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Identification of the Company-producer or Company-supplier Producer or Supplier Mail address Contact telephone Fax e-mail RUE “PA “Belaruskali” Republic of Belarus, 223710, city of Soligorsk, Minsk region, Korzha street, 5 + 375 (174) 298677, + 375 (174) 298501 + 375 (174) 298432 (for extra consultations) + 375 (174) 298677 info@kali.by 3. Identification and Origin of Hazard.
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Identification and Origin of Hazard. Influence on a human Common influence Ways of contact Most injured internal organs and systems of a human Moderately hazardous influence on a human. Do not form toxic compounds in air. Operations with Muriate of Potash are radiation safe. Can irritate skin, eyes and upper respiratory tract.
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Aerosol inhalation, wet skin or eye contact, ingestion Nervous, respiratory and cardiovascular systems, gastrointestinal tract, liver, kidneys, electrolyte metabolism, skin, eyes Muriate of Potash SDS BY No. 600122610.001 – 2008 Page 4 Symptoms observed: In mild cases In acute cases Clinical presentation of acute poisoning Respiratory tract, skin and eyes irritation Weakness, motion activity reduction, throat scratching, coughing, disturbance of breathing.
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In acute cases of high doses swallowing – burning pain in oral cavity. Nausea, vomiting, stomach pain, diarrhea, disturbance of heartbeats, dystaxia, convulsions. Influence on environment (air, water, soil) Common influence Influence on environment Influence observed Hygienic norms (MAC in working area, water, soil) In case of skin contact In case of eye contact In case of swallowing The product does not change its properties in the environment. Possible air, soil and water pollution.
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Possible air, soil and water pollution. Improper handling, transportation and storage. Exceeding the agricultural chemistry rates of fertilizers application. Can influence the environment in case of emergency. Change of organoleptic properties of water (foreign taste)/ MAC w.a.
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– 5 mg/m3 hazard class 3 MAC atm.air, one-time – 300 mkg/ m3 MAC daily average – 100 mkg/m3 MAC annual average – 50 mkg/ m3 , resorptive hazard class 4 MAC service water (chloride anion Cl-) - 350 mg/l, organic taste, hazard class 4 MAC soil (by KCl) - 360 mg/kg, water migrated. MAC fishery potash-ion 50,0 mg/dm3 ,sanitary and toxic; for sea water basins 390 mg/l at 13-18%; toxic; MAC fishery chloride - ion – 300 mg/ dm3, sanitary – toxic, for sea water basins 11900 mg/l at 12-18%; toxic.
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Rinse thoroughly with running water Rinse thoroughly with plenty of water. Rinse the stomach with plenty of warm water mixed with activated charcoal (1g/kg of body weight). Ask for medical assistance if necessary. 4. First-Aid Measures In case of respiratory tract irritation Contra-indications First-Aid means Take the injured person outside, provide warm and piece. No information Activated charcoal In case of acute poisoning use calcium containing preparations. Muriate of Potash SDS BY No.
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Muriate of Potash SDS BY No. 600122610.001 – 2008 Page 5 5. Fire-Fighting Measures Fire risk Common characteristics of fire and explosion hazards Recommended fire-fighting means Forbidden fire-fighting means Personal protective measures and equipment (firemen and personnel protective measures) Possibility of thermal decomposition Fire and explosion-proof Non-reachable For packages (PP-bags) use any type of extinguishers, water or sand.
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No information Fire-protective uniform and safety device in accordance with TNLA No 6. Accidental Release Measures. Preventive measures Common recommendations Handling and storage Personal protection Environmental protection Utilization and disposal of waste Transportation Disposal measures Necessary usual measures Aspiration on reloading points. Ventilation of the production rooms. Air control. Avoid inhalation of aerosol. Store in warehouses protected from atmospherical condensation.
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Avoid inhalation, eye and skin contacts. Use personal protective devices. Avoid dispersion in air, penetration in sewerage, subsoil and surface waters and soil in concentration exceeding the limits (see section 12 of Safety Data Sheet) See section 13 of Safety Data Sheet Muriate of potash is transported either in bulk or in packages. Material packed in bags is transported by all transport means; material packed in containers is transported in open type railway wagons.
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(see section 14 of Safety Data Sheet). Isolate a dangerous zone, send all unauthorized persons away of accident area, if necessary send them for medical checkup. Leakage and spillage: Collect the product in a dry way and take it out to a covered storehouse or to a site protected from moisture and atmospheric precipitation for further use as fertilizer. Prevent the product from entering into water courses and drains. Fires: Take out undamaged packs from the fire area if it is not dangerous.
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Extinguish the fire from maximal distance. Personal and group protection means: See SDS, Section 8. Muriate of Potash SDS BY No. 600122610.001 – 2008 Page 6 Emergency recovery: Put polluted residues of the product into special containers, paper or polypropylene bags and remove it to industrial wastes dump. Wash the area with water. Avoid the release of washing water into water courses and soil. 7.
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7. Handling and Storage Personal and group protection measures: Suction-and-exhaust ventilating of working areas. Regular control of maximal allowable concentration of the product in air of working areas. Use personal protective equipment. Timely clean working areas; move away the spilled product; avoid dusting when packaging the product. Storage conditions: Product to be stored in closed warehouses, protected from atmospheric precipitation and ground water.
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Product packed in big-bags can be stored at open areas with hard surface and under shed. Store at ambient temperatures. Storage period: Guarantee period – 6 months since manufactured (GOST 4568). Guarantee period of MOP for retail trade – 24 months since manufactured (GOST 4568). Guarantee period – 1 year since dispatched (STO SPEKS 001). Incompatible substances: Organic substances, acids and alkalies.
