFERRED. Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. KEEP OUT OF SURFACE WATERS AND SEWERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, A NIOSH-APPROVED FULL FACEPIECE CHEMICAL CARTRIDGE RESPIRATOR MAY BE USED. ALTERNATIVELY, A SUPPLIED AIR FULL FACEPIECE RESPIRATOR OR AIRLINED HOOD MAY BE WORN. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND IMPERVIOUS CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=140.C, 284.F Melt/Freeze Pt:<-100.C, -148.F Vapor Pres:4 @ 68F Vapor Density:4.5 Spec Gravity:0.87 Evaporation Rate & Reference:0.42 (N-BUTYL ACETATE=1) Solubility in Water:0.2 G% @ 20C Appearance and Odor:CLEAR COLORLESS LIQUID, CHARACTERISTIC FRUITY ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS AND ALKALIES. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE MAY BE FORMED. ==================== Disposal Considerations ==================== Waste Disposal Methods:COLLECTED SPILLS MAY BE ATOMIZED IN A RCRA- APPROVED COMBUSTION CHAMBER OR SHIPPED TO RCRA APPROVED FACILITY FOR DISPOSAL;RQ(CWA/CERCLA):5000LBS;ENSURE COMPLIANCE W/LOCAL,STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ORANGE LOTION HAND CLEANER WITH PUMICE, 0954 Preparer's Name:DONALD H SINNER CAGE:GO199 CAGE:GO199 CAGE:02905 ============= Composition/Information on Ingredients ============= Ingred Name:CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-,(R)-; (D-LIMONENE) CAS:5989-27-5 RTECS #:GW6360000 Fraction by Wt: 7-15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALKOXYLATED FATTY ALCOHOL; (LINEAR ALCOHOL ALKOXYLATE) CAS:69227-21-0 Fraction by Wt: 5-10% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:DIRECT CONTACT MAY CAUSE IRRITATION. INGESTION:MAY CAUSE GASTRIC UPSET. SKIN:PROLONGED CONTACT OR REPEATED OVEREXPOSURE MAY CAUSE IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . EYES:DO NOT RUB EYES. FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. IF CONDITION WORSENS OR IRRITATION PERSISTS, CONTACT A PHYSICIAN. INGESTION:DRINK PLENTY OF MILK OR WATER. CALL PHYSICIAN OR POISON CONTROL CENTER IN CASE OF SYMPTOMS OR ILLNESS. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP WITH ABSORBENT MATERIAL. CONTAIN AND PICK UP WASTE MATERIALS. PUT IN A SEALED APPROVED CONTAINER. FLUSH AREA WITH WATER TO REDUCE SLIPPING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT TAKE INTERNALLY. WASH THOROUGHLY WITH PLENTY OF WATER AFTER ACCIDENTAL CONTACT. Other Precautions:KEEP OUT OF REACH OF CHILDREN. KEEP FROM FREEZING. AVOID EXCESSIVE HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NOT REQUIRED WHEN USED AS DIRECTED. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NOT REQUIRED WHEN USED AS DIRECTED. Work Hygienic Practices:GOOD HOUSEKEEPING AND PERSONAL CARE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:201F,94C Vapor Pres:15 Vapor Density:0.6 Spec Gravity:1.02 (H*2O=1) pH:6-7 Evaporation Rate & Reference:0.7 (H*2O=1) Solubility in Water:80% Appearance and Odor:CREAMY OPAQUE VISCOUS GEL, ORANGE FRAGRANCE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:JET GLO SYSTEM INTERMIXED COLORS, LEAD COLORS Resp. Party Other MSDS Num.:JETGLO/1 CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE; VP: 5.9 MM HG CAS:1330-20-7 RTECS #:ZE2100000 Minumum % Wt:2. Maxumum % Wt:4. Other REC Limits:N/K OSHA PEL:100 PPM OSHA STEL:N/K ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PROPANOL, 1(OR 2)-(2-METHOXYMETHYLETHOXY)-; (2-METHOXYMETHYLETHOXYPROPANOL) VP: 0.4 MM HG CAS:34590-94-8 RTECS #:JM1575000 Minumum % Wt:0. Maxumum % Wt:2. Other REC Limits:N/K OSHA PEL:600 MG/M3;100 PPM OSHA STEL:N/K ACGIH TLV:606 MG/M3;100 PPM ACGIH STEL:909 MG/M3;150 PPM Ingred Name:METHYL ETHYL KETONE; VP: 70.0 MM HG CAS:78-93-3 RTECS #:EL6475000 Minumum % Wt:0. Maxumum % Wt:2. Other REC Limits:N/K OSHA PEL:590 MG/M3;200 PPM OSHA STEL:N/K ACGIH TLV:590 MG/M3;200 PPM ACGIH STEL:885 MG/M3;300 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ACETATE; VP: 86.0 MM HG CAS:141-78-6 RTECS #:AH5425000 Minumum % Wt:8. Maxumum % Wt:24. Other REC Limits:N/K OSHA PEL:1400 MG/M3;400 PPM OSHA STEL:N/K ACGIH TLV:1440 MG/M3;400 PPM ACGIH STEL:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-PROPANOL, 1-METHOXY-, ACETATE; (1-METHOXY-2-PROPANOL ACETATE) VP: 1.8 MM HG CAS:108-65-6 RTECS #:AI8925000 Minumum % Wt:20. Maxumum % Wt:30. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:PROPANOL, 1(OR 2)-(2-METHOXYMETHYLETHOXY)-, ACETATE; (METHOXYMETHYETHOXY-PROPANOL ACETATE) CAS:88917-22-0 Minumum % Wt:1. Maxumum % Wt:2. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Minumum % Wt:0. Maxumum % Wt:35. Other REC Limits:N/K OSHA PEL:15 MG/M3 OSHA STEL:N/K ACGIH TLV:10 MG/M3 ACGIH STEL:N/K Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Minumum % Wt:0. Maxumum % Wt:2. Other REC Limits:N/K OSHA PEL:3.5 MG/M3 OSHA STEL:N/K ACGIH TLV:3.5 MG/M3 ACGIH STEL:N/K Ingred Name:LEAD CHROMATE CAS:1344-37-2 < Wt:25. Other REC Limits:N/K OSHA PEL:0.05 MG/M3 OSHA STEL:N/K ACGIH TLV:0.05 MG/M3 ACGIH STEL:N/K Ingred Name:LEAD (COMPOUND) (MAXIMUM) (%LEAD):25(15) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 25(15%) Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:0.15 MG/M3 ACGIH STEL:N/K EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CHROMIUM (COMPOUND) (MAXIMUM)(% CHROMIUM) 25(4) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 25(4%) Other REC Limits:N/K OSHA PEL:1 MG/M3 OSHA STEL:N/K ACGIH TLV:0.5 MG/M3 ACGIH STEL:N/K EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ALCOHOLS & ACETATES CAN BE ABSORBED THRU SKIN.TO MIN EXPOS, FOLLOW RECS FOR PROPER USE, VENT, & PERS PROT EQUIP. ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREX P MAY RSLT IN UNCON & POSS DEATH. ACUTE OCCUP EXPOS TO LEAD IS UNCOMMON, BUT RSLTS IN SYMPS SIMILAR TO CHRONIC OVEREXP DESCRIBED BELOW. SIGNS & SYMPS OF OVEREXP: HDCH, DIZZ, NAUS, & LOSS OF COORD AR E INDICATIONS OF EXCESS EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOS. CHRONIC: CHRONIC OVEREXP TO LEAD MAY RSLT IN DMG TO BLOOD-FORM, NERV, URINARY, & REPRO SYS (EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOLUME 65, PAGE 149, 1996: GROUP 2B. ANIMAL: LUNG. LEAD CHROMATE: IARC MONOGRAPHS, VOL 49, PG 49, 1990:GRP 1. NTP 7TH ANNUAL RPT ON CARCIN, 1997: KNOWN TO BE CARCINOGE NIC. HUMAN:LUNG. Effects of Overexposure:HLTH HAZ: (INCL EMBRYOTOX EFTS). SYMPS INCL ABDOM DISCOMFORT/PAIN, CONSTIP, LOSS OF APPETITE, METALLIC TASTE, NAUS, INSOMNIA, NERV IRRITABILITY, WEAK, MUSCLE & JOINT PAINS, HDCH & DIZZ. CHROMATES AR E LISTED BY IARC & NTP. ALTHOUGH STUDIES HAVE ASSOC EXPOS TO CHROMIUM VI CMPDS W/INCRD RISK OF RESP CANCER, AVAIL EVIDENCE INDICATES THAT LEAD CHROMATE (CHROME YELLOW, MOLYBDATE ORANGE)/LEAD SULFATE DOES NOT PRESENT THIS HAZ.PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, CARDIOVASCULAR, BLOOD-FORMING, & REPRO SYS. (SUP DAT) Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC RESPIRATORY AND/OR SKIN REACTION IN SUSCEPTIBLE PERSONS OR SENSITIZATION. THIS EFFECT MAY BE DELAYED SEVERAL HOURS AFTER EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: IF ANY BREATHING PROBLEMS OCCUR DURING USE, LEAVE THE AREA AND GET FRESH AIR. IF PROBLEMS REMAIN OR OCCUR LATER, IMMEDIATELY GET MEDICAL ATTENTION.SKIN: WASH AFFECTED AREA THOROUGHLY WI TH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:=-4.4C, 24.F Lower Limits:1.0% Upper Limits:13.1% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSUR E BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLOSED CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PREC. DURING EM ER CONDITIONS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPTOMS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTENTION. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. IF CATALYST IS SPILLED, ALL PERSONNEL IN AREA SHOULD BE PROTECTED AS IN CONTROL MEASURES SECTION. COVER SPILL W/ABSORBENT MATL. DEACTIVATE SPILLED MATERIAL W/10% AMMONIUM HYDROXIDE SOLUTION (HOUSEHOLD AMMONIA). AFTER 10 MINUTES, COLLECT IN OPEN CONTAINERS & ADD MORE AMMONIA. COVER LOOSELY. WASH SPILL AREA W/SOAP & WATER. Neutralizing Agent:10% AMMONIUM HYDROXIDE SOLUTION (HOUSEHOLD AMMONIA). ======================Handling and Storage ====================== Handling and Storage Precautions:NO PERS SHOULD USE THESE PRODS/BE IN AREA WHERE THEY ARE BEING USED, IF THEY HAVE CHRONIC (LONG-TERM) LUNG/BRTHG PROBLEMS/IF THEY EVER HAD A RXN TO ISOCYANATES.BEFORE INITIAL USE OF LEAD-CONTAINING COLORS, CONSULT OSHA'S STD FOR OCCUP EXPOS TO LEAD (29 CFR 1910.1025). USE ONLY W/ADEQ VENT. Other Precautions:AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. THESE COATINGS MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS DUST" IN ING SECTION) WHICH MAY BE PRESENT AT HAZ LEVELS ONLYDURING SANDING/ABRADING OF DRIED FILM. CONTENTS ARE FLAM. KEEP AWAY FROM HEAT, SPKS, & OPEN FLAME. (OTHER INFO) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE OVERSPRAY IS PRESENT, A POS PRESS AIR SUPP RESP (TC19C NIOSH APPRVD) SHOULD BE WORN. IF UNAVAIL, A PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH MAY BE EFFECTIVE. FOLLOW RESP MFR'S DIRECTIONS FOR USE. WEAR RESP FOR WHOLE TIME OF SPRAYING & UNTIL ALL VAPS & MISTS ARE GONE. (ECOLOGICAL INFO) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94, 1910.107, 1910.108. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . USE BARRIER CREAM ON EXPOSED SKIN. Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health SIGNS & SYMPS OF OVEREXP: PERS SENSITIVE TO ISOCYANATES WILL EXPERIENCE INCRD ALLERGIC RXN ON RPTD EXPOS. METHYL ETHYL KETONE MAY INCR NERV SYS EFTS OF OTHER SOLVS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT ATTAINABLE IN WORKPLACE. (OTHER INFO) ================== Physical/Chemical Properties ================== Boiling Pt:>72.8C, 163.F B.P. Text:163-393F Vapor Pres:SEE INGREDIENTS Vapor Density:HVR/AIR Spec Gravity:0.89-1.41 VOC Grams/Liter:4.1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:53-98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALLICS CONTAIN ALUMINUM. CONTAM W/WATER, ACIDS/ALKALIS CAN CAUSE EVOLUTION OF HYDROGEN, WHICH MAY RSLT IN DANGEROUSLY INCRD PRESS IN CLSD CONTRS. CONTAM OF CATALYST W/WATER, ALCOHOLS, AMINES, & OTHER CMPDS WHICH REACT Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS IN INGREDIENTS SECTION. =================== Toxicological Information=================== Toxicological Information:OTHER INFO: KEEP CONTR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CONTRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. DO NOT APPLY LEAD-CONTAINING COLORS ON TOYS/OTHER CHILDREN'S ARTICLES, FURNITURE/ANY INTERIOR SURF OF A DWELLING/FACILITY WHICH MAY BE OCCUPIED/USED BY CHILDREN.DO NOT APPLY ON ANY EXTERIOR SURF OF DWELLING UNITS, SUCH AS WINDOW SILL S, PORCHES, STAIRS/RAILINGS TO WHICH CHILDREN MAY BE COMMONLY EXPOSED. THESE PRODS MAY BE MIXED W/OTHER COMPONENTS BEFORE USE. BEFORE OPENING PACKAGES, READ & FOLLOW WARNING LABELS ON ALL COMPONENTS . (ECOLOGICAL INFO) ===================== Ecological Information ===================== Ecological:TOX INFO: INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL/FATAL. RESP PROT: NO PERS SHOULD BE ALLOWED IN AREA WHERE THESE PRODS ARE BEING USED UNLESS EQUIPPED W/SAME RESP PROT REC FOR PAINTERS. WHEN SANDING, WIREBRUSHING, ABRADING, BURNING/WELDING DRIED FILM, WEAR PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST NON-VOLAT MATLS IN INGS SECTION.VOC: 4.1-5.1 LBS/GAL . MATLS TO AVOID: ISOCYANATES, MAY RSLT IN DANGEROUS PRESS IN, & POSS BURSTING OF, CLOSED CONTRS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS.WASTE FROM PRODS CONTAINING LEAD/CHROMIUM MUST ALSO BE TESTED FOREXTRACTABILITY. WASTE FROM PRODS CONTAINING METHYL ETHYL KETONE MAY ALSO REQUIRE TESTING FOR EXTRAC TABILITY. (OTHER INFO) =================== MSDS Transport Information =================== Transport Information:DOL STORAGE CATEGORY - 1B. ===================== Regulatory Information ===================== SARA Title III Information:LEAD COMPOUND AND CHROMIUM COMPOUND ARE SUBJECT TO THE REPORTING REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) SECTION 313, 40 CFR 372.65 C. Federal Regulatory Information:ALL CHEMICALS IN THESE PRODUCTS ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY. State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PST-525, SILICONE GREASE CAGE:03CA3 Contract Num:SP0450-00-D-4037 CAGE:03CA3 ============= Composition/Information on Ingredients ============= Ingred Name:DIMETHYLPOLYSILOXANE CAS:63148-62-9 RTECS #:JT6484500 Minumum % Wt:75. Maxumum % Wt:95. Ingred Name:SILICA, AMORPHOUS CAS:112945-52-5 RTECS #:VV7310000 Minumum % Wt:5. Maxumum % Wt:25. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY. Health Hazards Acute and Chronic:EYES: CONTACT WITH EYES MAY CAUSE REDNESS. SKIN: CONTACT WITH SKIN CAUSES NO KNOWN IRRITATION. Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY. Effects of Overexposure:EYES:REDNESS. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH EYES WITH COPIOUS AMOUNTS OF WATER FOR 15 MINUTES. IF IRRITATION PERSISTS CONTACT A PHYSICIAN. SKIN: WASH CONTACTED AREAS WITH SOAP AND WATER. INGESTION: IF INGESTED, SEEK PROMPT MEDICAL A TTENTION. DO NOT INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point:>93.3C, 200.F Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL (SMALL FIRES), FOAM, OR WATER SPRAY. Fire Fighting Procedures:NO DATA PROVIDED BY RESPONSIBLE PARTY. Unusual Fire/Explosion Hazard:NO DATA PROVIDED BY RESPONSIBLE PARTY. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT MATERIALS TO COLLECT AND CONTAIN MATERIAL FOR DISPOSAL. RECOMMENDATION FOR DISPOSAL. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TEMPERATURES BELOW 100F. Other Precautions:NO SPECIAL REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO DATA PROVIDED BY RESPONSIBLE PARTY. Ventilation:NOT REQUIRED. Other Protective Equipment:NO DATA PROVIDED BY RESPONSIBLE PARTY. Work Hygienic Practices:NO DATA PROVIDED BY RESPONSIBLE PARTY. Supplemental Safety and Health NO DATA PROVIDED BY RESPONSIBLE PARTY. ================== Physical/Chemical Properties ================== HCC:V5 Boiling Pt:>300.C, 572.F Vapor Pres:<5 MM HG @ 25C Vapor Density:>1 Spec Gravity:>1.0 pH:NEUTRAL Solubility in Water:INSOLUBLE Appearance and Odor:TRANSLUSCENT PASTE. Percent Volatiles by Volume:<1.5 ================= Stability and Reactivity Data ================= NO DATA PROVIDED BY RESPONSIBLE PARTY. Stability Condition to Avoid:NO DATA PROVIDED BY RESPONSIBLE PARTY. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, SILICON DIOXIDE. =================== Toxicological Information=================== Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT & IATA: NON-HAZARDOUS. ===================== Regulatory Information ===================== SARA Title III Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. Federal Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYSOL PC 12-007 M,PART A Kit Part:Y CAGE:04347 CAGE:04347 ============= Composition/Information on Ingredients ============= Ingred Name:BISPHENOL A-EPICHLOROHYDRIN COPOLYMER CAS:25068-38-6 RTECS #:SL6475000 Fraction by Wt: 60 - 95% Other REC Limits:NONE RECOMMENDED Ingred Name:N-BUTYL GLYCIDYL ETHER (BGE) CAS:2426-08-6 RTECS #:TX4200000 Fraction by Wt: 5 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:25 PPM; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACT. ACUTE- INHALE:HARMFUL IF INHALED. MAY CAUSE ALLERGIC RESPIRATORY REACTION SUCH AS ASTHMA. EYE:MAY CAUSE IRRITATION. SKIN:PROLONGED/REPEATED CONTACT MA Y CAUSE IRRITATION. ORAL:MODERATELY TOXIC. HARMFUL IF SWALLOWED. MAY CAUSE VOMITING. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, NAUSEA, HEADACHE, VOMITING, DIARRHEA, TEARING, DIFFICULT BREATHING, ASTHMA Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT IN DUCE VOMITING. IF CONSCIOUS, RINSE MOUTHWITH WATER. SEEK PROMPT MEDICAL ATTENTION. IF SPONTANEOUS VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF VOMITUS INTO LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:155F,68C Extinguishing Media:WATER FOG, CARBON DIOXIDE, SAND, FOAM/DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. PICK UP SPILL WITH NON-FLAMMABLE ABSORBENT MATERIAL SUCH AS SAND. PLACE IN CONTAINER FOR DISPOSAL. PREVENT LIQUID FROM ENTERIN G SEWERS, WATERWAYS. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL (<25C/77F), VENTILATED AREA AWAY FROM SOURCES OF IGNITION AND STRONG OXIDIZING AGENTS. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:AVOID BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. LAUNDER BEFORE REUSE. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A NIOSH-APPROVED RESPIRATOR MUST BE WORN. A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD29 CFR 1910.134. Ventilation:USE LOCAL EXHAUST VENTILATION. Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE LOCATED NEARBY. WEAR APPROPRIATE PROTECTIVE CLOTHING FOR RISK OF EXPOSURE. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health KEY1:F8. THIS PRODUCT IS A KIT CONSISTING OF TWO PARTS. PART A (EPOXY RESIN), HAS PNI A; PART B (URETHANE HARDENER) HAS PNI F, SAME NSN. FORMULA FOR PART B HAS CHANGED. SEE PNI B OR D, SAME NSN. ================== Physical/Chemical Properties ================== HCC:V5 NRC/State Lic Num:NOT RELEVANT Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN Vapor Pres:2.0 Vapor Density:3.8 Spec Gravity:1.1 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:INSOLUBLE Appearance and Odor:AMBER, MEDIUM VISCOSITY LIQUID, AROMATIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:EXCESSIVE HEAT, OPEN FLAMES Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, POSSIBLE ORGANIC COMPOUNDS. Conditions to Avoid Polymerization:EXOTHERMIC ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATION, REUSE OR RECYCLING IS RECOMMENDED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SEALED LEAD-ACID BATTERY CAGE:5P319 CAGE:05839 CAGE:S0293 CAGE:5P319 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 10-20% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LEAD DIOXIDES Fraction by Wt: 5-25% Other REC Limits:NONE RECOMMENDED Ingred Name:LEAD (SARA 313) (CERCLA) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 30-60% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1025 ACGIH TLV:0.05MG/M3, A3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:LEAD SULFATE (SARA 313) (CERCLA) CAS:7446-14-2 RTECS #:OG4375000 Fraction by Wt: 1-25% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15 MG(PB)/M3; 9596 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: WASH EYES/SKIN WITH WATER PROMPTLY AFTER CONTACT. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:UNKNON Extinguishing Media:WATER, FOG, FOAM, DRY CHEMICAL, CARBON DIOXIDE OR DRY SAND. Fire Fighting Procedures:N/A. Unusual Fire/Explosion Hazard:BATTERY IS NOT A HAZARD UNDER NORMAL USE. THERE IS NO HAZARD OF FIRE OR EXPLOSION UNLESS THE BATTERY IS ABUSED. ================== Accidental Release Measures ================== Spill Release Procedures:IF THE BATTERY IS ACCIDENTALLY BROKEN AND ELECTROYLTE LEAKS OUT, WIPE UP WITH CLOTH, NEUTRALIZE THE ACID WITH AN ALKALINE SUBSTANCE SUCH AS AMMONIUM SOLUTION AND BAKING POWDER. DO NOT SHORT CIRCUIT. Neutralizing Agent:AMMONIUM SOLUTION AND BAKING POWDER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:DO NOT USE VINYL CHLORIDE SHEATED WIRE OR A VINYL CHLORIDE SHEET, VINYL CHLORIDE MAY CRACK BATTERY CONTAINER OR COVER. ============= Exposure Controls/Personal Protection ============= Other Protective Equipment:ONLY NECESSARY IF BATTERY IS CRACKED OR DISASSEMBLED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health BATTERY IS AN ARTICLE ACCORDING TO A LETTER BY MR. CHARLES P. MONAHAN, ENVIRONMENTAL MANAGER, PANASONIC,DATED 7 JAN, 1998. DOES NOT REQUIRE MSDS. ================== Physical/Chemical Properties ================== HCC:N1 Viscosity:NA Appearance and Odor:6 VOLT/10 APH, SEALED BATTERY. ITEM IS AN ARTICLE AS DEFINED BY 29 CFR 1910.120 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT INCINERATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:XMF-B(CRONEX X-RAY MULTI-PROC FXR/REPL-PT B CAGE:18773 CAGE:18773 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM CHLORIDE CAS:7446-70-0 RTECS #:BD0525000 Fraction by Wt: <30% OSHA PEL:2 MG/M3 (AS AL) ACGIH TLV:2 MG/M3 (AS AL);8990 Ingred Name:ACETIC ACID (SARA III) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: <50% OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:GLUCONIC ACID; CAS #526-95-4 RTECS #:LZ5100000 Fraction by Wt: <10% Ingred Name:WATER; CAS #7732-18-5 CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== Effects of Overexposure:EYES/SKIN:BURNS;INHAL:CAN CAUSE SEV RESP IRRIT & DENTAL EROSION;INGEST:CAUSES GI CORROSION ======================= First Aid Measures ======================= First Aid:SKIN:WASH W.SOAP & H*2O. EYES:FLUSH W. H*2O. INGESTED:DON'T INDUCE VOMITING. INHALED:REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEED. KEEP WARM & QUIET. REMOVE CONTAMINATED CLOTHING. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER,WATER SPRAY/FOG,"ALCOHOL" FOAM,DRY CHEMICAL, CO*2. Fire Fighting Procedures:WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL CONTR. Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN UP. DIKE SPILL.PREVENT LIQUID FROM ENTERING SEWERS,WATERWAYS OR LOW AREAS.SOAK UP WITH SAWDUST,SAND,OIL DRY OR OTHER ABSORBENT MATERIAL.SPILL MAY BE NEUTRALIZED W/SODIUM CARBONATE BEFORE DISP ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED Other Precautions:KEEP AWAY FROM STRONG BASES,FOOD STUFF & SUNLIGHT/HEAT.USE ONLY WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN POORLY VENTLD AREA,USE CHEM CART RESP W/ORG VAP/ACID GAS CART Ventilation:NO SPECIAL REQUIREMENTS W ADEQUATE VENT. Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR PROLONGED CONTACT. Supplemental Safety and Health MSDS E-79659 FM MFR DATED 11/85, ITEM CRONEX X-RAY MULTI PROCESS FIXER/REPLENISHER PRT B IS TWO PRT PRODUCT THIS DESCRIBES PRT B SEE PNI A FOR OTHER PRT KEY1:J6 ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:>212F/>100C Spec Gravity:1.2 Solubility in Water:COMPLETE Appearance and Odor:LIGHT AMBER,CLEAR LIQ W/SLIGHT VINEGAR ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES. Stability Condition to Avoid:NOT KNOWN Hazardous Decomposition Products:NOT KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:RECOVER NONUSABLE FREE LIQ &/OR CONTMNTD WATER,& DISPOSE OF IN AN APPRVD & PERMITTD BIOLOGICAL TREATMNT SYSTEM/DEEPWELL.DISPOSE OF NONUSABLE SOLID MATL &/OR CONTMNTD SOIL IN AN APPROVD & PERMITTD LAND FILL.PRETREAT LIQ BEFORE DISCHARGING TOSEWER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:4394 LIGHTWEIGHT BODY FILLER CAGE:16522 CAGE:16522 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENE GLYCOL, MALEIC ANHYDRIDE, PHTHALIC ANHYDRIDE POLYMER*97-2* CAS:26123-45-5 Fraction by Wt: <35% Ingred Name:STYRENE, STYRENE MONOMER (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B) *97-2* CAS:100-42-5 RTECS #:WL3675000 Fraction by Wt: <18% EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM SILICATE (IARC - GROUP 3) *97-2* CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: <50% OSHA PEL:2 MG/CUM (RESP DUST) ACGIH TLV:2 MG/CUM (RESP DUST) Ingred Name:GLASS OXIDE, FIBER GLASS WOOL, LEAD BOROSILICATE GLASS ENAMEL FLUX CAS:65997-17-3 Fraction by Wt: <50% Ingred Name:VOLATILE ORGANIC CONTENT: 216 G/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: MAY CAUSE IRRITATION. INHALATION: VAPORS MAY CAUSE MUCOUS MEMBRANE & UPPER RESPIRATORY TRACT IRRITATION. REPEATED EXPOSURE TO HIGH CONCENTRATIONS OF VAPOR MAY CAUSE LIVER & KIDNEY DAMAGE. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, DISCOMFORT. Medical Cond Aggravated by Exposure:INDIVIDUALS W/CHRONIC RESPIRATORY CONDITIONS (ASTHMA, CHRONIC BRONCHITIS, EMPHYSEMA). ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN AL L CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:90F (SEE SUPP) Lower Limits:1.1 Upper Limits:6.1 Extinguishing Media:SMALL FIRES: CO2, DRY CHEMICAL. LARGE FIRES: FOAM, WATER FOG. Fire Fighting Procedures:DENSE SMOKE SERIOUSLY LIMITS VISIBILITY. VENT SMOKE & USE GAS MASK/REMOTE AIR SUPPLY. WEAR MSHA/NIOSH APPROVED SCBA W/PROTECTIVE EQUIPMENT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. INCREASE VENITLATION TO MAXIMIZE VAPOR DISPERSAL. DIKE TO PREVENT RUNOOF INTO SEWERS/WATERWAYS. MATERIAL MAY BE REMOVED BY SHOVELING, WIPING. SWEEP/CLEAN W/INERT MATERIALS & PLACE IN CLOSED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA. DON'T STORE IN DIRECT SUNLIGHT. USE W/ADEQUATE GENERAL & LOCAL EXHAUST VENTILATION TO MINIMIZE EXPOSURE TO VAPORS. Other Precautions:BOND & GROUND CONTAINERS FOR TRANSFER OF PRODUCT TO PREVENT STATIC SPARKS. AVOID PROLONGED/REPEATED CONTACT W/SKIN & EYE CONTACT. STYRENE VAPORS ARE UNIHIBITED & MAY CAUSE BLOCKAGE OF VENTILATION VENT S DUETO POLYMERIZATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR/DUST RESPIRATOR TO AVOID INHALATION OF EXCESSIVE AIR CONTAMINANTS. Ventilation:LOCAL EXHAUST SHOULD BE USED TO CONTROL THE EMISSION OF AIR CONTAMINANTS. GENERAL DILUTION MAY REDUCE AIR CONCENTRATIONS Other Protective Equipment:SAFETY SHOWERS & EYE WASH STATIONS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. CLEAN HANDS W/SOAP & WATER AFTER EVERY USAGE. Supplemental Safety and Health THE PHYSICAL DATA INFORMATION IS FOR STYRENE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:293F(SUPP) Vapor Pres:5.2(SUPP) Vapor Density:3.6(SUPP) Spec Gravity:1.05-1.35 Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE PASTE W/STYRENE ODOR Percent Volatiles by Volume:18 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, PEROXIDES, OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAME. Hazardous Decomposition Products:CO, CO2, HYDROCARBONS, ORGANIC ACIDS. Conditions to Avoid Polymerization:UNREGULATED CONTACT W/ORGANIC PEROXIDES, EXPOSURE TO HEAT, OPEN FLAME & PROLONGED STORAGE >100F. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. IF DISCARDED, MATERIAL & CONTAINERS ARE CONSIDERED RCRA HAZARDOUS WASTES BASED ON THE CHARACTERISTIC OF IGNITABILITY. UN1866.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:R-27705-1 CONTACT ADHESIVE Resp. Party Other MSDS Num.:PRODUCT CODE 27705 Preparer's Name:CAROL N. BUSH CAGE:1D2U1 CAGE:1D2U1 CAGE:30150 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 = Wt:16. Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-HEXANE CAS:110-54-3 RTECS #:MN9275000 = Wt:19. Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CYCLOHEXANE CAS:110-82-7 RTECS #:GU6300000 = Wt:1. Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:400 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-METHYLPENTANE CAS:107-83-5 RTECS #:SA2985000 = Wt:10. Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:400 PPM Ingred Name:3-METHYLPENTANE CAS:96-14-0 = Wt:10. Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:400 PPM Ingred Name:MEK CAS:78-93-3 RTECS #:EL6475000 = Wt:28. Other REC Limits:NONE RECOMMENDED OSHA PEL:590 MG/M3;200 PPM ACGIH TLV:590 MG/M3;200 PPM ACGIH STEL:885 MG/M3;300 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, CNS, BRAIN, LIVER, KIDNEYS, LUNG. ACUTE - MAY CAUSE SEVERE EYE IRRITATION, TEARING AND BLURRED VISION. SKIN CONTACT CAN DRY AND DEFAT SKIN CAUSING CRACKS, IRRITATION, AND DE RMATITIS. CAN BE ABSORBED THROUGH SKIN.HARMFUL IF INGESTED. ASPIRATION HAZARD. CAN CAUSE GASTROINTESTINAL IRRITATION, VOMITING, AND DIARRHEA. CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CA USE BIRTH DEFECTS. INHALATION CAUSES IRRITATION, DIZZINESS, HEADACHE, BREATHING DIFFICULTY, AND LOSS OF COORDINATION. CHRONIC - MAY CAUSE LIVER, KIDNEYS EFFECTS, DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SEVERE IRRITATION, NAUSEA, VOMITING, TEARING, BLURRED VISION, DRY SKIN, HEADACHE, LOSS OF COORDINATION Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED CENTRAL NERVOUS SYSTEM, LIVER, KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICAL RESPIRATION IF NOT BREATHING. IF BREATHING IS DIFFICULT, OXYGEN MAY BE GIVEN BY QUALIFIED PERSONNEL. EYE CONTACT: IMMEDIATELY FLU SH WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. SKIN: WASH WITH SOAP AND PLENTY OF WATER. INGESTION: DO NOT INDUCE VOMITING. CAN CAUSE CHEMICAL PNEUMONITIS. IF VOMITING OCCURS, KEEP HEAD BEL OW HIPS. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=-28.9C, -20.F Lower Limits:1.0 % Upper Limits:11.0 % Extinguishing Media:FOAM, C02, DRY CHEMICAL Fire Fighting Procedures:REPSIRATORY EQUIPMENT SHOULD BE WORN TO AVOID INHALATION OF CONCENTRATED VAPERS. WATER SHOULD NOT BE USED EXCEPT AS FOG TO KEEP NEARBY CONTAINERS COOL. Unusual Fire/Explosion Hazard:HANDLE AS FLAMMABLE LIQUID. VAPORS FORM AN EXPLOSIVE MIXTURE IN AIR BETWEEN THE UPPER AND LOWER LIMITS WHICH CAN BE IGNITED BY MANY SOURCES SUCH AS POLOT LIGHTS, OPEN FLAMES, ELECTRICAL MOTORS AND SWI TCHES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. DO NOT WALK THROUGH SPILL; STOP SPILL IF POSSIBLE. USE A VAPOR SUPPRESSING FOAM TO REDUCE VAPORS. CONTAIN AND PICK UP WITH NON -FLAMMABLE ABSORBENT SUCH AS SAND, VERMICULITE. GROUND ALL HANDLING EQUIPMENTS. PREVENT LIQUID FROM ENTERING SEWERS, WATERWAYS, CONFINED SPACES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM IGNITION SOURCES, AND INCOMPATIBLES. KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:AVOID BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. LAUNDER BEFORE REUSE. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF TLV IS EXCEEDED OR FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR OR AIR-PURIFYING RESPIRATOR. IN EMERGENCY OR CONFINED SPACES, WEAR A NIOSH-APP ROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS OR A FRESH-AIR SUPPLING RESPIRATOR.. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:EYE BATH, WASHING FACILITY, EMERGENCY SHOWER, LAB COAT OR UNIFORM. THE USE OF HEAD CAPS WHENEVER POSSIBLE IS STRONGLY RECOMMENDED. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=61.1C, 142.F B.P. Text:142 TO 231 DEG F Vapor Density:> AIR Spec Gravity:0.8 (H20=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NO Appearance and Odor:BLACK AND OFFENSIVE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG ALKALIES Stability Condition to Avoid:EXCESSIVE HEAT, POOR VENTILATION, CORROSIVE ATMOSPHERE, EXCESSIVE AGING, SPARKS, OPEN FLAMES, HOT SURFACES, STATIC ELECTRICITY AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES AND POSSIBLE ACROLEIN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DISPOSE OF IN AN APPROVED HAZARDOUS WASTE LANDFILLS, OR AN APPROVED INCINERATOR OR CONTRACT WITH A LICENSED WASTE DISPOSAL SERVICE. RECYCLING, REUSING OR BURNING FOR ENERGYRECOVERY IS RECOMMENDED.
1
eyes_protection_mandatory