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Product transportation recommendations: Avoid product spillages during bulk transportation by rail and water. See section 14. Materials recommended for safety packaging: Specialized big-bags, polypropylene bags with polyethylene inserts. 8. Exposure Control/Personal Protection Working areas parameters to be unconditionally controlled: MAC in w.a.
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– 5 mg/m3 Measures to assure the allowable concentration of harmful substances: Installation and maintenance of failure-free operation of exhaust ventilation system and corresponding devices of dust collecting. Control of KCl aerosol content in working areas air. Mechanization of transport, prepackaging and packaging operations. Muriate of Potash SDS BY No. 600122610.001 – 2008 Page 7 Personal protection General recommendations: Use safety clothing and shoes to avoid direct contact with product.
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Respiratory protection: Dust respirators according Eye protection: Safety glasses according Safety clothing: Special clothing according 9. Physical and chemical Appearance: properties Fine product in small crystals from grayish-white to reddish- brown colour. Granules of irregular form from grayish-white to reddish- brown colour. Odour: Odourless.
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Odour: Odourless. Molecular mass: 75,543 Melting temperature: 768-776°C Boiling temperature: 1406-1430°C Thermal capacity: 0,16 cal/(g·°C) Density of single crystals: 1,98-1,99 g/cm3 pH: 5,5-8,8 (50000 mg/l of water) Water solubility, mg/l H2O 330000-342000 (20°C) 560000-562000 (100°C) Solubility in other solvents Slightly soluble in liquid ammonia and ethanol. Insoluble in most organic solvents and fats. 10.
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Insoluble in most organic solvents and fats. 10. Stability and reactivity Stability Chemically stable substance Reactivity Reacts with acids and alkalies. Substances to avoid: Organic substances, acids, alkalies. Hazardous decomposition products: None Useful agrochemical life: Not limited. 11. Toxicological information: Human exposure Moderately hazard substance.
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Ingestion toxicity (mg/kg) (tested animals: white rats) Toxicity Test data DL16 690 mg/kg DL50 744 vg/kg DL84 810 mg/kg Muriate of Potash SDS BY No. 600122610.001 – 2008 Page 8 Concentration of minimal toxicity (effect thresholds, their dimensionality, way and time of injection, type of animals, humans): MChr-10 mg/m3 (neuromuscular irritability effect).
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EC-51-152 mg/m3, inh., 6 months, rats (decline in body weight increase, increase in neuromuscular irritability, potassium and chlorine concentration, cholinesterase activity, reduction of sodium concentration in blood) ED-60 mg/kg, intra-stomach,1 day, woman (nausea, vomiting, blood coagulation failure). Information on dangerous remote effects of human exposure (influence on reproduction function, carcinogenicity, accumulation capacity, irritability etc. ): Skin-resorbtive and sensibilizing actions.
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): Skin-resorbtive and sensibilizing actions. Mutagenicity: not confirmed by IARC (International Agency for Research on Cancer). Embryotropic, gonadotropic, teratogenic and cancerogenic effects have not been not studied. Not cumulative in terms of mortality effects evidence (cumulation coefficient: > 5), shows general toxicological nature of action with changes mostly in functional state of liver, nephroses and circumferential blood system.
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Moderately irritates eyes mucosa and classified as grade 2 in terms of irritant action intensity. 12. Ecological information Evaluation of possible ecological effect (air, soil, water, biota) Can pollute the environment in case of violation of storage and transportation rules. Extremely stable in abiotic conditions. Destructive for water organisms. Most important characteristics of influence on environment Hygienic regulations (MAC of product in atmospheric air, water, soil) MAC w.a.
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– 5 mg/m3, hazard class 3 MAC atm.
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air, one-time - 300 mkg/m3, MAC daily average – 100 mkg/m3, MAC annual average - 50 mkg/m3, resorptive, hazard class 4, MAC service water (chloride anion Cl–) – 350 mg/l, organic taste, hazard class 4 MAC soil (by KCl) – 360,0 mg/kg water migrated Ecotoxicity indices Acute toxicity for fish CL50 (mg/k) Species Exposure time (h) 2300 Leuciscus idus 48 373 Phoxinus phoxinus 12-29 10000 Gambusia affinis 24 4200 Gambusia affinis 48 74,6 Diplodus cervinus 4,5-15,0 Muriate of Potash SDS BY No.
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600122610.001 – 2008 Page 9 2010 Lepomis macrochirus 96 5500 Lepomis macrochirus 24 12500 Cyprinus carpio 5 Transformation in environment No transformation. 13. Disposal Considerations Safety measures when handling waste material generated as the result of utilization, storage, transportation, emergencies, etc: Same safety measures as for product handling (see sections 6 and 7 of Safety Data Sheet).
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Information on places and methods of treatment, recycling and disposal of product wastes, including packing: Spilled muriate of potash can be used as normal product. Empty packages are to be recycled at public waste disposal sites. 14.
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14. Transportation information Transport name (subject to type range): Various types of muriate of potash Means of transportation: Goods transportation is effected in accordance with the rules valid for a corresponding mean of transportation Hazard classification: Product is not classified as dangerous, it is not within the rules of GOST 19433; but when transported by inland water ways the product being a corrosive substance of low effect is classified as dangerous (hazard class 9.1).
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Appropriate marking is not required. Transport marking: Transport marking is made according to GOST 14192 with application of the sign “Keep dry”, and the sign “Protect from the sun” is applied if packages are made from polymeric materials. Emergency card: Not required. Hazard information when transported by railway: Danger code is not determined. Muriate of Potash SDS BY No. 600122610.001 – 2008 Page 10 15.