======================================================= Product ID: SILVER-COPPER-PHOSPHOROUS BRAZING ALLOYS, SIL-FOS 1 Cage: 91874 Box: 638 ======================================================= Contractor Summary ======================================================= Cage: 91874 ======================================================= Ingredients ======================================================= Cas: 7440-50-8 RTECS #: GL5325000 % Wt: >75 OSHA PEL: 0.1MG/M3 FUME/1 DUST ACGIH TLV: 0.2 MG/M3 FUME EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 7723-14-0 RTECS #: TH3500000 % Wt: 5-7.25 OSHA PEL: 0.1 MG/M3 ACGIH TLV: 0.02 PPM EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 7440-22-4 RTECS #: VW3500000 % Wt: 0.9-18 OSHA PEL: 0.01 MG/M3 ACGIH TLV: 0.1 MG/M3 EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ & DIARR. CHRONIC:INHAL:SILVER:MAY PRDCE ----------------------------- & RESP TRACT. COPPER:MAY CAUSE DMG TO LIVER, ----------------------------- LIVER, KIDNEY, SPLEEN, PANCREAS, SKELETAL SYS & BRAIN. ----------------------------- CUTTING" (AMERICAN WELDING SOCIETY, MIAMI, FL 33135). ----------------------------- ----------------------------- Other REC Limits: NONE RECOMMENDED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHAL:COPPER:ACUTE EXPOS MAY CAUSE RESP TRACT IRRIT, FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAKNESS & METALLIC TASTE. PHOSPHORUS:STABLE & RELATIVELY NON-TOX AT ROOM TEMP. WHEN HEATED IN PRESENCE OF AIR, IT IS CONVERTED TO PHOSPHORUS PENTOXIDE, WHICH IS CORR & IRRIT TO EYES, NOSE, THROAT & MUC MEMBS. (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZS:SKIN:CONT W/MATL IN SOLID FORMS IS NOT KNOWN TO BE HAZ. IN POWDERED FORM, MAY PRDCE LOCALIZED IRRIT, LOCALIZED ARGYRIA (FROM SILVER), & OR DISCOLORATION & CONT DERM (FROM COPPER). EYES:IN PO WDERED FORM MAY PRDCE LOCALIZED ARGYRIA, IRRIT, CONJUNCT, & ULCERATION OF CORNEA. INGEST:IN FINELY-DIVIDED FORM Medical Cond Aggravated By Exposure: PRE-EXISTING PULMONARY DISEASES (E.G., BRONCHITIS, EMPHYSEMA) MAY BE AGGRAVATED BY INHALATION EXPOSURE TO THIS MATERIAL, PARTICULARLY AS FUME. First Aid: INHAL:REMOVE FROM CONTAM AREA, ADMIN OXYG, & SEEK MED ATTN. KEEP WARM & AT REST. PERFORM ARTF RESP IF BRTHG HAS STOPPED. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED AREA W/LG QTYS OF WATER FOR AT LST 15 M IN. SEEK MED ATTN IF NEC. EYES:FLUSH AFFECTED AREAS W/WATER FOR AT LST 15 MIN. SEEK MED ATTN IF NEC. INGEST:IF CONSCIOUS, INDUCE VOMIT. IF UNCON/CONVULSIVE, SEEK IMMED MED ASSISTANCE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: CLEAN UP SPILLED MATL SO AS TO MIN DISPERSION OF DUST. WET SWEEPING/VACUUMING USING HEPA FILTRATION ARE RECOM METHODS. RQ'S OF COMPONENT MATLS UNDER SARA TITLE III, SECTION 313 ARE AS FOLLOWS:SILVER:1 000 LBS, PHOSPHOROUS:1 LB, COPPER:5000 LBS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS (FP N). RETURN TO MANUFACTURER OR RECLAIM. Handling And Storage Precautions: DO NOT STORE AT HIGHLY-ELEVATED TEMPS/IN PROXIMITY TO INCOMPATIBLE MATLS (SEE REACTIVITY DATA). AVOID FLAMMABLE FABRICS. Other Precautions: BRAZING ALLOYS MAY BE USED W/SEPARATELY-APPLIED FLUX WHICH, WHEN HEATED, MAY EMIT IRRIT &/OR TOX GASES & FUMES. CONSULT MSDS FOR SPEC FLUX IN USE TO DETERM ITS HAZS & APPROP PROT MEASURES. FOR GEN GUI DANCE, REFER TO AMERICAN NATL ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE DRY POWDER. DO NOT USE WATER. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: IN FINELY-DIVIDED FORM, THIS MATL MAY IGNITE WHEN EXPOSED TO FLAME/BY RXN W/INCOMPATIBLE MATLS (SEE REACTIVITY DATA FOR INCOMPATIBLE MATLS). FIRES/EXPLO(SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: IF EXPOSURE LEVELS EXCEED THE OSHA PEL, WEAR A NIOSH/MSHA APPROVED RESPIRATOR HAVING A PROTECTION FACTOR APPROPRIATE TO THE AIRBORNE CONCENTRATIONS OF THE CONTAMINANTS GENERATED. Ventilation: USE MECH LOC EXHST VENT ADEQ TO MAINTAIN AIRBORNE CONCS OF ALL COMPONENTS & THEIR DECOMP PRODS TO W/IN THEIR Other Protective Equipment: EMER EYE BATH & DELUGE SHOWER WHICH MEETS ANSI DESIGN CRITERIA (FP N). APPROP PROT CLTHG TO PVNT SKIN INJURIES (SUPDAT) Work Hygienic Practices: TO AVOID INGEST OF MATL, WASH HANDS & FACE BEFORE EATING, DRINKING, OR CONSUMPTION OF TOBACCO. Supplemental Safety and Health: EXPLO HAZS:INVOLVING MATL MAY RELS POTNTLY TOX EMISSIONS OF METAL, METAL OXIDE, & PHOSPHORUS FUMES (SEE INGS FOR HAZ COMPONENTS & DECOMP PRODS). MATL TO AVOID:PEROXYFORMIC ACID; F*2; PERMONOSULFURIC A CID; CHLORATES; CS*2; SEOCL; SEOF; SEF*4; BROMATES; IODATES. OTHER PROT EQUIP:FROM HAZS OF BRAZING &/OR FOR ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: 1190F,643C Spec Gravity: 7.86-8.44 Solubility in Water: INSOLUBLE Appearance and Odor: LIGHT-COPPER METAL IN FORM OF WIRE, ROD, STRIP, POWDER OR PREFORMED SHAPES. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: STABLE AT ROOM TEMPERATURE. Materials To Avoid: ACETYLENE; NH*3; HNO*3; AZIDES; ETHANOL; ETHYLENE IMINE; MG; CF*3; CL*2; CLO*2; CLO; INORG & ORG PEROXIDES; (SUPP DATA) Hazardous Decomposition Products: HEATING AT BRAZING TEMPS MAY LIBERATE OXIDES OF METALS & PHOSPHORUS (FOR SPEC HAZ COMPONENTS & DECOMP PRODS, SEE INGS). Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SILVER-COPPER-PHOSPHOROUS BRAZING ALLOYS, SIL-FOS 1 Cage: 91874 Company Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO Street: 5656 SOUTH PENNSYLVANIA AVENUE Zipcode: 53110 Label Required IND: Y Date Of Label Review: 04/07/1995 Status Code: C Label Date: 04/07/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:INHAL:MAY CAUSE RESP TRACT IRRIT, FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAKNESS & METALLIC TASTE. PHOSPHORUS PENTOXIDE IS CORR & IRRIT TO EYES, NOSE, THROAT & MUC MEMBS. SKIN:IN POWDERED FORM, MAY PRODUCE LOCALIZED IRRIT, LOCALIZED ARGYRIA (FROM SILVER), AND/OR DISCOLORATION & CONT DERM (FROM COPPER). EYES:IN POWDERED FORM MAY PRODUCE LOCALIZED ARGYRIA, IRRIT, CONJUNCT & ULCERATION OF CORNEA. INGEST:IN FINELY-DIVIDED FORM MAY PRDCE GASTRIC IRRIT, VOMIT, ABDOM PAIN, HEMORRHAGE & DIARR. CHRONIC:SILVER:MAY PRDCE ARGYRIA, PERM BLUE-GRAY DISCOLORATION OF SKIN, EYES, MUCOUS MEMBRANES AND RESPIRA TORY TRACT. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BLUE GREASE, 90993 Preparer's Name:G.F.S. CAGE:18399 CAGE:18399 ============= Composition/Information on Ingredients ============= Ingred Name:ANTIMONY DIALKYLDITHIO-CARBAMATE CAS:15890-25-2 Fraction by Wt: 2% OSHA PEL:0.5 MG/M3 (SB) ACGIH TLV:0.5 MG/M3 (SB) Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED HEAVY NAPHTHENIC; (PETROLEUM OIL) CAS:64742-52-5 RTECS #:PY8035000 Fraction by Wt: >86% OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) >13000 MG/KG Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: YES, EYE IRRIT. CHRONIC: YES, SKIN IRRITATION. NONE EXPECTED ULESS PERS IS HYPERSINSITIVE TO APRON TO AVOID CONTACT. CAUSES E YE IRRITATION. MAY CAUSE SKIN & LIVER DMG W/CHRONIC EXPOS, PROLONGED CONTACT, OR INJECTION FROM HIGH PRESS GUN. Explanation of Carcinogenicity:MINERAL OIL:IARC GROUP 1. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL MD. SKIN: WASH THOROUGHLY WITH PLENTY OF WATER & SOAP. INHAL: IF AFFECTED, REMOVE TO FRESH AIR. INGEST: SEEK PHYSICIAN IMMEDI ATELY, SHOW MSDS OR LABEL, DO NOT INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point:450F,232C Extinguishing Media:WATER, FOG, FOAM, DRY CHEMICAL, CO*2. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROT EQUIP . TREAT AS A PETROLEUM FIRE. Unusual Fire/Explosion Hazard:WILL NOT FLASH SPONTANEOUSLY, MAY IGNITE IF EXPOSED TO OPEN FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP WITH ABSORBENT MATERIAL. DISPOSE OF AS A NON-HAZARDOUS WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WASH THOROUGHLY AFTER USING. ALWAYS READ AND FOLLOW DIRECTIONS ON PRODUCT LABEL. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ADDITIONAL TECHNICAL DATA SHEETS AND/OR MSDS ARE AVAILABLE UPON REQUEST. FOR PROFESSIONAL AND INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ONLY WITH ADEQUATE VENTILATION. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH THOROUGHLY AFTER USING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:680F,360C Spec Gravity:0.89 Solubility in Water:INSOLUBLE Appearance and Odor:BLUE PASTE, PETROLEUM LUBRICANT ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO Hazardous Decomposition Products:BY COMBUSTION: CO, CO*2, SBO*X, S, N*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTES IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDROBROMIC ACID POTASSIUM SALT, 4907 CAGE:DO242 CAGE:63612 CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM BROMIDE CAS:7758-02-3 RTECS #:TS7650000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE IRRITATION ON CONTACT WITH SKIN, EYES OR MUCOUS MEMBRANES. DUST INHALATION MAY BE IRRITATING TO RESPIRATORY SYSTEM. PROLONGED INHALATION CAN CAUSE BRONCHITIS. INGESTION CAN CAUSE NAUSEA, VOM ITING AND DEPRESSION. RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO DUST. TESTS ON LABORATORY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS:ANIMALS INDICATE MATERIAL MAY PRODUCE ADVERSE MUTAGENIC EFFECTS. Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. EYES:IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. SKIN:WASH THOROUGHLY WITH SOAP AND WATER. INHALATION:REMOVE TO FRESH AIR; GI VE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGESTION:IF CONSCIOUS, DRINK WATER AND INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERS. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Extinguishing Media:USE ANY SUITABLE FOR ADJACENT MATERIALS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE PROT EQUIP LISTED UNDER CTL MEASURES. ELIM ANY IGNIT SOURCES UNTIL AREA IS DETERM TO BE FREE FROM EXPLO/FIRE HAZS. CNTN RELS & ELIM ITS SOURCE, IF THIS C AN BE DONE W/OUT RISK. TAKE UP & (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE AT CONTROLLED ROOM TEMPERATURE. DO NOT BREATHE DUST. DO NOT GET IN EYES. AVOID PROLONGED OR REPEATED SKIN CONTACT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. Supplemental Safety and Health SPILL PROC:CONTAINERIZE FOR PROPER DISPOSAL AS DESCRIBED UNDER DISPOSAL. COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS ON PREVENT SKIN CONTACT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:2516F,1380C Melt/Freeze Pt:M.P/F.P Text:1346F,730C Spec Gravity:2.75 (H*2O=1) Solubility in Water:53% Appearance and Odor:WHITE CRYSTALS OR GRANULES, ODORLESS. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, OXIDIZERS. Stability Condition to Avoid:DUSTING. Hazardous Decomposition Products:BROMINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL DOES NOT HAVE AN EPA WASTE NUMBER AND IS NOT LISTED WASTE. HOWEVER CONSULTATION W/PERMITTED WASTE DISP SITE (TSD) SHOULD BE ACCOMPLISHED. ALWAYS CONT PERMITTED TSD TO ASSURE COMPLIANCE W/ALL CURRENT LOC, STATE & FED REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1 PROPANOL 99+% 19780, A414 1 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:N-PROPYL ALCOHOL CAS:71-23-8 RTECS #:UH8225000 Fraction by Wt: >99% OSHA PEL:200 PPM ACGIH TLV:S,200PPM/250STEL; 95 Ingred Name:SUPDAT: IF BRTHG IS DFCLT, GIVE OXYGEN. GET MEDICAL AID. NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY & SUPPORTIVELY. RTECS #:9999999ZZ Ingred Name:OTHER PREC: STORE IN A COOL, DRY PLACE. STORE IN A TIGHTLY CLOSED CNTNR. KEEP FROM CNTCT W/OXIDIZING MATLS. FLAMM-AREA. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: GM/KG/81 WEEKS. 1-PROPANOL CAUSED LIVER TUMORS & LEUKEMIA ACCRD TO RTECS CRITERIA. REPROD (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: EFTS: AN EXPOS OF 7000 PPM/7 HRS CAUSED A REDUCTION IN FERTITLY IN MALE RATS & CAUSED FETOTOXIC EFTS. (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: A DOSE OF 1000 PPM/7 HOURS CAUSED MUSCULOSKELETAL ABNORMALITIES AND POST - IMPLANTATION MORTALITY. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 6800 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE MOD IRRIT. MAY RSLT IN CORNEAL INJURY. SKIN: MAY CAUSE MOD SKIN IRRIT. PRLNG &/RPTD CNTCT MAY CAUSE DEFAT OF SKIN & DERM. INGEST: MAY CAUSE GI IRRIT W/NAUS, VOMIT & DIARR. MAY CA USE CNS DEPRESS, CHARACTERIZED BY EXCITEMENT, FOLLOW BY HDCH, DIZZ, DROW, & NAUS. ADVANCES STAGES MAY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: CAUSE COLLAPSE, UNCONSCIOUSNESS, COMA & POSS DEATH DUE TO RESP FAILURE. INHAL: INHAL OF VAP MAY CAUSE RESP TRACT IRRIT. MAY CAUSE EFTS SIMILAR TO THOSE DESCRIBED FOR INGESTION. CHRONIC: PRLN G/RPTD SKIN CNTCT MAY CAUSE DEFAT & DERM. CHRONIC EXPOS MAY CAUSE LIVER DAMAGE. EPIDEMIOLOGY: ORAL RAT TDLO=50 (ING 4) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH W/PLENTY OF H*2O FOR AT LEAST 15 MIN, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: GET MED AID. FLUSH W/PLENTY OF SOAP & H*2O FOR AT LEAST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOES. INGEST: DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. GET MED AID. INHAL: REMOVE FROM EXPOS (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:59.0F,15.0C Lower Limits:2.00 VOL% Upper Limits:12.00 VOL % Extinguishing Media:USE H*2O SPRAY TO COOL FIRE-EXPOSED CNTNRS. USE DRY CHEM, CO*2/ALCOHOL-RESIST FOAM. DO NOT USE STRAIGHT STREAMS OF H*2O. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . CNTNRS CAN BUILD UP PRESS IF EXPOSED TO HEAT &/FIRE. COMBUST GENERATES TOX FUMES. DURING A FIRE, IRRIT (SUPDAT) Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SPILL W/INERT MATERIAL, (EG, DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. USE WATER SPRAY TO DISPERSE THE GAS/VAPOR. REMOVE ALL SOURCES OF IGNITION. PROVIDE VENTILATION. USE PROPER PERS PROT EQUIP AS INDICATED IN SECTION 8. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE WITH ADEQUATE VENT. USE SPARK-PROOF TOOLS & EXPLOSION PROOF EQUIP. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE, (LIQ &/VAP), & CAN BE DANGEROUS. Other Precautions:DO NOT GET ON SKIN/IN EYES. DO NOT INGEST/INHALE. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY CNTNS TO HEAT, SPARKS/OPEN FLAMES. KEEP AWAY FROM HEAT, SPARKS, & FLAME. DO NOT STORE NEAR COMBUST MATLS. (ING 3) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS AND APPROVED BY NIOSH MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENT TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPLOSURE LIMITS. Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT W/SKIN. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health FIRE FIGHT PROC: & HIGHLY TOX GASES MAY BE GENERATED BY THERMAL DECOMP/COMBUST. FLAMM LIQ. CAN RELS VAPS THAT FORM EXPLOSIVE MIX AT TEMPS ABOVE FLASHPOINT. VAP MAY BE HEAVIER THAN AIR. THEY CAN SPREAD ALONG GROUND & COLLECT IN LOW/CONFINEDAREAS. FIRST AID PROC: TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:207F,97C Melt/Freeze Pt:M.P/F.P Text:-197F,-127C Vapor Pres:14.3 @ 20C Vapor Density:2.07 Spec Gravity:0.8040 G/CM3 Evaporation Rate & Reference:1.3 (BUTYL ACETATE = 1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; ALCOHOL-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACID CHLORIDES, ACID ANHYDRIDES, OXIDIZING AGENTS, POTASSIUM TERT-BUTOXIDE. Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SIKAFLEX 15LM WHITE, 440 CAGE:0PMN0 CAGE:0PMN0 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CARBONATE; (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM OXIDE CAS:1305-78-8 RTECS #:EW3100000 OSHA PEL:5 MG/M3 ACGIH TLV:2 MG/M3 Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:XYLENE; (MIXED ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE REVERSIBLE INFLAMM EFT ON UPPER RESP SYS. CAUSES ALLERGIC SENSIT IN SUBSTANCIAL PROPORTION OF HUMANS/ANIMALS IN NORM TISS AFTER RPTD EXPOS. SKIN: MAY CAUSE REVERSIBLE INFLAMM E FT ON SKIN/TISS AT SITE OF CONT. CAUSESALLERGIC SENSIT IN SUBSTANCIAL PROPORTION OF HUMANS/ANIMALS IN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: NORM TISS AFTER RPTD EXPOS. EYES: CAUSES IRRIT. INGEST: MAY CAUSE EFTS TO GI TRACT, USUALLY RESULTING FROM INGEST OF MATLS, SUCH AS IRRIT, NAUS, GI DISORDERS, ULCERATION, DIARR/CONSTIPATION. Medical Cond Aggravated by Exposure:ASTHMA TYPE CONDITIONS, CHRONIC BRONCHITIS AND OTHER CHRONIC RESPIRATORY CONDITIONS. RECURRENT SKIN ECZEMA, PRESENSITIZATION TO PRODUCT. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED, INSTITUTE ARTIFICIAL RESPIRATION. CONSULT MD. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. IF SYMPTOMS PERSIST CONSULT MD. EYES: RINSE THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. CONSULT MD. INGEST: DILUTE WITH WATER. CONTACT MD. ===================== Fire Fighting Measures ===================== Flash Point:105F,41C Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING AND/OR TOXIC GASES AND AEROSOLS FROM THE DECOMPOSITION/COMBUSTION PRODUCTS MAY BE PRESENT. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. CONTAIN SPILL AND COLLECT WITH ABSORBENT MATERIAL AND TRANSFER INTO SUITABLE CONTAINERS. AVOID CONTACT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. STORE IN TIGHTLY CLOSED CONTR & PROTECT FROM MOISTURE & FOREIGN MATL. STOR TEMP 32F MIN, 122F MAX. Other Precautions:IF CLOSED CONTR OF MATL IS EXPOSED TO HEAT, PRESS CAN BUILD UP. IF MOISTURE ENTERS DRUM, PRESS BUILD UP DUE TO RXN. AT MAX STOR TEMP NOTED, MATL MAY POLYMERIZE W/OUT HAZ. IDEAL STOR TEMP IS 50-81F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR RECOMMENDED. Ventilation:LOCAL AND MECHANICAL EXHAUSTS HIGHLY RECOMMENDED. Other Protective Equipment:WEAR LONG SLEEVE SHIRT AND LONG PANTS TO AVOID SKIN CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Vapor Density:HVR/AIR Spec Gravity:1.19 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:PASTE WITH AROMATIC ODOR Percent Volatiles by Volume:<6% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ALCOHOL, AMINES. Stability Condition to Avoid:OPEN FLAME, HEAT. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: WEBTEX 200 ACOUSTICAL ADHESIVE-FLAMMABLE, 70060 Cage: 90300 Box: 277 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 90300 Box: 277 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: MAY IRRITATE EYES, SKIN, NOSE & RESP TRACT. IF INGESTED CAUSES VOMIT, DIARR & DEPRESSED RESP. INHAL MAY AFFECT BRAIN/NERV SYS CAUSING DIZZ, HDCH/NAUS. CHRONIC: REPORTS HAVE ASSOC PRLNGD & RPTD OCCUP OVEREXP TO SOLV W/PERM BRAIN & NERV SYS DAM. PRLNGD/RPTD CONT W/SKIN CAN CAUSE DEFAT OF SKIN LEADING TO DERM. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE KNOWN. First Aid: EYE: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONTACT A PHYS IMMED. SKIN: WASH W/SOAP & WATER. INHAL: REMOVE TO FRESH AIR. CONTACT PHYS IMMED. INGEST: DO NOT INDUCE VOMIT. CONTACT PH YS/REGIONAL POISON CONTROL CTR IMMED. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE ABSORBENT MATERIAL OR SCRAPE UP DRIED MATERIAL AND PLACE INTO CONTAINERS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL STANDARDS. DISCARDED MATERIAL SHOULD BE INCINERATED AT A PERMITTED FACILITY. DO NOT REUSE EMPTY CONTAINERS. Handling And Storage Precautions: STORE AWAY FROM CAUSTICS & OXIDIZERS. KEEP CONTRS TIGHTLY CLSD WHEN NOT IN USE. KEEP OUT OF REACH OF CHILDREN. Other Precautions: KEEP CONTAINERS FROM EXCESSIVE HEAT AND FREEZING. INTENTIONAL MISUSE BY DELIB CONC AND INHALING VAPORS MAY BE HARMFUL/FATAL. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: SCC Flash Point Text: 81.0F,27.2C Extinguishing Media: FOAM, WATER FOG, DRY CHEMICALS OR CO*2. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). COOL EXPOSED CONTAINER W/WATER. Unusual Fire/Explosion Hazard: CONTRS MAY EXPLODE IF EXPOSED TO EXTREME HEAT. ELIM SOURCES OF IGNIT: HEAT, ELEC EQUIP, SPARKS & FLAME. DO NOT PUT IN CONT W/CAUSTICS OR OXIDIZING MATERIALS. ======================================================= Control Measures ======================================================= Respiratory Protection: IF 8-HR EXPOS LIM/VALUE IS EXCEEDED FOR ANY COMPONENT, USE A NIOSH/MSHA APPRVD RESP. CONSULT YOUR SFTY EQUIP SUPPLIER AND OSHA REG, 29 CFR 1910.134 FOR RESP REQUIREMENTS. Ventilation: PROVIDE SUFF MECH VENT (LOC/GEN EXHST) TO MAINTAIN EXPOS BELOW PEL & TLV. VAPS ARE HVR/AIR & WILL COLLECT IN (SUPDAT) Other Protective Equipment: PROVIDE SOLV IMPERMEABLE APRON IF BODY CONT W/PROD MAY OCCUR. BARRIER CREAMS MAY BE USED. EMERG EYE WASH AND (SUPP) Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health: VENT: LOW AREAS. CHECK LOW AREAS (BASEMENTS, SUMPS, ETC) BEFORE ENTERING. OTHER PROT EQUIP: DELUGE SHOWER WHICH MEETS ANSI DESIGN CRITERIA (FP N). ======================================================= Physical/Chemical Properties ======================================================= Vapor Pres: 46@20C Vapor Density: >1 Spec Gravity: 1.41(H*2O=1) Evaporation Rate & Reference: 36(ETHYL ETHER=1) Solubility in Water: EMULSION Appearance and Odor: PASTE WITH AN ALCOHOL ODOR Percent Volatiles by Volume: 18 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXCESSIVE HEAT AND FREEZING. Materials To Avoid: STRONG OXIDIZERS AND CAUSTICS. Hazardous Decomposition Products: NORMAL COMBUSTION PRODUCTS, I.E. CO*X, NO*X. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: WEBTEX 200 ACOUSTICAL ADHESIVE-FLAMMABLE, 70060 Cage: 90300 Company Name: DAP INC. PO Box: 277 Zipcode: 45401-0277 Label Required IND: Y Date Of Label Review: 03/21/1994 Status Code: C Label Date: 03/21/1994 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMMABLE. STORE AWAY FROM CAUSTICS AND OXIDIZERS. ACUTE: MAY IRRITATE EYES, SKIN, NOSE AND RESPIRATORY TRACT. IF INGESTED CAUSES VOMITING, DIARRHEA AND DEPRESSED RESPIRATION. INHALATION MAY AFFECT TH E BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. CHRONIC: REPORTS HAVE ASSOCIATED PROLONGED AND REPEATED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM D AMAGE. PROLONGED OR REPEAWTED CONTACT W/SKIN CAN CAUSE DEFATTING OF SKIN LEADING TO DERMATITIS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:THORTEX METAL-TECH F.G. BASE, 2011/101 Preparer's Name:A. HILL CAGE:IO111 CAGE:IO111 CAGE:TO901 ============= Composition/Information on Ingredients ============= Ingred Name:BISPHENOL A/EPICHLOROHYDRIN EPOXY RESIN (>5 2/3 %) CAS:25068-38-6 RTECS #:CE6880000 < Wt:5. ACGIH TLV:ND ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/D Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATING TO SKIN AND EYES. TOXICOLOGICAL PROPERTIES: SKIN CONTACT MAY CAUSE IRRITATION AND SENSITIZATION LEADING TO DERMATITIS. ======================= First Aid Measures ======================= First Aid:SKIN CONTACT: WASH WITH SOAP AND WATER. EYE CONTACT: FLUSH WITH COPIOUS QUANTITIES OF CLEAN WATER FOR AT LEAST 15 MINUTES. INGESTION: CONTACT A PHYSICIAN IMMEDIATELY . INHALATION: REMOVE TO FRE SH AIR. SUPPORT BREATHING. CONTACT A PHYSICIAN IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:>150.C, 302.F Autoignition Temp:>450.C, 842.F Extinguishing Media:USE FOAM, WATER MIST, CARBON DIOXIDE OR DRY POWDER TO EXTINGUISH FIRES. Fire Fighting Procedures:USE NIOSH-APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB WITH EARTH, SAND OR NON-FLAMMABLE ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT EAT OR DRINK DURING USE - OBSERVE GOOD INDUSTRIAL HYGIENE. STORE IN SEALED CONTAINERS AT TEMPERATURES BETWEEN 10C AND 30C. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE OF CONCERN . Other Protective Equipment:EYEWASH MEETING ANSI DESIGN CRITERIA . Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:>250.C, 482.F Melt/Freeze Pt:M.P/F.P Text:NA Spec Gravity:2.8 pH:NA Solubility in Water:INSOLUBLE Appearance and Odor:DARK GREY PASTE; VERY FAINT SWEET ODOUR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NON-COMPATIBILITY WITH OTHER SUBSTANCES? NO. =================== Toxicological Information=================== Toxicological Information:LD50: ND. SKIN CONTACT MAY CAUSE IRRITATION AND SENSITIZATION LEADING TO DERMATITIS. ===================== Ecological Information ===================== Ecological:NO SIGNIFICANT DATA. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS . INCINERATE OR DISPOSE OF IN AN APPROVED INDUSTRIAL WASTE SITE. =================== MSDS Transport Information =================== Transport Information:NOT RESTRICTED. ===================== Regulatory Information ===================== Federal Regulatory Information:LABEL CLASSIFICATION: XI - IRRITANT. RISK PHRASES: R43 - MAY CAUSE SENSITIZATION BY SKIN CONTACT. R36/38 - IRRITATING TO EYES AND SKIN. SAFETY PHRASES: S36/37/39 - WEAR ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:02086 CAPELLA HFC 46 NA CAGE:2R503 CAGE:3B431 CAGE:2R503 ============= Composition/Information on Ingredients ============= Ingred Name:SYNTHETIC POLYOL ESTER Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUND: NOT DETERMINED RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:RESP PROT: OF THE CONTAMINANT. AIR SUPPLIED RESPIRATORS SHOULD ALWAYS BE WORN WHEN AIRBORNE CONCENTRATION OF (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: THE CONTAMINANT OR OXYGEN CONTENT IS UNKNOWN. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:HAZ WASTE. THIS IS BECAUSE PROD USES, TRANSFORMATIONS, MIXS, PROCESSES, ETC, MAY RENDER RSLTG MATLS HAZ. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): > 5 G/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: MAY CAUSE MIN IRRIT, EXPERIENCED AS TEMPORARY DISCOMFORT. SKIN: BRIEF CONT IS NON IRRIT. PRLNG CONT, AS W/CLTHG WETTED W/MATL, MAY CAUSE DEFAT OF SKIN/IRRIT, SEEN AS LOC REDNESS W/POSS MI LD DISCOMFORT. OTHER ACUTE ADVERSE EFTSARE NOT EXPECTED FROM BRIEF CONT. INHAL: VAPS/MIST, IN EXCESS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: OF PERMISSIBLE CONCS/IN UNUSUALLY HIGH CONCS GENERATED FROM SPRAYING, HEATING MATL/AS FROM EXPOS IN POORLY VENTD AREAS/CONFINED SPACES, MAY CAUSE IRRIT OF NOSE & THROAT, HDCH, NAUS, & DROW. INGEST: IF MORE THAN SEVERAL MOUTHFULS ARE SWALLOWED, ABDOM DISCOMFORT, NAUS, & DIARR MAY OCCUR. Medical Cond Aggravated by Exposure:BECAUSE OF ITS DEFATTING PROPERTIES, PROLONGED AND REPEATED SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS (SKIN CONDITION). ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. GET MED ATTN IF IRRIT PERSISTS. SKIN: WASH W/PLENTY OF SOAP & WATER FOR SEVERAL MIN. GET MED ATTN IF IRRIT DEVELOPS/PERSISTS. INGEST: IF MORE THAN SE VERAL MOUTHFULS ARE SWALLOWED, GIVE 2 GLASSES OF WATER (16 OZ). GET MED ATTN. INHAL: REMOVE TO FRESH AIR. GET MED ATTN IF BRTHG BECOMES DFCLT/RESP IRRIT PERSISTS. REMOVE & DRY-CLEAN/LAUNDER (SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:480F,249C Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM, OR CARBON DIOXIDE TO EXTINGUISH FLAMES. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER OR FOAM MAY CAUSE FROTHING. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA. AVOID BRTHG VAP. WEAR APPROP PERS PROT EQUIP, INCL APPROP NIOSH APPRVD RESP PROT. CONTAIN SPILL IF POSS. WIPE UP/ABSORB ON SUITABLE MATL & SHOVEL UP. PVNT ENTRY INTO SEWERS & WATERWAYS. AVO ID CONT W/SKIN, EYES/CLOTHING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MINIMUM FEASIBLE HANDLING TEMPERATURES SHOULD BE MAINTAINED. Other Precautions:PERIODS OF EXPOSURE TO HIGH TEMPERATURES SHOULD BE MINIMIZED. WATER CONTAMINATION SHOULD BE AVOIDED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AIRBORNE CONCS SHOULD BE KEPT TO LOWEST LEVELS POSS. IF VAP, MIST/DUST IS GENERATED & OCCUP EXPOS LIM OF PROD/ANY COMPONENT OF PROD, IS EXCEEDED, USE APPROP NIOSH APPRVD AIR PURIFYING/AIR SUPP RESP AF TER DETERMINING AIRBORNE CONC (ING 3) Ventilation:LOC EXHST VENT REC IF GENERATING VAP, DUST/MIST. IF EXHST VENT IS NOT AVAIL/INADEQUATE, USE NIOSH APPRVD RESP AS APPROP. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WORKERS SHOULD WASH EXPOSED SKIN SEVERAL TIMES DAILY W/SOAP & WATER. SOILED WORK CLTHG SHOULD BE LAUNDERED/DRY-CLEANED. Supplemental Safety and Health FIRST AID PROC: CLTHG SOAKED W/THIS MATL BEFORE REUSE. DRY CLEANING OF CONTAM CLTHG MAY BE MORE EFFECTIVE THAN NORM LAUNDERING. INFORM INDIVIDUALS RESPONSIBLE FOR CLEANING OF POTENTIAL HAZS ASSOC W/HN DLG CONTAM CLTHG. ================== Physical/Chemical Properties ================== Spec Gravity:0.98 (H*2O=1) Appearance and Odor:LIGHT PALE LIQUID, MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE, CARBON DIOXIDE, IRRITATING ALDEHYDES AND KETONES. ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS PROD HAS BEEN EVALUATED FOR RCRA CHARACTS & DOES NOT MEET CRITERIA OF HAZ WASTE IF DISCARDED IN ITS PURCHASED FORM. UNDER RCRA, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE AT THE TIME OF DI SP, WHETHER PROD MEETS RCRA CRITERIA FOR (ING 5)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METADI AEROSOL SPRAY, 40-6288 CAGE:09410 CAGE:09410 ============= Composition/Information on Ingredients ============= Ingred Name:HEXYLENE GLYCOL CAS:107-41-5 RTECS #:SA0810000 Fraction by Wt: <10% OSHA PEL:C 25 PPM ACGIH TLV:C 25 PPM; 9192 Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 10-30% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 Ingred Name:P-11; (FLUORO CHLORO CARBON PROPELLANT). ING 3 & 4 ARE A 50/50 MIX. % OF MIX IN PRODUCT IS >60. CAS:1175-69-4 Fraction by Wt: SEE ING Ingred Name:DICHLORODIFLUOROMETHANE (SARA III) CAS:75-71-8 RTECS #:PA8200000 Fraction by Wt: SEE ING OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 Ingred Name:DIAMOND ABRASIVE VARIOUS GRADES. Fraction by Wt: 5% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DEFATTING WITH PROLONGED CONTACT. EYE/SKIN: MILD IRRITATION. INHALATION: DROWSINESS, DIZZINESS, NASAL AND RESPIRATORY IRRITATION. INGEST: NAUSEA, VOMITING, DIARRHEA, ABDOMINAL IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:OVER EXPOSURE MAY AGGRAVATE ASTHMATIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHALATION: MOVE INDIVIDUAL TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MIN. INGEST: DILUT E WITH WATER, INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point:COMBUSTIBLE Extinguishing Media:WATER, CARBON DIOXIDE, FOAM Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CONTR CONTAINS LIQUEFIED COMP GAS UNDER PRESS, PLUS MINOR AMOUNT OF FLAMM SOLVENT. THERMAL DECOMP PRODUCTS MAY INCL CHLORIDES, FLUORIDES, PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA - ABSORB LIQUID ON SUITABLE INERT ABSORBING MATERIAL AND DISPOSE IN SUITABLE WASTE CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PRODUCT CONTIANS LIQUEFIED GAS UNDER PRESSURE. AVOID TEMPERATURES ABOVE 125 F. Other Precautions:DO NOT SPRAY NEAR EYES. NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES, HOT SURFACES. HEAT &/OR UV RADIATION MAY CASUE FORMATION OF CHLORIDES, FLUORIDES, PHOSGEN E. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED AIR MASK IN PRESENCE OF HIGH VAPOR CONCENTRATION. Ventilation:LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV IN INGREDIENT SECTION. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:GOOD PERSONAL HYGIENE TO BE FOLLOWED AT ALL TIMES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-6F,-21C Melt/Freeze Pt:M.P/F.P Text:90% Vapor Pres:1900@ 70 F Vapor Density:3 Spec Gravity:>1 Evaporation Rate & Reference:>1 (BUTYL ACETATE=1) Solubility in Water:PARIALLY SOLUBLE Appearance and Odor:PLEASANT ODOR, VARIOUS COLORS ACCORDING TO DIAMOND GRADE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG MINERAL ACIDS, STRONG OXIDIZING AGENTS, RUBBER AND SOME PLASTICS. Stability Condition to Avoid:AVOID OPEN FLAMES OR HIGH TEMPERATURES ABOVE 125 F IN STORAGE CANS. Hazardous Decomposition Products:HIGH TEMP (FLAME) DECOMPOSITION OF PROPELLANT ONLY MAY FOAM HYDROCHLORIC AND HEDROFLUORIC ACIDS, POSSIBLE PHOSGENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH WASTE MATERIAL WITHOUT PROPELLANT DOWN DRAIN. DISPOSAL MUST I/A/W FEDERAL, STATE & LOCAL REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MARK 81 PART A CAGE:JO128 CAGE:JO128 CAGE:1T794 ============= Composition/Information on Ingredients ============= Ingred Name:BISPHENOL A DIGLYCIDYL ETHER RESIN, EPOXY RESIN, ARALDITE 6004, 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN CAS:25068-38-6 RTECS #:KD4380000 Fraction by Wt: <35% Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: <5% Other REC Limits:590 MG/CUM OSHA PEL:200 PPM ACGIH TLV:590 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CELLOSOLVE ACETATE (ETHYLENE GLYCOL ETHYL ETHER ACETATE), 2-ETHOXYETHYL ACETATE CAS:111-15-9 RTECS #:KK8225000 Fraction by Wt: <20% OSHA PEL:100 PPM ACGIH TLV:5 PPM SKIN Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL CARBINOL CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: <10% Other REC Limits:400 PPM OSHA PEL:400 PPM ACGIH TLV:400 PPM Ingred Name:INORGANIC FILLERS Fraction by Wt: <30% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. INHALATION: MUCOUS MEMBRANE IRRITATION, HEADACHE, DIZZINESS, & NAUSEA. SKIN: IRRITATION, DERMATITIS, SENSITIZATION, & ALLERGIC REACTION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION. INHALATION: MUCOUS MEMBRANE IRRITATION, HEADACHE, DIZZINESS, & NAUSEA. SKIN: IRRITATION, DERMATITIS, SENSITIZATION, & ALLERGIC REACTION. Medical Cond Aggravated by Exposure:ALLERGY, ECZEMA, & SKIN CONDITIONS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH W/MILD SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS DIFFICULT. INGESTION: IF CONSCIOUS, GIVE PLENTY OF WATE R. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:65F Extinguishing Media:CO2, FOAM, DRY CHEMICAL, OR WATER SPRAY Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS Unusual Fire/Explosion Hazard:HEATING FORMS TOXIC, FLAMMABLE VAPORS WHICH MAY FORM EXPLOSIVE MIXTURES W/AIR. FLAMMABLE LIQUID. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. TAKE UP W/ABSORBENT MATERIAL. SHOVEL INTO CLOSABLE CONTAINER. FLUSH CONTAMINATED AREA W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA. USE W/GOOD VENTILATION. Other Precautions:AVOID CONTACT W/EYES, SKIN, & CLOTHING. AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ORGANIC CHEMICAL CARTRIDGE RESPIRATOR. Ventilation:LOCAL EXHAUST OR MECHANICAL (GENERAL) Other Protective Equipment:APPROPRIATE EQUIPMENT & BARRIER CREAM Work Hygienic Practices:REMOVE WET CONTAMINATED, NON-IMPERVIOUS CLOTHING/WASH BEFORE REUSE. WASH AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.4 Solubility in Water:INSOLUBLE Appearance and Odor:PIGMENTED LIQUID W/SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS OR BASES IN BULK, POLYAMIDES, & POLYAMINES Stability Condition to Avoid:ELEVATED TEMPERATURES Hazardous Decomposition Products:CO, CO2, & ALDEHYDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. FLAMMABLE LIQUID.