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600122610.001 – 2008 Page 10 15. Regulatory information National legislation Laws of the Republic of Belarus “Environment Protection Act” “Consumers Protection Act” “Plants Protection Act” Documents controlling the humans and environment requirements (certificates): Certificates of conformity. International legislation Warning marking (danger symbols, risk level, etc): Safety factor: S:22-24/25. Do not inhale the product aerosol. Avoid all contacts with eyes and skin. 16.
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Avoid all contacts with eyes and skin. 16. Other information Use recommendations Used as fertilizer for direct soil application, as well as raw material for dry blinding while chemical products producing. Use restrictions: No restrictions.
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Interim Secretariat for the Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade PIC CIRCULAR X - December 1999 CONTENTS 1. THE PURPOSE OF THE PIC CIRCULAR …………………..……………………. 2. IMPLEMENTATION OF THE INTERIM PIC PROCEDURE …………………… 2.1 Designated national authorities ………………………………………………..…….
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2.2 Notifications of final regulatory action to ban or severely restrict a chemical……… 2.3 Proposals for inclusion of severely hazardous pesticide formulations received under the interim PIC procedure ……………………………………………………. 2.4 Chemicals subject to the interim PIC procedure and distribution of decision guidance documents (DGDs) …………………………………………….
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2.5 Transmittal of a response concerning future import of a chemical ………………… 2.6 Information on responses received concerning future import of a chemical……….. 2.7 Information on transit movements ………………………………………………….. 3. ADDITIONAL INFORMATION FOR DNAs …….……………………………… 3.1 Information on status of signature and ratification of the Convention …………….. 3.2 Documents available under the interim PIC procedure …………………………….
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Appendices I. Synopsis of notifications of final regulatory action received under the interim PIC procedure ….…………………………….…………………………. II. Proposals for inclusion of severely hazardous pesticide formulations received under the interim PIC procedure ….………………………….……………………... III. Chemicals currently subject to the interim PIC procedure …….……………….…... IV. Listing of all importing country responses received from Parties as of 30 November 1999 ……………………………………………………….…………….
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V. Synopsis of notifications of control actions received before 11 September 1998 under the original PIC procedure ……………………………….…………………... 1 2 2 2 3 3 3 3 4 4 4 5 6 7 8 11 147 1. THE PURPOSE OF THE PIC CIRCULAR The Conference of Plenipotentiaries, held in Rotterdam on 10 and 11 September 1998, adopted the text of the Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals in International Trade.
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The Conference also considered that interim arrangements were required to continue to operate a voluntary PIC procedure, in order to protect human health and the environment from certain hazardous chemicals and pesticides, pending the entry into force of the Convention and to prepare for its effective operation once it enters into force.
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The Conference, therefore, changed the original, voluntary procedure to bring it into line with the procedure established by the Convention with effect from the date on which the Convention was opened for signature (11 September 1998). The original PIC procedure with these changes is hereinafter referred to as the "interim PIC procedure".
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PIC CIRCULAR X December 1999 2 The purpose of the PIC Circular is to provide all Parties1, through their designated national authorities (DNAs), with the information required to be circulated by the Secretariat under the interim PIC procedure, in line with Articles 4, 5, 6, 7, 10, 11 and 14 of the Convention. However, the decision guidance documents to be dispatched to Parties1 in line with Article 7, paragraph 3, are sent out in a separate communication.
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The PIC Circular will be published every six months, in June and December. 2. IMPLEMENTATION OF THE INTERIM PIC PROCEDURE 2.1 Designated national authorities (in line with Article 4 of the Convention) In line with Article 4, paragraph 4 of the Convention, the Secretariat shall inform the Parties1 of new nominations or changes in nominations of designated national authorities (DNAs).
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Since the last PIC Circular was distributed in June 1999, five States (Czech Republic, Democratic People’s Republic of Korea, Guinea Bissau, South Africa, Holy See) have nominated, for the first time, a DNA for participation in the interim PIC procedure, two States (Chile, Portugal) have nominated additional DNAs, while 12 States have provided changes (Australia, Bahrain, Belize, Costa Rica, Egypt, Indonesia, Netherlands, Peru, Rwanda, St. Vincent, Syria, Venezuela).
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A complete list of DNAs under the interim PIC procedure is being distributed together with the present Circular. 2.2 Notification of final regulatory action to ban or severely restrict a chemical (in line with Article 5 of the Convention) In line with Article 5, paragraph 3 of the Convention, the Secretariat is to circulate summaries of notifications of final regulatory action received, and which the Secretariat has verified contain the information required by Annex I of the Convention.
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In line with Article 5, paragraph 4 of the Convention, the Secretariat is to circulate a synopsis of the notifications of final regulatory action received, including information regarding those notifications that do not contain all the information required by Annex I of the Convention.
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Such a synopsis of notifications received under the interim PIC procedure, including the summaries of the notifications the Secretariat has verified contain the information required by Annex I of the Convention and information regarding those notifications that have been verified not to contain all the information required by said Annex, is provided as Appendix I, parts A and B of this Circular.
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Parties1 that have submitted notifications, which are still under verification by the Secretariat, are listed in Appendix I, part C of this Circular. A synopsis of the notifications of control actions received before 11 September 1999 under the original PIC procedure, including information regarding those notifications that do not contain all the information required by Annex I of the Convention, is provided as Appendix V of this Circular.
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Please note that a new form for notification of final regulatory action to ban or severely restrict a chemical (UNEP/FAO/PIC/FORM/1/E/4-99) was sent to all DNAs in June 1999. DNAs are kindly requested not to use the old form circulated to them under the original PIC procedure. When a submission is made, the date of issue, signature of the DNA and official seal must be provided for each individual form to ensure its legal status.
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1 During the interim period before the Convention enters into force, a "Party" is understood to mean any State or regional economic integration organization having nominated a designated national authority or authorities for the purpose of participating in the interim PIC procedure.
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PIC CIRCULAR X December 1999 3 2.3 Proposals for inclusion of severely hazardous pesticide formulations received under the interim PIC procedure (in line with Article 6 of the Convention) In line with Article 6, paragraph 2 of the Convention, the Secretariat is to circulate summaries of those proposals for inclusion of severely hazardous pesticide formulations in the interim PIC procedure, which the Secretariat has verified contain the information required by part 1 of Annex IV of the Convention.
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Such summaries are provided as Appendix II, part A of this Circular. Parties1 that have submitted proposals, which are still under verification by the Secretariat, are listed in Appendix II, part B of this Circular. When a submission is made, the date of issue, signature of the DNA and official seal must be provided for each individual proposal to ensure its legal status.
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2.4 Chemicals subject to the interim PIC procedure and distribution of decision guidance documents (in line with Article 7 of the Convention) Appendix III of this Circular lists all chemicals that are currently subject to the interim PIC procedure and the date of first dispatch of the corresponding decision guidance document (DGD) to DNAs. To date, there are 19 pesticides, five severely hazardous pesticide formulations and five industrial chemicals.
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These include the chemicals binapacryl and toxaphene for which the INC, at its 6th session in July 1999, adopted the corresponding decision guidance documents, with the effect that these two chemicals are now subject to the interim PIC procedure. The Secretariat dispatched the DGDs for binapacryl and toxaphene on 1 September 1999 to all Parties1, through their DNAs.
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2.5 Transmittal of a response concerning future import of a chemical (in line with Article 10, paragraphs 2, 3 and 4 of the Convention) In line with Article 10, paragraph 2 of the Convention, each Party1 shall transmit to the Secretariat, as soon as possible, and in any event no later than nine months after the date of dispatch of the DGD, a response concerning the future import of the chemical concerned.
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In line with Article 10, paragraph 4 of the Convention, the response shall consist of either a final decision or an interim response. The interim response may include an interim decision regarding import. Please note that a new form for importing country response (UNEP/FAO/PIC/FORM/2/E/4- 99) was sent in June 1999 to all DNAs. DNAs are kindly requested not to use the old form circulated to them under the original PIC procedure.
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When a submission is made, the date of issue, signature of the DNA and official seal must be provided for each individual form to ensure its legal status. In line with Article 10, paragraph 2 of the Convention, if a Party1 modifies this response, the DNA shall forthwith submit the revised response to the Secretariat.
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In line with Article 10, paragraph 3 of the Convention, the Secretariat shall, at the expiration of the time period given in Article 10, paragraph 2, forthwith address to a Party1 that has not provided such a response, a written request to do so, through its DNA. Where the phrase “case of failure to transmit a response” is listed in Appendix IV for a Party1, the DNA should consider this to represent the written request for that Party1 to provide a response according to Article 10, paragraph 3.
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2.6 Information on responses received concerning future import of a chemical (in line with Article 10, paragraph 10 and Article 11, paragraph 2 of the Convention) In line with Article 10, paragraph 10 of the Convention, the Secretariat shall, every six months, inform all Parties1 of the responses received regarding future import, including a description PIC CIRCULAR X December 1999 4 of the legislative or administration measures on which the decisions have been based, where available, and information on cases of failure to transmit a response.
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A listing of all importing country responses received from Parties1 as of 30 November 1999 is provided as Appendix IV. Please note that any response not addressing importation is considered as an interim response that does not contain an interim decision. Considerable efforts have been made by the Secretariat to ensure that the information included in this compilation of import responses is both complete and accurate.
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DNAs are requested to review the entries for their country and to bring any errors or omissions to the attention of the Secretariat as soon as possible. Parties1 that had nominated a DNA by 11 September 1998, but had not provided an import response for the 27 chemicals subject, at that time, to the interim PIC procedure by 30 May 1999, were identified in Circular IX (dated 12 June 1999) as having failed to transmit a response for those chemicals.
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In addition to the above, each Party1 that has failed to transmit an import response for a chemical listed in Appendix III of this Circular within 9 months of the date of dispatch of the DGD to the Party1, through the DNA, is identified in Appendix IV of the this Circular. The Secretariat wishes to draw the attention of DNAs to Article 11, paragraph 2 of the Convention, in relation to the failure to transmit a response or an interim response that does not contain an interim decision.
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2.7 Information on transit movements (in line with Article 14, paragraph 5) Since the last Circular, no Party1 has reported to the Secretariat its need for information on transit movements through its territory of chemicals included in the interim PIC procedure. 3.
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3. ADDITIONAL INFORMATION FOR DNAs 3.1 Information on status of signature and ratification of the Convention The Convention was adopted at the Conference of the Plenipotentiaries in Rotterdam on 10 September 1998 and opened for signature on 11 September 1998. It remained open for signature for one year at the UN Headquarters in New York till 10 September 1999.