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:INTERBOND SILICONE ALUMINUM, HTA154 (V) CAGE:INCMM CAGE:INCMM CAGE:26351 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE. VP: 10 @ 20C CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 24-28% OSHA PEL:100 PPM;150 PPM STEL ACGIH TLV:100 PPM;150 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MINERAL SPIRITS (MFR CAS #8030-30-4) CAS:8043-92-3 Fraction by Wt: 10-15% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:9-OCTADECENOIC ACID, (Z)-; (OLEIC ACID) CAS:112-80-1 RTECS #:RG2275000 Fraction by Wt: 1-5% Ingred Name:ALUMINUM CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 25-30% OSHA PEL:15MG/M3 DUST;5 FUME ACGIH TLV:10MG/M3 DUST;5 FUME ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: CAN CAUSE IRRITATION WITH REDNESS, TEARING AND BLURRED VISION. SKIN: IRRITATING. MAY RESULT IN DERMATITIS. INHAL: IRRITATION OF RESPIRATORY TRACT. HEADACHE AND DIZZINESS AND UNCONSCIOUSNESS. ING EST: MAY CAUSE GI IRRITATION. CHRONIC OVEREXP TO, AND MISUSE OF, SOLVENTS HAS BEEN LINKED TO PERM BRAIN & NERV SYS DMG. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SKIN AND RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY WITH COPIOUS QUANTITIES OF WATER FOR AT LEAST 15 MINUTES. CALL MD IMMEDIATELY. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH PLENTY OF SOAP AND WATER. LAUNDER CLOTHES BEFO RE REUSE. INHAL: REMOVE TO FRESH AIR. GIVE ARTF RESP IF NEEDED. CALL MD. INGEST: CALL MD IMMEDIATELY TO DETERMINE WHETHER OR NOT TO INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:81.0F,27.2C Lower Limits:1% Extinguishing Media:FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .SMOTHER FLAMES W/ONE OF ABOVE EXTING MEDIA.WATER MAY BE USED TO COOL UNOPENED CNTNRS,BUT MUST (SUPP DATA) Unusual Fire/Explosion Hazard:CONTAINS FLAM SOLV.DO NOT USE IN AREAS WHERE SPARK/OPEN FLAME ARE PRESENT.EXPLO HYDROGEN GAS MAY BE GENERATED IN PRESENCE OF MOISTURE, ALKALIS/ACIDS.(SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES. AVOID INHALATION OF VAPORS. VENTILATE AREA. CLEAN UP WITH ABSORBENT MATERIALS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BLDGS DESIGNED & PROT FOR STORAGE OF LIQ W/NFPA CLASS GIVEN BY OSHA CLASS. AVOID BRTHG DUST/CHIPS FROM SANDING/BLASTING SURF COATED W/PROD. Other Precautions:RECOMMENDED GROUNDING AND BONDING OF CONTAINERS WHEN TRANSFERRING LIQUIDS AND POWDERS TO AVOID STATIC CHARGE BUILDUP. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN OUTDOOR/OPEN AREAS, W/UNRESTRICTED VENT; USE NIOSH/MSHA APPRVD FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING SPRAY APPLICATN. IN RESTRICTED VENT AREAS, USE NIOSH/MSHA APPRVD RE SP I/A/W 29CFR1910.134 TO (SUPP DATA) Ventilation:PROVIDE SUFFICIENT VENT, IN VOLUME & PATTERN TO KEEP TLV & LEL OF HAZ INGREDS <LIMS & TO REMOVE DECOMP PRODS (SUPP DATA) Other Protective Equipment:WEAR APPROPRIATE IMPERVIOUS PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:REMOVE AND WASH SOILED CLOTHING BEFORE REUSE; WASH HANDS BEFORE EATING OR SMOKING. Supplemental Safety and Health FIRE FIGHT PROC:NOT BE USED AS AN EXTING MEDIA. TAKE CARE TO PVNT SPREAD OF BURNING LIQ W/WATER. CLSD CNTNRS MAY EXPLD WHEN EXPSD TO EXTREME HEAT. EXPLO HAZ:EXPLO MAY OCCUR IF CONTAM W/STRONG OXIDIZIN G AGENTS. VENT:DURING WELDING/FLAME CUTTING ON SURF COATED W/PROD. RESP:REMOVE COMBINATION OF PARTICULATES & VAPORS. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:280F,138C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MOISTURE, OXIDIZING AGENTS. Stability Condition to Avoid:STORE AWAY FROM DIRECT HEAT, FLAME OR SPARK. KEEP DRY, PRODUCES EXPLO HYDROGEN GAS. Hazardous Decomposition Products:CO, CO*2, VARIOUS HYDROGEN FRAGMENTS, ALUMINUM FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE UNOPENED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:521-80 BLACK SILATHANE INT/EXT BRUTONE INTERIOR ALKYD SEMI-G CAGE:EO376 CAGE:EO376 CAGE:85520 ============= Composition/Information on Ingredients ============= Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM SILICATE *96-4* CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 0-5% OSHA PEL:2 MG/CUM (RESP DUST) ACGIH TLV:2 MG/CUM (RESP DUST) Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS *96-4* CAS:64742-88-7 Fraction by Wt: 0-5% Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:VOLATILE ORGANIC CONTENT: 3.32 TO 3.74 LBS/GAL RTECS #:9999999VO Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS *96-4* CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 25-50% Other REC Limits:525 MG/CUM OSHA PEL:500 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE NOSE, THROAT & EYE IRRITATION. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DIZZINESS, HEADACHE, INTOXICATION, EUPHORIA, UNCONSCIOUSNESS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LUKE WARM WATER FOR 15 MINS. SKIN: FLUSH WASH W/COPIOUS AMOUNTS OF LUKE WARM WATER. INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING IF REQUIRED. INGESTION: RINSE MOUTH IMMEDIATELY. GI VE 6-8 OUNCES OF LIQUID. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DON'T INDUCE VOMITING UNLESS ADVISED BY A PHYSICIAN. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:104F Lower Limits:0.9 Upper Limits:7 Extinguishing Media:THE NFPA CLASS B EXTINGUISHER. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CLOSED CONTAINERS. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DON'T APPLY TO HOT SURFACES. NEVER USE WELDING/CUTTING TORCH ON/NEAR CONTAINER, MAY IGNITE/EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:STOP &/CONTAIN DISCHARGE SAFELY. KEEP SOURCES OF IGNITION AWAY. VENTILATE AREA. USE NON-SPARKING TOOLS. COVER W/INERT MATERIAL. KEEP OUT OF DRAINS, SEWERS/WATERWAYS. CONTACT FIRE AUTHORITIES. NOTIFY L OCAL HEALTH & POLLUTION CONTROL AGENCIES. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. DON'T CUT/PUNCTURE CONTAINER. DON'T WELD NEAR CONTAINER. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. USE W/ADEQUATE VENTILATION. Other Precautions:GROUND CONTAINERS WHEN POURING & LIMIT FREE-FALL TO A FEW INCHES. AVOID CONTAMINATED RAGS/IGNITABLE ORGANIC MATERIALS. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY BE H ARMFUL/FATAL. DON'T BREATHE VAPORS/MIST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN OPEN AREAS DURING SPRAY APPLICATION, USE NIOSH/MSHA MECHANICAL FILTER RESPIRATOR/IN RESTRICTED AREAS, USE NIOSH/MSHA APPROVED CHEMICAL MECHANICAL FILTERS/IN CONFINED AREAS, USE NIOSH/MSHA APPROVED AIR LINE TYPE RESPIRATORS/HOODS. Ventilation:GENERAL DILUTION/LOCAL EXHAUST TO KEEP TLV BELOW ACCEPTABLE LIMIT DURING WELDING/FLAME CUTTING ON COATED SURFACES. Other Protective Equipment:APRON Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS THOROUGHLY BEFORE EATING & USING WASHROOM. Supplemental Safety and Health % VOLATILE BY VOLUME: 50.96-57.73. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300-416F Vapor Pres:2 Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN BU AC Percent Volatiles by Volume:(SUPP) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WELDING Stability Condition to Avoid:SPARKS, OPEN FLAME, HOT SURFACES, SOURCES OF IGNITION. Hazardous Decomposition Products:CO, CO2 & OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T FLUSH TO SEWER, WATERSHED/WATERWAY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:QUALITY-FIBERED ALUMINUM COATING, F-600 CAGE:IO527 CAGE:FELDS CAGE:IO527 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS CAS:64742-88-7 Fraction by Wt: 45-55% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALUMINUM; (ALUMINUM FLAKE) (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 10-25% OSHA PEL:15 MG/M3 DUST;5 FUME ACGIH TLV:10 MG/M3 DUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: RED, IRRIT, BLURRED VISION. INHAL: NASAL & RESP IRRIT, FATG, DIZZ, WEAK, HDCH. INGEST: GI IRRIT, NAUS, VOMIT & DIARR. ASPIR INTO LUNGS CAN CAUSE CHEM PNEUM. SKIN: RED, DEFAT OF SKIN, DERM. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG/SKIN CONDITIONS WOULD BE AGGRAVATED BY CONTINUED EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/CLEAN WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, GET MED ATTN. INHAL: REMOVE FROM EXPOSURE, AND ADMINISTER OXYGEN IF BRTHG IS IRREG. GET MED ATTN IMMED. INGEST: DO NOT INDUCEVOMIT. MATERIAL CAN BE ASPIRATED INTO LUNGS AND CAUSE CHEM PNEUM. GET MED ATTN. SKIN: REMOVE ANY CONTAMD CLTHG & WASH AREA W/SOAP &WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:107F,42C Lower Limits:0.9% Upper Limits:7% Extinguishing Media:CO*2, FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS ARE AN EXPLOSION HAZARD WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. RECOVER FREE PRODUCT. ADD SAND, EARTH OR OTHER SUITABLE ABSORBENT TO SPILL AREA. MINIMIZE VAPOR AND SKIN CONTACT. KEEP PRODUCT FROM SEWERS AND WATERCOURSES BY DIKING AND IM POUNDING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM IGNITION SOURCES. VENT AREA. Other Precautions:AVOID BREATHING VAPORS. KEEP CONTAINERS CLOSED. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR. Ventilation:MECHANICAL LOCAL OR GENERAL EXHAUST IS RECOMMENDED. Other Protective Equipment:COVERALLS MAY BE USED DEPENDING UPON APPLICATION. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPEC GRAV: 1.01-1.08(H*2O=1). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:310F,154C Vapor Pres:<10@25C Vapor Density:4.8 Spec Gravity:SUPP DATA Evaporation Rate & Reference:<1(BUTYL ACETATE=1) Solubility in Water:INSOLUBLE Appearance and Odor:SILVER VISCOUS LIQUID WITH AROMATIC SOLVENT ODOR Percent Volatiles by Volume:60-65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:WILL FORM HYDROGEN GAS IN WATER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER & STEEL COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPIPHEN 825-MODIFIER T CAGE:4Y418 CAGE:4Y418 ============= Composition/Information on Ingredients ============= Ingred Name:POLYSULFIDE RESIN Fraction by Wt: 100% Ingred Name:DIETHYLENE TRIAMINE CAS:111-40-0 RTECS #:IE1225000 Fraction by Wt: 100% Other REC Limits:4 MG/CUM OSHA PEL:1 PPM ACGIH TLV:S, 1 PPM; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TESTS INDICATE THIS PRODUCT IS NOT A PRIMARY IRRITANT BUT MAY POSSIBLY CAUSE SENSITIZATION. THIS MATERIAL IS A FATIGUING AGENT. Explanation of Carcinogenicity:NONE Effects of Overexposure:POSSIBLE SENSITIZATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:418F Extinguishing Media:WATER, CO2, FOAM, DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:COVER SPILL W/ABSORBENT. REMOVE TO CONTAINER. WIPE FLOOR W/RAGS & SMALL AMOUNT OF 1,1,1-TRICHOROETHANE. REMOVE RAGS TO CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:THIS MATERIAL IS A FATIGUING AGENT & SHOULD BE HANDLED W/PRECAUTION. AVOID CONTACT W/SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS NEEDED Ventilation:MECHANICAL Other Protective Equipment:LONG SLEEVE WORK SHIRTS Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:THICK AMBER LIQUID Percent Volatiles by Volume:0.2% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A LANDFILL IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AC-25 TRU-TEST SELECT ACOUSTICAL LATEX TILE PAINT, WHITE CAGE:TRUTE CAGE:TRUTE ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <5% Other REC Limits:10 MG/CUM OSHA PEL:50 PPM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM, MAGNESIUM SILICATE CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 10% OSHA PEL:20 MPPCF ACGIH TLV:2 MG/CUM (RESP DUST) Ingred Name:VOL ORGANIC CMPD: <100 G/L RTECS #:9999999VO Ingred Name:WEIGHT PER GALLON IN POUNDS: 11.4 RTECS #:9999999WG ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF EYES, NOSE, THROAT, & MUCOUS MEMBRANES OF RESPIRATORY TRACT. SKIN/EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: IRRITATION TO EYES, NOSE, THROAT, & MUCOUS MEMBRANES OF RESPIRATORY TRACT. SKIN/EYES: IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYES: FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER. INGESTION: GIVE 2 GLASSES OF WATER TO DILUTE. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENT ION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:WATER MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE OR BUILD-UP PRESSURE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE & CONTAIN SPILL W/INERT MATERIAL SUCH AS SAND OR EARTH. TRANSFER THE LIQUID TO CONTAINERS FOR RECOVERY OR DISPOSAL. KEEP SPILL OUT OF SEWERS & OPEN BODIES OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. AVOID CONTACT W/SKIN & EYES. DON'T TAKE INTERNALLY. AVOID INHALATION OF VAPORS OR SPRAY MISTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN BRUSHED OR ROLLED NONE REQUIRED IF GOOD VENTILATION MAINTAINED. DURING SPRAY APPLICATION, AN APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE AIRBORN PARTICLES OF OVERSPRAY IS REQUIRED. Ventilation:SUFFICIENT TO KEEP <TLV. Other Protective Equipment:EYE WASH FACILITY, PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING, OR USING WASHROOM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Density:<AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:WHITE LIQUID. Percent Volatiles by Volume:70% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXTREME HEAT & FREEZING ==================== Disposal Considerations ==================== Waste Disposal Methods:LIQUID MATERIAL & CONTAMINATED DIKING MATERIAL SHOULD BE LANDFILLED ACCORDING TO CURRENT LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:122 8865 DK-50 DEVELOPER,PART B Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM METABORATE CAS:7775-19-1 RTECS #:ED4640000 Fraction by Wt: 15 - 20% Other REC Limits:NONE SPECIFIED Ingred Name:POTASSIUM BROMIDE CAS:7758-02-3 RTECS #:TS7650000 Fraction by Wt: 1 - 5% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 75 - 80% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES AND RESPIRATORY SYSTEM. ACUTE- EYES:MAY CAUSE TRANSIENT IRRITATION. SKIN:LOW HAZARD FOR RECOMMENDED HANDLING. INHALATION:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IF SUL FUR DIOXIDE PRESENT, RESPIRATORY IRRITATION MAY OCCUR. ORAL:EXPECTED TO BE A LOW INGESTION HAZARD. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:IRRITATION Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT IN DUCE VOMITING. IF CONSCIOUS, DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHENICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE AWAY FROM STRONG ACIDS. Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP OUT OF REACH OF CHILDREN. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFIDES MAY LIBERATE SULFUR DIOXIDE GAS WHICH IS IRRITATING TO RESPIRATORY TRACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:GOOD GENERAL VENTILATION (10 AIR CHANGES/HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment:PROVIDE EYE WASH STATION, SAFETY SHOWER, WASHING FACILITIES. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health KEY1:N1. SEE PNI A FOR PART A. THIS PRODUCT HAS: A MODERATE BIOCHEMICAL OXYGEN DEMAND, A LOW POTENTIAL TO AFFECT AQUATIC ORGANISMS. AFTER DILUTION WITH A LARGE AMOUNT OF WATER, THIS PRODUCT IS NOT EXP ECTED TO CAUSE ADVERSE ENVIRONMENT EFFECTS. ================== Physical/Chemical Properties ================== HCC:T4 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:NOT GIVEN Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:NEGLIGIBLE Vapor Density:NOT GIVEN Spec Gravity:>1.00 Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:COMPLETE Appearance and Odor:LIGHT YELLOW SOLID. ODORLESS. Percent Volatiles by Volume:NEGLIG ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:SULFUR DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. IF NOT RESTRICTED, FLUSH TO SEWER WITH LARGE AMOUNT OF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TRAFFIC LANE CLEANER (AND XB) CAGE:GO308 CAGE:CHEMP CAGE:GO308 ============= Composition/Information on Ingredients ============= Ingred Name:TETRAPOTASSIUM DIPHOSPHORATE CAS:7320-34-5 RTECS #:JL6735000 Ingred Name:LINEAR (C12 & C14) ALKYL ALCOHOLS, ETHOXYLATED *93-4* CAS:68439-50-9 Ingred Name:N-BUTOXYPROPANOL CAS:5131-66-8 RTECS #:UA7700000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN, EYE, & RESPIRATORY IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: IRRITATION. INGESTION: NAUSEA. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: CONSULT PHYSICIAN. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:>200F Extinguishing Media:CO2, DRY CHEMICAL, WATER OR FOG Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SELF-CONTAINED POSITIVE PRESSURE BREATHING APPARATUS & PROTECTIVE CLOTHING. ======================Handling and Storage ====================== Other Precautions:ONE SHOULD ALWAYS USE CHEMICALS W/AWARENESS OF POTENTIAL HAZARDS, KNOWN & UNKNOWN, & THEIR EFFECT ON THE HUMAN SYSTEM. MINIMIZE EMPLOYEE EXPOSURE TO ALL CHEMICALS, INCLUDING THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED MASK Ventilation:MECHANICAL TO KEEP BELOW TLV Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PRACTICES Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 212F Spec Gravity:1.01 pH: 12-13 Solubility in Water:COMPLETE Appearance and Odor:LIGHT GREEN CLEAR LIQUID W/MILD SOLVENT ODOR Percent Volatiles by Volume:83 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Hazardous Decomposition Products:ACRID & TOXIC FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TRACE METALS ERA CERTIFIED PRIORITY POLLUTNT, 531 CAGE:1R664 CAGE:1R664 ============= Composition/Information on Ingredients ============= Ingred Name:ARSENIC; (ARSENIC METAL OR TRIOXIDE) (SARA 302/313) (CERCLA) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <0.004% OSHA PEL:SEE 1910.1018 ACGIH TLV:0.01 MG/M3, A1 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ACETIC ACID, BERYLLIUM SALT; (BERYLLIUM ACETATE) CAS:543-81-7 RTECS #:AF5250000 Fraction by Wt: <0.04% OSHA PEL:0.002 MG/M3 (MFR) ACGIH TLV:0.002 MG/M3 (MFR) Ingred Name:CADMIUM (METAL) (SARA 313) (CERCLA) CAS:7440-43-9 RTECS #:EU9800000 Fraction by Wt: <0.003% OSHA PEL:0.2 MG/M3 DUST ACGIH TLV:0.01 MG/M3 DUST EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:CHROMIUM (DICHROMATE) (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: <0.03% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NICKEL (METAL) (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: <0.01% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:ALUMINUM (III) NITRATE (1:3) CAS:13473-90-0 RTECS #:BD1040000 Fraction by Wt: <0.07% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ANTIMONY POTASSIUM TARTRATE (SARA 313) (CERCLA) CAS:28300-74-5 RTECS #:CC6825000 Fraction by Wt: <0.007% OSHA PEL:0.5 MG (SB)/M3 ACGIH TLV:0.5 MG (SB)/M3 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:BARIUM NITRATE (OR CARBONATE) CAS:10022-31-8 RTECS #:CQ9625000 Fraction by Wt: <0.02% OSHA PEL:5 MG BA/M3 ACGIH TLV:2 MG BA/M3 Ingred Name:BORIC ACID CAS:10043-35-3 RTECS #:ED4550000 Fraction by Wt: <0.06% OSHA PEL:10 MG BORATES/M3 ACGIH TLV:5 MG BORATES/M3 Ingred Name:ACETIC ACID, COBALT (2+) SALT; (COBALT ACETATE) CAS:71-48-7 RTECS #:AG3150000 Fraction by Wt: <0.05% OSHA PEL:0.05 MG C0/M3 ACGIH TLV:0.05 MG C0/M3 Ingred Name:COPPER (METALLIC) (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: <0.01% OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:IRON NITRATE CAS:10421-48-4 RTECS #:QU8915000 Fraction by Wt: <0.04% OSHA PEL:1.0 MG/M3 (MFR) ACGIH TLV:1.0 MG/M3 (MFR) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LEAD (METAL OR ACETATE) (SARA 313) (CERCLA) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: <0.02% OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15 MG(PB)/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MANGANESE (METALLIC) (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: <0.01% OSHA PEL:C 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST Ingred Name:MERCURY (METALLIC) (SARA 313) (CERCLA) CAS:7439-97-6 RTECS #:OV4550000 Fraction by Wt: <0.0002% OSHA PEL:C, 0.1 MG/M3 ACGIH TLV:0.025 MG/M3, S EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MOLYBDENUM (AS MOLYBDATE) (SARA 313) CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: <0.02% OSHA PEL:5 MG(MO)/M3 ACGIH TLV:5 MG(MO)/M3 Ingred Name:SELENIUM (METAL OR AS SELENATE) (SARA 313) (CERCLA) CAS:7782-49-2 RTECS #:VS7700000 Fraction by Wt: <0.003% OSHA PEL:0.2 MG/M3 ACGIH TLV:0.2 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SILVER (I) NITRATE (1:1) (SARA 313) (CERCLA) CAS:7761-88-8 RTECS #:VW4725000 Fraction by Wt: <0.004% OSHA PEL:0.01 MG(AG)/M3 ACGIH TLV:0.01 MG(AG)/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:STRONTIUM (II) NITRATE (1:2) (OR CARBONATE) CAS:10042-76-9 RTECS #:WK9800000 Fraction by Wt: <0.03% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:THALLIUM (I) NITRATE (1:1) CAS:10102-45-1 RTECS #:XG5950000 Fraction by Wt: <0.005% OSHA PEL:0.1 MG/M3 (MFR) ACGIH TLV:0.1 MG/M3 (MFR) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:AMMONIUM VANADIUM OXIDE; (AMMONIUM VANADATE) (CERCLA) CAS:11115-67-6 RTECS #:BT5140000 Fraction by Wt: <0.03% OSHA PEL:0.05 MG (V2O5)/M3 ACGIH TLV:0.05 MG (V2O5)/M3 Ingred Name:ZINC (METAL) (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: <0.01% OSHA PEL:5.0 MG/M3 (MFR) ACGIH TLV:5.0 MG/M3 (MFR) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NITRIC ACID (PRESERVATIVE) (SARA 302/313) (CERCLA) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: <5% OSHA PEL:2 PPM ACGIH TLV:2 PPM/4 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUP DAT: DISTURB, CARD ARRHYS, COLLAPSE & DEATH. ING 9:BORATE INTOXICATION, CARDIOVASCULAR COLLAPSE. ING 10: (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24: POIS. SEV GASTRO-ENTERITIS, ABDOM PAIN, FLUSHING, DEAFNESS, RASH. CONT NEHC FOR MORE SPECIFIC INFO . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHRONIC:ING 1:NEUROLOGICAL, SKIN & NAIL CHANGES. ING 2:SENSIT & CHRONIC PULM TOXIN. ING 3:BONE PAIN & URINARY PROTEIN LOSS. ING 4:NASAL SEPTAL PERFORATION. ING 5:ALLERGIC SENSIT. ING 10:GOITER/HEART F AILURE. ING 13:ABDOM PAIN, NEUROPATHY, LEAD POIS. ING 14:POIS, NEUROLOGICAL DISORDER. ING 15: (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:GINGIVITIS, STOMATITIS, EXCESS SALIVATION, TREMOR & PSYCHOLOGICAL CHANGES. ING 16:BONE/JOINT SYMPS, GOUT/ANEMIA. ING 17:LIVER DMG. ING 18:SENSIT. ING 20:ALOPECIA & NEUROPATHY. LEAD & MERCURY APPEAR ON THE NAVY OCCUP CHEM REPRO HAZLIST. SEEK CONSULT FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST (SUP DAT) Medical Cond Aggravated by Exposure:ASTHMA, RENAL FAILURE, LIVER DISEASE, THYROID DISORDERS, CARDIAC DISEASE, PARKINSON'S DISEASE, GOUT, DERMATITIS. CONTACT NEHC FOR MORE SPECIFIC INFORMATION . ======================= First Aid Measures ======================= First Aid:EYE/SKIN: FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MIN. CONSULT EYE SPECIALIST FOR ANY SIGNIFICANT EYE IRRIT/EYE CONT. INHAL: IF IN DISTRESS, ADMIN MOIST OXYGEN & SEEK MED ATTN. INGEST: INDUCE VO MIT. SEEK MED ATTN FOR ANY INGEST OF PROD. DUE TO MANY POSS TOX INGS, ANY INGEST REQUIRES ASSESSMENT BY TRAINED MED PERS. BE CERTAIN TO SEND LABEL INFO & MSDS W/PATIENT TO ASSIST IN EVAL & TREATMENT. ===================== Fire Fighting Measures ===================== Flash Point:NOT IGNITABLE Extinguishing Media:NONE. USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NONE. WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:DRY MATERIAL SHOULD BE SWEPT, WET MOPPED, OR VACUUMED, THEN DISPOSED OF AS HAZARDOUS WASTE DUE TO METAL COMPONENTS. AVOID PRODUCTION OF DUST USING SWEEPING COMPOUND OR HEPA FILTERED VACUUM EQUIPMENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INHALATION OR HEATING OF DRY MATERIAL. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED PARTICULATE MASK (HEPA) SHOULD BE USED WHENEVER UNCONTROLLED DUST EXPOSURE IS LIKELY. Ventilation:LOCAL EXHAUST/MECHANICAL: USE IN HOOD. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE SHOWER . LABORATORY COAT, APRON & CLOSED SHOES SHOULD BE WORN. Work Hygienic Practices:AVOID INHALATION OF DUST. AVOID HEATING OF DRY MATERIAL. Supplemental Safety and Health EFTS OF OVEREXP:HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ACUTE:ING 1:POIS. SHOCK. ING 3:POIS. SEV GASTRO-ENTERITIS, CARDIO-VASCULAR COLLAPSE, KIDNEY/LIVER DMG, BONE PAIN. ING 4:NON-HEALING ULCE RATION. ING 5:DIARR, VOMIT & ABDOM PAIN. ING 6:CATHARTIC EFTS IF INGESTED. ING 8:POIS. VOMIT, DIARR, ELECTROLYTE(ING 24) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:23.7 Vapor Density:HVR/AIR Spec Gravity:1.00 Evaporation Rate & Reference:1.00 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS HAZARDOUS WASTE DUE TO METAL COMPONENTS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS . CONTACT NEHC FOR MORE SPECIFIC INFORMATION .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-P-95C TY 1 25526 BLUE, PC 700L40 Preparer's Name:ROBERT COMMISSO CAGE:DO312 CAGE:58963 CAGE:DO312 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS (VAPOR PRESSURE 2.0 MM HG @ 68 F) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 20% Other REC Limits:NONE SPECIFIED OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 7% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 15% Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MAGNESIUM SILICATE CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED ACGIH TLV:2 MG/M3 Ingred Name:METHYL AMYL KETONE (SARA 313) (VAPOR PRESSURE 2.1 MM HG @ 68 F) CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 14% Other REC Limits:100 PPM Ingred Name:CHLORINATED RUBBER RESIN Fraction by Wt: 15% Other REC Limits:NONE SPECIFIED Ingred Name:CHLORINATED ALKYD RESIN Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED Ingred Name:MATERIAL VOC: 4.95 LB/GL (593 G/L) RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DIRECT CONTACT TO EYES: IRRIT. PROLONGED/REPEATED CONTACT: SKIN IRRIT. INHALATION OF HIGH CONC OF VAPORS MAY LEAD TO LUNG CHANGES, NAUSEA, VOMITING, COUGH, PULMONARY IRRIT & CENTRAL NERV SYS DEPRESS. INGESTION: GASTROINTEST DISTURBANCES. ASPIRATION OF PROD INTO LUNGS MAY CAUSE PNEUMONITIS21FEB92NARY EDEMA & HEMORRAGE. Effects of Overexposure:INHAL: BREATHING OF HIGH VAPOR CONC MAY CAUSE DROWSINESS, DIZZINESS, FATIGUE, FOLLOWED BY COMA. EYE: DIRECT CONTACT/CONTACT W/VAPOR--IRRIT. SKIN: PROLONG/REPEAT--IRRIT/DERMATITIS. SKIN ABSORPTION: PRO LONG/REPEAT--DEFATTING/IRRIT/DERMATITIS. INGEST: ASPIRATION INTO LUNGS--PNEUMONITIS, PULMONARY EDEMA & HEMMORAGE. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES IN OR HISTORY OF AILMENTS INVOLVING SKIN, CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEY. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. SEEK MEDICAL AID. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. SEEK MEDICAL AID IF IRRITATION PERSISTS. INGESTION: IMMEDIATELY SEEK MED ICAL AID. DO NOT INDUCT VOMITING. DO NOT ATTEMPT TO GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:45.0F,7.2C Autoignition Temp:Autoignition Temp Text:474 F Lower Limits:1.0% Upper Limits:7.9% Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:APPROVED GAS MASK REQUIRED FOR FIRE FIGHTING PERSONNEL. WATER MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CONTAINERS. IF WATER IS USED, FOG NOZZLES PREFERRED. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHLTY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. REMOVE ALL SOURCES OF IGNITION. STAY UPWIND. ABSORB WITH INERT MATERIAL. FLUSH AREA WITH WATER. VENTILATE AREA FOR AT LEAST 24 HOURS OR UNTIL AREA HAS BEEN DECLARED SAFE . ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED AND UPRIGHT TO PREVENT LEAKAGE. AVOID FLAMES, WELDING, OPEN LIGHTS, ETC. AVOID BREATHING OF VAPOR AND SPRAY MIST. Other Precautions:AVOID SKIN AND EYE CONTACT. MAINTAIN GOOD PERSONAL HYGIENE. DO NOT USE IN CONFINED AREAS, TANK OR PIT WITHOUT ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENT DOESN'T MAINTAIN INHALATION EXPOSURES BELOW TLV/PEL, USE NIOSH/MSHA APPRVD UNITS. USE UNITS PER CURRENT 29 CFR 1910.134 & FOLLOW MFRS' INSTRUCTIONS & WARNINGS. IF W/IN OSHA PROTECTION FACTOR, AIR PURIFYING OV/FILTER UNITS ARE OK. Ventilation:LOCAL AND MECHANICAL EXHAUST. Other Protective Equipment:EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:MAINTAIN GOOD PERSONAL HYGIENE. DO NOT USE IN CONFINED AREAS WITHOUT ADEQUATE VENTILATION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:230 TO 310F Vapor Density:> AIR Spec Gravity:1.2 (WATER=1) Viscosity:70+ KU Evaporation Rate & Reference:SLOWER THAN ETHER. Solubility in Water:ESSENTIALLY NIL. Appearance and Odor:VISCOUS LIQUID WITH TYPICAL PAINT ODOR. Percent Volatiles by Volume:71.8 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:FLAMES, SPARKS, SMOKING AND HEAT. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:USE INERT ABSORBENT MATERIALS ON SPILLS. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:383 BROWN ZENTHANE P/N 08606TUZ-GD Preparer's Name:JANE FREEMAN CAGE:09225 CAGE:09225 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ISOAMYL KETONE (SOLVENT) CAS:110-12-3 RTECS #:MP3850000 Fraction by Wt: 24.302% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9293 Ingred Name:BLACK IRON OXIDE (PIGMENT) (EXPOSURE LIMITS ARE FOR IRON OXIDE FUME) CAS:1317-61-9 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:RED IRON OXIDE (PIGMENT) (EXPOSURE LIMITS ARE FOR IRON OXIDE FUME) CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:SILICA (PIGMENT) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 20-30% Other REC Limits:NONE SPECIFIED OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE CAS:28182-81-2 RTECS #:NQ9170000 Fraction by Wt: 20-30% Other REC Limits:.5 PPM/STEL 1 MG/M3 Ingred Name:TRIVALENT CHROME (INSOLUBLE) (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 5.116% Other REC Limits:NONE SPECIFIED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:AROMATIC HYDROCARBON (MIXTURE OF C8'S TO C10'S) CAS:64742-95-6 Fraction by Wt: 1.198% Other REC Limits:MFR LIMIT: 100 PPM Ingred Name:BUTYL ACETATE (SOLVENT) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 1.198% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM ACGIH TLV:150 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HEXAMETHYLENE DIISOCYANATE MONOMER CAS:822-06-0 RTECS #:MO1740000 Fraction by Wt: 0.048% Other REC Limits:NONE SPECIFIED OSHA PEL:0.005 PPM ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:VM&P NAPHTHA (SOLVENT) CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 4.959% Other REC Limits:NONE SPECIFIED OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:XYLENE (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1.950% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/STEL 150 PPM ACGIH TLV:100 PPM/STEL 150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOC: 3.485 LBS/GAL; 417.152 GRAMS/LITER RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES Health Hazards Acute and Chronic:ACUTE; IRRITATION TO SKIN, EYES, & RESPIRATORY TRACT (WATERING EYES, DRY THROAT, COUGHING, HEADACHE, TIGHT CHEST, BURNING SENSATION). HEADACHE, DIZZINESS, NAUSEA MAY BE EXPERIENCED BY SOME AS A RESULT OF EXPOSURE TO SOLVENTS. Explanation of Carcinogenicity:IARC HAS LISTED SILICA AS A PROBABLE HUMAN CARCINOGEN. Effects of Overexposure:CHRONIC: REPEATED & PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE, LIVER, & KIDNEY DAMAGE. RESPIRATORY SENSITIZATION (ASTHMA LIKE SYMPTOMS), SKIN SENSITI ZATION (RASH, ITCHING, HIVES, SWELLING OF THE EXTREMITIES). DERMATITIS. Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY AILMENTS; CHEMICAL SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. NOTIFY PHYSICIAN. EYES: FLUSH IMMEDIATELY WITH RUNNING WATER FOR AT LEAST 15 MIN, LIFTING EYELIDS. TAKE TO PHYSICIAN. SKIN: WASH AFFECTED AREAS WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING. WASH BEFORE REUSE. CONSULT PHYSICIAN IF IRRITATION DEVELOPS/PERSISTS. INGESTION: CALL A PHYSICAN OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:54.0F,12.2C Autoignition Temp:Autoignition Temp Text:450.0F Lower Limits:0.9 Upper Limits:8.2 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT WITH SELF-CONTAINED BREATHING APPARATUS. DURING FIRE, IRRITATING/HIGHLY TOXIC GASES & SMOKE PRESENT FROM DECOMP/COMBUSTION PRODUCTS. Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD.KEEP FROM HEAT/IGNIT SOURCE.CLSD CNTNR MAY EXPLODE W/HEAT,BURST W/WATER CONTAMINATN. DONT APPLY TO HOT SRFCS.NEVER CUT,WELD NEAR DRUM-EXPLOSIVE. ================== Accidental Release Measures ================== Spill Release Procedures:EVAC NON-ESSENTL PEOPLE.REMOVE IGNIT SOURCE.VENT.AVOID BREATHING.COVER SPILL W/INERT ABSORB.POUR LIQ DECONTAM OVER SPILLAGE-ALLOW 10 MIN REACT TIME.COLLECT MAT'L IN OPEN CNTNR ADD DECONTAM SOLUTION.CO VER LOOSELY.WASH DOWN AREA W/DECONTAM,FLUSH W/H20. Neutralizing Agent:0-10%AMMONIUM HYDROXIDE,2-5%DETERGENT & WATER.SOLUTN:TEGRITOL 20%TMN-10,80%WATER ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F OR BELOW 32F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED TO COMPLY WITH OSHA 1910.106. KEEP FROM SPARKS & OPEN FLAME. Other Precautions:KEEP CNTNR CLOSED. IF MOISTURE ENTERS, DONT RESEAL. DONT INGEST. GROUND CNTNRS WHEN POURING. AVOID LIQ FREE FALL >FEW INCHES. USE W/VENT & RESP EQUIP. EMPTIED CNTNRS MAY RETAIN HZD RESIDUE. FOLLOW PRE CAUTIONS. AVOID EYE, SKIN, CLOTH CONTACT ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AIRLINE RESPIRATOR UNLESS AIR SAMPLING SHOWS EXPOSURE TO BE BELOW PEL. THEN, EITHER CHEMICAL CARTRIDGE RESPIRATORS OR AIRLINE RESPIRATORS REQUIRED. USE SAME PRECAUTIONS DURING MIXING OR ANY OPERAT IONS WHERE PAINT FUMES WOULD BE PRESENT. Ventilation:GENERAL DILUTION/LOCAL EXHAUST TO KEEP BELOW PEL/TLV DURING MIXING, APPLICATION, CURING & REMOVE DECOMP PROD (WELD,CUT). Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN CONTACT AT A MINIMUM. Work Hygienic Practices:WASH HANDS AND ANY EXPOSED SKIN THOROUGHLY BEFORE EATING OR SMOKING. SMOKE IN DESIGNATED AREAS ONLY. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:244 TO 418F Decomp Temp:Decomp Text:400F,204C Vapor Pres:15.00 Vapor Density:> AIR Spec Gravity:1.22 Viscosity:65-68 KU Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE Solubility in Water:REACTS WITH WATER Appearance and Odor:OPAQUE LIQUID, SOLVENT ODOR Percent Volatiles by Volume:51.55 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ONCE MATERIAL HAS BEEN EXPOSED TO ANY OF THE ABOVE OR ATMOSPHERIC MOISTURE DONT SEAL CNTNR AS CO2 COULD BLDUP IN CNTNR. Stability Condition to Avoid:CONTAMINATION WITH WATER, EPOXY CATALYSTS, ALCOHOLS, GLYCOL ETHERS, BASES, METAL COMPLEXES OR OTHER ACTIVE MATERIALS. Hazardous Decomposition Products:CO2, CO, OXIDES OF NITROGEN, TRACES OF HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANATE. Conditions to Avoid Polymerization:SEE ABOVE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DECONTAMINATE CONTAINERS PRIOR TO DISPOSAL. ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:11010, TMC SOLVENT Preparer's Name:ROBERT M. EICHHORN CAGE:58225 CAGE:58225 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANE,1,1,2-TRICHLORO-1,2,2-TRIFLUORO-; (TRICHLOROTRIFLUOROETHANE) CAS:76-13-1 RTECS #:KJ4000000 OSHA PEL:1000 PPM, 1250 STEL ACGIH TLV:1000 PPM, 1250 STEL Ozone Depleting Chemical:1 Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) CAS:75-09-2 RTECS #:PA8050000 OSHA PEL:500 PPM; 1000, C ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 Ingred Name:SUPP DATA:CHLOROFLUOROCARBON (CFC) MATL HAVE PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:HAVE SIMILAR EFTS IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS OR CFC'S . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: THRU THE INTESTINAL TRACT. GIVE 2 GLASSES OF H*2O/ACTIVATED CHARCOAL SLURRY (50 GRAMS ACTIVATED (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:CHARCOAL IN 400 ML H*2O) NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. NOTE TO PHYS:BECAUSE OF POSS INCR(ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:RISK OF ELICITING CARDIAC DYSRYTHMIAS, CATECHOLAMINE DRUGS SUCH EPINEPHRINE, SHOULD BE CONSIDERED ONLY AS (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:LAST RESORT IN LIFE THREATENING EMERGENCIES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHAL: VAP IS HVR/AIR & CAN CAUSE ASPHY BY REDUCING O2 AVAIL FOR BRTHG. BRTHG HIGH CONC OF VAP MAY CAUSE LT-HEAD, GIDD, SHORT OF BRTH, NAUS, & MAY LEAD TO NARCOS, CARDIAC IRREG, UNCON/ DEATH. METHYLEN E CHLORIDE IS METABOLIZED TO CO RAISINGCARBOXY HEMOGLOBIN CONC IN BLOOD W/RSLTG SYMP OF CO POISONING (EFTS OF OVEREXP) Explanation of Carcinogenicity:METHYLENE CHLORIDE: GROUP 2B(IARC), ANTICIPATED TO BE CARCINOGEN (NTP). Effects of Overexposure:HLTH HAZ: SKIN: METHYLENE CHLORIDE IS CLASSIFIED AS AN IRRITANT. SKIN PERMEATION OF METHYLENE CHLORIDE CAN OCCUR IN AMTS CAPABLE OF PRDCG EFTS OF SYSTEMIC TOX. NOTE: IN SCREENING STUDIES W/EXPER ANIMA LS, EXPOSURE TO TRICHLOROTRIFLUOROMETHANE APPROX 5,000PPM(V/V) & ABOVE, FOLLOWED BY LG INTRAVENOUS (SUPP DATA) Medical Cond Aggravated by Exposure:SKIN DISEASE: TMC IS A DEFATTING AGENT. PERSONS W/PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS AGENT. CARDIOVASCULAR DISEASE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR, CALL PHYS. IF NOT BRTHG, GIVE ARTF RESP, PREF MOUTH TO MOUTH. IF BRTHG IS DFCLT, GIVE O2. DO NOT GIVE EPINEPHRINE/SIMILAR DRUGS. EYE: IMMED FLUSH W/PLENTY OF H2O FOR @ LST 15 MIN. CALL PHYS. SKIN: FLUSH W/H2O. GET MED ATTN IF IRRIT IS PRESENT. INGEST: CALL PHYS. DO NOT INDUCE VOMIT AS HAZ OF ASPIRATING MATL INTO LUNGS IS >HAZ THAN ALLOWING IT TO PROGRESS (ING 7) ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:NONE Extinguishing Media:NON-FLAMMABLE. MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DECOMPOSITION INTO HALOGEN ACIDS OR CARBONYL HALIDES. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE CHLORIDES, FLUORIDES, HCL & PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP SPILL ON ABSORBENT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE @ TEMPERATURES ABOVE 125F. AVOID BREATHING VAPORS & SKIN EXPOSURE. USE ONLY IN WELL VENTILATED AREAS. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIATION MAY CAUSE FORMATION OF CHLORIDES, FLUORIDES, HCL &/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNDER NORMAL MANFACTURING CONDITIONS NONE IS REQUIRED. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST-NORMAL VENTILATION IS GENERALLY ADEQUATE. MECHANICAL (GEN)-USE IN LOW PLACES. Other Protective Equipment:NONE. Work Hygienic Practices:NORMAL CARE. Supplemental Safety and Health EFTS OF OVEREXP:EPINEPHRINE CHALLENGE, HAS INDUCED SERIOUS CARDIAC IRREG. BASED ON ANIMAL STUDIES OF INDIVIDUAL COMPONENTS & HUMAN EXPER THIS MIX POSES NO HAZ TO MAN RELATIVE TO SYSTEMIC TOX, CARCINOG ENICITY, MUTAGENICITY OR TERATOGENICITYWHEN OCCUP EXPOS ARE BELOW ITS RECOM EXPOS LIM. CHLOROCARBON/ (ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:97.2F,36.2C Vapor Pres:4150@70F Vapor Density:4.9 Spec Gravity:1.42(H2O=1) Evaporation Rate & Reference:0.3(CC14=1) Solubility in Water:NIL Appearance and Odor:CLEAR LIQUID, SLIGHT SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS, POWDERED AL, ZN & BE, ETC. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HALOGEN ACIDS &/OR CARBONYL HALIDES. CHLORIDES, FLUORIDES, HCL & PHOSGENE . ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-C-43616,CLNG.CMPD,AIRCRFT SURFACE,CL I CAGE:MO694 CAGE:MO694 CAGE:3D863 ============= Composition/Information on Ingredients ============= Ingred Name:AROMATIC HYDROCARBON, HI-FLASH AROMATIC SOLVENT Fraction by Wt: <25% ACGIH TLV:100PPM ======================= First Aid Measures ======================= First Aid:SKIN/EYE CNTCT: FLUSH 15 MIN MINIM W/RUNNING WATER. IF IRRIT PERSISTS, CNTCT MD. ===================== Fire Fighting Measures ===================== Flash Point:145F TCC Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEM ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP W/RAGS, SAWDUST, ETC. PLACE IN APPRVD TYPE CNTNR. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHST, DESIRABLE Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:200F Spec Gravity:0.99 Solubility in Water:EMULSION Appearance and Odor:AMBER LIQ, SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE FED, STATE, LOCAL DISPOSAL REG
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DRIERITE 8 MESH, WITHOUT INDICATOR, 23893-7 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID, CALCIUM SALT (1:1); (CALCIUM SULFATE) (DRIERITE) CAS:7778-18-9 RTECS #:WS6920000 OSHA PEL:15MG/M3 TDUST;5RDUST ACGIH TLV:10 MG/M3 TDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL IF INHALED. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: IMMED FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MIN. SEEK MED ADVICE. SKIN:IMMED WASH W/SOAP & COPIOUS AMOUNTS OF WATER. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTF RESP. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGEST: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSICOUS. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEM POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPROVED RESPIRATOR, CHEMICAL PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENT AREA & WASH SPILL SIT E AFTER MATL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INHALATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PRLNGD/RPTD EXPOSURE. KEEP TIGHTLY CLOSED. HYDROSCOPIC. Other Precautions:STORE IN A COOL DRY PLACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:OFF-WHITE CHIPS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. CONTACT WITH DIAZOMETHANE VAPOR RESULTS IN EXOTHERM & MAY LEAD TO DETONATION. Stability Condition to Avoid:PROTECT FROM MOISTURE. Hazardous Decomposition Products:NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURY IN LANDFILL SITE APPROVED FOR THE DISPOSAL OF CHEMICAL AND HAZARDOUS WASTES. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PHOSPHORIC ACID CAGE:63415 CAGE:60777 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID (SARA III) CAS:7664-38-2 RTECS #:TB6300000 Fraction by Wt: 85% Other REC Limits:ACGIH STEL 3 MG/CUM OSHA PEL:1 MG/M3/3 STEL ACGIH TLV:1 MG/M3/3 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 15% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL-RAT 1530 MG/KG Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PHOSPHORIC ACID IS A SEVERE IRRITANT TO CORROSIVE TO EYES,SKIN,MUCOUS MEMBRANES. Effects of Overexposure:EYE:BURNS,IRRRITATION. SKIN:BURNS,IRRITATION. INHALED:EXPECTED ONLY IF PRODUCT IS MISTED (UNUSUAL CONDITION). IRRITATION RESPIRATORY TRACT,TEETH EROSION. INGESTION:BURNS,IRRITATION TO G/I TRACT,NAUSEA ,DISPNEA,VOMITING,COLLAPSE. Medical Cond Aggravated by Exposure:BREATHING MIST MAY RESULT IN AGGRAVATING BRONCHITIS, OR BRONCHIAL PNEUMONIA. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER. SKIN:WASH WITH SOAP & WATER. INHALED:REMOVE FROM EXPOSURE. GET MEDICAL ATTENTION. INGESTED:DILUTE BY DRINKING LARGE QUANTITIES OF MILK OR WATER. DO NOT INDUCE VOMITING. GET MEDIC AL ATTENTION. ACID MUST BE DILUTED 100:1 TO RENDER IT HARMLESS. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER SPRAY. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. AVOID BREATHING CORROSIVE VAPORS. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD ================== Accidental Release Measures ================== Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. RECOVER LIQUID IF POSSIBLE. ABSORB REMAINDER WITH SAND,VERMICULITE,ETC. PLACE IN CLOSED CONTAINERS FOR DISPOSAL. Neutralizing Agent:SODIUM BICARBONATE OR 50/50 MIX OF SODA ASH & SLAKED LIME. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:USE LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:IMPERVIOUS CLOTHING OR APRON TO PREVENT SKIN CONTACT. EYE WASH AND SAFETY SHOWER. Work Hygienic Practices:USE STRICT CHEMICAL HYGIENE PRACTICES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:266F/130C Melt/Freeze Pt:M.P/F.P Text:52F/11C Vapor Pres:0.03 @ 20C Spec Gravity:1.8 pH:ACID Solubility in Water:MISCIBLE Appearance and Odor:CLEAR COLORLESS LIQUID. ODORLESS. VISCOUS WHEN CONCENTRATED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES. CORROSIVE TO METALS. Stability Condition to Avoid:HIGH TEMPERATURE;MAY BURN,BUT WILL NOT READILY IGNITE. Hazardous Decomposition Products:TOXIC OXIDES OF PHOSPHORUS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SUPERMIL GREASE NO.A-72832. CAGE:15958 CAGE:15958 ============= Composition/Information on Ingredients ============= Ingred Name:DIESTER OIL (TAKE TLV AS OIL MIST) ACGIH TLV:5MG/CUM(OILMIST Ingred Name:LITHIUM SOAP THICKENER CAS:4485-12-5 RTECS #:WI4370000 ACGIH TLV:NOT SPECIFIED ===================== Hazards Identification ===================== Effects of Overexposure:PER MFR,NONE ILL EFFECTS EXPECTED;MAY IRRITATE EYES,SKIN OR RESPIRATORY TRACT PROLONGED CONTACT ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER SYMPTOMS OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL (B-C),CO*2,WATERFOG,FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA IN AN ENCLOSED AREA. Unusual Fire/Explosion Hazard:NONE NOTED ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;REMOVE ALL IGNITION SOURCES & CONTAIN;USE ABSORBENT MATERIAL AND RECOVER/PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY AND VENTILATED AREA.AVOID OPEN FLAMES/SPARKS.KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:AVOID CONTACT WITH SKIN AND EYES.DO NOT BREATHE MIST/VAPORS.WASH THOROUGHLY AFTER EACH USE.DO NOT USE CONTAMINATED CLOTHES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED SCBA/OR RESPIRATOR FOR ORGANIC VAPOR/MIST>TL Ventilation:MECH(GEN)OR LOCAL EXHAUST THAT PROVIDES ADEQUATE VENTILATION Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR PROLONGED CONTACT. Supplemental Safety and Health MSDS REVISED:AUGUST 1981:9150-00-223-4014 IS CANCELLED AS OF 66250;AND REPLACED BY 9150-00-985-7246 ================== Physical/Chemical Properties ================== HCC:V6 Solubility in Water:NEGLIGIBLE Appearance and Odor:LAVENDER COLORED,SMOOTH TEXTURED GREASE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HIGH TEMP,OPEN FLAMES,SPARKS Hazardous Decomposition Products:NONE NOTE BY THE MFR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF COLLECTED MATERIAL IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FEATHER PATCH, CM-0080 Preparer's Name:PETER FUQUA CAGE:HO842 CAGE:HO842 ============= Composition/Information on Ingredients ============= Ingred Name:PORTLAND CEMENT CAS:65997-15-1 RTECS #:VV8770000 OSHA PEL:10 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:0.1 MG/M3 RDUST ACGIH TLV:0.1 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHAL:CEMENT DUST CAN CAUSE INFLAMMATION OF THE LINING TISSUE OF NOSE & INFLAMMATION OF THE EYE. HYPERSENSITIVE INDIVIDUALS MAY DEVELOP A RASH ON THE SKIN. SKIN CONTACT:WET CEMENT, ESPECIALLY AS AN IN GREDIENT IN PLASTIC CONCRETE CAN DRY THE SKIN & CAUSE ALKALI BURNS. EYE CONTACT:CEMENT DUST CAN CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP 6TH ANNUAL REPORT ON CARCINS, (SUPDAT) Effects of Overexposure:HLTH HAZ:IRRITATION IN EYES & UPPER RESPIRATORY SYSTEM. Medical Cond Aggravated by Exposure:HYPERSENSITIVE INDIVIDUALS MAY DEVELOP A SKIN RASH. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTF RESP) . EYES:IRRIGATE W/WATER FOR AT LEAST 15 MINUTES & CONSULT MD. SKIN:WASH EXPOSED AREA W/PLENTY OF WATER IMMEDIATELY. INGEST: DO NO T INGEST, CONSULT MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP USING DRY METHODS THAT DO NOT DISPERSE THE DUST INTO THE AIR. AVOID BREATHING THE DUST. EMERGENCY PROCEDURES ARE NOT REQUIRED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:SHOULD BE STORED IN A DRY SHADED AREA. ELEVATED MATL TEMP ACCELERATES SETTING & THEREBY REDUCES WORKING TIME. Other Precautions:AVOID CONTACT W/EYES OR PROLONGED CONTACT W/SKIN. KEEP OUT OF THE REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR. (NIOSH/MSHA APPROVED DUST MASKS). Ventilation:AVOID BREATHING DUST. Other Protective Equipment:ANSI APPVD EMERGENCY EYE WASH & DELUGE SHOWER . IMPERVIOUS BOOTS & CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:GOOD HOUSEKEEPING PROCEDURES SHOULD BE FOLLOWED AT ALL TIMES. Supplemental Safety and Health EXPLAN OF CARCIN:1991:ANTICIPATED TO BE CARCINOGEN. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:0.7 (H2O=1) Solubility in Water:SLIGHT Appearance and Odor:POWDER W/NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . CAN BE TREATED AS COMMON WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEVELOPER FOR DC-211,213RE (RL-725RE) CAGE:8Z900 CAGE:8Z900 ============= Composition/Information on Ingredients ============= Ingred Name:PIGMENTS Fraction by Wt: 0.8% Ingred Name:THERMOPLASTIC POLYMER (TOTAL VEHICLE=9.1%) Ingred Name:FERRITE Fraction by Wt: 90.1% ===================== Hazards Identification ===================== Effects of Overexposure:NEITHER IRRITATING,CORROSIVE,VOLATILE NOR TOXIC. ======================= First Aid Measures ======================= First Aid:NORMAL WASHING W/SOAP & WATER. FLUSH EYES W/WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2,WATER,FOAM OR DRY CHEMICAL Unusual Fire/Explosion Hazard:NOTHING ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP W/A VACUUM CLEANER. ======================Handling and Storage ====================== Handling and Storage Precautions:CLOSE CAP TIGHTLY & STORE IN A DRY,COOL & DARK PLACE. DO NOT STORE NEAR COMBUSTIBLES OR HEAT SOURCES. AVOID INHALATION OF DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNNECESSARY (AVOID INHALATION OF DUST) Ventilation:UNNECESSARY Other Protective Equipment:UNNECESSARY Supplemental Safety and Health VAPOR PRESSURE & VAPOR DENSITY: N/A. ================== Physical/Chemical Properties ================== Spec Gravity:2.3 Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK & ODORLESS Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOTHING Hazardous Decomposition Products:NOTHING ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS DEVELOPER IS INSOLUBLE IN WATER. DO NOT FLUSH TO SEWER. ROUTE WASTE DEVELOPER FOR LANDFILL. WASTE DISPOSAL MUST BE IAW FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:REGULAR UNLEADED GASOLINE, CPS201186 CAGE:8X116 CAGE:8X116 ============= Composition/Information on Ingredients ============= Ingred Name:ING 24: OF THIS MATL THAT COULD REACH ANY SURF WATERS. TOLL FREE NUMBER FOR U.S. COAST GUARD NRC IS 1-800-424-8802. RTECS #:9999999ZZ Ingred Name:SPILL PROC:POLLUTANT; PVNT CONTAM OF SOIL & WATER & FROM ENTERING DRAIN & SEWER SYS. REGS REQ REPORTING SPILLS (ING 25) RTECS #:9999999ZZ Ingred Name:PENTANE; (N-PENTANE) CAS:109-66-0 RTECS #:RZ9450000 Fraction by Wt: >1% OSHA PEL:1000 PPM ACGIH TLV:600 PPM; 750 STEL Ingred Name:HEPTANE; (N-HEPTANE) CAS:142-82-5 RTECS #:MI7700000 Fraction by Wt: >1% OSHA PEL:500 PPM ACGIH TLV:400 PPM; 500 STEL Ingred Name:CYCLOHEXANE, METHYL-; (METHYLCYCLOHEXANE) CAS:108-87-2 RTECS #:GV6125000 Fraction by Wt: >1% OSHA PEL:500 PPM ACGIH TLV:400 PPM Ingred Name:BENZENE, TRIMETHYL- (MIXED ISOMERS); (TRIMETHYLBENZENE) CAS:25551-13-7 RTECS #:DC3220000 Fraction by Wt: >1% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:PENTANE, 2,2,4-TRIMETHYL-; (TRIMETHYLPENTANE-2,2,4) (CERCLA) CAS:540-81-1 RTECS #:SA3320000 Fraction by Wt: >1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHER, TERT-BUTYL METHYL; (METHYL TERT BUTYL ETHER (MTBE)) (SARA 313) (CERCLA) CAS:1634-04-4 RTECS #:KN5250000 Fraction by Wt: <15% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ETHER, TERT-BUTYL ETHYL; (ETHYL TERT BUTYL ETHER) (ETBE) CAS:637-92-3 RTECS #:KN4730200 Fraction by Wt: <18% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BUTANE, 2-METHOXY-2-METHYL; (TERT-AMYL METHYL ETHER; (TAME)) CAS:994-05-8 RTECS #:EK4421000 Fraction by Wt: <17% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHYL ALCOHOL; (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: <10% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:SUPDAT:APPETITE, WEAK & INCOORD. INHAL:SLIGHTLY TOX TO INTERNAL ORGANS. INHAL OF VAP AT CONCS >1000PPM MAY CAUSE(ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: CNS EFTS:HDCH, DIZZ, APPETITE LOSS, WEAK & INCOORD. >5000PPM: UNCON, COMA & DEATH. BRIEF EXPOS TO HIGH (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:VAP CONCS MAY CAUSE PULM EDEMA & BRONCH. INTENTIONAL ABUSE MAY RSLT IN CONVLS, DELIRIUM & HALLUCINATIONS.(ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: RESP TRACT IRRIT MAY INCL NASAL DISCHARGE, SORE THROAT, COUGH, BRONCH, PULM EDEMA & BRTHG DFCLTY. REFER (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: TO OSHA BENZENE STD (29 CFR 1910.1028) BEFORE USING PROD. CNTCT NEHC FOR MORE INFO ON HLTH HAZS . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: TREATMENT CTR/HOSPITAL. INHAL: IF SYMPS OCCUR, MOVE TO FRESH AIR. IF EFTS CONTINUE, SEE MD. (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22: NOTE TO MD: INGEST OF PROD/SUBSEQUENT VOMIT CAN RSLT IN ASPIR OF LIGHT HYDROCARB LIQ WHICH CAN CAUSE PNEUMIT. RTECS #:9999999ZZ Ingred Name:BUTANE; (N-BUTANE) CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: >1% OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:GASOLINE (CONTAINING INGREDIENTS 2-12 AND CAN CONTAIN INGREDIENTS 13-15 OR 16) CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: 100% OSHA PEL:300 PPM ACGIH TLV:300 PPM; 500 STEL Ingred Name:BENZENE (SARA 313) (CERCLA) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <4.2% OSHA PEL:N/K ACGIH TLV:10 PPM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE) (SARA 313) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: >1% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: >1% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: >1% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HEXANE; (N-HEXANE) (CERCLA) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: >1% OSHA PEL:500 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) >5 ML/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:TOLUENE APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO HAZS. CONSULT APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST & SAFE HNDLG & EXPOS INFO . EYES:SLIGHT IRRIT & COULD CAUSE PRLNGD VISION IMPAIRMENT. SYMPS INCL PAIN, TEARS, SWELL, REDNESS & BLURRED VISION. CNTCT W/VAPS, FUMES OR SPRAY MIST (EFTS OF OVEREXP) Explanation of Carcinogenicity:GASOLINE:IARC MONO, VOL 45, PG 159, 1989:GRP 2B. BENZENE:IARC MONO, SUPP, VOL 7, PG 120, 1987:GRP 1. NTP 7TH (SUPDAT) Effects of Overexposure:HLTH HAZ: COULD CAUSE SIMILAR SYMPS. SKIN:MOD IRRITANT & COULD CAUSE PRLNGD INJURY. SYMPS MAY INCL PAIN/FEELING OF HEAT, DISCOLORATION, SWELL & BLISTERS. PRACTICALLY NON-TOX IF ABSORBED. PRLNGD/RPTD C NTCT MAY CAUSE CRACKED/DRY SKIN. INGEST:SLIGHTLY TOX TO INTERNAL ORGANS. NERVOUS SYS IS TARGET ORGAN. CAN ENTER (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH IMMED W/FRESH WATER FOR AT LST 15 MIN WHILE HOLDING LIDS OPEN. REMOVE CNTCT LENSES. IF IRRIT PERSISTS, SEE MD. SKIN:REMOVE CONTAM CLTHG. WASH SKIN THOROUGHLY W/SOAP & WATER. SEE MD IF SYMPS OCCUR. INGEST:GIVE WATER/MILK TO DRINK& CALL FOR MED ADVICE. DO NOT MAKE PERSON VOMIT UNLESS DIRECTED BY MED PERS. IF ADVICE CANNOT BE OBTAINED, TAKE PERSON & PROD TO NEAREST MED EMER (ING 22) ===================== Fire Fighting Measures ===================== Flash Point:<-49F,<-45C Lower Limits:1.4% Upper Limits:7.6% Extinguishing Media:FIRE FIGHTING FOAM: ALCOHOL RESISTANT TYPE (AR) AFFF, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NORMAL COMBUSTION FORMS CARBON DIOXIDE AND WATER VAPOR; INCOMPLETE COMBUSTION CAN PRODUCE CARBON MONOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIM IGNIT SOURCES. CLEAN UP IMMED OBSERVING PRECS. FOR SM SPILLS USE APPROP TECHNIQUES SUCH AS SORB MATLS/PUMPING. WHERE FEASIBLE & APPROP REMOVE CONTAM SOIL. FOLLOW PROCS FOR REPORTING & RESPONDING TO LARGER RELS. MATL CONSIDERED WATER (ING 24) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT USE/STORE NEAR FLAME, SPKS/HOT SURFS. KEEP CNTNR CLSD. DO NOT TRANSFER LIQ TO UNLABELED CNTNR. DO NOT WELD/HEAD/DRILL CNTNR. REPLACE CAP/BUNG. Other Precautions:EXTREME FIRE HAZ. LIQ EVAPS VERY QUICKLY EVEN AT LOW TEMPS & FORMS VAP (FUMES) WHICH CATCH FIRE & BURN W/EXPLO VIOLENCE. INVISIBLE VAP SPREADS EASILY & CAN BE SET ON FIRE BY MANY SOURCES. EMPTIED CNTN R STILL CNTNS HAZ OR EXPLO VAP OR LIQ. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPEC RESP PROT NORMALLY REQD. HOWEVER, IF OPERATING CNDTNS CREATE AIRBORNE CONCS WHICH EXCEED RECOM EXPOS STDS, USE OF NIOSH APPRVD RESP REQD. REFER TO OSHA BENZENE STD TO DETERM TYPE OF RESP REQD BASED ON EXPOS LEVELS. Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . AVOID PRLNGD/FREQUENTLY RPTD SKIN CNTCT; MINIMIZE BY WEARING PROT CLTHG. Work Hygienic Practices:NEVER SIPHON GAS BY MOUTH. USE ONLY AS MOTOR FUEL. READ & OBSERVE ALL LABEL PRECS. DO NOT GET MATL IN EYES. Supplemental Safety and Health VP: 5-15 PSI (MAX) @ 100F (VARIABLE). EXPLAN OF CARCIN: ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE CARCIN. OSHA REGULATED:CFR 29 1910.1028. EFTS OF OVEREXP: LUNGS DIRECTLY (ASPIR) DURING SWALLOW/VOMIT. O NCE IN LUNGS VERY DFCLT TO REMOVE & CANCAUSE SEV INJURY & DEATH. SYMPS OF INGEST MAY INCL HDCH, DIZZ, LOSS OF (ING 17) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>77F,>25C Vapor Pres:SUPDAT Vapor Density:3-4 Spec Gravity:0.7-0.8 Solubility in Water:INSOLUBLE Appearance and Odor:ORANGE TO BRONZE LIQUID. Percent Volatiles by Volume:99+ ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT WITH STRONG OXIDIZING AGENTS SUCH AS CHLORATES, NITRATES, PEROXIDES, ETC. Stability Condition to Avoid:NO DATA AVAILABLE. Hazardous Decomposition Products:NO DATA AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS. MAY MEET CRITERIA OF HAZ WASTE UNDER RCRA/OTHER STATE & LOC REGS. MEASUREMENT OF PHYSICAL PROPERTIES & ANALYSIS MAY BE NEC TO MAKE DETERMINATION. IF HAZ , FED LAW REQS DISP AT LICENSED HAZ DISP FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DREMEL 500 8111 BROWN TRIPOLI ROUGE CAGE:IO588 CAGE:84563 CAGE:IO588 ============= Composition/Information on Ingredients ============= Ingred Name:TRIGLYCERIDES CAS:61789-97-7 Fraction by Wt: 12% OSHA PEL:15 MG/M3 (MFR) ACGIH TLV:10 MG/M3 (MFR) Ingred Name:TALLOW; (TALLOW GLYCERIDES) CAS:67701-27-3 Fraction by Wt: 11% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PARAFFIN; (PETROLATUM) CAS:8002-74-2 RTECS #:RV0350000 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TRIPOLI CAS:7631-86-9 Fraction by Wt: 72% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE COUGH, SHORT OF (DUST) BRTH. CHRONIC: MAY AFFECT BRTHG CAPACITY (DUST). INGEST: NO KNOWN ADVERSE EFTS, BUT INGEST NOT RECOMM. SKIN CONT & ABSORP: IRRIT OF SKIN MAY OCCUR DUE TO MECH/CHEM ACTION. EYE: DUST MAY IRRITATE. OTHER POTNTL HLTH RISKS (PRLNGD INHAL OF DUST PARTICLES MAY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: RSLT IN DISABLING PULM FIBROSIS). SYMPS MIGHT INCL DEPOSITS OF MATLS IN EYES, EARS, NASAL PASSAGES, IRRIT OF MUC MEMB. WARNING: DO NOT BREATHE DUST OF CMPDS CNTNG ABRASIVE MATLS W/OUT FOLLOW ING OSHA SFTY & HLTH STD FOR DUST ACCUMULATION COLLECTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. APPLY ARTF RESP AS NEEDED. OBTAIN FIRST AID/MED ASSISTANCE. INGEST: OBTAIN FIRST AID OR MED ASSIST, IF NEEDED. SKIN: OBTAIN FIRST AID/MED ASSIST, IF NEEDED. EYE: WASH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, OBTAIN FIRST AID OR MED ASSIST, IF NEEDED. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>300F,>149C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL/FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . TREAT BUFFING DEBRIS, DUST, DIRT AS AN OIL FIRE. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP INTO CONTAINERS. STORAGE OF BUFFING WHEEL AND COMPOUND DEBRIS MAY CONTAIN COMBUSTIBLE LINT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE W/ADEQUATE VENTILATION FOR NUISANCE DUST WHEN USING. SEE OSHA CFR 1910.24 (VENT) & 29 CFR 1910.1000 (AIR CONTAM). Other Precautions:KEEP LIQUIDS FROM FREEZING. STORE AWAY FROM EXCESSIVE HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OSHA 24 CFR/134 NIOSH/MSHA APPROVED RESPIRATOR FOR PARTICULATES FROM BUFFING DEBRIS. Ventilation:LOCAL EXHAUST: GENERAL ROOM VENTILATION. MECHANICAL(GENERAL): RECOMMENDED VENTING TO DUST COLLECTORS. Other Protective Equipment:PROTECTIVE WORK CLOTHING, BODY APRON OR BELLY PADS, SAFETY SHOES, AS NEEDED. HEARING PROTECTION. OSHA 29CFR1910.122. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>250F,>121C Melt/Freeze Pt:M.P/F.P Text:135F,57C Spec Gravity:1.5 Evaporation Rate & Reference:NONE Solubility in Water:NEGLIGIBLE Appearance and Odor:CAKE FORM/BROWN COLOR/TALLOW ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS OR REDUCING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:ON COMBUSTION HYDROCARBONS MAY FORM TO PRODUCE SMOKE, CARBON MONOXIDE, CARBON DIOXIDE. Conditions to Avoid Polymerization:USING UNDER CONDITION OF INSUFFICIENT DUST COLLECTING SYSTEM. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-P-115 F TYPE I CLASS I LEAD-FREE YELLOW CAGE:KO024 CAGE:KO024 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM NAPHTHA (SARA 313) CAS:64742-89-8 Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:100 PPM Ingred Name:TOLUENE (TOLUOL) (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 4-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 Other REC Limits:NONE RECOMMENDED ACGIH TLV:10 MG/M3 Ingred Name:PERCHLOROETHYLENE (CERCLA) CAS:127-18-4 RTECS #:KX3850000 Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ACETONE (SARA 313) (CERCLA) CAS:67-64-1 RTECS #:AL3150000 Other REC Limits:NONE RECOMMENDED OSHA PEL:750 PPM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ORGANO MONTMORILLIONITE (NON-HAZARDOUS INGREDIENTS) Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT Ingred Name:SOYBEAN OIL RESIN SOLIDS (NON-HAZARDOUS INGREDIENTS) Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT Ingred Name:HANSA YELLOW X (NON-HAZARDOUS INGREDIENT) Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: STINGING, TEARING, REDNESS, SWELLING. SKIN: DRYNESS, IRRIT. INHAL: NASAL AND RESPIRATORY IRRIT, DIZZY, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUS, DEATH. INGEST: GI IRRIT, NAUSEA, VOMIT. AS PIRATION INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. CHRONIC: INHAL: LIVER/KIDNEY/BRAI DAMAGE. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER. SKIN: WASH W/SOAP AND WATER. WASH CLOTHES BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. INGEST: DONT INDUCE VOMIT. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:40.0F,4.4C Lower Limits:1.0 Upper Limits:7.0 Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL AND HALON. Fire Fighting Procedures:USE SCBA W/FULL-FACE PIECE OPERATED IN PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:KEEP AWAY FROM HEAT SOURCES. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG GROUND. EMPTY CONTAINERS (W/RESIDUE) ARE FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP W/ABSORBENT MATERIAL AND DEPOSIT IN A SAFE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:DONT PUT EMPTY OR FULL CONTAINERS NEAR ANY HEAT SOURCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED SCBA. Ventilation:LOCAL EXHAUST OR MECHANICAL (GENERAL) Other Protective Equipment:IMPERVIOUS CLOTHES AND SHOES Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:200 TO 210F Melt/Freeze Pt:M.P/F.P Text:LIQUID Vapor Pres:50 TO 60 Vapor Density:3.00-4.00 Spec Gravity:1.45-1.55 Evaporation Rate & Reference:2-3 (BUAC)=1 Solubility in Water:NEGLIGIBLE Appearance and Odor:YELLOW, PETROLEUM ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:IN POSTED TOXIC LANDFILL ACCORDING TO STATE, LOCAL AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PHOSPHOLIPASE C TYPE XIV FROM C.PERFRINGENS CAGE:21076 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHOLIPASE C CAS:9001-86-9 RTECS #:SZ6116000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. EXPOSURE CAN CAUSE GI DISTURBANCES. PROLONGED OR REPEATED EXPOSURE MAY CAUSE ALLERGIC REACTIONS IN CERTAIN SENSITIVE INDIVIDUALS. THETOXICOLOGICAL PROPERTIES HAVE NOT BEENTHOROUGHLY INVESTIGATED. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD. SKIN:FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES AND CALL MD. INHAL:REMO VE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT, CALL MD. EYE: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING EYELIDS W/FINGERS. CALL MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATER IAL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT AND INHALATION. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:PROTECTIVE CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE, AND LOCAL LAWS.
1
eyes_protection_mandatory