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During the signature period, the following 72 States and one regional economic integration organization signed the Convention: Angola, Argentina, Armenia, Australia, Austria, Barbados, Belgium, Benin, Brazil, Burkina Faso, Cameroon, Chad, Chile, China, Colombia, Congo, Costa Rica, Côte d'Ivoire, Cuba, Cyprus, Czech Republic, Democratic Republic of the Congo, Denmark, Ecuador, El Salvador, European Community, Finland, France, Germany, Ghana, Greece, Guinea-Bissau, Hungary, Indonesia, Iran (Islamic Republic of), Israel, Italy, Japan, Kenya, Kuwait, Kyrgyzstan, Luxembourg, Madagascar, Mali, Mauritania, Mongolia, Namibia, Netherlands, New Zealand, Norway, Pakistan, Panama, Paraguay, Peru, Philippines, Portugal, Republic of Korea, Saint Lucia, Senegal, Seychelles, Slovenia, Spain, Sweden, Switzerland, Syrian Arab Republic, Tajikistan, Togo, Tunisia, Turkey, United Kingdom of Great Britain and Northern Ireland, United Republic of Tanzania, United States of America and Uruguay.
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The Convention will enter into force 90 days after the deposition of 50 instruments of ratification, acceptance, approval or accession. As of 30 November 1999, two States (El Salvador and Slovenia) have ratified, accepted, approved or acceded to the Convention. PIC CIRCULAR X December 1999 5 3.2 Documents available under the interim PIC procedure The following materials can be obtained from the Secretariat: !
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The Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade (available in Arabic, Chinese, English, French, Russian and Spanish); ! Final Act of the Conference of Plenipotentiaries on the Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade (available in Arabic, Chinese, English, French, Russian and Spanish); !
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Decision guidance documents for aldrin, DDT, dieldrin, dinoseb and dinoseb salts, fluoroacetamide and HCH (mixed isomers) (available in English, French and Spanish); ! Decision guidance documents for chlordane, EDB, heptachlor, chlordimeform and mercury compounds (available in English, French and Spanish); ! Decision guidance documents for captafol, chlorobenzilate, hexachlorobenzene, lindane, pentachlorophenol and 2,4,5-T (available in English, French and Spanish); !
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Decision guidance documents for binapacryl and toxaphene (available in English, French and Spanish); ! Decision guidance documents for severely hazardous formulations of methamidophos, methyl parathion, monocrotophos, parathion and phosphamidon (available in English, French and Spanish); ! Decision guidance documents for crocidolite, polybrominated biphenyls, polychlorinated biphenyls, polychlorinated terphenyls and tris(2,3-dibromopropyl) phosphate (available in English, French and Spanish); !
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Register of designated national authorities under the interim PIC procedure (English only); ! Form for notification of final regulatory action to ban or severely restrict a chemical (available in English, French and Spanish); ! Instructions for submission of notification of final regulatory action to ban or severely restrict a chemical (available in English, French and Spanish); ! Form for importing country response (available in English, French and Spanish); !
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Instructions for submission of importing country response (available in English, French and Spanish). Most of these documents can also be obtained from the Rotterdam Convention homepage at http://www.pic.int.
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Should you have any queries regarding aspects of the development and operation of the PIC procedure, please do not hesitate to contact the Secretariat at the following addresses: Interim Secretariat for the Rotterdam Convention Plant Protection Service Plant Production and Protection Division, FAO Viale delle Terme di Caracalla 00100 Rome, Italy Tel: (+39 06) 5705 3441 Fax: (+39 06) 5705 6347 E-mail: pic@fao.org Interim Secretariat for the Rotterdam Convention UNEP Chemicals 11-13, Chemin des Anémones CH – 1219 Châtelaine, Geneva, Switzerland Tel: (+41 22) 917 8183 Fax: (+41 22) 797 3460 E-mail: pic@unep.ch PIC CIRCULAR X December 1999 6 APPENDIX I SYNOPSIS OF NOTIFICATIONS OF FINAL REGULATORY ACTION RECEIVED UNDER THE INTERIM PIC PROCEDURE Part A: SUMMARY OF EACH NOTIFICATION OF FINAL REGULATORY ACTION THAT HAS BEEN VERIFIED TO CONTAIN ALL THE INFORMATION REQUIRED BY ANNEX I OF THE CONVENTION The notifications of final regulatory action received after the last Circular (published on 12 June 1999) are still under verification by the Secretariat in accordance with Article 5, paragraph 3 of the Convention.
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Part B: INFORMATION ON NOTIFICATIONS OF FINAL REGULATORY ACTION THAT HAVE BEEN VERIFIED NOT TO CONTAIN ALL THE INFORMATION REQUIRED BY ANNEX I OF THE CONVENTION The notifications of final regulatory action received after the last Circular (published on 12 June 1999) are still under verification by the Secretariat in accordance with Article 5, paragraph 3 of the Convention.
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Part C: NOTIFICATIONS OF FINAL REGULATORY ACTION STILL UNDER VERIFICATION Notifications of final regulatory action have been received by the Secretariat from the States listed below.
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These notifications are still under verification by the Secretariat in accordance with Article 5, paragraph 3 of the Convention: Australia El Salvador Hungary Japan Lao People’s Democratic Republic Niger Thailand PIC CIRCULAR X December 1999 7 APPENDIX II PROPOSALS FOR INCLUSION OF SEVERELY HAZARDOUS PESTICIDE FORMULATIONS RECEIVED UNDER THE INTERIM PIC PROCEDURE Part A: SUMMARY OF EACH PROPOSAL OF SEVERELY HAZARDOUS PESTICIDE FORMULATION THAT HAS BEEN VERIFIED TO CONTAIN ALL INFORMATION REQUIRED BY ANNEX IV, PART I, OF THE CONVENTION NO PROPOSALS FOR INCLUSION OF SEVERELY HAZARDOUS PESTICIDE FORMULATIONS IN THE INTERIM PIC PROCEDURE HAVE BEEN RECEIVED OR ARE UNDER VERIFICATION BY THE SECRETARIAT, IN LINE WITH ARTICLE 6, PARAGRAPH 2.
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Part B: PROPOSALS OF SEVERELY HAZARDOUS PESTICIDE FORMULATIONS STILL UNDER VERIFICATION No proposals for inclusion of severely hazardous pesticide formulations in the interim PIC procedure have been received or are under verification by the Secretariat, in line with Article 6, paragraph 2.
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PIC CIRCULAR X December 1999 APPENDIX III CHEMICALS CURRENTLY SUBJECT TO THE INTERIM PIC PROCEDURE Chemical Relevant CAS number(s) Category Date of first dispatch of decision guidance document 2,4,5-T 93-76-5 Pesticide Prior to adoption of Convention Aldrin 309-00-2 Pesticide Prior to adoption of Convention Binapacryl 485-31-4 Pesticide 1 September 1999 Captafol 2425-06-1 Pesticide Prior to adoption of Convention Chlordane 57-74-9 Pesticide Prior to adoption of Convention Chlordimeform 6164-98-3 Pesticide Prior to adoption of Convention Chlorobenzilate 510-15-6 Pesticide Prior to adoption of Convention DDT 50-29-3 Pesticide Prior to adoption of Convention Dieldrin 60-57-1 Pesticide Prior to adoption of Convention Dinoseb and dinoseb salts 88-85-7 Pesticide Prior to adoption of Convention 1,2-dibromoethane (EDB) 106-93-4 Pesticide Prior to adoption of Convention Fluoroacetamide 640-19-7 Pesticide Prior to adoption of Convention HCH (mixed isomers) 608-73-1 Pesticide Prior to adoption of Convention Heptachlor 76-44-8 Pesticide Prior to adoption of Convention Hexachlorobenzene 118-74-1 Pesticide Prior to adoption of Convention Lindane 58-89-9 Pesticide Prior to adoption of Convention Mercury compounds, including inorganic mercury compounds, alkyl mercury compounds and alkyloxyalkyl and aryl mercury compounds Pesticide Prior to adoption of Convention Pentachlorophenol 87-86-5 Pesticide Prior to adoption of Convention Toxaphene 8001-35-2 Pesticide 1 September 1999 PIC CIRCULAR X December 1999 9 Chemical Relevant CAS
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CIRCULAR X December 1999 9 Chemical Relevant CAS number(s) Category Date of first dispatch of decision guidance document Methamidophos (Soluble liquid formulations of the substance that exceed 600 g active ingredient/l) 10265-92-6 Severely hazardous pesticide formulation Prior to adoption of Convention Methyl-parathion (emulsifiable concentrates (EC) with 19.5%, 40%, 50%, 60% active ingredient and dusts containing 1.5%, 2% and 3% active ingredient) 298-00-0 Severely hazardous pesticide formulation Prior to adoption of Convention Monocrotophos (Soluble
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to adoption of Convention Monocrotophos (Soluble liquid formulations of the substance that exceed 600 g active ingredient/l) 6923-22-4 Severely hazardous pesticide formulation Prior to adoption of Convention Parathion (all formulations - aerosols, dustable powder (DP), emulsifiable concentrate (EC), granules (GR) and wettable powders (WP) - of this substance are included, except capsule suspensions (CS)) 56-38-2 Severely hazardous pesticide formulation Prior to adoption of Convention Phosphamidon (Soluble liquid formulations of the substance that exceed 1000 g active ingredient/l) 13171-21-6 (mixture, (E)&(Z) isomers) 23783-98-4 ((Z)-isomer) 297-99-4 ((E)-isomer) Severely hazardous pesticide formulation Prior to adoption of Convention Crocidolite 12001-28-4 Industrial Prior to adoption of Convention Polybrominated biphenyls (PBB) 36355-01-8 (hexa-) 27858-07-7 (octa-) 13654-09-6 (deca-) Industrial Prior to adoption of Convention Polychlorinated biphenyls (PCB) 1336-36-3 Industrial Prior to adoption of Convention Polychlorinated terphenyls (PCT) 61788-33-8 Industrial Prior to adoption of Convention Tris (2,3-dibromopropyl) phosphate 126-72-7 Industrial Prior to adoption of Convention 10 PIC CIRCULAR X December 1999 APPENDIX IV LISTING OF ALL IMPORTING COUNTRY RESPONSES RECEIVED FROM PARTIES AS OF NOVEMBER 1999 Chemical page 2,4,5-T ................................................................................................................................................................................... 11
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11 Aldrin..................................................................................................................................................................................... 16 Binapacryl.............................................................................................................................................................................. 22 Captafol
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22 Captafol ................................................................................................................................................................................. 23 Chlordane .............................................................................................................................................................................. 28 Chlordimeform ...................................................................................................................................................................... 34 Chlorobenzilate...................................................................................................................................................................... 40 DDT....................................................................................................................................................................................... 45 Dieldrin.................................................................................................................................................................................. 51 Dinoseb and Dinoseb Salts.................................................................................................................................................... 57 EDB (1,2-dibromoethane) ..................................................................................................................................................... 63 Fluoroacetamide .................................................................................................................................................................... 69 HCH (mixed isomers)............................................................................................................................................................ 75 Heptachlor ............................................................................................................................................................................. 81
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81 Hexachlorobenzene ............................................................................................................................................................... 86 Lindane (gamma-HCH)......................................................................................................................................................... 91 Mercury Compounds............................................................................................................................................................. 96 Pentachlorophenol ............................................................................................................................................................... 102 Toxaphene (Camphechlor) .................................................................................................................................................. 107 Methamidophos (Soluble liquid formulations of the substance that exceed 600 g active ingredient/l)............................... 108 Methyl-parathion (emulsifiable concentrates (EC) with 19.5%, 40%, 50%, 60% active ingredient and dusts containing 1.5%, 2% and 3% active ingredient).................................................................................................................................... 111 Monocrotophos (Soluble liquid formulations of the substance that exceed 600 g active ingredient/l) ............................... 114 Parathion (all formulations - aerosols, dustable powder (DP), emulsifiable concentrate (EC), granules (GR) and wettable powders (WP) - of this substance are included, except capsule suspensions (CS))............................................................ 118 Phosphamidon (Soluble liquid formulations of the substance that exceed 1000 g active ingredient/l)............................... 122 Crocidolite........................................................................................................................................................................... 125
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125 Polybrominated Biphenyls (PBBs)...................................................................................................................................... 129 Polychlorinated Biphenyls (PCBs)...................................................................................................................................... 133 Polychlorinated Terphenyls (PCTs) .................................................................................................................................... 138 Tris(2,3 dibromopropyl)phosphate...................................................................................................................................... 142 11 Appendix IV Listing of all importing country responses as of 30 November 1999 2,4,5-T CAS: 93-76-5 ANGOLA Final decision on import Published: 01/1998 no consent BOSNIA AND HERZEGOVINA Interim decision on import Published: 01/1998 no consent BURUNDI Final decision on import Published: 06/1999 no consent CANADA Final decision on import Published: 01/1998 no consent CHAD Interim decision on import Published: 01/1998 no consent Remarks: Final decision pending passage of pesticide control decree.
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CHILE Final decision on import Published: 01/1998 no consent CHINA Final decision on import Published: 01/1998 no consent COLOMBIA Final decision on import Published: 01/1998 no consent Remarks: ICA resolution 749/79 cancels the registration of herbicides based on 2,4,5-T and 2,4,5-TP. COSTA RICA Final decision on import Published: 06/1999 no consent CUBA Final decision on import Published: 12/1999 no consent CYPRUS Final decision on import Published: 01/1998 no consent Remarks: Banned as a pesticide.
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Pest Control Products Board decision October 1979. ESTONIA Final decision on import Published: 01/1998 no consent Remarks: Compound has not been submitted for registration. NORWAY Final decision on import Published: 01/1998 no consent Remarks: Decision 27/73 of 26 Feb 1973. GABON Interim decision on import Published: 01/1998 no consent Remarks: Ministerial decrees have been introduced for the application of Law 7/77 to regulate the import, trade and use of various phytopharmaceutical products.
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Need more time to reach final decision. GAMBIA Final decision on import Published: 01/1998 no consent Remarks: It has been placed on the list of banned pesticides. HONDURAS Final decision on import Published: 01/1998 no consent Remarks: Not registered. Banned in May 1991 due to problems of contamination and health effects. HUNGARY Final decision on import Published: 01/1998 no consent Remarks: Withdrawal documents of Ministry of Agriculture: 9032/1992, 28027/1971, 10254/1971.
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Reason for withdrawal: the unacceptable toxic effect of the active substances. INDIA Final decision on import Published: 01/1998 no consent Remarks: Refused registration due to its extremely hazardous nature and difficulties involved in the availability of impurity-free material. 12 Importing country responses as of 30 November 1999 -2,4,5-T (CAS: 93-76-5) INDONESIA Final decision on import Published: 07/1998 no consent Remarks: Not registered.
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JAMAICA Final decision on import Published: 06/1999 no consent Remarks: Not registered. JAPAN Interim decision on import Published: 12/1999 consent Remarks: A final decision regarding import will be taken only when the chemical is examined as a new chemical after the first notification. Conditions for Import: Registration with the Ministry of Health and Welfare or Prefectural Governor as an importer required.
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For uses other than agricultural chemical, notification to the Minister of International Trade and Industry and the Minister of Health and Welfare required. Registration with the Minister of Agriculture, Forestry and Fisheries required for sale as an agricultural chemical. KAZAKSTAN Final decision on import Published: 01/1998 no consent KENYA Final decision on import Published: 07/1998 no consent Remarks: Not registered. Other pesticides available for similar use.
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Other pesticides available for similar use. IRAQ Final decision on import Published: 01/1998 no consent KOREA, REPUBLIC OF Final decision on import Published: 01/1998 no consent Remarks: The substance has never been registered in Korea. KUWAIT Final decision on import Published: 01/1998 no consent LAO PEOPLE'S Final decision on import Published: 12/1999 no consent DEMOCRATIC REPUBLIC LATVIA Final decision on import Published: 01/1998 no consent Remarks: Compound has not been submitted for registration.
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MADAGASCAR Interim decision on import Published: 01/1998 no consent Remarks: No request for registration. Use practically abandoned. Need more time to reach final decision. MALAYSIA Final decision on import Published: 01/1998 no consent Remarks: Import and manufacture of all pesticides is controlled under the Pesticides Act 1974 through a registration scheme. The Act is implemented by the Pesticides Board of Malaysia. 2,4,5-T is not registered under the above Act.
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2,4,5-T is not registered under the above Act. This means that it cannot be imported, manufactured, sold and used in the country. MALTA Final decision on import Published: 07/1998 no consent MAURITIUS Final decision on import Published: 01/1998 no consent MEXICO Final decision on import Published: 01/1998 no consent Remarks: Import of this product is banned. Product classified as "Use Banned."
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Product classified as "Use Banned." NEW ZEALAND Final decision on import Published: 01/1998 no consent Remarks: The last 2,4,5-T-based pesticide registration was withdrawn (at the manufacturer's request) in 1990. No import or sale permitted. NIGER Interim decision on import Published: 07/1998 no consent Remarks: Not registered. This product not used in Niger. A final decision will be taken in 1998.
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A final decision will be taken in 1998. 13 Importing country responses as of 30 November 1999 -2,4,5-T (CAS: 93-76-5) NIGERIA Final decision on import Published: 01/1998 no consent PAKISTAN Interim decision on import Published: 01/1998 no consent Remarks: Agricultural Pesticide Ordinance 1971. Agricultural Pesticide Rules 1971. PANAMA Final decision on import Published: 07/1998 no consent Remarks: Not registered. Prohibited for use in agriculture.
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
Togo
Prohibited for use in agriculture. PARAGUAY Interim decision on import Published: 01/1998 no consent Remarks: There are no laws that prohibit the use of this product in the country.
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
Togo
PERU Final decision on import Published: 06/1999 no consent PHILIPPINES Final decision on import Published: 07/1998 no consent SAMOA Final decision on import Published: 01/1998 no consent SLOVAKIA Final decision on import Published: 01/1998 no consent Remarks: Act No 285 of 20 November 1995 of the National Council of Slovak Republic on phytosanitary care and list of registered pesticides. SLOVENIA Final decision on import Published: 07/1998 consent Remarks: Prohibited for plant protection use.
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
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Not registered. SUDAN Final decision on import Published: 01/1998 no consent Remarks: The Pesticides and Plant Protection Materials Act, 1994; the National Council for Pesticides. Not registered. SURINAME Interim decision on import Published: 07/1998 consent Remarks: Import prohibited. Final decision on import pending. Conditions for Import: General conditions apply.
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
Togo
Conditions for Import: General conditions apply. SWITZERLAND Final decision on import Published: 12/1999 no consent Remarks: Ordinance relating to Environmentally Hazardous Substances, Annex 3.1: Manufacture, supply, import and use of the Substance and products containing the substance are prohibited.
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
Togo
SYRIAN ARAB REPUBLIC Final decision on import Published: 07/1998 no consent TANZANIA, UNITED Interim decision on import Published: 01/1998 consent REPUBLIC OF Conditions for Import: Permitted only for total weed clearance on roads. THAILAND Final decision on import Published: 01/1998 no consent Remarks: 2,4,5-T was banned according to notification of Ministry of Industry issued under the Hazardous Substance Act B.E.2535 (1992) which has been effective since 2 May 1995.
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
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TOGO Interim decision on import Published: 01/1998 no consent Remarks: Law 96-007/PR of 3 July 1996 concerning plant protection in TURKEY Final decision on import Published: 01/1998 no consent Remarks: Banned by Ministry of Agriculture in 1978.
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
Togo
UGANDA Final decision on import Published: 06/1999 no consent Remarks: Not registered UNITED ARAB EMIRATES Final decision on import Published: 07/1998 no consent 14 Importing country responses as of 30 November 1999 -2,4,5-T (CAS: 93-76-5) URUGUAY Interim decision on import Published: 01/1998 no consent Remarks: Presently product is not registered, imported, manufactured or formulated. By December 1997 final decision on product registration, importation, formulation, fabrication and use will be taken.
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
Togo
VANUATU Interim decision on import Published: 01/1998 no consent Remarks: These chemicals are currently not registered nor approved under the national legislative act (Pesticide Control Act No. 11 of 1993).
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
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VIET NAM Final decision on import Published: 06/1999 no consent 15 Importing country responses as of 30 November 1999 -2,4,5-T (CAS: 93-76-5) Case of failure to transmit a response 2,4,5-T CAS: 93-76-5 Albania, Algeria, Antigua And Barbuda, Argentina, Armenia, Bahamas, Bahrain, Bangladesh, Barbados, Belize, Benin, Bhutan, Bolivia, Botswana, Brazil, Bulgaria, Burkina Faso, Cameroon, Cape Verde, Central African Republic, Comoros, Congo Democratic Republic, Congo Republic of, Cook Islands, Cote D’ivoire, Dominica, Dominican Republic, Ecuador, Egypt, El Salvador, Ethiopia, European Union, Fiji, Georgia, Ghana, Grenada, Guatemala, Guinea, Haiti, Iran (Islamic Republic of), Israel, Jordan, Lebanon, Lesotho, Liberia, Libyan Arab Jamahiriya, Lithuania, Malawi, Mali, Mauritania, Moldova, Mongolia, Morocco, Mozambique, Myanmar, Nepal, Nicaragua, Oman, Papua New Guinea, Qatar, Romania, Russian Federation, Rwanda, Saint Kitts And Nevis, Saint Lucia, Saint Vincent And The Grenadines, Sao Tome And Principe, Saudi Arabia, Senegal, Sierra Leone, Solomon Islands, Sri Lanka, Tajikistan, Tonga, Trinidad And Tobago, Tunisia, Ukraine, United States of America, Uzbekistan, Venezuela, Zambia, Zimbabwe.
https://docs-lawep.s3.us-east-2.amazonaws.com/thematic2a/pw_1/1715698264607.pdf
http://www.pic.int/Portals/5/en/Circular/CIRC10EN.pdf
Togo